FINAL
BEST DEMONSTRATED AVAILABLE TECHNOLOGY (BOAT)
BACKGROUND DOCUMENT FOR
K086 (INK FORMULATION EQUIPMENT CLEANING WASTES)
Larry Rosengrant, Chief
Treatment Technology Section
Jose Labiosa
Project Manager
U.S. Environmental Protection Agency
Office of Solid Waste
401 M Street, S.W.
Washington, D.C. 20460
MAY 1990
NOTE: This background document is on addendum to the August 1988 Final Best Demonstrated
Available Technology (BOAT) Background Document for K086 Solvent Wash (EPA/530-SH-88-031N).
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ACKNOWLEDGEMENTS
This document was prepared for the U.S. Environmental Protection
Agency, Office of Solid Waste, by Versar Inc. under Contract
No. 68-W9-0068. Mr. Larry Rosengrant, Chief, Treatment Technology
Section, Waste Treatment Branch, served as the EPA Program Manager during
the preparation of this document and the development of treatment
standards for the K086 wastewaters and nonwastewaters. The technical
project officer for the waste was Ms. Monica Chatmon-McEaddy. Mr. Jose
Labiosa served as work assignment manager. Mr. Steven Silverman served
as legal advisor.
Versar personnel involved in the preparation of this document
included Mr. Jerome Strauss, Program Manager; Mr. Stephen Schwartz,
Assistant Program Manager; Ms. Christel Ackerman and Ms. Josephfina
Castellanos, Principal Investigators; Ms. Justine Alchowiak, Quality
Assurance Officer; Ms. Juliet Crumrine, Technical Editor; and Ms. Sally
Gravely, Secretary.
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TABLE OF CONTENTS
Section Page No.
1. INTRODUCTION AND SUMMARY 1-1
2. INDUSTRIES AFFECTED AND WASTE CHARACTERIZATION 2-1
2.1 Industries Affected 2-1
2.2 Waste Characterization 2-1
3. APPLICABLE AND DEMONSTRATED TECHNOLOGIES . , 3-1
3 .1 Nonwastewaters 3-1
3.2 Wastewaters 3-2
4. PERFORMANCE DATA 4-1
5. DETERMINATION OF BEST DEMONSTRATED AVAILABLE TECHNOLOGY
(BOAT) 5-1
6. SELECTION OF REGULATED CONSTITUENTS 6-1
7. CALCULATION OF BOAT TREATMENT STANDARDS 7-1
7.1 Volatile Organics 7-2
7.1.1 Acetone 7-2
7.1.2 n-Butyl Alcohol 7-4
7.1.3 Ethyl Acetate 7-5
7.1.4 Ethylbenzene 7-6
7.1.5 Toluene and Xylene 7-6
7.1.6 Methanol 7-7
7.1.7 Methyl Ethyl Ketone and Methyl Isobutyl Ketone .... 7-8
7.1.8 Methylene Chloride, 1,1,1-Trichloroethane and
Trichloroethylene 7-9
7.2 Semivolatile Organics: Acetophenone, bis(2-ethylhexyl)
phthalate, butyl benzyl phthalate, cyclohexanone,
1,2-dichlorobenzene, diethylphthalate, dimethyIphthalate
di-n-butylphthalate, di-n-octylphthalate, naphthalene,
nitrobenzene 7-11
7.3 Metals 7-15
7.4 Cyanide 7-16
8. REFERENCES 8-1
Appendix A Treatment Performance Data for U and P Counterparts
to K086 Constituents A-l
ii
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LIST OF TABLES
Page No.
Table 1-1 BDAT Treatment Standards for K086 Wastewaters 1-4
Table 1-2 BDAT Treatment Standards for K086 Nonwastewaters 1-5
Table 2-1 K086 Waste Characterization Data 2-2
Table 6-1 Additional Candidates for Regulation of K086 6-2
Table 7-la BDAT Treatment Standards for K086 Volatile Organic
Constituents (Single Grab Samples) 7-3
Table 7-lb BDAT Treatment Standards for K086 Volatile Organic
Constituents (Composite Samples) 7-4
Table 7-2 BDAT Treatment Standards for K086 Semivolatile
Organic Constituents 7-13
Table 7-3 BDAT Treatment Standards for K086 Metals and
Cyanide 7-17
iii
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1. INTRODUCTION AND SUMMARY
K086 is defined as "solvent washes and sludges, caustic washes and
sludges, or water washes and sludges from cleaning tubs and equipment
used in the formulation of ink from pigments, driers, soaps and
stabilizers containing chromium and lead" (40 CFR 261.32). Although
these listing criteria suggest three treatability groups, the Agency
believes that it is unnecessary to subcategorize this waste code (beyond
subcategorization of wastewaters and nonwastewaters).
To date, only the solvent wash form of K086 has been regulated. This
was done as part of the First Third rulemaking (53 FR 31138,
August 17, 1988). Since promulgation of the final rule for the First
Third, the Agency has obtained additional K086 waste characterization
data and has performed additional analyses. This new information has
enabled the Agency to re-evaluate the existing K086 treatment standards,
to develop the final revisions for K086 (solvent washes), and to develop
the final treatment standards and approach of all K086 wastes. Except
for metals in K086 wastes, treatment standards promulgated today are
based on revisions and existing standards for the corresponding P and U
waste codes. The listing criteria for K086 wastes include several
operations from the ink manufacturing process generating K086 wastes.
Also, these criteria point out the presence of other listed wastes such
as F001-F005 spent solvents and U or P wastes. (See Listing Background
Document for K086 (USEPA 1980)). Since both K086 wastes and P and U
wastes are likely to be commingled with other wastes for treatment by
incineration, the Agency believes that it is appropriate for organic
constituents of K086 to have the same treatment standard as their P and U
counterparts or similar P or U waste.
In todays rule, EPA is adopting a modified approach for the November
22, 1989, proposed rule (54 FR 48372) revisions for K086 (solvent wash)
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including the addition of seven new constituents for regulation and to
revise the August 17, 1988, promulgated treatment standards for them.
The proposed revisions relied exclusively on incineration performance
data for the development of treatment standards. In response to
comments, EPA modified and developed the proposed revisions to include
treatment standards based on residuals generated from various wastewater
treatment processes rather than incineration scrubber waters. (See
Sections 4 through 7, for a discussion of these additional data.) The
final revisions for K086 (solvent washes) would apply to all forms of
K086 wastewaters and nonwastewaters. See Section 4 for detailed
information regarding these revisions.
This background document presents the additional data and analyses
that are the support for the promulgated K086 treatment standards. This
background document is an addendum to the August 1988 background document
for K086 solvent wash (USEPA 1988a).
The Agency has obtained additional waste characterization data
regarding caustic washes, caustic wash sludges, and solvent wash
sludges. These new data are presented in Appendix A of this addendum,
including waste characterization data originally presented in the K086
solvent wash background document. In addition, the Agency contacted
numerous ink formulators during development of the Third Thirds Proposed
Rule (November 22, 1989) to obtain qualitative information regarding both
K086 waste characterization and industry practices regarding K086
treatment and disposal. Based on analysis of both the old data and the
new data, the Agency concludes that the best demonstrated available
technology (BDAT) and the treatment standards for the various forms of
K086 will be ased on the BDAT for the U and P counterparts.
For K086 wastewaters, BDAT treatment standards for organic
constituents are based on treatment performance data generated from the
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residuals of one or more wastewater treatment processes. Specifically,
these performance data are transferred from EPA's Final Best Demonstrated
Available Technology (BOAT) Background Document for Wastewater Forms of
Organic U and P Wastes and Multi-source Leachate (F039) for Which There
Are Concentration-Based Treatment STandards, Volume A (USEPA 1990). (See
Section 7.0 for a discussion of these transferred data).
BOAT treatment standards for the regulated organics and cyanides in
K086 nonwastewaters are based on incineration. BOAT treatment standards
for the regulated metals are based on hexavalent chromium reduction to
trivalent chromium, followed by lime precipitation and sludge filtration
with stabilization of the sludge. BOAT treatment standards for cyanide
in wastewaters is based on cyanide oxidation.
Promulgated treatment standards for wastewater and nonwastewater
forms of K086 are contained in Table 1-1 and Table 1-2. A number of
differences exist between the treatment standards contained in Table 1-1
and Table 1-2 and the treatment standards promulgated for K086 solvent
wash as part of the First Third rulemaking. These differences include
the following:
• Addition of cyanide and expansion of the number of semivolatile
organic constituents to incorporate the Agency's latest waste
characterization data and analyses and
• Revision of numerical values of some treatment standards
originally promulgated on August 17, 1988 (53 FR 31138).
• Revision for the withdrawal of cyclohexanone and methanol in
K086 nonwastewaters originally promulgated in the August 17, 1988
(53 FR 31138).
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Table 1-1 BOAT Treatment Standards for K086
(Wastewaters)
Maximum for any
Single Grab Sample
Total Composition
Regulated Constituent (mg/1)
Acetone 0.28
Acetophenone 0.010
n-Butyl alcohol 5.6
Cyclohexanone 0.36
1,2-Dichlorobenzene 0.088
Methyl isobutyl ketone 0.14
Methyl ethyl ketone 0.28
Cyanides (Total) 1.9
Chromium (Total) 0.32
Lead 0.037
Maximum for any
Composite Sample
Total Composition
Regulated Constituent (mg/1)
Bis(2-ethylhexyl)phthalate 0.28
Butylbenzylphthalate 0.017
Diethyl phthalate 0.20
Dimethyl phthalate 0.047
Di-n-butyl phthalate 0.057
Di-n-octyl phthalate 0.017
Ethyl acetate 0.34
Ethyl benzene 0.057
Methanol . 5.6*
Methylene chloride 0.089
Naphthalene 0.059
Nitrobenzene 0.068
Toluene 0.080
1,1,1-Trichloroethane 0.054
Trichloroethylene 0.054
Xylenes (Total) 0.32
*Standard for methanol is based on analysis of a composite sample using
SW-846 Msthod 8000.
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Table 1-2 BOAT Treatment Standards for K086
(Nonwastewaters)
Maximum for any
Single Grab Sample
Total Composition
Regulated Constituent (mg/kg)
Acetone 160
Acetophenone 9.7
Bis(2-ethylhexyl)phthalate 28
n-Butyl alcohol 2.6
Butylbenzylphthalate 7.9
1,2-Dichlorobenzene 6.2
Diethyl phthalate 28
Dimethyl phthalate 28
Di-n-butyl phthalate 28
Di-n-octyl phthalate 28
Ethyl acetate 33
Ethyl benzene 6.0
Methyl isobutyl ketone 33
Methyl ethyl ketone 36
Methylene chloride ' 33
Naphthalene 3.1
Nitrobenzene 14
Toluene 28
1,1,1-Trichloroethane 5.6
Trichloroethylene 5.6
Xylenes (Total) 28
Cyanide (Total) 1.5
Maximum for any
Single Grab Sample
TCLP
Regulated Constituent (mg/1)
Chromium 0.094
Lead 0.37
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Except for the chromium (total) and lead treatment standards,
standards for K086 solvent wash promulgated as part of the First Third
rulemaking (see 53 FR 31138, August 17, 1988) are now superseded by the
treatment standards finalized in the May 8, 1990, final rule.
For the applicability of the promulgated standards, a wastewater is
defined as wastes containing less than 1 percent (weight basis) total
suspended solids* and less than 1 percent (weight basis) total organic
carbon (TOC). Waste not meeting this definition must comply with the
promulgated treatment standards for nonwastewaters.
* The term "total suspended solids" (TSS) clarifies EPA's previously used
terminology of "total solids" and "filterable solids." Specifically,
the quantity of total suspended solids is measured by Method 209C
(total suspended solid dried at 103°C to 105°C) in Standard
Methods for the Examination of Water and Wastewater, 15th edition
(APHA, AQQA, and WPCF 1985).
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2. INDUSTRIES AFFECTED AND WASTE CHARACTERIZATION
2.1 Industries Affected
The Agency has no new data that would change the description of the
ink formulation industry contained in the K086 solvent wash background
document.
2.2 Waste Characterization
The Agency has obtained information regarding K086 sludges and
caustic/water wash wastes since promulgation of the First Third Final
Rule. This .information is presented in Table 2-1. Table 2-1 also
contains the data regarding K086 solvent wash that were in the K086
solvent wash background document. Note that the liquid portion of the
caustic wash, although consisting mostly of water, contains total organic
carbon of 26,000 mg/1. This liquid is a nonwastewater under the Agency's
definitions because its organic content is greater than 1 percent by
weight. (In the K086 solvent wash background document (USEPA 1988a),
wastewaters are defined as wastes containing less than 1 percent (weight
basis) total suspended solids and less than 1 percent (weight basis)
total organic carbon. Wastes not meeting this definition are considered
nonwastewaters.)
Table 2-1 contains composition data for K086 solvent wash liquid
wastes and sludge wastes and for K086 caustic wash liquid wastes and
sludge wastes. The data for K086 solvent wash liquid wastes were
reported in the K086 solvent wash background document (USEPA 1988a) and
are repeated in Table 2-1 for convenience. The data for the caustic wash
liquid and sludge wastes were obtained by sampling and analysis of one
ink formulator's wastes (USEPA 1989c). The data for solvent wash sludge
were obtained by sampling and analysis of another ink formulator's waste
(Versar 1988a).
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2988Q
Table 2-1 K086 Waste Characterization Data
Untreated K086 caustic wash Untreated K086 solveH
BOAT Untreated K086 solvent wash waste concentration wash sludge waste |
reference liquid waste concentration (mg/kg) Liquid (mg/1) Sludge (rag/kg) concentration (mg/kg)
nurter Analyte (1) (1) (2) (2) (3)
222
21
225
226
34
229
38
42
43
45
215-7
53
70
232
98
121
154
155
156
157
158
159
221
160
161
162
163
164
165
166
167
168
Volatile Oman ics
Acetone
Oichlorodlfluoranethane
Ethyl acetate
Ethytbenzene
Methyl ethyl ketone
Nethyl isobutyl ketone
Methylene chloride
Tetrach loroethene
Toluene
1 . 1. l-Tr1chloraethane
Xylene (total)
Sanlvolatlle Organic*
Acetophenone
b1s(2-Ethylhexy1)phtha1ate
Cyc lohexanone
Oi-n-butyl phthalate
Isophorone
Naphthalene
Metals
Antimony
Arsenic
Barlu*
Beryl HUM
CaoteliM
Chromium (total)
ChroniuM (hexavalent)
Copper
Lead
Mercury
Nickel
SeleniuM
Silver
Thallium
Vanadiun
Zinc
CBI
-
-
CBI
CBI
CBI
CBI
-
CBI
CBI
CBI
.
CBI
CBI
-
CBI
CBI
CBI
-
CBI
-
CBI
CBI
CBI
-
CBI
-
CBI
CBI
CBI
-
-
CBI
3
NO
256.000 NO
NO
-
NO
1.5
0.52
3.6
NO
NO
NO
NO
NO
NO
NO
NO
0.57
0.04
0.54 0.46
NO
4.3 0.006
116.0 164
156
0.34
1.1 179
0.03
2.4 9.9
0.5 0.6
0.32 0.03
2.2
NO
1.1 0.22
NO
6.5
NO
NO
-
NO
80
NO
380
5.3
9.1
19
37
NO
83
NO
NO
NO
1.1
3.880
NO
9
1.850
257
495
9.250
1.1
34.7
NO
2.5
NO
NO
183
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
2-2
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2988g
Table 2-1 (Continued)
Untreated K086 Caustic Wash Untreated K086 solvent
BOAT Untreated K086 solvent wash Waste Concentration wash sludge waste
reference liquid waste concentration (dig/kg) Liquid (mg/1) Sludge (mg/kg) concentration (nig/kg)
number Analyte (1) (2) (2) (2) (3)
Inorganics Other Than Metals
Chloride
169 Cyanide CBI
170 Fluoride
Sulfate
171 Sulfide CBI
Other
pH CBI
Dissolved solids
Moisture CBI
Total organic carbon CBI
Total organic halide
Oven vo la tiles at 105*C (X)
Ash (X) CBI
Sulfur (X)
Btu/lb (X) CBI
Carbon (X)
Hydrogen (X)
Nitrogen (X)
Chlorine (X)
Moisture by distillation
Volatile matter at 950*F
Total solids CBI
Organic ink pigments
Ethyl alcohol
Naphtha CBI
734
412
475
1.420
25
6.3 11.93
71.700
-
26.000
17
90.44
4.6
0.1
13.600 <100
3.03
10.1
0.28
0.1
_
-
5.700
77.000
667.000
~ -
263
7.120
606
574
131
11.28
-
456.000
203.000
9.1
_
15.96
0.18
<100
22.8
8.4
1.63
0.88
47.65
78.58
-
.
-
-
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI
CBI Confidential Business Information.
No analysis performed.
NO Not detected.
Sources: (1) USEPA 1988a (Table 2-3).
(2) USEPA 1989c.
(3) Versar 1988a.
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The Agency has obtained no data for K086 water wash liquid wastes and
sludge wastes. However, the Agency believes that the compositions of
K086 water wash liquids and sludges are similar to the compositions of
K086 caustic wash liquids and sludges because water washes and caustic
washes are both water-based and because they are both usually used to
clean equipment used to formulate similar (water-based) inks.
Conceivably, K086 water wash liquids and sludges could contain higher
water contents and lower waste constituent concentrations than their K086
caustic wash counterparts because the K086 water wash liquids and sludges
lack the caustic cleaning agent. This suggests that K086 water wash
liquids and sludges are easier to treat, or certainly no more difficult
to treat, than their K086 caustic wash counterparts and that transfer of
BOAT and treatment standards from K086 caustic wash to K086 water wash is
appropriate.
Table 2-1 shows, as expected, that the sludges from K086 caustic
washes and solvent washes contain higher solids contents than do the
liquids. Also, the water content of the caustic wash liquids and sludges
are higher than those of the solvent wash liquids and sludges. From a
treatability standpoint, however, there are many more similarities than
differences among the various wastes. Many of the same organic,
inorganic, and metal constituents are present in all the wastes.
Furthermore, all of the wastes, including the caustic wash liquid, have
similar amounts of organics, cyanide, and metals. Although it is
water-based, the caustic wash liquid waste does not meet the Agency's
definition of wastewater. The similarities among the wastes strongly
imply that the same treatment train for removing or destroying organics,
cyanide, and metals is likely to be appropriate for each waste.
In addition, the Agency has contacted numerous generators or potential
generators of K086 (Versar 1988b-d), has monitored technical literature
of the ink formulation industry (Flick 1985, Leach 1988, NAPIM 1988), and
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has maintained contact with the National Association of Printing Ink
Manufacturers. Data from these activities indicate or confirm the
following with regard to the business, technology, and operating
practices of the printing ink manufacturing industry:
• About one million new ink formulations are prepared yearly and
several million ink formulation specifications are retained on active
file.
• Formulations are changed and retailored in response to customer
needs, market forces, technology advances, and the availability of
new or improved raw materials.
• Use of chromium- and lead-based pigments is decreasing.
• Use of organic pigments is increasing.
• Ink formulation tubs and equipment are cleaned between batches.
Liquids and sludges resulting from cleaning operations are kept in
vessels that are separate from the tubs used for ink formulation.
Liquids resulting from cleaning operations are generally reused for
cleaning. Vessels containing spent cleaning liquids and sludges are
emptied periodically, e.g., weekly or monthly, into drums. The drums
are shipped to a commercial treater for treatment and disposal.
• A few K086 generators appear to practice limited onsite recycle
(e.g., distillation of solvent-containing wastes) or onsite
pretreatment (e.g., neutralization) of K086 waste prior to shipment
of the waste to a treater.
• Cleaning solutions--both solvent- and water-based--are reused many
times for cleaning different formulations before the cleaning
solutions are considered "spent."
• Plants generally formulate both solvent/oil-based inks and
water-based inks.
• No evidence was found that ink formulation equipment dedicated
exclusively to formulation of lead- and/or chromium-containing inks
is used. No evidence was found that ink formulation cleaning wastes
containing lead or chromium are segregated from ink formulation
cleaning wastes that do not contain these metals.
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3. APPLICABLE AND DEMONSTRATED TREATMENT TECHNOLOGIES
The Agency has identified no applicable and demonstrated technologies
for K086 beyond those already described in the K086 solvent wash
background document (USEPA 1988a).
For the reasons discussed below, the Agency believes that the
applicable and demonstrated technologies for K086 solvent wash liquid are
also applicable and demonstrated for K086 solvent wash sludge. For
instance, incineration has been identified as an applicable technology
for organics in solvent wash wastes (USEPA 1988a). This standard was
revised to reflect detection levels in different wastes because the
matrices used to generate the proposed standards were ash from burns of
phthalate wastes (K024) and disulfoton wastes (K037), both unique
matrices. Acetone and ethyl acetate are volatile organics while K024 and
K037 raw wastes, from which proposed standards for these compounds were
derived, are high in semivolatile compounds such as polynuclear aromatics
(PNAs). EPA chose to base the promulgated standards on a matrix from
incinerated wood-preserving wastes (K001 PCP and creosote) because these
are complex matrices with high concentrations of many organic compounds,
volatiles, semivolatiles, chlorinateds, and others, and, consequently,
are particularly difficult to analyze. Detection limits from these
compounds are therefore particularly achievable.
As with K086 solvent wash, K086 sludges can be fed to incinerators
via conventional centrifugal pumps, positive displacement pumps, ram
feeders, or screw feeders.
3.1 Nonwastewaters
Incineration is a destruction technology in which energy, as heat, is
transferred to the waste to destabilize chemical bonds and destroy
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hazardous organic constituents. Combustion gases from the incinerator
are then fed to a scrubber system for cooling and removal of any
entrained particulates and acid gases. In general, with the exception of
liquid injection incineration, two residuals are generated by incinerator
processes: ash and scrubber water.
Once organics are treated by incineration, the metals originally in
the wastes are contained in the incineration residues such as scrubber
water and ashes. Hexavalent chromium can be reduced to trivalent
chromium, and the leachability of the trivalent chromium can be decreased
by stabilization. However, dissolution of the incinerator ash in water
may be needed for subsequent reduction of hexavalent chromium to
trivalent chromium, e.g., by water-soluble reducing agents such as sodium
bisulfite or the ferrous form of iron.
Similarly, organics in K086 wastes resulting from water or caustic
cleaning of ink formulation tubs and equipment can also be treated by
incineration. This treatment, however, may require relatively large
amounts of supplemental fuel for proper incineration because of the high
concentration of water in the wastes. At least one facility has reported
treating K086 liquid wastes resulting from water or caustic washing by
incineration.
3.2 Wastewaters
Another way of treating high water content K086 liquid waste includes
decanting the liquid from the sludge, partially treating the liquid to
precipitate a portion of the suspended and dissolved solids, and reusing
the liquid. Wet air oxidation and chemical oxidation followed by carbon
adsorption should also be considered applicable technologies for
pretreatment of high water content K086 liquid wastewaters. Wet air
oxidation is a destruction technology in which hazardous organic
3-2
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constituents in wastes are oxidized and destroyed under pressure at
elevated temperatures in the presence of dissolved oxygen. This
technology is applicable for wastes composed primarily of water and up to
10 percent total organic constituents. Wet air oxidation generates one
treatment residual: treated effluent. The treated effluent may require
further treatment for hazardous organic constituents by carbon
adsorption. The carbon is then incinerated and must meet nonwastewater
standards. This process gives the option of incinerating a smaller
amount of waste.
It is conceivable that biological treatment (including activated
sludge) could be applicable for treatment of the organics in high water
content K086 nonwastewaters and wastewaters. Biological treatment is a
destruction technology in which hazardous organic constituents in
wastewaters are biodegraded. This technology generates two treatment
residuals: a treated effluent and a waste biosludge. Waste biosludge
may be land disposed without further treatment if it is less than or
equal to the BOAT nonwastewater treatment standards. Again, the Agency
has no data regarding the performance of these technologies on K086
wastes or similar wastes. Thus, the Agency does not consider these
technologies demonstrated for K086 wastes.
Other available technologies considered by the Agency are powdered
D
activated carbon addition to activated sludge (PACT ), granular
activated carbon (GAC), and steam stripping (SS).
PACT and GAC treatments are a combination of carbon adsorption and
biological treatment in which hazardous organic constituents are
biodegraded or selectively adsorped onto powder-activated carbon. This
technology generates two treatment residuals: a treated effluent and
spent carbon/biosludge. The spent carbon may be regenerated and recycled
to the process or may be incinerated.
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Steam stripping is a separation technology in which wastewaters
containing volatile organics have the organics removed by application of
heat using steam as the heat source. This technology generates one
treatment residual: treated effluent. Emissions from steam stripping
may require further treatment.
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4. PERFORMANCE DATA
On August 17, 1988, the treatment standards promulgated for K086
wastes were based on the incineration of a K086 solvent wash. The incine-
ration of this wash yielded an incineration scrubber wastewater and no
ash. Characterization of K086 incineration scrubber waters showed that
the organics from the untreated K086 solvent wash were substantially
reduced but the metals were concentrated in the residue. Based on the
above-mentioned characterization data of these incineration scrubber
waters, EPA identified a metal-bearing wastewater with similar
treatability characteristics to the K086 solvent wash that had been
treated by hexavalent chromium reduction to trivalent chromium followed
by excess lime precipitation and filtration. The wastewater treatment
sludge derived from the treatment of this similar metal-bearing
wastewater contained detection levels for volatile and semivolatile
organics. Therefore, the Agency proposed and promulgated treatment
standards for the K086 (solvent washes) nonwastewaters based on the
highest detection limit of the organic constituents in this similar
wastewater treatment sludge.
New information suggests that facilities generating K086 may be
phasing out the generation of these wastes. However, some facilities
still report sporadic generation of K086. EPA believes that these wastes
can be treated by certain BOAT technologies such as incineration for
nonwastewaters; wet air oxidation, biological treatment, or steam
stripping technologies for wastewaters; and technologies designed to
treat metals. Because of the sporadic generation of K086 wastes, the
characteristics of its listing criteria, and the known waste management
practices for these wastes, EPA expects residues from the treatment of
K086 to show similar analytical difficulties as those shown by U and P
wastes. As a result, the Agency is promulgating, for the constituents
candidate for regulation in K086 wastes (cyanides and organics), the same
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treatment standards proposed for its U and P counterparts except for
methanol- and cyclohexanone-containing nonwastewaters. The treatment
standards promulgated for methanol and cyclohexanone nonwastewaters are
methods of treatment.
For K086 wastewaters, the treatment standards for the U and P
counterparts were developed and updated using treatment performance data
for wastewaters from various sources: (1) the Office of Water's
Industrial Technology Division (ITD) and National Pollution Discharge
Elimination System (NPDES) data; (2) the Hazardous Waste Engineering
Research Laboratory (WERL) data base; (3) the Office of Solid Waste's
BOAT data from previous land disposal restrictions rules and the
wastewater treatment test on wet air oxidation (WAO) and PACT^
technologies; (4) industry-submitted leachate treatment performance data;
and (5) additional wastewater treatment data from literature articles on
WAO and PACTR. (USEPA 1990a).
For K086 nonwastewaters, the treatment standards or methods of
treatment are based on the U and P counterparts. Numerical treatment
standards were developed for wastes that are amenable to quantification
in hazardous waste matrices, and treatment standards specifying method of
treatment were developed for wastes that are not amenable to
quantification in hazardous waste matrices using current analytical
methods.
The Agency has treatment performance data from two rotary kiln
incinerator test burns EPA performed in June 1989 for waste constituents
from several of the waste treatability groups. The Agency also has
treatment performance data from 12 other incineration tests performed by
EPA for previous rulemakings for the BOAT program (USEPA 1990b).
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5. DETERMINATION OF BEST DEMONSTRATED AVAILABLE TECHNOLOGY
(BDAT)
Data regarding characterization of K086 wastes and regarding ink
formulation industry practices with regard to K086 treatment and disposal
are reported earlier in this addendum and in the original background
document. Conclusions drawn from analysis of the data are presented in
the section entitled "Industries Affected and Waste Characterization."
The Agency has obtained no new numerical treatment performance data.
Based on an examination of both old and new data, the Agency
concludes that the best demonstrated available technology (BDAT) for all
forms of K086 waste is the same as that for K086 solvent wash as
contained in the background document for K086 solvent wash (USEPA 1988a).
This conclusion is based on the similarities among the wastes as
discussed in the Industries Affected and Waste Characterization section.
The Agency believes that K086 wastes generated by ink formulators
would rarely meet the Agency's definition of wastewaters (less than
1 weight percent total suspended solids and less than 1 weight percent
total organic carbon). Incineration of the as-generated K086 wastes
would, however, result in wastewaters, e.g., incinerator scrubber waters,
or incinerator ash that has been mixed with water for the purpose of
reduction of hexavalent chromium (Cr ) to trivalent chromium
(Cr ). Both of these wastewaters are considered K086 wastes by virtue
of the Agency's "derived from" rule.
The BDAT for K086 wastes contained in the K086 solvent wash
background document (USEPA 1988a) is summarized below by major K086 waste
component.
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Maior K086 Waste Component
Nonwastewater organics
and cyanide
Metals
BOAT
Wastewater Organics
Incineration
Hexavalent chromium reduction
to trivalent chromium followed
by lime precipitation and
sludge filtration with
stabilization of sludge
Incineration, wet air
oxidation or chemical
oxidation followed by carbon
adsorption, biological
treatment, or steam stripping
As shown, BDAT for organics and cyanide in K086 nonwastewaters is
incineration. BDAT for organics in K086 wastewaters is incineration, wet
air oxidation or chemical oxidation followed by carbon adsorption,
biological treatment, or steam stripping (see Section 7). BDAT for
chromium and lead in K086 is hexavalent chromium reduction followed by
lime precipitation, sludge filtration, and stabilization of the sludge.
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6. SELECTION OF REGULATED CONSTITUENTS
The Agency reviewed the list of regulated constituents for the K086
solvent wash in light of the additional data on waste characterization
and industry practices. This review resulted in a revised list, which
has been expanded by the addition of several constituents. The Agency
believes that the revised list is appropriate for all forms of K086 waste.
The characterization data available for K086 wastes show a large
number of hazardous constituents in K086 that could be candidates for
regulation, possibly as a result of the widespread industry practice of
reusing the same cleaning/ washing solutions to clean the equipment used
for the formulation of many different ink batches (USEPA 1980, Versar
1989). Also, some of these hazardous constituents could be residues left
in the ink formulation equipment that were originally ingredients or
constituents in the feedstock materials used in the formulation of inks.
Table 2-1 of this addendum lists all BOAT constituents detected in the
K086 wastes characterized by the Agency. Any BOAT list constituent that
is present above its detection limit is a candidate for regulation.
EPA is proposing to broaden the list of regulated constituents
contained in the K086 solvent wash background document (USEPA 1988a) to
account for constituents that are shown in Table 2-1 of this addendum but
were not regulated in the First Third K086 solvent wash rulemaking. The
constituents on the broadened list are acetophenone, butyl benzyl
phthalate, di-n-butyl phthalate, and cyanide.
In addition, EPA proposes to regulate several other BOAT list
constituents. These other constituents, which are listed in Table 6-1,
are phthalate constituents. These additional phthalates are proposed for
regulation either because they are reported as ink formulation
ingredients (Flick 1985) or because they are BOAT list phthalates that
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could be used as substitutes for the phthalates shown in Table 2-1. The
phthalates--bis (2-ethylhexyl) phthalate, butyl benzyl phthalate, and
di-n-butyl phthalate--are shown in Table 2-1. The Agency is including
the additional phthalates shown in Table 6-1 because the members of the
regulated community can simply switch from regulated BDAT list phthalates
to nonregulated BDAT list phthalates in order to avoid regulation. This
approach is consistent with the Agency's determinations for the solvent
standards already promulgated in the First Third Final Rule (53 FR 31138).
Table 6-1 Additional Constituents
for Regulation of K086
BDAT reference number Constituent
92 Diethyl phthalate
97 Dimethyl phthalate
104 Di-n-octyl phthalate
The Agency believes that treatment of regulated BDAT constituents to
levels given in this addendum will result in essentially complete removal
or destruction of unregulated BDAT list constituents.
The Agency considered adding additional metals to lead and chromium,
which were regulated for K086 solvent wash. For example, both barium and
cadmium were considered for addition. However, the Agency decided not to
add additional metals for this rulemaking because the Agency believes
regulation of chromium and lead will provide for regulation of barium and
cadmium, as well as other BDAT metals that may be present in K086
wastes. Those processes used to reduce lead and chromium concentrations
in the K086 treatment residual leachate to below the treatment standards
are also known to reduce concentrations of other metals in the K086
treatment residual leachate (see data in Table 4-2 of the K086 solvent
wash background document (USEPA 1988a)).
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7. CALCULATION OF BOAT TREATMENT STANDARDS
The explanation of the calculation of the treatment standards is
/
given below on a constituent-by-constituent basis, in approximately the
same order as that in Table 1-1.
The Agency points out that many of the treatment standards for
individual regulated constituents are now different from the treatment
standards set for K086 solvent wash in the First Third rulemaking,
particularly regarding organic constituents. This is because of the
Agency's belief that treatment, particularly incineration, of K086 wastes
is often done with other hazardous and nonhazardous wastes (i.e.,
co-incineration). The mixing of K086 wastes with other solvents as well
as other hazardous/nonhazardous wastes prior to incineration may result
in treatment residuals (incinerator ashes and scrubber waters) that could
vary in composition, possibly affecting detection limits for the
regulated organic constituents.
Several commenters to the First Third Rule expressed the above
concern regarding achieving K086 solvent wash standards. Thus, the
Agency has reviewed additional incineration data and is revising some of
the standards for K086 solvent wash in order to address the issue.
With regard to the co-incineration issue, the Agency believes that
treatment of K086 is similar to the offsite treatment of P and U wastes.
That is, P and U wastes that are not treated at the site where they are
generated are shipped to commercial treatment facilities where the P and
U wastes are treated along with other wastes. Since both K086 wastes and
P and U wastes are likely to be commingled with other wastes for
treatment by incineration, the Agency believes it is appropriate that
organic constituents of K086 have the same treatment standards as their
P and U counterparts.
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In conjunction with this and prior rulemakings, the Agency has
examined numerous sets of data for incineration of wastes containing
organic constituents that are the same as or similar to the organic
constituents found in K086 wastes. Based on these examinations, the
Agency believes that well-designed, well-operated incinerators are
capable of destroying organics in K086 waste to concentrations well below
the standards being proposed for K086 organic constituents, regardless of
whether the K086 wastes are mixed with other hazardous or nonhazardous
wastes.
Wastewater treatment data primarily from EPA's Office of Water have
been analyzed for the development of concentration-based treatment
standards for many of the U and P wastes. These data include the
treatment of wastewaters that are not specifically listed as U or P
wastewaters, but do contain many of the corresponding U or P constituents.
7.1 Volatile Orcanics
7.1.1 Acetone
For nonwastewaters, the Agency has examined data from 14 incineration
burns. This examination was conducted in conjunction with the Third
Third rulemaking for U002. Acetone was detected in three of the
incineration tests. The highest detection limit in the test in which it
was detected in the untreated waste was 0.01 ppm. The Agency believes
that this detection limit is too low to be routinely achievable in ash by
analytical laboratories. The highest detection limit for acetone from
all the incineration tests was used to calculate a treatment standard of
160 mg/kg acetone for U002. This standard is transferred to acetone in
K086 nonwastewaters and is presented in Table 7-1.
In contrast, the acetone standard for K086 solvent wash nonwastewater
in the First Third rulemaking was determined based on the acetone
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Table 7-la BOAT Treatment Standards for
K086 Volatile Organic Constituents
Maximum (single grab sample)
Nonwastewater Wastewater
Constituent Total concentration Total concentration
(mgAg) (mg/1)
Acetone 160 0.28
n-Butyl alcohol 2.6 5.6
Methyl ethyl ketone 36 0.28
Methyl isobutyl ketone 36 0.14
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Table 7-lb BOAT Treatment Standards for
K086 Volatile Organic Constituents
Maximum (composite samples)
Constituent
Nonwastewater
Total concentration
(mg/kg)
Uastewater
Total concentration
(mg/D
Ethyl acetate
Ethylbenzene
Methanol
Methylene chloride
Toluene
1 , 1 , 1-Trichloroethane
Trichloroethylene
Xylene (total)
33
6.0
[a]
33
28
5.6
5.6
28
0.34
0.057
5.6
0.089
0.080
0.054
0.054
0.32
[a] At this time, EPA is withdrawing this constituent from the list of
regulated constituents in K086 nonwastewaters (see Section 7.1.6 for
a discussion of this decision).
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detection limit in a filter cake resulting from the filtration of a
metal-bearing wastewater that had been treated to precipitate metals.
This resulted in a standard of 0.37 mg/1 acetone. The Agency notes that
today's promulgated standard for acetone is based on acetone detection
limits in incinerator ash. Because incineration processes destroy
acetone, and the resulting matrices reflect the treatment of K086 wastes
that yield ash, the Agency believes this new standard is more realistic
than the one previously promulgated for K086 solvent washes.
The data available for wastewaters containing acetone were compiled
from the WERL and NPDES data bases and wet air oxidation (WAO) data and
are presented in the Appendix A. The promulgated BOAT standard was set
using biological treatment technology and an achievable effluent of 100
ppb. When leachate treatment performance data are submitted, showing
substantial treatment for a constituent that shows average leachate
effluent values greater than those used in setting the treatment
standard, the leachate treatment performance data are given priority and
used as BDAT.
The resulting BDAT treatment standard for acetone-containing
wastewaters is 0.28 ppm as shown in Table 7-1.
7.1.2 n-Butyl Alcohol
The Agency believes that nonwastewaters containing n-butanol would be
essentially completely destroyed in a well-designed, well-operated
incinerator and that analyses of incinerator ash and scrubber waters
would show nondetectable concentrations of n-butanol. Thus, performance
data from well-designed and well-operated incinerators would always show
nondetectable concentrations of n-butanol in the incinerator residuals.
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In conjunction with setting treatment standards for n-butanol in
U031, the Agency examined detection limits for n-butanol in incinerator
ash and incinerator scrubber water. In many cases there were no attempts
made to analyze for n-butanol and therefore no detection limit data were
available. However, the Agency did find detection limit data for
analysis of incinerator residuals from one incinerator. These limits
were 0.4 mg/kg and 0.2 mg/1 for n-butanol in the ash and scrubber water,
respectively. The Agency used an accuracy correction factor of 2.33 and
a variability factor of 2.8 to calculate a treatment standard for
n-butanol of 2.6 in U031 nonwastewaters (see Table 7-1).
For wastewaters containing n-butyl alcohol, data were compiled from
the Hazardous Waste Engineering Research Laboratory (WERL) data base and
are presented in Appendix A. The promulgated BDAT standard was set using
biological treatment and an achievable effluent of 2000 ppb. The
resulting treatment standard for wastewaters containing n-butyl alcohol
is 5.6 ppm as shown in Table 7-1.
7.1.3 Ethyl Acetate
The standard for nonwastewaters containing ethyl acetate was revised
to reflect detection levels in different wastes because the matrices used
to generate the proposed standards were ash from burns of phthalate
wastes (K024) and disulfoton wastes (K037), both unique matrices.
Acetone and ethyl acetate are volatile organics while K024 and K037 raw
wastes, from which proposed standards for these compounds were derived,
are high in semivolatile compounds such as PNAs. EPA chose to base the
promulgated standards on a matrix from incinerated wood-preserving wastes
(K001 PCP and creosote) because these are complex matrices with high
concentrations of many organic compounds, volatiles, semivolatiles,
chlorinateds, and others, and, consequently, are particularly difficult
to analyze. Detection limit from these compounds are thus particularly
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achievable. Therefore, the Agency is revising the nonwastewater standard
for ethyl acetate to 29 mg/kg as shown in Table 7-1.
For wastewaters containing ethyl acetate, data were compiled from the
WERL data base and the EPA WAO test. These data are presented in
Appendix A. Biological treatment (e.g., activated sludge) has been
selected as BOAT because the data show a high influent concentration and
high removal efficiency. The treatment standard for wastewaters
containing ethyl acetate is 0.34 ppm as shown in Table 7-1.
7.1.4 Ethylbenzene
The Agency is revising the nonwastewater standard for ethylbenzene
based on treatment performance data for K019. Detailed information on
the treatment performance data and methodology used to calculate the
treatment standards can be found in the K019 background document.
Therefore, for ethylbenzene nonwastewaters, the treatment standard is
6.0 mg/1 and is shown in Table 7-1.
For wastewaters containing ethylbenzene, data were compiled from the
WERL data base, BOAT Solvents Rule data, and literature PACT® AND WAO
data. These data are presented in Appendix A. The promulgated BOAT
standard was set using biological treatment and an achievable effluent of
10 ppb. The BOAT treatment standard for ethylbenzene-containing
wastewaters is 0.057 ppm as shown in Table 7-1.
7.1.5 Toluene and Xylene (total)
In conjunction with the rulemaking for aromatic hydrocarbon U-wastes,
the Agency is transferring treatment standards for toluene (U220) and
total xylene (U239) to K086 wastes (USEPA 1989e).
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For U220 and U239 nonwastewaters, the standards are 28 mg/kg toluene
and 28 mg/kg total xylene. Detailed information on the treatment
performance data and methodology used to calculate the treatment
standards can be found in the U220 (toluene) and U239 (total xylene)
background documents.
For wastewaters containing toluene, data were available from the ITD
and WERL data bases, BOAT Solvents Rule data, literature WAO and
PACT® data, and EPA WAO test data. The BOAT for toluene is steam
stripping, and the treatment standard is 0.08 mg/1. For wastewaters
containing xylene, data were available from the NPDES and WERL data
bases, BOAT Solvents Rule data, and literature WAO and PACT® data.
The BDAT for wastewaters containing xylene is wet air oxidation, and the
treatment standard is 0.32 mg/1.
The treatment standards presented above can be found in Table 7-1.
7.1.6 Methanol
For nonwastewaters containing methanol, a method of treatment for
nonwastewaters containing methanol is being specified as the treatment
standard because of complications encountered in applying the treatment
standard calculation methodology for U and P wastes to the data available
for a particular waste.
Treatment standards for U and P wastes that are amenable to
quantification in hazardous waste matrices were calculated based on
detection limits for incinerator ash and scrubber water residuals
collected during the 14 BDAT incineration treatment tests performed by
EPA for the BDAT Land Disposal Restrictions Program. Concentration-based
treatment standards were calculated by multiplying the constituent
detection limit by an accuracy correction factor and by a variability
factor. The range of detection limits spanned several orders of
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magnitude, suggesting the presence of matrix interferences in the
treatment residuals. The treatment standards that were then calculated
were 1,000 ppm or greater. The establishment of treatment standards at
these levels would not ensure substantial treatment for the constituents
of concern. Therefore, for nonwastewaters containing methanol, the
Agency is specifying a method of treatment consisting of incineration,
wet air oxidation followed by chemical adsorption, or chemical oxidation
followed by chemical adsorption. The carbon is then incinerated and must
meet the nonwastewater standard.
For wastewaters containing methanol, data were compiled from the WERL
data base and literature PACT® data and are presented in Appendix A.
The promulgated BOAT standard was set using biological treatment and an
achievable effluent of 2,000 ppb. When leachate treatment performance
data were submitted showing substantial treatment for a constituent that
showed average leachate effluent values greater than those used in
setting the proposed standard, the leachate treatment performance data
were given priority and used as BOAT. Therefore, for methanol in
wastewater forms of multisource leachate, the treatment standard is
5.6 mg/1 as shown in Table 7-1.
7.1.7 Methyl Ethyl Ketone and Methyl Isobutyl Ketone
In conjunction with the rulemaking for U159 (methyl ethyl ketone) and
U161 (methyl isobutyl ketone), the Agency examined results of
incinerating several different wastes containing these constituents in
several different incinerators (USEPA 1989d). The constituents were not
detected in incinerator ash or scrubber water in all cases except one
case where the blank was contaminated with methyl ethyl ketone.
The Agency is transferring the resultant standard of 33 mg/kg for
methyl isobutyl ketone in U161 nonwastewater to methyl isobutyl ketone in
K086 nonwastewater. The Agency is transferring the treatment standards
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for methyl ethyl ketone in U159 nonwastewater to methyl ethyl ketone in
K086 nonwastewater. The treatment standards for nonwastewaters
containing methyl ethyl ketone and methyl isobutyl ketone are 36 mg/kg
and 33 mg/kg, respectively. These standards are presented in Table 7-1.
Detailed information on the treatment performance data and methodology
used to calculate the treatment standards can be found in the U159
(methyl ethyl ketone) and U161 (methyl isobutyl ketone) background
documents.
The data available for methyl ethyl ketone-containing wastewaters
were compiled from the NPDES data base, WERL data base, literature
PACT® and WAO data, and EPA WAO test data. These data are presented
in Appendix A. The promulgated BOAT standard was set using biological
treatment and an achievable effluent of 50 ppb. The treatment standard
for methyl ethyl ketone-containing wastewaters is 0.28 mg/1. The data
available for methyl isobutyl ketone-containing wastewaters were compiled
from the WERL and NPDES data bases, BDAT Solvent Rule data, and EPA WAO
test data. The promulgated BDAT standard was set using biological
treatment and an achievable effluent of 50 ppb. The treatment standard
for methyl isobutyl ketone wastewaters is 0.14 mg/1 as shown in Table 7-1.
For promulgated wastewater standards for both methyl ethyl ketone and
methyl isobutyl ketone, the leachate treatment performance data were
given priority and used as BDAT because they showed substantial treatment
for a constituent that showed average leachate effluent values greater
than those used in setting the proposed standards.
7.1.8 Methylene Chloride, 1,1,1-Trichloroethane, and Trichloroethylene
The Agency is proposing treatment standards for methylene chloride,
1,1,1-trichloroethane, and trichloroethylene in U080, U226, and U228 in
conjunction with the regulation of halogenated aliphatic U-wastes (USEPA
1989f).
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The treatment standards for nonwastewaters containing methylene
chloride, 1,1,1-trichloroethane, and trichloroethylene are based on
examination of performance data and detection limits of many incinerator
ashes and scrubber waters resulting from treatment of wastes containing
halogenated aliphatics. The Agency is transferring the standards for
U080, U226, and U228 to K086. Thus for K086 nonwastewaters, the proposed
standards are 33 mg/kg, 5.6 mg/kg, and 5.6 mg/kg for methylene chloride,
1,1,1-trichloroethane, and trichloroethylene, respectively. These
standards are presented in Table 7-1.
Although methylene chloride is a common laboratory contaminant at
very low levels, the Agency believes that good laboratory practices can
reduce the presence of methylene chloride to a few parts per billion in
the blank. The Agency has also reviewed its own data for the 14
incinerator burns and believes that a laboratory can achieve good
recovery for this constituent. Therefore, the Agency is promulgating a
concentration-based standard of 33 mg/kg. This standard was revised when
EPA reevaluated the recovery factor used to calculate the standard. The
proposed standard was based on an average recovery factor from several of
the spiked constituents, whereas the revised standard is based on the
recovery factor from a single constituent.
For wastewaters containing methylene chloride, 1,1,1-trichloroethane,
and trichloroethylene, data available included the ITD and WERL data
bases, BDAT Solvents Rule data, and literature WAO and PACT® data.
The treatment performance data available from the ITD data base were used
for setting the promulgated treatment standards for these three
constituents. The BDAT for all three constituents is steam stripping.
The treatment standards for wastewater forms of methylene chloride,
1,1,1-trichloroethane, and trichloroethylene are presented in Table 7-1,
For K086 wastewaters, the treatment standards are 0.089 mg/1, 0.054 mg/1,
and 0.054 mg/1 for methylene chloride, 1,1,1-trichloroethane, and
trichloroethylene, respectively.
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7.2 Semivolatile Oreanics
The Agency is proposing to regulate the following semivolatile
organics in K086 treatment residuals:
Acetophenone Dimethylphthalate
Bis(2-ethylhexyl)phthalate Di-n-butylphthalate
Butyl benzyl phthalate Di-n-octylphthalate
Cyclohexanone Naphthalene
1,2-Dichlorobenzene Nitrobenzene
Diethylphthalate
Acetophenone (U004) is being regulated as part of the oxygenated
hydrocarbon treatability group (USEPA 1989d). The Agency is transferring
the standard for U004 to this K086 constituent. Additional detection
limit data received presented detection limits for acetophenone that were
1.4 to 8.6 mg/kg for five laboratories and 15.9 rag/kg for one
laboratory. The detection limits for EPA's data ranged from 0.19 to
2.0 mg/kg. Therefore, EPA believes that laboratories can analyze this
constituent at levels below the revised nonwastewater treatment standard
of 9.7 mg/kg. This standard was revised when EPA reevaluated the
recovery factor used to calculate the standard. The proposed standard
was based on an average recovery factor from several of the spiked
constituents, whereas the revised standard is based on the recovery
factor from a single constituent. Thus the treatment standard for this
K086 nonwastewater is 9.7 mg/kg acetophenone as shown in Table 7-2.
The data available for wastewaters containing acetophenone were
compiled from the NPDES database and leachate treatment performance data
and are presented in Appendix A. The promulgated BOAT standard was set
using biological treatment and an achievable effluent of 2.9 ppb. The
treatment standard for K086 wastewaters containing acetophenone is
0.010 mg/1 as shown in Table 7-2.
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Phthalate U-wastes were regulated as part of the Agency's Second
Third rulemaking. Background data and explanations for the phthalate
treatment standards were contained in the background document for
phthalate waste (USEPA 1989g). The Agency proposes to transfer the
standards for the phthalate U-wastes to the regulated phthalates in
K086. The U- or K- waste counterparts to each phthalate are
bis(2-ethylhexyl)phthalate (U028), butylbenzyl phthalate (K019), diethyl
phthalate (U088), dimethyl phthalate (U102), di-n-butyl phthalate (U069),
and di-n-octyl phthalate (U107). Thus the promulgated standards for
bis(2-ethylhexyl)phthalate, diethyl phthalate, dimethyl phthalate,
di-n-butyl phthalate, and di-n-octyl phalate are 28 mg/kg in K086
nonwastewaters and are presented in Table 7-2. The promulgated treatment
standard for butylbenzylphthalate is 7.9 mg/1 as shown in Table 7-2.
Detailed information on the treatment performance data and methodology
used to calculate the treatment standards can be found in the respective
U- or K- waste background documents.
For wastewaters containing phthalate U-wastes, three sources of
wastewater treatment performance data were available for
bis(2-ethylhexyl)phthalate, diethyl phthalate, dimethyl phthalate,
di-n-butyl phthalate, and di-n-octyl phthalate. These are the ITD and
WERL data bases and literature WAO and PACT® data presented in
Appendix A. The ITD data were used for setting the BOAT standards
presented in Table 7-2. The BOAT for these constituents is biological
treatment.
For wastewaters containing butyl benzyl phthalate, data were compiled
from the NPDES and WERL data bases and literature PACT® data. These
data are presented in Appendix A. The promulgated BDAT standard was set
using biological treatment (e.g., activated sludge) and an achievable
effluent of 3 ppb. The treatment standard for wastewaters containing
butyl benzyl phthalate is 0.017 mg/1 as shown in Table 7-2.
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Table 7-2 BOAT Treatment Standards for
K086 Semivolatile Organic Constituents
Maximum (single grab samples)
Nonwastewater Wastewater
Constituent Total concentration Total concentration
(mg/kg) (mg/1)
Acetophenone 9.7 0.10
Cyc1ohexanone [a] 0.36
1,2-Dichlorobenzene 6.2 0.088
[a] At this time, EPA is withdrawing this constituent from the list of
regulated constituents in K086 nonwastewaters.
Maximum (composite samples)
Nonwastewater Wastewater
Constituent Total concentration Total concentration
(mg/kg) (mg/1)
Bis(2-ethylhexyl)phthalate
Butylbenzylphthalate
Diethyl phthalate
Dimethyl phthalate
Di-n-butyl phthalate
Di-n-octyl phthalate
Naphthalene
Nitrobenzene
28
7.9
28
28
28
28
3.1
14
0.28
0.017
0.20
0.047
0.057
0.017
0.059
0.068
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For nonwastewaters containing cyclohexanone, the Agency has
determined that a concentration-based treatment standard cannot be
supported for this constituent. Data submitted by a commenter
representing the hazardous waste treatment industry for nonwastewater
forms of cyclohexanone reported such drastic detection limit
discrepancies or extreme recoveries that EPA believes these analytes
belong in the category of those constituents not amenable to
quantification. Therefore, the Agency is promulgating a treatment
standard based on a method of treatment. This method of treatment is
incineration.
For wastewaters containing cyclohexanone, no treatment performance
data were available from any of the examined sources. Treatment
performance data were therefore transferred to this constituent from
methyl ethyl ketone. The data are presented in Appendix A. Using a
transfer from this constituent results in a BOAT of biological treatment
and a wastewater treatment standard of 0.36 mg/1 as shown in Table 7-2.
In conjunction with the proposed rulemaking for Third Third wastes,
the Agency is proposing standards for 1,2-dichlorobenzene-, napthalene-,
and nitrobenzene-containing U-wastes (U020, U165, and U169,
respectively). Documentation for the treatment standards for these
wastes can be found in their respective background documents (USEPA
1989h, USEPA 1989i, USEPA 1989J). The Agency proposes to transfer the
standards for U020, U165, and U169 to K086 wastes. Thus the proposed
treatment standards for K086 nonwastewaters are 6.2 mg/kg,
1,2-dichlorobenzene, 3.1 mg/kg naphthalene, and 14 mg/kg nitrobenzene.
For naphthalene-containing nonwastewaters, EPA reevaluated the data
supporting this constituent. The detection limits ranged from 0.11 to
2 mg/kg. Additional data presented detection limits ranging from 0.18 to
0.34 for five laboratories and 5.7 for a sixth laboratory. Based on
these data, the Agency believes that detection limits below 3 mg/kg are
achievable. Therefore, the Agency is promulgating a standard of
7-15
3593g
-------
3.1 mg/kg for nonwastewaters containing naphthalene. This standard is
based on the data from the incineration of K019. Treatment standards for
the constituents listed above are presented in Table 7-2.
For wastewaters containing 1,2-dichlorobenzene, the data available
were compiled from the WERL data base, BDAT Solvents Rule data, and
literature WAO data. These data are presented in Appendix A. The
promulgated treatment standard was set using biological treatment and an
achievable effluent of 16 ppb. The wastewater treatment standard for
1,2-dichlorobenzene is 0.088 mg/1 as shown in Table 7-2.
For wastewaters containing naphthalene, data were compiled from the
ITD and WERL data bases as well as literature from WAO data. These data
are presented in Appendix A. The BDAT for naphthalene wastewaters is
biological treatment, and the treatment standard is 0.059 mg/1 as shown
in Table 7-2.
For wastewaters containing nitrobenzene, data were compiled from the
ITD, BDAT, and WERL data bases, BDAT Solvents Rule data, and literature
WAO data and are presented in Appendix A. The BDAT for this constituent
is steam stripping followed by activated carbon. The treatment standard
for wastewaters containing nitrobenzene is 0.068 mg/1 and is shown in
Table 7-2.
7.3 Metals
The Agency believes that the standards for metals given in the K086
solvent wash background document are applicable to all forms of K086
wastes. The Agency recognizes that as-generated K086 wastes may have
different compositions (see Table 2-1). Consequently, different
as-generated K086 wastes may require different pretreatment steps prior
to application of chromium reduction/lime precipitation/stabilization
steps. Suitable pretreatment, e.g., by incineration to destroy organics
7-16
3593g
-------
and cyanide, would lead to feeds to the chromium reduction/lime
precipitation/stabilization steps that are similar with respect to
chromium and lead, regardless of the initial compositions of the
as-generated K086 wastes. Thus, the Agency is retaining the K086 solvent
wash metals standards and making them applicable to all forms of K086
wastes. For nonwastewaters, the standards are 0.094 mg/1 chromium and
0.37 mg/1 lead in the TCLP leachate; for wastewaters the standards are
0.32 mg/1 chromium and 0.037 mg/1 lead. The treatment standards
presented above are presented in Table 7-3.
7.4 Cyanide
For cyanide in K086, the Agency is proposing standards based on
previously promulgated standards for F010 (USEPA 1989k). These standards
are 1.5 mg/kg cyanide for nonwastewaters and 1.9 mg/1 cyanide for
wastewaters; the standards are presented in Table 7-3.
7-17
3S93s
-------
Table 7-3 BOAT Treatment Standards for
K086 Metals and Cyanide
Nonwastewater Nonwastewater Wastewater
Total concentration Total concentration
Constituent (mg/kg) TCLP (mg/1) (mg/1)
Chromium (total) N/A 0.094 0.32
Lead N/A 0.37 0.037
Cyanide 1.5 N/A 1.9
7-18
3593g
-------
8. REFERENCES
References for this addendum are as follows:
Acurex. 1986. Characterization of hazardous waste incineration
residuals. Van Buren, D., Poe, G. and Carlo Castaldini, Acurex Final
Report FR-86-102/EE, EPA Contract No. 68-03-3241. Mountain View,
California: Acurex Corporation.
Flick, E.W. 1985. Printing ink formulations. 1985. Park Ridge, New
Jersey: Noyes Publications.
Leach, R.H., Armstrong, C., Brown, J.F., Mackenzie, M.J., Randall, L.,
and Smith, H.G. (eds.). 1988. The printing ink manual. 4th ed. ISBN
0-7476-0000-7. London: Van Nostrand Reinhold (International) Co. Ltd.
Hazardous Waste Treatment Council. 1990. Public comment and data
submitted in response to EPA proposed land disposal restrictions Third
Third scheduled wastes. January 1990. EPA RCRA Docket
No. LD12-00032. Washington, D.C.: U.S. Environmental Protection
Agency.
NAPIM. 1988. National Association of Printing Ink Manufacturers, Inc.
Printing ink handbook. 5th ed. Compiled by Product and Technical
Committees, National Association of Printing Ink Manufacturers, Inc.
Harrison, New York: National Association of Printing Inc.
Manufacturers, Inc.
USEPA. 1980. U.S. Environmental Protection Agency. RCRA listing
background document waste code K086. Washington, D.C.: U.S.
Environmental Protection Agency.
USEPA. 1986. U.S. Environmental Protection Agency, Office of Solid
Waste and Emergency Response. Test methods for evaluating solid
waste. SW-846 Third Edition. Washington D.C.: U.S. Environmental
Protection Agency.
USEPA. 1988a. U.S. Environmental Protection Agency. Final best
demonstrated available technology (BOAT) background document for K086
solvent wash. (EPA/530-SW-88-031N). Washington, D.C.: U.S.
Environmental Protection Agency.
USEPA. 1988b. U.S. Environmental Protection Agency. Final onsite
engineering report of treatment technology performance and operation
for Rollins Environmental Services (TX) Inc., Deer Park, Texas.
Washington, D.C.: U.S. Environmental Protection Agency.
8-1
3594
-------
USEPA. 1988c. U.S. Environmental Protection Agency. Onsite engineering
report of treatment technology performance and operation for Millipore
Corporation Bedford Massachusetts. Final draft. Washington, D.C.:
U.S. Environmental Protection Agency.
USEPA. 1988d. U.S. Environmental Protection Agency. Draft onsite
engineering report of treatment technology performance and operation
for wet air oxidation of F007 at Zimpro/Passavant, Inc., in Rothschild,
Wisconsin. Washington, D.C.: U.S. Environmental Protection Agency.
USEPA. 1989a. U.S. Environmental Protection Agency. Proposed best
demonstrated available technology (BOAT) background document for
oxygenated hydrocarbons and others. Washington, D.C.: U.S.
Environmental Protection Agency.
USEPA. 1989b. U.S. Environmental Protection Agency. Best demonstrated
available technology (BDAT) background document for methodology.
Washington, D.C.: U.S. Environmental Protection Agency.
USEPA. 1989c. U.S. Environmental Protection Agency. Draft K086
characterization report for Croda Inks Corporation, St. Louis,
Missouri. Cincinnati, Ohio: U.S. Environmental Protection Agency.
USEPA. 1989d. U.S. Environmental Protection Agency. Proposed best
demonstrated available technology (BDAT) background document for
oxygenated functional groups and oxygenated heterocyclic U and P
wastes. Washington, D.C., U.S. Environmental Protection Agency.
USEPA. 1989e. U.S. Environmental Protection Agency. Proposed best
demonstrated available technology (BDAT) background document for
non-halogenated aromatic U-wastes. Washington, D.C. U.S.
Environmental Protection Agency.
USEPA. 1989f. U.S. Environmental Protection Agency. Proposed best
demonstrated available technology (BDAT) background document for
halogenated aliphatic U-wastes. Washington, D.C. U.S. Environmental
Protection Agency.
USEPA. 1989g. U.S. Environmental Protection Agency. Final best
demonstrated available technology (BDAT) background document for
phthalate wastes. Washington, D.C. U.S. Environmental Protection
Agency.
USEPA. 1989h. U.S. Environmental Protection Agency. Proposed best
demonstrated available technology (BDAT) background document for
chlorobenzenes and other wastes. Washington, D.C. U.S. Environmental
Protection Agency.
8-2
3594
-------
USEPA. 19891. U.S. Environmental Protection Agency. Proposed best
demonstrated available technology (BOAT) background document for
polynuclear aromatic wastes. Washington, D.C. U.S. Environmental
Protection Agency.
USEPA. 1989J. U.S. Environmental Protection Agency. Proposed best
demonstrated available technology (BDAT) background document for
nitrogen-containing organic wastes. Washington, D.C. U.S.
Environmental Protection Agency.
USEPA. 1989k. U.S. Environmental Protection Agency. Final best
demonstrated available technology (BDAT) background document for
cyanides. Washington, D.C. U.S. Environmental Protection Agency.
USEPA. 1990a. U.S. Environmental Protection Agency. Best demonstrated
available technology (BDAT) background document for U and P wastes and
multi-source leachates, Volume A. Washington, D.C.: U.S.
Environmental Protection Agency.
USEPA. 1990b. U.S. Environmental Protection Agency. Best demonstrated
available technology (BDAT) background document for U and P wastes and
multi-source leachates, Volume C. Washington, D.C.: U.S.
Environmental Protection Agency.
Versar. 1988a. Laboratory report, solvent wash sludge. Project
939.91.8-3. Versar Inc., Springfield, Virginia. (CBI).
Versar. 1988b. Summary of limited telephone survey concerning K086
caustic washes handling and treatment. Memorandum dated March 1, 1988,
from P. Redmond (Versar) to J. Labiosa (EPA).
Versar. 1988c. K086 washwater composition data. Memorandum dated
February 5, 1988, from S. Schwartz (Versar) to J. Labiosa (EPA).
Versar. 1988d. Waste characterization data for K086 wastewaters.
Memorandum dated February 3, 1988, from P. Redmond (Versar) to
J. Labiosa (EPA).
Versar. 1989. File memos dated May 8, 1989, documenting telephone
conversations with approximately 35 ink formulators.
8-3
3594
-------
APPENDIX A
-------
WASTEKATER TREATMENT PERFORMANCE DATA
FOR ACETONE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (%) (%)
(ppb) (ppb)
AS
AS
• GAC
PACT
PACT
RO
RO
ss
HOX
HOx |B]
Piloc
Full
Full
B«neh
Bench
Full
Full
Pilot
Full
B«nch
NY0084859
NH0001376
MA0000442
NY0107760
CT0001341
AZ0000108
AZ0000108
Azooooioa
MA0000442
NY0081698
NY0107484
241B
1168E
24SB
242E
Zimpro
250B
2SOB
1082E
242E
780
1000-10000
10000-100000
1000-10000
100-1000
233
1000-10000
10000-100000
10000-100000
1000000
1000000
8
10
10
14
23
11
11
11
4
a
16
s
i
i
126.000
620.560
808.000
296.429
420.000
0.846
1.000
1.000
31.000
804.965
1010.780
28.000
1100.000
50.000
20.000
20.000
200.000
5800.000
10000.000
230.000
10000.000
98.5
97.1
95.9
91.4
91
81
78
80
99.99
99.4
••••——•.
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
WERL
WERL
WERL
WERL
WAO
WERL
WERL
WERL
WERL
WERL
INDUSTRY SUBMITTED LEACHATE TREATMENT
PERFORMANCE DATA FOR ACETONE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (%) (%)
(ppb) (ppb)
BT
BT
CWM
CHM
100
100
1900-10000
9133
100
100
97.92
98.91
LEACHATE
LEACHATE
A-l
-------
HASTEHATER TREATMENT PERFORMANCE DATA
FOR n-BUTYL ALCOHOL
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (%) (%)
(ppb) (ppb)
• AS Full 1168E 10000-100000 40.000 99.79 HERL •
TABLE 4-8B
INDUSTRY SUBMITTED LEACHATE TREATMENT PERFORMANCE
DATA FOR n-BUTYL ALCOHOL
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION <%) (%)
(ppb) (ppb)
BT Cm 2000 2800 1 2000 28.57 LEACHATE
A-2
-------
HASTENATER TREATMENT PERFORMANCE DATA
FOR ETHYL ACETATE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (%) (%)
(ppb) (ppb)
• AS Bench 2020 1000-10000 60.000 96.4 HERL •
WOx Pilot Zlapr 130 630000-770000 3 580.000 WAO
A-3
-------
HAS7EHA7ER TREATMENT PERFORMANCE DATA
FOR ETHYL BENZENE
DETECTION RANGE NO. OP AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (%) (%)
(ppb) (ppb)
AL
AL
AL
AL+AS
API+OAF+AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
Pilot
Piloc
Full
Full
Full
Bench
Full
Piloc
Full
Full
Pilot
Full
Full
Full
Bench
Full
Full
Full
Full
Full
Pilot
Full
Full
Full
Full
Full
Full
Full
Pilot
Pilot
Full
Full
Full
Bench
Full
Full
Full
Full
Full
Bench
203A
203A
IB
2330
14B2D
200B
201B
206B
6B
238A
240A
6B
234A
234A
2020
6B
97 SB
IB
975B
IB
241B
IB
IB
IB
IB
6B
IB
975B
203A
RCF2
IB
IB
IB
200B
SB
68
6B
IB
6B
200B
100-1000
100-1000
0-100
1000-10000
10000-100000
100-1000
0-100
0-100
100-1000
0-100
0-100
100-1000
0-100
0-100
10000-100000
1000-10000
1000-10000
0-100
100-1000
0-100
100-1000
0-100
0-100
0-100
0-100
1000-10000
0-100
0-100
100-1000
23SOO
100-1000
100-1000
100-1000
0-100
100-1000
100-1000
100-1000
0-100
10000-100000
100-1000
14
14
4
21
4
6
16
20
3
3
14
24
4
6
4
S
3
5
4
5
3
3
14
6
6
3
4
9
7
IS
29
4
7
12
12.000
27.000
10.000
4.000
3.300
0.700
6.000
0.200
10.000
O.SOO
1.000
10.000
0.200
0.200
80.000
10.000
8.000
9.000
10.000
3.000
S.OOO
S.OOO
1.000
1.000
S.OOO
25.000
3.000
8.000
6.000
366.000
4.000
2.000
1.000
O.SOO
10.000
10.000
10.000
8.000
10.000
0.600
89
76
69
99.93
99.98
99.89
92.8
99.76
98.2
97.2
98.4
94.4
99.14
99.22
99.87
99.47
99.8
90.7
96.4
69
97.6
89
98.1
97.7
79
98.7
95.4
87
94.6
97.5
99.26
99.17
99.5
97.9
98.9
97.4
89
99.97
99.5
WERL
HERL
WERL
WERL
WERL
HERL
WERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HEW.
HERL
HERL
HERL
HERL
WERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
BOAT »
HERL
HERL
WERL
HERL
HERL
HERL
WERL
HERL
HERL
HERL
I ITD Dac* presented in the BOAT Solvent* Rule F001-FOOS Background Document.
A-4
-------
HASTENATER TREATMENT PERFORMANCE DATA
FOR ETHYL BENZENE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (%) (%)
(ppb) (ppb)
1
A.
IS+F11
Airs
Airs
LrS+GAC
BT
BT
BT
BT
BT
BT
BT
BT
BT
BT
BT
BT
BT
BT
CAC
GAC
PACT
PACT
PACT
PACT
RO
RO
RO
ss
TF
TF
TF
TF
OF
NO*
WOx
WOX (B)
WOX [B]
Full
Pilot
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Pilot
Full
Bench
B«neh
Banch
B«nch
Pilot
Pilot
Full
Pilot
Pilot
Pilot
Full
Full
Pilot
Full
Full
B*nch
Baneh
6B
224B
69A
229A
P211
P234
P221
P293
P238
P21S
P242
P244
P257
P202
P230
P299
P2S1
P253
203A
14210
242E
Zlmpro
200B
Zimpro
180A
250B
250B
RCF2
240A
203A
IB
IB
2SOB
Zimpro
242E
1054E
1054E
0-100
0-100
0-100
0-100
12923-80000
10-3850
10-140
2287-3565
220-3350
564-4150
190-553
608
63-3648
96-596
101-3040
22-230
1235-1360
10-144
100-1000
0-100
0-100
185
0-100
21
0-100
0-100
1000-10000
23500
0-100
100-1000
100-1000
0-100
100-1000
50 19000-27000
1000-10000
1000-10000
100000-1000000
15
1
19
7
33
3
2
2
3
2
1
27
20
15
16
3
2
14
1
11
1
5
14
14
4
4
2
10
0
0
1
10
10
10
10
10
10
10
10
12
10
10
10
10
10
73
0
5
1
0
5
0
5
170
206
1
31
11
4
70
3550
21
500
30000
.000
.500
.300
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.100
.000
.000
.400
.000
.020
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
90
91.9
94.1
80
34
37
76
99.5
99.57
76
71
92.9
97
98.4
72
90.8
90.9
59
99.65
94.6
97
WCRL
WERL
HERL
WERL
BOAT
BOAT
BOAT
BOAT
BOAT
BOAT
BOAT
BOAT
BOAT
BOAT
BOAT
BOAT
BOAT
BOAT
HERL
HERL
HERL
HAO
HERL
HAO
HERL
HERL
HERL
BOAT
HERL
HERL
HERL
HERL
HERL
HAO
HERL
HERL
HERL
I ITD data pr«i»nt»d in the BOAT Solvents Rul* F001-F005 Background Document.
A-5
-------
HASTEHATER TREATMENT PERFORMANCE DATA
FOR METHANOL
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (%) (!)
(ppb) (ppb)
• PACT
ss
HOX
HOC
Bench
Pilot
Full
Bench
Zimpro
1082E
242E
780
208000
1000000
1000000
1000000
1 10.000
230000.000
210000.000
290000.000
99.99
84
89.6
91
MAO •
HERL
HERL
HERL
INDUSTRY SUBMITTED LEACKATE TREATMENT PERFORMANCE
DATA FOR METHANOL
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (%) (%)
(ppb) (ppb)
BT
CHM
2000
7600-31000
2000.000
87.23 LEACHATE
A-6
-------
TABLE 4-32A
HASTENATER TREATMENT PERFORMANCE DATA
FOR METHYL ETHYL KETONC
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (%) (%)
(ppb) (ppb)
AS
AS
AS
• PACT
• PACT
• PACT
WOx
MO*
HOX * PACT
HO* (B)
WOX [B]
Pilot
Pilot
Pilot
tench
B«nch
Bench
Pilot
Full
Pilot
Bench
Bench
NY0096792
NY0072231
IN0036072
NM0001503
2418
2S2C
2S2C
Zlopro
Zimpro
Zlapro
Zimpro
242E
Zlapro
78D
780
100-1000
100000-1000000
10000-100000
2300
266
300
1000000
100 130000-250000
1000000
100000-1000000
8
10
14
1
S
6
7
1
1
1
3
3.400
39.400
779.360
27000.000
9.000
900.000
500.000
14.000
1.000
0.010
2300.000
100
1000.000
1000.000
96.6
99.7
99
99.39
99.6
99.9
99.9
99.9
99.9
99.9
99.6
NPDES
NPDE5
NPDES
NPDES
HERL
HERL
WERL
WAO •
WAO •
HAO •
HAO
WERL
WAO
WERL
HERL
TABLE 4-32B
INDUSTRY SUBMITTED LEACHATE TREATMENT PERFORMANCE
DATA FOR METHYL ETHYL KETONE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (%) (t)
(ppb) (ppb)
BT
BT
am
cm
100
100
2000-19000
-7067
100.000
100.000
98.78
98.58
LEACHATE
LEACHATE
A-7
-------
HASTEHATER TREATMENT PERFORMANCE DATA
FOR METHYL ISOBUTYL KETONE
DETECTION RANGE NO. OP AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (%) (%)
(ppb) (ppb)
AS
AS
RO
• S3
HO*
HOB » PACT
Pilot
Pilot
Full
Piloc
Full
Pilot
NH0001S03
REF2
241B
250B
RET2
242E
Zlopro
76400
100-1000
100-1000
76400
100000-1000000
SO 620000-830000
1
6
4
5
3
70900.000
41817.000
6.000
15.000
10.000
S.OOO
50.000
98.1
89.9
99.99
NPDES
BOAT »
HERL
MERL
BOAT * •
HERL
HAO
I ITD data pr«««nt«d in th« BOAT Solvents Rule F001-F005 Background Document.
INDUSTRY SUBMITTED LEACHATE TREATMENT PERFORMANCE
DATA FOR METHYL ISOBUTYL KETONE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (%) (I)
(ppb) (ppb)
BT
BT
BS
CHM
CHM
50
50
1400-7800
-2167
50.000
50.000
98.61
97.69
LEACHATE
LEACHATC
A-8
-------
MASTEHATER TREATMENT PERFORMANCE DATA
FOR METHYLENE CHLORIDE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (%) (%)
(ppb) (ppb)
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS+Fil
Airs
Airs
AirS+GAC
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Bench
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Pilot
Full
Full
Full
Full
Pilot
Full
Full
Full
Full
Full
Full
Full
Piloc
Pilot
Full
IB
IB
IB
234A
201B
975B
IB
IB
IB
IB
68
IB
238A
234*
202D
37SE
6B
IB
68
IB
6B
IB
ia
6B
IB
206B
1168E
234A
IB
IB
241B
375E
IB
375E
IB
IB
375E
6B
20SE
1362E
229A
0-100
0-100
0-100
0-100
0-100
0-100
0-100
100-1000
100-1000
0-100
0-100
0-100
0-100
0-100
100000-1000000
0-100
1000-10000
0-100
1000-10000
0-100
1000-10000
0-100
1000-10000
0-100
100-1000
100-1000
10000-100000
100-1000
10000-100000
0-100
100-1000
0-100
0-100
1000-10000
1000-10000
0-100
0-100
0-100
100-1000
100-1000
100-1000
3
3
4
27
3
6
6
4
3
4
3
7
40
s
10
3
3
6
s
10
s
20
5
4
S
7
6
7
5
S
7
9
3
19
23.000
17.000
31.000
2.000
45.000
0.430
9.000
46.000
130.000
23.000
10.000
61.000
11.000
4.900
510.000
10.000
54.000
16.000
31.000
23.000
1C. 000
17.000
56.000
13.000
560.000
4.000
920.000
0.800
12000.000
17.000
110.000
5.000
61.000
55.000
2000.000
62.000
20.000
29.000
3.000
5.300
1.000
64
72
31
93.3
51
92
75
69
54
57
77
34
78
56
. 99.72
69
98.6
72
99.53
74
99.74
77
97.8
79
31
96.6
98.4
99.5
14
64
78
80
34
99.3
S
35
64
26
99.6
99
99.8
HER!
HERL
HERL
HERL
WERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
WERL
HERL
A-9
-------
HASTENATER TREATMENT PERFORMANCE DATA
FOR METHYLENE CHLORIDE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (%) (%)
(ppta) (ppb)
BT
BT
BT+AC
CACtAiTS
GAC
GAC
PACT
PACT
RO
RO
• ss
* ss
• ss
ss
ss
ss
ss
ss
ss
ss
TF
TF
TF
TF
TF
TF
TF
TF
TF
HOX
WOx
WOX
WOx
Full
Full
Full
Full
Full
Full
Bench
Bench
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Pilot
Piloc
Full
P246
P265
P246
18330
245B
237A
242E
Zlapro
250B
2SOB
725
913
4 1ST
6B
2S1B
251B
6B
P12003
68
P284
IB
37SE
IB
IB
IB
IB
IB
37SE
IB
REF10
Zlapro
780
242E
27-3907
500-750
10-5550
0-100
100-1000
100-1000
0-100
84
100-1000
10000-100000
10 10-5100
10 200-10400
10 198-12100
1000-10000
1000-10000
1000000
1000-10000
225000-12000000
100-1000
198-12100
0-100
0-100
0-100
0-100
0-100
100-1000
100-1000
100-1000
100-1000
15000-3600000
60000
10-100
100000-1000000
13
3
28
25
1
1
1
13
14
15
15
10
10
9
40
2
15
5
7
3
5
5
6
4
7
5
3
1
11.000
27.000
10.000
2.400
10.000
10.000
20.000
20.000
80.000
15000.000
217.300
10.000
10.500
10.000
10.000
11.000
78.000
24413.000
10.000
10.000
20.000
12.000
23.000
58.000
21.000
16.000
120.000
21.000
37.000
5000.000
10.000
10.000
84.000
92.3
99
94.4
76
76
66
44
99.52
99.17
100
95.1
99
67
8
36
40
77
89
56
88
66
99.9
99.98
99.99
BOAT »
BOAT 1
BOAT »
HERL
HERL
WERL
HERL
UAO
WERL
WERL
ITD-L •
ITD-L •
ITD-L •
WERL
WERL
HERL
WERL
BOAT *
WERL
BOAT *
WERL
WERL
WERL
WERL
WERL
HERL
HERL
HERL
WERL
BOAT »
WAO
WERL
WCRL
I ITD data presented in the BOAT Solvent* Rule F001-F005 Background Document.
A-10
-------
NASTENATER TREATMENT PERFORMANCE DATA
FOR TOLUENE
TECHNOLOGY
AL
AL
AL
ALtAS
API+DAF*AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
TECHNOLOGY
SIZE
Full
Baneh
Full
Full
Full
B«nch
Full
Full
Full
Full
8«nch
Full
Full
Full
Full
Full
Full
Full
Full
Pilot
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Pilot
DETECTION RANGE
FACILITY LIMIT INFLUENT
(ppb) CONCENTRATION
(ppb)
SB
37 ID
IB
2330
1482D
2020
68
6B
975B
6B
200B
6B
IB
6B
6B
97 SB
6B
97SB
6B
226B
6B
6B
IB
97SB
IB
234A
IB
1S87E
201B
IB
IB
234A
IB
IB
238A
6B
IB
IB
241B
100-1000
1000-10000
100-1000
1000-10000
10000-100000
10000-100000
10000-100000
1000-10000
1000-10000
10000-100000
100-1000
1000-10000
1000-10000
1000-10000
1000-10000
1000-10000
1000-10000
100-1000
1000-10000
100000-1000000
100-1000
100-1000
0-100
100-1000
100-1000
0-100
0-100
0-100
100-1000
100-1000
0-100
0-100
100-1000
0-100
0-100
100-1000
0-100
0-100
100-1000
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (%) (%)
(ppb)
3
6
21
4
3
3
3
10
24
6
IS
3
7
33
7
14
4
5
6
4
32
S
4
4
5
3
3
5
4
5
10.000
90.000
32.000
4.000
11.000
10.000
73.000
10.000
12.000
76.000
0.800
10.000
9.000
10.000
24.000
280.000
10.000
23.000
20.000
300.000
10.000
10.000
4.000
7.600
4.000
0.700
3.000
0.100
57.000
12.000
1.000
0.200
4.000
2.000
6.200
10.000
2.000
4.000
4.000
98.2
97
96.1
99.8S
99.93
99.98
99.84
99.57
99.68
99.90
99.3
99.73
99.81
99.88
99.76
96.3
99.5
86
99.8
99. 8S
97.8
97.6
88
99.04
99.48
97.1
90.6
99
87
96.8
98
96.2
96.4
97.6
92.7
94.4
97.1
86
98.6
REFERENCE
WERL
WERL
WERL
WERL
WERL
WERL
WERl
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
A-11
-------
WASTEHATER TREATMENT PERFORMANCE DATA
FOR TOLUENE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (%) (%)
(ppb) (ppb)
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS » Fll
Airs
Airs
Airs
Airs
Airs
Airs
Airs
Airs
AlrS+GAC
BT
BT
BT
BT
BT
BT
BT
BT
BT
BT
BT
BT
BT
BT
BT
BT
BT
Full
Full
Full
Full
Full
Full
Full
Full
Plloc
Full
Full
Full
Pilot
Full
Full
Pilot
Bench
Full
Full
Pilot
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
234A
IB
IB
IB
IB
234A
IB
IB
206B
IB
234A
IB
REF2
6B
322B
1362E
132BE
69A
322B
224B
322B
322B
22 9A
P206
P211
P202
P244
P210
P223
P217
P234
P242
P221
P208
P240
P246
P2S1
P2S3
P257
P26S
0-100
0-100
100-1000
0-100
0-100
0-100
0-100
100-1000
100-1000
100-1000
100-1000
100-1000
92000
10000-100000
100-1000
0-100
10000-100000
0-100
0-100
0-100
1000-10000
10000-100000
0-100
834-57475
1154-4000
60-155
1109
135-5805
99-265
34400-60000
2350-35000
1200-1533
10-323
140-640
22700
77-12938
15840-26060
66-230
1730-12900
37750-50000
5
6
6
5
6
5
20
6
6
6
3
24
3
5
5
1
6
3
19
10
7
20
1
2
3
3
32
2
3
14
1
9
3
3
27
3
0
3
20
1
1
0
2
56
0
10
0
31
23467
10
0
1
2800
0
2
0
34
114
1
1491
10
10
10
10
10
73
21
10
10
10
10
630
10
103
12
10
.200
.000
.000
.000
.000
.200
.000
.000
.600
.000
.200
.000
.000
.000
.660
.700
.000
.940
.000
.500
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
96.
94
89
97.
97.
97.
96.
93.
99.
96.
99.
95.
99.
99.
95.
92.
97
97.
98.
99.
99.
90
9
3
4
7
3
8
76
4
9
4
98
77
3
4
4
9
18
33
WERL
HERL
WERL
HERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
BDAT
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
BDAT
BOAT
BDAT
BDAT
BDAT
BOAT
BDAT
3DAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BOAT
BDAT
BDAT
t
I ITD data pr«§«nc»d in th» BDAT Solvent* Rule F001-F005 Background Document.
A-12
-------
HASTENATER TREATMENT PERFORMANCE DATA
FOR TOLUENE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (») (%)
(ppb) (ppb)
BT
BT
BT
BT
BT+AC
CAC
GAC
CAC
PACT
PACT
PACT
PACT
RO
RO
RO
• ss
ss
ss
• ss
ss
ss
SS+AC
TF
TF
TF
TF
TF
TF
UF
WOX
HOx
WO*
WOK
NOx
KOK
HO*
WOX
WOx
WOX
WOX
WOX
FuU
Full
Full
Full
Full
Pilot
Full
Pilot
Bench
Bench
Bench
Bench
Full
Pilot
Full
Full
Full
Pilot
Full
Full
Full
Full
Full
Full
Full
Full
Pilot
Bench
Bench
Pilot
Full
Full
Pilot
Pilot
Bench
Bench
Bench
Bench
P286
P21S
P230
REF4
P246
43SB
24SB
REF7
200B
242E
Zlapro
Ziapro
2SOB
2SOB
2SOB
0415" 10
6B
6B
0415* 10
REF4
P246
P297
6B
IB
IB
IB
IB
IB
2 SOB
REF10
Zlapro
Zimpro
Zimpro
Ziapro SO
242E
780
Ziapro 5
78D
78D
10S4E
10S4E
24000-160000
3300-4550
3503-30347
680
77-12938
10000-100000
10000-100000
120
100-1000
0-100
2730
57
100-1000
0-100
1000-10000
19300-29000
1000-10000
10000-100000
2570-4230
92000
57-98
640-8650
100-1000
0-100
0-100
0-100
0-100
100-1000
100-1000
8500000
4330000
SOOO
30000
62000-82000
100-1000
10000-100000
130000-180000
1000-10000
10000-100000
10000-100000
1000000
3
3
15
1
10
1
1
13
1
1
3
2
3
4
5
4
3
3
5
6
5
6
4
1
1
1
1
2
3
76.000
10.000
10.000
4.000
113.000
10.000
10.000
0.300
0.300
5.000
1.000
5.000
20.000
12.000
420.000
12.000
10.000
12.000
22.300
42.000
10.000
11.000
10.000
10.000
7.000
2.000
1.000
7.000
84.000
200000.000
12000.000
500.000
500.000
10950.000
57.000
500.000
5.000
500.000
1000.000
500.000
220000.000
99.96
99.94
99.75
91.2
99.9
91
92.5
86
94.7
99.71
99.95
96.3
88
86
97.2
98.2
97.8
35
99.7
90
98.3
72
98.3
99.9
90
98.8
98.9
95.7
BOAT
BOAT
BOAT
BOAT
BOAT
WERL
WERL
BOAT t
WERL
WERL
WAO
WAO
WERL
WERL
WERL
ITD-L
WERL
WERL
ITD-L
BOAT t
BOAT I
BOAT t
. WERL
WERL
WERL
WERL
WERL
WERL
WERL
BOAT 1
WAO
WAO
WAO
WAO
WERL
WERL
WAO
WERL
WERL
WERL
WERL
I ITD dac* presented in the BDAT Solvents Rule F001-F005 Background Document.
A-13
-------
HASTEWATER TREATMENT PERTORMANCE DATA
FOR 1,1,1-TRICHLOROETHANE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (%) (%)
(ppb) (ppb)
AL
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Pilot
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Pilot
Full
Full
Full
Banch
Pilot
Pilot
IB
201B
IB
234A
IB
IB
IB
IB
IB
6B
375E
IB
975B
234A
20GB
IB
IB
IB
IB
IB
234A
238A
234A
IB
238A
1S87E
IB
375E
IB
IB
IB
241B
IB
IB
234A
202D
REF6
REF2
0-100
0-100
0-100000
1000-10000
1000-10000
0-100
0-100
0-100
100-1000
100-1000
0-100
0-100
100-1000
0-100
100-1000
100-1000
100-1000
0-100
0-100
100-1000
0-100
0-100
0-100
0-100
0-100
100-1000
100-1000
0-100
0-100
0-100
0-100
100-1000
0-100
0-100
0-100
100000-1000000
237
150000
5
6
4
6
5
4
s
6
3
7
4
20
5
6
6
4
6
3
3
3
S
7
3
3
3
S
5
3
1
6
10.000
21.000
10.000
1.300
890.000
9.000
10.000
10.000
12.000
10.000
1.000
12.000
4.000
1.000
0.300
54.000
5.000
30.000
5.000
28.000
1.300
2.200
1.300
2.000
2.900
0.270
100.000
1.000
7.000
8.000
2.000
8.000
1.000
4.000
1.300
1600.000
23.000
48683.000
90
79
89
99.88
87
84
84
81
90
98.9
92.3
87
98.1
97.6
. 99.77
89
96.2
39
95
94.3
76
85
73
95.8
77
99.73
70
92.3
83
84
95. 8
97.2
98.4
88
88
98.6
WER1
HERL
WERL
WERL
WERL
HERL
WERL
HERL
HERL
WERL
HERL
HERL
WERL
HERL
WERL
HERL
HERL
HERL
HERL
WERL
WERL
HERL
WERL
WERL
WERL
HERL
HERL
HERL
WERL
WERL
HERL
WERL
WERL
WERL
HERL
HERL
3DAT 1
BOAT »
t ITS d»t* pr«»«nt»d In th« BOAT Solvant* Rule F001-F005 Background Document.
A-14
-------
MASTEWATER TREATMENT PERFORMANCE DATA
FOR 1,1,1-TRICHLORO ETHANE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (%) (t)
(ppb) (ppb)
AirS
Airs
Airs
AlrS
Airs
Airs
Airs
Airs
Airs
Airs
Airs
Airs
BT
GAC
SAC
GAC
GAC
PACT
PACT
PACT
RO
RO
RO
RO
S3
• S3
SS
TF
TF
TF
TF
UV (8)
HOx
WOx
WOx
Pilot
Pilot
Pilot
Pilot
Pilot
Pilot
Pilot
Pilot
Pilot
Pilot
Full
Pilot
Full
Bench
Full
Full
Pilot
Bench
Bench
Bench
Pilot
Full
Pilot
Full
Full
Full
PilOC
Full
Full
Full
Full
Bench
Full
Full
211B
207B
812C
222B
B12E
211B
1362E
812E
2178
20SE
1344E
219B
P240
1362E
1264B
1264B
812E
242C
Zimpro
Zimpro
180A
2 SOB
323B
250B
6B
913
REF2
375E
IB
IB
IB
1138E
RCF10
Zimpro
242E
0-100
0-100
1000-10000
100-1000
0-100
100-1000
1000-10000
100-1000
0-100
100-1000
100-1000
0-100
10-215
10-100
0-100
100-1000
100-1000
100-1000
4970
405
0-100
100-1000
0-100
100-1000
10000-100000
10 11900-35000
150000
0-100
0-100
100-1000
0-100
0-100
370000
SO 6900-9600
100000-1000000
1
1
1
1
3
1
1
3
1
1
1
14
5
7
5
6
5
1
2
1.000
0.500
49.000
1.100
3.000
1.700
130.000
12.000
0.300
7.000
0.200
0.500
10.000
1.000
1.000
1.000
1.000
25.000
1.000
25.000
0.050
36.000
2.000
10.000
10.000
10.000
463.000
1.000
2.000
2.000
5.000
30.000
1000.000
400.000
98.8
97.5
95.9
99.75
92.9
99.5
97.8
89
97
96.8
99.98
96.7
99.99
96.6
99.35
99.05
93.8
99.9
93.8
98.2
95.6
97.8
93.8
99.94
50
92.6
98.3
92.2
40
99.96
WERL
HERL
WERL
WERL
HERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
BOAT »
WERL
WERL
WERL
WERL
WERL
WAO
WAO
WERL
WERL
WERL
WERL
WERL
ITD-L
BOAT »
WERL
WERL
WERL
WERL
WERL
BOAT 1
WAO
WERL
t ITO data presented in the BOAT Solvent* Rule F001-F005 Background Document.
A-15
-------
HASTENATCR TREATMENT PERFORMANCE DATA
FOR TRICHLOROCTHCNE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION <%) (%)
(ppb) (ppb)
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
Airs
AizS
Airs
Airs
Airs
Airs
B«nch
Full
Full
Full
Full
Full
Full
Pilot
Full
Full
Pilot
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Pilot
Pilot
Full
Pilot
Pilot
Pilot
2020
IB
IB
6B
1S87C
375E
IB
206B
238A
IB
241B
IB
234A
201B
IB
IB
68
238A
234A
IB
IB
IB
IB
IB
1362E
209B
199B
26A
216B
219B
10000-100000
0-100
100-1000
100-1000
0-100
0-100
0-100
100-1000
0-100
100-1000
100-1000
100-1000
0-100
0-100
0-100
0-100
0-100
0-100
0-100
100-1000
100-1000
0-100
100-1000
0-100
1000-10000
100-1000
100-1000
100-1000
100-1000
100-1000
4
6
3
7
6
20
3
4
5
6
6
6
5
5
3
5
6
4
6
5
3
1
1
1
210.000
5.000
2.000
10.000
0.100
2.SOO
1.000
l.SOO
2.100
3.000
7.000
£4.000
0.700
13.000
2.000
1.000
10.000
O.SOO
0.700
31.000
87.000
4.000
37.000
16.000
1.000
0.800
1.500
27.000
2.100
0.500
99.78
89
99.23
94.1
95.7
58
96.7
98.6
90.6
97.3
96.7
87
71
87
97.6
98.5
89
94.8
92.3
74
87
89.7
92.6
72
99.94
99.58
99.75
87
98.9
99.58
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
A-16
-------
WASTENATCR TREATMENT PERFORMANCE DATA
FOR TRICHLOROCTHENE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (%) (%)
(ppb) (ppb)
AirS
Airs
Airs
Airs
Airs
Airs
Airs
Airs
Airs
Airs
Airs
Airs
Airs
Airs
Airs
Airs
Airs
Airs
AirS
Airs
AirS
AirS
AirS
AirS
BT
BT
BT
BT
BT+AC
CAC+AirS
ChOX
Pilot
Pilot
Piiot
Pilot
Pilot
Full
Pilot
Pilot
Full
Full
Pilot
Pilot
Pilot
Pilot
Pilot
Pilot
Full
Pilot
Pilot
Pilot
Full
Pilot
Pilot
Pilot
Full
Full
Full
Full
Full
Full
Pilot
369A
211B
20SE
220B
217B
322B
1327E
212B
223B
69A
369A
2218
isasE
1363E
1327E
211B
1042E
21SB
208B
222B
322B
1585E
7 ID
207B
REF4
P213
P217
P2S3
P246
1833D
2026A
0-100
100-1000
0-100
100-1000
100-1000
100-1000
1000-10000
0-100
0-100
0-100
0-100
0-100
0-100
100-1000
0-100
1000-10000
0-100
0-100
0-100
0-100
1000-10000
1000-10000
100-1000
0-100
60
16-76
96-224
484
40-70
0-100
0-100
1
1
1
10
1
1
1
1
1
1
1
1
7
1
1
1
1
3
3
1
3
20
4
0.300
3.100
1.000
0.200
1.200
0.460
190.000
0.400
0.500
1.400
3.000
O.SOO
4.300
S.OOO
4.300
7.700
0.300
0.500
0.700
0.300
11.000
170.000
5.000
0.500
5.800
10.000
10.000
16.000
10.000
0.200
3.700
99.44
98.6
97.2
99.92
99.69
99.91
91.3
99.6
98.2
98.1
93.2
99.44
87
97.1
. 87
99.3
99.68
98
99.03
99. n
99.77
84
98.5
98.7
90
96.2
WERL
WERL
WERL
WERL
WERL
HERL
WERL
HERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
BOAT 1
BOAT »
BOAT »
BOAT »
BOAT »
WERL
WERL
» ITD data pr«i«nt»d in th« BOAT Solvent! Rul« F001-F005 Background Document.
A-17
-------
WA5TCWATER TREATMENT PERFORMANCE DATA
FOR TRICHLOROETHENE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (%) (%)
(ppb) (ppb)
ChOx
Chred
Chred
Chred
CAC
GAC
GAC
GAC
CAC
GAC
GAC
PACT
PACT
PACT
PACT
RO
RO
RO
• ss
ss
ss
ss
ss
• ss
ss
TF
TF
TF
TF
TF
UV (B]
HOX
HOX
WOx [B]
Pilot
Piloc
Bench
Bench
Full
Full
Full
Full
Full
Full
Pilot
Bench
Bench
Bench
Bench
Full
Full
Pilot
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Bench
Bench
Bench
Bench
2026A
1264B
1264B
245B
1264B
24SB
237A
RCF8
242E
Zlmpro
Zlmpro
Zlapro
2SOB
2 SOB
323B
415
2S1B
6B
6B
251B
913
P284
IB
IB
IB
IB
IB
1138E
Zimpro
Zlmpro
780
100-1000
200
260
300
100-1000
0-100
100-1000
0-100
1000-10000
100-1000
171
0-100
326
90
32.8
100-1000
0-100
0-100
10 59-10300
1000-10000
1000-10000
10000-100000
1000-10000
10 22900-52700
10-10300
0-100
100-1000
0-100
0-100
0-100
0-100
500000
300000
100000-1000000
1
1
1
1
1
1
1
1
1
1
1
15
10
14
2
10
14
15
6
5
5
5
6
1
1
7.100
5.000
3.900
0.400
1.000
1.000
10.000
1.300
10.000
10.000
0.590
10.000
1.000
10.000
0.005
110.000
5.500
68.000
16.100
5.000
16.000
10.000
10.000
10.000
16.000
1.000
1.000
1.000
1.000
5.000
22.000
1700.000
2000.000
1700.000
94.4
99.36
98.8
97.8
98.6
99.46
95.8
89
99.7
89
99.98
78
79
30
99.91
99.20
99.97
99.79
98.8
99.33
98.5
98.4
93.2
56
99.7
99.3
99.66
HERL
ART
ART
ART
HERL
HERL
HERL
HERL
HERL
HERL
BOAT »
HERL
WAO
HAO
HAO
HERL
HERL
HERL
ITD-L '
HERL
HERL
HERL
HERL
ITD-L '
BOAT t
HERL
HERL
HERL
HERL
HERL
HERL
HAO
WAO
HERL
t ITD data presented In the BOAT Solvents Rule F001-F005 Background Document.
A-18
-------
HASTENATER TREATMENT PERFORMANCE DATA
TOR 1,2-XYLENE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (%) (»)
(ppb) (ppb)
AS
AS
Airs
PACT
PACT
RO
• MO*
Full
Bench
Pilot
Bench
Bench
Full
Full
NY0183628
1587E
200B
224B
242E
Zlnpro
2 SOB
242E
0-100
100-1000
0-100
0-100
79
10000-100000
10000-100000
3
IS
1
1
198.330
0.100
0.900
O.SOO
S.OOO
s.ooo
300.000
79.000
98.6
99.2
93
93.7
94
97.8
99.92
NPDES
HERL
HERL
HERL
HER!
WAO
HERL
HERL •
MASTENATER TREATMENT PERFORMANCE DATA
FOR 1,3-XYLENE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (%) (%)
(ppb) (ppb)
AS
Airs
GAC
PACT
PACT
• HO*
Full
Pilot
Full
Bench
Bench
Full
NY0183628
1587E
2248
14210
242E
Zimpro
242E
3
0-100
0-100 1
0-100
0-100
33 1
10000-100000
193.330
0.100
0.500
.0.130
10.000
10.000
33.000
98.3
72
20
70
70
99.7
NPOES
HERL
HERL
HERL
HERL
MAO
HERL •
HASTENATER TREATMENT PERFORMANCE DATA
FOR 1,4-XYLENE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (%) (%)
(ppb) (ppb)
Airs
OAC
Pilot
Full
NY0183628
224B
1421D
0-100
0-100
198.330
0.500
0.040
90
37
NPDES
HERL
HERL
A-19
-------
NASTEHATER TREATMENT PERFORMANCE DATA
FOR XYLENE
DETECTION RANGE NO. or AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (%) (%)
(ppb) (ppb)
GAC
WO*
WOK
Pilot
Pilot
REF7
REF10
Zlapro
140
21200
8385000
1
1
1
0.100
500.000
20000.000
99.8
BOAT »
BOAT »
WAO
» ITO data pr«««nt»d in ch« BOAT Solvvnci Rul» F001-F005 Background Document.
A-20
-------
NASTCMATCR TREATMENT PERTORMANCt DATA
TOR ACETOPHENONE
OCTCCTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (%) (%)
(ppb)
NH0001S71 32 10361.560 NPDES
INDUSTRY SUBMITTED LCACHATC TREATMENT PERFORMANCE
DATA FOR ACETOPHENONE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (%) (%)
(ppb) (ppb)
BT CIM 2.9 35 1 2.900 91.71 LEACHATE
A-21
-------
NASTEKATER TREATMENT PERFORMANCE DATA
FOR BIS(2-ETHYLHEXYL)PHTHALATE
TECHNOLOGY
AL
AL
AL
AL
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
CAC
• BT
PACT
PACT
RO
TF
TF
TF
TF
TF
TF
TF
HOX
HOx
HO* IB)
DETECTION RANGE
TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCENTRATION
(ppb)
Pilot
Full
Bench
Pilot
Full
Full
Full
Pilot
Pilot
Full
Bench
Full
Pilot
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Pilot
Pilot
Full
Full
Bench
Full
Full
Full
Pilot
Full
Bench
Bench
Full
Full
Pilot
Full
Full
Full
Full
Pilot
Full
Full
Bench
203A
IB
3710
203A
IB
IB
IB
24 IB
203A
IB
2020
IB
241B
IB
IB
IB
IB
IB
IB
6B
IB
IB
2018
IB
204A
240A
IB
IB
10SOE
IB
IB
IB
203A
948 10
97SB
Zimpro
2 SOB
IB
203A
IB
IB
IB
IB
240A
Zimpro 2
Zimpro 11
1054E
100-1000
100-1000
1000-10000
100-1000
0-100
0-100
0-100
100-1000
100-1000
0-100
100-1000
0-100
1000-10000
100-1000
0-100
100-1000
0-100
0-100
0-100
1000-10000
0-100
100-1000
0-100
0-100
0-100
100-1000
100-1000
0-100
100-1000
0-100
0-100
100-1000
100-1000
11-11740
100-1000
561
0-100
0-100
100-1000
0-100
0-100
0-100
0-100
100-1000
4800
1800
100000-1000000
NO. Or AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (%) (%)
(ppb)
11
6
11
6
4
4
5
11
6
3
4
6
6
S
5
6
4
37
4
6
3
4
a
10
6
6
5
6
3
6
11
33
1
5
11
5
4
6
S
6
1
1
34.000
73.000
190.000
30.000
8.000
18.000
5.000
7.000
18.000
10.000
60.000
10.000
390.000
90.000
11.000
31.000
9.000
20.000
67.000
47.000
11.000
40.000
S.OOO
16.000
11.000
46.000
48.000
51.000
35.000
10.000
6.000
190.000
15.000
43.300
3.000
2.000
8.000
60.000
39.000
5.000
22.000
26.000
33.000
43.000
10.000
0.000
100.000
80
39
90.5
82
79
47
81
93.7
89
84
77
66
64
59
64
72
67
73
33
97.1
76
86
93.8
70
79
73
63
39
91.2
81
86
57
91.1
99.46
99.6
90
3
77
81
24
32
56
79
99.99
REFERENCE
HERL
HERL
HERL
MERL
MERL
MERL
MERL
MERL
MERL
MERL
HERL
HERL
HERL
MERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
MERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
ITD-L •
HERL
HAD
HERL
HERL
HERL
WERL
HERL
HERL
HERL
HERL
MAO
MAO
HERL
A-22
-------
NASTCNATCR TREATMENT PERFORMANCE DATA
FOR BUTYL BENZYL PHTHALATE
TECHNOLOGY
AS
A3
AS
• AS
AS
AS
AS
BT
BT
PACT
DETECTION RANGE
TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCENTRATION
(ppb)
Piloc
Full
Full
Full
Pilot
Pilot
Full
Full
Full
Baneh
LAOOC5501
NY0199648
NY0032140
NY0032140
PA0022047
NY018362B
LA0066214
204A
IB
IB
IB
241B
241B
IB
PA0026247
LA003B245
Zlmpro
0-100
0-100
0-100
100-1000
0-100
100-1000
0-100
129
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (%) (%)
(ppb)
6
11
2
2
10
4
15
8
3
3
6
5
11
6
25
38
1
10.000
10.730
136.500
58.000
7.000
17.500
5.000
1.300
5.000
2.000
3.000
9.000
12.000
2.000
13.795
10.066
2.000
96.2
91.8
93.8
98.3
82
97
96.7
98.4
REFERENCE
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
HCRL
HERL
WERL
WERL •
HERL
WERL
WERL
NPDES
NPDCS
WAO
A-23
-------
NASTENATER TREATMENT PERFORMANCE DATA
TOR O-OICHLOROBENZENE
TECHNOLOGY
AIT
AL
AL
AL
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AirS
Airs
BGAC
BT
• BT
BT
BT+AC
GAC
GAC
PACT
PACT
PACT
PACT
RBC
RO
RO
WOK
WOK
WOK
TECHNOLOGIC
SIZE
Bench
Pilot
Piloc
Beach
Pull
Full
Piloc
Piloc
Full
Full
Full
Full
Bench
Full
Full
Bench
Piloc
Bench
Full
Full
Bench
Bench
Piloc
Bench
Full
Full
Full
Full
Full
Full
Bench
Bench
Full
Full
Piloc
Piloc
Piloc
Bench
Bench
Piloc
DETECTION
FACILITY LIMIT
(ppb)
501A
192D
1920
3710
IB
6B
1920
1920
6B
IB
IB
6B
200B
IB
1587E
2020
241B
10SOE
37SE
6B
1054E
1328E
222B
501 A
P246
P202
P206
P24C
24SB
1421D
242E
200B
6B
6B
1920
323B
180A
Zl&pro
Zlapro
780
RANGE
INFLUENT
CONCENTRATION
(ppb)
0-100
100-1000
1000-10000
1000-10000
100-1000
1000-10000
1000-10000
100-1000
100-1000
100-1000
0-100
1000-10000
100-1000
100-1000
0-100
10000-100000
100-1000
100-1000
0-100
100-1000
100-1000
10000-100000
0-100
0-100
768-2801
1350-4387
233-2333
7(8-3275
100-1000
0-100
0-100
100-1000
1000-10000
100-1000
100-1000
0-100
0-100
590000
6530000
> 1000000
NO. OF
DATA
POINTS
25
4
3
330
2
3
4
14
5
10
5
7
3
5
1
34
14
4
10
17
1
14
10
4
1
1
1
AVERAGE
EFFLUENT
CONCENTRATION
(ppb)
0.380
10.000
100.000
72.000
6.000
52.000
110.000
270.000
35.000
5.000
2.000
16.000
8.000
10.000
1.200
50.000
25.000
1.600
5.000
10.000
8.000
6200.000
0.500
0.310
596.000
16.000
88.000
176.000
10.000
0.270
5.000
2.900
88.000
64.000
10.000
11.000
0.090
150000.000
2017000.000
29000.000
RECOVERY REMOVAL
(%> («)
96
97.7
94.8
97.6
96
98.5
94.3
37
96.2
96.2
94.3
99.33
92.7
91.7
79
99.94
93.2
99.6
67
92.9
98.4
74
83
96.8
98.9
90
83
97.5
98.5
90
97.7
70
92.5
74.6
69.1
98.7
REFERENCE
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
WERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
BOAT I
BOAT »
BOAT t
BOAT »
HERL
HERL
HERL
HCRL
WERL
HERL
WERL
WERL
WERL
HAD
WAO
WERL
I ITO d*ca presencod in Che BOAT Solvencs Rule F001-FOOS Background Document.
A-24
-------
NASTENATER TREATMENT PERFORMANCE DATA
FOR DIETHYL PHTHALATE
TECHNOLOGY
AS
AS
AS
AS
AS
• BT
PACT
TECHNOLOGY
SIZE
Pilot
Full
Pilot
Full
Full •
Full
Bench
DETECTION
FACILITY LIMIT
(ppb)
204A
6B
241B
IB
IB
948 10
Zlopro
RANGE
INFLUENT
CONCENTRATION
(ppb)
0-100
1000-10000
100-1000
0-100
0-100
14-15000
88
NO. or
DATA
POINTS
8
36
11
4
3
33
1
AVERAGE
EFFLUENT
CONCENTRATION
(ppb)
1.200
28.000
12.000
1.000
3.000
23.500
1.000
RECOVERY REMOVAL
(») (%)
97.4
97.7
97.6
96.7
88
98.9
REFERENCE
NERL
NERL
NERL
NERL
NERL
ITD-L •
NAO
A-25
-------
HASTCNATER TREATMENT PERFORMANCE DATA
FOR DIMETHYL PHTHALATE
TECHNOLOGY
AS
AS
AS
AS
AS
• 8T
PACT
HOx
TECHNOLOGY
SIZE
Full
Full
Pilot
Pilot
Full
Full
Bench
Full
FACILITY
IB
6B
241B
204A
IB
948
Zimpro
Zimpro
DETECTION
LIMIT
(ppb)
10
1
RANGE
INFLUENT
CONCENTRATION
(ppb)
100-1000
100-1000
100-1000
0-100
0-100
10-C25
332
(1000
NO. or
DATA
POINTS
1
16
10
8
1
22
1
1
AVERAGE
EFFLUENT
CONCENTRATION
(ppb)
2.000
20.000
13.000
0.800
30.000
10.000
1.000
0.000
RECOVERY REMOVAL
(») (%)
98.2
92.8
97.7
98.3
12
99.7
REFERENCE
HERL
HERL
HERL
HERL
HERL
ITD-L •
HAD
MAO
A-26
-------
NA5TCNATER TREATMENT PERFORMANCE DATA
FOR DI-n-BUTYL PHTHALATt
TECHNOLOGY
AL
XL
AL
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
CAC
ChOx
• BT
ir
TF
TF
TF
TECHNOLOGY
SIZE
Bench
Pilot
Pilot
Pilot
Full
Full
Full
Full
Full
Full
Pilot
Pilot
Full
Pilot
Bench
Full
Pilot
Bench
Full
Full
Full
Pilot
Pilot
DETECTION
FACILITY LIMIT
(ppb)
3710
203A
203A
240A
IB
97SB
IB
201B
IB
IB
204A
203A
6B
24 IB
10SOE
6B
203A
9758
948 10
IB
IB
203A
240A
RANGE
INFLUENT
CONCENTRATION
(ppb)
100-1000
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
100-1000
100-1000
100-1000
1000-10000
0-100
0-100
19-2000
0-100
0-100
0-100
0-100
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (%) («)
(ppb)
11
11
12
6
4
2
5
3
8
11
31
11
5
6
11
33
5
3
11
11
s.ooo
14.000
44.000
8.000
4.000
3.000
S.OOO
3.000
5.000
10.000
2.700
7.000
13.000
17.000
2.400
30.000
47.000
3.000
13.000
6.000
20.000
52.000
16.000
99.5
81
40
91.4
91.7
87
94.4
93.5
93.8
87
93.9
90.4
96.8
96
99.4
98.7
36
87
92.6
70
29
81
REFERENCE
MERL
HCRL
WERL
NERL
WERL
WERL
HERL
MERL
WERL
WERL
WERL
HERL
WERL
WERL
WERL
HERL
HERL
HERL
ITD-L •
HERL
WERL
WERL
HERL
A-27
-------
NASTENATER TREATMENT PERFORMANCE DATA
FOR DI-n-OCTYL PHTKALATE
TECHNOLOGY
AL
AS
AS
* AS
BT
ChOx
PACT
TECHNOLOGY
SIZE
Bench
Full
Pilot
Full
Full
Bench
Bench
DETECTION
FACILITY LIMIT
(ppb)
MAOOOS304
LA0065501
LA0066214
M30001970
OH0002445
NI0044636
NY0004138
OH0002445
3710
IB
204A
IB
LA003824S
97SB
97 SB
RANGE
INFLUENT
CONCENTRATION
(ppb)
1000-10000
0-100
0-100
100-1000
1000-10000
1000-10000
NO. OF
DATA
POINTS
21
6
IS
1
6
1
5
1
2
8
1
38
AVERAGE
EFFLUENT
CONCENTRATION
(ppb)
9.810
10.000
10.000
110.000
5.717
47000.000
48.000
4.000
48.000
12.000
4.800
3.000
9.961
3CO.OOO
3.000
RECOVERY REMOVAL
(%) (%)
97.6
79
83
98.6
80
99.75
REFERENCE
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
WERL
HERL
WERL
HERL •
NPDES
WERL
WERL
A-28
-------
NASTENATER TREATMENT PERFORMANCE DATA
FOR NAPHTHALENE
TECHNOLOGY
AL
AL
AL
AL
AL
AL+AL
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
Airs
CAC
ChOx
• BT
PACT
RBC
RO
TT
TT
IT
NO*
TECHNOLOGY
SIZE
Pilot
Bench
Pilot
Pilot
Pilot
run
Full
Full
Bench
Pilot
Pilot
Full
Pilot
Bench
Pilot
Pilot
Full
Full
Full
Full
Pilot
Full
Full
Full
Pilot
tench
Pilot
Bench
Full
Bench
Pilot
Pilot
Pilot
Full
Pilot
Full
DETECTION RANGE
FACILITY LIMIT INFLUENT
(ppb) CONCENTRATION
(ppb>
1920
3710
1920
203A
203A
2330
201B
6B
1050E
24 IB
241B
975B
204A
2020
203A
240A
IB
IB
6B
6B
1920
IB
«B
68
1920
1328E
203A
97SB
1293
Zlopro
1920
180A
240A
IB
203A
Zlapro
0-100
100-1000
100-1000
100-1000
100-1000
100-1000
0-100
100-1000
100-1000
100-1000
100-1000
100-1000
0-100
1000-10000
100-1000
100-1000
0-100
100-1000
10000-100000
100-1000
0-100
0-100
1000-10000
100-1000
100-1000
10000-100000
100-1000
0-100
10 11227-37145
191
0-100
0-100
100-1000
0-100
100-1000
6 1200
NO. Or AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (%) (!)
(ppb)
11
11
21
11
2
5
11
5
8
11
12
5
5
14
13
4
7
3
S
11
IS
1
11
6
11
1
10.000
23.000
25.000
13.000
36.000
16.000
5.000
14.000
2.000
8.900
10.000
1.000
0.700
10.000
4.000
6.000
9.000
10.000
10.000
10.000
10.000
3.000
10.000
10.000
25.000
6200.000
79.000
2.000
10.000
1.000
10.000
0.020
14.000
3.000
74.000
210.000
82
97.7
96.5
88
67
98.3
89
95.9
99.5
97.9
93
99.17
99.09
99.86
96.3
95
86
95.4
99.95
99
82
91.9
99.56
96
96.5
74
27
88
99.9
82
80
88
89
32
REFERENCE
NERL
NERL
NERL
NERL
NERL
NERL
HERL
NERL
HERL
NERL
HERL
HERL
HERL
HERL
HERL
HERL
NERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
NERL
NERL
HERL
WERL
IID-L •
HAO
HERL
HERL
HERL
HERL
HERL
HAO
A-29
-------
NASTEMATER TREATMENT PERFORMANCE DATA
TECHNOLOGY
AL
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
Airs
BT
BT+AC
ChOx
U
LI
LL+SS
LL+SS+AC
PACT
PACT
PACT
PACT
SCO*
ss
ss
* S3+AC
• SS+AC
SS+AC
HO*
TECHNOLOGY
SIZE
Bench
full
Full
Full
Bench
Bench
Full
Full
Pilot
Full
Pilot
Bmeh
Full
Full
Bench
Full
Full
Full
Full
Bench
Full
Bench
Bench
Pilot
Full
Full
Full
Full
Full
Bench
FACILITY
3710
975B
68
6B
2020
200B
97SB
6B
241B
IB
24 IB
1328E
P246
P246
975B
K104
K103
K103/K104
K103/K104
190E
6B
97SB
2008
650
P297
P246
500
2680
P297
Zimpro
DETECTION RANGE
LIMIT INFLODR
(ppb) CONCENTRATION
(ppb)
1000-10000
100-1000
1000-10000
10000-100000
10000-100000
100-1000
100>1000
1000-10000
100-1000
100-1000
100-1000
100000-1000000
821-5559
821-90500
0-100
30 2200000-3900000
30 1500000-3000000
30 1500000-3900000
30 1500000-3900000
100-1000
1000-10000
100-1000
100-1000
1000000
87000-330000
91200-1965760
14 14-5460000
14 87000-330000
87000-330000
5125000
NO. or
DATA
POINTS
330
3
16
28
4
1
10
5
14
18
5
5
5
4
4
12
10
15
37
10
10
1
AVERAGE
EFFLUENT
CONCENTRATION
(PP*»
69.000
96.000
120.000
150.000
2200.000
3.000
3.400
14.000
10.000
23.000
32.000
96000.000
737.000
297.000
2.000
2420000.000
2200000.000
2400.000
30.000
21.000
14.000
2.000
3.700
22.000
11793.000
251325.000
520.300
712.600
713.000
255000.000
RECOVERY REMOVAL
(%) (%)
97.7
72
96.1
99.8
97.8
97.5
99.48
99.78
92.3
90
92.8
16
95.9
115
115
115
115
96
98.8
98.3
96.7
99.99
95
REFERENCE
HERL
NERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
BOAT 1
BOAT »
HERL
BOAT
BOAT
BOAT
BOAT
HERL
HERL
HERL
HERL
HERL
BOAT »
BOAT 1
ITD-L •
ITD-L •
3DAT t
HAO
I ITD data presented in the BOAT Solvents Rule F001-FOOS Background Docunent.
A-30
-------
NASTEWATER TREATMENT PERFORMANCE DATA
FOR CHROMIUM (TOTAL)
TECHNOLOGY
AL
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
TECHNOLOGY
SIZE
Pull
Full
Pull
Full
Full
Full
Full
Full
Full
Full .
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
DETECTION RANGE
FACILITY LIMIT INFLUENT
(ppb) CONCENTRATION
(ppb)
IB
234A
IB
167E
IB
IB
234A
IB
167E
IB
2«3A
IB
IB
IB
IB
234A
IB
IB
198E
234A
2 34 A
IB
IB
243A
IB
IB
IB
IB
167E
IB
167E
100-10000
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
100-1000
100-1000
100-1000
100-1000
1000-10000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (%) (%)
(Ppb)
6
7
6
6
7
7
6
6
33
7
7
6
130.000
7.000
29.000
9.000
5.000
22.000
16.000
6.000
3.000
12.000
12.000
36.000
35.000
6.000
11.000
34.000
36.000
24.000
40.000
3.000
14.000
16.000
40.000
28.000
62.000
59.000
19.000
38.000
6.000
16.000
12.000
89.00
84.00
64.00
72.00
90.90
69.00
82.00
85.00
96.10
76.00
83.00
62.00
65.00
89.00
78.00
58.00
64.00
70.00
79.00
94.60
89.00
87.00
76.00
77.00
95.60
86.00
89.00
84.00
98.50
90.00
92.30
REFERENCE
WERL
HERL
WERL
HERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
A-31
-------
HASTENATER TREATMENT PERFORMANCE DATA
FOR CHROMIUM (TOTAL)
DETECTION RANGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCENTRATION
(ppb)
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL REFERENCE
POINTS CONCENTRATION (%) (%)
(ppb)
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
CAC
CAC (B)
ChOx/Pt (B)
ChPt
ChPt (B)
CbPt (B)
chpt+Fii Fll
Fil
L+S*d
• L+S«d»Fil
PACT
PttSad
S*d
S«d+Fll
TT
TF
TF
TF
TF
TF
TF
Full
Pilot
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Bench
Bench
Full
Pilot
Pilot
Pilot
Pilot
Full
Full
Pilot
Full
Full
Pilot
Full
Pilot
Full
Full
Full
Full
Full
Full
Full
Full
IB
1294B
IB
IB
IB
IB
IB
2018
234A
IB
IB
IB
IB
IB
393A
638B
248A
245B
2S4B
2S4B
2S4B
254B
K062
K062
254B
1294B
SO
1294B
IB
IB
IB
IB
IB
IB
IB
100-1000
1000-10000
100-1000
1000-10000
100-1000
1000-10000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
1000-10000
10000-100000
100-1000
10000-100000
10000-100000
100-1000
70-917000
6000-7000000
100-1000
100-116000
100-116000
1000-10000
0-35400
1000-10000
100-116000
100-1000
100-1000
0-100
100-1000
100-1000
100-1000
0-100
6
3
6
6
6
96
6
35
7
7
6
6
6
6
1
1
1
16
14
14
16
9
11
14
3
38
3
6
6
6
6
6
6
6
48.000
390.000
26.000
110.000
52.000
140.000
19.000
51.000
20.000
46.000
28.000
35.000
50.000
19.000
40.000
50.000
0.500
34.000
77.000
170.000
47.000
75.000
57.000
135.000 68.0-
39.000
84.000
70.000
320.000
572.000
1100.000
80.000
57.000
34.000
15.000
92.000
180.000
44.000
17.000
88.00
64.00
80.00
97.40
82.00
90.00
83.00
77.00
82.00
89.00
93.50
68.00
54.00
88.00
94.10
62.00
74.00
99.95
76.00
99.66
99.91
77.00
90.20
71.00
66.00
56.00
69.00
67.00
23.00
25.00
71.00
48.00
MERL
MERL
WERL
MERL
WERL
WERL
MERL
MERL
MERL
MERL
MERL
MERL
MERL
MERL
MERL
MERL
MERL
MERL
MERL
MERL
MERL
MERL
BOAT
BOAT
MERL
ITD-CKDB
ITD-CKDB
MERL
ITD-MF
MERL
ITD-CKDB
MERL
MERL
MERL
MERL
MERL
MERL
MERL
A-32
-------
NASTtMATCR TREATMENT PERFORMANCE DATA
TOR LEAD
DETECTION RANGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCENTRATION
(ppb)
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL REFERENCE
POINTS CONCENTRATION (%) (%)
(ppb)
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
CAC
Chr*d/Pt+S*dtFll
Fil
L+Sad
• L+S«d+ril
PACT
Pt+S«d
S«d
S«d»FU
TF
TF
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Pilot
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Pilot
Full
Full
Pilot
Full
Pilot
Full
Full
Full
IB
IB
IB
201B
167E
167E
234A
IB
167E
234A
IB
167E
234A
IB
243A
201B
234A
1294B
IB
IB
IB
198E
IB
243A
IB
234A
IB
IB
IB
975B
IB
IB
393A
K062
254B
1294B
100
1294B
IB
IB
100-1000
0-100
0-100
0-100
100-1000
0-100
0-100
0-100
100-1000
0-100
1000-10000
0-100
0-100
0-100
0-100
100-1000
0-100
1000-10000
0-100
100-1000
0-100
0-100
100-1000
0-100
100-1000
0-100
0-100
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
10000-212000
100-1000
100-29200
100-29200
1000-10000
0-42300
1000-10000
100-29200
0-100
100-1000
6
6
6
10
7
6
7
6
7
6
6
7
3
6
6
6
33
6
6
7
6
6
6
6
6
11
14
3
44
3
6
6
86.000
20.000
20.000
50.000
16.000
17.000
1.000
50.000
12.000
1.000
59.000
21.000
0.000
20.000
5.400
70.000
1.000
650.000
44.000
25.000
20.000
40.000
70.000
2.200
47.000
1.000
24.000
56.000
30.000
66.000
92.000
53.000
32.000
10.000 76
100.000
120.000
80.000
500.000
200.000
2000.000
30.000
20.000
130.000
57.00
66.00
66.00
34.00
86.00
73.00
98.70
50.00
90.20
98.50
95.10
52.00
98.00
70.00
88.00
50.00
97.80
68.00
52.00
88.00
64.00
50.00
50.00
92.10
75.00
97.80
70.00
57.00
79.00
40.00
23.00
67.00
87.00
63.00
75.00
78.00
75.00
19.00
HERL
HERL
WERL
HERL
WERL
WERL
HERL
HERL
HERL
WERL
WERL
HERL
HERL
HERL
HERL
HERL
HERL
WERL
WERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
BOAT
HERL
ITD-CMDB
ITD-CMDB
HERL
ITD-MF
HERL
ITD-CMDB
HERL
HERL
A-33
-------
HASTEWATER TREATMENT PERFORMANCE DATA
FOR CYANIDE
TECHNOLOGY
XL
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
TECHNOLOGY
SIZE
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
DETECTION RANGE
FACILITY LIMIT INFLUENT
(ppb) CONCENTRATION
(ppb)
IB
IB
IB
IB
IB
IB
IB
201B
IB
167E
IB
IB
IB
IB
IB
IB
160A
IB
167E
IB
IB
IB
201B
167E
IB
167E
IB
IB
160A
0-100
100-1000
100-1000
100-1000
100-1000
100-1000
0-100
0-100
100-1000
0-100
0-100
100-1000
100-1000
100-1000
1000-10000
0-100
100-1000
1000-10000
100-1000
0-100
100-1000
0-100
1000-10000
100-1000
100-1000
100-1000
1000-10000
0-100
0-100
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (%) (%)
(ppb)
6
6
6
6
6
6
t
28
6
6
6
6
6
6
6
60
6
6
6
7
6
6
6
6
60
10.000
10.000
160.000
65.000
320.000
150.000
27.000
90.000
54.000
19.000
5.000
47.000
110.000
110.000
110.000
24.000
79.000
130.000
20.000
41.000
370.000
6.000
110.000
22.000
250.000
110.000
240.000
7.000
8.000
88
91.7
53
59
29
70
«7
0
79
44
SB
88
59
35
97.7
35
55
91.9
88
42
58
65
. 97.7
80
65
64
80
75
91
REFERENCE
HERL
NERL
HERL
NERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
A-34
-------
NASTEHATER TREATMENT PERFORMANCE DATA
TOR CYANIDE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (%) (»)
(ppb) (ppb)
AS
AS
AS
ChOx (CD
ChOx/Pt (B)
ChOx/Pt (B)
• CN/0«
LL+SS
LL+SS+AC
L»Sed
L+Sed+Fil
RBC
ss
TF
TF
TF
IF
TF
TF
NO*
MOX (B)
NOs (B)
Full
Full
Full
Pilot
Bench
Bench
Full
Full
Full
Full
Full
Full
Pilot
Full
Full
Full
Full
Full
Full
Pilot
Bench
Bench
IB
IB
IB
1077B
248A
248A
K103/K104
K103/X104
IB
1082E
IB
IB
IB
IB
. IB
IB
780
10S4E
1054E
1000-10000
100-1000
1000-10000
10000-100000
> 1000000
>1000000
5-20 45-1680000
10-6280
10-6280
120-3280
120-3280
1000-10000
10000-100000
100-1000
100-1000
100-1000
100-1000
0-100
0-100
100000-1000000
10000-100000
>1000000
6
6
6
20
1
1
1529
5
4
6
220.000
87.000
380.000
6700.000
v- 1000.000
100.000
180.00
2960.000 72
362.000 72
70.00
47.00
84.000
39000.000
130.000
47.000
310.000
110.000
17.000
53.000
6000.000
1200.000
170.000
90
64
71
92.4
100
100
95.8
38
65
74
56
59
39
36
98
. 98.7
100
HERL
NERL
MERL
HERL
MERL
HERL
ITD-MF •
BOAT
BOAT
ITD-CMDB
ITD-CMDB
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
A-35
------- |