FINAL
BEST DEMONSTRATED AVAILABLE TECHNOLOGY (BOAT)
BACKGROUND DOCUMENT
FOR
U AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
VOLUME C:
NONWASTEWATER FORMS OF ORGANIC U AND P WASTES AND
MULTI-SOURCE LEACHATE (F039) FOR WHICH THERE ARE
CONCENTRATION-BASED TREATMENT STANDARDS
Richard Kinch
Acting Chief, Waste Treatment Branch
Lisa Jones
Project Manager
U.S. ENVIRONMENTAL PROTECTION AGENCY
Office of Solid Waste
401 M Street, S.W.
Washington, D.C. 20460
May 1990
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TABLE OF CONTENTS
1.0 INTRODUCTION 1-1
1.1 Regulatory Background 1-1
1.2 User's Guide to the Five-Volume U and P Waste and
Multi-Source Leachate (F039) Background Document
Set 1-3
1.3 Summary of Contents: Volume C 1-4
2.0 INDUSTRY AFFECTED AND WASTE CHARACTERIZATION 2-1
2.1 Industry Affected and Process Description 2-1
2.1.1 U and P wastes 2-1
2.1.2 Multi-Source Leachate (F039) 2-2
2.2 Waste Characterization 2-3
2.3 Determination of Waste Treatability Groups .... 2-3
2.3.1 Aromatic Wastes 2-4
2.3.2 Brominated Organic Wastes 2-4
2.3.3 Halogenated Aliphatic Wastes 2-4
2.3.4 Halogenated Pesticide and Chlorobenzene
Wastes 2-5
2.3.5 Halogenated Phenolic Wastes 2-6
2.3.6 Oxygenated Hydrocarbon and Heterocyclic
Wastes 2-6
2.3.7 Wastes of a Pharmaceutical Nature .... 2-7
2.3.8 Phenolic Wastes 2-7
2.3.9 Polynuclear Aromatic Wastes 2-8
2.3.10 Organo-nitrogen Compound Wastes 2-8
2.3.11 Miscellaneous Halogenated Organic
Wastes 2-9
2.3.12 Multi-Source Leachate (F039) 2-9
3.0 IDENTIFICATION OF BEST DEMONSTRATED AND AVAILABLE
TECHNOLOGY (BOAT) 3-1
3.1 Applicable Treatment Technologies 3-2
3.1.1 Organic Constituents 3-2
3.1.2 Metal Constituents 3-4
3.2 Demonstrated Treatment Technologies 3-5
3.2.1 Organic Constituents 3-5
3.2.2 Metal Constituents 3-8
3.3 Identification of Best Demonstrated and
Available Technology (BOAT) 3-8
3.3.1 Organic Constituents 3-9
3.3.2 Metal Constituents 3-10
4.0 TREATMENT PERFORMANCE DATA 1
4.1 U and P Nonwastewaters 3
4.1.1 Brominated Organic Wastes 3
4.1.2 Halogenated Pesticides and Chlorobenzenes . 4
4.1.3 Polynuclear Aromatic Wastes 4
4.2 Multi-Source Leachate (F039) 5
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TABLE OF CONTENTS (Continued)
5.0 SELECTION OF REGULATED CONSTITUENTS 5-1
5.1 U and P Wastes 5-1
5.1.1 U051 - Creosote 5-1
5.1.2 U052 - Cresols '. 5-1
5.1.3 U060 and U061 - ODD and DDT 5-2
5.1.4 U084 - 1,3-Dichloropropene 5-2
5.1.5 U129 - gamma-BBC (Lindane) 5-2
5.1.6 P050 - Endosulfan 5-3
5.1.7 P051 - Endrin and Metabolites 5-3
5.1.8 P059 - Heptachlor 5-3
5.2 Multi-Source Leachate (F039) 5-3
5.2.1 Constituents Selected for Regulation . . 5-4
5.2.2 Constituents Not Selected for Regulation 5-5
6.0 CALCULATION OF BOAT TREATMENT STANDARDS 6-1
6.1 Treatment Standard Calculation Methodology for U and
P Wastes . . . '. 6-1
6.1.1 Detection Limits 6-2
6.1.2 Accuracy Correction Factors 6-3
6.1.3 Variability Factors 6-4
6.2 Detailed Discussion of Organic U and P Waste Treatment
Standard Calculations 6-5
6.2.1 Aromatic Wastes 6-5
6.2.2 Brominated Organic Wastes 6-5
6.2.3 Halogenated Aliphatic Wastes 6-5
6.2.4 Halogenated Pesticide and Chlorobenzene
Wastes 6-6
6.2.5 Halogenated Phenolics Wastes 6-7
6.2.6 Miscellaneous Halogenated Organic Wastes 6-7
6.2.7 Organo-nitrogen Compound Wastes 6-8
6.2.8 Oxygenated Hydrocarbon and Heterocyclic
Wastes 6-8
6.2.9 Wastes of a Pharmaceutical Nature .... 6-9
6.2.10 Phenolics 6-9
6.2.11 Polynuclear Aromatic Wastes 6-9
6.3 Detailed Discussion of Treatment Standard Calculations
for Multi-Source Leachate (F039) Constituents ... 6-10
6.3.1 Multi-Source Leachate (F039) Constituents
With a Corresponding U or P Waste .... 6-11
6.3.2 Multi-Source Leachate (F039) Constituents
Without a Corresponding U or P Waste . . 6-12
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TABLE OF CONTENTS (Continued)
Page
7.0 ACKNOWLEDGEMENTS 7-1
8.0 REFERENCES 8-1
APPENDIX A - U and P Waste Generator Information A-l
APPENDIX B - Chemical Structure For U And P Waste Codes . . B-l
APPENDIX C - Supplemental Treatment Performance Data ... C-l
APPENDIX D - Accuracy Correction of Data D-l
APPENDIX E - Variability Factor Calculations . E-l
iii
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LIST OF TABLES
1-1 TREATMENT STANDARDS FOR U AND P WASTES AND MULTI-SOURCE
LEACHATE (F039) INCLUDED IN VOLUME A, B, AND C; BY WASTE
CODE 1-7
1-2 TREATMENT STANDARDS FOR U AND P WASTES AND MULTI-SOURCE
LEACHATE (F039) INCLUDED IN VOLUMES A, B, AND C;
ALPHABETICALLY 1-13
1-3 TREATMENT STANDARDS FOR U AND P NONWASTEWATERS AND
MULTI-SOURCE LEACHATE (F039) INCLUDED IN VOLUME C 1-24
2-1 TREATABILITY GROUPS FOR NONWASTEWATER FORMS OF ANALYZABLE
ORGANIC U AND P WASTES AND MULTI-SOURCE LEACHATE (F039) . . . 2-10
4-1 WASTES TESTED BY INCINERATION 4-6
4-2 SUMMARY OF DETECTION LIMITS FOR WASTE CONSTITUENTS FROM
THE FOURTEEN EPA INCINERATION TESTS 4-7
4-3 TREATMENT PERFORMANCE DATA COLLECTED BY EPA FOR ETHYLENE
DIBROMIDE (EDB) AT ROLLINS ENVIRONMENTAL SERVICES, INC.
(TEXAS) - INCINERATION 4-11
4-4 DESIGN PARAMETERS FOR THE INCINERATOR SYSTEM AT ROLLINS
ENVIRONMENTAL SERVICES, INC. (TEXAS) 4-12
5-1 BOAT LIST CONSTITUENTS SELECTED FOR REGULATION IN
NONWASTEWATER FORMS OF ORGANIC U AND P WASTES 5-7
5-2 REGULATED MULTI-SOURCE LEACHATE (F039) CONSTITUENTS 5-11
5-3 NONWASTEWATER CONSTITUENTS NOT REGULATED IN MULTI-SOURCE
LEACHATE (F039) AND REGULATED CONSTITUENTS THAT CONTROL
THEIR TREATMENT 5-15
6-1 TREATMENT STANDARD CALCULATIONS FOR NONWASTEWATER U AND P
WASTES AND FOR MULTI-SOURCE LEACHATE (F039) 6-13
6-2 TREATMENT STANDARD CALCULATIONS FOR NONWASTEWATER U AND P
WASTES THAT ARE BASED ON PERFORMANCE DATA OTHER THAN
THE ELEVEN INCINERATION TESTS 6-17
6-3 TREATMENT STANDARD CALCULATIONS FOR MULTI-SOURCE LEACHATE
(F039) CONSTITUENTS THAT ARE BASED ON PERFORMANCE DATA
OTHER THAN THE ELEVEN INCINERATION TESTS 6-18
6-4 NONWASTEWATER TREATMENT STANDARDS FOR MULTI-SOURCE LEACHATE
(F039) CONSTITUENTS 6-21
IV
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1.0
INTRODUCTION
1.1
ReEulatorv Background
Section 3004(m) of the Resource Conservation and Recovery Act
(RCRA), as amended by the Hazardous and Solid Waste Amendments (HSWA) on
November 8, 1984, requires the U.S. Environmental Protection Agency (EPA or
the Agency) to promulgate treatment standards for certain hazardous wastes
based on the Best Demonstrated Available Technology (BOAT) for those wastes.
More than 500 of these hazardous wastes were listed as of December 1988 (see
Title 40, Code of Federal Regulations. Part 261 (40 CFR Part 261)). The
Agency divided the listed hazardous wastes into five groups. The wastes in
each group were examined to determine whether further land disposal is protec-
tive of human health and the environment (see 40 CFR Part 268). The five
groups and their respective dates of promulgation of treatment standards are:
Solvent and dioxin wastes
"California List" wastes
"First Third" wastes
"Second Third" wastes
"Third Third" wastes
November 7, 1986
July 8, 1987
August 8, 1988
June 8, 1989
On or before May 8, 1990
Several wastes included in this schedule were regulated ahead of schedule, and
several wastes in the "First Third" or "Second Third" group of wastes were
deferred to the "Third Third" group of wastes. Treatment standards for the
Third Third wastes will become effective no later than May 8, 1990. On and
after this date, wastes regulated in the "Third Third" rulemaking will have to
comply with applicable treatment standards prior to "land disposal" as defined
in 40 CFR Part 268.
This document provides the Agency's rationale and technical support
for developing concentration-based treatment standards for organic
constituents in U and P nonwastewaters, for lead in U051 nonwastewaters, and
for constituents in multi-source leachate nonwastewaters (F039). These
standards are applicable to the wastes as listed as well as to any wastes
generated by the management or treatment of the listed wastes. For the
purpose of determining the applicability of the treatment standards,
1-1
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wastewaters are defined as wastes containing less than 1% (weight basis) total
suspended solids1 and less than 1% (weight basis) total organic carbon (TOC).
Wastes not meeting the wastewater definition must comply with treatment
standards for nonwastewaters.
In general, numerical treatment standards were developed for wastes
that are amenable to quantification in hazardous waste matrices, and treatment
standards specifying methods of treatment were developed for wastes that are
not amenable to quantification in hazardous waste matrices using current
analytical methods.
The Agency's legal authority and promulgated methodology for
establishing treatment standards and the petition process for requesting a
variance from the treatment standards are summarized in EPA's Methodology for
Developing BOAT Treatment Standards (Reference 2).
U wastes include discarded commercial chemical products,
manufacturing intermediates, off-specification commercial products, container
or inner liner residues, and residues, contaminated water, soil, or debris
resulting from a cleanup of a spill that are identified as toxic wastes.
F wastes include discarded commercial chemical products, manufacturing
intermediates, off-specification commercial products, container or inner liner
residues, and residues, contaminated water, soil, or debris resulting from a
cleanup of a spill that are identified as acutely hazardous wastes.
Multi-source leachate (F039) is any liquid, including any suspended
components in the liquid, that has percolated through, or drained from the
treatment, storage, or disposal of more than one listed hazardous waste.
'The term "total suspended solids" (TSS) clarifies EPA's previously used
terminology of "total solids" and "filterable solids." Specifically, total
suspended solids are measured by Method 209c (Total Suspended Solids Dried at
103 to 105°C) in Standard Methods for the Examination of Water and Wastewater
(Reference 1).
1-2
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1.2 User's Guide to the Five-Volume U and P Waste and Multt-Source
Leachate (F039) Background Document Set
In the interest of clarity, the Agency has reorganized the "Third
Third" background documents that were prepared for proposal of the Third Third
Rule. Multi-Source leachate (F039) and the majority of the U and P waste
codes addressed in the Third Third Rule are now covered in a five-volume set
of background documents.
The five-volume background document set is organized as follows.
• Volume A - Wastewater forms of organic U and P wastes and
multi-source leachate (F039) for which there are concentration-
based treatment standards;
• Volume B - U and P wastewaters and nonwastewaters with methods
of treatment as treatment standards;
• Volume C (this document) - Nonwastewater forms of organic U and
P wastes and multi-source leachate (F039) for which there are
concentration-based treatment standards;
• Volume D - Reactive U and P wastewaters and nonwastewaters with
methods of treatment as treatment standards; and
• Volume E - Gases.
Volumes A, B, and C each have a set of cross-referenced tables that
are intended as a guide to help the reader locate a particular waste code or
constituent and its treatment standard, for the codes included within the
first three volumes of the set. These tables list the volume in which the
nonwastewater and wastewater forms of each waste code and multi-source
leachate (F039) are discussed, and the corresponding regulated constituents
and treatment standards. Table 1-1 is organized by waste code. Table 1-2 is
organized alphabetically by regulated constituent. (All tables are presented
at the end of Section 1.0.)
1-3
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1 . 3 $ ijiipfliflrv of Contents '.
This background document provides the Agency's rationale and
technical support for selecting constituents for regulation and for developing
concentration-based treatment standards for the nonwastewater forms of organic
U and P wastes and for the nonwastewater forms of multi-source leachate (F039)
listed in Table 1-3.
A description of the industry that may be affected by these land
disposal restrictions, the processes generating these wastes, and the avail-
able waste characterization data is presented in Section 2.0. Section 2.0
also includes EPA's rationale for combining the waste codes included in this
document into twelve treatability groups.
EPA's rationale for identifying BOAT for wastes included in this
document is presented in Section 3.0. Specifically, BDAT has been identified
as incineration for organic constituents in nonwastewater U and P wastes and
in multi-source leachate (F039) , and as stabilization for metal constituents
in U051 and multi-source leachate (F039).
Section 4.0 contains treatment performance data the Agency used to
determine BDAT and to calculate treatment standards for the wastes included in
this document. The Agency has treatment performance data from two rotary kiln
incineration tests EPA performed in June 1989 for waste constituents from
several of the waste treatability groups. The Agency also has treatment
performance data from 12 other incineration tests performed by EPA for
previous rulemakings for the BDAT program.
EPA's rationale for selecting constituents for regulation is
presented in Section 5.0. Due to the lack of characterization data for
U and P nonwastewaters , only the constituent for which the waste was listed
was considered for regulation, with the exceptions of U051, U052, U060, U061,
U084, U129, P050, P051, and P059, for which additional constituents were
selected for regulation.
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Multi-source leachate (F039) constituents selected for regulation
are presented in Table 5-2. The Agency believes that regulation of these
constituents will control the remaining constituents, as presented in
Table 5-3.
Section 6.0 includes the calculation of treatment standards for the
regulated constituents in the nonwastewater forms of the U and P wastes and
the nonwastewater forms of multi-source leachate (F039) listed in Table 1-3.
The units used for total constituent concentration of organic constituents are
rog/kg (parts per million on a weight-by-weight basis) for the nonwastewater
forms of these wastes. BOAT treatment standards for U and P wastes and multi-
source leachate included in this document were determined based on treatment
performance data (discussed in Section 4.0).
Generally, if a U or P waste constituent is on the BDAT List, the
Agency prefers to develop a concentration-based treatment standard for that
constituent, rather than a treatment standard specified as a method of
treatment. However, it may not always be appropriate to set concentration-
based treatment standards for certain constituents, as discussed in Volume B:
U and P Wastewaters and Nonwastewaters with Methods of Treatment as Treatment
Standards.
For two waste codes, U240 (2,4-dichlorophenoxyacetic acid and salts
and esters) and P047 (4,6-dinitro-o-cresol and salts), the Agency is
specifying both concentration-based treatment standards and a method of
treatment as the treatment standard. Because 2,4-dichlorophenoxyacetic acid
salts and esters and 4,6-dinitro-o-cresol salts are not analyzed as 2,4-
dichlorophenoxyacetic acid or 4,6-dinitro-o-cresol, numerical treatment
standards for 2,4-dichlorophenoxyacetic acid and 4,6-dinitro-o-cresol do not
necessarily represent treatment of salts and esters of these wastes. Where a
facility can reasonably assume that only 2,4-dichlorophenoxyacetic acid or
4,6-dinitro-o-cresol is being handled, only the concentration-based treatment
standards for 2,4-dichlorophenoxyacetic acid and 4,6-dinitro-o-cresol (as
discussed in this volume) would apply. However, should one expect that salts
or esters could be formed during storage, treatment, or disposal, the U240 and
1-5
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P047 nonwastewaters would have to be incinerated, in accordance with the BOAT
treatment standard discussed in Volume B.
Section 7.0 acknowledges the persons involved in developing the
regulation for these wastes. Section 8.0 includes references cited in this
document.
Industries that may generate the wastes regulated under the Third
Third Land Disposal Restrictions rule, and the approximate number and
geographic distribution of the facilities, are listed in Appendix A. The
chemical structures of the U and P wastes included in this background document
are listed in Appendix B. Appendix C contains treatment performance data to
supplement the data presented in Section 4.0. Appendix D includes relevant
QA/QC information corresponding to treatment performance data presented in
Section 4.0. Appendix E includes variability factor calculations
corresponding to treatment standard calculations presented in Section 6.0.
1-6
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Table 1-1
TREATMENT STANDARDS FOR U AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C; BY WASTE CODE
Wasteuater Nonwasteuater
Waste
Code
F039
P001
P002
P003
P004
POOS
P007
POOS
POU
P016
P017
P018
P020
P022
P023
P024
P026
P027
P028
P03A
P037
P042
P045
P046
P047
P047
P048
P049
P050
P050
P050
P051
P051
P054
P057
P058
P059
P059
P060
P064
P066
P067
P069
P070
Regulated Constituents
Multi -Source Leachate Constituents - Refer
Warfarin (>0.3%)
l-Acetyl-2-thiourea
Acrolein
Aldrin
Allyl alcohol
S-Aminomethyl-3-isoxazolol
4 - Ami nopy r i d i ne
Thiophenol (Benzenethiol)
B i s(ch I oromethy I ) ether
Bromoacetone
Brucine
2-sec-Butyl -4,6-dinitrophenol (Dinoseb)
Carbon disulfide
Chloroacetaldehyde
p-Chloroani line
1 - ( o- Ch 1 oropheny 1 ) th i ourea
3-Chloropropionitri le
Benzyl chloride
2-Cyclohexyl-4,6-dinitrophenol
Dieldrin
Epinephrine
Thiofanox
alpha.alpha-Dimethylphenethylamine
4,6-Dini tro-o-cresol
4,6-Dini tro-o-cresol salts
2,4-Dini trophenol
2,4-Dithiobiuret
Endosulfan I
Endosulfan 1 1
Endosulfan sulfate
Endrin
Endrin aldehyde
Aziridine
Fluoroacetamide
Fluoroacetic acid, sodium salt
Heptachlor
Heptachlor epoxide
Isodrin
Isocyanic acid, methyl ester
Methomyl
2-Methylaziridine
Methyllactonitrile
Aldicarb
Document
to Table 1-2
B
B
A
A
B
B
B
B
B
B
B
A
A
B
A
B
B
B
B
A
B
B
B
A
B
A
B
A
A
A
A
A
B
B
B
A
A
A
B
B
B
B
B
Treatment
Standard (mg/l) *
for Treatment Standards
BDAT
BDAT
0.29
0.021
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
0.066
O.OH
BDAT
0.46
BDAT
BDAT
BDAT
BOAT
0.017
BOAT
BDAT
BDAT
0.28
BDAT
0.12
BDAT
0.023
0.029
0.029
0.0028
0.025
BDAT
BDAT
BDAT
0.0012
0.016
0.021
BDAT
BDAT
BDAT
BDAT
BDAT
Document
for each
B
B
B
C
B
B
B
B
B
B
B
C
B
8
C
B
B
B
B
C
B
B
B
C
B
C
B
C
C
C
C
C
B
B
B
C
C
C
B
B
B
B
B
Treatment
Standard (mg/kg) **
Regulated Constituent
BDAT-FS
BDAT
BDAT-FS
0.066
BDAT-FS
BDAT
BDAT
BDAT
BOAT
BDAT
BOAT
2.5
BDAT
BDAT
16
BDAT
BDAT
BDAT
BDAT
0.13
BDAT
BDAT
BDAT
160
BOAT
160
BDAT
0.066
0.13
0.13
0.13
0.13
BDAT
BDAT
BDAT
0.066
0.066
0.066
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT for wastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
BDAT for nonwastewaters is incineration but fuel substitution is also BDAT for the waste codes marked as BDAT-FS.
1-7
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Table 1-1 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C; BY WASTE CODE
Wastewater Nonwastewater
Waste
Code
P072
P075
P077
P082
P084
P088
P093
P095
P101
P102
P108
P116
P118
P123
U001
U002
U003
U004
U005
U006
U007
U008
U009
U010
U011
U012
U014
U015
U016
U017
U018
U019
U020
U021
U022
U024
U025
U026
U027
U029
U030
U031
U033
U034
U035
Regulated Constituents
1-Naphthyl-2-thiourea
Nicotine and salts
p-Ni troani line
N-Nitrosodimethylamine
N-Nitrosomethylvinylamine
Endothall
N-Phenylthiourea
Phosgene
Ethyl cyanide (Propanenitri le)
Propargyl alcohol
Strychnine and salts
Thiosemicarbazide
Trichloromethanethiol
Toxaphene
Acetaldehyde
Acetone
Acetonitri le
Acetophenone
2-Acetylaminof luorene
Acetyl chloride
Aery I amide
Acrylic acid
Acrylonitri le
Mitomycin C
Ami t role
Ani line
Auramine
Azaserine
Benz(c)acridine
Benzal chloride
Benz(a)anthracene
Benzene
Benzene sulfonyl chloride
Benzidine
Benzo(a)pyrene
8is(2-chlorbethoxy)methane
Bis(2-chloroethyl)ether
Chlornaphazine
Bis(2-chloroisopropyl)ether
Bromomethane (Methyl bromide)
4-Bromophenyl phenyl ether
n-Butyl alcohol
Carbonyl fluoride
Trichloroacetaldehyde (Chloral)
Chlorambuci I
Document
B
B
A
A
B
B
B
B
A
B
B
B
B
A
8
A
A
A
A
B •
B
B
A
B
B
A
B
B
B
B
A
A
B
B
A
A
A
B
A
A
A
A
B
B
B
Treatment
Standard (mg/l) *
BDAT
BOAT
0.028
0.40
BDAT
BDAT
BDAT
BDAT
0.24
BDAT
BDAT
BDAT
BDAT
0.0095
BDAT
0.28
0.17
0.010
0.059
BOAT
BDAT
BDAT
0.24
BDAT
BDAT
0.81
BDAT
BDAT
BDAT
BDAT
0.059
0.14
BDAT
BDAT
0.061
0.036
0.033
BDAT
0.055
0.11
0.055
5.6
BDAT
BOAT
BDAT
Document
B
B
C
B
B
B
B
B
C
B
B
B
B
C
B
C
B
C
C
B
B
B
C
B
B
C
B
B
B
B
C
C
B
B
C
C
C
B
C
C
C
C
B
B
B
Treatment
Standard (mg/kg) **
BDAT
BDAT
28
BDAT
BOAT
BDAT-FS
BDAT
BDAT
360
BDAT-FS
BDAT
BDAT
BDAT
1.3
BDAT
160
BDAT
9.7
140
BDAT
BDAT
BDAT-FS
84
BDAT
BDAT
14
BDAT
BDAT
BDAT-FS
BDAT
8.2
36
BDAT
BDAT
8.2
7.2
7.2
BDAT
7.2
15
15
2.6
BDAT
BDAT
BDAT
* BOAT for wastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
** BOAT for nonwastewaters is incineration but fuel substitution is also BOAT for the waste codes marked as BDAT-FS.
1-8
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Table 1-1 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C; BY UASTE CODE
Uastewater Nonwastewater
Waste
Code
U036
U037
U038
U039
U041
U042
U043
U044
U045
U046
U047
U048
U049
U050
U051
U051
U051
U051
U051
U051
U05.1
U052
U052
U053
U055
U056
U057
U059
U060
U060
U061
U061
U061
U061
U061
U061
U062
U063
U064
U066
U067
U068
U070
U071
U072
Regulated Constituents
Chlordane (alpha and gamma)
Chlorobenzene
Chlorobenzilate
p-Chloro-m-cresol
1-Chloro-2,3- epoxypropane ( Epi ch I orohydr in)
2-Chloroethyl vinyl ether
Vinyl chloride
Chloroform
Chloromethane (Methyl chloride)
Chloromethyl methyl ether
2-Chloronaphthalene
2-Chlorophenol
4-Chloro-o-toluidine hydrochloride
Chrysene
Creosote • Lead
Creosote - Naphthalene
Creosote - Pentachlorophenol
Creosote - Phenanthrene
Creosote - Pyrene
Creosote - Toluene
Creosote - Xylenes (total)
Cresol (m- and p- isomers)
o-Cresol
Crotonaldehyde
Cumene
Cyclohexane
Cyclohexanone
Daunomycin
o,p'-DDD
p,p'-DDD
o,p'-DDD
p,p'-DDD
o,p'-DDE
P.P'-DDE.
o,p'-DDT
p,p'-DDT
Diallate
Dibenz(a,h)anthracene
1,2,7,8-Dibenzopyrene
1 ,2-Dibromo-3-chloropropane
1,2-Dibromoethane (Ethylene Oi bromide)
D i bromomethane
o-Di chlorobenzene
m-D i ch lorobenzene
p-Dichlorobenzene
Document
A
A
A
A
B
B
A
A
A
B
A
A
B
A
A
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A
A
A
A
A
A
A
B
B
B
A
B
A
A
A
A
A
A
A
A
B
A
B
A
A
A
A
A
A
Treatment
Standard (mg/l) *
0.0033
0.057
0.10
0.018
BOAT
BOAT
0.27
0.046
0.19
BOAT
0.055
0.044
BOAT
0.059
0.28
0.059
0.089
0.059
0.067
0.080
0.32
0.77
0.11
BOAT
BOAT
BOAT
0.36
BOAT
0.023
0.023
0.023
0.023
0.031
0.031
0.0039
0.0039
BOAT
0.055
BOAT
0.11
0.028
0.11
0.088
0.036
0.090
Document
C
C
B
C
B
B
C
C
C
B
C
C
B
C
C
C
C
C
C
C
C
C
C
B
B
B
B
B
C
C
C
C
C
C
C
C
B
C
B
C
C
C
C
C
C
Treatment
Standard (mg/kg) **
0.13
5.7
BOAT
14
BOAT
BOAT
33
5.6
33
BOAT
5.6
5.7
BOAT
8.2
0.51 a
3.1
7.4
3.1
8.2
28
28
3.2
5.6
BDAT-FS
BDAT-FS
BDAT-FS
BDAT-FS
BDAT
0.087
0.087
0.087
0.087
0.087
0.087
0.087
0.087
BDAT
8.2
BDAT-FS
15
15
15'
6.2
6.2
6.2
* BDAT for wastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
** BDAT for nonwastewaters is incineration but fuel substitution is also BDAT for the waste codes marked as BDAT-FS.
a Units for the lead standard are mg/l; analyzed by TCLP extract.
1-9
-------
Table 1-1 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND MULT I-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, 8, AND C; BY WASTE CODE
Wastewater Nonwastewater
Waste
Code
U073
U074
U074
U075
U076
U077
U078
U079
U080
U081
U082
U083
U084
U084
U085
U089
U090
U091
U092
U093
U094
U095
U097
U101
U105
U106
U108
U110
U111
U112
U113
U1U
U115
U116
U117
U118
U119
U120
U121
U122
U123
U124
U125
U126
Regulated Constituents
3,3' -Dichlorobenzidine
cis-1 ,4-Dichloro-2-butene
trans- 1,4-Dichloro-2-butene
Dichlorodif luoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethylene
trans-1,2-Dichloroethylene
Methylene chloride
2,4-Dichlorophenol
2,6-Dichlorophenol
1 ,2-Dichloropropane
cis-1, 3-D ichloropropylene
trans-1,3-Dichl oropropy I ene
1 ,2:3,4-Diepoxybutane
Diethylsti Ibestrol
Dihydrosafrole
3,3'-Dimethoxybenzidine
D i methyl ami ne
p-D i methyl ami noazobenzene
7,12-Dimethyl benz(a)anthracene
3,3' -Dimethylbenzidine
Dimethylcarbamoyl chloride
2,4-Dimethylphenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
1,4-Dioxane
Dipropylamine
Di-n-propylnitrosamine
Ethyl acetate
Ethyl acrylate
Ethylene bis-di thiocarbamic acid
Ethyl ene oxide
Ethylene thiourea
Ethyl ether
Ethyl methacrylate
Ethyl methanesulfonate
Fluoranthene
T r i ch I oromonof luoromethane
Formaldehyde
Formic acid
Furan
Furfural
Glycidylaldehyde
Document
B
B
B
A
A
A
A
A
A
A
A
A
A
A
B
B
B
B
B
B
B
B
B
A
A
A
A
B
A
A
B
B
A
B
A
A
B
A
A
B
B
B
B
B
Treatment
Standard (mg/l) *
BOAT
BOAT
BDAT
0.23
0.059
0.21
0.025
0.054
0.089
0.044
0.044
0.85
0.036
0.036
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
0.036
0.32
0.55
0.12
BDAT
0.40
0.34
BDAT
BDAT
0.12
BDAT
0.12
0.14
BDAT
0.068
0.020
BDAT
BDAT
BDAT
BDAT
BDAT
Document
B
B
B
C
C
C
C
C
C
C
C
C
C
C
B
B
B
B
B
B
B
B
B
C
C
C
C
B
C
C
B
B
a
B
C
C
B
C
C
B
B
B
B
B
Treatment
Standard (mg/kg) *"
BDAT
BDAT
BDAT
7.2
7.2
7.2
33
33
33
14
14
18
18
18
BDAT-FS
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT-FS
BDAT
BDAT
14
140
28
170
BDAT
14
33
BDAT-FS
BDAT
a
BDAT
160
160
BDAT
8.2
33
BDAT-FS
BDAT-FS
BDAT-FS
BDAT-FS
BDAT-FS
* BDAT for wastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
** BDAT for nonwastewaters is incineration but fuel substitution is also BDAT for the waste codes marked as BDAT-FS.
3 Constituent is regulated in the wastewater form but not in the nonwastewater form.
1-10
-------
Table 1-1 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C; BY WASTE CODE
Wastewater Nonwastewater
Waste
Code
U127
U128
U129
U129
U129
U129
U130
U131
U132
U137
U138
UUO
U141
U142
UU3
UH7
UH8
UU9
U150
U152
U153
U154
U155
U156
U157
U158
U159
U161
U162
U163
U164
U165
U166
U167
U168
U169
U170
U171
U172
U173
U174
U176
U177
U178
U179
Regulated Constituents
Hexach lorobenzene
Hexachlorobutadiene
alpha-BHC
beta-BHC
delta-BHC
gamma -BHC (Lindane)
Hexach 1 orocyc I open t ad i ene
Hexachloroethane
Hexach 1 oroph ene
Indenod ,2,3-c,d)pyrene
lodomethane
Isobutyl alcohol
Isosafrole
Kepone
Lasiocarpine
Maleic anhydride
Ha I etc hydrazide
Malononitri le
Melphalan
Methacrylonitrile
Methanethiol
Methanol
Methapyrilene
Methyl chlorocarbonate
3-Methylcholanthrene
4,4'-Methylenebis(2-chloroaniline)
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl methacrylate
N-Methyl-N-nitro-N-nitrosoguanidine
Methylthiouracil
Naphthalene
1 ,4-Naphthoquinone
1-Naphthylamine
2-Naphthylamine
Nitrobenzene
4-Nitrophenol
2-Nitropropane
N-Nitrosodi-n-butylamine
N-Nitrosodiethanolamine
N-Nitrosodiethylamine
N-Ni troso-N-ethylurea
N-Nitroso-N-methylurea
N-Nitroso-N-methylurethane
N-Nitrosopiperidine
Document
A
A
A
A
A
A
A
A
6
A
A
A
A
A
B
B
B
B
B
A
B
A
A
B
A
A
A
A
A
B
B
A
B
B
A
A
A
B
A
B
A
8
B
B
A
Treatment
Standard (mg/l) *
0.055
0.055
0.00014
0.00014
0.023
0.0017
0.057
0.055
BOAT
0.0055
0.19
5.6
0.081
0.0011
BOAT
BOAT
BOAT
BOAT
BOAT
0.24
BOAT
5.6
0.081
BOAT
0.0055
0.50
0.28
0.14
0.14
BOAT
BOAT
0.059
BOAT
BOAT
0.52
0.068
0.12
BOAT
0.40
BOAT
0.40
BOAT
BOAT
BOAT
0.013
Document
C
C
C
C
C
C
C
C
B
C
C
C
C
C
B
B
B
B
B
C
B
B
C
B
C
C
C
C
C
B
B
C
B
B
B
C
C
B
C
B
C
B
B
B
C
Treatment
Standard (mg/kg) **
37
28
0.066
0.066
0.066
0.066
3.6
28
BOAT
8.2
65
170
2.6
0.13
BOAT
BDAT-FS
BOAT
BOAT
BOAT
84
BOAT
BOAT-FS
1.5
BOAT
15
35
36
33
160
BOAT
BOAT
3.1
BOAT
BOAT
BOAT
14
29
BOAT
17
BDAT
28
BDAT
BDAT
BDAT
35
* BDAT for wastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
** BDAT for nonwastewaters is incineration but fuel substitution is also BDAT for the waste codes marked as BDAT-FS.
1-11
-------
Table 1-1 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C; BY WASTE CODE
Wastewater Nonwastewater
Waste
Code
U180
U181
U182
U183
U184
U185
U186
U187
U188
U191
U192
U193
U194
U196
U197
U200
U201
U202
U203
U206
U207
U208
U209
U210
U211
U213
U218
U219
U220
U222
U225
U226
U227
U228
U234
U236
U237
U238
U239
U240
U240
U243
U244
11247
U248
Regulated Constituents
N-Mitrosopyrrolidine
5-Nitro-o-toluidine
Paraldehyde
Pentach I orobenzene
Pentach I oroethane
Pentachloroni trobehzene
1 ,3-Pentadiene
Phenacetin
Phenol
2-Picot ine
Pronamide
1,3-Propane sultone
n-Propylamine
Pyridine
p-Benzoquinone
Reserpine
Resoreinol
Saccharin and salts
Safrole
Streptozotocin
1,2,4,5- Tet rach I orobenzene
1,1, 1 ,2-Tetrachloroethane
1,1,2, 2-Tetrach I oroethane
Tetrachloroethylene
Carbon tetrachloride
Tetrahydrofuran
Thioacetamide
Thiourea
Toluene
o-Toluidine hydrochloride
Tribromomethane (Bromoform)
1,1, 1 -Trichloroethane
1,1,2-Trichloroethane
Trichloroethylene
synt-Trini trobenzene
Trypan blue
Uraci I mustard
Ethyl carbamate
Xylenes (total)
2,4-Dichlorophenoxyacetic acid
2,4-Dichlorophenoxyacetic salts and esters
Hexachloropropene
Th i ram
Methoxychlor
Warfarin (<0.3%)
Document
A
A
B
A
B
A
B
A
A
B
A
B
B
A
B
B
B
B
A
B
A
A
A
A
A
B
B
B
A
B
A
A
A
A
B
B
B
B
A
A
B
A
B
A
B
Treatment
Standard (mg/l) *
0.013
0.32
BOAT
0.055
BOAT
0.055
BOAT
0.081
0.039
BOAT
0.093
BDAT
BDAT
0.014
BDAT
BDAT
BDAT
BDAT
0.081
BDAT
0.055
0.057
0.057
0.056
0.057
BDAT
BDAT
BDAT
0.080
BDAT
0.63
0.054
0.054
0.054
BDAT
BDAT
BDAT
BDAT
0.32
0.72
BDAT
0.035
BDAT
0.25
BOAT
Document
C
C
B
C
B
C
B
C
C
B
C
B
B
C
B
B
B
B
C
B
C
C
C
C
C
B
B
B
C
B
C
C
C
C
B
B
B
B
C
C
B
C
B
C
B
Treatment
Standard (mg/kg) **
35
28
BDAT-FS
37
BOAT
4.8
BDAT-FS
16
6.2
BDAT
1.5
BDAT
BDAT
16
BDAT-FS
BDAT
BDAT-FS
BDAT
22
BDAT
19
42
42
5.6
5.6
BDAT-FS
BDA-
BDA;
28
BDAT
15
5.6
5.6
5.6
BDAT
BDAT
BDAT
BDAT
28
10
BDAT
28
BDAT
0.18
BDAT-FS
* BDAT for wastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
•* BDAT for nonwasteuaters is incineration but fuel substitution is also BDAT for the-waste codes marked as BDAT-FS.
1-12
-------
Table 1-2
TREATMENT STANDARDS FOR U AND P WASTES AND MULT I-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C; ALPHABETICALLY
Uastewater
Nonwastewater
Regulated U and P Waste Constituents
Acetaldehyde
Acetone
Acetoni tri le
Acetophenone
2-Acetylaminof luorene
Acetyl chloride
1-Acetyl-2-thiourea
Acrolein
Acrylamide
Acryl ic acid
Acryloni tri le
Aldicarb
Aldrin
Allyl alcohol
5-Aminomethyl -3- isoxazolol
4 - Am i nopy r i d i ne
Ami trole
Ani line
Auramine
Azaserine
Aziridine
Benzal chloride
Benz(a)anthracene
Benz(c)acridine
Benzene
Benzene sulfonyl chloride
Benzidine
Benzo(a)pyrene
p-Benzoquinone
Benzyl chloride
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC
Bis(2-chloroethoxy)methane
Bis(2-chloroethyl)ether
Bis(2-chloroi sopropy I ) ether
B i s( ch I oromethy I )ether
Bromoacetone
Bromomethane (Methyl bromide)
4-Bromophenyl phenyl ether
Brucine
n-Butyl alcohol
2-sec-Butyl-4,6-dinitrophenol (Dinoseb)
Carbon disulfide
Waste
Code
U001
U002
U003
UOQ4
U005
U006
P002
P003
U007
U008
U009
P070
P004
POOS
P007 -
POOS
U011
U012
U014
U015
P054
U017
U018
U016
U019
U020
U021
U022
U197
P028
U129
U129
U129
U129
U024
U025
U027
P016
P017
U029
U030
P018
U031
P020
P022
i
Document
B
A
A
A
A
B
B
A
B
B
A
B
A
B
B
B
B
A
B
B
B
B
A
B
A
B
B
A
B
B
A
A
A
A
A
A
A
B
B
A
A
B
A
A
B
Treatment
Standard (mg/O *
BOAT
0.28
0.17
0.010
0.059
BOAT
BDAT
0.29
BDAT
BDAT
0.24
BDAT
0.021
BDAT
BDAT
BOAT
BDAT
0.81
BDAT
BDAT
BDAT
BOAT
0.059
BDAT
O.U
BDAT
BDAT
0.061
BDAT
BDAT
0.00014
0.00014
0.023
0.0017
0.036
0.033
0.055
BOAT
BDAT
0.11
0.055
BDAT
5.6
0.066
BDAT
Document
B
C
B
C
C
B
B
B
B
B
C
B
C
B
B
B
B
C
B
B
B
B
C
B
C
B
8
C
B
B
C
C
C
C
C
C
C
B
B
C
C
B
C
C
B
Treatment
Standard (mg/kg) **
BDAT
160
BOAT
9.7
140
BDAT
BDAT
BDAT-FS
BDAT
BDAT-FS
84
BDAT
0.066
BDAT-FS
BDAT
BDAT
BDAT
14
BDAT
BDAT
BDAT
BDAT
8.2
BDAT-FS
36
BDAT
BDAT
8.2
BDAT-FS
BDAT
0.066
0.066
0.066
0.066
7.2
7.2
7.2
BDAT
BDAT
15
15
BDAT
2.6
2.5
BDAT
BDAT for wastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
BDAT for nonwastewaters is incineration. Fuel substitution is also BDAT for the waste codes marked as BDAT-FS.
1-13
-------
Table 1-2 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C; ALPHABETICALLY
Wastewater
Nonwastewater
Regulated U and P Waste Constituents
Carbon tetrachloride
Carbonyl fluoride
Chlorambuci I
Chlordane (alpha and gamma)
Chloroacetaldehyde
p-Chloroani I ine
Chlorobenzene
Chlorobenzi late
1-Chtoro-2,3-epoxypropane (Epichlorohydrin)
2-Chloroethyl vinyl ether
Chloroform
p-Chloro-m-cresol
Chloromethane (Methyl chloride)
Chloromethyl methyl ether
Chlornaphazine
2-Chloronaphthalene
4-Chloro-o-toluidine hydroehloride
2-Chlorophenol
1 - ( o- Ch 1 oropheny I ) th i ourea
3-Chloropropionitri le
Chrysene
Creosote - Lead
Creosote - Naphthalene
Creosote - Pentachlorophenol
Creosote • Phenanthrene
Creosote - Pyrene
Creosote - Toluene
Creosote - Xylenes (total)
Cresol (m- and p- isomers)
o-Cresol
Crotonaldehyde
Cumene
Cyclohexane
Cyclohexanone
2-Cyclohexyl-4,6-dinitrophenol
Daunomycin
o,p'-ODD
p,p' -ODD
o,p'-DDD
p,p'-DDD
o,p'-DDE
p,p'-DDE
o,p'-DDT
p,p'-DDT
Waste
Code
U211
U033
U035
U036
P023
P024
U037
U038
U041
U042
U044
U039
U045
U046
U026
U047
UCK9
U048
P026
P027
U050
U051
U051
UOS1
U051
U051
U051
U051
U052
U052
U053
U055
UOS6
U057
P034
U059
U060
U060
U061
U061
U061
U061
U061
U061
Document
A
B
B
A
B
A
A
A
B
B
A
A
A
B
B
A
B
A
B
B
A
A
A
A
A
A
A
A
A
A
B
B
B
A
B
B
A
A
A
A
A
A
A
A
Treatment
Standard (mg/l) *
0.057
BOAT
BOAT
0.0033
BOAT
0.46
0.057
0.10
BOAT
BOAT
0.046
0.018
0.19
BDAT
BDAT
0.055
BDAT
0.044
BDAT
BDAT
0.059
0.28
0.059
0.089
0.059
0.067
0.080
0.32
0.77
0.11
BDAT
BDAT
BDAT
0.36
BDAT
BDAT
0.023
0.023
0.023
0.023
0.031
0.031
0.0039
0.0039
Document
C
B
B
C
B
C
C
B
B
B
C
C
C
B
B
C
B
C
B
B
C
C
C
C
C
C
C
C
C
C
B
B
B
B
B
B
C
C
C
C
C
C
C
C
Treatment
Standard (mg/kg) **
5.6
BDAT
BDAT
0.13
BDAT
16
5.7
BDAT
BDAT
BDAT
5.6
14
33
BDAT
BDAT
5.6
BDAT
5.7
BDAT
BDAT
8.2
o.5i a
3.1
7.4
3.1
8.2
28
28
3.2
5.6
BDAT-FS
BDAT-FS
BDAT-FS
BDAT-FS
BDAT
BDAT
0.087
0.087
0.087
0.087
0.087
0.087
0.087
0.087
* BDAT for wastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
** BDAT for nonwastewaters is incineration. Fuel substitution is also BDAT for the waste codes marked as BDAT-FS.
a Units for the lead standard are mg/l, analyzed by TCLP extract.
-------
Table 1-2 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND MULT I-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C; ALPHABETICALLY
Uasteuater
Nonwasteuater
Regulated U and P Waste Constituents
Diallate
Dibenz(a,h)anthracene
1,2,7,8-Dibenzopyrene
1 ,2-Dibromo-3-chloropropane
1 ,2-Dibromoethane (Ethylene dibromide)
Dibromomethane
m-Dichlorobenzene
o-Dichlorobenzene
p-Dichlorobenzene
3,3' -Dichlorobenzidine
cis-1 , 4-Dichloro-2-butene
trans -1 , 4-Dichloro-2-butene
0 i ch 1 orod i f 1 uoromethane
1 , 1 -Dichloroethane
1,2-Dichloroethane
1 , 1 -Dichloroethylene
trans-1 ,2-Dichloroethylene
2,4-Dichlorophenol
2,6-Dichlorophenol
2,4-Dichlorophenoxyacetie acid
2,4-Oichlorophenoxyacetie salts and esters
1,2-Dichloropropane
cis-1 ,3-Dichloropropylene
trans- 1 ,3-Dichloropropylene
Dieldrin
1 ,2:3,4-Diepoxybutane
Diethylstilbestrol
Oihydrosafrole
3,3' -Dimethoxybenzidine
D i methyl ami ne
p-Dimethylaminoazobenzene
7, 12-Oimethyl benz(a)anthracene
3,3' -Oimethylbenzidine
Dimethylcarbamoyl chloride
alpha,alpha-Dimethylphenethylamine
2,4-Dimethylphenol
4,6-Dinitro-o-cresol
4,6-Dinitro-o-cresol salts
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-propylnitrosamine
1,4-Dioxane
Dipropylamine
2,4-Oithiobiuret
Waste
Code
U062
U063
U064
U066
U067
U068
U071
U070
U072
U073
U074
U074
U075
U076
U077
U078
U079
U081
U082
U240
U240
U083
U084
U084
P037
U085
U089
U090
U091
U092
U093
U094
U095
U097
P046
U1Q1
P047
P047
P048
U105
U106
U111
U108
U110
P049
Document
B
A
B
A
A
A
A
A
A
B
B
B
A
A
A
A
A
A
A
A
B
A
A
A
A
B
B
B
B
B
B
B
B
B
B
A
A
B
A
A
A
A
A
B
B
Treatment
Standard (mg/l) *
BOAT
0.055
BOAT
0.11
0.028
0.11
0.036
0.088
0.090
BOAT
BDAT
BOAT
0.23
0.059
0.21
0.025
0.054
0.044
0.044
0.72
BDAT
0.65
0.036
0.036
0.017
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
0.036
0.28
BDAT
0.12
0.32
0.55
0.40
0.12
BDAT
BDAT
Document
B
C
B
C .
C
C
C
C
C
B
B
B
C
C
C
C
C
C
C
C
B
C
C
C
C
B
B
B
B
B
B
B
B
B
B
C
C
B
C
C
C
C
C
B
B
Treatment
Standard (mg/kg) **
BDAT
8.2
BDAT-FS
15
15
15
6.2
6.2
6.2
BDAT
BDAT
8DAT
7.2
7.2
7.2
33
33
U
14
10
BDAT
18
18
18
0.13
BDAT-FS
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT-FS
BDAT
BDAT
BDAT
14
160
BDAT
160
140
28
14
170
BDAT
BDAT
BDAT for wastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
BDAT for nonwastewaters is incineration. Fuel substitution is also BDAT for the waste codes marked as BDAT-FS.
1-15
-------
Table 1-2 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND HULTI-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C; ALPHABETICALLY
Uastewater
Nonuastewater
Regulated U and P Waste Constituents
Endosulfan I
Endosutfan II
Endosulfan sulfate
Endothall
Endrin
Endrin aldehyde
Epinephrine
Ethyl acetate
Ethyl acrylate
Ethyl carbamate
Ethyl cyanide (Propanenitri le)
Ethyl ether
Ethyl methacrylate
Ethyl methanesulfonate
Ethylene bis-di thiocarbamic acid
Ethylene oxide
Ethylene thiourea
Fluoranthene
Fluoroacetamide
Fluoroacetic acid, sodium salt
Formaldehyde
Formic acid
Furan
Furfural
G lye idyl aldehyde
Heptachlor
Heptachlor epoxide
Hexachlorobenzene
Hexach t orobutadi ene
Hexach 1 orocyc I open t ad i ene
Hexach I oroethane
Hexach I oroph ene
Hexach I oropropene
Indenod ,2,3-c,d)pyrene
lodomethane
Isobutyl alcohol
Isocyanic acid, methyl ester
Isodrin
Isosafrole
Kepone
Lasiocarpine
Ha lei c anhydride
Ma lei c hydrazide
Malononi tri le
Waste
Code
P050
P050
P050
P088
P051
P051
P042
U112
U113
U238
P101
U117
U118
U119
U114-
U11S
U116
U120
P057
P058
U122
U123
U124
U125
U126
P059
P059
U127
U128
U130
U131
U132
U243
U137
U138
U140
P064
P060
U141
U142
UU3
U147
U148
U149
Document
A
A
A
B
A
A
B
A
B
B
A
A
A
B
B
A
B
A
B
B
B
B
B
B
B
A
A
A
A
A
A
B
A
A
A
A
B
A
A
A
B
B
B
B
Treatment
Standard (mg/l) *
0.023
0.029
0.029
BOAT
0.0028
0.025
BOAT
0.34
BDAT
BDAT
0.24
0.12
0.14
BDAT
BDAT
0.12
BDAT
0.068
BDAT
BOAT
BDAT
BOAT
BDAT
BDAT
BDAT
0.0012
0.016
0.055
0.055
0.057
0.055
BDAT
0.035
0.0055
0.19
5.6
BDAT
0.021
0.081
0.0011
BDAT
BDAT
BDAT
BDAT
Document
C
C
C
B
C
C
B
C
B
B
C
C
C
B
B
. a
B
c
B
B
B
B
B
B
B
C
C
C
C
C
c
B
C
C
C
C
B
C
C
C
B
B
B
B
Treatment
Standard (mg/kg) **
0.066
0.13
0.13
BDAT-FS
0.13
0.13
BDAT
33
BDAT-FS
BDAT
360
160
160
BDAT
BDAT
a
BDAT
8.2
BDAT
BDAT
BDAT-FS
BDAT-FS
BDAT-FS
BDAT-FS
BDAT-FS
0.066
0.066
37
28
3.6
28
BDAT
28
8.2
65
170
BDAT
0.066
2.6
0.13
BDAT
BDAT-FS
BDAT
BDAT
* BDAT for wastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
** BDAT for nonwastewaters is incineration. Fuel substitution is also BDAT for the waste codes marked as BDAT-FS.
5) Constituent is regulated in the wastewater form, but not in the nonwastewater form.
1-16
-------
Table 1-2 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND MULT I-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C; ALPHABETICALLY
Uastewater
Nonwastewater
Regulated U and P Waste Constituents
Melphalan
Methacrylonitrile
Methanethiol
Methanol
Methapyrilene
Methomyl
Methoxychlor
Methyl chlorocarbonate
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl methacrylate
2-Methylaziridine
3-Methylcholanthrene
4,4' -Methylenebis(2-chloroani I ine)
Methylene chloride
Methyllactonitri le
N-Methyl-N-nitro-N-nitrosoguanidine
Methylthiouraci I
Mitomycin C
Naphthalene
1,4-Naphthoquinone
1-Naphthylanrine
2-Naphthylamine
1-Naphthyl-2-thiourea
Nicotine and salts
p-Ni troani 1 ine
Nitrobenzene
5-Nitro-o-toluidine
4-Nitrophenol
2-Ni tropropane
N-Nitrosodiethanolantine
N-Nitrosodiethylamine
N-Ni trosodimethylamine
N-Nitrosodi-n-butylamine
N-Ni trosomethylvinylamine
N-Nitroso-N-ethylurea
N-Ni troso-N-methylurea
N-Nitroso-N-methylurethane
N-Ni trosopi peri dine
N-Nitrosopyrrolidine
Paraldehyde
Pentachloroethane
Pent ach I orobenzene
Pentachloronitrobenzene
1,3-Pentadiene
Waste
Code
U150
U152
U153
U154
U155
P066
U247
U156
U159
U161
U162
P067
U157
U158
U080
P069
U163
U164
U010
U165
U166
U167
U168
P072
POTS
P077
U169
U181
U170
U171
U173
U174
P082
U172
P084
U176
U177
U178
U179
U180
U182
U184
U183
U185
U186
Document
B
A
B
A
A
B
A
B
A
A
A
B
A
A
A
B
B
B
B
A
B
B
A
B
B
A
A
A
A
B
B
A
A
A
B
B
B
B
A
A
B
B
A
A
B
Treatment
Standard (mg/l) *
BOAT
0.24
BOAT
5.6
0.081
BOAT
0.25
BOAT
0.28
0.14
0.14
BOAT
0.0055
0.50
0.089
BOAT
BOAT
BOAT
BOAT
0.059
BOAT
BOAT
0.52
BOAT
BOAT
0.028
0.068
0.32
0.12
BOAT
BOAT
0.40
0.40
0.40
BOAT
BOAT
BOAT
BOAT
0.013
0.013
BOAT
BOAT
0.055
0.055
BOAT
Document
B
C
B
B
C
B
C
B
C
C
C
B
C
C
C
B
B
B
B
C
B
B
B
B
B
C
C
C
C
B
B
C
B
C
B
B
B
B
C
C
B
B
C
C
B
Treatment
Standard (mg/kg) **
BOAT
84
BOAT
BDAT-FS
1.5
BOAT
0.18
BOAT
36
33
160
BOAT
15
35
33
BOAT
BOAT
BOAT
BOAT
3.1
BDAT-FS
BOAT
BOAT
BDAT
BOAT
28
14
28
29
BDAT
BDAT
28
BDAT
17
BDAT
BDAT
BDAT
BDAT
35
35
BDAT-FS
BDAT
37
4.8
BDAT-FS
* BDAT for wastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
** BDAT for nonwastewaters is incineration. Fuel substitution is also BDAT for the waste codes marked as BDAT-FS.
1-17
-------
Table 1-2 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND MULT I-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C; ALPHABETICALLY
Wastewater
Nonwastewater
Regulated U and P Waste Constituents
Phenacetin
Phenol
N-Phenylthiourea
Phosgene
2-Picoline
Pronamide
1,3-Propane sultone
Propargyl alcohol
n-Propylamine
Pyridine
Reserpine
Resorcinol
Saccharin and salts
Safrole
Streptozotocin
Strychnine and salts
1,2,4,5-Tetrachlorobenzene
1,1, 1 ,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
Tetrahydrofuran
Thioacet amide
Thiofanox
Thiophenol (Benzenethiol)
Thiosemicarbazide
Thiourea
Thiram
Toluene
o-Toluidine hydrochloride
Toxaphene
Tribromomethane (Bromoform)
Trichloroacetaldehyde (Chloral)
1,1, 1 -Trichloroethane
1 , 1 , 2 - T r i ch I oroethane
Trichloroethylene
T r i ch I oromethaneth i ol
T r i ch 1 oromonof I uoromethane
sym-Tri nitrobenzene
Trypan blue
Uraci I mustard
Vinyl chloride
Warfarin (>0.3X)
Warfarin (<0.3X)
Xylenes (total)
Waste
Code
U187
U188
P093
P095
U191
U192
U193
P102
U194
U196
U200
U201
U202
U203
U206
P108
U207
U208
U209
U210
U213
U218
P045
POU
P116
U219
U244
U220
U222
P123
U225
U034
U226
U227
U228
P118
U121
U234
U236
U237
U043
P001
U248
U239
Document
A
A
B
B
B
A
B
B
B
A
B
B
B
A
B
B
A
A
A
A
B
B
B
B
B
B
B
A
B
A
A
B
A
A
A
B
A
B
B
B
A
B
B
A
Treatment
Standard (mg/l) *
0.081
0.039
BOAT
BOAT
BOAT
0.093
BOAT
BOAT
BOAT
0.014
BOAT
BDAT
BDAT
0.081
BDAT
BDAT
0.055
0.057
0.057
0.056
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
0.080
BDAT
0.0095
0.63
BDAT
0.054
0.054
0.054
BDAT
0.020
BDAT
BDAT
BDAT
0.27
BOAT
BDAT
0.32
Document
C
C
B
B
B
C
B
B
B
C
B
B
B
C
B
B
C
C
C
C
B
B
B
B
B
B
B
C
B
C
C
B
C
C
C
B
C
B
B
B
C
B
B
C
Treatment
Standard (mg/kg) **
16
6.2
BDAT
BDAT
BDAT
1.5
BDAT
BDAT-FS
BDAT
16
BDAT
BDAT-FS
BDAT
22
BDAT
BDAT
19
42
42
5.6
BDAT-FS
BDAT
BDAT
BDAT
BDAT
BDAT
BDAT
28
BDAT
1.3
15
BDAT
5.6
5.6
5.6
BDAT
33
BDAT
BDAT
BDAT
33
BDAT-FS
BDAT-FS
28
* BDAT for wastewaters is wet air or chemical oxidation followed by carbon adsorption or incineration.
** BDAT for nonwastewaters is incineration. Fuel substitution is also BDAT for the waste codes marked as BDAT-FS.
1-18
-------
Table 1-2 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C; ALPHABETICALLY
Uastewater
Nonwastewater
Regulated Leachate Constituents
Acenaphthalene
Acenaphthene
Acetone
Acetonitrile
Acetophenone
2-Acetylaminof luorene
Acrolein
Acryloni tri le
Aldrin
4-Aminobiphenyl
Ani I ine
Anthracene
Aramite
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroctor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
Benz(a)anthracene
Benzene
BenzoC b) f I uoranthene
8enzo(k)f luoranthene
Benzo(g,h, i )perylene
Benzo(a)pyrene
alpha-BHC
beta-BHC
delta-BHC
ganma-BHC (Lindane)
Bis(2-chloroethoxy)methane
Bis(2-chloroethyl)ether
Bis(2-chloroisopropyl )ether
Bis(2-ethylhexyl)phthalate
Bromodichloromethane
Bromomethane (Methyl bromide)
4-Bromophenyl phenyl ether
n-Butyl alcohol
Butyl benzyl phthalate
2-sec-Butyl-4,6-dinitrophenol (Dinoseb)
Carbon disulfide
Carbon tetrachloride
Chlordane (alpha and gamma)
p-Chloroani line
Chlorobenzene
Waste
Code
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
FQ39
F039
F039
F039
Document
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
Treatment
Standard (mg/l)
0.059
0.059
0.28
0.17
0.010
0.059
0.29
0.24
0.021
0.13
0.810
0.059
0.36
0.013
0.014
0.013
0.017
0.013
0.014
0.014
0.059
0.140
0.055
0.059
0.0055
0.061
0.00014
0.00014
0.023
0.0017
0.036
0.033
0.055
0.28
0.35
0.11
0.055
5.6
0.017
0.066
0.014
0.057
0.0033
0.46
0.057
Document
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
Treatment
Standard (mg/kg)
3.4
4.0
160
NR
9.7
140
NR
84
0.066
NR
14
4.0
NR
0.92
0.92
0.92
0.92
0.92
1.8
1.8
8.2
36
3.4
3.4
1.5
8.2
0.066
0.066
0.066
0.066
7.2
7.2
7.2
28
15
15
15
2.6
7.9
2.5
NR
5.6
0.13
16
5.7
NR = Not regulated. See Section 5.0 of the appropriate volume for discussion.
1-19
-------
Table 1-2 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, 8, AND C; ALPHABETICALLY
Uasteuater
Nonwastewater
Regulated Leachate Constituents
Chlorobenzilate
2-Chloro-1 ,3- butadiene
Ch 1 orodi bromomethane
Chloroethane
Chloroform
p-Chloro-m-cresot
Chloromethane (Methyl chloride)
2-Chloronaphthalene
2-Chlorophenol
3-Chloropropene
Chrysene
Cresol (m- and p- isomers)
o-Cresol
Cyclohexanone
o,p' -ODD
p,p'-DDD
o,p'-DDE
p,p'-DDE
o,p'-DDT
p,p'-DDT
D ibenz( a, h) anthracene
Dibenzo(a,e)pyrene
1,2-Dibromo-3-.chloropropane
1 ,2-Dibromoethane (Ethylene dibromide)
Di bromomethane
m- D i ch I orobenzene
o-Dichlorobenzene
p-Oichlorobenzene
D i ch I orodi f luoromethane
1 , 1-Di chloroethane
1 ,2-Di chloroethane
1 , 1-Dichloroethylene
trans -1 ,2-Dichloroethylene
2 , 4 - D i ch I oropheno I
2,6-Dichlorophenol
2,4-Dichlorophenoxyacetic acid
1 , 2 • D i ch I oropropane
c is- 1,3-0 ichloropropene
trans-1,3-Dichloropropene
Dieldrin
Diethyl phthalate
2,4-Dimethylphenol
Dimethyl phthalate
Di-n-butyl phthalate
1 ,4-Di nitrobenzene
Waste
Code
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
Document
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
Treatment
Standard (mg/l)
0.10
0.057
0.057
0.27
0.046
0.018
0.19
0.055
0.044
0.036
0.059
0.77
0.11
0.36
0.023
0.023
0.031
0.031
0.0039
0.0039
0.055
0.061
0.11
0.028
0.11
0.036
0.088
0.090
0.23
0.059
0.21
0.025
0.054
0.044
0.044
0.72
0.85
0.036
0.036
0.017
0.20
0.036
0.047
0.057
0.32
Document
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C
C
C
C
C
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
Treatment
Standard (rag/kg)
NR
NR
15
6.0
5.6
14
33
5.6
5.7
28
8.2
3.2
5.6
NR
0.087
0.087
0.087
0.087
0.087
0.087
8.2
NR
15
15
15
6.2
6.2
6.2
7.2
7.2
7.2
33
33
14
14
10
18
18
18
0.13
28
14
28
28
2.3
NR = Not regulated. See Section 5.0 of the appropriate volume for discussion.
1-20
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Table 1-2 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C; ALPHABETICALLY
Uasteuater
Nonwastewater
Regulated Leachate Constituents
4,6-Dinitro-o-cresol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octyl phthalate
Di-n-propylnitrosamine
1 ,4-Dioxane
Diphenylamine
1 ,2-Diphenythydrazine
Diphenylni trosamine
Disulfoton
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Ethyl acetate
Ethyl benzene
Ethyl cyanide (Propanenitrile)
Ethyl ether
Ethyl methacrylate
Ethylene oxide
Famphur
Fluoranthene
Fluorene
Heptachlor
Heptachlor epoxide
Hexachlorobenzene
Hexach I orobutadi ene
Hexach 1 orocyc I opent ad i ene
Hexach I orod i benzof urans
Hexachlorodibenzo-p-dioxins
Hexach loroethane
Hexach I oropropene
Indeno(1,2,3-c,d)pyrene
lodomethane
Isobutyl alcohol
Isodrin
Isosafrole
Kepone
Methacrylonitri le
Methanol
Methapyrilene
Methoxychlor
Methyl ethyl ketone
Waste
Code
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
Document
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
Treatment
Standard (mg/l)
0.28
0.12
0.32
0.55
0.017
0.40
0.12
0.52
0.087
0.40
0.017
0.023
0.029
0.029
0.0028
0.025
0.34
0.057
0.24
0.12
0.14
0.12
0.017
0.068
0.059
0.0012
0.016
0.055
0.055
0.057
0.000063
0.000063
0.055
0.035
0.0055
0.19
5.6
0.021
0.081
0.0011
0.24
5.6
0.081
0.25
0.28
Document
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C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
. C
C
C
C
C
Treatment
Standard (mg/kg)
160
160
140
28
28
14
170
NR
NR
NR
6.2
0.066
0.13
0.13
0.13
0.13
33
6.0
360
160
160
NR
15
8.2
4.0
0.066
0.066
37
28
3.6
0.001
0.001
28
28
8.2
65
170
0.066
2.6
0.13
84
NR
1.5
0.18
36
NR = Not regulated. See Section 5.0 of the appropriate volume for discussion.
1-21
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Table 1-2 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C; ALPHABETICALLY
Wastewater
Nonwastewater
Regulated Leachate Constituents
Methyl isobutyl ketone
Methyl methacrylate
Methyl methanesulfonate
Methyl parathion
3-Methylcholanthrene
4,4'-Methylenebis(2-chloroaniline)
Methylene chloride
Naphthalene
2-Naphthylamine
p-Ni troani line
Nitrobenzene
5-Nitro-o-toluidine
4-Ni trophenol
N-Nitrosodiethylamine
N-Nitrosodimethylamine
N-Nitrosodi-n-butylamine
N-Ni trosomethylethylamine
N-Ni trosomorpho line
N-Nitrosopiperidine
N-Ni trosopyrrolidine
Parathion
Pentachlorobenzene
Pentach I orodi benzof urans
Pentachlorodibenzo-p-dioxins
Pentach 1 oron i t robenzene
Pentach lorophenol
Phenacetin
Phenanthrene
Phenol
Phorate
Phthalic anhydride
Pronamide
Pyrene
Pyridine
Safrole
Silvex (2,4,5-TP)
1,2,4,5-Tetrachlorobenzene
Tet rach 1 orodi benzof urans
Tetrachlorodibenzo-p-dioxins
1 ,1,1,2-Tetrachloroethane
1 , 1 ,2,2-Tetrachloroethane
Tetrachloroethylene
2 , 3 , 4 , 6- Tet rach 1 oropheno I
Toluene
Toxaphene
Waste
Code
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
Document
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
Treatment
Standard (nig/ 1)
0.14
0.14
0.018
0.014
0.0055
0.50
0.089
0.059
0.52
0.028
0.068
0.32
0.12
0.40
0.40
0.40
0.40
0.40
0.013
0.013
0.014
0.055
0.000063
0.000063
0.055
0.089
0.081
0.059
0.039
0.021
0.069
0.093
0.067
0.014
0.081
0.72
0.055
0.000063
0.000063
0.057
0.057
0.056
0.030
0.080
0.0095
Document
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
Treatment
Standard (mg/kg)
33
160
NR
4.6
15
35
33
3.1
NR
28
14
28
29
28
NR
17
2.3
2.3
35
35
4.6
37
0.001
0.001
4.8
7.4
16
3.1
6.2
4.6
NR
1.5
8.2
16
22
7.9
19
0.001
0.001
42
42
5.6
37
28
1.3
NR = Not regulated. See Section 5.0 of the appropriate volume for discussion.
1-22
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Table 1-2 (Continued)
TREATMENT STANDARDS FOR U AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
INCLUDED IN VOLUMES A, B, AND C; ALPHABETICALLY
Uastewater
Nonwasteuater
Regulated Leachate Constituents
Tribromomethane (Bromoform)
1,2,4-Trichlorobenzene
1,1 ,1-Trichloroethane
1,1,2-Trichloroethane
T r i ch I oroe thy I ene
T r i ch 1 oromonof luoromethane
2 , 4 , 5 - T r i ch I oropheno I
2,4,6-Trichlorophenol
2 , 4 , 5 - T r i ch I orophenoxyacet i c ac i d
1 , 2 , 3 - T r i ch I oropropane
1 , 1 ,2-Trichloro-1 ,2,2-trif luoroethane
Tris(2,3-dibromopropyl)phosphate
Vinyl chloride
Xylenes
Cyanides (total)
Fluoride
Sulfide
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium (total)
Copper
Lead
Mercury
Nickel
Selenium
Si Iver
Thallium
Vanadium
Zinc
Waste
Code
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
F039
Document
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
Treatment
Standard (mg/l)
0.63
0.055
0.054
0.054
0.054
0.020
0.18
0.035
0.72
0.85
0.057
0.11
0.27
0.32
1.2
35
14
1.9
1.4
1.2
0.82
0.20
0.37
1.3
0.28
0.15
0.55
0.82
0.29
1.4
0.042
1.0
Document
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C
C
C
C
C
C
C
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
c
Treatment
Standard (mg/kg)
15
19
5.6
5.6
5.6
33
37
37
7.9
28
28
NR
33
28
1.8
NR
NR
TCLP (mg/l)
0.23
5.0 3
52
.NR
0.066
5.2
NR
0.51
0.025
0.32
5.7
0.072
NR
NR
NR
NR = Not regulated. See Section 5.0 of the appropriate volume for discussion.
3 Based on EP Toxicity.
1-23
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Table 1-3
TREATMENT STANDARDS FOR U AND P NONUASTEWATERS
AND MULTI-SOURCE LEACHATE (F039) INCLUDED IN VOLUME C
Waste
Code
F039
Regulated Constituent
Mul ti -Source Leachate (HSL) - Refer to Table
Treatment
Standard (mg/kg)
1-2 for the
Treatment Standard for each Regulated HSL Constituent.
P004
P020
P024
P037
P047
P048
P050
P050
P050
P051
P051
P059
P059
P060
P077
P101
P123
U002
U004
U005
U009
U012
U018
U019
U022
U024
U025
U027
U029
U030
U031
U036
U037
U039
U043
U044
U045
U047
U048
U050
U051
U051
U051
U051
U051
U051
U051
Aldrin
2-sec-Butyl-4,6-dinitrophenol (Dinoseb)
p-Chloroani line
Dieldrin
4,6-Dinitro-o-cresol
2,4-Dini trophenol
Endosulfan I
Endosulfan It
Endosulfan sulfate
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxide
Isodrin
p-Nitroani line
Ethyl cyanide (Propanenitri le)
Toxaphene
Acetone
Acetophenone
2 - Acety 1 ami nof I uorene
Acrylonitrile
Aniline
Benz(a)anthracene
Benzene
Benzo(a)pyrene
Bis(2-chloroethoxy)methane
Bis(2-chloroethyl)ether
Bis(2-chloroisopropyl)ether
Bromomethane (Methyl bromide)
4-Bromophenyl phenyl ether
n-Butyl alcohol
Chlordane (alpha and gamma)
Chlorobenzene
p-Chloro-m-cresol
Vinyl chloride
Chloroform
Chloromethane (Methyl chloride)
2-Chloronaphthalene
2-Chlorophenol
Chrysene
Creosote - Lead
Creosote - Naphthalene
Creosote - Pentachlorophenol
Creosote - Phenanthrene
Creosote • Pyrene
Creosote - Toluene
Creosote - Xylenes (total)
0.066
2.5
16
0.13
160
160
0.066
0.13 .
0.13
0.13
0.13
0.066
0.066
0.066
28
360
1.3
160
9.7
140
84
14
8.2
36
8.2
7.2
7.2
7.2
15
15
2.6
0.13
5.7
14
33
5.6
33
5.6
5.7
8.2
0.51 a
3.1
7.4
3.1
8.2
28
28
1-24
-------
Table 1-3 (Continued)
TREATMENT STANDARDS FOR U AND P NONUASTEUATERS
AND MULTI-SOURCE LEACHATE (F039) INCLUDED IN VOLUME C
Waste
Code
U052
U052
U060
U060
U061
U061
U061
U061
U061
U061
U063
U066
U067
U068
U070
U071
U072
U075
U076
U077
U078
U079
U080
U081
U082
U083
U084
U084
U101
U105
U106
U108
U111
U112
U117
U118
U120
U121
U127
U128
U129
U129
U129
U129
U130
U131
U137
U138
UUO
U141
Regulated Constituent
Cresol (m- and p- isomers)
o-Cresol
o,p'-DDD
p,p'-DDD
o,p'-DDD
p,p'-DDD
o,p'-DDE
p,p'-DDE
o,p'-DDT
p,p'-DDT
Dibenz(a,h)anthracerie
1 ,2-Dibromo-3-chloropropane
1 ,2-Dibromoethane (Ethylene Di bromide)
D i bromomethane
o-Dichlorobenzene
m-D i ch lorobenzene
p-D i ch lorobenzene
Dichlorodif luoromethane
1 , 1 -D i ch 1 oroethane
1,2-Oichlorocthane
1,1-Diehloroethylen*
trans-1,2-Diehloroethylene
Methylene chloride
2.4-Dichlorophenol
2,6-Dichlorophenol
1 , 2 - D i ch I oropropane
cis-1,3-Dichloroprbpylene
trans-1 ,3-Dichloropropylene
2,4-Dimethylphenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
1,4-Dioxane
Di-n-propylnitrosamine
Ethyl acetate
Ethyl ether
Ethyl methacrylate
Fluoranthene
T r i ch I oromonof I uoromethane
Hexach lorobenzene
Hexach I orobutadi ene
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
Hexach 1 orocyc I opentadi ene
Hexach I oroethane
Indeno(1,2,3-c,d)pyrene
lodomethane
Isobutyl alcohol
Isosafrole
Treatment
Standard (mg/kg)
3.2
5.6
0.087
0.087
0.087
0.087
0.087
0.087
0.087
0.087
8.2
15
15
15
6.2
6.2
6.2
7.2
7.2
7.2
33
33
33
U
U
18
18
18
14
UO
28
170
14
33
160
160
8.2
33
37
28
0.066
0.066
0.066
0.066
3.6
28
8.2
65
170
2.6
1-25
-------
Table 1-3 (Continued)
TREATMENT STANDARDS FOR U AND P NONUASTEUATERS
AND MULTI-SOURCE LEACHATE (F039) INCLUDED IN VOLUME C
Waste
Code
UU2
U152
U155
U157
U158
U159
U161
U162
U165
U169
U170
U172
U174
U179
U180
U181
U183
U185
U187
U188
U192
U196
U203
U207
U208
U209
U210
U211
U220
U22S
U226
U227
U228
U239
U240
U243
U247
Regulated Constituent
Kepone
Methacrylom'trile
Methapyrilene
3-Methylcholanthrene
4,4'-Methylenebis(2-chloroaniline)
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl methacrylate
Naphthalene
Nitrobenzene
4-Nitrophenol
N -N itrosodi-n- butyl ami ne
N-Nitrosodiethylamine
N-Nitrosopiperidine
N-Nitrosopyrrolidine
5-Nitro-o-toluidine .
Pent ach I orobenzene
Pentach 1 oroni t robenzene
Phenacetin
Phenol
Pronamide
Pyridine
Safrole
1 , 2 , 4 , 5 - Tet rach I orobenzene
1,1, 1 ,2-Tetrachloroethane
1 , 1 ,2,2-Tetrachloroethane
Tet rach I oroethy I ene
Carbon tetrachloride
Toluene
Tribromomethane (Bromoform)
1,1, 1 -Trichlorocthane
1,1,2-Trichloroethane
Trichloroethylene
Xylenes (total)
2.4-Dichlorophenoxyacetic acid
Hexach loropropene
Methoxychlor
Treatment
Standard (mg/kg)
0.13
84
1.5
15
35
36
33
160
3.1
14
29
17
28
35
35
28
37
4.8
16
6.2
1.5
16
22
19
42
42
5.6
5.6
28
15
5.6
5.6
5.6
28
10
28
0.18
3 Units for the lead standard are mg/l; analyzed by TCLP extract.
1-26
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2.0 INDUSTRY AFFECTED AND WASTE CHARACTERIZATION
This section describes the industries affected by the land disposal
restrictions for the U and P wastes and multi-source leachate (F039) listed in
Table 1-3, the processes generating the wastes, the available characterization
data, and the determination of waste treatability groups.
2.1 Industry Affected and Process Description
2.1.1 U and P wastes
U or P wastes consist of a commercial chemical product or manufac-
turing intermediate from a non-specific source containing any of the chemicals
listed in 40 CFR 261.33(e) or (f) and in which the listed chemical is the sole
active ingredient. Commercial chemical products or manufacturing intermedi-
ates include all commercially pure grades of the listed chemical, all techni-
cal grades, and all formulated products in which the listed chemical is the
sole active ingredient. In addition, an off-specification product that, if it
met specification, would have the generic name included in either 261.33(e) or
(f) is a U or P waste. Any residue that is a listed chemical remaining in a
container or inner liner removed from a container that will not be recycled,
reclaimed, or reused; or any residue or contaminated soil, water, or debris
from a spill of such a chemical, is also a U or P waste. However, these
wastes do not include manufacturing process wastes. A waste occurs when a
product is:
• Discarded or intended to be discarded;
• Mixed with another material and applied to the land for dust
suppression or road treatment;
• Applied to land in lieu of its original intended use; or
• Distributed or burned as a fuel or fuel additive.
U wastes are identified as toxic; P wastes are identified as acutely hazard-
ous. Whether a waste is acutely hazardous or toxic generally has no bearing
on its treatability.
2-1
-------
Industries that generate the wastes listed in Table 1-3 include the
organic chemical, pharmaceutical, dye and pigment, textile and fiber,
pesticide, and rubber industries; universities; military compounds; and
treatment facilities throughout the United States. The Agency estimates that
there are approximately 1,200 facilities that may be affected by this rule.
The four-digit Standard Industrial Classification (SIC) codes associated with
the organic chemicals included in this document include 2869 (Industrial
Organic Chemicals, Not Elsewhere Classified), 2879 (Pesticides and
Agricultural Chemicals, Not Elsewhere Classified), and 2899 (Chemical and
Chemical Preparations, Not Elsewhere Classified). Table A-l in Appendix A
identifies the industrial uses of the commercial chemical products included in
Volumes A, B, and C. Table A-2 summarizes the total number of facilities that
may generate each waste code. The number of facilities that may generate each
waste code are listed by state and by EPA region in Table A-3.
2.1.2 Multi-Source Leachate (F039^
Leachate is defined in 40 CFR 260.10 as any liquid, including any
suspended components in the liquid, that has percolated through or drained
from hazardous waste. Leachate that is derived from the treatment, storage,
or disposal of listed hazardous waste is classified as a hazardous waste by
virtue of the "derived-from" rule in 40 CFR 261.3(c)(2). Multi-source
leachate (F039) is leachate that is derived from the treatment, storage, or
disposal of more than one listed hazardous waste or is leachate generated via
contact with more than one hazardous waste. (Leachate that is generated from
the treatment, storage, or disposal of only one listed hazardous waste is a
single-source leachate subject to the treatment standard established for the
waste from which it is derived.)
Multi-source leachate (F039) is most often generated by hazardous
waste treatment, storage, and disposal (TSD) facilities, although generators
who accumulate more than one hazardous waste on site may also generate multi-
source leachate. An example of multi-source leachate is liquid draining into
soil from a landfill unit that stores more than one hazardous waste.
2-2
-------
2.2 Waste Characterization
Waste characterization data are not currently available for any of
the waste codes included in this document. Due to the diversity of methods of
waste generation (e.g., off-specification products, spills in soil or water,
landfill leachate), the composition of these wastes varies greatly. The
constituents of concern in the wastes may be present at concentrations varying
from several parts per million to nearly 100% in virtually pure products.
2.3 Determination of Waste Treatabilitv Groups
The wastes included in this document were combined into treatability
groups based on similarities in elemental composition and in functional groups
present within the chemical structure of each waste. The industries that
generate these wastes were also considered in establishing these groups. In
most cases, the wastes within each treatability group are believed to be
similar in composition and chemical structure, and are therefore expected to
be able to be treated to similar levels by an applicable treatment technology.
The wastes were combined into twelve treatability groups:
• Aromatic Wastes;
• Brominated Organic Wastes;
• Halogenated Aliphatic Wastes;
'• Halogenated Pesticide and Chlorobenzene Wastes;
• Halogenated Phenolic Wastes;
• Oxygenated Hydrocarbon and Heterocyclic Wastes;
• Wastes of a Pharmaceutical Nature;
• Phenolic Wastes;
• Polynuclear Aromatic Wastes;
• Organo-nitrogen Compound Wastes;
• Miscellaneous Halogenated Organic Wastes; and
• Multi-Source Leachate (F039).
Chemical structures for the waste constituents are presented in Appendix B.
Table 2-1 at the end of this section presents, by treatability group, codes
that are discussed in this document.
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2.3.1 Aromatic Wastes
The waste codes included in this treatability group contain
compounds that are classified as aromatics. The structural feature common to
all of the compounds in this group is that all of the bonds of these compounds
are carbon-carbon and carbon-hydrogen bonds. Compounds in this group have one
or more of the following functional groups as part of their structure: an
aromatic ring, single carbon-carbon bonds, and double carbon-carbon bonds.
The following waste codes are included in this group:
U019 Benzene;
U220 Toluene; and
U239 Xylene(s).
2.3.2 Brominated Organic Wastes
The waste codes included in this treatability group include bro-
minated hydrocarbons. The Agency believes that the presence of bromine in the
chemical structure may require modified design and carefully controlled
operation of an incineration system. Therefore, the following waste codes
have been combined into a separate brominated organics treatability group:
• U029 Bromomethane (Methyl bromide);
• U030 4-Bromophenyl phenyl ether;
• U066 l,2-Dibromo-3-chloropropane;
U067 1,2-Dibromoethane;
• U068 Dibromomethane; and
• U225 Tribromomethane (Bromoform).
2.3.3 Halogenated Aliphatic Wastes
The waste codes included in this treatability group contain
compounds that are classified as halogenated aliphatics. These compounds have
common functional groups of single and double carbon-carbon bonds. The
compounds in this group also have chlorine atoms substituting for hydrogen
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atoms in at least one bond of the compound. The following waste codes are
included in this group:
• U044 Chloroform;
U076 1,1-Dichloroethane;
• U077 1,2-Dichloroethane;
U078 1,1-Dichloroethylene;
U079 trans-l,2-Dichloroethylene;
U080 Methylene chloride;
U083 1,2-Dichloropropane;
U084 1,3-Dichloropropylene;
• U131 Hexachloroethane;
U208 1,1,1,2-Tetrachloroethane;
U209 1,1,2,2-Tetrachloroethane;
U210 Tetrachloroethylene;
U211 Carbon tetrachloride;
U226 1,1,1-Trichloroethane;
U227 1,1,2-Trichloroethane;
• U228 Trichloroethylene; and
• U243 Hexachloropropylene.
2.3.4
Halogenated Pesticide and Chlorobenzene Wastes
The waste codes included in this treatability group include the
following general chemical structures (see Appendix B for illustrations):
chlorinated nonbornane or nonbomene derivatives; chlorobenzenes;
chlorophenoxycarboxylic acid and derivatives; chlorinated diphenyls; and
gamma-BHC and hexachlorobutadiene. Host of these wastes are generated in the
pesticides and agricultural chemicals industries. The following waste codes
are included in this treatability group:
P004 Aldrin;
P037 Dieldrin;
P050 Endosulfan;
P051 Endrin;
P059 Heptachlor;
• P060 Isodrin;
• PI23 Toxaphene;
• U036 Chlordane (alpha and gamma);
U037 Chlorobenzene;
U060 ODD;
U061 DDT;
• U070 o-Dichlorobenzene;
• U071 m-Dichlorobenzene;
• U072 p-Dichlorobenzene;
• U127 Hexachlorobenzene;
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• U128 Hexachlorobutadiene;
• - U129 gamma-BHC (Lindane);
• U130 Hexachlorocyclopentadiene
U142 Kepone;
• U183 Pentachlorobenzene;
• U185 Pentachloronitrobenzene;
U207 1,2,4,5-Tetrachlorobenzene;
• U240 2,4-Dichlorophenoxyacetic acid; and
U247 Methoxychlor.
2.3.5 Halogenated Phenolic Wastes
The waste codes included in this treatability group contain
compounds that are classified as halogenated phenols. The functional groups
common to all of the compounds in this group are an aromatic ring and a
carbon-oxygen-hydrogen single bond system. In addition, all of these
compounds have at least one chlorine atom attached to the aromatic ring.
Based on these similarities in elemental composition and functional groups,
the waste codes listed below were grouped together:
• U039 p-Chloro-m-cresol;
• U048 2-Chlorophenol;
U081 2,4-Dichlorophenol; and
U082 2,6-Dichlorophenol.
2.3.6 Oxygenated Hydrocarbon and Heterocvclic Wastes
The waste codes included in this treatability group are judged to be
structurally similar, based on the presence of oxygen-containing functional
groups. These compounds contain at least one oxygen atom integrated into the
chemical structure by a single or double bond to a carbon. This group also
includes functional groups such as ketones, aldehydes, and alcohols.
Accordingly, the following oxygenated hydrocarbon and heterocyclic wastes were
combined into one treatability group:
U002 Acetone;
• U004 Acetophenone;
U031 n-Butyl alcohol;
U108 1,4-Dioxane;
U112 Ethyl acetate;
U117 Ethyl ether;
U118 Ethyl methacrylate;
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U140 Isobutyl alcohol;
• ~ U159 Methyl ethyl ketone;
U161 Methyl isobutyl ketone; and
• U162 Methyl methacrylate.
2.3.7 Wastes of a Pharmaceutical Nature
Waste codes included in this treatability group are wastes asso-
ciated with the pharmaceutical industry or wastes that are similar to pharma-
ceutical wastes. All of the waste constituents included in this group are
large, complex, heavily-substituted molecules. Almost all of the waste
constituents are aromatic with nitrogen- or sulfur-heterocyclic structures or
polynuclear aromatic structures. All of the waste constituents have multiple
double bonds and include oxygen, nitrogen, or sulfur atoms. The following
waste codes are included in this treatability group:
U141 Isosafrole;
U155 Methapyrilene;
U187 Phenacetin; and
U203 Safrole;
2.3.8 Phenolic Wastes
The waste codes included in this treatability group represent
compounds that are classified as phenols and nitrophenols. The functional
groups common to all of the compounds in this group are an aromatic ring and a
carbon-oxygen-hydrogen single bond system. The hydroxyl group is attached
directly to the aromatic ring. The nitrophenols also have a nitro group (N02)
attached directly to the ring. Based on these similarities in elemental
composition and functional groups, the waste codes listed below were grouped
together:
• P020 2-sec-Butyl-4-6-dinitrophenol (Dinoseb);
• P047 4,6-Dinitro-o-cresol;
P048 2,4-Dinitrophenol;
• U052 Cresols (o-, m-, and p- isomers);
U101 2,4-Dimethylphenol;
• U170 4-Nitrophenol; and
U188 Phenol.
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2.3.9 Polvnuclear Aromatic Wastes
The waste codes included in this treatability group represent
compounds that are classified as polynuclear aromatics. These compounds
contain at least two fused or bridged aromatic rings and have an aromatic ring
as the common functional group. The compounds in this group also have several
substituents attached to their rings, including amides. In some cases, one of
the aromatic carbons may be substituted with another element. The following
waste codes are included in this group:
• U005 2-Acetylarainofluorene;
• U018 Benz(a)anthracene;
• U022 Benzo(a)pyrene;
U050 Chrysene;
• U051 Creosote (naphthalene, pentachlorophenol,
phenanthrene, pyrene, toluene, xylene(s), lead);
• U063 Dibenz(a,h)anthracene;
U120 Fluoranthene;
U137 Indeno(l,2,3-c,d)pyrene;
• U157 3-Methylcholanthrene; and
U165 Naphthalene.
2.3.10 Organo-nitrogen Compound Wastes
EPA grouped all remaining non-halogenated wastes containing nitrogen
functional groups that were not included in the waste treatability groups
described above into the organo-nitrogen compound treatability group. The
waste codes in the organo-nitrogen compound treatability group include the
following general chemical structures (see Appendix B for illustration):
nitrogen heterocyclics; amines and amides; aminated diphenyls and biphenyls;
nitriles; nitro compounds; and nitroso compounds. The following waste codes
have been combined into this treatability group:
• P077 p-Nitroaniline;
• .P101 Ethyl cyanide (Propanenitrile);
U009 Acrylonitrile;
U012 Aniline;
• U105 2,4-Dinitrotoluene;
• U106 2,6-Dinitrotoluene;
• Ulll Di-n-propylnitrosamine;
• U152 Methacrylonitrile;
• U169 Nitrobenzene;
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U172 N-Nitrosodi-n-butylamine;
U174 N-Nitrosodiethylamine
U179 N-Nitrosopiperidine;
U180 N-Nitrosopyrrolidine;
U181 5-Nitro-o-toluidlne; and
U196 Pyridine.
2.3.11 Miscellaneous Halogenated Organic Wastes
EPA grouped all remaining halogenated organic wastes that were not
included in other waste treatability groups described above into the
miscellaneous halogenated organics treatability group. The miscellaneous
halogenated organic waste codes include the following general chemical
structures (see Appendix B for illustration): chlorinated diphenyls;
chlorinated polynuclear aromatics; chlorinated amines, amides, and nitriles;
chlorinated methylbenzenes; halogenated aliphatics; halogenated aldehydes,
ethers, and esters; and halogenated organosulfur compounds. The following
waste codes are included in this group:
• P024 p-Chloroaniline;
• U024 Bis(2-chloroethoxy)methane;
U025 Bis(2-chloroethyl)ether;
• U027 Bis(2-chloroisopropyl)ether;
U043 Vinyl'chloride;
• U045 Chloromethane;
U047 2-Chloronaphthalene;
• U075 Dichlprodifluoromethane;
• U121 Trichloromonofluoromethane;
• U138 Iodomethane;
U158 4,4'-Methylenebis(2-chloroaniline); and
U192 Pronamide.
2.3.12 Multi-Source Leachate (F039)
The multi-source leachates (F039) included in this document are
grouped together for organizational purposes rather than for common
treatability characteristics. As noted in Section 2.1.2, they are all
generated in a similar fashion. Section 5.0 contains a discussion of the
regulated constituents in F039.
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TABLE 2-1
TREATABILITY GROUPS FOR NONWASTEWATER FORMS OF ANALYZABLE
ORGANIC U AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
AROMATIC WASTES
U019 Benzene
U220 Toluene
U239 Xylenes
BROMINATED ORGANIC WASTES
U029 Bromomethane (Methyl bromide)
U030 4-Bromophenyl phenyl ether
U066 1,2-Dibromo-3-chloropropane
U067 1,2-Dibromoethane
U068 Dibromomethane
U225 Tribromomethane (Bromoform)
HALOGENATED ALIPHATIC WASTES
U044 Chloroform
U076 1,1-Dichloroethane
U077 1,2-Dichloroethane
U078 1,1-Dichloroethylene
U079 trans-l,2-Dichloroethylene
U080 Methylene chloride
U083 1,2-Dichloropropane
U084 1,3-Dichloropropylene
U131 Hexachloroethane
U208 1,1,1,2-Tetrachloroethane
U209 1,1,2,2-Tetrachloroethane
U210 Tetrachloroethylene
U211 Carbon tetrachloride
U226 1,1,1-Trichloroethane
U227 1,1,2-Trichloroethane
U228 Trichlorethylene
U243 Hexachloropropylene
HALOGENATED PESTICIDE AND CHLOROBENZENE WASTES
P004 Aldrin
P037 Dieldrin
P050 Endosulfan
P051 Endrin
P059 Heptachlor
P060 Isodrin
PI23 Toxaphene
U036 Chlordane (alpha and gamma)
U037 Chlorobenzene
U060 ODD
U061 DDT
U070 o-Dichlorobenzene
U071 m-Dichlorobenzene
U072 p-Dichlorobenzene
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TABLE 2-1 (Continued)
TREATABILITY GROUPS FOR NONWASTEWATER FORMS OF ANALYZABLE
ORGANIC U AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
HALOGENATED PESTICIDE AND CHLOROBENZENE WASTES (Continued)
U127 Hexachlorobenzene
U128 Hexachlorobutadiene
U129 gamma-BHC (Lindane)
U130 Hexachlorocyclopentadiene
U142 Kepone
U183 Pentachlorobenzene
U185 Pentachloronitrobenzene
U207 1,2,4,5-Tetrachlorobenzene
U240 2,4-Dichlorophenoxyacetic acid
U247 Methoxychlor
HALOGENATED PHENOLIC WASTES
U039 p-Chloro-m-cresol
U048 2-Chlorophenol
U081 2,4-Dichlorophenol
U082 2,6-Dichlorophenol
OXYGENATED HYDROCARBON AND HETEROCYCLIC WASTES
U002 Acetone
U004 Acetophenone
U031 n-Butyl alcohol
U108 1,4-Dioxane
U112 Ethyl acetate
U117 Ethyl ether
U118 Ethyl methacrylate
U140 Isobutyl alcohol
U159 Methyl ethyl ketone
U161 Methyl isobutyl ketone
U162 Methyl methacrylate
WASTES OF A PHARMACEUTICAL NATURE
U141 Isosafrole
U155 Methapyrilene
U187 Phenacetin
U203 Safrole
PHENOLIC WASTES
P020 2-sec-Butyl-4,6-dinitrophenol (Dinoseb)
P047 4,6-Dinitro-o-cresol
P048 2,4-Dinitrophenol
U052 Cresol •
U101 2,4-Dimethylphenol
U170 4-Nitrophenol
U188 Phenol
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TABLE 2-1 (Continued)
TREATABILITY GROUPS FOR NONWASTEWATER FORMS OF ANALYZABLE
ORGANIC U AND P WASTES AND MULTI-SOURCE LEACHATE (F039)
POLYNUCLEAR AROMATIC WASTES
U005 2-Acetylaminofluorene
U018 Benz(a)anthracene
U022 Benzo(a)pyrene
U050 Chrysene
U051 Creosote
U063 Dibenz(a,h)anthracene
U120 Fluoranthene
U137 Indeno(l,2,3-c,d)pyrene
U157 3-Methylcholanthrene
U165 Naphthalene
ORGANO-NITROGEN COMPOUND WASTES
P077 p-Nitroaniline
P101 Ethyl cyanide (Propanenitrile)
U009 Acrylonitrile
U012 Aniline
U105 2,4-Dinitrotoluene
U106 2,6-Dinitrotoluene
Ulll Di-n-propylnitrosamine
U152 Methacrylonitrile
U169 Nitrobenzene
U172 N-Nitrosodi-n-butylamine
U174 N-Nitrosodiethylamine
U179 N-Nitrosopiperidine
U180 N-Nitrosopyrrolidine
U181 5-Nitro-o-toluidine
U196 Pyridine
MISCELLANEOUS HALOGENATED ORGANIC WASTES
P024 p-Chloroaniline
U024 Bis(2-chloroethoxy)methane
U025 Bis(2-chloroethyl)ether
U027 Bis(2-chloroisopropyl)ether
U043 Vinyl chloride
U045 Chloromethane (Methyl chloride)
U047 2-Chloronaphthalene
U075 Dichlorodifluoromethane
U121 Trichloromonofluoromethane
U138 Iodomethane
U158 4,4'-Methylenebis(2-chloroaniline)
U192 Pronamide
F039 MULTI-SOURCE LEACHATE
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3.0 IDENTIFICATION OF BEST DEMONSTRATED AND AVAILABLE TECHNOLOGY (BOAT)
This section presents the Agency's rationale for determining the
best demonstrated available technology (BDAT) for nonwastewater forms of
multi-source leachate (F039) and analyzable organic U and P wastes. BDAT for
organic constituents with concentration-based treatment standards is
incineration. BDAT for metal constituents with concentration-based treatment
standards is stabilization.
This section presents the Agency's determination of:
• Applicable technologies;
• Demonstrated technologies; and
• The best demonstrated available technology (BDAT) for treatment
of these wastes.
In determining BDAT, the Agency first determines which technologies are
potentially applicable for treatment of the waste(s) of interest. The Agency
then determines which of the applicable technologies are demonstrated for
treatment of the waste(s) of Interest. Next, the Agency determines which of
the demonstrated technologies is "best" for the purpose of establishing BDAT.
Integral to the determination of BDAT is the evaluation of all available
treatment performance data. The treatment performance data that were
evaluated to determine BDAT f|or these wastes are presented in Section 4.0.
Finally, the Agency determines whether the best demonstrated technology is
available, for treatment of the waste(s) of interest.
The U and P wastes and the majority of the regulated constituents in
multi-source leachate (F039) included in this document are organic.
Therefore, treatment technologies are identified in this section for treatment
of hazardous organic constituents. Treatment technologies for metal
constituents in U051 and multi-source leachate are also identified in this
section.
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3.1 Applicable Treatment Technologies
To be applicable, a technology must theoretically be usable to treat
the waste. Detailed descriptions of technologies that are applicable to treat
listed hazardous wastes are provided in EPA's Treatment Technology Background
Document (Reference 3).
3.1.1 Organic Constituents
Since nonwastewater forms of the U and P and multi-source leachate
(F039) wastes may contain hazardous organic constituents at treatable
concentrations, applicable treatment technologies include those that destroy
or reduce the total amount of various organic compounds in the waste. The
Agency has identified the following treatment technologies as applicable for
these wastes:
• Incineration (fluidized-bed, rotary kiln, and liquid injec-
tion) ;
• Fuel substitution;
• Solvent extraction followed by incineration or recycle of the
extract; and
• Critical fluid extraction followed by incineration of the
contaminated solvents.
Total recycle or reuse may also be applicable for certain wastes, such as off-
specification commercial chemical products. These treatment technologies were
identified based on current waste treatment practices and engineering judg-
ment.
Incineration
Incineration is a destruction technology in which energy, as heat,
is transferred to the waste to destabilize chemical bonds and destroy hazard-
ous organic constituents. In a fluidized-bed incinerator, waste is injected
into the fluidized-bed material (generally sand and/or incinerator ash), where
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it is heated to its ignition temperature. Heat energy from the combustion
reactions is then transferred back to the fluidized bed. Ash is removed
periodically during operation and during bed change-outs.
In a rotary kiln incinerator, wastes are fed into the elevated end
of the kiln, and the rotation of the kiln mixes the waste with hot gases to
heat the waste to its ignition temperature. Ash is removed from the lower end
of the kiln. Combustion gases from the kiln enter the afterburner for com-
plete destruction of organic waste constituents. Other wastes may also be
injected into the afterburner.
In a liquid injection incinerator, liquid wastes are atomized and
injected into the incinerator. In general, only wastes with low or negligible
ash contents are amenable to liquid injection incineration. Therefore, this
technology generally does not generate an ash residual.
Combustion gases from the incinerator are then fed to a scrubber
system for cooling and removal of entrained particulates and acid gases, if
present. In general, with the exception of liquid injection incineration, two
residuals are generated by incineration processes: ash and scrubber water.
Fuel Substitution
Fuel substitution is a destruction technology in which energy, as
heat, is transferred to the waste to destabilize chemical bonds and destroy
organic constituents. Fuel substitution differs from incineration in that the
waste is used as a fuel in industrial furnaces or boilers. Two residuals may
be generated by the fuel substitution process: ash and scrubber water.
Solvent Extraction
Solvent extraction is a separation technology in which organics are
removed from the waste due to greater constituent solubility in the solvent
phase than in the waste phase. This technology generates two residuals: a
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treated waste residual and an extract. The extract may be recycled or may be
treated by incineration.
Critical Fluid Extraction
Critical fluid extraction is a solvent extraction technology in
which the solvent is brought to its critical state (liquified gas) to aid in
the extraction of hazardous organic constituents from the wastes. After the
extraction step, the solvent is returned to its normal gaseous state, generat-
ing a small volume of extract that is concentrated in hazardous organic
constituents. This technology generates two residuals: a treated waste
residual and an extract. The extract may be recycled or may be treated by
incineration.
Total Recycle or Reuse
Total recycle or reuse of a waste in the same process or another
process eliminates the generation of the waste and consequently generates no
treatment residuals.
3.1.2 Metal Constituents
Since nonwastewater forms of the U and P and multi-source leachate
(F039) wastes may contain hazardous metal constituents in treatable
concentrations, applicable treatment technologies include those that destroy,
immobilize, or reduce the amount of metals in the waste. The Agency has
identified the following treatment technologies as applicable for these
wastes:
• Stabilization; and
• Acid leaching.
Stabilization
Stabilization refers to a broad class of treatment processes that
chemically reduce the mobility of metal constituents in a waste by binding
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them into a solid material that resists leaching when water or a mild acid
solution comes into contact with the waste material. Organic materials are
not usually effectively stabilized and may, in fact, inhibit the stabilization
of metals. Hence, stabilization is applicable to nonwastewaters only after
the organics have been removed by other treatment, such as incineration.
Acid Leaching
Acid leaching is a separation technology used to recover metals from
wastes in solid or slurry form. This process is most effective with wastes
containing high concentrations of metals that are soluble in a strong acid
solution or that can be converted by reaction with a strong acid to a soluble
form.
3.2 Demonstrated Treatment Technologies
To be demonstrated, a technology must be employed in full-scale
operation for treatment of the waste in question or a similar waste. Technol-
ogies available only at pilot1- or bench-scale operations are not considered in
identifying demonstrated technologies.
3.2.1 Organic Constituents
The Agency has identified incineration as a demonstrated technology
for treatment of organic constituents in nonwastewater forms of the U and P
and multi-source leachate (F039) wastes. For the land disposal restrictions
program, the Agency conducted rotary kiln incineration tests on a full-scale
operational basis. The Agency also conducted an ethylene dibromide (EDB)
incineration test. The following waste constituents in each treatability
group were incinerated in at least one of the incineration tests, as described
in Section 4.0:
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Aromatic Wastes
U019 Benzene
U220 Toluene
U239 Xylenes
Brominated Organic Wastes
U067 1,2-Dibromoethane (Ethylene dibromide)
Halogenated Aliphatic Wastes
U044 Chloroform
U076 1,1-Dichloroethane
U077 1,2-Dichloroethane
U080 Methylene chloride
U131 Hexachloroethane
U210 Tetrachloroethylene
U211 Carbon tetrachloride
U226 1,1,1-Trichloroethane
U227 1,1,2-Trichloroethane
U228 Trichloroethylene
Halogenated Pesticide and Chlorobenzene Wastes
P059 Heptachlor
U036 Chlordane
U037 Chlorobenzene
U070 o-Dichlorobenzene
U072 p-Dichlorobenzene
U127 Hexachlorobenzene
U128 Hexachlorobutadiene
U130 Hexachlorocyclopentadiene
U183 Pentachlorobenzene
U185 Pentachloronitrobenzene
.U207 1,2,4,5-Tetrachlorobenzene
U240 2,4-Dichlorophenoxyacetic acid
U247 Methoxychlor
Halogenated Phenolic Wastes
U081 2,4-Dichlorophenol
U082 2,6-Dichlorophenol
OxvEenated Hydrocarbon and Heterocyclic Wastes
U159 Methyl ethyl ketone
U161 Methyl isobutyl ketone
Wastes of a Pharmaceutical Nature
U141 Isosafrole
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Phenolic Wastes
P020 2-sec-Butyl-4,6-dlnitrophenol (Dinoseb)
U052 o-Cresol
U052 p-Cresol
U188 Phenol
Polvnuclear Aromatic Wastes
U018 Benz(a)anthracene
U022 Benzo(a)pyrene
U050 Chrysene
U051 Creosote
U120 Fluoranthene
U137 Indeno(l,2,3-c,d)pyrene
Oreano-nitrogen Compound Wastes
U009 Acrylonitrile
U012 Aniline
U169 Nitrobenzene
U196 Pyridine
Miscellaneous Halogenated Organic Wastes
U025 Bis(2-chloroethyl)ether
U043 Vinyl chloride
U045 Chloromethane (methyl Chloride)
U075 Dichlorodifluoromethane
U192 Pronamide
Multi-Source Leachates
All of the above
The Agency believes that since incineration is demonstrated for treatment of
the above waste constituents, treatment is therefore demonstrated for all
organic waste constituents within each treatability group. Analytical data
and complete discussions of the test methods used are available in the
corresponding on-site engineering reports (OERs) for each test. A list of the
treatment tests conducted by the Agency as part of the BOAT program, along
with references for the corresponding OERs, is provided in Table 4-1.
The Agency is not aware of any facilities that treat by fuel
substitution the nonwastewater forms of the wastes included in this document;
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therefore, the Agency believes that fuel substitution is not currently
demonstrated for these wastes.
The Agency is not aware of any facilities that treat nonwastewater
forms of the wastes included in this document, or wastes judged to be similar,
on a full-scale operational basis using solvent extraction or critical fluid
extraction; therefore, EPA believes that these technologies are not currently
demonstrated for these wastes.
The Agency believes that recycling and reuse is applicable for off-
specification U and P wastes; however, the Agency is only aware of facilities
that do so for various pesticide U and P wastes. Therefore, recycle and reuse
is not considered demonstrated for multi-source leachate (F039) or U or P
wastes other than some pesticide wastes.
3.2.2 Metal Constituents
The Agency has identified stabilization as a demonstrated technology
for treatment of metals in U051 (creosote) nonwastewaters and in multi-source
leachate (F039) nonwastewaters. Stabilization has been demonstrated on a
full-scale operational basis for wastes similar to these wastes, as discussed
in Section 4.0.
The Agency is not aware of any facilities that treat nonwastewater
forms of the wastes included in this document, or wastes judged to be similar,
on a full-scale operational basis using acid leaching; therefore, EPA believes
that this technology is not currently demonstrated for these wastes.
3.3 Identification of Best Demonstrated and Available Technology (BOAT)
EPA determines best demonstrated and available technology (BOAT)
based on a thorough review of all the treatment data available on the waste of
concern or wastes judged to be similar. The treatment performance data that
were evaluated for the U and P and multi-source leachate (F039) wastes are
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presented in Section 4.0. The treatment performance data are first screened
to determine:
• Whether the data represent operation of a well-designed and
well-operated treatment system;
• Whether sufficient analytical quality assurance/quality control
measures were employed to ensure the accuracy of the data; and
• Whether the appropriate measure of performance was used to
assess the performance of the particular treatment technology.
Following the identification of the "best" demonstrated technology,
the Agency determines whether the technology is "available." An available
treatment technology is one that (1) is not a proprietary or patented process
that cannot be purchased or licensed from the proprietor (i.e., it must be
commercially available), and (2) substantially diminishes the toxicity of the
waste or substantially reduces the likelihood of migration of hazardous
constituents from the waste.
3.3.1 Organic Constituents
EPA has identified incineration as demonstrated for organic
constituents in nonwastewater forms of the U and P and multi-source leachate
(F039) wastes. EPA has data from the incineration of constituents included in
each waste treatability group.
All of the incineration data included in Section 4.0 represent BOAT
for wastes included in previous rulemakings and therefore have already met the
above conditions, with the exceptions of tests 13 and 14, and the ethylene
dibromide incineration test. Treatment performance data and design and
operating data for tests 13 and 14 and the ethylene dibromide incineration
test are included or are referenced in Section 4.0. These treatment systems
were well-designed and well-operated, and sufficient analytical quality
assurance/quality control measures were employed during the tests. The
appropriate measure of performance (total constituent concentration) was used
to assess the treatment systems. Therefore, tests 13 and 14 and the ethylene
dibromide test meet the above conditions. Thus, incineration is the "best"
3-9
-------
technology for treating organic nonwastewater forms of these wastes in each
treatability group.
Incineration, identified as the "best" technology for these organic
wastes, is commercially available. Treatment performance data included in
Section 4.0 show substantial treatment by incineration for waste constituents
of concern and other similar constituents. Therefore, incineration is
"available," and therefore BOAT, for treatment of the organic wastes included
in this document.
3.3.2 Metal Constituents
EPA has identified stabilization as demonstrated for metal
constituents in nonwastewater forms of the U and P and multi-source leachate
(F039) wastes.
All stabilization data presented in Section 4.0 represent "best" for
wastes included in previous rulemakings, and therefore have already been
determined to meet the conditions described above regarding well-designed and
well-operated treatment systems, QA/QC measures, and appropriate measures of
performance. In addition, as stabilization is the only technology considered
to be demonstrated for the metal constituents, it is also the best
demonstrated technology for these wastes. Hence, stabilization is "best" for
metal constituents in nonwastewaters.
Stabilization, identified as a "best" technology for the metal
constituents, is commercially available. Treatment performance data for
stabilization, included or referenced in Section 4.0, show substantial
reduction in the mobilization of metals of concern and other similar
constituents. Therefore, stabilization is "available," and therefore BOAT,
for treatment of the metal waste constituents in this document.
3-10
-------
4.0 TREATMENT PERFORMANCE DATA
This section presents the data available to EPA on the performance
of treatment technologies that are demonstrated for treatment of nonwastewater
forms of the U and P wastes and multi-source leachate (F039) included in this
document. Treatment performance data are used elsewhere in this document to
determine which technologies represent BOAT (Section 3.3), to select
constituents for regulation (Section 5.0), and to develop treatment standards
(Section 6.0). In addition to using treatment performance data from full-
scale operations, eligible data may include that developed at research
facilities or obtained at less than full-scale operations, provided that the
technology is demonstrated in full-scale operation for the waste or similar
wastes.
In an effort to account for the wide range of physical forms and
chemical compositions of nonwastewater forms of organic U and P wastes and
multi-source leachate (F039), EPA examined all available BDAT incineration
data to develop treatment standards for these wastes. Specifically, the
Agency considered treatment performance data from the 14 EPA-conducted
incineration tests listed in Table 4-1. (All tables are presented at the end
of this section.)
In most cases, for the organic U and P wastes and the corresponding
multi-source leachate (F039) constituents, multiple sets of treatment
performance data were used to develop treatment standards. In cases where an
individual waste constituent of concern was detected in the untreated or
treated wastes from one or more treatment tests, data from only those tests
were used to develop treatment standards for that constituent. If an
individual constituent of concern was not detected in any of the untreated or
treated wastes from the 14 incineration tests, the Agency believes that the
constituent would be treated by incineration similarly to other constituents
in the same treatability group that were detected. Therefore, detection
limits achieved for that individual constituent of concern in ash from all the
tests were used to develop treatment standards. The methodology used to
develop these treatment standards is discussed in more detail in Section 6.0,
4-1
-------
and the data that were used to develop treatment standards for these wastes
are presented in this section.
Treatment performance data, to the extent that they are available to
EPA, include the concentrations for a given constituent in the untreated and
treated wastes, values of operating parameters measured at the time the waste
was treated, and values of relevant design parameters for the treatment
technology. Only treatment performance data for the waste constituents of
interest are presented in this section. Values of design and operating
parameters for each incineration treatment test can be found in the
corresponding On-Site Engineering Report for each test (References 4
through 17).
Table 4-2 presents the highest detection limits available for the
incinerator ash in all 14 incineration tests for the regulated organic waste
constituents included in this document. More than one detection limit for a
constituent in the ash from an incineration test may have been reported. To
account for the anticipated variability in untreated U and P wastes, the
highest detection limit for the constituent was selected and is presented in
Table 4-2. Appendix C presents data for waste constituents that were detected
in the untreated waste, incinerator ash, or scrubber water in one or more of
the 14 incineration tests listed in Table 4-1.
After reviewing treatment performance data from the 14 incineration
tests, the Agency determined that the data from.Tests 3, 5, and 6 were not
suitable for use in developing treatment standards for organic U and P and
multi-source leachate (F039) nonwastewaters. Data from Test 3 were not
considered because the detection limits were clearly above the average
detection limits for the other incineration tests. In addition, the wastes
treated in Test 3 did not contain significant concentrations of the
constituents of concern. Data from Tests 5 and 6 were not considered because
the wastes treated were K024 (a ph.thaiic anhydride waste) and K037 (a
disulfoton waste). These wastes represent unique matrices that the Agency
does not believe are representative of U and P or multi-source leachate (F039)
4-2
-------
waste matrices included in this document. Therefore, data from Tests 3, 5,
and 6 were not considered further in developing treatment standards.
In general, treatment standards for the organic constituents in U
and P wastes and multi-source leachate (F039) were calculated using data for
the appropriate constituent or constituents from the remaining 11 incineration
tests listed in Table 4-1. The following subsections discuss, by treatability
group, waste codes for which data were not available from the incineration
tests or for which the data from the incineration tests were not appropriate
for use in calculating treatment standards.
4.1 U and P Nonwastewaters
4.1.1 Brominated Organic Wastes
The Agency is aware of several facilities that currently incinerate
bromine-containing wastes. Recently, at Rollins Environmental Services, Deer
Park, Texas, the Agency incinerated ethylene dibromine wastes that were
cancelled pesticides under FIFRA provisions. Excess oxygen conditions had to
be carefully controlled to reduce the amount of bromine gas and to increase
the amount of hydrogen bromine gas generated by incineration. Hydrogen
bromine is readily absorbed by the air pollution control devices (APCDs),
while bromine is difficult to remove by APCDs. The Agency believes that
control of the undesirable conversion of the bromine-containing waste to
bromine gas significantly affects the design and operation of the incineration
systems. For these reasons, the Agency does not believe that transfer of
treatment performance data from incineration of non-brominated wastes (i.e.,
from any of the 14 tests listed in Table 4-1) is technically valid for the
purpose of developing numerical treatment standards for brominated organic
wastes.
Therefore, treatment performance data from the ethylene dibromide
incineration test were used to develop treatment standards for U067 (ethylene
I
dibromide) and were transferred to the remaining waste codes in the brominated
organics treatability group. Treatment performance data from the ethylene
4-3
-------
dibromide incineration test for the untreated waste feed and the incinerator
ash treatment residual are included in Table 4-3. Design data for the
treatment systems used for the ethylene dibromide incineration test are
included in Table 4-4.
4.1.2 Halogenated Pesticides and Chlorobenzenes
Treatment performance data for the o,p'-isomers for ODD, DDE, and
DDT (U060 and U061) are not available. Therefore, incineration treatment
performance data were transferred from the p,p'-isomers, based on structural
similarities, the purpose of developing BOAT treatment standards.
The Agency believes that the detection limits available for isodrin
(P060) in incinerator ash are too low to be routinely achievable by analytical
laboratories. Therefore, the Agency is transferring the treatment performance
data for aldrin (P004) to isodrin for the purpose of developing BDAT treatment
standards.
4.1.3 Polvnuclear Aromatic Wastes
U051 differs from the other wastes in the polynuclear aromatic
treatability group in that it is not defined by one chemical or constituent,
but by a group of chemicals defined by the generic name "creosote." Creosote
is a derivative of coal that contains a wide range of constituents, including
cresols, phenols, naphthalene, benz(a)anthracene, benzo(a)pyrene,
fluoranthene, chrysene, indeno(l,2,3-c,d)pyrene, acenaphthalene, and lead.
The presence of these polynuclear aromatics is the reason that this waste code
has been placed in this treatability group.
Treatment performance data for the organic constituents in U051 were
obtained from the 11 incineration tests discussed in Section 4.1. Treatment
performance data for lead in U051 nonwastewaters were transferred from
stabilization of metals in F006. (Section 5.0 discusses selection of
regulated constituents.) The treatment performance data for stabilization of
F006 is available in the BDAT Background Document for F006 (Reference 20).
4-4
-------
4.2 Multi-Source Leachate (FQ39'>
For the majority of the regulated organic constituents in
nonwastewater forms of multi-source leachate (F039), the Agency is developing
treatment standards based on the incineration performance data used to develop
treatment standards for the corresponding U or P waste. For the multi-source
leachate constituents that do not correspond to a U or P waste, the Agency is
developing treatment standards based on treatment performance data from a
variety of sources. The data sources are described in Section 6.0.
4-5
-------
Table 4-1
WASTES TESTED BY INCINERATION
Test Number
1
2
3
4
5
6
7
8
9
10
11
12
13
14
Waste Code(s) Tested
K001-Pentachlorophenol
KOOl-Creosote
K011, K013, K014
K019
K024
K037
K048, K051
K087
K101
K102
F024
K015
D014, D016, P059a,
U127a, U192a
U141a, U028a, P020a,
U122a, U226a, U2398,
U080a, U220a, U166a,
U161a, Ul88a
On-Site
Engineering Background
Technology Report Document
Used Reference(s) Reference
Rotary Kiln
RotaryKiln
Rotary Kiln
Rotary Kiln
Rotary Kiln
Rotary Kiln
Fluidized-Bed
Rotary Kiln
Rotary Kiln
Rotary Kiln
Rotary Kiln
Liquid Injection
Rotary Kiln
4
5
6
7
8
9
10,11
12
13
14
15
16
17
21
21
NA
22 .
23
24
25
26
27
28
29
30
NA
Rotary Kiln
17
NA
NA - Not applicable.
"Commercial chemical products were used in these incineration tests as
surrogates for these wastes.
4-6
-------
Table 4-2
SUMMARY OF DETECTION LIMITS FOR WASTE CONSTITUENTS
FROM THE FOURTEEN EPA INCINERATION TESTS *
Waste BDAT
Code No. Constituent
Test No. ** -> 1
Detection Limit (ppm)
45 6
10
11
13
U
AROMATIC WASTES
U019 4 Benzene
U220 43 Toluene
U239 215-217 Xylenes
HALOGENATEO ALIPHATIC WASTES
U044
U076
U077
U078
U079
U080
U083
U084
U084
U131
U209
U208
U210
U211
U226
*- U227
^, U228
U243
14
22
23
24
25
38
26
28
27
113
41
40
42
7
45
46
47
115
HALOGENATED
P004
P037
P050
P050
P050
P051
P051
P059
P059
P060
P123
U036
U037
U060
U061
U061
U061
172
181
182
183
238
184
185
186
187
188
191
177
9
178
178
179
180
Chloroform
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethylene
trans- 1,2-Dichloroethylene
Methylene chloride
1 , 2 - D i ch I oropropane
cis-1,3-Dichloropropylene
trans-1,3-Dichloropropylene
Hexach I oroethane
1 , 1 ,2,2-Tetrachloroethane
1,1, 1 ,2-Tetrachloroethane
Tetrachloroethylene
Carbon tetrachloride
1,1,1-Trichloroethane
1,1.2-Trichloroethane
Trichloroethylene
Hexach I oropropy I ene
PESTICIDE AND CHLOROBENZENE WASTES
Atdrin
Dieldrin
Endosulfan 1
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxide
Isodrin
Toxaphene
Chlordane (alpha and gamma)
Chlorobenzene
ODD
ODD
DDE
DDT
2
2 a
2 a
2
2
2
2
2
10 c
5
5
5
0.5
2
2
2
2
2
2
2
0.5
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2
NA
NA
NA
NA
10
10
10
10
10
10
10
10
50
10
10
10
0.11
10
10
10
10
10
10
10
0.3S
0.001
0.001
0.001
0.001
NA
0.001
0.002
0.001
0.001
0.001
0.1
0.015
10
0.002
0.002
0.001
0.002
a 2 a.b
a 2 a
a 2 a
2 c
2
2
2
2
50
5
5
5
10
2
2
2 a
2
2
2
2
10
0.0000015
0.0000015
0.0000015
0.0000015
NA
0.000015
0.000003
0.0000010
0.0000015
0.0000015
0.0002
0.0002
0.002
0.000003
0.000003
0.0000015
0.000003
2
2 c
2
2 a
2 a
2 a
2
2
10
5
5
5
10 a
2
2
2 a
2 a
2 a
2
2 a
10
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2 a
NA
NA
NA
NA
2 a.b.c
2 a.b.c
2 c
2
2
2
2
2
50
5
5
5
0.5
2 a.b
2
2 c
2
2
2
2
0.5
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2
NA
NA
NA
NA
2
2 a
2
2
2
2
2
2
50
5
5
5
0.40
2 a.c
2
2
2 a.c
2
2
2
0.40
0.001
0.001
0.001
0.001
NA
0.001
0.002
0.001
0.001
0.001
0.1
0.015
2
0.002
0.002
0.001
0.002
2
2
2
2
2
2
2
2
10
5
5
5
1
2
2
2
2
2
2
2
1
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2
NA
NA
NA
NA
0.025 a 0.005
2 a.b 0.025 a.b.c 0.005 a
2 a.b 0.025 a 0.005
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
1
0.025
0.025
0.025
0.025
0.025
0.025
0.025
NR
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.025
NA
NA
NA
NA
0.005
0.005
0.005
0.005
0.005
0.005
0.005
0.005
0.005
0.42
0.005
0.005
0.005
0.005
0.005
0.005
0.005
NR
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.005
NA
NA
NA
NA
1.5
1.5
1.5
1.5
1.5
1.5
1.5
1.5
1.5
1.5
1.5
1.5
1
1.5
1.5
1.5
1.5
1.5
1.5
1.5
NR
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.5
NA
NA
NA
NA
0.005
a 0.005
a 0.005
0.005
0.005
0.005
0.005
0.005
0.005
0.005
0.005
0.005
0.351
0.005
0.005
0.005
0.005
0.005
0.005
0.005
0.702
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.005
NA
NA
NA
NA
0.01 i
0.01 a
0.01
0.01
0.01
a 0.01
0.01
0.01
0.01 b
a 0.01
a 0.01
a 0.01
a 0.36
0.01
0.01
a 0.01 a
0.01 a.b
0.01
a 0.01
0.01
0.36
0.0066
0.013
0.0066
0.013
0.013
0.013
0.013
0.0066 a
0.0066
NR
0.13
0.013 a
0.010 a
0.013
0.013
0.013
0.013
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.36
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.36
0.0066
0.013
0.0066
0.013
0.013
0.013
0.013
0.0066
0.0066
NR
0.13
0.013
0.010
0.013
0.013
0.013
0.013
a,b
-------
Table 4-2 (Continued)
SUMMARY OF DETECTION LIMITS FOR WASTE CONSTITUENTS
FROM THE FOURTEEN EPA INCINERATION TESTS *
CO
Waste BOAT
Code No. Constituent Test No.* ->
HALOGENATED PESTICIDE AND CHLOROBENZENE WASTES
U070 87 ortho-Dichlorobenzene
U071 86 meta-Dichlorobenzene
U072 88 para-Dichlorobenzene
U127 110 Hexachlorobenzene
U128 111 Hexachlorobutadiene
U129 173 alpha-BHC
U129 174 beta-BHC
U129 175 delta-BHC
U129 176 gamma -BHC (Lindane)
U130 112 Hexachlorocyclopentadiene
U142 189 Kepone
U183 136 Pentachlorobenzene
U185 138 Pentachloronitrobenzene
U207 148 1,2,4,5-Tetrachlorobenzene
U240 192 2,4-Dichlorophenoxyacetic acid
U247 190 Methoxychlor
HALOGENATED PHENOLIC WASTES
U039 76 p-Chloro-m-cresol
U048 78 2-Chlorophenol
U081 90 2,4-Oichlorophenol
U082 91 2,6-Dichlorophenol
OXYGENATED HYDROCARBON AND HETEROCYCLIC WASTES
U002 222 Acetone
U004 53 Acetophenone
U031 223 n-Butyl alcohol
U108 29 1,4-Dioxane
U112 225 Ethyl acetate
U117 227 Ethyl ether
U118 31 Ethyl methacrylate
U140 33 Isobutyl alcohol
U159 34 Methyl ethyl ketone
U161 229 Methyl isobutyl ketone
U162 35 Methyl methacrylate
WASTES OF A PHARMACEUTICAL NATURE
U141 117 Isosafrole
U155 118 Methapyrilene
U187 140 Phenacetin
U203 147 Safrole
Detection Limit (ppm)
1
2
3
4
5
6
7
8
9
10
11
13
14
(continued)
0.5
0.5
0.5
0.5
0.5
NA
NA
NA
NA
0.5
NA
0.5
5
5
NA
NA
0.5
0.5
0.5
0.5
50
0.5
NA
50
5
50
2
0.2
10
10
2
5
NA
5
5
0.13
0.13
0.29
0.13
0.06
0.0005
0.001
0.001
0.001
0.4
0.006
0.1
0.17
0.1
0.5
0.003
0.2
0.22
0.18
0.46
50
0.19
NA
NA
10
NA
50
NA
50
a 100
50
0.1
0.8
NA
0.17
0.01
0.01
0.01
0.01
0.01
0.0000008
0.0000015
0.0000015
0.000001
0.01
NR
0.01
0.1
0.01
0.0005
0.000005
0.01
0.01
0.01
0.01
0.05 a
0.01
NA
NA
0.002
NA
0.01
NA
0.05
0.01
0.01
0.1
NA
0.1
NA
2 a
2
2 a
10 a
10 a
NA
NA
NA
NA
10
NA
10 a
10
5 a
NA
NA
5
2
5 a
5 a
10
2
NA
NA
NA
NA
2
2
10 a
10
2
NA
NA
2
NA
0.50
0.50
0.50
0.5
0.5
NA
NA
NA
NA
0.5
NA
0.5
5
5
NA
NA
0.5
0.5
0.5
0.5
50
0.5
NA
100
2 c
50
2
NA
10 a,b
10
2
5
NA
5
5
0.4
0.4
0.4
0.4
0.4
0.0005
0.001
0.001
0.001
0.4
0.006
0.4
4
0.4
0.02
0.003
0.4
0.4
0.4
0.4
50
0.4
NA
NA
2
NA
10
NA
50 b
10
10
4
NA
4
4
0.2
0.2
0.2
1
1
NA
NA
NA
NA
1
NA
1
1
0.5
NA
NA
0.5
0.2
0.5
0.5
10
0.2
NA
NA
NA
NA
2
2
10
10
2
NA
NA
0.2
NA
NA
NA
NA
NA
1
NA
NR
10
2
NA
NA
1
1
1
NR
0.05
2
NA
1
NA
NA
0.5
1
0.025 a.c
0.025
0.5
2
NR
2
5
0.42
0.42
0.42
0.42
0.42
NA
NA
NA
NA
0.42
NA
ND
4.2
0.84
NA
NA
0.42
0.42
0.42
ND
0.01 a
0.84
NA
0.2
NA
NA
0.1
0.2
0.01
0.01
0.1
0.84
NA
0.84
2.1
NA
NA
NA
NA
1
NA
ND
1
2
NA
NA
1
1
1
ND
3
2
NA
60
NA
NA
30
60
3
3
30
2
NA
2
5
0.351
0.351
0.351
0.351
0.351
NA
NA
NA
NA
0.351
NA
1.76
3.51
0.702
NA
NA
0.351
0.351
0.351
0.702
0.01
1.76
NA
0.2
NA
NA
0.1
0.2
0.01
0.01
0.1
0.702
NA
0.702
1.76
a 0.36
0.36
a 0.36
a 0.36
0.36
0.0066
0.0066
0.0066
0.0066
0.36
NR
0.36
0.36
0.36
0.2
0.013
0.36
0.36
0.36
0.36
a 0.02
0.36
0.4
0.4
0.04
0.01
0.01
1
a 0.02
0.02
0.01
0.36
0.36
0.36
0.36
0.36
0.36
0.36
a 0.36
a 0.36
0.0066
0.0066
0.0066
0.0066
a 0.36
NR
a 0.36
a 0.36
0.36
a.b.c 0.2 a.b
a 0.013
0.36
0.36
a 0.36
0.36
a.b 0.02
0.36
0.4
0.4
0.04
0.01
0.01
1
0.02
0.02 a
0.01
0.36 a
0.36
0.36
0.36
-------
Table 4-2 (Continued)
SUMMARY OF DETECTION LIMITS FOR WASTE CONSTITUEMTS
FROM THE FOURTEEN EPA INCINERATION TESTS *
Waste BOAT
Code No. Constituent Test No.*
PHENOLIC WASTES
P020 73 2-sec-Butyl-4,6-dinitrophenol
P047 100 4,6-Dinitro-o-cresol and salts
P048 101 2,4-Dinitrophenol
U052 81 o-Cresol
U052 82 Cresol (m- and p- isomers)
U101 96 2.4-Dimethyl phenol
U170 127 4-Nitrophenol
U188 142 Phenol
POLYNUCLEAR AROMATIC WASTES
U005 54 2-Acetylanrinof luorene
U018 59 Benz(a)anthracene
U022 62 Benzo(a)pyrene
U050 80 Chrysene
U063 83 Dibenz(a,h)anthracene
U120 108 Fluoranthene
*~ U137 116 lndeno(1,2>3-c.d)pyrene
' U157 119 3-Hethylcholanthrene
U165 121 Naphthalene
U051 121 Creosote-Naphthalene
U051 139 Creosote-Pentachlorophenol
U051 141 Creosote-Phenanthrene
U051 145 Creosote-Pyrene
U051 43 Creosote-Toluene
U051 215-217 Creosote- Xy I enes
ORGANO- NITROGEN COMPOUND WASTES
P077 125 p-Nitroaniline
P101 30 Ethyl cyanide (Propanenitri le)
U009 3 Acrylonitrile
U012 56 Aniline
U105 102 2,4-Dinitrotoluene
U106 103 2,6-Dinitrotoluene
U111 105 D,i-n-propylnitrosamine
U152 37 Methacrylonitrile
U169 126 Nitrobenzene
U172 128 N-Nitrosodi-n-butylamine
U174 129 N-Nitrosodtethylamine
U179 133 N-Nitrosopiperidine
U180 134 N-Nitrosopyrrolidine
U181 135 5-Nitro-o-toluidine
U196 39 Pyridine
Detection Limit (ppm)
-> 1
NA
2.5
2.5
0.5
0.5
0.5
2.5
0.5
50
0.5 a.
0.5 a
0.5 a
0.5
0.5 a
0.5
5
0.5 a
0.5 a
2.5 a
0.5 a
0.5 a
2 a
2 a
2.5
0.1
10
1
0.5
0.5
NR
0.2
0.5
5
5
10
10
10
5 c
2
NA
1.6
2.8
0.67
0.67
0.18
0.16
0.1 a
0.43
0.52 a
0.17 a
0.17 a
0.17
0.15 a
0.25
0.23
0.11 a
0.11 a
0.24
0.36 a
0.13 a
10 a
10 a
3.4
NA
10
0.67
0.38
0.13
NA
NA
0.13
0.21
0.18
0.19
0.28
0.17
NA
3
NA
0.05
0.05
0.01
0.01
0.01
0.05
0.01
1000
10
10
10
10
10
10
100
10
10
50
10
10
2 a
2 a
0.05
NA
0.1 a
0.02
0.01
0.01
0.01
NA
0.01
0.1
0.1
0.2
0.2
0.2
NA
4
NA
50
50
2 a
2
5
10
2 a
NA
2.0
2.0
2.0
2.0
2.0
5.0
NA
2.0 a
2.0 a
50
2.0 a
2.0
2 c
2
10
100
10
5 a
50
10
5
10
5 a
5
10
10
10
NA
NA
5
NA
2.5
2.5
0.5 •
0.5
0.5
2.5
0.5
50
0.50
0.50
0.50
0.50
0.50
0.50
5.0
0.5
0.5
2.5
0.5
0.5
2 a.b.c
2 c
2.5
NR
10
1
0.5
0.5
NA
10
0.5
5
5
10
10
10
NA
6
NA
2
2
0.4
0.4
0.4
2
0.4
40
0.40
0.40
0.40
0.40
0.40
0.40
4.0
0.4
0.4
2.0
0.4
0.4
2 a
2
2
NA
10
0.7
0.4
0.4
NA
NA
0.4
4
4
7
7
7
NA
7
NA
5
5
0.2
0.2
0.5
1
0.2
NA
0.20
0.20
0.20
0.20
0.20
0.50
NA
0.20
0.20
5.0
0.20
0.20
2
2
1
100
10
0.5
5
1
0.5
10
0.5
0.5
1
1
1
NA
2
8
5
5
5
1
1 a
1
5
1 a
2.0
a 1.0 a
1.0 a
a 1.0 a
1.0
1.0 a
1.0 a
2.0
a 1.0 a
a 1.0 a
5.0
a 1.0 a
a 1.0 a
a,b 0.025 a,b,c
a,b 0.025 a
5
0.5
0.5
1
1
1
NA
0.5
1
NR
NR
1
5
2
2
9
2.1
2
2
0.42
0.42
0.42
2
0.42
0.84
0.42
0.42
0.42
0.42
0.42
0.42
0.84
0.42
0.42
2.0
0.42
0.42
0.005 a
0.005
2
0.1
0.1
0.42
0.42
0.42
0.42
0.1
0.42
NR
NR
0.42
2.1
0.84
0.4
10
5
5
5
1
1
1
5
1 afc
2.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.5 a
.5 a
5
30
30
1
1
1
1
30
1
NR
NR
1
5
2
120
11
1.76
1.76
1.76
0.351
0.351
0.351
1.76
0.351 a
0.702
0.351 a
0.351 a
0.351 a
0.351
0.351
0.351 a
0.702
0.351
0.351
1.76
0.351 a
0.351
0.005
0.005
1.76
0.1
0.1
0.351
0.351
0.351
0.351
0.1
0.351
0.702
0.351
0.351
1.76
0.702
0.4
13
0.36
1.7
1.7
0.36
0.36
0.36
1.7
0.36
0.36
0.36
0.36
0.36
0.36
0.36
0.36
0.36
0.36
0.36
1.7
0.36
0.36
0.01 a
0.01
1.7
0.01
0.1
0.36
0.36
0.36
0.36
0.01
0.36
0.36
0.36
0.36
0.36
0.36
0.5
14
0.36 a
1.7
1.7
0.36
0.36
0.36
1.7
0.36 a
0.36
0.36
0.36
0.36
0.36
0.36
0.36
0.36
0.36
0.36
1.7
0.36
0.36
0.01 a
0.01
1.7
0.01
0.1
0.36
0.36
0.36
0.36
0.01
0.36
0.36
0.36
0.36
0.36
0.36
0.5
-------
Table 4-2 (Continued)
SUMMARY OF DETECTION LIMITS FOR WASTE CONSTITUENTS
FROM THE FOURTEEN EPA INCINERATION TESTS *
Detection Limit (ppm)
wasie
Code
No.
Constituent Test No.* ->
1
2
3
4
5
6
7
8
9
10
11
13
14
MISCELLANEOUS HALOGENATED ORGANIC WASTES
P024
U024
U025
U027
U043
U045
U047
U075
U121
U138
U1 58
1)192
74
67
68
69
50
15
77
21
48
32
120
144
p-Chloroaniline
Bis(2-chloroethoxy)methane
Bis(2-chloroethyl )ether
Bis(2-chloroisopropyl)ether
Vinyl chloride
Chlorome thane (Methyl chloride)
2-Chloronaphthalene
D i ch loromonof 1 uoromethane
Trichlorofluorome thane
lodomethane
4,4'-Methylenebis(2-chloroaniline)
Pronamide
5
0.5
0.5
0.5
2
2
0.5
2
2
2
10
5
0.67
0.36
0.38
0.38
10
10
0.13
10
10
20
NA
0.12
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.002
0.002
0.002
0.2
0.1
5
2
2
2
2
2
2
2
2
2
NA
10
5
0.5
a 0.5
0.5
2
2 a
0.5
2 b.c
2
2
10
5
0.4
0.4
0.4
0.4
10
10
0.4
2
2
2
7
4
0.5
0.2
0.2
0.2
2
2
0.2
2
2
2
NA
1
1
NA
1
1
0.05
0.05
1
a 0.050
0.025
0.25
2
NR
0.42
0.42
0.42
0.42
0.01
0.01
0.42
0.010
0.005
0.05
0.84
1
1
1
1
3
3
1
3
1.5
15
2
0.351
0.351
0.351
0.351
0.01
0.01
0.351
0.01 b.c
0.005
0.05
0.702
ND ND 0.702
0.36
0.36
0.36
0.36
0.02
0.02
0.36
0.02
0.01
0.01
0.36
0.36
0.36
0.36
0.36
0.36
0.02
0.02
0.36
0.02
0.01
0.01
0.36
a,b 0.36
* Incinerator ash samples were not collected for Test 12.
** Treatment test number is indicated in Table 4-1.
NA = Not Available
NR = Not Reported
a = Detected in untreated waste.
b = Detected in incinerator ash.
c = Detected in scrubber water.
-------
Table 4-3
TREATMENT PERFORMANCE DATA COLLECTED BY EPA FOR ETHYLENE DIBROMIDE (EDB)
AT ROLLINS ENVIRONMENTAL SERVICES, INC. (TEXAS) - INCINERATION
Untreated Waste
Incineration Ash
BOAT List
Constituent
1 , 2-Dibromoethane
(Ethylene dibromide)
Sample
Set No.
1
2
3
Detection
Limit
(mg/kg)
25,000
25 i 000
25; 000
Concentration
of EDB
(mg/kg)
119,000
92,000
102,000
I
Detection
Limit
(mg/kg)
5
5
5
2DB in Solids
Discharge
Stream
(mg/kg)
< 5
< 5
< 5
Source: EDB Test Burn Program Emissions Test Results (Reference 18).
4-11
-------
Table 4-4
DESIGN PARAMETERS FOR THE INCINERATOR SYSTEM AT ROLLINS
ENVIRONMENTAL SERVICES, INC. (TEXAS)
Physical Design Parameter
ROTARY KILN:
Manufacturer
Height
Inside diameter
Length
Volume
Width
Materials of construction:
Outer shell
Front wall
LODDBY FURNACE:
Manufacturer
Height
Inside diameter
Length
Volume
Width
AFTERBURNER:
Manufacturer
Height
Inside diameter
Length
Volume
Width
Materials of construction:
Outer shell
Ceiling
NR - Not Reported.
Value or Description
NR
9.5 feet
32.8 feet
2,324 cubic feet
NR
1.18-inch steel plate with 9-inch
refractory lining.
0.59-inch steel plate with castable
refractory and refractory brick lining.
NR
6.25 feet
14 feet
429 cubic feet
NR
13.5 feet
NR
49 feet
8,300 cubic feet
12.5 feet
13-inch refractory bricks supported by
stainless steel clips attached to steel
beams.
6-inch bricks
* - This equipment was especially designed for RES(TX), Inc., and therefore
does not carry a model number.
Source: Reference 18.
4-12
-------
5.0 SELECTION OF REGULATED CONSTITUENTS
This section presents EPA's methodology and rationale for selection
of regulated constituents for the U and P and multi-source leachate (F039)
wastes included in this document.
5.1 U and P Wastes
Due to the lack of characterization data for the U and P wastes,
only the constituents for which the wastes were listed were considered for
regulation. Exceptions include the following waste codes: U051, U052, U060,
U061, U084, U129, P050, P051, and P059. These exceptions are discussed in
greater detail in the following subsections.
The waste constituents selected for regulation in each of the eleven
U and P waste treatability groups discussed in this document are summarized in
Table 5-1. (All tables are presented at the end of this section.)
5.1.1 U051 - Creosote
U051, from the polynuclear aromatic wastes treatability group, is
listed as creosote. Creosote is a derivative of coal that contains a wide
range of constituents, including cresols, phenols, naphthalene,
benz(a)anthracene, benzo(a)pyrene, fluoranthene, chrysene, indeno(l,2,3-
c,d)pyrene, acenaphthalene, and lead. Creosote has been previously regulated
in K001. The Agency is selecting the same organic and metal constituents for
regulation in nonwastewater forms of U051 as were regulated in nonwastewater
forms of K001 in the First Third: naphthalene, pentachlorophenol,
phenanthrene, pyrene, toluene, xylenes, and lead.
5.1.2 U052 - Cresols
U052, from the phenolic wastes treatability group, is listed as
"cresols (cresylic acid)." Cresylic acid is the name given to a mixture of
three isomeric cresols (methyl phenols), in which the meta-cresol
5-1
-------
predominates. Thus, U052 typically contains various levels of ortho-cresol,
meta-cresol, and para-cresol. Current analytical methods cannot distinguish
between the meta and para isomers of cresol. Therefore, the Agency is
selecting ortho-cresol and a combination of meta- and para-cresol for
regulation in U052.
5.1.3 UP60 and UP61 - ODD and DDT
U060 and U061 are in the halogenated pesticide and chlorobenzene
wastes treatability group. ODD and DDT, the compounds for which U060 and U061
were respectively listed, can both exist as one of two isomers: o,p'-DDD or
p,p'-DDD; and o,p'-DDT or p,p'-DDT. Each of these isomers can be analyzed by
SW-846 Method 8080 for organochlorine pesticides. Therefore, the Agency is
selecting both isomers for regulation in U060 and U061. In addition, ODD and
DDE are common breakdown products of DDT. Accordingly, the Agency is also
selecting the p,p' and o,p' isomers of both ODD and DDE for regulation in U061
wastes.
5.1.4 U084 - 1.3-Dichloropropene
U084, from the halogenated aliphatic wastes treatability group, is
listed as 1,3-dichloropropylene. Because of the position of the chlorines in
the structure, this alkene can exist as a mixture of two stereoisomers, cis-
1,3-dichloropropylene and trans-1,3-dichloropropylene. Both of these isomers
can be analyzed using SW-846 methods. Therefore, the Agency is selecting both
isomers for regulation in U084.
5.1.5 U129 - gamma-BHC (Lindane)
Lindane (represented by U129 in the halogenated pesticide and
chlorobenzene wastes treatability group) is the gamma-isomer of a class of
compounds known as hexachlorocyclohexanes and is often referred to as "gamma-
BHC." (BHC is an abbreviation for benzene hexachloride, which is a misnomer
since benzene is not part of the chemical structure.) Lindane is the most
common isomer of hexachlorocyclohexane (BHC). Typical commercial mixtures of
5-2
-------
Lindane include Che three other BHC isomers, alpha-, beta-, and delta-BHC, at
high concentrations. Therefore, the Agency is selecting all four BHC isomers
for regulation in U129.
5.1.6 P050 - Endosulfan
P050 is in the halogenated pesticide and chlorobenzene wastes
treatability group. Endosulfan, the compound for which P050 was listed as a
hazardous waste, commonly exists as a mixture of two isomers: endosulfan I
and endosulfan II. Both can be analyzed by SW-846 Method 8080 for
organochlorine pesticides. Accordingly, both isomers were selected for
regulation in P050. In addition, endosulfan can be converted to endosulfan
sulfate in environmental samples. Therefore, the Agency is also selecting
endosulfan sulfate for regulation in P050.
5.1.7 P051 - Endrin and Metabolites
P051 is in the halogenated pesticide and chlorobenzene wastes
treatability group. The most common metabolite of endrin is endrin aldehyde.
The Agency is selecting both endrin and endrin aldehyde for regulation in
P051.
5.1.8 P059 - Heptachlor
P059 is in the halogenated pesticide and chlorobenzene wastes
treatability group. Heptachlor can be commonly converted to heptachlor
epoxide in environmental samples. Therefore, the Agency is selecting both
heptachlor and heptachlor epoxide for regulation in P059.
5.2 Multi-Source Leachate (F039)
As discussed in Section 1.0, multi-source leachate (F039) is liquid
which percolates through or from listed hazardous waste, including the F, D,
K, U, and P wastes. Therefore, the Agency initially considered for regulation
all of the constituents that are present in listed hazardous wastes. These
5-3
-------
constituents include the BDAT List constituents and other hazardous
constituents which are not on the BDAT List due to the fact they are
unanalyzable or poorly quantified in hazardous waste matrices. .Since it is
not possible for the Agency to establish concentration-based treatment
standards for these nonquantifiable constituents, the Agency generally
specifies a method of treatment as the treatment standard for these wastes.
By regulating all waste constituents for which concentration-based treatment
standards are appropriate, the Agency believes that these constituents will
control those constituents for which numerical standards are not appropriate,
obviating the need to specify methods of treatment. Specifically, regulated
constituents within each treatability group will control other non-regulated
constituents within that treatability group. The Agency believes that this is
technically valid since structurally similar compounds are likely to be
treated by the same treatment technology and to achieve similar treatment
performance.
5.2.1 Constituents Selected for Regulation
The Agency selected for regulation in multi-source leachate those U
and P waste constituents for which numerical treatment standards were
developed. The Agency also selected for regulation those BDAT List
constituents which do not have a corresponding U or P waste designation.
Exceptions to this general methodology are discussed below. Regulated
constituents in multi-source leachate (F039) are listed in Table 5-2.
Metallic U and P Wastes (Arsenic. Selenium. Chromium. Lead, and
Mercury)
As discussed in the respective background documents for arsenic,
selenium, chromium, lead, and mercury wastes, these waste constituents include
metallic compounds such as metallic salts, organometallics, and bimetallic
compounds that are not uniquely analyzable. For example, given a mixture of
chromium nitrate and chromium sulfate, analytical methods will measure
chromium but cannot determine whether it is in the sulfate or nitrate form.
Therefore, regulated constituents include the metallic constituent only and
5-4
-------
not metallic salt, organo metallic, or bimetallic compounds. The Agency
believes that the metal serves as a surrogate regulated constituent for these
metallic compounds.
All other BDAT List metal constituents are being regulated in multi-
source leachate (F039) except beryllium, hexavalent chromium, copper,
thallium, vanadium, and zinc as discussed in Section 5.2.2.
Cyanide P Wastes
As discussed in the Best Demonstrated Available Technology (BDAT)
Background Document for Cyanide Wastes (Reference 28), these wastes include
metallic cyanides, cyanide salts, and hydrogen cyanide that are not uniquely
analyzable. For example, analytical methods will measure total cyanide, but
will not measure barium cyanide. Therefore, regulated constituents include
total cyanide only and not the metallic cyanide, cyanide salts, or hydrogen
cyanide compounds. The Agency believes that total cyanide serves as a
surrogate regulated constituent for these cyanide compounds.
5.2.2 Constituents Not Selected for Regulation
Waste constituents that were not selected for regulation in multi-
source leachate (F039) include:
• Non-analyzable Organic U and P Wastes;
• Incinerable Reactive Organics and Hydrazine Derivatives;
• Incinerable Inorganics;
• Fluorines;
• Recoverable Metallies (including beryllium dust, nickel
carbonyl, and osmium tetroxide);
• Thallium and Vanadium U and P Wastes;
• Other BDAT List Metals (including beryllium, hexavalent
chromium, copper, and zinc);
5-5
-------
• Cyanide Compounds;
• Gases; and
• Organophosphorus Pesticide Wastes.
These waste constituents and their corresponding "controlling" constituents
are listed in Table 5-3. As discussed previously, the Agency believes that
these waste constituents will be controlled by regulation of other waste
constituents. In most instances, controlling constituents include other
constituents within the same treatability group/subgroup that are regulated in
nonwastewater forms of multi-source leachate (F039). In some cases, none of
the constituents in a treatability group/subgroup were regulated in leachate,
therefore; "controlling" constituents were transferred from another similar
treatability group/subgroup, as indicated in Table 5-3.
Details concerning reasons why numerical treatment standards are not
appropriate for the multi-source leachate constituents that are not being
regulated are included in Volume B, D, and E of this five volume background
document set and in the preamble for the Final Third Third rule.
5-6
-------
TABLE 5-1
BDAT LIST CONSTITUENTS SELECTED FOR REGULATION
IN NONWASTEWATER FORMS OF ORGANIC U AND P WASTES
AROMATIC WASTES
U019 Benzene
U220 Toluene
U239 Xylenes
BROMINATED ORGANIC WASTES
U029 Bromomethane (Methyl bromide)
U030 4-Bromophenyl phenyl ether
U066 1,2-Dibromo-3-chloropropane
U067 1,2-Dibromoethane (Ethylene dibromide)
U068 Dibromomethane
U225 Tribromomethane (Bromoform)
HALOGENATED ALIPHATIC WASTES
U044 Chloroform
U076 1,1-Dichloroethane
U077 1,2-Dichloroethane
U078 1,1-Dichloroethylene
U079 trans-l,2-Dichloroethylene
U080 Methylene chloride
U083 1,2-Dichloropropane
U084 cis-l,3-Dichloropropylene
U084 trans-l,3-Dichloropropylene
U131 Hexachloroethane
U208 1,1,1,2-Tetrachloroethane
U209 1,1,2,2-Tetrachloroethane
U210 Tetrachloroethylene
U211 Carbon tetrachloride
U226 1,1,1-Trichloroethane
U227 1,1,2-Trichloroethane
U228 Trichlorethylene
U243 Hexachloropropylene
HALOGENATED PESTICIDE AND CHLOROBENZENE WASTES
P004 Aldrin
P037 Dieldrin
P050 Endosulfan I
P050 Endosulfan II
P050 Endosulfan sulfate
P051 Endrin
P051 Endrin aldehyde
P059 Heptachlor
P059 Heptachlor epoxide
P060 Isodrin
PI23 Toxaphene
5-7
-------
TABLE 5-1 (Continued)
BOAT LIST CONSTITUENTS SELECTED FOR REGULATION
IN NONWASTEWATER FORMS OF ORGANIC U AND P WASTES
HALOGENATED PESTICIDE AND CHLOROBENZENE WASTES (Continued)
U036 Chlordane (alpha and gamma isomers)
U037 Chlorobenzene
U060 o,p'-DDD
U060 p,p'-DDD
U061 o,p'-DDD
U061 p,p'-DDD
U061 o,p'-DDE
U061 p,p'-DDE
U061 o,p'-DDT
U061 p,p'-DDT
U070 o-Dichlorobenzene
U071 m-Dichlorobenzene
U072 p-Dichlorobenzene
U127 Hexachlorobenzene
U128 Hexachlorobutadiene
U129 alpha-BHC
U129 beta-BHC
U129 delta-BHC
U129 gamma-BHC (Lindane)
U130 Hexachlorocyclopentadiene
U142 Kepone
U183 Pentachlorobenzene
U185 Pentachloronitrobenzene
U207 1,2,4,5-Tetrachlorobenzene
U240 2,4-Dichlorophenoxyacetic acid
U247 Methoxychlor
HALOGENATED PHENOLIC WASTES
U039 p-Chloro-m-cresol
U048 2-Chlorophenol
U081 2,4-Dichlorophenol
U082 2,6-Dichlorophenol
OXYGENATED HYDROCARBON AND HETEROCYCLIC WASTES
U002 Acetone
U004 Acetophenone
U031 n-Butyl alcohol
U108 1,4-Dioxane
U112 Ethyl acetate
U117 Ethyl ether
U118 Ethyl methacrylate
U140 Isobutyl alcohol
U159 Methyl ethyl ketone
U161 Methyl isobutyl ketone
U162 Methyl methacrylate
5-8
-------
TABLE 5-1 (Continued)
BOAT LIST CONSTITUENTS SELECTED FOR REGULATION
IN NONWASTEWATER FORMS OF ORGANIC U AND P WASTES
WASTES OF A PHARMACEUTICAL NATURE
U141 Isosafrole
U155 Methapyrilene
U187 Phenacetin
U203 Safrole
PHENOLIC WASTES
P020 2-sec-Butyl-4,6-dinitrophenol (Dinoseb)
P047 4,6-Dinitro-o-cresol
P048 2,4-Dinitrophenol
U052 Cresol (m- and p- isomers)
U052 o-Cresol
U101 2,4-Dimethylphenol
U170 4-Nitrophenol
U188 Phenol
POLYNUCLEAR AROMATIC WASTES
U005 2-Acetylaminofluorene
U018 Benz(a)anthracene
U022 Benzo(a)pyrene
U050 Chrysene
U063 Dibenz(a,h)anthracene
U120 Fluoranthene
U137 Indenq(l,2,3-c,d)pyrene
U157 3-Methylcholanthrene
U165 Naphthalene
U051 . Creosote - Lead
Creosote - Naphthalene
Creosote - Pentachlorophenol
Creosote - Phenanthrene
Creosote - Pyrene
Creosote - Toluene
Creosote - Xylenes (total)
ORGANO-NITROGEN COMPOUND WASTES
P077 p-Nitroaniline
P101 Ethyl cyanide (Propanenitrile)
U009 Acrylonitrile
U012 Aniline
U105 2,4-Dinitrotoluene
U106 2,6-Dinitrotoluene
Ulll Di-n-propylnitrosamine
U152 Methacrylonitrile
U169 Nitrobenzene
5-9
-------
TABLE 5-1 (Continued)
BOAT LIST CONSTITUENTS SELECTED FOR REGULATION
IN NONWASTEWATER FORMS OF ORGANIC U AND P WASTES
ORGANO-NITROGEN COMPOUND WASTES (Continued)
U172 N-Nitrosodi-n-butylamine
U174 N-Nitrosodiethylamine
U179 N-Nitrosopiperidine
U180 N-Nitrosopyrrolidine
U181 5-Nitro-o-toluidine
U196 Pyridine
MISCELLANEOUS HALOGENATED ORGANIC WASTES
P024 p-Chloroaniline
U024 Bis(2-chloroethoxy)methane
U025 Bis(2-chloroethyl)ether
U027 Bis(2-chloroisopropyl)ether
U043 Vinyl chloride
U045 Chloromethane (Methyl chloride)
U047 2-Chloronaphthalene
U075 Dichlorodifluoromethane
U121 Trichloromonofluoromethane
U138 lodomethane
U158 4,4'-Methylenebis(2 -chloroaniline)
U192 Pronamide
5-10
-------
Table 5-2
REGULATED MULTI-SOURCE LEACHATE (F039) CONSTITUENTS
BOAT
List No. Regulated Organic Constituent
51. Acenaphthalene
52. Acenaphthene
222. Acetone
53. Acetophenone
54. 2-Acetylaminofluorene
3. Acrylonitrile
172. Aldrin
56. Aniline
57. Anthracene
200. Aroclor 1016
201. Aroclor 1221
202. Aroclor 1232
203. Aroclor 1242
204. Aroclor 1248
205. Aroclor 1254
206. Aroclor 1260
173. alpha-BHC
174. beta-BHC
175. delta-BHC
176. gamma-BHC (Lindane)
59. Benz(a)anthracene
4. Benzene
62. Benzo(a)pyrene
63. Benzo(b)fluoranthene
64. Benzo(g,h,i)perylene
65. Benzo(k)fluoranthene
67. Bis(2-chloroethoxy)methane
68. Bis(2-chloroethyl)ether
69. Bis(2-chloroisopropyl)ether
70. Bis(2-ethylhexyl)phthalate
5. Bromodichloromethane
6. Bromomethane (Methyl bromide)
71. 4-Bromophenyl phenyl ether
223. n-Butyl alcohol
72. Butyl benzyl phthalate
73. 2-sec-Butyl-4,6-dinitrophenol (Dinoseb)
7. Carbon tetrachloride
177. Chlbrdane (alpha and gamma)
74. p-Chloroaniline
9. Chlorobenzene
11. Chlorodibromomethane
12. Chlbroethane
14. Chloroform
76. p-Chloro-m-cresol
15. Chloromethane (Methyl chloride)
77. 2 -Chloronaphthalene
78. 2-Chlorophenol
16. 3-Chloropropylene
80. Chrysene
82. Cresol (m- and p- isomers)
81. o-Cresol
5-11
-------
Table 5-2 (Continued)
REGULATED MULTI-SOURCE LEACHATE (F039) CONSTITUENTS
BDAT
List No. Regulated Organic Constituent
235. o,p'-DDD
178. p,p'-DDD
236. o,p'-DDE
179. p,p'-DDE
237. o,p'-DDT
180. p.p'-DDT
83. Dibenz(a,h)anthracene
17. 1,2-Dibromo-3-chloropropane
18. 1,2-Dibromoethane (Ethylene dibromide)
19. Dibromomethane
86. m-Dichlorobenzene
87. o-Dichlorobenzene
88. p-Dichlorobenzene
21. Dichlorodifluoromethane
22. 1,1-Dichloroethane
23. 1,2-Dichloroethane
24. 1,1-Dichloroethylene
25. trans-l,2-Dichloroethylene
90. 2,4-Dichlorophenol
91. 2,6-Dichlorophenol
192. 2,4-Dichlorophenoxyacetic acid (2,4-D)
26. 1,2-Dichloropropane
27. cis-l,3-Dichloropropylene
28. trans-l,3-Dichloropropylene
181. Dieldrin
92. Diethyl phthalate
96. 2.4-Dimethylphenol
97. Dimethyl phthalate
98. Di-n-butyl phthalate
99. 1,4-Dinitrobenzene
100. 4,6-Dinitro-o-cresol
101. 2,4-Dinitrophenol
102. 2,4-Dinitrotoluene
103. 2,6-Dinitrotoluene
104. Di-n-octyl phthalate
105. Di-n-propylnitrosamine
29. 1,4-Dioxane
195. Disulfoton
182. Endosulfan I
183. Endosulfan II
238. Endosulfan sulfate
184. Endrin
185. Endrin aldehyde
225. Ethyl acetate
226. Ethyl benzene
30. Ethyl cyanide (Propanenitrile)
227. Ethyl ether
31. Ethyl methacrylate
196. Famphur
108. Fluoranthene
5-12
-------
Table 5-2 (Continued)
REGULATED MULTI-SOURCE LEACHATE (F039) CONSTITUENTS
BDAT
List No. Regulated Organic Constituent
109. Fluorene
186. Heptachlor
187. Heptachlor epoxide
110. Hexachlorobenzene
111. Hexachlorobutadiene
112. Hexachlorocyclopentadiene
208. Hexachlorodibenzofurans
207. Hexachlorodibenzo-p-dioxins
113. Hexachloroethane
114. Hexachloropropylene
116. Indeno(l,2,3-c,d)pyrene
32. lodomethane
33. Isobutyl alcohol
188. Isodrin
117. Isosafrole
189. Kepo'ne
37. Methacrylonitrile
118. Me thapyr i1ene
190. Methoxychlor
34. Methyl ethyl ketone
229. Methyl isobutyl ketone
35. Methyl methacrylate
197. Methyl parathion
119. 3-Methylcholanthrene
120. 4,4'-Methylenebis(2 -chloroaniline)
38. Methylene chloride
121. Naphthalene
125. p-Nitroaniline
126. Nitrobenzene
135. 5-Nitro-o-toluidine
127. 4-Nitrophenol
129. N-Nitrosodiethylamine
128. N-Nitrosodi-n-butylamine
131. N-Nitrosomethylethylamine
132. N-Nitrosomorpholine
133. N-Nitrosopiperidine
134. N-Nitrosopyrrolidine
198. Parathion
136. Pentachlorobenzene
210. Pentachlorodibenzofurans
209. Pentachlorodibenzo-p-dioxins
138. Pentachloronitrobenzene
139. Pentachlorophenol
140. Phenacetin
141. Phenanthrene
142. Phenol
199. Phorate
144. Pronamide
145. Pyrene
39. Pyridine
5-13
-------
Table 5-2 (Continued)
REGULATED MULTI-SOURCE LEACHATE (F039) CONSTITUENTS
BOAT
List No. Regulated Organic Constituent
147. Safrole
193. Silvex (2,4,5-TP)
148. 1,2,4,5-Tetrachlorobenzene
212. Tetrachlorodibenzofurans
211. Tetrachlorodibenzo-p-dioxins
40. 1,1,1,2-Tetrachloroethane
41. 1,1,2,2-Tetrachloroethane
42. Tetrachloroethylene
149. 2,3,4,6-Tetrachlorophenol
43. Toluene
191. Toxaphene
44. Tribromomethane (Bromoform)
150. 1,2,4-Trichlorobenzene
45. 1,1,1-Trichloroethane
46. 1,1,2-Trichloroethane
47. Trichloroethylene
48. Trichloromonofluoromethane
151. 2,4,5-Trichlorophenol
152. 2,4,6-Trichlorophenol
194. 2,4,5-Trichlorophenoxyacetic acid (2,4,5-T)
49. 1,2,3-Trichloropropane
231. 1,1,2-Trichloro-1,2,2-trifluoroethane
50. Vinyl chloride
215.-217. Xylenes (total)
BDAT
List No.
Regulated Inorganic Constituent
169,
Cyanides (total)
BDAT
List No. Regulated Metal Constituent
154. Antimony
155. Arsenic
156. Barium
158. Cadmium
159. Chromium (total)
161. Lead
162. Mercury
163. Nickel
164. Selenium
165. Silver
5-14
-------
Table 5-3
NONWASTEWATER CONSTITUENTS NOT REGULATED IN MULTI-SOURCE LEACHATE (F039)
AND REGULATED CONSTITUENTS THAT CONTROL THEIR TREATMENT
Constituents Not Regulated
"Controlling" Constituent(s)
Waste
Code
P046
P064
U007
U092
U110
1-167
U168
U194
U238
U223
U014
U021
U091
U093
U095
U236
U055
U056
U186
P017
Constituent
Waste
Code
Constituent
AMIDES AND AMINES:
alpha,alpha-DimethyIphen-
ethylamine
Isocyanic acid, methyl ester
Acrylamide
Dimethylamine
Dipropylamine
1-Naphthylamine
2-Naphthylamine (a)
n-Propylamine
Ethyl carbamate
Toluenediamine
U012 Aniline
AMINATED DIPHENYLS/BIPHENYLS:
Auramine
Benzidine
3,3'-Dimethoxybenzidine
p-Dimethylaminoazobenzene (a,*)
3,3'-Dimethylbenzidine
Trypan blue
A -Aminobiphenyl
Diphenylamine/
diphenylnitrosamine
Transfer from amides and amines
AROMATIC AND OTHER HYDROCARBON WASTES:
Cumene
Cyclohexane
1,3-Pentadiene
Bromoacetone
U019
U220
U239
Benzene
Toluene
Xylenes
BROMINATED ORGANIC WASTES:
U029 Bromomethane
U030 4-Bromophenyl phenyl ether
U066 l,2-Dibromo-3-chloropropane
U067 1,2-Dibromoethane (Ethylene dibromide)
U068 Dibromomethane
U225 Bromoform
5-15
-------
Table 5-3 (Continued)
NONWASTEWATER CONSTITUENTS NOT REGULATED IN MULTI-SOURCE LEACHATE (F039)
AND REGULATED CONSTITUENTS THAT CONTROL THEIR TREATMENT
Constituents Not Regulated
"Controlling" Constituent(s)
Waste
Code
Constituent
Waste
Code
Constituent
CHLORINATED ALIPHATIC WASTES:
U074
U074
U184
cis-1,4-Dichloro-2-butene
trans-1,4-Dichloro-2-butene
Pentachloroethane
2-Chloro-l,3-butadiene
U044 Chloroform
U076 1,1-Dichloroethane
U077 1,2-Dichloroethane
U078 1,1-Dichloroethylene
U079 1,2-Dichloroethylene (trans isomer)
U080 Methylene chloride
U083 1,2-Dichloropropane
U084 1,3-Dichloropropylene (cis & trans)
U131 Hexachloroethane
U208 1,1,1,2-Tetrachloroethane
U209 1,1,2,2-Tetrachloroethane
U210 Tetrachloroethylene
U211 Carbon tetrachloride
U226 1,1,1-Trichloroethane
U227 1,1,2-Trichloroethane
U228 Trichloroethylene
U243 Hexachloropropylene
CHLORINATED AMIDES AND AMINES:
P057
U049
U097
U222
U073
U038
U132
P024 p-Chloroaniline
U192 Pronamide
Fluoroacetamide
4 -Chloro-o-toluidine
hydrochloride
Dimethylcarbamoyl chloride
o-Toluidine hydrochloride
CHLORINATED DIPHENYLS:
3,3'-Dichlorobenzidine U158 4,4-Methylenebis(2-chloroaniline)
CHLORINATED DIPHENYLS (PESTICIDES):
Chlorobenzilate (a)
Hexachlorophene
U060 ODD (o,p'- and p,p'- isomers)
U061 ODD (o,p'- and p,p'- isoraers)
U061 DDE (o,p'- and p,p'- isomers)
U061 DDT (o,p'- and p,p'- isomers)
U247 Methoxychlor
5-16
-------
Table 5-3 (Continued)
NONWASTEWATER CONSTITUENTS NOT REGULATED IN MULTI-SOURCE LEACHATE (F039)
AND REGULATED CONSTITUENTS THAT CONTROL THEIR TREATMENT
Constituents Not Regulated
"Controlling" Constituent(s)
Constituent
Waste
Code
P028
U017
Constituent
Waste
Code
CHLORINATED METHYLBENZENES:
Benzyl chloride
Benzal chloride (a)
Transfer from chlorinated polynuclear
aromatics
U026
P026
P118
U020
U062
U240
P031
P033
U246
U223
U134
P056
U115
P076
P078
CHLORINATED POLYNUCLEAR AROMATICS:
Chlornaphazine U047 2-Chloronaphthalene
CHLORINATED ORGANOSULFURS:
1-(o-Chlorophenyl)thiourea
Trichloromethanethiol
Benzene sulfonyl chloride
Diallate
Transfer from halogenated aliphatic
wastes and aromatic wastes
2,4-D salts
Cyanogen
Cyanogen chloride
Cyanogen bromide
Toluene diisocyanate
Cyanide (amenable)
Sulfide
Hydrofluoric acid
Fluorine
Fluoride
Ethylene oxide
Nitric oxide
Nitrogen dioxide
CHLOROPHENOXYACETIC ACID AND DERIVATIVES:
U240 2,4-D
CYANIDE COMPOUNDS:
Cyanide (total)
FLUORINES:
Transfer cyanide compounds
GASES:
Transfer oxygenated wastes
5-17
-------
Table 5-3 (Continued)
NONWASTEWATER CONSTITUENTS NOT REGULATED IN MULTI-SOURCE LEACHATE (F039)
AND REGULATED CONSTITUENTS THAT CONTROL THEIR TREATMENT
Constituents Not Regulated "Controlling" Constituent(s)
Waste Waste
Code Constituent Code Constituent
HALOGENATED ALDEHYDES, ETHERS, AND ESTERS:
P016 Bis(chloromethyl)ether U024 Bis(2-chloroethoxy)methane
P023 Chloroacetaldehyde U025 Dichloroethyl ether
P058 Fluoroacetic acid, sodium U027 Bis(2-chloroisopropyl) ether
salt
P095 Phosgene
U006 Acetyl chloride
U033 Carbonyl fluoride
U034 Trichloroacetaldehyde
U041 l-Chloro-2,3-epoxypropane
U042 2-Chloroethyl vinyl ether
U046 Chloromethyl methyl ether
U156 Methyl chlorocarbonate
HALOGENATED ALIPHATICS:
P027 3-Chloropropionitrile U043 Vinyl chloride
U045 Chloromethane
U075 Dichlorodifluoromethane
U121 Trichloromonofluoromethane
U138 lodomethane
INCINERABLE INORGANICS:
P096 Phosphine Transfer cyanide compounds
P105 Sodium azide
U189 Phosphorus sulfide
U249 Zinc phosphide (<10%)
P006 Aluminum phosphide
P122 Zinc phosphide (>10%)
U135 Hydrogen sulfide
INCINERABLE REACTIVE ORGANICS AND HYDRAZINE DERIVATIVES:
U096 alpha,alpha-Dimethyl benzyl Transfer from amides and amines
hydroperoxide
U109 1,2-Diphenylhydrazine
P009 Ammonium picrate
P081 Nitroglycerin
U133 Hydrazine
U086 N,N-Diethylhydrazine
U160 Methyl ethyl ketone peroxide
P068 Methyl hydrazine
PI12 Tetranitromethane
U023 Benzotrichloride
U098 1,1-Dimethylhydrazine
U099 1,2-Dimethylhydrazine
U103 Dimethyl sulfate
5-18
-------
Table 5-3 (Continued)
NONWASTEWATER CONSTITUENTS NOT REGULATED IN MULTI-SOURCE LEACHATE (F039)
AND REGULATED CONSTITUENTS THAT CONTROL THEIR TREATMENT
Constituents Not Regulated
"Controlling" Constituent(s)
Waste
Code
P069
U003
U149
POOS
P018
P054
P067
U011
U148
U191
Constituent
Uaste
Code
Constituent
Methyllactonitrile
Acetonitrile (a)
Malononitrile
NITRILES:
P101
U009
U152
Ethyl cyanide (Propanenitrile)
Acrylonitrile
Methacrylonitrile
NITROGEN HETEROCYCLIC COMPOUNDS:
4-Aminopyridine
Brucine
Aziridine
2-Methylaziridine
Amitrole
Maleic hydrazide
2-Picoline
U179 N-Nitrosopiperidine
U180 N-Nitrosopyrrolidine
U196 Pyridine
•U171
U234
P082
P084
U173
U176
U177
U178
2-Nitropropane
sym-Trinitrobenzene
NITRO COMPOUNDS:
P077
U105
U106
U169
U181
NITROSO COMPOUNDS:
p-Nitroaniline
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Nitrobenzene
5-Nitro-o-toluidine
N-Nitrosodimethylamine
N-Nitrosomethylvinylamine
N-Nitrosodiethanolamine
N-Nitroso-N-ethylurea
N-Nitroso-N-methylurea
N-Nitroso-N-methylurethane
Ulll Di-n-propylnitrosamine
U172 N-Nitrosodi-n-butylamine
U174 N-Nitrosodiethylamine
5-19
-------
Table 5-3 (Continued)
NONWASTEWATER CONSTITUENTS NOT REGULATED IN MULTI-SOURCE LEACHATE (F039)
AND REGULATED CONSTITUENTS THAT CONTROL THEIR TREATMENT
Constituents Not Regulated "Controlling" Constituent(s)
Waste Waste
Code Constituent Code Constituent
ORGANO-PHOSPHORUS PESTICIDE WASTES:
P040 Diethyl 2-pyrazinyl P039 Disulfoton
phosphorothioate P071 Methyl parathion
P041 Diethyl-p-nitrophenylphosphate P089 Parathion
P043 Diisopropylfluorophosphate P094 Phorate
P044 Dimethoate P097 Famphur
P062 Hexaethyl tetraphosphate
P085 Octamethyl pyrophosphoramide
P109 Tetraethyl dithiopyrophosphate .
Pill Tetraethyl pyrophosphate
U058 Cyclophosphamide
U087 0,0-Diethyl S-methyl
dithiophosphate
U235 Tris(2,3-dibromopropyl)
phosphate
ORGANO-SULFUR COMPOUND WASTES:
P002 l-Acetyl-2-thiourea Transfer from halogenated aliphatic
P014 Thiophenol (Benzenethiol) wastes and aromatic wastes
P022 Carbon disulfide
P045 Thiofanox
P049 2,4-Dithiobiuret
P066 Methomyl
P070 Aldicarb
P072 l-Naphthyl-2-thiourea
P093 N-Phenylthiourea
P116 Thiosemicarbazide
U114 Ethylene bis-dithiocarbamic
acid
U116 Ethylene thiourea
U119 Ethyl methanesulfonate
U153 Methanethiol
U193 1,3-Propane sultone
U218 Thioacetamide
U219 Thiourea
U244 Thiram
Aramite
Benzenethiol
Methyl methanesulfonate
5-20
-------
Table 5-3 (Continued)
NONWASTEWATER CONSTITUENTS NOT REGULATED IN MULTI-SOURCE LEACHATE (F039)
AND REGULATED CONSTITUENTS THAT CONTROL THEIR TREATMENT
Constituents Not Regulated
"Controlling" Constituent(s)
Waste
Code
P001
P003
P005
P088
P102
U001
U008
U053
U057
U085
U113
U122
U123
U124
U125
U126
U147
U154
U166
U182
U190
U197
U213
U248
P007
P042
P075
P108
U010
U015
U035
U059
U089
U090
U143
U150
U163
U164
U200
L'202
U206
U237
Constituent
Waste
Code
Constituent
OXYGENATED HYDROCARBON AND HETEROCYCLIC WASTES:
Warfarin (>0.3%)
Acrolein
Allyl alcohol
Endothall
Propargyl alcohol
Acetaldehyde
Acrylic acid
Crotonaldehyde
Cyclohexanone (a)
1,2:3,4 -Diepoxybutane
Ethyl acrylate
Formaldehyde
Formic acid
Fur an
Furfural
Glycidylaldehyde
Maleic anhydride
Methanol
1,4-Naphthoquinone
Paraldehyde
Phthalic anhydride
p-Benzoquinone
Tetrahydrofuran
Warfarin (<0.3%)
U002 Acetone
U004 Acetophenone
U031 n-Butyl alcohol
U108 1,4-Dioxane
U112 Ethyl acetate
U117 Ethyl ether
U118 Ethyl methacrylate
U140 Isobutyl alcohol
U159 Methyl ethyl ketone
U161 Methyl isobutyl ketone
U162 Methyl methacrylate
WASTES OF A PHARMACEUTICAL NATURE:
5 -Aminomethyl- 3 -isoxazolol
Epinephrine
Nicotine and salts
Strychnine and salts
Mitomycin C
Azaserine
Chlorambucil
Daunomycin
Diethylstilbestrol
Dihydrosafrole
Lasiocarpine
Melphalan
N-Methyl-N-nitro-N-nitroso-
guanidine
Methylthiouracil
Reserpine
Saccharin and salts
Streptozotocin
Uracil mustard
U141 Isosafrole
U155 Methapyrilene
U187 Phenacetin
U203 Safrole
5-21
-------
Table 5-3 (Continued)
NONWASTEWATER CONSTITUENTS NOT REGULATED IN MULTI-SOURCE LEACHATE (F039)
AND REGULATED CONSTITUENTS THAT CONTROL THEIR TREATMENT
Constituents Not Regulated
Constituent
"Controlling" Constituent(s)
Constituent
Waste
Code
P034
P047
U201
U016
U064
U094
P015
P073
P087
P113
P114
P115
U214
U215
U216
U217
Waste
Code
PHENOLIC WASTES:
2-Cyclohexyl-4,6-dinitro-
phenol
4,6-Dinitro-o-cresol salts
Resorcinol
P020
P047
P048
U052
U101
U170
U188
2-sec-Butyl-4,6-dinitrophenol (Dinoseb)
4,6-Dinitro-o-cresol
2,4-Dinitrophenol
Cresol (o-, m-, and p- isomers)
2,4-Dimethylphenol
4-Nitrophenol
Phenol
POLYNUCLEAR AROMATIC WASTES:
Benz(c)acridine
1,2,7,8 -Dibenzopyrene
(Dibenzo(a,i)pyrene)
7,12-Dimethyl benz(a)-
anthracene
Dibenzo(a,e)pyrene
U005 2-Acetylaminofluorene
U018 Benz(a)anthracene
U022 Benzo(a)pyrene
U050 Chrysene
U051 Creosote
U063 Dibenz(a,h)anthracene
U120 Fluoranthene
U137 Indeno(l,2,3-c,d)pyrene
U157 3-Methylcholanthrene
U165 Naphthalene
RECOVERABLE METALLICS:
Beryllium dust
Nickel carbonyl
Osmium tetroxide
THALLIUM:
Thallic oxide
Thallium selenite
Thallium (I) sulfate
Thallium (I) acetate
Thallium (I) carbonate
Thallium (I) chloride
Thallium (I) nitrate
Antimony
Arsenic
Barium
Cadmium
Chromium (total)
Lead
Mercury
Nickel
Selenium
Silver
Antimony
Arsenic
Barium
Cadmium
Chromium (total)
Lead
Mercury
Nickel
Selenium
Silver
5-22
-------
Table 5-3 (Continued)
NONWASTEWATER CONSTITUENTS NOT REGULATED IN MULTI-SOURCE LEACHATE (F039)
AND REGULATED CONSTITUENTS THAT CONTROL THEIR TREATMENT
Constituents Not Regulated
Constituent
"Controlling" Constituent(s)
Constituent
Waste
Code
P119
P120
Waste
Code
VANADIUM:
Ammonium vanadate
Vanadium pentoxide
Antimony
Arsenic
Barium
Cadmium
Chromium (total)
Lead
Mercury
Nickel
Selenium
Silver
OTHER BOAT LIST METALS:
Beryllium
Chromium (hexavalent)
Copper
Zinc
Antimony
Arsenic
Barium
Cadmium
Chromium
Lead
Mercury
Nickel
Selenium
Silver
(total)
Constituent for which a method of treatment is being promulgated
for nonwasterwaters based on the Interlaboratory Ash Study.
May not be applicable to wastewaters.
Has # std for wastewater and method std for nonwastewater
(based on ash study). May not be applicable for wastewaters.
5-23
-------
6.0 CALCULATION OF BOAT TREATMENT STANDARDS
The Agency bases numerical treatment standards for regulated con-
stituents on the performance of well-designed and well-operated BOAT treatment
systems. These standards account for analytical limitations in available
treatment performance data and for variabilities related to treatment, sam-
pling, and analytical techniques and procedures. This section presents the
treatment standards calculated for the constituents selected for regulation in
Section 5.0 using the available performance data discussed in Section 4.0.
6.1 Treatment Standard Calculation Methodology for U and P Wastes
Treatment standards for U and P wastes amenable to quantification in
hazardous waste matrices were calculated based on data compiled from the BOAT
incineration database for incinerator ash and scrubber water. Specifically,
the Agency considered treatment performance data from 11 of the 14
incineration tests listed in Table 4-1. As discussed in Section 4.0, data
from Tests 3, 5, and 6 were not used in calculating treatment standards for
the U and P wastes.
The Agency considered the detection limits from all 11 tests and
determined which were the most representative for each U and P waste
constituent. As described below, to account for the anticipated variability
in untreated U and P wastes, the Agency usually selected the highest detection
limit for each constituent from the 11 incineration tests.
For each U and P waste code included in this document, the Agency
first determined whether the waste constituent of concern was detected in the
untreated or treated wastes included in any of the 11 treatment tests. For
each treatability group, treatment performance data for waste constituents
that were detected in one or more of the 11 treatment tests are included in
Appendix C. Table 4-2 presents detection limits for these waste constituents
in the 11 treatment tests. Detection limits for waste constituents that were
not quantified above detection limits in the untreated or treated wastes from
any of the 11 treatment tests are also summarized in Table 4-2.
6-1
-------
For a waste constituent that was detected in the untreated waste, a
treatment standard was developed based on the highest detection limit for that
constituent in ash from those tests in which the waste constituent was
detected. If a constituent was detected in either of the treatment residuals
(ash or scrubber water), but not in the untreated waste, the Agency feels
there is reason to believe that the constituent was actually present in the
untreated waste. Therefore, the treatment standard for the constituent was
developed based on the highest detection limit for that constituent in ash
from those tests in which the waste constituent was detected. For a waste
constituent that was not detected in any of the untreated or treated wastes in
the 11 treatment tests, the Agency developed a treatment standard based on the
highest detection limit for that constituent in the ash in all 11 treatment
tests.
Numerical treatment standards for waste constituents selected for
regulation in Section 5.0 were calculated by first multiplying the constituent
detection limit in ash by an accuracy correction factor and then multiplying
the result by a variability factor. The following sections discuss these
three components of the treatment standard calculations. These calculations
are summarized in Tables 6-1 and 6-2 (all tables are at the end of this
section).
6.1.1 Detection Limits
Detection limits (presented in Section 4.0) for the ash residuals
were used to calculate treatment standards for nonwastewater forms of these
wastes. In cases where the-waste constituent was detected in more than one
incineration test, the highest detection limit for that constituent in the ash
in those tests was used. For example, 1,2-dichloroethane (U077) was detected
in two treatment tests (4 and 11), as indicated in Table C-l. The highest
detection limit for the ash samples was 2 ppm in Test 4. Therefore, 2 ppm is
shown in Table 6-1 as the detection limit for 1,2-dichloroethane and was used
to calculate the applicable nonwastewater treatment standard.
6-2
-------
For each waste constituent not detected In the untreated or treated
wastes in any of the 11 tests, the highest detection limit reported for that
constituent in ash in the 11 treatment tests was used. For example, isobutyl
alcohol (U140) was not detected in any of the 11 treatment tests and,
therefore, does not appear on Table C-l. Detection limits for this
constituent in ash ranged from 0.2 ppm to 60 ppm, as indicated in Table 4-2.
Therefore, the detection limit of 60 ppm from Test 10 is shown in Table 6-1 as
the detection limit for isobutyl alcohol and was used to calculate the
applicable nonwastewater treatment standard.
Exceptions to this general methodology are noted in the treatability
group discussions in Section 6.2.
6.1.2 Accuracy Correction Factors
The detection limits used to calculate treatment standards were
corrected using matrix spike recovery data from the same test from which the
detection limits were taken in order to account for analytical interferences
associated with the chemical matrices of the samples. Detection limits were
corrected for accuracy as follows:
• A matrix spike recovery was determined for each waste constitu-
ent. In cases where a matrix spike was not performed for a
waste constituent in the treatment test from which the detec-
tion limit was taken, the matrix spike recovery from a similar
constituent from that treatment test was transferred to the
constituent. The source of recovery data used for each con-
stituent is indicated on Table 6-1.
• An accuracy correction factor was determined for each of the
above constituents by dividing 100 by the matrix spike recovery
(percent) for that constituent.
• Detection limits for each of the waste constituents were
corrected by multiplying the detection limit for each
constituent by its corresponding accuracy correction factor.
The detection limit and accuracy correction factor for each
constituent are shown on Table 6-1.
Matrix spike recoveries used to adjust detection limits for the 11
incineration tests are included in Appendix D. Duplicate matrix spikes were
6-3
-------
performed for some waste constituents. If a duplicate matrix spike was
performed for a constituent, the matrix spike recovery used for that constitu-
ent was the lower of the two values from the first matrix spike and the
duplicate spike. Matrix spike recoveries of less than 20% are not acceptable
and were not used to correct detection limits. Matrix spike recoveries
greater than 100% were considered to be 100% for the purpose of this calcula-
tion so that the data were not adjusted to concentrations below the detection
limits. In cases where the detection limit came from more than one test, the
lowest matrix spike recovery among the tests was used. For example, the
highest detection limit for p-chloroaniline (P024) was 5 ppm in Tests 1 and 4.
No matrix spike was performed for p-chloroaniline in Tests 1 or 4. Therefore,
the matrix spike recovery data for a similar constituent, 4-nitrophenol from
Tests 1 and 4 were used to determine the accuracy correction factor for p-
chloroaniline. The lowest matrix spike recovery for 4-nitrophenol from Tests
1 and 4 was 90% in Test 1. Therefore, 90% was entered onto Table 6-1 as the
recovery for p-chloroaniline and was used to calculate the accuracy correction
factor. Using the lowest recovery available resulted in the highest accuracy
correction factor. The tests from which matrix spike recoveries were used are
indicated in Table 6-1.
The specific methods used to determine the accuracy correction
factors for each of the waste constituents are discussed in the treatability
group subsections in Section 6.2.
6.1.3 Variability Factors
The variability factor accounts for the variability inherent in
treatment system performance, treatment residual collection, and analysis of
the treated waste samples. Variability factors could not be calculated for
waste constituents that were not detected in the incinerator ash residuals.
In these cases, a variability factor of 2.8 was used to account for this
inherent variability, as discussed in the Methodology for Developing Treatment
Standards (Reference 2). If a constituent was detected in the ash, then a
variability factor could be calculated. The only constituent for which a
variability factor could be calculated was 2,4-Dichlorophenoxyacetic acid
6-4
-------
(U240). 2,4-D was detected in the ash from Test 13 and a variability factor
was calculated for this constituent. The variability factor calculation is
included in Appendix E. The variability factors used to calculate the
treatment standards for each waste constituent are included in Tables 6-1 and
6-2.
6.2 Detailed Discussion of Organic U and P Waste Treatment Standard
Calculations
6.2.1 Aromatic Wastes
All treatment standards for waste constituents included in the
aromatic wastes treatability group were calculated according to the
methodology described above and are presented in Table 6-1.
6.2.2 Brominated Organic Wastes
Treatment performance data from the Agency's ethylene dibromide
incineration test were used to calculate BOAT treatment standards for
nonwastewater forms of the brominated organic wastes, as discussed in Section
4.1.3. The treatment standards calculated for these wastes are included in
Table 6-2.
6.2.3 Halogenated Aliphatic Wastes
With the exceptions of 1,2-dichloropropane; cis-1,3-
dichloropropylene; trans-1,3-dichloropropylene; and 1,1,2-trichloroethane; all
treatment standards for waste constituents included in the halogenated
aliphatic wastes treatability group were calculated according to the
methodology described above and are presented in Table 6-1.
1,2-Dichloropropane;, cis-1,3-dichloropropylene; trans-1,3-
dichloropropylene; and 1,1,2-trichloroethane were detected in the untreated
waste in only Test 11. According to the treatment standard calculation
methodology described above, the detection limit for each of these
6-5
-------
constituents from Test 11 should be used to calculate the treatment standards.
However, the Agency believes that the detection limits from Test 4 are more
appropriate for calculating the treatment standards for these constituents.
Both the F024 treated in Test 11 and the K019 treated in Test 4 were
chlorinated aliphatic wastes; however, detection limits were higher for
constituents in the K019 incinerator ash, as this matrix was more difficult to
analyze than the F024 matrix. The Agency believes that the higher detection
limits for 1,2-dichloropropane, cis-l,3-dichloropropylene, trans-1,3-
dichloropropylene, and 1,1,2-trichloroethane from K019 ash in Test 4 represent
detection limits that all analytical laboratories can reliably achieve in
complex waste matrices. The resulting treatment standards, presented in Table
6-1, account for the anticipated variability in U and P wastes and should be
achievable on a routine basis for the majority of the U and P wastes.
6.2.4 Halogenated Pesticide and Chlorobenzene Wastes
With the exceptions of isodrin and kepone, all treatment standards
for waste constituents included in the halogenated pesticide and chlorobenzene
wastes treatability group were calculated according to the methodology
described above and are presented in Table 6-1. Acceptable matrix spike
recoveries for incinerator ash were not available for U240, a phenoxyacetic
acid herbicide. Therefore, a recovery of 20% was used for this constituent.
As discussed in Section 4.1.2, detection limit data for aldrin from
the 11 incineration tests were transferred to calculate the BOAT treatment
standard for isodrin in P060 nonwastewaters. The highest detection limit for
aldrin from the 11 incineration tests was used to calculate the treatment
standard for isodrin and the treatment standard calculated is included in
Table 6-1.
The highest detection limit available for kepone from the 11
incineration tests was 0.006 ppm from Test 2. The Agency believes that a
treatment standard based on this detection limit is too low to be routinely
achievable. A comparison of the available detection limits for kepone in the
14 incineration tests to those of similar compounds analyzed by the same
6-6
-------
method indicated that the detection limits for kepone are generally six times
higher than those of similar compounds analyzed by the same method (for
example, gamma-BHC). However, a treatment standard for kepone based on the
detection limit of 0.006 ppm from Test 2 would not reflect the 6:1 ratio when
compared to the treatment standards for similar compounds analyzed by the same
method. Therefore, the Agency believes the detection limit for kepone of
0.006 ppm from Test 2 should be multiplied by a factor of six to calculate the
treatment standard for U142. The remainder of the treatment standard
calculation for kepone was performed according to the methodology described
above. The treatment standard for kepone is included in Table 6-1.
Finally, for U240 (2,4-D and salts and esters), the Agency is
specifying both concentration-based treatment standards and a method of
treatment as the treatment standard. Because 2,4-D salts and esters are not
analyzed as 2,4-D, a numerical treatment standard for 2,4-D does not
necessarily represent treatment of salts and esters of U240. Where a facility
can reasonably assume that only 2,4-D is being handled, only the
concentration-based treatment standard for 2,4-D should be applied. However,
should one expect that salts or esters could be formed during storage,
treatment, or disposal, the U240 nonwastewaters would have to be incinerated
according to the BDAT treatment'standard for U240 salts and esters presented
in Volume B.
6.2.5 Halogenated Phenolic Wastes
All treatment standards for waste constituents included in the
halogenated phenolic wastes treatability group were calculated according to
the methodology described above and are presented in Table 6-1.
6.2.6 Miscellaneous Halogenated Organic Wastes
With the exception of vinyl chloride, all treatment standards for
waste constituents included in the miscellaneous halogenated organic wastes
treatability group were calculated according to the methodology described
above and are presented in Table 6-1.
6-7
-------
Vinyl chloride was detected in the scrubber water residual in Test
11. The Agency therefore believes that vinyl chloride was present in the
untreated waste in Test 11. According to the methodology described above, the
detection limit for vinyl chloride in the ash from Test 11. According to the
methodology described above, the detection limit for vinyl chloride in the ash
from Test 11 should have been used to calculate the treatment standard for
U043. The detection limit for vinyl chloride in the incinerator ash from Test
11 was 0.01 ppm. The Agency believes that this detection limit is too low to
be routinely achievable in ash by analytical laboratories. Therefore, the
highest detection limit for vinyl chloride in ash from all 11 incineration
tests was used to calculate the treatment standard for U043. The treatment
standard calculated for vinyl chloride is presented in Table 6-1.
6.2.7 Organo-nitrogen Compound Wastes
All treatment standards for waste constituents included in the
organo-nitrogen compound wastes treatability group were calculated according
to the methodology described above and are presented in Table 6-1.
6.2.8 Oxygenated Hydrocarbon and Heterocvclic Wastes
With the exception of acetone, all treatment standards for waste
constituents included in the oxygenated hydrocarbon and heterocyclic wastes
treatability group were calculated according to the methodology described
above and are presented in Table 6-1.
Acetone was detected in the untreated waste in 3 of the 11
incineration tests, Tests 9, 11, and 13. According to the methodology
described above, the highest detection limit for acetone in the ash from Tests
9, 11, and 13 should have been used to calculate the treatment standard for
U002. The highest detection limit for acetone in Tests 9, 11, and 13 was
0.01 ppm. The Agency believes that this detection limit is too low to be
routinely achievable in ash by analytical laboratories. Therefore, the
highest detection limit for acetone from all 11 incineration tests was used to
6-8
-------
calculate the treatment standard for U002. The treatment standard calculated
for acetone is presented in Table 6-1.
6.2.9 Wastes of a Pharmaceutical Nature
All treatment standards for waste constituents included in the
wastes of a pharmaceutical nature this treatability group were calculated
according to the methodology described above and are presented in Table 6-1.
6.2.10 Phenolics
All treatment standards for waste constituents included in this
treatability group were calculated according to the methodology described
above and are presented in Table 6-1.
For P047 (4,6-dinitro-o-cresol and salts), the Agency is specifying
both concentration-based treatment standards and a method of treatment as the
treatment standard. Because 4,6-dinitro-o-cresol salts are not analyzed as
4,6-dinitro-o-cresol, a numerical treatment standard for 4,6-dinitro-o-cresol
does not necessarily represent treatment of salts of P047. Where a facility
can reasonably.assume that only 4,6-dinitro-o-cresol is being handled, only
the concentration-based treatment standard for 4,6-dinitro-o-cresol should be
applied. However, should one expect that salts could be formed during
storage, treatment, or disposal, the P047 nonwastewaters would have to be
incinerated according to the treatment standard for P047 salts presented in
Volume B.
6.2.11 Polvnuclear Aromatic .Wastes
With the exceptions of lead in U051 and dibenz(a,h)anthracene,
naphthalene, and phenanthrene, iall treatment standards for waste constituents
included in the polynuclear aromatic wastes treatability group were calculated
according to the methodology described above and are presented in Table 6-1.
6-9
-------
The treatment standard for lead in U051 nonwastewaters is based on
treatment performance data transferred from stabilization of F006, as
discussed in Section 4.1.11. The treatment standard for lead in U051
nonwastewaters was calculated as indicated in Table 6-2.
For dibenz(a,h)anthracene, napththalene, and phenanthrene the
highest detection limits for each constituent was 2.0 ppm from Test 4.
However, the Agency believes that the detection limits from Test 8 are more
representative of the detection limits routinely achievable for these
polynuclear aromatic constituents. The K087 treated in Test 8 contained the
highest concentrations of polynuclear aromatic constituents of any of the
wastes treated in the 11 incineration tests. The K019 treated in Test 4 was
comprised mostly of halogenated aliphatic constituents. Therefore, the
detection limit for each of the constituents dibenz(a,h)anthrancene,
naphthalene, and phenanthrene from Test 8 was used to calculate the treatment
standards for these constituents presented in Table 6-1.
6.3 Detailed Discussion of Treatment Standard Calculations for
Multi-Source Leachate (F039) Constituents
Treatment standards for the majority of the regulated constituents
in nonwastewater forms of multi-source leachate (F039) were calculated using
the methodology described in Sections 6.1 and 6.2 for U and P wastes.
Treatment standards for the remaining regulated constituents in multi-source
leachate (F039) nonwastewaters were calculated by the methodology described in
the Methodology for Developing Treatment Standards (Reference 2) using data
transferred from F, K, and D wastes. A complete list of the regulated
nonwastewater multi-source leachate constituents and the treatment standards
for F039 is presented in Table 6-4. The specific methodology used to
calculate the treatment standard for each multi-source leachate (F039)
constituent is discussed in the subsections below.
6-10
-------
6.3.1 Multi-Source Leachate (F039) Constituents With a Corresponding U or
P Waste
The majority of the regulated organic constituents in nonwastewater
forms of multi-source leachate (F039) are also regulated in a U or P waste.
For these constituents, the treatment standard was calculated using the data
and methodology used for the corresponding U or P waste (except for certain
pesticide constituents as described below).
The treatment standards calculated for the U and P waste
constituents included in this document are presented in Table 6-1. Six of the
regulated nonwastewater multi-source leachate constituents diethyl phthalate,
dimethyl phthalate, di-n-butyl phthalate, di-n-octyl phthalate, bis(2-
ethylhexyl)phthalate, and barium correspond to a U or P waste that is not
included in this background document. Treatment standards calculated for
these six constituents are presented in Table 6-3, and were calculated using
the methodology described in the Methodology for Developing Treatment
Standards (Reference 2). Detailed information on the treatment performance
data and the methodology used to calculate the treatment standards for these
six constituents can be found in the appropriate background document for each
U or P waste code.
For five pesticide constituents, disulfoton, famphur, methyl
parathion, parathion, and phorate, the Agency does not believe that the
detection limits in incinerator ash are routinely achievable in a leachate
nonwastewater matrix. (Data from incinerator ash were used to calculate
treatment standards for the U and P waste codes for these constituents.)
Therefore, treatment performance data for these leachate constituents are not
being transferred from the corresponding U or P waste. The Agency is
establishing treatment standards for disulfoton, famphur, parathion, and
phorate based on detection limits in a nonwastewater residual resulting from
the handling (sludge drying) of multi-source leachate (F039) (Reference 19).
These data represent detection limits following the thermal drying of a
wastewater treatment sludge generated by the biological treatment of multi-
source leachate. The detection limits for parathion are being transferred to
6-11
-------
methyl parathion. The treatment standards calculated for these five
constituents are also presented in Table 6-3.
6.3.2 Multi-Source Leachate (F039) Constituents Without a Corresponding U
or P Waste
The treatment standards for the regulated multi-source leachate
(F039) constituents that do not have a corresponding U or P waste were
calculated using the methodology described in the Methodology for Developing
Treatment Standards (Reference 2). In general, the treated waste data for
each constituent were corrected for accuracy, then the average of the
accuracy-corrected treatment values was multiplied by a variability factor to
determine the treatment standard. Treatment standards calculated for these
constituents are presented in Table 6-3. Treatment performance data for most
of these constituents were transferred from regulated D, F, or K wastes, as
indicated in Table 6-3. Detailed information on the treatment performance
data and the methodology used to calculate the treatment standards for these
constituents can be found in the appropriate background document for each D,
F, or K waste. Treatment performance data for bromodichloromethane and
chlorodibromomethane were transferred from the ethylene dibromide incineration
test conducted by the Agency.
6-12
-------
le
TREATMENT STANDARD CALCULATIONS FOR NONWASTEWATER U AND P WASTES AND TOR MULTI-SOURCE LEACMATE (F039)
cr>
Waste
Code
BOAT
Number
Constituent
Detected In
in Untreated or
Treated Waste Detection
(Y or N) Limit (ppm)
Detection Recovery Data Corrected
Limit Transferred Accuracy Detection Treatment
Taken From Recovery From Correction Limit Variability Standard
Test 0(s) * (%) (BOAT ft/Test #)* Factor (ppm) Factor (ppm) **
AROMATIC WASTES
U019
U220
U239
4
43
215-217
Benzene
Toluene
Xylenes
Y
Y
Y
10
10
10
2
2
2
78
99
100
4/2
43/2
9/2
.28 12.82
1.01 10.10
1.00 10.00
2.8
2.8
2.8
36
28
28
HALOGENATED ALIPHATIC WASTES
U044
U076
U077
U078
U079
U080
U083
U084
U084
U131
U208
U209
U210
U211
U226
U227
U228
U243
14
22
23
24
25
38
26
28
27
113
40
41
42
7
45
46
47
115
Chloroform
1,1-Dichloroethane
1 ,2-Dichloroethane
1 , 1 -Oichloroethylene
trans- 1,2-Dichloroethylene
Methylene chloride
1 , 2 - 0 i ch I oropropane
cis-1,3-Dichloropropylene
trans-1,3-Dichloropropylene
Hexach I oroe thane
1,1. 1 ,2-Tetrachloroethane
1 , 1 ,2,2-Tetrachloroethane
Tetrachloroethylene
Carbon tetrachloride
1,1, 1 -Trichloroethane
1,1,2-Trichloroethane
Trichloroethylene
Hexach I oropropy I ene
Y
Y
Y
N
H
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
N
2
2
2
10
10
10
5
5
5
10
10
10
2
2
2
2
2
10
4
4
4
2
2
1
4
4
4
4
2
2
4
4
4
4
4
4
100
78
78
86
86
84
78
78
78
100
67
67
100
100
100
100
100
100
47/4
24/4
24/4
24/2
24/2
47/1
24/4
24/4
24/4
47/4
47/2
47/2
47/4
47/4
47/4
47/4
47/4
47/4
.00 2.00
.28 2.56
.28 2.56
.16 11.63
.16 11.63
.19 11.90
.28 6.41
.28 6.41
.28 6.41
.00 10.00
.49 14.93
.49 14.93
.00 2.00
.00 2.00
.00 2.00
.00 2.00
1.00 2.00
1.00 10.00
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
5.6
7.2
7.2
33
33
33
18
18
18
28
42
42
5.6
5.6
5.6
5.6
5.6
28
HALOGENATED PESTICIDE AND CHLOROBENZENE WASTES
P004
P037
P050
P050
P050
P051
P051
P059
P059
P060
P123
U036
U037
U060
U060
U061
U061
U061
U061
172
181
182
183
238
184
185
186
187
188
191
177
'9
335
178
235
178
236
179
Aldrin
Dieldrin
Endosulfan 1
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxide
Isodrin
Toxaphene
Chlordane (alpha and gamma)
Chlorobenzene
o,p'-DDD
p,p'-DDD
o,p'-DOD
p,p'-DDD
o,p'-DDE
p,p'-DDE
N
N
N
N
N
N
N
Y
N
N
N
Y
Y
N
N
N
N
N
N
0.0066
0.013
0.0066
0.013
0.013
0.013
0.013
0.0066
0.0066
0.0066
0.13
0.013
2
0.013
0.013
0.013
0.013
0.013
0.013
13,14
13,14
13,14
13,14
13,14
13,14
13,14
13
13,14
13,14
13,14
13
4
13,14
13,14
13,14
13,14
13,14
13,14
28
28
28
28
28
28
28
28
28
28
28
28
99
42
42
42
42
42
42
186/13 3.57 0.02
186/13 3.57 0.05
186/13 3.57 0.02
186/13 3.57 0.05
186/13 3.57 0.05
186/13 3.57 0.05
186/13 3.57 0.05
186/13 3.57 0.02
186/13 3.57 0.02
186/13 3.57 0.02
186/13 3.57 0.46
186/13 3.57 0.05
9/4
1.01 2.02
190/14 2.38 0.03
190/14 2.38 0.03
190/14 2.38 0.03
190/14 2.38 0.03
190/14 2.38 0.03
190/14 2.38 0.03
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
0.066
0.13
0.066
0.13
0.13
0.13
0.13
0.066
0.066
0.066
1.3
0.13
5.7
0.087
0.087
0.087
0.087
0.087
0.087
Treatment test number is indicated in Table 4-1.
** Trcntmcnt standards apply to U and P wastes and to multi
-source leachate.
-------
Table 6-1 (Continued)
TREATMENT STANDARD CALCULATIONS FOR NONUASTEUATER U AND P WASTES AND FOR MULT I-SOURCE LEACHATE (F039)
Waste BOAT
Code Number
Constituent
Detected In
in Untreated or
Treated Waste Detection
(Y or N) Limit (ppm)
Detection
Limit
Taken From
Test #(s) *
Recovery Data
Transferred
Recovery From
(%) (BOAT #/Test #)*
Corrected
Accuracy Detection
Correction Limit
Factor (ppm)
Treatment
Variability Standard
Factor (ppm)
HALOGENATEO PESTICIDE AND CHLOROBENZENE WASTES (continued)
U061
U061
U070
U071
U07Z
U127
U128
U129
U129
U129
U129
U130
UU2
U183
U185
U207
U240
U247
237
180
87
86
88
110
111
173
174
175
176
112
189
136
138
148
192
190
o.p'-DDT
p.p'-DDT
o-D i ch I orobenzene
m-D i ch I orobenzene
p-Dich I orobenzene
Hexach I orobenzene
Hexachlorobutadiene
alpha-BHC
beta-BHC
delta-BHC
gamma -BHC (Lindane)
Hexach I orocyc I opentadi ene
Kepone
Pentach I orobenzene
Pent ach 1 oron i t robenzene
1.2,4,5-Tetrachlorobenzene
2,4-Dichlorophenoxyacetic acid
Methoxychlor
N
N
Y
N
Y
Y
Y
N
N
N
N
Y
N
Y
Y
Y
Y
Y
0.013
0.013
2
2
2
10
10
0.0066
0.0066
0.0066
0.0066
0.36
0.036
10
0.36
5
0.2
0.013
13,14
13,14
4
4
4
4
4
13,14
13,14
13,14
13,14
13
2
4
13
4
13
13
42
42
90
90
90
75
100
28
28
28
28
28
75
75
21
75
20
20
190/14
190/14
88/4
88/4
88/4
150/4
47/4
186/13
186/13
186/13
186/13
186/13
187/2
150/4
110/13
150/4
192/13
190/13
2.38
2.38
1.11
1.11
1.11
1.33
1.00
3.57
3.57
3.57
3.57
3.57
1.33
1.33
4.76
1.33
5.00
5.00
0.03
0.03
2.22
2.22
2.22
13.33
10.00
0.02
0.02
0.02
0.02
1.29
0.05
13.33
1.71
6.67
1.00
0.07
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
10.13
2.8
0.087
0.087
6.2
6.2
6.2
37
28
0.066
0.066
0.066
0.066
3.6
0.13
37
4.8
19
10
0.18
HALOGENATED PHENOLIC WASTES
U039
U048
U081
U082
76
78
90
91
p-Chloro-m-cresol
2-Chlorophenol
2,4-Dichlorophenol
2,6-Dichlorophenol
N
N
Y
Y
5
2
5
5
4
4
4
4
100
98
98
98
76/4
78/4
78/4
78/4
1.00
1.02
1.02
1.02
5.00
2.04
5.10
5.10
2.8
2.8
2.8
2.8
14
5.7
14
14
OXYGENATED HYDROCARBON AND HETEROCYCLIC WASTES
U002
U004
U031
U108
U112
U117
U118
UHO
U159
U161
U162
WASTES
U141
U155
U187
U203
222
53
223
29
225
227
31
33
34
229
35
Acetone
Acetophenone
n-Butyl alcohol
1,4-Dioxane
Ethyl acetate
Ethyl ether
Ethyl methacrylate
Isobutyl alcohol
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl methacrylate
Y
N
N
N
Y
N
N
N
Y
Y
N
50
2
0.4
60
10
50
50
60
10
10
50
2
4,8,10
13,14
10
2
1
2
10
4
1
2
86
58
43
100
86
86
86
100
78
84
86
24/2
102/10
229/14
4/10
24/2
24/2
24/2
24/10
24/4
47/1
24/2
.16
.72
2.33
.00
.16
.16
.16
.00
.28
.19
.16
58.14
3.45
0.93
60.00
11.63
58.14
58.14
60.00
12.82
11.90
58.14
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
160
9.7
2.6
170
33
160
160
170
36
33
160
OF A PHARMACEUTICAL NATURE
117
11.8
140
147
Isosaf role
Methapyri 1 ene
Phenacetin
Safrole
Y
N
N
N
0.36
0.36
5
5
14
13,14
1
1,8,10
39
69
90
64
117/14
144/13
127/1
76/10
2.56
1.45
1.11
1.56
0.92
0.52
5.56
7.81
2.8
2.8
2.8
2.8
2.6
1.5
16
22
Trontmont test number is indicated in Table 4-1.
Treatment standards apply to U and P wastes and to multi-source leachate.
-------
TREAIMENT STANDARD CALCULATIOMS FOR NONWASTEUATER U AND P WASTES AND FOR MULTI-SOURCE LEACHATE (F039)
Waste
Code
BDAT
Number
Detected In Detection Recovery Data Corrected
in Untreated or Limit Transferred Accuracy Detection Treatment
Treated Waste Detection Taken From Recovery From Correction Limit Variability Standard
Constituent (Y or N) Limit (ppro) Test #(s) * (%) (BDAT #/Test #)* Factor (ppm) Factor (ppn)
PHENOLIC WASTES
P020
P047
P048
U052
U052
U101
U170
U188
73
100
101
82
81
. 96
127
142
2-sec-Buty I -4, 6-dini trophenol (Dinoseb)
4,6-Dinitro-o-cresol
2,4-Dini trophenol
Cresol (m- and p- isomers)
o-Cresol
2,4-Dimethylphenol
4-Ni trophenol
Phenol
Y
N
N
Y
Y
N
N
Y
0.36
50
50
1
2
5
10
2
14
4
4
8
4
4
4
4
41
90
90
87
100
100
97
90
73/14
142/4
142/4
76/8
76/4
76/4
127/4
142/4
2.44
.11
.11
.15
.00
.00
.03
.11
0.88
55.56
55.56
1.15
2.00
5.00
10.31
2.22
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.5
160
160
3.2
5.6
14
29
6.2
POLYNUCLEAR AROMATIC WASTES
U005
U018
U022
U050
U051
U051
U051
U051
U051
U051
U063
U120
U137
U157
U165
54
59
62
80
121
139
141
145
43
215-217
83
108
116
119
121
ORGANO-N1TROGEN
P077
P101
U009
U012
U105
U106
U111
U152
U169
U172
U174
U179
U180
U181
U196
125
30
3
56
102
103
105
37
126
128
129
133
134
135
39
2-Acetylaminofluorene
Benz(a)anthracene
Benzo(a)pyrene
Chrysene
Creosote- Naph thai ene
Creosote- Pentach 1 oropnenol
Creosote-Phenanthrene
Creosote- Pyrene
Creosote-Toluene
Creosote- Xy I enes
Dibenz(a,h)anthracene
Fluoranthene
Indeno(1,2,3-c,d)pyrene
3-Methylcholanthrene
Naphthalene
COMPOUND WASTES
p-Nitroaniline
Ethyl cyanide (Propanenitrile)
Acrylonitrile
Anil ine
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-propylnitrosamine
Methacrylonitrile
Nitrobenzene
N-Ni trosodi -n-butylamine
N-Nitrosodiethylamine
N-Ni trosopi per idine
N-Ni trosopyrrol idine
5-Nitro-o-toluidine
Pyr idine
N
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
N
Y
N
N
Y
Y
N
N
N
N
Y
N
N
N
N
N
Y
50
1
1
1
1
3
1
1
10
10
1
1
1
5
1
10
100
30
5
50
10
5
30
5
5
10
10
10
10
5
1
8
8
8
8
1
8
8
2
2
8
8
8
1
8
4
4.7
10
4
4
4
4
10
4
1,4
4
1,4
1.4
1
1
100
34
34
34
91
95
91
34
99
99
34
34
34
96
91
100
78
100
97
100
100
100
100
97
81
100
81
81
100
88
52/1
145/8
145/8
145/8
52/8
139/1
52/8
145/8
43/2
43/2
145/8
145/8
145/8
145/1
52/8
102/4
24/4
24/10
127/4
102/4
102/4
105/4
24/10
127/4
105/1
105/4
105/1
105/1
102/1
4/1
1.00
2.94
2.94
2.94
1.10
1.05
1.10
2.94
1.01
1.01
2.94
2.94
2.94
1.04
1.10
1.00
1.28
1.00
1.03
1.00
1.00
1.00
1.00
1.03
1.23
1.00
1.23
1.23
1.00
1.14
50.0
2.94
2.94
2.94
1.10
2.63
1.10
2.94
10.1
10.1
2.94
2.94
2.94
5.21
1.10
10.00
128.21
30.00
5.15
50.00
10.00
5.00
30.00
5.15
6.17
10.00
12.35
12.35
10.00
5.68
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
140
8.2
8.2
8.2
3.1
7.4
3.1
8.2
28
28
8.2
8.2
8.2
15
3.1
28
360
84
14
140
28
14
84
14
17
28
35
35
28
16
* Treatment test number is indicated in Table 4-1.
** Treatment standards apply to U and P wastes and to multi-source leachate.
-------
Tnble 6-1 (Continued)
TREATMENT STANDARD CALCULATIONS FOR NONUASTEWATER U AND P WASTES AND FOR MULTI-SOURCE LEACHATE (F039)
Waste BOAT
Code Number
Constituent
Detected In Detection
in Untreated or Limit
Treated Waste Detection Taken From
(Y or N) Limit (ppm) Test 0(s) *
Recovery Data Corrected
Transferred Accuracy Detection Treatment
Recovery From Correction Limit Variability Standard
(%) (BOAT #/Test #)* Factor (ppm) Factor (ppm)
MISCELLANEOUS HALOGENATED ORGANIC WASTES
P024 74 p-Chloroaniline
U024 67 Bis(2-chloroethoxy)methane
U025 68 Bis(2-chloroethyl)ether
U027 69 Bis(2-chloroisopropyl)ether
U043 50 Vinyl chloride
U045 15 Chloromethane (Methyl chloride)
U047 77 2-Chloronaphthalene
U075 21 DichIorodifluoromethane
U121 48 Trichloromonofluoromethane
U138 32 lodomethane
U158 120 4,4'-Methylenebis(2-chloroanitine)
U192 144 Pronamide
5
2
2
2
10
10
I
2
10
20
10
0.33
4
4
4
2
2
4
4,7
2
1
13
90
78
78
78
86
86
100
78
86
86
81
69
127/1
24/4
24/4
24/4
24/2
24/2
52/4
24/4
24/2
24/2
105/1
144/13
1
.11
.28
.28
.28
.16
.16
.00
.28
.16
.16
.23
.45
5.56
2.56
2.56
2.56
11.63
11.63
2.00
2.56
11.63
23.26
12.35
0.48
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
16
7.2
7.2
7.2
33
33
5.6
7.2
33
65
35
1.5
* Treatment test number is indicated in Table 4-1.
** Treatment standards apply to U and P wastes and to multi-source leachate.
-------
Table 6-2
TREATMENT STANDARD CALCULATIONS FOR NONWASTEWATER U AND P WASTES THAT
ARE BASED ON PERFORMANCE DATA OTHER THAN THE ELEVEN INCINERATION TESTS
Regulated Constituent
(SW-846 Method Number)
BROMINATED ORGANIC WASTES
Constituent from which
Treatment performance
Data were Transferred
Arithmetic Average
of Corrected Variability
Treatment Performance Factor
Values (pptn) (VF)
Treatment Standard
(Average x VF)
(ppm)
U029 Bromomethane (Methyl bromide)
U066 1,2-Dibromo-3-chloropropane
U067 1,2-Dibrombcnethane
(Ethylene dibromide)
U068 Dibromome thane
U225 Bromoform (Tribromomethane)
U030 4-Brotnophenyl phenyl ether
Ethylene dibromide (EDB Test Burn) 5.41
Ethylene dibromide (EDB Test Burn) 5.41
Ethylene dibromide (EDB Test Burn) 5.41
Ethylene dibromide (EDB Test Burn) 5.41
Ethylene dibromide (EDB Test Burn) 5.41
Ethylene dibromide (EDB Test Burn) 5.41
2.8
2.8
2.8
2.8
2.8
2.8
15
15
15
15
15
15
I
f—'
~J
POLYNUCLEAR AROMATIC WASTES
U051 Lead Lead (F006) 0.37 1.37
* This treatment standard applies to the concentration of the constituent in the TCLP leachate.
0.51'
-------
Table 6-3
TREATMENT STANDARD CALCULATIONS FOR MULTI-SOURCE LEACHATE (F039)
CONSTITUENTS THAT ARE BASED ON PERFORMANCE DATA OTHER
THAN THE ELEVEN INCINERATION TESTS
BOAT List Constituent
Waste Code/Constituent
From Which Treatment
Performance Data
Were Transferred
Average Concentration
. in the Treatment
Residual (ppm)
Accuracy
Correction Factor
Variability
Factor
Treatment
Standard (ppm)
I
^-*
co
ORGAN ICS
51. Acenaphthalene
52. Acenaphthene
57. Anthracene
200. Aroclor 1016
201. Aroclor 1221
202. Aroclor 1232
203. Aroclor 1242
204. Aroclor 1248
205. Aroclor 1254
206. Aroclor 1260
63. Benzo(b)fluoranthene
65. Benzo(k)fluoranthene
64. Benzo(g,h,i)perylene
70. Bis(2-ethylhexyl)phthalate
5. Bromodichloromethane
72. Butyl benzyl phthalate
11. Chlorodibromomethane
12. Chloroethane
16. 3-Chloropropylene
92. Diethyl phthalate
97. Dimethyl phthalate
98. Di-n-butyl phthalate
99. 1,4-Dinitrobenzene
K087/51 1.00
K001-C/52 0.65
K001-C/57 0.65
K085/190 0.33 a
K085/190 0.33 a
K085/190 0.33 a
K085/190 0.33 a
K085/190 0.33 a
K085/190 0.65 a
K085/190 0.65 a
K087/63 1.00
K087/65 1.00
F024/64 0.336
U028/70 <8.2
EDB Tes.t Burn/18 5.41 b
K019 RCRA Blend/70 3.67
EDB Test Burn/18 5.41 b
K019/23 2.00
K019/113 10.00
U088/92 <8.2
U102/97 <8.2
U069/98 <8.2
3rd 3rd Test Burn+/73 0.3375
1.217
2.174
2.174
.217
.217
.613
.190
.000
.064
.000
.190
.190
.190
2.439
a - Arithmetic average of corrected treated waste values. The accuracy correction factors for
this constituent are presented in the background document for the appropriate waste code.
b - Arithmetic average of corrected treated waste values.
c - 1 ppb represents the analytica detection limit that can be achieved for these constituents by
laboratories in the United States, and is consistent with the detection limit for dioxins in F024.
d - This is the Characteristic Level based on the Extraction Procedure (EP) toxicity test.
+ - Test burn conducted by the Agency at John Zink Co., Tulsa, OK (Reference 17).
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.16
2.8
2.8
2.8
2.8
2.8
2.8
2.8
3.4
4.0
4.0
0.92
0.92
0.92
0.92
0.92
1.8
1.8
3.4
3.4
1.5
28.
15.
7.9
15.
6.0
28.
28.
28.
28.
2.3
-------
BOAT List Constituent
Table 6-3 (Continued)
TREATMENT STANDARD CALCULATIONS FOR MULTI-SOURCE LEACHATE (F039)
CONSTITUENTS THAT ARE BASED ON PERFORMANCE DATA OTHER
THAN THE ELEVEN INCINERATION TESTS
Waste Code/Constituent
From Which Treatment
Performance Data
Were Transferred
Average Concentration
in the Treatment
Residual (ppm)
Accuracy
Correction Factor
Variability
Factor
Treatment
Standard (ppm)
ORGAN1CS (Continued)
104. Di-n-octyl phthalate
195. Disulfoton
226. Ethyl benzene
196. Famphur
109. Fluorene
208. Hexachlorodibenzofurans
207. Hexachlorodibenzo-p-dioxins
197. Methyl parathion
131. N-Nitrosomethylethylamine
132. N-Nitrosomorpholine
198. Parathion
210. Pentachlorodibenzofurans
209. Pentachlorodibenzo-p-dioxins
199. Phorate
193. Silvex (2,4.5-TP)
194. 2.4,5-T
212. Tetrachlorodibenzofurans
211. Tetrachlorodibenzo-p-dioxins
149. 2,3,4.6-Tetrachlorophenol
150. 1,2,4-Trichlorobenzene
151. 2,4,5-Trichlorophenol
152. 2.4.6-Trichlorophenol
U107/104
Leachate Data/195
K019 RCRA Blend/226
Leachate Data/196
K001-C/109
F024/-
F024/-
Leachate Data/198
3rd 3rd Test Burn+/73
3rd 3rd Test Burn*/73
Leachate Data/198
F024/-
F024/-
Leachate Data/199
3rd 3rd Test Burn*/192
3rd 3rd Test Burn*/192
F024/-
F024/-
K001-PCP/139
K019/150
K001-PCP/139
K001-PCP/139
<8.2
2.00
2.00
5.00
0.65
1.5
0.3375
0.3375
1.5
1.5
0.155
0.155
12.5
5.0
12.5
12.5
1.190
1.099
1.067
1.099
2.174
1.099
2.439
2.439
1.099
1.099
5.000
5.000
1.053
1.333
1.053
1.053
a - Arithmetic average of corrected treated waste values. The accuracy correction factors for
this constituent are presented in the background document for the appropriate waste code.
b - Arithmetic average of corrected treated waste values.
c - 1 ppb represents the analytica detection limit that can be achieved for these constituents by
laboratories in the United States, and is consistent with the detection limit for dioxins in F024.
d - This is the Characteristic Level based on the Extraction Procedure
-------
Table 6-3 (Continued)
TREATMENT STANDARD CALCULATIONS FOR MULT I-SOURCE LEACHATE (F039)
CONSTITUENTS THAT ARE BASED ON PERFORMANCE DATA OTHER
THAN THE ELEVEN INCINERATION TESTS
BOAT List Constituent
Waste Code/Constituent
From Which Treatment
Performance Data
Were Transferred
Average Concentration
in the Treatment
Residual (ppm)
Accuracy
Correction Factor
Variability
Factor
Treatment
Standard (ppm)
ORGAN1CS (Continued)
49. 1,2,3-Trichloropropane
231. 1,1,2-Trichloro-1,2,2-trifluoroethane
INORGANICS
169. Cyanide (total)
METALS
154. Antimony
155. Arsenic
156. Barium
158. Cadmium
159. Chromium (total)
161. Lead
162. Mercury
163. Nickel
164. Selenium
165. Silver
K019/113
K019/113
K048-K052/169
K021/154
D004/155
P013/156
F006/158
F006/159
F006/161
K071/162
F006/163
D010/164
F006/165
10.
10.
0.27 a
<0.060
12.7
0.018
0.66
0.37
0.0043
0.072
0.674
0.056
1.00
1.00
1.35
1.176
1.176
2.8
2.8
6.4
2.8
3.50
3.72
7.94
1.37
5.47
4.47
7.15
1.29
28.
28.
1.8
TCLP Leachate
(mg/l)
0.23
5.0 d
52.
0.066
5.2
0.51
0.025
0.32
5.7
0.072
a - Arithmetic average of corrected treated waste values. The accuracy correction factors for
this constituent are presented in the background document for the appropriate waste code.
b - Arithmetic average of corrected treated waste values.
c - 1 ppb represents the analytica detection limit that can be achieved for these constituents by
laboratories-in the United States, and is consistent with the detection limit for dioxins in F024.
d - This is the Characteristic Level based on the Extraction Procedure (EP) toxicity test.
+ - Test burn conducted by the Agency at John Zink Co., Tulsa, OK (Reference 17).
-------
Table 6-4
NONWASTEWATER TREATMENT STANDARDS FOR MULT I-SOURCE LEACHATE (F039) CONSTITUENTS
Waste Code From
Which Treatment
Performance Data
Regulated Organic Constituents Were Transferred
Acenaphthalene
Acenaphthene
Acetone
Acetophenone
2-Acetylaminof luorene
Acrylonitrile
Aldrin
Ani line
Anthracene
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
Benz(a)anthracene
Benzene
BenzoC b) f I uoranthene
BenzoC k ) f I uoranthene
Benzo(g,h, i )perylene
Benzo(a)pyrene
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
Bis(2-chloroethoxy)methane
Bis(2-chloroethyl)ether
Bis(2-chloroisopropyl)ether
Bis(2-ethylhexyl)phthalate
Bromod i ch 1 oromethane
Bromomethane (Methyl bromide)
4-Bromophenyl phenyl ether
n-Butyl alcohol
Butyl benzyl ph thai ate
2-sec-Butyl-4,6-dinitrophenol (Dinoseb)
Carbon tetrachloride
Chlordane (alpha and gamma)
p-Chloroaniline
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
p-Chloro-m-cresol
Chi oromethane (Methyl chloride)
2 - Ch I oronaph tha I ene
2-Chlorophenol
3-Chloropropylene
Chrysene
K087
K001-C
U002
U004
U005
U009
P004
U012
K001-C
K085
K085
K085
K085
K085
K085
K085
U018
U019
K087
K087
F024
U022
U129
U129
U129
U129
U024
U025
U027
U028
EDB Test Burn
U029
U030
U031
K019 RCRA Blend
P020
U211
U036
P024
U037
EDB Test Burn
K019
U044
U039
U045
U047
U048
K019
U050
Treatment
Standard (mg/kg)
3.4
4.0
160
9.7
140
84
0.066
14
4.0
0.92
0.92
0.92
0.92
0.92
1.8
1.8
8.2
36
3.4
3.4
1.5
8.2
0.066
0.066
0.066
0.066
7.2
7.2
7.2
28
15
15
15
2.6
7.9
2.5
5.6
0.13
16
5.7
15
6.0
5.6
14
33
5.6
5.7
28
8.2
6-21
-------
Table 6-4 (Continued)
NONWASTEWATER TREATMENT STANDARDS FOR MULTI-SOURCE LEACHATE (F039) CONSTITUENTS
Waste Code From
Which Treatment
Performance Data Treatment
Regulated Organic Constituents Were Transferred Standard (mg/kg)
Cresol (m- and p- isomers)
o-Cresol
o,p'-DDD
p,p'-DDD
o.p'-DDE
p.p'-DDE
o,p'-DDT
p,p'-DDT
Dibenz(a,h)anthracene
1 , 2 - D i bromo- 3 - ch 1 oropropane
1 ,2-Dibromoethane (Ethylene di bromide)
Dibromomethane
m-Dichlorobenzene
o-Dichlorobenzene
p-D i ch I orobenzene
D i chlorodi f luoromethane
1,1-Dichloroethane
1 , 2 - D i ch I oroethane
1 , 1 -D i ch I oroethy I ene
trans-1 ,2-Dichloroethylene
2,4-Dichlorophenol
2,6-Dichlorophenol
2,4-Dichlorophenoxyacetic acid
1 , 2 - D i ch I oropropane
cis-1,3-Dichloropropylene
trans-1, 3-Dichloropropylene
Dieldrin
Diethyl ph thai ate
2,4-Dimethylphenol
Dimethyl ph the I ate
Di-n-butyl phthalate
1,4-Dinitrobenzene
4,6-Dinitro-o-cresol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octyl phthalate
Di -n-propylnitrosamine
1,4-Dioxane
Disulfoton
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Ethyl acetate
Ethyl benzene
Ethyl cyanide (Propanenitri le)
Ethyl ether
U052
U052
U060-U061
U060-U061
U061
U061
U061
U061
U063
U066
U067
U068
U071
U070
U072
U075
U076
U077
U078
U079
U081
U082
U240
U083
U084
U084
P037
U088
U101
U102
U069
3rd 3rd Test Burn
P047
P048
U105
U106
U107
U111
U108
Leachate Data
P050
P050
P050
P051
P051
U112
K019 RCRA Blend
P101
U117
3.2
5.6
0.087
0.087
0.087
0.087
0.087
0.087
8.2
15
15
15
6.2
6.2
6.2
7.2
7.2
7.2
33
33
14
14
10
18
18
18
0.13
28
14
28
28
2.3
160
160
140
28
28
14
170
6.2
0.066
0.13
0.13
0.13
0.13
33
6.0
360
160
6-22
-------
Table 6-4 (Continued)
NONWASTEWATER TREATMENT STANDARDS FOR MULT I-SOURCE LEACHATE (F039) CONSTITUENTS
Waste Code From
Which Treatment
Regulated Organic Constituents
Ethyl methacrylate
Famphur
Fluoranthene
Fluorene
Heptachlor
Heptachlor epoxide
Hexach I orobenzene
Hexach I orobutadi ene
Hexachlorocyclopentadiene
Hexach I orodi benzof urans
Hexach lorodibenzo-p-dioxins
Hexach I oroethane
Hexachloropropylene
Indeno(1,2,3-c,d)pyrene
lodomethane
Isobutyl alcohol
Isodrin
Isosafrole
Kepone
Methacrylonitrile
Methapyri 1 ene
Methoxyehlor
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl methacrylate
Methyl parathion
3-Methylcholanthrene
4,4'-Methylenebis(2-chloroamMine)
Methyl ene chloride
Naphthalene
p-Nitroani line
Nitrobenzene
5-Nitro-o-toluidine
4-Nitrophenol
N-Nitrosodiethylamine
N-Nitrosodi-n-butylarnine
N-Nitrosomethylethylamine
N-Nitrosomorpholine
N-Nitrosopiperidine
N-Nitrosopyrrolidine
Parathion
Pentach I orobenzene
Pentach 1 orodi benzof urans
Pentach 1 orodi benzo-p-dioxins
Pentach loronitrobenzene
Pentach I orophenol
Phenacetin
Phenanthrene
Phenol
Phorate
Performance Data
Were Transferred
U118
Leachate Data
U120
K001-C
P059
P059
U127
U128
U130
F024
F024
U131
U243
U137
U138
UUO
P060
UU1
UU2
U152
U155
U247
U159
U161
U162
Leachate Data
U157
U158
U080
U165
P077
U169
U181
U170
U174
U172
3rd 3rd Test Burn
3rd 3rd Test Burn
U179
U180
Leachate Data
U183
F024
F024
U185
U051
U187
U051
U188
Leachate. Data
Treatment
Standard (mg/kg)
160
15
8.2
4.0
0.066
0.066
37
28
3.6
0.001
0.001
28
28
8.2
65
170
0.066
2.6
0.13
84
1.5
0.18
36
33
160
4.6
15
35
33
3.1
28
14
28
29
28
17
2.3
2.3
35
35
4.6
37
0.001
0.001
4.8
7.4
16
3.1
6.2
4.6
6-23
-------
Table 6-4 (Continued)
NONWASTEWATER TREATMENT STANDARDS FOR MULT1-SOURCE LEACHATE (F039) CONSTITUENTS
Regulated Organic Constituents
Waste Code From
Which Treatment
Performance Data
Were Transferred
Treatment
Standard (rag/kg)
Pronamide
Pyrene
Pyridine
Safrole
Silvex (2,4,5-TP)
1,2,4,5-Tetrachlorobenzene
Tet rachIorod i benzofurans
Tetrachlorodibenzo-p-dioxins
1,1,1,2-Tet rachIoroethene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
2,3,4,6-Tetrachlorophenol
Toluene
Toxaphene
Tribromomethane (Bromoform)
1,2,4-Trichlorobenzene
1,1.1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethylene
Trichloromonofluoromethane
2,4,5-Trlchlorophenol
2,4,6-Trichlorophenol
2,4,5-Trichlorophenoxyacetic acid
1,2,3-Trichloropropane
1,1,2-Trichloro-1,2,2-trifluoroethane
Vinyl chloride
Xylenes
Regulated Inorganic Constituents:
Cyanides (total)
U192
U051
U196
U203
3rd 3rd Test Burn
U207
F024
F024
U208
U209
U210
K001-PCP
U220
P123
U225
K019
U226
U227
U228
U121
K001-PCP
K001-PCP
3rd 3rd Test Burn
K019
K019
U043
U239
K048-K052
Waste Code From
1.5
8.2
16
22
7.9
19
0.001
0.001
42
42
5.6
37
28
1.3
15
19
5.6
5.6
5.6
33
37
37
7.9
28
28
33
28
1.8
Regulated Metal Constituents
Antimony
Arsenic
Barium
Cadmium
Chromium (total)
Lead
Mercury
Nickel
Selenium
Silver
Which Treatment
Performance Data
Were Transferred
K021
D004
P013
F006
F006
F006
K071
F006
D010
F006
Treatment
Standard
TCLP (mg/l)
0.23
s.o a
52
0.066
5.2
0.51
0.025
0.32
5.7
0.072 -
S Based on EP Toxicity.
6-24
-------
7.0 ACKNOWLEDGEMENTS
This background document was prepared for the U.S. Environmental
Protection Agency, Office of Solid Waste, by Radian Corporation under Contract
No. 68-W9-0072. This document was prepared under the direction of Richard
Kinch, Acting Chief, Waste Treatment Branch; Larry Rosengrant, Section Head,
Treatment Technology Section; Jerry Vorbach, Project Officer; and Lisa Jones,
Project Manager. Steve Silverman served as EPA legal advisor.
The following personnel from Radian Corporation were involved in
preparing this document: John Williams, Program Manager; Mary Willett,
Project Director; and the Radian engineering team, Chrisanti Haretos, Colleen
Kane, Wendy Rovansek, and Douglas Spengel.
7-1
-------
8.0 REFERENCES
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U.S. Environmental Protection Agency.
4. USEPA. 1987. U.S. Environmental Protection Agency. Onsite
Engineering Report of Treatment Technology Performance and Operation
for Incineration of KOOl-Pentachlorophenol (PGP) Waste at the U.S.
Environmental Protection Agency Combustion Research Facility.
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Agency.
5. USEPA. 1987. U.S. Environmental Protection Agency. Onsite
Engineering Report of Treatment Performance and Operation for
Incineration of K001-Creosote Waste at the U.S. Environmental
Protection Aeencv Combustion Research Facility. November 23, 1987.
Washington, D.C.: U.S. Environmental Protection Agency.
6. USEPA. 1987. U.S. Environmental Protection Agency. Onsite
Engineering Report of Treatment Performance and Operation for
Incineration of K011/K013/K014 Sludge at the John Zink Test
Facility. November 2, 1987. Washington, D.C.: U.S. Environmental
Protection Agency.
7. USEPA. 1988. U.S. Environmental Protection Agency. Non-
confidential Version of the Onsite Engineering Report of Treatment
Technology Performance and Operation for Rollins Environmental
Services (TX) Inc.. Deer Park. Texas. March 11, 1988. Washington,
D.C.: U.S. Environmental Protection Agency.
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Engineering Report of Treatment Technology Performance and
Operation: Incineration of K024 Waste at the U.S. Environmental
Protection Agency Combustion Research Facility. Washington, D.C.:
U.S. Environmental Protection Agency.
9. USEPA. 1987. U.S. Environmental Protection Agency. Onsite
EnEJneering Report of Treatment Technology Performance and Operation
for Incineration of K037 Waste at the Combustion Research Facility.
November 16, 1987. Washington, D.C.: U.S. Environmental Protection
Agency.
8-1
-------
10. USEPA. 1988. U.S. Environmental Protection Agency. Onsite
Engineering Report of Treatment Technology Performance and Operation
for Amoco Oil Company. Whiting. Indiana. February 29, 1988.
Washington, D.C.: U.S. Environmental Protection Agency.
11. USEPA. 1988. Onsite Engineering Report of Treatment Technology
Performance and Operation for Amoco Oil Company. Whiting. Indiana.
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12. USEPA. 1988. U.S. Environmental Protection Agency. Onsite
Engineering Report of Treatment Technology Performance and Operation
for Incineration of K087 Waste at the Combustion Research Facility.
Jefferson. Arkansas. February 22, 1988. Washington, D.C.: U.S.
Environmental Protection Agency.
13. USEPA. 1988. U.S. Environmental Protection Agency. Onsite
Engineering Report for John Zink Company for K101. April 25, 1988.
Washington, D.C.: U.S. Environmental Protection Agency.
14. USEPA. 1988. U.S. Environmental Protection Agency. Onsite
Engineering Report for John Zink Company for K102. April 25, 1988.
Washington, D.C.: U.S. Environmental Protection Agency.
15. USEPA. 1988. U.S. Environmental Protection Agency. Onsite
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for Incineration for ENSCO. El Dorado. Arkansas. December, 1988.
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16. USEPA. 1987. U.S. Environmental Protection Agency. Onsite
Engineering Report of Treatment Performance and Operation for
Incineration of K015 Waste at the John Zink Company Test Facility.
December 4, 1987. Washington, D.C.: U.S. Environmental Protection
Agency.
17. USEPA. 1990. U.S. Environmental Protection Agency, Office of Solid
Waste. Onsite Engineering report of Treatment Technology
Performance and Operation for John Zink Company. Washington, D. C.:
U.S. Environmental Protection Agency.
18. Rollins Environmental Services, Inc. 1988. RES (TX) EPS Test Burn
Program Emissions Test Results. Volume 1. Deer Park, TX: Rollins
Environmental Services.
19. Chemical Waste Management, Inc. 1989. Treated Bio-solids Data
Representing Thermal Drying. Submitted to EPA RCRA Docket F-89-
LD12-FFFFF. Comment No. LD12S0591. Washington, D.C.: U.S.
Environmental Protection Agency.
8-2
-------
20. USEPA. 1988. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BOAT) Background
Document for F006 Waste. Washington, D.C.: U.S. Environmental
Protection Agency.
21. USEPA. 1988. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BOAT) Background
Document for K001 Waste. Washington, D.C.: U.S. Environmental
Protection Agency.
22. USEPA. 1988. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BOAT) Background
Document for K016. K018. K019. K020. K030 Wastes. Washington, D.C.:
U.S. Environmental Protection Agency.
23. USEPA. 1988. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BDAT) Background
Document for K024 Waste. Washington, D.C.: U.S. Environmental
Protection Agency.
24. USEPA. 1988. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BOAT) Background
Document for K037 Waste. Washington, D.C.: U.S. Environmental
Protection Agency.
25. USEPA. 1988. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BOAT) Background
Document for K048-K052 Waste. Washington, D.C.: U.S. Environmental
Protection Agency.
26. USEPA. 1988. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BOAT) Background
Document for K087 Waste. Washington, D.C.: U.S. Environmental
Protection Agency.
27. USEPA. 1988. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BOAT) Background
Document for K101 and K102. Low Arsenic Subcategory. Washington,
D.C.: U.S. Environmental Protection Agency.
28. USEPA. 1989. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BOAT") Background
Document for Cyanide Wastes. Washington, D.C.: U.S. Environmental
Protection Agency.
29. USEPA. 1989. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BOAT) Background
Document for F024 Waste. Washington, D.C.: U.S. Environmental
Protection Agency.
8-3
-------
30. USEPA. 1988. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BOAT) Background
Document for KOI5 Waste. Washington, D.C.: U.S. Environmental
Protection Agency.
31. USEPA. 1988. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BOAT) Background
Document for K022 Waste. Washington, D.C.: U.S. Environmental
Protection Agency.
32. Radian Corporation. 1987. Analytical Results. Combustion Research
Facility Test Burn K001 Creosote Waste. Austin, Texas: Radian
Corporation.
33. National Library of Medicine, Toxicology Data Network, Hazardous
Substances Databank (HDSB).
34. SRI International. 1987. 1987 Directory of Chemical Producers -
United States of America. Menlo Park, California: SRI
International.
35. SRI International. 1988. 1988 Directory of Chemical Producers -
United States of America. Menlo Park, California: SRI
International.
36. USEPA. 1986. U.S. Environmental Protection Agency. National
Survey of Hazardous Waste Treatment. Storage. Disposal. Recycling
Facilities. Washington, D.C.: U.S. Environmental Protection
Agency.
37. USEPA. 1987. U.S. Environmental Protection Agency, Office of Solid
Waste. Generic Quality Assurance Prolect Plan for Land Disposal
Restrictions Program ("BOAT"). Washington, D.C.: U.S.
Environmental Protection Agency.
38. Verschueren, K., ed. 1983. Handbook of Environmental Data on
Organic Chemicals. 2nd ed. New York, New York: Van Nostrand
Reinhold Company.
39. Windholz, M., ed. 1983. The Merck Index. 10th ed. Rahway, New
Jersey: Merck & Company.
40. USEPA. 1990. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BOAT) Background
Document for K031. K084. K101. K012. Characteristic Arsenic Wastes
(D004). Characteristic Selenium Wastes (D010). and P and U Wastes
Containing Arsenic and Selenium Listing Constituents. Washington,
D.C.: U.S. Environmental Protection Agency.
8-4
-------
41. USEPA. 1990. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BDAT) Background
Document for Barium Wastes D005 and P013. Washington, D.C.: U.S.
Environmental Protection Agency.
42. USEPA. 1988. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BOAT) Background
Document for K071. Washington, D.C.: U.S. Environmental Protection
Agency.
43. USEPA. 1990. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BOAT) Background
Document for K021. Washington, D.C.: U.S. Environmental Protection
Agency.
44. USEPA. 1990. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BDAT) Background
Document for Halogenated Pesticide and Chlorobenzene Wastes K032-
K034. K041. K042. K085. K097. K105. D012-D017. Washington, D.C.:
U.S. Environmental Protection Agency.
45. USEPA. 1989. U.S. Environmental Protection Agency, Office of Solid
Waste. Best Demonstrated Available Technology (BOAT) for Phthalate
Wastes. June, 1989. Washington, D.C.: U.S. Environmental
Protection Agency.
46. USEPA. 1987. U.S. Environmental Protection Agency, Office of Solid
Waste. Analytical Results. John Zink Facility Test Burn of K015
Waste. Washington, D.C.: U.S. Environmental Protection Agency.
47. USEPA. 1987. U.S. Environmental Protection Agency, Office of Solid
Waste. Analytical Results. John Zink Facility Test Burn of K011.
K013. and K014 Acrvlonitrile Waste. Washington, D.C.: U.S.
Environmental Protection Agency.
48. USEPA. 1987. U.S. Environmental Protection Agency, Office of Solid
Waste. Combustion Research Facility Test Burn of K024. Volatiles.
Semivolatiles. Metals, and Carbon Analysis. Washington, D.C.: U.S.
Environmental Protection Agency,
49. USEPA. 1987. U.S. Environmental Protection Agency, Office of Solid
Waste. Analytical Results. Combustion Research Facility Test Burn
of K001 PGP Waste. Washington, D.C.: U.S. Environmental Protection
Agency.
50. USEPA. 1987. U.S. Environmental Protection Agency, Office of Solid
Waste. Analytical Results. Combustion Research Facility Test Burn
of K001 Creosote Wastes. Washington, D.C.: U.S. Environmental
Protection Agency.
8-5
-------
51. USEPA. 1987. U.S. Environmental Protection Agency, Office of Solid
Waste. Analytical Results. Combustion Research Facility Test Burn
of K037 Waste. Washington, D.C.: U.S. Environmental Protection
Agency.
8-6
-------
APPENDIX A
U AND P WASTE GENERATOR INFORMATION
A-l
-------
TABLE A-1
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
WASTECODE NAME
INDUSTRY
USE (a)
U001 Acetaldehyde
>
U002
Acetone
U003
Acetonitrile
Food Processing
Plastics and Resins Manufacturing
Dyes and Pigments Manufacturing
Cosmetics and Fragrances
Organic Chemical Manufacturing
Agricultural Chemical Manufacturing
Film
Fiber Manufacturing
Electronic Components Manufacturing
Paint Manufacturing
Plastics and Resins Manufacturing
Pharmaceutical Manufacturing
Explosives
Organic Chemical Manufacturing
Printing
Synthetic flavor ingredient
Manufacture of resins and plastics
Manufacture of dyes
Manufacture of perfumes
Chemical intermediate for pyridine, pyridine bases,
pentaerythritol, 1,3-butylene glycol, chloral,
glyoxal, crotonaldehyde, acetaldehyde 1,1-dimethylhydrazone,
acetaldehyde cyanohydrin, acetaldehyde oxime,
paraldehyde, metaldehyde, halogenated derivatives,
acetaldol, sodium sulphite addition product,
acetic anhydride, ethylidene diacetate, alkyl amine,
ethyl acetate, isobutyl acetate, lactic acid,
acetic acid, peracetic acid
Monomer for polyacetaldehyde and comonomer for polymers
Chemical intermediate for pesticides
Chemical intermediate for photographic formulations
Alcohol denaturant
Spinning solvent for cellulose acetate
Cleaning and drying electronic parts
Solvent for paints, varnishes, lacquers
Solvent for resins and plastics
Solvent in the manufacture of Pharmaceuticals
Manufacture of smokeless powder
Solvent for fats, oils waxes
Manufacture of mesityl oxide, acetic acid, diacetone,
alcohol, chloroform, iodoform, bromoform, acetic anhydride
Chemical intermediate for methacrylates,
methyl isobutyl ketone, methyl isobutyl carbinol,
bisphenol A, isophorone
Solvent for printing inks
Deodorizers for specialty naphthas
Solvent for inorganic compounds
Specialty solvent
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
WASTECODE NAME
INDUSTRY
USE (a)
U003 (continued)
>
u>
UOOA Acetophenone
Food Processing
Metal Finishing
Dyes and Pigments
U005 2,3-Acetylaminofluorene
Organic Chemicals
Pesticide Manufacturing
Petroleoum Refining
Pharmaceuticals/Medicine
Dyes and Pigments Manufacturing
Plastics and Resins Manufacturing
Organic Chemical Manufacturing
Food Processing
Cosmetics and Fragrances
Tobacco
Construction
Polar solvent
Starting material for many nitrogen-containing compounds
Recrystallizing steroids
Extraction of fatty acids from fish liver,animalSveg. oils
Non-aqueous solvent for inorganic salts
Brightners for metal
Chemical intermediate -gamm-naphthaleneacetic acid,etc.
In miscellaneous operations for cyanide dyes
Medium for promoting ionizatlon
In electrodinetic transducers and angular accelerometers
Solvent in non-aqueous titrations
Starting material thiamine.acetamidine, etc.
Solvent in hydrocarbon extraction processes
Chemical intermediate-pesticide manufacture
Coloring matter from some petroleum hydrocarbons
Separation of alkaloids from tissue extraction
Solvent for dyes
Specialty solvent for plastics and resins
Chemical intermediate for the odorant,
ethyl methyl phenylglycidate, the riot
control agent, 2-chloroacetophenone,
2-bromoacetophenone( for dyes, 3-nitroacetophenone
Flavoring agent in non-alcoholic beverages,
ice cream, candy, baked goods, gelatins,
and puddings
Fragrance ingredient in soaps, detergents,
creams, lotions, and perfumes
Flavoring in tobacco
In coal tar for road surfaces and roofing materials
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
==S=C=S===BS===e=====S:=========ES:S=
INDUSTRY
USE (a)
U005 (continued)
U006 Acetyl chloride
U007 Acrylamide
Pharmaceutical
Organic Chemicals Manufacturing
Medicine
Laboratory
Specialty Chemical
Dyes and Pigments
Pharmaceuticals
Agricultural Chemicals
Mining
Binder for electrodes in aluminum reduction process
Treatment of skin disorders
Waterproofing
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
Catalyst in chlorination of acetic acid
Production of acetamide
Production of acetyl sulflde
Testing for cholesterol
Determination of water in inorganic liquid
Chemical intermediate acetanilide preparation
Chemical intermediate acetophenone reparation
Qualitative organic analysis
Synthesis of dienestrol diacetate
Production of thioacetic acid
Chlorinating agent inorganic compounds and triarylcarbinols
Acetylating agent
Manufacture dyestuffs
Pharmaceuticals manufacturing
Sewage and waste treatment
Polyacrylamides manufacturing
Flocculating aid for precip. suspended solids from aqueous systems
Flocculants
Cross-linking agent
In soil-conditioning agents
In ore processing, adhesives
Chemical intermediate in polyaeryI amides
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
UASTECODE NAME
INDUSTRY
========
USE (a)
U007 (continued)
U008 Acrylic acid
>
t_n
U009 Acrylonitrile
Paper and Textile
Building & Construction
Dyes and Pigments
Organic Chemicals Manufacturing
Textiles
Organic Chemical Manufacturing
Textiles
Cleaning Products
Leather and Tanning
Plastics and Resins Manufacturing
Agricultural Chemicals
Plastics
Water Treatment
Paper and textile sizes
Construction of dam foundations ft tunnels
Synthesis of dyes
Reactive monomer & intermed. organic chemicals production
Permanent press fabrics
Chemical intermediate for ethyl acrylate, n-butyl acrylate,
methyl acrylate, 2-ethylhexyl acrylate, acrylate hydoxyethyl
Monomer for polyacrylic acid and salts
Comonomer with scryI amide for polymers used as polymers
Surface coatings
Textile applications
Manufacture of polishes
Manufacture of leather
Production of water soluble resins and salts
Chemical intermediate antioxidants synthesis
In co-polymers with styrene and butadiene
Chemical intermediate surface-active agents
Comonomer for starch/acrylonitrile copolymers
Funigant for mills and commodities (former use)
Synthetic soil blocks
Chemical intermediate for acrylamidoaminoethane sulfonic acid
Elastomers for hoses, gaskets & protective clothing
Chemical intermediate for fatty aminopropylamine & derivs.
Modifier for natural polymers
Comonomer for nitrite elastomers
In floccutants for water and waste treatment
Comonomer for alkyd/acrylonitrite copolymers
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
UASTECOOE NAME
INDUSTRY
USE (B)
U009 (continued)
>
U010
U011
Hitomycin C
Amitrole
Agricultural Chemicals
Plastics
Paper Manufacturing
Petroleum
Adhesive and Sealants
Bottling
Dyes and Pigments
Textiles and Fibers
Food Processing
Pesticide Manufacturing
Pharmaceuticals
Plastics and Resins
Rubber
Medicine
Agricultural Chemicals
Photography
U012
Aniline
Organic synthesis to introd. cyanoethyl group
Comonomer with styrene for urethane polyether polyols
Chemical intermediate for adiponitrite & acrylamide
Fumigating stored tobacco
In plastics for appliances,automobile interior,boats,RV bodies,etc.
Retention aids in paper-making & flotation processes
Comonomer for barrier resins
Mobility control agents in crude oil recovery
Comonomer for acrylic acid
No information available
Bottles for soft drinks (use discontinued)
Chemical intermediate dyes
To improve the dye and working properties of acrylic fibers
Comonomer for acrylic and modacrylic fibers
Manufacture of blankets,draperies,upholstery,syn. furs,wigs
In apparel,carpet ing,home furnishing,sandbags,fiUer cloths,etc.
Cyanoethylat ion of cotton
Applied to mi 11 ing,baking,food processing machinery
In insecticides
Pesticide fumigant for stored grain (former use)
Chemical intermediate Pharmaceuticals
Chemical intermediate for glutethimide (sedative)
No information available
Manufacturing nitrite rubbers
Medication
Herbicide for non-crop uses (aquatics, hardwood nursery stock)
Cotton defoliant
Herbicide for food crops (former use)
Plant growth regulator
Reagent in photography
Chemical intermediate for substituted aniline salts
-------
WASTECODE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
. INDUSTRY
USE (a)
U012 (continued)
>
Plastics and Resins
Explosives
Agricultural Chemicals
Cosmet i cs/F ragrances
Dyes and Pigments
Photography
Food Processing
Leather and Tanning
Organic Chemicals
Plastics and Resins Manufacturing
Paper Manufacturing
Pesticides Manufacturing
Isocyanate synthesis
Catalyst and stabilizer for hydrogen peroxide synthesis
Chemical intermediate for 6-Anilinophenol
Solvent
Vulcanization accelerator
Chemical intermediate for hydroquinone
Cellulose as a precursor
Manufacture shoe blacks
Azeotropic agent in manufact. of anhydrous hydrazine
Chemical intermediate for methylenediisocyanate
Manufacture isocyanates for urethane foam
Manufacture explosives
Manufacture of teryl & optical whitening agents
Chemical intermediate for corrosion inhibitors
Manufacture herbicides, fungicides
Manufacture perfumes
Chemical intermediate for dyes ft pigments
In situ dyeing agent
Manufacture photographic chemicals
In synthesis of intermediates for artificial sweeteners
Component of skin stains
Manufacture of rigid polyurethanes
Component of lacquers ft wood stains
Chemical intermediate for specialty resins & cyclohexylamine
Manufacture res ins.varnishes
Paint removers
Analytical reagent in paper chemistry
Chemical intermediate for pesticides
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
===rs=assE=sasss=sass=======s===s==ss==
INDUSTRY
USE (a)
U012 (continued)
UOU Auramine
>
oo
U015 Azaserine
U016 Benz(c)acridine
U017 Benzal chloride
U018 Benz(a)anthracerte
U019 Benzene
Petroleum Refining
Pharmaceutical Manufacturing
Printing
Rubber
Dyes and Pigments
Pharmaceuticals
Agricultural Chemicals
Medicine
Pharmaceuticals/Medicine
Construction
Pharmaceutical
Organic Chemicals Manufacturing
Chemical Research
Specialty Chemical
Dyes and Pigments Manufacturing
Chemical Research
Organic Chemicals Manufacturing
Medicine
Dyes and Pigments
No information available
Chemical intermediate for Pharmaceuticals
Printing inks,cloth marking inks
Chemical intermediate for rubber processing
Dye for lacquers,pen inks,carbon papers,typewriter ribbons
Food dye in some countries
Dye for paper,cardboard,textiles,leather,oils,waxes,alcoholic solvents
Preparation of solvent yellow 34
Smoke dye
Antiseptic
Fungicide
Research chemical
Antineoplastic agent, antibiotic, abort)facient, antifungal
In coal tar for road surfaces and roofing materials
Binder for electrodes in aluminum reduction process
Treatment of skin disorders
Waterproofing
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
Research chemical
Preparation of benzoyl chloride
Manufacture of cimamic acid
Chemical intermediate for benzaldehyde
In dyes
No commercial use in U.S.
Manufacture of styrenes, phenols, cyclohexanes
Manufacture of medicinal chemicals
Manufacture of dyes
Manufacture of artificial leather, linoleum, oil cloth
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U019 (continued)
U020 Benzenesulfonyl chloride
I U021 Benzidine
vo
U022 Benzo(a)pyrene
Plastics and Resins
Soap
Pesticide
Specialty Chemical
Pesticide
Laboratory
Food
Paper
Sugar
Medicine
Laboratory
Specialty Chemical
Printing
Plastics
Dyes and Pigments
Rubber
Construction
Pharmaceutical
Manufacture of airplane dopes
Manufacture of varnishes and lacquers
Solvent for waxes, resins, oils, etc.
Manufacture of detergents
Manufacture of pesticides
Chemical intermediate for benzonitrile
Chemical intermediate for thiophenol
Chemical intermediate for glybuzole
Chemical intermediate for benzene sulfonamides
Chemical intermediate for N-2-chloroethyl amides
Esters formerly'used as insecticides,miticides.fenson acaricide
Reagent for Freiedl-Crafts sulfonulation
Reagent for hydrogen peroxide in milk
Production of security paper
Spray reagent for sugars
Used to verify TLC bands attributed to blood (former use)
Stain in microscopy
Lab agent to detect cyanide t sulfate
Quantitative determination of nicotine
Organic synthesis
Used in security printing
Llquificat ion meadurement
Manufacture of plastic films
Chemical intermediate for AZO dyes
Stiffening agent in rubber compounding
In coal tar for road surfaces and roofing materials
Binder for electrodes in aluminum reduction process
Treatment of skin disorders
Waterproofing
-------
WASIECODE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
sss=ssrsr=sss=sssssaa2aBsa=sssssss=sasss=aass
INDUSTRY
USE (a)
U022 (continued)
U024 Bis(2-chloroethoxy)methane
U025 Dichloroethyt ether
I
I—•
o
U026 Chloronaphazine
U027 bis-(2-chloroeisopropyl)ether
U029 Methyl bromide
Organic Chemicals Manufacturing
Medical Research
Rubber
Petroleum Refining
Agricultural Chemicals
Organic Chemicals
Pesticides
Pharmaceuticals
Textiles
Lubricant
Medicine
Textiles
Food
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
Positive control for mutagenicity end careinogenicity studies
Solvent
Chemical intermediate for polysulfide rubber
Scavenge lead deposits in gasoline
Purification of oils
Soil fumigant (former use)
Control earworms on corn (former use)
Chemical intermediate & cross-1 inker
Acaricide (former use)
Anesthetic
Scouring of textiles
Used in aerosols
GeneraI/selective solvent production lubricating oils
In ICier boiling
Antineoplastic agent (not in U.S.)
Chemical intermediate
In paint and varnish removers
Spotting and cleaning solutions
Solvent for fats, waxes, grease
Textile processing
Food sterilization
Extraction of oils from nuts, seeds, flowers
Fire extinquisher
Refrigerant
In ionization chambers
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
=========
WASTECOOE NAME
==================================================
SS= = = = = = S = S = = asS = = = a = = =: = = ;: = = = = S = =
INDUSTRY
USE (a)
U029
U033
U034
U035
U036
U037
U038
U039
(continued)
U030 6-Bromophenyl phenyl ether
U031 n-Butyl alcohol
Carbon fluoride
Trichloroacetaldehyde
Chlorambucil
Chlordane
Chlorobenzene
Chlorobenzilate
p-Chloro-m-cresol
Agricultural Chemicals
Dyes and Pigments
Pesticides
Pharmaceuticals
Chemical Research
Pharmaceutical Manufacturing
Veterinary Medicine
Furniture Manufacturing
Organic Chemical Manufacturing
Petroleum
Pesticides
Medicine
Veterinary Medicine
Pesticide
Pesticide
Pesticide
Degreesing wool
Funigant for soil
Solvent in aniline dyes
Insect and rodent control in space and commodity fumigations
Methylating agent
Not in U.S.
Manufacture of Pharmaceuticals
Bactericide
Solvent for surface coatings
Chemical intermediate for ethylene glycol,
monobutyl ethers, glycol ethers, plasticizers,
n-butyl acetate, n-butyl acrylate, butylamines,
2,4-D esters
Dehydrating agent
Solvent for vegetable oils and alkaloids
Chemical intermediate in organic synthesis
Induce swelling of starch granules
Spraying and pouring of polyurethanes
Chemical intermediate for chloral hydrate
Chemical intermediate for herbicide trichloroacetic acid
Intermediate in manufacture of DDT,methoxychlor,DDVP,naled,trichlorofon
Not produced in U.S. (imported from U.K.)
Antineoplastic agent: leukemia,Hodgkins disease,malignant lymphomas,etc.
Antineoplastic agent
Insecticide
Manufacture of insecticide
Acaricide
External germicide
-------
WASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
r===s:============r=sr======sscss=sasz====B==ssr===========
INDUSTRY
USE (a)
U041 n-Chloro-2,3-epoxypropane
Plastics and Resins
Paper Manufacturing
>
I
Agricultural Chemicals
Optics
Scavenging additive to trichloroethylene
Preparation of compensates with polyfunctional substances
Chemical intermediate for give idyl acrylate and glycidyl methacrylate
Polymer coating materials in water supply systems
Reactive plasticizer
Comonomer for unmodified epoxy resins
Preparation of ion exchange resins,elastomers,solvents,plasticizers
Solvent for natural & synthetic resins,guns,cellulose esters & ethers
Solvent for lacquers,cement for celluloid
Solvent for paints,varnishes,nail enamels
Comonomer for polyamide-epichlorohydrin resins
Raw material for epoxy & phenoxy resins
Heat stabilizer for plastics
High wet-strength resins for paper industry
Chemical intermediate for polythiols
Cross-linking agent for hydrogel sheet for temporary wound dressing
Stabilizer in chlorine-containing material
Intermediate in the production of beta-blocker, aryloxypropanolamine
Hair products
In formation of polythioaldane carboxylic acid oligomers in hair shampoo
Cross-1 inking agent for cyclodextrins
Production of poly(oxlyalkylene)ether derivatives
Co-stabilizer to enhance mixed-metal combination
Cross-linking agent in microencapsulation
Chemical intermediate for alkyl glyceryl ether sulfonate surfactants
Raw material for glycerol and glycidol derivatives
Chemical, intermediate for glycidyl ethers,glycerin
Monomer or comonomer in epichlorohydrin elastomers
Sporicide
Chemical intermediate for quaternary ammonium salts
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
UOA1 (continued)
U042 2-Chtoroethyl vinyl ether
U043 Vinyl chloride
I
H-'
OJ
U044 Chloroform
U045 Chloromethane
Pesticides
Pharmaceuticals
Rubber
Fibers
Pharmaceuticals
Plastics
Textiles and Fibers
Adhesive and Sealants Industry
Automobile Manufacturing
Building and Construction
Electrical Equipment
Glass
Packaging
Paper
Plastics
Rubber
Rubber
Agricultural Chemicals
Insect fumigant
Stable insecticide emulsion
Manufacture of Pharmaceuticals
Curing propylene-based rubbers
Copolymer with ethyl acrylate to produce acrylic elastomer
Chemical intermediate for anesthetics, sedatives, t cellulose ethers
Monomer/comonomer for polyvinyl chloride
Monomer and comonomer for fibers
Chemical intermediate
Plastic adhesive
No information available
Production vinyl asbestos floor tiles
Insulation for electrical wire,cable,piping
No information available
Food, medical supplies
No information available
Organic synthesis of plastics
No information available
Solvent for fats, oils, rubber, alkaloids, waxes, resins
Cleaning agent
Fire extinguishers
Manufacturing of methyl cellulose
Manufacturing of tetramethylead
Methylat ing agent
Propellent
Herbicide
Manufacturing of fumigants
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
WASTECODE NAME
INDUSTRY
USE (a)
UOA5
(continued)
Pharmaceuticals
Plastics
Rubber
Steel
T inter
U046
Chloromethyl methyl ether
UOA7
U048
U049
U050
2-Chloronaphthalene
2-Chlorophenol
4-Chloro-o-toluidine hydrochloride Dyes and Pigments
Chrysene
U051
Creosote
Construction
Pharmaceutical
Organic Chemicals Manufacturing
Chemical Research
Medicine
Anesthetic
Foaming agent
Manufacturing of synthetic rubbers
Solvent and diluent in butyl rubber production
Production of silicone resins and rubbers
Foaming agent stainless steel
Processing of timber products
Extractant for oils, fats and resins
Fluid for thermometric ft thermostatic equipment
Chemical intermediate
Terminates polymerization of bakelite polysulfone
Industrial polymers
Alkylating agent ft solvent in manufacture of water repellents
Intermediate in synthesis of chloromethylated compound
Preparation of ion-exchange resins
Chemical intermediate for dodecylbenzyl chloride
No information available
No information available
Produce AZO dyes for cotton,si Ik,acetate,nylon
Chemical intermediate for dyes
In coal tar for road surfaces and roofing materials
Binder for electrodes in aluminum reduction process
Treatment of skin disorders
Waterproofing
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
Research chemical
Antipyretic, styptic, astringent
-------
WASTECODE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U051 (continued)
U052 Cresols
U053 Crotonaldehyde
U055
U056
Cunene (tsopropylbenzene)
Cyclohexane
U057
Cyclohexanone
Plastics and Resins
Veterinary Medicine
Pharmaceutical
Uood Preserving
Agricultural Chemicals
Organic Chemical Manufacturing
Plastics and Resins Manufacturing
Tire
Petroleum Refining
Agricultural Chemical Manufacturing
Military
Organic Chemical Manufacturing
Leather and Tanning
Organic Chemicals Manufacturing
Plastics and Resins
Paint
Laboratories
Organic Chemicals Manufacturing
Petroleum Refining
Organic Chemical Manufacturing
Plastics and Resins Manufacturing
Lubricant for die molds
Waterproofing agent
Parasiticide, deodorant
External antiseptic, disinfectant, expectorant, local anesthetic,
gastric sedative
Preservative
Herbicide manufacturing
Chemical intermediate for 2-ethylhexyl alcohol
Solvent for polyvinyl chloride
Preparation of rubber accelerators
Purification of lubricating oils
Manufacture of insecticides
Manufacture of tear gas
Organic synthesis
Leather tanning
Manufacture of phenol, acetone, acetophenone, a-methylstyrene
Solvent for lacquers and resins
Paint and varnish remover
Extraction of essential oils
Molecular weight determination
Manufacture of adipic acid, benzene, cyclohexyl chloride,
nitrocyclohexane, cyclohexanol, Cyclohexanone
Manufacture of solid fuel for camp stoves
In fungicidal formulations
In recrystatlization of steroids
Chemical intermediate in synthesis of caprolactam
Solvent for lacquers, wood stains, paint, and varnish removers
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
WASTECODE NAME
INDUSTRY
USE (a)
U057 (continued)
UOS9
U060
U061
U062
Daunomycin
DDD
DDT
Diallate
U063 Dibenzo(a.h)anthracene
U06A 1,2,7,8-Dibenzopyrene
U066 1.2-Dibromo-3-chloropropane
U067 Ethylene dibromide
Leather and Tanning
Pharmaceuticals
Pesticide
Pesticide
Agricultural Chemicals
Construction
Pharmaceutical
Organic Chemicals Manufacturing
Construction
Pharmaceutical
Organic Chemicals Manufacturing
Medical Research
Agricultural Chemicals
Agricultural Chemicals
Plastics and Resins
Solvent for polyvinyl chloride and its copolymers
Spot remover and degreaser for leather
Antineoplastic agent, antibiotic (not produced in U.S.)
Nonsystemic contact and stomach insecticide
Nonsystemic contact and stomach insecticide
Sprout inhibitor
Herbicide
In coal tar for road surfaces and roofing materials
Binder for electrodes in aluminum reduction process
Treatment of skin disorders
Waterproofing
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
In coal tar for road surfaces and roofing materials
Binder for electrodes in aluminum reduction process
Treatment of skin disorders
Waterproofing
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
Experimental carcinogen
Intermediate in organic synthesis
Commercial preparation for flame retardant
Soil fumigant for pineapple in Hawaii
Quarantine fumigant some fruits & veg.
Solvent for resins,gums,waxes
Chemical intermediate and in gauge fluids
Vault fumigation
-------
WASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE Of U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U067
(continued)
U068
U070
U071
U072
U073
U07A
U075
Oibromoroethane
1,2-DichIorobenzene
1.3-Dichlorobenzene
1,A-DichIorobenzene
3,3'-Dichlorobenzidine
1, A -0 i ch I oro- 2- butene
D i cht orodifluoromethane
Dyes and Pigments
Food Processing
Pesticides
Pharmaceuticals
T inter
Plastics and Resins
Pesticide
Pesticide
Dyes and Pigments
Plastics
Rubber
Organic Chemicals Manufacturing
Pesticide
Health and Safety
Catalyst in preparation of Grignard reagents
Chemical intermediate for vinyl bromide
Chemical intermediate for dyes
Spot fumigation milling machinery
Termite and Japanese beetle control
Insecticidal fumigant for stored products
Beehive supers
Soil treatment (insects and nematodes)
Chemical intermediate for Pharmaceuticals
Felled log fumigation
Organic synthesis
Gauge fluid
Ingredient of fire-estinquishing fluids
Heavy liquid in solid separations
Solvent for waxes & resins
Fumigant and insecticide
No information available
Manufacture of moth repellent, soil fumigant
Curing agent
Paint and ink formulation
Manufacture of AZO dyes
Chemical intermediate for dyes
Plastic compounding ingredient
Rubber compounding ingredient
Chemical intermediate for hexamethylenediamine and chloroprene
Nematocides and as chemical intermediate
Leak-detecting agent
Refrigerant
-------
WASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
=====S=S========S===SSSSC==3S»CSC======================SS=
INDUSTRY
USE (a)
U075 (continued)
oo
Plastics
Adhesive and Sealants Industry
Agricultural Chemicals
Automobile Manufacturing
Bottle Manufacturing
Cosmetics Manufacturing
Electrical Equipment
Food Processing
Food Processing
Food Service/Restaurant
Medicine
Metals Manufacturing
Organic Chemicals
Paint Manufacturing and Application
Paint Manufacturing and Application
Petroleum Refining
Pharmaceutical Manufacturing
Plastics
U076 1,1-Oichloroothane
Organic Chemicals Manufacturing
Polymerization catalyst
Aerosol propellent
Aerosol propellent
Refrigerant for air conditioning
No information available
Aerosol propellent
Manufacturing electrical insulation and generator windings
Solvent or diluent in fumigants for food sterilization
Freezing of foods
Chilling of glasses
Preparation of frozen tissue sections
Copper and aluminum purification
Synthesis of Freons
Used in paints & varnish removers
Aerosol propellant
Petroleum recovery
Aerosol propellant
Refrigerant in home & commercial applications
Used in polymerization process
Aerosol propellent in cleaners
Working fluid for heat pumps and in hydraulic fluids
Foaming agent for surfactants
Foaming agent in fire extinquishers
Water purification
Used in thermal expansion valves
Chemical intermediate for vinyl chloride, 1,1,1-trichloroethane
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
= SE= ====== = :=£=======E2SS=:=S=:=SS3SSSS8SSSSS= ========:=£= = =S====£=======
INDUSTRY
USE (a)
U077 1.2-Dichloroethane
U076 1.1-Dichloroethylene
U079 1.2-Dichloroethylene
U080 Nethylene chloride
U081
U082
U083
VO
UOM
U091
2,4-Dichlorophenol
2,6-Dichlorophenol
1,2-D i ch I oropropane
1,3-Dichloropropene
U085 1,2:3,4-Diepoxybutane
U089 Diethylstilbestrol
U090 Dihydrosafrole
3,3'-Dimethoxybenzidine
Plastics and Resins
Organic Chemicals Manufacturing
Food Processing
Organic Chemicals Manufacturing
Pesticide
Dry Cleaning
Pesticide
Dry Cleaning
Pesticide
Commercial Testing Laboratories
Pharmaceuticals/Medicine
Flavor
Cosmetics and Fragrances
Tanning, Paper, Rubber, Textiles
Solvent for fat and oils
Solvent for waxes, gum, resins
Funigant
Intermediate for vinilydene polymer plastics
Solvent for fats, phenol, camphors
Solvent for cellulose acetate
Degrees ing and cleaning fluids
Solvent
Organic synthesis
Systemic herbacide
Oil and fat solvent
In dry cleaning fluids
In degrees ing
Insecticidal funigant mixtures
Oil and fat solvent
In dry cleaning fluids
In degreesing
Insecticidal funigant mixtures
Research chemical
No longer used
Chemical intermediate for piperonyl butoxide (not in U.S.)
Flavoring agent in root beer
Fragrance for cosmetics
Detection of thiocyanates, nitrites, & some metals
Dye
Chemical intermediate in production of 0-dianisidine diisocyanate
-------
UASTECODE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U091 (continued)
U092 Dimethylamine
r
NJ
O
Dyes and Pigments
Dyes and Pigments
Detergents
Pharmaceuticals
Petroleum Refining
Agricultural Chemicals
Textiles
Pesticides
Plastics and Resins
Film
Leather and Tanning .
Rubber
U093 p-Dimethylaminoazobenzene
Chemical intermediate in dyes and pigments
Reagent for magnesium
Missile fuel
Dyes
Ion exchange agent
Chemical intermediate for lauryl dimethylamine oxide
Manufacture of detergents
Surfactant
No information available
Antiknock agent in fuels
Gasoline stabilizer
Attract boll weevils
Antioxidants
Dehairing agent
Textile chemicals
Electroplating
Acid gas absorbent
Flotation agent
Pesticide propellent
Chemical intermediate for dimethylformamide.dimethylacetamide
Plasticizer
Rocket propellent
Dimethylamine salt of 2,4-D
Photographic chemical
Tanning
Accelerator in vulcanizing rubber
Not produced or used in U.S.
-------
WASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
S====S==S==SSSSSS=SasS3S3&X2SCE=S===SS==S==S
INDUSTRY
USE (a)
U094 7.12-Dimethylbenz(a)anthracene
U09S 3.3'-Dimethylbenzidine
to
U097 Dimethyl carbonyl chloride
U101 2,4-Dimethyl phenol
U105 2.4-Dinitrotoluene
Construction
Pharmaceutical
Organic Chemicals Manufacturing
Medical Research
Dyes and Pigments
Plastics and Resins
Pesticides
Pesticide
Dyes and Pigments
Explosives
Munition
Plastics and Resins
Rubber
U106 2,6-Dinitrbtoluene
In coal tar for road surfaces and roofing materials
Binder for electrodes in aluminum reduction process
Treatment of skin disorders
Waterproofing
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
Induces malignant tumors in testing of antineoplastic drugs
Free chlorine in water
Reagent for gold detection
In chlorine test kits I test tapes in clinical laboratories
Chemical intermediate for AZO dyes
Curing agent for urethane resins
Chemical intermediate for parasympathomimetic agents
Pesticide (former use)
Insecticide, fungicide
Chemical intermediate for dyes
Production of toluenediamine (Ramey nickel slurry process)
Chemical intermediate in production of toluene diisocyanate
Added to sensitizing materials in dynamite
Plasticizer in moderate and high explosives
Gelatinizing & waterproofing agent
Explosives intermediate
Modifier'for smokeless powders
Plastics manufacture
Rubber chemical
Chemical intermediate for toluene-2,2-diamine
Synthesis of urethane polymers, flexible & rigid foams
-------
WASTECODE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
SSS=ES&S=SS=S=S3SSCSSSS==SSSB8SSSS==EKSS===SS
INDUSTRY
USE (a)
U106 (continued)
U108 1,4-Dioxane
to
ro
U110 Oipropylamine
U111 Oi-n-propylnitrosamine
U112 Ethyl acetate
Dyes and Pigments
Explosives
Plastics and Resins
Cosmetics and Fragrances
Paint Manufacturing
Paper Processing
Dyes and Pigments Manufacturing
Cleaning Products
Organic Chemical Manufacturing
Plastics and Resins Manufacturing
Agricultural Chemicals
Organic Chemical Manufacturing
Medicine
Food Processing
Plastics and Resins Manufacturing
Printing
Paint Manufacturing
Munitions
Film
In dyes
In synthesis of TNT
Gelatinizing and waterproofing agent in explosives
Surface coatings
Manufacture of cosmetic products
Manufacture of lacquers, paints, varnishes, paint
Solvent in pulping of wood
Wetting and dispersing agent in textile
processing, dye-baths, stain and printing
compositions
Manufacture of cleaning and detergent preparations,
adhesiyes, fumigants, emulsions, and polishing
compositions
Solvent for fats, oils, waxes
Solvent for natural and synthetic resins
Purification of perfIuoro-compounds
Chemical intermediate for S-propyl-di-n-propylthiocarbamate
Chemical intermediate for herbicide S-ethyl-di-n-propylthiocarbamate
Research chemical
Organic synthesis
Carminative, antispasmodic, and counterirritant
Component of base sheet (cellophane)
Diluent in inks for marking fruits and vegetables,
synthetic flavoring
Solvent for plastics
Solvent for inks
Solvent for varnishes, lacquers
Manufacture of smokeless powder
Manufacture of photographic films and plates
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
====SZCS33=SSS=S===SSSSS8ECa*SSSZ===S==E=3==
INDUSTRY
USE (a)
U112
U113
(continued)
Ethyl acrylate
KJ
OJ
U114
U116
Ethylene bis-dithiocarbaraic acid
Ethylene thiourea
U117
Diethyl ether
Leather and Tanning
Cosmetics and Fragrances
Paint Manufacturing
Textiles
Paper Coating
Cleaning Products
Adhesives and Sealants
Leather and Tanning
Food Processing
Agricultural Chemicals
Agricultural Chemicals
Dyes and Pigments
Pesticides
Pharmaceuticals
Plastics and Resins
Rubber
Organic Chemical Manufacturing
Cosmetics and Fragrances
Explosives
Automotive
Commercial Testing Laboratories
Veterinary Medicine
Manufacture of artificial leather
Manufacture of perfumes and fragrances
Emulsion polymers for trade sale paints
Textile coating and printing
Paper coatings
Floor finishes
Emulsion polymers for adhesives and sealants
Leather finishes
Synthetic flavorings
Heavy metal salts as fungicides
Electroplating baths
Intermediate for antioxidants
Intermediate for fungicides
Intermediate for dyes
Intermediate for insecticides
Intermediate for Pharmaceuticals
Manufacture of synthetic resins
Accelerator for neoprene rubbers
Solvent for waxes, fats, and oils
Reagent for organic synthesis
Chemical intermediate for monoethanolamine, ethylene
Solvent for perfumes
Manufacture of gun powder
Primer for gasoline engines
Extractant of hormones from plant and animal tissues
Inhalation anesthetic, antispasmodic, rubefacient
-------
UASTECODE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U118 Methacrylic acid, ethyl ester
U119 Ethyl methane sulfonate
U120 Fluoranthene
f
U121
FIuorot r i chIoromethane
Plastics and Resins Manufacturing
Cleaning Products
Pharmaceutical Manufacturing
Biochemical Research
Construction
Pharmaceutical
Organic Chemicals Manufacturing
Chemical Research
Agricultural Chemicals
Cosmetic and Fragrance
Electrical Equipment
Food Processing
Organic Chemicals
Paint Manufacturing and Application
Pharmaceuticals
Comonomer in acrylic polymers for surface coating resins
Acrylic emulsion polymers for polishes
Comonomer in denture base material
Not produced in U.S.
In coal tar for road surfaces and roofing materials
Binder for electrodes in aluminum reduction process
Treatment of acute and chronic dermatoses
Waterproofing
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
In lining for steel and ductile iron potable water pipes and storage
tanks
Research chemical
Sulfonation solvent in chemical synthesis
Dielectric fluid in bubble chambers in wind tunnels
Aerosol propellent
Blowing agent in production of polyurethane foam
Production of polymeric resins
Chemical intermediate
Aerosol propellant
Aerosol propellent
Electric insulation
No information available
Manufacture cleaning compounds
Aerosol propellent
Aerosol propellant
Manufacture fire extinquishers
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
cr£c=s===scc=s===s==s=s==sss£sccsss====zr===
INDUSTRY
USE (a)
U121 (continued)
U122 Formaldehyde
U123 Formic acid
Plastics and Resins Manufacturing
Organic Chemical Manufacturing
Tire
Medicine
Dyes and Pigments Manufacturing
Leather and Tanning
Explosives
Agriculture
Agricultural Chemical Manufacturing
Paint Manufacturing
Textiles
Organic Chemical Manufacturing
Cosmetics and Fragrances
Medicine
Fiber Manufacturing
Aerosol propellent (floor waxes)
Refrigerant
Solvent and degreesing agent
Chemical intermediate for phenolic, polyacetal
and melamine resins
Chemical intermediate for resorcfnol-formaldehyde
and aniline-formaldehyde resins
Chemical intermediate for acetylenic chemicals,
(1,4-butanediol), polyols (pentaerythritol),
hexamethylenetetramine, methylene dianiline,
pyridine chemicals, nitroparaffin derivatives
Chemical intermediate for rubber processing chemicals
Disinfectant
Embalming agent
Component of dyes as starch preservative
Chemical intermediate for synthetic tanning agent
Chemical intermediate for explosives
Soil sterilant in mushroom houses before planting
Manufacture of fumigants, insecticides
Manufacture of comnercial paint strippers, lacquers
Dyeing and finishing of textiles
Preparation of organic esters
Manufacture of refrigerants
Solvent for perfumes
Antiseptic
Silvering glass
Cellulose formate
Ore floatation
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
UASTECOOE NAME
INDUSTRY
USE (a)
U123 (continued)
U124 Furan
U125 Furfural
>
ho
U126 Glycidylaldehyde
U127 Hexachlorobenzene
U128 Hexachlorobutadiene
U129 Lindane
U130 Hexachlorocyclopentadiene
U131 Hexachloroethane
Plastics and Resins Manufacturing
Leather and Tanning
Organic Chemical Manufacturing
Organic Chemical Manufacturing
Petroleum Refining
Adhesives and Sealants
Food Processing
Plastics and Resins Manufacturing
Medicine
Paint Manufacturing
Agricultural Chemical Manufacturing
Automotive
Commercial Testing Laboratories
Wool Weaving and Finishing
Leather and Tanning
Medicine
Pesticide
Rubber
Pesticide
Pesticide Manufacturing
Explosive
Manufacture of vinyl resin plasticizers
Leather tanning
Chemical intermediate for tetrahydrofuran
Organic synthesis for pyrrole, thiophene
Solvent in extraction of butadiene from C4 streams
Refining of lubricating oils
Constituent of rubber cement
Synthetic flavoring ingredient
Solvent for synthetic and natural resins
Screening test for urine
Manufacture of varnishes
Insecticide, fungicide, germicide
Wetting agent in the manufacture of abrasive
uheels and brake linings
Research chemical
Cross-1 inking agent for finishing of wool
Oil tanning and fat-liquoring of leather
Oil tanning and fat-liquoring of surgical sutures
Protein insolubilization
Chemical intermediate in glycerol manufacture
Fungicide
Solvent for rubber
Insecticide
Chemical intermediate for aldrin. dieldrin, endrin, endosulfan,
chlordane, heptachlor, isodrin
Solvent
Explosives
-------
==£=========;:====================::
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
=s=s=ss==s==r=====s=s==3ss=s«»ssces=r========
INDUSTRY
USE (a)
U131 (continued)
U132 Hexachlorophene
U137 ldeno(1.2,3-c.d)pyrene
U138 lodomethane
UUO Isobutyl alcohol
Rubber
Soap
Cosmetics
Construction
Pharmaceutical
Organic Chemicals Manufacturing
Chemical Research
Pharmaceuticals
Food Processing
Plastics and Resins Manufacturing
Cosmetics and Fragrances
Pharmaceutical Manufacturing
Camphor substitute in celluloid
Vulcanizing accelerator
In soap and germicide I preparations
In cosmetic preparations
In coal tar for road surfaces and roofing materials
Binder for electrodes in aluminum reduction process
Treatment of acute and chronic dermatoses
Waterproofing
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
Research chemical
Chemical intermediate for me thyIamines & quarternary ammonium iodides
Chemical intermediate for for phosponium iodides
Chemical intermediate for organometalIics
Alkylating agent
Methylating agent in prep, pharmaceutical intermediates
Microscopy
Building block for radioactive tracers synthesis
Testing for pyridine
As imbedding material of diatom examination
As fire extinquisher
Manufacture of food additives
Solvent for surface coatings and adhesives
Chemical intermediate for isobutyl esters used
as plasticizers
Manufacture of perfumes
Processing solvent for Pharmaceuticals
-------
WASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
UKO (continued)
UU1 Isosafrole
>
CO
UU3 Lasiocarpine
U147 Naleic anhydride
UU8 Maleic anhydride
Agricultural Chemical Manufacturing
Organic Chemical Manufacturing
Petroleum Refining
Flavor
Cosmetic and Fragrance
Medicine
Organic Chemical Manufacturing
Plastics and Resins Manufacturing
Dyes and Pigments Manufacturing
Pharmaceutical Manufacturing
Agricultural Chemical Manufacturing
Petroleum Refining
Agricultural Chemicals
Processing solvent for pesticides
Chemical intermediate for isobutyIamines, zinc
diisobutyldithiophosphate, isobutyI acetate,
acrylate and methacrylate esters
Diluent-reagent in the alkylation of amino resins
Cosolvent in tertiary oil recovery
Chemical intermediate for isobutyI esters used
as plasticizers
In root beer (former use) and sarsaparilla flavors
Manufacture heliotropin
Chemical intermediate for dihydrosafrole (not in U.S.)
Manufacture pesticide synergists
Modify oriental perfumes
Research chemical
Diene syntheses, co-polymerization reactions
Chemical intermediate for fumaric acid, malic acid
. Chemical intermediate for surfactants, chlorendic
anhydride and acid, rosin adducts
Manufacture of alkyd-type resins, reactive plasticizers
Comonomer for unsaturated polyester resins
Manufacture of dye intermediates
Manufacture of Pharmaceuticals
Manufacture of agricultural chemicals
Chemical intermediate for lube oil dispersants
and corrosion inhibitors
Synthesis of pyridazine
Uracil antimetabolite
Weed control in mixture with 2,4-0
Inhibits plant growth (tobacco, potato & onions)
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
=S=========S===S==SS£S5S==SC3£SSC£==S==£===r£
INDUSTRY
USE (a)
UU8 (continued)
UH9 Nalonitrile
> U150 Melphalan
!o U1S2 Methacrylonitrile
U153 Nethanethiol
Medicine
Lubricant
Medicine
Medicine
Medicine
Plastics and Resins
F(avor
Agricultural Chemicals
Pesticides
Petroleum Refining
Plastics and Resins
U154 Methyl alcohol
Sugar content stabilizer in beets
Fungicidal
Photosensitizer
Formerly used to treat mental illness
Acrylic fiber and dyestuff synthesis
Organic synthesis
Lubricating oil additive
Leaching agent for gold
Thfamine synthesis
Anti-cancer agent synthesis
Antineoplastic agent
Preparation of homopolymers & copolymers
Intermediate in preparation of acids, amides, amines, esters, nitriles
Monomer for copolymers
Monomer for polymethacrylonitrile
Manufacture of elastomers, coatings, plastics
Synthetic flavoring and adjuvants
Synthesis of methimine
Synthetic flavoring substances and adjuvants
Catalyst
Gas odorant for hazardous gases
Synthesis of methimine
Intermediate in fungicides
Intermediate in pesticide manufacture
Intermediate in jet fuels manufacture
Intermediate in plastics manufacture
Kill animal pathogenic bacteria and maggots on
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
WASTECOOE NAME
INDUSTRY
USE (a)
U154 (continued)
U155 Methapyrilene
U1S6 Methyl chlorocarbonate
U157 3-Methylcholanthrene
Agricultural Chemicals
Petroleum Refining
Printing
Pharmaceuticals
Veterinary Medicine
Pesticides
Construction
Pharmaceutical
Organic Chemicals Manufacturing
Medical Research
U158 4,4-Methylene-bis-(2-chloroaniline)
U159
Methyl ethyl Ice tone
Munitions
Aircraft
Plastics and Resins Manufacturing
Paint Manufacturing
Cement
household contents, mortuary instruments, human
bedding and clothing, tissues, human stools,
and cadavers
Treatment against onion smut, dutch elm disease.
and wood root
Removal of toxic organic pollutants from soil
Kill slime forming bacteria in oil recovery
injection water and packer fluid
Duplicating fluid
Removal of 2,4-dinitrotoluene from spent carbons
Sedative in sleeping aids
Antihistaminic
Antihistaminic agent
In organic synthesis
In insecticides
In coal tar for road surfaces and roofing materials
Binder for electrodes in aluminum reduction process
Treatment of acute and chronic dermatoses
Waterproofing
Electrical insulation, pipe coating, sound insulation
Synthesis of organic chemicals
Induces specific forms of cytochrome in cancer research
Components in home appliances
Manufacture of radar systems
Manufacture of gun mounts
Manufacture of jet engine turbine blades
Curing agent
Manufacture of paint removers
Manufacture of cements
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
WASTECOOE NAME
INDUSTRY
USE (a)
U159 (continued)
U161 Methyl isobutyl ketone
U162 Methyl methacrylate
U163 H-Hethyl,N-nitro-,N-nitroguanidine
U164 Methylthiouracil
U165 Naphthalene
Adhesives and Sealants'
Cleaning Products
Organic Chemical Manufacturing
Building Products
Magnetic Tape
Printing
Agricultural Chemical Manufacturing
Medicine
Pharmaceutical Manufacturing
Paint Manufacturing
Organic Chemical Manufacturing
Dry Cleaning
Food Processing
Organic Chemical Manufacturing
Medicine
Human/Veterinary Medicine
Organic Chemicals Manufacturing
Plastics and Resins
Manufacture of adhesives
Solvent for adhesives
Cleaning fluids
Organic synthesis
'Oxidation promoter in manufacture of terephthalic
acid from p-xylene
Solvent for coatings
Solvent for magnetic tape
Solvent for printing inks
Solvent for cosolvent in pesticide formulations
Sterilizer for baterial spores on surgical instruments,
hypodermic needles/syringes, and dental instruments
Denaturant for rubbing alcohol
Manufacture of antibiotics
Solvent for paints, varnishes, cellulose lacquer
Manufacture of methyl amyl alcohol
Organic synthesis, extraction processes
Manufacture of dry cleaning preparations
Manufacture of synthetic flavoring substances
Monomer for polymethyl methacrylate, comonomer
for copolymers
Chemical intermediate for higher methacrylate esters
Laboratory preparation of diazomethane (former use)
Research chemicals
Anti-thyroid agent (Not produced in U.S.)
Manufacture of phthalic and anthranilic acids, naphthols,
naphthylamines, sulfonic acid
Manufacture of synthetic resins
Manufacture of cellulowid, lampblack, smokeless powder
Preparation of anthiaquinone
-------
=====================
WASTECODE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
ss=ssss=s=s==s:sssassssss8ssvsas5ssss=====s=s==sss====ssr=====
INDUSTRY
USE (a)
U165
(continued)
U166 1,4-Naphthoquinone
f
U167 1-Naphthylamine
U168 2-Naphthylamine
Dyes and Pigments
Pesticide
Leather and Tanning
Veterinary Medicine
Tire
Plastics and Resins Manufacturing
Dyes and Pigments Manufacturing
Pharmaceutical Manufacturing
Agricultural Chemical Manufacturing
Dyes and Pigments
Pesticides
Pesticides
Rubber
Dyes and Pigments
Rubber
Rubber
U169 Nitrobenzene
• Manufacture of indigo
Formation of perylene
Chemical intermediate for 1-naphthyl-n-methyl carbonate insecticide
Chemical intermediate for beta-naphthol and synthetic tanning chemicals
Chemical intermediate for naphthalene sulfactants
Insecticide, antiseptic, vermicide
Ingredient in moth repellent and toilet bowl deodorants
Manufacture of hydronaphthalenes used as solvents in lubricants and
motor fuels
Polymerization regulator for rubber
Polymerization regulator for polyester resins
Synthesis of dyes
Synthesis of Pharmaceuticals
Algicide
Chemical intermediate for imidazoline adrenergic agent
Chemical intermediate for N-1-Naphthylphthalmic acid herbicide
Toning prints made with cerium salts
Chemical intermediate for dyes
Chemical intermediate for 1-Naphthylthiourea rodenticide (former use)
Chemical intermediate for fluoroacetamide miticide (former use)
Chemical intermediated for N-Phenyl-1-Naphthylemine rubber antioxidant
Production 2-chloronaphthylamine
Former chemical intermediate for dyes
Former chemical intermediate for rubber antioxidants
Formerly in manufacture of rubber
Solvent
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
SSSS=SS=SSS=S=S=3S==SS3SSSSCSSS=3SSSSS
INDUSTRY
USE (a)
U169 (continued)
LO
U)
U170
U171
4-Nitrophenol
2-Hitropropane
Jewelry
Plastics and Resins
Food
Pesticides
Pharmaceuticals
Rubber
Pesticide
Paint and Varnish
Dyes and Pigments
Munitions
Ingredient of metal polishes
Manufacture pyroxylin compound
Preservative in spray paints
Solvent for cellulose ethers
Chemical intermediate for aniline, dichloroanilines
Refining lubricating oils
In soaps, shoe polishes
Substitute for almond essence
Production of isocyanates
Modifying esterification of cellulose acetate
Constituent of floor polishes
Production of pesticides
Production of Pharmaceuticals (acetominophen)
Production of rubber chemicals
Production of parathion, fungicide
Paint and varnish removal
Chemical intermediate for 2-Amino-2-methyl-1-propanol
Increase wetting ability & electrostatic spraying properties
Solvent for chemical reactions
Provide better flow characteristics & film integrety
Chemical synthesis
Insure greater pigment dispersion
Co-solvent for coatings, ink, & adhesives
Insure more complete solvent release
Rocket propellent
Improve drying time in solvent systems
-------
UASTECCOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
ssse=sscsss:s2ssssscssass3csssassssas:ss=s:sss=C
INDUSTRY
USE (a)
U171
U172
U173
U174
(continued)
N-Nitroso-di-n-butylamine
N-Nitroso-diethanolamine
N-Nitrosodiethylemine
U176 N-Nitroso-N-ethylurea
U177 N-Nitroso-N-methylurea
U178 N-Nitroso-N-methylurethane
U179 N-Nitrosopiperidine
U180 N-Nitrosopyrrolidine
U101 5-Nitro-o-toluidine
U182 Paraldehyde
Coating
Coating
Dyes and Pigments
Pesticides
Petroleum Refining
Pharmaceuticals
Research
Research
Research
Petroleum Refining
Research
Research
Research
Research
Dyes and Pigments
Organic Chemical Manufacturing
Dyes and Pigments Manufacturing
Processing solvent for extractions and separations
Acid-proof lacquer on battery cases
Solvent systems
Intermediate in synthesis of dyes
Intermediate in synthesis of insecticides
Racing car fuel
Gasoline additive
Smoke depressant in diesel fuel
Intermediate in synthesis of Pharmaceuticals
Research chemical
Researh chemical
Research chemical
Stabilizer
Antioxidant
Gasoline and lubricant additive
Research chemical
Laboratory preparation of diazoethane
Mutagenic effects on various plants
Laboratory synthesis of diazomethane
Laboratory synthesis of diazomethane
Research chemical
Research chemical
Research chemical
Chemical intermediate for pigments and dyes
Substitute for acetaldehyde
Solvent for fats, oils, waxes
Manufacture of dyestuff intermediates
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
WASTECODE NAME
INDUSTRY
USE (a)
U182 (continued)
U183 Pentachtorobenzene
U184 Pentachloroethane
>
CO
I/I
U18S
U186
U187
U188
U191
Pentachloroni trobenzene
1,3-Pentadiene
Phenacetin
Phenol
2-Picoline
U192 Pronamide
U193 1.3-Propane sulfone
U194 n-Propylamine
Plastics and Resins Manufacturing
Leather and Tanning
Fiber Manufacturing
Coal
Agricultural Chemicals
Organic Chemicals Manufacturing
Lumber
Agricultural Chemical
Hair Products
Pharmaceuticals/Veterinary Medicine
Dyes and Pigments
Plastics and Resins
Agricultural Chemical
Textiles
Dyes and Pigments
Pesticides
Solvent for guns, resins
Manufacture of leather
Mixtures for cellulose derivatives
No information available
Solvent for oil and grease in metal cleaning
Separation of coal from impurities
Soil sterilization
Solvent for cellulose acetate, cellulose esthers. resins
Drying agent for timber
Fungicide
Manufacture of synthetic rubber
Stabilizer for hydrogen peroxide in hair bleaching preparation
Analgesic and antipyretic
Disenfectant
Chemical intermediate for 2-chloro-6-(trichloromethyl)pyridine
Organic intermediate for Pharmaceuticals,rubber chemicals
Chemical intermediate for 2-vinylpyridine, herbicide picloram.amprolium
Intermediate
Intermediate
Herbicide for vegetables
Confer water solubility and anionic character
Chemical intermediate to sulfopropyl group
Chemical intermediate for textile resins
Chemical intermediate for propyl isocyanate
Chemical intermediate for dyes
Chemical intermediate for pesticides
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
UASTECODE NAME
U194 (continued)
U196 Pyridine
INDUSTRY
USE (a)
>
to
Petroleum Refinining
Pharmaceuticals
Rubber
Pharmaceuticals
U197 1,4-Benzoquinone
Agricultural Chemicals
Dyes and Pigments
Explosives
Food Products
Paint Manufacturing
Petroleum Refining
Plastics and Resins
Rubber
Textiles
Agricultural Chemical Manufacturing
Chemical intermediate for petroleum additives
Chemical intermediate for drugs
Chemical intermediate for rubber chemicals
Solvent reaction medium or catalyst in carbohydrate treatment
In organic synthesis and analytical chemistry
As an inhibitor & preparation of inhibitor
Manufacture vitamins,sulfa drugs,disinfectants
Chemical intermediate for antihistamines
Manufacture of stimulants,local anesthetics
Solvent in drug manufacture
Chemical intermediate for diquat 4 paraquat, piperidine
Solvent for anhydrous mineral salts
To denature alcohol & antifreeze mixtures
Reduces nitrogen oxide in flue gas
Synthesis of piperidine
Reagent
Manufacture fungicides
Manufacture dyestuffs
Manufacture explosives
Useful in seafood, smoke falvor, chocolate
Solvent reaction medium or catalyst in paint manufacture
In oil and gas well drilling
Solvent in manufacture of polyurethane resins
No information available
Chemical intermediate for water-proofing agents in textiles
Manufacture of fungicides
-------
5===SS=======S==
UASTECODE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U197
(continued)
U200
U201
Reserpine
Resorcinol
Saccharin
U203 Safrole
U206 Streptozatocin
Organic Chemical Manufacturing
Film
Leather and Tanning
Cosmetics and Fragrances
Pharmaceuticals
Leather and Tanning
Explosives
Dyes and Pigments
Plastics and Resins
Animal Food Products
Electroplating
Food Products
Adhesives and Sealants
Cosmetics
Pesticides
Pharmaceuticals
Medicine
Veterinary Medicine (Research)
Analytical reagent, oxidizing agent
Determination of amino acids by the formation
of red charge-transfer complexes
Photography
Tanning hides
Transform nitrogen containing-compounds into
colored substances
Medication
In tanning
Manufacture of resins
Cattle feed additive
Electroplating bath additive
Non-caloric synthetic sweetener -- food, gun, toothpaste, smokeless
tobacco, etc.
Chemical intermediate for heliotropin
Chemical intermediate ofr isosafrole
Manufacture of piperonyl butoxide
As preservative in mucilage and library paste
Fragrance for cosmetics
Pediculicide
Flavoring agent for drugs, topical antiseptic
Carminative
Antineoplastic agent in cancer treatment
Experimental use in diabetes & as antimicrobial agent
Diabetogenic agent
U207 1,2,4,5-Tetrachlorobenzene
No information available
-------
UASTECODE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U208 1,1,1,2-Tetrachloroethane
U209 1,1,2.2-Tetrachloroethane
U)
oo
U210 Tetrachloroethylene
U211 Carbon tetrachloride
U213 Tetrahydrofuran
Plastics and Resins
Agricultural Chemicals
Medical Research
Organic Chemicals Manufacturing
Plastics and Resins
Agricultural Chemicals
Medical Research
Organic Chemicals Manufacturing
Dry Cleaning
Dry Cleaning
Automobile
Pesticide
Organic Chemicals Manufacturing
Food Processing
Plastics and Resins Manufacturing
Organic Chemical Manufacturing
Nonflammable solvent for fats, oils, waxes, resins, cellulose acetate,
rubber, phosphorous, sulfur
Manufacture of paint, varnish, and rust removers
Soil sterilization, weed killer, and insecticide formulations
Immersion fluid in crystallography
Provide pathological changes in gastrointestinal tract, liver, kidneys
Chemical intermediate for trichloroethylene, halogenated hydrocarbons
Nonflammable solvent for fats, oils, waxes, resins, cellulose acetate,
rubber, phosphorous, sulfur
Manufacture of paint, varnish, and rust removers
Soil sterilization, weed killer, and insecticide formulations
Immersion fluid in crystallography
Provide pathological changes in gastrointestinal tract, liver, kidneys
Chemical intermediate for trichloroethylene, halogenated hydrocarbons
Degrees ing metals
Solvent
Fire extinguisher
Cleaning clothing
Azeotropic drying agent for wet spark plugs
Solvent for oils, fats, lacquers, varnishes, rubber, waxes, resins
Extracting oil from flowers, seeds
Insecticide
Starting material for organic compounds
Indirect food additive for food contact surface
of articles intended for use in food processing
Solvent for resins and plastics
Chemical intermediate for polytetramethylene
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
==========
UASTECODE NAME
INDUSTRY
USE (a)
U213 (continued)
U218 Thioacetamide
u>
VO
U219 Thiourea
Magnetic Tape
Cleaning Products
Printing
Leather, Textiles, Paper
Medicine
Rubber
Cosmetics
Paper Manufacturing
Wood Preserving
Paper
Adhesives and Sealants
glycol, tetrahydrothiophene
Solvent for top coating solutions, protective
coatings, coating magnetic tapes
Solvent for cleaning
Agent in liquid membrane electrode manufacturing
Polymerization solvent
Solvent for print inks
Solvent for production of tetraethyl and
tetramethyl lead
Solvent
Stabilizer for fuel with tetraethyllead
Substitute for Hydrogen sulfide in labs
Solubilizer for riboflavin
Analytical reagent
Accelerator for buna rubber
Removal of mercury from wastewaters
In hair preparations
Preparation of non-glare mirrors
In paper whiteners
Stain prevention of hemlock wood
In scrub soln for waste gas containing NO(X)&SO(X)
Stabilizer for diazo coating solns for copy film & paper
Reagent for bismuth, selenite ions
Liquifier/peptizing agent for glue
In dry-cleaning chemicals
Chelating agent
Synthesis of sulfthiazote
-------
s==s==ss======: =:===::===:====
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
U219
(continued)
£•
o
U220 Toluene
Textiles
Agricultural Chemicals
Dyes and Pigments
Photography
Pesticides
Pharmaceuticals
Plastics and Resins
Textiles
Veterinary Medicine
Organic Chemicals Manufacturing
Explosives
Dyes and Pigments
Food
Medicine
Cosmetics and Fragrance
Catalyst in isomerization of maleic to fumaric acid
Intermediate for S-lodo-2-thiouracil
In cleaning and plating baths for metals
Manufacture of fire retardant for lacy fabrics
Metal corrosion inhibitor for pickling solutions
Radioprotector in X-irradiated mice
Reduces interferences for analysis of cadmium
Vulcanization accelerator
In mineral oil
Fungicide
Sprout accelerator in dormant tubers
Dye intermediate
Photographic fixing agent and remove stains from negatives
Complexing agent for color print photography
Synthesis of insecticides
Synthesis of Pharmaceuticals
Manufacture of resins
In-boiler water treatment
Flame-proofing agent for nylon
Weighting agent for silk
Experimentally as thyroid inhibitor or goitrogen
Medication
Manufacture of benzoic acid, benzaldehyde
Manufacture of explosives
Manufacture of dyes
Manufacture of caprolactam
Manufacture of saccharin
Manufacture of medicines
Manufacture of perfumes
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
UASTECODE NAHE
INDUSTRY
USE (a)
U220 (continued)
U222 o-Toluidine hydrochloride
U225 Bromoform
U226 1.1,1-Trichloroethane
U227 1,1,2-Trichloroethane
U228 Trichloroethylene
Toy Manufacturing
Plastics and Resins
Petroleum Refining
Dyes and Pigments
Organic Chemicals Manufacturing
Ai rcraft/Aerospace
Pharmaceuti cals
Rubber
Shipbuilding
Adhesive solvent in plastic toys end model airplanes
Solvent for paints, lacquers, gums, resins
Extraction of various principals from plants
Gasoline additive
Chemical intermediate for dyes
Ingredient in fire-resistant chemicals
Chemical intermediate for organic synthesis
Solvent.in liquid-solvent extractions
Flotation agent in sedimentary petrographical surveys
Catalyst/sensitizer in polymer reactions
Solvent for waxes,greases,& oils
Flotation agent in purification of materials (quartz)
Flotation agent in mineral separation
In gauge fluid
Reagent for graphite ore fractionation
Solvent in nuclear magnetic resonance studies
No information available
Sedative
Synthesis of Pharmaceuticals
Catalyst/sensitizer in vulcanization of rubber
No information available
Cold-type'metal cleaning
Cleaning plastic molds
Solvent for fats, waxes, natural resins, alkaloids
Solvent for fats, waxes, resins, oils, rubber, paints,
varnishes, cellulose esters and ethers
Solvent extraction
-------
WASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
S£==S==SSS3==55=SS5SS&S=BaSS3SSSSS5===SS===SS
INDUSTRY
====:= ============3
USE (a)
>
N)
U228 (continued)
U234 sym-Trinitrobenzene
U236 Trypan blue
U237 Uracil Mustard
U238 Ethyl carbamate
U239 Xylenes
Dry Cleaning
Organic Chemicals Manufacturing
Pharmaceutical
Explosives
Rubber
Dyes and Pigments
Medicine
Medicine
Medicine
Agricultural Chemicals
Biochemical Research
Cosmetics
Pesticides
Pharmaceuticals
Textiles
Veterinary Medicine
Organic Chemicals Manufacturing
Textile and Fiber
Degreesing
Acid-base indicator for 12.0-14.0 pH
Explosive
Vulcanize natural rubber
Biological stain
Dye for textiles,leather,paper
Therapeutic agent for sleeping sickness
Antineoplastic agent (essentially obsolete drug)
Formerly as adjunct to sulfonamide therapy
Preparation and modification of amino resins
Anti-neoplastic agent
Solvent for barious organic materials
Solubilizer and co-solvent for fumigants
No information available
Solubilizer and co-solvent
Solubilizer and co-solvent
Formerly topical bactericide
Formerly component sclerosing soln for varicose veins
Intermediate for Pharmaceuticals
Chemical intermediate for N-hydroxymethyl derivatives
Anesthetic, hypnotic, sedative, diuretic
As a solvent
Raw material in production of benzoic acid, phthalic anhydride,
isophthalic and terephthalic acids
Manufacture of polyester fibers
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
=S=S==SS==S3SSSSSSBSSSS3BSS8SSS8SSS=:=========
INDUSTRY
USE (a)
U239 (continued)
U240 2.4-D, Salts and esters
U243 Hexachloropropene
U244
Thiram
to
Dyes and Pigments
Laboratories
Pesticide
Plastic and Resin
Agricultural Chemicals
Wood Preserving
Food Products
Rubber
Paper
Pharmaceuticals
Agricultural Chemicals
Manufacturing dyes
Sterilizing catgut
With Canada'balsam as oil-immersion in microscopy
Cleaning agent in microscope techniques
Systemic herbicide
Solvent
Plasticizer
Hydraulic fluid
Preparation of uranium tetrachloride
Production of monochloropentene
Peptizer for polysulfide elastomer
Fungicide for industrial textiles
Preservative
Activator for guanidine,amine,& thiazole cure systems
Mushroom disinfectant
Antioxidant in polyolefins
Vulcanizing agent for rubber
Accelerator for natural & isoprene rubbers,etc.
Fungicide for use on paper, polyurethane foam products
Bacteriostat in soap and antiseptic sprays
Activator for sulfenamide accelerators
Fungicide for seed treatment
Animal repellent for trees and shrubs
U247 Methoxychlor
U2A8 Warfarin
P001 Warfarin
Pesticide
Agricultural Chemical Manufacturing
Medicine
Agricultural Chemical Manufacturing
Insecticide
Rodenticide for noruay rats and house mice
Anticoagulant therapy
Rodenticide for norway rats and house mice
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
==ss===s====s==ss=s=s=sss=====n==3aa=sss=ssKs
INDUSTRY
USE (a)
P001 (continued)
P002 1-Acetyl-2-thiourea
Medicine
Anticoagulant therapy
No information available
P003 Acrolein
POCK Aldrin
POOS Allyl alcohol
P007 5-Aminoethyl-3-isoxazolol
POOS 4-Aminopyridine
POU Thiophenol (Benzenethiol)
P016 Bis-(chloromethyl)ether
P017 Bromoacetone
P018 Brucine
Agricultural Chemical Manufacturing
Organic Chemical Manufacturing
Pharmaceutical Manufacturing
Plastics and Resins Manufacturing
Agricultural Chemical Manufacturing
Military
Pesticide
Agricultural Chemical Manufacturing
Organic Chemical Manufacturing
Plastics and Resins Manufacturing
Medicine
Plastics
Agricultural Chemicals,
Pesticides
Plastics
Specialty Chemical
Plastics
Munitions
Specialty Chemical
Pesticide
Chemical intermediate in synthesis of glycerin,
acrylic acid and esters
Chemical intermediate for Pharmaceuticals
Chemical intermediate for glycerol, polyurethane,
and polyester resins
Aquatic herbicide, biocide, slimicide
Component of military poison gases
Lacrimogenic warning agent in methyl chloride refrigerant
Insecticide, fumigant
Herbicide for weed, seeds and fungi
Intermediate in synthesis of glycerin
Manufacture of resins and plasticizers
Laboratory use
Antiemetic
Solvents, reagents and chemicals
Chemical intermediate for carbophenothion fungicide
Chemical intermediate for carbophenothion insecticide & acaricide
Alkyleting agent in manufacture of polymers
Monitoring indicator for chloromethyl ether
Intermediate in synthesis of anionic exchange strong-base resins
Lab reagent
Organic synthesis
Chemical Mar gas
Tear gas
Reagent for separating racemic mixtures
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEHICAL PRODUCTS
UASTECOOE NAHE
INDUSTRY
USE (a)
P018 (continued)
P020 Dinoseb
P022 Carbon disulfide
Pesticide
Clothing
Automobile Manufacturing
Metals Recovery
Wood. Housing
Lubricants, Uax, Soap, Food
Chemical
Specialty Chemical
Plastics
Medicine
Electroplating
Plastics
Electronic
Petroleum
Rubber
Adhesives and Sealants
Agricultural Chemicals
Denaturant for ethanol
Herbicide
Chemical intermediate for rayon
Corrosion inhibitor
Agent in removal of metals form waste water
Putty preservatives
Tallow
Catalyst and catalyst adjuvant and activator
Dissolving free sulfur,phosphorous,iodine
Regenerator for transition metal sulfide catalysts
Manufacture of xanthogenates
Xanthation of cellulose in preparation of viscose
Flame lubricant in cutting glass
Chemical intermediate for carbon tetrachloride
Chemical intermediate for cellophane
Solvent for phosphorous,selenium,bromine,iodine,fats & resins
Optical glass
Agent in metal treatment and plating (gold and nickel)
Polymerization inhibitor for vinyl chloride
Electronic vacuum tubes
Solvent for cleaning and extractions
Generating petroleum catalysts
Solvent for waxes.lacquers.camphor.resins,vulcanized rubber
Chemical intermediate for sulfur and carbonyl sulfide.xanthates
Rubber cement
Chemical intermediate for adhesives for food packaging
Solvent in extraction of growth inhibitors
Preservation of fresh fruit
Explosive
Explosives
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
==== ======SS=S=XSSSS==SSSSBSSSSSSB8SS======S=
INDUSTRY
USE (a)
P022 (continued)
P023 Chloroacetaldehyde
P024 p-ChIoroan iIi ne
P026 1-(o-Chlorophenyl)thiourea
P027 3-Chloroproprionitrile
P028 Benzyl chloride
Film
Pesticides
Agricultural Chemical
Petroleum Refining
Plastics and Resins
Rubber
Veterinary Medicine
Timber
Specialty Chemical
Water Treatment
Agricultural Chemicals
Dentistry
Agricultural Chemicals
Dyes and Pigments Manufacturing
Specialty Chemical
Pharmaceuticals Manufacturing
Specialty Chemical
Agricultural Chemicals
Flavoring
Cosmetics and Fragrances
Pharmaceuticals
Development restrainer for instant color photography
Solvent for pesticide intermediates
Fumigant
Seed treatment on conifers
Soil disinfectants
Rocket fuel
Paints,enamels,varnishes,paint removers
Chemical intermediate for rubber compounds
Cold vulcanization of rubber
Veterinary anthelmintic
Bark removal from trees
Chemical intermediate
In manufacture of 2-aminothiazole
Control of algae,bacteria,and fungi in water
Fungicide
As spinning solution of poly B-aniline
Chemical intermediate for urea herbicides
Chemical intermediate for dyes and pigments
Not manufactured or used industrially in U.S.
Combines reactivity of nitrile and an alkyl halide
Pharmaceutical and polymer synthesis
Chemical intermediate for other benzyl phthalates
Chemical intermediate for n-butyl benzyl phthalate
Manufacture of benzyl compounds
Synthesis of tribenzyltin chloride
Blocking agent to monoalkylated piperazine
Conversion of tertiary amines to quaternary ammonia chlorides
Manufacture of batericides
Manufacture of flavors and odorants
Manufacture of perfumes
Manufacture of pharmaceutical products
-------
ssssssssssssssss
UASTECCOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
P028
(continued)
>
-J
P034 2-Cyclohexyl-4,6-dinitrophenol
P037 Dieldrin
P042 Ephinephrine
POA5
P046
P047
P048
P049
P050
P051
P054
Thiofanox
Dyes and Pigments
Photography
Dyes and Pigments
Lubricant Manufacturing
Plastics and Resins
Agricultural Chemicals
Pesticides
Petroleum Refining
Pharmaceuticals
Rubber
Pesticide
Pesticide
Medicine
Pesticides
alpha,alpha-Dimethyl phenethylamine Medicine
4,6-Oinotro-o-cresol and salts Pesticide
2,4-Dinitrophenol
2,4-Dithiobiuret
Endosulfan
Endrin and metabolites
Aziridine
Pesticide
Pesticides
Plastics and Resins
Rubber
Pesticide
Pesticide
Specialty Chemical
Manufacture of synthetic tannins
Pickling inhibitors
Manufacture of photographic developer
Manufacture of dyes
Manufacture of lubricants
Manufacture of artificial resins
Manufacture of plastics and plasticizers
Production of electron-beam-sensitive fluid media
Manufacture of fungicides
Manufacture of insecticides
Gasoline gum inhibitor
Penicillin precursors
Rubber accelerators
Insecticide
Insecticide
To counter allergic reactions, prolong infiltration anesthetics
Adrenergic agent
Sympathomimetic, vasconstrictor, cardiac stimulant, bronchodilater
Systemic soil insecticide
Acaricide and nematocide (soil t seed treatment)
No information available
Ovicidal spray for fruit trees
Insecticide
Manufacture of insecticides, rodenticides
Plasticizer, intermediate in resin manufacture
Rubber accelerator
Insecticide for vegetables
Insecticide, in dieldrin
In binders
-------
UASTECOOE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
P054
(continued)
Plastics
Specialty Chemical
00
P057 2-Fluoroacetamide
P05B Fluoroacetic acid
P059 Heptachlor
P060 Isodrin
POM Isocyanic acid, methyl ether
P066 Methomyl
P067 2-Methylaziridine
Paint Manufacturing
Cosmetics
Adhesives and Sealants
Agricultural Chemicals
Photography
Paper
Pesticides
Petroleum Refining
Textiles
Pesticides
Pesticides
Pesticide
Pesticide
Agricultural Chemicals
Pesticides
Pesticides
Food
Specialty Chemical
Comonomer for polymers
Monomer for polyethyleneimine
As flocculation aids
In surfactants
In ion exchange resins
Chemical intermediate for N-(2-hydroxyethyl)ethyleneimine
Manufacture of trimethyIntel anine
Manufacture of taurine
In lacquers
In cosmetics
In adhesives
As plant mutagen to improve varieties
Exhibits sporicidal action
In photographic chemicals
Polymerization products
Control of insect pests by chemosterilization
In petroleum refining chemicals, fuels, oils
Strengthening, shrinkproofing, stiffening, flameproof ing, waterproofing
Insecticide
Rodenticide
Rodenticide
Predacide (predatory animals)
Insecticide for cotton boll weevil
Manufacture and use discontinued in U.S.
Chemical intermediate for carbamate herbicides
Chemical intermediate for carbamate insecticides
Nematocide, insecticide
Chemical intermediate in gelatins
Comonomer for polymer with methacrylic acid & esters
Chemical intermediate for Tris(2-methyl-1,3,5-triazine
Fiber modification
-------
UASTECODE HAKE
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
£==sss==s==sss==ss=ss3sss3vaa3csnsssss======
INDUSTRY
USE (a)
P067 (continued)
vo
P069
Hethyllactonitrite
P070
P072
POTS
Aldicarb
1-MaphthyI-2-th iourea
Nicotine
P077
4-Nitroaniline
Adhesives and Sealants
Agricultural Chemicals
Dyes and Pigments
Film
Oil Additives
Paper
Petroleun Refining
Pharmaceuticals
Plastics and Resins
Rubber
Textiles
Specialty Chemical
Pharmaceuticals
Petroleum
Pesticides Manufacturing
Pesticides
Pesticides
Leather and Tanning
Agricultural Chemicals
Pesticides
Veterinary Medicine
Automobile Manufacturing
Petrol euro
Dyes and Pigments
As polymer
In imine derivatives for agricultural chemicals
As polymer
Chemical intermediate in photography
Modifiers for viscoseity, high pressure performance, oxidation resist.
Chemical intermediate for oil additives
As polymer
Ftocculants. modifier for rocket propellent fuels
Organic .intermediate
In imine derivatives for medicinal chemicals
Chemical intermediate in modification of latex coating resins
Organic intermediate
As polymer
Chemical intermediate for methyl methacrylate
Reagent in formation of aldehyde cyanohydrins
Chemical intermediate for methacrylic acid & higher esters
Used to produce a pharmaceutical intermediate
Stereoselective hydrocyanattng reagent
Complexing agent for metals refining and separation
Manufacture insecticides
Insecticide, acaracide, nematocide
Rodenticide for Norway rat (former use)
In tanning
Greenhouse fumigant
Insecticide
Ectoparasitic, anthelrointic
Corrosion inhibitor
Chemical intermediate for gasoline gum inhibitors
Chemical intermediate for dyes and pigments
-------
UASTECODE NAME
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
INDUSTRY
USE (a)
P077 (continued)
P082 N-Nitrosodimethylamine
•r
Ln
O
P084 N-Nitrosomethylvinylamine
P088 Endothail
P093 N-Phenylthiourea
P095 Phosgene
Specialty Chemical
Pharmaceuticals
Veterinary Medicine
Lubricant Manufacturing
Research
Specialty Chemical
Petroleum refining
Plastics
Fibers
Agricultural Chemicals
Pesticides
Rubber
Agricultural Chemical Manufacturing
Medicine
Agricultural Chemicals
Plastics and Resins
Specialty Chemical
Chemical intermediate for antioxidants .
Chemical intermediate for P-Phenylenediamine
No information available
For poultry
In lubricants
Research chemical
Preparation of thiocarbonyl fluoride polymers
Chemical intermediate for 1,1-Dimethylhydrazine (former use)
Antioxidant
Production of rocket fuels (former use)
Condensers to increase dielectric constant
Inactive metal anode-electrolyte systems (high-energy batteries)
Plasticizer for acrylonitrile polymers, solvent
Softener for copolymers
Solvent
Industrial solvent
Inhibition of nitrification in soil
As nematocide
Plasticization of rubber
Rubber accelerator
Research chemical
Herbicide, defoliant, dessicant, growth regulator,
aquatic algicide and herbicide
In genetics research
Rabbit.rat.weasel repellent
Monomer for polycarbonate resins
Chemical intermediate for toluene diisocyanate
Chemical intermediate for methyl isocyanate
Chemical intermediate for polymethylene polyphenylisocyanate
Intermediate, carbonylating agent
Chemical intermediate for diethyl carbonate,dimethyl carbamoyl chloride
-------
TABLE A-1 (Continued)
INDUSTRIAL USE OF U AND P CHEMICAL PRODUCTS
WASTECODE NAME
INDUSTRY
USE (a)
P095
(continued)
P101
r
P108
P116
P118
P123
Propanenitrile
P102 Propargyl alcohol
Strychnine
Thiosemicarbazide
Trichloromethanethiol
Toxaphene
Munitions
Dyes and Pigments
Organic Chemicals Manufacturing
Specialty Chemical
Automotive
Organic Chemical Manufacturing
Agricultural Chemical Manufacturing
Commercial Testing Laboratories
Pharmaceutical Manufacturing
Pesticides
Agricultural Chemicals
Pesticides
Photography
Pesticide
Chemical intermediate for diphenylmethane-4,4'-diisocyanate
Chemical intermediate for acyl chlorides, chloroformate esters
War gas
Production of aniline dyes
Preparation of organic chemicals
Solvent, dielectric fluid, intermediate
Experimental applications: ulcerogen
Chemical intermediate for Di-n-propylamine
Corrosion inhibitor
Prevent hydrogen embrittlement of steel
Solvent stabilizer
Soil fumigant
Lab reagent
Manufacture of Pharmaceuticals
Destroying predatory animals and trapping fur-bearing animals
Rodent control in forage crops production
Rodent control in fruit production
Reagent for ketones and certain metals
Chemical intermediate for herbicides
Fungicide for rice
Rodenticide
No information available
No information available
Pesticide for cotton crops
(a) Sources: National Library of Medicine, Toxicology Data Network, Hazardous Substances DataBank (HSDB) (Reference 33).
Handbook of Environmental Data on Organic Chemicals (Reference 38).
Merck Index 1983. (Reference 39).
-------
Table A-2
NUMBER OF FACILITIES THAT MAY GENERATE U AND P WASTES
INCLUDED IN BACKGROUND DOCUMENT VOLUMES A, B, AND C
Waste Number of Waste Number of
Code Facilities* Code Facilities*
P001
P002
P003
P004
POOS
POOS
P014
P016
P017
P018
P020
P022
P023
P024
P026
P027
P028
P034
P037
P042
P045
P046
P047
P048
P050
P051
P054
P057
POS8
P059
P064
P066
P067
P069
P070
P072
P075
P077
P082
P084
P088
P093
P095
P101
P102
P108
P116
P118
P123
U001
U002
U003
U004
U005
U006
U007
U008
U009
U010
U011 .
U012
U014
U016
U017
U018
3
1
2
3
3
5
6
4
4
3
1
14
5
6
1
2
20
1
9
5
1
1
2
2
6
3
2
2
1
5
4
6
3
2
5
1
3
9
1
1
3
1
23
7
3
6
8
2
4
6
13
22
7
1
13
19
4
22
4
6
27
4
NA
2
2
U019
U020
U021
U022
U024
U025
U026
U027
U029
U030
U031
U033
U034
U036
U037
U038
U039
U041
U042
U043
U044
U045
U046
U047
U048
U050
U051
U052
U053
U055
U056
U057
U060
U061
U063
U064
U066
U067
U068
U070
U071
U072
U073
U074
U075
U076
U077
U078
U079
U080
U081
U082
U083
U084
U085
U089
U091
U092
U094
U095
U105
U106
U108
U110
U112
71
9
5
6
1
2
1
1
3
1
11
8
6
10
10
2
1
2
1
14
38
13
3
2
2
1
13
5
4
11
10
18
1
26
1
1
5
9
9
8
6
13
4
1
19
1
23
2
3
41
3
4
2
2
0
3
2
11
4
2
11
4
9
7
5
Waste Number of Waste
Code Facilities* Code
U113
U114
U116
U117
U118
U120
U121
U122
U123
U124
U125
U126
U127
U128
U129
U130
U131
U132
U137
U138
U140
U141
U142
U147
U148
U149
U152
U153
U154
U155
U156
U157
U158
U159
U161
U162
U163
U164
U165
U166
U167
U168
U169
U170
U171
U174
U177
U181
U182
U183
U184
U18S
U186
U187
U188
U191
U192
U194
U196
U197
U200
U201
U202
U203
U206
5
1
1
5
2
1
12
73
1
6
5
0
3
2
20
6
4
2
1
19
8
2
6
8
10
1
4
1
12
3
2
1
8
31
5
3
6
4
17
4
17
2
17
2
4
3
1
1
0
2
2
6
3
5
13
11
1
8
6
1
7
1
3
6
3
U207
U208
U209
U210
U211
U213
U220
U221
U222
U223
U225
U226
U227
U228
U234
U236
U238
U239
U240
U243
U244
U247
U248
Number of
Facilities*
1
1
3
32
33
6
48
9
1
38
6
44
5
39
1
2
4
42
18
1
2
8
3
Sources: National Library of Medicine, Toxicology Data Network,
Hazardous Substances Databank (HSDB) (Reference 33)
1987, 1988 SRI Directory of Chemical Producers, USA (References 34 and 35)
U.S. EPA 1986 TSDR Survey (Reference 36)
A-52
-------
Table A-3
NUMBER OF FACILITIES IN EACH STATE THAT HAY GENERATE U AND P WASTES
INCLUDED IN BACKGROUND DOCUMENT VOLUMES A, B, AND C
State
Alabama
Alaska
Arizona
Arkansas
California
Colorado
Connecticut
Delaware
Florida
i_n Georgia
to
Hawaii
Idaho
Illinois
Indiana
. Iowa
Kansas
Kentucky
Louisiana
Ma i ne
Maryland
Massachusetts
EPA
Region
IV
X
IX
VI
IX
VIII
I
III
IV
IV
IX
X
V
V
VII
VII
IV
VI
1
III
1
Waste Codes (Number of Facilities)
P014(1) P022(1) P034(1) P042(1) P095(1) P10K1) 0019(2) 0020(1) 0038(1) 0061(1) 0080(1) 0122(3) 0129(2)
0220(1) 0228(1) 0239(2) 0244(1)
0061(1) 0220(1) 0226(1) 0227(1) 0228(1) 0240(2)
0211(1) 0219(1) 0220(2) 0223(1) 0228(1)
P047(1) 0029(2) 0061(1) 0067(3) 0122(2) 0211(1) 0220(1) 0226(1) 0240(1)
P004(1) P037(1) P042(1) P064(1) P108(1) 0002(1) 0033(1) 0057(2) 0061(2) 0067(1) 0070(1) 0072(1) 0075(3)
0124(1) 0129(1) 0138(1) 0051(1) 0159(2) 0161(1) 0188(1) 0211(1) 0218(1) 0220(2) 0223(1) 0225(1) 0226(6)
P066(1) 0226(1) 0239(1)
P022(1) P116(1) 0006(1) 0007(1) 0031(1) 0044(2) 0073(1) 0075(1) 0077(1) 0080(1) 0091(1) 0092(1) 0138(1)
0210(1) 0219(1) 0220(1) 0223(3) 0226(2) 0239(1) 0244(3)
P014(1) P022(1) P028(1) P050(1) P066(1) P070(1) P077(1) P095(1) P10K1) P108(1) 0006(2) 0007(1) 0009(1)
0020(1) 0022(1) 0036(1) 0044(1) 0048(1) 0055(1) 0056(1) 0061(1) 0070(2) 0071(1) 0072(2) 0074(1) 0077(1)
0105(1) 0114(1) 0116(1) 0127(1) 0131(1) 0138(1) 0148(1) 0152(1) 0154(1) 0163(1) 0165(1) 0167(1) 0169(1)
0210(2) 0211(1) 0218(1) 0220(1) 0223(1) 0226(1) 0227(1) 0228(1) 0239(1) 0240(1) 0247(1)
P016(1) P088(1) 0057(1) 0075(1) 0080(1) 0082(1) 0092(1) 0110(1) 0125(1) 0142(2) 0147(1) 0154(1) 0158(1)
0226(2) 0228(1) 0239(2)
P050(1) P070(1) 0033(1) 0057(1) 0061(2) 0114(10)0122(1) 0129(1) 0051(1) 0159(1) 0170(1) 0220(1) 0228(2)
P059(1) 0061(1) 0129(1) 0240(1)
0051(1) 0228(1)
P037(1) P042(1) P077(2) 0003(3) 0004(1) 0009(3) 0011(1) 0012(1) 0019(2) 0033(1) 0036(1) 0037(1) 0044(2)
0072(1) 0075(1) 0077(1) 0117(1) 0121(2) 0122(2) 0130(1) 0148(1) 0051(2) 0155(1) 0158(1) 0159(2) 0165(1)
0206(1) 0210(1) 0211(2) 0219(1) 0220(3) 0223(1) 0225(1) 0226(2) 0228(2) 0234(1) 0239(1) 0240(4)
P008(1) P017(1) P095(1) 0002(1) 0031(1) 0080(1) 0092(2) 0171(1) 0188(1) 0191(1) 0196(1) 0228(1)
0061(1)
0002(1) 0004(1) 0057(1) 0122(2) 0132(1) 0138(1) 0159(1) 0188(1)
0009(1) 0043(1) 0044(1) 0045(1) 0057(1) 0070(1) 0075(1) 0080(1) 0092(1) 0122(2) 0051(1) 0211(1) 0220(1)
P003(1) P022(1) P024(2) P095(3) 0007(2) 0008(1) 0009(2) 0012(2) 0015(2) 0016(1) 0031(2) 0036(1) 0037(1)
0057(1) 0061(1) 0077(6) 0080(1) 0108(1) 0113(1) 0121(1) 0122(5) 0148(5) 0154(3) 0159(1) 0162(1) 0165(1)
0200(1) 0211(2) 0213(1) 0220(3) 0221(2) 0223(3) 0227(1) 0239(2) 0247(1)
0036(1)
P095(1) 0042(1) 0080(1) 0156(1) U223(2) 0226(1) 0228(3)
P023(2) P050(1) 0003(2) U007(1) 0009(1) 0044(2) 0053(1) 0057(1) 0080(2) U108(1) 0110(1) 0112(1) 0122(1)
U210(1) U220(2) U226(1) U238(1) U239(1) U247(1)
0051(1) 0170(1) 0210(1) 0211(2)
0080(3) 0082(1) 0121(3) 0122(1)
0228(4) 0239(4)
0148(1) 0158(1) 0159(1) U163(1)
0011(1) 0012(1) 0018(1) U019(1)
0079(1) 0080(1) 0089(2) 0092(1)
0185(1) 0194(1) 0202(1) 0209(1)
0194(1) 0210(1) 0220(2) U223(2)
0045(1) 0052(1) 0057(1) U070(1)
0169(1) 0171(1) 0174(1) 0191(1)
0221(1) 0226(1)
0039(1) 0043(6) 0044(1) 0045(2)
0169(1) 0185(1) U188(1) 0194(1)
U051(1) 0159(2) 0193(1) U194(1)
-------
State
Michigan
Minnesota
Mississippi
Missouri
Montana
Nebraska
Nevada
New Jersey
EPA
Region
V
IV
VII
VIII
VII
IX
II
Table A-3 (continued)
NUMBER OF FACILITIES IN EACH STATE THAT MAY GENERATE U AND P WASTES
INCLUDED IN BACKGROUND DOCUMENT VOLUMES A, B, AND C
Waste Codes (Number of Facilities)
P064(1) P088(1) P095(1) U007(1) U045<1) U068<1) U073(1) U075(1) U078(1) U080(1) U08KD U110(1) U112(1) U12K1) U16S(1) U206(1) U21K1)
U219(1) U225(1) U240(1)
P067(1) P077(1) U019O) U044(1) U061(1) U07K1) U080(2) U082(1) U122(1) U185(1) U226(1) U227(1) U247(1)
P020(1) P022(1) P050(1) U012(2) U044<1) U1U(1) U122(3) U129(2) U169(1) U21KD U220(1) U223(1) U226(1) U228(1) U247(1)
POOA(1) P037(1) P050(1) P05K1) P059(1) P066(1) P070(1) P10K1) P108(1) P123(1) U003(1) U006(1) U007(2) U01K1) U012(1) U019(2) U036(1)
U037(1) U044O) U056(1) U06K2) U072(1) U075(1) U077(1) U079(1) U080(2) U09KD U117(1) U122(1) U129(1) U13K1) U155(1) U158(1) U165(1)
U167(1) U169(1) U183(1) U185(1) U187(1) U200(1) U21KD U220(3) U225(1) U239(1) U240(1) U247(1)
U122(1)
U125(1)
P123(1) U034(1) U06K1) U072(1) U080(1) U228(1) P014(1)
POOK1) P017(2) P018(1) P022(1) P023(1) P024(2) P028(6) P037(1) P047(1) P048(1> P057(1) P067(2) P072(1) P077(1) P095(1) P116(3) U002(1)
U004(3) U006(5) U007(3) U009(1) U011(1) U012(3) U014(3) U017(1) U019(1) U03K2) U033(1) U037(1) U044(3) U045<1) U052(1) UOS7(1) U06K2)
U067(1) U068(4) U07H1) U072(1) U075(4) U080(2) U092(1) U10S(1) U108(3) U110(1) U117(1) U12K2) U122(S) U124(1) U125(1) U138(6) U14K1)
U147(1) U148(2) U159(10)U161(1) U163(1) U165(2) U166(1) U167(1) U169(2) U18K1) U187(1) U188(1) U19K2) U194(1) U196(2) U200(2) U203(4)
U218(4) U219(2) U220(1) U222(1) U223(1) U226(2) U228(2) U236(2) U238(1) U239C3) U244(1) U248(1)
P095(1) U209(1) U210C1) U21K1) U220(1) U223(1) U225(1) U226(2) U228(1) U239(1)
POOK1) P008(1) P016(1) P017(1) P022C1) P023(1) P027(1) P028(1) P075(1) P093(1) P095(1) P10KD P108(2) P116(2) U003<3) U007(3) U009(1)
U010(2) U012(1) U020(2) U02K2) U022(2) U037(1) U044(4) U045(2) U046(1) U047(1) UOS2(1) U057(1) U06K1) U064(1) U067(1) U068(2) U070(1)
U077(1) U080(2) U094(1) U095(1) U105(1) U114(1) U122(3) U129(1) U130(1) U138(4) U140(1) U147(1) U159(3) U163<1) U165(2) U166(1) U169(3)
U184(1) U187(2) U19K3) U196(2) U200(1) U202(1) U207(1) U210C5) U21K3) U219(3) U220(2) U22KD U223(8) U228(3) U239(3) U248(1)
P008O) POK(1) P022(1) P028(1) P037(1) P048(1) P050(1) POSK1) P059(1) P10K1) P123(1) U003(2) U005(1) U006(1) U007(1) U009(1) U010(1)
UOH(I) U012(2) U014(1) U018(1) U019(1) U02K1) U022(1) U034(1) U036(2) U037(1) U043(1) U044(2) U050(1) U056(1) U064(1) U067(1) U068C1)
U070(1) U077(1) U080(2) U089(1) U092(1) U110(1) U119(1) U122(6) U127(1) U128(1) U129(1) U14K1) U142(1) U148(1) U157(1) U158(1) U163(1)
U165(1) U168(1) U169(1) U174(1) U177(1) U200(1) U203(1) U210(2) U21K1) U220(1) U22K1) U226(1) U228(1) U238(1) U239(1)
U06K1)
P037(1) P077(1) P095(2) P118(1) U001(2) U003(1) U007(1) U009(2) U012(6) U019(1) U02K1) U033(1) U034(1) U037(1) U044(5) U056(3) U057(1)
U06K1) U07K1) U072C1) U077(1) U080(3) U095(1) U108(1) U122(4) U125(1) U13K1) U138(1) U05K1) U185(1) U188(1) U194(1) U202(1) U210(2)
U21K2) U220(2) U22K1) U223(3) U226(5) U228(4) U239(3) U240(2)
U210(1)
U019(1) U037(1) U038(1) U077(1) U122(8) U220(1) U239(1)
P024(1) P028C3) P037(1) P077(1) U001(1) U002(2) U004(1) U006(1) U009(1) U011(1) U020(1) U024(1) U031(2) U044(2) U045(1) U046(1) U053(1)
U055(2) U057(1) U06H2) U067(1) U072(1) U075(3) U077(2) U080(3) U105(1) U114(1) U117(1) U12K2) U122(2) U124(1) U129(2) U130(1) UK2(1)
U147(2) U152(1) U159(3) U165(1) U188(1) U19K1) U192(1) U196(1) U201(1) U210(1) U219(2) U220(2) U226(4) U228(2) U239(2) U240(1) U244(1)
U002(1) U003(2) U004(1) U019(1) U03K1) U037(1) U044(1) U056(1) U077(1) U080(1) U140(1) U169(1)
U138(1) U21H1)
U220(1) U239(1)
-------
State
EPA
Region
Table A-3 (continued)
NUMBER OF FACILITIES IN EACH STATE THAT HAY GENERATE U AND P WASTES
INCLUDED IN BACKGROUND DOCUMENT VOLUMES A, B, AND C
Waste Codes (Number of Facilities)
South Carolina IV
Tennessee
Texas
Utah
IV
VI
VIII
in
Ln
Vermont I
Virginia III
Washington X
West Virginia III
Wisconsin V
P008(1) P037(1) U017(1) U019(1) U044(1) 11061(1) U072(1) U075(1) U077(1) U080(1) U108(1) U121(1) U122(4) U129(2) U130(1) U138(1) U142M)
U05K1) U210(2) U21K2) U219(1) U220(2) U226(2) U228(1) U239<2) U240(1)
P022(1) P028(1) P059(1) P069(1) P075(1) U003(1) U012(1) U019(1) U020(1) U053(1) U06KD U072(1) U112(1) U124(1) U129(1) U130(1) U140(1)
U154C1) U159(1) U16K1) U162(1) U197(1) U21K1) U213(1) U228(1)
P005(2) P014(1) P022(1) P066(2) P069(1) P09S(5) P10K1) P116(1) P118(1) UOOK3) U002(5) U003(4) U006(1) U007(1) U008(3) U009(4) U012(3)
U019(4) U020(1) U025(1) U026(1) U027(1) U03K2) U033(1) 1)034(2) U036(1) U04K2) U043(5) U044(3) 1)045(1) U052(1) UOS6(1) U057(3) U061(2)
U072(1) U073(1) U074(1) U077(3) U080(4) U08K1) U084(1) U092(1) U105(2) U106(1) U108(1) U112(2) U113(4) U114(1) U118(1) U122(10)U123(1)
U129(2) U138(1) U140(4) U147(1) U05K1) U152(1) U153(3) 1)154(6) U156(1) U159(3) U16K1) U162(1) U165(4) 1)166(1) U169(1) U171(1) U188(3)
U194(1) U210(3) U21K4) U213(1) U220(7) U22K2) U223(5) U226(2) U228(2) U239(1) U240(1)
P054(1)
U044(1)
P018(1) P077C1) U007(1) U019(2) U020(1) U036(1) U044(2) U057(1) U080(1) U110(1) U117(1) U129(1) U140(1) U05KD U158(1) U167(1) U194(1)
U210(3) U21K2) U219(1) U220(1) U223(2) U226(1) U228(1) U239(1)
P002(1) P016(1) P022(1) P028(1) P042(2) U019(1) U022(1) U043(1) U044(1) U055(1) UOS6(1) U064(1) U075(1) U080(1) U122(2) U152(1) U1S8(2)
U169(1) U188(2) U210(1) U21K1) U219(1) U220(1) U226(2) U228(1) U239(2) U240(1)
P004(1) P022O) P045(1) P064(2) P066(1) P070(2) U002(2) U003(1) U009(2) U012(2) U044(1) U04S(2) U053(1) U070(1) U072(1) U077(1) U080(2)
U092(1) U105C2) U106(2) U108(1) U116(2) U118(1) U122(2) U147(1) U148(1) U159(1) 1)161(1) U165C1) U169(2) U19K2) U210(1) U223(3) U244(1)
U247(1)
POOK1)
P059(1)
U019(1)
U063(1)
U105(1)
1)149(1)
U203C1)
P003(1) P005(1)
P075(1) P077(1)
U020(1) U02K1)
1)064(1) U067(1)
P008(1)
P082(1)
U022(1)
U068(1)
U05K1) U152(1)
U206(1) U208(1)
U153(1)
U21K1)
P014(3)
P084(1)
U029(1)
U071(1)
U120(1)
U15S(1)
U214(2)
P016(1)
P095(1)
U030(1)
U072(1)
U122(1)
U163(1)
U218(1)
P017{1)
P10K1)
U034(1)
U073(1)
U125(1)
U165(1)
U219(1)
P018(1)
P102(1)
U036(1)
U074(1)
U127(1)
U166(1)
U220(2)
P022(1)
P108(1)
U037(1)
U076(1)
U128(1)
U168<1)
U221(1)
P023(1)
U04S(1)
U077(1)
U129(1)
U169(1)
U225(1)
P024(1)
P123(1)
U046(1)
U079(1)
U130(1)
U17K1)
1)226(1)
P026(1)
U003(1)
U047(1)
U08K1)
U13K1)
U174(1)
U227(1)
P027(1)
U006(1)
U048(1)
U082C1)
U132(1)
1)183(1)
U238(1)
P037(1)
U007(1)
U055(1)
U083(1)
U137(1)
U185(1)
U240(1)
P046(1)
U009(2)
U056(1)
U084(1)
U138(1)
U187(1)
U243(1)
P05K1)
U010(1)
U057(1)
U089(1)
U142(1)
U193(1)
U247(1)
P054(1)
U012(1)
U060(1)
U092(1)
U147(1)
U200(1)
U248(1)
Sources: National Library of Medicine, Toxicology Data Network,
Hazardous Substances Databank (HSDB) (Reference 33)
1987 and 1988 SRI Directory of Chemical Producers (References 34 and 35)
U.S. EPA 1986 TSDR Survey (Reference 36)
-------
APPENDIX B
CHEMICAL STRUCTURE
FOR U AND P WASTE CODES
B-l
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
AROMATICS AND OTHER HYDROCARBON WASTES
(ANALYZABLE)
U019: B«nz«nc
U220: Telucn* (m«thylb«nz«n«)
CH, CH,
CH,
H
o-Xyiana
•CH,
para-Xylan*
U239: Xylana(s)
orthe-Xylana, mata-Xylana and para-Xylana
B-2
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
AROMATICS AND OTHER HYDROCARBON WASTES
(NONANALYZABLE)
U055: Cum«n« (lseprepylb«nz«n»)
UQSt: Cyeleticxan*
CH,CH«CHCH«CH,
IHM: 1,3-PENTAOIENE
B-3
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
BROMINATED ORGANIC WASTES
(ANALYZABLE)
H -
C-Br
\
H
uo 30 4 -
^>\r>€v"v\|
H H
» i »
H - C-C-C-
i i \
Br Br C\
H W
W
i
V4
Br
\
•-C-H
l
Br
B-4
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
BROMINATED ORGANIC WASTES
(NONANALYZABLE)
U O H
i u i
VA -C.-C-C--
l t
B-5
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
HALOGENATED ALIPHATIC WASTES
(ANALYZABLE)
CL
H C CL
CL
U044: Chloroform
CL H
I I
CL C C H
H H
U076: 1,1-Dichloroethane
T T
H-C-C-H
H H
U077: 1,2-Dlchloroethane
H—*-C=C CL
I I
H CL
U078: 1,1-Dlchloroethylene
CL C^C CL
H H
U079: 1,2-Dlchloroethylene
n
H C CL
U080: Methylen* Chloride
H H H
I I I
H—C C^C^H
I I I
H CL CL
U083: 1,2-Dlchloropropan*
rt
H
CL C-
•CL
I I
H H
U084: i,3-0lchloroprop«ne
B-6
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
HALOGENATED ALIPHATIC WASTES
(ANALYZABLE) (Continued)
CL CL
—C—H
I I
CL CL
T T
c=c
i i
CL CL
U209: 1,1,2,2-Tatrachioroathana U210: Tatrachloroathylena
CL-
CL CL
I I
-C C-
I I
CL H
U208: 1,1,1,2-Tatracliloroattiana
CL CL
I- I
CL—C——C—CL
I I
CL CL
U131: Haxaehloroethana
CL
CL—C—CL
CL
U211: Carbon Tatraetilerida
CL H
I I
CL C—C H
I I
CL H
U226: 1,1,1-TricftIoroathana
CL H
I I
CL—C—C CL
H H
U227: 1,1,2-Trfeiiloroathana
CL
CL CL
I I
U228: Trlchloroethylane
B-7
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
HALOGENATED ALIPHATIC WASTES
(ANALYZABLE) (Continued)
CL . CL
CL—C C=C CL
CL CL
U243: Hexaehloropropene
B-8
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
HALOGENATED ALIPHATIC WASTES
(NONANALYZABLE)
CL CL
I I
H C C=C—C—H
I I I I
H H H H
U074: 1,4-Dichloro-2-Butene
T T
CL C—C CL
CL H
U184: P«ntaehloroetimn«
B-9
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
HALOGENATED PESTICIDES AND CHLOROBENZENES
(ANALYZABLE)
CJt
B-10
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
HALOGENATED PESTICIDES AND CHLOROBENZENES
(ANALYZABLE) (Continued)
-, PPP
tttfel
; PPT
CJ
o.
1/03-0 l;2.-pi'
B-ll
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
HALOGENATED PESTICIDES AND CHLOROBENZENES
(ANALYZABLE) (Continued)
ill 11-
Cl
I
- BHC
Cl
Cl
B-12
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
HALOGENATED PESTICIDES AND CHLOROBEN2ENES
(ANALYZABLE) (Continued)
o-cw,
B-13
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
HALOGENATED PESTICIDES AND CHLOROBENZENES
(NONANALYZABLE)
(and esfers)
B-I4
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
HALOGENATED PHENOLIC WASTES
(ANALYZABLE)
p-
OH
t/O'W 2.-
UOS2.
B-15
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
OXYGENATED HYDROCARBON AND HETEROCYCLIC WASTES
(ANALYZABLE)
u o v\
I l\ I
c-c-c-u
t
w
\
H
U ooM Actfro p\rve.\ror»e.
H W
1 V
u -C-C
\ I
VA H
-C-C -OVA
0
U03I
HO H
t it >
H-C.-C--0-C
I I
H H
-C -
H H V\ V4
i i t v
H-C-C-0-C-C-U
\
H
u\n EtKM\
B-16
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
OXYGENATED HYDROCARBON AND HETEROCYCUC WASTES
(ANALYZABLE) (Continued)
H
H O H H ^-H
\ \\ \ \ H V H
-C.C-C-C.-C-H \c,
W-C-H H « \ / I
H A^
U\MO
H cj « /°NVA
W O U U H-C-C-C-C-M
M-CL-C-C-C-H H w c^
111 14/ XU
H H H
u1
W O H
I U t
W-C=C-C-C-VA
1 »
\
B-17
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
OXYGENATED HYDROCARBON AND HETEROCYCLIC WASTES
(NONANALYZABLE) .
o u
II I
C-C-VA
1
H
%0'
I
H
P001
(>0.3%)
Poo3 Aoro\ t:
0\A
o
It
C
ll
O
H
H
\\
oVco\r\o\
UOOl
B-18
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
OXYGENATED HYDROCARBON AND HETEROCYCUC WASTES
(NONANALYZABLE) (Continued)
V-c
/
rt
, /
"xc"
\
H H O
\ I II
H H
OVA
UOC*
a
H
/*-«
v
O I
C-H
VA
uo-%5 \,2:3,4 -
O
H O H H \\
\ \\ \ \
C = CL-H-C-0-C -C-H
I \ i H
H H H
dLv^ <*^«. j
B-19
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
OXYGENATED HYDROCARBON AND HETEROCYCLIC WASTES
(NONANALYZABLE) (Continued)
o
\\
VI-C.-OH
O
O O
/\ U
W-CL-C-C-H
\ \
w
1
-C-OM
1
W
UV6M
B-20
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
OXYGENATED HYDROCARBON AND HETEROCYCUC WASTES
(NONANALYZABLE) (Continued)
H
W-
I
C-W
i
W
O
U 3 \ 3
ro
B-21
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
WASTES OF A PHARMACEUTICAL NATURE
(ANALYZABLE)
U
H M
_n_c-c — n
C
V
H
55
H-C—C-0
H
H
I
C
I
H
M
O
U
i
-C
I
w
-VA
B-22
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
WASTES OF A PHARMACEUTICAL NATURE
(NONANALYZABLE)
9001 6-
- S -
H M
H H V
i i / \u
w-o-c-c-n u
u
POT 5
B-23
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
WASTES OF A PHARMACEUTICAL NATURE
(NONANALYZABLE) (Continued)
o-o-c-n
UOVO
;\n C
U
O
\\
V4
\
O
\\
/•» c r^ —C — C. — C."-O~"H
I \
H W
B-24
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
WASTES OF A PHARMACEUTICAL NATURE
(NONANALYZABLE) (Continued)
w —
U O 5 9
HO-
-lA.-(o}-
1 VA N /
^-c-c-H
oH
\ \
B-25
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
WASTES OF A PHARMACEUTICAL NATURE
(NONANALYZABLE) (Continued)
H
i
n
\\
\
n
w
n
\
\ (P 3
- n -n\ Vo -
B-26
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
WASTES OF A PHARMACEUTICAL NATURE
(NONANALYZABLE) (Continued)
B-27
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
WASTES OF A PHARMACEUTICAL NATURE
(NONANALYZABLE) (Continued)
n=o
B-28
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
PHENOUCS
(ANALYZABLE)
OH
U
NO-
P02.0
OH
HO,.
OH
UI01
OH
NO,
OH
B-29
-------
OH
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
PHENOLICS
(NONANALYZABLE)
on
NO,
on
B-30
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
POLYNUCLEAR AROMATIC WASTES
(ANALYZABLE)
H H V H
\ / I \ ^~^ ^H
I II II I
H H
U005: 2-AcetylamlnofIuorene
H
H H
I I I II
I II I I
I I I
H H H
U018: Benz(a) Anthracene
H H
I I
H
II II I
I I
I I I
H H H
U022: Benzo(a)pyrene
B-31
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
POLYNUCLEAR AROMATIC WASTES
(ANALY2ABLE) (Continued)
H H
I I
H 'C^ "C
II
H
H
I II I I
H
KT C "
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
POLYNUCLEAR AROMATIC WASTES
(ANALYZABLE) (Continued)
H
H
H^ X
.C^ ^H
S^
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
POLYNUCLEAR AROMATIC WASTES
(ANALYZABLE) (Continued)
r r
—
I I II I
I I I I
»
I
H
U157: 3-Methylcholanthrene
H H
H H
U16S: Naphthalene
B-34
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
POLYNUCLEAR AROMATIC WASTES
(NONANALYZABLE)
H H H
II I
H
U016: Benz(c)Acrid!na
H
H
I I II
II I II
N^Sc^'X
I II I I
I I I
H H H
U064: 1,2,7,3-OIb«nzopyren«
B-35
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
POLYNUCLEAR AROMATIC WASTES
(NONANALYZABLE) (Continued)
H
H CH, ""N^N^
I II II
I I
H CH3 H
U094: 7,12-DImethylbenz(a)anthracene
B-36
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
ORGANO-NITROGEN COMPOUND WASTES
(ANALYZABLE)
PO-J-?
H
\
n
a-- ..... -o
H W
i i
H-C-
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
ORGANO-NITROGEN COMPOUND WASTES
(ANALYZABUE) (Continued)
uvu
V?
n
u « .7 n-n-o
H W (4
, >
-
H H « M
H H « «
rrr
V4 VA U
B-38
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
ORGANO-NITROGEN COMPOUND WASTES
(ANALYZABLE) (Continued)
U
i
I
A\
H -
h
\\ H /
c-'c/
1 I
H W
rro\'»
U \
B-39
-------
4-
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
ORGANO-NITROGEN COMPOUND WASTES
(NONANALYZABLE)
c._c-n
H
H
POSH Q
r
O
U
H
\-\
ac\cfl,
C
\ /
H
l
N
/
B-40
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
ORGANO-NITROGEN COMPOUND WASTES
(NONANALYZABLE) (Continued)
N
111
I * '
H-C-C-C-H
H OH H
- Kl i
H
C/
I A fc
B-41
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
ORGANO-NITROGEN COMPOUND WASTES
(NONANALYZABLE) (Continued)
w
I
-C.-C-2 n
I
U
c
/
i \\
c-c
-n
aoo 3 Qce^to c\'\
\jkO\\
U.O IM
B-42
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
ORGANO-NITROGEN COMPOUND WASTES
(NONANALYZABLE) (Continued)
' "U
t* «^ o x v
1
H
W * H
-^JCL-C.
" ^ ^ n-M
H-C.-C-C.
i I »
Hi\ IA
n **
'»n e.
B-43
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
ORGANO-NITROGEN COMPOUND WASTES
(NONANALYZABLE) (Continued)
H
N =C-C-CH
H
H
n
O.....O
H O U
\ \ \
H-C.-C-C
\
-H
1
\
H
•?S
H
\
B-44
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
ORGANO-NITROGEN COMPOUND WASTES
(NONANALYZABLE) (Continued)
/
V
H
O
O
II
H-
C-H
I
o
II /
w-0-c.-n
M
\
VA V>
YA-0'
IA
V4 VA
B-45
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
ORGANO-NITROGEN COMPOUND WASTES
(NONANALYZABLE) (Continued)
0-1
/^n— • p
\ /
o
H
\\
M H
B-46
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
ORGANO-SULFUR COMPOUND WASTES
(NONANALYZABLE)
I
H
Pom
Po o£ \ -
H —
H
I
H-C
? 1
c-c
-C-H
5-C-S
HMO
i i u
H-C —N —C—O
1
H
—N=C-C-
M
C
H
$-4
— H
POM 5"
5 S
\\ \\
-c-n -c.-n
»
U
\
H
I
VA-C -c«n
I i
H 5
I
VA —C-H
\
H
O
u
O -CL
M
\
U
B-47
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
I
VA
v4--c-c.
* l
H U-C-H
.
ORGANO-SULFUR COMPOUND WASTES
(NONANALY2ABLE) (Continued)
O u
U /
n-o-c.-n a
c
/ \
„'
PO"?O CX\dL\
H 5
\ U
n-c-n'
,u
\
s u u
\ u \ V
S
u
n-c-c-n
/ i i \
M H »
B-48
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
ORGANO-SULFUR COMPOUND WASTES
(NONANALYZABLE) (Continued)
MO V4 H
I II II
H-C-5-0-C-C-V4
I ' '
W H H
O's
> M-H
O * H H O
^ \\ \ \ v \\
V4-C.-S-H »i » \ \ »
\ o VA VA ^ o
VA
U A S
^« ^— W4 i i »^
H-C-C.-M/ V>-c-\nx
H SH H "H
B-49
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
ORGANO-SULFUR COMPOUND WASTES
(NONANALYZABLE) (Continued)
v * , y
u/ \ u \\ / u
H H
B-50
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
MISCELLANEOUS HALOGENATED ORGANIC WASTES
(ANALYZABLE)
M H
I I
H
CJl-C-C-0- 0-W
I I I
W M \\
H H
i •
-C-(L
1 '
H H
W H
I I
M M
e.iv%€<- uoai
M H H
t \ \
e.-c.-c. -
» I »
H O J4
vA \ H
t
M
W
B-51
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
MISCELLANEOUS HALOGENATED ORGANIC WASTES
(ANALYZABLE) (Continued)
00
•
H-C.-H
CJ)
\
CL-F
I
U.OH1
U015
— C-F
I
c-x
\
B-52
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
MISCELLANEOUS HALOGENATED ORGANIC WASTES
(ANALYZABLE) (Continued)
•J
B-53
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
MISCELLANEOUS HALOGENATED ORGANIC WASTES
(NONANALYZABLE)
H H
\ t
-C. -C-
I
H
H
U
n
3 -
H-C-H
O
n
-c -n
I
F
B-54
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
MISCELLANEOUS HALOGENATED ORGANIC WASTES
(NONANALYZABLE) (Continued)
HO
i u
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
MISCELLANEOUS HALOGENATED ORGANIC WASTES
(NONANALYZABLE) (Continued)
U033
\\
\ \
-C.-CL
I
OJ!
H
/
C
I
H
W
I
C.
l
H
—C.-QJJ
UO-54
VAOMI I-
H «
c-e-
i \
H H
H
H
I
cje -c.-
i
H
H
\ \/»r>u\
B-56
-------
CHEMICAL STRUCTURES FOR U AND P WASTE CODES
MISCELLANEOUS HALOGENATED ORGANIC WASTES
(NONANALYZABLE) (Continued)
»N /"
Nn HN /
c
\
V*
U
O
\\
H-^ V
H
i
-C
I
H
\
\
n
/
s
»
chloride.
\
U
o
o -
B-57
-------
APPENDIX C
SUPPLEMENTAL TREATMENT PERFORMANCE DATA
C-l
-------
Table C-1
WASTE CONSTITUENTS DETECTED IN THE UNTREATED OR TREATED WASTES IN ONE OR MORE OF THE FOURTEEN INCINERATION TESTS
Detected In
Waste BOAT Treatment
Code Number Waste Constituent Test Number*
Concentration In
Untreated Waste
(ppm)
Concentration In Ash
(ppm)[# of sample sets]**
Concentration In Scrubber Water
(ppm)[# of sample sets]**
n
I
to
AROMATIC WASTES
U019 4 Benzene
U220 43 Toluene
U239 215/ Xylenes (total)
216/
217
HALOGENATED ALIPHATIC WASTES
U044 14 Chloroform
U076 22 1,1-Dichloroethane
U077 23 1.2-Dichloroethane
U080 38 Methylene chloride
U083 26 1 ,2-Dichloropropane
U084 28 cis-1,3-Dichloropropylene
U084 27 trans-1,3-Dichloropropylene
2
3
5
8
1
2
3
4
5
6
7
8
9
10
13
14
1
2
3
5
7
8
10
3
4
4
4
11
1
13
14
11
11
11
51 - 83
48 - 61
<2.0 - 3.0
5.6 - 212
10 - 41
100 - 170
2.3 - 3.6
<2.000
<2.0 - 5.0
201 - 2.000
22 - 120
5.0 - 152
<25 - 42
5.4 - 23
0.021
69,000
12 - 130
120 - 170
<2.0 - 7.2
<2.0
<14 - 120
3.0 - 123
<1.5 - 5.3
<2.0
4,600 - 6,000
<2,000 - 2,200
87,000 - 130,000
<0.025 - 11,000
<10
<6,300
87,000
<0.025 - 230,000
^0.025 - 160,000
<0.025 - 290,000
<10 [7]
<2.0 [6], 6.9 [1]
<2.0 [11. 3.0 [2]
<0.025 [5]
<2.0 [3]
<10 [7]
<2.0 [71
<2.0 [6]
2.0 [2], 8.0 [1]
<2.0 [6]
<2.0 [51. 3.0 [1]
<0.025 [2], 0.085 [1], 0.15 [1], 0.19 [1]
<0.005 [4]
<1.5 [4]
<0.005 [3], <0.01 [1]
<0.01 [4]
<2.0 [3]
<10 [7]
<2.0 [71
<2.0 [3]
<2.0 [5], 5.8 [1]
<0.025 [5]
<1.5 [4]
<2.0 [7]
<2.0 16]
<2.0 [6]
<2.0 [6]
<0.005 16]
<10 [3]
<0.005[1], 0.090M], 0.012[1], 0.01511]
<0.010 [31, 0.016 11]
<0.005 [6]
<0.005 [6]
<0.005 16]
<0.010 [7]
<0.002 [7]
<0.002 [41. 0.002 [1], 0.003 [1]
<0.005 [8]
<0.002 [31
<0.010 [71
<0.002 [7]
<0.002 [31. 0.0026 [1], 0.0032 [1], 0.0046 [1]
<0.002 [3], 0.002 [11. 0.003 [11, 0.004 [1]
<0.002 [8]
<0.004 [6]
<0.005 [5], 0.008 [21, 0.009 [1]
<0.005 [4]
<0.005 [6]
<0.005 [3]
<0.005 [4]
<0.002 [3]
<0.010 [7]
<0.002 [7]
<0.002 [5], 0.004 [1]
<0.004 [61
<0.005 [8]
<0.005 [6]
0.0021 [11, 0.0029 [21. 0.0030 [1],
0.0031 [11, 0.0036 [2]
<0.002 [6]
<0.002 [6]
<0.002 [6]
<0.005 [6]
<0.010 [21. 0.061 [1]
<0.005 [A]
<0.005 [4]
<0.005 [6]
<0.005 [6]
<0.005 (6)
* - Treatment tests are identified by number in Table 4-1. Data from Tests 3, 5, and 6 were not used to calculate treatment standards.
** - Number in brackets indicates the number of sample sets for which that value was reported.
-------
Table C-1 (Continued)
WASTE CONSTITUENTS DETECTED IN THE UNTREATED OR TREATED UASTES IN ONE OR MORE OF THE FOURTEEN INCINERATION TESTS
Detected In Concentration In
Waste BOAT Treatment Untreated Waste
Code Number Waste Constituent Test Number* (ppro)
HALOGENATED
U131
U209
U210
U211
U226
0 "227
1
^ U228
113
41
42
7
45
46
47
HALOGENATED
P059
U036
U037
U070
U072
U127
186
177
9
87
88
110
ALIPHATIC UASTES (continued)
Hexach I oroethane
1 , 1 ,2,2-Tetrachloroethane
Tet rach loroethy I ene
Carbon tetrachloride
1.1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethylene
PESTICIDE AND CHLOR08ENZENE WASTES
Heptachlor
Chlordane (alpha and gamma)
Chlorobenzene
ortho-Dichlorobenzene
para-Di chlorobenzene
Hexach 1 orobenzene
4
11
5
6
3
4
5
11
13
4
6
13
4
14
11
4
13
13
4
13
t>
11
.4
11
4
11
13
85 - 120
0.44
2.0 - 3.0
<20
2.3 - 3.9
6.000 - 7.800
<2.0
0.33
0.023
3.500 - 4.100
<20
0.017
33.000 - 81,000
130.000
<0.025 - 860
2,200 - 3.210
16,000 - 88,000
6,600 - 44,900
<2,000 - 3,000
0.027
250
302
74 - 90
2.08
60 - 87
2.08
13,000
Concentration In Ash
(ppm)[# of sample sets]**
<10 [6]
<0.333 [5J, <0.351 tl]
2.0 [1], 3.0 [2]
<2.0 (6)
<2.0 t7]
<2.0 [6]
<2.0 13]
<0.005 [6J
<0.005 [3]-. <0.01 [-1-1
<2.0 [6]
<2.0 [6]
<0.005[1], 0.008(11, <0.010[1], 0.048(1]
<2.0 [6]
<0.01 [4]
<0.005 [61
<2.0 [6]
<0.0066 [31, <0.0065 [1]
<0.013 [4]
<2.0 [6]
<0.005[1],<0.01[3]
<2.0 [6]
<0.333 [5], <0.351 [1]
<2.0 [6]
<0.333 [51. <0.351 [1]
<10 [6]
<0.333 [5], <0.351 [1]
<0.31 [11. <0.33 [21. < 0.36 [1]
Concentration In Scrubber Water
(ppm)[# of sample sets]**
<0.010 [6]
<0.0121 [11. <0.0116 [1], <0.0108 [11.
<0.0104 [1], <0.0106 [11, <0.0107 [1]
<0.002 [6]
<0.002 [71. 0.003 [1]
<0.002 [7]
<0.002 [6]
<0.002 [5], 0.003 [1]
<0.005 [61
<0.005 [4]
<0.002 [6]
<0.002 [71, 0.0073 [1]
<0.005 [41
<0.002 [6]
<0.005 [41
<0.005 [6]
<0.002 [6]
<0. 00005 [4]
<0.0001[4]
<0.002[6]
<0.005[4]
<0.002 [6]
<0.0121 [1], <0.0116 [1], <0.0108 [1],
<0.0104 [1], <0.0106 [1], <0.0107 11]
<0.002 [6]
<0.0121 [1], <0.0116 [1], <0.0108 [1],
<0.0104 [1], <0.0106 [1], <0.0107 [1]
<0.01 [6]
<0. 0121(11. <0.0116 [1], <0.0108 [1],
<0.01 [2], <0.011 [2]
* - Treatment tests are identified by number in Table 4-1. Data from Tests 3, 5, and 6 were not used to calculate treatment standards.
** - Number in brackets indicates the number of sample sets for which that value was reported.
-------
Table C-1 (Continued)
WASTE CONSTITUENTS DETECTED IN THE UNTREATED OR TREATED WASTES IN ONE OR MORE OF THE FOURTEEN INCINERATION TESTS
Waste
Code
Detected In Concentration In
BDAT Treatment Untreated Waste
Number Waste Constituent Test Number* (ppm)
HALOGENATED
U128
U130
U183
U185
U207
U240
U247
111
112
136
138
148
192
190
HALOGENATED
U081
U082
90
91
OXYGENATED
U002
U112
U159
U161
222
225
34
229
PESTICIDE AND CHLOROBENZENE WASTES
Hexach 1 orobut ad i ene
Hexachlorocyclopentadiene
Pent ach I orobenzene
Pentachloroni trobenzene
1,2,4,5-Tetrachlorobenzene
2,4-Dichlorophenoxyacetic acid
Methoxychlor
PHENOLIC WASTES
2,4-Dichlorophenol
2,6-Dichlorophenol
HYDROCARBON AND HETEROCYCLIC WASTES
Acetone
Ethyl acetate
Methyl ethyl ketone
Methyl isobutyl ketone
(continued)
4 210
13 22 - 230
13
4
13
13
4
13
14
13
4
13
4
3
9
11
13
5
4
5
6
8
11
1
14
120 - 1,800
51 - 65
24
1/300
62-88
0.35 - 17
0.35 - 17
50,000 - 190,000
420
140
430 - 500
0.081 - 0.095
<50 - 81
<0.05 - 21,000
0.055
<250
<1,000 - 10,000
200 - 600
<500
<2.0 - 10
2,200
0.016
52,000
Concentration In Ash
(ppm)[# of sample sets]**
<10 [6]
<0.31 [11, <0.33 [2], <0.36 [1]
<0.31 111, <0.33 [21, <0.36 [1]
<10 [6]
<0.31 [11, <0.33 [2], <0.36 [1]
<0.33 [31, <0.36 [1J
<5.0 [61
0.021 [1], <0.2 [3]
<0.002 [21. 0.067 (11, 0.23 [1]
<0.013 [41
<5.0 [6]
<0.31 [11, <0.33 [21, <0.36 [1]
<5.0 [6]
<0.05 [71
<0.01 [3]
<0.01 [6]
<0.01 [31, 0.02 [11
<2.0 [31
<10 [6]
1100 (11, 780 [1], 460 111
385 [1], 54011], 640 [1], 380 [1],<50m,<50m
<0.025 [51
<0.010 [6]
<10 [3]
<0.020 [4]
Concentration In Scrubber Water
(ppm)[# of sample sets]**
<0.01 [6]
<0.01 [21, <0.011
<0.01 [21, <0,011
<0.01 (61
<0.01 [21, <0.011
<0.01 [21, <0.011
<0.005 [61
[2]
[2]
121
[2]
0. 0041 [11,0. 0069(1], 0.0074(11,0. 011 [1]
<0.00013 [4]
<0.0001 [4]
<0.005 [6]
<0.01 [2], <0.011
<0.005 [6]
<0.05 [6]
<0.01 [4]
<0.01 [6]
<0.01 [41
<0.002 [7], 0.036
0.019 [1], 0.020
<0.01 [6]
<0.01 [10]
<0.050 [61
<0.010 [51. 0.014
<0.01 [6]
<0.01 [6]
<0.01 [4]
[2]
•
HI.
[1]
11]
* - Treatment tests are identified by number in Table 4-1. Data from Tests 3, 5, and 6 were not used to calculate treatment standards.
** - Number in brackets indicates the number of sample sets for which that value was reported.
-------
Table C-1 (Continued)
WASTE CONSTITUENTS DETECTED IN THE UNTREATED OR TREATED WASTES IN ONE OR MORE OF THE FOURTEEN INCINERATION TESTS
Waste BOAT
Code Number Waste Constituent
WASTES OF A PHARMACEUTICAL NATURE
U141 117 Isosafrole
PHENOLIC WASTES
P020 73 2-sec-Butyl-4,6-dinitrophenol
U052 81 o-Cresol
U052 82 Cresol (m- and p- isomers)
U188 142 Phenol
<"> POLYNUCLEAR AROMATIC WASTES
U018 59 Benz(a)anthracene
U022 62 Benzo(a)pyrene
U050 80 Chrysene
Detected In
Treatment
Test Number*
14
14
4
8
2
4
8
10
11
14
1
2
7
8
11
1
2
8
11
1
2
7
8
11
Concentration In
Untreated Waste
35,000
77.000
20
894 - 1,026
2,400 - 3,900
78
894 - 1,026
0.010
1,842
13,000
1.900 - 3.400
4,000 - 4,600
<20 - 29
5,400 - 7,500
<0.351 - 0.89
<500 - 940
1,600 - 1,900
3,800 - 5,400
<0.351 - 0.60
1,900 - 3,600
4,100 - 4,800
<20 - 51
4,700 - 6,500
<0.351 - 1.06
Concentration In Ash
(ppm)[# of sample sets]**
<0.36 [1], <0.33 [3]
<0.33 [3], <0.36 [1]
<2.0 [61
<1.0 [5]
<0.10 [6]
<2.0 [61
<1.0 [51
<1.0 [4]
<0.333 [5], <0.351 [11
<0.33 [31, <0.36 [1]
<0.5 [31
<0.52 [7]
<0.2 [6]
<1.0 [5]
<0.333 [51, <0.351 [1]
<0.5 [3]
<0.17 [7]
<1.0 [5]
<0.333 [51. <0.351 [1]
<0.5 [3]
<0.17 (71
<0.2 [6]
<1.0 [5]
<0.333 [5], <0.351 [1]
Concentration In Scrubber Water
(ppm)[# of sample sets]**
<0.013 [4]
<0.013 [1]
<0.002 [6]
<0.010 [61
<0.002 [6]
<0.002 [6]
<0.010 [61
0.015 [11. 0.017 [2], 0.019 [1],
0.022 [1], 0.023 [1]
<0.0121 11], <0.0116 [11, <0.0108 [1],
<0.0104 [11, <0.0106 11], <0.0107 [1]
<0.013 [4]
<0.010 [4]
<0.008 [7]
<0.01 [6]
<0.010 [8]
<0.0104 [11. <0.0106 [11. <0.0107 [1] .
<0.0108 [1], <0.0116 11], <0.0121 [1]
<0.010 [4]
<0.003 [7]
<0.010 [8]
<0.0104 [I], <0.0106 [1], <0.0107 [1] ,
<0.0108 [1], <0.0116 [1], <0.0121 [1]
<0.010 [4]
<0.003 [7]
<0.010 [6]
<0.010 [8]
<0.0104 [1], <0.0106 [1], <0.0107 [1],
<0.0108 [1], <0.0116 [1], <0.0121 [1]
* - Treatment tests are identified by number in Table 4-1. Data from Tests 3, 5, and 6 were not used to calculate treatment standards.
** - Number in brackets indicates the number of sample sets for which that value was reported.
-------
Table C-1 (Continued)
WASTE CONSTITUENTS DETECTED IN THE UNTREATED OR TREATED WASTES IN ONE OR MORE OF THE FOURTEEN INCINERATION TESTS
Waste BOAT
Code Number Waste Constituent
Detected In
Treatment
Test Number*
s::s====s:==========:s=====:===.=======::===2:====^========================2
Concentration In
Untreated Waste
(ppm)
Concentration In Ash
(ppn)rj of sample sets]
Concentration In Scrubber Water
(ppm)[# of sample sets]**
POLYNUCLEAR AROMATIC WASTES (continued)
U051 121 Creosote - Naphthalene
139 Creosote - Pentachlorophenol
141 Creosote - Phenanthrene
O
I
145 Creosote - Pyrene
43 Creosote - Toluene
215/ Creosote - Xylenes (total)
216/
217
1
2
4
7
8
lOl 1
1
2
4
7
8
11
1
2
7
8
1
2
3
4
5
6
7
8
9
10
13
14
1
2
3
5
7
8
10
26,000 - 51,000
29,000 - 43,000
314 - 470
93 - 170
63,000 - 81,000
<1,000 - 2,300
28,000 - 42,000
29,000 - 41,000
11 - 21
77 - 120
15,000 - 41.000
<0.351 - 1.27
9,200 - 15,000
12,000 - 17.000
31 - 74
5,900 - 9,700
10 - 41
100 - 170
2.3 - 3.6
<2,000
<2.0 - 5.0
201 - 2,000
22 - 120
5.0 - 152
<25 - 42
5.4 - 23
<0.021
69,000
12 - 130
120 - 170
<2.0 - 7.2
<2.0
-------
Table C-1 (Continued)
WASTE CONSTITUENTS DETECTED IN THE UNTREATED OR TREATED WASTES IN ONE OR MORE OF THE FOURTEEN INCINERATION TESTS
Waste BOAT
Code Number Waste Constituent
POLYNUCLEAR AROMATIC WASTES (continued)
U120 108 Fluoranthene
U137 116 Indeno(1,2,3-c,d)pyrene
U165 121 Naphthalene
ORGANO-NITROGEN COMPOUND WASTES
U009 3 Acrylonitrile
U012 56 Aniline
U169 126 Nitrobenzene
U196 39 Pyridine
MISCELLANEOUS HALOGENATED ORGANIC WASTES
U025 68 Bis(2-chloroethyl)ether
U043 50 Vinyl chloride
U045 15 Chloromethane
U075 21 Dichlorodifluoromethane
U192 144 Pronamide
Detected In
Treatment
Test Number*
1
2
8
8
11
1
2
4
7
8
3
4
4
1
4
11
5
5
7
11
13
Concentration In
Untreated Waste
13.000 - 21,000
21,000 - 26,000
<982 - 12,000
2,100 - 3,100
<0.351 - 0.41
26,000 - 51,000
29.000 - 43,000
- 314 - 470
93 - 170
63,000 - 81,000
0.41 - 0.95
1.2
0.027 - 8.2
<5.0
280 - 340
<20,000
<2.0 - 40
<2.0
<14 - 310
<20,000
24,000
Concentration In Ash
(ppra)rj of sample sets]**
<0.50 [31
<0.15 [71
<1.0 [51
<1.0 [5]
<0.333 [51. <0.351 [1]
<0.50 [3]
<0.11 [7]
<2.0 [6]
<0.20 [6]
<1.0 [5]
<0.10 [7]
<5.0 [6]
<5.0 [6]
<5.0 [3]
<2.0 [6]
<0.01 [6]
<2.0 [3]
<2.0 [21. 23 [1]
<2.0 [6]
0.71 [11, 1.4 [1], 1.5 [11.
1.6 [1], 1.7 [1], 1.4 [1]
<0.33 [2], 0.36 [11, 0.31 (1]
Concentration In Scrubber Water
(ppm)[# of sample sets]**
<0.010 [4]
<0.002 [7]
<0.010 [81
<0.010 [81
<0.0104 [11. <0.0106 Ml, <0:0107 [1],
<0.0108 Ml. <0.0116 Ml, <0.0121 [1]
<0.010 [41
<0.002 [7]
<0.002 [6]
<0.010 [6]
<0.010 [8]
<0.10 [7]
<0.005 [6]
<0.005 [6]
<0.005 (51, 0.061 [1]
<0.002 [6]
<0.01 [51. 0.03 [1]
<0.002 [10]
<0.002 [9], 0.023 [11
<0.05 [6]
<0.01 [2], 0.29 [1], 0.36 [1],
0.4 [1], 0.44 [1]
<0.01 [2], <0.011 [2]
* - Treatment tests are identified by number in Table 4-1. Data from Tests 3, 5, and 6 were not used to calculate treatment standards.
** - Number in brackets indicates the number of sample sets for which that value was reported.
-------
APPENDIX D
ACCURACY CORRECTION OF DATA
D-l
-------
APPENDIX D
ACCURACY CORRECTION OF DATA
The treatment performance data and detection limit data used to
determine treatment standards were adjusted to account for analytical
interferences associated with the chemical matrices of the samples.
Generally, treatment performance data were corrected for accuracy as follows:
(1) a matrix spike recovery was determined for each BOAT List constituent; (2)
an accuracy correction factor was determined for each of the above
constituents by dividing 100 by the matrix spike recovery (percent) for that
constituent; and (3) treatment performance data or detection limit data for
each BOAT List constituent were corrected by multiplying the data for each
constituent by its corresponding accuracy correction factor. The procedure
for accuracy correction of the data is described in further detail below.
Matrix spike recoveries are developed by analyzing a sample of a
treated waste for a. constituent and then re-analyzing the sample after the
addition of a known amount of the same constituent (i.e, spike) to the sample.
The matrix spike recovery represents the total amount of constituent recovered
after spiking, minus the initial concentration of the constituent in the
sample, and the result divided by the spike concentration of the constituent.
Duplicate matrix spikes were performed for some BOAT List constituents. If a
duplicate matrix spike was performed for a constituent, the matrix spike
recovery used for that constituent was the lower of the two values from the
first matrix spike and the duplicate spike.
In cases where a matrix spike was not performed for a waste
constituent in the treatment test from which the detection limit was taken,
the matrix spike recovery from a similar constituent from the treatment test
was transferred to the constituent.
For some multi-source leachate (F039) constituents, treatment
performance data were transferred from F, D, or K wastes. In these cases,
when a matrix spike was not performed for a particular constituent, the matrix
D-2
-------
spike recovery for each constituent was derived from the average matrix spike
recoveries of the appropriate analytical fraction (e.g., volatile or
semivolatile organics) for which recovery data were available. First, the
matrix spike recoveries for all volatile or semivolatiles from the first
matrix spike were averaged. An average matrix spike recovery was then
calculated for the duplicate matrix spike recoveries. The lower of the two
average matrix.spike recoveries was used to calculate the accuracy correction
factor for the constituent.
An accuracy correction factor was determined for each constituent by
dividing 100 by the matrix spike recovery (percent) for that constituent. An
accuracy correction factor of 1.00 was used when both the matrix spike and
duplicate matrix spike recoveries exceeded 100%, so that the data were not
adjusted to concentrations below the detection limits. Matrix spike values of
less than 20% are not acceptable and were not used to correct detection
limits, nor included in calculating average matrix spike recoveries.
Table D-l presents the matrix spike recoveries obtained in each of
the 11 incineration tests. Table D-2 presents the accuracy correction of data
from the ethylene dibromide (EDB) incineration test. For accuracy correction
of data other than that from the 11 incineration tests or the EDB test, refer
to the appropriate background document. Matrix spike recoveries and accuracy
correction factors used for each U and P waste and multi-source leachate
(F039) constituent included in this document are presented in Tables 6-1
through 6 - 3.
D-3
-------
TABLE D-1
MATRIX SPIKE PERCENT RECOVERIES IN ASH FROM ELEVEN INCINERATION TESTS
O
.p-
BDAT
No. Constituent
Volatile Organics:
1 Acetonitrile
2 Acrolein
3 Acrylonitrile
4 Benzene
9 Chlorobenzene
22 1,1-Dichloroethane
24 1,1-Dichloroethylene
229 Methyl isobutyl ketone
38 Methylene Chloride
43 Toluene
45 1,1,1-Trichloroethane
47 Trichloroethylene
215-217 Total Xylenes
Semivolatile Organics:
51 Acenaphthalene
52 Acenaphthene
70 Bis(2-ethylhexyl)phthalate
73 2-sec-Butyl-4,6-dinitrophenol
76 p-Chloro-m-cresol
78 2-Chlorophenol
87 p-Oi Chlorobenzene
88 o-Di Chlorobenzene
102 2,4-Oinitrotoluene
105 Di-n-propylnitrosamine
110 Hexachlorobenzene
117 Isosafrole
127 4-Nitrophenol
130 Pentachlorophenol
142 Phenol
144 Pronamide
145 Pyrene
150 1,2,4-Trichlorobenzene
Organochlorine Pesticides:
176 gamma- BHC
181 Dieldrin
186 Heptachlor
187 Heptachlor epoxide
190 Methoxychlor
Phenoxyacetic Acid Herbicides:
192 2,4-Dichlorophenoxyacetic acid
193 Silvex (2,4.5-TP)
194 2.4.5-T
Test 1
88,88
124,120
108,108
88,84
120,120
90,95
100.105
94,94
120,120
81,82
100,90
95,105
85,80
96,100
95,100
Test 2
78,88
102,112
86,95
99,110
67. 77
0,3.4
113,88
35,68
59.53
48,46
0,0
67,62
1.2,2.6
0.0
72,65
0.0
30,30
62,75
75,88
118,145
42,69
Test 4
90.85
99.100
85.78
107,112
110,110
110,120
98,100
90,99
107,110
120,130
97,110
88.88
90,97
120,92
75,80
Test 7
88
46
96
80
76
66,63
56,57
70,70
75,76
54,52
70,70
32,31
34,34
65,65
58,53
90,86
Test 8
100,98
106,106
114,114
114,114
106,104
114,114
93,91
92,87
78,83
79.89
121.109
82.84
37,35
7,11
77,80
34.39
84,89
Test 9
102,106
104.110
100,96
100,96
106,116
116,126
41,39
47,44
41,39
40,39
48,47
46,45
33.32
30.25
41,40
46,45
41,39
Test 10
104,108
106.110
126,130
126,130
112,114
112,116
73,74
66,64
62.58
75,70
58,58
64,61
22,21
38,35
65.61
85,79
75,76
Test 11
126,130
90,108
80,122
170,222
178.216
30,88
98,135
78,102
72,90
38.100
110.118
50.90
27.64
101,122
6,82
60,90
Test 13
117,156
92,56
35,32
88,117
300,309
243.153
539,866
210.294
61,23
51.24
86.78
65,13
88,84
49.42
26.23
73.56
58,50
54.21
34,28
91,48
74,0
70.61
99.69
49,0
30,25
54.28
16.0
0,0
0,0
0.0
Test 14
103.97
115.109
75.73
48,43
120,124
109,93
109,110
109,103
92.91
60,54
78.71
41,41
90,79
53,41
29,17
71,63
53,46
74,139
44,39
77,64
77,69
70,60
92,84
73,66
36,24
88,93
0,42
0.0
0.0
0,0
* No matrix spike recovery data was collected for the ash from incineration test 12.
-------
Table D-2
ACCURACY CORRECTION OF ETHYLENE DIBROMIDE
INCINERATION TREATMENT PERFORMANCE DATA
Average
Accuracy Accuracy-
Matrix Correction Accuracy- Corrected
Uncorrected Data (ppm) Spike Factor Corrected Data (ppm) Data (ppm)
BOAT List Sample Set Sample Set
Constituent #1 #2 #3 #1 #2. #3.
Ethylene 555 92.5% 1.08 5.41 5.41 5.41 5.41
Dibromi.de
(1,2 -DIbromoe thane)
Source: EDB Test Burn Program Emissions Test Results (Reference 18).
-------
APPENDIX E
VARIABILITY FACTOR CALCULATIONS
E-l
-------
APPENDIX E
VARIABILITY FACTOR CALCULATIONS
As noted in Section 6.1, the variability factor accounts for the
variability inherent in treatment system performance, treatment residual
collection, and treatment sample analysis. For more information on
calculation of variability factors, see EPA's Methodology for Developing BOAT
Treatment Standards (Reference 2).
A variability factor was calculated for a constituent when the test
from which the detection limit was transferred contained the constituent at
concentrations above the detection limit in the treatment residual (ash). The
variability factor and the data used to calculate it are shown in Table E-l
for U240 nonwastewaters. For some multi-source leachate (F039) constituents
for which treatment performance data were transferred from F, D, or K wastes,
a variability factor was calculated. For these constituents, the variability
factor calculations can be found in the background document for the waste from
which data were transferred.
E-2
-------
Table E-l
VARIABILITY FACTOR CALCULATION FOR
U240 NONWASTEWATERS
INPUT DATA:
Constituent:
BOAT Number:
Accuracy Correction Factor:
Unadjusted
Value (ppm)
1
2
3
4
0.021
0.2
0.2
0.2
2,4-Dichlorophenoxyacetic acid
192
5.00
A or PL
A
DL
DL
DL
Adjusted
Value (ppm)
0.105
1.0
1.0
1.0
In of
Adjusted
Values
-2.25379
0
0
0
RESULTS:
Mean of Adj Values: 0.7763
Mean of Ins: -0.5634
STD of Ins: 1.1269
C99: 7.8634
VF: 10.1300
A - Actual value detected in treatment residual.
DL - Detection limit (not detected above the detection limit in the treatment
residual).
E-3
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