United States
           Environmental Protection
           Agency
Office of Solid Waste
(OS-312)
Washington, DC 20460
July 1990
           Solid Waste
&EPA    Notification of Regulated Waste Activity

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           \
                         UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
                                       WASHINGTON, D.C. 20460
This package is designed to help you determine if you are subject to the regulations under RCRA and, if so, to
help you notify EPA or your authorized State of your activities and get a U.S. EPA Identification Number. RCRA
is a Federal law.  If you are regulated but do not comply with the RCRA notification requirements, you may be
subject to civil penalties.

The following materials are contained in the indicated sections of this  booklet:
Section
   I)     Guidance on how to determine if you handle a hazardous waste that is regulated under RCRA;
   II)    Guidance  on  how  to determine  if  your  waste  activities are  regulated   under  U.S.  EPA's
         "Waste-As-Fuel" provisions;
   III)   Guidance on how to file the Notification Form and a list of contacts, alphabetized by State, where you
         can  get  information, obtain more forms, and send your completed form;
   IV)   Two copies of EPA Form 8700-12: "Notification to EPA of Regulated Waste Activity" and complete
         line  by line instructions for filling out the Notification form;
   V)    A list of definitions to help in understanding and completing  the Notification Form;
   VI)   Guidance on EPA hazardous waste numbers for waste streams commonly generated by small quantity
         generators, Table 1 "Typical Waste Streams Produced by  Small Quantity Generators" and Table 2
         "Typical Waste Streams and EPA Hazardous Waste Numbers"; and
   VII)  A reprint of Part 261 (July  1,  1989) from Title 40 of the Code of Federal  Regulations  (CFR).  This
         document  contains the  regulations that U.S. EPA  has developed, identifying and  listing hazardous
         waste.
   VIII) A reprint of the Toxicity Characteristics Rule from the Federal Register, Vol. 55, No. 61 (March 29, 1990).
         This document contains the regulations that U.S. EPA has developed, describing toxicity characteristic
         waste. A reprint of a correction to the Toxicity Characteristic Rule from the Federal Register, Vol. 55, No.
         126 (June 29, 1990).

To obtain a copy of 40 CFR Part 266 which discusses the waste-as-fuel administrative standards, contact your
EPA Regional Office listed later in this package, or call the RCRA I Superfund Industry Assistance Hotline at 1-800-
424-9346 (or in Washington, D.C. at (202) 382-3000). After your completed notification is received, you will be
sent a  written acknowledgment that will  include your U.S. EPA Identification Number.  You must use this
number on all communications with  U.S. EPA regarding your activities.

It is important for you to understand that this package only addresses  the requirements of the Federal hazardous
waste program. Many States may have  requirements that are different from the Federal requirements; those
States may use this form or a similar form which may require additional information not required on this form. It
is up to you,  as the waste  handler, to learn about all the requirements  that affect you.

Finally, we know that understanding these regulations and how they affect  your  business is not an easy job. In
Section III of the instructions, we have listed the addresses and phone numbers of the contacts for each State who
can answer your questions and help you understand the Federal and State  regulations that apply to you. In
addition to those contacts, the following  contacts are also available to  help with your questions:

    A) RCRA I Superfund Industry Assistance Hotline —  1-800-424-9346 (If you are located in Washington, D.C.
        call (202)  382-3000)

     B) EPA Small Business Ombudsman Hotline — 1-800-368-5888

     C) Your  Trade Association

                                                - 1

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              How to Notify U.S.  EPA of Your Waste Activities
I.    How to Determine if You Handle a
      Regulated Hazardous Waste
Persons  who generate, transport,  treat, store,  or
dispose   of  solid   wastes  are  responsible  for
determining if their solid waste is a hazardous waste
regulated  under  the  Resource  Conservation and
Recoveiy  Act (RCRA).   In addition,  persons who
recycle secondary materials must also  determine
whether  those materials are  solid  and  hazardous
wastes under the  provisions of RCRA. If you need
help  making this determination after  reading these
instructions, contact the  addressee listed for your
State in Section III. C. of these instructions.
You will need to refer to 40 CFR Part 261 of the Code
of Federal  Regulations (copy enclosed,  see Section
VII) to help you  decide if the waste you handle is
regulated under RCRA.*
To determine if you are regulated under RCRA, ask
yourself the following questions:

A) Do I Handle A Solid Waste?

Section 261.2 of  the Code of Federal  Regulations
(hereafter referred to as CFR) defines "solid waste"
as any discarded material that is not excluded  under
Section 261.4(a) or that is not excluded by variance
granted  under    Sections  260.30 and 260.31.   A
discarded material is any material which is:
     1) abandoned, as explained in 261.2(b); or

     2) recycled, as explained in 261.2(c); or

     3) considered inherently waste-like as explained
        in 261.2(c).

B) Has My Solid  Waste Been  Excluded From The
   Regulations Under Section 261.4?

The list of general exclusions can be found in Section
261.4 of the CFR.  If the solid waste that you handle
has been excluded, either by rule or special variance,
then you  do not need  to  notify U.S. EPA for that
waste.
     1) by specifically listing the waste and assigning
        it a unique EPA  Waste Code Number; or

     2) by regulating it because  it possesses any of
        four hazardous characteristics and assigning
        it a generic EPA Waste Code Number.

C) Is  My  Solid  Waste  Specifically Listed  as a
   Hazardous Waste?
Sections 261.31 — 261.33 of the CFR identify certain
solid wastes that U.S. EPA has specifically listed as
hazardous.  Persons who handle listed  hazardous
waste are subject to regulation and must notify U.S.
EPA of their  activities unless they are exempted as
discussed below.  Refer to this section of the CFR
(enclosed as Section VII) to see  if your waste is
included as a "listed waste."

D) Does My  Solid Waste  Possess  a  Hazardous
   Characteristic?
Even if your waste is not specifically listed as a
hazardous waste, it may still be hazardous because it
exhibits certain hazardous characteristics.  These
characteristics are —
     1) Ignitability;
     2) Corrosivity;
     3) Reactivity; and
     4) Toxicity Characteristic.
Sections 261.20  through 261.24 of the CFR explain
what each of the  characteristics  is and outlines the
testing  procedures you should use to determine if
your waste meets these characteristics. Persons who
handle  characteristic waste that is regulated must
notify  U.S. EPA of their   activities unless they are
exempted, as discussed below.  If you are handling a
newly regulated waste (see Toxicity Characteristics
Rule in Section VIII) and  have already notified EPA
prior to that activity and already  have  an  EPA
Identification Number, no re-notification is required.

E) Has  My Hazardous Waste Been Exempted From
  The Regulations?
If your solid waste was not excluded from regulation,     The list  of exemptions can be  found in 261.5 and
you need to determine if it is a hazardous waste that     261.6(a)(3) of the CFR. If the hazardous waste that
U.S.  EPA  regulates.   The U.S.  EPA  regulates     you handle has been exempted, then you do not need
hazardous waste two ways:                             to notify U.S. EPA for that waste.
  * Many States have requirements that vary from the Federal regulations. These State regulations may be more strict than the Federal requirements
  bv identifying additional wastes as hazardous, or may not yet include all wastes currently regulated under RCRA. It is your responsibility to comply
  with all regulations that apply to you. For more information on state requirements, you are strongly urged to contact the appropriate addressee listed
 for your State in Section III of these instructions.
                                                  -2-
EPA Form 8700-12 (07-90) Previous edition is obsolete.

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II.    How To Determine if You Must Notify of
      Your Waste-as-Fuel Activities
Persons who market or burn hazardous waste or used
oil (and  any material  produced from or otherwise
containing hazardous waste or used oil) for  energy
recovery are required  to notify  U.S. EPA (or their
State agency if the State  is authorized to operate its
own hazardous waste  program) and  obtain  a U.S.
EPA Identification Number unless they are exempt as
outlined below (see  Subparts D and E of 40 CFR Part
266). Hazardous waste and used oil are considered to
be burned for energy recovery if they are burned in a
boiler or industrial furnace that is  not regulated as a
hazardous waste incinerator under Subpart O of 40
CFR Parts 264 or 265.
Even if you have  previously  notified U.S. EPA of
hazardous waste  activities and have a U.S. EPA
Identification Number, you must renotify to identify
your waste-as-fuel activities.  (You do not have to
renotify for  those  activities you previously notified
for,  only for any newly regulated activities.)  If you
have previously notified, be  sure to complete  Item I
"First or Subsequent Notification," by marking an
"X" in the box for  subsequent notification.  Fill in
your U.S. EPA Identification  Number in the  spaces
provided. (Your U.S. EPA Identification Number will
not change.)

Who is Exempt From Waste-As-Fuel Notification
Requirements?

   1) Ordinary Generators (and  initial transporters):
      Generators (and initial transporters who pick
      up used oil or hazardous waste from generators)
      are not marketers subject to the notification
      requirement // they do not market hazardous
      waste fuel or used oil fuel directly to a burner. In
      such  situations,  it is the recipient of that fuel
   who makes the decision to market the materials
   as  a  fuel,   (typically  after  processing  or
   blending), and it is   the recipient  who must
   notify.
   In  addition,  used  oil  generators  or initial
   transporters who send their oil to a person who
   processes or blends it to produce used oil fuel
   and who incidently burns used oil to provide
   energy for the processing or blending are  also
   exempt from the notification requirement. This
   is   because   such  persons    are   generally
   considered to be primarily fuel processors and
   marketers, but  only incidental burners.
2) Persons who Market or Burn Specification Used
   Oil Fuel:  Used  oil   fuel  that  meets  the
   specification provided under 40 CFR 266.40(e)
   is   essentially  exempt from  the  regulations.
   However, the person who first claims  that  the
   used oil meets the specification  is subject to  the
   notification and certain other requirements. The
   burner (or any subsequent marketer) is not
   required to notify.
3) Used Oil Generators Operating Used-Oil-Fired
   Space Heaters: Persons who burn their used oil
   (and used oil received from individuals who are
   do-it  yourself oil changers) in used-oil-fired
   space heaters are exempt from the notification
   requirement provided  that the device is vented
   to the outdoors.
4) Specific Exemptions Provided by 40 CFR 261.6:
   The rules provide  conditional exemptions  for
   several  specific waste-derived  fuels  under
   261.6(a)(3),  including  fuels  produced  by
   petroleum refineries  that  recycle    refinery
   hazardous waste, and coke and coal tar derived
   from coal coking  wastes by the iron and steel
   industry.  Marketers  and  burners  of these
   exempted fuels  are   not  subject  to  the
   notification requirement.
EPA Form 8700-12 (07-90) Previous edition is obsolete.
                                                 -3-

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III.   How to File EPA Form 8700-12,
      "Notification of Regulated Waste
      Activity?"
If your waste activity is regulated under RCRA, you
must notify the U.S. EPA of your activities and obtain
a U.S. EPA Identification Number. You can satisfy
both of these requirements by completing and signing
the enclosed  notification form and mailing it to the
appropriate address listed in Part C of this section.

Per the Hazardous Waste Import  Regulations, 40
CFR  262.60, foreign generators should not apply for a
Federal I.D. number.   These regulations state that
when filling out a U.S. manifest, you must include the
name and address of the foreign generator, and the
name and address and  EPA I.D.  number of the
importer.   Please  contact U.S.  firms  involved with
your shipments and determine which firm will serve as
importer.

If this  is  a  subsequent notification, you  need to
complete Items I, II, III, VI, VII, VIII and X and any
other sections  that are being added  to (i.e., newly
regulated   activities)  or  altered  (i.e.,  installation
contact).  All other sections may be left blank.

A) How Many Forms  Should I File?

   A person who is subject  to the hazardous waste
   regulations and/or the  waste-as-fuel regulations
   under RCRA should submit one notification form
   per  site or location.  If  you conduct hazardous
   waste activities at  more than one  location, you
   must submit a separate form for each location. (If
   you   previously  notified for  hazardous waste
   activities and are now notifying for  waste-as-fuel
   activities at  the same location, you must submit a
   second form,  but your U.S. EPA Identification
   Number will remain the same.)
   If you only transport hazardous waste and do not
   generate, market, burn, treat, store, or dispose of
   these  wastes, you  may submit one form  which
   covers all transportation  activities your company
   conducts.   This form should be  sent   to the
   appropriate address (listed in Part  C) that  serves
   the   State  where   your    company   has its
   headquarters  or  principal  place  of  business.
   However,  if you   are a transporter who also
   generates, treats, stores, or disposes of hazardous
   wastes, you must complete and submit  separate
   notification forms to cover each location.

B) Can I Request  That This Information  Be  Kept
   Confidential?
   All information you submit in a notification can be
   released to the public, according to the Freedom of
   Information Act, unless it is determined  to be
   confidential by U.S. EPA pursuant to 40 CFR Part
   2. Since notification  information is very general,
   the  U.S. EPA  believes it  is unlikely  that any
   information in your notification could qualify to be
   protected from release. However, you may make a
   claim  of confidentiality  by printing  the  word
   "CONFIDENTIAL"  on   both  sides  of  the
   Notification Form and on any attachments.
   EPA will take action on the confidentiality claims
   in accordance with  40  CFR Part 2.

C) Where Should I Send my  Completed Form?
   Listed alphabetically, on the following pages, are
   the addresses and phone  numbers of the proper
   contacts in each  State where you can get additional
   information  and more forms,  and where you
   should mail your completed forms. As  shown
   here, the U.S. EPA and many States have arranged
   for the States to  answer your questions and receive
   completed forms. In a few instances, the workload
   is shared  between  U.S. EPA and  the  State, or
   handled by U.S. EPA  alone.  To avoid delay and
   confusion, follow the directions for your State very
   carefully.
EPA Form 8700-12 (07-90) Previous edition is obsolete.
                                                -4-

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                      Alphabetized  State Listing of Hazardous Waste Contacts
Alabama
Land Division
Alabama Department of Environmental Management
1751 Federal Drive
Montgomery, Alabama 36130
(205)271-7730

Alaska
U S. EPA Region X
Waste Management Branch
MS IIW-112
1200 Sixth Avenue
Seattle. Washington 98101
(206)442-0151

American Samoa
Environmental  Quality Commission
Government of American Samoa
Pago Pago, American Samoa 96799
Overseas Operator Commercial call (684) Country Code 663-2304

Arizona
Office of Waste and Water Quality Management
Arizona Department of Environmental Quality
2005 N. Central Avenue, Room 304
Phoenix, Arizona 85004
(602)257-2305

Arkansas
Arkansas Department of Pollution C'onlrol and Ecology
P.O. Box 9583
Little Rock. Arkansas 72219
(501)562-7444

California
California Department of Health Services
Toxic Substances Control Division
Department of  Health Services
P.O. Box 942732, 400 P. Street
Sacramento, California 95814
(916)323-2913


Colorado
Hazardous Materials & Waste Management Division
Colorado Department of Health
4210 E. llth Avenue
Denver, Colorado 80220
(303)331-4830

Connecticut
Waste Management Bureau
Department of  Environmental Protection
State Office Building
Hartford, Connecticut 06106
(203)566-8844


Delaware
Delaware Department of Natural Resources
& Environmental Control
Division of Air  and Waste Management
Hazardous Waste Management Branch
P.O. Box 1401, 89  Kings Highway
Dover,  Delaware 19903
(302)736-3689
District of Columbia
Department of Consumer and Regulator)' Affairs
Environmental Control Division
Pesticides and Hazardous Waste Branch
614 HSt., NW
Room 505
Washington, D.C. 20001

(202)783-3194

Effective December 1.  199(1
Department of Consumer and Regulator)' Affairs
Environmental Control Division
Pesticides and Hazardous Waste Branch
2100 Martin Luther King Jr. Ave, S.E.
Room 204
Washington, D.C. 20020

Florida
Hazardous Waste Section
Department of Environmental Regulations
Twin I.'«, i- ()tfice Building
260(1 III.in Shine Road
TalUi.,-Mi  I lorida 32399-2400
(904)488-0300

Georgia
I-Iml Protection Branch
Industrial and  Hazardous
Waste Management Program
Floyd Towers East 205 Butler Street, S.E.
Atlanta, Georgia 30334
(404)656-2833

Guam
Guam Environmental Protection Agency
IT&E
Harmon Plaza Complex, Unit D-107
130 Rojas St.
Harmon, Guam 96911
Overseas Operator (Commercial Call (671) 646-7579)

Hawaii
To Obtain Information or Fonm Contact:
Department of Health
Hazardous Waste Program
P.O. Box 3378
Honolulu, Hawaii 96801
(808)548-2270

Mail Your Completed Forms to •
U.S. EPA Region IX
RCRA Programs Section
Hazardous Waste Management Division
1235 Mission St.
San Francisco, California 94103

Idaho
Idaho Department of Health & Welfare
Tower Building, Third  Floor
450 West State Street
Boise, Idaho  83720
(208)334-5879
                                                              - 5-
EPA Form 8700-12 (07-90) Previous edition is obsolete.

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Illinois
To Obtain Information or Forms Contact:
U.S. EPA Region V
RCRA Activities
Waste Management Division
P.O. Box A3587
Chicago, IL  60690
(312) 886-4001

Mail completed forms to:
Illinois Environmental Protection Agency
Division of Land Pollution Control
2200 Churchill Road
Springfield, Illinois 62706
(217)782-6760

Indiana
To Obtain Information or Forms Contact:
Indiana Department of Environmental Management
105 S.  Meridian Street
P.O. Box 6015
Indianapolis, Indiana 46225
(317)232-3210

Mail completed forms to:
U.S. EPA Region V
RCRA Activities
Waste  Management Division
P.O. Box A3587
Chicago, IL 60690

 Iowa
 U.S. EPA Region VII
 RCRA Branch
 726 Minnesota  Avenue
 Kansas City, Kansas 66101
 (913) 236-2852 or 1 (800) 223-0425

 Kansas
 Bureau of Air and Waste Management
 Department of  Health and Environment
 Forbes Field, Building 740
 Topeka, Kansas 66620
 (913)296-1600

 Kentucky
 Division of Waste Management
 Department of  Environmental Protection
 Cabinet for Natural Resources
 & Environmental Protection
 Fort Boone Plaza, Bldg. #2
 Frankfort, Kentucky 40601
 (502)564-6716

 Louisiana*
 Louisiana Department of Environmental Quality
 Department of  Solid and Hazardous Waste
 P.O. Box 44307
 Baton Rouge, Louisiana 70804
 (504)342-1354

 Maine
 Bureau of Oil and Hazardous Materials Control
Department of Environmental Protection
Ray Bldg. Station #17
Augusta, Maine 04333
(207)289-2651
Maryland
Maryland Department of the Environment
Waste Management Administration
2500 Broening Highway
Baltimore, Maryland 21224
(301)631-3304


Massachusetts
Division of Hazardous Waste
Department of Environmental Protection
One Winter Street, 5th Floor
Boston, Massachusetts 02108
(617)292-5851

Michigan
To Obtain Information or Forms Contact:
Waste Management Division
Environmental Protection Bureau
Department of Natural Resources
Box 30038
Lansing, Michigan 48909
(517)373-2730

Mail completed forms to:
U.S. EPA Region V
RCRA Activities
Waste Management Division
P.O. Box A3587
Chicago, IL 60690

Minnesota
To Obtain Information or Forms Contact:
Solid and Hazardous Waste  Division
Minnesota  Pollution Control Agency
520 Lafayette Road,  North
St. Paul, Minnesota 55155
(612)296-7282

Mail completed forms to:
U.S. EPA Region V
RCRA Activities
Waste Management Division
P.O. Box A3587
Chicago. IL 60690

Mississippi
Hazardous Waste Division
Bureau of Pollution Control
Department of Environmental Quality
P.O. Box 10385
Jackson, Mississippi 39289-0385
(601)961-5062

Missouri
Waste Management Program
Department of Natural Resource
Jefferson Building
205 Jefferson  Street (13/14  floor)
P.O. Box 176
Jefferson City, Missouri 65102
(314)751-3176

Montana
Solid and Hazardous Waste  Bureau
Department of Health and Environmental Sciences
Cogswell Bldg.
Helena, Montana 59620
(406)444-1430
 Louisiana you must have an EPA ID number
                                                                -6-
 EPA Form 8700-12 (07-90) Previous edition is obsolete.

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Nebraska

Hazardous Waste Management Section
Department of Environmental Control
State House Station
P.O. Box 98922
Lincoln, Nebraska 68509-8922
(402)471-4217
North Carolina
Hazardous Waste Section
Division of Solid Waste Management
Department of Environment, Health and Natural Resources
P.O. Box 27687
Raleigh, North Carolina 27611-7687
(919)733-2178
Nevada
Waste Management Bureau
Division of Environmental Protection
Department of Conservation & Natural Resources
Capitol Complex
123 West Nye Lane
Carson City, Nevada 89710
(702)687-5872
New Hampshire
Department of Environmental Services
Waste Management Division
6 Hazen Drive
Concord, New Hampshire 03301
(603) 271-2900
New Jersey
To Obtain Information:

New Jersey Department of Environmental Protection
Division of Waste Management
Bureau of Hazardous Waste Classification and Manifests
401 East State Street, CN-028
Trenton, New Jersey 08625
(609) 292-8341

Obtain Forms from and Mail Completed Forms to:

U.S. EPA - Region II
Permits Administration Branch
26 Federal Plaza, Room 505
New York, NY  10278
New Mexico
New Mexico Health & Environment Dept.
Hazardous Waste Bureau
1190 St. Francis Drive
Sante Fe, New Mexico  87503
(505) 827-2929
North Dakota
Division of Waste Management
Department of Health and Consolidated Laboratories
1200 Missouri Avenue
P.O. Box 5520
Bismarck, North Dakota 58502-5520
(701)224-2366


Northern Mariana Islands
To Obtain Information or Forms Contact:
Department of Public Health and Environmental Services
Division of Environmental Quality
Dr. Torres Hospital
P.O. Box 1304
Saipan, Mariana Islands 96950
Overseas Operator: (676) 234-6984
Cable Address: Gov. NMI Saipan

Mail Your Completed Forms to:
U.S. EPA Region IX
RCRA Programs Section (H-2-3)
Hazardous Waste Management Division
1235 Mission Street
San Fransisco, California 94103
Ohio
U.S. EPA Region V
RCRA Activities
Waste Management Division
P.O. Box A3587
Chicago, Illinois 60690
(312)886-4001


Oklahoma
Oklahoma State Department of Health
Industrial Waste Division
1000 Northeast 10th Street
Oklahoma City, Oklahoma 73152
(405)271-5338

Oregon
Oregon Department of Environmental Quality
Hazardous Waste Operations
811 Southwest 6th Avenue
Portland, Oregon 97204
(503)229-5913
New York
To Obtain Information:

New York Department of Environmental Conservation
Division of Hazardous Waste Substances Regulation
P.O. Box 12820
Albany, New York 12212
(518)457-0530

Obtain Forms from and Mail Completed Forms to:

U.S. EPA - Region II
Permits Administration Branch
26 Federal Plaza, Room 505
New York, NY 10278
Pennsylvania
To Obtain Information or Forms Contact:
Pennsylvania Department of Environmental Resources
Bureau of Waste Management
P.O. Box 2063
Harrisburg,  Pennsylvania 17120
(717)787-9870

Mail completed forms to:
U.S. EPA Region III
RCRA Programs Branch
Pennsylvania Section (3 HW51)
841 Chestnut Building
Philadelphia, PA 19107
EPA Form 8700-12 (07-90) Previous edition is obsolete.
                                                              -7-

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Puerto Rico
To Obtain Information or Forms Contact:
Puerto Rico Environmental Quality Board
Land Pollution Control Area
Inspection, Monitoring and Surveillance
P.O. Box 11488
Santurce, Puerto Rico 00910-1488
(809)722-0439

Obtain Forms from and Mail Your Completed Forms to:
U.S. EPA Region II
Permits Administration Branch
26 Federal Plaza, Room 505
New York, New York 10278
Virgin Islands

To Obtain Information or Forms Contact:

Virgin Islands Department of Planning & Natural Resources
Division of Environmental Proteciton
179 Altona and Welgunst
St. Thomas, Virgin Islands 00801
(809) 774-3320

Obtain Forms from and Mail Completed Forms to:

U.S. EPA Region II
Permits Administration Branch
26 Federal Plaza, Room 505
New York, New York 10278
 Rhode Island
 Division of Air and Hazardous Materials
 Department of Environmental Management
 291 Promenade Street
 Providence, Rhode Island 02908-5767
 (401)277-2808


 South Carolina
 Bureau of Solid Waste Management
 Hazardous Waste Management
 Department of Health and Environmental Control
 2600 Bull Street
 Columbia,  South Carolina
 (803) 734-2500


 South Dakota
 Office of Waste Management
 Department of Water and Natural Resources
 Joe Foss Building,  523 East Capitol Street
 Pierre, South Dakota 57501-3181
 (605)773-3153


 Tennessee
 Division of Solid Waste Management
 Tennessee  Department of Health and Environment
 701 Broadway
 Customs House, 4th Floor
 Nashville, Tennessee 37247-3530
 (615)741-3424

 Texas
 Texas Water Commission
 Compliance Assistance Unit
 Hazardous and Solid Waste Division
 P.O. Box 13087, Capitol Station
 Austin, Texas 78711-3087
 (512)463-8175

 Utah
 Bureau of Solid and Hazardous Waste Management
 Department of Health
 P.O. Box 16690
 288 North  1460 West
 Salt Lake City, Utah 84116-0690
 (801)538-6170
Vermont
Hazardous Materials Management Division
Department of Environmental Conservation
103 South Main Street
Waterbury, Vermont 05676
(802) 244-8702
 EPA Form 8700-12 (07-90) Previous edition is obsolete.
Virginia

Virginia Department of Waste Management
Monroe Building, llth Floor
101 North 14th Street
Richmond, Virginia 23219
(804)225-2667
Washington

Solid and Hazardous Waste Management Division
Department of Ecology  Mail Stop PV-11
Olympia, Washington 98504
(206)459-6369
West Virginia

West Virginia Division of Natural Resources
Waste Management Section
1356 Hansford Street
Charleston, West Virginia 25301
(304)348-5393
Wisconsin

To Obtain Information or Forms Contact:

Bureau of Solid Waste
Department of Natural Resources
P.O. Box 7921
Madison, Wisconsin 53707
(608)266-1327

Mail completed forms to:

U.S. EPA Region V
RCRA Activities
Waste Management Division
P.O. Box A3587
Chicago, IL 60690
Wyoming

U.S. EPA Region VIII
Hazardous Waste Management Division (8HWM-ON)
999 18th Street, Suite 500
Denver, Colorado 80202-2405

(303) 293-1795
                                                               -8-

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                                     U.S. EPA Regional Offices
Region


  I



  II



  III
  IV
  V
  VI
  VII
  VIII
  IX
  X
Geographic Area Covered
Connecticut, Maine, Massachusetts, New
Hampshire, Rhode Island, Vermont
New Jersey, New York, Puerto Rico,
Virgin Islands
Delaware, District of Columbia,
Maryland, Pennsylvania, Virginia,
West Virginia
Alabama, Florida, Georgia, Kentucky,
Mississippi, North Carolina, South
Carolina, Tennessee
Illinois, Indiana, Michigan, Minnesota,
Ohio, Wisconsin
Arkansas, Louisiana, New Mexico,
Oklahoma, Texas
Iowa, Kansas, Nebraska, Missouri
Colorado, Montana, North Dakota,
South Dakota, Utah, Wyoming
Arizona, California, Hawaii, Nevada,
American Samoa, Guam, Northern
Mariana Islands
Alaska, Idaho, Oregon, Washington
EPA Regional Offices
U.S. EPA Region I
Waste Management Division
JFK Federal Building
Boston, MA 02203-2211

U.S. EPA Region II
Permits Administration Branch
26 Federal Plaza, Room 505
New York, NY 10278

U.S. EPA Region III
RCRA Programs Branch
(3 HW 53)
841 Chestnut Street
Philadelphia, PA 19107

U.S. EPA Region IV
Hazardous Waste Management Division
345 Courtland Street, NE
Atlanta, GA 30365

U.S. EPA Region V
RCRA Activities
Waste Management Division
P.O. Box A3587
Chicago, IE 60690

U.S. EPA Region VI
Hazardous Waste Management Division
First Interstate Bank Tower
1445 Ross Avenue, Suite 1200
Dallas, TX 75202-2733

U.S. EPA Region VII
RCRA Branch
726 Minnesota Avenue
Kansas City, KS 66620

U.S. EPA Region VIII
Hazardous Waste Management Division
(8HWM-ON)
999 18th Street, Suite 500
Denver, CO 80202-2405

U.S. EPA Region IX
Hazardous Waste Management Division
1235 Mission Street
San Francisco, CA 94103

U.S. EPA Region X
Waste Management Branch (HW-112)
1200 Sixth Avenue
Seattle, WA 98101
                                                   -9-
EPA Form 8700-12 (07-90) Previous edition is obsolete.

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   Estimated burden:  Public reporting burden for this collection of information is estimated to be 3.5 hours,
   including time for reviewing instructions, searching existing data sources, gathering and maintaining the
   data needed, and completing and reviewing the collection of information. Send comments regarding the
   burden estimate or any other aspect of this collection of information, including suggestions for reducing
   this burden, to Chief, Information Policy Branch, PM-223, U.S. Environmental Protection Agency, 401
   M St., S. W., Washington, D. C. 20460; and to the Paperwork Reduction Project (2050-0028), Office of
   Management  and Budget,  Washington, D.C. 20503.
 IV. Line-by-Line Instructions for Completing
      EPA Form 8700-12
 Type or print in black ink all items except Item X,
 "Signature," leaving a blank box between words. The
 boxes  are   spaced   at   1/4"  intervals  which
 accommodate  elite type (12  characters  per inch).
 When  typing,  hit  the  space  bar  twice between
 characters. If you print, place each character in a box.
 Abbreviate if necessary to stay within the  number of
 boxes allowed  for  each Item.   If you  must  use
 additional sheets, indicate clearly the number of the
 Item on the form to which the  information  on the
 separate sheet applies.

 (NOTE:  When submitting a  subsequent notification
form, notifiers must complete in their entirety Items I, II,
 III, VI, VII, VIII andX.  Other sections that are being
 added to (i.e., newly regulated activities) or altered (i.e.,
 installation contact) must also be  completed. All other
sections may be left blank.)
Item I — Installation's EPA ID Number:
Place an "X"  in  the appropriate box  to indicate
whether this is your first or a subsequent notification
for this site.  If you have filed a previous  notification,
enter the EPA Identification Number assigned to this
site in the boxes provided.  Leave EPA ID Number
blank if this is your first notification for this site.

Note: When the owner of a facility changes, the new
owner must notify U.S. EPA of the change, even if the
previous  owner  already  received  a   U.S.  EPA
Identification Number. Because the U.S.  EPA ID
Number is "site-specific," the new owner will keep the
existing ID number.  If the facility moves to another
location, the owner/operator must notify EPA of this
change.    In  this  instance   a  new  U.S.  EPA
Identification Number  will be  assigned, since the
facility has changed locations.

EPA Form 8700-12 (07-90) Previous edition is obsolete.
- 10-
     Items  II  and  III  —  Name  and  Location of
     Installation:
     Complete  Items  II and III.  Please note that the
     address you give for Item   III,  "Location of In-
     stallation," must be a physical  address, not a post
     office  box  or route number.

     County Name and Code:  Give the county code, if
     known. If you do not know the county code, enter the
     county name, from which  EPA can automatically
     generate the county  code.  If the county name is
     unknown contact the local Post Office. To obtain a list
     of county  codes, contact  the  National  Technical
     Information Service, U.S. Department of Commerce,
     Springfield, Virginia, 22161 or at  (703) 487-4650. The
     list of codes is contained in the Federal  Information
     Processing Standards   Publication  (FIPS  PUB)
     number 6-3.

     Item FV — Installation Mailing Address:
     Please enter the Installation Mailing Address. If the
     Mailing Address  and the Location of Installation
     (Item  III) are the same, you can  print "Same" in box
     for Item IV.

     Item V —  Installation Contact:
     Enter  the name, title, and business telephone number
     of the person who should  be contacted  regarding
     information submitted on this form.

     Item VI — Installation  Contact Address:

     A) Code:   If the contact address is the same as the
       location of installation address listed in Item III or
       the installation mailing address listed in Item IV,
       place an "X" in the  appropriate box to indicate
       where the contact may be reached. If the location
       of  installation address, the installation mailing
       address, and the installation contact  address are
       all the same, mark the "Location" box. If an "X" is
       entered  in either the location or mailing box, Item
       VT.  B. should be left blank.

    B) Address: Enter the contact address only if the
       contact  address is  different from  either  the

-------
   location of installation address (Item IE) or the
   installation mailing address (Item IV),  and Item
   VI. A. was left blank.

Item VII — Ownership:

A) Name: Enter the name of the legal owner(s) of the
   installation, including  the  property owner.  Also
   enter the address and phone number where this
   individual  can be reached.   Use the  comment
   section in XI or additional sheets if necessary to list
   more than one owner.
B) Land Type:  Using the codes listed below, indicate
   in VII. B. the code which best describes the current
   legal status  of the land on which  the facility is
   located:
    F  =
    S  =
    I   =
    P  =
    c  =
    M =
    D  =
    O  =
Federal
State
Indian
Private
County
Municipal*
District
Other
    *Note:  If the Land Type is best described as
    Indian, County or District, please use those
    codes.  Otherwise, use Municipal.

C) Owner  Type:   Using  the  codes  listed below,
   indicate in VII. C. the code which best describes
   the legal status of the current  owner of the facility:
    F  =
    S  =
    I   =
    P  =
    C  =
    M  =
    D  =
    O  =
Federal
State
Indian
Private
County
Municipal*
District
Other
    'Note:  If the Owner  Type is best described as
    Indian,  County or District, please use those
    codes.  Otherwise,  use Municipal.

D) Change of  Owner Indicator:    (// this  is your
   installation's first notification, leave Item  VII. D.
   blank and skip to Item VIII.  If this is a subsequent
   notification,  complete  Item  VII. D. as directed
   below.)

   If the owner of this facility has changed since the
   facility's original notification, place an "X" in the
   box marked "Yes"  and enter the date the owner
   changed.

EPA Form 8700-12 (07-90) Previous edition is obsolete.
   If the owner of this facility has not changed since
   the facility's original notification, place an "X" in
   the box marked "No" and skip to Item VIII.

   If  an  additional owner(s)  has  been  added or
   replaced  since the facility's original notification,
   place an  "X" in  the box marked "Yes".  Use the
   comment  section  in  XI  to list any  additional
   owners, the dates they became owners, and which
   owner(s) (if any) they replaced. If necessary attach
   a separate sheet  of paper.

Item VIII — Type of Regulated Waste Activity:

A) Hazardous Waste Activity:  Mark an "X" in  the
   appropriate box(es) to  show  which  hazardous
   waste activities are going on at this installation.

   1)  Generator: If you generate a  hazardous waste
      that is identified by characteristic or listed in 40
      CFR Part 261, mark an "X" in the appropriate
      box for the quantity of non-acutely hazardous
      waste that is generated per calendar month. If
      you generate  acutely hazardous waste please
      refer  to  40   CFR   Part  262  for  further
      information.

   2)  Transporter:  If you transport hazardous waste,
      indicate if it is your own waste, for commercial
      purposes,   or mark   both  boxes  if   both
      classifications apply.   Mark  an "X"  in  each
      appropriate box  to indicate the method(s) of
      transportation you use.  Transporters do not
      have to complete Item IX of this form, but must
      sign the certification in Item  X. The  Federal
      regulations for hazardous waste transporters
      are found in 40 CFR Part 263.

   3)  Treater/Storer/Disposer: If you treat,  store or
      dispose  of  regulated   hazardous  waste,  then
      mark an "X" in this box.  You are reminded to
      contact  the appropriate addressee listed for
      your State in Section III. C. of this package to
      request   Part  A  of  the  RCRA  Permit
      Application.   The Federal  regulations  for
      hazardous waste facility owners/ operators are
      found  in 40 CFR Parts 264  and 265.

   4)  Hazardous Waste  Fuel:    If  you  market
      hazardous  waste  fuel, place an "X" in the
      appropriate box(es).   If you  burn hazardous
      waste  fuel on-site,   place  an  "X"  in  the
      appropriate box and  indicate the type(s) of
      combustion devices in which  hazardous waste
      fuel is burned. (Refer to definition section for
      complete description of each device).

      Note:  Generators are  required  to  notify for
      waste-as-fuel activities  only if they market
      directly to the burner.
                                        • 11

-------
      "Other  Marketer" is defined as any  person,
      other than a generator marketing hazardous
      waste, who markets hazardous waste fuel.
   5) Underground   Injection  Control:    If  you
      generate  and/or treat, store  or dispose  of
      hazardous waste, place an "X" in the box if an
      injection well  is located at your installation.
      "Underground Injection" means the subsurface
      emplacement of fluids through a bored, drilled
      or driven well; or through a dug well, where the
      depth of the dug well is greater than the largest
      surface dimension.

 B) Used Oil Fuel Activities
   Mark an "X" in the appropriate box(es) to indicate
   which used oil fuel activities are taking place at
   this installation.
   1) Off-Specification Used Oil Fuel:  If you market
      off-specification used oil, place an "X" in the
      appropriate box(es).  If you burn used oil fuel
      place an "X" in the box(es) below to indicate
      type(s)  of  combustion   devices  in  which
      off-specification used oil fuel is burned.  (Refer
      to definition section for complete description of
      each device).
      Note: Used oil generators are required to notify
      only if marketing directly to the burner.
      "Other  Marketer" is defined as any  person,
      other than a generator marketing his  or  her
      used oil, who markets used oil fuel.
   2) Specification Used Oil Fuel: If you are the first
      to claim that the used oil meets the specification
      established in 40 CFR 266.40(e) and is  exempt
      from further regulation, you must mark an "X"
      in this box.

Item IX — Description of Regulated Wastes:
(Only persons involved in  hazardous   waste activity
(Item VIII A.) need to complete this item. Transporters
requesting a U.S. EPA  Identification Number do  not
need  to complete this item,   but  must sign  the
"Certification" in Item X.)
You will need to  refer to 40 CFR Part 261 (enclosed as
Section VII) in order to complete this section. Part
261  identifies  those  wastes that EPA defines as
hazardous.  If you need help completing this section,
please contact the appropriate addressee for your
State as listed in Section III. C. of this package.
A) Characteristics of Nonlisted Hazardous Wastes: If
you handle hazardous wastes which are not listed in 40
CFR  Part  261,  Subpart  D  but  do  exhibit a
characteristic  of hazardous waste as defined in 40
CFR Part 261, Subpart C, you  should describe these
wastes by the  EPA hazardous  waste number for the
characteristic.  Place  an "X" in the box next  to the
characteristic  of the wastes that you handle.  If you
mark  "4. Toxicity Characteristic,"  please list  the
specific EPA hazardous waste number for the specific
contaminant(s)  in  the  box(es) provided.  Refer to
Section VIII to determine the appropriate hazardous
waste number.

B) Listed Hazardous Wastes: If you handle hazardous
wastes that are listed in  40 CFR Part 261, Subpart D,
enter the appropriate 4-digit  numbers in the boxes
provided.
Note - If you  handle  more than 12 listed hazardous
wastes, please  continue listing the waste  codes on the
extra sheet provided at the end of this booklet. If it is
used,  attach  the additional page to the rest of the form
before mailing it to the appropriate EPA Regional or
State  Office.

C) Other Wastes: If you handle other wastes or State
regulated wastes that have  a  waste  code, enter  the
appropriate code number in the boxes provided.

Item  X — Certification:
This  certification  must be signed  by the owner,
operator, or an  authorized representative of your
installation.   An "authorized    representative" is a
person responsible for  the overall operation of  the
facility (i.e.,  a  plant manger or superintendent, or a
person of equal responsibility). All notifications must
include this certification to be complete.

Item XI — Comments:
Use this space for any additional comments.
EPA Form 8700-12 (07-90) Previous edition is obsolete.
                                                 - 12-

-------
Please print or type with ELITE type (12 characters per inch) in the unshaded areas only
                                                          Form Approved. OMB No. 2050-0028. Expires W-31-91
                                                                      	GSA No. 0246-EPA-OT
 Please refer to the Instructions
 for Filing Notification before
 completing this form.  The
 information requested here is
 required by law (Section 3010
 of the Resource Conservation
 and Recovery Act),
   Notification  of
Regulated Waste
        Activity
                                     United States Environmental Protection
                                                                         Date Received
                                                                     (For Official Use Only)
 1. Installation's EPA ID Number (Mark X In the appropriate box)
      A. First Notification
            B. Subsequent Notification
             (complete item C)
                                                                          C. Installation's EPA ID Number
 II. Name of Installation (Include company and specific site name)
 111. Location of Installation (Physical address not P.O. Box or Route Number)
 Street (continued)
            Countv Name
 IV. Installation Mailing Address (See Instructions)
 Street or P.O. Box
 V. Installation Contact (Person to be contacted regarding waste activities at site)
                                                        Phone Number (ana code and number)
 VI. installation Contact Address (See Instructions)
A. Contact Address
 location   Mailing
B. Street or P.O. Box
 VII. Ownership (See instructions)
  A. Name of Installation's Legal Owner
  Street, P.O. Box, or Route Number
  City or Town
                                                State
  Phone Number (area code and number)
                                             B. Land Type
                                      C. Owner Type
                            of Owner     (Date Changed)
                                       Month    Pay    Year
                                                                                              LLJ.
EPA Form 8700-12 (01-90) Previous edition is obsolete.
                                                                                               Continue on reverse

-------
Please print or type with ELITE type (12 characters per inch) in the unshaded areas only
                                                          Fom Approved. OMB No. 2050-0028. Expires W-31-91
                                                                               GSANo. 0246-EPA-OT
                                                                                      ID - For Official Use Only
 VIII. Type of Regulated Waste Activity (Mark 'X* In the appropriate boxes. Refer to instructions.)
                          A. Hazardous Waste Activity
                                                         B. Used Oil Fuel Activities
    1. Generator (See Instructions)
      a.  Greater than 1QOOkg/mo {2,200 Ibs.)
      b.  100 to 1000 kg/mo (220 - 2,200 Ibs,)
      c.  Less than 100 kg/mo (220 Ibs.)
    2. Transporter (Indicate Mode in boxes 1-5 below)
      a.  For own waste only
      b.  For commercial purposes
      Mode of Transportation
     [~]  1. Air
         2. Rail
                || 3. Treater, Storer, Disposer (at Installation)
                       Note: A permit is required for
                       this activity; see instructions.
                    4. Hazardous Waste Fuel
                       a.  Generator Marketing to Burner
                       b.  Other Marketers
                       c.
                                                                                   D
                                                                                   D
                                                                                  1. Off-Specificaton Used Oil Fuel
                                                                                  ]  a.  Generator Marketing to Burner
                                                                                    b.  Other Markerer
D
|~l 3. Highway
D 4. Water
f~~| 5. Other - specify
                                                    Burner - indicate devtee(s) -
                                                   _Type of Combustion Device
                                                      1. Utility Boiler
                                                      2. Industrial Boiler
                                                      3. Industrial Furnace
                                           L_J 5. Underground Injection Control
                                                                                    c.  Burner - indicate device(s) -
                                                                                        Type of Combustion Device
                                                                                      E3 1. Utility Boiler
                                                                                      |~"l 2. Industrial Boiler
                                                                                      I   I 3. Industrial Furnace
                                                            2.  Specification Used Oil Fuel Marketer
                                                               (or On-stte Burner) Who Rrst Claims
                                                               the Oil Meets trie Specification
 IX. Description of Regulated Wastes (Use additional sheets If necessary)
     Characteristics of Nonlisted Hazardous Wastes. Mark 'X' in the boxes corresponding to the characteristics of nonlisted hazardous
     wastes your installation handles.  (See 40 CFR Parts 261.20 - 261.24)	
A.

1. Ignltable
              2, Corrosive
                 (D002)
3. Reactive  4. EP Toxic
  (D003)      (POOP)
                                                   (Ust specific EPA hazardous waste number(s) tor the EP Toxic contaminants))
 | B.  Listed Hazardous Wastes. (See40CFR 261.31 - 337See instructions if you need to list more than 12 waste codesT)
1






7




2




8






3

v

9







4




10






5




11






6




12




pC.  Other Wastes. (State or other wastes requiring an I.D. number. See instructions.) |
 / certify under penalty of law that I have personally examined and am familiar with the information submitted in this
 and all attached documents, and that based on my Inquiry of those Individuals Immediately responsible for
 obtaining the information, I believe that the submitted Information Is true, accurate, and complete.  I am aware
 that there are significant penalties  for submitting false Information,  Including the  possibility of fines and
 imprisonment.	
Signature
              Name and Official Title (type or print)
                                                                                        Date Signed
XI, Comments
| Note: Mail completed form to the appropriate EPA Regional or State Office.  (See Section III of the booklet for addresses.) \
EPA Form 8700-12 (01-90) Previous edition is obsolete.
                                -2-

-------
Please print or type with ELITE type (12 characters per inch) in the unshaded areas only
                                                              Form Approved. OMB No. 2050-0028. Expires 10-31-91
                                                                          	GSANO. 0246-£PA-OT_
 Please refer to the Instructions
 for Filing Notification before
 completing this form.   The
 information requested here is
 required by law (Section 3010
 of the Resource Conservation
 and Recovery Act).
              $EPA
  Notification of
Regulated Waste
        Activity
                                    United States Environmental Protection
    Date Received
(For Official Use Only)
 I. Installation's EPA ID Number (Mark 'X" In the appropriate box)
      A. First Notification
                  B. Subsequent Notification
                   (complete Item C)
                                                                        C. Installation's EPA ID Number
 IK Name of Installation (Include company and specific site name)
 III. Location of Installation (Physical address not P.O. Box or Route Number)
 Street
 Street (continued)
 City or Town
                                                                State
                                                           ZIP Code
County Code
County Name
 IV. Installation Mailing Address (See Instructions)
 Street or P.O. Box
 City or Town
                                                                State
                                                           ZIP Code
 V. Installation Contact (Person to be contacted regarding waste activities at site)
 Name (last)
                                          (first)
 Job Title
                                           Phone Number (area code and number)
 VI. Installation Contact Address (See Instructions)
A. Contact Address
 Location  Mailing
      B. Street or P.O. Box
 City or Town
                                                    State
                       ZIP Code
 VII. Ownership (See Instructions)
  A. Name of Installation's Legal Owner
  Street, P.O. Box, or Route Number
  City or Town
                                                    State
                                                                       ZIP Code
  Phone Number (area code and number)
                                           B. Land Type
                                           C. Owner Type
                   D. Change of Owner
                        Indicator
                                                                   Yes
                                                               No
   (Date Changed)
 Month    Day    Year
                                          DLL
EPA Form 8700-12 (01-90) Previous edition is obsolete.
                                                                                .Continue on reverse

-------
Please print or type with ELITE type (12 characters per inch) in the unshaded areas only
                                                                                 Form Approved. OMB No. 2050-0028. Expires 10-31-91
                                                                                                       GSA No. 0246-EPA-OT
                                                                                       ID - For Official Use Only
 VIII. Type of Regulated Waste Activity (Mark 'X' In the appropriate boxes. Refer to Instructions.)
                          A. Hazardous Waste Activity
                                                                                 B, Used Oil Fuel Activities
                                           D
D
D
1,  Generator (See Instructions)
   a.  Greater than 1000kg/mo (2,200 Ibs.)
   b.  100 to 1000 kg/mo (220 - 2,200 Ibs.)
   c.  Less than 100 kg/mo (220 fbs.)
2.  Transporter (Indicate Mode in boxes 1-5 below)
   a.  For own waste only
   b.  For commercial purposes
   Mods of Transportation
      1.  Air
      2.  Rail
      3.  Highway
      4.  Water
      5.  Other - specify
     D
     D
3. Treater, Storer, Disposer (at installation)
  Note: A permit is required for
  this activity: see instructions.
4. Hazardous Waste Fuel
  a.  Generator Marketing to Burner
  b.  Other Marketers
  c.  Burner - indicate devtee(s) -
      Type of Combustion Device
         1.  Utility Boiler
         2.  Industrial Boiler
     	I  3.  Industrial Furnace
5. Underground Injection Control
   1. Off-Specification Used Oil Fuel
I""]}  a.  Generator Marketing to Burner
[~~l  b.  Other Markerer
I   I  c.  Burner - indicate device(s) -
        Type of Combustion Device
      LJ 1.  Utility Boiler
      I  I 2.  Industrial Boiler
      I	I 3.  Industrial Furnace
                                                                                       2. Specification Used Oil Fuel Marketer
                                                                                          (or On-site Burner) Who First Claims
                                                                                          the Oil Meets trie Specification
 IX. Description of Regulated Wastes (Use additional sheets If necessary)
 A. Characteristics of Nonlisted Hazardous Wastes. Mark 'X' in the boxes corresponding to the characteristics of nonlisted hazardous
[	wastes your installation handles. (See 40 CFR Parts 261.20 - 261.24)	
 1. Ignitable
    (D001)
           2. Corrosive 3. Reactive 4. EP Toxic
              (DQ02J      (DQ03)      (D0QQ)
     (List specific EPA hazardous waste number(s) for the EP Toxic contaminants))
 B.  Listed Hazardous Wastes. (See 40 CFR 261.31 -33. See instructions if you need to list more than 12 waste codes.)  |
1






7





2




8







3







9





4




10





5




11





6





12





I C.  Other Wastes. (State or other wastes requiring an I.D. number.  See instructionsT);
 / certify under penalty of law that I have personally examined and am familiar with the information submitted in this
 and all attached documents, and that based on my inquiry of those individuals immediately responsible for
 obtaining the information, I believe that the submitted information is true, accurate, and complete. I am aware
 that there are significant penalties  for submitting false information, including the possibility  of  fines and
 imprisonment.
Signature
                                      Name and Official Title (type or print)
                                           Date Signed
| Note: Mail completed form to the appropriate EPA Regional or State Office. (See Section III of the booklet for addresses.) ]
EPA Form 8700-12 (01-90) Previous edition is obsolete.
                                                        -2-

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V.     Definitions
The following definitions are included to help you to
understand and complete the Notification Form:

ACT or RCRA means the Solid Waste Disposal Act,
as  amended by  the  Resource  Conservation and
Recovery Act of 1976, as amended by the Hazardous
and Solid Waste Amendments of 1984, 42  U.S.C.
Section 6901  et seq.

Authorized   Representative  means   the   person
responsible for the overall operation of the facility or
an  operational unit  (i.e.,  part of a facility), e.g.,
superintendent or  plant  manager,  or  person  of
equivalent responsibility.

Boiler means an enclosed  device using controlled
flame   combustion   and   having  the  following
characteristics:
  (1)  the unit has physical  provisions for recovering
      and exporting energy in the form of  steam,
      heated fluids, or heated gases;

  (2)  the unit's combustion chamber and primary
      energy recovery section(s) are of integral design
      (i.e.,  they  are  physically  formed  into one
      manufactured or assembled unit);

  (3)  the unit  continuously maintains an  energy
      recovery  efficiency of at  least  60  percent,
      calculated in terms  of the  recovered  energy
      compared with the thermal value of the fuel;

  (4)  the unit exports and utilizes at least 75 percent
      of the recovered energy, calculated on an  annual
      basis (excluding recovered heat used internally
      in the same unit, for example, to preheat fuel or
      combustion  air  or drive fans  or feedwater
      pumps); and

  (5)  the  unit  is   one   which   the  Regional
      Administrator   has   determined    on   a
      case-by-case  basis,   to  be  a  boiler after
      considering the  standards in 40 CFR 260.32.
Burner means the owner or operator of any boiler or
industrial furnace that burns hazardous waste fuel for
energy recovery and that is not regulated as a RCRA
hazardous waste incinerator.

Disposal means the  discharge, deposit,  injection,
dumping, spilling,  leaking, or placing of  any solid
waste or hazardous waste into or on any land or water
so that such solid waste or  hazardous waste or any
constituent thereof may enter the environment or be

EPA Form 8700-12 (07-90) Previous edition is obsolete.
     emitted into the air or discharged into any waters,
     including ground waters.

     Disposal Facility means a facility or part of a facility at
     which hazardous waste is intentionally placed into or
     on any land or water, and at which waste will remain
     after closure.

     EPA Identification (I.D.) Number means the number
     assigned by EPA to each generator, transporter, and
     treatment, storage, or disposal facility.

     Facility means all contiguous land, structures, other
     appurtenances, and improvements on the land, used
     for treating, storing, or disposing of hazardous waste.
     A facility may consist of several treatment, storage, or
     disposal operational units (e.g., one or more landfills,
     surface impoundments, or combinations of them).


     Generator means any  person, by site, whose act  or
     process produces hazardous waste identified or listed
     in 40 CFR Part 261.

     Hazardous  Waste  means  a  hazardous  waste  as
     defined in 40 CFR 261.3.

     Hazardous Waste Fuel means hazardous waste and
     any fuel that contains hazardous waste that is burned
     for energy recovery in  a boiler or industrial furnace
     that is not subject to regulation as a RCRA hazardous
     waste incinerator. However, the following hazardous
     waste fuels are subject  to regulation as used oil fuels:
      (1)  Used oil fuel burned for energy recovery that is
          also a hazardous waste solely because it exhibits
          a characteristic of hazardous waste identified in
          Subpart C of 40 CFR Part 261; and

      (2)  Used oil fuel  mixed with hazardous wastes
          generated by a small quantity generator subject
          to 40 CFR 261.5.

     Industrial Boiler means a boiler located on the site of
     a facility engaged in  a  manufacturing process where
     substances  are  transformed  into  new  products,
     including    the  component parts of products, by
     mechanical or chemical processes.

     Industrial Furnace  means  any  of the  following
     enclosed  devices that are integral  components  of
     manufacturing processes and  that use controlled
     flame combustion to accomplish recovery of materials
     or  energy: cement kilns, lime kilns, aggregate kilns
     (including asphalt kilns), phosphate kilns, coke ovens,
     blast furnaces, smelting furnaces,  refining  furnaces,
     titanium dioxide chloride process oxidation reactors,
- 13-

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methane reforming furnaces, pulping liquor recovery
furnaces, combustion devices used in the recovery of
sulfer values  from spent  sulfuric acid,  and other
devices  as the Administrator may add to this list.

Marketer means a person who  markets hazardous
waste fuel  or used oil  fuel. However, the following
marketers are not subject  to waste-as-fuel require-
ments (including notification) under Subparts D and
E of 40 CFR Part 266:
  (1)  Generators   and  initial  transporters  (i.e.,
      transporters who receive hazardous waste or
      used  oil  directly from  generators including
      initial   transporters  who  operate  transfer
      stations) who do not market directly to persons
      who burn the fuels; and

  (2)  Persons who market used oil fuel that meets the
      specification provided under 40 CFR 266.40(e)
      and who are not the first to claim the oil meets
      the specification.

Municipality  means  a city, village, town, borough,
county, parish,  district, association, Indian tribe or
authorized Indian tribal organization, designated and
approved management agency under Section 208 of
the Clean Water Act, or any other public body created
by  or under State law and having jurisdiction  over
disposal of sewage, industrial wastes, or other wastes.

Off-Specification  Used Oil Fuel means used oil fuel
that does not meet the specification provided under 40
CFR 266.40(e).

Operator means the person responsible for the overall
operation of a facility.

Owner means a person who owns a facility or part of a
facility, including landowner.

Specification Used Oil  Fuel means used oil fuel that
meets  the  specification  provided  under  40 CFR
266.40(e).

Storage means  the holding of hazardous waste for a
temporary period, at the end of which the hazardous
waste is treated, disposed of, or stored elsewhere.
Transportation means the movement of hazardous
waste by air, rail, highway, or water.

Transporter means a person engaged in the off-site
transportation  of  hazardous  waste  by  air,  rail,
highway, or water.

Treatment means any method, technique, or process,
including  neutralization, designed  to change  the
physical,   chemical,  or  biological  character  or
composition of  any hazardous  waste  so  as to
neutralize  such waste, or so as to recover energy or
material resources from the waste, or so as to render
such waste nonhazardous, or less hazardous; safer to
transport,  store  or  dispose  of;  or amenable  for
recovery, amenable for storage, or reduced in volume.
Such  term  includes any  activity or  processing
designed to change the physical form or composition
of hazardous waste so as to render it nonhazardous.

Used Oil means  any oil that has been refined from
crude oil, used, and as a result of such use, is
contaminated by physical  or  chemical  impurities.
Wastes that contain oils that have not been used (e.g.,
fuel oil storage tank bottom  clean-out wastes) are not
used oil unless they are mixed with used oil.

Used Oil Fuel means any used oil burned (or destined
to be burned) for energy recovery including any fuel
produced from used oil by processing, blending or
other treatment, and that does not contain hazardous
waste (other than that generated by a small quantity
generator and exempt from regulation as hazardous
waste under provisions of 40 CFR 261.5). Used oil fuel
may itself exhibit a characteristic of hazardous waste
and remain subject  to regulation as  used oil fuel
provided it is not mixed with hazardous waste.

Utility Boiler means a boiler that is used to produce
electricity, steam or heated or cooled air or other gases
or fluids for sale.

Waste Fuel means hazardous  waste fuel  or  off-
specification used oil fuel.
 EPA Form 8700-12 (07-90) Previous edition is obsolete.
                                                 - 14-

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VI.   EPA Hazardous Waste Numbers for
      Waste Streams Commonly Generated by
      Small  Quantity Generators
The  Environmental  Protection Agency recognizes
that  generators of small  quantities of hazardous
waste, many of which are small businesses, may not be
familiar with the manner in which hazardous waste
materials  are identified  in   the  Code  of  Federal
Regulations.  This insert has been assembled  in order
to aid small quantity generators in determining for
their wastes the EPA  Hazardous Waste Numbers
that  are needed to  complete the "Notification of
Regulated Waste Activity," Form 8700-12.

This insert is composed of two tables. Table 1 lists
eighteen general  industry categories that  contain
small  quantity  generators.    For each of these
categories, commonly  generated  hazardous waste
streams are identified. Table 2 lists EPA Hazardous
Waste  Numbers for each waste stream identified in
Table  1.

To use this insert:

     1.  Locate your industry in Table 1 to identify the
        waste streams common  to your activities.

     2.  Find each of your waste streams in Table 2,
        and review the more detailed descriptions of
        typical  wastes to determine  which waste
        streams actually result from your activities.

     3.  If you determine that a waste stream does
        apply  to  you, report the   4-digit  EPA
        Hazardous Waste Number in Item IX. B. of
        Form 8700-12,  "Notification of Regulated
        Waste Activity."

The industries and waste  streams described here do
not provide a comprehensive list but rather serve as a
guide to potential  small  quantity   generators in
determining which  of their  wastes,  if  any,  are
hazardous.   Except  for the pesticide category,  this
insert does  not  include  EPA Hazardous  Waste
Numbers for commercial chemical products that are
hazardous when discarded unused. These chemicals
and their EPA Hazardous Waste Number are listed
in 40 CFR 261.33.
If the specific Hazardous Waste Number that should
be applied to your  waste stream  is unclear, please
refer to 40 CFR Part 261, reprinted in Section VII of
this notification package.  In those cases where more
than one Hazardous  Waste Number is applicable, all
should be used. If you have any questions, or if you
are unable to determine the proper EPA Hazardous
Waste Numbers for  your  wastes, contact your state
hazardous waste management agency as  listed in
Section  III  of this  notification  package,  or  the
RCRA/Superfund Hotline at 1-800-424-9346.
EPA Form 8700-12 (07-90) Previous edition is obsolete.
                                               -15-

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                                                Table 1

             Typical Waste Streams Produced by Small Quantity Generators
              Industry
Waste Streams
              Laboratories
              Printing and Allied Industries
               Pesticide End Users and Application
               Construction
               Equipment Repair
               Furniture/Wood Manufacturing and
               Refinishing

               Other Manufacturing:
                          1) Textiles
                          2) Plastics
                          3) Leather

               Laundries and Dry Cleaners
               Educational and Vocational Shops
               Building Cleaning and Maintenance
               Vehicle Maintenance
Acids/Bases
Heavy Metals/Inorganics
Ignitable Wastes
Reactives
Solvents

Acids/Bases
Heavy Metals/Inorganics
Ink Sludges
Spent Plating Wastes
Solvents

Heavy Metals/Inorganics
Services
Pesticides
Solvents

Acids/Bases
Ignitable Wastes
Solvents

Acids/Bases
Ignitable Wastes
Lead Acid Batteries
Solvents

Ignitable Wastes
Solvents
Heavy Metals/Inorganics
Solvents
Dry Cleaning Filtration
Residues
Solvents

Acids/Bases
Ignitable Wastes
Pesticides
Reactives
Solvents

Acid/Bases
Solvents

Acids/Bases
Heavy Metals/Inorganics
Ignitable Wastes
Lead Acid Batteries
Solvents
                                                   - 16-
EPA Form 8700-12 (07-90) Previous edition is obsolete.

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                                          Table 1 (continued)

              Typical Waste Streams Produced by Small Quantity Generators
               Industry
               Wood Preserving

               Motor Freight Terminals and Railroad
               Funeral Services

               Metal Manufacturing
               Chemical Manufacturers
               Cleaning Agents and Cosmetics
               Formulators
Waste Streams
Preserving Agents

Acids/Bases
Transportation
Heavy Metals/Inorganics
Ignitable Wastes
Lead Acid Batteries
Solvents

Solvents (formaldehyde)

Acids/Bases
Cyanide Wastes
Heavy Metals/Inorganics
Ignitable Wastes
Reactives
Solvents
Spent Plating Wastes

Acids/Bases
Cyanide Wastes
Heavy Metals/Inorganics
Ignitable Wastes
Reactives
Solvents

Acids/Bases
Heavy Metals/Inorganics
Ignitable Wastes
Pesticides
Solvents

Acids/Bases
Cyanide Wastes
Heavy Meals/Inorganics
Ignitable Wastes
Pesticides
Reactives
Solvents
                                                   -17-
EPA Form 8700-12 (07-90) Previous edition is obsolete.

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                                              Table 2

               Typical Waste Streams and EPA Hazardous Waste Numbers
ACIDS/BASES:
Acids, bases or mixtures having a pH less than or equal to 2 or greater than or equal to 12.5, or liquids that corrode
steel at a rate greater than 0.25 inches per year, are considered to be corrosive (for a complete  description of
corrosive wastes, see 40 CFR 261.22, Characteristic of corrosivity).  All corrosive materials and solutions have the
EPA Hazardous  Waste Number of D002.  The following are some examples of the  more commonly used
corrosives:
                        Examples of Corrosive Waste Streams
              Acetic Acid                                Oleum
              Ammonium Hydroxide                       Perchloric Acid
              Chromic Acid                              Phosphoric Acid
              Hydrobromic Acid                          Potassium Hydroxide
              Hydrochloric Acid                          Sodium Hydroxide
              Hydrofluoric Acid                          Sulfuric Acid
              Nitric Acid


 DRY CLEANING FILTRATION RESIDUES:

 Cooked powder residue (perchloroethylene plants only), still residues and spent cartridge filters containing
 perchloroethylene or valclene are hazardous and have an EPA Hazardous Waste Number of F002.

 Still residues containing petroleum solvents with a flash point less than  140° F are also considered hazardous, and
 have an EPA Hazardous Waste Number of D001.


 HEAVY METALS/INORGANICS:

 Heavy Metals and other inorganic waste materials exhibit the characteristic of EP Toxicity and are considered
 hazardous if the extract from  a  representative sample  of the waste has any of the  specific constituent
 concentrations as shown in 40 CFR 261.24, Table  1. This may include dusts, solutions, wastewater treatment
 sludges, paint wastes, waste  inks and other  such materials which contain heavy metals/inorganics (note that
 wastewater  treatment sludges from electroplating operations containing nickel and cyanide, are identified as
 F006). The  following are EP Toxic:

              Waste Stream                            EPA Hazardous Waste Number

              Arsenic                                             D004
              Barium                                             D005
              Cadmium                                           D006
              Chromium                                          D007
              Lead                                               D008
              Mercury                                            D009
              Selenium                                           D010
              Silver                                              DO 11


 IGNITABLE WASTES:

 Ignitable wastes include any flammable liquids, nonliquids, and contained gases that have a flashpoint less than
 140F (for a complete description of ignitable wastes, see 40 CFR 261.21, Characteristic of ignitability). Examples
 are spent solvents (see also solvents), solvent still bottoms, ignitable paint wastes (paint removers, brush cleaners
                                               - 18-
 EPA Form 8700-12 (07-90) Previous edition is obsolete.

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                                        Table 2 (continued)

and stripping agents), epoxy resins and adhesives (epoxies, rubber cements and marine glues), and waste inks
containing flammable solvents. Unless otherwise specified, all  ignitable wastes have an EPA Hazardous Waste
Number of D001.

Some commonly used ignitable compounds are:

              Waste Stream                           EPA Hazardous Waste Number

              Acetone                                             F003
              Benzene                                            D001
              n-Butyl Alcohol                                      F003
              Chlorobcnzene                                       F002
              Cychlohexanone                                      F003
              Ethyl Acetate                                        F003
              Ethylbenzene                                        F003
              Ethyl Ether                                          F003
              Ethylene Dichloride                                   D001
              Methanol                                           F003
              Methyl Isobutyl Ketone                                F003
              Petroleum Distillates                                  D001
              Xylene                                             F003


INK SLUDGES CONTAINING CHROMIUM AND LEAD:

This includes solvent washes and sludges, caustic washes and sludges, or waster washes and sludges from cleaning
tubs and equipment  used in the  formulation of ink from pigments, driers, soaps, and stabilizers containing
chromium and lead.  All ink sludges have an EPA Hazardous  Waste Number of K086.


LEAD ACID BATTERIES:

Used lead acid batteries should be reported on the notification form only if they are not recycled. Used lead acid
batteries that are recycled do not need to be counted in determining the quantity of waste that you generate per
month,  nor  do they require  a hazardous waste manifest when shipped off your  premises. (Note:   Special
requirements do apply if you recycle your batteries on your own premises — see 40 CFR Part 266.)

              Waste Stream                           EPA Hazardous Waste Number

              Lead Dross                                          D008
              Spent Acids                                          D002
              Lead Acid Batteries                                   D008, D002
ORGANIC WASTES:

See Section VIII, Table 1-Maximum Concentration of Contaminants for the Toxicity Characteristic for a list of
constituents and regulatory levels.


PESTICIDES:

Pesticides, pesticide residues, washing and rinsing solutions and dips which contain constituent concentrations at
or above Toxicity Characteristic regulatory levels (see Section VIII) are hazardous waste. Pesticides that have an
oral LD50 toxicity (rat) < 50 mg/kg, inhalation LC50 toxicity (rat) < 2 mg/L or a dermal LD 50 toxicity (rabbit)
                                               - 19 -
EPA Form 8700-12 (07-90) Previous edition is obsolete.

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                                         Table 2 (continued)
< 200 mg/kg, are hazardous materials.  The following pesticides would be hazardous waste if they are technical
grade, unused and disposed.  For a more complete  listing, see 40 CFR 261.32-33 for specific listed pesticides,
discarded commercial chemical products, and other   wastes, wastewaters, sludges, and by-products from
pesticide production.  (Note that while many of these pesticides are not longer in common use, they are included
here for those cases where they may be found in storage.)
              Waste Stream
EPA Hazardous Waste Number
              Aldicarb
              Aldrin
              Amitrole
              Arsenic Pentoxide
              Arsenic Trioxide
              Cacodylic Acid
              Carbamic Acid, Methylnitroso-
              Ethyl Ester
              Chlordane
              Copper Cyanides
              1,2-Dibromo-3-Chloropropane
              1,2-Dichloropropane
              1,3-Dichloropropene
              2,4-Dichlorophenoxy Acetic Acid
              DDT
              Dieldrin
              Dimethoate
              Dimethylcarbamoyl Chloride
              Dinitrocresol
              Dinoseb
              Disodium Monmomethane arsonate
              Disulfoton
              Endosulfan
              Endrin
              Ethylmercuric Chloride
              Famphur
              Nepthachlor
              Hexachlorobenzene
              Kepone
              Lindane
              2-Methoxy Mercuric Chloride
              Methoxychlor
              Methyl Parahtion
              Monosodium Methanearsonate
              Nicotine
              Parathion
              Pentachloronitrobenzene
              Pentachlorophenol
              Phenylmercuir Acetate
              Phorate
           P070
           P004
           U011
           P011
           P012
           U136

           U178
           U036
           P029
           U066
           U083
           U084
           U240
           U061
           P037
           P044
           U097
           P047
           P020
           D004
           P039
           P050
           P051
           D009
           P097
           P059
           U127
           U142
           U129
           D009
           D014
           P071
           D004
           P075
           P089
           U185
           U242
           D009
           P094
EPA Form 8700-12 (07-90) Previous edition is obsolete.
                                                 -20-

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                                         Table 2 (continued)
              Strychnine
              2,4,5-Trichlorophenoxy Acetic  Acid
              2-(2,4,5-Trichlorophenoxy)-Propionic Acid
              Thallium Sulfate
              Thiram
              Toxaphene
              Warfarin
           P108
           U232
           U233
           P115
           U244
           P123
           U248
SOLVENTS:

Spent solvents, solvent still bottoms or mixtures containing solvents are  often hazardous. This includes solvents
used in degreasing and paint brush cleaning, and distillation residues from reclamation. The following are some
commonly used hazardous solvents (see also ignitable wastes for other hazardous solvents, and 40 CFR 261.31 for
most listed hazardous waste  solvents):
              Waste Stream
EPA Hazardous Waste Number
Benzene
Carbon Disulfide
Carbon Tetrachloride
Chlorobenzene
Cresols
Cresylic Acid
O-Dichlorobenzene
Ethanol
Ethylene Dichloride
Isobutanol
Isopropanol
Kerosene
Methyl Ethyl Ketone
Methylene Chloride
Naphtha
Nitrobenzene
D001
F005
F001
F002
F004
F004
F002
D001
D001
F005
D001
D001
F005
F001
F002
D001
F004









(Sludges)
(Still Bottoms)
              Petroleum Solvents (Flash-
              point less than 140F)
              Pyridine
              1,1,1 -Trichloroet hane

              Tetrachloroethylene

              Toluene
              Trichloroethylene

              Trichlorofluoromethane
              Trichlorotrifluoroethane
              White Spirits
D001
F005
F001
F002
F001
F002
F005
F001
F002
F002
F002
D001


(Sludges)
(Still Bottoms)
(Sludges)
(Still Bottoms)

(Sludges)
(Still Bottoms)



EPA Form 8700-12 (07-90) Previous edition is obsolete.

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                                        Table 2 (continued)
REACTTVES:
Reactive wastes include reactive materials or mixtures which are unstable, react violently with or form explosive
mixtures with water, generate  toxic gases or vapors when mixed with water (or when exposed to pH conditions
between 2 and 12.5 in the case of cyanide or sulfide bearing wastes), or are  capable of detonation or explosive
reaction when irritated or heated (for a complete description of reactive wastes, see 40 CFR 261.23, Characteristic
of reactivity).  Unless otherwise specified, all reactive wastes have an EPA Hazardous Waste Number of D003.
The following materials are commonly considered to be reactive:


              Waste Stream                           EPA Hazardous Waste Number

              Acetyl Chloride                                      D003
              Chromic Acid                                        D003
              Cyanides                                            D003
              Organic Peroxides                                    D003
              Perchlorates                                         D003
              Permanganates                                       D003
              Hypochlorites                                        D003
              Sulfides                                             D003
 SPENT PLATING AND CYANIDE WASTES:

 Spent plating wastes contain cleaning solutions and plating solutions  with caustics, solvents, heavy metals and
 cyanides.  Cyanide wastes may also  be generated from heat treatment operations, pigment production and
 manufacturing of anti-caking agents. Plating wastes are generally Hazardous Waste Numbers F006-F009.  Heat
 treatment wastes are generally Hazardous Waste  Numbers F010-F012. See 40 CFR 261.31 for a more complete
 description of plating wastes.


 WOOD PRESERVING AGENTS:

 Compounds or mixtures used in wood preserving, including the wastewater  treatment sludge from wastewater
 treatment operations, are considered hazardous. Bottom sediment sludges from the treatment of wastewater
 processes that use creosote or pentachlorophenol are hazardous, and have an EPA Hazardous Waste Number of
 K001.  Unless otherwise indicated, specific wood  preserving components are:

              Waste Stream                           EPA Hazardous Waste Number

              Chromated Copper Arsenate                           D004
              Creosote                                            K001
              Pentachlorophenol                                   K001
                                                -22-
EPA Form 8700-12 (07-90) Previous edition Is obsolete.

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VII.  Reprint of Part 261 from Title 40 of the
     Code of Federal Regulations
                                                    Protection  of
                                                    Environment
                                                    40
                                                    PART 261

                                                    Revised as of July 1, 1989

                                                    CONTAINING
                                                    A CODIFICATION OF DOCUMENTS
                                                    OF GENERAL APPLICABILITY
                                                    AND FUTURE EFFECT

                                                    AS OF JULY 1, 1989
                                                    With Ancillaries


                                                    Published by
                                                    the Office of the Federal Register
                                                    National Archives and Records
                                                    Administration

                                                    as a Special Edition of
                                                    the Federal Register

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Part 261
          40 CFR Ch. I (7-1-89 Edition)
  PART 261—IDENTIFICATION AND
  LISTING OF HAZARDOUS WASTE

           Subpart A—General

Sec.
261.1  Purpose and scope.
261.2  Definition of solid waste.
261.3  Definition of hazardous waste.
261.4  Exclusions.
261.5  Special requirements  for hazardous
   waste   generated   by   conditionally
   exempt small quantity generators.
261.6  Requirements for recyclable materi-
   als.
261.7  Residues of  hazardous  waste  in
   empty containers.

Subpart B—Criteria for Identifying the Charac-
    teristics of Hazardous Waste and for List-
    ing Hazardous Wastes

261.10  Criteria for identifying the charac-
   teristics of hazardous waste.
261.11  Criteria for  listing hazardous waste.

   Subpart C—Characteristics of Hazardous
                Waste

261.20  General.
261.21  Characteristic of ignitability.
261.22  Characteristic of corrosivity.
261.23  Characteristic of reactivity.
261.24  Characteristic of EP toxicity.

    Subpart D—Lists  of Hazardous Wastes

261.30  General.
261.31  Hazardous wastes from non-specific
   sources.
261.32  Hazardous  wastes   from   specific
   sources.
261.33  Discarded   commercial  chemical
   products, off-specification species, con-
   tainer residues, and spill residues there-
   of.

              APPENDICES

APPENDIX   I—REPRESENTATIVE   SAMPLING
   METHODS
APPENDIX  II—EP  TOXICITY   TEST  PROCE-
   DURES
APPENDIX  III—CHEMICAL  ANALYSIS  TEST
   METHODS
APPENDIX IV—[RESERVED FOR  RADIOACTIVE
   WASTE TEST METHODS]
APPENDIX  V—[RESERVED FOR  INFECTIOUS
   WASTE TREATMENT SPECIFICATIONS]
APPENDIX  VI—[RESERVED  FOR ETIOLOGIC
   AGENTS]
APPENDIX VII—BASIS FOR LISTING HAZARD-
   OUS WASTE
APPENDIX VIII—HAZARDOUS CONSTITUENTS
APPENDIX  IX—WASTES  EXCLUDED  UNDER
   51 260.20 AND 260.22
APPENDIX  X—METHOD  OF  ANALYSIS  FOR
   CHORINATED DIBENZO-P-DIOXINS AND -Di-
   BENZOFURANS
  AUTHORITY: 42 U.S.C. 6905. 6912(a), 6921,
6922, and 6938.
  SOURCE: 45 FR 3311S, May 19, 1980, unless
otherwise noted.


         Subpart A—General

§ 261.1  Purpose and scope.
  (a)  This  part  identifies  those  solid
wastes which are subject to regulation
as hazardous wastes under Parts 262
through 265, 268, and  Parts 270, 271,
and 124 of this chapter and which are
subject  to  the   notification require-
ments of  section 3010  of RCRA.  In
this part:
  (1)  Subpart  A defines  the terms
"solid waste" and "hazardous waste",
identifies those  wastes  which are ex-
cluded  from regulation under  Parts
262 through 266,  268 and 270 and es-
tablishes special management require-
ments for hazardous waste produced
by conditionally exempt small quanti-
ty generators  and   hazardous waste
which is recycled.
  (2)  Subpart B  sets  forth the criteria
used  by EPA to identify characteris-
tics of hazardous waste and to list par-
ticular hazardous wastes.
  (3)  Subpart C  identifies characteris-
tics of hazardous waste.
  (4)  Subpart  D lists particular  haz-
ardous wastes.
  (b)(l) The definition  of solid waste
contained  in this  part applies only to
wastes that also  are hazardous for pur-
poses of the regulations implementing
Subtitle C of RCRA. For example,  it
does  not  apply  to materials (such as
non-hazardous  scrap, paper, textiles,
or rubber) that are not otherwise haz-
ardous wastes and that are recycled.
  (2)  This  part identifies only some of
the materials which are solid  wastes
and  hazardous  wastes  under sections
3007, 3013, and 7003 of RCRA. A mate-
rial which  is not defined as a solid
waste in this part, or is not a hazard-
ous waste identified  or listed in this
part,  is still a solid waste and a hazard-
ous waste for purposes of these sec-
tions  if:
  (i)  In the case of sections 3007 and
3013,  EPA has reason to believe  that

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Environmental Protection Agency
                              §261.2
the  material  may be  a solid waste
within the meaning of section 1004(27)
of  RCRA  and  a  hazardous waste
within the meaning of section 1004(5)
of RCRA; or
  (ii) In the case  of section 7003, the
statutory elements are established.
  (c) For the purposes of §§ 261.2 and
261.6:
  (DA "spent material"  is any materi-
al that  has  been used and  as a result
of contamination  can no longer serve
the purpose for which it was produced
without processing;
  (2) "Sludge"  has the same meaning
used in § 260.10 of this chapter;
  (3) A "by-product" is a material that
is not one of the primary products of a
production process and is not solely  or
separately produced by the production
process. Examples are process residues
such  as slags  or  distillation  column
bottoms. The term does  not include a
co-product that is produced for the
general public's use and is ordinarily
used in  the form it is produced by the
process.
  (4) A material is "reclaimed" if it is
processed to recover a usable product,
or if  it is regenerated. Examples are
recovery of lead values from spent bat-
teries and  regeneration  of  spent sol-
vents.
  (5) A material is "used or reused" if
it is either:
  (i) Employed  as an ingredient (in-
cluding  use  as an  intermediate) in an
industrial process  to make  a product
(for   example,  distillation  bottoms
from one process used as feedstock  in
another process). However,  a material
will not satisfy this condition if dis-
tinct components  of the material are
recovered as separate end products (as
when  metals  are  recovered  from
metal-containing secondary materials);
or
  (ii)  Employed in a particular  func-
tion or application as an effective sub-
stitute for a commercial product (for
example, spent  pickle liquor used  as
phosphorous precipitant and sludge
conditioner in wastewater treatment).
  (6) "Scrap metal"  is bits  and pieces
of metal parts  (e.g.,)  bars, turnings,
rods, sheets, wire)  or metal pieces that
may be combined  together  with bolts
or soldering (e.g., radiators, scrap auto-
mobiles,  railroad  box   cars),  which
when worn or superfluous can be recy-
cled.
  (7)  A material is  "recycled" if  it is
used, reused, or reclaimed.
  (8) A material is "accumulated spec-
ulatively" if it is accumulated before
being recycled. A material is not accu-
mulated speculatively, however, if the
person accumulating it can show  that
the material is potentially recyclable
and has a feasible means of being recy-
cled;  and that—during  the calendar
year (commencing on January 1)—the
amount of material that is recycled, or
transferred to a different site for recy-
cling, equals  at  least 75 percent by
weight  or volume of the amount of
that material accumulated at the be-
ginning of the period. In calculating
the percentage of turnover, the 75 per-
cent requirement is  to be  applied to
each material of the same type (e.g.,
slags  from a single  smelting process)
that is recycled in the same way  (i.e.,
from which the same material is recov-
ered or that is used  in the same way).
Materials accumulating  in  units that
would  be exempt   from  regulation
under § 261.4(c) are not be included in
making  the  calculation.  (Materials
that  are already   defined  as  solid
wastes also  are not  to be included in
making the calculation.) Materials are
no longer in this category once  they
are removed from accumulation for re-
cycling, however.

[45 FR 33119, May 19,  1980,  as amended at
48 FR 14293, Apr. 1, 1983; 50 FR 663, Jan. 4,
1985; 51 FR  10174,  Mar. 24, 1986; 51 FR
40636, Nov. 7,  1986]

§ 261.2  Definition of solid waste.
  (a)(l) A solid waste is any discarded
material  that  is  not  excluded  by
§ 261.4(a) or that is not  excluded by
variance granted under  §§ 260.30  and
260.31.
  (2) A discarded material is any mate-
rial which is:
  (i) Abandoned, as explained in para-
graph (b) of this section; or
  (ii) Recycled, as explained in para-
graph (c) of  this section; or
  (iii)  Considered  inherently  waste-
like, as explained  in paragraph (d) of
this section.
  (b) Materials are solid waste if they
are abandoned by being:

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§261.2
         40 CFR Ch. I (7-1-89 Edition)
  (1) Disposed of; or
  (2) Burned or incinerated; or
  (3) Accumulated, stored,  or treated
(but not recycled) before or in lieu of
being abandoned by being disposed of,
burned, or incinerated.
  (c) Materials are solid wastes if they
are recycled—or  accumulated, stored,
or treated before recycling—as speci-
fied in paragraphs (c)(l) through (4)
of this section.
  (1)  Used in a  manner constituting
disposal, (i) Materials noted with a "*"
in Column 1 of Table I are solid wastes
when they are:
  (A) Applied to or placed on the land
in a manner that constitutes disposal;
or
  (B) Used  to produce products that
are applied to or placed on the land or
are otherwise contained in products
that are applied to or placed on the
land (in which cases the product itself
remains a solid waste).
  (ii)  However, commercial chemical
products listed in § 261.33 are not solid
wastes if they are  applied to the land
and that is their  ordinary manner of
use.
  (2) Burning for  energy  recovery,  (i)
Materials noted with a "*" in column 2
of Table 1  are solid wastes when they
are:
  (A) Burned to recover energy;
  (B)  Used to produce  a fuel  or  are
otherwise contained in fuels (in which
cases  the  fuel  itself  remains  a solid
waste).
  (ii)  However, commercial chemical
products listed in § 261.33 are not solid
wastes if they are themselves fuels.
  (3) Reclaimed. Materials noted with
a "*" in column 3 of Table 1 are solid
wastes when reclaimed.
  (4) Accumulated speculatively. Mate-
rials noted with a  "*" in column  4 of
Table 1 are solid wastes when accumu-
lated speculatively.
                                   TABLE 1

Spent Materials 	 	
Sludges (listed in 40 CFR Part 261 31 or 261 32)
Sludges exhibiting a charactenstic ot hazardous waste
By-products (listed in 40 CFR Part 261 31 or 261 32)
By-products exhibiting a charactenstic of hazardous waste 	
Commercial chemical products listed in 40 CFR 261.33 	
Scrap metal..

Use
constituting
disposal
(§261.2(0(1))
d)
(*)
(")
(•)
(*)
(*)
(*)
(*)

Energy
recovery/fuel
(§261.2(c)(2))
(2)
(•
(•
(•
(•
(•
(•
(•

Reclamation
(§261.2(0(3))
(3)
(•)
(•)

(*)


(*)

Speculative
accumulation
(§261.2(c)(4))
(4)
(*)
(")
(*)
(*)
(*)

(*)

  Note: The terms "spent materials", "sludges", "by-products." and "scrap metal" are defined in §261.1.
  (d) Inherently  waste-like materials.
The  following  materials  are  solid
wastes when they are recycled in any
manner:
  (1) Hazardous Waste Nos. F020, F021
(unless used as an ingredient to make
a  product at the site of generation),
F022, F023, F026, and F028.
  (2) The Administrator will use the
following criteria to add wastes to that
list:
  (i)(A) The materials are ordinarily
disposed of, burned, or incinerated;  or
  (B) The materials contain toxic con-
stituents  listed in Appendix VIII  of
Part 261  and  these  constituents are
not ordinarily  found in raw materials
or  products for  which  the  materials
substitute (or are found in raw materi-
als  or  products in smaller concentra-
tions)  and  are not used  or reused
during the recycling process; and
  (ii) The material may pose a  sub-
stantial hazard to  human health and
the environment when recycled.
  (e) Materials  that are not solid waste
when recycled.  (1) Materials are not
solid wastes when  they can be shown
to be recycled by being:
  (i) Used or reused as ingredients  in
an industrial process to  make a prod-
uct,  provided  the  materials  are not
being reclaimed; or
  (ii) Used or reused as  effective  sub-
stitutes for commercial products; or

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Environmental Protection Agency
                              §261.3
  (iii) Returned to the original process
from which they are generated, with-
out first being reclaimed. The material
must be returned as a substitute for
raw  material feedstock, and the proc-
ess must use raw materials as principal
feedstocks.
  (2) The  following materials  are solid
wastes,  even if the recycling involves
use,  reuse, or return  to  the original
process  (described in paragraphs (e)(l)
(i) through (iii) of this section):
  (i) Materials used in a manner con-
stituting disposal, or used to produce
products that are applied to the land;
or
  (ii) Materials burned for  energy re-
covery,  used to produce a fuel, or con-
tained in fuels; or
  (iii) Materials accumulated specula-
tively; or
  (iv) Materials  listed in  paragraph
(d)(l) of this section.
  (f)  Documentation  of  claims  that
materials  are not solid wastes or are
conditionally exempt from regulation.
Respondents in actions to enforce reg-
ulations implementing Subtitle C of
RCRA who raise a claim that a certain
material is not a solid waste, or is con-
ditionally  exempt  from  regulation,
must demonstrate  that  there  is  a
known  market or disposition for the
material,  and  that  they  meet  the
terms of the exclusion or exemption.
In doing so, they must provide appro-
priate documentation (such  as  con-
tracts showing that a second person
uses the material as an ingredient in a
production  process)  to  demonstrate
that the material is not a waste, or  is
exempt  from  regulation.  In addition,
owners  or operators of facilities claim-
ing  that  they  actually are recycling
materials  must show  that  they  have
the necessary equipment to do so.

[50 FR 664, Jan. 4, 1985, as amended at 50
FR 33542, Aug. 20, 1985]

§ 261.3  Definition of hazardous waste.
  (a) A solid  waste,  as  defined  in
§ 261.2,  is a hazardous waste if:
  (1) It  is not excluded from regula-
tion  as  a  hazardous waste under
§ 261.4(b); and
  (2) It  meets any of the following cri-
teria:
  (i) It exhibits any of the characteris-
tics  of hazardous waste  identified  in
Subpart C.
  (ii) It is listed in Subpart D and has
not  been excluded from  the  lists  in
Subpart D under §§ 260.20 and 260.22
of this chapter.
  (iii) It  is a mixture of a solid waste
and a hazardous waste that is listed  in
Subpart  D solely because  it exhibits
one  or more of the characteristics  of
hazardous waste identified in Subpart
C, unless the resultant mixture  no
longer exhibits  any characteristic  of
hazardous waste identified in Subpart
C.
  (iv) It is a mixture of solid waste and
one or more hazardous wastes listed  in
Subpart D and has not been excluded
from this paragraph under §§ 260.20
and  260.22 of this chapter; however,
the following mixtures of solid wastes
and  hazardous wastes  listed in Sub-
part  D  are  not  hazardous  wastes
(except by  application of  paragraph
(a)(2) (i) or (ii) of this section) if the
generator can  demonstrate that the
mixture consists of wastewater the dis-
charge of which is subject to regula-
tion under either section 402 or sec-
tion 307(b) of the Clean Water Act (in-
cluding wastewater at facilities which
have   eliminated  the  discharge   of
wastewater) and:
  (A) One  or more of the  following
spent  solvents  listed   in  § 261.31—
carbon tetrachloride,  tetrachloroethy-
lene,      trichoroethylene—Provided,
That the maximum total weekly usage
of  these  solvents  (other  than  the
amounts  that can be demonstrated not
to be discharged to wastewater) divid-
ed  by the  average  weekly  flow  of
wastewater into the headworks of the
facility's  wastewater treatment or pre-
treatment system does not exceed  1
part per million; or
  (B) One  or more of the  following
spent solvents listed in § 261.31—meth-
ylene  chloride,  1,1,1-trichloroethane,
chlorobenzene, o-dichlorobenzene, cre-
sols, cresylic acid, nitrobenzene, tolu-
ene, methyl  ethyl  ketone, carbon di-
sulfide,  isobutanol,  pyridine,  spent
chlorofluorocarbon solvents—provided
that the  maximum total weekly usage
of  these  solvents  (other than  the
amounts  that can be demonstrated not
to be discharged to wastewater) divid-

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§261.3
         40 CFR Ch. I (7-149 Edition)
ed  by the  average weekly flow  of
wastewater into the headworks of the
facility's wastewater treatment or pre-
treatment system does not  exceed  25
parts per million; or
  (C) One  of  the following wastes
listed  in  § 261.32—heat  exchanger
bundle cleaning sludge from the petro-
leum refining industry (EPA Hazard-
ous Waste No. K050); or
  (D) A discarded commercial chemi-
cal product, or chemical intermediate
listed in § 261.33, arising from de mini-
mis  losses  of  these  materials  from
manufacturing  operations  in  which
these materials are used as raw mate-
rials or are produced in the manufac-
turing process. For purposes of  this
subparagraph, "de minimis" losses in-
clude those from normal material han-
dling operations (e.g.  spills from the
unloading  or  transfer   of  materials
from bins or other containers, leaks
from pipes,  valves or  other devices
used  to  transfer materials);  minor
leaks of  process equipment,  storage
tanks or containers; leaks from well-
maintained pump packings and seals;
sample  purgings;  relief  device  dis-
charges; discharges from safety show-
ers and rinsing and cleaning of person-
al safety equipment; and rinsate from
empty containers or from containers
that are rendered empty by that rins-
ing; or
  (E) Wastewater resulting from labo-
ratory operations containing toxic (T)
wastes listed in Subpart D, Provided,
That the  annualized average flow  of
laboratory wastewater does not exceed
one  percent  of total wastewater  flow
into the headworks of  the  facility's
wastewater  treatment  or  pre-treat-
ment system, or provided the wastes,
combined annualized average concen-
tration does  not exceed  one part per
million in the headworks of the facili-
ty's wastewater treatment or pre-treat-
ment facility. Toxic (T) wastes used in
laboratories  that  are  demonstrated
not to be discharged to wastewater are
not to be included in this calculation.
  (b) A solid waste which is not ex-
cluded from regulation  under para-
graph (a)(l) of this section becomes a
hazardous waste when any of the fol-
lowing events occur:
  (1) In the  case of a waste listed  in
Subpart D, when the waste first meets
the  listing description  set  forth in
Subpart D.
  (2) In the case of a mixture of solid
waste and one or more listed hazard-
ous wastes, when a hazardous waste
listed in Subpart D is first  added to
the solid waste.
  (3) In  the case of any other waste
(including a waste mixture), when the
waste exhibits any of the characteris-
tics identified in Subpart C.
  (c) Unless and until it meets the cri-
teria of paragraph (d):
  (DA hazardous waste will  remain a
hazardous waste.
  (2)(i) Except as otherwise  provided
in paragraph  (c)(2)(ii)  of this section,
any solid waste  generated  from  the
treatment, storage,  or disposal of  a
hazardous waste, including any sludge,
spill residue, ash,  emission control
dust, or leachate (but not including
precipitation  run-off)  is a hazardous
waste. (However,  materials that are re-
claimed from solid wastes and that are
used-beneficially are not solid wastes
and hence are not hazardous wastes
under  this  provision  unless  the re-
claimed material is burned for energy
recovery or used in  a  manner consti-
tuting disposal.)
  (ii) The  following solid wastes  are
not hazardous even  though  they are
generated from  the treatment, stor-
age, or disposal of a hazardous waste.
unless they exhibit one or more of the
characteristics of hazardous waste: (A)
Waste  pickle  liquor  sludge generated
by lime  stabilization of spent pickle
liquor from the iron and steel industry
(SIC Codes 331 and 332).
  (B) Waste from burning any of the
materials exempted  from  regulation
by § 261.6(a)(3) (v) through (ix).
  (d) Any solid  waste  described  in
paragraph (c) of  this section is  not a
hazardous waste if it meets the follow-
ing criteria:
  (1) In the case  of any solid waste, it
does not exhibit any of the character-
istics of hazardous waste identified in
Subpart C.
  (2) In the case of a waste which is a
listed waste under Subpart D, contains
a waste listed under Subpart D or is
derived from a waste listed in Subpart
D, it  also has  been  excluded  from
paragraph (c) under  {§260.20  and
260.22 of this chapter.

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Environmental Protection Agency
                              §261.4
[45 FR 33119, May 19, 1980. as amended at
46 FR  56588, Nov. 17. 1981; 50 FR 14219,
Apr. 11, 1985; 50 FR 49202. Nov. 29, 1985; 52
FR 11821, Apr. 13, 1987]

§ 261.4  Exclusions.
  (a)  Materials which are not solid
wastes. The  following materials  are
not solid wastes for the purpose of this
part:
  (l)(i) Domestic sewage; and
  (ii) Any mixture of domestic sewage
and other wastes that passes through
a  sewer  system  to a publicly-owned
treatment works for treatment. "Do-
mestic sewage" means untreated sani-
tary wastes that pass through a sewer
system.
  (2) Industrial wastewater discharges
that are point source discharges sub-
ject to regulation under section 402 of
the Clean Water Act, as amended.
[Comment' This exclusion applies only to
the actual point source discharge.  It does
not exclude industrial wastewaters while
they are being collected, stored or  treated
before discharge, nor does it exclude sludges
that are generated by industrial wastewater
treatment.]
  (3) Irrigation return flows.
  (4)  Source,  special  nuclear or  by-
product  material  as defined by the
Atomic Energy Act of 1954, as amend-
ed, 42 U.S.C. 2011 et seq.
  (5)  Materials subjected  to  in-situ
mining techniques which are not re-
moved from the ground as part of the
extraction process.
  (6) Pulping liquors (i.e., black liquor)
that are  reclaimed in a pulping liquor
recovery furnace and then reused  in
the pulping process, unless it is accu-
mulated  speculatively as defined  in
§ 261.l(c) of this chapter.
  (7)  Spent  sulfuric acid  used   to
produce  virgin sulfuric acid, unless it
is accumulated speculatively as  de-
fined in § 261.l(c) of this chapter.
  (8) Secondary materials that are re-
claimed and  returned to the original
process or processes  in  which they
were generated where they are reused
in the production process provided:
  (i) Only tank storage is involved, and
the entire process through completion
of reclamation is  closed by being  en-
tirely connected  with pipes or other
comparable enclosed means of convey-
ance;
  (ii) Reclamation  does not  involve
controlled flame combustion (such as
occurs in boilers, industrial furnaces,
or incinerators);
  (iii)  The secondary materials  are
never accumulated in such  tanks for
over twelve months without being re-
claimed; and
  (iv) The reclaimed  material  is not
used  to produce  a fuel, or used  to
produce products that are used  in a
manner constituting disposal.
  (b) Solid wastes which are not haz-
ardous  wastes. The  following  solid
wastes are not hazardous wastes:
  (1)   Household  waste,   including
household waste that has been collect-
ed, transported, stored,  treated, dis-
posed, recovered  (e.g., refuse-derived
fuel)  or  reused.  "Household  waste"
means  any material  (including  gar-
bage, trash  and  sanitary  wastes  in
septic tanks) derived from households
(including single  and multiple  resi-
dences,  hotels  and  motels,  bunk-
houses, ranger stations, crew quarters,
campgrounds, picnic grounds and day-
use recreation areas). A resource re-
covery  facility managing  municipal
solid waste shall not be  deemed  to be
treating, storing, disposing of,  or oth-
erwise managing hazardous wastes for
the purposes of regulation under this
subtitle, if such facility:
  (i) Receives and burns only
  (A) Household  waste  (from  single
and multiple dwellings, hotels, motels,
and other residential sources) and
  (B) Solid waste from commercial or
industrial sources that does not  con-
tain hazardous waste; and
  (ii) Such facility does not accept haz-
ardous wastes and the  owner or opera-
tor of  such facility   has  established
contractual requirements or other ap-
propriate   notification or  inspection
procedures to  assure  that  hazardous
wastes are not received at or burned in
such facility.
  (2) Solid wastes generated by any of
the following  and which are returned
to the soils as fertilizers:
  (i) The  growing  and harvesting of
agricultural crops.
  (ii) The  raising of animals, including
animal manures.
  (3) Mining overburden returned  to
the mine site.

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§261.4
         40 CFR Ch. I (7-1-89 Edition)
  (4) Fly ash waste, bottom ash waste,
slag waste, and flue gas emission con-
trol waste generated primarily from
the combustion of coal or other fossil
fuels.
  (5) Drilling fluids, produced waters,
and other wastes associated with the
exploration, development, or  produc-
tion  of  crude oil, natural gas or geo-
thermal energy.
  (6)(i) Wastes which fail the  test for
the characteristic of EP toxicity  be-
cause chromium  is  present  or are
listed in Subpart D due to the pres-
ence of chromium, which do  not fail
the test for the  characteristic of  EP
toxicity for any other constituent or
are not listed due to the presence of
any other constituent, and  which do
not fail the text for any other charac-
teristic, if it is shown by a waste gener-
ator or by waste generators that:
  (A)  The chromium in  the waste is
exclusively (or nearly exclusively) tri-
valent chromium; and
  (B)  The waste is generated from an
industrial process which uses trivalent
chromium exlcusively (or nearly exclu-
sively) and the process does not gener-
ate hexavalent chromium; and
  (C)  The waste  is typically and fre-
quently managed in non-oxidizing en-
vironments.
  (ii)  Specific wastes  which meet the
standard  in  paragraphs  (b)(6)(i)(A),
(B) and (C) (so long as they do not fail
the test for the charactristic of  EP
toxicity, and do not fail the  test for
any other characteristic) are:
  (A)  Chrome (blue) trimmings gener-
ated by the following subcategories of
the leather  tanning and finishing in-
dustry;  hair pulp/chrome tan/retan/
wet  finish; hair  save/chrome tan/
retan/wet finish; retan/wet  finish; no
beamhouse;   through-the-blue;   and
shearling.
  (B)  Chrome (blue) shavings generat-
ed by the following subcategories of
the leather  tanning and finishing in-
dustry:  Hair pulp/chrome tan/retan/
wet  finish; hair  save/chrome tan/
retan/wet finish; retan/wet  finish; no
beamhouse;  through-the-blue;   and
shearling.
  (C)  Buffing  dust generated by the
following subcategories of the leather
tanning  and finishing industry; hair
pulp/chrome  tan/retan/wet   finish;
hair    save/chrome    tan/retan/wet
finish;  retan/wet  finish;  no  beam-
house; through-the-blue.
  (D) Sewer screenings  generated  by
the  following subcategories of  the
leather tanning  and finishing  indus-
try:  Hair  pulp/crome  tan/retan/wet
finish;  hair  save/chrome tan/retan/
wet finish; retan/wet finish; no  beam-
house;  through-the-blue; and  shear-
ling.
  (E) Wastewater  treatment sludges
generated by the following subcategor-
ies of the leather tanning and finish-
ing industry:  Hair pulp/chrome tan/
retan/wet  finish;  hair  save/chrome
tan/retan/wet   finish;    retan/wet
finish;  no  beamhouse;  through-the-
blue; and shearling.
  (F)  Wastewater  treatment  sludes
generated by the  following subcategor-
ies of the leather tanning and finish-
ing industry:  Hair pulp/chrome tan/
retan/wet  finish; hair  save/chrome-
tan/retan/wet finish; and  through-
the-blue.
  (G) Waste scrap leather  from the
leather  tanning  industry,  the shoe
manufacturing industry, and  other
leather  product manufacturing indus-
tries.
  (H) Wastewater  treatment sludges
from the production of TiO2 pigment
using chromium-bearing ores by the
chloride process.
  (7) Solid waste  from the extraction,
beneficiation  and  procesing of  ores
and minerals  (including  coal), includ-
ing phosphate rock and overburden
from the mining  of uranium ore. For
the purposes of this paragraph, solid
waste from the processing of ores and
minerals does not include:
  (i)  Acid  plant blowdown  slurry/
sludge  resulting from  the thickening
of blowdown  slurry  from  primary
copper production;
  (ii) Surface impoundment solids con-
tained in the dredged from surface im-
poundments at primary lead smelting
facilities;
  (iii) Sludge from treatment of proc-
ess wastewater and/or acid plant blow-
down from primary zinc production;
  (iv) Spent  potliners from primary
aluminum reduction;
  (v) Emission control dust  or sludge
from  ferrochromiumsilicon  produc-
tion;

-------
Environmental Protection Agency
                             §261.4
  (vi) Emission control dust or sludge
from ferrochromium production.
  (8) Cement kiln dust waste.
  (9) Solid waste which consists of dis-
carded wood or wood products which
fails the test for  the characteristic of
EP toxicity and which is not a hazard-
ous waste for  any other reason if the
waste is generated by persons who uti-
lize  the arsenical-treated  wood  and
wood products for these materials' in-
tended end use.
  (c) Hazardous wastes which are ex-
empted from  certain  regulations.  A
hazardous waste which is generated in
a  product  or  raw  material  storage
tank, a product or raw material trans-
port vehicle  or vessel, a product or raw
material pipeline, or in a manufactur-
ing process unit or an associated  non-
waste-treatment-manufacturing   unit,
is not  subject  to  regulation under
Parts 262 through 265, 268,  270, 271
and  124 of this chapter or to the  noti-
fication requirements of section  3010
of RCRA until it exits the  unit  in
which it  was  generated, unless the
unit  is a surface impoundment,  or
unless the hazardous waste remains in
the unit more than 90 days after the
unit ceases  to be  operated for manu-
facturing, or for storage or transporta-
tion of product or raw materials.
  (d) Samples.  (1) Except as provided
in paragraph  (d)(2) of this section, a
sample of solid waste or a sample  of
water, soil,  or air, which is collected
for the sole purpose of testing to de-
termine its characteristics or composi-
tion,  is not subject to  any  require-
ments  of  this  part  or  Parts  262
through 268 or Part 270 or Part 124 of
this chapter or to the notification re-
quirements  of section 3010 of RCRA,
when:
  (i) The sample  is being transported
to a laboratory for the purpose of test-
ing; or
  (ii) The sample is being transported
back to the sample collector after test-
ing; or
  (iii) The sample  is being stored by
the sample  collector before transport
to a laboratory for testing; or
  (iv) The sample is being stored in a
laboratory before testing; or
  (v) The sample is being stored in a
laboratory after testing but before it is
returned to the sample collector; or
  (vi) The sample is being stored tem-
porarily in the laboratory after testing
for a specific purpose  (for  example,
until conclusion of  a court case or en-
forcement action where further  test-
ing of the sample may be necessary).
  (2) In  order to qualify for the ex-
emption  in  paragraphs (d)(l) (i) and
(ii) of this section,  a sample collector
shipping samples to a laboratory and a
laboratory   returning  samples  to  a
sample collector must:
  (i)  Comply with U.S. Department of
Transportation  (DOT),  U.S.  Postal
Service (USPS),  or  any other applica-
ble shipping requirements; or
  (ii)  Comply  with the  following re-
quirements if the sample collector de-
termines that DOT, USPS,  or other
shipping requirements do not apply to
the shipment of  the sample:
  (A) Assure that the following infor-
mation accompanies the sample:
  (1)  The  sample  collector's name,
mailing   address,   and  telephone
number;
  (2) The laboratory's name, mailing
address, and telephone number;
  (3) The quantity of the sample;
  (4) The date of shipment; and
  (5) A description of the sample.
  (B) Package the  sample so that it
does not leak, spill, or  vaporize from
its packaging.
  (3) This exemption does not apply if
the  laboratory  determines that the
waste is hazardous but the laboratory
is no longer meeting any of the condi-
tions stated  in paragraph (d)(l) of this
section.
  (e) Treatability Study Samples. (1)
Except as provided in paragraph (e)(2)
of this section,  persons who generate
or collect samples for  the  purpose of
conducting treatability  studies as de-
fined in section 260.10, are not subject
to  any  requirement  of  Parts   261
through  263 of this chapter or to the
notification  requirements  of Section
3010 of RCRA,  nor are  such samples
included in the quantity  determina-
tions of § 261.5 and § 262.34(d) when:
  (i) The sample is being collected and
prepared  for  transportation by  the
generator or sample collector; or
  (ii) The sample is being accumulated
or stored by the generator or sample
collector prior to transportation to  a
laboratory or testing facility; or

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§261.4

  (iii) The sample is being transported
to the laboratory or testing facility for
the purpose of conducting a treatabil-
ity study.
  (2)  The  exemption  in  paragraph
(e)(l) of this  section is  applicable to
samples of hazardous waste being col-
lected and shipped for the purpose of
conducting treatability studies provid-
ed that:
  (i) The generator or sample collector
uses (in "treatability studies") no more
than 1000 kg of any non-acute hazard-
ous waste, 1  kg of acute hazardous
waste, or 250  kg  of soils,  water,  or
debris contaminated with  acute  haz-
ardous waste  for each process being
evaluated for  each  generated waste
stream; and
  (ii)  The mass of each sample ship-
ment  does not  exceed 1000 kg of  non-
acute hazardous waste, 1 kg of acute
hazardous  waste, or 250 kg of soils,
water, or  debris contaminated  with
acute hazardous waste; and
  (iii) The sample must be packaged so
that it will not leak, spill, or vaporize
from  its packaging  during shipment
and the requirements of paragraph A
or B of this subparagraph are met.
  (A)   The  transportation   of   each
sample  shipment complies with  U.S.
Department of Transportation (DOT),
U.S.  Postal Service (USPS),  or  any
other  applicable  shipping  require-
ments; or
  (B)  If the  DOT,  USPS, or other
shipping requirements do not apply to
the shipment  of the sample, the fol-
lowing  information  must accompany
the sample:
  (1)  The name, mailing address, and
telephone number of the originator of
the sample;
  (2)  The  name,  address,  and  tele-
phone number of the facility that will
perform the treatability study;
  (3) The quantity of the sample;
  (4) The date of shipment; and
  (5)  A description  of the sample, in-
cluding  its EPA  Hazardous  Waste
Number.
  (iv) The sample is shipped to a labo-
ratory  or  testing  facility  which  is
exempt under  § 261.4(f) or has an ap-
propriate  RCRA  permit or  interim
status.
  (v)  The generator or sample collec-
tor maintains the following records for
         40 CFR Ch. I (7-1-89 Edition)

a period ending 3 years after comple-
tion of the treatability study:
  (A)  Copies  of the shipping  docu-
ments;
  (B)  A copy of the contract with the
facility   conducting  the  treatability
study;
  (C)  Documentation showing:
  (1)  The  amount of waste shipped
under this exemption;
  (2)  The  name, address,  and  EPA
identification number of the laborato-
ry or  testing facility that received the
waste;
  (3) The date the shipment was made;
and
  (4)  Whether  or not unused samples
and residues were returned to the gen-
erator.
  (vi)  The generator reports the infor-
mation   required  under  paragraph
(eXvXC) of  this section in its biennial
report.
  (3)  The Regional  Administrator, or
State Director (if located in an author-
ized State),  may grant requests,  on a
case-by-case basis, for quantity limits
in excess of those specified in  para-
graph (e)(2)(i) of this section, for up to
an additional 500 kg of non-acute haz-
ardous waste, 1 kg of acute  hazardous
waste, and  250  kg  of soils, water, or
debris contaminated  with acute  haz-
ardous waste, to conduct further treat-
ability study evaluation  when: There
has been an equipment or mechanical
failure during the conduct of a treat-
ability study; there is a need to verify
the results  of a previously conducted
treatability  study; there  is  a need to
study and  analyze  alternative  tech-
niques within a  previously  evaluated
treatment process; or there is a  need
to do  further evaluation of an ongoing
treatability  study to determine  final
specifications for treatment. The addi-
tional quantities allowed are subject to
all the provisions in paragraphs (eXl)
and 
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Environmental Protection Agency
                              §261.4
  (ii)  Documentation  accounting for
all  samples of hazardous waste  from
the waste stream  which  have  been
sent  for  or  undergone treatability
studies including the data each previ-
ous sample from the waste stream was
shipped, the quantity of each previous
shipment, the laboratory or testing fa-
cility  to  which it was  shipped,  what
treatability study processes were con-
ducted on each sample shipped, and
the available results of  each treatabil-
ity study;
  (iii) A  description of  the technical
modifications  or  change in specifica-
tions  which will be evaluated and the
expected results;
  (iv)  If such further study is being re-
quired due to equipment or mechani-
cal  failure, the applicant must include
information regarding the reason for
the failure or breakdown and also in-
clude  what procedures or  equipment
improvements have been made  to pro-
tect against further breakdowns; and
  (v) Such other information that the
Regional Administrator considers nec-
essary.
  (f) Samples  Undergoing Treatability
Studies at Laboratories and  Testing
Facilities. Samples undergoing treat-
ability studies and the  laboratory  or
testing facility conducting such treat-
ability studies (to the extent such fa-
cilities are not otherwise  subject  to
RCRA requirements) are not subject
to any requirement of this Part, Part
124, Parts 262-266, 268, and 270, or to
the notification requirements of Sec-
tion 3010  of RCRA provided that the
conditions   of  paragraphs  (f)  (1)
through (11) of this section are met. A
mobile treatment  unit (MTU)  may
qualify as a testing facility  subject to
paragraphs (f) (1) through (11) of this
section. Where a group of MTUs are
located at the same  site, the  limita-
tions  specified in (f) (1) through (11)
of this section apply  to  the entire
group of MTUs collectively as if the
group were one MTU.
  (1) No less than 45  days before con-
ducting treatability studies,  the facili-
ty notifies the Regional Administra-
tor, or State Director (if located in an
authorized State), in writing that it in-
tends  to  conduct  treatability  studies
under this paragraph.
  (2) The laboratory or testing facility
conducting the treatability study has
an EPA identification number.
  (3) No more than a total of 250 kg of
"as received" hazardous waste is sub-
jected to initiation of treatment in all
treatability studies in any single day.
"As received" waste refers to the waste
as received in the shipment from the
generator or sample collector.
  (4)  The quantity of "as received"
hazardous waste stored at  the  facility
for the purpose of evaluation in treat-
ability studies does not exceed 1000 kg,
the total of which can include 500 kg
of soils, water, or debris contaminated
with acute hazardous waste or  1 kg of
acute hazardous waste. This quantity
limitation does not include:
  (i) Treatability study residues; and
  (ii)  Treatment  materials  (including
nonhazardous solid waste) added  to
"as received" hazardous waste.
  (5)  No  more  than 90  days have
elapsed since the treatability study for
the-sample was completed,  or no more
than  one year has elapsed since  the
generator or  sample collector shipped
the sample to the laboratory or testing
facility, whichever date first occurs.
  (6) The treatability study does  not
involve the  placement of  hazardous
waste on the land or  open burning of
hazardous waste.
  (7)  The facility  maintains records
for 3  years  following completion  of
each study that show compliance with
the treatment rate limits and the stor-
age time and quantity limits. The fol-
lowing specific information must be in-
cluded for each treatability study con-
ducted:
  (i)  The name,  address,  and EPA
identification number of the generator
or sample collector  of each  waste
sample;
  (ii) The date the shipment was re-
ceived;
  (iii) The quantity of waste accepted;
  (iv) The quantity of "as received"
waste in storage each day;
  (v)  The date  the treatment study
was initiated and  the amount of "as
received"  waste introduced  to treat-
ment each day;
  (vi) The date the treatability study
was concluded;
  (vii) The date any unused sample or
residues generated from the treatabil-

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§261.5
         40 CFR Ch. I (7-1-89 Edition)
ity study were returned to the genera-
tor or sample collector or, if sent to a
designated facility, the name of the fa-
cility  and  the  EPA  identification
number.
  (8) The facility keeps, on-site, a copy
of the treatability study contract and
all shipping papers associated with the
transport of treatability study samples
to and  from the facility  for  a period
ending  3  years  from  the completion
date of each treatability study.
  (9) The facility prepares and submits
a report to the Regional Administra-
tor, or State Director (if located in an
authorized  State),  by March  15  of
each year that estimates the number
of studies and the amount of waste ex-
pected to  be used in treatability  stud-
ies during the current year, and  in-
cludes the following information for
the previous calendar year:
  (i)  The  name,  address,  and  EPA
identification number of the facility
conducting the treatability studies;
  (ii) The types (by process) of treat-
ability studies conducted;
  (iii) The names and addresses of per-
sons for whom studies have been con-
ducted (including their EPA identifica-
tion  numbers);
  (iv) The total quantity of waste in
storage each day;
  (v) The  quantity and types of waste
subjected to treatability studies;
  (vi) When each  treatability  study
was conducted;
  (vii) The final disposition of residues
and  unused sample from  each  treat-
ability study.
  (10) The facility determines whether
any  unused sample or residues gener-
ated by the treatability study are haz-
ardous  waste under § 261.3 and, if  so,
are subject  to Parts 261 through 268,
and  Part  270 of this Chapter, unless
the  residues and unused samples are
returned  to the   sample  originator
under the § 261.4(e) exemption.
  (11) The facility notifies the Region-
al Administrator, or State Director (if
located in an  authorized State),  by
letter when  the facility is no longer
planning  to  conduct any  treatability
studies at the site.

(Approved  by the Office of  Management
and  Budget under control number  2050-
0088)
 [45 PR 33119. May 19. 1980]
  EDITORIAL NOTE: For FEDERAL REGISTER ci-
tations affecting § 261.4, see the List of CFR
Sections Affected in the Finding Aids sec-
tion of this volume.

§ 261.5 Special requirements for hazard-
   ous waste  generated  by  conditionally
   exempt small quantity generators.

  (a)  A  generator  is  a conditionally
exempt small quantity generator in a
calendar  month if  he generates no
more than 100 kilograms of hazardous
waste in that month.
  (b)  Except for those wastes identi-
fied in paragraphs (e),  (f), (g), and (j)
of this section, a conditionally exempt
small quantity generator's hazardous
wastes are  not  subject to regulation
under Parts 262 through 266, 268, and
Parts 270 and 124 of this chapter, and
the notification requirements of sec-
tion 3010 of RCRA,  provided the gen-
erator complies with the requirements
of paragraphs (f), (g),  and (j) of this
section.
  (c) Hazardous waste  that is not sub-
ject  to regulation or  that is subject
only to  § 262.11. § 262.12, § 262.40(c),
and  § 262.41  is not included in the
quantity determinations of  this  part
and Parts 262 through 266, 268, and
270 and is not subject to any of the re-
quirements  of those parts. Hazardous
waste that  is subject  to  the require-
ments of  § 261.6 (b) and (c)  and Sub-
parts  C, D, and F of Part 266 is includ-
ed in  the quantity  determination of
this part and is subject to the require-
ments of Parts  262  through 266 and
270.
  (d)  In  determining the quantity of
hazardous waste generated,  a genera-
tor need not include:
  (1) Hazardous waste  when it is re-
moved from on-site storage; or
  (2) Hazardous waste produced by on-
site treatment (including reclamation)
of his hazardous waste, so long as the
hazardous waste that  is  treated was
counted once; or
  (3) Spent materials that are generat-
ed, reclaimed, and subsequently reused
on-site, so long as such spent materials
have been counted once.
  (e)  If a generator  generates  acute
hazardous waste in a calendar month
in quantities  greater  than  set forth

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Environmental Protection Agency
                              §261.5
below, all quantities of that acute haz-
ardous waste are subject to full regula-
tion under Parts 262 through 266, 268,
and Parts 270 and 124 of this chapter,
and the notification requirements  of
section 3010 of RCRA:
  (DA total of  one kilogram of  acute
hazardous wastes listed in  §§ 261.31,
261.32, or 261.33(e).
  (2) A total of 100 kilograms of any
residue or contaminated soil, waste,  or
other debris  resulting from the clean-
up  of  a spill, into  or on any land  or
water, of any acute hazardous wastes
listed in §§ 261.31, 261.32, or 261.33(e).
  [Comment: "Full regulation" means those
regulations  applicable  to  generators  of
greater than 1,000 kg of non-acutely hazard-
ous waste in a calendar month.]
  (f)  In order  for acute  hazardous
wastes  generated  by a  generator  of
acute hazardous wastes in quantities
equal to or less than those set forth  in
paragraph (e)(l) or (2) of this section
to  be  excluded from fu 1  regulation
under this section, the generator must
comply  with the  following  require-
ments:
  (1) Section 262.11 of this chapter;
  (2) The  generator  may  accumulate
acute hazardous waste on-site.   If he
accumulates at any time acute hazard-
ous wastes in quantities greater than
those set forth  in paragraph  (e)(l)  or
(e)(2) of this section, all of those accu-
mulated wastes  are  subject to regula-
tion under Parts 262 through  266, 268,
and Parts 270 and 124 of this chapter,
and the applicable  notification re-
quirements of section 3010 of RCRA.
The time period of  § 262.34(a) of this
chapter, for accumulation of wastes
on-site, begins when the accumulated
wastes exceed the applicable exclusion
limit;
  (3)  A  conditionally  exempt   small
quantity generator may either treat  or
dispose of his acute  hazardous waste
in an on-site facility or ensure delivery
to an off-site treatment, storage or dis-
posal facility, either of which, if  locat-
ed in the U.S., is:
  (i) Permitted under Part 270 of this
chapter;
  (ii) In interim  status under Parts 270
and 265 of this chapter;
  (iii) Authorized  to manage hazard-
ous waste by a State with a hazardous
waste management program approved
under Part 271 of this chapter;
  (iv) Permitted, licensed, or registered
by a State to manage municipal or in-
dustrial solid waste; or
  (v) A facility which:
  (A) Beneficially uses or reuses, or le-
gitimately  recycles  or  reclaims  its
waste; or
  (B) Treats its waste prior to benefi-
cial  use  or reuse, or legitimate  recy-
cling or reclamation.
  (g) In order for hazardous waste gen-
erated by a conditionally exempt small
quantity generator in quantities of less
than 100 kilograms of hazardous waste
during  a calendar  month to  be ex-
cluded from full regulation under this
section,  the generator  must  comply
with the following requirements:
  (1) Section 262.11  of this chapter;
  (2)  The conditionally  exempt small
quantity  generator  may  accumulate
hazardous waste on-site. If he accumu-
lates at any time more than a total of
1000  kilograms  of   his hazardous
wastes,   all  of  those   accumulated
wastes are subject to regulation under
the special provisions of Part  262 ap-
plicable to generators of between 100
kg and 1000 kg of hazardous waste in a
calendar month as well as the require-
ments of Parts  263 through 266, 268,
and Parts 270 and 124 of this chapter,
and  the  applicable  notification re-
quirements of section 3010 of  RCRA.
The  time period of § 262.34(d) for ac-
cumulation of wastes on-site begins for
a conditionally exempt  small quantity
generator   when   the   accumulated
wastes exceed 1000 kilograms;
  (3)  A  conditionally  exempt small
quantity generator may either treat or
dispose  of his hazardous waste in  an
on-site facility or ensure delivery to an
off-site treatment, storage or disposal
facility, either of which, if located in
the U.S., is:
  (i)  Permitted under Part 270 of this
chapter;
  (ii) In interim status under Parts 270
and 265 of this chapter;
  (iii) Authorized to  manage hazard-
ous waste by a State with a hazardous
waste management  program  approved
under Part 271 of this chapter;
  (iv) Permitted, licensed, or registered
by a State to manage municipal or in-
dustrial solid waste; or
  (v) A facility which:

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§261.6
         40 CFR Ch. I (7-1-89 Edition)
  (A) Beneficially uses or reuses, or le-
gitimately  recycles  or  reclaims  its
waste; or
  (B) Treats its waste prior to benefi-
cial  use or reuse, or legitimate  recy-
cling or reclamation.
  (h) Hazardous waste subject to the
reduced requirements of this  section
may be mixed  with non-hazardous
waste and remain subject to these re-
duced requirements even though the
resultant mixture exceeds the  quanti-
ty limitations identified in this section,
unless  the mixture meets any of the
characteristics  of  hazardous  waste
identified in Subpart C.
  (i) If any person mixes a solid waste
with a hazardous waste that exceeds a
quantity exclusion level of this  sec-
tion, the mixture is subject to full reg-
ulation.
  (j) If a conditionally exempt small
quantity generator's wastes  are mixed
with used oil, the mixture is subject to
Subpart E of Part 266 of this chapter
if it is  destined to  be burned for
energy  recovery.  Any  material  pro-
duced from such a mixture by process-
ing,  blending,  or  other  treatment is
also  so regulated  if it is destined to be
burned for energy recovery.
[51 FR 10174. Mar.  24, 1986, as  amended at
51 FR 28682. Aug. 8, 1986; 51 FR 40637, Nov.
7, 1986; 53 FR 27163, July 19, 1988]

§ 261.6  Requirements for recyclable mate-
   rials.
  (a)(l)  Hazardous wastes that are re-
cycled are subject to the requirements
for generators,  transporters, and stor-
age facilities of paragraphs (b)  and (c)
of this section,  except for the materi-
als listed in paragraphs (a)(2)  and
(a)(3)  of  this  section.  Hazardous
wastes that are recycled will be known
as "recyclable materials."
  (2) The following recyclable materi-
als are not subject to the requirements
of this section but are regulated under
Subparts C through G of Part 266 of
this  chapter and  all  applicable provi-
sions in Parts 270  and 124 of this chap-
ter:
  (i)  Recyclable materials used  in a
manner constituting disposal (Subpart
C);
  (ii) Hazardous  wastes  burned  for
energy recovery in boilers and indus-
trial furnaces that are not regulated
under Subpart O of Part 264 or 265 of
this chapter (Subpart D);
  (iii) Used oil that exhibits  one or
more of the characteristics of hazard-
ous waste and is burned for energy re-
covery  in  boilers and  industrial  fur-
naces that are not  regulated under
Subpart O of Part 264 or 265 of  this
chapter (Subpart E);
  (iv) Recyclable materials from which
precious metals  are  reclaimed (Sub-
part F);
  (v) Spent lead-acid batteries that are
being reclaimed (Subpart G).
  (3) The following recyclable materi-
als are not subject to regulation under
Parts 262 through  Parts 266 or Parts
268, 270 or 124 of this chapter, and are
not subject to the notification require-
ments of section 3010 of RCRA:
  (i) Industrial ethyl alcohol that is re-
claimed  except that, unless provided
otherwise  in  an  international agree-
ment as specified in § 262.58:
  (A) A person initiating a shipment
for reclamation in  a foreign country,
and  any  intermediary  arranging  for
the shipment, must comply with  the
requirements applicable to a  primary
exporter in §§ 262.53, 262.56 (a)(l)-(4),
(6), and (b), and 262.57, export such
materials only upon consent of the re-
ceiving  country and  in conformance
with  the  EPA  Acknowledgment of
Consent as defined in  Subpart E of
Part 262, and provide a copy of  the
EPA Acknowledgment of  Consent to
the shipment to the transporter trans-
porting  the shipment for export;
  (B)  Transporters  transporting  a
shipment for export may not accept a
shipment if he knows  the shipment
does not conform to the EPA Acknowl-
edgment of Consent, must ensure that
a copy of the EPA Acknowledgment of
Consent accompanies  the shipment
and must ensure that it is delivered to
the facility designated by  the person
initiating the shipment.
  (ii)  Used batteries (or used battery
cells) returned to a battery manufac-
turer for regeneration;
  (iii) Used oil that  exhibits one or
more of the characteristics of hazard-
ous waste but is recycled in some other
manner than being  burned for energy
recovery;
  (iv) Scrap metal;

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Environmental Protection Agency
                              §261.7
  (v) Fuels produced from the refining
of oil-bearing hazardous wastes along
with normal process  streams at a pe-
troleum refining facility if such wastes
result  from  normal  petroleum refin-
ing,  production,  and  transportation
practices;
  (vi)  Oil  reclaimed  from  hazardous
waste  resulting from normal petrole-
um refining, production, and transpor-
tation  practices, which  oil is to be re-
fined  along   with   normal   process
streams at a petroleum refining facili-
ty;
  (vii)  Coke and coal tar from the  iron
and steel industry that contains EPA
Hazardous Waste  No. K087 (Decanter
tank  tar sludge  from  coking oper-
ations) from the iron and steel produc-
tion process;
  (viiiXA) Hazardous waste  fuel  pro-
duced   from   oil-bearing   hazardous
wastes from petroleum refining,  pro-
duction, or transportation practices, or
produced from oil  reclaimed from such
hazardous wastes, where such hazard-
ous wastes are reintroduced  into a
process that does not use distillation
or does  not  produce products from
crude oil so long as the resulting  fuel
meets  the used oil specification under
§ 266.40(e) of this  chapter and so long
as no other hazardous wastes are used
to produce the hazardous waste fuel;
  (B) Hazardous waste  fuel  produced
from oil-bearing hazardous waste from
petroleum  refining   production,  and
transportation practices,  where  such
hazardous   wastes are  reintroduced
into a  refining process after a point at
which  contaminants  are  removed, so
long as the fuel meets the used oil fuel
specification under § 266.40(e) of  this
chapter; and
  (C)  Oil reclaimed  from oil-bearing
hazardous wastes  from petroleum re-
fining,  production, and  transportation
practices,  which   reclaimed  oil   is
burned as  a fuel  without reintroduc-
tion to a refining process, so long as
the reclaimed  oil  meets the  used oil
fuel specification  under § 266.40(e) of
this chapter; and
  (ix) Petroleum coke produced from
petroleum  refinery hazardous wastes
containing oil  at the same  facility at
which  such  wastes  were generated,
unless  the resulting coke product  ex-
ceeds one or more of the characteris-
tics  of  hazardous waste  in Part  261,
Subpart C.
  (b) Generators and transporters  of
recyclable materials are subject to the
applicable  requirements of Parts 262
and  263 of this chapter and the notifi-
cation  requirements  under   section
3010 of RCRA, except as provided  in
paragraph (a) of this section.
  (c)(l) Owners or  operators of facili-
ties  that store  recyclable materials
before they are recycled are regulated
under all applicable provisions  of Sub-
parts A through L of Parts 264  and
265,  and under Parts 124,  266, 268, and
270 of this  Chapter and  the notifica-
tion  requirements under  section 3010
of RCRA, except as provided in para-
graph  (a) of  this section. (The recy-
cling process itself is exempt from reg-
ulation.)
  (2) Owners or operators of facilities
that recycle recyclable materials with-
out storing  them before they are rcy-
cled  are subject  to the following re-
quirements,  except  as   provided   in
paragraph (a) of this section:
  (i)  Notification requirements under
section 3010 of RCRA;
  (ii) Sections 265.71 and  265.72 (deal-
ing with the use of the  manifest and
manifest discrepancies) of this chap-
ter.

[50 FR 49203, Nov. 29, 1985, as amended  at
51 FR 28682, Aug. 8, 1986; 51 FR 40637, Nov.
7, 1986; 52 FR 11821, Apr. 13, 1987]

§ 261.7  Residues  of  hazardous waste  in
   empty containers.

  (a)(l) Any hazardous waste  remain-
ing in either (i) an empty container  or
(ii) an inner  liner  removed from  an
empty container, as defined in para-
graph (b) of this section, is not  subject
to regulation under Parts 261 through
265,  or Part 268, 270 or  124  of this
chapter or to the notification require-
ments of section 3010 of RCRA.
  (2) Any hazardous waste in either (i)
a container that is not empty or (ii) an
inner liner removed from  a container
that is not empty, as defined in para-
graph (b)  of this section,  is subject  to
regulation  under Parts  261 through
265,  and Parts 268,  270 and 124 of this
chapter and  to  the notification  re-
quirements of section 3010 of RCRA.

-------
§261.10
         40 CFR Ch. I (7-1-89 Edition)
  (b)(l) A container or an inner liner
removed from a container  that has
held any hazardous  waste,  except a
waste that is a compressed gas or that
is identified as  an acute  hazardous
waste  listed in  §§ 261.31,  261.32, or
261.33(e) of this chapter is empty if:
  (i) All wastes  have  been removed
that can be  removed using  the  prac-
tices commonly employed to  remove
materials from that type of container,
e.g., pouring, pumping, and aspirating,
and
  (ii)  No  more  than 2.5 centimeters
(one inch) of residue remain  on the
bottom of the container or inner  liner,
or
  (iiiXA) No more  than 3  percent by
weight  of the total  capacity  of the
container remains in  the container or
inner liner if the container is less than
or equal to 110 gallons in size, or
  (B)  No more  than  0.3 percent by
weight  of the total  capacity  of the
container remains in  the container or
inner liner if the container is  greater
than 110 gallons in size.
  (2) A container that has held a haz-
ardous waste that is a compressed gas
is empty when the pressure in the con-
tainer approaches atmospheric.
  (3) A container or an inner liner re-
moved from a container that has held
an  acute hazardous  waste  listed in
§§ 261.31, 261.32. or 261.33(e) is empty
if:
  (i) The container or inner liner has
been triple rinsed using a solvent  capa-
ble of removing the commercial chemi-
cal product  or manufacturing chemi-
cal intermediate;
  (ii) The container or inner liner has
been cleaned by another method that
has been shown in the scientific litera-
ture, or by tests conducted by the gen-
erator, to achieve equivalent removal;
or
  (iii) In the case of  a container, the
inner liner that prevented contact of
the commercial chemical  product or
manufacturing chemical intermediate
with the container, has been removed.
[45 PR 78529, Nov. 25, 1980, as amended at
47 FR 36097, Aug. 18, 1982; 48 PR  14294,
Apr. 1,  1983; 50 FR 1999, Jan.  14,  1985; 51
FR 40637, Nov. 7, 1986]
Subpart  B—Criteria  for  Identifying
     the  Characteristics of Hazardous
     Waste and for Listing Hazardous
     Waste

§261.10  Criteria for identifying the char-
    acteristics of hazardous waste.
  (a) The Administrator shall identify
and define a characteristic of hazard-
ous waste in Subpart C only upon de-
termining that:
  (1) A solid waste that  exhibits the
characteristic may:
  (i) Cause, or significantly contribute
to,  an  increase in mortality  or  an in-
crease  in serious irreversible, or inca-
pacitating reversible, illness; or
  (ii) Pose  a substantial present or po-
tential hazard to human health  or the
environment when  it  is  improperly
treated,  stored, transported, disposed
of or otherwise managed; and
  (2) The characteristic can be:
  (i) Measured by an available  stand-
ardized test method which is reason-
ably within the  capability of genera-
tors of solid waste  or private  sector
laboratories that are available to serve
generators of solid waste; or
  (ii) Reasonably detected by genera-
tors of  solid  waste  through  their
knowledge of their waste.

§261.11  Criteria   for  listing  hazardous
    waste.
  (a) The  Administrator shall  list a
solid waste as a hazardous waste only
upon determining that the solid waste
meets one of the  following criteria:
  (1) It exhibits any of the character-
istics of  hazardous waste  identified in
Subpart C.
  (2) It has been found to be fatal to
humans in low doses or, in the absence
of data on  human toxicity, it has been
shown in studies  to have an oral LD 50
toxicity  (rat) of less than  50 milli-
grams  per  kilogram, an inhalation LC
50 toxicity (rat) of less than 2 milli-
grams per liter, or a dermal LD 50 tox-
icity (rabbit)  of less than 200 milli-
grams per kilogram or is otherwise ca-
pable of causing or significantly  con-
tributing to an increase in serious irre-
versible,  or incapacitating reversible,
illness.  (Waste  listed in  accordance
with these criteria will be designated
Acute Hazardous Waste.)

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Environmental Protection Agency
                             §261.20
  (3) It contains any of the toxic con-
stituents  listed  in  Appendix   VIII
unless,  after  considering any of the
following factors,  the Administrator
concludes that the waste is not  capa-
ble of posing  a substantial present or
potential  hazard to human health or
the  environment  when  improperly
treated,  stored,  transported  or dis-
posed of, or otherwise managed:
  (i) The nature of  the toxicity pre-
sented by the  constituent.
  (ii) The concentration of the constit-
uent in the waste.
  (iii) The potential of the constituent
or any toxic  degradation  product of
the constituent to migrate from the
waste into the environment under the
types of improper management consid-
ered in paragraph (a)(3)(vii)  of this
section.
  (iv) The persistence of the constitu-
ent or any toxic degradation product
of the constituent.
  (v) The potential for the constituent
or any toxic  degradation  product of
the constituent to degrade into non-
harmful constituents and the rate of
degradation.
  (vi) The degree to which the constit-
uent  or  any  degradation product of
the constituent bioaccumulates in eco-
systems.
  (vii) The plausible types of improper
management to which the waste  could
be subjected.
  (viii) The quantities of the waste
generated  at  individual  generation
sites or on a regional  or national  basis.
  (ix) The nature  and severity of the
human  health  and  environmental
damage that has occurred as a result
of  the   improper   management  of
wastes containing the constituent.
  (x)  Action taken by other  govern-
mental agencies  or  regulatory  pro-
grams based on the health or environ-
mental hazard posed by the waste or
waste constituent.
  (xi) Such other factors as may be ap-
propriate.
Substances will be listed on Appendix
VIII only if they have been shown in
scientific  studies to have toxic,  carci-
nogenic,  mutagenic or terg  ogenic ef-
fects on humans or other life forms.
  (Wastes listed in  accordance  with
these criteria  will be  designated Toxic
wastes.)
  (b) The Administrator may list class-
es or types of solid waste as hazardous
waste if he has reason to believe that
individual wastes, within the class  or
type of waste,  typically or frequently
are hazardous under the definition  of
hazardous  waste found  in  section
1004(5) of the Act.
  (c) The Administrator will use the
criteria for listing specified in this sec-
tion to establish the  exclusion limits
referred to in § 261.5(c).

    Subpart C—Characteristics of
          Hazardous Waste
§ 261.20  General.
  (a)  A  solid  waste,  as  defined
in
§ 261.2, which  is  not excluded  from
regulation as a hazardous waste under
§ 261.4(b), is a hazardous waste if it ex-
hibits any of the characteristics identi-
fied in this subpart.

{Comment:  § 262.11  of this chapter sets
forth the generator's responsibility to deter-
mine whether his  waste  exhibits one  or
more of the characteristics identified in this
subpart]

  (b) A hazardous waste which is iden-
tified by a characteristic in this sub-
part, but  is not listed as a  hazardous
waste  in  Subpart D, is assigned the
EPA  Hazardous  Waste  Number set
forth in the respective  characteristic
in this subpart. This number must be
used in complying with the  notifica-
tion requirements of section 3010  of
the Act and certain recordkeeping and
reporting  requirements under   Parts
262 through 265, 268, and Part 270  of
this chapter.
  (c) For purposes of this subpart, the
Administrator will  consider  a sample
obtained using any  of  the  applicable
sampling methods specified in Appen-
dix I  to  be  a representative sample
within the meaning of Part 260 of this
chapter.

[Comment: Since the Appendix I sampling
methods are not being formally adopted  by
the Administrator, a person who  desires to
employ an alternative sampling method is
not required to demonstrate the equivalency
of his  method  under the procedures set
forth in §§ 260.20 and 260.21.]
[45 PR 33119, May 19, 1980, as amended at
48 FR 14294, Apr. 1, 1983; 51 FR 40636, Nov.
7, 1986]

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§261.21
         40 CFR Ch. I (7-1-89 Edition)
§ 261.21  Characteristic of ignitability.
  (a) A solid waste exhibits the charac-
teristic of ignitability  if  a representa-
tive sample of the waste  has any of
the following properties:
  (1) It is a liquid, other than an aque-
ous solution containing  less  than 24
percent  alcohol  by volume and has
flash  point less than 60°C (140°F), as
determined   by   a  Pensky-Martens
Closed  Cup  Tester,   using  the  test
method specified  in ASTM Standard
D-93-79  or D-93-80 (incorporated by
reference, see § 260.11), or a Setaflash
Closed  Cup  Tester,   using  the  test
method specified  in ASTM Standard
D-3278-78 (incorporated  by reference,
see §  260.11), or as determined by an
equivalent  test  method  approved by
the Administrator under  procedures
set forth in §§ 260.20 and 260.21.
  (2) It  is not a liquid and is  capable,
under standard temperature and  pres-
sure,  of causing fire through  friction,
absorption of moisture or spontaneous
chemical changes and, when ignited,
burns so vigorously and persistently
that it creates a hazard.
  (3) It  is an ignitable  compressed gas
as defined in  49 CFR  173.300 and as
determined by the test  methods de-
scribed  in that  regulation or equiva-
lent test methods approved by the Ad-
ministrator under §§ 260.20 and 260.21.
  (4) It  is an oxidizer as  defined  in 49
CFR 173.151.
  (b)  A  solid waste that  exhibits the
characteristic of ignitability, but is not
listed as a hazardous waste in  Subpart
D,  has   the  EPA Hazardous Waste
Number of D001.
[45 FR 33119, May 19, 1980. as amended at
46 FR 35247, July 7, 1981]

§ 261.22  Characteristic of corrosivity.
  (a) A solid waste exhibits the charac-
teristic  of corrosivity if  a representa-
tive sample of the waste has either of
the following properties:
  (1)  It  is aqueous and has a pH less
than  or equal to 2 or  greater than or
equal to 12.5, as determined by a pH
meter  using  either  an  EPA   test
method or an equivalent test method
approved by the Administrator under
the procedures set forth in §§ 260.20
and 260.21. The EPA test method for
pH is specified as Method 5.2  in "Test
Methods  for the  Evaluation  of  Solid
Waste,  Physical/Chemical Methods"
(incorporated   by   reference,    see
§ 260.11).
  (2)  It is a liquid and corrodes steel
(SAE 1020) at a rate greater than 6.35
mm (0.250 inch) per year at a test tem-
perature of 55°C (130°F) as determined
by the test method specified in NACE
(National Association of Corrosion En-
gineers) Standard TM-01-69 as stand-
ardized in "Test Methods for the Eval-
uation  of  Solid  Waste,  Physical/
Chemical Methods" (incorporated by
reference, see  § 260.11) or  an equiva-
lent test method approved by the Ad-
ministrator under the  procedures  set
forth in §§ 260.20 and 260.21.
  (b)  A solid waste that exhibits the
characteristic of corrosivity, but is not
listed as a hazardous waste in Subpart
D,  has the EPA Hazardous Waste
Number of D002.

[45 FR 33119, May 19, 1980, as amended at
46 FR 35247, July 7, 1981]

§ 261.23  Characteristic of reactivity.
  (a) A solid waste exhibits the charac-
teristic of reactivity if a representative
sample of the waste has any of the fol-
lowing properties:
  (1) It is normally unstable and  read-
ily undergoes violent change  without
detonating.
  (2) It reacts violently with water.
  (3)  It  forms potentially explosive
mixtures with water.
  (4) When mixed with water, it gener-
ates toxic gases, vapors or fumes in a
quantity sufficient to present a danger
to human health or the environment.
  (5) It is a cyanide or sulfide bearing
waste which, when exposed to pH con-
ditions between 2 and 12.5, can gener-
ate  toxic  gases, vapors  or  fumes in a
quantity sufficient to present a danger
to human health or the environment.
  (6) It is  capable of detonation or ex-
plosive reaction if it is  subjected to a
strong initiating source or if  heated
under confinement.
  (7) It is readily capable of detona-
tion or explosive decomposition or re-
action at  standard temperature  and
pressure.
  (8) It is a forbidden explosive as de-
fined  in 49 CFR 173.51, or a  Class A
explosive  as defined in 49 CFR 173.53

-------
Environmental Protection Agency
                             §261.30
or a Class B explosive as defined in 49
CFR 173.88.
  (b) A solid  waste that exhibits  the
characteristic of reactivity, but is  not
listed as a hazardous waste in Subpart
D,  has  the  EPA Hazardous  Waste
Number of D003.

§ 261.24  Characteristic of EP toxicity.
  (a) A solid waste exhibits the charac-
teristic of EP  toxicity if, using the test
methods described in Appendix II or
equivalent methods  approved  by  the
Administrator under the procedures
set forth in §§260.20 and 260.21,  the
extract  from  a representative  sample
of the waste contains any of the con-
taminants listed in Table I  at  a con-
centration equal to or greater than  the
respective value given  in  that  Table.
Where the waste contains less than 0.5
percent  filterable  solids, the  waste
itself, after filtering, is considered to
be the extract for the purposes of this
section.
  (b) A  solid  waste that exhibits  the
characteristic  of EP toxicity,  but is  not
listed as a hazardous waste in Subpart
D,  has   the  EPA Hazardous   Waste
Number specified in Table I which cor-
responds  to  the  toxic  contaminant
causing  it to be hazardous.

TABLE I—MAXIMUM CONCENTRATION  OF CON-
  TAMINANTS  FOR CHARACTERISTIC  OF  EP
  TOXICITY
TABLE I—MAXIMUM CONCENTRATION OF CON-
  TAMINANTS FOR CHARACTERISTIC  OF  EP
  TOXICITY—Continued
EPA
hazardous
waste
number
D004
D005
D006
D007
0008
D009
D010
D011
D012 	
D013
D014 	
D015 	

Contaminant
Arsenic
Barium 	
Cadmium 	
Chromium 	
Lead
Mercury
Selenium
Silver 	
Endrin (1,2,3,4.10,10-hexach-
loro-1,7-epoxy-
1 ,4,4a,5,6,7,8,8a-octahydro-
1 ,4-endo, endo-5,8-dimeth-
a no- naphthalene
UrxJane (1,2,3,4,5,6-hexa- chlor-
ocydohexane, gamma isomer.
Methoxychlor (1.1.1-Trichloro-
2,2-bis [p-methoxy-
phenyl] ethane).
Toxaphene (C,JH,«CI., Technical
chlorinated camphene, 67-69
percent chlorine).
Maximum
concentra-
tion
(milligrams
per liter)
50
100.0
1.0
5.0
50
02
1 0
5.0
0.02
0.4
10.0
0.5

EPA
hazardous
waste
number
D016...
D017

Contaminant
2 4-0 (2 4-Dichlorophenoxyace-
tic acid).
2 4 5-TP Silvex (2 4 5-Trichlo-
rophenoxypropionic acid).
Maximum
concentra-
tion
(milligrams
per liter)
100
1 0

    Subpart D—Lists of Hazardous
               Wastes

§ 261.30  General.
  (a)  A  solid  waste  is a  hazardous
waste  if it is  listed  in this  subpart,
unless it has been excluded from this
list under §§ 260.20 and 260.22.
  (b)  The  Administrator will indicate
his basis for listing the classes or types
of wastes listed in this Subpart by em-
ploying one or more of the following
Hazard Codes:
Ignitable Waste	
Corrosive Waste	
Reactive Waste	
EP Toxic Waste	
Acute Hazardous Waste	
Toxic Waste	
 (I)
(C)
(R)
(E)
(H)
(T)
Appendix VII identifies the constitu-
ent which caused the Administrator to
list the waste as an  EP Toxic  Waste
(E) or Toxic Waste  (T) in §§261.31
and 261.32.
  (c) Each hazardous waste listed  in
this subpart  is assigned an EPA Haz-
ardous Waste Number which precedes
the name of the waste. This number
must  be used in complying with the
notification  requirements  of Section
3010 of  the  Act and certain  record-
keeping  and  reporting  requirements
under Parts 262 through 265, 268, and
Part 270 of this chapter.
  (d) The following hazardous wastes
listed in § 261.31 or  § 261.32 are subject
to the exclusion limits for acutely haz-
ardous wastes established  in  § 261.5:
EPA  Hazardous Wastes Nos.  FO20,
FO21, FO22,  FO23,  FO26, and FO27.
[45 FR 33119,  May 19. 1980, as amended at
48 FR 14294, Apr. 1, 1983; 50 FR 2000, Jan.
14, 1985; 51 FR 40636,  Nov. 7, 1986]

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§ 261.31                                                             40  CFR Ch. I  (7-1-89 Edition)

§ 261.31   Hazardous wastes from non-specific sources.
  The  following  solid  wastes   are  listed   hazardous  wastes  from  non-specific
sources unless they are excluded under §§  260.20  and 260.22 and listed  in Appen-
dix IX.
Industry and EPA hazardous
        waste No.
                              Hazardous waste
 Hazard
  code
Generic:
  F001...
F002..
  F003..
  F004
  F005..
  F006..
  F019..
  F007..
  F008..

  F009..

  F010..

  F011..

  F012..

  F024..
  F020..
The following spent halogenated solvents used in degreasing: Tetrachloroethylene,
  trichloroethylene, methylene  chlonde.  1,1,1-tnchloroethane, carbon tetrachlonde,
  and chlorinated fluorocarbons; all spent solvent mixtures/blends used in degreas-
  ing containing, before use, a total of ten percent or more (by volume) of one or
  more of the above halogenated solvents or those solvents listed in F002, F004,
  and F005; and still bottoms from the recovery of these spent solvents and spent
  solvent mixtures.
The following spent halogenated solvents: Tetrachloroethylene, methylene chloride.
  trichloroethylene, 1,1,1-tnchloroethane,  chlorobenzene, 1,1,2-trichloro-1,2,2-trifluor-
  oethane,  ortho-dichlorobenzene, tnchlorofluoromethane, and 1,1,2-tnchloroethane;
  all spent  solvent mixtures/blends containing, before use, a total of ten percent or
  more (by volume) of one or more of  the  above halogenated  solvents or those
  listed in F001, F004, or F005; and still bottoms from the recovery of these spent
  solvents and spent solvent mixtures.
The following spent non-halogenated solvents: Xylene, acetone, ethyl  acetate, ethyl
  benzene, ethyl ether, methyl  isobutyl ketone,  n-butyl alcohol, cyclohexanone, and
  methanol; all spent solvent mixtures/blends containing, before use, only the above
  spent non-halogenated solvents; and all spent solvent mixtures/blends containing,
  before  use, one  or more of the above non-halogenated solvents, and, a total of
  ten percent or more (by volume) of one or_more of those solvents listed in F001,
  F002, F004, and  F005; and still bottoms from the recovery of these spent solvents
  and spent solvent mixtures.
The  following  spent non-halogenated  solvents:  Cresols  and cresylic  acid, and
  nitrobenzene;  all spent solvent mixtures/blends containing, before use. a total of
  ten percent or more (by volume) of one or more of  the  above non-halogenated
  solvents or those solvents listed in F001, F002, and F005; and still  bottoms from
  the recovery of these spent solvents and spent solvent mixtures.
The following spent non-halogenated solvents: Toluene,  methyl ethyl ketone,  carbon
  disulfide,  isobutanol, pyndme, benzene, 2-ethoxyethanol,  and 2-nitropropane;  all
  spent  solvent mixtures/blends  containing,  before  use, a  total of ten percent  or
  more (by volume) of one or more of the above non-halogenated solvents or those
  solvents  listed in F001.  F002, or F004; and still bottoms from the recovery  of
  these spent solvents and spent solvent mixtures.
Wastewater treatment  sludges from  electroplating  operations  except  from the
  following  processes: (1)  Sulfunc  acid anodizing  of aluminum;  (2)  tin plating on
  carbon  steel,  (3) zinc plating  (segregated basis) on carbon steel; (4) aluminum  or
  zinc-aluminum plating on carbon  steel; (5)  cleaning/stripping associated with  tin.
  zinc and  aluminum plating on carbon steel; and (6) chemical etching  and milling of
  aluminum.
Wastewater treatment sludges from the chemical conversion coating of aluminum	
Spent cyanide plating bath solutions from electroplating operations	
Plating bath residues from the bottom of plating  baths from electroplating operations
  where cyanides are used in the process.
Spent stnppmg  and cleaning  bath  solutions  from  electroplating  operations where
  cyanides  are used in the process.
Quenching  bath residues from  oil baths from metal heat treating  operations where
  cyanides  are used in the process.
Spent cyanide  solutions  from salt  bath pot cleaning  from metal  heat  treating
  operations.
Quenching waste water treatment sludges from metal  heat treating operations where
  cyanides  are used in the process.
Wastes,  including  but not limited to.  distillation residues,  heavy ends,  tars, and
  reactor clean-out wastes  from the production of chlorinated aliphatic hydrocar-
  bons,  having  carbon content from one to five,  utilizing  free  radical catalyzed
  processes.  [This listing does not include light ends, spent filters and  filter aids,
  spent dessicants, wastewater, wastewater treatment sludges, spent catalysts and
  wastes listed in § 261.32.].
Wastes (except wastewater and  spent carbon from hydrogen chlonde purification)
  from the  production or manufacturing use (as a reactant, chemical intermediate,  or
  component in a  formulating  process) of tri- or tetrachlorophenol, or of interme-
  diates  used to produce their pesticide derivatives.  (This listing  does not include
  wastes  from  the production  of  Hexachlorophene from  highly purrfied 2,4,5-
  trichlorophenol.).
                                                                                                          (T)
(T)
to-
                                                                                                         d.T)
                                                                                                         (T)
(T)
(R, T)
(R, T)

(R, T)

(R. T)

(R, T)

(T)

m
                                                                                                         (H)

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Environmental Protection Agency
                                                                     §261.32
Industry and EPA hazardous
        waste No.
                            Hazardous waste
 Hazard
  code
  F021	
  F022.
  F023	
  F026..
  F027	
  F028..
Wastes (except wastewater and spent carbon from hydrogen chloride purification)
  from the production or manufacturing use (as a reactant. chemical intermediate, or
  component in a formulating  process)  of pentachlorophenol,  or of intermediates
  used to produce its derivatives.
Wastes (except wastewater and spent carbon from hydrogen chloride purification)
  from the manufacturing use (as a reactant, chemical intermediate, or component in
  a formulating process) of tetra-.  penta-, or hexachlorobenzenes  under alkaline
  conditions
Wastes (except wastewater and spent carbon from hydrogen chloride punfication)
  from the production of matenals on  equipment previously used for the production
  or manufactunng use (as a reactant, chemical intermediate,  or component In a
  formulating process)  of tri- and tetrachlorophenols (This listing does not include
  wastes from equipment used only for the production or use of Hexachlorophene
  from highly purified 2,4,5-trichlorophenol.)
Wastes (except wastewater and spent carbon from hydrogen chloride purification)
  from the production of matenals on equipment previously used for the manufactur-
  ing use (as a reactant, chemical intermediate, or component in  a formulating
  process) of tetra-, penta-, or hexachlorobenzene under alkaline conditions.
Discarded unused  formulations  containing tn-, tetra-, or pentachlorophenol or dis-
  carded unused formulations containing compounds derived from these chlorophen-
  ols (This listing does not  include formulations containing Hexachlorophene sythe-
  sized from prepurified 2,4,5-tnchlorophenol as the sole component.)
Residues resulting  from the incineration or thermal treatment of soil  contaminated
  with EPA Hazardous Waste Nos F020, F021. F022, F023. F026, and F027
(H)
                                                                                                  (H)
                                                                                                  (H)
                                                                                                  (H)
                                                                                                  (H)
                                                                                                 (T)
  *(I,T) should be used to specify mixtures containing ignitable and toxic constituents.

[46 FR 4617, Jan. 16,  1981]
  EDITORIAL NOTE: For FEDERAL REGISTER  citations affecting § 261.31, see  the  List of CFR
Sections Affected in the Finding Aids section of this volume.

§ 261.32  Hazardous  wastes from specific sources.
  The following solid wastes  are listed hazardous wastes  from specific sources
unless they are excluded under §§ 260.20  and 260.22  and listed in  Appendix IX.
Industry and EPA hazardous
waste No
Wood preservation: K001 	
Inorganic pigments:
K002 . ....
K003 	
K004 	
K005
K006
K007 	
K008 	
Organic chemicals:
K009 	
K010
K011
K013
K014
K015 .
K016 	
K017 	
K018 	
K019 	
K020 	
K021 	
K022
K023 	
Hazardous waste
Bottom sediment sludge from the treatment of wastewaters from wood preserving
processes that use creosote and/or pentachlorophenol
Wastewater treatment sludge from the production of chrome yellow and orange
pigments.
Wastewater treatment sludge from the production of molybdate orange pigments
Wastewater treatment sludge from the production of zinc yellow pigments 	
Wastewater treatment sludge from the production of chrome green pigments
Wastewater treatment sludge from the production of chrome oxide green pigments
(anhydrous and hydrated).
Wastewater treatment sludge from the production of iron blue pigments ..
Oven residue from the production of chrome oxide green pigments 	
Distillation bottoms from the production of acetaldehyde from ethylene 	
Distillation side cuts from the production of acetaldehyde from ethylene
Bottom stream from the wastewater stripper in the production of acrylonitrile
Bottom stream from the acetonitnle column in the production of acrylonitrile
Bottoms from the acelonitnle punfication column in the production of acrylonitrile
Still bottoms from the distillation of benzyl chloride 	
Heavy ends or distillation residues from the production of carbon tetrachloride 	
Heavy ends (still bottoms) from the purification column in the production of
epichlorohydnn
Heavy ends from the tractionation column in ethyl chloride production 	
Heavy ends from the distillation of ethylene dichlonde in ethylene dichlonde
production.
Heavy ends from the distillation of vinyl chloride in vinyl chloride monomer
production.
Aqueous spent antimony catalyst waste from fluoromethanes production .. .
Distillation bottom tars from the production of phenol/acetone from cumene
Distillation hqht ends from the production of phthalic anhydride from naphthalene
Hazard
code
(T)
(T)
(T)
(T)
(T)
(T)
(T)
(T)
(T)

(R T)
(R T)
(T)
(T)
(T)
(T)
(T)
(T)
(T)
(T)
f~n
m

-------
§261.32
40 CFR Ch. I (7-1-89 Edition)
Industry and EPA hazardous
waste No.
K024
K093
K094 	 	
K025 	
K026
K027
K028
K029
K095
K096 	 _ 	
K030 	
K083
K103
K104 	
K085
K105 . .
K111 	
K112
K113 	
K114 	
K115
K116 	
K117
K118 	
K136
Inorganic chemicals:
K071
K073 	
K106
Pesticides:
K031 	
K032 	
K033 	
K034
K097 	
K035 	
K036 	
K037 	
K038 	
K039 	
K040 	
K041 	
K098 	
K042 	
K043 	
K099 	
K123 	
K124 	
K125 	

Hazardous waste
Distillation bottoms from the production of phthalic anhydride from naphthalene
Distillation light ends from the production of phthalic anhydride from ortho-xylene
Distillation bottoms from the production of phthalic anhydride from ortho-xylene
Distillation bottoms from the production of nitrobenzene by the nitration of benzene....
Stripping still tails from the production of methy ethyl pyndines . .
Centnfuge and distillation residues from toluene diisocyanate production 	
Spent catalyst from the hydrochlonnator reactor in the production of 1,1,1-trichlor-
oethane
Waste from the product steam stnpper in the production of 1,1,1-trichloroethane 	
Distillation bottoms from the production of 1 1 1 -trichloroethane
Heavy ends from the heavy ends column from the production of 1,1,1 -trichloroeth-
ane.
Column bottoms or heavy ends from the combined production of tnchloroethylene
and perchloroethylene.
Distillation bottoms from aniline production . 	
Process residues from aniline extraction from the production of aniline 	
Combined wastewater streams generated from nitrobenzene/aniline production 	
Distillation or fractionation column bottoms from the production of chlorobenzenes
Separated aqueous stream from the reactor product washing step in the production
of chlorobenzenes.
Product washwaters from the production of dinitrotoluene via nitration of toluene 	
Reaction by-product water from the drying column in the production of toluenedta-
mine via hydrogenation of dinitrotoluene.
Condensed liquid light enr*r from the purification of toluenediamme in the production
of toluenediamme via hydrogenation of dinitrotoluene.
Vicmals from the purification of toluenediamme in the production of toluenediamine
via hydrogenation of dinitrotoluene
Heavy ends from the purification of toluenediamme in the production of toluenedia-
mine via hydrogenation of dinitrotoluene.
Organic condensate from the solvent recovery column in the production of toluene
diisocyanate via phosgenation of toluenediamme.
Wastewater from the reactor vent gas scrubber in the production of ethylene
dibromide via brommation of ethene
Spent adsorbent solids from purification of ethylene dibromide in the production of
ethylene dibromide via brommation of ethene.
Still bottoms from the purification of ethylene dibromide in the production of ethylene
dibromide via brommation of ethene.
separately prepunfied brine is not used.
Chlonnated hydrocarbon waste from the purification step of the diaphragm cell
process using graphite anodes in chlorine production.
Wastewater treatment sludge from the mercury cell process in chlorine production
By-product salts generated in the production of MSMA and cacodylic acid
Wastewater treatment sludge from the production of chlordane
Wastewater and scrub water from the chlonnation of cyclopentadiene in the
production of chlordane.
Filter solids from the filtration of hexachlorocyclopentadiene in the production of
chlordane
Vacuum stripper discharge from the chlordane chlormator in the production of
chlordane.
Wastewater treatment sludges generated in the production of creosote
Still bottoms from toluene reclamation distillation in the production of disultoton
Wastewater treatment sludges from the production of disulfoton
Wastewater from the washing and stripping of phorate production
Filter cake from the filtration of diethylphosphorodithioic acid in the production of
phorate.
Wastewater treatment sludge from the production of phorate
Wastewater treatment sludge from the production of toxaphene
Untreated process wastewater from the production of toxaphene 	
Heavy ends or distillation residues from the distillation of tetrachlorobenzene in the
production of 2,4,5-T.
2,6-Dichlorophenol waste from the production of 2,4-D 	
Untreated wastewater from the production of 2,4-D 	
Process wastewater (including supernates, filtrates, and washwaters) from the
production of ethylenebis: locarbamic acid and its salt.
Reactor vent scrubber water from the production of ethylenebisdrthiocarbamic acid
and its salts.
Filtration, evaporation, and centntugation solids from the production of ethylenebis-
dithiocarbamic acid and its salts.
Hazard
code
(T)
CO
(T)
(T)
(T)
(R T)
(T)
CO
(T)
(T)
CO
(T)
(T)
(T)
(T)
(T)
(C,T)
(T)
(T)
(T)





m




rn









m




fc "n



-------
 Environmental Protection Agency
                              §261.33
Industry and EPA hazardous
waste No.
K126 	
Explosives:
K044 	
K045 	
K046 	
K047 	
Petroleum refining:
K048 	
K049 	
K050 	
K051 	
K052 	
Iron and steel:
K061 	
K062
Primary copper:
K064 	
Primary lead:
K065
Primary zinc:
K066 	
Primary aluminum.
K088 	
Ferroalloys:
K090 	
K091 	
Secondary lead:
K069
K100
Veterinary Pharmaceuticals:
KOB4
K101
K102 	
Ink formulation: K086
Coking:
K060 	
K087 	

Hazardous waste
Baghouse dust and floor sweepings in milling and packaging operations from the
production or formulation of ethylenebisdithiocarbamic acid and its salts
Wastewater treatment sludges from the manufacturing and processing of explosives
Spent carbon from the treatment of wastewater containing explosives
Wastewater treatment sludges from the manufacturing formulation and loading of
lead-based initiating compounds
Pink/red water from TNT operations
Dissolved air flotation (DAF) float from the petroleum refining industry
Slop oil emulsion solids from the petroleum refining industry
Heat exchanger bundle cleaning sludge from the petroleum refining industry
API separator sludge from the petroleum refining industry
Tank bottoms (leaded) from the petroleum refining industry
Emission control dust/sludge from the primary production of steel in electric
furnaces.
and steel industry (SIC Codes 331 and 332)
Acid plant blowdown slurry /sludge resulting from the thickening of blowdown slurry
from primary copper production
at primary lead smelting facilities
Sludge from treatment of process wastewater and/or acid plant blowdown from
primary zinc production
Spent potlmers from primary aluminum reduction .
Emission control dust or sludge from ferrochromiumsilicon production .
Emission control dust or sludge from ferrochromium production
Emission control dust/sludge from secondary lead smelting
Waste leaching solution from acid leaching of emission control dust/sludge from
secondary lead smelting
ceuticals from arsenic or organo-arsenic compounds
Distillation tar residues from the distillation of aniline-based compounds in the
production of veterinary Pharmaceuticals from arsenic or organo-arsenic com-
pounds.
Residue from the use of activated carbon for decolonzation in the production of
vetennary Pharmaceuticals from arsenic or organo-arsenic compounds.
Solvent washes and sludges, caustic washes and sludges, or water washes and
sludges from cleaning tubs and equipment used in the formulation of ink from
pigments, driers, soaps, and stabilizers containing chromium and lead.
Ammonia still lime sludge from coking operations
Decanter tank tar sludge from coking operations

Hazard
code
(T)
(R)
(R)
(T)
(R)
(T)
(T)
(T)

(T)

fc ~n
(T)

(T)
("0
(T)





(T)


[46 FR 4618, Jan. 16, 1981]
  EDITORIAL NOTE: For FEDERAL REGISTER citations affecting § 261.32, see the List of CFR
Sections Affected in the Finding Aids section of this volume.
§ 261.33  Discarde d commercial  chemical
    products, off-specification species, con-
    tainer   residues,  and  spill  residues
    thereof.
  The following materials or items are
hazardous wastes if and when they are
discarded or intended to be discarded
as described in  § 261.2(a)(2)(i),  when
they are mixed with waste oil or used
oil  or other material and applied to
the land for dust suppression or road
treatment,  when  they  are otherwise
applied to  the  land in lieu of  their
original intended use or when they are
contained in products that are applied
to the land in lieu of their original in-
tended use, or when, in lieu of  their
original  intended use,  they are pro-
duced for  use as  (or as a component

-------
§261.33
         40 CFR Ch. I (7-1-89 Edition)
of) a fuel, distributed for use as a fuel,
or burned as a fuel.
  (a)  Any  commercial chemical prod-
uct, or manufacturing chemical inter-
mediate  having   the  generic   name
listed  in paragraph  (e) or (f) of this
section.
  (b)  Any off-specification commercial
chemical  product or manufacturing
chemical intermediate which, if it met
specifications, would have the generic
name  listed in paragraph (e) or (f) of
this section.
  (c)  Any residue remaining in a con-
tainer or  in  an inner  liner  removed
from  a container  that has  held any
commercial chemical product or man-
ufacturing    chemical   intermediate
having the   generic  name  listed  in
paragraph (e) of  this section,  unless
the container is empty as defined in
§ 261.7(b)(3) of the chapter.

{.Comment: Unless the residue is being bene-
ficially used or reused,  or legitimately recy-
cled or reclaimed;  or  being  accumulated,
stored, transported or treated prior to such
use, re-use, recycling or reclamation, EPA
considers the residue to be intended for dis-
card, and thus,  a hazardous waste. An exam-
ple of a legitimate  re-use  of the  residue
would be where the residue remains in the
container and the container is used to hold
the same commercial chemical product or
manufacturing  chemical intermediate it pre-
viously held. An example of the discard of
the residue would be where the drum is sent
to a drum  reconditioner who reconditions
the drum but discards the residue.]

  (d)  Any residue or contaminated soil,
water or  other debris resulting from
the cleanup of a spill into or on any
land   or  water  of  any  commercial
chemical   product or manufacturing
chemical  intermediate having the ge-
neric name listed  in paragraph  (e) or
(f) of this section, or any residue or
contaminated soil,  water   or   other
debris resulting from the cleanup of a
spill, into or on any land or water, of
any off-specification chemical product
and manufacturing chemical interme-
diate which,  if it met specifications,
would have the generic name listed in
paragraph (e) or (f) of this section.

[Comment: The phrase "commercial chemi-
cal  product or manufacturing chemical in-
termediate having the generic name listed
in .  .  ." refers  to  a chemical  substance
which is  manufactured or formulated for
commercial  or manufacturing  use  which
consists of the commercially pure grade of
the chemical, any technical grades of the
chemical  that are produced or marketed,
and all formulations in which the chemical
is the sole  active ingredient. It does not
refer to a material, such as a manufacturing
process waste, that contains any of the sub-
stances listed in paragraph (e) or (f). Where
a manufacturing process waste is deemed to
be a hazardous waste because it contains a
substance listed in paragraph (e) or (f), such
waste will be listed  in either § 261.31 or
§ 261.32 or will be identified as a hazardous
waste by the characteristics set forth in
Subpart C of this part.]

  (e) The commercial chemical  prod-
ucts, manufacturing chemical interme-
diates  or off-specification  commercial
chemical  products  or manufacturing
chemical intermediates referred  to in
paragraphs (a) through (d) of this sec-
tion, are identified as acute hazardous
wastes (H) and are subject to be the
small quantity  exclusion  defined  in
§ 261.5(e).

[.Comment: For the convenience of the regu-
lated community the  primary  hazardous
properties of these materials have been indi-
cated by the letters T (Toxicity). and R (Re-
activity). Absence of a letter indicates that
the  compound only is listed for acute toxici-
ty.]

  These  wastes  and  their correspond-
ing EPA Hazardous  Waste  Numbers
are:
Haz-
ardous
waste
No.
P023
P002
P057
P058
P002
POOS
P070
P004
Chemical
abstracts No.
107-20-0
591-08-2
640-19-7
62-74-8
591-08-2
107-02-8
116-06-3
309-00-2
Substance
Acetaldehyde, chloro-
Acetamide, N-(aminothioxomethyl)-
Acetamide, 2-fluoro-
Acelic acid, fluoro-, sodium salt
1 -Acetyl-2-thiourea
Acrolem
Aldicarb
Aldnn

-------
Environmental  Protection  Agency
                                                                                           §261.33
Haz-
ardous
waste
No.

Chemical
abstracts No


Substance

POOS
P006
P007
POOS
P009
P119
P099
P010
P012
P011
P011
P012
P038
P036
P054
P067
P013
P024
P077
P028
P042
P046
P014
P001

P028
P015
P017
P018
P045

P021
P021
P022
P095
P023
P024
P026
P027
P029
P029
P030
P031
P033
P033
P034
P016
P036
P037
P038
P041
P040
P043
P004


P060


P037

P051

P044
P046
P047
P048
P020
P085
P111
P039
  107-18-6
20859-73-8
 2763-96-4
  504-24-5
  131-74-8
 7803-55-6
  506-61-6
 7778-39-4
 1327-53-3
 1303-28-2
 1303-28-2
 1327-53-3
  692-42-2
  696-28-6
  151-56-4
   75-55-8
  542-62-1
  106-47-8
  100-01-6
  100-44-7
   51-43-4
  122-09-8
  108-98-5
  1 81-81-2

  100-44-7
 7440-41-7
  598-31-2
  357-57-3
39196-18-4

  592-01-8
  592-01-8
   75-15-0
   75-44-5
  107-20-0
  106-47-8
 5344-82-1
  542-76-7
  544-92-3
  544-92-3
  460-19-5
  506-77-4
  506-77-4
  131-89-5
  542-88-1
  696-28-6
   60-57-1
  692-42-2
  311-45-5
  297-97-2
   55-91-4
  309-00-2


  465-73-6


   60-57-1

  1 72-20-8

   60-51-5
  122-09-8
 1 534-52-1
   51-28-5
   88-85-7
  152-16-9
  107-49-3
  298-04-4
Allyl alcohol
Aluminum phosphide (R.T)
5-(Ammomethyl)-3-isoxazolol
4-Ammopyndine
Ammonium picrate (R)
Ammonium vanadate
Argentate(l-), bis(cyano-C)-, potassium
Arsenic acid  H3AsO«
Arsenic oxide
Arsenic oxide
Arsenic pentoxide
Arsenic tnoxide
Arsine, diethyl-
Arsonous dichlonde. phenyl-
Azindme
Azmdine. 2-methyl-
Banum cyanide
Benzenamme, 4-chloro-
Benzenamme. 4-nitro-
Benzene, (chloromethyl)-
1,2-Benzenediol, 4-[1-hydroxy-2-(methylammo)ethyl]-, (R)-
Benzeneethanamme, alpha,alpha-dimethyl-
Benzenethiol
2H-1-Benzopyran-2-one, 4-hydroxy-3-(3-oxo-1-phenylbutyl)-, & salts, when present at concentrations
  greater than 0.3%
Benzyl chloride
Beryllium
Bromoacetone
Brucme
2-Butanone, 3,3-dimethyl-1 -(methylthio)-,
  O-[methylamino)carbonyl] oxime
Calcium  cyanide
Calcium  cyanide Ca(CN)2
Carbon disulfide
Carbonic dichlonde
Chloroacetaldehyde
p-Chloroanilme
1 -(o-Chlorophenyl)thiourea
3-Chloropropionitnle
Copper cyanide
Copper cyanide Cu(CN)
Cyanides (soluble cyanide salts), not otherwise specified
Cyanogen
Cyanogen chloride
Cyanogen chloride (CN)CI
2-Cyclohexy I-4,6-dmitrophenol
Dichloromethyl ether
Dichlorophenylarsme
Dieldrm
Diethylarsme
Diethyl-p-nitrophenyl phosphate
O,O-Diethyl 0-pyrazmyl phosphorothioate
Dusopropylfluorophosphate (DFP)
1,4,5,8-Dimethanonaphthalene, 1,2.3.4,10,10-hexa- chloro-1,4.4a,5,8,8a,-hexahydro-,
  (1 alpha,4alpha,4abeta,5alpha.8alpha.8abeta)-
1,4,5,8-Dimethanonaphthalene, 1,2.3,4,10,10-hexa- chloro-1,4,4a,5,8.8a-hexahydro-,
  (1alpha,4alpha,4abeta,5beta,8beta,8abeta)-
2,7:3,6-Dimethanonaphth[2.3-b]oxirene, 3,4,5,6,9,9-hexachloro-1a,2,2a,3,6,6a,7,7a-octahydro-,
  (1 aalpha.2beta,2aalpha.3beta.6beta.6aalpha,7beta, 7aalpha)-
2,7:3,6-Dimethanonaphth [2,3-b]oxirene, 3,4,5,6,9,9-hexachloro-1a,2,2a,3,6,6a,7,7a-octahydro-,
  (1aalpha,2beta,2abeta,3alpha.6alpha.6abeta,7beta, 7aalpha)-, & metabolites
Dimethoate
alpha,alpha-Dimethylphenethylamme
4,6-Dinitro-o-cresol. & salts
2,4-Dinitrophenol
Dinoseb
Diphosphoramide, octamethyl-
Diphosphonc acid, tetraethyl ester
Oisulfoton

-------
§261.33
40 CFR Ch. I (7-1-89 Edition)
Haz-
ardous Chemical
waste abstracts No
No.
P049 541-53-7
P050 1 1 5-29-7
P088 145-73-3
P051 72-20-8
P051 72-20-8
P042 51-43-4
P031 460-19-5
P066 16752-77-5

P101 107-12-0
P054 151-56-4
P097 52-85-7
P056 7782-41-4
P057 640-19-7
P058 62-74-8
P065 628-86-4
P059 76-44-8
P062 757-58-4
P116 79-19-6
P068 60-34-4
P063 74-90-8
P063 74-90-8
P096 7803-51-2
P060 465-73-6
P007 2763-96-4
P092 62-38-4
P065 628-86-4
P082 62-75-9
P064 624-83-9
P016 542-88-1
P112 509-14-8
P118 75-70-7
P050 115-29-7

P059 76-44-8

P066 16752-77-5
P068 60-34-4
P064 624-83-9
P069 75-86-5
P071 298-00-0
P072 86-88-4
P073 13463-39-3
P073 13463-39-3
P074 557-19-7
P074 557-19-7
P075 '54-11-5
P076 10102-43-9
P077 100-01-6
P078 10102-44-0
P076 10102-43-9
P078 10102-44-0
P081 55-63-0
P082 62-75-9
P084 4549-40-0
P085 152-16-9
P087 20816-12-0
P087 20816-12-0
P088 145-73-3
P089 56-38-2
P034 131-89-5
P048 51-28-5
P047 ' 534-52-1
P020 88-85-7
P009 131-74-8
P092 62-38-4
P093 103-85-5
P094 298-02-2
P095 75-44-5
P096 7803-51-2
Substance
Dithiobiuret
Endosulfan
Endothall
Endnn
Endrin, & metabolites
Epinephnne
Ethanedmitnle
Ethanimidothioic acid.








N-[[(methylamino)carbonyl]oxy]-. methyl ester
Ethyl cyanide
Ethyleneimine
Famphur
Fluorine
Fluoroacetamide
Fluoroacetic acid, sodium salt
Fulmmic acid. mercury(2 + ) salt (R.T)
Heptachlor
Hexaethyl tetraphosphate
Hydrazmecarbothioamide
Hydrazine, methyl-
Hydrocyanic acid
Hydrogen cyanide
Hydrogen phosphide
Isodnn
3(2H)-lsoxazolone. 5-(aminomethyl)-
Mercury, (acetato-O)phenyl-
Mercury fulminate (R,T)
Methanamme. N-methyl-N-nitroso-
Methane, isocyanato-
Methane. oxybistchloro-
Methane, tetranitro- (R)
Methanethiol, trichloro-
6,9-Methano-2,4,3-benzodioxathiepin, 6,7.8.9























10.10-
hexachloro-1 ,5,5a,6,9.9a-hexahydro-. 3-oxide
4,7-Methano-1H-indene. 1,4,5.6,7.8.8-heptachloro-
3a,4,7,7a-tetrahydro-
Methomyl
Methyl hydrazine
Methyl isocyanate
2-Methyllactonitrile
Methyl parathion
alpha-Naphthylthiourea
Nickel carbonyl
Nickel carbonyl Ni(CO)., (T-4)-
Nickel cyanide
Nickel cynaide Ni(CN)2
Nicotine. & salts
Nitric oxide
p-Nitroanilme
Nitrogen dioxide
Nitrogen oxide NO
Nitrogen oxide NO?
Nitroglycerine (R)
N-Nitrosodimethylamme
N-Nitrosomethylvinylamme
Octamethylpyrophosphoramide
Osmium oxide OsO«, (T-4)-
Osmium tetroxide
7-Oxabicyclo[2.2. 1 ] heptane-2,3-dicarboxyhc
Parathion
Phenol, 2-cyclohexyl-4,6-dmitro-
Phenol, 2,4-dinitro-
Phenol, 2-methyl-4,6-dinitro-, & salts
Phenol, 2-(1 -methylpropylH.e-dinitro-
Phenol, 2,4,6-trimtro-, ammonium salt (R)
Phenylmercury acetate
Phenylthiourea
Phorate
Phosgene
Phosphine























acid












-------
Environmental Protection Agency
§261.33
Haz-
ardous
waste
No.
P041
P039

P094

P044
P043
P089
P040
P097

P071
P110
P098
P098
P099
P070

P101
P027
P069
P081
P017
P102
P003
POOS
P067
P102
P008
P075
P114
P103
P104
P104
P105
P106
P106
P107
P108
P018
P108
P115
P109
P110
P111
P112
P062
P113
P113
P114
P115
P109
P045
P049
P014
P116
P026
P072
P093
P123
P118
P119
P120
P120
P064
P001
P121
P121
P122
Chemical
abstracts No.
311-45-5
298-04-4

298-02-2

60-51-5
55-91-4
56-38-2
297-97-2
52-85-7

298-00-0
78-00-2
151-50-8
151-50-8
506-61-6
116-06-3

107-12-0
542-76-7
75-86-5
55-63-0
598-31-2
107-19-7
107-02-8
107-18-6
75-55-8
107-19-7
504-24-5
1 54-11-5
12039-52-0
630-10-4
506-64-9
506-64-9
26628-22-8
143-33-9
143-33-9
1314-96-1
1 57-24-9
357-57-3
1 57-24-9
7446-18-6
3689-24-5
78-00-2
107-49-3
509-14-8
757-58-4
1314-32-5
1314-32-5
12039-52-0
7446-18-6
3689-24-5
39196-18-4
541-53-7
108-98-5
79-19-6
5344-82-1
86-88-4
103-85-5
8001-35-2
75-70-7
7803-55-6
1314-62-1
1314-62-1
4549-40-0
'81-81-2
557-21-1
557-21-1
1314-84-7
Substance
Phosphoric acid, diethyl 4-nitrophenyl ester
Phosphorodithioic acid, O.O-diethyl
S-[2-(ethylthio)ethyl] ester
Phosphorodithioic acid, 0,O-diethyl
S-[(ethylthio)methyl] ester
Phosphorodithioic acid, O,O-dimethyl S-[2-(methylamino)-2-oxoethyl] ester
Phosphorofluoridic acid, bis(l-methylethyl) ester
Phosphorothioic acid, O,O-diethyl O-(4-nitrophenyl) ester
Phosphorothioic acid, O.O-diethyl O-pyrazmyl ester
Phosphorothioic acid.
O-[4-t(dimethylamino)sulfonyl]phenyl] O.O-dimethyl ester
Phosphorothioic acid, O,O,-dimethyl O-(4-nitrophenyl) ester
Plumbane, tetraethyl-
Potassium cyanide
Potassium cyanide K(CN)
Potassium silver cyanide
Propanal, 2-methyl-2-(methylthio)-.
O- [ (methylamino)carbonyl ]oxime
Propanenitnle
Propanemtnle, 3-chloro-
Propanenitrile, 2-hydroxy-2-methyl-
1 ,2,3-Propanetnol, tnmtrate (R)
2-Propanone, 1-bromo-
Propargyl alcohol
2-Propenal
2-Propen-1 -ol
1 ,2-Propylenimme
2-Propyn-1-ol
4-Pyndmamine
Pyndine, 3-(1-methyl-2-pyrrolidmyl)-, (S)-, & salts
Selenious acid, dithallium(1 -t-) salt
Selenourea
Silver cyanide
Silver cyanide Ag(CN)
Sodium azide
Sodium cyanide
Sodium cyanide Na(CN)
Strontium sulfide SrS
Strychnidin-10-one, & salts
Strychnidin-10-one, 2,3-dimethoxy-
Strychnine, & salts
Sulfunc acid, dithallium(1 + ) salt
Tetraethyldithiopyrophosphate
Tetraethyl lead
Tetraethyl pyrophosphate
Tetranrtromethane (R)
Tetraphosphonc acid, hexaethyl ester
Thallic oxide
Thallium oxide TliOj
Thallium(l) selenite
Thallium(l) sulfate
Thiodiphosphonc acid, tetraethyl ester
Thiofanox
Thioimidodicarbonic diamide [(H2N)C(S)]3NH
Thiophenol
Thiosemicarbazide
Thiourea, (2-chlorophenyl)-
Thiourea, 1 -naphthalenyl-
Thiourea. phenyl-
Toxaphene
Tnchloromethanethiol
Vanadic acid, ammonium salt
Vanadium oxide V,Os
Vanadium pentoxide
Vinylamine, N-methyl-N-nitroso-
Warfann, & salts, when present at concentrations greater than 0.3%
Zinc cyanide
Zinc cyanide Zn(CN),
Zinc phosphide Zn»P», when present at concentrations greater than 10% (R,T)
 ' CAS Number given for parent compound only.

-------
§261.33

  (f)  The  commercial chemical  prod-
ucts,  manfacturing  chemical  interme-
diates, or off-specification commercial
chemical products referred to in para-
graphs (a) through  (d) of this section,
are  identified   as   toxic  wastes  (T),
unless otherwise  designated  and  are
subject to the  small  quantity genera-
tor exclusion defined  in  §  261.5 (a) and
(g).
                                                        40 CFR Ch.  I  (7-1-89 Edition)

                                            [Comment: For the convenience of the regu-
                                            lated community,  the  primary  hazardous
                                            properties of these materials have been indi-
                                            cated by the  letters T (Toxicity), R (Reac-
                                            tivity),  I (Ignitability) and C (Corrosivity).
                                            Absence of a  letter indicates that the  com-
                                            pound is only  listed for toxicity.]
                                               These wastes  and  their correspond-
                                            ing  EPA  Hazardous  Waste  Numbers
                                            are:
 Haz-
ardous
 waste
  No.
  Chemical
abstracts No
                                    Substance
U001
U034
U187
U005
U240
U112
U144
U214
see
  F027
U002
U003
U004
U005
U006
U007
U008
U009
U011
U012
U136
U014
11015
U010

U157
U016
U017
U192
U018
U094
U012
U014
U049
U093
U328
U353
U158
U222
U181
U019
U038
U030
U035
U037
U221
U028
U069
U088
U102
U107
U070
U071
U072
U060"
    75-07-0
    75-87-6
    62-44-2
    53-96-3
   1 94-75-7
   141-78-6
   301-04-2
   563-68-8
    93-76-5

    67-64-1
    75-05-8
    98-86-2
    53-96-3
    75-36-5
    79-06-1
    79-10-7
   107-13-1
    61-82-5
    62-53-3
    75-60-5
   492-80-8
   115-02-6
    50-07-7

    56-49-5
   225-51-4
    98-87-3
 23950-58-5
    56-55-3
    57-97-6
    62-53-3
   492-80-8
  3165-93-3
    60-11-7
    95-53-4
   106-49-0
   101-14-4
   636-21-5
    99-55-8
    71-43-2
   510-15-6
   101-55-3
   305-03-3
   108-90-7
 25376-45-8
   117-81-7
    84-74-2
    84-66-2
   131-11-3
   117-64-0
    95-50-1
   541-73-1
   106-46-7
    72-54-8
Acetaldehyde (I)
Acetaldehyde. trichloro-
Acetamide, N-(4-ethoxyphenyl)-
Acetamide, N-9H-fluoren-2-yl-
Acetic acid, (2,4-dichlorophenoxy)-. salts & esters
Acetic acid ethyl ester (I)
Acetic acid, lead(2 + ) salt
Acetic acid, thalhum(1 +) salt
Acetic acid, (2,4,5-tnchlorophenoxy)-

Acetone (I)
Acetonitnle (I.T)
Acetophenone
2-Acetylaminolluorene
Acetyl chloride (C.R.T)
Acrylamide
Acrylic acid (I)
Acrylonitnle
Amitrole
Aniline (I,T)
Arsmic acid, dimethyl-
Auramme
Azasenne
Azinno[2',3':3,4]pyrrolo[1,2-a]mdole-4,7-dione, 6-amino-8-[[(aminocarbonyl)oxy]methyl]-
  1,1a,2,8,8a,8b-hexahydro-8a-methoxy-5-methyl-, [1aS-(1aalpha. 8beta,8aalpha,8balpha)]-
Benz[j]aceanthrylene, 1,2-dihydro-3-methyl-
Benz[c]acndme
Benzal chloride
Benzamide, 3,5-dichloro-N-(1,l-dimethyl-2-propynyl)-
Benz[a]anthracene
Benztalanthracene, 7,12-dimethyl-
Benzenamme (I,T)
Benzenamme, 4,4'-carbonimidoylbis[N,N-dimethyl-
Benzenamme, 4-chloro-2-methyl-, hydrochloride
Benzenamme, N,N-dimethyl-4-(phenylazo)-
Benzenamme, 2-methyl-
Benzenamme, 4-methyl-
Benzenamme, 4,4'-methylenebis[2-chloro-
Benzenamme, 2-methyl-, hydrochloride
Benzenamine, 2-methyl-5-nitro-
Benzene (|,T)
Benzeneacetic acid, 4-chloro-alpha-(4-chlorophenyl)-alpha-hydroxy-, ethyl ester
Benzene, 1 -bromo-4-phenoxy-
Benzenebutanoic acid, 4-[bis(2-chloroethyl)ammo]-
Benzene, chloro-
Benzenediamine, ar-methyl-
1,2-Benzenedicarboxyhc acid. bis(2-ethylhexyl) ester
1,2-Benzenedicarboxylic acid, dibutyl ester
1,2-Benzenedicarboxyhc acid, diethyl ester
1,2-Benzenedicarboxylic acid, dimethyl ester
1,2-Benzenedicarboxylic acid, dioctyl ester
Benzene, 1,2-dichloro-
Benzene, 1,3-dichloro-
Benzene, 1,4-dichloro-
Benzene, 1,1 '-(2.2-dichloroethylidene)bis[4-chloro-

-------
Environmental  Protection Agency
                                                                                            § 261.33
Haz-
ardous
waste
No.

Chemical
abstracts No.


Substance

U017
U223
U239
U201
U127
U056
U220
U105
U106
U055
U169
U183
U185
U020
U020
U207
U061
U247
U023
U234
U021
U202
U203
U141
U090
U064
U248

U022
U197
U023
U085
U021
U073
U091
U095
U225
U030
U128
U172
U031
U159
U160
U053
U074
U143
U031
U136
U032
U238
U178
U097
U114

U062
U215
U033
U156
U033
U211
U034
U035
U036
U026
U037
U038
U039
   98-87-3
26471-62-5
 1330-20-7
  108-46-3
  118-74-1
  110-82-7
  108-88-3
  121-14-2
  606-20-2
   98-82-8
   98-95-3
  608-93-5
   82-68-8
   98-09-9
   98-09-9
   95-94-3
   50-29-3
   72-43-5
   98-07-7
   99-35-4
   92-87-5
  1 81-07-2
   94-59-7
  120-58-1
   94-58-6
  189-55-9
  •81-81-2

   50-32-8
  106-51-4
   98-07-7
 1464-53-5
   92-87-5
   91-94-1
  119-90-4
  119-93-7
   75-25-2
  101-55-3
   87-68-3
  924-16-3
   71-36-3
   78-93-3
 1338-23-4
 4170-30-3
  764-41-0
  303-34-4
   71-36-3
   75-60-5
13765-19-0
   51-79-6
  615-53-2
   79-44-7
 1 111-54-6

 2303-16-4
 6533-73-9
  353-50-4
   79-22-1
  353-50-4
   56-23-5
   75-87-6
  305-03-3
   57-74-9
  494-03-1
  108-90-7
  510-15-6
   59-50-7
Benzene, (dichloromethyl)-
Benzene, 1,3-dnsocyanatomethyl- (R,T)
Benzene, dimethyl- (I,T)
1,3-Benzenediol
Benzene, hexachlorc-
Benzene, hexahydro- (I)
Benzene, methyl-
Benzene, 1-methyl-2,4-dinitro-
Benzene, 2-methyl-1,3-dinitro-
Benzene, (1-methylethyl)- (I)
Benzene, nitro-
Benzene, pentachloro-
Benzene, pentachloronitro-
Benzenesulfonic acid chlonde (C,R)
Benzenesulfonyl chlonde (C,R)
Benzene, 1,2,4,5-tetrachloro-
Benzene, 1,1 '-(2,2,2-tnchloroethylidene)bis[4-chloro-
Benzene, 1,1'-(2,2,2-tnchloroethylidene)bis[4- methoxy-
Benzene, (tnchloromethyl)-
Benzene, 1,3,5-tnmtro-
Benzxjine
1,2-Benzisothiazol-3(2H)-one,  1,1-dioxide, & salts
1,3-Benzodioxole, 5-(2-propenyl)-
1,3-Benzodioxole, 5-(1-propenyl)-
1,3-Benzodioxole, 5-propyl-
Benzo [ rst ] pentaphene
2H-1-Benzopyran-2-one, 4-hydroxy-3-(3-oxo-1-phenyl-butyl)-, & salts, when present at concentrations
  of 0.3% or less
Benzotalpyrene
p-Benzoqumone
Benzotnchlonde (C.R.T)
2,2'-Bioxirane
[1,1'-Biphenyl]-4,4'-diamine
[ 1,1 '-Biphenyl]-4,4'-diamine, 3,3'-dichloro-
[ 1,1 '-Biphenyl]-4,4'-diamine, 3,3'-dimethoxy-
[1,1'-Biphenyl]-4,4'-diamine, 3,3'-dimethyl-
Bromofomi
4-Bromophenyl phenyl ether
1,3-Butadiene, 1,1,2,3,4,4-hexachloro-
1 -Butanamme, N-butyl-N-nitroso-
1-Butanol (I)
2-Butanone (I.T)
2-Butanone, peroxide (R,T)
2-Butenal
2-Butene,  1,4-dichloro-  (I,T)
2-Butenoic acid, 2-methyl-, 7-[[2,3-dihydroxy-
  2-(1-methoxyethyl)-3-methyl-1-oxobutoxy]methyl]-
  2,3;5,7a-tetrahydro-1 H-pyrrolizin-1 -yl ester,
  [1S-[1alpha(Z),7(2S*,3R'),7aalpha]]-
n-Butyl alcohol (I)
Cacodylic acid
Calcium  chromate
Carbamic acid, ethyl ester
Carbamic acid, methylnitroso-, ethyl ester
Carbamic chloride, dimethyl-
Carbamodrthioic acid, 1,2-ethanediyltHS-,
  salts & esters
Carbamothiotc acid, bis(l-methylethyl)-, S-(2,3-dichloro-2-propenyl) ester
Carbonic acid, dithallium(1 +)  salt
Carbonic difluoride
Cartaonochloridic acid, methyl  ester (I,T)
Carbon oxyfluonde (R,T)
Carbon tetrachloride
Chloral
Chlorambucil
Chkxdane, alpha & gamma isomers
Chkxnaphazin
Chkxobenzene
Chkxobenzilate
p-Chkxc-m-cresol
    80-144  O—89-
                     -15

-------
§261.33
40 CFR Ch. I (7-1-89 Edition)
Haz-
ardous
waste
No.
U042
U044
U046
U047
U048
U049
U032
U050
U051
U052
U053
U055
U246
U197
U056
U129

U057
U130
U058
U240
U059
U060
U061
U062
U063
U064
U066
U069
U070
U071
U072
U073
U074
U075
U078
U079
U025
U027
U024
U081
U082
U084
U085
U108
U028
U086
U087
U088
U089
U090
U091
U092
U093
U094
U095
U096
U097
U098
U099
U101
U102
U103
U105
U106
U107
U108
U109
U110
U111
Chemical
abstracts No
110-75-8
67-66-3
107-30-2
91-58-7
95-57-8
3165-93-3
13765-19-0
218-01-9

1319-77-3
4170-30-3
98-82-8
506-68-3
106-51-4
110-82-7
58-89-9

108-94-1
77-47-4
50-18-0
i 94-75-7
20830-81-3
72-54-8
50-29-3
2303-16-4
53-70-3
189-55-9
96-12-8
84-74-2
95-50-1
541-73-1
106-46-7
91-94-1
764-41-0
75-71-8
75-35-4
1 56-60-5
111-44-4
108-60-1
111-91-1
120-83-2
87-65-0
542-75-6
1464-53-5
123-91-1
117-81-7
1615-80-1
3288-58-2
84-66-2
56-53-1
94-58-6
119-90-4
124-40-3
60-11-7
57-97-6
119-93-7
80-15-9
79-44-7
57-14-7
540-73-8
105-67-9
131-11-3
77-78-1
121-14-2
606-20-2
117-84-0
123-91-1
122-66-7
142-84-7
621-64-7
Substance
2-Chloroethyl vinyl ether
Chloroform
Chloromethyl methyl ether
beta-Chloronaphthalene
o-Chlorophenol
4-Chloro-o-toluidine. hydrochlonde
Chromic acid H3CrO«, calcium salt
Chrysene
Creosote
Cresol (Cresylic acid)
Crotonaldehyde
Cumene (I)
Cyanogen bromide (CN)Br
2,5-Cyclohexadiene-1 ,4-dione
Cyclohexane (I)
Cyclohexane, 1 ,2.3.4,5.6-hexachloro-,
( 1 alpha,2alpha,3beta.4alpha,5alpha,6beta)-
Cyclohexanone (1)
1 ,3-Cyclopentadiene. 1 ,2,3.4,5.5-hexachloro-
Cyclophosphamide
2.4-D, salts & esters
Daunomycin
ODD
DDT
Diallate
Dibenzta.h] anthracene
Dibenzo[a,i]pyrene
1 ,2-Dibromo-3-chloropropane
Dibutyl phthalate
o-Dichlorobenzene
m-Dichlorobenzene
p-Dichlorobenzene
3,3'-Dichlorobenzidine
1,4-Dichloro-2-butene (I.T)
Dirhlorodrfluoromethane
1,1-Dichloroethylene
1,2-Dichloroethylene
Dichloroethyl ether
Dichloroisopropyl ether
Dichloromethoxy ethane
2,4-Dichlorophenol
2,6-Dichlorophenol
1 ,3-Dichloropropene
1,2:3,4-Diepoxybutane (I.T)
1 ,4-Diethyleneoxide
Diethylhexyl phthalate
N.N'-Diethylhydrazine
O,O-Diethyl S-methyl dithiophosphate
Diethyl phthalate
Diethylstilbesterol
Dihydrosatrole
3,3'-Dimethoxybenzidme
Dimethylamme (I)
p-Dimethylammoazobenzene
7,12-Dimethylbenz[a]anthracene
3,3'-Dimethylbenzidine
alpha, alpha-Dimethylbearylhydroperoxide (R)
Dimethylcarbamoyl chloride
1 ,1 -Dimethylhydrazine
1 ,2-Dtmethylhydrazine
2,4-Dimethylphenol
Dimethyl phthalate
Dimethyl sulfate
2.4-Dinrtrotoluene
2,6-Dinrtrotoluene
Di-rvoctyl phthalate
1 ,4-Dioxane
1 ,2-Diphenythydrazine
Dipropylamine (I)
Dt-n-propylnitrosamine

-------
Environmental Protection Agency
§261.33
Haz-
ardous Chemical
waste abstracts No.
No.
U041 106-89-8
U001 75-07-0
U174 55-18-5
U155 91-80-5
U067 106-93-4
U076 75-34-3
U077 107-06-2
U131 67-72-1
U024 111-91-1
U117 60-29-7
U025 1 1 1 -44-4
U184 76-01-7
U208 630-20-6
U209 79-34-5
U218 62-55-5
U226 71-55-6
U227 79-00-5
U359 110-80-5
U173 1116-54-7
U004 98-86-2
U043 75-01-4
U042 110-75-8
U078 75-35-4
U079 156-60-5
U210 127-18-4
U228 79-01-6
U112 141-78-6
U113 140-88-5
U238 51-79-6
U117 60-29-7
U114 ' 111-54-6
U067 106-93-4
U077 107-06-2
U359 110-80-5
U115 75-21-8
U116 96-45-7
U076 75-34-3
U118 97-63-2
U119 62-50-0
U120 206-44-0
U122 50-00-0
U123 64-18-6
U124 110-OO-9
U125 98-01-1
U147 108-31-6
U213 109-99-9
U125 98-01-1
U124 110-00-9
U206 18883-66-4
U206 18883-66-4

U126 765-34-4
U163 70-25-7
U127 118-74-1
U126 87-68-3
U130 77-47-4
U131 67-72-1
U132 70-30-4
U243 1888-71-7
U133 302-01-2
U086 1615-80-1
U098 57-14-7
U099 540-73-8
U109 122-66-7
U134 7664-39-3
U134 7664-39-3
U135 7783-06-4
U135 7783-O6-4
U096 80-15-9
U116 96-45-7
Substance
Epichlorohydnn
Ethanal (I)
Ethanamine, N-ethyl-N-nitroso-



1 ,2-Ethanediamme, N,N-dimethyl-N'-2-pyndmyl-N'-(2-thienylmethyl)-
Ethane, 1,2-dibromo-
Ethane, 1,1-dichloro-
Ethane, 1,2-dichloro-
Ethane, hexachloro-
Ethane, 1 , 1 '-[ methylenebis(oxy) ] bis [ 2-chloro-
Ethane, 1,V-oxybis-(l)
Ethane, 1,1'-oxybis[2-chloro-
Ethane, pentachlorc-
Ethane, 1,1.1,2-tetrachloro-
Ethane, 1,1,2,2-tetrachloro-
Ethanethioamide
Ethane, 1,1,1-tnchloro-
Ethane, 1,1,2-tnchloro-
Ethanol, 2-ethoxy-
Ethanol, 2,2'-(nitrosoimino)bis-
Ethanone, 1-phenyl-
Ethene, chloro-
Ethene, (2-chloroethoxy)-
Ethene, 1,1-dichloro-
Ethene, 1 ,2-dichloro-, (E)-
Ethene, tetrachloro-
Ethene, trichloro-
Ethyl acetate (I)
Ethyl acrylate (I)
Ethyl carbamate (urethane)
Ethyl ether (I)
Ethylenebisdithiocarbamic acid, salts & esters
Ethylene dibromide
Ethylene dichloride
Ethylene glycol monoethyl ether
Ethylene oxide (I,T)
Ethylenethiourea
Ethylidene dichlonde
Ethyl methacrylate
Ethyl methanesulfonate
Fluoranthene
Formaldehyde
Formic acid (C.T)
Furan (I)
2-Furancarboxaldehyde (I)
2,5-Furandione
Furan, tetrahydro-(l)
Furfural (I)
Furturan (I)
Glucopyranose, 2-deoxy-2-(3-methyl-3-nitrosoureido)-,
D-Glucose. 2-deoxy-2- [ C (methylnitrosoammo)-
carbonyUamino]-
Glycidylaldehyde
Guanidine, N-methyl-N'-nitro-N-mtroso-
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Hexachlorophene
Hexachloropropene
Hydrazme (R,T)
Hydrazine, 1,2-diethyl-
Hydrazine, 1 , 1 -dimethyl-
Hydrazine, 1 ,2-dimethyl-
Hydrazine, 1 ,2-diphenyl-
Hydrofluoric acid (C.T)
Hydrogen fluoride (C,T)
Hydrogen sulfide
Hydrogen sulfide H,S
Hydroperoxide, 1 -methyl- 1 -phenylethyl- (R)
2-lmidazolidinethione












































D-






















-------
§261.33
                                                               40 CFR Ch.  I  (7-1-89 Edition)
 Haz-
ardous
 waste
  No.
  Chemical
abstracts No.
                                         Substance
U137
U190
U140
U141
U142
U143
U144
U146
U145
U146
U129
U163
U147
U148
U149
U150
U151
U152
U092
U029
U045
U046
U068
U080
U075
U136
U119
U211
U153
U225
U044
U121
U036
U154
U155
U142
U247
U154
U029
U186
U045
U156
U226
LM57
U158
U066
U080
U159
U160
U138
U161
U162
U161
U164
U010
U059

U167
U168
U026
U165
U047
U166
U236

U166
U167
U168
U217
U169
    193-39-5
     85-44-9
     78-83-1
    120-58-1
    143-50-0
    303-34-4
    301-04-2
   1335-32-6
   7446-27-7
   1335-32-6
     58-89-9
     70-25-7
    108-31-6
    123-33-1
    109-77-3
    148-82-3
   7439-97-6
    126-98-7
    124-40-3
     74-83-9
     74-87-3
    107-30-2
     74-95-3
     75-09-2
     75-71-8
     74-88-4
     62-50-0
     56-23-5
     74-93-1
     75-25-2
     67-66-3
     75-69-4
     57-74-9
     67-56-1
     91-80-5
    143-50-0
     72-43-5
     67-56-1
     74-«3-9
    504-60-9
     74-87-3
     79-22-1
     71-55-6
     56-49-5
    101-14-4
     74-95-3
     75-09-2
     78-93-3
   1338-23-4
     74-88-4
    108-10-1
     80-62-6
    108-10-1
     56-04-2
     50-07-7
  20830-81-3

    134-32-7
     91-59-8
    494-03-1
     91-20-3
     91-58-7
    130-15-4
     72-57-1

    130-15-4
    134-32-7
     91-59-8
  10102-45-1
     98-95-3
IndenoC 1,2,3-cd]pyrene
1,3-lsobenzofurandione
Isobutyl alcohol (I,T)
Isosafrole
Kepone
Lasiocarpme
Lead acetate
Lead, bis(acetato-O)tetrahydroxytri-
Lead phosphate
Lead subacetate
LJndane
MNNG
Maleic  anhydride
Maleic  hydrazide
Malononitnle
Melphalan
Mercury
Methacrylonrtrile (I, T)
Methanamine, N-methyl- (I)
Methane, bromo-
Methane, chloro- (I, T)
Methane, chloromethoxy-
Methane. dibromo-
Methane, dichloro-
Methane, dichlorodifluoro-
Methane, iodo-
Methanesulfonic acid, ethyl ester
Methane, tetrachloro-
Methanethtol (I, T)
Methane, tribromo-
Methane, trichloro-
Methane, tnchlorofluoro-
4,7-Methano-1 H-indene, 1,2,4,5,6.7,8.8-octachloro-2,3,3a,4,7,7a-hexahydro-
Methanol (I)
Methapyrilene
1,3.4-Metheno-2H-cyclobuta[cd]pentalen-2-one, 1,1a,3,3a,4,5,5,5a,5b,6-decachlorooctahydro-
Methoxychlor
Methyl  alcohol (I)
Methyl  bromide
1-Methylbutadiene (I)
Methyl  chlonde (I.T)
Methyl  chlorocarbonate (I,T)
Methyl  chloroform
3-Methylcholanthrene
4,4'-Methylenebis(2-chloroaniline)
Methylene bromide
Methylene chloride
Methyl  ethyl ketone (MEK) (I.T)
Methyl  ethyl ketone peroxide (R,T)
Methyl  iodide
Methyl  isobutyl ketone (I)
Methyl  methacrylate (I.T)
4-Methyl-2-pentanone (I)
Methylthiouracil
Mitomycin C
5,12-Naphthacenedione. 8-acetyl-10-[(3-amino-2,3,6-tndeoxy)-alpha-L-lyxo-hexopyranosyl)oxy]-
  7,8,9,10-tetrahydro-6,8,11-trihydroxy-1-methoxy-, (8S-cis)-
1-Naphthalenamine
2-Naphthalenamine
Naphthalenamine, N,N'-bis<2-chloroethyl)-
Naphthalene
Naphthalene,  2-chloro-
1,4-Naphthalenedione
2,7-Naphthalenedisurfonic acid, 3.3'-[(3.3'-
  dimethyl[1,V-biphenyl]-4,4'-diyl)bis(azo)bis[5-amino-4-hydroxy]-, tetrasodium salt
1,4-Naphthoquinone
alpha-Naphthylamine
beta-Naphthylamine
Nitric acid. thallium(1 +) salt
Nitrobenzene  (I.T)

-------
Environmental Protection Agency
§261.33
Haz-
ardous
waste
No.
U170
U171
U172
U173
U174
U176
U177
U178
U179
U180
U181
U193
U058

U115
U126
U041
U182
U183
U184
U185
See
F027
U161
U186
U187
U188
U048
U039
U081
U082
U089
U101
U052
U132
U170
See
F027
See
F027
See
F027
See
F027
U150
U145
U087
U189
U190
U191
U179
U192
U194
U111
U110
U066
U083
U149
U171
U027
U193
See
F027
U235
U140
U002
U007
U084
U243
U009
Chemical
abstracts No.
100-02-7
79-46-9
924-16-3
1116-54-7
55-18-5
759-73-9
684-93-5
615-53-2
100-75-4
930-55-2
99-55-8
1120-71-4
50-18-0

75-21-8
765-34-4
106-89-8
123-63-7
608-93-5
76-01-7
82-68-8
87-86-5

108-10-1
504-60-9
62-44-2
108-95-2
95-57-8
59-50-7
120-83-2
87-65-0
56-53-1
105-67-9
1319-77-3
70-30-4
100-02-7
87-86-5

58-90-2

95-95-4

88-06-2

148-82-3
7446-27-7
3288-58-2
1314-80-3
85-44-9
109-06-8
100-75-4
23950-58-5
107-10-8
621-64-7
142-84-7
96-12-8
78-87-5
109-77-3
79-46-9
108-60-1
1120-71-4
93-72-1

126-72-7
78-83-1
67-64-1
79-06-1
542-75-6
1888-71-7
107-13-1
Substance
p-Nitrophenol
2-Nitropropane (|,T)
N-Nitrosodi-n-butylamine
N-Nitrosodiethanolamine
N-Nitrosodiethylamine
N-Nitroso-N-ethylurea
N-Nitroso-N-methylurea
N-Nitroso-N-methylurethane
N-Nitrosopipendine
N-Nitrosopyrrolidine
5-Nitro-o-toluidine
1 .2-Oxathiolane, 2,2-dioxide
2H-1 ,3,2-Oxazaphosphorin-2-amine,
N,N-bis(2-chloroethyl)tetrahydro-, 2-oxide
Oxirane (I,T)
Oxiranecarboxyaldehyde
Oxirane, (chloromethyl)-
Paraldehyde
Pentachlorobenzene
Pentachloroethane
Pentachloronitrobenzene (PCNB)
Pentachlorophenol

Pentanol, 4-methyl-
1 ,3-Pentadiene (I)
Phenacetin
Phenol
Phenol, 2-chloro-
Phenol, 4-chlorc~3-methyl-
Phenol, 2,4-dichloro-
Phenol, 2,6-dichloro-
Phenol, 4,4'-(1,2-diethyl-1,2-ethenediyl)bis-, (El-
Phenol, 2,4-dim8thyl-
Phenol, methyl-
Phenol, 2,2'-methylenebist3.4,6-trichloro-
Phenol, 4-nitro-
Phenol, pentachloro-

Phenol, 2.3,4,6-tetrachloro-

Phenol, 2.4,5-trichloro-

Phenol, 2,4,6-trichloro-

L-Phenylalanine, 4- [ bis(2-chlof oethyl)amino] -
Phosphoric acid, lead(2 + ) salt (2:3)
Phosphorodithioic acid, O,O-diethyl S-methyl ester
Phosphorus sulfide (R)
Phthalic anhydride
2-Picolme
Piperidine, 1-nitroso-
Pronamide
1-Propanamine (I,T)
1-Propanamine, N-nrtroso-N-propyl-
1-Propanamine, N-propyl- (I)
Propane, 1 ,2-dibromo-3-chloro-
Propane, 1 ,2-dichloro-
Propanedinitrile
Propane, 2-nrtro- (I.T)
Propane, 2.2'-oxybist2-chloro-
1,3-Propane sultone
Propanoic acid, 2-(2.4,5-tnchlorophenoxy)-

1-Propanol, 2,3-dibromo-, phosphate (3:1)
1-Propanol, 2-methyl- (I,T)
2-Propanone (I)
2-Propenamide
1-Propene, 1 ,3-dichkxo-
1-Propene, 1,1,2,3.3,3-hexachtoro-
2-Propenenrtrile

-------
§261.33
40 CFR Ch. I (7-1-89 Edition)
Haz-
ardous
waste
No.
U152
uooe
U113
U118
U162
U194
U083
U148
U196
U191
U237

U164
U180
U200
U201
U202
U203
U204
U204
U205
U205
U015
See
F027
U206
U103
U189
See
F027
U207
U208
U209
U210
See
F027
U213
U214
U215
U216
U216
U217
U218
U153
U244
U219
U244
U220
U221
U223
U328
U353
U222
U011
U227
U228
U121
See
F027
See
F027
U234
U182
U235
U236
U237
U176
U177
U043
U248
Chemical
abstracts No.
126-98-7
79-10-7
140-88-5
97-63-2
80-62-6
107-10-8
78-87-5
123-33-1
110-86-1
109-06-8
66-75-1

56-04-2
930-55-2
50-55-5
108-46-3
' 81-07-2
94-59-7
7783-00-8
7783-00-8
7488-56-4
7488-56-4
1 1 5-02-6
93-72-1

1 8883-66-4
77-78-1
1314-80-3
93-76-5

95-94-3
630-20-6
79-34-5
127-18-4
58-90-2

109-99-9
563-68-8
6533-73-9
7791-12-0
7791-12-0
10102-45-1
62-55-5
74-93-1
137-26-8
62-56-6
137-26-8
108-88-3
25376-45-8
26471-62-5
95-53-4
106-49-0
636-21-5
61-82-5
79-00-5
79-01-6
75-69-4
95-95-4

88-06-2

99-35-4
123-63-7
126-72-7
72-57-1
66-75-1
759-73-9
684-93-5
75-01-4
1 81-81-2
Substance
2-Propenenitrile, 2-methyl- (I.T)
2-Propenoic acid (I)
2-Propenoic acid, ethyl ester (I)
2-Propenoic acid, 2-methyl-, ethyl ester
2-Propenoic acid, 2-methyl-, methyl ester (I.T)
n-Propylamine (I.T)
Propylene dichlonde
3,6-Pyndazinedione, 1.2-dihydro-
Pyridme
Pyridme. 2-methyl-
2,4-(1 H,3H)-Pynmidmedione, 5-[bis(2-
chloroethyl)amino]-
4(1H)-Pynmidinone, 2,3-dihydro-6-methyl-2-thioxo-
Pyrrolidine, 1-nitroso-
Reserpine
Resorcinol
Saccharin. & salts
Safrole
Selenious acid
Selenium dioxide
Selenium sulfide
Selenium sulfide SeS? (R,T)
L-Senne, diazoacetate (ester)
Silvex (2,4,5-TP)

Streptozotocm
Sulfunc acid, dimethyl ester
Sulfur phosphide (R)
2,4,5-T

1 ,2,4,5-Tetrachlorobenzene
1,1,1 ,2-Tetrachloroethane
1 . 1 ,2,2-Tetrachloroethane
Tetrachloroethylene
2,3,4,6-Tetrachlorophenol

Tetrahydrofuran (I)
Thallium(l) acetate
Thallium(l) carbonate
Thallium(l) chlonde
Thallium chlonde Tlcl
Thallium(l) nitrate
Thioacetamide
Thiomethanol (I.T)
Thioperoxydicarbomc diamide [(H2N)C(S)]3S2, tetramethyl-
Thiourea
Thiram
Toluene
Toluenediamme
Toluene diisccyanate (R,T)
o-Toluidine
p-Toluidme
o-Toluidine hydrochlonde
1 H-1 ,2,4-Triazol-3-amine
1 ,1 ,2-Tnchloroethane
Tnchloroethylene
Tnchloromonofluoromethane
2.4,5-Tnchlorophenol

2,4,6-Trichlorophenol

1 ,3,5-Trinitrobenzene (R.T)
1,3,5-Trioxane. 2.4,6-tnmethyl-
Tris(2,3-dibromopropyl) phosphate
Trypan blue
Uracil mustard
Urea. N-ethyl-N-nitroso-
Urea, N-methyl-N-nitroso-
Vinyl chloride
Wartann, & salts, when present at concentrations of 0.3% or less

-------
 Environmental Protection Agency
                       Part 261, App. II
Haz-
ardous
waste
No.
U239
U200

U249

Chemical
abstracts No.

1330-20-7
50-55-5

1314-84-7

Substance

Xylene (I)
Yohimban-16-carboxyUc acid, 11.17-dimethoxy-18-[(3,4,5-tnmethoxybenzoyOoxy]-. methyl ester.
(3beta. 1 6beta, 1 /alpha, 1 8beta,20alpha)-
Zinc phosphide ZrvjPj, when present at concentrations of 10% or less
  1 CAS Number given lor parent compound only.

 (Approved by the Office of Management and Budget under control number 2050-0047)
 [45 FR 78529, 78541, Nov. 25, 1980]

  EDITORIAL NOTE: For FEDERAL REGISTER citations affecting § 261.33, see the List of CFR
 Sections Affected in the Finding Aids section of this volume.
 APPENDIX I—REPRESENTATIVE SAMPLING
                METHODS
    APPENDIX II—EP TOXICITY TEST
              PROCEDURES
  The methods and equipment used  for
sampling waste materials will vary with the
form and consistency of the waste materials
to be sampled. Samples collected using the
sampling protocols  listed  below, for  sam-
pling waste with properties similar to the in-
dicated materials, will be considered by the
Agency to be representative of the waste.

Extremely viscous liquid—ASTM Standard
  D140-70  Crushed or  powdered material—
  ASTM Standard D346-75 Soil or rock-like
  material—ASTM Standard  D420-69  Soil-
  like material—ASTM Standard D1452-65
Fly   Ash-like  material—ASTM  Standard
  D2234-76 [ASTM Standards are available
  from ASTM, 1916  Race  St., Philadelphia,
  PA 19103]
Containerized liquid wastes—"COLIWASA"
  described in "Test Methods for the Eval-
  uation of Solid Waste, Physical/Chemical
  Methods," " U.S. Environmental  Protec-
  tion Agency, Office of Solid Waste, Wash-
  ington, D.C.  20460.  [Copies may  be ob-
  tained from Solid Waste Information, U.S.
  Environmental Protection Agency, 26 W.
  St. Clair St., Cincinnati. Ohio 45268]
Liquid waste  in pits,  ponds, lagoons, and
  similar reservoirs.—"Pond  Sampler"  de-
  scribed in "Test  Methods for the Evalua-
  tion of Solid Waste, Physical/Chemical
  Methods." "

  This manual also  contains additional in-
formation on application of these protocols.
       A. Extraction Procedure (EP)

  1. A representative sample of the waste to
be tested (minimum size 100 grams) shall be
obtained using the methods specified in Ap-
pendix I or any  other method  capable  of
yielding a representative sample within the
meaning of Part 260. [For detailed guidance
on conducting the various aspects of the EP
see "Test Methods  for the Evaluation  of
Solid Waste, Physical/Chemical  Methods"
(incorporated by reference, see § 260.11).]
  2. The sample shall be separated into its
component liquid and solid phases using the
method  described  in  "Separation  Proce-
dure" below. If the solid residue "• obtained
using this method totals less than 0.5%  of
the original weight of the waste, the residue
can  be  discarded and  the operator shall
treat the liquid phase  as  the extract and
proceed immediately to Step 8.
  3. The solid material obtained from the
Separation Procedure shall be evaluated for
its particle size. If the solid material has a
surface area per gram of material equal to,
or greater than, 3.1 cm2 or passes through a
9.5 mm (0.375 inch) standard sieve, the oper-
ator shall proceed to Step  4. If the surface
area is smaller or the  particle size  larger
than  specified  above,  the solid  material
shall be  prepared for extraction  by  crush-
ing, cutting or grinding the material so that
  "•The percent  solids is determined  by
drying the filter pad at 80"C until it reaches
constant weight and  then calculating the
percent solids using the following equation:
  Percent solids =
  •These methods are  also  described  In
"Samplers and  Sampling  Procedures  for
Hazardous Waste Streams," EPA 600/2-80-
018. January 1980.
  (weight of pad + solid) - (tare weight of pad)

          initial weight of sample
X100

-------
Part 261, App. II
          40 CFR Ch. I (7-1-89 Edition)
it passes through a 9.5 mm (0.375 inch) sieve
or,  if the material is in a single  piece, by
subjecting  the material to the  "Structural
Integrity Procedure" described below.
  4. The solid material obtained in Step 3
shall be weighed and placed in an  extractor
with 16 times its weight of deionized water.
Do not allow the material to dry prior to
weighing. For purposes of this  test,  an ac-
ceptable extractor is one which will impart
sufficient agitation to the mixture to not
only prevent stratification  of  the  sample
and extraction fluid but also insure that all
sample surfaces  are  continuously  brought
into contact  with well mixed extraction
fluid.
  5. After the solid material and  deionized
water are placed in the extractor, the opera-
tor shall begin  agitation  and measure the
pH of  the  solution in the extractor.  If the
pH is greater than 5.0, the pH of  the solu-
tion shall  be decreased  to  5.0 ±  0.2  by
adding 0.5  N acetic acid. If the  pH is equal
to or less than 5.0, no acetic  acid should be
added. The pH of the solution shall be mon-
itored, as described below, during the course
of the extraction and if the pH rises above
5.2, 0.5N acetic acid shall be added to bring
the pH down to  5.0 ± 0.2. However, in no
event shall the  aggregrate amount of acid
added  to the solution exceed 4 ml of acid
per gram of solid. The mixture shall be agi-
tated for 24 hours and maintained  at  20°-
40°C (68°-104°F) during this time.  It  is rec-
ommended that the operator monitor  and
adjust the  pH during the course of the ex-
traction with a device such as the Type 45-A
pH Controller manufactured by Chemtrix,
Inc., Hillsboro, Oregon 97123 or its equiva-
lent, in conjunction with  a metering pump
and reservoir of 0.5N acetic acid. If such a
system  is   not  available,  the following
manual procedure shall be employed:
  (a) A pH meter shall be calibrated in ac-
cordance with the manufacturer's specifica-
tions.
  (b)  The  pH  of the  solution  shall  be
checked and, if  necessary, 0.5N acetic acid
shall  be manually  added to the extractor
until the pH reaches 5.0 ± 0.2.  The  pH of
the solution shall be adjusted at 15, 30 and
60  minute intervals,  moving to the next
longer interval if the pH does not have to be
adjusted more than 0.5N pH units,
  (c) The  adjustment procedure  shall  be
continued for at least 6 hours.
  (d) If at the end of the 24-hour extraction
period, the pH of the solution is not below
5.2 and the maximum amount of acid (4 ml
per gram of solids) has not been added, the
pH shall be adjusted to 5.0 ± 0.2  and the ex-
traction  continued for  an additional four
hours, during which the pH shall be adjust-
ed at one hour intervals.
  6. At the end of the 24 hour extraction
period,  deionized water shall be  added to
the extractor in an amount determined by
the following equation:
V = (20)(W)-16(W)-A
V=ml deionized water to be added
W=weight in grams of solid charged to ex-
   tractor
A=ml of 0.5N acetic acid  added during ex-
   traction
  7. The material in the extractor shall be
separated  into  its  component liquid  and
solid phases as described under "Separation
Procedure."
  8. The liquids resulting from Steps 2 and 7
shall be combined. This combined liquid (or
the waste itself if it has less than Vz percent
solids, as noted in Step 2) is the extract and
shall be analyzed for the presence of  any of
the contaminants specified in Table I of
§ 261.24  using the  Analytical Procedures
designated below.

           Separation Procedure

  Equipment:  A filter holder, designed for
filtration media having a nominal pore size
of 0.45 micrometers and capable of applying
a 5.3 kg/cm2 (75 psi) hydrostatic pressure to
the solution  being filtered, shall be used.
For   mixtures  containing   nonabsorptive
solids,  where separation  can be  effected
without imposing a 5.3 kg/cm2 pressure dif-
ferential,  vacuum filters employing  a  0.45
micrometers filter media can be used. (For
further guidance on  filtration equipment or
procedures see "Test Methods for Evaluat-
ing Solid Waste. Physical/Chemical  Meth-
ods"    incorporated    by   reference,   see
§260.11). Procedure:2
  (i)  Following  manufacturer's  directions.
the filter unit shall be assembled with a
filter  bed consisting  of  a  0.45  micrometer
filter  membrane. For difficult or slow to
filter mixtures a prefilter bed consisting of
the following prefilters  in increasing pore
size (0.65  micrometer membrane, fine glass
  'This procedure is intended to result in
separation  of the "free" liquid portion of
the waste from any solid matter having a
particle size  >0.45 ^m.  If the sample will
not filter,  various other separation  tech-
niques can be used to aid in the filtration.
As  described  above,  pressure  filtration is
employed to speed up the filtration process.
This does not alter the nature of the separa-
tion. If liquid does not separate during fil-
tration, the waste can be centrif uged. If sep-
aration occurs during  centrifugation, the
liquid  portion  (centrifugate)  is   filtered
through the 0.45 jim filter prior to becoming
mixed with the liquid portion of the waste
obtained from the initial filtration. Any ma-
terial that will not pass through the  filter
after  centrifugation  is considered  a  solid
and is extracted.

-------
Environmental Protection Agency
                        Part 261, App. II
fiber  prefilter, and  coarse  glass fiber pre-
filter) can be used.
  (ii) The waste shall be poured into the fil-
tration unit.
  (iii) The reservoir shall be slowly pressur-
ized until liquid begins to flow from the fil-
trate  outlet at which point the pressure in
the filter shall be immediately lowered to
10-15 psig.  Filtration  shall  be continued
until liquid flow ceases.
  (iv) The pressure shall be increased step-
wise in 10 psi increments to 75 psig and fil-
tration continued until flow  ceases or  the
pressurizing gas begins  to exit from the fil-
trate outlet.
  (v) The filter unit shall be depressurized,
the solid material removed and weighed and
then  transferred  to  the extraction appara-
tus, or, in the case of final filtration prior to
analysis, discarded. Do not allow the materi-
al retained on the filter pad to dry prior to
weighing.
  (vi) The liquid phase shall be stored at 4°C
for subsequent use in Step 8.

     B. Structural Integrity Procedure

  Equipment: A Structural Integrity Tester
having a 3.18 cm (1.25 in.) diameter hammer
weighing  0.33 kg  (0.73 Ibs.) and having a
free  fall of 15.24 cm (6 in.) shall be  used.
This device  is  available from  Associated
Design and Manufacturing Company,  Alex-
andria, VA 22314, as Part No. 125, or it may
be fabricated  to  meet the  specifications
shown in Figure 1.

-------
Part 261, App. II
40 CFR Ch. I (7-1-89 Edition)
                              f
                              15r25cm
                               (6")

                               i
                                          COMBINED
                                         " WEIGHT
                                          33Kg
                                           73lbl
/  /
    (3 1Scm»
   ' 11.25")
     SAMPLE
      /-ELASTOMERIC*
        SAMPLE HOLDER
                              33cm
                              (1.3")
                              94cm
                              137')
                                          T
                                          7 1cm
                                         i
  *ELASTOMERIC SAMPLE HOLDER FABRICATED OF
    MATERIAL FIRM ENOUGH TO SUPPORT THE SAMPLE
                     Figure  1
           COMPACTION TESTER

-------
Environmental Protection Agency
                                                                 Part 261, App. Ill
               Procedure
  1. The sample holder shall  be filled with
the material to be tested. If the sample of
waste is a large monolithic block,  a portion
shall be cut from the block having the di-
mensions of a 3.3 cm (1.3  in.) diameter x 7.1
cm (2.8 in.) cylinder.  For a fixated waste,
samples may be cast in the form of a 3.3 cm
(1.3 in.) diameter x 7.1 cm (2.8 in.) cylinder
for purposes of conducting this test. In such
cases, the  waste may be allowed to cure for
30 days prior to further testing.
  2. The sample holder shall be placed into
the Structural  Integrity  Tester,  then the
hammer shall be  raised to  its  maximum
height and dropped. This shall be repeated
fifteen times.
  3. The material shall be removed from the
sample holder, weighed,  and transferred to
the extraction apparatus for extraction.

Analytical Procedures for Analyzing Extract
                                            TABLE 1—ANALYSIS METHODS FOR ORGANIC
                                                CHEMICALS CONTAINED IN SW-846
  The  test methods  for analyzing the ex-
tract are as follows"
  1. For arsenic, barium, cadmium, chromi-
urn lead, mercury, selenium, silver, endrin,
lindane.  methoxychlor,   toxaphene,  2,4-
D[2,4-dichlorophenoxyacetic acid]  or 2,4,5-
TP [2,4,5-trichlorophenoxypropionic acid]:
"Test Methods for the Evaluation of Solid
Waste, Physical /Chemical  Methods" (incor-
porated by reference, see §  260.11).
  2. [Reserved]
  For all analyses, the methods of standard
addition shall be  used for  quantification of
species concentration.
[45 FR 33119. May 19.  1980, as amended at
46 FR 35247. July 7, 1981]

   APPENDIX HI-CHEMICAL ANALYSIS
             TEST METHODS
  Tables 1, 2, and 3 specify the appropriate
analytical procedures,  described  in  "Test
Methods for Evaluating Solid Waste, Physi-
cal/Chemical Methods,"  (incorporated  by
reference see 5 260 ID which shan be used
to determine whether a sample contains a
given Appendix VII or VIII toxic COnstitU-
ent.
  Table 1 identifies each Appendix VII or
VIII organic constituent along with the ap-
proved measurement method. Table 2  iden-
ufies the corresponding methods for  inor-
ganic species. Table 3 summarizes the con-
tents of SW-846 and supplies specific sec-
tion  and method numbers for sampling and
analysis methods.
  Prior  to  final  sampling  and  analysis
method selection the analyst should consult
the specific section or method described in
SW-846 for additional guidance on which of
the approved methods should be employed
for a specific sample analysis situation.
Compound
Acetonitrile
Acrolein 	 	
Acrylamide 	 	
Acrylonitrile 	
2-Amino-l-methylbenzene (o-Toluidine)
4-Amino-l-methylbenzene (p-Tolutdine)
Aniline 	
Benzene
Benz(a)anthracene 	 	
Benzo(a)pyrene 	 	
Benzotrichioride 	
Benzyl chloride 	 	
Benzo(b)f!uoanthene 	

Bis(2-chloroethvt)ether
Bis(2-chloroisopropyl)ether
Carbon bisulfide 	
Carbon tetrachloride .. .

Chlorinated biphenyls
Chlorinated dibenzo-p-dioxins 	
Chlorinated dibenzofurans 	
Chloroacetaldehyde
Chlorobenzene
Chloroform
Chioromethane
2-Chlorophenol 	
Chrysene 	

Cresol(s)
Cresylic Acid(s) 	
Dichlorobenzene(s) 	
Dichloroethane(s) 	

Dichlorophenoxyacetic acid
Dichloropropanol ..
2 4-Dimethylphenol. .
Dinitrobenzene 	
4,6-Dinitro-o-cresol 	 . . 	
2 4-Dinitrotoluene
2 6-Oinitrotoluene

2-Ethoxyethanol
Ethyl ether
Ethyiene dibromide 	
Ethyiene thiourea
Formaldehyde
Formic acid 	
Heptachlor 	
Hexachlorobenzene 	

Hexachloroethane
Hexachlorocyclopentadiene 	
Undane 	
Maleic anhydride 	
Methanol 	
Methomyl 	
Methyl ethyl ketone 	
Methyl isobutyl ketone 	

Napthoqumone
Nitrobenzene 	
4-Nitrophenol 	
Method
Numbers
8030, 8240
8030, 8240
8015, 8240
8030. 8240
8250
8250
8250
8020 8024
8100, 8250,
8310
8100, 8250,
8310
8120, 8250
8120, 8250
8100, 8250,
8010, 8240
8010, 8240
8010 8240
8015, 8240
8010 8240
8080 8250
8080 8250

8280
8010 8240
8020 8240
8010 8240
8010 8240
8040, 8250
8100, 8250
8100 8250
8040 8250
8040 8250
8010 8120
8010, 8240
8010 8240
8150 8250
8120 8250
8040 8250
8090 8250
8040 8250
8090 8250
8060 8250
8080 8250
8030 8240
8015 8240
8010 8240
8250 8330
8015 8240
8250
8080 8250
8120 8250
8120 8250
8010 8240
8120 8250
8080 8250
8250
8010 8240
8250
8015 8240
8015 8240
8100 8250
8090 8250
8090 8250
8040. 8240

-------
Port 261 r App. Ill
         40 CFR Ch. I (7-1-89 Edition)
TABLE  1—ANALYSIS METHODS  FOR ORGANIC
  CHEMICALS CONTAINED IN SW-846—Contin-

  ued
TABLE 1—ANALYSIS METHODS  FOR ORGANIC
  CHEMICALS CONTAINED IN SW-846—Contin-
  ued
Compound
2-Nitropropane 	
Paraldehyde (trimer of acetaldehyde) 	
Pentachlorophenol 	
Phenol 	
Phorate 	
Phosphorodithioic acid esters 	
Phthalic anhydride 	
2-Picoline . 	
Pyridine ... 	
Tetrachlorobenzene(s) 	
Tetrachloroethane(s) 	
Tetrachloroethene 	
Tetrachlorophenol 	
Toluene 	
Toluene diisocyanate(s)
Toluenediamine
2,4-Toluenediamine 	
2,6-Toluenediamme 	
3 4-Toluenediamine 	
Toxaphene. 	
Trichloroethane 	
Trichloroethene(s)
Trichtofofluoromethane
Thchlorophenol(s)
2 4 5-Trichlorophenoxy propionic acid
Thchloropfopane
Vinyl chloride 	
Vinvlidene chloride 	
Method
Numbers
8030, 8240
8015, 8240
8040, 8250
8040, 8250
8140
8140
8090, 8250
8090, 8250
8090, 8250
8120, 8250
8010. 8240
8010, 8240
8040, 8250
8020, 8024
8250
8250
8250
8250
8250
8080, 8250
8010, 8240
8010, 8240
8010, 8240
8040 8250
8150 8250
8010 8240
8010, 8240
8010. 8240
Compound
Xylene 	

Method
Numbers
8020 8240

                                            1 Analyne for phenanthrene and carbazole; if these are
                                          present in a ratio between 1.4:1 and 5:1 creosote should be
                                          considered present.


                                          TABLE 2—ANALYSIS METHODS FOR INORGANIC

                                               CHEMICALS CONTAINED IN SW-846
Compound
Antimony 	
Arsenic 	
Barium 	
Cadmium 	
Chromium 	
Chromium: Hexavalent 	
Lead 	
Mercury 	
Nickel 	
Selenium 	
Silver
Cyanides
Total Organic Halogen 	
Sulfides 	

First edition
method(s)
850
8.51
852
8.53
8.54
8.545, 8.546
8.547
856
857
858
8.59
860
855
8.66
867

Second
edition
method(s)
7040 7041
7060 7061
7080 7081
7090 7091
7190 7191
7195, 7196,
7197
7420 7421
7470 7471
7520 7521
7740 7741
7760 7761
9010
9020
9030

            TABLE 3—SAMPLING AND ANALYSIS METHODS CONTAINED IN SW-846

Title
Sampling of Solid Wastes . 	
Development of Appropriate Sampling Plans 	
Regulatory and Scientific Objectives 	
Fundamental Statistical Concepts 	
Basic Statistical Strategies 	
Simple Random Sampling 	
Stratified Random Sampling 	
Systematic Random Sampling 	
Special Considerations 	
Composite Sampling 	
Subsampling 	
Cost and Loss Functions 	
Implementation of Sampling Plan 	
Selection of Sampling Equipment 	
Composite Liquid Waste Sampler 	
Weighted Bottle 	
Dinoer 	
Thief 	
Trier 	
Auger 	
Scoop and Shovel 	 ,..,r 	 	 , 	 	
Selection of Sample Containers 	

Documentation of Chain of Custody 	 ,...„
Sample Labels 	

Field Log Book 	
Chain-of-Custody Record 	
First*
Section
No.
1 0
1 0
1 0-2
1 0-3
1 0-7



1 0-7



1.0-7

3.2.1
322
3.2.3
3.2.4
3.2.5
3.2.6
3.2.7
3.3
33
2.0
2.0-1
2.0-3
2.0-5
2.0-6
sdition
Method
No.




























Second
Section
No.
1 0
1 1
1 1 1
112
113
1131
1132
1133

1141
1142
1143
1 2
121
1211
1212
1213
1214
1215
1216
1.2 1 7
122
1 2 •?
1 3
131
1 32
133
1.3.4
edition
Method
No.





























-------
Environmental Protection Agency                          Part 261, App. Ill
      TABLE 3—SAMPLING AND ANALYSIS METHODS CONTAINED IN SW-846—Continued

Title
Sample Analysis Request Sheet 	
Samp'o O>IK«»ry tn 1 ahoratnry
Shipping of Samples 	
Receipt and Logging of Sample 	
Assignment of Sample for Analysis 	
Sampling Methodology 	 	
Containers , , 	
Tanks . •
Waste Piles 	
Landfills and Lagoons 	
Waste Evaluation Procedures 	
Characteristics of Hazardous Waste 	
Ignitability 	
Pensky-Martens Closed-Cup Method 	
Setaflash Closed-Cup Method
Corrosivity
Corrosivity Toward Steel
Reactivity
Extraction Procedure Toxicity
Extraction Procedure Toxicity Test 	
Method and Structural Integrity Test 	
Sample Workup Techniques 	 	
Inorganic Techniques
Acid Digestion for Flame AAS
Acid Digestion for Furnace AAS
Acid Digestion of Oil Grease or Wax..
Dissolution Procedure for Oil, Grease or Wax 	
Alkaline Digestion . . . 	
Organic Techniques 	
Separatory Funnel Liquid-Liquid Extraction 	
Continuous Liquid-Liquid Extraction ,
Acid-Base Cleanup Extraction
Soxhlet Extraction . 	
Sonication Extraction 	
Sample Introduction Techniques 	
Headspace 	 	
Purge-and-Trap 	
Inorganic Analytical Methods
Antimony Flame AAS
Antimony Furnace AAS 	
Arsenic Flame AAS 	
Arsenic Furnace AAS . 	
Barium, Flame AAS ... 	
Barium Furnace AAS
Cadmium Flame AAS
Cadmium Furnace AAS 	
Chromium Flame AAS 	
Chromium Furnace AAS 	
Chromium Hexavalent Coprecipitation 	
Chromium Hexavalent, Colorimetric 	
Chromium, Hexavalent Chelation 	 ~ 	
Lead, Flame AAS 	
Lead, Furnace AAS 	
Mercury Cold Vapor Liquid 	
Mercury Cold Vapor Solid 	
Nickel Flame AAS 	
Nickel Furnace AAS 	
Selenium Flame AAS 	
Selenium Gaseous Hydride AAS 	
Silver Flame AAS 	
Silver, Furnace AAS 	
Organic Analytical Methods 	
Gas Chromatographic Methods 	
Haiogenated Volatile Organics 	
Nonhalogenated Volatile Organics 	
Aromatic Volatile Organics 	
Acrolein Acrytonitrile Acetonrtrile 	
Phenols 	
First «
Section
No.
20-9
20-10
20-10
20-12
20-13
30
32-2
32-2
32-2
3 2-2


40
4 1
4 1
50
5 3
60
70
7.1, 7.2 7 5
7 4

849
i
i
849-9
8.49-8
80
80
90
90
80
80
80

80
80
80
80
80
80
80
80
80
80
80
80
80
80
80
8.0
8.0
8.0
80
80
80
8.0
8.0
8.0
8.0
8.0
8.0
8.0
8.0
80
8.0
80
8.0
Jditxm
Method
No.



























8458

9 1
901
884
886
885

882
883

850
8 50
851
851
852
8 52
853
853
854
854
8545
8.546
8.547
8.56
8.56
857
857
858
8.58
8.59
8.59
8.60
8.60


8.01
801
8.02
803
8.04
Secone
Section
No.
3 5
36
3 7
38
39
1 4
4 1
4 2
4 3
44
20
2 1
211
2 1 1
211
212
212
213
2 1 4

214
40
4 1
4 1
4 1
4 1

4 1
42
42
4 2
4 2
42
42
50
50
50
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
80
8 1
81
8 1
8 1
8 1
8.1
edition
Method
No.













1010
1020

1110



1310


3010
3020
3030

3060

3510
3520
3530
3540
3550

5020
5030

7470
7471
7060
7061
7080
7081
7130
7131
7090
7191
7195
7196
7197
7420
7421
7470
7471
7520
7521
7740
7741
7760
7761


8010
8015
8020
AO.'V)
8040

-------
Part 261, App. VII                                         40 CFR  Ch.  I (7-1-89 Edition)

        TABLE 3—SAMPLING AND ANALYSIS METHODS CONTAINED IN SW-846—Continued

Title
Phthalate Esters
Organochlonne Pesticides and PCBs
Nrtroaromatjcs and Cyclic Ketones 	
Poiynuclear Aromatic Hydrocarbons ....
Chlorinated Hydrocarbons
Organophosprtorus Pesticides
Chlorinated Herbicides
Gas Chromatographic/Mass Spectroscopy Methods (GC/MS) 	
GC/MS Volatiles 	 	
GC/MS Semi-Volatiles Packed Column 	
GC/MS Semi-Volatiles Capillary .
Analysis of Chlorinated Dioxins and Dibenzofurans
High Performance Liquid Chromatographic Methods (HPLC)
Polynuclear Aromatic Hydrocarbons
Miscellaneous Analytical Methods 	
Cyanide' Total and Amenable to Chlonnation 	
Total Organic Halogen (TOX) 	 	
Sulftdes .. . .
pH Measurement
Quality Control/Quality Assurance

Program Design 	
Sampling 	 	
Analysis 	 	
Data Handling 	 	

First e
Section
No.
80
80
8.0
80
80
80
80
8.0
8.0
8.0
80

80
80
8.0
8.0
8.0
80
50
100
100
10.0
10.0
10.0
100

xJJtion
Method
No.
806
808
809
8 10
8 12
822
840

824
825
827


8 10

855
866
867
52







Second
Section
No.
8 1
8 1
8 1
8 1
8 1
8 1
8 1
82
82
82
82
82
8 3
8 3
90
90
90
90
90
10 1
10 1
102
103
104
105

edition
Method
No.
8060
8080
8090
8100
8120
8140
8150

8240
8250
8270
8280

8310

9010
9020
9030
9040







  1 See specific metal.

[48 FR 15257, Apr. 8, 1983. as amended at 50 PR 2000, Jan.  14.  1985; 50 FR 42942. Oct. 23.
1985; 51 FR 5330. Feb. 13. 1986; 51 FR 6541. Feb. 25, 1986; 51 FR 37729, Oct. 24, 1986]
      APPENDIX IV—[RESERVED FOR
  RADIOACTIVE WASTE TEST METHODS]

APPENDIX  V—[RESERVED   FOR   INFEC-
     TIOUS WASTE TREATMENT SPECIFICA-
     TIONS]

      APPENDIX VI—[RESERVED FOR
            ETIOLOGIC AGENTS]

    APPENDIX VII—BASIS FOR LISTING
             HAZARDOUS WASTE
                                             EPA
                                           hazard-
                                             ous
                                            waste
                                             No.
  EPA
 hazard-
  ous
 waste
  No.
F001	


F002	
F003	
F004	
    Hazardous constituents for which listed
Tetrachloroethytene, methylene chloride  thchlor-
  oethylene,  1,1,1-trichloroethane,  carbon tetra-
  chloride. chlorinated fluorocarbons.
Tetrachkxoetnytene, methylene chloride,  trichlor-
  oethylene,  1,1,1-trichloroethane,  1.1,2-trichtor-
  oethane,  chtorobenzene,  1,1,2-trichloro-1,2,2-
  trichfluoroethane, ortno-dichlorobenzene. trich-
  (orofluoromethane.
NA
Cresols and cresylic acid, nitrobenzene.
                                           F005	
                                           F006	

                                           F007	
                                           F008	
                                           F009	
                                           F010	
                                           F011	
                                           F012	
                                           F019	
                                           F020	
F021	


F022	

F023	
             Hazardous constituents for which listed
Toluene, methyl ethyl  ketone, carbon disulfide,
  isobutanol, pyndine, 2-ethoxyethanol. benzene,
  2-nitropropane.
Cadmium, hexavalent chromium,  nickel, cyanide
  (complexed).
Cyanide (salts).
Cyanide (salts).
Cyanide (salts).
Cyanide (salts).
Cyanide (salts).
Cyanide (complexed).
Hexavalent chromium, cyanide (complexed).
Tetra- and  pentachlofodibenzo-p-dtoxins;  tetra
  and   pentachlorodi-benzofurans;   tri-   and
  tetrachkxophenols and their chkxophenoxy de-
  rivative acids, esters, ethers, amine and  other
  salts.
Penta- and  hexachlorodibenzo-p-dioxins; penta-
  and  hexachlorodibenzofurans;   pentachkxo-
  phervol and its derivatives.
Tetra-, penta-, and hexachtorodibenzo-p-dioxins;
  tetra-, penta-. and hexachkxodibenzolurans.
Tetra-, and  pentachlorodibenzo-fMjioxins;  tetra-
  and pentachlorodibenzolurans;  tri- and  tetra-
  chlorophenols and their chlorophenoxy deriva-
  tive acids, esters, ethers, amine and other  salts.

-------
 Environmental  Protection Agency
                                                                                 Part  261, App. VII
   EPA
 hazard-
   ous
  waste
   No.
 F024......
F026..

F027..




F028..




K001..
K002..
K003..
K004..
K005..
K006..
K007..
K008..
K009..

K010..
K011..
K013..
K014..
K015..

K016..
K017..


K018..

K01B..
      Hazardous constituents-lor which listed
Chtoromethane,  dichloromethane,  trichlorometh-
  ane.  carbon tetrachloride, cfiloroethylene, 1,1-
  dichloroethane,  1,2-dichloroethane,  trans-1-2-
  dichloroethylene,   1,1-dichtoroetnytene,   1,1,1-
  thchloroethane,  1,1.2-tnchkxoethane,  trichlor-
  oethylene,  1,1,1,2-tetra-chtoroethane,  1,1,2,2-te-
  trachloroethane,  tetrachloroethytene,   pentach-
  loroethane,  hexachloroethane, aHyl chloride (3-
  chloropropene),  dichloropropane,  dichloropro-
  pene,  2-chloro-1.3-butadiene,  hexachloro-1,3-
  butadiene,  hexachlorocyclopentadiene, hexach-
  lorocyclohexane, benzene, chlorbenzene, dich-
  lorobenzenes, 1,2,4-tnchkxobenzene, tetrachlor-
  obenzene,  pentachlorobenzene. hexachloroben-
  zene, toluene, naphthalene.
Tetra-.  penta-, and  tiexachkxodibenzo-p-dioxins;
  tetra-, penta-, and hexachlorodibenzofurans.
Tetra-,  penta-, and  hexachlorodibenzo-p-dioxins;
  tetra-, penta-, and hexachlorodibenzofurans; tri-,
  tetra-. and  pentachlorophenols and their chlorc-
  phenoxy derivative acids,  esters,  ethers, amine
  and other salts.
Tetra-,  penta-, and  hexachtorodibenzo-p-dioxins;
  tetra-, penta-, and hexachlorodibenzofurans; tri-,
  tetra-, and  pentachlorophenols and their chloro-
  phenoxy derivative acids,  esters,  ethers, amine
  and other salts.
Pentachlorophenol,  phenol,  2-chlorophenol,  p-
  chloro-m-cresol,  2,4-dimethylphenyl, 2,4-dinitro-
  phenol,   tnchlorophenols,   tetrachlorophenols,
  2,4-dinitrophenol, cresosote, chrysene,  naphtha-
  lene,     fluoranthene,     benzo(b)fluoranthene,
  benzo(a)pyrene,         indeno(1,2,3-cd)pyrene,
  benz(a)anthracene,  dibenz(a)anthracene, acen-
  aphthalene.
Hexavalent chromium, lead
Hexavalent chromium, lead.
Hexavalent chromium.
Hexavalent chromium, lead.
Hexavalent chromium.
Cyanide (complexed), hexavalent chromium.
Hexavalent chromium.
Chloroform,  formaldehyde,  methylene   chloride,
  methyl chloride, paraldehyde. formic acid.
Chloroform,  formaldehyde,  methylene   chloride,
  methyl chloride, paraldehyde, formic acid, chlor-
  oacetaldehyde.
Acrylonitrile, acetonitrile, hydrocyanic acid.
Hydrocyanic acid, acrylonitrile, acetonitrile.
Acetonitrile, acrylamide.
Benzyl chloride, chlorobenzene, toluene, benzo-
  trichloride.
Hexachlorobenzene, hexachkxobutadiene, carbon
  tetrachloride, hexachloroethane.  perchloroethy-
  lene.
Eptchkxonydrin,  chkyoethers   [bis(chloromethyl)
  ether  and bis  (2-chloroethyl) ethers],  tnchkxo-
  propane, dichkxopropanots
1,2-dichloroethane, trichloroethytene,  hexachloro-
  butadiene, hexachlorobenzene.
Ethytene dichkxide,  1,1.1-trichtoroethane,  1,1,2-
  trichtoroethane, tetrachkxoethanes (1,1.2,2-te-
  trachkxoethane and 1.1,1.2-tetrachloroethane),
  trichloroethytene,  tetrachtoroethyteoe,  carbon
  tetrachkxide, chloroform,  vtnyl  chloode. vinyli-
  dene chloride.
   EPA
 hazard-
   ous
  waste
   No.
                                                             K020	
K021..
K022..
K023..
K024..
K025..
K026..
K027..
K028..
K029..

K030..
K031..
K032..
K033..
K034..
K035..
K036..

K037..

K038..

K039..

K040..

K041..
K042..
K043..

K044..
K045..
K046..
K047..
K048..
K049..
K050..
K051..
K052..
K060..

K061..
K062..
K064..
K065..
K066..
K069..
K071..
K073..
                                                            K083..

                                                            K084..
                                                            K085..
                                                            K086..
                                                                  Hazardous constituents for which listed
 Ethylene  dichloride.  1,1,1-trichloroethane,  1,1,2-
   tnchkxoethane, tetrachloroethanes  (1,1,2,2-te-
   trachk>roethane and  1,1,1,2-tetrachloroethane),
   trichloroethytene,  tetrachkxoethylene,  carbon
   tetrachlonde,  chloroform, vinyl  chloride,  vinyli-
   dene chkxide.
 Antimony, carbon tetrachloride, chloroform.
 Phenol, tars (porycyclic aromatic hydrocarbons).
 Phthalic anhydride, maletc anhydndo.
 Phthalic anhydride, 1,4-naphthoquinone.
 Meta-dinitrobenzene, 2,4-dinitrotoluene.
 Paraldehyde, pyridines, 2-pkx>line.
 Toluene dnsocyanate, toluene-2, 4-diamine.
 1,1,1-tnchloroethane, vinyl chloride.
 1,2-dichkxoethane,    1,1,1-trichloroethane.  vinyl
   chloride, vinylidene chloride, chloroform.
 Hexachlorobenzene,  hexachkxobutadiene,  hexa-
   chloroethane,  1,1,1,2-tetrachloroethane, 1,1,2.2-
   tetrachkxoethane,  ethytene dichloride.
 Arsenic.
 Hexachlorocyclopentadiene.
 Hexachlorocyclopentadiene.
 Hexachlorocyclopentadiene.
 Creosote,  chrysene, naphthalene,  fluoranthene
   benzo
-------
Port 261, App.  VIII
                                                          40 CFR Ch. I (7-1-89 Edition)
  EPA
 hazard-
  ous
 waste
  No.
K087..
K088..
K090..
K091..
K093..
K094..
K095..

K096..

K097..
K098..
K099..
K100..
K101..
K102..
K103..
K104..

K105..

K106..
Kill..
K112..
     Hazard*
                      nts tor which listed
Phenol, naphthalene.
Cyanide (complexes).
CncomiufTi.
    Do.
Phthallc anhydride, maMc anhydride.
1.1.2-trichloroethane.    1.1.1,2-tetrachloroethane,
  1 .1 .2,2-tetrschtoroetnane.
1,2-dichloroethane,  1.1,1-trichloroethane,   1.1,2-
  trichloroethane.
Chlordane, heptachtor.
Toxaphene.
2,4-dichlorophenol, 2,4,6-trichlorophenol.
Hexavalent chromium, toad, cadmium.
Arsenic.
Arsenic.
Aniline, nitrobenzene, phenytonediamine.
Aniline,  benzene,  diphenylamine,  nitrobenzene,
  phenytonediamine.
Benzene, monochlorobenzene, dichkxobenzenes,
  2,4,6-tnchkxophenol.
Mercury.
2,4-Dinitrotoluene.
2,4-Toluenediamine,  o-toluidme,  p-toluidine, ani-
  line.
  EPA
 hazard-
  ous
 waste
  No.
K113..

K114..
K115..
K116..

K117..
K118..
K123..
K124..
K125..
K126..
K136..
     Hazardous constituents (or which listed
2,4-Toluenediamine,  otoluidine,  p-toluidine, ani-
  line.
2,4-Toluenediamine, o-toluidine, p-toluidine.
2,4-Toluenediamine.
Carbon tetrachloride, tetrachloroethylene,  chloro-
  form, phosgene.
Ethylene dibromide.
Ethylene dibromide.
Ethylene thiourea.
Ethylene thiourea.
Ethylene thiourea.
Ethylene thiourea.
Ethylene dibromide.
  N.A.—Waste is hazardous because it fails the test for the
characteristic of ignitability, corrosivity, or reactivity.

[46 FR 4619, Jan. 16, 1981, as amended at 46
PR  27477, May  20.  1981; 49 FR 5312,  Feb.
10, 1984;  50 FR  2000,  Jan. 14.  1985; 50 FR
42942. Oct. 23, 1985; 51 FR 5330, Feb. 13.
1986; 51  FR  6541,  Feb.  25, 1986;  51  FR
37729, Oct. 24, 1986; 54 FR  35421, Sept. 13.
1989]
                          APPENDIX VIII—HAZARDOUS CONSTITUENTS
Common name
Acetonitrito 	
Acetophenone 	
2-Acetytaminefluarone 	
Acetyl chloride 	
1-Acetyl-2-trxoufea 	
Acrotoin 	
Acrylamide 	
Acrytonitrile 	
Atlatonns 	
Aldicarb 	
Aldnn 	
Alryl alcohol 	
Aluminum phosphide 	
4-Aminobiphenyl 	
5-(Aminomethyl)-3-isoxazolol 	
4-Aminopyndine 	
Amrtrote 	
Ammonium vanadate 	
Aniline 	
Antimony 	 „ 	
Antimony compounds. N.O.S.1 	 „ 	
Aramtte 	
Arsenic 	 - 	 .... . .
Arsenic compounds, N.O.S.1 	 	
Arsenic acid 	
Arsenic pentoxide 	 ....
Arsenic thoxide 	
Chemical abstracts name
Same
Ethanone, 1-phenyl-
Acetamide N-9H-fluoren-2-yl-
Same 	
Acetamide N-(aminothioxomethyl)-
2-Propenal.
2-Propenamtde
2-Propenenitrile
Same
Propanal 2-methyl-2-(methylthio)- O-
[ (methylamino)carbonyl ]oxime .
1458-
Oimethanonaphthalene. 1,2,3,4,10.10-10-
hexachkxc-1 ,4.4a,5,8.8a-hexahydrc-.
(1alpna.4alpha,4abeta.5alpha,8alpha,
Babeta)-.
2-Propen- 1 -ol
Same 	
t1,1'-Biphenyl]-4-amine 	
3(2H)-lsoxazolone 5-(aminomethyi)-
4-Pyridinamine 	
1 H-1 ,2,4-Tnazol-3-amine
Vanadic acid, ammonium salt
Benzenamine
Same 	

Sulfurous acid. 2-chloroethyl 2-[4-(l 1-
dimethylethyl)phenoxy]-1 -methylethyl
ester.
Same

Arsenic acid HjAsGu 	
Arsenic oxide AsiOt
Arsenic oxide AsiOi 	
Chemical
abstracts No.
75-05-8
98-86-2
53-96-3
75-36-5
591-08-2
107-02-8
79_0$_1
107-13-1
1402-68-2
116-06-3
309-00-2

PDRRQ 71-P
92-67-1
97CO Qft_4
cn4_?4 R
R1-R9 A
7ftm ^*i-fi
CO Cn O
744Q.36-0

1 40-57-8
7440-38-2

7770004
nm-9R_9
1327-53-3
Hazardous
waste No.
U003
U004
U005
U006
P002
P003
U007
U009

P070
P004

POOS

	
P007



U012






pni9

-------
Environmental Protection Agency
Part 261, App. VIII
Common name

Azaserine 	

Barium compounds, N.O.S. ' 	
Barium cyanide 	
Benz[c]acridine 	
Benz[a]anthracene 	
Benzal chloride 	
Benzene 	 - 	
Benzenearsonic acid 	
Benzidine
BenzoCblfluoranthene 	
BenzoCjJfluoranthene .. . 	
Benzo[a]pyrene 	
p-Benzoquinone 	
Benzotrichloride . . 	
Benzyl chloride
Beryllium 	
Beryllium compounds, N.O.S.1 	
Bromoacetone
Bromoform 	
4-Bromophenyl phenyl ether . . . ..
Bnjcine 	
Butyl benzyl phthalate .. .
Cacodylic acid 	
Cadmium . . ..
Cadmium compounds N O S '
Calcium chromate
Calcium cyanide
Carbon disulfide
Carbon oxyfluoride 	
Carbon tetrachloride
Chloral
Chkxambucil 	
Chlordane
Chlordane (alpha and gamma isomers)
Chlorinated benzenes N O S '
Chlorinated ethane, N.O.S.1 	
Chlorinated fluorocarbons N.O.S.1 	
Chlorinated naphthalene N O.S.1 	
Chlorinated phenol N O S '
Chtomaphazin , , • ,, ,,
Chloroacetaldehyde
Chloroalkyl ethers N O S '
p-Chloroaniline
Chlorobenzene
Chkxobenzilate 	
p-Chloro-m-cresol 	
2-Chkxoethyl vinyl ether 	
Chloroform 	
Chtoromethyl methyl ether 	
beta-Chloronaphthalene . .
o-Chlorophenol
1 -(o-Chlorophenyl)thiourea
Chloroprene
3-Chloropropionitrile 	
Chromium
Chromium compounds N O S l
Ghrysene
Citrus red No 2 . 	
Coal tar creosote
Copper cyanide
Creosote
Oesol (Cresyllc acid)
Crotonaldehyde 	
Chemical abstracts name
Benzenamine 4 4'-carbonimidoyfbis[N N-di-
methyl.
L-Serine diazoacetate (ester)
Same

Same
Same 	
Same
Benzene (dichloromethyl)-
Same 	
Arsonic acid phenyl-
[1 1 '-Biphenyl]-4 4 '-diamine
Benz [ e ] acephenanthrylene
Same
Same 	
2,5-Cyclohexadiene-1 4-dione
Benzene (trichloromethyl)-
Benzene (chloromethyl)-
Same 	

2-Propanone 1 -bromo-
Methane, tribromo- 	
Benzene 1 -bromo-4-phenoxy-
Strychnidin-10-one 2 3-dimetho>cy-
1 2-Benzenedicarboxylic acid butyl phenyl-
methyl ester.
Arsinic acid dimethyl-
Same m

Chromic acid H^CrO* calcium salt
Calcium cyanide Ca(CN)z
Same
Carbonic difluoride 	
Methane tetrachloro-
Acetaldehyde trichloro-
Benzenebutanoic acid, 4-[bis(2-
chloroethyl)amino]-.
4 7-Methano-1H-indene 1 245678 8-oc-
tachloro-2,3.3a,4,7,7a-hexahydro-.





Naphthalenamine N N'-bis(2-chloroethyl)-
Acetaldehyde chloro-

Benzenamine 4-chloro-
Benzene chloro-
Benzeneacetic acid, 4-chloro-alpha-(4-chlor-
ophenyl)-alpha-hydroxy-, ethyl ester.
Phenol, 4-chloro-3-methyl- 	
Ethene, (2-chloroethoxy)- 	
Methane, trichloro- 	
Methane chloromethoxy- 	
Naphthalene, 2-chloro- 	
Phenol 2-chloro- 	
Thiourea (2-chlcrophenyl)- .
1 3-Butadiene 2-chloro-
Propanenitnle, 3-chloro- 	
Same 	

Same 	
2-Naphthalenol, 1-[(2,5-
dimethoxyphenyl)azo]-.
Same
Copper cyanide CuCN 	
Same 	 - 	 - 	
Phenol methyl-
2-Butenal 	
Chemical
abstracts No.
492-80-8
115-02-6
7440-39-3

542-62-1
225-51-4
56-55-3
98-37-3
71-43-2
98-05-5
92-87-5
205-99-2
20i-82-3
SC-32-8
106-51-4
98-07-7
100-44-7
7440-41-7

598-31-2
75-25-2
101-55-3
357-57-3
85-68-7
75-60-5
7440-43-9

13765-19-0
592-01-8
75-15-0
353-50-4
56-23-5
75-87-6
305-03-3
57-74-9






494-03-1
107-20-0

106-47-8
108-90-7
510-15-6
59-50-7
110-75-8
67-66-3
107-30-2
91-58-7
95-57-8
5344-82-1
126-99-8
542-76-7
7440-47-3

218-01-9
6358-53-8
8007-45-2
544-92-3

1319-77-3
4170-30-3
Hazardous
waste No.
U014
U015


P013
U016
U018
U017
U019

U021


U022
U197
U023
P028
P015

P017
U225
U030
P018

U136


U032
P021
P022
U033
U211
U034
U035
U036
U036





U026
P023

P024
U037
U038
U039
U042
U044
U046
U047
U048
P026

P027


U050


P029
U051
U052
U053

-------
Part 261,  App. VIII
                                                       40 CFR Ch. I (7-149 Edition)
              Common name
                                                    Chemical abstracts name
                                                                       Chemical
                                                                     abstracts No.
                                                               Hazardous
                                                               waste No.
Cyanides  (soluble
   N.O.S.'.
Cyanogen	
Cyanogen bromide..
Cyanogen chloride..
Cycasin	
salts  and  complexes)
 2-Cyck>hexyl-4,6-dinitrophenoL
 Cyclophosphamide	
 2,4-D	
 2,4-D, salts, esters..
 Daunomycin	
 ODD.

 DDE..

 DDT..
 Diallate
 Dibenz[a,h]acridine	
 Dibenz[a,jlacridine	
 Dibenz[a.h]anthracene	
 7H-Dibenzo[c,g]carbazole	
 Dibenzo[a,e]pyrene	
 Dibenzota.hlpyrene	
 Dibenzo(a,i]pyrene	
 1,2-Dibromo-3-chloropropane
 Dibutyl phthalate	
 o-Dichlorobenzene	
 m-Dichlorobenzene	
 p-Dichlorobenzene	
 Dichlorobenzene, N.O.S.1	
 3,3'-DtchlOfobenzidine	
 l,4-Dichloro-2-butene	
 Dtchlofodrftuoromethane	
 Dichloroethylene, N.O.S.1	
 1,1-Dichloroethylene	
 1,2-Dichloroethylene	
 Dtchloroethyi ether	
 Dichloroisopropyl ether	
 Dichloromethoxy ethane	
Dichloromethyl ether	
2,4-Dichlorophenol	
2,6-Dtehlorophenol	
Dichlorophertylarsine	
Dichloropropane, N.O.S.1..
Dtchkxopropanol, N.O.S.1.
Dichloropropene, N.O.S.1,
1,3-Dichloropropene	
Dieldrin	
1,2:3,4-Diepoxybutane..
Dietnytarsine	
1,4-DiethyteneoxkJe	
Dtethylhexyl phthalate..
N.N'-Diethythydrazine	
O,O-Dwthyl S-rnethyt dithiophospnate.
                                                    (methyl-ONN-
Ethanedinitrile	
Cyanogen bromide (CN)Br.
Cyanogen chloride (CN)CI.
beta-D-Glucopyranoside,
  azoxy)methyl.
Phenol, 2-cyclohexyl-4.6-dinitro-	
2H-1,3,2-Oxazaphosphorin-2-amine,
  bis(2-chloroethyl)tetrahydro-,  2-oxide.
Acetic acid, (2,4-dichlorophenoxy)-	
                                                             N.N-
Dwthyl-p-nttrophenyl phosphate	
Dtethyl phthalate	_	
O,O-Dtethy1 O-pyrazinyl phosphoro- thtoate.
                        5,12-Naphthacenedione, 8-acetyl-10-[(3-
                          amino-2,3,6-trideoxy-alpha-l-lyxo-
                          hexopyranosyl)oxy ] -7,8,9,10-tetrahydro-
                          6,8,11-trihydroxy-1-methoxy-, (8S-cis)-
                        Benzene,  1,1 '-(2.2-dichloroethylidene)bis[4-
                          chloro-.
                        Benzene,   1,1 '-(dichloroethenylidene)bis[4-
                          chloro-.
                        Benzene,                       1,1'-(2,2,2-
                          trichloroethylidene)bis[4-chloro-.
                        Carbamothioic acid,  bis(l-methylethyl)-, S-
                          (2,3-dichlorc-2-propenyl) ester.
                        Same	
                        Same	
                        Same	
                        Same	_	
                        Naphtho[1,2,3,4-detJchrysene	
                        Dibenzotb.deflchrysene	
                        Benzo[rst]pentaphene	
                        Propane, 1,2-dibromo-3-chloro-	
                        1,2-Benzenedicarboxylic acid, dibutyl ester	
                        Benzene, 1,2-dichloro-	
                        Benzene, 1,3-dichloro-	
                        Benzene, 1,4-dichlorc-	
                        Benzene, dichloro-	
                        [1,1 '-Biphenyl]-4,4'-diamine, 3,3'-dichlorc-	
                        2-Butene, 1,4-dichlorc-	
                        Methane, dichlorodifluoro-	
                        Dichloroethylene	
                        Ethene, 1,1-dichlorc-	
                        Ethene, 1,2-dichlrol-, (E)-	
                        Ethane, 1,Voxybis[2-chloro-	
                        Propane, 2,2'-oxybis[2-chloro-	
                        Ethane,       1 ,r-[methylenebis(oxy)]bis[2-
                          chloro-.
                        Methane, oxybisCchloro-	
                        Phenol, 2,4-dichloro-	
                        Phenol, 2,6-dichloro-	
                        Arsonous dichloride, phenyl-	
                        Propane, dichloro-	
                        Propanol, dichloro-	
                        1-Propene, dichloro-	
                        1-Propene, 1,3-dichloro-	
                        2,7:3.6-Dimethanonaphth[2,3-b]oxirene,
                          3,4,5,6,9,9-hexachloro-1a,2,2a,3,6,6a,7.7a-
                          octahydro-,
                          (laatpha,2beta,2aalpha,3oeta,6beta,
                          6aa)pha,7bela,7aalpha>-.
                        2,2'-Bioxirane	
                        Arsine, diethyl-	
                        1,4-Dk>xane	
                        1,2-Benzenedicarboxylic  acid,   bis<2-etfiyl-
                          hexyl) ester.
                        Hydrazine,  1,2-diethyl-	
                        Phosphorodithioc acid, O.O-dietriyl S-methyl
                          ester.
                        Phosphoric acid, dwlhyl 4-nrtropnenyl ester....
                        1^-BenzenedicarboxyMc acid, diethyl ester	
                        Phosphorothkx: add,  O.O-diethyl  O-pyra-
                          zinyl ester.
   460-19-5
   506-68-3
   506-77-4
14901-08-7

   131-89-5
    50-18-0

    94-75-7

20830-81-3
                                                    72-54-8

                                                    72-55-9

                                                    50-29-3

                                                  2303-16-4

                                                   226-36-8
                                                   224-42-0
                                                    53-70-3
                                                   194-59-2
                                                   192-65-4
                                                   189-64-0
                                                   189-55-9
                                                    96-12-8
                                                    84-74-2
                                                    95-50-1
                                                   541-73-t
                                                   106-46-7
                                                 25321-22-6
                                                    91-94-1
                                                   764-41-0
                                                    75-71-8
                                                 25323-30-2
                                                    75-35-4
                                                   156-60-5
P030

P031
U246
P033
P034
U058

U240
U240
U059
                    U060
                   U061

                   U062
                   U063
                   U064
                   U066
                   U069
                   U070
                   U071
                   U072
                   U073
                   U074
                   U075
                                                   108-60-1
                                                   111-91-1

                                                   542-88-1
                                                   120-83-2
                                                    87-65-0
                                                   696-28-6
                                                26638-19-7
                                                26545-73-3
                                                26952-23-8
                                                   542-75-6
                                                    60-57-1
                                                 1464-53-5
                                                  692-42-2
                                                  123-91-1
                                                  117-81-7

                                                 1615-80-1
                                                 3288-58-2

                                                  311-45-5
                                                   84-66-2
                                                  297-97-2
                   U078
                   U079
                   U025
                   U027
                   U024

                   P016
                   U081
                   UOB2
                   P036
                   U084
                   P037
                   U065
                   P038
                   U108
                   U028

                   U086
                   U067

                   P041
                   uoee
                   P040

-------
Environmental Protection Agency
Part 261, App. VIII
Common name
Diethylstilbesterol 	
Dihydrosafrole 	
Diisopropylfluocophosphate (DFP) 	
Dimethoate 	
3 S'-Dimethoxybenzidine
p-Dimethylaminoazobenzene 	
7 12-Dimethylbenz[a]anthracene 	
3 3'-Oimethylb6nzidine
Dimethylcarbamoyl chloride
1 1 -Dimethylhydrazine 	
1 2-Dimethylhydrazme 	
alpha alpha-Dimethylphenethylamine
2 4-Dimethylphenol 	
Dimethyl phthalate 	
Dimethyl sulfate
Dinitrobenzene N.O.S. ' 	
4 6-Dinitro-o-cresol 	
4 6-Dimtro-o-cresol salts 	
2 4-Dinitrophenol 	
2 4-Dinitrotoluene 	
2 6-Dinitrotoluene
Dinoseb 	
Di-n-octyl phthalate 	
Diphenylamine 	
1 2-Diphenylhydrazine 	
Di-n-propylnrtrosamine... .
DisuHoton 	
Dithiobiuret 	
Endosulfan 	
Endothall 	
Endrin 	
Endrin metabolites 	
Epichlorohydnn
Epinephnne .
Ethyl carbamate (urethane) 	
Ethyl cyanide ....
Ethylenebisdithiocarbamic acid
Ethylenebisdithiocarbamic acid saJts and
esters.
Ethylene dibromide
Ethylene dichloride
Ethylene glycol monoethyl ether

Ethylene oxide 	
Ethytenethiourea 	 	
EthylkJene dichloride . . . . 	
Ethyl metnacrylate ...
Ethyl methanesurfonate
Famphur
FHioranthene
Fluorine
FtuoroaoGtamide
Fkxxoacebc acid, sodium salt 	
Formaldehyde 	
Formic acid . .
Grycidylalderiyde
HaJomethanes. N.O.S. ' 	
Chemical abstracts name
Phenol, 4,4'-(1 2-diethyl-1 2-ethenedryl)bis-
(E)-.
1,3-Benzodioxole, 5-propyl-
Phosphorofluoridic acid bis(1-methylethyl)
ester.
Phosphorodithioic acid, O,O-dimethyl S-[2-
(methylamino)-2-oxoethyl] ester.
[1 1 '-Biphenyl]-4 4'-diamine 3 3'-dim©thoxy-
Benzenamme N N-dimethyl-4-(phenylazo)-
Benztalanthracene, 7 12-dimethyl-
[1 1'-Biphenyl]-4 4'-diamine 3 3'-dimethyl-
Carbamic chloride dimethyl-
Hydrazine, 1,1-dimethyl-
Hydrazine 1 2-dimethyl-
Benzeneethanamine alpha alpha-dimethyl-
Phenol, 2,4-dimethyl-
1 2-Benzenedicarboxylic acid dimethyl ester
Sulfuric acid dimethyl ester
Benzone, dinitro-
Phenol 2-methyl-4 6-dinitro-

Phenol, 2,4-dinitro-
Benzene 1 -methyl-2 4-dinrtro-
Benzene 2-methyl-1 3-dinitro-
Phenol, 2-(1-methylpropyl)-4 6-dinitrc-
1 2-Benzenedicarboxylic acid dioctyl ester
Benzenamine, N-phenyl-
Hydrazine. 1 ,2-diphenyt-
1 -Propanamine N-nitroso-N-propyl-
Phosphorodithioic acid O O-diethyl S-C2-
(ethylthio)ethyl] ester.
Thioimidodicarbonic diamide C(HiN)C(S)]3N
H.
6,9-Methano-2 4 3-benzodioxathiepin
6,7,8,3,1 0,1 0-hexachloro-1 ,5,5a,6,9,9a-
hexahydro-, 3-oxide.
7-Oxabicyclo[2 2 1 ] heptane- 2 3-dicarboxylic
acid.
2 7'3 6-Dimethanonaphth[2 3-b]oxirene
3,4,5,6,9,9-hexachloro-1a,2,2a,3,6,6a,7,7a-
octa-hydro-.
(1 aalpha,2beta,2abeta,3alpha,6aipna,
6abeta,7beta,7aalpha)-.
Oxirane (chloromethyl)-
1 ,2-BenzenedKjl 4- [ 1 -hydroxy-2-
(methylamino)ethyl]-, (R)-.
Carbamic acid, ethyl ester
Propanenrtrile .
Carbamodithioic acid 1 2-ethanediylbis-

Ethane, 1 2-dibromo-
Ethane 1 2-dichloro-
Ethanol 2-ethoxy-
Aziridine
Oxirane 	
2-lmidazolidinethione 	
Ethane, 1,1-dichloro- ....
2-Propenoic acid 2-methyl- ethyl ester
Methanesulfonic acid ethyl ester
Phosphorothioic acid O-[4-
t(dimethylamino)surfonyl]phenyl] O.O-di-
methyl ester.
Same.
Same
Acetamide 2-fluoro-
Acetic acid, fluoro-, sodium salt
Same
Same
Oxiranecarboxyaldehyde

Chemical
abstracts No.
56-53-1
94-56-6
55_91_4
60-51-5
1 19-90-4
60-11-7
57-97-6
1 1 9-93-7
79 44 7
57 14-7
540-73-8
122-09-8
105-67-9
131_11_3
77-78-1
25154-54-5
534-52-1

51-28-5
121-14-2
606-20-2
88-85-7
117-84-0
122-39-4
122-66-7
621-64-7
298-04-4
541-53-7
115-29-7
145-73-3
72-20-8

106-89-8
51-43-4
51-79_6
107-12-0
1 1 1 -54-6

106-93-4
107-06-2
110-80-5
151-56-4
75-21-8
96-45-7
75-34-3
97-63-2
62-50-0
52-85-7
206-44-0
7782-41-4
640-19-7
62-74-8
50-00-0
64-18-6
765-34-4

Hazardous
waste No.
U089
U090
P043
P044
U091
U093
U094
U095
U097
U098
U099
P046
U101
U102
U103

P047
P047
P048
U105
U106
P020
U017

U109
U111
P039
P049
P050
P088
P051
P051
U041
P042
U238
P101
U114
U114
U067
U077
U359
P054
U115
U116
U076
U118
U119
P097
U120
P056
P057
P058
U122
U123
U126


-------
Part 261, App. VIII
40 CFR Ch. I (7-1-89 Edition)
Common name
Heptachlor 	

Heptachlor epoxkte (alpha beta, and
gamma isomers).
Hexachlorobutadiene 	
Hexachtorocydopentadiene
Hexachlorodib6nzo-p-dioxins 	
Hexachkxodibenzoturans
Hexachloro6thane 	
Hexachlorophene

Hexaethyl tetrapnosphate


Hydrogen fluoride

Indenod 23-cd]pyrene
Isobutyl alcohol
laodrin
Isosufrol*
Kepone 	
Lasiocarpine
Lead 	
Lead compounds, N.O.S. ' 	
Lead acetate 	
Lead phosphate .
Lead subacetate
Lindane
Maleic anhydride 	
Mateic hydrazide 	
Malononitrile 	
Melphalan 	 _ 	
Mercury 	
Mercury compounds, N.O.S.1 	
Mercury fulminate 	
Methacrylonrtrile 	
Methapyrilene 	
Methomyl 	
Methoxychkx 	
Methyl bromide 	
Methyl chloride 	
Methyl chlorocarbonate 	
Methyl chloroform
3-Methytchotantfirene 	
4,4'-Methytenebis(2-chloroaniline)
Methylene bromide
Methytene chloride
Methyl ethyl ketone (MEK)
Methyl ethyl ketone peroxide
Methyl hydrgzine
Methyl iodide
Methvt iaocvanate 	
Chemical abstracts name
4,7-Methano-1 H-indene, 1 ,4,5,6,7,8,8-hep-
tachloro-3a,4,7,7a-tetrahydro-.
2,5-Methano-2H-indeno[ 1 ,2-b]oxirene,
2,3,4,5,6.7,7-heptachloro-1 a,1 b,5,5a,6,6a-
hexa- hydro-,
(1aalpha,1bbeta,2alpha,5alpha,5abeta,
6beta,6aalpha)-.
Benzene, hexachloro- 	
1 ,3-Butadiene, 1,1,2,3,4,4-hexachloro- 	
1 3-Cyclopentadiene, 1 ,2,3,4,5,5-hexachkxo- .


Ethane, hexachloro- 	
Phenol, 2,2'-methylenebis[3,4,6-trichloro- 	
1-Propene 1 1 2,3,3,3-hexachloro-
Tetraphosphoric acid, hexaethyl ester 	
Same 	
Hydrocyanic acid
Hydrofluoric acid 	
Hydrogen sulfide H?S.
Same 	
1-Propanol, 2-methyl- 	
1,4,5,8-
Oimethanonaphthalene, 1,2,3,4.10.10-
hexachloro-1 ,4,4a,5,8,8a-hexahydro-,
(1 alpha,4alpha,4abeta,5beta,8beta,8abeta)-.
1 ,3-Benzodioxole, 5-(1-propenyl)- 	
1 ,3,4-Metheno-2H-cyclobuta[cd]pentalen-2-
one, 1,1a,3,3a,4,5,5,5a,5b,6-
decachlorooctahydro-.
2-Butenoic acid 2-methyl- 7-[[2 3-dihydroxy-
2-(1-methoxyethyl)-3-methyl-1-
oxobutoxy]methyl]-2,3,5,7a-tetrahydro-lH-
pyrrolizin-1-yl ester,
[ 1 S-[ 1 alpha(Z),7(2S' ,3R*),7aalpha]J-
Same

Acetic acid lead(2+) salt
Phosphoric acid lead(2+) salt (2'3)
Lead bis(acetato-O)tetrahydroxytri-
Cyclohexane 12345 6-hexachloro-
(1 alpha,2alpha,3beta,4alpha,5alpha,6beta)-.
2 5-Furandione
3 6-Pyridazinedione 1 2-dihydro-
Propanedinitrile
L-Phenylalanine 4-[bis(2-
chloroethyl)aminol]-.
Same

Fulmiruc acid mercury(2-f-) salt
2-Propenenitrile 2-methyl-
1 2-Ethanediamine N N-dimethyl-N'-2-pyri-
dinyl-N'-(2-thieny1methyl)-.
Ethanimidothioic acid N-
[[(methylamino)carbonyl]oxy]-, methyl
ester.
Benzene 1,1 '-(2,2,2-
trichloroethylidene)bis[4-methoxy-.
Methane bromo- 	
Methane chloro- 	
Carbonochkxidic acid, methyl ester 	
Ethane 1 1 1-trichloro- 	
Benz[j]aceanthrylene, l,2-dihydro-3-mettiyl-...
Benzenamine 4 4'-methylenebis[2-chk>ro- 	
Methane dibromo- 	
Methane dichloro- 	

2-Butanone peroxide 	
Hydrazine methyl- 	
Methane iodo- 	
Methane, isocvanato- 	
Chemical
abstracts No.
76-44-8
1024-57-3

11B-74-1
87-«8-3
77-47.4


67-72-1
70-30-4
1888-71-7
757-58-4
302-01-2
74-90-8
7664-39-3
7783-06-4
193-39-5
76-83-1
465-73-6
120-58-1
143-50-0
303-34-1
7439-92-1

301-04-2
7446-27-7
1335-32-6
58-69-9
108-31-6
123-33-1
109-77-3
148-82-3
7439-97-6

628-86-4
126-98-7
91-80-5
16752-77-5
72-43-5
74-83-9
74-87-3
79-22-1
71-55-6
56-49-5
101-14-4
74-95-3
75-09-2
78-93-3
1338-23-4
60-34-4
74-88-4
624-83-9
Hazardous
waste No.
P059


U127
U128
U130


U131
U132
U243
P062
U133
P063
U134
U135
U137
U140
P060
U141
U142
4143


U144
U145
U146
U129
U147
U148
U149
U150
U151

P065
U152
U155
P066
U247
U029
U045
U156
U99A
U157
U158
IJOAft
ijonn
in «;o
IJtfin
Pom
U11A
POB4

-------
Environmental Protection Agency
Part 261, App. VIII
Common name
2-Methyllactonitrile
Methyl methacrylate
Methyl methanesulfonate

Metnylthiouracil 	
Mrtomycin C 	
MNNG 	
Mustard gas 	
Napntha'^ne 	 	
1 4-Naphthopuinone
alpha-Naphthylamine
beta-Naphthytamin6
alpha-Naphthylthiourea
Nickel 	
Nickel compounds N.O.S. ' 	
Nickel carbonyl . .
Nickel cyanide
Nicotine 	
Nicotine salts 	
Nitric oxide
p-Nitroaniline
Nitrobenzene
Nitrogen dioxide
Nitrogen mustard
Nitrogen mustard hydrochloride salt 	
Nitrogen mustard N-oxide 	
Nitrogen mustard N-oxide hydro- chloride
salt
Nitroglycerin
p-Nitrophenol
2-Nrtropropane 	 	
Nitrosamines N O S l
N-Nitrosodi-n-butyiamine 	
N-Nitrosodiethanoiamine
N-Nitrosodiethylamine
N-Nitrosodimethylamine
N-Nitrosc-N-ethylurea
N-Nitrosomethylethylamine
N-Nitroso-N-methylurea
N-Nrtroso-N-methylurethane 	
N-Nitrosomethylvinylamine
N-Nitrosomorpholine
N-Nitrosonomicotine
N-Nitrosopiperidine
N-Nitrosopyrrolidine
N-Nitrososarcosine
5-Nrtro-o-toluidine
Octamethylpyrophosphoramide
Osmium tetroxide
Paraktehyde ...
Parathton 	
Perrtachkyobenzene 	
PentBchlorodibenzo-p-dioxins
Pentachkxodibenzofurans
Pentachkxoethane
Pantachloronitrobenzene (PCNB)
Pontachkxophenol
Phenacetin 	
Phenol
Phenyteoediamine
Phenytmercury acetate..
Phenvtthkxjrea 	
Chemical abstracts name
Propanenitrile, 2-hydroxy-2-methyl-
2-Propenoic acid, 2-methyl- methyl ester
Methanesulfonic acid methyl ester
Phosphorothioic acid O O-dimethyl O-(4-ni-
trophenyl) ester.
4(1H)-Pyrimidinone, 2,3-dihydro-6-methyt-2-
thioxo-.
Azinno[2',3':3,4]pyrrolo[1,2-a]indole-4 7-
dione,
$-amino-8-[ [(aminocarbonyt)oxy]methyl]-
1 ,1 a,2.8,8a,8b-hexahydro-8a-methoxy-5-
methyl-, [1aS-
(laalpha,8beta,8aalpha,8balpha)]-.
Guanidine, N-methyl-N'-nitro-N-nitrosc-
Ethane, 1,1'-thiobis[2-chloro- 	
Same 	
1 ,4-Naphthalenedione 	
1 -Naphthalenamine 	
2-Naphthalenamine
Thiourea 1 -naphthalenyl-
Same 	

Nickel carbonyl Ni(CO)., (T-4>-. .
Nickel cyanide Ni(CN), 	
Pyridme, 3-(1-methyl-2-pyrrolidinyl)-, (Si-

Nitrogen oxide NO
Benzenamine 4-nitro-
Benzene. nitro- 	
Nitrogen oxide NO» 	
Ethanamine, 2-chloro-N-(2-chtoroethyl)-N-
methyl-.
Ethanamine, 2-chloro-N-(2-chloroethyl)-N-
methyl-, N-oxide.
1 ,2,3-Propanetriol, trinitrate...
Phenol. 4-nitro- 	
Propane, 2-nitro- 	

1-Butanamme, N-butyl-N-nitroso- 	
Ethanol, 2,2'-(nitrosoimino)bis-
Ethanamine, N-ethyl-N-nitroso-
Methanamine, N-methyl-N-mtroso- 	
Urea, N-ethyl-N-nitroso- 	
Ethanamine N-methyl-N-nitroso-
Urea N-methyl-N-nitroso-
Carbamic acid, methylnitroso-, ethyl ester 	
Vinylamine, N-methyl-N-mtroso- 	
Morpholine, 4-nitroso- 	
Pyridine, 3-(1-nitroso-2-pyrrolidinyl)-, (S)- 	
Piperidine, 1-nitroso- 	
Pyrrolidine 1 -nitroso-
Glycine N-methyl-N-nitroso-
Benzenamine 2-methyl-5-nitro- 	
Oiphosphoramide octamethyl- 	
Osmium oxide OsO4, (T-4)- 	
1 ,3,5-Thoxane, 2,4,6-trimethyV 	
Phosphorothioic acid, O,O-diethyl O-(4-nitro-
phenyt) ester.
Benzene, pentachloro- 	


Ethane pentachkxo- 	
Benzene, pentachkxonitro- 	
Phenol pentachloro-
Acetamide, N-<4-ethoxyphenyl)- 	
Same
Benzenediamine
Mercury, (acetato-O)phenyl- 	
Thiourea. phenvl- 	
Chemical
abstracts No.
75-86-5
80-62-6
66-27-3
298-00-0
56-04-2
50-07-7
70-25-7
505-60-2
91-20-3
130-15-4
134-32-7
91-59-8
86-88-4
7440-02-0

1 3463-39-3
557-19-7
54-11-5

10102-43-9
100-01-6
98-95-3
10102-44-0
51-75-2

126-85-2

55-63-0
100-02-7
79-46-9
35576-91 -1D
924-16-3
1116-54-7
55-18-5
62-75-9
759-73-9
10595-95-6
684-93-5
615-53-2
4549-40-0
59-89-2
16543-55-8
100-75-4
930-55-2
13256-22-9
99-55-8
152-16-9
20816-12-0
123-63-7
56-38-2
608-93-5


76-01-7
82-68-8
87-86-5
62-44-2
108-95-2
25265-76-3
62-38-4
103-85-5
Hazardous
waste No.
P069
U162

P071
U164
U010
U163

U165
U166
U167
U168
P072


P073
P074
P075
P075
P076
P077
U169
P078




P081
U170
U171

U172
U173
U174
P082
U176

U177
U178
P084


U179
U180

U181
P085
P087
U182
P089
U183


U184
U185
Sea F027
U187
U188

P092
P093

-------
Part 261 r App. VIII
40 CFR Ch. I (7-1-89 Edition)
Common name
Phosgene 	

Phorale 	
Phthalic acid esters N.O S ' 	
Phthalic anhydnde 	

Polychlonnated biphenyls N O S ' 	

Potassium silver cyanide 	

1 3-Propane sultone 	
n-Propylamine

Propylene dichloride

Propytthiouracil .. ..
Pyridine
Reserpine 	
Resorcinol . 	
Saccharin .. 	
Saccharin salts 	
Safroto
Selenium 	
Selenium compounds, N.O.S.1 	
Selenium dioxide 	
Selenium sulfide 	
Selenourea 	 	
Silver 	
Silver compounds, N.O.S.1 	
Silver cyanide 	
Silvex (2,4.5-TP)
Sodium cyanide 	
Streptozotocin
Strontium sulfide2 	
Strychnine 	
Strychnine salts 	
TCDD 	
1 ,2,4,5-Tetrachlorobenzene 	
Tetrachlorodibenzo-p-dioxins 	
Tetrachkxodibenzoturans 	
Tetrachloroethane, N.O.S.1 	
1,1,1,2-Tetrachloroethane 	
1,1,2,2-Tetrachloroethane 	
Tetrachloroethylene 	
2,3,4,6-Tetrachlorophenol 	
Tetraethyldithiopyrophosphate 	
Tetraethyl lead 	
Tetraethyl pyrophosphate 	
Tetranrtromethane 	
Thallium 	
Thallium compounds, N.O.S.1 	
Thallic oxide 	
ThallMjm(l) acetate 	
Thallkim(l) carbonate 	 . .
ThaJltum(l) chloride 	
Thallkjm(l) nitrate 	
Thallium selenrte 	
ThalliumO) sulfate 	
Thioacetamide 	
Thtofanox 	
Truomethanol
Thtophenol
Thio«u»mk-Jirt>fl7irta
Thkxirea 	
Chemical abstracts name
Carbonic dichlonde 	
Same 	
Phosphorodithioic acid, O,O-diethyl S-
[(ethylthio)methyl] ester.
1 ,3-lsobenzofurandione 	
Pyridine 2-methyl- . .

Potassium cyanide K(CN) . ...
Argentate(l-), bis(cyano-C)-, potassium 	
Benzamide 3,5-dichloro-N-(1 1 -dimethyl-2-
propynyl)-.
1 ,2-Oxathiolane, 2,2-dioxide 	
1 -Propanamine .... 	
2-Propyn-1-ol
Propane 1 2-dichloro- 	
Azindine 2-methyl-
4(1H)-Pynmidmone 2,3-dihydro-6-propyl-2-
thioxo-.
Same
Yohimban- 1 6-carboxylic acid, 111 7-dimettv
oxy-18-[(3,4,5-tnmethoxybenzoyl)oxy]-
smethyl ester,
(3beta, 1 6beta, 1 7alpha, 1 8beta,20alpha)-.
1,3-Benzenediol...
1 2-Benzisothiazol-3(2H)-one 1 1 -dioxide

1 3-Benzodioxole 5-(2-propenyl)-
Same 	

Selenious acid 	
Selenium sulfide SeS?
Same
Same

Silver cyanide Ag(CN)
Propanoic acid 2-(2 4 5-trichlorophenoxy)-
Sodium cyanide Na(CN)

C[(methylnitrosoamino)cart>onyl]amino]-.
Strontium sulfide SrS
Strychnidin- 1 0-one

DibenzoCb e][1 4]dioxin 237 8-tetrachloro-
Benzene, 1 ,2,4,5-tetrachloro-


Ethane tetrachlorc- N O S
Ethane 1 1 1 2-tetrachloro-
Ethane 112 2-tetrachloro-
Ethene tetrachloro-
Phenol 234 6-tetrachloro-
Thiodiphosphohc acid tetraethyl ester
Plumbane tetraethyl-
Diphosphoric acid tetraethyl ester
Methane tetranitrc-
Same 	 	

Thallium oxide TlaOa
Acetic acid thallium) 1 +) salt
Carbonic acid dithallium(l+) salt
Thallium chloride TO
Nitric acid thalhum(i +) salt
Selenious acid dithallium(l+) salt 	
Sulfunc acid dithalhum(1 +) salt 	
Ethanethioamide .... 	
2-Butanone 3,3-dimethyl-1-(methytti-.io)-, 0-
C(methylamino)cartX)ny1] onme.
Methanethiol 	
Benzenethiol 	
Hydrazinecarbothioarnide 	
Same 	
Chemical
abstracts No.
75-44-5
7803-51-2
298-02-2

85-44-9
109-06-8

151-50-8
506-61-6
23950-58-5
1120-71-4
107-10-8
107-19-7
78-87-5
75-55-8
51-52-5
110-86-1
50-55-5
108-46-3
81-07-2

94-59-7
7782-49-2

7783-00-8
7488-56-4
$30-10_4
7440-22-4

506-64-9
93-72-1
143-33-9
18883-66—4
1314-96-1
57-24-9

1746-01-6
95-94-3


25322-20-7
630-20-6
79-34-5
127-18-4
58-90-2
3689-24-5
76-00-2
107-49-3
509-14-8
7440-28-0

1314-32-5
563-68-8
6533-73-9
7791-12-0
10102-45-1
12039-52-0
7446-18-6
62-55-5
39196-18-4
74-93-1
108-98-5
79-19-6
62-56-6
Hazardous
waste No.
P095
P096
P094

U190
U191

P098
P099
U192
U193
U194
P102
U083
P067

U196
U200
U201
U202
U202
U203


U204
U205
P103


P104
San Pn?7
P106
i looft
P107
P108
P108

U207



U208
U209
ll?in
See F027
P1OQ
P110
P1 1 1
P119


PI n
11914
I IO1C
MOlft
l IQ17

P11C
1I91A
P045
1 1-tCQ
PO1^
P1 16
U219

-------
Environmental Protection Agency
Part 261, App. IX
Common name
Thiram 	 	
Toluene 	
Toluenediamine 	 	 	
Toluene-2,4-diamme 	
Toluene-2 6-diamine 	
Toloene-3 4-diamine 	
Toluene diisocyanate 	
o-Toluidine 	
o-Toluidine hydrochloride
p-Toluidine 	
Toxaphene 	 	 	
1 2 4-Trichlorobenzene 	
1 1 2-Tnchloroethane .
Trichloroethylene 	
Trichloromethanethiol 	 	
Trichloromonofluoromethane 	
2 4 5-Trichlorophenol 	
2 4 6-Trichlorophenol
245-T
Trichloropropane, N.O.S. '.. . . ..
1 2 3-Trichloropropane 	 	
O O O-Triethyl phosphorothioate 	
1 3 5-Trinitrobenzene
Tris(1-aziridinyl)phosphine sulfide
Tris(2 3-dibromopropyl) phosphate .. . .
Trypan blue 	
Uracil mustard
Vanadium pentoxide
Vinyl chloride 	
Warfarin 	
Warfarin
Warfarin salts when present at concentra-
tions less than 0.3%.
Warfarin salts when present at concentra-
tions greater than 0.3%.
Zinc cyanide
Zinc phosphide
Zinc phosph'd^ , , , , , , 	

Chemical abstracts name
Thioperoxydicarbonic diamide [(H,N)C(S)]jS
2, tetramethyk
Benzene, methyl- . .
Benzenediamine, ar-methyl-
1,3-Benzenediamme, 4-methyl-
1 3-Benzenediamine 2-methyl-
1 2-Benzenediamine 4-methyl-
Benzene 1 3-diisocyanatomethyl-
Benzenamine 2-methyl-
Benzenamine 2-methyl- hydrochloride
Benzenamine, 4-methyl-
Same 	
Benzene, 1 ,2,4-tnchloro-
Ethane 1 1 2-trichlorc-
Ethene tnchloro-
Methanethiol trichloro-
Methane, trichlorofluoro-
Phenol, 2,4,5-trichloro- .
Phenol 2 4 6-trichloro-
Acetic acid (2 4 5-trichlorophenoxy)-

Propane, 1,2,3-trichloro-
Phosphorothioic acid, O,O O-triethyl ester
Benzene 1 3 5-trinitro-
Azindine 1 1 ' 1 "-phosphinothioylidynetris-
1-Propanol 2 3-dibromo- phosphate (3*1)
2.7-Naphthalenedisulfonic acid 3 3'-[(3 3'-di-
methyl[1,1'-biphenyi]-4,4'-dry1)bis, when present at con-
centrations of 10% or less.
Chemical
abstracts No.
137-26-8
108-68-3
25376-45-8
95-80-7
823-40-5
496-72-0
26471-62-5
95-53-4
636-21-5
106-49-0
8001-35-2
120-82-1
79-00-5
79-01-6
75-70-7
75-69-4
95-95-4
88-06-2
93-76-5
25735-29-9
96-18-4
126-68-1
99-35-4
52-24-4
126-72-7
72-57-1
66-75-1
1314-62-1
75-01-4
81-81-2
81-81-2


557-21-1
1314-84-7
1314-84-7

Hazardous
waste No.
U244
U220
U221



U223
U328
U222
U353
P123

U227
U228
P118
U121
See F027
See F027
See F027



U234

U235
U236
U237
P120
U043
U248
P001
U248
P001
P121
P122
U249

  1 The abbreviation N.O.S. (not otherwise specified) signifies those members of the general class not specifically listed by
name in this appendix.
  'At 53 FR 43884, Oct. 31, 1988. Appendix VIII was amended by removing the listing: "Stontium sulfide • * * Same • * *
1314—ge—1.". The amendatory instruction in that document was incorrect and the Environmental  Protection Agency will
publish a correction document in the FEDERAL REGISTER at a later date.


[53 FR 13388, Apr. 22, 1988, as amended at 53 FR 43881, Oct. 31, 1988]

            APPENDIX IX—WASTES EXCLUDED UNDER §§ 260.20 AND 260.22
                 TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES
Facility
Arco Building
Products.
Arco Chemical
Co.
BBC Brown
Boveri, Inc.
Address
Sugar creek,
Ohio.
Miami, FL 	

Sanford, FL 	

Waste description
Dewatered wastewater treatment sludge (EPA Hazardous Waste No. F019) generated from
the chemical conversion coating of aluminum after August 1 5, 1 986.
Dewatered wastewater treatment sludge (EPA Hazardous Waste No. FO19) generated from
the chemical conversion coating of aluminum after April 29, 1986.
Dewatered Wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from
electroplating operations after October 17, 1986.

-------
Part 261, App. IX                               40 CFR Ch. I (7-1-89 Edition)
         TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
Facility
Bommer
Industries
Inc..
Capitol
Products
Corp.
Capitol
Products
Corporation.
Chamberlian-
Feathertite,
Inc.
Cincinnati
Metropolitan
Sewer
District
Continental
Can Co.
Dover Corp.,
Nome Div.
Eli Lilly and
Company..




EPA's Mobile
Incineration
System.







EPA's Mobile
Incineration
System
(MIS).
















Address
Landrum, SC....


Harrisburg, PA..


Kentland, IN 	


Hot Springs,
AR.

Cincinnati, OH..



Olympia, WA ....

Tulsa OK

Clinton,
Indiana..




Denney Farm
Site;
McDowell,
MO.






McDowell. MO..



















Waste description
Wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from their
electroplating operations and contained in evaporation ponds #1 and #2 on August 12.
1987.
Dewatered wastewater treatment slugdges (EPA Hazardous Waste No. FO19) generated
from the chemical conversion coating of aluminum after September 12, 1986.

Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F019) generated from
the chemical conversion coating of aluminum after November 17, 1986.

Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F019) generated from
the chemical conversion coating of aluminum after July 16, 1986.

Sluiced bottom ash (approximately 25,000 cubic yards) contained in the South Lagoon, on
September 13, 1985 which contains EPA Hazardous Waste Nos. F001, F002, F003, F004,
and F005.

Dewatered wastewater treatment sludges (DPA Hazardous Waste No. FO19) generated from
the chemical conversion coating of aluminum after September 12, 1986.
Dewatered wastewater treatment sludge (EPA Hazardous Waste No. FO06) generated from
their electroplating operations after April 29, 1986.
Incinerator scrubber liquids, entenng and contained in their onsite surface impoundment, and
solids settling from these liquids originating from the burning of spent solvents (EPA
Hazardous Waste Nos. F002, F003, and F005) contained in their onsite surface impound-
ment and solids retention area on August 18, 1988 and any new incinerator scubber
liquids and settled solids generated in the surface impoundment and and disposed of in
the retention are after August 12, 1988.
Process wastewater, rotary kiln ash, CHEAE media, and other solids (except spent activated
carbon) (EPA Hazardous Waste Nos. F020, F022. F023, F026, F027, and F028) generated
during the field demonstration of EPA's Mobile Incinerator at the Denney Farm Site in
McDowell, Missouri, after July 25, 1985, so long as: (1) The incinerator is functioning
properly: (2) a grab sample is taken from each tank at wastewater generated and the EP
leachate values do not exceed 0.03 ppm for mercury, 0.14 ppm for selenium, and 0.68
ppm for chromium; and (3) a grab sample is taken from each drum of soil or ash
generated and a core sample is collected from each CHEAF roll generated and the EP
leachate values of daily composites do not exceed 0.044 ppm in ash or CHEAF media for
mercury or 0.22 ppm in ash or CHEAF media for selenium.
Kiln ash, cyclone ash, separator sludge, and filtered wastewater (except spent activated
carbon) (EPA Hazardous Waste No. F027) generated during the treatment of cancelled
pesticides containing 2,4,5-T and Silvex and rotated materials by the EPA's Mobile
Incineration System at the Denney Farm Site in McDowell, Missouri after March 11, 1988,
so long as:
(1) the incinerator is monitored continuously and is in compliance with operating
permit conditions. Should the incinerator fail to comply with the permit conditions
relevant to the mechanical operation of the incinerator, RCB must test the
residues generated during the run when the failure occurred according to the
requirements of Conditions (2) through (5), regardless of whether or not the
demonstration in Condition (6) has been made;
(2) Four grab samples of wastewater must be composited from the volume of
filtered wastewater collected after each eight hour run and, prior to disposal, the
composite samples analyzed for the EP toxic metals, nickel, and cyanide. If
arsenic, chromium, lead, and silver EP leachate test results exceed 0.44 ppm;
barium levels exceed 8.8 ppm; cadmium and selenium levels exceed 0.09 pom;
mercury levels exceed 0.02 ppm; nickel levels exceed 4.4 ppm; or cyanide levels
exceed 1.8 ppm, the wastewater must be retreated to achieve these levels or
must be disposed in accordance with Subtitle C of RCRA. Analyses must be
performed according to SW-846 methodologies.

-------
Environmental Protection Agency                          Part 261, App. IX
         TABLE 1— WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
Facility






































































Address






































































Waste description
(3) One grab sample must be taken from each drum of kiln ash generated dunng
each eight hour run; all grabs collected dunng a given eight hour run must then
be composited to form one composite sample. One grab sample must be taken
from each drum of cyclone ash generated dunng each eight hour run; all grabs
collected during a given eight hour run must then be composited to form one
composite sample. A composite sample of four grab samples of the separator
sludge must be collected at the end of each eight hour run. Prior to the disposal
of the residues from each eight hour run, an EP leachate test must be performed
on these composite samples and the leachate analyzed for the EP toxic metals,
nickel, and cyanide. If arsenic, chromium, lead, and silver EP leachate test results
exceed 1.6 ppm; banum levels exceed 32 ppm, cadmium and selenium levels
exceed 0.3 ppm; mercury levels exceed 0.07 ppm; nickel levels exceed 16 ppm;
or cyanide levels exceed 6.5 ppm, the wastes must be retreated to achieve these
levels or must be disposed in accordance with Subtitle C of RCRA. Analyses
must be performed according to SW-846 methodologies.
(4) RGB must generate, pnor to disposal of residues, verification data from each
eight hour run for each treatment residue (i.e., kiln ash, cyclone ash, separator
sludge, and filtered wastewater) to demonstrate that the maximum allowable
treatment residue concentrations listed below are not exceeded. Samples must
be collected as specified in conditions (2) and (3). Analyses must be performed
according to SW-846 methodologies. Any residues which exceed any of the
levels listed below must be retreated or must be disposed as hazardous.
Solid and sludge concentrations must not exceed the following levels:
Aldnn — 0.015 ppm
Benzene — 9.7 ppm
Benzo(a)pyrene — 0.43 ppm
Benzo(b)fluoranthene — 1.8 ppm
Chlordane — 0.37 ppm
Chloroform — 5.4 ppm
Chrysene — 170 ppm
Dibenz(a,h)anthracene — 0.083 ppm
1 ,2-Dichloroethane— 4.1 ppm
Dichloromethane — 2.4 ppm
2,4-Dichlorophenol — 480 ppm
Dichlorvos— 260 ppm
Disutfaton— 23 ppm
Endosulfan I — 310 ppm
Fluorene — 120 ppm
lndeno(1,2,3-od)pyrene — 330 ppm
Methyl parathion — 210 ppm
Nitrosodiphenytamine — 130 ppm
Phenanthrene — 150 ppm
Polychlorinated biphenyls — 0.31 ppm
Tetrachloroethylene — 59 ppm
2.4,5-TP (silvex)— 110 ppm
2,4,6-Trichlorophenol — 3.9 ppm.
And detected wastewater concentrations do not exceed the following levels:
Acetone — 35 ppm
Aldnn— 0.000018 ppm
Benzene — 0.044 ppm
Benzo(a)pyrene — 0.000027 ppm
Benzo(b)fluoranthene — 0.00018 ppm
Biphenyl — 15 ppm
Bis-2-ethylhexyl phthalate — 6.2 ppm
Chlordane — 0.00024 ppm
Chlorobenzene — 8.8 ppm
Chloroform— 0.052 ppm
Chrysene — 0.0018 ppm
2,4-D — 3.5 ppm
Dibenz(a,h)anthracene — 0.000006 ppm
Dichloromethane — 0.042 ppm
1 ,3-Dtchkxobenzene — 34 ppm
1 ,4-Dichlorobenzene — 0.66 ppm
1 ,2-Dichlorobenzene — 26 ppm
1 ,2-Dichloroethane — 0.044 ppm
2,4-Dichlorophenol— 0.88 ppm
Dichlorvos — 0.78 ppm
Diethyl phthalate — 4,400 ppm
Disulfaton — 0.016 ppm
Endosulfan I— 0.020 ppm

-------
Port 261, App. IX                               40 CFR Ch. I (7-1-89 Edition)
         TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
Facility

























































Address

























































Waste description
Ethyl benzene — 35 ppm
Fluoranthene — 1.8 ppm
Fluorene — 0.018 ppm
lndeno(1,2,3-cd)pyrene — 0.0018 ppm
Isophorone — 62 ppm
Methyl chloride— 35 ppm
Methyl parathion— 0.099 ppm
Naphthalene — 80 ppm
Nitrosodiphenylamine — 0.063 ppm
Pentachlorophenol — 8.8 ppm
Phenanthrene — 0.018 ppm
Phenol — 8.8 ppm
Polychlonnated biphenyls — 0.000072 ppm
Pyrene— 35 ppm
Tetrachloroethylene — 0.059 ppm
2,3,4, 6-Tetrachlorophenol — 8.8 ppm
Toluene — 88 ppm
2,4,5-TP (silvex)— 0.088 ppm
1 ,2,4-Trichlorobenzene — 6.2 ppm
2,4,6-Tnchlorophenol— 0.018 ppm
2,4,5-Trichlorophenol — 35 ppm
2,4,5-Tnchlorophenoxyacetic acid — 0.88 ppm
Xylene — 619 ppm;
(5) RGB must generate, prior to disposal of residues, verification data from each
eight hour run for each treatment residue (i.e., kiln ash, cyclone ash, separator
sludge, and filtered wastewaler) to demonstrate that the residues do not contain
tetra-, penta-, or hexachlorodibenzo-p-dtoxins or furans at levels of regulatory
concern. Samples must be collected as specified in conditions (2) and (3). The
TCOD equivalent levels for solids must be less than 5 ppt and for wastewater the
levels must be below 0.002 ppt. Any residues with detected dioxins or furans in
excess of these levels must be retreated or must be disposed as acutely
hazardous. Method 8290, a high resolution gas chromatography and high resolu-
tion mass spectroscopy (HRGC/HRMS) analytical method, must be used. For
tetra- and penta-chlorinated dioxin and turan homologs, the maximum practical
quantitation limit must not exceed 15 ppt for solids and 120 ppq for wastewaters.
For hexachlorinated dioxin and furan homologs, the maximum practical quantita-
tion limit must not exceed 37 ppt for solids and 0.3 ppt for wastewaters;
(6) The test data from conditions (1), (2), (3), (4) and (5) must be kept on file by
RGB for inspection purposes and must be compiled, summarized, and submitted
to the Assistant Administrator for Solid Waste and Emergency Response by
certified mail on a monthly basis and when the treatment of the cancelled
pesticides and related materials is concluded. The testing requirements for
conditions (2), (3), (4), and (5) will continue until RGB provides the Assistant
Administrator with the results of four consecutive batch analyses for the peti-
tioned wastes, none of which exceed the maximum allowable treatment residue
concentrations listed m these conditions and the Assistant Administrator notifies
RGB that the conditions have been lined. All data submitted will be placed in the
RCRA docket.
(7) RGB must provide a signed copy of the following certification statement when
submitting data in response to the conditions listed above: "Under civil and
cnminal penalty of law for the making or submission of false or fraudulent
statements or representations, I certify that the information contained in or
accompanying this document is true, accurate, and complete. As to the (those)
identified section(s) of this document for which I cannot personalty verify its (their)
accuracy, I certify as the Agency official having supervisory responsibility for the
persons who, acting under my direct instructions, made the verification that this
information is true, accurate and complete."

-------
Environmental  Protection Agency                                         Part 261, App. IX

              TABLE 1— WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
    Facility
                  Address
                                                 Waste description
Envmte
  Corporation.
Canton, Ohio;
  Harvey,
  Illinois;
  Thomaston,
  Connecticut;
  and York,
  PA.
Falconer
  Glass
  IndusL, Inc.
Florida
  Production
  Engineering
  Company.
General Cable
  Co.
General
  Electric
  Company.
General
  Motors
  Corp.,
  Fisher Body
  Division.
Falconer. NY.
Daytona
  Beach,
  Florida.

Murxae, IN.
Shreveport
  Louisiana

Eryria, OH	
Dewatered  wastewater sludges (EPA Hazardous Waste No.  F006) generated from electro-
  plating operations; spent cyanide plating solutions  (EPA  Hazardous  Waste No.  F007)
  generated from electroplating operations; plating bath residues from the bottom of plating
  baths (EPA Hazardous Waste No. F008) generated from electroplating  operations where
  cyanides  are used in the  process; spent stripping and  cleaning bath solutions (EPA
  Hazardous Waste No. F009) generated from electro-plating  operations where cyanides are
  used in the process; spent cyanide solutions from salt bath pot cleaning (EPA Hazardous
  Waste No.  F011) generated from Metal heat  treating operations;  quenching  wastewater
  treatment sludges (EPA Hazardous Waste No. F012) generated from metal heat treating
  where cyanides are used in the process; wastewater treatment sludges (EPA Hazardous
  Waste No. F019) generated from the chemical  conversion coating of aluminum  after
  November 14,  1986. To ensure that hazardous constituents are not present in the waste
  at levels  of regulatory concern,  the facility must implement  a contingency testing program
  for the petitioned wastes.  This testing program must meet the following conditions for the
  exclusions to be valid:
(1) Each batch of treatment residue  must be representatively sampled and tested using the
  EP Toxicity test for arsenic, banum, cadmium, chromium, lead, selenium, silver, mercury,
  and nickel. If the extract concentrations for chromium,  lead, arsenic, and silver exceed
  0.315 ppm; banum levels exceed 6.3  ppm;  cadmium and selenium exceed 0.063 ppm;
  mercury exceeds 0.0126 ppm; or nickel levels  exceed 2.205 ppm,  the waste must be re-
  treated or managed and disposed  as a hazardous waste under 40  CFR  Parts  262 to 265
  and the permitting standards of 40 CFR Part 270.
(2) Each batch of treatment residue must be tested for reactive and teachable cyanide. If the
  reactive cyanide levels exceed 250 ppm or leachable cyanide levels (using the EP Toxicity
  test without acetic acid adjustment) exceed  1.26  ppm, the waste  must be re-treated or
  managed and disposed as a hazardous waste under 40 CFR Parts  262 to 265 and the
  permitting standards of 40 CFR Part 270.
(3) F.ach batch of waste must  be tested for the total content  of specific organic toxicants. If
  the total  content of anthracene exceeds 76.8 ppm,  1,2-diphenyl hydrazine exceeds 0.001
  ppm, methylene chlonde exceeds 8.18 ppm, methyl ethyl  ketone  exceeds 326 ppm, n-
  nitrosodiphenylamine exceeds 11.9 ppm, phenol exceeds 1,566 ppm, tetrachloroethylene
  exceeds 0.188  ppm, or tnchloroethylene exceeds 0.592 ppm. the waste must be managed
  and disposed as a hazardous waste under 40 CFR Parts 262 and 265 and the permitting
  standards of 40 CFR Part 270.
(4)  A grab  sample  must be collected from each batch to  form one monthly composite
  sample which must be tested using GC/MS analysis  for the  compounds listed in #3 above
  as well   as the  remaining  organics on the  priority pollutant  list (See 47  FR  52309
  November 19, 1982, for a list of the priority pollutants.)
(5) The data from conditions 1-4 must be kept on file at the  facility for inspection purposes
  and must be compiled, summarized, and submitted  to the  Administrator by certified mail
  semi-annually.  The Agency  will  review this  information and if  needed will propose to
  modify or withdraw the exclusion.
The organics testing descnbed in conditions 3 and 4 above are not required until six months
  from the  date  of promulgation.  The Agency's  decision  to conditionally exclude  the
  treatment residue generated from the wastewater treatment systems  at these facilities
  applies only to  the wastewater and solids treatment systems  as they presently exist as
  described in the delisting petition. The  exclusion does not apply to the proposed process
  additions  described in  the petition as recovery including crystalizaton, electrolytic metals
  recovery,  evaporative recovery, and ion exchange.
Wastewater treatment  sludges from the  filter press  and  magnetic  drum separator  (EPA
  Hazardous Waste No. F006) generated from  electroplating  operations after July 16,  1986.

This is a one-tame  exclusion. Wastewater treatment  sludges (EPA  Hazardous  Waste  No.
  F006) generated from electroplating operations and  contained in four on-site trenches on
  January 23, 1987.

Dewatered  wastewater treatment sludges (EPA  Hazardous  Waste Nos. F006  and K062)
  generated from electroplating operations and steel finishing operations after  October 24,
  1966. This exclusion does not apply to sludges  in  any on-site impoundments as  of  this
  date.
Wastewater treatment sludges (EPA Hazardous Waste  No  F006) generated from electroplat-
  ing  operations  and  contained  in four on-site treatment  ponds  on August  12,  1987.

The residue generated from the  use of the Chemfix* treatment process on sludge (EPA
  Hazardous Waste No.  F006) generated from electroplating operations and contained in
  three  on-site surface impoundments on November 14, 1986. To assure that stabilization
  occurs, the following conditions apply to this exclusion:

(1) Mixing ratios shall be  monitored continuously to assure consistent treatment

-------
Part 261, App. IX                               40 CFR Ch. I (7-1-89 Edition)
         TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
Facility












Goodyear Tire
and Rubber
Co..
Gould Inc

Hanover Wire
doth
Division.
Hotston Army
Ammunition
Plant
Imperial

Clevite.
International
Minerals
and
Chemical
Corporation.
Kay-Fries, Inc ...


Keymark Corp..


Keymark Corp..


Lederie
Laborato-
ries..


Lincoln Plating
Company.
Loxcreen

Company,
Inc.
Marquette
Electronics
Incorporat-
ed..
Martin
Marietta
Aerospace.
Merck 4
Company,
Incorporat-
ed.
Maytag
Company.

Metropolitan
wOWOf
District of
Greater
Cincinnati.
Address












Randleman,
NC..

McConnels-
ville, OH.
Hanover,
Pennsylva-
nia.
Kingsport,
Tennessee.

Salem IN


Terre Haute,
Indiana.



Stoney Point,
NY.

Fonda, NY


Fonda, New
York.

Pearl River,
NY..



Lincoln, NE 	

Hayti MO



Milwaukee,
Wisconsin..


Ocala, Florida...


Elkton,
Virginia.


Newton, IA 	


Cincinnati, OH ..




Waste description
(2) One grab sample of the treated waste shall be taken each hour as it is pumped to the
holding area (cell) from each trailer unit At the end of each production day, the grab
samples from the individual trailer units will be composited and the EP toxicrty test will be
run on each composite sample. It lead or total chromium concentrations exceed 0.315
ppm or if nickel exceeds 2.17 pom, in the EP extract the waste will be removed and
retreated or disposed of as a hazardous waste.
(3) The treated waste shall be pumped into bermed cells which are constructed to assure
that the treated waste is identifiable and retrievable (i.e.. the material can be removed and
either disposed of as a hazardous waste or retreated if conditions 1 or 2 are not met).
Failure to satisfy any of these conditions would render the exclusion void. This is a one-time
exclusion, applicable only to the residue generated from the use of the Chemfix* treatment
process on the sludge currentty contained in the three on-site surface impoundments.
Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from
electroplating operations.

Wastewater treatment sludge (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations after November 27, 1985.
Dewatered fitter cake (EPA Hazardous Waste No. F006) generated from electroplating
operations after August 15, 1966.

Dewatered wastewater treatment sludges (EPA Hazardous Waste Nos. F003, F005, and
K044) generated from the manufacturing and processing of explosives and containing
spent non-halogenated solvents after November 14, 1986.
Solid resin cakes containing EPA Hazardous Waste No. F002 generated after August 27

1985, from solvent recovery operations.
Spent non-halogenated solvents and still bottoms (EPA Hazardous Waste No. F003)
generated from the recovery of n-butyr alchohol after August 15, 1986.



Biological aeration lagoon sludge and finer press sludge generated after September 21,
1984, which contain EPA Hazardous Waste Nos. F003 and F005 as well as that disposed
of in a holding lagoon as of September 21, 1984.
Wastewater treatment sludge (EPA Hazardous Waste No. F019) generated from chemical

conversion coating of aluminum after November 27, 1985.
Wastewater treatment sludges (EPA Hazardous Waste No. F019) generated from the
chemical conversion coating of aluminum and contained in an on-site impoundment on
August 12, 1987. This is a one-time exclusion.
Spent non-halogenated solvents and still bottoms (EPA Hazardous Waste Nos. F003 and
F005) generated from the recovery of the following solvents: Xytene, acetone, ethyt
acetate, ethyl ether, methyl isobutyf ketone, n-butyl alcohol, cydohexanone, methanol,
toluene, and pyridine after August 2, 1988. Excusion applies to primary and secondary
filter press sludges and compost soils generated from these sludges.
Wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations after November 17, 1986.
Dewatered wastewater treatment sludoes (EPA Hazardous Waste No F019J Generated from

the chemical conversion coating of aluminum after Jury 16, 1986.

Wastewater treatment sludge (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations. This exclusion was published on April 20, 1989.


Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from
electroplating operations after January 23, 1987.

One-time exclusion for fly ash (EPA Hazardous Waste No. F002) from the incineration of
wastewater treatment sludge generated from pharmaceutical production processes and
stored in an on-site fly ash lagoon. This exclusion was published on May 12, 1989.

Wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations and wastewater treatment sludges (EPA Hazardous Waste No. F019)
generated from the chemical conversion coating of aluminum November 17, 1986.
Sluiced bottom ash sludge (approximately 25,000 cubic yards), contained in the North
Lagoon, on September 21, 1984, which contains EPA Hazardous Wastes Nos F001
F002, F003, F004, and F005.



-------
Environmental Protection Agency                                        Part 261, App. IX

              TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
   Facility
                  Address
                                                Waste description
Michelin Tire
  Corp.
Monroe Auto
  Equipment

North
  American
  Philips
  Consumer
  Electronics
  Corporation.
Pamcor C, Inc.

Plastene
  Supply
  Company.
Reynolds
  Metals
  Company.
Siegel-Robert,
  Inc.
Square D
  Company.
Syntex
  Agribusi-
  ness.
Sandy
  Springs,
  South
  Carolina.
Paragould, AR.
Greenville,
  Tennessee.
Las Piedras.
  PR.
Portageville,
  Missouri.

Sheffield, AL...
St. Louis, MO.

Oxford, Ohio...

Springfield,
  MO.
Dewatered wastewater treatment sludge (EPA Hazardous Wastes No. F006) generated from
  electroplating operations after November 14, 1986.
Wastewater treatment sludge (EPA Hazardous Waste No. F006) generated from electroplat-
  ing  operations  after vacuum filtration after November 27,  1985. This exclusion does not
  apply to the sludge contained in the on-srte impoundment.
Wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from electroplat-
  ing  operations.  This exclusion was published on April 20, 1989.
Dewatered Wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from
  electroplating operations after October 17, 1986.
Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from
  electroplating operations after August 15, 1986.

Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F019) generated from
  the chemical conversion coating of aluminum after August 15, 1986.

Wastewater treatment sludge (EPA Hazardous Waste No. F006) generated from electroplat-
  ing operations after November 27, 1985.
Dewatered niter  press sludge (EPA Hazardous Waste No. F006) generated from electroplat-
  ing operations after August 15, 1986.
Kiln  ash, cyclone  ash, separator sludge, and filtered wastewater (except spent actuated
  carbon) (EPA  Hazardous Waste No. F020 generated during the treatment of wastewater
  treatment sludge by the  EPA's Mobile Incineration System at the Denney Farm  Site in
  McDowell, Missouri after June 2, 1988, so long as:
(1) The incinerator is  monitored continuously and  is in  compliance with operating permit
  conditions. Should the incinerator fail to comply with the permit conditions relevant to the
  mechanical  operation of the incinerator, Syntex must test the residues generated dunng
  the run when the failure occurred according to the requirements of Conditions (2) through
  (6), regardless of whether or not  the demonstration in Condition  (7) has  been made.
(2) Four grab samples of wastewater  must be composited  from the volume  of  filtered
  wastewater  collected after each eight hour run and,  prior to disposal the  composite
  samples  must  be analyzed  for the EP  toxic metals,  nickel, and  cyanide.  If  arsenic,
  chromium, lead,  and silver  EP leachate test results  exceed 0.61  ppm; barium  levels
  exceed 12 ppm; cadmium and selenium levels exceed 0.12 ppm; mercury levels exceed
  0.02  ppm;  nickel levels  exceed  6.1  ppm; or  cyanide levels  exceed  2.4  ppm,  the
  wastewater  must be retreated to achieve these levels or must be disposed in accordance
  with all applicable  hazardous waste regulations. Analyses must be performed  according to
  SW-846 methodologies.
(3) One grab  sample must  be  taken  from  each drum of kiln  and  cyclone ash  generated
  dunng each eight hour run; all grabs collected during a given eight hour run must then be
  composited  to form one composite sample. A composite sample of four grab samples of
  the separator  sludge must be collected at the end of  each eight hour run.  Prior to the
  disposal of the residues from each eight hour run, an EP leachate test must be performed
  on these composite samples and the leachate analyzed for the EP  toxic  metals, nickel,
  and cyanide (using a distilled water extraction for the cyanide extraction) to  demonstrate
  that the following  maximum  allowable treatment residue concentrations listed  below are
  not exceeded.  Analyses  must be performed according to SW-846  methodologies. Any
  residues which exceed any of the levels listed below must be retreated to achieve these
  levels or must be disposed in accordance with all applicable hazardous waste regulations.
Maximum Allowable Solids Treatment  Residue EP Leachate Concentrations (mg/L)
  Arsenic—1.6
  Barium—32
  Cadmium—0.32
  Chromium—1.6
  Lead—1.6
  Mercury—0.065
  Nickel—16
  Selenium-0.32
  Silver—1.6
  Cyanide—6.5

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Part 261, App. IX                                               40 CFR Ch.  I  (7-1-89 Edition)

              TABLE 1—WASTES EXCLUDED  FROM NON-SPECIFIC SOURCES—Continued
    Facility
                  Address
Waste description
                              (4)—If Syntex stabilizes any of the kiln and cyclone ash or separator sludge, a Portland
                                cement-type stabilization  process must be  used and  Syntex  must collect a composite
                                sample of four grab samples from each batch of stabilized waste. An MEP leachate test
                                must  be  performed  on these composite samples and  the leachate analyzed for the EP
                                toxic metals, nickel, and cyanide (using a distilled water  extraction for the cyanide leachate
                                analysis)  to demonstrate  that the maximum allowable treatment residue concentrations
                                listed in Condition (3) are not exceeded during any run of the MEP extraction. Analyses
                                must  be performed according to SW-846 methodologies. Any residues which exceed any
                                of the levels listed in Condition (3) must be retreated to achieve these levels or must be
                                disposed in accordance with all applicable hazardous waste regulations. (If the residues
                                are stabilized, the analyses required in this condition supercede  the analyses required in
                                Condition (3).)
                              (5) Syntex must generate, prior to disposal of residues, verification data from each eight hour
                                run from  each treatment residue (i.e.. kiln and cyclone ash, separator sludge, and filtered
                                wastewater) to demonstrate that the  maximum allowable treatment residue concentrations
                                listed below are not exceeded. Samples must be collected as  specified in  Conditions (2)
                                and (3). Analyses must be performed according to SW-846  methodologies. Any solid or
                                liquid  residues which exceed any of  the levels listed  below must be retreated to achieve
                                these levels or must be disposed in accordance with Subtitle C of RCRA.
                              Maximum Allowable Wastewater Concentrations (ppm):
                                Benz(a)anthracene—1 x 10~4
                                Benzo(a)pyrene—4 x 10"5
                                Benzo(b)fluoranthene—2x 10'4
                                Chloroform—0.07
                                Chrysene—0.002
                                Dibenz(a,h)anthracene—9x 10~6
                                1,2-Dichloroethane—0.06
                                Oichloromethane—0.06
                                lndeno(1,2,3-cd)pyrene—0.002
                                Polychlorinated biphenyls—1 x 10'4
                                1,2,4,5-Tetrachlorobenzene—0.13
                                2,3,4,6-Tetrachlorophenol—12
                                Toluene—120
                                Trichloroethylene—0.04
                                2,4,5-Trichlorophenol—49
                                2,4,6-Trichlorophenol—0.02
                              Maximum Allowable Solid Treatment Residue Concentrations (ppm):
                                Benz(a)anthracene—1.1
                                Benzo(a)pyrene—0.43
                                Benzo(b)fluoranthene— 1.8
                                Chloroform—5.4
                                Chrysene—170
                                Dibenz(a, h)anthracene—0.083
                                Dichloromethane—2.4
                                1,2-Dichloroethane—4.1
                                lndeno(1,2,3-cd)pyrene—330
                                Polychlonnated biphenyls—0.31
                                1,2,4,5-Tetrachlorobenzene—720
                                Trichloroethylene—6.6
                                2,4,6-Trichlorophenol—3.9
                              (6) Syntex must generate, pnor to disposal of residues, verification data from each eight hour
                                run for each treatment residue (i.e.,  kiln and cyclone ash, separator sludge, and filtered
                                wastewater) to demonstrate that the  residues do not contain tetra-, penta-, or hexachloro-
                                dibenzo-p-dioxins or  furans at levels of regulatory concern. Samples must be collected as
                                specified  in Conditions (2) and  (3). The TCDD equivalent levels for wastewaters must be
                                less than 2 ppq and less than 5 ppt for the solid treatment residues. Any residues with
                                detected  dioxms or furans  in  excess of these  levels  must be retreated or must  be
                                disposed  as acutely  hazardous. Method 8290, a high resolution gas chromatography and
                                high resolution mass spectroscopy (HRGC/HRMS) analytical  method, must be used. For
                                tetra-  and pentachloronated dioxin and furan homologs, the maximum practical quantitation
                                limit must not exceed 15 ppt  for solids and  120 ppq for wastewaters. For hexachlonnated
                                homologs, the maximum practical quantitation limit must not exceed 37 ppt for solids and
                                300 ppq for wastewaters.
                              (7)(A) The test data from Conditions (1), (2). (3), (4). (5) and (6) must be kept on file by
                                Syntex for inspection purposes and must be compiled, summarized, and submitted to the
                                Section Chief. Vanances Section,  PSPD/OSW (WH-563), US EPA, 401 M Street, S.W.,
                                Washington, D.C. 20460 by certified  mail on a monthly  basis and when the treatment of
                                the lagoon sludge is concluded. All  data submitted will  be placed in the RCRA docket

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Environmental  Protection Agency                                         Part 261,  App.  IX

              TABLE 1— WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
    Facility
                  Address
                                                 Waste description
SRol
  Tennessee.
Tennessee
  Electroplat-
  ing.
Ripfey, TN	

Ripley,
  Tennessee.
Texas
  Instruments,
  Inc.
Tricil
  Environmen-
  tal Systems,
  Inc.
Dallas, TX.
Milliard. Ohio..
(B) The testing requirements for Conditions (2), (3), (4), (5), and (6) will continue until Syntex
  provides the Section Chief, Variances Section, with the results of four consecutive batch
  analyses for the  petitioned  wastes,  none of  which exceed  the maximum  allowable
  treatment residue concentrations  listed  in  these  conditions  and  the  Section  Chief,
  Variances Section, notifies Syntex that the conditions have been lined.
(B)  Syntex must  provide  a  signed  copy  of the  following  certification statement when
  submitting data in response  to  the conditions  listed above:  "Under civil  and criminal
  penalty of   law for  the  making or submission  of false  or  fraudulent  statements or
  representations, I  certify that the information contained in or accompanying this document
  is true, accurate, and complete. As to the  (those) identified section(s) of this document for
  which I cannot personally verify its (their) accuracy, I certify as the company official having
  supervisor/ responsibility  for the persons  who, acting under my direct instructions, made
  the verification that this information is true, accurate and complete."
Dewatered wastewater  treatment sludges (EPA Hazardous Waste  No.  F006) generated from
  the copper,  nickel, and chromium electroplating of plastic parts after November  17, 1986.
Dewatered wastewater treatment sludges  (EPA Hazardous  Waste Nos.  F006) generated
  from electroplating operations after November 17, 1986.  To ensure chromium  levels do
  not exceed the  regulatory standards there must be continuous batch testing of the filter
  press sludge for  chromium for 45 days  after the  exclusion is granted. Each  batch of
  treatment residue  must be representatively sampled and tested using the EP toxicity  test
  for chromium. This data must be kept on  file at the facility for inspection purposes. If the
  extract levels exceed 0.922 pom of chromium the waste must be managed and disposed
  of as hazardous.  If  these conditions are  not met,  the exclusion  does not apply. This
  exclusion does  not  apply  to sludges  in  any on-site impoundments  as  of this date.
Wastewater treatment sludges (EPA Hazardous Waste Nos. F006 and  F019) generated after
  August 27,  1985, from their electroplating operations that have been batch tested  for
  cadmium using the EP toxicity procedure and have been found to contain less than 0.30
  ppm cadmium in the  EP extract Wastewater treatment sludges that exceed this level will
  be considered a hazardous waste.
Dewatered wastewater treatment sludges (EPA Hazardous Waste No.  F006) generated from
  electroplating operations after November 17, 1986. To ensure that hazardous constituents
  are not present  in the waste at levels of regulatory concern, the facility must implement a
  contingency  testing program for the petitioned wastes. This testing program must meet the
  following conditions for the exclusion to be valid:
(1)  Each batch of  treatment residue must be representatively sampled and tested  using the
  total oil and  grease test and the EP Toxicity test (or the Oily Waste EP test, if the oil  and
  grease  content of  the  waste  exceeds  one  percent)  for  arsenic,  barium, cadmium,
  chromium, lead, selenium, silver, mercury, and nickel. It the extract concentrations  for
  chromium, lead, arsenic,  and silver exceed 0.315  ppm; barium levels exceed  6.3 ppm;
  cadmium and selenium levels exceed 0.063 ppm;  mercury levels exceed  0.013 ppm; or
  nickel levels exceed 2.2 ppm, the waste will be re-treated or managed and disposed as a
  hazardous waste under 40 CFR Parts 262 to 265 and the permitting standards of 40 CFR
  Part 270.
(2)  Each batch of treatment  residue must be  tested for reactive and leachable cyanide. If the
  reactive cyanide levels exceed 250 ppm or leachable cyanide levels  (using the EP Toxicity
  test without  acetic acid adjustment) exceed 1.26 ppm, the waste must be re-treated or
  managed and disposed as a hazardous waste under 40 CFR Parts 262 to  265 and the
  permitting standards of 40 CFR Part 270.
(3)  Each batch of the waste must be tested for the total content of the following organic
  toxicants. If  the total content of any of  the constituents  exceeds the maximum  levels
  shown, the  waste must be managed and  disposed as a hazardous waste  under 40 CFR
  Parts 262 to 265 and the permitting standards of 40 CFR Part 270.
                   Compound and Maximum Acceptable Levels (ppm)
Acrolein, 56.8
Anthracene, 76.8
Benzene, 0.106
p-Chkxo-m-cresol, 133
1,1-Dichtoroethane, 0.01
Fkxxene, 10.4
Methytene chloride, 8.2
Methyl ethyl ketone,  326
n-Nitrosodiphenylamine, 11.9
Phenanthrene,  14
Tetrachtoroethylene, 0.188
Trichkxoethylene. 0.59
Chloroform, 0.013
1.2-DtcrOoroethane. 0.0083
1,2-tran»-Dichloroe1hylene, 231
2,4-Dirrwthylphenol. 12.5
Vinyl chloride, 0.18

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Port 261, App.  IX                                               40 CFR Ch. I (7-1-89 Edition)

              TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
   Facility
                  Address
                                                 Waste description
Tricil
  Environmen-
  tal Systems,
  Inc.
Nashville,
  Tennessee
Tricil
  Environmen-
  tal Systems,
  Inc.
Mustogon,
  Michigan.
(4)  A grab sample  must be collected  from  each batch to form one monthly composite
  sample, which must be tested using GC/MS analysis for the compounds shown above as
  well as the remaining organics on the priority pollutant list. (See 47 FR 52309, November
  19, 1982, for a list of the priority pollutants.)
(5)  The test data from  conditions 1-4  must be kept  on  file at the facility  for inspection
  purposes and  must be  compiled, summarized,  and submitted to the Administrator by
  certified mail  on  a  semiannual  basis. The Agency will review this information and if
  needed, will propose to modify or withdraw the exclusion. The  organics testing described
  in conditions 3 and 4 above is not required until May 18,  1987. The Agency's decision to
  conditionally exclude  the treatment  residue  generated  from the  wastewater treatment
  system at this facility applies only to the wastewater treatment residue as described in this
  petition.
Dewatered wastewater treatment sludges (EPA Hazardous Waste  No. F019) generated from
  chemical conversion  coating  of aluminum after  November 17,  1986. To ensure  that
  hazardous constituents are not present in the waste at levels of regulatory concern, the
  facility  must implement a contingency testing program  for  the petitioned  wastes.  This
  testing  program  must meet  the  following conditions  for the exclusion  to be valid:
(1)  Each  batch of treatment residue must be representatively sampled and tested using the
  total oil and grease test and the EP Toxicrty test (or the Oily Waste EP test, if the oil and
  grease  content of the  waste exceeds one percent)  for  arsenic, barium, cadmium,
  chromium, lead, selenium,  silver,  mercury,  and nickel. If the extract concentrations for
  chromium, lead, arsenic, and silver exceed  1.1  ppm; barium  levels exceed 22.2 ppm;
  cadmium and selenium levels exceed 0.22 ppm; mercury levels exceed 0.044  ppm; or
  nickel levels exceed 7.8 ppm, the waste will be re-treated or managed and disposed as a
  hazardous waste under 40 CFR Parts  262 to 265 and the permitting standards of 40 CFR
  Part 270.
(2) Each batch of treatment residue must be tested for reactive and leachable cyanide. If the
  reactive cyanide levels exceed 250 ppm or leachable cyanide levels (using the EP Toxicrty
  test without acetic acid adjustment)  exceed  4.4 ppm, the waste  must be  re-treated or
  managed and disposed as a hazardous waste under 40 CFR Parts 262  to 265  and the
  permitting standards of 40 CFR Part 270.
(3)  Each  batch of the  waste must be tested for the total  content of the following organic
  toxicants. If the total  content of  any  of the constituents exceeds the maximum levels
  shown,  the waste  must be managed and disposed as a hazardous waste under  40  CFR
  Parts 262 to 265 and the permitting standards of 40 CFR  Part 270.
                   Compound and Maximum Acceptable Levels (ppm)
Acrolein, 363
Anthracene, 492
Benzene,  0.68
p-Chloro-m-cresol, 848
1,1-Dichloroethane, 0.068
Fluorene,  66.7
Methylene chloride. 52.4
n-Nitrosodiphenylamine, 76.1
Phenanthrene, 89
Tetrachloroethylene,  1.2
Trichloroetnylene, 3.78
Chloroform, 0.081
1,2-Dtchlofoethane, 0.053
2.4-Dimethylphenol. 79.7
Vinyl chloride, 1.16
1,2-Oiphenyl hydrazine, 0.005
(4)  A grab sample  must be collected  from each  batch to form one monthly composite
  sample, which must be tested using GC/MS analysis for the compounds shown above as
  well as the remaining organics on the  priority  pollutant list (See 47 FR 52309, November
  19, 1982, for a list of the  priority pollutants.)
(5)  The test data from conditions 1-4  must be kept on file at  the facility for inspection
  purposes and  must  be compiled,  summarized, and submitted to the Administrator  by
  certified mail  on  a semiannual  basis. The Agency  will  review this information and  If
  needed, will propose to modify or withdraw the exclusion. The organics testing described
  in conditions 3 and 4 above is not  requved until May 18, 1987. The Agency's decision to
  conditionally  exclude  the treatment residue  generated  from  the  wastewater treatment
  system at this facility applies only to the wastewater treatment residue as described in this
  petition.
Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from
  electroplating operations after November 17, 1966. To ensure that hazardous constituents
  are not present in  the waste at levels  of regulatory  concern, the facility must implement a
  contingency testing program for the petitioned  wastes. This testing program must meet the
  following conditions for the exclusion to be valid:

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Environmental Protection Agency                            Part 261, App. IX



           Table 1—Wastes Excluded From Non-Specific Sources—Continued
Facility
















































United
Technologies
Automotive,
Inc.
Universal Oil
Products.

U.S. EPA
Combustion
Research
Facility.
U.S.
Nameplate
Company,
Inc..

VAWof
America
Incorporat-
ed.
Address
















































Jeffersonville,
IN.

Decatur,
Alabama.

Jefferson,
Arkansas.


Mount Vemon,
Iowa..



St. Augustine,
Florida.


Waste descnption
(1) Each batch of treatment residue must be representatively sampled and tested using the
total oil and grease test and the EP Toxicity test (or the Oily Waste EP test, if the oil and
grease content of the waste exceeds one percent) for arsenic, banum, cadmium,
chromium, lead, selenium, silver, mercury, and nickel. If the extract concentrations for
chromium, lead, arsenic, and silver exceed 0.315 ppm; banum levels exceed 6.3 ppm;
cadmium and selenium levels exceed 0.063 ppm; mercury levels exceed 0.013 ppm; or
nickel levels exceed 2.2 ppm, the waste will be re-treated or managed and disposed as a
hazardous waste under 40 CFR Parts 262 to 265 and the permitting standards of 40 CFR
Part 270.
(2) Each batch of treatment residue must be tested for reactive and leachable cyanide. If the
reactive cyanide levels exceed 250 ppm or leachable cyanide levels (using the EP Toxicity
test without acetic acid adjustment) exceed 1.26 ppm, the waste must be re-treated or
managed and disposed as a hazardous waste under 40 CFR Parts 262 to 265 and the
permitting standards of 40 CFR Part 270.
(3) Each batch of the waste must be tested for the total content of the following organic
toxicants. If the total content of any of the constituents exceeds the maximum levels
shown, the waste must be managed and disposed as a hazardous waste under 40 CFR
Parts 262 to 265 and the permitting standards of 40 CFR Part 270.
Compound and Maximum Acceptable Levels (ppm)
Acrolein, 56.8
Anthracene, 76.8
Benzene, 0.106
p-Chloro-m-cresol, 133
1,1-Dichloroethane, 0.01
Fluorene, 10.4
Methylene chloride, 8.2
Methyl ethyl ketone, 326
n-Nitrosodiphenylamme, 1 1 .9
Phenanthrene, 14
Tetrachloroethylene, 0.188
Tnchloroethylene, 0.59
Chloroform, 0.013
1 ,2-Dichloroethane, 0.0083
1 ,2-trans-Dichloroethylene, 231
2,4-Dimethylphenol, 12.5
Vinyl chloride, 0.18
(4) A grab sample must be collected from each batch to form one monthly composite
sample, which must be tested using GC/MS analysis for the compounds shown above as
well as the remaining organics on the priority pollutant list. (See 47 FR 52309, November
19, 1982, for a list of the priority pollutants.)
(5) The test data from conditions 1-4 must be kept on file at the facility for inspection
purposes and must be compiled, summarized, and submitted to the Administrator by
certified mail on a semiannual basis The Agency will review this information and if
needed, will propose to modify or withdraw the exclusion. The organics testing described
in conditions 3 and 4 above is not required until May 18, 1987. The Agency's decision to
conditionally exclude the treatment residue generated from the wastewater treatment
system at this facility applies only to the wastewater treatment residue as described in this
petition.
Dewatered wastewater treatment sludge (EPA Hazardous Waste No. FO1 9) generated from
the chemical conversion of aluminum after April 29, 1986.

Wastewater Treatment sludges (EPA Hazardous Waste No. F006) generated from
electroplating operations and contained in two orvsite lagoons on August 1 5, 1 986. This is a one-
time exclusion.
One-time exclusion for scrubber water (EPA Hazardous Waste No. F020) generated in 1985
from the incineration of Vertac still bottoms. This exclusion was published on June 28,
1989.

Retreated wastewater treatment sludges (EPA Hazardous Waste No. F006) previously
generated from electroplating operations and currently contained in an on-site surface
impoundment after September 28, 1988. This is a one-time exclusion for the reteated
wastes only. This exclubon does not relieve the waste unit from regulatory compliance
under Subtitle C.
Wastewater treatment sludge filter cake (EPA Hazardous Waste No. F019) generated from
the chemical conversion coating of aluminum. This exclusion was published on February 1 .
1989.

        n—RQ-
              -ifi

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Part 261,  App.  IX                                               40  CFR Ch.  I  (7-1-89 Edition)

              TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
Facility
Vermont
American,
Corp.
Waterloo
Industries.

Watervliet
Arsenal.
William L.
Bonnell Co.

William L.
Bonnell Co.

Windsor
Plastics, Inc.
Address
Newark, OH 	


Pocahontas,
AR

Watervliet, NY ..

Carthage, TN....


Newnan,
Georgia.

Evansville, IN ...

Waste description
Wastewater treatment sludge (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations after November 27, 1985.

Wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations after dewatenng and held on-site on July 17, 1986 and any such sludge
generated (after dewatenng) after July 17, 1986.
Wastewater treatment sludges (EPA Hazardous Waste No F006) generated from electroplat-
ing operations after January 10, 1986.
Dewatered Wastewater treatment sludges (Vacuum filter sludge) (EPA Hazardous Waste No.
F019) currently generated from the chemical conversion coating of aluminum after October
17, 1986. This exclusion does not apply to sludges in the on-site surface impoundments.
Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F019) generated from
the chemical conversion coating of aluminum after November 14, 1986. This exclusion
does not include sludges contained in Bonnell's on-site surface impoundments.
Spent non-halogenated solvents and still bottoms (EPA Hazardous Waste No. F003)
generated from the recovery of acetone after November 17, 1986.
                        TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES
    Facility
                  Address
                                                Waste descnption
American
  Cyanamid

Amoco Oil Co.
Hannibal.
  Missouri

Wood River,
  IL.
Bethlehem
  Steel Corp..
Steelton, PA.
Wastewater and sludge (EPA Hazardous Waste No K038) generated from the washing and
  stripping of phorate production and contained in on-site lagoons on May 8,  1987, and such
  wastewater and sludge generated after May 8, 1987.
150 million gallons  of  DAF from petroleum refining contained in in  four surge ponds after
  treatment with  the  Chemifix* stabilization process.  This waste contains  EPA Hazardous
  Waste No K048  This exclusion applies to the 150 million gallons of waste after chemical
  stabilization  as long as the mixing  ratios of the reagent  with the waste  are monitored
  continuously and do not vary outside of the limits presented in the demonstration samples;
  one grab sample is taken each hour from each treatment unit, composited, and EP toxicity
  tests performed on each sample. If the levels of lead or total chromium exceed 0.5 ppm in
  the  EP  extract, then the waste that was  processed during the compositing period  is
  considered hazardous; the treatment residue shall be pumped into  bermed cells to ensure
  that the waste is identifiable in the event  that removal is necessary.
Uncured and cured chemically  stabilized electnc arc  furnace dust/sludge (CSEAFD) treat-
  ment residue (K061) generated  from the primary production of steel after May 22, 1989.
  This exclusion is conditioned upon the data obtained from Bethlehem's full-scale CSEAFD
  treatment facility because Bethlehem's original data were obtained  from a laboratory-scale
  CSEAFD treatment process. To  ensure that  hazardous constituents are not present in the
  waste at  levels of regulatory concern once the full-scale treatment facility  is in operation,
  Bethlehem must  implement  a  testing  program for  the petitioned waste. This testing
  program must meet the following conditions for the exclusion to be  valid:
(1) Testing:
(A) Initial Testing: During the first four weeks of operation of the full-scale treatment system,
  Bethlehem must collect representative grab samples of each treated batch of the CSEAFD
  and composite  the grab samples  daily. The daily composites, pnor to disposal,  must be
  analyzed for the EP leachate concentrations of all the  EP toxic metals, nickel and cyanide
  (using distilled water in the cyanide  extractions), and  the total constituent concentrations
  of reactive sulfide and reactive  cyanide.  Analyses  must be performed according to SW-
  846 methodologies. Bethlehem  must report the analytical  test data obtained during this
  initial  period  no  later  than 90 days after  the treatment  of the first full-scale  batch.
(B) Subsequent Testing: Bethlehem must  collect representative grab samples from every
  treated batch of  CSEAFD generated daily  and composite all  of the grab  samples  to
  produce a weekly composite sample. Bethlehem then  must  analyze each weekly compos-
  ite  sample for  the EP  leachate concentrations of all the EP  toxic metals and  nickel.
  Analyses must  be performed according  to  SW-846 methodologies. The analytical data,
  including  all quality control information,  must be compiled  and maintained on site for a
  minimum  of three  years. These  data must be furnised upon request and made available
  for inspection by  any employee or representative of  EPA or the  State of Pennsylvania.
(2) Delisting levels  If the EP extract concentrations  resulting from the testing in condition
  (1)(A)  or (1)(B)  for  chromium,  lead, arsenic, or silver  exceed 0.315 mg/l; for banum
  exceeds 6.3  mg/l;  for cadmium or selenium exceed 0.063  mg/l; for mercury  exceeds
  0.0126 mg/l or for nickel  exceeds 0.0126 mg/l; for cyanide exceeds 1.26 mg/l, or total
  reactive  cyanide  or total  reactive sulfide levels exceed  250 mg/kg and 500 mg/kg,
  respectively, the waste must either be re-treated or managed and disposed in accordance
  with Subtitle C of  RCRA.

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Environmental Protection  Agency                                          Part 261, App. IX

                 TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
    Facility
                   Address
                                                  Waste description
Bethlehem
  Steel Corp.
Johnstown,
  PA.
(3) Data submitta/s: Within one week of system start-up,  Bethlehem must notify the Section
  Chief, Variances Section (see address below) when their full-scale stabilization  system is
  on-line and  waste treatment has begun. All  data  obtained  through the initial  testing
  condition (1)(A), must be submitted to  the Section Chief, Variances Section, PSPD/OSW,
  (OS-343), U.S.  EPA,  401 M Street, S.W., Washington,  DC 20460 within the time period
  specified in  condition (1)(A). At  the  Section  Chief's  request,  Bethlehem  must  submit
  analytical data obtained through condition (1)(B) to  the above  address, within the time
  period specified by the Section Chief.  Failure to submit the required  data obtained f-^m
  either condition  (1)(A) or (1)(B) within the  specified time periods will be considered by the
  Agency sufficient basis to revoke Bethlehem's exclusion to the  extent directed by EPA. All
  data must be accompanied by the following certification statement:
"Under civil and criminal penalty of  law for  the making or submission of false or fraudulent
  statements or representations (pursuant to the  applicable provisions of the Federal Code
  which include,  but  may not be  limited to, 18  U.S.C. 6928), I  certify  that the information
  contained in  or accompanying this document is true, accurate and complete.
"As to the (those) identified section(s) of this document for which I cannot personally verify
  its  (their)  truth  and accuracy,  I  certify as  the company  official   having  supervisory
  responsibility  for  the  persons  who,  acting  under  my  direct  instructions, made  the
  verification that this information is true,  accurate and complete.
"In  the event that any of this information is determined by EPA  in its sole discretion to be
  false, inaccurate or incomplete, and upon  conveyance of this  fact  to the  company,  I
  recognize and agree that this exclusion of wastes will be void  as if it  never had effect or
  to the extent directed by EPA and that the company will be liable for  any actions taken in
  contravention of the company's  RCRA  and  CERCLA  obligations  premised upon  the
  company's reliance on the void exclusion."
Uncured and cured chemically stabilized electric arc furnace dust/sludge (CSEAFD) treat-
  ment residue (K061) generated  from the  primary production of steel  after  May 22, 1989.
  This exclusion is conditioned upon the  data obtained from Bethlehem's full-scale CSEAFD
  treatment facility because BethleKem's onginal  data were obtained from a  labortory-scale
  CSEAFD treatment process. To  ensure that hazardous constituents are not present in the
  waste at  levels of regulatory concern once the full-scale treatment facility is in operation,
  Bethlehem must implement a  testing  program  for  the  petitioned  waste.  This  testing
  program must meet the  following conditions for the exclusion to be valid:
(1) Testing:
(A) Initial Testing:  During the first four weeks of operation of the full-scale treatment system,
  Bethlehem must collect representative grab samples of each treated batch of the CSEAFD
  and composite the grab samples  daily. The daily composites,  prior  to disposal, must be
  analyzed for  the EP leachate concentrations of all the EP toxic metals, nickel and cyanide
  (using distilled water in the  cyanide extractions),  and the total constituent  concentrations
  of reactive sulfide and reactive  cyanide. Analyses must be performed according to SW-
  846  methodologies. Bethlehem  must report the analytical test data  obtained during  this
  initial  period no later than  90 days  after the  treatment of the first full-scale batch.
(B)  Subsequent Testing: Bethlehem must  collect representative grab samples from every
  treated batch of CSEAFD  generated  daily and  composite all  of the grab  samples to
  produce a weekly composite sample. Bethlehem then must analyze each weekly compos-
  ite  sample for the EP leachate concentrations  of all  the EP  toxic  metals  and nickel.
  Analyses must be  performed according  to SW-846  methodologies.  The analytical data,
  including all  quality control  information, must be compiled  and  maintained on site for a
  minimum of three years. These  data must be furnished  upon request and made available
  for  inspection by any employeee or representative of EPA or  the State of Pennsylvania.
(2) Delisting levels: If the EP extract concentrations resulting from the  testing  in  condition
  (1)(A) or (1)(B) for chromium,  lead, arsenic,  or silver exceed  0.315 mg/l, for  barium
  exceeds 6.3 mg/l; for  cadmium or selenium exceed  0.063 mg/l; for mercury exceeds
  0.0126 mg/l; for nickel exceeds 3.15  mg/l;  or for cyanide exceeds  1.26 mg/l, or total
  reactive cyanide or total reactive sulfide levels exceed 250 mg/kg and  500  mg/kg.
  respectively,  the waste must either be re-treated or managed and disposed in accordance
  with Subtitle  C of RCRA.
(3) Data submittals: Within one week of system start-up, Bethlehem must notify the Section
  Chief, Variances Section (see address below) when their full-scale stabilization system is
  on-line and  waste treatment has begun. All  data  obtained  through the initial  testing
  condition (1)(A), must be submitted to  the Section Chief, Variances Section, PSPD/OSW,
  (OS-343), U.S.  EPA, 401 M Street, SW., Washington, DC 20406 within the  time period
  specified in  condition (1)(A). At  the  Section  Chief's  request,  Bethlehem  must  submit
  analytical data obtained through condition (1)(B) to  the above  address, within the time
  period specified by the Section Chief.  Failure to submit the required  data obtained from
  either condition  (1)(A) or (1)(B) within the  specified time penods will be considered by the
  Agency sufficient basis to revoke Bethlehem's exclusion to the  extent directed by EPA. All
  data must be accompanied by the following certification statement:

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Part 261, App. IX                                                40  CFR Ch. I (7-1-89 Edition)

                 TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
    Facility
   Address
                                  Waste description
CF&I Steel
  Corporation..
Pueblo,
  Colorado..
"Under civil  and criminal penalty of law for the making or submission of false or fraudulent
  statements or representations (pursuant  to the applicable provisions of the Federal Code
  which include, but may not be  limited to, 18 U.S.C. 6928), I  certify that  the  information
  contained  in or accompanying this document is true, accurate and complete.
"As to the (those) identified section(s) of this document for  which  I cannot personally verify
  its  (their)  truth  and  accuracy,  I  certify as  the  company  official  having  supevisory
  responsibility  for  the persons  who,  acting  under  my  direct instructions,  made the
  verification that this information is true, accurate and complete.
"In the event that any of this information is determined by EPA in its sole discretion to be
  false,  inaccurate or incomplete, and upon conveyance of this fact to the company,  I
  recognize  and agree that this exclusion of wastes will be void as if it never  had effect or
  to the extent  directed by EPA and that the company will be liable for any actions taken in
  contravention of  the  company's  RCRA and CERCLA  obligations  premised  upon the
  company's reliance on the void exclusion."
Fully-cured   chemically  stabilized  electric  arc  furnace  dust/sludge  (CSEAFD)  treatment
  residue (EPA  Hazardous Waste No. K061) generated from the primary production of steel
  after May  9, 1989  This exclusion is conditioned upon the data obtained from CF&l's full-
  scale  CSEAFD treatment  facility  because CF&l's  onginal data  was  obtained from  a
  laboratory-scale CSEAFD  treatment  process. To  ensure  that hazardous constituents are
  not  present  in the waste at  levels  of regulatory concern once the  full-scale  treatment
  facility is  in operation, CF&I  must  implement a testing program  for the petitioned  waste.
  This testing  program must meet the following conditions for  the  exclusion to be vaild:
(1) Testing:
(A) Initial Testing: During the first four weeks of operation of the full-scale treatment system,
  CF&I must collect representative grab samples of each treated batch of  the CSEAFD and
  composite the grab  samples daily. The daily composites, prior  to disposal, must  be
  analyzed for the EP leachate  concentrations of all the EP toxic metals, nickel, and cyanide
  (using distilled water in the cyanide  e_xtractions),  and the  total constituent concentrations
  of reactive sulfide and reactive cyanide  Analyses must be performed according to SW-
  846 methodologies. CF&I  must report the analytical test data obtained dunng  this initial
  penod no later than 90 days after the treatment of the first full-scale batch.
(B)  Subsequent Testing: CF&I must collect representative grab samples from every treated
  batch  of CSEAFD generated  daily and  composite all of the grab  samples to  produce a
  weekly composite  sample. CF&I then must analyze each weekly composite sample for the
  EP  leachate concentrations of all  of the EP toxic metals and nickel. Analyses must be
  performed according to SW-846 methodologies.  The analytical data,  including  all  quality
  control information, must  be  compiled and maintained on site  for a minimum of three
  years. These  data must be furnished upon request and made available for inspection by
  any employee or representative of EPA or the State of Colorado.
(2) Delisting  levels: If the EP extract concentrations  determined in conditions  (1)(A) or (1)(B)
  for chromium, lead, arsenic, or silver exceed 0.315 mg/1; for barium  exceeds 6.3  mg/1;
  for  cadmium  or selenium exceed 0.063 mg/1;  for  mercury exceeds  0.0126  mg/1; for
  nickel exceeds 3.15 mg/1; or for cyanide exceeds 4.42 mg/1, or total reactive  cyanide or
  total reactive  sulfide levels exceed 250  mg/kg and 500 mg/kg, respectively,  the  waste
  must either be re-treated or  managed and disposed  in accordance with Subtitle C of
  RCRA.
(3) Data subrmttals: Within one  week of system start-up, CF&I must notify the Section  Chief,
  Variances  Section (see address below) when  their full-scale stabilization  system is on-line
  and waste treatment has begun.  All data obtained through the initial  testing condition
  (1)(A), must be submitted to the Section  Chief, Variances Section, PSPD/OSW, (OS-343),
  U.S. EPA,  401 M  Street, SW., Washington, DC 20460 within the time penod specified in
  condition (1)(A). At the Section Chief's request, CF&I must submit analytical data obtained
  through condition  (1)(B) to the  above address,  within the time  penod  specified by the
  Section Chief Failure to submit the required data obtained from  either condition (1)(A) or
  (1)(B)  within the specified time penods will be considered by the Agency sufficient basis to
  revoke CF&l's exclusion to the extent directed by  EPA. All data must be accompanied by
  the  following  certification  statement: "Under  civil and  criminal  penalty of  law for the
  making of  submission of false or fraudulent statements or representations (pursuant  to the
  applicable  provisions  of the Federal Code which  include,  but may not be limited  to,  18
  U.S.C. 6928), I certify that the information contained in or accompanying this document is
  true, accurate and complete.  As to the (those) identified section(s) of this document for
  which I cannot personally verify its  (their) truth and accuracy, I certify  as the company
  official having supervisory  responsibility  for the  persons who,  acting  under  my  direct
  instructions, made the verification that this information is true, accurate and  complete. In
  the  event  that any of this  information is determined by EPA in  its sole discretion  to be
  false,  inaccurate  or incomplete, and upon conveyance of this  fact to the company.  I
  recognize  and agree that this exclusion of wastes will be void as if it never had effect or
  to the extent directed by EPA and that the company will be liable for any actions taken in
  contravention of  the  company's RCRA  and  CERCLA obligations premised  upon the
  company's reliance on the void exclusion  "

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Environmental Protection Agency                                         Part 261, App. IX

                 TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
   Facility
                  Address
                                                Waste description
Envirrte
  Corporation.
Canton, Ohio;
  Harvey,
  Illinois;
  Thomaston,
  Connecticut
  and York
  PA.
LCP Chemical.
Meart Corp	

Monsanto
  Industrial
  Chemicals
  Company.
Orrington, ME..
Peekskill. NY...

Sauget. Illinois.
Spent pickle  liquor  (EPA  Hazardous  Waste  No.  K062) generated  from steel  finishing
  operations of facilities within  the  iron and  steel industry (SIC Codes 331  and 332);
  wastewater  treatment  sludge  (EPA  Hazardous Waste  No. K002)  generated  from  the
  production of chrome  yellow and  orange  pigments; wastewater treatment  sludge (EPA
  Hazardous  Waste  No. K003)  generated  from  the  production  of molybdate  orange
  pigments; wastewater treatment sludge (EPA  Hazardous Waste  No. K004) generated from
  the  production of  zinc yellow pigments; wastewater treatment sludge  (EPA Hazardous
  Waste No. K005) generated from the production  of chrome green pigments; wastewater
  treatment sludge (EPA Hazardous Waste  No.  K006)  generated from the  production of
  chrome  oxide green pigments  (anhydrous and hydrated);  wastewater  treatment sludge
  (EPA Hazardous Waste No. K007) generated from the production of iron blue pigments;
  oven residues (EPA  Hazardous Waste No. K008)  generated from the production of
  chrome  oxide  green pigments after  November  14,  1986. To  ensure that  hazardous
  constituents are not present in the  waste at levels of regulatory concern, the facility must
  implement a contingency  testing program for the  petitioned wastes.  This testing  program
  must meet the following conditions for the exclusions to be valid;
(1) Each batch of treatment  residue must be  representatively sampled  and tested using the
  EP Toxicity  test for arsenic, banum, cadmium,  chromium, lead, selenium, silver,  mercury,
  and nickel.  If the extract  concentrations for  chromium,  lead, arsenic, and  silver exceed
  0.315  ppm;  barium  levels exceed  6.3 ppm;  cadmium and  selenium exceed 0.063 ppm;
  mercury  exceeds 0.0126 ppm;  or nickel levels exceed 2.205 ppm, the waste must be re-
  treated or managed and disposed as a hazardous waste under 40 CFR  Parts 262 to  265
  and the permitting standards of 40 CFR Part 270.
(2) Each batch of treatment residue must be tested for reactive and leachable cyanide If the
  reactive  cyanide  levels exceed  250 ppm; or  leachable cyanide levels (using the EP
  Toxicity  test without acetic  acid adjustment) exceed  1.26  ppm,  the waste  must be re-
  treated or managed  and  disposed  as hazardous  waste under 40 CFR  Parts 262 to  265
  and the permitting standards of 40 CFR 270.
(3) Each batch of waste must be tested for the total content  of specific organic toxicants.  If
  the total content of anthracene exceeds 76.8 ppm, 1,2-diphenyl hydrazine exceeds 0.001
  ppm, methylene chlonde  exceeds  8.18 ppm, methyl ethyl ketone exceeds  326  ppm, n-
  nitrosodiphenylamine exceeds 11.9 ppm, phenol exceeds 1,566 ppm, tetrachloroethylene
  exceeds  0.188 ppm, or tnchloroethylene exceeds 0.592 ppm. the waste must be managed
  and disposed as a hazardous waste  under 40  CFR Parts 262  to 265 and the permitting
  standards of 40 CFR Part 270.
(4) A  grab sample must be collected from  each  batch to form one monthly  composite
  sample which must  be tested  using GC/MS analysis for the compounds  listed in  #3
  above as well as the remaining organics on  the priority pollutan  list. (See 47 FR 52309,
  November 19, 1982, for a list of the pnority  pollutants.)
(5) The data from conditions 1-4 must be kept on file at the facility for inspection purposes
  and must be compiled, summarized, and submitted  to the Administrator by  certified  mail
  semi-annually. The  Agency  will  review this  information and  if needed will propose to
  modify or withdraw the exclusion.  The organics testing  described in conditions  3 and  4
  above is not required until six  months from  the date of promulgation. The  Agency's
  decision  to  conditionally exclude the treatment residue generated from the wastewater
  treatment systems at these facilities applies only  to the wastewater  and solids treatment
  systems  as  they presently exist as described in the  delisting petition. The exclusion does
  not  apply to the  proposed process additions described  in  the petition  as  recovery,
  including  crystalization, electrolytic metals  recovery, evaporative  recovery,  and ion ex-
  change.
Brine purification muds and wastewater treatment sludges generated after August 27. 1985
  from their chlor-alkali manufactunng  operations (EPA Hazardous Waste Nos.  K071  and
  K106) that have been batch tested for mercury  using the EP toxicity  procedures and have
  been found to contain less than 0.05 ppm mercury in the EP extract  Brine purification
  muds  and wastewater treatment sludges  that exceed  this level will  be  considered  a
  hazardous waste.
Wastewater treatment sludge (EPA Hazardous Waste Nos. K006 and K007) generated from
  the production of chrome  oxide green and iron blue pigments  after  November 27, 1985.
Brine purification muds (EPA Hazardous Waste No.  K071) generated from the mercury cell
  process  in chlorine production, where separately prepunfied  bnne is not used after August
  15, 1986.

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Part 261, App. IX                                                40 CFR Ch.  I  (7-1-89 Edition)

                 TABLC 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
    Facility
                  Address
                                                  Waste description
Roanoke
  Electric
  Steel Corp..
Roanoke, VA.
Stauffer
  Chemical
  Co.
Stautfer
  Chemical
  Co.
Tricil
  Environmen-
  tal Systems,
  Inc.
Axis, AL	
St. Gabriel, LA
Milliard, Ohio....
Fully-cured chemically stabilized  electric  arc  furnace  dust/sludge  (CSEAFD)  treatment
  residue  (EPA Hazardous Waste  No. K061)  generated from the pnmary production of steel
  after  March  22,  1989. This exclusion is conditioned upon the data  obtained  from
  Roanoke's  full-scale CSEAFD treatment  facility  because Roanoke's  original  data  were
  obtained from a laboratory-scale CSEAFD treatment process. To ensure that hazardous
  constituents are not present in  the waste at  levels of  regulatory concern  once the full-
  scale treatment facility is in operation, Roanoke must implement a testing program for the
  petitioned waste.
This testing program  must meet  the following conditions for the exclusion to be valid:
(1)  Testing:
(A)  Initial testing: During the first four weeks of operation of the full-scale treatment system,
  Roanoke must collect representative grab samples of each treated batch of the CSEAFD
  and composite the grab samples daily. The daily composites, prior to  disposal, must  be
  analyzed for the EP leachate concentrations of all the EP toxic metals, nickel and cyanide
  (using distilled water in the cyanide extractions), and the total constituent concentrations
  of reactive  sulfide and  reactive  cyanide. Analyses must be performed  according to  SW-
  846  methodologies. Roanoke must  report the analytical test data obtained during  this
  initial  penod  no later  than  90 days  after the treatment of the  first full-scale batch.
(B)  Subsequent testing:  Roanoke must  collect representative  grab samples  from every
  treated  batch  of CSEAFD  generated daily and  composite all of the grab samples to
  produce a weekly composite sample. Roanoke then must analyze each weekly composite
  sample for all of the EP toxic metals and nickel. Analyses must be performed according to
  SW-846 methodologies. The analytical data, including all quality control information, must
  be compiled and maintained on site for a  minimum of three years. These  data must be
  furnished upon request  and made available for inspection by any employee or representa-
  tive of EPA or the State of Virginia
(2)  Delisting levels: If the EP extract concentrations  tor  chromium, lead, arsenic, or silver
  exceed 0.315 mg/l; for banum exceeds 6.3 mg/l; tor cadmium or selenium  exceed 0.063
  mg/l; for mercury  exceeds 0.0126-mg/l; tor  nickel exceeds  3.15  mg/l; or for cyanide
  exceeds  1.26 mg/l, or  total  reactive  cyanide  or total reactive sulfide  levels exceed 250
  mg/kg and  500 mg/kg, respectively, the waste must either be  re-treated or  managed and
  disposed in accordance with Subtitle C of RCRA.
(3)  Data submittals: Within one week of system start-up,  Roanoke must notify the Section
  Chief, Variances Section (see address below) when their full-scale stabilization system in
  on-line and waste  treatment has begun.  All data obtained  through  the  initial  testing
  condition (1 )(A), must be submitted to the  Section Chief, Variances Section, PSPD/OSW,
  (OS-343), U.S. EPA, 401  M Street, SW.,  Washington, DC 20460  within  the time penod
  specified in  condition (.1Y.A). Failure to submit the required data or keep the required
  records  will be considered by  the Agency, at its  discretion,  sufficient basis  to  revoke
  Roanoke's  exclusion. All data must  be accompanied by the following  certification state-
  ment: "Under civil  and  cnminal  penalty of law for the  making or submission of false or
  fraudulent statements or representations (pursuant to  the applicable  provisions  of  the
  Federal  Code which include, but may not be  limited to, 18 USC 6928), I certify that the
  information  contained in or  accompanying this document is true, accurate and complete.
  As to the (those) identified section(s) of this document for which I cannot personally verify
  its  (their) truth  and accuracy, I certify  as  the  company  official having supervisory
  responsibility  for  the  persons  who,  acting  under my direct  instructions,  made  the
  verification that this information  is true,  accurate and complete. In  the  event that  any of
  this information is  determined by EPA  in  its  sole  discretion to be false,  inaccurate  or
  incomplete, and upon conveyance of this fact to the company,  I recognize and agree that
  this exclusion of wastes will be void as rf it never had effect or to the extent directed  by
  EPA and that the  company  will be  liable for  any actions taken in contravention  of  the
  company's RCRA and CERCLA  obligations premised upon the  company's reliance  on the
  void exclusion."
Bnne purification  muds generated from  their  chlor-alkali manufacturing operatings (EPA
  Hazardous  Waste  No.  K071) and  disposed of  in  brine mud pond HWTF:  5 EP-201.

Brine punfication  muds, which  have been  washed  and  vacuum filtered, generated after
  August 27,  1985 from their chlof-alkali manufacturing operations (EPA  Hazardous  Waste
  No. K071) that  have been batch tested for  mercury using the  EP toxicity procedure and
  have  been  found to contain  less than 0.05  ppm  in mercury in the  EP extract. Brine
  purification muds that exceed this level will be considered a hazardous waste.
Spent pickle liquor (EPA Hazardous Waste No. K062) generated by steel finishing operations
  of facilities within the iron and steel industry (SIC Codes 331 and 332) after November 17,
  1986. To ensure that hazardous constituents  are not present in the waste at levels of
  regulatory concern,  the facility  must  implement a  contingency testing program for  the
  petitioned wastes.  This testing  program must  meet  the  following conditions  for  the
  exclusions to be valid:

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Environmental  Protection  Agency                                         Part 261, App. IX

                 TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
   Facility
                  Address
                                                Waste description
Tncil
  Environmen-
  tal System,
  Inc.
Muskegon,
  Michigan.
(1) Each batch of treatment restdue must be representatively sampled and tested using the
  total oil and grease test and the EP Toxicity test (or the Oily Waste EP test, if the oil and
  grease content of  the  waste  exceeds one percent)  for  arsenic,  barium,  cadmium,
  chromium, lead, mercury, selenium,  silver and nickel.  If the extract concentrations for
  chromium, lead, arsenic,  barium,  and silver  exceed 6.3 ppm;  cadmium and  selenium
  exceed 0.063 ppm; mercury levels exceed 0.013 ppm; or nickel levels exceed 2.2 ppm,
  the waste will be retreated or managed and disposed as a hazardous waste under 40 CFR
  Parts 262 to 265 and the permitting standards  of 40 CFR  270.
(2) Each batch  of treatment residue must be tested for reactive and leachable cyanide. It the
  reactive  cyanide levels exceed 250  ppm;  or leachable cyanide levels  (using (her  EP
  Toxicity  test  without acetic acid  adjustment) exceed  1.26 ppm.  the waste must  be
  retreated  or managed and disposed as hazardous waste  under 40 CFR Parts 262 to 265
  and the permitting  standards of 40 CFR Part 270.
(3) Each batch of waste must  be tested  for  the total content of the following  organic
  toxicants. If the total content  of any of  the  constituents exceeds  the maximum levels
  shown, the waste  must be managed and disposed  as a  hazardous waste under 40 CFR
  Parts 262 and 265 and the permitting standards of 40 CFR Part 270.
                   Compound and Maximum Acceptable Levels (ppm)
Acrolem, 56.8
Anthracene, 76.8
Benzene, 0.106
p-Chloro-m-cresol, 133
1,1-Dichloroethane, 0.01
Fluorene, 10.4
Methylenechlonde, 8.2
Methyl ethyl ketone,  326
n-Nitrosodiphenylamme, 11.9
Phenanthrene, 14
Tetrachloroethylene,  0.188
Trichloroethylene, 0.59
Chloroform, 0.013
1,2-Dichloroethane, 0.0083
1,2-trans-Dichloroethylene, 231
2,4-Dimethylphenol, 12.5
Vinyl chloride. 0.18
1,2-Diphenyl hydrazine, O.OOi
(4) A grab  sample  must be collected  from  each batch to  form one  monthy composite
  sample, which must be tested using GC/MS  analysis for the organic  compounds shown
  above, as well as  the remaining organics on the priority  pollutant list (see 47 FR 52309,
  November 19, 1982, Appendix A-126 Priority Pollutants).
(5) The test data from conditions 1-4  must  be kept on file  at the facility for inspection
  purposes  and must be compiled, summarized, and  submitted  to the Administrator by
  certified  mail  on  a  semiannual basis. The  Agency will review this  information and if
  needed, will propose to modify  or withdraw  the exclusion The organics testing descnbed
  in conditions  3 and 4 above is not required  until May 18, 1987 The  Agency's decision to
  conditionally  exclude the  treatment  residue  generated  from  the wastewater  treatment
  system at this facility applies only to  the wastewater treatment residue described in this
  petition.
Spent pickle liquor (EPA Hazardous Waste No. K062) generated by steel finishing operations
  of facilities within the iron and steel industry (SIC Codes 331 and 332); after November 17.
  1986. To ensure that hazardous constituents are  not  present in the  waste  at levels of
  regulatory  concern,  the facility must  implement a  contingency  testing program  for  the
  petitioned  wastes   This  estmg program  must meet  the following  conditions  for  the
  exclusion to be valid.
(1) Each batch of  treatment residue must be representatively sampled  and tested using  the
  total oil and grease test and the EP Toxicity test (or the Oily Waste EP test, if the oil and
  grease content of  the  waste  exceeds one percent)  for  arsenic,  barium,  cadmium,
  chromium, lead, mercury, selenium,  silver and nickel.  If the extract  concentrations for
  chromium, lead, arsenic,  barium,  and silver  exceed 6.3 ppm,  cadmium and selenium
  exceed 0.063 ppm; mercury levels exceed 0.013 ppm; or nickel levels exceed 2.2 ppm,
  the waste will be retreated or managed and disposed as a hazardous waste under 40 CFR
  Parts 262 to 265 and the permitting standards  of 40 CFR  270.
(2) Each batch  of treatment residue must be tested for reactive and leachable cyanide. If the
  reactive  cyanide levels exceed 250  ppm; or leachable cyanide levels (using  the  EP
  Toxicity  test  without acetic acid  adjustment) exceed  1.26 ppm,  the waste must be
  retreated  or managed and disposed as hazardous waste under 40 CFR Parts 262 to 265
  and the permitting  standards of  40 CFR Part 270.

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Port 261, App. X                                           40 CFR Ch. I (7-1-89  Edition)

               TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
   Facility
                Address
                                                         Waste description
Vulcan
  Materials
  Company.
Port Edwards,
  Wl.
(3) Each batch of waste must be tested lor the total content  of the following organic
  toxicants. If the total content of any of the constituents  exceeds the maximum levels
  shown, the waste  must be managed and disposed as a hazardous waste under 40 CFR
  Parts 262 and 265 and the permitting standards of 40 CFR Part 270:
                 Compound and Maximum Acceptable Levels (ppm)
Acrolein, 56.8
Anthracene, 76.8
Benzene, 0.106
p-Chloro-m-cresol, 133
1,1-Dichloroethane, 0.01
Fluorene, 10.4
Methylenechlonde, 8.2
Methyl ethyl ketone. 326
n-Nitrosodiphenylamine, 11.9
Phenanthrene, 14
Tetrachloroethylene, 0.188
Tnchtoroethylene, 0.59
Chloroform, 0.013
1,2-Dichloroethane, 0.0083
1,2-trans-Dichloroethylene, 231
2,4-Dimethylphenol, 12.5
Vinyl chloride, 0.18
1.2-Diphenyl hydraztne, 0.001
(4) A grab sample must be collected from each batch to  form one monthly composite
  sample,  which must be tested using GC/MS analysis tor the organic compounds shown
  above, as well as  the remaining  organics on the priority pollutant list (see 47 FR 52309,
  November 19, 1982, Appendix A-126 Priority Pollutants).
(5) The test data from conditions  1-4 must be kept on file at the facility for inspection
  purposes and must be compiled,  summarized, and submitted  to the Administrator  by
  certified  mail on a  semiannual  basis.  The Agency will review this  information and  if
  needed, will propose to modify or withdraw the exclusion. The organics testing described
  in conditions 3 and 4 above is not required until May 18, 1987. The Agency's decision to
  conditionally exclude the treatment residue  generated from the wasterwater treatment
  system at this facility applies only to the wastewater treatment  residue described in this
  petition.
Bnne purification muds (EPA Hazardous Waste No. K071) generated from the mercury cell
  process  in chlorine production,  where  separately  prepunfied  brine  is not used  after
  November 17, 1986. To assure that mercury  levels  in this waste  are maintained at
  acceptable levels,  the following conditions apply to this exclusion: Each batch of treated
  bnne clanfier muds and saturate* insolubles must be tested (by the extraction procedure)
  prior to disposal and the leachate concentration of mercury  must be less than or equal to
  0.0129 ppm. If the waste does not meet this requirement,  then it must be  re-treated or
  disposed of as hazardous. This  exclusion does not apply  to wastes for which  either of
  these conditions is not satisfied
TABLE 3—WASTES EXCLUDED FROM COMMER-
   CIAL  CHEMICAL PRODUCTS,  OFF-SPECIFICA-
   TION  SPECIES,  CONTAINER RESIDUES, AND
   SOIL RESIDUES THEREOF
Facility
Union Carbide
Corp.
Address
Tatt LA

Waste descnption
Contaminated soil (approxi-
mately 1 1 ,000 cubic
yards), which contains
acrolein in concentra-
tions of less than 9 ppm.
 [49 FR 37070. Sept. 21, 1984]

   EDITORIAL NOTE: For FEDERAL REGISTER ci-
 tations affecting Appendix IX of  Part 261,
 see the List of CFR Sections Affected in the
 Finding Aids section of this volume.
                                      APPENDIX X—METHOD OF ANALYSIS FOR
                                           CHLORINATED     DIBENZO-P-DIOXINS
                                           AND     -DIBENZOFURANS *• *• * 4

                                                        Method 8280
                                        1. Scope and Application
                                         'This method is appropriate  for the anal-
                                      ysis  of tetra-,  penta-,  and  hexachlorinated
                                      dibenzo-p-dioxins and -dibenzofurans.
                                         'Analytical protocol  for determination of
                                      TCDDs in phenolic chemical wastes and soil
                                      samples  obtained  from  the  proximity of
                                      chemical  dumps.  T.O.  Tiernan  and   M.
                                      Taylor.  Brehm  Laboratory,  Wright  State
                                      University, Dayton, OH 45435.
                                                                             Continued

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Environmental Protection Agency
                       Part 261, App. X
  1.1  This method measures the concentra-
tion of chlorinated dibenzo-p-dioxins  and
chlorinated  dibenzofurans   in   chemical
wastes including still  bottoms, filter aids,
sludges, spent carbon,  and reactor residues,
and in soils.
  1.2  The sensitivity of this method is de-
pendent upon the level of interferences.
  1.3  This method is recommended for use
only by analysts experienced with  residue
analysis and skilled in mass spectral analyti-
cal techniques.
  1.4  Because  of  the extreme toxicity of
these compounds,  the analyst must take
necessary  precautions  to prevent exposure
to himself, or to others, of materials known
or believed to contain CDDs or CDFs.
  2. Summary of the Method
  2.1  This method is  an analytical extrac-
tion  cleanup  procedure,  and  capillary
column gas  chromatograph-low  resolution
mass  spectrometry method, using capillary
column GC/MS  conditions  and  internal
standard  techniques, which  allow for the
measurement of PCDDs and PCDFs in the
extract.
  2.2  If interferences  are  encountered, the
method provides selected  general  purpose
cleanup procedures to aid the analyst in
their elimination.
  3. Interferences
  3.1  Solvents,  reagents,  glassware,  and
other sample processing hardware may yield
discrete artifacts and/or elevated baselines
causing misinterpretation of gas chromato-
grams. All of these materials must be dem-
onstrated   to be  free  from  interferences
  J Analytical protocol for determination of
chlorinated dibenzo-p-dioxins and chlorinat-
ed dibenzofurans in river water. T.O.  Tier-
nan  and  M.  Taylor. Brehm Laboratory,
Wright State University, Dayton, OH 45435.
  4 In general, the techniques that should be
used to handle these materials are those
which  are followed for radioactive or infec-
tious  laboratory materials.  Assistance in
evaluating laboratory  practices  may be ob-
tained  from  industrial hygienists  and  per-
sons specializing in  safe laboratory  prac-
tices. Typical infectious waste incinerators
are probably not satisfactory devices for dis-
posal of materials highly contaminated with
CDDs or CDFs. Safety instructions are out-
lined in EPA Test Method 613(4.0)
  See also: (1) "Program for monitoring po-
tential contamination  in the laboratory fol-
lowing the handling and analyses of chlorin-
ated dibenzo-p-dioxins and dibenzofurans"
by F. D. Hileman et al., In: Human and En-
vironmental  Risks  of Chlorinated Dioxins
and Related Compounds, R.E. Tucker,  et al,
eds., Plenum  Publishing  Corp.,  1983. 2)
Safety procedures outlined in EPA Method
613,  Federal  Register volume 44, No.  233,
December 3, 1979.
under the conditions of the analysis by run-
ning  method  blanks.  Specific selection of
reagents and purification of solvents by dis-
tillation in all-glass  systems  may be  re-
quired.
  3.2  Interferences co-extracted from the
samples will vary considerably from source
to source, depending  upon the diversity of
the industry being sampled. PCDD is often
associated with other interfering chlorinat-
ed compounds such as PCB's which may be
at concentrations several orders of magni-
tude higher than that of PCDD. While gen-
eral cleanup techniques are provided as part
of this method, unique samples may require
additional  cleanup  approaches  to achieve
the sensitivity stated in Table 1.

 TABLE  1—GAS CHROMATOGRAPHY OF TCDD
Column
Glass capillary 	

Reten-
tion time
(min.)
9.5

Detec-
tion limit
(ng/kg)'
0.003

  1 Detection limit for liquid samples is 0.003 /ig/l. This is
calculated from the minimum detectable GC response being
equal to five times the GC background noise assuming a 1
ml effective final volume of the 1 liter sample extract, and a
GC injection of 5 microliters. Detection levels apply to both
electron  capture and  GC/MS detection. For further details
see 44 FR 69526 (December 3, 1979).

  3.3  The other isomers of tetrachlorodi-
benzo-p-dioxin may interfere with the meas-
urement of 2,3,7,8-TCDD. Capillary column
gas chromatography is required to resolve
those isomers that yield virtually identical
mass fragmentation patterns.
  4. Apparatus and Materials
  4.1.   Sampling equipment for discrete or
composite sampling.
  4.1.1  Grab sample bottle—amber glass, 1-
liter or 1-quart  volume. French or Boston
Round design is  recommended. The contain-
er must be washed and solvent rinsed before
use to minimize interferences.
  4.1.2.  Bottle caps—threaded  to  screw on
to the sample bottles. Caps must be lined
with Teflon. Solvent washed foil, used with
the shiny side towards the sample, may be
substituted for the Teflon if sample  is not
corrosive.
  4.1.3. Compositing equipment—automatic
or manual composing system. No tygon or
rubber tubing may be used,  and the system
must  incorporate  glass  sample containers
for the collection of a minimum of 250 ml.
Sample containers must be  kept refrigerat-
ed after sampling.
  4.2  Water bath—heated,  with concentric
ring cover, capable  of temperature control
(±2 °C). The bath should be used in a hood.
  4.3  Gas chromatograph/mass spectrome-
ter data system.
  4.3.1  Gas chromatograph: An analytical
system with  a  temperature-programmable

-------
Part 261, App. X
                                            40 CFR Ch. I (7-1.89 Edition)
gas chromatograph and all required accesso-
ries including syringes, analytical columns,
and gases.
  4.3.2  Column: SP-2250 coated on a 30 m
long x  0.25 mm I.D. glass column (Supelco
No. 2-3714  or  equivalent). Glass capillary
column conditions: Helium carrier gas at 30
cm/sec  linear velocity run splitless. Column
temperature is 210 °C.
  4.3.3  Mass spectrometer: Capable of scan-
ning from 35 to 450 amu every 1 sec or less,
utilizing 70 volts (nominal) electron energy
in the electron impact ionization mode and
producing a.mass spectrum which meets all
the criteria in Table 2 when 50 ng of deca-
fluorotriphenyl-phosphine (DFTPP) is  in-
jected through the GC inlet. The  system
must  also be capable of selected ion moni-
toring (SIM) for  at  least  4  ions  simulta-
neously, with a cycle time of 1 sec  or less.
Minimum integration time for SIM is  100
ms. Selected ion monitoring is verified by in-
jecting .015 ng of TCDD Cl37 to give a mini-
mum  signal to noise ratio of 5 to 1 at mass
328.

    TABLE 2—DFTPP KEY IONS AND ION
           ABUNDANCE CRITERIA '
   Mass
       51
       68
       70
      127
      197
      196
      199
      275
      365
      441
      442
      443
                  Ion abundance criteria
30-60% of mass 198.
Less than 2% ol mass 69.
Less than 2% of mass 69.
40-60% of mass 198.
Less than 1% of mass 198.
Base peak, 100% relative abundance.
5-9% of mass 198.
10-30% of mass 198.
Greater than 1% of mass 198.
Present but less than mass 443.
Greater than 40% of mass 198.
17-23% of mass 442
  1 J. W. Eichelberger, L.E. Harris, and W.L. Budde. 1975.
Reference compound to calibrate ion abundance measure-
ment in gas chromatography-mass spectrometry. Analytical
Chemistry 47:995.

  4.3.4  GC/MS  interface:  Any  GC-to-MS
interface  that gives acceptable calibration
points at 50 ng per injection for each com-
pound of interest and achieves  acceptable
tuning  performance criteria  (see  Sections
6.1 through  6.3)  may  be used.  GC-to-MS
interfaces constructed of all glass  or  glass-
lined materials are recommended. Glass can
be deactivated by silanizing with dichlorodi-
methylsilane. The interface must be capable
of transporting at least 10 ng of the compo-
nents of interest from the GC to the MS.
  4.3.5  Data  system:  A  computer system
must be interfaced to the mass spectrome-
ter. The system must  allow the continuous
acquisition and storage on machine-readable
media of all mass spectra obtained through-
out  the duration of the chromatographic
program. The computer must have  software
that can  search any GC/MS data file for
ions of a specific mass and that can plot
such  ion  abundances  versus  time or  scan
number. This type of  plot is defined  as an
Extracted Ion Current Profile (EICP). Soft-
ware  must  also  be able to integrate the
abundance,  in any EICP, between specified
time or scan number limits.
  4.4  Pipettes-Disposable, Pasteur, 150 mm
long x  5 mm ID (Fisher Scientific Co., No.
13-678-6A or equivalent).
  4.5  Flint  glass bottle (Teflon-lined screw
cap).
  4.6  Reacti-vial (silanized) (Pierce  Chemi-
cal Co.).
  5. Reagents
  5.1  Potassium   hydroxide-(ACS),  2% in
distilled water.
  5.2  Sulfuric acid-(ACS), concentrated.
  5.3  Methylene chloride, hexane, benzene,
petroleum ether, methanol, tetradecane-pes-
ticide quality or equivalent.
  5.4  Prepare  stock standard  solutions of
TCDD  and  "Cl-TCDD (molecular  weight
328) in  a glove box. The stock solutions are
stored in a glovebox, and checked frequent-
ly for signs of degradation  or  evaporation,
especially just prior to  the preparation of
working standards.
  5.5  Alumina-basic, Woelm; 80/200 mesh.
Before use activate overnight at 600*C, cool
to room temperature in a dessicator.
  5.6  Prepurified nitrogen gas
  6.0  Calibration
  6.1  Before using any cleanup  procedure,
the analyst  must process a series of calibra-
tion standards through  the procedure to
validate elution patterns and the absence of
interferences from reagents.
  6.2  Prepare  GC/MS calibration stand-
ards for the  internal  standard technique
that will allow for measurement of relative
response factors  of at least  three CDD/
"CDD  ratios. Thus,  for TCDDs, at  least
three TCDD/"C1-TCDD and  TCDF/"C1-
TCDF  must  be  determined.8  The   "Cl-
TCDD/F  concentration  in  the  standard
should  be fixed and selected to yield a re-
producible response at  the most sensitive
setting  of the mass spectrometer. Response
factors  for PCDD and  HxCDD may be de-
termined by measuring the response of the
tetrachloro-labelled compounds relative to
                                    8 "Cl-labelled  2,3,7,8-TCDD  and  2,3,7.8-
                                  TCDF are available from K.O.R. Isotopes.
                                  and  Cambridge Isotopes,  Inc.,  Cambridge,
                                  MA. Proper standardization requires the use
                                  of a specific labelled isomer for each conge-
                                  ner to be determined. However,  the only la-
                                  belled isomers  readily available  are  "Cl-
                                  2.3,7.8-TCDD and  "Cl-2,3,7,8-TCDF. This
                                  method therefore uses these isomers  as sur-
                                  rogates  for  the CDDs  and CDFs.  When
                                  other  labelled CDDs and CDFs are avail-
                                  able, their use will be required.

-------
Environmental  Protection Agency
                       Part 261, App. X
that  of  the unlabelled  1,2,3,4- or  2,3,7,8-
TCDD,   1,2,3,4,7-PCDD   or   1,2,3,4,7,8-
HxCDD, which are commercially available.6
  6.3  Assemble the necessary  GC/MS ap-
paratus and establish operating parameters
equivalent to those indicated in Section 11.1
of  this  method.  Calibrate  the  GC/MS
system  according  to  Eichelberger,  et  al.
(1975) by the use of decafluorotriphenyl
phosphine (DFTPP). By injecting calibra-
tion standards, establish the response fac-
tors for CDDs vs. "Cl-TCDD, and for CDPs
us.  "Cl-TCDF. The detection limit provided
in Table 1 should  be  verified  by  injecting
.015 ng of "Cl-TCDD  which should  give a
minimum signal to noise ratio  of 5  to 1 at
mass  328.
  7. Quality Control
  7.1  Before  processing any samples, the
analyst should  demonstrate through  the
analysis of a distilled water method  blank,
that all glassware and reagents are interfer-
ence-free. Each time a set of samples is ex-
tracted, or there  is a change in reagents, a
method blank should be processed as a safe-
guard against laboratory  contamination.
  7.2  Standard quality assurance  practices
must  be used with this method. Field repli-
cates  must be collected to measure the pre-
cision of the sampling  technique. Laborato-
ry replicates must be analyzed to  establish
the precision of the analysis. Fortified sam-
ples must be analyzed to establish the accu-
racy of the analysis.
  8. Sample  Collection,  Preservation, and
Handling
  8.1  Grab  and composite samples must be
collected in glass containers. Conventional
sampling  practices should be followed,
except  that  the  bottle  must  not  be
prewashed with  sample  before collection.
Composite samples should  be  collected in
glass  containers in  accordance with  the re-
quirements  of the RCRA  program. Sam-
pling  equipment must  be free of tygon and
other potential sources of contamination.
  8.2  The samples  must be  iced or refriger-
ated from the time of collection until ex-
traction. Chemical preservatives should not
be used  in  the field unless more than 24
hours will elapse before delivery  to the labo-
ratory. If an aqueous  sample is taken and
the sample will not be extracted within 48
hours of collection, the sample should  be
adjusted to a pH range of 6.0-8.0  with
sodium hydroxide or sulf uric acid.
  • This procedure is adopted because stand-
ards are not available for most of the CDDs
and  CDFs, and assumes that all the con-
geners will show the same response as the
unlabelled congener used as a standard. Al-
though this assumption may not be true in
all cases, the error will be small.
  8.3 All samples must be extracted within
7 days  and completely analyzed within 30
days of collection.
  9. Extraction and Cleanup Procedures
  9.1 Use an aliquot of 1-10 g sample of the
chemical waste or soil to be analyzed.  Soils
should  be dried using a stream of prepuri-
fied  nitrogen and pulverized in a ball-mill or
similar  device. Perform this operation in a
clear area with proper hood space. Transfer
the  sample to a  tared 125  ml flint  glass
bottle  (Teflon-lined screw cap) and deter-
mine the weight of the sample. Add an ap-
propriate  quantity of "Cl-labelled 2,3,7,8-
TCDD (adjust the quantity according to the
required  minimum  detectable  concentra-
tion), which is employed as  an internal
standard.
  9.2  Extraction
  9.2.1   Extract chemical waste  samples by
adding  10  ml methanol,  40  ml petroleum
ether, 50 ml doubly distilled water, and  then
shaking the mixture for 2 minutes.  Tars
should be completely dissolved in any of the
recommended  neat   solvents.   Activated
carbon samples must be extracted with ben-
zene using  method 3540  in  SW-846  (Test
Methods for Evaluating Solid Waste—Physi-
cal/Chemical   Methods,   available   from
G.P.O.  Stock #055-022-81001-2). Quantita-
tively transfer  the organic extract or dis-
solved sample to a clean 250 ml flint glass
bottle (Teflon lined screw cap), add 50 ml
doubly distilled water and shake for  2  min-
utes. Discard the aqueous layer and proceed
with Step 9.3.
  9.2.2   Extract soil samples by adding 40
ml of petroleum  ether  to the sample, and
then shaking for 20 minutes. Quantitatively
transfer the organic extract to a clean 250
ml  flint glass  bottle (Teflon-lined screw
cap), add  50 ml doubly distilled water and
shake for 2 minutes. Discard the aqueous
layer and proceed with Step 9.3.
  9.3  Wash the organic layer with 50 ml of
20%  aqueous potassium hydroxide by shak-
ing for 10  minutes and then remove and dis-
card the aqueous layer.
  9.4  Wash the organic layer with 50 ml of
doubly distilled water by shaking for 2  min-
utes, and discard the aqueous layer.
  9.5  Cautiously add  50  ml concentrated
sulfuric acid and  shake  for 10 minutes.
Allow the mixture to stand until layers sep-
arate  (approximately  10  minutes),  and
remove  and discard the acid layer. Repeat
acid  washing until no color is visible in the
acid layer.
  9.6  Add 50 ml of doubly distilled water to
the organic extract and shake for 2 minutes.
Remove and discard the aqueous layer and
dry the organic layer by adding lOg of anhy-
drous sodium sulf ate.
  9.7  Concentrate the extract  to incipient
dryness by  heating in a 55*  C water  bath
and simultaneously flowing a stream of pre-

-------
Port 261, App. X
          40 CFR Ch. I (7-1-89 Edition)
purified nitrogen over the extract. Quanti-
tatively transfer the residue to an alumina
microcolumn fabricated as follows:
  9.7.1 Cut off the top section  of a  10 ml
disposable Pyrex pipette at the 4.0 ml mark
and insert a plug of silanized glass wool into
the tip of the lower portion of the pipette.
  9.7.2 Add  2.8g of  Woelm basic alumina
(previously  activated  at 600'  C  overnight
and then cooled to room  temperature in  a
desiccator just prior to use).
  9.7.3 Transfer  sample  extract  with  a
small volume of methylene chloride.
  9.8  Elute the microcolumn with 10 ml of
3% methylene  chloride-in-hexane followed
by  15 ml  of 20% methylene chloride-in-
hexane and  discard  these effluents.  Elute
the column with 15 ml of 50% methylene
chloride-in-hexane and concentrate this ef-
fluent (55°  C water bath, stream of prepuri-
fied nitrogen) to about 0.3-0.5 ml.
  9.9  Quantitatively  transfer the residue
(using methylene chloride to rinse the con-
tainer)  to  a silanized Reacti-Vial (Pierce
Chemical Co.). Evaporate,  using a stream of
prepurified  nitrogen,  almost  to dryness,
rinse  the walls of the vessel with approxi-
mately 0.5 ml methylene chloride, evaporate
just  to  dryness, and  tightly cap the vial.
Store the  vial at 5* C  until analysis,  at
which time the sample is reconstituted by
the addition of tridecane.
  9.10  Approximately 1  hour before  GC-
MS (HRGC-LRMS) analysis, dilute the resi-
due in the micro-reaction vessel with an ap-
propriate  quantity  of tridecane. Gently
swirl the tridecane on the lower portion of
the vessel to ensure dissolution of the CDDs
and CDPs. Analyze a sample by GC/EC to
provide insight into the complexity of  the
problem, and to determine  the  manner in
which the  mass  spectrometer  should be
used.  Inject  an appropriate aliquot  of  the
sample into the GC-MS instrument, using a
syringe.
  9.11  If, upon preliminary GC-MS analy-
sis, the sample appears to contain interfer-
ing substances which obscure  the analyses
for  CDDs and CDFs,  high performance
liquid chromatographic (HPLC) cleanup of
the extract is accomplished, prior to further
GC-MS analysis.
  10. HPLC Cleanup Procedure''
  10.1  Place approximately 2 ml of hexane
in a 50 ml flint glass sample bottle fitted
with a Teflon-lined cap.
  10.2  At the  appropriate  retention time,
position  sample bottle  to  collect the re-
quired fraction.
  10.3  Add  2 ml of 5% (w/v) sodium car-
bonate to the sample fraction collected and
shake for one minute.
  10.4  Quantitatively  remove the hexane
layer (top layer) and transfer to a micro-re-
action vessel.
  10.5  Concentrate the fraction to dryness
and retain for further analysis.
  11. GC/MS Analysis
  11.1  The following column conditions are
recommended: Glass capillary column con-
ditions:  SP-2250 coated  on  a 30 m long  x
0.25  mm I.D. glass column (Supelco No. 2-
3714, or equivalent) with helium carrier gas
at 30 cm/sec linear velocity, run splitless.
Column temperature is 210°C. Under these
conditions the retention time for TCDDs is
about_ 9.5 minutes.  Calibrate the system
daily with, a minimum, three injections of
standard mixtures.
  11.2  Calculate response factors for stand-
ards relative to "Cl-TCDD/F (see Section
12).
  11.3  Analyze  samples with selected  ion
monitoring of at least two ions from Table
3.  Proof of  the presence of CDD  or CDF
exists if the following conditions are met:
  11.3.1   The retention time  of the peak in
the sample must match that in the stand-
ard,  within  the performance specifications
of the analytical system.
  11.3.2   The  ratio  of  ions must  agree
within 10% with that of the standard.
  11.3.3   The retention  time of the peak
maximum for the  ions of interest must ex-
actly match that of the peak.
  1 For cleanup see also method #8320 or
#8330, SW-846. Test Methods for Evaluat-
ing Solid Waste, Physical/Chemical Meth-
ods (1982).

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Environmental Protection Agency
                       Port 261, App. X
TABLE 3—LIST OF ACCURATE MASSES  MONITORED USING GC SELECTED-ION MONITORING, Low
  RESOLUTION, MASS SPECTROMETRY  FOR SIMULTANEOUS DETERMINATION OF TETRA-, PENTA-,
  AND HEXACHLORINATED DIBENZO-P-DIOXINS AND DIBENZOFURANS


Class of chlorinated dibenzodioxm or dibenzofuran






Penta 	

Hexa 	


Number
ril
chlorine
substit-
uents (x)

4




5

6


Monitored m/z
for
dibenzodioxins
C»H,-,0,\t

1 319 897
321.894
2 327 885
3 256 933
3 258 930
1 353 858
355855
389816
391.813

Monitored m/z
for
dibenzofurans
C.iH.-.OCl,

i 303 902
305.903
2 31 1.894


i 337 863
339.860
373 821
375.818
Approxi-
mate
theoretical
ratio
expected
on basis of
isotopic
abundance
0 74
1.00

0 21
020
0 57
1.00
1 00
0.87
  1 Molecular ion peak.
  2 Cl<—labelled standard peaks.
  3 Ions which can be monitored in TCDD analyses for confirmation purposes
  11.4  Quantitate the CDD and CDF peaks
from  the response relative to the    "Cl-
TCDD/F  internal standards.  Recovery  of
the internal standard  should be  greater
than 50 percent.
  11.5  If  a response is obtained for the ap-
propriate  set of ions, but is outside the ex-
pected ratio, a co-eluting impurity may  be
suspected. In this case,  another set of ions
characteristic  of  the CDD/CDF molecules
should  be analyzed.  For  TCDD a good
choice of  ions is m/e 257 and m/e 259. For
TCDF a good choice of  ions is m/e 241 and
243. These ions are useful in characterizing
the molecular structure to TCDD or TCDF.
For analysis of TCDD good analytical tech-
nique would require using all four ions, m/e
257, 320,  322, and 328,  to  verify  detection
and signal to noise ratio of 5 to 1. Suspected
impurities such as DDE, DDD, or PCB resi-
dues can be confirmed by checking for their
major fragments.  These materials can be re-
moved by the cleanup columns. Failure  to
meet  criteria  should  be explained  in the
report, or the sample reanalyzed.
  11.6  If  broad background interference re-
stricts the sensitivity of the GC/MS analy-
sis, the analyst should  employ cleanup pro-
cedures and reanalyze by GC/MS. See sec-
tion 10.0.
  11.7  In those circumstances where these
procedures do not yield a definitive conclu-
sion, the use of high resolution mass spec-
trometry is suggested.
  12. Calculations
  12.1  Determine the concentration of indi-
vidual compounds according to the formula:
                               AxA,
   Concentration, >i.g/gm =
where:
A=fig  of  internal standard added to the
   sample •
G = gm of sample extracted
A.=area of  characteristic ion  of the com-
   pound being quantified.
AH=area of  characteristic ion  of the inter-
   nal standard
R,=response factor»
  Response factors are calculated using data
obtained from the analysis  of standards ac-
cording to the formula:
              Rf
A.xCu

AuxC.
where:
  'The  proper  amount of standard to be
used  is determined  from the calibration
curve (See Section 6.0).
  'If   standards  for   PCDDs/Fs   and
HxCDDs/Fs are not available, response fac-
tors for ions derived from these congeners
are calculated relative to J1C1-TCDD/F. The
analyst may use response factors for 1,2,3,4-
or   2.3.7.8-TCDD,    1,2,3,4,7-PeCDD,   or
1,2,3,4.7,8-HxCDD   for   quantitation  of
TCDDs/Fs,  PeCDDs/Fs  and HxCDDs/Fs,
respectively. Implicit in this requirement is
the assumption  that the  same response is
obtained from  PCDDs/Fs ccontaining the
same numbers of chlorine atoms.

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Part 261, App. X                                   40 CFR Ch. I (7-1-89 Edition)

Cu=concentration of the internal standard    When duplicate and spiked samples are ana-
Ce=concentration  of  the  standard  com-  lyzed. all data obtained should be reported.
    pound                                   12.3  Accuracy and Precision. No data are
  12.2  Report  results  in micrograms per  available at this time.
gram without correction  for recovery  data.  [50 FR 2001, Jan. 14, 1985]

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VIII. Reprint of Toxicity Characteristic Rule &

    Correction Notice from the Federal Register
                                           Thursday
                                           March 29 1990
                                           Part II
                                           Environmental

                                           Protection  Agency

                                           40 CFR Part 261 et al.
                                           Hazardous Waste Management System;
                                           Identification and Listing of Hazardous
                                           Waste; Toxicity Characteristics Revisions;
                                           Final Rule

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11862      Federal Register  /  Vol. 55. No. 61  /  Thursday. March  29.  1990  /  Rules  and Regulations
PART 261—IDENTIFICATION AND
LISTING OF HAZARDOUS WASTE

  1. The authority citation for part 261
continues to read as follows:
  Authority: 42 U.S.C. 6905. 6912(a). 6921. and
6922.
  2. Section 261.4 is amended by
revising paragraphs (b)(6)(i)
introductory text, and (b)(9) and by
adding paragraph (b)(10) to read as
follows:

§ 261.4  Exclusions.

  (b) '  ' '
  (6)(i) Wastes which fail the test for the
Toxicity Characteristic because
chromium is present or are listed in
su'opart D due to the presence of
chromium, which do not fail the test for
the Toxicity Characteristic for any other
constituent or are not listed due to the
presence of any other constituent, and
which do not fail the test for any other
characteristic, if it is shown by a  waste
generator or by  waste generators that:

   (9) Solid waste which consists  of
discarded wood or wood products
which fails the test for the Toxicity
Characteristic solely for arsenic and
which is not a hazardous waste for any
other reason or  reasons, if the waste is
generated by persons who utilize the
arsenical-treated wood and wood
products for these materials' intended
end use.
   (10) Petroleum-contaminated media
and debris that  fail the test for the
Toxicity Characteristic of § 261.24 and
are subject to the corrective action
regulations under part 280 of this
chapter.
  3. Section 261.8 is added to subpart A
to read as follows:

§261.8  PCS Wastes Regulated Under
Toxic Substance Control Act
  The disposal of PCB-containing
dielectric fluid and electric equipment
containing such fluid authorized for- use
and regulated under part 761 of this
chapter and that are hazardous only
because they fail the test for the
Toxicity Characteristic (Hazardous
Waste Codes D018 through D043 only)
are exempt from regulation under parts
261 through  265, and parts 268, 270, and
124 of this chapter, and the notification
requirements of section 3010 of RCRA.
  4. Section 261.24 is revised to read as
follows:

§261.24  Toxicity characteristic.
  (a) A solid waste exhibits  the
characteristic of toxicity if. using the test
methods described in Appendix II or
equivalent methods approved by the
Administrator under the procedures set
forth in §§ 260.20 and 260.21, the extract
from a representative sample of the
waste contains any of the contaminants
listed in Table 1 at the concentration
equal to or greater than the respective
value given in that Table. Where the
waste contains less than 0.5  percent
filterable solids, the waste itself, after
filtering using the methodology outlined
in Appendix II, is considered to be the
extract for the purpose of this section.
  (b) A solid waste that exhibits the
characteristic of toxicity, but is not
listed as a hazardous waste  in subpart
D, has  the EPA Hazardous Waste
Number specified in Table 1  which
corresponds to the toxic contaminant
causing it to be hazardous.
TABLE 1.—MAXIMUM CONCENTRATION OF
  CONTAMINANTS   FOR  THE  TOXICITY
  CHARACTERISTIC
• EPA
HW
1 No.1
D004
D005
D018
DOG6
1 D019
D020
! D02t
DC22
D007
! D023
D024
' D025
! D026
DQ16
DG27
! D028
D029
DC30
DC12
D031
D032
C033
D034
COOS
C013
D009
C014
D035
0036
D037
C038
D010
DC11
D039
D015
D040
D041
C042
D017
0043
: Contaminant
Arsenic
Banum
Benzene 	
Cadmium 	
Carbon
tetrachloride
Chlordane 	
Chlorobenzene 	
Chloroform
Chromium . . .
o-Cresol 	
•n-Cresol 	
p-Cresol
Oesol
2.4-D 	
1.4-
Oichloroben-
zene.
1.2-
Dichloroeth-
ane.
1,1-
Dichloroethy-
lene.
2.4-
Dimtrotoluene.
Endnn
Heptachlor (and
its hydroxide).
Hexachloroben-
zene.
Hexachlorobuta-
diene.
Hexachloroeth-
ane.
Lead 	
Lindane
Mercury 	
Methoxychlor 	
Methyl ethyl
ketone.
Nitrobenzene 	
Pentrachloro-
phenol.
Pyndine 	
Selenium
Silver 	
Tetrachloroethyl-
ene.
Toxaphene 	
Trichloroethyl-
ene.
2,4.5-
Tnchloro-
phenol.
2.4.6-
Tnchlorc-
phenol.
2.4.5-TP (Silvex)...
Vinyl chloride 	
CAS No 2
7440-38-2
7440-39-3
71-43-2
7440-43-9
56-23-5
57.74-0
108-90-7
67-66-3
7440-47-3
95-48-7
108-39-4
106-44-5

94-75-7
106-46-7
107-06-2
75-35-4
121-14-2
72 20-8
76-44-8
118-74-1
87-68-3
67-72-1
7439-92-1
58-89-9
7439-97-6
72-43-5
78-93-3
98-95-3
87-86-5
110-86-1
7782-49-2
7440-22-4
127-18-4
8001-35-2
79-01-6
95-95-4
88-06-2
93-72-1
75-01-4
Regula-
tory
Level
(mg/L)
50
1000
05
1 0
05
003
100.0
60
50
4 2000
•200.0
•2000
4 2000
100
75
05
0.7
0.13
002
1.0C8
013
05
3.0
50
0.4
02
100
200.0
2.0
100.0
"5.0
1.0
5.0
0.7
0.5
0.5
400.0
20
1.0
0.2
                                                                                   ' Hazardous waste number.
                                                                                   - Chemical abstracts service number.
                                                                                   ' Quantitation  limit is greater than the calculated
                                                                                 regulatory level.  The quantitation limit therefore be-
                                                                                 comes the regulatory level.
                                                                                   * If o-. n>. and p-Cresol concentrations cannot be
                                                                                 differentiated. th« total cresol (D026) concentration
                                                                                 is used. The regulatory level of total cresol is 200
                                                                                 mg/l.

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	Federal Register  /  Vol. 55.  No. 61  /  Thursday. March 29. 1990  /  Rules  and  Regulations     H863


  5. Section 261.30 is amended by          employing one or more of the following    Appendix VII identifies the constituent
revising paragraph (b) to read as           Hazard Codes:                           which caused the Administrator to list
follows:                                                                         the waste as a Toxicity Characteristic
S 261.30  General.                         Ignitable Waste	  ;I)     Waste (E) or Toxic Waste (T) in
'.....                    Corrosive Waste	 id     §§ 261.31 and 261.32.
                                        Peactive Waste	 (R)     .....
  (b) The Administrator will indicate his   Toxicity Characteristic Waste	 (E)
basis for listing the classes or types of      Acute Hazardous Waste	 (H)
wastes listed in this subpart by            Toxic Waste	 (T)

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Friday
June 29, 1990
Part V



Environmental

Protection  Agency

40 CFR Parts 261, 264, 265, 268, 271 and
302
Hazardous Waste Management System;
Identification and Listing of Hazardous
Waste; Toxicity Characteristic Revisions;
Final Rule

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26986
Federal Register / Vol. 55, No.  126 / Friday, June 29,  1990 / Rules and Regulations
ENVIRONMENTAL PROTECTION
AGENCY

40 CFR Parts 261, 264, 265, 268, 271
and 302

[SWH-FRL-3792-2;EPA/OSW-FR-90-014]

RIN 2050-AA78

Hazardous Waste Management
System; Identification and Listing of
Hazardous Waste; Toxicity
Characteristic Revisions

AGENCY: Environmental Protection
Agency.
ACTION: Final rule; corrections.

SUMMARY: On March 29,1990 (55 FR
11798), the Environmentl Protection
Agency (EPA) promulgated a rule to
revise the existing toxicity
characteristics, which are used to
identify those wastes which are
hazardous and thus subject to regulation
under subtitle C of the Resource
Conservation and Recovery Act (RCRA)
due to their potential to leach significant
concentrations of specific toxic
constituents. Since promulgation, the
Agency has found the need to make
corrections to the rule in order to ensure
consistency of the toxicity characteristic
leaching procedure (TCLP), Method
1311, with other methods contained in
Test Methods for Evaluating Solid
Waste (Physical/Chemical Methods),
SW-846 and to clarify the section on
quality assurance. This notice also
corrects several errors in the March 29,
1990 notice.
DATES: Effective date: September 25,
1990. The effective date and compliance
dates are  not changed by this document.
FOR FURTHER INFORMATION CONTACT:
For general information about this
notice, contact the RCRA/Superfund
Hotline at (800) 424-9348 (toll free) or
(202) 382-3000 in the Washington, DC
metropolitan area. For information on
specific aspects  of this notice, contact
Steve Cochran, Office of Solid Waste
(OS-332), U.S. Environmental Protection
Agency, 401 M Street SW, Washington,
DC 20460, (202) 475-8551.
I. SUPPLEMENTARY INFORMATION:
A. Background
  On March 29,1990 (55 FR 11798), EPA
promulgated a rule to revise the existing
toxicity characteristics, which are used
to identify those wastes which are
hazardous and thus subject to regulation
under subtitle C of RCRA. The rule
broadened and refined the scope of the
hazardous waste regulatory program
and fulfilled specific statutory mandates
under the Hazardous and Solid Waste
Amendments of 1984.
                            Today's notice makes corrections to
                          appendix II of the regulatory language of
                          the March 29,1990 final rule, Method
                          1311, the TCLP. The method has been
                          reorganized to correspond to the current
                          version of Test Methods for Evaluating
                          Solid Waste (Chemical/Physical
                          Methods), SW-846. In addition, the
                          quality assurance section has been
                          renumbered and has been clarified to
                          eliminate confusion. Today's notice also
                          corrects several typographical errors
                          and other omissions that appeared in
                          the final rule revising the toxicity
                          characteristics.
                            The preamble to the March 29,1990
                          final rule stated that any person that
                          would like to use the TCLP before the
                          effective date of the rule (September 25,
                          1990) may do so in order to determine
                          whether the eight heavy metals and six
                          pesticides that are currently regulated
                          under the Extraction Procedure (EP)
                          Toxicity Characteristic leach at levels of
                          regulatory concern. This language was
                          included because the TCLP is required
                          for both waste determination (on
                          September 25,1990, the TC effective
                          date) and the land disposal restrictions
                          program. The Agency today is clarifying
                          that, while it is appropriate to use just
                          one leach test to fulfill both
                          requirements, persons that would like to
                          continue using the EP leach test until the
                          effective date of the TC rule may do so.
                          It should be noted, however, that the EP
                          test may still be required as a matter of
                          state Law,  and this regulation does not
                          affect such state law requirements.
                          B. Method 1311 and Quality Assurance
                            Today's notice makes technical
                          corrections to mistakes made in Method
                          1311, and to errors made during
                          typesetting, and provides clarifications
                          to specific procedures of the method.
                          The method also is being reorganized by
                          placing the leaching procedure in one
                          section and the quality assurance in a
                          separate section to conform with the
                          format used in SW-846.
                            A correction is being made in the
                          calculation for the weight of waste to
                          charge the Zero-Headspace Extractor
                          (ZHE). In the final rule published March
                          29,1990, the method incorrectly stated
                          that the optimum sample size to charge
                          into the ZHE should be determined for
                          wastes containing >0.5% solids. This
                          calculation results in a charge sample
                          greater than the capacity of the ZHE.
                          The Agency today is correcting the
                          procedure to require a determination on
                          wastes containing >5% solids. The
                          sample holding times and errors made
                          during typesetting are also being
                          corrected by today's notice.
                            The Agency received inquiries
                          indicating that confusion exists
concerning correction factors and ho-.v
they should be applied. Therefore, the
Agency is making a technical correction
in } 8.2.5 of Method 1311. published in
today's notice, by adding a formula for
correcting measured values for
analytical bias. Also, inquiries indicate
that EPA's discussion of the appropriate
GC and GC/MS methods to be used was
improper. The preamble language is
corrected by today's notice to indicate
the appropriate GC and GC/MS
methods to be used.
  Method 1311 is also being reorganized
by today's notice by placing the leaching
procedure itself in one section, 7.0. (The
steps of the leaching procedure were
previously presented in sections 7, 8,
and 9 in the March 29,1990 final rule.) In
addition, this notice makes minor
corrections to the quality assurance
section and it is renumbered 8.0. This
reorganization provides consistency
with SW-846.
  Appendix II. Method 1311 of the
March  29,1990 final rule is replaced in
its entirety by Method 1311 of this notice
in order to incorporate the corrections,
reorganizations, and clarifications
which are being made by today's notice.
  The March  29,1990 final rule provided
an exclusion under 40 CFR 261.4 for
petroleum-contaminated media and
debris that fail the Toxicity
Characteristic. This exclusion applies
only to petroleum-contaminated media
and debris which exhibit the TC for any
one or more of the newly identified
organic constituents, and which are
subject to corrective action under part
280. The regulatory language of this
exclusion in the final rule is revised by
today's notice to correctly reflect this
application.

C Corrections
  1. On page 11798, column one, under
"DATES," in the second line of the
compliance dates paragraph, change
"generators: September 25,1990. Small"
to "generators and treatment, storage,
and disposal facilities (TSDFs):
September 25,1990. Small".
  2. On page 11804, Table 11.2—Toxicity
Characteristics Constitutents and
Regulatory Levels, change the column
beading "Constituent (mg/L)" to
"Constituent".
  3. On page 11804, Table II.2—Toxicity
Characteristic Constituents and
Regulatory Levels, line twenty, change
"Heptachlor (and its hydroxide)" to
"Heptachlor (and its epoxide)".
  4. On page 11815, column three. Table
C—1—Chronic Toxicity Reference
Levels, lines nineteen and twenty,
change "Heptachlor (and its hydroxide)"
to "Heptachlor (and its epoxide)".

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              Federal  Register /  Vol. 55,  No.  126 / Friday. June  29.  1990  /  Rules  and Regulations
                                                                          26987
   5. On page 11825, column one, fourth
 bullet, first line, change "The data
 extracted from RFSs" to "The data
 extracted from RFAs".
   6. On page 11829, columnn one, the
 first full paragraph (lines twenty-four)
 through thirty-six) is replaced by the
 following: "The Agency agrees that the
 GC method (Method 8040) or the GC/MS
 method (Method 8270) for phenols and
 the GC/Electron Capture Detection
 (GC/ECD) for phenoxyacid herbicides
 (Method 8150) are more advantageous
 for the analysis of these analytes
 because the equipment is more readily
 available than the HPLC, despite the
 associated difficulties. HPLC methods
 for phenols and phenoxyacid herbicides
 are not included in the third edition of
 SW-846 because of a lack of validation
 data. The Agency will allow only the
 use of the previously mentioned GC and
 GC/MS methods (Methods 8040 or 8270)
 or their equivalents for phenols and
 Method 8150 for phenoxyacid herbicides
 until auch time that the Agency proposes
 an HPLC method."
   7. On page 11831, column two,
 paragraph b, seventh line, change "rule
 of 40 CFR 262.3(a)(2)(iv) or the" to "ruls
 of 40 CFR 261.3(a)(2)(iv) or the".
   8. On page 11S35, column one. first
 and second line, change "July 25,1985"
 to "July 15,1985".
   9. On page 11837, column one, third
 complete paragraph, thirteenth line,
 change "for TSDFs on February 5,1987
 (53 FR" to "for TSDFs on February 5,
 1987 (52 FR".
   10. On page 11840, column three, first
 bullet of second complete paragraph,
 first line, change "Solid waste that is a
 hazardous waste" to "Used oil that is a
 hazardous waste".
   11. On page 11844, Table IV-1.—TC
 Constituent and Regulatory Levels
 Proposed June 13.1986—Continued,
 fourth line, change the CASNO for D034
 from "76-44-2" to "76-44-8".
   12. On page 11844. Table IV-1.—TC
 Constituent and Regulatory Levels
 Proposed June 13.1986—Continued, line
 twenty-one, change to read as follows:
 D045.... 1,1.1.2-Tetrachloroethane
 . . .  . 630-20-«.  . . .10.0.
   13. On page 11844, column two, Table
 IV-2.—Organic Constituents, fourth line,
 change the CASNO for D021 from "106-
 90-7" to "108-90-7".
  14. On page 11844, column three,
 Table IV-2.—Organic Constituents-
 Continued, first line, change "D031....
 Heptachlor (and its hydroxide).... 76-
44-2" to "D031.... Heptachlor (and its
 epoxide). . . .76-44-8".
  15. On page 11846. Table FV-3—
Toxicity Characteristic Constituents and
Regulatory Levels—Continued, tenth
line, change "Heptachlor (and its
.hydroxide)'1 to "Heptachlor (and its
epoxide)".
  16. Also on page 11846, column two,
third line, change "270 of chapter 40." to
"270 of title 40.".

PART261-CAMENDED]

§261.4  [Corrected]
  17. On page 11862, column two, in
§ 261.4 paragraph  (b)(10), is corrected to
read as follows:
  10. Petroleum-contaminated media
and debris that fail the test for the
Toxicity Characteristic of § 261.24
(Hazardous Waste Codes D018 through
D043 only) and are subject to the
corrective action regulations under part
280 of this chapter.

§ 261.24  [Corrected]
  18. Also on page 11862, column three,
in §  261.24 Table 1.—Maximum
Concentration of Contaminants for the
Toxicity Characteristic, lines twenty-
eight and twenty-nine, change
"Heptachlor (and its hydroxide)" to
"Heptachlor (and its epoxide)"

PART 271—[AMENDED]

§ 271.1  [Corrected]
  19. On page 11876, in § 271.1 (j) Table
1—Regulations Implementing the
Hazardous and Solid Waste
Amendments of 1984, the Federal
Register reference should be "55 FR
11798-11877".

PART 302—[AMENDED]

§302.4  [Corrected]
  20. On page 11877, in § 302.4, Table
302.4, List of Hazardous Substances and
Reportable Quantities, in the first
column, make the following corrections:
  A. In the ninth line, change
"Heptachlor (and hydroxide) (D031)" to
"Heptachlor (and epoxide) (D031)."
  B. In line twenty-five, change
"Thrichloroethylene (D040)" to
"Trichloroethylene (D040)".
  C. In line twenty-six, change "2,4,5-
Trichlorethylene (D041)" to "2,4,5-
Trichlorophenol (D041)".
  Dated: June 22,1990.
Mary A. Cade,
Acting Assistant Administrator,
  In addition to the corrections made
above, part 261 is amended by revising
appendix II to read as follows:

Ap  endix II—Method 1311 Toxicity
Characteristic Leaching Procedure
(TCLP)

1.0  Scope and Application
  1.1  The TCLP is designed to determine the
mobility of both organic and inorganic
 analytes present in liquid, solid, end
 multiphasic wastes.
  1.2 If a total analysis of the waste
 demonstrates that individual analytes are nul
 present in the waste, or that they are present
 but at such low concentrations that the
 appropriate regulatory levels could not
 possibly be exceeded, the TCLP need not be
 run.
  1.3 If an analysis of any one of the liquid
 fractions of the TCLP extract indicates that a
 regulated compound is present at such high
 concentrations that, even after accounting for
 dilution from the other fractions of the
 extract, the concentration would be equal !o
 or above the regulatory level for that
 compound, then the waste is hazardous and it
 is not necessary to analyze the remaining
 fractions of the extract.
  1.4  If an analysis of extract obtained
 using a bottle extractor shows that the
 concentration of any regulated volatile
 analyte equals or exceeds the regulatory
 level for that compound, then the waste is
 hazardous and extraction using the ZHE is
not necessary. However, extract from a bottle
extractor cannot be used to demonstrate that
 the concentration of volatile compounds is
 below the regulatory level.

2.0  Summary of Method
  2.1  For liquid wastes (i.e., those
containing less than 0.5% dry solid material),
the waste, after filtration through a 0.8 to 0.6
fim glass fiber filter, is defined as the TCLP
extract.
  2.2  For wastes containing greater than or
equal to 0.5% solids, the liquid, if any. is
separated from the solid phase and stored for
later analysis; the particle size of the solid
phase is reduced, if necessary. The solid
phase Is extracted with an amount of
extraction fluid equal to 20 times the weight
of the solid phase. The extraction fluid
employed is a function of the alkalinity of the
solid phase of the waste. A special extractor
vessel is used when testing for volatile
analytes (see Table 1 for a list of volatile
compounds). Following extraction, the liquid
extract is separated from the solid phase by
filtration through a 0.6 to 0.8 /im glass fiber
filter.
  2.3  If compatible (i.e., multiple phases will
not form on combination), the initial liquid
phase of the waste is added to the liquid
extract, and these are analyzed together. If
incompatible, the liquids are analyzed
separately and the results are mathematically
combined to yield a volume-weighted
average concentration.

3.0  Interferences
  3.1  Potential interferences that may be
encountered during analysis are discussed in
 the individual analytical methods.

4.0  Appara tus and Ma terials
  4.1  Agitation apparatus: The agitation
 apparatus must be capable of rotating the
extraction vessel In an end-over-end fashion
 (see Figure 1) at 30 ±2 rpm. Suitable devices
 known to EPA are identified in Table 2.
  4.2  Extraction Vessels.
  4.2.1  Zero-Headspace Extraction Vessel
 (ZHE). This device is for use only when thp
 waste is being tested for the mobility of

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26988	Federal Register  /  Vol.  55. No. 126  / Friday. June 29.  1990 / Rules and Regulations
volatile analytes (i.e., those listed in Table 1).
The ZHE (depicted in Figure 2) allows for
liquid/solid separation within the device, and
effectively precludes headspace. This type of
vessel allows for initial Ikjuid/solid
separation, extraction, and final extract
filtration without opening th« vessel (see
section 4.3.1). Th« vessels shall have an
internal volume of 500-600 mL. and be
equipped to accommodate a 90-110 mm filter.
The devices contain VTTON®' O-rings which
should b« replaced frequently. Suitable ZHE
devices known to EPA are identified in Table
3.
  For the ZKE to be acceptable for use. the
piston within the ZHE should be able to be
moved with approximately 15 pounds per
square inch (psi) or less. If it takes more
pressure to move the piston, the O-rings in
the device she-aid be replaced. If this does cot
solve the problem, the ZHE is unacceptable
for TCLP analyses and the manufacturer
should be contacted.
  The ZHE should be checked for leaks after
every extraction. If the device contains a
built-in pressure gauge, pressurize the device
to 50 psi. allow it to stand unattended for 1
hour, and recceck the pressure. If the device
does not have a  built-in pressure gauge,
pressurize the device to 50 psi, submerge it in
water, and check for the presence of air
bubbles escaping from any of the fittings. If
nressnre is lost check all fittings and inspect
and replace O-rings, if necessary. Retest the
device. IT leakage problems cannot be solved.
the manufacturer should be contacted.
  Some ZHE* ate gas pressure to actuate the
ZHE piston, while others use mechanical
pressure (see Table 3). Whereas the volatiles
procedure* (see  section 7.3) refers to pounds
per square inch (psi). for the mechanically
actuated piston, the pressure applied is
measured in torque-inch-pounds. Refer to the
manufacturer's instructions as to the proper
conversion.
  122  Bottle Extraction Vessel When the
waste is being evaluated using the
nonvolatile extraction, a jar with sufficient
capacity to hold the sample and the
extraction fluid is needed. Headspace is
allowed in this vessel
  The extraction bottles may be constructed
from various materials, depending on the
analytes to be analyzed and the nature of the
waste (see section 4.13). It is recommended
that borosilicate glass bottles be used instead
of other types of glass, especially when
inorganics are of concern. Plastic bottles,
other than polytetrafiuoroethylene, shall not
be used if organics are to be investigated.
Bottles are available from a number of
laboratory suppliers. When this type of
extraction vessel is used, the filtration  device
discussed in section 4.X2 is used for  initial
liquid/solid separation and final extract
filtration.
  4.3  Filtration Devices: It is recommended
that all filtration* be performed in a hood.
  4.3.1  Zero-Headapace Extractor Vessel
(ZHE): When the waste is evaluated for
volatiles. the zero-headspace extraction
vessel described in section 4-2.1 is used for
filtration. The device shall be capable of
supporting and keeping in place the glass
fiber filter and be able to withstand the
pressure needed to accomplish separation (50
psi).
  Note: When it is suspected that the glass
fiber filter has been ruptured, an in-line glass
fiber filter may be used to filter the material
within the ZHE.
  4.3.2  Filter Holder When the waste is
evaluated for other than volatile analytes,
any filter bolder capable of supporting a glass
fiber filter and able to withstand the pressure
needed to accomplish separation may be
used. Suitable filter holders range from
simple vacuum units to relatively complex
systems capable of exerting pressures of up
to 50 psi or more. The type of filter bolder
used depends on the properties of the
material to be filtered (see section 4.3.3).
These devices shall have a minimum internal
volume of 300 mL and be equipped to
accommodate a minimum filter size of 47 mm
(filter holders having an internal capacity of
1.5 L or greater, and equipped to
accommodate a 142 nun diameter filter, are
recommended). Vacuum filtration can only be
used for wastes with low solids content
(<10%) and for highly granular, liquid-
containing wastes. All other types of wastes
should be filtered using positive pressure
filtration. Suitable filter holders known to
EPA are shown in Table 4.
  4.3.3  Materials of Construction:
Extraction vessels and filtration devices shall
be made of inert materials which will not
leach or absorb waste components. Class,
polytetrafluoroethylene (PTFE). or type 318
stainless steel equipment may be used when
evaluating the mobility of both organic and
inorganic components. Devices made of high
density polyethylene (HDPE), polypropylene
(PP), or polyvinyl chloride  (PVC) may be used
only when evaluating the mobility of metals.
Borosilicate glass bottles are recommended
for use over other types of glass bottles,
especially when inorganics are analytes of
concern.
  4.4  Filters: Filters shall be made of
borosilicate glass fiber, shall contain no
binder materials, and shall have an effective
pore size of 0.6 to 0.8 jim. or equivalent
Filters known to EPA which meet these
specifications are identified in Table 5. Pre-
filters most not be used. When  evaluating the
mobility of metals, filters shall  be acid-
washed prior to use by rinsing with IN nitric
acid followed by three consecutive rinses
with deionized distilled water (a minimum of
1 L per rinse is recommended).  Class fiber
filter are fragile and should be handled with
care.
  4.5  pH Meters: T.ie meter should be
accurate to ± 0.05 units at 25°C.
  4.6  ZHE Extract Collection  Devices:
TEDLAR® * bags or glass, stainless steel or
PTFE gag-tight syringes are used to collect
the initial liquid phase and the  final extract of
the waste when using the ZHE device. The
devices listed are recommended for use
under the following conditions:
  4 6.1  If a waste contains an aqueous
liquid phase or if a waste does  not contain a
significant amount of nonaqueous liquid (i.e.,
<1% of total waste), the TEDLAR® bag or a
   1 VITON* b s regl»t»ied tndemari of DuPtmt.
  • TEDLAR® i» • registered trademark of Duponl.
600 mL syringe should be used to collect and
combine the initial liquid and solid extract
  4.6.2  If • waste contains a significant
amount of nonaqueous liquid in the initial
liquid phase (i.e^ >1% of total waste), the
syringe or the TEDLAR® bag may be used
for both the intitial solid/liquid separation
and the final extract filtration. However,
analysts should use one or the other, not
both.
  4.6.3  V the waste contains no initial liquid
phase (is 100% solid) or has no significant
solid phase (is 100% liquid), either the
TEDLAR® bag or the syringe may be used. If
the syringe is used, discard the first 5 mL of
liquid expressed from the device. The
remaining aliquots are used for analysis.
  4.7   ZHE Extraction Fluid Transfer
Devices: Any device capable of transferring
the extraction fluid into the ZHE without
changing the nature of the extraction fluid is
acceptable (e.g. a positive displacement or
peristaltic pump, a gas tight syringe, pressure
filtration unit (see section 4.3.2), or other ZHE
device).
  4.8   Laboratory Balance: Any laboratory
balance accurate to within ± 0.01 grams may
be used (all weight measurements are to be
within ± 0.1 grams).
  4.9   Beaker or Erlenmeyer flask, glass, 500
mL
  4.10   Watchglass, appropriate diameter to
cover beaker or erlenmeyer flask.
  4.11   Magnetic stlrrer.

5.0 Reagents
  5.1   Reagent grade chemicals shall be used
in all tests. Unless otherwise indicated, it is
intended that all reagents shall conform to
the specifications of the Committee on
Analytical Reagents of the American
Chemical Society, where such specifications
are available. Other grades may be used,
provided it is first ascertained that the
reagent is of sufficiently high purity to permit
its use without lessening the  accuracy of the
determination.
  5.2   Reagent water. Reagent water is
defined as water in which an interferant is
not observed at or above the methods
detection limit of the analyte(s) of interest
For nonvolatile extractions, ASTM Type II
water or equivalent meets the definition of
reagent water. For volatile extractions, it is
recommended that reagent water be
generated by any of the following methods.
Reagent water should be monitored
periodically for impurities.
  5.2.1  Reagent water for volatile
extractions may be generated by passing tap
water through a carbon filter bed containing
about 500 grams of activated carbon (Calgon
Corp., Filtrasorb-300 or equivalent).
  5.2.2  A water purification system
(Millipore Super-Q or equivalent) may also be
used to generate reagent water for volatile
extractions.
  5.2.3  Reagent water for volatile
extractions may also be prepared by boiling
water for 15 minutes. Subsequently, while
maintaining the water temperature at 90 + 5
degrees C, bubble a  contaminant-free inert
gas (e.g.. nitrogen) through the water for 1
hour. While still hot transfer the water to a
narrow mouth screw-cap bottle under zero-

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                Federal Register // Vol. S5. No.  126 J Friday, June  29. 19SD / Sules and  Regabrtkms
                                                                                2B889
 headspace and weal with a Teflon-lined
 septum and cap.
  ,6.3  *i>«irochl«»ricaadilNJ, Ud.madfi
 from ACSceagent grade.
  5.4  Nitric acid (IN), HNQ», jnade from
 ACS reagent grade.
  5.5  Sodium hydroxide (IN), NaOH. made
 from ACS reagent grade.
  5.6  Glacial acetic acid, CHsClIjOOH,
 ACS reagent grade.
  5.7  Extraction fluid.
  5.7.1  Extraction fluid #1: Add.5.7 mL
 glacial CHiCHiOOH to 500  mL of reagent
 water (See section 5.2). add 64.3 mL of IN
 NaOH, and dilute to a volume of 1 liter.
 When correctly prepared, the pH of this fluid
 will be 4.93±0.05.
  5.72  Extraction fluid #2: Dilute 5.7 mL
 glacial TJMiCffeOOH -with reagent-water (See
 section *:2) to «-volume of! liter. When
 correctly prepared. thepH-of this fluid will be
 2.88±O.Q5.
  Note:These extraction fluids should be
 monitored frequently tor impurities. The pH
 should be checked prior to  use to ensure that
 these fluids vre made -up accurately. If
 impurtfieB are f orard or the  pH is not within
 the above specifications, the fluid shall be
 discarded and fresh extraction fluid prepared.
  5.6  Analytical standards shall be
 prepared according to the appropriate
 analytical method.

 6.0   StsnphCDUectian.ffeBervation.iand
 Handling
  6.1 AU maples shall be (collected using
 an appropriate mmpiing plan.
  6.2 The TCLP may place requirements on
 the .minimal .tize .of the field sample,
 depending upon the physical state  or states of
 the waste and Jhe«nalytesiof concern. An
 aliquot if needed -for preliminary evaluation
 of which extraction fluid is to be used lor the
 nonvolatile aaalyte extraction procedure.
 Another .aliquot .may be needed to  actually
 conduct ihe nonvolatile extraction {see
 section 1.4 concerning the use  of this .extract
 for volatile organics). H volatile organics-are
 of concern,.another aliquot jnay "be needed.
 Quality control measures may require
 additional aliquols."Further, ills always wise
 to collect .more samples just In case
 something goes .wrong with the initial attempt
 to conduct flie test.
  6.3  Preservatives shall not  be added to
samples'before extraction.
  6.4  Samples may be refrigerated unless
refrigeration results in irreversible physical
change to fee waste. If precipitation occurs.
the entire ••ample f including precipitate)
should toe •extracted.
  6.5  When the waste is to be evaluated for
volatile amflytes, care lihaB be taken to
minimize F whether the »va Rte
contains insignificant solids and is, therefore,
its own extract after filtration (section  7.1.2);
(3) determination of whether the solid portion
of the waste requires particle size reduction
(section 7X3); and <4) determination of which
of the two extraction fluids are to be used for
the nonvolatile TCLP extraction of the  waste
(section .7.1,4.).
   7.1.1  .Preliminary (determination of percent
solids; iPeroent«obd* is defined as that
fraction *>f « waste sample (asm percentage
of'the total sample) from which no liquid may
be forced out by an applied pressure, as
described below.
   7J1.1.1  If the-waste will obviously yield no
liquid when subjected to •pressure filtration
(i.e.. is 100% solids) proceed to'section  7.1.3.
   7.1.1.2  if ihe sample is liquid or
mnltiphaaic. liquid/iofad separation to make
a preliminary betcentrifuged prim to filtration.
Centrifugation is to toe wed only as an  aid to
filtration, if raed, the liquid shanM be
decanted and filtered followed by filtration of
 the aolid portion of*he waste through the
 «ame ifiltratton system.
   7.1.17  Quantitatively transfer the waste
 sample to the fitteriholder ^liquid and solid
 phases). Spread 1% of original
 sample weight) has obviously adhered to the
 container used to transfer the sample to the
 filtration apparatus, determine the weight of
 this residue and subtract it from the sample
 weight determined in section 7.1.1.5 to
 determine he weight of the waste sample that
 will be filtered.
  Gradoadly apply vacunm 'or 'gentle pressure
 of l-lOpsi.'urrtil wir-er pressurizing gas moves
 through the filter. If this point is not reached
 under 10 psi, and if 710 "additional liquid has
 passed through the filter in aiy 2 minute
 interval shrwry increase-me pressure in 10
 psi increments to a maximum of 50 psi. After
 each incremental increase of 10 psi. ff'the
 pressurizing gas lias not moved through the
 filter, and if no additional liquid has passed
 through the filter in any 2 minute interval,
 proceed to the next 10 psi increment. When
 the presBurizing^as begins to move through
the filter, or when liquid flow has ceased at
 50 psi (i.e., filtration does not result in any
 additional filtrate within any 2 minute
period), «top the filtration.
  •Note: Instantaneous application of high
 pressure can degrade the glass .fiber filter and
 may cause prema ture plugging.
  7.1.1,8   The material in the filter holder is
defined as the «olid phase of the waste, and
the 'filtrate is defined as the liquid phase.
  Note: Some wastes, such as oily wastes
and some paint wastes, will obviously
contain some material that appears to be a
liquid. Even after applying vacuum or
pressure filtration, as outlined in section
7.1.1.7, this material may not filter. 7f this is
the 'case, 'fhe •material -within the filtration
device 1» defined an a solid Co not replace
the original filter with a fresh filter under any
circumstances. Dsetirfly one filter.
  7.1.1:9  .Determine the weight of the liquid
phase by subtracting the weight of the filtrate
container "(see .section 7.1.1:3) from fhe total
weight of the filtrate-filled container.
Determine the weight of the solid phase of
the waste sample by KrbtraCtmg the weight
of the liquid phase from the-weight of the
total-waste-sample, as-determined m section
7.1.1.5 or 7.1.1.7.
  Record the weight of the liquid and solid
phases. •Calculate the percent solids as
follows:
                              .Percent solids  =
                                                        Weight afaelid (section 7-1.13)'
                                                 Total weight of *vasle IsecGon 7.1.1.5 or 7.1.1.7)
                                                                                                  X100

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26990	Federal Register /  Vol.  55, No. 126  /  Friday. June  29, 1990  /  Rules  and Regulations
  7.1.2  If the percent solids determined in
section 7.1.1.9 is equal to or greater than 0.5^,
then proceed either to section 7.1.3 to
determine whether the solid material requires
particle size reduction or to section 7.1.2.1 if it
is noticed that a small amount of the filtrate
is entrained in wetting of the filter. If the
percent solids determined  in section 7.1.1.9 is
less than 0.5%, then proceed to section 7.2.9 if
the nonvolatile TCLP is to be performed and
to section 7.3 with a fresh portion of the
waste if the volatile TCLP is to be performed.
  7.1.2.1   Remove the solid phase and filter
from the filtration apparatus.
  7.1.2.2   Dry the filter and solid phase at
100± 20°C until two successive weighings
yield the same value within ± 1%. Record the
final weight.
  Note: Caution should be taken to ensure
that the subject solid will not flash upon
heating. It is recommended that the drying
oven be vented to a hood or other
appropriate device.
  7.1.2.3   Calculate the percent dry solids as
follows:
                                 dry solids =
  (Weight of dry waste + filter)—tared weight of filter

    Initial weight of waste (section 7.1.1.5 or 7.1.1.7)
                                                                                                  XlOO
   7.1.2.4  If the percent dry solids is less
 than 0.5%, then proceed to section 7.2.9 if the
 nonvolatile TCLP is to be performed, and to
 section 7.3 if the volatile TCLP is to be
 performed. If the percent dry solids is greater
 than or equal to 0.5%, and if the nonvolatile
 TCLP is to be performed, return to the
 beginning of this section (7.1) and, with a
 (resh portion of waste, determine whether
 particle size  reduction is necessary (section
 7.1.3) and determine the appropriate
 extraction fluid (section 7.1.4). If only the
 volatile TCLP is to be performed, see the note
 in section 7.1.4.
   7.1.3   Determination of whether the waste
 requires particle size reduction (particle size
 is reduced during this step): Using the solid
 portion of the waste, evaluate the solid for
 particle size. Particle size reduction is
 required, unless the solid has a surface area
 per gram of material equal to or greater than
 3.1 cm', or is smaller than 1 cm in its
 narrowest dimension (i.e., is capable of
 passing through a 0.5 mm (0.375 inch)
 standard sieve). If the surface area is smaller
 or the particle size larger than described
 above,  prepare the solid portion  of the waste
 for extraction by crushing, cutting, or grinding
 the waste to a surface area or particle size as
 described above. If the solids are prepared
 for organic volatiles extraction, special
 precautions must be taken (see section 7.3.6).
   Note: Surface area criteria are meant for
 filamentous (e.g., paper, cloth, and similar)
 waste materials. Actual measurement of
 surface area is not required, nor is it
 recommended. For materials that do not
 obviously meet the criteria, sample-specific
 methods would need to be developed and
 employed to measure the surface area. Such
 methodology is currently not available.
   7.1.4   Determination of appropriate
 extraction fluid: If the solid content of the
 waste is greater than or equal to 0.5% and if
 the sample will be extracted for nonvolatile
 constituents (section 7.2), determine the
 appropriate fluid (section 5.7) for the
 nonvolatiles extraction as follows:
   Note: TCLP extraction for volatile
 constituents uses only extraction fluid frl
 (section 5.7.1). Therefore, if TCLP extraction
 for nonvolatiles is not required, proceed to
 section 7.3.
   7.1.4.1  Weigh out a small subsample of
 the solid phase of the waste, reduce the solid
 (if necessary) to a particle size of
 approximately 1 mm in diameter or less, and
 transfer 5.0 grams of the solid phase of the
waste to a 500 mL beaker or Erlenmeyer
flask.
  7.1.4.2 Add 96.5 mL of reagent water to
the beaker, cover with a watchglass, and stir
vigorously for 5 minutes using a magnetic
etirrer. Measure and record the pM. If the pH
is <5.0, use extraction fluid #1. Proceed to
section 7.2.
  7.1.4.3 If the pH from section 7.1.4.2 is
>5.0, add 3.5 mL IN NCI, slurry briefly, cover
with a watchglass, heat to 50°C, and hold at
50°C for 10 minutes.
  7.1.4.4 Let the solution cool to room
temperature and record the pH. If the pH is
<5.0, use extraction fluid #1. If the pH is
>5.0, use extraction fluid P2. Proceed to
section 7.2.
  7.1.5  If the aliquot of the waste used for
the preliminary evaluation (sections 7.1.1-
7.1.4) was determined to be 100% solid at
section 7.1.1.1, then it can be used for the
section 7.2 extraction (assuming at least 100
grams remain), and the section 7.3 extraction
(assuming at least 25 grams remain). If the
aliquot was subjected to the procedure in
section 7.1.1.7, then another aliquot shall be
used for the volatile extraction procedure in
section 7.3. The aliquot of the waste
subjected to the procedure in section 7.1.1.7
might be appropriate for use for the  section
72 extraction if an adequate amount of solid
(as determined by section 7.1.1.9) was
obtained. The amount of solid necessary is
dependent upon whether a sufficient amount
of extract will be produced to support the
analyses. If an adequate amount of solid
remains, proceed to section 7.2.10 of the
nonvolatile TCLP extraction.
  7.2  Procedure When Volatiles are not
Involved. A minimum sample size of 100
grams (solid and liquid phases) is
recommended. In some cases, a larger sample
size may be appropriate, depending on the
solids content of the waste sample (percent
solids, See section 7.1.1), whether the initial
liquid phase of the waste will be miscible
with the aqueous extract of the solid, and
whether inorganics, semivolatile organics,
pesticides, and herbicides are all analytes of
concern. Enough solids should be generated
for extraction such that the volume of TCLP
extract will be sufficient to support all of the
analyses required. If the amount of extract
generated by a single TCLP extraction will
not be sufficient to perform all of the
analyses, more than one extraction may be
performed and the extracts from each
combined and aliquoted for analysis.
  7.2.1  If the waste will obviously yield no
liquid when subjected to pressure filtration
(i.e., is 100% solid, see section 7.1.1), weigh
out a subsample of the waste (100 gram
minimum) and proceed to section 7.2.9.
  7.2.2  If the sample is liquid or multiphasic,
liquid/solid separation is required. This
involves the filtration device described in
section 4.3.2 and is outlined in sections 7.2.3
to 7.2.B.
  7.2.3  Pre-weigh the container that will
receive the filtrate.
  7.2.4  Assemble the filter holder and filter
following the  manufacturer's instructions.
Place the filter on the support screen and
secure. Acid-wash the filter if evaluating the
mobility of metals (see section 4.4).
  Note: Acid-washed filters may be used for
all nonvolatile extractions even when metals
are not of concern.
  7.2.5  Weigh out a subsample of the waste
(100 gram minimum) and record the weight If
the waste contains <0.5% dry solids (section
7.1.2), the liquid portion of the waste, after
filtration, is defined as the TCLP extract.
Therefore, enough of the sample should be
filtered so that the amount of filtered liquid
will support all of the analyses required of
the TCLP extract. For wastes containing
>0.5% dry solids (sections 7.1.1  or 7.1.2), use
the percent solids information obtained in
section 7.1.1 to determine the optimum
sample size (100 gram minimum) for filtration.
Enough solids should be generated by
filtration to support the analyses to be
performed on the TCLP extract.
  7.2.6  Allow  slurries to stand to permit the
solid phase to settle. Wastes that settle
slowly may be centrifuged prior to filtration.
Use centrifugation only as  an aid to filtration.
If the waste is centrifuged, the liquid should
be decanted and filtered followed by
filtration of the solid portion of the waste
through the same filtration system.
  7.2.7  Quantitatively transfer the waste
sample (liquid and solid phases) to  the filter
holder (see section 4.3.2). Spread the waste
sample evenly over the surface of the filter. If
filtration of the  waste at 4 "C reduces the
amount of expressed liquid over what would
be expressed  at room temperature, then
allow the sample to warm up to room
temperature in the device before filtering.
  Note: If waste material (>1%  of the original
sample weight)  has obviously adhered to the
container used to transfer the sample to the
filtration apparatus, determine the weight of

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                Federal  Register / Vol.  55,  No. 126 /  Friday. June 29,  199Q / Rates and Regulations
                                                                                 26*91
 this residue and subtract it from the sample
 weight-determined in section 7,2.5,to
 determine the weight of 4he-waste sample
 that will be filtered.
   Gradually apply vacuum or-gentle pressure
 of 1-10 psi, until air or pressurizing gas moves
 through the filter. If this point is reached
 under 10j>si, and if no additional .liquid has
 passed .through the filter in any 2 minute
 interval, .slowly increase the pressure in 10
 psi increments to a maximum of 50 psi. Alter
 each incremental increase of 10 psi, if the
 pressurizing gas 'has not mover! through the
 filter, and if no additional liquid has-passed
 through the filter in any 2 minute interval,
 proceed to the next 10 psi increment. When
 the pressurizing gas begins to move through
 the filter, or when the liquid flow has ceased
 at 50 psi (i.e., filtration does not result in any
 additional filtrate within a 2 minute period).
 stop the filtration.
   Note: Instantaneous application of high
 pressure can degrade the glass fiber filter and
 may cause premature plugging.
  7.2.8  The material In the filter bolder is
defined as the solid phase of the waste, and
the filtrate is defined as the liquid phase.
Weigh the filtrate. Th« liquid phase may now
be either analyzed (See section 7.2.12)-or
stored at 4°C until time of analysis.
  Note: Some wastes, such as oily wastes
end some paint wastes, will-obviously
contain some material .that appears to be a
liquid. Even after applying vacuum or
pressure filtration, as outlined in section 7.2.7.
this material may not filter. If this is the case.
the material within the-filtration device is
defined as a solid and is carried through the
extraction as a solid. Do not replace the
original filter with a fresh filter  under any
circumstances. Use only one filter.
  7.2.9  If the waste contains <0.5%dry
solids (see section 7.1.2), proceed to section
7.2.13. If the waste contains >0.5% dry solids
(see section 7.1.1 or 7.1.2), and if particle size
reduction  of the solid was needed in section
7.1.3, proceed to section 7.2.10. If the waste as
received passes afl.5 mm sieve,
 quantitatively transfer the solid material into
 the ex tractor bottle along with the filter used
 to -separate the initial liquid from the solid
 phase, and proceed to section 7.2.11.
  7.2.10  Prepare the solid portion of the
 waste for extraction by crushing, cutting, or
 grinding the waste to a surf ace area or
 particle «ize as described in section 7.1.3.
 When the surface area .or particle size has
 been appropriately altered, qualitatively
 transfer the-solid material into an extractor
 bottle. Include the filter used to separate the
 initial liquid irons the .solid phase.
  Note: Sieving  extract as
 follows:
  7.2.13.1  If the waste contained no initial
liquid phase, the filtered liquid material
 obtained from section 7.2.12 is defined as the
TCLP extract. Proceed to section 7.2.14.
  7.2.13.2  If compatible (e.g.. multiple
phases will not result on combination),
combine the filtered liquid resulting from
section 7.2.12 with the initial liquid phase of
the waste obtained in section 7.2.7. This
combined liquid is defined as the TCLP
extract. Proceed to section 7.2.14.
  7.2.13.3  If the initial liquid phase of the
waste, as obtained from section 7.2.7, is not
or may Jiot be compatible with the filtered
liquid resulting from section 7.2.12, do not
combine these liquids. Analyze these liquids,
collectively defined as theTCLP extract, and
combine the results mathematically, as
described in section 7.2.14.
  7.2.14  Following collection of the TCLP
extract, the pH -of the extract should be
recorded. Immediately aliquot and preserve
the extract for •analysis. Metals ahqutrts must
be acidified with nitric acid to pH <2. If
precipitation Is observed vpon addition of
nitric acrd to a smell aliquert «* the -extract,
then the remaining 'portion of the extract for
metals analyses shall not be »c%ifified -and the
extract -shall be analyzed as soon as-possible.
AH other aliquot* must be -stored -under
refrigeration \t *-C) tintil analyzed. The T-CLP
extract shall be prepared and analyzed
according to appropriate analytical methods.
TCLP extracts to be analyzed for BKFtals shall
be acid digested except in those instances
where digestion causes loss «f metallic
snalytes. If an analysis of the undigested
extract ishows -that the concentration-of any
regulated metallic anaryte exceeds the
regulatory •level, then the •waste is hazardous
and digestion of the extract is not necessary.
However,-data on undigested extracts alone
cannot be used to demonstrate that the waste
is not hazardous.  If the individual phases are
to be analyzed separately, determine the
volume of the individual phases (to ± 0.5%),
conduct the appropriate analyses, and
combine the results mathematically by using
a simple volume-weighted average:
 Final Analyte
 Concentration
where.
                            V,+V2
V, =The volume of-the lirhi phase (L).
Ci = The concentration of the analyte of
    concern in the first phase (mg/LJ.
Vj = T,he volume of the second phase (L).
C-. = The concentration of the analyte of
    concern in the second phase Jmg/L).
  7.2.15  Compare the .analyte
concentration* in the TCLPevtrad with the
levels identified in the appropriate
regulations. Refer to .section fl.O for quality
assurance Eeqwrements.
  7.3   Procedure When Violatiles are
Involved. Use  the ZHE device to obtain TCLP
extract for analyst* of volatile compounds
only. Ejctrad resulting from the use of the
ZHEliiatt not  beosed to evaluate the
mobility of nonvolatile anaJytes ,fe~£.. .metal*,
pesticides, etcj.
  The ZHE device has approximately a £00
mL internal capacity. The ZHE can thus
accommodate  a maximum of 25 grams of
solid {defined  a« that fraction oi a sample
from which no additional liquid may be
forced «ut by an applied pressure of 50 psi).
due to the seed to add an amount of
extraction fluid .equal to 20  times the weight
of the solid phase.
  Charge the ZHE with sample only once and
do not open the device until the final extract
(of the solid) has been collected. Repeated
filling of the ZHE to obtain  25 grams of solid
is not  permitted.
  Do not allow the waste, the initial liquid
phase, or the extract to be exposed to the
atmosphere for any more time than is
absolutely necessary. Any manipulation  of
these  materials should be done when cold
(4°C) to minimize loss of volatiles
  7.3.1  Pre-weigh the (evacuated) filtrate
collection container (See section 4.6) and set
aside. If using  a TEDLAR1 bag, express all
liquid from the ZHE device  into the bag.

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26992
Federal Register  / Vol. 55. No. 126  / Friday.  June  29. 1990 /  Rules and  Regulations
whether for the initial or final liquid/solid
separation, and take an aliquot from the
liquid in the bag for analysis. The containers
listed in section 4.6 are recommended for use
under the conditions stated in sections 4.8.1-
4.6.3.
  7.3.2  Place the ZHE piston within the
body of the ZHE (it may be helpful first to
moisten the piston O-rings slightly with
extraction fluid). Adjust the piston within the
ZHE body to a height that will minimize the
distance the piston will have to move once
the ZHE is charged with sample (based upon
sample size requirements determined from
section 7.3, section 7.1.1 and/or 7.1.2). Secure
                              the gas inlet/outlet flange (bottom flange)
                              onto the ZHE body in accordance with the
                              manufacturer's instructions. Secure the glass
                              fiber filter between the support screens and
                              set aside. Set liquid inlet/outlet flange (top
                              flange) aside.
                                7.3.3  If the waste is 100% solid (see
                              section 7.1.1), weigh out a subsample (25
                              gram maximum) of the waste, record weight,
                              and proceed to section 7.3.5.
                                7.3.4  If the waste contains <5% dry solids
                              (section 7.1.2), the liquid portion of waste,
                              after filtration, is defined as the TCLP
                              extract. Filter enough of the sample so that
                              the amount of filtered liquid will support all
of the volatile analyses required. For wastes
containing >5% dry solids (sections 7.1.1
and/or 7.1.2), use the percent solids
information obtained in section 7.1.1  to
determine the optimum sample size to charge
into the ZHE. The recommended sample size
is as follows:
  7.3.4.1  For wastes containing <5% solids
(see Section 7.1.1), weigh out a 500 gram
subsample of waste and record the weight.
  7.3.4.2  For wastes containing >5% solids
(see Section 7.1.1), determine the amount of
waste to charge into the ZHE as follows:
                                 Weight of waste to charge ZHE =
                                                                                25
                                                                    percent solids (section 7.1.1)
                                                                                 X100
   Weigh out a subsample of the waste of the
 appropriate size and record the weight.
   7.3.5  If particle size reduction of the solid
 portion of the waste was required In section
 7.1.3, proceed to section 7.3.6. If particle size
 reduction was not required in section 7.1.3,
 proceed to section 7.3.7.
   7.3.6  Prepare the waste for extraction by
 crushing, cutting, or grinding the solid  portion
 of the waste to a surface area or particle size
 as described in section 7.1.3.1. Wastes and
 appropriate reduction equipment should be
 refrigerated, if possible, to 4°C prior to
 particle size reduction. The means used to
 effect particle size reduction must not
 generate heat in and of itself. If reduction of
 the solid phase of the waste is necessary,
 exposure of the waste to the atmosphere
 should be avoided to the extent possible.
   Note: Sieving of the waste is not
 recommended due to the possibility that
 volatiles may be lost. The use of an
 appropriately graduated ruler is
 recommended as an acceptable alternative.
 Surface area requirements are meant for
 filamentous (e.g., paper, cloth) and similar
 waste materials. Actual measurement of
 surface area is  not recommended.
   When the surface area or particle size has
 been appropriately altered, proceed to
 section 7.3.7.
   7.3.7  Waste slurries need not be allowed
 to stand to permit the solid phase to settle.
 Do not centrifuge wastes prior to filtration.
   7.3.8  Quantitatively transfer the entire
 sample (liquid and solid phases) quickly to
 the ZHE. Secure the filter and support
 screens onto the top flange of the device and
                              secure the top flange to the ZHE body m
                              accordance with the manufacturer's
                              instructions. Tighten all ZHE fittings and
                              place the device in the vertical position (gas
                              inlet/outlet flange on the bottom). Do not
                              attach the extract  collection device to the top
                              plate.
                                Note: If waste material (>l%ot original
                              sample weight) has obviously adhered to the
                              container used to transfer the sample to the
                              ZHE, determine the weight of this residue
                              and subtract it from the sample weight
                              determined in section 7.3.4 to determine the
                              weight of the waste sample that will be
                              filtered.
                                Attach a gas line to the gas  inlet/outlet
                              valve (bottom flange) and, with the liquid
                              inlet/outlet valve (top flange)  open, begin
                              applying gentle pressure of 1-10 psi (or more
                              if necessary) to force all headspace slowly
                              out of the ZHE device into a hood. At the first
                              appearance of liquid from the liquid inlet/
                              outlet valve, quickly close the valve and
                              discontinue pressure. If filtration of the waste
                              at 4 °C reduces the amount of expressed
                              liquid over what would be expressed at room
                              temperature, then  allow the sample to warm
                              up to room temperature in the device before
                              filtering. If the waste is 100% solid (see
                              section 7.1.1), slowly increase the pressure to
                              a maximum of 50 psi to force most of the
                              headspace out of the device and proceed to
                              section 7.3.12.
                                7.3.9   Attach  the evacuated pre-weighed
                              filtrate collection container to the liquid
                              inlet/outlet valve and open the valve. Begin
                              applying gentle pressure of 1-10 psi to force
                              the liquid phase of the  sample into the filtrate
collection container. If no additional liquid
has passed through the filter in any 2 minute
interval, slowly increase the pressure in 10
psi increments to a maximum of 50 psi. After
each incremental increase of 10 psi, if no
additional liquid has passed through the filter
in any 2 minute interval, proceed to the next
10 psi increment. When liquid flow has
ceased such that continued pressure filtration
at 50 psi does not result in any additional
filtrate within a 2 minute period, stop the
filtration. Close the liquid inlet/outlet valve,
discontinue pressure to the piston, and
disconnect and weigh the filtrate collection
container.
  Note: Instantaneous application of high
pressure can degrade the glass fiber filter and
may cause premature plugging.
  7.3.10  The material in the ZHE is defined
as the solid phase of the waste and the
filtrate is defined as the liquid phase.
  Note: Some wastes, such as oily wastes
and some  paint wastes, will obviously
contain some material that appears to be a
liquid. Even after applying pressure filtration,
this material will not filter. If this is the case,
the material within the filtration device is
defined as a solid and is carried through the
TCLP extraction as a solid.
  If the  original waste contained <0.5% dry
solids (see section 7.1.2), this filtrate is
defined as the TCLP extract and is analyzed
directly. Proceed to section 7.3.15.
  7.3.11  The liquid phase may now be either
analyzed immediately (See sections 7.3.13
through 7.3.15) or stored at 4'C under minimal
headspace conditions until time of analysis.
  Determine the weight of extraction fluid #1
to add to the ZHE as follows:
Weight of extraction fluid  =
                            20 X percent solids (section 7.1.1) x weight of waste filtered (section 7.3.4 or 7.3.8)

                                                                100

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               Federal Register  / Vol. 55, No. 126 /  Friday, June  29. 1990 /  Rules  and Regulations
                                                                                 2699.T
  7.3.12  The following sections detail how
to add the appropriate amount of extraction
fluid to the solid material within the ZHE and
agitation of the ZHE vessel. Extraction fluid
£1 is used in all cases (See section 5.7).
  7.3.12.1  With the ZHE in the vertical
position, attach a line from the extraction
fluid reservoir to the liquid inlet/outlet valve.
The line used shall contain fresh extraction
fluid and should be preflushed with fluid to
eliminate any air pockets in the line. Release
gas pressure on the ZHE piston (from the gas
inlet/outlet  valve), open the liquid inlet/
outlet valve, and begin transferring extraction
fluid (by pumping or similar means) into the
ZHE. Continue pumping extraction fluid into
the ZHE until the appropriate amount of fluid
has been introduced into the device.
  7.3.12.2  After the extraction fluid has
been added, immediately close the liquid
inlet/outlet  valve and disconnect the
extraction fluid line. Check the ZHE to ensure
that all valves are in their closed positions.
Manually rotate the device in an end-over-
end fashion 2 or 3 times. Reposition the ZHK
in the vertical position with the liquid inlet/
outlet valve on top. Pressurize the ZHE to 5-
10 psi (if necessary) and slowly open the
liquid inlet/outlet valve to bleed out any
headspace (into a hood) that may have been
introduced due to the addition of extraction
fluid. This bleeding shall be done quickly and
shall be stopped at the first appearance of
liquid from  the valve. Re-pressurize the ZHE
with 5-10 psi and check all ZHE fittings to
ensure that  they are closed.
  7.3.12.3  Place the ZHE in the rotary
agitation apparatus (if it is not already there)
and rotate at 30 ± 2 rpm for 18 ± 2 hours.
Ambient temperature (i.e.. temperature of
room in which extraction occurs) shall be
maintained  at 22 ± 3°C during agitation.
  7.3.13  Following the 18  ± 2 hour agitation
period check the pressure behind the ZHE
piston by quickly opening and closing the  gas
inlet/outlet  valve and noting the escape of
gas. If the pressure has not been maintained
(i.e., no gas  release observed), the device is
leaking. Check the ZHE for leaking as
specified in lection 4.2.1, and perform the
extraction again with a new sample of waste.
If the pressure within the device has been
maintained, the material in the extractor
vessel is once again separated into its
component liquid and solid phases. If the
waste contained an initial liquid phase, the
liquid may be filtered directly into the same
filtrate collection container (i.e.,  TEDLAR*
bag) holding the initial liquid phase of the
waste. A separate filtrate collection container
must be used if combining would create
multiple phases, or there is not enough
volume left within the filtrate collection
container. Filter through the glass fiber filter.
using the ZHE device as discussed in section
7.3.9. All extract shall be filtered and
collected if the TEDLAR* bag is used, if the
extract is multiphasic, or if the waste
contained an initial liquid phase  (see sections
4.6 and 7.3.1).
  Note: An in-line glass fiber filter may be
used to filter the material within  the ZHE if it
is suspected that the glass fiber filter has
been ruptured.
  7.3.14  If the original waste contained no
initial liquid phase, the filtered liquid
material obtained from section 7.3.13 is
defined as the TCLP extract. If the waste
contained an initial liquid phase, the filtered
liquid material obtained from section 7.3.13
and the initial liquid phase (section 7.3.9) are
collectively defined as the TCLP extract.
  7.3.15  Following collection of the TCLP
extract, immediately prepare the  extract for
analysis and store with minimal headspace at
4°C until analyzed. Analyze the TCLP extract
according to the appropriate analytical
methods. If the individual phases are to be
analyzed separately (i.e.. are not  miscible).
determine the volume of the individual
phases (to 0.5%), conduct the appropriate
analyses, and combine the results
mathematically by using a  simple volume-
weighted average:
   Final Analtye
   Concentration
where:
Vi =The volume of the first phases (L).
C, =The concentration of the analyte of
    concern in the first phase (mg/L).
Vj=The volume of the second phase (L).
Cj=The concentration of the analyte of
    concern in the second phase (mg/L).
  7.3.16  Compare the analyte
concentrations in the TCLP extract with the
levels identified in the appropriate
regulations. Refer to section 8.0 for quality
assurance requirements.

8.0  Quality Assurance
  8.1  A minimum of one blank (using the
same extraction fluid as used for the
samples) must be analyzed for every 20
extractions that have been conducted in an
extraction vessel.
  8.2  A matrix spike shall be performed for
each waste type (e.g.. wastewater treatment
sludge, contaminated soil, etc.) unless the
result exceeds the regulatory level and the
data is being used solely to demonstrate thai
the waste property exceeds the regulatory
level. A minimum of one matrix spike must
be analyzed tor each analytical batch. The
bias determined from the matrix spike
determination shall be used to correct the
measured values. (See sections 8.2.4 and
8.2.5.) As a minimum, follow the matrix spike
addition guidance provided in each analytical
method.
  B.C.I  Matrix spikes are to be added afler
filtration of the TCLP extract and before
preservation. Matrix spikes should not be
added prior to TCLP extraction of the sample.
  8.2.2  In most cases, matrix spikes should
be added at a concentration equivalent to the
corresponding regulatory level. If the analytt
concentration is less than one half the
regulatory level, the spike concentration mny
be as low as one half of the analyte
concentration, but may not be not less than
five times the method detection limit. In order
to avoid differences in matrix effects, the
matrix spikes must be added to the same
nominal volume of TCLP extract as that
which was  analyzed for the unspiked sample.
  B.2.3  The purpose of the matrix spike is to
monitor the performance of the analytical
methods used, and to determine whether
matrix interferences exist. Use of other
internal calibration methods, modification of
the analytical methods, or use of alternate
analytical methods may be needed to
accurately  measure the analyte concentration
of the TCLP extract when the recovery of the
matrix spike is below the expected analytical
method performance.
  8.2.4  Matrix spike recoveries are
calculated by the following formula-
5/.R (% Recovery) = 100 [X.-XJ/K

where:
X, = measured value for the spiked sample,
Xu = measured value for the unspiked sample.
     and
K=  known value of the spike in the sample
  8.2.5   Measured values are corrected for
analytical bias using the following formula:
where:
X, = corrected value, and
Xu = measured value of the unspiked sample.
  8.3   All quality control measures described
in the appropriate analytical methods shall
be followed.
  8.4   Samples must undergo TCLP
extraction within the following time periods

-------
26994
Federal  Register  / Vol. 55,  No.  126  / Friday, June 29, 1990  / Rules  and Regulations
                                            SAMPLE MAXIMUM HOLDING TIMES (DAYS)

Volatile? . 	 	
Sflmivolatiles , 	
Mercury 	 . - .. -. -. 	
Mptat* mtrtaii marcmi* _ 	 _ 	 ^ - - 	 	 	 _.,..,, 	 ,,.,,, -,.--,-,-..-

from:
Field
collection
taTCLP
extraction
14
14
28
160

From:
TCLP
extraction
to:
Prepara-
tive
extraction
MA
7
NA
NA

From:
prepara-
tive
extraction
lo:
deter urt-
native
analysis
14
40
28
180

Total
elapsed
time
28
61
56
360

    NA = Not applicable.
   If sample holding times are exceeded.
 the values obtained will be considered
 minimal concentrations. Exceeding the
 holding time i» not acceptable in
 establishing that a waste does not
 exceed the regulatory level Exceeding
 the holding time will not invalidate
 characterization if the waste exceeds
 the regulatory level


    TABLE t,—VOLATILE ANALYTES '•*
                              TABLE 2.—SUITABLE ROTARY AGITATION
                                     APPARATUS '—Continued
TABLE 4.—SUITABLE FILTER HOLDERS '
Compound*
Arntnn* 	 	 	 	
Benzene. — .. 	 ..« 	
n-B«ityt alcohol 	
Carbon dnetfide 	 	 	
Carbon tettacMoride 	 	 _...
Chiorobenzene
Chloroform. 	
1 ?-Diehlnroelhane
1.1-Oichloroethy(ene 	
Elnyt •crtatB
Ethyl benzene 	 	 	
Ethytether 	
Isabutannl
Metnunnl
Methytene chtonde 	 	 	
Mathyl d^y MO«* 	
Methyl Botoutyl ketone 	
Telrachlocoelhylane 	 	 	
Toluene 	
i.1,1.-Trichto»o««rtane 	 _
TricMnmithylaaf
Trichlorofluoromelhane 	 	 	
1,1,2-Trtehtor>1i2-tiiftjoroelhane ..._.
Vinyl chloride 	
Xylene-.. 	 __ 	

CAS No.
67-64-1
71-43-2
71-36-3
75-15-0
56-23-5
108-80-7
67-66-3
107-06-2
75-35-4
14>-78-6
100-41-4
60-29-7
78-83-1
67-56-1
75-O9-2
78-43-3
108-10-1
«7-18-4
IOfr-W-3
71-65-6
79-O/t-«
75-6S-4
76-tS-l
75-O1-4
1330-20-7

   1 When testing tar any or all ot these anetytes, the
 zero-headspace extractor  vessel shali be used n-
 stead of U« bottle extractor.
   'Benzene^ carbon  laMcMonde.  ehtorebenzene,
 chloroform,  1,2-dtentowthane,  1,1-dfchteroe«ivleoe,
 methyJ ethyl ketone, tetrachloroethyjene.  trichlor-
 oethylene. and vinyl chloride are toxicity charactens-
 tic constituents.
  TABLE 2.—SUITABLE ROTARY AGITATION
               APPARATUS '
Company
Anarytical
Testing and
Consulting
Services. Inc.
Location i Model No.
Wamngten, PA,
(215)343-
4490.
4-vessel
(DC20S), 8-
vessel
(DC20). 12
vessel
(DC20B1
Company
Associated
Design and
Manufactur-
ing Company.






Environmental
Machine and
Design, Inc.

IRA Machine
Shop and
Laboratory
Lars Lande
Manufactur-
ing.

Mufipore Corp 	



Location
Alexandria VA,
(703) 549-
5999.







Lynchbufs. VA.
(804) 845-
6424.

Santurca, PR,
(809) 752-
4004.
wrutmore Lake,
Ml, (313)
449-4116.

Bedford, MA,
(800)225-
3384.

Model No.
2-Messel (3740-
2). 4-*eSSel
(3740-4). 6-
vesseJ<3740-
6), 8-vesael
(3740-8). 12-
vessel (3740-
12L24-
vesael(3740-
24).
•-vessel (08-
00-00)4-
vessel(04-
00-00).
8-vessel
(011001).

10- vessel
(OWRE), 5-
vessel
(5VRE).
4-ZHEOT4 1.
Her. bottle
extractor
(YT30ORAHW).
                                              1 Any device that rotate* the extraction vessel m
                                            an end-over-end fashion at 30 ± 2 rpm is accepta-
                                            ble.
                                              TABLE 3.—SUITABLE ZERO-HEADSPACE
                                                      EXTRACTOR VESSELS '
Company
Analytical
Testing 4
Consulting
Services. Inc..
Associated
Design and
Manufactur-
ing Company.
Lars Lande
Manufactur-
ing '•
M:lbpore
Corporation.

Environmental
Machine and
Design, Inc..
Location
Wanington. PA.
(215)343-
4490.

Alexandria VA.
(703)549-
5999.

Whomore LaKe.
W. (313)
449-4116.
Bedford, MA,
(600)225-
3384.
Lynchourg. VA,
(804)845-
6424.
Model No.
C102.
Mechanical
Pressure
Device.
3745-ZHE. Gas
Pressure
Device.

ZHE-11, Gas
Pressure
Device.
YT30090HW,
Gas Pressure
Device.
VOLA-TOX1,
Gas Pressure
Device.
                                              1 Any device that meets the specifications listed in
                                            section 4.2.1. ol the method is acceptable.
                                              • This device uses a 110 mm fitter
Comparry
Nucteo-
pore
Corpo-
ration.


Micro
Filtra-
tion
Sys-
tems.



Millioore
Corpo-
ration.


Location
Pleasan-
ton.
CA,
(800)
882-
7711.
Dublin,
CA.
(800)
334-
7132,
(415)
828-
6010.
Bedford,
MA,
(800)
225-
3384.
Model/catalogue
No.
425910
410430




302400
311400






YT30142HW
XX10047OO



Size
142mm.
47
mm



142 mm
47
(lull





142 rr«r
47
mm


                                                                                          1 Any device capable of separating the bguid from
                                                                                        the solid phase  of the waste Is suitable, providing
                                                                                        that R is chemically compatible with the waste and
                                                                                        the- constituents to be analyzed. Plastic devices (not
                                                                                        listed  above) may  be used  when only morganc
                                                                                        arwtytes are of  concern.  The 142 mm  sue dttei
                                                                                        holder is recommended.
                                                                            TABLE 5.—SUITABLE FILTER MEDIA
Company
Millipore
Corporation.

Nudeopore
Corporation.

Whatman
Laboratory
Products.
Inc..
Micro Filtration
Systems.


Location
Bedford. MA.
(600)225-
3384.
Pleasanton,
CA. (415)
463-2530.
CDfton, NJ.
(201)773-
5800.

Dublin, CA,
(800)334-
7132, (415)
828-6010.
Model
AP40


211625


GFF



GF75



Pore
Size
(turn)
0.7


0.7


07



07



                                                                                          1 Any filter that meets the specifications tn sertcm
                                                                                        4.4 of the Method is suitable.
                                                                                        •ILUNO CODE SSSO-SO-M

-------
     Federal Register / Vol. 55, No. 126 / Friday, June 29,1990 / Rules and Regulations       26995
    Motor
(30 ±  2 rpm)
Extraction Vessel Holder
         Figure  1.  Rotary Agitation Apparatus

-------
26996
Federal Register / Vol. 55, No. 128 / Friday. June 29.1990 / Rules and Regulations
    Top Range-
                           Uquid Inlet/Outlet Valve
                                     t
      Support Screen/
                Fitter^
      Support Sereer/
        Viton o-rings
 Bottom Range
  Pressurized Gas
  Inlet/Outlet Valvs

                        Piston
                               Pressure
                                Gauge
        Figure 2.   zerc-Headspace Extractor (ZHE)

-------
Federal Register / Vol. 55, No. 126 / Friday. June 29.1990 / Rules and Regulations
                        26997
                     METHOD 1311

      TOXICITY CHARACTERISTIC LEACHATE PROCEDURE
                     f  START 1

CD
i

Separate
liquids from
solids with
0.6 - 0.8 urn
glass fiber
filter
i
i
<0.5%

Discard
solids

Use a
sub-sample of
waste
1
t
What is
the %
solids in the
waste?
i
100%
t
Examine
solids

CD

i
Liquid
Separate
n -„ liquids from
>0-5% solids with
0.6 - 0.8 um
glass fiber
filter





Solid
                      Must the
                      solid be
                      miHed?
Yes
                    Extract with
                 appropriate fluid
                1)  Bottle extractor
                 for non-volatiles
                2)  ZHE device for
                     volatiles
                                                     Reduce
                                                   particle size
                                                   to <9.5 mm
    -CD

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26998
Federal Register / Vol. 55, No. 126 / Friday, June 29, 1990 / Rules and Regulations
                         METHOD 1311  (CONTINUED)

                TOXICITY CHARACTERISTIC LEACHATE PROCEDURE
                              LZJ
    LZJ
                   Store liquid
                     at  4 t
     Separate
   extract from
    solids with
  0.6 -  0.8 urn
    qlass fiber
       filter
         Solid
    Is
  liquid
compatible
 with the
 extract?
                                            Measure amount of
                                            liauid and analyze
                                             (mathematically
                                            combine result with
                                             result of extract
                                                 analysis)
                               Combine
                             extract with
                             liquid phase
                               of  waste
                                Analyze
                                 liquid
                              [ STOP ]«-
[FR Doc. 90-15048 Filed 6-2&-90; 8:45 am)

BILLING CODE «560-50-C

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                                                 GSAN0.0246-EPA-OJ
                                                                                            IP -Tor Official Use Omy
IX. Description of Regulated Wastes Continued (Additional sheet) ^^^^^^^^^^^^^^^^^^^^^H
| B. Listed Hazardous Wastes. (See 40 CFR 261.31 - 33. Use this page only if you need to list more than 12 waste codes. |







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1
13




19




25




31




37




43




49




55




61




67




73




79




85




91




97




103




109




,115




--

14




20




26




32




38




44




50




56




62




68




74




80




86




92




98




104




110




116























15




21




27




33




39




45




51




57




63
u_



69




75




81




87




93




99




105




111




117








16




22




28




34




40




46




52-




58




64




70




76




82




88




94




100




106




112




118








•


17




23




29




35




41




47




53




59




65




71




77




83




89




95




t01




107




113




119























MM
18




24




30




36




42




48




54




60




66




_
72




78
,



84




90




96




102




108




114




120




1







EPA Form 8700-12 (01-90)  Previous edition is obsolete.
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