FINAL
BEST DEMONSTRATED AVAILABLE TECHNOLOGY (BOAT)
BACKGROUND DOCUMENT
FOR
U AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
VOLUME B:
U & P WASTEWATERS AND NONWASTEWATERS WITH
METHODS OF TREATMENT AS TREATMENT STANDARDS
Richard Kinch
Acting Chief, Waste Treatment Branch
Lisa Jones
Project Manager
U.S. ENVIRONMENTAL PROTECTION AGENCY
Office of Solid Waste
401 M Street, S.W.
Washington, D.C. 20460
May 8, 1990
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TABLE OF CONTENTS
1.0 INTRODUCTION 1-1
1.1 Regulatory Background 1-1
1.2 User's Guide to the Three-Volume U and P Waste and
Multi-Source Leachate (F039) Background Document Set . . 1-2
1.3 Summary of Contents: Volume B 1-3
2.0 INDUSTRY AFFECTED AND WASTE CHARACTERIZATION 2-1
2.1 Industry Affected 2-1
2.2 Waste Characterization 2-2
2.3 Determination of Waste Treatability Groups 2-2
2.3.1 Aromatic and Other Hydrocarbon Wastes .... 2-3
2.3.2 Brominated Organic Wastes 2-3
2.3.3 Halogenated Aliphatic Wastes 2-4
2.3.4 Halogenated Pesticide and Chlorobenzene
Wastes 2-4
2.3.5 Oxygenated Hydrocarbon and Heterocyclic
Wastes 2-4
2.3.6 Wastes of a Pharmaceutical Nature 2-5
2.3.7 Phenolic Wastes 2-6
2.3.8 Pol/nuclear Aromatic Wastes 2-6>
2.3.9 Organo-Nitrogen Compound Wastes 2-7
2.3.10 Organo-Sulfur Compound Wastes 2-8
2.3.11 Miscellaneous Halogenated Organic Wastes ... 2-8
3.0 COMPLICATIONS PRECLUDING THE CALCULATION OF CONCENTRATION-
BASED TREATMENT STANDARDS 3-1
3.1 Analytical Complications 3-1
3.1.1 Unavailability of a Verified Analytical
Method 3-2
3.1.2 Commercial Unavailability of Calibration
Standards 3-2
3.1.3 Instability in Water 3-3
3.1.4 Multiple Chemical Identity 3-3
3.2 Complications Associated with the Treatability
Database 3-4
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TABLE OF CONTENTS (Continued)
4.0 IDENTIFICATION OF APPLICABLE, DEMONSTRATED, AND BEST
TECHNOLOGY 4-1
4.1 Applicable Treatment Technologies 4-1
4.1.1 Nonwaste waters 4-2
4.1.2 Wastewaters 4-6
4.2 Demonstrated Treatment Technologies 4-9
4.2.1 Nonwastewaters 4-9
4.2.2 Wastewaters 4-12
4.3 Identification of Best Demonstrated Available Treat-
ment Technology (BOAT) 4-15
4.3.1 Nonwastewaters 4-16
4.3.2 Wastewaters 4-18
5.0 DETERMINATION OF BOAT TREATMENT STANDARDS AS METHODS OF
TREATMENT 5-1
6.0 ACKNOWLEDGEMENTS 6-1
7.0 REFERENCES 7-1
APPENDIX A - U and P Waste Generation Tables A-l
APPENDIX B - U and P Constituent Chemical Structures .... B-l
APPENDIX C - Problems Encountered In Treatment Standard
Calculations Precluding Promulgation of
Numerical Standards C-l
ii
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LIST OF TABLES
Page
1-1 TREATMENT STANDARDS FOR U & P WASTES AND MULTI-SOURCE
LEACHATE (F039) INCLUDED IN VOLUMES A, B, AND C;
BY WASTE CODES 1-5
1-2 TREATMENT STANDARDS FOR U & P
WASTES AND MULTI-SOURCE LEACHATE (F039) INCLUDED IN
VOLUMES A, B, AND C; ALPHABETICALLY 1-11
1-3 U & P WASTES WITH METHODS OF TREATMENT AS TREATMENT
STANDARDS 1-22
2-1 WASTE TREATABILITY GROUPS FOR NONANALYZABLE
U AND P WASTES 2-10
3-1 COMPLICATIONS PRECLUDING CALCULATION OF CONCENTRATION-BASED
TREATMENT STANDARDS 3-6
4-1 WASTES TESTED BY INCINERATION 4-21
5-1 BOAT TREATMENT STANDARDS FOR NONANALYZABLE U AND P
WASTE CODES 5-3
iii
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1.0
INTRODUCTION
1.1
Regulatory Background
Section 3004(m) of the Resource Conservation and Recovery Act
(RCRA), as amended by the Hazardous and Solid Waste Amendments (HSWA) on
November 8, 1984, requires the U.S. Environmental Protection Agency (EPA or
the Agency) to promulgate treatment standards for certain hazardous wastes
based on the Best Demonstrated Available Technology (BOAT) for those wastes.
More than 500 of these hazardous wastes were listed as of December 1988 (see
Title 40, Code of Federal Regulations. Part 261 (40 CFR Part 261)). The
Agency divided the listed hazardous wastes into five groups. The wastes in
each group were examined to determine whether further land disposal is protec-
tive of human health and the environment (see 40 CFR Part 268). The five
groups and their respective dates of promulgation of treatment standards are:
Solvent and dioxin wastes
"California List" wastes
"First Third" wastes
"Second Third" wastes
"Third Third" wastes
November 7, 1986
July 8, 1987
August 8, 1988
June 8, 1989
On or before May 8, 1990
Several wastes included in this schedule were regulated ahead of schedule, and
several wastes in the "First Third" or "Second Third" group of wastes were
deferred to the "Third Third" group of wastes. Treatment standards for the
Third Third wastes will become effective no later than May 8, 1990. On and
after this date, wastes regulated in the "Third Third" rulemaking will have to
comply with applicable treatment standards prior to "land disposal" as defined
in 40 CFR Part 268.
This background document provides the Agency's rationale and techni-
cal support for developing treatment standards for those U and P wastes with
methods of treatment as the BDAT treatment standards. These standards are
applicable to the wastes as listed in 40 CFR 261.33(e) and (f) as well as to
any wastes generated by the management or treatment of the listed waste.
Treatment standards are specified for both nonwastewater and wastewater forms
of each listed hazardous waste. For the purpose of determining the applic-
1-1
-------
ability of the_ treatment standards, wastewaters are defined as wastes contain-
ing less than 1% (weight basis) total suspended solids1 and less than 1%
(weight basis) total organic carbon (TOC). Wastes not meeting the wastewater
definition must comply with treatment standards for nonwastewaters.
The Agency's legal authority and promulgated methodology for estab-
lishing treatment standards and the petition process for requesting a variance
from the treatment standards are summarized in EPA's Methodology for Develop-
ing BOAT Treatment Standards (Reference 1).
U wastes include discarded commercial chemical products, manufactur-
ing chemical intermediates, off-specification commercial chemical products,
container and inner liner residues, and spill cleanup residues, including
contaminated water, soil, or debris, that are identified as toxic wastes. P
wastes include discarded commercial chemical products, manufacturing chemical
intermediates, off-specification commercial chemical products, container and
inner liner residues, and spill cleanup residues, including contaminated
water, soil, or debris, that are identified as acutely hazardous wastes.
Section 2.0 discusses the definition of U and P wastes in greater detail.
1.2 User's Guide to the Three-Volume U and P Waste and Multi-Source
Leachate (F039) Background Document Set
In the interest of clarity, the Agency has reorganized the "Third
Third" background documents that were prepared for proposal of the Third Third
Rule. Multi-source leachate (F039) and the majority of the organic U and P
waste codes addressed in the Third Third Proposed Rule are now covered in a
five-volume set of background documents.
1The term "total suspended solids" (TSS) clarifies EPA's previously used
terminology of "total solids" and "filterable solids." Specifically, total
suspended solids are measured by Method 209c (Total Suspended Solids Dried at
103 to 105°C) in Standard Methods for the Examination of Water and Wastewater
(Reference 2).
1-2
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The_five-volume background document set is organized as follows:
• Volume A - Wastewater forms of organic U and P wastes and
multi-source leachate (F039) for which there are concentration-
based treatment standards;
• Volume B (this document) - U and P wastewaters and nonwaste-
waters with methods of treatment as treatment standards;
• Volume C - Nonwastewater forms of organic U and P wastes and
multi-source leachate (F039) for which there are concentration-
based treatment standards.
• Volume D - Reactive U and P wastes and nonwastewaters with
methods of treatment as treatment standards; and
• Volume E - Gases.
Volumes A, B, and C each contain a set of cross-referenced treatment
standard tables which are intended as a guide to help the reader locate a
particular waste code or constituent and its treatment standard. These tables
list the volume in which the nonwastewater and wastewater forms of each waste
code and multi-source leachate (F039) constituent are discussed. Table 1-1 in
each volume is organized by waste code; Table 1-2 in each volume is organized
alphabetically by the common name of the regulated constituent. (All tables
are presented at the end of this section.)
1.3 Summary of Contents: Volume B
This background document provides the Agency's rationale and techni-
cal support for developing treatment standards for the organic U and P wastes
for which concentration-based treatment standards could not be developed. The
waste codes included in this background document are listed in Table 1-3.
Section 2.0 presents available waste characterization data, provides
a discussion of the industries and processes that generate the U and P wastes
included in this document, and provides the determination of the waste treata-
bility groups.
Section 3.0 includes a discussion of the issues preventing the
Agency from developing and promulgating concentration-based treatment stan-
1-3
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dards for the_U and P waste codes included in this document. Developing
concentration-based treatment standards is not feasible for the' majority of
these U and P wastes due to difficulties in quantifying the particular U or P
waste constituents of concern in hazardous waste matrices. Quantification
difficulties are due to the lack of effective SW-846 analytical methods, the
lack of commercially available analytical reagent standards, the instabilities
of the constituents in water, and multiple chemical identity. Some of the U
and P waste codes included in this document may be amenable to quantification
in hazardous waste matrices; however, as discussed in Section 3.0, treatment
standards were developed as methods of treatment due to problems encountered
in collecting representative treatment performance data.
Sections 4.0 and 5.0 present EPA's methodology and rationale for
identifying as BOAT methods of treatment for the U and P waste codes included
in this document. BDAT for nonwastewater forms of these wastes is incinera-
tion. BOAT for wastewater forms of these wastes is any one of the following
treatment trains:
• Wet air oxidation followed by carbon adsorption;
• Chemical oxidation followed by carbon adsorption; or
• Incineration.
Tables 1-1 and 1-2 list the BDAT treatment standards for all of the Third
Third organic U and P wastes, including those discussed in this document.
Section 6.0 acknowledges the persons involved in developing regula-
tions for these wastes. Section 7.0 presents references cited in this docu-
ment. Appendix A lists the facilities that may generate these U and P wastes
and the approximate number and geographic distribution of facilities that may
be affected by land disposal restrictions of these wastes. Appendix B pre-
sents the chemical structures for the U and P constituents covered in the
five-volume background document set. Appendix C presents the problems encoun-
tered in calculating concentration-based treatment standards for certain U and
P constituents. These problems precluded promulgation of numerical standards,
and as a result, methods of treatment were set as BDAT treatment standards for
these waste codes.
1-4
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Table 1-1
TREATMENT STANDARDS FOR U AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A. B, AND C; BY WASTE CODE
Wastewater Nonwasteuater
Waste
Code
F039
P001
P002
P003
P004
POOS
P007
POOS
POU
P016
P017
P018
P020
P022
P023
P024
P026
P027
P028
P034
P037
P042
P045
P046
P047
P047
P048
P049
P050
P050
P050
P051
P051
POS4
P057
P058
P059
P059
P060
P064
P066
P067
P069
P070
Regulated Constituents
Multi-Source Leachate Constituents - Refer
Warfarin (>0.3X)
1-Acetyl-2-thiourea
Acrolein
Aldrin
Allyl alcohol
5-Aminomethyl-3-isoxazolol
4-Aminopyridine
Thiophenol (Benzenethiol)
Bis(chloromethyl)ether
Bromoacetone
Brucine
2- sec-Butyl -4, 6-dinitrophenol (Dinoseb)
Carbon disulfide
Ch 1 oroaceta Idehyde
p-Chloroani line
1-(o-Chlorophenyl)thiourea
3-Chloropropionitri le
Benzyl chloride
2-Cyclohexyl-4,6-dinitrophenol
Dieldrin
Epinephrine
Thiofanox
alpha.alpha-Dimethylphenethylamine
4,6-Dinitro-o-cresol
4,6-Dinitro-o-cresol salts
2,4-Dinitrophenol
2,4-Dithiobiuret
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Aziridine
Fluoroacetamide
Fluoroacetic acid, sodium salt
Heptachlor '%£,
Heptachlor epoxide
Isodrin
Isocyanic acid, methyl ester
Methomyl
2-Methylaziridine
Methyl lactonitri le
Aldicarb
Document
to Table 1-2
B
B
A
A
B
B
B
B
B
B
8
A
A
B
A
B
B
B
B
A
B
B
B
A
B
A
B
A
A
A
A
A
B
B
B
A
A
A
B
B
B
B
B
Treatment
Standard (mg/l) *
for Treatment Standards
BOAT
BOAT
0.29
0.021
BOAT
BDAT
BOAT
BDAT
BDAT
BDAT
BDAT
0.066
0.014
BDAT
0.46
BOAT
BDAT
BDAT
BDAT
0.017
BDAT
BDAT
BDAT
0.28
BDAT
0.12
BDAT
0.023
0.029
0.029
0.0028
0.025
BDAT
BDAT
BDAT
0.0012
0.016
0.021
BDAT
BDAT
BDAT
BDAT
BDAT
Document
for each
B
B
B
C
B
B
B
B
B
B
B
C
B
B
C
B
B
B
B
C
B
B
B
C
B
C
B
C
C
C
C
C
B
B
B
C
C
C
B
B
B .
B
B
Treatment
Standard (mg/kg) **
Regulated Constituent
BDAT-FS
BDAT
BDAT-FS
0.066
BDAT-FS
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
2.5
BDAT
BDAT
16
BDAT
BDAT
BDAT
BDAT
0.13
BDAT
BDAT
BDAT
160
BDAT
160
BOAT
0.066
0.13
0.13
0.13
0.13
BDAT
BDAT
BDAT
0.066
0.066
0.066
BOAT
BDAT
BDAT
BDAT
BDAT
* BDAT for wastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
** BDAT for nonwastewaters is incineration but fuel substitution is also BDAT for the waste codes marked as BDAT-FS.
1-5
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Table 1-1 (Continued)
TREATMENT STANDARDS FOR (J AND P WASTES AND MULT1 -SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C; BY WASTE CODE
Wastewater Nonwastewater
Waste
Code
P072
P075
P077
P082
P084
P088
P093
P095
P101
P102
P108
P116
P118
P123
U001
U002
U003
U004
UOOS
U006
U007
UOOS
U009
U010
U011
U012
U014
U015
U016
U017
U018
U019
U020
U021
U022
U024
U025
U026
U027
U029
U030
U031
U033
U034
U035
Regulated Constituents
1-Naphthyl-2-thiourea
Nicotine and salts
p-Nitroaniline
N-Nitrosodimethylamine
N-Nitrosomethylvinylamine
Endothall
N-Phenylthiourea
Phosgene
Ethyl cyanide (Propanenitrile)
Propargyl alcohol
Strychnine and salts
Thiosemicarbazide
Trichloromethanethiol
Toxaphene
Acet aldehyde
Acetone
Acetonitrile
Acetophenone
2-Acetylaminof luorene
Acetyl chloride
Acrylamide
Acrylic acid
Acrylonitrile
Mitomycin C
Amitrole
Ani line
Auramine
Azaserine
Benz
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Table 1-1 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, 8, AND C; BY WASTE CODE
Wastewater Nonwastewater
Waste
Code
U036
U037
U038
U039
U041
U042
U043
U044
U045
U046
U047
U048
U049
U050
U051
U051
U051
U051
U051
UOS1
U051
U052
U052
U053
U055
U056
U057
U059
U060
U060
U061
U061
U061
U061
U061
U061
U062
U063
U064
U066
U067
U068
U070
U071
U072
Regulated Constituents
Chlordane (alpha and gamma)
Chlorobenzene
Chlorobenzilate
p-Chloro-m-cresol
1-Chloro-2,3-epoxypropane (Epichlorohydrin)
2-Chloroethyl vinyl ether
Vinyl chloride
Chloroform
Chloromethane (Methyl chloride)
Chloromethyl methyl ether
2-Chloronaphthalene
2-Chlorophenol
4-Chloro-o-toluidine hydrochloride
Chrysene
Creosote - Lead
Creosote - Naphthalene
Creosote - Pentachlorophenol
Creosote - Phenanthrene
Creosote • Pyrene
Creosote - Toluene
Creosote - Xylenes (total)
Cresol (m- and p- isomers)
o-Cresol
Crotonaldehyde
Cumene
Cyclohexane
Cyclohexanone
Oaunomycin
o,p'-DDD '
p.p'-DDD
o,p'-ODD
p,p'-ODD
o,p'-DDE
p.p'-ODE
o,p'-ODT
p.p'-DDT
Dial late
Dibenz(a,h)anthracene
1 , 2 , 7, 8-0 i benzopyrene
1 ,2-Dibromo-3-chloropropane
1,2-Dibromoethane (Ethylene Di bromide)
D i bromomethane
o-D i ch I orobenzene
m-D i ch I orobenzene
p-D i ch I orobenzene
Document
A
A
A
A
8
B
A
A
A
8
A
A
B
A
A
B
B
B
A
B
A
A
A
A
A
A
A
A
B
A
B
A
A
A
A
A
A
Treatment
Standard (mg/l) *
0.0033
0.057
0.10
0.018
BOAT
BOAT
0.27
0.046
0.19
BOAT
0.055
0.044
BDAT
0.059
0.28
0.059
0.089
0.059
0.067
0.080
0.32
0.77
0.11
BDAT
BDAT
BDAT
0.36
BDAT
0.023
0.023
0.023
0.023
0.031
0.031
0.0039
0.0039
BDAT
0.055
BDAT
0.11
0.028
0.11
0.088
0.036
0.090
Document
C
C
B
C
B
B
C
C
C
B
C
C
B
C
C
C
C
C
C
C
C
C
C
B
B
B
B
B
C
C
C
C
C
C
C
C
B
C
B
C
C
C
C
C
C
Treatment
Standard (mg/kg) **
0.13
5.7
BDAT
14
BDAT
BDAT
33
5.6
33
BDAT
5.6
5.7
BDAT
8.2
0.51 3 '
3.1
7.4
3.1
8.2
28
28'
3.2
5.6
BDAT-FS
8DAT-FS
BDAT-FS
BDAT-FS
BDAT
0.087
0.087
0.087
0.087
0.087
0.087
0.087
0.087
BDAT
8.2
BDAT-FS
15
15
15
6.2
6.2
6.2
* BDAT for wastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
** BDAT for nonwastewaters is incineration but fuel substitution is also BDAT for the waste codes marked as BDAT-FS.
a Units for the lead standard are mg/l; analyzed by TCLP extract.
1-7
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Table 1-1 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C; BY WASTE CODE
Uastewater Nonwastewater
Waste
Code
U073
U074
U074
U075
U076
U077
U078
U079
U080
U081
U082
U083
U084
U084
U085
U089
U090
U091
U092
U093
U094
U095
U097
U101
U105
U106
U108
U110
U111
U112
U113
U114
U115
U116
U117
U118
U119
U120
U121
U122
U123
U124
U125
U126
Regulated Constituents .
3,3'-Dichlorobenzidine
cis-1,4-Dichloro-2-butene
trans-1,4-Dichloro-2-butene
Dichlorodif tuoromethane
1,1-Dichloroethane
1 , 2-D i ch I oroethane
1 , 1-Dichloroethylene
trans-1,2-Dichloroethylene
Methylene chloride
2,4-Dichlorophenol
2 , 6-0 i ch I oropheno I
1 , 2-D i ch loropropane
cis-1,3-Dichloropropylene
trans-1,3-Dichloropropylene
1,2:3,4-Diepoxybutane
Diethylstilbestrol
Dihydrosafrole
3,3' -Dimethoxybenzidine
Dimethylamine
p-Dimethylaminoazobenzene
7,12-Dimethyl benz(a)anthracene
3,3'-Dimethylbenzidine
Oimethylcarbamoyl chloride
2,4-Dimethylphenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
1,4-Dioxane
Dipropylamine
Di-n-propylnitrosamine
Ethyl acetate
Ethyl acrylate
Ethylene bis-dithiocarbamic acid
Ethylene oxide
Ethylene thiourea
Ethyl ether
Ethyl methacrylate
Ethyl methanesulfonate
Fluoranthene
Tr i ch loromonof luoromethane
Formaldehyde
Formic acid
Furan
Furfural
Glycidylaldehyde
Document
B
B
B
A
A
A
A
A
A
A
A
A
A
A
B
B
B
B
B
B
B
B
B
A
A
A
A
B
A
A
B
B
A
B
A
A
B
A
A
B
B
B
B
B
Treatment
Standard (mg/l) *
BOAT
BOAT
BOAT
0.23
0.059
0.21
0.025
0.054
0.089
0.044
0.044
0.85
0.036
0.036
BOAT
BDAT
BOAT
BOAT
BDAT
BOAT
BDAT
BDAT
BDAT
0.036
0.32
0.55
0.12
BDAT
0.40
0.34
BDAT
BDAT
0.12
BDAT
0.12
0.14
BDAT
0.068
0.020
BDAT
BOAT
BDAT
BOAT
BDAT
Document
B
B
B
C
C
C
C
C
C
C
C
C
C
C
B
B
B
B
B
B
B
B
B
C
C
C
C
B
C
C
8
B
a
B
C
C
B
C
C
B
B
B
B
B
Treatment
Standard (mg/kg) **
BDAT
BDAT
BDAT
7.2
7.2
7.2
33
33
33
14
14
18
18
18
BDAT-FS
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT-FS
BDAT
BDAT
14
140
28
170
BDAT
14
33
BDAT-FS
BDAT
a
BOAT
160
160
BDAT
8.2
33
BDAT-FS
BDAT-FS
BDAT-FS
BDAT-FS
BDAT-FS
* BDAT for wastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
** BOAT for nonwastewaters is incineration but fuel substitution is also BDAT for the waste codes marked as BDAT-FS.
a Constituent is regulated in the wastewater form but not in the nonwastewater form.
1-8
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Table 1-1 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C; BY WASTE CODE
Wastewater Nonwastewater
Waste
Code
U127
U128
U129
U129
U129
U129
U130
U131
U132
U137
U138
UUO
U141
U142
U143
UU7
U148
UU9
U150
U152
U153
U154
U155
U156
U157
U158
U159
U161
U162
U163
U164
U165
U166
U167
U168
U169
U170
U171
U172
U173
U174
U176
U177
U178
U179
Regulated Constituents
Hexachlorobenzene
Hexach I orobutadi ene
alpha-BHC
beta-BHC
delta-BHC
gamma- BHC (Lindane)
Hexach 1 orocyc 1 open t ad i ene
Hexach I oroethane
Hexach I oroph ene
Indeno(1,2,3-c,d)pyrene
lodomethane
Isobutyl alcohol
Isosafrole
Kepone
Lasiocarpine
Maleic anhydride
Maleic hydrazide
Malononitrile
Melphalan
Methacrylonitrile
Methanethiol
Methanol
Methapyrilene
Methyl chlorocarbonate
3-Methylcholanthrene
4,4'-Methylenebis(2-chloroaniline)
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl methacrylate
N-Methyl-N-nitro-N-nitrosoguanidine
Methylthiouracil
Naphthalene
1,4-Naphthoquinone
1-Naphthylamine
2-Naphthylamine
Nitrobenzene
4-Nitrophenol
2-Nitropropane
N-Nitrosodi-n-butylamine
N-Nitrosodiethanolamine
N-Nitrosodiethylamine
N-Nitroso-N-ethylurea
N-Nitroso-N-methylurea
N-Nitroso-N-methylurethane
N-Nitrosopiperidine
Document
A
A
A
A
A
A
A
A
B
A
A
A
A
A
B
B
B
B
B
A
B
A
A
B
A
A
A
A
A
B
B
A
B
B
A
A
A
B
A
B
A
B
B
B
A
Treatment
Standard (rug/ 1) *
0.055
0.055
0.00014
0.00014
0.023
0.0017
0.057
0.055
BOAT
0.0055
0.19
5.6
0.081
0.0011
BOAT
BOAT
BOAT
BOAT
BOAT
0.24
BOAT
5.6
0.081
BOAT
0.0055
0.50
0.28
0.14
0.14
BOAT
BDAT
0.059
BDAT
BOAT
0.52
0.068
0.12
BDAT
0.40
BOAT
0.40
BDAT
BOAT
BDAT
0.013
Document
C
C
C
C
C
C
C
C
B
C
C
C
C
C
B
B
B
B
B
C
B
B
C
B
C
C
C
C
C
B
B
C
B
B
B
C
C
B
C
B
C
B
B
8
C
Treatment
Standard (mg/kg) **
37
28
0.066
0.066
0.066
0.066
3.6
28
BDAT
8.2
65
170
2.6
0.13
BDAT
BDAT-FS
BDAT
BDAT
BDAT
84
BDAT
BDAT-FS
1.5
BDAT
15
35
36
33
160
BDAT
BDAT
3.1
BDAT
BDAT
BDAT
14
29
BDAT
17
BDAT
28
BDAT
BDAT
BDAT
35
BDAT for uastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
BDAT for nonwastewaters is incineration but fuel substitution is also BDAT for the waste codes marked as BDAT-FS.
1-9
-------
Table 1-1 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C; BY WASTE CODE
• Wastewater Nonwasteuater
Waste
Code
U180
U181
U182
U183
U184
U185
U186
U187
U188
U191
U192
U193
U194
U196
U197
U200
U201
U202
U203
U206
U207
U208
U209
U210
U211
U213
U218
U219
U220
U222
U225
U226
U227
U228
U234
U236
U237
U238
U239
U240
U240
U243
U244
U247
U248
Regulated Constituents
N-Nitrosopyrrolidine
5-Nitro-o-toluidine
Paraldehyde
Pentach I orobenzene
Pentach loroethane
Pentach I oroni t robenzene
1,3-Pentadiene
Phenacetin
Phenol
2-Picoline
Pronamide
1,3-Propane sultone
n-Propylamine
Pyridine
p-Benzoquinone
Reserpine
Resorcinol
Saccharin and salts
Safrole
Streptozotocin
1 , 2 , 4 , 5 - Tet rach I orobenzene
1,1,1, 2- Tetrach loroethane
1 , 1 ,2,2-Tetrachloroethane
Tetrach loroethylene
Carbon tetrachloride
Tetrahydrofuran
Thioacet amide
Thiourea
Toluene
o-Toluidine hydrochloride
Tribromomethane (Bromoform)
1,1 ,1-Trich loroethane
1 , 1 ,2-Trich loroethane
Trich loroethylene
sym-Tri nitrobenzene
Trypan blue
Uracil mustard
Ethyl carbamate
Xylenes (total)
2,4-Dichlorophenoxyacetic acid
2,4-Dichlorophenoxyacetic salts and esters
Hexach loropropene
Thiram
Methoxychlor
Warfarin (<0.3X)
Document
A
A
B
A
B
A
B
A
A
B
A
B
B
A
B
B
B
B
A
B
A
A
A
A
A
B
B
B
A
B
A
A
A
A
B
B
B
B
A
A
B
A
B
A
B
Treatment
Standard (mg/l) *
0.013
0.32
BOAT
0.055
BOAT
0.055
' BOAT
0.081
0.039
BOAT
0.093
BOAT
BOAT
0.014
BOAT
BOAT
BOAT
BOAT
0.081
BOAT
0.055
0.057
0.057
0.056
0.057
BDAT
BOAT
BOAT
0.080
BDAT
0.63
0.054
0.054
0.054
BOAT
BOAT
BDAT
BOAT
0.32
0.72
BOAT
0.035
BOAT
0.25
BDAT
Document
C
C
B
C
B
C
B
C
C
B
C
B
B
C
B
B
B
B
C
B
C
C
C
C
C
8
B
B
C
B
C
C
C
C
B
B
B
B
C
C
B
C
B
C
B
Treatment
Standard (mg/kg) **
35
28
BDAT-FS
37
BDAT
4.8
BDAT-FS
16
6.2
BDAT
1.5
BDAT
BDAT
16
BDAT-FS
8DAT
BDAT-FS
BDAT
22
BDAT
19
42
42
5.6
5.6
BDAT-FS
BDAT
BDAT
28
BDAT
15
5.6
5.6
5.6
BDAT
BDAT
BDAT
BDAT
28
10
BDAT
28
BDAT
0.18
BDAT-FS
* BDAT for wastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
** BDAT for nonwastewaters is incineration but fuel substitution is also BDAT for the waste codes marked as BDAT-FS.
1-10
-------
Table 1-2
TREATMENT STANDARDS FOR U AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, 8, AND C; ALPHABETICALLY
Wastewater
Nonwastewater
Regulated U and P Waste Constituents
Acetaldehyde
Acetone
Acetonitrile
Acetophenone
2-Acetylaminof luorene
Acetyl chloride
1-Acetyl-2-thiourea
Acrolein
Aery I amide
Acrylic acid
Acrylonitrile
Aldicarb
Aldrin
Allyl alcohol
5-Aminomethyl-3-isoxazolol
4-Aminopyridine
Amitrole
Ani line
Auramine
Azaserine
Aziridine
Benzal chloride
BenzC a Janthracene
Benz(c)acridine
Benzene
Benzene sulfonyl chloride
Benzidine
Benzo(a)pyrene
p-8enzoquinone
Benzyl chloride
alpha-BHC
beta-BHC
delta-BHC
gamma -BHC
Bis(2-chloroethoxy)methane
Bis(2-chloroethyl)ether
Bis(2-chloroisopropyl)ether
Bis(chloromethyl)ether
Bromoacetone
Bromome thane (Methyl bromide)
.4-Bromophenyl phenyl ether
Brucine
n-Butyl alcohol
2-sec-Butyl-4,6-dinitrophenol (Dinoseb)
Carbon disulfide
Waste
Code
U001
U002
U003
U004
U005
U006
P002
P003
U007
U008
U009
P070
P004
POOS
P007
P008
U011
U012
U014
U015
P054
U017
U018
U016
U019
U020
U021
U022
U197
P028
U129
U129
U129
U129
U024
U025
U027
P016
P017
U029
U030
P018
U031
P020
P022
Document
B
A
A
A
A
B
B
A
B
B
A
B
A
B
B
B
B
A
B
B
B
B
A
B
A
B
B
A
B
8
A
A
A
A
A
A
A
B
B
A
A
B
A
A
B
Treatment
Standard (mg/l) *
BOAT
0.28
0.17
0.010
0.059
BOAT
BDAT
0.29
BDAT
BDAT
0.24
BDAT
0.021
BDAT
BDAT
BDAT
BDAT
0.81
BDAT
BDAT
BDAT
BOAT
0.059
BDAT
0.14
BDAT
BDAT
0.061
BDAT
BDAT
0.00014
0.00014
0.023
0.0017
0.036
0.033
0.055
BDAT
BDAT
0.11
0.055
BDAT
5.6
0.066
BDAT
Document
B
C
B
C
C
B
B
B
B
B
C
B
C
B
B
B
B
C
B
B
B
B
C
B
C
B
B
C
B
B
C
C
C
C
C
C
C
B
B
C
C
B
C
C
B
Treatment
Standard (mg/kg) **
BDAT
160
BDAT
9.7
140
BDAT
BDAT
BOAT-FS
BDAT
BDAT-FS
84
BDAT
0.066
BDAT-FS
BDAT
BDAT
BDAT
14
BDAT
BDAT
BDAT
BDAT
8.2
BDAT-FS
36
BDAT
BDAT
8.2
BOAT-FS
BDAT
0.066
0.066
0.066
0.066
7.2
7.2
7.2
BDAT
BDAT
15
15
BDAT
2.6
2.5
BDAT
* BDAT for wastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
** BDAT for nonwastewaters is incineration. Fuel substitution is also BDAT for the waste codes marked as BDAT-FS.
1-11
-------
Table 1-2 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C; ALPHABETICALLY
Uastewater
Nonwastewater
Regulated U and P Waste Constituents
Carbon tetrachloride
Carbonyl fluoride
Chlorambucil
Chlordane (alpha and gamma)
Ch 1 oroaceta Idehyde
p-Chloroaniline
Chlorobenzene
Chlorobenzi late
1-Chloro-2,3-epoxypropane (Epichlorohydrin)
2-Chloroethyl vinyl ether
Chloroform
p-Chloro-m-cresol
Chloromethane (Methyl chloride)
Chloromethyl methyl ether
Chlornaphazine
2-Chloronaphthalene
4-Chloro-o-toluidine hydrochloride
2-Chlorophenol
1 - (o-Chlopophenyl Khiourea
3-Chloropropionitri le
Chrysene
Creosote - Lead
Creosote - Naphthalene
Creosote - Pentachlorophenol
Creosote - Phenanthrene
Creosote - Pyrene
Creosote - Toluene
Creosote - Xylenes (total)
Cresol (m- and p- isomers)
o-Cresol
Crotona Idehyde
Cumene
Cyclohexane
Cyclohexanone
2-Cyclohexyl-4,6-dinitrophenol
Oaunomycin
o,p'-DDD
p,p'-DDD
o,p' -ODD
p,p'-DDD
o,p'-DDE
p,p'-DDE
o,p'-DDT
p,p'-DDT
Waste
Code
U211
U033
U035
U036
P023
P024
U037
U038
U041
U042
U044
U039
U045
U046
U026
U047
U049
U048
P026
P027
U050
UOS1
U051
UOS1
U051
U051
U051
U051
U052
U052
U053
U055
U056
U057
P034
U059
U060
U060
U061
U061
U061
U061
U061
U061
Document
A
B
B
A
B
A
A
A
B
B
A
A
A
B
B
A
8
A
B
8
A
A
A
A
A
A
A
A
A
A
B
B
B
A
B
B
A
A
A
A
A
A
A
A
Treatment
Standard (mg/l) *
0.057
BOAT
BOAT
0.0033
BDAT
0.46
0.057
0.10
BDAT
BDAT
0.046
0.018
0.19
BDAT
BDAT
0.055
BDAT
0.044
BDAT
BDAT
0.059
0.28
0.059
0.089
0.059
0.067
0.080
0.32
0.77
0.11
BDAT
BOAT
BDAT
0.36
BOAT
BDAT
0.023
0.023
0.023
0.023
0.031
0.031
0.0039
0.0039
Document
C
B
B
C
B
C
C
B
B
B
C
C
C
B
B
C
8
C
B
B
C
C
C
C
C
C
C
C
C
C
B
B
B
B
B
B
C
C
C
C
C
C
C
C
Treatment
Standard (mg/kg) **
5.6
BDAT
BOAT
0.13
BDAT
16
5.7
BDAT
BOAT
BDAT
5.6
14
33
BDAT
BDAT
5.6
BDAT
5.7
BDAT
BDAT
8.2
0.51 a
3.1
7.4
3.1
8.2
28
28
3.2
5.6
BOAT-fS
BDAT-FS
BDAT-FS
BDAT-FS
BDAT
BDAT
0.087
0.087
0.087
0.087
0.087
0.087
0.087
0.087
* BDAT for wastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
** BDAT for nonwastewaters is incineration. Fuel substitution is also BDAT for the waste codes marked as BDAT-FS.
a Units for the lead standard are mg/l, analyzed by TCLP extract.
1-12
-------
Table 1-2 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, 8, AND C; ALPHABETICALLY
Uastewater
Nonuastewater
Regulated U and P Waste Constituents
Dial late
Dibenz(a,h)anthracene
1,2,7,8-Dibenzopyrene
1 , 2 - 0 i bromo- 3 - ch I oropropane
1,2-Dibromoethane
-------
Table 1-2 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C; ALPHABETICALLY
Uasteuater
Nonuastewater
Regulated U and P Waste Constituents
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endothall
Endrin
Endrin aldehyde
Epinephrine
Ethyl acetate
Ethyl acrylate
Ethyl carbamate
Ethyl cyanide (Propanenitri le)
Ethyl ether
Ethyl methacrylate
Ethyl methanesulfonate
Ethylene bis-di thiocarbamic acid
Ethylene oxide
Ethylene thiourea
Fluoranthene
Fluoroacetamide
Fluoroacetic acid, sodium salt
Formaldehyde
Formic acid
Furan
Furfural
G lye idyl aldehyde
Heptachlor
Heptachlor epoxide
Hexachlorobenzene
Hexach I orobutadi ene
Hexach lorocyclopentadiene
Hexach I oroethane
Hexachlorophene
Hexach I oropropene
Indeno(1,2,3-c,d)pyrene
lodomethane
Isobutyl alcohol
Isocyanic acid, methyl ester
Isodrin
Isosafrole
Kepone
Lasiocarpine
Maleic anhydride
Maleic hydrazide
Malononitrile
Waste
Code
P050
P050
P050
P088
P051
P051
P042
U112
U113
U238
P101
U117
U118
U119
U114
U115
U116
U120
P057
P058
U122
U123
U124
U125
U126
P059
P059
U127
U128
U130
U131
U132
U243
U137
U138
UUO
P064
P060
U141
U142
U143
U147
U148
U149
Document
A
A
A
B
A
A
B
A
B
B
A
A
A
B
B
A
B
A
B
B
B
B
B
B
B
A
A
A
A
A
A
B
A
A
A
A
B
A
A
A
B
B
B
B
Treatment
Standard (mg/l) *
0.023
0.029
0.029
BOAT
0.0028
0.025
BOAT
0.34
BOAT
BOAT
0.24
0.12
0.14
BOAT
BOAT
0.12
BOAT
0.068
BOAT
BOAT
BOAT
BOAT
BOAT
BOAT
BOAT
0.0012
0.016
0.055
0.055
0.057
0.055
BDAT
0.035
0.0055
0.19
5.6
BDAT
0.021
0.081
0.0011
BDAT
BDAT
BDAT
BDAT
Document
C
C
C
B
C
C
B
C
B
B
C
C
C
B
B
a
B
C
B
B
B
B
B
B
B
C
C
C
C
C
C
B
C
C
C
C
B
C
C
C
B
B
B
B
Treatment
Standard (mg/kg) **
0.066
0.13
0.13
BDAT-FS
0.13
0.13
BDAT
33
BDAT-FS
BDAT
360
160
160
BDAT
BDAT
a
BDAT
8.2
BDAT
BDAT
BDAT-FS
BDAT-FS
BDAT-FS
BDAT-FS
BDAT-FS
0.066
0.066'
37
28
3.6
28
BDAT
28
8.2
65
170
BDAT
0.066
2.6
0.13
BDAT
BDAT-FS
BDAT
BDAT
* BDAT for wastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
** BDAT for nonwastewaters is incineration. Fuel substitution is also BDAT for the waste codes marked as BDAT-FS.
a Constituent is regulated in the wastewater form, but not in the nonwastewater form.
1-14
-------
Table 1-2 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND HULTI-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, 8, AND C; ALPHABETICALLY
Wastewater
Nonwastewater
Regulated U and P Waste Constituents
Melphalan
Methacrylonitrile
Methanethiol
Methanol
Methapyrilene
Methomyl
Methoxychlor
Methyl chlorocarbonate
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl methacrylate
2-Methylaziridine
3-Methyleholanthrene
4,4'-Methylenebis(2-chloroaniline)
Methylene chloride
Methyllactonitrile
N-Methyl-N-nitro-N-nitrosoguanidine
Methyl thiouraci I
Mitomycin C
Naphthalene
1 ,4-Naphthoquinone
1-Naphthylamine
2-Naphthylamine
1-Naphthyl-2-thiourea
Nicotine and salts
p-Nitroaniline
Nitrobenzene
5-Nitro-o-toluidine
4-Nitrophenol
2-Nitropropane
N-Nitrosodiethanolamine
N-Nitrosodiethylamine
N-Nitrosodimethylamine
N-Nitrosodi-n-butylamine
N-N itrosomethyl vinyl ami ne
N-Nitroso-N-ethylurea
N-Nitroso-N-methylurea
N-Nitroso-N-methylurethane
N-Nitrosopip«ridine
N-Nitrosopyrrolidine
Paraldehyde
Pentach I oroethane
Pentach I orobenzene
Pentach I oroni trobenzene
1,3-Pentadiene
Waste
Code
U150
U152
U1S3
U154
U155
P066
U247
U156
U159
U161
U162
P067
U157
U158
U080
P069
U163
U164
U010
U165
U166
U167
U168
P072
POTS
P077
U169
U181
U170
U171
U173
U174
P082
U172
P084
U176
U177
U178
U179
U180
U182
U184
U183
U185
U186
Document
B
A
B
A
A
B
A
B
A
A
A
B
A
A
A
B
B
B
B
A
B
B
A
B
B
A
A
A
A
B
B
A
A
A
B
B
B
B
A
A
B
B
A
A
8
Treatment
Standard (mg/l) *
BOAT
0.24
BOAT
5.6
0.081
BOAT
0.25
BOAT
0.28
0.14
0.14
BOAT
0.0055
0.50
0.089
BDAT
BOAT
BOAT
BOAT
0.059
BOAT
BDAT
0.52
BDAT
BDAT
0.028
0.068
0.32
0.12
BOAT
BDAT
0.40
0.40
0.40
BDAT
BDAT
BOAT
BDAT
0.013
0.013
BOAT
BDAT
0.055
0.055
BDAT
Document
B
C
B
B
C
B
C
B
C
C
C
B
C
C
C
B
B
B
B
C
B
B
B
B
B
C
C
C
C
B
B
C
B
C
B
B
B
B
C
C
B
B
C
C
B
Treatment
Standard (mg/kg) **
BDAT
84
BDAT
BDAT-FS
1.5
BDAT
0.18
BDAT
36
33
160
BDAT
15
35
33
BDAT
BDAT
BDAT
BDAT
3.1
BDAT-FS
BDAT
BDAT
BDAT
BDAT
28
14
28
29
BDAT
BDAT
28
BOAT
17
BDAT
BDAT
BDAT
BDAT
35
35
BDAT-FS
BDAT
37
4.8
BDAT-FS
* BDAT for wastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
** BDAT for nonwastewaters is incineration. Fuel substitution is also BDAT for the waste codes marked as BDAT-FS.
1-15
-------
Table 1-2 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND MULT!-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C; ALPHABETICALLY
Uastewater
Nonwastewater
Regulated U and P Waste Constituents
Phenacetin
Phenol
N-Phenylthiourea
Phosgene
2-Picoline
Pronamide
1,3-Propane sultone
Propargyl alcohol
n-Propylamine
Pyridine
Reserpine
Resorcinol
Saccharin and salts
Safrole
Streptozotocin
Strychnine and salts
1 ,2,4,5-Tetrachlorobenzene
1,1,1 ,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
Tetrahydrofuran
Thioacetamide
Thiofanox
Thiophenol (Benzenethiol)
Thiosemicarbazide
Thiourea
Thiram
Toluene
o-Toluidine hydrochloride
Toxaphene
Tribromome thane (Bromoform)
Trichloroacetaldehyde (Chloral)
1,1, 1 -Trichloroethane
1 , 1 ,2-Trichloroethane
Trichloroethylene
Trichloromethanethiol
T r i ch 1 oromonof I uoromethane
sym- T r i n i t robenzene
Trypan blue
Uracil mustard
Vinyl chloride
Warfarin (>0.3X)
Warfarin (<0.3X)
Xylenes (total)
Waste
Code
U187
U188
P093
P095
U191
U192
U193
P102
U194
U196
U200
U201
U202
U203
U206
P108
U207
U208
U209
U210
U213
U218
P045
POH
P116
U219
U244
U220
U222
P123
U225
U034
U226
U227
U228
P118
U121
U234
U236
U237
U043
P001
U248
U239
Document
A
A
B
B
B
A
B
B
B
A
B
B
B
A
B
B
A
A
A
A
B
B
B
B
B
B
B
A
B
A
A
B
A
A
A
B
A
B
B
B
A
B
B
A
Treatment
Standard (mg/l) *
0.081
0.039
BOAT
BOAT
BOAT
0.093
BDAT
BOAT
BDAT
0.014
BDAT
BOAT
BDAT
0.081
BDAT
BDAT
0.055
0.057
0.057
0.056
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
0.080
BDAT
0.0095
0.63
BDAT
0.054
0.054
0.054
BDAT
0.020
BDAT
BDAT
BDAT
0.27
BDAT
BDAT
0.32
Document
C
C
B
B
B
C
8
B
B
C
B
B
B
C
B
B
C
C
C
C
B
B
B
B
B
B
B
C
B
C
C
B
C
C
C
B
C
B
B
B
C
B
B
C
Treatment
Standard (mg/kg) **
16-
6.2
BDAT
BDAT
BDAT
1.5
BDAT
BDAT-FS
BDAT
16
BDAT
BDAT-FS
BDAT
22
BOAT
BDAT
19
42
42
5.6
BDAT-FS
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
28
BDAT
1.3
15
BDAT
5.6
5.6
5.6
BDAT
33
BDAT
BDAT
BDAT
33
BDAT-FS
BDAT-FS
28
* BDAT for uastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
** BDAT for nonwastewaters is incineration. Fuel substitution is also BDAT for the waste codes marked as BDAT-FS.
1-16
-------
Table 1-2 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND MULT I-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C; ALPHABETICALLY
Wasteuater
Nonwastewater
Regulated Leachate Constituents
Acenaphthalene
Acenaphthene
Acetone
Acetonitrile
Acetophenone
2-Acetylaminof luorene
Acrolein
Acrylonitri le
Aldrin
4-Aminobiphenyl
Ani line
Anthracene
Aramite
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
Benz(a)anthracene
Benzene
Benzo(b)f luoranthene
Benzo(k)f luoranthene
Benzo(g,h,i)perylene
Benzo(a)pyrene
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
B i s( 2- ch loroethoxy )methane
Bis(2-chloroethyl)ether
Bis(2-chloroisopropyl)ether
Bis(2-ethylhexyl)phthalate
Bromodiehloromethane
Bromomethane (Methyl bromide)
4-Bromophenyl phenyl ether
n-Butyl alcohol
Butyl benzyl phthalate
2-sec-Butyl-4,6-dini trophenol (Dinoseb)
Carbon disulfide
Carbon tetrachloride
Chlordane (alpha and gamma)
p-Chloroani line
Chlorobenzene
Uaste
Code
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
Document
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
Treatment
Standard (mg/l)
0.059
0.059
0.28
0.17
0.010
0.059
0.29
0.24
0.021
0.13
0.810
0.059
0.36
0.013
0.014
0.013
0.017
0.013
0.014
0.014
0.059
0.140
0.055
0.059
0.0055
0.061
0.00014
0.00014
0.023
0.0017
0.036
0.033
0.055
0.28
0.35
0.11
0.055
5.6
0.017
0.066
0.014
0.057
0.0033
0.46
0.057
Document
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
Treatment
Standard (mg/kg)
3.4
4.0
160
NR
9.7
140
NR
84
0.066
NR
14
4.0
NR
0.92
0.92
0.92
0.92
0.92
1.8
1.8
8.2
36
3.4
3.4
1.5
8.2
0.066
0.066
0.066
0.066
7.2
7.2
7.2
28
15
15
15
2.6
7.9
2.5
NR
5.6
0.13
16
5.7
NR = Not regulated. See Section 5.0 of the appropriate volume for discussion.
1-17
-------
Table 1-2 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND MULT I-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, 8, AND C; ALPHABETICALLY
Wastewater
Nonuastewater
Regulated Leachate Constituents
Chtorobenzi late
2-Chloro-1,3-butadiene
Chlorodibromomethane
Chloroethane
Chloroform
p-Chloro-m-cresol
Chloromethane (Methyl chloride)
2 - Ch I oronaph tha I ene
2-Chlorophenol
3-Chloropropene
Chrysene
Cresol (m- and p- isomers)
o-Cresol
Cyclohexanone
o,p'-DDD
p,p'-DDD
o,p'-DOE
p.p'-DOE
o,p'-OOT
p.p'-DDT
Dibenz(a,h)anthracene
Dibenzo(a,e)pypene
1 , 2 -0 i bronw-3-ch loropropane
1,2-Dibromoethane (Ethylene di bromide)
0 i bromomethane
m-0 i ch I orobenzene
o-Dichlorobenzene
p-Dichlorobenzene
D i ch I orod i f I uoromethane
1 , 1 -Oichloroethane
1, 2 -Di chloroethane
1 , 1 - D i ch 1 oroethy I ene
trans- 1 ,2-Oichloroethylene
2,4-Dichlorophenol
2,6-Dichlorophenol
2,4-Dichlorophenoxyacetic acid
1, 2-0 ich loropropane
cis-1 ,3-Dichloropropene
trans-1 ,3-Dichloropropene
Dieldrin
Diethyl phthalate
2,4-Oimethylphenol
Dimethyl phthalate
Di-n-butyl phthalate
1 ,4-Di nitrobenzene
Waste
Code
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
Document
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
Treatment
Standard
-------
Table 1-2 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND MULT1-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, 8. AND C; ALPHABETICALLY
Uasteuater
Nonuastewater
Regulated Leachate Constituents
4,6-Dinitro-o-cresol
2,4-Dinitrophenol
2,4-Dini trotoluene
2,6-Dinitrotoluene
Oi-n-octyl phthalate
Di-n-propylnitrosamine
1,4-Dioxane
Diphenylamine
1,2-Diphenylhydrazine
Diphenytni trosamine
Oisulfoton
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Ethyl acetate
Ethyl benztrw
Ethyl cyanide (Prepan«nitrile)
Ethyl ether
Ethyl methacrylate
Ethylene oxide
Famphur
Fluoranthene
Fluorene
Heptachlor
Heptachlor epoxide
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexach I orod i benzof urans
Hexach 1 orodi benzo-p-di ox i ns
Hexach I oroethane
Hexach I oropropene
Indeno(1,2,3-c,d)pyrene
lodomethane
Isobutyl alcohol
Isodrin
Isosafrole
Kepone
Methacrylonitrile
Methanol
Hethapyrilene
Methoxychlor
Methyl ethyl ketone
Waste
Code
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
Document
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
Treatment
Standard (ing/ 1)
0.28
0.12
0.32
0.55
0.017
0.40
0.12
O.S2
0.087
0.40
0.017
0.023
0.029
0.029
0.0028
0.025
0.34
0.057
0.24
0.12
0.14
0.12
0.017
0.068
0.059
0.0012
0.016
0.055
0.055
0.057
0.000063
0.000063
0.055
0.035
0.0055
0.19
5.6
0.021
0.081
0.0011
0.24
5.6
0.081
0.25
0.28
Document
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
Treatment
Standard (mg/kg)
160
160
140
28
28
14
170
NR
NR
NR
6.2
0.066
0.13
0.13
0.13
0.13
33
6.0
360
160
160
NR
15
8.2
4.0
0.066
0.066
37
28
3.6
0.001
0.001
28
28
8.2
65
170
0.066
2.6
0.13
84
NR
1.5
0.18
36
NR = Not regulated. See Section 5.0 of the appropriate volume for discussion.
1-19
-------
Table 1-2 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND HULTI-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C; ALPHABETICALLY
Wastewater
Nonwastewater
Regulated Leachate Constituents
Methyl isobutyl ketone
Methyl methacrylate
Methyl methanesulfonate
Methyl parathion
3-Methylcholanthrene
4,4'-Methylenebis(2-chloroaniline)
Methylene chloride
Naphthalene
2-Naphthylamine
p-Nitroani line
Nitrobenzene
5-Nitro-o-toluidine
4-Nitrophenol
N-Nitrosodiethylamine
N-Nitrosodimethylamine
N-Nitrosodi-n-butylamine •
N - N i t rosomethy I ethy I ami ne
N-Nitrosomorpholine
N-Nitrosopiperidine
N-Nitrosopyrrolidine
Parathion
Pentach I orobenzene
Pent ach I orodi benzof urans
Pentach I orodi benzo-p-di oxi ns
Pent ach I oron i t robenzene
Pentach I oropheno I
Phenacetin
Phenanthrene
Phenol
Phorate
Phthalic anhydride
Pronamide
Pyrene
Pyridine
Safrole
Silvex (2,4,5-TP)
1,2,4,5-Tetrachlorobenzene
Tetrachlorodi benzof urans
Tetrachlopodibenzo-p-dioxins
1,1,1 ,2-Tetrachloroethane
1 , 1 ,2,2-Tetrachloroethane
Tetrachloroethylene
2,3,4,6-Tetrachlorophenol
Toluene
Toxaphene
Waste
Code
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
Document
-A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
Treatment
Standard (ing/ 1)
0.14
0.14
0.018
0.014
0.0055
0.50
0.089
0.059
0.52
0.028
0.068
0.32
0.12
0.40
0.40
0.40
0.40
0.40
0.013
0.013
0.014
0.055
0.000063
0.000063
0.055
0.089
0.081
0.059
0.039
0.021
0.069
0.093
0.067
0.014
0.081
0.72
0.055
0.000063
0.000063
0.057
0.057
0.056
0.030
0.080
0.0095
Document
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
Treatment
Standard (mg/kg)
33
160
NR
4.6
15
35
33
3.1
NR
28
14
28
29
28
NR
17
2.3
2.3
35
35
4.6
37
0.001
0.001
4.8
7.4
16
3.1
6.2
4.6
NR
1.5
8.2
16
22
7.9
19
0.001
0.001
42
42
5.6
37
28
1.3
NR = Not regulated. See Section 5.0 of the appropriate volume for discussion.
1-20
-------
Table 1-2 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C; ALPHABETICALLY
Uasteuater
Nonwastewater
Regulated Leachate Constituents
Tribromome thane (Bromoform)
1,2,4-Trichlorobenzene
1 ,1,1-Trichloroethane
1 , 1 ,2-Trichloroethane
Trichloroethylene
Trichloromonof luoromethane
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
2,4,5-Trichlorophenoxyacetic acid
1,2,3-Trichloropropane
1, 1,2-Trichloro- 1,2,2- trif luoroethane
Tris(2,3-dibromopropyl)phosphate
Vinyl chloride
Xylenes
Cyanides (total)
Fluoride
Sulfide
Antimony
Arsenic
Barium
Beryl lium
Cadmium
Chromium (total)
Copper
Lead
Mercury
Nickel
Selenium
Si Iver
Thallium
Vanadium
Zinc
Waste
Code
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
Document
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
Treatment
Standard (mg/l)
0.63
0.055
0.054
0.054
0.054
0.020
0.18
0.035
0.72
0.85
0.057
0.11
0.27
0.32
1.2
35
14
1.9
1.4
1.2
0.82
0.20
0.37
1.3
0.28
0.15
0.55
0.82
0.29
1.4
0.042
1.0
Document
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
Treatment
Standard (mg/kg)
15
19
5.6
5.6
5.6
33
3,7
37
7.9
28
28
NR
33
28
1.8
NR
NR
TCLP (mg/l)
0.23
5.0 a
52
NR
0.066
5.2
NR
0.51
0.025
0.32
5.7
0.072
NR
NR
NR
NR = Not regulated. See Section 5.0 of the appropriate volume for discussion.
3 Based on EP Toxicity.
1-21
-------
Table 1-3
U & P UASTES WITH METHODS OF TREATMENT AS TREATMENT STANDARDS
Uastewater Nonwastewater
Regulated Constituent
Warfarin (>0.3X)
1-Acetyl-2-thiourea
Acrolein
Allyl alcohol
5-Aminomethyl-3-isoxazolol
4-Aminopyridine
Thiophenol (Benzenethiol )
Bis(chloromethyl)ether
Bromoacetone
Srucine
Carbon disulfide
Ch 1 oroaceta Idehyde
1 - ( o- Ch 1 oropheny I ) th i ourea
3-Chloropropionitri le
Benzyl chloride
2-Cyclohexyl-4,6-dinitrophenol
Epinephrine
Thiofanox
alpha.alpha-Dimethylphenethylamine
4,6-Dinitro-o-cresol salts
2,4-Dithiobiuret
Aziridine
Fluoroacetamide
Fluoroacetic acid, sodium salt
Isocyam'c acid, methyl ester
Methomyl
2-Methylaziridine
Methyllactonitri le
Aldicarb
1-Naphthyl-2-thiourea
Nicotine and salts
N-Nitrosodimethytamine
N-Ni trosomethylvinylamine
Endothall
N-Phenylthiourea
Phosgene
Propargyl alcohol
Strychnine and salts
Thiosemicarbazide
T r i ch 1 oromethaneth i ol
Acetaldehyde
Acetonitrile
Acetyl chloride
Acrytamide
Acrylic acid
Mitomycin C
waste
Code
P001
P002
P003
POOS
P007
POOS
P014
P016
P017
P018
P022
P023
P026
P027
P028
P034
P042
P045
P046
P047
P049
P054
P057
P058
P064
P066
P067
P069
P070
P072
POTS
P082
P084
P088
P093
P095
P102
P108
P116
P118
U001
U003
U006
U007
U008
U010
Document
B
8
A
B
B
B
B
B
B
B
A
B
B
B
B
8
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
A
B
B
B
B
B
B
B
B
B
A
B
A
B
B
Standard (mg/l) *
BOAT
BOAT
0.29
BDAT
BOAT
BDAT
BDAT
BDAT
BDAT
BDAT
O.OU
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
0.40
BDAT
BDAT
BDAT
BDAT
BDAT
BOAT
BDAT
BDAT
BDAT
0.17
BDAT
1.0
BDAT
BDAT
Document
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
Standard (mg/kg) **
BDAT-FS
BDAT
BDAT-FS
BDAT-FS
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT •
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT-FS
BDAT
BDAT
BDAT-FS
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT-FS
BDAT
* BDAT for wastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
** BDAT for nonwastewaters is incineration. Fuel substitution is also BDAT for the wastes codes marked as BDAT-FS.
1-22
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Table 1-3 (Continued)
U & P WASTES WITH METHODS OF TREATMENT AS TREATMENT STANDARDS
Uastewater
Nonwastewater
Regulated Constituent
Amitrole
Auramine
Azaserine
Benz(c)acridine
Benzal chloride
Benzene sulfonyl chloride
Benzidine
Chlornaphazine
Carbonyl fluoride
Trichloroacetaldehyde (Chloral)
Chlorambuci I
Chlorobenzi late
1-Chloro-2,3-epoxypropane (Epichlorohydrin)
2-Chloroethyl vinyl ether
Chloromethyl methyl ether
4-Chloro-o-toluidine hydrochloride
Crotonaldehyde
Cumene
Cyclohexane
Cyclohexanone
Daunomycin
Diallate
1 ,2,7,8-Dibenzopyrene
3,3' -D i chlorobenzi dine
cis-1 ,4-Dichloro-2-butene
trans-1 ,4-Dichloro-2-butene
1 , 2:3,4-Diepoxybutane
Diethylsti Ibestrol
Dihydrosafrole
3,3' -Dimethoxybenzidine
Dimethylamine
p-Oimethylaminoazobenzene
7,12-Dimethyl benz(a)anthracene
3,3'-Dimethylbenzidine
Dimethylcarbamoyl chloride
Dipropytamine
Ethyl acrylate
Ethylene bis-dithiocarbamic acid
Ethylene thiourea
Ethyl methanesulfonate
Formaldehyde
Formic acid
Furan
Furfural
G tyc idyl aldehyde
waste
Code
U011
UOU
U015
U016
UOU
U020
U021
U026
U033
U034
U035
U038
U041
U042
U046
U049
U053
U055
UOS6
U057
U059
U062
U064
U073
U074
U074
U085
U089
U090
U091
U092
U093
U094
U095
U097
U110
U113
U114
U116
U119
U122
U123
U124
U125
U126
Document
B
B
B
B
A
B
B
B
B
B
B
A
B
A
B
B
B
B
B
A
B
B
B
A
A
A
B
B
B
A
B
A
B
B
B
B
B
B
B
B
B
B
B
8
B
Standard (mg/l) *
BOAT
BOAT
BOAT
BDAT
0.055
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
0.10
BDAT
0.057
BDAT
BDAT
BDAT
BDAT
BDAT
0.36
BDAT
BDAT
BDAT
0.13
0.036
0.036
BDAT
BDAT
BDAT
0.13
BDAT
0.13
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
Document
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B.
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
Standard (mg/kg) **
BOAT
BDAT
BDAT
BDAT-FS
BDAT
BDAT
BDAT
BOAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT-FS
BDAT-FS
BOAT-FS
BDAT-FS
BDAT
BDAT
BDAT-FS
BDAT
BDAT
BDAT
BDAT-FS
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT-FS
BDAT
BDAT
BDAT
BDAT-FS
BDAT
BDAT
BDAT
BDAT-FS
BDAT-FS
BDAT-FS
BDAT-FS
BDAT-FS
BDAT for wastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
BDAT for nonwastewaters is incineration. Fuel substitution is also BDAT for the waste codes marked as BDAT-FS.
1-23
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Table 1-3 (Continued)
U & P WASTES WITH METHODS OF TREATMENT AS TREATMENT STANDARDS
Uasteuater
Nonwastewater
Regulated Constituent
Waste
Code Document
Standard (mg/l) *
Document Standard (mg/kg)
Hexachlorophene U132 B
Lasiocarpine U143 B
Ma leic anhydride U147 B
Maleic hydrazide UU8 B
Malononitrile UU9 B
Melphalan U150 B
Methanethiol U153 B
Methanol U154 A
Methyl chlorocarbonate U156 B
N-Methyl-N-nitro-N-nitrosoguanidine U163 B
Methylthiouracil U164 B
1,4-Naphthoquinone U166 B
1-Naphthylamine U167 B
2-Naphthylamine U168 A
2-Nitropropane U171 B
N-Nitrosodiethanolamine U173 B
N-Nitroso-N-ethylurea U176 B
N-Nitroso-N-methylurea U177 B
N-Nitroso-N-methylurethane U178 B
Paraldehyde U182 B
Pentachloroethane U184 B
1,3-Pentadiene U186 B
2-Picoline U191 8
1,3-Propane sultone U193 B
n-Propylamine U194 B
p-Benzoquinone U197 B
Reserpine ' U200 B
Resorcinol U201 B
Saccharin and salts U202 B
Streptozotocin U206 B
Tetrahydrofuran U213 B
Thioacetamide U218 B
Thiourea U219 B
o-Toluidine hydrochloride U222 B
sym-Trinitrobenzene U234 B
Trypan blue U236 B
Uracil mustard U237 B
Ethyl carbamate U238 B
2,4-Dichlorophenoxyacetic salts and esters U240 B
Thiram U244 8
Warfarin (<0.3%) U248 B
BOAT
BOAT
BOAT
BOAT
BOAT
BOAT
BOAT
5.6
BOAT
BOAT
BOAT
BOAT
BOAT
0.52
BDAT
BOAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT-FS
BDAT
BDAT
BDAT
BDAT
BDAT-FS
BDAT
BDAT
BDAT
BDAT
8DAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT-FS
BDAT
BDAT-FS
BDAT
BDAT
BDAT
BDAT-FS
BOAT
BDAT-FS
BDAT
BDAT
BDAT-FS
BDAT
BOAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BOAT
BDAT-FS
* BDAT for wastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
** BDAT for nonwastewaters is incineration. Fuel substitution is also BDAT for the waste codes marked as BDAT-FS.
1-24
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2.0 INDUSTRY AFFECTED AND WASTE CHARACTERIZATION
This section provides a description of the industries affected by
the land disposal restrictions for the wastes listed in Table 1-3, the pro-
cesses generating the wastes, the available waste characterization data, and
the determination of the waste treatability groups.
2.1 Industry Affected
A U or P waste consists of a commercial chemical product or manufac-
turing intermediate from a non-specific source containing any of the chemicals
listed in 40 CFR 261.33(e) or (f) and in which the listed chemical is the sole
active ingredient. Commercial chemical products or manufacturing intermedi-
ates include all commercially pure grades of the listed chemical, all techni-
cal grades, and all formulated products in which the listed chemical is the
sole active ingredient. In addition, an off-specification product that, if it
met specification, would have the generic name included in either 261.33(e) or
(f). is a U or P waste. Any residue that is a listed chemical remaining in a
container or in an inner liner removed from a container that will not be
recycled, reclaimed, or reused; or any residue or contaminated soil, water, or
debris from a spill of such a chemical is also a U or P waste. However, these
wastes do not include manufacturing process wastes. A waste occurs when a
product is:
• Discarded or intended to be discarded;
• Mixed with another material and applied to the land for dust
suppression or road treatment;
• Applied to land in lieu of its original intended use; or
• Distributed or burned as a fuel or fuel additive.
U wastes are identified as toxic; P wastes are identified as acutely
hazardous. Whether a waste is acutely hazardous or toxic generally has no
bearing on its treatability.
2-1
-------
Industries that generate the wastes listed in Table 1-3 include the
organic chemical, pharmaceutical, dye and pigment, textile and fiber, pesti-
cide, and rubber industries. The Agency estimates that approximately 600
facilities generate these wastes. The four-digit Standard Industrial Classi-
fication (SIC) Codes associated with the organic chemicals industry is 2869
(Industrial Organic Chemicals, Not Elsewhere Classified). Table A-l in
Appendix A identifies the industrial uses of these commercial chemical
products. Table A-2 provides a summary of the number of facilities that may
generate each waste. The facilities that may generate the U and P waste codes
are listed by state and by EPA region in Table A-3.
2.2 Waste Characterization
Waste characterization data are not currently available for any of
the waste codes included in this document. Due to the diversity of methods of
waste generation, the compositions of these wastes vary greatly. The con-
stituents of concern may be present at concentrations varying from several
parts per million in a waste to nearly 100% in a waste generated from
virtually pure product.
2.3 Determination of Waste Treatabilitv Groups
In the course of developing treatment standards, EPA combined the
wastes included in this document, as well as all other Third Third U and P
wastes, into treatability groups based on similarities in composition, struc-
ture, and functional groups present within the structure of the chemical. The
industries that generate these wastes were also considered in establishing
these groups.
The U and P wastes have been combined into the following treatabil-
ity groups:
• Aromatic Wastes;
• Brominated Organic Wastes;
• Halogenated Aliphatic Wastes;
• Halogenated Pesticide and Chlorobenzene Wastes;
2-2
-------
• _ Oxygenated Hydrocarbon and Heterocyclic Wastes;
• Wastes of a Pharmaceutical Nature;
• Phenolic Wastes;
• Polynuclear Aromatic Wastes;
• Organo-Nitrogen Compound Wastes;
• Organo-Sulfur Compound Wastes; and
• Miscellaneous Halogenated Organic Wastes.
The specific waste codes included within each treatability group in this
document are listed in Table 2-1 (at the end of this section), and the treata-
bility groups are discussed in more detail in the following subsections. The
U and P waste treatability groups contain both analyzable and nonanalyzable
constituents; only the constituents which have methods of treatment as BOAT
treatment standards are discussed below. The chemical structures for all of
the U and P waste constituents are presented in Appendix B.
2.3.1 Aromatic and Other Hydrocarbon Wastes
Waste codes in the aromatic and other hydrocarbon wastes treata-
bility group have an aromatic ring as a common functional group. Cyclohexane,
which can be reformed into aromatic hydrocarbons, and 1,3-pentadiene, which
has aromatic characteristics due to its conjugated double bonds, are also
included in this group. Some of the compounds in this group have aliphatic
side chains as substituents of the ring. The following waste codes are
included in this group:
• • U055 - Cumene
• U056 - Cyclohexane
U186 - 1,3-Pentadiene
2.3.2 Brominated Organic Wastes
The brominated organic wastes treatability group consists of P017,
bromoacetone, which is a brominated and oxygenated hydrocarbon. The Agency
believes that the presence of bromine in the chemical structure requires
modified design and operation of an incineration system. Accordingly, P017
has been placed in a separate brominated organics treatability group.
2-3
-------
2.3.3 Halogenated Aliphatic Wastes
Waste codes included in the halogenated aliphatic wastes treata-
bility group have common functional groups of single and double carbon-carbon
bonds, with chlorine atoms substituting for hydrogen atoms in at least one
bond of the compound. The following waste codes are included in this group:
• U074 - cis-l,4-Dichloro-2-butene
• U074 - trans-l,4-Dichloro-2-butene
• U184 - Pentachloroethane
2.3.4 Halogenated Pesticide and Chlorobenzene Wastes
Waste codes included in the halogenated pesticide and chlorobenzene
wastes treatability group are wastes associated with the pesticides industry
or wastes that are similar to pesticide wastes. The compounds in this treata-
bility group include chlorinated norbornanes and norbornene derivatives,
chlorophenoxy carboxylic acids, and chlorinated diphenyls. Chlorinated
norbornanes and norbornene derivatives have common functional groups of single
and double carbon-carbon bonds and have methyl chlorine substituents attached
to their rings. The functional groups common to chlorophenoxy carboxylic
acids include an aromatic ring, a carbon-oxygen-carbon single bond system, a
carbon-oxygen double bond, and a carbon-oxygen-hydrogen single bond system, as
well as at least two chlorines attached to the aromatic ring. Chlorinated
diphenyls consist of two aromatic rings singly bonded to a common carbon atom,
with at least one chlorine atom included in their structure. Members of each
of these subgroups are used as pesticides. The following waste codes are
included in this group:
• U038 - Chlorobenzilate
• U132 - Hexachlorophene
• U240 - 2,4-Dichlorophenoxyacetic salts and esters
2.3.5 Oxygenated Hydrocarbon and Heterocyclic Wastes
Waste codes included in the oxygenated hydrocarbon and heterocyclic
waste treatability group include oxygenated compounds that were not included
2-4
-------
in other waste treatability groups. These compounds contain at least one
oxygen atom integrated into the chemical structure by a single or double bond .
to a carbon atom. This group includes functional groups such as ketones,
aldehydes, and alcohols. The following waste codes are included in this
group:
P001 - Warfarin (>0.3%)
P003 - Acrolein
POOS - Allyl alcohol
P088 - Endothall
• P102 - Propargyl alcohol
• U001 - Acetaldehyde
U008 - Acrylic acid
• U053 - Crotonaldehyde
• U057 - Cyclohexanone
U085 - l,2:3,4-Diepoxybutane
• U113 - Ethyl acrylate
• U122 - Formaldehyde
U123 - Formic acid
U124 - Furan
U125 - Furfural
U126 - Glycidylaldehyde
U147 - Maleic anhydride
U154 - Methanol
• U166 - 1,4-Naphthoquinone
U182 - Paraldehyde
• U197 - p-Benzoquinone
• U213 - Tetrahydrofuran
U248 - Warfarin (<0.3%)
2.3.6 Wastes of a Pharmaceutical Nature
Waste codes included in the wastes of a pharmaceutical nature
treatability group are wastes associated with the pharmaceutical industry or
wastes that are similar to pharmaceutical wastes. All of the waste consti-
tuents included in this group are large, complex, heavily-substituted mole-
cules. Almost all of the waste constituents have aromatic rings incorporating
nitrogen- or sulfur-heterocyclic units or polynuclear aromatic structures.
All of the waste constituents have multiple double bonds and include oxygen,
nitrogen, or sulfur atoms. The following waste codes are included in this
group:
2-5
-------
• _ P007 - 5-Aminomethyl-3-isoxazolol
P042 - Epinephrine
• P075 - Nicotine and salts
P108 - Strychnine and salts
U010 - Mitomycin C
• U015 - Azaserine
U035 - Chlorambucil
• U059 - Daunomycin
U089 - Diethylstilbestrol
• U090 - Dihydrosafrole
• U143 - Lasiocarpine
U150 - Melphalan
U163 - N-Methyl-N-nitro-N-nitrosoguanidine
• U164 - Methylthiouracil
• U200 - Reserpine
• U202 - Saccharin and salts
• U206 - Streptozotocin
U237 - Uracil mustard
2.3.7 Phenolic Wastes
Waste codes included in the phenolic wastes treatability group
represent compounds that are classified as phenols and nitrophenols. The
nitrophenols also have a nitro group (N02) attached directly to the ring. The
following waste codes are included in this group:
P034 - 2-Cyclohexyl-4,6-dinitrophenol
• P047 - 4,6-Dinitro-o-cresol salts
U201 - Resorcinol
2.3.8 Polvnuclear Aromatic Wastes
The waste codes included in the polynuclear aromatic wastes group
represent compounds that are classified as polynuclear aromatics. These
compounds contain at least two fused or bridged aromatic rings and have an
aromatic ring as the common functional group. The compounds in this group
also have several substituents attached to their rings, including amides. In
some cases, one of the aromatic carbons may be substituted with another
element. The following waste codes are included in this group:
• U016 - 3,4-Benzacridine
• U064 - 1,2,7,8-Dibenzopyrene
• U094 - 7,12-Dimethyl benz(a)anthracene
2-6
-------
2.3.9
Organo-Nitrogen Compound Wastes
EPA grouped the nonhalogenated wastes containing nitrogen functional
groups that were not included in other waste treatability groups addressed in
the Third Third, into the organo-nitrogen compound wastes treatability group.
The compounds in the organo-nitrogen compound wastes treatability group
include nitrogen heterocyclics, amines and amides, aminated diphenyls and
biphenyls, nitriles, nitro compounds, and nitroso compounds. The following
waste codes are included in this group:
POOS - 4-Aminopyridine
P018 - Brucine
P046 - alpha,alpha-Dimethylphenethylamine
P054 - Aziridine
P064 - Isocyanic acid, methyl ester
P067 - 2-Methylaziridine
P069 - Methyllactonitrile
P082 - N-Nitrosodimethylamine
P084 - N-Nitrosomethylvinylamine
U003 - Acetonitrile
U007 - Acrylamide
U011 - Amitrole
U014 - Auramine
U021 - Benzidine
U091 - 3,3'-Dimethoxybenzidine
U092 - Dimethylamine
U093 - p-Dimethylaminoazobenzene
U095 - 3,3'-Dimethylbenzidine
U110 - Dipropylamine
U148 - Maleic hydrazide
U149 - Malononitrile
U167 - 1-Naphthylamine
U168 - 2-Naphthylamine
U171 - 2-Nitropropane
U173 - N-Nitrosodiethanolamine
U176 - N-Nitroso-N-ethylurea
U177 - N-Nitroso-N-methylurea
U178 - N-Nitroso-N-methylurethane
U191 - 2-Picoline
U194 - n-Propylamine
U234 - sym-Trinitrobenzene
U236 - Trypan blue
U238 - Ethyl carbamate
2-7
-------
2.3.10 Organo-Sulfur Compound Wastes
Waste codes included in the organo-sulfur compound wastes treata-
bility group include organo-sulfur compounds that were not included in other
waste treatability groups. The compounds in this group include aliphatic and
aromatic species; all of which have sulfur-carbon bonds as part of their
structure. The following waste codes are included in this group:
• P002 - l-Acetyl-2-thiourea
• P014 - Thiophenol (Benzenethiol)
P022 - Carbon disulfide
• P045 - Thiofanox
P049 - 2,4-Dithiobiuret
P066 - Methomyl
P070 - Aldicarb
P072 - l-Naphthyl-2-thiourea
• P093 - N-Phenylthiourea
• P116 - Thiosemicarbazide
• U114 - Ethylene bis-dithiocarbamic acid
• U116 - Ethylene thiourea
• U119 - Ethyl methanesulfonate
U153 - Methanethiol
• U193 - 1,3-Propane sultone
• U218 - Thioacetamide
U219 - Thiourea
U244 - Thirara
2.3.11 Miscellaneous Halogenated Organic Wastes
EPA grouped halogenated organic wastes (except brominated organic
wastes) that were not included in other waste treatability groups addressed in
the Third Third group of wastes into the miscellaneous halogenated organic
wastes treatability group. The compounds in this treatability group include
several of each of the following categories: chlorinated diphenyls; chlor-
inated polynuclear aromatics; chlorinated amines, amides, and nitriles;
chlorinated methylbenzenes; halogenated aliphatics; halogenated aldehydes,
ethers, and esters; and halogenated organosulfur compounds. The following
waste codes are included in this group:
• P016 - Bis(chloromethyl)ether
• P023 - Chloroacetaldehyde
• P026 - l-(o-Chlorophenyl)thiourea
2-8
-------
P027 - 3-Chloropropionitrile
P028 - Benzyl chloride
P057 - Fluoroacetamide
POS8 - Fluoroacetic acid, sodium salt
P095 - Phosgene
P118 - Trichloromethanethiol
U006 - Acetyl chloride
U017 - Benzal chloride
U020 - Benzene sulfonyl chloride
U026 - Chlor naphazine
U033 - Carbonyl fluoride
U034 - Trichloroacetaldehyde
U041 - l-Chloro-2,3-epoxypropane
U042 - 2-Chloroethyl vinyl ether
U046 - Chloromethyl methyl ether
U049 - 4-Chloro-o-toluidine hydrochloride
U062 - Diallate
U073 - 3,3'-Dichlorobenzidine
U097 - Dimethyl carbamoyl chloride
U156 - Methyl chlorocarbonate
U222 - o-Toluidine hydrochloride
2-9
-------
Table 2-1
WASTET TREATABILITY GROUPS FOR NONANALYZABLE U AND P WASTES
AROMATIC AND OTHER HYDROCARBON WASTES
U055 Cumene
U056 Cyclohexane
U186 1,3-Pentadiene
BROMINATED ORGANIC WASTES
P017 Bromoacetone
HALOGENATED ALIPHATIC WASTES
U074 cis-l,4-Dichloro-2-butene
U074 trans-l,4-Dichloro-2-butene
U184 Pentachlorethane
HALOGENATED PESTICIDE AND CHLOROBENZENE WASTES
U038 Chlorobenzilate
U132 Hexachlorophene
U240 2,4-Dichlorophenoxyacetic salts and esters
OXYGENATED HYDROCARBON AND HETEROCYCLIC WASTES
P001 Warfarin (>0.3%)
P003 Acrolein
POOS Allyl alcohol
P088 Endothall
P102 Propargyl alcohol
U001 Acetaldehyde
U008 Acrylic acid
U05 3 •Crotonaldehyde
U057 Cyclohexanone
U085 l,2:3,4-Diepoxybutane
U113 Ethyl acrylate
U122 Formaldehyde
U123 Formic acid
U124 Furan
U125 Furfural
U126 Glycidylaldehyde
U147 Maleic anhydride
U154 Methanol
Ul6 6 1,4-Naphthoquinone
U182 Paraldehyde
U197 p-Benzoquinone
U213 Tetrahydrofuran
U248 Warfarin (<0.3%)
2-10
-------
Table 2-1 (Continued)
WASTE" TREATABILITY GROUPS FOR NONANALYZABLE U AND P WASTES
WASTES OF A PHARMACEUTICAL NATURE
P007 5-Aminomethyl-3-isoxazolol
P042 Epinephrine
P075 Nicotine and salts
P108 Strychnine and salts
U010 Mitomycin C
U015 Azaserine
U035 Chlorambucil
U059 Daunomycin
U089 Diethylstilbestrol
U090 Dihydrosafrole
U143 Lasiocarpine
U150 Melphalan
U163 N-Methyl-N-nitro-N-nitrosoguanidine
U164 Methylthiouracil
U200 Reserpine
U202 Saccharin and salts
U206 Streptozotocin
U237 Uracil mustard
PHENOLIC WASTES
P034 2-Cyclohexyl-4,6-dinitrophenol
P047 4,6-Dinitro-o-cresol salts
U201 Resorcinol
POLYNUCLEAR AROMATIC WASTES
U016 Benz(c)acridine
U064 1,2,7,8-Dibenzopyrene
U094 7,12-Dimethyl benz(a)anthracene
ORGANO-NITROGEN COMPOUND WASTES
POOS 4-Aminopyridine
P018 Brucine
P046 alpha,alpha-Dimethylphenethylamine
P054 Aziridine
P064 Isocyanic acid, methyl ester
P067 2-Methylaziridine
P069 Methyllactonitrile
P082 N-Nitrosodimethylamine
P084 N-Nitrosomethylvinylamine
U003 Acetonitrile
U007 Acrylamide
U011 Amitrole
U014 Auramine
U021 Benzidine
2-11
-------
Table 2-1 (Continued)
WASTE"TREATABILITY GROUPS FOR NONANALYZABLE U AND P WASTES
ORGANO-NITROGEN COMPOUND WASTES (Continued)
U091 3,3'-Dimethoxybenzidine
U092 Dimethylamine
U093 p-Dimethylaminoazobenzene
U095 3,3'-Dimethylbenzidine
U110 Dipropylamine
U148 Maleic hydrazide
U149 Malononitrile
U167 1-Naphthylamine
U168 2-Naphthylamine
U171 2-Nitropropane
U173 N-Nitrosodiethanolamine
U176 N-Nitroso-N-ethylurea
U177 N-Nitroso-N-methylurea
U178 N-Nitroso-N-methylurethane
U191 2-Picoline
U194 n-Propylamine
U234 sym-Trinitrobenzene
U236 Trypan blue
U238 Ethyl carbamate
ORGANO-SULFUR COMPOUND WASTES
P002 l-Acetyl-2-thiourea
P014 Thiophenol (Benzenethiol)
P022 Carbon disulfide
P045 Thiofanox
P049 2,4-Dithiobiuret
P066 Methomyl
P070 Aldicarb
P072 l-Naphthyl-2-thiourea
P093 N-Phenylthiourea
P116 Thiosemicarbazide
U114 Ethylene bis-dithiocarbamic acid
U116 Ethylene thiourea
U119 Ethyl methanesulfonate
U153 Methanethiol
U193 1,3-Propane sultone
U218 Thioacetamide
U219 Thiourea
U244 Thiram
2-12
-------
Table 2-1 (Continued)
WASTE" TREATABILITY GROUPS FOR NONANALYZABLE U AND P WASTES
MISCELLANEOUS HALOGENATED ORGANIC WASTES
P016 Bis(chloromethyl)ether
P023 Chloroacetaldehyde
P026 l-(o-Chlorophenyl)thiourea
P027 3-Chloropropionitrile
P028 Benzyl chloride
P057 Fluoroacetamide
P058 Fluoroacetic acid, sodium salt
P095 Phosgene
P118 Trichloromethanethiol
U006 Acetyl chloride
U017 Benzal chloride
U020 Benzene sulfonyl chloride
U026 Chlornaphazine
U033 Carbonyl fluoride
U034 Trichloroacetaldehyde
U041 l-Chloro-2,3-epoxypropane
U042 2-Chloroethyl vinyl ether
U046 Chloromethyl methyl ether
U049 4-Chloro-o-toluidine hydrochloride
U062 Diallate
U073 3,3'-Dichlorobenzidine
U097 Dimethylcarbamoyl chloride
U156 Methyl chlorocarbonate
U222 o-Toluidine hydrochloride
2-13
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3.0 COMPLICATIONS PRECLUDING THE CALCULATION OF CONCENTRATION-BASED
TREATMENT STANDARDS
Developing and promulgating concentration-based treatment standards
for the U and P wastes regulated in this document was not feasible due to
difficulties in either (1) quantifying the particular U or P waste constituent
in hazardous waste matrices; or (2) applying the U and P waste treatment
standard calculation methodology to the available treatment data. The
specific complications precluding the calculation of a concentration-based
treatment standard for each U and P waste are identified in Table 3-1 (at the
end of this section) and are discussed in greater detail below.
3.1 Analytical Complications
Complications arise in the process of analyzing many U and P wastes
because the constituents of concern cannot be reliably quantified in hazardous
waste matrices. These complications preclude the establishment of concentra-
tion-based treatment standards. As a result, the Agency must establish
methods of treatment as the treatment standards for these wastes. The four
most common analytical complications for these wastes are as follows:
No EPA-approved methods exist that are currently verified and
demonstrated for the reliable quantification of the constitu-
ents of concern in treatment residuals;
Calibration standards for the constituents of concern are not
currently available in the commercial market;
The compound is unstable in water or may react with water; and
The listed waste does not represent a single chemical entity.
These complications are explained in more detail in the following subsections.
3-1
-------
3.1.1 Unavailability of a Verified Analytical Method
Some U and P waste constituents are not amenable to quantification
in hazardous waste matrices because SW-846 analytical methods have not yet
been established for their analysis. These compounds are not target analytes
for any known analytical methodologies. As a result, no verified methods are
available for their analysis and the stability, accuracy, and precision of
analytical results have not been determined.
For some U and P waste constituents, only high-performance liquid
chromatography (HPLC) analytical methods can be used to measure their con-
centrations. Although HPLC techniques have been used to quantify certain
compounds in relatively clean aqueous matrices, the Agency has not completely
verified that HPLC is appropriate for analysis of either untreated wastes or
treatment residuals. There is only one HPLC method that is currently listed.
in SW-846 as applicable for analysis of solid wastes, with limited applicabil-
ity. Until validation of this method is completed, the Agency does not
believe that it should establish concentration-based treatment standards for
U and P waste constituents based on data from HPLC analyses.
In other cases, SW-846 analytical methods have been established for
the analysis of particular U and P waste constituents; however, analytical
problems have been documented which significantly impact the accuracy of the
data obtained using these methods. Until these problems can be resolved, the
Agency does not believe that it should establish concentration-based treatment
standards for U and P waste constituents based on data from these analyses.
3.1.2 (fomin«»rcial Unavailability of Calibration Standards
Solutions of known purity and concentration of a chemical or mix of
chemicals are often referred to as calibration standards. These standards are
used by analytical laboratories to verify the accuracy and precision of an
analysis for a particular chemical or group of chemicals. The continued
availability of these standards from commercial chemical suppliers is
necessary to maintain proper quality assurance/quality control of quantitative
3-2
-------
analysis for constituents in treatment residuals, as required by the facility
analytical plan as part of the Part B permit requirement.
EPA determined which calibration standards are commercially avail-
able by asking five major suppliers whether they had the chemicals in stock
and whether they were available for shipment to prospective buyers. Unless a
compound is consistently in stock at major suppliers, the Agency believes that
the difficulties in obtaining these calibration standards and in verifying
their purity are sufficient cause not to establish concentration-based treat-
ment standards for these constituents in U and P wastes.
3.1.3 Instability in Water
Some U and P compounds dissociate, decompose, or otherwise sig-
nificantly change their identity when exposed to water. EPA is not establish-
ing concentration-based treatment standards for these compounds because some
moisture is typically inherent in most treatment residuals, particularly in
wastes classified as wastewaters. Thus, while analytical methods may exist
for some of these "unstable" compounds when measured in nonaqueous and certain
aqueous matrices, accurate quantification of their concentrations in treatment
residuals where there is a reasonable expectation that water may be present
would be severely hampered. Additionally, several constituents represented by
U and P codes were excluded front 40 CFR 264 Appendix IX (and therefore the
BOAT List) due to their instability in water.
3.1.4 Multiple Chemical Identity
For several U and P waste codes, the specific listing for that waste
code does not identify only one constituent for which the listing applies
(e.g., P075 is listed as "Nicotine and salts" and P051 is listed as "Endrin
and metabolites").
In cases where the U or P listing does not specify particular
isomers and there are a limited number of isomers, treatment standards typi-
cally are reported as applicable to all isomers, are isomer-specific, or are
3-3
-------
applicable to_the sum of the isomers depending on whether the identity of
isomers can be distinguished.
When the U or P waste code specifies "and salts" or "and metabo-
lites," the Agency typically chooses to specify a method of treatment as the
treatment standard rather than to establish a concentration-based standard to
preclude analysis for a particular chemical that may not have been present
originally.
3.2 Complications Associated with the Treatability Database
Some of the U and P waste codes included in this document are
amenable to quantification in hazardous waste matrices; however, methods of
treatment were specified as the treatment standards due to complications
encountered in applying the treatment standard calculation methodology for U
and P wastes to the treatment performance data available for particular
wastes. The affected U and P codes are:
POOS - Acrolein;
• U042 - 2-Chloroethyl vinyl ether;
• U091 - 3,3'-Dimethoxybenzidine; and
U095 - 3,3'-Dimethylbenzidine.
Treatment standards for wastewater forms of the U and P wastes that
are amenable to quantification in hazardous waste matrices were calculated
based on treatment performance data from various sources, including: (1) the
Office of Water's Industrial Technology Division (ITD) (specifically from the
Organic Chemicals, Plastics, and Synthetic Fibers (OCPSF) data base); (2) the
Office of Solid Waste's BOAT data (from previous land disposal restrictions
rules); (3) National Pollution Discharge Elimination System (NPDES) data; (4)
the Hazardous Waste Engineering Research Laboratory (HWERL) database; and (5)
additional wastewater treatment data 'from literature articles on wet air
oxidation and PACTR. Wastewater treatment performance data were not available
for the constituent of concern in U091 and U095 and data appropriate for
transfer to these constituents could not be identified. Therefore, concen-
3-4
-------
tration-based_treatment standards could not be calculated and a method of
treatment was established for the wastewater forms of U091 and U095.
Treatment standards for nonwastewater forms of the U and P wastes
that are amenable to quantification in hazardous waste matrices were calcu-
lated based on detection limits for incinerator ash residuals collected during
the 14 BOAT incineration treatment tests (listed in Table 4-1) performed by
EPA for the BOAT Land Disposal Restrictions Program. Concentration-based
treatment standards were calculated by multiplying the constituent detection
limit by an accuracy correction factor and by a variability factor. For the
nonwastewater forms of POOS, U042, U091, and U095, the range of detection
limits for these U and P wastes spanned several orders of magnitude, suggest-
ing that analyses for these constituents are difficult in incinerator ash
matrices due to matrix interferences. The treatment standards that were then
calculated based on these data were 1,000 ppm or greater. The establishment
of treatment standards at these levels would not ensure substantial treatment
for the constituents of concern. Therefore, for these constituents, in
nonwas vater forms of these U and P wastes, the Agency is specifying a method
of treatment as the BDAT treatment standard, rather than establishing concen-
tration-based treatment standards.
3-5
-------
Table 3-1
COMPLICATIONS PRECLUDING CALCULATION OF CONCENTRATION-BASED TREATMENT STANDARDS
Verified Analytical Method Unavailable
Unstable In Water
Waste
Code
P001
P002
P003
POOS
P007
Constituent
Warfarin (>0.3X)
1-Acetyl-2-thiourea
Acrolein
Allyl alcohol
5-Aminomethyl-3-isoxazolol
Only HPLC
No SW-846 Methods Available;
Method Not Good For
Available Complex Matrices
X
X
X
X
Analysis
Hay
Present
Problems
Chemical
Standards Not Group,
Commercially Not Single
Avai table Const i tuent
BOAT Constituent
Constituent Not Included In
Unstable 40 CFR Part 264
In Water Appendix IX
I
Magnitude Of
Numerical Standard
Does Not Represent
Substantial Treatment
X
CO
I
P008 4-Aminopyridine
P014 Thiophenol (Benzenethiol)
P016 Bis(chloromethyl)ether
P017 Bromoacetone
P018 Brucine
P022 Carbon bisulfide
P023 Chloroacetaldehyde
P026 1-(o-Chlorophenyl)thiourea
P027 3-Chloropropionitrile
P028 Benzyl chloride
P034 2-Cyclohexyl-4,6-dinitrophenol
P042 Epinephrine
P045 Thiofanox
P046 alpha,alpha-Dimethylphenethylamine
P047 4,6-Dinitro-o-cresol salts
-------
Table 3-1 (Continued)
COMPLICATIONS PRECLUDING CALCULATION OF CONCENTRATION-BASED TREATMENT STANDARDS
Verified Analytical Method Unavailable Unstable In Water
Code
P049
P054
P057
POS8
P064
P066
P067
P069
P070
P072
POTS
P082
P084
P088
P093
P095
P102
P108
P116
Constituent
2,4-Dithiobiuret
Aziridine
Fluoroacetamide
Fluoroacetic acid, sodium salt
Isocyanic acid, methyl ester
Methomyl
2-Methylaziridine
Methyl lactonitrile
Aldicarb
1-Naphthyl-2-thiourea
Nicotine and salts
N-Nitrosodimethylamine
N-Nitrosomethylvinylamine
Endothall
N-Phenylthiourea
Phosgene
Propargyl alcohol
Strychnine and salts
Th i osemi carbaz i de
1
Only HPLC Analysis Chemical BOAT Constituent Magnitude Of
No SU-846 Methods Available; May Standards Not Group, Constituent Not Included In Numerical Standard
Method Not Good For Present Commercially Not Single Unstable 40 CFR Part 264 Does Not Represent
Available Complex Matrices Problems Available Constituent In Water Appendix IX Substantial Treatment
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
P118 Trichloromethanethiol
-------
Table 3-1 (Continued)
COMPLICATIONS PRECLUDING CALCULATION OF CONCENTRATION-BASED TREATMENT STANDARDS
Verified Analytical Method Unavailable
Unstable In Water
oo
Code
U001
U003
U006
U007
U008
U010
U011
U014
U015
U016
U017
U020
U021
U026
U033
Constituent
Ace t aldehyde
Acetonitrile
Acetyl chloride
Acrylamide
Acrylic acid
Mitomycin C
Ami t role
Auramine
Azaserine
Benz(c)acridine
Benzal chloride
Benzene sulfonyl chloride
Benzidine
Chlornaphazine
Carbonyl fluoride
1
Only HPLC Analysis Chemical BOAT Constituent Magnitude Of
No SW-846 Methods Available; May Standards Not Group, Constituent Not Included In Numerical Standard
Method Not Good For Present Commercially Not Single Unstable 40 CFR Part 264 Does Not Represent
Available Complex Matrices Problems Available Constituent In Water Appendix IX Substantial Treatment
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
U034 Trichloroacetaldehyde (Chloral)
U035 Chlorambucil
U038 Chlorobenzilate
U041 1-Chloro-2,3-epoxypropane (Epichlorohydrin)
U042 2-Chloroethyl vinyl ether
-------
Table 3-1 (Continued)
COMPLICATIONS PRECLUDING CALCULATION OF CONCENTRATION-BASED TREATMENT STANDARDS
Verified Analytical Method Unavailable
Unstable In Water
Code
U046
U049
U053
U055
U056
U057
U059
U)
1 U062
vO
U064
U073
U074
U074
U08S
U089
U090
Only HPLC
No SU-846 Methods Available;
Method Not Good For
Constituent Available Complex Matrices
Chloromethyl methyl ether
4-Chloro-o-toluidine hydrochloride X
Crotonaldehyde
Cumene X
Cyclohexane
Cyclohexanone
Daunomycin X
Diallate X
1,2,7,8-Dibenzopyrene
3,3'-Dichlorobenzidine
cis-1,4-Dichloro-2-butene
trans- 1,4-Dichloro-2-butene
1,2:3,4-Diepoxybutane X
Oiethylstilbestrol X
Dihydrosafrole
I
Analysis Chemical BOAT Constituent Magnitude Of
May Standards Not Group, Constituent Not Included In Numerical Standard
Present Commercially Not Single Unstable 40 CFR Part 264 Does Not Represent
Problems Available Constituent In Water Appendix IX Substantial Treatment
X
X
X
X
X
X
X
X
X
U091 3,3'-Dimethoxybenzidine
U092 Dimethylamine
U093 p-Dimethylaminoazobenzene
U094 7,12-Dimethyl benz(a)anthracene
U095 3,3'-Dimethylbenzidine
-------
Table 3-1 (Continued)
COMPLICATIONS PRECLUDING CALCULATION OF CONCENTRATION-BASED TREATMENT STANDARDS
Verified Analytical Method Unavailable
Unstable In Water
UJ
I
Code
U097
U110
U113
U1U
U116
U119
U122
U123
U124
U125
U126
U132
UH3
U147
UU8
Constituent
Dimethylcarbamoyl chloride
Dipropylamine
Ethyl acrylate
Ethylene bis-dithiocarbamic acid
Ethylene thiourea
Ethyl methanesulfonate
Formaldehyde
Formic acid
Furan
Furfural
Glycidylaldeyde
Hexachlorophene
Lasiocarpine
Maleic anhydride
Haleic hydrazide
Only HPLC Analysis Chemical BOAT Constituent Magnitude Of
No SW-846 Methods Available; May Standards Not Group, Constituent Not Included In Numerical Standard
Method Not Good For Present Commercially Not Single Unstable 40 CFR Part 264 Does Not Represent
Available Complex Matrices Problems Available Constituent In Water Appendix IX Substantial Treatment
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
U149 Malononitrile
U150 Helphalan
U1S3 Hethanethiol
U154 Methanol
U156 Methyl chlorocarbonate
-------
Table 3-1 (Continued)
COMPLICATIONS PRECLUDING CALCULATION OF CONCENTRATION-BASED TREATMENT STANDARDS
Verified Analytical Method Unavailable
Unstable In Water
10
I
Code
U163
U164
U166
U167
U168
U171
U173
U176
U177
U178
U182
U184
U186
U191
U193
Only HPLC
No SU-846 Methods Available;
Method Not Good For
Constituent Available Complex Matrices
N-Methyl-N-nitro-N-nitrosoguanidine X
Methyl thiouraci 1 X
1,4-Naphthoquinone
1-Naphthylamine
2-Naphthylamine
2-Nitropropane
N-Nitrosodiethanolamine X
N-Nitroso-M-ethylurea X
N-Nitroso-N-methylurea X
N-Nitroso-N-methylurethane X
Paraldehyde
Pentach I oroethane
1,3-Pentadiene X
2-Picoline
1,3-Propane sultone X
Analysis
May
Present
Problems
X
X
X
X
X
Chemical BOAT Constituent Magnitude Of
Standards Not Group, Constituent Not Included In Numerical Standard
Commercially Not Single Unstable 40 CFR Part 264 Does Not Represent
Available Constituent In Water Appendix IX Substantial Treatment
X
U194 n-Propylamine .
U197 p-Benzoquinone
U200 Reserpine
U201 Resorcinol
U202 Saccharin and salts
-------
Table 3-1 (Continued)
COMPLICATIONS PRECLUDING CALCULATION OF CONCENTRATION-BASED TREATMENT STANDARDS
Verified Analytical Method Unavailable
Unstable In Water
Code
U206
U213
U218
U219
U222
w U23*
,1 u236
N» U237
U238
U240
Constituent
Streptozotocin
Tetrahydrofuran
Thioacetamide
Thiourea
o-Toluidine hydrochloride
sym- T r i n i t robenzene
Trypan blue
Uracil mustard
Ethyl carbamate
2,4-Dichlorophenoxyacetic
No SU-846
Method
Available
X
X
X
salts and esters
Only HPLC
Methods Available;
Not Good For
Complex Matrices
X
X
X
X
X
Analysis Chemical BDAT Constituent Magnitude Of
May Standards Not Group, Constituent Not Included In Numerical Standard
Present Commercially Not Single Unstable 40 CFR Part 264 Does Not Represent
Problems Available Constituent In Water Appendix IX Substantial Treatment
X
X
U244 Thiram
U248 Warfarin (<0.3X)
-------
4.0 IDENTIFICATION OF APPLICABLE, DEMONSTRATED, AND BEST TECHNOLOGY
This section presents the Agency's rationale for determining the
best demonstrated available technology (BOAT) for treating U and P wastes for
which concentration-based treatment standards could not be calculated. These
standards could not be calculated due to difficulties in either (1) quantify-
ing the particular U or P waste constituent in hazardous waste matrices; or
(2) applying the U and P waste treatment standard calculation methodology to
the available treatment data.
This section presents the Agency's determination of:
• Applicable technologies;
• Demonstrated technologies; and
• The best demonstrated available technology (BOAT) for treatment
of these wastes.
In determining BDAT, the Agency first determines which technologies are
potentially applicable for treatment of the waste(s) of interest. The Agency
then determines which of the applicable technologies are demonstrated for
treatment of the waste(s) of interest. Next, the Agency determines which of
the demonstrated technologies is "best" for the purpose of establishing BDAT.
Finally, the Agency determines whether the best demonstrated technology is
"available" for treatment of the waste(s) of interest.
4.1 Applicable Treatment Technologies
To be applicable, a technology must theoretically be usable to treat
the waste in question or a waste that is similar in terms of parameters that
affect treatment selection. The following subsections present applicable
treatment technologies for nonwastewater and wastewater forms of the U and P
wastes included in this document. Detailed descriptions of technologies that
are applicable to treat listed hazardous wastes are provided in EPA's Treat-
ment Technology Background Document (Reference 3).
4-1
-------
4.1.1 Non"flstewaters
Since nonwastewater forms of the U and P wastes generally contain
hazardous organic constituents at treatable concentrations, applicable treat-
ment technologies include those that destroy or reduce the total amount of
various organic compounds in the waste. The Agency has identified the follow-
ing treatment technologies as applicable for these wastes:
• Incineration (fluidized-bed, rotary kiln, and liquid injec-
tion) ;
• Fuel substitution;
• Solvent extraction followed by incineration or recycle of the
extract;
• Critical fluid extraction followed by incineration of the
contaminated solvents;
• Wet air oxidation;
• Chemical oxidation; and
• Distillation.
Total recycle or reuse may also be applicable for certain wastes, such as off-
specification commercial chemical products. These treatment technologies were
identified based on current waste treatment practices and engineering
judgment.
Many of the U and P wastes addressed in this background document are
generated in a variety of physical forms. The physical form of the waste may
govern the selection of the actual type of applicable treatment technology.
For example, a contaminated soil may be amenable to rotary kiln incineration,
while an off-specification liquid chemical product may be amenable to liquid
injection incineration.
4-2
-------
Incineration
Incineration is a destruction technology in which energy, as heat,
is transferred to the waste to destabilize chemical bonds and destroy
hazardous organic constituents. The three types of incinerator design applic-
able to U and P organic wastes are fluidized-bed, rotary kiln, and liquid
injection incineration.
In a fluidized-bed incinerator, solid and semi-solid wastes are
injected into the fluidized-bed material (generally sand and/or incinerator
ash), where it is heated to its ignition temperature. Heat energy from the
combustion reactions is then transferred back to the fluidized-bed. Ash is
removed periodically during operation and during bed change-outs.
In a rotary kiln incinerator, solid and semi-solid wastes are fed
into the elevated end of the kiln, and the rotation of the kiln mixes the
waste with hot gases to heat the waste to its ignition temperature. Ash is
removed from the lower end of the kiln. Combustion gases from the kiln enter
the afterburner for complete destruction of organic waste constituents. Other
wastes may also be injected into the afterburner.
In a liquid injection incinerator, liquid wastes are atomized and
injected into the incinerator. In general, only wastes with low or negligible
ash contents are amenable to liquid injection incineration. Therefore, this
technology generally does not generate an ash residual.
Combustion gases from the incinerator are then fed to a scrubber
system for cooling and removal of entrained particulates and acid gases, if
present. In general, with the exception of liquid injection incineration, two
residuals are generated by incineration processes: ash and scrubber water.
Further treatment of organics in ash or scrubber water should not be required.
4-3
-------
Fuel Substitution
Fuel substitution is a destruction technology in which energy, as
heat, is transferred to the waste to destabilize chemical bonds and destroy
organic constituents. Fuel substitution differs from incineration in that the
waste is used as a fuel in industrial furnaces or boilers. Two residuals may
be generated by the fuel substitution process: ash and scrubber water.
Further treatment of organics in ash or scrubber water should not be required.
Solvent Extraction
Solvent extraction is a separation technology in which organics are
removed from the waste due to greater constituent solubility in the solvent
phase than in the waste phase. This technology generates two residuals: a
treated waste residual and a treated waste extract. The extract may be
recycled or may be destroyed by incineration.
Critical Fluid Extraction
Critical fluid extraction is a solvent extraction technology in
which the solvent is brought to its critical state (liquid gas) to aid in the
extraction of hazardous organic constituents from the wastes. After the
extraction step, the solvent is returned to its normal gaseous state, generat-
ing a small volume of extract that is concentrated in hazardous organic
constituents. This technology generates two residuals: a treated waste
residual and a treated waste extract. The extract may be recycled or may be
destroyed by incineration.
Wet Air Oxidation
Wet air oxidation is a destruction technology in which hazardous
organic constituents in wastes are oxidized and destroyed under pressure at
elevated temperatures in the presence of dissolved oxygen. This technology is
applicable for wastes comprised primarily of water and up to 10% total organic
constituents. Wet air oxidation generates one treatment residual: treated
4-4
-------
effluent. Tha. treated effluent may require further treatment for hazardous
organic constituents by carbon adsorption (this technology is described in
Section 4.1.2). Air emissions from wet air oxidation may require further
treatment by incineration.
Chemical Oxidation
Chemical oxidation is a treatment technology that may be used to
treat wastes containing organics and, in some cases, to treat sulfide and
cyanide wastes. The basic principle of chemical oxidation is that some
dissolved organic compounds, inorganic cyanides, and sulfides are chemically
oxidized to yield carbon dioxide, water, salts, simple organic acids, and, in
the case of sulfides, sulfates. The principal chemical oxidants used are
hypochlorite, chlorine gas, chlorine dioxide, hydrogen peroxide, ozone, and
potassium permanganate. Chemical oxidation generates an aqueous waste stream
which is either discharged or transferred to another process for further
treatment.
Distillation
Distillation is the separation of a liquid mixture into various
components by a process of vaporization and condensation. As a treatment
technology, distillation is applicable to the treatment of wastes containing
organics that are volatile enough to be removed by the application of heat.
This technology generates an organic stream that may be reusable and a bottom
stream that is often incinerated.
Total Recycle or Reuse
Total recycle or reuse of a waste in the same process or another
process eliminates the generation of the waste and consequently generates no
treatment residuals. Total recycle or reuse may be applicable for certain U
and P wastes, such as off-specification products.
4-5
-------
4.1.2 Wasrewaters
Since wastewater forms of the U and P wastes may contain hazardous
organic constituents at treatable concentrations, applicable technologies
include those that destroy or reduce the total amount of various organic
compounds in the waste. Therefore, the Agency has identified the following
treatment technologies as potentially applicable for treatment of these
wastes:
• Incineration (fluidized-bed, rotary kiln, and liquid
injection);
• Wet air oxidation;
• Biological treatment;
• Carbon adsorption;
• Solvent extraction followed by incineration or recycle of the
extract;
• Chemical oxidation;
• Distillation; and
• Steam stripping.
Total recycle or reuse may also be applicable for certain wastewaters. These
treatment technologies were identified based on current waste treatment
practices, and engineering judgment.
The concentrations and type(s) of waste constituents present in the
waste generally determine which technology is most applicable. Carbon adsorp-
tion, for example, is often used as a polishing step following primary treat-
ment by biological treatment, solvent extraction, or wet air oxidation.
Typically, carbon adsorption is applicable for treatment of wastewaters
containing less than 0.1% total organic constituents. Wet air oxidation,
biological treatment, and solvent extraction are applicable for treatment of
wastewaters containing up to 1% total organic constituents. Many of the
wastewaters that are the subject of this document may contain constituents
4-6
-------
that are too .toxic to biomass and therefore cannot be treated effectively by
biological treatment.
Incineration
The description of incineration of nonwastewaters was given pre-
viously in Section 4.1.1. This description also applies to the incineration
of wastevaters, particularly that of liquid injection incineration.
Wet Air Oxidation
The description of wet air oxidation of nonwastewaters was previous-
ly described previously in Section 4.1.1. This description also applies to
the wet air oxidation of wastewaters.
Biological Treatment
Biological treatment is a destruction technology in which hazardous
organic constituents in wastewaters are biodegraded. This technology gener-
ates two treatment residuals: a treated effluent and a waste biosludge.
Waste biosludge may be land-disposed without further treatment if it meets the
BOAT treatment standard for the nonwastewater form of the waste.
Carbon Adsorption
Carbon adsorption is a separation technology in which hazardous
organic constituents in wastewaters are selectively adsorbed onto activated
carbon. This technology generates two treatment residuals: a treated efflu-
ent and spent activated carbon. The spent activated carbon can be reactivated
and recycled.
4-7
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Solwnt Extraction
The description of solvent extraction of nonwastewaters was given
previously in Section 4.1.1. This description also applies to the solvent
extraction of wastewaters.
Chemical Oxidation
The .description of chemical oxidation of nonwastewaters was given
previously in Section 4.1.1. This description also applies to the chemical
oxidation of wastewaters.
Distillation
The description of distillation of nonwastewater was given previous-
ly in Section 4.1.1. This description also applies to the distillation of
wastewaters.
Steam Stripping
Steam stripping is a form of distillation applicable to the treat-
ment of wastewaters containing organics that are volatile enough to be removed
by the application of heat, using steam as the heat source. The constituents
that are volatilized are then condensed and typically either reused or further
treated by liquid injection incineration. Typically, steam stripping is
applied where there is less than 1% volatile organics in the waste.
Total Recycle or Reuse
Total recycle or reuse of a waste in the same process or another
process eliminates the generation of the waste and consequently generates no
treatment residual.
4-8
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4.2 Demonstrated Treatment Technologies
To be demonstrated, a technology must be employed in full-scale
operation for treatment of the waste in question or a similar waste. Tech-
nologies available only at pilot- or bench-scale operations are not considered
in identifying demonstrated technologies.
4.2.1 Nonwastewaters
The Agency has identified incineration as a demonstrated technology
for treatment of nonwastewater forms of the U and P wastes included in this
document. For the land disposal restrictions program, the Agency tested
rotary kiln incineration on a full-scale operational basis for the following
waste constituents:
Aromatic and other Hydrocarbon Wastes
Toluene
Brominated Organic Wastes
1,2-Dibromoethane (ethylene dibromide)
Halogenated Aliphatic Wastes
Bis(2-chloroethyl)ether
1,1-Dichloroethane
1,1,1-Trichloroethane
1,2,4-Trichlorobenzene
Halogenated Pesticide and Chlorobenzene Wastes
Hexachlorocyclopentadiene
Chlordane
Heptachlor
Chlorobenzene
1,2-Dichlorobenzene
1,4-Dichlorobenzene
Hexachlorobenzene
Pentachlorobenzene
Pentachloronitrobenzene
1,2,4,5-Tetrachlorobenzene
2,4-Dichlorophenoxyacetic acid
Methoxychlor
Hexachlorobutadiene
4-9
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Oxygenated Hydrocarbon and Heterocvclic U and P Wastes
Acetone
Ethyl acetate
Methyl ethyl ketone
Methyl isobutyl ketone
1,4-Naphthoquinone
Wastes of a Pharmaceutical Nature
Isosafrole
Phenolic Wastes
2-sec-Butyl-4,6-dinitrophenol (Dinoseb)
o-Cresol
p-Cresol
Phenol
Polynuclear Aromatic Wastes
Benzo(a)pyrene
Chrysene
Indeno(1,2,3-cd)pyrene
Benz(a)anthracene
Fluoranthene
Naphthalene
Organo-Nitrogen Compound Wastes
Acetonitrile
Acrylonitrile
Aniline
Nitrobenzene
Pyridine
Miscellaneous Halogenated Organic Wastes
Chloromethane
Dichlorodifluoromethane
Vinyl chloride
Bis(2-chloroethyl)ether
3,3'-Dichlorobenzidine
Pronamide
The Agency believes that since incineration is demonstrated for
treatment of these waste constituents, incineration is also demonstrated for
all of the U and P wastes included in each treatability group. As discussed
in Section 2.0, similar chemical and physical properties are exhibited by the
4-10
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constituents in each treatability group. Incineration should be able to
destabilize and destroy, in a similar fashion, waste constituents which -
exhibit similar chemical structures. Therefore, incineration is expected to
successfully treat all of the U and P wastes in each treatability group.
Complete discussions of test methods and presentations of analytical data are
available in the on-site engineering reports (OERs) for the tests. (A list of
the treatment tests conducted by the Agency as part of the BOAT Land Disposal
Restrictions Program, along with references for the corresponding OERs and
background documents, is provided in Table 4-1 at the end of this section.)
No technologies have been identified as demonstrated for treatment
of organo-sulfur nonwastewaters. However, the Agency believes that inciner-
ation is also demonstrated for organo-sulfur compound wastes because they are
similar in chemical structure to other chlorinated organo-sulfur wastes in the
miscellaneous halogenated organic waste treatability group that have been
successfully treated by incineration on a full-scale operational basis. In
addition, the Agency believes that incineration is demonstrated on a full-
scale operational basis for treatment of aromatic and polynuclear aromatic
nonwastewaters based on a review of data provided by many of the treaters of
these U-wastes identified in the 1986 TSDR Survey (Reference 4).
The Agency is not aware of any facilities that treat these wastes by
fuel substitution; however, the Agency believes that fuel substitution is
demonstrated for wastes that are more difficult to treat, such as K027, Klll-
K116, U221, and U223. These wastes contain dinitrotoluene, toluenediamine,
and toluene diisocyanate, which tend to polymerize and are therefore con-
sidered by the Agency to be more difficult to treat than the U and P wastes
included in this document. Therefore, the Agency believes that fuel substitu-
tion is a demonstrated technology for the U and P nonwastewaters included in
this document.
From review of the 1986 TSDR Survey (Reference 4) and the USEPA's
Water Engineering Research Laboratory (WERL) database (Reference 5), the
Agency determined that some facilities also treat nonwastewater forms of
aromatic and polynuclear aromatic wastes or wastes judged to be similar on a
4-11
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full-scale operational basis using wet air oxidation, chemical oxidation, and
distillation; therefore, EPA believes that these technologies are also demon-
strated (on a full-scale basis) for aromatic and polynuclear aromatic wastes.
The Agency is not aware of any facilities that treat nonwastewater
forms of these wastes or wastes judged to be similar on a full-scale opera-
tional basis using solvent extraction or critical fluid extraction; therefore,
EPA believes that these technologies are not currently demonstrated for these
wastes.
Total recycle or reuse is demonstrated for treatment of several off-
specification pesticide nonwastewaters as determined from telephone contacts
with pesticide manufacturers, femulators, and packagers. The Agency is not
aware of any other types of facilities that conduct total recycle or reuse of
wastes in other U and P treatability groups included in this document.
Therefore, recycle and reuse is not considered to be demonstrated for any of
these other wastes at this time.
"4.2.2 Wastewaters
The following technologies have been identified as demonstrated for
treatment of the following waste constituents (organized by chemical struc-
ture) :
Aromatic and Other Hydrocarbon Wastes
Incineration
Biological Treatment
Carbon Adsorption
Wet Air Oxidation
Chemical Oxidation
Steam Stripping
Brominated Organic Wastes
Biological Treatment
4-12
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Halogenated Aliphatic Wastes
Incineration
Wet Air Oxidation
Chemical Oxidation
Biological Treatment
Carbon Adsorption
Solvent Extraction
Distillation
Steam Stripping
Halogenated Pesticide and Chlorobenzene Wastes
Biological Treatment
Wet Air Oxidation
Steam Stripping
Carbon Adsorption
Oxygenated Hydrocarbon and Heterocvclic Wastes
Biological Treatment
Carbon Adsorption
Steam Stripping
Wet Air Oxidation
Wastes of a Pharmaceutical Nature
Wet Air Oxidation
Phenolic Wastes
Wet Air Oxidation
Carbon Adsorption
Biological Treatment
Chemical Oxidation
Solvent Extraction
Steam Stripping
Polynuclear Aromatic Wastes
Incineration
Biological Treatment
Carbon Adsorption
Wet Air Oxidation
Chemical Oxidation
Steam Stripping
4-13
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Orpqno-Nitrogen Compound Wastes
Biological Treatment
Carbon Adsorption
Steam Stripping
Wet Air Oxidation
Solvent Extraction
Miscellaneous Halogenated Organic Wastes
Biological Treatment
Steam Stripping
Carbon Adsorption
Solvent Extraction followed by Steam Stripping followed by Carbon
Adsorption
Chemical Oxidation
Wet Air Oxidation
No technologies have been identified as demonstrated for treatment
of organo-sulfur compound wastewaters. The Agency believes, however, that
since these wastes are similar in chemical structure to chlorinated organo-
sulfur wastes in the miscellaneous halogenated organic waste treatability
group, treatment technologies identified as demonstrated for miscellaneous
halogenated organic wastewaters are also demonstrated for organo-sulfur
compound wastewaters.
For some of the waste groups, the Agency is not aware of any facili-
ties that incinerate wastewater forms of the U and P wastes. However, com-
menters to the Second Third proposed rule indicated that they were indeed
incinerating many wastewaters and that they did not want to be precluded from
doing so. In addition, the Agency has conducted incineration tests which
demonstrate that incineration is an effective treatment technology for a wide
variety of U and P organic compounds - halogenateds and nonhalogenateds - and
pesticides. EPA's evidence that incineration constitutes significant treat-
ment for these compounds is that these compounds were analyzed at or near
their detection limits in the ash and scrubber water from these tests. These
compounds have similar chemical structures and physical properties to the
compounds in all of the waste treatability groups represented in this docu-
ment. Since incineration is demonstrated for treatment of waste constituents
in nonwastewater forms of these wastes as discussed in Section 4.2.1, the
4-14
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Agency believes incineration is also demonstrated for these waste constituents
in wastewater forms of these wastes. Therefore, the Agency is also identify-
ing incineration as a demonstrated technology for wastewaters.
The Agency is aware of several facilities that recycle and reuse
off-specification halogenated pesticides and chlorobenzene, halogenated
phenolic, and phenolic U and P wastes. Therefore, recycle and reuse is
considered to be demonstrated for these wastes. The Agency is not aware of
any facilities generating U and P wastes in the other waste groups that do so.
Therefore, recycle and reuse is not considered to be demonstrated for these
wastes at this time.
Based on engineering judgment, the Agency considers the following
technologies to be demonstrated for wastewater forms of the U and P wastes
included in this document:
Distillation;
• Solvent extraction;
• Steam stripping;
• Biological treatment;
• Wet air oxidation;
• Chemical oxidation;
• Carbon adsorption; and
• Incineration.
4.3 Identification of Best Demonstrated Available Treatment Technology
(BOAT)
Best demonstrated technology is determined based on a thorough
review of all the treatment data available on the waste of concern or wastes
judged to be similar. Following the identification of "best," the Agency
determines whether the technology is "available." An available treatment
technology is one that (1) is not a proprietary or patented process that
cannot be purchased or licensed from the proprietor (i.e., it must be commer-
cially available), and (2) substantially diminishes the toxicity of the waste
or substantially reduces the likelihood of migration of hazardous constituents
from the waste.
4-15
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4.3.1 Nonwastewaters
For a treatment technology to be identified as "best," the treatment
performance data are first screened to determine:
• Whether the data represent operation of a well-designed and
well-operated treatment system;
• Whether sufficient analytical quality assurance/quality control
measures were employed to ensure the accuracy of the data; and
• Whether the appropriate measure of performance was used to
assess the performance of the particular treatment technology.
As discussed previously, distillation, chemical oxidation, wet air
oxidation, fuel substitution, and incineration are all demonstrated treatment
technologies for nonwastewater forms of U and P wastes.
The Agency has obtained a large amount of incinerator ash analytical
data from the 14 BOAT land disposal restrictions program treatment tests,
conducted at what EPA considers to be well-designed and well-operated hazard-
ous waste incinerators. Strict quality assurance/quality control measures
were employed to ensure the accuracy of the data, and since EPA was collecting
these data to identify and characterize BOAT treatment technologies, appro-
priate performance variables, namely, U and P waste constituent concentrations
in treated and untreated waste, were measured. Based on this data and other
information, the Agency has determined that due to the high temperatures,
efficient mixing, and consistent residence times used at commercial hazardous
waste incinerators, incineration processes are relatively indiscriminate in
the destruction of organics. Based on the treatability data available, the
Agency considers incineration to be a "best" technology for the treatment of
nonwastewater forms of U and P wastes. The Agency believes that since incin-
eration is BDAT for wastes amenable for quantification within each treata-
bility group, incineration would also be BDAT for all of the wastes in each
group.
The Agency does not have analytical data characterizing the treat-
ment performance of fuel substitution on nonwastewater forms of unquantifiable
4-16
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U and P wastes; however, based on the significant energy recovery value of
some U and P wastes, the Agency believes that fuel substitution may qualify as
a "best" technology for these wastes.
EPA is concerned, though, that using those U and P wastes, which
contain sulfur, nitrogen, and halogens, as fuel to boilers and furnaces may
result in unregulated SOX, NOZ, and halogen emissions. As a result, the
Agency considers fuel substitution to be a "best" technology only for non-
wastewater forms of U and P wastes which contain carbon, hydrogen, and/or
oxygen in their molecular structure. Fuel substitution is not considered a
"best" technology for nonwastewater forms of U and P wastes which contain
sulfur, nitrogen, or halogens in their molecular structure.
The Agency has very little analytical data characterizing treatment
performance of chemical oxidation, wet air oxidation, or distillation on
nonwastewater forms of U and P wastes. The only data available is limited to
the treatment of certain aromatic and polynuclear aromatic U and P wastes.
EPA does not have any basis for transferring this treatability data to other U
and P waste treatability groups; therefore, the Agency does not consider
chemical oxidation, wet air oxidation, or distillation to be "best" tech-
nologies for the treatment of nonwastewater forms of unquantifiable U and P
wastes.
Incineration is a commercially available technology. Additionally,
treatment performance data from the 14 BOAT incineration treatment tests
(Table 4-1) show substantial treatment by incineration for waste constituents
of concern and other similar constituents in nonwastewater forms of unquan-
tifiable U and P wastes. Therefore, incineration is an "available" treatment
technology for these wastes for the purpose of establishing BOAT.
Fuel substitution, according to industry comments, is also a com-
mercially available technology. Fuel substitution typically takes place in
cement kilns, industrial boilers and furnaces, and other commercial combustion
chambers. The Agency believes that fuel substitution substantially decreases
the toxicity of applicable U and P wastes (i.e., compounds containing only
4-17
-------
carbon, hydrogen, and/or oxygen) since organic constituents should similarly
be destroyed incinerators and industrial boilers and furnaces. Therefore,
fuel substitution is an "available" treatment technology for those wastes for
the purpose of establishing BDAT.
Incineration has been determined to be BDAT for all of the non-
wastewaters that cannot be quantified in hazardous waste matrices using
current analytical methods, based on similarities in chemical and physical
properties. Additionally, the Agency believes that the combustion charac-
teristics of U and P wastes with high energy value are essentially the same,
regardless of whether they are incinerated or used as fuel in industrial
boilers and furnaces. As a result, the Agency has determined that fuel
substitution is also BDAT for the unquantifiable U and P nonwastewaters that
contain only carbon, hydrogen, and/or oxygen in their chemical structure.
4.3.2 Wastewaters
As discussed previously, distillation, solvent extraction, steam
stripping, biological treatment, wet air oxidation, chemical oxidation, carbon
adsorption, and incineration are all demonstrated technologies for U and P
wastewaters.
The Agency believes that the best technologies for treating the U
and P wastewaters, for which methods of treatment are being promulgated as
treatment standards, are those technologies that destroy the U and P constit-
uents. Steam stripping, solvent extraction, and distillation are technologies
that remove the U and P constituents from the wastewater stream; however, the
waste constituents are not destroyed but are transferred to a more concen-
trated waste stream, i.e., the condensate, extract, or bottom stream (or still
bottoms). This waste stream would require further treatment before disposal.
As a result, the Agency does not consider steam stripping, solvent extraction,
or distillation to be best technologies for treating wastewater forms of the U
and P wastes covered in this document.
4-18
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The_£act that a technology removes waste constituents, but does not
destroy them, does not necessarily preclude it from being considered "best."
As discussed below, carbon adsorption is being promulgated as part of the
chemical and wet air oxidation treatment trains. The purpose of the carbon
adsorption step as part of this treatment train is to remove organic oxidation
by-products resulting from the oxidation of U and P waste constituents.
Carbon adsorption was selected for this removal step over steam stripping,
solvent extraction, and distillation because the Agency believes that carbon
adsorption is the most appropriate removal technology for the widest range of
organic compounds likely to be present in the oxidation effluent stream.
Biological treatment is not considered to be the best technology for
treatment of these organic U and P wastewaters since concentrations of these
wastes in the influent to the biological treatment unit cannot be measured.
Therefore, the treatment unit operators cannot control the levels of these
wastes reaching the working organisms in the biological treatment unit. The
risk of sending unmeasurable quantities of these wastes to a biological
treatment unit includes the possibility of shock loads that would disable the
plant's working organisms, allowing these wastes to exit untreated in the
effluent until the biological treatment system could be restored to working
order.
Wet air oxidation and chemical oxidation provide treatment by
oxidizing (or destroying) the BOAT constituents, or those judged to be sim-
ilar, found in these wastes. However, to ensure effective treatment of these
U and P wastes, treatment should include a final carbon adsorption step.
Since these constituents are unquantifiable, and therefore it is not possible
to accurately judge the effectiveness of wet air oxidation and chemical
oxidation, the Agency believes that it is sound engineering judgment to
include a final step of carbon adsorption following the oxidation. This step
will ensure that these organic constituents and the oxidation by-products are
removed from the wastewater matrix. Additionally, spent carbon from treating
these wastewaters becomes a nonwastewater form of this waste (54 Federal
Register 26630-1, June 23, 1989) and thus must be incinerated. EPA believes
that incineration is the most successful method of treatment for a wide
4-19
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variety of organic wastes, and therefore is including carbon adsorption in the
oxidation treatment train to ensure ultimate destruction of the U and P wastes
present in the wastewater.
For wastewaters, in cases where the Agency has treatment performance
data for demonstrated and available wastewater treatment processes and incin-
eration (as measured by total constituent concentration in scrubber water),
the Agency prefers to establish treatment standards based on the wastewater
treatment processes. However, the Agency has determined that wastewaters are
also treated by incineration and does not intend to preclude industry from
continuing this practice. Therefore, EPA is also identifying incineration as
best demonstrated technology for these wastes.
Treatment performance data included in Volume A of the Background
Document for Organic U and P Wastes and Multi-Source Leachate (F039) show
substantial treatment of organic constituents by wet air oxidation, carbon
adsorption, and chemical oxidation. In addition, these technologies are com-
mercially available. Therefore, these technologies are considered to be
"available" treatment technologies for the purpose of establishing BOAT. As
discussed in Section 4.3.1, incineration is also an "available" treatment
technology for treatment of these wastes.
EPA is promulgating the following treatment trains as BOAT for U and
P wastewaters that are not quantifiable. The Agency believes that all three
treatment trains will ensure effective treatment (removal and destruction) of
the constituents of concern. The treatment trains are:
• Chemical oxidation followed by carbon adsorption;
• Wet air oxidation followed by carbon adsorption; and
• Incineration.
Any one of the above three treatment trains may be used to meet the wastewater
treatment standards for wastewater forms of these U and P wastes.
4-20
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Table 4-1
WASTES TESTED BY INCINERATION
Test Number
1
2
3
4
5
6
7
8
9
10
11
12
13
14
Waste Code(s) Tested
K001-Pentachlorophenol
K001-Creosote
K011, K013, K014
K019
K024
K037
K048, K051
K087
K101
K102
F024
K015
D014, D016, P059a,
U127a, U192a
U141a, U028', P020',
U122", U226", U239a,
U080", U220", U166",
U161', U188"
On-Site
Background Engineering
Document Report
Reference Reference
Technology Used Number (s) Number (s)
Rotary Kiln
Rotary Kiln
Rotary Kiln
Rotary Kiln
Rotary Kiln
Rotary Kiln
Fluidized-bed
Rotary Kiln
Rotary Kiln
Rotary Kiln
Rotary Kiln
Liquid Injection
Rotary Kiln
7
7
6
8
9
10
11
12
13
14
15
16
NA •
17
18
19
20
21
22
23, 24
25
26
27
28
29
30
Rotary Kiln
NA
31
NA - Not applicable.
'Commercial chemical products were used in these test burns as surrogates
for these wastes.
4-21
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5.0 DETERMINATION OF BOAT TREATMENT STANDARDS AS METHODS OF TREATMENT
EPA was unable to develop and promulgate concentration-based treat-
ment standards for.the U and P wastes covered in this document due to dif-
ficulties in either (1) quantifying the particular U or P waste constituent in
hazardous waste matrices; or (2) applying the U and P waste treatment standard
calculation methodology to the available treatment data. By grouping these U
and P wastes into treatability groups along with U and P wastes that are
amenable to treatment standard quantification, and then documenting successful
treatment of the quantifiable U and P constituents, the Agency determined that
these same treatment technologies could successfully treat the unquantifiable
U and P constituents. As a result, EPA is setting these methods of treatment
as BDAT treatment standards for the U and P waste codes covered in this
volume.
The methods of treatment specified as the treatment standards for
the U and P wastes covered in this volume are.presented in Table 5-1 (at the
end of this section). Incineration has been identified as BDAT for nonwaste-
water forms of these wastes. In addition, fuel substitution has been identi-
fied as BDAT for nonwastewater forms of the unquantifiable U and P wastes that
contain only carbon, hydrogen, and/or oxygen in their chemical structure. Wet
air oxidation followed by carbon adsorption, chemical oxidation followed by
carbon adsorption, and incineration are treatment technologies judged to be of
equivalent merit in treating U and P wastewaters, and therefore have been
identified as BDAT for wastewater forms of these wastes. Any one of the three
technologies may be used to meet the wastewater treatment standard for the
wastewater forms of the U and P wastes covered in this document.
Methods of treatment are being promulgated as the BDAT treatment
standards for the nonwastewater forms of several U and P wastes, U003, U038,
U057, U073, U093, and U168, that are amenable to quantification in wastewater
matrices (see Table 1-1). This change has been made based on information
submitted by a commenter representing the hazardous waste treatment industry.
The commenter reported such substantial problems, such as drastic detection
limit discrepancies and extreme matrix spike recoveries, in analyzing these
wastes in incinerator ash, that EPA believes that these analytes belong in the
category of those constituents not amenable to quantification.
5-1
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Table 5-1
BOAT TREATMENT STANDARDS FOR NONANALYZABLE U & P WASTE CODES
Uastewater
Nonwastewater
Regulated Constituent
Warfarin (>0.3%)
1-Acetyl-2-thiourea
Acrolein
AUyl alcohol
5-Aminomethyl-3-isoxazolol
4 - Am i nopy r i d i ne
Thiophenol (Benzenethiol)
Bis(chloromethyl)ether
Bromoacetone
Brucine
Carbon disulfide
Chloroacetaldehyde
1-(o-Chlorophenyt )thiourea
3-Chloropropionitri le
Benzyl chloride
2-Cyclohexyl-4,6-dinitrophenol
Epinephrine
Thiofanox
a 1 pha , a Ipha-D imethylphenethy larnine
4,6-Oinitro-o-cresol salts
2,4-Dithiobiuret
Aziridine
Fluoroacetamide
Fluoroacetic acid, sodium salt
Isocyanic acid, methyl ester
Methomyl
2-Methylaziridine
Methyl lactonitrile
Aldicarb
1-Naphthyt-2-thiourea
Nicotine and salts
N-Ni trosodimethylamine
N-Ni trosomethylvinylamine
Endothall
N-Phenylthiourea
Phosgene
Propargyl alcohol
Strychnine and salts
Thiosemicarbazide
T r i ch I oromethaneth i o I
Acetaldehyde
Acetonitri le
Acetyl chloride
Acrylantide
Acrylic acid
Mitomycin C
waste
Code
P001
P002
P003
POOS
P007
POOS
P014
P016
P017
P018
P022
P023
P026
P027
P028
P034
P042
P045
P046
P047
P049
P054
P057
P058
P064
P066
P067
P069
P070
P072
POTS
P082
P084
P088
P093
P095
P102
P108
P116
P118
U001
U003
U006
U007
U008
U010
Document
B
B
A
B
B
B
B
B
B
B
A
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
A
B
B
B
B
B
B
B
B
B
A
B
A
B
B
Standard (mg/l) *
BDAT
BOAT
0.29
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
0.014
BDAT
BOAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BOAT
BDAT
BDAT
BDAT
BDAT
BDAT
0.40
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
0.17
BDAT
1.0
BDAT
BOAT
Document
B
B
B
B
B
B
B
B
B
B
B
B
8
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
8
B
B
B
Standard (mg/kg) **
BDAT-FS
BOAT
BDAT-FS
BDAT-FS
BDAT
BDAT
BDAT
BDAT
BOAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT .
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT-FS
BDAT
BDAT
BDAT-FS
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT-FS
BDAT
* BOAT for uastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
** BDAT for nonwastewaters is incineration. Fuel substitution is also BOAT for the waste codes marked as BDAT-FS.
5-2
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Table 5-1 (Continued)
BOAT TREATMENT STANDARDS FOR NONANALYZABLE U & P WASTE CODES
Uasteuater
Nonwastewater
Regulated Constituent
Ami trole
Auramine
Azaserine
Benz(c)acridine
Benzal chloride
Benzene sulfonyl chloride
Benzidine
Chtornaphazine
Carbonyl fluoride
Trichloroacetaldehyde (Chloral)
ChlorambucU
Chlorobenzilate
1-Chloro-2,3-epoxypropane (Epichlorohydrin)
2-Chloroethyl vinyl ether
Chloromethyl methyl ether
4-Chloro-o-toluidine hydrochloride
Crotonaldehyde
Cumene
Cyclohexanc
Cyclohexanone
Daunomycin
Diallate
1 , 2 , 7 , 8 - D i benzopy rene
3,3' -Dichlorobenzidine
cis-1 ,4-Dichloro-2-biitene
trans-1 ,4-Dichloro-2-butene
1 ,2:3,4-Diepoxybutane
Oiethylstilbestrol
Dihydrosafrole
3,3' -Dimethoxybenzidine
Dimethylamine
p-Dimethylaminoazobenzene
7, 12-Dimethyt benz(a)anthracene
3,3'-Oimethylbenzidine
Dimethylcarbamoyl chloride
Dipropylamine
Ethyl acrylate
Ethylene bis-dithiocarbamic acid
Ethylene thiourea
Ethyl methanesulfonate
Formaldehyde
Formic acid
Furan
Furfural
Glycidylaldehyde
waste
Code
U011
U014
U015
U016
U017
U020
U021
U026
U033
U034
U035
U038
U041
U042
U046
U049
U053
U055
U056
U057
U059
U062
U064
U073
U074
U074
U085
UOS9
U090
U091
U092
U093
U094
U095
U097
U110
U113
U114
U116
U119
U122
U123
U124
U125
U126
Document
B
B
B
B
A
B
B
B
B
B
B
A
B
A
B
B
B
B
B
A
B
B
B
A
A
A
B
B
B
A
B
A
B
B
B
B
B
B
B
B
B
B
B
B
B
Standard (nig/ 1) *
BOAT
BOAT
BOAT
BDAT
0.055
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
0.10
BDAT
0.057
BDAT
BDAT
BDAT
BDAT
BDAT
0.36
BDAT
BDAT
BDAT
0.13
0.036
0.036
BDAT
BDAT
BDAT
0.13
BDAT
0.13
BDAT
BDAT
BDAT
BDAT
BDAT
BOAT
BDAT
BDAT
BOAT
BDAT
BDAT
BOAT
BDAT
Document
B
B
B
B
B
B
B
8
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
B
8
B
B
B
B
B
B
B
B
B
B
Standard (mg/kg) **
BDAT
BDAT
BDAT
BDAT-FS
BDAT •
BDAT
BDAT
BOAT
BDAT
BDAT
BDAT
BOAT
BDAT
BDAT
BDAT
BOAT
BDAT-FS
BDAT-FS
BDAT-FS
BDAT-FS
BDAT
BDAT
BDAT-FS
BDAT
BDAT
BDAT
BDAT-FS
BOAT
BDAT
BDAT
BDAT
BDAT
BDAT-FS
BDAT
BDAT
BDAT
BDAT-FS
BDAT
BOAT
BDAT
BDAT-FS
BDAT-FS
BDAT-FS
BDAT-FS
BDAT-FS
* BOAT for wastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
** BOAT for nonwastewaters is incineration. Fuel substitution is also BDAT for the waste codes marked as BDAT-FS.
5-3
-------
Table 5-1 (Continued)
BOAT TREATMENT STANDARDS FOR NONANALYZABLE U & P WASTE CODES
Regulated Constituent
Uastewater
Waste
Code Document Standard (mg/l) *
Nonwastewater
Document Standard (mg/kg) **
Hexachlorophene U132 B
Lasiocarpine U143 8
Maleic anhydride UU7 8
Maleic hydrazide U148 B
Malononitrile U149 B
Melphalan U150 B
Methanethiol U153 B
Methanot U154 A
Methyl chlorocarbonate U156 B
N-Methyl-N-nitro-N-nitrosoguanidine U163 B
MethylthiouraciI U164 B
1,4-Naphthoquinone U166 B
1-Naphthylamine U167 B
2-Naphthylamine U16S A
2-Nitropropane U171 B
N-Nitrosodiethanolamine U173 B
N-Nitroso-N-ethylurea U176 B
N-Nitroso-N-methylurea U177 B
N-Nitroso-N-methylurethane U178 B
Paraldehyde U182 B
Pentachloroethane U184 B
1,3-Pentadiene U186 B
2-Picoline U191 B
1,3-Propane sultone U193 B
n-Propylamine U194 B
p-Benzoquinone U197 B
Reserpine U200 B
Resorcinol U201 B
Saccharin and salts • U202 B
Streptozotocin U206 B
Tetrahydrofuran U213 B
Thioacetamide U218 B
Thiourea U219 B
o-Toluidine hydrochloride U222 B
sym-Trinitrobenzene U234 B
Trypan blue U236 B
Uracil mustard U237 B
Ethyl carbamate U238 B
2,4-Dichlorophenoxyacetic salts and esters U240 B
Thiram U244 B
Warfarin (<0.3%) U248 B
BDAT
BOAT
BDAT
BDAT
BDAT
BDAT
BDAT
5.6
BDAT
BDAT
BOAT
BDAT
BDAT
0.52
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT-FS
BDAT
BDAT
BDAT
BDAT
BDAT-FS
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT-FS
BDAT
BDAT-FS
BDAT
BDAT
BDAT
BDAT-FS
BDAT
BDAT-FS
BDAT
BDAT
BDAT-FS
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT-FS
* BDAT for wastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
** BDAT for nonwastewaters is incineration. Fuel substitution is also BDAT for the wastes codes marked as BDAT-FS.
5-4
-------
6.0 ACKNOWLEDGEMENTS
This background document was prepared for the U.S. Environmental
Protection Agency, Office of Solid Waste, by Radian Corporation under Contract
No. 68-W9-0072. This document was prepared under the direction of Richard
Kinch, Acting Chief, Waste Treatment Branch; Larry Rosengrant, Section Head,
Treatment Technology Section; Jerry Vorbach, Project Officer; and Lisa Jones,
Project Manager. Steve Silverman served as EPA legal advisor.
The following personnel from Radian Corporation were involved in
preparing this document: John Williams, Program Manager; Mary Willett,
Project Director; and the Radian engineering team, Chrisanti Haretos, John
Horstman, Colleen Kane, Wendy Rovansek, and Doug Spengel.
6-1
-------
7.0 REFERENCES
1. USEPA. 1988. U.S. Environmental Protection Agency, Office of Solid
Waste. Methodology for Developing Treatment Standards. Washington,
D.C.: U.S.'Environmental Protection Agency.
2. American Public Health Association, American Water Works Association, and
the Water Pollution Control Federation. 1985. Standard Methods for the
Examination of Water and Wastewater. Sixteenth Edition. Washington,
D.C.: American Public Health Association.
3. USEPA. 1988. U.S. Environmental Protection Agency. Treatment Tech-
nology Background Document. Washington, D.C.: U.S. Environmental
Protection Agency.
4. USEPA. 1986. U.S. Environmental Protection Agency. National Survey of
Hazardous Waste Treatment. Storage. Disposal. Recycling Facilities.
Washington, D.C.: U.S. Environmental Protection Agency.
5. USEPA. 1989. U.S. Environmental Protection Agency. Water Engineering
Research Laboratory (WERL) Treatabilitv DataBase. Cincinnati, Ohio.
6. USEPA. 1989. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BOAT) Background Document
for K011. K013. and K014 Wastes. Washington, D.C.: U.S. Environmental
Protection Agency.
7. USEPA. 1988. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BOAT) Background Document
for K001 Waste. Washington, D. C.: U.S. Environmental Protection
Agency.
8. USEPA. 1988. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BOAT) Background Document
for K016. K018. K019. K020. and K030. Washington, D. C.: U.S. Environ-
mental Protection Agency.
9. USEPA. 1988. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BOAT) Background Docu-
ment for K024 Waste. Washington, D. C.: U.S. Environmental Protection
Agency.
10. USEPA. 1988. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BOAT) Background Document
for K037 Waste. Washington, D. C.: U.S. Environmental Protection
Agency.
11. USEPA. 1988. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BOAT) Background Document
for K048-K052 Waste. Washington, D. C.: U.S. Environmental Protection
Agency.
7-1
-------
12. USEPA. 1988. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BOAT) Background Document
for K087 Waste. Washington, D. C.: U.S. Environmental Protection
Agency.
13. USEPA. 1988. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BOAT) Background Document
for K101 and K102. Low Arsenic Subcategory. Washington, D. C.: U.S.
Environmental Protection Agency.
14. USEPA. 1988. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BOAT) Background Document
for F024 Waste. Washington, D. C.: U.S. Environmental Protection
Agency.
15. USEPA. 1988. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BOAT) Background Document
for K015 Waste. Washington, D. C.:. U.S. Environmental Protection
Agency.
16. USEPA. 1987. U.S. Environmental Protection Agency. Onsite Engineering
Report of Treatment Technology Performance and Operation for Incineration
of KOOl-Pentachlorophenol (PGP) Waste at the U.S. Environmental Protec-
tion Agency Combustion Research Facility. November 12, 1987. Washing-
ton, D.C.: U.S. Environmental Protection Agency.
•17. USEPA. 1987. U.S. Environmental Protection Agency. Onsite Engineering
Report of Treatment Performance and Operation for Incineration of K001-
Creosote Waste at the U.S. Environmental Protection Agency Combustion
Research Facility. November 23, 1987. Washington, D.C.: U.S. Environ-
mental Protection Agency.
18. USEPA. 1987. U.S.-Environmental Protection Agency. Onsite Engineering
Report of Treatment Performance and Operation for Incineration of
K011/K013/K014 Sludge at the John Zink Test Facility. November 2, 1987.
Washington, D.C.: U.S. Environmental Protection Agency.
19. USEPA. 1988. U.S. Environmental Protection Agency. Non-confidential
Version of the Onsite Engineering Report of Treatment Technology Perfor-
mance and Operation for Rollins Environmental Services (TX) Inc.. Deer
Park. Texas. March 11, 1988. Washington, D.C.: U.S. Environmental
Protection Agency.
20. USEPA. 1987. U.S. Environmental Protection Agency. Onsite Engineering
Report of Treatment Technology Performance and Operation: Incineration
of K024 Waste at the U.S. Environmental Protection Agency Combustion
Research Facility. Washington, D.C.: U.S. Environmental Protection
Agency.
7-2
-------
21. USEPA. 1987. U.S. Environmental Protection Agency. Onsite Engineering
Report oIT Treatment Technology Performance and Operation for Incineration
of K037 Waste at the Combustion Research Facility. November 16, 1987.
Washington, D.C.: U.S. Environmental Protection Agency.
22. USEPA. 1988. U.S. Environmental Protection Agency. Onsite Engineering
Report of Treatment Technology Performance and Operation for Amoco Oil
Company. Whiting. Indiana. February 29, 1988. Washington, D.C.: U.S.
Environmental Protection Agency.
23. USEPA. 1988. Onsite Engineering Report of Treatment Technology Perfor-
mance and Operation for Amoco Oil Company. Whiting. Indiana. July 15,
1988. Washington, D.C.: U.S. Environmental Protection Agency.
24. USEPA. 1988. U.S. Environmental Protection Agency. Onsite Engineering
Report of Treatment Technology Performance and Operation for Incineration
of K087 Waste at the Combustion Research Facility. Jefferson. Arkansas.
February 22, 1988. Washington, D.C.: U.S. Environmental Protection
Agency.
25. USEPA. 1988. U.S. Environmental Protection Agency. Onsite Engineering
Report for John Zink Company for K101. April 25, 1988. Washington,
D.C.: U.S. Environmental Protection Agency.
26. USEPA. 1988. U.S. Environmental Protection Agency. Onsite Engineering
Report for John Zink Company for K102. April 25, 1988. Washington,
D.C.: U.S. Environmental Protection Agency.
27. USEPA. 1988. U.S. Environmental Protection Agency. Onsite Engineering
Report of Treatment Technology Performance and Operation for Incineration
for ENSCO. El Dorado. Arkansas. December, 1988. Washington, D.C.: U.S.
Environmental Protection Agency.
28. USEPA. 1987. U.S. Environmental Protection Agency. Onsite Engineering
Report of Treatment Performance and Operation for Incineration of K015
Waste at the John Zink Company Test Facility. December 4, 1987.
Washington, D.C.: U.S. Environmental Protection Agency.
19. USEPA. 1989. U.S. Environmental Protection Agency, Office of Solid
Waste. Onsite Engineering report of Treatment Technology Performance and
Operation for John Zink Company. Washington, D. C.: U.S. Environmental
Protection Agency.
30. USEPA. 1989. U.S. Environmental Protection Agency. Onsite Engineering
Report for the Third Thirds Incineration Treatment Test. 1989. Washing-
ton, D.C.: U.S. Environmental Protection Agency.
31. Verschueren, K., ed. 1983. Handbook of Environmental Data on Organic
Chemicals. 2nd ed. New York, New York: Van Nostrand Reinhold Company.
32. Windholz, M., ed. 1983. The Merck Index. 10th ed. Rahway, New Jersey:
Merck & Company.
7-3
-------
33. SRI International. 1987. 1987 Directory of Chemical Producers - United
States of America. Menlo Park, California: SRI International.
34. SRI International. 1988. 1988 Directory of Chemical Producers - United
States of America. Menlo Park, California: SRI International, pp. 820-
837, 456, 526, 542, 558-560, 574, 582, 679, 783, 839, 916, 927, 933, and
1032.
7-4
-------
APPENDIX A
U AND P WASTE GENERATOR INFORMATION
A-l
-------
UASTECOOE NAME
TABLE A-1
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
SSS33E«SSSSSSSSSSSSSS«SSSS&SSSSSS?=SSSS=SC==S
INDUSTRY
USE (a)
U001 Acetaldehyde
>
U002
Acetone
U003
Acetoni trite
Food Processing
Plastics and Resins Manufacturing
Dyes and Pigments Manufacturing
Cosnetics and Fragrances
Organic Chemical Manufacturing
Agricultural Chemical Manufacturing
Film
Fiber Manufacturing
Electronic Components Manufacturing
Paint Manufacturing
Plastics and Resins Manufacturing
Pharmaceutical Manufacturing
Explosives
Organic Chemical Manufacturing
Printing
Synthetic flavor ingredient
Manufacture of resins and plastics .
Manufacture of dyes
Manufacture of perfumes
Chemical intermediate for pyridine, pyridine bases.
pentaerythritol. 1,3-butylene glycot, chloral.
glyoxal, crotonaldehyde, acetaldehyde 1,1-dimethylhydrazone.
acetaldehyde cyanohydrin. acetaldehyde oxime.
paraldehyde, metaldehyde, halogenated derivatives.
acetaldol, sodium sulphite addition product,
acetic anhydride, ethylidene diacetate, alkyi amine.
ethyl acetate, isobutyl acetate, lactic acid,
acetic acid, peracetic acid
Monomer for polyacetaldehyde and comonomer for polymers
Chemical intermediate for pesticides
Chemical intermediate for photographic formulations
Alcohol denaturant
Spinning solvent for cellulose acetate
Cleaning and drying electronic parts
Solvent for paints, varnishes, lacquers
Solvent for resins and plastics
Solvent in the manufacture of Pharmaceuticals
Manufacture of smokeless powder
Solvent for fats, oils waxes
Manufacture of mesityl oxide, acetic acid, diacetone,
alcohol, chloroform, iodoform, bromoform, acetic anhydride
Chemical intermediate for methacrylates,
methyl isobutyl ketone, methyl isobutyl carbinol,
bisphenol A, isophorone
Solvent for printing inks
Deodorizers for specialty naphthas
Solvent for inorganic compounds
Specialty solvent
-------
UASTECODE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U003 (continued)
T
LJ
UOOA Acetophenone
Food Processing
Metal Finishing
Dyes and Pigments
U005
2,3-Acetylaminofluorene
Organic Chemicals
Pesticide Manufacturing
Petroleoun Refining
Pharmaceuticals/Medicine
Dyes and Pigments Manufacturing
Plastics and Resins Manufacturing
Organic Chemical Manufacturing
Food Processing
Cosmetics and Fragrances
tobacco
Construction
Polar solvent
Starting Material for nany nitrogen-containing compounds
RecrystalUsing steroids
Extraction of fatty acids from fish liver,animal&veg. oils
Non-aqueous solvent for inorganic salts
Brightners for Metal
Chemical intermediate -gaoma-naphthaleneacetic acid.etc.
In miscellaneous operations for cyanide dyes
Medium for promoting ionization
In electrodinetic transducers and angular accelerometers
Solvent in non-aqueous titrations
Starting material thiamine.acetamidine, etc.
Solvent in hydrocarbon extraction processes
Chemical intermediate-pesticide manufacture
Coloring matter from some petroleum hydrocarbons
Separation of alkaloids from tissue extraction
Solvent for dyes
Specialty solvent for plastics and resins
Chemical intermediate for the odorant.
ethyl methyl phenylglycidate, the riot
control agent, 2-chloroacetophenone.
2-bromoacetophenone, for dyes. 3-nitroacetophenone
Flavoring agent in non-alcoholic beverages,
ice cream, candy, baked goods, gelatins,
and puddings
Fragrance ingredient in soaps, detergents,
creams, lotions, and perfumes
flavoring in tobacco
In coal tar for road surfaces and roofing mater liils
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
UASTECOOE NAME
INDUSTRY
USE (a)
UOOS (continued)
U006 Acetyl chloride
U007 Acrylanide
Pharmaceutical
Organic Chemicals Manufacturing
Medicine
Laboratory
Specialty Chemical
Dyes and Pigments
Pharmaceuticals
Agricultural Chemicals
Mining
Binder for electrodes in aluninun reduction process
Treatoient of skin disorders .
Waterproofing
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chenicals
Catalyst in chlorination of acetic acid
Production of acetamide
Production of acetyl sulfide
Testing for cholesterol
Determination of water in inorganic liquid
Chemical intermediate acetanilide preparation
Chemical intermediate acetophenone reparation
Qualitative organic analysis
Synthesis of dienestrol diacetate
Production of thioacetic acid
Chlorinating agent inorganic compounds and triarylcarbinots
Acetylating agent
Manufacture dyestuffs
Pharmaceuticals manufacturing
Sewage and waste treatment
Polyacrylamides manufacturing
Flocculating aid for precip. suspended solids from aqueous systems
Flocculants
Cross-1 ink ing agent
In soil-conditioning agents
In ore processing, adhesivcs
Chemical intermediate in polyacrylamides
-------
CSSSSSSBSSSSSSEB
UASTECCOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U007 (continued)
U008 Acrylic acid
Ln
U009 Acrylonitrile
Paper and Textile
Building I Construction
Dyes and Pigments
Organic Chemicals Manufacturing
Textiles
Organic Chemical Manufacturing
Textiles
Cleaning Products
Leather and Tanning
Plastics and Resins Manufacturing
Agricultural Chemicals
Plastics
Water Treatment
Paper and textile sizes
Construction of dam foundations ( tunnels '
Synthesis of dyes
Reactive monomer I interned, organic chemicals production
Permanent press fabrics
Chemical intermediate for ethyl acrylate, n-butyl acrylate,
methyl acrylate. 2-ethylhexyl acrylate, acrylate hydoxyethyl
Monomer for polyacrylic acid and salts
Comonomer with acrylamide for polymers used as polymers
Surface coatings
Textile applications
Manufacture of polishes
Manufacture of leather
Production of Mater soluble resins and salts
Chemical intermediate antioxidants synthesis
In co-polymers with styrene and butadiene
Chemical intermediate surface-active agents
Commoner for starch/acrylonitrile copolymers
Finigant for mills and commodities (former use)
Synthetic soil blocks
Chemical intermediate for acrylamidoaminoethane sulfonic acid
Elastomers for hoses, gaskets & protective clothing
Chemical intermediate for fatty aminopropylamine & derivs.
Modifier for natural polymers
Comonomer for nitrile elastomers
In flocculants for water and waste treatment
Comonomer (or alkyd/ucrytonitrile copolymers
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
UASTECODE NAME
INDUSTRY
USE (a)
U009 (continued)
U010 Hitomycin C
U011 Amitrole
Agricultural Chemicals
Plastics
Paper Manufacturing
Petroleui
Adhesive and Sealants
Bottling
Dyes and Pigments
Textiles and Fibers
Food Processing
Pesticide Manufacturing
Pharmaceuticals
Plastics and Resins
Rubber
Medicine
Agricultural Chemicals
Photography
U012 Aniline
Organic synthesis to introd. cyanoethyl group
Comonomer with styrene for urethane polyether polyols ,
Chemical intermediate for adiponitrile & aeryIamide
Fumigating stored tobacco
In plastics for appliances.automobile interior,boats.RV bodies,etc.
Retention aids in papermaking t flotation processes
Comonomer for barrier resins
Mobility control agents in crude oil recovery
Comonomer for acrylic acid
No information available
Bottles for soft drinks (use discontinued)
Chemical intermediate dyes
To improve the dye and working properties of acrylic fibers
Comonomer for acrylic and modacrylic fibers
Manufacture of blankets,draperies,upholstery,syn. furs,wigs
In apparel.carpeting,home furnishing,sandbags,filter cloths,etc.
Cyanoethylation of cotton
Applied to mi 11 ing,baking,food processing machinery
In insecticides
Pesticide funigant for stored grain (former use)
Chemical intermediate Pharmaceuticals
Chemical intermediate for glutethimide (sedative)
No information available
Manufacturing nitrite rubbers
Medication
Herbicide for non-crop uses (aquatics, hardwood nursery stock)
Cotton defoliant
Herbicide for food crops (former use)
Plant growth regulator
Reagent in photography
Chemical intermediate for substituted aniline salts
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U012
(continued)
Plastics and Resins
Explosives
Agricultural Chemicals
Cosoet ics/fragrances
Dyes and Pigments
Photography
Food Processing
Leather and Tanning
Organic Chemicals
Plastics and Resins Manufacturing
Paper Manufacturing
Pesticides Manufacturing
Isocyanate synthesis
Catalyst and stabilizer for hydrogen peroxide synthesis |
Chemical intermediate for 4-Anilinophenol
Solvent
Vulcanization accelerator
Chemical intermediate for hydroquinone
Cellulose as • precursor
Manufacture shoe blacks
Azeotropic agent in manufact. of anhydrous hydrazine
Chemical intermediate for methylenediisocyanate
Manufacture isocyanates for urethane foam
Manufacture explosives
Manufacture of teryl t optical whitening agents
Chemical intermediate for corrosion inhibitors
Manufacture herbicides, fungicides
Manufacture perfumes
Chenical intermediate for dyes I pigments
In situ dyeing agent
Manufacture photographic chemicals
In synthesis of intermediates for artificial sweeteners
Component of skin stains
Manufacture of rigid polyurethanes
Component of lacquers & wood stains
Chemical intermediate for specialty resins & cyclohexylamine
Manufacture resins.varnishes
Paint removers
Analytical reagent in paper chemistry
Chemical intermediate for pesticides
-------
UASTECQOE HAKE
TABLE A-1 (Continued)
INDUSTRIAL USE Of U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U012 (continued)
U014 Auramine
CD
U015 Azaserine
U016 Benz(c)acridine
U017 Benzal chloride
U01B Benz(a)anthracene
U019 Benzene
Petroleum Refining
Pharmaceutical Manufacturing
Printing
Rubber
Dyes and Pigments
Pharmaceuticals
Agricultural Chemicals
Medicine
Pharmaceuticals/Medicine
Construction
Pharmaceutical
Organic Chemicals Manufacturing
Chemical Research
Specialty Chemical
Dyes and Pigments Manufacturing
Chemical Research
Organic Chemicals Manufacturing
Medicine
Dyes and Pigments
No information available
Chemical intermediate for Pharmaceuticals
Printing inks,cloth marking inks
Chemical intermediate for rubber processing
Dye for lacquers.pen inks.carbon papers.typewriter ribbons
Food dye in some countries
Dye for paper,cardboard,textites.leather,oils,uaxes,alcoholic solvents
Preparation of solvent yellow 34
Smoke dye
Antiseptic
fungicide
Research chemical
Antineoplastic agent, antibiotic, abortifacient, antifungal
In coal tar for road surfaces and roofing materials
Binder for electrodes in aluminum reduction process
Treatment of skin disorders
Waterproofing
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
Research chemical
Preparation of benzoyl chloride
Manufacture of cimamic acid
Chemical intermediate for benzaldehyde
In dyes
No commercial use in U.S.
Manufacture of styrenes, phenols, cyclohexanes
Manufacture of medicinal chemicals
Manufacture of dyes
Manufacture of artificial leather, linoleum, oil cloth
-------
UASTECODE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE Of U AND P CHEMICAL PRODUCTS
=£S = 38=S:£333S3S=S3S=&S3SXSS3Z3SSS333333SSS=S3
INDUSTRY
USE (a)
U019 (continued)
U020 Benzenesulfonyl chloride
I U021 Benzidine
us
U022 Benzo(a)pyrene
Plastics and Resins
Soap
Pesticide
Specialty Chemical
Pesticide
Laboratory
Food
Paper
Sugar
Medicine
Laboratory
Specialty Chemical
Printing
Plastics
Dyes and Pigments
Rubber
Construction
Pharmaceutical
Manufacture of airplane dopes
Manufacture of varnishes and lacquers
Solvent for waxes, resins, oils, etc.
Manufacture of detergents
Manufacture of pesticides
Chemical intermediate for benzonitrile
Chemical intermediate for thiophenol
Chemical intermediate for glybuzole
Chemical intermediate for benzene sulfonamides
Chemical intermediate for H-2-chloroethyl amides
Esters formerly used as insecticides.miticides.fenson acaricide
Reagent for Freiedl-Crafts sulfemulation
Reagent for hydrogen peroxide in milk
Production of security paper
Spray reagent for sugars
Used to verify TLC bands attributed to blood (former use)
Stain in microscopy
Lab agent to detect cyanide & sulfate
Quantitative determination of nicotine
Organic synthesis
Used in security printing
Liquification meadurement
Manufacture of plastic films
Chemical intermediate for AZO dyes
Stiffening agent in rubber compounding
In coal tar for road surfaces and roofing materials
Binder for electrodes in aluminum reduction process
Treatment of skin disorders
Waterproof ing
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AMD P CHEMICAL PRODUCTS
UASTECOOE NAME
INDUSTRY
USE (a)
U022 (continued)
U024 Bis(2-chloroethoxy)methane
U02S Oichlorocthyl ether
U026 Chloronaphazine
U027 bi»-(2-chloroei80propyl)ether
U029 Methyl bromide
Organic Chemicals Manufacturing
Medical Research
Rubber
Petroleui Refining
Agricultural Chemicals
Organic Chemicals
Pesticides
Pharmaceuticals
Textiles
Lubricant
Medicine
Textiles
food
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
Positive control for mutagenicity and carcinogenicity studies
Solvent
Chemical intermediate for polysulfide rubber
Scavenge lead deposits in gasoline
Purification of oils
Soil funigant (former use)
Control earworms on corn (former use)
Chemical intermediate t cross-1 inker
Acaricide (former use)
Anesthetic
Scouring of textiles
Used in aerosols
General/selective solvent production lubricating oils
In Kier boiling
Antineoplastic agent (not in U.S.)
Chemical intermediate
In paint and varnish removers
Spotting and cleaning solutions
Solvent for fats, waxes, grease
Textile processing
Food sterilization
Extraction of oils from nuts, seeds, flowers
Fire extinquisher
Refrigerant
In ionization chambers
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
3S~ = SZ*SSSSS£SSSS3SSUVBaSSSSV8ESXSSSSSSSSSSS
INDUSTRY
USE (a)
U029 (continued)
U030 4-Bromophenyl phenyl ether
U031 n-Butyl alcohol
U033
U034
U035
U036
U037
U038
U039
Carbon fluoride
Trichloroacetaldehyde
Chlorambucil
Chlordane
Chlorobenzene
Chlorobenzilate
p-Chloro-m-cresol
Agricultural Chemicals
Dyes and Pigments
Pesticides
Pharnaceuticals
Cheaiical Research
Pharmaceutical Manufacturing
Veterinary Medicine
Furniture Manufacturing
Organic Chemical Manufacturing
Petrolem
Pesticides
Medicine
Veterinary Medicine
Pesticide
Pesticide
Pest iride
Degreesing wool
Ftmugant for soil .
Solvent in aniline dyes
Insect and rodent control in space and commodity fumigations
Nethylating agent
Not in U.S.
Manufacture of Pharmaceuticals
Bactericide
Solvent for surface coatings
Chemical intermediate for ethylene glycol,
monobutyl ethers, glycol ethers, plasticizers.
n-butyl acetate, n-butyl acrylate, butylamines,
2,4-0 esters
Dehydrating agent
Solvent for vegetable oils and alkaloids
Chemical intermediate in organic synthesis
Induce swelling of starch granules
Spraying and pouring of polyurethanes
Chemical intermediate for chloral hydrate
Chemical intermediate for herbicide trichloroacetic acid
Intermediate in manufacture of DDT.methoxychlor.ODVP.naled,trichlorofon
Not produced in U.S. (imported from U.K.)
Antineoplastic agent: Ieukemia.Hodgkins disease,malignant lymphomas,etc.
Antineoplastic agent
Insecticide
Manufacture of insecticide
Acaricide
External germicide
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
UASTECOOE NAME
INDUSTRY
USE (a)
U041 n-Chloro-2.3-epoxypropane
Plastics and Resins
Paper Manufacturing
Agricultural Chemicals
Optics
Scavenging additive to trichloroethylene
Preparation of condensates with polyfunctional substances '
Chemical intenaediate for glycidyl acrylate and glycidyl methacrylate
Polymer coating Materials in water supply systems
Reactive plasticizer
Comonomer for unmodified epoxy resins
Preparation of ion exchange resins,elastomers.solvents,plasticizers
Solvent for natural t synthetic resins.guns.cellulose esters & ethers
Solvent for lacquers.cement for celluloid
Solvent for paints,varnishes.nail enamels
Comonomer for polyamide-epichlorohydrin resins
Raw material for epoxy & phenoxy resins
Heat stabilizer for plastics
High wet-strength resins for paper industry
Chemical intermediate for polythiols
Cross-linking agent for hydrogel sheet for temporary wound dressing
Stabilizer in chlorine-containing material
Intermediate in the production of beta-blocker, aryloxypropanolamine
Hair products
In formation of polythioaldane carboxylic acid oligomers in hair shampoo
Cross-1 inking agent for cyclodextrins
Production of poly(oxlyalkylene)ether derivatives
Co-stabilizer to enhance mixed-metal combination
Cross-linking agent in microencapsulation
Chemical intermediate for alkyl glyceryl ether sulfonate surfactants
Raw material for glycerol and glycidol derivatives
Chemical intermediate for glycidyl ethers,glycerin
Monomer or comonomer in epichlorohydrin elastomers
Sporicide
Chemical interuicduitc for quaternary aiiinonium salts
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U041 (continued)
U042 2-Chloroethyl vinyl ether
U043 Vinyl chloride
OJ
U044 Chloroform
U045 Chloronethane
Pesticides
Pharmaceuticals
Rubber
Fibers
Pharmaceuticals
Plastics
Textiles and Fibers
Adhesive and Sealants Industry
Automobile Manufacturing
Building and Construction
Electrical Equipment
Glass
Packaging
Paper
Plastics
Rubber
Rubber
Agricultural Chemicals
Insect fumigant
Stable insecticide emulsion
Manufacture of Pharmaceuticals '
Curing propylene-based rubbers
Copolymer with ethyl aeryI ate to produce acrylic elastomer
Chenical intermediate for anesthetics, sedatives, I cellulose ethers
Monomer/comonamer for polyvinyl chloride
Monomer and cononomer for fibers
Chenical intermediate
Plastic adhesive
No information available
Production vinyl asbestos floor tiles
Insulation for electrical wire,cable,piping
No information available
Food, medical supplies
No information available
Organic synthesis of plastics
No information available
Solvent for fats, oils, rubber, alkaloids, waxes, resins
Cleaning agent
Fire extinguishers
Manufacturing of methyl cellulose
Manufacturing of tetramethylead
Methylat ing agent
Propellent
Herbicide
Manufacturing of fumganib
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND f CHEMICAL PRODUCTS
CXSSSSS52=SSSSSSSSS
INDUSTRY
USE (a)
UOA5 (continued)
Pharmaceuticals
Plastics
Rubber
Steel
Timber
UOA6 Chloromethyl methyl ether
U047 2-Chloronaphthalene
UOA8 2-Chlorophenol
U049 4-Chloro-o-toluidine hydrochloride Dyes and Pigments
UOSO Chrysene
U051
Creosote
Construction
Pharmaceutical
Organic Chemicals Manufacturing
Chemical Research
Medicine
Anesthetic
Foaming agent
Manufacturing of synthetic rubbers
Solvent and diluent in butyl rubber production
Production of silicons resins and rubbers
Foaming agent stainless steel
Processing of timber products
Extractant for oils, fats and resins
Fluid for thermometric t thermostatic equipment
Chemical intermediate
Terminates polymerization of bakelite polysulfone
Industrial polymers
Alkylating agent t solvent in manufacture of water repellents
Intermediate in synthesis of chioromethylated compound
Preparation of ion-exchange resins
Chemical intermediate for dodecylbenzyl chloride
Ho information available
Ho information available
Produce AZO dyes for cotton,siIk.acetate,nylon
Chemical intermediate for dyes
In coal tar for road surfaces and roofing materials
Binder for electrodes in aluminum reduction process
Treatment of skin disorders
Waterproofing
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
Research chemical
Antipyretic, styptic, astringent
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
UASTECOOE NAME
INDUSTRY
USE (a)
U051 (continued)
U052 Cresols
U053 Crotonaldehyde
U055 Cunene (Isopropylbenzene)
U056 Cyclohexane
U057
Cyclohexanone
Plastics and Resins
Veterinary Medicine
Pharmaceutical
Wood Preserving
Agricultural Chemicals
Organic Chemical Manufacturing
Plastics and Resins Manufacturing
Tire
Petroleum Refining
Agricultural Chemical Manufacturing
Military
Organic Chemical Manufacturing
Leather and Tanning
Organic Chemicals Manufacturing
Plastics and Resins
Paint
Laboratories
Organic Chemicals Manufacturing
Petroleum Refining
Organic Chemical Manufacturing
Plastics and Resins Manufacturing
Lubricant for die molds
Waterproof ing agent I
Parasiticide, deodorant
External antiseptic, disinfectant, expectorant, local anesthetic,
gastric sedative
Preservative
Herbicide manufacturing
Chemical intermediate for 2-ethylhexyl alcohol
Solvent for polyvinyl chloride
Preparation of rubber accelerators
Purification of lubricating oils
Manufacture of insecticides
Manufacture of tear gas
Organic synthesis
Leather tanning
Manufacture of phenol, acetone, acetophenone, a-methylstyrene
Solvent for lacquers and resins
Paint and varnish remover
Extraction of essential oils
Molecular weight determination
Manufacture of adipic acid, benzene, cyclohexyl chloride,
nitrocyclohexane, cyclohexanol, cyclohexanone
Manufacture of solid fuel for camp stoves
In fungicidal formulations
• In recrystallization of steroids
Chemical intermediate in synthesis of caprolactam
Solvent for lacquers, wood stains, paint, and varnish removers
-------
UASTECOOE NAME
U063 bibenzo(a,h)anthracene
U06A
1,2,7.8-Dibenzopyrene
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U066
1,2-Oibromo-3-chloropropane
U067 Ethylene dibromide
Construction
Pharmaceutical
Organic Chemicals Manufacturing
Construction
Pharmaceutical
Organic Chemicals Manufacturing
Medical Research
Agricultural Chemicals
Agricultural Chemicals
Plastics and Resins
In coal tar for road surfaces and roofing materials
Binder for electrodes in aluminum reduction process
Treatment of skin disorders
Waterproofing
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
In coal tar for road surfaces and roofing materials
Binder for electrodes in aluminum reduction process
Treatment of skin disorders
Waterproofing
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
Experimental carcinogen
Intermediate in organic synthesis
Commercial preparation for flame retardant
Soil fumigant for pineapple in Hawaii
Quarantine funigant some fruits & veg.
Solvent for resins,gums.waxes
Chemical intermediate and in gauge fluids
Vault fumigation
==============
U057
U059
U060
U061
U062
(continued)
Daunonycin
ODD
DDT
Dial late
Leather and Tanning
Pharmaceuticals
Pesticide
Pesticide
Agricultural Chemicals
Solvent lor polyvinyl chloride and its copolymers
Spot remover and degreaser for leather
Antineoplastic agent, antibiotic (not produced in U.S.)
Nonsystemic contact and stomach insecticide
Monsysteaic contact and stomach insecticide
Sprout inhibitor
Herbicide
-------
ESSSZESSBCSSSSSa
UASTECOOE MANE
TABLE A-1 (Continued)
INDUSTRIAL USE Of U AND f CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U067
(continued)
U068
Dibr
thane
U070
U071
U072
U073
1,2-Dichlorobenzene
1.3-Dichlorobenzene
1,4-DiehIorobenzene
3.3'-Oichlorobenzidine
U074
U075
1.4-Oichloro-2-butene
0 i chlorodi fIuoromethane
Dyes and Pigments
Food Processing
Pesticides
Phsmaceuticats
Timber
Plastics and Resins
Pesticide
Pesticide
Dyes and Pigments
Plastics
Rubber
Organic Chemicals Manufacturing
Pesticide
Health and Safety
Catalyst in preparation of Grignard reagents
Chemical intermediate for vinyl bromide '
Chemical intermediate for dyes
Spot fuaigation Milling machinery
Termite and Japanese beetle control
Insecticidal fuvigant for stored products
Beehive supers
Soil treatment (insects and nematodes)
Chemical intermediate for Pharmaceuticals
Felled log f litigation
Organic synthesis
Gauge fluid
Ingredient of fire-estinquishing fluids
Heavy liquid in solid separations
Solvent for waxes i resins
Fumigant and insecticide
No information available
Manufacture of moth repellent, soil fumigant
Curing agent
Paint and ink formulation
Manufacture of AZO dyes
Chemical intermediate for dyes
Plastic compounding ingredient
Rubber compounding ingredient
Chemical intermediate for hexatnethylenediamine and chloroprene
Nematoe ides and as chemical intermediate
Leak-detecting agent
Refrigerant
-------
VMSTECQOE NANE
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U075 (continued)
CO
Plastics
Adhesive and Sealants Industry
Agricultural Chemicals
Autonobile Manufacturing
Bottle Manufacturing
Cosmetics Manufacturing
Electrical Equipment
Food Processing
Food Processing
Food Service/Restaurant
Medicine
Metals Manufacturing
Organic Chemicals
Paint Manufacturing and Application
Paint Manufacturing and Application
Petroleum Refining
Pharmaceutical Manufacturing
Plastics
U076 1,1-Dichloroethane
Organic Chemicals Manufacturing
Polymerization catalyst
Aerosol propellent
Aerosol propellent
Refrigerant for air conditioning
No information available
Aerosol propellent
Manufacturing electrical insulation and generator windings
Solvent or diluent in funigants for food sterilization
Freezing of foods
Chilling of glasses
Preparation of frozen tissue sections
Copper and aluminum purification
Synthesis of Freons
Used in paints & varnish removers
Aerosol propelIant
Petroleum recovery
Aerosol propelIant
Refrigerant in home & conmercial applications
Used in polymerization process
Aerosol propellent in cleaners
Working fluid for heat pumps and in hydraulic fluids
Foaming agent for surfactants
Foaming agent in fire extinquishers
Water purification
Used in thermal expansion valves
Chemical intermediate for vinyl chloride, 1,1,1- ti ichloi ouih.ine
-------
ssssssssssssssssssssassssssssssssssssssssssssssssss
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AMD P CHEMICAL PRODUCTS
sssssss—sssssss—csasxMmsMssmassssssssssssssss
INDUSTRY
USE (a)
(1077 1.2-Oichtoroethane
U078 1,1-Oichloroethylene
0079 1.2-Dichloroethylene
U080 Nethylene chloride
uoai
U082
U083
U084
U091
2,4-Dichlorophenol
2.6-Dichlorophenol
1,2-Dichloropropane
1,3-Dichloropropene
U085 1.2:3,4-Diepoxybutane
U089 DiethylstiIbestrol
U090 Oihydrosafrole
3,3'-Dimethoxybenzidine
Plastics and Resins
Organic Chemicals Manufacturing
Food Processing
Organic Chemicals Manufacturing
Pesticide
Dry Cleaning
Pesticide
Dry Cleaning
Pesticide
Comnercial Testing Laboratories
Pharmaceuticals/Medicine
Flavor
Cosmetics and Fragrances
Tanning, Paper, Rubber, Textiles
Solvent for fat and oils
Solvent for waxes, gun, resins
Funigant
Intermediate for vinilydene polymer plastics
Solvent for fats, phenol, camphors
Solvent for cellulose acetate
Degrees ing and cleaning fluids
Solvent
Organic synthesis
Systemic herbacide
Oil and fat solvent
In dry cleaning fluids
In degreesing
'Insecticidal funlgant mixtures
Oil and fat solvent
In dry cleaning fluids
In degreasing
Insecticidal fuaigant mixtures
Research chemical
No longer used
Chemical intermediate for piperonyl butoxide (not in U.S.)
Flavoring agent in root beer
Fragrance for cosmetics
Detection of thiocyanates, nitrites, & some metals
Dye
Chemical intermediate in production of 0-dianisidme di isocyanuic-
-------
sssssssssssssscs
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHENICAL PRODUCTS
INDUSTRY
USE (a)
U091
U092
(continued)
Dimethylamine
N>
O
Dyes and Pigments
Dyes and Pigments
Detergents
Pharmaceuticals
Petroleum Refining
Agricultural Chemicals
Textiles
Pesticides
Plastics and Resins
Film
Leather and Tanning
Rubber
U093 p-Dimethylaminoazobenzene
Chemical intermediate in dyes and pigments
Reagent for magnesium
Missile fuel
Dyes
Ion exchange agent
Chemical intermediate for lauryl dimethylamine oxide
Manufacture of detergents
Surfactant
No information available
Antiknock agent in fuels
Gasoline stabilizer
Attract boll weevils
Antioxidants
Dehairing agent
Textile chemicals
Electroplating
Acid gas absorbent
Flotation agent
Pesticide propellant
Chemical intermediate for dimethylformamide.dimethylacetamide
Plasticizer
Rocket propellent
Dimethylamine salt of 2,4-D
Photographic chemical
Tanning
Accelerator in vulcanizing rubber
Not produced or used in U.S.
-------
WASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
===S=SSS=S==SS=SSO
INDUSTRY
USE (a)
U094 7. 12-Dimethylbenz(a)anthracene
U095 3.3'-Dimethylbenzidine
IvJ
U097 Dimethyl carbonyl chloride
U101 2.4-Dimethyl phenol
U105 2.4-Dinitrotoluene
Construction
Pharmaceutical
Organic Chemicals Manufacturing
Medical Research
Dyes and Pigments
Plastics and Resins
Pesticides
Pesticide
Dyes and Pigments
Explosives
Munition
Plastics and Resins
Rubber
U106 2,6-Dinitrotoluene
In coal tar for road surfaces and roofing materials
Binder for electrodes in aluminum reduction process
Treatment of skin disorders
Waterproofing
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
Induces malignant tumors in testing of antineoplastic drugs
Free chlorine in water
Reagent for gold detection
In chlorine test kits t test tapes in clinical laboratories
Chemical intermediate for AZO dyes
Curing agent for urethane resins
Chemical intermediate for parasympathomimetic agents
Pesticide (former use)
Insecticide, fungicide
Chemical intermediate for dyes
Production of toluenediamine (Raraey nickel slurry process)
Chemical intermediate in production of toluene diisocyanate
Added to sensitizing materials in dynamite
Plasticizer in moderate and high explosives
Gelatinizing t waterproofing agent
Explosives intermediate
Modifier for smokeless powders
Plastics manufacture
Rubber chemical
Chemical intermediate tor toluene-2,2-diamine
Synthesis of urethane polymers, flexible £ rigid foams
-------
UASTECODE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U106 (continued)
U108 1,4-Dioxane
to
ro
U110 Dipropylamine
U111 Di-n-propylnitrosanine
U112 Ethyl acetate
Dyes and Pigments
Explosives
Plastics and Resins
Cosmetics and Fragrances
Paint Manufacturing
Paper Processing
Dyes and Pigments Manufacturing
Cleaning Products
Organic Chemical Manufacturing
Plastics and Resins Manufacturing
Agricultural Chemicals
Organic Chemical Manufacturing
Medicine
Food Processing
Plastics and Resins Manufacturing
Printing
Paint Manufacturing
Munitions
Film
In dyes
In synthesis of TNT ,
Gelatinizing and waterproofing agent in explosives '
Surface coatings
Manufacture of cosmetic products
Manufacture of lacquers, paints, varnishes, paint
Solvent in pulping of wood
Wetting and dispersing agent in textile
processing, dye-baths, stain and printing
compositions
Manufacture of cleaning and detergent preparations,
adhesives, fuaigants, emulsions, and polishing
compositions
Solvent for fats, oils, waxes
Solvent for natural and synthetic resins
Purification of perfIuoro-compounds
Chemical intermediate for S-propyl-di-n-propylthiocarbamate
Chemical intermediate for herbicide S-ethyl-di-n-propylthiocarbamate
Research chemical
Organic synthesis
Carminative, antispasmodic, and counter irritant
Component of base sheet (cellophane)
Diluent in inks for marking fruits and vegetables,
synthetic flavoring
Solvent for plastics
Solvent for inks
Solvent for varnishes, lacquers
Manufacture of smokeless powder
Manufacture of photographic films and plates
-------
SS3SSSSS3SSS5SSCSSCSSXB8B;
UASTECQOE NAME
:83S8B38SSSS8S33333 =
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AMD P CHEMICAL PRODUCTS
33SS5S3S3333S33333333S3SS333338BBB8SCS88B38BB8S3S3SS3S333888B88E8S
INDUSTRY
USE (a)
U112
U113
(continued)
Ethyl acrylate
to
CO
U1U
U116
Ethytene bis-dithiocarbamic acid
Ethylene thiourea
U117 Oiethyl ether
Leather and Tanning
Cosmetics and Fragrances
Paint Manufacturing
Textiles
Paper Coating
Cleaning Products
Adhesives and Sealants
Leather and Tanning
Food Processing
Agricultural Chemicals
Agricultural Chemicals
Dyes and Pigments
Pesticides
Pharmaceuticals
Plastics and Resins
Rubber
Organic Chemical Manufacturing
Cosmetics and Fragrances
Explosives
Automotive
Commercial Testing Laboratories
Veterinary Medicine
Manufacture of artificial leather
Manufacture of perfumes and fragrances
Eaulsion polymers for trade sale paints
Textile coating and printing
Paper coatings
Floor finishes
Eaulsion polymers for adhesives and sealants
Leather finishes
Synthetic flavorings
Heavy metal (alts as fungicides
Electroplating baths
Intermediate for antioxidants
Intermediate for fungicides
Intermediate for dyes
Intermediate for insecticides
Intermediate for Pharmaceuticals
Manufacture of synthetic resins
Accelerator for neoprene rubbers
Solvent for waxes, fats, and oils
Reagent for organic synthesis
Chemical intermediate for monoethanolamine, ethylene
Solvent for perfumes
Manufacture of gun powder
Primer for gasoline engines
Extractant of hormones from plant and animal tissues
Inhalation anesthetic, antispasmodic, rubclacient
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
= SSSS = SS = S = SS5SESC
INDUSTRY
USE (a)
U118 Methacrylic acid, ethyl ester
U119 Ethyl methane sulfonate
U120 Fluoranthene
N)
.p-
U121 Fluorotrichloromethane
Plastics and Resins Manufacturing
Cleaning Products
Pharmaceutical Manufacturing
Biochemical Research
Construction
Pharmaceutical
Organic Chemicals Manufacturing
Chemical Research
Agricultural Chemicals
Cosmetic and Fragrance
Electrical Equipment
Food Processing
Organic Chemicals
Paint Manufacturing and Application
Pharmaceuticals
Comononer in acrylic polymers for surface coating resins
Acrylic emulsion polymers for polishes i
Comonomer in denture base material
Not produced in U.S.
In coal tar for road surfaces and roofing materials
Binder for electrodes in aluminum reduction process
Treatment of acute and chronic dermatoses
Waterproofing
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
In lining for steel and ductile iron potable Hater pipes and storage
tanks
Research chemical
Sulfonation solvent in chemical synthesis
Dielectric fluid in bubble chambers in wind tunnels
Aerosol propellant
Blowing agent in production of polyurethane foam
Production of polymeric resins
Chemical intermediate
Aerosol propellant
Aerosol propellant
Electric insulation
No information available
Manufacture cleaning compounds
Aerosol propellent
Aerosol propel I ant
Manufacture fire extinquishers
-------
UASTECGDE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U121 (continued)
U122 Formaldehyde
t-j
U123 Formic acid
Plastics and Resins Manufacturing
Organic Chemical Manufacturing
Tire
Medicine
Dyes and Pigments Manufacturing
Leather and Tanning
Explosives
Agriculture
Agricultural Chemical Manufacturing
Paint Manufacturing
Textiles
Organic Chemical Manufacturing
Cosmetics and Fragrances
Medicine
Fiber Manufacturing
Aerosol propellent (floor waxes)
Refrigerant
Solvent and degreesing agent
Chemical intermediate for phenolic, polyacetal
and MeIeaine resins
Chemical intermediate for resorcinol-formaldehyde
and aniline-formaldehyde resins
Chemical intermediate for acetylenic chemicals,
(1,4-butanediol), polyols (pentaerythritol).
hexamethylenetetramine, methylene dianiline,
pyridine chemicals, nitroparaffin derivatives
Chemical intermediate for rubber processing chemicals
Disinfectant
Embalming agent
Component of dyes as starch preservative
Chemical intermediate for synthetic tanning agent
Chemical intermediate for explosives
Soil sterilant in mushroom houses before planting
Manufacture of funigants, insecticides
Manufacture of commercial paint strippers, lacquers
Dyeing and finishing of textiles
Preparation of organic esters
Manufacture of refrigerants
Solvent for perfumes
Antiseptic
Silvering glass
Cellulose formate
Ore floatation
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
UASTECODE NAME
U123 (continued)
U124 Furan
U125 Furfural
INDUSTRY
USE (a)
NJ
U126 Glycidylaldehyde
U127 Hexachlorobenzene
U128 Hexachlorobutadiene
U129 Lindane
U130 Hexachlorocyclopentadiene
U131 Hexachloroethane
Plastics .and Resins Manufacturing
Leather and Tanning
Organic Chemical Manufacturing
Organic Chemical Manufacturing
Petrolem Refining
Adhesives and Sealants
Food Processing
Plastics and Resins Manufacturing
Medicine
Paint Manufacturing
Agricultural Chemical Manufacturing
Automotive
Commercial Testing Laboratories
Uool Weaving and Finishing
Leather and Tanning
Medicine
Pesticide
Rubber
Pesticide
Pesticide Manufacturing
Explosive
Manufacture of vinyl resin plasticizers
Leather tanning
Chemical intermediate for tetrahydrofuran
Organic synthesis for pyrrole, thiophene
Solvent in extraction of butadiene from C4 streams
Refining of lubricating oils
Constituent of rubber cement
Synthetic flavoring ingredient
Solvent for synthetic and natural resins
Screening test for urine
Manufacture of varnishes
Insecticide, fungicide, germicide
Wetting agent in the manufacture of abrasive
wheels and brake linings
Research chemical
Cross-1 inking agent for finishing of wool
Oil tanning and fat-liquoring of leather
Oil tanning and fat-liquoring of surgical sutures
Protein insolubilization
Chemical intermediate in glycerol manufacture
Fungicide
Solvent for rubber
Insecticide
Chemical intermediate for atdnn, dieldrin, endrin, endosulfan,
chlordane, heptachlor, isodrin
Solvent
Explosives
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AMD P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U131 (continued)
U132 Hexachlorophene
U137 ldeno(1,2,3-c,d)pyrene
to
U138 lodomethane
UUO Isobutyl alcohol
R liber
Soap
Cosmetics
Construction
Pharmaceutical
Organic Chemicals Manufacturing
Chemical Research
Pharmaceuticals
food Processing
Plastics and Resins Manufacturing
Cosmetics and Fragrances
Pharmaceutical Manufacturing
Camphor substitute in celluloid
Vulcanizing accelerator
In soap and germicidal preparations
In cosmetic preparations
In coal tar for road surfaces and roofing materials
Binder for electrodes in aluminum reduction process
Treatment of acute and chronic dermatoses
Waterproofing
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
Research chemical
Chemical intermediate for methylamines I quarternary ammonium iodides
Chemical intermediate for for phosponiun iodides
Chemical intermediate for organometallics
Alkylating agent
Methylating agent in prep, pharmaceutical intermediates
Microscopy
Building block for radioactive tracers synthesis
Testing for pyridine
As imbedding material of diatom examination
As fire extinguisher
Manufacture of food additives
Solvent for surface coatings and adhesives
Chemical intermediate for isobutyl esters used
as plasticizers
Manufacture of perfumes
Processing solvent (or pharmaceuticals
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
=r2=E=SSSSSS=S=SSSS3BB«S3SSSS8aaBSSSSSS===SS
INDUSTRY
USE (a)
UUO
(continued)
UU1
Isosafrole
ro
oo
UU3
UU7
Lasiocarpine
Maleic anhydride
UU8
Maleic anhydride
Agricultural Chemical Manufacturing
Organic Chemical Manufacturing
Petroleum Refining
Flavor
Cosmetic and Fragrance
Medicine
Organic Chemical Manufacturing
Plastics and Resins Manufacturing .
Dyes and Pigments Manufacturing
Pharmaceutical Manufacturing
Agricultural Chemical Manufacturing
Petroleum Refining
Agricultural Chemicals
Processing solvent for pesticides
Chemical intermediate for isobutylamines, zinc
diisobutytdithiophosphate, isobutyl acetate.
acrylate and methacrylate esters
Diluent-reagent in the alkylation of amino resins
Cosolvent in tertiary oil recovery
Chemical intermediate for isobutyl esters used
as plasticizers
In root beer (former use) and sarsaparilla flavors
Manufacture heliotropin
Chemical intermediate for dihydrosafrole (not in U.S.)
Manufacture pesticide synergists
Modify oriental perfumes
Research chemical
Diene syntheses, co-polymerization reactions
Chemical intermediate for fumaric acid, malic acid
Chemical intermediate for surfactants, chlorendic
anhydride and acid, rosin adducts
Manufacture of alkyd-type resins, reactive plasticizers
Comonomer for unsaturated polyester resins
Manufacture of dye intermediates
Manufacture of Pharmaceuticals
Manufacture of agricultural chemicals
Chemical intermediate for lube oil dispersants
and corrosion inhibitors
Synthesis of pyridazine
Uracil antimetabolite
Weed control in mixture with 2.4-0
Inhibits plant growth (tobacco, potato & onions)
-------
UASTECCDE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
UU6 (continued)
UU9 Malonitrile
P> U150 Helphalan
to U152 Methacrylonitrite
U153 Hethanethiol
Medicine
LUbricant
Medicine
Medicine
Medicine
Plastics and Resins
Flavor
Agricultural Chemicals
Pesticides
Petroleum Refining
Plastics and Resins
U1S4 Methyl alcohol
Sugar content stabilizer in beets
Fungicidal
Photosensitizer
Foraerly used to treat mental illness
Acrylic fiber and dyestuff synthesis
Organic synthesis
Lubricating oil additive
Leaching agent for gold
Thiamine synthesis
Anti-cancer agent synthesis
Antineoplastic agent
Preparation of hooopolymers & copolyners
Intermediate in preparation of acids, amides, amines, esters, nitrites
Monomer for copolymers
Monomer for polymethacrylonitrile
Manufacture of elastomers, coatings, plastics
Synthetic flavoring and adjuvants
Synthesis of •ethimine
Synthetic flavoring substances and adjuvants
Catalyst
Gas odorant for hazardous gases
Synthesis of methimine
Intermediate in fungicides
Intermediate in pesticide manufacture
Intermediate in jet fuels manufacture
Intermediate in plastics manufacture
Kill animal pathogenic bacteria and maggots on
-------
BBB&S8333S3S8E33SSSE8SSSK3SSB3888SS8
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
= = =; = = = = = = = = = =
U154 (continued)
u>
o
U1SS Methapyrilene
U1S6 Methyl chlorocarbonate
Ut57 3-Methylcholanthrene
Agricultural Chemicals
Petroleum Refining
Printing
Pharmaceuticals
Veterinary Medicine
Pesticides
Construction
Pharmaceutical
Organic Chemicals Manufacturing
Medical Research
U158 4,4-Methylene-bis-(2-chloroaniline)
U159
Methyl ethyl ketone
Munitions
Aircraft
Plastics and Resins Manufacturing
Paint Manufacturing
Cement
household contents, nortuary instrunents. human
bedding and clothing, tissues, human stools,
and cadavers
Treatment against onion smut, dutch elm disease,
and wood root
Removal of toxic organic pollutants from soil
Kill sliac forcing bacteria in oil recovery
injection water and packer fluid
Duplicating fluid
Removal of 2,4-dinitrotoluene from spent carbons
Sedative in sleeping aids
Antihistaainic
Antihistaainic agent
In organic synthesis
In insecticides
In coal tar for road surfaces and roofing materials
Binder for electrodes in aluminum reduction process
Treatment of acute and chronic dermatoses
Waterproofing
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
Induces specific forms of cytochrome in cancer research
Components in home appliances
Manufacture of radar systems
Manufacture of gun mounts
Manufacture of jet engine turbine blades
Curing agent
Manufacture of paint removers
Manufacture of cements
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
UASTECOOE NAME
INDUSTRY
USE (a)
U159 (continued)
U161 Methyl isobutyt ketone
U162 Methyl methacrylate
U163 N-Hethyl,N-nitro-,N-nitroguanidine
U1M Methylthiouracil
U165 Naphthalene
Adhesives and Sealants
Cleaning Products
Organic Chemical Manufacturing
Building Products
Magnetic Tape
Printing
Agricultural Chemical Manufacturing
Medicine
Pharmaceutical Manufacturing
Paint Manufacturing
Organic Chemical Manufacturing
Dry Cleaning
Food Processing
Organic Chemical Manufacturing
Medicine
Hunan/Veterinary Medicine
Organic Chemicals Manufacturing
Plastics and Resins
Manufacture of adhesives
Solvent for adhesives
Cleaning fluids
Organic synthesis
Oxidation promoter in manufacture of terephthalic
acid from p-xylene
Solvent for coatings
Solvent for magnetic tape
Solvent for printing inks
Solvent for cosolvent in pesticide formulations
.Sterilizer for baterial spores on surgical instruments,
hypodermic needles/syringes, and dental instruments
Denaturant for rubbing alcohol
Manufacture of antibiotics
Solvent for paints, varnishes, cellulose lacquer
Manufacture of methyl anyI alcohol
Organic synthesis, extraction processes
Manufacture of dry cleaning preparations
Manufacture of synthetic flavoring substances
Monomer for polymethyl methacrylate, comonomer
for copolymers
Chemical intermediate for higher methacrylate esters
Laboratory preparation of diazomethane (former use)
Research chemicals
Anti-thyroid agent (Hot produced in U.S.)
Manufacture of phthalic and anthranilic acids, naphthols,
naph thyI amines, sulfonic acid
Manufacture of synthetic resins
Manufacture of cellulouid, lampblack, smokeless powder
Preparation of anthiaquinone
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U16S (continued)
U166 1,4-Naphthoquinone
OJ
to
UI67 1-Naphthylamine
U168 2-Naphthytamine
Dyes and Pigments
Pesticide
Leather and Tanning
Veterinary Medicine
Tire
Plastics and Resins Manufacturing
Dyes and Pigments Manufacturing
Pharmaceutical Manufacturing
Agricultural Chemical Manufacturing
Dyes and Pigments
Pesticides
Pesticides
Rubber
Dyes and Pigments
Rubber
Rubber
U169 Nitrobenzene
Manufacture of indigo
Formation of perylene
Chemical intermediate for 1-naphthyl-n-methyl carbamate insecticide
Chemical intermediate for beta-naphthol and synthetic tanning chemicals
Chemical intermediate for naphthalene sulfactants
Insecticide, antiseptic, vermicide
Ingredient in moth repellent and toilet bowl deodorants
Manufacture of hydronaphthalenes used as solvents in lubricants and
motor fuels
Polymerization regulator for rubber
Polymerization regulator for polyester resins
Synthesis of dyes
Synthesis of Pharmaceuticals
Algicide
Chemical intermediate for inidazoline adrenergic agent
Chemical intermediate for N-1-Naphthylphthalmic acid herbicide
Toning prints made uith cerium salts
Chemical intermediate for dyes
Chemical intermediate for 1-Naphthylthiourea rodenticide (former use)
Chemical intermediate for fluoroacetamide miticide (former use)
Chemical intermediated for N-Phenyl-1-Naphthylamine rubber antioxidant
Production 2-chloronaphthylamine
Former chemical intermediate for dyes
Former chemical intermediate for rubber antioxidants
Formerly in manufacture of rubber
Solvent
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AMD P CHEMICAL PRODUCTS
WASTECOOE NAME
INDUSTRY
USE (a)
U169 (continued)
Jewelry
Plastics and Resins
Food
u>
u>
U170
U171
4-Nitrophenol
2-Nitropropane
Pesticides
Pharmaceuticals
Rubber
Pesticide
Paint and Varnish
Dyes and Pigments
Munitions
Ingredient of netaI polishes
Manufacture pyroxylin compound
Preservative in spray paints
Solvent for cellulose ethers
Chenical intermediate for aniline, dichloroanilines
Refining lubricating oils
In soaps, shoe polishes
Substitute for almond essence
Production of isocyanates
Modifying esterification of cellulose acetate
Constituent of floor polishes
Production of pesticides
Production of Pharmaceuticals (acetoninophen)
Production of rubber chemicals
Production of parathion, fungicide
Paint and varnish removal
Chenical intermediate for 2-Amino-2-methyl-1-propanol
Increase wetting ability t electrostatic spraying properties
Solvent for chemical reactions
Provide better flow characteristics t film integrety
Chemical synthesis
Insure greater pigment dispersion
Co-solvent for coatings, ink, t adhesives
Insure more complete solvent release
Rocket propellent
Improve drying time in solvent systems
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
3 = = = 3 = 3333 = 33 = 3333333
WASTECOOE NAME
E33S333S333333BS33SS3S3SSSSS33VSS33333333333333333332
INDUSTRY
=====3=3333333=33333335
USE (a)
U171 (continued)
U172 N-Mitroso-di-n-butylamine
U173 N-Nitroso-diethanolamine
U174 N-NitrosodiethylMine
U176 N-Mitroso-N-ethylurea
U177 N-Nitroso-N-«ethylurea
U178 N-Mitroso-N-nethylurethane
U179 . N-Nitrosopiperidine
U180 M-Nitrosopyrrolidine
U181 5-Nitro-o-toluidine
U182 Paraldehyde
Coating
Coating
Dyes and Pigments
Pesticides
Petroleua Refining
Pharmaceuticals
Research
Research
Research
Petroleum Refining
Research
Research
Research
Research
Dyes and Pigments
Organic Chemical Manufacturing
Dyes and Pigments Manufacturing
Processing solvent for extractions and separations
Acid-proof lacquer on battery cases
Solvent systems
Intermediate in synthesis of dyes
Intermediate in synthesis of insecticides
Racing car fuel
Gasoline additive
Smoke depressant in diesel fuel
Intermediate in synthesis of Pharmaceuticals
Research chemical
Researh chemical
Research chemical
Stabilizer
Antioxidant
Gasoline and lubricant additive
Research chemical
Laboratory preparation of diazoethane
Mutagenic effects on various plants
Laboratory synthesis of diazomethane
Laboratory synthesis of diazomethane
Research chemical
Research chemical
Research chemical
Chemical intermediate for pigments and dyes
Substitute for acetaldehyde
Solvent for fats, oils, waxes
Manufacture of dyestuff intermediates
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AMD P CHEMICAL PRODUCTS
UASTECOOE NAME
INDUSTRY
USE (a)
U1B2 (continued)
U183 PentachIorobenzene
U164 Pentachloroethane
>
U)
Ol
U1BS
U1B6
U187
U188
U191
Pentach t oroni t robenzene
1.3-Pentadiene
Phenacetin
Phenol
2-Picoline
U192 Pronamide
U193 1,3-Propane sulfone
1)194 n-Propylamine
Plastics and Resins Manufacturing
Leather and Tanning
Fiber Manufacturing
Coal
Agricultural Chemicals
Organic Chemicals Manufacturing
Luaber
Agricultural Chemical
Hair Products
Pharmaceuticals/Veterinary Medicine
Dyes and Pigments
Plastics and Resins
Agricultural Chemical
Textiles
Dyes and Pigments
Pesticides
Solvent for guns, resins
Manufacture of leather
Mixtures for cellulose derivatives
No information available
Solvent for oil and grease in metal cleaning
Separation of coal fron impurities
Soil sterilization
Solvent for cellulose acetate, cellulose esthers, resins
Drying agent for timber
Fungicide
Manufacture of synthetic rubber>
Stabilizer for hydrogen peroxide in hair bleaching preparation
Analgesic and antipyretic
Disenfectant
Chemical intermediate for 2-chloro-6-(trichloromethyl)pyridine
Organic intermediate for Pharmaceuticals,rubber chemicals
Chemical intermediate for 2-vinylpyridine, herbicide picloram.amproliun
Intermediate
Intermediate
Herbicide for vegetables
Confer water solubility and anionic character
Chemical intermediate to sulfopropyl group
Chemical intermediate for textile resins
Chemical intermediate for propyl isocyanate
Chemical intermediate for dyes
Chemical intermediate for pesticides
-------
================
UASIECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
UW
(continued)
U196 Pyridine
>
OJ
Petroleum Refinining
Pharmaceuticals
Rubber
Pharmaceuticals
U197
1,4-Benzoquinone
Agricultural Chemicals
Dyes and Pigments
Explosives
Food Products
Paint Manufacturing
Petroleum Refining
Plastics and Resins
Rubber
Textiles
Agricultural Chemical Manufacturing
Chemical intermediate for petroleum additives
Chemical intermediate for drugs
Chemical intermediate for rubber chemicals
Solvent reaction medium or catalyst in carbohydrate treatment
In organic synthesis and analytical chemistry
As an inhibitor t preparation of inhibitor
Manufacture vitamins,sulfa drugs,disinfectants
Chemical intermediate for antihistamines
Manufacture of stimulants,local anesthetics
Solvent in drug manufacture
Chemical intermediate for diquat t paraquat, piperidine
Solvent for anhydrous mineral salts
To denature alcohol ( antifreeze mixtures
Reduces nitrogen oxide in flue gas
Synthesis of piperidine
s
Reagent
Manufacture fungicides
Manufacture dyestuffs
Manufacture explosives
Useful in seafood, smoke falvor. chocolate
Solvent reaction medium or catalyst in paint manufacture
In oil and gas well drilling
Solvent in manufacture of polyurethane resins
No information available
Chemical intermediate for water-proofing agents in textiles
Manufacture of fungicides
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U197 (continued)
U200
U201
Reserpine
Resorcinol
U202
Saccharin
U203
Safrole
U206 Streptozatocin
Organic Chemical Manufacturing
Film
Leather and Tanning
CoHMtict and Fragrances
Pharmaceuticals
Leather and Tanning
Explosives
Dyes and Pigments
Plastics and Resins
Animal Food Products
Electroplating
Food Products
Adhesives and Sealants
Cosmetics
Pesticides
Pharmaceuticals
Medicine
Veterinary Medicine (Research)
Analytical reagent, oxidizing agent
Determination of amino acids by the formation
of red charge-transfer complexes
Photography
Tanning hides
Transfor* nitrogen containing-coopounds into
colored substances
Medication
In tanning
Manufacture of resins
Cattle feed additive
Electroplating bath additive
Non-caloric synthetic sweetener -- food, gum, toothpaste, smokeless
tobacco, etc.
Chemical intermediate for heliotropin
Chemical intermediate ofr isosafrole
Manufacture of piperonyl butoxide
As preservative in mucilage and library paste
Fragrance for cosmetics
Pediculicide
Flavoring agent for drugs, topical antiseptic
Carminative
Antineoplastic agent in cancer treatment
Experimental use in diabetes & as antimicrobial agent
Diabetogenic agent
U207 1,2,4.5-Tetrachlorobenzene
No information available
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
UASTECODE NAME
INDUSTRY
USE (a)
U208 1.1,1.2-Tetrachloroethane
U209 1,1.2,2-Tetrachloroethane
i
to
cxi
U210 Tetrachloroethylene
U211 Carbon tetrachloride
U213 Tetrahydrofuran
Plastics and Resins
Agricultural Chemicals
Nedical Research
Organic Chemicals Manufacturing
Plastics and Resins
Agricultural Chemicals
Nedical Research
Organic Chemicals Manufacturing
Dry Cleaning
Dry Cleaning
Automobile
Pesticide
Organic Chemicals Manufacturing
Food Processing
Plastics and .Resins Manufacturing
Organic Chemical Manufacturing
Nonflammable solvent for fats, oils, Maxes, resins, cellulose acetate,
rubber, phosphorous, sulfur
Manufacture of paint, varnish, and rust removers '
Soil sterilization, weed killer, and insecticide formulations
Immersion fluid in crystallography
Provide pathological changes in gastrointestinal tract, liver, kidneys
Chemical intermediate for trichloroethylene, halogenated hydrocarbons
Nonflammable solvent for fats, oils, waxes, resins, cellulose acetate,
rtfcber. phosphorous, sulfur
Manufacture of paint, varnish, and rust removers
Soil sterilization, Meed killer, and insecticide formulations
Immersion fluid in crystallography
Provide pathological changes in gastrointestinal tract, liver, kidneys
Chemical intermediate for trichloroethylene. halogenated hydrocarbons
Degreesing metals
Solvent
Fire extinguisher
Cleaning clothing
Azeotropic drying agent for uet spark plugs
Solvent for oils, fats, lacquers, varnishes, rubber, Maxes, resins
Extracting oil from floners, seeds
Insecticide
Starting material for organic compounds
Indirect food additive for food contact surface
of articles intended for use in food processing
Solvent for resins and plastics
Chemical intermediate for polytetramethylene
-------
TABLE A-1 (Continued)
INDUSTRIAL USE Of U AMD P CHEMICAL PRODUCTS
UASTECOOE NAME
INDUSTRY
USE (a)
U213 (continued)
U21B
Thioacetmide
Nagnetic Tape
Cleaning Products
Printing
Leather. Textiles, Paper
U)
\o
U219
Thiourea
Medicine
Rubber
Cosawtics
Paper Manufacturing
Wood Preserving
Paper
Adhesives and Sealants
gtycol. tetrahydrothiophene
Solvent for top coating solutions, protective
coatings, coating magnetic tapes
Solvent for cleaning
Agent in liquid Membrane electrode Manufacturing
PolyMerization solvent
Solvent for print inks
Solvent for production of tetraethyl and
tetramethyl lead
Solvent
Stabilizer for fuel with tetraethyllead
Substitute for Hydrogen sulfide in labs
Solubilizer for riboflavin
Analytical reagent
Accelerator for buna rubber
Reanval of mercury from uasteuaters
In hair preparations
Preparation of non-glare Mirrors
In paper whiteners
Stain prevention of hemlock wood
In scrub soln for waste gas containing NO(X)&SO(X)
Stabilizer for diazo coating solns for copy film & paper
Reagent for bismuth, setenite ions
Llquifier/peptizing agent for glue
In dry-cleaning chemicals
Che I at ing agent
Synthesis of sulfthiazote
-------
WASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U219 (continued)
*-
o
U220
Toluene
Textiles
Agricultural Chemicals
Dyes and Pigments
Photography
Pesticides
Pharmaceuticals
Plastics and Resins
Textiles
Veterinary Medicine
Organic Chemicals Manufacturing
Explosives
Dyes and Pigments
Food
Medicine
Cosmetics and Fragrance
Catalyst in isomerization of naleic to fumaric acid
Intermediate for 5-lodo-2-thiouracil
In cleaning and plating baths for metals
Manufacture of fire retardant for lacy fabrics
Metal corrosion inhibitor for pickling solutions
Radioprotector in X-irradiated mice
Reduces interferences for analysis of cadmium
Vulcanization accelerator
In mineral oil
Fungicide
Sprout accelerator in dormant tubers
Dye intermediate
Photographic fixing agent and remove stains from negatives
Complexing agent for color print photography
Synthesis of insecticides
Synthesis of Pharmaceuticals
Manufacture of resins
In-boiier water treatment
Flame-proofing agent for nylon
Weighting agent for silk
Experimentally as thyroid inhibitor or goitrogen
Medication
Manufacture of benzoic acid, benzaldehyde
Manufacture of explosives
Manufacture of dyes
Manufacture of caprolactam
Manufacture of saccharin
Manufacture of medicines
Manufacture of perfunes
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
UASTECOOE NAME
INDUSTRY
USE (a)
U220 (continued)
U222 o-Toluidine hydrochloride
U225 Bromoform
U226 1.1,1-Trichloroethane
U227 1,1.2-Trichloroethane
U228 Trichloroethylene
Toy Manufacturing
Plastics and Resins
Petroleua Refining
Dyes and Pignents
Organic Chemicals Manufacturing
Aircraft/Aerospace
Pharmaceuticals
Rubber
Shipbuilding
Adhesive solvent in plastic toys and nodeI airplanes
Solvent for paints, lacquers, guns, resins
Extraction of various principals from plants
Gasoline additive
Chemical intermediate for dyes
Ingredient in fire-resistant chemicals
Chemical intermediate for organic synthesis
Solvent in liquid-solvent extractions
Flotation agent in sedimentary petrographical surveys
Catalyst/sensitizer in polymer reactions
Solvent for waxet,greases,! oils
Flotation agent in purification of materials (quartz)
Flotation agent in mineral separation
In gauge fluid
Reagent for graphite ore fractionation
Solvent in nuclear magnetic resonance studies
No information available
Sedative
Synthesis of Pharmaceuticals
Catalyst/sensitizer in vulcanization of rubber
No information available
Cold-type metal cleaning
Cleaning plastic molds
Solvent for fats, waxes, natural resins, alkaloids
Solvent for fats, waxes, resins, oils, rubber, paints.
varnishes, cellulose esters and ethers
Solvent extraction
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
UASTECODE NAME
INDUSTRY
USE (a)
r
U228 (continued)
U234 sym-Trinitrobenzene
U236 Trypan blue
U237 Uracil Mustard
U238 Ethyl carbamate
U239 Xylenes
Dry Cleaning
Organic Chemicals Manufacturing
Pharmaceutical
Explosives
Rubber
Dyes and Pigments
Medicine
Medicine
Medicine
Agricultural Chemicals
Biochemical Research
Cosmetics
Pesticides
Pharmaceuticals
Textiles
Veterinary Medicine
Organic Chemicals Manufacturing
Textile and Fiber
Degressing
Acid-base indicator for 12.0-U.O pH
Explosive
Vulcanize natural rubber
Biological stain
Dye for textiles,leather.paper
Therapeutic agent for sleeping sickness
Antineoplastic agent (essentially obsolete drug)
Formerly as adjunct to sulfonamide therapy
Preparation and modification of anino resins
Anti-neoplastic agent
Solvent for barious organic materials
Solutilizer and co-solvent for funigants
No information available
x
Solubilizer and co-solvent
Solubilizer and co-solvent
Formerly topical bactericide
Formerly component sclerosing soln for varicose veins
Intermediate for Pharmaceuticals
Chemical intermediate for N-hydroxymethyl derivatives
Anesthetic, hypnotic, sedative, diuretic
As a solvent
Raw material in production of benzoic acid, phthalic anhydride,
isophthalic and terephthalic acids
Manufacture of polyester fibers
-------
UASTECGOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U239 (continued)
U240 2.4-0. Salts and esters
U243 Hexachloropropene
U244
Thira
is
u>
Dyes and Pigments
Laboratories
Pesticide
Plastic and Resin
Agricultural Chemicals
Wood Preserving
Food Products
Rubber
Paper
Pharmaceuticals
Agricultural Chemicals
Manufacturing dyes
Sterilizing catgut
With Canada balsam as oil-immersion in microscopy
Cleaning agent in microscope techniques
Systemic herbicide
Solvent
Plasticizer
Hydraulic fluid
Preparation of uranium tetrachloride
Production of monochloropentene
Peptizer for polysulfide elastomer
Fungicide for industrial textiles
Preservative
Activator for guanidine,amine,i thiazole cure systems
Mushroom disinfectant
Antioxidant in polyolefins
Vulcanizing agent for rubber
Accelerator for natural t isoprene rubbers.etc.
Fungicide for use on paper, polyurethane foam products
Bacteriostat in soap and antiseptic sprays
Activator for sulfenamide accelerators
Fungicide for seed treatment
Animal repellent for trees and shrubs
U247 Methoxychlor
U248 Warfarin
P001 Warfarin
Pesticide
Agricultural Chemical Manufacturing
Hedicine
Agricultural Chemical Manufacturing
Insecticide
Rodenticide for norway rats and house mice
Anticoagulant therapy
Rodenticide for norway rats and house mice
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHENICAL PRODUCTS
UASTECOOE NAME
INDUSTRY
USE (a)
P001 (continued)
P002 1-Acetyl-2-thiour««
Medicine
Anticoagulant therapy
No information available
P003 Acrolein
POOA Aldrin
POOS Allyl alcohol
P007 5-Aminoethyl-3-isoxazolol
POOS 4-Aminopyridine
POU Thiophenol (Benzenethiol)
P016 Bis-(chloromethyl)ether
P017 Bromoacetone
P018 Brucine
Agricultural Chemical Manufacturing
Organic Chemical Manufacturing
Pharmaceutical Manufacturing
Plastics and Resins Manufacturing
Agricultural Chemical Manufacturing
Military
Pesticide
Agricultural Chemical Manufacturing
Organic Chemical Manufacturing
Plastics and Resins Manufacturing
Medicine
Plastics
Agricultural Chemicals,
Pesticides
Plastics
Specialty Chemical
Plastics
Munitions
Specialty Chemical
Pesticide
Chemical intermediate in synthesis of glycerin,
acrylic acid and esters
Chemical intermediate for Pharmaceuticals
Chemical intermediate for glycerol, polyurethane,
and polyester resins
Aquatic herbicide, biocide, slimicide
Component of military poison gases
Lacrlmogenic warning agent in methyl chloride refrigerant
Insecticide, fumigant
Herbicide for weed, seeds and fungi
Intermediate in synthesis of glycerin
Manufacture of resins and plasticizers
Laboratory use •
Antiemetic
Solvents, reagents and chemicals
Chemical intermediate for carbophenothion fungicide
Chemical intermediate for carbophenothion insecticide & acaricide
Alkylating agent in manufacture of polymers
Monitoring indicator for chloromethyl ether
Intermediate in synthesis of anionic exchange strong-base resins
Lab reagent
Organic synthesis
Chemical war gas
Tear gas
Reagent for separating racemic mixtures
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AMD P CHEMICAL PRODUCTS
UASTECODE NAME
INDUSTRY
USE (a)
P018 (continued)
P020 Dinoseb
P022 Carbon disulfide
Pesticide
Clothing
Automobile Manufacturing
Metals Recovery
Wood, Housing
Lubricants. Wax. Soap, Food
Chemical
Specialty Chemical
Plastics
Medicine
Electroplating
Plastics
Electronic
Petroleum
Rubber
Adhesives and Sealants
Agricultural Chemicals
Explosive
Denaturant for ethanol
Herbicide
Cheatcat interned!ate for rayon
Corrosion inhibitor
Agent in removal of metals for* waste water
Putty preservatives
Tallow
Catalyst and catalyst adjuvant and activator
Dissolving free sulfur,phosphorous,iodine
Regenerator for transition metal sulfide catalysts
Manufacture of xanthogenates
Xanthation of cellulose in preparation of viscose
Flame lubricant in cutting glass
Chemical intermediate for carbon tetrachloride
Chemical intermediate for cellophane
Solvent for phosphorous,seleniua.bromine. iodine, fats & resins
Optical glass
Agent in metal treatment and plating (gold and nickel)
Polymerization inhibitor for vinyl chloride
Electronic vacuum tubes
Solvent for cleaning and extractions
Generating petroleum catalysts
Solvent for waxes, lacquers, camphor, res ins, vulcanized rubber
Chemical intermediate for sulfur and carbonyl sulfide,xanthates
Rubber cement
Chemical intermediate for adhesives for food packaging
Solvent in extraction of growth inhibitors
Preservation of fresh fruit
Explosives
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
UASIECOOE NAME
INDUSTRY
USE (a)
P022 (continued)
P023 Chloroacetaldehyde
P024 p-Chtoroanitine
P026 1-(o-Chlorophenyl)thiourea
P027 3-Chloroproprionitrile
P028 Benzyl chloride
Filn
Pesticides
Agricultural Chemical
Petroleum Refining
Plastics and Resins
Rubber
Veterinary Medicine
Titter
Specialty Chemical
Uater Treatment
Agricultural Chemicals
Dentistry
Agricultural Chemicals
Dyes and Pigments Manufacturing
Specialty Chemical
Pharmaceuticals Manufacturing
Specialty Chemical
Agricultural Chemicals
Flavoring
Cosmetics and Fragrances
Pharmaceuticals
Development restrainer for instant color photography
Solvent for pesticide intermediates
Fuiigant
Seed treatment on conifers
Soil disinfectants
Rocket fuel
Paints,enamels,varnishes,paint removers
Chemical intermediate for rubber compounds
Cold vulcanization of rubber
Veterinary anthelmintic
Bark removal from trees
Chemical intermediate
In manufacture of 2-aminothiazole
Control of algae,bacteria,and fungi in water
Fungicide
As spinning solution of poly B-aniline
Chemical intermediate for urea herbicides
Chemical intermediate for dyes and pigments
Not manufactured or used industrially in U.S.
Combines reactivity of nitrile and an alkyl halide
Pharmaceutical and polymer synthesis
Chemical intermediate for other benzyl phthalates
Chemical intermediate for n-butyl benzyl phthalate
Manufacture of benzyl compounds
Synthesis of tribenzyltin chloride
Blocking agent to monoalkylated piperazine
Conversion of tertiary amines to quaternary ammonia chlorides
Manufacture of batericides
Manufacture of flavors and odorants
Manufacture of perfunes
Manufacture of pharmaceutical products
-------
33====38BSSS33S88B883:
UASTECCOE NAME
lS88S«8SB8B3C83E3333S3333S3«S«8S8B8a
TABLE A-1 (Continued)
INDUSTRIAL USE Of U AND P CHEMICAL PRODUCTS
8S3SSS3B3CS3S*EleC*3BatB«B*M;B«83BBS«C6S3
INDUSTRY
S3333EESSS3ES333S33
USE (a)
P028
(continued)
P03A 2-Cyclohexyl-4,6-dinitrophenol
P037 Dieldrin
P042 Ephinephrine
P045
POA6
P047
P(KB
P049
P050
P051
P054
Thiofanox
Dyes and Pigments
Photography
Dyes and Pigments
Lubricant Manufacturing
Plastics and Resins
Agricultural Chemicals
Pesticides
Petroleua Refining
Phanaaceuticals
Rubber
Pesticide
Pesticide
Medicine
Pesticides
alpha,alpha-Dimethyl phenethylamine Medicine
4.6-Oinotro-o-cresol and salts Pesticide
2.4-Dinitrophenol
2,4-Dithiobiuret
Endosulfan
Endrin and metabolites
Aziridine
Pesticide
Pesticides
Plastics and Resins
Rubber
Pesticide
Pesticide
Specialty Chemical
Manufacture of synthetic tannins
Pickling inhibitors
Manufacture of photographic developer
Manufacture of dyes
Manufacture of lubricants
Manufacture of artificial resins
Manufacture of plastics and plasticizers
Production of electron-bean-sensitive fluid media
Manufacture of fungicides
Manufacture of insecticides
Gasoline gum inhibitor
Penicillin precursors
Rubber accelerators
Insecticide
Insecticide
To counter allergic reactions, prolong infiltration anesthetics
Adrenergic agent
Synpathoninetic, vasconstrictor, cardiac stimulant, bronchodilator
Systemic soil insecticide
Acaricide and neoatoclde (soil t seed treatment)
No information available
Ovicidal spray for fruit trees
Insecticide
Manufacture of insecticides, rodenticides
Plasticizer. intermediate in resin manufacture
Rubber accelerator
Insecticide for vegetables
Insecticide, in dieldrin
In binders
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AM) P CHEMICAL PRODUCTS
UASIECOOE NAME
INDUSTRY
USE (a)
P05«
(continued)
Plastics
Specialty Chemical
*-
CD
P057
P058
2-Fluoroacetanide
Fluoroacetic acid
P059 Heptachlor
P060 Isodrin
P064 Isocyanic acid, methyl ether
P066 Methomyl
P067 2-Hethylaziridine
Paint Manufacturing
Cosmetics
Adhesives and Sealants
Agricultural Chemicals
Photography
Paper
Pesticides
Petroleua Refining
Textiles
Pesticides
Pesticides
Pesticide
Pesticide
Agricultural Chemicals
Pesticides
Pesticides
Food
Specialty Chemical
Comonomer for polymers
Monomer for polyethyleneimine
As flocculation aids
In surfactants
In ion exchange resins
Chemical intermediate for N-(2-hydroxyethyl)ethyleneimine
Manufacture of trimethylmelanine
Manufacture of taurine
In lacquers
In cosmetics
In edhesi.ves
As plant mutagen to improve varieties
Exhibits sporicidal action
In photographic chemicals
Polymerization products
Control of insect pests by chenosteritization
In petroleum refining chemicals, fuels, oils
Strengthening, shrinkproof ing, stiffening, flameproof ing, waterproofing
Insecticide
Rodenticide
R extent i tide
Predacide (predatory animals)
Insecticide for cotton boll weevil
Manufacture and use discontinued in U.S.
Chemical intermediate for carbamate herbicides
Chemical intermediate for carbamate insecticides
Nematocide, insecticide
Chemical intermediate in gelatins
Comonomer for polymer with methacrytic acid & esters
Chemical intermediate for lris(2-methyl-1,3,5-triaiine
Fiber modification
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
==ssss==eaa»e«»m«»*n«««a«»s»3S3o«es==r
INDUSTRY
USE (a)
P067 (continued)
P069 Methyltactonitrile
P070 Aldicarb
P072 1-Naphthyl-2-thiourea
POTS Nicotine
P077
4-Nitroaniline
Adhesive* and Sealants
Agricultural Chemicals
Dyes and Pigments
Fit*
Oil Additives
Paper
Petroleui Refining
Pharmaceuticals
Plastics and Resins
Rubber
Textiles
Specialty Chemical
Pharmaceuticals
Petroleui
Pesticides Manufacturing
Pesticides
Pesticides
Leather and Tanning
Agricultural Chemicals
Pesticides
Veterinary Medicine
Automobile Manufacturing
Petroleum
Dyes and Pigments
As polymer
In imine derivatives for agricultural chemicals
As polymer
Chemical intermediate in photography
Modifiers for viscoscity, high pressure performance, oxidation resist.
Chemical intermediate for oil additives
As polymer
Flocculants. modifier for rocket propellent fuels
Organic intermediate
In imine derivatives for medicinal chemicals
Chemical intermediate in modification of latex coating resins
Organic intermediate
As polymer
Chemical intermediate for methyl methacrylate
Reagent in formation of aldehyde cyanohydrins
Chemical intermediate for methacrylic acid 1 higher esters
Used to produce a pharmaceutical intermediate
Stereoselective hydrocyanating reagent
Complex ing agent for metals refining and separation
Manufacture insecticides
Insecticide, acaracide, nematocide
Rodenticide for Norway rat (former use)
In tanning
Greenhouse funigant
Insecticide
Ectoparasitic, anthelmintic
Corrosion inhibitor
Chemical intermediate for gasoline gun inhibitors
Chemical intermediate for dyes and pigments
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
UASTECOOE NAME
INDUSTRY
USE (a)
P077 (continued)
Specialty Chemical
P082 N-Nitrosodimethylamine
s>
o
P084 N-Nitrosomethylvinylamine
P088 Endothall
P093 N-Phenylthiourea
P095 Phosgene
Pharmaceuticals
Veterinary Medicine
Lubricant Manufacturing
Research
Specialty Chemical
Petroleum refining
Plastics
Fibers
Agricultural Chemicals
Pesticides
Rubber
Agricultural Chemical Manufacturing
Medicine
Agricultural Chemicals
Plastics and Resins
Specialty Chemical
Chemical intermediate for antioxidants .
Chemical intermediate for P-Phenylenediamine
No information available
For poultry
In lubricants
Research chemical
Preparation of thiocarbonyl fluoride polymers
Chemical intermediate for 1,1-Dimethylhydrazine (former use)
Antioxidant
Production of rocket fuels (former use)
Condensers to increase dielectric constant
Inactive metal anode-electrolyte systems (high-energy batteries)
Plasticizer for acrylonitrile polymers, solvent
Softener for copolymers
Solvent
Industrial solvent
Inhibition of nitrification in soil
'As nematocide
Plasticization of rubber
Rubber accelerator
Research chemical
Herbicide, defoliant, dessicant, growth regulator,
aquatic algicide and herbicide
In genetics research
Rabbit,rat,weasel repellent
Monomer for polycarbonate resins
Chemical intermediate for toluene diisocyanate
Chemical intermediate for methyl isocyanate
Chemical intermediate for polymethylene potyphenytisocyanate
Intermediate, carbonylating agent
Chemical intermediate for diethyl carbonate,dimethyl carbamoyl chloride
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
WASTECOOE NAME INDUSTRY USE (a)
P095 (continued)
P101 Propanenitrile
P102 Propargyl alcohol
>
P108 Strychnine
P116 Thiosemicarbazide
P118 Trichloromethanethiol
P123 Toxaphene
Munitions
Dyes and Pigments
Organic Chemicals Manufacturing
Specialty Chemical
Automotive
Organic Chemical Manufacturing
Agricultural Chemical Manufacturing
Commercial Testing Laboratories
Pharmaceutical Manufacturing
Pesticides
Agricultural Chemicals
Pesticides
Photography
Pesticide
Chemical intermediate for diphenylmethane-4,4'-diisocyanate
Chemical intermediate for acyl chlorides, chloroformate esters
War gas
Production of aniline dyes
Preparation of organic chemicals
Solvent, dielectric fluid, intermediate
Experimental applications: ulcerogen
Chemical intermediate for Di-n-propylamine
Corrosion inhibitor
Prevent hydrogen embrittIement of steel
Solvent stabilizer
Soil fumigant
Lab reagent
Manufacture of Pharmaceuticals
Destroying predatory animals and trapping fur-bearing animals
Rodent control in forage crops production
Rodent control in fruit production
Reagent for ketones and certain metals
Chemical intermediate for herbicides
Fungicide for rice
Rodenticide
No information available
No information available
Pesticide for cotton crops
(a) Sources: National Library of Medicine, Hazardous Substances Databank (Reference 32).
Handbook of Environmental Data on Organic Chemicals (Reference 33).
Merck Index 1983. (Reference 34).
-------
Table A-2
NUMBER OF FACILITIES THAT MAY GENERATE U AND P WASTES
INCLUDED IN BACKGROUND DOCUMENT VOLUMES A, 6, AND C
Waste Number of Waste Number of Waste Number of
Code Facilities* Code Facilities* Code Facilities*
P001
P002
P003
P004
POOS
POOS
P014
P016
P017
P018
P020
P022
P023
P024
P026
P027
P028
P034
P037
P042
P045
P046
P047
P048
P050
P051
P054
P057
P058
P059
P064
P066
P067
P069
P070
POT2
POTS
POTT
P082
P084
P088
P093
P095
P101
P102
P108
P116
P118
P123
U001
U002
U003
U004
U005
U006
UOOT
U008
U009
U010
U011
U012
U014
U016
U01T
U018
3
1
2
3
3
5
6
4
4
3
1
14
5
6
1
2
20
1
9
5
1
1
2
2
6
3
2
2
1
5
4
6
3
2
5
1
3
9
1
1
3
1
23
T
3
6
8
2
4
6
13
22
T
1
13
19
4
22
4
6
2T
4
NA
2
2
U019
U020
U021
U022
U024
U025
U026
U027
U029
U030
U031
U033
U034
U036
U037
U038
U039
U041
U042
U043
U044
U045
U046
U047
U048
U050
U051
U052
U053
U055
U056
U057
U060
U061
U063
U064
U066
U06T
U068
UOTO
UOT1
UOT2
UOT3
U074
U075
UOT6.
UOTT
UOT8
UOT9
U080
U081
U082
U083
U084
U085
U089
U091
U092
U094
U095
U105
U106
U108
U110
U112
T1
9
5
6
1
2
1
1
3
1
11
8
6
10
10
2
1
2
1
14
38
13
3
2
2
1
13
5
4
11
10
18
1
26
1
1
5
9
9
8
6
13
4
1
19
1
23
2
3
41
3
4
2
2
0
3
2
11
4
2
11
4
9
T
5
U113
U114
U116
U11T
U118
U120
U121
U122
U123
U124
U125
U126
U127
U128
U129
U130
U131
U132
U137
U138
U140
U141
U142
U147
U148
U149
U152
U153
U154
U15S
U156
U15T
U158
U159
U161
U162
U163
U164
U165
U166
U16T
U168
U169
U170
U171
U1T4
U1T7
U181
U182
U183
U184
U18S
U186
U187
U188
U191
U192
U194
U196
U197
U200
U201
U202
U203
5
1
1
5
2
1
12
73
1
6
5
0
3
2
20
6
4
2
1
19
8
2
6
8
10
1
4
1
12
3
2
1
8
31
5
3
6
4
IT
4
1T
2
17
2
4
3
1
1
0
2
2
6
3
5
13
11
1
8
6
1
7
1
3
6
Waste
Code
U20T
U208
U209
U210
U211
U213
U220
U221
U222
U223
U225
U226
U22T
U228
U234
U236
U238
U239
U240
U243
U244
U24T
U248
U206 3
Number of
Facilities*
1
1
3
32
33
6
48
9
1
38
6
44
5
39
1
2
4
42
18 '
1
2
8
3
•Sources: U.S. EPA 1986 TSDR Survey (Reference 4)
1987, 1988 SRI Directory of Chemical Producers, USA (References 35 and 36)
National Library of Medicine, Toxicology Data Network, Hazardous
Substances Databank (HSDB) (Reference 32)
A-52
-------
Table A3
NUMBER OF FACILITIES IN EACH STATE THAT NAY GENERATE U AND P WASTES
INCLUDED IN BACKGROUND DOCUMENT VOLUMES A. B. AND C
ui
u>
State
Alabama
Alaska
Arizona
Arkansas
California
EPA
Region
IV
X
IX
VI
IX
Waste Codes (Nunfcer of Facilities)
POU(1) P022(1) P034(1) P042(1) P095(1) PIOI(I) U019(2) 0020(1)
U220(1) U228(1) U239(2) 0244(1)
0061(1) U220(1) U226(1) U227(1) U228O) 0240(2)
U211(1) U219(1) U220(2) U223(1) U228(1)
P047<1) 11029(2) U06K1) U067(3) U122(2) 0211(1) U220(1) U226(1)
P004(1) P037O) PM2(1) POM(1) P108(1) 0002(1) 1)033(1) U057(2)
11036(1) U06U1) U080(1) U122(3) U129(2) U05K1) U170(1) U210(1) U21K2)
0240(1)
U06K2) U067(1) U070(1) U072(1) U07S(3) U080(3) 0082(1) U121(3) U122(1)
Colorado VIII
Connecticut I
Delaware
Florida
Georgia
Hawaii
Idaho
Illinois
Indiana
Iowa
Kansas
Kentucky
Louisiana
III
IV
IV
IX
X
V
V
VII
VII
IV
VI
Ma i ne I
Maryland III
Massachusetts I
0124(1) 0129(1) U138(1) U05K1) U159(2) U16K1) U1B8(1) U21K1) U218(1) U220(2) U223(1) U225(1) U226(6) 0228(4) 0239(4)
P066(1) U226(1) U239(1)
P022(1) P116(1) 0006(1) U007(1) U03K1) 0044(2) 0073(1) U075(1) U077(1) U080(1) U09KD U092(1) U138(1) 0148(1) U158(1) U159(1) U163(1)
U210(1) U219(1) U220(1) U223(3) U226(2) 0239(1) 0244(3)
P014(1) P022(1) P028(1) P050(1) P066(1) P070(1) P077(1) P09S(1) PIOI(I) P108(1) U006(2) U007(1)
U020(1) U022(1) 0036(1) 0044(1) U048(1) 1)055(1) 0056(1) U061(1) U070(2) U07K1) U072(2) U074(1)
0105(1) U114(1) U116O) U127(1) U13K1) U138(1) 0148(1) U1S2(1) U154(1) U163(1) U165(1) U167(1)
U210(2) 0211(1) U218(1) U220(1) U223(1) U226(1) 0227(1) U228(1) 0239(1) 0240(1) 0247(1)
P016(1) P088(1) 0057(1) U07S(1) U080(1) U082(1) U092(1) U110(1) U125(1) U142(2) 0147(1) 0154(1)
0226(2) 0228(1) 0239(2)
P050(1) P070(1) 0033(1) U057(1> U06K2) 0114(10)0122(1) U129(1) 0051(1) 0159(1) 0170(1) 0220(1)
P059(1) 0061(1) 0129(1) 0240(1)
0051(1) 0228(1)
P037(1) P042(1) P077(2) U003(3) 0004(1) 0009(3) U01K1) U012(1) 0019(2) 0033(1) 0036(1) 0037(1)
0072(1) 0075(1) 0077(1) 0117(1) 0121(2) 0122(2) 0130(1) U148(1) 0051(2) 0155(1) 0158(1) U159(2)
U206(1) 0210(1) 0211(2) 0219(1) 0220(3) 0223(1) 0225(1) 0226(2) 0228(2) 0234(1) 0239(1) 0240(4)
0009(1) 0011(1) 0012(1) 0018(1) 0019(1)
0077(1) O079(1) 0080(1) 0089(2) 0092(1)
0169(1) 0185(1) 0194(1) 0202(1) 0209(1)
0158(1) 0194(1) 0210(1) 0220(2) 0223(2)
0228(2)
0044(2) 0045(1) 0052(1) 0057(1) 0070(1)
0165(1) 0169(1) 0171(1) 0174(1) 0191(1)
P008(1) P017(1) P095(1) 0002(1) 0031(1) 0080(1) 0092(2) 0171(1) 0188(1) 0191(1) 0196(1) 0228(1)
0061(1)
0002(1) 0004(1) 0057(1) 0122(2) 0132(1) 0138(1) 0159(1) 0188(1)
0009(1) 0043(1) 0044(1) 0045(1) 0057(1) 0070(1) 0075(1) 0080(1) 0092(1) 0122(2) U05KD 0211(1) 0220(1) 0221(1) 0226(1)
0037(1) 0039(1) 0043(6) 0044(1) 0045(2)
0165(1) 0169(1) 0185(1) 0188(1) 0194(1)
P003(1) P022(1) P024(2) P095(3) 0007(2) 0008(1) 0009(2) 0012(2) 0015(2) 0016(1) 0031(2) 0036(1)
0057(1) 0061(1) 0077(6) 0080(1) 0108(1) 0113(1) O121(1) 0122(5) 0148(5) 0154(3) 0159(1) 0162(1)
0200(1) 0211(2) 0213(1) 0220(3) 0221(2) 0223(3) 0227(1) 0239(2) 0247(1)
0036(1)
P095(1) 0042(1) U080(1) 0156(1) 0223(2) 0226(1) 0228(3)
P023(2) P050(1) 0003(2) 0007(1) U009(1) 0044(2) 0053(1) 0057(1) 0080(2) 0108(1) 0110(1) 0112(1) 0122(1) 0051(1) 0159(2) 0193(1) 0194(1)
0210(1) 1)220(2) 0226(1) 0238(1) 0239(1) 0247(1)
-------
State
Michigan
EPA
Region
Table A-J (continued)
NUMBER OF FACILITIES IN EACH STATE THAT MAY GENERATE U AND P WASTES
INCLUDED IN BACKGROUND DOCUMENT VOLUMES A. B, AND C
Minnesota
Mississippi
Missouri
V
IV
VII
Ul
Montana VIII
Nebraska VII
Nevada IX
I
New Jersey 11
New Mexico VI
New York II
North Carolina IV
North Dakota VIII
Ohio V
Oklahoma VI
Oregon X
Pennsylvania III
Puerto Rico II
Rhode Island I
Waste Codes (Murker of Facilities)
POM<1) P088(1) P095C1) U007(1) U045(1> U068C1) 0073(1) U075(1) U078(1) 0080(1) 1)081(1) U110(1) U112(1) U12K1) U165(1) U206(1) 11211(1)
U219(1) U22S(1) 0240(1)
P067(1) P077(1) U019(1) UOU(1) U06KD U07K1) 1)080(2) U082(1) U122(1> U185(1) U226(1) U227(1) 0247(1)
P020(1) P022(1) P050(1> 1)012(2) U044(1) U1U(1) U122(3) U129(2) U169(1) U21K1) U220(1) U223(1) U226(1) U228(1) 0247(1) I
P004(1) P037(1) P050(1) P05K1) POS9(1) P066(1) P070(1) P10K1) P108(1) P123(1) U003(1) 0006(1) U007(2) U011(1) U012(1) 0019(2) 0036(1)
0037(1) 0044(1) 0056(1) 0061(2) 11072(1) 0075(1) 0077(1) U079(1) 0080(2) 0091(1) 0117(1) 0122(1) 0129(1) 0131(1) 0155(1) 0158(1) 0165(1)
0167(1) 0169(1) 0183(1) 0185(1) 0187(1) 0200(1) 0211(1) U220(3) 0225(1) 0239(1) 0240(1) 0247(1)
0122(1)
0125(1)
P123(1) 0034(1) 0061(1) 0072(1) 0080(1) 0228(1) P014(1)
POOK1) P017(2) P018(1) P022(1) P023(1) P024(2) P028(6) P037(1) P047(1) P04B(1) P057(1) P067(2) P072(1) P077(1) P095O) P116(3) 0002(1)
0004(3) 0006(5) 0007(3) 0009(1) 0011(1) 0012(3) 0014(3) 0017(1) 0019(1) 0031(2) U033(1) 0037(1) 0044(3) 0045(1) 0052(1) 0057(1) 0061(2)
0067(1) 0068(4) 0071(1) 0072(1) 0075(4) 0080(2) 0092(1) 0105(1) 0108(3) 0110(1) 0117(1) 0121(2) 0122(5) 0124(1) 0125(1) 0138(6) 0141(1)
0147(1) U148(2) 0159(10)0161(1) 0163(1) 0165(2) 0166(1) 0167(1) 0169(2) 0181(1) 0187(1) 0188(1) 0191(2) 0194(1) 0196(2) 0200(2) 0203(4)
0218(4) 0219(2) 0220(1) U222(1) 0223(1) 0226(2) 0228(2) 0236(2) 0238(1) 0239(3) 0244(1) 0248(1)
P095O) 0209(1) 0210(1) 0211(1) 0220(1) 0223(1) 0225(1) 0226(2) 0228(1) 0239(1)
POOK1) P008O) P016(1) P017(1) P022(1) P023(1) P027(1) P028(1) P075(1) P093(1) P095(1) PIOI(I) P108(2) P116(2) 0003(3) 0007(3) 0009(1)
0010(2) 0012(1) 0020(2) U02K2) 0022(2) O037(1) 0044(4) 0045(2) 0046(1) 0047(1) 0052(1) 0057(1) 0061(1) 0064(1) 0067(1) 0068(2) 0070(1)
0077(1) 0080(2) 0094(1) 0095(1) 0105(1) 0114(1) 0122(3) 0129(1) 0130(1) 0138(4) 0140(1) 0147(1) 0159(3) 0163(1) 0165(2) 0166(1) 0169(3)
0184(1) 0187(2) 0191(3) 0196(2) 0200(1) 0202(1) 0207(1) 0210(5) 0211(3) 0219(3) 0220(2) 0221(1) 0223(8) 0228(3) 0239(3) 0248(1)
P008(1) P014(1) P022(1) P028(1) P037(1) P048(1) P050(1) P05K1) P059(1) P10K1) P123(1) 0003(2) 0005(1) 0006(1) 0007(1) 0009(1) 0010(1)
0011(1) 0012(2) 0014(1) 0018(1) 0019(1) 0021(1) 0022(1) 0034(1) 0036(2) 0037(1) 0043(1) 0044(2) 0050(1) 0056(1) 0064(1) 0067(1) 0068(1)
0070(1) 0077(1) 0080(2) U089(1) 0092(1) 0110(1) 0119(1) 0122(6) 0127(1) 0128(1) 0129(1) 0141(1) 0142(1) 0148(1) 0157(1) 0158(1) 0163(1)
0165(1) 0168(1) 0169(1) 0174(1) 0177(1) 0200(1) 0203(1) 0210(2) 0211(1) 0220(1) 0221(1) 0226(1) 0228(1) 0238(1) 0239(1)
0061(1)
P037(1) P077(1) P095(2) P118(1) 0001(2) U003(1) 0007(1) 0009(2) 0012(6) U019(1) 0021(1) 0033(1) 0034(1) 0037(1) U044(5) 0056(3) 0057(1)
0061(1) 0071(1) 0072(1) 0077(1) 0080(3) U095(1) 0108(1) 0122(4) 0125(1) 0131(1) 0138(1) 0051(1) 0185(1) 0188(1) 0194(1) 0202(1) 0210(2)
0211(2) 0220(2) 0221(1) 0223(3) 0226(5) 0228(4) 0239(3) 0240(2)
0210(1)
0019(1) U037(1) 0038(1) 0077(1) 0122(8) 0220(1) 0239(1)
P024(1) P028(3) P037(1) P077(1) 0001(1) U002(2) 0004(1) 0006(1) 0009(1) UOH(I) U020(1) U024(1) U03K2) 0044(2) 0045(1) U046(1) 0053(1)
0055(2) U057(1) U06U2) 0067(1) 0072(1) 0075(3) 0077(2) 0080(3) 0105(1) 0114(1) 0117(1) U12K2) U122(2) U124(1) 0129(2) O130(1) 0142(1)
0147(2) 0152(1) 0159(3) 0165(1) 0188(1) 0191(1) 0192(1) 0196(1) 0201(1) 0210(1) U219(2) U220(2) 0226(4) 0228(2) 0239(2) 0240(1) 0244(1)
0002(1) U003(2) 0004(1) 0019(1) 0031(1) 0037(1) 0044(1) U056(1) 0077(1) U080(1) U140(1) U169(1) 0191(1) 0220(1) 0239(1)
0138(1) U21K1)
-------
State
•SBXS=S£&=
South Carolina IV
EPA
Region
Tennessee
Texas
Utah
Vermont
Virginia
IV
VI
VIII
I
III
>
Ul
Washington X
West Virginia III
Wisconsin V
Table A-3 (continued)
NUMBER OF FACILITIES IM EACH STATE THAT NAY GENERATE U AND P WASTES
INCLUDED IN BACKGROUND DOCUMENT VOLUMES A, B. AND C
Waste Codes (Nuriber of Facilities)
•m«*MmaBBBX&S3S3SCa£SSXBB*MaSBSKS = 5SS=a3S3 = Catt33SSXS«e*X*SBX3SS2 = SesSSS = = 5 = = 3C = = = = = S = = = S = = = SSS3SS£S = = SS = = = = = == = = = = = S = = S = = = = £ = SSC = SS£ = 3
P008(1) P037(1) U017O) U019(1) 0044(1) U06U1) U072(1> U075(1) U077(1) U080<1) 0108(1) U12KD 0122(4) 0129(2) U130(1) U138(1) UU2(1)
0051(1) U210(2) U21K2) 0219(1) U220(2) U226(2) U228(1) 0239(2) 0240(1)
P022(1) P028(1) P059(1) P069(1) P075(1> U003(1) U012(1> U019(1) U020(1) U053(1) U06K1) U072(1) U112(1) 0124(1) U129(1) U130(1) UUO(1)
0154(1) U159(1) U16K1) U162(1) U197(1) U21K1) U213O) U228(1)
,
P005(2) POU(1) P022(1) P066(2) P069(1) P095(5) P10K1) P1 16(1) P118(1) UOOK3) U002(5) 0003(4) U006(1) U007(1) U008(3) 0009(4) U012(3)
0019(4) U020(1) U025(1) U026(1) U027(1) U03U2) U033(1) O034(2) 0036(1) 0041(2) 0043(5) 0044(3) 0045(1) U052(1) O056(1) 0057(3) U06U2)
U072(1) U073(1) U074(1) U077(3) 0080(4) U08H1) 1)084(1) 0092(1) U105(2) 0106(1) 0108(1) 0112(2) U113(4) U114(1) 0118(1) 0122(10)0123(1)
U129(2) U138(1) U140(4) UU7(1) U05KD 0152(1) 0153(3) 0154(6) U156(1) U159(3) 0161(1) 0162(1) U165(4) U166(1) 0169(1) 0171(1) 0188(3)
um<1) U210(3) U21K4) U213(1) U220(7) 0221(2) (1223(5) U226(2) U228(2) 0239(1) 0240(1)
P054C1)
0044(1)
P018(1) P077(1) 0007(1) U019(2) 0020(1) O036(1) 0044(2) 0057(1) O0&0(1) 0110(1) 0117(1) 0129(1) 0140(1) 0051(1) 0158(1) 0167(1) 0194(1)
U210(3) U21K2) 0219(1) U220(1) U223(2) U226(1) U228(1) 0239(1)
P002(1) P016(1) P022(1) P028(1) P042(2) 0019(1) 0022(1) 0043(1) O044(1) 0055(1) 0056(1) 0064(1) O075(1) U080(1) 0122(2) 0152(1) 0158(2)
U169(1) U1B8(2) 0210(1) U21K1) U219(1) 0220(1) U226(2) U228(1) U239(2) 0240(1)
P004(1) P022(1) P045(1) P064(2) P066(1) P070(2) 0002(2) 0003(1) 0009(2) 0012(2) U044(1) 0045(2) 0053(1) O070O) 0072(1) 0077(1) 1)080(2)
0092(1) U105(2) 0106(2) U108(1) U116(2) U118(1) U122(2) U147(1) UU8(1) 0159(1) 0161(1) 0165(1) 0169(2) 0191(2) 0210(1) 0223(3) 0244(1)
0247(1)
POOK1)
P059(1)
0019(1)
0063(1)
0105(1)
0149(1)
0203(1)
P003(1)
P075(1)
0020(1)
U064(1)
0110(1)
0051(1)
0206(1)
P005(1)
P077(1)
0021(1)
0067(1)
0116(1)
0152(1)
0208(1)
P008(1)
P082(1)
0022(1)
0068(1)
0119(1)
U153(1)
0211(1)
P014(3)
P084(1)
0029(1)
0071(1)
0120(1)
0155(1)
0214(2)
P016(1)
P095(1)
0030(1)
0072(1)
0122(1)
0163(1)
0218(1)
P017(1)
P10K1)
0034(1)
0073(1)
0125(1)
0165(1)
0219(1)
P018(1)
P102(1)
0036(1)
0074(1)
U127(1)
0166(1)
0220(2)
P022(1)
P108(1)
U037(1)
0076(1)
0128(1)
0168(1)
0221(1)
P023O)
0045(1)
0077(1)
0129(1)
0169(1)
0225(1)
P024(1>
P123(1)
0046(1)
0079(1)
0130(1)
0171(1)
0226(1)
P026(1)
0003(1)
0047(1)
0081(1)
0131(1)
0174(1)
0227(1)
P027(1)
0006(1)
0048(1)
0082(1)
0132(1)
0183(1)
0238(1)
P037(1)
0007(1)
0055(1)
0083(1)
0137(1)
0185(1)
0240(1)
P046O)
0009(2)
0056(1)
0084(1)
0138(1)
0187(1)
0243(1)
P051(1)
0010(1)
0057(1)
0089(1)
0142(1)
0193(1)
0247(1)
P054(1)
0012(1)
0060(1)
0092(1)
0147(1)
0200(1)
0248(1)
-------
Appendix B
U AND P CONSTITUENT CHEMICAL STRUCTURES
B-l
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
AROMATICS AND OTHER HYDROCARBON WASTES
(ANALYZABLE)
U01I: B«ns«n«
U220: ToUMit* (m«thylb«nun*)
\_/
V >—
o-Xyt«n*
para»Xyl«n«
U239:
ortho-Xyltna, meta-Xyl«M and para-Xyl«n«
B-2
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
AROMATICS AND OTHER HYDROCARBON WASTES
(NONANALYZABLE)
M
K
M^ ^C.. ..M
U055: Cum«nc (lsopropylb«nz*na)
UOSt: Cyeloh«»n«
H ^CM,
CHjCH.CHCH.CH,
B-3
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
BROMINATED ORGANIC WASTES
(ANALYZABLE)
H
H
-C-Br
\
H
UO 3O M -
H \\ H
» i »
H-C.-C-C-H
« i I
Br Br C\
H H
> l
i
H
Br
\
-C-H
\
6r
B-4
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
BROMINATED ORGANIC WASTES
(NONANALYZABLE)
\A O U
t \\ i
H -C-C-C--
I I
B-5
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
HALOGENATED ALIPHATIC WASTES
(ANALYZABLE)
CL
H C—CL
CL
U044: Chloroform
CL H
I I
CL C C H
I I
H H
U076: 1,1-Dlchloroethane
CL CL
I I
H C C H
I I
H H
U077: 1t2-Dlehloroethan«
M^^^™ C^SSS G™""™ CL
I I
H CL
U078: 1,1-Dlchloroethylene
CL—CsssC—CL
H H
U079: 1,2-Dlchloro«thyi«n«
•CL
U080: M«thyl«n« Chloride
H H H
I I I
C_C
I I
CL CL
I
U083: 1,2-Dlchloropropan«
T T
CL—C C=C—CL
H H
U084: l,3-0lchloroprop«n«
B-6
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
HALOGENATED ALIPHATIC WASTES
(ANALYZABLE) (Continued)
CL CL
I I
CL CL
CL CL
I I
c=c
I I
CL CL
U209: 1,1,2,2-T«trachloro«than« U210: T«traehloro«thyl«n«
CL CL
I I
CL—C—C—H
I I
CL H
U208: 1,1,1,2-Tatrachloroathana
CL CL
I- I
CL—C—C CL
I I
CL CL
U131: Haxachloroethant
CL
CL C—CL
CL
U211: Carbon Tctrachlerld*
CL H
I I
CL—C—C—H
I I
CL H
U226: 1,1,1-Trtehloroathana
CL H
I I
CL C C CL
H H
U227: 1,1,2-Trtchloro«than«
CL-
CL CL
I I
•H
U228: Tricftloro«thyl«n«
B-7
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
HALOGENATED ALIPHATIC WASTES
(ANALYZABLE) (Continued)
T ' T
CL—C—C^=C—CL
CL CL
U243: Hexachloroprop«n«
B-8
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
HALOGENATED ALIPHATIC WASTES
(NONANALYZABLE)
CL CL
I I
H C C:=C C-
I I I I
H H H H
•H
U074: 1,4-Dlchloro-2-Butene
t T
CL—C—C—CL
CL H
UI84: Ptnuehloro«Uinn«
B-9
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
HALOGENATED PESTICIDES AND CHLOROBENZENES
(ANALYZABLE)
ft* P
CJt
B-10
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
HALOGENATED PESTICIDES AND CHLOROBENZENES
(ANALYZABLE) (Continued)
PPP
B-ll
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
HALOGENATED PESTICIDES AND CHLOROBENZENES
(ANALYZABLE) (Continued)
*;<
Cl'
Cl
I
J
a
- BnC
B-12
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
HALOGENATED PESTICIDES AND CHLOROBENZENES
(ANALYZABLE) (Continued)
CI
UlfO
0-WI,
B-13
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
HALOGENATED PESTICIDES AND CHLOROBENZENES
(NONANALYZABLE)
slens)
B-14
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
HALOQENATED PHENOLIC WASTES
(ANALYZABLE)
9-
Z-
B-15
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
OXYGENATED HYDROCARBON AND HETEROCYCUC WASTES
(ANALYZABLE)
W O
I V\
W
UOOM
H H
U H V4
U03I
lull \ \ \ \
C.-C.-0-C-C-H H-C-C-0-C-C-VA
1 ' ' \ \ \ \
« H W U H H H
EtKM\
B-16
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
OXYGENATED HYDROCARBON AND HETEROCYCUC WASTES
(ANALYZABLE) (Continued)
W
t
-C
V
O
\\
»^*> ^
-c-c
\
i-c-w
\
U
H
I
> — *•
•• x«»
i
. H
U\MO
H O H
rf O U U H-C-C-C-C.-H
C.-C-C-0-H i > N
i H H '
\-\ O W
l II *
W-C=C-C-C-H
I *
H-C-IA H
B-17
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
OXYGENATED HYDROCARBON AND HETEROCYCUC WASTES
(NONANALYZABLE)
o u
II I
c-c-w
I
H
I
M
Pooi
(>o.3%)
Poo3
\
W
H
I
W
H
u
W
U00\
B-18
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
OXYGENATED HYDROCARBON AND HETEROCYCLJC WASTES
~ (NONANALYZABLE) (Continued)
\ /
XOC O H-C.-C.C-C-H
v H H
OVA
\\
O
I
C-W
\
I
O I
\ r - v4
\JkO5l C.sjc\oVNeocanoe. ~-
H O H H
\ \\ \ \
C = C.-H-C-0-C -C-H ,
l » i H
H H M
B-19
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
OXYGENATED HYDROCARBON AND HETEROCYCUC WASTES
(NONANALYZABLE) (Continued)
\\
VA\
O
O
/\
H A
I
M
B-20
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
OXYGENATED HYDROCARBON AND HETEROCYCLJC WASTES
- (NONANALYZABLE) (Continued)
lM -
H
-H
noofi.
I
c
i
W
p -
U a 13
B-21
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
WASTES OF A PHARMACEUTICAL NATURE
(ANALYZABLE)
— n— c-c -n
H H
\
i
H-C
I
H
— c-o
I
C
I
H
H O
1 U
n—c
-c- H
i
c
I
H
H —
-VA
0103
B-22
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
WASTES OF A PHARMACEUTICAL NATURE
(NONANALYZABLE)
9001
H-C-H
B-23
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
WASTES OF A PHARMACEUTICAL NATURE
(NONANALYZABLE) (Continued)
UOVO
w
-c
-0-H
H
'» \
B-24
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
WASTES OF A PHARMACEUTICAL NATURE
(NONANALYZABLE) (Continued)
O OH
W
HO-
-.c-«o-(0)-oH
I
U
B-25
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
WASTES OF A PHARMACEUTICAL NATURE
(NONANALYZABLE) (Continued)
— C
OH
=C-C-CHc.H5
H
/ su Nu
U
i
n
U
W H
\ /
n
A
\
. \ (P 3
B-26
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
WASTES OF A PHARMACEUTICAL NATURE
(NONANALYZABLE) (Continued)
H
I
w
,V^\TV^
O— O
/
\ \
\
-C-M
\
M
H
o—o
5)
B-27
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
WASTES OF A PHARMACEUTICAL NATURE
(NONANALYZABLE) (Continued)
n=o
%?vvS
«' Vx-JU
U-C-U
1
tt -C-U
H
n
B-28
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
PHENOUCS
(ANALYZABLE)
OH
U
NO-
POZO
(Dinoseb)
NO,
OH
OH
p-
OH
UIOI Z/Kft'i
OH
OH
Ul??
B-29
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
PHENOUCS
(NONANALYZABLE)
OU
Ort
v;ioi
B-30
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
POLYNUCLEAR AROMATIC WASTES
(ANALYZABLE)
I \/ I
H
I II II I H H
H H
UOOS: 2-Acetylaminofluorene
H
H H
I I I II
I II I I
III
H H H
U018: Benz(a) Anthracene
H H
I I
H
I I II
I II I I
I I I
H H H
UQ22: Benzo(a)pyrene
B-31
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
POLYNUCLEAR AROMATIC WASTES
(ANALYZABLE) (Continued)
H H
I I
H
II II I
I II I I
H H
U050: Chrysena
H
MM — ..
I I I II
H. ^ /^c/SscX^H
II I I
» ' 1 I
H
U063:
B-32
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
POLYNUCLEAR AROMATIC WASTES
(ANALYZABLE) (Continued)
•S^ ^c
r- 1 »
U120: Ruorantti«n«
H
H
H
I I
I II I II I
-.- -. I /% ^/-
II I
H H
U137: lndeno(1,2,3-c,d)pyrene
B-33
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
POLYNUCLEAR AROMATIC WASTES
(ANALYZABLE) (Continued)
r r
H C— - C
I I I
I I II I
^
I I I
I
H
U157: 3-Methylcholanthrene
H H
I
H H
U165: Naphthalene
B-34
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
POLYNUCLEAR AROMATIC WASTES
(NONANALYZABLE)
H H H
II
I I
S^-xC^x
II
w ^
I II
H- y H
H
U016: Benz(c)Acridlna
U064: 1,2,7,8-Olbcnzopyren*
B-35
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
POLYNUCLEAR AROMATIC WASTES
(NONANALYZABLE) (Continued)
H
.H
~^^ ^^^" ~^k. _ .^r~
H Ob ^C
I II
II I I
H
I I I
H cm H
U094: 7,1 2-Dlmethylbenz(a)anthracene
B-36
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
ORGANO-NITROGEN COMPOUND WASTES
(ANALYZABLE)
H \\
I I
H-C-C.-C.
I I
H H
PIO
PO-J-? P-
C.-C.
l' s
M t*n
n
o.
^:X
n
U\O(P
B-37
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
ORGANO-NITROGEN COMPOUND WASTES
(ANALYZABLE) (Continued)
U «
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
ORGANO-NITROGEN COMPOUND WASTES
(ANALYZABLE) (Continued)
W
H-
\
c
H N
C.-C
I \
H H
r-w
rro
\\
B-39
-------
4-
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
ORGANO-NITROGEN COMPOUND WASTES
(NONANALYZABLE)
» mo
H
H
H
r
M
»
G 7,'\/*"• A\ ne.
O
U
1
M
U
— W
VA
B-40
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
ORGANO-NITROGEN COMPOUND WASTES
(NONANALYZABLE) (Continued)
N
in
H C H
j. 1 I
H-C-C-C—H
1 I I
H OH H
O- n\
. 1 X
c*
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
ORGANO-NITROGEN COMPOUND WASTES
(NONANALYZABLE) (Continued)
w
I
H-C--C.
\
Vt
s n
/
U003
\/H
n
i
W-C-H
I
H
v\ H
\ /
n7"^
B-42
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
ORGANO-NITROGEN COMPOUND WASTES
(NONANALYZABLE) (Continued)
\
H
W M H
H-c-V-9\
H U M n.
•^
H-C.-C-C'
i i
B-43
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
ORGANO-NITROGEN COMPOUND WASTES
(NONANALYZABLE) (Continued)
K-H
N=C-
H
1
c-c
i
H
V/°
H O U
1 l I
H-C.-C-C-
OH
ort
n-n-o
^r>/ ^
H
B-44
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
ORGANO-NITROGEN COMPOUND WASTES
(NONANALYZABLE) (Continued)
U
/
V
V >
U
\
• c
I
U
o
II /
H-0-c.-n
\
\A V*
\ i
H-OC
\
W
B-45
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
ORGANO-NITROGEN COMPOUND WASTES
(NONANALYZABLE) (Continued)
/n
-------
CHEMICAL STRUCTURES FOR. U AND P WASTE CODES
ORGANO-SULFUR COMPOUND WASTES
(NONANALYZABLE)
H O
\ \\ \ »
vA-c-c-n-c-n-U
I
H
\
5-H
Pom
Po o£ \ -
H
I
H-C— H
* I V
c -c- c -
H
u
H
I
.— N_L_0_N=-C-.C-S-C-H
H
POM 5*
H
u-c -
5 5
u \i
'm-c-n -c-n
^ i
VA
H
c
i
5
1
-C-H
\
H
o
\\
n-o -c--
H
M
\ /
C
B-A7
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
VA
I
\
VA
U
\
\
U-C-VA
\
\A
ORGANO-SULFUR COMPOUND WASTES
(NONANALYZABLE) (Continued)
o
\\
CX\dL\carb
u
n-c-o'
\
VA -
,u
u
VA
S U
u \
5
u
\
n-c-c-n
S
\1
c-w
/
\
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
ORGANO-SULFUR COMPOUND WASTES
(NONANALYZABLE) (Continued)
H O H H
I U \ *
H-C-5-0-C-C-W
I I I
H H
O VA H H O
VA-5-C-C-C-5-H
C'^>-H »i \ \ \ »
7 O ^ U VA O
VA
u \ 53
H H^ u
xn-t
B-49
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
ORGANO-SULFUR COMPOUND WASTES
(NONANALYZABLE) (Continued)
v * s y
u/ \ u u / \
H n-c-s-s-c-n Hn
VH
344
B-50
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
MISCELLANEOUS HALOQENATED ORGANIC WASTES
(ANALYZABLE)
M H H
I I I
QJt-C-C-O- O-M
I I I
W W H
H H
11
H H
H H
It
C.-C
II
MM
K H H
i \ \
CJl -(L-C.-C. -
1 l ',
H O V4
CJl -
c.-C.-d.-CJl
\ I I
W OH W
UO 3-7
B-51
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
MISCELLANEOUS HALOGENATED ORGANIC WASTES
(ANALYZABLE) (Continued)
N
/
U -C-
I
H
(Lfi
\
•C-F
i
F
"D\
OF
I
H
i
-c-x
\
B-52
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
MISCELLANEOUS HALOGENATED ORGANIC WASTES
(ANALYZABLE) (Continued)
M,4
B-53
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
MISCELLANEOUS HALOGENATED ORGANIC WASTES
(NONANALYZABLE)
VA
\
H
tt H
k l
c.-c.
1
H
H
/rrv i u /
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
MISCELLANEOUS HALOGENATED ORGANIC WASTES
(NONANALYZABLE) (Continued)
H Q
i \\
dfi
ac-v
H
c,
T r \
*s
o
C\
aon
B-55
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
MISCELLANEOUS HALOGENATED ORGANIC WASTES
(NONANALYZABLE) (Continued)
Chlor
LAO33
mj1
W
1 I
-C. -
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
MISCELLANEOUS HALOGENATED ORGANIC WASTES
(NONANALYZABLE) (Continued)
*x /H
n «s ,H
c
NV4
>Xor>
B-57
-------
APPENDIX C
PROBLEMS ENCOUNTERED IN TREATMENT STANDARD
CALCULATIONS PRECLUDING PROMULGATION OF NUMERICAL STANDARDS
C-l
-------
APPENDIX C
PROBLEMS ENCOUNTERED IN TREATMENT STANDARD
CALCULATIONS PRECLUDING PROMULGATION OF CONCENTRATION-BASED STANDARDS
Treatment standards for the majority of wastewater forms of the U
and P wastes covered volumes A, B, and C were calculated based on the waste-
water treatment database compiled by the Agency for establishing standards for
multi-source leachate (F039) (See Background Document for U and P wastes and
Multi-Source Leachates, Volume A). Wastewater treatment performance data were
not available for the constituent of concern in UO 91 (3,3'-Dimethoxy-
benzidine) and U095 (3,3'-DimethyIbenzidine). Therefore, concentration-based
standards could not be calculated and a method of treatment was established
for the wastewater forms of these waste codes.
Treatment standards for the majority of nonwastewater forms of the U
and P wastes covered in volumes A, B, and C were calculated based on data
compiled from the BDAT incineration database for incinerator ash residuals.
(See the Background Document for U and P Wastes and Multi-Source Leachates,
Volumes C.) Specifically, the Agency considered treatment performance data
from the 14 incineration tests conducted under the BDAT program (see Table 4-
1). Nonwastewater treatment standards for waste constituents selected for
regulation were calculated by multiplying the constituent detection limit in
ash by an accuracy correction factor and by a variability factor. These three
components of the treatment standard calculation are discussed below.
C.I Detection Limits
U and P waste constituent detection limits for the ash residuals
were used to calculate treatment standards for nonwastewater forms of the U
and P wastes. In cases where the waste constituent was detected in the
untreated waste from more than one incineration test, the treatment standard
was based on the highest detection limit for that constituent in the ash
residual. For waste constituents not detected in any of the 14 tests, the
C-2
-------
highest detection limit reported for that constituent in the ash residual from
the 14 treatment tests was used.
C.2 Accuracy Correction Factors
The detection limits used to calculate treatment standards were
corrected to account for analytical interferences associated with the sample
matrices. To do this, the Agency used the matrix spike recovery data from
that same test from which the detection limits were taken. Detection limits
were corrected for accuracy as follows:
1. A matrix spike recovery was determined for each waste con-
stituent. In cases where a matrix spike recovery was not per-
formed for a waste constituent from the treatment test for which
the detection limit was used, the matrix spike recovery for a
similar constituent from that treatment test was transferred to
that constituent.
2. An accuracy correction factor was calculated by dividing 100 by
the matrix spike recovery (percent) for that constituent.
3. Detection limits for each waste constituent were corrected by
multiplying the detection limit for each constituent by its
corresponding accuracy correction factor.
C.3 Variability Factors
The variability factor accounts for the variability inherent in
treatment system performance, treatment residual.collection, and analysis of
the treated waste samples. If a constituent was present above the detection
limit in the ash from the test from which the detection limit was transferred,
a variability factor was calculated using the data from that test. Varia-
bility factors could not be calculated for waste constituents that were not
detected in the incinerator ash residuals. In these cases, a variability
factor of 2.8 was used to account for this inherent variability. The vari-
ability factor calculation is described in EPA's Methodology for Developing
BOAT Treatment Standards (Reference 1).
C-3
-------
C.4 U and P Waste Constituents Amenable to Quantification Having Method
of Treatment Set as BOAT Treatment Standard
Four U and P waste constituents are amenable to analytical quanti-
fication, yet methods of treatment have been established as the BOAT treatment
standard. These constituents are:
P003 Acrolein;
U042 2-Chloroethyl vinyl ether;
U091 3,3'-Dimethoxybenzidine; and
U095 3-3'-Dimethylbenzidine.
Using the treatment standard calculation methodology described
above, the standards that were calculated for these waste codes ranged from
970 ppm - 2,400 ppm. The Agency does not believe that treatment standards of
this magnitude are representative of substantial treatment for these organic
constituents. In addition, the constituent detection limits ranged over five
to six orders of magnitude, with none determined to be outliers. The detec-
tion limit ranges for these constituents are shown below:
U and P Wastes Detection Limit Range
Acrolein 0.01 - 500 ppm
2-Chloroethyl vinyl ether 0.01 - 200 ppm
3,3'-Dimethoxybenzidine 0.42 - 500 ppm
3,3'-Dimethylbenzidine 0.55 - 500 ppm
This broad range of detection limits suggests that analyses for these con-
stituents are difficult in incinerator ash matrices due to matrix inter-
ferences .
Based on the above discussion, the Agency is specifying methods of
treatment as the treatment standards for these waste codes. The determination
of treatment standards for these waste codes is discussed further in Section
4.0 of this document.
C-4
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