FINAL
BEST DEMONSTRATED AVAILABLE TECHNOLOGY (BOAT)
BACKGROUND DOCUMENT
FOR
U AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
VOLUME A
WASTEWATER FORMS OF ORGANIC U AND P WASTES AND
MULTI-SOURCE LEACHATE (F039) FOR WHICH THERE ARE
CONCENTRATION-BASED TREATMENT STANDARDS
Richard Kinch
Acting Chief, Waste Treatment Branch
Mary Cunningham
Project Manager
U.S. ENVIRONMENTAL PROTECTION AGENCY
Office of Solid Waste
401 M Street, S.W.
Washington, D.C. 20460
May 1990
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TABLE OF CONTENTS
Page
1.0 INTRODUCTION 1-1
1.1 Regulatory Background 1-1
1.2 User's Guide to the Five-Volume U and P Waste and
Multi-source Leachate Background Document Set 1-3
1.3 Summary of Contents: Volume A 1-4
2.0 INDUSTRY AFFECTED AND WASTE CHARACTERIZATION 2-1
2.1 Industry Affected 2-1
2.1.1 U and P Wastes 2-1
2.1.2 Multi-source Leachate 2-2
2.2 Waste Characterization 2-2
2.3 Determination of Waste Treatability Groups 2-3
3.0 IDENTIFICATION OF THE BEST DEMONSTRATED AVAILABLE
TECHNOLOGY (BOAT) 3-1
3.1 Applicable Treatment Technologies 3-2
3.1.1 Organics 3-2
3.1.2 Inorganics 3-5
3.1.3 Metals 3-6
3.2 Demonstrated Treatment Technologies 3-8
3.3 Identification of Best Demonstrated Available
Technology (BOAT) 3-8
4.0 TREATMENT PERFORMANCE DATABASE 4-1
4.1 Sources of Treatment Data 4-1
4.1.1 BOAT Database 4-1
4.1.2 WAO/PACT" Data 4-3
4.1.3 ITD Database--Promulgated Limits 4-3
4.1.4 NPDES Database 4-4
4.1.5 WERL Database 4-4
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TABLE OF CONTENTS (Continued)
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4.1.6 Leachate Treatment Performance Data 4-5
4.1.7 Other Sources 4-5
4.2 Volatiles 4-13
4.3 Semivolatiles 4-106
4.4 Metals 4-216
4.5 Inorganics 4-253
4.6 Organochlorine Pesticides 4-260
4.7 Phenoxyacetic Acid Herbicides 4-285
4.8 Organophosphorous Insecticides 4-290
4.9 PCBs 4-294
4.10 Dioxins and Furans 4-302
5.0 SELECTION OF REGULATED CONSTITUENTS 5-1
5.1 Constituents Selected for Regulation 5-1
5.2 Multi-source Leachate Constituents Controlled by the
Regulated Multi-source Leachate Constituents 5-2
6.0 CALCULATION OF FINAL WASTEWATER BOAT TREATMENT STANDARDS . . 6-1
6.1 Variability Factors 6-1
6.2 Accuracy Correction Factors 6-2
6.3 Calculatidn of BOAT Treatment Standards 6-3
7.0 ACKNOWLEDGEMENTS . 7-1
8.0 REFERENCES 8-1
APPENDIX A - Industry Characterization A-l
APPENDIX B - U and P Wastes Arranged by Third Third
Treatability Groups B-l
APPENDIX C - Method Detection Limits C-l
ii
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LIST OF TABLES
Page
1-1 TREATMENT STANDARDS FOR U AND P WASTES AND MULTI-SOURCE
LEACHATE (F039) INCLUDED IN VOLUMES A, B, AND C; BY WASTE
CODE 1-6
1-2 TREATMENT STANDARDS FOR U AND P WASTES AND MULTI-SOURCE
LEACHATE (F039) INCLUDED IN VOLUMES A, B, AND C;
ALPHABETICALLY 1-12
1-3 BOAT TREATMENT STANDARDS FOR ORGANIC CONSTITUENTS IN U AND
P WASTEWATERS 1-23
1-4 BOAT TREATMENT STANDARDS FOR MULTI-SOURCE LEACHATE (P039)
WASTEWATERS 1-26
4-1A WASTEWATER TREATMENT PERFORMANCE DATA FOR ACETONE 4-15
4-IB INDUSTRY-SUBMITTED LEACHATE TREATMENT PERFORMANCE DATA FOR
ACETONE 4-15
4-2 WASTEWATER TREATMENT PERFORMANCE DATA FOR ACETONITRILE . . . 4-17
4-3 WASTEWATER TREATMENT PERFORMANCE DATA FOR ACROLEIN 4-17
4-4 WASTEWATER TREATMENT PERFORMANCE DATA FOR ACRYLONITRILE ... 4-19
4-5 WASTEWATER TREATMENT PERFORMANCE DATA FOR BENZENE 4-21
iii
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LIST OF TABLES (CONTINUED)
4-6 WASTEWATER TREATMENT PERFORMANCE DATA FOR
BROMODICHLOROMETHANE 4-24
4-7 WASTEWATER TREATMENT PERFORMANCE DATA FOR BROMOMETHANE ... 4-25
4-8A WASTEWATER TREATMENT PERFORMANCE DATA FOR n-BUTYL ALCOHOL . . 4-27
4-8B INDUSTRY-SUBMITTED LEACHATE TREATMENT PERFORMANCE DATA FOR
n-BUTYL ALCOHOL 4-27
4-9 WASTEWATER TREATMENT PERFORMANCE DATA FOR CARBON
TETRACHLORIDE 4-29
4-10A WASTEWATER TREATMENT PERFORMANCE DATA FOR CARBON DISULFIDE . 4-30
4-10B INDUSTRY-SUBMITTED LEACHATE TREATMENT PERFORMANCE DATA FOR
CARBON DISULFIDE 4-30
4-11 WASTEWATER TREATMENT PERFORMANCE DATA FOR CHLOROBENZENE . . . 4-32
4-12 WASTEWATER TREATMENT PERFORMANCE DATA FOR
CHLORODIBROMOMETHANE 4-35
4-13 WASTEWATER TREATMENT PERFORMANCE DATA FOR CHLOROETHANE ... 4-35
4-14 THIS TABLE HAS BEEN DELETED
4-15 WASTEWATER TREATMENT PERFORMANCE DATA FOR CHLOROFORM .... 4-37
4-16 WASTEWATER TREATMENT PERFORMANCE DATA FOR CHLOROMETHANE ... 4-40
iv
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LIST OF TABLES (CONTINUED)
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4-17 WASTEWATER TREATMENT PERFORMANCE DATA FOR 1,2-DIBROMOETHANE . 4-42
4-18 WASTEWATER TREATMENT PERFORMANCE DATA FOR
DICHLORODIFLUOROMETHANE 4-44
4-19 WASTEWATER TREATMENT PERFORMANCE DATA FOR 1,1-DICHLOROETHANE 4-46
4-20 WASTEWATER TREATMENT PERFORMANCE DATA FOR 1,2-DICHLOROETHANE 4-48
4-21 WASTEWATER TREATMENT PERFORMANCE DATA FOR
1,1-DICHLOROETHYLENE 4-50
4-22 WASTEWATER TREATMENT PERFORMANCE DATA FOR TRANS-1,2-
DICHLOROETHYLENE 4-52
4-23 WASTEWATER TREATMENT PERFORMANCE DATA FOR 1,2-DICHLOROPROPANE 4-53
4-24 WASTEWATER TREATMENT PERFORMANCE DATA FOR CIS/TRANS
1,3-DICHLOROPROPENE 4-55
4-25 WASTEWATER TREATMENT PERFORMANCE DATA FOR 1,4-DIOXANE .... 4-56
4-26 WASTEWATER TREATMENT PERFORMANCE DATA FOR ETHYL ACETATE . . . 4-57
4-27 WASTEWATER TREATMENT PERFORMANCE DATA FOR ETHYL BENZENE ... 4-59
4-28 WASTEWATER TREATMENT PERFORMANCE DATA FOR ETHYL CYANIDE . . . 4-61
4-29 WASTEWATER TREATMENT PERFORMANCE DATA FOR ETHYL ETHER .... 4-62
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LIST OF TABLES (CONTINUED)
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4-30 INDUSTRY-SUBMITTED LEACHATE TREATMENT PERFORMANCE DATA FOR
ISOBUTYL ALCOHOL 4-67
4-31A WASTEWATER TREATMENT PERFORMANCE DATA FOR METHANOL 4-67
4-31B INDUSTRY-SUBMITTED LEACHATE TREATMENT PERFORMANCE DATA FOR
METHANOL 4-67
4-32A WASTEWATER TREATMENT PERFORMANCE DATA FOR METHYL ETHYL
KETONE 4-69
4-32B INDUSTRY-SUBMITTED LEACHATE TREATMENT PERFORMANCE DATA FOR
METHYL ETHYL KETONE 4-69
4-33A WASTEWATER TREATMENT PERFORMANCE DATA FOR METHYL ISOBUTYL
KETONE 4-71
4-33B INDUSTRY-SUBMITTED LEACHATE TREATMENT PERFORMANCE DATA FOR
METHYL ISOBUTYL KETONE 4-71
4-34 WASTEWATER TREATMENT PERFORMANCE DATA FOR METHACRYLONITRILE . 4-73
4-35 WASTEWATER TREATMENT PERFORMANCE DATA FOR METHYLENE CHLORIDE 4-75
4-36 WASTEWATER TREATMENT PERFORMANCE DATA FOR PYRIDINE 4-78
4-37 WASTEWATER TREATMENT PERFORMANCE DATA FOR 1,1,1,2-
TETRACHLOROETHANE 4-78
VI
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LIST OF TABLES (CONTINUED)
4-38 WASTEWATER TREATMENT PERFORMANCE DATA FOR 1,1,2,2-
TETRACHLOROETHANE 4-79
4-39 WASTEWATER TREATMENT PERFORMANCE DATA FOR TETRACHLOROETHENE . 4-81
4-40 WASTEWATER TREATMENT PERFORMANCE DATA FOR TOLUENE 4-84
4-41 WASTEWATER TREATMENT PERFORMANCE DATA FOR TRIBROMOMETHANE . . 4-87
4-42 WASTEWATER TREATMENT PERFORMANCE DATA FOR 1,1,1-
TRICHLOROETHANE . 4-89
4-43 WASTEWATER TREATMENT PERFORMANCE DATA FOR 1,1,2-
TRICHLOROETHANE 4-92
4-44 WASTEWATER TREATMENT PERFORMANCE DATA FOR TRICHLOROETHENE . . 4-94
4-45 WASTEWATER TREATMENT PERFORMANCE DATA FOR
TRICHLOROMONOFLUOROMETHANE 4-98
4-46 WASTEWATER TREATMENT PERFORMANCE DATA FOR 1,1,2-TRICHLORO-
1,2,2-TRIFLUOROETHANE 4-100
4-47 WASTEWATER TREATMENT PERFORMANCE DATA FOR VINYL CHLORIDE . . 4-102
4-48 WASTEWATER TREATMENT PERFORMANCE DATA FOR 1,2-XYLENE .... 4-104
4-49 WASTEWATER TREATMENT PERFORMANCE DATA FOR 1,3-XYLENE .... 4-104
4-50 WASTEWATER TREATMENT PERFORMANCE DATA FOR 1,4-XYLENE .... 4-104
vii
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LIST OF TABLES (CONTINUED)
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4-51 WASTEWATER TREATMENT PERFORMANCE DATA FOR XYLENE 4-105
4-52 WASTEWATER TREATMENT PERFORMANCE DATA FOR ACENAPHTHALENE . . 4-107
4-53 WASTEWATER TREATMENT PERFORMANCE DATA FOR ACENAPHTHENE ... 4-109
4-54A WASTEWATER TREATMENT PERFORMANCE DATA FOR ACETOPHENONE ... 4-110
4-54B INDUSTRY-SUBMITTED LEACHATE TREATMENT PERFORMANCE DATA FOR
ACETOPHENONE 4-110
4-55 WASTEWATER TREATMENT PERFORMANCE DATA FOR ANILINE 4-113
4-56 WASTEWATER TREATMENT PERFORMANCE DATA FOR ANTHRACENE .... 4-114
4-57 WASTEWATER TREATMENT PERFORMANCE DATA BOR BENZ(A)ANTHRACENE . 4-116
4-58 WASTEWATER TREATMENT PERFORMANCE DATA FOR BENZO(A)PYRENE . . 4-118
4-59 WASTEWATER TREATMENT PERFORMANCE DATA FOR
BENZO(B)FLUORANTHENE 4-119
4-60 WASTEWATER TREATMENT PERFORMANCE DATA FOR BENZO(GHI)PERYLENE 4-120
4-61 WASTEWATER TREATMENT PERFORMANCE DATA FOR
BENZO(K)FLUORANTHENE 4-121
4-62A WASTEWATER TREATMENT PERFORMANCE DATA FOR
BIS(2-CHLOROETHOXY)METHANE 4-123
viii
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LIST OF TABLES (CONTINUED)
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4-62B INDUSTRY-SUBMITTED TREATMENT PERFORMANCE DATA FOR
BIS(2-CHLOROETHOXY)METHANE 4-123
4-63 WASTEWATER TREATMENT PERFORMANCE DATA FOR
BIS(2-CHLOROETHYL)ETHER 4-124
4-64 WASTEWATER TREATMENT PERFORMANCE DATA FOR
BIS(2-CHLOROISOPROPYL)ETHER 4-125
4-65 WASTEWATER TREATMENT PERFORMANCE DATA FOR
BIS(2-ETHYLHEXYL)PHTHALATE 4-127
4-66 WASTEWATER TREATMENT PERFORMANCE DATA FOR 4-BROMOPHENYL
PHENYL ETHER 4-128
4-67 WASTEWATER TREATMENT PERFORMANCE DATA FOR BUTYL BENZYL
PHTHALATE 4-130
4-68 WASTEWATER TREATMENT PERFORMANCE DATA FOR 2-SEC-BUTYL-4,6-
DINITROPHENOL 4-130
4-69 WASTEWATER TREATMENT PERFORMANCE DATA FOR p-CHLORANILINE . . 4-131
4-70 WASTEWATER TREATMENT PERFORMANCE DATA FOR p-CHLORO-m-CRESOL . 4-134
4-71 WASTEWATER TREATMENT PERFORMANCE DATA FOR 2-CHLORONAPHTHALENE 4-134
4-72 WASTEWATER TREATMENT PERFORMANCE DATA FOR 2-CHLOROPHENOL . . 4-135
IX
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LIST OF TABLES (CONTINUED)
Paee
4-73 WASTEWATER TREATMENT PERFORMANCE DATA FOR CHRYSENE 4-136
4-74 WASTEWATER TREATMENT PERFORMANCE DATA FOR ORTHO-CRESOL . . . 4-137
4-75 WASTEWATER TREATMENT PERFORMANCE DATA FOR PARA-CRESOL .... 4-138
4-76 WASTEWATER TREATMENT PERFORMANCE DATA FOR
DIBENZ(A,H)ANTHRACENE 4-140
4-77A WASTEWATER TREATMENT PERFORMANCE DATA FOR m-DICHLOROBENZENE . 4-143
4-77B INDUSTRY-SUBMITTED TREATMENT PERFORMANCE DATA FOR
m-DICHLOROBENZENE 4-143
4-78 WASTEWATER TREATMENT PERFORMANCE DATA FOR o-DICHLOROBENZENE . 4-145
4-79 WASTEWATER TREATMENT PERFORMANCE DATA FOR p-DICHLOROEBENZENE 4-147
4-80 THIS TABLE HAS BEEN DELETED
4-81 WASTEWATER TREATMENT PERFORMANCE DATA FOR 2,4-DICHLOROPHENOL 4-148
4-82 WASTEWATER TREATMENT PERFORMANCE DATA FOR DIETHYL PHTHALATE . 4-150
4-83 WASTEWATER TREATMENT PERFORMANCE DATA FOR 2,4-DIMETHYLPHENOL 4-152
4-84 WASTEWATER TREATMENT PERFORMANCE DATA FOR DIMETHYL PHTHALATE 4-153
4-85 WASTEWATER TREATMENT PERFORMANCE DATA FOR Dl-n-BUTYL
PHTHALATE 4-155
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LIST OF TABLES (CONTINUED)
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4-86 WASTEWATER TREATMENT PERFORMANCE DATA FOR 4,6-DINITRO-o-
CRESOL 4-158
4-87 WASTEWATER TREATMENT PERFORMANCE DATA FOR 2,4-DINITROPHENOL . 4-160
4-88 WASTEWATER TREATMENT PERFORMANCE DATA FOR 2,4-DINITROTOLUENE 4-161
4-89 WASTEWATER TREATMENT PERFORMANCE DATA FOR 2,6-DINITROTOLUENE 4-162
4-90 WASTEWATER TREATMENT PERFORMANCE DATA FOR DI-n-OCTYL
PHTHALATE 4-163
4-91 WASTEWATER TREATMENT PERFORMANCE DATA FOR
1,2-DIPHENYLHYDRAZINE 4-166
4-92 WASTEWATER TREATMENT PERFORMANCE DATA FOR FLUORANTHENE . . . 4-168
4-93 WASTEWATER TREATMENT PERFORMANCE DATA FOR FLUORENE 4-169
4-94 WASTEWATER TREATMENT PERFORMANCE DATA FOR HEXACHLOROBENZENE . 4-171
4-95 WASTEWATER TREATMENT PERFORMANCE DATA FOR
HEXACHLOROBUTADIENE 4-171
4-96 WASTEWATER TREATMENT PERFORMANCE DATA FOR
HEXACHLOROCYCLOPENTADIENE 4-171A
4-97 WASTEWATER TREATMENT PERFORMANCE DATA FOR HEXACHLOROETHENE . 4-172
xi
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_ LIST OF TABLES (CONTINUED)
Page
4-98 WASTEWATER TREATMENT PERFORMANCE DATA FOR INDENO(1,2,3-
CD)PYRENE 4-174
4-99 WASTEWATER TREATMENT PERFORMANCE DATA FOR 4,4'-
METHYLENEBIS(2-CHLOROANILINE) 4-177
4-100 WASTEWATER TREATMENT PERFORMANCE DATA FOR NAPHTHALENE .... 4-180
4-101 WASTEWATER TREATMENT PERFORMANCE DATA FOR 2-NAPHTHYLAMINE . . 4-181
4-102 WASTEWATER TREATMENT PERFORMANCE DATA FOR p-NITROANILINE . . 4-182
4-103 WASTEWATER TREATMENT PERFORMANCE DATA FOR NITROBENOZENE . . . 4-184
4-104 WASTEWATER TREATMENT PERFORMANCE DATA FOR 4-NITROPHENOL . . . 4-186
4-105 WASTEWATER TREATMENT PERFORMANCE DATA FOR N-
NITROSODIMETHYLAMINE 4-188.
4-106 WASTEWATER TREATMENT PERFORMANCE DATA FOR PENTACHLOROPHENOL . 4-195
4-107 WASTEWATER TREATMENT PERFORMANCE DATA FOR PHENACETIN .... 4-197
4-108 WASTEWATER TREATMENT PERFORMANCE DATA FOR PHENANTHRENE . . . 4-199
4-109A WASTEWATER TREATMENT PERFORMANCE DATA FOR PHENOL 4-201
4-109B INDUSTRY-SUBMITTED LEACHATE TREATMENT PERFORMANCE DATA
FOR PHENOL 4-202
xii
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LIST OF TABLES (CONTINUED)
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4-109C INDUSTRY-SUBMITTED LEACHATE TREATMENT PERFORMANCE DATA
FOR PHTHALIC ANHYDRIDE 4-203
4-110 WASTEWATER TREATMENT PERFORMANCE DATA FOR PRONAMIDE 4-204
4-111 WASTEWATER TREATMENT PERFORMANCE DATA FOR PYRENE 4-206
4-112 THIS TABLE HAS BEEN DELETED
4-113 WASTEWATER TREATMENT PERFORMANCE DATA FOR 1,2,4,5-
TETRACHLOROBENZENE 4-208
4-114 WASTEWATER TREATMENT PERFORMANCE DATA FOR 2,3,4,6-
TETRACHLOROPHENOL 4-209
4-115 WASTEWATER TREATMENT PERFORMANCE DATA FOR 1,2,4-
TRICHLOROBENZENE 4-210
4-116A WASTEWATER TREATMENT PERFORMANCE DATA FOR 2,4,5-
TRICHLOROPHENOL 4-212
4-116B INDUSTRY-SUBMITTED TREATMENT PERFORMANCE DATA FOR 2,4,5-
TRICHLOROPHENOL 4-212
4-117A WASTEWATER TREATMENT PERFORMANCE DATA FOR 2,4,6-
TRICHLOROPHENOL 4-214
4-117B INDUSTRY-SUBMITTED TREATMENT PERFORMANCE DATA FOR 2,4,6-
TRICHLOROPHENOL 4-214
xiii
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LIST OF TABLES (CONTINUED)
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4-118 WASTEWATER TREATMENT PERFORMANCE DATA FOR ANTIMONY 4-218
4-119 WASTEWATER TREATMENT PERFORMANCE DATA FOR ARSENIC 4-220
4-120 WASTEWATER TREATMENT PERFORMANCE DATA FOR BARIUM 4-222
4-121 WASTEWATER TREATMENT PERFORMANCE DATA FOR BERYLLIUM 4-224
4-122 WASTEWATER TREATMENT PERFORMANCE DATA FOR CADMIUM 4-226
4-123 WASTEWATER TREATMENT PERFORMANCE DATA FOR CHROMIUM (TOTAL) . 4-228
4-124 WASTEWATER TREATMENT PERFORMANCE DATA FOR COPPER 4-231
4-125 WASTEWATER TREATMENT PERFORMANCE DATA FOR LEAD 4-234
4-126 WASTEWATER TREATMENT PERFORMANCE DATA FOR MERCURY 4-236
4-127 WASTEWATER TREATMENT PERFORMANCE DATA FOR NICKEL 4-238
4-128 WASTEWATER TREATMENT PERFORMANCE DATA FOR SELENIUM 4-241
4-129 WASTEWATER TREATMENT PERFORMANCE DATA FOR SILVER 4-243
4-130 WASTEWATER TREATMENT PERFORMANCE DATA FOR THALLIUM 4-245
4-131 WASTEWATER TREATMENT PERFORMANCE DATA FOR VANADIUM 4-248
4-132 WASTEWATER TREATMENT PERFORMANCE DATA FOR ZINC 4-251
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LIST OF TABLES (CONTINUED)
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4-133 WASTEWATER TREATMENT PERFORMANCE DATA FOR CYANIDE 4-255
4-134 WASTEWATER TREATMENT PERFORMANCE DATA FOR FLUORIDE 4-258
4-135 WASTEWATER TREATMENT PERFORMANCE DATA FOR SULFIDE 4-259
4-136 WASTEWATER TREATMENT PERFORMANCE DATA FOR ALDRIN 4-261
4-137 WASTEWATER TREATMENT PERFORMANCE DATA FOR ALPHA-BHC . . . . . 4-262
4-138 WASTEWATER TREATMENT PERFORMANCE DATA FOR BETA-BHC 4-263
4-139 WASTEWATER TREATMENT PERFORMANCE DATA FOR DELTA-BHC 4-264
4-140 WASTEWATER TREATMENT PERFORMANCE DATA FOR GAMMA-BHC 4-265
4-141 WASTEWATER TREATMENT PERFORMANCE DATA FOR CHLORDANE 4-267
4-142 WASTEWATER TREATMENT PERFORMANCE DATA FOR DDD 4-268
4-143 WASTEWATER TREATMENT PERFORMANCE DATA FOR DDE 4-269
4-144 WASTEWATER TREATMENT PERFORMANCE DATA FOR DDT 4-271
4-145 WASTEWATER TREATMENT PERFORMANCE DATA FOR DIELDRIN 4-272
4-146 WASTEWATER TREATMENT PERFORMANCE DATA FOR ENDOSULFAN I ... 4-273
4-147 WASTEWATER TREATMENT PERFORMANCE DATA FOR ENDOSULFAN II ... 4-274
xv
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LIST OF TABLES (CONTINUED)
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4-148 WASTEWATER TREATMENT PERFORMANCE DATA FOR ENDRIN 4-277
4-149 WASTEWATER TREATMENT PERFORMANCE DATA FOR ENDRIN ALDEHYDE . . 4-278
4-150 WASTEWATER TREATMENT PERFORMANCE DATA FOR HEPTACHLOR .... 4-279
4-151A WASTEWATER TREATMENT PERFORMANCE DATA FOR HEPTACHLOR
EPOXIDE 4-280
4-151B INDUSTRY-SUBMITTED LEACHATE TREATMENT PERFORMANCE DATA FOR
KEPONE 4-282
4-152 WASTEWATER TREATMENT PERFORMANCE DATA FOR METHOXYCLOR .... 4-283
4-153 WASTEWATER TREATMENT PERFORMANCE DATA FOR TOXAPHENE 4-284
4-154 WASTEWATER TREATMENT PERFORMANCE DATA FOR 2,4-
DICHLOROPHENOXYACETIC ACID 4-287
4-155 WASTEWATER TREATMENT PERFORMANCE DATA FOR SILVEX 4-288
4-156 WASTEWATER TREATMENT PERFORMANCE DATA FOR 2,4,5-T . . ... . . 4-289
4-157 WASTEWATER TREATMENT PERFORMANCE DATA FOR AROCLOR 1016 ... 4-295
4-158 WASTEWATER TREATMENT PERFORMANCE DATA FOR AROCLOR 1221 . . . 4-296
4-159 WASTEWATER TREATMENT PERFORMANCE DATA FOR AROCLOR 1232 . . . 4-297
4-160 WASTEWATER TREATMENT PERFORMANCE DATA FOR AROCLOR 1242 ... 4-298
xvi
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LIST OF TABLES (CONTINUED)
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4-161 WASTEWATER TREATMENT PERFORMANCE DATA FOR AROCLOR 1248
4-299
4-162 WASTEWATER TREATMENT PERFORMANCE DATA FOR AROCLOR 1254
4-300
4-163 WASTEWATER TREATMENT PERFORMANCE DATA FOR AROCLOR 1260
4-301
4-164 WASTEWATER TREATMENT PERFORMANCE DATA FOR
HEXACHLORODIBENZO-p-DIOXINS 4-303
4-165 WASTEWATER TREATMENT PERFORMANCE DATA FOR
HEXACHLORODIBENZOFURANS 4-304
4-166 WASTEWATER TREATMENT PERFORMANCE DATA FOR
PENTACHLORODIBENZO-p-DIOXINS 4-305
4-167A WASTEWATER TREATMENT PERFORMANCE DATA FOR
PENTACHLORODIBENZOFURANS 4-307
4-167B INDUSTRY-SUBMITTED LEACHATE TREATMENT PERFORMANCE DATA FOR
PENTACHLORODIBENZOFURANS 4-307
4-168A WASTEWATER TREATMENT PERFORMANCE DATA FOR
TETRACHLORODIBENZO-p-DIOXINS 4-309
4-168B INDUSTRY-SUBMITTED TREATMENT PERFORMANCE DATA FOR
TETRACHLORODIBENZO-p-DIXOINS 4-309
4-169 WASTEWATER TREATMENT PERFORMANCE DATA FOR
TETRACHLORODIBENZOFURANS 4-310
xvii
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LIST OF TABLES (CONTINUED)
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5-1 WASTEWATER CONSTITUENTS NOT REGULATED IN MULTI-SOURCE
LEACHATE AND REGULATED CONSTITUENTS THAT CONTROL FOR
THEIR TREATMENT 5-4
6-1 VOLATILE VARIABILITY FACTOR CALCULATION 6-4
6-2 SEMIVOLATILE VARIABILITY FACTOR CALCULATION 6-5
6-3 VOLATILE ACCURACY CORRECTION FACTOR CALCULATIONS - EPA
DATA 6-6
6-4 SEMIVOLATILE ACCURACY CORRECTION FACTOR CALCULATIONS - EPA
DATA 6-7
6-5 VOLATILE ACCURACY CORRECTION FACTOR CALCULATIONS FOR DOW
LEACHATE DATA 6-8
6-6 VOLATILE ACCURACY CORRECTION FACTOR CALCULATIONS FOR CWM
LEACHATE DATA 6-9
6-7 SEMIVOLATILE ACCURACY CORRECTION FACTOR CALCULATIONS FOR
DOW LEACHATE DATA 6-10
6-8 ORGANOCHLORINE PESTICIDES ACCURACY CORRECTION FACTOR
CALCULATIONS FOR DOW LEACHATE DATA 6-11
6-9 ORGANOPHOSPHORUS INSECTICIDE ACCURACY CORRECTION FACTOR
CALCULATIONS FOR DOW LEACHATE DATA 6-12
xviii
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LIST OF TABLES (CONTINUED)
Page
6-10 BOAT TREATMENT STANDARDS FOR MULTI-SOURCE LEACHATE AND
ORGANIC U AND P WASTES 6-13
xix
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1.0 INTRODUCTION
1.1 Regulatory Background
Section 3004(m) of the Resource Conservation and Recovery Act
(RCRA), as amended by the Hazardous and Solid Waste Amendments (HSWA) on
November 8, 1984, requires the U.S. Environmental Protection Agency (EPA or
the Agency) to promulgate treatment standards for certain hazardous wastes
based on the Best Demonstrated Available Technology (BOAT) for those wastes.
More than 500 of these hazardous wastes were listed as of December 1988 (see
Title 40, Code of Federal Regulations. Part 261 (40 CFR Part 261)). The
Agency divided the listed hazardous wastes into five groups. The wastes in
each group were examined to determine whether further land disposal is
protective of human health and the environment (see 40 CFR Part 268). The
five groups and their respective dates of promulgation of treatment standards
are:
• Solvent and dioxin wastes November 7, 1986
• "California List" wastes July 8, 1987
• "First Third" wastes August 8, 1988
• "Second Third" wastes June 8, 1989
"Third Third" wastes On or before May 8, 1990
Several wastes included in this schedule were regulated ahead of schedule, and
several wastes in the "First Third" or "Second Third" group of wastes were
deferred to the "Third Third" group of wastes. Treatment standards for the
"Third Third" wastes will become effective no later than May 8, 1990. On and
after this date, wastes regulated in the "Third Third" rulemaking will have to
comply with applicable treatment standards prior to "land disposal" as defined
in 40 CFR Part 268.
This document provides the Agency's rationale and technical support
for developing concentration-based treatment standards for multi-source
leachates and organic U and P wastes that are amenable to quantification in
hazardous waste matrices. These standards are applicable to the wastes as
listed as well as to any wastes generated by the management or treatment of
1-1
-------
the listed was_te. Treatment standards are specified for both nonwastewater
and wastewater forms of each listed hazardous waste. .For the purpose of
determining the applicability of the treatment standards, wastewaters are
defined as wastes containing less than 1% (weight basis) total suspended
solids1 and less than 1% (weight basis) total organic carbon (TOC). Wastes
not meeting the wastewater definition must comply with treatment standards for
nonwastewaters. In general, numerical treatment standards were developed for
wastes that are amenable to quantification in hazardous waste matrices, and
treatment standards specifying methods of treatment were developed for wastes
that are not amenable to quantification in hazardous waste matrices using
currently available analytical methods.
The Agency's legal authority and promulgated methodology for
establishing treatment standards and the petition process for requesting a
variance from the treatment standards are summarized in EPA's Methodology for
Developing BOAT Treatment Standards (Reference 1).
U wastes include discarded commercial chemical products,
manufacturing chemical intermediates, off-specification commercial chemical
products, container or inner liner residues, and residues, contaminated water,
soil, or debris resulting from cleanup of a spill that are identified as toxic
wastes. P wastes include discarded commercial chemical products,
manufacturing chemical intermediates, off-specification commercial chemical
products, container or inner liner residues, and residues, contaminated water,
soil, or debris resulting from cleanup of a spill that are identified as
acutely hazardous wastes. Section 2.0 discusses the definition of U and P
wastes in greater detail.
1The term "total suspended solids" (TSS) clarifies EPA's previously used
terminology of "total solids" and "filterable solids." Specifically, total
suspended solids are measured by Method 209c (Total Suspended Solids Dried at
103 to 105°C in Standard Methods for the Examination of Water and Wastewater
(Reference 18).
1-2
-------
Multi-source leachate is any liquid, including any suspended
components in the liquid, that has percolated through or drained from the
treatment, storage, or disposal of more than one listed hazardous waste.
Section 2.0 discusses the definition of multi-source leachate in greater
detail.
1.2 User's Guide to the Five-Volume U and P Waste and Multi-source
Leachate Background Document Set
In the interest of clarity, the Agency has reorganized the "Third
Third" background documents that were prepared for proposal of the Third Third
Rule. Multi-source leachates and the majority of the U and P waste codes
addressed in the Third Third Proposed Rule are now covered in a five-volume
set of background documents.
The five-volume background document set is organized as follows:
• Volume A (this document) - Wastewater forms of organic U and P
wastes and multi-source leachate for which there are
concentration-based treatment standards;
• Volume B - U and P wastewaters and non-wastewaters with methods
of treatment as treatment standards;
• Volume C - Nonwastewater forms of organic U and P wastes and
multi-source leachate for which there are concentration-based
treatment standards;
• Volume D - Reactive U and P wastewaters and non-wastewaters
with methods of treatment as treatment standards; and
• Volume E - Gaseous U and P wastes.
Volumes A, B, and C have a set of cross-reference tables which help
the reader locate a particular waste code or constituent and its treatment
standard. These tables list the volume in which the nonwastewater and
wastewater forms of each waste code and multi-source leachate are discussed,
and the corresponding regulated constituents and treatment standards.
Table 1-1 in each volume is organized by waste code. Table 1-2 in each volume
is organized alphabetically by regulated constituent.
1-3
-------
1.3 ^tMIBHPTy °^ Contents: Volume A
This background document provides the Agency's rationale and
technical support for selecting constituents for regulation and for developing
treatment standards for the wastewater forms of these wastes. The specific U
and P wastes that are the subject of this document are listed in Table 1-3 by
waste code. Table 1-3 also presents the constituents for which the wastes are
listed. The specific multi-source leachate constituents that are the subject
of this document are listed alphabetically in Table 1-4 by constituent name.
Tables 1-3 and 1-4 summarize the promulgated treatment standards for these
wastes.
Section 2.0 of this background document presents a description of
the industry that may be affected by these land disposal restrictions, the
processes generating these wastes, available waste characterization data, and
the determination of waste treatability groups.
EPA's methodology for identifying BDAT for wastes included in this
document is presented in Section 3.0. Concentration-based treatment standards
for all organic constituents in wastewater forms of U and P wastes and for all
BDAT List constituents that may be present in multi-source leachate have been
developed based on wastewater treatment performance data from several sources
and technologies. This section describes the data hierarchy used to determine
the "best" treatment performance data for determining the BDAT treatment
standards.
Section 4.0 gives a brief description of each of the data sources
used to provide wastewater treatment performance data. This section presents
the treatment performance data that the Agency used to determine BDAT and
promulgated treatment standards for the wastes included in this document. The
Agency has treatment performance data for wastewaters from various sources
including: (1) the Office of Water's Industrial Technology Division (ITD) and
National Pollutant Discharge Elimination System (NPDES) data; (2) the
Hazardous Waste Engineering Research Laboratory (WERL) database; (3) the
1-4
-------
Office of Solid Waste's BDAT data from previous land disposal restrictions
rules and the wastewater treatment test on wet air oxidation (WAO) and PACT*
technologies; (4) industry-submitted leachate treatment performance data; and
(5) additional wastewater treatment data from literature including articles on
WAO and PACTR.
EPA's rationale for selecting constituents for regulation is
presented in Section 5.0. Due to the lack of characterization data for most U
and P wastewaters, only the constituent for which the waste is listed is being
regulated. In the case of multi-source leachates, almost all of the BDAT List
constituents are being regulated since a leachate may contain any or all of
these constituents.
Section 6.0 describes the calculations used to determine the
promulgated treatment standards for organic constituents in U and P
wastewaters and BDAT list constituents in multi-source leachate wastewaters.
Tables 1-3 and 1-4 at the end of Section 1.0 summarize these treatment
standards. The units for total composition of the constituents are mg/1 or
parts per million on a weight-by-volume basis, for the wastewater forms of
these wastes.
Section 7.0 acknowledges the persons involved in developing the
regulation of these wastes. Section 8.0 includes references cited in this
document. Appendix A includes industry characterization and waste
characterization tables. Appendix B includes a list of the U and P wastes
arranged by Third Third treatability groups. Appendix C includes method
detection limits for constituents discussed in this background document.
1-5
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Table 1-1
TREATMENT STANDARDS FOR 0 AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C; BY HASTE CODE
Wastewater Nonvastevater
Haste
Code Regulated Constituents
F039 Multi-Source Leachate Constituents - Refer
P001 Warfarin (>0.3*)
P002 l-Acetyl-2-thiourea
P003 Acrolein
P004 Aldrin
P005 Allyl alcohol
P007 5-Aninonethyl-3-isoxazolol
POOS 4-Aoinopyridine
P014 Tbiopbenol (Benzenethiol)
P016 Bis(chloronethyl)ether
P017 Bronoacetone
P018 Brucine
P020 2-sec-Butyl-4,6-dinitrophenol (Dinoseb)
P022 Carbon disulfide
P023 Chloroacetaldehyde
P024 p-Chloroaniline
P026 l-(
-------
Table 1-1 (Continued)
TREATMENT STANDARDS FOR C AND P WASTES AND MDLTI-SOORCE LEACHATE (F039)
IMCLDDED IN VOIMES A, B, AND C; BY HASTE CODE
Wastewater Nonwastevater
Haste
Code Jegulated Constituents
P072 l-Naphthyl-2-thiourea
P075 Nicotine and salts
P077 p-Nitroaniline
P082 N-Nitrosodinethylanine
P084 H-Nitrosonethylvinylaiiine
P088 Endothall
P093 N-Phenylthiourea
P095 Phosgene
P101 Ethyl cyanide (Propanenitrile)
P102 Proparqyl alcohol
P108 Strychnine and salts
P116 Thiosenicarbazide
P118 Trichloronethanethiol
P123 Toxaphene
0001 Acetaldehyde
0002 Acetone
0003 Acetonitrile
0004 Acetophenone
COOS 2-Acetylaninofluorene
0006 Acetyl chloride
0007 Acrylaaide
0008 Acrylic acid
0009 Acrylonitrile
0010 Hitonycin C
0011 Anitrole
0012 Aniline
0014 Auranine
0015 Azaserine
0016 Benzicjacridine
U017 Benzal chloride
U018 Benz i a ^anthracene
U019 Benzene
0020 Benzene sulfonyl chloride
0021 Benzidine
0022 Benzo(a)pyrene
0024 Bis(2-chloroethoxy)Bethane
0025 Bis(2-chloroethyl)ether
0026 Chlornaphazine
0027 Bis (2-chloroisopropyl) ether
0029 Brononethane (Methyl bronide)
0030 4-Bronophenyl phenyl ether
0031 n-Butyl alcohol
0033 Carbonyl fluoride
0034 Trichloroacetaldehyde (Chloral)
0035 Chloranbucil
Treataent
Docunent Standard (ng/1) *
B
B
A
A
B
B
B
B
A
B
B
B
B
A
B
A
A
A
A
B
B
B
A
B
B
A
B
B
B
B
A
A
B
B
A
A
A
B
A
A
A
A
B
B
B
BOAT
BOAT
0.028
0.40
BDAT
BOAT
BDAT
BDAT
0.24
BDAT
BDAT
BDAT
BDAT
0.0095
BDAT
0.28
0.17
0.010
0.059
BDAT
BDAT
BDAT
0.24
BDAT
BDAT
0.81
BDAT
BDAT
BDAT
BDAT
0.059
0.14
BDAT
BDAT
0.061
0.036
0.033
BDAT
0.055
0.11
0.055
5.6
BDAT
BDAT
BDAT
Docunent
B
B
C
B
B
B
B
B
C
B
B
B
B
C
B
C
B
C
C
B
B
B
C
B
B
C
B
B
B
B
C
C
B
B
C
C
C
B
C
C
C
C
B
B
B
Treatnent
Standard (ng/kg) **
BDAT
BDAT
28
BDAT
BDAT
BDAT-PS
BDAT
BDAT
360
BDAT-FS
BDAT
BDAT
BDAT
1.3
BDAT
160
BDAT
9.7
140
BDAT
BDAT
BDAT-FS
84
BDAT
BDAT
14
BDAT
BDAT
BDAT-FS
BDAT
3.2
36
BDAT
BDAT
8.2
7.2
7.2
BDAT
7.2
15
15
2.6
BDAT
BDAT
BDAT
* BDAT for vastevaters is vet air or chenical oxidation followed by carbon adsorption or incineration.
** BDAT for nonvastevaters is incineration but fuel substitution is also BDAT for the waste codes narked as BDAT-FS.
1-7
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Table 1-1 (Continued)
TREATHEHT STANDARDS FOR D AND P WASTES AND HDLTI-SOCRCE LEACHATE (F039)
INCLUDED IN VOLOHES A, B, AND C; BY WASTE CODE
Wastewater Nonwastevater
Waste
Code
0036
U037
D038
0039
U041
C042
0043
0044
0045
0046
0047
0048
0049
0050
0051
0051
0051
0051
0051
0051
0051
0052
0052
0053
0055
0056
0057
0059
0060
C060
0061
0061
0061
0061
0061
0061
0062
0063
0064
0066
0067
0068
0070
0071
0072
Regulated Constituents
Chlordane (alpha and ganna)
Chlorobenzene
Chlorobenzilate
p-Chloro-B-cresol
l-Chloro-2 , 3-epoxypropane ( Epichlorohydrin )
2-Chloroethyl vinyl ether
Vinyl chloride
Chloroforn
Chlorotethane (Methyl chloride)
Chloronethyl nethyl ether
2-Chloronaphthalene
2-Chlorophenol
4-Chloro-o-toluidine hydrochloride
Chrysene
Creosote - Lead
Creosote - Naphthalene
Creosote - Pentachlorophenol
Creosote - Pbenanthrene
Creosote - Pyrene
Creosote - Toluene
Creosote - Xylenes (total)
Cresol (B- and p- isoaers)
o-Cresol
Crotonaldebyde
Cunene
Cyclohexane
Cyclohexanone
Daunonycin
o,p'-DDD
p,p'-DDD
o,p'-DDD
p,p'-DDD
o,p'-DDE
p,p'-DDE
o,p'-DDT
p,p'-DDT
Diallate
Dibenz ( a, h) anthracene
1,2,7,8-Dibenzopyrene
1 ,2-Dibrono-3-chloropropane
1,2-Dibronoethane (Etbylene Dibronide)
Dibrononethane
o-Dichlorobenzene
a-Dichlorobenzene
p-Dichlorobenzene
Docunent
A
A
A
A
B
B
A
A
A
B
A
A
B
A
A
A
A
A
A
A
A
A
A
B
B
B
A
B
A
A
A
A
A
A
A
A
B
A
B
A
A
A
A
A
A
Treatment
Standard (ug/1) *
0.0033
0.057
0.10
0.018
BOAT
BOAT
0.27
0.046
0.19
BOAT
0.055
0.044
BDAT
0.059
0.28
0.059
0.089
0.059
0.067
0.080
0.32
0.77
0.11
BDAT
BDAT
BDAT
0.36
BDAT
0.023
0.023
0.023
0.023
0.031
0.031
0.0039
0.0039
BDAT
0.055
BDAT
0.11
0.028
0.11
0.088
0.036
0.090
Docunent
C
C
B
C
B
B
C
C
C
B
C
C
B
C
C
C
C
C
C
C
C
C
C
B
B
B
B
B
C
C
C
C
C
C
C
C
B
C
B
C
C
C
C
C
C
Treatment
Standard fig/kg) **
0.13
5.7
BDAT
14
BDAT
BOAT
33
5.6
33
BDAT
5.6
5.7
BDAT
8.2
0.51 «
3.1
7.4
3.1
8.2
28
28
3.2
5.6
BDAT-FS
BDAT-FS
BDAT-FS
BDAT-FS
BDAT
0.087
0.087
0.087
0.087
0.087
0.087
0.087
0.087
BDAT
8.2
BDAT-FS
15
15
15
6.2
6.2
6.2
* BDAT for vastevaters is wet air or cbenical oxidation followed by carbon adsorption or incineration.
** BDAT for nonwastewaters is incineration but fuel substitution is also BDAT for the waste codes narked as BDAT-FS.
§ Onits for the lead standard are ng/1; analyzed by TCLP extract.
1-8
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Table 1-1 (Continued)
TREATMENT STANDARDS FOR D AND P WASTES AND MULTI-SOURCE LEACHATE (P039)
INCLUDED IN VOLUMES A, B, AND C; BY WASTE CODE
Wastewater Nonvasteuater
Waste
Code
U073
U074
0074
0075
C076
U077
0078
0079
0080
0081
U082
0083
0084
0084
0085
U089
0090
0091
U092
0093
U094
0095
0097
0101
0105
0106
U108
0110
0111
0112
0113
0114
0115
0116
0117
0118
0119
0120
0121
0122
0123
0124
0125
0126
Regulated Constituents
3,3' -Dichlorobenz idine
cis-1 , 4-Dichloro-2-butene
trans-1 , 4-Dichloro-2-butene
Dichlorodifluoronethane
1,1-Dichloroethane
1,2-Dichloroe thane
1,1-Dichloroethylene
trans-l ,2-Dichloroethylene
Nethylene chloride
2,4-Dichlorophenol
2,6-Dichlorophenol
1,2-Dichloropropane
cis-1 , 3-Dichloropropylene
trans-1 ,3-Dichloropropylene
1,2:3, 4-Diepoxy butane
Diethylstilbestrol
Dihydrosafrole
3,3' -Dinethoxybenz idine
Dinethylanine '
p-Dinethylaninoazobenzene
7,12-Dinethyl benz(a)anthracene
3,3' -Dinethy Ibenz idine
Dinethylcarbanoyl chloride
2,4-Diiethylphenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
1,4-Dioxane
Dipropylanine
Di-n-propylnitrosanine
Ethyl acetate
Ethyl acrylate
Ethylene bis-dithiocarbanic acid
Ethylene oxide
Ethylene thiourea
Ethyl ether
Ethyl nethacrylate
Ethyl nethanesulfonate
Fluoranthene
TricbloroDonofluoronethane
Forialdehyde
Foraic acid
Furan
Furfural
Glycidylaldehyde
Docunent
B
B
B
A
A
A
A
A
A
A
A
A
A
A
B
B
B
B
B
B
B
B
B
A
A
A
A
B
A
A
B
B
A
B
A
A
B
A
A
B
B
B
B
B
Treatment
Standard (nq/1) *
BOAT
BOAT
BOAT
0.23
0.059
0.21
0.025
0.054
0.089
0.044
0.044
0.85
0.036
0.036
BDAT
BOAT
BOAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
0.036
0.32
0.55
0.12
BDAT
0.40
0.34
BDAT
BDAT
0.12
BDAT
0.12
0.14
BDAT
0.068
0.020
BDAT
BDAT
BDAT
BDAT
BDAT
Docunent
B
B
B
C
C
C
C
C
C
C
C
C
C
C
B
B
B
B
B
B
B
B
B
C
C
C
C
B
C
C
B
B
§
B
C
C
B
C
C
B
B
B
B
B
Treatnent
Standard fug/kg) **
BDAT
BDAT
BDAT
7.2
7.2
7.2
33
33
33
14
14
18
18
18
BDAT-FS
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT-FS
BDAT
BDAT
14
140
28
170
BDAT
14
33
BDAT-FS
BDAT
§
BDAT
160
160
,BDAT
8.2
33
BDAT-FS
BDAT-FS
BDAT-FS
BDAT-FS
BDAT-FS
* BDAT for vastevaters is vet air or cheaical oxidation followed by carbon adsorption or incineration.
** BDAT for nonvastevaters is incineration but fuel substitution is also BDAT for the vaste codes narked as BDAT-FS.
@ Constituent is regulated in the vastevater fora but not in the nonwastewater font.
1-9
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Table 1-1 (Continued)
TREATMENT STANDARDS FOR 0 AND P WASTES AND HCLTI-SOCRCE LEACHATE |F039i
INCLUDED IN VOLUMES A, B, AHD C; BY «ASTE CODE
Wastewater Honwastevater
Waste
Code Regulated Constituents
D127 Hexachlorobenzene
C128 Hexachlorobutadiene
D129 alpha-BHC
C129 beta-BHC
U129 delta-BBC
0129 ganna-BHC (Lindane)
U130 Hexachlorocyclopentadiene
U131 Hexachloroethane
U132 Hexachlorophene
0137 Indeno(l,2,3-c,d)pyrene
U138 lodonethane
0140 Isobutyl alcohol
0141 Isosafrole
C142 Kepone
U143 Lasiocarpine
U147 Kaleic anhydride
0148 Haleic hydrazide
0149 Halononitrile
0150 Helphalan
0152 Kethacrylonitrile
0153 Hethanethiol
0154 Methanol
0155 Methapyrilene
0156 Methyl chlorocarbonate
0157 3-Hethylcholanthrene
0158 4,4' -Methylenebis( 2-chloroaniline)
0159 Methyl ethyl ketone
0161 Kethyl isobutyl ketone
0162 Methyl nethacrylate
Q63 N-Nethyl-N-nitro-H-nitrosoguanidine
U164 Hethylthiouracil
C165 Naphthalene
C166 1,4-Naphthoquinone
U167 l-Naphthylanine
0168 2-Haphthylatine
0169 Nitrobenzene
0170 4-Hitrophenol
0171 2-Hitropropane
0172 H-Hitrosodi-n-butylanine
0173 H-Hitrosodiethanolanine
0174 N-Nitrosodiethylanine
0176 H-Nitroso-H-ethylurea
0177 H-Hitroso-H-nethylurea
0178 N-Hitroso-N-nethylurethane
0179 H-Hitrosopiperidine
Docunent
A
A
A
A
A
A
i
A
B
A
A
A
A
A
B
B
B
B
B
A
B
A
A
B
A
A
A
A
A
B
B
i
B
B
A
A
A
B
A
B
A
B
B
B
A
Treatnent
Standard (ng/1) *
0.055
0.055
0.00014
0.00014
0.023
0.0017
0.057
0.055
BDAT
0.0055
0.19
5.6
0.081
0.0011
BDAT
BDAT
BDAT
BDAT
BDAT
0.24
BDAT
5.6
0.081
BDAT
0.0055
0.50
0.28
0.14
0.14
BDAT
BDAT
0.059
BDAT
BDAT
0.52
0.068
0.12
BDAT
0.40
BDAT
0.40
BDAT
BDAT
BDAT
0.013
Docunent
C
C
C
C
C
C
C
C
B
C
C
C
C
C
B
B
B
B
B
C
B
B
C
B
C
C
C
C
C
B
B
C
B
B
B
C
C ,
B
C
B
C
B
B
B
C
Treatuent
Standard fug/kg) **
37
28
0.066
0.066
0.066
0.066
3.6
28
BDAT
8.2
65
170
2.6
0.13
BDAT
BDAT-FS
BDAT
BDAT
BDAT
84
BDAT
BDAT-FS
1.5
BDAT
15
35
36
33
160
BOAT
BDAT
3.1
BDAT
BDAT
BDAT
14
29
BDAT
17
BDAT
28
BDAT
BDAT
BDAT
35
* BDAT for wastevaters is wet air or chenical oxidation followed by carbon adsorption or incineration.
** BDAT for nonwastewaters is incineration but fuel substitution is also BDAT for the waste codes narked as BDAT-FS.
1-10
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Table 1-1 (Continued)
TREATMENT STANDARDS FOR D AND P WASTES AND HOLTI-SOCRCE LEACHATE (F039)
INCLODED IH VOLCKES A, B, AND C; BY WASTE CODE
Wastewater Nonvastevater
Waste
Code
U180
D181
U182
0183
U184
C185
C186
D187
D188
0191
D192
D193
U194
C196
D197
D200
U201
D202
D203
D206
0207
U208
0209
0210
0211
0213
0218
0219
0220
D222
C225
C226
0227
0228
0234
0236
0237
0238
0239
0240
0240
0243
0244
0247
0248
Regulated Constituents 1
N-Nitrosopyrrolidine
5-Nitro-o-toluidine
Paraldehyde
Pentachlorobenzene
Pentachloroethane
Pentachloronitrobenzene
1,3-Pentadiene
Phenacetin
Phenol
2-Picoline
Pronanide
1,3-Propane sultone
n-Propylanine
Pyridine
p-Benzoquinone
Reserpine
Resorcinol
Saccharin and salts
Safrole
Streptozotocin
1,2,4,5-Tetrachlorobenzene
1,1,1, 2-Tetr achloroethane
1,1,2, 2-Tetrachloroethane
Tetrachloroethylene
Carbon tetrachloride
Tetrahydrofuran
Thioacetanide
Thiourea
Toluene
o-Toluidine hydrochloride
Tribrononethajie (Bronoforn)
1 , 1 , 1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethylene
syu-Trinitrobenzene
Trypan blue
Oracil nustard
Ethyl carbanate
Xylenes
2, 4-Dichlorophenoxy acetic acid
2,4-Dichlorophenoxyacetic salts and esters
Hexachloropropene
Thiran
Hethoxychlor
Warfarin (<0.3I)
tocunent £
A
A
B
A
B
A
B
A
A
B
A
B
B
A
B
B
B
B
A
B
A
A
A
A
A
B
B
B
A
B
A
A
A
A
B
B '
B
B
A
A
B
A '
B
A
B
Treatment
standard (ng/1) *
0.013
0.32
BOAT
0.055
BOAT
0.055
BOAT
0.081
0.039
BDAT
0.093
BDAT
BDAT
0.014
BDAT
BDAT
BDAT
BDAT
0.081
BDAT
0.055
0.057
0.057
0.056
0.057
BDAT
BDAT
BDAT
0.080
BDAT
0.63
0.054
0.054
0.054
BDAT
BDAT
BDAT
BDAT
0.32
0.72
BDAT
0.035
BDAT
0.25
BDAT
Docunent
C
C
B
C
B
C
B
C
C
B
C
B
B
C
B
B
B
B
C
B
C
C
C
C
C
B
B
B
C
B
C
C
C
C
B
B
B
B
C
C
B
C
B
C
B
Treatient
Standard (ng/kg) **
35
28
BDAT-FS
37
BDAT
4.3
BDAT-FS
16
6.2
BDAT
1.5
BDAT
BDAT
16
BDAT-FS
BDAT
BDAT-FS
BDAT
22
BDAT
19
42
42
5.6
5.6
BDAT-FS
BDAT
BDAT
28
BOAT
15'
5.6
5.6
5.6
BDAT
BDAT
BDAT
BDAT
28
10
BDAT
28
BDAT
0.18
BDAT-FS
* BDAT for vastevaters is vet air or cbenical oxidation followed by carbon adsorption or incineration.
** BDAT for nonvastevaters is incineration but fuel substitution is also BDAT for the waste codes narked as BDAT-FS.
1-11
-------
Table 1-2
TREATMENT STANDARDS FOR 0 AHD P WASTES AND KCLTI-SOCRCE LEACHATE (F039)
INCLODED IK VOLOHES A, B, AND C; ALPHABETICALLY
Wastewater
Honwastewater
Regulated u and P Waste Constituents
Acetaldehyde
Acetone
Acetonitrile
Acetophenone
2-Acetylaninofluorene
Acetyl chloride
l-Acetyl-2-thiourea
Acrolein
Acr/lanide
Acrylic acid
Acrylonitrile
Aldicarb
Aldrin
Allyl alcohol
5-Aninonethyl-3-isoxazolol
4-Aninopyridine
Anitrole
Aniline
Auranine
Azaserine
Aziridine
Benzal chloride
Benz(a)anthracene
Benz(c)acridine
Benzene
Benzene sulfonyl chloride
Benzidine
Benzo(a)pyrene
p-Benzoquinone
Benzyl chloride
alpha-BHC
beta-BHC
delta-BBC
ganaa-BHC
Bis ( 2-chlor oethoxy ) nethane
Bisj 2-chloroethyl )ether
Bis ( 2-chloroisopropy 1 ) ether
Bis(chloronethyl)ether
Bronoacetone
Brononethane (Methyl bronide)
4-Bronopbenyl phenyl ether
Brucine
n-Butyl alcohol
2-sec-Butyl-4 ,6-dinitrophenol (Dinoseb)
Carbon disulf ide
Haste
Code
0001
0002
0003
0004
0005
0006
P002
P003
0007
0008
0009
P070
P004
POOS
P007
POOS
0011
0012
0014
0015
P054
0017
0018
0016
0019
0020
0021
0022
0197
P028
0129
0129
0129
0129
0024
oofc
0027
P016
P017
0029
0030
P018
0031
P020
P022
Docunent
B
A
A
A
A
B
B
A
B
B
A
B
A
B
B
B
B
A
B
B
B
B
A
B
A
B
B
A
B
B
A
A
A
A
A
A
A
B
B
A
A
B
A
A
A
Treatment
Standard (ng/1) *
BDAT
0.28
0.17
0.010
0.059
BDAT
BDAT
0.29
BDAT
BDAT
0.24
BDAT
0.021
BDAT
BDAT
BDAT
BDAT
0.81
BDAT
BDAT
BDAT
BDAT
0.059
BDAT
0.14
BDAT
BDAT
0.061
BDAT
BDAT
0.00014
0.00014
0.023
0.0017
0.036
0.033
0.055
BDAT
BDAT
0.11
0.055
BDAT
5.6
0.066
0.014
Docunent
B
C
B
C
C
B
B
B
B
B
C
B
C
B
B
B
B
C
B
B
B
B
C
B
C
B
B
C
B
B
C
C
C
C
C
C
C
B
B
C
C
B
C
C
B
Treatoent
Standard (ug/kg) **
BDAT
160
BDAT
9.7
140
BDAT
BDAT
BDAT-FS
BDAT
BDAT-FS
84
BDAT
0.066
BDAT-FS
BDAT
BDAT
BDAT
14
BDAT
BDAT
BDAT
BDAT
8.2
BDAT-FS
36
' BDAT
BDAT
8.2
BDAT-FS
BDAT
0.066
0.066
0.066
0.066
7.2
7.2
7.2
BDAT
BDAT
15
15
BDAT
2.6
2.5
BDAT
* BDAT for vastevaters is wet air or cbenical oxidation followed by carbon adsorption or incineration.
** BDAT for nonwastewaters is incineration. Fuel substitution is also BDAT for the waste codes narked as BDAT-FS.
1-12
-------
Table 1-2 (Continued)
TREATMENT STANDARDS FOR D AND P WASTES AND HCLTI-SOCRCE LEACHATE (F039)
INCLUDED IN VOLUXES A, B, AND C; ALPHABETICALLY
Wastewater
Honwastewater
Regulated D and P Waste Constituents
Carbon tetrachloride
Carbpnyl fluoride
Chloranbucil
Chlordane (alpha and qanna)
Chloroacet aldehyde
p-Chloroaniline
Chlorobenzene
Chlorobenzilate
l-Chloro-2 , 3-epoxypropane ( Epichlorohydrin )
2-Chloroethyl vinyl ether
Chlorofom
p-Chloro-n-cresol
Chloronethane (Methyl chloride)
Chloronethyl nethyl ether
Chlornaphazine
2-Chloronapbthalene
4-Chloro-o-toluidine hydrochloride
2-Chlorophenol
1- ( o-Cblorophenyl )thiourea
3
-------
Table 1-2 (Continued)
TREATNEHT STANDARDS FOR D AND P PASTES AND HCLTI-SOCJCE LEACHATE (F039)
INCLCDED IH VOLDMS A, B, AND C; ALPHABETICALLY
Wastewater
Nonvastevater
Regulated D and P Haste Constituents
Diallate
Diben z( a, h) anthracene
1,2,7,8-Dibenzopyrene
1 , 2-Dibrono-3-chloropropane
1,2-Dibronoethane (Ethylene dibronide)
Dibrononethane
n-Dichlorobenzene
o-Dichlorobenzene
p-Dichlorobenzene
3,3' -Dichlorobenz idine
cis-1 , 4-Dichloro-2-butene
trans-1 ,4-Dichloro-2-butene
Dichlorodifluoronetbane
1,1-Dichloroe thane
1,2-Dichloroethane
1 , 1-Dichloroethy lene
trans-1, 2-Dichloroethylene
2,4-Dichloropbenol
2,6-Dichlorophenol
2, 4-Dichlorophenoxy acetic acid
2,4-Dichlorophenoxyacetic salts and esters
1,2-Dichloropropane
cis-1 , 3-Dichloropropylene
trans-1 , 3-Dichloropropylene
Dieldrin
l,2:3,4-Diepoxybutane
Diethylstilbestrol
Dihydrosafrole
3,3' -Dinethoxybenz idine
Dinethylanine
p-Dinethylaninoazobenzene
",12-Dinethyl benzf a (anthracene
3 , 3 ' -Dinethylbenzidine
Dinethylcarbanoyl chloride
alpha ,alpha-Dinethylphenethylanine
2,4-Dinethylphenol
4 , 6-Dinitro-o-cresol
4,6-Dinitro-o-cresol salts
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di -n-propylnitrosanine
1,4-Dioxane
Dipropylanine
2,4-Dithiobiuret
Waste
Code
0062
U063
G064
0066
U067
U068
0071
U070
0072
0073
0074
0074
0075
0076
0077
0078
0079
0081
0082
0240
0240
0083
0084
0084
P037
0085
0089
0090
0091
0092
0093
0094
0095
0097
P046
0101
P047
P047
P048
0105
0106
0111
0108
0110
P049
Docunent
B
A
B
A
A
A
i
i
A
B
B
B
A
A
A
A
A
A
A
A
B
A
A
A
A
B
B
B
B
B
B
B
B
B
B
A
A
B
A
A
A
A
A
B
B
Treatnent
Standard (ng/1) *
BDAT
0.055
BDAT
0.11
0.028
0.11
0.036
0.088
0.090
BDAT
BDAT
BDAT
0.23
0.059
0.21
0.025
0.054
0.044
0.044
0.72
BOAT
0.85
0.036
0.036
0.017
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
0.036
0.28
BDAT
0.12
0.32
0.55
0.40
0.12
BDAT
BDAT
Docunent
B
C
B
C
C
C
C
C
C
B
B
B
C
C
C
C
C
C
C
C
B
C
C
C
C
B
B
B
B
B
B
B
B
B
B
c •
C
B
C
C
C
C
C
B
B
Treatnent
Standard (ng/kg) **
BDAT
8.2
BDAT-FS
15
15
15
6.2
6.2
6.2
BDAT
BDAT
BDAT
7.2
7.2
7.2
33
33
14
14
10
BDAT
18
18
18
0.13
BDAT-FS
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT-FS
BDAT
BDAT
BDAT
14
160
BDAT
160
140
28
14
170
BDAT
BDAT
* BDAT for wastevaters is wet air or chenical oxidation followed by carbon adsorption or incineration.
** BDAT for nonwastewaters is incineration. Fuel substitution is also BDAT for the waste codes Barked as BDAT-FS.
1-14
-------
Table 1-2 (Continued)
TREATMENT STANDARDS FOR C AHD P PASTES AND HULTI-SOCRCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C; ALPHABETICALLY
Wastevater
Nonwastewater
Regulated D and P Waste Constituents
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endothall
Endrin
Endrin aldehyde
Epinephrine
Ethyl acetate
Ethyl acrylate
Ethyl carbaoate
Ethyl cyanide (Propanenitrile)
Ethyl ether
Ethyl nethacrylate
Ethyl oethanesulfonate
Ethylene bis-dithiocarbanic acid
Ethylene oxide
Ethylene thiourea
Fluoranthene
Fluoroacetanide
Fluoroacetic acid, sodiun salt
Fonaldehyde
Formic acid
Furan
Furfural
Glycidylaldehyde
Heptachlor
Heptachlor epoxide
Hexachlorobenzene
Hexachlorobutadiene
flex achlorocyclopentad iene
Hexachloroethane
Hexachlorophene
Hexachloropropene
Indeno(l,2,3-c,d)pyrene
lodonethane
Isobutyl alcohol
Isocyanic acid, nethyl ester
Isodrin
Isosafrole
Kepone
Lasiocarpine
Kaleic anhydride
Kaleic hydrazide
Nalononitrile
Waste
Code
P050
P050
P050
P088
P051
P051
P042
C112
U113
0238
P101
0117
0118
0119
0114
0115
0116
0120
P057
P058
0122
0123
0124
0125
0126
P059
P059
0127
0128
0130
0131
0132
0243
0137
0138
0140
P064
P060
0141
0142
0143
0147
0148
0149
Docunent
A
A
A
B
A
A
B
A
B
B
A
A
A
B
B
A
B
A
B
B
B
B
B
B
B
A
A
A
A
A
A
B
A
A
A
A
B
A
A
A
B
B
B
B
Treataent
Standard (ng/1) *
0.023
0.029
0.029
BOAT
0.0028
0.025
BOAT
0.34
BOAT
BOAT
0.24
0.12
0.14
BOAT
BOAT
0.12
BDAT
0.068
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
0.0012
0.016
0.055
0.055
0.057
0.055
BDAT
0.035
0.0055
0.19
5.6
BDAT
0.021
0.081
0.0011
BDAT
BDAT .
BDAT
BDAT
Document
C
C
C
B
C
C
B
C
B
B
C
C
C
B
B
e
B
C
B
B
B
B
B
B
B
C
C
C
C
C
C
B
C
C
C
C
B
C
C
C
B
B
B
B
Treatnent
Standard (ng/kg) **
0.066
0.13
0.13
BDAT-FS
0.13
0.13
BDAT
33
BDAT-FS
BDAT
360
160
160
BDAT
BDAT
§
BDAT
8.2
BDAT
BDAT
BDAT-FS
BDAT-FS
BDAT-FS
BDAT-FS
BDAT-FS
0.066
0.066
37
28
3.6
28
BDAT
28
8.2
65
170
BDAT
0.066
2.6
0.13
BDAT
BDAT-FS
BDAT
BDAT
* BDAT for wastewaters is vet air or cheuical oxidation followed by carbon adsorption or incineration.
** BDAT for nonvastevaters is incineration. Fuel substitution is also BDAT for the vaste codes narked as BDAT-FS.
6 Constituent is regulated in the wastevater fora, but not in the nonwastevater fora.
1-15
-------
Table 1-2 (Continued)
TREATMENT STANDARDS FOR D AND P WASTES AND KDLTI-SOORCE LEACHATE (F039)
INCLCDED IN VOLOXES A, B, AHD C; ALPHABETICALLY
tfastewater
Nonwastevater
Requlated D and P Waste Constituents
Helphalan
Hethacrylonitrile
Hethanetbiol
Hethanol
Hethapyrilene
Methonyl
Netboxychlor
Methyl chlorocarbonate
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl nethacrylate
2-Methylaziridine
3-Methylcholanthrene
4,4' -Nethy lenebis( 2-chloroaniline )
Methylene chloride
Methy llactonitrile
N-Methyl-N-nitro-N-nitrosoguanidine
Hethylthiouracil
Hitonycin C
Naphthalene
1,4-Naphthoquinone
1-Naphthylanine
2-Naphthylaaine
l-Naphthyl-2-thiourea
Nicotine and salts
p-Nitroaniline
Nitrobenzene
5-Nitro-o-toluidine
4-Nitrophenol
2-Nitropropane
N-Nitrosodiethanolanine
H-Nitrosodiethylanine
N-NitrosodinethylaBine
N-Nitrosodi-n-butylaiune
N-Nitrosouethylvinylanine
N-Nitroso-N-ethylurea
U-Nitroso-N-uethylurea
N-Nitroso-N-nethylurethane
N-Nitrosopiperidine
N-Nitrosopyrrolidine
Paraldehyde
Pentachloroethane
Pentachlorobenzene
Pentachloronitrobenz ene
1,3-Pentadiene
Waste
Code
0150
0152
0153
0154
U155
P066
0247
0156
0159
0161
0162
P067
0157
0158
0080
P069
0163
0164
0010
0165
0166
0167
0168
P072
P075
P077
0169
0181
0170
0171
' 0173
C174
P082
0172
P084
0176
0177
0178
0179
0180
0182
0184
0183
0185
0186
Docunent
B
A
B
A
A
B
A
B
A
A
A
B
A
A
A
B
B
B
B
A
B
B
A
B
B
A
A
A
A
B
B
A
A
A
B
B
B
B
A
A
B
B
A
A
B
Treataent
Standard (ng/1) *
BDAT
0.24
BDAT
5.6
0.081
BDAT
0.25
BDAT
0.28
0.14
0.14
BDAT
0.0055
0.50
0.089
BDAT
BDAT
BDAT
BDAT
0.059
BDAT
BDAT
0.52
BDAT
BDAT
0.028
0.068
0.32
0.12
BDAT
BDAT
0.40
0.40
0.40
BDAT
BDAT
BDAT
BDAT
0.013
0.013
BDAT
BDAT
0.055
0.055
BDAT
Docunent
B
C
B
B
C
B
C
B
C
C
C
B
C
C
C
B
B
B
B
C
B
B
B
B
B
C
C
C
C
B
B
C
B
C
B
B
B
B
C
C
B
B
C
C
B
Treatnent
Standard (ng/kg) **
BDAT
84
BDAT
BDAT-FS
1.5
BDAT
0.18
BDAT
36
33
160
BDAT
15
35
33
BDAT
BDAT
BDAT
BDAT
3.1
BDAT-FS
BDAT
BDAT
BDAT
BDAT
28
14
28
29
BDAT
BDAT
28
BDAT
17
BDAT
BDAT
BDAT
BDAT
35
35
BDAT-FS
BDAT
37
4.8
BDAT-FS
* BDAT for wastewaters is wet air or chenical oxidation followed by carbon adsorption or incineration.
** BDAT for nonvastevaters is incineration. Fuel substitution is also BDAT for the waste codes narked as BDAT-FS.
1-16
-------
Table 1-2 (Continued)
TREATMENT STANDARDS FOR 0 AND P WASTES AND HULTI-SOCRCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AMD C; ALPHABETICAL
Wastevater
Nonvastevater
Regulated U and P Waste Constituents
Phenacetin
Phenol
N-Phenylthiourea
Phosgene
2-Picoline
Pronanide
1,3-Propane sultone
Propargyl alcohol
n-Propylanine
Pyridine
Reserpine
Resorcinol
Saccharin and salts
Safrole
Streptozotocin
Strychnine and salts
1 , 2 , 4 , 5-Tetrachlorobenzene
1,1,1, 2-Tetr achloroe thane
1,1,2, 2-Tetrachloroethane
Tetrachloroethylene
Tetrahydrofuran
Thioacetanide
Tbiofanox
Thiophenol (Benzenethiol)
Tluosenicarbazide
Thiourea
ThiraD
Toluene
o-Toluidine hydrochloride
Toxaphene
Tribrononethane (Bronofomj
Trichloroacetaldehyde (Chloral)
1,1,1-Trichloroethane
1,1,2-Trichloroe thane
Trichloroethylene
Trichlorouethanethiol
Trichlorononofluoronethane
syn-Trinitrobenzene
Trypan blue
Dracil mustard
Vinyl chloride
Warfarin (>0.3I)
Warfarin (<0.3t)
Xylenes
Waste
Code
U187
U188
P093
P095
U191
0192
U193
P102
D194
0196
0200
0201
U202
0203
0206
P108
0207
0208
0209
0210
0213
0218
P045
P014
P116
0219
0244
0220
0222
P123
0225
0034
0226
0227
0228
P118 '
0121
0234
0236
0237
0043
P001
0248
0239
Docunent
A
A
B
B
B
A
B
B
B
A
B
B
B
A
B
B
A
A
A
A
B
B
B
B
B
B
B
A
B
A
A
B
A
A
A
B
A
B
B
B
A
B
B
A
Treatnent
Standard (ng/1) *
0.081
0.039
BOAT
BOAT
BOAT
0.093
BOAT
BOAT
BDAT
0.014
BDAT
BDAT
BDAT
0.081
BDAT
BDAT
0.055
0.057
0.057
0.056
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
0.080
BDAT
0.0095
0.63
BDAT
0.054
0.054
0.054
BDAT
0.020
BDAT
BDAT
BDAT
0.27
BDAT
BDAT
0.32
Docunent
C
C
B
B
B
C
B
B
B
C
B
B
B
C
B
B
C
C
C
C
B
B
B
B
B
B
B
C
B
C
C
B
C
C
C
B
C
B
B
B
C
B
B
C
Treatment
Standard (ng/kg) **
16
6.2
BDAT
BDAT
BDAT
1.5
BDAT
BDAT-FS
BDAT
16
BDAT
BDAT-FS
BDAT
22
BDAT
BDAT
19
42
42
5.6
BDAT-FS
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
28
BDAT
1.3
15
BDAT
5.6
5.6
5.6
BDAT
33
BDAT
BDAT
BDAT
33
BDAT-FS
BDAT-FS
28
* BDAT for wastewaters is wet air or cheaical oxidation followed by carbon adsorption or incineration.
** BDAT for nonvastevaters is incineration. Fuel substitution is also BDAT for the vaste codes Barked as BDAT-FS.
1-17
-------
Table 1-2 (Continued)
TREATMENT STANDARDS FOR D AHD P WASTES AND MULTI-SOURCE LEACHATE (F039)
INCLUDED IH VOLCHES A, B, AMD C; ALPHABETICALLY
Wastewater
Nonvastewater
Regulated Leachate Constituents
Acenaphthalene
Acenaphthene
Acetone
Acetonitrile
Acetophenone
2-Acetylaninofluorene
Acrolein
Acrylonitrile
Aldrin
4-Aninobiphenyl
Aniline
Anthracene
Aranite
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
Benz(a)anthracene
Benzene
Benzo(b)fluorantbene
Benzojkjfluoranthene
Benzo(g,h,i)perylene
Benzo(a)pyrene
alpha-BHC
beta-BHC
delta-BBC
qanna-BHC (Lindane)
Bisl 2-cbloroethoxy )nethane
Bis< 2-chloroethyl lether
Bisl 2-chloroisopropyl )etber
Bis ( 2-ethy Ihexy 1 ) phthalate
Bronodichloroiiethane
Brononethane (Methyl bronide)
4-Bronophenyl pbenyl ether
n-Butyl alcohol
Butyl benzyl phthalate
2-sec-Butyl-4 ,6-dinitrophenol (Dinoseb)
Carbon disulfide
Carbon tetrachloride
Chlordane (alpha and gama)
p-Chloroaniline
Haste
Code
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
. F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
Docunent
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
Treataent
Standard (ng/1)
0.059
0.059
0.28
0.17
0.010
0.059
0.29
0.24
0.021
0.13
0.810
0.059
0.36
0.013
0.014
0.013
0.017
0.013
0.014
0.014
0.059
0.140
0.055
0.059
0.0055
0.061
0.00014
0.00014
0.023
0.0017
0.036
0.033
0.055
0.28
0.35
0.11
0.055
5.6
0.017
0.066
0.014
0.057
0.0033
0.46
Docunent
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
- c
C
c
c
c
c
c
c
c
c
c
c
c
c
Treatnent
Standard (ng/kg)
3.4
4.0
160
HR
9.7
140
MR
84
0.066
HR
14
4.0
HR
0.92
0.92
0.92
0.92
0.92
1.8
1.8
8.2
36
3.4
3.4
1.5
8.2
0.066
0.066
0.066
0.066
7.2
7.2
7.2
28
15
15
15
2.6
7.9
2.5
NR
5.6
0.13
16
HR = Hot regulated. See Section 5.0 of the appropriate volute for discussion.
1-18
-------
Table 1-2 (Continued)
TREATMENT STANDARDS FOR D AND P WASTES AND HULTI-SOCRCE LEACHATE (F039)
INCLUDED IN VOLOHES A, B, AND C; ALPHABETICALLY
Wastewater
Nonvastewater
Regulated Leachate Constituents
Chlorobenzene
Chlorobenzilate
2-Chloro-l , 3-butadiene
Chlorodibrononethane
Chloroethane
Chloroforn
p-Chloro-D-cresol
Chlorooethane (Methyl chloride)
2-Cbloronaphthalene
2-Chlorophenol
3-Chloropropene
Chrysene
Cresol (B- and p- isoners)
o-Cresol
Cyclohexanone
o,p'-DDD
p,p'-DDD
0,p'-DDE
p,p'-DDB
o,p'-DDT
p,p'-DDT
Dibenz(a,h)anthracene
Dibenzo(a,e)pyrene
1 , 2-Dibrono-3-chloropropane
1,2-Dibrotoethane (Ethylene dibronide)
DibroBone thane
n-Dicblorobenzene
o-Dichlorobenzene
p-Dichlorobenzene
Dichlorodifluoronethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethylene
trans-l,2-Dichloroethylene
2,4-Dichlorophenol
2,6-Dichlorophenol
2,4-Dichlorophenoxyacetic acid
1,2-Dichloropropane
cis-1 , 3-Dichloropropene
trans-1 , 3-Dichloropropene
Dieldrin
Diethyl phthalate
Haste
Code
P039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
Docunent
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
i
A
A
A
A
A
A
A
A
A
A
Treatnent
Standard (ng/1)
0.057
0.10
0.057
0.057
0.27
0.046
0.018
0.19
0.055
0.044
0.036
0.059
0.77
0.11
0.36
0.023
0.023
0.031
0.031
0.0039
0.0039
0.055
0.061
0.11
0.028
0.11
0.036
0.088
0.090
0.23
0.059
0.21
0.025
0.054
0.044
0.044
0.72
0.85
0.036
0.036
0.017
0.20
Docunent
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
Treatnent
Standard ing/kg)
5.7
HR
NR
15
6.0
5.6
14
33
5.6
5.7
28
8.2
3.2
5.6
HR
0.087
0.087
0.087
0.087
0.087
0.087
8.2
HR
15
15
15
6.2
6.2
6.2
7.2
7.2
7.2
33
33
14
14
10
18
18
18
0.13
28
HR = Hot regulated. See Section 5.0 of the appropriate volune for discussion.
1-19
-------
Table 1-2 (Continued)
TREATHEHT STANDARDS FOR 0 AHD P WASTES AHD MULTI-SOURCE LEACHATE (F039)
INCLUDED IN VOLUKES A, B, AHD C; ALPHABETICALLY
Wastewater
Nonvastevater
Regulated Leacbate Constituents
2,4-Dinethylphenol
Dinethyl phthalate
Di-n-butyl pbthalate
1,4-Dinitrobenzene
4,6-Dinitro-o-cresol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octyl phthalate
Di-n-propylnitrosanine
1,4-Dioxane
Diphenylanine
1 , 2-Dipheny Ihydraz ine
Diphenylnitrosanine
Disulfoton
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Ethyl acetate
Ethyl benzene
Ethyl cyanide (Propanenitrile)
Ethyl ether
Ethyl nethacrylate
Ethylene oxide
Fanphur
Fluoranthene
Fluorene
Heptachlor
Heptachlor epoxide
Hexachlorobenzene
Bexachlorobutadiene
Hexachlorocyclopentadiene
Hexachlorodibenzofurans
Hexachlorodibenzo-p-dioxins
Hexachloroethane
Hexachloropropene
Indeno(l,2,3-c,d)pyrene
lodonethane
Isobutyl alcohol
Isodrin
Isosafrole
Kepone
Methacrylonitrile
Hethanol
Haste
Code
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
Docunent
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
Treatnent
Standard (ng/1)
0.036
0.047
0.057
0.32
0.28
Q.12
0.32
0.55
0.017
0.40
0.12
0.52
0.087
0.40
0.017
0.023
0.029
0.029
0.0028
0.025
0.34
0.057
0.24
0.12
0.14
0.12
0.017
0.068
0.059
0.0012
0.016
0.055
0.055
0.057
0.000063
0.000063
0.055
0.035
0.0055
0.19
5.6
0.021
0.081
0.0011
0.24
5.6
Docunent
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
Treatient
Standard (ng/kg)
14
28
28
2.3
160
160
140
28
28
14
170
tl?,
HK
UK
6.2
0.066
0.13
0.13
0.13
0.13
33
6.0
360
160
160
HK
15
8.2
4.0
0.066
0.066
37
28
3.6
0.001
0.001
28
28
8.2
65
170
0.066
2.6
0.13
84
MR
MR = Not regulated. See Section 5.0 of the appropriate voluae for discussion.
1-20
-------
Table 1-2 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND HULTI-SOCRCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C? ALPHABETICALLY
Mastevater
Noriwastewater
Regulated Leachate Constituents
Hethapyrilene
Hethoxychlor
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl nethacrylate
Methyl nethanesulfonate
Methyl parathion
3-Methylcholanthrene
4,4' -Nethy lenebis ( 2-chloroaniline)
Hethylene chloride
Naphthalene
2-Naphthylanine
p-Nitroaniline
Nitrobenzene
5-Nitro-o-toluidine
4-Nitrophenol
N-Nitrosodiethylanine
H-Nitrosodinethylanine
N-Nitrosodi-n-butylanine
N-Nitrosonethylethylanine
N-Nitrosouorpholine
N-Nitrosopiperidine
N-Nitrosopyrrolidine
Parathion
Pentachlorobenz ene
Pentachlorodibenzofurans
Pentachlorodibenzo-p-dionns
Pentachloronitrobenzene
Pentachlorophenol
Phenacetin
Phenanthrene
Phenol
Phorate
Phthalic anhydride
Pronanide
Pyrene
Pyridine
Safrole
Silvex (2,4,5-TP)
1,2,4, 5-Tetr achlorobenzene
Tetrachlorodibenzofurans
Tetrachlorodibenzo-p-dioxins
1,1,1, 2-Tetrachloroethane
1,1,2, 2-Tetrachloroethane
Tetrachloroethylene
Haste
Code
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
P039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
Docunent
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
'A
A
A
A
A
A
l
r.
A
A
A
A
A
A
A
A
A
A
A
A
A
Treatnent
Standard (ng/1)
0.081
0.25
0.28
0.14
0.14
0.018
0.014
0.0055
0.50
0.089
0.059
0.52
0.028
0.068
0.32
0.12
0.40
0.40
0.40
0.40
0.40
0.013
0.013
0.014
0.055
0.000063
0.000063
0.055
0.089
0.081
0.059
0.039
0.021
0.069
0.093
0.067
0.014
0.081
0.72
0.055
0.000063
0.000063
0.057
0.057
0.056
Docunent
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
Treatnent
Standard (ng/kg)
1.5
0.18
36
33
160
m
4.6
15
35
33
3.1
m
28
14
28
29
28
NR
17
2.3
2.3
35
35
4.6
37
0.001
0.001
4.8
7.4
16
3.1
6.2
4.6
NR
1.5
8.2
16
22
7.9
19
0.001
0.001
42
42
5.6
NR = Not regulated. See Section 5.0 of the appropriate volune for discussion.
1-21
-------
Table 1-2 (Continued)
TREATMENT STANDARDS FOR 0 AMD P WASTES AHD MULTI-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AMD C; ALPHABETICALLY
Wastevrater
Nonvastevater
Regulated Leachate Constituents
2,3,4, 6-Tetrachlorophenol
Toluene
Toxapbene
Tribrononethane (Bronoforn)
1,2, 4-Trichlorobenzene
1,1,1-Trichloroethane
1,1, 2-Tr icbloroethane
Trichloroethylene
TrichloroBonofluoronethane
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
2,4,5-Trichlorophenoxyacetic acid
1,2, 3-Trichloropropane
1,1, 2-Tr ichloro-1 , 2 , 2-trif luoroethane
Tris(2,3-dibronopropyl)phosphate
Vinyl chloride
Xylenes
Cyanides (Total)
Fluoride
Sulfide
Antimony
Arsenic
Bariua
Berylliun
Cadniuo
Chroniun (total)
Copper
Lead
Mercury
Nickel
Seleniua
Silver
Thalliun
Vanadiun
Zinc
Waste
Code
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
Docunent
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
Treatnent
Standard (ng/1)
0.030
0.080
0.0095
0.63
0.055
0.054
0.054
0.054
0.020
0.18
0.035
0.72
0.85
0.057
0.11
0.27
0.32
1.2
35
14
1.9
1.4
1.2
0.82
0.20
0.37
1.3
0.28
0.15
0.55
0.82
0.29
1.4
0.042
1.0
Docunent
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
Treatnent
Standard (ng/kg)
37
28
1.3
15
19
5.6
5.6
5.6
33
37
37
7.9
28
28
m
33
28
1.8
NR
HR
TCLP (ng/1)
0.23
5.0 §
52
NR
0.066
5.2
HR
0.51
0.025
0.32
5.7
0.072
HR
NR
HR
NR = Not regulated. See Section 5.0 of the appropriate volune for discussion.
§ Based on EP Toxicity.
1-22
-------
TABLE 1-3
BOAT TREATMENT STANDARDS FOR ORGANIC CONSTITOENTS IN
D AND P WASTEWATERS
REGCLATH) TOTAL
ORGANIC COMPOSITION
COHSTITUEHTS (Dg/1)
P003 Acrolein 0.29
P004 Aldrin ,., 0.021
P020 2-sec-Butyl-4.6-dimtrophenol 0.066
P022 Carbon disulfide 0.014
P024 p-Chlor.oaniline 0.46
P037 Dieldrin 0.017
P047 4,6-Dinitro-o-cresol 0.28
P048 -2,4-Dinitrophenol 0.12
P050 Endosulfan 1 0.023
P050 Endosulfan II 0.029
P050 Endosulfan sulfate 0.029
P051 Endrjn aldehyde 0.025
P051 Endrin ..., 0.0028
P059 Heptachlor epoxide 0.016
P059 Heptachlor..:; 0.0012
P060 Isodrin..,., 0.021
P077 p-N;troaniUne 0.028
P082 N-Nitrosodinethylanine 0.40
P101 Ethyl cyanide..! 0.24
P123 Toxaphene 0.0095
D002 Acetone 0.28
0003 Acetonitrile 0.17
0004 Acetophenone 0.010
0005 2-Acetylaninofluorene 0.059
0009 Acrvlonitrile 0.24
0012 Aniline 0.81
0017 Benzal chloride 0.055
0018 Benz(a)anthracene '. 0.059
0019 Benzene 0.14
0022 Benzo(a)pyrene 0.061
0024 bis 2-cMoroethoxy)nethane 0.036
0025 b^s 2-chloroethyl)ether 0.033
0027 bis 2-chloroisopropyl)ether 0.055
U029 BroBonetfiane. 0.11
0030 4-Bronopbenyl phenyl ether 0.055
0031 n-Butvl alcohol.... 5.6
0036 Chlorfene 0.0033
0037 chlorobenzene 0.057
0038 Chlorobenzilate 0.10
U039 p-Chloro-B-cresol 0.018
0043 vinyl chloride 0.27
C044 Chlorofom 0.046
0045 Chloronethane 0.19
U047 2-Chloronaphthalene 0.055
U048 2-Chlorophenol 0.044
0050 Chrysene 0.059
0051 Pentachlorophenol 0.089
0051 Phenanthrenfe 0.059
0051 Pvrene 0.067
0052 ueta/para-Cresol 0.77
0052 orthoiCresol 0.11
0057 Cyclohexanone 0.36
0060 oJp'-DDD 0.023
0060 p,p'-DDD 0.023
1-23
-------
TABLE 1-3 (Continued)
BDAT TREATHENT STANDARDS FOR ORGANIC CONSTITUENTS IN
D AMD P WASTEWATERS
REGULATED TOTAL
ORGANIC COMPOSITION
CONSTITUENTS (ng/1)
D061 o,
C061 p,
D061 o,
U061 p,
U061 0
C061
p'-DDD 0.023
,p'-DDD 0.023
p'-DDE 0.031
, >'-DDE 0.031
f'-DDT 0.0039
)'-DDT 0.0039
C063 Dibenz?a,h)anthracene 0.055
U066 l,2-Dibrono-3-chloropropane 0.11
C067 1,2-Dibromoethane 0.028
C068 Dibrouonethane 0.11
U0?o o-Dichlorobenzene 0.083
C071 n-D;chlorobenzene 0.036
U072 p-Dichlorobenzene 0.090
U073 3,3'-Dichlorobenzidine 0.13
D074 cis-l,4-Dichloro-2-butene 0.036
U074 trans-1,4-Dichloro-2-butene 0.036
0075 Dichlorodifluoronethane 0.23
0076 1,1-Djchloroethane... 0.059
C077 1 2-D;chloroethane 0.21
0078 1,1-Dichloroethylene 0.025
D079 tfans-l,2-Dichl6roethene 0.054
C080 Kethviene chloride 0.089
0081 2,4-Dichlorophenol 0.044
0082 2,6-Dichlorobhenol 0.044
0083 1,2-Dichlo.ropropane 0.85
0084 cis-l.S-Dicbloropropene 0.036
U084 trans-1,S-Dichloroprppene 0.036
0091 3,3'-Dinetho?ybenzidine 0.13
U093 p-DiBethylaninoazobenzene 0.130
0101 2,4-DJBethylphenol 0.036
0105 2,4-Dinitroto:
0106 2,6-Dinitroto^
uene '. 0.32
.uene 0.55
0108 M-Dioxane 0.12
Olll Di-n-propylnitrosoanine 0.40
0112 Ethyrac&tate 0.34
0117 Ethyl ether 0.12
0118 Ethyl nethacrylate 0.14
0120 Fl\ioranthene.. 0.068
0121 TrichloroDonof luoronethane 0.020
0127 Hexachlorobenzene 0.055
0128 Hexachlorobutadiene 0.055
0129 alpha-BHC 0.00014
C129 beta-BHC 0.00014
0129 delta-BHC 0.023
C129 ganna-BHC 0.0017
1130 Hexachlorocyclopentadiene 0.057
0131 Hexachloroethane 0.055
0137 Indeno(l,2,3-cd)pyrene 0.0055
0138 lodonethane '. 0.19
0140 Isobutyl alcohol 5.6
0141 Isosaffole 0.081
0142 Kepone 0.0011
1-24
-------
TABLE 1-3 (Continued)
BOAT TREATMENT STANDARDS FOR ORGANIC CONSTITUENTS IN
D AMD P HASTEWATERS
MGULATED " TOTAL
ORGANIC COMPOSITION
COHSTITCEHTS Ing/l)
D152 Methacrylonitrile 0.24
0155 Nethapyhlene 0.081
D157 3-Betnvlchloanthrene , 0.0055
0158 4,4'-Methylenebis (2-chloranihne) 0.50
0159 Methyl ethyl ketone 0.28
C161 Methyl isobutyl ketone 0.14
C162 Methyl nethacfylate 0.14
0165 Naphthalene 0.059
D168 2-Haphthylanine 0.52
0169 Nitrobenzene 0.068
0170 4-Nitrophenol , 0.12
U172 N-Hitroiodi-n-butylanine 0.400
0174 H-Hitrosodiethylanine 0.40
0179 N-Njtrosoplperidine 0.013
0180 H-H}tr<>sopyrroU3ine 0.013
0181 5-Nitro-o-tolmdine 0.32
0183 Pentachlorobenzene 0.055
U185 Pentachlpronitrobenzene 0.055
0187 Phenacetin 0.081
0188 PhenoL 0.039
0192 Prona^ide 0.093
0196 Pyridine 0.014
0203 Sifrole 0.081
0207 1,2,4,5-Tetrachlorobenzene 0.055
0208 1,1,1,2-Tetrachloroethane 0.057
0209 1,1,2 2-TetracHoroethane 0.057
0210 Tetracbloroethene 0.056
0211 Carbon tetrachloride 0.057
0220 Tojuene 0.080
0225 Tribronopthane (broooforn) 0.63
0226 1,1,1-Tqchloroethane 0.054
0227 1 1,2-Trichloroethane 0.054
0228 Trichloroethene 0.054
0239 Xylene(s) 0.32
0240 2,4-Dichlorophenoxyacetic acid 0.72
0243 Hexachloropropene 0.035
0247 Hethoxyclor 0.25
1-25
-------
Table 1-4
- BOAT TREATMENT STANDARDS FOR MULTI-SOURCE LEACHATE (P039)
HASTEWATERS
Maxima for any
24 Hr. Conposite
Regulated Organic and
Inorganic Constituents
Acenaphthalene
Acenaphthene
Acetone
Acetonitrile
Acetopbenone
2-Acetylaninofluorene
Acrolein
Acrylonitrile
Aldrin
4-Aninobiphenyl
Aniline
Anthracene
Aranite
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
Benz(a)anthracene
Benzene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(g,h,i)perylene
Benzoi a ipyrene
alpha-BHC
beta-BHC
delta-BBC
ganna-BHC (Lindane)
Bis ( 2-chloroetboxy ) nethane
Bis ( 2-chloroethy 1 ) ether
Bis ( 2-chloroisopropy 1 ) ether
Bis( 2-ethylhexyl)phthalate
BroDodichloronethane
Brououe thane (Methyl bronide)
4-Bronophenyl phenyl ether
n-Butyl alcohol
Butyl benzyl phthalate
2-sec-Butyl-4;6-dinitrophenol (Dinoseb)
Carbon disulfide
Carbon tetrachloride
Chlordane (alpha and ganna)
p-Chloroaniline
Waste
Code
F039
F039
F039.
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
Total Conposition
(•q/D
0.059
0.059
0.28
0.17
0.010
0.059
0.29
0.24
0.021
0.13
0.810
0.059
0.36
0.013
0.014
0.013
0.017
0.013
0.014
0.014
0.059
0.140
0.055
0.059
0.0055
0.061
0.00014
0.00014
0.023
0.0017
0.036
0.033
0.055
0.28
0.35
0.11
0.055
5.6
0.017
0.066
0.014
0.057
0.0033
0.46
1-26
-------
Table 1-4 (Continued)
- BOAT TREATMENT STANDARDS FOR MDLTI-SODRCE LEACHATE (P039)
WASTEWATERS
Maxima for any
24 Hr. Composite
Regulated Orqanic and
Inorganic Constituents
Chlorobenzene
Chlorobenzilate
2-Chloro-l , 3-butadiene
Chlorodibronone thane
Chloroethane
Chlorofora
p-Chloro-D-cresol
Chloronethane (Kethyl chloride)
2-Chloronaphthalene
2-Chlorophenol
3-Chloropropene
Chrysene
Cresol (D- and p- isoners)
o-Cresol
Cycloheianone
o,p'-DDD
p,p'-DDD
0,p'-DDE
p,p'-DDE
o,p'-DDT
Plp'-DDT
Dibeni( a ,h) anthracene
Dibenzo(a,e)pyrene
1 , 2-Dibroao-3-chloropropane
1,2-DibroDoethane (Ethylene dibronide)
Dibrouone thane
n-Dichlorobenzene
o-Dichlorobenzene
p-Dichlorobenzene
Dichlorodifluoronethane
1,1-Dichloroethane
1,2-Dichloroe thane
1,1-Dichloroethylene
trans-l , 2-Dichloroethylene
2,4-Dichlorophenol
2,6-Dichlorophenol
2,4-Dichlorophenoxyacetic acid
1,2-Dichloropropane
cis-1 , 3-Dichloropropene
trans-l ,3-Dichloropropene
Dieldrin
Die thy 1 phthalate
Waste
Code
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
P039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
Total Opposition
(•g/i)
0.057
0.10
0.057
0.057
0.27
0.046
0.018
0.19
0.055
0.044
0.036
0.059
0.77
0.11
0.36
0.023
0.023
0.031
0.031
0.0039
0.0039
0.055
0.061
0.11
0.028
0.11
0.036
0.088
0.090
0.23
0.059
0.21
. 0.025
0.054
0.044
0.044
0.72
0.85
0.036
0.036
0.017
0.20
1-27
-------
Table 1-4 (Continued)
BOAT TREATMENT STANDARDS FOR KULTI-SODRCE LEACHATE (P039)
WASTEWATERS
Haxinun for any
24 Hr. Conposite
Regulated Organic and
Inorganic Constituents
2,4-Dinethylphenol
Dimethyl phthalate
Di-n-butyl phthalate
1,4-Dinitrobenzene
4,6-Dinitro-o-cresol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octyl phthalate
Di-n-propylnitrosanine
1,4-Dioxane
Diphenylanine
1,2-Diphenylhydrazine
Diphenylnitrosanine
Disulfoton
Endosulfan I
Endosulfan II
Endosulfan sulf ate
Endrin
Endrin aldehyde
Ethyl acetate
Ethyl benzene
Ethyl cyanide (Propanenitrile)
Ethyl ether
Ethyl nethacrylate
Ethylene oxide
Fanphur
Fluoranthene
Fluorene
Heptachlor
Beptachlor epoxide
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachlorodibenzofurans
Hexachlorodibenzo-p-dioxins
Hexachloroethane
Hexachloropropene
Indeno(l,2,3-c,d)pyrene
lodoaethane
Isobutyl alcohol
Isodrin
Isosafrole
Kepone
Hethacrylonitrile
Hethanol
Haste
Code
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039 .
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
Total Conposition
(•g/D
0.036
0.047
0.057
0.32
0.28
0.12
0.32
0.55
0.017
0.40
0.12
0.52
0.087
0.40
0.017
0.023
0.029
0.029
0.0028
0.025
0.34
0.057
0.24
0.12
0.14
0.12
0.017
0.068
0.059
0.0012
0.016
0.055
0.055
0.057
0.000063
0.000063
0.055
0.035
0.0055
0.19
5.6
0.021
0.081
0.0011
0.24
5.6
1-28
-------
Table 1-4 (Continued)
- BOAT TJEATHEHT STANDARDS FOR NULTI-SOCRCE LEACHATE (P039)
WASTEWATERS
Maxima for any
24 Hr. Conposite
Regulated Organic and
Inorganic Constituents
Hetbapyrilene
Nethoxychlor
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl nethacrylate
Methyl nethanesulfonate
Methyl parathion
3-Hethylcholanthrene
4,4'-Hethylenebis(2-chloroaniline)
Nethylene chloride
Naphthalene
2-NapbthylaDine
p-Hitroaniline
Nitrobenzene
5-Hitro-o-toluidine
4-Hitropbenol
H-Bitrosodietbylanine
H-Hitrosodiaethylaaine
N-Hitrosodi-n-butylaiiine
N-Nitrosonethylethylanine
H-NitrosoDorpholine
H-Nitrosopiperidine
N-Hitrosopyrrolidine
Parathion
Pentachlorobenzene
Pentachlorodibenzofurans
Pentachlorodibenzo-p-dioxins
Pentachloronitroben z ene
Pentachlorophenol
Phenacetin
Phenanthrene
Phenol
Phorate
Phthalic anhydride
Pronanide
Pyrene
Pyridine
Safrole
Silvex |2,4,5-TP)
1,2,4, 5-Tetrachlorobenzene
Tetrachlorodibenzofurans
Tetrachlorodibenzo-p-dioxins
1,1,1, 2-Tetrachloroethane
1,1,2, 2-Tetrachloroethane
Tetrachloroethylene
Waste
Code
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
>039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
Total Conposition
fng/D
0.081
0.25
0.28
0.14
0.14
0.018
0.014
0.0055
0.50
0.089
0.059
0.52
0.028
0.068
0.32
0.12
0.40
0.40
0.40
0.40
0.40
0.013
0.013
0.014
0.055
0.000063
0.000063
0.055
0.089
0.081
0.059
0.039
0.021
0.069
0.093
0.067
0.014
0.081
0.72
0.055
0.000063
0.000063
0.057
0.057
0.056
1-29
-------
Table 1-4 (Continued)
-BOAT TREATMENT STANDARDS FOR HCITI-SOCRCE LEACHATE (P039)
HASTEWATERS
Maximal for any
24 Hr. Composite
Regulated Organic and
Inorganic Constituents
2,3,4, 6-Tetrachlor ophenol
Toluene
Toxapbene
TribroQonethane (Bronoforn)
1,2, 4-Tr ichlorobenz ene
1,1,1-Trichloroethane
1,1, 2-Tr ichloroethane
Trichloroethylene
Trichlorononofluoronethane
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
2 , 4 , 5-Tr ichlorophenoxy acetic acid
1,2, 3-Tr ichloropropane
1,1, 2-Tr ichloro-1 , 2 , 2-tr if luoroe thane
Tris(2,3-dibronopropyl)phosphate
Vinyl chloride
Xylenes
Cyanides (Total)
Fluoride
Sulfide
Antinony
Arsenic
Bariua
Berylliun
Cadniun
Chroniua (total)
Copper
Lead
Mercury
Nickel
SeleniuB
Silver
Thalliun
Vanadiun
Zinc
Waste
Code
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
Total Composition
(nq/D
0.030
0.080
0.0095
0.63
0.055
0.054
0.054
0.054
0.020
0.18
0.035
0.72
0.85
0.057
0.11
0.27
0.32
1.2
35
14
1.9
1.4
1.2
0.82
0.20
0.37
1.3
0.28
0.15
0.55
0.82
0.29
1.4
0.042
1.0
1-30
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2.0 INDUSTRY AFFECTED AND WASTE CHARACTERIZATION
This section describes the industries affected by the land disposal
restrictions for the wastes listed in Tables 1-3 and 1-4, the processes
generating the wastes, the available waste characterization data, and the
determination of waste treatability groups.
2.1 Industry Affected
2.1.1 U and P Wastes
A U or P waste consists of a commercial chemical product or
manufacturing intermediate from a non-specific source containing any of the
chemicals listed in 40 CFR 261.33(e) or (f) and in which the listed chemical
is the sole active ingredient. Commercial chemical products or manufacturing
intermediates include all commercially pure grades of the listed chemical, all
technical grades, and all formulated products in which the listed chemical is
the sole active ingredient. In addition, an off-specification product that,
if it met specification, would have the generic name included in either
261.33(e) or (f) is a U or P waste. Any residue that is a listed chemical
remaining in a container or inner liner removed from a container that will noc
be recycled, reclaimed, or reused; or any residue or contaminated soil, water,
or debris from a spill of such a chemical is also a U or P waste. However,
these wastes do not include manufacturing process wastes. A waste occurs when
a product is:
• Discarded or intended to be discarded;
• Mixed with another material and applied to the land for dust
suppression of road treatment;
• Applied to land in lieu of its original intended use; or
• Distributed or burned as a fuel or fuel additive.
2-1
-------
U wastes are identified as toxic; P wastes are identified as acutely
hazardous. Whether a waste is acutely hazardous or toxic generally has no
bearing on its treatability.
Industries that generate the wastes listed in Tables 1-3 and 1-4
include organic chemical, agricultural chemical, pharmaceutical, pesticide,
plastic and resin, cosmetic and fragrance, paint, leather and tanning, and
rubber industries; universities; military compounds; and treatment and
disposal facilities throughout the United States. The tables in Appendix A
identify the industrial uses of the commercial chemical products included in
Table 1-3 and summarize the total number of facilities that may generate these
wastes. The number of facilities that may generate each waste code are listed
by state and by EPA region.
2.1.2 Multi-source Leachate
"Leachate" is defined in 40 CFR 260.10 as "any liquid, including any
suspended components in the liquid, that has percolated through or drained
from hazardous waste". Leachate that is derived from the treatment, storage,
or disposal of listed hazardous waste is classified as a hazardous waste by
virtue of the "derived-from" rule in 40 CFR 261.3(c)(2). Multi-source
leachate is leachate that is derived from the treatment, storage, or disposal
of more than one listed hazardous waste or is leachate generated via contact
with more than one hazardous waste. (Leachate that is generated from the
treatment, storage, or disposal of only one listed hazardous waste and does
not come in contact with any other listed hazardous waste is a single-source
leachate subject to the treatment standards established for the waste from
which it is derived.)
Multi-source leachate is most often generated by hazardous waste
treatment, storage, and disposal (TSD) facilities although generators who
accumulate more than one hazardous waste on site may also generate multi-
source leachate. An example of multi-source leachate is liquid draining into
soils from a landfill unit that stores more than one hazardous waste.
2-2
-------
2.2 Waste Characterization
Waste characterization data are not currently available for the U
and P wastes included in this document. Limited multi-source leachate
characterization data were submitted during the comment period and are
presented in Table A-4 of Appendix A. Due to the diversity of methods of
waste generation, the composition of U and P wastes and multi-source leachate
varies greatly. The constituents of concern may be present at concentrations
varying from parts per billion in a waste to nearly 100% in a waste generated
from virtually pure product.
2.3 Determination of Waste Treatabilitv Groups
The U and P wastes included in this document were combined into
treatability groups based on similarity in elemental composition and
functional groups within the structure of the chemical. These groupings are
presented in Appendix B.
2-3
-------
3.0 IDENTIFICATION OF THE BEST DEMONSTRATED AVAILABLE TECHNOLOGY (BOAT)
This section presents the Agency's rationale for determining the
best demonstrated available technology (BOAT) for BOAT List constituents in
wastewater forms of multi-source leachate and organic constituents in
wastewater forms of U and P wastes for which a concentration-based treatment
standard has been set. Concentration-based treatment standards for these
wastewaters have been developed based on wastewater treatment data from
several sources and technologies.
This section presents the Agency's determination of:
• Applicable technologies;
• Demonstrated technologies; and
• Best demonstrated available technology (BOAT) for treatment of
these wastes.
In determining BOAT, the Agency first determines which technologies are
potentially "applicable" for treatment of the waste(s) of interest. The
Agency then determines which of the applicable technologies are "demonstrated"
for treatment of the waste(s) of interest. The next step is to determine
which of the demonstrated technologies is "best" for the purposes of
establishing BDAT. Finally, the Agency determines whether the best
demonstrated technology is available for treatment of the waste(s) of
interest. Integral to the determination of BDAT is the evaluation of all
available treatment performance data. The treatment performance data that
were evaluated to determine BDAT for these wastes are presented in
Section 4.0.
All of the constituents of interest in U and P wastewaters included
in this document are organic. Therefore, the treatment technologies
identified for U and P waste constituents and organic multi-source leachate
constituents are for treatment of hazardous organic constituents. Multi-
source leachates may also contain inorganic and metal constituents at
treatable concentrations and the Agency is therefore also identifying
technologies for treatment of inorganic and metal constituents.
3-1
-------
3.1 Applicable Treatment Technologies
To be applicable, a technology must theoretically be usable to treat
the waste. Detailed descriptions of technologies that are applicable to treat
listed hazardous wastes are provided in EPA's Treatment Technology Background
Document (Reference 17).
3.1.1 Organics
Since wastewater forms of U and P wastes and multi-source leachate
may contain hazardous organic constituents at treatable concentrations,
applicable technologies include those that destroy or reduce the total amount
of various organic compounds in the wastewater. Therefore, the Agency has
identified the following treatment technologies as potentially applicable for
treatment of these wastes:
• Biological Treatment (including aerobic fixed film, aerobic
lagoons, activated sludge, anaerobic fixed film, rotating
biological contactors, sequential batch reactor, and trickling
filter technologies);
• PACT" Treatment (including powdered activated carbon addition
to activated sludge and biological granular activated carbon
technologies);
• Carbon Adsorption Treatment (including activated carbon and
granular activated carbon technologies);
• Solvent Extraction Treatment (including liquid, liquid
extraction technology);
• Chemical Oxidation Treatment;
• Wet Air Oxidation Treatment (including supercritical oxidation
technology);
• Stripping Treatment (including steam stripping and air
stripping technologies);
• Reverse Osmosis Treatment; and
• Chemically Assisted Clarification Treatment (including chemical
precipitation technology).
3-2
-------
Total recycle or reuse may also be applicable for certain wastewaters. These
treatment technologies were identified based on current waste treatment
practices and engineering judgment.
The concentrations and type(s) of waste constituents present in the
waste generally determine which technology is most applicable. Carbon
adsorption, for example, is often used as a polishing step following primary
treatment by biological treatment, solvent extraction, or wet air oxidation.
Typically, carbon adsorption is applicable for treatment of wastewaters
containing less than 0.1% total organic constituents. Wet air oxidation,
PACT" treatment, biological treatment, and solvent extraction are applicable
for treatment of wastewaters containing up to 1% total organic constituents.
Some of the wastewaters that are the subject of this document may contain
constituents that are too toxic to biomass and therefore cannot be treated
effectively by biological treatment or PACT0 treatment.
Biological Treatment
Biological treatment is a destruction technology in which hazardous
organic constituents in wastewaters are biodegraded. This technology
generates two treatment residuals: a treated effluent and a waste biosludge.
Waste biosludge may be land disposed without further treatment if it meets the
applicable BOAT nonwastewater treatment standards for regulated constituents.
PACT" Treatment
PACTR treatment is a combination of carbon adsorption and biological
treatment in which hazardous organic constituents are biodegraded or
selectively adsorbed onto powdered-activated carbon. This technology
generates two treatment residuals: a treated effluent and spent
carbon/biosludge. The spent carbon may be regenerated and recycled to the
process or may be incinerated.
3-3
-------
Carbon Adsorption
Carbon adsorption is a separation technology in which hazardous
organic constituents in wastewaters are selectively adsorbed onto activated
carbon. This technology generates two treatment residuals: a treated
effluent and spent activated carbon. The spent activated carbon can be
reactivated, recycled, or incinerated.
Solvent Extraction
Solvent extraction is a separation technology in which organics are
removed from the waste due to greater constituent solubility in the solvent
phase than in the waste phase. This technology generates two residuals: a
treated waste residual and an extract. The extract may be recycled or treated
by incineration.
Chemical Oxidation
Chemical oxidation is a destruction technology in which inorganic
cyanide, some dissolved organic compounds, and sulfides are chemically
oxidized to yield carbon dioxide, water, salts, simple organic acids,
and sulfates. This technology generates one treatment residual: treated
effluent.
Wet Air Oxidation
Wet air oxidation is a destruction technology in which hazardous
organic constituents in wastes are oxidized and destroyed under pressure at
elevated temperatures in the presence of dissolved oxygen. This technology is
applicable for wastes comprised primarily of water and up to 10% total organic
constituents. Wet air oxidation generates one treatment residual: treated
effluent. The treated effluent may require further treatment for hazardous
organic constituents by carbon adsorption or PACT8 treatment. Emissions from
wet air oxidation may also require further treatment.
3-4
-------
Stripping Treatment
Stripping treatment is a separation technology. Steam stripping is
a technology in which wastewaters containing volatile organics have the
organics removed by application of heat using steam as the heat source. Air
stripping is a technology in which wastewaters containing volatile organics
have the organics removed by volatilization. This technology generates one
treatment residual: treated effluent. Emissions from stripping treatment may
require further treatment.
Reverse Osmosis
Reverse osmosis is a separation technology in which dissolved
organics (usually salts) are removed from a wastewater by filtering the
wastewater through a semipermeable membrane at a pressure greater than the
osmotic pressure caused by the dissolved organics in the wastewater. This
technology generates two treatment residuals: the treated effluent wastewater
and the concentrated organic salt materials which do not pass through the
membrane.
Chemically Assisted Clarification
Chemically assisted clarification, including chemical precipitation,
is a separation technology in which the additional of chemicals during
treatment results in the formation of insoluble solid precipitates from the
organics or inorganics in the wastewater. The solids formed are then
separated from the wastewater by settling, clarification, and/or polishing
filtration. This technology generates two treatment residuals: treated
wastewater effluent and separated solid precipitate. The solid precipitate
would then require additional treatment as specified by the nonwastewater BOAT
treatment standards.
3-5
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3.1.2 Inorganics
Since wastewater forms of multi-source leachate may contain
inorganic constituents (i.e., cyanide, sulfide, fluoride) at treatable
concentrations, applicable technologies include those that destroy or reduce
the total amount of various inorganic compounds in the wastewater. Therefore,
the Agency has identified the following treatment technologies as potentially
applicable for treatment of these wastes:
• Biological Treatment (including activated sludge, aerobic
lagoons, rotating biological contactors, and trickling filter
technologies);
• Carbon Adsorption Treatment (including activated carbon
technology);
• Solvent Extraction Treatment (including liquid, liquid
extraction);
• Chemical Oxidation Treatment (including cyanide oxidation,
chemical oxidation with chlorine, and chemical oxidation
followed by precipitation);
• Wet Air Oxidation Treatment;
• Stripping Treatment (including steam stripping);
• Reverse Osmosis Treatment;
• Chemically Assisted Clarification Treatment (including chemical
precipitation and lime and settle and filter technologies); and
• Activated Alumina Sorption Treatment.
As previously discussed, the concentrations and type(s) of waste constituents
present in the waste generally determine which technology is most applicable.
The applicable technologies for inorganics in wastewaters are described under
the organic technology descriptions. Activated alumina sorption treatment is
similar to the carbon adsorption technology described above, but uses an
activated alumina material instead of activated carbon.
3-6
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3.1.3 Metals
Since wastewater forms of these wastes may contain metal
constituents at treatable concentrations, applicable technologies include
those that destroy or reduce the total amount of various metal compounds in
the wastewater. Therefore, the Agency has identified the following treatment
technologies as potentially applicable for treatment of these wastes:
• Biological Treatment (including activated sludge, aerobic
lagoons, rotating biological contactors, and trickling filter
technologies);
• PACT8 Treatment;
• Chemical Oxidation Treatment (including chemical oxidation
followed by precipitation technologies);
• Chemically Assisted Clarification Treatment (including chemical
precipitation and chemical precipitation followed by filtration
technologies);
• Lime, sedimentation, filtration treatment; and
• Chemical Reduction Treatment (including chemical
reduction/precipitation followed by sedimentation and
filtration technologies).
The applicable technologies for metals in wastewaters are described under the
organic technology descriptions with the following additions:
Lime. Sedimentation. Filtration
Lime, sedimentation, and filtration is a separation technology in
which hazardous metal constituents in wastewater are mixed with lime to
produce an insoluble metal oxide material that settles out of solution in the
wastewater. The metal oxide precipitate is then filtered out of the
wastewater solution. This technology generates two treatment residuals: a
treated effluent and filter cake containing lime and metal oxides. The filter
cake may require additional treatment, prior to land disposal, to meet
applicable nonwastewater treatment standards for regulated constituents
remaining in the filter cake.
3-7
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Chemical Reduction
Chemical reduction followed by precipitation is a separation
technology in which hazardous metal constituents are chemically reduced from a
higher oxidation state to a lower oxidation state. The reduced metal is then
in a form amenable to chemical precipitation and subsequent sedimentation
and/or filtration. This technology generates two treatment residuals: a
treated effluent and a settled or filtered solid containing the precipitated
metal. The solid residual may require additional treatment, prior to land
disposal, to meet applicable nonwastewater treatment standards for regulated
constituents remaining in the residual.
3.2 Demonstrated Treatment Technologies
To be demonstrated, a technology must be employed in full-scale
operation for treatment of the waste in question or a similar waste.
Technologies available only at pilot- or bench-scale operations are not
considered in identifying demonstrated technologies.
All of the technologies identified as applicable for organic,
inorganic, and metal constituents in multi-source leachate and organic U and P
wastewaters have been demonstrated in full-scale operation for treatment of
wastewaters containing these various constituents or similar constituents.
The data presented in Section 4.0 are from full-scale treatment by these
technologies. The Agency, therefore, believes that all of the technologies
presented in Section 3.1 can be considered further to determine BDAT.
3.3 Identification of Best Demonstrated Available Technology (BDAT)
Best demonstrated and available technology (BDAT) is determined
based on a thorough review of all the treatment data available on the waste of
concern or waste judged to be similar. The treatment performance data that
were evaluated for these wastes are presented in Section 4.0.
3-8
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As described in EPA's methodology document (Reference 1), once
applicable and demonstrated treatment technologies are determined for the
wastes of interest, treatment performance data are examined to identify the
technologies that perform "best." Following the identification of best, the
Agency determines whether the best demonstrated technology is "available". An
available treatment technology is one that (1) is not a proprietary or
patented process that cannot be purchased or licensed from the proprietor
(i.e., it must be commercially available), and (2) substantially diminishes
the toxicity of the waste or substantially reduces the likelihood of migration
of hazardous constituents from the waste.
The "best" demonstrated technology was determined for each
constituent following a thorough review of all data available on the treatment
of that constituent. The actual best and resulting BOAT selected for each
constituent is described along with the presentation of treatment performance
data in Section 4.0.
To determine "best," a hierarchy was established to evaluate the
data presented in Section 4.0. In general, the Agency believes that data from
the ITD and BOAT programs should be used instead of data from other sources.
The ITD database represents a very comprehensive source of wastewater
treatment data and usually represents longer term sampling with a greater
number of sample sets than other wastewater treatment data bases. Data
generated as part of the BOAT program represent controlled tests and follow
EPA protocols for sampling and analysis procedures. The following outlines
the methodology used to determine "best" for wastewater constituents that are
included in this document:
(1) For any volatile, semivolatile, and metal constituent with ITD
performance data and a promulgated ITD effluent limitation, the
ITD data were used to calculate the BDAT treatment standard for
that constituent. The data representing ITD Option I2 were
used in all cases.
2A discussion of ITD's Option I is presented in Reference 11.
3-9
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(2) For any constituent for which promulgated ITD standards (based
~ on actual treatment performance data) do not exist, data from
an Agency-sponsored BDAT wastewater treatment test were used to
determine the BDAT treatment standard for that constituent
(when it was available).
(3) For any constituent with industry-submitted leachate treatment
performance data, where the data showed substantial treatment
and the data were considered better or more representative of
treatment performance than Agency data, the Agency used the
industry-submitted leachate data to calculate the BDAT
concentration-based standard.
(4) For any constituent without ITD data, BDAT wastewater treatment
test data, or industry-submitted leachate treatment performance
data showing substantial treatment, other available treatment
performance data were evaluated to determine BDAT and were used
to calculate the BDAT concentration-based standard. Considered
in this evaluation were the treatment technology for which data
were available, whether the data represented a full-, pilot- or
bench-scale technology, the concentration of the constituent of
interest in the influent to treatment, the average
concentration of the constituent of interest in the effluent
from treatment, and the removal efficiency of the treatment
technology. Full-scale treatment data with an influent
concentration range greater than 100 ppb were preferred over
pilot- or bench-scale data and preferred over data with a low
(i.e., 0-100 ppb) influent concentration range. If several
sets of data met these criteria (i.e., full-scale available
technologies with high influent concentrations) they were
compared by examination of their average effluent values and
percent removals to determine the data set(s) which had the
lowest effluent values and the technology with the highest
percent removal.
(5) For any constituent where treatment performance data were not
available from any of the examined sources, data were
transferred for calculation of a BDAT treatment standard from a
similar constituent in a waste judged to be similar.
Several deviations from the above hierarchy were necessary due to
the data available for specific constituents. These deviations are discussed
in the constituent discussions in Section 4.0.
The demonstrated technologies identified in Section 3.2 and
determined to be best for each constituent as identified in Section 4.0 are
all commercially available. In addition, treatment performance data included
3-10
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in Section 4.0 show substantial treatment of the constituent for which the
technology was selected. Therefore, the technologies selected as best and
demonstrated for each constituent are also considered to be available, and
therefore, BDAT for that constituent.
3-11
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4.0 TREATMENT PERFORMANCE DATABASE
This section presents the wastewater treatment performance data
available to the Agency for each BOAT List constituent. This section also
discusses the use of the data to determine BOAT and to calculate treatment
standards for each constituent being regulated in wastewater forms of multi-
source leachate and each organic constituent in U and P wastewaters. Section
4.1 gives a brief description of each data source examined for applicable
wastewater treatment performance data. Sections 4.2 to 4.10 present, on a
constituent-by-constituent basis, the wastewater treatment performance data
considered in determining BOAT. The tables in Sections 4.2 to 4.10 are
organized by constituent type (i.e., volatiles, semivolatiles, metals, etc.)
and each section is preceded by an index of the constituents presented in that
section.
The tables in this section present the available treatment
performance data for each constituent. The data used to determine the
proposed BOAT treatment standard are shown with an asterisk. The constituent
discussions that precede the data tables indicate whether the promulgated BOAT
technology differs from that proposed and present any additional data that may
have been considered in determining the final concentration-based treatment
standard.
4.1 Sources of Treatment Data
This section describes each of the wastewater treatment performance
data sources used to determine BOAT for wastewater forms of multi-source
leachates and organic U and P wastes.
4.1.1 BOAT Database
The BDAT database consists of treatment performance data collected
to establish treatment standards in the First, Second, and Third Third BDAT
land disposal restrictions program.
4-1
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Extensive sampling of incineration systems has been conducted under
the BDAT program. As part of these sampling episodes, incineration scrubber
water data have been collected to set BDAT standards for wastewater forms of
specific hazardous waste codes. In the case of wastewater forms of organic U
and P wastes and multi-source leachate, the Agency prefers to use appropriate
wastewater treatment data from well-designed and well-operated wastewacer
treatment units rather than scrubber water concentrations to develop
wastewater treatment standards. (This does not, however, preclude the Agency
from establishing treatment standards for other wastes based on constituent
concentrations in incinerator scrubber waters.) Therefore, treatment
performance data that represented a specific technology applicable to
wastewater treatment, such as biological treatment or chemical precipitation,
were used from the BDAT database.
BDAT wastewater treatment performance data were available from waste
codes K103, K104, and K062 from the First and Second Third group of wastes.
The wastewater treatment technologies represented by these codes include
liquid, liquid extraction, steam stripping, and activated carbon for organics
and chromium reduction followed by chemical precipitation, sedimentation, and
filtration for metals.
Additionally, as part of the development of the final rule
restricting the land disposal of solvent wastes F001-F005, the Agency examined
data from ITD sampling episodes, which were presented in the F001-F005
background document (Reference 4). The technologies examined for these codes
included biological treatment, activated carbon, steam stripping, air
stripping, and wet air oxidation. The wastewater treatment performance data
presented for F001-F005 constituents were incorporated into the tables of this
section.
4-2
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4.1.2 WAQ^PACT" Data
For specific Third Third U and P waste codes, a wastewater treatment
performance test was conducted on Wet Air Oxidation (WAO) and PACTR treatment
technologies. The treatment performance data from this test were incorporated
into the tables of this section.
4.1.3 ITD Database--Promulgated Limits
In response to the Federal Water Pollution Control Act (FWPCA) of
1972 and the Clean Water Act (CWA) of 1977, EPA promulgated regulations to
reduce the level of pollutants in wastewater discharged from industrial point
sources using the "Best Available Technology Economically Achievable." The
program of developing and promulgating effluent guidelines was assigned to the
Industrial Technology Division (ITD) within EPA's Office of Water Regulations
and Standards. To date, ITD has promulgated effluent regulations for 27
industrial categories.
The treatment performance data used for ITD's promulgation efforts
have been summarized by category in specific effluent limitations guidelines
and standards development documents. The treatment performance data from the
Final Development Document for Effluent Limitations Guidelines and Standards
for the Organic Chemicals, Plastics, and Synthetic Fibers Point Source
Category for BOAT List organic constituents for which ITD effluent limitations
exist were incorporated into the tables of this section. Treatment
performance data for BOAT List inorganic and metal constituents for which ITD
effluent limitations exist were also incorporated into the tables of this
section. Wastewater treatment performance data for inorganics and metals were
from the Final Development Documents for Effluent Limitations Guidelines and
Standards for the Inorganics, Nonferrous Metals Manufacturing, and Metal
Finishing Point Source Categories.
4-3
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4.1.4 NPDES Database
Under the Clean Water Act, the discharge of pollutants into the
waters of the United States is prohibited unless a permit is issued by EPA or
a state under the National Pollutant Discharge Elimination System (NPDES). An
NPDES permit provides effluent limitations for specific pollutants that a
facility can discharge. The permit also provides for monitoring and reporting
requirements by a facility to check whether the effluent limitations are being
met. The monitoring data submitted by facilities as part of the NPDES permic
program is summarized in a database.
The NPDES database was searched for 90 BOAT List constituents to
identify facilities that have monitoring data for any of those constituents.
Constituent data from this search, representing concentrations of constituents
in wastewater effluents, have been incorporated into the tables of this
section. EPA was unable to evaluate whether substantial treatment occurred
since corresponding influent concentrations of the constituents were
unavailable. Therefore, NPDES data were only used to calculate standards when
other data were unavailable. The treatment technologies or treatment trains
represented by the NPDES data were identified in some, but not all cases.
Where available, the treatment technology has been specified in the tables of
this section.
4.1.5 WERL Database
U.S. EPA's Risk Reduction Engineering Laboratory, which now includes
the former Water Engineering Research Laboratory (WERL), has developed and is
continuing to expand a database on the treatability of chemicals in various
types of waters and wastewaters. This WERL database has been compiled from
wastewater treatment performance data available in literature. The treatment
performance data for BDAT List constituents in this database have been
included in the tables of this section.
4-4
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4.1.6 Leachate Treatment Performance Data
Leachate treatment performance data were submitted to the Agency
just prior to the proposal of the Third Third rule. The data were developed
and compiled by a leachate committee composed of several major domestic
corporations. This leachate committee was formed in April 1989 following the
stay by the U.S. Court of Appeals, D.C. Circuit, of the land disposal
restrictions for the First Third group of wastes as it applied to hazardous
waste leachate. (Waste Management Inc. v EPA CADC, No. 88-1581, 8/9/88.)
Data submitted includes waste characterization data, and full-scale
and bench-scale treatment performance data on multi-source leachate. The data
showed that most of the proposed treatment standards for BOAT List
constituents in wastewater forms of multi-source leachate were achievable by
the treatment technologies included in the industry-submitted leachate data.
For those constituents for which data indicated that the proposed standard
could not be met but the submitted leachate treatment performance data showed
substantial treatment, the Agency used the leachate treatment performance data
as a basis for calculating concentration-based treatment standards. For those
constituents with little or no treatment performance data where industry-
submitted leachate treatment performance data were available and showed
substantial treatment, the Agency used the leachate treatment performance data
as a basis for calculating concentration-based treatment standards. The
leachate treatment performance data used to recalculate treatment standards
have been included in the data tables of this section.
4.1.7 Other Sources
Other sources of wastewater treatment performance data for BOAT List
constituents that were evaluated include data in literature that were not
already part of the WERL database and data in literature submitted by industry
on the WAO and PACT" treatment processes.
4-5
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DATABASE KEY
BOAT Best Demonstrated Available Technology
ITD Industrial Technology Division
NPDES National Pollutant Discharge Elimination System
WAO Wet Air Oxidation
WERL Water Engineering Research Laboratory
OCPSF Organic Chemicals, Plastics, and Synthetic Fibers
CMDB Combined Metals Database
MF Metal Finishing
4-6
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KEY TO TREATMENT TECHNOLOGIES
ASS - Activated Alumina Sorption
AC - Activated Carbon
AFF - Aerobic Fixed Film
AL - Aerobic Lagoon*
API - API Oil/Water Separator
AS - Activated Sludge
Airs'- Air Stripping
AnFF - Anaerobic Fixed Film
AnL - Anaerobic Lagoons
BGAC - Biological Granular Activated Carbon
CAC - Chemically Assisted Clarification
Chem/Cond - Chemical Conditioning
ChOx - Chemical Oxidation IParantheses shows oxidation chemical
ie. ChOx (Oz) - la ozone]
ChOx/Pt - Chemical Oxidation/Precipitation
ChPt - Chemical Precipitation
Chred/Pt - Chemical Reduction/Precipitation
CN/Ox - Cyanide Oxidation
COAG - Coagulation
DAF - Dissolved Air Flotation
FiL - Filtration
FLOAT - Floatation
GAC - Activated Carbon [Granular]
Gr/Rem - Grease/Oil Removal
KPEG - Oechlorlnation of Toxics using an Alkoxide (Formed by the
reaction of potassium hydroxide with polyethylene
glycol [PEG400]]
IE - Ion Exchange
L - Lime
LL - Liquid, Liquid Extraction
Neut - Neutralization
PACT - Powdered Activated Carbon Addition to Activated Sludge
RBC - Rotating Biological Contactor
RO - Reverie Osmosis
SBR - Sequential Batch Reactor
SCOx - Super Critical Oxidation
SExt - Solvent Extraction
SS - Steam Stripping
Sed - Sedimentation
TF - Trickling Filter
OF - Ultrafiltration
UV - Ultraviolet Radiation
wox - Wet Air Oxidation
NOTES:
+ is the first process unit followed in process train by
the second ie. AS + Fll - Activated Sludge followed
by Filtration.
+ is the two units together ie. UFwPAC - Ultrafiltration
using Powdered Activated Carbon.
IB] is batch instead of continuous flow.
4-7
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KEY TO CONSTITUENT LOCATIONS IN SECTION 4.0
Constituents PAGE t
Acenaphthalene 4-107
Acenaphtbene 4-108
Acetone 4-14
Acetonitrile 4-16
Acetophenone 4-110
2-Acetylaninofluorene 4-111
Acrolein 4-16
Acrylonitrile 4-18
Aldrin 4-261
4-Aninobiphenyl 4-112
Aniline 4-113
Anthracene 4-114
Aranite 4-115
Aroclor 1016 4-295
Aroclor 1221 4-296
Aroclor 1232 4-297
Aroclor 1242 4-298
Aroclor 1248 4-299
Aroclor 1254 4-300
Aroclor 1260 4-301
Benz(a)anthracene 4-116
Benzene 4-20
Benzo(b)fluoranthene 4-119
Benzo(k)fluorantbene 4-121
Benzo(g,h,i)perylene 4-120
Benzo(ajpyrene 4-117
alpha-BBC 4-262
beta-BHC 4-263
delta-BHC 4-264
ganna-BHC (Lindane) 4-265
Bis(2-chloroethoxy)nethane 4-122
Bis(2-chloroethyl)etber 4-124
Bis(2-chloroisopropyl)ether 4-125
Bis(2-ethylhexyl)pbtbalate 4-126
Bronodichloronethane 4-23
Brononetbane (Methyl bronide) 4-25
4-Bronophenyl phenyl ether 4-128
n-Butyl alcohol 4-26
Butyl benzyl phthalate 4-129
2-sec-Butyl-4,6-dinitrophenol (Dinoseb) 4-129
Carbon disulfide 4-30
Carbon tetrachloride 4-28
Chlordane (alpha and ganaa) 4-266
p-Chloroaniline 4-131
4-8
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KEY TO CONSTITUENT LOCATIONS IN SECTION 4.0 (Continued)
Constituents PAGE I
Chlorobenzene 4-31
Chlorobenzilate 4-132
2-Chloro-l,3-butadiene 4-33
Chlorodibrononethane 4-33
Chloroethane 4-34
Chloroforu 4-36
p-Chloro-n-cresol 4-133
Chloronethane (Methyl chloride) 4-39
2-Chloronaphthalene 4-133
2-Chlorophenol 4-135
3-Chloropropene 4-41
Chrysene 4-136
Cresol (a- and p- isoners) 4-138
o-Cresol 4-137
Cyclohexanone 4-139
o,p'-DDD 4-268
p,p'-DDD 4-268
o,p'-DDE 4-269
p,p'-DDE 4-269
o,p'-MT 4-270
p,p'-DDT 4-270
Dibenz(a,h)anthracene 4-140
Dibenzo(a,e)pyrene 4-141
l,2-Dibrono-3-chloropropane 4-41
1,2-Dibroioethane (Ethylene dibronide) 4-42
Dibrononethane 4-43
n-Dichlorobenzene 4-142
o-Dichlorobenzene 4-144
p-Dichlorobenzene 4-146
Dicblorodifluoronethane 4-44
1,1-Dichloroethane 4-45
1,2-Dicbloroethane 4-47
1,1-Dichloroethylene 4-49
trans-l,2-Dichloroethylene 4-51
2,4-Dichlorophenol 4-148
2,6-Diddorophenol 4-149
2,4-Dkhlorophenoxyacetic acid 4-286
1,2-Dichloropropane 4-53
cis-l,3-Dicbloropropene 4-55
trans-1,3-Dichloropropene 4-54
Dieldrin 4-272
Diethyl phtbalate 4-150
4-9
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KEY TO CQNSTITUEHT LOCATIONS IK SECTION 4.0 (Continued)
Constituents PAGE
2,4-Dinethylphenol 4-151
Dinethyl phthalate 4-153
Di-n-butyl phthalate 4-154
1,4-Dinitrobenzene 4-156
4,6-Dinitro-o-cresol 4-157
2,4-Dinitrophenol 4-159
2,4-Dinitrotoluene 4-161
2,6-Dinitrotoluene 4-162
Di-n-octyl phthalate 4-163
Di-n-propylnitrosauine 4-164
1,4-Dioxane 4-56
Dipbenylanine 4-164
1,2-Diphenylhydrazine 4-166
Diphenylnitrosanine 4-165
Disulfoton 4-291
Endosulfan I 4-273
Endosulfan II 4-274
Endosulfan sulfate 4-275
Endrin 4-276
Endrin aldehyde 4-278
Ethyl acetate 4-57
Ethyl benzene 4-58
Ethyl cyanide (Propanenitrile) 4-61
Ethyl ether 4-62
Ethyl nethacrylate 4-63
Ethylene oxide 4-64
Fanphur 4-291
Fluoranthene 4-167
Fluorene 4-169
Heptachlor 4-279
Heptachlor epoxide 4-280
Hexachlorobenzene 4-170
Hexachlorobutadiene 4-170
Bexachlorocyclopentadiene 4-171A
Hexachlorodibenzofurans 4-304
Hexachlorodibenzo-p-dioxins 4-303
Hexachloroethane 4-172
Hexachloropropene 4-173
Indeno(l,2,3-c,d)pyrene 4-174
lodonethane 4-65
Isobutyl alcohol 4-65
Isodrin 4-281
Isosafrole 4-175
Kepone 4-282
Methacrylonitrile 4-73
Hethanol 4-66
4-10
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KEY TO CONSTITUENT LOCATIONS IN SECTION 4.0 (Continued)
Constituents PAGE
Methapyrilene 4-175
Methoxychlor 4-283
Methyl ethyl ketone 4-68
Methyl isobutyl ketone 4-70
Methyl nethacrylate 4-72
Methyl nethanesulfonate • 4-178
Methyl parathion 4-292
3-Methylcholanthrene 4-176
4,4'-Nethylenebis(2-chloroaniline) 4-177
Methylene chloride 4-74
Naphthalene 4-179
2-Haphthylanine 4-181
p-Nitroaniline 4-182
Nitrobenzene 4-183
5-Hitro-o-toluidine 4-191
4-Hitrophenol 4-185
N-Nitrosodiethylaiine 4-187
N-Nitrosodinethylatine 4-188
M-ffitrosodi-n-butylaaine 4-189
N-Hitrosonethylethylanine 4-189
H-Hitrosonorpholine 4-190
M-Nitrosopiperidine 4-190
H-Nitrosopyrrolidine 4-191
Parathion 4-292
Pentacblorobenzene 4-192
Pentacbiorodibenzofurans 4-306
Pentachlorodibenzo-p-dioxins 4-305
Pentachloronitrobenzene 4-193
Pentachlorophenol 4-194
Phenacetin 4-197
Phenanthrene 4-198
Phenol 4-200
Phorate 4-293
Phthalic anhydride 4-203
Pronatide 4-204
Pyrene 4-205
Pyridine 4-77
Safrole 4-207
Silvex (2,4,5-TP) 4-288
1,2,4,5-Tetrachlorobenzene 4-208
Tetrachlorodibenzofurans 4-310
Tetrachlorodibenzo-p-dioxins 4-308
1,1,1,2-Tetrachloroethane 4-77
1,1,2,2-Tetrachloroethane 4-79
Tetrachloroethylene 4-80
4-11
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KEY TO CONSTITUENT LOCATIONS IN SECTION 4.0 (Continued)
Constituents PAGE I
2,3,4,6-Tetrachlorophenol 4-209
Toluene 4-83
Toxaphene 4-284
Tribrouonethane (Bronofom) 4-87
1,2,4-Trichlorobenzene 4-210
1,1,1-Trichloroethane - 4-88
1,1,2-Trichloroethane 4-91
TricbloroetJiylene 4-93
Trichlorononofluoronethane 4-97
2,4,5-Trichlorophenol 4-211
2,4,6-Trichlorophenol 4-213
2,4,5-Tricnlorophenoxyacetic acid 4-289
1,2,3-Trichloropropane 4-99
1,1,2-Trichloro-1,2,2-trifluoroethane 4-100
Tris( 2,3-dibronopropy 1) phosphate 4-215
Vinyl chloride 4-101
Xylenes 4-103
Cyanides (Total) 4-254
Fluoride 4-257
Sulfide 4-259
Antiaony 4-217
Arsenic 4-219
Bariiia ' 4-221
Berylliuu 4-224
Cadniun 4-225
ChroniuB (total) 4-227
Copper 4-230
Lead 4-233
Mercury 4-235
Nickel 4-237
Seleniun 4-240
Silver 4-242
Thalliui 4-244
Vanadiun 4-247
Zinc 4-250
4-12
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4.2
Volatiles
Constituents discussed in this Section include:
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Benzene
Bromodichloromethane
Bromomethane
n-Butyl alcohol
Carbon-tetrachloride
Carbon disulfide
Chlorobenzene
2 -Chloro-1,3-butadiene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
3 -Chloropropene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane
D ibromomethane
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethylene
trans-1,2-Dichloroethene
1,2-Dichloropropane
trans-1,3-Dichloropropene
cis-1,3-Dichloropropene
1,4-Dioxane
Ethyl acetate
Ethyl benzene
Ethyl cyanide
Ethyl ether
Ethyl methacrylate
Ethylene oxide
lodomethane
Isobutyl alcohol
Methanol
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl methacrylate
Methacrylonitrile
Methylene chloride
Pyridine
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Tribromomethane
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichloromonofluoromethane
1,2,3-Trichloropropane
l,l,2-Trlchloro-l,2,2-tri-
fluoroethane
Vinyl chloride
Xylenes
4-13
-------
Acetone (U002). The data available for acetone were compiled from
the WERL and NPDES databases and literature wet air oxidation (WAO) data and
are presented in Table 4-lA. In addition, leachate treatment performance data
submitted by industry just prior to proposal is presented in Table 4-IB.
Technologies for which data are available include biological treatment (BT),
activated sludge (AS), granular activated carbon (GAC), powdered activated
carbon addition to activated sludge (PACTR), reverse osmosis (RO), steam
stripping (SS) , and wet air oxidation (WOx). The treatment performance data
represent bench-, pilot-, and full-scale studies. The resulting effluent
concentrations ranged from 0.846 ppb to 10,000 ppb.
At proposal, BDAT for acetone was identified as carbon adsorption
and the treatment standard was based on an effluent concentration of 50 ppb
from granular activated carbon (GAC). Between proposal and promulgation, EPA
evaluated the industry-submitted leachate data available for acetone. Since
this data for biological treatment (BT) showed substantial treatment of
acetone and showed average leachate effluent values greater than that of GAC,
these data were used to calculate the promulgated standards. Therefore, BDAT
for acetone is biological treatment.
The BDAT treatment standard for acetone was calculated using the
effluent concentration of 100 ppb and the appropriate variability factor and
accuracy correction factor. The calculation of the resulting BDAT treatment
standard for acetone (0.28 ppm) is described in Section 6.0 and is shown in
Table 6-10.
4-14
-------
TABLE 4-1A
WASTEWATER TREATMENT PERFORMANCE DATA
FOR ACETONE
TECHNOLOGY
AS
AS
* GAC
PACT
PACT
RO
RO
SS
WOx
«OX [B]
TECHNOLOGY
SIZE
Pilot
. Full
Full
Bench
Bench
Full
Full
Pilot
Full
Bench
. DETECTION RANGE
FACILITY LIMIT INFLDENT
(ppb) CONCENTRATION
(ppb)
NY0084859
NH0001376
HA0000442
NY0107760
CT0001341
AZ0000108
AZ0000108
AZ0000108
KA0000442
NY0081698
HY0107484
241B
1163E
245B
242E
Zinpro
25DB
250B
1082E
242E
78D
1000-10000
10000-100000
1000-10000
100-1000
233
1000-10000
10000-100000
10000-100000
1000000
1000000
NO. OF
DATA
POINTS
8
10
10
14
23
11
11
11
4
8
16
5
1
1
AVERAGE
EFFLCENT RECOVERY REMOVAL
CONCENTRATION (\) (I)
(ppb)
126.000
620.560
808.000
296.429
420.000
0.846
1.000
1.000
31.000
804.965
1010.780
28.000
1100.000
50.000
20.000
20.000
200.000
5800.000
10000.000
230.000
10000.000
98.5
97.1
95.9
91.4
91
81
78
80
99.99
99.4
REFERENCE
HPDES
HPDES
HPDES
NPDES
HPDES
HPDES
HPDES
HPDES
HPDES
HPDES
HPDES
XERL
ViERL
WERL *
WERL
WAO
SERL
a'ERL
*EKL
mi
*ERL
Data used in developing proposed standard.
TABLE 4-1B
INDUSTRY-SUBMITTED LEACHATE TREATMENT
PERFORMANCE DATA FOR ACETONE
TECHNOLOGY TECHHOLOGY
SIZE
DETECTION
FACILITY LIMIT
(PPb)
RANGE NO. OF AVERAGE
INFLUENT DATA EFFLUENT
CONCENTRATION POINTS CONCENTRATION
(ppb) (ppb)
RECOVERY REMOVAL REFERENCE
(*) W
BT
BT
CWM
Offl
100
100
1900-10000
9133
100
100
97.92
98.91
LEACHATE
LEACHATE
4-15
-------
Acetonitrile (U003). The data available for acetonitrile were
compiled from Che WERL database and literature FACTR data and are presented in
Table 4-2. Technologies for which data are available include AS, GAC, PACTR,
SS, and WOx. The treatment performance data represent bench-, pilot-, and
full-scale studies. The resulting effluent concentrations ranged from 5.0 ppb
to 30,000 ppb.
BDAT for acetonitrile is being promulgated as proposed and is
identified as PACTR. PACTR was selected as BDAT because of its high influent
concentration and high removal efficiency. PACTR was chosen as BDAT over GAC
due to its higher influent concentration. The BDAT treatment standard for
acetonitrile was calculated using the effluent concentration of 30 ppb and the
appropriate variability factor and accuracy correction factor. The
calculation of the resulting BDAT treatment standard for acetonitrile (0.17
ppm) is described in Section 6.0 and is shown in Table 6-10.
Acrolein (POOS). The data available for acrolein were compiled from
the WERL and NPDES databases and literature WAO data and are presented in
Table 4-3. Technologies for which data are available include AS, BT,
coagulation followed by sedimentation (COAG + Sed), and WOx. The treatment
performance data represent both bench- and full-scale studies. Resulting
effluent concentrations ranged from 0.002 ppb to 21,696 ppb.
BDAT for acrolein is being promulgated as proposed and is identified
as activated sludge biological treatment (AS). Activated sludge was selected
as BDAT because of its high influent concentration and high removal
efficiency. The BDAT treatment standard for acrolein was calculated using the
effluent concentration of 50 ppb and the appropriate variability factor and
accuracy correction factor. The calculation of the resulting BDAT treatment
standard for acrolein (0.29 ppm) is described in Section 6.0 and is shown in
Table 6-10.
4-16
-------
TABLE 4-2
HASTEHATER TREATMENT PERFORMANCE DATA
' FOR ACETONITRILE
TECHNOLOGY
AS
GAC
* PACT
ss
Wx
*0x
*ox ;BI
Wx 'Bi
TECHNOLOGY
SIZE
Bench
Bench
Bench
Pilot
Bench
Full
Bench
Bench
DETECTION RANGE HO. OF
FACILITY LIMIT INFLCENT DATA
(ppb) CONCENTRATION POINTS
(PPb)
1054E
1054E
Zinpro
1082E
2inpro
242E
1054E
1054E
10000-100000
1000-10000
30000 1
100000-1000000
1040000 1
10000-100000
100000-1000000
10000-100000
AVERAGE
EFFLOENT RECOVERY REMOVAL
CONCENTRATION (*) (!)
(PPb)
5100.000
5.000
30.000
2000.000
17000.000
30000.000
28000.000
30000.000
83
99.90
99.9
99.46
98.4
63
96.9
54
REFERENCE
*ERL
*ERL
W.O *
ViERL
*AO
VERL
vvERL
WERL
* Data used in developing proposed standard.
TABLE 4-3
«ASTEWATER TREATMENT PERFORMANCE DATA
FOR ACROLEIN
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLDENT DATA EFFLDENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (i) (*)
W (PPb) (PPb)
LA0065501
LA0066214
PA0011371
SC0002798
NJ0001660
TN0002810
IL0000621
VA0002160
HI0002313
LA0066435
NJ0028291
SC0000281
IL0000621
PA0026379
TX0008788
NJ0004286
* AS Bench 202D
BT Full PA0026549
BT Full IL0001350
BT Full LA0038245
COAGrSed Full PA0013129
*0x Bench Zinpro
6
15
19
14
5
4
1
12
2
11
2
12
2
2
7
4
10000-100000
20
24
36
1
8410000 1
100.000
50.357
1.000
27.143
81.000
33.000
10.000
100.000
0.002
100.000
1.000
21696.000
8.000
60.000
50.000
22.500
50.000
4016.000
50.000
95.000
10.000
3000.000
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES .
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
HPDES
NPDES
99.92 *ERL *
HPDES
IfPDES
NPDES
HPDES
99.96 "XAO
Data used in developing proposed standard.
4-17
-------
Acrvlonltrile (U009). Several sources of wastewater treatment
performance data were available for acrylonitrile, including data from the
ITD, and WERL databases as well as literature WAO data. These data are
presented in Table 4-4. Technologies for which data are available include BT,
AS, activated sludge followed by filtration (AS + Fil), GAG, and WOx. The
treatment performance data represent bench- and full-scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BDAT for acrylonitrile is being promulgated as proposed and is
identified as biological treatment (BT). The BDAT treatment standard was
calculated using the ITD median long-term average of 50 ppb and the ITD Option
1 variability factor. The calculation of the resulting BDAT treatment
standard for acrylonitrile (0.24 ppm) is described in Section 6.0 and is shown
in Table 6-10.
4-18
-------
TABLE 4-4
WASTFrfATER TREATMENT PERFORMANCE DATA
' FOR ACRYLOHITRILE
TECHHOLOGY TECHNOLOGY FACILITY
SIZE
AS
AS
AS
AS
AS
AS
ASrFll
GAC
* BT
DETECTION
LIMIT
(PPb)
Bench 202D
Ful
Benc
Benc
Benc
Ful
6B
1 923D
3 923D
) 1054E
L 66
Full 6B
Bench 1054E
Full 2536
50
*0x Bench Zinoro
MOx [B
Wx FB
«0x IB
Bench 23BA
Bench 1054E
Bench 1054E
RANGE
INFLUENT
CONCENTRATION
(ppb)
100000-1000000
1000-10000
1000000
100000-1000000
1000-10000
10000-100000
100000-1000000
1000-10000
43496-414785
8060000
1000000
10000-100000
1000000
NO. OF
DATA
POINTS
2
3
3
33
15
15
1
1
AVERAGE
EFFLDENT RECOVERY
CONCENTRATION (*)
(PPb)
50.000
50.000
500.000
500.000
1200.000
50.000
50.000
1.500
50.000
80000.000
7200.000
900.000
10000.000
REMOVAL
(*)
99.97
98.6
99.95
99.93
88
99.93
09 Q?
99.88
99
99.91
99.1
99.4
REFERENCE
*ERL
»ERL
•*TRL
SERL
*ERL
"XERL
.XERL
'mi
ITD-L
viAO
X'ERL
viERL
WERL
it
Data used in developing proposed standard.
4-19
-------
Benzene (U019). Several sources of wastewater treatment performance
data were available for benzene, including data from the ITD, BDAT, and WERL
databases as well as literature PACTR data. These data are presented in
Table 4-5. Technologies for which data are available include aerobic lagoons
(AL), aerobic lagoons followed by activated sludge (AL+AS), API oil/water
separation followed by dissolved air flotation and activated sludge
(API+DAF+AS), AS, AS+Fil, air stripping (AirS), air stripping followed by
granular activated carbon, (AirS+GAC), GAG, liquid, liquid extraction (LL),
liquid, liquid extraction followed by steam stripping (LL+SS), liquid, liquid
extraction followed by steam stripping and activated carbon (LL+SS+AC), PACTR,
RO, SS, trickling filter (TF), trickling filter followed by activated sludge
(TF+AS), and WOx. The treatment performance data represent bench- and full-
scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BDAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BDAT for benzene is being promulgated as proposed and is identified
as steam stripping (SS). The BDAT treatment standard was calculated using the
ITD median long-term average of 10 ppb and the ITD Option 1 variability
factor. The calculation of the resulting BDAT treatment standard for benzene
(0.14 ppm) is described in Section 6.0 and is shown in Table 6-10.
4-20
-------
TABLE 4-5
WASTEWATER TREATMENT PERFORMANCE DATA
FOR BENZENE
TECHNOLOGY
AL
AL
AL
AL
AL*AS
APPDAFtAS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
iS+Fll
AirS
AirS
AirS
AirS
AirS
AirS+GAC
. DETECTION RANGE
TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCENTRATION
(ppb)
Bench 371D
Fu
Fu
Fu
Fu
Fu.
Fu
Benc
Benc
Fu
Fu
Fu
Fu
Ful
1 6B
1 IB
1 6B
233D
1482D
6B
> 200B
) 200B
1 IB
1 6B
1 IB
1 6B
1 6B
Full IB
Bench 202D
Full 6B
Full 6B
Full 6B
Full 6B
Benc
Ful
Ful
Ful
ful
h 200B
6B
234A
201B
IB
Pilot 206B
Full 234A
Ful
Benc
Ful
Pilo
Ful
Pilo
6B
1 1328E
322B
: 224B
322B
t 1362E
Full 229A
1000-10000
100-1000
100-1000
100-1000
10000-100000
1000-10000
100-1000
100-1000
• 100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100000-1000000
1000-10000
1000-10000
1000-10000
0-100
0-100
10000-100000
100-1000
0-100
0-100
0-100
0-100
100000-1000000
10000-100000
100-1000
100-1000
1000-10000
100-1000
0-100
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (1) (I)
(PPb)
2
6
2
21
4
7
16
8
6
22
6
14
3
6
3
27
3
28
16
15
10
6
20
3
5
22
1
19
3
19
60.000
10.000
10.000
10.000
13.000
3.700
10.000
0.800
1.000
2.000
30.000
1.000
10.000
10.000
2.000
40.000
10.000
11.000
10.000
10.000
0.500
10.000
0.600
6.000
16.000
0.200
0.700
20.000
9300.000
0.440
0.500
52.000
1.000
1.000
98
98.9
94.4
92.3
99.9
99.96
98.8
99.3
99.83
99
91.7
99.55
95.7
95.6
98.9
99.97
99.09
99.8
99.71
89.6
97.8
99.97
99.83
81
84
99.73
97.4
99.99
90
99.74
99.67
98.7
99.09
90.9
REFERENCE
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
4-21
-------
TABLE 4-5 (Continued)
WASTEWATER TREATMENT PERFORMANCE DATA
FOR BENZENE
TECHNOLOGY
GAC
LL
LL
LL+SS
LLtSS+AC
PACT
PACT
PACT
PACT
SO
RO
RO
RO
RO
* SS
* SS
* SS
* SS
SS
SS
SS
SS
SS
TF
TF+AS
DP
MOX
WOx [B1
wox IB
TECHNOLOGY FACILITY
SIZE
Full 245B
Full K104
Full K103
Full K103/K104
Full K103/K104
Bench 242E
Bench 200B
Bench Zinpro
Bench Zmbro
Full 2MB
full 250B
PUot 323B
Pilot 250B
Ful
Ful
Fu.
Fu
Fli
Ftt
Fit
FU
Fa
Fu
FlL
Ful
1 250B
0415
2680
1494
0415
6B
6B
6B
' 6B
251B
IB
1 6B
Pilot 250B
Full 242E
Bench 1054E
Bench 1054E
DETECTION RANGE
LIMIT IHFLCENT
(ppb) CONCENTRATION
(ppb)
5
5
5
5
10
10
10
10
1000-10000
4500-320000
32000-81000
4500-320000
4500-320000
0-100
100-1000
290
29
1000-10000
0-100
0-100
100-1000
100-1000
22300-48100
34693-147212
239-2008310
274000-412000
100000-1000000
100000-1000000
10000-100000
10000-100000
100-1000
0-100
10000-100000
1000-10000
1000-10000
1000-10000
100000-1000000
NO. OF
DATA
POINTS
1
5
5
5
4
12
1
1
4
10
13
3
3
12
2
10
10
5
3
AVERAGE
EFFLUENT RECOVERY REMOVAL
CONCENTRATION (1) (%)
(ppb)
10.000
35600.000 76
3560.000 76
5.600 76
19.000 76
5.000
0.700
1.000
5.000
140.000
3.800
32.000
50.000
67.000
38.800
10.000
44.800
200.300
200.000
48.000
10.000
10.000
10.000
1.000
10.000
230.000
29.000
500.000
180000.000
99.28
0
0
0
0
33
99.34
99.7
83
92.2
95.1
19
78
92.7
99.94
99.99
99.97
99.99
96.3
97.5
99.97
78
99.64
53
82
REFERENCE
AERL
BOAT
BOAT
BDAI
BOAT
WERL
AERL
WAO
WAO
WERL
WERL
WERL
*ERL
WERL
ITD-L *
ITD-L *
ITD-L *
ITD-L *
WERL
HERL
WERL
WERL
WERL
«ERL
WERL
WERL
WERL
WERL
WERL
Data used in developing proposed standard.
4-22
-------
Bromodichloromethane. The data available for bromodichloromethane
were compiled from the WERL and NPDES databases and literature PACTR data.
These data are presented in Table 4-6. Technologies for which data are
available include AS, AirS, BT, chemical assisted clarification in conjunction
with air stripping (CAC+AirS) and WOx. The treatment performance data
represent bench-, pilot-, and full-scale studies. The resulting effluent
concentrations ranged from 0.030 ppb to 2,503.4 ppb.
BOAT for bromodichloromethane is being promulgated as proposed and
is identified as reverse osmosis (RO). Reverse osmosis was selected as BOAT
because it represents full-scale data with a high influent concentration range
and high removal efficiency. Other full-scale data with high influent
concentrations did not achieve a lower effluent concentration. Lower effluent
concentrations were achieved using PACT", but the data represented bench-scale
studies. The BOAT treatment standard for bromodichloromethane was calculated
using the effluent concentration of 61 ppb and the appropriate variability
factor and accuracy correction factor. The calculation of the resulting BDAT
treatment standard for bromodichloromethane (0.35 ppm) is described in Section
6.0 and is shown in Table 6-10.
4-23
-------
TABLE 4-6
WASTEWATER TREATMENT PERFORHAHCE DATA
FOR BROHODICHLOROHETHANE
TECHNOLOGY
AS
AS
AjrS
AirS
Ajr5
AirS
BT
BT
BT
BT
BT
BT
BT
CAC+AirS
ChOx
ChOx
PACT
PACT
RO
* RO
Wx
DETECTION RANGE
TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCENTRATION
(Ppb)
PA0026662
LA0065501
LA0066214
LA0066435
PA0011371
NJ0060968
HY0094781
HJ0004952
PA0026379
LA0005983
PA0027049
NJ0060968
NY0075019
NY0074489
HY0108154
NY0165166
HY0007048
KY0003603
HY0007579
NY0165166
NY0107697
NY0007579
NY0007579
NY0007889
NY0024392
NY0027057
Full IB
PUot 206B
PUot 225B
Pilot 213B
Benc
Pilo
Ful
Ful
Ful
Ful
Ful
Ful
Ful
Ful
Benc
Benc
Benc
h 1328E
210B
. PA0026786
PA0008419
PA0026247
PA0008419
PA0026603
HY0079481
LA0038245
1833D
) 640E
t 640E
1 242E
Bench Zinpro
PUot 180A
Full 250B
Full 242E
0-100
0-100
0-100
0-100
100-1000
0-100
0-100
0-100
0-100
100-1000
500
0-100
100-1000
1000000
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (°<) (1)
(ppb)
2
6
15
12
8
1
5
24
67
12
17
8
7
10
9
1
1
3
6
4
8
28
2
20
1
1
5
1
7
1
21
10
30
9
38
19
2
1
1
3.000
8.300
11.786
4.400
1.000
1.800
7.900
4.972
4.000
0.010
3.092
7.359
1.800
1.300
1.100
1.000
1.000
5.000
4.000
1.000
8.300
3.500
2.300
2503.400
2.160
15.000
6.000
0.200
0.130
1.000
37.000
1.000
286.000
8.000
4.000
122.667
4.000
6.411
5.190
0.030
3.000
1.000
20.000
20.000
0.110
61.000
500.000
71
99.78
61
93.8
82
96.2
90
89
95
96
96
79
91
99.95
REFERENCE
HPDES
HPDES
HPDES
NPDES
HPDES
NPDES
HPDES
NPDES
HPDES
NPDES
HPDES
NPDES
HPDES
HPDES
HPDES
HPDES
HPDES
HPDES
HPDES
HPDES
HPDES
NPDES
HPDES
NPDES
HPDES
NPDES
*ERL
ViERL
WERL
WERL
*ERL
WERL
HPDES
HPDES
HPDES
HPDES
HPDES
NPDES
HPDES
:i
-------
Bromomethane (U029). The data for bromomethane were compiled from
the WERL and NPDES databases and are presented in Table 4-7. Technologies for
which data are available include AS and BT. The treatment performance data
represent full-scale technologies and results in an effluent concentration
range of 1 ppb to 20 ppb.
BOAT for bromomethane is being promulgated as proposed and is
identified as activated sludge biological treatment (AS). Activated sludge
was selected as BOAT since the data shows high influent concentrations and a
high removal efficiency. The BDAT treatment standard for bromomethane was
calculated using the effluent concentration of 20 ppb and the appropriate
variability factor and accuracy correction factor. The calculation of the
resulting BDAT treatment standard for bromomethane (0.11 ppm) is described in
Section 6.0 and is shown in Table 6-10.
TABLE 4-7
WASTEWATES TREATMENT PERFORMANCE DATA
FOR BROMOMETHAira
TECHNOLOGY
* AS
* AS
BT
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY FACILITY LIMIT INFLCENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (1) (1)
(ppb) (ppb)
Full
Full
Full
LA0066435
LA0066214
PA0011371
LA0065501
HJ0028291
IB
IB
LA0038245
12
15
9
6
2
100-1000 5
100-1000 2
38
5.600
11.786
1.000
10.000
1.000
20.000
20.000
9.868
KPDES
NPDES
NPDES
HPDES
HPDES
82 >'ERL *
82 ATM, *
NPDES
Data used in developing proposed standard.
4-25
-------
n-Butvl Alcohol. The data available for n-butyl alcohol were
compiled from the WERL database and are presented in Table 4-8A-. In addition,
leachate treatment performance data submitted by industry just prior to
proposal is presented in Table 4-8B. Technologies for which data are
available include full-scale AS and BT. The resulting effluent concentrations
ranged from 40 ppb to 2000 ppb.
At proposal, BOAT for n-butyl alcohol was identified as activated
sludge biological treatment (AS) and the treatment standard was based on an
effluent concentration of 40 ppb from activated sludge. Between proposal and
promulgation, EPA evaluated the industry-submitted leachate data available for
n-butyl alcohol. Since this data for biological treatment (BT) showed
substantial treatment of n-butyl alcohol and showed average leachate effluent
values greater than that of AS, these data were used to calculate the
promulgated standards. Therefore, BOAT for n-butyl alcohol is biological
treatment.
The BDAT treatment standard for n-butyl alcohol was calculated using
the effluent concentration of 2000 ppb and the appropriate variability factor
and accuracy correction factor. The calculation of the resulting BDAT
treatment standard for n-butyl alcohol (5.6 ppm) is described in Section 6.0
and is shown in Table 6-10.
4-26
-------
TABLE 4-8A
WASTEHATER TREATMENT PERFORHAHCE DATA
FOR n-BOTYL ALCOHOL
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (!) (!)
_Ppb_) _ppb)
" * AS" " Full 1168E~ 10000-100000 40.000 99.79 XEJL *
* Data used in developing proposed standard.
TABLE 4-8B
INDOSTRY-SUBHITTED LEACHATE TREATMENT PERFORMANCE
DATA FOR n-BUTYL ALCOHOL
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY. TECHNOLOGY FACILITY LIMIT INFLDENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (!) (!)
_P_b] (ppb]
BT CWM loOO 2800 1 2000 28.57 LEACHATE
4-27
-------
Carbon Tetrachlorlde (U221). The data available for carbon
tetrachloride were compiled from the WERL database, BDAT Solvents Rule data,
and literature WAO and PACT" data. These data are presented in Table 4-9.
Technologies for which data are available include AL, AS, AS+Fil, AirS, BT,
chemically assisted clarification (CAC), GAG, PACT", RO, SS, and WOx. The
treatment performance data represent bench-, pilot, and full-scale studies.
The resulting effluent concentrations ranged from 0.200 ppb to 12,000 ppb.
BDAT for carbon tetrachloride is being promulgated as proposed and
is identified as biological treatment (BT). Biological treatment was selected
as BDAT because it represents full-scale data developed from ITD sampling and
was used as part of the BDAT Solvents Rule. The effluent concentration
achievable by this technology is supported by similar effluent concentrations
from the SS and GAG treatment performance data. The BDAT treatment standard
for carbon tetrachloride was calculated using the effluent concentration of 10
ppb and the appropriate variability factor and accuracy correction factor.
The calculation of the resulting BDAT treatment standard for carbon
tetrachloride (0.057 ppm) is described in Section 6.0 and is shown in Table 6-
10.
4-28
-------
TABLE 4-9
TREATMENT PERFORMANCE DATA
WASTEWATER . ._
FOR CARBON TETRACHLORIDE
TECHNOLOGY
AL
AL
AS
AS
AS
AS
AS
AS
AS
AS
AS+Fil
A$tFll
AltS
* BT
BT
CAC
GAC
GAC
PACT
PACT
PACT
RO
SCOx
SS
SS
TF
TF
Wx
WOX
DETECTION RANGE
TECHNOLOGY FACILITY LIMIT INFLDENT
SIZE (ppb) CONCENTRATION
(PPb)
Pilot 203A
Pilot 203A
Pilot 203A
Full IB
Pilot 206B
Full 975B
Bench 202D
full 6B
Pilot 241B
Pilot 240A
Full 6B
Ful
Benc
Ful.
Ful
Pilot
Ful
Ful
Benc
6B
1 1328E
P225
REF4
203A
1264B
237A
1 242E
Bench Zinpro
Bench Zinpro
PUot 323B
Pilot 65D
Full 251B
full 251B
PUOt 203A
Pilot 240A
Bench Zinpro
Full 242E
0-100
0-100
0-100
100-1000
0-100
0-100
10000-100000
100-1000
100-1000
0-100
1000-10000
10000-100000
10000-100000
51-44000
95
100-1000
0-100
0-100
1000-10000
860
2000
100-1000
100-1000
10000-100000
1000-10000
0-100
0-100
4330000
1000000
NO. OF
DATA
POINTS
14
14
14
6
20
3
12
14
2
5
17
1
14
1
1
1
1
10
10
14
12
1
AVERAGE
EFFLUENT RECOVERY REMOVAL
CONCENTRATION (») (*)
(PPb)
11
15
13
16
0
3
130
10
5
4
10
10
7600
10
5
101
1
10
30
1
30
2
20
5
10
26
4
12000
2000
.000
.000
.000
.000
.200
.000
.000
.000
.000
.000
.000
.000
.000
.000
.500
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
84
78
81
88'
99.67 •
94.8
99.32
96.7
98.3
90.7
99.09
99.96
89
0
87
89
98.5
99.9
98.5
98
96.5
99.99
99.41
62
90.7
99.7
99.92
REFERENCE
HEM,
*m
«ERL
•mi
AERL
*ERL
XERL
viERL
AERL
XERL
ViERL
XERL
WERL
BOAT * *
BDAT 1
WERL
"rfERL
«ERL
XERL
viAO
«AO
'mi
WERL
WERL
WERL
WERL
ViERL
WAO
WERL
t ITD data presented in the BDAT Solvents Rule F001-F005 Background Docunent.
* Data used in developing proposed standard.
4-29
-------
Carbon Disulfide. The data available for carbon disulfide were
compiled from the NPDES data for one facility and are presented in
Table 4-10A. Due to the lack of any other information for this compound the
proposed BDAT treatment standard was based on the average effluent
concentration from this facility. In addition to the NPDES data, leachate
treatment performance data submitted by industry were received just prior to
proposal and are presented in Table 4-10B. The technology for which data are
available was BT and had a resulting effluent concentration of 5 ppb.
Between proposal and promulgation, EPA evaluated the industry-
submitted leachate data available for carbon disulfide. Since this data for
biological treatment (BT) showed substantial treatment of carbon disulfide,
these data were used to calculate the promulgated standards. Therefore, BDAT
for carbon disulfide is biological treatment.
The BDAT treatment standard for carbon disulfide was calculated
using the effluent concentration of 5 ppb and the appropriate variability
factor and accuracy correction factor. The calculation of the resulting BDAT
treatment standard for carbon disulfide (0.014 ppm) is described in Section
6.0 and is shown in Table 6-10.
TABLE 4-10A
WASTEWATEX TREATMENT PERFORMAHCE DATA
FOE GABON DISDLFIDE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (?) (T)
" (ppb) (ppb)__
* " RY0000345 " 2 55-°°° tIPDES *
* Data used in developing proposed standard.
TABLE 4-10B
INDUSTRY-SUBMITTED LEACHATE TREATMENT PERFORMANCE
DATA FOR CARBON DISULFIDE
TECHNO LOG
BT
BT
Y TECHNOLOGY
SIZE
FACILITY
EMELLE
BFI
DETECTION
LIMIT
(ppb) C
5
5
RANGE
ONCENTRATIO
(ppb)
10
260
NO. OF
'N POINTS (
1
1
AVERAGE
SNCENTRATIOl
(PPb)
5
5
RECOVERY
1 (*)
REMOVAL
m
50
98.07
REFERENCE
LEACHATE
LEACHATE
4-30
-------
Chlorobenzene (U037). The data available for chlorobenzene were
compiled from the WERL database, BOAT Solvents Rule data, and literature PACTR
and WAO data. These data are presented in Table 4-11. Technologies for which
data are available include aerobic fixed film (AFF), AL, AS, AirS, biological
granular activated carbon columns (BGAC), BT, GAG, PACT", RO, SS, and WOx.
The treatment performance data represent bench-, pilot-, and full-scale
studies. The resulting effluent concentrations ranged from 0.250 ppb to
1,550,000 ppb.
BOAT for chlorobenzene is being promulgated as proposed and is
identified as biological treatment (BT). Biological treatment was selected as
BOAT because it represents full-scale data developed from ITD sampling and was
used as part of the BOAT Solvents Rule. The effluent concentration achievable
by this technology is supported by similar effluent concentrations from the AS
and PACTR treatment performance data. The BOAT treatment standard for
chlorobenzene was calculated using the effluent concentration of 10 ppb and
the appropriate variability factor and accuracy correction factor. The
calculation of the resulting BOAT treatment standard for chlorobenzene (0.057
ppm) is described in Section 6.0 and is shown in Table 6-10.
4-31
-------
TABLE 4-11
WASTEWATER TREATMENT PERFORMANCE DATA
• FOR CHLOROBENZENE
TECHHOLOGV TECHNOLOGY FACILITY
SIZE
AFF Bench 501A
AL Bench 371D
AS Bench 200B
AS Bench 200B
AS Full 975B
AS Full 6B
AS Bench 200B
AS Full 975B
AS Full 975B
AS full IB
AS Pilot 206B
AS Pilot 241B
AS Full 975B
AirS Bench 1328E
AirS Bench 1328E
BGAC Bench 501A
BT Full P206
BT Full P246
BT Full P263
BT Full REF4
* BT Fu
BT+AC Fu
GAC FU
GAC Fu
GAC Fu
GAC FU
PACT FU
1 P202
1 P246
1 245B
1 245B
1 237A
i!421D
6B
PACT Bench 200B
PACT Bench 242E
PACT Bench Zinpro
RO Pilot 323B
RO Ful
RO Fu]
SS Ful
WOx Benc
«0x Benc
250B
250B
251B
I Zinpro
h Zinpro
DETECTION RANGE
LIMIT INFLUENT
(ppb) CONCENTRATION
(ppb)
0-100
1000-10000
100-1000
100-1000
100-1000
100-1000
0-100
100-1000
0-100
100-1000
100-1000
100-1000
100-1000
1000-10000
10000-100000
0-100
929-49775
10-3040
443-832
1900
79-429
10-7200
100-1000
1000-10000
1000-10000
0-100
1000-10000
100-1000
0-100
31
0-100
0-100
1000-10000
100-1000
5535000
792000
NO. OF
DATA
POINTS
9
12
6
4
8
6
20
5
5
5
23
8
13
3
1
20
16
1
1
1
4
11
1
1
10
1
1
AVERAGE
EFFLUENT RECOVERY
CONCENTRATION (3)
(PPb)
1
160
1
1
6
10
0
10
6
3
1
4
12
1800
3300
0
841
101
504
12
10
30
10
10
10
0
10
0
5
5
12
4
120
10
1550000
61000
.000
.000
.100
.300
.000
.000
.200
.000
.000
.000
.300
.000
.000
.000
.000
.290
.000
.000
.000
.000
.000
.000
.000
.000
.000
.250
.000
.800
.000
.000
.000
.000
.000
.000
.000
.000
REMOVAL
(*)
90.7
94.7
99.17
99.81
94.6
98.9
99.23
94.6
84
98.9
99.34
98.6
97.8
77
89.
97.6
96.6
99.7
99.17
56
99.38
99.37
84
84
50
53
91.6
97.4
72
92.3
REFERENCE
'mi
WERL
SERL
WERL
>!ERL
SERL
SERL
SERL
SERL
SERL
SERL
WERL
SERL
WERL
SERL
WERL
BOAT f
BOAT .•
BOAT :!
BOAT j
BOAT *
BOAT ji
SERL
WERL
WERL
WERL
SERL
WERL
WERL
WAO
WERL
WERL
SERL
SERL
SAO
WAO
I ITD data presented in the BDAT Solvents Rule F001-F005 Background Docunent.
* Data used in developing proposed standard.
4-32
-------
2-Chloro-l.3-butadiene. No wastewater treatment performance data
were available for 2-chloro-1,3-butadiene from any of the examined sources.
Treatment performance data were therefore transferred to this constituent from
a constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
2-Chloro-l,3-butadiene is similar in structure to those constituents in
treatability group III.A.2.c.(3)(e) and the constituent used to transfer
treatment performance data from was hexachlorobutadiene. The treatment
performance data for hexachlorobutadiene are presented in Table 4-95. Using a
transfer from this constituent results in a BOAT for 2-chloro-l,3-butadiene of
activated sludge followed by filtration (AS + Fil) and a BOAT treatment
standard of 0.057 ppra as described in Section 6.0 and shown in Table 6-10.
Chlorodibromomethane. The data available for chlorodibromomethane
were compiled from the WERL and NPDES databases and are presented in Table
4-12. Technologies for which data are available include AS, AirS, BT,
CAC+AirS, GAG, and RO. The treatment performance data represent bench-,
pilot, and full-scale studies. The resulting effluent concentrations ranged
from 0.010 ppb to 2503.370 ppb.
BOAT for chlorodibromomethane is being promulgated as proposed and
is identified as carbon adsorption. Granular activated carbon (GAG) was
selected as BOAT because it represents full-scale available treatment
performance data and the Agency preferred this full-scale data to the pilot-
scale activated sludge data. The BOAT treatment standard for chlorodi-
broraomethane was calculated using the effluent concentration of 10 ppb and the
appropriate variability factor and accuracy correction factor. The
calculation of the resulting BOAT treatment standard for chlorodibromomethane
(0.057 ppm) is described in Section 6.0 and is shown in Table 6-10.
4-33
-------
Chloroethane. For chloroethane, two sources of wastewater treatment
performance data were available, including data from the ITD, and WERL
databases. These data are presented in Table 4-13. Technologies for which
data are available include AL, AS, PACT", and SS, with all of the treatment
performance data representing full-scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BDAT for chloroethane is being promulgated as proposed and is
identified as steam stripping (SS). The BDAT treatment standard was
calculated using the ITD median long-term average of 50 ppb.and the ITD Option
1 variability factor. The calculation of the resulting BDAT treatment
standard for chloroethane (0.27 ppm) is described in Section 6.0 and is shown
in Table 6-10.
4-34
-------
TABLE 4-12
WASTEWATER TREATMENT PERFORMANCE DATA
FOR CHLORODIBROMOMETHANE
TECHNOLOGY
•£
AjrS
AirS
BT
CiC+AirS
* GAC
RO
DETECTION RANGE
TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCENTRATION
(ppb)
Pilot
Pilot
Bench
Full
Full
Full
Pilot
HJ0028291
HY0007889
AZ0000018
KY0003603
PA0011371
PA0026379
PA0026662
PA0027049
LA0005983
AZ0000108
A20000108
206B
213B
1328E
PA0008419
1833D
237A
180A
0-100
0-100
100-1000
0-100
0-100
0-100
NO. OF AVERAGE
DATA EFFLOENT RECOVERY REMOVAL
POINTS CONCENTRATION (*) (i)
(ppb)
2
8
11
1
8
3
2
13
66
11
11
20
1
5
14
6
1
1.000
2503.370
11.000
5.000
1.000
2.300
2.000
21.839
0.010
1.000
1.491
7.000
1.000
50.000
86.000
0.070
10.000
0.110
88
80
78
96.3
52
79
REFERENCE
KPDES
HPDES
HPDES
NPDES
KPDES
IIPDES
HPDES
HPDES
HPDES
HPDES
HPDES
ViERL
*ERL
ViERL
HPDES
*m
ViERL *
VIERL
Data used in developing proposed standard.
TABLE 4-13
WASTEMTEJ TREATMENT PERFORMANCE DATA
FOR CHLOROETHANE
TECHNOLOGY
AL
AS
&
AS
PACT
* SS
* SS
SS
SS
TECHNOLOGY
SIZE
Full
Full
Full
Full
Full
Full
Full
Full
Full
FACILITY
IB
IB
IB
6B
6B
913
415T
6B
99.75
DETECTION RANGE
LIMIT INFLCENT
(ppb) CONCENTRATION
(ppb)
100-1000
100-1000
100-1000
100-1000
1000-10000
50 50-47700
50 690-42000
10000-100000
10000-100000
NO. OF
DATA
POINTS 0
5
4
3
14
15
2
15
AVERAGE
EFFLUENT RECN
ONCENTRATION (»]
(ppb)
260.000
250.000
640.000
50.000
63.000
50.000
50.000
50.000
50.000
/EBY REMOVAL
I W
30
0
0
87
96.8
99.88
99.75
REFERENCE
V.ERL
WERL
WERL
3JE8L
VOL
ITD-L *
ITD-L *
*m
*m
* Data used in developing proposed standard.
4-35
-------
Chloroform (U044). Several sources of wastewater treatment
performance data were available for chloroform including data from the ITD,
and WERL databases and literature WAO and PACT8 data. These data are
presented in Table .4-15. Technologies for which data are available include
AL, AS, AS+Fil, AirS, CAC, CAC+AirS, chemical oxidation (ChOx), GAG, PACT",
RO, SS, TF, and WOx. The treatment performance data represent bench-, pilot-,
and full-scale data.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BDAT for chloroform is being promulgated as proposed and is
identified as steam stripping (SS). The BDAT treatment standard was
calculated using the ITD median long-term average of 12.2 ppb and the ITD
Option 1 variability factor. The calculation of the resulting BDAT treatment
standard for chloroform (0.046 ppm) is described in Section 6.0 and is shown
in Table 6-10.
4-36
-------
TABLE 4-15
WASTEWATER TREATMENT PERFORMANCE DATA
• FOR CHLOROFORM
TECHNOLOGY
AL
AL
AL
AL
AL
AL
AL
AS
AS
.AS
AS
AS
AS
AS
.AS
AS
.AS
AS
AS
.AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS+PU
AS^Fll
Mrs
A;rS
AirS
AirS
TECHNOLOGY FACILITY
SIZE
Full 1607B
F.U11 IB
Pilot 203A
Full 141A
Full 1607B
Full 1607B
Pilot 203A
Full IB
Full 6B
Full IB
Full 6B
Bench 202D
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
fill
PllO
Fill
Ful
PllO
234A
IB
375E
IB
975B
234A
234A
1 6B
238A
1607B
1607B
206B
375E
1587E
t 241B
Full 234A
Pilot 203A
Full 6B
Full 201B
Full 234A
Pilot 240A
Full 6B
Full 6B
Be.nch 1328E
Pilot 369A
Pilot 213B
Bench 1328E
DETECTION RANGE
LIMIT INFLUENT
(ppb) CONCENTRATION
(PPb)
0-100
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
0-100
100-1000
0-100
100-1000
10000-100000
0-100
0-100
0-100
100-1000
0-100
0-100
0-100
100-1000
0-100
100-1000
1000-10000
100-1000
0-100
0-100
100-1000
0-100
100-1000
1000-10000
0-100
0-100
0-100
1000-10000
100-1000
100000-1000000
0-100
0-100
10000-100000
NO. OF
DATA
POINTS
3
6
14
2
3
14
3
1
5
3
6
7
6
3
3
3
2
20
5
14
27
29
14
3
14
5
1
5
AVERAGE
EFFLDENT RECOVERY REMOVAL
CONCENTRATION (*) (*)
(PPb)
9.000
26.000
53.000
16.000
10.000
130.000
31.000
20.000
30.000
6.000
10.000
200.000
1.200
21.000
1.000
59.000
2.000
2.300
0.500
10.000
2.400
50.000
40.000
3.600
20.000
1.600
44.000
1.300
18.000
19.000
38.000
1.300
2.000
10.000
10.000
16000.000
1.400
13.000
4400.000
90.1
96.8
61
92.3
97.4
86
77
80
77
86
97.7
99.43
61
62
75
51
93.8
72
98.4
98.2
46
86
96.9
97.4
78
65
85
84
87
98.7
53
65
98
99.41
95.8
93.1
98.2
77
83
REFERENCE
*ERL
ViERL
*ERL
ViERL
*ERL
>TRL
*ERL
>'E8L
*ERL
*ERL
>m
•XERL
*ERL
JiERL
*ERL
'mi
'mi
ViERL
*ERL
>m
XERL
XERL
*ERL
;mi
«ERL
WERL
WERL
*ERL
*ERL
WERL
ViERL
/iERL
WERL
*ERL
»ERL
SERL
WERL
«ERL
*ERL
4-37
-------
TABLE 4-15 (Continued)
WASTEWATER TREATMENT PERFORMANCE DATA
FOR CHLOROFORM
TECHNOLOGY TECHNOLOGY FACILITY
SIZE
AirS Pilot 225B
AirS Bench 17A
AirS Bench 17A
AirS Bench 17A
AirS Bench 17A
AirS Pilot 210B
AirS Bench 17A
AirS Bench 1328E
AirS Pilot 434B
CAC Pilot 203A
CACrAirS Full 1833D
ChOx Bench 640E
ChOx Bench 640E
ChOx (Oz) P;lo
t 331D
ChOx [Oz Pilot 331D
GAC Full 1264B
GAC Pilot 331D
GAC Full 245B
GAC Full 237A
GAC Full 245B
PACT Bench 242E
PACT Bench Zjnpro
PACT Bench Zinpro
RO Pilot 18&A
RO Full 250B
RO Full 250B
SCOX Pilot 65D
* SS Fa
* SS Fu
SS Fil
SS Fu
SS Fu
SS Fu.
TF Pilo
TF Ful
1 415T
913
6B
6B
251B
251B
t 240A
1 IB
TF Pilot 203A
WOx Bench Z;npro
WOx Bench Zinpro
DETECTION RANGE
LIMIT INFLDENT
(ppb) CONCENTRATION
(ppb)
0-100
0-100
1000-10000
0-100
100-1000
100-1000
100-1000
100-1000
1000-10000
100-1000
0-100
100-1000
100-1000
0-100
0-100
0-100
0-100
100-1000
100-1000
100-1000
0-100
1470
38
0-100
1000-10000
100-1000
100-1000
10 7330-1088000
10 28700-200000
100000-1000000
10000-100000
1000000
100000-1000000
0-100
0-100
100-1000
4450000
270000
NO. OF AVERAGE
DATA EFFLDENT RECOVERY REMOVAL
POINTS CONCENTRATION (*) (\)
(ppb)
1
1
5
4
14
25
2
1
1
1
1
1
1
15
14
15
2
10
10
14
14
1
1
0.130
2.600
110.000
3.900
4.200
1.000
3.700
34.000
41.000
106.000
0.200
7.000
3.000
46.000
2.800
1.000
1.000
10.000
10.000
10.000
20.000
1.000
20.000
0.890
110.000
53.000
1.700
10.500
129.200
10.000
120.000
6000.000
9600.000
11.000
14.000
102.000
3000.000
1000.000
98.9
96.9
91.7
88
98.6
99.2
98.6
84
98
22
89
96
99
37
35
87
98.6
97.6
98.1
96.2
47
99.9
47
71
94.5
87
99.83
99.99
99.88
99.99
96.4
89
86
24
99.9
99
REFERENCE
AERL
WERL
AERL
WERL
SEW,
WERL
WERL
WERL
XEP.L
WERL
WERL
AERL
WERL
WERL
SERL
WERL
WERL
WERL
WERL
WERL
WERL
MAO
»AD
WERL
WERL
WERL
XERL
ITD-L *
ITD-L *
WERL
A'ERL
WERL
WERL
WERL
WERL
WERL
WAO
WAO
Data used in developing proposed standard.
4-38
-------
Chloromethane (D045). Three sources of wastewater treatment
performance data were available for chloromethane including data from the ITD,
WERL and NPDES databases. These data are presented in Table 4-16.
Technologies for which data are available include AS, AS+Fil, BT, and SS. All
of the treatment performance data represent full-scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BDAT for chloromethane is being promulgated as proposed and is
identified as steam stripping (SS). The BDAT treatment standard was
calculated using the ITD median long-term average of 50 ppb and the ITD Option
1 variability factor. The calculation of the resulting BDAT treatment
standard for chloromethane (0.19 ppm) is described in Section 6.0 and is shown
in Table 6-10.
4-39
-------
TABLE 4-16
WASTEWATER TREATMENT PERFORMANCE DATA
• FOB CHLOROHETHANE
TECHNOLOGY
AS
AS
AS
AStFil
BT
BT
BT
BT
Sed+Fil
* SS
SS
SS
DETECTION RANGE
TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCENTRATION
(ppb)
Full
FnJ
Fa
Fu
Fu
Fu
Fu.
Fu
FU.
FU
Fu
Fu]
LI
1
1
1
1
1
1
1
.1
CT0000434
KY0003514
PA0011371
LA0004057
KA0005304
IL0001627
HY0202061
NY0075957
NY0008605
NJ0028291
MD0000345
KY0003603
W0004740
OH0025461
SC0001180
LA0066214
LA0066435
LA0065501
TX0007439
IB
IB
IB
6B
KY0002119
LA0038245
PA0026689
WV0023116
PA0010502
725 50
6B
251B
100-1000
100-1000
100-1000
0-100
9440-1290000
100000-1000000
10000-100000
NO. OF AVERAGE
DATA EFFLDENT RECOVERY REMOVAL
POINTS CONCENTRATION (*) (%)
(Ppb)
5
1
9
22
21
9
29
13
15
2
1
1
2
40
15
12
6
42
6
5
5
7
1
38
2
18
26
13
11
10
22.600
6.000
1.000
12.300
10.048
9.333
1.000
20.769
6.400
1.000
10.000
10.000
10.000
21.700
8.974
11.786
6.500
10.000
3.500
110.000
11.000
91.000
50.000
10.000
10.263
12.100
16.111
1.308
923.100
50.000
5.000
66
96.3
75
39
99.96
99.99
REFERENCE
HPDES
NPDES
HPDES
NPDES
HPDES
HPDES
KPDES
HPDES
HPDES
NPDES
HPDES
NPDES
HPDES
NPDES
HPDES
NPDES
HPDES
NPDES
HPDES
ViERL
SERL
mi
ViERL
WERL
WERL
HERL
SERL
WERL
ITD-L *
•mi
MERL
Data used in developing proposed standard.
4-40
-------
3-Chloroprooene. No wastewater treatment performance data were
available for 3-chloropropene from any of the examined sources. Treatment
performance data were therefore transferred to this constituent from a
constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
3-Chloropropene is similar in structure to those constituents in treatability
group II.A.2.b.(3) and the constituent used to transfer treatment performance
data from was cis-1,3-dichloropropene. The treatment performance data for
cis-1,3-dichloropropene are presented in Table 4-24. Using a transfer from
this constituent results in a BOAT for 3-chloropropene of activated sludge
biological treatment and a BOAT treatment standard of 0.036 ppm as described
in Section 6.0 and shown in Table 6-10.
1.2-Dibromo-3-chloroproDane (U066). No wastewater treatment
performance data were available for l,2-dibromo-3-chloropropane from any of
the examined sources. Treatment performance data were therefore transferred
to this constituent from a constituent judged to be similar in elemental
composition and functional groups within the structure of the chemical. For
constituents represented by a U or P code, this means that constituents
included in the same waste treatability group (see Appendix B) were candidates
for transfer of data. l,2-Dibromo-3-chloropropane is in treatability group
III.A.2.e and the constituent used to transfer treatment performance data from
was bromomethane. The treatment performance data for bromomethane are
presented in Table 4-7. Using a transfer from this constituent results in a
BOAT for l,2-dibromo-3-chloropropane of activated sludge biological treatment
and a BOAT treatment standard of 0.11 ppm as described in Section 6.0 and
shown in Table 6-10.
4-41
-------
1.2-Dibromoethane (U067). The data available for 1,2-dlbromoethane
were compiled from the WERL database and are presented in Table 4-17.
Technologies for which data are available include AirS and RO. The treatment
performance data represent pilot-scale studies only. The resulting effluent
concentrations ranged from 0.06 ppb to 7.0 ppb with a detection limit for 1,2-
dibroraoethane established at 4.8 ppb (see Table C-l of Appendix C).
BDAT for 1,2-dibromoethane is being promulgated as proposed and is
identified as air stripping (AirS). Air stripping was selected as BDAT
because of its high removal efficiency and ability to treat the wastewater to
a level less than the detection limit concentration. The BDAT treatment
standard for 1,2-dibromoethane was calculated using the detection limit for
this constituent of 4.8 ppb and the appropriate variability factor and
accuracy correction factor. The calculation of the resulting BDAT treatment
standard for 1,2-dibromoethane (0.028 ppm) is described in Section 6.0 and is
shown in Table 6-10.
TABLE 4-17
WASTEWATER TREATMENT PERFORMANCE DATA
FOR 1,2-DIBROMOETHAire
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (T) (*)
___(ppb_ (ppb] _______
""IlrS Pilot" ~~2~m~ 0-100 1 0.060 96.5 VERL *
RO Pilot 323B 0-100 1 7.000 15 VERL
* Data used in developing proposed standard.
4-42
-------
Dibrpmomethane (U068). No wastewater treatment performance data
were available for dibromomethane from any of the examined sources. Treatment
performance data were therefore transferred to this constituent frpm a
constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
Dibromomethane is in treatability group III.A.2.e and the constituent used to
transfer treatment performance data from was bromoethane. The treatment
performance data for bromomethane are presented in Table 4-7. Using a
transfer from this constituent results in a BOAT for dibromomethane of
activated sludge biological treatment and a BOAT treatment standard of 0.11
ppm as described in Section 6.0 and shown in Table 6-10.
4-43
-------
Dichlorodifluoromethane (U075). The data available for
dichlorodifluoromethane were compiled from the WERL and NFDES databases and
are presented in Table 4-18. The technology for which data were available was
full-scale AS and resulted in an effluent concentration of 40 ppb.
BDAT for dichlorodifluoromethane is being promulgated as proposed
and is identified as activated sludge biological treatment (AS). Activated
sludge was selected as BDAT since this was the only demonstrated technology
for which data were available. The BDAT treatment standard for
dichlorodifluoromethane was calculated using the effluent concentration of
40 ppb and the appropriate variability factor and accuracy correction factor.
The calculation of the resulting BDAT treatment standard for dichloro-
difluoromethane (0.23 ppm) is described in Section 6.0 and is shown in
Table 6-10.
TABLE 4-18
WASTEWATER TREATMENT PERFORMANCE DATA
FOR DICHLORODIFLCOROHETHANE
TECHNOLOGY TECHNOLOGY
SIZE
* AS Full
FACILITY
A20000108
AZ0000108
AZ0000108
MY0166511
NY0060534
NJ0028291
IB
DETECTION
LIMIT
(PPb)
RANGE
INFLDENT
CONCENTRATION
(ppb)
0-100
NO. OF
DATA
POINTS
11
11
11
2
5
2
4
AVERAGE
EFFLDENT RECOVERY
CONCENTRATION (1)
(ppb)
0.346
1.000
1.000
7.500
1.000
1.000
40.000
REMOVAL
(*)
33
REFERENCE
KPDES
NPDES
IIPDES
NPDES
IfPDES
NPDES
XERL *
Data used in developing proposed standard.
4-44
-------
1.1-Dichloroethane (U076). Two sources of wastewater treatment
performance data were available for 1,1-dichloroethane, including data from
the ITD, and WERL databases. These data are presented in Table 4-19.
Technologies for which data are available include AL, AS, AirS, AirS+GAC, CAC,
GAG, PACTR, RO, SS, and TF. The treatment performance data represent bench-,
pilot-, and full-scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BDAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BDAT for 1,1-dichloroethane is being promulgated as proposed and is
identified as steam stripping (SS). The BDAT.treatment standard was
calculated using the ITD median long-term average of 10 ppb and the ITD Option
1 variability factor. The calculation of the resulting BDAT treatment
standard for 1,1-dichloroethane (0.059 ppm) is described in Section 6.0 and is
shown in Table 6-10.
4-45
-------
TABLE 4-19
WASTEWATER TREATMENT PERFORMANCE
FOR 1,1-DICHLOROETHANE
TECHNOLOGY TECHNOLOGY FACILITY
SI2E
AL Pilot 203A
AL Pilot 203A
AL Full IB
AS Pilot 203A
AS Pjlot 240A
AirS Pilot 222B
AirS Pilot 1362E
AirS+GAC Ful
1 229A
CAC Pilot 203A
GAC Bench 1362E
GAC Full 1264B
PACT Bench Zinpro
RO Ful
RO Fu:
RO Fu.
* SS Fii
SS Fu
SS Fill
1 250B
250B
250B
913
251B
1 6B
TF Pilot 240A
TF Pilot 203A
DETECTION RANGE
LIMIT INFLUENT
(ppb) CONCENTRATION
(ppb)
100-1000
100-1000
0-100
100-1000
0-100
0-100
1000-10000
0-100
100-1000
1000-10000
0-100
640
1000-10000
100-1000
0-100
10 3400-13900
10000-100000
1000-10000
0-100
100-1000
DATA
NO. OF AVERAGE
DATA EFFLOEKT RECOVERY REMOVAL
POINTS CONCENTRATION (t) (t)
14
14
2
14
14
1
3
19
14
1
14
10
2
14
14
(ppb)
19
45
10
8
2
0
630
1
111
1
1
1
84
64
3
10
10
10
7
94
.000
.000
.000
.000
.000
.300
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
87
69
88
94.4
97.5
97.5
75
97.4
23
99.97
80
99.8
92.4
89
95.4
99.9
99.9
91.3
35
REFERENCE
XERL
'iiERL
«ERL
*m
*ERL
Jv'ERL
VERL
*ERL
*ERL
XERL
*ERL
KAO
*ERL
WIRL
'*ERL
ITD-L *
«ERL
WERL
SESL
>m
Data used in developing proposed standard.
4-46
-------
1.2-Dichloroethane (U077). Several sources of wastewater treatment
performance data were available for 1,2-dichloroethane, including data from
the ITD, and WERL databases and literature WAO data. These data are presented
in Table 4-20. Technologies for which data are available include AL, AL+AS,
AS, AS+Fil, AirS, CAC, PACT", RO, SS, TF, and WOx. The treatment performance
data represent bench-, pilot-, and full-scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BDAT for 1,2-dichloroethane is being promulgated as proposed and is
identified as steam stripping (SS). The BDAT treatment standard was
calculated using the ITD median long-term average of 25.6 ppb and the ITD
Option 1 variability factor. The calculation of the resulting BDAT treatment
standard for 1,2-dichloroethane (0.21 ppra) is described in Section 6.0 and is
shown in Table 6-10.
4-47
-------
TABLE 4-20
WASTEWATER TREATMENT PERFORMANCE DATA
FOR 1,2-DICHLOROETHANE
TECHNOLOGY TECHNOLOGY FACILITY
SHE
AL Pilot 203A
AL Full IB
AL Pilot 203A
AL+AS Full 233D
AS Pjlot 203A
AS Pilot 241B
AS Full IB
AS full 6B
AS Pilot 240A
AS Full 6B
AS Full 375E
AS Bench 202D
AS Ful
AS Ful
{IB
6B
AS Full 6B
AS+Fil Ful
AirS Ful
1 6B
1 322B
AirS full 322B
CAC Pilot 203A
PACT Bench Zinpro
RO Full 250B
RO Full 250B
RO Pilot 323B
RO Fu
* SS FU
* SS Pu
SS Fu
SS FU
SS Ful
TF Pllo
250B
415T
913
251B
6B
6B
t 240A
TF Full 375E
TF Pilot 203A
WOx Bench Zinpro
«0x (B) Bench 1054E
DETECTION RANGE NO. OF
LIHIT INFLUENT DATA
(Mb) CONCENTRATION POINTS
(PPb)
100-1000
1000-10000
100-1000
1000-10000
100-1000
100-1000
1000-10000
100-1000
0-100
1000-10000
100-1000
100000-1000000
10000-100000
100-1000
100-1000
10000-100000
100-1000
1000-10000
100-1000
210
1000-10000
0-100
0-100
100-1000
10 2339900-2347600
10 172000-327000
1000000
1000000
100000-1000000
0-100
100-1000
100-1000
6280000
1000000
14
6
14
21
14
3
6
3
13
25
7
6
13
12
3
5
5
14
1
1
15
14
10
15
2
13
7
14
AVERAGE
EFFLDENT RECOVERY REMOVAL
CONCENTRATION (J) (1)
(PPb)
15
10
45
8
22
140
4400
12
5
29
74
3700
1800
94
15
1200
55
189
109
1
350
13
32
43
56
73
97
56
50
12
45
93
13000
230000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.100
.300
.000
.000
.000
.000
.000
.000
.000
.000
90.2
99.75
71
99.67
86
57
33
98.1
94.3
98.6
32
98.6
89
84
98.5
98.5
89
91.8
29
99.5
84
79
37
76
99.99
99.99
99.98
86
65
39
99.8
93.6
REFERENCE
SERL
JiEKL
*ERL
SERL
*ERL
*ERL
*ERL
"-JERL
*ERL
am
*ERL
•mi
SEW,
rmi
•ERL
'mi
SiERL
•mi
XERL
ViAO
*ERL
viERL
*ERL
•mi
ITD-L *
ITD-L *
WERL
HERL
HEKL
MEJL
»ERL
•mi
*AO
iiiERL
Data used in developing proposed standard.
4-48
-------
1.1-Dichloroethvlene (U078). Two sources of wastewater treatment
performance data were available for 1,2-dichloroethylene, including data from
the ITD, and WERL databases. These data are presented in Table 4-21.
Technologies for which data are available include AL, AS, AirS, CAC, GAG, RO,
SS, and TF. The treatment performance data represent pilot- and full-scale
studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BOAT for 1,1-dichloroethylene is being promulgated as proposed and
is identified as steam stripping (SS). The BOAT treatment standard was
calculated using the ITD median long-term average of 10 ppb and the ITD Option
1 variability factor. The calculation of the resulting BOAT treatment
standard for 1,1-dichloroethylene (0.025 ppm) is described in Section 6.0 and
is shown in Table 6-10.
4-49
-------
TABLE 4-21
WiSTEWATER TREATMENT PERFORMANCE DATA
FOR 1,1-DICHLOROETHYLENE
TECHNOLOGY
AL
AL
AS
AS
AS
AS
AS
AS
AS
AS
AS
AirS
AirS
AirS
AirS
A;rS
AirS
QC
GAC
GAC
GAC
RO
RO
RO
SS
SS
SS
* SS
* SS
TF
TF
DETECTION RANGE
TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCENTRATION
(PPb)
Pilot 203A
Pilot 203A
Full 6B
Pilot 206B
full 201B
Pilot 203A
Full IB
Full 6B
Full IB
Pilot 240A
Full 6B
Pilot 217B
Pjlot 222B
Pilot 1362E
Full 1344E
Pilot 1139E
Pilot 1139E
Pilot 203A
Full 237A
Full 1264B
Pilo
Ful
Fui
e
Fll
Fu
Fll
pjfi
t 1139E
250B
250B
250B
251B
6B
6B
415T 10
913 10
240A
Pilot 203A
100-1000
100-1000
100-1000
0-100
0-100
100-1000
0-100
100-1000
0-100
0-100
100-1000
0-100
0-100
1000-10000
1000-10000
100-1000
0-100
100-1000
0-100
0-100
0-100
0-100
0-100
1000-10000
1000-10000
1000-10000
1000-10000
200-10800
2900-12300
0-100
100-1000
NO. OF AVERAGE
DATA EFFLDENT RECOVERY REMOVAL
POINTS CONCENTRATION (*) (!)
(PPb)
14
14
20
2
14
2
22
12
3
1
1
6
2
14
1
10
2
15
15
14
12
14
83.000
35.000
10.000
0.200
1.000
14.000
5.000
10.000
6.000
1.000
25.000
0.300
1.000
4.000
2.000
7.400
1.000
150.000
10.000
1.000
1.000
1.200
3.100
240.000
10.' 000
10.000
10.200
10.000
1.000
85.000
61
84
97.2
99.75
97.5
93.4
86
97
92.9
98.3
97
95.6
92.3
99.82
99.94
92.7
98.6
29
64
70
97
98.4
72
78
99.79
99.87
99.77
98.3
60
REFERENCE
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
WERL
XERL
XERL
WERL
ITD-L *
ITD-L *
WERL
XERL
Data used in developing proposed standard.
4-50
-------
Trans-1.2-Dtchloroethene (D079). Two sources of wastewater
treatment performance data were available for trans-l,2-dichloroethene,
including data from the ITD, and WERL databases. These data are presented in
Table 4-22. Technologies for which data are available include AS, AS+Fil,
AirS, GAC, RO, SS, and TF. The treatment performance data represent bench-,
pilot-, and full-scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BOAT for trans-l,2-dichloroethene is being promulgated as
proposed and is identified as steam stripping (SS). The BOAT treatment
standard was calculated using the ITD median long-term average of 10 ppb and
the ITD Option 1 variability factor. The calculation of the resulting BOAT
treatment standard for trans-l,2-dichloroethene (0.054 ppm) is described in
Section 6.0 and is shown in Table 6-10.
4-51
-------
TABLE 4-22
WASTEWATER TREATMENT PERFORMANCE DATA
FOR TRANS-1,2-DICHLOROETHYLENE
TECHNOLOGY
AS
AS
AS
ASrFil
AirS
AirS
AirS
AirS
AirS
GAC
RO
* SS
* SS
SS
SS
TF
TECHNOLOGY FACILITY
SIZE
Full IB
Full IB
Full IB
Full 6B
Bench 1328E
Pilot 1362E
Pilot 7LD
Pilot 1363E
Bench 1328E
Fu
Fu
Fu
Fu
Fu
Ful
Ful
245B
250B
415T
913
6B
6B
IB
DETECTION RANGE
LIMIT INFLUENT
(ppb) CONCENTRATION
(PPb)
0-100
0-100
0-100
100-1000
1000-10000
1000-10000
100-1000
100-1000
100000-1000000
100-1000
10000-100000
10 4860-43000
10 14100-70300
10000-100000
10000-100000
0-100
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (») (*)
(PPb)
3
4
3
5
3
1
5
1
15
14
15
2
5
7.000
3.000
8.000
78.000
1500.000
1.300
5.000
5.000
17000.000
10.000
8000.000
14.100
10.000
14.000
10.000
1.000
88
93.5
71
81
80
99.9
98.1
95.2
84
92.5
64
99.9
100
97.9
REFERENCE
WERL
*ERL
*ERL
ViERL
ViERL
ViERL
ViERL
ViERL
ViERL
ViERL
ITD-L *
ITD-L *
WERL
ViERL
VJERL
Data used in developing proposed standard.
4-52
-------
1.2^pichloroprooane (D083). The data available for 1,2-
dichloropropane were compiled from the WERL database and the EPA WAO test.
These data are presented in Table 4-23. Technologies for which data are
available include AS, AirS, ozonation (ChOx(Oz)), GAG, and WOX. The treatment
performance data represent bench-, pilot-, and full-scale studies. The
resulting effluent concentrations ranged from 0.500 ppb to 1,800 ppb.
BOAT for 1,2-dichloropropane is being promulgated as proposed and is
identified as activated sludge biological treatment (AS). Activated sludge
was selected as BOAT because it represents full-scale data with various high
influent ranges and substantial treatment removals. The activated sludge data
were used in preference to the EPA WAO test data due to the lower effluent
values achievable by activated sludge treatment as well as the fact that it
represents full-scale data over the WAO pilot-scale data. The BDAT treatment
standard for 1,2-dichloropropane was calculated using an effluent
concentration of 148.4 ppb (which represents an average of the AS effluent
concentrations presented for full-scale treatment) and the appropriate
variability factor and accuracy correction factor. The calculation of the
resulting BDAT treatment standard for 1,2-dichloropropane (0.85 ppm) is
described in Section 6.0 and is shown in Table 6-10.
TABLE 4-23
WASTEWATER TREATMENT PERFORMANCE DATA
FOR 1,2-DICHLOROPROPANE
TECHNOLOGY
* AS
AS
AS
* AS
* AS
* AS
.AS
* -AS
AirS
AirS
ChOx (Oz)
ChOx [Oz
GAC
aox
TECHNOLOGY
SIZE
Full
B^nch
Pilot
Full
Full
Full
Pilot
Full
Pilot
Pilot
Pilot
Pilot
Pilot
Pilot
FACILITY
6B
202D
241B
IB
6B
6B
206B
6B
222B
1362E
331D
331D
331D
Zinpro
DETECTION RANGE
LIMIT INFLUENT
(ppb) CONCENTRATION
(Ppb)
100-1000
100000-1000000
100-1000
1000-10000
1000-10000
1000-10000
100-1000
100-1000
0-100
100-1000
0-100
0-100
0-100
150 550000-630000
HO. OF
DATA
POINTS
15
5
1
3
3
20
24
1
3
3
AVERAGE
EFFLUENT RECOVERY
CONCENTRATION (51
(ppb)
490.000
1300.000
61.000
1.000
180.000
60.000
6.000
11.000
0.500
2.700
3.000
4.800
1.000
1607.000
REMOVAL
(*»
37
99.01
76
99.96
98.2
96.7
98.1
98.2
75
99
33
21
84
REFERENCE
AERL *
WERL
WERL
WERL *
WERL *
WERL *
WERL
WERL *
WERL
WERL
WERL
WERL
WERL
WAO
* Data used in developing proposed standard.
4-53
-------
Trans-1.3-Dlchloropropene (U084). The data available for trans-1,3-
dichloropropene were compiled from the WERL database and are presented in
Table 4-24. The data are presented as 1,3-dichloropropene since the database
did not identify individual isomers and were therefore used for both trans -
and cis-1,3-dichloropropene. Technologies for which data are available
include AL, AS, and TF. The treatment performance data represent full-scale
studies and shows effluent concentrations ranging from 1 ppb to 63 ppb.
BOAT for trans-1,3-dichloropropene is being promulgated as proposed
and is identified as activated sludge biological treatment (AS). Activated
sludge was selected as BOAT because of its high influent concentration and
high removal efficiency. The BOAT treatment standard for trans-1,3-
dichloropropene was calculated using an effluent concentration of 6.35 ppb
(which represents the average of the effluent concentration values presented
for AS full-scale treatment) and the appropriate variability factor and
accuracy correction factor. The calculation of the resulting BOAT treatment
standard for trans-1,3-dichloropropene (0.036 ppm) is described in Section 6.0
and is shown in Table 6-10.
4-54
-------
Cis-1.3-0ichloroprooene (U084). The data available for cis-1,3-
dichloropropene were compiled from the WERL database and are presented In
Table 4-24. The data were presented as 1,3-dichloropropene because the
database did not identify individual isomers and were therefore used for both
cis- and trans-1,3-dichloropropene. Technologies for which data are available
include AL, AS, and TF. The treatment performance data represent full-scale
studies and shows effluent concentrations ranging from 1 ppb to 63 ppb.
BOAT for cis-1,3-dichloropropene is being promulgated as proposed
and is identified as activated sludge biological treatment (AS). Activated
sludge was selected as BOAT because of its high influent concentration and
high removal efficiency. The BOAT treatment standard for cis-1,3-
dichloropropene was calculated using the effluent concentration of 6.35 ppb
(which represents the average of the effluent concentration values presented
for AS full-scale treatment) and the appropriate variability factor and
accuracy correction factor. The calculation of the resulting BDAT treatment
standard for cis-1,3-dichloropropene (0.036 ppm) is described in Section 6.0
and is shown in Table 6-10.
TABLE 4-24
WASTEWATER TREATMENT PERFORMANCE DATA
FOR CIS/TRANS 1,3-DICHLOROPROPEHE
TECHNOLOGY
AL
* AS
* AS
TF
TECHNOLOGY
SIZE
Full
Full
Pull
Full
DETECTION RANGE
FACILITY LIHIT INFLUENT
(ppb) CONCENTRATION
(ppb I
6B
975B
6B
IB
100-1000
100-1000
100-1000
0-100
NO. OF AVERAGE'
DATA EFFLUENT RECO',
POINTS CONCENTRATION (I;
(PPb)
3
23
1
63.000
2.700
10.000
1.000
;ERY REMOVAL
i m
38
97.6
97.4
99
REFERENCE
*ERL
*ERL *
AERL *
*ERL
Data used in developing proposed standard.
4-55
-------
1.4-Dioxane (U108). The data available for 1,4-dioxane were
compiled from the NPDES database and the EPA WAO test. These data are
presented in Table 4-25. The technology for which data were available was WOx
and the treatment performance data represent a pilot-scale study. The
resulting effluent concentrations ranged from 489.5 ppb to 10,000 ppb.
At proposal, BOAT for 1,4-dioxane was identified as wet air
oxidation and the treatment standard was based on the effluent concentration
of 10,000 ppb (the detection limit). However, upon further evaluation of this
data, EPA does not believe that the detection levels established in the WAO
test represent the effluent values that are achievable. Therefore, EPA is not
basing the BOAT standard for 1,4-dioxane on the wet air oxidation test results
but is rather transferring treatment performance data from ethyl ether. The
treatment performance data for ethyl ether are presented in Table 4-29. Using
a transfer from this constituent results in a BOAT for 1,4-dioxane of reverse
osmosis and a BOAT treatment standard of 0.12 ppm as described in Section 6.0
and shown in Table 6-10.
TABLE 4-25
WASTEWATER TREATMENT PERFORMANCE DATA
FOR 1,4-DIOXANE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLOENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION °<) (t)
_ppb] (P_P_b)
aooorm 21 2188.100 NPDES
SC0000400 24 489.500 HPDES
* Wx Pilot Zinpro 10000 1200000-1300000 3 10000.000 *AO *
* Data used in developing proposed standard.
4-56
-------
Ethvl Acetate (U112). The data available for ethyl acetate were
compiled from the WERL database and the EPA WAO test. These data are
presented in Table 4-26. The technologies for which data are available
include AS and WOX; The treatment performance data represent bench- and
pilot-scale studies. The effluent concentration range from 60 ppb to 580 ppb.
BOAT for ethyl acetate is being promulgated as proposed and is
identified as activated sludge biological treatment (AS). Activated sludge
was selected as BOAT because the data show a high influent concentration and
high removal efficiency. The AS data was preferred over the EPA WAO test data
due to the lower effluent values achievable by activated sludge treatment.
The BOAT treatment standard for ethyl acetate was calculated using the
effluent concentration of 60 ppb and the appropriate variability factor and
accuracy correction factor. The calculation of the resulting BOAT treatment
standard for ethyl acetate (0.34 ppm) is described in Section 6.0 and is shown
in Table 6-10.
TABLE 4-26
WASTEWATER TREATMENT PERFORHAHCE DATA
FOR ETHYL ACETATE
DETECTION RANGE HO. OP AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIUIT INFLUENT DATA EFFLDENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (I) (I)
(ppb) (ppb)
* AS Bench ?020 1000-10000 60.000 96.4 *ERL *
*0x Pilot Zinpro 130 630000-770000 3 580.000 *AO
* Data used in developing proposed standard.
4-57
-------
Ethvlbenzene. The data available for ethylbenzene were compiled
from the WERL database, BDAT Solvents Rule data, and literature PACT" and WAO
data. These data are presented in Table 4-27. Technologies for which data
are available include AL, AL + AS, AS, API + DAF + AS, AS + Fil, Airs, Airs +
GAG, BT, GAG, GAG, PACT", RO, SS, TF, and WOx. The treatment performance data
represent bench-, pilot-, and full-scale studies with resulting effluent
concentrations ranging from 0.100 ppb to 30,000 ppb.
BDAT for ethylbenzene is being promulgated as proposed and is
identified as biological treatment (BT). Biological treatment was selected as
BDAT because it represents full-scale data developed from ITD sampling and was
used as part of the BDAT Solvents Rule. The effluent concentration achievable
by this technology is supported by similar effluent concentrations from the
WERL activated sludge treatment performance data. The BDAT treatment standard
for ethylbenzene was calculated using the effluent concentration of 10 ppb and
the appropriate variability factor and accuracy correction factor. The
calculation of the resulting BDAT treatment standard for ethylbenzene (0.057
ppm) is described in Section 6.0 and is shown in Table 6-10.
4-58
-------
TABLE 4-27
WASTEWATER TREATMENT PERFORMANCE DATA
• FOR ETHYL BENZENE
TECHNOLOGY
DETECTION RANGE
TECHNOLOGY FACILITY LIMIT INFLCENT
SIZE (ppb) CONCENTRATION
(ppb)
AL Pilot 203 A
AL Pilot 203 A
AL Full IB
AL*AS Full 233D
APIADAF+AS Full 1482D
AS Bench 200B
AS Full 201B
AS Pilot • 206B
AS Full 6B
.AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
Full 238A
Pilot 240A
Full 6B
Full 234A
Full 234A
Bench 202D
Full 6B
Full 975B
Full IB
Full 975B
Full IB
Pilot 241B
Pul
Fu
Fa
FU
R
ful
IB
IB
IB
IB
6B
IB
975B
Pilot 203A
Pilot REF2
Ful
Put
Ful
Benc
Fu
Fu.
Fu
Fu
Ful
IB
IB
IB
h 200B
6B
6B
6B
IB
1 6B
Bench 200B
100-1000
100-1000
0-100
1000-10000
10000-100000
100-1000
0-100
0-100
100-1000
0-100
0-100
100-1000
0-100
0-100
10000-100000
1000-10000
1000-10000
0-100
100-1000
0-100
100-1000
0-100
0-100
0-100
0-100
1000-10000
0-100
0-100
100-1000
23500
100-1000
100-1000
100-1000
0-100
100-1000
100-1000
100-1000
0-100
10000-100000
100-1000
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (i) (!)
(Ppb)
14
14
21
4
6
16
20
3
14
24
4
6
4
5
3
5
4
5
3
'14
6
6
3
4
9
7
15
29
4
7
12
12.000
27.000
10.000
4.000
3.300
0.700
6.000
0.200
10.000
0.500
1.000
10.000
0.200
0.200
80.000
10.000
8.000
9.000
10.000
3.000
5.000
5.000
1.000
1.000
5.000
25.000
3.000
8.000
6.000
366.000
4.000
2.000
1.000
0.500
10.000
10.000
10.000
8.000
10.000
0.600
89
76
69
99.93
99.98
99.89
92.8
99.76
98.2
97.2
98.4
94.4
99.14
99.22
99.87
99.47
99.8
90.7
96.4
89
97.6
89
98.1
97.7
79
98.7
95.4
87
94.6
97.5
99.26
99.17
99.5
97.9
98.9
97.4
89
99.97
99.5
REFERENCE
JOL
*ERL
*ERL
*ERL
*EW.
>m
*ERL
SERL
*ERL
*E8L
ViERL
>TRL
*ERL
ViERL
*ERL
*ERL
*ERL
>iERL
*ERL
«ERL
*ERL
ViERL
*ERL
KERL
MERL
WERL
»m
WERL
«ERL
BOAT 1
SERL
mi
mi
>'ERL
*ERL
SERL
WERL
ViERL
«ERL
>"ERL
I LTD Data presented in the BDAT Solvents Rule F001-F005 Background Docunent.
4-59
-------
TABLE 4-27 {Continued}
WASTEWATER TREATMENT PERFORMANCE DATA
FOR ETHYL BENZENE
TECHNOLOGY
ASrFil
AirS
AirS
AirS-GAC
* BT
* BT
* BT •
* BT
* BT
* BT
* BT
* BT
BT
* BT
* BT
* BT
* BT
* BT
CAC
GAC
PACT
PACT
PACT
PACT
RO
JO
RO
SS
TF
TF
TF
TF
CF
WOx
HOX
MOX [Bl
WOx B
TECHNOLOGY
SIZE
Full
Pilot
Full
Pull
Ml
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Pull
Pull
Pilot
Full
Bench
Bench
Bench
Bench
Pilot
Pilot
full
phot
Pilot
Pilot
Full
Full
Pilot
Full
Full
Bench
Bench
FACILITY
6B
224B
69A
229A
P211
P234
P221
P293
P238
P215
P242
P244
P257
P202
P230
P299
P251
P253
203A
1421D
242E
Zinpro
200B
Zinpro
18DA
250B
250B
REF2
240A
203A
IB
IB
250B
Zinpro
242E
1054E
1054E
DETECTION RANGE
LIMIT INFLDENT
(ppb) CONCENTRATION
(PPt>)
0-100
0-100
0-100
0-100
12923-30000
10-3850
10-140
2287-3565
. 220-3350
564-4150
190-553
608
63-3648
96-596
101-3040
22-230
1235-1360
10-144
100-1000
0-100
0-100
185
0-100
21
0-100
0-100
1000-10000
23500
0-100
100-1000
100-1000
0-100
100-1000
50 19000-27000
1000-10000
1000-10000
100000-1000000
NO. OF
DATA
POINTS
15
1
19
7
33
3
2
2
3
2
1
27
20
15
16
3
2
14
1
11
1
5
14
14
4
4
2
AVERAGE
EFFLUENT REC01
CONCENTRATION (\
(ppb)
10.000
0.500
0.300
1.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
12.000
10.000
10.000
10.000
10.000
10.000
73.000
0.100
5.000
1.000
0.400
5.000
0.020
5.000
170.000
206.000
1.000
31.000
11.000
4.000
70.000
3550.000
21.000
500.000
30000.000
/ERY REMOVAL
W
90
91.9
94.1
80
34
37
76
99.5
99.57
76
71
92.9
97
98.4
72
90.8
90.9
59
99.65
94.6
97
REFEREI
*ERL
mi
*ERL
VERL
BOAT
BOAT
BOAT
BDAT
BOAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
A'ERL
WERL
*ERL
ViAO
WERL
W.O
WERL
'mi
*ERL
BDAT
>m
WERL
KERL
*m
*ERL
no
VEKL
WERL
SERL
KE
*
*
*
X
*
*
i *
1 *
J
j *
? *
t *
i *
i *
I ITD data presented in the BDAT Solvents Rule F001-F005 Background Document.
* Data used in developing proposed standard.
4-60
-------
Ethvl Cyanide (P101). The data available for ethyl cyanide were
compiled from the WERL database and are presented in Table 4-28. Technologies
for which data are available include both solvent extraction (SExt) and WOx.
The treatment performance data represent bench- and pilot-scale studies. The
resulting effluent concentrations ranged from 7,000 ppb to 38,000 ppb.
At proposal, BOAT for ethyl cyanide was identified as wet air
oxidation and the treatment standard was based on an effluent concentration of
7,000 ppb. However, upon further evaluation of this data, EPA does not
believe that the effluent level achieved in the WAO test represents BOAT
effluent values that are achievable. Therefore, EPA is not basing the BOAT
standard for ethyl cyanide on the wet air oxidation test results but is rather
transferring treatment performance data from acrylonitrile. The treatment
performance data for acrylonitrile are presented in Table 4-4. Using a
transfer from this constituent results in a BOAT for ethyl cyanide of
biological treatment and a BOAT treatment standard of 0.24 ppm as described in
Section 6.0 and shown in Table 6-10.
TABLE 4-28
WASTEWATER TREATMENT PERFORMANCE DATA
FOR ETHYL CYANIDE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE [ppb) CONCENTRATION POINTS CONCENTRATION (*) (*)
" (ppb) (_ppb)_ _ '
SExt Pilot 1082E 10000-100000 38000.000 55 XERL
* Wx [B] Bench 78D 100000-1000000 "000.000 98.2 >'ERL *
* Data used in developing proposed standard.
4-61
-------
Ethvl Ether (U117). The data available for ethyl ether were
compiled from the WERL database and are presented in Table 4-29. The only
technology for which data were available was full-scale RO treatment. The
resulting effluent concentrations ranged from 17 ppb to 24 ppb.
BOAT for ethyl ether is being promulgated as proposed and is
identified as reverse osmosis (RO). Reverse osmosis was selected as BOAT
because it represents full-scale demonstrated treatment with a high removal
efficiency. The BOAT treatment standard for ethyl ether was calculated using
an effluent concentration of 20.5 ppb (which represents the average of the
data presented) and the appropriate variability factor and accuracy correction
factor. The calculation of the resulting BDAT treatment standard for ethyl
ether (0.12 ppm) is described in Section 6.0 and is shown in Table 6-10.
TABLE 4-29
WASTEWATER TREATMENT PERFORMANCE DATA
FOR ETHYL ETHER
DETECTION RANGE HO. OP AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLDENT DATA EFFLDENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (I) (V)
_ppb] _ppb_
""* RO Full 250B 100-1000 17.000 88 WERL *
* RO Full 250B 100-1000 24.000 92.8 KERL *
* Data used in developing proposed standard.
4-62
-------
Ethvl Methacrvlate (U118). No wastewater treatment performance data
were available for ethyl methacrylate from any of the examined'sources.
Treatment performance data were therefore transferred to this constituent from
a constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
Ethyl methacrylate is in treatability group III.A.3.e and the constituent used
to transfer treatment performance data from was methyl isobutyl ketone. The
treatment performance data for methyl isobutyl ketone are presented in
Tables 4-33A and 4-33B. Using a transfer from this constituent results in a
BOAT for ethyl methacrylate of biological treatment and a BOAT treatment
standard of 0.14 ppm as described in Section 6.0 and shown in Table 6-10.
4-63
-------
Ethvlene Oxide. No wastewater treatment performance data were
available for ethylene oxide which indicate treatment of this constituent.
Treatment performance data were therefore transferred to this constituent from
a constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
Ethylene oxide is similar in structure to the constituents in treatability
group III.A.3.e and the constituent used to transfer treatment performance
data from was ethyl ether. The treatment performance data for ethyl ether are
presented in Table 4-29. Using a transfer from this constituent results in a
BOAT for ethylene oxide of reverse osmosis and a BOAT treatment standard of
0.12 ppm as described in Section 6.0 and shown in Table 6-10.
This standard applies to multi-source leachate and U115 wastewaters
which contain ethylene oxide from sources other than ethylene oxide gas.
Wastewaters generated from the gaseous form of ethylene oxide are subject to
the wastewater standard presented in the Final Best Demonstrated Available
Technology (BOAT) Background Document for U and P Wastes and Multi-source
Leachate (F039). Volume E - Gaseous U and P Wastes.
4-64
-------
lodomethane (U138). No wastewater treatment performance data were
available for iodomethane from any of the examined sources. Treatment
performance data were therefore transferred to this constituent from a
constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
lodomethane is in treatability group III.A.2.f.(5) and the constituent used to
transfer treatment performance data from was chloromethane. The treatment
performance data for chloromethane are presented in Table 4-16. Using a
transfer from this constituent results in a BOAT for iodomethane of steam
stripping and a BDAT treatment standard of 0.19 ppm as described in Section
6.0 and shown in Table 6-10.
Isobutyl Alcohol (U140). No wastewater treatment performance data
were available during proposal for isobutyl alcohol (isobutanol) from any of
the examined sources. Treatment performance data were therefore transferred
to this constituent from a constituent judged to be similar in elemental
composition and functional groups within the structure of the chemical. For
constituents represented by a U or P code, this means that constituents
included in the same waste treatability group (see Appendix B) were candidates
for transfer of data. Isobutyl alcohol is in treatability group III.A.3.e and
the constituent used to transfer treatment performance data from at proposal
was n-butyl alcohol (n-butanol).
Leachate treatment performance data submitted by industry were
received just prior to proposal and are presented in Table 4-30. Between
proposal and promulgation, EPA evaluated these industry-submitted leachate
data for isobutyl alcohol. Since these data for biological treatment (BT)
showed substantial treatment of isobutyl alcohol, these data were used to
calculate the promulgated standard. Therefore, BDAT for isobutyl alcohol is
biological treatment.
The BDAT treatment standard for isobutyl alcohol was calculated
using the effluent concentration of 2000 ppb and the appropriate variability
4-65
-------
factor and accuracy correction factor. The calculation of the resulting BOAT
treatment standard for isobutyl alcohol (5.6 ppm) is described in Section 6.0
and is shown in Table 6-10.
Methanol. The data available for methanol were compiled from the
WERL database and literature PACTR data and are presented in Table 4-31A. In
addition, leachate treatment performance data submitted by industry just prior
to proposal is presented in Table 4-31B. Technologies for which data are
available include PACT8, SS, WOx, and BT. The treatment performance data
represent bench-, pilot-, and full-scale studies. The resulting effluent
concentrations ranged from 10 ppb to 290,000 ppb.
At proposal, BOAT for methanol was identified as PACTR and the
treatment standard was based on an effluent concentration of 10 ppb. Between
proposal and promulgation, EPA evaluated the industry-submitted leachate data
available for methanol. Since this data for biological treatment (BT) showed
substantial treatment of methanol and showed average leachate effluent values
greater than that of PACT", these data were used to calculate the promulgated
standard. Therefore, BOAT for methanol is biological treatment.
The BOAT treatment standard for methanol was calculated using the
effluent concentration of 2000 ppb and the appropriate variability factor and
accuracy correction factor. The calculation of the resulting BOAT treatment
standard for methanol (5.6 ppm) is described in Section 6.0 and is shown in
Table 6-10.
4-66
-------
TABLE 4-30
INDUSTRY-SUBMITTED LEACHATE TREATMENT PERFORMANCE
'DATA FOR ISOBUTYL ALCOHOL
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (I) (*)
(ppb) (ppb)
BT
CTH
2000
2500-21000
3
2000.000
77.61 LEACHATE
TABLE 4-31A
WASTEWATER TREATMENT PERFORMANCE DATA
FOR METHANOL
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (\) (*)
(ppb) (ppb)
* PACT
SS
Wx
MOX
Bench
Pilot
Full
Bench
Zinpro
1082E
242E
78D
208000
1000000
1000000
1000000
1
10.000
230000.000
210000.000
290000.000
99.99
84
89.6
91
WAO *
WERL
'mi
*ERL
Data used in developing proposed standard.
TABLE 4-31B
INDUSTRY-SUBMITTED LEACHATE TREATMENT PERFORMANCE
DATA FOR HETHANOL
TECHNOLOGY
TECHNOLOGY
SIZE
FACILITY
DETECTION
LIMIT
(ppb)
RANGE
INFLUENT
CONCENTRATION
(PPb)
NO. OF
DATA
POINTS
AVERAGE
EFFLUENT
CONCENTRATION
(PPb)
RECOVERY
REMOVAL
m
REFERENCE
BT
CTM
2000
7600-31000
2000.000
87.23 LEACHATE
4-67
-------
Methyl Ethvl Ketone (U159). The data available for methyl ethyl
ketone were compiled from the NPDES database, WERL database, literature PACTR
and WAO data and EPA WAO test data. These data are presented in Table 4-32A.
In addition, leachate treatment performance data submitted by industry just
prior to proposal are presented in Table 4-32B. Technologies for which data
are available include AS, PACTR, WOx, and BT. The treatment performance data
represent bench-, pilot-, and full-scale studies with resulting effluent
concentrations ranging from 0.01 ppb to 27,000 ppb.
At proposal, BOAT for methyl ethyl ketone was identified as PACTR
and the treatment standard was based on an effluent concentration of 5 ppb.
Between proposal and promulgation, EPA evaluated the industry-submitted
leachate data available for methyl ethyl ketone. Since these data for
biological treatment (BT) showed substantial treatment of methyl ethyl ketone
and showed average leachate effluent values greater than that of PACTR, these
data were used to calculate the promulgated standard. Therefore, BOAT for
methyl ethyl ketone is biological treatment.
The BOAT treatment standard for methyl ethyl ketone was calculated
using the effluent concentration of 100 ppb and the appropriate variability
factor and.accuracy correction factor. The calculation of the resulting BDAT
treatment standard for methyl ethyl ketone (0.28 ppm) is described in Section
6.0 and is shown in Table 6-10.
4-68
-------
TABLE 4-32A
WASTEWATER TREATMENT PERFORHAHCE DATA
FOP METHYL ETHYL KETOHE
TECHNOLOGY TECHNOLOGY
SIZE
AS
AS
AS
* PACT
* PACT
* PACT
Wx
aox
«0x r PACT
WOx [Bl
Wx B
Pilot
P^lot
Pilot
Bench
Bench
Bench
Pilot
Full
Pilot
Bench
Bench
. DETECTION RANGE HO. OF AVERAGE
FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL
(ppb) CONCENTRATION POINTS CONCENTRATION (») (\)
(ppb) (ppb)
NY0096792
NY0072231
IN0036072
NH0001503
241B
252E
252E
jjnpro
Zinpro
Zinpro
Zinpro
24$E
Zinpro
786
78D
100-1000
100000-1000000
10000-100000
2300
266
300
6000000
1000000
100 130000-250000
1000000
100000-1000000
8
10
14
1
5
6
*7
i
i
i
i
3
3.400
39.400
779.360
27000.000
9.000
900.000
500.000
14.000
1.000
0.010
1000.000
2300.000
100
1000.000
1000.000
96.6
99.7
99
99.39
99.6
QQ Q
99 '.9
99.9
99.9
99.9
99.6
REFERENCE
HPDES
NPDES
HPDES
NPDES
XEKL
>m
*ERL
AAO *
VJ.-.O *
A'AO *
AAO
>m
MAO
•*m
«ERL
* Data used in developing proposed standard.
TABLE 4-32B
INDUSTRY-SUBMITTED LEACHATE TREATMENT PERFORMANCE
DATA FOR METHYL ETHYL KETONE
DETECTION RANGE NO. OF AVERAGE
TECHHOLOGY TECHHOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (I) (I)
(ppb) (ppb)
BT
BT
CWM 100 2000-19000 3
B Gffl 100 -7067 3
100.000
100.000
98.78 LEACHATE
98.58 LEACHATE
4-69
-------
Methyl Isobutvl Ketone (U161). The data available for methyl
isobutyl ketone were compiled from the WERL and NPDES databases, BOAT solvent
rule data, and EPA WAO test data. These data are presented in Table 4-33A.
In addition, leachate treatment performance data submitted by industry just
prior to proposal are presented in Table 4-33B. Technologies for which data
are available include AS, RO, SS, WOx, PACTR, and BT. The treatment
performance data represent pilot- and full-scale studies. The resulting
effluent concentrations ranged from 5 ppb to 70,900 ppb.
At proposal, BOAT for methyl isobutyl ketone was identified as steam
stripping and the treatment standard was based on an effluent concentration of
10 ppb. Between proposal and promulgation, EPA evaluated the industry-
submitted leachate data available for methyl isobutyl ketone. Since these
data for biological treatment (BT) showed substantial treatment of methyl
isobutyl ketone and showed average leachate effluent values greater than that
of steam stripping, these data were used to calculate the promulgated
standard. Therefore, BOAT for methyl isobutyl ketone is biological treatment.
The BOAT treatment standard for methyl isobutyl ketone was
calculated using the effluent concentration of 50 ppb and the appropriate
variability factor and accuracy correction factor. The calculation of the
resulting BOAT treatment standard for methyl isobutyl ketone (0.14 ppm) is
described in Section 6.0 and is shown in Table 6-10.
4-70
-------
TABLE 4-33A
NASTEWATER TREATMENT PERFORMANCE DATA
FOR METHYL ISOBUTYL KETOHE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLDENT RECOVERY
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (t)
(ppb) (ppb)
REMOVAL REFERENCE
AS
AS
RO
* SS
*0x
Wx f PACT
Pilot
Pilot
Full
Pilot
Full
Pilot
IIH0001503
REF2
241B
250B
REF2
?42E
Zinpro
76400
100-1000
100-1000
76400
100000-1000000
50 620000-830000
1
6
4
5
3
70900.000
41817.000
6.000
15.000
10.000
5.000
50.000
98.1
89.9
99.99
HPDES
BOAT jf
*ERL
XERL
BOAT t *
*ERL '
XAO
I ITD data presented in the BOAT Solvents Rule F001-F005 Background Docunent.
* Data used in developing proposed standard.
TABLE 4-33B
INDUSTRY-SUBMITTED LEACBATE TREATMENT PERFORMANCE
DATA FOR METHYL ISOBUTYL KETONE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (*) (?)
(ppb) ' (ppb)
BT
BT
BS
CWH
Offl
50
50
1400-7800
-2167
50.000
50.000
98.61
97.69
LEACHATE
LEACHATE•
4-71
-------
Methyl Methacrvlate (U162). No wastewater treatment performance
data were available for methyl methacrylate from any of the examined sources.
Treatment performance data were therefore transferred to this constituent from
a constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
Methyl methacrylate is in treatability group III.A.3.e and the constituent
used to transfer treatment performance data from was methyl isobutyl ketone.
The treatment performance data for methyl isobutyl ketone are presented in
Tables 4-33A and 4-33B. Using a transfer from this constituent results in a
BOAT for methyl methacrylate of biological treatment and a BDAT treatment
standard of 0.14 ppm as described in Section 6.0 and shown in Table 6-10.
4-72
-------
Methacrvlonitrile (U152). The data available for methacrylonitrile
were compiled from the EPA WAO test. The data are presented in Table 4-34.
The technology for which data were available was WOx and the treatment
performance data represent a pilot-scale study. The resulting average
effluent concentration was 10000 ppb.
At proposal, BOAT for methacrylonitrile was identified as wet air
oxidation and the treatment standard was based on the effluent concentration
of 10,000 ppb (the detection limit). However, upon further evaluation of this
data, EPA does not believe that the detection levels established in the WAO
test represent the effluent values that are achievable. Therefore, EPA is not
basing the BOAT standard for methacrylonitrile on the wet air oxidation test
results but is rather transferring treatment performance data from
acrylonitrile. The treatment performance data for acrylonitrile are presented
in Table 4-4. Using a transfer from this constituent results in a BOAT for
methacrylonitrile of biological treatment and a BOAT treatment standard of
0.24 ppm as described in Section 6.0 and shown in Table 6-10.
TABLE 4-34
MASTEWATER TREATMENT PERFORMANCE DATA
FOR HETHACRYLONITRILE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUeiT DATA EFFLCENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (?) I?)
(ppb) (ppb)
* Wx Pilot Sinpro 10000 1100-1300 3 10000 99.17 *AO *
* Data used in developing proposed standard.
4-73
-------
Methylene Chloride (U080). Several sources of wastewater treatment
performance data were available for methylene chloride, including data from
the ITD and WERL databases, BDAT Solvents Rule data, and literature WAO and
PACT" data. Technologies for which data are available include AS, AS+Fil,
AirS, AirS+GAC, BT, BT+AC, CAC+AirS, GAG, PACT", RO, SS, TF, and WOx. The
treatment performance data represent bench-, pilot-, and full-scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BDAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BDAT for methylene chloride is being promulgated as proposed and is
identified as steam stripping. The BDAT treatment standard was calculated
using the ITD median long-term average of 22.956 ppb and the ITD Option 1
variability factor. The calculation of the resulting BDAT treatment standard
for methylene chloride (0.089 ppm) is described in Section 6.0 and is shown in
Table 6-10.
4-74
-------
TABLE 4-35
HASTEWMER TREATMENT PERFORMANCE DATA
FOR HETHYLEHE CHLORIDE
TECHNOLOGY
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
' AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
.AS
AS
AS
AS
AS
AS
AS.
ASfFil
AirS
AirS
AirS'GAC
. DETECTION RANGE
TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCENTRATION
(ppb)
Full IB
Ful
Ful
Ful
Ful
Ful
: IB
IB
234A
201B
1 975B
Full IB
Full IB
Full IB
Full IB
Full 6B
Full IB
Full 238A
Full 234A
Bench 202D
Ful
Ful
Ful
Ful
Ful
Fu
Fu
Fu
Fa
fu
Pilo
Fu
Fu
Fu
F,ul
1 375E
6B
IB
6B
IB
6B
IB
1 IB
6B
IB
206B
1168E
234A
IB
IB
Pilot 241B
Ful
Fu
Fu
Fu
Fu
Fu
Ful
375E
IB
375E
IB
IB
375E
66
Pilot 205E
Pil6t 1362E
Full 229A
0-100
0-100
0-100
0-100
0-100
0-100
0-100
100-1000
100-1000
0-100
0-100
0-100
0-100
0-100
100000-1000000
0-100
1000-10000
0-100
1000-10000
0-100
1000-10000
0-100
1000-10000
0-100
100-1000
100-1000
10000-100000
100-1000
10000-100000
0-100
100-1000
0-100
0-100
1000-10000
1000-10000
0-100
0-100
0-100
100-1000
100-1000
100-1000
NO. OF
DATA
POINTS
3
3
4
27
3
6
6
4
4
3
7
40
5
10
3
3
6
5
10
5
20
5
4
5
7
6
7
5
5
7
9
3
19
AVERAGE
EFFLUENT RECOVERY REMOVAL
CONCENTRATION (\) (})
(Ppb)
23.000
17.000
31.000
2.000
45.000
0.430
9.000
46.000
130.000
23.000
10.000
61.000
11.000
4.900
510.000
10.000
54.000
16.000
31.000
23.000
10.000
17.000 '
56.000
13.000
560.000
4.000
920.000
0.800
12000.000
17.000
110.000
5.000
61.000
55.000
2000.000
62.000
20.000
29.000
3.000
5.300
1.000
64
72
31
93.3
51
92
75
69
54
57
77
34
78
56
99.72
69
98.6
72
99.53
74
99.74
77
97.8
79
31
96.6
98.4
99.5
14
64
78
80
34
99.3
5
35
64
26
99.6
QQ
99". 8
REFERENCE
«ERL '
'mi
/iERL
>:ERL
*ERL
•/iERL
*ERL
*ERL
ViERL
*ERL
*ERL
'mi
«ERL
WERL
wERL
*ERL
*ERL
JJERL
*ERL
*ERL
WERL
*ERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
'/iERL
«ERL
MERL
MERL
ViERL
WERL
«ERL
*ERL
>'ERL
*ERL
4-75
-------
. TABLE 4-35 (Continued)
WASTEWATER TREATMENT PERFORMANCE DATA
FOR HETHYLENE CHLORIDE
TECHNOLOGY
BT
BT
BT+AC
CAC-AirS
GAC
GAC
PACT
PACT
RO
RO
* SS
* SS
* SS
SS
SS
SS
SS
SS
SS
SS
TF
IF
TF
TF
TF
TF
TF
TF
TF
HOx
Wx
«OX
WOX
TECHNOLOGY FACILITY
SIZE
Fu
Fu:
FU
Fa
Fu
P246
P265
P246
1833D
245B
Full 237A
Bench 242E
Bench Zinpro
Full 25&B
Full 250B
Full 725
Full 913
Full 415T
Full 6B
Ful
Ful
Ful
Ful
Ful
Fu
Fu
Fu
Fu
Fu
Fu
FU
Fu
Fu
Fu
1 251B
251B
6B
P12003
6B
P284
IB
375E
IB
IB
IB
IB
IB
375E
1 IB
REF10
Pjlot Ziupro
Pilot 786
Full 242E
DETECTION RANGE NO. OF
LIMIT INFLUENT DATA
(ppb) CONCENTRATION POINTS
(Ppb)
27-3907
500-750
10-5550
0-100
100-1000
100-1000
0-100
34
100-1000
10000-100000
10 10-5100
10 200-10400
10 198-12100
1000-10000
1000-10000
1000000
1000-10000
225000-12000000
100-1000
198-12100
0-100
0-100
0-100
0-100
0-100
100-1000
100-1000
100-1000
100-1000
15000-3600000
60000
10-100
100000-1000000
13
3
28
25
1
1
1
13
14
15
15
10
10
9
40
2
15
5 '
7
3
5
5
6
4
7
5
3
1
AVERAGE
EFFLUENT RECOVERY REMOVAL
CONCENTRATION (1) (*)
(PPb)
11.000
27.000
10.000
2.400
10.000
10.000
20.000
20.000
80.000
15000.000
217.300
10.000
10.500
10.000
10.000
11.000
78.000
24413.000
10.000
10.000
20.000
12.000
23.000
58.000
21.000
16.000
120.000
21.000
37.000
5000.000
10.000
10.000
84.000
92.3
99
94.4
76
. 76
66
44
99.52
99.17
100
95.1
99
67
8
36
40
77
89
56
88
66
99.9
99.98
99.99
REFERENCE
BDAT I
BOAT ?
BDAT i
>m
*ERL
>m
*ERL
WO
*ERL
>m
ITD-L *
ITD-L *
ITD-L *
AERL
WERL
'AERL
AERL
BDAT T*
AERL
BDAT 1
AERL
HEKL
AERL
WERL
UERL
WEBL
WERL
HERL
AERL
BDAT #
»AO
rf'ERL
WERL
I ITD data presented in the BDAT Solvents Rule F001-F005 Background Docunent.
* Data used in developing proposed standard.
4-76
-------
Pyridine (U196). The data available for pyridine were compiled from
the WERL database and EPA WAO test data and are presented in Table 4-36.
Technologies for which data are available include AS, AnFF, and WOx + PACTR.
The treatment performance data represent bench-, and pilot-scale studies. The
resulting effluent concentrations ranged from 0.9 ppb to 1900 ppb with a
detection limit for pyridine established at 2.4 ppb (see Table C-l,
Appendix C).
BOAT for pyridine is being promulgated as proposed and is identified
as anaerobic fixed film biological treatment (ARFF). Anaerobic fixed film was
selected as BOAT since this demonstrated biological treatment technology
showed substantial treatment to levels below the detection limit. The BOAT
treatment standard for pyridine was calculated using an effluent concentration
of 2.4 ppb (which represents the detection limit for pyridine) and the
appropriate variability factor and accuracy correction factor. The
calculation of the resulting BOAT treatment standard for pyridine (0.014 ppm)
is described in Section 6.0 and is shown in Table 6-10.
1.1.1.2-Tetrachloroethane (U208). The data available for 1,1,1,2-
tetrachloroethane were compiled from literature WAO data and are presented in
Table 4-37. The technology for which data were available was bench-scale
PACT".
BOAT for 1,1,1,2-tetrachloroethane is being promulgated as proposed
and is identified as PACT8. PACT* was selected as BOAT because it represents
data with a high removal efficiency and the lowest achievable effluent. The
BOAT treatment standard for 1,1,1,2-tetrachloroethane was calculated using the
effluent concentration of 10 ppb and the appropriate variability factor and
accuracy correction factor. The calculation of the resulting BOAT treatment
standard for 1,1,1,2-tetrachloroethane (0.057 ppm) is described in Section 6.0
and is shown in Table 6-10.
4-77
-------
' TABLE 4-36
WASTEWATER TREATMENT PERFORMANCE DATA
FOB PYRIDINE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLDEHT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (I) (I)
(ppb) (ppb)
AS
* AnFF
Wx - PACT
Bench
Pilot
Pilot
1054E
235D
Zinpro
1000-10000
1000-10000
>180000
3
1900.000
0.900
146.000
37
99.9
99.9
XERL
«ERL *
>;io
Data used in developinq proposed standard.
TABLE 4-37
WASTEWATER TREATHENT PERFORMANCE DATA
FOR 1,1,1,2-TETRACHLOROETHANE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLDENT DATA EFFLOENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (*) (*)
(ppb)
* PACT Bench Zinpro 36 1 10.000 72 WAO *
* Data used in developing proposed standard.
4-78
-------
1.1.2.2-Tetrachloroethane (U209). The data available for 1,1,2,2-
tetrachloroethane were compiled from the WERL and NPDES databases and are
presented in Table 4-38. Technologies for which data are available include
AS, AirS, BT, and GAC. The treatment performance data represent bench-,
pilot-, and full-scale studies. The resulting effluent concentrations ranged
from 0.0005 ppb to 11,000 ppb.
BOAT for 1,1,2,2-tetrachloroethane is being promulgated as proposed
and is identified as carbon adsorption. Granular activated carbon (GAC) was
selected as BDAT because of its full-scale treatment performance with high
influent concentrations and a high removal efficiency. The BDAT treatment
standard for 1,1,2,2-tetrachloroethane was calculated using the effluent
concentration of 10 ppb and the appropriate variability factor and accuracy
correction factor. The calculation of the resulting BDAT treatment standard
for 1,1,2,2-tetrachloroethane (0.057 ppm) is described in Section 6.0 and is
shown in Table '6-10.
TABLE 4-38
flASTEWATER TREATMENT PERFORMANCE DATA
FOR 1,1,2,2-TETRACHLOROETHANE
TECHNOLOGY
AS
AS
AirS
AirS
BT
* GAC
TECHNOLOGY
SIZE
Bench
Full
Pilot
Pilot
Full
Full
FACILITY
NY0007048
NJ0028291
LA0066435
LA0066214
LA0065501
NJ0030392
202D
IB
1363E
71D
LA0038245
245B
DETECTION RANGE
LIMIT INFLDENT
(ppb) CONCENTRATION
(ppb)
100000-1000000
0-100
100-1000
100-1000
1000-10000
NO. OF
DATA
POINTS
9
2
13
15
6
4
2
1
38
1
AVERAGE
EFFLUENT RECOVERY
CONCENTRATION (*)
1 L I
(PPb)
1.560
1.000
7.570
5.000
5.000
0.005
11000.000
3.000
4.600
41.000
5.313
10.000
REMOVAL
94.5
93.5
99
95.5
99.1
REFERENCE
NPDES
NPDES
NPDES
HPDES
1IPDES
NPDES
>m
SERL
*ERL
NPDES
SERL *
Data used in developing proposed standard.
4-79
-------
Tetrachloroethene (U210). Several sources of wastewater treatment
performance data were available for tetrachloroethene, including data from the
ITD and WERL databases, BDAT Solvents Rule data, and literature PACTR data.
These data are presented in Table 4-39. Technologies for which data are
available include AL, AS, AS+Fil, Airs, AnFF, BT, CAC+AirS, ChOX, chemical
reduction (Chred), GAC, PACT", RO, SS, TF, and WOx. The treatment performance
data represent bench-, pilot-, and full-scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BDAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BDAT for tetrachloroethene is being promulgated as proposed and is
identified as steam stripping (SS). The BDAT treatment standard was
calculated using the ITD median long-term average of 10.4 ppb and the ITD
Option 1 variability factor. The calculation of the resulting BDAT treatment
standard for tetrachloroethene (0.056 ppm) is described in Section 6.0 and is
shown in Table 6-10.
4-80
-------
TABLE 4-39
HASTEWATER TREATMENT PERFORMANCE DATA
FOR TETRACHLOROETHEHE
DETECTION RANGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCENTRATION
(Ppb)
AL Full IB
AS Full IB
AS Full IB
AS Full IB
AS Full 238A
AS Full 1587E
.AS Full 234A
AS Full 238A
AS Full IB
.AS Full 234A
AS Full IB
AS Full IB
.AS Ful
AS Ful
{IB
IB
AS Pilot 241B
AS Full IB
AS Full 201B
AS Full IB
AS Full IB
AS Full IB
.AS Fu
AS Fu
AS Fu
AS. Fu
AS+Fjl Fu
AS+Fll Ful
AirS PllO
A*rS Pilo
Ajr5 Ful
AirS PUo
1 234A
IB
IB
IB
6B
6B
; 221B
71D
223B
222B
AirS Pilot 217B
AirS Pilot 207B
AjrS Full 69A
AirS Pilot 220B
AirS Pilot 208B
AirS Pilot 1363E
AjrS Pilot 214B
AjrS Full 1042E
AirS Full 322B
AirS Pilot 1362E
AnFF Bench 724D
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
100-1000
0-100
100-1000
0-100
0-100
100-1000
1000-10000
0-100
0-100
100-1000
100-1000
0-100
0-100
0-100
100-1000
10000-100000
100-1000
0-100
0-100
100-1000
0-100
100-1000
0-100
0-100
0-100
0-100
0-100
100-1000
100-1000
100-1000
1000-10000
10000-100000
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (1) (I)
(PPb)
6
3
5
4
3
3
4
5
5
3
6
5
6
22
4
6
6
6
5
4
3
15
1
1
1
1
1
1
1
1
1
9
3
10
10
2
8
2
0
22
1
1
3
9
5
22
28
11
440
8
6
48
26
0
8
14
100
230
11
0
0
0
0
0
0
0
0
0
0
0
0
1
5
4
.000
.000
.000
.000
.100
.870
.000
.600
.000
.900
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.600
.000
.000
.000
.000
.000
.500
.200
.800
.200
.300
.500
.960
.200
.200
.200
.900
.500
.200
.000
.400
80
83
97.5
85
87
97.8
49
87
96
96.7
75
96.7
45
71
95.3
85
89.5
93
79
78
95.9
85
74
83
99.04
97.7
95.8
98.7
99.43
94.3
99.73
98.3
98.4
99.76
99.17
97.1
99.31
99.71
99.75
99.74
99.99
REFERENCE
AERL
WERL
AERL
>TRL
XERL
*ERL
AERL
>m
AERL
AERL
AERL
WERL
tfERL
WERL
»ERL
WERL
WERL
WERL
VERL
WERL
XERL
WERL
WERL
WERL
HERL
HERL
A'ERL
KERL
WERL
WERL
WERL
MERL
•*ERL
ViERL
AERL
WERL
UERL
WERL
VOL
viERL
VERL
4-81
-------
- TABLE 4-39 (Continued)
WASTEWATER TREATMENT PERFORMANCE DATA
FOR TETRACHLOROETHENE
TECHHOLOGY
BT
BT
BT
CACrAirS
ChOx
ChOx
Chred
GAC
GAC
GAC
PACT
PACT
PACT
RO
RO
* SS
SS
SS
TF
TF
TF
TF
TF
TF
0V [B]
HOX1 J
WO*
DETECTION RANGE
TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCENTRATION
(PPb)
Ful
Ful
Ful
F.ul
Pilo
1 P225
P280
REF4
1333D
t 2026A
Pilot 2026A
Bench
Full 1264B
Full 245B
Full 237A
Bench 242E
Bench Zjnpro
Bench Ziobro
Pilot 323B
Pilot 180A
Full 913 10
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Ful
Benc
1 251B
6B
IB
IB
IB
IB
IB
IB
h 1138E
EEF10
Pilot 78D
95-31500
110-1748
62
0-100
0-100
0-100
250
0-100
1000-10000
100-1000
100-1000
304
136
0-100
0-100
10800-241000
1000-10000
10000-100000
0-100
100-1000
0-100
0-100
0-100
0-100
0-100
41000
1000000
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (1) (*)
(PPb)
18
12
1
7
4
4
1
1
1
1
1
14
10
2
5
5
3
4
6
5
1
1
47.000
10.000
7.300
0.100
2.000
1.700
5.000
1.000
10.000
10.000
10.000
1.000
10.000
30.000
0.250
18.400
10.000
10.000
12.000
26.000
18.000
1.000
6.000
3.000
7.500
1000.000
900.000
39
36
84
95.2
99.13
96.3
92.6
99.7
93
68
81
99.29
99.95
81
83
54
96.9
92.7
94.3
85
99.98
REFERENCE
BDAT |
BDAT |
BDAT 1
*ERL
*ERL
>m
ART
ViERL
*ERL
A'ERL
A'ERL
MAO
*AO
XERL
. »ERL
ITD-L *
v»ERL
XERL
«ERL
>m
*ERL
WERL
«ERL
MERL
WERL .
BDAT #
MERL
ITD data presented in the BDAT Solvents Rule F001-F005 Background Docuiient.
Data used in developing proposed standard.
4-82
-------
Toluene (U220). Several sources of wastewater treatment performance
data were available for toluene, including data from the ITD and WERL
databases, BOAT Solvents Rule data, literature WAO and PACTR data, and EPA WAO
test data. These data are presented in Table 4-40. Technologies for which
data are available include AL, AL+AS, API+DAF+AS, AS, AS+Fil, AirS, AirS+GAC,
BT, BT+AC, GAG, PACT", RO, SS. SS+AC, TF, WOx+PACTR, and WOx. The treatment
performance data represent bench-, pilot-, and full-scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BDAT for toluene is being promulgated as proposed and is identified
as steam stripping (SS). The BDAT treatment standard was calculated using the
ITD median long-term average of 10 ppb and the ITD Option 1 variability
factor. The calculation of the resulting BDAT treatment standard for toluene
(0.080 ppra) is described in Section 6.0 and is shown in Table 6-10.
4-83
-------
TABLE 4-40
HASTEWATER TREATMENT PERFORMANCE DATA
FOR TOLUENE
TECHNOLOGY
AL
AL
AL
AL+AS
API+DAF+AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
.AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
DETECTION RANGE
TECHNOLOGY FACILITY LIMIT INFLDENT
SIZE (ppb) CONCENTRATION
(ppb)
Full 6B
Bench 371D
Full IB
Full 233D
Full 1482D
Bench 202D
Full 6B
Full 6B
Full 975B
Full 6B
Bench 200B
Full 6B
Full IB
Full 6B
Full 6B
Full 975B
Full 6B
Full 975B
Full 6B
Pilot 226B
Ful
Fit
Fu
Fa
Fu
Pu
Fu
FU
Fu
FU
Fu
Fu
FU
Fu
Fu
Fu
Fu
Fu
6B
6B
IB
975B
IB
234A
IB
1587E
201B
IB
IB
234A
IB
IB
238A
6B
IB
IB
Pilot 241B
100-1000
1000-10000
100-1000
1000-10000
10000-100000
10000-100000
10000-100000
1000-10000
1000-10000
10000-100000
100-1000
1000-10000
1000-10000
1000-10000
1000-10000
1000-10000
1000-10000
100-1000
1000-10000
100000-1000000
100-1000
100-1000
0-100
100-1000
100-1000
0-100
0-100
0-100
100-1000
100-1000
0-100
0-100
100-1000
0-100
0-100
100-1000
0-100
0-100
100-1000
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (») (*)
(PPb)
3
6
21
4
3
3
3
10
24
6
15
3
7
33
7
14
4
5
6
4
32
5
4
4
5
3
3
5
4
5
10.000
90.000
32.000
4.000
11.000
10.000
73.000
10.000
12.000
76.000
0.800
10.000
9.000
10.000
24.000 .
280.000
10.000
23.000
20.000
300.000
10.000
10.000
4.000
7.600
4.000
0.700
3.000
0.100
57.000
12.000
1.000
0.200
4.000
2.000
6.200
10.000
2.000
4.000
4.000
98.2
97
96.1
99.85
99.93
99.93
99.84
99.57
99.68
99.90
99.3
99.73
99.81
99.88
99.76
96.3
99.5
86
99.8
99.85
97.8
97.6
88
99.04
99.48
97.1
90.6
99
87
96.8
98
96.2
96.4
97.6
92.7
94.4
97.1
86
98.6
REFERENCE
HERL
HERL
'mi
•mi
SERL
HERL
i'ERL
HERL •
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
'mi
HERL
HERL
HERL
viERL
HERL
HERL
HERL
>m
HERL
HERL
HERL
HERL
HERL
WERL
HERL
HERL
HERL
WERL
HERL
4-84
-------
. TABLE 4-40 (Continued!
JttSTEiATER TREATMENT PERFORMANCE DATA
FOR TOLUENE
TECHNOLOGY
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS + Fil
AjrS
4rS
A;rS
AirS
AirS
AirS
A;rS
AirS
AirS+GAC
BT
BT
BT
BT
BT
BT
BT
BT
BT
BT
BT
BT
BT
BT
BT
BT
BT
TECHNOLOGY FACILITY
SIZE
Full 234A
Full IB
Full IB
Fu
Fu
FU
Fu
Ful
IB
IB
234A
IB
1 'IB
Pilot 206B
Full IB
Full 234A
Full IB
Pilot REF2
Full 6B
full 322B
Pilot 1362E
Benc
Ful
Ful
Pilo
Ful
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
1 1328E
69A
322B
224B
322B
322B
229A
P206
P211
P202
P244
P210
P223
P217
P234
P242
P221
P208
P240
P246
P251
Full P253
Full P257
Full P265
DETECTION RANGE
LIMIT INFLUENT
(ppb) CONCENTRATION
(Ppb)
0-100
0-100
100-1000
0-100
0-100
0-100
0-100
100-1000
100-1000
100-1000
100-1000
100-1000
92000
10000-100000
100-1000
0-100
10000-100000
0-100
0-100
0-100
1000-10000
10000-100000
0-100
834-57475
1154-4000
60-155
1109
135-5805
99-265
34400-60000
2350-35000
1200-1533
10-323
140-640
22700
77-12938
15840-26060
66-230
1730-12900
37750-50000
NO. OF
DATA
POINTS
5
6
6
5
6
5
20
6
6
6
3
24
3
5
5
1
6
3
19
10
7
20
1
2
3
3
32
3
14
1
9
3
3
27
3
AVERAGE
EFFLDENT RECOVERY
CONCENTRATION (%)
(ppb)
0.200
3.000
20.000
1.000
1.000
0.200
2.000
56.000
0.600
10.000
0.200
31.000
23467.000
10.000
0.660
1.700
2800.000
0.940
2.000
0.500
34.000
114.000
1.000
1491.000
10.000
10.000
10.000
10.000
10.000
73.000
21.000
10.000
10.000
10.000
10.000
630.000
10.000
103.000
12.000
10.000
REMOVAL
.m
96.9
94
89
97.3
97.4
97.7
96.3
93.8
99.76
96.4
99.9
95.4
99.98
99.77
95.3
92.4
97
97.4
98.9
99.18
99.33
90
REFERENCE
XERL
MERL
•*ERL
«ERL
SERL
*ERL
HERL
VJERL
*m
ViERL
KERL
KERL
BOAT t
ViERL
ViERL
viERL
ViERL •
«ERL
ViERL
'mi
ViERL
'mi
viERL
BDAT t
BOAT '•
BDAT ,
BDAT
BDAT
BDAT
BDAT ,
BDAT
BDAT ,
BDAT
BDAT
BDAT 1
BDAT 1
BDAT |
BDAT |
BDAT i
BDAT I
I ITD data presented in the BDAT Solvents Rule F001-F005 Background Document.
4-85
-------
• TABLE 4-40 (Continued)
WASTEWATER TREATMENT PERFORMANCE DATA
FOR TOLUENE
TECHNOLOGY TECHNOLOGY FACILITY
SIZE
BT
BT
BT
BT
BT+AC
GAC
GAC
GAC
PACT
PACT
PACT
PACT
RO
RO
RO
* SS
SS
SS
* SS
SS
SS
SS+AC
TF
TF
TF
TF
TF
TF
UF
SOx
WOx
WOx
WOX
WOX
WOX
Ful
Ful
Ful
Ful
Ful
P286
P215
P230
REF4
P246
Pilot 435B
. full 245B
Pilot REF7
Benc
Benc
Benc
Benc
Ful
b 200B
1 242E
i Zjrapro
i Zinpro
1 250B
Pilot 250B
Full 250B
0415**
Full 6B
. Full 6B
0415*
Pilo
Fill
Ful
Ful
Ful
Ful
Ful
Ful
t REF4
P246
P297
6B
IB
IB
IB
1 IB
F.U11 IB
Pilot 250B
REF10
Bench Zjnpro
Bench Z^npro
Pilot Z;mpro
Full Zinpro
Full 242E
WOX Pilot ?8D
Wx + PACT Pilot Zinoro
Wx [b
*OX ;b
Wx fb
Wx >b
Bench 78D
Bench 78D
Bench 1054E
Bench 1054E
DETECTION RANGE
LIMIT INFLUENT
(ppb) CONCENTRATION
(PPb)
24000-160000
3300-4550
3503-30347
680
77-12938
10000-100000
10000-100000
120
100-1000
0-100
2730
57
100-1000
0-100
1000-10000
10 19300-29000
1000-10000
10000-100000
10 2570-4230
92000
57-98
640-8650
100-1000
0-100
0-100
0-100
0-100
100-1000
100-1000
8500000
4330000
5000
30000
50 62000-82000
100-1000
10000-100000
5 130000-180000
1000-10000
10000-100000
10000-100000
1000000
NO. OF
DATA
POINTS
3
3
15
1
10
1
1
13
1
1
3
2
3
4
5
4
3
3
5
6
5
6
4
1
1
1
1
3
AVERAGE
EFFLUENT
CONCENTRATION
(PPD)
76.000
10.000
10.000
4.000
113.000
10.000
10.000
0.300
0.300
5.000
1.000
5.000
20.000
12.000
420.000
12.000
10.000
12.000
22.300
42.000
10.000
11.000
10.000
10.000
7.000
2.000
1.000
7.000
84.000
200000.000
12000.000
500.000
500.000
10950.000
57.000
500.000
5.000
500.000
1000.000
500.000
220000.000
RECOVERY REMOVAL
(*) (*)
99.96
99.94
99.75
91.2
99.9
91
92.5
36
94.7
99.71
99.95
96.3
88
86
97.2
98.2
97.8
35
99.7
90
98.3
72
98.3
99.9
90
98.8
98.9
95.7
REFERENCE
BDAT |
BOAT 1
BDAT 1
BDAT |
BDAT if
*ERL
*ERL
BDAT i
ViERL
viEM,
>iAO
WAO
WERL
*'ERL
«ERL
ITD-L *
»m
WERL
ITD-L *
BDAT i
BDAT |
BDAT 1
WERL
HERL
WERL
HERL
KERL
WERL
'OSL
BDAT 1
»AO
tfAO
MAO
MAO
*ERL
WERL
«AO
»ERL
ViERL
>iERL
*ERL
I ITD data presented in the BDAT Solvents Rule F001-F005 Background Document.
* Data used in developing proposed standard.
4-86
-------
Trihromomethane (D225). The data available for tribromomethane were
compiled from the WERL and NPDES databases and are presented in Table 4-41.
Technologies for which data are available include AL, AS, AirS, BT, CAC,
CAC+AirS, RO, and TF. The treatment performance data represent bench-, pilot-
, and full-scale studies. The resulting effluent concentrations ranged from
0.01 ppb to 201.0 ppb.
BDAT for tribromomethane is being promulgated as proposed and is
identified as reverse osmosis (RO). Reverse osmosis was selected as BDAT
since these data represent full-scale substantial treatment by a demonstrated
technology with a high influent concentration. The BDAT treatment standard
for tribromomethane was calculated using the effluent concentration of 110 ppb
and the appropriate variability factor and accuracy correction factor. The
calculation of the resulting BDAT treatment standard for tribromomethane (0.63
ppm) is described in Section 6.0 and is shown in Table 6-10.
TABLE 4-41
WASTEWATER TREATMENT PERFORMANCE DATA
FOR TmBSOHOMETHANE
TECHHOLOGY
AL
AL
AS
AS
AS
AirS
AirS
AirS
AirS
BT
BT
CAC
CAOAirS
* RO
TF
TF
DETECTION RANGE
TECHHOLOGY FACILITY LIMIT IMFLDEHT
SIZE (ppb) CONCENTRATION
(PPb)
pjiot
Pilot
Full
Pilot
Pilot
Bench
Pilot
PUot
Pilot
Full
Pull
Pilot
Full
F,ull
PHot
Pilot
KY0003603
LA0005983
PA0011371
NU0108154
AZ0000108
AZ0000108
AZ0000108
LA0065501
LA0066435
LA0066214
HJ0028291
NY0165166
203A
203A
IB
203A
240A
1328E
434B
434B
369A
PA0008419
LA0038245
203A
1833D
250B
240A
203A
0-100
0-100
0-100
0-100
0-100
100-1000
100-1000
1000-10000
0-100
100-1000
0-100
10000-100000
0-100
0-100
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (i) (I)
(PPb)
1
66
8
8
11
11
11
6
13
15
4
14
14
1
14
13
4
4
11
38
14
5
13
14
5.000
0.010
1.000
1.750
5.455
1.336
4.109
8.300
4.000
11.786
1.000
2.000
15.000
22.000
4.000
29.000
14.000
79.000
8.600
59.000
8.800
201.000
5.440
114.000
0.100
110.000
10.000
41.000
83
76
90.5
68
76
71
99
97
84
0
75
99.6
83
54
REFERENCE
NPDES
NPDES
JfPDES
NPDES
NPDES
NPDES
NPDES
NPDES
tfPDES
NPDES
HPDES
NPDES
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
NPDES
HPDES
WERL
WERL
WERL *
WERL
WERL
* Data used in developing proposed standard.
4-87
-------
1.1-^L-Trichloroe thane (U226). Several sources of wastewater
treatment performance data were available for 1,1,1-trichloroethane, including
data from the ITD and WERL databases, BOAT Solvents Rule data, and literature
WAO data. These data are presented in Table 4-42. Technologies for which
data are available include AL, AS, AirS, BT, GAG, PACT", RO, SS, TF, and WOx.
The treatment performance data represent bench-, pilot-, and full-scale
studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BDAT for 1,1,1-trichloroethane is being promulgated'as proposed and
is identified as steam stripping (SS). The BDAT treatment standard was
calculated using the ITD median long-term average of 10 ppb and the ITD Option
1 variability factor. The calculation of the resulting BDAT treatment
standard for 1,1,1-trichloroethane (0.054 ppm) is described in Section 6.0 and
is shown in Table 6-10.
4-88
-------
TABLE 4-42
WASTEWATER TREATMENT PERFORMANCE DATA
FOR 1,1,1-TRICHLOROETHANE
TECHNOLOGY
AL
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
.AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
DETECTION RANGE
TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCENTRATION
(ppb)
Full IB
Ful
Ful
Ful
Ful
Ful
Ful
Ful
Ful
Ful
Ful
Ful
Ful
Ful
201B
IB
234A
IB
IB
IB
IB
IB
6B
375E
IB
975B
234A
Pilot 206B
Ful
Ful
Ful
Ful
Ful
Ful
Ful
Ful
Ful
Put
Ful
Ful
Pul
Ful
Pul
Ful
IB
IB
IB
IB
IB
234A
238A
234A
IB
238A
1587E
IB
375E
IB
IB
1 IB
Full IB
Full IB
Full 234A
Bench 202D
P;lot REF6
Pilot REP2
0-100
0-100
0-100000
1000-10000
1000-10000
0-100
0-100
0-100
100-1000
100-1000
0-100
0-100
100-1000
0-100
100-1000
100-1000
100-1000
0-100
0-100
100-1000
0-100
0-100
0-100
0-100
0-100
100-1000
100-1000
0-100
0-100
0-100
0-100
100-1000
0-100
0-100
0-100
100000-1000000
237
150000
HO. OF
DATA
POINTS
5
6
4
6
5
4
5
6
3
7
4
20
5
6
6
4
6
3
3
3
5
7
3
3
3
5
5
3
6
AVERAGE
EFFLUENT RECOVERY REMOVAL
CONCENTRATION (1) (t)
(ppb)
10.000
21.000
10.000
1.300
850.000
9.000
10.000
10.000
12.000
10.000
1.000
12.000
4.000
1.000
0.300
54.000
5.000
30.000
5.000
28.000
1.300
2.200
1.300
2.000
2.900
0.270
100.000
1.000
7.000
8.000
2.000
8.000
1.000
4.000
1.300
1600.000
23.000
48683.000
90
79
89
99.88
87
84
84
81
90
98.9
92.3
87
98.1
97.6
99.77 '
89
96.2
39
95
94.3
76
85
73
95.8
77
99.73
70
92.3
83
84
95.8
97.2
98.4
88
88
98.6
REFERENCE
WERL
WERL
XERL
WERL
XERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
mi
WERL
WERL
WERL
WERL
WERL
WEPL
WERL
WERL
BOAT i
BOAT I
ITD data presented in the BOAT Solvents Rule F001-F005 Background Docunent.
4-89
-------
. TABLE 4-42 (Continued)
WASTEWATER TREATMENT PERFORMANCE DATA
FOR 1,1,1-TRICHLOROETHANE
TECHNOLOGY
AirS
AirS
AirS
AirS
AirS
AirS
AjrS
AirS
AirS
AirS
AirS
AirS
BT
GAC
GAC
GAC
GAC
PACT
PACT
PACT
RO
RO
RO
RO
SS
* SS
SS
TP
TF
TF
UV [B]
f v\
WOx
WO*
TECHNOLOGY
SIZE
Pilot
Pilot
Pilot
Pilot
Pilot
Pilot
Pilot
Pilot
Pilot
Pilot
Full
Pilot
Full
Bench
Full
Full
Pilot
Bench
Bench
Pfl?t
Pull
Pilot
Full
fai
Pilot
Pull
Full
Full
Full
Bench
Full
Full
FACILITY
211B
207B
812E
222B
812E
211B
1362E
812E
217B
205E
1344E
219B
P240
1362E
1264B
1264B
812E
242E
Zinpro
Zinpro
180A
250B
323B
250B
6B
913
REF2
375E
IB
IB
IB
1133E
REF10
Zmpro
242E
DETECTION RANGE
LIMIT IHFLCENT
(ppb) CONCENTRATION
(PPb)
0-100
0-100
1000-10000
100-1000
0-100
100-1000
1000-10000
100-1000
0-100
100-1000
100-1000
0-100
10-215
10-100
0-100
100-1000
100-1000
100-1000
4970
405
0-100
100-1000
0-100
100-1000
10000-100000
10 11900-35000
150000
0-100
0-100
100-1000
0-100
0-100
370000
50 6900-9600
100000-1000000
NO. OF
DATA
POINTS (
1
1
1
1
3
1
1
3
1
1
1
14
5
7
5
6
5
1
2
AVERAGE
EFFLUENT RECO
30NCENTRATION (\
(ppb)
1.000
0.500
49.000
1.100
3.000
1.700
130.000
12.000
0.300
7.000
0.200
0.500
10.000
1.000
1.000
1.000
1.000
25.000
1.000
25.000
0.050
36.000
2.000
10.000
10.000
10.000
463.000
1.000
2.000
2.000
5.000
30.000
1000.000
400.000
;ERY REMOVAL
) (*)
98.8
97.5
95.9
99.75
92.9
99.5
97.8
39
97
96.8
99.98
96.7
99.99
96.6
99.35
99.05
93.3
99.9
93.8
98.2
95.6
97.8
93.8
99.94
50
92.6
98.3
92.2
40
99.96
REFERENCE
*ERL
'i^ERL
*'ERL
WERL
*ERL
*ERL
*ERL
viERL
AERL
XERL
«ERL
viERL
BOAT 1
viERL
KERL
rfERL
WERL
«ERL
«AO
no
VOL
MEM.
WERL
WERL
WERL
ITD-L *
BOAT \
WERL
»ERL
MERL
VIERL
WERL
BOAT 1
WAO
»ERL
I ITD data presented in the BDAT Solvents Rule F001-F005 Background Docunent.
* Data used in developing proposed standard.
4-90
-------
1.1~2-Trichloroethane (D227). Several sources of wastewater
treatment performance data were available for 1,1,2-trichloroethane, including
data from the ITD and WERL databases and literature PACT* data. These data
are presented in Table 4-43. Technologies for which data are available
include AS, PACT", SS, and WOx. The treatment performance data represent
bench-, pilot-, and full-scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BOAT for 1,1,2-trichloroethane is being promulgated as proposed and
is identified as steam stripping (SS). The BDAT treatment standard was
calculated using the ITD median long-term average of 10 ppb and the ITD Option
1 variability factor. The calculation of the resulting BDAT treatment
standard for 1,1,2-trichloroethane (0.054 ppm) is described in Section 6.0 and
is shown in Table 6-10.
4-91
-------
TABLE 4-43
WASTEHATER TREATMENT PERFORMANCE DATA
FOR 1,1,2-TRICHLOROETHANE
TECHNOLOGY TECHNOLOGY FACILITY
SIZE
AS Full 6B
AS Pilot 206B
AS Full 6B
AS Full IB
AS Pilot 241B
PACT Bench 242E
PACT Bench 190E
PACT Bench Zinpro
SCOx Pilot 65D
* SS Fu
* SS Fu
SS FU
SS Fu
SS Fu
1 913
415T
66
6B
1 251B
SS Full 251B
»0x Full 242E
DETECTION RANGE
LIMIT INFLUENT
(ppb) CONCENTRATION
(PPb)
100-1000
100-1000
0-100
0-100
100-1000
0-100
1000-10000
30
100000-1000000
10 416-26400
10 220-14500
10000-100000
1000-10000
1000-10000
1000-10000
10000-100000
NO. OF AVERAGE
DATA EFFLDENT RECOVERY REMOVAL
POINTS CONCENTRATION (») (1)
(PPb)
3
20
3
3
5
1
14
15
2
8
10
10
18
28
10
5
110
5
4
5
36
11
10
10
10
10
5
30
.000
.000
.000
.000
.000
.000
.200
.000
.000
.200
.000
.000
.000
.000
.000
.000
97.1
79
60
88
54
83
99.68
33
99.98
99.96
99.85
99.87
99.91
99.91
REFERENCE
XERL
ML
KERL
>!ERL
*ERL
mi
*ERL
>'AO
SEW,
ITD-L *
IID-L *
MERL
iJERL
ViERL
>IERL
HERL
Data used in developing proposed standard.
4-92
-------
Trichloroethene (U228). Several sources of wastewaCer treatment
performance data were available for trichloroethene, including data from the
ITD and WERL databases, BOAT Solvents Rule data, BOAT test data, and
additional literature data. These data are presented in Table 4-44.
Technologies for which data are available include Chred, AS, AirS, BT, BT+AC,
CAC+Air S, ChOx, GAG, PACTR, RO, SS, TF, and WOx. The treatment performance
data represent bench-, pilot-, and full-scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BDAT for trichloroethene is being promulgated as proposed and is
identified as steam stripping (SS). The BDAT treatment standard was
calculated using the ITD median long-term average of 10 ppb and the ITD Option
1 variability factor. The calculation of the resulting BDAT treatment
standard for trichloroethene (0.054 ppm) is described in Section 6.0 and is
shown in Table 6-10.
4-93
-------
TABLE 4-44
MASTEHATER TREATMENT PERFORMANCE DATA
FOR TRICHLOROETHEHE
TECHNOLOGY
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AjrS
AjrS
AjrS
AjrS
AirS
TECHNOLOGY FACILITY
SIZE
Bench 202D
Ful
Fu..
Fu
Fu.
FU:
Ful
1 IB
1 IB
L 6B
1 1587E
L 375E
1 IB
Pilot 206B
Full 238A
Pull IB
Pilot 241B
Pull IB
Pul
Ful
Ful
Ful
Ful
Ful
Ful
Ful
Ful
Ful
Ful
Pilo
Piloi
Ful
1 234A
201B
IB
IB
6B
238A
234A
IB
IB
IB
IB
IB
I 1362E
: 209B
199B
Pilot 26A
Pilot 216B
Pilot 219B
DETECTION RANGE
LIMIT INFLUENT
(ppb) CONCENTRATION
(PI*)
10000-100000
0-100
100-1000
100-1000
0-100
0-100
0-100
100-1000
0-100
100-1000
100-1000
100-1000
0-100
0-100
0-100
0-100
0-100
0-100
0-100
100-1000
100-1000
0-100
100-1000
0-100
1000-10000
100-1000
100-1000
100-1000
100-1000
100-1000
NO. OF
DATA
POINTS
4
'6
3
i
6
20
3
4
5
6
6
6
5
5
3
5
6
4
6
5
3
1
1
AVERAGE
EFFLDENT
CONCENTRATION
(PPb)
210.000
5.000
2.000
10.000
0.100
2.500
1.000
1.500
2.100
3.000
7.000
64.000
0.700
13.000
2.000
1.000
10.000
0.500
0.700
31.000
87.000
4.000
37.000
16.000
1.000
0.800
1.500
27.000
2.100
0.500
RECOVERY REMOVAL
(*) (*)
99.78
89
99.23
94.1
95.7
58
96.7
98.6
90.6
97.3
96.7
87
71
87
97.6
98.5
89
94.8
92.3
74
87
89.7
92.6
72
99.94
99.58
99.75
87
98.9
99.58
REFERENCE
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
HERL
WERL
•mi
WERL
WERL
WERL
WERL
4-94
-------
• TABLE 4-44 (Continued)
VJASTEWATER TREATMENT PERFORMANCE DATA
FOR TRICHLOROETHENE
TECHNOLOGY TECHNOLOGY FACILITY
SIZE
AirS Pilot 369A
AirS Pilot 211B
AirS Pilot 205E
AirS Pilot 220B
AirS Pilot 217B
AirS Full 322B
AirS Pilot 1327E
AirS Pilot 212B
AirS Full 223B
AjrS Full 69A
AirS Pilot 369A
AirS Pile
AjrS Pil<
AjrS P}1<
A;rS ?U<
A}rS Pil<
)t 221B
)t 1585E
)t 1363E
)t 1327E
)t 211B
A;rS Full 1042E
AirS PUot 215B
AirS Pilot 208B
A;rS Pilot 222B
AirS Full 322B
AjrS PUot 1585E
AjrS PUot 71D
AirS Pile
BT Fu
BT Pu
BT Fu
BT Fu
BTtAC Fu
)t 207B
1 REF4
1 P213
.1 P217
1 P253
LI P246
CAC+AirS Full 1833D
CnOx Pilot 2026A
DETECTION RANGE
LIMIT INFLUENT
(ppb) CONCENTRATION
(Ppb)
0-100
100-1000
0-100
100-1000
100-1000
100-1000
1000-10000
0-100
0-100
0-100
0-100
0-100
0-100
100-1000
0-100
1000-10000
0-100
0-100
0-100
0-100
1000-10000
1000-10000
100-1000
0-100
60
16-76
98-224
484
40-70
0-100
0-100
NO. OF
DATA
POINTS
1
1
1
10
1
1
1
1
1
1
1
1
1
1
1
1
3
3
1
3
20
4
AVERAGE
EFFLDENT RECOVERY
CONCENTRATION (1)
(ppb)
0
3
1
0
1
0
190
0
0
1
3
0
4
5
4
7
0
0
0
0
11
170
5
0
5
10
10
16
10
0
3
.300
.100
.000
.200
.200
.460
.000
.400
.500
.400
.000
.500
.300
.000
.300
.700
.300
.500
.700
.300
.000
.000
.000
.500
.800
.000
.000
.000
.000
.200
.700
REMOVAL
(*)
99.44
98.6
97.2
99.92
99.69
99.91
91.3
99.6
98.2
98.1
93.2
99.44
87
97.1
87
99.3
99.68
98
99.03
99.21
99.77
84
98.5
98.7
90
96.2
REFERENCE
ViERL
'mi
•mi
ViERL
ViERL
"viERL
VjERL
XERL
mi
ViERL
ViERL
WERL
SERL
ViERL
ViERL
'mi
ViERL
ViERL
ViERL
mi
WERL
WERL
BDAT
BDAT i
BOAT-
BDAT
BDAT :
WERL
WERL
I ITD data presented in the BDAT Solvents Rule F001-F005 Background Docuaent.
4-95
-------
• TABLE 4-44 (Continued)
WASTEWATER TREATMENT PERFORMANCE DATA
FOR TRICHLOROETHENE
TECHNOLOGY
ChOx
Chred
Chred
Chred
GAC
GAC
GAC
GAC
GAC
GAC
GAC
PACT
PACT
PACT
PACT
RO
RO
RO
* SS
SS
SS
SS
SS
* SS
SS
TF
TP
TP
TF
TP
UV [Bl
wox1 '
HOx
WOx [B]
TECHHOLOGY FACILITY
SIZE
Pilot 2026A
Pilot
Bench
Bench
Full 1264B
Fu.
Fu
Fu
Fu
Ful
1 1264B
245B
1264B
245B
1 237A
Pilot REF8
Benc
Benc
Benc
Benc
Ful
Ful
Pilo
Fu
Fu
Fu
Fu
Fu
FU
FU
Pu
Pu
Fu
Fu
1 242E
i Zinpro
i Zjnpro
i Zinpro
250B
250B
323B
415
251B
6B
6B
251B
913
P284
IB
IB
IB
IB
Full IB
Bench U38E
Bench Zjnpro
Bench Zinpro
Bench 78D
DETECTION RANGE
LIMIT INFLUENT
(ppb) CONCENTRATION
(PPb)
100-1000
200
280
300
100-1000
0-100
100-1000'
0-100
1000-10000
100-1000
171
0-100
326
90
32.8
100-1000
0-100
0-100
10 59-10300
1000-10000
1000-10000
10000-100000
1000-10000
10 22900-52700
10-10300
0-100
100-1000
0-100
0-100
0-100
0-100
500000
300000
100000-1000000
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (1) (1)
(PPb)
1
1
1
1
1
1
1
1
1
1
1
15
10
14
2
10
14
15
6
5
5
5
6
1
1
7.100
5.000
3.900
0.400
1.000
1.000
10.000
1.300
10.000
10.000
0.590
10.000
1.000
10.000
0.005
110.000
5.500
68.000
16.100
5.000
16.000
10.000
10.000
10.000
16.000
1.000
1.000
1.000
1.000
5.000
22.000
1700.000
2000.000
1700.000
94.4
99.36
98.8
97.8
98.6
99.46
95.8
89
99.7
89
99.98
78
79
30
99.91
99.20
99.97
99.79
98.8
-99.33
98.5
98.4
93.2
56
99.7
99.3
99.66
REFERENCE
WERL
ART
ART
ACT
WERL
WERL
WERL
*m
*ERL
WERL
BOAT |f
rmi
WAO
MAO
WAO
WERL
WERL
WERL
ITD-L *
WERL
WERL
KERL
KERL
ITD-L *
BOAT |
WERL
WERL
WERL
WERL
WERL
WERL
WAO
WAO
WERL
t ITD data presented in the BOAT Solvents Rule F001-F005 Background Docunent.
* Data usedin developing proposed standard.
4-96
-------
Trichloromonofluoromethane (U121). The data available for
trichloromonofluoromethane were compiled from the WERL and NPDES databases,
the BOAT database, and BOAT Solvents Rule data. These data are presented in
Table 4-45. Technologies for which data are available include AS, AirS+GAC,
BT, LL, LL+SS, LL+SS+AC. The treatment performance represents full-scale
studies. The resulting effluent concentrations ranged from 1 ppb to
2,400 ppb.
BOAT for trichloromonofluoromethane is being promulgated as proposed
and is identified as liquid-liquid extraction followed by steam stripping
followed by activated carbon (LL + SS + AC). LL+SS+AC was selected as
BOAT since this treatment train has the best removal from those data developed
for BOAT (K103/K104) using BOAT guidelines. The BOAT treatment standard for
trichloromonofluoromethane was calculated using the effluent concentration of
7 ppb and the appropriate variability factor and accuracy correction factor.
The calculation of the resulting BOAT treatment standard for
trichloromonofluoromethane (0.020 ppm) is described in Section 6.0 and is
shown in Table 6-10.
4-97
-------
TABLE 4-45
WASTEWATER TREATMENT PERFORMANCE DATA
FOR TRICHLOROHONOPLUOROMETHAME
TECHNOLOGY
AS
AirS+GAC
BT
BT
LL
LL
LL+SS
* LL+SS+AC
DETECTIOM RANGE
TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCEMTRATIOM
(ppb)
KY0003603
BY0157112
NY0157112
NJ0028291
NY0002101
NY0199371
NY0002101
LA0065501
AZ0000108
AZ0000108
LA0066435
AZ0000108
HY0005096
NY0005096
NY0007048
HY0177482
Full
Ful
Ful.
Fui:
Ful
Fui:
Ful
Ful]
IB
229A
LA0038245
REF4
K104
K103
K103/K104
K103/K104
5
5
5
5
100-1000
0-100
920
250-20000
2500-5000
250-20000
250-20000
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL REFERENCE
POINTS CONCENTRATION (1 (1)
(ppb)
1
1
1
2
8
19
8
6
11
11
13
11
1
15
9
42
19
37
1
5
5
5
4
64.000
30.000
30.000
1.000
8.750
2.000
8.125
10.000
1.000
1.009
4.846
1.736
10.000
10.000
1.000
3.200
4.000
1.000
16.541
13.000
2400.000
1250.000
105.000
7.000
NPDES
NPDES
NPDES
NPDES
HPDES
HPDES
HPDES
NPDES
HPDES
NPDES
HPDES
NPDES
NPDES
NPDES
HPDES
NPDES
97.9 »ERL
98.6 «ERL
NPDES
BDAT 1
BOAT
BDAT
BDAT
BDAT *
i ITD data presented ii) the BOAT Solvents Rule F001-F005 Background Docunent.
* Data usw in developing proposed standard.
4-98
-------
1.2-^3-Trichloropropane. No wastewater treatment performance data
were available for 1,2,3-trichloropropane from any of the examined sources.
Treatment performance data were therefore transferred to this constituent from
a constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
1,2,3-Trichloropropane is similar in structure to those constituents in
treatability group II.A.2.b.(3) and the constituent used to transfer treatment
performance data from was 1,2-dichloropropane. The treatment performance data
for 1,2-dichloropropane is presented in Table 4-23. Using a transfer from
this constituent results in a BOAT for 1,2,3-trichloropropane of activated
sludge biological treatment and a BOAT treatment standard of 0.85 ppm as
described in Section 6.0 and shown in Table 6-10.
4-99
-------
1. l-f2-Trichloro-l.2.2-Trifluoroethane. The data available for
1,1,2-trichloro-1,2,2-trifluoroethane were compiled from the WERL and NPDES
databases and are presented in Table 4-46. The technology for which data were
available was WOx. The treatment performance data represent pilot-scale
studies with data effluent concentrations ranging from 1 ppb to 2,000 ppb.
At proposal, BOAT for l,l,2-trichloro-l,2,2-trifluoroethane was
identified as wet air oxidation and the treatment standard was based on the
effluent concentration of 2,000 ppb. However, upon further evaluation of this
data, EPA does not believe that this effluent concentration established in the
UAO test represents BOAT effluent values that are achievable. Therefore, EPA
is not basing the BOAT standard for l,l,2-trichloro-l,2,2-trifluoroethane on
the wet air oxidation test results but is rather transferring treatment
performance data from hexachloroethane. The treatment performance data for
hexachloroethane are presented in Table 4-97. Using a transfer from this
constituent results in a BDAT for 1,1,2-trichloro-1,2,2-trifluoroethane of
activated sludge biological treatment followed by filtration and a BDAT
treatment standard of 0.057 ppm as described in Section 6.0 and shown in
Table 6-10.
FOR
TABLE 4-46
WASTEWATER TREATMENT PERFORMANCE DATA
DETECTION RANGE NO. OF AVERAGE
TECHHOLOGY TECHNOLOGY FACILITY LIMIT IHFLCEHT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (\) (1
(ppb) (ppb)
NY0005096
NY0003395
NY0005860
M 0005860
NY0005860
HY0005860
NY0107409
* »OX Pilot 78D
14
6
1
17
9
2
1000000
10.000
5.000
10.000
1.000
1.000
3.100
1.000
2000.000
WPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
99.93. WERL *
* Data used in developing proposed standard.
4-100
-------
Vinvl Chloride (U043). Two sources of wastewater treatment
performance data were available for vinyl chloride, including data from the
ITD and WERL databases. These data are presented in Table'4-47. Technologies
for which data are available include AS, AS+Fil, AirS, and SS. The treatment
performance data represent pilot- and full-scale data.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BOAT for vinyl chloride is being promulgated as proposed and is
identified as steam stripping (SS). The BDAT treatment standard was
calculated using the ITD median long-term average of 50 ppb and the ITD Option
1 variability factor. The calculation of the resulting BDAT treatment
standard for vinyl chloride (0.27 ppm) is described in Section 6.0 and is
shown in Table 6-10.
4-101
-------
TABLE 4-47
WASTEWATER TREATMENT PERFORHAHCE DATA
FOB VIHYL CHLORIDE
TECHNOLOGY
AS
AS
AS
AS
AS-Fil
AirS
AirS
AirS
SS
* SS
* SS
SS
TECHNOLOGY FACILITY
SIZE
Full 6B
Full IB
Full IB
Full IB
Full 6B
Pilot 217B
Fill.
FuL
Ful
Fui:
Ful
1344E
69A
251B
913
725
Full 6B
DETECTION RANGE
LIMIT INFLUENT
(ppb) CONCENTRATION
(ppb)
50
50
100-1000
1000-10000
0-100
10000-100000
1000-10000
0-100
100-1000
0-100
1000-10000
50-3500
410000-2230000
1000000
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (1) (*)
(Ppb)
3
6
4
6
14
1
10
14
13
11
50.000
100.000
20.000
3900.000
50.000
0.500
0.100
0.300
10.000
50.000
37944.200
120.000
94.9
94.1
80
92.9
98.3
93.1
99.99
96.4
99.88
99.99
REFERENCE
*ERL
*ERL
XERL
'mi
*ERL
AERL
-ERL
viEPL
*ERL
ITD-L *
ITD-L *
WERL
Data used in developing proposed standard.
4-102
-------
XvLanes (U239). The data available for xylenes were compiled from
the NPDES and WERL database, BOAT Solvents Rule data, and literature WAO and
PACTR data. These data are presented in Tables 4-48, 4-49, 4-50, and 4-51.
Technologies for which data are available include AS, AirS, PACT", RO, GAG,
and WOx. The treatment performance data represent bench-, pilot-, and full-
scale studies. The resulting effluent concentrations ranged from 0.1 ppb to
20,000 ppb, with a detection limit established at 0.5 ppb (see Table C-l,
Appendix C).
The proposed and promulgated BOAT standard for xylenes was set using
the combined data of all three isomers. WOx technology and an achievable
effluent of 56 ppb were selected. WOx and RO were the only full-scale data
available at the higher concentration ranges. The RO study was not able to
achieve the low effluent concentrations the WOx technology achieved.
Therefore, WOx was selected as BDAT. The 56 ppb effluent concentration is the
average of the data available for WOx full-scale studies. The resulting BDAT
treatment standard for xylenes is 0.32 ppm as shown in Table 6-10.
4-103
-------
TABLE 4-48
WASTEWATER TREATMENT PERFORMANCE DATA
FOR 1,2-XYLENE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (I) (I)
(ppb) (ppb)
AS
AS
AirS
PACT
PACT
RO
* Wx
Full
Bench
Pilot
Bench
Bench
Full
Full
NY0183628
1587E
200B
224B
242E
Iinpro
250B
242E
0-100
100-1000
0-100
0-100
79
10000-100000
10000-100000
3
15
1
1
198.330
0.100
0.900
0.500
5.000
5.000
300.000
79.000
98.6
99.2
93
93.7
94
97.8
99.92
NPDES
*ERL
*m
'/iERL
*IRL
*AO
XERL
"XERL *
* Data used in developing proposed standard.
TABLE 4-49
WASTEWATER TREATMENT PERFORMANCE DATA
FOR 1,3-XYLENE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (*) (\)
(ppb) (ppb)
AS
AirS
GAC
PACT
PACT
* WOx
Ful
Pilo
Ful
Benc
Benc
Ful
NY0183628
1587E
. 224B
1421D
1 242E
i Zinpro
L 242E
0-100
0-100
0-100
0-100
33
10000-100000
3
1
1
193.330
0.100
0.500
0.130
10.000
10.000
33.000
98.3
72
20
70
70
99.7
NPDES
WERL
WERL
WERL
•«RL
SAO
XERL *
Data used in developing proposed standard.
TABLE 4-50
WASTEWATER TREATMENT PERFORMANE DATA
FOR 1,4-XYLENE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (\) (\)
™ (ppb) (ppb)
AirS
GAC
Pilot
Pull
NY0183628
224B
1421D
0-100
0-100
3
1
198.330
0.500
0.040
90
37
NPDES
viEJL
XERL
4-104
-------
TABLE 4-51
WASTEWATER TREATMENT PERFORMANCE DATA
FOR XYLENE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (I) (*)
(ppb) (ppb)
GAC
WOX
NOX
Pilot
Pilot
REF7
REF10
Zinpro
140
21200
8385000
1
1
1
0.100
500.000
20000.000
99.8
BDAT i
BDAT |
ITD data presented in the BDAT Solvents Rule F001-F005 Background Document.
4-105
-------
4.3
Senvi-volatiles
Constituents discussed in this section include:
Acenaphthalene
Acenaphthene
Acetophenone
2 -Acetylaminofluorene
4-Aminobiphenyl
Aniline
Anthracene
Aramite
Benz(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Bis(2-chloroethoxy)raethane
Bis(2-chloroethyl)ether
Bis(2-chloroisopropyl)ether
Bis(2-ethylhexyl)phthalate
4-Bromophenyl phenyl ether
Butyl Benzyl phthalate
2 -Sec-Butyl-4,6-Dinitrophenol
p-chloroaniline
Chlorobenzilate
p-Chloro-m-cresol
2 -Chloronaphthalene
2-Chlorophenol
Chrysene
ortho-Cresol
meta/para-Cresol
Cyclohexanone
Dibenz(a,h)anthracene
Dibenzo(a,e)pyrene
m-Dichlorobenzene
o-Dichlorobenzene
p-Dichlorobenzene
2 ,4-Dichlorophenol
2,6-Dichlorophenol
Diethyl phthalate
2,4-Dimethyl phenbl
Dimethyl phthalate
Di-n-butyl phthalate
1,4-Dinitrobenzene
4,6-Dinitro-o-Cresol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6 -Dinitrotoluene
Di-n-octyl phthalate
Di-n-propylnitrosamine
Diphenylamine
Diphenylnitrosamine
1,2 -Diphenylhydrazine
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroe thane
Hexachloropropene
Indeno(1,2,3 -cd)pyrene
Isosafrole
Methapyrilene
3-Methylcholanthrene
4,4'-Methylenebis(2 -chloroaniline)
Methyl methanesulfonate
Naphthalene
2 -Naphthylamine
p-Nitroaniline
Nitrobenzene
4-Nitrophenol
N-Nitrosodiethylamine
N-Nitrosodimethylamine
N-Nitrosodi-n-butylaraine
N-Nitrosomethylethylamine
N-Nitrosomorpholine
N-Nitrosopiperidine
N-Nitrosopyrrolidine
5-Nitro-o-toluidine
Pentachlorobenzene
Pentachloronitrobenzene
Pentachlorophenol
Phenacetin
Phenanthrene
Phenol
Phthalic Anhydride
Pronamide
Pyrene
Safrole
1,2,4,5-Tetrachlorobenzene
2,3,4,6-Tetrachlorophenol
1,2,4-Trichlorobenzene
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
Tris(2,3-dibromopropyl)phosphate
4-106
-------
Aceaaohthalene. Two sources of wastewater treatment performance
data were available for acenaphthalene, including data from the ITD, and WERL
databases. These data are presented in Table 4-52. Technologies for which
data are available include AL, AS, AS+Fil, and BT. All of the treatment
performance data represent full-scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3)A promulgated ITD limit represents data that have undergone both
EPA and industry review and acceptance.
BDAT for acenaphthalene is being promulgated as proposed and is
identified as biological treatment (BT). The BDAT treatment standard was
calculated using the ITD median long-term average of 10 ppb and the ITD Option
1 variability factor. The calculation of the resulting BDAT treatment
standard for acenaphthalene (0.059 ppm) is described in Section 6.0 and is
shown in Table 6-10.
TABLE 4-52
WASTEWATES TREATMENT PERFORMANCE DATA
FOR ACENAPHTHALENE
TECHNOLOGY
AL
AS
AS+Fil
* BT
DETECTION
TECHNOLOGY FACILITY LIHIT
SIZE (ppb)
RU
Ful
Full
6B
. 6B
6B
1293 10
RANGE
INFLDENT
CONCENTRATION
(PPb)
100-1000
100-1000
1000-10000
191-699
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (*) (\)
(PPb)
13
3
15
10.000
10.000
13.000
10.000
98.4
97.9
99.87
REFERENCE
WERL
WERL
WERL
ITD-L *
Data used in developing proposed standard.
4-107
-------
Aceaaphthene. Three sources of wastewater treatment performance
data were available for acenaphthene, including data from the ITD, and WERL
databases as well as literature WAO data. These data are presented in Table
4-53. Technologies for which data are available include AS, AS+Fil, CAC, BT,
PACT", TF, and WOx. The treatment performance data represent bench-, pilot-,
and full-scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BDAT for acenaphthene is being promulgated as proposed and is
identified as biological treatment (BT). The BDAT treatment standard was
calculated using the ITD median long-term average of 10 ppb and the ITD Option
1 variability factor. The calculation of the resulting BDAT treatment
standard for acenaphthene (0.059 ppm) is described in Section 6.0 and is shown
in Table 6-10.
4-108
-------
TABLE 4-53
WASTEHATER TREATMENT PERFORMANCE DATA
FOR ACENAPHTHENE
TECHNOLOGY
AS
AS
AS
AS
AS
AS+Fil
CAC
Fll
* BT
PACT
TF
WOx
WOx [BJ
DETECTION
TECHNOLOGY FACILITY LIMIT
SIZE (ppb)
Ful
Pilo
Ful
Ful.
fa.
L 975B
. 204A
6B
201B
6B
6B
Pilot 195B
ft
Benc
Ful
Benc
792E
1293 10
l 975B
IB
i Ziroro
Bench 236A
RANGE
INFLUENT
CONCENTRATION
0-100
0-100
0-100
100-1000
100-1000
1000-10000
0-100
0-100
513-1516
0-100
0-100
7000000
> 1000000
NO. OF
DATA
AVERAGE
EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (i)
8
7
3
13
8
it
4
1
1
4.800
1.200
10.000
1.000
10.000
13.000
10.000
2.000
10.000
4.000
6.000
500.000
2800.000
(»)
77
97
90
99.44
98.9
99.66
67
83
90
86
99.99
99.96
REFERENCE
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
ITD-L *
WERL
WERL
WAO
WERL
* Data used in developing proposed standard.
4-109
-------
Ace-tophenone (U004). The data available for acetophenone were
compiled from the NPDES database and are presented in Table 4-54A. In
addition, leachate treatment performance data submitted by industry prior to
proposal are presented in Table 4-54B. The treatment technology for which
data are available is BT and the resulting average effluent concentration from
the leachate data is 2.9 ppb.
At proposal, BDAT for acetophenone was not identified and the
treatment standard was based on an effluent concentration of 10,361 ppb from •
data in the NPDES database. Between proposal and promulgation, EPA evaluated
the industry-submitted leachate data available for acetophenone. Since these
data for biological treatment (BT) showed substantial treatment of
acetophenone, these data were used to calculate the promulgated standard.
Therefore, BDAT for acetophenone is biological treatment.
The BDAT treatment standard for acetophenone was calculated using
the effluent concentration of 2.9 ppb and the appropriate variability factor
and accuracy correction factor. The calculation of the resulting BDAT
treatment standard for acetophenone (0.010 ppm) is described in Section 6.0
and is shown in Table 6-10.
TABLE 4-54A
WASTEHATER TREATMENT PERFORMANCE DATA
FOR ACETOPHENONE
TECHNOLOGY TECHNOLOGY
SIZE
*
FACILITY
NH0001571
DETECTION
LIMIT
(PPb)
RANGE
INFLDENT
CONCENTRATION
(ppb)
NO. OF
DATA
POINTS
32
AVERAGE
EFFLUENT
CONCENTRATION
(ppb)
10361.56
RECOVERY
W
REMOVAL
(*)
REFERENCE
NPDES *
Data used in developing proposed standard.
TABLE 4-54B
INDUSTRY-SUBMITTED LEACHATE TREATMENT PERFORMANCE
DATA FOR ACETOPHENONE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (I) (})
(ppb] {ppb]
CWH 2.9 35 1 2.900 91.71 LEACHATE
4-110
-------
2-Acetvlaminofluorene (U005). No wastewater treatment performance
data were available for 2-acetylaminofluorene from any of the examined
sources.
Treatment performance data were therefore transferred to this
constituent from a constituent judged to be similar in elemental composition
and functional groups within the structure of the chemical. For constituents
represented by a U or P code, this means that constituents included in the
same waste treatability group (see Appendix B) were candidates for transfer of
data. 2-Acetylaminofluorene is in treatability group III.A.3.c and the
constituent used to transfer treatment performance data from was
benz(a)anthracene. The treatment performance data for benz(a)anthracene is
presented in Table 4-57. Using a transfer from this constituent results in a
BOAT for 2-acetylaminofluorene of biological treatment and a BOAT treatment
standard of 0.059 ppm as described in Section 6.0 and shown in Table 6-10.
4-111
-------
4-Aminobiphenvl. No wastewater treatment performance data were
available for 4-aminobiphenyl from any of the examined sources. Treatment
performance data were therefore transferred to this constituent from a
constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
4-Aminobiphenyl is similar in structure to constituents in treatability group
III.A.2.f.(1) and the constituent used to transfer treatment performance data
from was 3,3'-dichlorobenzidine. The treatment performance data for 3,3'-
dichlorobenzidine are presented in Table 4-80. Using a transfer from this
constituent results in a BOAT for 4-aminobiphenyl of aerated lagoon biological
treatment and a BOAT treatment standard of 0.13 ppm as described in Section
6.0 and shown in Table 6-10.
4-112
-------
Aniline (U012). The data available for aniline were compiled from
the NPDES, WERL, and BDAT databases and are presented in Table 4-55.
Technologies for which data are available include AS, BT, CA, LL, LL+SS* and
LL+SS+AC. The treatment performance data represent both pilot- and full-scale
studies. The resulting effluent concentrations ranged from 4.95 ppb to
165,000 ppb.
BDAT for aniline is being promulgated as proposed and is identified
as liquid liquid extraction followed by steam stripping followed by activated
carbon (LL+SS+AC). LL+SS+AC was selected as BDAT because it represents the
best full-scale technology with data developed under BDAT guidelines
(K103/K104). The BDAT treatment standard for aniline was calculated using the
effluent concentration of 262 ppb and the appropriate variability factor and
accuracy correction factor. The calculation of the resulting BDAT treatment
standard for aniline (0.81 ppm) is described in Section 6.0 and is shown in
Table 6-10.
TABLE 4-55
WASTEWATER TREATMENT PERFORMANCE DATA
FOR ANILINE
TECHNOLOGY
AS
BT
CA
LL
LL
LL+SS
* LL+SS+AC
TECHNOLOGY FACILITY
SIZE
Pilo
Fu
Fu
Fu
Fa
Fu
Fu
CT0001341
NJ0005291
SC0000914
t 226B
1 TX0002933
NJ0004219
K104
K103
K103/K104
1 K103/K104
DETECTION
LIMT
(PPb)
30
30
30
30
RANGE
INFLUENT
CONCENTRATION
(PPD)
100000-1000000
150000-300000
33000000-53000000
150000-53000000
150000-53000000
NO. OF
DATA
POINTS
1
• 16
12
13
49
2
5
5
4
AVERAGE
pppT npwp
CONCENTRATION
(ppb)
10.000
7383.300
10.000
80.000
22.670
4.950
165000.000
90800.000
2400.000
262.000
RECOVERY
(*)
91
91
91
91
REXOVAL REFERENCE
(*)
NPDES
NPDES
NPDES
99.93 WERL
NPDES
NPDES
BDAT
BDAT
BDAT
BDAT *
Data used in developing proposed standard.
4-113
-------
Anthracene. Two sources of wastewater treatment performance data
were available for anthracene, including data from the ITD and WERL databases.
These data are presented in Table 4-56. Technologies for which data are
available include AS, AS+Fil, BT, and TF. The treatment performance data
represent pilot- and full-scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BDAT for anthracene is being promulgated as proposed and is
identified as biological treatment (BT). The BDAT treatment standard was
calculated using the ITD median long-term average of 10 ppb and the ITD Option
1 variability factor. The calculation of the resulting BDAT treatment
standard for anthracene (0.059 ppm) is described in Section 6.0 and is shown
in Table 6-10.
TABLE 4-56
HASTEWATER TREATMENT PERFORMANCE DATA
FOR ANTHRACENE
TECHNOLOGY
AS
AS
AS
ASfPil
Fll
* BT
TP
TECHNOLOGY
SIZE
Fill
Pul
PllO
Fll
Pu
Fll
Pul
FACILITY
6B
IB
204A
6B
792E
1293
IB
DETECTION
(Ppb)
10
RANGE
INFLDENT
CONCENTRATION
100-1000
0-100
0-100
1000-10000
0-100
418-943
100-1000
NO. OF
DATA
POINTS
14
4
8
3
15
6
AVERAGE
EFFLUENT RECOVERY
CONCENTRATION (1)
(ppb)
10.000
13.000
0.900
10.000
1.000
10.000
17.000
REMOVAL
(*)
98.6
82
97.4
99.52
97.2
92.3
REFERENCE
WERL
WERL
WERL
WERL
WERL
ITD-L
WERL
*
Data used in developing proposed standard.
4-114
-------
Aramite. No wastewater treatment performance data were available
for aramite from any of the examined sources. Treatment performance data were
therefore transferred to this constituent from a constituent judged to be
similar in elemental composition and functional groups within the structure of
the chemical. For constituents represented by a U or P code, this means that
constituents included in the same waste treatability group (see Appendix B)
were candidates for transfer of data. Aramite is similar in structure to
constituents in treatability group III.A.3.e and the constituent used to
transfer treatment performance data from was methyl ethyl ketone. The
treatment performance data for methyl ethyl ketone is presented in
Tables 4-32A and 4-32B. Using a transfer from this constituent results in a
BOAT for aramite of biological treatment and a BOAT treatment standard of 0.36
ppra as described in Section 6.0 and shown in Table 6-10.
4-115
-------
Benz^a')anthracene (U018). Two sources of wastewater treatment
performance data were available for benz(a)anthracene, including data from the
ITD and WERL databases. These data are presented in Table 4-57. Technologies
for which data are available include AS, AS+Fil, and BT. The treatment
performance data represent pilot- and full-scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BOAT for benz(a)anthracene is being promulgated as proposed and is
identified as biological treatment (BT). The BOAT treatment standard was
calculated using the ITD median long-term average of 10 ppb and the ITD Option
1 variability factor. The calculation of the resulting BOAT treatment
standard for benz(a)anthracene (0.059 ppm) is described in Section 6.0 and is
shown in Table 6-10.
TABLE 4-57
HASTEHATER TREATMENT PERFORMANCE DATA
FOR BENZ(a)ANTHRACENE
TECHHOLOGY
DETECTION
TECHNOLOGY FACILITY LIMIT
SIZE (ppb)
RANGE
INFLUENT
CONCENTRATION
(ppb)
NO. OF AVERAGE
DATA EFFLUENT
POINTS CONCENTRATION
(PPb)
RECOVERY REMOVAL REFERENCE
(*). (*)
AS
AS
AS
ASfFil
Fil
* BT
tffi
Fu.
^
Ful
Ful
1 201B
t 204A
6B
6B
1 792E
1293 10
0-100
0-100
100-1000
1000-10000
1000-10000
10-614
1
8
12
4
15
1.000
0.600
10.000
56.000
3.000
10.000
98.3
97.5
97
96.5
99.75
WERL
WERL
WERL
WERL
WERL
ITD-L *
Data used in developing proposed standard.
4-116
-------
Benzo(a)pvrene (D022). Two sources of wastewater treatment
performance data were available for benzo(a)pyrene, including data from the
ITD and WERL databases. These data are presented in Table 4-58. Technologies
for which data are available include AS, CAC, ChOx, GAC, BT, and TF. The
treatment performance data represent bench-, pilot-, and full-scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BDAT for benzo(a)pyrene is being promulgated as proposed and is
identified as biological treatment (BT). The BDAT treatment standard was
calculated using the ITD median long-term average of 10.3 ppb and the ITD
Option 1 variability factor. The calculation of the resulting BDAT treatment
standard for benzo(a)pyrene (0.061 ppm) is described in Section 6.0 and is
shown in Table 6-10.
4-117
-------
TABLE 4-58
WASTEWATER TREATMENT PERFORMANCE DATA
FOR BENZO(a)PYRENE
DETECTION
TECHNOLOGY TECHNOLOGY FACILITY LIMIT
SIZE (ppb)
AS Ful
AS Fu
AS Fu
AS Fu
AS Fu
1 375E
375E
375E
375E
6B
CAC Pilot 195B
ChOx(Oz) Bench 153D
Fll Full 792E
Fil Pilot 195D
GAC Pilot 195D
*
BT Full 1293 10
Sed Bench 153D
IF Full 126E
TF Full 375E
IF Full 375E
RANGE
INFLUENT
CONCENTRATION
(PPb)
0-100
0-100
0-100
0-100
100-1000
1000-10000
0-100
100-1000
0-100
1000-10000
10-426
0-100
0-100
0-100
0-100
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (!) (I I
(PPb)
7
7
7
7
10
3
4
8
8
15
n
7
0.027
0.028
0.016
0.021
10.000
20.000
1.000
1.000
10.000
20.000
10.300
4.200
0.120
0.016
0.035
86
88
97.4
86
95.2
98.2
76
99.31
50
98.2
37
25
93.6
89
REFERENCE
«ERL
MEW,
*ERL
VERL
*'ERL
VERL
SERL
VERL
XERL
VERL
ITD-L *
VERL
ViERL
*ERL
*ERL
Data used in developing proposed standard.
4-118
-------
Benzofblfluoranthene. The data available for benzo(b)fluoranthene
were compiled from the NPDES and WERL databases and are presented in Table
4-59. Technologies for which data are available include AS, BT, RO, and TF.
The treatment performance data represent pilot- and full-scale studies and the
resulting effluent concentrations ranged from 0.001 ppb to 10 ppb.
BOAT for benzo(b)fluoranthene is being promulgated as proposed and
is identified as activated sludge biological treatment (AS). Activated sludge
was selected as BOAT because it represents full-scale data with a high
influent concentration range and a high removal efficiency. The BOAT
treatment standard for benzo(b)fluoranthene was calculated using the effluent
concentration of 10 ppb and the appropriate variability factor and accuracy
correction factor. The calculation of the resulting BOAT treatment standard
for benzo(b)fluoranthene (0.055 ppm) is described in Section 6.0 and is shown
in Table 6-10.
TABLE 4-59
WASTEWTER TREATMENT PERFORMANCE DATA
FOR BENZO(b)FLUORANTHENE
TECHNOLOGY
* AS
AS
AS
AS
AS
BT
BT
RO
TF
TF
DETECTION RANGE
TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCENTRATION
(PPb)
LA0066214
HD0000345
NY0000281
NY0000281
IL0001627
MD0000345
K-0003603
KY0003514
W0004740
LA0065501
Full 6B
Ful
FVL
Fu.
Fu
FU.
Ful
Pile
375E
375E
375E
375E
LA0038245
. KY0002119
1634E
Full 375E
Full 375E
100-1000
0-100
0-100
0-100
0-100
0-100
0-100
0-100
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (!) (1)
(PPb)
15
1
9
9
1
1
1
1
6
10
7
7
7
1
38
1
7
7
10.000
10.000
5.000
4.844
10.111
10.000
10.000
10.000
10.000
10.000
10.000
0.023
0.014
0.023
0.017
10.126
10.000
0.001
0.033
0.017
95.4
88
97.8
89.6
89
92.1
89.7
93.2
REFERENCE
HPDES
HPDES
NPDES
NPDES
HPDES
NPDES
HPDES
NPDES
HPDES
HPDES
«EJL *
AERL
*ERL
«ERL
*ERL
NPDES
HPDES
*ERL
SEM,
WERL
Data used in developing proposed standard.
4-119
-------
BenzofghDpervlene. The data available for benzo(ghi)perylene were
compiled from the NPDES and UERL databases and are presented in Table 4-60.
Technologies for which data are available include AS, BT, CAC, chlorination
(ChOx(Cl)) and TF. The treatment performance data represent pilot- and full-
scale studies and the resulting effluent concentrations ranged from 0.009 ppb
to 10.108 ppb. The detection limit for benzo(ghi)perylene is 1 ppb (see Table
C-l, Appendix C).
BDAT for benzo(ghi)perylene is being promulgated as proposed and is
identified as activated sludge biological treatment (AS). Activated sludge
was selected as BDAT because of the consistency of its performance of the
full-scale technologies presented. The BDAT treatment standard for
benzo(ghi)perylene was calculated using a concentration of 1 ppb (which
represents the detection limit) and the appropriate variability factor and
accuracy correction factor. The calculation of the resulting BDAT treatment
standard for benzo(ghi)perylene (0.0055 ppm) is described in Section 6.0 and
is shown in Table 6-10.
TABLE 4-60
WASTEWATER TREATMENT PERFORMANCE DATA
FOR BENZO(qhl)PERYLENB
TECHNOLOGY
* AS
* AS
* AS
* AS
* AS
BT
CAC
ChOx(Cl)
Fil
Fil
TF
TF
DETECTION RANGE
TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCENTRATION
(ppb)
Full
FU:
Fu
Fu.
Fu
Fu]
1
.1
1
LI
1
Pilot
Full
Full
Fu
Fu
LI
1
Full
LA0066214
LA0065501
375E
375E
IB
375E
375E
LA0038245
195B
1081D
1081D
792E
375E
375E
0-100
0-100
0-100
0-100
0-100
100-1000
0-100
0-100
100-1000
0-100
0-100
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (}) (1)
(ppb)
15
6
*7
7
1
7
7
38
8
4
7
7
10.000
10.000
0.015
0.022
3.000
0.019
0.021
10.108
10.000
0.009
0.033
2.000
0.028
0.016
96.9
35
91.4
83
36
96.8
73
48
99.29
87
91.6
REFERENCE
NPDES
IIPDES
WEPi *
ViERL *
mi *
XERL *
NPDES
«ERL
MERL
MEKL
«ERL
mi
Data used in developing proposed standard.
4-120
-------
BenzoflOfluoranthene. Two sources of wastewater treatment
performance data were available for benzo(k)fluoranthene, including data from
the ITD and WERL databases. These data are presented in Table 4-61.
Technologies for which data are available include AS, BT, RO, and TF, and the
treatment performance data represent pilot- and full-scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BDAT for benzo(k)fluoranthene is being promulgated as proposed and
is identified as biological treatment (BT). The BDAT treatment standard was
calculated using the ITD median long-term average of 10 ppb and the ITD Option
1 variability factor. The calculation of the resulting BDAT treatment
standard for benzo(k)fluoranthene (0.059 ppm) is described in Section 6.0 and
is shown in Table 6-10.
TABLE 4-61
WASTEWATER TREATMENT PERFORMANCE DATA
FOR BENSO(k)FLDORANTHENE
DETECTION
TECHNOLOGY TECHNOLOGY FACILITY LIMIT
SIZE (ppb)
RANGE NO. OF AVERAGE
INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
CONCENTRATION POINTS CONCENTRATION (I) (?)
(ppb) (ppb)
AS
AS
AS
AS
* BT
RO
TF
TF
Ful
Fa
Fu.
Fa
Ful
Pilo
Ful
Ful
1 6B
375E
375E
375E
1293 10
t 1634E
1 375E
1 375E
100-1000
0-100
0-100
0-100
10-352
0-100
0-100
0-100
10
7
7
7
15
7
•7
10.000
0.012
0.010
0.013
10.000
0.001
0.015
0.014
94.7
89
96.6
89
94
90.6
90
«ERL
WERL
WERL
SERL
ITD-L *
XERL
"XERL
ViERL
Data used in developing proposed standard.
4-121
-------
Bis(2-chloroethoxv)methane (U024). The data available for bis(2-
chloroethoxy)methane were compiled from the NPDES and WERL databases and are
presented in Table 4-62A. In addition, leachate treatment performance data
submitted by industry just prior to proposal are presented in Table 4-62B.
Technologies for which data are available include full-scale AS, BT, and TF
studies. The resulting effluent concentrations ranged from 0.001 ppb to
20 ppb.
At proposal, BOAT for bis(2-chloroethoxy)methane was identified as
biological treatment and the treatment standard was based on an effluent
concentration of 2 ppb from activated sludge (AS). Between proposal and
promulgation, EPA evaluated the industry-submitted leachate data available for
bis(2-chloroethoxy)methane. Since this data for biological treatment (BT)
showed substantial treatment of bis(2-chloroethoxy)methane and showed average
leachate effluent values greater than that of AS, these data were used to
calculate the promulgated standard. Therefore, BOAT for bis(2-chloro-
ethoxy)methane is biological treatment.
The BOAT treatment standard for bis(2-chloroethoxy)methane was
calculated using the effluent concentration of 10 ppb and the appropriate
variability factor and accuracy correction factor. The calculation of the
resulting BOAT treatment standard for bis(2-chloroethoxy)methane (0.036 ppm)
is described in Section 6.0 and is shown in Table 6-10.
4-122
-------
TABLE 4-62A
WASTEWATER TREATMENT PERFORMANCE DATA
FOR BIS(2-CHLOROETHOXY)HETHANB
TECHNOLOGY
* AS
BT
BT
BT
BT
TF
DETECTION
TECHNOLOGY FACILITY LIHIT
SIZE (ppb)'
Ful
FU:
Fu
FU:
Fu
FU:
NYOI78152
PA0022047
LA0066214
H.0065501
1 201B
: HI0029173
HJ0004120
: LA0038245
.. PA0026247
:. IB
RANGE
INFLUENT
CONCENTRATION
(PPb)
0-100
0-100
NO. OF
DATA
POINTS
1
12
15
6
2
11
25
38
25
AVERAGE
EFFLDENT
CONCENTRATION
(PPb)
0.001
7.750
10.000
10.000
2.000
3.000
9.420
10.140
10.310
20.000
RECOVERY REMOVAL
(*) (*)
92.3
43
REFERENCE
HPDES
HPDES
KPDES
HPDES
XERL *
HPDES
KPDES
HPDES
HPDES
VERL
Data used in developing proposed standard.
TABLE 4-62B
INDUSTRY-SUBMITTED TREATMENT PERFORMANCE DATA
FOR BIS(2-CHLOROETHOXY)METHANE
TECHNOLOGY
TECHNOLOGY
SIZE
DETECTION
FACILITY LIMIT
(PPb)
RANGE
INFLDEHT
CONCENTRATION
(PPb)
NO. OF AVERAGE
DATA EFFLUENT
POINTS CONCENTRATION
(PPb)
RECOVERY REMOVAL REFERENCE
(*) W
BT
DOW
10
50-395
3
10.000
94.68 IEACHATE
4-123
-------
Bis(2-chloroethvl^ether (U025). The data available for bis(2-
chloroethyl)ether were compiled from the NPDES and WERL databases and are
presented in Table 4-63. Technologies for which data are available include
AL, AS, BT, CAC, ChOx, and TF. The treatment performance data represent
bench-, pilot-, and full-scale studies. The resulting effluent concentrations
ranged from 1 ppb to 430 ppb.
BOAT for bis(2-chloroethyl)ether is being promulgated as proposed
and is identified as activated sludge biological treatment (AS). Activated
sludge was selected as BOAT because the data represent full-scale treatment
performance with a high influent concentration and high removal efficiency.
The BOAT treatment standard for bis(2-chloroethyl)ether was calculated using
the effluent concentration of 6 ppb and the appropriate variability factor and
accuracy correction factor. The calculation of the resulting BOAT treatment
standard for bis(2-chloroethyl)ether (0.033 ppm) is described in Section 6.0
and is shown in Table 6-10.
TABLE 4-63
WASTEWATER TREATMENT PERFORHAHCE DATA
FOR BIS(2-CHLOROETHYL)ETHEJ
TECHNOLOGY
AL
AL
AS
AS
AS
AS
* AS
BT
BT
BT
BT
BT
BT
CAC
ChOx
TF
TF
DETECTION RANGE
TECHNOLOGY FACILITY LIMIT INFLDENT
SIZE (ppb) CONCENTRATION
(PPb)
LA0065501
PA0012777
HY0107174
MI0000868
LA0066214
Pilot 203A
Pilot 203A
Full IB
Pilot 240A
Full 6B
Pilot 203A
Ful
Ful
Ful
Ful
Fui:
Ful
Fui:
975B
KY0002119
LA0038245
PA0026247
PA0026689
HI0029173
HI0029173
Pilot 203A
Bench 975B
Pilot 203A
Pilot 240A
100-1000
100-1000
100-1000
0-100
1000-10000
100-1000
1000-10000
100-1000
1000-10000
100-1000
0-100
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (*) (?)
(ppb)
6
38
8
8
15
11
11
11
9
3
11
13
38
25
2
15
15
11
11
8
10.000
3.014
25.875
2.750
10.000
102.000
78.000
13.000
29.000
430.000
30.000
6.000
12.080
12.492
10.880
2.500
1.000
1.000
114.000
6.000
132.000
65.000
. 29
46
98.3
67
73
79
99.87
20
99.74
8
32
REFERENCE
NPDES
NPDES
NPDES
NPDES
tfPDES
*ERL
*ERL
>IRL
'mi
ViERL
*ERL
•mi *
NPDES
HPDES
HPDES
HPDES
HPDES
NPDES
»ERL
tfERL
«ERL
'mi
Data used in developing proposed standard.
4-124
-------
Bis(2-chloroisopropvl)ether (D027). The data available for bis(2-
chloroisopropyl)ether were compiled from Che NPDES database and are presented
in Table 4-64. The technology for which data were available was full-scale
BT. The resulting effluent concentrations ranged from 8 ppb to 103,766 ppb.
BDAT for bis(2-chloroisopropyl)ether is being promulgated as
proposed and is identified as biological treatment (BT). Biological treatment
was selected as BDAT because it represents full-scale treatment and no
additional data were available. The BDAT treatment standard for bis(2-
chloroisopropyl)ether was calculated using an effluent concentration of 10.075
ppb (which represents the average of the BT effluent values after deleting the
103,766 ppb value which was considered an outlier) and the appropriate
variability factor and accuracy correction factor. The calculation of the
resulting BDAT treatment standard for bis(2-chloroisopropyl)ether (0.055 ppm)
is described in Section 6.0 and is shown in Table 6-10.
TABLE 4-64
WASTEWATER TREATMENT PERFORMANCE DATA
FOR BIS(2-CHLOROISOPROPYL)BTHER
TECHNOLOGY
* BT
* BT
BT
TECHNOLOGY
SIZE
Full
Full
Full
DETECTION
FACILITY LIMIT
(PPb)
LA0066214
LA0065501
IL0001627
KY0003514
KY0003603
MD0000345
«V0004740
MI0000540
PA0022047
LA0038245
PA0026247
KY0002119
RANGE
INFLUENT
CONCENTRATION
(PPb)
80. OF
DATA
POINTS
15
6
9
1
1
1
1
10
11
38
24
13
AVERAGE
EFFLUENT RECOVERY
CONCENTRATION (I)
(PPb)
10.000
10.000
10.000
10.000
10.000
10.000
15.000
1144.300
8.000
10.150
10.000
103766.000
REMOVAL REFERENCE
w
NPDES
NPDES
NPDES
NPDES
tfPDES
HPDES
tIPDES
1IPDES
tIPDES
NPDES *
HPDES *
NPDES
Data used in developing proposed standard.
4-125
-------
Bis(2-ethvlhexvl)phthalate. Three sources of wastewater treatment
performance data were available for bis(2-ethylhexyl)phthalate, including data
from the ITD and WERL databases and literature WAO and PACT" data. These data
are presented in Table 4-65. Technologies for which data are available
include AL, AS, CAC, BT, PACT", RO, TF, and WOx. The treatment performance
data represent bench-, pilot-, and full-scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BDAT for bis(2-ethylhexyl)phthalate is being promulgated as proposed
and is identified as biological treatment (BT). The BDAT treatment standard
was calculated using the ITD median long-term average of 47.1 ppb and the ITD
Option 1 variability factor. The calculation of the resulting BDAT treatment
standard for bis(2-ethylhexyl)phthalate (0.28 ppm) is described in Section 6.0
and is shown in Table 6-10.
4-126
-------
TABLE 4-65
WASTEWATER TREATMENT PERFORMANCE DATA
FOR BIS(2-ETHYLHEnL)PHTHALATE
TECHHOLOGY
AL
AL
AL
AL
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
CAC
* BT
PACT
PACT
RO
TF
TF
TF
TF
TF
TF
TF
XOx
XOx
XOX [B'>
DETECTION RANGE
TECHHOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb)' CONCENTRATION
(PPb)
Pilot 203 A
Full IB
Bench 371D
Pilot 203A
Full IB
Full IB
Full IB
Pilot 241B
Pilot 203A
Full IB
Bench 202D
Full IB
Pilot 241B
Ful
Fu.
Fu
Fu
Pu
IB
IB
IB
IB
IB
Full IB
Fu
Fu
Fu
Fu
6B
IB
IB
201B
IB
Pilot 204A
Pilot 240A
Full IB
Ful
Benc
fit
Fttl
Pilo
Ful
IB
1 1050E
IB
IB
IB
: 203A
1 948 10
Bench 975B
Bench Ziipro
Full 250B
full IB
Pilot 203A
Full IB
Full IB
Full IB
Pilot 240A
Full 2inpro 2
Full Zinpro 11
Bench 1053E
100-1000
100-1000
1000-10000
100-1000
0-100
0-100
0-100
100-1000
100-1000
0-100
100-1000
0-100
1000-10000
100-1000
0-100
100-1000
0-100
0-100
0-100
1000-10000
0-100
100-1000
0-100
0-100
0-100
100-1000
100-1000
0-100
100-1000
0-100
0-100
100-1000
100-1000
11-11740
100-1000
561
0-100
0-100
100-1000
0-100
0-100
0-100
0-100
100-1000
4800
1800
100000-1000000
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION {\) (»)
11
6
11
6
4
4
5
11
6
3
4
6
6
5
5
6
4
37
4
6
3
4
8
10
6
6
5
6
6
11
33
1
5
11
5
4
6
5
6
1
1
34.000
73.000
190.000
30.000
S.OOO
13.000
5.000
7.000
18.000
10.000
60.000
10.000
390.000
90.000
11.000
31.000
9.000
20.000
67.000
47.000
11.000
40.000
5.000
16.000
11.000
46.000
48.000
51.000
35.000
10.000
6.000
190.000
15.000
43.300
3.000
2.000
8.000
60.000
39.000
5.000
22.000
26.000
33.000
43.000
10.000
0.000
100.000
80
39
90.5
32
79
47
81
93.7
89
84
66
64
59
64
72
67
73
33
97.1
76
86
93.8
70
79
73
63
39
91.2
81
86
57
91.1
99.46
99.6
90
3
77
81
24
32
56
79
99.99
REFERENCE
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
•XERL
XERL
XERL
XERL
WERL
WERL
XERL
XERL
XERL
XERL
XERL
XERL
WERL
WERL
XERL
XERL
XERL
XERL
XERL
WERL
WERL
WERL
WERL
ITD-L *
XERL
A\0
XERL
XERL
XERL
XERL
XERL '
WERL
XERL
XERL
XAO
XAO
XERL
* Data used in developing proposed standard.
4-127
-------
4-Brpmophenvl phenvl ether (U030). The data available for
4-bromophenyl phenyl ether were compiled from the NPDES database and are
presented in Table 4-66. The technology for which data were available was
full-scale BT. The effluent concentrations of the data documented ranged from
10.0 ppb to 10.05 ppb.
BDAT for 4-bromophenyl phenyl ether is being promulgated as proposed
and is identified as biological treatment (BT). Biological treatment was
selected as BDAT because it represents full-scale treatment and no additional
data were available. The BDAT treatment standard for 4-bromophenyl phenyl
ether was calculated using the effluent concentration of 10.05 ppb and the
appropriate variability factor and accuracy correction factor. The
calculation of the resulting BDAT treatment standard for 4-bromophenyl phenyl
ether (0.055 ppm) is described in Section 6.0 and is shown in Table 6-10.
TABLE 4-66
WASTEWATER TREATMENT PERFORMANCE DATA
FOR 4-BROMOPHENYL PHENYL ETHER
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (I) (\)
_ (ppb) _ (ppb)
LA0066214 15 10.000 NPDES
LA0065501 6 10.000 HPDES
* BT ' Full LA0038245 38 10.050 NPDES *
Data used in developing proposed standard.
4-128
-------
Butvl Benzyl Fhthalate. The data available for butyl benzyl
phthalate were compiled from the NPDES and WERL databases and literature PACTR
data. These data are presented in Table 4-67. Technologies for which data
are available include AS, BT, and PACT" and the treatment performance data
represent bench-, pilot-, and full-scale studies. The resulting effluent
concentrations ranged from 1.3 ppb to 136.5 ppb.
BDAT for butyl benzyl phthalate is being promulgated as proposed and
is identified as activated sludge biological treatment (AS). Activated sludge
was selected as BDAT because it represents full-scale data with a high
influent concentration and high removal efficiency. The BDAT treatment
standard for butyl benzyl phthalate was calculated using the effluent
concentration of 3 ppb and the appropriate variability factor and accuracy
correction factor. The calculation of the resulting BDAT treatment standard
for butyl benzyl phthalate (0.017 ppm) is described in Section 6.0 and is
shown in Table 6-10.
2-Sec-Butvl-4.6-Dinitrophenol (P020). The data available for 2-sec-
butyl-4,6-dinitrophenol were compiled from the WERL database and EPA WAO test
data. These data are presented in Table 4-68. Technologies for which data
are available include WOx and WOx+PACTR. The treatment performance data
represent pilot- and full-scale data.
The proposed BDAT standard was set using WOx technology and an
achievable effluent of 190 ppb. The promulgated BDAT standard was set using
WOx+PACTR treatment and an achievable effluent of 8.7 ppb. WOx+PACTR was
selected as BDAT because the data represented by these technologies was
generated by EPA as part of the BDAT program. Additionally these data show a
high removal efficiency and a low effluent value.
The calculation of the resulting BDAT treatment standard for 2-sec-
butyl-4,6-dinitrophenol (0.066 ppm) is described in Section 6.0 and is shown
in Table 6-10.
4-129
-------
TABLE 4-67
WASTEWATER TREATMENT PERFORMANCE DATA
FOK BUTYL BENZYL PHTHALATE
TECHHOLOGY
AS
AS
AS
* AS
AS
AS
AS
BT
BT
PACT
DETECTION RANGE
TECHHOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb)- CONCENTRATION
(PPb)
Pilot
Full
Full
Full
Pilot
Pilot
Full
Full
Full
Bench
LA0065501
NY0199648
NY0032140
NY0032140
PA0022047
NY0183628
LA0066214
204A
IB
IB
IB
241B
241B
IB
PA0026247
LA0038245
Zinpro
0-100
0-100
0-100
100-1000
0-100
100-1000
0-100
129
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (1) (!)
(PPb)
6
11
2
2
10
4
15
8
3
3
6
5
11
6
25
38
1
10.000
10.730
136.500
58.000
7.000
17.500
5.000
1.300
5.000
2.000
3.000
9.000
12.000
2.000
13.795
10.066
2.000
96.2
91.8
93.3
98.3
32
97
96.7
98.4
REFERENCE
KPDES
MPDES
NPDES
HPDES
NPDES
NPDES
HPDES
>TRL
*ERL
>m
XIPl *
'XERL
XERL
KERL
MPDES
NPDES
W.O
Data used in developing proposed standard.
TABLE 4-68
WASTEWATER TREATMENT PERFORMANCE DATA
FOR 2-SEC-BDTYL-4,6-DINITROPHENOL
DETECTION
TECHHOLOGY TECHHOLOGY FACILITY LIMIT
SIZE (ppb)
RANGE
IHFLDEHT
CONCENTRATION
(ppb)
NO. OF AVERAGE
DATA EFFLOEHT
POINTS CONCENTRATION
(ppb)
RECOVERY REMOVAL REFERENCE
(t) (t)
* »0x
WOx
Full
Pilot
78D
Zinpro
PAC Pilot Zinpro 3.3
* Data used in developing proposed standard.
10000-100000
O40-400
190.000
8.700
99.5
97.8
XERL
WAO
4-130
-------
p-Chloroanlline (P024). The data available for p-chloroaniline were
compiled from EPA's WAO treatment test and are presented in Table 4-69. These
data represent pilot-scale WOx and WOx+PACTR. WOx and PACT" were considered
demonstrated technologies for p-chloroaniline since the Agency believes these
technologies exist as full-scale units treating organic constituents similar
to p-chloroaniline. The resulting effluent concentration was 120 ppb.
The proposed BOAT standard was set using the WOx performance data
and an achievable effluent of 11,000 ppb (the lowest detection limit from the
WOx test). Since PACTR data became available just prior to proposal, the
treatment train WOx+PACT* was not considered until after proposal. The
promulgated BOAT standard was set using the treatment train WOx+PACTH and an
achievable effluent of 120 ppb (the detection limit from the PACTH test).
WOx+PACTR was selected as BOAT because data from this treatment train show a
high influent concentration, high removal efficiency, and represent data
generated by EPA as part of the BOAT program.
The calculation of the resulting BOAT treatment standard for
p-chloroaniline (0.46 ppm) is described in Section 6.0 and is shown in
Table 6-10.
TABLE 4-69
WASTEWATEJ TREATMENT PESFORHASCE DATA
FOB p-CHLOROANILINE
DETECTION
TECHNOLOGY TECHNOLOGY FACILITY LIKIT
SIZE (ppb)
RANGE NO. OF AVERAGE
INFLCEHT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
CONCENTRATION POINTS CONCENTRATION (?) (?)
(ppb) (ppb)
*
wox
>Wx
WOx
WOX
+ PACT
PI
PI,
Pi
pa
ot
ot
ot
ot
Zjnpro
zfr
ZlBj
ZlB
MTO
pro
jro
11000
12000
25000
120
46000-59000
46000-59000
46000-59000
46000-59000
1
1
1
3
ND
ND
ND
120.
000
*AO *
XAO
*AO
99.8 ViAO
Data used in developing proposed standard.
4-131
-------
ChlorobenzHate (U038). No wastewater treatment performance data
were available for chlorobenzilate from any of the examined sources.
Treatment performance data were therefore transferred to this constituent from
a constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
Chlorobenzilate is in treatability group III.A.2.c.(3)(d) and the constituent
used to transfer treatment performance data from was methoxychlor. The
treatment performance data for methoxychlor are presented in Table 4-152.
Using a transfer from this constituent results in a BDAT for chlorobenzilate
of wet air oxidation and a BDAT treatment standard of 0.10 ppm as described in
Section 6.0 and shown in Table 6-10.
4-132
-------
p-Chloro-m-cresol (U039). The data available for p-chloro-m-cresol
were compiled from the NPDES and WERL databases and are presented in
Table 4-70. Technologies for which data are available include full-scale AS
and BT. The resulting effluent concentrations ranged from 0.9 ppb to
11.568 ppb.
BOAT for p-chloro-m-cresol is being promulgated as proposed and is
identified as activated sludge biological treatment (AS). Activated sludge
was selected as BOAT since it represents full-scale treatment with a high
removal efficiency and a low effluent concentration value. The BOAT treatment
standard for p-chloro-m-cresol was calculated using the effluent concentration
of 4 ppb and the appropriate variability factor and accuracy correction
factor. The calculation of the resulting BDAT treatment standard for p-
chloro-m-cresol (0.018 ppm) is described in Section 6.0 and is shown in
Table 6-10.
2-Chloronaphthalene (U047). The data available for 2-chloronaph-
thalene were compiled from the NPDES database and are presented in Table 4-71.
The technology for which data were available was full-scale BT. The effluent
concentrations of all the data documented ranged from 10.0 ppb to 10.05 ppb.
BDAT for 2-chloronaphthalene is being promulgated as proposed and is
identified as biological treatment (BT). Biological treatment was selected as
BDAT because of it represents full-scale treatment and no additional data were
available. The BDAT treatment standard for 2-chloronaphthalene was calculated
using the effluent concentration of 10.05 ppb and the appropriate variability
factor and accuracy correction factor. The calculation of the resulting BDAT
treatment standard for 2-chloronaphthalene (0.055 ppm) is described in Section
6.0 and is shown in Table 6-10.
4-133
-------
TABLE 4-70
WASTEHATER TREATMENT PERFORMANCE DATA
FOR p-CHLORO-a-CRESOL
DETECTION RANGE NO.. OP AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LINIT INFLDENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb)- CONCENTRATION POINTS CONCENTRATION (*) (t)
(ppb) (ppb)
WI0029971
LA0065501
WI0029971
NY0002470
WI0029971
LA0066214
* AS Pull IB
BT Full LA0038245
1.25-7.7 2
6
1.25-7.7 2
3
2
15
0-100 1
37
7.700
10.000
1.250
10.000
0.900
10.000
4.000
11.568
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
87 HERL *
NPDES
Data used in developing proposed standard.
TABLE 4-71
WASTEHATER TREATMENT PERFORMANCE DATA
FOR 2-CHLORONAPHTHALENE
TECHNOLOGY
DETECTION
TECHNOLOGY FACILITY LIMJT
SIZE
RANGE
INFLDENT
CONCENTRATION
(ppb)
NO. OP
DATA
POINTS
AVERAGE
EFFLUENT RECOVERY REMOVAL REFERENCE
CONCENTJATIOH (I) (?)
(ppb)
* BT
Pull
LA0066214
LA0065501
LA0038245
15
6
38
10.000
10.000
10.050
NPDES
NPDES
NPDES *
Data used in developing proposed standard.
4-134
-------
2-ChlorophenoI (U048). The data available for 2-chlorophenol were
compiled from the WERL database and literature PACTR and WAO data. These data
are presented in Table 4-72. Technologies for which data are available
include AL, AS, PACT", rotating biological contactors (RBC), SCOx, and WOx.
The treatment performance data represent bench-, pilot-, and full-scale
studies. The resulting effluent concentrations ranged from 0.05 ppb to
39,000 ppb.
BOAT for 2-chlorophenol is being promulgated as proposed and is
identified as activated sludge biological treatment (BT). Activated sludge
was selected as BOAT because it represents full-scale treatment with high
influent concentrations and a high removal efficiency. The BDAT treatment
standard for 2-chlorophenol was calculated using the effluent concentration of
10 ppb and the appropriate variability factor and accuracy correction factor.
The calculation of the resulting BDAT treatment standard for 2-chlorophenol
(0.044 ppm) is described in Section 6.0 and is shown in Table 6-10.
TABLE 4-72
WASTEWATER TREATMENT PERFORMANCE DATA
FOR 2-CHLOROPHENOL
TECHHOLOGY
AL
AL
* AS
AS
AS
AS
PACT
PACT
RBC
SCOx
«0x
«0x [Bl
VOX. B
TECHHOLOGY
SIZE
Pilot
Pilot
Ml
Pilot
Full
Pilot
Bench
Full
Pilot
Pilot
Bench
Bench
Bench
DETECTION
FACILITY • LIMIT
(PPb)
192D
192D
6B
192D
6B
192D
Zinpro
6B
192D
6.5D
Zinpro
236A
1101D
RANGE
IKFLDEHT
CONCENTRATION
(ppb)
100-1000
1000-10000
10000-100000
100-1000
100-1000
1000-10000
31.9
10000-100000
100-1000
HOOOOOO
12410000
>1000000
>1000000
NO. OF
DATA
POINTS
2
3
1
10
1
1
AVERAGE
EFFLDENT
CONCENTRATION
(ppb)
10.000
10.000
10.000
10.000
10.000
10.000
0.050
93.000
10.000
36.000
15000.000
17000.000
39000.000
RECOVERY REMOVAL
<*) m
95
99.0?
99.93
95
97.2
99.07
99.84
99.78
95
99.99
99.88
99.86
99.22
REFERENCE
>m
•mi
>:ERL *
;>ERL
>;ERL
'mi
*AO
wm
>iERL
WERL
«AO
*ERL
*ERL
Data used in developing proposed standard.
4-135
-------
Chrvsene (U050), Two sources of wastewater treatment performance
data were available for chrysene, including data from the ITD and WERL
databases. These data are presented in Table 4-73. Technologies for which
data are available include AS, AS+Fil, and BT. The treatment performance data
represent pilot- and full-scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BOAT for chrysene is being promulgated as proposed and is identified
as biological treatment (BT). The BDAT treatment standard was calculated
using the ITD median long-term average of 10 ppb and the ITD Option 1
variability factor. The calculation of the resulting BDAT treatment standard
for chrysene (0.059 ppm) is described in Section 6.0 and is shown in Table
6-10.
TABLE 4-73
WASTEWATER TREATMENT PERFORMANCE DATA
FOR CHRYSENE
TECHNOLOGY
AS
AS
AS
AS-F.il
Fil
* BT
TECHNOLOGY
SIZE
Pilot
Full
Full
Full
Full
Full
FACILITY
204A
6B
6B
6B
792E
1293
DETECTION
LIMIT
(Ppb)
10
RANGE
INFLCEHT
CONCENTRATION
(ppb)
0-100
100-1000
100-1000
1000-10000
100-1000
10-677
NO. OF
DATA
POINTS
8
4
11
3
4
15
AVERAGE
EFFLUENT RECOVERY
CONCENTRATION (*)
(ppb)
1.200
10.000
10.000
10.000
1.000
10.000
REMOVAL
w
96.9
99
96.8
99.09
99.76
REFERENCE
SERL
XERL
*m
VERL
*ERL
ITD-L *
Data used in developing proposed standard.
4-136
-------
ortho-Cresol (U052). The data available for ortho-cresol were
compiled from the WERL database and the BOAT Solvents Rule data. These data
are presented in Table 4-74. Technologies for which data are available
include anaerobic fixed film (Anff) separately and in conjunction with GAG
(AnFFwGAC), BT, and RO. The treatment performance data represent bench-,
pilot-, and full-scale studies and the resulting effluent concentrations
ranged from 14 ppb to 26,000 ppb.
BOAT for ortho-cresol is being promulgated as proposed and is
identified as biological treatment (BT). Biological treatment was selected as
BOAT because it represents full-scale data developed from ITD sampling and was
used as part of the BDAT Solvents Rule. The BOAT treatment standard for
ortho-cresol was calculated using the effluent concentration of 25 ppb and the
appropriate variability factor and accuracy correction factor. The
calculation of the resulting BDAT treatment standard for ortho-cresol (0.11
ppm) is described in Section 6.0 and is shown in Table 6-10.
TABLE 4-74
WASTEWATER TREATMENT PERFORMANCE DATA
FOR ortho-CRESOL
TECHNOLOGY
AnFF
AnFF
AnFFvGAC
* BT
SO
TECHNOLOGY
SIZE
Bench
P}lot
Pilot
Full
Pull
FACILITY
230A
235D
249D
REPS
250B
DETECTION
LIMIT
(PPb)
RANGE
INFLDENT
CONCENTRATION
(PPb)
100000-1000000
10000-100000
100000-1000000
1886-2536
100-1000
NO. OP
DATA
POINTS
2
AVERAGE
EFFLUENT RECOVERY
CONCENTRATION (I)
(ppb)
26000.000
7800.000
8800.000
25.000
14.000
REMOVAL
W
78
85
98.7
98.5
REFERENCE
VIERL
WERL
vOL
BDAT 1 *
WERL
I ITD data presented in the BDAT Solvents Rule F001-F005 Background Document.
* Data used in developing proposed standard.
4-137
-------
meta/para-Cresol (U052). The data available for meta/para-cresol
were compiled from the WERL database and are presented.in Table 4-75.
Technologies for which data are available include gravity oil water separation
followed by dissolved air flotation separation followed by AS (API+DAF+AS),
AS, AnFF, RO, and SExt. The treatment performance data represent bench-,
pilot-, and full-scale studies. The resulting effluent concentrations ranged
from 72 ppb to 17,000 ppb.
BOAT for meta/para-cresol is being promulgated as proposed and is
identified as activated sludge biological treatment (AS). Activated sludge
was selected as BOAT because it represents a demonstrated technology with a
high removal efficiency and was the BOAT chosen for ortho isomers of cresol.
The BOAT treatment standard for meta/para-cresol was calculated using the
effluent concentration of 174 ppb and the appropriate variability factor and
accuracy correction factor. The calculation of the resulting BOAT treatment
standard for meta/para-cresol (0.77 ppm) is described in Section 6.0 and is
shown in Table 6-10.
TABLE 4-75
HASTEWATEB TREATMENT PERFORHANCE DATA
FOB Seta/para-CRESOL
TECHNOLOGY
API+DAF+AS
* AS
AnFF
RO
SExt
TECHNOLOGY
SIZE
Bench
FACILITY
1482D
241B
230A
250B
1082E
DETECTION
LIHIT
(PPb)
RANGE
INFLUENT
CONCENTRATION
(PPb)
1000-10000
100-1000
100000-1000000
1000-10000
100000-1000000
NO. OF
DATA
POINTS
4
9
AVERAGE
EFFLUENT RECOVERY
CONCENTRATION (1)
(PPb)
160.000
174.000
17000.000
72.000
3000.000
REMOVAL
(*)
87
68
90.7
97.7
99.66
REFERENCE
WERL
WERL *
WERL
WERL
WERL
Data used in developing proposed standard.
4-138
-------
Cyclohexanone (U057). No wastewater treatment performance data were
available for cyclohexanone from any of the examined sources. Treatment
performance data were therefore transferred to this constituent from a
constituent judged.to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
Cyclohexanone is in treatability group III.A.3.e and the constituent used to
transfer treatment performance data from was methyl ethyl ketone. The
treatment performance data for methyl ethyl ketone are presented in
Tables 4-32A and 4-32B. Using a transfer from this constituent results in a
BOAT for cyclohexanone of biological treatment and a BOAT treatment standard
of 0.36 ppm as described in Section 6.0 and shown in Table 6-10.
4-139
-------
Dibenz(a.h)anthracene (U063). The data available for
dibenz(a,h)anthracene were compiled from the NPDES and WERL databases and are
presented in Table 4-76. The technologies for which data are available
include pilot-scale CAC and full-scale BT. The resulting effluent
concentration ranged from 10 ppb to 10.066 ppb.
BOAT for dibenz(a,h)anthracene is being promulgated as proposed and
is identified as chemically assisted coagulation (CAC). CAC was selected as
BDAT because it represents a demonstrated technology with high influent
concentrations and a high removal efficiency. The BDAT treatment standard for
dibenz(a,h)anthracene was calculated using the effluent concentration of 10
ppb and the appropriate variability factor and accuracy correction factor.
The calculation of the resulting BDAT treatment standard for dibenz(a.h)-
anthracene (0.055 ppm) is described in Section 6.0 and is shown in Table 6-10.
TABLE 4-76
WASTEWATEB TREATMENT PERFORMANCE DATA
FOR DIBENZ(a;h)ANTHBACENE
DETECTION RANGE NO. OP AVERAGE
TECHNOLOGY TECHHOLOGY FACILITY LIMIT INFLDEHT DATA EFFLOEHT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (I) ('<)
__' _________ (ppb) ____________________ (ppb) ________ ___ _______ _ ______________
LA0066214 15 10.000 HPDES
LA0065501 6 10.000 NPDES
BT Full LA0038245 • 38 10.066 HPDES
* CAC Pilot 195B 1W~1 8 0'00 '8 * *
Data used in developing proposed standard.
4-140
-------
Dibenzo(a.e')pvrene. No wastewater treatment performance data were
available for dibenzo(a,e)pyrene from any of the examined sources. Treatment
performance data were therefore transferred to this constituent from a
constituent judged.to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
Dibenzo(a,e)pyrene is similar in structure to constituents in treatability
group III.A.3.c and the constituent used to transfer treatment performance
data from was benzo(a)pyrene. The treatment performance data for
benzo(a)pyrene are presented in Table 5-58. Using a transfer from this
constituent results in a BOAT for dibenzo(a,e)pyrene of biological treatment
and a BOAT treatment standard of 0.061 ppm as described in Section 6.0 and
shown in Table 6-10.
4-141
-------
m-Dichlorobenzene (U071). The data available for m-dichlorobenzene
were compiled from the WERL database and are presented in Table 4-77A. In
addition, leachate treatment performance data submitted by industry just prior
to proposal are presented in Table 4-77B. Technologies for which data are
available include aerobic fixed film (AFF), AS, AirS, BGAC, GAG, PACTR, RO,
and BT. The treatment performance data represent bench-, pilot-, and full-
scale studies. The resulting effluent concentrations ranged from 0.160 ppb to
3,300 ppb.
At proposal, BOAT for m-dichlorobenzene was identified as biological
treatment and the treatment standard was based on an effluent concentration of
3.6 ppb from activated sludge (AS). Between proposal and promulgation, EPA
evaluated the Industry-submitted leachate data available for m-dichloro-
benzene. Since this data for biological treatment (BT) showed substantial
treatment of m-dichlorobenzene and showed average leachate effluent values
greater than that of activated sludge, these data were used to calculate the
promulgated standard. Therefore, BOAT for m-dichlorobenzene is biological
treatment.
The BDAT treatment standard for m-dichlorobenzene was calculated
using the effluent concentration of 10 ppb and the appropriate variability
factor and accuracy correction factor. The calculation of the resulting BDAT
treatment standard for m-dichlorobenzene (0.036 ppm) is described in Section
6.0 and is shown in Table 6-10.
4-142
-------
TABLE 4-77A
HASTEWATER TREATMENT PERFORMANCE DATA
FOR l-DICHLOROBENZENE
TECHNOLOGY
AFF
AS
* AS
AS
AS
AS
AS
AirS
BGAC
GAC
PACT
PACT
. RO
RO
TECHNOLOGY
SIZE
"R9
Full
Pilot
Pull
Full
Bench
Bench
Bench
Full
Bench
Pilot
Pilot
FACILITY
501A
1587E
975B
241B
IB
975B
202D
1328E
501A
1421D
975B
6B
323B
' 180A
DETECTION RANGE
LIMIT INFLUENT
(ppb)- CONCENTRATION
(PPb)
0-100
0-100
100-1000
100-1000
100-1000
0-100
10000-100000
10000-100000
0-100
0-100
0-100
100-1000
0-100
0-100
NO. OF
DATA
POINTS
34
11
2
5
34
10
1
AVERAGE
EFFLUENT RECOVERY
CONCENTRATION (t)
(PPb)
7.100
0.270
3.600
41.000
5.000
1.200
340.000
3300.000
0.500
0.290
2.000
25.000
9.000
0.160
REMOVAL
'(*)
_
99.14
89
98
93.3
99.51
89
94.9
80
83
96.9
66
69
REFERENCE
""WERL
WERL
WERL *
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
Data used in developing proposed standard.
TABLE 4-77B
INDUSTRY-SUBMITTED TREATMENT PERFORMANCE
DATA FOR n-DICHLOROBENZENE
TECHNOLOGY
TECHNOLOGY
SIZE
FACILITY
DETECTION
LIMIT
RANGE
INFLUENT
CONCENTRATION
(PPD)
NO. OF
DATA
POINTS
AVERAGE
EFFLUENT
CONCENTRATION
(PPb)
RECOVERY
(*)
REMOVAL
(*)
REFERENCE
BT
DON
10
46-205
10.000
91.24 LEACHATE
4-143
-------
o-Dichlorobenzene (U070). The data available for o-dichlorobenzene
were compiled from the WERL database, BOAT Solvents Rule data, and literature
WAO data. These data are presented in Table 4-78. Technologies for which
data are available include AFF, AL, AS, AirS, BGAC, BT, GAG, PACT", RBC, RO,
and WOx. The treatment performance data represent bench-, pilot-, and full-
scale studies. The resulting effluent concentrations ranged from 0.09 ppb to
2,017,000 ppb.
BOAT for o-dichlorobenzene is being promulgated as proposed and is
identified as biological treatment (BT). Biological treatment was selected as
BOAT because it represents full-scale data developed from ITD sampling and was
used as part of the BOAT Solvents Rule. The effluent concentration achievable
by this technology is supported by similar effluent concentrations from the
WERL activated sludge treatment performance data. The BOAT treatment standard
for o-dichlorobenzene was calculated using the effluent concentration of 16
ppb and the appropriate variability factor and accuracy correction factor.
The calculation of the resulting BOAT treatment standard for o-dichlorobenzene
(0.088 ppm) is described in Section 6.0 and is shown in Table 6-10.
4-144
-------
TABLE 4-78
WASTEWATER TREATMENT PERFORMANCE DATA
FOR 0-DICHLOROBENZENE
TECHNOLOGY
AFP
AL
AL
AL
AS
AS
AS
AS
AS
AS
AS
AS
AS
. AS
AS
AS
AS
AS
AS
AS
AS
AirS
BGAC
BT
* BT
BT
BT+AC
GAC
GAC
PACT
PACT
PACT
PACT
RBC
RO
RO
WOx
WOX
WOK
DETECTION
TECHNOLOGY FACILITY LIMIT
SIZE (ppb)
Bench 501A
P}lot 192D
Pilot 192D
Bench 371D
Full IB
full 6B
Pilot 192D
Pilot 192D
Ful
Ful
Ful
Ful
Benc
Ful
Ful
6B
IB
IB
66
l 200B
IB
1587E
Bench 202D
Pilot 241B
Bench 1050E
Full 375E
Full 6B
Bench 1054E
B^nch 1328E
Pilot 222B
Bench 501A
Ful
FU
FU
FU
Fu
Ful
Benc
Bend
Ful
P246
P202
P206
P246
245B
1421D
1 242E
1 200B
6B
6B
P}lot 192D
P;lot 323B
Pilot 180A
Bench Zinpro
Bench Zinpro
Pilot 786
RANGE
INFLUENT
CONCENTRATION
(PPb)
0-100
100-1000
1000-10000
1000-10000
100-1000
1000-10000
1000-10000
100-1000
100-1000
100-1000
0-100
1000-10000
100-1000
100-1000
0-100
10000-100000
100-1000
100-1000
0-100
100-1000
100-1000
10000-100000
0-100
0-100
768-2801
1350-4387
233-2333
768-3275
100-1000
0-100
0-100
100-1000
1000-10000
100-1000
100-1000
0-100
0-100
590000
6530000
>1000000
HO. OF
DATA
POINTS
25
4
3
330
2
3
4
14
5
10
5
7
3
5
34
14
4
10
17
1
14
10
4
1
1
1
AVERAGE
EFFLUENT RECOVERY
CONCENTRATION (»)
(PPb)
0.380
10.000
100.000
72.000
6.000
52.000
110.000
270.000
35.000
5.000
2.000
16.000
8.000
10.000
1.200
50.000
25.000
1.600
5.000
10.000
8.000
6200.000
0.500
0.310
596.000
16.000
88.000
176.000
10.000
0.270
5.000
2.900
88.000
64.000
10.000
11.000
0.090
150000.000
2017000.000
29000.000
REMOVAL
0)
96
97.7
94.8
97.6
96
98.5
94.3
37
96.2
96.2
94.3
99.33
92.7
91.7
79
99.94
93.2
99.6
67
92.9
98.4
74
83
96.8
98.9
90
83
97.5
98.5
90
97.7
70
92.5
74.6
69.1
98.7
REFERENCE
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
HERL
WERL
BDAT
BDA *
BDAT
BDAT i
WERL
WER,
WER,
WERL
WERL
WERL
WERL
WERL
WERL
WAO
WAO
WERL
I ITD data presented in the BDAT Solvents Rule F001-F005 Background DocuBent.
* Data used in developing proposed standard.
4-145
-------
p-Dichlorobenzene (U072). The data available for p-dichlorobenzene
were compiled from the WERL database and literature UAO data. These data are
presented in Table 4-79. Technologies for which data are available include
AFF, AL, AS, AirS, BGAC, CAC, ChOx, GAG, PACT", RBC, RO, and TF. The
treatment performance data represent bench-, pilot, and full-scale studies.
The resulting effluent concentrations ranged from 0.004 ppb to 3,600 ppb.
BOAT for p-dichlorobenzene is being promulgated as proposed and is
identified as activated sludge biological treatment (AS). Activated sludge
was selected as BOAT because it represents full-scale data with high influent
concentrations and high removal efficiencies. The BOAT treatment standard for
p-dichlorobenzene was calculated using an effluent concentration of 16.33 ppb
(which represents an average of the data presented for the activated sludge
technology in the high influent concentration ranges) and the appropriate
variability factor and accuracy correction factor. The calculation of the
resulting BDAT treatment standard for p-dichlorobenzene (0.090 ppm) is
described in Section 6.0 and is shown in Table 6-10.
4-146
-------
TABLE 4-79
WASTEWATER TREATMENT PERFORMANCE DATA
FOR p-DICHLOROBENZENE
TECHNOLOGY
AFT
AL
AL
AL
AL
AS
AS
AS
* AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
* AS
AS
* AS
AirS
BGAC
CAC
ChOx
GAC
GAC
PACT
PACT
PACT
RBC
RO
TF
TF
—
DETECTION RANGE
TECHNOLOGY FACILITY "LIMIT" INFLOENT
SIZE
(ppb) CONCENTRATION
(PPb)
Bench 501A 0-100
NO. OF
DATA
POINTS
27
Pilot 192D 0-100
Pjlot 203A 0-100
Pilot 203A 0-100
11
11
Pilot 192D 100-1000
Pull IB 0-100
Pull 234A 0-100
Pilot 241B 100-1000
2
4
full 975B 1000-10000
PUot 192D 100-1000
Pilot 631D 0-100
Pilot 631D 0-100
Pilot 240A 100-1000
12
Pilot 192D 0-100
full 234A 0-100
Pilot 241B 100-1000
ffl
ful
Pilo
Fu
Pul
M
Pul
Benc
Benc
201B 0-100
IB 0-100
IB
0-100
: 203A 0-100
11
2
1
11
234A 0-100
6B
100-1000
4
975B 0-100
975B 100-1000
J 1328E 10000-100000
1 501A 0-100
Pilot 203A 0-100
Bench 9751
Full 245
Pul
Benc
Benc
Bend
PJlo
I 1H
1 9.751
i Zimi
t 1921
3 0-100
1 100-1000
> 0-100
1 0-100
8 0-100
ro 36.6
3 0-100
Pilot 180A 0-100
Pilot 240A 100-1000
Pilot 203A 0-100
5
34
11
1
1
11
11
AVERAGE
EFFLUENT • RECOVERY
CONCENTRATION (\)
(PPb)
0.200
10.000
31.000
12.000
10.000
10.000
0.500
10.000
12.000
10.000
0.004
0.004
8.000
10.000
0.500
19.000
6.000
5.000
8.000
5.000
0.500
10.000
4.900
27.000
3600.000
0.270
66.000
5.000
10.000
0.200
5.000
5.000
0.015
10.000
0.670
16.000
58.000
REMOVAL
(*)
98.1
88
67
87
90.5
76
81
90.7
99.63
90.5
99
99
93.8
88
90
95.1
79
93.1
83
94.6
91.7
97
92.8
96.6
90
97.5
29
91.1
96
9?25
92.3
99.96
88
61
88
38
REFERENCE
MERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
HERL *
WERL
WERL
WERL
WERL
WERL
HERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL *
WERL
WERL *
WERL
WERL
WERL
WERL
WERL
HERL
WERL
WERL
WAO
WERL
WERL
WERL
WERL
Data used in developing proposed standard.
4-147
-------
2.4-Dichlorophenol (U081). The data available for 2,4-dichloro-
phenol were compiled from the WERL database, literature WAO data, and EPA WAO
test data. These data are presented in Table 4-81. Technologies for which
data are available include AL, AS, CAC, GAG, PACT", TF, WOx and WOx+PACTR.
The treatment performance data represent bench-, pilot-, and full-scale
studies. The resulting effluent concentrations ranged from 0.2 ppb to
3,600 ppb.
BOAT for 2,4-dichlorophenol is being promulgated as proposed and is
identified as activated sludge biological treatment (AS). Activated sludge
was selected as BDAT because it represents full-scale data with a high
influent concentration and the lowest achievable effluent concentration. The
BDAT treatment standard for 2,4-dichlorophenol was calculated using the
effluent concentration of 10 ppb and the appropriate variability factor and
accuracy correction factor. The calculation of the resulting BDAT treatment
standard for 2,4-dichlorophenol (0.044 ppm) is described in Section 6.0 and is
shown in Table 6-10.
TABLE 4-81
WASTEWATER TREATMENT PERFORMANCE DATA
FOR 2,4-DICHLOROPHENOL
TECHNOLOGY !
AL
AL
AS
AS
AS
AS
AS
AS
AS
AS
* AS
AS
AS
CAC
GAC
PACT
PACT
PACT
TF
TF
ViOx
SOx
>»X » PACT
PECHNOLOGY
SIZE
Pilot
Pilot
Full
' Ml
Full
Full
Pilot
Bench
Pilot
Full
Full
Bench
Pilot
Pilot
Full
Bench
Pilot
Pilot
Pilot
Bench
Bench
Pilot
DETECTION
FACILITY LIMIT
203A
203A
201B
253B
253B
975B
203A
1050E
240A
IB
6B
202D
848D
203A
237A
975B
6B
848D
203A
240A
Zinpro
Zinpro
Zinpro 33
1 RANGE
INFLDENT
CONCENTRATION
(ppb)
100-1000
100-1000
0-100
0-100
0-100
0-100
100-1000
100-1000
100-1000
100-1000
100-1000
10000-100000
10000-100000
100-1000
0-100
1000-10000
10000-100000
10000-100000
100-1000
0-100
23500
500000
160000-180000
NO. OF
DATA
POINTS (
11
11
2
1
1
11
5
11
4
2
8
11
1
10
8
11
9
1
1
3
AVERAGE
EFFLUENT RECO\
BNCENTRATION (1)
(ppb)
155.000
65.000
12.000
0.200
2.100
3.000
1.000
0.800
12.000
300.000
10.000
3600.000
340.000
92.000
5.000
3.000
18.000
10.000
200.000
36.000
380.000
2000.000
36.330
/ERY REMOVAL
i W
32
71
54
98
19
83
99.56
99.8
89
52
98.7
95.2
99.57
60
50
99.88
99.9
99.99
12
64
98.4
99.6
REFERENCE
WERL
>;ERL
*:ERL
*ERL
VERL
*ERL
>:ERL
"XERL
>m
*ERL *
WERL
•XERL
tfERL
•XERL
'XERL
WERL
WERL
'XERL
SiERL
/SAO
*AO
*'AO
Data used in developing proposed standard.
4-148
-------
2.6-Dichlorophenol (U082). No wastewater treatment performance data
were available for 2,6-dichlorophenol from any of the examined sources.
Treatment performance data were therefore transferred to this constituent from
a constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
2,6-dichlorophenol is in treatability group III.A.2.d and the constituent used
to transfer treatment performance data from was 2,4-dichlorophenol. The
treatment performance data for 2,4-dichlorophenol are presented in Table 4-81.
Using a transfer from this constituent results in a BOAT for 2,4-dichloro-
phenol of activated sludge biological treatment and a BOAT treatment standard
of 0.044 ppm as described in Section 6.0 and shown in Table 6-10.
4-149
-------
Diethvl phthalate. Three sources of wastewater treatment
performance data were available for diethyl phthalate, including data from the
ITD and WERL databases and literature FACTn data. These data are presented in
Table 4-82. Technologies for which data are available include AS, BT, and
PACT". The treatment performance data represent bench-, pilot-, and full-
scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BDAT for diethyl phthalate is being promulgated as proposed and is
identified as biological treatment (BT). The BDAT treatment standard was
calculated using the ITD median long-term average of 42.5 ppb and the ITD
Option 1 variability factor. The calculation of the resulting BDAT treatment
standard for diethyl phthalate (0.20 ppm) is described in Section 6.0 and is
shown in Table 6-10.
TABLE 4-82
WASTEWATER TREATMENT PERFORMANCE DATA
FOR DIETHYL PHTHALATE
TECHNOLOGY
AS
AS
AS
AS
AS
* BT
PACT
TECHNOLOGY
SIZE
Pilot
Full
Pilot
Full
Full
Pull
Bench
FACILITY
204A
6B
241B
IB
IB
948
Zinpro
DETECTION
LIMIT
(Ppb)
10
RANGE
INFLCENT
CONCENTRATION
(ppb)
0-100
1000-10000
100-1000
0-100
0-100
14-15000
88
NO. OF
DATA
POINTS
8
36
11
4
3
33
AVERAGE
EFFLUENT RECOVERY
CONCENTRATION (1)
(PPb)
1.200
28.000
12.000
1.000
3.000
23.500
1.000
REMOVAL
(*)
97.4
97.7
97.6
96.7
38
98.9
REFERENCE
"XERL
*ERL
AERL
AERL
ITD-L *
WAO
Data used in developing proposed standard.
4-150
-------
2.4-DimethYlphenol (U101). Several sources of wastewater treatment
performance data were available for 2,4-dimethylphenol, including data from
the ITD and WERL databases, literature WAO data, and EPA WAO test data. These
data are presented in Table 4-83. Technologies for which data are available
include AL, AS, AS+Fil, AnFF, anaerobic fixed film with granular activated
carbon (AnFFwGAC) , BT, RBC, RO, TF, WOx, and WOx+PACT*. The treatment
performance data represent bench-, pilot-, and full-scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BOAT for 2,4-dimethylphenol is being promulgated as proposed and is
identified as biological treatment (BT). The BDAT treatment standard was
calculated using the ITD median long-term average of 10.794 ppb and the ITD
Option 1 variability factor. The calculation of the resulting BDAT treatment
standard for 2,4-dimethyl phenol (0.036 ppm) is described in Section 6.0 and
is shown in Table 6-10.
4-151
-------
TABLE 4-83
WASTEWATER TREATMENT PERFORHAHCE DATA
FOR 2,4-DIHETHYLPHENOL
TECHNOLOGY TECHHOLOGY
SIZE
AL
AS
AS
AS
AS
AS+Pil
AnFF
AnFFvGAC
* BT
RBC
RO
TF
«OX
'*0x + PACT
»OX [B]
Pilot
Full
Pilot
Full
Pilot
full
Pilot
Pilot
Full
Pilot
Full
Full
Bench
Pilot
Bench
DETECTION RANGE
FACILITY LIMIT INFLUENT
(ppb) CONCENTRATION
(ppb)
192D
6B
192D
6B
204A
6B
235D
249D
1293 10
192D
250B
IB
Znpro
Ziupro 33
23BA
1000-10000
100-1000
1000-10000
10000-100000
0-100
1000-10000
. 1000-10000
10000-100000 •
16216-73537
1000-10000
100-1000
0-100
8220000
530000-790000
> 1000000
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (*) (i)
(ppb)
7
14
8
3
.15
2
1
3
1
10.000
13.000
10.000
10.000
0.900
10.000
0.400
0.050
10.000
10.000
16.000
25.000
100.000
75.330
820.000
99.81
98.1
99.81
99.97
99.06
99,9
0090
99 .'93
99.31
98.4
38
99.99
99.99
REFERENCE
•ERL
XERL
#m
>:ERL
MERL
ViERL
AlRL
•mi
ITD-L *
>:ERL
*ERL
AERL
«AO
SAO
XERL
* Data used in developing proposed standard.
4-152
-------
Dimethyl phthalate. Several sources of wastewater treatment
performance data were available for dimethyl phthalate, including data from
the ITD and WERL databases and literature PACT" and WAO data. These data are
presented in Table 4-84. Technologies for which data are available include
AS, BT, PACT", and WOx. The treatment performance data represent bench-,
pilot-, and full-scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BDAT for dimethyl phthalate is being promulgated as proposed and is
identified as biological treatment (BT). The BDAT treatment standard was
calculated using the ITD median long-term average of 10 ppb and the ITD Option
1 variability factor. The calculation of the resulting BDAT treatment
standard for dimethyl phthalate (0.047 ppm) is described in Section 6.0 and is
shown in Table 6-10.
TABLE 4-84
WASTEWATER TREATMENT PERFORMANCE DATA
FOR DIMETHYL PHTHALATE
TECHNOLOGY
AS
AS
AS
AS
X
* BT
PACT
WX
TECHNOLOGY
SIZE
Full
Full
Pilot
Pilot
Full
Full
Bench
Full
FACILITY
IB
6B
241B
204A
IB
9.48
Zinpro
Zinpro
DETECTION
LIMIT
(PPb)
10
1
RANGE
INFLUENT
CONCENTRATION
(PPb)
100-1000
100-1000
100-1000
0-100
0-100
10-625
332
61000
HO. OF
DATA
POINTS
16
10
8
1
22
1
1
AVERAGE
EFFLDENT RECOVERY
CONCENTRATION (1)
(ppb)
2.000
20.000
13.000
0.800
30.000
10.000 .
1.000
0.000
REMOVAL
m
98.2
92.8
QT 7
98 .'3
12
99.7
REFERENCE
XERL
ViERL
*ERL
>m
>;ERL
ITD-L *
«AO
A'AO
Data used in developing proposed standard.
4-153
-------
Dl-n-butvl phthalate. Two sources of wastewater treatment
performance data were available for di-n-butyl phthalate, including data from
the ITD and WERL databases, these data are presented in Table 4-85.
Technologies for which data are available include AL, AS, CAC, ChOx, BT, and
TF. The treatment performance data represent bench-, pilot-, and full-scale
studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCFSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BDAT for di-n-butyl phthalate is being promulgated as proposed and
is identified as biological treatment (BT). The BDAT treatment standard was
calculated using the ITD median long-term average of 17.606 ppb and the ITD
Option 1 variability factor. The calculation of the resulting BDAT treatment
standard for di-n-butyl phthalate (0.057 ppm) is described in Section 6.0 and
is shown in Table 6-10.
4-154
-------
TABLE 4-85
viASTEWATER TREATMENT PERFORMANCE DATA
FOR DI-n-BUTYL PHTHALATB
DETECTION
TECHNOLOGY TECHNOLOGY FACILITY LIMIT
SIZE (ppb)-
AL Bench 371D
AL Pilot 203A
AL Pilot 203A
AS Pilot 240A
AS Fu
AS Fu.
AS Fu
AS Fu
AS Fu
!.S Fu
IB
975B
IB
201B
IB
IB
AS Pilot 204A
AS Pilot 203A
AS Full 6B
AS Pilot 241B
AS Bench 1050E
AS Full 6B
CAC Pilot 203A
ChOx Bench 975B
* BT Full 948 10
TF Ful
TF Ful
1 IB
1 IB
TF PUot 203A
TF Pilot 240A
RANGE
INFLUENT
CONCENTRATION
(ppb)
100-1000
0-100
0-100
0-100
0-100
0-100
.0-100
0-100
0-100
0-100
0-100
0-100
100-1000
100-1000
100-1000
1000-10000
0-100
0-100
19-2000
0-100
0-100
0-100
0-100
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (1) (1)
(PPb)
11
11
12
6
4
2
5
3
8
11
31
11
5
6
11
33
5
3
11
11
5
14
44
8
4
3
5
3
5
10
2
7
13
17
2
30
47
3
13
6
20
52
16
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.700
.000
.000
.000
.400
.000
.000
.000
.000
.000
.000
.000
.000
99.5
81
40
91.4
91.7
37
94.4
93.5
93.8
87
93.9
90.4
96.8
96
99.4
98.7
36
87
92.6
70
29
81
REFERENCE
XERL
'mi
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
VIERL
XERL
XERL
ITD-L *
XERL
XERL
XERL
WERL
Data used in developing proposed standard.
4-155
-------
1.4-Dinitrobenzene. No wastewater treatment performance data were
available for 1,4-dinitrobenzene from any of the examined sources. Treatment
performance data were therefore transferred to this constituent from a
constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
1,4-Dinitrobenzene is similar in structure to constituents in treatability
group III.3.f.(5) and the constituent used to transfer treatment performance
data from was 2,4-dinitrotoluene. The treatment performance data for
2,4-dinitrotoluene are presented in Table 4-88. Using a transfer from this
constituent results in a BOAT for 1,4-dinitrobenzene of PACT" and a BDAT
treatment standard of 0.32 ppm as described in Section 6.0 and shown in Table
6-10.
4-156
-------
4.6-Dtnitro-o-cresol (P047). Three sources of wastewater treatment
performance data were available for 4,6-dinitro-o-cresol, including data from
the ITD and WERL databases and EPA VAO test data. These data are presented in
Table 4-86. Technologies for which data are available include activated
carbon (AC), AS, PACT", and WOx+PACTR. The treatment performance data
represent pilot- and full-scale data.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BDAT for 4,6-dinitro-o-cresol is being promulgated as proposed and
is identified as activated carbon (AC). The BDAT treatment standard was
calculated using the ITD median long-term average of 24 ppb and the ITD
Option 1 variability factor. The calculation of the resulting BDAT treatment
standard for 4,6-dinitro-o-cresol (0.28 ppm) is described in Section 6.0 and
is shown in Table 6-10.
Wastes which are believed to contain 4,6-dinitro-o-cresol salts
and/or esters are required to meet the BDAT standards identified in the Final
BDAT Background Document for Uastewater and Nonwastewater Forms of Organic U
and P Wastes for Which a Method of Treatment Standard Has Been Set, Volume B
(Reference 19).
4-157
-------
TABLE 4-86
WASTEWTER TREATMENT PERFORMANCE DATA
FOB 4,6-DINITRO-o-CRESOL
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLDEHT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (!) (*)
(ppb) jppbj
* AC Full 2680T 24 7622-11400 9 24.000 ITD-L *
AS Pilot 848D 10000-100000 8 20000.000 23 viERL
PACT Pilot 848D 10000-100000 8 16000.000 39 »ERL
PACT Pilot 8.48D 10000-100000 8 3000.000 89 *EJL
Wx i PACT Pilot Zinpro 290 <140000 3 293.330 XAO
* Data used in developinq proposed standard.
4-158
-------
2.4-Dtnitrophenol (P048). Several sources of wastewater treatment
performance data were available for 2,4-dinitrophenol, including data from the
ITD, BOAT, and WERL databases as well as additional literature data. These
data are presented in Table 4-87. Technologies for which data are available
include AC, AS, ChOx, Chred, LL, LL+SS, LL+SS+AC, and PACT". The treatment
performance data represent bench- and full-scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone .
both EPA and industry review and acceptance.
BDAT for 2,4-dinitrophenol is being promulgated as proposed and is
identified as activated carbon (AC). The BDAT treatment standard was
calculated using the ITD median long-term average of SO ppb and the ITD Option
1 variability factor. The calculation of the resulting BDAT treatment
standard for 2,4-dinitrophenol (0.12 ppm) is described in Section 6.0 and is
shown in Table 6-10.
4-159
-------
TABLE 4-8?
WASTEWATER TREATMENT PERFORMANCE DATA
FOR 2,4-DIMITROPHENOL
TECHNOLOGY
* AC
AS
AS
AS
AS
AS
AS
ChOx
ChOx
Chred
LL
LL
LLtSS
LL+SS+AC
PACT
DETECTION RANGE NO. OF
TECHNOLOGY FACILITY LIMIT INFLUENT DATA
SIZE (ppb) CONCENTRATION POINTS
(ppb)
Ful
Full
Ful
.Ful
Benc
Ful
Ful
I 2680T
6B
6B
6B
1 202D
975B
I 975B
50
Bench 975B
Bench 975B
Bench
Full K104
Pull K103
Full K103/K104
Full K103/K104
150
150
150
150
Bench 975B
20000-58155
1000-10000
1000-10000
1000-10000
10000-100000
1000-10000
1000-10000
1000-10000
100-1000
85-94
750000-1500000
7500000-15000000
750000-15000000
750000-15000000
1000-10000
9
2
3
4
4
5
5
5
4
AVERAGE
EFFLUENT RECOVERY REMOVAL
CONCENTRATION (\) (1)
(ppb)
373
50
50
100
660
4300
430
42
42
4
325000
420000
42000
297
42
.000
.000
.000
.000
.000
.000
.000
.000
.000
.400
.000
.000
.000
.000
.000
97.
95.
97.
99.
19
84
98.
88
98.
4
4
6
31
•}
3
REFERENCE
ITD-L *
«ERL
SEBL
mi
SEW,
AERL
*ERL
>m
AEPL
ART
BOAT
BOAT
BOAT
BOAT
»ERL
Data used in developing proposed standard.
4-160
-------
2.4-Dinitrotoluene (U105). The data available for 2,4-dinitro-
toluene were compiled from the WERL database and literature WAO data. These
data are presented in Table 4-88. Technologies for which data are available
include AS, PACT8, and WOx and the treatment performance data represent bench-
and full-scale studies. The resulting effluent concentrations ranged from
58 ppb to 26000 ppb.
BOAT for 2,4-dinitrotoluene is being promulgated as proposed and is
identified as PACTR. PACT" was selected as BDAT because it represents full-
scale data with a high influent concentration and the lowest effluent
concentration. The BDAT treatment standard for 2,4-dinitrotoluene was
calculated using the effluent concentration of 58 ppb and the appropriate
variability factor and accuracy correction factor. The calculation of the
resulting BDAT treatment standard for 2,4-dinitrotoluene (0.32 ppm) is
described in Section 6.0 and is shown in Table 6-10.
TABLE 4-88
WASTEWATER TREATMENT PERFORMANCE DATA
FOR 2,4-DINITROTOLUENE
TECHNOLOGY
AS
* PACT
XOx
/fox ;B;
TECHNOLOGY
SIZE
Full
Full
Bench
Bench
DETECTION RANGE
FACILITY LIMIT INFLUENT
(ppb) CONCENTRATION
(ppb)
6B
6B
Zinpro
236A
10000-100000
1000-10000
10000000
>1000000
NO. OF
DATA
POINTS
3
4
1
1
AVERAGE
EFFLUENT RECOVERY REMOVAL
CONCENTRATION (*) (1)
(ppb)
110.000
58.000
26000.000
12000.000
99.15
96.4
9Q 74
99.83
REFERENCE
AERL
>:ERL *
VAO
AERL
* Data used in developing proposed standard.
4-161
-------
2.6-Dinitrotoluene (U106). The data available for 2,6-dinitro-
toluene were compiled from the WERL database and are presented in Table 4-89.
Technologies for which data are available include AL, AS, and PACT". The
treatment performance data represent bench-, pilot-, and full-scale studies.
The resulting effluent concentrations ranged from 18 ppb to 260 ppb.
BOAT for 2,6-dinitrotoluene is being promulgated as proposed and is
identified as PACTH. PACTR was selected as BOAT because it represents full-
scale data with a high influent concentration and the lowest average effluent
concentration of those data which show substantial treatment. The BOAT
treatment standard for 2,6-dinitrotoluene was calculated using the effluent
concentration of 100 ppb and the appropriate variability factor and accuracy
correction factor. The calculation of the resulting BOAT treatment standard
for 2,6-dinitrotoluene (0.55 ppm) is described in Section 6.0 and is shown in
Table 6-10.
TABLE 4-89
WASTEWATER TREATMENT PERFORMANCE DATA
FOR 2,6-DINITROTOLUENE
TECHNOLOGY
AL
AS
AS
AS
* PACT
TECHNOLOGY
SIZE
Bench
Full
Pilot
Full
Full
FACILITY
371D
6B
241B
IB
6B
DETECTION
LIMIT
(ppb)
RANGE
INFLDENT
CONCENTRATION
(PPb)
100-1000
1000-10000
100-1000
0-100
100-1000
NO. OF
DATA
POINTS
3
10
2
3
AVERAGE
EFFLUENT
CONCENTRATION
(PPb)
27.000
260.000
124.000
13.000
100.000
RECOVERY REMOVAL
(*) (*)
97.3
92.4
70
18
70
REFERENCE
AERL
*ERL
AERL
AERL
XERL *
Data used in developing proposed standard.
4-162
-------
Di-n-octvl phthalate. The data available for di-n-octyl phthalate
were compiled from Che NPDES and WERL databases and are presented in
Table 4-90. Technologies for which data are available include AL, AS, BT,
ChOx, and PACT". The treatment performance data represent bench-, pilot-, and
full-scale studies. The resulting effluent concentrations ranged from 3 ppb
to 47,000 ppb.
BOAT for di-n-octyl phthalate is being promulgated as proposed and
is identified as activated sludge biological treatment (AS). Activated sludge
was selected as BOAT because it represents full-scale treatment with a high
influent concentration and a high removal efficiency. The BOAT treatment
standard for di-n-octyl phthalate was calculated using the effluent
concentration of 3 ppb and the appropriate variability factor and accuracy
correction factor. The calculation of the resulting BOAT treatment standard
for di-n-octyl phthalate (0.017 ppm) is described in Section 6.0 and is shown
in Table 6-10.
TABLE 4-90
WASTEWATER TREATMENT PERFORMANCE DATA
FOR DI-n-OCTYL PHTHALATE
TECHNOLOGY
AL
AS
AS
* AS
BT
ChOx
PACT
TECHNOLOGY
SIZE
Bench
Full
Pilot
Full
Full
Bench
Bench
DETECTION
FACILITY LIMIT
(PPb)
KA0005304
LA0065501
LA0066214
MS0001970
OH0002445
VI0044636
NY0004138
OH0002445
371D
IB
204A
IB
LA0038245
975B
975B
RANGE
INFLUENT
CONCENTRATION
(PPb)
1000-10000
0-100
0-100
100-1000
1000-10000
1000-10000
NO. OF
DATA
POINTS
21
6
15
1
6
1
5
1
2
8
1
38
AVERAGE
EFFLUENT RECOVERY
CONCENTRATION (1)
(PPb)
9.810
10.000
10.000
110.000
5.717
47000.000
48.000
4.000
48.000
12.000
4.800
3.000
9.961
360.000
3.000
REMOVAL
W
97.6
79
83
98.6
80
99.75
REFERENCE
HPDES
IIPDES
NPDES
IIPDES
IIPDES
HPDES
HPDES
IIPDES
*ERL
>'ERL
*ERL
*ERL *
HPDES
rxm
XERL
Data used in developing proposed standard.
4-163
-------
Di-n-propvlnitrosamine (Ulll). No wastewater treatment performance
data were available for di-n-propylnitrosamine from any of the examined
sources. Treatment performance data were therefore transferred to this
constituent from a constituent judged to be similar in elemental composition
and functional groups within the structure of the chemical. For constituents
represented by a U or P code, this means that constituents included in the
same waste treatability group (see Appendix B) were candidates for transfer of
data. Di-n-propylnitrosamine is in treatability group III.A.3.f.(6) and the
constituent used to transfer treatment performance data from was N-nitroso-
dimethylamine. The treatment performance data for N-nitroso-dimethylamine are
presented in Table 4-105. Using a transfer from this constituent results in a
BOAT for di-n-propylnitrosamine of activated sludge biological treatment and a
BDAT treatment standard of 0.40 ppm as described in Section 6.0 and shown in
Table 6-10.
Diphenvlamine. No wastewater treatment performance data were
available for diphenylamine from any of the examined sources. Treatment
performance data were therefore transferred to this constituent from a
constituent judged to be.similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
Diphenylamine is similar in structure to constituents in treatability group
III.A.3.f.(2) and the constituent used to transfer treatment performance data
from was 2-naphthylamine. The treatment performance data for 2-naphthylamine
are presented in Table 4-101. Using a transfer from this constituent results
in a BDAT for diphenylamine of activated sludge biological treatment and a
BDAT treatment standard of 0.52 ppm as described in Section 6.0 and shown in
Table 6-10.
4-164
-------
Diphenvlnitrosamine. No wastewater treatment performance data were
available for diphenylnitrosamine from any of the examined-sources. Treatment
performance data were therefore transferred to this constituent from a
constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
Diphenylnitrosamine is similar in structure to constituents in treatability
group III.A.3.f.(6) and the constituent used to transfer treatment performance
data from was N-nitrosodimethylamine. The treatment performance data for
N-nitrosodimethylamine are presented in Table 4-105. Using a transfer from
this constituent results in a BOAT for diphenylnitrosamine of activated sludge
biological treatment and a BOAT treatment standard of 0.40 ppm as described in
Section 6.0 and shown in Table 6-10.
4-165
-------
1.2-Dit>henvlhvdrazine. The data available for 1,2-diphenylhydrazine
were compiled from the WERL and NFDES databases and are presented in
Table 4-91. Technologies for which data are available include AS, BT, and
WOx. The treatment performance data represent bench- and full-scale studies.
The resulting effluent concentrations ranged from 7.0 ppb to 1,000 ppb.
BDAT for 1,2-diphenylhydrazine is being promulgated as proposed and
is identified as biological treatment (BT). Biological treatment was
selected as BDAT since it represents full-scale data and demonstrates
substantial treatment. The BDAT treatment standard for 1,2-diphenylhdrazine
was calculated using an average effluent concentration of 15.811 ppb (which
represents the average of the full-scale data from the biological treatment
technologies) and the appropriate variability factor and accuracy correction
factor. The calculation of the resulting BDAT treatment standard for 1,2-
diphenylhydrazine (0.087 ppm) is described in Section 6.0 and is shown in
Table 6-10.
TABLE 4-91
WASTEWATER TREATMENT PERFORMANCE DATA
FOR 1,2-DIPHENYLHYDRAZINE
TECHNOLOGY
* AS
* BT
viOx [B]
DETECTION RANGE HO. OF AVERAGE
TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION ('<) (1)
(ppb) (ppb)
PA0022047
LA0065501
SC00009I4
PA0026379
LA0066214
TX0052591
Full IB
Full LA0038245
Bench 236A
12
6
12
3
15
11
0-100 1
37
> 1000000 1
7.000
10.000
10.000
10.000
10.000
17.300
10.000
. 21.622
1000.000
NPDES
NPDES
NPDES
HPDES
HPDES
HPDES
62 *ERL *
NPDES *
99.98 X'ERL
Data used in developing proposed standard.
4-166
-------
Fluoranthene (U120). Two sources of wastewater treatment
performance data were available for fluoranthene, including data from the ITD
and WERL databases. These data are presented in Table 4-92. Technologies for
which data are available include AL, AS, AS+Fil, CAC, ChOx, BT, PACT", RO, and
TF. The treatment performance data represent bench-, pilot-, and full-scale
studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BDAT for fluoranthene is being promulgated as proposed and is
identified as biological treatment (BT). The BDAT treatment standard was
calculated using the ITD median long-term average of 11.533 ppb and the ITD
Option 1 variability factor. The calculation of the resulting BDAT treatment
standard for fluoranthene (0.068 ppm) is described in Section 6.0 and is shown
in Table 6-10.
4-167
-------
TABLE 4-92
WASTEWATER TREATMENT PERFORMANCE DATA
FOR FLDORANTHENE
TECHNOLOGY
AL
AL
AS
AS
AS
AS
AS
AS
AS
AS
ASrFil
CAC
CAC
ChOx(Cl)
FJ1
Fll
Fll
* BT
PACT
RO
TF
TF
TF
TF
TF
TECHNOLOGY
SIZE
Pilot
Pilot
Full
full
Pilot
Full
Full
Pilot
Full
Pilot
Full
Pilot
Pilot
Pilot
Full
Full
Full
B^nch
Pilot
Pilot
Full
Full
Full
Pilot
DETECTION
FACILITY LIMIT
(PPb)'
203A
203A
375E
375E
204A
375E
6B
240A
375E
203A
6B
195B
203A
1081D
195B
577E
1081D
792E
1293 10
975B
1634E
203A
375E
375E
IB
240A
RANGE
INFLUENT
CONCENTRATION
(ppb)
100-1000
100-1000
0-100
0-100
0-100
0-100
1000-10000
0-100
0-100
100-1000
1000-10000
1000-10000
100-1000
0-100
100-1000
0-100
0-100
1000-10000
988-2141
0-100
0-100
100-1000
0-100
0-100
0-100
0-100
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (t) (4)
(PPb)
11
11
7
7
8
7
14
12
7
11
3
8
11
8
4
15
11
7
7
4
11
36.000
23.000
0.041
0.048
1.900
0.038
12.000
8.000
0.029
5.000
16.000
170.000
13.000
0.045
110.000
0.001
0.081
8.000
11.500
3.000
0.007
49.000
0.029
0.044
12.000
14.000
65
78
98.1
93.3
93.9
94.1
99.25
91.8
96.8
95.2
99.69
93.7
88
44
35
99.92
42
99.56
77
88
53
97.1
96.3
69
85
REFERENCE
XERL
XERL
WERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XERL
XEPL
ITD-L *
XERL
XERL
XERL
«ERL
XERL
WERL
XERL
Data used in developing proposed standard.
4-168
-------
Fluorene. Two sources of wastewater treatment performance data were
available for fluorene, including data from the ITD and WERL databases. These
data are presented in Table 4-93. Technologies for which data are available
include AL, AS, BT; and TF and the treatment performance data represent pilot-
and full-scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BOAT for fluorene is being promulgated as proposed and is identified
as biological treatment (BT). The BDAT treatment standard was calculated
using the ITD median long-term average of 10 ppb and the ITD Option 1
variability factor. The calculation of the resulting BDAT treatment standard
for fluorene (0.059 ppm) is described in Section 6.0 and is shown in Table 6-
10.
TABLE 4-93
WASTEWATER TREATMENT PERFORMANCE DATA
FOR FLUOPEHE
TECHNOLOGY
AL
AS
AS
* BT
TF
TECHNOLOGY
SIZE
Full
Full
Pilot
FACILITY
6B
6B
204A
1293
IB
DETECTION
LIMIT
(PPD)
10
RANGE
INFLUENT
CONCENTRATION
(PPb)
100-1000
1000-10000
0-100
678-1873
0-100
NO. OF
DATA
POINTS
3
13
8
15
4
AVERAGE
EFFLUENT RECOVERY
CONCENTRATION (1)
(Ppb)
10.000
10.000
0.700
10.000
20.000
REMOVAL
(»)
94.1
99.17
98.2
54
REFERENCE
«ERL
•mi
>;ERL
ITD-L *
WERL
* Data used in developing proposed standard.
4-169
-------
Hexachlorobenzene (U127). The data available for hexachlorobenzene
were compiled from the WERL database and are presented in Table 4-94.
Technologies for which data are available include AS, AS+Fil, and GAG and the
data are all from treatment at full-scale facilities. The resulting effluent
concentrations ranged from 0.01 ppb to 20 ppb.
BOAT for hexachlorobenzene is being promulgated as proposed and is
identified as activated sludge followed by filtration (AS+Fil). AS+Fil was
selected as BOAT since it represents full-scale data with a high influent
concentration and a high removal efficiency. The BOAT treatment standard for
hexachlorobenzene was calculated using the effluent concentration of 10 ppb
and the appropriate variability factor and accuracy correction factor. The
calculation of the resulting BOAT treatment standard for hexachlorobenzene
(0.055 ppm) is described in Section 6.0 and is shown in Table 6-10.
Hexachlorobutadiene (U128). The data available for hexachloro-
butadiene were compiled from the WERL database and are presented in
Table 4-95. Technologies for which data are available include AS, AS+Fil, and
GAG in both full- and pilot-scale studies. The resulting effluent
concentrations ranged from 10 ppb to 20 ppb.
BOAT for hexachlorobutadiene is being promulgated as proposed and is
identified as activated sludge followed by filtration (AS+Fil). AS+Fil was
selected as BOAT since it represents full-scale data with a high influent
concentration and a high removal efficiency. The BOAT treatment standard for
hexachlorobutadiene was calculated using the effluent concentration of 10 ppb
and the appropriate variability factor and accuracy correction factor. The
calculation of the resulting BDAT treatment standard for hexachlorobutadiene
(0.055 ppm) is described in Section 6.0 and is shown in Table 6-10.
4-170
-------
TABLE 4-94
WASTEWATER TREATMENT PERFORMANCE DATA
FOR HEXACHLOROBENZENE
TECHNOLOGY
AS
AS
* AS+Pil
GAC
TECHNOLOGY
SIZE
Full
Full
Full
Full
• DETECTION RANGE
FACILITY LIHIT INFLUENT
(pi*)- CONCENTRATION
(PPb)
375E
375E
6B
237A
0-100
0-100
100-1000
0-100
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (1) (!)
(PPb)
7
7
14
1
0.010
0.010
10.000
20.000
83
94.4
96.7
38
REFERENCE
«ERL
HIM,
WERL *
*ERL
Data used in developing proposed standard.
TABLE 4-95
WASTEWATER TREATMENT PERFORMANCE DATA
FOR HEXACHLOROBOTADIEHE
DETECTION
TECHNOLOGY TECHNOLOGY FACILITY LIHIT
SIZE (ppb)
RANGE
INFLUENT
CONCENTRATION
NO. OF AVERAGE
DATA EFFLUENT
POINTS CONCENTRATION
(ppb)
RECOVERY REMOVAL REFERENCE
(!) It)
AS
AS+FU
AS+Fll
GAC
Pilot
Full
241B
6B
6B
237A
100-1000
100-1000
1000-10000
100-1000
11
2
14
1
15.000
10.000
10.000
20.000
96.2
92.8
99.6
82
*ERL
SEHL *
«ERL *
WERL
Data used in developing proposed standard.
4-171
-------
Hexachlorocvclopentadiene (U130). The data available for
hexachlorocyclopentadiene were compiled from the NPDES database and literature
WAO data. These data are presented in Table 4-96. The treatment technologies
for which data are available include full-scale BT and bench-scale WOx. The
effluent concentrations of all the data documented ranged from 0.2 ppb to
15,000 ppb.
BDAT for hexachlorocyclopentadiene is being promulgated as proposed
and is identified as biological treatment (BT). Biological treatment was
selected as BDAT since it represents full-scale treatment performance. The
BDAT treatment standard for hexachlorocyclopentadiene was calculated using the
effluent concentration of 10.263 ppb and the appropriate variability factor
and accuracy correction factor. The calculation of the resulting BDAT
treatment standard for hexachlorocyclopentadiene (0.057 ppm) is described in
Section 6.0 and is shown in Table 6-10.
TABLE 4-96
WASTEWATER TREATMENT PERFORMANCE DATA
FOR HEXACHLOROCYCLOPENTADIENE
TECHNOLOGY TECHNOLOGY
SIZE
* BT Full
Wx Bench
DETECTION
FACILITY LIMIT
LA0065501
NI0025739
LA0066214
NY0107174
LA0038245
Zinpro
RANGE
INFLCENT
CONCENTRATION
(ppb)
> 10000000
NO. OF
DATA
POINTS
6
15
24
38
1
AVERAGE
EFFLDENT RECOVERY
CONCENTRATION (I)
(ppb)
10.000
0.200
10.000
1.000
10.263
15000.000
REMOVAL
(*)
99.9
REFERENCE
NPDES
NPDES
NPDES
NPDES
tfPDES *
Data used in developing proposed standard.
4-171A
-------
Hexachloroethane (U131). The data available for hexachloroethane
were compiled from the WERL database and are presented in Table 4-97.
Technologies for which data are available include AS and AS+Fil. Data are
available from pilot and full-scale studies. The resulting effluent
concentration for both studies was 10 ppb.
BOAT for hexachloroethane is being promulgated as proposed and is
identified as activated sludge followed by filtration (AS+Fil). AS+Fil was
selected as BOAT since it represents full-scale treatment performance with a
high removal efficiency. The BOAT treatment standard for hexachloroethane was
calculated using the effluent concentration of 10 ppb and the appropriate
variability factor and accuracy correction factor. The calculation of the
resulting BOAT treatment standard for hexachloroethane (0.055 ppm) is
described in Section 6.0 and is shown in Table 6-10.
TABLE 4-97
WASTEWATER TREATMENT PERFORMANCE DATA
FOR HEXACHLOROETHANE
DETECTION RANGE NO. OF AVERAGE
TECHHOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (t) (})
(PPb) (PP '
AS Pilot 241B 100-1000 11 10.000 97.1
* ASrPil Full 6B 100-1000 14 10.000 93.8 ViERL *
* Data used in developing proposed standard.
4-172
-------
Hexachloropropene (U243). No wastewater treatment performance data
were available for hexachloropropene from any of the examined sources.
Treatment performance data were therefore transferred to this constituent from
a constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
Hexachloropropene is in treatability group III.A.2.b.(3) and the constituent
used to transfer treatment performance data from was cis-1,3-dichloropropene.
The treatment performance data for cis-1,3-dichloropropene are presented in
Table 4-24. Using a transfer from this constituent results in a BDAT for
hexachloropropene of activated sludge biological treatment and a BDAT
treatment standard of 0.035 ppm as described in Section 6.0 and shown in
Table 6-10.
4-173
-------
Indenof1.2.3-cdlovrene (U137). The data available for indeno(l,2,3-
cd)pyrerie were compiled from the NPDES and WERL databases and are presented in
Table 4-98. Technologies for which data are available include AS, BT,
chlorination, and TF. All of the treatment performance data represent full-
scale studies. The resulting effluent concentrations ranged from 0.009 ppb to
28 ppb. The detection limit for indeno(l,2,3-cd)pyrene is 1 ppb (see Table
C-l, Appendix C).
BDAT for indeno(l,2,3-cd)pyrene is being promulgated as proposed and
is identified as activated sludge biological treatment (AS). Activated sludge
was selected as BDAT since it represents full-scale treatment performance with
a high removal efficiency. The BDAT treatment standard for indeno(l,2,3-
cd)pyrene was calculated using an effluent concentration of 1 ppb (which
represents the detection limit for indeno(l,2,3-cd)pyrene) and the appropriate
variability factor and accuracy correction factor. The calculation of the
resulting BDAT treatment standard for indeno(l,3,3-cd)pyrene (0.0055 ppm) is
described in Section 6.0 and is shown in Table 6-10.
TABLE 4-98
WASTEWATER TREATMENT PERFORMANCE DATA
FOR INDENOfl^S-cdjPYRENE
TECHNOLOGY
* AS
* AS
* AS
* AS
BT
ChOx(Cl)
Fll
TF
TF
DETECTION
TECHNOLOGY FACILITY LIMIT
SIZE (ppb)
LA0065501
LA0066214
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
1 375E
375E
375E
375E
LA0038245
1081D
1081D
1 375E
Full 375E
RANGE
INFLUENT
CONCENTRATION
(ppb)
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
NO. OF
DATA
POINTS
6
15
7
7
7
7
38
7
7
AVERAGE
EFFLOEHT RECOVERY REMOVAL
CONCENTRATION (*)
(ppb)
10.000
28.000
0.013
0.011
0.017
0.015
10.097
0.009
0.027
0.012
0.019
m
92.8
97
84
86
67
59
92.5
89
REFERENCE
NPDES
NPDES
*ERL *
AERL *
*ERL *
«ERL *
NPDES
HEM,
AERL
Data used in developing proposed standard.
4-174
-------
Isosafrole (U141). No wastewater treatment performance data were
available for isosafrole from any of the examined sources. Treatment
performance data were therefore transferred to this constituent from a
constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
Isosafrole is in treatability group III.A.3.h and the constituent used to
transfer treatment performance data from was phenacetin. The treatment
performance data for phenacetin are presented in Table 4-107. Using a
transfer from this constituent results in a BOAT for isosafrole of wet air
oxidation followed by PACT" and a BOAT treatment standard of 0.081 ppm as
described in Section 6.0 and shown in Table 6-10.
Methapvrilene (U155). No wastewater treatment performance data were
available for methapyrilene from any of the examined sources. Treatment
performance data were therefore transferred to this constituent from a
constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
Methapyrilene is in treatability group III.A.3.h and the constituent used to
transfer treatment performance data from was phenacetin. The treatment
performance data for phenacetin are presented in Table 4-107. Using a
transfer from this constituent results in a BOAT for methapyrilene of wet air
oxidation followed by PACT8 and a BOAT treatment standard of 0.081 ppm as
described in Section 6.0 and shown in Table 6-10.
4-175
-------
3-Methvlcholanthrene (U157). No wastewater treatment performance
data were available for 3-methylcholanthrene from any of the examined sources.
Treatment performance data were therefore transferred to this constituent from
a constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
3-Methylcholanthrene is in treatability group III.A.3.c and the constituent
used to transfer treatment performance data from was indeno(l,2,3-cd)pyrene.
The treatment performance data for indeno(l,2,3-cd)pyrene are presented in
Table 4-98. Using a transfer from this constituent results in a BOAT for
3-Methylcholanthrene of activated sludge biological treatment and a BOAT
treatment standard of 0.0055 ppm as described in Section 6.0 and shown in
Table 6-10.
4-176
-------
4.4^-Methvlenebis(2-chloroaniline) (U158). The data available for
4,4'-methylenebis(2-chloroaniline) were compiled from the WERL database and
are presented in Table 4-99. The technology for. which data were available was
a bench-scale AS study with a resulting effluent concentration of 90 ppb.
BDAT for 4,4'-Methylenebis(2-chloraniline) is being promulgated as
proposed and is identified as activated sludge biological treatment (AS).
Activated sludge was selected as BDAT since it represents data from a
technology which the Agency believes to be demonstrated in full-scale units
for organic constituents similar to 4,4'-Methylenebis(2-chloraniline) and
shows a high removal efficiency. The BOAT treatment standard for 4,4'-
Methylenebis(2-chloraniline) was calculated using the effluent concentration
of 90 ppb and the appropriate variability factor and accuracy correction
factor. The calculation of the resulting BDAT treatment standard for 4,4'-
Methylenebis(2-chloraniline) (0.50 ppm) is described in Section 6.0 and is
shown in Table 6-10.
TABLE 4-99
WASTEWATER TREATMENT PERFORMANCE DATA
FOR 4,4'-HETHYLEHEBIS (2-CHLOROANILINE)
. DETECTION RANGE HO. OF AVERAGE
TECHHOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (*) (*)
(ppb) (ppb)
* AS ' Bench 315B 1000-10000 4 90.000 95.7 v.'EPl *
* Data used in developing proposed standard.
4-177
-------
Methyl methanesulfonate. No wastewater treatment performance data
were available for methyl methanesulfonate from any of the examined sources.
Treatment performance data were therefore transferred to this constituent from
a constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
Methyl methanesulfonate is similar in structure to constituents in
treatability group III.A.3.g and the constituent used to transfer treatment
performance data from was carbon disulfide. The treatment performance data
for carbon disulfide are presented in Tables 4-10A and 4-10B. Using a
transfer from this constituent results in a BOAT for methyl methanesulfonate
of biological treatment and a BOAT treatment standard of 0.018 ppm as
described in Section 6.0 and shown in Table 6-10.
4-178
-------
Naphthalene (U165). Three sources of wastewater treatment
performance data were available for naphthalene, including data from the ITD
and WERL databases as well as literature WAO data. These data are presented
in Table 4-100. Technologies for which data are available include AL, AS,
AirS, CAC, ChOx, BT, PACT", RBC, RO, TF, and WOx. The treatment performance
data represent bench-, pilot-, and full-scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BDAT for naphthalene is being promulgated as proposed and is
identified as biological treatment (BT). The BDAT treatment standard was
calculated using the ITD median long-term average of 10 ppb and the ITD Option
1 variability factor. The calculation of the resulting BDAT treatment
standard for naphthalene (0.059 ppm) is described in Section 6.0 and is shown
in Table 6-10.
4-179
-------
TABLE 4-100
WASTEWATER TREATMENT PERFORMANCE DATA
FOR NAPHTHALENE
TECHNOLOGY
a
AL
AL
AL
AL+AL
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AirS
CAC
ChOx
* BT
PACT
RBC
RO
5?
TF
WOx
TECHNOLOGY FACILITY
SIZE
Pilot I92D
Bench 371D
Pjlot 192D
PUOt 203A
Pilot 203A
Full 233D
Full 201B
Full 6B
Bencl
PflO'
1 1050E
241B
Pilot 241B
Full 975B
Pilot 204A
Bend
Piloi
1 202D
: 203A
Pilot 240A
Full
Ful
Ful
Pffi
Fill
Ful
PS|
L IB
IB
6B
L 6B
192D
IB
6B
6B
: 192D
1 1328E
Pilot 203A
Bench 975B
Full 1293
Bend
Pjlo'
I Zimro
: 192D
P|lot 180A
Pilot 240A
Full IB
Pilot 203A
Full Zinpro
DETECTION RANGE
LIMIT INFLUENT
(ppb) CONCENTRATION
(ppb)
0-100
100-1000
100-1000
100-1000
100-1000
100-1000
0-100
100-1000
100-1000
100-1000
100-1000
100-1000
0-100
1000-10000
100-1000
100-1000
0-100
100-1000
10000-100000
100-1000
0-100
0-100
1000-10000
100-1000
100-1000
10000-100000
100-1000
0-100
10 11227-37145
191
0-100
0-100
100-1000
0-100
100-1000
6 1200
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION ft) (\)
11
11
21
11
2
5
11
5
8
11
12
5
5
14
13
4
7
3
5
11
15
1
11
6
11
1
(PPb)
10
23
25
13
36
16
5
14
2
8
10
1
0
10
4
6
9
10
10
10
1C
1C
10
6200
79
2
10
1
10
0
14
74
210
.000
.000
.000
.000
.000
.000
.000
.000
.000
.900
.000
.000
.700
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.020
.000
.000
.000
.000
82
97.7
96.5
88
67
98.3
89
95.9
99.5
97.9
93
99.17
99.09
99.86
96.3
95
86
95.4
99.95
99
82
91.9
99.56
96
96.5
74
27
88
99.9
82
80
88
89
32
REFERENCE
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
ITD-L *
WAO
WERL
WERL
WERL
WERL
WERL
WAO
Data used in developing proposed standard.
4-180
-------
2-Naphthvlamlne (D168). The data available for 2-naphthylamine were
compiled from the WERL database and are presented in Table 4-101. The
technology for which data were available was bench-scale AS with a resulting
effluent concentration of 95 ppb.
BOAT for 2-naphthylamine is being promulgated as proposed and is
identified as activated sludge biological treatment (AS). Activated sludge
was selected as BDAT since it represents data from a technology which the
Agency believes to be demonstrated in full-scale units for organic
constituents similar to 2-naphthylamine and shows a high removal efficiency.
The BDAT treatment standard for 2-naphthylamine was calculated using the
effluent concentration of 95 ppb and the appropriate variability factor and
accuracy correction factor. The calculation of the resulting BDAT treatment
standard for 2-naphthylamine (0.52 ppm) is described in Section 6.0 and is
shown in Table 6-10.
TABLE 4-101
WASTEWATER TREATMENT PERFORMANCE DATA
FOB 2-NAPHTHYLAMINE
DETECTION RANGE NO. OF AVERAGE '
TECHNOLOGY TECHNOLOGY FACILITY LIHIT INFLUENT DATA EFFLDENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (I) (*)
(ppb) (ppb)
* AS Bench 315B 1000-10000 2 95.000 95.4 /ERL *
* Data used in developing proposed standard.
4-181
-------
p-flj.troanillne (P077). The data available for p-nitroaniline were
compiled from the WERL database and are presented in Table 4-102. The
technology for which data were available was bench-scale PACTR with a
resulting effluent concentration of 3 ppb. The detection limit for
p-Nitroaniline is 5 ppb (see Table C-l, Appendix C).
BDAT for p-nitroaniline is being promulgated as proposed and is
identified as PACT8. PACT* was selected as BDAT since it represents data from
a technology which the Agency believes to be demonstrated in full-scale units
for organic constituents similar to p-nitroaniline and shows a high removal
efficiency. The BDAT treatment standard for p-nitroaniline was calculated
using an effluent concentration of 5 ppb (which represents the detection
limit) and the appropriate variability factor and accuracy correction factor.
The calculation of the resulting BDAT treatment standard for p-nitroaniline
(0.028 ppm) is described in Section 6.0 and is shown in Table 6-10.
TABLE 4-102
HASTEWATER TREATMENT PERFORMANCE DATA
FOR p-NITROANILINE
DETECTION
TECHNOLOGY TECHNOLOGY FACILITY LIMIT
SIZE (ppb)
RANGE
INFLUENT
CONCENTRATION
(PPb)
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL REFERENCE
POINTS CONCENTRATION (t) (I)
(PPb)
* PACT
Bench
190E
10000-100000
3.000
99.96 HERL *
* Data used in developing proposed standard.
4-182
-------
Nitrobenzene (U169). Several sources of wastewater treatment
performance data were available for nitrobenzene, including data from the ITD,
BOAT, and WERL databases, BOAT Solvents Rule data, and literature WAO data.
These data are presented in Table 4-103. Technologies for which data are
available include AL, AS, AirS, BT, BT+AC, ChOx, LL, LL+SS, LL+SS+AC, PACT",
SS, SS+AC, and WOx. The treatment performance data represent bench-, pilot-,
and full-scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BDAT for nitrobenzene is being promulgated as proposed and is
identified as steam stripping followed by activated carbon (SS+AC). The BDAT
treatment standard was calculated using the ITD median long-term average of 14
ppb and the ITD Option 1 variability factor. The calculation of the resulting
BDAT treatment standard for nitrobenzene (0.068 ppm) is described in Section
6.0 and is shown in Table 6-10.
4-183
-------
TABLE 4-103
WASTEWATER TREATMENT PERFORMANCE DATA
FOR NITROBENZENE
TECHNOLOGY TECHNOLOGY FACILITY
SIZE
AL Ben
AS Pu
AS Fu
AS Fu
AS Ben
ch 371D
11 975B
11 6B
1 6B
ch 202D
DETECTION
LIHIT
(PPb)
> ff >
AS Bench 200B
AS Full 975B
AS full 6B
AS Pilot 241B
AS Full IB
AS Pilot 241B
AirS Bench 1328E
BT Full P246
BTHC Full P246
ChOx Bench 975B
LL Full K104
LL Fu
LL+SS FU
11 K103
11 K103/K104
LL+SS+AC Full K1037K104
30
30
30
30
PACT Bench 190E
PACT Full 6B
PACT Bench 975B
PACT Bench 200B
SCO* Pilot 65D
SS FU
SS Fu
* SSfAC Fu
* SS+AC FU
SS+AC Pu
1 P297
1 P246
1 500
1 2680
1 P297
14
14
HO* Bench Zispro
RANGE
INFLDENT
CONCENTRATION
(PI»)
1000-10000
100-1000
1000-10000
10000-100000
10000-100000
100-1000
100-1000
1000-10000
100-1000
100-1000
100-1000
100000-1000000
821-5559
821-90500
0-100
2200000-3900000
1500000-3000000
1500000-3900000
1500000-3900000
100-1000
1000-10000
100-1000
100-1000
1000000
87000-330000
91200-1965760
14-5460000
87000-330000
87000-330000
5125000
HO. OF
DATA
POINTS
330
3
16
28
4
1
10
14
18
5
5
5
4
4
12
10
15
37
10
10
1
AVERAGE
EFFLOEH
RECOVERY
TONCENTRATIOH (1)
(m
69.
96.
120.
150.
2200.
3.
3.
14.
10.
23.
32.
96000.
737.
297.
2.
2420000.
2200000.
2400.
30.
21.
14.
2.
3.
22.
11793.
251325.
520.
712.
713.
255000.
000
000
000
000
000
000
400
000
000
000
000
000
000
000
000
000 115
000 115
000 115
000 115
000
000
700
000
000
000
300
600
000
000
REMOVAL
(*)
97.7
72
96.1
99.8
97.8
97.5
99.48
99.78
92.3
90
92.8
16
95.9
96
98.8
98.3
96.7
99.99
95
REFERENCE
WERL
WERL
mi
WERL
WERL
WERL
WERL
WERL
m
WERL
WERL
HERL
BOAT /
BOAT )
WERL
BOAT
BOAT
BOAT
BDAT
WERL
WERL
WERL
WERL
WERL
BDAT I
BDAT I
ITD-L *
ITD-L *
BDAT 1
MAO
I ITD data resented in the BDAT Solvents Me F001-F005 Background Docment.
* Data usea in developing proposed standard.
4-184
-------
4-Nitrophenol (U170). Three sources of wastewater treatment
performance data were available for 4-nitrophenol, including data from the ITD
and WERL databases and literature WAO data. These data are presented in Table
4-104. Technologies for which data are available include AC, AS, LL+SS,
PACT", and WOx. The treatment performance data represent bench- and full-
scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BDAT for 4-nitrophenol is being promulgated as proposed and is
identified as activated carbon (AC). The BDAT treatment standard was
calculated using the ITD median long-term average of 50 ppb and the ITD Option
1 variability factor. The calculation of the resulting BDAT treatment
standard for 4-nitrophenol (0.12 ppm) is described in Section 6.0 and is shown
in Table 6-10.
4-185
-------
TABLE 4-104
HASTEWATER TREATMENT PERFORMANCE DATA
FOR 4-NITROPHEHOL
TECHHOLOGY
* AC
AS
AS
AS
LLrSS
PACT
PACT
«0x
*ox ;BI
wx :BJ
TEOBOLOGY FACILITY
SIZE
Rti
Ful
Fui:
Ful
Bend
Full
Bend
Bend
Bend
L 2680T
6B
6B
IB
L K103/K104
1 WOE
L 6B
i Zinpro
) 235A
) 1101D
DETECTION
LIKIT
(ppb)
50
150
RANGE
IHFLDEHT
CONCENTRATION
(PPb)
1790-6603
100-1000
100-1000
100-1000
750000-15000000
100-1000
1000-10000
10000000
> 1000000
> 1000000
NO. OF
DATA
POINTS
9
3
3
2
5
8
1
1
AVERAGE
EFFLOENT RECOVERY
CONCENTRATION (*)
(PPb)
50.000
50.000
140.000
25.000
14200.000
3.900
50.000
40000.000
4000.000
10000.000
REMOVAL
W
93.1
79
95.1
99.46
95.8
99.6
99.96
99.01
REFERENCE
ITD-L
«ERL
»ERL
vIERL
BOAT
*m
V.IRL
-------
N-Mtrosodiethvlamine (U174). No wastewater treatment performance
data were available for N-nitrosodiethylamine from any of the examined
sources. Treatment performance data were therefore transferred to this
constituent from a constituent judged to be similar in elemental composition
and functional groups within the structure of the chemical. For constituents
represented by a U or P code, this means that constituents included in the
same waste treatability group (see Appendix B) were candidates for transfer of
data. N-Nitrosodiethylamine is in treatability group II.A.3.f.(6) and the
constituent used to transfer treatment performance data from was
N-nitrosodimethylamine. The treatment performance data for N-nitro-
sodimethylamine is presented in Table 4-105. Using a transfer from this
constituent results in BOAT for N-nitrosodiethylamine of activated sludge
biological treatment and a BDAT treatment standard of 0.40 ppm as described in
Section 6.0 and shown in Table 6-10.
4-187
-------
N-Nltrosodimethvlamine (F082). The data available for N-
nitrosodimethylamine were compiled from the NPDES and WERL databases,
published articles, and literature WAO data. These data are presented in
Table 4-105. Technologies for which data are available include AS, BT,
chemical reduction (Chred) and WOx. The treatment performance data represent
bench- and full-scale studies. The resulting effluent concentrations ranged
from an unspecified not detect value to 22,000 ppb.
BOAT for N-nitrosodimethylamine is being promulgated as proposed and
is identified as activated sludge biological treatment (AS). Activated sludge
was selected as BOAT since it represents a technology which the Agency
believes is demonstrated on a full-scale unit for organic constituents similar
to N-nitrosodimethylamine and shows a high removal efficiency. The BOAT
treatment standard for N-nitrosodimethylamine was calculated using the
effluent concentration of 73 ppb and the appropriate variability factor and
accuracy correction factor. The calculation of the resulting BOAT treatment
standard for N-nitrosodimethylamine (0.40 ppm) is described in Section 6.0 and
is shown in Table 6-10.
TABLE 4-105
WASTEWATER TREATMENT PERFORKAHCE DATA
FOR N-NITJOSODINETHYLAHINE
TECHNOLOGY
* AS
BT
Chred
Wx
«0x
DETECTION RANGE
TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCENTRATION
W ippb)
Bench
Full
Bench
Bench
Bench
LA0065501
LA0066214
NY0199648
315B
LA0038245
Zinpro
Zinpro
1000-10000
1000
510000
5030000
NO. OF
DATA
POINTS
6
15
10
4
37
3
1
1
AVERAGE
EFFLUENT RECOVERY REMOVAL REFERENCE
CONCENTRATION (?) |Tl
(ppb)
10.000
10.000
11.800
73.000
10.270
ND
1000.000
22000.000
MPDES
NPDES
1IPDES
96.7 *ERL *
NPDES
ART
99.8 *AO
99.6 ViAO
Data used in developing proposed standard.
4-188
-------
N-Nitrosodi-n-butvlamine (U172). No wastewater treatment
performance data were available for N-nitrosodi-n-butylamine from any of the
examined sources. Treatment performance data were therefore transferred to
this constituent from a constituent judged to be similar in elemental
composition and functional groups within the structure of the chemical. For
constituents represented by a U or P code, this means that constituents
included in the same waste treatability group (see Appendix B) were candidates
for transfer of data. N-Nitrosodi-n-butylamine is in treatability group
III.A.3.f.(6) and the constituent used to transfer treatment performance data
from was N-nitrosodimethylamine. The treatment performance data for
N-nitrosodimethylamine are presented in Table 4-105. Using a transfer from
this constituent results in a BOAT for N-nitrosodi-n-butylamine of activated
sludge biological treatment and a BOAT treatment standard of 0.40 ppm as
described in Section 6.0 and shown in Table 6-10.
N-Nitrosomethvlethvlamlne. No wastewater treatment performance data
were available for N-nitrosomethylethylamine from any of the examined sources.
Treatment performance data were therefore transferred to this constituent from
a constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
N-Nitrosomethylethylamine is similar in structure to constituents in
treatability group III.A.3.f.(6) and the constituent used to transfer
treatment performance data from was N-nitrosodimethylamine. The treatment
performance data for N-nitrosodimethylamine are presented in Table 4-105.
Using a transfer from this constituent results in a BOAT for
N-nitrosomethylethylamine of activated sludge biological treatment and a BOAT
treatment standard of 0.40 ppm as described in Section 6.0 and shown in
Table 6-10.
4-189
-------
N-Nitrosomorpholine. No wastewater treatment performance data were
available for N-nitrosomorpholine from any of the examined sources. Treatment
performance data were therefore transferred to this constituent from a
constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
N-Nitrosomorpholine is similar in structure to constituents in treatability
group III.A.3.f.(6) and the constituent used to transfer treatment performance
data from was N-nitrosodimethylamine. The treatment performance data for
N-nitrosodimethylamine are presented in Table 4-105. Using a transfer from
this constituent results in a BOAT for N-nitrosomorpholine of activated sludge
biological treatment and a BOAT treatment standard of 0.40 ppm as described in
Section 6.0 and shown in Table 6-10.
N-Nltrosopiperidine (U179). No wastewater treatment performance
data were available for N-nitrosopiperidine from any of the examined sources.
Treatment performance data were therefore transferred to this constituent from
a constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data. N-
Nitrosopiperidine is in treatability group III.A.3.f.(1) and the constituent
used to transfer treatment performance data from was pyridine. The treatment
performance data for pyridine are presented in Table 4-36. Using a transfer
from this constituent results in a BOAT for N-nitrosopiperidine of anaerobic
fixed film biological treatment and a BOAT treatment standard of 0.013 ppm as
described in Section 6.0 and shown in Table 6-10.
4-190
-------
N-nltrosopvrrolidlne (U180). No wastewater treatment performance
data were available for N-nitrosopyrrolidine from any of the examined sources.
Treatment performance data were therefore transferred to this constituent from
a constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
N-Nitrosopyrrolidine is in treatability group III.A.3.f.(1) and the
constituent used to transfer treatment performance data from was pyridine.
The treatment performance data for pyridine are presented in Table 4-36.
Using a transfer from this constituent results in a BOAT for N-nitroso-
pyrrolidine of anaerobic fixed film biological treatment and a BOAT treatment
standard of 0.013 ppm as described in Section 6.0 and shown in Table 6-10.
5-Nitro-o-toluidine (U181). No wastewater treatment performance
data were available for 5-nitro-o-toluidine from any of the examined sources.
Treatment performance data were therefore transferred to this constituent from
a constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
5-Nitro-o-toluidine is in treatability group III.A.3.f.(5) and the constituent
used to transfer treatment performance data from was 2,4-dinitro-toluene. The
treatment performance data for 2,4-dinitrotoluene are presented in Table 4-88.
Using a transfer from this constituent results in a BDAT for 5-nitro-o-
toluidine of PACT8 and a BDAT treatment standard of 0.32 ppm as described in
Section 6.0 and shown in Table 6-10.
4-191
-------
Pentachlorobenzene (U183). No wastewater treatment performance data
were available for pentachlorobenzene from any of the examined sources.
Treatment performance data were therefore transferred to this constituent from
a constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
Pentachlorobenzene is in treatability group III.A.2.c.(3)(b) and the
constituent used to transfer treatment performance data from was
hexachlorobenzene. The treatment performance data for hexachlorobenzene are
presented in Table 4-94. Using a transfer from this constituent results in a
BOAT for pentachlorobenzene of activated sludge followed by filtration and a
BOAT treatment standard of 0.055 ppm as described in Section 6.0 and shown in
Table 6-10.
4-192
-------
Pentachloronitrobenzene (U185). No wastewater treatment performance
data were available for pentachloronitrobenzene from any of the examined
sources. Treatment performance data were therefore transferred to this
constituent from a constituent judged to be similar in elemental composition
and functional groups within the structure of the chemical. For constituents
represented by a U or P code, this means that constituents included in the
same waste treatability group (see Appendix B) were candidates for transfer of
data. Pentachloronitrobenzene is in treatability group III.A.2.c.(3)(b) and
the constituent used to transfer treatment performance data from was
hexachlorobenzene. The treatment performance data for hexachlorobenzene are
presented in Table 4-94. Using a transfer from this constituent results in a
BOAT for pentachloronitrobenzene of activated sludge followed by filtration
and a BOAT treatment standard of 0.055 ppm as described in Section 6.0 and
shown in Table 6-10.
4-193
-------
PerLtachlorophenol (U051). The data available for pentachlorophenol
were compiled from the NPDES and WERL databases, and literature WAO data.
These data are presented in Table 4-106. Technologies for which data are
available include AL, AS, CAC, BT, Fil+GAC, RBC, GAG, RO, TF, and WOx. The
treatment performance data represent bench-, pilot-, and full-scale studies.
The resulting effluent concentrations ranged from 0.01 ppb to 135,000 ppb.
BOAT for pentachlorophenol is being promulgated as proposed and is
identified as filtration followed by granular activated carbon (Fil+GAC).
Fil+GAC was selected as BOAT since it represents treatment data with a high
influent concentration and a high removal efficiency. The effluent
concentration achievable by Fil+GAC is supported by the effluent concentration
data from the biological treatment technologies. The BOAT treatment standard
for pentachlorophenol was calculated using the effluent concentration of 20
ppb and the appropriate variability factor and accuracy correction factor.
The calculation of the resulting BOAT treatment standard for pentachlorophenol
(0.089 ppm) is described in Section 6.0 and is shown in Table 6-10.
4-194
-------
TABLE 4-106
WASTEWATER TREATMENT PERFORMANCE DATA
FOP PENTACHLOROPHENOL
TECHNOLOGY
AL
AL
AL
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
TECHNOLOGY FACILITY
SIZE
LA0066214
TX0001201
OH0058874
MS0044580
TX0001201
M00103349
HW0049786
NJ0050750
LA0065501
OH0004961
CT0003751
WI0025739
WY0032590
PA0026531
WY0032590
CT0001341
. A NY0001210
Pilot 203A
Pilot 203A
Pilot 192D
Bench 1050E
Pilot 192D
Pilot 240A
Ful
Benc
Benc
Benc
Ful
Pilo
673B
1 1691A
1 202D
1 960E
375E
: 204A
Pull 375E
DETECTION RANGE
LIMIT INFLUENT
(ppb) CONCENTRATION
0-100
0-100
100-1000
100-1000
100-1000
0-100
1000-10000
100-1000
1000-10000
10000-100000
0-100
0-100
0-100
NO. OF
DATA
POINTS
15
9
5
1
59
14
40
5
6
1
1
1
34
29
1
24
11
11
5
9
29
4
7
8
7
AVERAGE
EFFLUENT RECOVERY
CONCENTRATION (1)
(ppb)
10.000
29.400
7624.000
3.000
41 900
3.700
3.148
18.775
5.000
16200.000
10.000
40.000
1.000
23103.400
1.000
64.600
>m
20.000
10.000
2.800
70.000
20.000
3600.000
1.000
170.000
5400.000
0.620
6.300
0.650
REMOVAL
32
76
98
99.3
86
60
57
99.66
97.9
74
15
17
14
REFERENCE
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
4-195
-------
TABLE 4-106 (Continued)
WASTEWATER TREATMENT PERFORMANCE DATA
- FOR PENTACHLOROPHENOL
TECHNOLOGY
AS
AS
AS
AS
AS
AS
BT
BT
BT
CAC
COAG+Sed+BT+Fil
Fll
RBC
RO
TF
TF
TF
TF
if
TF
WOX
WOx [B]
TECHNOLOGY FACILITY
SIZE
Pilot 203A
Benc
Ful
Benc
Benc
Ful
Ful
Ful
Pilo
Plo
) 1691A
375E
1 40D
l 1691A
375E
PA0008800
PA0026247
LA0038245
: 203A
. HI0024023
t 673B
Pilot 673B
P lot 673B
Pilot 192D
P lot 180A
Pilot 240A
Ful
Ful
Pilo
Ful
Ful
Benc
Benc
375E
.IB
IB
: 203A
375E
H00023264
i Zirpro
1 235A
DETECTION RANGE NO. OF
LIMIT' INFLUENT DATA
(ppb) CONCENTRATION POINTS
(PPb)
0-100 11
10000-100000
0-100 7
10000-100000 30
1000-10000
0-100 7
6
25
41
0-100 11
18
1000-10000 28
100-1000 9
1000-10000 28
100-1000
0-100
0-100 10
0-100 7
100-1000 6
0-100 6
0-100 11
0-100 7
10
5000000 1
> 1000000 1
AVERAGE
EFFLUENT
CONCENTRATION
(PPb)
3.000
2.000
0.190
68.000
2.000
0.410
585.200
28.600
44.624
50.000
20.444
3400.000
20.000
30.000
90.000
0.100
25.000
0.430
220.000
14.000
82.000
0.500
12.100
135000.000
6000.000
RECOVERY REMOVAL
96.4
99.98
63
99.66
99.94
39
40
6
fi:?2
82
86
39
6
35
69
2
33
97.3
99.88
REFERENCE
WERL
WERL
WERL
WERL
WERL
WERL
NPDES
NPDES
NPDES
WERL
NPDES
WERL
S *
WERL
WERL
UERL
WERL
WERL
WERL
WERL
WERL
NPDES
WAO
WERL
Data used in developing proposed standard.
4-196
-------
Phenacetin (U187). The data available for phenacetin were compiled
from the EPA WAO treatment test and are presented in Table 4-107. These data
represent pilot-scale WOx and WOx+PACTR. WOx and PACT" were considered
demonstrated technologies for phenacetin since the Agency believes these
technologies exist as full-scale units treating organic constituents similar
to phenacetin. The resulting average effluent concentration was 31 ppb.
The proposed BOAT standard was set using the WOx performance data
and an achievable effluent of 2,400 ppb (the lowest detection limit from the
WOx test). Since PACT" data became available just prior to proposal, the
treatment train WOx+PACT" was not considered until after proposal. The
promulgated BOAT standard was set using the treatment train WOx+PACTR and an
achievable effluent of 31 ppb (the detection limit from the PACT" test).
WOx+PACTR was selected as BOAT because data from this treatment train show a
high influent concentration, high removal efficiency, and represent data
generated by EPA as part of the BOAT program.
The calculation of the resulting BOAT treatment standard for
phenacetin (0.081) is described in Section 6.0 and is shown in Table 6-10.
TABLE 4-107
WASTEWATER TREATMENT PERFORMANCE DATA
FOR PHENACETIN
TECHNOLOGY
* WOX
WOX
* WOX
WOX t PACT
TECHNOLOGY
SIZE
Pilot
PUot
Pilot
FACILITY
Zinpro
Z}npro
Zinpro
Zinpro
DETECTION
LIMIT
2400
5300
2400
26
RANGE
INFLDENT
CONCENTRATION
120000
120000
120000
<4800-120000
NO. OF
DATA
POINTS
1
1
3
AVERAGE
EFFLUENT
CONCENTRATION
(ppb)
ND
ND
ND
31.000
RECOVERY REMOVAL REFERENCE
(*) (*)
WAO *
WAO
WAO *
WAO
Data used in developing proposed standard.
4-197
-------
Phenanthrene (U051). Two sources of wastewater treatment
performance data were available for phenanthrene, including data from the ITD
and WERL databases. These data are presented in Table 4-108. Technologies
for which data are available include AL, AS, AS+Fil, CAC, BT, PACT", and TF.
The treatment performance data represent bench-, pilot-, and full-scale
studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BDAT for phenanthrene is being promulgated as proposed and is
identified as biological treatment (BT). The BDAT treatment standard was
calculated using the ITD median long-term average of 10 ppb and the ITD Option
1 variability factor. The calculation of the resulting BDAT treatment
standard for phenanthrene (0.059 ppm) is described in Section 6.0 and is shown
in Table 6-10.
4-198
-------
TABLE 4-108
WASTEHATEB TREATMENT PERFORMANCE DATA
FOB PHENANTHRENE
TECHNOLOGY
AL
AL
AL
AL
AS
AS
AS
AS
AS
AS
AS
AS+Pil
CAC
Fll
* BT
PACT
TF
TF
TF
TECHNOLOGY
SIZE
Full
P;lot
Pilot
Bench
Pilot
Pilot
Full
Pilot
Full
Bench
Bench
full
Pilot
Full
F^lll
Pjlot
Pilot
Full
DETECTION
FACILITY LIMIT
(PPb)'
6B
203A
203A
371D
204A
240A
6B
203A
IB
202D
1050E
6B
203A
792E
1293 10
6B
240A
203A
IB
RANGE
INFLUENT
CONCENTRATION
(ppb)
100-1000
0-100
0-100
100-1000
0-100
0-100
1000-10000
0-100
0-100
100-1000
100-1000
1000-10000
0-100
0-100
2035-4711
100-1000
0-100
0-100
100-1000
NO. OF
DATA
POINTS
5
11
11
8
12
14
11
4
. 5
3
11
4
15
10
10
11
6.
AVERAGE
EFFLUENT RECOVERY
CONCENTRATION (!)
(PPb)
10.000
40.000
16.000
15.000
1.100
6.000
10.000
4.000
13.000
10.000
2.000
17.000
24.000
10.000
10.000
25.000
9.000
51.000
17.000
REMOVAL
(*)
92.9
58
83
98.5
97.2
93
99.7
95.8
32
98.2
99.5
• 99.8
75
85
95.9
90
46
91.5
REFERENCE
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
ITD-L *
WERL
WERL
WERL
WERL
Data used in developing proposed standard.
4-199
-------
Phenol (U188). Several sources of wastewater treatment performance
data were available for phenol, including data from the ITD, BOAT, and WERL
databases as well as literature WAO data. These data are presented in Table
4-109A. In addition, leachate treatment performance data submitted by
industry just prior to proposal are presented in Table 4-109B. Technologies
for which data are available include AL, API+DAF+AS, AS, ChOx, GAG, BT, LL,
LL+SS, LL+SS+AC, PACTR, RBC, RO, SBR, SS, TF, WOx, AS+Fil, and Anff. The
treatment performance data represent bench-, pilot-, and full-scale studies.
At proposal, BOAT for phenol was identified as biological treatment
and the treatment standard was based on an ITD median long-term average
effluent concentration of 10.363 ppb from the ITD database. Between proposal
and promulgation, EPA evaluated the industry-submitted leachate data available
for phenol. Since this data for biological treatment (BT) showed substantial
treatment of phenol, these data were used to calculate the promulgated
standards. Therefore, BOAT for phenol is biological treatment.
The BDAT treatment standard for phenol was calculated using the
effluent concentration of 10 ppb and the appropriate variability factor and
accuracy correction factor: The calculation of the resulting BDAT treatment
standard for. phenol (0.039 ppm) is described in Section 6.0 and is shown in
Table 6-10.
4-200
-------
TABLE 4-109A
WASTEWATER TREATMENT PERFORMANCE DATA
FOR PHENOL
TECHNOLOGY
AL
AL
AL
AL
API+DAF+AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS+Fil
AS+Fll
DETECTION
TECHNOLOGY FACILITY LIMIT
SIZE (ppb)-
Pjlo
PllO
Ful
Ful
Ful
Ful
Benc
Pul
ful
PllO
Fu.
Ful
Ful
Ful
Ful
Ful
Ful
Benc
Ful
Ful
Ful
PllO
Ful
Ful
Ful
Ful
Ful
Ful
?Ful
Ful
P 10
t 203A
: 203A
6B
: 192D
1482D
IB
IB
1 202D
6B
IB
: 203A
201B
IB
6B
IB
IB
975B
IB
1 1054E
. 240A
6B
1122E
6B
: 241B
6B
975B
6B
IB
IB
6B
226B
975B
6B
: 204A
Pilot 192D
Ful
Benc
i
Ful
6B
l 1054E
6B
IB
6B
1 66
RANGE
INFLUENT
CONCENTRATION
(ppb)
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
0-100
100000-1000000
100-1000
100-1000
100-1000
100-1000
100-1000
10000-100000
100-1000
0-100
1000-10000
100-1000
100000-1000000
0-100
100-1000
10000-100000
100-1000
100-1000
1000-10000
100-1000
100-1000
100-1000
0-100
100-1000
100000-1000000
1000-10000
100000-1000000
100-1000
100-1000
1000-10000
10000-100000
100000-1000000
100-1000
10000-100000
100-1000
NO. OF
DATA
POINTS
11
11
3
4
5
6
39
5
11
31
6
3
6
3
5
11
7
3
4
10
11
6
6
3
6
2
8
4
13
6
15
AVERAGE
EFFLUENT
CONCENTRATION
(PPb)
84.000
18.000
11.000
10.000
85.000
2.000
26.000
0.010
10.000
8.000
14.000
20.000
1.000
10.000
61.000
1.000
6.600
1.000
0.250
10.000
15.000
4000.000
120.000
8.000
21.000
20.000
10.000
1.000
1.000
10.000
500.000
160.000
10.000
14.000
10.000
56.000
1000.000
10.000
25.000
13.000
10.000
RECOVERY REMOVAL
(*) (*)
33
86
90.8
98.99
89.5
98.6
63
99.99
96.4
97.2
89
92.6
99.89
99.94
92.4
96.4
99.87
99.33
99.88
90
98
95.2
97.9
97.2
99.64
87
96.3
99.44
98.3
98.6
99.95
95
99.99
94.6
98.99
96.9
95
99.99
94.4
99.98
98
REFERENCE
WERL
WERL
HERL
HERL
WERL
WERL
HERL
HERL
HERL
HERL
HERL
HERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
HERL
HERL
WERL
WERL
WERL
WERL
WERL
WERL
HERL
HERL
HERL
WERL
WERL
WERL
4-201
-------
TABLE 4-109A (Continued)
WASTEWATER TREATMENT PERFORMANCE DATA
FOR PHENOL
TECHNOLOGY TECHNOLOGY FACILITY
AnFF
AnFF
AnFF
AnFF
AnFF
AnFF
AnFF
AnFFwGAC
CAC
ChOx
ChOx
ChOx
GAC
GAC
GAC
* BT
LL
LL
LL+SS
LLtSS+AC
PACT
PACT
PACT
PACT
RBC
BBC
RO
SBR
SBR
SBR
SBRvPACT
SExt
SS
TF
TF
TF
TF
WOX
WOX I
WOX 1
WOX I
SIZE
Pilot 231A
Pilot 231A
B^nch 230A
P;lot 231A
Pilot 231A
Bench 230A
Pilot 235D
Pjlot 249D
Pilot 203A
Benc
Benc
Benc
Benc
Rt
Ful
sa
Ful
Ful
Benc
Benc
1 975B
1 975B
1 975B
1 1054E
245B
237A
1293
K104
K103
K103/K104
K1037K104
3 190E
1 975B
Full 6B
Be.nc
Pjlo
Plla
Pilo
1 975B
: 603E
: 192D
250B
1433D
Pilot 227D
Bench 64D
Bench 64D
P}lot 1082E
Pilot 1082E
Pilot 203A
pffi
Pul
Benc
J Benc
J Benc
L IB
: 240A
L IB
i Zitpro
1 1054E
i 1101D
} Bench 236A
DETECTION RANGE
LIMIT INFLUENT
(ppb) CONCENTRATION
(ppb)
1000000
1000000
logooo-ioooooo
100000-1000000
100000-1000000
> 1000000
100000-1000000
1000000
100-1000
100-1000
100-1000
1000-10000
100-1000
100-1000 .
1000-10000
10 698564-978672
30 150000-300000
30 1500000-3000000
30 150000-3000000
30 150000-3000000
10000-100000
1000-10000
1000-10000
1000-10000
100000-1000000
100-1000
1000-10000
10000-100000
100000-1000000
100000-1000000
100000-1000000
>1000000
100000-1000000
100-1000
100-1000
0-100
0-100
10000000
100000-1000000
>1000000
> 1000000
NO. OF
DATA
POINTS
11
1
1
15
5
5
4
3
16
1
11
6
10
6
1
1
AVERAGE
EFFLDENT RECOVERY
CONCENTRATION (\)
(Ppb)
700.000
30.000
10.000
10.000
70.000
1000.000
240.000
50.000
99.000
16.000
2.000
12.000
10.000
10.000
5.000
10.000
165000.000 21
84000.000 21
2400.000 21
60.000 21
1.800
2.000
30.000
8.000
1700.000
10.000
120.000
1000.000
1000.000
3000.000
1000.000
210000.000
160.000
64.000
47.000
8.000
1.000
20000.000
27000.000
3600.000
3000.000
REMOVAL
($)
99.98
99.99
98.97
99.99
99.98
99.95
99.86
99.99
21
93.3
98.3
99.37
99
92.6
99.89
99.99
99.96
98.6
99.85
99.6
98.99
93.6
97.7
99.81
99.63
99.88
95.4
24
49
82
91.3
98.2
99.8
97.3
99.92
99.97
REFERENCE
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
ITD-L *
BOAT
BOAT
BOAT
BOAT
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WAO
WERL
WERL
WERL
Data used in developing proposed standard.
TABLE 4-109B
INDUSTRY-SDBHITTED LEACHATE TREATMENT PERFORMANCE
DATA FOR PHENOL
TECHNOLOGY
BT
!Y TECHNOLOGY
SIZE
FACILITY
DETECTION
PR
RANGE
INFLUENT
CONCENTRATION
(ppb)
NO. OF
DATA
POINTS
AVERAGE
EFFLDENT
CONCENTRATION
(ppb)
RECOVERY
(*)
REMOVAL
W
REFERENCE
DOW
10
715-2500
10.000
99.32 LEACHATE
4-202
-------
Phrhalic Anhydride (U190). No wastewater treatment performance data
were available at proposal for phthalic anhydride from any of the examined
sources. Treatment performance data were therefore transferred to this
constituent from a similar compound, methyl ethyl ketone. In addition,
leachate treatment performance data were submitted by industry just prior to
proposal and are presented in Table 4-109C. At proposal, BOAT for phthalic
anhydride was identified as PACT0 and the treatment standard was based on an
effluent concentration of 5 ppb from a transfer of methyl ethyl ketone
treatment performance data. Between proposal and promulgation, EPA evaluated
the industry-submitted leachate data available for phthalic anhydride. Since
this data for biological treatment (BT) showed substantial treatment of
phthalic anhydride and showed average leachate effluent values greater than
that of PACTn , these data were used to calculate the promulgated standard.
Therefore, BOAT for phthalic anhydride is biological treatment.
The BDAT treatment standard for phthalic anhydride was calculated
using the effluent concentration of 15 ppb and the appropriate variability
factor and accuracy correction factor. The calculation of the resulting BDAT
treatment standard for phthalic anhydride (0.069 ppm) is described in Section
6.0 and is shown in Table 6-10.
TABLE 4-109C
INDUSTRY-SOBNITTED LEACHATE TREATMENT PERFORMANCE
DATA FOR PHTHALIC ANHYDRIDE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLDENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (!) (T)
(ppb) (ppb)
BT Bench OM -26633 3 15.000 99.94 LEACHATE
4-203
-------
PrnT)amide (U192) . The data available for pronamide were compiled
from the EPA WAO treatment test and are presented in Table 4-110. These data
represent pilot-scale WOx and WOx+PACT". WOx and PACT" were considered
demonstrated technologies for pronamide since the Agency believes these
technologies exists as full-scale units treating organic constituents similar
to pronamide. The resulting average effluent concentration is 29 ppb.
The proposed BOAT standard was set using the WOx performance data
and an achievable effluent of 21 ppb (the lowest detection limit from the WOx
test). Since PACT" data became available just prior to proposal, the
treatment train WOx+PACTR was not considered until after proposal. The
promulgated BOAT standard was set using the treatment train WOx+PACTR and an
achievable effluent of 29 ppb (which represents the average of the three sets
of data). WOx+PACTn was selected as BOAT because data from this treatment
train show a high influent concentration, high removal efficiency, and
represent data generated by EPA as part of the BOAT program.
The calculation of the resulting BOAT treatment standard for
pronamide (0.093 ppm) is described in Section 6.0 and is shown in Table 6-10.
TABLE 4-110
SASTEWATER TREATMENT PERFORMANCE DATA
FOR PRONAMIDE
DETECTION
TECHNOLOGY TECHNOLOGY FACILITY LIMIT
SIZE (ppb)
RANGE NO. OF AVERAGE
INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
CONCENTRATION POINTS CONCENTRATION (I) |T)
(ppb) (ppb)
*
. WOx
WOX
WOx
WOx-
HOX
+ PACT
P*
?i
P;
PI
PI
ot
ot
ot
ot
ot
Znmro
Zl
z
I
n
LD
n
ZlB
iro
pro
pro
iro
21
2000
2100
4500
22
91000-100000
91000-100000
91000-100000
91000-100000
91000-100000
1
1
1
1
3
ND
ND
ND
ND
29.000
wAO *
viAO
V.O
WAO
WAO
Data used in developing proposed standard.
4-204
-------
Pvrene (U051). Three sources of wastewater treatment performance
data were available for pyrene, including data from the ITD and WERL databases
as well as literature WAO data. These data are presented in Table 4-111.
Technologies for which data are available include AL, AS, AS+Fil, CAC, ChOx,
GAG, BT, TF, and WOx. The treatment performance data represent bench-, pilot-
, and full-scale studies.
The treatment performance data available from the ITD database were
used for setting the proposed and promulgated BOAT standard for this
constituent for the following reasons:
(1) The ITD data represent treatment performance data from the
OCPSF sampling episodes. The data collected by ITD include
long-term sampling of several industries. These data are
therefore a good reflection of the total organic chemical
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD data were carefully screened prior to inclusion in the
OCPSF database. These data were used in determining an ITD
promulgated limit.
(3) A promulgated ITD limit represents data that have undergone
both EPA and industry review and acceptance.
BDAT for pyrene is being promulgated as proposed and is identified
as biological treatment (BT). The BDAT treatment standard was calculated
using the ITD median long-term average of 11.33 ppb and the ITD Option 1
variability factor. The calculation of the resulting BDAT treatment standard
for pyrene (0.067 ppm) is described in Section 6.0 and is shown in Table
6-10.
4-205
-------
TABLE 4-111
WASTEWATER TREATMENT PERFORMANCE DATA
FOR PYRENE
TECHNOLOGY
AL
AL
AL
AS
AS
AS
AS
AS
AS+Fil
CAC
CAC
ChOx(Cl)
Fll
n
Pj..
Fl
GAC
* BT
TF
TF
HOX
TECHNOLOGY
SUE
Bench
Pilot
Pjlot
Pilot
full
Phot
Pilot
Full
Full
Pilot
Pilot
Full
Pjlot
Pilot
Pull
full
Pilot
Ml
PJlot
Pilot
Bench
DETECTION RANGE
FACILITY LIMIT INFLUENT
(ppb) CONCENTRATION
371D
203A
203A
203A
IB
204A
240A
6B
6B
195B
203A
1081D
195B
577E
1081D
792E
195D
1293 10
203A
240A
Zinpro
(ppb)
100-1000
100-1000
100-1000
100-1000
0-100
0-100
0-100
100-1000
1000-10000
1000-10000
100-1000
0-100
100-1000
0-100
0-100
1000-10000
0-100
641-1438
100-1000
0-100
500000
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (1) (1)
(ppb)
11
11
11
11
1
8
12
14
3
8
11
8
4
6
15
11
10
1
15
36
25
5
5
10
10
16
110
12
0
80
0
0
6
10
10
48
17
260
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.018
.000
.001
.045
.000
.000
.300
.000
.000
.000
97
65
76
95.2
80
93.3
90
99
99.48
94.5
88
60
27
99.96
40
99.5
79
54
83
99.95
REFERENCE
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
ITD-L *
WERL
WERL
WAO
* Data used in developing proposed standard.
4-206
-------
Safrole (U203). No wastewater treatment performance data were
available for safrole from any of the examined sources. Treatment performance
data were therefore transferred to this constituent from a constituent judged
to be similar in elemental composition and functional groups within the
structure of the chemical. For constituents represented by a U or F code,
this means that constituents included in the same waste treatability group
(see Appendix B) were candidates for transfer of data. Safrole is in
treatability group III.A.3.h and the constituent used to transfer treatment
performance data from was phenacetin. The treatment performance data for
phenacetin are presented in Table 4-107. Using a transfer from this
constituent results in a BOAT for safrole of wet air oxidation followed by
PACT" and a BOAT treatment standard of 0.081 ppm as described in Section 6.0
and shown in Table 6-10.
4-207
-------
1.2.4.5-Tetrachlorobenzene (U207). The data available for 1,2,4,5-
tetrachlorobenzene were compiled from the NPDES database and are presented in
Table 4-113. Since influent values were not available for the NPDES data and
since the NPDES average effluent value was below the compound detection limit
of 1.5 ppb it cannot be determined that this data represents treatment.
Treatment performance data were therefore transferred to this constituent from
a constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
1,2,4,5-Tetrachlorobenzene is in treatability group III.A.2.c.(3)(b) and the
constituent used to transfer treatment performance data from was
hexachlorobenzene. The treatment performance data for hexachlorobenzene is
presented in Table 4-94. Using a transfer from this constituent results in a
BOAT for 1,2,4,5-tetrachlorobenzene of activated sludge followed by filtration
and a BOAT treatment standard of 0.055 ppm as described in Section 6.0 and
shown in Table 6-10.
TABLE 4-113
MASTEWATER TREATKEHT PERFORMANCE DATA
FOR 1,2,4,5-TETRACHLOROBENZENE
TECHNOLOGY
DETECTION
TECHNOLOGY FACILITY LIMIT
SIZE (ppb)
RANGE
INFLUENT
CONCENTRATION
(ppb)
NO. OF
DATA
AVERAGE
EFFLDENT
POINTS CONCENTRATION
(PPb)
RECOVERY REMOVAL REFERENCE
(*) M
MI0000868
1.111
NPDES
4-208
-------
2.3^.4.6-Tetrachlorophenol. The data available for 2,3,4,6-tetra-
chlorophenol were compiled from the WERL database and are presented in
Table 4-114. Technologies for which data are available include full-scale AS
and TF. The resulting effluent concentrations ranged from 0.06 ppb to
0.21 ppb.
BDAT for 2,3,4,6-tetrachlorophenol is being promulgated as proposed
and is identified a biological treatment (BT). Both AS and TF are biological
processes and since effluent concentrations for both technologies were
similar, the general treatment technology BT was selected to represent both
technologies. BT was selected as BDAT since this data represents a
demonstrated technology with average removal efficiencies and low effluent
concentrations. Since the average effluent concentration values seen were
below the EPA method detection limit, the BDAT standard was set using the
detection limit of 6.8 ppb in lieu of the actual data (see Table C-l,
Appendix C). The actual data presented substantiates that this level of
treatment is achievable.
The calculation of the resulting BDAT treatment standard for
2,3,4,6-tetrachlorophenol (0.030) is described in Section 6.0 and is shown in
Table 6-10.
TABLE 4-114
WASTEWATER TREATMENT PERFORMANCE DATA
FOR 2,3,4,6-TETRACHLOROPHESOL
DETECTION RANGE NO. OP AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (\) (\)
(ppb) (ppb)
AS
AS
AS
AS
TP
TF
375E
375E
375E
375E
375E
375E
0-100
0-100
0-100
0-100
0-100
0-100
7
7
7
7
7
7
0.060
0.210
0.180
0.110
0.100
0.060
62
16
5
15
28
45
WERL *
WERL *
WERL *
WERL *
WERL *
WERL *
Data used in developing proposed standard.
4-209
-------
1.2.4-Trlcholorobenzene. The data available for 1,2,4-
trichlorobenzene were compiled from the WERL database and are presented in
Table 4-115. Technologies for which data are available include AFF, AS, BGAC,
GAG, PACT", RO, and TF. The treatment performance data represent bench-,
pilot-, and full-scale studies. The resulting effluent concentrations ranged
from 0.02 ppb to 89 ppb.
BDAT for 1,2,4-trichlorobenzene is being promulgated as proposed and
is identified as PACTn. PACTR was selected as BDAT since this technology
represents full-scale treatment with a high influent concentration and a high
removal efficiency. The BDAT treatment standard for 1,2,4-trichlorobenzene
was calculated using the effluent concentration of 10 ppb and the appropriate
variability factor and accuracy correction factor. The calculation of the
resulting BDAT treatment standard for 1,2,4-trichlorobenzene (0.055 ppm) is
described in Section 6.0 and is shown in Table 6-10.
TABLE 4-115
WASTEWATER TREATMENT PERFORMANCE DATA
FOB 1,2,4-TRICHLOROBENZENB
TECHNOLOGY
AFF
AS
AS
AS
AS
AS
AS
AS
BGAC
GAC
GAC
PACT
* PACT
RO
TF
DETECTION RANGE
TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCENTRATION
(ppb)
• Bench 501A
Full 6B
Pilot 241B
Ful
Ful
Ful
Ful
Benc
Benc
Ful
Ful
IB
201B
IB
975B
1 200B
B 501A
245B
L 1421D
Bench 200B
Pilot 180A
Full IB
0-100
100-1000
100-1000
0-100
0-100
1000-10000
100-1000
100-1000
0-100
1000-10000
0-100
100-1000
100-1000
0-100
0-100
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCEPTION (V| (1)
(PPD)
23
330
9
6
13
4
14
34
1
12
10
3
0.870
71.000
89.000
8.000
14.000
39.000
36.000
12.000
0.280
10.000
0.830
2.100
10.000
0.020
5.000
90.5
88
86
92
80
91.9
34
90
96.9
99.74
90
98
96
95.7
91.7
REFERENCE
*ERL
'«RL
VERL
*ERL
>'ERL
*ERL
*ERL
WERL
*ERL
m
'mi
AERL *
KERL
ViERL
Data used in developing proposed standard.
4-210
-------
2.4.5-Trichlorophenol. The data available for 2,4,5-trichlorophenol
were compiled from the NPDES database and are presented in Table 4-116A. In
addition, leachate treatment performance data submitted by industry just prior
to proposal are presented in Table 4-116B. The demonstrated treatment
technology presented was BT.
At proposal, BDAT for 2,4,5-trichlorophenol was identified as
activated sludge (AS) and the treatment standard was based on an effluent
concentration of 1 ppb from a transfer of 2,4,6-trichlorophenol treatment
performance data. Between proposal and promulgation, EPA evaluated the
industry-submitted leachate data available for 2,4,5-trichlorophenol. Since
this data for biological treatment (BT) showed substantial treatment of 2,4,5-
trichlorophenol and showed average leachate effluent values greater than that
of activated sludge, these data were used to calculate the promulgated
standard. In addition, the Agency preferred to set the BDAT treatment
standard on actual data rather than on a transfer of treatment performance
data. Therefore, BDAT for 2,4,5-trichlorophenol is biological treatment.
The BDAT treatment standard for 2,4,5-trichlorophenol was calculated
using the effluent concentration of 50 ppb and the appropriate variability
factor and accuracy correction factor. The calculation of the resulting BDAT
treatment standard for 2,4,5-trichlorophenol (0.18 ppm) is described in
Section 6.0 and is shown in Table 6-10.
4-211
-------
TABLE 4-1161
WASTEWATER TREATMENT PERFORMANCE DATA
FOR 2,4,5-TRICHLOROPHENOL
DETECTION JANGE_ NQ._OF .AVERAGE
TECHHOLOGY TECHHOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (I) (I)
(_P_P_b) (_ppb) ___
Gr/Rei Full WI0029149 4 8.000 HPDES
TABLE 4-116B
INDUSTRY-SUBMITTED TREATMENT PERFORMANCE
DATA FOR 2,4,5-TRICHLOROPHENOL
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHHOLOGY FACILITY LIMIT INFLDENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS C08CENTRATIOH (I) (I)
(ppb) (ppb)
BT DOH 50 25-1000 3 50.000 90.1 LEACHATE
4-212
-------
2.4.6-Trichlorophenol. The data available for 2,4,6-trichlorophenol
were compiled from the NPDES and WERL databases and are presented in
Table 4-117A. In addition, leachate treatment performance data submitted by
industry just prior to proposal are presented in Table 4-117B. Technologies
for which data are available include AS, BT, and RO. The treatment
performance data represent pilot- and full-scale studies. The resulting
effluent concentrations ranged from 0.01 ppb to 7,150 ppb.
At proposal, BOAT for 2,4,6-trichlorophenol was identified as
activated sludge (AS) and the treatment standard was based on an effluent
concentration of 1 ppb. Between proposal and promulgation, EPA evaluated the
industry-submitted leachate data available for 2,4,6-trichlorophenol. Since
this data for biological treatment (BT) showed substantial treatment of 2,4,6-
trichlorophenol and showed average leachate effluent values greater than those
of activated sludge, these data were used to calculate the promulgated
standard. Therefore, BOAT for 2,4,6-trichlorophenol is biological treatment.
The BDAT treatment standard for 2,4,6-trichlorophenol was calculated
using the effluent concentration of 10 ppb and the appropriate variability
factor and accuracy correction factor. The calculation of the resulting BDAT
treatment standard for 2,4,6-trichlorophenol (0.035 ppm) is described in
Section 6.0 and is shown in Table 6-10.
4-213
-------
TABLE 4-117A
«ASTEV1ATER TREATMENT PERFORMANCE DATA
FOR 2,4,6-TRICHLOROPHENOL
DETECTION RANGE NO. OF AVERAGE
TECHHOLOGY TECHHOLOGY FACILITY LIMIT INFLUENT DATA EFFLOENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (1) (I)
(PPb) (ppb)
* AS Fu
* AS Fu
BT Fu
BT Fu
BT Fu
BT Ful
RO Pllo
PA0033367
PA0036650
AR0038512
PA0008231
LA0065501
AR0038512
CT0001341
HI0000868
PA0008231
LA0066214 .
MJ0005134
375E
375E
PA0026247
LA0038245
NY0026042
KI0022276
t 180A
1
6
25
7
6
20
30
8
1
15
18
0-100 7
0-100 7
25
38
3
22
0-100
10
5
3083
7150
10
1294
398
2
10
10
37
0
0
11
10
5
0
0
.000
.170
.510
.000
.000
.810
.000
.000
.000
.000
.647
.070
040
.'520
.466
.000
.635
.010
HPDES
NPDES
HPDES
NPDES
HPDES
NPDES
NPDES
NPDES
MPDES
NPDES
HPDES
42 HEW, *
60 «ERL *
NPDES
HPDES
NPDES
HPDES
98 /JEBL
Data used in developing proposed standard.
TABLE 4-117B
IHDCSTRY-SUBNITTED TREATMENT PERFORMAHCE
DATA FOR 2,4,6-TRICHLOROPHENOL
TECHHOLOGY
TECHHOLOGY
SIZE
FACILITY
DETECTION
LIMIT
(ppb)
RANGE
IHFLDEBT
CONCENTRATION
(PPb)
NO. OF
DATA
POINTS
AVERAGE
EFFLUENT
CONCENTRATION
(PPb)
RECOVERY
(*)
REMOVAL
(*)
REFEREHCE
BT
DOW
10
26-200
10.000
90.49 LEACHATE
4-214
-------
Tris(2.3-dibromopropvl)phosphate (U235). No wastewater treatment
performance data were available for tris(2,3-dibromopropyl)phosphate from any
of the examined sources. Treatment performance data were therefore
transferred to this constituent from a constituent judged to be similar in
elemental composition and functional groups within the structure of the
chemical. For constituents represented by a U or P code, this means that
constituents included in the same waste treatability group (see Appendix B)
were candidates for transfer of data. Tris(2,3-dibromopropyl)phosphate is
similar in structure to constituents in treatability group III.A.2.e and the
constituent used to transfer treatment performance data from was bromomethane.
The treatment performance data for bromomethane are presented in Table 4-7.
Using a transfer from this constituent results in a BOAT for tris(2,3-
dibromopropyl)phosphate of activated sludge biological treatment and a BOAT
treatment standard of 0.11 ppm as described in Section 6.0 and shown in
Table 6-10.
4-215
-------
4.4 Metals
Constituents discussed in this section include:
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium (total)
Copper
Lead
Mercury
Nickel
Selenium
Silver
Thallium
Vanadium
Zinc
The data presented in this section and the standards based on these data apply
to multi-source leachate wastewaters only. Metal wastewater standards for U
and P wastewaters are identified in separate background documents.
4-216
-------
Ant-fanony. Two sources of wastewater treatment performance data were
available for antimony, including data from the ITD-CMDB and WERL database.
These data are presented in Table 4-118. Technologies for which data are
available include AS, CAC, L+Sed, and L+Sed+Fil. The treatment performance
data represent bench- and full-scale studies.
The treatment performance data available from the ITD-CMDB were used
for setting the proposed and promulgated BOAT standard for this constituent
for the following reasons:
(1) The ITD-CMDB represents industry wide treatment performance
data which were collected as part of ITD's effluent guidelines
work. These data are therefore a good reflection of the metals
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD-CMDB data were carefully screened prior to inclusion in
the OCPSF database. These data were used in determining ITD
promulgated limits.
(3) In addition, the ITD-CMDB data have been challenged in court
and were upheld. These data therefore represent a reviewed and
accepted source of treatment performance data.
The BOAT for antimony is lime conditioning followed by sedimentation
and filtration (L+Sed+Fil) and using the ITD mean long term average and ITD-
CMDB variability factor, a BOAT treatment standard equal to the ITD 1-day
maximum limit was calculated as shown in Table 6-10. The BDAT treatment
standard for antimony is 1.9 ppm.
4-217
-------
TABLE 4-118
WASTEWATER TREATMENT PERFORMANCE DATA
FOR ANTIMONY
TECHNOLOGY
AS
AS
AS
AS
AS
AS
AS
AS
AS
CAC (B)
L+Sed
* LfSed+Fil
DETECTION RANGE
TECHNOLOGY FACILITY LIMIT INFLDENT
SIZE (ppb) CONCENTRATION
Full
Fui:
Ful
Ful.
Ful
Ful.
L IB
975B
L 201B
IB
IB
IB
Full IB
Full IB
Full ' IB
"Rft 638B
Full
(PPD)
0-1000
100-1000
0-100
0-100
0-100
0-100
0-100
0-100
0-100
1000-10000
8500
8500
NO. OP AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (1) (I)
6
11
2
6
6
6
4
6
1
(PP»|
58.000
59.000
6.000
6.000
5.000
2.000
2.000
14.000
6.000
200.000
700.000
470.000
59.00
66.00
54.00
68.00
44.00
60.00
50.00
72.00
50.00
88.00
REFERENCE
SEW,
<
-------
Arsenic. Three sources of wastewater treatment performance data
were available for arsenic, including data from the ITD-CMDB, WERL and BOAT
databases. These data are presented in Table 4-119. Technologies for which
data are available include AL, AS, CAC, Chred/Pt+SED+Fil, L+Sed, L+Sed+Fil,
and TF. The treatment performance data represent bench- and full-scale
studies.
The treatment performance data available from the ITD-CMDB were used
for setting the proposed and promulgated BOAT standard for this constituent
for the following reasons:
(1) The ITD-CMDB represents industry wide treatment performance
data which were collected as part of ITD's effluent guidelines
work. These data are therefore a good reflection of the metals
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD-CMDB data were carefully screened prior to inclusion in
the OCFSF database. These data were used in determining ITD
promulgated limits.
(3) In addition, the ITD-CMDB data have been challenged in court
and were upheld. These data therefore represent a reviewed and
accepted source of treatment performance data.
The BOAT for arsenic is lime conditioning followed by sedimentation
and filtration (L+Sed+Fil) and using the ITD mean long term average and ITD-
CMDB variability factor, a BOAT treatment standard equal to the ITD 1-day
maximum limit was calculated as shown in Table 6-10. The BOAT treatment
standard for arsenic is 1.4 ppm.
4-219
-------
TABLE 4-119
WASTEWATER TREATMENT PERFORMANCE DATA
FOR ARSENIC
DETECTION RANGE
TECHHOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCENTRATION
(Ppb)
AL
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
CAC
CAC (B)
CAC (Bi .
Chred/PUSed+Pil
L+Sed.
* L+Sed+Fil
TF
Ful
Fu
Fu
Fu
Fu
Fu.
Fu
Fa
Fa
Fa
Fu
Fa
Fa
Fa
Benc
Benc
Ful
Ful
Ful
Ful
1 IB
234A
234A
234A
234A
234A
201B
IB
IB
IB
IB
IB
975B
393A
) 638B
D 638B
K062
IB
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
100-1000
0-100
0-100
100-1000
<100-3000
4200
4200
0-100
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (1) (1)
(ppb)
4
7
7
7
7
7
6
6
6
6
6
5
1
1
11
6
8.000
3.000
6.000
6.000
1.000
1.000
4.000
4.000
2.000
2.000
3.000
2.000
83.000
6.300
8.000
2.000
180.000
510.000
340.000
32.000
0.00
50.00
40.00
50.00
75.00
39.00
50.00
50.00
50.00
50.00
0.00
33.00
27.00
34.00
67.00
99.69
0.00
REFERENCE
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
BOAT
ITD-CKDB
ITD-CKDB *
WERL
Data used in developing proposed standard.
4-220
-------
Two sources of wastewater treatment performance data were
available for barium, including data from the ITD-CMDB and UERL database.
These data are presented in Table 4*120. Technologies for which data are
available include AL, AS, RBC, L+Sed, L+Sed+Fil, and TF. The treatment
performance data represent full-scale studies.
The treatment performance data available from the ITD-CMDB were used
for setting the proposed and promulgated BOAT standard for this constituent
for the following reasons:
(1) The ITD-CMDB represents industry wide treatment performance
data which were collected as part of ITD's effluent guidelines
work. These data are therefore a good reflection of the metals
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD-CMDB data were carefully screened prior to inclusion in
the OCPSF database. These data were used in determining ITD
promulgated limits.
(3) In addition, the ITD-CMDB data have been challenged in court
and were upheld. These data therefore represent a reviewed and
accepted source of treatment performance data.
The BOAT for barium is lime conditioning followed by sedimentation
and filtration (L+Sed+Fil) and using the ITD mean long term average and ITD-
CMDB variability factor, a BDAT treatment standard equal to the ITD 1-day
maximum limit was calculated as shown in Table 6-10. The BDAT treatment
standard for barium is 1.2 ppm.
4-221
-------
TABLE 4-120
WASTEWATER TREATMENT PERFORMANCE DATA
FOR BARIUM
TECHNOLOGY
AL
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
IS
AS
AS
AS
AS
AS
AS
AS
AS
TECHNOLOGY FACILITY
SIZE
Ful
Fu
FU
Fu
Fu
Fu.
Fu
Fu
Fu
Fu
Fu
1 IB
IB
IB
IB
IB
IB
IB
IB
IB
IB
IB
Full IB
Fu
Pu
Fu
Fu
Fu
FU
Ful
Fu
Fu
FU
FU
FU
FU
Fu
FU
Fu
FU
201B
IB
IB
IB
IB
IB
IB
IB
IB
IB
IB
IB
IB
IB
IB
IB
IB
IB
Full IB
Full IB
Full IB
DETECTION RANGE
LIMIT INFLUENT
(ppb) CONCENTRATION
(ppb)
100-1000
0-100
0-100
0-100
0-100
100-1000
100-1000
0-100
100-1000
0-100
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
- 100-1000
100-1000
100-1000
0-100
100-1000
0-100
100-1000
100-1000
100-1000
100-1000
0-100
100-1000
100-1000
100-1000
100-1000
100-1000
HO. OF
DATA
POINTS
6
6
6
6
6
5
6
6
6
6
4
6
35
6
6
6
6
4
6
6
6
6
6
6
4
6
6
6
6
6
6
6
6
6
AVERAGE
EFFLUENT RECOVERY
CONCENTRATION (1)
(PPb)
47.000
22.000
12.000
17.000
54.000
17.000
49.000
19.000
15.000
23.000
2.000
38.000
30.000
94.000
44.000
34.000
41.000
180.000
67.000
18.000
59.000
19.000
64.000
29.000
46.000
34.000
16.000
18.000
21.000
32.000
58.000
31.000
100.000
43.000
REMOVAL
(*)
76.00
75.00
72.00
79.00
46.00
86.00
62.00
64.00
86.00
73.00
98.30
65.00
75.00
61.00
63.00
88.00
71.00
67.00
61.00
95.50
82.00
76.00
77.00
71.00
62.00
69.00
86.00
85.00
72.00
75.00
61.00
89.70
44.00
75.00
REFERENCE
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WER,
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
4-222
-------
TABLE 4-120 (Continued)
WASTEWATER TREATMENT PERFORMANCE DATA
FOR BARIUM
TECHHOLOGY
* L+Sed+Fil
RBC
TF
TF
TF
TF
TP
TF
TF
TF
TF
TF
TF
TF
DETECTION RANGE
TECHHOLOGY FACILITY LIMIT IHFLDEHT
SIZE (ppb) CONCENTRATION
(ppb)
Fu
Fu
FU
FU
Fu
Fu
FU
FU
FU
FU
FU
Fu
Fu
Fu
Ful
IB
IB
IB
IB
IB
IB
IB
IB
IB
IB
IB
IB
1 IB
2600
2600
100-1000
0-100
0-100
0-100
100-1000
100-1000
100-1000
0-100
100-1000
100-1000
100-1000
0-100
100-1000
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (*) (i)
(PPb)
6
6
6
6
6
6
6
6
6
6
6
6
6
420.000
280.000
26.000
33.000
13.000
32.000
72.000
120.000
110.000
43.000
53.000
79.000
47.000
17.000
140.000
78.00
39.00
83.00
68.00
52.00
62.00
21.00
49.00
71.00
58.00
57.00
80.00
39.00
REFERENCE
ITD-CKDB
ITD-CHDB *
*ERL
WEKL
*ERL
*ERL
UEKL
WERL
HERL
HERL
HERL
HERL
WERL
HERL
HERL
Data used in developing proposed standard.
4-223
-------
Beryllium. Two sources of wastewater treatment performance data
were available for beryllium, including data from the ITD-CMDB and WERL
database. These data are presented in Table 4-121. Technologies for which
data are available include AS, L+Sed, and L+Sed+Fil. The treatment
performance data represent full-scale studies.
The treatment performance data available from the ITD-CMDB were used
for setting the proposed and promulgated BOAT standard for this constituent
for the following reasons:
(1) The ITD-CMDB represents industry wide treatment performance
data which were collected as part of ITD's effluent guidelines
work. These data are therefore a good reflection of the metals
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD-CMDB data were carefully screened prior to inclusion in
the OCPSF database. These data were used in determining ITD
promulgated limits.
(3) In addition, the ITD-CMDB data have been challenged in court
and were upheld. These data therefore represent a reviewed and
accepted source of treatment performance data.
The BOAT for Beryllium is lime conditioning followed by
sedimentation and filtration (L+Sed+Fil) and using the ITD mean long term
average and ITD-CMDB variability factor, a BDAT treatment standard equal to
the ITD 1-day maximum limit was calculated as shown in Table 6-10. The BDAT
treatment standard for beryllium is 0.82 ppm.
TABLE 4-121
WASTEWATER TREATMENT PERFORMANCE DATA
FOR BERYLLIUM
DETECTIOH RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLDENT DATA EFFLDENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (\) (1)
(ppb) (ppb)
AS Full IB
AS Full 201B
L+Sed Full
* L+Sed+Fil Full
0-100 2
0-100 6
10240
10240
2.000
1.000
300.000
200.000
50.00 WERL
75.00 WERL
ITD-CKDB
ITD-CMDB *
Data used in developing proposed standard.
4-224
-------
Cadmium. Three sources of wastewater treatment performance data
were available for cadmium, including data from the ITD-CMDB, WERL database,
and ITD-MF database. These data are presented in Table 4-122. Technologies
for which data are available include AS, CAC, ChOx/Pt, ChPt, Fil, L+Sed,
L+Sed+Fil, pt.+Sed, Sed+Fil, and TF. The treatment performance data
represent bench-, pilot-, and full-scale studies.
The treatment performance data available from the ITD-CMDB were used
for setting the proposed and promulgated BOAT standard for this constituent
for the following reasons:
(1) The ITD-CMDB represents industry wide treatment performance
data which were collected as part of ITD's effluent guidelines
work. These data are therefore a good reflection of the metals
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD-CMDB data were carefully screened prior to inclusion in
the OCPSF database. These data were used in determining ITD
promulgated limits.
(3) In addition, the ITD-CMDB data have been challenged in court
and were upheld. These data therefore represent a reviewed and
accepted source of treatment performance data.
The BOAT for cadmium is lime conditioning followed by sedimentation
and filtration (L+Sed+Fil) and using the ITD mean long term average and ITD-
CMDB variability factor, a BDAT treatment standard equal to the ITD 1-day
maximum limit was calculated as shown in Table 6-10. The BDAT treatment
standard for cadmium is 0.20 ppm.
4-225
-------
TABLE 4-122
WASTEWATER TREATMENT PERFORMANCE DATA
FOR CADMIUM
TECHHOLOGY TECHBOLOGY FACILITY
SIZE
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
CAC
CACfB
ChOx/Pt
CDOxVPt
opt
Fil
LtSed
Ful
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Pu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
FU
Fu
FU
FU
FU
FU
Pu
Fu
B) Benc
B Benc
' Ful
Pilo
Ful
* L+Sed+Fll Ful
Pt+Sed
Ful
Sed+Fil Ful
IF
TF
Ful
Ful
243A
234A
234A
234A
243A
201B
1 167E
IB
IB
234A
IB
IB
167E
IB
IB
167E
IB
IB
IB
IB
167E
975B
IB
IB
IB
393A
638B
1 248A
1 248A
245B
254B
IB
1 IB
DETECTION RANGE
LIMIT INFLUENT
(ppb) CONCENTRATION
(PPb)
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
1000-10000
0-100
0-100
0-100
0-100
10000-100000
100000-1000000
1000-10000
0-100
100-3830
100-3830
5 0-21500
100-3830
0-100
0-100
NO. OF
DATA
POINTS
7
7
7
16
7
6
7
6
6
6
6
7
6
6
6
6
6
6
1
1
1
1
13
31
6
6
AVERAGE
EFFLUENT
CONCENTRATION
(ppb)
0.300
0.100
•0.100
5.500
1.000
7.000
1.000
2.000
7.000
0.100
2.000
3.000
1.000
5.000
2.000
1.000
5.000
2.000
6.000
3.000
1.000
28.000
65.000
96.000
15.000
5.300
30.000
900.000
800.000
13.000
34.000
79.000
49.000
190.000
10.000
16.000
2.000
RECOVERY REMOVAL
90.90
99.41
99.47
68.00
85.00
30.00
95.20
60.00
86.00
95.80
87.00
95.50
90.90
82.00
80.00
93.30
58.00
67.00
40.00
62.00
97.80
77.00
94.10
90.10
91.20
44.00
75.00
91.30
99.65
99.31
40.00
76.00
92.60
REFERENCE
WERL
*ERL
SEW,'
viERL
•mi
>m
«m
ViERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
ITD-CHDB
ITD-CMDB *
ITD-NF
ITD-CNDB
WERL
WERL
Data used in developing proposed standard.
4-226
-------
Chromium (Total). Several sources of wastewater treatment
performance data were available for chromium, including data from the ITD-
CMDB, WERL, BOAT, and ITD-MF databases. These data are presented in
Table 4-123. Technologies for which data are available include AL, AS, CAC,
ChOx, ChPt, Fil, L+Sed+Fil, PACT", Sed, and TF. The treatment performance
data represent bench-, pilot, and full-scale studies.
The treatment performance data available from the ITD-CMDB were used
for setting the proposed and promulgated BOAT standard for this constituent
for the following reasons:
(1) The ITD-CMDB represents industry wide treatment performance
data which were collected as part of ITD's effluent guidelines
work. These data are therefore a good reflection of the metals
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD-CMDB data were carefully screened prior to inclusion in
the OCPSF database. These data were used in determining ITD
promulgated limits.
(3) In addition, the ITD-CMDB data have been challenged in court
and were upheld. These data therefore represent a reviewed and
accepted source of treatment performance data.
The BOAT for chromium (total) is lime conditioning followed by
sedimentation and filtration (L+Sed+Fil) and using the ITD mean long term
average and ITD-CMDB variability factor, a BDAT treatment standard equal to
the ITD 1-day maximum limit was calculated as shown in Table 6-10. The BDAT
treatment standard for chromium (total) is 0.37 ppm.
4-227
-------
TABLE 4-123
WASTEWATER TREATMENT PERFORMANCE DATA
FOR CHROHIUH (TOTAL)
TECHNOLOGY
AL
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
DETECTION RANGE
TECHNOLOGY FACILITY LIMIT INFLOENT
SIZE (ppb) CONCENTRATION
(PPb)
Full IB
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
FU
Fu
Fu
Fu
Fu
Fu
Fu
FU
FU
FU
Fu
FU
Fu
Ful
234A
IB
167E
IB
IB
234A
IB
167E
IB
243A
IB
IB
IB
IB
234A
IB
IB
198E
234A
234A
IB
IB
243A
IB
IB
IB
IB
167E
IB
167E
100-10000
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
100-1000
100-1000
100-1000
100-1000
1000-10000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (1) (T)
(ppb)
6
7
6
6
7
7
6
6
6
6
6
6
7
6
6
33
7
7
6
6
6
6
6
6
6
130.000
7.000
29.000
9.000
5.000
22.000
16.000
6.000
3.000
12.000
12.000
36.000
35.000
6.000
11.000
34.000
36.000
24.000
40.000
3.000
14.000
16.000
40.000
28.000
62.000
59.000
19.000
38.000
6.000
16.000
12.000
89.00
84.00
64.00
72.00
90.90
69.00
82.00
85.00
96.10
76.00
83.00
62.00
65.00
89.00
78.00
58.00
64.00
70.00
79.00
94.60
89.00
87.00
76.00
77.00
95.60
86.00
89.00
84.00
98.50
90.00
92.30 .
REFERENCE
WERL
A'ERL
WERL
XERL
WERL
*ERL
*ERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
HERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
•mi
WERL
4-228
-------
TABLE 4-123 (Continued)
WASTEWATER TREATMENT PERFORMANCE DATA
FOR CHROMIUM (TOTAL)
TECHNOLOGY
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
CAC
CAC IB)
ChOx/Pt B)
ChPt '
ChPt (B
ChPt B
ChPt+Fjl i B)
ChPt+Fll B)
Chred/Pt+Sed+FU
Chred/Pt+Sed+Fil
Fil
L+Sed
* L+Sed+Fil
PACT
Pt+Sed
Sed
Sed+Fil
TF
TF
TF
TF
TF
TF
TF
TECHNOLOGY FACILITY
SIZE
Full IB
Pilot 1294B
Full IB
Ful
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
FU
Fu
Ful
1 IB
1 IB
1 IB
1 IB
1 201B
1 234A
1 IB
1 IB
1 IB
1 IB
1 IB
1 393A
Bench 638B
Bench 248A
MI 245B
PUo
PUO
ffi
M
Pile
Ful
Ful
Pilo
Ful
t 254B
t 254B
t 254B
t 254B
1 K062
1 K062
t 254B
! 1294B
Pilot 1294B
Ful
Fu
FU
FU
Pu
Fu
FU
Fu
1 IB
1 IB
1 IB
1 IB
1 IB
1 IB
1 IB
DETECTION RANGE
LIMIT INFLUENT
(ppb) CONCENTRATION
(PPb)
100-1000
1000-10000
100-1000
1000-10000
100-1000
1000-10000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
1000-10000
10000-100000
100-1000
10000-100000
10000-100000
100-1000
70-917000
6000-7000000
100-1000
100-116000
100-116000
1000-10000
50 0-35400
1000-10000
100-116000
100-1000
100-1000
0-100
100-1000
100-1000
100-1000
0-100
NO. OF
DATA
POINTS
6
6
6
6
96
6
35
7
7
6
6
6
6
1
1
16
14
14
16
9
11
14
3
38
3
6
6
6
6
6
6
6
AVERAGE
EFFLDENT
CONCENTRATION
(PPb)
48.000
390.000
26.000
110.000
52.000
140.000
19.000
51.000
20.000
46.000
28.000
35.000
50.000
19.000
40.000
50.000
0.500
34.000
77.000
170.000
47.000
75.000
57.000
135.000
39.000
84.000
70.000
320.000
572.000
1100.000
80.000
57.000
34.000
15.000
92.000
180.000
44.000
17.000
RECOVERY REMOVAL
(*) (*)
88.00
64.00
80.00
97.40
82.00
90.00
83.00
77.00
82.00
89.00
93.50
68.00
54.00
88.00
94.10
62.00
74.00
99.95
76.00
99.66
99.91
77.00
68.0
90.20
71.00
66.00
56.00
69.00
67.00
23.00
25.00
71.00
48.00
REFERENCE
WERL
mi
WERL
>m
XERL
'mi
WERL
WERL
1ERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
HERL
WERL
WERL
WERL
WERL
BDAT
BDAT
WERL
ITD-CHDB
ITD-CKDB *
WERL
ITD-KF
WERL
ITD-CKDB
WERL
WERL
WERL
WERL
WERL
WERL
WERL
Data used in developing proposed standard.
4-229
-------
Copper. Several sources of wastewater treatment performance data
were available for copper, including data from the ITD-CMDB, WERL, BOAT, and
ITD-MF databases. These data are presented in Table 4-124. Technologies for
which data are available include AL, AS, CAC, ChOx, ChPt, L+Sed, L+Sed+Fil,
Pt+Sed, RBC, Sed+Fil, and TF. The treatment performance data represent
bench-, pilot-, and full-scale studies.
The treatment performance data available from the ITD-CMDB were used
for setting the proposed and promulgated BOAT standard for this constituent
for the following reasons:
(1) The ITD-CMDB represents industry wide treatment performance
data which were collected as part of ITD's effluent guidelines
work. These data are therefore a good reflection of the metals
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD-CMDB data were carefully screened prior to inclusion in
the OCPSF database. These data were used in determining ITD
promulgated limits.
(3) In addition, the ITD-CMDB data have been challenged in court
and were upheld. These data therefore represent a reviewed and
accepted source of treatment performance data.
The BOAT for copper is lime conditioning followed by sedimentation
and filtration (L+Sed+Fil) and using the ITD mean long term average and ITD-
CMDB variability factor, a BOAT treatment standard equal to the ITD 1-day
maximum limit was calculated as shown in Table 6-10. The BOAT treatment
standard for copper is 1.3 ppra.
4-230
-------
TABLE 4-124
WASTEWATEX TREATMENT PERFORMANCE DATA
FOB COPPER
TECHNOLOGY
AL
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
DETECTION RANGE
TECHNOLOGY FACILITY LIMIT IHFLDEHT
SIZE (ppb) CONCENTRATION
(ppb)
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
FU
FU
FU
FU
FU
FU
Fu
FU
FU
FU
FU
FU
FU
Fu
FU
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Ful
1 IB
IB
234A
IB
234A
IB
IB
IB
IB
198E
142A
167E
IB
201B
IB
IB
243A
IB
IB
234A
167E
IB
IB
IB
IB
IB
234A
243A
IB
234A
IB
IB
IB
IB
IB
IB
IB
167E
975B
IB
IB
100-1000
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
100-1000
100-1000
100-1000
100-1000
1000-10000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
1000-10000
100-1000
100-1000
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (1) (t)
(PPb)
6
6
7
6
7
6
6
6
6
33
14
6
35
6
6
7
6
7
6
6
6
6
6
7
6
7
6
6
6
6
6
6
6
6
6
13.000
31.000
1.000
26.000
1.000
15.000
12.000
3.000
3.000
30.000
10.000
3.000
44.000
24.000
2.000
8.000
10.000
10.000
17.000
1.000
5.000
7.000
35.000
28.000
130.000
49.000
30.000
14.000
86.000
26.000
27.000
47.000
39.000
28.000
19.000
15.000
40.000
9.000
82.000
81.000
5.000
90.70
56.00
98.90
63.00
98.20
85.00
83.00
92.00
86.00
77.00
86.00
92.30
56.00
72.00
90.00
92.00
84.00
82.00
63.00
98.70
96.20
94.20
81.00
90.30
92.40
78.00
86.00
87.00
90.70
86.00
85.00
93.80
82.00
77.00
94.20
93.80
84.00
93.30
97.50
90.00
96.90
REFERENCE
WERL
WERL
WERL
WERL
SOL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
mi
HERL
WERL
mi
mi
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
HERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
4-231
-------
TABLE 4-124 (Continued)
WASTEWATER TREATMENT PERFORMANCE DATA
FOR COPPER
TECHNOLOGY TECHNOLOGY FACILITY
SIZE
AS
AS
AS
AS
AS
AS
AS
CAC
CAC I
CAC 1
CAC I
ChOx/Pt
ChOxVPt
ChPt
ChPt
Full 167E
Ful 975B
Full IB
Ful IB
Full IB
Ful IB
Full IB
Ful 393A
\ Bench 638B
Bench 638B
I Benco 638B
B) Bench 248A
B Bench 248A
full 245B
Pll<
ChPt (B) P;l(
ChPt+Fjl B) PU<
ChPUFll (B). Pll(
Chred/Pt+Sed+Fil Fu
L+Sed Fu
* L+Sed+Fil Pu
Pt+Sed FUJ
RBC
Ful
SedfFil FuJ
TF
TF
TF
TF
TF
TF
TF
TF
TF
TF
TF
FuJ
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
FU
>t 254B
>t 254B
)t 254B
>f 254B
1 K062
IB
1 IB
1 IB
1 IB
1 IB
1 IB
1 IB
1 IB
1 IB
1 IB
1 IB
1 IB
DETECTIOH RANGE
LIMIT INFLUENT
(ppb) CONCENTRATION
(PPb)
100-1000
1000-10000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100000-1000000
HOOOOOO
1000-10000
100000-1000000
100000-1000000
100000-1000000
100000-1000000
5000-865000
100-108000
100-108000
20 0-500000
0-100
100-108000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
0-100
0-100
0-100
0-100
100-1000
NO. OF
DATA
POINTS
6
6
6
6
6
1
1
1
1
1
8
8
8
8
11
47
6
6
6
6
6
6
6
6
6
6
6
6
AVERAGE
EFFLUENT RECOVERY
CONCENTRATION (1)
(PPb)
14.000
4800.000
9.000
20.000
11.000
14.000
8.000
130.000
10.000
220.000
110.000
7600.000
1500.000
150.000
910.000
930.000
120.000
150.000
16520.000
580.000
390.000
815.000
2.000
50.000
160.000
12.000
62.000
110.000
68.000
120.000
12.000
30.000
25.000
10.000
150.000
REMOVAL
(?)
89.00
16.00
95.00
83.00
90.80
96.10
92.70
66.00
95.40
73.00
80.00
93.70
99.96
97.70
99.63
99.60
99. 95
99.94
94.90
33.00
93.30
74.00
45.00
38.00
67.00
48.00
48.00
57.00
86.00
56.00
REFERENCE
WERL
ViERL
*m
>m
WERL
*m
WERL
WERL
WERL
HERL
WERL
mi
WERL
mi
MERL
WERL
UERL
WERL
BOAT
ITD-CXDB
ITD-CHDB *
ITD-HF
WERL
ITD-CHDB
WERL
WERL
HERL
WERL
UERL
WERL
WERL
WERL
WERL
WERL
WERL
Data used in developing proposed standard.
4-232
-------
Lead, Several sources of wastewater treatment performance data were
available for lead, including data from the ITD-CMDB, WERL, BOAT, and ITD-MF
databases. These data are presented in Table 4-125. Technologies for which
data are available include AS, CAC, Fil, L+Sed, L+Sed+Fil, PACT", Pt+Sed, Sed,
Sed+Fil, and TF. The treatment performance data represent pilot- and full-
scale studies.
The treatment performance data available form the ITD-CMDB were used
for setting the proposed and promulgated BOAT standard for this constituent
for the following reasons:
(1) The ITD-CMDB represents industry wide treatment performance
data which were collected as part of ITD's effluent guidelines
work. These data are therefore a good reflection of the metals
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD-CMDB data were carefully screened prior to inclusion in
the OCPSF database. These data were used in determining ITD
promulgated limits.
(3) In addition, the ITD-CMDB data have been challenged in court
and were upheld. These data therefore represent a reviewed and
accepted source of treatment performance data.
The BDAT for lead is lime conditioning followed by sedimentation and
filtration (L+Sed+Fil) and using the ITD mean long term average and ITD-CMDB
variability factor, a BDAT treatment standard equal to the ITD 1-day maximum
limit was calculated as shown in Table 6-10. The BDAT treatment standard for
lead is 0.28 ppra.
4-233
-------
TABLE 4-125
WASTEWATER TREATMENT PERFORMANCE DATA
FOR LEAD
DETECTION RANGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCENTRATION
(PPb)
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
CAC
Chred/Pt+Sed+Fil
Fil
L+Sed
* L+Sed+Fil
PACT
Pt+Sed
Sed
Sed+Fil
TP
TF
Full IB
Full IB
Full IB
Full 201B
Full 167E
Full 167E
Full 234A
Fu
Fu
Fu
Fu
Pu
FU
Fu
Fu
FU
Ful
Pilo
Pu
Pu
Fu
Fu
Fu
Fu
Pu
Fu
Fu
Pu
Pu
Fu
Fu
Fu
Fu
Pul
Pilo
IB
167E
234A
IB
167E
234A
IB
243A
201B
234A
1294B
IB
IB
IB
198E
IB
243A
IB
234A
IB
IB
IB
975B
IB
IB
393A
K062
t 254B
Full
Pilot 1294B
Full 100
Pilot 1294B
Full
Full IB
Full IB
100-1000
0-100
0-100
0-100
100-1000
0-100
0-100
0-100
100-1000
0-100
1000-10000
0-100
0-100
0-100
0-100
100-1000
0-100
1000-10000
0-100
100-1000
0-100
0-100
100-1000
0-100
100-1000
0-100
0-100
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
10000-212000
100-1000
100-29200
100-29200
1000-10000
0-42300
1000-10000
100-29200
0-100
100-1000
NO. OF
DATA
POINTS
6
6
6
10
7
6
7
6
7
6
6
7
3
6
6
6
33
6
6
7
6
6
6
6
6
11
14
3
44
3
6
6
AVERAGE
EPFLDENT RECOVERY REMOVAL
CONCENTRATION (t) (1)
(PPb)
86.000
20.000
20.000
50.000
16.000
17.000
1.000
50.000
12.000
1.000
59.000
21.000
0.000
20.000
5.400
70.000
1.000
650.000
44.000
25.000
20.000
40.000
70.000
2.200
47.000
1.000
24.000
56.000
30.000
66.000
92.000
53.000
32.000
10.000 76
100.000
120.000
80.000
500.000
200.000
2000.000
30.000
20.000
130.000
57.00
66.00
66.00
34.00
86.00
73.00
98.70
50.00
90.20
98.50
95.10
52.00
98.00
70.00
88.00
50.00
97.80
68.00
52.00
88.00
64.00
50.00
50.00
92.10
75.00
97.80
70.00
57.00
79.00
40.00
23.00
67.00
87.00
63.00
75.00
78.00
75.00
19.00
REFERENCE
WERL
WERL
WERL
WERL
WERL
WERL
XERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
MERL
KERL
WERL
WERL
WERL
UERL
WERL
WERL
HERL
WERL
WERL
WERL
HERL
WERL
WERL
WERL
BOAT
WERL
ITD-ODB
ITD-CMDB *
WERL
ITD-MF
WERL
ITD-CKDB
•mi
WERL
Data used in developing proposed standard.
4-234
-------
Mercury. Two sources of wastewater treatment performance data were
available for mercury, including data from the ITD-CMDB and WERL database.
These data are presented in Table 4-126. Technologies for which data are
available include AS, CAC, L+Sed, L+Sed+Fil, Sed+Fil, and TF. The treatment
performance data represent full-scale studies.
The treatment performance data available from the ITD-CMDB were used
for setting the proposed and promulgated BOAT standard for this constituent
for the following reasons:
(1) The ITD-CMDB represents industry wide treatment performance
data which were collected as part of ITD's effluent guidelines
work. These data are therefore a good reflection of the metals
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD-CMDB data were carefully screened prior to inclusion in
the OCPSF database. These data were used in determining ITD
promulgated limits.
(3) In addition, the ITD-CMDB data have been challenged in court
and were upheld. These data therefore represent a reviewed and
accepted source of treatment performance data.
The BDAT for mercury is lime conditioning followed by sedimentation
and filtration (L+Sed+Fil) and using the ITD mean long term average and ITD-
CMDB variability factor, a BDAT treatment standard equal to the ITD 1-day
maximum limit was calculated as shown in Table 6-10. The BDAT treatment
standard for mercury is 0.15 ppm.
4-235
-------
TABLE 4-126
WASTEWATER TREATMENT PERFORMANCE DATA
FOR MERCURY
TECHNOLOGY
AS
AS
AS
AS
AS
AS
AS
.IS
AS
AS
AS
AS
AS
AS
AS
AS
AS
CAC
L+Sed
* L+Sed+Pil
Sed+Fil
TF
TF
TF
TF
TF
TF
TF
TF
DETECTION RANGE
TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCENTRATION
(ppb)
Fal
Fa
Fa
Fa
Fu
Fa
1 IB
IB
IB
: IB
IB
: 201B
Full IB
Fal
Fu
Fu
Fu
Fu
FU
FU
Fu
Fu
Fu
Fa
Fu
Fa
Fa
Fu
Fu
Fa
Fu
Fa
Fu
Fa
Fal
IB
IB
IB
IB
IB
IB
IB
IB
IB
IB
393A
TF
IB
IB
IB
IB
IB
IB
IB
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (1) (t)
(PPb)
6
6
6
6
6
19
6
6
6
6
6
7
6
6
6
6
6
6
6
6
6
6
6
6
6
0.220
0.200
0.200
0.230
0.230
0.300
0.230
0.450
0.130
1.000
1.200
0.400
0.200
0.200
0.220
0.300
0.230
0.090
60.000
36.000
30.000
0.570
0.200
0.200
0.270
0.430
0.650
0.300
0.280
63.00
62.00
43.00
92.80
56.00
35.00
62.00
62.00
68.00
41.00
76.00
0.00
74.00
78.00
64.00
52.00
58.00
87.00
37.00
68.00
43.00
60.00
3J:88
46.00
47.00
REFERENCE
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
UERL
WERL
UERL
WERL
WERL
WERL
JTD-CNDB
ITD-CHDB *
ITD-CNDB
WERL
WERL
WERL
WERL
UERL
UERL
UERL
UERL
Data used in developing proposed standard.
4-236
-------
Nickel. Several sources of wastewater treatment performance data
were available for nickel, including data from the ITD-CMDB, WERL, BOAT, and
ITD-MF databases. These data are presented in Table 4-127. Technologies for
which data are available include AL, AS, CAC, ChOx/Pt, ChPt, Chpt+Fil,
Chred/Pt+Sed+Fil, L+Sed, L+Sed+Fil, Pt+Sed, Sed+Fil, and TF. The treatment
performance data represent bench-, pilot-, and full-scale studies.
The treatment performance data available from the ITD-CMDB were used
for setting the proposed and promulgated BOAT standard for this constituent
for the following reasons:
(1) The ITD-CMDB represents industry wide treatment performance
data which were collected as part of ITD's effluent guidelines
work. These data are therefore a good reflection of the metals
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD-CMDB data were carefully screened prior to inclusion in
the OCPSF database. These data were used in determining ITD
promulgated limits.
(3) In addition, the ITD-CMDB data have been challenged in court
and were upheld. These data therefore represent a reviewed and
accepted source of treatment performance data.
The BOAT for nickel is lime conditioning followed by sedimentation
and filtration (L+Sed+Fil) and using the ITD mean long term average and ITD-
CMDB variability factor, a BOAT treatment standard equal to the ITD 1-day
maximum limit was calculated as shown in Table 6-10. The BOAT treatment
standard for nickel is 0.55 ppm.
4-237
-------
TABLE 4-127
WASTEWATER TREATMENT PERFORMANCE DATA
FOR NICKEL
TECHNOLOGY
AL
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
DETECTION RANGE
TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCENTRATION
(ppb)
Ful
Fu
Fu
Fll
FU.
Fu
1 IB
IB
IB
IB
234A
234A
Full 167E
Ful
Ful
Ful
Ful
Ful
FU
Fu
FU
Fu.
Fu
FU
Pu
FU.
Fu
Fu
Fu
Fll
FU
FU
FU
FU
Fu
FU
Ful
201B
167E
IB
243A
IB
IB
IB
IB
975B
IB
975B
IB
IB
IB
IB
IB
IB
IB
IB
234A
167E
IB
167E
243A
100-1000
0-100
0-100
1000-10000
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
100-1000
0-100
100-1000
0-100
100-1000
0-100
100-1000
100-1000
0-100
100-1000
0-100
100-1000
0-100
100-1000
0-100
0-100
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL
POINTS CONCENTRATION (1) (?)
(ppb)
6
6
6
6
7
7
27
7
6
6
6
6
6
6
6
6
6
6
7
6
6
7
6
53.000
25.000
74.000
200.000
9.000
1.000
14.000
66.000
73.000
20.000
41.000
70.000
45.000
82.000
10.000
102.000
17.000
80.000
22.000
120.000
36.000
120.000
56.000
40.000
98.000
44.000
13.000
2.000
290.000
10.000
19.000
76.00
34.00
19.00
82.00
79.00
94.40
85.00
34.00
17.00
33.00
39.00
19.00
35.00
16.00
78.00
27.00
29.00
50.00
65.00
14.00
34.00
25.00
49.00
56.00
42.00
19.00
88.00
96.10
59.00
83.00
17.00
REFERENCE
WERl
WERL
WERL
SE8L
*ERL
*ERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
mi
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
4-238
-------
TABLE 4-127 (Continued)
WASTEWATER TREATMENT PERFORMANCE DATA
FOR NICKEL
TECHNOLOGY TECHNOLOGY FACILITY
SIZE
AS Full IB
AS Fu
AS Fu
AS Fu
AS Fu
AS Fa
AS Fu
CAC FU
CAC (Bl
CAC [B
ChOx/Pt
ChOx/Pt
Benc
Benc
B) Benc
B) Benc
IB
234A
234A
234A
IB
IB
393A
I 638B
1 638B
i 248A
h 248A
ChPt ' Full 245B
ChPt B]
ChPt B
ChPt iB
ChPt B
ChPt B
ChPt B
ChPt+Fil i
ChPUFU
CUPt+FU i
ChPt+FU
CbPt+Flt i
Cnred/Pt+S«
Pilot 254B
Pilot 254B
Pilot 2MB
Pilot 254B
Pilot 254B
PUot 254B
B P;lot 254B
B PUot 254B
V PUOt 254B
B Pilot 254B
B Pllo
+Fil Ful
L+Sed Ful
* L+Sed+Fil Fu
Pt+Sed Fu
Sed+Fil Fu
TF Fu
TF FU
TF Ftt
TF Ful
254B
K062
IB
IB
IB
1 IB
DETECTION RANGE
LIMIT INFLDENT
(ppb) CONCENTRATION
(ppb)
0-100
0-100
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
1000-10000
>1000000
10000-100000
10000-100000
10000-100000
10000-100000
1000-10000
1000-10000
100000-1000000
10000-100000
10000-100000
10000-100000
10000-100000
100000-1000000
1000-10000
4000-100310000
100-27500
100-27500
40 0-415000
100-27500
100-1000
0-100
0-100
0-100
NO. OF
DATA
POINTS
6
7
7
7
6
6
1
1
1
1
1
8
3
17
16
3
8
8
8
3
3
17
11
45
6
6
6
6
AVERAGE
EFFLUENT
CONCENTRATION
(PPb)
74.000
13.000
21.000
1.000
50.000
270.000
240.000
120.000
100.000
100.000
28000.000
1900.000
27.000
190.000
2300.000
500.000
75.000
650.000
170.000
69.000
66.000
130.000
220.000
490.000
340.000
740.000
220.000
942.000
50.000
70.000
40.000
58.000
49.000
RECOVERY REMOVAL
(*) (*)
19.00
38.00
92.20
QQ 71
70 '.00
31.00
46.00
20.00
41.00
93.30
99.43
91.10
99.79
99.48
84.00
58.00
93.40
99.91
99.52
99.81
99.81
99.07
99.97
59.00
93.0
36.00
36.00
0.00
23.00
REFERENCE
WERL
WERL
*m
A'ERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
HERL
WERL
«ERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
BOAT
ITD-CHDB
ITD-CNDB *
ITD-HF
ITD-CKDB
WERL
WERL
WERL
WERL
Data used in developing proposed standard.
4-239
-------
Selenium. Two sources of wastewater treatment performance data were
available for selenium, including data from the ITD-CMDB and WERL database.
These data are presented in Table 4-128. Technologies for which data are
available include AL, AS, L+Sed, L+Sed+Fil, and TF, and these data all
represent full-scale studies.
The treatment performance data available from the ITD-CMDB were used
for setting the proposed and promulgated BOAT standard for this constituent
for the following reasons:
(1) The ITD-CMDB represents industry wide treatment performance
data which were collected as part of ITD's effluent guidelines
work. These data are therefore a good reflection of the metals
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD-CMDB data were carefully screened prior to inclusion in
the OCPSF database. These data were used in determining ITD
promulgated limits.
(3) In addition, the ITD-CMDB data have been challenged in court
and were upheld. These data therefore represent a reviewed and
accepted source of treatment performance data.
The BOAT for selenium is lime conditioning followed by sedimentation
and filtration (L+Sed+Fil) and using the ITD mean long term average and ITD-
CMDB variability factor, a BDAT treatment standard equal to the ITD 1-day
maximum limit was calculated as shown in Table 6-10. The BDAT treatment
standard for selenium is 0.82 ppm.
4-240
-------
TABLE 4-128
WASTEWATER TREATMENT PERFORMANCE'DATA
FOR SELENIUM
DETECTION RANGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCENTRATION
(PPb)
NO. OF AVERAGE
DATA EFFLUENT RECOVERY REMOVAL REFERENCE
POINTS CONCENTRATION (t) (*)
(PPb)
AL
AS
AS
AS
AS
AS
LtSed
* LtSed+Fil
TF
FuJ
Fu
Fu
Fu
Fu
Fu.
Fu.
Fu
FU]
LI
1
LI
1
LI
1
LI
1
j
IB
IB
975B
IB
201B
IB
IB
0-100
0-100
0-100
0-100
0-100
0-100
4200
4200
0-100
5
5
6
6
4
6
3.000
2.000
12.000
3.000
3.000
2.000
300.000
200.000
3.000
40.00
33.00
40.00
0.00
0.00
33.00
25.00
WERL
WERL
WERL
ViERL
WERL
ii'E'RL
ITD-CKDB
ITD-CMDB *
WERL
Data used in developing proposed standard.
4-241
-------
Silver. Three sources of wastewater treatment performance data were
available for silver, including data froin the ITD-CMDB and the WERL and ITD-MF
databases. These data are presented in Table 4-129. Technologies for which
data are available include AL, AS, L+Sed, L+Sed+Fil, Pt+Sed, Sed+Fil, and TF.
The treatment performance data represent full-scale studies.
The treatment performance data available from the ITD-CMDB were used
for setting the proposed and promulgated BOAT standard for this constituent
for the following reasons:
(1) The ITD-CMDB represents industry wide treatment performance
data which were collected as part of ITD's effluent guidelines
work. These data are therefore a good reflection of the metals
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD-CMDB data were carefully screened prior to inclusion in
the OCPSF database. These data were used in determining ITD
promulgated limits.
(3) In addition, the ITD-CMDB data have been challenged in court
and were upheld. These data therefore represent a reviewed and
accepted source of treatment performance data.
The BOAT for silver is lime conditioning followed by sedimentation
and filtration (L+Sed+Fil) and using the ITD mean long term average and ITD-
CMDB variability factor, a BDAT treatment standard equal to the ITD 1-day
maximum limit was calculated as shown in Table 6-10. The BDAT treatment
standard for silver is 0.29 ppm.
4-242
-------
TABLE 4-129
WASTEWTER TREATMENT PERFORMANCE DATA
FOR SILVER
TECHNOLOGY
AL
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
L+Sed
* L+Sed+Fil
Pt+Sed
Sed+Fil
TF
TF
TF
TF
TECHNOLOGY
SIZE
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
Full
DETECTION
FACILITY LIMIT
(PPb)
IB
975B
IB
201B
IB
IB
IB
IB
IB
IB
IB
IB
IB
IB
IB
IB
IB
10
IB
IB
IB
IB
RANGE
INFLUENT
CONCENTRATION
(Ppb)
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
4700
4700
0-600000
0-100
0-100
0-100
0-100
MO. OF
DATA
POINTS (
6
6
35
6
6
6
6
6
6
6
6
6
6
6
6
6
21
6
6
6
6
AVERAGE
EFFLUENT REC01
X5NCENTRATION ('
(PPb)
2.000
15.000
2.000
1.000
5.000
2.000
3.000
1.000
1.000
1.000
5.000
3.000
5.000
2.000
3.000
5.000
1.000
100.000
70.000
96.000
50.000
2.000
7.000
8.000
3.000
;ERY REMOVAL
0 (*)
60.00
50.00
94.10
88.00
50.00
78.00
87.00
88.00
86.00
80.00
71.00
85.00
67.00
90.50
81.00
72.00
90.90
90.00
63.00
47.00
73.00
REFERENCE
SERL
3IERL
SERL
'mi
*m
*m
*ERL
«ERL •
XERL
'mi
WERL
HERL
HERL
WERL
WERL
«ERL
viERL
ITD-OJDB
ITD-CMDB *
ITD-HF
ITD-CKDB
viERL
WERL
WERL
HERL
Data used in developing proposed standard.
4-243
-------
Thallium. Three sources of wastewater treatment performance data
were available for thallium, including data from the ITD-CMDB and WERL and
NPDES databases. These data are presented in Table 4-130. Technologies for
which data are available include AL, AS, BT, BT+Fil, L+Sed, L+Sed+Fil, and
Sed+COAG. These data represent full-scale studies.
The treatment performance data available from the ITD-CMDB were used
for setting the proposed and promulgated BOAT standard for this constituent
for the following reasons:
(1) The ITD-CMDB represents industry wide treatment performance
data which were collected as part of ITD's effluent guidelines
work. These data are therefore a good reflection of the metals
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD-CMDB data were carefully screened prior to inclusion in
the OCPSF database. These data were used in determining ITD
promulgated limits.
(3) In addition, the ITD-CMDB data have been challenged in court
and were upheld. These data therefore represent a reviewed and
accepted source of treatment performance data.
The BOAT for thallium is lime conditioning followed by sedimentation
and filtration (L+Sed+Fil) and using the ITD mean long term average and ITD-
CMDB variability factor, a BOAT treatment standard equal to the ITD 1-day
maximum limit was calculated as shown in Table 6-10. The BDAT treatment
standard for thallium is 1.4 ppra.
4-244
-------
TABLE 4-130
WASTEWATER TREATMENT PERFORMANCE DATA
FOR THALLIUM
DETECTION RANGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLDEHT
SIZE (ppb) CONCENTRATION
(ppb)
NJ0053511
SC0035947
OH0006939
PA0026964
OH0006912
PA0004839
HJ0053511
PA0025933
PA0027511
PA0023256
CT0001538
PA0011371
MA0001783
PA0008281
KA0001783
PA0008281
KA0001783
NJ0053511
MA0001783
PA0013765
PA0008281
PA0004839
PA0023256
PA0011371
KA0001783
KA0001783
HA0001783
MA0001783
NJ0000191
NY0177482
NY0177482
NY0201421
NY0000558
LA0065501
LA0066214
NO. OF
DATA
POINTS
4
13
9
20
9
1
1
1
11
27
10
19
2
1
2
1
2
1
2
11
1
2
14
1
1
1
5
1
1
42
3
3
6
15
AVERAGE
EFFLUENT RECOVERY REMOVAL
CONCENTRATION (1) (\)
(PPb)
0.055
386847.000
52.973
39.000
27.167
10.000
0.010
50.000
4.500
47.900
13.000
1.800
502.500
100.000
1000.000
100.000
1000.000
0.100
1000.000
10.600
100.000
25.000
191.600
1.000
1000.000
5.000
1000.000
403.000
10.000
10.000
9.790
16.670
13.300
55.000
61.022
REFERENCE
NPDES
NPDES
NPDES
NPDES
NPDES
WPDES
NPDES
HPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
HPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
4-245
-------
TABLE 4-130 (Continued)
WASTEWATER TREATMENT PERFORMANCE DATA
FOR THALLIUM
TECHNOLOGY
AL
AS
AS
AS
AS
AS
BT
BT
BT
BT
BT
BT
BT
BT+Fil
L+Sed
* L+Sed+Fll
Neut
Sed+COAG
DETECTION RANGE
TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCENTRATION
(PPb)
Ful
Ful
Ful
Ful
Ful
1 IB
IB
975B
IB
1 201B
Full IB
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu
Fu.
PA0008800
WI0024597
PA0026549
W0003620
PA0026786
PA0027031
LA0038245
IN0022829
WI0001040
SI0000311
0-100
0-100
0-100
0-100
0-100
0-100
NO. OF
DATA
POINTS
1
1
6
6
2
6 •
3
21
2
8
19
40
12
4
3
AVERAGE
EFFLUENT RECOVERY REMOVAL
CONCENTRATION (t) (*)
(PPb)
5.000
1.000
5.000
1.000
1.000
1.000
116.000
2.000
2.200
20.000
39.500
9.700
48.075
204.000
500.000
340.000
1.000
1667.000
50.00
75.00
89.00
0.00
0.00
0.00
REFERENCE
WERL
ViERL
«m
ViERL
*ERL
mi
NODES
NPDES
NPDES
NPDES
HPDES
NPDES
NPDES
NPDES
ITD-CMDB
ITD-OffiB *
NPDES
NPDES
Data used in developing proposed standard.
4-246
-------
Vanadium. The data available for vanadium were compiled from the
WERL and NPDES databases. These data are presented in Table 4-131.
Technologies for which data are available include AL, AS, BT, ChPt, and TF.
All of the data represent full-scale studies. The resulting effluent
concentrations ranged from 2.0 ppb to 190.0 ppb.
The proposed and promulgated BDAT standard was set using the ChPt
technology and an achievable effluent of 3.0 ppb. Chemical precipitation
(ChPt) was selected as BDAT since the ChPt data represent substantial
treatment by a full-scale demonstrated technology. In addition, ChPt data
showed the best percent removal and the highest influent concentrations.
The calculation of the resulting BDAT treatment standard for
vanadium (0.042 ppm) is described in Section 6.0 and is shown in Table 6-10.
4-247
-------
TABLE 4-131
WASTEWATER TREATMENT PERFORMANCE DATA
FOR VANADIUM
DETECTION RANGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCENTRATION
(ppb)
- MI0025135
VA0004103
VA0004103
HI0025135
AR0000523
NY0008231
NY0005908
NY0104213
NY0005932
NY0104213
NY0005711
NY0002186
NY0006262
NY0005908
NY0005932
NY0005711
NY0008010
NY0107522
NY0110043
NY0166456
NY0002186
LA0005347
NY0005941
NY0005959
NY0104213
CA0047953
CA0004961
CA0005096
CA0005789
TX0004669
TX0007072
TX0007072
TX0077593
NO. OF
DATA
POINTS
12
1
18
19
57
20
29
25
14
1
9
2
18
22
30
3
13
3
3
8
10
2
30
30
16
1
15
30
30
45
1
9
58
AVERAGE
EFFLUENT RECOVERY REMOVAL
CONCENTRATION (\) (!)
(PPb)
1366.700
200.000
200.000
17468.400
60947.400
1676.400
3591.400
324.000
13257.100
500.000
53.300
1766.000
538.500
444.100
2041.700
53.300
893.100
133.300
10.000
82.500
3227.000
300.000
2610.000
3002.900
319.400
20.000
108.311
70.000
1827.000
2046.890
1.000
55.000
583.450
REFERENCE
HPDES
NPDES
NPDES
NPDES
tfPDES
NPDES
KPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
KPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
4-248
-------
TABLE 4-131 (Continued)
WASTEWATEJ TREATMENT PERFORMANCE DATA
FOR VANADIUM
TECHNOLOGY
AL
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
BT
* ChPt
FLOAT
S
S
TF
DETECTION RANGE
TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCENTRATION
(ppb)
Fu
Fu
Fll
Fu
Fu
Fu
Fu
PlL
Fu
Fu.
Fu
Fu
Fu
FU
Fu
Fu
IB
IB
IB
IB
IB
IB
IB
201B
IB
IB
IB
CA0005053
24SB
1 CA0005550
1 KY0001899
1 LA0045233
Full IB
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
100-1000
100-1000
1000-10000
0-100
NO. OF
DATA
POINTS
4
6
4
5
4
5
4
24
4
6
6
32
1
31
13
23
6
AVERAGE
EFFLUENT RECOVERY REMOVAL
CONCENTRATION (t) (*)
(ppb)
5.000
6.000
10.000
2.000
11.000
3.000
29.000
4.000
2.000
130.000
190.000
191.000
3.000
370.000
9376.800
7378.000
9.000
38.00
50.00
23.00
82.00
21.00
25.00
59.00
43.00
75.00
7.00
10.00
99.72
0.00
REFERENCE
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
NPDES
WERL *
NPDES
NPDES
NPDES
WERL
Data used in developing proposed standard.
4-249
-------
Zinc. Several sources of wastewater treatment performance data were
available for zinc, including data from the ITD-CMDB, WERL, BOAT, and ITD-MF
databases. These data are presented in Table 4-132. Technologies for which
data are available include AL, AS, CAC, ChOx/Pt, ChPt, ChPt+Fil,
Chred/Pt+Sed+Fil, L+Sed, Pt+Sed, Sed+Fil, L+Sed+Fil, RBC, and TF. The
treatment performance data represent bench-, pilot-, and full-scale studies.
The treatment performance data available from the ITD-CMDB were used
for setting the proposed and promulgated BDAT standard for this constituent
for the following reasons:
(1) The ITD-CMDB represents industry wide treatment performance
data which were collected as part of ITD's effluent guidelines
work. These data are therefore a good reflection of the metals
industry and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD-CMDB data were carefully screened prior to inclusion in
the OCPSF database. These data were used in determining ITD
promulgated limits.
(3) In addition, the ITD-CMDB data have been challenged in court
and were upheld. These data therefore represent a reviewed and
accepted source of treatment performance data.
The BDAT for zinc is lime conditioning followed by sedimentation and
filtration (L+Sed+Fil) and using the ITD mean long term average and ITD-CMDB
variability factor, a BDAT treatment standard equal to the ITD 1-day maximum
limit was'calculated as shown in Table 6-10. The BDAT treatment standard for
zinc is 1.0 ppm.
4-250
-------
TABLE 4-132
WASTEWATER TREATHEHT PERFORMANCE DATA
FOR ZINC
TECHNOLOGY
AL
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
AS
TECHNOLOGY FACILITY
SIZE
Ful
Fa
Fu
Fu
Fu
Pa
Fu
Fa
Fu
Fa
Fu
Fa
Fu
Fa
Fa
Fa
Fu
Pa
Fu
Fa
Fu
Fa
Fa
Fa
Fu
Pu
Fa
Pa
Fa
Pa
Fa
Pa
Fa
Fa
Fa
Fa
Fa
Fa
Ful
1 IB
IB
IB
IB
234A
IB
IB
IB
167E
IB
IB
IB
IB
IB
IB
IB
IB
IB
IB
IB
167E
IB
IB
234A
IB
IB
IB
IB
198E
234A
IB
IB
243A
IB
IB
234A
243A
167E
1 IB
DETECTION RANGE
LIKIT INFLUENT
(ppb) CONCENTRATION
(PPb)
100-1000
1000-10000
1000-10000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
100-1000
1000-10000
1000-10000
100-1000
100-1000
100-1000
100-1000
100-1000
0-100
100-1000
100-1000
1000-10000
100-1000
100-1000
100-1000
100-1000
1000-10000
1000-10000
100-1000
1000-10000
100-1000
100-1000
100-1000
1000-10000
100-1000
100-1000
100-1000
NO. OF
DATA
POINTS
6
6
6
6
7
6
6
6
6
7
6
6
6
6
7
6
6
6
6
6
6
7
6
6
6
6
33
7
6
6
6
6
7
6
AVERAGE
EFFLUENT
CONCENTRATION
(PPb)
93.000
640.000
36.000
57.000
160.000
110.000
64.000
47.000
9.000
220.000
52.000
30.000
17.000
110.000
270.000
90.000
44.000
130.000
55.000
51.000
2.000
74.000
40.000
50.000
130.000
37.000
57.000
94.000
480.000
10.000
130.000
2600.000
99.000
200.000
90.000
30.000
42.000
34.000
73.000
RECOVERY REMOVAL
W W
90.00
84.00
98.70
64.00
62.00
82.00
64.00
79.00
97.80
55.00
81.00
87.00
84.00
92.70
83.00
65.00
84.00
84.00
84.00
81.00
94.10
78.00
67.00
96.90
66.00
79.00
86.00
81.00
74.00
99.25
44.00
64.00
79.00
75.00
89.00
97.20
85.00
95.10
65.00
REFERENCE
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
mi
WERL
WERL
WERL
WERL
WERL
WERL'
WERL
WERL
WERL
WERL
WERL
4-251
-------
TABLE 4-132 (Continued)
WASTEWATER TREATMENT PERFORMANCE DATA
FOR ZINC
TECHNOLOGY TECHNOLOGY FACILITY
SIZE
AS
AS
AS
AS
AS
AS
AS
AS
Ful
Ful
Ful
Fu
FU
Fu
Fu.
Ful
IB
234A
142A
167E
201B
IB
IB
IB
CAC Full 393A
CAC (
CAC
CAC
ChOx/Pt
ChOx/Pt
B Bench 638B
B Benc
B Benc
B) Benc
B Benc
CbPt ' Ful
ChPt (
chPt |
ChPt+Fil
Cnred/Pt+S
B) Pile
b 638B
1 638B
1 248A
I 248A
245B
254B
B Pjlot 254B
(B) Pilot 254B
«o>Fil Pull K062
L+Sed. Ful
* L+Sed+Fil Ful
Pt+Sed Ful
RBC
Fu
Sed+Fil Ful
TF
r
i1
T
T1
TF
TF
TF
TF
TF
TF
Fu
Fu
Fu
FU
Fu
Ftt
Fu
Fu
Fu
Fu
IB
IB
IB
IB
IB
IB
IB
IB
IB
IB
IB
Full IB
DETECTION RANGE
LIMIT INFLUENT
(ppb) CONCENTRATION
(PPb)
100-1000
0-100
100-1000
100-1000
100-1000
100-1000
100-1000
1000-10000
1000-10000
1000-10000
100-1000
100-1000
1000-10000
1000-10000
10000-100000
100-1000
1000-10000
1000-10000
400-171000
100-337000
100-337000
5 0-16500000
0-100
100-337000
100-1000
100-1000
100-1000
100-1000
100-1000
0-100
100-1000
100-1000
100-1000
0-100
100-1000
NO. OF
DATA
POINTS
6
7
14
35
6
6
6
1
1
1
1
16
17
17
11
34
6
6
6
6
6
6
6
6
6
6
6
6
AVERAGE
EFFLDENT RECOVERY
CONCENTRATION (1)
(PPb)
110.000
10.000
100.000
10.000
100.000
66.000
36.000
480.000
560.000
160.000
180.000
30.000
1200.000
1100.000
22.000
22.000
90.000
73.000
245.000
330.000
230.000
549.000
20.000
10.000
110.000
56.000
81.000
34.000
94.000
51.000
78.000
200.000
36.000
77.000
74.000
REMOVAL
W
81.00
75.00
75.00
94.10
72.00
74.00
90.30
90.20
62.00
97.00
55.00
90.90
84.00
79.00
99.93
96.70
91.90
93.40
80.00
42.00
73.00
32.00
87.00
72.00
42.00
66.00
50.00
74.00
16.00
38.00
REFERENCE
WERL
WERL
WERL
WERL
WERL
WERL
WERL
HERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
HERL
HERL
WERL
BOAT
ITD-CMDB
ITD-CMDB *
ITD-MF
WERL
ITD-CMDB
WERL
WERL
WERL
HERL
HEEL
WERL
UERL
WERL
WERL
WERL
WERL
Data used in developing proposed standard.
4-552
-------
4.5 Inorganics
Constituents discussed in this Section include:
Cyanide
Fluoride
Sulfide
The data presented in this Section and the standards based on these data apply
to multi-source leachate wastewaters only. Inorganic vastewater standards for
U and P wastecodes are identified in separate background documents.
4-253
-------
Cyanide. The data available for cyanide were compiled from the
BDAT, WERL, and ITD databases. These data are presented in Table 4-133.
Technologies for which data are available include AL, AS, ChOx(Cl), ChOX/Pt,
RBC, SS, TF, WOx, LL+SS, LL+SS+AC, L+Sed, L+Sed+Fil, and cyanide oxidation
(CN/OX). The treatment performance data represent bench-, pilot-, and full-
scale studies. The resulting effluent concentrations ranged from 5.0 ppb to
39,000 ppb.
The proposed and promulgated BDAT standard was set using the CN/OX
technology and an achievable effluent of 180.0 ppb. CN/OX was selected as
BDAT since this technology represents full-scale ITD data collected for the
metal finishing database as well as the fact that this full-scale demonstrated
treatment technology shows substantial treatment.
Data from the ITD Metal finishing database were chosen in preference
to the ITD-CMDB data since cyanide requires oxidation for treatment to occur.
Lime conditioning followed by sedimentation and filtration (L+Sed+Fil) data
from the ITD-CMDB are not expected to actually represent treatment of cyanide
but rather dilution. Therefore, the metal finishing data were used to
calculate the cyanide BDAT treatment standard.
The resulting BDAT treatment standard for cyanide is 1.2 ppm as
shown in Table 6-10.
4-254
-------
TABLE 4-133
WASTEWATER TREATMENT PERFORMANCE DATA
FOR CYANIDE
TECHNOLOGY TECHNOLOGY FACILITY
SIZE
AL Full IB
AS Full IB
AS Full IB
AS Full IB
AS Fu
AS F\i
AS Fu
AS Fu.
AS Fu
AS Fu.
AS Fu
AS Fu:
AS Fu
AS Fu.
AS Fu
AS Fa
AS Fu
AS FU
AS Fu
AS Fu
AS Fu
AS Fu.
IB
IB
IB
201B
IB
167E
IB
IB
IB
IB
IB
IB
160A
IB
167E
IB
IB
IB
AS Full 201B
AS Fu
AS Fu
AS Fu
AS Fu
AS Fu
AS Fill
167E
IB
167E
IB
IB
160A
DETECTION RANGE
LIMIT INFLUENT
(ppb) CONCENTRATION
(PPb)
0-100
100-1000
100-1000
100-1000
100-1000
100-1000
0-100
0-100
100-1000
0-100
0-100
100-1000
100-1000
100-1000
1000-10000
0-100
100-1000
1000-10000
100-1000
0-100
100-1000
0-100
1000-10000
100-1000
100-1000
100-1000
1000-10000
0-100
0-100
NO. OF
DATA
POINTS
6
6
6
6
6
6
6
28
6
6
6
6
6
6
6
60
6
6
6
7
6
6
6
6
60
AVERAGE
EFFLUENT RECOVERY
CONCENTRATION (1)
(ppb)
10.000
10.000
160.000
65.000
320.000
150.000
27.000
90.000
54.000
19.000
5.000
47.000
110.000
110.000
110.000
24.000
79.000
130.000
20.000
41.000
370.000
6.000
110.000
22.000
250.000
110.000
240.000
7.000
8.000
REMOVAL
W
88
91.7
53
59
29
70
67
0
79
44
58
88
59
35
97.7
35
55
91.9
88
42
58
65
97.7
80
65
64
80
75
91
REFERENCE
WERL
HERL
KEEL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL '
HERL
WESL
WERL
WERL
WERL
WERL
WERL
HERL
4-255
-------
TABLE 4-133 (Continued) .
WASTEWATER TREATMENT PERFORMANCE DATA
FOR CYANIDE
TECHNOLOGY
AS
AS
AS
ChOx(Cl)
ChOx/Pt (B)
ChOx/Pt (B)
* CN/Ox
LL-SS
LL^SSrAC
L+Sed
LrSedi-Fil
RBC
SS
TF
TF
TF
TF
TF
TF
HOx
WOX (B)
WO* B
TECHNOLOGY FACILITY
SIZE
Full IB
Full IB
Full IB
Pilot 1077B
Benc
Benc
Fu
Ft
Fu,
Fu
Fu
Fu
Pilo
FU
Fu
Fu
Fu
Fu
Fu
h 248A
248A
K103/K104
K103/K104
IB
: 1082E
IB
IB
IB
IB
IB
IB
Pilot 78D
Bench 1054E
Bench 1054E
DETECTION RANGE
LIMIT INFLDENT
(ppb) CONCENTRATION
(PPb)
1000-10000
100-1000
1000-10000
10000-100000
> 1000000
>1000000
5-20 45-1680000
10-6280
10-6280
120-3280
120-3280
1000-10000
10000-100000
100-1000
100-1000
100-1000
100-1000
0-100
0-100
100000-1000000
10000-100000
>1000000
NO. OF AVERAGE
DATA EFFLUENT RECOVERY
POINTS CONCENTRATION (1)
(PPb)
6
6
6
20
1
1
1529
5
4
6
6
6
6
6
6
6
220.000
87.000
380.000
6700.000
1000.000
100.000
180.00
2960.000 72
362.000 72
70.00
47.00
84.000
39000.000
130.000
47.000
310.000
110.000
17.000
53.000
6000.000
1200.000
170.000
REMOVAL
(*)
90
64
71
92.4
100
100
95.8
38
65
74
56
59
39
36
98
98.7
100
REFERENCE
WERL
WERL
WERL
WERL
WERL
WERL
ITD-MF *
BOAT
BOAT
ITD-CMDB
ITD-CKDB
WERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
HERL
* Data used in developing proposed standard.
4-256
-------
Fluoride. The data available for fluoride were compiled from the
BDAT, WERL, and ITD databases. These data are presented in Table 4-134.
Technologies for which data are available include AAS, ChPt, RO, L+Sed,
LL+SS+AC, and L+Sed+Fil. The treatment performance data represent bench-,
pilot-, and full-scale data. The resulting effluent concentrations ranged
from 200 ppb to 14,500 ppb.
The treatment performance data available from the ITD-CMDB were used
for setting the proposed and promulgated BDAT standard for this constituent
for the following reasons:
(1) The ITD-CMDB represents industry wide treatment performance
data which were collected as part of ITD's effluent guidelines
work. These data are therefore a good reflection of industry
and can adequately represent a wastewater of unknown
characteristics.
(2) The ITD-CMDB data were carefully screened prior to inclusion in
that database. These data were used in determining ITD
promulgated limits.
(3) In addition, the ITD-CMDB data have been challenged in court
and were upheld. These data therefore represent a reviewed and
accepted source of treatment performance data.
The BDAT for fluoride is lime conditioning followed by sedimentation
(L+Sed). L+Sed+Fil data were also available from the ITD-CMDB for fluoride.
However, based on the average effluent concentrations, L+Sed provided
equivalent treatment to L+Sed+Fil. Using the ITD mean long term average and
ITD-CMDB variability factor, a BDAT treatment standard equal to the ITD 1-day
maximum limit was calculated as shown in Table 6-10. The BDAT treatment
standard for fluoride is 35 ppm.
4-257
-------
TABLE 4-134
WASTEWATER TREATMENT PERFORMAHCE DATA
FOR FLUORIDE
DETECTION RANGE MO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLDEHT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (I) (*)
(ppb) (ppb)
AAS
AAS
ChPt (B)
* L+Sed
L+Sed+Fil
LL+SS+AC
RO
RO
RO
Full
Full
Bench
Full
Full
Full
Pilot
Full
Full
1264B
1264B
1313E
K103/K104
180A
1264B
1264B
10000-100000
1000-10000
1000-10000
200 4
100-1000 16
1000-10000
1000-10000
200.000
200.000
300.000
14500.000
14500.000
462.000
210.000
600.000
600.000
98.8
95.2
92.5
74
86
86
mi
WERL
WERL
ITD-CMDB *
ITD-CMDB
BOAT
WERL
WERL
WERL
Data used in developing proposed standard.
4-258
-------
Sulfide. The data available for sulfide were compiled from the BOAT
and WERL databases. These data are presented in Table 4-135. Technologies
for which data are available include ChOx(Cl), SS, LL+SS, and LL+SS+AC. The
treatment performance data represent pilot- and full-scale data. The
resulting effluent concentrations ranged from 600 ppb to 8,000 ppb.
The proposed and promulgated BDAT standard was set using liquid,
liquid extraction followed by steam stripping (LL+SS) technology and an
achievable effluent of 1,000 ppb. LL+SS was selected as BDAT since this
technology was tested as part of a BDAT treatment test on K103/K104 and shows
substantial treatment on a full scale level. LL+SS+AC data were also
available from the BDAT test. However, based .on the average effluent
concentrations, LL+SS provided equivalent treatment to LL+SS+AC.
The resulting BDAT treatment standard for sulfide is 14 ppm as shown
in Table 6-10.
TABLE 4-135
WASTEWATER TREATMENT PERFORMANCE DATA
FOP, SCLFIDE
TECHNOLOGY
ChOx(Cl)
* LL+SS
ssr
TECHNOLOGY
SIZE
Pilot
Pilot
FACILITY
1077B
K103/K104
K103/K104
1082E
DETECTION RANGE
LIMIT INFLDENT
(ppb) CONCENTRATION
(PPb)
10000-100000
1000-89000
1000-89000
100000-1000000
NO. OF
DATA
POINTS
15
5
4
AVERAGE
EFFLUENT RECOVERY
CONCENTRATION (?)
(PPb)
600.000
1000.000
1000.000
8000.000
REMOVAL
(*)
97.5
97.3
REFERENCE
WERL
BDAT *
BDAT
MEKL
Data used in developing proposed standard.
4-259
-------
4.6 Organochlorine Pesticides
Constituents discussed in this section include:
Aldrin
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC
Chlordane
p,p'-and o,p'-DDD
p,p'-and o,p'-DDE
p,p'-and o,p'-DDT
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxide
Isodrin
Kepone
Methoxychlor
Toxaphene
4-260
-------
Aldrin (POOA). The data available for aldrin were compiled from the
NPDES database and are presented in Table 4-136. The technology for which
data were available was full-scale BT. The resulting effluent concentration
was 1.4919 ppb.
BDAT for aldrin is being promulgated as proposed and is identified
as biological treatment (BT). Biological treatment was selected as BDAT since
it represents full-scale data and the only technology for which the Agency has
data. The BDAT treatment standard for aldrin was calculated using the
effluent concentration of 1.4919 ppb and the appropriate variability factor
and accuracy correction factor. The calculation of the resulting BDAT
treatment standard for aldrin (0.021 ppm) is described in Section 6.0 and is
shown in Table 6-10.
TABLE 4-136
WASTEWATER TREATMENT PERFORMANCE DATA
FOR ALDRIN
DETECTION RANGE NO. OP AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIHIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (t) (t)
_____(PPb)(ppb)______
LA0066214 15 1.0000 NPDES
LA0065501 6 0.3500 NPDES
* BT Pull LA0038245 43 1.4919 NPDES *
* Data used in developing proposed standard.
4-261
-------
alpha-BHC (U129). The data available for alpha-BHC were compiled
from the NPDES and WERL databases and are presented in Table 4-137.
Technologies for which data are available include full-scale AS, BT, and GAC.
The resulting effluent concentrations ranged from 0.010 ppb to 1.6053 ppb.
BDAT for alpha-BHC is being promulgated as proposed and is
identified as carbon adsorption. Granular activated carbon (GAC) was selected
as BDAT since it represents full-scale data with a high influent concentration
and a high removal efficiency. The BDAT treatment standard for alpha-BHC was
calculated using the effluent concentration of 0.01 ppb and the appropriate
variability factor and accuracy correction factor. The calculation of the
resulting BDAT treatment standard for alpha-BHC (0.00014 ppm) is described in
Section 6.0 and is shown in Table 6-10.
TABLE 4-137
WASTEHATE8 TREATHEHT PERFOHUBCE DATA
POI ALPBA-BHC
DETECTION RANGE ~~~~NO. OF AVE1AGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLOENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (I) (I)
(ppb) (ppb)
AS
AS
BT
BT
* GAC
Full
Fui:
M
LA0066214
LA0065501
L 375E
201B
LA0038245
PA0026689
L 237A
0-100
0-100
100-1000
15
6
1
38
1
1.0000
0.3500
0.0200
1.0000
1.6053
0.5000
0.0100
67
77
99.99
NPDES
NPDES
WERL
WERL
NPDES
NPDES
ma *
Data used in developing proposed standard.
4-262
-------
beta-BHC (U129). The data available for beta-BHC were compiled from
the NPDES and WERL databases and are presented in Table 4-138. Technologies
for which data are available include full-scale AS, BT, and GAC. The
resulting effluent concentrations ranged from 0.010 ppb to 16.7 ppb.
BOAT for beta-BHC is being promulgated as proposed and is identified
as carbon adsorption. Granular activated carbon (GAC) was selected as BDAT
since it represents full-scale data with a high influent concentration and a
high removal efficiency. The BDAT treatment standard for beta-BHC was
calculated using the effluent concentration of 0.01 ppb and the appropriate
variability factor and accuracy correction factor. The calculation of the
resulting BDAT treatment standard for beta-BHC (0.00014 ppm) is described in
Section 6.0 and is shown in Table 6-10.
TABLE 4-138
HASTEWATER TREATMENT PERFORMANCE DATA
FOi BETA-BHC
TECHNOLOGY
AS
BT
* GAC
TECHNOLOGY
SIZE
Full
Full
Full
FACILITY
LA0065501
LA0058882
LA0058882
375E
LA0038245
237A
DETECTION
LIMIT
(ppb)
RANGE
INFLUENT
CONCENTRATION
(Ppb)
0-100
100-1000
NO. OF
DATA
POINTS
6
32
33
7
38
AVERAGE
EFFLOENT
CONCENTRATION
(ppb)
0.4000
15.0000
16.7000
0.0200
1.6053
0.0100
RECOVERY REMOVAL
(*) (*)
71
99.99
REFERENCE
NPDES
NPDES
NPDES
WERL
NPDES
WERL *
Data used in developing proposed standard.
4-263
-------
delta-BHC (U129). The data available for delta-BHC were compiled
from the NPDES database and are presented in Table 4-139. The technology for
which data were available was full-scale BT. The resulting effluent
concentrations of all the data documented ranged from 0.35 ppb to 15.3 ppb.
BOAT for delta-BHC is being promulgated as proposed and is
identified as biological treatment (BT). Biological treatment was selected as
BDAT since it represents full-scale treatment performance data and is the only
demonstrated technology for which the Agency has data. The BDAT treatment
standard for delta-BHC was calculated using the effluent concentration of
1.6316 ppb and the appropriate variability factor and accuracy correction
factor. The calculation of the resulting BDAT treatment standard for delta-
BHC (0.023 ppm) is described in Section 6.0 and is shown in Table 6-10.
TABLE 4-139
WASTEWATER TREATMENT PERFORHABCE DATA
FOB DELTA-BHC
TECHNOLOGY
* BT
TECHNOLOGY
SIZE
Full
FACILITY
LA0058882
LA0065501
LA0058882
LA0038245
DETECTION
LIHIT
(PPb)
RANGE
INFLUENT
CONCENTRATION
(PPb)
NO. OF
DATA
POINTS
32
6
33
38
AVERAGE
EFFLUENT
CONCENTRATION
(PPb)
15.0000
0.3500
15.3000
1.6316
RECOVERY
(*)
REMOVAL
(*)
REFERENCE
NPDES
NPDES
NPDES
NPDES *
Data used in developing proposed standard.
4-264
-------
(U129). The data available for gamma-BHC were compiled
from the NPDES and WERL databases and are presented in Table 4-140.
Technologies for which data are available include AL, AS, BT, CAC, GAG, PACTR,
and TF. The treatment performance data represent bench-, pilot-, and full-
scale studies. The resulting effluent concentrations ranged from 0.006 ppb to
99 ppb.
BDAT for gamma-BHC is being promulgated as proposed and is
identified as carbon adsorption. Granular activated carbon (GAG) was selected
as BDAT since it represents full-scale data with a high influent concentration
and a high removal efficiency. The BDAT treatment standard for gamma-BHC was
calculated using the effluent concentration of 0.12 ppb and the appropriate
variability factor and accuracy correction factor. The calculation of the
resulting BDAT treatment standard for gamma-BHC (0.0017 ppm) is described in
Section 6.0 and is shown in Table 6-10.
TABLE 4-140
HASTBWATER TREATMENT PERFOKHABCE DATA
FOX GAMRA-BHC
TECHHOLOGY
AL
AL
AS
AS
AS
AS
AS
AS
AS
AS
AS
BT
CAC
* GAC
PACT
TF
TF
TF
TF
TECHHOLOGY
SIZE
Pilot
Full
Full
Pilot
Pilot
Full
Pilot
Bench
Full
Full
Full
Pilot
Full
Bench
B
Pilot
FACILITY
203A
203A
375E
375E
240A
203A
375E
204A
200B
375E
201B
PA0026247
203A
237A
200B
375E
375E
240A
203A
DETECTION RANGE
LIMIT IHFLOEHT
(ppb) CONCENTRATION
(ppb)
0-100
0-100
0-100
0-100
0-100
0-100
0-100
0-100
100-1000
0-100
0-100
0-100
100-1000
100-1000
0-100
0-100
0-100
0-100
NO. OF
DATA
POINTS <
11
11
7
7
11
11
7
8
13
7
2
21
11
1
17
7
7
10
11
AVERAGE
EFFLDEHT RECOVERY
30NCENTRATION (!)
7.0000
22.0000
0.1100
0.0700
27.0000
31.0000
0.0210
26.0000
99.0000
0.0600
1.0000
0.0061
32.0000
0.1200
8.0000
0.0600
0.1100
37.0000
34.0000
REMOVAL
82
44
39
36
59
20
81
44
8.3
88
66
18
99.97
92.1
14
58
46
13
REFERENCE
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
WERL
NPDES
XERL
WERL *
WERL
WERL
HERL
WERL
WERL
Data used in developing proposed standard.
4-265
-------
TABLE 4-141
WASTEWATER TREATMENT PERFORMANCE DATA
FOR CBLORDANE
TECHNOLOGY
* BT
* BT
* BT
* BT
BT
BT
BT
BT
BT
BT
* BT
* BT
* BT
Chred
. DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY FACILITY LIMIT INFLDEHT DATA EFFLDENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (t) (I)
(ppb) (ppb)
Full
Full
Full
Full
Full
Full
Full
fill
Full
Full
Pilot
CA0107611
CA004S216
CA0037681
CA0037681
OH0058874
LA0058882
LA0065501
LA0058882
PA0026531
CA0038598
CA0048194
CA0107417
CA0108031
LA0038245
CA0107395
CA0048160
TH0020711
CA0037737
CA0048143
CA0047996
CA0037494
CA00478S1
CA0047364
CA0022756
CA0110604
5
13
29
33
6
32
29
5
5
6
1
38
5
22
4
2
1
2
3
1
9
30 6
0.1000
132.0000
0.1000
0.1000
0.0200
15.9000
0.5000
15.6000
483.4500
0.1000
0.3420
0.0802
0.0100
1.6500
0.2360
0.0100
0.0400
0.0500
0.1600
0.0500
0.1250
0.0500
0.0502
0.5000
0.1000
0.1000
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
HPDES *
NPDES *
NPDES *
NPD
NPD
NPD
NPD
NPD
NPD
NPD
HPD
ES *
!S
IS
$
IS
s
:s
ES
NPDES
HPDES
AW
* Data used in developing proposed standard.
4-267
-------
p.p'- and o.pr- DDD (U060). The data available for DDD were
compiled from the NPDES database and are presented in Table 4-142. The
technology for which data were available was full-scale BT. The resulting
effluent concentrations of all the data documented ranged from 1.0 ppb to
1.6238 ppb.
BDAT for p,p'- and o,p'-DDD is being promulgated as proposed and is
identified as biological treatment (BT). Biological treatment was selected as
BDAT since it represents full-scale data and was the only technology for which
the Agency had data. The BDAT treatment standard for p,p-' and o,p'-DDD was
calculated using the effluent concentration of 1.6238 ppb and the appropriate
variability factor and accuracy correction factor. The calculation of the
resulting BDAT treatment standard for p,p'- and o,p'-DDD (0.023 ppm) is
described in Section 6.0 and is shown in Table 6-10.
TABLE 4-142
WASTEWATER TREATMENT PERFORMANCE DATA
FOR DDD
DETECTION RAHCE HO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIKIT INFLOENT DATA EFFLUENT RECOVERY REHOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (?) (t)
_(PPb)(ppb)_
HY0000345~~~ " " 2 1.0000 NPDES
LA0065501 6 1.0000 NPDES
LA0066214 15 1.0000 NPDES
* BT Full LA0038245 42 1.6238 NPDES *
Data used in developing proposed standard.
4-268
-------
p.p'- and o.p'- DDE (U061). The data available for DDE were
compiled from the NPDES and WERL databases and are presented in Table 4-143.
The technology for which data were available was full-scale BT. The resulting
effluent concentrations for all data documented ranged from 0.016 ppb to
2.229 ppb.
BDAT for p,p'- and o,p'-DDE is being promulgated as proposed and is
identified as biological treatment (BT). Biological treatment was selected as
BDAT since it represents full-scale treatment by a demonstrated technology.
Although Sed data were also available, this technology alone is not considered
applicable for the treatment of organics since it does not reduce or destroy
the overall levels of organics and, therefore, Sed was not considered for
BDAT. The BDAT treatment standard for p,p'- and o,p'-DDE was calculated using
the effluent concentration of 2.229 ppb and the appropriate variability factor
and accuracy correction factor. The calculation of the resulting BDAT
treatment standard for p,p'- and o,p'-DDE (0.031 ppm) is described in Section
6.0 and is shown in Table 6-10.
TABLE 4-143
WASTEWATER TREATMENT PERPORHAHCE DATA
FOR DDE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT Jgg^ ^ co^ION "jjf
NY0000345
LA0066214
LA0065501
* BT Full LA0038245
Sed Full 981E
2
1
38
0-100 4
1.0000
1.0000
1.0000
2.2290
0.0160
ERY REMOVAL REFERENCE
(•)
NPDES
NPDES
NPDES
NPDES *
33 WERL
* Data used in developing proposed standard.
4-269
-------
p.p'- and o.p'- DDT (U061). The data available for DDT were
compiled from the NPDES database and are presented in Table 4-144.
Technologies for which data are available include full-scale BT and chemical
conditioning followed by biological treatment (Chem/Cond + BT). The resulting
effluent concentrations ranged from 0.0003 ppb to 102.0 ppb with a detection
limit for DDT established at 0.012 ppb (see Table C-l, Appendix C).
BOAT for p,p'- and o,p'-DDT is being promulgated as proposed and is
identified as biological treatment (BT). Biological treatment was selected as
BOAT since it represents full-scale data. Chemical conditioning followed by
biological treatment (chem/cond+BT) data were also available from the NPDES
database for DDT. However, based on the average effluent concentrations,
biological treatment alone provided equivalent treatment to chem/cond+BT. The
BDAT treatment standard for p,p'- and o,p'-DDT was calculated using an
effluent concentration of 0.28 ppb (which represents the average of all BT
effluent values; a value below the detection limit was set at the detection
limit) and the appropriate variability factor and accuracy correction factor.
The calculation of the resulting BDAT treatment standard for p,p'- and o,p'-
DDT (0.0039 ppm) is described in Section 6.0 and is shown in Table 6-10.
4-270
-------
TABLE 4-144
WASTEWATER TREATMENT PERFORMANCE DATA
FOP DDT
TECHNOLOGY
* BT
BT
BT
BT
BT
BT
BT
BT
BT
BT
Chen/Cond+BT
. DETECTION RANGE
TECHNOLOGY FACILITY LIMIT INFLUENT
SIZE (ppb) CONCENTRATION
(ppb)
CA0037681
CA0038598
CA0048003
CA0048194
CA0037681
CA0107417
CA0107611
NY0000345
LA0065501
LA0066214
CA0048216
Full CA0047364
Full CA0110604
Full LA0038245
Full CA0022756
Full CA0037494
Full CA0108031
Full CA0037737
Full CA0048143
Full CA0047996
Full CA0047881
Full WI0003077
NO. OF
DATA
POINTS
29
5
1
5
13
6
1
2
6
15
5
3
9
37
1
I
3
1
1
AVERAGE
EFFLUENT
CONCENTRATION
(PPb)
0.1500
0.0480
0.2000
0.2440
0.0750
0.0802
0.0400
1.0000
1.0000
1.0000
102.0000
0.0201
0.0500
1.5351
0.5000
0.0375
0.0003
m
0.0500
0.5000
0.0600
RECOVERY REMOVAL REFERENCE
(*) W
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES *
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES *
KPDES
* Data used in developing proposed standard.
4-271
-------
Dieldrin (P037). The data available for dieldrin were compiled from
the NPDES and WERL databases and are presented in Table 4-145. Technologies
for which data are available include pilot-scale AS, and full-scale BT. The
resulting effluent concentrations ranged from 0.01 ppb to 95 ppb.
BDAT for dieldrin is being promulgated as proposed and is identified
as biological treatment (BT). Biological treatment was selected as BDAT since
it represents full-scale data and achieves a lower effluent concentration than
the other data documented. The BDAT treatment standard for dieldrin was
calculated using an effluent concentration of 1.198 ppb (which represents an
average of the two full-scale BT data points) and the appropriate variability
factor and accuracy correction factor. The calculation of the resulting BDAT
treatment standard for dieldrin (0.017 ppm) is described in Section 6.0 and is
shown in Table 6-10.
TABLE 4-145
WASTEWATER TREATMENT PERFORMANCE DATA
FOR DIELDRIN
TECHNOLOGY
AS
* BT
* BT
Sed
TECHNOLOGY
SIZE
Pilot
RU
Full
DETECTION
FACILITY LIMIT
[ppb)
AR0037800
LA0058882
LA0065501
AR0037800
LA0058882
AR0037800
AR0037800
AR0037800
241B
LA0038245
PA0026247
981E
RANGE
IHFLOEHT
CONCENTRATION
(PPb)
100-1000
0-100
NO. OF
DATA
POINTS
46
32
6
31
33
39
3
44
10
38
25
5
AVERAGE
EFFLDEHT RECOVERY
CONCENTRATION (1)
(PPb)
10.0000
15.2000
0.1000
0.3352
15.5000
0.0100
0.0100
0.0100
95.0000
1.5500
0.8460
0.0160
REMOVAL
(*)
86
48
REFERENCE
NPDES
NPDES
NPDES
NPDES
HPDES
NPDES
NPDES
NPDES
WERL
NPDES *
HPDES *
MEBL
Data used in developing proposed standard.
4-272
-------
Endosulfan I (P050). The data available for endosulfan I were
compiled from the NPDES database and are presented in Table 4-146. The
technology for which data were available was full-scale BT. The resulting
effluent concentrations of all the data documented ranged from 0.5 ppb to
1.71 ppb.
BDAT for endosulfan 1 is being promulgated as proposed and is
identified as biological treatment (BT). Biological treatment was selected as
BDAT since it represents full-scale data and is the only demonstrated
technology for which the Agency has data. The BDAT treatment standard for
endosulfan I was calculated using the effluent concentration of 1.6711 ppb and
the appropriate variability factor and accuracy correction factor. The
calculation of the resulting BDAT treatment standard for endosulfan 1
(0.023 ppm) is described in Section 6.0 and is shown in Table 6-10.
WASTEWATER TREATMENT PERFORMANCE DATA
FOR ENDOSDLFAK I
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLDEHT DATA EFFLDENT RECOVERY
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (I)
(ppb) (ppb)
LA0065501
NY0000345
NY0003336
LA0066214
* BT Full LA0038245
6
2
15
38
1.7100
1.0000
0.0500
1.0000
1.6711
REMOVAL REFERENCE
W
NPDES
NPDES
NPDES
NPDES
NPDES *
Data used in developing proposed standard.
4-273
-------
Endosulfan Sulfate (P050). No wastewater treatment performance data
were available for endosulfan sulfate from any of the examined sources.
Treatment performance data were therefore transferred to this constituent from
a constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
a U or P code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
Endosulfan sulfate is in treatability group III.A.2.c.(3)(a) and the
constituent used to transfer treatment performance data from was
endosulfan II. The treatment performance data for endosulfan II is presented
in Table 4-147. Using a transfer from this constituent results in a BDAT for
endosulfan sulfate of biological treatment and a BDAT treatment standard of
0.029 ppm as described in Section 6.0 and shown in Table 6-10.
4-275
-------
Endrin (P051). The data available for endrin were compiled from the
NPDES database and are presented in Table 4-148. The technology for which
data were available was full-scale BT. The resulting effluent concentrations
ranged from 0.0003 ppb to 94 ppb with a detection limit for endrin established
at 0.006 ppb (see Table C-l, Appendix C).
BDAT for endrin is being promulgated as proposed and is identified
as biological treatment (BT). Biological treatment was selected as BDAT since
it represents full-scale data and is the only demonstrated technology for
which the Agency has data. The BDAT treatment standard for endrin was
calculated using an effluent concentration of 0.1992 ppb (which represents the
average of all BT effluent values; a value below the detection limit was set
at the detection limit) and the appropriate variability factor and accuracy
correction factor. The calculation of the resulting BDAT treatment standard
for endrin (0.0028 ppm) is described in Section 6.0 and is shown in
Table 6-10.
4-276
-------
Endrin Aldehyde (P051). The data available for endrin aldehyde were
compiled from the NPDES database and are presented in Table 4-149. The
technology for which data were available was full-scale BT. The resulting
effluent concentrations of all the data documented ranged from 1.0 ppb to
1.8054 ppb.
BOAT for endrin aldehyde is being promulgated as proposed and is
identified as biological treatment (BT). Biological treatment was selected as
BOAT since it represents full-scale data and is the only demonstrated
technology for which the Agency had data. The BDAT treatment standard for
endrin aldehyde was calculated using the effluent concentration of 1.8054 ppb
and the appropriate variability factor and accuracy correction factor. The
calculation of the resulting BDAT treatment standard for endrin aldehyde
(0.025 ppm) is described in Section 6.0 and is shown in Table 6-10.
TABLE 4-149
WASTEWATER TREATKENT PERPORHAHCE DATA
FOP ENDRIN ALDEHYDE
DETECTION RANGE HO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIHIT INFLCENT DATA EPFLDEHT RECOVERY REHOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (I) (t)
(ppb) (ppb)
LA0066214 15 1.0000 NPDES
LA0065501 6 1.7200 NPDES
* BT Full LA0038245 37 1.8054 NPDES *
Data used in developing proposed standard.
4-278
-------
Heptachlor (P059). The data available for heptachlor were compiled
from the NPDES and WERL databases and are presented in Table 4-150.
Technologies for which data are available include AL, AS, BT, CAC, GAG, and
TF. The treatment performance data represents pilot- and full-scale studies.
The resulting effluent concentrations ranged from 0.01 ppb to 26 ppb with a
detection limit for heptachlor established at 0.083 ppb (see Table C-l,
Appendix C).
BDAT for heptachlor is being promulgated as proposed and is
identified as carbon adsorption. Granular activated carbon (GAG) was selected
as BDAT since it represents full-scale data with a high influent concentration
and a high removal efficiency. The BDAT treatment standard for heptachlor was
calculated using an effluent concentration of 0.083 ppb (which represents the
detection limit) and the appropriate variability factor and accuracy
correction factor. The calculation of the resulting BDAT treatment standard
for heptachlor (0.0012 ppm) is described in Section 6.0 and is shown in
Table 6-10.
TABLE 4-150
WASTEWATER TREATMENT PERFOfiHAKE DATA
FOR HEPTACHLOR
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY - LIHIT INFLDENT DATA EFFLDENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (*) (I)
(ppb) (ppb)
AL
AL
AS
AS
AS
BT
BT
CAC
* GAC
TF
TF
Pilot
Pilot
Pilot
Pilot
Full
Full
Pilot
Full
p)lot
Pilot
LA0058882
LA0058882
LA0065501
PA0026531
FL0021661
203A
203A
240A
203A
204A
LA0038245
PA0026247
203A
237A
203A
240A
0-100
0-100
0-100
0-100
0-100
0-100
100-1000
0-100
0-100
33
32
29
3
11
11
13
11
8
39
25
11
1
11
12
15
15
0
22
0
13
13
25
13
2
1
0
14
0
18
26
.3000
.0000
.1000
.4140
.0430
.0000
.0000
.0000
.0000
.3000
.7590
.8470
.0000
.0100
.0000
.0000
67
67
68
67
92.8
64
99.99
54
67
NPDES
NPDES
NPDES
NPDES
NPDES
WERL
WERL
WERL '
WERL
WERL
HPDES
NPDES
WERL
WERL *
WERL
WERL
* Data used in developing proposed standard.
4-279
-------
Heptachlor Enoxide (P059). The data available for heptachlor
epoxide were compiled from the NPDES database and are presented in
Table 4-151A. The technology for which data were available was full-scale BT.
The effluent concentrations of all the data presented ranged from 0.1 ppb to
16.5 ppb.
BDAT for heptachlor epoxide is being promulgated as proposed and is
identified as biological treatment (BT). Biological treatment was selected as
BDAT since it represents full-scale data and is the only demonstrated
technology for which the Agency has data. The BDAT treatment standard for
heptachlor epoxide was calculated using the effluent concentration of 1.1449
ppb and the appropriate variability factor and accuracy correction factor.
The calculation of the resulting BDAT treatment standard for heptachlor
epoxide (0.016 ppm) is described in Section 6.0 and is shown in Table 6-10.
TABLE 4-151A
WASTEWATER TREATMENT PERFORMANCE DATA
FOB HEPTACHLOR EPOXIDE
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLDENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (!) (I)
''
LA0065501 6 0.1000 HPDES
LA0058882 32 15.9000 NPDES
LA0058882 33 16.5000 NPDES
* BT Full LA0038245 39 1.1449 NPDES *
* Data used in developing proposed standard.
4-280
-------
Keoone (D142). No wastewater treatment performance data were
available at proposal for kepone from any of the examined sources. Treatment
performance data were therefore transferred to this constituent from a similar
compound. The Agency received industry-submitted leachate treatment
performance data just prior to proposal. The leachate data for kepone are
presented in Table 4-151B.
At proposal, BOAT for kepone was identified as biological treatment
and the treatment standard was based on an effluent concentration of 0.678 ppb
from a transfer of toxaphene treatment performance data. Between proposal and
promulgation, EPA evaluated the industry-submitted leachate data available for
kepone. Since this data for biological treatment (BT) showed substantial
treatment of kepone, these data were used to calculate the promulgated
standard. Therefore, BOAT for kepone is biological treatment.
The BDAT treatment standard for kepone was calculated using the
effluent concentration of 0.317 ppb and the appropriate variability factor and
accuracy correction factor. The calculation of the resulting BDAT treatment
standard for kepone (0.0011 ppm) is described in Section 6.0 and is shown in
Table 6-10.
TABLE 4-151B
aDOSTRY-SUBKITTED LEACHATE TREATMENT PERFOR8ABCE
DATA FOE KEPONE
DETECTION RABGE HO. OF
TECHNOLOGY TECHNOLOGY FACILITY LIKIT IFFLDENT DATA
SIZE (ppb) CONCENTRATIOH POINTS
(ppb)
AVERAGE
EFFLDENT RECOVERY REMOVAL REFERENCE
"UTRATIOH (I) (*)
(ppb)
BT
B
CWH
-70.7
3
0.3170
99.55 LEACHATE
4-282
-------
Methoxvclor (U247). The data available for methoxyclor were
compiled from the WERL and NPDES databases and are presented in Table 4-152.
Technologies for which data are available include full-scale BT and WOx. The
resulting effluent concentrations ranged from 0.01 ppb to 53.652 ppb.
BOAT for methoxychlor is being promulgated as proposed and is
identified as wet air oxidation (WOx). Vet air oxidation was selected as BDAT
since it represents a full-scale demonstrated technology with substantial
treatment for methoxyclor. In addition, the wet air oxidation data showed a
high influent concentration. The BDAT treatment standard for methoxyclor was
calculated using the effluent concentration of 18 ppb and the appropriate
variability factor and accuracy correction factor. The calculation of the
resulting BDAT treatment standard for methoxyclor (0.25 ppm) is described in
Section 6.0 and is shown in Table 6-10.
TABLE 4-152
WASTEHATER TREATMENT PERFORMANCE DATA
FOP METHOnCLOR
DETECTION RANGE BO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIHIT IHFLDEHT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (*) (t)
ppb
OH0058874 5 0.0100 NPDES
BT Full WV0000108 14 53.6520 NPDES
* WOx Full 78D 1000-10000 18.0000 99.8 WERL
Data used in developing proposed standard.
4-283
-------
Toxaphene (P123). The data available for toxaphene were compiled
from the NPDES database and are presented in Table 4-153. The technology for
which data were available was full-scale BT. Resulting effluent
concentrations ranged from 0.05 ppb to 1,004 ppb with a. detection limit for
toxaphene established a 0.24 ppb (see Table C-l, Appendix C).
BOAT for toxaphene is being promulgated as proposed and is
identified as biological treatment (BT). Biological treatment was selected as
BDAT since it represents full-scale data and is the only demonstrated
technology for which the Agency has data. The BDAT treatment standard for
toxaphene was calculated using an effluent concentration of 0.6781 ppb (which
represents the average of all BT effluent values; a value below the detection
limit was set at the detection limit) and the appropriate variability factor
and accuracy correction factor. The calculation of the resulting BDAT
treatment standard for toxaphene (0.0095 ppm) is described in Section 6.0 and
is shown in Table 6-10.
TABLE 4-153
WASTEHATEX TREATMENT PERFOBUBCE DATA
FOB TOXAPHENE
TECHNOLOGY
* BT
:i
* BT
* BT
* BT
* BT
* BT
* BT
* BT
TECHNOLOGY
SIZE
Full
Full
Full
Full
Full
Full
Full
Full
DETECTION
FACILITY LIMIT
(PPb)
OH0058874
GA0003735
CA0107611
CA0048194
CA0037681
LA0058882
CA0048216
LA0058882
LA0065501
NS0027995
Q0107417
GA0003735
CA0037681
CA0038598
CA0047881
CA0108031
CA0048143
CA0047996
CA0110604
CA0047364
CA0037737
CA0037494
CA0022756
LA0038245
RANGE NO. OF
IHFLDERT DATA
CONCENTRATION POINTS
(PPb)
5
1
1
5
13
33
5
32
6
8
5
39
29
5
1
1
1
9
3
4
2
1
38
AVERAGE
EFFLUENT RECOVERY
CONCENTRATION (!)
(PPb)
0.2000
2.2000
0.1000
1.2520
0.5000
15.9000
1004.0000
15.6000
1.0000
444.0000
0.1001
1.3000
0.4000
0.7400
2.0000
0.1000
0.4500
0.0500
0.0900
0.3667
0.1325
0.2625
1.0000
1.7421
REMOVAL REFERENCE
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES *
Data used in developing proposed standard.
4-284
-------
Silvex. Limited data were available for silvex from one NPDES
facility. These data are presented in Table 4-155. Due to a lack of
information on this facility (i.e., influent concentration, technology basis)
these data were not used to set BDAT. Treatment performance data were
therefore transferred to this constituent from a constituent judged to be
similar in elemental composition and functional groups within the structure of
the chemical. For constituents represented by a U or P code, this means that
/
constituents included in the same waste treatability group (see Appendix B)
were candidates for transfer of data. Silvex is similar in structure to
constituents in treatability group III.A.2.c.(3)(c) and the constituent used
to transfer treatment performance data from was 2,4-dichlorophenoxyacetic
acid. The treatment performance data for 2,4-dichlorophenoxyacetic acid
are presented in Table 4-154. Using a transfer from this constituent results
in a BOAT for silvex of chlorination (ChOx(Cl)) and a BDAT treatment standard
of 0.72 ppm as described in Section 6.0 and shown in Table 6-10.
TABLE 4-155
WASTEWATER TREATMENT PERFORMANCE DATA
FOB SILVEX
DETECTION RAKE MO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (I) (I)
(ppb) ' '
H0000868 9 3778 NPDES
4-288
-------
2.4.5-T. Limited data were available for 2,4,5-T from four NPDES
facilities. These data are presented in Table 4-156. Based on the high
effluent concentrations, none of these data were believed to represent
substantial treatment and were, therefore, not used to set BOAT. Treatment
performance data were therefore transferred to this constituent from a
constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. For constituents represented by
/
a U or F code, this means that constituents included in the same waste
treatability group (see Appendix B) were candidates for transfer of data.
2,4,5-T is similar in structure to constituents in treatability group
III.A.2.c.(3)(c) and the constituent used to transfer treatment performance
data from was 2,4-dichlorophenoxyacetic acid. The treatment performance data
for 2,4-dichlorophenoxyacetic acid is presented in Table 4-154. Using a
transfer from this constituent results in a BOAT for 2,4,5-T of chlorination
(ChOx(Cl)) and a BDAT treatment standard of 0.72 ppm as described in
Section 6.0 and shown in Table 6-10.
TABLE 4-156
WASTEWATER TREATMENT PERFORMANCE DATA
FOR 2,4,5-T
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLDENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (i) (I)
(ppb) jppb]
NY0106259 """ 5 2.000 NPDES
AR0038512 20 1232.000 NPDES
AR0038512 25 1292.830 NPDES
BT Full LA0038245 40 703.930 NPDES
4-289
-------
4.8 Organophosohorous Insecticides
Constituents discussed in this section include:
Disulfoton
Famphur
Methyl parathion
Parathion
Phorate
All of these constituents were grouped into a single treatability group during
the Second Third Rule. The treatability group for these constituents is the
organophosphorus wastes.
4-290
-------
Disulfoton (P039). No wastewater treatment performance data were
available for disulfoton from any of the examined sources. Treatment
performance data were therefore transferred to this constituent from a
constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. The constituent used to transfer
treatment performance data from was carbon disulfide. Carbon disulfide was
chosen for transfer since it is the only sulfur containing compound most
similar to the organophosphorus waste group for which the Agency has treatment
performance data. The treatment performance data for carbon disulfide are
presented in Tables 4-10A and 4-10B. Using a transfer from this constituent
results in a BDAT for disulfoton of biological treatment and a BOAT treatment
standard of 0.017 ppm as described in Section 6.0 and shown in Table 6-10.
Famphur (F097). No wastewater treatment performance data were
available for famphur from any of the examined sources. Treatment performance
data were therefore transferred to this constituent from a constituent judged
to be similar in elemental composition and functional groups within the
structure of the chemical. The constituent used to transfer treatment
performance data from was carbon disulfide. Carbon disulfide was chosen for
transfer since it is the only sulfur containing compound most similar to the
organophosorus waste group for which the Agency has treatment performance
data. The treatment performance data for carbon disulfide are presented in
Tables 4-10A and 4-10B. Using a transfer from this constituent results in a
BDAT for famphur of biological treatment and a BDAT treatment standard of
0.017 ppm as described in Section 6.0 and shown in Table 6-10.
4-291
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Methvl Parathion (P071). No wastewater treatment performance data
were available for methyl parathion from any of the examined sources.
Treatment performance data were therefore transferred to this constituent from
a constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. The constituent used to transfer
treatment performance data from was carbon disulfide. Carbon disulfide was
chosen for transfer since it is the only sulfur containing compound most
/
similar to the organophosphorus waste group for which the Agency has treatment
performance data. The treatment performance data for carbon disulfide are
presented in Tables 4-10A and 4-10B. Using a transfer from this constituent
results in a BOAT for methyl parathion of biological and a BOAT treatment
standard of 0.014 ppm as described in Section 6.0 and shown in Table 6-10.
Parathion (P089). No wastewater treatment performance data were
available for parathion from any of the examined sources. Treatment
performance data were therefore transferred to this constituent from a
constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. The constituent used to transfer
treatment performance data from was carbon disulfide. Carbon disulfide was
chosen for transfer since it is the only sulfur containing compound most
similar to the organophosphorus waste group for which the Agency has treatment
performance data. The treatment performance data for carbon disulfide are
presented in Tables 4-10A and 4-10B. Using a transfer from this constituent
results in a BDAT for parathion of biological treatment and a BOAT treatment
standard of 0.017 ppm as described in Section 6.0 and shown in Table 6-10.
4-292
-------
Phorate (P094). No wastewater treatment performance data were
available for phorate from any of the examined sources. Treatment performance
data were therefore transferred to this constituent from a constituent judged
to be similar in elemental composition and functional groups within the
structure of the chemical. The constituent used to transfer treatment
performance data from was carbon disulfide. Carbon disulfide was chosen for
transfer since it is the only sulfur containing compound most similar to the
t
organophosphorus waste group for which the Agency has treatment performance
data. The treatment performance data for carbon disulfide are presented in
Tables 4-10A and 4-10B. Using a transfer from this constituent results in a
BDAT for phorate of biological treatment and a BOAT treatment standard of
0.021 ppm as described in Section 6.0 and shown in Table 6-10.
4-293
-------
4.9
PCBs
Constituents discussed in this section include:
Aroclor
Aroclor
Aroclor
Aroclor
Aroclor
Aroclor
Aroclor
1016
1221
1232
1242
1248
1254
1260
4-294
-------
Aroclor 1016. The data available for aroclor 1016 were compiled
from the NPDES database and are presented in Table 4-157. The technology for
which data were available was full-scale BT. The effluent concentrations for
all documented data ranged from 0.5 ppb to 4.033 ppb.
BDAT for Aroclor 1016 is being promulgated as proposed and is
identified as biological treatment (BT). Biological treatment was selected as
BDAT since it represents full-scale data and is the only demonstrated
technology for which the Agency has data. The BDAT treatment standard for
Aroclor 1016 was calculated using the effluent concentration of 0.911 ppb and
the appropriate variability factor and accuracy correction factor. The
calculation of the resulting BDAT treatment standard for Aroclor 1016
(0.013 ppm) is described in Section 6.0 and is shown in Table 6-10.
HASTEHATER
4-157
FOR AROCLOR 1016
DATA
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT Jfftfo JJfc Jfgg^
(ppb) (ppb)
RECOVERY REMOVAL REFERENCE
(») (*)
* BT
HY0007129
LA0066214
LA0065501
TN0001520
NY0007129
Full LA0038245
5
15
6
3
37
0.500 -
1.000
0.500
4.033
0.500
0.911
NPDES
NPDES
HPDES
NPDES
HPDES
NPDES *
* Data used in developing proposed standard.
4-295
-------
Aroclor 1221. The data available for aroclor 1221 were compiled
from the NPDES database and are presented in Table 4-158. The technology for
which data were available was full-scale BT. The effluent concentrations for
all documented data ranged from 0.13 ppb to 15.3 ppb.
BOAT for Aroclor 1221 is being promulgated as proposed and is
identified as biological treatment (BT). Biological treatment was selected as
BOAT since it represents full-scale data and is the only demonstrated
technology for which the Agency has data. The BDAT treatment standard for
Aroclor 1221 was calculated using the effluent concentration of 1.018 ppb and
the appropriate variability factor and accuracy correction factor. The
calculation of the resulting BDAT treatment standard for Aroclor 1221
(0.014 ppm) is described in Section 6.0 and is shown in Table 6-10.
TABLE 4-158
WASTEWATER TREATMENT PERFORMANCE DATA
FOP AROOOR 1221
TECHNOLOGY
* BT
TECHNOLOGY FACILITY
SUE
LA0065501
LA0058882
LA0058882
NY0007129
KY0007129
Full LA0038245
DETECTION RANGE
LIMIT INFLUENT
(ppb) CONCENTRATION
(PPb)
NO. OF
DATA
POINTS
6
33
32
5
3
39
AVERAGE
EFFLOENT RECOVERY
CONCENTRATION (I)
(PPb)
0.130
15.300
15.000
0.500
0.500
1.018
REMOVAL REFERENCE
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES *
Data used in developing proposed standard.
4-296
-------
Aroclor 1232. The data available for aroclor 1232 were compiled
from the NPDES database and are presented in Table 4-159. The technology for
which data were available was full-scale BT. The effluent concentrations of
all documented data ranged from 0.5 ppb to 15.3 ppb.
BDAT for Aroclor 1232 is being promulgated as proposed and is
identified as biological treatment (BT). Biological treatment was selected as
BDAT because of since it represents full-scale data and is the only
demonstrated technology for which the Agency has data. The BDAT treatment
standard for Aroclor 1232 was calculated using the effluent concentration of
0.915 ppb and the appropriate variability factor and accuracy correction
factor. The calculation of the resulting BDAT treatment standard for Aroclor
1232 (0.013 ppm) is described in Section 6.0 and is shown in Table 6-10.
TABLE 4-159
WASTEWATER TREATMENT PERFORKAHCE DATA
FOR APOCLOR 1232
TECHNOLOGY
* BT
TECHNOLOGY
SIZE
Full
FACILITY
LA0058882
LA0058S82
LA0065501
HY0007129
HY0007129
LA0038245
DETECTIOB
LIMIT
(PPb)
RANGE
INFLUENT
CONCENTRATION
(PPb)
HO. OF
DATA
POINTS
33
32
3
5
39
AVERAGE
EFFLUENT RECOVERY
CONCENTRATION (*)
(PPb)
15.300
15.000
0.500
0.500
0.500
0.915
REMOVAL REFERFJK
m
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
:E
*
Data used in developing proposed standard.
4-297
-------
Aroclor 1242. The data available for aroclor 1242 were compiled
from the NPDES database and are presented in Table 4-160. The technology for
which data were available was full-scale BT. The effluent concentrations of
all documented data ranged from 0.5 ppb to 15.3 ppb.
BDAT for Aroclor 1242 is being promulgated as proposed and is
identified as biological treatment (BT). Biological treatment was selected as
BDAT since it represents full-scale data and is the only demonstrated
technology for which the Agency has data. The BDAT treatment standard for
Aroclor 1242 was calculated using the effluent concentration of 1.186 ppb and
the appropriate variability factor and accuracy correction factor. The
calculation of the resulting BDAT treatment standard for Aroclor 1242
(0.017 ppm) is described in Section 6.0 and is shown in Table 6-10.
TABLE 4-160
WASTEWATER TREATMENT PERFOKHAHCE DATA
FOR ASOCLOR 1242
DETECTION RANGE HO. OF AVERAGE
TECHHOLOGY TECHNOLOGY FACILITY LIKIT INFLDEHT DATA EFFLUENT RECOVERY
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (1)
(ppb) (ppb)
LA0065501
LA0058882
NY0007129
NY0202037
NY0007226
LA0058882
HY0007129
NY0000566
* BT Full LA0038245
6
1
29
7
33
5
12
39
0.500
12.260
0.593
0.500
0.623
15.300
0.612
1.433
1.186
REMOVAL REFERENCE
(»)
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
HPDES
NPDES
NPDES *
Data used in developing proposed standard.
4-298
-------
Aroclor 1254. The data available for aroclor 1254 were compiled
from the NPDES and WERL databases and are presented in Table 4-162. The
technologies for which data are available include AFF and BT. The treatment
performance data represent bench- and full-scale studies. Resulting effluent
concentrations ranged from 0.36 ppb to 15.3 ppb.
BDAT for Aroclor 1254 is being promulgated as proposed and is
/
identified as biological treatment (BT). Biological treatment was selected as
BDAT since it represents full-scale data and was preferred over bench-scale
aerobic fixed film (AFF) data. The effluent concentrations achieved by AFF
support the effluent concentration achieved by biological treatment. The BDAT
treatment standard for Aroclor 1254 was calculated using the effluent
concentration of 0.967 ppb and the appropriate variability factor and accuracy
correction factor. The calculation of the resulting BDAT treatment standard
for Aroclor 1254 (0.014 ppm) is described in Section 6.0 and is shown in
Table 6-10.
TABLE 4-162
WASTEWATER TREATMENT PERFORMANCE DATA
FOR AROCLOR 1254
TECHNOLOGY
AFF
AFF
* BT
TECHNOLOGY
SIZE
Bench
Bench
Full
FACILITY
LA0058882
LA0065501
HY0007129
LA0058882
HY0007129
70A
70A
LA0038245
DETECTION
LIHIT
(PPb)
RANGE NO. OF
INFLDENT DATA
CONCENTRATION POINTS
(PPb)
100-1000
0-100
31
6
33
19
17
39
AVERAGE
EFFLOENT
CONCENTRATION
(ppb)
12.260
1.000
0.667
15.300
1.000
11.000
0.360
0.967
RECOVERY REMOVAL
(*) (*)
98.9
64
REFERENCE
NPD
HPD
NPD
NPD
NPD
HER
KER
NPD
ES
IS
5
!S
!S
I
j
ES
*
* Data used in developing proposed standard.
4-300
-------
Aroclor 1260. The data available for aroclor 1260 were compiled
from the NPDES and WERL databases and are presented in Table 4-163. The
technologies for which data are available include full-scale BT and Sed. The
resulting effluent, concentrations ranged from 0.028 ppb to 15.3 ppb.
BDAT for Aroclor 1260 is being promulgated as proposed and is
identified as biological treatment (BT). Biological treatment was selected as
BDAT since it represents full-scale data from a demonstrated technology.
Although Sed data were also available, this technology alone is not considered
applicable for the treatment of organics and therefore was not considered for
BDAT. The BDAT treatment standard for Aroclor 1260 was calculated using the
effluent concentration of 0.967 ppb and the appropriate variability factor and
accuracy correction factor. The calculation of the resulting BDAT treatment
standard for Aroclor 1260 (0.014 ppm) is described in Section 6.0 and is shown
in Table 6-10.
TABLE 4-163
HASTEWATER TREATMENT PERFORMANCE DATA
FOR AROCLOR 1260
TECHHOLOGY TECHNOLOGY
SIZE
* BT Full
Sed Full
DETECTION
FACILITY LIKIT
(PPb)
IN0053384
IH0053334
PA0026662
LA0058882
HY0007129
LA0058882
LA0065501
HY0007129
IN0053384
LA0038245
981E
RANGE
IHFLDEHT
CONCENTRATION
(PPb)
0-100
NO. OF
DATA
POINTS
1
43
2
33
5
31
6
3
1
39
5
AVERAGE
EFFLOEHT RECOVERY
CONCENTRATION (*)
(PPb)
0.500
0.560
0.500
15.300
1.000
12.260
1.000
0.833
0.500
0.967
0.028
REHOVAL REFEREHCE
0)
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES
NPDES *
52 SEW,
Data used in developing proposed standard.
4-301
-------
4.10 Pioxins and Furans
Constituents discussed in this section include:
Hexachlorodibenzo-p-dioxins
Hexachlorodibenzofurans
Pentachlorodibenzo-p-dioxins
Pentachlorodibenzofurans
Tetrachlorodibenzo-p-dioxins
Tetrachlorodibenzofurans
4-302
-------
Hexachlorodlbenzo-p-dioxlns. The data available for
hexachlorodibenzo-p-dioxin were compiled from the VERL database and are
presented in Table 4-164. The only documented treatment technology was bench-
scale dechlorination of toxics using an alkoxide formed by the reaction of
potassium hydroxide with polyethylene (KPEG). KPEG was not considered a
demonstrated treatment technology since the Agency is not aware of full-scale
applications in operation. KPEG was therefore not considered when determining
BOAT. Treatment performance data were therefore transferred to
hexachlorodibenzo-p-dioxin from a constituent judged to be similar in
elemental composition and functional groups within the structure of the
chemical. The constituent used to transfer treatment performance data from
was tetrachlorodibenzo-p-dioxin. Tetrachlorodibenzo-p-dioxin was chosen for
transfer since it represents the constituent most similar in structure to
hexachlorodibenzo-p-dioxin. The treatment performance data for
tetrachlorodibenzo-p-dioxin are presented in Tables 4-168A and 4-168B. Using
a transfer from this constituent results in a BDAT for hexachlorodibenzo-p-
dioxin of biological treatment and a BDAT treatment standard of 0.000063 ppm
as described in Section 6.0 and shown in Table 6-10.
4-164
WASTBWATEX TREATKEHT PERPORHAHCE DATA
FOE HEXACHLOBODIBENZO-p-DIOXINS
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLOEHT DATA EFFLUENT RECOVERY REKOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (I) (I)
(ppb) (ppb]
KPEG (B) Bench 244B 1000-10000 1 2.10000 99.93 WERL
4-303
-------
Hexachlorodibenzofurans. The data available for hexachlorodibenzo-
furan were compiled from the WERL database and are presented in Table 4-165.
The only documented treatment technology was bench-scale dechlorination of
toxics using an alkoxide formed by the reaction of potassium hydroxide with
polyethylene (KPEG). KPEG was not considered a demonstrated treatment
technology since the Agency is not aware of full-scale applications in
operation. KPEG was therefore not considered when determining BDAT.
Treatment performance data were therefore transferred to this constituent from
a constituent judged to be similar in elemental composition and functional
groups within the structure of the chemical. The constituent used to transfer
treatment performance data from was tetrachlorodibenzo-p-dioxin.
Tetrachlorodibenzo-p-dioxiri was chosen for transfer since it represents the
constituent most similar in structure to hexachlorodibenzofuran. The
treatment performance data for tetrachlorodibenzo-p-dioxin are presented in
Tables 4-168A and 4-1.68B. Using a transfer from this constituent results in a
BDAT for hexachlorodibenzofuran of biological treatment and a BDAT treatment
standard of 0.000063 ppm as described in Section 6.0 and shown in Table 6-10.
TABLE 4-165
WASTEWATER TREATMENT PERFORMANCE DATA
FOR HEXACHLORODIBEHZOFDRANS
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIHIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (rob) CONCENTRATION POINTS CONCENTRATION (I) (\)
_(PPb)(ppb]
" KPEG (B) Bench " 244B~~ 1000-10000 1 0.76000 99.98 WERL
4-304
-------
Pentachlorodibenzofurans. The data available for pentachloro-
dibenzofuran were compiled from the VERL database and are presented in
Table 4-167A. In addition, leachate treatment performance data submitted by
industry prior to proposal are presented in Table 4-167B. Technologies for
which data are available include bench-scale KPEG and BT. However, the bench-
scale KPEG technology is not considered demonstrated since the Agency is not
aware of full-scale applications in operation. KPEG was therefore not
considered when determining BOAT.
At proposal, BOAT for pentachlorodibenzofuran was identified as
biological treatment and the treatment standard was based on a transfer of
treatment performance data from tetrachlorodibenzo-p-dioxin. Between proposal
and promulgation, EPA evaluated the industry-submitted leachate data available
for pentachlorodibenzofuran. Since this data for biological treatment (BT)
showed substantial treatment of pentachlorodibenzofuran, these data were used
to calculate the promulgated standard. Therefore, BOAT for pentachloro-
dibenzofuran is biological treatment.
The BOAT treatment standard for pentachlorodibenzofuran was
calculated using the effluent concentration of 0.0025 ppb (which represents
the average effluent of the two BT data sets) and the appropriate variability
factor and accuracy correction factor. The calculation of the resulting BDAT
treatment standard for pentachlorodibenzofuran (0.000035 ppm) is described in
Section 6.0 and is shown in Table 6-10.
4-306
-------
TABLE 4-167A
WASTBWATER TREATMENT PERFORMANCE DATA
FOR PENTACHLORODIBENZOFURANS
DETECTION RANGE HO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIHIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (t)
ppb)
KPEG (B) Bench 244B 100-1000 1 0.71000 9991 WERL
TABLE 4-167B
INDCSTRY-SnBMITTED LEACHATE TREATMENT PERFORMANCE
DATA FOR PENTACHLORODIBENZOFCRANS
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLCENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (I) (t)
(ppb) (ppb)
BT Offl 0.0001-0.0027 3 0.002 LEACHATE
BT B Offl -0.0118 3 0.003 77.68 LEACHATE
4-307
-------
Tetrachlorodibenzo-p-dioxins. The data available for
tetrachlorodibenzo-p-dioxin were compiled from the WERL database and are
presented in Table 4-168A. in addition, leachate treatment performance data
submitted by industry prior to proposal are presented in Table 4-168B.
Technologies for which data are available include AS, GAC, KPEG, and BT. The
treatment performance data represent bench- and full-scale studies. Resulting
effluent concentrations ranged from 0.00001 ppb to 0.65 ppb.
At proposal, BDAT for tetrachlorodibenzo-p-dioxin was identified as
activated sludge (AS) and the treatment standard was based on an effluent
concentration of 0.00044 ppb. Between proposal and promulgation, EPA
evaluated the industry-submitted leachate data available for tetrachloro-
dibenzo-p-dioxin. Since this data for biological treatment (BT) showed
substantial treatment of tetrachlorodibenzo-p-dioxin and showed an average
leachate effluent values greater than that of AS, these data were used to
calculate the promulgated standard. Therefore, BDAT for tetrachlorodibenzo-p-
dioxin is biological treatment.
The BDAT treatment standard for tetrachlorodibenzo-p-dioxin was
calculated using the effluent concentration of 0.0045 ppb and the appropriate
variability factor and accuracy correction factor. The calculation of the
resulting BDAT treatment standard for tetrachlorodibenzo-p-dioxin (0.000063
ppra) is described in Section 6.0 and is shown in Table 6-10.
4-308
-------
TABLE 4-168A
WASTEWATER TREATMENT PERFORMANCE DATA
FOR TETRACHLORODIBEHZO-p-DIOXINS
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (I) (I)
(ppb) (ppb)
* AS
* AS
GAC
KPEG (B)
KPEG B
Full
ffll
Bench
Bench
253B
253B
245B
244B
244B
0-100
0-100
0-100
0-100
100-1000
1
1
1
1
0.00012
0.00001
0.00087
0.65000
0.37000
14
75
93.6
97.7
99.91
WERL *
WERL *
WERL
mi
WERL
Data used in developing proposed standard.
TABLE 4-168B
INDUSTRY-SUBMITTED TREATMENT PERFORMANCE DATA
FOR TETRACHLORODIBEHZO-p-DIOXINS
DETECTION RANGE NO. OP AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLDENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (I) (I)
(ppb) (ppb)
BT CWM 0.0021-0.0039 3 0.00500 LEACHATE
BT B CWM -0.0176 3 0.00400 78.79 LEACHATE
4-309
-------
Tetrachlorodibenzofurans. The data available for tetrachloro-
dibenzofuran were compiled from the WERL database and are presented in
Table 4-169. The only documented treatment technology was bench-scale
dechlorination of toxics using an alkoxide formed by the reaction of potassium
hydroxide with polyethylene (KPEG). KPEG was not considered a demonstrated
treatment technology since the Agency is not aware of full-scale applications
in operation. KPEG was therefore not considered when determining BDAT.
Treatment performance data were therefore transferred to tetrachloro-
dibenzofuran from a constituent judged to be similar in elemental composition
and functional groups within the structure of the chemical. The constituent
used to transfer treatment performance data from was tetrachlorodibenzo-p-
dioxin. Tetrachlorodibenzo-p-dioxin was chosen for transfer since it
represents the constituent most similar in structure to tetrachloro-
dibenzofuran. The treatment performance data for tetrachlorodibenzo-p-dioxin
are presented in Tables 4-168A and 4-168B. Using a transfer from this
constituent results in a BDAT for tetrachlorodibenzofuran of biological
treatment and a BDAT treatment standard of 0.000063 ppm as described in
Section 6.0 and shown in Table 6-10.
TABLE 4-169
WASTEHATEX TREATMENT PERFORMANCE DATA
FOR TETSACHLORODIBEKZOFURAliS
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLDEHT DATA EFFLOENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (I) (*)
(ppb](ppb]
"KPEC~(B) Bench ~244B~100-1000 i 0.35000 99. ?e WERL
4-310
-------
constituents._ The multi-source leachate vastewater constituents for which
concentration-based standards are being established are presented in
Table 1-4.
5.2 Multi-source Leachate Constituents Controlled by the Regulated
Multi-source Leachate Constituents
Waste constituents that were not selected for regulation in multi-
source leachate wastewaters include:
• Non-analyzable organic U and P wastes;
• Incinerable reactive organics and hydrazine derivatives;
• Incinerable inorganics;
• Florines;
• Recoverable metallics;
• Thallium and vanadium U and P wastes;
• Hexavalent chromium;
• Cyanide compounds;
• Gases; and
• Organophosphorus pesticide wastes.
Generally, the Agency specifies a method of treatment as the
treatment standard for a constituent when it is not appropriate to establish a
concentration-based treatment standard. However, in the case of multi-source
leachate, the Agency does not believe setting a method of treatment is
appropriate since multi-source leachates are highly variable and many
different technologies may be appropriate for treatment depending on the
waste. In addition, the Agency believes that constituents in multi-source
leachate that do not have a concentration-based standard can be controlled by
the regulation of the BDAT List constituents for which concentration-based
standards are being established. Specifically, constituents will be
controlled by regulation of other constituents within the same treatability
5-2
-------
group. The Agency believes that this is technically valid since structurally
similar compounds are likely to be treated by the same technology and to
achieve similar treatment performance. Table 5-1 presents constituents not
selected for regulation in multi-source leachate and presents the regulated
constituent(s) in the same (or similar) treatability group that will control
those constituents. In those cases where there are no controlling
constituents in the same treatability group, a controlling constituent is
presented from a structurally similar treatability group.
Additional detail on the reasons why concentration-based treatment
standards are not appropriate for the constituents that were not selected for
regulation in multi-source leachate wastewaters is included in the respective
background documents and preamble sections for these wastes.
5-3
-------
Table 5-1
WASTEWATER CONSTITUENTS HOT REGULATED IN KULTI-SOURCE LEACHATE AND
REGULATED CONSTITUENTS TEAT CONTROL FOR THEIR TREATMENT
Constituents Not Regulated "Controlling" Constituent(s)
Waste Haste
Code Constituent Code Constituent
AROHATIC AND OTHER HYDROCARBON WASTES:
U055 Cunene U019 Benzene
U056 Cyclohexane D220 Toluene
U186 1,3-Pentadiene U239 Xylenes
BROKINATED ORGANIC WASTES:
P017 Bronoacetone D029 Brooonetbane
U030 4-Bronop&enyl phenyl ether
0066 l,2-Dibroio-3-chloropropane
U067 1,2-Dibronoethane (Etbylene dibronide)
U068 Dibrononethane
U225 Bronofom
HALOGENATED ALIPHATIC HASTES:
U074 cis-l,4-Dichloro-2-butene U044 Chlorofora
U074 trans-l,4-Dichloro-2-butene U076 1,1-Dichloroethane
U184 Pentachloroethane U077 1,2-Dicbloroethane
U078 1,1-Dichloroethylene
U079 1,2-Dichloroethylene (trans isoner)
0080 Hethylene chloride
U083 1,2-Dichloropropane
0084 1,3-Didiloropropylene (cis & trans)
U131 Hexachloroethane
U208 1,1,1,2-Tetracnloroethane
U209 1,1,2,2-Tetradaoroethane
U210 Tetradiloroethylene
U211 Carbon tetrachloride
0226 1,1,1-Trichloroethane
C227 1,1,2-Trichloroethane
0228 Trichloroethylene
U243 Hexachloropropylene
CHLORINATED NORBORNANE AND NORBORNENE DERIVATIVES:
POM Aldrin
P037 Dieldrin
P050 Endosulfan I and II
P051 Endrin
P059 Heptachlor
P060 Isodrin
5-4
-------
- Table 5-1 (Continued)
WASTEWATER CONSTITUENTS HOT REGULATED IN HULTI-SOURCE LEACHATE AND
REGULATED CONSTITUENTS THAT CONTROL FOR THEIR TREATMENT
Constituents Not Regulated
Constituent
"Controlling11 Constituent (s)
Constituent
Waste
Code
Haste
Code
U038
U132
P001
P003
P005
P088
P102
0001
0008
U053
C057
U085
U113
C122
U123
U124
U125
0126
U147
U166
U182
U197
U213
U248
CHLORINATED NORBORNANE AND NORBORNENE DERIVATIVES (Continued):
P123 Toxaphene
U036 Chlordane
U130 Hexachlorocyclopentadiene
D142 Kepone
U240 2,4-D salts
CHLOROPHEHOXYACETIC ACID AND DERIVATIVES:
U240 2,4-D
CHLORINATED DIPHENYLS:
Chlorobenzilate (a)
Hexachlorophene
U060
U061
U061
0061
D247
DDD (o,p(- and p,p'- isoners)
DDD (o,p'- and p,p'- isoners)
DDE (o,p'- and p,p'- isoners)
DDT (o,p(- and p,p'- isoners)
Retbozycnlor
OXYGENATED HYDROCARBON AND HETEROCYCLIC HASTES:
Warfarin (>0.3*)
Acrolein
Allyl alcohol
Endothall
Propargyl alcohol
Acetaldehyde
Acrylic acid
Crotonaldehyde
Cyclohexanone (a)
l,2:3,4-Diepoxybutane
Ethyl acrylate
Fornaldehyde
Fornic acid
Fur an
Furfural
Glycidylaldehyde
Maleic anhydride
1,4-Naphthoquinone
Paraldehyde
p-Benzoquinone
Tetrahydrofuran •
Warfarin (<0.3*)
U002 Acetone
U004 Acetophenone
U031 n-Butyl alcohol (n-Butanol)
U108 1,4-Dioxane
0112 Ethyl acetate
0117 Ethyl ether
U118 Ethyl nethacrylate
U140 Isobutyl alcohol (Isobutanol)
U154 Hethanol
U159 Methyl ethyl ketone
U161 Hethyl isobutyl ketone.
U162 Methyl nethacrylate
5-5
-------
Table 5-1 (Continued)
WASTEWATER CONSTITUENTS NOT REGULATED IN NOLTI-SOURCE LEACHATE AND
REGULATED CONSTITUENTS THAT CONTROL FOR THEIR TREATMENT
Constituents Not Regulated "Controlling" Constituent(s)
Waste Waste
Code Constituent Code Constituent
WASTES OF A PHARMACEUTICAL NATURE:
P007 5-Aninonethyl-3-isoxazolol U141 Isosafrole
P042 Epinephrine U155 Nethapyrilene
P075 Nicotine and salts 0187 Phenacetin
P108 Strychnine and salts U203 Safrole
C010 Kitonycin C
C015 Azaserine
C035 Chloranbucil
U059 Daunonycin
U089 Diethylstilbestrol
U090 Dihydrosafrole
U143 Lasiocarpine
G150 Melphalan
U163 N-Kethyl-, N-nitro-; N-nitroso-
guanidine
0164 Metbylthiouracil
C200 Reserpine
U202 Saccharin and salts
D206 Streptozotocin
U237 Uracil uustard
PHENOLIC WASTES:
P034 2-Cyclohexyl-4,6-dinitro- P020 2-sec-Butyl-4,6-dinitrophenol (Dinoseb)
phenol P047 4,6-Dinitro-o-cresol
P047 4,6-Dinitro-o-cresol salts P048 2,4-Dinitrophenol
U201 Resorcinol U052 Cresol (o-, D-, and p- isoners)
UlOl 2,4-Dinethylphenol
U170 4-Nitrophenol
0188 Phenol
POLYNUCLEAR AROMATIC WASTES:
U016 Benz(c)acridine U005 2-Acetylaninofluorene
U064 1,2,7,8-Dibenzopyrene U018 Benz(a)anthracene
U094 7,12-Dinethyl benz(a)- U022 Benz(a)pyrene
anthracene U050 Chrysene
Dibenzo(a,i)pyrene U051 Creosote
U063 Dibenzj a,h Anthracene
U120 Fluoranthene
U137 Indeno(l,2,3-c,d)pyrene
U157 3-Methylcholanthrene
U165 Naphthalene
5-6
-------
Table 5-1 (Continued)
WASTEWATER CONSTITUENTS NOT REGULATED IN KULTI-SOORCE LEACHATE AND
REGULATED CONSTITUENTS THAT CONTROL FOR THEIR TREATMENT
Constituents Hot Regulated "Controlling" Constituent(s)
Haste Waste
Code Constituent Code Constituent
NITROGEN HETEROCYCLIC CONFOUNDS:
POOS 4-Aninopyridine C179 N-Nitrosopiperidine
P018 Brucine U180 N-Nitrosopyrrolidine
P054 Aziridine U196 Pyridine
P067 2-Hethylaziridine
U011 Anitrole
U148 Haleic hydrazide
0191 2-Picoline
ABIDES AMD AXHES:
P046 alpha,alpha-Diuethylphen- 0012 Aniline
etbylanine U168 2-Naphthylanine
P064 Isocyanic acid, uethyl ester
U007 Acrylanide
0092 Dinethylaaine
U110 Dipropylanine
0167 i-Napbthylanine
U194 n-Propylanine
U238 Ethyl carbanate
U223 Toluenedianine
AKINATED DIPHEKYLS/BIPHENYLS:
0014 Auranine Transfer fron anides and anines
D021 Benzidine
0091 3,3'-Dinethoxybenzidine
0093 p-Dinetbylaninoazobenzene
0095 3,3'-Dinethylbenzidine
U236 Trypan blue
NITHLES:
P069 Methyllactonitrile P101 Ethyl cyanide (Propanenitrile)
D003 Acetonitrile (a) U009 Acrylonitrile
0149 Kalononitrile 0152 Hethacrylonitrile
5-7
-------
- Table 5-1 (Continued)
WASTEWATER CONSTITUHTTS HOT REGULATED IK KOMI-SOURCE LEACHATE AND
REGULATED COHSTITUENTS THAT CONTROL FOR THEIR TREATMENT
Constituents Hot Regulated "Controlling" Constituent(s)
waste Waste
Code Constituent Code Constituent
HITRO COHPOUNDS:
U171 2-Hitropropane P077 p-Hitroaniline
U234 syii-Trinitrobenzene U105 2,4-Dinitrotoluene
D106 2,6-Dinitrotoluene
U169 Nitrobenzene
D181 5-Hitro-o-toluidine
HITROSO COMPOUNDS:
P084 H-Hitrosonethylvinylanine P082 N-Hitrosodinethylaaine
D173 H-NitrosodiethanolaBine Ulll Di-n-propylnitrosaaine
U176 N-Hitroso-H-ethylurea U172 N-Hitrosodi-n-butylanine
U177 H-Nitroso-H-nethylurea U174 N-Nitrosodiethylaaine
U178 N-Nitroso-N-nethylurethane
ORGAN-SULFUR COMPOUND HASTES:
P002 l-Acetyl-2-thiourea Transfer fron baloqenated aliphatic
P014 Benzenethipl (Tbiopbenol) wastes and aronatic wastes
P045 Thiofanox
P049 2,4-Dithiobiuret P022 Carbon disulfide
P066 Kethoayl
P070 Aldicarb
P072 ' l-Haphthyl-2-thiourea
P093 H-Mienylthiourea
P116 Thiosenicarbazide
U114 Ethylene bis-dithiocarbanic
acid
U116 Ethylene tbiourea
0119 Ethyl nethane sulfonate
0153 Hetbane thiol
0193 1,3-Propane sultone
U218 Thioacetanide
U219 Thiourea
U244 Thiran
5-8
-------
— Table 5-1 (Continued)
WASTEWATER CONSTITOEHTS HOT REGULATED IH HCLTI-SOORCE LEACHATE AHD
REGULATED CONSTITUENTS THAT CONTROL FOR THEIR TREATMENT
Constituents Hot Regulated
"Controlling" Constituent(s)
Viaste
Code
P026
P118
U020
U062
0096
P009
P081
D133
0086
0160
P068
P112
0023
0098
0099
0103
Constituent
Haste
Code
Constituent
CHLORINATED ORGANOSOLFORS:
1-(o-Chlorophenyl)thiourea
Trichloronethanethiol
Benzene sulfonyl chloride
Diallate
Transfer frou halogenated aliphatic
vastes and aronatic vastes
INCINERABLE REACTIVE ORGANICS AHD HYDRAZINE DERIVATIVES:
alpha,alpha-Diaethyl benzyl
bydroperoxide
Araoniun picrate
Hitroqlycerin
Hydrazine
H,N-Diethylhydrazine
Uethyl ethyl ketone peroxide
Methyl hydrarine
TetranitroBethane
Benrotrichloride
1,1-DinethyIhydraz ine
1,2-DiuethyIhydrazine
Dinethyl sulfate
Transfer froa aoides and aiines
0109 1,2-DiphenyIhydrazine
INCINERABLE INORGANICS:
P096 Phosphine
P105 SodiuD azide
U189 Phosphorus sulfide
0249 Zinc phosphide (<10*)
P006 Aluninun phosphide
P122 Zinc phosphide (>10I)
0135 Hydrogen sulfide
0134 Hydrofluoric acid
P056 Fluorine
Transfer cyanide conpounds
FLUORINES:
Transfer cyanide conpounds
5-10
-------
- Table 5-1 (Continued)
WASTEWATER CONSTITUENTS NOT REGULATED IN MULTI-SOURCE LEACHATE AND
REGULATED CONSTITUENTS THAT CONTROL FOR THEIR TREATMENT
Constituents Not Regulated
Constituent
"Controlling" Constituent(s)
Constituent
Waste
Code
Haste
Code
RECOVERABLE HETALLICS:
P015 Berylliun dust
P0?3 Nickel carbonyl
P087 Osniun tetroxide
THALLIUN:
P113
P114
P115
U214
U215
U216
C217
Thallic oxide
Thalliun selenite
Thalliva (I) sulfate
Thalliun (I) acetate
Thalliun (I) carbonate
Thalliun (I) chloride
Thaliuu (I) nitrate .
VANADIUM:
P119
P120
Annoniun vanadate
Vanadiun pentoxide
Antimony
Arsenic
Barium
Cadniun
Chroniun (total)
Lead
Mercury
Mickel
Seleniun
Silver
Antinony
Arsenic
Bariia
Caduiun
Coroniun (total)
Lead
Mercury
Nickel
Seleniua
Silver
Antimony
Arsenic
Bariun
Cadniun
ChroniuD (total)
Lead
Mercury
Mickel
Seleniuo
Silver
5-11
-------
- Table 5-1 (Continued)
WASTEWATER CONSTITUENTS HOT REGULATED IK MULTI-SOURCE LEACHATE AHD
REGULATED CONSTITUENTS THAT CONTROL FOR THEIR TREATMENT
Constituents Not Regulated "Controlling" Constituent(s)
Waste Waste
Code Constituent Code Constituent
OTHER BDAT LIST METALS:
Chroniuu (hexavalent) Antimony
Arsenic
Bariun
Cadniun
Chroniun (total)
Lead
Mercury
Hickel
Seleniui
Silver
CYANIDE COMPOUNDS:
P031 Cyanogen Cyanide (total)
P033 Cyanogen chloride
U246 Cyanogen broaide
U223 Toluene diisocyanate
GASES:
P076 Nitric oxide Transfer oxygenated wastes
P078 nitrogen dioxide
ORGAMOPBOSPBORUS PESTICIDE WASTES:
P040 Diethyl 2-pyrazinyl P039 Disulfoton
phosphorothioate P071 Methyl parathion
P041 Diethyl-p-nitrophenyl P089 Parathion
phosphate P094 Phorate
P043 Diisopropylfluorophosphate P097 Fanphur
P044 Dinethoate G235 Tris(2,3-dibronopropyl)
P062 Hexaethyl tetraphosphate phosphate
P085 Octanethyl pyrophosphoranide
P109 Tetraethyl dithiopyrophosphate
Pill Tetraethyl pyrophosphate
U058 Cyclophosphanide
U087 0,0-Diethyl S-nethyl
dithiophosphate
5-12
-------
a: Constituent for which a method of treatnent is being promulgated
for nonvastervaters based on 'the Interlaboratory Ash Study.
Hay not be applicable to wastevaters.
*: Has nunerical standard for vastevater and nethod of treatnent standard for nonwaste-
vater (based on ash study). Hay not be applicable for wastewaters.
5-13
-------
average variability factors were generated from the ITD variability factors
and are specific to the type of constituent under consideration (i.e.,
volatile, acid neutral semivolatile, etc.). The average volatile variability
factor is an average of the sum of volatile variability factors from ITD data
as shown in Table 6-1. The average semivolatile variability factors are
averages of the sum of semivolatile variability factors from ITD data as shown
in Table 6-2. Determination of these average variability factors is similar
to the procedure used by EPA in the BDAT land disposal rule in the past to
determine average accuracy correction factors. Second, for constituents in
this category that are not a volatile or semivolatile, a variability factor of
2.8 was used. For constituents where the long term average was based on all
not-detected values, a variability factor of 2.8 was also used.
6.2 Accuracy Correction Factors
Accuracy correction factors account for analytical interferences
associated with the chemical matrices of the samples. In those cases where an
ITD variability factor was used, another accuracy correction factor was not
used. This was done since ITD variability factors were originally calculated
to represent performance, analytical, and matrix variations. In cases where
an ITD variability factor was not used, an accuracy correction factor was
determined and included in the treatment standard calculation.
Since matrix spike data (which is used in determining accuracy
correction factors) were unavailable for most of the data examined, analytical
matrix spike data were pooled from BDAT sources and from leachate sources.
Leachate matrix spike data were used to determine an accuracy correction
factor for cases where leachate treatment performance data were used to
establish a treatment standard. The BDAT matrix spike data were used in all
other cases. Where an accuracy correction factor was not available for a
specific constituent, an average accuracy correction factor was determined as
shown in Tables 6-3 to 6-9.
6-2
-------
For_constituents requiring an accuracy correction factor where one
was not available for the constituent and an average accuracy correction
factor could not be determined, a worst case accuracy correction factor was
used. The worst case accuracy correction factor was based on a matrix spike
percent recovery of 20 percent (the lowest percent recovery that the BOAT
methodology allows). The calculated accuracy correction factor in this worst
case then equals 5 (100 divided by 20).
6.3 Calculation of BOAT Treatment Standards
Calculation of BOAT treatment standards involves three steps. These
are: (1) accuracy correction of the treatment performance data to take into
account any analytical interferences associated with the chemical make-up of
the samples; (2) determination of a variability factor specific to each
constituent in a treatment performance data set to correct for normal
variations in the performance of a particular technology over time; and (3)
calculation of the treatment standard which is equal to the average effluent
concentration multiplied by the accuracy correction factor multiplied by the
variability factor. Treatment standards calculated for each BOAT List
constituent being regulated are presented in Table 6-10.
6-3
-------
TABLE 6-1
VOLATILE VARIABILITY FACTOR CALCULATION
VOLATILES ITD VARIABILITY
FACTOR
Acrylonitrile 4.83045
Benzene 13.5252
Chloroetbane 5.34808
Chlorofora 3.71334
Chloronethane 3.79125
1,1-Dichloroethane 5.88383
1,2-Djchloroethane 8.22387
1,1-Dichloroethene 2.4723
Trans-1,2-Dichloroethene 5.34808
Nethylene Chloride 3.86915
Tetrachloroetbylene 5.34808
Toluene 7.9506
1,1,1-Trjchloroethane 5.34808
l'l,2-Trichloroeth2ne 5.34808
Tricbloroetbvlene 5.34808
Vinyl Chloride 5.34808
AVERAGE = 5.7310
VOLATILES VF = 5.7310
6-4
-------
TABLE 6-2
SEHVOLATILE VARIABILITY FACTOR CALCULATION
VOLATILE ITD VARIABILITY
FACTOR
ACID NEUTRALS
2,4-Dinetnylphenol 3.2565
4,6-Dnutro-b-cresol 11.5417
2,4-Dinitrophenol 2.45842
4-Nitrophenol 2.47783
Phenol 2.49705
AVERAGE = 4.4463
ACID NEUTRAL SEHIVOLATILES VF = 4.4463
BASE NEUTRALS
Acenaphthalene 5.89125
Acenaphthene 5.89125
Anthracene 5.89125
Benzo (a) anthracene 5.89125
Benzo (a) pvrene 5.89125
Benzo fkj nuoranthene 5.89125
Bis(2-ethylheicyl) phthalate 5.91768
Chrysene ; J ' K 5.89125
Dfetbyl pbtHalate 4.75961
Dinethyl pnthalate 4.63833
Da-n-bityl pbthalate 3.23768
Fluoranthene 5.89125
Fluorene 5.89125
Naphthalene 5.89125
Nitrobenzene 4.83045
Phenanthrene 5.89125
P>Trene . 5.89125
AVERAGE = 5.5340
BASE NEUTRAL SEHVOLATILE VF = 5.5340
6-5
-------
TABLE 6-3
VOLATILE ACCURACY CORRECTION FACTOR CALCULATIONS - EPA DATA
VOLATILE
PERCENT RECOVERY
LOW
WAO A WAO B K103/K104 VALUE ACF
n-Butanol
Isobutanol
Hethanol
3-Chloropropionitrile
1,4-Dioxane
2-Ethoxyethanol
Ethylene oxjde
Metnacrylomtrile
Trichloroethene
1,1-Dichloroethene
Benzene
Chlorobenzene
Toluene
VOLATILE ACF = 100/100 = 1.0
82
97
93
159
152
157
103
150
87
108
165
98
94
92
88
171
153
172
37
158
89
110
190
110
84
102
99
162
155
161
50
165
87
120
110
88
87
93
89
85
182
153
161
22
169
88
120
120 76 94
90
90
82
89
85
159
152
157
22
150
87
108
76
88
87
1.2
1.1
1.2
1.0
1.0
1.0
4.6
1.0
1.2
1.0
1.3
1.1
1.2
AVERAGE = 103.23
SET AT = 100
MOTES: If Percent Recovery is less, than 201 that value
is dropped froi consideration.
If Percent Recovery is greater than 100* that
recovery is set at 100*.
To deteraine an Accuracy Correction Factor [ACF] fqr
Volatiles, the average of all lov values for volatile
constituents is calculated. ACF = 100/ avg. lov value.
6-6
-------
TABLE 6-4
SEHIVOLATILE ACCURACY CORRECTIOH FACTOR CALCDLATIOHS - EPA DATA
SEHIVOLATILES
Acid Neutrals
p-Chloro-B-cresol
2-Chlorophenol
Pentachlophenol
4-Nitrophenol
Phenol
21
55
68
20
94
12
55
82
13
82
PERCENT RECOVERY
LOW
WAOA NAOB K103/K104 VALDE
58
55
0
43
42
21 26
AVERAGE
21
55
68
20
21
37
ACP
4.8
1.8
1.5
5.0
4.8
ACID NEUTRAL SEHIVOLATILES ACF = 100/37 =2.7
Base Neutrals
Acenaphtbene 72 86 79
1,4-Dichlorobenzene 65 74 52
2,4-Dinitrotoluene 78 112 69
N-nitroso-di-n-propylanine 79 92 51
Pyrene 68 67 84
1,2,4-Trichlorobenzene 73 87 61
Nitrobenzene
Aniline
BASE NEUTRAL SEHIVOLATILES ACF - 100/72.3 = 1.38
115 116
91 97
72
52
69
61
115
91
1.4
1.9
1.5
2.0
1.5
1.6
1.0
1.1
AVERAGE = 72.3
NOTES: If Percent Recovery is less, than 20$ that value
is dropped froi consideration.
If Percen^ Recovery is greater than 1001 that
recovery is-set at 1001.
To detertine an Accuracy Correction Factor [ACT] for
Volat;les, the average of all low values for volatile
constituents is calculated. ACT = 100/ avg. lov value.
6-7
-------
TABLE 6-5
VOLATILE ACCURACY CORRECTION FACTOR CALCULATIONS
FOP DOW LEACHATE DATA
PERCENT RECOVERY
LOW
VOLATILE US USD VALUE ACF
Methanol 100 100 100 i.o
Isobutyl alcohol 101 101 101 1.0
n-butyl alcohol 105 99 99 1.01
1,1-Dichloroethene 130 132 130 1.0
Trichloroethene 94 94 94 1.06
Chlorobenzene 98 96 96 1.04
Toluene 100 100 100 1.0
Benzene 94 94 94 1.06
AVERAGE = 101.75
VOLATILE ACF = 100/100 =1.00 SET AT = 100
MOTES: I.f Percent Recovery js less, than 201 that value
is dropped froi consideration.
If Percent Recovery is greater than 100* that
recovery is set at 1001.
To detenine an Accuracy Correction Factor [ACF] for
Volat^les, the average of all low values for volatile
constituents is calculated. ACF = 100/ avg. lov value.
6-8
-------
TABLE 6-6
VOLATILE ACCURACY CORRECTION FACTOR CALCULATIONS
FOR CWH LEACHATE DATA
VOLATILES
Acetone
n-Butyl Alcohol
Isobutyl Alcohol
Xethyl Ethyl Ketone
Hethinol
Hethyl Isobutyl Ketone
PERCENT
REMOVAL
99
112
112
99
112
99
ACF
1.01
1.0
1.0
1.01
1.0
1.01
AVERAGE = 105.5
VOLATILE ACF = 100/100 =1.00 SET AT = 100
NOTES: If Percent Recovery is less than 20* that value
is dropped froo consideration.
If Percent Recovery is greater than 1001 that
recovery is set at 1001.
To deternine an Accuracy Correction Factor [ACF] fgr
Volatiles, the average of all lov values for volatile
constituents is calculated. ACF = 100/ avg. low value.
6-9
-------
TABLE 6-7
SEKIVOLATILE ACCURACY CORRECTION FACTOR CALCULATIONS
FOR DOW LEACHATE DATA
SEHIVOLATILES
Acid Neutrals
Pentachlorophenol
Phenol
2-Chlorophenol
p-chloro-n-cresol
4-Nitrophenol
MS
79
71
72
79
109
PERCENT RECOVERY
HSD
83
74
73
84
100
AVERAGE =
LOW
VALUE
79
79
100
80.2
ACF
1.3
1.4
1.4
1.3
1.0
ACID NEUTRAL SEHIVOLATILES ACF = 100/80.2 =1.25
Base Neutrals
1,2,4-Trichlorobenzene 80
Acenapthene 81
2,4-Dimtro toluene 84
Pyrene 87
N-Nitroso-n-propylanine 60
1,4-Dichlorobenzene 74
89
86
83
105
65
82
AVERAGE =
80
81
83
87
60
74
1.3
1.2
1.2
1.1
1.7
1.4
77.5
BASE NEUTRAL SEHIVOLATILES ACF = 100/77.5 = 1.29
NOTES: Jf Percent Recovery is less, than 201 that value
is dropped frOs consideration.
If Percent Recovery is greater than 1001 that
recovery is set at 100%.
To deternine an Accuracy Correction Factor [ACF] for senivolatiles,
the average of all low values for senivolatile constituents is
calculated. ACF = 100/ avg. low value.
6-10
-------
TABLE 6-9
ORGANOPHOSPHORUS INSECTICIDE ACCURACY CORRECTION FACTOR
CALCULATIONS FOR DOW LEACHATE DATA
ORGANOPHOSPBORUS
INSECTICIDES
Prorate
Disulfoton
Methyl Parathion
MS
67
83
102
PERCENT R
MSD
71
87
106
ECOVERY
LOW
VALDE
67
83
102
ACF
1.5
1.2
1.0
AVERAGE = 84.0
ORGAHOPHOSPHORUS INSECTICIDE ACF = 100/84.0 = 1.19
NOTES: Jf Percent Recovery is less than 201 that value
is dropped fron consideration.
If Percent Recovery is greater than 1001 that
recovery is set at 100$.
TO determine an Accuracy Correction Factor [ACF] for organopbospborus
insecticides, the average of all lov values for organopnosphorus
insecticides constituents is calculated. ACF = 1007 avq. lov value.
6-12
-------
TABLE 6-10
BOAT TREATMENT STANDARDS FOR KDLTI-SOCRCE
LEACHATE AND ORGANIC U AND P WASTEWATERS
1
CONSTITOEHTS
Acetone
Acena
Acena
Shthalene
btbene
Acetohitrile
Acrolein
Acetophenone
2-Acetylaninofluorene
Acryionitrile
Aldfin
4-An;nobiphenyl
Aniline
3 or P
Code
0002
0003
P003
0004
0005
0009
P004
C012
Anthracene
Aranite
Aroclor 1016
Aroclor 1221
Aroc
Aroc
Aroc
Aroc
Aroc
or 1232
or 1242
or 1248
or 1254
or 1260
alpha-BHC
beta-BHC
delta-BHC
gamia-BHC
Benzene
Benz( a) anthracene
Benzo
Benzo
Benzo
Benzo
Brpno
Tribr
alpyrene
bjfluoranthene
gni)perylene
K)fiuoranthene
ichlorouethane
ononethane
Brononethane
4-Bronophenyl phenyl ether
n-Butyl alcohol
Butyl benzyl phthalate
2-sec-Buty 1-4 , 6-dinitrophenol
Carbon tetrachloride
Carbon disulfide
Chlordane
p-Chloroaniline
chlorobenzene
Chlorobenzilate
0129
0129
0129
0129
0019
0018
C022
0225
0029
0030
0031
P020
0211
0036
P024
0037
0038
2-Chloro-l ,3-butadiene
Chlorodibronouethane
Chloroethane
Bisi 2-chloroetboxy Methane
Bis(2-chloroethyl (ether
Chloroforn
Bis(2-chloroisopropyl)ether
p-cnloro-D-cresol
chloroaethane
0024
0025
C044
0027
0039
0045
LONG TERH
Ava. Eff
(Ppn)
0.10
0.010
0.010
0.030
0.050
0.0029
0.010
0.050
0.0015
0.024
0.26
0.010
0.10
0.00091
0.0010
0.00092
0.0012
0.00093
0.000967
0.000967
0.000010
0.000010
0.0016
0.00012
0.010
0.010
0.010
0.010
0.0010
0.010
0.061
0.11
0.020
0.010
2.0
0.0030
<0.0087
0.010
0.0050
0.00023
<0.120
0.010
0.018
0.010
0.010
0.050
0.010
0.006
0.012
0.010
0.004
0.050
VF
2.8
5.9
5.9
5.7
5.7
2.8
5.9
4.8
2.8
5.5
2.8
5.9
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
14
5.9
5.9
5.5
5.5
5.9
5.7
5.7
5.7
5.5
2.8
5.5
2.8
5.7
2.8
2.8
2.8
5.7
5.5
5.7
5.7
5.3
2.8
5.5
3.7
5.5
4.4
3.8
BOAT TPEATHEBT
ACF STANDARD
(PPO)
1.01
1.3
5.0
1.1
1.3
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
1.0
2.7
1.0
5
1.4
1.3
0.28
0.059
0.059
0.17
0.29
0.010
0.059
0.24
0.021
0.13
0.81
0.059
0.36
0.013
0.014
0.013
0.017
0.013
0.014
0.014
0.00014
0.00014
0.023
0.0017
0.14
0.059
0.061
0.055
0.0055
0.059
0.35
0.63
0.11
0.055
5.6
0.017
0.066
0.057
0.014
0.0033
0.46
0.057
0.10
0.057
0.057
0.27
0.036
0.033
0.046
0.055
0.018
0.19
6-13
-------
TABLE 6-10 (Continued)
BOAT TREATMENT STANDARDS FOR HULTI-SOCRCE
LZACHATE AND ORGANIC U AND P WASTEWATERS
U or P
CONSTITUEHTS Code
2-Chloronaphthalene
2-Chlorophenol
3-Chloropropene
' Chrysene
ortno-Cresol
neta/para-Cresol
Cyclohexanone
1 , 2-D;brono-3-chloropropane
1,2-Dibrouoethane
Dibropoaethane
2,4-Dichlorophenoxyacet:c acid
DDE
DDT
Dibenzofa.eipyrene
Dibenz(a,h)anthracene
Ir is ( 2 , 3-dibronopropy 1 )
t-Djchlotobentene
o-Djchlorobenzene
p-Dicblorpbenzene
Dichlorodifluorone thane
1,1-Djchloroe thane
l,2-D;chloroethane
1,1-Dichlorpethylene
Trans:1.2-Dichloroethene
2,4-Djchlorophenol
2,6-Dichlorophenol
1.2-Dichloroprppane
T?ans-l,3-Dic6loropropene
c js-1 , 3-Dichloropropene
Djeldrin
Diethyl phthalate
2,4-Dinethylphenol
Dnethyl phthlate
Di-n-butyi phthalate
1,4-Djnjtrobenzene
4 ,6-Dimtro-o-cresol
2,4-Djnjtrophenol
2,4-D;n;trotoluene
2,6-Dinitrotoluene
Dj-n-octyl phtbalate
Di -n-propy Jnitrosoanine
Diphenylaeine
Diphenylnitrosaaine
1 . 2-Di6heny Ihydraz me
• 'JIN'* • *
1,4-Dioxane
Disulfoton
0047
D048
C050
0052
U052
U057
C066
U067
U068
C240
C060
C061
C061
D063
0235
0071
0070
0072
0075
0076
0077
0078
0079
0081
0082
0083
0084
0084
P037
0101
P047
P048
0105
0106
Dili
0108
P039
LOHG TERN
Avg. ffi
(PP")
0.010
0.010
0.0063
0.010
0.025
0.17
0.10
0.020
0.0048
0.020
0.052
0.0016
0.0022
0.00028
0.010
0.010
0.020
0.010
0.016
0.016
0.040
0.010
0.026
0.010
0.010
0.010
0.010
0.15
0.0063
0.0063
0.0012
0.043
0.011
0.010
0.018
0.058
0.024
0.050
0.058
0.10
0.0030
0.073
0.095
0.073
0.016
0.021
0.0050
VF ACF
5.5
4.4
5.7
5.9
4.4
4.4
2.8 1.3
5.7
5.7
5.7
2.8 5.0
2.8 5.0
2.8 5.0
2.8 5.0
5.9
5.5
5.5
2.8 1.3
5.5
5.5
5.7
5.9
8.2
2.5
5.3
4.4
4.4
5,7
5.7
5.7
2.8 5.0
4.8
3.3
4.6
3.2
5.5
12
2.5
5.5
5.5
5.5
5.5
5.5
5.5
5.5
5.7
2.8 1.2
BOAT TREATMENT
STANDARD
(PPn)
0.055
0.044
0.036
0.059
0.11
0.77
0.36
0.11
0.028
0.11
0.72
0.023
0.031
0.0039
0.061
0.055
0.11
0.036
0.088
0.090
0.23
0.059
0.21
0.025
0.054
0.044
0.044
0.85
0.036
0.036
0.017
0.20
0.036
0.047
0.057
0.32
0.28
0.12
0.32
0.55
0.017
0.40
0.520
0.40
0.087
0.12
0.017
6-14
-------
TABLE 6-10 (Continued)
BOAT TREATMENT STANDARDS FOR MULTI-SOURCE
LEACHATE AND ORGANIC U AMD P WASTEWATERS
CONSTITUENTS
Endosulfan I
Endosulfan II
Endosulfan sulf ate
Endrin
Endrin aldehyde
Ethyl acetate
Ethyl benzene
Ethyl ether
Bis[2-ethylhexyl)phthalate
Ethyl netnacryiate
Ethylene oxide
Fanphur
Fluoranthene
Fluorene
Heptac
Heptac
Hexac
Hexac
Bexac
Hexac
Hexac
Hexac
hlor
hlor epoxide
ilorobefizene
ilorobutadiene
orocyclopentadiene
orodibenzofurans
iorodibenzo-p-dioxins
iloroethane
Hexachloropropene
Indeno(l,2,3-cd)pyrene
lodonethane
Isobutyl alcohol
Isodrin
Isosafrole
Kepone
Nethacrylonitrile
Methanol
Methapyrilene
Nethofcyclor
3-Nethylcholanthrene
4,4'-Hethyleiiebjs
2-chloraniline)
Hethy
Metby
Netny
Metby
Methy
Hetty
Naphtf
ene chloride
ethyl ketone
isobutyl ketone
nethacrylate
nethaitesulfonate
parathion
alene
2-Naphthylanine
p-Nitroaniline
Nitrobenzene
5-Nitro-o-toluidine
4-Njtrophenol
N-Nitrosod}ethylanine
N-Njtrosodinetflylanine
N-Nitrosodi-n-butylanine
H-Nitrosonetbyletflylanine
N-NitrosonprphpUne
N-Njtrosopiperidine
n-Nitrosopyrrolidine
Parathion
D or P
Code
P050
P050
P050
P051
P051
U112
U117
U118
P097
U120
P059
P059
0127
G128
U130
D131
D243
D137
0138
0140
P060
0141
0142
0152
0154
0155
0247
0157
0158
0080
0159
0161
0162
P071
0165
U168
P077
0169
U181
U170
0174
P082
0172
0179
0180
P089
LONG TERH
Avg. Eff
UP)
0.0017
0.0020
0.0020
0.00020
0.0018
0.060
0.010
0.021
0.047
0.050
0.021
0.0050
0.012
0.010
0.000083
0.0011
0.010
0.010
0.01026
0.0000045
0.0000045
0.010
0.0064
0.0010
0.050
2.0
0.0015
<0.031
0.00032
0.050
2.0
<0.031
0.018
0.0010
0.090
0.023
0.10
0.050
0.0500
0.0050
0.00500
0.010
0.095
0.005
0.014
0.058
0.050
0.073
0.073
0.073
0.073
0.073
0.0024
0.0024
0.0050
VF
2.8
2.8
2.8
2.8
2.8
5.7
5.7
5.7
5.9
2.8
5.7
2.8
5.9
5.9
2.8
2.8
5.5
5.5
5.5
2.8
2.8
5.5
5.5
5.5
3.8
2.8
2.8
1.9
2.8
4.8
2.8
1.9
2.8
5.5
- 5.5
3.9
2.8
2.8
2.8
2.8
2.8
5.9
5.5
5.5
4.8
5.5
2.5
5.5
5.5
5.5
5.5
5.5
5.5
5.5
2.8
ACF
5.0
5.0
5.0
5.0
5.0
1.0
1.2
5.0
5.0
5.0
5.0
1.0
5.0
1.4
1.2
1.0
1.4
5.0
1.0
1.0
1.0
1.3
1.0
1.2
BDAT TREATMENT
STANDARD
(W»)
0.023
0.029
0.029
0.0028
0.025
0.34
0.057
0.12
0.28
0.14
0.12
0.017
0.068
0.059
0.0012
0.016
0.055
0.055
0.057
0.000063
0.000063
0.055
0.035
0.0055
0.19
5.6
0.021
0.081
0.011
0.24
5.6
0.081
0.25
0.0055
0.50
0.089
0.28
0.14
0.14
0.018
0.014
0.059
0.52
0.028
0.068
0.32
0.12
0.40
0.40
0.40
0.40 •
0.40
0.013
0.013
0.017
6-15
-------
TABLE 6-10 (Continued)
BOAT TREATMENT STAHDARDS FOR MULTI-SOURCE
LEACHATE AND ORGANIC D AND P WASTEWATEKS
CONSTITUENTS
Pentachlorobenzene
Pentachlorodibenzofurans
Pentachlorodibenzo-p-dioxins
Pentachloronitrobenzene
PentachlQrophenol
Phenacetin
Phenanthrene
Phenol
Phorate
Phthalic anhydride
Ethyl cyanide
Pronaniae
Pyrene
Pyridine
Safrole
Silvex
2,4,5-T
1,2, 4 ,5-Tetrachlorobenzene
Tetrachlorodjbenzofurans
Tetrachlorodibenzo-p-dioxins
1,1,1, 2-Tetrachloroethane
1,1, 2, 2-Tetrachloroethane
Tetracbloroethene
2,3,4 , 6-Tetrachlorophenol
Toluene
Toxaphene
1 , 2 , 4-Tr Jchlorobenz ene
1,1,1-Trjchloroethane
LLZ-Tricbloroethane
Tr]cnloroethene
TrichlorononofluoroBe thane
2,4, 5-Tr ;chlorophenol
2 , 4 , 6-Tr ^chlorophenol
1,2, 3-Tr;chloropropane
l,l,2-Tnchlororl,2,2-
trifluoroethane
Vinyl chloride
§" lene(s)
* i » '
anide
write
Sulfide
Antinqny
Arsenic
Bariun
BeryUiun
Cadniun
ChroniUB( total)
Copper
Lelfl
Mercury
Hickel
Seleniun
Silver
Thall4UB
Vanadiun
Zinc
0 or P
Code
0183
0185
0051
0187
0051
0188
P094
P101
C192
C051
U196
C203
D017
0207
0208
0209
0210
0220
P123
0226
0227
0228
0121
0043
0239
D003
P056
P010
P013
D006
0032
P110
P065
P103
P099
P114
P119
LONG TERM
Avg. Eff
(PP»)
0.010
0.0000025
0.0000045
0.010
0.020
<0.031
0.010
0.010
0.0050
0.015
0.050
<0.029
0.011
0.0024
<0.031
0.13
0.13
0.010
0.0000045
0.0000045
0.010
0.010
0.010
0.0068
0.010
0.00068
0.010
0.010
0.010
0.010
0.0070
0.050
0.010
0.15
0.010
0.050
0.056
0.18
i5
0.47
0.34
0.28
0.20
0.049
0.070
0.39
0.080
0.036
0.22
0.20
0.070
0.34
0.0030
0.23
VF
5.5
2.8
2.8
5.5
4.4
1.9
5.9
2.8
2.8
2.8
4.8
2.3
5.9
5.7
1.9
2.8
2.8
5.5
2.8
2.8
5.7
5.7
5.3
4.4
8.0
2.8
5.5
5.3
5.3
5.3
2.8
2.8
2.8
5.7
5.7
5.3
5.7
6.7
2.4
2.8
4.1
4.1
4.1
4.1
4.1
5.3
3.3
3.5
4.1
2.5
4.1
4.1
4.1
2.8
4.4
ACF
5.0
5.0
1.4
1.4
1.5
1.6
1.4
1.4
5.0
5.0
5.0
5.0
5.0
1.0
1.3
1.3
5.0
5.0
BOAT TREATMENT
STANDARD
(PP")
0.055
0.000035
0.000063
0.055
0.089
0.081
0.059
0.039
0.021
0.069
0.24
0.093
0.067
0.014
0.081
0.72
0.72
0.055
0.000063
0.000063
0.057
0.057
0.056
0.030
0.080
0.0095
0.055
0.054
0.054
0.054
0.020
0.18
0.035
0.85
0.057
0.27
0.32
1.2
35
14
1.9
1.4
1.2
0.82
0.20
0.37
1.3
0.28
0.15
0.55
0.82
0.29
1.4
0.042
1.0
6-16
-------
7.0 ACKNOWLEDGEMENTS
This background document was prepared for the U.S. Environmental
Protection Agency, Office of Solid Waste, by Radian Corporation under Contract
No. 68-W9-0072. This document was prepared under the direction of Richard
Kinch, Acting Chief, Waste Treatment Branch; Larry Rosengrant, Section Head,
Treatment Technology Section; Jerry Vorbach, Project Officer; and Mary
Cunningham, Project Manager. Steve Silverman served as EPA legal advisor.
The following personnel from Radian Corporation were involved in
preparing this document: John Williams, Program Manager; Mary Willett,
Project Director; and the Radian engineering team, Stephanie Hansen, and
Chrisanti Haretos.
7-1
-------
8.0 REFERENCES
1. USEPA. Methodology for Developing Treatment Standards. U.S.
Environmental Protection Agency, Washington, D.C., 1988.
2. USEPA. Best Demonstrated Available Technology (BOAT) Background
Document for Aniline Production Treatability Group (K103. K104).
U.S. Environmental Protection Agency, Washington, D.C., 1988.
3. USEPA. Best Demonstrated Available Technology (BOAT) Background
Document for K062. U.S. Environmental Protection Agency,
Washington, D.C., 1988.
4. USEPA. Best Demonstrated Available Technology (BOAT) Background
Document for F001-F005 Spent Solvents. Volume 2, U.S. Environmental
Protection Agency, Washington, D.C., 1986.
5. Meidl, J. and Peterson, R., Zimpro/Passavant, Inc., 1987. The
Treatment of Contaminated Groundwater and RCRA Wastewater at Bofors-
Nobel, Inc., 4th National RCRA Conference on Hazardous Waste and
Hazardous Materials (HMCRI), Washington, D.C.
6. Hoffman, M. and Oettinger, T., Zimpro/Passavant, Inc., 1987.
Landfill Leachate with the PACTR system. 60th Annual Meeting of the
Central States Water Pollution Control Association. St. Paul, MN.
7. Dietrich, M., et. al., Zimpro/Passavant, Inc., 1988. Removal of
Pollutants From Dilute Wastewater by the PACT" Treatment Process.
Environmental Progress. 7:143 -149.
8. Dietrich, M., et. al., Zimpro/Passavant, Inc., 1985. Wet Air
Oxidation of Hazardous Organics in Wastewater. Environmental
Progress. 4:171-177.
9. Dietrich, M., et. al., Zimpro/Passavant, Inc., 1984. Demonstration
of Full-Scale Wet Air Oxidation of Hazardous Wastes. Rothschild,
WI: Zimpro Inc.
10. USEPA. Onsite Engineering Report for Zimpro/Passavant Inc. -
Rothschild. WI. U.S. Environmental Protection Agency, Washington,
D.C., October 1989.
11. USEPA. U.S. Environmental Protection Agency, Officer of Water
Regulations and Standards. Development Document for Effluent
Limitations Guidelines New Source Performance Standards and
Pretreatment Standards for the Organic Chemicals and the Plastics
and Synthetic Fibers Point Source Category. Volumes I and II. U.S.
Environmental Protection Agency, Washington, D.C., 1987.
8-1
-------
12. USEEA. U.S. Environmental Protection Agency, Office of Water
Regulations and Standards. Development Document for Effluent
Limitations Guidelines New Source Performance Standards for the
Metal Finishing Point Source Category. U.S. Environmental
Protection AGency, Washington, D.C., 1983.
13. USEPA. U.S. Environmental Protection Agency, Office of Water
Regulations and Standards. Development Document for Effluent
Limitations Guidelines and Standards for the Nonferrous Metals
Manufacturing Point Source Category. Volume I, U.S. Environmental
Protection Agency, Washington, D.C. 1988.
14. USEPA. U.S. Environmental Protection Agency, Office of wAter
Regulations and Standards. Development Document for New Source
Performance Standards and Pretreatment Standards for the Inorganic
Chemicals Manufacturing Point Source Category. U.S. Environmental
Protection Agency, Washington, D.C., 1982.
15. USEPA. 1989. Office of Research and Development. Computer
printout: Data on wastewater treatment from the WERL treatability
database. Retrieved 02/89. Cincinnati, OH: U.S. Environmental
Protection Agency.
16. USEPA. 1989. PCS. Computer printout: Facilities with
quantity/concentration data from the National Pollutant Discharge
Elimination System (NPDES). Retrieved 09/89. Washington, D.C.:
U.S. Environmental Protection Agency.
17. USEPA. Treatment Technology Background Document. U.S.
Environmental Protection Agency, Washington, D.C., June 1989.
18. American Public Health Association, American Water Works
Association, and Water Pollution Control Federal. 1985. Standard
Methods for the Examination of Water and Wastewater. Sixteenth
Edition. Washington, D.C.
19. USEPA. 1990. U.S. Environmental Protection Agency, Office of Solid
Waste. Final Best Demonstrated Available Technology (BOAT)
Background Document for U and P Wastes and Multi-Source Leachate
(F039). Volume B: U and P Wastewaters and Nonwastewaters With
Methods of Treatment as Treatment Standards. Washington, D.C.:
U.S. Environmental Protection Agency.
8-2
-------
APPENDIX A
Industry Characterization
A-l
-------
UASTECODE NAME
==================r uses E==
TABLE A-1
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U001 Acetaldehyde
NJ
U002 Acetone
U003 Acetonitrile
Food Processing
Plastics and Resins Manufacturing
Dyes and Pigments Manufacturing
Cosmetics and Fragrances
Organic Chemical Manufacturing
Agricultural Chemical Manufacturing
Film
Fiber Manufacturing
Electronic Components Manufacturing
Paint Manufacturing
Plastics and Resins Manufacturing
Pharmaceutical Manufacturing
Explosives
Organic Chemical Manufacturing
Printing
Synthetic flavor ingredient
Manufacture of resins and plastics
Manufacture of dyes
Manufacture of perfumes
Chemical intermediate for pyridine, pyridine bases.
pentaerythritol, 1,3-butylene glycol, chloral,
glyoxat. crotonaldehyde. acetaldehyde 1,1-dicnethylhydrazone,
acetaldehyde cyanohydrin, acetaldehyde oxime,
paraldehyde, metaldehyde, halogenated derivatives,
acetaldol, sodium sulphite addition product,
acetic anhydride, ethylidene diacetate, alkyl emine,-
ethyl acetate, isobutyl acetate, lactic acid,
acetic acid, peracetic acid
Monomer for polyacetaldehyde and comonomer for polymers
Chemical intermediate for pesticides
Chemical intermediate for photographic formulations
Alcohol denaturant
Spinning solvent for cellulose acetate
Cleaning and drying electronic parts
Solvent for paints, varnishes, lacquers
Solvent for resins and plastics
Solvent in the manufacture of Pharmaceuticals
Manufacture of smokeless powder
Solvent for fats, oils waxes
Manufacture of mesityl oxide, acetic acid, diacetone,
alcohol, chloroform, iodoform, bromoform, acetic anhydride
Chemical intermediate for methacrylates,
methyl isobutyl ketone, methyl isobutyl carbinol,
bisphenol A, isophorone
Solvent for printing inks
Deodorizers for specialty naphthas
Solvent for inorganic compounds
Specialty solvent
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
WASTECOOE NAME
INDUSTRY USE (a)
U003 (continued)
OJ
U004 Acetophenone
Food Processing
Metal Finishing
Dyes and Pigments
U005 2,3-Acetylaminofluorene
Organic Chemicals
Pesticide Manufacturing
Petroleoum Refining
Phanmceut i ca I s/Med i c i ne
Dyes and Pigments Manufacturing
Plastics and Resins Manufacturing
Organic Chemical Manufacturing
Food Processing
Cosmetics and Fragrances
Tobacco
Construction
Polar solvent
Starting material for many nitrogen-containing compounds
I
Recrystallizing steroids
Extraction of fatty acids from fish liver,animal&veg. oils
Non-aqueous solvent for inorganic salts
Brightners for metal
Chemical intermediate -gamma-naphthaleneacetic acid,etc.
In miscellaneous operations for cyanide dyes
Medium for promoting ionization
In electrodinetic transducers and angular accelerometers
Solvent in non-aqueous titrations
Starting material thiamine.acetamidine, etc.
Solvent in hydrocarbon extraction processes
Chemical intermediate-pesticide manufacture
Coloring matter from some petroleum hydrocarbons
Separation of alkaloids from tissue extraction
Solvent for dyes
Specialty solvent for plastics and resins
Chemical intermediate for the odorant,
ethyl methyl phenylglycidate, the riot
control agent, 2-chloroacetophenone,
2-bromoacetophenone, for dyes. 3-nitroacetophenone
Flavoring agent in non-alcoholic beverages,
ice cream, candy, baked goods, gelatins,
and puddings
Fragrance ingredient in soaps, detergents,
creams, lotions, and perfumes
Flavoring in tobacco
In coal tar for road surfaces and roofing materials
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AMD P CHEMICAL PRODUCTS
UASTECOOE NAME
INDUSTRY
USE (a)
U005 (continued)
U006 Acetyl chloride
>
U007 AeryI amide
Pharmaceutical
Organic Chemicals Manufacturing
Medicine
Laboratory
Specialty Chemical
Dyes and Pigments
Pharmaceuticals
Agricultural Chemicals
Mining
Binder for electrodes in aluminum reduction process
Treatment of skin disorders
Waterproofing
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
Catalyst in chlorination of acetic acid
Production of acetamide
Production of acetyl sulfide
Testing for cholesterol
Determination of water in inorganic liquid
Chemical intermediate acetanilide preparation
Chemical intermediate acetophenone reparation
Qualitative organic analysis
Synthesis of dienestrol diacetate
Production of thioacetic acid
Chlorinating agent inorganic compounds and triarylcarbinols
Acetylat ing agent
Manufacture dyestuffs
Pharmaceuticals manufacturing
Sewage and waste treatment
Polyacrylamides manufacturing
Flocculating aid for precip. suspended solids from aqueous systems
Flocculants
Cross-linking agent
In soil-conditioning agents
In ore processing, ndhesives
Chemical intermediate in polyacrylamides
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
WASTECOOE NAME
INDUSTRY
USE (a)
U007 (continued)
U008 Acrylic acid
>
U009
Acrylonitrile
Paper and Textile
Building & Construction
Dyes and Pigments
Organic Chemicals Manufacturing
Textiles
Organic Chemical Manufacturing
Textiles
Cleaning Products
Leather and Tanning
Plastics end Resins Manufacturing
Agricultural Chemicals
Plastics
Water Treatment
Paper and textile sizes
Construction of dam foundations & tunnels ,
Synthesis of dyes
Reactive monomer & intermed. organic chemicals production
Permanent press fabrics
Chemical intermediate for ethyl acrylate, n-butyl acrylate,
methyl acrylate, 2-ethylhexyl acrylate. acrylate hydoxyethyl
Monomer for polyacrylic acid and salts
Comonomer with aeryI amide for polymers used as polymers
Surface coatings
Textile applications
Manufacture of polishes
Manufacture of leather
Production of water soluble resins and salts
Chemical intermediate antioxidants synthesis
In co-polymers with styrene and butadiene
Chemical intermediate surface-active agents
Comonomer for starch/acrylonitrile copolymers
Fumigant for mills and commodities (former use)
Synthetic soil blocks
Chemical intermediate for acrylamidoaminoethane sulfonic acid
v
Elastomers for hoses, gaskets & protective clothing
Chemical intermediate for fatty aminopropylamine & derivs.
Modifier for natural polymers
Comonomer for nitrile elastomers
In flocculants for water and waste treatment
Combnomer for alkyd/acrylonitrile copolymers
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
UASTECOOE NAME
INDUSTRY
USE (a)
U009 (continued)
>
U010 Hitocnycin C
U011 Amitrole
Agricultural Chemicals
Plastics
Paper Manufacturing
Petroleum
Adhesive and Sealants
Bottling
Dyes and Pigments
Textiles and Fibers
Food Processing
Pesticide Manufacturing
Pharmaceuticals
Plastics and Resins
Rubber
Medicine
Agricultural Chemicals
Photography
U012 Aniline
Organic synthesis to introd. cyanoethyl group
Comonomer with styrene for urethane polyether polyols
Chemical intermediate for adiponitrile & acrylamide '
Fumigating stored tobacco
In plastics for appliances.automobile interior,boats,RV bodies,etc.
Retention aids in papermaking ft flotation processes
Comonomer for barrier resins
Mobility control agents in crude oil recovery
Comonomer for acrylic acid
No information available
Bottles for soft drinks (use discontinued)
Chemical intermediate dyes
To improve the dye and working properties of acrylic fibers
Comonomer for acrylic and modacrylic fibers
Manufacture of blankets,draperies,upholstery,syn. furs,wigs
In apparel,carpeting,home furnishing,sandbags,filter cloths,etc.
Cyanoethylat ion of cotton
Applied to mi I ling,baking,food processing machinery
In insecticides
Pesticide fumigant for stored grain (former use)
Chemical intermediate Pharmaceuticals
Chemical intermediate for glutethimide (sedative)
No information available
Manufacturing nitrile rubbers
Medication
Herbicide for non-crop uses (aquatics, hardwood nursery stock)
Cotton defoliant
Herbicide for food crops (former use)
Plant growth regulator
Reagent in photography
Chemical intermediate for substituted aniline salts
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
== = = = = = === =====SKS3SSSSSS=S======================= ====
INDUSTRY
USE (a)
U012 (continued)
Plastics and Resins
Explosives
Agricultural Chemicals
Cosmetics/Fragrances
Dyes and Pigments
Photography-
Food Processing
Leather and Tanning
Organic Chemicals
Plastics and Resins Manufacturing
Paper Manufacturing
Pesticides Manufacturing
Isocyanate synthesis
Catalyst and stabilizer for hydrogen peroxide synthesis ,
Chemical intermediate for 4-Anilinophenol
Solvent
Vulcanization accelerator
Chemical intermediate for hydroquinone
Cellulose as a precursor
Manufacture shoe blacks
Azeotropic agent in manufact. of anhydrous hydrazine
Chemical intermediate for methylenediisocyanate
Manufacture isocyanates for urethane foam
Manufacture explosives
Manufacture of teryl & optical whitening agents
Chemical intermediate for corrosion inhibitors
Manufacture herbicides, fungicides
Manufacture perfumes
Chemical intermediate for dyes & pigments
In situ dyeing agent
Manufacture photographic chemicals
In synthesis of intermediates for artificial sweeteners
Component of skin stains
Manufacture of rigid polyurethanes
Component of lacquers & wood stains
Chemical intermediate for specialty resins & eyeIohexyI amine
Manufacture resins,varnishes
Paint removers
Analytical reagent in paper chemistry
Chemical intermediate for pesticides
-------
TABLE A-1 (Continued)
INDUSTRIAL USE Of u AW) P CHEMICAL PRODUCTS
UASTECGOE NAME
INDUSTRY
USE (a)
U012 (continued)
UOH Auramine
>
oo
U015 Azaserine
U016 Benz(c)acridine
U017 Benzal chloride
U018 Benz(a)anthracene
U019 Benzene
Petroleum Refining
Pharmaceutical Manufacturing
Printing
Rubber
Dyes and Pigments
Pharmaceuticals
Agricultural Chemicals
Medicine
Pharmaceut i caIs/Medi c i ne
Construction
Pharmaceutical
Organic Chemicals Manufacturing
Chemical Research
Specialty Chemical
Dyes and Pigments Manufacturing
Chemical Research
Organic Chemicals Manufacturing
Medicine
Dyes and Pigments
Ho information available
Chemical intermediate for Pharmaceuticals .
Printing inks,cloth marking inks
Chemical intermediate for rubber processing
Dye for lacquers,pen inks,carbon papers,typewriter ribbons
Food dye in some countries
Dye for paper,cardboard,textiles,leather,oils,waxes,alcoholic solvents
Preparation of solvent yellow 34
S«oke dye
Antiseptic
Fungicide
Research chemical
Antineoplastic agent, antibiotic, abortifacient, antifungal
In coal tar for road surfaces and roofing materials
Binder for electrodes in aluminum reduction process
Treatment of skin disorders
Waterproofing
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
Research chemical
Preparation of benzoyl chloride
Manufacture of cimamic acid
Chemical intermediate for benzaldehyde
In dyes
No cocnnercial use in U.S.
Manufacture of styrenes, phenols, cyclohexanes
Manufacture of medicinal chemicals
Manufacture of dyes
Manufacture of artificial leather, linoleum, oil cloth
-------
=====================
UASTECODE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U019 (continued)
U020 BenzenesulfonyI chloride
U021 Benzidine
U022 Benzo(a)pyrene
Plastics and Resins
Soap
Pesticide
Specialty Chemical
Pesticide
Laboratory
Food
Paper
Sugar
Medicine
Laboratory
Specialty Chemical
Printing
Plastics
Dyes and Pigments
Rubber
Construction
Pharmaceutical
Manufacture of airplane dopes
Manufacture of varnishes and lacquers |
Solvent for waxes, resins, oils, etc.
Manufacture of detergents
Manufacture of pesticides
Chemical intermediate for benzonitrile
Chemical intermediate for thiophenol
Chemical intermediate for glybuzole
Chemical intermediate for benzene sulfonamides
Chemical intermediate for N-2-chloroethyl amides
Esters formerly used as insecticides,miticides.fenson acaricide
Reagent for Freiedl-Crafts sulfonulation
Reagent for hydrogen peroxide in milk
Production of security paper
Spray reagent for sugars
Used to verify TLC bands attributed to blood (former use)
Stain in microscopy
Lab agent to detect cyanide & sulfate
Quantitative determination of nicotine
Organic synthesis
Used in security printing
Liquificat ion meadurement
Manufacture of plastic films
Chemical intermediate for AZO dyes
Stiffening agent in rubber compounding
In coal tar for road surfaces and roofing materials
Binder for electrodes in aluminum reduction process
Treatment of skin disorders
Waterproofing
-------
TABLE A-1 (Continued)
INDUSTRIAL USE Of u Am) P CHEMICAL PRODUCTS
UASTECOOE NAME
INDUSTRY
USE (a)
U029
(continued)
U030 4-Bromophenyl phenyl ether
U031 n-Butyl alcohol
U033 Carbon fluoride
U034 Trichloroacetaldehyde
U035 Chlorambucil
U036 Chlordane
U037 Chtorobenzene
U038 Chlorobenzilate
U039 p-Chloro-m-cresol
Agricultural Chemicals
Dyes and Pigments
Pesticides
Pharmaceuticals
Chemical Research
Pharmaceutical Manufacturing
Veterinary Medicine
Furniture Manufacturing
Organic Chemical Manufacturing
Petroleum
Pesticides
Medicine
Veterinary Medicine
Pesticide
Pesticide
Pesticide
Degreesing wool
Funigant for soil
I
Solvent in aniline dyes
Insect and rodent control in space and commodity fumigations
Methylat ing agent
Not in U.S.
Manufacture of Pharmaceuticals
Bactericide
Solvent for surface coatings
Chemical intermediate for ethylene glycol.
nonobutyl ethers, glycol ethers, plasticizers,
n-butyl acetate, n-butyl acrylate, butylamines,
2,4-0 esters
Dehydrating agent
Solvent for vegetable oils and alkaloids
Chemical intermediate in organic synthesis
Induce swelling of starch granules
Spraying and pouring of polyurethanes
Chemical intermediate for chloral hydrate
Chemical intermediate for herbicide trichloroacetic acid
Intermediate in manufacture of DDT,methoxychlor,DDVP,naled,trichlorofon
Not produced in U.S. (imported from U.K.)
Antineoplastic agent: leukemia,Hodgkins disease,matignant lymphomas.etc.
Antineoplastic agent
Insecticide
Manufacture of insecticide
Acaricide
External germicide
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
====s=======ssss==rssss======r££=ss=ssssass=
INDUSTRY
USE (a)
U041 n-Chloro-2,3-epoxypropane
Plastics and Resins
Paper Manufacturing
Agricultural Chemicals
Optics
Scavenging additive to trichloroethylene
Preparation of condensates with polyfunctional substancesj
Chemical intermediate for glycidyl acrytate and glycidyl methacrylate
Polymer coating materials in water supply systems
Reactive plasticizer
Comonomer for unmodified epoxy resins
Preparation of ion exchange resins,elastomers,solvents,plasticizers
Solvent for natural ft synthetic resins,gums,cellulose esters & ethers
Solvent for lacquers,cement for celluloid
Solvent for paints,varnishes,nail enamels
Comonomer for polyamide-epichlorohydrin resins
Raw Material for epoxy ft phenoxy resins
Heat stabilizer for plastics
High wet-strength resins for paper industry
Chemical intermediate for polythiols
Cross-1 ink ing agent for hydrogel sheet for temporary wound dressing
Stabilizer in chlorine-containing material
Intermediate in the production of beta-blocker, aryloxypropanolamine
Hair products
In formation of polythioaldane carboxylic acid oligomers in hair shampoo
Cross-linking agent for cyclodextrins
Production of poly(oxlyalkylene)ether derivatives
Co-stabilizer to enhance mixed-metal combination
Cross-linking agent in microencapsulation
Chemical intermediate for alkyl glyceryl ether sulfonate surfactants
Raw material for glycerol and glycidol derivatives
Chemical intermediate for glycidyl ethers,glycerin
Monomer or Comonomer in epichlorohydrin elastomers
Sporicide
Chemical intermediate for quaternary ammonium salts
-------
TABLE A-1 (Continued)
1KBUSTR1AL USE Of U AW P CHEMICAL PRODUCTS
UASTECODE NAME
INDUSTRY
USE (a)
U045
(continued)
Pharmaceut i caIs
Plastics
Rubber
Steel
T iiter
U046
Chlororaethyl methyl ether
U047
UOA8
UOA9
U050
2-Chloronaphthalene
2-Chlorophenot
4-Chloro-o-toluidine hydrochloride Dyes and Pigments
Chrysene
U051
Creosote
Construction
Pharmaceutical
Organic Chemicals Manufacturing
Chemical Research
Medicine
Anesthetic
Foaming agent
Manufacturing of synthetic rubbers
Solvent and diluent in butyl rubber production
Production of silicone resins and rubbers
Foaming agent stainless steel
Processing of timber products
Extractant for oils, fats and resins
Fluid for thermometric & thermostatic equipment
Chemical intermediate
Terminates polymerization of bakelite polysulfone
Industrial polymers
Alkylating agent & solvent in manufacture of water repellents
Intermediate in synthesis of chloromethylated compound
Preparation of ion-exchange resins
Chemical intermediate for dodecylbenzyl chloride
No information available
No information available
Produce AZO dyes for cotton,silk,acetate,nylon
Chemical intermediate for dyes
In coal tar for road surfaces and roofing materials
Binder for electrodes in aluminum reduction process
Treatment of skin disorders
Waterproofing
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
Research chemical
Antipyretic, styptic, astringent
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
==s=s:ss===:=======
UASTECOOE NAME
INDUSTRY
USE (a)
U051
(continued)
UOS2
U053
Cresols
Crotonaldehyde
I
>-•
v_n
U055 Cunene (Isopropylbenzene)
U056 Cyclohexane
U057 Cyclohexanone
Plastics and Resins
Veterinary Medicine
Pharmaceutical
Wood Preserving
Agricultural Chemicals
Organic Chemical Manufacturing
Plastics and Resins Manufacturing
Tire
Petroleum Refining
Agricultural Chemical Manufacturing
Military
Organic Chemical Manufacturing
Leather and Tanning
Organic Chemicals Manufacturing
Plastics and Resins
Paint
Laboratories
Organic Chemicals Manufacturing
Petroleum Refining
Organic Chemical Manufacturing
Plastics and Resins Manufacturing
Lubricant for die molds
Waterproofing agent
Parasiticide, deodorant
External antiseptic, disinfectant, expectorant, local anesthetic,
gastric sedative
Preservative
Herbicide manufacturing
Chemical intermediate for 2-ethylhexyl alcohol
Solvent for polyvinyl chloride
Preparation of rubber accelerators
Purification of lubricating oils
Manufacture of insecticides
Manufacture of tear gas
Organic synthesis
Leather tanning
Manufacture of phenol, acetone, acetophenone, a-methylstyrene
Solvent for lacquers and resins
Paint and varnish remover
Extraction of essential oils
Molecular weight determination
Manufacture of adipic acid, benzene, cyclohexyl chloride,
nitrocyclohexane, cyclohexanol, Cyclohexanone
Manufacture of solid fue\ for camp stoves
In fungicidal formulations
In recrystallization of steroids
Chemical intermediate in synthesis of caprolactam
Solvent for lacquers, wood stains, paint, and varnish removers
-------
TABLE A-1 (Continued)
IKDUSTRiAL USE OF U ASO P CHEMICAL PRODUCTS
UASTECOOE NAME
INDUSTRY
USE (a)
UOS7 (continued)
U059
U060
U061
U062
Daunomycin
ODD
DDT
Diallate
U063 Dibenzo(a>h)anthracene
U064 1,2,7,8-Dibenzopyrene
U066 1,2-Dibroroo-3-chloropropane
U067 Ethylene dibromide
Leather and Tanning
Pharmaceuticals
Pesticide
Pesticide
Agricultural Chemicals
Construction
Phai
eutical
Organic Chemicals Manufacturing
Construction
Pharmaceutical
Organic Chemicals Manufacturing
Medical Research
Agricultural Chemicals
Agricultural Chemicals
Plastics and Resins
Solvent for polyvinyl chloride and its copolymers
Spot remover and degreaser for leather
Antineoplastic agent, antibiotic (not produced in U.S.)
Monsystemic contact and stomach insecticide
Nonsystemic contact and stomach insecticide
Sprout inhibitor
Herbicide
In coal tar for road surfaces and roofing materials
Binder for electrodes in aluminum reduction process
Treatment of skin disorders
Waterproof i ng
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
In coal tar for road surfaces and roofing materials
Binder for electrodes in aluminum reduction process
Treatment of skin disorders
Waterproofing
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
Experimental carcinogen
Intermediate in organic synthesis
Commercial preparation for flame retardant
Soil fumigant for pineapple in Hawaii
Quarantine fumigant some fruits & veg.
Solvent for res ins,guns,Maxes
Chemical intermediate and in gauge fluids
Vault fumigation
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
===== = = ====as=SSS5=CSSSSSSS===S==S===SSSSSS==
INDUSTRY
USE (a)
U067 (continued)
U068 Dibromomethane
U070 1.2-Dichlorobenzene
U071 1,3-Dichlorobenzene
U072 1,4-Dichlorobenzene
U073 3,3'-Dlchlorobenzidine
U074 1,4-Dichloro-2-butene
U075 Dichlorodifluoromethane
Dyes and Pigments
Food Processing
Pesticides
Pharmaceuticals
Timber
Plastics and Resins
Pesticide
Pesticide
Dyes and Pigments
Plastics
Rubber
Organic Chemicals Manufacturing
Pesticide
Health and Safety
Catalyst in preparation of Grignard reagents
Chemical intermediate for vinyl bromide (
Chemical intermediate for dyes
Spot fumigation milling machinery
Termite and Japanese beetle control
Insecticidal fumigant for stored products
Beehive supers
Soft treatment (insects and nematodes)
Chemical intermediate for Pharmaceuticals
Felled log fumigation
Organic synthesis
Gauge fluid
Ingredient of fire-estinquishing fluids
Heavy liquid in solid separations
Solvent for waxes & resins
Fumigant and insecticide
No information available
Manufacture of moth repellent, soil fumigant
Curing agent
Paint and ink formulation
Manufacture of AZO dyes
Chemical intermediate for dyes
Plastic compounding ingredient
Rubber compounding ingredient
Chemical intermediate for hexamethylenediamine and chloroprene
Nematocides and as chemical intermediate
Leak-detecting agent
Refrigerant
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
===ss========sssssss=s=ss====sssass=ss=====s=sssssss==a=r=ssa25
USE (a)
U075 (continued)
Plastics
Adhesive and Sealants Industry
Agricultural Chemicals
Automobile Manufacturing
Bottle Manufacturing
Cosmetics Manufacturing
Electrical Equipment
Food Processing •
Food Processing
Food Service/Restaurant
Medicine
Metals Manufacturing
Organic Chemicals
Paint Manufacturing and Application
Paint Manufacturing and Application
Petroleum Refining
Pharmaceutical Manufacturing
Plastics
I
U076 1,1-Dichloroethane
Organic Chemicals Manufacturing
Polynerization catalyst
Aerosol propellent
Aerosol propellent
Refrigerant for air conditioning
No information available
Aerosol propellent
Manufacturing electrical insulation and generator windings
Solvent or diluent in fumigants for food sterilization
Freezing of foods
Chilling of glasses
Preparation of frozen tissue sections
Copper and aluminum purification
Synthesis of Freons
Used in paints & varnish removers
Aerosol propellent
Petroleum recovery
Aerosol propel(ant
Refrigerant in home & commercial applications
Used in polymerization process
Aerosol propellent in cleaners
Working fluid for heat pumps end in hydraulic fluids
Foaming agent for surfactants
Foaming agent in fire extinguishers
Water purification
Used in thermal expansion valves
Chemical intermediate for vinyl chloride, 1,1,1-trichloroethane
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
UASTECODE NAME
INDUSTRY
USE (a)
U077 1.2-Dichloroethane
U078 1.1-Dichloroethylene
U079 1.2-D i chIoroethyIene
U080 Methylene chloride
U081
U082
> U083
i—•
vo
U08A
U091
2,4-Oichlorophenol
2,6-Dichlorophenol
1,2-Oichloropropane
1,3-Dichloropropene
U085 1,2:3,4-Diepoxybutane
U089 Diethylstilbestrot
U090 Dihydrosafrole
3,3'-Dimethoxybenzidine
Plastics and Resins
Organic Chemicals Manufacturing
Food Processing
Organic Chemicals Manufacturing
Pesticide
Dry Cleaning
Pesticide
Dry Cleaning
Pesticide
Commercial Testing Laboratories
Pharmaceuticals/Medicine
Flavor
Cosmetics and Fragrances
Tanning, Paper, Rubber, Textiles
I
Solvent for fat and oils
Solvent for waxes, gum, resins
Fumigant
Intermediate for vinilydene polymer plastics
Solvent for fats, phenol, camphors
Solvent for cellulose acetate
Degreesing and cleaning fluids
Solvent
Organic synthesis
Systemic herbacide
Oil and fat solvent
In dry cleaning fluids
In degrees ing
Insecticidal fumigant mixtures
Oil and fat solvent
In dry cleaning fluids
In degreesing
Insecticidal fumigant mixtures
Research chemical
No longer used
Chemical intermediate for piperonyl butoxide (not in U.S.)
Flavoring agent in root beer
Fragrance for cosmetics
Detection of thiocyanates, nitrites, ft some metals
Dye
Chemical intermediate in production of 0-dianisidine diisocyanate
-------
UASTECCCE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U091 (continued)
U092 Dimethyl mine
K)
O
Dyes and Pigments
Dyes and Pigments
Detergents
Pharmaceuticals
Petroleum Refining
Agricultural Chemicals
Textiles
Pesticides
Plastics and Resins
Film
Leather and Tanning
Rubber
U093
p-0 i methyl aminoazobenzene
Cheaical intermediate in dyes and pigments
Reagent for magnesium
Missile fuel
Dyes
Ion exchange agent
Chemical intermediate for lauryl dimethylamine oxide
Manufacture of detergents
Surfactant
No information available
Antiknock agent in fuels
Gasoline stabilizer
Attract boll weevils
Antioxidants
Dehairing agent
Textile chemicals
Electroplating
Acid gas absorbent
Flotation agent
Pesticide propellant
Che*ical intermediate for dimethylformamide.dimethylacetamide
Plasticizer
Rocket propellent
Dimethylamine salt of 2,4-D
Photographic chemical
Tanning
Accelerator in vulcanizing rubber
Not produced or used in U.S.
-------
=============r====ae===================s
UASTECGOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
=====S=========SSS3E
INDUSTRY
USE (a)
U094 7.12-Dimethylbenz(B)anthraceoe
U095 3,3'-Dimethylbenzidine
U097 Dimethyl carbonyl chloride
U101 2.4-Dimethyl phenol
U105 2,4-Dinitrotoluene
Construction
Pharmaceutical
Organic Chemicals Manufacturing
Medical Research
Dyes and Pigments
Plastics end Resins
Pesticides
Pesticide
Dyes and Pigments
Explosives
Munition
Plastics and Resins
Rubber
U106 2.6-Dinitrotoluene
In coal tar for road surfaces and roofing materials
Binder for electrodes in aluminum reduction process i
Treatment of skin disorders
Waterproofing
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
Induces malignant tumors in testing of antineoplastic drugs
Free chlorine in water
Reagent for gold detection
In chlorine test kits & test tapes in clinical laboratories
Chenical intermediate for AZO dyes
Curing agent for urethane resins
Chemical intermediate for parasympathomimetic agents
Pesticide (former use)
Insecticide, fungicide
Cheatcat intermediate for dyes
Production of toluenediamine (Ramey nickel slurry process)
Chenical intermediate in production of toluene diisocyanate
Added to sensitizing materials in dynamite
Plasticizer in moderate and high explosives
Gelatinizing & waterproofing agent
Explosives intermediate
Modifier for smokeless powders
Plastics manufacture
Rubber chemical
Chenical intermediate for toluene-2,2-diamine
Synthesis of urethane polymers, flexible & rigid foams
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF u AJO ? CHEMICAL PRODUCTS
UASTECOOE NAME
INDUSTRY
USE (a)
U106 (continued)
U108 1.4-Dioxane
N>
N>
U110 DipropyIoffline
U111 Di-n-propylnitrosamine
U112 Ethyl acetate
Dyes and Pigments
Explosives
Plastics end Resins
Cosmetics and Fragrances
Paint Manufacturing
Paper Processing'
Dyes and Pigments Manufacturing
Cleaning Products
Organic Chemical Manufacturing
Plastics and Resins Manufacturing
Agricultural Chemicals
Organic Chemical Manufacturing
Medicine
Food Processing
Plastics and Resins Manufacturing
Printing
Paint Manufacturing
Munitions
Film
In dyes
In synthesis of TNT
Gelatinizing and waterproofing agent in explosives i
Surface coatings
Manufacture of cosmetic products
Manufacture of lacquers, paints, varnishes, paint
Solvent in pulping of wood
Wetting and dispersing agent in textile
processing, dye-baths, stain and printing
compositions
Manufacture of cleaning and detergent preparations,
adhesives, fumigants, emulsions, and polishing
compositions
Solvent for fats, oils, waxes
Solvent for natural and synthetic resins
Purification of perfIuoro-compounds
Chemical intermediate for S-propyl-di-n-propylthiocarbamate
Chearical intermediate for herbicide S-ethyl-di-n-propylthiocarbamate
Research chemical
Organic synthesis
Carminative, ant{spasmodic, and counterirritant
Component of base sheet (cellophane)
Diluent in inks for marking fruits and vegetables,
synthetic flavoring
Solvent for plastics
Solvent for inks
Solvent for varnishes, lacquers
Manufacture of smokeless powder
Manufacture of photographic films and plates
-------
UASTECODE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U112
(continued)
U113 Ethyl acrylate
U1U
U116
Ethylene bis-dithiocarbamic acid
Ethylene thiourea
NJ
OJ
U117
Diethyl ether
Leather and Tanning
Cosmetics and Fragrances
Paint Manufacturing
Textiles
Paper Coating
Cleaning Products
Adhesives and Sealants
Leather and Tanning
Food Processing
Agricultural Chemicals
Agricultural Chemicals
Dyes and Pigments
Pesticides
Pharmaceuticals
Plastics and Resins
Rubber
Organic Chemical Manufacturing
Cosmetics and Fragrances
Explosives
Automotive
Commercial Testing Laboratories
Veterinary Medicine
Manufacture of artificial leather
Manufacture of perfumes and fragrances
Emulsion polymers for trade sale paints
Textile coating and printing
Paper coatings
Floor finishes
Emulsion polymers for adhesives and sealants
Leather finishes
Synthetic flavorings
Heavy metal salts as fungicides
Electroplating baths
Intermediate for antioxidants
Intermediate for fungicides
Intermediate for dyes
Intermediate for insecticides
Intermediate for Pharmaceuticals
Manufacture of synthetic resins
Accelerator for neoprene rubbers
Solvent for waxes, fats, and oils
Reagent for organic synthesis
Chemical intermediate for monoethanolamine, ethylene
Solvent for perfumes
Manufacture of gun powder
Primer for gasoline engines
Extractant of hormones from plant and animal tissues
Inhalation anesthetic, antispasmodic, rubefacient
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AMD P CHEMICAL PRODUCTS
UASTECOOE NAME
• INDUSTRY
USE (a)
U118 Methacrylic acid, ethyl ester
U119 Ethyl methane sulfonate
U120 Fluoranthene
>
NJ
U121
Fluorotrichlorocnethane
Plastics and Resins Manufacturing
Cleaning Products
Pharmaceutical Manufacturing
Biochemical Research
Construction
Phamaceutical
Organic Chemicals Manufacturing
Chemical Research
Agricultural Chemicals
Cosmetic and Fragrance
Electrical Equipment
Food Processing
Organic Chemicals
Paint Manufacturing and Application
Pharmaceuticals
CoMonomer in acrylic polymers for surface coating resins
Acrylic emulsion polymers for polishes
Cononomer in denture base material
Not produced in U.S.
In coal tar for road surfaces and roofing materials
Binder for electrodes in aluminum reduction process
Treatment of acute and chronic dermatoses
Waterproof i ng
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
In lining for steel and ductile iron potable water pipes and storage
tanks
Research chemical
Sulfonation solvent in chemical synthesis
Dielectric fluid in bubble chanters in wind tunnels
Aerosol propellent
Blowing agent in production of polyurethane foam
Production of polymeric resins
Chemical intermediate
Aerosol propellent
Aerosol propellent
Electric insulation
No information available
Manufacture cleaning compounds
Aerosol propel I ant
Aerosol propellant
Manufacture fire extinguishers
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U121 (continued)
U122 Formaldehyde
U123 Formic acid
Plastics and Resins Manufacturing
Organic Chemical Manufacturing
Tire
Medicine
Dyes and Pigments Manufacturing
Leather and Tanning
Explosives
Agriculture
Agricultural Chemical Manufacturing
Paint Manufacturing
Textiles
Organic Chemical Manufacturing
Cosmetics and Fragrances
Medicine
Fiber Manufacturing
Aerosol propel(ant (floor waxes)
Refrigerant
Solvent and degreasing agent
Chemical intermediate for phenolic, polyacetal
and meIamine resins
Chemical intermediate for resorcinol-formaldehyde
and aniline-formaldehyde resins
Chemical intermediate for acetylenic chemicals,
(1,4-butanediol), polyols (pentaerythritol),
hexamethylenetetramine, methylene dianiline,
pyridine chemicals, nitroparaffin derivatives
Chemical intermediate for rubber processing chemicals
Disinfectant
Embalming agent
Component of dyes as starch preservative
Chemical intermediate for synthetic tanning agent
Chemical intermediate for explosives
Soil sterilant in mushroom houses before planting
Manufacture of fumigants, insecticides
Manufacture of commercial paint strippers, lacquers
Dyeing and finishing of textiles
Preparation of organic esters
Manufacture of refrigerants
Solvent for perfumes
Antiseptic
Silvering glass
Cellulose formate
Ore floatation
-------
UASTECOOE NANE
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CXERICAL PRODUCTS
======r========5=s5SS==C8SSSS=S====S£=SS£BS==
INDUSTRY
USE (a)
U123 (continued)
U124 Furan
U125 Furfural
N>
U126
U127
U128
U129
U130
U131
Glycidylaldehyde
HexachIorobenzene
Hexach t orobut ad i ene
Lindane
HexachIorocyc(opent ad i ene
HexachIoroethane
Plastics and Resins Manufacturing
Leather end Tanning
Organic Chemical Manufacturing
Organic Chemical Manufacturing
Petroleum Refining
Adhesives and Sealants
Food Processing
Plastics and Resins Manufacturing
Medicine
Paint Manufacturing
Agricultural Chemical Manufacturing
Automotive
Commercial Testing laboratories
Wool Heaving and Finishing
Leather and Tanning
Medicine
Pesticid?
Rubber
Pesticide
Pesticide Manufacturing
Explosive
Manufacture of vinyl resin plasticizers
Leather tanning
Cheaical intermediate for tetrahydrofuran
Organic synthesis for pyrrole, thiophene
Solvent in extraction of butadiene from C4 streams
Refining of lubricating oils
Constituent of rubber cement
Synthetic flavoring ingredient
Solvent for synthetic and natural resins
Screening test for urine
Manufacture of varnishes
Insecticide, fungicide, germicide
Wetting agent in the manufacture of abrasive
wheels and brake linings
Research chemical
Cross-1 inking agent for finishing of wool
Oil tanning and fat-liquoring of leather
Oil tanning and fat-liquoring of surgical sutures
Protein insolubilizatioo
Chemical intermediate in glycerol manufacture
Fungicide
Solvent for rubber
Insecticide
Chemical intermediate for aide in, dieldrin, endrin, endosulfan,
chlordane, heptachlor, isodrin
Solvent
Explosives
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRXUCTS
UASTECOOE NAME
INDUSTRY
USE (a)
U131 (continued)
U132 Hexachlorophene
U137 Ideno(1.2f3-c,d)pyrene
!^ U138 ' lodomethane
UHO Isobutyl alcohol
Rubber
Soap
Cosmetics
Construction
Pharmaceutical
Organic Chemicals Manufacturing
Chemical Research
Pharmaceuticals
Food Processing
Plastics and Resins Manufacturing
Cosmetics and Fragrances
Pharmaceutical Manufacturing
Camphor substitute in celluloid
Vulcanizing accelerator
In soap and germicideI preparations
In cosmetic preparations
In coal tar for road surfaces and roofing materials
Binder for electrodes in aluminum reduction process
Treatment of acute and chronic dermatoses
Waterproofing
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
Research chemical
Chemical intermediate for methylamines & quarternary ammonium iodides
Chemical intermediate for for phosponium iodides
Chemical intermediate for organometallies
Alkylating agent
Methylat ing agent in prep, pharmaceutical intermediates
Microscopy
Building block for radioactive tracers synthesis
Testing for pyridine
As imbedding material of diatom examination
As fire extinquisher
Manufacture of food additives
Solvent for surface coatings and adhesives
Chemical intermediate for isobutyl esters used
as plasticizers
Manufacture of perfumes
Processing solvent for Pharmaceuticals
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AMD P CHEMICAL PRODUCTS
UASTECOOE HAKE
INDUSTRY
USE (a)
UU8 (continued)
UU9 Natonitrile
U150 Melphalan
•f U1S2 Methacrylonitrile
N)
U153 Methanethiol
Medicine
Lubricant
Medicine
Medicine
Medicine
Plastics and Resins
Flavor
Agricultural Chemicals
Pesticides
Petroleum Refining
Plastics and Resins
U1S4 Methyl alcohol
Sugar content stabilizer in beets
Fungicidal
Photosensitiier
Formerly used to treat mental illness
Acrylic fiber and dyestuff synthesis
Organic synthesis
Lubricating oil additive
Leaching agent for gold
Thfamine synthesis
Anti-cancer agent synthesis
Antineoplastic agent
Preparation of hornopolymers & copolymers
Intermediate in preparation of acids, amides, amines, esters, nitrites
Monomer for copolymers
Monomer for polymethacrylonitrile
Manufacture of elastomers, coatings, plastics
Synthetic flavoring and adjuvants
Synthesis of methimine
Synthetic flavoring substances and adjuvants
Catalyst
Gas odorant for hazardous gases
Synthesis of methimine
Intermediate in fungicides
Intermediate in pesticide manufacture
Intermediate in jet fuels manufacture
Intermediate in plastics manufacture
Kill animal pathogenic bacteria and maggots on
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U154 (continued)
OJ
o
U155 Nethapyrilene
U1S6 Methyl chlorocarbonate
U157 3-Methylcholanthrene
Agricultural Chemicals
Petroleum Refining
Printing
Pharmaceuticals
Veterinary Medicine
Pesticides
Construction
Pharmaceutical
Organic Chemicals- Manufacturing
Medical Research
U158 4,4-Methylene-bis-(2-chloroaniline)
U159 Methyl ethyl ketone
Munitions
Aircraft
Plastics and Resins Manufacturing
Paint Manufacturing
Cement
household contents, mortuary instruments, human
bedding and clothing, tissues, human stools,
and cadavers
Treatment against onion smut, dutch elm disease,
and wood root
Removal of toxic organic pollutants from soil
Kill slime forming bacteria in oil recovery
injection water and packer fluid
Duplicating fluid
Removal of 2.4-dinitrotoluene from spent carbons
•Sedative in sleeping aids
Antihistaminic
Antihistaminic agent
In organic synthesis
In insecticides
In coal tar for road surfaces and roofing materials
Binder for electrodes in aluminum reduction process
Treatment of acute and chronic dermatoses
Waterproof i ng
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
Induces specific forms of cytochrome in cancer research
Components in home appliances
Manufacture of radar systems
Manufacture of gun mounts
Manufacture of jet engine turbine blades
Curing agent
Manufacture of paint removers
Manufacture of cements
-------
UASTECOOE NAME
TABLE A-1 (Continued)
SKDUSTRiAL USE Of U ASB P CHEMICAL PROCUCTS
==s=sss==ssssssssssosttsa=ssss=s=ssssssssassss
INDUSTRY
USE (a)
U1S9 (continued)
>
u>
U161
Methyl isobutyl ketone
U162 Nethyl methacrylate
U163 N-Nethyl,N-nitro-.N-nitroguanidine
U164 MethylthiouraciI
U165 Naphthalene
Adhesives and Sealants
Cleaning Products
Organic Chemical Manufacturing
Building Products
Magnetic Tape
Printing
Agricultural Chemical Manufacturing
Medicine
Pharmaceutical Manufacturing
Paint Manufacturing
Organic Chemical Manufacturing
Dry Cleaning
Food Processing
Organic Chemical Manufacturing
Medicine
Human/Veterinary Medicine
Organic Chemicals Manufacturing
Plastics end Resins
Manufacture of adhesives
Solvent for adhesives
Cleaning fluids
Organic synthesis
Oxidation promoter in manufacture of terephthalic
acid from p-xylene
Solvent for coatings
Solvent for magnetic tape
Solvent for printing inks
Solvent for cosolvent in pesticide formulations
Sterilizer for baterial spores on surgical instruments,
hypodermic needles/syringes, and dental instruments
Denaturant for rubbing alcohol
Manufacture of antibiotics
Solvent for paints, varnishes, cellulose lacquer
Manufacture of methyl amyl alcohol
Organic synthesis, extraction processes
Manufacture of dry cleaning preparations
Manufacture of synthetic flavoring substances
Monomer for polymethyl methacrylate, comonomer
for copolymers
Chemical intermediate for higher methacrylate esters
Laboratory preparation of diazomethane (former use)
Research chemicals
Anti-thyroid agent (Not produced in U.S.)
Manufacture of phthalic and anthranilic acids, naphthols,
naphthylamines, sulfonic acid
Manufacture of synthetic resins
Manufacture of cellulowid, lampblack, smokeless powder
Preparation of anthiaquinone
-------
UASTECOOE NAHE
TABLE A-1 (Continued)
INDUSTRIAL USE Of U AND P CHEMICAL PRODUCTS
=========S=SSS;SSSECBSSSSE========S=S
INDUSTRY
USE (a)
U165 (continued)
U166 1,4-Naphthoquinone
U167 1-Naphthytamine
U168 2-Naphthylamine
Dyes and Pigments
Pesticide
Leather and Tanning
Veterinary Medicine
Tire
Plastics and Resins Manufacturing
Dyes and Pigments Manufacturing
Pharmaceutical Manufacturing
Agricultural Chemical Manufacturing
Dyes and Pigments
Pesticides
Pesticides
Rubber
Dyes and Pigments
Rubber
Rubber
U169 Nitrobenzene
Manufacture of indigo
Formation of perylene |
Chemical intermediate for 1-naphthyl-n-methyl carbonate insecticide
Chemical intermediate for beta-naphthol and synthetic tanning chemicals
Chemical intermediate for naphthalene sulfactants
Insecticide, antiseptic, vermicide
Ingredient in moth repellent and toilet bowl deodorants
Manufacture of hydronaphthalenes used as solvents in lubricants and
motor fuels
Polymerization regulator for rubber
Polymerization regulator for polyester resins
Synthesis of dyes
Synthesis of Pharmaceuticals
Algicide
Chemical intermediate for imidazoline adrenergic agent
Chemical intermediate for N-1-Naphthylphthalmic acid herbicide
Toning prints made with cerium salts
Chemical intermediate for dyes
Chemical intermediate for 1-Naphthylthiourea rodent icicle (former use)
Chemical intermediate for fluoroacetamide miticide (former use)
Chemical intermediated for N-Phenyl-1-Naphthylamine rubber antioxidant
Production 2-chloronaphthylamine
Former chemical intermediate for dyes
Former chemical intermediate for rubber antioxidants
Formerly in manufacture of rubber
Solvent
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE Or U AND P CKEKiCAL PRODUCTS
INDUSTRY
USE (a)
U169 (continued)
u>
u>
U170
U171
4-Nitrophenol
2-Nitropropane
Jewelry
Plastics and Resins
Food
Pesticides
Pharmaceuticals
Rubber
Pesticide
Paint and Varnish
Dyes and Pigments
Munitions
Ingredient of metal polishes
Manufacture pyroxylin compound
Preservative in spray paints
Solvent for cellulose ethers
Chemical intermediate for aniline, dichloroanilines
Refining lubricating oils
In soaps, shoe polishes
Substitute for almond essence
Production of isocyanates
Modifying esterification of cellulose acetate
Constituent of floor polishes
Production of pesticides
Production of Pharmaceuticals (acetaminophen)
Production of rubber chemicals
Production of parathion, fungicide
Paint and varnish removal
Chemical intermediate for 2-Amino-2-methyl-1-propanol
Increase wetting ability & electrostatic spraying properties
Solvent for chemical reactions
Provide better flow characteristics & film integrety
Chemical synthesis
Insure greater pigment dispersion
Co-solvent for coatings, ink, & adhesives
Insure more complete solvent release
Rocket propellent
Improve drying time in solvent systems
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U171 (continued)
U172 N-Nitroso-di-n-butylamine
U173 N-Nitroso-diethanolamine
U174 N-Nitrosodiethylamine
U176 N-Nitroso-N-ethylurea
U177 N-Nitroso-N-methylurea
U178 N-Nitroso-H-methylurethane
U179 N-Nitrosopiperidine
U180 N-Nitrosopyrrolidine
U181 5-Nitro-o-toluidine
U182 Paraldehyde
Coating
Coating
Dyes and Pigments
Pesticides
Petroleum Refining
Pharmaceuticals
Research
Research
Research
Petroleum Refining
Research
Research
Research
Research
Dyes and Pigments
Organic Chemical Manufacturing
Dyes and Pigments Manufacturing
Processing solvent for extractions and separations
Acid-proof lacquer on battery cases
Solvent systems
Intermediate in synthesis of dyes
Intermediate in synthesis of insecticides
Racing car fuel
Gasoline additive
Smoke depressant in diesel fuel
Intermediate in synthesis of Pharmaceuticals
Research chemical
Researh chemical
Research chemical
Stabilizer
Antioxidant
Gasoline and lubricant additive
Research chemical
Laboratory preparation of diazoethane
Mutagenic effects on various plants
Laboratory synthesis of diazomethane
Laboratory synthesis of diazomethane
Research chemical
Research chemical
Research chemical
Chemical intermediate for pigments and dyes
Substitute for acetaldehyde
Solvent for fats, oils, waxes
Manufacture of dyestuff intermediates
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
SSS===SE==SSSS=SSS3CSSSSCSSSSSSSISSSSS3SSSSSSa
INDUSTRY
USE (a)
U182 (continued)
U183 Pentachlorobenzene
U184 Pentachloroethane
>
CO
Ul
U185
U186
U187
U188
U191
Pentachloroni trobenzene
1,3-Pentadiene
Phenacetin
Phenol
2-Picoline
U192 Pronamide
U193 1,3-Propane sulfone
U19* n-Propylamine
Plastics and Resins Manufacturing
Leather and Tanning
Fiber Manufacturing
Coal
Agricultural Chemicals
Organic Chemicals Manufacturing
Lumber
Agricultural Chemical
Hair Products
Pharmaceuticals/Veterinary Medicine
Dyes and Pigments
Plastics and Resins
Agricultural Chemical
Textiles
Dyes and Pigments
Pesticides
Solvent for guns, resins
Manufacture of leather
Mixtures for cellulose derivatives
No information available
Solvent for oil and grease in metal cleaning
Separation of coal from impurities
Soil sterilization
Solvent for cellulose acetate, cellulose esthers, resins
Drying agent for timber '
Fungicide
Manufacture of synthetic rubber
Stabilizer for hydrogen peroxide in hair bleaching preparation
Analgesic and antipyretic
Oisenfectant
Chemical intermediate for 2-chloro-6-(trichloromethyl)pyridine
Organic intermediate for Pharmaceuticals,rubber chemicals
Chemical intermediate for 2-vinylpyridine, herbicide picloram.amproliun
Intermediate
Intermediate
Herbicide for vegetables
Confer water solubility and anionic character
Chemical intermediate to sulfopropyl group
Chemical intermediate for textile resins
Chemical intermediate for propyl isocyanate
Chemical intermediate for dyes
Chemical intermediate for pesticides
-------
UASTECOOE NAME
U194 (continued)
U196 Pyridine
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
B=================ss===ssss=====:s========3r==r===============
INDUSTRY
USE (a)
Petroleum Refinining
Pharmaceuticals
Rubber
Pharmaceuticals
U197 1,4-Benzoquinone
Agricultural Chemicals
Dyes and Pigments
Explosives
Food Products
Paint Manufacturing
Petroleum Refining
Plastics and Resins
Rubber
Textiles
Agricultural Chemical Manufacturing
Chemical intermediate for petroleum additives
Chemical intermediate for drugs
Chemical intermediate for rubber chemicals
Solvent reaction medium or catalyst in carbohydrate treatment
In organic synthesis and analytical chemistry
As an inhibitor & preparation of inhibitor
Manufacture vitamins,sulfa drugs.disinfectants
Chemical intermediate for antihistamines
Manufacture of stimulants,local anesthetics
Solvent in drug manufacture
Chemical intermediate for diquat & paraquat, piperidine
Solvent for anhydrous mineral salts
To denature alcohol & antifreeze mixtures
Reduces nitrogen oxide in flue gas
Synthesis of piperidine
Reagent
Manufacture fungicides
Manufacture dyestuffs
Manufacture explosives
Useful in seafood, smoke falvor, chocolate
Solvent reaction medium or catalyst in paint manufacture
In oil and gas well drilling
Solvent in manufacture of polyurethane resins
No information available
Chemical intermediate for water-proofing agents in textiles
Manufacture of fungicides
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
ssssss=sss2S3ssess«m»s««3ssac=zsc5a=s3s*ssss
INDUSTRY
USE (a)
U197 (continued)
U200
U201
Reserpine
Resorcinol
U202
Saccharin
U203
Safrote
U206 Streptozatocin
Organic Chemical Manufacturing
Film
Leather and Tanning
Cosmetics and Fragrances
Pharmaceuticals
Leather and Tanning
Explosives
Dye* and Pigments
Plastics and Resins
Animal Food Products
Electroplating
Food Products
Adhesives and Sealants
Cosmetics
Pesticides
Pharmaceuticals
Medicine
Veterinary Medicine (Research)
Analytical reagent, oxidizing agent
Determination of ami no acids by the formation
of red charge-transfer complexes
Photography
Tanning hides
Transform nitrogen containing-compounds into
colored substances
Medication
In tanning
Manufacture of resins
Cattle feed additive
Electroplating bath additive
Non-caloric synthetic sweetener -- food, gun, toothpaste, smokeless
tobacco, etc.
Chemical intermediate for heliotropin
Chemical intermediate ofr isosafrole
Manufacture of piperonyl butoxide
As preservative in mucilage and library paste
Fragrance for cosmetics
Pediculicide
Flavoring agent for drugs, topical antiseptic
Carminative
Antineoplastic agent in cancer treatment
Experimental use in diabetes & as antimicrobial agent
Diabetogenic agent
U207 1,2,4,5-Tetrachlorobenzene
No information available
-------
UASTECODE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U208 1.1,1,2-Tetrachloroethane
U209 1.1,2.2-Tetrachloroethane
u>
oo
U210
Tet rachIoroethyIene
U211 Carbon tetrachloride
U213 Tetrahydrofuran
Plastics and Resins
Agricultural Chemicals
Hedical Research
Organic Chemicals Manufacturing
Plastics and Resins
Agricultural Chemicals
Hedical Research
Organic Chemicals Manufacturing
Dry Cleaning
Dry Cleaning
Automobile
Pesticide
Organic Chemicals Manufacturing
Food Processing
Plastics and Resins Manufacturing
Organic Chemical Manufacturing
Nonflammable solvent for fats, oils, waxes, resins, cellulose acetate,
rubber, phosphorous, sulfur
Manufacture of paint, varnish, and rust removers I
Soil sterilization, weed killer, and insecticide formulations
Immersion fluid in crystallography
Provide pathological changes in gastrointestinal tract, liver, kidneys
Chemical intermediate for trichloroethylene, halogenated hydrocarbons
Nonflamnable solvent for fats, oils, waxes, resins, cellulose acetate,
rubber, phosphorous, sulfur
Manufacture of paint, varnish, and rust removers
Soil sterilization, weed killer, and insecticide formulations
Immersion fluid in crystallography
Provide pathological changes in gastrointestinal tract, liver, kidneys
Chemical intermediate for trichloroethylene, halogenated hydrocarbons
Oegreasing metals
Solvent
Fire extinquisher
Cleaning clothing
Azeotropic drying agent for wet spark plugs
Solvent for oils, fats, lacquers, varnishes, rubber, waxes, resins
Extracting oil from flowers, seeds
Insecticide
Starting material for organic compounds
Indirect food additive for food contact surface
of articles intended for use in food processing
Solvent for resins and plastics
Chemical intermediate for polytetramethytene
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
UASTECOOE NAME
INDUSTRY
USE (a)
U213
(continued)
U21B
Thioacetamide
u>
vo
U219
Thiourea
Magnetic Tape
Cleaning Products
Printing
Leather, Textiles, Paper
Medicine
Rubber
Cosmetics
Paper Manufacturing
Uood Preserving
Paper
Adhesives and Sealants
glycol, tetrahydrothiophene
Solvent for top coating solutions, protective
coatings, coating magnetic tapes
Solvent for cleaning
Agent in liquid membrane electrode manufacturing
Polymerization solvent
Solvent for print inks
Solvent for production of tetraethyl and
tetramethyl lead
Solvent
Stabilizer for fuel with tetraethyllead
Substitute for Hydrogen sulfide in labs
Solubilizer for riboflavin
Analytical reagent
Accelerator for buna rubber
Removal of mercury from wasteuaters
In hair preparations
Preparation of non-glare mirrors
In paper uhiteners
Stain prevention of hemlock wood
In scrub soln for waste gas containing NO(X)&SO(X)
Stabilizer for diazo coating solns for copy film & paper
Reagent for bismuth, selenite ions
Liquifier/peptizing agent for glue
In dry-cleaning chemicals
CheIat ing agent
Synthesis of sulfthiazole
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
================5=SSSSS
INDUSTRY
USE (a)
U219 (continued)
U220 Toluene
Textiles
Agricultural Chemicals
Dyes and Pigments
Photography
Pesticides
Pharmaceuticals
Plastics and Resins
Textiles
Veterinary Medicine
Organic Chemicals Manufacturing
Explosives
Dyes and Pigments
Food
Medicine
Cosmetics and Fragrance
Catalyst in isomerization of maleic to fumaric acid
Intermediate for S-lodo-2-thiouracil
In cleaning and plating baths for metals
Manufacture of fire retardant for lacy fabrics
Metal corrosion inhibitor for pickling solutions
Radioprotector in X-irradiated mice
Reduces interferences for analysis of cadmium
Vulcanization accelerator
In mineral oil
Fungicide
Sprout accelerator in dormant tubers
Dye intermediate
Photographic fixing agent and remove stains from negatives
Complexing agent for color print photography
Synthesis of insecticides
Synthesis of Pharmaceuticals
Manufacture of resins
In-boiler water treatment
Flame-proof ing agent for nylon
Weighting agent for silk
Experimentally as thyroid inhibitor or goitrogen
Medication
Manufacture of benzoic acid, benzaldehyde
Manufacture of explosives
Manufacture of dyes
Manufacture of caprolactam
Manufacture of saccharin
Manufacture of medicines
Manufacture of perfumes
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE Of U AdC P CHEMICAL PRODUCTS
====SS3=C8S8SSCSSSSSS=S======SSSSSS3
INDUSTRY
USE (a)
U220 (continued)
U222 o-Toluidine hydrochloride
U225 Bromoforn
U226 1,1,1-Trichloroethane
U227 1,1,2-Trichloroethane
U228 Trichloroethylene
Toy Manufacturing
Plastics and Resins
Petroleum Refining
Dyes and Pigments
Organic Chemicals Manufacturing
A i rcraf t/Aerospace
Pharmaceuticals
Rubber
Shipbuilding
Adhesive solvent in plastic toys and model airplanes
Solvent for paints, lacquers, gums, resins
Extraction of various principals from plants
Gasoline additive.
Chemical intermediate for dyes
Ingredient in fire-resistant chemicals
Chemical intermediate for organic synthesis
Solvent in liquid-solvent extractions
Flotation agent in sedimentary petrographiesI surveys
Catalyst/sensitizer in polymer reactions
Solvent for waxes,greases,! oils
Flotation agent in purification of materials (quartz)
Flotation agent in mineral separation
In gauge fluid
Reagent for graphite ore fractionation
Solvent in nuclear magnetic resonance studies
No information available
Sedative
Synthesis of pharmaceuticals
Catalyst/sensitizer in vulcanization of rubber
No information available
Cold-type metal cleaning
Cleaning plastic molds
Solvent for fats, waxes, natural resins, alkaloids
Solvent for fats, waxes, resins, oils, rubber, paints,
varnishes, cellulose esters and ethers
Solvent extraction
-------
UASTECCOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
rs=s=======r=s==sssnBssassssss=ss===as33sss=
INDUSTRY
USE (a)
U228 (continued)
U234 sym-Trinitrobenzene
U236 Trypan blue
U237 Uracil Mustard
Ethyl carbamate
U239 Xylenes
Dry Cleaning-
Organic Chemicals Manufacturing
Pharmaceutical
Explosives
Rubber
Dyes end Pigments
Medicine
Medicine
Medicine
Agricultural Chemicals
Biochemical Research
Cosmetics
Pesticides
Pharmaceuticals
Textiles
Veterinary Medicine
Organic Chemicals Manufacturing
Textile and Fiber
Degreesing
Acid-base indicator for 12.0-H.O pH
Explosive
Vulcanize natural rubber
Biological stain
Dye for textiles.leather,paper
Therapeutic agent for sleeping sickness
Antineoplastic agent (essentially obsolete drug)
Formerly as adjunct to sulfonamide therapy
Preparation and modification of amino resins
Anti*neoplastic agent
Solvent for barious organic materials
Solubilizer and co-solvent for funigants
No information available
Solubilizer and co-solvent
Solubilizer and co-solvent
Formerly topical bactericide
Formerly component sclerosing soln for varicose veins
Intermediate for Pharmaceuticals
Chemical intermediate for N-hydroxymethyl derivatives
Anesthetic, hypnotic, sedative, diuretic
As a solvent
Raw material in production of benzoic acid, phthalic anhydride,
isophthalic and terephthalic acids
Manufacture of polyester fibers
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AW) P CHEMICAL PRODUCTS
5SS=SES=CSSSS«S3S=S::=SSES*SSK3SeSEEEEEE=E=SEEESBSESSES=== = = = === = =
INDUSTRY
USE (a)
U239 (continued)
U240 2,4-D, Salts and esters
U2A3 Hexachtoropropene
U244
Thiram
Dyes and Pigments
Laboratories
Pesticide
Plastic and Resin
Agricultural Chemicals
Wood Preserving
Food Products
Rubber
Paper
Pharmaceut i caIs
Agricultural Chemicals
Manufacturing dyes
Sterilizing catgut
With Canada balsam as oil-immersion in microscopy
Cleaning agent in microscope techniques
Systemic herbicide
Solvent
Plasticizer
Hydraulic fluid
Preparation of uranium tetrachloride
Production of monochloropentene
Peptizer for polysulfide elastomer
Fungicide for industrial textiles
Preservative
Activator for guanidine,amine,& thiazole cure systems
Mushroom disinfectant
Antioxidant in polyolefins
Vulcanizing agent for rubber
Accelerator for natural & isoprene rubbers,etc.
Fungicide for use on paper, polyurethane foam products
Bacteriostat in soap and antiseptic sprays
Activator for sulfenamide accelerators
Fungicide for seed treatment
Animal repellent for trees and shrubs
U247 Methoxychlor
U248 Uarfarin
P001 Warfarin
Pesticide
Agricultural Chemical Manufacturing
Medicine
Agricultural Chemical Manufacturing
Insecticide
Rodenticide for norway rats and house mice
Anticoagulant therapy
Rodenticide for norway rats and house mice
-------
UASTECODE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
=============
USE (a)
P001 (continued)
P002 1-Acetyl-2-thiourea
Medicine
Anticoagulant therapy
No information available
P003 Acrolein
I
•P-
.p-
P004 Aldrin
POOS Allyl alcohol
P007 5-Aminoethyl-3-isoxazolol
P008 4-Aminopyridine
P014 Thiophenol (Benzenethiol)
P016 Bis-(chloromethyl)ether
P017 Bromoacetone
P018 Brucine
Agricultural Chemical Manufacturing
Organic Chemical Manufacturing
Pharmaceutical Manufacturing
Plastics and Resins Manufacturing
Agricultural Chemical Manufacturing
Military
Pesticide
Agricultural Chemical Manufacturing
Organic Chemical Manufacturing
Plastics and Resins Manufacturing
Medicine
Plastics
Agricultural Chemicals,
Pesticides
Plastics
Specialty Chemical
Plastics
Munitions
Specialty Chemical
Pesticide
Chemical intermediate in synthesis of glycerin.
acrylic acid and esters
Chemical intermediate for Pharmaceuticals
Chemical intermediate for glycerol, polyurethane,
and polyester resins
Aquatic herbicide, biocide, slimicide
Component of military poison gases
Lacrimogenic warning agent in methyl chloride refrigerant
Insecticide, funigant
Herbicide for weed, seeds and fungi
Intermediate in synthesis of glycerin
Manufacture of resins and plasticizers
Laboratory use
Antiemetic
Solvents, reagents and chemicals
Chemical intermediate for carbophenothion fungicide
Chemical intermediate for carbophenothion insecticide & acaricide
Alkylating agent in manufacture of polymers
Monitoring indicator for chloromethyl ether
Intermediate in synthesis of anionic exchange strong-base resins
Lab reagent
Organic synthesis
Chemical war gas
Tear gas
Reagent for separating racemic mixtures
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
P018 (continued)
P020 Dinoseb
P022 Carbon disulfide
>
-c-
Pesticide
Clothing
Automobile Manufacturing
Metals Recovery
Wood, Housing
Lubricants, Wax, Soap, Food
Chemical
Specialty Chemical
Plastics
Medicine
Electroplating
Plastics
Electronic
Petroleum
Rubber
Adhesives and Sealants
Agricultural Chemicals
Denaturant for ethanol
Herbicide
Chemical intermediate for rayon
Corrosion inhibitor
Agent in removal of metals form waste water
Putty preservatives
Tallow
Catalyst and catalyst adjuvant and activator
Dissolving free sulfur,phosphorous,iodine
Regenerator for transition metal sulfide catalysts
Manufacture of xanthogenates
Xanthation of cellulose in preparation of viscose
Flame lubricant in cutting glass
Chemical intermediate for carbon tetrachloride
Chemical intermediate for cellophane
Solvent for phosphorous,selenium,bromine, iodine,fats & resins
Optical glass
Agent in metal treatment and plating (gold and nickel)
Polymerization inhibitor for vinyl chloride
Electronic vacuum tubes
Solvent for cleaning and extractions
Generating petroleum catalysts
Solvent for waxes,lacquers,camphor,resins,vulcanized rubber
Chemical intermediate for sulfur and carbonyl sulfide,xanthates
Rubber cement
Chemical intermediate for adhesives for food packaging
Solvent in extraction of growth inhibitors
Preservation of fresh fruit
Explosive
Explosives
-------
UASTECODE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
====SBSSSSSSSSSSSSESeSSSSSSESSSSSSSS==Z==S=5S
INDUSTRY
==s===================r===ssscs:
USE (a)
:=£===SS==
P022 (continued)
P023 Chloroacetaldehyde
P024 p-Chloroaniline
P026 1-(o-Chlorophenyl)thiourea
P027 3-Chloroproprionitrile
P028 Benzyl chloride
Film
Pesticides
Agricultural Chemical
Petroleum Refining
Plastics and Resins
Rubber
Veterinary Medicine
Timber
Specialty Chemical
Water Treatment
Agricultural Chemicals
Dentistry
Agricultural Chemicals
Dyes and Pigments Manufacturing
Specialty Chemical
Pharmaceuticals Manufacturing
Specialty Chemical
Agricultural Chemicals
Flavoring
Cosmetics and-Fragrances
Pharmaceuticals
Development restrainer for instant color photography
Solvent for pesticide intermediates
Fumigant
Seed treatment on conifers
Soil disinfectants
Rocket fuel
Paints,enamels,varnishes,paint removers
Chemical intermediate for rubber compounds
Cold vulcanization of rubber
Veterinary anthelmintic
Bark removal from trees
Chemical intermediate
In manufacture of 2-aminothiazole
Control of algae,bacteria,and fungi in water
Fungicide
As spinning solution of poly B-aniline
Chemical intermediate for urea herbicides
Chemical intermediate for dyes and pigments
Not manufactured or used industrially in U.S.
Combines reactivity of nitrile and an alkyl halide
Pharmaceutical and polymer synthesis
Chemical intermediate for other benzyl phthalates
Chemical intermediate for n-butyl benzyl phthalate
Manufacture of benzyl compounds
Synthesis of tribenzyltin chloride
Blocking agent to monoalkylated piperazine
Conversion of tertiary amines to quaternary ammonia chlorides
Manufacture of batericides
Manufacture of flavors and odorants
Manufacture of perfumes
Manufacture of pharmaceutical products
-------
(U036). The data available for chlordane were compiled
from the NPDES database and literature data. These data are presented in
Table 4-141. Technologies for which data are available include full-scale BT
and pilot- scale Chred. The resulting effluent concentrations ranged from
0.01 ppb to 483 ppb, with a detection limit for chlordane established a
0.014 ppb. (See Table C-l, Appendix C.)
BDAT for chlordane is being promulgated as proposed and is
identified as biological treatment (BT) . Biological treatment was selected as
BDAT since it represents full-scale treatment performance data and was the
only technology for which the Agency had data. The BDAT treatment standard
for chlordane was calculated using an effluent concentration of 0.2336 ppb
(which represents the average of all BT effluent values; a value below the
detection limit was set at the detection limit) and the appropriate
variability factor and accuracy correction factor. The calculation of the
resulting BDAT treatment standard for chlordane (0.0033 ppm) is described in
Section 6.0 and is shown in Table 6-10.
4-266
-------
Pentachlorodlbenzo-p-dioxlns. The data available for
pentachlorodibenzo-p-dioxin were compiled from the WERL database and are
presented in Table 4-166. The only documented treatment technology was bench-
scale dechlorination of toxics using an alkoxide formed by the reaction of
potassium hydroxide with polyethylene (KPEG). KPEG was not considered a
demonstrated treatment technology since the Agency is not aware of full-scale
applications in operation. KPEG was therefore not considered when determining
BDAT. Treatment performance data were therefore transferred to pentachloro-
dibenzo-p-dioxin from a constituent judged to be similar in elemental
composition and functional groups within the structure of the chemical. The
constituent used to transfer treatment performance data from was
tetrachlorodibenzo-p-dioxin. Tetrachlorodibenzo-p-dioxin was chosen for
transfer since it represents the constituent most similar in structure to
pentachlorodibenzo-p-dioxin. The treatment performance data for
tetrachlorodibenzo-p-dioxin are presented in Tables 4-168A and 4-168B. Using
a transfer from this constituent results in a BDAT for pentachlorodibenzo-p-
dioxin of biological treatment and a BDAT treatment standard of 0.000063 ppm
as described in Section 6.0 and shown in Table 6-10.
TABLE 4-166
WASTEWATER TREATMENT PERFORMANCE DATA
FOR PENTACHLORODIBENZO-p-DIOXINS
DETECTION RANGE NO. OF AVERAGE
TECHNOLOGY TECHNOLOGY FACILITY LIMIT INFLUENT DATA EFFLUENT RECOVERY REMOVAL REFERENCE
SIZE (ppb) CONCENTRATION POINTS CONCENTRATION (I) (t)
KPEG(B) Bench 244B 100-1000 1 0.36000 99.93 WERL
4-305
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
UASIECOOE NAME
INDUSTRY
USE (a)
P028
(continued)
P034
P037
P042
PDAS
P046
P047
P048
P049
P050
P051
P054
2-Cyclohexyl-4,6-dinitrophenol
Oieldrin
Ephinephrine
Thiofanox
Dyes and Pigments
Photography
Dyes and Pigments
Lubricant Manufacturing
Plastics and Resins
Agricultural Chemicals
Pesticides
Petroleun Refining
Pharmaceuticals
Rubber
Pesticide
Pesticide
Medicine
Pesticides
alpha,alpha-Dimethyl phenethylamine Medicine
4,6-Dinotro-o-cresol and salts Pesticide
2.4-Dinitrophenol
2,4-Dithiobiuret
Endosulfan
Endrin and metabolites
Aziridine
Pesticide
Pesticides
Plastics and Resins
Rubber
Pesticide
Pesticide
Specialty Chemical
Manufacture of synthetic tannins
Pickling inhibitors
Manufacture of photographic developer
Manufacture of dyes
Manufacture of lubricants
Manufacture of artificial resins
Manufacture of plastics and plasticizers
Production of electron-beam-sensitive fluid media
Manufacture of fungicides
Manufacture of insecticides
Gasoline gun inhibitor
Penicillin precursors
Rubber accelerators
Insecticide
Insecticide
To counter allergic reactions, prolong infiltration anesthetics
Adrenergic agent
Sympathomimetic. vasconstrictor, cardiac stimulant, bronchodilator
Systemic soil insecticide
Acaricide and nematocide (soil I seed treatment)
No information available
Ovicidal spray for fruit trees
Insecticide
Manufacture of insecticides, rodenticides
Plasticizer, intermediate in resin manufacture
Rubber accelerator
Insecticide for vegetables
Insecticide, in dicldrin
In binders
-------
UASTECODE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
:===ss========sss=ss==asss=5S£=s=========ssss
INDUSTRY
USE (a)
P054
(continued)
Plastics
Specialty Chemical
*-
c»
P057 2-Fluoroacetamide
P058 Fluoroacetic acid
P059 Heptachlor
P060 Isodrin
POM Isocyanic acid, methyl ether
P066 Methomyl
P067 2-Hethylaziridine
Paint Manufacturing
Cosmetics
Adhesives and Sealants
Agricultural Chemicals
Photography
Paper
Pesticides
Petroleum Refining
Textiles
Pesticides
Pesticides
Pesticide
Pesticide
Agricultural Chemicals
Pesticides
Pesticides
Food
Specialty Chemical
Comonomer for polymers
Monomer for polyethyleneimine
As flocculation aids
In surfactants
In ion exchange resins
Chemical intermediate for N-(2-hydroxyethyl)ethyleneimine
Manufacture of trimethylmelanine
Manufacture of taurine
In lacquers
In cosmetics
In adhesives
As plant mutagen to improve varieties
Exhibits sporicidal action
In photographic chemicals
Polymerization products
Control of insect pests by chemosterilization
In petroleum refining chemicals, fuels, oils
Strengthening, shrinkproofing, stiffening, flameproof ing, waterproofing
Insecticide
Rodenticide
Rodenticide
Predacide (predatory animals)
Insecticide for cotton boll weevil
Manufacture and use discontinued in U.S.
Chemical intermediate for carbonate herbicides
Chemical intermediate for carbamate insecticides
Nematocide, insecticide
Chemical intermediate in gelatins
Comonomer for polymer with methacrylic acid & esters
Chemical intermediate for Tris(2-methyl-1,3,5-triazine
Fiber modification
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
UASTECOOE NAME
=========E=================S=S3
INDUSTRY
USE (a)
P067 (continued)
^
VD
P069
Methyllectonitrile
P070
P072
POTS
Aldicarb
1-Naphthyt-2-thiourea
Nicotine
P077
4-Nitroaniline
Adhesive.8 and Sealants
Agricultural Chemicals
Dyes end Pigments
Film
Oil Additives
Paper
Petroleum Refining
Pharmaceuticals
Plastics and Resins
Rubber
Textiles
Specialty Chemical
Pharmaceuticals
Petroleum
Pesticides Manufacturing
Pesticides
Pesticides
Leather and Tanning
Agricultural Chemicals
Pesticides
Veterinary Medicine
Automobile Manufacturing
Petroleum
Dyes and Pigments
As polymer
In inline derivatives for agricultural chemicals
As polymer
Chemical intermediate in photography
Modifiers for viscoseity, high pressure performance, oxidation resist.
Chemical intermediate for oil additives
As polymer
Flocculants, modifier for rocket propellent fuels
Organic intermediate
In inine derivatives for medicinal chemicals
Chemical intermediate in modification of latex coating resins
Organic intermediate
As polymer
Chemical intermediate for methyl methacrylate
Reagent in formation of aldehyde cyanohydrins
Chemical intermediate for methacrylic acid & higher esters
Used to produce a pharmaceutical intermediate
Stereoselective hydrocyanating reagent
Complexing agent for metals refining and separation
Manufacture insecticides
Insecticide, acaracide, nematocide
Rodenticide for Norway rat (former use)
In tanning
Greenhouse fumigant
Insecticide
Ectoparasitic, anthelmintic
Corrosion inhibitor
Chemical intermediate for gasoline gum inhibitors
Chemical intermediate.for dyes and pigments
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
sssssssssssssssssss=sasssssssssccss:ssssssss=s
INDUSTRY
USE (a)
P077 (continued)
P082 N-Nitrosodimethylamine
Ul
o
P084 N-Nitrosomethylvinylamine
POM Endothall
P093 N-Phenylthiourea
P095
Phosgene
Specialty Chemical
Pharmaceuticals
Veterinary Medicine
Lubricant Manufacturing
Research
Specialty Chemical
Petroleum refining
Plastics
Fibers
Agricultural Chemicals
Pesticides
Rubber
Agricultural Chemical Manufacturing
Medicine
Agricultural Chemicals
Plastics and Resins
Specialty Chemical
Chemical intermediate for antioxidants
Chemical intermediate for P-Phenylenediamine
No information available
For poultry
In lubricants
Research chemical
Preparation of thiocarbonyl fluoride polymers
Chemical intermediate for 1,1-Dimethylhydrazine (former use)
Antioxidant
Production of rocket fuels (former use)
Condensers to increase dielectric constant
Inactive metal anode-electrolyte systems (high-energy batteries)
Plasticizer for acrylonitrile polymers, solvent
Softener for copolymers
Solvent
Industrial solvent
Inhibition of nitrification in soil
As nematocide
Plasticization of rubber
Rubber accelerator
Research chemical
Herbicide, defoliant, dessicant, growth regulator,
aquatic algicide and herbicide
In genetics research
Rabbit,rat,weasel repellent
Monomer for polycarbonate resins
Chemical intermediate for toluene diisocyanate
Chemical intermediate for methyl isocyanate
Chemical intermediate for polymethytene polyphenylisocyanate
Intermediate, carbonylating agent
Chemical intermediate for diethyl carbonate,dimethyl carbamoyl chloride
-------
TABLE A-1 (Continued)
INDUSTRIAL USE CF U AND P CHEMICAL PRODUCTS
UASTECOOE NAME INDUSTRY USE (a)
P095
P101
P102
P108
P116
P118
P123
(continued)
Propanenitrile
Propargyl alcohol
Strychnine
Thiosemicarbazide
Trichloromethanethiol
Toxaphene
Munitions
Dyes and Pigments
Organic Chemicals Manufacturing
Specialty Chemical
Automotive
Organic Chemical Manufacturing
Agricultural Chemical Manufacturing
Commercial Testing Laboratories
Pharmaceutical Manufacturing
Pesticides
Agricultural Chemicals
Pesticides
Photography
Pesticide
Chemical intermediate for diphenylmethane-4,4'-diisocyanate
Chemical intermediate for acyl chlorides, chloroformate esters
War gas
Production of aniline dyes
Preparation of organic chemicals
Solvent, dielectric fluid, intermediate
Experimental applications: ulcerogen
Chemical intermediate for Di-n-propylamine
Corrosion inhibitor
Prevent hydrogen embrittlement of steel
Solvent stabilizer
Soil fumigant
Lab reagent
Manufacture of Pharmaceuticals
Destroying predatory animals and trapping fur-bearing animals
Rodent control in forage crops production
Rodent control in fruit production
Reagent for ketones and certain metals
Chemical intermediate for herbicides
Fungicide for rice
Rodenticide
No information available
No information available
Pesticide for cotton crops
(a) Sources: National Library of Medicine, Hazardous Substances Databank (Reference 32).
Handbook of Environmental Data on Organic Chemicals (Reference 33).
Merck Index 1983. (Reference 34).
-------
Waste Number of
Code Facilities*
Table A-2
NUMBER OF FACILITIES THAT MAY GENERATE U AND P WASTES
INCLUDED IN BACKGROUND DOCUMENT VOLUMES A, B, AND C
Waste Number of
Code Facilities*
Waste Number of
Code Facilities*
Waste Number of
Code Facilities*
P001
POOS
P003
P004
POOS
POOS
POK
P016
P017
P018
P020
P022
P023
P024
P026
P027
P028
P034
P037
P042
P045
P046
P047
P048
P050
P051
P054
P057
P058
P059
P064
P066
P067
P069
P070
P072
POTS
P077
P082
P084
P088
P093
P095
P101
P102
P108
P116
P118
P123
U001
U002
U003
U004
U005
U006
U007
U008
U009
U010
U011
U012
U014
U016
U017
U018
3
1
2
3
3
5
6
4
4
3
1
14
5
6
1
2
20
1
9
5
1
1
2
2
6
3
2
2
1
5
4
6
3
2
5
1
3
9
1
1
3
1
23
7
3
6
8
2
4
6
13
22
7
1
13
19
4
22
4
6
27
4
NA
2
2
U019
U020
U021
U022
U024
U025
U026
U027
U029
U030
U031
U033
U034
U036
U037
U038
U039
U041
U042
U043
U044
U045
U046
U047
U048
U050
U051
U052
U053
U055
U056
U057
U060
U061
U063
U064
U066
U067
U068
U070
U071
U072
U073
U074
U075
U076
U077
U078
U079
U080
U081
U082
U083
U084
U08S
U089
U091
U092
U094
U095
U105
U106
U108
U110
U112
. 71
9
5
6
1
2
1
1
3
1
11
8
6
10
10
2
1
2
1
14
38
13
3
2
2
1
13
5
4
11
10
18
1
26
1
1
5
9
9
8
6
13
4
1
19
1
23
2
3
41
3
4
2
2
0
3
2
11
4
2
11
4
9
7
5
U113
U114
U116
U117
U118
U120
U121
U122
U123
U124
U125
U126
U127
U128
U129
U130
U131
U132
U137
U138
U140
U141
U142
U147
U148
U149
U152
U153
U1S4
U1S5
U156
U157
U1S8
U159
U161
U162
U163
U164
U16S
U166
U167
U168
U169
U170
U171
U174
U177
U181
U182
U183
U184
U185
U186
U187
U188
U191
U192
U194
U196
U197
U200
U201
U202
U203
U206
5
1
1
5
2
1
12
73
1
6
5
0
3
2
20
6
4
2
1
19
8
2
6
8
10
1
4
1
12
3
2
1
8
31
5
3
6
4
17
4
17
2
17
2
4
3
1
1
0
2
2
6
3
5
13
11
1
8
6
1
7
1
3
6
3
U207
U208
U209
U210
U211
U213
U220
U221
U222
U223
U225
U226
U227
U228
U234
U236
U238
U239
U240
U243
U244
U247
U248
1
1
3
32
33
6
48
9
1
38
6
44
5
39
1
2
4
42
18
1
2
8
3
•Sources: U.S. EPA 1986 TSDR Survey (Reference 4)
1987, 1988 SRI Directory of Chemical Producers, USA (References 35 and 36)
National Library of Medicine, Toxicology Data Network, Hazardous
Substances Databank (HSDB) (Reference 32)
A-52
-------
State
At
Alaska
Arizona
Arkanaaa
California
EPA
Region
Teble A3
NUMBER OF FACILITIES IN EACH STAIE THAI NAT GENERATE U AND P WASTES
INCLUDED IN BACKGROUND DOCUMENT VOLUMES A, B, AND C
Waste Codes (Nurter of Facilities)
i
Ul
U)
Delaware
Florida
Georgia
Hawaii
Idaho
Illinois
Indiana
Iowa
Kansas
Kentucky
Louisiana
IV
X
IX
VI
IK
Colorado VIII
Connecticut I
III
IV
IV
IX
X
V
V
VII
VII
IV
VI
Maine I
Maryland III
Massachusetts I
POU(1) P022(1) P034(1) P(K2(1) P09S(1) PIOI(I) 0019(2) 0020(1) 0038(1) U06U1) U000(1) U122(3) U129(2) 0051(1) U170(1) U210(1) 0211(2)
U220(1) U228(1) 0239(2) 0244(1)
0061(1) 0220(1) U226(1) U227(1) U228(1) 0240(2)
0211(1) U219(1) U220(2) 0223(1) 0228(1)
P047(1) 0029(2) U06K1) U067(J) 0122(2) 0211(1) U220(1) 0226(1) U240(1)
P004(1) P037(1) P042(1) POM(1) P108(1) O002(t) U03J(1) 0057(2) 0061(2) (1067(1) U070(1) 0072(1)
0124(1) 0129(1) U138(1) U05K1) 0159(2) 0161(1) U188<1) 0211(1) 0218(1) U220(2) 0223(1) 0225(1)
P066(1) 0226(1) U239<1)
0075(3) 0080(3) 0082(1) 0121(3) 0122(1)
0226(6) 0228(4) 0239(4)
P022(1) PI16(1) U006(1) U007(1) 0031(1) 0044(2) 0073(1) 0075(1) 0077(1) 0080(1) 0091(1) O092(1) 0138(1) U148(1) 0158(1) 0159(1) 0163(1)
0210(1) 0219(1) U220(1) 0223(3) 0226(2) 0239(1) 0244(3)
P014(1) P022(1) P028(1) P050(1) P066(1) P070(1) P077(1) P095(1) PIOI(I) P108(1) 0006(2) 0007(1)
0020(1) 0022(1) 0036(1) 0044(1) 0048(1) 0055(1) 0056(1) 0061(1) 0070(2) 0071(1) 0072(2) O074(1)
0105(1) 0114(1) U116(1) U127(1) U131(1) 0138(1) 0148(1) 0152(1) 0154(1) U163(1) 0165(1) 0167(1)
0210(2) 0211(1) 0218(1) 0220(1) 0223(1) 0226(1) 0227(1) 0228(1) 0239(1) 0240(1) 0247(1)
P016(1) P088O) 0057(1) 0075(1) 0080(1) 0082(1) 0092(1) 0110(1) 0125(1) 0142(2) 0147(1) 0154(1)
0226(2) 0228(1) 0239(2)
P050(1) P070O) 0033(1) 0057(1) 0061(2) 0114(10)0122(1) 0129(1) 0051(1) 0159(1) U170(1) 0220(1)
P059(1) 0061(1) (1129(1) U240(1)
0051(1) U228(1)
P037(1) P042(1) P077(2) 0003(3) 0004(1) 0009(3) 0011(1) U012(1) 0019(2) U033(1) 0036(1) 0037(1)
0072(1) 0075(1) 0077(1) 0117(1) 0121(2) 0122(2) 0130(1) 0148(1) 0051(2) 0155(1) 0158(1) 0159(2)
0206(1) 0210(1) U21U2) U219(1) 0220(3) (1223(1) 0225(1) 0226(2) 0228(2) U234(1) 0239(1) 0240(4)
0009(1) 0011(1) 0012(1) 0018(1) 0019(1)
0077(1) 0079(1) 0080(1) 0089(2) 0092(1)
0169(1) 0185(1) 0194(1) 0202(1) O209(1)
0158(1) 0194(1) 0210(1) 0220(2) 0223(2)
0228(2)
0044(2) 0045(1) U052(1) O057(1) O070(1)
0165(1) 0169(1) 0171(1) 0174(1) 0191(1)
P008(1) P017(1) P095(1) 0002(1) 0031(1) O080(1) U092(2> 0171(1) 0188(1) 0191(1) U196(1) 0228(1)
0061(1)
0002(1) U004(1) 0057(1) 0122(2) 0132(1) 0138(1) 0159(1) 0188(1)
0009(1) U043(1) 0044(1) 0045(1) 0057(1) O070(1) 0075(1) 0080(1) U092(1) U122(2) 0051(1) 0211(1) 0220(1) O22KD 0226(1)
0037(1) 0039(1) 0043(6) 0044(1) 0045(2)
0165(1) 0169(1) 0185(1) 0188(1) 0194(1)
P003(1) P022(1) P024(2) P095(3) 0007(2) 0008(1) U009(2) 0012(2) O015(2) 0016(1) 0031(2) U036(1)
0057(1) 0061(1) 0077(6) 0080(1) 0108(1) O113(1) 0121(1) 0122(5) 0148(5) 0154(3) 0159(1) 0162(1)
0200(1) 0211(2) 0213(1) 0220(3) 0221(2) 0223(3) 0227(1) 0239(2) O247(1)
0036(1)
P095(1) U(W2(1) 0080(1) 0156(1) 0223(2) O226(1) 0228(3)
P023(2) P050(1) 0003(2) O007(1) U009(1) U044(2) U053(1) U057(1) 0080(2) U108(1) UI10M) U112(1) U122O) UOS1(1) U159(2) O193(1) U194(1)
U210(1) U220(2) 0226(1) U238(1) U2J9(1) U247(1)
-------
State
Michigan
EPA
Region
Table A-3 (continued)
NUMBER OF FACILITIES IN EACH STATE THAT NAY GENERATE U AND P WASTES
INCLUDED IN BACKGROUND DOCUMENT VOLUMES A. B. AND C
Uaste Codes (Nuifcer of Facilities)
P064(1) P088(1) P095(1> U007(1) 0045(I) UOoBd) U073CD U075(1) U07B(1) U080(1) UOai(l) U110(I) UI12(1) UI2K1) 0165(1) 0206(1) 0211(1)
0219(1) U225(1) 0240(1)
Minnesota
Mississippi
NiMouri
Montana
Nebraska
Nevada
New Jersey
V
IV
VII
X
VII
IX
II
>
Ul
New Mexico VI
New York II
North Carolina IV
North Dakota VIII
Ohio V
Oklahoma VI
Oregon X
Pennsylvania III
Puerto Rico II
Rhode Island I
P067(1) P077(1> 0019(1) 0044(1) 0061(1) U07U1) 11080(2) U082(1) 0122(1) U1B5(1) U226(1) U227(1) 0247(1)
P020(1) P022(1) POSO(I) U012(2) 0044(1) U1U(1) 0122(3) 0129(2) U169(1) U211(1) U220(1) U223(1) U226(1) U228(1) 0247(1) '
P004(1) P037(1) POSOd) P05H1) POS9(1) P066(1) P070(1) PIOI(I) P108(1) P123(1) U003(1) U006(1) U007(2) UOII(I) U012(1) U019(2) U036(1)
U037(1) UOU(I) U05o(1) U061(2) U072d) UOTSd) U077(1) UOTVd) U080(2) U09U1) U117(1) U122(1) U129d) U13K1) U155C1) U1S8(1) U16S(1)
U167{1) U169(1) UlBSd) UlSSd) Uie/d) U200(1) U211<1) U220(S) U22Sd) U239d) U240<1) U247(1)
U122(1)
U12S(1)
P123(1) 0034(1) 0061(1) U072(1) UOBO(I) U22B(1> POU(I)
POOKD P017(2) POIB(I) P022(1) P023d) P024(2> P028(6) P037(1) P047(1> P048(1) P057(1) P067(2) P072(1) P077(1) P095(1) P116(3) U002d)
U004(3) U006(5) U007(3) 0009(1) U01K1) U012(3) UOU(3) U017(1) U019(1) 11031(2) U033(1) 0037(1) 0044(3) 0045(1) 0052(1) U057(1) U06K2)
0067(1) 0068(4) U071(1) U072(1) 0075(4) 0080(2) U092(1) 0105(1) 0108(3) U110(1) 0117(1) 0121(2) 0122(5) 0124(1) U125(1) 0138(6) 0141(1)
0147(1) 0148(2) 0159(10)0161(1) 0163(1) 0165(2) 0166(1) U167(1) U169(2) 11181(1) 0187(1) U168(1) 0191(2) 0194(1) 0196(2) 0200(2) 0203(4)
0218(4) 0219(2) 0220(1) 0222(1) 0223(1) 0226(2) 0228(2) 0236(2) 0238(1) 0239(3) 0244(1) 0248(1)
P095(1) 0209(1) 0210(1) 0211(1) 0220(1) 0223d) 0225(1) 0226(2) 0228(1) U239(1)
POOKD P008(1) P016(1) P017(1) P022(1) P023(1) P027(1) P02B(1) P075(1) P093(1) P095(1) P10K1) P108(2) P116(2) U003(3) 0007(3) 0009(1)
0010(2) 0012(1) 0020(2) U02K2) 0022(2) 0037(1) 0044(4) 0045(2) 0046(1) 0047(1) 0052(1) 0057(1) 0061(1) 1)064(1) O067(1) 0068(2) 0070(1)
0077(1) 0080(2) U094(1) 0095(1) 0105(1) 0114(1) 0122(3) 0129(1) 0130(1) 0138(4) 0140(1) 0147(1) 0159(3) 0163(1) 0165(2) 0166(1) 0169(3)
0184(1) 0187(2) 0191(3) 0196(2) 0200(1) 0202(1) U207(1) U210(5) 11211(3) 0219(3) 0220(2) 0221(1) 0223(8) 0228(3) 0239(3) 0248(1)
P008(1) P014(1) P022(1) P028(1) P037(1) P048(1) P050(1) P05K1) P059(1) P10K1) P123(1> U003(2) UOOS(I) 0006(1) 0007(1) 0009(1) 0010(1)
0011(1) 0012(2) 0014(1) 11018(1) 0019(1) 0021(1) 0022(1) 0034(1) 0036(2) O037(1) 0043(1) 0044(2) 0050(1) 0056(1) U064(1) 0067(1) 11068(1)
U070(1) 0077(1) 0080(2) 0069(1) U092(1) 0110(1) U119(1) 0122(6) 11127(1) 0128(1) 0129(1) 0141(1) 0142(1) 0148(1) 0157(1) 0158(1) 0163(1)
0165(1) 0168(1) 0169(1) 11174(1) 0177(1) 0200(1) U203(1) U210(2) U21K1) U220(1) 0221(1) 0226(1) 0228(1) 0238(1) 0239(1)
0061(1)
P037(1) P077(1) P095(2) PI18(1) 0001(2) 0003(1) U007(1) 0009(2) U012(6) 0019(1) 0021(1) 0033(1) 0034(1) 0037(1) 0044(5) 0056(3) 0057(1)
0061(1) U07KD 0072(1) 0077(1) 0080(3) 0095(1) 0108(1) 0122(4) 0125(1) 0131(1) 0138(1) 0051(1) 0185(1) 0188(1) 0194(1) 0202(1) 0210(2)
0211(2) 0220(2) 0221(1) 0223(3) 0226(5) 0228(4) 0239(3) 0240(2)
0210(1)
0019(1) 0037(1) U038(1) 0077(1) 0122(8) 0220(1) 0239(1)
P024(1) P028(3) P037(1) P077(1) 0001(1) U002(2) 0004(1) 0006(1) 0009(1) 0011(1) U0?0(1) U02M1) U03K2) U044(2) 0045(1) U046(1) U053(1)
0055(2) 0057(1) 0061(2) 0067(1) 0072(1) 0075(3) 0077(2) 0080(3) O105(1) 0114(1) 0117(1) 0121(2) 0122(2) U124(1) 0129(2) 0130(1) 0142(1)
0147(2) 0152(1) 0159(3) 0165(1) 0188(1) 0191(1) 0192(1) 0196(1) 0201(1) 0210(1) 0219(2) 0220(2) 0226(4) 0228(2) 0239(2) 0240(1) 0244(1)
0002(1) U003(2) 0004(1) 0019(1) 0031(1) 0037(1) 0044(1) 0056(1) 0077(1) 0080(1) UKO(1) U169(1) 0191(1) O220(1) O239(1)
0138(1) U21K1)
-------
State
South Carolina IV
EPA
Region
Table A-3 (continued)
NUMBER OF FACILITIES IN EACH STATE THAT NAY GENERATE U AND P WASTES
INCLUDED IN BACKGROUND DOCUMENT VOLUMES A, B. AND C
Uaste Codes (Nunber of Facilities)
P008(1) P037(1) 0017(1) 0019(1) 0044(1) U061(1) 0072(1) 0075(1) U077(1) 0080(1) U108(1) 0121(1) 0122(4) U129(2) U130(1) 0138(1) UU2(1)
U05K1) U210(2) 0211(2) O219(1) U220(2) 0226(2) 0228(1) 0239(2) 0240(1)
Tennessee
Texas
Utah
Verannt
Virginia
IV
VI
VIII
III
P022(1) P028(1) P059(1) P069(1) P075(1) 000J(1) 0012(1) 0019(1) 0020(1) 0053(1) 0061(1) 0072(1) 0112(1) 0124(1) U129(1) U130(1) 0140(1)
U154(1) 0159(1) U16K1) U162(1) 0197(1) 0211(1) 0213(1) 0228(1) I
P022(1) P066(2) P069(1) P095(5) P10HD P116(1) P118(1) 0001(3) 0002(5) O003(4) 0006(1) 0007(1) 0008(3) 0009(4) 0012(3)
U025(1) U026(1) 0027(1) 0031(2) 0033(1) 0034(2) U036(1) 0041(2) 0043(5) O044(3) 0045(1) O052(1) 0056(1) 0057(3) 0061(2)
0074(1) U077(3) U080(4) 0081(1) 0084(1) O092(1) U105(2) 0106(1) 0108(1) 0112(2) 0113(4) 0114(1) 0118(1) 0122(10)0123(1)
0140(4) U147(1) 0051(1) 0152(1) 0153(3) 0154(6) 11156(1) 0159(3) 0161(1) 0162(1) 0165(4) 0166(1) 0169(1) 0171(1) 0188(3)
0211(4) 0213(1) 0220(7) 0221(2) 0223(5) 0226(2) O228(2) 0239(1) 0240(1)
Washington X
Uest Virginia III
P005(2) P014(1)
0019(4) 0020(1)
0072(1) 0073(1)
0129(2) 0138(1)
0194(1) 0210(3)
P054(1)
0044(1)
P018(1) P077(1) 0007(1) 0019(2) 0020(1) 0036(1) 0044(2) 0057(1) 0080(1) 0110(1) 0117(1) 0129(1) 0140(1) 0051(1) 0158(1) 0167(1) 0194(1)
0210(3) 0211(2) 0219(1) 0220(1) 0223(2) 0226(1) U226X1) 0239(1)
P002(1) P016O) P022(1) P028(1) P042(2) 0019(1) 0022(1) 0043(1) 0044(1) 0055(1) O056(1) 0064(1) 0075(1) 0080(1) 0122(2) 0152(1) 0158(2)
0169(1) 0188(2) 0210(1) 0211(1) 0219(1) 0220(1) 0226(2) 0228(1) 0239(2) 0240(1)
P004(1) P022(1) P045(1) P064(2) P066(1) P070(2) 0002(2) 0003(1) 0009(2) 0012(2) U044(1) 0045(2) 0053(1) 0070(1) O072(1) 0077(1) 0080(2)
0092(1) 0105(2) U106C2) U108(1) 0116(2) 0118(1) 0122(2) 0147(1) 0148(1) 0159(1) 0161(1) 0165(1) 0169(2) 0191(2) 0210(1) 0223(3) 0244(1)
0247(1)
Wisconsin V
POOK1)
P059O)
0019(1)
0063(1)
0105(1)
0149(1)
0203(1)
P003(1) P005(1)
P075(1) P077(1)
0020(1) 0021(1)
0064(1) 0067(1)
0110(1) 0116(1)
0051(1) 0152(1)
0206(1) 11208(1)
POOB(I)
P082O)
0022(1)
0068(1)
0119(1)
11153(1)
0211(1)
P014(3) P016(1)
P084(1) P095(1)
0029(1) 0030(1)
0071(1) 0072(1)
0120(1) 0122(1)
0155(1) 0163(1)
0214(2) 0218(1)
P017(1) P018(1)
P10K1) P102(1)
0034(1) 0036(1)
11073(1) 0074(1)
11125(1) 0127(1)
0165(1) 0166(1)
0219(1) 11220(2)
P022(1) P023(1)
P108(1) PI 16(1)
0037(1) 0045(1)
0076(1) 0077(1)
0128(1) 0129(1)
0168(1) 0169(1)
0221(1) 0225(1)
P024(1)
P123(1)
U046(1)
0079(1)
0130(1)
0171(1)
0226(1)
P026(1) P027(1)
0003(1) 0006(1)
0047(1) 0048(1)
0081(1) 0082(1)
0131(1) 0132(1)
0174(1) 0183(1)
U227(1) 0238(1)
P037(1)
0007(1)
0055(1)
0083(1)
0137(1)
U185(1)
U240( 1 )
P046O)
0009(2)
0056(1)
0084(1)
0138(1)
0187(1)
0243(1)
P05K1) P054(1)
0010(1) 0012(1)
0057(1) 0060(1)
0089(1) 0092(1)
0142(1) 0147(1)
0193(1) 0200(1)
0247(1) 0248(1)
-------
Table A-4
AVERAGE CONCENTRATION OF MEASUREMENT "HITS'
ON LEACHATE (In ppb)
BOAT
NO.
222
S3
3
56
154
155
156
4
157
173
176
67
70
5
y*
1 1
223
158
8
7
74
9
11
14
15
78
159
221
160
81
82
169
84
85
18
19
86
87
22
23
25
24
90
192
26
96
100
29
219
226
227
224
106
PREFIX
A
•J»
rt-
P-
2-
o-
P-
1,2-
p-
1.3-
U-
1,1-
1.2-
Trena-1.2-
1.1-
2.4-
2.4-
U-
2.4-
4.6-
1.4-
2
COMPOUND
Acetone
Acetophenome
Acrytonrtrile
Aniline
Antimony
Arsenic
iarium
Benzene
Beryllium
BHC-alpha
BHC-gamma
3i«(2-chloroethoxy)methane
Bls(2-ethylhexyf)phtrialate
Bromodichloromethane
D hi i. i MttiAr
Butyl alcohol
Cadmium
Carbon diaulfid*
Carbon tatrachlorida
Chloroanilin*
Chlorab«nz«n«
ChlofodibrorfMthan*
Chlorotorm
ChloronwttMfw
Chloropheool
Chromium (total)
Chromium, VI
Copper
Crettl
Craaol
Cyanide* (total)
Oibenzo(a.e)pyrene
3ibenzo(a.O py rene
Oibramoetnane
nihrnmnm*tfianA
uwonuMnemana
Dicnlorooenzena
Dichlof uCMnzvno
_.j , . .
UlCf IIOI OUOf U9I M
OieMoroethane
Dtehkxoethane
OL-hiA. n Hi ana
u ic niof Owinw n •
ni hi i •(! iAn
UtCilKJIUvUiyMnV
•i » , L I
UfdiiOfOpnvnoi
#%1 LI »_ _^ -J
jicniOrOpnvnoxyvcviic •cio
•hi L I
LnCniOfOpfvpWfV
n* ii i h i
LmTMVTy Ipr ICnOl
DinHro-o-creaol
Oioxane
Diphenylnitroaamine
Ethyl benzene
Bhyl ether
B.. .. *
etnyoxyeinafioi
n iiiiHn
riuuiaiiuwiia
CWM/WMNA LEACHATES
CID2
5950.0
3S.O
3133.333
90.667
236.667
15.0
2800.0
103.0
35.667
123.0
640.0
130.0
41.5
MC06
12233.333
450.0
89.333
143.333
28.0
3.5
18.15
2200.0
68.333
29.0
195.0
58.0
8.0
296.667
1183.333
236.667
0.035
0.53
150.0
90.0
275.0
39.0
BSCALE
9133.333
9913.333
38.333
39.0
5.0
6008.5
141.0
10.0
5.2
162.0
516.667
61.0
24666.667
186.667
620.0
570.0
1100.0
DOW
LEACHATE
713.333
51.0
140.0
75.0
15.0
656.667
270.0
590.0
46.667
3.0
20667
&W*^V
1700.0
33.0
470.0
9.0
250.2
1290.0
24.333
16.0
11.0
30.0
6.0
39.333
114.2
364.0
19.0
10.0
4815.333
212.0
320.0
8.5
100.0
10.0
1000.0
19.0
137.2
64.0
9.0
BFI
LEACHATE
160000.0
4000.0
4000.0
530.0
29.0
120.0
34000.0
63.0
440.0
9900.0
4500.0
3500.0
190.0
17.0
35.0
3500.0
12000.0
290.0
2200.0
2100.0
1100.0
4400.0
4800.0
25000.0
260.0
370.0
3900.0
40000.0
A-56
-------
Table A-4 (Continued)
AVERAGE CONCENTRATION OF MEASUREMENT'HITS'
ON LEACHATE (in ppb)
BOAT
NO.
106
170
110
111
206
207
33
189
161
162
228
34
229
38
121
163
196
205
206
136
210
139
141
142
220
143
145
39
164
165
193
171
148
213
211
9^9
«I«
41
149
166
43
44
150
46
45
47
151
152
194
49
167
SO
PREFIX
2-
12,4,5-
2.3,7,8-
1.1.22-
2.3,4.6-
12.4-
1,12-
1,1,1-
2.4.5-
2.4,6-
2.4.5-
12.3-
COMPOUNO
Fluoranthene
Fluoride
Hexachlorobenzene
Hexachtorobutadiene
Hexachlorodibenzo-furan*
Hexachlorodibenzo-p-dioxins
leobutanol
Kepone
Lead
Mercury
Methanol
Methyl ethyl ketone
Methyl isobutyl ketone
Methylene chloride
Naphthalene
Nickel
Parathion
PCB-Aroclor 1254
PCB-Arockx 1260
Pentachlorobenzene
Pentachlorodibenzo-ruran*
Pentachlorophenol
Phenai ittirene
Prienol
Phthalic anhydride (aa acid)
Pteoline
Pyrane
Pyridine
Selenium
Silver
Silvex
Suffide
Tetrachlorobenzene
Tetrachlorodibenzo-p-dioxin
Tetrachlorodibenzo-p-dioxirn
T*a*6nlorodiD*nzofuran*
Tetrachtofoethane
etracmofoeinene
Tetrachtorophenol
Thallium .
Toluene
Tribromomethane
Trichlorobenzene
T nchiofoetnane
Trichloroethane
Trichloroethylene
Trichlorophenol
Trichtoro phenol
Trichlorophenoxyacetic acid
Trichloropropane
Vanadium
Vinyl Chloride
CWM/WMNA LEACHATES
CID2
1850.0
8933.333
27.333
02
15666.667
8166.667
3600.0
820.0
53.5
250.0
1780.0
61.0
4.6
5600.0
430.0
180.0
42.333
MC06
2200.0
0.013
4833.333
17.0
2.4
24666.667
9033.333
8200.0
3066.667
650.0
30.0
0.097
10600.0
32000.0
7.9
8800.0
n /MM
O.UOZ
816.667
•fi A
os.o
473.333
110.0
67.0
110.0
383.333
71.0
BSCALE
78333.333
0.019
0.021
3.9
200.0
25.333
1.4
21889.333
7066.667
2166.667
1766.667
856.667
170.0
0.032
18333.333
37450.0
1200.0
78.667
15.0
2300.0
0.034
0.048
f\ tvt
0.03
3.9
176.667
40.5
11.0
DOW
LEACHATE
9.0
3530.0
35.667
11.0
02
49200.0
213.333
2440.0
80.0
9.0
66.8
59.667
10.5
1472.0
7.0
2.0
8.0
3.0
27066.667
208.0
•% *
0.4
17 A
27.4
41.0
110.0
1058.0
9.0
340.0
20.5
8.5
25.0
26.0
6.0
12.0
47.5
BFI
LEACHATE
520.0
8500.0
1400.0
0.7
470000.0
170000.0
13000.0
110.0
180000.0
37.0
60000.0
*}AfV\ f\
Z4OO.O
8700.0
500.0
8800.0
450.0
A-57
-------
Table A-4 (Continued)
AVERAGE CONCENTRATION OF MEASUREMENT "HITS'
ON LEACHATE On ppb)
BOAT
NO.
215
216
217
168
PREFK
1,2-
1.3-
1.4-
COMPOUNO
XylWM
Xyl«fM
Xyl*n«
Zinc
Xyl«n«» (totaO
CWM/WMNA LEACHATES
CI02
323.333
2490.0
MC06
300.0
296.667
BSCALE
9^
1ZO
12.0
158.0
DOW
LEACHATE
428.333
295.8
BFI
LEACHATE
64.0
700.0
A-58
-------
APPENDIX B
U and P Wastes Arranged by Third Third
Treatability Groups
B-l
-------
APPENDIX B
WASTE TREATABILITY CROUPS
II.A.2.b.(3)
Halogenated allphatlcs
ANALYZABLES:
U044,
0074,
U076,
U077,
0078,
0079,
U080,
U083,
0084,
0131,
U184,
U208,
U209,
U210,
0211,
0226,
0227,
0228,
0243,
Chloroform
l,4-Dichloro-2-butene (trans) and
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethylene
1,2-Dichloroethylene
Mechylene chloride
1,2-Dlchloropropane
1,3-Dichloropropene (trans), (els)
Hexachloroethane
Pentachloroethane
1,1,1,2-Tecrachloroethane
l,l,2,2_Tetrachloroethane
Tetrachloroethylene
Carbon tetrachloride
1,1,1-Trlchloroethane
1,1,2-Trichloroethana
Trlchloroethylene
Hexachloropropene
(cis)
III.A.2.c.(3).(a)
Halogenated pesticides and chlorobenzenes - chlorinated norbornane
and norbornene derivatives
ANALYZABLES:
P004, Aldrin
P037, Dieldrin
P050, Endotulfan (I), (II), and (sulfate)
P051, Endrin
POS9, Heptachlor
P060, Isodzin
P123, Toxaphene
0036, Chlordane
0130, Hexachlorocyclopentadiene
0142, Kepone
III.A.2.c.(3).(b)
Halogenated pesticides and chlorobenzenes
ANALYZABLES:
0037, Chlorobenzene
0070, 1,2-Dichlorobenzene
0071, 1,3-Olchlorobenzene
0072, 1,4-Dichlorobenzene
0127, Hexachlorobenzene
0183, Pentachlorobenzene
0185, Pentachloronitrobenzene
0207, 1,2,4,5-Tetrachlorobenzene
III.A.2.c.(3).(c)
Halogenated pesticides and chlorobenzenes - chlorophenoxycarboxylic aicd and derivatives
ANALYZABLES:
B-2
-------
U240, 2,4-D
UNANALYZABLES:
U240, 2,4-D salts and esters (I)
I .(d)
Halogenated pesticides and chlorobenzene - chlorinated diphenyls
ANALYZABLES:
U038, Chlorobenzllate
U060, ODD
U061, DDT
U132, Hexachlorophene
U247, Methoxychlor
III.A.2.c.(3).(e)
Halogenated pesticides and chlorobenzene - Llndane and hexachlorobutadlene
ANALYZABLESi
U128, HaxAchlorobutadlene
U129, Llndane
III.A.2.d
Halogenaced phenolic*
ANALYZABLESi
U039, p-Chloro-m-cre»ol
U048, 2-Chlorophenol
U081, 2,4-Dlchlorophenol
U082, 2,6-Dlchlorophenol
III.A.2.e
Bromlnated organi.cs
ANALYZABLCS:
UNANALYZABLES:
U029, BroDomethane
U030, 4-Bromophenyl phenyl ether
U066, 1,2-Dlbromo-3-chloropropane
U067, Ethylena dlbromide
U068, Dlbromomethane
U22S, Bromoform
P017, Bromoacetone
U246, Cyanogen bromide
III.A.2.£.(1)
Chlorinated dlphenyls
ANALYZABLES:
U073, 3,3'-Dichlorob«niidine
U158, 4,4-Methylen*-bii-(2-chloro«nilin«)
B-3
-------
III.A.2.f.(2)
Chlorinated polynuclear aromatics
ANALYZABLES:
UNANALYZABLES:
U047 2-Chloronaphthalene
U026, Chloronaphazine
III.A.2.f.(3)
Chlorinated amides and amides
ANALYZABLES:
UNANALYZABLES:
P024, p-Chloroanlllne
U192, Pronamlde
P057, 2-Fluoroacetamide
U049, 4-Chloro-o-toluldlne hydrochloride
U097, Dimethyl carbonyl chloride
U222, o-Toluldine hydrochloride
III.A.2.f.(4)
Chlorinated methylbenzenei
ANALYZABLESI
UNANALYZABLESI
U017, Benial chloride
P028, Benzyl chloride
Halogenated allphatics
ANALYZABLES:
UNANALYZABLES:
U0443,Vinyl chloride
U045, Chloromethane
U075, Oichlorodifluoromethane
U121, Fluorotrichloromethane
U138, lodomethane
P027, 3-Chloroproprlonltrlle
III.A.2.f.(6)
Halogenated aldehydes/
ethers and esters
ANALYZABLES:
U024, bis-(2-Chloroethoxy)methane
U025, Dichloroethyl ether
U027, bis-(2-Chloroisopropyl) ether
U042, 2-Chloro«thyl vinyl ether
B-4
-------
UNANALYZABLES:
U034, Trichloroaceataldehyde
0156, Methyl chlorocarbonate
P016, bis-(Chloromechyl)ether
P023, Chloroacetaldehyde
P058, Fluoroacetic acid
P095, Phosgene
U006, Acetyl chloride
U033, Carbonyl Fluoride
U041, n-Chloro-2,3-epoxypropane
U046, Chloromethyl methyl ether
III.A.2.f.(7)
Chlorinated organosulfurs
ANALYZABLES:
P026, l-(o-Chlorophenyl)thiourea
P113, Trichloromethanthiol
U020, Benzenesulfonyl chloride
U062, Dlallate
III.A.3.b
Aromatica and other hydrocarbon!
ANALYZABLES:
U019, Benzene
U220, Toluene
U239, Xylenes
U055, Cumene
0056, Cyclohexan*
U0186, P«ntadi«n»
III.A.3.c
Polynuclear aromatic hydrocarbon!
ANALYZABLES:
UNANALYZABLES:
U005, 2-Acetylaninofluorene
U018, Benz(a)anthracene
U022, Benzo(a)pyr»ne
U050, Chryiana
U063, Dibenzo(a,h)anthracene
U120, Pluoranthene
U137, Indeno(l,2,3-c,d)pyrene
U1S7, 3-Methylcholanthrene
U165, Naphthalene
U051, Creosote, Regulated with numerical standards for individual
constituents ... Naphthalene
Pentachlorophenol
Phennathrene
Pyrene
Toluene
Xylenes
Lead
U016, Bent(c)acridine
U064, 1,2,7,8-Dibenzopyrene
U094, 7,12-Dioethylbenz(a)anthracene
B-5
-------
III.A.3.d
Phenolics
ANALYZABLES:
UNANALYZABLES:
P020, Dinoseb(2-sec-Butyl-4,6-dinitrophenol)
P047, 4,6-Dinitro-o-cresol and salts
P048, 2,4_Dinitrophenol
U052, Cresols
U101, 2,4-Dimethylphenol
U170, 4-Nitrophenol
U188, Phenol
U201, Raaorcinol
P034, 2-Cyclohexyl-4,6-dlntrophenol
III.A.3.e
Oxygenated hydrocarbons and heterocycllcs
ANALYZABLES:
UNANALYZ ABLES:
P003, Acrolein
U002, Acetone
U004, Acetophenone
U031, N-Butanol
U057, Cyclohexanone
U108, 1,4-Dioxane
U112, Ethyl acetate
U117, Ethyl ether
U118, Ethyl methacrylate
U140, iBObutanol
U154, Methanol
U159, Methyl ethyl ketone
U161, Methyl isobutyl ketone
U162, Methyl methacrylate
Ul 6 6, 1,4-Napht hoquInone
U197, p-Benzoquinone
P001, Warfarin
POOS, Allyl alcohol
P088, Endothall
U123, Formic acid
U248, Warfarin (>0.3%)
P102, Propargyl alcohol
U001, Acetaldehyde
U008, Acrylic acid
U124, Furan
U125, Furfural
U213, Tetrahydrofuran
U08 5, 1,2,3,4-Dlepoxybutane
U113, Ethyl acrylate
U122, Formaldehyde
U053, Crotonaldehyde
U126, Glycidaldehyde
U147, Malelc anhydride
U182, Paraldehyde
III.A.3.f.(I)
Nitrogen hetercyclic compounds
B-6
-------
ANALYZABLES!
UNANALYZABLES:
U179, N-Nicrosopiperidine
U180, N-Nitrosopyrrolidine
U196, Pyridine
POOS, 4-Arainopyridine
P018, Brucine
P054, Ethyleneinine (Aziridine)
P067, 2-MeChylaziridlne
U011, Amitrole
U148, Maleic hydrazide
U191, 2-Picoline
III.A.3.f.(2)
Amides and amines
ANALYZABLES:
UNANALYZABLES:
U007, Acrylamide
U012, Aniline
U167, 1-Naphthylamine
U168, 2-Naphthylamine
P046, alpha,alpha-Dimethylphenethylamins
P064, Isocyanic acid, methyl ester
U092, Dlmethylanlne
U110, Dipropylamine
U194, n-Propylaoin*
U238, Ethyl carbaoate
III.A.3.f.(3)
Aminated diphenyls/biphenyls
ANALYZABLES:
U021, Benzidine
U091, 3,3'-Dimethoxybanzidine
U093, p-DlD«thylanino«xob«nz*n*
U09S, 3,'-Dimethylb«nzidin«
U014, Auraaine
U236, trypan blue
III.A.3.f.(4)
Nitriles
ANALYZABLES:
UNANALYZABLES:
P101, Propanenitrile (ethyl cyanide)
U003, Acetonitrile
U009, Acrylonitrile
U152, Methacrylonitrile
U149, Malonltrile
P069, Methyllactonitrile
B-7
-------
III.A.3.f.(S)
Nitro compounds
ANALYZABLES:
UNANALYZABLES:
P077, p-Nitroaniline
U105, 2,4-Dlnitrotoluene
U106, 2,6-Dlnitrotoluene
U169, Nitrobenzene
U181, 5-Nitro-o-toluidine
U234, sym-Trinltrobenzene
U171, 2-Nltropropane
III.A.3.f.(6)
Nittroso compounds
ANALYZABLES:
P082, N-Nitrosodimethylamlne
Ulll, Dl-n-propylnitroaoamine
U172, N-Nitroso-di-n-butylamine
U174, N-Nitroeodiethylamine
P084, N-Nitro§omethylvinylamina
U173, N-Nitroso-diethanolaoine
U176, N-Nitroso-N-echylurea
U177, N-Nitroso-N-methylurea
U176, N-Nitroso-N-methylurothane
III.A.3.g
Organosulfur compounds
ANALYZABLES:
UNANALYZABLES:
P014, Thiophenol
P022, Carbon disulfide
P002, 1-Acetyl, 2-thiourea
P049, 2,4-Dithiobiuret
P066, Methomyl
P070, Aldicarb
P072, l-Naphthyl-2-thiourea
P093, N-Phenylthiourea
P116, Thiosemicarbazide
U114, Ethylene bis-dithiocarbamic acid
U116, Ethylene thlourea
U193, 1,3-Propane sulfone
U153, Methanethiol
U218, Thioacetamide
U219, Thlourea
U244, Thlram
P045, Thiofanox
U119, Ethyl methane sulfonate
III.A.3.h
Pharmaceutical compounds
ANALYZABLES:
P108, Strychnine and salts
B-8
-------
UNANALYZABLES:
U141, Isosafrole
U1S5, Methapyrilene
U187, Phenacetln
U203, Safrole
P007, 5-Aminoethyl 3-isoxazolol (muscimol)
P042, Epinephrine
P075, Nicotine and sales
U010, Mitomycin
U015, Azaserlne
U035, Chlorambucll
U059, Daunomycln
U089, Diethylstilbestrol
U143, Laalocarplne
U150, Melphalan
U163, N-Methyl-, N-nltro-, N-nltroguanidlne
U164, Methylthiouracil
U200, Reserplne
U202, Saccharin
U206, SCreptozococin
U090, Dihydrosafrole
U237, Uracll mustard
III.A.4.f.(1)
Inclnerable reactive organic! and hydratine derivative*
ANALYZABLES:
UNANALYZABLES S
U096, alpha,alpha-Dimethyl benzyl hydroperoxide
U109, 1,2-Dlphenylhydrazine
POOS, Ammonium picrate
P081, Nitroglycerin
U133, Hydrazine
U086, N,N-Diethylhydrazlne
U160, Methy ethyl ketone peroxide
P068, Methyl hydrazine
PI12, Tetranitrooethane
U023> Bencotrichloride
U09B, 1,1-Dimethylhydrazine
U099, 1,2-Dimethylhydrazine
U103, Dimethyl sulfate
III.A.4.f.(2)
Incinerable organics
ANALYZABLES:
P096, Phosphine
P105, Sodium azlde
U189, Phosphorus sulfide
U249, Zinc phosphide (<10%)
POOS, Aluminum phosphide
P122, Zinc phosphide (>10%)
U13S, Hydrogen sulfide
III.A.4.f.(3)
Fluorines
UNANALYZABLES:
U134, Hydrofluoric acid
P056, Fluorine
B-9
-------
III.A.4.f.(4)
Recoverable metallics
ANALYZABLES:
UNANALYZABLES:
P015, Beryllium dust
P073, Nickel carbonyl
P087, Osmium tetroxlde
III.A.S.b
Arsenic and Selenium
UNANALYZABLES:
P103, Selenourea
U136, Cacodyllc acid
P036, Dlchlorophenylarslne
P038, Dlethylarslne
P010, Arsenic acid
P011, Arsenic (V) oxide
P012, Arsenic (III) oxide
P114, Thalluo selenlte
U204, Selenlous acid
U205, Selenium dlsulflde
III.A.5.e
Chromium
ANALYZABLES:
UNANALYZABLES:
U032, Calcium chromate
P110, Tetraethyl lead
U144, Lead acetate
U145, Lead phosphate
U146, Lead subacetate
III.A.5.g
Mercury
ANALYZABLES:
UN ANALYZABLES:
III.A.5.1
Thallium
ANALYZABLESI
U151, Mercury
P092, Phenylmercuric acetate
P065, Mercury fulminate
P113, Thalllc oxide
B-10
-------
P114, Thallium selenite
PUS, Thallium (I) sulfate
U214, Thallium (I) acetate
U215, Thallium (I) carbonate
U216, Thallium (I) chloride
U217, Thallium (I) nitrate
III. A. 5. J
Vanadium
METHOD
III.A.6.m
Gases
ANALYZABLES:
UNANALYZABLES:
P119, Ammonium vanadate
P120, Vanadium pentoxlde
U115, Ethylene oxide
P076, Nitric oxide
P078, Nitrogen dioxide
B-ll
-------
APPENDIX C
Method Detection Limits
C-l
-------
TABLE C-l
METHOD DETECTION LIMIT TABLE
KEY: NG - NOT GIVEN
ND - NOT DETERMINED
* - SYSTEM OR REAGENT BLANK DET. LIMIT
CONSTITUENTS
Acetone
Acetonitrile
Acrolein
Acrylonltrlle
Benzene
Bromodichloromethane
Bromomethane
n-Butyl alcohol
Carbon tetrachloride
Carbon disulfide
Chlorobenzene
2-Chloro-l, 3-butadiene
Chlorodibromooethane
Chloroethane
2-Chloroethyl vinyl ether
Chloroform
Chloromethane
3-Chloropropylene
1, 2-Dlbromo-3-ohloropropane
1, 2-Dibromoethane
Dlbromomethane
Trans-1, 4-Dichloro-2-butene
Dlchlorodifluoroawthane
1, l-Dlchloro»thane
1, 2-Dichloroethane
1, l-Dichloro«thyl«ne
Trana-lf 2-Dlchloro«thylene
1, 2-Dlchloropropane
Trans-1, 3-Dlchloropropylene
cls-1, 3-Dlchloropropylene
1,4-Dioxane
Ethyl acetate
Ethyl benzene
Ethyl cyanide
Ethyl ether
Ethyl methacrylate
Ethylene oxide
lodome thane
Isobutyl alcohol
Methanol
Methyl ethyl ketone
Methyl Isobutyl ketone
Methyl methacrylate
Methacrylonltrlle
Methylene chloride
Pyrldine
1, 1, 1, 2-Tetrachloroethane
1, 1, 2, 2-Tetrachloroethane
Tetrachloroethylene
Toluene
Tribroraomethane
1/1, 1-Trlchloroethane
1, 1, 2-Trichloroothane
Trlchloroethylene
Trichloromonofluoromethane
1, 2, 3-Trichloropropane
1, 1, 2-Trichloro-l, 2, 2-
trifluoroethane
Vinyl chlorite
Xylene(s)
Acenaphthalene
METHOD
DL (PPB)
NG
NG
NG
NG
NG
NG
NG
NG
NG
10
•6.5
0.5
0.5
1
0.5
0.5
0.5
0.5
1
1
0.5
1
•4.8
0.5
0.5
0.5
0.5
0.5
0.5
0.5
•10000
NG
NO
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
0.5
0.5
•2.4
0.5
0.5
0.5
0.5
0.5
1
0.5
1
ANALYTICAL
METHOD
6240
8240
8240
8240
8240
8240
8240
8240
8240
8240
8240
8240
8240 .
8240
8240
8240
8240
8240
8240
8240
8040
8240
8240
8240
8240
8240
8240
8240
8240
8240
8240
8240
8240
8240
8240
8240
8240
8240
8240
8240
8015
8015
8240
8240
8240
8240
8240
8240
8240
8240
8240
8240
8240
8240
8240
8240
8240
8240
8240
8270
C-2
-------
TABLE C-l
METHOD DETECTION LIMIT TABLE
KEY: NG - NOT GIVEN
ND - NOT DETERMINED
* - SYSTEM OR REAGENT BLANK DET. LIMIT
CONSTITUENTS
Acenaphthene
Acetophenone
2-Acetylamlnofluorene
4-Aminobipheny1
Aniline
Anthracene
Araralte
Benz(a)anthracene
Benzol chloride
Benzenethlol
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
p-B«nzoqulnone
Bis(2-chloroethoxy)methane
Bis(2-chloroethyl)ether
Bl« (2-ehloroisopropyl)ether
Bis(2-ethylhexyl)phthalate
4-Bromophenyl phenyl ether
Butyl benzyl phthalate
2-sec-Butyl-4,6-dinitrophenol
p-Chloroaniline
Chlorobentilate
p-Chloro-tn-cre«ol
2-Chloronaphthalene
2-Chlorophenol
Chrysene
ortho-Cresol
meta/para-Cresol
Cyclohexanone
Dibenzo(a,e)pyrene
Dibenz(a,h)anthracene
m-Dichlorobenzene
o-Dichlorobenzeno
p-Dichlorobenzene
3.3'-Dlchlorobontidine
2,4-Dichlorophenol
2,6-Dichlorophenol
Dlethyl phthalate
3,3'-Dlmethoxybencidine
p-Dlmethylaminoazobenzene
3,3'-Dimethylbenzldine
2,4-DimethyIphenol
Dimethyl phthlate
Dl-n-butyl phthalate
1,4-Dinltrobenzene
4,6-Dinitro-o-cresol
2,4-Dlnitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Dl-n-octyl phthalate
Di-n-propylnitrosoamine
Diphenylamine
Diphenylnitrosamine
1,2-Diphenylhydrazine
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
METHOD
DL (PPB)
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NC
NG
NG
NG
NG
NG
NG
NG
NG
NG
1
1
1
1
1
1
1
1
1
1
0.07
2
ANALYTICAL
METHOD
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
B270
8270
8270
8270
8270
8270
8270
8270
8150
8270
8270
8270
6270
8270
8270
8270 •
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
C-3
-------
TABLE C-l
METHOD DETECTION LIMIT TABLE
KEY: NG - NOT GIVEN
ND - NOT DETERMINED
« - SYSTEM OR REAGENT BLANK DET. LIMIT
CONSTITUENTS
Hexachloroethane
Hexachlorophene
Hexachloropropylene
Indeno (1,2, 3-cd) pyrene
Isosafrole
Methapyrilene
3-Methylchloanthrene
4,4'-Methylenebis (2-chloraniline)
Methyl methanesulfonate
Naphthalene
1, 4-Naphthoquinone
1-Naphthylamlne
2-Naphthylamine
p-Nltroanilin«
Nitrobenzene
4-Nitrophenol
N-Nitrosodi-n-butylamine
N-NitroBodimethylamine
N-Nitrosomethylathylamin«
N-Nitrosomorpholine
N-Nitrosopiperidlne
n-Nltrosopyrrolidine
5-Nitro-o-toluidin*
Pentachlorobenzene
Pentachloroethane
Pentachloronitrobentena
Pentachlorophenol
Phenacetin
Phenanthrene
Phenol
Phthallc anhydride
Pronamide
Pyrene
Resorcinol
Safrole
1, 2, 4, 5-Tetrachlorobenzene
2, 3, 4, 6-Tetrachlorophenol
1,2, 4-Trlchlorobenzene
2,4, 5-Tr ichlorophenol
2, 4, 6-Trichlorophenol
Tr is ( 2 , 3-dibromopropy 1 ) phosphate
Acrylamide
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium (total)
Copper
Lead
Mercury
Nickel
Selenium
Silver
Thallium
Vanadium
Zinc
Cyanide
Fluoride
Sulfide
Aldrin
METHOD
DL (PPB)
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
NG
1
1
1
5
1
5
5
1
1
1
*1.5
1
1
1
32
1
2
0.3
4
7
6
1
0.2
15
2
7
1
8
2
100
0.004
ANALYTICAL
METHOD
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
8270
6010
7060
6010
6010
6010
6010
6010
7421
7470/7471
6010
7740
6010
7841
6010
6010
335.3
340.2
9030
8080
8080
C-4
-------
TABLE C-l
METHOD DETECTION LIMIT TABLE
KEY: NG - NOT GIVEN
NO - NOT DETERMINED
* - SYSTEM OR REAGENT BLANK DET. LIMIT
CONSTITUENTS .
alpha-BHC
beta-BHC
delta-BHC
gamma -BHC
Chlordane
DDD
DDE
DDT
Dleldrln
Endosulfan I
Endosulfan II
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxida
leodrin
Kepone
Methoxyclor
Toxaphane
2,4-Dlchlorophenoxyacetlc acid
Silver
2,4,5,T
Disulfoton
Famphur
Methyl parathion
Parathlon
Phorate
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 124B
Aroclor 1254
Aroclor 1260
Hexachlorodibenzo-p-dioxlns
Hexachlorodibanzofurans
Pentachlorodibansc— p-dioxin*
Pentachlorodibenzofurans
Tetrachlorodibenzo-p-dioxini
Tetrachlorodibenzofuran*
2, 3, 7, 8-Tetrachlorodibenzo-p-dioxin
METHOD
DL (PPB)
0.003
0.006
0.009
0.004
0.014
0.011
0.004
0.012
0.002
0.014
0.004
0.006
0.023
0.003
0.083
NG
NG
0.176
0.24
1.2
0.17
0.2
0.2
NG
0.03
NG
0.15
ND
ND
ND
0.065
ND
ND
ND
2.21 PPT
2.53 PPT
1.27 PPT
1.64 PPT
0.44 PPT
0.63 PPT
0.44 PPT
ANALYTICAL
METHOD
60BO
8080
8080
8080
8080
8080
8080
8080
8080
8080
8080
8080
8080
8080
8080
8080
8080
8080
8080
8150
8150
8150
8140
8140
8140
8140
8140
8080
8080
8080
8080
8060
8080
8080
8280
8280
8280
8280
8280
8280
8280
Detction Limits from:
1. SH-846
2. Methods for Chemical Analysis of Hater and Hastes
3. Reagent and ays blanks from WAO Treatment Test
C-5
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