U.S. Environmental Protection Agency
Office of Solid Waste
Toxicity Characteristic
Training Course
1990
Parts l-IV
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SOMETHING NEW UNDER RCRA
The U.S. Environmental Protection Agency (EPA) has developed a new rule that broadens the number of
toxic wastes regulated by EPA. The new Toxiciry Characteristic (TC) Rule will strengthen the hazardous waste
regulatory program under the Resource Conservation and Recovery Act (RCRA), thereby providing better
protection of human health and the environment Central to this new rule is an expansion of the list of
constituents that must be considered when determining whether a waste is hazardous due to its toxicity.
(Toxiciry is one of the four characteristics used by EPA to determine whether a waste is hazardous.) An
improved test for determining potential toxicity is another important component of the new rule. As a result of
these changes, more chemical waste will be determined hazardous - and more small businesses will be covered
under the RCRA hazardous waste regulatory program.
WHAT is theTC Rule?
The TC Rule includes a set of regulatory levels used to determine if waste is hazardous based on its toxicity.
EPA bases all regulatory levels for hazardous chemicals on health-based concentration thresholds and a
dilution/anenuation factor specific for each chemical. A concentration threshold indicates how much of the
chemical adversely affects human health, while the dilution/attenuation factor indicates how easily the chemical
could seep into ground water, possibly contaminating drinking water supplies. The levels set in the TC rule
were determined by multiplying the health-based number by a generic dilution/attenuation factor of 100. The
resulting TC levels will be published in the Code of federal Regulations (40 CFR 261.24). Under the new rule,
companies that produce or use the constituents listed below must determine the amount of the chemical present
in their waste. If testing is required, they must use a leaching test called the TCLP (Toxicity Characteristic Leaching Proce-
dure). The TCLP is a modified form of the old Extraction Procedure (EP), and is more precise and easier to perform.
WHO is Affected by the Rule?
If a business uses any of the constituents listed below, they must determine whether the chemicals are
present above the levels specified in the new regulation. If so, that waste is hazardous under the new rule, and
is considered a TC waste.' Regulatory levels remain the same for the eight metals and six pesticides identified
as hazardous wastes under the old EP toxicity characteristic
What's New: Companies that produce or use the constituents listed below must determine the levels present in their
waste sample extract or leachate, based either on their knowledge of their processes or by application of the TCLP.
Old EP Constituents
Arsenic
Barium
Cadmium
Chromium
Lead
Mercury
Selenium
Silver
Endrin
Londane
Methoxychlor
Toxaphene
2,4-Dichlorophenoxycetic acid
2,4,5-Trichlorophenoxypropionic acid
New Organic Constituents
Benzene
Carbon tetracholoride
Chlordane
Chlorobenzene
Chloroform
m-Cresol
o-Cresol
p-Cresol
1,4-Dichlorobenzene
1,2-Dichloroethane
1,1-Dichloroethylene
2,4-Dinitro toluene
Heptachlor (and its hydroxide)
Hexachloro-13-butadiene
Hexachloro benzene
Hexachloroe thane
Methyl ethyl ketone
Nitrobenzene
Pentachlorophenol
Pyridine
Tetrachloroethylene
Trichloroethylene
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
Vinyl chloride
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Generators are legally responsible for determining whether they produce hazardous wastes. Tests for any
hazardous characteristic (toricity, ignitability, reactivity, or corrosivity) can be conducted at analytical laboratories
or in-house. State waste program officials can provide information on licensed laboratories. If any waste is
determined to be hazardous, the generator must follow the requirements established under RCRA for the
transport, treatment, storage, and disposal of hazardous waste. Under this new rule, many treatment, storage,
and disposal facilities will be required to apply for new or modified RCRA permits if they accept TC waste.
Generators should, therefore, be sure to work only with EPA-permitted handlers.
WHEN Does the Rule Take Effect?
EPA published the new rule on March 29, 1990. Small quantity generators (those that produce 220 to 2,200
Ibs of waste in any calendar month) have one year from that date to comply; generators that produce 2,200 Ibs
or more in any month have six months from the date of publication to comply. Generators covered by the new
rule must:
Notify EPA that they produce a TC waste.
Obtain an EPA ID number.
Fill out a manifest for shipping.
Use transporters that have EPA identification numbers.
Use permitted treatment, storage, and disposal facilities.
Not store the waste more than 180 days (or 270 days if the waste
is being shipped more than 200 miles).
These procedures apply to all hazardous waste, whether it is considered hazardous because of its toxicity or any
other hazardous characteristic
For More Information . . .
Call EPA's RCRA Hotline (800-424-9346, or TDD 800-553-7672 for the hearing impaired) for a copy
of the Federal Register notice of the rule, a TC rule fact sheet, and compliance guidelines for affected
industries. The Hotline answers technical and general questions regarding RCRA from 8:30 am to 7:30
pm EST, Monday through Friday excluding federal holidays.
Ask the RCRA Hotline for Does Your Business Produce Hazardous Waste (EPA/530-SW-90-027). This
publication provides industry-specific waste stream and waste management information. The brochure
also lists state and regional hazardous waste program contacts, and advises businesses whom to call
regarding additional state regulations that may apply to hazardous waste disposal. Some trade
associations will also distribute the brochure.
Call EPA's Small Business Ombudsman Hotline (800-368-5888, or 557-1938 in Washington, D.C.) for
questions specific to small businesses.
Refer to the Code of Federal Regulations, 40 CFR Part 261, for the applicable RCRA regulations.
That section details the listed hazardous wastes, describes the hazardous characteristics, and specifies
test methods to be used.
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COURSE EVALUATION
TOXICITY CHARACTERISTIC WORKSHOP
1. What were the strengths of this course?
2. What were the areas of this course that could be improved?
3. Were there topic areas included that should not be? What topic areas should
be included that were not?
4. Other Comments
(please use back if you need additional space to comment)
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FACTS AND FIGURES
ON THE TOXiCITY CHARACTERISTIC (TO RULE
Whdt the Rule Does: Adds 25 chemicals to the eight metals and six pesti-
cides on the existing list of constituents regulated under RCRA. The rule also
establishes regulatory levels for the new organic chemicals listed, and re-
places the Extraction Procedures leach test with the Toxicity Characteristic
Leaching Procedure.
When It Takes Effect: Generators must comply with this regulation within
six months of the date of notice in the Federal Register; small quantity gen-
erators must comply within one year.
Who It Affects: The rule will bring waste above regulatory levels into the
system primarily from the following industries:
Major Industrial Sectors Analyzed
For the Regulatory Impact Analysis
Organic Chemicals
Petroleum Refining
Pharmaceuticals
Pipelines, except Natural Gas
Plastics Materials and Resins
Pulp and Paper
Rubber and Miscellaneous Plastics Products
Synthetic Fibers
Synthetic Rubber
Textile Mills
Wholesale Petroleum Marketing
Potentially Affected Industries:
Generators: 15,000-17,000
New Treatment, Storage, and Disposal Facilities (TSDFs): 200-400, in addi-
tion to the existing 5,000 TSDFs.
Estimated Economic Savings: Approximately $3.8 billion in damage to
ground water resources avoided.
Estimated Quantity of Waste Affected: Some 1.8 million metric tons per
year of non waste waters, which account for most of the cost, may be subject to
the rule. Additionally, 700 million metric tons of wastewater may also be
affected.
March 1990
A EPA
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OUTREACH MATERIAL DESCRIPTIONS
(1) Large Quantity Generator (LQG) Brochure
Describes TC impacts specific to "Large Quantity
Generators", and how LQGs can comply with the new
regulation. Includes example of waste minimization
techniques. (Targets LQGs)
The New Toxicity Characteristic Rule; Information and
Tips for Generators (EPA/530-SW-90-028).
(2) Small Quantity Generator (SQG) Brochure
Includes basic information about RCRA, HW manifests,
and EPA Regional and state contacts. Includes example
of waste minimization techniques. (Targets SQGs;
especially appropriate for newly regulated generators)
Does Your Business Produce Hazardous Waste? Many Small
Businesses Do (EPA/530-SW-90-027).
(3) Industry-specific Sheets (18)
Each sheet includes information about the waste stream
that is generated by specific industries, and outlines
the management practices called for. (Targets LQGs and
SQGs)
Vehicle Maintenance (EPA/530-SW-90-027A).
Drycleaning & Laundry (EPA/530-SW-90-027B).
Furniture/Wood Refinishing (EPA/530-SW-90-027C).
Equipment Repair (EPA/530-SW-90-027D).
Textile Manufacturing (EPA/530-SW-90-027E).
Wood Preserving (EPA/530-SW-90-027F).
Printing & Allied Industry (EPA/530-SW-90-027G).
Chemical Manufacturers (EPA/530-SW-90-027H).
Pesticides End-users (EPA/530-SW-90-027I).
Construction (EPA/530-SW-90-027J).
Railroad Transport (EPA/530-SW-90-027K).
Educational/Vocational (EPA/530-SW-90-027L).
Laboratories (EPA/530-SW-90-027M).
Metal Manufacturing (EPA/530-SW-90-027N).
Pulp & Paper Industry (EPA/530-SW-90-0270).
Formulators (EPA/530-SW-90-027P).
Cleaning & Cosmetics (EPA/530-SW-90-027Q).
Leather/Leather Products (EPA/530-SW-90-027R).
Hazardous Waste Manifest (EPA/530-SW-90-027S).
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(4) Waste Minimization Booklet
Defines waste minimization, emphasizes its importance
to successful waste management, and highlights several
case studies. (Appropriate for all industry)
Waste Minimization; Environmental Quality with
Economic Benefits (EPA/530-SW-87-026) October 1987.
(5) Permit Modification Brochure
Outlines the new RCRA permit modification requirements
for Class 1, 2, and 3 modifications. (Targets permitted
facilities)
Modifying RCRA Permits (EPA/530-SW-89-050) September
1989.
(6) Used Oil Brochures
A series of brochures emphasizing the importance of
used oil recycling. (Appropriate for facilities that
use oil in industrial processes or services)
How to Set Up a Local Program to Recycle Used oil
(EPA/530-SW-89-039A) May 1989.
Recycling Used Oil; What Can You Do? (EPA/530-SW-89-
039B) June 1989.
Recycling Used Oil; 10 Steps to Change Your Oil
(EPA/530-SW-89-039C) June 1989.
Recycling Used Oil; For Service Stations and Other
Vehicle-service Facilities (EPA/530-SW-89-039D) June
1989.
(7) FRN Reprint
Copy of the Notice which appeared in the Federal
Register; includes preamble and rule. (Appropriate for
all affected industries)
Federal Register. Vol. 55, No. 61, Part II, Thursday,
March 29, 1990.
HOW TO OBTAIN:
EPA Regional personnel can obtain these publications by calling
the RCRA Docket at FTS/202-475-9327.
Others can obtain these publications by calling the
RCRA/Superfund Hotline at 1-800-424-9346 or 202-382-3000.
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TOXICITY CHARACTERISTIC VIDEO PRESENTATION FOR THE REGULATED
COMMUNITY.
As directed in the 1984 Hazardous and Solid Waste
Amendments (HSWA), the Environmental Protection Agency (EPA)
has promulgated the final rule of the Toxicity
Characteristic. The Toxicity Characteristic (TC) was
promulgated on March 29, 1990 (see 55 FR 11798). OSW plans
to use video as one of the methods for informing the public
of the TC final rule.
The development and use of a video is a new approach
for OSW for providing outreach and communication support to
the regulated community impacted by a major final rule. The
videotape is potentially the most important part of the
outreach effort. The video insures a timely and standardized
method for delivering information to the public.
The purpose of the video is to advise the public of the
promulgation, the environmental benefits, and the generator
and treatment, storage, disposal facility (TSDF)
responsibilities that result from the TC final rule. As
stated earlier, the audience for this video is the regulated
community, especially those newly regulated by the TC.
There are four key messages that the video will get
across to the public. They are: the purpose for the TC
(environmental protection), the responsibilities of the
generators and TSDFs, that pollution prevention and waste
minimization are viable waste management strategies that
should be explored, and who one can contacted for more
information.
EXPECTED COMPLETION DATE: July 1990
DISTRIBUTION: To be sent to Regional contacts for the TC
workshop, in addition to Chambers of Commerce, and
others not yet specified.
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TOXICITY CHARACTERISTIC
TRAINING COURSE
Presented by:
Characterization and Assessment Division
Office of Solid Waste
U.S. Environmental Protection Agency
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Morning
AGENDA
Part One: Overview of the Toxicity Characteristic
9:00 - 10:00 a.m.
Part Two: Pollution Prevention and the Toxicity
Characteristic
BREAK
Part Three: Relationship of Toxicity Characteristic
to Other RCRA Subtitle C Programs
10:00 - 10:30 a.m.
10:45 - 11:30 a.m.
Part Four: Relationship of Toxicity Characteristic
to Other Laws
11:30 - 12:00 noon
Afternoon
Part Five: Universe of Affected Facilities
Part Six: Implementation of the Toxicity
Characteristic: Permitting
1:00 - 1:30 p.m.
1:30 - 4:00 p.m.
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Appendices To the Training Course
Appendix A Constituents Regulated Under the Toxicity Characteristic
Appendix B Summary of Requirements Under the Toxicity Characteristic
Appendix C Toxicity Characteristic Permitting Strategy
Appendix D Toxicity Characteristic Federal Register Notice
Appendix E Key Contacts for More Information on the TC
Appendix F Toxicity Characteristic Outreach Material
Appendix G Toxicity Characteristic Fact Sheet
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PART ONE
Overview of the
Toxicity Characteristic
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Part One: Overview of TC
INTRODUCTION
Topics covered in Part One include:
Background of RCRA Hazardous Waste Definition
Background on EP Toxicity Characteristic
Proposed Toxicity Characteristic
Toxicity Characteristic Final Rule
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Part One: Overview of TC
BACKGROUND ON HAZARDOUS WASTE DEFINITION 1-1
RCRA §3001 requires EPA to define "hazardous wastes"
Section 3001 (a) - criteria for identifying and listing hazardous wastes
Section 3001 (b) - characteristics of hazardous waste
EPA has promulgated 218 specific listings and four hazardous waste
characteristics
One characteristic was extraction procedure (EP) toxicity
EPA has promulgated 218 wastes as listed hazardous wastes since 1980.
New listings added each year
Listings may be industry- and process- specific (K-wastes) or may cover
all wastes fitting description (F-wastes).
EPA identified and promulgated four hazardous waste characteristics in 1980:
Ignitability
Corrosivity
Reactivity
Extraction Procedure (EP) Toxicity Characteristic
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Part One: Overview of TC
BACKGROUND ON HAZARDOUS WASTE DEFINITION 1-2
Hazardous waste listings
21 non-specific sources (e.g., F001-F005 spent solvents such as
tetrachloroethylene)
94 specific sources (e.g., K015, still bottoms from distillation of
benzyl chloride)
103 commercial chemical products (P and U wastes), off-specification
products, residues, debris from spills, and containers
Exclusions and exemptions from hazardous waste listings
For example, household hazardous waste
Subpart D of 40 CFR Part 261 lists hazardous wastes by:
Non-specific sources (F-wastes);
Specific sources (K-wastes); and
Commercial chemical products, off-specification products, residues, debris
from spills, and containers that stored acute hazardous chemicals and
were not decontaminated (P and U wastes).
The listed wastes are hazardous unless:
Excluded under 40 CFR 260.20 and 260.22, petitions to modify or revoke
hazardous waste listings;
Meet exclusions and exemptions in §§261.2 and 261.4
Household hazardous wastes
Large volume-low toxicity wastes
Trivalent-chromium wastes from leather tanning industry
Arsenically-treated wood products
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Part One: Overview of TC
BACKGROUND ON HAZARDOUS WASTE DEFINITION
1-3
Criteria for listing hazardous wastes
C
«t4
Of
Tojdcanu
Cmcentratlon
Toxicant
Waste
C
Nature of
Toidctty
on of |
"J
List Wast*
As Hazardous
Persistence
Bloaccumula
Potential _
Toxicants
tanoM
atton
J
C
Plausible
Types of
Improper
Management
^-k,
Decision Team
*--^
\
Quantities
Waste
"J
Not Ust Waste
As Hazardous
The decision to list or not list a waste as hazardous is made by a team of EPA
experts who consider the following criteria:
Nature of toxicity
Concentration of toxicant in waste
Migration potential of toxicants
Persistence and bioaccumulation potential of toxicants
Plausible types of improper management
Quantities of waste
If waste is not listed, still may be a hazardous waste if it exhibits a
characteristic.
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Part One: Overview of TC
BACKGROUND ON HAZARDOUS WASTE DEFINITION
1-4
Hazardous waste characteristics
Ignitable
Corrosive
Reactive
EP or TC Toxic
A solid waste is a hazardous waste whether listed or not if the waste exhibits
any of these characteristics:
Ignitability - waste that has a flash point of lower than 140 degrees F, or
is capable of causing fire (40 CFR 261.21)
Corrosivity - waste with a pH less than 2 or more than 12.5, or a waste
that corrodes steel at a rate greater than 0.25 inch annually (40 CFR
261.22)
Reactivity - waste that is explosive, capable of reacting violently when
exposed to water, or generates toxic gas when exposed to water or other
liquids that are mildly acidic or alkaline (40 CFR 261.23)
EP Toxicitv (now amended by TC rule) - waste contains any of the 14
identified contaminants in excess of the allowable maximum concentration
(40 CFR 261.24)
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Part One: Overview of TC
BACKGROUND ON EP TOXICITY CHARACTERISTIC 1-5
EP Toxicity Characteristic promulgated in May 1980
14 constituents regulated
-- Applied DAF of 100 to the NIPDWS
Extraction Procedure (EP) leach test used to evaluate hazardousness of
waste
Waste is hazardous based on potential threat to human health and the
environment, if improperly managed
EPA developed the toxicity characteristic (TC) because:
- Mandate by HSWA
EP did not consider organics
Limitations of EP test (j)i<-> ns4y^'~\ ^/ »<>>'*:i**]
EP Toxicity Characteristic identifies wastes with potential to leach toxic
constituents from wastes into ground water unless subject to Subtitle C
controls.
Constituents are extracted in a procedure that simulates the leaching
action that occurs in landfills.
National Interim Primary Drinking Water Standards (NIPDWS) were
benchmarks for toxicity.
EP levels = 100 times the NIPDWS
14 contaminants were identified:
METALS INSECTICIDES HERBICIDES
arsenic endrin 2,4-D
barium lindane 2,4,5-TP
cadmium methoxychlor
chromium toxaphene
lead
mercury
selenium
silver
EP Toxicity Characteristic was promulgated in May 1980.
Congress was concerned that some wastes posing a threat to human health
and the environment were not being brought into the hazardous waste system.
Organic constituents other than listed spent solvents
EP test assessed risks of only a few of hazardous constituents
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Part One: Overview of TC
BACKGROUND ON EP TOXICITY CHARACTERISTIC
7-6
EP toxicity characteristic mismanagement scenario
Municipal Landfill
>*-
Hazardous waste characteristics are designed to identify solid wastes that pose
a threat to human health and the environment when improperly managed
(RCRA §1004(5)).
Reasonable worst-case assumption of hazardous wastes co-disposed with
municipal solid wastes (MSW) ensures that hazardous wastes will be
adequately identified, regardless of the manner in which they are actually
managed.
Mismanagement scenario guided the refinement of the leaching procedure and
the development of inputs for the subsurface fate and transport model.
One set of regulatory levels applies to all wastes.
No exceptions for wastes not co-disposed with MSW (e.g., monofills,
surface impoundments).
Management-based approach (i.e., different standards based on how
wastes are managed) could complicate effective implementation of RCRA
regulations.
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Part One: Overview of TC
PROPOSED TOXICITY CHARACTERISTIC 1-7
EPA proposed Toxicity Characteristic on June 13, 1986
Add 38 organic constituents (and kept 14 EP constituents)
Develop regulatory levels based on subsurface fate and transport model
Replace EP test protocol with toxicity characteristic leaching procedure
(TCLP)
Several rounds of subsequent comments on proposal
Proposed rule (51 FR 21648) identified 38 organics in addition to existing 14
compounds that could cause a waste to be hazardous.
Selection of constituents was based upon availability of:
Health effects data
Physical/chemical data to allow fate and transport modeling
Unlike the existing EP, dilution/attenuation factors (DAFs) for organics are
compound-specific and derived from a ground-water transport model.
Modeled scenario is a municipal landfill.
Model predicts reduction in concentration of constituents as they migrate
from the landfill to a drinking water well.
Reduction is expressed as a constituent-specific DAF.
Proposed rule described the toxicity characteristic leaching procedure (TCLP).
Development of TCLP was driven by the need to address the leaching of
organic compounds.
In evaluating alternatives, EPA considered whether the test was:
Economical
Easy to perform
Rugged
Precise for improved reproducibility
TCLP was already used to demonstrate that a waste meets the best
demonstrated available technology (BOAT) standards (Appendix I to 40
CFR Part 268).
In some cases, the TCLP may be more aggressive than EP for metals.
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Part One: Overview of TC
TOX/C/TY CHARACTERISTIC FINAL RULE 1-8
EPA promulgated final TC on March 29, 1990
Major provisions of TC:
Adds 25 of 38 organic constituents to 14 EP constituents (39 total)
Uses subsurface fate and transport model to develop DAF to calculate
regulatory levels
Replaces EP with TCLP
Appendix A of this course lists all of these constituents
EPA promulgated final TC on March 29, 1990 (effective September 25, 1990).
Adds 25 new organic constituents to the existing 14 compounds.
Establishes regulatory levels for the organic constituents based on
health-based concentration limits and a DAF developed using the
subsurface fate and transport model.
All newly regulated constituents are nonhydrolyzing or minimally
hydrolyzing.
Pentachlorophenol is regulated in TC, but a new level will be
reproposed. Reproposal will be to set a more stringent regulatory
level.
Replaces EP test with TCLP test
TCLP is designed to determine mobility of organic and inorganic
contaminants in liquid, solid, and multiphasic wastes.
Two proposed modifications for use of TCLP in TC and LDRs: (1) a
detailed method flow chart to explain how analysts perform the test;
and (2) information on new equipment suppliers and availability of
testing equipment.
Only use the gas chromatography/mass spectroscopy (GC/MS)
method until HPLC method is adopted.
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Part One: Overview of TC
CONSTITUENTS OF CONCERN 1-9
Original EP Toxicity Characteristic
EPA HW1
Number
D004
D005
D006
D007
D016
D012
D008
D013
D009
D014
D010
D011
D015
D017
Constituents -- all kept under TC
^ J^ *""
Constituent ^^^^j. -^^
Arsenic
Barium
Cadmium
Chromium
2,4-D
Endrin
Lead
Lindane
Mercury
Methoxychlor
Selenium
Silver
Toxaphene
2,4,5-TP (Silvex)
Hazardous waste number
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Part One: Overview of TC
CONSTITUENTS OF CONCERN 1-10
New Toxicity Characteristic Constituents
EPA HW1
Number Constituent
D018 Benzene
D019 Carbon tetrachloride
D020 Chlordane
D021 Chlorobenzene
D022 Chloroform
D023 o-Cresol
D024 m-Cresol
\ D025 p-Cresol
DQ26&~> 1 ,4-Dichlorobenzene
1 ,2-Dichloroethane
1 ,1 -Dichloroethylene
00290** 2,4-Dinitrotoluene
DQ3Q<&> Heptachlor (and its hydroxide)
D031 1J3l Hexachlorobenzene
1 Hazardous waste number
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Part One: Overview of TC
CONSTITUENTS OF CONCERN Page 1-11
New Toxicity Characteristic Constituents (cont'd)
EPA HW1
Number Constituent
Hexachloro-1,3-butadiene
D03-3" ° * V Hexachloroethane
0034^^" Methyl ethyl ketone
DQ35- #*<* Nitrobenzene
DQ36- ° i7 Pentachlorophenol
DQ3J-V*? Pyridine
DQ38 *? ^ Tetrachloroethylene
Trichloroethylene
2,3,5-Trichlorophenol
2,4,6-Trichlorophenol
0042-^3 Vinyl Chloride
Hazardous waste number
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.,
Part One: Overview of TC iJrOft f-
CONSTITUENTS OF CONCERN ^' ' 1-12
7 of original 38 constituents deferred for future action because:
Subsurface model predicts high DAFs for hydrolyzing constituents
Model does not account for toxicity of byproducts generated
EPA has developed DAFs for nondegrading constituents, but is still improving
its approach for developing DAFs for constituents expected to hydrolyze during
transport.
EPA is currently determining which byproducts result from hydrolysis, and is
developing protocol for evaluating the amount of byproduct for hydrolyzing
constituents
7 hydrolyzing constituents listed in June 13, 1986 proposed rule will
eventually be added to TC:
Acrylonitrile
Bis (2-chloroethyl) ether
Methylene chloride
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1,2-Trichloroethane
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Part One: Overview of TC
CONSTITUENTS OF CONCERN 1-13
6 of original 38 organic constituents deferred for future action because:
Steady-state assumption may be inappropriate for constituents that are:
Slow moving
Relatively low toxicity
Relatively low concentration in waste
EPA has determined that the steady-state condition assumed in the subsurface
fate and transport model is valid for most constituents.
Model may over predict the concentration at the down gradient well for
some proposed constituents.
6 constituents were deferred because the steady-state condition was not
achieved:
Carbon disulfide
1 ,2-Dichlorobenzene
Isobutanol
Phenol
2,3,4,6-Tetrachlorophenol
Regulatory levels will eventually be promulgated or reproposed for these
constituents. (Refer to Appendix A of training course for composite list of
deferred constituents.)
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Part One: Overview of TC
BASIS FOR REGULATORY LEVELS
1-14
Drinking water standards (NIPDWS) used as basis for original EP
Chronic toxicity reference levels (CTRLs) used for revised TC
CTRLs
Selection of organic constituents based on the ability to establish for each
constituent:
A chronic toxicity reference level (CTRL)
A constituent-specific DAF
CTRLs for revised TC are health-based:
Maximum Contaminant Levels (MCLs) when available
- Risk-Specific Doses (RSDs) fopSafcihogins
~~ ""^
Risk level used to set RSDs in final rule is 10~5; meaning 1 person in
a population of 100,000 is at risk of getting cancer.
RSDs will not be apportioned.
- Reference Doses (RfDs) for^norvcarcinogens ">
Estimate of the daily dose of a substance that will result in no
observed adverse effects after a lifetime of exposure.
Constituents without a CTRL were not regulated. (Refer to Appendix A of this
training course for CTRLs basis and reference levels for TC constituents.)
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Part One: Overview of TC
DILUTION/ATTENUATION FACTORS (DAFS) 1-15
DAF is expected reduction in concentration of a constituent during transport;
subsurface fate and transport model used to calculate compound-specific DAFs
DAF of 100, based on monte carlo simulation, set for final TC
M*
DAF represents expected reduction in concentration of a constituent during
transport through soil and ground-water from leachate release to exposure
point.
Unlike EP, DAFs for TC are compound-specific and/or derived from ground-
water transport model (EPACML), which includes an unsaturated zone module.
Model Assumptions:
infinite source
constant aquifer thickness
steady-state conditions
uniform, continuous ground-water flow in vertical direction
constituents in the landfill degrade
degradation in the unsaturated zone is limited to hydrolysis
well located anywhere downgradient from landfill within the areal
extent of the plume based on Subtitle D facilities
ground-water recharge based on volume of water and factors of the
aquifer
ground-water upstream of disposal site is uncontaminated
hydraulic conductivity does not vary with temperature
Data used:
surveyed landfill data (size, distance to wells, thickness of
unsaturated zone)
compound-specific hydrolysis data
soil adsorption data based on three soil categories
30 climatic ranges
Model Parameters:
ground-water velocity - ground-water pH
hydrolysis rates - recharge rate
ground-water temperature - exposure points
source penetration depth - dispersivity values
concentration of contaminant- well location
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Part One: Overview of TC
REGULATORY LEVELS 1-16
DAF x CTRL = Regulatory Level
For example, arsenic MCL = 0.05 mg/l and DAF = 100; therefore, TC
level* = 5.0 mg/l
If quantitation limit for chemical > regulatory level, then quantitation limit is
regulatory level
Existing 14 EP toxicity regulatory levels remain the same
However, leaching procedures are different; so wastes hazardous under EP
and TCLP may not be the same
DAF x CTRL = Regulatory Level
Regulatory levels are calculated in 2 steps:
The toxicity of constituents wtee8=^sieHSBddaiedtee^£ad*©Rment is
measured by health-based CTRLs.
The expected fate of constituents when released into
environment is expressed as a DAF.
Regulatory level = DAF x CTRL
Regulatory levels are based on the assumption that a population drinks 2
liters of water per day for 70 years. (Refer to Appendix A of training
course for regulatory levels of TC constituents.)
If quantitation limit > regulatory level, quantitation limit = regulatory level
The quantitation limit is the lowest level that can be reliably measured in a
laboratory.
-- 3 constituents have regulatory levels set at a quantitation limit:
2,4-dinitrotoluene, hexachlorobenzene, and pyridine.
Existing 1 4 EPTC regulatory levels remain the same, but may result in different
wastes being hazardous.
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Part One: Overview of TC
TOXICITY CHARACTERISTIC LEACHING PROCEDURE (TCLP) 1-17
TCLP test replaces EP test
Sampling for TCLP is required at the point of generation
Filtration, extraction, and/or separation of a waste to test nonvolatile organics
Bottle extraction vessel
Agitation apparatus
Filtration devices
Reagents
Zero-Headspace Extraction Vessel (ZHE) used to test volatile organics
vt ry
The TCLP, which replaces the EP, is designed to determine the mobility of both
organic and inorganic constituents present in liquid, solid, and multiphasic
wastes.
Sampling is required at the point of generation, i.e., when the waste becomes a
solid waste. A waste must be a solid waste before it can be classified as a
hazardous waste under RCRA.
EPA believes that determination of a waste at the point of generation is
appropriate for surface impoundments and consistent with other
hazardous waste regulations.
If a waste leachate contains any of the constituents at a concentration at or
above the corresponding regulatory level, the waste is hazardous.
Filtration, extraction and/or separation of a waste are used to test
nonvolatile constituents.
Zero-Headspace Extraction Vessel (ZHE) is used to test for the mobility of
volatile constituents.
The 15-step procedure for analyzing nonvolatiles and 16-step procedure for
analyzing volatiles are revised in 40 CFR Part 261, Appendix Il-Method 1311
Toxicity Characteristic Leaching Procedure (TCLP).
Wastes that have TCLP levels less than regulatory levels are not necessarily
nonhazardous. These wastes may be listed as hazardous (depending on
source or process of generation) or may exhibit another hazardous waste
characteristic.
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Part One: Overview of TC
MAKING THE TC DETERMINATION 1-18
Under TC, generators remain responsible for determining whether waste is
hazardous
If waste is not excluded, generator must determine whether the waste exhibits
any hazardous waste characteristics
Determination may be based on testing or knowledge
If waste is hazardous and subject to Subtitle C control, generator must keep
records unless the waste is specifically excluded or managed in exempt units
Under TC, generators remain responsible for determining whether waste is
hazardous.
Generators are not required to test wastes to make this determination.
If a waste is excluded from regulation (40 CFR 261.4) or is listed (Subpart
D of 40 CFR Part 261), no further determination of hazardousness is
necessary.
If waste is not excluded, the generator must determine whether the waste
exhibits any hazardous waste characteristics, TC being one such characteristic.
Generator may determine whether waste exhibits a characteristic by (a)
testing the waste or (b) applying knowledge of the waste.
If a waste is hazardous, the generator must keep records.
Records establishing basis for TC determination must be kept at least
three years after generator handles the waste.
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PART TWO
Pollution Prevention and
the Toxicity Characteristic
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Part Two: TC and Pollution Prevention
BACKGROUND ON WASTE MINIMIZATION POLICY 2-1
Congress made waste minimization a national policy in RCRA §1003(b)
Source reduction ,
Recycling
EPA has made pollution prevention an Agency objective
Highest priority on source reduction
1986 Report to Congress on waste minimization issues
No mandatory waste minimization programs at this time
Essential component of all regulations
Congress declared waste minimization to be a national policy in RCRA
§1003(b). The section emphasizes source reduction and recycling as strategies
for managing solid waste.
Similarly, EPA has made pollution prevention an Agency objective with a high
priority on source reduction. Source reduction means reducing the volume or
toxicity of wastes before they are generated.
In 1984, reflecting increased national concern over hazardous wastes, Congress
directed EPA to report on the potential desirability and feasibility of mandatory
waste minimization techniques.
EPA's 1986 Report to Congress on waste minimization explored technical,
economic, and policy issues related to hazardous waste source reduction and
recycling. The Agency concluded that mandatory waste minimization programs
are not feasible or desirable at this time.
EPA believes that continuing analysis of data from generators and other
sources will provide the basis for a followup report to Congress later this year
on the need for statutory authority on waste minimization.
EPA is evaluating all regulations and programs for waste minimization
incentives.
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Part Two: TC and Pollution Prevention
POLLUTION PREVENTION ASSISTANCE 2-2
EPA provides technical information to industry on waste reduction
Pollution Prevention Information Clearinghouse
Electronic Information Exchange System
EPA incorporates pollution prevention into communication strategy for the TC
regulation
EPA also supports State source reduction programs
EPA is providing technical information to industry on waste reduction.
Pollution Prevention Information Clearinghouse (PPIC), a network of
people and resources throughout the United States that have direct
experience on waste reduction in many industries.
Electronic Information Exchange System, part of PPIC, a data base of
bulletins, programs, contacts, and reports related to pollution prevention.
EPA is incorporating pollution prevention into the communication strategy for
the TC regulation by providing information targeted towards small businesses
specifically and industry in general through pamphlets, industry publications,
and conferences.
The New Toxicity Characteristic Rule: Information and Tips for Generators
(EPA-530-SW-90-028)
Does Your Business Produce Hazardous Waste? Many Small Businesses
Do (EPA-530-SW-90-027)
EPA is supporting development of State programs to assist generators in waste
reduction efforts. Many States (Alaska, North Carolina, and Oregon, for
example) already provide technical assistance and waste reduction information
to industry.
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Part Two: TC and Pollution Prevention
POLLUTION PREVENTION INCENTIVES 2-3
TC incentives for pollution prevention:
Economics (increased cost of compliance)
Regulations (burdens of compliance)
Liability
Public image
Environmental concern
EPA role in increasing pollution prevention
Generators can realize real economic savings from adopting waste minimization
techniques.
Increased land disposal costs
Savings in raw materials
Avoidance of costly alternative treatment technologies
The TC alters the management of wastes that contain toxic substances at
hazardous levels by ending management in unregulated land-based units.
The high cost of compliance with RCRA Subtitle C requirements under the TC
provides the regulated community with significant incentives to rethink their
practices for managing solid wastes that contain hazardous constituents.
Regulations such as (1) the required certification of a waste minimization
program on the hazardous waste manifest and the biennial report, (2) the land
disposal restrictions and bans, and (3) the increasing permitting requirements
for waste handling and treatment, direct generators toward increased waste
reduction activities.
The potential reduction in generator liability for environmental problems at both
onsite and offsite treatment, storage, and disposal facilities, as well as for
worker safety can translate into tremendous cost savings.
Developing an effective waste minimization program can result in an improved
public image in the community and among employees.
. Waste reduction provides direct benefits related to protecting human health and
the environment from the mismanagement of hazardous wastes.
The bottom line for EPA to get across: generators can reduce waste and save
money.
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Part Two: TC and Pollution Prevention
POLLUTION PREVENTION APPROACHES
2-4
Conduct a waste minimization assessment
Select a few waste streams
Keep accurate records
Identify waste minimization techniques
Inventory Mangement
Modification of
Equipment
Production Process
Changes
Recycling and Reuse
First step in a waste reduction program is a waste minimization assessment.
EPA recommends selecting a few wastes or processes for intensive
assessment.
Generators need to keep accurate records on existing waste generation
rates and management costs, particularly for the waste streams targeted
for source reduction or recycling.
Many small businesses are turning to pollution prevention practices because of
small quantity generator regulations.
For example, a drycleaning operation reduced its solvent wastes by
regularly checking for and sealing any system leaks, a production process
change that can be practiced in all industries.
Additionally, drycleaning operation modified its equipment by installing a
conditioning system and a carbon adsorption unit to recover solvent.
EPA believes that industries have the potential to substitute less toxic source
materials in their processes as part of inventory management, and will consider
whether any technical assistance could aid industry in these efforts.
For example, low-toxicity paints can be substituted in paint application
processes, integral to many industrial operations.
Any suggestions from industries affected by the TC on how the Agency might
facilitate waste reduction efforts should be directed to the Pollution Prevention
Office, U.S. EPA, Washington, D.C. 20460.
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lil
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PART THREE
Relationship of Toxicity Characteristic
to Other RCRA Subtitle C Programs
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Part Three: Relationship to Other RCRA Subtitle C Programs
OVERVIEW: TC AFFECTS OTHER RCRA REGULATIONS
3-1
TC Will Have No Effect
Huantou* Wane
Ltotlngi
Wnln haurdou* by
virtue ol the "mixture" and
"derived tram" rutoe
(261.4
Exduekma
TC may affect implementation of other RCRA programs:
Corrective action and closure
Land disposal restrictions (LDRs)
Minimum technology requirements
Mixture rule exemption
Previously delisted wastes
Special waste exclusions d^
The TC will have no direct effect on the following:
Hazardous waste listings
Waste that are hazardous by the "mixture" and "derived from" rules
Wastes already excluded from regulation under §261 .4
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Part Three: Relationship to Other RCRA Subtitle C Programs
OVERVIEW: TC AFFECTS OTHER RCRA REGULATIONS
3-2
TC May Affect
"'
Land Disposal
^"-^iiinlmum^nolbfly ' -
,- . ..-. '^.r^ .><<:; > ,*** I x.
Requirements
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Part Three: Relationship to Other RCRA Subtitle C Programs
CORRECTIVE ACTION AND CLOSURE 3-3
TC increases universe of regulated and affected facilities; therefore:
Number of Subtitle C permitted and interim status facilities subject to
corrective action will increase
Number of permitted or interim status facilities deciding to close will
increase
Number of post-closure permits will increase
/) Excavated material from corrective action and closure that exhibits the TC must
be managed as hazardous waste
TC levels are not used to set clean-up levels for corrective actions or clean
closures
To the extent that the TC adds more wastes of concern or brings more
facilities under the RCRA program as hazardous waste management facilities,
additional units and facilities will be newly subject to the Subtitle C corrective
action and closure requirements.
Previously unregulated TSDFs managing TC wastes will be subject to RCRA
requirements if they do not close or change management practices (e.g.,
exempt tanks) before TC becomes effective.
Existing RCRA facilities may have to amend their closure plans to reflect newly
regulated units.
RIA estimates that at least 93 facilities will decide to close rather than seek a
permit; number that actually decides to close may be much higher.
The Subtitle C corrective action program addresses remediation of releases of
hazardous waste or constituents from facilities subject to RCRA permitting. The
TC levels are neither action levels nor cleanup standards, both of which are
developed from site-specific information gathered during the investigatory and
evaluative phases of the process.
TC constituent levels also are not related to:
health-based cleanup standards,
or "clean closure" levels
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Part Three: Relationship to Other RCRA Subtitle C Programs
LAND DISPOSAL RESTRICTIONS 3-4
Some TC wastes not immediately subject to LDRs on effective date of TC rule;
others will have LDR standards:
LDR standards will be in effect for 14 wastes previously regulated
under EP
No LDR standards for 25 new TC wastes
LDR treatment standards based on best demonstrated available technology
(BOAT); the characteristic (regulatory) levels developed using risk-based
approach
Nevertheless, for some constituents, LDR treatment standards are set at
the characteristic (regulatory) level
HSWA requires EPA to make an LDR determination for all newly listed wastes
within 6 months of publication in the Federal Register, or by the effective date
of TC. Newly listed or identified wastes are not automatically prohibited from
land disposal under LDRs if EPA fails to make this required determination
within six months (i.e., no "hammer" provisions).
EPA has set LDR standards for 14 EP characteristic constituents, which
EPA does not consider newly identified. These 14 constituents will have
to meet LDR treatment standards before land disposal on effective date of
TC rule.
The 25 new organics identified by the TC are considered newly identified
constituents and are not (yet) affected by LDRs. A separate rulemaking
will be required to set LDR standards for these constituents.
EPA will review treatability of each TC constituent independently when setting
LDR treatment standards for TC wastes. These standards may differ from
standards set for spent solvent wastes (F001-F005) based on differences in
treatability.
Since LDR treatment standards are based entirely on technology-based
standards expressed as BOAT, while TC levels are based upon health-based
allowable concentration levels and dilution/attenuation factors, the TC levels are
not the same as LDR treatment standards. However, for many of the
characteristic wastes, EPA has set the LDR treatment standards at the
characteristic (regulatory) level.
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Part Three: Relationship to Other RCRA Subtitle C Programs
MINIMUM TECHNOLOGY REQUIREMENTS 3-5
Facilities newly regulated under RCRA because of TC may need to comply with
minimum technology requirements
RCRA imposes minimum technology requirements on owners/operators of
certain landfills and surface impoundments seeking permits
HSWA requires:
Interim status waste piles, landfills, and surface impoundments to meet
certain minimum technology requirements
Surface impoundments to be retrofitted to meet minimum technology
requirements
Existing land disposal units (except surface impoundments) that already
contained wastes that exhibit the TC will not require retrofitting unless they are
expanding or are replacing units or continuing to place TC wastes in unit after
TC effective date.
The minimum technology requirements for interim status surface impoundments
are found in 40 CFR 265.221.
Surface impoundments that become regulated under Subtitle C because of the
TC rule will need to meet the minimum technology requirements by March
1994. This extension applies only to those impoundments that contain solely
the newly identified or characteristic wastes.
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Part Three: Relationship to Other RCRA Subtitle C Programs
EXEMPTION FOR TANKS 3-6
TC wastes treated in wastewater treatment tanks are exempt from hazardous
waste management standards under 40 CFR 264.1 (g) and 265.1 (c)
Generators that manage TC wastewaters in on-site surface impoundments may
switch to exempt tanks
To escape Subtitle C regulation, generators and handlers must convert their
surface impoundments to tanks prior to effective date of final rule
Facilities managing TC wastes after the effective date, even unintentionally, will
be subject to interim status standards
/ - ? r JL v
iT ** a
40 CFR 264.1 (g) and 265.1 (c) exempt treatment of hazardous wastes in
wastewater treatment units from regulation under Subtitle C.
A generator choosing to continue managing wastewaters in an on-site surface
impoundment or to manage non-wastewaters on-site will require either interim
status (and eventually a RCRA permit) or a RCRA permit modification or
change during interim status, depending on whether or not the facility is
currently a Subtitle C TSDF.
If the conversion to tanks is not complete before the effective date of the final
rule, the facility will need to apply for interim status, and the surface
impoundment will be subject to the 40 CFR Part 265 closure and post-closure
requirements.
Part VI of this course discusses implementation scenarios in more detail.
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Part Three: Relationship to Other RCRA Subtitle C Programs
MIXTURE RULE EXEMPTION 3-7
Mixture rule exemption was not modified in TC rule; mixtures of wastewaters
and certain listed spent solvents are exempt unless the wastewaters:
Exhibit a characteristic, or
Contain listed hazardous wastes not specified in the exemption
TC may bring currently exempted wastewaters under Subtitle C regulation
EPA is considering reducing mixture rule exemption levels
The mixture rule under 40 CFR 261.3(a)(2)(iv) provides an exemption from
RCRA Subtitle C regulation for mixtures of wastewaters and certain listed spent
solvents in low concentrations.
The mixture rule exemption is an exemption from the hazardous waste listings,
not the characteristics. Therefore, the mixture rule exemption is not an
exemption from the TC rule.
The mixture rule exemption ensures that mixtures of wastewaters and certain
listed spent solvents will not be considered hazardous unless they exhibit a
characteristic of hazardous waste.
EPA plans to propose in the future that the mixture rule exemption levels be
reduced so that they are equivalent to, or lower than, the TC regulatory levels.
This would clarify the mixture rule exemption and make it more consistent with
current risk information.
The TC regulatory levels are based on state-of-the-art toxicological data and
risk assessment methodologies, and are the best measures available to identify
wastewater mixtures that pose a threat to human health and the environment.
In contrast, the mixture rule exemption levels are based upon less current risk
information.
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Part Three: Relationship to Other RCRA Subtitle C Programs
PREVIOUSLY DELISTED WASTES Q#> <*** ^o, 2 *3 3-8
A waste may not be delisted if it exhibits a hazardous characteristic (e.g., the
characteristic of toxicity)
TC rule applies to already delisted wastes that exhibit the TC
These wastes no longer considered "not hazardous"
Wastes must be managed under Subtitle C
Delisting levels are generally more stringent than the final TC levels; therefore,
impact of TC rule on previously delisted wastes is expected to be minimal
Wastes "excluded" from Subtitle C regulation under the delisting program may
nevertheless be hazardous if they exhibit a hazardous characteristic (see 40
CFR 260.22). Hazardous waste characteristic levels are those above which a
waste is hazardous due to a particular property; delisting levels are those
below which a waste is not hazardous for any reason. Thus, it is reasonable
that these two levels do not coincide.
EPA has decided to use the Toxicity Characteristic model (EPACML) in place of
the model currently used in the delisting program.
Although the TC rule applies to delisted wastes, EPA does not, in general,
expect that such wastes will become hazardous because of application of the
revised TC. However, if a previously delisted waste exhibits the TC, it will again
be subject to Subtitle C requirements and the facility will have to notify EPA of
its activity.
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Part Three: Relationship to Other RCRA Subtitle C Programs
SPECIAL WASTE EXEMPTIONS 3-9
RCRA defines four special waste categories:
Mining wastes
Mineral processing wastes
Oil and gas wastes
Domestic sewage
Subtitle C may apply to special wastes on a case-by-case basis
Special waste exclusions are being reevaluated as mandated by Congress
TC may be applicable to those special wastes regulated under Subtitle C
If EPA makes a determination that any special wastes should be regulated
under RCRA Subtitle C, the Agency will at that time make a separate
determination concerning the applicability of the TC to such wastes.
After completing the studies required by RCRA Section 8002, EPA may
determine that one or more special wastes should be regulated under RCRA
Subtitle C. Such wastes would then be listed or the generators required to
determine whether the wastes exhibit a hazardous characteristic, including TC.
Bevill wastes (i.e., mineral processing) and oil and gas wastes are currently
having their regulatory status reviewed. Several formerly exempt Bevill wastes
have had their exclusion removed and are now being regulated under Subtitle
C.
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Part Three: Relationship to Other RCRA Subtitle C Programs
MIXED WASTE 3-10
Mixed waste with TC constituents is considered HSWA regulated
Therefore, EPA Regions have responsibility to implement
State mixed waste status for TC-contaminated wastes does not matter
Many generators will be small quantity generators
EPA Regions will need to issue storage permits
.'") Mixed waste regulation is not a HSWA provision. Therefore, generally, EPA will
not administer mixed waste regulations.
(} Mixed waste with TC constituents is HSWA; therefore, EPA has responsibility to
implement the RCRA program.
State status regarding mixed waste does not matter for TC mixed wastes.
EPA will administer program in States that both have and do not have
mixed waste authorization.
Many generators of mixed waste may be small quantity generators (e.g.,
universities, hospitals).
Major EPA role will be to issue permits to storage facilities (there are no
approved disposal facilities).
^.s "* ,.,*J:*<^
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Part Three: Relationship to Other RCRA Subtitle C Programs
OVERVIEW: TC AFFECTS OTHER RCRA REGULATIONS 3-11
The TC will have no direct effect on the following:
Hazardous waste listings
Waste that are hazardous by the "mixture" and "derived from" rules
Wastes already excluded from regulation under §261.4
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Part Three: Relationship to Other RCRA Subtitle C Programs
HAZARDOUS WASTE LISTINGS 3-12
TC rule has no effect on listings of hazardous waste
Waste listed as hazardous is always considered hazardous, unless delisted
Listed wastes with concentrations of TC constituents below regulatory
levels are still hazardous
Hazardous waste listings will continue to complement the revised TC, as they
did the EP characteristic. The TC revisions do not justify elimination of any of
the hazardous waste listings.
Listed wastes continue to be hazardous, despite the fact that they may contain
TC constituents in concentrations below the regulatory levels.
TC regulatory levels are not designed to identify the full range of wastes that
may be toxic to human beings. Instead, the characteristic levels were
established at concentrations where there is a high degree of certainty that any
wastes with constituents at levels exceeding the regulatory levels pose a
potential threat to human health.
Listed wastes that pass the characteristic test may nevertheless be hazardous,
either because:
They contain listed constituents at concentrations below the TC regulatory
levels but at levels and under circumstances that nevertheless render the
waste hazardous, or
They contain hazardous constituents that are not covered by the TC rule.
Listed wastes frequently contain hazardous constituents other than the ones
cited in Appendix VII of 40 CFR Part 261. The additional hazardous
constituents that are present in a waste may not be on the list of TC
constituents. Removing wastes from a hazardous waste listing without an
evaluation of additional constituents would be inconsistent with the intent of
RCRA §3001 (f).
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Part Three: Relationship to Other RCRA Subtitle C Programs
"MIXTURE" AND "DERIVED FROM" RULES 3-13
TC has no effect on regulatory status of waste mixtures or derived from wastes
Mixture of listed wastes and solid wastes and residues derived from listed
wastes are still hazardous until delisted
TC alone is not adequate to regulate mixtures and treatment residues
Problems may result by applying mixture and derived from rules
EPA expects to establish self-implementing de minimis exemption
The "mixture" rule (40 CFR 261.3(a)(2)(iv)) states that any mixture of a listed
hazardous waste and a solid waste is itself a RCRA hazardous waste.
The "derived from" rule (40 CFR 261.3(c)) states that any waste derived from
the treatment, storage, or disposal of a listed hazardous waste is hazardous.
EPA does not believe TC rule alone is sufficient to determine if waste mixtures
or treatment residues are hazardous. Many of the reasons are the same as for
listings:
May be additional, non-TC constituents in mixture or residue that make
substance hazardous;
May be inconsistent with RCRA §3001 (f); or
Concentration levels below TC levels may still pose risk to human health
or environment.
The mixture and derived from rules may create some inequities in the treatment
of certain diluted wastes. For example, very low concentrations of constituents
in listed wastes may still be considered hazardous after treatment.
EPA plans to propose an amendment to the definition of hazardous waste,
establishing self-implementing de minimis exemption levels for hazardous
constituents found in listed wastes. Listed wastes that meet these exemption
levels would no longer be listed hazardous wastes and thus would need to be
managed as hazardous wastes only if they exhibit a hazardous waste
characteristic.
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Part Three: Relationship to Other RCRA Subtitle C Programs
§261.4(b) EXCLUSIONS 3-74
TC rule does not apply to wastes that are already excluded from Subtitle C
regulations under §261.4
For example, household hazardous waste is excluded from
Subtitle C; it remains excluded after TC effective date
TC rule does not add any exclusions to the applicability of previously
promulgated hazardous waste characteristics
Wastes already excluded from Subtitle C regulations will continue to be exempt
from regulation as hazardous wastes, even if they exhibit the TC.
\
EPA does not at this time intend to expand the list of exemptions under
§261.4(b) to include creosote- and pentachlorophenol-treated wood.
Other wastes that are excluded from Subtitle C in §261.4(b) include:
Household hazardous wastes
Certain mining wastes
Certain solid wastes generated from farming or raising animals
Certain wastes generated primarily from the combustion of coal or other
fossil fuels
Waste associated with production of crude oil and natural gas
Some chromium containing wastes
Solid waste from extraction, beneficiation, and processing of ores and
minerals
Cement kiln dust waste
Certain wood or wood products
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iV
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PART FOUR
Relationship of Toxicity Characteristic
to Other Laws
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Part Four: Relationship to Other Programs
OVERVIEW 4-1
Underground Storage Tanks (LIST)
. CERCLA or Superfund
Clean Water Act (CWA)
Safe Drinking Water Act (SDWA)
Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA)
Used Oil Recycling Act
Toxic Substances Control Act (TSCA)
Lead Abatement
RCRA Regional personnel may be asked questions about how TC affects
various programs.
In general, TC increases the areas in which RCRA overlaps with other
programs.
Some exclusions in TC rule directly address certain overlaps with other laws
-- UST
RGBs under TSCA
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Part Four: Relationship to Other Programs
RCRA SUBTITLE I - UNDERGROUND STORAGE TANKS 4-2
Two programs currently regulate underground storage tanks:
Tanks containing solid or hazardous wastes - Subtitle D or C
Tanks containing product (petroleum or hazardous substances) - Subtitle I
TC may increase number of tanks regulated under Subtitle C
Product (petroleum, hazardous substance) that leaks may become a waste and
may also exhibit TC
Subtitle I and Subtitle C potentially overlap if a substance exhibits the TC
characteristic and origin of substance is not known
It is important to determine what is contained in a tank to determine which
regulatory program (i.e., Subtitle C or Subtitle I) applies:
Subtitle C regulates hazardous wastes
Subtitle I regulates hazardous substance product and petroleum
Hazardous product that leaks may become hazardous waste
Petroleum and hazardous product may exhibit the TC
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Part Four: Relationship to Other Programs
RCRA SUBTITLE I - UNDERGROUND STORAGE TANKS 4-3
Corrective action under Subtitle I addresses releases of product
Old releases of product not subject to Subtitle I may have occurred
Inactive tanks
In areas considered RCRA solid waste management units
If waste exhibits TC for D004-D017, RCRA standards may apply to these old
releases
TC rule exempts D01 8-D042 wastes from RCRA regulation if covered under
Subtitle I Corrective Action
Petroleum-contaminated soil and ground water
Petroleum-contaminated debris (tanks, sludges in tanks)
EPA is studying impacts of Subtitle C regulation on petroleum-contaminated
areas
Petroleum contains several of the TC hazardous constituents. Therefore, it is
likely that some of the petroleum-contaminated media will exhibit the TC.
The management of any petroleum-contaminated media exhibiting TC would
normally be subject to Subtitle C requirements for hazardous waste
management. However, EPA believes further study of these impacts is
necessary before imposing TC requirements on soil and ground water
contaminated solely by gasoline from USTs.
Because the Agency has insufficient information concerning the impact of the
TC rule on LIST cleanups, but believes that any such impact may be
environmentally counterproductive, EPA has decided to defer a final decision
on the application of the TC to media and debris contaminated with petroleum
from USTs exhibiting the D018-D042 waste characteristics that are subject to
the 40 CFR Part 280 requirements.
EPA believes deferral of a final decision concerning the application of the TC
rule to UST cleanups is necessary because imposition of the Subtitle C
requirements is likely to significantly delay cleanups and severely discourage
the self-monitoring and voluntary reporting essential to implementation of the
UST program.
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Part Four: Relationship to Other Programs
CERCLA OR SUPERFUND 4-4
CERCLA response actions must comply with all ARARs, including RCRA
TC will cause more Superfund wastes to be classified as RCRA hazardous
wastes
Thus, more Superfund cleanups will be subject to RCRA ARARs
TC will not however, affect CERCLA clean-up levels
Comprehensive Environmental Response, Compensation, and Liability Act
(CERCLA or Superfund) addresses remediation of inactive waste sites.
ARARs are "applicable or relevant and appropriate requirements." CERCLA
must meet other Federal or State environmental requirements when they are
applicable or relevant and appropriate to CERCLA action.
Primary effect of TC on Superfund will be to regulate many organic constituents
found at Superfund sites as RCRA hazardous wastes.
A current problem at many Superfund sites is determining if organic
constituent is from a listed RCRA hazardous waste (e.g., is acetone a
spent solvent?)
Often, there is little evidence about the source of contamination that exists
at Superfund sites to prove waste is a listed waste. Therefore, waste may
not be managed under RCRA (but it will be handled in a protective
manner according to risk assessment)
Under the TC, if acetone is found above TC regulatory level, waste is
hazardous regardless of whether evidence exists to determine if it is a
spent solvent.
Like RCRA corrective actions, Superfund response personnel will not use the
TC to determine whether to undertake a clean-up action; rather, the TC will
affect decisions concerning the management of wastes generated during
cleanup activities (i.e., hazardous wastes generated during cleanup must they
be managed in accordance with Subtitle C).
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Part Four: Relationship to Other Programs
CLEAN WATER ACT (CWA) 4-5
The CWA controls discharges of pollutants to surface waters and to publicly
owned treatment works (POTWs)
Regulatory levels of TC consistent with CWA levels:
NPDES effluent guidelines
Pretreatment standards
Clean Water Act regulates discharges of hazardous substances to surface
water (through NPDES permit program), and pretreatment standards for
POTWs.
EPA believes TC levels and CWA standards are consistent.
These CWA discharges are exempt from RCRA regulation under 40 CFR Part
261.
Therefore, treated wastewaters exhibiting TC are regulated under RCRA unless:
-- , discharged under NPDES unit
treated in POTW
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Part Four: Relationship to Other Programs
CLEAN WATER ACT (CWA) 4-6
Wastewaters subject to CWA standards
May not have exhibited RCRA hazardous waste characteristic
May, however, now exhibit TC
Therefore, may be subject to RCRA management standards unless
exempted
EPA believes few POTW sludges will exhibit TC
Those that do are subject to RCRA
EPA may reconsider exclusion for sludges from RCRA
Wastewater treatment facilities using impoundments to treat TC waste may be
subject to RCRA.
The Agency expects many owner/operators to replace impoundments with
treatment tanks.
Wastewater treatment tanks are exempt from Subtitle C regulation 40 CFR
264.1(g)(6) and 265.1(c).
If a POTW sludge (from wastewater treatment) exhibits TC, however, the
owner/operator must treat the sludge to remove the characteristic.
Through pre-treatment program (i.e., before POTW receives discharge); or
Treatment after sludge is produced.
Agency indicates that it may reconsider its current decision to regulate under
RCRA POTW sludges after the sewage sludge management regulations are
promulgated.
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Part Four: Relationship to Other Programs
SAFE DRINKING WATER ACT (SDWA) 4-7
SDWA mandates EPA to establish regulations to protect human health from
contaminants in drinking water
SDWA primary drinking water regulations include MCLs for specific
contaminants
TC levels based on SDWA MCLs in many cases
Safe Drinking Water Act establishes maximum levels of contaminants
acceptable in public drinking water supplies.
Maximum Contaminant Levels (MCLs)
Maximum Contaminant Level Goals (MCLGs)
TC fate and transport model assumes ingesting contaminated drinking water
and uses MCLs as basis for setting regulatory levels for many TC constituents.
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Part Four: Relationship to Other Programs
SAFE DRINKING WATER ACT (SDWA) 4-8
Underground injection control (UIC) program regulates injection of fluids to
protect underground sources of drinking water (USDWs)
Five classes of wells regulated under UIC
Class I - municipal or industrial waste
Class II - oil and gas production
Class III - mineral recovery
Class IV - hazardous or radioactive waste into or above a USDW
Class V - all other wells used for injection of fluids
(include septic tanks, sumps)
Class I wells are often used by generators of hazardous waste or
owner/operators of hazardous waste management facilities to inject hazardous
waste. The largest user of hazardous waste Class I wells is the chemical
industry.
Class IV wells are banned with the exception of wells used for remediation of
aquifers which have been contaminated with hazardous wastes (40 CFR
144.13).
The largest group of injection wells is Class V, with approximately 180,000
wells. The second largest group of wells is the Class II group which contains
approximately 150,000 wells, followed by Class III wells with 20,000. Class I is
the smallest class of wells with 554 reported in 1989.
The Agency is working on enforcing the ban on shallow injection of hazardous
wastes. The Agency is also developing guidance on best management
practices to reduce the amount and toxicity of wastes generated by these
users of Class V wells and to try and eliminate their use for disposal of
industrial wastes (40 CFR 144.24).
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Part Four: Relationship to Other Programs
SAFE DRINKING WATER ACT (SDWA) 4-9
TC rule may:
Increase number of Class I wells accepting TC wastes
Bring newly identified hazardous Class I wells into Subtitle C
Many Class V wells could be accepting hazardous wastes; number may
increase with TC rule
Class V wells likely receiving TC wastes:
Agricultural drainage wells
Industrial drainage wells
Experimental technology wells
Industrial process water and waste disposal wells
Automobile service station wells, and
Aquifer remediation-related wells
Most of the categories of Class V wells probably are not currently receiving
injected RCRA hazardous waste. Wastes injected into many of the Class V
wells are exempted from regulation as a hazardous waste. For example:
geothermal electric and direct heat reinjection wells, several of the domestic
wastewater disposal wells, most of the mineral and fossil fuel recovery-related
wells, and certain experimental technology wells.
Some facilities that inject hazardous wastes in Class V wells probably are small
quantity generators and, therefore, may be conditionally exempt from
hazardous waste regulations, if they produce < 100 kg per month of hazardous
waste and meet all other regulations.
Many of the facilities that operate Class V wells (e.g., auto service stations) also
generate listed hazardous waste, such as solvents. It is possible that some
facilities are not managing their listed wastes properly and that the wastes are
entering Class V wells.
It also appears that fluids released into these wells could contain metals and
organics on the new TC list of toxicants.
It is unclear at this time what effects TC will have on UIC program because
Class V program is very new.
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Part Four Relationship to Other Programs
FEDERAL INSECTICIDE, FUNGICIDE, AND RODENTICIDE ACT
(FIFRA) 4-10
FIFRA regulates sale, distribution, and use of all pesticide products
TC rule:
Adds one pesticide to TC constituents
Retains six pesticides regulated under old EP
Other TC constituents may be ingredients in pesticides
If pesticide wastes exhibit the TC, they are subject to Subtitle C regulation
unless they are exempt
Current RCRA exemptions limit extent pesticide users subject to RCRA:
Household waste (e.g., household pesticide wastes) exemption.
Farmers exemption (i.e., if triple rinse containers, dispose of the rinsate on
own farm 40 CFR 262.51 and follow label instructions.
Small quantity generator reduced requirements. Many pesticide users are
small quantity generators.
Properly emptied containers may be exempted from further RCRA
requirements under 40 CFR 261.7. Many pesticide containers, therefore
may not be subject to regulation as hazardous waste.
No change in listed pesticide wastes that are either pure, technical grade, or
sole active ingredient product wastes; will continue to be regulated under
Subtitle C (P and U listings).
The exemption for arsenic-treated wood was not expanded in the TC rule
This exemption may be reevaluated in the future
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Part Four: Relationship to Other Programs
FEDERAL INSECTICIDE, FUNGICIDE, AND RODENTICIDE ACT
(FIFRA) ' 4-11
Multiple active ingredient products
Not listed as hazardous (i.e., not P- or U-wastes when disposed)
Hazardous only if they are a solid waste and exhibit a characteristic
TC increases potential for multiple active ingredient product wastes to be
hazardous
Principal TC effects felt by: commercial applicators (i.e., large quantity
generators who use multiple active ingredient products)
The principal effects of adding new pesticide constituents to the TC will be felt
by commercial applicators, such as aerial applicators and pest control
operators. If they use large quantities of multiple active ingredient pesticide
products that have not previously been regulated, such applicators may be
newly subject to RCRA Subtitle C requirements.
Wastes from multiple active ingredient products that do not exhibit a
characteristic will still be regulated under any applicable FIFRA and RCRA
Subtitle D requirements.
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Part Four: Relationship to Other Programs
USED OIL RECYCLING ACT 4-12
Some used oil exhibits TC or ignitability characteristic
TC will affect used oil that is disposed of, primarily in three categories:
Used oil used for road oiling
Used oil that is dumped
Used oil that is disposed in solid waste landfills and incinerators
TC will not affect used oil that is:
Managed by do-it-vourselfers (exempt as household hazardous waste)
Recycled through energy recovery (40 CFR Part 266 regulates this
activity)
Recycled in any other manner (exempt from RCRA regulation)
Used oil may exhibit TC characteristic.
Used Oil exhibiting characteristic that is disposed of is subject to full RCRA
Subtitle C regulation.
Characteristic as well as non-hazardous used oil that is recycled by being
burned for energy recovery is subject to Subpart E of 40 CFR Part 266, or
Subpart D is mixed with hazardous waste.
Used oil generated by do-it-yourselfers is exempt from RCRA under 40
CFR 261.4(b)(1) or is subject to reduced requirements under the small
quantity generator provisions of 261.5.
Used oil that exhibits one or more of the characteristics of hazardous
waste but is recycled in some other manner than being burned for energy
recovery is exempt under 261.6(a)(3)(iii).
Significant quantities of used oil may exhibit EP toxicity for metals, but little
used oil is currently recognized as EP toxic.
Shifts in used oil management practices may result from regulation of used oil
under the TC. Management practices may shift away from road oiling,
dumping, and disposal in solid waste facilities to burning as fuel, recycling, and
disposal in Subtitle C facilities.
Standards for controlling used oil that is recycled were proposed on November
29, 1985 (50 FR 49212), but are not final.
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Part Four: Relationship to Other Programs
TOXIC SUBSTANCES CONTROL ACT (TSCA) 4-13
TSCA addresses manufacturing, processing, distribution of hazardous
substances or mixtures; PCBs are a major regulated substance
If TSCA-regulated products become wastes, they become RCRA regulated
If PCBs are fully regulated under TSCA, TC rule exempts certain PCB-wastes
from RCRA
Exempt wastes include PCB-containing dielectric fluids removed from:
Electrical transformers
Capacitors
Associated PCB-contaminated electrical equipment
RCRA retains regulation of PCB wastes classified as D004-D017 wastes
Toxic Substances Control Act (TSCA) regulates toxic substances and
specifically addresses PCB management and disposal.
Dielectric fluids from electrical transformers, capacitors and associated PCB-
contaminated electrical equipment could exhibit the TC because they may
contain TC constituents such as chlorinated benzene.
These wastes are exempted from Subtitle C management standards if
they exhibit waste codes D018-D043.
The exemption applies only to certain wastes noted above fully regulated
under TSCA, not all PCB wastes.
PCB wastes exhibiting D004-D017 characteristics (i.e., those hazardous under
EP toxicity) remain regulated under RCRA if they are a D004-D017 waste under
TC.
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Part Four: Relationship to Other Programs
LEAD ABATEMENT 4-14
TC rule retains existing regulatory level for lead (0.5 mg/l) pending further
Agency validation and study.of the fate and transport of metals
TCLP test may be more aggressive than the EP test in certain concentration
ranges of lead and under certain conditions
More lead wastes might be hazardous by TC
This determination will depend on total lead concentration
TCLP and EP yield similar results at concentration ATSDR recommends for lead
abatement level (500-1,000 ppm total lead)
ATSDR has recommended a lead abatement level of between 500 and 1,000
ppm for lead.
Superfund recently issued directive recommending cleanup of sites to meet
total lead levels set forth in ATSDR standards.
Results show TCLP is a more aggressive test (i.e., results in greater lead
concentrations in leachate) than the EP in the 2,500 to 10,000 ppm (total lead
in soil) range, but appears to give similar results in other concentration ranges.
ATSDR proposes using an action level of 1,000 ppm for lead abatement
programs. At this level, TCLP and EP appear to yield similar results.
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