EPA-560/4-84-001B
October 1982
A COMPENDIUM.OF REPORTED PHYSICAL
AND CHEMICAL CHARACTERIZATION DATA
FOR PETROLEUM AND SYNTHETIC FUEL PRODUCTS
Volume II - Direct Coal Liquefaction Products
by
S. Quinlivan, A. Panahloo,
M. Ghassemi (Program Manager and Technical Director)
and
M. Haro
EPA Contract No. 68-02-3174
Work Assignment Nos. 92 and 99
and
Work Assignment No. 124, Purchase Order No. 19870
EPA Technical Director:
George F. Wirth
Economics & Technology Division
Office of Toxic Substances
. Washington, DC 2C450
PESTICIDES AND TOXIC SUBSTANCES
IVIRONMENTAL PROTECTION AGENCY
WASHINGTON, DC 20460
-------
EPA-560/4-84-001B
October 1982
A COMPENDIUM OF REPORTED PHYSICAL
AND CHEMICAL CHARACTERIZATION DATA
FOR PETROLEUM AND SYNTHETIC FUEL PRODUCTS
Volume II - Direct Coal Liquefaction Products
by
S. Quinlivan, A. Panahloo,
M. Ghassemi (Program Manager and Technical Director)
and
M. Haro
Prepared For Radian Corporation
Research Triangle Park, NC
EPA Contract No. 68-02-3174
Work Assignment Nos. 92 and 99
and
Work Assignment No. 124, Purchase Order No. 19870
EPA Technical Director:
George F. Wirth
Economics & Technology Division
Office of Toxic Substances
Washington, DC 20460
OFFICE OF PESTICIDES AND TOXIC SUBSTANCES
U.S. ENVIRONMENTAL PROTECTION AGENCY
WASHINGTON, DC 20460
-------
DISCLAIMER
This report was prepared under contract to an agency of the United States
Government. Neither the United States Government nor any of its employees,
contractors, subcontractors, or their employees makes any warranty, expressed
or implied, or assumes any legal liability or responsibility for any third
party's use or the results of such use of any information, apparatus, product,
or process disclosed in this report, or represents that its use by such third
party would not infringe on privately owned rights.
Publication of the data in this document does not signify that the con-
tents necessarily reflect the joint or separate views and policies of each
sponsoring agency. Mention of trade names or commercial products does not
constitute endorsement or recommendation for use.
-------
CONTENTS
VOLUME I. Petroleum and Shale Oil Products
Abstract iii
Acknowledgements v
1.0 Background, Objectives, Scope, and Overview of the Current
Data Base 1
2.0 Data Sources and Organization of the Compendium 4
3.0 Glossary 24
3.1 Sample Sources/Descriptions 24
3.2 Abbreviations and Symbols 26
Part I. Petroleum Crude, Raw Shale Oil, and Hydrotreated
Shale Oil 27
Part II. Naphtha 118
Part III. Jet Fuel 144
Part IV. Diesel Fuel 191
Part V. Residual Fuel 235
VOLUME II. Direct Coal Liquefaction Products
Part VI. Raw and Hydrotreated Whole Process Liquids 267
Part VII. Coal Liquid Intermediates 328
Part VIII. Naphthas 450
Part IX. Raw and Hydrotreated Middle Distillates and Blends
(Jet, Diesel, Other Light Fuel Oils) 597
Part X. Raw and Hydrotreated Heavy Distillates (Heavy Fuel Oils)
and Residua 719
References 896
IV
-------
Part VI. Raw and Hydrotreated Whole Process Liquids
267
-------
Material
Coal raw
whole
process
liquids
Table 163. Specific Gravity
Process Coal Type
SRC-II
Value Sample Description/Source Reference
Pitt-Seams 0.9427
WV
(Black-
vine
No. 2
Mine)
Ft. Lewis pilot plant
144
Hydro-
treated
whole
process
liquids
EDS
NA
IL No. 6
(Monterey
Mine)
0.928
One tpd pilot plant,
once-through mode
144
268
-------
Table 164. API Gravity
Value
Material
Coal raw
whole
process
liquids
Hydro-
treated
whole
process
liquids
Process
SRC- 1 1
EDS
H-Coal
SRC- 1 1
Coal Type (degrees)
KY No. 9 18.6
and 14
IL No. 6
(River
King
Mine)
and
Pitt-Seams
WV
(B lack-
vine
No. 2
Mine)
IL No. 6 21.0
(Monterey
Mine)
Wyodak 35 . 1
IL No. 6 25.8
IL No. 6 20.9
IL No. 6 27.6
(Burning
Star
Mine)
Wyodak 36.0
IL No. 6 28.2
Pitt-Seams 37.1
WV
(Black-
vine
No. 2
Mine)
(Continued)
269
Sample Description/Source
Ft. Lewis pilot plant
(Chevron Sample No.
WOW- 3666)
One tpd pilot plant,
once-through mode
PDU, syncrude mode
(Chevron Sample No.
WOW-4137)
PDU, syncrude mode
(Chevron Sample No.
WOW-3919)
PDU, syncrude mode
PDU, Ashland Oil sample
PDU, syncrude mode, rerun
whole process liquid
(Chevron Sample No.
SGQ 7064)
PDU, syncrude mode, rerun
whole process liquid
(Chevron Sample No.
SGQ 6979)
From high severity hydro-
treatment with ICR 106
catalyst, Chevron sample
(Operating conditions:
average catalyst tempera-
ture, 750°F; LHSV, 1.0;
total pressure, 2500 psig;
H2 mean pressure, 2325
psia; recycle gas, 14,550
SCF/bbl)
Reference
86
144
95
95
98
96
95
95
141
-------
Material
Hydro-
treated
whole
process
liquids
Process
SRC-11
Table 164 (Concluded)
Value
Value
Coal Type (degrees) Sample Description/Source Reference
Pitt-Seams 34.3
WV
(Black-
vil le
No. 2
Mine)
Pitt-Seams 30.3
WV
(Black-
vine
No. 2
Mine)
From intermediate severity
hydrotreatment with ICR
106 catalyst, Chevron
sample (Operating con-
ditions: average
catalyst temperature
750°F; LHSV, 1.5;
total pressure, 2500
psig; H2 mean pressure,
2345 psia; recycle gas,
14,830 SCF/bbl)
From low severity hydro-
treatment with ICR 106
catalyst, Chevron
sample (Operating con-
ditions: average
catalyst temperature,
750°F; LHSV, 1.5;
total pressure, 2000
psig; H2 mean pressure,
1765 psia; recycle gas,
8070 SCF/bbl)
141
270
-------
Table 165. Density
Material
Coal
raw
whole
process
liquids
Process Coal Type
H-coal Wyodak
Wyodak
Wyodak
Wyodak
Wyodak
IL No. 6
Value
(g/rcl)
1.204
(70'F)
1.238
(70'F)
1.201
(70°F)
1.171
(70'F)
0.8405
(68°F)
0.8626
(68°F)
Sample Description/Source
PDU Run 10 (ORNL Sample
27B)
PDU Run 10 (ORNL Sample
34A)
PDU Run 10 (ORNL Sample
42A)
PDU Run 10 (ORNL Sample
43A)
PDU, syncrude mode, rerun
whole process liquid
(Chevron Sample No. SGQ
7064)
PDU, syncrude mode, rerun
whole process liquid,
(Chevron Sample No. SGQ
6979)
Reference
158
158
158
158
95
95
Hydro-
treated
whole
process
liquids
NA
271
-------
Table 166. Distillation Data
Material
Coal raw
whole
process
liquids
Process Coal Type
SRC-II
KY No. 9
and 14
IL No. 6
(River
King
Mine)
and
Pitt-Seams
WV
(Black-
ville
No. 2
Mine)
H-Coal Wyodak
IL No. 6
Value %
(Degrees)
1547
217°F-
IBP/5*
2817
382'F-
10/30
438°F-50
4847
597°F-
70/90
6997
850°F-
95/EP
1207
188°F-
IBP/5*
215 /
280°F-
10/30
355°F-50
424/
526°F-
70/90
6017
650 °F-
95/EP
1407
204°F-
IBP/5*
2367
329°F-
10/30
398BF-50
466/
582°F-
70/90
648/
704°F-
95/EP
(Continued)
Sample Description/Source Reference
Ft. Lewis pilot plant
(Chevron Sample No.
WOW-3666)
86
PDU, syncrude mode
(Chevron Sample No,
WOW-4137)
95
POU, syncrude mode
(Chevron Sample No.
WOW-3919)
95
272
-------
Table 166 (Concluded)
Value
Material Process Coal Type (Degrees) Sample Description/Source Reference
Hydro- NA
treated
whole
process
liquids
Explanatory Notes
*Detennined via ASTM D-86 and/or D-1160.
273
-------
Table 167. GC Simulated Distillation
Material
Coal raw
whole
process
liquids
Process Coal Type
SRC-II
Value
(Boiling
Point
Range
Sample Description/Source Reference
KY No. 9
and 14,
IL No. 6
(River
King
Mine)
and
56/
189°F-
IBP/5
241/579°F-
10/30
424'F-50
473/
Ft. Lewis pilot plant
(Chevron Sample No.
WOW-3666)
86
Pitt-Seams 562°F-
WV
(Black-
ville
No. 2
Mine)
H-Coal Wyodak
IL No. 6
70/90
6427
820°F-
95/99
53/
156'F-
IBP/5
173/
261°F
10/30
354°F-50
429/
535°F-
70/90
602/
785°F-
95/99
56/
177°F-
IBP/5
213/
333°F-
10/30
404°F-50
476/
588°F-
70/90
654/
765°F
95/99
(Continued)
PDU, syncrude mode
(Chevron Sample No.
WOW-4137)
95
PDU, syncrude mode
(Chevron Sample No.
WOW-3919)
95
274
-------
Table'167 (Continued)
Material
Coal raw
whole
process
liquids
Process Coal Type
H-Coal Wyodak
IL No. 6
Value
(Boiling
Point
Range)
52/165-
IBP/5
178/269-
10/30
356-50
424/509-
70/90
542/603-
95/99
101/175-
IBP/5
181/194-
10/30
335-50
417/508-
70/90
538/589-
95/99
Hydro-
treated
whole
process
liquids
SRC-II Pitt-Seams 62/
WV
(Black-
ville
No. 2
Mine)
177°F-
IBP/5
210/
278°F-
10/30
364°F-50
419/
505°F-
70/90
553/
662'F-
95/99
Pitt-Seams 59/
WV
(Black-
ville
No. 2
Mine)
176°F-
IBP/5
210/
279°F-
10/30
370°F-50
436/
519°F-
70/90
572/
690°F-
95/99
Sample Description/Source Reference
PDU, syncrude mode, rerun
whole process liquid
(Chevron Sample No. SGQ
7064)
POU, syncrude mode, rerun
whole process liquid
(Chevron Sample No. SGQ
6979)
From high severity hydro-
treatment with ICR 106
catalyst, Chevron sample
(Operating conditions:
average catalyst tempera-
ture, 750°F; LHSV, 1.0;
total pressure, 2500 psig;
\\2 mean pressure, 2325
psia; recycle gas, 14,550
SCF/bbl)
From intermediate severity
hydrotreatment with ICR
106 catalyst, Chevron
Sample (Operating con-
ditions: average catalyst
temperature, 750°F; LHSV,
1.5; total pressure, 2500
psig; H2 mean pressure,
2345 psia; recycle gas,
14,830 SCF/bbl)
(Continued)
275
95
95
141
141
-------
Table 167 (Concluded)
Material
Hydro-
treated
whole
process
liquids
Process Coal Type
Value
(Boiling
Point
Range)
Sample Description/Source Reference
SRC-II Pitt-Seams 587
WV
(Black-
vine
No. 2
Mine)
174'F-
IBP/5
2121
292°F-
10/30
394T-50
446/
539°F-
70/90
600/
728°F-
95/99
From low severity hydro-
treatment with ICR 106
catalyst, Chevron sample
(Operating conditions:
average catalyst tempera-
ture, 750'F; LHSV, 1.5;
total pressure, 2000 psig;
\\2 mean pressure, 1765
psia; recycle gas, 8070
SCF/bbl)
141
276
-------
Material
Coal raw
whole
process
liquids
Table 168. Refractive Index
Process Coal Type Value Sample Description/Source Reference
SRC-II
KY No. 9
and 14,
IL No. 6
(River
King
Mine)
and
Pitt-Seams
WV
(Black-
vil le
No. 2
Mine)
1.5073
(176°F)
Hydro-
treated
whole
process
liquids
H-Coal Wyodak
IL No. 6
NA
1.4735
(68'F)
1.5050
(688F)
Ft. Lewis pilot plant
(Chevron Sample No.
WOW-3666)
86
PDU, syncrude mode
(Chevron Sample No.
WOW-4137)
PDU, syncrude mode
(Chevron Sample No.
WOW-3919)
95
95
277
-------
Table 169. Molecular Weight
Material
Coal raw
whole
process
liquids
Process Coal Type
SRC-II KY No. 9
and 14,
IL No. 6
(River
King
Mine)
and
Pitt-Seams
WV
(Black-
ville
No. 2
Mine)
H-Coal Wyodak
IL No. 6
Wyodak
IL No. 6
Hydro-
treated
whole
process
liquids
NA
Value
(g/mole) Sample Description/Source Reference
132
130
147
136
136
Ft. Lewis pilot plant
(Chevron Sample No.
WOW-3 66 6)
PDU, syncrude mode
(Chevron Sample No.
WOW-4137)
POD, syncrude mode
(Chevron Sample No.
WOW-3919)
POD, syncrude mode, rerun
whole process liquid
(Chevron Sample No. SGQ
7064)
PDU, syncrude mode, rerun
whole process liquid
(Chevron Sample No. SGQ
6979)
86
95
95
95
95
278
-------
Table 170. Viscosity
Material
Coal raw
whole
process
liquids
Hydro-
treated
whole
process
liquids
Process Coal Type
SRC-II KY No. 9
and 14,
IL No. 6
(River
King
Mine)
and
Pitt-Seam
WV
(Black-
vine
No. 2
Mine)
H-Coal Wyodak
IL No. 6
NA
Value
(Centi-
Stokes)
2.196
(100°F)
1.617
(13CTF)
1.225
(100'F)
1.645
(100°F)
Sample Description/Source Reference
Ft. Lewis pilot plant
(Chevron Sample No.
WOW-3666)
86
PDU, syncrude mode
(Chevron Sample No.
WOW-4137)
PDU, syncrude mode
(Chevron Sample No.
WOW-3919)
95
95
279
-------
Table 171. Pour Point
Material Process Coal Type (°F) Sample Description/Source Reference
Coal raw SRC-II KY No. 9 <-80 Ft. Lewis pilot plant 86
whole and 14, (Chevron Sample No.
process IL No. 6 WOW-3666)
liquids (River
King
Mine)
and
Pitt-Seams
WV
(Black-
vine
No. 2
Mine)
Hydro- NA
treated
whole
process
liquids
280
-------
Table 172. Carbon Residue*
Material
Coal raw
whole
process
liquids
Value
Process Coal Type (wt %}
SRC-II KY No. 9 0.70
and 14,
IL No. 6
(River
King
Mine)
and
Pitt-Seams
WV
(Black-
vil le
No. 2
Mine)
Sample Description/Source
Ft. Lewis pilot plant
(Chevron Sample No.
WOW- 3666)
Reference
86
H-Coal Wyodak
IL No. 6
Wyodak
IL No. 6
Hydro- NA
treated
whole
process
liquids
Explanatory Notes
*Ramsbottom carbon residues
0.23 PDU, syncrude mode
(Chevron Sample No.
WOW-4137)
0.29/ PDU, syncrude mode
0.30 (Chevron Sample No.
WOW-3919)
0.15 PDU, syncrude mode, re-
run whole process liquid
(Chevron Sample No. SGQ
7064)
0.30 PDU, syncrude mode, re-
run whole process liquid
(Chevron Sample No. SGQ
6979)
95
95
95
95
281
-------
Table 173. Heat of Combustion
Value
(Btu/
Material Process Coal Type Ib) Sample Description/Source Reference
Coal raw EDS IL No. 6 18,710 One tpd pilot plant, 144
whole (Monterey (HHV) once-through mode
process Mine)
liquids
Hydro- NA
treated
whole
process
liquids
282
-------
Table 174. Aniline Point
Material
Coal
raw
whole
process
liquids
Process Coal Type
SRC-II KY No. 9
and 14,
IL No. 6
(River
King
Mine)
and
Pitt-Seams
WV
(Black-
vine
No. 2
Mine)
H-Coal IL No. 6
Hydro-
treated
whole
process
liquids
SRC-II
<30
Pitt-Seams
WV
(Black-
ville
No. 2
Mine)
<32
98.7
Pitt-Seams
WV
(Black-
ville
No. 2
Mine)
69.9
Sample Description/Source Reference
Ft.Lewis pilot plant
(Chevron Sample No.
WOW-3666)
86
PDU, syncrude mode
(Chevron Sample No.
WOW-3919)
From high severity hydro-
treatment with ICR 106
catalyst, Chevron sample
(Operating conditions:
average catalyst tempera-
ture, 750°F; LHSV, 1.0;
total pressure, 2500 psig;
H£ mean pressure, 2325
psia; recycle gas, 14,550
SCF/bbl)
From intermediate severity
hydrotreatment with ICR
106 catalyst, Chevron
Sample (Operating condi-
tions: average catalyst
temperature, 750°F; LHSV,
1.5; total pressure, 2500
psig; \\2 mean pressure,
2345 psia; recycle gas,
14,830 SCF/bbl)
95
141
141
(Continued)
283
-------
Table -174 (Concluded)
Value
Material Process Coal Type (°F) Sample Description/Source Reference
Hydro- SRC-II Pitt-Seams 38.3 From low severity hydro- 141
treated WV treatment with ICR 106
whole (Black- catalyst, Chevron sample
process ville (Operating conditions:
liquids No. 2 average catalyst tempera-
Mine) ture, 750'F; LHSV, 1.5;
total pressure, 2000 psig;
H2 mean pressure, 1765
psia; recycle gas, 8070
SCF/bbl)
284
-------
Material
Coal raw
whole
process
liquids
Process Coal Type
Table 175. Bromine Number
Sample Description/Source Reference
SRC-II
Hydro-
treated
whole
process
liquids
NA
KY No. 9
and 14,
IL No. 6
(River
King
Mine)
and
Pitt-Seams
WV
(Black-
ville
No. 2
Mine)
H-Coal Wyodak
IL No. 6
Wyodak
IL No. 6
Value
70
24/27
37/40
17
31
Ft. Lewis pilot plant
(Chevron Sample No.
WOW-3666)
POU, syncrude mode
(Chevron Sample No.
WOW-4137)
PDU, syncrude mode
(Chevron Sample No.
WOW-3919)
PDU, syncrude mode, re-
run whole process liquid
(Chevron Sample No. SGQ
7064)
PDU, syncrude mode, re-
run whole process liquid
(Chevron Sample No. SGQ
6979)
86
95
95
95
95
285
-------
Table 176. Oxygen Content
Material
Coal raw
whole
process
liquids
Process Coal Type
SRC-II
EDS
KY No. 9
and 14,
IL No. 6
(River
King
Mine)
and
Pitt-Seams
WV
(Black-
vine
No. 2
Mine)
Pitt-Seams
WV
(Black-
vine
No. 2
Mine)
IL No. 6
(Monterey
Mine)
H-Coal Wyodak
IL No. 6
Wyodak
IL No. 6
IL No. 6
(Burning
Star
Mine)
Value
(wt %)
3.79
1.75
0.85
1.88/
1.71
0.67
1.96
1.93
Sample Description/Source Reference
Ft. Lewis pilot plant
(Chevron Sample No.
WOW-3666)
3.79 Ft. Lewis pilot plant
One tpd pilot plant,
once-through mode
PDU, syncrude mode
(Chevron Sample No.
WOW-4137)
PDU, syncrude mode
(Chevron Sample No.
WOW-3919)
PDU, syncrude mode, re-
run whole process liquid
(Chevron Sample No. SGQ
7064)
PDU, syncrude mode, re-
run whole process liquid
(Chevron Sample No. SGQ
6979)
PDU, Ashland Oil sample
(Continued)
286
86
144
144
95
95
95
95
96
-------
Material
Table 176 (Continued)
Value
Process Coal Type (wt %) Sample Description/Source Reference
Coal raw
whole
process
liquids
SRC- I I Wyodak
Wyodak
Wyodak
Wyodak
2.5*
1.4*
1.5*
1.6*
PDU Run 10 (ORNL Sample
27B)
PDU Run 10 (ORNL Sample
34A)
PDU Run 10 (ORNL Sample
42A)
PDU Run 10 (ORNL Sample
146
146
146
146
Hydro-
treated
whole
process
liquids
NA
Pitt-Seams
WV
(Black-
ville
No. 2
Mine)
Pitt-Seams
WV
(Black-
vi lie
No. 2
Mine)
4.66
(Batch l)t
4.11
(Batch 2)
4.12
(Batch 3)
4.80
(Batch 6)
0.0070f
43 A)
PDU Run 130-73
145
0.0550f
From high severity hydro-
treatment with ICR 106 cata-
lyst, Chevron sample
(Operating conditions:
average catalyst tempera-
ture, 750'F; LHSV, 1.0;
total pressure, 2500 psig;
H2 mean pressure, 2325
psia; recycle gas, 14,550
SCF/bbl)
From intermediate severity
hydrotreatment with ICR 106
catalyst, Chevron Sample
(Operating conditions: ave-
rage catalyst temperature,
750°F; LHSV, 1.5; total
pressure, 2500 psig; H^
mean pressure, 2345 psia;
recycle gas, 14,830 SCF/bbl)
141
141
(Continued)
287
-------
Table 176 (Concluded)
Material
Hydro-
treated
whole
process
liquids
Process Coal Type
SRC-11
Pitt-Seams
WV
(Black-
vine
No. 2
Mine)
Value
(wt %}
0.4300f
Sample Description/Source Reference
From low severity hydro-
treatment with ICR 106
catalyst, Chevron sample
(Operating conditions:
average catalyst tempera-
ture, 750°F; LHSV, 1.5;
total pressure, 2000 psig:
H2 mean pressure, 1765
psia; recycle gas, 8670
SCF/bbl)
Explanatory Notes
*By difference
'''Batches 4 and 5 were blended with same proportions of atmospheric
overhead, atmospheric bottom and de-ashed vacuum bottoms as Batch 3.
They were not analyzed.
flncludes dissolved water.
141
288
-------
Table 177. Sulfur Content
Material
Coal raw
whole
process
liquids
Value
Process Coal Type (wt %)
SRC-II KY No. 9 0.29
and 14,
IL No. 6
(River
King
Mine)
and
Pitt-Seams
WV
(Black-
ville
No. 2
Mine)
Sample Description/Source
Ft. Lewis pilot plant
(Chevron Sample No.
WOW-3666)
Reference
86
EDS
Pitt-Seams 0.29
WV
(Black-
vine
No. 2
Mine)
Ft. Lewis pilot plant
IL No. 6
(Monterey
Mine)
H-Coal Wyodak
IL No. 6
Wyodak
0.479
0.041
0.31/
0.33
0.025
IL No. 6
0.14
One tpd pilot plant,
once-through mode
PDU, syncrude mode
(Chevron Sample No.
WOW-4137)
PDU, syncrude mode
(Chevron Sample No.
WOW-3919)
PDU, syncrude mode, re-
run whole process liquid
(Chevron Sample No.
SGQ 7064)
PDU, syncrude mode, re-
run whole process liquid
(Chevron Sample No.
SGQ 6979)
IL No. fr 0.22
PDU, syncrude mode
144
144
95
95
95
95
98
(Continued)
289
-------
Table 177 (Continued)
Material
Coal raw
whole
process
liquids
Hydro-
treated
whole
process
liquids
Process Coal Type
H-Coal IL No. 6
(Burning
Star
Mine)
Wyodak
Wyodak
Wyodak
Wyodak
NA
SRC-II Pitt-Seams
WV
(Black-
ville
No. 2
Mine)
Value
(wt %)
0.47
0.3
0.4
0.5
0.4
0.70
(Batch 1)*
0.62
(Batch 2)
0.57
(Batch 3)
NA
(Batch 6)
0.00041
Sample Description/Source Reference
PDU, Ashland Oil sample
POU Run 10 (ORNL Sample
27B)
POU Run 10 (ORNL Sample
34A)
PDU Run 10 (ORNL Sample
42A)
PDU Run 10 (ORNL Sample
43A)
PDU Run 130-73
Pitt-Seams
WV
(Black-
ville
No. 2
Mine)
0.00046
From high severity hydro-
treatment with ICR 106
catalyst, Chevron sample
(Operating conditions:
average catalyst tempera-
ture, 750'F; LHSV, 1.0;
total pressure, 2500 psig;
H2 mean pressure, 2325
psia; recycle gas, 14,550
SCF/bbl)
From intermediate severity
hydrotreatment with ICR
106 catalyst, Chevron
Sample (Operating condi-
tions: average catalyst
temperature, 750°.F; LHSV,
1.5; total pressure, 2500
psig; \\2 mean pressure,
2345 psia; recycle gas,
14,830 SCF/bbl)
(Continued)
290
96
146
146
146
146
145
141
141
-------
Material
Hydro-
treated
whole
process
liquids
Table 177 (Concluded)
Process Coal Type
SRC-11
Pitt-Seams
WV
(Black-
vine
No. 2
Mine)
Value
(wt %)
0.0010
Explanatory Notes
Sample Description/Source Reference
From low severity hydro-
treatment with ICR 106
catalyst, Chevron sample
(Operating conditions:
average catalyst tempera-
ture, 750°F; LHSV, 1.5;
total pressure, 2000 psig;
\\2 mean pressure, 1765
psia; recycle gas, 8070
SCF/bbl)
141
*Batches 4 and 5 were blended with same proportions of atmospheric
overhead, atmospheric bottom and de-ashed vacuum bottoms as Batch 3.
They were not analyzed.
291
-------
Table 178. Nitrogen Content
Material
Coal raw
whole
process
liquids
Value
Process Coal Type (wt %)
SRC-II KY No. 9 0.85
and 14,
IL No. 6
(River
King
Mine)
and
Pitt-Seams
WV
(Black-
ville
No. 2
Mine)
Sample Description/Source
Ft. Lewis pilot plant
(Chevron Sample No.
WOW-3666)
Reference
86
EDS
Pitt-Seams 0.85
WV
(Black-
vine
No. 2
Mine)
Ft. Lewis pilot plant
IL No. 6
(Monterey
Mine)
H-Coal Wyodak
IL No. 6
Wyodak
IL No. 6
IL No. 6
(Burning
Star
Mine)
0.48
0.17
0.44/
0.48
0.15
0.33
0.81
One tpd pilot plant,
once-through mode
POD, syncrude mode
(Chevron Sample No.
WOW-4137)
PDU, syncrude mode
(Chevron Sample No.
WOW-3919)
PDU, syncrude mode, re-
run whole process liquid
(Chevron Sample No. SGQ
7064)
PDU, syncrude mode, re-
run whole process liquid
(Chevron Sample No. SGQ
6979)
PDU, Ashland Oil sample
(Continued)
292
144
144
95
95
95
95
96
-------
Table 178 (Continued)
Material
Coal raw
whole
process
liquids
Process
H-Coal
Hydro-
treated
whole
process
liquids
SRC-II
Coal Type
Wyodak
Wyodak
Wyodak
Wyodak
NA
Value
(wt X)
0.7
0.8
0.8
0.7
Sample Description/Source Reference
PDU Run 10 (ORNL Sample
27B)
PDU Run 10 (ORNL Sample
34A)
PDU Run 10 (ORNL Sample
42A)
PDU Run 10 (ORNL Sample
43 A)
Pitt-Seams
WV
(Black-
ville
No. 2
Mine)
(Batch 1)*
(Batch 2)
(Batch 3)
(Batch 6)
0.000045
Pitt-Seams
WV
(Black-
ville
No. 2
Mine)
0.0021
From high severity hydro-
treatment with ICR 106
catalyst, Chevron sample
(Operating conditions:
average catalyst tempera-
ture, 750°F; LHSV, 1.0;
total pressure, 2500 psig;
H2 mean pressure, 2325
psia; recycle gas, 14,550
SCF/bbl)
From intermediate severity
hydrotreatment with ICR
106 catalyst, Chevron
sample (Operating condi-
tions: average catalyst
temperature, 750°F; LHSV,
1.5; total pressure, 2500
psig; Hj? mean pressure,
2345 psia; recycle gas,
14,830 SCF/bbl)
146
146
146
146
145
141
141
(Continued)
293
-------
Material
Hydro-
treated
whole
process
liquids
Table 178 (Concluded)
Process Coal Type
SRC-11
Pitt-Seams
WV
(Black-
vine
No. 2
Mine)
Value
(wt %)
0.0513
Explanatory Notes
Sample Description/Source Reference
From low severity hydro-
treatment with ICR 106
catalyst, Chevron sample
(Operating conditions:
average catalyst tempera-
ture, 750°F; LHSV, 1.5;
total pressure, 2000 psig;
\\2 mean pressure, 1765
psia; recycle gas, 8070
SCF/bbl)
141
*Batches 4 and 5 were blended with same proportions of atmospheric
overhead, atmospheric bottom and de-ashed vacuum bottoms as Batch 3.
They were not analyzed.
294
-------
Table 179. Carbon Content
Value
(wt %}
84.68
Material Process Coal Type
Coal raw SRC-11 KY No. 9
whole and 14,
process IL No. 6
liquids (River
King
Mine)
and
Pitt-Seams
WV
(Black-
vine
No. 2
Mine)
Pitt-Seam, 84.61
WV
(Black-
vine
No. 2
Mine)
H-Coal Wyodak 86.20
IL No. 6 86.94
IL No. 6 86.13
Sample Description/Source Reference
Ft. Lewis pilot plant 86
(Chevron Sample No.
WOW-3666)
Ft. Lewis pilot plant
IL No. 6
(Burning
Star
Mine)
Wyodak
Wyodak
Wyodak
87.6 P
77.9 P
2
78.7 P
3
78.4 P
4
(Continued)
295
POU, syncrude mode
(Chevron Sample No.
WOW-4137)
PDU, syncrude mode
(Chevron Sample No.
WOW-3919)
PDU, syncrude mode, re-
run whole process liquid
(Chevron Sample No. SGQ
6979)
PDU, Ashland Oil sample
PDU Run 10 (ORNL Sample
27B)
PDU Run 10 (ORNL Sample
34A)
PDU Run 10 (ORNL Sample
144
95
95
95
96
146
146
146
-------
Material
Coal raw
whole
process
liquids
Table 179 (Concluded)
Process Coal Type
H-Coal Wyodak 80.3
NA
Explanatory Notes
Value
(wt %)
Sample Description/Source Reference
146
PDU Run 10 (ORNL Sample
43A)
(Batch 1)* PDU Run 130-73
(Batch 2)
(Batch 3)
(Batch 6)
145
*Batches 4 and 5 were blended with same proportions of atmospheric overhead,
atmospheric bottom and de-ashed vacuum bottoms as Batch 3. They were not
analyzed.
296
-------
Table 180. Hydrogen Content
Material
Coal raw
whole
process
liquids
Process Coal Type
SRC-II
EDS
KY No. 9
and 14,
IL No. 6
(River
King
Mine)
and
Pitt-Seams
WV
(Black-
ville
No. 2
Mine)
Pitt-Seams
WV
(Black-
vine
No. 2
Mine)
IL No. 6
(Monterey
Mine)
H-Coal Wyodak
IL No. 6
IL No. 6
IL No. 6
(Burning
Star
Mine)
Wyodak
Wyodak
Value
(wt %} Sample Description/Source Reference
10.54 Ft. Lewis pilot plant
(Chevron Sample No.
WOW-3666)
10.46 Ft. Lewis pilot plant
10.56 One tpd pilot plant,
once-through mode
12.74 PDU, syncrude mode
(Chevron Sample No.
WOW-4137)
11.39 POU, syncrude mode
(Chevron Sample No.
WOW-3919)
11.44 PDU, syncrude mode, re-
run whole process liquid
(Chevron Sample No. SGQ
6979)
7.4 PDU, Ashland Oil sample
6.3 PDU Run 10 (ORNL Sample
27B)
6.2 PDU Run 10 (ORNL Sample
34A)
(Continued)
297
86
144
144
95
95
95
96
146
146
-------
Table 180 (Continued)
Material
Coal raw
whole
process
liquids
Process Coal Type
H-Coal Wyodak
Wyodak
NA
Hydro-
treated
whole
process
liquids
SRC-II
Value
(wt %)
6.7
7.2
Sample Description/Source Reference
146
PDU Run 10 (ORNL Sample
42A)
POU Run 10 (ORNL Sample
43A)
6.71 PDU Run 130-73
(Batch 1)*
7.15
(Batch 2)
7.30
(Batch 3)
7.38
(Batch 6)
Pitt-Seams
WV
(Black-
vine
No. 2
Mine)
12.8
Pitt-Seams 12.1
WV
(Black-
vi 1 le
No. 2
Mine)
From high severity hydro-
treatment with ICR 106
catalyst, Chevron sample
(Operating conditions:
average catalyst tempera-
ture, 750°F; LHSV, 1.0;
total pressure, 2500 psig;
H2 mean pressure, 2325
psia; recycle gas, 14,550
SCF/bbl)
From intermediate severity
hydrotreatment with ICR
106 catalyst, Chevron
sample (Operating condi-
tions: average catalyst
temperature, 750°F; LHSV,
1.5; total pressure, 2500
psig; \\2 mean pressure,
2345 psia; recycle gas,
14,830 SCF/bbl)
146
145
141
141
(Continued)
298
-------
Material
Hydro-
treated
whole
process
liquids
Table 180 (Concluded)
Process Coal Type
Value
(wt %)
SRC-II
Pitt-Seams 11.4
WV
(Black-
vine
No. 2
Mine)
Explanatory Notes
Sample Description/Source Reference
From low severity hydro-
treatment with ICR 106
catalyst, Chevron sample
(Operating conditions:
average catalyst tempera-
ture, 750°F; LHSV, 1.5;
total pressure, 2000 psig;
H2 mean pressure, 1765
psia; recycle gas, 8070
SCF/bbl)
141
*Batches 4 and 5 were blended with same proportions of atmospheric overhead,
atmospheric bottom and de-ashed vacuum bottoms as Batch 3. They were not
analyzed.
299
-------
Table 181. Trace Element Content (ppmw)
CO
o
o
Material
Coal raw
whole
process
liquids
Process Coal Type Ti
SRC-II Pittsburgh 1.4
(Powhattan
No. 5 Al
Mine)
<0.5
Sb
0.00185
il
0.034
Na
0.095
Sc
0.00023
Ce
<0.004
Th
<0.0004
Ga
0.00031
V
<0.01
Cl
0.538
Se
0.064
Co
0.00135
Rb
<0.007
Tb
<0. 00006
La
0.00091
U
<0.0015
Zr
NO
Ca
98
Mn
0.010
"a
0.057
Cr
0.021
Cs
0.00047
Eu
0.000078
Sr
<0.12
Hf
<0.0003
Cu
5.88
Mj Sample Description/Source Refereru
<6 Ft. Lewis pilot plant 140
As
0.064
B£
0.00918
£e
2.43
K
0.22
Sm
0.000052
Ba
0.082
Ta
<0.0002
Zn
0.021
Hydro-
treated
whole
process
liquids
NA
-------
Table 182. Ash Content (by Ultimate Analysis)
Material
Coal raw
whole
process
liquids
Value
Process Coal Type (wt %)
SRC- I I KY No. 9 0.004
and 14,
IL No. 6
(River
King
Mine)
and
Pitt-Seams
WV
(Black-
vine
No. 2
Mine)
Sample Description/Source
Ft. Lewis pilot plant
(Chevron Sample No.
WOW-3666)
Reference
86
Hydro-
treated
whole
process
liquids
H-Coal Wyodak <0.002
IL No. 6 0.009
Wyodak <0.003
NA
IL No. 6 <0.002
PDU, syncrude mode
(Chevron Sample No.
WOW-4137)
PDU, syncrude mode
(Chevron Sample No.
WOW-3919)
PDU, syncrude mode, re-
run whole process liquid
(Chevron Sample No. SGQ
7064)
PDU, syncrude mode, re-
run whole process liquid
(Chevron Sample No. SGQ
6979)
95
95
95
95
301
-------
Table 183. Saturates and Aromatics Content
Material
Coal raw
whole
process
liquids
A. Saturates
Process Coal Type
SRC-II
Hydro-
treated
whole
process
liquids
SRC-II
NA
H-Coal Wyodak
IL No. 6
Wyodak
IL No. 6
Pitt-Seams
WV
(Blackville
No. 2 Mine)
Pitt-Seams
WV
(Blackville
No. 2 Mine)
Value
(Vol %)
44.6
56.1
44.6
47.2
45.7
82.2
65.8
Sample Description/Source Reference
Ft. Lewis pilot plant 94
(Chevron Sample No.
WOW-3666)
PDU, syncrude mode 95
(Chevron Sample No.
WOW-4137)
PDU, syncrude mode 95
(Chevron Sample No.
WOW-3919)
PDU, syncrude mode, rerun 95
whole process liquid
(Chevron Sample No.
SGQ 7064)
PDU, syncrude mode, rerun 95
whole process liquid
(Chevron Sample No.
SGQ 6979)
From high severity hydro- 141
treatment with ICR 106
catalyst, Chevron sample
(Operating conditions:
average catalyst temper-
ature, 750°F; LHSV, 1.0;
total pressure, 2500 psig;
\\2 mean pressure,
2325 psia; recycle gas,
14,550 SCF/bbl)
From intermediate severity 141
hydrotreatment with ICR
106 catalyst, Chevron
Sample (Operating condi-
tions: average catalyst
temperature, 750°F; LHSV,
1.5; total pressure, 2500
psig; \\2 mean pressure,
2345 psia; recycle gas,
14,830 SCF/bbl)
(Continued)
302
-------
Table 183 (Continued)
Material
Hydro-
treated
whole
process
liquids
Process Coal Type
SRC-II
H-Coal
Coal raw
whole
process
liquids
B. Aromatics
SRC-II
Pitt-Seams
WV
(Blackville
No. 2 Mine)
NA
NA
Wyodak
IL No. 6
NA
H-Coal Wyodak
IL No. 6
Wyodak
IL No. 6
Value
(Vol %)
52.3
51.3
96.5
88.5
81.5
55.2
43.9
55.4
52.8
54.3
Sample Description/Source Reference
From low severity hydro-
treatment with ICR 106
catalyst, Chevron sample
(Operating conditions:
average catalyst temper-
ature, 750'F; LHSV, 1.5;
total pressure, 2000 psig;
H2 mean pressure,
1765 psia; recycle gas,
8070 SCF/bbl)
Ft. Lewis pilot plant,
moderate severity hydro-
treatment
Ft. Lewis pilot plant,
high severity hydro-
treatment
POU, from medium severity
hydrotreatment
PDU, from high
hydrotreatment
severity
Ft. Lewis pilot plant
(Chevron Sample No.
WOW-3666)
POU, syncrude mode
(Chevron Sample No.
WOW-4137)
POU, syncrude mode
(Chevron Sample No.
WOW-3919)
POU, syncrude mode, rerun
whole process liquid
(Chevron Sample No.
S6Q 7064)
PDU, syncrude mode, rerun
whole process liquid
(Chevron Sample No.
SGQ 6979)
141
128
129
128
128
94
95
95
95
95
(Continued)
303
-------
Table 183 (Concluded)
Material
Hydro-
treated
whole
process
1iquids
Process Coal Type
SRC-11
Pitt-Seams
WV
(Blackville
No. 2 Mine)
Value
(Vol %)
17.8
Pitt-Seams 34.2
WV
(Blackville
No. 2 Mine)
Pitt-Seams
WV
(Blackville
No. 2 Mine)
NA
NA
H-Coal Wyodak
IL No. 6
47.7
48.7
3.9
11.5
18.5
Sample Description/Source Reference
From high severity hydro-
treatment with ICR 106
catalyst, Chevron sample
(Operating conditions:
average catalyst temper-
ature, 750°F; LHSV, 1.0;
total pressure, 2500 psig;
\\2 mean pressure,
2325 psia; recycle gas,
14,550 SCF/bbl)
From intermediate severity
hydrotreatment with ICR
106 catalyst, Chevron
sample (Operating condi-
tions: average catalyst
temperature, 750°F; LHSV,
1.5; total pressure, 2500
psig; \\2 mean pressure,
2345 psia; recycle gas,
14,830 SCF/bbl)
From low severity hydro-
treatment with ICR 106
catalyst, Chevron sample
(Operating conditions:
average catalyst temper-
ature, 750°F; LHSV, 1.5;
total pressure, 2000 psig;
\\2 mean pressure,
1765 psia; recycle gas,
8070 SCF/bbl)
Ft. Lewis pilot plant,
moderate severity hydro-
treatment
Ft. Lewis pilot plant,
high severity hydro-
treatment
PDU, from medium severity
hydrotreatment
PDU, from high
hydrotreatment
severity
141
141
141
128
129
128
128
304
-------
Table 184. Detailed Hydrocarbon Class Analysis
co
o
on
Material Process
Coal raw
whole
process
liquids
Hydro-
treated
whole
process
liquids
SRC-11
Coal
Type
NA
NA
Compound Class
Monocycloparaffins
Bicycloparaffins
Tricycloparaffins
Alkylbenzenes
Indans and tetralins
Dinaphthenebenzenes
Naphthalenes
Value
(Vol %) Sample Description/Source
11.9
8.4
19
15
26
3.7
9.4
Ft. Lewis pilot plant
(Chevron Sample No.
WOW-3666)
Reference
94
-------
Table 185.
Material Process Coal Type
Additional Hydrocarbon Compound Class Analysis
Obtained by Solvent Fractionation
Coal raw SRC- 1 1
whole
process
liquids
KY No. 9 Hot
and 14, Heptane
IL No. 6 Asphaltenes
(River
King Mine) Benzene
and Pitt- Insolubles
Seams WV
(Blackville
No. 2 Mine)
Value (wt %)
CO
o
en
Pitt-Seams Benzene
WV Insolubles
(Blackville
No. 2 Mine)
H-Coal Wyodak
IL No. 6
Wyodak
IL No. 6
Hot Cy
insolubles
Hot C7
insolubles
Hot C7
insolubles
Hot C7
insolubles
Sample Description/Source Reference
0.0468 Ft. Lewis pilot plant 86
(Chevron Sample No.
WOW-3666)
<0.03
0.03 Ft. Lewis pilot plant 144
0.0068 PDU, syncrude mode 95
(Chevron Sample No.
WOW-4137)
0.35 PDU, syncrude mode 95
(Chevron Sample No.
WOW-3919)
<0.0010 PDU, syncrude mode, rerun 95
whole process liquid
(Chevron Sample No.
SGQ 7064)
0.0054 PDU, syncrude mode, rerun 95
whole process liquid
(Chevron Sample No.
SGQ 6979)
(Continued)
-------
Table 185 (Continued)
Material Process Coal Type
Coal raw H-Coal Wyodak
whole
process
liquids
co
o
Wyodak
Wyodak
Value (wt %)
Pentane solubles 54.5
and benzene
solubles (oils)
Pentane 4.5
insolubles and
benzene solubles
(asphaltenes)
Pyridine solubles 4.9
and benzene
insolubles
(preasphaltenes)
Pyridine 36.1
Insolubles and
benzene insolubles
(residue)
Pentane solubles 52.9
benzene solubles
(oils)
Pentane insolubles 8.6
and benzene
solubles
(asphaltenes)
Sample Description/Source Reference
PDU Run 10 (ORNL Sample 146
27B)
PDU Run 10 (ORNL Sample
27B)
PDU Run 10 (ORNL Sample
34A)
146
146
(Continued)
-------
Table 185 (Continued)
Material Process Coal Type
Coal raw H-Coal Wyodak
whole
process
liquids
Wyodak
CO
o
CO
Value (wt %)
Pyridine solubles 5.6
and benzene
Insolubles
(preasphaltenes)
Pyridine 32.9
insolubles and
benzene Insolubles
(residue)
Pentane solubles 59.4
and benzene
solubles (oils)
Pentane insolubles 7.2
and benzene
solubles
(asphaltenes)
Pyridine solubles 4.7
and benzene
insolubles
(preasphaltenes)
Pyridine 28.7
insolubles and
benzene Insolubles
(residue)
Sample Description/Source Reference
PDU Run 10 (ORNL Sample 146
34 A)
PDU Run 10 (ORNL Sample
42A)
146
(Continued)
-------
Table 185 (Concluded)
o
lO
Material Process Coal Type
Coal raw H-Coal Wyodak
whole
process
liquids
Hydro-
treated
whole
process
liquids
NA
Value (wt %)
Pentane solubles 67.8
and benzene
solubles (oils)
Pentane Insolubles 9.0
and benzene
solubles
(asphaltenes)
Pyridine solubles 0.7
and benzene
Insolubles
(preasphaltenes)
Pyridine 22.5
Insolubles and
benzene Insolubles
(residue)
Sample Description/Source Reference
PDU Run 10 (ORNL Sample 146
43A)
-------
Table 186*. Nitrogen-Containing Compound Classes
Material Process Coal Type
Wyodak
Coal raw H-Coal
process
liquids
Hydro-
treated
whole
process
liquids
NA
Value (wt %)
Sample Description/Source Reference
Basic Nitrogen
IL No. 6 Basic Nitrogen
0.13 PDU, syncrude mode
(Chevron Sample No.
WOW-4137)
0.13/ PDU, syncrude mode
0.30 (Chevron Sample No.
WOW-3919)
95
95
OJ
o
-------
Table 187. Individual Sulfur-Containing Compounds
Material
Type Hoi Wt
Compound
Staple DesertptIon/Source Reference
Co*1 raw
whole
process
liquids
SRC-1
No. 9
Sulfur Heterocycle Chroaatographlc fraction SO Ib/day POU
139
134
136
ISO
148
150
148
150
164
164
164
164
164
162
162
162
162
184
178.
184
198
198
212
212
212
208
222
222
234
234
234
248
248
248
262
262
258
benzo(b)thlophene*
2.3-d)hydrobenzo[b]thtophene
Ci-d1hydrobenzo[b]th1ophenef
Ci-benzo[b]th1ophene
Cj-dthydrobenzo b]thtophene
3-methy)benzo[b thlophene*
Cj-dlhydrobenzo blthlophene
Cj-dlhydrobenzo V thlophene
Cj-dthydrobenzo V thlophene
Cj-dthydrobenzo b]thlophene
Cj-dthydrobenzo bjthlophene
Cj-dthydrobenzo bjthlophene
5-ethylbenzo[b]th1ophene*
C2-benzo[b]th1ophene
C2-benzo[b]th1ophene
C?-benzo[b]thlophene
dibenzothlophene (and/or
n
-------
Table 187 (Concluded)
Material Process Coil Type Hoi Ht
Compound
Sample Description/Source Reference
Coal raw
whole
process
liquids
SRC-11
Pittsburgh
No. 8
CO
ro
NA
b]
tt
V
b
b
b
b
thlophene
lophene*
thlophene
thlophene
thlophene
thlophene
thlophene
Sulfur Heterocycle Chromatographlc Fraction
134 benzo(b)th1ophene*
136 2.3-dlhydrobenzo[b]th1ophene
150 C]-d1hydrobenzo[b]thlophenet
150 C]-dfhydrobenzo[b]thlophene
M8 Ci-benzo[b]th1ophene
150 Ci-dlhydrobenzo
148 3-aethylbenzo[b
150 Cj-dlhydrobenzo
164 Cj-dlhydrobenzoj
164 Cj-dlhydrobenzo
164 Cj-dlhydrobenzoj
164 Cj-dihydrobenzoL
162 5-ethylbenzo[b]th1ophene*
162 C?-benzo[b]thlophene
184 dlbenzothlophene (and/or
iuphtho[1.2-b]th1ophene)*
178, phenanthrene and naphtho[2,l-b]th1ophenc*
184
198 Ci-dtbenzothlophene
198 Cj-dlbeniothlophene
198 C)-d1benzoth1ophene
212 Cj-dlbenzothlophene
212 Cj-dtbenzothlophene
212 C2-d1benzoth1ophene
212 Cj-dibenzothlophene
208 pnenanthro[4,5-bcd]th1ophene
222 Ci-phenanthro[4,5-bcd]th
-------
Table 188. General Physical and Chemical Properties Data for Various Distillation Fractions
of Raw and Hydrotreated Whole Process Liquids
Material Process
Coal
raw
whole
process
liquids
SRC-11
co
CO
Coal Type
Powhattan
No. 5
Distillation
Fraction No.
1
2
3
4
6
6
7
a
9
10
11
12
13
M*
IS
16
17
18
19
Distillation
Data
50 Utft Off
leap.. *F
152
211
249
279
332
384
428
485
526
572
648
711
749
570
696
757
821
890
969
Holecular Height
Gravity
64.4.63.8
52.5.52.0
52.5.52.2
42.7.42.6
27.0.26.2,26.3
17.2.16.5
15.6,15.5
13.6,13.3,13.5
13.2.12.5
10.6.10.3
5.1.4.4.4.5
0.0, -0.8
-2.1.-1.7
7.4.7.5
0.0. .-0.3
-2. 2. -2. 9, -3. 2
-5. 2, -5.0
-8. 9. -12.9
-13.1
Pour
Point, *F
<-65
<-65
<-6S
<-65
<-6S
<-65
<-65
-45
-30
0
40
65
85
15
70
85
100
150
210
Cryoscoplc
85
95
108
114
131
126
140
154
MA
HA
NA
MA
NA
NA
NA
NA
HA
NA
NA
Vapor Pressure
Osmometry Sample Description/Source Reference
NA PDU P-99 143
NA
NA
NA
118
128
137
163
156
166
230.214
246,247
243
189
214
238.247
251
310.304
363.320
(Continued)
-------
Table 188 (Continued)
Distillation API Viscosity GC Simulated
Material Process Coal Type Fraction Gravity (Centlstofces) Distillation
Gun
Content Freeze
(ag/100 ml) Point (*F)
Coal H-Coal tyodak
raw
whole
process
liquids
CO
Kyodak
Cj-lBO-F
180-250«F
250*F*
250'F*
250*F*
69.7
53.7
250-300°F 46.6
300-350'F 37.9
350'F* 23.0
IL No. 6 250'F* 36.3
37.8
39.4
39.3
HA
MA
HA
2.581
(100'F)
1,194
(130'F)
HA
HA
HA
HA
HA
18/45'F- IBP/5 HA
83/136°F-10/30
159'F-50
172/187*F-70/90
192/200«F-95/99
152/178°F-IBP/5 HA
182/207*F-10/30
224-F-50
232/251'F-70/90
259/273'F-95/99
203/245'F- IBP/5 HA
252/272*F-10/30
283-F-50
296/313-F-70/90
323/332'F-95/99
244/298'F- IBP/5 HA
305/323'F- 10/30
337'F-SO
350/363'F- 70/90
368/375°-95/99
298/361°F-lBP/5 HA
374/416'F-10/30
457'F-50
514/649-F-70/90
677/785°F-95/99
589*F-EP 500
530'F-EP 2
591*F-EP ^500
<572°F-EP Probably
<7
(Continued)
HA
HA
HA
HA
HA
HA
HA
-27
<-94
Sample Description/Source Deference
POU. syncrude node 95
250°F+ distillate. PDU, 95
syncrude node
250°F* rerun distillate. 95
PDU, syncrude node
250'F* distillate. PDU, 95
syncrude node
250-F+ rerun distillate, 95
POU, syncrude node
-------
Table 188 (Continued)
Hydro-
trtttri
•holt
proctst
tlquld»
SKC-II M
CO
tn
Rcutrck
ATI
41.1
4*.I
4S.7
2».J
24.7
20.(
AnlltM
PolnlCFI
H.I
M.I
71. (
Ut.i
tl.f
-------
Table 188 (Concluded)
CO
—i
CT>
Distillation API
Material Process Co*) Type Friction Gravity
Hydro- H-Coal IL No. 6 C5-180*f 73.8
treated
whole
process
liquids
180-315°F 51.1
IL No. 6 Cs-180'F 72.9
180-315*F 51.5
IL No. 6 C5-180'F 72.3
180-315*F 51.4
Octane No. Octane No. Distillation
F-l. Clear F-2, Clear Data (*F)
88.6 83.1 96/111-F-IBP/5
115/126'F-10/30
139'F-SO
151/161'F-70/90
165/167*F-95/EP
£8.5 69.5 213/222'F- IBP/5
225/236^-10/30
249-F-50
268/296*F- 70/90
305/34fl*F-95/EP
68.5 82.8 96/112-7- IBP/5
117/128*F-10/30
138°F-50
146/160^-70/90
165/167'F-95/EP
69.2 70.0 210/222'F- IBP/5
226/236-F- 10/30
246*F-50
262/291«F-70/90
301/336'F-95/EP
88.3 83.1 100/116°F-IBP/S
120/131«F-10/30
142*F-50
153/162"F-70/90
166/WF-95/EP
69.0 69.8 210/223°F-IBP/5
226/234 "F- 10/30
248'F-SO
265/294'F- 70/90
300/310-F-95/EP
6C Simulated
Distillation
M
160/192'F- IBP/5
199/224-F-10/30
2S2°F-50
284/320'F-70/90
327/335-F-95/99
HA
160/192*F-IBP/S
200/225'F- 10/30
253*F-50
284/317'F-70/90
324/332-F-95/99
NA
161/193*F-IBP/5
200/225°F- 10/30
254"F-50
285/318-F-70/90
324/331°F-95/99
Sample Description/Source Reference
From 315°F extinction 95
recycle hydrocracktng of
denitrified whole coal
liquid Chevron Sample No.
UOU-4022 over fresh 1CR
202 catalyst, PDU Run
62-266, Run Hours 339-363.
Operating conditions:
average catalyst tempera-
ture, 580°F; LHSV. 1.70.
Fron 315"F extinction 95
recycle hydrocracktng of
denitrified whole coal
liquid Chevron Sample
No. WOU-4022 over fresh
ICR 202 catalyst. PDU
Run 62-266, Run Hours
363-387. Operating con-
ditions: average catalyst
tenperature. 450°F; LHSV.
1.70.
Proa 315*F extinction 95
recycle hydrocracking of
denitrified whole coal
liquid Chevron Sample No.
UOU-4022 over fresh ICR
202 catalyst, PDU Run
62-266, Hun Hours 435-459.
Operating conditions:
average catalyst tempera-
ture. 583°F; LHSV. 1.70.
Explanatory Notes
•405-710'F front-end material obtained from second distillation, Sample No. 80-0-14.
-------
Table 189. Elemental Composition Data for Various Distillation Fractions
for Raw and Hydrotreated Whole Process Liquids
Elemental Composition.
LO
Material
Cotl raw
whole
process
liquids
Olstllla-
tton
Process Coal Type Fraction
SRC- II Powhattan No. 1
"°'B No. 2
No. 3
No. 4
No. 6
No. 6
No. 7
No. 8
No. 9
No. 10
No. 11
No. 12
No. 13
No. 14
Ho. 15
No. 16
No. 17
No. 18
No. 19
H-Coal Kyodjk C5-180
180-250
250-300
300-350
350«F+
50 wtS
Off Teup
•f
152
211
249
279
332
384
428
485
526
572
648
711
749
570
696
757
821
890
969
NA
NA
NA
NA
NA
C
84.
86.
85.
87.
83.
83.
84.
86.
87.
88.
88.
89.
90.
88.
88.
89.
88.
88.
89.
NA
NA
NA
HA
HA
28
02
73
22
98
56
61
12
35
33
84
08
38
12
66
10
70
63
31
Ut 1
H
14.43
13.33
13.66
12.44
10.48
9.49
9.35
9.25
9.64
8.96
8.13
7.68
7.70
8.37
7.66
7.34
7.27
7.02
6.32
NA
NA
HA
HA
NA
(Dry Basis)
N
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
1.
1.
1.
0.
1.
1.
1.
1.
1.
0.
0.
0.
0.
0.
55
24
27
a
36
82
72
17
85
76
10
13
28
90
31
39
56
75
82
38
014
0415
1435
25
0
0.67
0.33
0.24
0.08
4.70
6.06
5.19
3.15
1.95
1.78
1.59
1.87
0.27
2.29
1.90
1.81
2.03
1.99
1.98
0.50
0.12
0.90
1.43
NA
S
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
Staple Description/Source
07 POU P-99
08
10
15
48
07
13
31
21
17
34
24
37
32
47
36
44
61
57
0211 POU. syncrude mod*
0256
0438
0430
0240
Reference
143
95
(Continued)
-------
Table 189 (Concluded)
Elemental Composition,
Material
Hydro-
treated
whole
process
liquids
Distilla-
tion
Process Coal Type Fraction
SRC- 1 1 NA NA
NA
50 wtX
Off Temp
•f
NA
NA
Wt % (Dry Basis)
C H N
NA 13.8 NA
NA 13.5 0.00073
0
NA
NA
S
NA
NA
Cd
_J
CO
NA
NA
NA
NA
NA
NA
NA
NA
NA 13.3 0.0119 0.3200 NA
NA 13.3 0.00005 NA NA
NA NA 0.0023 NA NA
NA NA 0.0702 0.5500 NA
Sample Description/Source Reference
180-350"F cut, high
severity hydrotreatment
with ICR 106 catalyst
180-350*F cut, medium
severity hydrotreatment
with ICR 106 catalyst
180-350"F cut, low
severity hydrotreatment
with ICR 106 catalyst
350'F+ cut, high
severity hydrotreatment
with ICR 106 catalyst
350'F+ cut, medium
severity hydrotreatment
with ICR 106 catalyst
350*F+ cut, low
severity hydrotreatment
with ICR 106 catalyst
141
-------
co
__j
10
Table 190. Hydrocarbon Analysis
Distillation Fractions for R<
Distilla-
Coal
Material Process Type
Coal raw H-Coal Wyodak
whole
process
liquids
Hydro- SRC- I I NA
treated
whole
process
liquids
tion
Fraction
C5-180*
180-250
250-300
300-350
350 'F+
NA
NA
NA
NA
NA
NA
(Aromatics and
iw and Hydrotrea
Value (vol %)
Aroma-
tics
3.3
8.7
16.6
22.6
55.0
13.1
19.1
23.2
22.9
50.3
66.8
Satu-
rates
96.7
91.3
83.4
77.5
45.0
87.0
80.9
76.8
77.1
49.7
33.2
Saturates Content) of Various
ted Whole Process Liquids
Sample Description/Source
PDU, syncrude mode
180-350'F cut, high
severity hydrotreatment
with ICR 106 catalyst
180-350"F cut, medium
severity hydrotreatment
with ICR 106 catalyst
180-350*7 cut, low
severity hydrotreatment
with ICR 106 catalyst
350°F+ cut, high
severity hydrotreatment
with ICR 106 catalyst
350"F+ cut, medium
severity hydrotreatment
with ICR 106 catalyst
350°F+ cut, low
severity hydrotreatment
with ICR 106 catalyst
Reference
95
141
Explanatory Notes
*Determined by low resolution mass spectrometry.
-------
Table 191. Detailed Hydrocarbon Class/Compound Analysis for Various Distillation
Fractions for Raw and Hydrotreated Whole Process Liquids*
Value
Material
Coal raw
whole
process
liquid
Hydro-
treated
whole
process
liquids
Process Coal Type Compound Class (Vol %) Sample Description/Source Reference
NA
SRC-II NA
CO
ro
o
Paraffins
C6
C7
Cg
C10
Aromatics
C6
C7
Cg
Total
Aromatics
0.07
2.9
3.1
2.4
0.9
NO
Total
Paraffins
Naphthenes
C6
C8
Cg
C10
Total
Naphthenest
9.4
4.8
22.9
21.6
19.2
9.0
ND
77.5
0.1
3.5
4.9
4.5
0.1
13.
(Continued)
1
180-350°F cut, high
severity hydrotreatment
with ICR 106 catalyst
141
-------
Table 191 (Continued)
Material
Hydro-
treated
whole
process
liquids
Process Coal Type Compound Class
SRC- I I NA Paraffins
CG
C7
c&
C9
C10
Cll
Total
Paraffins
Naphthenes
C6
Value
(Vol %)
0.05
3.1
3.4
1.7
1.0
0.2
9.5
4.0
Sample Description/Source
180-350°F cut, medium
severity hydrotreatment
with ICR 106 catalyst
Reference
141
u>
X*"
c9
C10
Total
Naphthenest
Aromatics
C6
C7
C8
C9
C10
Total
Aromatic
22.4
19.9
17.7
7.3
0.1
71.4
0.1
4.8
7.3
5.1
1.8
19.1
(Continued)
-------
Material
Hydro-
treated
whole
process
liquids
Table 191 (Continued)
Value
Process Coal Type Compound Class (Vol %) Sample Description/Source Reference
SRC-11 NA
CO
ro
ro
Paraffins
C6
C7
CB
C9
C10
Total
Paraffins
Naphthenes
Cg
C7
Cg
ClO
Cii
0.2
3.3
3.7
2.8
1.2
0.1
11.3
5.2
20.6
17.4
15.2
6.6
0.5
Total
Naphthenes
Aromatics
65.6
Cg
c7
Cg
C10
Total
Aromatics
0.4
5.6
8.5
6.0
2.7
23.2
141
180-350°cut, low
severity hydrotreatment
with ICR 106 catalyst
(Continued)
-------
Table 191 (Continued)
Material
Hydro-
treated
whole
process
liquids
Process Coal Type Compound Class
Value
(Vol %)
SRC-II NA
co
ro
CJ
Total Paraffins 6.5
Cycle- 2.4
paraffins
Dicyclo- 47.5
paraffins
TMcyclo- 20.7
paraffins
Total Naphthenes 70.6
Alkylbenzenes 5.1
Indans/Tetra- 15.2
lins
Benzodlcyclo- 1.2
paraffins
Naphthalenes 0.2
Benzolndans/ 1.2
Benzotetrallns
Total Aromatics 22.9
Total Paraffins 4.7
Cyclo- 9.9
paraffins
Dicyclo- 22.9
paraffins
Tricyclo- 12.2
paraffins
Total Naphthenes 45.0
Alkylbenzenes 9.5
Indans/Tetra- 34.9
lins
Benzodi- 3.5
cycloparaffins
Naphthalenes 1.1
Benzoindans/ 1.4
Benzotetralins
Total Aromatics 50.4
(Continued)
Sample Description/Source Reference
350°F+ cut, high
severity hydrotreatment
with ICR 106 catalyst
141
350°F+ cut, medium
severity hydrotreatment
with ICR 106 catalyst
-------
Table 191 (Concluded)
ro
-F*
Material
Hydro-
treated
whole
process
liquids
Process Coal Type Compound Class
SRC-11 NA
Total Paraffins
Cyclo-
parafflns
Dlcyclo-
parafflns
Trlcyclo-
parafflns
Total Naphthenes
Alkylbenzenes
Indans/Tetra-
11ns
Benzodi-
cycloparafflns
Naphthalenes
Benzolndans/
Benzotetralins
Total Aromatlcs
Value
(Vol %)
5.2
6.6
9.7
11.7
28.0
11.5
43.8
5.3
2.5
3.7
66.8
Sample Description/Source Reference
350°F+ cut, low
severity hydrotreatment
with ICR 106 catalyst
141
Explanatory Notes
*D1str1but1on by chromatography.
^Includes 6.4 vol % dlcycloparafflns (by mass spectroscopy).
fIncludes 5.5 vol % dlcycloparafflns (by mass spectroscopy).
-------
Table 192. Additional Detailed Hydrocarbon Class/Compound Analysis
for Various Distillation Fractions for Raw and
Hydrotreated Whole Process Liquids
froctn Cot\ lyn
OlitllUtlM FncttM He.
80 Ht I Off Toy, 'f
I 2 J 4 S 4 7 » 9 10
I522J124»2»1121044ZII4JS6HIJ2 Sum It PtHflUlM/Sourit Hlftrtnct
Co«l ru
•kalt
•rocilt
co
ro
en
SiC-ll hM*«tl» Sttuntu: Ton I . lit I «f Su?U
to. 6 f«r«»Ut. M 1 »f Slturltd
Cyclop
Pyrtntt - FluorutkcMI
DlhydrofiyrmM
Octikydropktuntkrtmi
Hi>ikydraplHR«itkrtH$
T*tr«kydri>pktiiutkr«ii«l
rktnintkrtMi
Fluur«nt>-Dlkydro|ilwniiitkr«Ml
TttrthydrMctMpktkiMI
HtpktluUn*t
iMItlMS
(Uphtkali
-10
-12
-4
OUf Ui: Toul. Kt I *f
4.0 74. (
S.4 11.
4.2 U.
0.0 0.
.2 0.
.2 0.
.0 IS.
.0 0.
.0 0.
.0 0.
.0 0.
.0 0.
0.0 0.
0.0 0.
ft.O 0.
0.0 0.
0.0 0.
B.O 0.
o.'o o!
0.0 0.
o.o a.
0.0 0.
0.0 0.
0.0 M.
D.O 0.
0.0 0.
0.0 0.
1.0 1.
I 76. i t<
U.( 21
41.3 ;
0.0 1
.1 I
.2 1
1 .f 1
.0 1
.0 1
.0
.0
.0
0.0
0.0
0.0
0.0
a.
1.
0.
0.
12. 1
0.
0.
4. 1
i 10.0
1.0 M.O 14. t 14.1
i.J 24.1 41.7 tl.(
t.2 (I.I 12.0 30.1
1.7 (.« 21.1 12.
>.2 0.2 2.1 2.1
1.1 0.« O.t 0.4
1.0 M.O 11. f li.l
1.0 0.0 0.0 0.<
1.0 0.0 0.0 0.
.0 0.0 0.0 0.
.0 0.0 0.0 0.
.0 0.0 0.0 0.
.0 0.0 0.0 0.
.0 0.0 0.0 0.
.0 0.0 0.0 0.
.0 O.I O.I 0.
.* 11. < 29.0 25.
.0 0.0 0.2 1.
.0 0.0 1.2 11.
.4 l».l 10.2 2.
.0 0.7 2.» 1.
I.I 44.1 U.f U.
1.0 6.0 2.0 2.1
12.0 i.
1 (4.4 61.
1 19. • 21.
14. t t.
1 7.6 f.
1.9 2.
) M.6 M.(
1 O.I O.I
0.0 O.I
0.2 0.
0.6 0.
0.2 0.
0.0 0.
O.t 0.
O.I 1.
t.7 11.
26.9 16.
1.1 t.
JO. 9 U.
6.1 I.
1.6 1.
21.0 «.
> ».»» O.I
4.
64.
11.
J.
4.
1.
) (4.
) 0.
) 0.
.
t
.
.
4 '.
.
) 1.0
PW-99
141
-------
Table 192 (Concluded)
H«t«rl«l
Catl rw
•hoi*
procix
ll^uldi
Coal Iyp«
Olitltlatlon Fraction No.
SO Mt I Off Imt. 'f
10 11 U 11 14 IS
SIC-11
Ponkattan
«•• *
CO
ro
Forwjla troup Typa. t of AroMtlci^
C22H24 DacahydrobaiuckrysaM
C22H22 OctahydroUnickryiaM
C22H20 HaiakydrobtnichrytaM
C22HU TatrahydrolKMCkryioM
C22H14 •aniockryiarw
C20H22 Oacahydrobanipyrant
C20H20 OctahydroBMipyran*
C20HI8 HaiahydrotwupyraM
C20HK TatrahydrobampyrMt
C20HI4 DthydrobanspyraM
C20H12 laniopyraaa
C18H24 Dodacakydrochryiao*
C18H20 Octahydrockryiana
CiaHIt HaiahydrockryitM
C1IH12 Chryitna
CKH20 Dacatiydropyran*
CUHU Haiahydropyruin
CliHU Tatrahydrofluorantka**
CUH10 ryrantfluoriotlwM
CUHU Olhydropyrana/TatrakytfrockryMM
CUHU OctahydropkanantkraA*
C14HK HanaliydrepKtAantkraM
C14H14 TatrahydrapluiwiitkrtiM
C14UIO fhMaAtkrana
CI3HIO Fluorana/OlkydroplwaaitkroM
C12H10 AcanapkthtAa/llpkanyl
CIOHI2 TatraU/PkanylcyclokaUM
CI2HI4 TatrahydroacwiapktkaM
CIOHO kaphtklaiw
UHt lauaM
0.0 0.1
0.0 0.(
0.0 O.I
.0 O.I
0 01
.0 O.I
.a o.i
.0 o.i
.0 O.I
.0 O.I
O.I
O.I
0.
2.
0.
0.
. 14.
4.
. M.
1.
. IS.
2. i.
i. 1.
f. 0.
2. ».
) O.I
I O.I
) O.I
> 0.
1 0
) O.I
) 0.
) 0.
O.I
1.
o!
i.
2«.
U.
0.
0.
2.
2.
0.
O.I 1.2 0.
0.1 1.0 0.
1 1.4 «.5 1.
1 O.I 1.0 0.
) 0.0 0.2 0.
1 11.) 4.1 12.
21.1 24.2 2.
lt.0 22.7 f.
0.0 0.0 2.
0.0 0.0 4.
l.i 0.0 U.
0.0 0.0 1.
0.0 0.0 t.
1.7 0.0 ).
2.) l.i I.
0.0 0.0 0.
O.i .1
l.S .1
1.1 2.4
t O.S f.i
IS.f i.
7.J 14.
11.1 11.
0.0 12.
1.5 0.
l».0 0.
t.t 1.
0.0 0.
I.I 0.
0.0 0.
4.1 7.S 7.4
11.1 <.* 2.
4.) 7.2 0.
i.O 1.1 0.
2. l.f i.
10. I.I 1.
10. 4.0 2.
0. 2.7 4.
0.0 0.0 1.
0.0 O.I 1.
0.0 0.0 0.
0.0 0.0 0.0
0.0 0.0 0.0
0.0 0.* 0.7
JMPU D«»crlptlon/S• Intorfaco kttMan tka arouttc
and olafln groupi.
fjpactral iiulytU for non-polar anwitlct lukfractlon
-------
Table 193. Individual Hydrocarbon Compound Analysis for Various Distillation Fractions
for Raw and Hydrotreated Whole Process Liquids*,t
Haterlal
Coal raw
Mhole
process
liquid
Process Coal Type
SRC-11
Powhatttn
No. S
to
ro
HA
Mass Spec-
tronetrlc
Peak Number
1
2
3
4
5
6
7
8
9
10
11
12
13
14
IS
16
17
16
19
20
21
22
23
24
25
26
27
28
29
30
31
32
Molecular
Height
118
132
132
128
146
142
160
154
156
170
168
184
166
198
192
180
184
178
198
206
204
192
204
206
202
202
216
216
230
244
228
258
Saaple Description/Source Reference
Indan
Ci-Indan
Tetralln (1.2.3.4-
tetrahydronaphthalene)
Naphthalene
Ci-Tetr*11n
Cj-Naphthalene
Cg-Tetralln
Blphenyl
Cj-Naphthalene
C3-Naphthalene
Cj-Blphenyl
Ci-Naphthalene
Fluorene
Cs-Naphthalene
€3-Blphenyl
Ci-Fluorene
Dibenzothlophene
Phenanthrene
Cj-Fluorene
Ci-Blphenyl
Phenylnaphthalene
Ci-Phenanthrene
Phenylnaphthalene
Cj-Phenanthrene
Fluoranthene
Pyrene
C]-Pyrene
Benzofluorene
Cj-Pyrene
Cj-Pyrene
Chrysene
^4-Pyrene
PDU P-99
142
Hydro-
treated
whole
process
liquid
Explanatory Notes
•Obtained via capillary col urn gas chrooatography of HPLC fractions.
^Analysis of the 867-967'F cut Indicated the presence of the following compounds: Chrysene. benzanthracene, perylene, benzoperylene,
dlbenzofluranthenes, coronene. azabenzpyrenes, azaperylenes and certain hydroxy- and antno-derlvattves (Reference 142).
-------
Part VII. Coal Liquid Intermediates
328
-------
Table 194. Specific Gravity
Material
Coal
liquid
inter-
medi ates
Process Coal Type
SRC-I KY No 9
and 14
EDS
KY No. 9
and 14
IL No. 6
0.984
0.9901
(60/60°F)
IL No. 6 0.97 +_ 0.02
(Monterey
Mine)
IL No. 6 0.99 +; 0.01
(Monterey
Mine)
IL No. 6 0.97 + 0.01
(Monterey
Mine)
IL No. 6 0.96
(Monterey
Mine)
0.01
IL No. 6 0.9593
(60/60°F)
IL No. 6 0.94 + 0.02
(Monterey
Mine)
Sample Description/Source Reference
Ft. Lewis pilot plant, 83
process solvent
Ft. Lewis pilot plant, 83
wash solvent
One tpd pilot plant, 99
process solvent from
"typical" run (Run A-5)
One tpd pilot plant, 99
process solvent; average
of three operating
conditions (840°F reactor
temperature; 15-40 minutes
residence time)
One tpd pilot plant, 99
process solvent; operating
conditions: 840°F reactor
temperature, 40 minutes
residence time; average of
ten yield periods
75 Ib per day development 99
unit, process solvent;
average of six operating
conditions (800-880°F
reactor temperature, 25-100
minutes residence time)
75 Ib per day development 99
unit, process solvent;
operating conditions:
840°F reactor temperature,
40 minutes residence time,
average of 21 yield
periods
One tpd pilot plant, 99
hydrogenated recycle
solvent from "typical"
run (Run A-6)
One tpd pilot plant, 99
hydrogenated recycle
solvent; average of three
operating conditions
(840°F reactor temperature;
15-40 minutes residence
time)
(Continued)
329
-------
Table 194 (Continued)
Material Process Coal Type
Value
Coal
liquid
inter-
medi ates
EDS IL No. 6 0.96 HH 0.01
(Monterey
Mine)
IL No. 6 1.1151
(60/60°F)
IL No. 6 1.15 + 0.03
(Monterey
Mine)
IL No. 6 1.12 + 0.07
(Monterey
Mine)
IL No. 6 1.11
(60/60'F)
IL No. 6 1.2800
(60/608F)
Wyodak
Wyodak
0.9590
(60/60'F)
0.98 + 0.01
Sample Description/Source Reference
One tpd pilot plant, 99
hydrogenated recycle
solvent; operating
conditions: 840°F reactor
temperature, 40 minutes
residence time; average of
ten yield periods
One tpd pilot plant, 99
vacuum gas oil from
"typical" run (Run A-2)
One tpd pilot plant, 99
vacuum gas oil; average of
three operating conditions
(840°F reactor temperature;
15-40 minutes residence
time)
One tpd pilot plant, 99
vacuum gas oil; operating
conditions: 840°F reactor
temperature; 40 minutes
residence time; average of
ten yield periods
One tpd pilot plant, coker 99
gas oil from "typical" run
One tpd pilot plant, coker 99
scrubber liquids from
"typical" run
One tpd pilot plant, 99
process solvent from
"typical" run (Run A-5)
One tpd pilot plant, 99
process solvent; average
of six operating
conditions (800-840°F
reactor temperature,
40-100 minutes residence
time)
(Continued)
330
-------
Material
Coal
liquid
inter-
mediates
Table 194 (Continued)
Process Coal Type Value Sample Description/Source Reference
EDS
Wyodak
Wyodak
Wyodak
Wyodak
Wyodak
Wyodak
Wyodak
0.96 + 0.01
0.98 + 0.01
0.99 + 0.01
0.9450
(60/60°F)
0.94 + 0.01
0.94 + 0.01
1.1210
(60/60°F)
(Continued)
331
One tpd pilot plant, 99
process solvent; operating
conditions: 840°F reactor
temperature, 60 minutes
residence time, average of
seven yield periods
75 Ib per day development 99
unit; process solvent;
average of eight operating
conditions (800-880°F
reactor temperature, 25-100
minutes residence time)
75 Ib per day development 99
unit; process solvent;
operating conditions:
880°F reactor temperature,
25 minutes residence time,
average of six yield
periods
One tpd pilot plant, 99
hydrogenated recycle
solvent from "typical" run
(Run A-6)
One tpd pilot plant, 99
hydrogenated recycle
solvent; average of six
operating conditions
(800-840'F reactor
temperature, 40-100
minutes residence time)
One tpd pilot plant, 99
hydrogenated recycle
solvent; operating
conditions: 840°F reactor
temperature, 60 minutes
residence time, average
of seven yield periods
One tpd pilot plant, 99
vacuum gas oil from
"typical" run (Run A-2)
-------
Table 194 (Concluded)
Material
Coal
liquid
inter-
mediates
Process Coal Type
EDS Wyodak
Wyodak
H-Coal
Value
1.12 + 0.08
1.11 + 0.06
Wyodak
Wyodak
IL No. 6
(Burning
Star Mine)
IL No. 6
(Burning
Star Mine)
IL No. 6
(Burning
Star Mine)
1.1540
(60/60'F)
1.2899
(60/60°F)
0.8733
0.935
0.953
Sample Description/Source Reference
One tpd pilot plant, 99
vacuum gas oil; average
of six operating
conditions (800-840'F
reactor temperature;
40-100 minutes residence
time)
One tpd pilot plant, 99
vacuum gas oil; operating
conditions: 840"F reactor
temperature, 60 minutes
residence time, average of
seven yield periods
One tpd pilot plant, coker 99
gas oil from "typical" run
One tpd pilot plant, coker 99
scrubber liquids from
"typical" run
PDU, blend of atmospheric 144
still overhead and
bottoms
PDU, syncrude mode, blend 97
of atmospheric still
overhead and vacuum still
overhead
PDU, fuel oil mode, blend 97
of atmospheric still
overhead and vacuum still
overhead
332
-------
Table 195. API Gravity
Material
Coal
liquid
inter-
mediates
Process Coal Type
SRC-I NA
NA
NA
EDS
IL No. 6
IL No. 6
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
Value
(Degrees)
5.7
7.7
18.6
11.4
10.0
18
15.57 + 4.29
Sample Description/Source Reference
84
Wilsonville pilot plant,
process solvent
Wilsonville pilot plant,
process solvent
Wilsonville pilot plant,
wash solvent
One tpd pilot plant,
process solvent from
"typical" run (Run A-5)
One tpd pilot plant,
process solvent
One tpd pilot plant,
process solvent
_ One tpd pilot plant,
process solvent; average
of three operating
conditions (840°F reactor
temperature; 15-40 minutes
residence time)
11.41 +_ 1.14 One tpd pilot plant,
process solvent; operating
conditions: 840°F reactor
temperature, 40 minutes
residence time; average of
ten yield periods.
14.58 + 2.78
16.24 + 2.61
(Continued)
75 Ib per day development
unit, process solvent;
average of six operating
conditions (800-880°F
reactor temperature, 25-100
minutes residence time)
75 Ib per day development
unit, process solvent;
operating conditions:
840°F reactor temperature,
40 minutes residence time,
average of 21 yield
periods
119
84
99
99
104
99
99
99
99
333
-------
Table 195 (Continued)
Material
Coal
liquid
inter-
mediates
Process Coal Type
EDS IL No. 6
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
IL No. 6
Wyodak
Value
(Degree)
16.0
18.99 + 2.70
16.00 + 1.55
-4.6
-8.37 + 3.26
-4.61 + 7.72
-4.0
-21.0
16.1
(Continued)
Sample Description/Source Reference
One tpd pilot plant, 99
hydrogenated recycle
solvent from "typical"
run (Run A-6)
One tpd pilot plant, 99
hydrogenated recycle
solvent; average of three
operating conditions
(840"F reactor temperature;
15-40 minutes residence
time)
One tpd pilot plant, 99
hydrogenated recycle
solvent; operating
conditions: 840°F reactor
temperature, 40 minutes
residence time; average of
ten yield periods
One tpd pilot plant, 99
vacuum gas oil from
"typical" run (Run A-2)
One tpd pilot plant, 99
vacuum gas oil; average
of three operating
conditions (840°F reactor
temperature; 15-40 minutes
residence time)
One tpd pilot plant, 99
vacuum gas oil; operating
conditions: 840"F reactor
temperature; 40 minutes
residence time; average
of ten yield periods
One tpd pilot plant, coker 99
gas oil from "typical" run
One tpd pilot plant, coker 99
scrubber liquids from
"typical" runs
One tpd pilot plant, 99
process solvent from
"typical" run (Run A-5)
334
-------
Table 195 (Continued)
Material Process Coal Type
Coal
liquid
inter-
mediates
EDS
Wyodak
Value
(Degrees)
13.45 + 1.83
Sample Description/Source Reference
Wyodak
15.93 + 1.53
Wyodak
One tpd pilot plant,
process solvent; average
of six operating
conditions (800-840°F
reactor temperature,
40-100 minutes residence
time)
One tpd pilot plant,
process solvent; operating
conditions: 840°F reactor
temperature, 60 minutes
residence time, average of
seven yield periods
13.32 +_ 1.74 75 Ib per day development
unit; process solvent;
average of eight operating
conditions (800-8808F
reactor temperature, 25-100
minutes residence time)
99
99
99
Wyodak
11.99 + 1.23
Wyodak
18.50 + 1.47
Wyodak
19.38 + 1.33
75 Ib per day development
unit; process solvent;
operating conditions:
880°F reactor temperature,
25 minutes residence time,
average of six yield
periods
One tpd pilot plant,
hydrogenated recycle
solvent; average of six
operating conditions
(800-840eF reactor
temperature, 40-100
minutes residence time)
One tpd pilot plant,
hydrogenated recycle
solvent; operating
conditions: 840°F reactor
temperature, 60 minutes
residence time, average
of seven yield periods
99
99
99
(Continued)
335
-------
Table 195 (Continued)
Material
Coal
liquid
inter-
mediates
Process Coal Type
EDS Wyodak
Value
(Degrees)
Wyodak
Wyodak
Wyodak
Wyodak
Wyodak
NA
NA
H-Coal IL No. 6
IL No. 6
Sample Description/Source Reference
99
-4.87 + 8.20 One tpd pilot plant,
vacuum gas oil; average
of six operating
conditions (800-840°F
reactor temperature;
40-100 minutes residence
time)
-4.14+^7.38 One tpd pilot plant,
vacuum gas oil; operating
conditions: 840°F reactor
temperature, 60 minutes
residence time, average of
seven yield periods
18.2
-5.3
-8.5
-21.8
16.0
17.1
32.6
31.6
(Continued)
One tpd pilot plant,
hydrogenated recycle
solvent from "typical" run
(Run A-6)
One tpd pilot plant,
vacuum gas oil from
"typical" run (Run A-2)
One tpd pilot plant, coker
gas oil from "typical" run
One tpd pilot plant, coker
scrubber liquids from
"typical" run
One tpd pilot plant,
hydrogenated recycle
solvent
One tpd pilot plant,
hydrogenated recycle
solvent, reprocessed to
remove 650*F fraction
PDU Run 8, Period 3AB,
fuel oil mode with low
catalyst age, atmospheric
still overhead*,*
PDU Run 8, Period 11B,
fuel oil mode with high
catalyst age, atmospheric
still overhead*,1"
99
99
99
99
99
84
84
155
155
336
-------
Table 195 (Continued)
Value
Material Process Coal Type (Degrees) Sample Description/Source Reference
Coal H-Coal IL No. 6 26.2 PDU Run 8, Period 20AB, 155
liquid intermediate mode with
inter- high catalyst age, atmos-
mediates pheric still overhead*,*
KY No. 11 32.5 PDU Run 9, Period 6AB, 156
syncrude mode, atmospheric
still overhead!,§
KY No. 11 33.2 PDU Run 9, Period 12AB, 156
syncrude mode, atmospheric
still overhead?,§
KY No. 11 32.9 PDU Run 9, Period 18AB, 156
syncrude mode, atmospheric
still overhead!,§
KY No. 11 31.9 PDU Run 9, Period 23AB, 156
syncrude mode, atmospheric
still overhead!,§
KY No. 11 36.3 PDU Run 9, Period 28AB, 156
syncrude mode, atmospheric
still overhead!,§
IL No. 6 4.2 PDU Run 8, Period 3AB, 155
fuel oil mode with low
catalyst age, vacuum still
overhead*,*
IL No. 6 3.5 PDU Run 8, Period 11B, 155
fuel oil mode with high
catalyst age, vacuum still
overhead*,*
IL No. 6 6.3 PDU Run 8, Period 20AB, 155
intermediate mode with high
catalyst age, vacuum still
overhead*,*
KY No. 11 4.6 PDU Run 9, Period 6AB, 156
syncrude mode, vacuum
still overhead^
KY No. 11 2.8 PDU Run 9, Period 12AB, 156
syncrude mode, vacuum
still overhead!,§
(Continued)
337
-------
Table 195 (Continued)
Material Process Coal Type
Coal
liquid
inter-
mediates
H-Coal KY No. 11
KY No. 11
KY No. 11
IL No. 6
(Burning
Star Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
IL No. 6
IL No. 6
KY No. 11
KY No. 11
KY No. 11
Value
(Degrees) Sample Description/Source Reference
4.1 PDU Run 9, Period 18AB, 156
syncrude mode, vacuum
still overhead?,§
2.5 PDU Run 9, Period 23AB, 156
syncrude mode, vacuum
still overheadf,§
2.8 PDU Run 9, Period 28AB, 156
syncrude mode, vacuum
still overhead^
19.8 PDU, fuel oil mode, blend 97
of atmospheric still
overhead and vacuum still
overhead (analyzed by BETC)#
17.0 PDU, syncrude mode, blend 97
of atmospheric still
overhead and vacuum still
overhead (analyzed by BETC)#
11.1 PDU Run 8, Period 3AB, 155
fuel oil mode with low
catalyst age, atmospheric
still bottoms*,*
9.8 PDU Run 8, Period 11B, 155
fuel oil mode with high
catalyst age, atmospheric
still bottoms*,t
10.9 PDU Run 8, Period 20AB, 155
intermediate mode with
high catalyst age, atmos-
pheric still bottoms*,"1"
10.1 PDU Run 9, Period 18AB, 156
syncrude mode, atmos-
pheric still bottomst,§
9.4 PDU Run 9, Period 23AB, 156
syncrude mode, atmos-
pheric still bottoms^,§
10.9 PDU Run 9, Period 28AB, 156
syncrude mode, atmos-
pheric still bottomsf,§
(Continued)
333
-------
Table 195 (Concluded)
Material
Coal
liquid
inter-
medi ates
Process Coal Type
H-Coal KY No. 11
KY No. 11
NA
IL No. 6
(Burning
Star Mine)
Value
(Degrees)
10.4
10.3
9.8
30.5
Sample Description/Source Reference
PDU Run 9, Period 6AB, 156
syncrude mode, atmos-
pheric still bottomsT;§
PDU Run 9, Period 12AB, 156
syncrude mode, atmos-
pheric still bottoms*,§
PDU, atmospheric stil 1 84
bottoms
PDU, blend of atmospheric 144
still overhead and bottoms
Explanatory Notes
*See General Comments section, Note 2, for summary of operating conditions used.
^Periods 3AB, 11B and 20AB are considered representative periods for the entire
PDU Run 8, which consisted of over 32 individual periods.
fSee General Comments section, Note 3, for summary of operating conditions used.
§Periods GAB, 12AB, 18AB, 23AB and 28AB are considered representative periods for
the entire PDU Run 9, which consisted of over 30 individual periods.
#See Part VIII, General Comments section, Note 3, for summary of operating conditions
used.
339
-------
Material
Coal
liquid
inter-
medi ates
Process Coal Type
EDS NA
NA
NA
H-Coal NA
NA
NA
NA
NA
Table 196. Density
Value
(g/ml) Sample Description/Source Reference
0.9787 One tpd pilot plant, 91
process solvent (DuPont
"Notebook" Sample No. 16928)
1.17* One tpd pilot plant, 91
vacuum gas oil (DuPont
"Notebook" Sample No. 16928)
l.lllt One tpd pilot plant, 91
heavy gas oil (DuPont
"Notebook" Sample No. 16928)
0.8442 PDU, fuel oil mode, 91
atmospheric still overhead
1.031 PDU, fuel oil mode, vacuum 91
still overhead
0.9926 PDU, fuel oil mode, 91
atmospheric still bottoms
1.49* PDU, fuel oil mode, 91
vacuum still bottoms
1.41* PDU, syncrude mode, 91
vacuum still bottoms
Explanatory Notes
*Helium Pycnometer at 71.6°F
1"By water displacement in Hubbarb-Carmick Pycnometer
340
-------
Table 197. Distillation Data
Material Process Coal Type
Value (%
Evaporation) Sample Description/Source
Reference
Coal SRC-I KY No. 9
liquid and 14
inter-
mediates
NA
KY No. 9
and 14
NA
EDS IL No. 6
IL No. 6
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
400'F-IBP
510°F-50
780°F-EP
413'F-IBP*
448°F-5
460'F-10
495'F-30
5400F-50^
6237-70*
NA-90
NA-95
NA-EP
266'F-IBP
398°F-50
523'F-EP
196'F-IBP*
230'F-5
350'F-10
374'F-30
388'F-50
399'F-70
427'F-90
450'F-95
519'F-EP
398'F-5
531'F-SO
833'F-95
422'F-10
457'F-50
658'F-90
390 + 8'F
-5
510 +
IS'F^SO
799 +
41'F~95
398 + 8'F
-5
531 +
16'F~50
833 +
53'F^95
(Continued)
341
Ft. Lewis pilot plant,
process solvent
Wilsonville pilot plant,
process solvent
Ft. Lewis pilot plant,
wash solvent
Wilsonville pilot plant,
wash solvent
One tpd pilot plant,
process solvent from
"typical" run (Run A-5)
One tpd pilot plant,
process solvent
One tpd pilot plant,
process solvent; average
of three operating
conditions (840'F reactor
temperature; 15-40 minutes
residence time)
One tpd pilot plant,
process solvent; operating
conditions: 840"F reactor
temperature, 40 minutes
residence time; average of
ten yield periods
83
84
83
84
99
99
99
99
-------
Table 197 (Continued)
Material
Value (%
Process Coal Type Evaporation) Sample Description/Source Reference
EDS IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
IL No. 6
(Monterey-
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
IL No. 6
Wyodak
401 + 4°F
-5
508 +
22°F-50
744 +
34°F~95
395 + 2'F
-5 ~
505 + 9°F
-50 ~
747 +
25°F-95
374°F-5
514°F-50
797°F-95
365 +
128F-5
495 +
18°F~50
751 +
50eF-95
374 +
20°F-S
514 +
797 -H
36'F-95
6299F-5
900eF-50
1030eF-90
3709F-5
700°F-50
960eF-95
379°F-5
465°F-50
716eF-95
(Continued)
342
75 Ib per day development 99
unit; process solvent;
operating conditions:
840°F reactor temperature,
40 minutes residence time,
average of 21 yield periods
One tpd pilot plant, 99
hydrogenated recycle
solvent from "typical" run
(Run A-6)
One tpd pilot plant, 99
hydrogenated recycle
solvent; average of three
operating conditions
(840"F reactor temperature,
15-40 minutes residence time)
One tpd pilot plant, 99
hydrogenated recycle
solvent; operating
conditions: 840°F reactor
temperature, 40 minutes
residence time, average
of ten yield periods
One tpd pilot plant, 99
vacuum gas oil from
"typical" run (Run A-2)
One tpd pilot plant, coker 99
gas oil from "typical"
run
One tpd pilot plant, 99
process solvent from
"typical" run (Run A-5)
-------
Table 197 (Continued)
Material Process Coal Type
Coal
liquid
inter-
mediates
EDS
Wyodak
Wyodak
Wyodak
Wyodak
Wyodak
Wyodak
Wyodak
Value (%
Evaporation) Sample Description/Source Reference
388 + 8°F-5 One tpd pilot plant,
99
482 +
13°F-50
731 +
37°F-95
379 +
12°F-5
465 +
12°F-50
716 +
28°F-95
408 +
48°F-5
509 +.
10°F-50
741 +
396 + 6°F-5
508 +
6°F-50
726 +
9°F-"9~5
365°F-5
454°F-50
689°F-95
365 +
10°F-5
474 +
13°F-50
743 +
43°FT95
365 + 4°F
-5 ~
454 + 5°F
-50 ~
689 +
20°F-95
(Continued)
343
process solvent; average
of six operating
conditions (800-840°F
reactor temperature,
40-100 minutes residence
time)
One tpd pilot plant,
process solvent; operating
conditions: 840°F reactor
temperature, 60 minutes
residence time, average of
seven yield periods
75 Ib per day development
unit; process solvent;
average of eight operating
conditions (800-880°F
reactor temperature, 25-100
minutes residence time)
75 Ib per day development
unit; process solvent;
operating conditions:
880°F reactor temperature,
25 minutes residence time,
average of six yield
periods
One tpd pilot plant,
hydrogenated recycle
solvent from "typical" run
(Run A-6)
One tpd pilot plant,
hydrogenated recycle
solvent; average of six
operating conditions
(800-840°F reactor
temperature, 40-100
minutes residence time)
One tpd pilot plant,
hydrogenated recycle
solvent; operating
conditions: 840°F reactor
temperature, 60 minutes
residence time, average
of seven yield periods
99
99
99
99
99
99
-------
Material Process Coal Type
Table 197 (Continued)
Value (%
Evaporation) Sample Description/Source Reference
Coal
liquid
inter-
mediates
EDS
Wyodak
Wyodak
Wyodak
Wyodak
NA
NA
605°F-5 One tpd pilot plant,
752°F-50 vacuum gas oil from
962°F-95 "typical" run (Run A-2)
400°F-5 One tpd pilot plant, coker
795°F-50 gas oil from "typical" run
980°F-95
499°F-5 One tpd pilot plant,
672°F-50 vacuum gas oil; average
908°F-95 of six operating
conditions (800-840°F
reactor temperature,
40-100 minutes residence
time)
473°F-5 One tpd pilot plant,
655°F-50 vacuum gas oil; operating
893°F-95 conditions: 840°F reactor
temperature, 60 minutes
residence time, average of
seven yield periods
194°F-IBP? One tpd pilot plant,
311°F-5 hydrogenated recycle
373°F-10 solvent
408°F-30
454°F-50
525°F-70
642°F-90
686°F-95
694°F-EP
NA-IBPf
409°F-5
419°F-10
453°F-30
499°F-50
538°F-70
584°F-90
602°F-95
608°F-EP
(Continued)
99
99
99
99
84
One tpd pilot plant,
hydrogenated recycle
solvent, reprocessed to
remove 650°F+ fraction
84
344
-------
Table 197 (Continued)
Material Process Coal Type
Coal
liquid
inter-
medi ates
H-Coal IL No. 6
IL No. 6
IL No. 6
KY No. 11
KY No. 11
KY No. 11
Value (%
Evaporation) Sample Description/Source Reference
139°F-IBP*
214°F-10
288°F-30
352°F-50
404°F-70
446°F-90
521°F-EP
140°F-IBP*
220°F-10
288°F-30
348°F-50
412°F-70
480°F-90
556°F-EP
156°F-IBP*
281°F-10
360°F-30
411°F-50
465°F-70
537°F-90
621°F-EP
144°F-IBP*
239°F-10
317°F-30
390°F-50
436°F-70
502°F-90
594°F-EP
148°F-IBP*
231°F-10
310°F-30
374°F-50
417°F-70
480°F-90
536°F-EP
141°F-IBP*
227°F-10
307°F-30
368°F-50
410°F-70
465°F-90
541°F-EP
(Continued)
345
PDU Run 8, Period 3AB,
fuel oil mode with low
catalyst age, atmospheric
still overhead§,#
PDU Run 8, Period 11B,
fuel oil mode with high
catalyst age, atmospheric
still overhead§,#
PDU Run 8, Period 20AB,
intermediate mode with
high catalyst age, atmos-
pheric still overhead§,#
PDU Run 9, Period 6AB,
syncrude mode, atmospheric
still overheadtt,ff
155
155
155
156
PDU Run 9, Period 12AB,
syncrude mode, atmospheric
still overhead'1"'', ft
156
PDU Run 9, Period 18AB,
syncrude mode, atmospheric
still overhead''"'', ft
156
-------
Table 197 (Continued)
Value (%
Material Process Coal Type Evaporation) Sample Description/Source Reference
Coal H-Coal KY No. 11
1iquid
inter-
mediates
KY No. 11
IL No. 6
IL No. 6
IL No. 6
KY No. 11
KY No. 11
144°F-IBP*
220'F-10
304'F-30
368°F-50
414°F-70
465°F-90
565°F-EP
136°F-IBP*
214°F-10
270°F-30
322°F-50
378°F-70
475°F-90
577'F-EP
468'F-IBP?
512°F-10
585°F-30
643°F-50
705°F-70
824'F-90
915°F-EP
436'F-IBPf
519°F-10
58S°F-30
649'F-50
737°F-70
790°F-90
930'F-EP
450'F-IBPf
537°F-10
600'F-30
706°F-50
7688F-70
865'F-90
1000° F-EP
451'F-IBP*
549°F-10
626°F-30
705°F-50
765°F-70
877°F-90
975°F-EP
467°F-IBP*
557'F-10
631°F-30
705'F-50
755°F-70
865°F-90
94CTF-EP
PDU Run 9, Period 28AB,
syncrude mode, atmospheric
still overhead1" Mr
PDU Run 9, Period 28AB,
syncrude mode, atmospheric
still overhead 1'1', ft
PDU Run 8, Period 3AB,
fuel oil mode with low
catalyst age, vacuum still
overhead§,#
PDU Run 8, Period 11B,
fuel oil mode with high
catalyst age, vacuum still
overhead§,#
PDU Run 8, Period 20AB,
intermediate mode with high
catalyst age, vacuum still
overhead§,#
PDU Run 9, Period 6AB,
syncrude mode, vacuum
still overhead '"".TT
PDU Run 9, Period 12AB,
syncrude mode, vacuum
stil 1 overhead1"' ,rf
(Continued)
156
156
155
155
155
156
156
346
-------
Table 197 (Continued)
Material Process Coal Type
Coal
liquid
inter-
mediates
H-Coal KY No. 11
KY No. 11
KY No. 11
IL No. 6
IL No. 6
IL No. 6
Value (X
Evaporation) Sample Description/Source Reference
432'F-IBP*
537°F-10
6068F-30
660°F-50
730'F-70
836°F-90
920°F-EP
4578F-IBP*
5538F-10
635°F-30
750aF-50
794°F-70
859°F-90
992°F-EP
412°F-IBP*
521°F-10
618'F-30
7138F-50
7528F-70
8608F-90
10108F-EP
4018F-IBP*
454°F-10
499°F-30
541°F-50
587'F-70
6808F-90
850'F-EP
409'F-IBP*
4698F-10
5098F-30
5528F-50
6008F-70
693°F-90
870°F-EP
4428F-IBP*
5088F-10
553°F-30
595°F-50
645°F-70
774°F-90
928°F-EP
(Continued]
347
PDU Run 9, Period 18AB,
syncrude mode, vacuum
still overhead'"'',ft
156
PDU Run 9, Period 23AB,
syncrude mode, vacuum
still overhead"*" ,fr
156
PDU Run 9, Period 28AB,
syncrude mode, vacuum
still overhead ,TT
156
PDU Run 8, Period 3AB,
fuel oil mode with low
catalyst age, atmospheric
still bottoms§,l
PDU Run 8, Period 11B,
fuel oil mode with high
catalyst age, atmospheric
still bottoms§,#
155
155
PDU Run 8, Period 20AB,
intermediate mode with
high catalyst age, atmos-
pheric still bottoms§,#
155
-------
Table 197 (Continued)
Material
Coal
liquid
inter-
mediates
Process Coal Type
H-Coal KY No. 11
KY No. 11
KY No. 11
KY No. 11
KY No. 11
NA
Value (56
Evaporation) Sample Description/Source
470'F-IBP*
521'F-IO
551aF-30
600°F-50
647°F-70
741'F-90
845'F-EP
467°F-IBP*
521°F-10
560'F-30
600°F-50
6498F-70
750°F-90
842*F-EP
459'F-IBP*
508°F-10
5518F-30
584°F-50
633°F-70
724°F-90
789°F-EP
469'F-IBP*
511'F-IO
547°F-30
593eF-50
646CF-70
77CTF-90
890'F-EP
3888F-IBP*
452'F-IO
5108F-30
5668F-50
629°F-70
772°F-90
910°F-EP
386°F-IBP*
429°F-5
439°F-10
502°F-30
559°F-50
620°F-70
734'F-90
746°F-95
746'F-EP
PDU Run 9, Period 6AB,
syncrude mode, atmospheric
still bottoms1"1",!?
Reference
156
PDU Run 9, Period 12AB,
syncrude mode, atmospheric
still bottoms",ft
156
PDU Run 9, Period 18AB,
syncrude mode, atmospheric
still bottomsn,tt
156
PDU Run 9, Period 23AB,
syncrude mode, atmospheric
still bottoms",!?
156
PDU Run 9, Period 28AB,
syncrude mode, atmospheric
still bottoms1"1",!!
156
PDU, atmospheric still
bottoms
84
(Continued)
348
-------
Material
Coal
liquid
inter-
mediates
Process Coal Type
H-Coal IL No. 6
Table 197 (Concluded)
Value (56
Evaporation) Sample Description/Source Reference
IL No. 6
IL No. 6
655eF-IBP** PDU Run 8, Period 3AB, 155
fuel oil mode with low
catalyst age, vacuum still
bottoms§,#
751'F-IBP** PDU Run 8, Period 11B, 155
fuel oil mode with high
catalyst age, vacuum still
bottoms§,#
714'F-IBP** PDU Run 8, Period 20AB, 155
intermediate mode with high
catalyst age, vacuum still
bottoms§,#
Explanatory Notes
*Determined via ASTM D-86.
^Distillation terminated due to solids in condenser.
fDetermined via ASTM D-1160.
§See General Comments, Note 2, for summary of operating conditions used.
#Periods 3AB, 11B and 20AB are considered representative periods for the entire
PDU Run 8, which consisted of over 32 individual periods.
**Determined via modified ASTM D-1160.
''"''See General Comments, Note 3, for summary of operating conditions used.
JfPeriods SAB, 12AB, 18AB, 23AB and 28AB are considered representative
periods of the entire PDU Run 9, which consisted of over 30 individual periods.
349
-------
Table 198. GC Simulated Distillation Data
Material
Coal
1iquid
inter-
mediates
Process
SRC-I NA
Coal
Type
NA
H-Coal NA
Value (Boiling
Point Range)
392°F-IBP*
411'F-5
444'F-IO
472°F-30
509°F-50
588'F-70
6748F-90
730°F-95
899°F-EP
188°F-IBP*
301°F-5
336'F-10
377°F-30
401'F-50
416'F-70
449°F-90
458°F-95
565°F-EP
305'F-IBP*
367eF-5
397°F-10
474'F-30
537*F-50
596'F-70
703°F-90
762°F-95
929°F-EP
Sample Description/Source Reference
Wilsonville pilot plant,
process solvent
84
Wilsonville pilot plant,
wash solvent
84
PDU, atmospheric still
bottoms
84
Explanatory Notes
*Determined via ASTM D-2887
350
-------
Table 199. Viscosity
Value
Material Process Coal Type (Centistokes) Sample Description/Source Reference
Coal SRC-I KY No. 9
liquid and 14
inter-
mediates
NA
KY No. 9
and 14
NA
EDS IL No. 6
IL No. 6
IL No. 6
(Monterey
(Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
IL No. 6
(Monterey
Mine)
44.0(cp at
100°F)
6.04(104'F)
1.45(212°F)
2.71(cp at
100'F)
1.75(104aF)
0.77(212'F)
5.0(100°F)
1.5(210'F)
3.6(100°F)
38 (SSU at
100'F)
4.17 + 0.75
(100 T)
1.34 + 0.11
(210°F)
5.04 + 0.51
(100T)
1.46 + 0.08
(210T)
3.7(100°F)
1.3(210°F)
3.09 -K 0.55
(100T)
1.13 + 0.16
(210T)
(Continued)
351
Ft. Lewis pilot plant,
process solvent
Wilsonville pilot plant,
recycle solvent
Ft. Lewis pilot plant,
wash solvent
Wilsonville pilot plant,
wash solvent
One tpd pilot plant,
process solvent from
"typical" run (Run A-5)
One tpd pilot plant,
process solvent
One tpd pilot plant,
process solvent
One tpd pilot plant,
process solvent; average
of three operating
conditions (840°F reactor
temperature; 15-40 minutes
residence time)
One tpd pilot plant,
process solvent; operating
conditions: 840*F reactor
temperature, 40 minutes
residence time; average of
ten yield periods.
One tpd pilot plant,
hydrogenated recycle
solvent from "typical"
run (Run A-6)
One tpd pilot plant,
hydrogenated recycle
solvent; average of three
operating conditions
(840°F reactor temperature;
15-40 minutes residence
time)
83
84
83
84
99
99
104
99
99
99
99
-------
Table 199 (Continued)
Value
Material Process Coal Type (Centistokes) Sample Description/Source Reference^
Coal EDS IL No. 6 3.70 + 0.49
liquid (Monterey (10CTF)
inter- Mine) 1.28 + 0.07
mediates (210TF)
IL No. 6
IL No. 6
IL No. 6
Wyodak
Wyodak
Wyodak
Wyodak
2.7(100'F)
One tpd pilot plant,
hydrogenated recycle
solvent; operating
conditions: 840"F reactor
temperature, 40 minutes
residence time; average of
ten yield periods
18,000
(100'F)
342
(210°F)
393
(100'F)
16
(210*F)
1255
(400°F)
100
(500°F)
One tpd pilot plant,
vacuum gas oil from
"typical" run (Run A-2)
One tpd pilot plant, coker
gas oil from "typical" run
One tpd pilot plant, coker
scrubber liquids from
"typical" run
One tpd pilot plant,
process solvent from
"typical" run (Run A-5)
4.01 + 2.69
(lOOT)
1.31 + 0.29
(21
-------
Table 199 (Continued)
Value
Material Process Coal Type (Centistokes) Sample Description/Source Reference
Coal
1iquid
inter-
mediates
EDS
Wyodak
Wyodak
Wyodak
Wyodak
Wyodak
MA
NA
2.71 + 0.39
(10(TF)
1.43 + 0.86
(210TF)
2.44 + 0.19
(100TF)
1.00 + 0.04
483
(210°F)
3
(3008F)
10,000
(170'F)
341
(210'F)
10,000
(420°F)
30
(550eF)
2.67
(104'F)
1.11
(212°F)
2.34
(1048F)
1.00
(212aF)
(Continued)
One tpd pilot plant, 99
hydrogenated recycle
solvent; average of six
operating conditions
(800-840°F reactor
temperature, 40-100
minutes residence time)
One tpd pilot plant, 99
hydrogenated recycle
solvent; operating
conditions: 840°F reactor
temperature, 60 minutes
residence time, average
of seven yield periods
One tpd pilot plant, 99
vacuum gas oil from
"typical" run (Run A-2)
One tpd pilot plant, coker 99
gas oil from "typical" run
One tpd pilot plant, coker 99
scrubber liquids from
"typical" run
One tpd pilot plant, 84
hydrogenated recycle
solvent
One tpd pilot plant, 84
hydrogenated recycle
solvent, reprocessed to
remove 650°F+ fraction
353
-------
Table 199 (Continued)
Value
Material Process Coal Type (Centistokes) Sample Description/Source Reference
Coal
liquid
inter-
mediates
H-Coal
IL No. 6
(Burning
Star Mine)
IL No. 6
(Monterey
Mine)
NA
IL No. 6
KY No. 11
KY No. 11
KY No. 11
KY No. 11
KY No. 11
38 (SSU PDU, fuel oil mode, blend
at 77°F) of atmospheric still
35 (SSU overhead and vacuum still
at 100°F) overhead
59 (SSU PDU, syncrude mode, blend of
at 77"F) atmospheric still
46 (SSU overhead and vacuum still
at 100" F) overhead
7.13
(104°F)
1.78
(212°F)
3430.0
(centipoise
at 500°F)f
710.0
(centipoise
at 500°F)f
480.0
(centipoise
at 500°F)t
450.0
(centipoise
at 500°F)t
690.0
(centipoise
at 500°F)f
500.0
(centipoise
at 500°F)f
PDU, atmospheric stil 1
bottoms
PDU Run 8, Period 118,
vacuum still bottoms,
fuel oil mode with high
catalyst age*,1"
PDU Run 9, Period 6AB,
syncrude mode, vacuum
still bottoms§,#
PDU Run 9, Period 12AB,
syncrude mode, vacuum
still bottoms§,#
PDU Run 9, Period 18AB,
syncrude mode, vacuum
still bottoms!,#
PDU Run 9, Period 23AB,
syncrude mode, vacuum
still bottoms!,!
PDU Run 9, Period 28AB,
syncrude mode, vacuum
still bottoms§,#
97
97
84
155
156
156
156
156
156
(Continued)
354
-------
Table 199 (Concluded)
Explanatory Notes
*See General Comments, Note 2, for summary of operating conditions used.
^Periods 3AB, 11B and 20AB are considered representative periods for the entire
PDU Run 8, which consisted of over 32 individual periods.
fAverage of Brookfield viscosity values at 5-100 RPM.
§See General Comments, Note 3, for summary of operating conditions used.
#Periods 6AB, 12AB, 18AB, 23AB and 28AB are considered representative periods for
the entire PDU Run 9, which consisted of over 30 individual periods.
355
-------
Table 200. Pour Point
Material
Coal
liquid
inter-
mediates
Value
Process Coal Type (°F)
SRC-1
EDS
H-Coal
NA
NA
IL No. 6
(Monterey
Mine)
NA
NA
IL No. 6
(Burning
Star Mine)
IL No. 6
(Monterey
Mine)
NA
35.0
<-65.0
-5
-36.0
-36.0
<5
<5
Sample Description/Source Reference
Wilsonville pilot plant, 84
process solvent
Wilsonville pilot plant, 84
wash solvent
One tpd pilot plant, 104
process solvent
One tpd pilot plant, 84
hydrogenated recycle
solvent
One tpd pilot plant, 84
hydrogenated recycle
solvent, reprocessed to
remove 650°F+ fraction
PDU, fuel oil mode, blend 97
of atmospheric still
overhead and vacuum still
overhead
PDU, syncrude mode, blend 97
of atmospheric still
overhead and vacuum still
overhead
PDU, atmospheric still 84
bottoms
356
-------
Table 201. Carbon Residue*,1"
Material Process Coal Type
Coal
liquid
inter-
medi ates
SRC-1
EDS
NA
NA
IL No. 6
(Monterey
Mine)
IL No. 6
NA
NA
H-Coal NA
IL. No. 6
(Burning
Star Mine)
Value
(Wt %) Sample Description/Source Reference
4.95 Wilsonville pilot plant, 84
process solvent
0.07 Wilsonville pilot plant, 84
wash solvent
3.0 One tpd pilot plant, 104
process solvent
3.1 One tpd pilot plant, 99
process solvent
0.03 One tpd pilot plant, 84
hydrogenated recycle
solvent
0.03 One tpd pilot plant, 84
hydrogenated recycle
solvent, reprocessed to
remove 650°F+ fraction
0.52 PDU, atmospheric still 84
bottoms
0.10 PDU, blend of atmospheric 144
still overhead and bottoms
Exp 1 ar^atpry_ Notes
*Determined via ASTM D-189
tConradsen carbon residue
357
-------
Table 202. Flash Point
Material Process Coal Type
Coal
liquid
inter-
mediates
SRC-I
EDS
NA
NA
IL No. 6
IL No.
IL No.
IL No.
6
6
6
IL No. 6
IL No. 6
IL No. 6
Wyodak
Wyodak
Wyodak
Wyodak
Value
(°F) Sample Description/Source Reference
235.0 Wilsonville pilot plant, 84
process solvent
95.0 Wilsonville pilot plant, 84
wash solvent
158 One tpd pilot plant, 99
process solvent from
"typical" run (Run A-5)
196 One tpd pilot plant, 99
process solvent
196 One tpd pilot plant, 104
process solvent
80 One tpd pilot plant, 99
hydrogenated recycle
solvent from "typical"
run (Run A-6)
>415 One tpd pilot plant, vacuum 99
gas oil from "typical" run
(Run A-2)
>415 One tpd pilot plant, coker 99
gas oil from "typical" run
>415 One tpd pilot plant, coker 99
scrubber liquids from
"typical" run
198 One tpd pilot plant, 99
process solvent from
"typical" run (Run A-5)
80 One tpd pilot plant, 99
hydrogenated recycle
solvent from "typical" run
(Run A-6)'
>415 One td pilot plant, vacuum 99
gas oil from "typical" run
(Run A-2)
>415 One tpd pilot plant, coker 99
gas oil from "typical" run
(Continued)
358
-------
Table 202 (Concluded)
Material
Coal
liquid
inter-
med i ate
Process Coal Type
EDS Wyodak
NA
NA
Value
"F]
>415
101.0
122.0
H-Coal NA
203
Sample Description/Source Reference
One tpd pilot plant, coker 99
scrubber liquids from
"typical" run
One tpd pilot plant,
hydrogenated recycle
solvent
One tpd pilot plant,
hydrogenated recycle
solvent, reprocessed to
remove 650°F+ fraction
PDU, atmospheric still
bottoms
84
84
84
359
-------
Table 203. Heat of Combustion
Materia]
Coal
liquid
inter-
mediates
Value
Process Coal Type (Btu/lb)
SRC-I NA
EDS
NA
IL No. 6
(Monterey
Mine)
IL No. 6
IL No. 6
IL No. 6
IL No. 6
Wyodak
Wyodak
Wyodak
Wyodak
17,299
(gross)
17,050
(gross)
IL No. 6 18,500
19,000
19,000
16,400
17,200
16,100
18,700
19,000
17,300
16,800
Sample Description/Source Reference
Wilsonville pilot plant, 84
recycle solvent
Wilsonville pilot plant, 84
wash solvent
One tpd pilot plant, 99
process solvent from
"typical" run (Run A-5)
One tpd pilot plant, 99
process solvent
One tpd pilot plant, 99
hydrogenated recycle
solvent from "typical"
run (Run A-6)
One tpd pilot plant, vacuum 99
gas oil from "typical" run
(Run A-2)
One tpd pilot plant, coker 99
gas oil from "typical" run
One tpd pilot plant, coker 99
scrubber liquids from
"typical" run
One tpd pilot plant, 99
process solvent from
"typical" run (Run A-5)
One tpd pilot plant, 99
hydrogenated recycle
solvent from "typical" run
(Run A-6)
One tpd pilot plant, vacuum 99
gas oil from "typical" run
(Run A-2)
One tpd pilot plant, coker 99
gas oil from "typical" run
(Continued)
360
-------
Table 203 (Concluded)
Material
Coal
liquid
inter-
mediates
Process Coal Type
EDS Wyodak
NA
NA
H-Coal NA
Value
(Btu/lb) Sample Description/Source Reference
16,000 One tpd pilot plant, coker 99
scrubber liquids from
"typical" run
18,343 One tpd pilot plant, 84
(gross) hydrogenated recycle
solvent
18,400 One tpd pilot plant, 84
(gross) hydrogenated recycle
solvent, reprocessed to
remove 650°F+ fraction
17,662 PDU, atmospheric still 84
(gross) bottoms
361
-------
Table 204. Heat Capacity
Value
Material Process Coal Type (Btu/lb/'F) Sample Description/Source Reference
Coal SRC-I KY No. 9 0.430 Ft. Lewis pilot plant, 83
liquid and 14 (100'F) process solvent
inter- 0.554
mediates (400°F)
KY No. 9 0.468 Ft. Lewis pilot plant, 83
and 14 (lOO'F) wash solvent
362
-------
Table 205. Bromine Number
Material Process Coal Type Value Sample Description/Source Reference
Coal EDS IL No. 6 13.9 One tpd pilot plant, 99
liquid process solvent
inter-
mediates H-Coal IL No. 6 41.7 PDU, blend of atmospheric 144
(Burning still overhead and bottoms
Star
Mine)
363
-------
Table 206. Color
Material
Coal
liquid
inter-
mediates
Process Coal Type
H-Coal IL No. 6
IL No. 6
Value
brownish
black
brownish
black
Sample Description/Source Reference
POD, fuel oil mode, blend 97
of atmospheric stil1
overhead and vacuum still
overhead
POU, syncrude mode, blend
of atmospheric still
overhead and vacuum still
overhead
97
364
-------
Table 207. Oxygen Content
Material Process Coal Type
Coal
liquid
inter-
mediates
SRC-1
EDS
KY No. 9
and 14
KY No. 9
and 14
NA
NA
NA
IL No. 6
Value
(Wt %)
2.39
5.77
2.2
2.8
5.7*
1.31
IL No. 6 1.12 +_ 0.17
(Monterey
Mine)
IL No. 6 1.31 + 0.24
(Monterey
Mine)
IL No. 6 0.29 + 0.04
(Monterey
Mine)
IL No. 6 0.30 + 0.07
(Monterey
Mine)
Sample Description/Source Reference
Ft Lewis pilot plant, 83
process solvent
Ft. Lewis pilot plant, 83
wash solvent
Wilsonville pilot plant, 84
process solvent
Wilsonville pilot plant, 119
process solvent
Wilsonville pilot plant, 84
wash solvent
One tpd pilot plant, 99
process solvent from
"typical" run (Run A-5)
One tpd pilot plant, 99
process solvent; average
of three operating
conditions (840°F reactor
temperature; 15-40 minutes
residence time)
One tpd pilot plant, 99
process solvent; operating
conditions: 840°F reactor
temperature, 40 minutes
residence time; average of
ten yield periods
75 Ib per day development 99
unit, process solvent;
average of six operating
conditions (800-880°F
reactor temperature, 25-100
minutes residence time)
75 Ib per day development 99
unit, process solvent;
operating conditions:
840°F reactor temperature,
40 minutes residence time,
average of 21 yield
periods
(Continued)
365
-------
Table 207 (Continued)
Material
Coal
liquid
inter-
mediates
Process Coal Type
EDS IL No. 6
Value
(Ht %)
0.43
IL No. 6 0.27 ^ 0.15
(Monterey
Mine)
IL No. 6 0.43 +_ 0.32
(Monterey
Mine)
IL No. 6
3.83
IL No. 6 4.36 +_ 0.47
(Monterey
Mine)
IL No. 6 3.83 +_ 0.33
(Monterey
Mine)
IL No. 6
IL No. 6
Wyodak
4.5
4.5
1.14
(Continued)
Sample Description/Source Reference
One tpd pilot plant, 99
hydrogenated recycle
solvent from "typical"
run (Run A-6)
One tpd pilot plant, 99
hydrogenated recycle
solvent; average of three
operating conditions
(840°F reactor temperature;
15-40 minutes residence
time)
One tpd pilot plant, 99
hydrogenated recycle
solvent; operating
conditions: 840°F reactor
temperature, 40 minutes
residence time; average of
ten yield periods
One tpd pilot plant, 99
vacuum gas oil from
"typical" run (Run A-2)
One tpd pilot plant, 99
vacuum gas oil; average
of three operating
conditions (840°F reactor
temperature; 15-40 minutes
residence time)
One tpd pilot plant, 99
vacuum gas oil; operating
conditions: 840°F reactor
temperature; 40 minutes
residence time; average
of ten yield periods
One tpd pilot plant, coker 99
gas oil from "typical" run
One tpd pilot plant, coker 99
scrubber liquids from
"typical" run
One tpd pilot plant, 99
process solvent from
"typical" run (Run A-5)
366
-------
Table 207 (Continued)
Material Process Coal Type
Coal
liquid
inter-
mediates
EDS
Wyodak
Value
(Wt %)
0.93 + 0.34
Wyodak
1.14 + 0.32
Wyodak
0.22 + 0.17
Wyodak
0.20 + 0.09
Wyodak
0.38
Wyodak
0.19 + 0.20
Wyodak
0.38 + 0.27
(Continued)
367
Sample Description/Source Reference
One tpd pilot plant, 99
process solvent; average
of six operating
conditions (800-840°F
reactor temperature,
40-100 minutes residence
time)
One tpd pilot plant, 99
process solvent; operating
conditions: 840°F reactor
temperature, 60 minutes
residence time, average of
seven yield periods
75 Ib per day development 99
unit; process solvent;
average of eight operating
conditions (800-880°F
reactor temperature, 25-100
minutes residence time)
75 Ib per day development 99
unit; process solvent;
operating conditions:
880°F reactor temperature,
25 minutes residence time,
average of six yield
periods
One tpd pilot plant, 99
hydrogenated recycle
solvent from "typical" run
(Run A-6)
One tpd pilot plant, 99
hydrogenated recycle
solvent; average of six
operating conditions
(800-840°F reactor
temperature, 40-100
minutes residence time)
One tpd pilot plant, 99
hydrogenated recycle
solvent; operating
conditions: 840°F reactor
temperature, 60 minutes
residence time, average
of seven yield periods
-------
Table 207 (Continued)
Material
Coal
liquid
inter-
mediates
Process Coal Type
EDS Wyodak
Wyodak
Wyodak
NA
NA
NA
NA
NA
Value
(Wt %)
2.52
3.06 + 0.94
2,52 + 0.63
Wyodak
Wyodak
2.43
3.39
0.33
0.48
Sample Description/Source Reference
99
1.04
3.46
3.18
(Continued)
368
One tpd pilot plant,
vacuum gas oil from
"typical" run (Run A-2)
One tpd pilot plant, 99
vacuum gas oil; average
of six operating
conditions (800-840°F
reactor temperature;
40-100 minutes residence
time)
One tpd pilot plant, 99
vacuum gas oil; operating
conditions: 840°F reactor
temperature, 60 minutes
residence time, average of
seven yield periods
One tpd pilot plant, coker 99
gas oil from "typical" run
One tpd pilot plant, coker 99
scrubber liquids from
"typical" run
One tpd pilot plant, 84
hydrogenated recycle
solvent
One tpd pilot plant, 84
hydrogenated recycle
solvent, reprocessed to
remove 650°F+ fraction
One tpd pilot plant, 91
process solvent (DuPont
"Notebook" Sample No. 16928)
One tpd pilot plant, 91
vacuum gas oil (DuPont
"Notebook" Sample No. 16928)
One tpd pilot plant, 91
heavy gas oil (DuPont
"Notebook" Sample No. 16928)
-------
Table 207 (Concluded)
Material
Coal
liquid
inter-
mediates
Process Coal Type
H-Coal NA
NA
NA
NA
NA
IL No. 6
(Burning
Star Mine)
Value
(Wt %)
1.45
1.40
1.54
10.84
12.91
1.72
Sample Description/Source
PDU, fuel oil mode,
atmospheric still overhead
PDU, fuel oil mode, vacuum
still overhead
PDU, fuel oil mode,
atmospheric still bottoms
PDU, fuel oil mode, vacuum
still bottoms
PDU, syncrude mode, vacuum
still bottoms
PDU, blend of atmospheric
still overhead and bottoms
Reference
91
91
91
91
91
144
NA
1.79
PDU, atmospheric still
bottoms
84
Explanatory Notes
*Contains 1.61 wt % miscible water
369
-------
Material
Coal
liquid
inter-
mediates
Process
SRC- 1
EDS
Tab!
Coal Type
KY No. 9
and 14
KY No. 9
and 14
NA
NA
NA
IL No. 6
e 208.
Value
(Wt %)
0.46
0.22
0.30
0.49
0.26
0.22
Sulfur Content
Sample Description/Sourc
Ft. Lewis pilot plant,
process solvent
Ft. Lewis pilot plant,
wash solvent
Wilsonville pilot plant,
process solvent
Wilsonville pilot plant,
process solvent
Wilsonville pilot plant,
wash solvent
One tpd pilot plant,
IL No. 6
IL No. 6
IL No. 6 0.
(Monterey
Mine)
IL No. 6 0
(Monterey
Mine)
IL No. 6 0.
(Monterey
Mine)
IL No. 6 0.
(Monterey
Mine)
Wl I W V fir Wl f* ' • W ^» f* i w I I «* J
process solvent from
"typical" run (Run A-5)
0.2860 One tpd pilot plant,
process solvent
0.3000 One tpd pilot plant,
process solvent
33 +_ 0.16 One tpd pilot plant,
process solvent; average
of three operating
conditions (840°F reactor
temperature; 15-40 minutes
residence time)
,22 _+ 0.03 One tpd pilot plant,
process solvent; operating
conditions: 840°F reactor
temperature, 40 minutes
residence time; average of
ten yield periods
,01 _+ 0.00 75 Ib per day development
unit, process solvent;
average of six operating
conditions (800-880°F
reactor temperature, 25-100
minutes residence time)
.01 _+ 0.00 75 Ib per day development
unit, process solvent;
operating conditions:
840°F reactor temperature,
40 minutes residence time,
average of 21 yield
periods
(Continued)
370
83
83
84
119
84
99
99
104
99
99
99
99
-------
Table 208 (Continued)
Material
Coal
liquid
inter-
mediates
Process Coal Type
EDS IL No. 6
Value
(Wt %)
0.01
IL No. 6 0.05 + 0.04
(Monterey
Mine)
IL No. 6 0.01 +_ 0.00
(Monterey
Mine)
IL No. 6
0.95
IL No. 6 1.12 + 0.16
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
0.95 + 0.08
IL No. 6
IL No. 6
Wyodak
1.0
1.3
0.01
(Continued)
371
Sample Description/Source Reference
One tpd pilot plant, 99
hydrogenated recycle
solvent from "typical"
run (Run A-6)
One tpd pilot plant, 99
hydrogenated recycle
solvent; average of three
operating conditions
(840"F reactor temperature;
15-40 minutes residence
time)
One tpd pilot plant, 99
hydrogenated recycle
solvent; operating
conditions: 840°F reactor
temperature, 40 minutes
residence time; average of
ten yield periods
One tpd pilot plant, 99
vacuum gas oil from
"typical" run (Run A-2)
One tpd pilot plant, 99
vacuum gas oil; average
of three operating
conditions (840°F reactor
temperature; 15-40 minutes
residence time)
One tpd pilot plant, 99
vacuum gas oil; operating
conditions: 840°F reactor
temperature; 40 minutes
residence time; average
of ten yield periods
One tpd pilot plant, coker 99
gas oil from "typical" run
One tpd pilot plant, coker 99
scrubber liquids from
"typical" run
One tpd pilot plant, 99
process solvent from
"typical" run (Run A-5)
-------
Table 208 (Continued)
Material
Coal
liquid
inter-
mediates
Process Coal Type
EDS Wyodak
Value
(Wt %)
0.02 + 0.01
Wyodak
0.01 + 0.00
Wyodak
0.00 + 0.00
Wyodak
0.00 + 0.00
Wyodak
Wyodak
0.00
0.01 + 0.01
Wyodak
0.00 + 0.00
(Continued)
Sample Description/Source Reference
One tpd pilot plant, 99
process solvent; average
of six operating
conditions (800-8408F
reactor temperature,
40-100 minutes residence
time)
One tpd pilot plant, 99
process solvent; operating
conditions: 840°F reactor
temperature, 60 minutes
residence time, average of
seven yield periods
75 Ib per day development 99
unit; process solvent;
average of eight operating
conditions (800-880"F
reactor temperature, 25-100
minutes residence time)
75 Ib per day development 99
unit; process solvent;
operating conditions:
880°F reactor temperature,
25 minutes residence time,
average of six yield
periods
One tpd pilot plant, 99
hydrogenated recycle
solvent from "typical" run
(Run A-6)
One tpd pilot plant, 99
hydrogenated recycle
solvent; average of six
operating conditions
(800-840°F reactor
temperature, 40-100
minutes residence time)
One tpd pilot plant, 99
hydrogenated recycle
solvent; operating
conditions: 840°F reactor
temperature, 60 minutes
residence time, average
of seven yield periods
372
-------
Table 208 (Continued)
Material Process Coal Type
Coal
liquid
inter-
mediates
EDS
Wyodak
Wyodak
Wyodak
Wyodak
Wyodak
NA
NA
NA
NA
NA
Value
(Wt %)
0.05
0.08 + 0.03
0.05 + 0.01
0.09
0.14
0.03
0.02
0.23
1.26
0.64
(Continued)
373
Sample Description/Source Reference
One tpd pilot plant, 99
vacuum gas oil from
"typical" run (Run A-2)
One tpd pilot plant, 99
vacuum gas oil; average
of six operating
conditions (800-840°F
reactor temperature;
40-100 minutes residence
time)
One tpd pilot plant, 99
vacuum gas oil; operating
conditions: 840"F reactor
temperature, 60 minutes
residence time, average of
seven yield periods
One tpd pilot plant, coker 99
gas oil from "typical" run
One tpd pilot plant, coker 99
scrubber liquids from
"typical" run
One tpd pilot plant, 84
hydrogenated recycle
solvent
One tpd pilot plant, 84
hydrogenated recycle
solvent, reprocessed to
remove 650°F+ fraction
One tpd pilot plant, 91
process solvent (DuPont
"Notebook" Sample No. 16928)
One tpd pilot plant, 91
vacuum gas oil (DuPont
"Notebook" Sample No. 16928)
One tpd pilot plant, 91
heavy gas oil (DuPont
"Notebook" Sample No. 16928)
-------
Table 208 (Continued)
Material
Coal
liquid
inter-
medi ates
Process Coal Type
H-Coal IL No. 6
IL No. 6
IL No. 6
KY No. 11
KY No. 11
KY No. 11
KY No. 11
IL No. 6
IL No. 6
Value
(Wt %)
0.13*
0.29*
0.26*
KY No. 11 <0.03*
0.12*
0.18*
0.17*
0.15*
0.07
0.17
Sample Description/Source Reference
POU Run 8, Period SAB, 155
fuel oil mode with low
catalyst age, atmospheric
still overhead"*",!
PDU Run 8, Period 11B, 155
fuel oil mode with high
catalyst age, atmospheric
still overhead*,?
PDU Run 8, Period 20AB, 155
intermediate mode with
high catalyst age, atmos-
pheric still overhead',*
PDU Run 9, Period SAB, 156
syncrude mode, atmospheric
still overhead§,#
PDU Run 9, Period 12AB, 156
syncrude mode, atmospheric
still overhead§,#
PDU Run 9, Period 18AB, 156
syncrude mode, atmospheric
still overhead§,#
PDU Run 9, Period 23AB, 156
syncrude mode, atmospheric
still overhead§,#
PDU Run 9, Period 28AB, 156
syncrude mode, atmospheric
still overhead§,#
PDU Run 8, Period SAB, 155
fuel oil mode with low
catalyst age, vacuum still
overhead*,*
PDU Run 8, Period 11B, 155
fuel oil mode with high
catalyst age, vacuum still
overhead*,!
(Continued)
374
-------
Materi a_l
Coal
liquid
inter-
medi ates
Process, Coal Type
H-Coal IL No. 6
Table 208 (Continued)
Sample Description/Source Reference
KY No. 11
KY No. 11
KY No. 11
KY No. 11
KY No. 11
IL No. 6
IL No. 6
IL No. 6
KY No. 11
KY No. 11
Value
(Wt *)
0.16
<0.03
0.05
0.11
0.17
0.13
<0.03
0.10
0.14
<0.03
<0.03
(Continued)
375
PDU Run 8, Period 20AB, 155
intermediate mode with
high catalyst age, vacuum
still overhead',!
PDU Run 9, Period SAB, 156
syncrude mode, vacuum
still overhead§,#
PDU Run 9, Period 12AB, 156
syncrude mode, vacuum
still overhead§,#
PDU Run 9, Period 18AB, 156
syncrude mode, vacuum
still overhead§,#
PDU Run 9, Period 23AB, 156
syncrude mode, vacuum
still overhead§,#
PDU Run 9, Period 28AB, 156
syncrude mode, vacuum
still overhead§,f
PDU Run 8, Period 3AB, 155
fuel oil mode with low
catalyst age, atmospheric
still bottoms1",f
PDU Run 8, Period 11B, 155
fuel oil mode with high
catalyst age, atmospheric
still bottoms*,t
PDU Run 8, Period 20AB, 155
intermediate mode with high
catalyst age, atmospheric
still bottoms',*
PDU Run 9, Period 6AB, 156
syncrude mode, atmos-
pheric still bottoms§,#
PDU Run 9, Period 12AB, 156
syncrude mode, atmos-
pheric still bottoms§,#
-------
Table 208 (Continued)
Material
Coal
liquid
inter -
medi ates
Process Coal Type
H-Coal KY No. 11
KY No. 11
KY No. 11
IL No. 6
Value
(Ht
IL No. 6
IL No. 6
KY No. 11
KY No. 11
KY No. 11
KY No. 11
KY No. 11
0.04
0.11
0.08
2.22
2.22
1.99
3.00
2.73
2.75
2.44
2.86
Sample Description/Source Reference
156
PDU Run 9, Period 18AB,
syncrude mode, atmospheric
still bottoms§,#
POU Run 9, Period 23AB,
syncrude mode, atmospheric
still bottoms§,#
POU Run 9, Period 28AB,
syncrude mode, atmos-
pheric still bottoms§,#
POU Run 8, Period 3AB,
fuel oil mode with low
catalyst age, vacuum still
bottoms',f
PDU Run 8, Period 11B,
fuel oil mode with high
catalyst age, vacuum still
bottoms
POU Run 8, Period 20AB,
intermediate mode with high
catalyst age, vacuum still
bottoms' ,f
PDU Run 9, Period 6AB,
syncrude mode, vacuum
still bottoms§,#
PDU Run 9, Period 12AB,
syncrude mode, vacuum
still bottoms§,#
PDU Run 9, Period 18AB,
syncrude mode, vacuum
still bottoms§,#
PDU Run 9, Period 23AB,
syncrude mode, vacuum
still bottoms§,#
PDU Run 9, Period 28AB,
syncrude mode, vacuum
still bottoms§, #
156
156
155
155
155
156
156
156
156
156
(Continued)
376
-------
Table 208 (Continued)
Material
Coal
liquid
inter-
mediates
Process Coal Type
H-Coal NA
NA
NA
NA
NA
IL No. 6
(Burning
Star Mine)
NA
IL. No. 6
IL. No. 6
IL No. 6
IL No. 6
IL No. 6
IL No. 6
Value
(Wt %)
0.41
Sample Description/Source Reference
91
PDU, fuel oil mode,
atmospheric still overhead
0.15
0.12
1.81
2.23
0.15
0.14
0.21
0.27
0.07
<0.03
<0.03
3.0
(Continued)
377
PDU, fuel oil mode, vacuum 91
stil1 overhead
PDU, fuel oil mode, 91
atmospheric still bottoms
PDU, fuel oil mode, vacuum 91
stil1 bottoms
PDU, syncrude mode, vacuum 91
still bottoms
PDU, blend of atmospheric 144
still overhead and bottoms
PDU, atmospheric still 84
bottoms
PDU, syncrude mode, blend of 97
atmospheric still overhead
and vacuum still overhead
PDU, fuel oil mode, blend of 97
atmospheric still overhead
and vacuum still overhead
PDU, syncrude mode, . 151
atmospheric still overhead,
DOE Sample No. 1308
PDU, syncrude mode, 151
atmospheric stjll bottoms,
DOE Sample No. 1309
PDU, syncrude mode, vacuum 151
still overhead, DOE Sample
No. 1310
PDU, syncrude mode, vacuum 151
still bottoms, DOE Sample
No. 1311
-------
Table 208 (Concluded)
Material
Coal
liquid
inter-
mediates
Process Coal Type
H-Coal IL. No. 6
IL. No 6
IL No. 6
IL. No. 6
Value
(Wt %)
0.2
0.5
0.1
2.2
Sample Description/Source Referencg
PDU, fuel oil mode, 151
atmospheric still overhead,
DOE Sample No. 1312
PDU, fuel oil mode, 151
atmospheric still bottoms,
DOE Sample No. 1313
PDU, fuel oil mode, vacuum 151
still overhead, DOE Sample
No. 1314
PDU, fuel oil mode, vacuum 151
still bottoms, DOE Sample
No. 1315
Explanatory Notes:
*H2S free
'''See General Comments section, Note 2, for summary of operating conditions used.
^Periods 3AB, 118 and 20AB are considered representative periods for the entire
PDU Run 8, which consisted of over 32 individual periods.
§See General Comments section, Note 3, for summary of operating conditions used.
IPeriods 6AB, 12AB, 18AB, 23AB and 28AB are considered representative periods for
the entire PDU Run 9» which consisted of over 30 individual periods.
378
-------
Material Process
Table 209. Nitrogen Content
Value
Coal Type (Wt %) Sample Description/Source
Coal
liquid
inter-
mediates
SRC-1
EDS
KY No. 9
and 14
KY No. 9
and 14
NA
NA
NA
IL No. 6
IL No. 6
0.30
IL No. 6 0.20
(Monterey
Mine)
IL No. 6 0.24 + 0.05
(Monterey
Mine)
IL No. 6 0.30 + 0.04
(Monterey
Mine)
IL No. 6 0.05 + 0.01
(Monterey
Mine)
IL No. 6 0.04 +_ 0.01
(Monterey
Mine)
(Continued)
379
Ft. Lewis pilot plant,
process solvent
Ft. Lewis pilot plant,
wash solvent
Wilsonville pilot plant,
process solvent
Wilsonville pilot plant,
process solvent
Wilsonville pilot plant,
wash solvent
One tpd pilot plant,
process solvent from
"typical" run (Run A-5)
One tpd pilot plant,
process solvent
One tpd pilot plant,
process solvent
Reference
83
83
84
119
84
99
99
104
99
One tpd pilot plant,
process solvent; average
of three operating
conditions (840°F reactor
temperature; 15-40 minutes
residence time)
One tpd pilot plant, 99
process solvent; operating
conditions: 840°F reactor
temperature, 40 minutes
residence time; average of
ten yield periods
75 Ib per day development 99
unit, process solvent;
average of six operating
conditions (800-880°F
reactor temperature, 25-100
minutes residence time)
75 Ib per day development 99
unit, process solvent;
operating conditions:
840°F reactor temperature,
40 minutes residence time,
average of 21 yield
periods
-------
Table 209 (Continued)
Material
Coal
liquid
inter-
mediates
Process Coal Type
EDS IL No. 6
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
IL No. 6
Wyodak
Value
(Wt %)
0.18
0.11 + 0.06
0.18 + 0.08
1.38
1.23 + 0.13
1.38 + 0.15
1.1
1.7
0.12
(Continued)
380
Sample Description/Source Reference
One tpd pilot plant, 99
hydrogenated recycle
solvent from "typical"
run (Run A-6)
One tpd pilot plant, 99
hydrogenated recycle
solvent; average of three
operating conditions
(840°F reactor temperature;
15-40 minutes residence
time)
One tpd pilot plant, 99
hydrogenated recycle
solvent; operating
conditions: 840°F reactor
temperature, 40 minutes
residence time; average of
ten yield periods
One tpd pilot plant, 99
vacuum gas oil from
"typical" run (Run A-2)
One tpd pilot plant, 99
vacuum gas oil; average
of three operating
conditions (840eF reactor
temperature; 15-40 minutes
residence time)
One tpd pilot plant, 99
vacuum gas oil; operating
conditions: 840°F reactor
temperature, 40 minutes
residence time; average
of ten yield periods
One tpd pilot plant, coker 99
gas oil from "typical" run
One tpd pilot plant, coker 99
scrubber liq-uids from
"typical" run
One tpd pilot plant, 99
process solvent from
"typical" run (Run A-5)
-------
Table 209 (Continued)
Material
Coal
liquid
inter-
mediates
Value
Process Coal Type (Wt %)
EDS
Wyodak 0.15 + 0.02
Wyodak 0.12 + 0.05
Wyodak 0.12 + 0.12
Wyodak 0.19 + 0.03
Wyodak
0.07
Wyodak 0.07 + 0.02
Wyodak
0.07 + 0.02
(Continued)
381
Sample Description/Source Reference
One tpd pilot plant, 99
process solvent; average
of six operating
conditions (800-840°F
reactor temperature,
40-100 minutes residence
time)
One tpd pilot plant, 99
process solvent; operating
conditions: 840"F reactor
temperature, 60 minutes
residence time, average of
seven yield periods
75 Ib per day development 99
unit; process solvent;
average of eight operating
conditions (800-880°F
reactor temperature, 25-100
minutes residence time)
75 Ib per day development 99
unit; process solvent;
operating conditions:
880°F reactor temperature,
25 minutes residence time,
average of six yield
periods
One tpd pilot plant, 99
hydrogenated recycle
solvent from "typical" run
(Run A-6)
One tpd pilot plant, 99
hydrogenated recycle
solvent; average of six
operating conditions
(800-840°F reactor
temperature, 40-100
minutes residence time)
One tpd pilot plant, 99
hydrogenated recycle
solvent; operating
conditions: 840°F reactor
temperature, 60 minutes
residence time, average
of seven yield periods
-------
Table 209 (Continued)
Material
Coal
liquid
inter-
mediates
Process
EDS
Coal Type
Wyodak
Value
(Wt %)
0.69
Sample Description/Source
One tpd pilot plant,
vacuum gas oil from
"typical" run (Run A-2)
Reference
99
Wyodak
0.76 + 0.19
Wyodak
Wyodak
Wyodak
NA
NA
NA
NA
NA
0.69 + 0.22
0.72
1.22
0.08
0.044
0.45
1.17
1.06
(Continued)
382
One tpd pilot plant, 99
vacuum gas oil; average
of six operating
conditions (800-840'F
reactor temperature;
40-100 minutes residence
time)
One tpd pilot plant, 99
vacuum gas oil; operating
conditions: 840°F reactor
temperature, 60 minutes
residence time, average of
seven yield periods
One tpd pilot plant, coker 99
gas oil from "typical" run
One tpd pilot plant, coker 99
scrubber liquids from
"typical" run
One tpd pilot plant, 84
hydrogenated recycle
solvent
One tpd pilot plant, 84
hydrogenated recycle
solvent, reprocessed to
remove 650"F+ fraction
One tpd pilot plant, 91
process solvent (DuPont
"Notebook" Sample No. 16928)
One tpd pilot plant, 91
vacuum gas oil (DuPont
"Notebook" Sample No. 16928)
One tpd pilot plant, 91
heavy gas oil (DuPont
"Notebook" Sample No. 16928)
-------
Table 209 (Continued)
Material
Coal
liquid
inter-
mediates
Process Coal Type
H-Coal IL No. 6
IL No. 6
IL No. 6
KY No. 11
KY No. 11
KY No. 11
KY No. 11
KY No. 11
Value
(Wt X)
0.24
0.28
0.38
0.31
0.36
0.33
0.42
0.28
Sample Description/Source Reference
POD Run 8, Period 3AB, 155
fuel oil mode with low
catalyst age, atmospheric
still overhead*,""
PDU Run 8, Period 11B, 155
fuel oil mode with high
catalyst age, atmospheric
still overhead*,"''
PDU Run 8, Period 20AB, 155
intermediate mode with
high catalyst age, atmos-
pheric still overhead
PDU Run 9, Period 6AB, 156
syncrude mode, atmospheric
still overhead!,§
PDU Run 9, Period 12AB, 156
syncrude mode, atmospheric
still overhead!,§
PDU Run 9, Period 18AB, 156
syncrude mode, atmospheric
still overhead!,§
PDU Run 9, Period 23AB, 156
syncrude mode, atmospheric
still overhead!,§
PDU Run 9, Period 28AB, 156
syncrude mode, atmospheric
still overhead!,§
IL No. 6
IL No. 6
0.93
0.71
PDU Run 8, Period 3AB, 155
fuel oil mode with low
catalyst age, vacuum still
overhead*,'
PDU Run 8, Period 118, 155
fuel oil mode with high
catalyst age, vacuum still
overhead*,'
(Continued)
383
-------
Table 209 (Continued)
Material
Coal
1iquid
inter-
mediates
Process Coal Type
H-Coal IL No. 6
KY No. 11
KY No. 11
KY No. 11
KY No. 11
KY No. 11
IL No. 6
IL No. 6
IL No. 6
KY No. 11
KY No. 11
Value
(Wt %)
0.62
0.63
0.75
0.69
0.75
0.96
0.40
0.55
0.57
0.53
0.47
Sample Description/Source Reference
PDU Run 8, Period 20AB, 155
intermediate mode with
high catalyst age, vacuum
still overhead*,'*'
PDU Run 9, Period 6AB, 156
syncrude mode, vacuum
still overhead!^
PDU Run 9, Period 12AB, 156
syncrude mode, vacuum
still overheadf,§
PDU Run 9, Period 18AB, 156
syncrude mode, vacuum
still overheadt,§
PDU Run 9, Period 23AB, 156
syncrude mode, vacuum
still overhead^
PDU Run 9, Period 28AB, 156
syncrude mode, vacuum
still overhead^
PDU Run 8, Period 3AB, 155
fuel oil mode with low
catalyst age, atmospheric
still bottoms*,1"
PDU Run 8, Period 11B, 155
fuel oil mode with high
catalyst age, atmospheric
still bottoms*,t
PDU Run 8, Period 20AB, 155
intermediate mode with high
catalyst age, atmospheric
still bottoms*,1"
PDU Run 9, Period 6AB, 156
syncrude mode, atmos-
pheric still bottoms!,§
PDU Run 9, Period 12AB, 156
syncrude mode, atmos-
pheric still bottomsf,§
(Continued)
384
-------
Table 209 (Continued)
Value
l Process Coal Type (Wt %0) Sample Description/Source Reference
Coal H-Coal KY No. 11 0.48 PDU Run 9, Period 18AB, 156
liquid syncrude mode, atmospheric
inter- still bottoms*,§
mediates
KY No. 11 0.69 PDU Run 9, Period 23AB, 156
syncrude mode, atmospheric
still bottoms?,§
KY No. 11 0.71 PDU Run 9, Period 28A8, 156
syncrude mode, atmos-
pheric still bottoms*,§
IL No. 6 1.32 PDU Run 8, Period 3AB, 155
fuel oil mode with low
catalyst age, vacuum still
bottoms*,'
IL No. 6 1.65 PDU Run 8, Period 11B, 155
fuel oil mode with high
catalyst age, vacuum still
bottoms*,T
IL No. 6 1.50 PDU Run 8, Period 20AB, 155
intermediate mode with high
catalyst age, vacuum still
bottoms*,*
KY No. 11 1.21 PDU Run 9, Period 6AB, 156
syncrude mode, vacuum
still bottomst,§
KY No. 11 1.28 PDU Run 9, Period 12AB, 156
syncrude mode, vacuum
still bottomst,§
KY No. 11 1.51 PDU Run 9, Period 18AB, 156
syncrude mode, vacuum
still bottoms*,§
KY No. 11 1.47 PDU Run 9, Period 23AB, 156
syncrude mode, vacuum
still bottomst,§
KY No. 11 1.48 PDU Run 9, Period 28AB, 156
syncrude mode, vacuum
still bottoms*,§
(Continued)
385
-------
Table 209 (Continued)
Material
Coal
liquid
inter-
mediates
Process Coal Type
H-Coal NA
NA
NA
NA
NA
IL No. 6
(Burning
Star Mine)
NA
IL. No. 6
Value
(Wt %)
0.86
0.69
0.78
1.28
1.25
0.37
0.61
0.440
Sample Description/Source
PDU, fuel oil mode,
atmospheric still overhead
PDU, fuel oil mode, vacuum
still overhead
PDU, fuel oil mode,
atmospheric still bottoms
PDU, fuel oil mode, vacuum
stil 1 bottoms
PDU, syncrude mode, vacuum
still bottoms
PDU, blend of atmospheric
still overhead and bottoms
PDU, atmospheric still
bottoms
Reference
91
91
91
91
91
144
84
PDU, syncrude mode, blend of 97
atmospheric still overhead
and vacuum still overhead
IL. No. 6 0.633 PDU, fuel oil mode, blend of 97
atmospheric still overhead
and vacuum still overhead
IL No. 6 0.17 PDU, syncrude mode, 151
atmospheric still overhead,
DOE Sample No. 1308
IL No. 6 0.37 PDU, syncrude mode, 151
atmospheric still bottoms,
DOE Sample No. 1309
IL No. 6 0.42 PDU, syncrude mode, vacuum 151
still overhead, DOE Sample
No. 1310
IL No. 6 0.90 PDU, syncrude mode, vacuum 151
still bottoms, DOE Sample
No. 1311
(Continued)
386
-------
Table 209 (Concluded)
Material
Coal
liquid
inter-
mediates
Process Coal Type
H-Coal IL No. 6
IL No. 6
IL No. 6
IL No. 6
Value
(Wt %)
0.30
0.40
0.50
1.5
Sample Description/Source Reference
PDU, fuel oil mode, 151
atmospheric still overhead,
DOE Sample No. 1312
PDU, fuel oil mode, 151
atmospheric still bottoms,
DOE Sample No. 1313
PDU, fuel oil mode, vacuum 151
still overhead, DOE Sample
No. 1314
PDU, fuel oil mode, vacuum 151
still bottoms, DOE Sample
No. 1315
Explanatory Notes:
*See General Comments section, Note 2, for summary of operating conditions used.
'Periods 3AB, 11B and 20AB are considered representative periods for the entire
PDU Run 8, which consisted of over 32 individual periods.
fSee General Comments section, Note 3, for summary of operating conditions used.
§Periods SAB, 12AB, 18AB, 23AB and 28AB are considered representative periods for
the entire PDU Run 9, which consisted of over 30 individual periods.
387
-------
Table 210. Carbon Content
Material Process Coal Type
Coal
liquid
inter-
medi ates
SRC-1
EDS
KY No. 9
and 14
KY No. 9
and 14
IL No. 6
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
5.71
5.36 + 0.35
1.71 + 0.18
89.93 + 0.62
89.49 + 0.15
89.24
Sample Description/Source Reference
83
Ft. Lewis pilot plant,
process solvent
Ft. Lewis pilot plant, 83
wash solvent
One tpd pilot plant, 99
process solvent from
"typical" run (Run A-5)
One tpd pilot plant, 99
process solvent; average
of three operating
conditions (840°F reactor
temperature; 15-40 minutes
residence time)
One tpd pilot plant, 99
process solvent; operating
conditions: 840°F reactor
temperature, 40 minutes
residence time; average of
ten yield periods
75 Ib per day development 99
unit, process solvent;
average of six operating
conditions (800-880°F
reactor temperature, 25-100
minutes residence time)
75 Ib per day development 99
unit, process solvent;
operating conditions:
840°F reactor temperature,
40 minutes residence time,
average of 21 yield
periods
One tpd pilot plant, 99
hydrogenated recycle
solvent from "typical"
run (Run A-6)
(Continued)
388
-------
Table 210 (Continued)
Material Process Coal Type
Coal
liquid
inter-
mediates
EDS
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
IL No. 6
Wyodak
Value
(Wt X)
89.52 + 0.16
89.24 + 0.23
86.9
85.94 + 0.72
Sample Description/Source Reference
One tpd pilot plant, 99
hydrogenated recycle
solvent; average of three
operating conditions
(840"F reactor temperature;
15-40 minutes residence
time)
One tpd pilot plant, 99
hydrogenated recycle
solvent; operating
conditions: 840°F reactor
temperature, 40 minutes
residence time; average of
ten yield periods
One tpd pilot plant, 99
vacuum gas oil from
"typical" run (Run A-2)
One tpd pilot plant, 99
vacuum gas oil; average
of three operating
conditions (840°F reactor
temperature; 15-40 minutes
residence time)
86.95 HK 0.49 One tpd pilot plant, 99
vacuum gas oil; operating
conditions: 840*F reactor
temperature; 40 minutes
residence time; average
of ten yield periods
36.0 One tpd pilot plant, coker 99
gas oil from "typical" run
86.7 One tpd pilot plant, coker 99
scrubber liquids from
"typical" run
89.26 One tpd pilot plant, 99
process solvent from
"typical" run (Run A-5)
(Continued)
389
-------
Table 210 (Continued)
Material Process Coal Type
Coal
liquid
inter-
mediates
EDS
Wyodak
Value
(Wt %)
89.68 + 0.40
Wyodak
89.26 + 0.15
Wyodak
90.24 + 1.12
Wyodak
90.46 + 0.13
Wyodak
Wyodak
89.47
89.61 + 0.30
Sample Description/Source Reference
One tpd pilot plant, 99
process solvent; average
of six operating
conditions (800-840°F
reactor temperature,
40-100 minutes residence
time)
One tpd .pilot plant, 99
process solvent; operating
conditions: 840°F reactor
temperature, 60 minutes
residence time, average of
seven yield periods
75 Ib per day development 99
unit; process solvent;
average of eight operating
conditions (800-880"F
reactor temperature, 25-100
minutes residence time)
75 Ib per day development 99
unit; process solvent;
operating conditions:
880"F reactor temperature,
25 minutes residence time,
average of six yield
periods
One tpd pilot plant, 99
hydrogenated recycle
solvent from "typical" run
(Run A-6)
One tpd pilot plant, 99
hydrogenated recycle
solvent; average of six
operating conditions
(800-840°F reactor
temperature, 40-100
minutes residence time)
(Continued)
390
-------
Table 210 (Continued)
Material
Coal
liquid
inter-
mediates
Process Coal Type
EDS Wyodak
Value
(Wt %)
Wyodak
Wyodak
Wyodak
Wyodak
Wyodak
NA
NA
NA
Sample Description/Source Reference
99
89.47 _+ 0.17 One tpd pilot plant,
hydrogenated recycle
solvent; operating
conditions: 840°F reactor
temperature, 60 minutes
residence time, average
of seven yield periods
89.28 One tpd pilot plant,
vacuum gas oil from
"typical" run (Run A-2)
88.40 ^ 1.46 One tpd pilot plant,
vacuum gas oil; average
of six operating
conditions (800-840°F
reactor temperature;
40-100 minutes residence
time)
89.28 +_ 0.94 One tpd pilot plant,
vacuum gas oil; operating
conditions: 840°F reactor
temperature, 60 minutes
residence time, average of
seven yield periods
90.13
89.68
88.58
85.90
87.49
(Continued)
391
One tpd pilot plant, coker
gas oil from "typical" run
One tpd pilot plant, coker
scrubber liquids from
"typical" run
One tpd pilot plant,
process solvent (DuPont
"Notebook" Sample No. 16928)
One tpd pilot plant,
vacuum gas oil (DuPont
"Notebook" Sample No. 16928)
One tpd pilot plant,
heavy gas oil (DuPont
"Notebook" Sample No. 16928)
99
99
99
99
99
91
91
91
-------
Table 210 (Continued)
Value
Material Process Coal Type (Vlt X) Sample Description/Source Reference
Coal H-Coal IL No. 6 87.56 PDU Run 8, Period SAB, 155
liquid fuel oil mode with low
inter- catalyst age, atmospheric
mediates still overhead*,1"
IL No. 6 85.70 PDU Run 8, Period 11B, 155
fuel oil mode with high
catalyst age, atmospheric
still overhead*,^
IL No. 6 86.66 PDU Run 8, Period 20AB, 155
intermediate mode with
high catalyst age, atmos-
pheric still overhead*,'
KY No. 11 85.35 PDU Run 9, Period 6AB, 156
syncrude mode, atmospheric
still overhead?,§
KY No. 11 84.05 PDU Run 9, Period 12AB, 156
syncrude mode, atmospheric
still overhead!,§
KY No. 11 85.60 PDU Run 9, Period 18AB, 156
syncrude mode, atmospheric
still overhead*,§
KY No. 11 87.33 PDU Run 9, Period 23AB, 156
syncrude mode, atmospheric
still overhead?,§
KY No. 11 86.92 PDU Run 9, Period 28AB, 156
syncrude mode, atmospheric
still overhead*,§
IL No. 6 89.65 PDU Run 8, Period 3AB, 155
fuel oil mode with low
catalyst age, vacuum still
overhead*,'
IL No. 6 89.07 PDU Run 8, Period 11B, 155
fuel oil mode with high
catalyst age, vacuum still
overhead*,'
(Continued)
392
-------
Table 210 (Continued)
Value
Material Process Coal Type (Wt %) Sample Description/Source Reference
Coal H-Coal IL No. 6 89.37 PDU Run 8, Period 20AB, 155
liquid intermediate mode with
inter- high catalyst age, vacuum
mediates still overhead*,'
KY No. 11 88.51 PDU Run 9, Period 6AB, 156
syncrude mode, vacuum
stil1 overhead?,§
KY No. 11 89.26 PDU Run 9, Period 12AB, 156
syncrude mode, vacuum
still overhead?,§
KY No. 11 89.21 PDU Run 9, Period 18AB, 156
syncrude mode, vacuum
still overhead!,§
KY No. 11 89.33 PDU Run 9, Period 23AB, 156
syncrude mode, vacuum
still overhead?,§
KY No. 11 88.38 PDU Run 9, Period 28AB, 156
syncrude mode, vacuum
still overhead?,§
IL No. 6 89.86 PDU Run 8, Period 3AB, 155
fuel oil mode with low
catalyst age, atmospheric
still bottoms*,''
IL No. 6 88.41 PDU Run 8, Period 11B, 155
fuel oil mode with high
catalyst age, atmospheric
still bottoms*,'
IL No. 6 88.92 PDU Run 8, Period 20AB, 155
intermediate mode with high
catalyst age, atmospheric
still bottoms*/
KY No. 11 88.73 PDU Run 9, Period 6AB, 156
syncrude mode, atmos-
pheric still bottomsf,§
KY No. 11 88.51 POU Run 9, Period 12AB, 156
syncrude mode, atmos-
pheric still bottoms?,§
(Continued)
393
-------
Table 210 (Continued)
Material.
Coal
liquid
inter-
mediates
Process Coal Type
H-Coal KY No. 11
KY No. 11
KY No. 11
IL No. 6
IL No. 6
IL No. 6
KY No. 11
KY No. 11
KY No. 11
KY No. 11
KY No. 11
Value
(Mt XO)
88.74
88.71
1.16
70.16
70.00
70.42
64.30
68.03
71.54
73.32
70.80
Sample Description/Source Reference
POU Run 9, Period 18AB, 156
syncrude mode, atmospheric
still bottoms?,§
PDU Run 9, Period 23AB, 156
syncrude mode, atmospheric
still bottoms*,§
POU Run 9, Period 28AB, 156
syncrude mode, atmos-
pheric still bottoms?,§
PDU Run 8, Period 3AB, 155
fuel oil mode with low
catalyst age, vacuum still
bottoms*,T
POU Run 8, Period 11B, 155
fuel oil mode with high
catalyst age, vacuum still
bottoms*,''
PDU Run 8, Period 20AB, 155
intermediate mode with high
catalyst age, vacuum still
bottoms*,T
PDU Run 9, Period 6AB, 156
syncrude mode, vacuum
still bottoms!,§
PDU Run 9, Period 12AB, 156
syncrude mode, vacuum
still bottoms?,§
PDU Run 9, Period 18AB, 156
syncrude mode, vacuum
still bottoms?,§
POU Run 9, Period 23AB, 156
syncrude mode, vacuum
still bottoms?,§
PDU Run 9, Period 28AB, 156
syncrude mode, vacuum
still bottoms?,§
(Continued)
394
-------
Table 210 (Concluded)
Material Process
Coal H-Coal
liquid
inter-
mediates
Explanatory Notes:
Coal Type
NA
NA
NA
NA
NA
IL No. 6
(Burning
Star Mine)
Value
(Wt %)
85.58
88.88
88.58
70.89
66.24
86.7
Sample Description/Source
PDU, fuel oil mode,
atmospheric still overhead
PDU, fuel oil mode, vacuum
stil 1 overhead
PDU, fuel oil mode,
atmospheric still bottoms
PDU, fuel oil mode, vacuum
still bottoms
PDU, syncrude mode, vacuum
still bottoms
PDU, blend of atmospheric
still overhead and bottoms
Reference
91
91
91
91
91
144
*See General Comments section, Note 2, for summary of operating conditions used.
^Periods SAB, 11B and 20AB are considered representative periods for the entire
PDU Run 8, which consisted of over 32 individual periods.
fSee General Comments section, Note 3, for summary of operating conditions used.
§Periods 6AB, 12AB, 18AB, 23AB and 28AB are considered representative periods for
the entire PDU Run 9, which consisted of over 30 individual periods.
395
-------
Material
Coal
1iquid
inter-
mediates
Table 211. Hydrogen Content
Value
Process Coal Type
SRC-I
EDS
KY No. 9
and 14
KY No. 9
and 14
NA
NA
NA
IL No. 6
IL No. 6
(Monterey
Mine)
8.65
7.74
7.65
9.23
9.46
10.0
IL No. 6 9.95 + 0.52
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
9.46 + 0.21
9.72 + 0.34
10.16 + 0.16
(Continued)
396
Sample Description/Source Reference
Ft. Lewis pilot plant, 83
process solvent
Ft. Lewis pilot plant, 83
wash solvent
Wilsonville pilot plant, 84
process solvent
Wilsonville pilot plant, 119
process solvent
Wilsonville pilot plant, 84
wash solvent
One tpd pilot plant, 99
process solvent from
"typical" run (Run A-5)
One tpd pilot plant, 104
process solvent
One tpd pilot plant, 99
process solvent; average
of three operating
conditions (8408F reactor
temperature; 15-40 minutes
residence time)
One tpd pilot plant, 99
process solvent; operating
conditions: 840°F reactor
temperature, 40 minutes
residence time; average of
ten yield periods
75 Ib per day development 99
unit, process solvent;
average of six operating
conditions (800-880°F
reactor temperature, 25-100
minutes residence time)
75 Ib per day development 99
unit, process solvent;
operating conditions:
840°F reactor temperature,
40 minutes residence time,
average of 21 yield
periods
-------
Table 211 (Continued)
Material
Coal
liquid
inter-
mediates
Process Coal Type
EDS IL No. 6
Value
(Wt %)
10.14
IL No. 6
(Monterey
Mine)
10.05 + 0.80
IL No. 6
(Monterey
Mine)
10.14 + 0.32
IL No. 6
6.74
IL No. 6 7.22 + 0.45
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
6.74 + 0.17
IL No. 6
IL No. 6
Wyodak
7.4
5.8
9.47
(Continued)
397
Sample Description/Source Reference
One tpd pilot plant, 99
hydrogenated recycle
solvent from "typical"
run (Run A-6)
One tpd pilot plant, 99
hydrogenated recycle
solvent; average of three
operating conditions
(840°F reactor temperature;
15-40 minutes residence
time)
One tpd pilot plant, 99
hydrogenated recycle
solvent; operating
conditions: 840°F reactor
temperature, 40 minutes
residence time; average of
ten yield periods
One tpd pilot plant, 99
vacuum gas oil from
"typical" run (Run A-2)
One tpd pilot plant, 99
vacuum gas oil; average
of three operating
conditions (840eF reactor
temperature; 15-40 minutes
residence time)
One tpd pilot plant, 99
vacuum gas oil; operating
conditions: 840°F reactor
temperature; 40 minutes
residence time; average
of ten yield periods
One tpd pilot plant, coker 99
gas oil from "typical" run
One tpd pilot plant, coker 99
scrubber liquids from
"typical" run
One tpd pilot plant, 99
process solvent from
"typical" run (Run A-5)
-------
Table 211 (Continued)
Material
Coal
liquid
inter-
mediates
Value
Process Coal Type (Wt %)
EDS Wyodak 9.22 + 0.32
Wyodak
9.47 + 0.31
Wyodak
9.42 + 0.37
Wyodak
9.15 + 0.18
Wyodak
Wyodak
10.08
10.12 + 0.37
Wyodak
10.08 + 0.23
(Continued)
Sample Description/Source Reference
One tpd pilot plant, 99
process solvent; average
of six operating
conditions (800-840°F
reactor temperature,
40-100 minutes residence
time)
One tpd pilot plant, 99
process solvent; operating
conditions: 840°F reactor
temperature, 60 minutes
residence time, average of
seven yield periods
75 Ib per day development 99
unit; process solvent;
average of eight operating
conditions (800-880'F
reactor temperature, 25-100
minutes residence time)
75 Ib per day development 99
unit; process solvent;
operating conditions:
880°F reactor temperature,
25 minutes residence time,
average of six yield
periods
One tpd pilot plant, 99
hydrogenated recycle
solvent from "typical" run
(Run A-6)
One tpd pilot plant, 99
hydrogenated recycle
solvent; average of six
operating conditions
(800-840°F reactor
temperature, 40-100
minutes residence time)
One tpd pilot plant, 99
hydrogenated recycle
solvent; operating
conditions: 840°F reactor
temperature, 60 minutes
residence time, average
of seven yield periods
398
-------
Table 211 (Continued)
Material
Coal
liquid
inter-
mediates
Process
EDS
Coal Type
Wyodak
Value
(Wt %)
7.45
Wyodak
Wyodak
Wyodak
Wyodak
NA
NA
NA
NA
NA
7.65 + 0.52
7.45 + 0.41
6.63
5.57
9.95
10.16
9.17
6.52
7.21
(Continued)
399
Sample Description/Source Reference
One tpd pilot plant, 99
vacuum gas oil from
"typical" run (Run A-2)
One tpd pilot plant, 99
vacuum gas oil; average
of six operating
conditions (800-840'F
reactor temperature;
40-100 minutes residence
time)
One tpd pilot plant, 99
vacuum gas oil; operating
conditions: 840°F reactor
temperature, 60 minutes
residence time, average of
seven yield periods
One tpd pilot plant, coker 99
gas oil from "typical" run
One tpd pilot plant, coker 99
scrubber liquids from
"typical" run
One tpd pilot plant, 84
hydrogenated recycle
solvent
One tpd pilot plant, 84
hydrogenated recycle
solvent, reprocessed to
remove 650°F+ fraction
One tpd pilot plant, 91
process solvent (DuPont
"Notebook" Sample No. 16928)
One tpd pilot plant, 91
vacuum gas oil (DuPont
"Notebook" Sample No. 16928)
One tpd pilot plant, 91
heavy gas oil (DuPont
"Notebook" Sample No. 16928)
-------
Table 211 (Continued)
Material
Coal
liquid
inter-
mediates
Process Coal Type
H-Coal IL No. 6
IL No. 6
IL No. 6
KY No. 11
KY No. 11
KY No. 11
KY No. 11
KY No. 11
Value
(Wt %)
11.73
11.42
11.07
11.64
11.67
11.57
12.06
12.25
Sample Description/Source Reference
PDU Run 8, Period SAB, 155
fuel oil mode with low
catalyst age, atmospheric
still overhead*,''
PDU Run 8, Period 118, 155
fuel oil mode with high
catalyst age, atmospheric
stil 1 overhead*,'
PDU Run 8, Period 20AB, 155
intermediate mode with
high catalyst age, atmos-
pheric still overhead*'""
PDU Run 9, Period 6AB, 156
syncrude mode, atmospheric
still overhead^,§
PDU Run 9, Period 12AB, 156
syncrude mode, atmospheric
still overhead!,§
PDU Run 9, Period 18AB, 156
syncrude mode, atmospheric
still overhead!,§
PDU Run 9, Period 23AB, 156
syncrude mode, atmospheric
still overhead!,§
PDU Run 9, Period 28AB, 156
syncrude mode, atmospheric
still overhead!,§
IL No. 6
IL No. 6
8.25 PDU Run 8, Period SAB, 155
fuel oil mode with low
catalyst age, vacuum still
overhead*,*
7.96 PDU Run 8, Period 118, 155
fuel oil mode with high
catalyst age, vacuum still
overhead*,*
(Continued)
400
-------
Table 211 (Continued)
Material
Coal
liquid
inter-
medi ates
Process Coal Type
H-Coal IL No. 6
KY No. 11
KY No. 11
KY No. 11
KY No. 11
KY No. 11
IL No. 6
IL No. 6
IL No. 6
KY No. 11
KY No. 11
Value
(Wt %}
8.60
8.36
8.22
8.08
8.13
8.06
9.19
8.74
9.21
9.27
8.99
Sample Description/Source Reference
PDU Run 8, Period 20AB, 155
intermediate mode with
high catalyst age, vacuum
still overhead*,'
POU Run 9, Period 6AB, 156
syncrude mode, vacuum
still overhead?,§
PDU Run 9, Period 12A8, 156
syncrude mode, vacuum
still overhead!,§
PDU Run 9, Period 18AB, 156
syncrude mode, vacuum
still overhead?,§
PDU Run 9, Period 23AB, 156
syncrude mode, vacuum
still overhead?,§
PDU Run 9, Period 28AB, 156
syncrude mode, vacuum
still overhead?",§
PDU Run 8, Period 3AB, 155
fuel oil mode with low
catalyst age, atmospheric
still bottoms*,1"
PDU Run 8, Period 11B, 155
fuel oil mode with high
catalyst age, atmospheric
still bottoms*,1"
PDU Run 8, Period 20AB, 155
intermediate mode with high
catalyst age, atmospheric
still bottoms*,1"
PDU Run 9, Period 6AB, 156
syncrude mode, atmos-
pheric still bottoms?,§
PDU Run 9, Period 12AB, 156
syncrude mode, atmos-
pheric still bottoms?,§
(Continued)
401
-------
Table 211 (Continued)
Material
Coal
liquid
inter-
mediates
Process Coal Type
H-Coal KY No. 11
KY No. 11
KY No. 11
IL No. 6
Value
(Wt
IL No. 6
IL No. 6
KY No. 11
KY No. 11
KY No. 11
KY No. 11
KY No. 11
9.02
8.84
9.21
4.73
4.57
4.49
4.32
4.35
4.58
4.78
4.48
Sample Description/Source Reference
PDU Run 9, Period 18AB, 156
syncrude mode, atmospheric
stil1 bottoms?,§
PDU Run 9, Period 23AB, 156
syncrude mode, atmospheric
still bottoms?,§
PDU Run 9, Period 28AB, 156
syncrude mode, atmos-
pheric still bottoms?,§
PDU Run 8, Period 3AB, 155
fuel oil mode with low
catalyst age, vacuum still
bottoms*,
PDU Run 8, Period 11B, 155
fuel oil mode with high
catalyst age, vacuum still
bottoms*,1"
PDU Run 8, Period 20AB, 155
intermediate mode with high
catalyst age, vacuum still
bottoms*,'
PDU Run 9, Period SAB, 156
syncrude mode, vacuum
still bottoms?,§
PDU Run 9, Period 12AB, 156
syncrude mode, vacuum
still bottoms?,§
PDU Run 9, Period 18AB, 156
syncrude mode, vacuum
still bottoms?,§
PDU Run 9, Period 23AB, 156
syncrude mode, vacuum
still bottoms?,§
PDU Run 9, Period 28AB, 156
syncrude mode, vacuum
still bottoms?,§
(Continued)
402
-------
Table 211 (Continued)
Material
Coal
1iquid
inter-
mediates
Value
Process Coal Type (Ut %)
H-Coal NA 12.02
NA 8.47
NA 9.01
NA 4.56
NA 4.16
IL No. 6 11.0
(Burning
Star Mine)
NA 9.27
IL No. 6 11.8
IL No. 6 9.4
IL No. 6 8.7
IL No. 6 4.3
IL. No. 6 11.4
IL. No 6 9.5
Sample Description/Source Reference
PDU fuel oil mode, 91
atmospheric still overhead
PDU, fuel oil mode, vacuum 91
still overhead
PDU, fuel oil mode, 91
atmospheric still bottoms
PDU, fuel oil mode, vacuum 91
still bottoms
PDU, syncrude mode, vacuum 91
still bottoms
PDU, blend of atmospheric 144
still overhead and bottoms
PDU, atmospheric still 84
bottoms
PDU, syncrude mode, 151
atmospheric still overhead,
DOE Sample No. 1308
PDU, syncrude mode, 151
atmospheric still bottoms,
DOE Sample No. 1309
PDU, syncrude mode, vacuum 151
still overhead, DOE Sample
No. 1310
PDU, syncrude mode, vacuum 151
still bottoms, DOE Sample
No. 1311
PDU, fuel oil mode, 151
atmospheric still overhead,
DOE Sample No. 1312
PDU, fuel oil mode, 151
atmospheric still bottoms,
DOE Sample No. 1313
(Continued)
403
-------
Material
Coal
liquid
inter-
mediates
Table 211 (Concluded)
Process Coal Type
H-Coal IL No. 6
IL No. 6
Value
(Wt %)
8.7
4.7
Sample Description/Source Reference
151
PDU, fuel oil mode, vacuum
still overhead, DOE Sample
No. 1314
PDU, fuel oil mode, vacuum
still bottoms, DOE Sample
No. 1315
151
Explanatory Notes:
*See General Comments section, Note 2, for summary of operating conditions used.
'''Periods 3AB, 118 and 20AB are considered representative periods for the entire
PDU Run 8, which consisted of over 32 individual periods.
fSee General Comments section, Note 3, for summary of operating conditions used.
§Periods 6AS, 12AB, 18AB, 23AB and 28AB are considered representative periods for
the entire PDU Run 9, which consisted of over 30 individual periods.
404
-------
Table 212. Trace Element Content (ppmw)
Coal
Material Process Type H Hi H P_i V. £b E^. £. Sample Description/Source Reference
Coal SRC-I NA <1.0 0.64 0.07 0.38 0.1 0.06 2.3 <0.2 Wilsonville pilot plant, 84
liquid process solvent
inter-
mediates NA <0.1 0.70 0.12 1.0 0.1 0.2 13.0 0.2 Wilsonville pilot plant, 84
wash solvent
NA 5.01 0.38 <0.1 <9 0.19 NA 107 NA Ft. Lewis pilot plant, 106
process solvent
NA <0.9 0.42 0.08 <6 <0.01 NA 7.59 NA Ft. Lewis pilot plant, 106
wash solvent
NA NA 1.7+ NA NA NA NA 14 +_ I NA Ft. Lewis pilot plant, 146
o 0.03 process solvent
EDS NA 0.07 12.0 1.2 2.6 0.02 0.3 3.1 1.8 One tpd pilot plant, 84
hydrogenated recycle
solvent
H-Coal NA <0.1 1.90 1.5 0.36 0.12 0.42 58.0 <0.01 PDU, atmospheric still 84
bottoms
(Continued)
-------
Table 212 (Continued)
Coal
Coal SRC-I
liquid
inter-
mediates
EDS
H-Coal
ype
NA
NA
NA
NA
NA
NA
NA
Al
NA
NA
1.30
<0.2
NA
NA
NA
Cl
NA
NA
66.8
89.3
NA
NA
NA
Mn
NA
NA
1.23
0.11
NA
NA
NA
As
NA
NA
0.38
0.015
0.013+
0.001
NA
NA
Sb
NA
NA
0.0068
<2.0
<0.002
NA
NA
Se
NA
NA
0.019
0.017
<0.008
NA
NA
Ha
NA
NA
<0.0001
0.00566
0.07+
0.01*
NA
NA
Sample Description/Source
Wilsonville pilot plant,
process solvent
Wilsonville pilot plant,
wash solvent
Ft. Lewis pilot plant,
process solvent
Ft. Lewis pilot plant,
wash solvent
Ft. Lewis pilot plant,
process solvent
One tpd pilot plant,
hydrogenated recycle
solvent
PDU, atmospheric still
bottoms
Refer*
84
84
106
106
146
84
84
(Continued)
-------
Table 212 (Continued)
Coal
Material
Coal
liquid
inter-
mediates
0
Process Type
SRC- I NA
NA
NA
NA
NA
EDS NA
Br
NA
NA
0.52
0.011
0.018+
0.002
NA
N1
NA
NA
<0,4
<0.2
NA
NA
Co
NA
NA
0.037
0.015
0.0026+
0.0005
NA
Cr
NA
NA
4.51
0.020
0.044+
0.009
NA
Rb
NA
NA
<0.07
NA
<0.05
NA
Cs
NA
NA
0.00371
0.00543
<0.001
NA
H-Coal NA
NA
NA
NA
NA
NA
NA
Sample Description/Source Reference
Wilsonville pilot plant, 84
process solvent
Wilsonville pilot plant, 84
wash solvent
Ft. Lewis pilot plant, 106
process solvent
Ft. Lewis pilot plant, 106
wash solvent
Ft. Lewis pilot plant, 146
process solvent
One tpd pilot plant, 84
hydrogenated recycle
solvent
PDU, atmospheric still 84
bottoms
(Continued)
-------
Table 212 (Continued)
Coal
Coal SRC-I
liquid
Inter-
mediates
o
00
EDS
ype
NA
NA
NA
NA
NA
NA
Tb Eu Sm Ce La Sr Sample Description/Source
NA NA NA NA NA NA Wilsonville pilot plant,
process solvent
NA NA NA NA NA NA Wilsonville pilot plant,
wash solvent
<0.002 0.00200 0.00259 <0.01 0.00287 <0.6 Ft. Lewis pilot plant,
process solvent
<0.001 0.00231 <0. 00005 <0.009 <0.0007 <0.5 Ft. Lewis pilot plant,
wash solvent
<0.0002 <0.0001 0.0002 NA <0.001 NA Ft. Lewis pilot plant,
process solvent
NA NA NA NA NA NA One tpd pilot plant,
Refer*
84
84
106
106
146
84
hydrogenated recycle
solvent
H-Coal NA NA NA NA NA NA NA PDU, atmospheric still 84
bottoms
(Continued)
-------
Table 212 (Continued)
Coal
Material Process
Coal SRC- I
liquid
inter-
mediates
o
10 EDS
Type
NA
NA
NA
NA
NA
NA
Ba
NA
NA
<0.7
<0.6
-------
Table 212 (Concluded)
Coal
Material
Coal
liquid
Inter-
mediates
j
>
Process Type
SRC- I NA
NA
NA
NA
NA
EDS NA
Ga
NA
NA
0.017
<0.002
NA
NA
Zr
NA
NA
NA
0.24
NA
NA
Cu
NA
NA
0.28
0.00961
NA
NA
Zn
NA
NA
0.51
0.0!
0.0!
0.0-
NA
H-Coal
NA
NA
NA
NA
NA
Explanatory Notes:
*Determined by Flameless Atomic Absorption Analysis
^Determined by Neutron Activation Analysis
Sample Description/Source Reference
84
Wilsonville pilot plant,
process solvent
Wilsonville pilot plant,
wash solvent
Ft. Lewis pilot plant,
process solvent
Ft. Lewis pilot plant,
wash solvent
0.058+^ Ft. Lewis pilot plant,
process solvent
One tpd pilot plant,
hydrogenated recycle
solvent
PDU, atmospheric still
bottoms
84
106
146
146
84
84
-------
Table 213. Ash Content (by Ultimate Analysis)
Material Process Coal Type
Coal
liquid
inter-
mediates
SRC-1
EDS
NA
NA
NA
NA
H-Coal NA
IL No. 6
(Burning
Star Mine)
Value
(Wt *)
<0.01
<0.01
0.0
0.001
0.01
0.0067
Sample Description/Source Reference
Wilsonville pilot plant, 84
process solvent
Wilsonville pilot plant, 84
wash solvent
One tpd pilot plant, 84
hydrogenated recycle
solvent
One tpd pilot plant, 84
hydrogenated recycle
solvent, reprocessed to
remove 650°F+ fraction
PDU, atmospheric still 84
bottoms
POU, blend of atmospheric 144
still overhead and bottoms
411
-------
Table 214 Saturates, Oleflns and Aromatlcs Contents
Material
Coal
liquid
inter-
mediates
Process
EOS
Coal Type
IL No. 6
Compound
Class
Naphthenes
Aromatics
-Volatile
Polars
Value
(wt %)
1.42
81.71
16.87
H-Coal
Wyodak
IL No. 6
IL No. 6
(Burning
Star Mine)
IL No. 6
(Monterey
Mine)
Total 100.00
Naphthenes 0.32
Aromatics
-Volatile 65.33
-Non-Volatile 12.20
Polars 22.15
Total 100.00
Saturates 10.0
Aromatics 90.0
Saturates 12.08
Olefins 2.10
Aromatics 12.18
Saturates 14.73
Olefins 1.24
Aromatics 10.93
Sample Description/Source Reference
One tpd pilot plant,
vacuum gas oil
One tpd pilot plant,
vacuum gas oil
One tpd pilot plant,
process solvent
PDU, fuel oil mode,
blend of atmospheric still
overhead and vacuum still
overhead streams (analyzed
by BETC)*
PDU, syncrude mode, blend
of atmospheric still
overhead and vacuum still
overhead streams (analyzed
by BETC)*
99
99
99
97
97
Explanatory Notes
*See Part VIII, General Comments section, Note 3, for summary of operating conditions used.
-------
Table 215. Detailed Hydrocarbon Class Compound Analysis
Material
Coal
liquid
inter-
mediates
Process Coal Type
SRC-I NA
CO
Value
Compound (wt %)
Naphthalene 0.01.00
2-Methylnaphthalene 0.3800
1-Methylnaphthalene 0.0930
Dimethylnaphthalene 1.1200
Dimethylnaphthalene 0.1700
Dimethylnaphthalene 0.4200
Dimethylnaphthalene 0.0650
2-Isopropylnaphthalene 0.0050
1-Isopropylnaphthalene 0.1400
C/j-Naphthalene 0.0050
Biphenyl 0.5900
Acenaphthylene 0.3400
Dimethylbiphenyl 0.2100
Dimethylbiphenyl 0.0560
Fluorene 0.6600
9-Methylfluorene 0.3100
1-Methylfluorene 0.3000
Anthracene/phenanthrene 2.3000
Methylphenanthrene 0.6200
1-Methylphenanthrene 0.3900
C2-Anthracene 0.0500
Fluoranthene 1.0500
Dihydropyrene 0.1200
Sample Description/Source Reference
Ft. Lewis pilot plant,
process solvent
146
(Continued)
-------
Table 215 (Continued)
Material
Coal
liquid
inter-
mediates
Process Coal Type
SRC-I NA
Compound
Pyrene
-Undecane
-Dodecane
-Tridecane
-Tetradecane
-Pentadecane
-Hexadecane
-Heptadecane
-Octadecane
-Nonadecane
-Eicosane
-Heneicosane
-Docosane
-Tricosane
-Tetracosane
-Pentacosane
-Hexacosane
-Heptacosane
-Octacosane
-Nonacosane
-Triacontane
-Hentriacontane
-Dotriacontane
-Tritriacontane
Value
(wt %) Sample Description/Source Reference
1.1200
0.0050
0.0080
0.0030
0.0340
0.1000
0.2000
0.3100
0.0920
0.0800
0.0930
0.0600
0.0670
0.0980
0.0900
0.0740
0.0450
0.0300
0.0150
0.0090
0.0060
0.0040
0.0010
0.0005
Ft. Lewis pilot plant,
wash solvent
146
(Continued)
-------
Table 215 (Continued)
Material
Coal
liquid
inter-
mediates
Process Coal Type
SRC-I NA
01
Value
Compound (wt %)
Xylene 0.1300
-Ethyl benzene 0.1700
-Ethylbenzene 0.0700
C3-Benzene 0.1500
C4-Benzene 0.0500
Indan 1.3000
MethylIndan 0.2500
Methylindan 0.1400
Methylindan 0.2300
Dimethylindan 0.0040
Tetralin 0.4100
Dimethyltetralin 0.1500
6-Methyltetralin 0.3200
Naphthalene 3.2000
2-Methylnaphthalene 3.2000
1-Methylnaphthalene 1.2000
Dimethylnaphthalene 1.3000
Dimethylnaphthalene 0.0700
Dimethylnaphthalene 0.4000
Dimethylnaphthalene 0.0160
2-Isopropylnaphthalene 0.0040
1-Isopropylnaphthalene 0.0210
C^-Naphthalene 0.0005
Sample Description/Source Reference
Ft. Lewis pilot plant,
wash solvent
146
(Continued)
-------
Table 215 (Continued)
Material
Coal
liquid
inter-
mediates
Process Coal Type
SRC-I NA
.£>
0>
Value
Compound (wt %)
Cyclohexylbenzene 0.0410
Biphenyl 1.0000
Acenaphthylene 0.0500
Dimethylbiphenyl 0.0035
Dimethylbiphenyl 0.0030
Fluorene 0.0250
9-Methylfluorene 0.0110
1-Methylfluorene 0.0010
Anthracene/phenanthrene 0.0130
Methylphenanthrene 0.0015
C2-Anthracene 0.0025
Fluoranthene 0.0035
Dihydropyrene 0.0025
Pyrene 0.0040
-Octane 0.0900
-Nonane 0.2700
-Decane 0.5000
-Undecane 0.8300
-Dodecane 2.1000
-Tridecane 1.4000
-Tetradecane 1.1000
-Pentadecane 0.4000
-Hexadecane 0.0400
-Heptadecane 0.0120
-Octadecane 0.0040
-Nonadecane 0.0500
Sample Description/Source Reference
Ft. Lewis pilot plant,
wash solvent
146
-------
Table 215 (Concluded)
Material Protest Coal Type Compound
V«lue
Co«t
liquid
inter-
mediates
EDS
IL No. 6
Hyodak
H-Coal
IL No. 6
(Burning
Star Nine)
6.51
23.17
19.66
16.77
66.33
1.18
5.72
9.95
26.01
42.66
3.38
5.56
4.92
5.13
4.20
1.07
Sanple Description/Source Reference
One tpd pilot plant. 99
vacuun gas oil
Volatile Aromatics
1-Ring
2-Rlng
3-Ring
4*-R1ng
Total
Volatile Arcnatics
l-R1ng
2-R1ng
3-Rlng
4*-R1ng
Total
Paraffins
Monocyc1opa ra f f i ns
Dicycloparaffins
Alkylbenzenes
Monocycllc benzenes
(including indans
and tetralins)
Naphthalenes
Total
Paraffins
Honocyc1opa ra f f1ns
Dtcycloparafftns
Alkylbenzenes
Monocycllc benzenes
(Including indans
and tetralins)
Naphthalenes
Total
Explanatory Notes
•See Part VIII. General Comments section, Note 3. for summary of operating conditions used.
IL No. 6
(Monterey
Nine)
3.70
7.51
4.57
4.94
3.80
1.14
One tpd pilot plant. 99
yacuu> gas oil
PDU. fuel oil aode. blend 97
of atnospherlc still over-
head and vacuua still
overhead streans,
(analyzed by 8ETC)*
PDU, syncrude aode. blend 97
of atmospheric still over-
head and vacuua still
overhead streams,
(analyzed by BETC)*
-------
Table 216. Compound Class Analysis Obtained by Solvent Fractionation
Material
Coal
liquid
inter-
mediates
Process Coal Type
H-Coal IL No. 6
(Burning
Star
Mine)
IL No. 6
OO
IL No. 6
IL No. 6
KY No. 11
KY No. 11
KY No. 11
Compound Type
C Insolubles
Toluene soluble
Non-Ash Toluene
insoluble
Toluene soluble
Non-Ash Toluene
insoluble
Toluene soluble
Non-Ash Toluene
insoluble
Toluene soluble
Non-Ash Toluene
insoluble
Toluene soluble
Non-Ash Toluene
insoluble
Toluene soluble
Non-Ash Toluene
insoluble
Value
(wt %)
0.10
55.27
24.92
48.40
33.14
50.71
29.20
51.19
23.10
55.83
23.53
52.86
28.54
Sample Description/Source Reference
PDU, blend of atmospheric 144
still overhead and bottoms
PDU Run 8, Period 3A8, 155
fuel oil mode with low
catalyst age, vacuum
still bottoms*,'
PDU Run 8, Period 118, 155
fuel oil mode with high
catalyst age, vacuum
still bottoms*,'
PDU Run 8, Period 20AB, 155
intermediate mode with
high catalyst age,
vacuum still bottoms*/
PDU Run 9, Period 6AB, 156
syncrude mode, vacuum
still bottoms?,§
PDU Run 9, Period 12AB, 156
syncrude mode, vacuum
still bottoms!,§
PDU Run 9, Period 18AB, 156
syncrude mode, vacuum
still bottoms?,§
(Continued)
-------
VO
Material Process Coal Type
KY No. 11
Table 216 (Concluded)
Value
Compound Type
Toluene soluble
Non-Ash Toluene
Insoluble
(wt %) Sample Description/Source Reference
57.60 PDU Run 9, Period 23AB, 156
26.33 syncrude mode, vacuum
still bottoms?,*
Toluene soluble
Non-Ash Toluene
insoluble
54.66 PDU Run 9, Period 28AB,
25.24 syncrude mode, vacuum
156
KY No. 11
W««_flcK T/il..nno 9C 0/1 3J1H., uuc 111UUC,
still bottoms?,
Explanatory Notes
*See General Comments section, Note 2, for summary of operating conditions used.
"•"Periods 3AB, 11B and 20AB are considered representative periods for the entire PDU Run 8, which
consisted of over 32 individual periods.
fSee General Comments section, Note 3, for summary of operating conditions used.
^Periods 6AB, 12AB, 18AB, 23AB and 28AB are considered representative periods for the entire PDU
Run 9, which consisted of over 30 individual periods.
-------
Material
Coal
liquid
inter-
mediates
Table 217. Nitrogen-, Oxygen- and Sulfur-Containing Compounds
Compound
Process Coal Type
SRC-I NA
NA
ro
o
EDS
IL No. 6
Value
(wt %)
Dibenzofuran 0.5800
Xanthene 0.0840
Dibenzothiophene 0.4200
Methyldibenzothiophene 0.0320
Dimethyldibenzothio-
phene 0.1200
Thioxanthene 0.3300
Oibenzofuran 0.0400
Xanthene 0.0030
Dibenzothiophene 0.0050
Methyldibenzothiophene 0.0015
Dimethyldibenzothio-
phene 0.0015
Thioxanthene 0.0002
Volatile Aromatics
Thiophenes
1-Ring 0.36
2-Ring 0.65
3-Ring 0.14
4+-Ring 0.06
Total TTT
Furans
1-Ring 1.78
2-Ring 5.20
3-Ring 3.00
4+-Ring 2.14
Total T2TT7
Sample Description/Source Reference
Ft. Lewis pilot plant, 146
process solvent
Ft. Lewis pilot plant,
wash solvent
146
One tpd pilot plant,
vacuum gas oil
99
(Continued)
-------
Material
Coal
liquid
inter-
medi ates
Process Coal Type
Wyodak
ro
H-Coal
IL No. 6
(Burning
Star Mine)
IL No. 6
(Monterey
Mine)
Compound
Table 217 (Concluded)
Sample Description/Source Reference
Volatile Aromatics
Thiophenes
1-Ring
2-Ring
3-Ring
4+-Ring
Total
Furans
1-Ring
2-Ring
3-Ring
4+-Ring
Total
Pyridines
Anilines
Acids
Pyridines
Anilines
Acids
Value
(wt X)
0.05
0.26
0.30
0.46
0.93
5.96
6.84
7.67
0.07
0.31
7.94
0.04
0.25
5.01
One tpd pilot plant,
vacuum gas oil
99
PDU, fuel oil mode,
blend of atmospheric still
overhead and vacuum still
overhead streams (analyzed
by BETC)*
PDU, syncrude mode, blend
of atmospheric still
overhead and vacuum still
overhead streams (analyzed
by BETC)*
97
97
Explanatory Notes
*See Part VIII, General Comments section, Note 3, for summary of operating conditions used.
-------
Table 218. Compound Class Analysis Obtained by Solvent Fractionation (wt %)
Ether Ether
Coal Ether Soluble Insoluble Soluble Insoluble Neutral Neutral
Process Type VoTallies Insolubles Acids Acids Bases Bases Saturates Aromatics
Coal H-Coal NA 0.6 NA 0.4 NA 2.0 0.8 20.2 62.6
liquid
inter-
mediates
NA 0.2 NA 0.6 NA 2.5 0.4 10.2 63.7
NA NA 65.1 2.0 0.6 2.1 3.6 0.8 5.8
NA 34.7 NA 0.9 NA 1.1 0.5 11.9 24.6
ro
ro
NA 0.8 NA 0.6 0.1 2.1 NA 22.9 55.8
NA 0.3 NA 1.2 0.3 2.6 NA 13.9 58.5
NA NA 59.5 0.2 0.8 1.8 9.6 1.3 8.0
(Continued)
-------
Table 218 (Concluded)
Neutral
Poly- Neutral
Aromatics Polar Total
NJ
oo
20.0
0.5
6.9
18.4
<0.1
10.3 <0.1 96.9
22.8 <0.1 100.4
0.5 98.4
74.2
89.2
19.7 <0.1 96.5
0.3 99.9
Neutral Fraction
Experimental Summation Recovery Sample Description/Source Reference
97.1
97.6
28.9
54.9
94.1
95.1
27.7
93.1 95.9 PDU, syncrude mode, atmos- 136
pheric still bottoms, DOE
Sample No. 1309
96.7 99.1 PDU, syncrude mode, vacuum 136
still overhead, DOE Sample
No. 1310
27.1 94.0 PDU, syncrude mode, vacuum 136
still bottoms, DOE Sample
No. 1311
37.0 67.4 PDU, fuel oil mode, atmos- 136
pheric still overhead, DOE
Sample No. 1312
85.6 91.0 PDU, fuel oil mode, atmos- 136
pheric still bottoms, DOE
Sample No. 1313
92.1 96.8 PDU, fuel oil mode, vacuum 136
still overhead, DOE Sample
No. 1314
28.0 101.1 PDU, fuel oil mode, vacuum 136
still bottoms, DOE Sample
No. 1315
-------
Table 219. Asphaltene Composition11
-p.
ro
NtUrUl
CM|
liquid
Ut«r-
•MlUtM
dul
Proutf TUP*
N-Co4l M Molecular fflrwli
N>l*cvUr Mltkt
Hjr*
«*
<
fjlcirton ir»-
Mttclty,
rrullttl
"••rurt'w
*
'« • •*'•»
• • II «1« ll"ll fl}"0 «0
41
M
1*
0.74
0.11
O.Jt
t.4
l.i
tt.l
l.i
l.U
14.7
IHf-Clul
»V» 01
«96(
JO
40
10
0.6«
O.M
0.47
11.0
1.0
U.t
l.«
1.01
10.1
t.pUnitort ItoUi
'A<>r>j< (itrtfalitM lif l*lu dilution «)il*4 UfUlu OlutlM >«|IM wtivrM li INF.
tllKtrrtctii t»r pfeMlIc ON «l>torpHo
-------
Table 220. General Physical and Chemical Properties of
Various Distillation Fractions of Coal
Liquid Intermediates
Distilla-
Value
Material
Coal
liquid
inter-
mediates
H-Coal NA
-P.
ro
tion
Fraction
API Gravity
(degrees)
Pour point,
•F
Flash point,
°F
Gross heat
of combus-
tion,
Btu/lb
210-480°F
30.0
<-65.0
<75.0
18,723
300-500° F
30.4
<-65.0
12.0
18,810
Viscosity,
(Centistokes)
104° F
212'F
1.12
0.62
Conradson
Carbon
residue,
wt %
0.05
(Continued)
1.17
0.60
0.01
PDU, from atmospheric
still overhead
84
-------
Table 220 (Continued)
Matenal
Coal
liquid
inter-
mediates
INi
Distilla- Value
tion
Process Coal Type Fraction 210-480'F 300-500°F Sample Descripion/Source Reference
H-Coal W Distillation Data*
IBP 236°F
5 278°F
10 304" F
30 338 °F
50 374°F
70 401 °F
90 442°F
95 470°F
EP 505 °F
Distillation Simulated by
Chromatography*
IBP 171
5 208
10 257
30 328
50 369
70 402
90 447
95 467
EP 550
PDU, from atmospheric 84
still overhead
220 °F
262 °F
280 "F
333°F
368* F
398° F
440°F
462 °F
485 °F
179
214
247
332
376
411
457
479
537
(Continued)
-------
Table 220 (Continued)
Material
Coal
liquid
inter-
mediates
Distilla-
tion
Process Coal Type Fraction
H-Coal NA
ro
IL No. 6
IL No. 6
Ash Content,
(by ultimate
analysis)
wt % <0.01
Distillation
Fraction IBP-400'F
Value
210-480'F 300-500^ Sample Descripion/Source Reference
84
API Gravity
(degrees)
38.2
Distillation
Fraction IBP-400°F
API Gravity
(degrees)
39.8
<0.01
400'F
19.4
400eF
18.2
PDU, from atmospheric
still overhead
PDU Run 8, Period 3AB,
fuel oil mode with
low catalyst age,
atmospheric still
overhead?,
PDU Run 8, Period 11B,
fuel oil mode with
high catalyst age,
atmospheric still
overhead^,*
155
155
(Continued)
-------
Table 220 (Continued)
Material
Coal
liquid
inter-
mediates
Distillation
Process Coal Type Fraction IBP-650°F 650°F+
H-Coal IL No. 6 API Gravity
(degrees)
35.6
IL No. 6
IL No. 6
Distillation
Fraction IBP-650°F
API Gravity
(degrees)
11.2
Distillation
Fraction IBP-650°F
API Gravity
(degrees)
11.3
19.0
650°F+
1.6
650°F+
2.3
Sample Descripion/Source Reference
PDU Run 8, Period 20AB, 155
intermediate mode with
high catalyst age,
atmospheric still
overhead^
PDU Run 8, Period 3AB, 155
fuel oil mode with
low catalyst age,
atmospheric still
bottomst,§
PDU Run 8, Period 11B, 155
fuel oil mode with
high catalyst age,
atmospheric still
bottomst,§
(Continued)
-------
Table 220 (Continued)
Distilla-
Value
ro
vo
Material
Coal
liquid
inter-
mediates
*
>
*
tion
Process Coal Type Fraction IBP-650°F
H-Coal IL No. 6 API Gravity 13.5
(degrees)
IL No. 6 API Gravity 8.7
(degrees)
Distillation
Fraction IBP-650°F
IL No. 6 API Gravity 8.4
(degees)
650°F+ Sample Descripion/Source
4.7 PDU Run 8, Period 20AB,
intermediate mode
with high catalyst
age, atmospheric
still bottoms?,*
0.1 PDU Run 8, Period 3AB,
fuel oil mode with
low catalyst age,
vacuum still
overhead*,*
650°F+
0.5 PDU Run 8, Period 11B,
fuel oil mode with
Reference
155
155
155
high catalyst age,
vacuum still
overhead*,
(Continued)
-------
Table 220 (Continued)
Distilla-
tion
Value
Material
Coal
liquid
inter-
mediates
Process Coal Type Fraction IBP-650°F
H-Coal IL No. 6 API Gravity 11.1
(degrees)
Distillation
Fraction IBP-975°F+
IL No. 6 API Gravity -5.7
(degrees)
IL No. 6 API Gravity -8.5
(degrees)
650QF+ Sample Descripion/Source
4.7 PDU Run 8, Period 20AB,
intermediate mode
with high catalyst
age, vacuum still
overhead!, §
PDU Run 8, Period 3AB,
fuel oil mode with
low catalyst age,
vacuum still
bottomsf,§
PDU Run 8, Period 11B,
fuel oil mode with
high catalyst age,
vacuum Still
bottoms? .§
Reference
155
155
155
(Continued)
-------
Table 220 (Continued)
Material
Distilla-
tion
Process Coal Type Fraction
Value
IBP-650'F
Distillation
Fraction IBP-400'F
KY No. 11 API Gravity
(degrees)
40.8
CO
KY No. 11 API Gravity
(degrees)
40.5
Coal
liquid
inter-
mediates
H-Coal IL No. 6 API Gravity -3.7
(degrees)
NA
4000F
22.8
Distillation
Fraction IBP-400°F 400"F+
22.0
Sample Descripion/Source Reference
PDU Run 8, Period 20AB,
intermediate mode with
high catalyst age,
vacuum $till
bottoms?,*
PDU Run 9, Period 6AB,
syncrude mode, atmos-
pheric still
overhead*,**
PDU Run 9, Period 12AB,
syncrude mode, atmos-
pheric still
overhead*,**
155
156
156
(Continued)
-------
Table 220 (Continued)
Material
Coal
liquid
inter-
mediates
Distilla-
tion
Process Coal^ Type Fraction
Value
IBP-650eF 650'FH
H-Coal KY No. 11 API Gravity
(degrees)
39.5
ro
KY No. 11 API Gravity
(degrees)
38.2
Distillation
Fraction IBP-400°F
KY No. 11 API Gravity
(degrees)
42.1
21.6
Distillation
Fraction IBP-400"F 400'F"1
20.1
400 °F
20.3
Sample Descripion/Source Reference
PDU Run 9, Period 18AB,
syncrude mode, atmos-
pheric still
overhead*,**
PDU Run 9, Period 23AB,
syncrude mode, atmos-
pheric still
overhead*,**
PDU Run 9, Period 28AB,
syncrude mode, atmos-
pheric still
overhead*,**
156
156
156
(Continued)
-------
Table 220 (Continued)
Material
Coal
liquid
inter-
mediates
Distilla-
tion
Process Coal Type Fraction
Value
IBP-650°F
H-Coal
co
CO
KY No. 11 API Gravity
(degrees)
13.9
Distillation
Fraction IBP-650°F
KY No. 11 API Gravity
(degrees)
13.4
Distillation
Fraction IBP-650°F
KY No. 11 API Gravity
(degrees)
13.5
650°F+
3.6
1.8
650°F+
3.1
Sample Descripion/Source Reference
PDU Run 9, Period 6AB, 156
syncrude mode, atmos-
pheric still
bottoms*,**
PDU Run 9, Period 12AB,
syncrude mode, atmos-
pheric still
bottoms*,**
PDU Run 9, Period 18AB,
syncrude mode, atmos-
pheric still
bottoms*,**
156
156
(Continued)
-------
Table 220 (Continued)
Material
Coal
liquid
inter-
mediates
Distilla-
tion
Process Coal Type Fraction
Value
IBP-650°F
H-Coal
OJ
KY No. 11 API Gravity
(degrees)
12.6
Distillation
Fraction IBP-650°F
KY No. 11 API Gravity
(degrees)
14.4
Distillation
Fraction IBP-650°F
KY No. 11 API Gravity
(degrees)
12.3
650°F+
2.3
650°F+
1.8
650°F*
0.1
Sample Descripion/Source Reference
PDU Run 9, Period 23AB, 156
syncrude mode, atmos-
pheric still
bottoms*,**
PDU Run 9, Period 28AB,
syncrude mode, atmos-
pheric still
bottoms*,**
PDU Run 9, Period 6AB,
syncrude mode,vacuum
still overhead*,**
156
156
(Continued)
-------
Table 220 (Continued)
Material
Coal
liquid
Inter-
mediates
Distilla-
tion
Process Coal Type Fraction
Value
IBP-650°F 650°F+ Sample Descripion/Source Reference
H-Coal
to
tn
KY No. 11 API Gravity
(degrees)
11.0
Distillation
Fraction IBP-650°F
KY No. 11 API Gravity 10.6
(degrees)
KY No. 11 API Gravity 7.9
(degrees)
KY No. 11 API Gravity 11.0
(degrees)
-0.8
650°F+
-1.2
Distillation
Fraction IBP-650°F 650°F+
-0.9
Distillation
Fraction IBP-650°F 650°F+
-0.8
PDU Run 9, Period 12AB,
syncrude mode, vacuum
still overhead*,**
PDU Run 9, Period 18AB,
syncrude mode, vacuum
still overhead*,**
PDU Run 9, Period 23AB,
syncrude mode, vacuum
still overhead*,**
PDU Run 9, Period 12AB,
syncrude mode, vacuum
still overhead*,**
156
156
156
156
(Continued)
-------
Table 220 (Continued)
Material
Coal
liquid
inter-
mediates
Distilla-
tion
Process Coal Type Fraction
Value
KY No. 11 API Gravity
(degrees)
-9.6
Distillation
Fraction IBP-975'F
KY No. 11 API Gravity
(degrees)
-9.8
IBP-65Q'F 65Q'F+ Sample Descripion/Source Reference
H-Coal KY No. 11 API Gravity -6.5 NA
(degrees)
Distillation
Fraction IBP-975'F
NA
NA
Distillation
Fraction IBP-975aF
KY No. 11 API Gravity -10.2 NA
(degrees)
PDU Run 9, Period 6AB,
syncrude mode^ vacuum
still bottoms*,**
PDU Run 9, Period 12AB,
syncrude mode, vacuum
still bottoms
PDU Run 9, Period 23AB,
syncrude mode, vacuum
still bottoms
PDU Run 9, Period 28AB,
syncrude mode, vacuum
still bottoms
156
156
156
156
(Continued)
-------
Table 220 (Continued)
Material
Coal
liquid
Inter-
mediates
CO
Process Coal Type
H-Coal IL No. 6
Distillation
Fraction
No.
1 (Stage 1,
760 mm Hg)
2
3
4
5
6
7
8
9
10
11 (Stage 2,
40 mm Hg)
12
13
14
15
Residuum
Cut
Temp
°F
122
167
212
257
302
347
392
437
482
527
392
437
482
527
572
Specific
Gravity
60/60°F
NA
NA
0.760
.783
.818
.874
.919
.939
.947
.964
1.001
1.030
1.071
NA
NA
1.140
"API
60°F
NA
NA
54.7
49.2
41.5
30.4
22.5
19.2
17.9
15.3
9.9
5.9
.6
NA
NA
NA
Refractive
Index
n0 at 20°C
NA
NA
1.41756
1.43517
1.45236
1.47633
1.47155
NA
NA
NA
NA
NA
NA
NA
NA
NA
Sample Description/Source Referenon
PDU, fuel oil mode, blend
of atmospheric still
overhead and vacuum still
overhead
97
(Continued)
-------
Table 220 (Concluded)
Material
Coal
liquid
inter-
mediates
P»
jj
»
Distillation
Fraction
Process Coal Type No.
H-Coal IL No. 6 1 (Stage 1,
760 mm Hg)
2
3
4
5
6
7
8
9
10
11 (Stage 2,
40 mm Hg)
12
13
14
15
Residuum
Cut
Temp
°F
122
167
212
257
302
347
392
437
482
527
392
437
482
527
572
Specific
Gravity
60/60°F
NA
NA
0.744
.775
.811
.865
.911
.936
.955
.973
1.001
1.045
1.063
1.087
1.112
1.158
NA
NA
58
51
43
32
23
19
16
13
9
3
1
NA
NA
NA
"API
60°F
.7
.1
.0
.1
.8
.7
.7
.9
.9
.9
.6
Refractive
Index
n0 at 20"C
NA
NA
1.41259
1.42667
1.44643
1.47238
1.49868
1.51897
NA
NA
NA
NA
NA
NA
NA
NA
Sample Description/Source Reference
PDU, syncrude mode, blend 97
of atmospheric still
overhead and vacuum still
overhead
Explanatory Notes
*Determined via ASTM D-86.
"•"Determined via ASTM D-2887.
fSee General Comments section, Note 2, for summary of operating conditions used.
§Periods 3AB, 11B and 20AB are considered representative periods for the entire PDU Run 8, which consisted of over
32 individual periods.
*See General Comments section, Note 3, for summary of operating conditions used.
**Periods 6AB, 12AB, 18AB, 23AB and 28AB are considered representative periods for the entire PDU Run 9, which consisted
of over 30 individual periods.
-------
Table 221. Elemental Composition of Various Distillation Fractions of Coal Liquid Intermediates
Material
Coal
liquid
inter-
mediates
Process Coal Type
H-Coal NA
CO
VO
IL No. 6
Value
Distillation
Fraction
H, wt%
S, wt %
N, wt %
0, wt %
Trace Metals
T1
Na
K
Ca
V
Pb
Fe
P
Distillation
Fraction
S, wt %
210-480'F
11.38
0.13
0.16
1.4
(ppm)
<1.0
0.43
0.06
0.15
0.9
0.02
0.7
<0.2
IBP-400T
0.09
300- 500 "F
11.19
0.16
0.16
1.1
<2.0
1.1
0.15
0.16
<0.1
0.04
1.0
<0.1
400" F+
0.27
Distillation
Fraction IBP-400"F 400°F+
Sample Description/Source Reference
PDU, from atmospheric
still overhead
84
PDU, Run 8, Period 3AB,
fuel oil mode with low
catalyst age, atmos-
pheric still
overhead*,'
155
IL No. 6 S, wt %
0.24
0.32 PDU, Run 8, Period 11B,
fuel oil mode with
high catalyst age,
atmospheric stil1
overhead*,t
155
(Continued)
-------
Material
Coal
liquid
inter-
mediates
Distillation
Process Coal Type Fraction
H-Coal IL No. 6 S, wt %
Table 221 (Continued)
Value
_L
Sample Description/Source Reference
155
IBP-400°F 400°Fn
0.24
Distillation
Fraction IBP-400°F
KY No. 11 S, wt %
<0.03
Distillation
Fraction IBP-400°F
KY No. 11 S, wt %
0.13
Distillation
Fraction IBP-400°F
KY No. 11 S, wt %
0.07
0.13
400°F+
<0.03
400°F+
<0.03
400°F+
0.08
PDU, Run 8, Period 20AB,
intermediate mode with
high catalyst age,
atmospheric still
overhead*,*
PDU, Run 9, Period 6AB,
syncrude mode, atmos-
pheric still
overhead^
PDU, Run 9, Period 12AB,
syncrude mode, atmos-
pheric still
overheadt,§
PDU, Run 9, Period 18AB,
syncrude mode, atmos-
pheric still
overheadt,§
156
156
156
(Continued)
-------
Distillation
Material Process Coal Type Fraction IBP-400°F
Table 221 (Concluded)
Value
Sample Description/Source Reference
400°F
or+
Coal H-Coal KY No. 11 S, wt %
liquid
Inter-
mediates
0.20 0.11 PDU, Run 9, Period 23AB,
syncrude mode, atmos-
pheric still
overheadt,§
156
Distillation
Fraction IBP-400°F
KY No. 11 S, wt
0.13
400°F+
0.11
PDU, Run 9, Period 28AB,
syncrude mode, atmos-
pheric still
overheadt,§
156
Explanatory Notes
*See General Comments section, Note 2, for summary of operating conditions used.
^Periods 3AB, 11B and 20AB are considered representative periods for the entire PDU Run 8, which consisted
of over 32 individual periods.
fSee General Comments section, Note 3, for summary of operating conditions used.
§Periods 6AB, 12AB, 18AB, 23AB and 28AB are considered representative periods for the entire PDU Run 9,
which consisted of over 30 individual periods.
-------
Table 222. Detailed Hydrocarbon and Heterocyclic-Compound Analysis for Various
Distillation Fractions of Coal Liquid Intermediates
ro
MtUrlil
Coil
liquid
Utir-
•*dtil*i
CCGC-HS
SCM
Proctn Coil Typ« Ho.*
MC-I M 171
244
Ml
Mi
M4
11*
11*
411
Ul
ill
132
641
170
iM
120
M4
Ul
MO
172
7M
7M
7U
7ii
7M
711
7M
124
Mi
IM
M7
177
IM
MS
IfllUI
KlpktkilM*
2-Ntllwl-l.t.l.4-tttrjrliU|iktkiliM
i-lioprapylMpktkilMt
OlbtnnfurM
PutldlCMt
W-fluiir*M
4-Nitk>|.|.l'.klpk*iwl
SM KM 7SO
MUllwI.l.prwlMi.ktk.lm
A dlMtkylklpkMyl
H*»d«CIM
4-NithyldlbiMafurM
C|*Alfcylbfpkiayl
l.lO-OlkydrMAtkriciiw
t. 10-OlkydroplwMiitkriM
A Mthyl-M-fluoraM
JM ICM MI
A butylMtkylnipktkitiM
HiptidiciM
CoMinti Suiili Oficrlpllon/Sourti »«r«r«nct
Plui 2.i-dlMtkylpkiMl (or polllbly lutkor liOMr) yllionvlll. pilot plint. 14*
proem Mlvint
Or i-Mtkyl IIOMF
Nijar lout It I/I • IM. Ill (1001). IM. Md 107
PaiilBly M •tkyiwtkjlMpktkiliM
rlui N.M. IM
SM MM iM
Or pcrlupktkiliM («ol lit 1U)
Plui < Mtkylblphinyl (IM ICM 7SO) Md 1
Mthyl-M-riuorinl (N.W. IM)
Polllbly a Mtkylp*rtupktkilini
Ponlbljr llphniyl-4-MrUiildikyai
Plui i Ci-ilkylblpkmyl (in Htl it ICM 784)
Hut i CflUylblplwityl
Plui • Cj-ilkylblpkinyl
(Contlnuld)
-------
Table 222 (Concluded)
co
tutorial
Coal
liquid
lotor-
•tdlatot
CCGC-HS
Scan
Procoti Coal Tyoo Ho.*
SIC-I «A 922
101*
1022
104i
1071
1077
111*
1214
1M1
1)99
1014
1071
10*7
1141
11(1
1177
1224
1270
1211
ms
1MJ
1)94
1400
UM
1U2
1S72
1«S)
It**
17)1
1M7
iaao
lisa
2019
2US
21SO
Valuo
CoMMiMd CoMonti 1 Sanplo Oascrlptlon/Sourco Itftrenc,
_=3= — |
Poulkly * Cz-aUyl»lpkonyl Soo «oto at icao 7M. Hllionnlllo pilot plant, 149
.. i • ^ M u. •!>< '"" *zo- •••»> dlitll-
Nlituro Includol H.Wt. IW ,„, cu, ({U-aSO*F) Irm
Pkonanlkroiw procoti tol«ont
Octadocano
9M-C«rt)«lolo
Nliturt Includol H.Kt. 19* and 210
A Mtkylpkonantkr***
Su lean 1071
•Madocaa*
flcoiano
HttwlcwaM
Oecotano
9H-Carkai«lo
A Ht«ylpl»nHtnroM
Soo icon 1071
2-Pkony1napktkal«M
An otnjrlpnooantkr«M
Soo KIO 11(1
FluorantkoM
Pyrono
1-PkonylnapktkaloM
A o*tkjrlpyrono Huttly a MtkyltluoranthM* or a kouolluoroH
Soo uan IMS
Soo comnont N.W. 21(. Ponlkly a o»tkylpktnylntpktnalooo
Docaiano
Irlcottno PUi N.tt. 2)0. Ponlkly a dlMtnylpyroM
Ckryiono
Totracotono Ponlbly anotkor M.«. 221 polynucloar aroHtlc
Hydrocarbon
PontacoiaM
A Mtkyl>o«i[alantkricono Poiiloly anotnor N.HI. 242 lio«r
Hniacoiano
Hoptacoiano
Nonacoiano
Trtacontano
Htnlrlacontano
Dotrlacontano
Trltrlacoatano
t»Blin«tory llottt
•OittralMd v!« ctpllliry colun oti ckraHto«r»pl\y ind Mti tp*ctro«try (CCSC-H5).
-------
Table 223. Nitrogen-Containing Compounds in Various Distillation Fractions
of Coal Liquid Intermediates*
COAl
Niter 111 Proem lyp«
Coil FAD SIC-I M
htAvy
dliltllAta
And
rctlduA
C«rbM
C}
C«
CJ
Cl
^2
t)
q
Ci
Cj
cj
Ci
cj
Cj
Ci
c«
Cj
q
Cj
£2
CA
c,
£»
q
Ci
Cj
Ci
ej
£4
£&
q
c,
cj
c)
q
C|
Cooound
Anlllnt
An II In.
talnolndAn
talnolndAn
AjilnOAAphtllAlBM
talnanlphthAlen*
talnanAphlhAliM
A*lnoniphthAl*ni
talnoaiabUiAlwi*
telnablphmyl
Ajilnoblphcnyl
Aalnoblpnenyl
talnoblphtnyl
talnoblph.nyl
A«lnof luorcn.
Ajilaaf luorent
telnof luorcnt
Anlnof luor«n«
Aalnofluar.M
AilnophtnintlirtM
ABlnophcoAiithrtM
AdnophcDAnkhrtM
A*lnophtAAntlir
-------
GENERAL COMMENTS
2.
Naphthalene, fluoranthene and pyrene have been identified via mass
spectrometry in raw SRC-I and SRC-II whole process liquids. The SRC-I
liquid was derived from a 50 Ib/day PDU and KY No. 9 coal. The SRC-II
liquid was derived from the Ft. Lewis pilot plant (ORNL Sample No.
RCS-UFO-13) and Pittsburgh No. 8 coal (Reference 139).
Data cited for Reference 155 for H-Coal PDU Run 8 pertain to the
following operating conditions:
Catalyst
Period
American Cyanamid HDS 1442A, 1/16" Extrudates (HRI 3830)
3AB 11AB 20AB
Operating Conditions
Hours of Run - Beginning
End
Catalyst Age (End Average) Lb Dry Coal/Lb
Catalyst Added, Cumulative*
Lbs/Ton Dry Coal
Coal Feed (Dry), Lb/Hr/Cu.ft. Reactor Volume
Average Reactor Temperature, °F
Unit Back Pressure (Unit BP), psig
H2 Partial Pressure, psia
Oil/Solid Ratio (Slurry Tank), Lb/Lb Solids
H2 Inlet Rate, MSCF/Ton Dry Coal
Recycle Gas, MSCF/Ton Dry Coal
Catalyst Inventory, End, Lbs
Catalyst Added, Lbs
Catalyst Withdrawn, Lbs *
Catalyst Age (End), Lb Dry Coal/Lb
Average (Basis)
Original Charge (Basis)
Catalyst Added, Cumulative*
Lbs/Ton Dry Coal
Catalyst Withdrawals
Withdrawal, Oil Laden, Lbs
Oi 1, Wt %
Molybdenum (Oil Free), Wt %*
Coal Feed (Dry)
Lbs/Hr/Cu Ft Reactor Volume
Moisture Wt % (Coal Sample)
Ash, Wt % (Dry Coal)
Recycle Flows, Lbs/Lb Solids
Atmospheric Still Bottoms
Vacuum Still Overhead
Inventory Change
Hydroclone Overflow (Oil)
Make-up Oil
TOTAL
445
28.00
52.00
274.2
.54
74.69
846.
2688.
1726.
1.92
36.56
21.60
50.81
3.94
4.28
274.2
288.4
190.00
202.00
867.6
1.00
77.51
849.
2584.
1756.
1.77
35.60
20.90
51.27
0.00
0.00
867.6
1193.0
378.00
402.00
1320.2
.63
49.25
850.
2631.
1874.
1.72
50.69
33.47
48.89
0.00
5.84
1320.2
2265.9
.54
8.53
31.21
7.26
.76
.35
.05
.86
0.00
1.92
1.00
0.00
.52
.33
-.05
.88
0.00
1.77
.63
10.86
23.24
6.97
74.69
3.60
10.84
77.51
4.48
10.87
49.25
2.02
10.87
.34
.31
-.01
1.04
.02
1.72
-------
Temperature, °F
Coal Preheater Outlet
Reactor Liquid Phase, Avg.
Max.
Separator-2" (@ 12" Skin)
Hydroclone Overflow
Vacuum Still Flash Zone
Pressure
Unit Back Pressure, psig
Hydrogen Make-up, psig
Hydrogen Partial Pressure, psia
(Reactor Outlet - Separator)
Vacuum Flash, Torr
Recycle Gas, MSCF/Ton Dry Coal
Vent Gas, MSCF/Ton Dry Coal
Hydrogen Purity
of Recycle Gas and Vent, %
Total H2, MSCF/Ton Dry Coal
(Reactor Outlet)
Hydrogen, Make-up + Recycle
MSCF/Ton Dry Coal
Partial Pressure, psia (Inlet)
Hydrogen Consumption (1)
MSCF/Ton Dry Coal
Wt % Dry Coal
Oil Additions
Make-up Oil, Lbs/Lb Dry Coal
Lbs/Hr/Cu Ft Reactor
Flush Oil, Lbs/Lb Dry Coal
734. 788.
846. 849.
860. 857.
829. 829.
499. 506.
521. 514.
36.56
2614.
12.26
3.26
0.00
0.00
.002
35.60
2562.
11.44
3.04
0.00
0.00
.002
798.
850.
856.
800.
468.
534.
2688.
2815.
1726.
4.
21.60
4,39
85.99
24.29
2584.
2727.
1756.
3.
20.90
3.89
88.06
24.16
2631.
2738.
1874.
2.
33.47
6.07
88.35
36.88
50.69
2557.
13.81
3.67
.02
.94
.004
Explanatory Notes
*10.30 wt % molybdenum is fresh catalyst
^Catalyst addition rate was changed at the beginning of Period 19. The cumulative
total was set to zero at the beginning of Period 19.
446
-------
3. Data cited for Reference 156 for H-Coal PDU Run 9 pertain to the
following operating conditions:
Catalyst
Period
American Cyanamid HDS 1442A, 1/16" Extrudates (HRI 3830)
6AB 12AB 18AB 23AB
Operating Conditions
Hours of Run - Beginning
End
Catalyst Age (End Average),
Lb Dry Coal/Lb
Catalyst Added, Cumulative
Lbs/Ton Dry Coal
Coal Feed (Dry), Lb/Hr/Cu.ft.
Reactor Volume
Average Reactor Temperature,
Unit Back Pressure (Unit BP),
H2 Partial Pressure, psig
Oil/Solid Ratio (Slurry Tank)
Lb/Lb Solids
H2 Inlet Rate, MSCF/Ton Dry Coal
Recycle Gas, MSCF/Ton Dry Coal
Catalyst Inventory, End, Lbs
Catalyst Added, Lbs
Catalyst Withdrawn, Lbs *
Catalyst Age (End), Lb Dry Coal/Lb
Average (Basis)
Original Charge (Basis)
Catalyst Added, Cumulative
Lbs/Ton Dry Coal
Catalyst Withdrawals
Withdrawal, Oil Laden, Lbs
Oil, Wt %
Molybdenum (Oil Free), Wt %*
Coal Feed (Dry)
Lbs/Hr/Cu Ft Reactor Volume
Moisture Wt % (Coal Sample)
Ash, Wt % (Dry Coal)
Recycle Flows, Lbs/Lb Solids
Atmospheric Still Bottoms
Vacuum Still Overhead
Inventory Change
Hydroclone Overflow (Oil)
Make-up Oil
TOTAL
28AB
119.00
143.00
282.0
1.20
31.84
°F 848.
psig 2703.
1725.
1.70
loal 57.92
il 37.70
102.40
7.15
5.16
lal/Lb
282.0
315.3
1.20
10.90
30.39
;* 7.01
i 31.84
1.69
9.42
.24
.23
-.01
1.22
0.00
1.70
263.00
287.00
548.6
1.10
32.18
850.
2696.
1862.
1.71
56.22
36.40
103.47
3.57
3.43
548.6
653.2
1.10
7.29
32.86
7.22
32.18
1.44
8.28
.29
.25
-.02
1.19
0.00
1.71
407.00
431.00
769.8
1.05
31.32
851.
2684.
1751.
1.67
55.00
37.00
106.61
4.50
3.48
769.8
974.1
1.05
7.37
26.55
6.63
31.32
1.64
8.65
.39
.22
.05
1.11
0.00
1.67
527.00
551.00
906.0
1.07
31.51
849.
2681.
1787.
1.74
54.28
37.41
108.93
2.10
1.98
906.0
1236.1
1.07
4.22
24.49
6.40
31.51
1.71
6.88
.26
.27
-.12
1.21
0.00
1.74
647.00
671.00
999.7
1.12
31.88
850.
2701.
1765.
1.66
55.31
36.82
110.50
3.90
3.14
999.7
1493.3
1.12
7.55
34.40
6.53
31.88
1.57
7.40
.33
.12
-.02
1.19
0.00
1.66
447
-------
Temperature, °F
Coal Preheater Outlet
Reactor Liquid Phase, Avg.
Max.
Separator-2" (9 12" Skin)
Hydroclone Overflow
Vacuum Still Flash Zone
Pressure
Unit Back Pressure, psig
Hydrogen Make-up, psig
Hydrogen Partial Pressure, psia
(Reactor Outlet - Separator)
Vacuum Flash, Torr
Recycle Gas, MSCF/Ton Dry Coal
Vent Gas, MSCF/Ton Dry Coal
Hydrogen Purity
of Recycle Gas and Vent, %
Total H2, MSCF/Ton Dry Coal
(Reactor Outlet)
Hydrogen, Make-up + Recycle
MSCF/Ton Dry Coal
Partial Pressure, psia (Inlet)
Hydrogen Consumption (1)
MSCF/Ton Dry Coal
Wt % Dry Coal
Chemical Hydrogen Consumption
MSCF/Ton Dry Coal
Oil Additions
Make-up Oil, Lbs/Lb Dry Coal
Lbs/Hr/Cu Ft Reactor
Flush Oil, Lbs/Lb Dry Coal
708.
848.
853.
804.
502.
531.
2703.
2882.
1874.
4.
37.70
5.94
84.65
38.89
57.92
2635.
19.03
5.05
18.23
0.00
0.00
.003
719
850.
854.
805.
502.
543.
2696.
2901.
1915.
2.
36.40
6.09
85.05
38.57
56.22
2659.
17.66
4.69
17.26
0.00
0.00
.003
741.
851.
854.
783.
500.
541.
2684.
2888.
1854.
2.
37.00
6.33
83.11
37.95
55.00
2607.
17.05
4.53
16.68
0.00
0.00
.003
751.
849.
854.
767.
496.
543.
2681.
2933.
1897.
1.
37.41
6.53
84.01
38.64
54.28
2655.
15.64
4.15
16.21
0.00
0.00
.003
773.
850.
856.
770.
489.
544.
2701.
2939.
1849.
1.
36.82
6.73
83.30
38.00
55.31
2658.
17.30
4.59
15.79
0.00
0.00
.003
Explanatory Notes
*10.30 wt % molybdenum is fresh catalyst
448
-------
4. The following benzo(a)pyrene concentrations have been determined in H-Coal
intermediates derived from the H-Coal PDU (Reference 161):
DOE Mode of Concentration
Sample No. Intermediate Operation (Mg/g)
1308 atmospheric still overhead syncrude 0.3
1309 atmospheric still bottoms syncrude 115+8
1310 vacuum still overhead syncrude 451
1311 vacuum still bottoms syncrude 233+14
1312 atmospheric still overhead fuel oil 5
1313 atmospheric still bottoms fuel oil 37
1314 vacuum separator overhead fuel oil 260
1315 vacuum still bottoms fuel oil 142
5. The following nitrogen-containing compound types have been identified
in a basic chromatographic fraction of SRC-I process solvent from the
SRC-I Ft. Lewis pilot plant (Reference 159): quinolines, benzoquino-
lines, azapyrenes, aminonaphthalenes, aminoanthracenes, amino-
phenanthrene, and aminopyrenes.
6. The following 2-aminonaphthalene concentrations have been determined in
H-Coal intermediates derived from the H-Coal PDU, syncrude mode (Refer-
ence 160): atmospheric still overhead (DOE Sample No. 1308), 18+7 ug/g;
atmospheric still bottoms (DOE Sample No. 1309), 13+2 ug/g; vacuum
still overhead (DOE Sample No. 1310), 18+_5 ug/g; and vacuum still
bottoms (DOE Sample No. 1311), 5+2 ug/g.
7. The following values (wt %) were obtained for SRC-I process solvent
from the Wilsonville pilot plant using alumina column chromatography
(Reference 127):
Distillation Fraction 600-650°F 650-700°F 7,00-750°F 750-800°F 800-850°F
Aliphatic hydrocarbons 40 +_ 7 35 + 11 26 +_ 15 19 +_ 10 5 +_ 5
Nitrogen-containing
polycyclic aromatic
compounds 9 + 6 19 +_ 9 21 +_ 8 22 +_ 8 35 +_ 7
Neutral polycyclic
aromatic hydrocarbons 32 +_ 6 30 _+ 8 31 +_ 5 30 +_ 5 20 _+ 3
Hydroxy polycyclic
aromatic hydrocarbons 6 +_ 6 9 ± 5 10 _+ 8 14 +_ 4 25 +_ 3
449
-------
Part VIII. NAPHTHAS
450
-------
Material
Coal raw
naphtha
Table
Process Coal Type
SRC-I KY No. 9 0.8408*
224. Specific Gravity
Value Sample Description/Source Reference
82
KY No. 9 0.8338*
KY No. 9 0.7958*
SRC- I I
EDS
KY No. 9
and 14
Powhattan
No. 5
IL No. 6
(Monterey
Mine)
0.934
0.7809*
0.8328f
IL No. 6 0.8275
IL No. 6 0.8258
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
0.83
0.01
0.83 +
0.01
Wilsonville pilot plant,
SRC unit (Run No. 220,
APCI Sample No. 1896CB)
Wilsonville pilot plant, 82
SRC unit, (Run No. 225,
APCI Sample No. 1910CB)
Wilsonville pilot plant, 82
SRC unit, sample washed
with caustic prior to
analysis, (Run No. 220,
APCI Sample No. 1933CB)
Ft. Lewis pilot plant1" 83
Ft. Lewis pilot plant 85
(UOP Sample No. 3777-1)
One tpd pilot plant; 87
once-through mode
(UOP Sample No. 3531-7)
One tpd pilot plant; 90
once-through mode
(SWRI Sample No. G-C2)
One tpd pilot plant, from 99
"typical" run (Run A-7)
One tpd pilot plant; 99
average of three operating
conditions (840°F reactor
temperature; 15-40
minutes residence time)
One tpd pilot plant; 99
operating conditions:
840°F reactor temperature,
40 minutes residence
time, average of ten
yield periods
(Continued)
451
-------
Table 224 (Continued)
Material
Coal raw
naphtha
Process Coal Type Value Sample Description/Source Reference
EDS
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
Wyodak
Wyodak
Wyodak
Wyodak
Wyodak
Wyodak
0.82
0.01
0.82
0.00
0.8150
0.8438
0.82 +
0.01 ~
0.81
0.01
0.82 +
0.02~
0.82
0.00
75 Ib per day development 99
unit; average of six
operating conditions
(800-880°F reactor
temperature; 25-100
minutes residence time)
75 Ib per day development 99
unit; operating condi-
tions: 840°F reactor
temperature, 40 minutes
residence time; average of
21 yield periods
One tpd pilot plant, from 99
"typical" run (Run A-7)
One tpd pilot plant, once- 90
through mode (SWRI
Sample No. G-C3)
One tpd pilot plant; 99
average of six operating
conditions (800-840°F
reactor temperature,
40-100 minutes residence
time)
One tpd pilot plant; 99
operating conditions:
840°F reactor temperature,
60 minutes residence
time; average of seven
yield periods
75 Ib per day development 99
unit; average of eight
operating conditions
(800-880°F reactor
temperature; 25-100
minutes residence time)
75 Ib per day development 99
unit; operating conditions:
880°F reactor temperature,
25 minutes residence time;
average of 6 yield
periods
(Continued)
452
-------
Material
Coal raw
naphtha
Table 224 (Continued)
Process Coal Type Value Sample Description/Source Reference
H-Coal
IL No. 6 0.8076f
IL No. 6
(Burning
Star Mine)
0.864
Hydro-
treated
coal
naphtha
SRC-II
IL No. 6 0.838
(Monterey
Mine)
Powhattan 0.771111
No. 5
EDS
IL No. 6 0.8058f
(Monterey
Mine)
H-Coal IL No. 6 0.7936f
(Continued)
453
PDU, syncrude mode; rerun 92
naphtha (UOP Sample No.
3531-1-2)
Derived from PDU atmos- 97
pheric still overhead and
vacuum still overhead
streams, fuel oil mode
(analyzed by BETC)§
Derived from PDU atmos- 97
pheric still overhead and
vacuum still overhead
streams, syncrude mode
(analyzed by BETC)§
Bench-scale continuous 85
hydrotreating of UOP coal
raw naphtha Sample No.
3777-1 (UOP Sample No.
3777-2, UOP Research
Plant 505, Run 874)
Bench-scale continuous 87
hydrotreating of UOP
Sample No. 3531-7 coal
raw naphtha, moderate
severity hydrotreatment
(UOP Sample No. 3531-12,
UOP Research Plant 629,
Run 218); operating condi-
tions: LHSV/LHSV base ,
0.125 P-P (base), 450
psig, T-T (base), 33°C
Bench-scale continuous 92
hydrotreating of UOP coal
raw naphtha Sample
No. 3531-1-2 moderate
severity hydrotreatment
(UOP Sample No. 3531-4,
UOP Research Plant 629,
Run 215). Operating
conditions: LHSV/LHSV,
0.125; P-P (base),
450 psig
-------
Table 224 (Continued)
Material
Coal-
derived
gasoline
Process Coal Type Value Sample Description/Source Reference
SRC-11
Powhattan
No. 5
EDS
IL No. 6
(Monterey
Mine)
0.8090
(Period
1)M
0.8151
(Period 2)
0.8109
(Period
0.8299
(Period 5)
0.8123
(Period 6)
0.8576
(Period
4)
Bench-scale continuous
platforming of hydro-
treated coal naphtha
Sample No. 3777-2 (UOP
Research Plant 636, Run
335)**
85
0.8504
Bench-scale continuous
platforming of moderate
hydrotreated coal
naphtha Sample No. 3531-12
87
(Period 2) (UOP Research Plant 508,
0.8483
(Period 3)
0.8443
(Period 4)
0.8393
(Period 5)
0.7475
(Period 6)
0.8363
(Period 7)
0.8529
(Period 8)
0.8623
(Period 9)
0.8735
(Period
10)
Run 1456)
TT
(Continued)
454
-------
Table 224 (Concluded)
Material
Coal
derived
gasoline
Process Coal Type Value Sample Description/Source Reference
H-Coal IL No. 6
0.8448 From bench-scale contin-
(Period uous platforming of
l)f,# moderately hydrotreated
0.8483 coal naphtha Sample No.
(Period 2) 3531-4 (UOP Research Plant
0.8458 636, Run No. 220)ft
(Period 4)
0.8403
(Period 5)
0.8418
(Period 6)
0.8373
(Period 7)
0.8358
(Period 8)
0.8338
(Period
10)
0.8565
(Period
14)
92
Explanatory Notes
*Determined via ASTM D-1298
'''See General Comments Section, Note 2, for summary of operating
conditions used.
^Measured at 60°F
§See General Comments Section, Note 3, for summary of operating
conditions used.
#Each period refers to a run time having a characteristic set of
operating conditions.
**See General Comments Section, Note 4, for summary of operating
conditions used.
General Comments Section, Note 5, for summary of operating
conditions used.
ffSee General Comments Section, Note 6, for summary of operating
conditions used.
455
-------
Table 225. API Gravity
Material
Coal raw
naphtha
Value
Process Coal Type (degrees) Sample Description/Source Reference
SRC-I
SRC-II
EDS
KY No. 9 36. 8*.
KY No. 9 38.2*'*
NA
KY No. 9
43.0
46.3
Powhattan 49.7'
No. 5
KY No. 9 36.2
and 14,
IL No. 6
(River
King Mine)
and
Pitt-
Seams WV
(Blackville
No. 2 Mine)
IL No. 6 38.4t
(Monterey
Mine)
IL No. 6 39.5
IL No. 6 39.9
IL No. 6 39.8
(Monterey
Mine)
Wilsonville pilot plant,
SRC unit (Run No. 220,
APCI Sample No. 1896CB)
Wilsonville pilot plant,
SRC unit (Run No. 225,
APCI Sample No. 1910CB)
Wilsonville pilot plant
Wilsonville pilot plant,
sample washed with
caustic prior to analysis
(Run No. 220, APCI Sample
No. 1933CB)
Ft. Lewis pilot plant
(UOP Sample No. 3777-1)
Ft. Lewis pilot plant
(Chevron Sample No. WOW
3750)
One tpd pilot plant,
once-through mode (UOP
Sample No. 3531-7)
One tpd pilot plant;
once-through mode (SWRI
Sample No. G-C2)
One tpd pilot plant, from
"typical" run (Run A-7)
One tpd pilot plant;
operating conditions:
840°F reactor temperature,
40 minutes residence time,
1500 psi reactor pressure;
average of yield period
Nos. 256-265
82
82
84
82
85
86
87
90
99
99
(Continued)
456.
-------
Table 225 (Continued)
Material
Coal raw
naphtha
Process Coal Type
EDS
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
Value
(degrees)
38.87 +
1.61
39.85
1.99
42.0
45.1
41.17
3.32
41.26 +
2.07 ~
Sample Description/Source Reference
One tpd pilot plant; 99
average of three operating
conditions (840°F reactor
temperature; 15-40
minutes residence time)
One tpd pilot plant; 99
operating conditions:
840°F reactor temperature,
40 minutes residence time;
average of ten yield
periods
One tpd pilot plant; 99
operating conditions:
840°F reactor temperature,
25 minutes residence time;
average of yield period
Nos. 225-231
One tpd pilot plant, 99
sample washed with
caustic prior to analysis;
operating conditions:
840°F reactor temperature,
25 minutes residence time;
average of yield period
Nos. 225-231
75 Ib per day development 99
unit; average of six
operating conditions
(800-880°F reactor
temperature, 25-100
minutes residence time)
75 Ib per day development 99
unit; operating conditions:
840°F reactor temperature,
40 minutes residence time;
average of 21 yield
periods
(Continued)
457
-------
Table 225 (Continued)
Material
Coal raw
naphtha
Value
Process Coal Type (degrees) Sample Description/Source Reference
EDS Wyodak 42.1 One tpd pilot plant, from 99
"typical" run (Run A-7)
Wyodak 36.2 One tpd pilot plant, 90
once-through mode (SWRI
Sample No. 6-C3)
Wyodak 39.91 +_ One tpd pilot plant; 99
2.08 average of six operating
conditions (800-840'F
reactor temperature,
40-100 minutes residence
time)
Wyodak 42.17 _+ One tpd pilot plant; 99
1.83 operating conditions:
840°F reactor temperature,
60 minutes residence
time; average of seven
yield periods
Wyodak 43.0 One tpd pilot plant; 99
operating conditions:
840°F reactor temperature,
60 minutes residence
time; 1500 psi reactor
pressure; average of
yield period Nos. 267-270
Wyodak 38.0 One tpd pilot plant; 99
operating conditions:
840°F reactor temperature,
25, 40 and 60 minutes
residence times; average
of yield period Nos.
237, 244 and 249
Wyodak 40.8 One tpd pilot plant, 99
sample washed with
caustic prior to analysis;
operating conditions:
840"F reactor temperature;
25, 40 and 60 minutes
residence times; average
of yield period Nos. 237,
244 and 249
(Continued)
458
-------
Table 225 (Continued)
Material
Coal raw
naphtha
Value
Process Coal Type (degrees)
EDS
Wyodak
42.02 +
2.47 ~"
Wyodak 42.01 +
0.60
H-Coal IL No. 6 43.71"
IL No. 6 40.6
(Burning
Star
Mine)
IL No. 6 32.3
(Burning
Star
Mine)
IL No. 6 37.4
(Monterey
Mine)
IL No. 6
Wyodak
W. KY
No. 11
35.0
43.9
42.8
Sample Description/Source Reference
75 Ib per day development
unit; average of eight
operating conditions
(800-880'F reactor
temperature, 25-100
minutes residence time)
75 Ib per day development
unit; operating conditions
8808F reactor temperature,
25 minutes residence
time; average of six
yield periods
PDU, syncrude mode, rerun
naphtha (UOP Sample No.
3531-1-2)
PDU (Ashland Oil sample)
Derived from PDU atmos-
pheric still overhead and
vacuum still overhead
streams, fuel oil mode
(analyzed by BETC)f
Derived from PDU atmos-
pheric still overhead and
vacuum still overhead
streams, syncrude mode
(analyzed by BETC)t
PDU, syncrude mode
PDU, syncrude mode
PDU, syncrude mode
99
99
92
96
97
97
109
109
109
(Continued)
459
-------
Table 225 (Continued)
Material
Hydro-
treated
coal
naphtha
Process Coal Type
SRC-II
Powhattan
No. 5
Value
(degrees)
52. Qt
KY No. 9
and 14,
IL No. 6,
(River
King Mine)
and Pitt-
Seam WV
(Black-
ville No.
2 Mine)
KY No. 9
and 14,
IL No. 6
(River
King Mine)
and Pitt-
Seam WV
(Black-
ville No.
2 Mine)
KY No. 9
and 14,
IL No. 6
(River
King Mine)
and Pitt-
Seams WV
(Black-
Ville No.
2 Mine)
46.9,
45.8
41.6
42.2,
41.8
Sample Description/Source Reference
Bench-scale continuous
hydrotreating of UOP
coal raw naphtha,
Sample No. 3777-1 (UOP
Sample No. 3777-2, UOP
Research Plant 505, Run
874)
Ft. Lewis pilot plant,
Chevron coal raw naphtha
Sample No. WOW 3750
hydrotreated with ICR
113 catalyst (Run No.
65-194, Run Hours 111-
135 and 231-255,
respectively)§
Ft. Lewis pilot plant,
Chevron coal raw naphtha
Sample No. SGQ 6502
partially hydrotreated
with ICR 113 catalyst
(Run No. 72-326)
Ft. Lewis pilot plant,
Chevron coal raw naphtha
Sample No. SGQ 6502
partially hydrotreated
and hydrofined with ICR
113 catalyst (Run No.
72-326, Run Hours 138-150
and 222-246, respectively)*
85
86
86
86
(Continued)
460
-------
Table 225 (Continued)
Material
Hydro-
treated
coal
naphtha
Process Coal Type
Value
(degrees)
EDS IL No. 6 44.lt
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
47.3
IL No. 6
(Monterey
Mine)
47.1
Wyodak
43.7
Wyodak
42.8
Sample Description/Source Reference
Bench-scale continuous 87
hydrotreating of UOP coal
raw naphtha Sample No.
3531-7, moderate severity
hydrotreatment (UOP
Sample No. 3531-12, UOP
Research Plant 629, Run
218); operating conditons:
LHSV/LHSV (base), 0.125,
P-P (base), 450 psig, T-T
(base), 33°C
From minimum severity 99
hydrotreatment in six-
train, fixed bed pilot
unit, operating condi-
tions: 238°F, reactor
temperature (T-Tref),
treat gas rate, 120% of
ref. value
From minimum severity 99
hydrotreatment of caustic-
washed sample in six-train,
fixed bed pilot unit;
operating conditions:
238°F reactor temperature
(T-Tref), treat gas
rate, 120% of ref. value
From minimum severity 99
.hydrotreatment in six-
train, fixed bed pilot
unit; operating condi-
tions: 238°F reactor
temperature (T-Tref),
treat gas rate, 120% of
ref. value
From minimum severity 99
hydrotreatment of caustic-
washed sample in six-
train, fixed bed pilot
unit; operating condi-
tions: 238°F reactor
temperature (T-Tref),
treat gas rate, 120% of
ref. value
(Continued)
461
-------
Table 225 (Continued)
Material
Hydro-
treated
coal
naphtha
Process Coal Type
Value
(degrees)
Sample Description/Source Reference
H-Coal IL No. 6 46.8*
Bench-scale continuous
hydrotreating of UOP raw
coal naphtha Sample No.
3531-1-2, moderate
severity hydrotreatment,
(UOP Sample No. 3531-4,
UOP Research Plant
629, Run 215) operating
conditions: P-P (base),
450 psig, LHSV/LHSV
(base), 0.125
92
Coal -
de ri ved
gasoline
SRC-11
Powhattan 43.4
No. 5
EDS
IL No. 6
(Monterey
Mine)
33.5
(Period
i)t**
34.9
(Period 2)
35.3
(Period 3)
36.1
(Period 4)
37.1
(Period 5)
57.8
(Period 6)
37.7
(Period 7)
34.4
(Period 8)
32.6
(Period 9)
30.5
Period
10)
Bench-scale continuous
(Period platforming of hydfo-
l)t,** treated coal naphtha
42.1 Sample No. 3777-2 (UOP
(Period 2) Research Plant 636, Run
43.0 335)*t
(Period 4)
39.0
(Period 5)
42.7
(Period 6)
Bench-scale continuous
platforming of moderately
hydrotreated coal naphtha
Sample No. 3531-12 (UOP
Research Plant 508, Run
1456)tt
85
87
NA
43.9
(Continued)
462
NA
-------
Table 225 (Concluded)
Material
Coal-
derived
gasoline
Process
H-Coal
Coal Type
IL No. 6
Value
(degrees)
Sample Description/Source Reference
36.0
(Period
l)t,**
35.3
Bench-scale continuous 92
platforming of moder-
ately hydrotreated
coal naphtha Sample No.
(Period 2) 3531-4 (UOP Research
35.8 Plant 636, Run 220)§§
(Period 4)
36.9
(Period 5)
36.6
(Period 6)
37.5
(Period 7)
37.8
(Period 8)
38.2
(Period
10)
33.7
Period
14)
Explanatory Notes
*Determined via ASTM D-1298
"•"Measured at 60°F
fSee General Comments Section, Note 3, for summary of operating conditions used.
§See General Comments Section, Note 7, for summary of operating conditions used.
#See General Comments Section, Note 8, for summary of operating conditions used.
**Each period refers to a run time having a characteristic set of operating conditions
used.
General Comments Section, Note 4, for summary of operating conditions used.
ffSee General Comments Section, Note 5, for summary of operating conditions used.
§§See General Comments Section, Note 6, for summary of operating conditions used.
463
-------
Table 226. Density
Material
Coal raw
naphtha
Process Coal Type
SRC-11 IL No. 6
EDS
IL No. 6
NA
Value
(g/ml)
0.8529
(77°F)
0.87*
0.8242
(77°F)
Sample Description/Source Reference
Ft. Lewis pilot plant, 91
(DuPont "Notebook"
Sample No. 16928)
NA
One tpd pilot plant
(DuPont "Notebook"
Sample No. 16928)
89
91
Hydro-
treated
coal
naphtha
Coal-
de ri ved
gasoline
EDS
NA
IL No. 6
Explanatory Notes
*Excludes the Cg/158°F naphtha cut
0.80"
NA
89
464
-------
Table 227. Reid Vapor Pressure
Material
Coal raw
naphtha
Hydro-
treated
coal
naphtha
Coal -
derived
gasoline
Process Coal Type
SRC-I KY No. 9
KY No. 9
KY No. 9
EDS IL No. 6
Wyodak
H-Coal IL No. 6
Wyodak
W.KY
No. 11
NA
NA
Explanatory Notes
^Determined via ASTM D-323
Value Sample Description/Source Reference
3.6 Wilsonville pilot plant, 82
(psia)* SRC unit (Run No. 220,
APCI Sample No. 1896CB)
4.35 Wilsonville pilot plant,
(psia)* SRC unit (Run No. 225,
APCI Sample No. 1910CB)
1.75 Wilsonville pilot plant,
(psia)* SRC unit, sample washed
with caustic prior to
analysis (Run No. 220,
APCI Sample No. 1933CB)
3.3
(ps1)
2.8
(psi)
2.4
(psi)
2.5
(psi)
2.0
(psi)
One tpd pilot plant; once-
through mode (SWRI Sample
No. G-C2)
One tpd pilot plant; once-
through mode (SWRI Sample
No. G-C3)
PDU, syncrude mode
POU, syncrude mode
PDU, syncrude mode
82
82
90
90
109
109
109
465
-------
Table 228. Distillation Data
Material
Coal raw
naphtha
Process Coal Type
SRC-I KY No. 9
KY No. 9
Value
(% Evaporation)
•IBP*
•10
•15
•20
•30
•40
•50
•60
•70
•80
•90
•EP
•IBP*
•10
•15
•20
•30
40
•50
•60
•70
80
•90
EP
Sample Description/Source Referenc
180'F-
NA •
217°F-
237°F-
260°F-
286°F-
308°F-
326'F-
344°F-
360'F-
380°F-
116'F-
169'F-
185°F-
218°F-
2468F-
268eF-
288°F-
306'F-
332'F-
352°F-
365'F-
389°F-
Wilsonville pilot plant,
SRC unit (Run No. 220,
APCI Sample No. 1896CB)
82
Wilsonville pilot plant,
SRC unit (Run No. 225,
APCI Sample No. 1910CB)
82
(Continued)
466
-------
Table 228 (Continued)
Material
Coal raw
naphtha
Process Coal Type
SRC-I
Value
(% Evaporation)
SRC-II
NA
KY No. 9
KY No. 9
and 14
Powhattan
No. 5
118aF-IBP*
158°F-5
182°F-10
228°F-30
266°F-50
305 'F- 70
357°F-90
NA -95
425eF-EP
136'F-IBP*
196'F-IO
NA -15
218°F-20
238°F-30
257*F-40
279*F-50
303°F-60
324eF-70
345°F-80
364 'F- 90
399°F-EP
166°F-IBP
344*F-50
500°F-EP
107°F-IBP*
134'F-5
157°F-10
188'F-20
2098F-30
226°F-40
243°F-50
261°F-60
279°F-70
292'F-80
316°F-90
346eF-95.
367°F-EP§
Sample Description/Source Reference
Wilsonville pilot plant 84
Wilsonville pilot plant,
SRC unit, sample washed
with caustic prior to
analysis (Run No. 220,
APCI Sample No. 1933CB)
82
Ft. Lewis pilot plantf
Ft. Lewis pilot plant
(UOP Sample No. 3777-1)
83
85
(Continued)
467
-------
Table 228 (Continued)
Material
Coal raw
naphtha
Process Coal Type
Value
(% Evaporation)
SRC-II KY No. 9
and 14,
IL No. 6
(River
King
Mine)
and Pitt-
Seams WV
(Blackville
No. 2 Mine)
EDS IL No. 6
(Monterey
Mine)
IL No. 6
151/179°F-
IBP/5*
197/249°F-
10/30
290°F-50
332/336°F-
70/90
380/393°F-
95/EP#
142°F-IBP*
178°F-10
208° F- 15
244°F-20
268°F-30
286°F-40
302°F-50
316°F-60
319°F-70
339°F-80
348° F- 90
ND -95
380°F-EP
125°F-5
305°F-50
389°F-95
Sample Description/Source Referenc
Ft. Lewis pilot plant
(Chevron Sample No.
WOW 3750)
86
One tpd pilot plant,
once-through mode (UOP
Sample No. 3531-7)
87
One tpd pilot plant, from
"typical" run (Run A-7)
99
IL No. 6
IL No. 6
223°F-10**
356°F-50
390°F-90
127°F-IBP
201°F-10
239°F-20
298°F-50
347°F-90
369°F-EP#
(Continued)
NA
One tpd pilot plant,
once-through mode
(SWRI Sample No. G-C2)
89
90
468
-------
Table 228 (Continued)
Material
Coal raw
naphtha
Process Coal Type
EDS
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
Wyodak
Wyodak
Value
(% Evaporation)
160/200°F-
IBP/5*
212/233°F-
10/20
253/272°F-
30/40
284/300°F-
50/60
314/328°F-
70/80
340/350°F-
90/95
382-EP
148/192°F-
IBP/5*
212/233°F-
10/20
248/265°F-
30/40
278/295°F-
50/60
312/325°F-
70/80
340/350°F-
90/95
410°-EP
129°F-IBP
207°F-10
250°F-20
320°F-50
365°F-90
388°F-EPtt
101°F-5
286°F-50
378°F-95
(Continued)
Sample Description/Source Reference
One tpd pilot plant;
operating conditions:
840°F reactor tempera-
ture, 25 minutes residence
time; average of yield
period Nos. 225-231
99
One tpd pilot plant,
sample washed with
caustic prior to
analysis; operating
conditions: 840°F
reactor temperature,
25 minutes residence
time; average of yield
period Nos. 225-231
One tpd pilot plant,
once-through mode
(SWRI Sample No. G-C3)
One tpd pilot plant, from
"typical" run (Run A-7)
99
90
99
469
-------
Table 228 (Continued)
Material
Coal raw
naphtha
Process Coal Type
Wyodak
Wyodak
H-Coal IL No. 6
Value
(% Evaporation)
147/200°F-
IBP/5*
212/245'F-
10/20
270/288°F-
30/40
312/328'F-
50/60
342/351'F-
70/80
362/372 °F-
90/95
411'F-EP
138/190'F
IBP/5*
211/238
10/20
262/284
30/40
304/322
50/60
340/356
70/80
371/389°
90/95
450'F-EP
F-
F-
F-
F-
F-
132°F-IBP
1708F-5
189°F-10
215°F-20
233eF-30
251'F-40
260*F-50
292°F-60
312°F-70
328°F-80
351'F-90
373°F-<
396°F-
Sample Description/Source Reference
One tpd pilot plant,
operating conditions:
840°F reactor tempera-
ture, 25, 40 and 60
minute residence times;
average of yield period
Nos. 237, 244 and 249
One tpd pilot plant,
sample washed with
caustic prior to
analysis; operating
conditions: 840°F
reactor temperature,
25, 40 and 60 minutes
residence times;
average of yield period
Nos. 237, 244 and 249
POD; syncrude mode;
rerun naphtha (UOP
Sample No. 3531-1-2)
99
99
92
(Continued)
470
-------
Table 228 (Continued)
Value
Material Process Coal Type (% Evaporation) Sample Description/Source Reference
Coal raw
naphtha
H-Coal
Hydro-
treated
coal
naphtha
SRC-1
IL No. 6
(Burning
Star Mine)
IL No. 6
KY No. 9
196'F-IBP
215'F-5
228°F-10
250*F-20
270eF-30
292"F-40
312°F-50
332°F-60
350'F-70
366°F-80
380*F-90
394 'F- 95
142'F-IBP*
192°F-5
217'F-10
241'F-20
282°F-30
2918F-40
318°F-50
339°F-60
355°F-70
369°F-80
384°F-90
3938F-95
402'F-EP
187°F-IBP*
219°F-10
NA -15
227°F-20
234°F-30
NA -40
252°F-50
NA -60
311'F-70
336eF-80
3648F-90
413°F-EP
PDU (Ashland Oil sample)
96
PDU, syncrude mode
109
Wilsonville pilot plant
(APCI Sample No. 1934CB)
82
(Continued)
471
-------
Material
Hydro-
treated
coal
naphtha
Table 228 (Continued)
Value
Process Coal Type (% Evaporation)
SRC-II Powhattan 136°F-IBP*
No. 5 168°F-5
180°F-10
196°F-20
209°F-30
220°F-40
233°F-50
249°F-60
270°F-70
289°F-80
311°F-90
330°F-95
388°F-EP§§
KY No. 9 166/188;
and 14, 175/198°F-
IL No. 6, IBP/5*
(River King 200/240;
Mine) and 205/236°F-
Pitt-Seams 10/30
WV 260/261°F-
(Blackville 50
No. 2 Mine) 297/356;
306/366°F-
70/90
385/428;
389/420°F-
95/EP
KY No. 9 200/216°F-
and 14, IBP/5*
IL No. 6, 228/255°F-
(River King 10/30
Mine) and 286-50
Pitt-Seams 321/364-
WV 70/90
(Blackville 382/408-
No. 2 Mine) 95/EP
KY No. 9 206/214°F-
and 14, IBP/5*
IL No. 6, 231/258°F-
(River King 10/30
Mine) and 290-50
Pitt-Seams 327/370-
WV 70/90
(Blackville 384/415-
No. 2 Mine) 95/EP##
(Continued)
472
Sample Description/Source
Bench-scale continuous
hydrotreating of UOP coal
raw naphtha Sample No.
3777-1 UOP Sample No.
3777-2 (UOP Research
Plant 505, Run 874)
Ft. Lewis pilot plant,
Chevron coal raw naphtha
Sample No. WOW 3750
hydrotreated with ICR 113
catalyst (Run No. 65-194,
Run Hours 111-135 and 231-
255, respectively)
Ft. Lewis pilot plant,
Chevron coal raw naphtha
Sample No. SGQ 6502
partially hydrotreated
with ICR 113 catalyst
(Run No. 72-326)
Ft. Lewis pilot plant
Chevron coal raw naphtha
Sample No. SGQ 6502
partially hydrotreated
and hydrofined with ICR
113 catalyst (Run No.
72-326, Run Hours 222-
246)***
Reference
85
86
86
86
-------
Table 228 (Continued^
Material
Hydro-
treated
coal
naphtha
Process Coal Type
EDS
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
Value
(% Evaporation)
202°F-
215°F-
226°F-
237°F-
250°F-
264°F-
287°F-
305°F-
322°F-
336°F-
351°F-
360°F-
374°F-
IBP*
5
10
20
30
40
50
60
70
80
90
95
EP
144/203°F-
IBP/5*
210/225°F-
10/20
238/253°F-
30/40
268/289°F-
50/60
306/322°F-
70/80
338/352°F-
90/95
157/204°F-
IBP/5*
214/233°F-
10/20
246/262°F-
30/40
278/293°F-
50/60
309/324°F-
70/80
341/350°F-
90/95
198°F-10
315°F-50
360°F-90
(Continued)
Sample Description/Source Reference
Bench-scale continuous
hydrotreating of UOP coal
raw naphtha Sample No.
3531-7, moderate severity
hydrotreatment (UOP Sample
No. 3531-12, UOP Research
Plant 629, Run 218)
operating conditions:
LHSV/LHSV (base), 0.125,
P-P(base), 450 psig,
T-T(base), 33°C
From minimum severity
hydrotreatment in six-
train, fixed bed pilot
unit; operating condi-
tions: 238°F reactor
temperature (T-Tref),
treat gas rate, 120%
of ref. value
87
From minimum severity
hydrotreatment of caustic
washed sample in six-
train, fixed bed pilot
unit; operating condi-
tions: 238°F reactor
temperature (T-Tref),
treat gas rate, 120%
of ref. value
99
99
NA
89
473
-------
Material
Hydro-
treated
coal
naphtha
Table 228 (Continued)
Value
Process Coal Type (% Evaporation) Sample Description/Source Reference
EDS
Wyodak
Wyodak
H-Coal IL No. 6
148-192°F-
IBP/5*
205/221°F-
10/20
246/266°F-
30/40
289/313°F-
50/60
333/350°F-
70/80
364/371°F-
90/95
161/212°F-
IBP/5*
226/247°F-
10/20
268/287°F-
30/40
306/329°F-
50/60
343/357°F-
70/80
371/389°F-
90/95
153°F-
185°F-
199°F-
217°F-
231°F-
246°F-
263°F-
284°F-
306°F-
329°F-
352°F-
367°F-
393°F-
(Continued)
IBP*
5
10
20
30
40
50
60
70
80
90
95
From minimum severity
hydrotreatment in six-
train, fixed bed pilot
unit; operating condi-
tions: 238°F reactor
temperature (T-Tref),
treat gas rate, 120%
of ref. value
From minimun severity
hydrotreatment of caustic
washed sample in six-
train, fixed bed pilot
unit; operating condi-
tions: 238°F reactor
temperature (T-Tref),
treat gas rate, 120%
of ref. value
Bench-scale continuous
hydrotreating of UOP
coal raw naphtha Sample
No. 3531-1-2, moderate
severity hydrotreatment
(UOP Sample No. 3531-4,
UOP Research Plant 629,
Run 215) operating
conditions: LHSV/LHSV,
0.125, P-P (base),
450 psig
99
99
92
474
-------
Table 228 (Continued)
Natartil
Coal-dtrl«td
gatollnt
Froctss Coal lypt
(ft Evaporation)
Saaolt Dttcrlptlon/Sourct Itftrtnct
SIC-II PoWtittan Ftflod I *.f Ftrlod 2 ».t Ftrlod 4 *.t Ftrlod 5 *.l Ftrlod t *.t
Ho. I
IK
IL No. »
(Monttrty
Hliw)
tn
H-Coal IL ft), t
atnch-scalt continuous
platforalnt, of hydro-
at
1S2'F-I8F
172'F-S
182'F-IO
212'F-3fl
244 'F -SO
280'F-70
322'F-90
343-F-9S
Wd'F-EF
Ftrlod 1 *.t
200'F-UF
215'F-S
227'F-IO
Ul'F-30
300'F-SO
339'F-70
17VF-90
402'F-U
441'F-Cr
Ftrlod * «,f
J90-F-IIP
209'F-S
220'F-IO
2S1'F-30
2aa*F-so
326'F-70
364 -F-M
380-F-95
407'F-f.F
Ftrlod 1 «.t
lil'F-IIF
taa'F-i
201'F-IO
238'F-30
272 'f -50
lll'F-70
X7'F-90
393*F-9S
442'F-EP
Ftrlod t «,l
16t'F-IIF
iaa'F-s
201'F-IO
237'F-30
274'F-SO
.1IO'F-70
3S8'F-90
397'F-9S
452'F-£F
isa' -IIF
173* -S
U3* -10
209' -30
247' -SO
282' -70
110' -90
3S9'F-9i
411'F-EP
Ftrlod 2 «,t
190'F-IIF
212'F-S
22f'F-IO
JWf-30
29CF-SO
334'F-70
172'F-90
387-F-9S
421'F-CF
Ftrlod 7 «,t
202'F-IIP
2H'F-S
22CF-10
26PF-30
29CF-50
lia'F-70
37S'F-<0
391'F-tt
4S2'F-t»
Ftrlod 2 «.t
156*F-laF
lai'F-s
200'F-IO
239'F-30
274'F-SO
31CF-70
370'F-90
19fF-)S
453'F-EF
Ftrlod 7 «.t
169'F-IIF
192'F-S
204*F-10
238'F-30
275'F-SO
312-F-70
36S'F-90
392'F-9S
435'F-EP
154-F-IIF
172'F-S
lU'F-10
212*F-30
24fF-SO
285'F-70
327-F-90
151'F-K
laO'F-EF
Ftrtod 1 *.t
197'F-iaF
216'F-S
228'F-IO
2WF-30
298' F- SO
138'F-TO
17S'F-90
3SO-F-9S
420'F-IF
Ftrlod 8 *.f
194'F-1IF
215'F-S
22CF-IO
257'F-IO
293'F-SO
132'F-70
370'F-90
38S'F-9S
419'F-EF
Ftrlod 4 M
1«5'F-IIF
191 'F-S
202'F-IO
240'F-SO
276'F-SO
3I8'F-70
370'F-90
19l'F-«5
444'F-CF
Ftrlod 8 *.»
UO'F-IIF
isa-F-s
20PF-10
237V-30
272'F-50
312-F-70
3£7'F-M>
387-F-9S
4JU'F-£P
ISO'F-IIF
171'F-S
tai'F-lo
212'F-30
24CF-50
284'F-70
329"f-90
348'F-K
UI'F-EF
Ptrlod 4 «,f
190'F-IIP
212'F-S
223'F-10
2U'F-30
290'F-SO
332-F-70
UI'F-90
M3'F-9S
410'F-EF
Ftrlod 9 «.t
198'F-HF
2J9'F-S
23I'F-IO
264'F-30
303'F-SO
143*F-70
3B8'F-90
409'F-M
4WF-EF
Ftrlod S M
1»4'F-I8F
190'F-S
204'F-IO
240'F-30
277'F-SO
321'F-70
172'F-90
39S'F-9S
425'F-EP
Period 10 • 1
169'F-UP
194'F-S
206'F-IO
239'F-30
27S'F-SO
3I7'F-70
366'F-90
384'F-9S
418'F-CF
151 'F- IIP
171'F-S
181'F-IO
211-F-30
245'F-SO
2837-70
12«'F-90
3SI'F-95
lai'F-EF
Ftrlod S «.t
198'F-IIF
2U'F-S
227'F-IO
2WF-30
298'F-SO
337'F-70
178-F-90
39.-F-96
43.-F-EP
Ftrlod 10 *.t
194'F-IIP
2l4'F-5
22t'F-IO
258'F-IO
294 'F -SO
13i'F-70
389'F-SO
40*'F-95
440'F-EF
Ftrlod 14 *.t
162' -IIP
188' -i
204* -10
241' -30
27f -50
317- -70
372' -90
394' -95
452'F-tF
trtattd coal naphtha
Stiplt No. 1777-2 (UOF
Itfta^ch Plant tit. lun
8tndi-sct1t continuous
platfonalnf of tudtr-
•ttly hydrotrtattd
coal naphtha Staple No.
3531-12, (UOF Itsttrck
Flanl 608. tun UM)|t|
8tnch-sctlt continuous
platfornlno. of aodtr-
tttly hydrotrttttd
coal naphtha S tip It Mo.
3S31-4. (UOF Itstarcb,
Fltnt tli. lun 220)!H
87
(Continued)
-------
Table 228 (Concluded)
Explanatory Notes
*Determined by ASTM D-86
'''Each period refers to a run time (usually less than 20 hours total time)
having a characteristic set of operating conditions.
fSee General Comments Section, Note 3, for summary of operating conditions used.
§97.5% recovered
#98% recovered, 1% residue, 1% loss
**Excludes the Cg/158°F naphtha cut
t1>98.5% recovered, 1% residue, 0.5% loss
f1r99% recovered
§§98.5% recovered
##99% recovered, 1% residue
***See General Comments Section, Note 8, for summary of operating conditions used.
tttsee General Comments Section, Note 4, for summary of operating conditions used.
fffSee General Comments Section, Note 5, for summary of operating conditions used.
§§§See General Comments Section, Note 6, for summary of operating conditions used.
476
-------
Table 229. GC Simulated Distillation Data
Material Process Coal Type Boiling Point Range Sample Description/Source Reference
Coal raw SRC-I KY No. 9 31'F - IBP* Wilsonville pilot plant, 82
naphtha 161°F - 10 SRC unit (Run No. 225,
182'F - 15 APCI Sample No. 1910CB)
205°F - 20
237°F - 30
273'F - 40
309°F - 50
338°F - 60
352°F - 70
372"F - 80
386°F - 90
400°F - 95
425°F - EP
KY No. 9 22°F - IBP Wilsonville pilot plant, 82
161'F - 10 SRC unit (Run No. 220,
184°F - 15 APCI Sample No. 1896C8)
209*F - 20
239°F - 30
2818F - 40
319 "F - 50
339°F - 60
360eF - 70
374'F - 80
393°F - 90
404'F - 95
434°F - EP
KY No. 9 188'F - IBP* Wilsonville pilot plant, 82
271*F - 10 Alcoa coker unit (APCI
281 "F - 15 Sample No. 1899CB)
285aF - 20
292°F - 30
324°F - 40
345'F - 50
366°F - 60
378°F - 70
387°F - 80
403'F - 90
414°F - 95
450°F - EP
NA 29°F - IBP* Wilsonville pilot plant 84
125°F - 5
155°F - 10
214°F - 30
266°F - 50
321°F - 70
369'F - 90
394*F - 95
471*F - EP (Continued)
477
-------
Table 229 (Continued)
Material Process Coal Type Boiling Point Range
Coal raw SRC-I KY No. 9
naphtha
KY No. 9
and 14,
IL No. 6
(River
King
Mine)
and
Pitt-
Seams WV
(Black-
ville No.
2 Mine)
84°F - IBP*
167°F - 10
188°F - 15
208° F - 20
235°F - 30
257°F - 40
285°F - 50
311°F - 60
337°F - 70
360°F - 80
388° F - 90
NA - 95
426°F - EP
53/153°F - IBP/5
173/235°F - 10/30
291 °F - 50
34S/395°F - 70/90
408/442°F - 95/99
EDS
NA
NA
IL No. 6
(Monterey
Mine)
32/149°F
149/347°F
347/644°F
32/149°F
149/347°F
374/644°F
6
64
31
8
59
34
125°F -
165°F -
214°F -
249°F -
280°F -
305°F -
327°F -
346°F -
365°F -
384° F -
390°F -
398° F -
5T
10
20
30
40
50
60
70
80
90
95
99
(Continued)
478
Sample Description/Source Reference
Wilsonville pilot plant,
SRC unit, sample washed
with caustic prior to
analysis (Run No. 220,
APCI Sample No. 1933CB)
82
Ft. Lewis pilot plant
(Chevron Sample No.
WOW 3750)
86
Ft. Lewis pilot plant
(DuPont "Notebook"
Sample No. 16928)
One tpd pilot plant, once-
through mode (OuPont
"Notebook" Sample No.
16928)
One tpd pilot plant;
operating conditions:
840°F reactor temperature,
40 minutes residence time,
1500 psi reactor pressure;
average of yield period
Nos. 256-265
91
91
99
-------
Table 229 (Continued)
Material Process Coal Type Boiling Point Range
EDS
Coal raw
naphtha
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
Wyodak
Wyodak
162+43'F - 5
315+21°F - 50
381+8'F - 95
125+11°F - 5
305+14'F - 50
389+10°F - 95
168+8*F - 5
310+15'F - 50
385+5*F - 95
160+6*F - 5
315+8'F - 50
384+38F - 95
113+9SF - 5
302+20"F - 50
386+18"F - 95
101"F - 5
286+19*F - 50
378+16°F - 95
Sample Description/Source Reference
One tpd pilot plant, 99
average of three operat-
ing conditions (840°F
reactor temperature;
15-40 minutes residence
time)
One tpd pilot plant; 99
operating conditions: SOOT
reactor temperature, 40
minutes residence time;
average of ten yi eld
periods
75 Ib per day development 99
unit; average of six
operating conditions
(800-880'F reactor
temperature, 25-100
minutes residence time)
75 Ib per day development 99
unit; operating conditions:
840°F reactor temperature,
40 minutes residence
time; average of 21 yield
periods
One tpd pilot plant; 99
average of six operating
conditions (800-840'F
reactor temperature,
40-100 minutes residence
time)
One tpd pilot plant; 99
operating conditions:
840°F reactor temperature,
60 minutes residence
time; average of 7 yield
periods
(Continued)
479
-------
Table 229 (Continued)
Material Process Coal Type Boiling Point Range Sample Description/Source Reference
Coal raw
naphtha
EDS
Wyod ak
Wyodak
Wyodak
H-Coal IL No. 6
105'F
150'F
196'F
2208F
252 °F
276'F
305 'F
331 °F
349 "F
364°F
372 8F
386 8F
- 5
- 10
- 20
- 30
- 40
- 50
- 60
- 70
- 80
- 90
- 95
- 99
159+218F - 5
302T188F - 50
389+11"F - 95
154+58F - 5
293+68F - 50
379+5*F - 95
988F
167°F
182 °F
2158F
237'F
280 8F
322°F
347 °F
368°F
388° F
400 °F
407°F
452 8F
- IBP*
- 5
- 10
- 20
- 30
- 40
- 50
- 60
- 70
- 80
- 90
- 95
- EP
One tpd pilot plant;
operating conditions:
840°F reactor temperature,
60 minutes residence
time, 1500 psi reactor
pressure; average of
yield period Nos. 267-270
99
75 Ib per day development
unit; average of eight
operating conditions (800-
850°F reactor temperature,
25-100 minutes residence
time)
75 Ib per day development
unit; operating conditions:
880°F reactor temperature,
25 minutes residence
time; average of six
yield periods
PDU, syncrude mode
99
99
109
(Continued)
480
-------
Table 229 (Continued)
Material Process Coal Type Boiling Point Range Sample Description/Source Reference
Coal raw H-Coal IL No. 6 97'F - IBP* PDU, syncrude mode 109
naphtha 160'F - 5
1868F - 10
216'F - 20
240'F - 30
268°F - 40
289°F - 50
319°F - 60
344°F - 70
366°F - 80
3938F - 90
402'F - 95
4298F - EP
W. KY 978F - IBP* PDU, syncrude mode 109
No. 11 155'F - 5
180°F - 10
204°F - 20
234'F - 30
2608F - 40
288"F - 50
315'F - 60
3418F - 70
369°F - 80
4048F - 90
432°F - 95
498°F - EP
(Continued)
481
-------
Table 229 (Continued)
Material Process Coal Type Boiling Point Range Sample Description/Source Reference
Hydro-
treated
coal
naphtha
SRC-1
KY No. 9
100°F -
182°F -
189°F -
209°F -
219°F -
234°F -
253°F -
284° F -
317°F -
351°F -
385°F -
404°F -
454°F -
IBP*
10
15
20
30
40
50
60
70
80
90
95
EP
Wilsonville pilot plant,
(APCI Sample No. 1934CB)
82
SRC-II
KY No. 9
and 14,
IL No. 6
(River
King
Mine)
and
Pitt-
Seams WV
(Black-
ville No.
2 Mine)
KY No. 9
and 14,
IL No. 6
(River
King
Mine)
and
Pitt-
Seams WV'
(Black-
ville No.
2 Mine)
50/155°F
52/160°F - IBP/5
173/214°F;
175/217°F - 10/30
246°F; 256°F - 50
302/374°F;
308/377°F - 70/90
391/464°F;
399/451°F - 95/99
135/184°F - IBP/5
216/260°F - 10/30
309°F - 50
359/406°F - 70/90
414/436°F - 95/99
Ft. Lewis pilot plant,
Chevron coal raw naphtha
Sample No. WOW 3750
hydrotreated with ICR 113
catalyst (Run No. 65-194,
run hours 111-135 and
23-255, respectively)?
86
Ft. Lewis pilot plant,
Chevron coal raw naphtha
Sample No. SGQ 6502
partially hydrotreated
with ICR 113 catalyst
(Run No. 72-326)
86
(Continued)
482
-------
Table 229 (Concluded)
Material Process Coal Type Boiling Point Range Sample Description/Source Reference
Hydro-
treated
coal
naphtha
SRC-11
KY No. 9
and 14,
IL No. 6
(River
King
Mine)
and
Pitt-
Seams wv
(Black-
vine No.
2 Mine)
96/179°F;
101/182°F - IBP/5
197/242°F;
199/247°F - 10/30
289; 294 - 50
340/394;
345/399 - 70/90
407/435;
411/437 - 95/99
Ft. Lewis pilot plant,
Chevron coal raw naphtha
Sample No. SGQ 6502
partially hydrotreated
and hydrofined with
ICR 113 catalyst (Run No.
72-326, Run Hours 138-150
and 222-246, respectively)§
86
Coal-
de ri ved
gasoline
NA
Explanatory Notes
*Determined via ASTM D-2887
'''Average of inspections of unknown number of individual samples derived from a
sequence of yield periods at "study design" conditions
fSee General Comments Section, Note 7, for summary of operating conditions used.
§See General Comments Section, Note 8, for summary of operating conditions used.
483
-------
Table 230. Molecular Weight
Material
Process Coal Type
Coal raw
naphtha
SCR-II
Hydrotreated
coal naphtha
Coal-derived
gasoline
KY No. 9
and 14
IL No. 6
(River
King
Mine)
and
Pitt-
Seams WV
(Black-
vine No.
2 Mine)
KY No. 9
and 14,
IL No. 6
(River
King
Mine)
and
Pitt-
Seams WV
(Black-
vine No.
2 Mine)
NA
Value
(g/mole)
118
Sample Description/Source Reference
Ft. Lewis pilot plant,
(Chevron Sample No.
WOW 3750)
86
119
Ft. Lewis pilot plant,
Chevron coal raw naphtha
Sample No. SGQ 6502
partially hydrotreated
and hydrofined with
ICR 113 catalyst (Run
No. 72-326, Run hours
222-246)
86
484
-------
Table 231. Total Acid Number
Material
Coal raw
naphtha
Hydro-
treated
coal
naphtha
Coal-
de rived
gasoline
Value
Process Coal Type (mg KOH/g) Sample Description/Source Reference
SRC-1
H-Coal
NA
NA
KY No. 9
KY No. 9
KY No. 9
IL No. 6
Wyodak
W. KY
No. 11
6.08* Wilsonville pilot plant,
SRC unit (Run No. 220,
APCI Sample No. 1896CB)
6.63* Wilsonville pilot plant,
SRC unit (Run No. 225;
APCI Sample No. 1910CB)
6.26* Wilsonville pilot plant,
SRC unit, sample washed
with caustic prior to
analysis (Run No. 220,
APCI Sample No. 1933CB)
0.07 POU, syncrude mode
0.13 ' PDU, syncrude mode
0.19 PDU, syncrude mode
82
82
82
109
109
109
Explanatory Notes
*Determined via ASTM D-664
485
-------
Table 232. Gum Content
Material
Coal raw
naphtha
Value
Process Coal Type (mg/100 ml) Sample Description/Source Reference
SRC-1
KY No. 9
KY No. 9
KY No. 9
47.0
107
38
SRC- I I
EDS
Powhattan
No. 5
IL No. 6
(Monterey
Mine)
12.0
44.0
IL No. 6 145
Wyodak 248
IL No. 6 122
Wyodak 258
H-Coal IL No. 6 40.0
IL No. 6
Wyodak
W. KY
No. 11
22
58
47
(Continued)
486
Wilsonville pilot plant, 82
SRC unit (Run No. 220,
APCI Sample No. 1896C8)
Wilsonville pilot plant, 82
SRC unit (Run No. 225,
APCI Sample No. 1910CB)
Wilsonville pilot plant, 82
SRC unit, sample washed
with caustic prior to
analysis (Run No. 220,
APCI Sample No. 1933CB)
Ft. Lewis, pilot plant 85
(UOP Sample No. 3777-1)
One tpd pilot plant, once- 87
through mode (UOP Sample No.
3531-7)
One tpd pilot plant, once- 90
through mode, unwashed
(SWRI Sample No. G-C2)
One tpd pilot plant, once- 90
through mode, washed
(SWRI Sample No. G-C3)
One tpd pilot plant, once- 90
through mode, washed
(SWRI Sample No. G-C2)
One tpd pilot plant, once- 90
through mode, unwashed
(SWRI Sample No. G-C3)
PDU, syncrude mode; rerun 92
naphtha, (UOP Sample
No. 3531-1-2)
POU, syncrude mode 109
PDU, syncrude mode 109
PDU, syncrude mode 109
-------
Material
Hydro-
treated
coal
naphtha
Table 232 (Concluded)
Value
Process Coal Type (mg/100 ml) Sample Description/Source Reference
SRC-1
SRC-II
Coal-
derived
gasoline
NA
KY No. 9
KY No. 9
and 14,
IL No. 6
(River
King
Mine)
and
Pitt-
Seams WV
(Black-
vine No.
2 Mine)
1.1
Wilsonville pilot plant,
SRC unit (APCI Sample
No. 1934CB)
Ft. Lewis pilot plant,
Chevron coal raw naphtha
Sample No. WOW 3750
hydrotreated with ICR 113
catalyst (Run No. 65-194,
Run Hours 111-135 and
231-255, respectively)*
82
86
Explanatory Notes
*See General Comments Section, Note 7, for summary of operating conditions used.
487
-------
Table 233. Viscosity
Material Process Coal Type
Coal raw SRC- I KY No. 9
naphtha
KY No. 9
NA
KY No. 9
KY No. 9
and 14
SCR- II KY No. 9
and 14,
IL No. 6
(River
King
Mine)
and
Pitt-
Seams WV
(Black-
vine No.
2 Mine)
EDS IL No. 6
Value
(centi-
(stokes) Sample Description/Source
1.304* Wilsonville pilot plant,
(68°F) SRC unit (Run No. 220,
0.960 APCI Sample No. 1896CB)
(104°F)
0.754
(140°F)
1.172 Wilsonville pilot plant,
(68°F) SRC unit (Run No. 225,
0.8791* APCI Sample No. 1918CB)
(104°F)
0.6858
(140°F)
1.03 Wilsonville pilot plant
(50°F)
0.85 Wilsonville pilot plant,
(68°F) SRC unit, sample washed
0.69* with caustic prior to
(104°F) analysis (Run No. 220,
0.57 APCI Sample No. 1933CB)
(140°F)
1.62 Ft. Lewis pilot plant*
(centi-
poise)
0.8933 Ft. Lewis pilot plant,
(100°F) (Chevron Sample No.
WOW 3750)
0.9 One tpd pilot plant, from
(100°F) "typical" run (Run A-7)
0.5
(210°F)
(Continued)
488
Reference
82
82
84
82
83
86
99
-------
Table 233 (Continued)
Material
Coal raw
naphtha
Process Coal Type
EDS
H-Coal
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
Wyodak
Wyodak
Wyodak
IL No. 6
(Burning
Star
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
Value
(centi-
(stokes)
0.85+_
0.03
(100'F)
0.47+
0.03
(210'F)
0.87+
0.06
(100'F)
0.50
(210'F)
0.8
(100'F)
0.5
(210'F)
0.86+
0.07
(100'F)
0.47+
0.03"
(210'F)
0.82+
0.07
(100'F)
0.46+
0.01"
(210*F)
1.08*
(100'F)
0.96*
(100'F)
0.950
(104'F)
Sample Description/Source Reference
One tpd pilot plant; 99
average of three operat-
ing conditions (840"F
reactor temperature;
15-40 minutes residence
time)
One tpd pilot plant; 99
operating conditions:
840°F reactor tempera-
ture; 40 minutes
residence time; average
of ten yield periods
One tpd pilot plant, from 99
"typical" run (Run A-7)
One tpd pilot plant; 99
average of six operating
conditions (800-840'F
reactor temperature,
40-100 minutes residence
time)
One tpd pilot plant; 99
operating conditions:
840°F reactor tempera-
ture, 60 minutes resi-
dence time; average of
seven yield periods
Derived from PDU atmos- 97
pheric still overhead
and vacuum still overhead
streams, fuel oil mode
(analyzed by BETC)t
Derived from PDU atmos- 97
pheric still overhead
and vacuum still overhead
streams, syncrude mode
(analyzed by BETC)?
PDU, syncrude mode 109
(Continued)
489
-------
Table 233 (Concluded)
Material
Coal raw
naphtha
Hydro-
treated
coal
naphtha
Coal-
derived
gasoline
Process Coal Type
H-Coal Wyodak
W. KY
No. 11
NA
NA
Value
(centi-
(stokes)
0.801
(104°F)
0.701
(104°F)
Sample Description/Source Reference
PDU, syncrude mode 109
PDU, syncrude mode
109
Explanatory Notes
*Determined via ASTM D-445
'''See General Comments Section, Note 7, for summary of operating conditions used.
fSee General Comments Section, Note 3, for summary of operating conditions used.
490
-------
Material
Coal raw
naphtha
Hydro-
treated
coal
naphtha
Coal-
de rived
gasoline
Table 234. Pour Point
Value
Process Coal Type
SRC-1
H-Coal
NA
NA
KY No. 9
KY No. 9
NA
KY No. 9
IL No. 6
(Burning
Star
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
Wyodak
<-80*
<-80*
<-65.0
<-80*
<5*
<5*
<-65
<-65
Sample Description/Source Reference
Wilsonville pilot plant, 82
SRC unit (Run No. 220,
APCI Sample No. 1896CB)
Wilsonville pilot plant,
SRC unit (Run No. 225,
APCI Sample No. 1910CB)
Wilsonville pilot plant
Wilsonville pilot plant:
SRC unit, sample washed
with caustic prior to
analysis (Run No. 220,
APCI Sample No. 1933CB)
Derived from POD
atmospheric still over-
head and vacuum still
overhead streams, fuel
oil mode (analyzed by
BETC)t
Derived from PDU
atmospheric still over-
head and vacuum still
overhead streams, syn-
crude mode (analyzed by
BETC)1"
PDU, syncrude mode
PDU, syncrude mode
82
84
82
97
97
109
109
Explanatory Note
*Determined via ASTM D-97
1"See General Comments Section, Note 3, for summary of operating conditions used.
491
-------
Table 235. Carbon Residue
Material
Raw coal
naphtha
Process
SRC- 1
Coal Type
KY No. 9
Value
(wt.%)
0.08*
Hydro-
treated
coal
naphtha
Coal-
de rived
gasoline
NA
NA
KY No. 9
NA
Sample Description/Source Reference
0.01'
Wilsonvilie pilot plant,
SRC unit (Run No. 220,
APCI Sample No. 1896CB)
Wilsonville pilot plant,
SRC unit (Run No. 225,
APCI Sample No. 1910C8)
<0.01*'t Wilsonville pilot plant
82
82
84
Explanatory Note
*Detennined via ASTM D-189
^Conradson carbon residue
492
-------
Table 236. Bottom Sediment and Water
Material
Coal raw
naphtha
Hydro-
treated
coal
naphtha
Coal-
de rived
gasoline
Process Coal Type
SRC-I KY No. 9
KY No. 9
KY No. 9
Value
(ml)
<0.05*
<0.05*
<0.05*
NA
NA
Sample Description/Source Reference
Wilsonville pilot plant,
SRC unit (Run No. 220,
APCI Sample No. 1896CB)
Wilsonville pilot plant,
SRC unit (Run No. 225,
APCI Sample No. 1910CB)
Wilsonville pilot plant,
SRC unit, sample washed
with caustic prior to
analysis (Run No. 220,
APCI Sample.No. 1933CB)
82
82
82
Explanatory Note
^Determined via ASTM D-1796
493
-------
Material
Coal raw
naphtha
Hydro-
treated
coal
naphtha
Coal-
de rived
gasoline
Table 237. Freeze Point
Value
Process Coal Type (°F)
SRC-I KY No. 9 <-76
KY No. 9 <-76
KY No. 9 <-76
MA
NA
Explanatory Note
*Determined via ASTM D-2386
Sample Description/Source Reference
Wilsonville pilot plant, 82
SRC unit (Run No. 220,
APCI Sample No. 1896CB)
Wilsonville pilot plant,
SRC unit (Run No. 225,
APCI Sample No. 1910CB)
Wilsonville pilot plant,
SRC unit, sample washed
with caustic prior to
analysis (Run No. 220,
APCI Sample No. 1933CB)
82
82
494
-------
Material
Coal raw
naphtha
Hydro-
treated
coal
naphtha
Coal-
de rived
gasoline
Table 238. Flash Point
Value
Process Coal Type
SRC-I KY No. 9
KY No. 9
NA
KY No. 9
EDS
NA
NA
IL No. 6
Wyodak
(°F) Sample Description/Source Reference
<-20* Wilsonville pilot plant, 82
SRC unit (Run No. 220,
APCI Sample No. 1896CB)
<-20* Wilsonville pilot plant, 82
SRC unit (Run No. 225,
APCI Sample No. 1910CB)
<75.0 Wilsonville pilot plant 84
<0* Wilsonville pilot plant, 82
SRC unit, sample washed
with caustic prior to
analysis (Run No. 220,
APCI Sample No. 1933CB)
<70 One tpd pilot plant, from 99
"typical" run (Run A-7)
<70 One tpd pilot plant, from 99
"typical" run (Run A-7)
Explanatory Note
determined via ASTM D-96
495
-------
Table 239. Smoke Point
Material
Coal raw
naphtha
Hydro-
treated
coal
naphtha
Coal-
de ri ved
gasoline
Process Coal Type
SRC-I KY No. 9
KY No. 9
KY No. 9
NA
Value
(mm)
14.7*
22*
12*
NA
Explanatory Note
determined via ASTM D-1322
Sample Description/Source Reference
Wilsonville pilot plant,
SRC unit (Run No. 220,
APCI Sample No. 1896CB)
Wilsonville pilot plant,
SRC unit (Run No. 225,
APCI Sample No. 1910CB)
Wilsonville pilot plant,
SRC unit, sample washed
with caustic prior to
analysis (Run No. 220,
APCI Sample No. 1933CB)
82
82
82
496
-------
Table 240. Heat of Combustion
Material
Coal raw
naphtha*
Hydro-
treated
coal
naphtha
Coal-
de pi ved
gasoline
Process Coal Type
SRC-1
EDS
NA
NA
KY No. 9
KY No. 9
KY No. 9
Value
(net,
(Btu/lb)
Sample Description/Source Reference
82
IL No. 6
Wyodak
W. KY
No. 11
IL No. 6
Wyodak
18,597
19,350
18,733
19,600
20,100
17,706t Wilsonville pilot plant,
SRC unit (Run No. 220,
APCI Sample No. 1896CB)
17,825t Wilsonville pilot plant, 82
SRC unit (Run No. 225,
APCI Sample No. 1910CB)
19,028t Wilsonville pilot plant, 82
SRC unit, sample washed
with caustic prior to
analysis (Run No. 220,
APCI Sample No. 1933CB)
PDU, syncrude mode 109
PDU, syncrude mode 109
PDU, syncrude mode 109
One tpd pilot plant, from 99
"typical" run (Run A-7)
One tpd pilot plant, from 99
"typical" run (Run A-7)
Explanatory Note
*An additional value for the gross heat of combustion of an SRC-I, Wilsonville
pilot plant sample is 19,000 Btu/lb (Ref. 84).
'''Determined via ASTM D-240
497
-------
Table 241. Aniline Point
Material
Coal raw
naphtha
Value
Process Coal Type (°F)
SRC-I KY No. 9 55.8*
KY No. 9 78.8*
KY No. 9 71*
Sample Description/Source Reference
Hydro-
treated
coal
naphtha
SCR-II KY No. 9 56.4
and 14,
IL No. 6
(River King
Mine) and
Pitt-Seams
WV
(Blackville
No. 2 Mine)
SRC-II KY No. 9 80.7,
and 14, 79.0
IL No. 6
(River King
Mine) and
Pitt-Seams
WV
(Blackville
No. 2 Mine)
KY No. 9 67.6
and 14,
IL No. 6
(River King
Mine) and
Pitt-Seams
WV
(Blackville
No. 2 Mine)
(Continued)
Wilsonville pilot plant,
SRC unit (Run No. 220,
APCI Sample No. 1896CB)
Wilsonville pilot plant,
SRC unit (Run No. 225,
APCI Sample No. 1910CB)
Wilsonville pilot plant,
SRC unit, sample washed
with caustic prior to
analysis (Run No.
220, APCI Sample No.
1933CB)
Ft. Lewis pilot plant
(Chevron Sample No.
WOW 3750)
82
82
82
86
Ft. Lewis pilot plant
Chevron coa-1 raw naphtha
Sample No. WOW 3750
hydrotreated with ICR 113
catalyst (Run No. 65-194,
Run Hours 111-135 and 231-
255, respectively)''"
Ft. Lewis pilot plant,
Chevron coal raw naphtha
Sample No. SGQ 6502
partialy hydrotreated
with ICR 113 catalyst
(Run No. 72-326)
86
86
498
-------
Hydro-
treated
coal
naphtha
Coal-
de rived
gasoline
Table 241 (Concluded)
Material Process Coal Type
SRC-II
KY No. 9
and 14,
IL No. 6
(River King
Mine) and
Pitt-Seams
WV
(Blackville
No. 2 Mine)
NA
Value
72.8,
70.0
Sample Description/Source Reference
Ft. Lewis pilot plant,
Chevron coal raw naphtha
Sample No. SGQ 6502
partially hydrotreated
and hydrofined with ICR
113 catalyst (Run No.
72-326, Run Hours 138-150
and 222-246, respectively)1"
86
Explanatory Note
*Determined via ASTM D-611
'''See General Comments Section, Note 7, for summary of operating conditions
used.
499
-------
Table 242. Bromine Number
Material
Coal raw
naphtha
Process Coal Type Value
SRC-I KY No. 9 107*
KY No. 9 20.5*
SRC-II
EDS
Powhattan
No. 5
KY No. 9
and 14,
IL No. 6
(River King
Mine) and
Pitt-Seams
WV
(Blackville
No. 2 Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
30.0
49,52
39
35.6
(cg/g)
19.3
(cg/g)
Sample Description/Source Reference
Wilsonville pilot plant,
SRC unit (Run No. 220;
APCI Sample No. 1896C8)
Wilsonville pilot plant,
SRC unit, sample washed
with caustic prior to
analysis (Run No. 220,
APCI Sample No. 1933CB)
Ft. Lewis pilot plant
(UOP Sample No. 3777-1)
Ft. Lewis pilot plant
(Chevron Sample No.
WOW 3750)
One tpd pilot plant;
once-through mode (UOP
Sample No. 3531-7)
One tpd pilot plant;
operating conditions:
840°F reactor tempera-
ture, 25 minutes
residence time; average
of yield period Nos.
225-231
One tpd pilot plant;
sample washed with
caustic prior to
analysis; operating
conditions: 840°F
reactor temperature,
25 minutes residence
time; average of yield
period Nos. 225-231
82
82
85
86
87
99
99
(Continued)
500
-------
Table 242 (Continued)
Material
Coal raw
naphtha
Process Coal Type Value Sample Description/Source Reference
EDS
Hydro-
treated
coal
naphtha
Wyodak
Wyodak
IL No. 6
Wyodak
W. KY
No. 11
H-Coal IL No. 6
30.6
(cg/g)
16.0
(cg/g)
35.6
13.8
25.1
19.3
SRC-I KY No. 9 <0.1*
SRC-II Powhattan 101.0
No.5
EDS IL No. 6 124.0
(Monterey
Mine)
(Continued)
One tpd pilot plant; 99
operating conditions:
840°F reactor tempera-
ture; 25, 40 and 60
minute residence time;
average of yield period
Nos. 237, 244 and 249
One tpd pilot plant; 99
sample washed with
caustic prior to
analysis; operating
conditions: 840°F
reactor temperature,
25, 40 and 60 minute
residence time; average
of yield period
Nos. 237, 244 and 249
PDU, syncrude mode 109
PDU, syncrude mode 109
PDU, syncrude mode 109
PDU; syncrude mode, rerun 92
naphtha, (UOP Sample No.
3531-1-2)
Wilsonville pilot plant 82
(APCI Sample No. 1934CB)
Bench-scale continuous 85
hydrotreating of UOP coal
raw naphtha Sample No.
3777-1 (UOP Sample No.
3777-2, UOP Research Plant
505, Run 874)
Bench-scale continuous 87
hydrotreating of moderate
UOP coal raw naphtha
Sample No. 3531-7,
moderate severity hydro-
treatment, (UOP
Sample No. 3531-12, UOP
Research Plant 629, Run
218); operating conditions:
LHSV/LHSV (base), 0.125,
P-P (base). 450 psig, T-T
(base), 33*C
501
-------
Table 242 (Concluded)
Material Process Coal Type Value Sample Description/Source Reference
Hydro- H-Coal IL No. 6 296 Bench-scale continuous 92
treated hydrotreating of moderate
coal UOP coal raw naphtha
naphtha Sample No. 3531-1-2,
moderate severity hydro-
treatment, (Sample No.
3531-4, UOP Research
Plant 629, Run 215);
operating conditions:
P-P (base), 450 psig,
LHSV/LHSV (base), 0.125
Coal- NA
de ri ved
gasoline
Explanatory Note
determined via ASTM D-1159
502
-------
Table 243. Copper Strip Corrosion
Material
Coal raw
naphtha
Process Coal Type
SRC-I KY No. 9
KY No. 9
KY No. 9
EDS
H-Coal
IL No. 6
Wyodak
Value
4b*
4b*
4b*
4c
la
IL No. 6
Wyodak
W. KY
No. 11
Ib
la
la
Sample Description/Source Reference
Wilsonville pilot plant, 82
SRC unit (Run No. 220,
APCI Sample No. 1896CB)
Wilsonville pilot plant,
SRC unit (Run No. 225,
APCI Sample No. 1910CB)
Wilsonville pilot plant,
SRC unit, sample washed
with caustic prior to
analysis (Run No. 220,
APCI Sample No. 1933CB)
One tpd pilot plant
once-through mode
(SWRI Sample No. G-C2)
One tpd pilot plant
once-through mode
(SWRI Sample No. G-C3)
PDU, syncrude mode
PDU, syncrude mode
PDU, syncrude mode
82
82
90
90
109
109
109
Hydro-
treated
coal
naphtha
Coal-
de rived
gasoline
NA
NA
Explanatory Note
*Determined via ASTM D-130
503
-------
Table 244. Moisture
Material
Coal raw
naphtha
Hydro-
treated
coal
naphtha
Coal-
de rived
gasoline
Process Coal Type
SRC-I KY No. 9
KY No. 9
KY No. 9
NA
NA
Value
(wt%)
0.58^
1.04*
0.24"
Sample Description/Source Reference
Wilsonville pilot plant.
SRC unit (Run No. 220,
APCI Sample No. 1896CB)
Wilsonville pilot plant,
SRC unit (Run No. 225,
APCI Sample No. 1910CB)
Wilsonville pilot plant.
SRC unit, sample washed
with caustic prior to
analysis (Run No. 220,
APCI Sample No. 1933CB)
Explanatory Note
determined via ASTM D-1744 (Karl Fischer reagent method)
82
82
82
504
-------
Material
Coal raw
naphtha
Table 245. Color
Process Coal Type Value* Sample Description/Source Reference
SRC-1
KY No. 9
KY No. 9
KY No. 9
1.75
(between
pale and
dark yellow)
2.5
(between
dark yellow
and
light amber)
0.0
(clear
white)
H-Coal
IL No. 6
(Burning
Star Mine)
IL No. 6
(Monterey
Mine)
NPA6
NPA4
1/2
Hydro-
treated
coal
naphtha
Coal-
de rived
gasoline
NA
NA
Wilsonville pilot plant,
SRC unit (Run No. 220,
APCI Sample No. 1896CB)
Wilsonville pilot plant,
SRC unit (Run No. 225,
APCI Sample No. 1910CB)
Wilsonville pilot plant,
SRC unit, sample washed
with caustic prior to
analysis (Run No. 220,
APCI Sample No. 1933CB)
Derived from PDU atmos-
pheric still overhead
and vacuum still over-
head streams, fuel oil
mode (analyzed by BETC)t
Derived from PDU atmos-
pheric still overhead
and vacuum still over-
head streams, syncrude
mode (analyzed by BETC)t
82
82
82
97
97
Explanatory Note
*Determined via ASTM D-1500
'''See General Comments Section, Note 3, for summary of operating conditions
used.
505
-------
Table 246. Research Octane Number (RON, clear)
Material
Coal raw
naphtha
Process Coal Type
SRC-11 Powhattan
No. 5
EDS IL No. 6
(Monterey
Mine)
IL No. 6
Wyodak
H-Coal IL No. 6
Hydro-
treated
coal
naphtha
SRC-II
Powhattan
No. 5
KY No. 9
and 14,
IL No. 6
(River King
Mine) and
Pitt-Seams
WV
(Blackville
No. 2 Mine)
KY No. 9
and 14,
IL No. 6
(River King
Mine) and
Pitt-Seams
WV
(Blackville
No. 2 Mine)
83.2
78.71
83.8t
80.3
70.9
69.4,
69.2
(F-l,
clear);
65.3,
65.3
(F-2.
clear)
74.4
Sample Description/Source^ Reference
Ft. Lewis pilot plant
(Sample No. 3777-1)
One tpd pilot plant,
once-through mode
(UOP Sample No. 3531-7)
One tpd pilot plant,
once-through mode
(SWRI Sample No. G-C2)
One tpd pilot plant,
once-through mode
(SWRI Sample No. G-C3)
PDU.syncrude mode,
rerun naphtha, (UOP
Sample No. 3531-1-2)
Bench-scale continuous
hydrotreating of UOP
coal raw naphtha Sample
No. 3777-1 (UOP Sample
No. 3777-2, UOP Research
Plant 505, Run 874)
Ft. Lewis pilot plant;
Chevron coal raw naphtha
Sample No. WOW 3750
hydrotreated with ICR
113 catalyst (Run No.
65-194,
Run Hours 111-135 and
231-255, respectively)!
Ft. Lewis pilot plant;
Chevron coal raw naphtha
Sample No. SGQ 6502
paritally hydrotreated
with ICR 113 catalyst
(Run No. 72-326)
85
87
90
90
92
85
86
86
(Continued)
506
-------
Material
Hydro-
treated
coal
naphtha
Table 246 (Continued)
Process Coal Type Value Sample Description/Source Reference
SRC-11
KY No. 9
and 14,
(River King
Mine) IL
No. 6 and
Pitt-Seams
WV
(Blackville
No. 2 Mine)
70.5, 71.2
(F-l,
clear);
65.2, NA
(F-2,
clear)
EDS
IL No. 6 64.5
(Monterey (clear)
Mine)
H-Coal IL No. 6
Coal-
de rived
gasoline
SRC-II
Powhattan
No. 5
66.8
88.5
(Period 1)#
94.5
(Period 2)
97.6
(Period 3)
92.6
(Period 4)
99.9
(Period 5)
93.8
(Period 6)
(Continued)
Ft. Lewis pilot plant;
Chevron coal raw naphta
Sample No. SGQ 6502
partially hydrotreated
and hydrofined with ICR 113
catalyst (Run No. 72-326,
Run Hours 138-150 and 222-
246 respectively)
Bench-scale continuous
hydrotreating of UOP coal
raw naphtha Sample No.
3531-7, moderate severity
hydrotreatment (UOP Sample
No. 3531-12, UOP Research
Plant 629, Run 218);
operating conditions: LHSV/
LHSV(base),0.125; P-P(base)
450 psig; T-T(base), 33°C
Bench-scale continuous
hydrotreating of UOP coal
raw naphtha Sample No.
3531-1-2,, moderate sever-
ity hydrotreatment (UOP
Sample No. 3531-4, UOP
Research Plant 629, Run 215)
operating conditions: P-P
(base), 450 spig; LHSV/LHSV
(base), 0.125
Bench-scale continuous
platforming of hydrotreated
coal naphtha Sample No.
No. 3777-2 (UOP Research
Plant 636, Run 335)**
86
87
92
85
507
-------
Material
Coal-
derived
gasoline
Table 246 (Continued)
Process Coal Type Value Sample Description/Source
EDS
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
Wyodak
H-Coal IL No. 6
99.7 Bench-scale continuous
(Period 1)# platforming of moderately
Reference
87
97.9
(Period 2)
95.9
(Period 3)
95.1
(Period 4)
92.1
(Period 5)
90.6
(Period 6)
90.4
(Period 7)
98.2
(Period 8)
101.5
(Period 9)
104.5
(Period 10)
105
105
100
105
hydrotreated coal naphtha
Sample No. 3531-12 (UOP
Research Plant 508,
Run 1456)
From minimum severity
hydrotreated sample, boil'
ing range 160 to 390°F
From minimum severity
hydrotreated sample, boil'
ing range 160 to 340°F
From minimum severity
hydrotreated sample, boil'
ing range 160 to 370'F
From minimum severity
hydrotreated sample, boil-
ing range 160 to 345°F
99.8 Bench-scale continuous
(Period 1)# platforming of moderately
99.8 hydrotreated coal naphtha
Sample No. 3531-4 (UOP
ResearchJM ant 636,
Run
99
99
99
99
92
(Period 2)
98.7
(Period 4)
97.7
(Period 5)
(Continued)
508
-------
Table 246 (Concluded)
Material Process Coal Type Value Sample Description/Source Reference
Coal- H-Coal IL No. 6 97.7
derived (Period 6)
gasoline 96.0
(Period 7)
95.9
(Period 8)
94.4
(Period 9)
94.2
(Period 10)
100.9
(Period 11)
101.3
(Period 12)
102.3
(Period 13)
102.6
(Period 14)
Explanatory Notes
*Motor octane number was 73.9
'''Motor octane number was 77.6
fSee General Comments Section, Note 7, for summary of operating conditions used.
§See General Comments Section, Note 8, for summary of operating conditions used.
#Each period refers to a run time having a characteristic set of operating
conditions.
**See General Comments Section, Note 4, for summary of operating conditions used.
1"l"See General Comments Section, Note 5, for summary of operating conditions used.
ffSee General Comments Section, Note 6, for summary of operating conditions used.
509
-------
Table 247. Oxygen Content
Material Process Coal Type Value (wt. %) Sample Description/Source Reference
Coal raw
naphtha
SRC-1
SRC-II
EDS
KY No. 9 3.96
KY No. 9 4.45
KY No. 9 0.29
KY No. 9 3.96
NA
3.3
KY No. 9 3.85
and 14
Powhattan 0.7814
No. 5
IL No. 6 1.3700
(Monterey
Mine)
IL No. 6 1.92
IL No. 6 2.25
IL No. 6 2.04+0.28
(Monterey
Mine)
IL No. 6 2.25+0.45
(Monterey
Mine)
IL No. 6 0.80+0.20
(Monterey
Mine)
(Continued)
510
Wilsonville pilot plant 82
SRC unit (Run No. 220,
APCI Sample No. 1896CB)
Wilsonville pilot plant 82
SRC unit (Run No. 225,
APCI Sample No. 1910CB)
Wilsonville pilot plant, 82
SRC unit sample washed
with caustic prior to
analysis, (Run No. 220,
APCI Sample No. 1933CB)
Wilsonville pilot plant, 82
Alcoa coker unit (APCI
Sample No. 1899C8)
Wilsonville pilot plant 84
Ft. Lewis pilot plant* 83
Ft. Lewis pilot plant 85
(UOP Sample No. 3777-1)
One tpd pilot plant; 87
once-through mode
(UOP Sample No. 3531-7)
One tpd pilot plant; 90
once-through mode
(SWRI Sample No. G-C2)
One tpd pilot plant, 99
from "typical" run
(Run A-7)
One tpd pilot plant; 99
average of three operating
conditions (840°F reactor
temperature; 15-40 minutes
residence time)
One tpd pilot plant; 99
operating conditions:
840°F reactor temperature,
40 minutes residence time,
average of ten yield
periods
75 Ib per day development 99
unit; average of six
operating conditions
(800-880°F reactor
temperature; 25-100 min-
utes residence time)
-------
Table 247 (Continued)
Material Process Coal Type Value (wt. %) Sample Description/Source Reference
Coal raw EDS
naphtha
IL No. 6 0.85+0.37
(Monterey
Mine)
Wyodak
Wyodak
Wyodak
NA
IL No. 6
Wyodak
W. KY
No. 11
1.84
2.67
2.73+0.59
Wyodak 2.67+0.44
Wyodak 0.65+0.48
Wyodak 0.47+0.19
2.37
H-Coal IL No. 6 0.5944
3.0
1.2
1.3
75 Ib per day development 99
unit; operating conditions:
840°F reactor temperature,
40 minutes residence time,
average of 21 yield periods
One tpd pilot plant, once 90
through mode (SWRI Sample
No. G-C3)
One tpd pilot plant, from 99
"typical" run (Run A-7)
One tpd pilot plant; average 99
of six opeating conditions
(800-840°F reactor tempera-
ture, 40-100 minutes
residence time)
One tpd pilot plant; operat- 99
ing conditions: 840"F
reactor temperature, 60
minutes residence time;
average of seven yield
periods
75 Ib per day development 99
unit; average of eight
operating conditions (800-
8808F reactor temperature;
25-100 minutes residence
time)
75 Ib per day development 99
unit; operating conditions:
880°F reactor temperature,
25 minutes residence time;
average of 6 yield periods
One tpd pilot plant 91
(DuPont "Notebook" Sample
No. 16928)
POU, syncrude mode; rerun 92
naphtha (UOP Sample No.
3531-1-2)
PDU, syncrude mode 109
POU, syncrude mode 109
PDU, syncrude mode 109
(Continued)
511
-------
Table 247 (Continued)
Material Process Coal Type Value (wt. %) Sample Description/Source Reference
Hydro-
treated
coal
naphtha
SRC-1
SRC-II
KY No. 9 <0.05
Powhattan 0.0359
No. 5
EDS
IL No. 6 0.0098
(Monterey
Mine)
H-Coal IL No. 6 0.0034
Coal-
derived
gasoline
SRC-II Powhattan 0.0160
No. 5 (Period I)1"
0.0183
(Period 2)
0.0299
(Period 3)
0.0336
(Period 4)
0.0311
(Period 5)
0.0251
(Period 6)
Wilsonville pilot plant 82
(APCI Sample No. 1934CB)
Bench-scale continuous 85
hydrotreating of UOP coal
raw naphtha Sample No.
3777-1 (UOP Sample No.
3777-2, UOP Research Plant
505, Run 874)
Bench-scale continuous 87
hydrotreating of UOP
coal raw naphtha Sample No.
3531-7, moderate severity
hydrotreatment (UOP Sample
No. 3531-12, UOP Research
Plant 629, Run 218)
Bench-scale continuous 92
hydrotreating of UOP coal
raw naphtha Sample No.
3531-1-2, moderate severity
hydrotreatment (UOP Sample
No. 3531-4, UOP Research
.Plant 629, Run 215).
Operating conditions:
LHSV/LHSV, 0.125; P-P
(base), 450 psig
Bench-scale continuous 85
platforming of hydrotreated
coal naphtha Sample No.
3777-2 (UOP Research Plant
636, Run 335)
(Continued)
512
-------
Table 247 (Concluded)
Material Process Coal Type Value (wt. %) Sample Description/Source Reference
Coal-
derived
gasoline
EDS
IL No. 6
(Monterey
Mine)
Explanatory Notes
NA (Period l)t
0.0100
(Period 2)
0.0068
(Period 3)
0.0074
(Period 4)
0.0057
(Period 5)
0.0098
(Period 6)
0.0061
(Period 7)
0.0100
(Period 8)
NA (Period 9)
NA (Period 10)
Bench-scale continuous
platforming of moderate
hydrotreated coal naphtha
Sample No. 3531-12 (UOP
Research Plant 508, Run
1456)
87
*See General Comments section, Note 2, for summary of operating conditions used.
'''Each period refers to a run time having a characteristic set of operating conditions.
513
-------
Table 248. Sulfur Content
Material Process Coal Type Value (wt. %) Sample Description/Source Reference
Coal raw
naphtha
SRC-I
KY No, 9
KY No. 9
KY No. 9
0.82
0.82
0.75
KY No. 9
0.22
SRC- 1 1
EDS
NA
KY No. 9
and 14
Powhattan
No. 5
IL No. 6
(Monterey
Mine)
IL No. 6
0.57
0.44
0.4400
0.9978
0.61
IL No. 6
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
0.58
0.73+0.14
0.58+0.09
0.01+0.01
(Continued)
514
Wilsonville pilot plant, 82
SRC unit (Run No. 220,
APCI Sample No. 1896CB)
Wilsonville pilot plant, 82
SRC unit (Run No. 225,
APCI Sample No. 1910CB)
Wilsonville pilot plant, 82
SRC unit sample washed
with caustic prior to
analysis, (Run No. 220,
APCI Sample No. 1933CB)
Wilsonville pilot plant, 82
Alcoa coker unit (APCI
Sample No. 1899CB)
Wilsonville pilot plant 84
Ft. Lewis pilot plant* 83
Ft. Lewis pilot plant 85
(UOP Sample No. 3777-1)
One tpd pilot plant; 87
once-through mode
(UOP Sample No. 3531-7)
One tpd pilot plant; 90
once-through mode
(SWRI Sample No. G-C2)
One tpd pilot plant, from 99
"typical" run (Run A-7)
One tpd pilot plant; 99
average of three operating
conditions (840°F reactor
temperature; 15-40 minutes
residence time)
One tpd pilot plant; 99
operating conditions:
840°F reactor temperature,
40 minutes residence time;
average of ten yield
periods
75 Ib per day development 99
unit; average of six
operating conditions
(800-880°F reactor
temperature; 25-100 min-
utes residence time)
-------
Table 248 (Continued)
Material Process Coal Type Value (wt. %) Sample Description/Source Reference
Coal raw EDS IL No. 6 0.01+0.00 75 Ib per day development 99
naphtha (Monterey unit; operating conditions:
Mine) 840°F reactor temperature,
40 minutes residence time;
average of 21 yield periods
Wyodak 0.21 One tpd pilot plant, once- 90
through mode (SWRI Sample
No. G-C3)
Wyodak 0.05 One tpd pilot plant, from 99
"typical" run (Run A-7)
Wyodak 0.08+0.02 One tpd pilot plant; average 99
of six operating conditions
(800-840°F reactor tempera-
ture, 40-100 minutes
residence time)
Wyodak 0.05+0.01 One tpd pilot plant; operat- 99
ing conditions: 840°F
reactor temperature, 60
minutes residence time;
average of seven yield
periods
Wyodak 0.00+0.00 75 Ib per day development 99
unit; average of eight
operating conditions (800-
880°F reactor temperature;
25-100 minutes residence
time)
Wyodak 0.00+0.00 75 Ib per day development 99
unit; operating conditions:
880°F reactor temperature,
25 minutes residence time,
average of 6 yield periods
NA 0.60 One tpd pilot plant 91
(DuPont "Notebook" Sample
No. 16928)
PDU, syncrude mode; rerun 92
naphtha (UOP Sample No.
3531-1-2)
0.1800 PDU (Ashland oil sample) 96
H-Coal IL No. 6 0.1289
IL No. 6
(Burning
Star
Mine)
IL No. 6
(Burning
Star
Mine)
0.13 Derived from PDU atmospheric 97
still overhead and vacuum
still overhead streams,
fuel oil mode (analyzed by
BETC)t
515 (Continued)
-------
Table 248 (Continued)
Material Process Coal Type Value (wt. %) Sample Description/Source Reference
97
Coal raw H-Coal
naphtha
IL No. 6 0.06
(Monterey
Mine)
Wyodak
W. KY
No. 11
0.1
0.2
Hydro-
treated
coal
naphtha
SCR-11
IL No. 6 0.2
Powhattan 0.000022
No. 5
EDS
IL No. 6 0.00001
(Monterey
Mine)
H-Coal IL No. 6 0.00039
Derived from PDU
atmospheric still overhead
and vacuum still overhead
streams, syncrude mode
(analyzed by BETC)
PDU, syncrude mode 109
PDU, syncrude mode 109
PDU, syncrude mode 109
Bench-scale continuous 85
hydrotreating of UOP coal
raw naphtha Sample No.
3777-1 (UOP Sample No.
3777-2, UOP Research Plant
505, Run 874)
Bench-scale continuous 87
hydrotreating of UOP
coal raw naphtha Sample No.
3531-7, moderate severity
hydrotreatment (UOP Sample
No. 3531-12, UOP Research
Plant 629, Run 218)
Bench-scale continuous 92
hydrotreating of UOP coal
raw naphtha Sample No.
3531-1-2 moderate severity
hydrotreatment (UOP Sample
No. 3531-4, UOP Research
Plant 629, Run 215).
Operating conditions:
LHSV/LHSV, 0.125; P-P
(base), 450 psig
(Continued)
516
-------
Table 248 (Concluded)
Material Process Coal Type Value (wt. %} Sample Description/Source Reference
Coal-
derived
gasoline
SRC-11
Powhattan
No. 5
EDS
IL No. 6
(Monterey
Mine)
Explanatory Notes
0.00001
(Period
0.00001
(Period 2)
0.00001
(Period 3)
0.00001
(Period 4)
0.00001
(Period 5)
0.00001
(Period 6)
0.00001
(Period
0.00001
(Period 2)
0.00001
(Period 3)
0.00001
(Period 4)
0.00001
(Period 5)
0.00001
(Period 6)
0.00001
(Period 7)
0.00001
(Period 8)
0.00001
(Period 9)
0.00001
(Period 10)
Bench-scale continuous
platforming of hydrotreated
coal naphtha Sample No.
3777-2 (UOP Research Plant
636, Run 335)§
Bench-scale continuous
platforming of moderate
hydrotreated coal naphtha
Sample No. 3531-12 (UOP
Research Plant 508, Run
1456)#
85
87
*See General Comments section, Note 2, for
'''See General Comments section, Note 3, for
fEach period refers to a run time having a
conditions.
§See General Comments section, Note 4, for
*See General Comments section, Note 5, for
summary of operating conditions used.
summary of operating conditions used.
characteristic set of operating
summary of operating conditions used.
summary of operating conditions used.
517
-------
Table 249. Nitrogen Content
Material Process Coal Type Value (wt. %) Sample Description/Source Reference
Coal raw SRC-I
naphtha
SRC-II
EDS
KY No. 9 0.35
KY No. 9 0.29
KY No. 9 0.33
KY No. 9 0.35
NA
0.29
KY No. 9 0.36
and 14
Powhattan 0.5140
No. 5
IL No. 6 0.2097
(Monterey
Mine)
IL No. 6 0.223
IL No. 6 0.17
IL No. 6 0.14+0.03
(Monterey
Mine)
IL No. 6 0.17^0.05
(Monterey
Mine)
IL No. 6 0.07+0.02
(Monterey
Mine)
(Continued)
518
Wilsonville pilot plant, 82
SRC unit (Run No. 220,
APCI Sample No. 1896CB)
Wilsonville pilot plant, 82
SRC unit (Run No. 225,
APCI Sample No. 1910CB)
Wilsonville pilot plant, 82
SRC unit sample washed
with caustic prior to
analysis, (Run No. 220,
APCI Sample No. 1933CB)
Wilsonville pilot plant, 82
Alcoa coker unit (APCI
Sample No. 1899C8)
Wilsonville pilot plant 84
Ft. Lewis pilot plant* 83
Ft. Lewis pilot plant 85
(UOP Sample No. 3777-1)
One tpd pilot plant; 87
once-through mode
(UOP Sample No. 3531-7)
One tpd pilot plant; 90
once-through mode
(SWRI Sample No. G-C2)
One tpd pilot plant, from 99
"typical" run (Run A-7)
One tpd pilot plant; 99
average of three operating
conditions (840°F reactor
temperature; 15-40 minutes
residence time)
One tpd pilot plant; 99
operating conditions:
840°F reactor temperature,
40 minutes residence time;
average of ten yield
periods
75 Ib per day development 99
unit; average of six
operating conditions
(800-880°F reactor
temperature; 25-100 min-
utes residence time)
-------
Table 249 (Continued)
Material Process Coal Type Value (wt. %) Sample Description/Source Reference
Coal raw EDS
naphtha
IL No. 6 0.03+_0.01
(Monterey
Mine)
Wyodak 0.207
Wyodak 0.16
Wyodak 0.17+0.02
Wyodak 0.16+0.02
Wyodak 0.07+0.03
Wyodak 0.08+0.01
NA
IL No. 6
(Burning
Star
Mine)
IL No. 6
(Burning
Star
Mine)
0.46
H-Coal IL No. 6 0.1930
0.1370
0.420
(Continued)
519
75 Ib per day development 99
unit; operating conditions:
840°F reactor temperature,
40 minutes residence time;
average of 21 yield periods
One tpd pilot plant, once- 90
through mode (SWRI Sample
No. G-C3)
One tpd pilot plant, from 99
"typical" run (Run A-7)
One tpd pilot plant; average 99
of six operating conditions
(800-840°F reactor tempera-
ture, 40-100 minutes
residence time)
One tpd pilot plant; operat- 99
ing conditions: 840°F
reactor temperature, 60
minutes residence time;
average of seven yield
periods
75 Ib per day development 99
unit; average of eight
operating conditions (800-
880°F reactor temperature;
25-100 minutes residence
time)
75 Ib per day development 99
unit; operating conditions:
880°F reactor temperature,
25 minutes residence time;
average of 6 yield periods
One tpd pilot plant, 91
(DuPont "Notebook" Sample
No. 16928)
PDU, syncrude mode; rerun 92
naphtha (UOP Sample No.
3531-1-2)
PDU (Ashland oil sample) 96
Derived from PDU atmos- 97
pheric still overhead and
vacuum still overhead
streams, fuel oil mode
(analyzed by BETC)t
-------
Material Process
Coal raw H-Coal
naphtha
Table 249 (Continued)
Coal Type Value (wt. %) Sample Description/Source Reference
IL No. 6
(Monterey
Mine)
0.212
Hydro-
treated
coal
naphtha
SRC-1
SRC-11
IL No. 6 3.0
KY No. 9 0.26
Powhattan
No. 5
0.00008
EDS
IL No. 6
(Monterey
Mine)
0.00002
H-Coal IL No. 6 0.000063
Coal-
derived
gasoline
SRC-11
Powhattan
No. 5
0.00001
(Period l)
0.00001
(Period 2)
0.00001
(Period 3)
0.00001
(Period 4)
0.00001
(Period 5)
0.00001
(Period 6)
Derived from PDU atmos- 97
pheric still overhead and
vacuum still overhead
streams, syncrude mode
(analyzed by BETC)f
PDU, syncrude mode 109
Wilsonville pilot plant 82
(APCI Sample No. 1934CB)
Bench-scale continuous 85
hydrotreating of UOP coal
raw naphtha Sample No.
3777-1 (UOP Sample No.
3777-2, UOP Research Plant
505, Run 874)
Bench-scale continuous 87
hydrotreating of UOP
coal raw naphtha Sample No.
3531-7, moderate severity
hydrotreatment (UOP Sample
No. 3531-12, UOP Research
Plant 629, Run 218)
Bench-scale continuous 92
hydrotreating of UOP coal
raw naphtha Sample No.
3531-1-2, moderate severity
hydrotreatment (UOP Sample
No. 3531-4, UOP Research
Plant 629, Run 215).
Operating conditions:
LHSV/LHSV, 0.125; P-P
(base), 450 psig
Bench-scale continuous 85
platforming of hydrotreated
coal naphtha Sample No.
3777-2 (UOP Research Plant
636, Run 335)§
(Continued)
520
-------
Table 249 (Concluded) (
Material^ Process Coal Type Value (wt. %} Sample Description/Source Reference
Coal-
derived
gasoline
EDS
IL No. 6 0.00001
(Monterey (Period l)t
Mine) 0.00001
(Period 2)
0.00001
(Period 3)
0.00001
(Period 4)
0.00001
(Period 5)
0.00001
(Period 6)
0.00001
(Period 7)
0.00001
(Period 8)
0.00001
(Period 9)
0.00001
(Period 10)
Bench-scale continuous
platforming of moderately
hydrotreated coal naphtha
Sample No. 3531-12 (UOP
Research Plant 508, Run
1456)#
Explanatory Notes
87
*See General Comments section, Note 2, for summary of operating conditions used.
'''See General Comments section, Note 3, for summary of operating conditions used.
fEach period refers to a run time having a characteristic set of operating
conditions.
§See General Comments section, Note 4, for summary of operating conditions used.
General Comments section, Note 5, for summary of operating conditions used.
521
-------
Table 250. Carbon Content
Material Process Coal Type Value (wt. %) Sample Description/Source^ Reference
Coal raw SRC-1
naphtha
SRC-II
EDS
KY No. 9 83.26
KY No. 9 83.39
KY No. 9 85.99
KY No. 9 84.43
KY No. 9 84.3
and 14
Powhattan 85.87
No. 5
IL No. 6 86.24
(Monterey
Mine)
IL No. 6 85.25
IL No. 6 84.66
IL No. 6 84.70+0.10
(Monterey
Mine)
IL No. 6 84.66+0.76
(Monterey
Mine)
IL No. 6 85.88+0.46
(Monterey
Mine)
Wilsonville pilot plant, 82
SRC unit (Run No. 220,
APCI Sample No. 1896CB)
Wilsonville pilot plant, 82
SRC unit (Run No. 225,
APCI Sample No. 1910CB)
Wilsonville pilot plant, 82
SRC unit sample washed
with caustic prior to
analysis, (Run No. 220,
APCI Sample No. 1933CB)
Wilsonville pilot plant, 82
Alcoa coker unit (APCI
Sample No. 1899CB)
Ft. Lewis pilot plant* 83
Ft. Lewis pilot plant 85
(UOP Sample No. 3777-1)
One tpd pilot plant; 87
once-through mode
(UOP Sample No. 3531-7)
One tpd pilot plant; 90
once-through mode
(SWRI Sample No. G-C2)
One tpd pilot plant, from 99
"typical" run (Run A-7)
One tpd pilot plant; 99
average of three operating
conditions (840"F reactor
temperature; 15-40 minutes
residence time)
One tpd pilot plant; 99
operating conditions:
840*F reactor temperature,
40 minutes residence time;
average of ten yield
periods
75 Ib per day development 99
unit; average of six
operating conditions
(800-880°F reactor
temperature; 25-100 min-
utes residence time)
(Continued)
522
-------
Table 250 (Continued)
Material Process Coal Type Value (wt. %) Sample Description/Source Reference
Coal raw EDS IL No. 6 85.93+_0.24 75 Ib per day development 99
naphtha (Monterey unit; operating conditions:
Mine) 840°F reactor temperature,
40 minutes residence time;
average of 21 yield periods
Wyodak 85.14 One tpd pilot plant, once- 90
through mode (SWRI Sample
No. G-C3)
Wyodak 84.70 One tpd pilot plant, from 99
"typical" run (Run A-7)
Wyodak 84.69+0.68 One tpd pilot plant; average 99
of six operating conditions
(800-840°F reactor tempera-
ture, 40-100 minutes
residence time)
Wyodak 84.70+1.17 One tpd pilot plant; operat- 99
ing conditions: 840°F
reactor temperature; 60
minutes residence time;
average of seven yield
periods
Wyodak 86.41+1.36 75 Ib per day development 99
unit; average of eight
operating conditions (800-
880°F reactor temperature;
25-100 minutes residence
time)
Wyodak 86.68+0.14 75 Ib per day development 99
unit; operating conditions:
880°F reactor temperature,
25 minutes residence time,
average of 6 yield periods
NA 84.20 One tpd pilot plant 91
(DuPont "Notebook" Sample
No. 16928)
PDU, syncrude mode; rerun 92
naphtha (UOP Sample No.
3531-1-2)
PDU, syncrude mode 109
H-Coal IL No. 6 85.90
IL No. 6 84.9
(Continued)
523
-------
Table 250 (Continued)
Material Process Coal Type Value (wt. %)
SRC-11 Powhattan 86.00
Hydro-
treated
coal
naphtha
Powhattan
No. 5
EDS
IL No. 6
(Monterey
Mine)
86.18
H-Coal IL No. 6
86.45
Coal-
derived
gasoline
SRC-II Powhattan 87.73
No. 5 (Period l)t
87.61
(Period 2)
87.31
(Period 3)
87.89
(Period 4)
QQ fl
OO.OO
(Period 5)
87.26
(Period 6)
Sample Description/Source Reference
Bench-scale continuous 85
hydrotreating of UOP coal
raw naphtha Sample No.
3777-1 (UOP Sample No.
3777-2, UOP Research Plant
505, Run 874)
Bench-scale continuous 87
hydrotreating of UOP
coal raw naphtha Sample No.
3531-7, moderate severity
hydrotreatment (UOP Sample
No. 3531-12, UOP Research
Plant 629, Run 218)
Bench-scale continuous 92
hydrotreating of UOP coal
raw naphtha Sample No.
3531-1-2, moderate severity
hydrotreatment (UOP Sample
No. 3531-4, UOP Research
Plant 629, Run 215).
Operating conditions:
LHSV/LHSV, 0.125; P-P
(base), 450 psig
Bench-scale continuous 85
platforming of hydrotreated
coal naphtha Sample No.
3777-2 (UOP Research Plant
636, Run 335)#
(Continued)
524
-------
Table 250 (Concluded)
Material Process Coal Type Value (wt. %) Sample Description/Source Reference
Coal-
derived
gasoline
EDS
IL No. 6 89.30
(Monterey (Period l)t
Mine)
H-Coal IL No. 6
89.48
(Period 2)
88.51
(Period 3)
88.18
(Period 4)
88.89
(Period 5)
88.06
(Period 6)
88.35
(Period 7)
88.96
(Period 8)
90.35
(Period 9)
89.73
(Period 10)
88.92
(Period 5)f
88.20
(Period 10)
88.96
(Period 14)
Explanatory Notes
Bench-scale continuous
platforming of moderately
hydrotreated coal naphtha
Sample No. 3531-12 (UOP
Research Plant 508, Run
1456)§
From bench-scale continuous
platforming of moderately
hydrotreated coal naphtha
Sample No. 3531-4 (UOP
Research Plant 636, Run No.
220 )#
87
92
*See General Comments section, Note 2, for summary of operating conditions used.
'''See General Comments section, Note 4, for summary of operating conditions used.
fEach period refers to a run time having a characteristic set of operating
conditions.
§See General Comments section, Note 5, for summary of operating conditions used.
*See General Comments section, Note 6, for summary of operating conditions used.
525
-------
Table 251. Hydrogen Content
Material Process Coal Type Value (wt. %) Sample Description/Source Reference
Coal raw SRC-I
naphtha
SRC-II
EDS
KY No. 9 11.85
KY No. 9^ 11.93
KY No. 9 13.28
KY No. 9 10.28
NA
12.18
KY No. 9 11.6
and 14
Powhattan 12.91
No. 5
IL No. 6 11.80
(Monterey
Mine)
IL No. 6 12.45
IL No. 6 12.34
IL No. 6 12.39+0.26
(Monterey
Mine)
IL No. 6 12.34+0.54
(Monterey
Mine)
IL No. 6 13.24+0.86
(Monterey
Mine)
Wilsonville pilot plant, 82
SRC unit (Run No. 220,
APCI Sample No. 1896CB)
Wilsonville pilot plant, 82
SRC unit (Run No. 225,
APCI Sample No. 1910CB)
Wilsonville pilot plant, 82
SRC unit sample washed
with caustic prior to
analysis, (Run No. 220,
APCI Sample No. 1933CB)
Wilsonville pilot plant, 82
Alcoa coker unit (APCI
Sample No. 1899CB)
Wilsonvile pilot plant 84
Ft. Lewis pilot plant* 83
Ft. Lewis pilot plant 85
(UOP Sample No. 3777-1)
One tpd pilot plant; 87
once-through mode
(UOP Sample No. 3531-7)
One tpd pilot plant; 90
once-through mode
(SWRI Sample No. G-C2)
One tpd pilot plant, from 99
"typical" run (Run A-7)
One tpd pilot plant; 99
average of three operating
conditions (840T reactor
temperature; 15-40 minutes
residence time)
One tpd pilot plant; 99
operating conditions:
840'F reactor temperature,
40 minutes residence time;
average of ten yield
periods
75 Ib per day development 99
unit; average of six
operating conditions
(800-880°F reactor
temperature; 25-100 min-
utes residence time)
(Continued)
526
-------
Table 251 (Continued)
Material Process Coal Type Value (wt. %) Sample Description/Source Reference
Coal raw
naphtha
EDS
IL No. 6
(Monterey
Mine)
Wyodak
Wyodak
Wyodak
Wyodak
Wyodak
Wyodak
H-Coal
NA
IL No. 6
13.18+0.13
12.56
12.42
12.33+0.26
12.42+0.!
12.87+0.14
12.77+0.10
12.04
12.80
IL No. 6 11.60
(Continued)
527
75 Ib per day development 99
unit; operating conditions:
840°F reactor temperature,
40 minutes residence time;
average of 21 yield periods
One tpd pilot plant, once- 90
through mode (SWRI Sample
No. G-C3)
One tpd pilot plant, from 99
"typical" run (Run A-7)
One tpd pilot plant; average 99
of six operating conditions
(800-840'F reactor tempera-
ture, 40-100 minutes
residence time)
One tpd pilot plant; operat- 99
ing conditions: 840T
reactor temperature, 60
minutes residence time;
average of seven yield
periods
75 Ib per day development 99
unit; average of eight
operating conditions (800-
8809F reactor temperature;
25-100 minutes residence
time)
75 Ib per day development 99
unit; operating conditions:
880°F reactor temperature,
25 minutes residence time;
average of 6 yield periods
One tpd pilot plant (DuPont 91
"Notebook" Sample No. 16928)
PDU, syncrude mode; rerun 92
naphtha (UOP Sample No.
3531-1-2)
PDU,syncrude mode 109
-------
Table 251 (Continued)
Material Process Coal Type Value (wt. %) Sample Description/Source Reference
Hydro-
treated
coal
naphtha
SRC-II
Powhattan
No. 5
13.66
EDS
IL No. 6
(Monterey
Mine)
13.13
H-Coal IL No. 6 13.59
Coal-
derived
gasoline
SRC-II Powhattan 11.36
No. 5 (Period l)t
10.91
(Period 2)
10.55
(Period 3)
11.35
(Period 4)
10.42
(Period 5)
10.75
(Period 6)
Bench scale continuous 85
hydrotreating of UOP coal
raw naphtha Sample No.
3777-1 (UOP Sample No.
3777-2, UOP Research Plant
505, Run 874)
Bench scale continuous 87
hydrotreating of UOP
coal raw naphtha Sample No.
3531-7, moderate severity
hydrotreatment (UOP Sample
No. 3531-12, UOP Research
Plant 629, Run 218)
Bench-scale continuous 92
hydrotreating of UOP coal
raw naphtha Sample No.
3531-1-2, moderate severity
hydrotreatment (UOP Sample
No. 3531-4, UOP Research
Plant 629, Run 215).
Operating conditions:
LHSV/LHSV, 0.125; P-P
(base), 450 psig
Bench scale continuous 85
platforming of hydrotreated
coal naphtha Sample No.
3777-2 (UOP Research Plant
636, Run 335)?
(Continued)
528
-------
Table 251 (Concluded)
Material Process Coal Type Value (wt. %} Sample Description/Source Reference
Coal-
derived
gasoline
EDS
IL No. 6
(Monterey
Mine)
H-Coal IL No. 6
Explanatory Notes
10.40
(Period I)"1"
10.74
(Period 2)
11.23
(Period 3)
11.45
(Period 4)
11.43
(Period 5)
11.59
(Period 6)
11.60
(Period 7)
10.51
(Period 8)
10.18
(Period 9)
9.94
(Period 10)
10.74
(Period 5)1"
11.76
(Period 10)
10.11
(Period 14)
Bench-scale continuous
platforming of moderately
hydrotreated coal naphtha
Sample No. 3531-12 (UOP
Research Plant 508, Run
1456)§
From bench-scale continuous
platforming of moderately
hydrotreated coal naphtha
Sample No. 3531-4 (UOP
Research Plant 636, Run
No. 220)#
87
92
*See General Comments section, Note 2, for summary of operating conditions used.
'''See General Comments section, Note 4, for summary of operating conditions used.
fEach period refers to a run time having a characteristic set of operating
conditions.
§See General Comments section, Note 5, for summary of operating conditions used.
*See General Comments section, Note 6, for summary of operating conditions used.
529
-------
Table 252A. Trace Elements Content (Qualitative Data)
Material Process Coal Type Trace Metals Present Sample Description/Source Reference
Coal
raw
naphtha
SRC-1
en
co
o
EDS
KY No. 9
KY No. 9
Major Si Wilsonville pilot plant,
Minor Na, Fe, K, Ca, SRC unit (Run No. 220,
Ti, Mg APCI Sample No. 1896CB)
Trace Ni, Cr, Ag,
Cu, B, Mn,
Pd, Sn
Major Si Wilsonville pilot plant,
Minor Ca, Zn, Fe, K, SRC unit (Run No. 225,
Al
Trace Ti, Cr, Mn,
Ni, Cu, Pb,
Br, Zr
APCI Sample No. 1910CB)
IL No. 6 Fe (XRF)
Wyodak None (XRF)
One tpd pilot plant,
once-through mode (SWRI
Sample No. G-C2)
One tpd pilot plant,
once-through mode
(SWRI Sample No. G-C3)
82
82
90
90
-------
Table 252B. Trace Elements Content (Quantitative Data) (ppmw)
Material
Coal
raw
naphtha
01
to
— '
Hydro-
treated
coal
naphtha
Coal-
derlved
gasoline
Process Coal Type
SRC- I MA
HA
NA
EOS IL No. 6
SRC- 11 NA
H-Coal IL No. 6
a NO. 6
Kyodak
U. KY
No. 11
HA NA
NA HA
Tl
NA
<1.3
<1.0
NA
<0.012
ND(2)
NA
»(2)
0.01
NA
HA
V
HA
<0.01
<0.1
NA
<0.02
0.1
0.2
O.I
<0.02
HA
NA
Ca
NA
<10
0.21
0.670
O.U
0.08
NA
0.12
0.21
HA
NA
*1
NA
0.92
NA
NA
<0.4
2.3
NA
2.9
<0.3
NA
NA
£1
HA
6.19
HA
HA
HA
NA
NA
HA
NA
NA
NA
H£
NA
<0.001
HA
0.029
<0.006
NA
HA
HA
HA
HA
HA
As
0. 105*
0.002
0.010
HA
HA
0.006f
0.005
HA
0.023
0.002
HA
HA
Sb
0.006+
0.001
<1
NA
HA
0.0041
HA
HA
HA
NA
NA
NA
Se
<0.009
0.023
NA
HA
0.00006
HA
NA
HA
HA
HA
HA
Hj
<0.01
7.43*
NA
HA
HA
ND
(0.02)
HA
0.013
ND
(0.004)
HA
HA
ST.
0.25+
0.004"
0.018
HA
HA
HA
HA
HA
NA
HA
HA
NA
.11
NA
<0.14
HA
0.049
<0.05
0.1
0.2
O.I
<0.5
HA
NA
Co
0.0044*
0.0006
0.010
HA
HA
<0.04
ND
(0.01)
NA
ND
(0.02)
NO
(0.04)
HA
HA
Cr
0.54+
0.02
0.012
HA
HA
<0.06
NA
NA
HA
NA
NA
HA
Fe
58*2
0.86
4.8
4
0.44
0.4
0.5
0.9
0.7
NA
HA
Ha
0.51+
0.01
0.78
0.60
0.720
0.84
0.3
NA
0.32
3.4
HA
NA
(Continued)
-------
Table 252B (Continued)
Material
Coal
raw
naphtha
en
CO
ro
Hydro-
treated
coal
naphtha
Coal-
de rived
gasoline
Process Coal Type
SRC- I NA
NA
HA
EDS IL No. 6
SRC-H NA
H-Coal IL No. 6
IL No. 6
Uyodak
U. KY
No. U
HA NA
NA NA
ftb
<0.06
<0.02
NA
NA
NA
NA
NA
NA
NA
NA
HA
Cs
<0.002
2.89*
NA
NA
HA
NA
NA
NA
NA
NA
NA
K
NA
«U
0.12
0.320
<0.02
0.0?
HA
NA
1.3
HA
HA
Sc
0.0044+
o.ooor
0.063*
HA
NA
NA
NA
HA
NA
HA
HA
HA
Tb
<0.0002
<0.6*
NA
NA
NA
NA
NA
NA
NA
NA
NA
Uu
<0.0001
1.40*
NA
NA
NA
NA
NA
NA
NA
NA
NA
Sra
0.0023+
0.0001
<0.046*
NA
NA
NA
NA
NA
NA
NA
NA
NA
Ce
NA
<7*
HA
HA
HA
HA
NA
NA
NA
NA
HA
La
0.0125+
0.008 "
<0.7
NA
NA
HA
HA
HA
NA
NA
NA
NA
Sr
NA
<0.3
NA
NA
<0.002
HA
HA
HA
HA
NA
HA
Ba
<2
<0.3
NA
0.013
<0.002
HA
NA
NA
HA
NA
NA
TJi
<0.001
<0.7*
NA
NA
NA
HA
NA
HA
HA
NA
NA
Hf
<0.004
<0.7*
NA
NA
NA
NA
NA
HA
HA
NA
NA
Ta
NA
<0.9*
NA
NA
NA
NA
NA
NA
NA
NA
HA
Ga
NA
6.15*
NA
NA
NA
NA
NA
HA
NA
NA
NA
Zr
HA
<0.2
NA
NA
NA
NA
NA
NA
HA
NA
NA
(Continued)
-------
Material Process Coal Type Cu
Table 252B (Concluded)
Zn M PJ) S_l Mo Sample Description/Source Reference
en
CO
co
Coal SRC- 1
raw
naphtha
EDS
SRC- 1 1
H-Coal
Hydro- NA
treated
coal
naphtha
Coal- NA
derived
gasoline
NA
NA
NA
IL No. 6
NA
IL No. 6
IL No. 6
Wyodak
W. KY
No. 11
—
—
NA
0.037
NA
NA
0.18
NA
NA
NA
NA
0.86+
0.04
0.02
NA
NA
0.35
NA
NA
NA
NA
NA
NA
NA
0.160
0.08
0.01
NA
0.03
0.09
--
__
NA
NA
NA
NA
<0.16
0.2
NA
0.1
<0.15
NA
NA
NA
NA
2.3
34
NA
27
32
NA
NA
NA
NA
<0.08
NO
(0.01)
NA
NO
(0.02)
<0.02
Ft. Lewis pilot plant§
Ft. Lewis pilot plant
Wilsonville pilot plant*
One tpd pilot plant once-
through mode
Ft. Lewis pilot plant
PDU, syncrude mode
PDU (Ashland oil sample)
PDU, syncrude mode
PDU, syncrude mode
--
146
106
84
107
125
109
96
109
109
«
— __
Explanatory Notes
*Values in ppb
t<0.1 ppmw of phosphorous also reported for this sample.
^Determined by flameless AAS. All other elements determined by
^Determined by neutron activation analysis.
ICP.
-------
Table 253. Saturates, Olefins
Material Process Coal Type Value (vol. X)
A. Saturates
Coal raw SRC-I KY No. 9 39.90* (wt. X)
naphtha 59.01"
KY No. 9 36.39* (wt. X)
KY No. 9 79.90* (wt. X)
and Aromatics Contents
Sample Description/Source Reference
SRC- I I Powhattan 68. 6?
No. 5
EDS IL No. 6 46.2t,§
(Monterey
Mine)
H-Coal IL No. 6
IL No. 6
(Burning
Star
Mine)
70. 1
66.2**
33.9 (wt. X)
IL No. 6 42.6 (wt. X)
(Monterey
Mine)
Wilsonville pilot plant, 82
SRC unit (Run No. 220,
APCI Sample No. 1896CB)
Wilsonville pilot plant, 82
SRC unit (Run No. 225,
APCI Sample No. 1910CB)
Wilsonville pilot plant, 82
sample washed with caustic
prior to analysis, (Run
No. 220, APCI Sample
No. 1933CB)
Ft. Lewis pilot plant 85
(UOP Sample No. 3777-1)
One tpd pilot plant; 87
once-through mode
(UOP Sample No. 3531-7)
POU, syncrude mode; rerun 92
naphtha (UOP Sample No.
3531-1-2)
Derived from PDU atmospheric 97
still overhead and vacuum
still overhead streams,
fuel oil mode (analyzed
by BETC)tt
Derived from PDU atmospheric 97
still overhead and vacuum
still overhead streams,
syncrude mode (analyzed by
BETC)tt
(Continued)
534
-------
Material Process Coal Type
B. Qlefins
Coal raw SRC-I KY No. 9
naphtha
Table 253 (Continued)
Value (vol. %} Sample Description/Source Reference
SRC-11
EDS
Powhattan
No. 5
IL No. 6
(Monterey
Mine)
Wyodak
H-Coal IL No. 6
IL No. 6
(Burning
Star
Mine)
IL No. 6
(Monterey
Mine)
10.9*
1.5??
(wt.
8.4?
9.9?
IL No. 6 4.9
0
.
5.5?
5.9 (wt. X)
3.6 (wt. %)
Wilsonville pilot plant 82
(Run No. 220, APCI
Sample No. 1896CB)
Ft. Lewis pilot plant 85
(UOP Sample No. 3777-1)
One tpd pilot plant; 87
once-through mode
(UOP Sample No. 3531-7)
One tpd pilot plant; 90
once-through mode
(SWRI Sample No. G-C2)
One tpd pilot plant; 90
once-through mode (SWRI
Sample No. 6-C3)
POU, syncrude mode; rerun 92
naphtha (UOP Sample No.
3531-1-2)
Derived from PDU atmospheric 97
still overhead and vacuum
still overhead streams,
fuel oil mode (analyzed
by BETC)tt
Derived from PDU atmospheric 97
still overhead and vacuum
still overhead streams,
syncrude mode (analyzed by
BETC)tt
(Continued)
535
-------
Table 253 (Continued)
Material Process Coal Type Value (vol. X) Sample Description/Source Reference
C. Aromatics
Coal raw SRC-1 KY No. 9
naphtha
SRC-II
EDS
30.11"
25.37* (wt. X)
KY No. 9 6.99* (wt. X)
KY No. 9 Nil* (wt. X)
Powh att an
No. 5
IL No. 6
(Monterey
Mine)
23.0*'§§
25.3f
IL No. 6 30.8
Wyodak
H-Coal IL No. 6
IL No. 6
(Burning
Star
Mine)
IL No. 6
(Monterey
Mine)
32
24.7#
18.6f
34.2
31.6
Wilsonville pilot plant 82
(Run No. 220, APCI
Sample No. 1896CB)
Wilsonville pilot plant 82
(Run No. 225, APCI
Sample No. 1910CB)
Wilsonville pilot plant", 82
sample washed with caustic
prior to analysis, (Run
No. 220, APCI Sample
No. 1933CB)
Ft. Lewis pilot plant 85
(UOP Sample No. 3777-1)
One tpd pilot plant; 87
once-through mode
(UOP Sample No. 3531-7)
One tpd pilot plant; 90
once-through mode (SWRI
Sample No. G-C2)
One tpd pilot plant; 90
once-through mode (SWRI
Sample No. G-C3)
POU, syncrude mode; rerun 92
naphtha (UOP Sample No.
3531-1-2)
Derived from PDU atmospheric 97
still overhead and vacuum
still overhead streams,
fuel oil mode (analyzed
by BETC)tt
Derived from PDU atmospheric 97
still overhead and vacuum
still overhead streams,
syncrude mode (analyzed by
BETC)tt
(Continued)
536
-------
Table 253 (Continued)
Material Process Coal Type Value (vol. %) Sample Description/Source Reference
A. Saturates
Hydro-
treated
coal
naphtha
SRC-II
Powhattan
No. 5
81. 2#
78. Of
EDS
IL No. 6
(Monterey
Mine)
79.
73.
8?
H-Coal IL No. 6
81.1*
82.4f
B. Olefins
Hydro-
treated
coal
naphtha
SRC-11 Powhattan NDr"
No. 5
H-Coal IL No. 6 0.0#
(Continued)
537
Bench-scale continuous 85
hydrotreating of UOP coal
raw naphtha Sample
No. 3777-1 (UOP Sample
No. 3777-2, UOP Research
Plant 505, Run 874)
Bench-scale continuous 87
hydrotreating of UOP
coal raw naphtha Sample
No. 3531-7, moderate
severity hydrotreatment
(UOP Sample No. 3531-12,
UOP Research Plant 629,
Run 218)
Bench-scale continuous 92
hydrotreating of UOP coal
raw naphtha Sample No.
3531-1-2, moderate severity
hydrotreatment (UOP
Sample No. 3531-4, UOP
Research Plant 629, Run
215). Operating condi-
tions: LHSV/LHSV, 0.125;
P-P (base), 450 psig
Bench-scale continuous 85
hydrotreating of UOP coal
raw naphtha Sample
No. 3777-1 (UOP Sample
No. 3777-2, UOP Research
Plant 505, Run 874)
Bench-scale continuous 92
hydrotreating of UOP coal
raw naphtha Sample No.
3531-1-2, moderate severity
hydrotreatment (UOP
Sample No. 3531-4, UOP
Research Plant 629, Run
215). Operating condi-
tions: LHSV/LHSV, 0.125;
P-P (base), 450 psig
-------
Table 253 (Concluded)
Material Process Coal Type Value (vol. %} Sample Description/Source Reference
C. Aromatics
Hydro-
treated
coal
naphtha
SRC-II
Powhattan
No. 5
EDS
IL No. 6
(Monterey
Mine)
20.1*+
21.62*
H-Coal IL No. 6
18.8# Bench-scale continuous 85
22.Of hydrotreating of UOP coal
raw naphtha Sample
No. 3777-1 (UOP Sample
No. 3777-2, UOP Research
Plant 505, Run 874)
Bench-scale continuous 87
hydrotreating of UOP
coal raw naphtha Sample
No. 3531-7, moderate
severity hydrotreatment
(UOP Sample No. 3531-12,
UOP Research Plant 629,
Run 218)
18.9# Bench-scale continuous 92
17.6f hydrotreating of UOP coal
raw naphtha Sample No.
3531-1-2, moderate severity
hydrotreatment (UOP
Sample No. 3531-4, UOP
Research Plant 629, Run
215). Operating condi-
tions: LHSV/LHSV, 0.125;
P-P (base), 450 psig
Coal- NA
derived
gasoline
Explanatory Notes
*Determined via APCI adsorption chromatography method.
tpONA analysis (after polars removed).
fMS hydrocarbon types, vol. %.
§Includes 8.7 vol. % polars.
#Flame ionization analysis (FIA).
**Includes 4.2 vol. % polars.
''"''See General Comments section, Note 3, for summary of operating conditions
used.
ffoiefins determined by bromination of the sample and reanalysis by GC/MS
§§Includes 6.8 vol. % polars.
538
-------
Table 254.
Material Process Coal Type
Coal raw SRC-I KY No. 9
naphtha
Detailed Hydrocarbon Class/Compound Analysis*
en
co
Compound/Class
Toluene
Cyclohexane
Methyl-Cyclohexane
Methyl-Cyclopentane
Hexane
2-Methyl-Pentane
Pentane
Heptane
D1-Methyl-Benzene
2,3-D1hydro-
Indene
Decane
Octane
1,2,3,4-Tetrahydro-
Naphthalene
Nonane
Ethyl-Cyclohexane
Ethyl-Methyl-
Benzene
TMmethyl-
Benzene
Wt % Sample Description/Source Reference
5.7t
2.6
2.4
2.2
2.2
2.1
2.1
1.8
1.8
1.8
1.7
1.6
1.6
1.5
1.5
1.4
1.4
Wilsonville pilot plant,
SRC unit (Run No. 220
APCI Sample No. 1896CB)
82
(Continued)
-------
Table 254 (Continued)
Material Process Coal Type Compound/Class
Wt % Sample Description/Source Reference
Coal raw
naphtha
en
-£»
o
SRC-I KY No. 9 Toluene
Cyclohexane
Nonane
Methyl-Cyclopentane
Methyl-Cyclohexane
Hexane
Pentane
2-Methyl-Pentane
2,3-D1hydro-
Indene
Heptane
Methyl-Benzene
1,2,3,4-Tetrahydro-
Naphthalene
Octane
Ethyl-Methyl-
Benzene
Ethy1-Methyl-
Cyclopentane
Dimethyl-Benzene
Methyl-2,3-D1-
hydro-Indene
6.6*
3.0
2.8
2.7
2.6
2.6
2.4
2.2
2.0
2.0
1.9
NA
1.7
1.5
1.5
1.4
1.3
Wilsonville pilot plant,
SRC unit (Run No. 225
APCI Sample No. 1910CB)
82
(Continued)
-------
Material Process Coal Type
Coal raw SRC-I KY No. 9
naphtha
en
Table 254 (Continued)
Compound/Class Wt %
Dimethyl -Benzene
Toluene
Ethyl-Benzene
Dimethyl -Benzene
Nonane
2,3-Dlhydro-
Indene
Naphthalene
Ethyl -Methyl-
Benzene
Trlmethyl -Benzene
4/5-Methyl-2,3-
D1 hydro- Indene
Dodecane
Undecane
Methyl -Benzene
1,2,3,4-Tetrahydro-
Naphthalene
Decane
Methyl -2, 3-
di hydro- Indene
Trlmethyl -Benzene
5.8t
5.6
5.0
2.1
2.0
1.8
1.7
1.6
1.6
1.5
1.3
1.9
1.3
1.3
1.2
0.99
Sample Description/Source Reference
Wllsonvllle pilot plant, 82
Alcoa coker unit (APCI
Sample No. 1899CB)
(Continued)
-------
Material Process
Coal raw
naphtha
SRC-1
en
Table 254 (Continued)
Coal Type Compound/Class Ut %
NA n-Octane 1.60
n-Nonane 0.87
n-Decane 0.98
n-Undecane 0.39
n-Oodecane 0.14
n-Tridecane 0.047
n-Tetradecane 0.017
n-Pentadecane 0.006
n-Hexadecane 0.001
n-Heptadecane 0.001
o-Ethylbenzene 0.98
C3-Benzene 0.39
Indan 0.43
Methylindan 0.051
Methylindan 0.018
Methyllndan 0.024
Dimethylindan <.0005
Tetralin 0.033
Dimethyltetralln <0.0005
6-Methyltetralin 0.0110
Naphthalene 0.163
Sample Description/Source Reference
Ft. Lewis pilot plant* 146
(Continued)
-------
Table 254 (Continued)
Material Process
Coal raw
naphtha
SRC-1
en
-P»
to
Coal Type Compound/Class Ut %
NA 2-Methylnaphthalene 0.069
1-Methylnaphthalene 0.011
Dimethylnaphthalene 0.008
Dimethylnaphthalene 0.007
Dimethylnaphthalene 0.010
Biphenyl 0.0080
Acenaphthylene 0.0002
Dimethylbiphenyl 0.0015
Dimethylbiphenyl 0.0021
Dibenzofuran 0.0008
Xanthene 0.0010
Dibenzothiophene 0.0003
Dimethyldibenzothiophene 0.0005
Fluorene 0.0015
9-Methylfluorene 0.0015
1-Methylfluorene 0.001
Anthracene/phenanthrene 0.0025
Methylphenanthrene 0.0006
1-Methylphenanthrene 0.0006
C2-Anthracene 0.0006
Fluoranthene 0.0015
Dihydropyrene 0.0006
Pyrene 0.002
Sample Description/Source Reference
Ft. Lewis pilot plant* 146
(Continued)
-------
Table 254 (Continued)
Material Process Coal Type Series Compound/Class
Wt
Vol. % Sample Description/Source Reference
Coal raw SRC- 1 1 Powhattan CnH2n+2
naphtha No. 5
cnH2n
cnH2n-2
^nH2n-4
cnH2n-6
cnH2n-10
cnH2n-12
tn
-P.
Paraffins
Naphthenes
Monocycloparaffins
Cyclopentanes
Cyclohexanes
Bi.Dicycloparaffins
Tricycloparaffins
Total Naphthenes
Aromatics
Alkylbenzenes
Indanes/Tetralins
Dinaphthenebenzenes
Naphthalenes
Total Aromatics
Olefinst
Monoolef ins
Diolefins and/or
monocycloolef ins
Triolefins and/or
dicycloolefins
Total Olefins
27
28
ND
ND
7
1
36
17
0
<0
<0
18
1
5
1
8
.8*
.4
.1
.0
.5
.4
.7
.1
.05
.25
.9
.1
.4
.4
31
28
ND
ND
7
1
37
15
0
.5*
.9
.2
.0
.1
.6
.6
Trace
Trace
16
2
5
1
7
.2
.1
.0
.3
.4
Ft. Lewis pilot plant
(UOP Sample No. 3777-1)
85
(Continued)
-------
Table 254 (Continued)
Material Process Coal Type Series Compound/Class
Ut % Vol. % Sample Description/Source Reference
Coal raw
naphtha
EDS
IL No. 6
(Monterey
Mine)
en
-p.
01
CnH2n-2
CnH2n-4
CnH2n+2 Paraffins
Naphthenes
Monocycloparaff ins
Cyclopentanes
Cyclohexanes
Bi.Dicycloparaffins
Tricycloparaffins
Total Naphthenes
Aromatic s
Alkylbenzenes
CnH2n-8 Indanes/Tetralins
CnH2n-10 Dinaphthenebenzenes
CnH2n-12 Naphthalenes
Total Aromatics
Oleflnsf
Monoolefins
Diolefins and/or
monocycloolef ins
Triolefins and/or
dicycloolef ins
Total Olefins
11.3 13.2
NO
9.8
14.1
10.9
7.4
42.2
17.5
8.7
0.5
Trace
26.7
2.3
5.4
1.4
9.1
NO
10.4
15.0
10.5
7.0
42.9
17.0
7.9
0.4
Trace
25.3
2.6
5.8
1.5
9.9
One tpd pilot plant;
once-through mode (UOP
Sample No. 3531-7)
87
(Continued)
-------
Table 254 (Continued)
Material Process Coal Type Series Compound/Class
Ht % Sample Description/Source Reference
Coal raw
naphtha
EDS
IL No. 6
(Monterey
Mine)
Ol
Paraffins
Naphthenes
Hydrindane
Decali n/Methy1-Hydri ndane
Benzene
Toluene
Cg-Aromatics
Cg-Aromatics
C^Q-Aromatics
Cu-Aromatics
Indane
Tetralin/Methyl-Indane
Methyl-Tetralin/Cj Indane
Indane
Methyl-Indenes
Naphthalene
Methyl-Napthalene
13.95
51.47
0.96
2.19
0.37
2.03
4.57
3.66
2.65
0.76
1.99
3.18
0.31
0.13
NO
NO
ND
One tpd pilot plant;
operating conditions:
840"F reactor temperature,
40 min-residence time,
1500 psi reactor pressure;
average of yield period
Nos. 256-265
99
(Continued)
-------
Table 254 (Continued)
Material Process Coal Type
Coal raw EDS Wyodak
naphtha
tn
Series Compound/Class Wt %
Paraffins 19.94
Naphthenes 47.02
Hydrlndane 0.28
DecalIn/Methyl Hydrlndane 4.96
Benzene 0.44
Toluene 3.34
Cg-Aromatics 5.21
Cg-Aromatics 3.80
CiQ-Aromatics 2.32
Cu-Aromatics 0.16
Indane 2.37
Tetralin/Methyl Indane 2.47
Methyl-Tetralin/Cn Indane 0.16
Indene 0.04
Methyl-Indenes NO
Naphthalene NO
Methyl-Napthalene NO
Sample Description/Source Reference
One tpd pilot plant;
operating conditions:
840T reactor temperature,
60 min-residence time,
1500 psi reactor pressure;
average of yield period
Nos. 267-270
99
(Continued)
-------
Table 254 (Continued)
Material Process Coal Type
Compound/Class ppm
Sample Description/Source Reference
Coal raw
naphtha
EDS
IL No. 6
tn
-£•
00
Butane
Pentane
Cyclopentane
Methyl Cyclopentane
Cyclohexane
Methyl Cyclohexane
C2 Cyclohexane
C6 Alkane
C7 Alkane
C8 Alkane
CIO Alkane
C6 Alkene
C7 Alkene
C8 Alkene
C6 Diene
C7 Diene
C8 Diene
C9 Alkene
C9 Diene
CIO Alkene
CIO Diene
Cll Alkene
Benzene
Toluene
C2 Benzene
C3 Benzene
C4 Benzene
3,
3,
160
,100
,200
33,000
43,000
36,000
2,200
15,000
14,000
57,000
5,800
12,000
63,000
240,000
49,000
40,000
93,000
87,000
52,000
29,000
27,000
3,500
6,000
37,000
66,000
6,400
12,000
One tpd pilot plant,
once-through mode
107
(Continued)
-------
Table 254 (Continued)
Material Process Coal Type
Compound/Class WT X Vol. %
Coal raw
naphtha
H-Coal IL No. 6 Paraffins
en
*.
UD
IL No. 6
(Burning
Star
Mine)
Napnthenes
Monocycloparaffins
Bi, Dicycloparaffins
Tricycloparaffins
Total Naphthenes
Arpmatics
Alkylbenzenes
Indanes/Tetralins
Naphthalenes
Total Aromatics
Olefinsf
Monoolefins
Oiolefins or
Monocycloolefins
Triolefins or
Di eye 1o-monoolefi ns
Total Olefins
Paraffins
Monocycloparaffins
Dicycloparaffins
Alkylbenzenes
Monocyclic benzenes
(indanes and tetralins)
Naphthalenes
Olefins
Total
9,
15.
13.
14,
11.
3.0
5.9
74.0
16.2
48.1
7.2
0.2
55.5
18.6
1.3
3.7
0.5
5.5
Sample Description/Source Reference
PDU, syncrude mode; rerun
naphtha (UOP Sample No.
3531-1-2)
92
Derived from PDU atmos-
pheric still overhead and
vacuum still overhead
streams, fuel oil mode
(analyzed by BETC)§
97
(Continued)
-------
Table 254 (Continued^
Material Process Coal Type
Compound/Class
en
o
Coal raw H-Coal
naphtha
Hydro- SRC- I I
treated
coal
naphtha
IL No. 6 Paraffins
(Monterey Monocyclopa raff Ins
Mine) Dlcycloparafflns
Alkyl benzenes
Monocyclic benzenes
(Indanes and tetralins)
Naphthalenes
Oleflns
Total
Powhattan Paraffins
No. 5 Naphthenes
Monocycloparaffins
Bi ,D1cycloparaffins
Trlcycloparaffins
Total Naphthenes
Aroma tics
Alkyl benzenes
Indanes, Tetralins
Naphthalenes
Total Aromatics
Total
10.7
21.7
13.2
14.3
11.0
3.3
3.6
77.8
25.20
47.28
5.57
0.0
52.85
21.53
0.42
0.0
21.95
100.00
IfJt % Vol. % Sample Description/Source Reference
Derived from PDU atmos-
pheric still overhead and
vacuum still overhead
streams, syncrude mode
(analyzed by BETC)§
97
Bench-scale continuous
hydrotreating of UOP coal
raw naphtha Sample No.
3777-1 (UOP Sample No.
3777-2, UOP Research
Plant 505, Run 874)
85
(Continued)
-------
Table 254 (Continued)
Material Process Coal Type
Hydro-
treated
coal
naphtha
EDS
IL No. 6
(Monterey
Mine)
01
01
H-Coal IL No. 6
Compound/Class Vol. %
Paraffins 12.90
Naphthenes
Monocycloparaffins 50.15
Bi.Dicycloparaffins 15.33
Tricycloparaffins 0.0
Total Naphthenes 65.48
Aromatics
Alkylbenzenes 17.82
Indanes, Tetralins 3.80
Naphthalenes 0.0
Total Aromatics 21.61
Total 100.00
Paraffins 15.96
Naphthenes
Monocycloparaffins 55.02
Bi, Dicycloparaffins 9.49
Tricycloparaffins 0.09
Total Naphthenes 64.60
Aromatics
Alkylbenzenes 16.54
Indanes, Tetralins 2.83
Naphthalenes 0.07
Total Aromatics 19.44
Total 100.00
Sample Description/Source Reference
Bench-scale continuous
hydrotreating of UOP coal
raw naphtha Sample No.
3531-7 (UOP Sample No.
3531-12, UOP Research
Plant 629, Run 218)
87
Bench-scale continuous
hydrotreating of UOP coal
raw naphtha Sample No.
3531-1-2, moderate severity
hydrotreatment (UOP
Sample No. 3531-4, UOP
Research Plant 629, Run
215). Operating conditions:
LHSV/LHSV, 0.125; P-P
(base), 450 psig
92
(Continued)
-------
Table 254 (Continued)
Ul
en
rv>
Material Process Coal Type Compound/Class
Coal- EDS Wyodak Acenaphthene
derived Fluorene
gasoline Phenanthrene
Fluoranthene
Benz(a)anthracene
Dimethylbenz(a)
anthracene
2-Dimethylbenz(a)
anthracene
Coronene
Total
IL No. 6 Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Benz(a)anthracene
Dimethylbenz(a)
anthracene
2-Dimethylbenz(a)
anthracene
Coronene
Total
Wyodak Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Benz(a)anthracene
Dimethylbenz(a)
anthracene
2-Dimethylbenz(a)
anthracene
Coronene
Vol.
0.0990
0.1160
0.0920
0.0720
0.0130
0.1070
0.1510
0.1360
0.1070
0.0170
Sample Description/Source Reference
0.0009 0.0027
0.0004
0.0001
Total 0.2510
(Continued)
0.0016
0.0004
0.3935 0.5230
0.0430
0.1110
0.0890
0.0540
0.0044
0.0005
0.0006
0.0001
0.3025
0.0410
0.1040
0.0710
0.0320
0.0023
0.0004
0.0004
0.0001
Reformed 370°F (end point)
naphtha from one tpd
pilot plant, having
Research Octane No.
(clear) values of 100.3
and 104.6, respectively
99
Reformed 340°F (end point)
naphtha from one tpd
pilot plant, having
Research Octane No.
(clear) value of 105.3
99
Reformed 325°F (end point)
naphtha from one tpd
pilot plant, having
Research Octane No.
(clear) value of 105.2
99
-------
Table 254 (Concluded)
Material Process Coal Type Compound/Class Period 1 Period 2 Period 3 Period 4 Period S PejrlodJS Period 9 Sample Description/Source Reference
en
tn
co
Coal- SRC- II
derived
gasoline
EOS
Coal- H-Coil
derived
gasoline
Powhattan Paraffins
No. 5 Naphthenes
Nonocycloparafflns
B1 .Dlcycloparaf f Ins
Trlcycloparaf fins
Total Naphthenes
Aroma tics
Alkylbenzenes
Indanes, Tetraltns
Naphthalenes
Total Aronatlcs
Total
IL No. 6 Paraffins
(Monterey Naphthenes
Mine) Nonocycloparafflns
BI.DIcycloparafftns
Trlcycloparaf fins
Total Naphthenes
Aroma tics
Alkylbenzenes
Indanes. Tetraltns
Naphthalenes
Total Aronatlcs
Total
IL No. 6 Paraffins
Naphthenes
Honocycloparaf f Ins
B1,D1cycloparaff1ns
Trlcycloparafftns
Total Naphthenes
Aronatlcs
Alfcylbenzenes
Indanes, Tetraltns
Naphthalenes
Total Aroma tics
Total
26.39 23.89
13.60 8.34
1.63 0.74
0.0 0.0
15.23 9.08
56.37 64.93
2.01 2.10
0.0 0.0
58.38 67.03
100.00 100.00
NA 15. 37
7.82
1.18
0.0
9.00
64.20
9.53
1.90
75.63
100.00
Period 5
18.85
8.80
0.63
0.0
9.43
61.99
7.72
2.01
71.72
100.00
20.60
7.40
0.28
0.0
7.68
69.36
2.11
0.25
71.72
100.00
NA
25.19 16.21
10.77 5.03
1.39 0.36
0.0 0.0
12.16 5.39
60.52 75.80
1.97 2.17
0.16 0.43
62.65 78.4
100.00 100.00
16.55 NA
15.56
1.02
0.0
16.58
56.24
8.88
1.75
66.87
100.00
Period 10
17.84
14.90
1.45
0.00
16.35
55.78
8.41
1.62
65.81
100.00
20.61
6.80
1.20
0.0
8.00
68.13
2.96
0.27
71.36
100.00
15.38
24.25
0.99
0.0
25.24
48.39
10.60
0.39
59.38
100.00
Period 14
11.71
4.63
0.32
0.0
4.95
74.38
6.33
2.63
83.34
100.00
NA
14.98
5.26
0.38
0.0
5.64
68.54
7.99
2.85
79.38
100.00
Bench-scale continuous
plat forming of hydro-
treated coal naphtha
Sample No. 3777-2 (UOP
Research Plant 636. Run
335)
85
Bench-scale continuous
pi atforming of hydro-
treated coal naphtha
Sample No. 3531-12 (UOP
Research Plant 508, Run
1456)
87
From bench-scale continuous
platfornlng of Moderately
hydrotreated coal naphtha
Sample No. 3531-4 (UOP
Research Plant 636, Run
No. 220)
92
Explanatory Notes
*A11 values by MS Analyses.
^Values by GC/HS analyses; the compounds listed are the twenty most prevalent compounds present In the sample.
tlhe total olefln number was obtained by StO; separation, but the mono-.dl.trl-olefin split Is estimated since no calibration coefficients are available.
§See General Comments section, Note 3, for summary of operating conditions used.
-------
Table 255. Nitrogen-, Oxygen- and Sulfur-Containing Compounds7
Material Process Coal Type
Coal raw SRC-I
naphtha
en
tn
KY No. 9
Value
Compound Class
3&4 Methyl Phenols
Phenol
2-Methyl Phenol
Total Phenols
3&4 Methyl Phenols
Phenol
2-Methyl Phenol
Total Phenols
KY No. 9 Total Phenols
KY No. 9
KY No. 9 3&4 Methyl Phenols
Phenol
2-Methyl Phenol
Wt. % Sample Description/Source Reference
7.5t
7.4
4.2
25.54
6.lt
7.4
5.6
56.65
17.92
11
5.8
5.0
Wilsonville pilot plant,
SRC unit (Run No. 220,
APCI Sample No. 1896CB)
Wilsonville pilot plant,
SRC unit (Run No. 225,
APCI Sample No. 1910CB)
Wilsonville pilot plant,
SRC unit, sample washed
with caustic prior to
analysis (Run No. 220,
APCI Sample No. 1933CB)
Wilsonville pilot plant,
Alcoa coker unit (APCI
Sample No. 1899CB)
82
82
82
82
(Continued)
-------
Table 255 (Continued)
Material Process Coal Type
Coal raw
naphtha
SRC-1
KY No. 9
KY No. 9
en
en
en
KY No. 9
Value
Compound Class
Phenol
o-Cresol
m+p-Cresol
2,6-Xylenol
o-Ethylphenol
2,4+2,5-Xylenol
m+p-Ethylphenol
2,3-Xylenol
3,4-Xylenol
Total
Phenol
o-Cresol
nH-p-Cresol
2,6-Xylenol
o-Ethylphenol
2,4+2,5-Xylenol
m+p-Ethylphenol
2,3-Xylenol
3,4-Xylenol
Total
Phenol
o-Cresol
m+p-Cresol
2,6-Xylenol
o-Ethylphenol
2,4+2,5-Xylenol
m+p-Ethylphenol
2,3-Xylenol
3,4-Xylenol
Total
(Continued)
Wt. % Sample Description/Source Reference
5.65
3.19
6.22
0.20
0.25
0.56
0.49
0.05
0.04
16.65
7.75
3.74
5.51
0.14
0.09
0.08
0.01
0.02
17.34
4.62
3.77
10.33
0.44
0.44
1.10
0.29
0.06
0.04
21.09
Wilsonvllle pilot plant,
SRC unit (Run No. 220,
APCI Sample No. 1896CB)
caustic extraction with
20% NaOH (1/1-v/v); GC
analysis of extract
Wilsonville pilot plant
SRC unit (Run No. 225,
APCI Sample No. 1910CB);
caustic extraction with
20% NaOH (1/1-v/v); GC
analysis of extract
Wilsonville pilot plant,
Alcoa coker unit (APCI
Sample No. 1899CB);
caustic extraction with
20% NaOH (1/1-v/v); GC
analysis of extract
82
82
82
-------
Table 255 (Continued)
Material Process Coal Type
Value
Compound Class
Coal raw
naphtha
SRC-11
Powhattan
No. 5
EDS
en
en
(Ti
IL NO. 6
(Monterey
Mine)
IL N. 6
(Monterey
Mine)
CnH2n-6°
CnH2n-7N
CnH2n-6°
Furans
Phenols
Naphtheno-pyridines
Thiophenes
Total
Furans
Phenols
Naphtheno-pyridines
Thiophenes
Total
Phenol
Cresols
Xylenols
Wyodak
Phenol
Cresols
Xylenols
Mt. % Vol. % Sample Description/Source Reference
3.0
ND
4.5
Trace
1.6
26.7
Trace
9.1
0.1
1.5
10.7
3.72
7.46
0.60
2.3
ND
3.2
Trace
1.3
25.3
Trace
7.4
0.1
1.2
8.7
4.64
2.70
0.15
Ft. Lewis pilot plant
(UOP Sample No. 3777-1)
85
One tpd pilot plant;
once-through mode (UOP
Sample No. 3531-7)
One tpd pilot plant;
operating conditions:
840T reactor temperature,
40 minutes residence
time, 1500 psi reactor
pressure; average of
yield period Nos. 256-265
One tpd pilot plant;
operating conditions:
840"F reactor temperature.
60 minutes residence time
87
99
99
(Continued)
-------
Table 255 (Continued)
Material Process Coal Type
Coal raw
naphtha
EDS
en
in
Value
Compound Class
IL No. 6 Ethers
Dioxane
Methyl Dioxane
C2 Dioxane
Tetrahydrofuran
Aldehydes, ketones
Methyl-N-Butyl ketone
Methyl-Iso-Butyl ketone
Phenols
0-Cresol
C2 Phenol
C3 Phenol
Hetergcycllc oxygen compounds
Methyl Furan
Benzofuran
Methyl benzofuran
C2 benzofuran
Heterpcyclic sulfur compounds
Thlophene
Methyl thlophene
C2 thiophenes
Vol. % Sample Description/Source Reference
4,100
2,400
3,000
45
880
2,000
1,300
5,900
900
11,000
22,000
14,000
800
350
1,700
16,000
One tpd pilot plant,
once-through mode
107
(Continued)
-------
Table 255 (Continued)
Material Process Coal Type
Coal raw
naphtha
H-Coal IL No. 6
en
en
00
IL No. 6
IL No. 6
(Burning
Star
Mine)
Value
Compound Class
Heterocyclic
Methyl Pyridines
C2 Pyridines
C3 Pyridines
C4 Pyridines
Ali cyclic
Aniline
Methyl Anilines
(Toluldines)
Total
Phenols
Pyridines
Thlophenes
Pyridines
Anilines
Adds
IL No. 6 Pyridines
(Monterey Anilines
Mine) Acids
Wt. % Sample Description/Source Reference
PDU, syncrude mode 109
1.3
5.3
6.5
1.6
14.7
22
63
85"
100
Vol. %
3.1
0.8
0.3
Wt. %
0.19
0.88
22.3
0.1
0.7
14.5
PDU, syncrude mode; 92
rerun naphtha (UOP
Sample No. 3531-1-2)
Derived from PDU atmos- 97
pherlc still overhead
and vacuum still overhead
streams, syncrude mode
(analyzed by BETC)t
Derived from PDU atmos- 97
pheric still overhead
vacuum still overhead
streams, syncrude mode
(analyzed by BETC)t
(Continued)
-------
Table 255 (Concluded)
en
en
Material Process Coal Type
Value
Compound Class
Coal raw H-Coal
naphtha
IL No. 6 Phenol
Methyl Phenols
C2 Phenols
C3 Phenols
Total
Wyodak Phenol
Methyl Phenols
C2 Phenols
C3 Phenols
Total
W.KY Phenol
No. 11 Methyl Phenols
C2 Phenols
C3 Phenols
Total
16
55
26
3
100
26
57
16
1
100
19
60
19
2
100
Wt. % Sample Description/Source Reference
PDU, syncrude mode
109
PDU, syncrude mode
109
PDU, syncrude mode
109
Hydro- NA
treated
coal
naphtha
Coal- NA
derived
gasoline
Explanatory Notes
*A11 values by MS analysis
Values by 6C/MS analysis
tSee General Comments section, Note 3, for summary of operating conditions used.
-------
Table 256. General Physical and Chemical Properties of Various Distillation Fractions
of Primary Coal Naphthas
Distillation Fraction
Material
Coal ran
naphtha
Process Coal Type
SRC-I Powhattan Vapor Temperature,
No. 5 5* Ut. Off
SOX Ut. Off
95X Ut. Off
Specific Gravity
(60T/60T)
Pour Point. "F
Molecular Height
Cryoscoplc
1
•F
108
152.6
343.4
0.7234
<-65.2
85
2
194
210.2
240.8
0.7701
<-65.2
95
3
237.2
249.8
257
0.7696
<-65.2
108
4
269.6
278.6
298.5
0.8125
<-65.2
114
Otst Illation
5
321.8
332.6
348.4
0.8956
<-65.2
131
fraction'*
6HC*
320t
325.4
330.8*
0.8827
NA
HA
6
374
384.8
399.2
0.9538
<-65.2
126
Sample Description/Source Reference
POU P-99 110
en
a\
o
EOS
IL No. 6
API Gravity
BP/180'F iao'F/275'F 275'F/32S'F 325/350'F 350'F/370'F 370'F
58.5 50.6 38.2 31.6 26.6 23.3
One tpd pilot plant,
Run VP-258
Operating conditions:
Reactor temperature,
840'F; residence tine.
40 ntnutes.
H-Coal IL No.6
Distillation Fraction
API Gravity
Refractive
Index (20'C)
Aniline Point, "f
IBP to 160'F
66.3
NA
HA
180'F to 400*F
32.3
1.449
86
(Continued)
3 tpd PDU, syncrude node
98
-------
Table 256 (Continued)
Distillation Fraction
Material Process Coal Type
Coal raw
naphtha
H-Coal IL (to. 6
in
01
Hyodak
API Gravtty
Refractive Index
Heating Value
(Btu/lb)
Bromine No.
(9/lOOg)
Distillation Data
API Gravtty
Refractive Index
Heating Value
(Btu/lb)
Bromine No.
(g/lOOg)
Distillation Data
IBP to 180'F
66.5
NA
NA
NA
NA
NA
NA
NA
NA
NA
180'F to 380*F
36.5
1.457
18.278
71.2
186°F-1BP
224-F-5
238'F-10
259'F-20
272'F-30
286-F-40
301-F-50
3WF-60
330-F-70
342'F-BO
355'F-90
368-F-95
376'F-EP
44.7
1.4351
19.540
31.2
189'F-IBP
220'F-S
240'F-10
251'F-20
262'F-30
274-F-40
286"F-50
298'F-60
315'F-70
328'F-aO
344"F-90
356"F-95
415'F-EP
Sample Description/Source Reference
PDU Run 5, syncrude mode, HI
Run 130-82. Period 29
PDU Run 6, syncrude node,
Run 130-83. Period 17
112
(Continued)
-------
Table 256 (Concluded)
Material Process Coal Type
Sample Description/Source Reference
Period 1§ Period 2§ Period 3§ Period 4§
Naphtha from
hydrotreated
coal liquid
SRC-11
tn
cr>
ro
KV No. 9
and 14.
IL No. 6
(King River
Nine) and
Pitt-Seams HV
(Blackville
No. 2 Htne)
C5 - 180'F Cut
API Gravity
Octane Number
F-l clear
F-2 clear
160 to 300'F Cut
API Gravity
Aniline Point. *F
Molecular Height
Octane Number
F-l Clear
F-2 Clear
TBP Distillation.
ST/5
10/30
50
70/90
95/99
Distillation'
ST/5
10/30
SO
70/90
95/EP
X Overhead
60.7
81.1
77.0
51.6
108.8
107
66.0
66.0
•Ft
98/177
180/220
246
269/294
303/NA
212/216
220/228
235
246/266
276/321
99.0
59.9
81.5
77.4
49.0
87.4
107
69.2
67.3
1S9/184
203/232
252
280/302
310/323
214/217
220/228
236
247/270
278/320
99
59.9
81.1
HA
48.4
79.2
NA
72.0
68.5
147/183
202/232
251
279/301
308/319
NA
58.6
82.2
NA
49.9
96.8
NA
68.4
66.9
157/183
206/233
252
277/299
306/317
213/217
221/228
235
246/265
274/313
99
Coal-
derived
gasoline
NA
Explanatory Notes
'Heart cut from secondary fractionalIon.
'Full cut boiling range.
foist illation simulated by chronatography.
9£ach period refers to a run time having a characteristic set of operating conditions.
'Determined by ASTH D-86.
Ft. Lewis pilot
plant, whole SRC-11
liquid hydrotreated
with ICR 106 catalyst
(Run No. 76-165).
Operating conditions
for Periods 1
through 4, respec-
tively: tine on-
stream, hr., 251-275.
539-563, 2339-2351,
2709-2733; average
catalyst temperature,
•f. 750, 750, 768.
776; and LHSV, 0.55.
1.51. 1.52 and 0.49.
86
-------
Table 257. Elemental Composition of Various Distillation Fractions of Primary Coal Naphthas
Value
en
cn
Co
Material Process Coal Type Boiling Range, *F
Coal raw EDS IL No. 6 Vol 1 of SanpU
Naphtha
Wt 1 of Swple
Composition, Wt (
Carbon
Hydrogen
Nitrogen
Sulfur
Oxygen
SRC- II Powhattan Distillation
No. 5 Cut No.
50 Wt I Otf
Temperature, "f
Composition, Wt %
Carbon
Hydrogen
N1 trogen
Oxygen
Sulfur
H-Coal IL No. 6 Boiling Range. *F
Composition. Wt I
Carbon
Hydrogen
Nitrogen
Oxygen
Sulfur
Wyodak Boiling Range. *F
Composition, Wt t
Carbon
Hydrogen
N1 trogen
Oxygen
Sulfur
IBP
20
18
85
14
0
0
0
152
84
M
0
0
0
/ZOO 200/2SO
.as
.56
.2S
.32
.03
.35
.05
»
.6
.28
.43
.55
.67
.07
17.40
16.549
85.76
13.55
0.03
0.59
0.07
2
210.2
86.02
13.33
0.24
0.33
0.08
IBP-180"F
85.38
14.52
NA
NA
NA
IBP-IBO'F
NA
NA
NA
NA
NA
250/300
19.
08
1.876
85.
12.
0.
0.
0.
3
249.
85.
13.
0.
0.
0.
56
76
02
99
67
8
73
66
27
24
10
300/325
12.78
13.43
84.64
12.39
0.03
0.89
2.05
4
278.6
87.22
12.44
0.11
0.08
0.15
180-380"
85.14
12.00
0.31
NA
0.38
180-380°
85. 55
13.23
0.13
<0.03
NA
325/350
12.
13.
83.
11.
0.
0.
3.
5
332.
83.
10.
0.
4.
0.
F
F
10
13
95
10
25
87
83
6
98
48
36
70
48
350/370 370* Sample Description/Source
15.
17.
85.
11.
0.
0.
2.
6
384.
83.
9.
0.
6.
0.
81 1.98 One tpd pilot plant. Run
No. YP-221
36 2.27
62 83.47
12 10.69
16 21.4
46 1.93
64 1.77
PDU No. P-99
8
56
49
62
06
07
PDU Run 5. syncrude node.
Run 130-82. Period 29
PDU Run 6, syncrude Mde,
Run 130-83. Period 17
Reference
99
110
111
112
(Continued)
-------
Table 257 (Concluded)
Value
Coal raw
naphtha
H-Coal
Naphtha
from
hydro-
treated
coal
liquid
SRC-II
C (Hi-
de rived
gasoline
HA
Coal Type Boiling Range, °F
It No. 6 Boiling Range. *f
Composition, Wt 1
Carbon
Hydrogen
Nitrogen
Oxygen
Sulfur
KY No. 9 Boiling Range. *F
and 14. Composition, ttt 1
IL No. 6
(King Nitrogen
River Oxygen
Mine
and
Pitt-Seams
UV (Black-
vllle No.
2 Nine)
IBP/200 200/250
IBP-180'F
NA
NA
NA
<0.07
NA
Period 1*
NA
NA
250/300 300/325 325/350
180-380"?
83.6
12.9
0.19
0.24
0.26
180-300«F
Period 2* Period 3*
0.00021 NA
0.0280 NA
350/370 370+
Period 4*
NA
NA
Explanatory Note
•Each period refers to a run time having • characteristic set of operating conditions.
Sample Description/Source Reference
3 tpd POU. syncrude node 98
Ft. Lewis pilot plant.
Run 130-82. Period 29
whole SRC-II liquid
hydrotreated with ICR 106
catalyst (Run No. 76-165).
Operating conditions for
Periods 1 through 4,
respectively: tine
on-streaa, hr., 251-175.
539-563. 2339-2351.
3709-2733; average
catalyst temperature *F,
750. 750. 768. 776. and
LHSV. 0.55. 1.51. 1.52
and 0.49.
86
86
-------
Table 258. Hydrocarbon and Oxygen-Containing Compounds and Compound Classes
Value
Material Process Coal Type
Coal raw EOS
Naphtha
IL No. 6
en
cn
en
IL No. 6
Boiling Range, "f
MS Compos Hon. Ut I
Paraffins
Naphthenes
Kydrlndane
Decalln/Methyl
Hydrlndane
Benzene
Toluene
Cg- Aroma tics
Cg-Aromatlcs
C 10- Aroma tics
Cji-Aronatlcs
Indane
Tetral In/Me thy 1-
Indane
Methyl -Tetralln/
C]|- Indane
Indane
Naphthalene
Phenol
Cresol
tylenols
Boiling Range. "F
HS Compost ton, Ut I
Paraffins
Naphthenes
Hydrlndane
Decaltn/Hethyl
Hydrlndane
Benzene
Toluene
Cg-Aromatlcs
Cj- Aroma tics
CiQ-Aroaatlcs
Cn-Aronatlcs
Indane
Tetraltn/Methyl-
Indane
Hethyl-Tetralln/
CD- Indane
Indane
Methyl -Indanes
Napthalene
IBP/ 200
35.00
61.73
NO
NO
2.66
0.58
0.02
0.01
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
100.00
IBP/ 180
30.64
59.71
NO
NO
2.20
0.89
1.34
1.03
0.71
0.23
0.53
1.03
MD
0.03
NO
NO
Methyl -Naphthalene NO
Phenol
Cresol
Xylenols
0.32
1.18
0.16
TM70D
200/250
16.23
68.46
NO
NO
0.32
14.82
0.16
0.01
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
100.00
180/275
11.97
75.29
NO
NO
0.45
7.23
4.82
0.01
NO
NO
NO
NO
NO
NO
NO
NO
NO
0.24
NO
NO
TBOfl
250/300
18.05
45.09
NO
NO
0.21
1.33
20.83
0.24
NO
NO
NO
NO
NO
NO
0.05
3.20
NO
NO
100.00
275/325
8.79
54.20
4.58
NO
0.04
0.51
13.30
7.35
7.35
NO
0.28
NO
NO
0.10
NO
0.06
NO
10.29
0.50
NO
TOOTOTJ
300/325
14.68
45.57
10.12
1.09
0.22
0.50
4.91
12.11
NO
NO
0.05
NO
NO
0.16
0.08
10.23
0.22
0.06
100.00
325/350
7.73
34.19
5.88
8.51
NO
0.40
1.09
14.23
4.25
NO
5.69
0.75
NO
NO
0.16
NA
0.15
5.02
11.55
0.40
TGOB
325/350
10.14
27.94
3.26
7.97
0.11
0.24
0.20
19.69
1.79
NO
5.51
NO
NO
0.03
0.33
18.67
3.77
0.35
TodTM
330/370
5.33
30.68
2.82
NO
NO
0.89
1.33
3.33
11.93
0.95
6.93
7.50
0.52
0.10
0.07
NO
NO
1.16
26.46
NO
TOOB
350/370
4.79
17.13
0.25
25.92
0.18
3.27
1.00
2.64
11.05
NO
14.59
1.95
ND6
0.06
NO
0.94
15.98
0.25
Too. oo
370+
4.63
18.71
6.10
3.05
NO
NO
2.02
2.25
4.60
7.84
2.56
22.04
4.44
0.63
0.06
0.34
0.03
0.45
8.65
11.61
rdoToTi
Sample Description/Source Reference
One tpd pilot plant, Run
No. YP-221
99
One tpd pilot plant. Run
No. If P-258
99
(Continued)
-------
Table 258 (Continued)
en
CT>
en
Value (Vol X)
Carbon Paraffins
Material Process Coal Type Boiling Range No. ISO-
Coal raw EDS IL No. 6 IBP-145'F 4
naphtha 5
6
145-177'f 5
6
7
1/7-207T 5
6
7
8
Hyodak Boiling Mange, *F
Vol < Of Sample
Ut * of Sample
Gravity, 'API
HS Analysis (Wtt)
Paraffins
Naphthenes
Hydrindane
Oecal in/Methyl
Hydrindane
Benzene
Toluene
Cg-Aromatics
Cg-Aromatlcs
CiQ-Aromatlcs
Cn-Aromatlcs
Indane
Tetralln/Methyl-
Indane
Hethyl-Tetralin/
CM- Indane
Indene
Naphthalene
Phenol
Cresol
Xylenols
NO
6.9S
S.84
12.79
0.15
12.22
0.07
13.14
NO
0.47
13.03
0.14
13.64
IBP/202
12.11
11.18
54.7
35.59
61.98
NO
NO
2.49
1.92
0.02
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
Normal
0.24
27.07
16.22
43.53
0.60
26.11
NO
26.71
0.04
3.46
1.26
NO
4.76
202/234
11.63
10.99
51.0
17.77
70.01
NO
NO
0.74
11.33
0.15
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
Oleflns
Alkenes
0.02
9.50
3.81
13.33
0.22
7.48
NO
7.70
NO
0.85
3.01
NO
3.86
234/256
11.70
11.15
49.0
18.20
68.23
NO
NO
0.33
7.85
5.38
0.01
NO
NO
NO
NO
ND
NO
ND
ND
NO
NO
CyC5 C
fr CyTC
NO NO ND
1.92 1.35 23.
2.85 ND ND
4.77 1
1.35 23.
ND ND 3.
ND ND 33.
ND NO NO
37.
Naphthenes
[ CyC6
Aroraat
TcY
ND ND
76 ND ND
0.06 0.41
Sample
Description/
Source
One tpd
pilot plant,
Run YP-258
76 0.06 0.41
35 ND ND
69 9.40 6.01
NO ND
.04 9.40 6.01
NO NO 0.09 ND ND
0.05 ND 12.27 53.52 3.55
5.84 ND 0.09 2.15 0.12
0.09 ND NO ND ND
5.98
256/278
12.01
11.75
44.8
15.71
62.59
ND
ND
0.25
4.00
15.95
0.12
ND
ND
ND
NO
ND
ND
0.03
1.35
ND
ND
12.
278/298
11.84
11.81
41.2
16.04
56.73
0.88
NO
0.24
1.40
16.66
2.11
ND
ND
NO
ND
ND
NO
0.17
5.77
NO
ND
45 55.64 3.67
298/315
11.58
11.92
36.1
14.96
47.78
5.12
0.43
0.29
0.74
11.05
7.66
0.08
NO
0.37
ND
ND
ND
0.14
11.38
NO
ND
315/330
11.70
12.35
31.5
13.51
37.69
5.93
4.80
0.30
0.83
5.11
11.19
0.99
NO
2.49
0.14
ND
ND
0.19
16.01
0.77
O.OS
330/345
11.01
12.49
28.3
9.89
29.49
3.87
13.59
0.32
1.83
1.94
9.65
3.60
ND
6.15
0.97
NO
ND
0.15
12.87
5.64
0.12
345/350
5.
6.
26
7
24
2,
20,
0
2
1
6
5.
.82
.36
.6
.24
.30
.18
,25
.32
80
15
.54
93
HO
7
2
.84
.37
NO
0
0
8
10,
0
.01
06
.24
.64
13
Total
100.00 One tpd
100.00 pilot plant.
40.7 Run YP-244
16.95
53.74
0.57
2.91
0.60
3.86
7.05
4.11
0.96
NO
1.58
0.33
ND
0.01
0.02
6.13
1.18
NO
Reference
99
99
100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00
(Continued)
-------
Table 258 (Continued)
en
CT»
•-4
Hatertal Process Coal Type Boiling Range. IBP-IBQ'F
Coal r*M H-Co*l 1L No. 6 C$ hydrocarbon
naphtha 1-Cj hydrocarbon
N-Ci hydrocarbon
Unidentified hydrocarbon
Unidentified hydrocarbon
Iso-Pentane
N-Pentane
Unidentified hydrocarbon
Unidentified hydrocarbon
2 Hethylpentane
3 Hethylpentane
Unidentified hydrocarbon
N-Hexane
Hethy1eyelohex ane
Unidentified hydrocarbon
Cyclohexane
Unidentified hydrocarbon
Unidentified hydrocarbon
Unidentified hydrocarbon
Unidentified hydrocarbon
Beniene
Boiling Range. 1BO-3BQ'F
Paraffins
Honocycloparaffins
Dlcycloparafflns
Total
Aliphatic Hono-olefins
Cyclic Hono-oleflns
Total
Alkylbenzenes C(
ut
.99
Ut
Sample Description/Source Reference
POU Run 5. syncrude mode. 111
Run 130-82, Period 29
Total
AUylindans t Tetrallns/C'
C"
Total
Naphthalene C\Q
Estimated Phenols
Total
(Continued)
-------
Table 258 (Concluded)
Material Process Coal TV
Boiling Range, 'f IBP-I60°F
ir\
CT>
00
Coal raw H-Coal
naphtha
Naphtha SRC- 1 1
from
Hydro
treated
coal
liquid
Hyodak Propane
Isobutane
Normal Butane
Butylene
Iso-Pentane
N-Pentane
Pentenes
2 Methylpentane
3 Methylpentane
Cyclopentene
N-Hexane
Methyl cyclopentane
Cyclohexane
C
-------
Table 259. General Physical and Chemical Properties of Non-Primary Coal Naphthas
Value
en
Material Process
Coal raw NA
naphtha
Naphtha from EDS
hydrotreated
coal liquid
Coal Type Distillation
--
IL No. 6 Specific Gravity*
(Honterey API Gravity, *
Hlne) Distillation. *F
IBP
5S
101
201
301
40%
50S
60S
70S
80S
90S
951
EP
S Over
S Bottons
Research Octant
No.. Clear
Brc»l nt Index
Molecular Weight
S Evaporation Temperature (*F)
„
0.7699
52.3
148
170
181
200
215
229
224
260
280
302
324
338
372
98.5
1.5
75.2
369
102
Sanple Description/Source
Blend of product from series
flow fron hydrocracklng of
gas oil feed fro> one tpd
pilot plant; hydrocracklng
perforated In bench-scale
continuous hydrocracklng unit
(UOP Sample No. 3532-23, UOP
Research Plant 601, Run 777).
Operating conditions: 500
pslg above base pressure.
Reference
87
(Continued)
-------
Table 259 (Continued)
Haterlil
Naphtha
from
hydro-
treated
co»l
liquid
Value
EDS
en
-~4
O
Coal Type
IL No. 6
(Monterey
Htne)
Specific Gravity*
API. Gravity. •
Distillation. *f
51
10(
201
301
401
SOI
601
701
801
901
951
If
I Over
I Bottoms
0.7796
50.0
1 Evaporation
138
160
170
191
207
222
236
253
273
296
318
331
392
98.0
2.0
Research Octane
No.. Clear
Broaine Index
Molecular Weight
Average
83.2
344
100
Sample Description/Source
Blend of product fron
hydrocracklng of gas oil
feed fron one tpd pilot
plant; hydrocracklng per-
formed In bench-scale con-
tinuous hydrocracklng unit
(UOP Sample No. 3532-26, UOP
Research Plant 601. Run 779).
Operating conditions; 500
pslg above base pressure.
Reference
87
(Continued)
-------
Table 259 (Continued)
Value
Material Process Coal Type
Naphtha
from
hydro-
treated
coal
liquid
H-Coal IL No. 6
en
Specific Gravity*
API Gravity. *
Distillation, 'f
IBP
5*
10*
20*
30*
4M
5M
60f
70*
801
90*
95*
EP
1 Over
% Bottoms
Research Octane
No.. Clear
Broalne Index
0.7809
49.7
KE vapor at Ion
120
148
162
184
202
218
233
250
269
289
319
336
400
99.0
1.0
84.2
298
Sample Description/Source
Fron moderate hydrocracklng
of gas oil feed from 3 tpd
POU operated In syncrude
made; hydrocracklng performed
In bench-scale continuous
hydrocracktng unit (OOP
Sample No. 3531-15. UOP
Research Plant 601. Runs 749
and 751). Operating condi-
tions: 500 pslg below base
pressure.
Reference
92
(Continued)
-------
Table 259 (Concluded)
Material Process Coal Type
Value
Naphtha
from
hydro-
treated
coil
liquid
H-Coal IL No. 6
en
^•J
ro
Specific Gravity*
WI 6r*vUy, *
Distillation, -f
IBP
5*
lot
20*
30*
40*
50*
601
701
BO*
90S
951
EP
X Over
1 Bottoms
Research Octane
Ho., Clear
Broalne Index
0.7822
49.4
1 Evaporation
127
156
172
194
213
231
248
262
288
311
342
375
518
98.5
1.5
80.2
126.0
Coal-derived
gasoline
See Table 2 of Part VI
Explanatory Notes
'Measured at 60*F
^Distillation simulated by chronatography
Sample Description/Source
From moderate hydrocracktng
of gas oil feed fron 3 tpd
POU operated In syncrude
•ode; hydrocracklng performed
In bench-scale continuous
hydrocracklng unit (UOP
Sample No. 3531-18. UOP
Research Plant 601. Runs 756
and 757). Operating condi-
tions: 500 pslg above base
pressure.
Reference
92
-------
Table 260. General Physical and Chemical Properties of Gasolines Derived
From Non-Primary Coal Naphthas
Value
Coal-derived
gasoline
EDS
en
•^l
CO
Coal Type
IL No. 6
(Monterey
Ntne)
IL No. 6
(Monterey
Mine)
API Gravityt
Specific Gravity t
Distillation. *Ff
IBP
51
101
301
sot
701
901
951
EP
Research Octane No
Clear
API Gravttyt
Specific Gravity*
Distillation. *M
IBP
SI
101
301
SOI
701
901
9S1
EP
Research Octane No
Period 1*
45.9
0.7976
142
164
174
212
2SO
291
340
360
382
.. 91.2
47.3
0.7914
140
160
172
206
238
280
328
343
3S7
., 90.4
Period 2*
43.8
0.8072
140
162
172
206
237
270
320
330
382
93.8
46.7
0.7941
150
160
170
204
238
278
326
341
356
91.3
Period 3*
43.9
0.8067
144
162
173
213
25S
293
344
364
382
96.0
45.8
0.7981
142
164
175
209
242
280
328
346
364
93.4
Period 4*
41.1
0.8198
135
160
171
216
256
296
347
367
405
99.8
44.4
0.8044
140
162
172
210
246
286
334
352
368
96.0
Period 5*
43.7
0.8076
144
164
176
217
258
303
352
376
398
96.9
42.7
0.8123
142
164
177
214
250
288
334
352
372
98.2
Period 6'
42.4
0.8137
ISO
166
178
220
262
304
356
391
418
98.4
41.8
0.8165
140
162
174
212
251
290
336
359
382
Clear
Fro* platforalng of 87
hydrocracked gas oil
saaple No. 3532-23 (UOP
Research Plant 636. Run
321). Operating condi-
tions for Periods 1
through 6, respectively:
P-P (base), pslg. 0 (all
periods); T-T (base). *C.
-118. -103. -85. -43.
-73. -58; LHSV/LHSV
(base). 1.49. 1.45. 1.54.
1.52. 1.51 and 1.45.
Froa platforalng of 87
hydrocracked gas oil
sanple No. 3S32-26 (UOP
Research Plant 636. Run
334). Operating condi-
tions for Periods 1
through 6. respectively:
P-P (base), pslg. 0 (all
periods); T-T (base). °C
periods); T-T (base), "C.
-154. -147. -133. -108.
-88. -67; LHSV/LHSV
(base). 1.57. 1.50. 1.52,
1.50. 1.46 and 1.45.
(Continued)
-------
Table 260 (Continued)
Coal-derived
gasoline
EDS
en
Coal Type
IL No. 6
(Monterey
Mine)
Value
Period 1* Period 2* Period 3* Period 4* Period 5* Period 6*
API Gravity*
Specific Gravity*
Distillation. *Ff
I8P
51
101
301
501
701
901
951
EP
Research Octane No.,
Clear
44.3
0.8049
140
160
174
201
245
290
344
380
424
98.9
41.0
0.82083
152
170
180
216
253
297
351
375
427
96.6
45.2
0.8008
132
152
165
201
235
277
331
350
410
93.7
46.2
0.7963
140
162
173
208
241
282
336
362
430
91.6
42.3
0.8134
138
160
171
209
247
285
346
367
429
98.3
41.7
0.8170
126
150
176
208
245
287
340
360
418
99.6
Period 7*
40.5
0.8227
134
154
167
212
252
289
348
372
448
101.2
Sample
Source Reference
Fro* platforntng 92
of Moderately
hydrocracked gas
oil. Saaple No.
3531-15 (UOP
Research Plant
508. Run 1457).
Operating condl-
Itlons for
Periods 1 through
7, respectively:
P-P (base), pslg.
0 (all periods);
T-T (base), "C.
-78. -103. -118,
-133, -78. -58. -38;
LHSV/LHSV (base).
1.50. 1.51. 1.45,
1.45. 1.49. 1.53.
1.47.
Period
API Gravity*
Specific Gravity*
Distillation. *Ff
IBP
51
101
301
SOS
701
901
951
EP
Research Octane No.,
Clear
45.4
0.7999
134
159
172
214
248
291
342
379
524
90.6
Period 2*
44.1
0.8053
143
165
178
216
252
296
349
399
524
93.6
Period 3*
43.4
0.8090
140
160
175
217
255
299
356
392
510
95.6
Period 4*
41.9
0.8160
132
159
173
217
257
301
354
381
461
98.1
Period 5*
40.0
8.251
142
169
183
226
260
303
363
420
440
99.3
Froa pi atforming
of Moderately
hydrocracked gas
oil. Simple No.
3531-18 (UOP
Research Plant
508. Run 1458).
Operating condl-
Ittons for
Periods 1 through
5. respectively:
P-P (base), pslg.
0 (all periods);
T-T (base), "C.
-118. -98. -78.
-53, -13; LHSV/
LHSV (base), 1.48.
1.49. 1.50. 1.49.
1.50.
92
(Continued)
-------
Table 260 (Concluded)
Material
Coal-
derived
gasoline
Process Coal Type Value
H-Coal NA API Gravltyt
Research Octane
No.. Clear
Distillation. *F
IBP
lot
50t
90*
EP
NA API Gravttyt
Research Octane
No. Clear
51.8 - 53.4
91.5
82-107
122-127
244-232
350-359
385-393
48.8-51.0
NA
Ol
•^4
cn
Distillation. *F
NA
IBP
lot
sot
90*
EP
API Gravltyt
Research Octane
No. Clear
Distillation. 'F
IBP
lot
50*
90*
EP
30-70
77-158
215-242
320-340
365-459
43.1-45.2
95.5-96.9
120-130
157-161
230-245
344-336
410-422
Sample Description/Source Reference
From series flow second stage hydrocracking 94
of Mildly hydrocracked gas oil Sample No.
96-3330A (Chevron Plant 536. Run 678).
Operating conditions: P-P (base), psl. -500;
LHSV/LHSV (base). 1.0; CPR/CPR (base). 1.18;
T-T (base), 'F. 47-49.
From simple flow second stage hydrocracking 94
of heavily hydrocracked gas oil Sample Ho.
96-3330A (Chevron Plant 601. Runs 749-751).
Operating conditions: P-P (base), psl.
-500; LHSV/LHSV (base). 0.725-1.45; CPR/CPR
(base). 1.25; T-T (base). *F. 20-50.
From fluid catalytic cracking of moderately 93
hydrotreated Sample No. 37-1117/8 (UOP
Research Plant 593. Run 255. Periods 1
through 5*. Operating conditions P-P (base),
psl. -10; LHSV/LHSV (base). 1.03-1.56; T-T
(base). 'F, 2-47.
Explanatory Notes
*Each period refers to a run time having a characteristic set of operating conditions.
'Measured at 69'F
{Determined by ASTM D-B6
-------
Table 261. Elemental Composition of Non-Primary Coal Naphthas and Gasoline
Material
Coal raw
naphtha
Naphtha
from
hydro-
treated
coal
liquids
Process Coal Type
NA
EOS
1L No. 6
(Monterey
Hlne)
85.63 13.74 0.00003 0.0378
0.00003
IL No. 6
(Monterey
Hlne)
86.70 12.84 0.00003 0.0237
0.00013
in
^j
cr>
H-Coal IL No. 6
86.52 13.09 0.00001 0.00409 0.0001
IL No. 6
86.13 13.47 0.000013 0.00409 0.00082
Sample Description/Source Reference
Blend of product froa series 87
flow fron hydrocracklng of
gas oil feed from one tpd
pilot plant; hydrocracklng
performed In bench-scale
continuous hydrocracklng unit
(UOP Sample No. 3532-23. UOP
Research Plant 601. Run 777).
Operating conditions: 500
pslg above base pressure.
Blend of product from hydro- 87
cracking of gas oil feed
from one tpd pilot plant;
hydrocracklng performed In
bench-scale continuous hydro-
cracking unit (UOP Sample No.
3532-26. UOP Research Plant
601. Run 779). Operating
conditions: 500 pslg above
base pressure.
From moderate hydrocracklng 92
of gas oil feed fron 3 tpd
PDU operated In syncrude
mode; hydrocracklng performed
In bench-scale continuous
hydrocracklng unit (UOP
Sample No. 3531-15. UOP
Research Plant 601, Runs 749
and 751). Operating condi-
tions: 500 pslg below base
pressure.
From moderate hydrocracklng 92
of gas oil feed from 3 tpd
POU operated In syncrude
mode; hydrocracktng performed
In bench-scale continuous
hydrocracklng unit (UOP
Sample No. 3531-18. UOP
Research Plant 601, Runs 756
and 757). Operating condi-
tions: 500 pslg below base
pressure.
(Continued)
-------
Table 261 (Concluded)
01
Mittrlil
darlnd
liiallM
Froctn Coil Typj
COS 11 to. f
MoAtirny
Ml**)
IL to. S
(Na*l«r«y
MM)
H-Catl IL la. (
Caapoiltlai.
Cirbo*
Hydraa**
NUraa**
Sulfur
OiyiM
Urban
Hydraa**
Nltrof**
Sulfur
OKyoM
Ctrba*
Hydraa**
HUraati
Sulfur
f*rl«d |*
07.14
12.11
0.0000)
C, -1S4. -147. -Ill
-100. -00. -*7; IHS»/LHS»
(b»*). I.S7. 1.60. 1.S2,
1.60. 1.4* *nd 1.4S
fro» pl-49.
94
-------
Table 262. Hydrocarbon Class Properties of Non-Primary Coal Naphthas and Gasoline
Material Process CodI Type
Coal raw HA
naphtha
Naphtha EDS
from
hydro-
treated
coat
liquids
IL No. 6
(Monterey
Mine)
Aromatics
14.2
Value. Vol »*
Saturates
as.8
Oleflns
HA
IL No. 6
(Monterey
Nine)
27.3
72.7
NA
Ui
~-4
00
H-Coal IL No. 6
34.43
65.57
NA
IL No. 6
23.26
76.74
NA
Sample Description/Source Reference
Blend of product from series 87
flow fron hydrocracklng of
gas oil feed from one tpd
pilot plant; hydrocracklng
performed In bench-scale
continuous hydrocracklng
unit (U0f> Sample No.
3532-23, UOP Research Plant
601. Run 777). Operating
conditions: 500 pslg above
base pressure.
Blend of product 67
fron hydrocracklng of gas
oil feed fron one tpd
pilot plant; hydrocracklng
performed In bench-scale
continuous hydrocracklng
unit (UOP Sample No.
3532-26. UOP Research Plant
601. Run 779). Operating
conditions: 500 pslg above
base pressure.
Fron moderate hydrocracklng 92
of gas oil feed froa 3
tpd POU operated In syncrude
node; hydrocracklng perforned
In bench-scale continuous
hydrocracklng unit (UOP
Sample No. 3531-15. UOP
Research Plant 601. Runs
749 and 751). Operating
conditions: 500 pslg below
base pressure.
froa moderate hydrocracklng 92
of gas oil feed fro* 3
tpd POU operated In syncrude
mode; hydrocracklng perforned
In bench-scale continuous
hydrocracklng unit (UOP
Sample No. 3531-18. UOP
Research Plant 601, Runs
756 and 757). Operating
conditions: 500 pslg below
base pressure.
(Continued)
-------
Table 262 (Continued)
Material Process Cot} Type Compound Class
Value (Vol. *)*
Period It Period 2t Period 3t Period 4t Period 5t Period 6t Period 7t Sample Description/Source
Coal
derived
gasoline
EDS
IL No. 6
(Monterey
Mine)
en
Paraffins
Naphthenes
Monocycloparaffins
B1. Olcyclo-
parafflns
Trtcycloparafflns
Aromatics
Alkylbenzenes
Indans, Tetrallns
Naphthalenes
Total
IL No. 6 Paraffins
(Monterey Naphthenes
Nine) Honocycloparafflns
B1. Dlcyclo-
parafflns
Trlcycloparaffins
Aronatlcs
Alkylbenzenes
Indans. Tetrallns
Naphthalenes
Total
H-Coal IL No. 6
Paraffins
Naphthenes
Monocycloparafflns
B1. Dicyclo-
parafftns
Trlcycloparafflns
Aronatics
Alkylbenzenes
Indans. Tetrallns
Naphthalenes
Total
IL No. 6 Paraffins
Naphthenes
Monocycloparafflns
B1. Olcyclo-
parafflns
Trlcycloparafftns
Aromatics
Alkylbenzenes
Indans, Tetrallns
Naphthalenes
Total
19.71
24.14
4.40
0.12
48.19
3.28
0.16
100.00
NA
NA
NA
NA
NA
NA
NA
NA
15.66
12.58
1.26
0.0
65.86
4.35
0.29
100.00
15.03
31.35
7.09
0.0
41.76
4.25
0.52
100.00
18.65
20.36
3.55
0.00
37.74
3.55
0.15
100.00
16.63
27.93
5. 75
0.00
46.75
2.94
0.00
100.00
NA
NA
NA
NA
NA
NA
NA
NA
16.65
25.91
4.69
0.23
47.26
4.70
0.56
100.00
18.80
16.61
21.9
0.00
57.15
3.42
0.14
100.00
16.63
25.15
4.29
0.00
50.54
3.37
0.02
100.00
NA
NA
NA
NA
NA
NA
HA
NA
15.27
21.30
3.32
0.21
54.20
5.05
0.65
100.00
17.21
6.85
0.46
0.00
71.45
3.49
0.54
100.00
15.39
16.21
3.76
0.00
60.19
4.37
0.08
100.00
9.56
26.69
4.20
0.13
52.23
6.73
0.46
100.00
15.13
13.64
2.19
0.00
62.94
5.26
0.84
100.00
20.69
14.68
1.75
0.00
58.67
3.91
0.29
100.00
16.42
13.43
0.73
0.00
65.85
3.54
0.03
100.00
NA
NA
NA
NA
NA
NA
NA
100.00
10.57
7.15
0.99
0.00
73.11
6.24
1.94
100.00
19.40
10.82
0.69
0.00
65.29
3.52
0.28
100.00
16.53
8.98
0.75
0.00
69.85
3.76
0.13
100.00
NA
NA
NA
NA
NA
NA
NA
100.00
NA
NA
NA
HA
NA
NA
NA
NA
MA
NA
NA
NA
NA
HA
NA
HA
HA
HA
NA
HA
NA
NA
HA
HA
13.14
6.08
0.59
0.0
75.45
4.29
0.45
HA
HA
NA
NA
NA
NA
NA
NA
NA
(Continued)
Reference
From platfomtng of hydro- 87
cracked gas oil Sample
No. 3532-23 (UOP Research
Plant 636. Run 321).
Operating conditions for
Periods 1 through 6,
respectively: P-P (base).
pslg, 0 (all periods); T-T
(base). 'C. -118. -103.
-85. -43. -73. -58; LHSV/
LHSV (base). 1.49. 1.45.
1.54. 1.52. 1.51 and 1.45.
From platforalng of hydro- 87
cracked gas oil Sample
No. 3532-26 (UOP Research
Plant 636. Run 334).
Operating conditions for
Periods 1 through 6,
respectively: P-P (base).
pslg. 0 (all periods); T-T
(base). *C. -154. -147. -133.
-108, -88. -67; LHSV/LHSV
(base), 1.57. 1.50, 1.52,
1.50. 1.46 and 1.45.
From platforalng of hydro- 92
cracked gas oil Sample
No. 3531-15 (UOP Research
Plant 508, Run 1457).
Operating conditions for
Periods 1 through 7,
respectively: P-P (base).
pslg. 0 (all periods); T-T
(base). *C. -78. -103, -118.
-133, -78. -58. -38; LHSV/
LHSV (base). 1.50. 1.51.
1.45. 1.45. 1.49, 1.53. 1.47.
Fron pi atforming of hydro- 92
cracked gas oil Sample
No. 3531-18 (UOP Research
Plant 508. Run 1458).
Operating conditions for
Periods 1 through 5,
respectively: P-P (base),
psig, 0 (all periods); T-T
(base). "C. -118. -98. -78.
-53. -13; LHSV/LHSV (base)
1.48. 1.49. 1.50, 1.49.
1.50.
-------
Table 262 (Concluded)
Material Process Coal Ty
Coal-
derived
gasoline
H-Coal NA
Aroaatlcs
29.1-34.3
Value. Vol %*
Saturates
65.7-70.9
NA
23.6-35.7
64.3-76.4
0.0-0.0
00
o
NA
45.2-50.7
44.5-49.5
4.2-6.2
Sample Description/Source Reference
From series flow second 94
stage hydrocracklng of
mildly hydrocracked gas oil
Sample No. 96-3330A (Chevron
Plant 536. Run 678). Operating
conditions: P-P (base), psl,
-500; LHSV/LHSV (base). 1.0;
CPR/CPR (base). 1.18; T-T
(base). *F. 47-49.
From simple flow second 94
stage hydrocracktng of
heavily hydrocracked gas
oil Sample No. 96-3330A
(Chevron Plant 601. Runs
749-751). Operating condi-
tions: P-P (base), psl. -500;
LHSV/LHSV (base). 0.725-
1.45; CPR/CPR (base), 1.25;
T-T (base). «F. 20-50.
Froo fluid catalytic 93
cracking of moderately
hydrotreated Sample No.
37-1117/8 (UOP Research
Plant 593. Run 225. Periods
1 through 5). Operating
conditions: P-P (base), psl,
-10; LHSV/LHSV (base),
1.03-1.56; T-T (base), "F
2-47.
Explanatory Notes:
Mil values by Mass Spectronetry except for values from References 94 and 93 which are by flame lonlzatlon analysis.
tEach period refers to i run time having a characteristic set of operating conditions.
-------
Table 263. General Physical and Chemical Properties of Various Distillation Fractions of
Non-Primary Coal Naphthas and Gasolines
Material Process
Co*) raw NA
naphtha
Coal Type
Value
Period 1* Period 2* Period 3* Period 4*
Saaple Description/Source Reference
Naphtha fro*
hydrotreated
coal liquid
SRC- II
en
00
KY No. 9
and 14,
IL No. 6
(King River
Nine), and
Pitt-SeaiM UV
(Blackvllle
No. 2 Nine)
C5 - IBO'F Cut
API Gravity
Heavy Naphtha
Boiling range, "F
API Gravity
Aniline Point, *F
Octane No.
F-l Clear
TBP Distillation, *F
ST/5
10/30
50
70/90
95/99
Distillation!
ST/5
10/30
50
70/90
95/EP
X Overhead
X Trap
Xln Flask
Viscosity.
cSt. 100'F
66.0
180-350
47.3
109.7
58.8
t
102/185
218/233
275
307/341
350/364
224/231
235/249
264
285/313
325/373
98
1
1
NA
63.3
180-400
42.3
110.0
54.4
134/214
221/273
332
372/396
402/410
NA
NA
NA
NA
NA
NA
NA
NA
NA
66.8
180-350
46.3
89.9
64-5
138/185
218/242
279
311/345
352/363
NA
NA
NA
NA
NA
NA
HA
HA
0.7964
63.1
180-400
39.7
84.9
63.8
153/214
222/273
323
370/398
407/416
233/245
254/282
314
342/366
375/414
99
0
1
NA
Ft. Lewis pilot plant,
400"F+ SRC-11 liquid
hydrotreated with ICR 106
catalyst (Run No. 76-166).
Operating conditions for
Periods 1 through 4
respectively: tl*e on-
streaa. hr.. 145-169.
169-193, 313-337.
337-361; average catalyst
temperature, 'F, 746. 7S1,
752. 752; LHSV. 0.55, 0.43,
0.99 and 0.99.
B6
(Continued)
-------
Table 263 (Continued)
Material
Naphtha
from
hydro-
treated
coal
liquid
en
03
ro
Process Coal Type
H-Coal IL No. 6 Boiling
Range. 'F
API Gravity
Research
Octane No.
TBP Distillation. *F
SI/5
10/30
50
70/90
9S/EP
IL No. 6 Boiling
Range, "F
API Gravity
TBP Distillation. 'Ft
ST/5
10/30
SO
70/90
95/EP
Uyodak Boiling
Range. 'F
API Gravity
Research
Octane No.
TBP Distillation. *F*
ST/5
10/30
50
70/90
95/EP
Value
C5-180
64.6
78.8
39/76
91/151
165
179/187
189/212
Cj-180
63.0
NA
NA
NA
NA
NA
C5-180
6S.8
79.0
23/83
98/157
168
182/188
190/200
180-250
53.9
NA
55/177
181/214
226
232/250
256/266
180-250
52.0
211/257
273/338
382
428/496
519/575
180-250
54.8
70.0
154/178
181/207
223
230/249
255/264
250-300
50.3
NA
208/246
250/263
278
287/303
308/319
250-300
51.3
NA
210/246
250/263
278
286/304
308/319
300-350
43.2
NA
253/293
299/317
329
344/355
360/367
300-350
44.3
NA
253/295
301/318
329
343/354
360/369
Sample Description/Source Reference
Froa hydrotr«at(ng of 95
H-Coal syncrude feed
(boiling range 140-704'F)
froa PDU Hun 5 operated In
syncrude node, over fresh ICR
106 catalyst for production
of jet/dlesel fuel (Chevron
Run 76-171. Hours 222-246).
Operating conditions:
catalyst temperature, 750*F;
LHSV. 1.0
Fro* hydrotreat Ing of rerun 95
H-Coal syncrude feed froa POU
Run S operated In syncrude
node over fresh ICR 106
catalyst for production of
jet/diesel fuel (Chevron Run
76-173. Hours 463-47S).
Operating conditions:
catalyst temperature, 748"F;
LHSV, 1.5.
Froa hydrotreatlng of 95
H-Coal syncrude feed (boiling
range 120-650'F) from POU
Run 6 operated in syncrude
node, over fresh ICR 106
catalyst for production of
jet/diesel fuel (Chevron Run
76-173. Hours 331-355).
Operating conditions:
catalyst temperature. 752'F;
LHSV. 1.0.
(Continued)
-------
Table 263 (Continued)
Material
Naphtha
from
hydro-
treated
coal
liquid
ui
00
CO
Process Coal Type
H-Coal IL No. 6 Boiling
Range, "F
API Gravity
Research
Octane No.
Motor Octane No.
TBP Distillation. *F*
ST/5
10/30
50
70/90
95/EP
IL No. 6 Boiling
Range, *F
API Gravity
Motor Octane No.
TBP Distillation. 'Ft
ST/6
10/30
50
70/90
95/EP
Uyodak Boiling
Range, "F
API Gravity
IBP. Distillation, *F*
ST/5
10/30
50
70/90
95/EP
Value
CS-IBO
64.0
82. 0
25/79
97/161
171
179/186
187/194
C5-180
65.0
NA
HA
NA
NA
NA
NA
CS-1BO
66. B
NA
NA
NA
NA
NA
180-250
52.7
NA
200/204
206/207
210
212/220
227/255
180-250
53.1
73.1
195/197
198/200
202
208/219
231/279
180-250
54.2
155/179
184/208
225
234/252
257/267
Sample Description/Source Reference
From hydrotreatlng of 95
H-Coal syncrude feed
(boiling range MO-704T)
from POU Run S operated in
syncrude node, over aged ICR
106 catalyst for production
of jet/dlesel fuel (Chevron
Run 76-171. Hours 3191-3215).
Operating conditions:
catalyst temperature. 774*F;
LHSV, 0.5.
From hydrotreating of rerun 95
H-Coa) syncrude feed fron POU
Run 5 operated In syncrude
•ode, over aged ICR 106
catalyst for production of
jet/dlesel fuel (Chevron Run
76-174. Hours 76-174).
Operating conditions:
catalyst temperature, 802'F;
LHSV. 1.5.
From hydrotreatlng of 95
H-Coal syncrude feed (boiling
range 120-650'F) from PDU
Run 6 operated In syncrude
•ode. over aged ICR 106
catalyst for production of
jet/diesel fuel (Chevron Run
76-174. Hours 208-232).
Operating conditions:
catalyst temperature, 802"F;
LHSV. 1.0.
(Continued)
-------
Table 263 (Continued)
Haterlal
Naphtha
from
hydro-
treated
coal
liquid
en
00
Process Coal Type
H-Coal Uyodak Boiling
Range. "F
API Gravity
TBP. Distillation, 'f
ST/5
10/30
50
70/90
95/EP
IL No. 6 Boiling
Range, "F
API Gravity
TBP Distillation. 'Ft
ST/5
10/30
50
70/90
95/EP
Uyodak Boiling
Range, *F
API Gravity
Research
Octane No.
TBP Distillation. 'Ft
ST/5
10/30
50
70/90
95/EP
Value
Cs-180
69.2
t
44/84
99/156
173
189/221
225/250
Cs-180
61.6
46/90
101/161
176
188/195
198/208
C5-180
65.0
HA
NA
NA
NA
NA
NA
180-250
56.4
45/143
161/184
214
224/248
262/298
180-250
51.8
157/179
183/218
226
235/250
256/269
180-250
54.2
71.3
200/203
204/206
209
213/220
227/264
250-300
50.5
205/241
248/265
278
288/304
309/319
250-300
45.9
212/245
251/273
283
293/305
311/321
300-350
43.5
257/292
299/318
330
344/356
362/371
300-350
39.9
252/291
300/320
332
345/357
362/367
Sample Description/Source Reference
Fron hydrotreating of rerun 95
H-Coal syncrude feed from POU
Run 6 operated tn syncrude
mode, over aged 1CR 106
catalyst for production of
jet/dlesel fuel (Chevron Run
76-174. Hours 604-610).
Operating conditions:
catalyst temperature. 803'F;
LHSV. 1.5.
Fran Moderate hydrotreatlng of 95
H-Coal syncrude feed (boiling
range 140-704'F) from POU Run
5 operated In syncrude node.
over ICft 106 catalyst for
production of heating oil
(Chevron Run 76-171, Hours
1967-1991). Operating
conditions: catalyst tempera-
ture. 77S*F; LHSV, 1.5.
From moderate hydrotreatlng of 95
H-Coal syncrude feed (boiling
range 120-650*F) from POU
Run 6 operated In syncrude
node, over ICR 113
catalyst for production of
heating oil (Chevron Run
66-203, Hours 1366-1390).
Operating conditions:
catalyst temperature. 747*F;
LHSV. 1.5.
(Continued)
-------
Table 263 (Concluded)
Haterlal
Naphtha
from
hydro-
treated
coal
liquid
en
CD
en
Process Coal Type
H-Coal IL No. 6 Bolting
Range, *F
API Gravity
TBP Distillation,
ST/5
10/30
50
70/90
95/EP
IL No. 6 Boiling
Rang*. *F
API Gravity
TBP Distillation.
ST/5
10/30
50
70/90
9S/EP
IL No. 6 Boiling
Range. *F
API Gravity
TBP Distillation.
ST/5
10/30
50
70/90
95/EP
Value
C5-180
64.7
•Ft
52/85
99/155
167
178/187
191/194
C5-180
62.2
•Ft
107/130
136/148
157
163/170
173/307
C5-180
61.6
•Ft
46/90
101/161
176
188/195
198/208
180-250
51.9
101/176
179/216
220
227/242
251/279
180-250
51.8
201/204
206/209
210
214/220
226/281
180-250
51.8
157/179
183/218
236
235/250
256/269
250-300
46.1
211/245
251/272
284
294/306
312/322
250-300
46.0
210/246
252/272
283
293/206
312/323
250-300
45.9
212/245
551/273
283
293/305
311/321
300-350
39.9
264/294
302/319
327
340/352
358/367
300-350
39.6
243/286
298/321
334
348/361
365/372
300-350
39.9
252/291
300/320
332
345/357
362/367
Coal-
derlved
gasoline
HA
Explanatory Notes:
*Each period refers to a run time having a characteristic set of operating conditions.
^Distillation simulated by chroroatography.
fDetermined by ASTH 0-86.
_ Sample Description/Source Deference
Fro* Moderate hydrotreatlng of 95
H-Coal syncrude feed (boiling
range 140-704'F) fro* PDU Run
5 operated In syncrude mode,
over ICR 106 catalyst for
production of fuel oil
(Chevron Run 76-171, Hours
654-678). Operating condi-
tions: catalyst temperature,
750*F; LHSV. 1.5; total
pressure, 2493 pslg; hydrogen
pressure, 2231 psia.
Froa Moderate hydrotreatlng 95
of H-Coal syncrude feed
(boiling range 140-704'F)
fro* PDU Run 5 operated In
syncrude mode, over ICR 106
catalyst for production of
fuel oil (Chevron Run 76-171.
Hours 1535-1559). Operating
conditions: catalyst tempera-
ture. 750°F; LHSV. 1.5; total
pressure, 2001 pslg; hydrogen
pressure, 1778 psta.
Fro» moderate hydrotreattng 95
of H-Coal syncrude feed
(boiling range 140-704'F)
fro* PDU Run 5 operated In
syncrude mode, over ICR
106 catalyst for production
of fuel oil (Chevron Run
76-171. Hours 1976-1991).
Operating conditions:
Catalyst temperature, 775°F;
1HSV, 1.5; total pressure
2073 pslg; hydrogen
pressure 1859 psia
-------
Material
Coal raw
naphtha
Naphtha from
hydrotreated
coat liquid
Table 264. Elemental Composition of Various Distillation Fractions
of Non-Primary Coal Naphthas and Gasoline
Value (Mt <) Sample Description/Source
Process
HA
SRC-I!
Boiling Range. C5 Period 1* Period 2* Period 3* Period 4*
KY No. 9
and M.
IL No. 6
(King River
Nine) and
Pitt-Seams UV
(Blackville
No. 2 H1ne)
Nitrogen
Oxygen
0.00009
0.0110
NA
HA
NA
NA
0.0002
0.0280
H-Coal
IL No. 6
Boning Range, *F
Sulfur
Cj-iao
NA
en
00
CT»
Boiling Range. *F C5-180
IL No. 6
Sulfur
NA
180-250
0.000014
Uyodak
Boiling Range. 'F C5-180
Sulfur NA
180-250
0.000025
NA
NA
Reference
86
180-250 250-300 300-350
0.00002* 0.00003* 0.00005*
250-300 300-350
Ft. Lewis pilot plant.
400'F+ SRC-II liquid
hydrotreated with ICR 106
catalyst (Run No. 76-166).
Operating conditions for
Periods 1 through 4
respectively: time on-
stream, hr.. 145-169,
169-193. 313-337.
337-361; average catalyst
temperature. 'F. 746, 751.
752. 752; LHSV. 0.55. 0.43.
0.99 and 0.99.
From hydrotreattng of 95
H-Coal syncrude feed
(boiling range 140-704'F)
from POU Run 5 operated In
syncrude mode, over fresh ICR
106 catalyst for production
of jet/diesel fuel (Chevron
Run 76-171, Hours 222-246).
Operating conditions:
catalyst temperature. 750*F;
LHSV, 1.0
From hydrotreatlng of rerun 95
H-Coal syncrude feed from PDU
Run 5 operated In syncrude
made over fresh ICR 106
catalyst for production of
jet/diesel fuel (Chevron Run
76-173, Hours 463-475).
Operating conditions:
catalyst temperature. 748'F;
LHSV. 1.5.
From hydrotreating of 95
H-Coal syncrude feed (boiling
range 120-650'F) from POU
Run 6 operated in syncrude
mode, over fresh ICR 106
catalyst for production of
jet/diesel fuel (Chevron Run
76-173, Hours 331-355).
Operating conditions:
catalyst temperature, 752'F;
LHSV, 1.0.
(Continued)
-------
Material Process Coal Type
Table 264 (Continued)
Value (Wt «)
Naphtha
fro*
hydro-
treated
coal
liquid
H-Coil
IL No. 6
tolling Range. *f C5-180 160-250
Sulfur HA 0.000022
IL No. 6
Boiling Range. 'F Cg-lSO 180-250
Sulfur NA 0.000020
en
CO
--J
Boiling Range. T C5-180
Uyodak
Sulfur
NA
lBOj-250
0.000021
Wyodak
Boiling Range. "F C5-180
Sulfur NA
180-250 250-300 300-350
0.00005 0.000071 0.000051
Sample Description/Source deference
Froa hydrotreatlng of 95
H-Coal syncrude feed
(boiling range 140-704'F)
fro« PDU Run 5 operated In
syncrude Mode, over aged ICR
106 catalyst for production
of jet/dlesel fuel (Chevron
Run 76-171. Hours 3191-3215).
Operating conditions:
catalyst tenperature. 774'F;
LHSV. 0.5.
Frooi hydrotreatlng of rerun 95
H-Coal syncrude feed from PDU
Run 5 operated In syncrude
•ode, over aged ICR 106
catalyst for production of
jet/dlesel fuel (Chevron Run
76-174. Hours 76-174).
Operating conditions:
catalyst temperature, 802*F;
LHSV. 1.5.
Froo hydrotreatlng of 95
H-Coal syncrude feed (boiling
range 120-650'F) from PDU
Run 6 operated In syncrude
node, over aged ICR 106
catalyst for production of
Jet/dlesel fuel (Chevron Run
76-174, Hours 208-232).
Operating conditions:
catalyst temperature, 802*F;
LHSV, 1.0.
Froa hydrotreatlng of rerun 95
H-Coal syncrude feed fro* PDU
Run 6 operated in syncrude
node, over aged ICR 106
catalyst for production of
jet/dtese) fuel (Chevron Run
76-174. Hours 604-610).
Operating conditions:
catalyst temperature. 803"F;
LHSV, 1.5.
(Continued)
-------
Table 264 (Concluded)
Material Process Coal Tyi
H-Coal 11 No. f
Vtlue (Ml «1
Sanple Description/Source Reference
trim
kydro-
treatad
cot)
Rolling Range. "F Cj-lM
Sulfur M
180-250
0.000018
HO-MO
0.00002*
300-350
0.000047
II »0. i
Sulfur
OlJIlM
0.000021
. •
Sulfur
Oiyge*
M
0.0003
O.OlfO
0.00033
M
a no. •
Sulfur
Oiygu
HA
0.000011
M
0.00002i
M
M Fro* e»d*r
-------
Table 265. Hydrocarbon Class Analysis of Various Distillation Fractions
of Non-Primary Coal Naphthas and Gasoline
M*ter Ul Process
Coal Type
Value (Vol <)
Boiling Range,
C5-I80'F
Period 1* Period 2* Period 3* Period 4*
Coal ran
naptha
Naphtha fro*
hydrotreated
coal liquid
NA
SRC-11
KY No. 9
and 14.
IL No. 6
(King River
Nine) and
Pitt-Se»s UV
(Blackvllle
No. 2 Mine)
Saturates?
AroMttcs
Saturates!
Aronatlcs
97.6
2.4
97.0
3.0
98. 0
2.0
NA
HA
Boiling Range. 'F Cj-180
H-Coal
IL No. 6
Saturates
Aronatics
in
00
IL No. 6
Saturates
Aromatic*
Uyodak
Saturates
Aromatlcs
98.0
2.0
NA
NA
98.4
1.6
NA
NA
87.3
12.7
82.9
17.1
NA
HA
180-250 250-300 300-350
98.1
1.9
98.2
1.8
98.3
1.7
98.4
1.6
NA
NA
NA
NA
98.1
1.8
98.0
2.0
97.2
2.8
Sample Description/Source Reference
Ft. Lewis pilot plant. 86
400*F+ SRC-II liquid
hydrotreated with ICR 106
catalyst (Run No. 76-166).
Operating conditions for
periods 1 through 4
respectively: time on-
stream. hr , 145-169.
169-193. 313-337.
337-361; average catalyst
temperature, *F, 746. 751.
752. 752; LHSV, 0.55. 0.43.
0.99 and 0.99.
Fro* hydrotreatlng of 95
H-Coal syncrude feed
(boiling range 140-704'F)
fro* POU Run 5 operated In
syncrude mode, over fresh ICR
106 catalyst for production
of jet/diesel fuel (Chevron
Run 76-171. Hours 222-246).
Operating conditions:
catalyst temperature, 750*F;
LHSV. 1.0
From hydrotreatlng of rerun 95
H-Coal syncrude feed from PDU
Run 5 operated in syncrude
mode over fresh ICR 106
catalyst for production of
jet/diesel fuel (Chevron Run
76-173. Hours 463-475).
Operating conditions:
catalyst temperature, 748'F;
LHSV. 1.5.
From hydrotreatlng of 95
H-Coai syncrude feed (boiling
range 1ZO-650'F) from PDU
Run 6 operated In syncrude
mode, over fresh ICR 106
catalyst for production of
jet/diese) fuel (Chevron Run
76-173. Hours 331-355).
Operating conditions:
catalyst temperature. 752~F;
LHSV. 1.0.
(Continued)
-------
Material Process
Table 265 (Continued)
Value (Vol <)
Bolting flange, 'f C5-180 180-250 250-300 300-350
Sample Description/Source Reference
Naphtha
from
hydro-
treated
coal
liquid
H-Coal
IL No. 6
IL No. 6
tn
IO
O
Uyodak
Wyodak
Saturates 94.5 93.6 NA NA From hydrotreatlng of 95
Aroaattcs 5.5 6.4 NA NA H-Coal syncrude feed
(boiling range 140-704'f)
from POU Run 5 operated In
syncrude mode, over aged ICR
106 catalyst for production
of jet/diesel fuel (Chevron
Run 76-171. Hours 3191-3215).
Operating conditions:
catalyst temperature, 774'F;
LHSV. 0.5.
Saturates NA 95.8 NA NA From hydrotreatlng of rerun 95
Aroaatlcs NA 4.2 NA NA H-Coal syncrude feed from PDU
Run S operated In syncrude
mode, over aged ICR 106
catalyst for production of
Jet/diesel fuel (Chevron Run
76-174. Hours 76-174).
Operating conditions:
catalyst temperature. 802*F;
LHSV. 1.5.
Saturates NA 93.8 HA NA Fran hydrotreating of 95
Aro«atlcs NA 6.2 NA NA H-Coal syncrude feed (boiling
range 120-650"F) from PDU
Run 6 operated in syncrude
mode, over aged ICR 106
catalyst for production of
Jet/diesel fuel (Chevron Run
76-174. Hours 208-232).
Operating conditions:
catalyst temperature. 802'F;
LHSV. 1.0.
Saturates 97.4 95.8 92.9 93.0 From hydrotreating of rerun 95
Aronattcs 2.6 4.2 7.1 7.0 H-Coal syncrude feed from PDU
Run 6 operated In syncrude
mode, over aged ICR 106
catalyst for production of
Jet/diesel fuel (Chevron Run
76-174. Hours 604-610).
Operating conditions:
catalyst temperature. 803'F;
LHSV. 1.5.
(Continued)
-------
Table 265 (Continued)
Material Process
Coal Type
Boiling Range. *f C&-180
Value (Vol t)
180-250 250-300 300-350
Sample OescrlptIon/Source Reference
Naphtha H-Coal 1L No. 6 Saturates 93.9 86.9 75.9 73.8 From moderate hydrotreattng 95
froa AroMtlcs 6.1 13.1 24.1 26.2 of H-Coa) syncrude feed
hydro- (boiling range 140-704°F)
treated from POU Run 5 operated in
coal syncrude mode, over ICR
Uquld 106 catalyst for production
of heating oil (Chevron
Run 76-171. Hours 1967-1991).
Operating conditions:
catalyst temperature, 775°f;
LHSV. 1.5.
Hyodak Saturates MA 90.7 NA HA Froa Moderate hydrotreatlng of 95
Aromatic* NA 9.2 NA NA H-Coal syncrude feed (boiling
range 120-650"F) from PDU Run
6 operated In syncrude node.
over ICR 113 catalyst for
production of heating oil
(Chevron Run 66-203, Hours
1366-1390). Operating condl-
•n tlons: catalyst temperature.
10 747°F; LHSV. 1.5.
~* IL No. 6 Saturates 92.5 87.9 77.4 75.0 Froa moderate hydrotreatlng of 95
Arowtics 7.5 12.1 22.6 25.0 H-Coal syncrude feed (boiling
range 140-704'F) from PDU
Run 5 operated In syncrude
•ode. over ICR 106
catalyst for production of
fuel oil (Chevron Run
76-171. Hours 654-678).
Operating conditions:
catalyst temperature, 7SO°F;
LHSV. 1.5; total pressure,
2493 pslg; hydrogen pressure.
2231 psia.
IL No. 6 Saturates 93.6 86.8 80.5 73.9 From moderate hydrotreatlng 95
AroMtlcs 6.2 13.1 19.5 26.1 of H-Coal syncrude feed
(boiling range 140-704°F)
from PDU Run 5 operated In
syncrude mode, over ICR
106 catalyst for production
of fuel oil (Chevron Run
76-171. Hours 1535-1659).
Operating conditions:
catalyst temperature 750°F;
LHSV. 1.5; total pressure
2001 pslg; hydrogen pressure
1778 psia.
(Continued)
-------
Table 265 (Concluded)
01
U3
Material Process
Value (Vol K)
Sample Description/Source Reference
Boiling Range. "F C5-180
180-250 250-300 300-350
Naphtha
frou
hydro-
treated
coal
liquid
H-Coal
IL No. 6
Saturates
Aroaatics
93.9
6.1
86,9
13.1
75.9
24.1
73.8
26.2
Explanatory Notes;
*Each pertod refers to a run time having a characteristic set of operating conditions.
tfty Low Resolution Mass Spectroscopy.
fBy Chromatography
from moderate hydrotreating of 95
H-Coal syncrude feed
(boiling range 140-704'F)
from POD Run & operated In
syncrude node, over ICR
106 catalyst for production
of fuel oil (Chevron Run
76-171. Hours 1976-1991).
Operating conditions:
catalyst temperature, 775*F;
LHSV, 1.5; total pressure.
2075 psig; hydrogen pressure.
1859 psta.
-------
Explanatory Notes
1. Operating data are reported when available from the reference cited or
from other readily available sources.
2. Data cited from Reference 83 from SRC-I Ft. Lewis pilot plant runs with
Kentucky Nos. 9 and 14 coals are typical values obtained under the wide
range of operating conditions summarized below:
Material Production Laboratory
Run Balance Runs Run Merriam, Ka.
Feed Slurry
Coal Cone. (wt%) 35-40 35-40 35-50
Total Space Rate
(lb/hr/ft3 29-98.8 68-203
Reactor Temperature
(°F) 844-870 840-860 816-869
Reactor Pressure
(psig) 1027-1528 1410-2000
Gas Feed Rate,
Thousands (SCF/T) 14.0-21.3 17.2-57.2
Total Coal
Conversion 93-94 93-96
H2 Consumption
(% MAF Feed Coal) 1.9-3.6 1.4-3.5
SRC Yield
(% MAF Feed Coal 58.3-67.3 33.7-63.5
Gas Yield (%) 4.9-8.7 5.7-20.4
Liquid Yield (%) 6.6-17.7 9.5-24.8
Sulfur in SRC (%) 0.76 (avg) 0.56-0.92 0.36-0.84
3. Data cited for Reference 97 for H-coal naphtha derived from PDU atmospheric
and vacuum still overhead streams are for the following operating conditions:
2.245 psig at the reactor outlet and 850°F reactor temperatures. In the
fuel oil mode of operation, a coal feed rate of 62.4 lbs/hr/ft3 reactor
(Continued)
593
-------
with hot separator reactor slurry recycle of 1.045 Ibs/lb coal and a dis-
tillate recycle of 1.40 Ibs/lb coal yielded a feed slurry containing 29.03
weight-percent coal. The blend of material produced by the reactor oper-
tion consisted of 27.9 weight-percent overhead produce (distillate) and
72.1 weight-percent vacuum bottoms product. In the syncrude mode of
operation, a coal feed rate of 31.2 Ibs/hr/ft^ reactor with a hot separator
reactor slurry recycle of 3.98 Ibs/lb coal and a distillate recycle of 0.40
Ibs/lb coal yielded a feed slurry containing 20.08 weight-percent coal.
The blend of material produced by the reactor in the syncrude mode of
operation consisted of 48.2 weight-percent overhead product and 51.8
weight-percent vacuum bottoms product. The amount of reacted hydrogen
in the fuel oil and the syncrude mode of operation were determined to be
12.2 and 15.2 Mscf/ton coal, respectively. The catalyst used in both
processes .was American Cyanamid HDS-2A.
4. Data cited in Reference 85 for bench-scale continuous platforming of
hydrotreated coal naphtha Sample No. 3777-2 (UOP Research Plant 636,
Run 335) were obtained under the following operating conditions:
P-P(base), LHSV/LHSV
Period psi T-T(base),°C base
1 0 -121 1.52
2 0 -87 1.48
3 0 -60 '1.50
4 0 -105 1.50
5 0 -87 1.46
5. Data cited in Reference 87 for bench-scale continuous platforming of
moderately hydrotreated coal naphtha Sample No. 3531-12 (UOP Research
Plant 508, Run 1456) were obtained under the following operating
conditions:
P-P(base), LHSV/LHSV
Period psi T-T(base),°C base
1 0 -53 1.55
2 0 -73 1.52
3 0 -86 1.53
4 0 -97 1.52
5 0 -114- 1.52
6 0 -119 1.42
7 0 -120 1.52
8 0 -69 1.51
9 0 -39 1.53
10 0 -6 1.51
(Continued)
594
-------
6. Data cited in Reference 92 for bench-scale continuous platforming of
moderately hydrotreated coal naphtha Sample No. 3531-4 (UOP Research
Plant 636, Run 220) were obtained under the following operating conditons:
P-P(base), LHSV/LHSV
Period psi T-T(base),°C base
1 0 -52 1.43
2 0 -52 1.49
4 0 -59 1.48
5 0 -66 1.51
6 0 -66 1.53
7 0 -78 1.49
8 0 -78 1.45
10 0 -88 1.49
14 0 -18 1.50
7. Data cited for Reference 86 for Chevron coal raw naphtha Sample No. WOW 3750
hydrotreated with ICR 113 catalyst (Run No. 65-194, Run Hours 111-135 and
231-255) respectively, were obtained under the following operating conditions:
Run Hours 111-135 231-255
Avg. Catalyst Temp; °F 692 699
LHSV 1.03 0.95
Total Pressure, psig 799 793
H2 Mean Pressure, psia 642 645
Total Gas In, SCF/.Bbl 4391 4629
Recycle Gas, SCP/Bbl 3282 3449
8. Data cited for Reference 86 for Chevron coal raw naphtha Sample No. SGQ 6502
partially hydrotreated and hydrofined with ICR 113 catalyst (Run No. 72-326,
Run Hours 138-150 and 222-246) respectively, were obtained under the following
operating conditions:
Run Hours 138-150 222-246
Avg. Catalyst Temp; *F 700 70
LHSV 2.02 2.01
Total Pressure, psig 648 638
\\2 Mean Pressure, psia 523 505
Total Gas In, SCF/Bbl 3029 2824
Recycle Gas, SCF/Bbl 2941 2695
9. The following additional motor octane values are available for H-Coal
naphtha derived from the PDU operated in the syncrude mode: 82.9
(IL. No. 6 coal), 65.2 (Wyodak coal), and 73.3 (W. KY No. 11 coal)
(Reference 109).
595
-------
General Comments
10. The following saturates and aromatics were identified in H-Coal naphtha derived
from IL No. 6 Coal, (PDU, syncrude mode) (Ref. 109):
A. Saturates B. Aromatics
Cs Alkane Benzene
Cyclopentane Toluene
CQ Alkane Ethyl benzene
Methylcyclopentane m&p-Xylenes
Cg Alkane o-Xylene
Cyclohexane Cg Aromatic
Dimethylcyclopentane CIQ Aromatic
Methylcyclohexane Naphthalene
Dimethylcyclohexane
Alkane
Cg Cycloalkane
trans-Hydrindane
cis-Hydrindane
Methyl-trans-Hydrindane
Methyl-ci s-Hydri ndane
Trans-Decalin
Indane
cis-Decalin
2-Methylindane
1-Methylindane
Cn aromatic
5-Methylindane
4-Methylindane
Tetralin
2-Methyltetralin
11. A value of 0.2 ppm benzopyrene was determined in SRC-I naphtha obtained from the
Ft. Lewis pilot plant (Reference 146).
596
-------
Part IX. Raw and Hydrotreated Middle Distillates and Blends (Jet, Diesel, Other
Light Fuel Oils)
597
-------
Material
Coal raw
middle
distillates
Table 266. Specifi
Process Coal Type Value
SRC-1* KY No. 9 l.OOO1"
KY No. 9 1.01361"
KY No. 9 0.9679t
Coal raw
middle
distillate
blends
(light
fuel
oils)
KY No. 9 0.9772+
SRC-11 NA
NA
H-Coal IL No. 6
(Burning
Star
Mine)
SRC-II NA
NA
0.97
(60°F)
0.9796
(60.8°F)
0.979
IL No. 6 1.025
(Monterey
Mine)
c Gravity
Sample Description/Source Reference
1.0021
0.9993
(Continued)
598
Wilsonville pilot plant, 82
SRC unit (Run No. 220,
APCI Sample No. 1897CB)
Wilsonville pilot plant, 82
SRC unit (Run No. 225,
APCI Sample No. 1911CB)
Wilsonville pilot plant, 82
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1941CB-1)
Wilsonville pilot plant, 82
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1949CB)
Ft. Lewis pilot plant 102
Ft. Lewis pilot plant 122
Derived from PDU atmos- 97
pheric still overhead
and vacuum still overhead
streams, fuel oil mode
(analyzed by BETC)f
Derived from PDU atmos- 97
pheric still overhead
and vacuum still over-
head streams, syncrude
mode (analyzed by
BETC)f
2.9/1 medium/heavy 113
distillate blend, UOP
Sample No. 3777-6
2.9/1 medium/heavy 113
distillate blend, UOP
Sample No. 3777-7
-------
Material
Hydro-
treated
middle
distillates
(jet/diesel/
other fuel
oil)
Hydro-
treated
middle
distillate
blends
(light
fuel
oils)
Process
NA
Table 266 (Concluded)
Coal Type Value Sample Description/Source Reference
SRC-11
NA
NA
NA
NA
0.9529 Moderately hydrotreated
2.9/1 medium/heavy
distillate blend, whole
liquid product, UOP
Sample No. 3777-21
0.9752 Moderately hydrotreated
2.9/1 medium/heavy
distillate blend,
400°F+ liquid product,
UOP Sample No. 3777-34
0.9135 Generally hydrotreated
2.9/1 medium/heavy
distillate blend, whole
liquid product, UOP
Sample No. 3777-28
0.9484- Generally hydrotreated
2.9/1 medium/heavy
distillate blend,
400°F+ liquid product,
UOP Sample No. 3777-41
Explanatory Notes
113
113
113
113
*The raw middle distillate from the proposed SRC-I demonstration plant will
consist of a 73.3/22.2/4.5 weight percent blend of middle distillates from the
SRC, LC-Finer and coker units, respectively. The calculated specific gravity
of this blend is approximately 0.998 (Reference 100).
^Determined via ASTM D-1298
fSee General Comments section, Note 3, for summary of operating conditions used.
599
-------
Table 267. API Gravity
Material
Coal raw
middle
distillates
Process Coal Type Value
SRC-I* KY No. 9 10.Qt
KY No. 9 8.1f
KY No. 9 14.7f
EDS
H-Coal
KY No. 9 13.31"
SRC-11 NA
13.3
Pittsburgh 13.4
No. 8
(Powhattan
Mine)
IL No. 6
IL No. 6
Wyodak
NA
17.7
15.4
21.4
18.4
IL No. 6 17.5
Sample Description/Source Reference
Wilsonville pilot plant, 82
SRC unit (Run No. 220,
APCI Sample No. 1897CB)
Wilsonville pilot plant,
SRC unit (Run No. 225,
APCI Sample No. 1911CB)
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1941CB-1)
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1949CB)
Ft. Lewis pilot plant
Ft. Lewis pilot plant
Raw 350-650°F distillate
from one tpd pilot plant
380-650°F distillate
from PDU, Run 5, Run
130-82, Period 29?
380-650°F distillate
from PDU Run 6, Run
130-83, Period 17§
>450-650°F distillate
from PDU (EPRI Sample
No. 3)
400-650°F distillate
from PDU, syncrude
mode
82
82
82
84
101
99
111
112
84
98
(Continued)
600
-------
Table 267 (Continued)
Material Process Coal Type
Coal raw. H-Coal IL No. 6
middle (Burning
distillates Star
Mine)
IL No. 6
(Monterey
Mine)
IL No. 6
(Burning
Star
Mine)
NA
IL No. 6
Wyodak
W. KY
No. 11
Value
13.0
6.6
16.7
29.5
15.1
22.7
14.6
IL No. 6 ^37
Wyodak
Coal raw
mi ddle
distillate
blends
(light
fuel
oils)
SRC-II NA
38.0
14.2
Pittsburgh 10.4
No. 8
(Powhattan
Mine)
NA
NA
11.7
10.3
(Continued)
601
Sample Description/Source Reference
Derived from PDU atmos- 97
pheric still overhead
and vacuum still over-
head streams, fuel oil
mode (analyzed by
BETC)#
Derived from PDU atmos-
pheric still overhead
and vacuum still over-
head streams, syncrude
mode (analyzed by BETC)#
PDU (Ashland Oil sample)
260-552°F distillate
derived from atmospheric
still overhead streams
PDU, syncrude mode
PDU, syncrude mode
PDU, syncrude mode
250-600°F distillate,
PDU, syncrude mode
250-600°F distillate,
PDU, syncrude mode
5.75/1 medium/heavy
distillate blend from
Ft. Lewis pilot plant
2.9/1 medium/heavy
distillate blend from
Ft. Lewis pilot plant
5/1 medium/heavy distil-
late blend from Ft.
Lewis pilot plant
5/1 medium/heavy distil-
late blend from Ft.
Lewis pilot plant
97
96
108
109
109
109
95
95
101
101
84
108
-------
Material
Coal raw
middle
distillate
blends
(light
fuel
oils)
Table 267
Process Coal Type Value
SRC-11 NA 9.7
Hydro- SRC-11
treated
middle
distillates
(jet/diesel/
other light
fuel oil) EDS
(Continued)
Sample Description/Source Reference
2.9/1 medium/heavy distil- 113
late blend, UOP Sample
No. 3777-6
NA
NA
NA
10.1
11
11.0
(60°F)
Pitt-Seams 36.3
WV (Black-
ville
No. 2
Mine)
IL No. 6 30
(Monterey
Mine)
IL No. 6 14.7
IL No. 6 18.0
IL No. 6 19.0
2.9/1 medium/heavy distil-
late blend, UOP Sample
No. 3777-7
Medium and heavy distil-
late blend
5.75/1 medium/heavy
distillate blend
Single-stage hydrotreated
<554°F distillate**
Partially hydrotreated
350-650°F distillate
from one tpd pilot
plant
Partially hydrotreated
350-650°F distillate
from one tpd pilot
plant
From low severity
hydrotreatment of
partially hydrotreated
350-650°F distillate
from one tpd pilot
plant
From moderate severity
hydrotreatment of
partially hydrotreated
350-650°F distillate
from one tpd pilot
plant
113
114
121
104
99
99
99
(Continued)
602
-------
Material
Hydro-
treated
middle
distillates
(jet/diesel/
other light
fuel oil)
Table 267 (Continued)
Process Coal Type Value Sample Description/Source Reference
EDS
IL No. 6 30.4
Wyodak
35.2
H-Coal
IL No. 6
(Burning
Star
Mine)
Wyodak
37
Hydro-
treated
middle
distillate
blends
(light
fuel
oils)
SRC-II NA
39.7
17.0
NA
13.6
NA
23.4
From high severity
hydrotreatment of
partially hydrotreated
350-650°F distillate
from one tpd pilot
plant
Raffinate from continuous
extraction (4:1 sulfolane
feed) of 350-525°F hydro-
treated solvent from one
tpd pilot plant
Single-stage hydrotreated
<554°F distillate from
PDUt1"
Single-stage hydrotreated
<554°F distillate from
99
99
88
Moderately hydrotreated
2.9/1 medium/heavy
distillate blend, whole
liquid product, UOP
Sample No. 3777-21
Moderately hydrotreated
2.9/1 medium/heavy
distillate blend,
400°F+ liquid product,
UOP Sample No. 3777-34
Severely hydrotreated
2.9/1 medium/heavy
distillate blend, whole
liquid product, UOP
Sample No. 3777-28
88
113
113
113
(Continued)
603
-------
Table 267 (Concluded)
Process
Coal Type
NA
Sample Description/Source Reference
Severely hydrotreated
2.9/1 medium/heavy
distillate blend, whole
liquid product, UOP
Sample No. 3777-41
Material
Hydro- SRC-II NA 17.7 Severely hydrotreated 113
treated
middle
distil late
blends
(light
fuel
oils)
Explanatory Notes
*The raw middle distillate from the proposed SRC-I demonstration plant will
consist of a 73.3/22.2/4.5 weight percent blend of middle distillates from the
SRC, LC-Finer and coker units, respectively (Reference 100).
'''Determined via ASTM D-1298; measured at 60°F.
tSee General Comments section, Note 4, for summary of operating conditions used.
§See General Comments section, Note 5, for summary of operating conditions used.
Note 3, for summary of operating conditions used.
Note 6, for summary of operating conditions used-
#See General Comments section,
**See General Comments section,
General Comments section, Note 7, for summary of operating conditions used.
604
-------
Table 268. Density
Material Process Coal Type Value Sample Description/Source Reference
Coal raw NA
middle
distillates
Coal raw SRC-II NA 0.9951 Medium and heavy distil- 115
middle late blend, before water
distillate wash, Chevron Sample No.
blends SGQ-7559
(light
fuel oil) NA 0.9885 Medium and heavy distil- 115
late blend, after water
wash, Chevron Sample No.
WOW-4551
Hydro- NA
treated
middle
distillates
(jet/diesel/
other light
fuel oil)
Hydro- NA
treated
middle
distillate
blends
(light
fuel oils)
605
-------
Table 269. Reid Vapor Pressure
Material Process Coal Type Value Sample Description/Source Reference
Coal raw SRC-I* KY No. 9 O.O1" Wilsonville pilot plant, 82
middle SRC unit (Run No. 220,
distillates APCI Sample No. 1897CB)
KY No. 9 O.O"1" Wilsonville pilot plant, 82
SRC unit (Run No. 225,
APCI Sample No. 1911CB)
KY No. 9 O.O1" Wilsonville pilot plant, 82
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1941CB-1)
KY No. 9 O.O1" Wilsonville pilot plant, 82
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1949CB)
Coal raw NA
middle
distillate
blends
(light
fuel oil)
Hydro- NA
treated
middle
distillates
(jet/diesel/
other light
fuel oil)
Hydro- NA
treated
middle
distillate
blends
(light
fuel oils)
Explanatory Notes
*The raw middle distillate from the proposed SRC-I demonstration plant will
consist of a 73.3/22.2/4.5 weight percent blend of middle distillates from
the SRC, LC-Finer and coker units, respectively (Reference 100).
"'"Determined via ASTM D-323.
606
-------
Table 270. Distillation Data
Material
Coal raw
middle
distillates
Process Coal Type
SRC-I* KY No. 9
Value
(%
KY No. 9
KY No. 9
Evaporation)
418°F-IBpt
452°F-10
NA-15
470°F-20
488°F-30
512°F-40
528°F-50
545°F-60
568°F-70
596°F-80
600°F-90
NA-EP
412°F-IBPt
436°F-10
NA-15
452°F-20
470°F-30
487°F-40
502°F-50
528°F-60
550°F-70
578°F-80
600°F-90
606°F-EP
412°F-IBpt
472°F-10
NA-15
487°F-20
496°F-30
541°F-40
546°F-50
570°F-60
584°F-70
596°F-80
605°F-90
618°F-EP
Sample Description/Source
Wilsonville pilot plant,
SRC unit (Run No. 220, APCI
Sample No. 1897CB)
Wilsonville pilot plant,
SRC unit (Run No. 225, APCI
Sample No. 1911CB)
Wilsonville pilot plant,
Lummus LC- Finer unit
(Lummus Run No. 2-LC,
Finer-29, APCI Sample
No. 1941CB-1)
Reference
82
82
82
(Continued)
607
-------
Material
Coal raw
middle
distillates
Table 270 (Continued)
Value
Process Coal Type Evaporation) Sample Description/Source Reference
SRC-1*
SRC-II
H-Coal
KY No. 9
NA
Pittsburgh
No. 8
(Powhattan
Mine)
NA
416°F-IBPt
438°F-10
NA-15
454°F-20
484°F-30
526°F-40
548° F- 50
558°F-60
568°F-70
578°F-80
600°F-90
610°F-EP
210°F-IBPt
NA-5
396°F-10
420°F-30
444°F-50
470°F-70
509°F-90
530°F-95
546°F-EP
220°F-IBpt
390°F-10
408°F-20
414°F-30
424°F-40
434°F-50
446° F- 60
448° F- 70
464°F-80
490°F-90
516°F-EP
352°F-IBpt
402°F-5
418°F-10
444°F-30
458°F-50
508°F-70
576°F-90
616°F-95
685°F-EP
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1949C8)
82
Ft. Lewis pilot plant
84
Ft. Lewis pilot plant
101
450-650°F distillate
from POD
84
(Continued)
608
-------
Table 270 (Continued)
Material
Coal raw
middle
distillates
Process Coal Type
H-Coal
Value
(X
Evaporation) Sample Description/Source
IL No. 6
(Burning
Star
Mine)
IL No. 6
Wyodak
452°F-IBP PDU (Ashland Oil Sample)
452°F-5
452°F-10
454°F-20
470°F-30
492°F-40
514°F-50
534°F-60
570°F-70
592°F-80
616°F-90
630°F-95
636°F-EP
398°F-IBP 380-650°F distillate
423°F-5 from PDU Run 5, Run
438T-10 130-82, Period 29**
455°F-20
467°F-30
482°F-40
500°F-50
522°F-60
548° F- 70
570°F-80
605°F-90
620°F-95
634°F-EPt»#
396°F-IBP 380-650°F distillate
418°F-5 from PDU Run 6, Run
426°F-10 130-83, Period 17tt
435°F-20
446°F-30
455°F-40
474°F-50
496°F-60
530°F-70
575°F-80
608°F-90
625°F-95
640°F-EP
Reference
96
111
112
(Continued)
609
-------
Table 270 (Continued)
Material
Coal raw
middle
distillate
blends
(light
fuel oils)
Process
SRC-11 NA
Value
(X
Coal Type
NA
Pittsburgh
No. 8
(Powhattan
Mine)
NA
NA
Evaporation)
226°F-IBPt
384°F-10
398°F-20
410°F-30
428°F-40
448° F- 50
460°F-60
486°F-70
518°F-80
566°F-90
604°F-EP
230°F-IBpt
386°F-10
408°F-20
424°F-30
428°F-40
448° F- 50
478°F-60
498°F-70
536°F-80
618°F-90
658°F-EP
220°F-IBPt
382°F-5
404°F-10
433°F-30
459°F-50
491°F-70
578°F-90
640°F-95
640°F-EP
386/407°F-
IBP§
417/445°F-
10/30
486°F-50
535/645°F-
70/90
711/799°F-
95/EP
(Continued)
610
Sample Description/Source
5.75/1 medium/heavy distil
late blend from Ft. Lewis
pilot plant
2.9/1 medium/heavy distil-
late blend from Ft. Lewis
pilot plant
5/1 medium/heavy distil-
late blend from Ft. Lewis
pilot plant
2.9/1 medium/heavy distil-
late blend, UOP Sample
No. 3777-6
Reference
- 101
101
84
113
-------
Material
Coal raw
middle
distillate
blends
(light
fuel oils)
Table 270 (Continued)
Value
Process Coal Type Evaporation) Sample Description/Source Reference
SRC-11 NA
Hydro-
treated
middle
distillates
(jet/diesel/
other light
fuel oil)
EDS
IL No. 6
IL No. 6
IL No. 6
IL No. 6
Wyodak
325/395°F-
IBP§
410/444°F-
10/30
472°F-50
512/656°F-
70/90
705/810°F-
95/EP
376°F-10
431°F-50
560°F-90
341°F-10
411°F-50
552°F-90
328°F-10
408°F-50
547°F-90
316°F-10
386°F-50
509°F-90
392°F-IBP
514°F-EP#
2.9/1 medium/heavy distil-
late blend, UOP Sample
No. 3777-7
113
Partially hydrotreated
350-650°F distillate
from one tpd pilot plant
From low severity hydro-
treatment of partially
hydrotreated 350-650°F
distil late from one
tpd pilot plant
From moderate severity
hydrotreatment of
partially hydrotreated
350-650°F distillate
from one tpd pilot
plant
From high severity
hydrotreatment of
partially hydrotreated
350-650°F distillate
from one tpd pilot
plant
Raffinate from continu-
ous extraction (4:1
sulfolane: feed) of
350-525°F hydrotreated
solvent from one tpd
pilot plant
99
99
99
99
99
(Continued)
611
-------
Material
Hydro-
treated
middle
distillate
blends
(light
fuel oils)
Table 270 (Continued)
Value
Process Coal Type Evaporation) Sample Description/Source Reference
SRC-11 NA
NA
NA
NA
280/350°F-
IBP§
374/422°F-
10/30
460°F-50
505/611°F-
70/90
687/779°F-
95/EP
418/428°F-
IBP§
436/462°F-
10/30
487°F-50
539/641°F-
70/90
691/790°F-
95/EP
234/302°F-
IBP§
331/400°F-
10/30
446°F-50
490/575°F-
70/90
628/724°F-
95/EP
408/440°F-
IBP§
448/463°F-
10/30
490°F-50
536/625°F-
70/90
668/748°F-
95/EP
(Continued)
Moderately hydrotreated
2.9/1 medium/heavy
distillate blend, whole
liquid product, UOP
Sample No. 3777-21
113
Moderately hydrotreated
2.9/1 medium/heavy
distillate blend, 400°F+
liquid product, UOP
Sample No. 3777-34
113
Severely hydrotreated
2.9/1 medium/heavy
distillate blend, whole
liquid product, UOP
Sample No. 3777-28
113
Severely hydrotreated
2.9/1 medium/heavy
distillate blend, 400°F+
liquid product, UOP
Sample No. 3777-41
113
612
-------
Table 270 (Concluded)
Explanatory Notes
*The raw middle distillate from the proposed SRC-I demonstration plant will consist
of a 73.3/22.2/4.5 weight percent blend of middle distillates from the SRC,
LC-Finer and coker units, respectively (Reference 100).
^Determined via ASTM D-86.
f98% recovery.
§Determined via ASTM D-1160.
#1.0% residue, 1.0% loss.
**See General Comments section, Note 4, for summary of operating conditions used.
"'"''See General Comments section, Note 5, for summary of operating conditions used.
613
-------
Table 271. GC Simulated Distillation Data
Material
Coal raw
middle
distillates
Process Coal Type
SRC-I* KY No. 9
KY No. 9
KY No. 9
Boiling
Point
Range
385°F-
424°F-10
441°F-15
453°F-20
482°F-30
508°F-40
534°F-50
557°F-60
584°F-70
604°F-80
628°F-90
741°F-EP
384°F.
415°F.
MA-
445°F.
464°F.
488°F.
515°F.
538°F.
561°F.
594°F.
612°F.
699°F.
393°F.
447°F.
471°F.
492°F.
525°F.
544°F.
566°F.
585°F.
601°F.
617°F.
634°F.
661°F.
• ISP1"
•10
•15
•20
•30
•40
•50
•60
• 70
•80
• 90
• EP
• ISP*
•10
•15
•20
•30
•40
• 50
•60
• 70
-80
•90
•EP
Sample Description/Source Reference
Wilsonville pilot plant,
SRC unit (Run No. 220,
APCI Sample No. 1897CB)
82
Wilsonville pilot plant,
SRC unit (Run No. 225,
APCI Sample No. 1911CB)
82
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1941CB-1)
82
(Continued)
614
-------
Table 271 (Continued)
Material
Coal raw
middle
distillates
Process
SRC-I*
SRC-II
H-Coal
Coal Type
KY No. 9
KY No. 9
NA
NA
Boil ing
Point
Range :
3970F-IBpf 1
443°F-10 1
482°F-15
511°F-20 1
533°F-30 1
549°F-40
568°F-50
588°F-60
606°F-70
627°F-80
674°F-90
NA-EP
406°F-IBPt ]
446°F-10
455°F-15 :
467°F-20
488° F- 30
509°F-40
528°F-50
547°F-60
572°F-70
598°F-80
61 3° F- 90
676°F-EP
279°F-IBpt l
331°F-5
355°F-10
399°F-30
439°F-50
472°F-70
514°F-90
535°F-95
584°F-EP
295°F-IBPt
367°F-5
389°F-10
426°F-30
458°F-50
500°F-70
558°F-90
586°F-95
685°F-EP
(Continued)
615
Sample Description/Source Reference
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1949CB)
82
Wilsonville pilot plant,
Alcoa coker unit, (APCI
Sample No. 1899CB)
82
Ft. Lewis pilot plant
84
450-650°F distillate
from POU
84
-------
Table 271 (Continued)
Material Process
Coal raw H-Coal
middle
distillates
Boiling
Point
Coal Type Range
IL No. 6 4080F-IBpt
435°F-5
443°F-10
459°F-20
477°F-30
492°F-40
509°F-50
525°F-60
540°F-70
558°F-80
583°F-90
598°F-95
657°F-EP
Wyodak 365°F-IBpt
400°F-5
415°F-10
435°F-20
447°F-30
456°F-40
469°F-50
485°F-60
497°F-70
516°F-80
543°F-90
567°F-95
602°F-EP
W. KY 392°F-IBPt
No. 11 406°F-5
420°F-10
447°F-20
470°F-30
495°F-40
520°F-50
546°F-60
570°F-70
594°F-80
624°F-90
648°F-95
703°F-EP
Sample Description/Source Reference
PDU, syncrude mode 109
POD, syncrude mode 109
PDU, syncrude mode 109
(Continued)
616
-------
Table 271 (Concluded)
Material
Coal raw
middle
distillate
blends
(light
fuel oils)
process Coal Type
SRC-11 NA
NA
NA
NA
Boiling
Point
Range
276°F-iBPt
331°F-5
358°F-10
404°F-30
445°F-50
482°F-70
540°F-90
593°F-95
762°F-EP
284°F-IBP
468°F-
average
739°F-EP
297°F-IBP
469°F-
average
754°F-EP
Sample Description/Source Reference
5/1 medium/heavy distil-
late blend from Ft. Lewis
pilot plant
84
Medium and heavy distil-
late blend, before water
wash, Chevron Sample No.
SGQ-7559
Medium and heavy distil-
late blend, after water
wash, Chevron Sample No.
WOW-4551
115
115
Hydro-
treated
middle
distillates
(jet/diesel ,
other light
fuel oil)
Explanatory Notes
*The raw middle distillate from the proposed SRC-I demonstration plant will consist
of a 73.3/22.2/4.5 weight percent blend of middle distillates from the SRC,
LC-Finer and coker units, respectively (Reference 100).
"^Determined via ASTM D-2887.
^Determined by ASTM D-2887 modified by decreasing the distillation rate to
prevent foaming.
617
-------
Table 272. Refractive Index
Material
Coal raw
middle
distillates
Process Coal Type
H-Coal IL No. 6
IL No. 6
Wyodak
NA
Value Sample Description/Source Reference
1.514 400-650°F distillate 98
(68°F) from PDU, syncrude mode
1.529 380-650°F distillate from 111
(68°F) PDU Run 5, Run 130-82
Period 29*
1.5308 380-650°F distillate from 112
(68°F) PDU Run 6, Run 130-83
Period 17'
Coal raw
middle
distillate
blends
(light
fuel oil)
Hydro- NA
•treated
middle
distillates
(jet/diesel/
other light
fuel oil)
Hydro- NA
treated
middle
distillate
blends
(light
fuel oils)
Explanatory Notes
*See General Comments section, Note 4, for summary of operating conditions used.
"''See General Comments Section, Note 5, for summary of operating conditions used.
618
-------
Table 273. Molecular Weight
Material
Coal raw
middle
distillates
Process Coal Type
SRC-I* KY No. 9
H-Coal
Coal raw
middle
distillate
blends
(light
fuel
oils)
Hydro-
treated
middle
distillate
blends
(jet/diesel/
other light
fuel oil)
NA
NA
Value
(g/mole)
1601"
KY No. 9 13Qt
KY No. 9 2051"
KY No. 9 1901"
IL No. 6
Wyodak
W. KY
No. 11
186
177
175
Sample Description/Source Reference
Wilsonville pilot plant, 82
SRC unit (Run No. 220,
APCI Sample No. 1897CB)
Wilsonville pilot plant,
SRC unit (Run No. 225,
APCI Sample No. 1911CB)
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1941C8-1)
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1949CB)
PDU, syncrude mode
POD, syncrude mode
PDU, syncrude mode
82
82
82
109
109
109
(Continued)
619
-------
Table 273 (Concluded)
Value
Material Process Coal Type (g/tnole) Sample Description/Source Reference
Hydro- NA
treated
middle
distillate
blends
(light
fuel
oils)
Explanatory Notes
*The raw middle distillate from the proposed SRC-I demonstration plant will
consist of a 73.3/22.2/4.5 weight percent blend of middle distillates from the
SRC, LC-Finer and coker units, respectively (Reference 100).
"^Determined via APCI method.
620
-------
Table 274. Total Acid Number
Value
Material Process Coal Type (mg KOH/g) Sample Description/Source Reference
Coal raw SRC-1* KY No. 9 22.51"
middle
distillates
KY No. 9 19.43"1"
KY No. 9 4.83"1"
KY No. 9 4.641"
Wilsonville pilot plant, 82
SRC unit (Run No. 220,
APCI Sample No. 1897CB)
Wilsonville pilot plant, 82
SRC unit (Run No. 225,
APCI Sample No. 1911CB)
Wilsonville pilot plant, 82
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1941CB-1)
Wilsonville pilot plant, 82
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1949CB)
Coal raw NA
middle
distillate
blends
(light
fuel
oils)
Hydro- NA
treated
middle
distil late
blends
(jet/diesel/
other light
fuel oil)
Hydro- NA
treated
middle
distillate
blends
(light
fuel
oils)
Explanatory Notes
*The raw middle distillate from the proposed SRC-I demonstration plant will
consist of a 73.3/22.2/4.5 weight percent blend of middle distillates from the
SRC, LC-Finer and coker units, respectively (Reference 100).
tDetermined via ASTM D-664.
621
-------
Table 275. Gum Content
Material
Coal raw
middle
distillates
Coal raw
middle
distillate
blends
(light
fuel
oils)
Hyd ro-
treated
middle
distillates
blends
(jet/diesel/
other light
fuel oil)
Process
H-Coal
SRC-11
EDS
H-Coal
Coal Type
IL No. 6
Wyodak
Value
(mg/100 ml) Sample Description/Source Reference
1 250-600°F distillate, 95
1
Pitt-Seams 2
WV (Black-
vine
No. 2
Mine)
Wyodak
3.2
IL No. 6
(Burning
Star
Mine)
Wyodak
250-600°F distillate,
PDU, syncrude mode
250-600°F distillate,
PDU, syncrude mode
Single-stage hydretreated
<554°F distillate*
Raffinate from continuous
extraction (4:1 sulfolane;
feed) of 350-525°F hydro-
treated solvent from one
tpd pilot plant
Single-stage hydrotreated
<554°F distillate from
PDU1"
Single-stage hydrotreated
554°F distillate from
PDU1"
NA
95
88
99
88
88
Hydro-
treated
middle
distillate
blends
(light
fuel
oils)
Explanatory Notes
*See General Comments section, Note 6, for summary of operating conditions used.
'''See General Comments section, Note 7, for summary of operating conditions used.
622
-------
Table 276. Viscosity
Material
Coal raw
middle
Process Coal Type
SRC-I* KY No. 9
KY No. 9
KY No. 9
EDS
Value
(Centistokes) Sample Description/Source Reference
13.445 (68°F)t Wilsonville pilot plant, 82
6.029 (104°F) SRC unit (Run No. 220,
3.441 (140°F) APCI Sample No. 1897CB)
KY No. 9
9.367 (68°F)t Wilsonville pilot plant,
4.715 (104°F) SRC unit (Run No. 225,
2.851 (140°F) APCI Sample No. 1911CB)
8.46 (68°F)t Wilsonville pilot plant,
4.62 (104°F) Lummus LC-Finer unit
2.92 (140°F) (Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1941CB-1)
7.137 (68°F)t Wilsonville pilot plant,
3.998 (104°F) Lummus LC-Finer unit
2.581 (140°F) (Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1949CB)
SRC-II NA
3.20 (104°F)
1.08 (212°F)
Pittsburgh 36.4 (SSU at
No. 8 140°F)
(Powhattan
Mine)
31.8 (SSU at
210°F)
Ft. Lewis pilot plant
Ft. Lewis pilot plant
NA
NA
6.3 (60°F)
3.55 x 10-6
m2/s (100.6°F)
IL No. 6 0.7 (100°F)
H-Coal IL No. 6
NA
46 (SSU at
72°F)
2.56 (104°F)
0.99 (212°F)
(Continued)
Ft. Lewis pilot plant
Ft. Lewis pilot plant
Raw 350-650°F distillate
from one tpd pilot plant
380-650°F distillate
from PDU Run 5, Run
130-82, Period 29f
450-650°F distillate
from PDU
82
82
82
84
101
102
122
99
111
84
623
-------
Table 276 (Continued)
Material
Process Coal Type
Value
(Centistokes)
Sample Description/Source Reference
Coal raw H-Coal
middle
distillates
IL No. 6
IL No. 6
(Burning
Star
Mine)
IL No. 6
(Monterey
Mine)
4.1 (100°F)
2.4 (210°F)
3.87 (100°F)t
39 (SSU at
100°F)
14.90 (100°F)t
77 (SSU at
100°F)
400-650°F distillate
from PDU, syncrude mode
Derived from PDU atmos-
pheric still overhead
and vacuum still over-
head streams, fuel oil
mode (analyzed by BETC)§
Derived from PDU atmos-
pheric still overhead and
vacuum still overhead
streams, syncrude mode
(analyzed by BETC)§
98
97
97
NA
IL No. 6
Wyodak
W. KY
No. 11
Coal raw
middle
distillate
blends
(light
fuel oils)
SRC-II NA
Pittsburgh
No. 8
(Powhattan
Mine)
NA
1.17 (100°F)
3.369 (104°F)
1.224 (212°F)
2.280 (104°F)
0.950 (212°F)
3.516 (104°F)
1.067 (212°F)
35.7 (SSU at
140°F)
32.6 (SSU at
210°F)
36.8 (SSU at
140°F)
33.0 (SSU at
210°F)
3.87 (104°F)
1.19 (212°F)
(Continued)
260-552°F distillate
derived from atmospheric
still overhead streams
PDU, syncrude mode
PDU, syncrude mode
PDU, syncrude mode
5.75/1 medium/heavy
distillate blend from
Ft. Lewis pilot plant
2.9/1 medium/heavy
distillate blend from
Ft. Lewis pilot plant
5/1 medium/heavy distil
late blend from Ft.
Lewis pilot plant
108
109
109
109
101
101
84
624
-------
Table 276 (Continued)
Material
Coal raw
middle
distillate
blends
(light
fuel oils)
Process Coal Type
SRC-11 NA
NA
Value
NA
Hydro-
treated
middle
distillates
(jet/diesel/
other light
fuel oil)
EDS
NA
IL No. 6
(Monterey
Mine)
(Centistokes) Sample Description/Source Reference
4.42 (100°F)
9.94
9.39
40 (SSU at
100°F)
32 (SSU at
100°F)
IL No. 6 2.1 (100°F)
IL No. 6 1.9 (100°F)
IL No. 6 1.9 (100°F)
IL No. 6 1.9 (100°F)
(Continued)
625
5/1 medium/heavy distil- 108
late blend from Ft. Lewis
pilot plant
Medium and heavy distil- 115
late blend, before water
wash, Chevron Sample
No. SGQ-7559
Medium and heavy distil- 115
late blend, after water
wash, Chevron Sample No.
WOW-4551
5.75/1 medium/heavy 121
distillate blend
Partially hydrotreated 104
350-650°F distillate
from one tpd pilot
plant
Partially hydrotreated 99
350-650°F distillate
from one tpd pilot
plant
From low severity 99
hydrotreatment of
partially hydrotreated
350-650°F distillate
from one tpd pilot
plant
From moderate severity 99
hydrotreatment of
350-650°F distillate
from one tpd pilot
plant
From high severity 99
hydrotreatment of
partially hydrotreated
350-650°F distillate
from one tpd pilot
plant
-------
Table 276 (Concluded)
Value
Material Process Coal Type (Centistokes) Sample Description/Source Reference
Hydro- EDS Wyodak 5.5 (5°F) Raffinate from continuous 99
treated extraction (4:1 sulfolane:
middle feed) of 350-525°F hydro-
distillates treated solvent from
(jet/diesel/ one tpd pilot plant
other light
fuel oil)
Hydro- NA
treated
middle
distillate
blends
(light
fuel oils)
Explanatory Notes
*The raw middle distillate from the proposed SRC-I demonstration plant will
consist of a 73.3/22.2/4.5 weight percent blend of middle distillates from the
SRC, LC-Finer and coker units, respectively (Reference 100).
"^Determined via ASTM D-445.
General Comments section, Note 4, for summary of operating conditions used.
§See General Comments section, Note 3, for summary of operating conditions used.
626
-------
Material
Coal raw
middle
distillates
Table 277. Pour Point
Process Coal Type Value (°F) Sample Description/Source Reference
SRC-I* KY No. 9
KY No. 9
KY No. 9
SRC-11
H-Coal
NA
NA
NA
IL No. 6
Wyodak
NA
IL No. 6
9"1" Wilsonville pilot plant, 82
(Run No. 220, APCI Sample
No. 1897CB)
-40+ Wilsonville pilot plant, 82
(Run No. 225, APCI Sample
No. 1911CB)
-421" Derived from tummus 82
LC-Finer unit for the
Wilsonville pilot plant
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1941CB)
-45"1" Derived from Lummus 82
LC-Finer unit for the
Wilsonville pilot plant
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1949CB)
<-65 Ft. Lewis pilot plant 84
<-45 Ft. Lewis pilot plant 102
-0.4 Ft. Lewis pilot plant 122
-35 380-650°F distillate 111
from PDU Run 5, Run
130-82, Period 29?
-10 380-650°F distillate 112
from PDU Run 6, Run
130-83, Period 17f
<-65.0 450-650°F distillate 84
from PDU
-100 400-650°F distillate 98
from PDU, syncrude
mode
(Continued)
627
-------
Material
Coal raw
middle
distillates
Table 277 (Continued)
Process Coal Type Value (°F) Sample Description/Source Reference
H-Coal
Coal raw
middle
distillate
blends
(light
fuel oils)
Hydro-
treated
middle
distillates
(jet/diesel/
other light
fuel oil)
EDS
IL No. 6
(Burning
Star
Mine)
IL No. 6
(Monterey
Mine)
NA
SRC-11 NA
NA
NA
IL No. 6
(Monterey
Mine)
<5
<5
-65
IL No. 6
Wyodak
W. KY
No. 11
-35
-25
-60
<-65
-60
-30
-70
Derived from PDU atmos- 97
pheric still overhead and
vacuum still overhead
streams, fuel oil mode
(analyzed by BETC)§
Derived from PDU atmos- 97
pheric still overhead
and vacuum still
overhead streams,
syncrude mode (analyzed
by BETC)§
260-552°F distillate 108
derived from atmospheric
still overhead streams
PDU, syncrude mode 109
PDU, syncrude mode 109
PDU, syncrude mode 109
5/1 medium/heavy 84
distillate blend from
Ft. Lewis pilot plant
5/1 medium/heavy 108
distillate blend from
Ft. Lewis pilot plant
5.75/1 medium/heavy 121
distillate blend
Partially hydrotreated 104
350-650°F distillate
from one tpd pilot
plant
(Continued)
628
-------
Material
Hydro-
treated
middle
distillate
blends
(light
fuel oils)
Table 277 (Concluded)
Process Coal Type Value (°F) Sample Description/Source Reference
NA
Explanatory Notes
*The raw middle distillate from the proposed SRC-I demonstration plant will
consist of a 73.3/22.2/4.5 weight percent blend of middle distillates from the SRC,
LC-Finer and coker units, respectively (Reference 100).
^Determined via ASTM D-97.
fSee General Comments section, Note 4, for summary of operating conditions used.
§See General Comments section, Note 3, for summary of operating conditions used.
629
-------
Table 278. Carbon Residue
Material
Coal raw
middle
di stillates
Process
SRC-1*
Coal Type
KY No. 9
distillate
(jet/diesel/
other light
fuel oil)
Value
(wt %)
O.Olt
KY No. 9 0.031"
KY No. 9
KY No. 9 O.OO1"
SRC- I I
EDS
H-Coal
Coal raw SRC- 1 1
middle
distil late
blends
(fuel oils)
Hydro- EDS
treated
middle
NA
NA
IL No. 6
NA
NA
NA
IL No. 6
(Monterey
Mine)
0.17*
0.03?
0.2f
0.08*
0.36f
0.51
O.Olf
IL No. 6 0.4f
Sample Description/Source Reference
Wilsonville pilot plant, 82
SRC unit (Run No. 220,
APCI Sample No. 1879CB)
Wilsonville pilot plant, 82
SRC unit (Run No. 225,
APCI Sample No. 1911CB)
Wilsonville pilot plant, 82
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1941CB-1)
Wilsonville pilot plant, 82
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1949CB)
Ft. Lewis pilot plant 84
Ft. Lewis pilot plant 102
Raw 350-650°F distillate 99
from one tpd pilot plant
450-650°F distillate 84
from PDU
5/1 medium/heavy distillate 84
blend from Ft. Lewis pilot
plant
Medium and heavy distillate 114
blend
Partially hydretreated 104
350-650°F distillate from
one tpd pilot plant
Partially hydrotreated 99
350-650°F distillate from
one tpd pilot plant
(Continued)
630
-------
Material
Hydro-
treated
middle
distillates
(jet/diesel/
other light
fuel oil)
process
EDS
Table 278 (Concluded)
Value
Coal Type (wt %) Sample Description/Source Reference
IL No. 6 0.05?
IL No. 6 0.04f
IL No. 6 O.Olf
From low severity hydro- 99
treatment of partially
hydrotreated 350-650°F
distillate from one tpd
pilot plant
From moderate severity 99
hydrotreatment of partially
hydrotreated 350-650°F
distillate from one tpd
pilot plant
From high severity hydro- 99
treatment of partially
hydrotreated 350-650°F
distillate from one tpd
pilot plant
NA
Hydro-
treated
middle
distillate
blends
(light
fuel oils)
Explanatory Notes
*The raw middle distillate from the proposed SRC-I demonstration plant will
consist of a 73.3/22.2/4.5 weight percent blend of middle distillates from
the SRC, LC-Finer and coker units, respectively (Reference 100).
"^Determined via ASTM D-189.
fConradson carbon residue.
63,1
-------
Table 279. Bottom Sediment and Water
Material
Coal raw
middle
distillates
Process
SRC-I*
Coal Type
KY No. 9
Coal raw
middle
distillate
blends
(light
fuel oil)
Hydro-
treated
middle
distillates
(jet/diesel/
other light
fuel oil)
SRC-11 NA
SRC-11 NA
Value
(ml)
<0.05t
KY No. 9 <0.05t
KY No. 9
KY No. 9 <0.05f
Pittsburgh
No. 8
(Powhattan
Mine)
0.10
(wt %)
0.04
0.04
NA
Sample Description/Source Reference
Wilsonville pilot plant, 82
SRC unit (Run No. 220,
APCI Sample No. 1897CB)
Wilsonville pilot plant, 82
SRC unit (Run No. 225,
APCI Sample No. 1911CB)
Wilsonville pilot plant, 82
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1941CB-1)
Wilsonville pilot plant, 82
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1949CB)
Ft. Lewis pilot plant 101
5.75/1 medium/heavy distil- 101
late blend from Ft. Lewis
pilot plant
2.9/1 medium/heavy distil- 101
late blend from Ft. Lewis
pilot plant
(Continued)
632
-------
Table 279 (Concluded)
M . . Value
aienal Process Coal Type (ml) Sample Description/Source Reference
Hydro- NA
treated
middle
distillate
blends
(light
fuel oils)
Explanatory Notes
*The raw middle distillate from the proposed SRC-I demonstration plant will
consist of a 73.3/22.2/4.5 weight percent blend of middle distillates from the
SRC, LC-Finer and coker units, respectively (Reference 100).
"•"Determined via ASTM D-1796.
633
-------
Table 280. Freeze Point
Material
Coal raw
middle
distillates
Process
Value
Coal Type (°F)
SRC-1* KY No. 9 -251"
KY No. 9 -501"
KY No. 9 <-76f
KY No. 9 <-76f
Coal raw
middle
distillate
blends
(light
fuel oils)
Hydro-
treated
middle
distillates
(jet/diesel/
other light
fuel oil)
H-Coal Wyodak -61
NA
SRC-11
Pitt-Seams -75
WV (Black-
vine No.
2 Mine)
EDS
Wyodak
-47.2
H-Coal
IL No. 6 -53
Sample Description/Source Reference
Wilsonville pilot plant,
SRC unit (Run No. 220,
APCI Sample No. 1897CB)
Wilsonville pilot plant,
SRC unit (Run No. 225,
APCI Sample No. 1911CB)
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1941CB-1)
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1949CB)
250-600°F distillate,
PDU, syncrude mode
82
82
82
82
95
Single-stage hydrotreated
<554°F distillatef
Raffinate from continuous
extraction (4:1 sulfolane:
feed) of 350-525°F hydro-
treated solvent from one
tpd pilot plant
Single-stage hydrotreated
<554°F distillate from PDU§
88
99
88
(Continued)
634
-------
Table 280 (Concluded)
Value
Material Process Coal Type (°F) Sample Description/Source Reference
Hydro- H-Coal Wyodak <-40 Single-stage hydrotreated 88
treated <554°F distillate from
middle PDU§
distillates
(jet/diesel/
other light
fuel oil )
Hydro- NA
treated
middle
distillate
blends
(light
fuel oils)
Explanatory Notes
*The raw middle distillate from the proposed SRC-I demonstration plant will
consist of a 73.3/22.2/4.5 weight percent blend of middle distillates from the
SRC, LC-Finer and coker units, respectively (Reference 100).
"^Determined via ASTM D-2386.
General Comments section, Note 6, for summary of operating conditions used.
§See General Comments section, Note 7, for summary of operating conditions used.
635
-------
Table 281. Flash Point
Value
Material
Coal raw
middle
distillates
Process Coal Type (°F)
SRC-1* KY No. 9 2061"
KY No. 9 215f
KY No. 9 2301"
EDS
KY No. 9 222f
SRC-11 NA
169
Pittsburgh 147
No. 8
(Powhattan
Mine)
NA
IL No. 6
>160
158
H-Coal IL No. 6 205
NA
NA
145.0
110
Sample Description/Source Reference
Wilsonville pilot plant, 82
SRC unit (Run No. 220,
APCI Sample No. 1897CB)
Wilsonville pilot plant,
SRC unit (Run No. 225,
APCI Sample No. 1911CB)
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1941CB-1)
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1949CB)
Ft. Lewis pilot plant
Ft.. Lewis pilot plant
Ft. Lewis pilot plant
Raw 350-650°F distillate
from one tpd pilot plant
380-650°F distillate
from PDU Run 5, Run
130-82, Period 29f
450-650°F distillate
from PDU
260-552°F distillate
derived from atmospheric
still overhead streams
82
82
82
84
101
102
99
111
84
108
(Continued)
636
-------
Table 281 (Continued)
Value
Material Process
Coal raw H-Coal
middle
di stil lates
Coal raw SRC- 1 1
middle
distillate
blends
(light
fuel oil)
Hydro- SRC- I I
treated
middle
distillates
(jet/diesel/
other light EDS
fuel oil)
Coal Type
IL No. 6
Wyodak
W. KY
No. 11
NA
Pittsburgh
No. 8
(Powhattan
Mine)
NA
NA
NA
Pitt -Seams
WV (Black-
vine No.
2 Mine)
IL No. 6
(Monterey
Mine)
(°F)
225
190
214
160
150
168
170
150
>100
120
IL No. 6 142
IL No. 6 134
Sample Description/Source Reference
PDU, syncrude mode 109
POD, syncrude mode 109
POU, syncrude mode 109
5.75/1 medium/heavy distil- 101
late blend from Ft. Lewis
pilot plant
2.9/1 medium/heavy distil- 101
late blend from Ft. Lewis
pilot plant
5/1 medium/heavy distillate 84
blend from Ft. Lewis pilot
plant
5/1 medium/heavy distillate 108
blend from Ft. Lewis pilot
plant
5.75/1 medium/heavy distil- 121
late blend
Single-stage hydrotreated 88
<554°F distillate§
Partially hydrotreated 104
350-650°F distillate from
one tpd pilot plant
Partially hydrotreated 99
350-650°F distillate from
one tpd pilot plant
From low severity hydro- 99
treatment of partially
hydrotreated 350-650°F
distillate from one tpd
pilot plant
(Continued)
637
-------
Table 281 (Concluded)
Value
Material
Hydro-
treated
middle
distillates
(jet/diesel/
other light
fuel oil)
Process Coal Type
EDS
IL No. 6 134
IL No. 6 116
Wyodak
150
H-Coal
IL No. 6
(Burning
Star
Mine)
Wyodak
108
>100
Sample Description/Source Reference
From moderate severity 99
hydrotreatment of partially
hydrotreated 350-650°F
distillate from one tpd
pilot plant
From high severity hydro- 99
treatment of partially
hydrotreated 350-650°F
distillate from one tpd
pilot plant
Raffinate from continuous 99
extraction (4:1 sulfolane
feed) of 350-525°F hydro-
treated solvent from one
tpd pilot plant
Single-stage hydrotreated 88
<554°F distillate from PDU#
Single-stage hydrotreated 88
<554°F distillate from PDU#
NA
Hyd ro-
treated
middle
distillate
blends
(light
fuel oils)
Explanatory Notes
*The raw middle distillate from the proposed SRC-I demonstration plant will
consist of a 73.3/22.2/4.5 weight percent blend of middle distillates from
the SRC, LC-Finer and coker units, respectively (Reference 100).
"''Determined via ASTM D-96.
fSee General Comments section, Note 4, for summary of operating conditions used.
§See General Comments section, Note 6, for summary of operating conditions used,
#See General Comments section, Note 7, for summary of operating conditions used.
638
-------
Table 282. Smoke Point
Value
Material Process Coal Type (mm)
Coal raw SRC-I* KY No. 9 61"
middle
distillates
KY No. 9 81"
KY No. 9
KY No. 9
Coal raw
middle
distillate
blends
(light
fuel oi 1 s)
Hydro- SRC-II
treated
distillates
(jet/diesel/
other light
fuel oil) EDS
H-Coal IL No. 6
NA
Pitt-Seams
WV (Black-
ville No.
2 Mine)
IL No. 6
IL No. 6
22
Sample Description/Source Reference
Wilsonville pilot plant,
SRC unit (Run No. 220,
APCI Sample No. 1897CB)
Wilsonville pilot plant,
SRC unit (Run No. 225,
APCI Sample No. 1911CB)
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1941CB-1)
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1949CB)
380-650°F distillate
from PDU Run 5, Run 130-82,
Period 29f
82
82
82
82
111
Single-stage hydrotreated
<554°F distillate§
88
7.8 Partially hydrotreated
350-650°F distillate from
one tpd pilot plant
7.8 From low severity hydro-
treatment of partially
hydrotreated 350-650°F
distillate from one tpd
pilot plant
(Continued)
639
99
99
-------
Table 282 (Concluded)
Material
Hyd ro-
treated
middle
distillates
(jet/diesel/
other light
fuel oil)
Process
EDS
Coal Type
IL No. 6
Value
(mm)
6.9
IL No. 6
Wyodak
H-Coal
IL No. 6
(Burning
Star
Mine)
Wyodak
Sample Description/Source Reference
From moderate severity 99
hydrotreatment of partially
hydrotreated 350-650°F
distillate from one tpd
pilot plant
17.2 From high severity hydro- 99
treatment of partially
hydrotreated 350-650°F
distillate from one tpd
pilot plant
15 Raffinate from continuous 99
extraction (4:1 sulfolane:
feed) of 350-525°F hydro-
treated solvent from one tpd
pilot plant
23 Single-stage hydrotreated 88
<554°F distillate from
PDU#
21 Single-stage hydrotreated 88
<554°F distillate from
PDU#
NA
Hydro-
treated
middle
distillate
blends
(light
fuel oils)
Explanatory Notes
*The raw middle distillate from the proposed SRC-I demonstration plant will
consist of a 73.3/22.2/4.5 weight percent blend of middle distillates from
the SRC, LC-Finer and coker units, respectively (Reference 100).
^Determined via ASTM D-1322.
fSee General Comments section, Note 4, for summary of operating conditions used.
§See General Comments section, Note 6, for summary of operating conditions used,
#See General Comments section, Note 7, for summary of operating conditions used,
640
-------
Table 283. Heat of Combustiorr
Value
Material Process Coal Type (BTU/lb) Sample Description/Source Reference
Coal raw
middle
distillates
SRC-I* KY No. 9 17,415f
KY No. 9 17,285"!"
KY No. 9 18,458"!"
KY No. 9 18,384+
SRC-11 NA
17,102
(gross)
Pittsburgh 17,000
No. 8 (HHV)
(Powhattan 16,190
Mine) (LHV)
NA
NA
NA
17,235
(net)
17,260
16,391
Wilsonville pilot plant,
SRC unit (Run No. 220,
APCI Sample No. 1897CB)
Wilsonville pilot plant,
SRC unit (Run No. 225,
APCI Sample No. 1911CB)
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1941CB-1)
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1949CB)
Ft. Lewis pilot plant
Ft. Lewis pilot plant
Ft. Lewis pilot plant
Ft. Lewis pilot plant
Ft. Lewis pilot plant
82
82
82
82
84
101
102
126
122
H-Coal IL No. 6 17,706
Wyodak
18,523
380-650°F distillate
from PDU Run 5, Run
130-82, Period 29*
380-650°F distillate
from PDU Run 6, Run
130-83, Period 17§
(Continued)
111
112
641
-------
Table 283 (Continued)
Material
Coal raw
middle
distillates
Process
H-Coal
Value
Coal Type (BTU/lb)
NA 18,331
(gross)
NA 17,670
(net)
18,700
(gross)
18,068
18,616
17,937
IL No. 6
Wyodak
W. KY
No. 11
Coal raw
middle
distillate
blends
(light
fuel oils)
SRC-II NA
17,330
(HHV)
16,490
(LHV)
Sample Description/Source Reference
450-650°F distillate 84
from POU (EPRI Sample
No. 3)
260-552°F distillate 108
derived from atmospheric
still overhead streams
(analyzed by Truesdail)
POU, syncrude mode 109
PDU, syncrude mode 109
PDU, syncrude mode 109
5.75/1 medium/heavy 101
distillate blend from
Ft. Lewis pilot plant
Pittsburgh 17,110
No. 8 (HHV)
(Powhattan 16,340
Mine) (LHV)
NA 17,090
NA 16,470
(net)
17,300
(gross)*
17,605
(gross)**
NA 17,081
NA 17,590
NA 17,140
2.9/1 medium/heavy 101
distillate blend from
Ft. Lewis pilot plant
5/1 medium/heavy 84
distillate blend from
Ft. Lewis pilot plant
5/1 medium/heavy 108
distillate blend from
Ft. Lewis pilot plant
(analyzed by Truesdail
and Gulf)
5.75/1 medium/heavy 121
distillate blend
3/1 medium/heavy 126
distillate blend, from
Ft. Lewis pilot plant
2/1 medium/heavy 126
distillate blend, from
Ft. Lewis pilot plant
(Continued)
642
-------
Table 283 (Concluded)
Material
Coal raw
middle
distillate
blends
(light
fuel oils)
Hydro-
treated
middle
distillates
(jet/diesel/
other light
fuel oil)
Process Coal Type
SRC-II NA
Value
(BTU/lb)
17,130
EDS
IL No. 6
Wyodak
20,500
(HHV)
18,000
(net)
Sample Description/Source Reference
1/2 medium/heavy distil- 126
late from Ft. Lewis
pilot plant
Partially hydrotreated 104
350-650°F distillate
from one tpd pilot
plant
Raffinate from continuous 99
extraction (4:1 sulfolane:
feed) of 350-525°F boiling
range hydrotreated solvent
from one tpd pilot plant)
NA
Hydro-
treated
middle
distillate
blends
(light
fuel oils)
Explanatory Notes
*The raw middle distillate from the proposed SRC-I demonstration plant will
consist of a 73.3/22.2/4.5 weight percent blend of middle distillates from
the SRC, LC-Finer and coker units, respectively (Reference 100).
'''Determined via ASTM D-240.
fSee General Comments section, Note 4, for summary of operating conditions used.
§See General Comments section, Note 5, for summary of operating conditions used.
^Analyzed by Truesdail Laboratories.
**Analyzed by Gulf Oil.
643
-------
Table 284. Aniline Point
Value
Material Process Coal Type (°F)
Coal raw SRC-I* KY No. 9 25f
middle
distillates
KY No. 9 <-50f
KY No, 9 <-50f
KY No. 9 <-50t
Coal raw
middle
distillate
blends
(light
fuel oil)
EDS
NA
IL No. 6 -5.5
EDS
Hyd ro-
treated
middle
distillates
(jet/diesel/
other light SRC-11
fuel oil)
IL No. 6 <-36
IL No. 6 -25
IL No. 6 -13.5
Sample Description/Source Reference
Wilsonville pilot plant,
SRC unit (Run No. 220,
APCI Sample No. 1897CB)
Wilsonville pilot plant,
SRC unit (Run No. 225,
APCI Sample No. 1911CB)
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1941CB-1)
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1949CB)
Raw 350-650°F distillate
from one tpd pilot plant
Partially hydretreated
350-650°F distillate'
from one tpd pilot plant
From low severity hydro-
treatment of partially
hydrotreated 350-650°F
distillate from one tpd
pilot plant
From moderate severity
hydrotreatment of
partially hydrotreated
350-650°F distillate
from one tpd pilot plant
(Continued)
644
82
82
82
82
99
99
99
99
-------
Table 284 (Concluded)
Process
Value
Coal Type (°F)
Sample Description/Source Reference
From high severity hydro-
treatment of partially
hydrotreated 350-650°F
distillate from one tpd
pilot plant
Material
Hydro- EDS IL No. 6 +102.5 From high severity hydro- 99
treated
middle
distillates
(jet/diesel/
other light
fuel oil)
Hydro- NA
treated
middle
distillate
blends
(light
fuel oils)
Explanatory Notes
*The raw middle distillate from the proposed SRC-I demonstration plant will
consist of a 73.3/22.2/4.5 weight percent blend of middle distillates from
the SRC, LC-Finer anpl coker units, respectively (Reference 100).
Determined via ASTM D-611.
645
-------
Material
Coal raw
middle
distillates
Process
EDS
Coal raw
middle
distillate
blends
(light
fuel oils)
Hydro-
treated
middle
distillates
(jet/diesel/
other light
fuel oil)
EDS
Table 285. Bromine Number
Coal Type Value Sample Description/Source Reference_
SRC-I* KY No. 9 33. 01"
IL No. 6
H-Coal IL No. 6
NA
Wyodak
IL No. 6
IL No. 6
IL No. 6
IL No. 6
16.1
50.4
21.6
9.8
2.0
1.7
0.44
Wilsonville pilot plant,
SRC unit (Run No. 220,
APCI Sample No. 1897CB)
Raw 350-650°F distillate
from one tpd pilot plant
380-650°F distillate from
PDU Run 5. Run 130-82,
Period 29t
380-650°F distillate from
PDU Run 6. Run 130-83,
Period 17§
Partially hydrotreated
350-650°F distillate
from one tpd pilot plant
From low severity hydro-
treatment of partially
hydrotreated 350-650°F
distillate from one
tpd pilot plant
From moderate severity
hydrotreatment of
partially hydrotreated
350-650°F distillate
from one tpd pilot
plant
From high severity
hydrotreatment of
partially hydrotreated
350-650°F distillate
from one tpd pilot
plant
82
99
111
112
99
99
99
99
(Continued)
646
-------
Table 285 (Concluded)
Material Process Coal Type Value Sample Description/Source Reference
Hydro- NA
treated
middle
distillate
blends
(light
fuel oils)
Explanatory Notes
*The raw middle distillate from the proposed SRC-I demonstration plant will
consist of a 73.3/22.2/4.5 weight percent blend of middle distillates from
the SRC, LC-Finer and coker units, respectively (Reference 100).
"'"Determined via ASTM D-1159.
fSee General Comments section, Note 4, for summary of operating conditions used.
§See General Comments section, Note 5, for summary of operating conditions used.
647
-------
Table 286.
Material Process Coal Type
Coal raw SRC-I* KY No. 9
middle
distillates
KY No. 9
KY No. 9
Copper Strip Corrosion
Value Sample Description/Source Reference
KY No. 9
lat
EDS
NA
IL No. 6
la
Coal raw
middle
distillate
blends
(light
fuel oils)
Hydro- SRC-II
treated
middle
distillates
(jet/diesel/
other light EDS
fuel oil)
Pitt-Seams
WV (Black-
vine No.
2 Mine)
IL No. 6
Ib
IL No. 6
2c
Wilsonville pilot plant,
SRC unit (Run No. 220,
APCI Sample No. 1897C8)
Wilsonville pilot plant,
SRC unit (Run No. 225,
APCI Sample No. 1911CB)
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1941CB-1)
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1949CB)
Raw 350-650°F distillate
from one tpd pilot plant
82
82
82
82
99
Single-stage hydrotreated
<554°F distillate?
Partially hydrotreated
350-650°F distillate
from one tpd pilot
plant
From low severity hydro-
treatment of partially
hydrotreated 350-650°F
distillate from one tpd
pilot plant
99
99
(Continued)
648
-------
Material
Hydro-
treated
middle
distillates
(jet/diesel/
other light
fuel oil)
Table 286 (Concluded)
Process Coal Type Value Sample Description/Source Reference
EDS
IL No. 6 2c
IL No. 6 3b
Wyodak
1.2
(2 hr at
212°F)
H-Coal
IL No. 6
(Burning
Star
Mine)
Wyodak
From moderate severity 99
hydrotreatment of
partially hydrotreated
350-650°F distillate
from one tpd pilot
plant
From high severity 99
hydrotreatment of
partially hydrotreated
350-650°F distillate
from one tpd pilot
plant
Raffinate from continu- 99
ous extraction (4:1
sulfolane: feed) of
350-525°F hydrotreated
solvent from one tpd
pilot plant
Single-stage hydrotreated 88
<554°F distillate from PDU§
Single-stage hydrotreated
<554°F distillate from PDU§
NA
Hydro-
treated
middle
distillate
blends
(light
fuel oils)
Explanatory Notes
*The raw middle distillate from the proposed SRC-I demonstration plant will
consist of a 73.3/22.2/4.5 weight percent blend of middle distillates from
the SRC, LC-Finer and coker units, respectively (Reference 100).
^Determined via ASTM D-130.
fSee General Comments section, Note 6, for summary of operating conditions used.
§See General Comments section, Note 7, for summary of operating conditions used.
649
-------
Table 287. Moisture Content
Material Process Coal Type Value Sample Description/Source
*
Coal raw SRC- 1* KY No. 9 0.041" Wilsonville pilot plant,
middle SRC unit (Run No. 220,
distillates APC I Sample No. 1897CB)
KY No. 9 0.051" Wilsonville pilot plant, 82
SRC unit (Run No. 225,
APCI Sample No. 1911C8)
KY No. 9 0.031" Wilsonville pilot plant, 82
Lummus LC- Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1941CB-1)
KY No. 9 O'.OS1" Wilsonville pilot plant, 82
Lummus LC- Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1949CB)
Coal raw NA
middle
distillate
blends
(light
fuel oils)
Hydro- NA
treated
middle
distillates
(jet/diesel/
other light
fuel oil)
Hydro- NA
treated
middle
distillate
bl ends
(light
fuel oils)
Explanatory Notes
*The raw middle distillate from the proposed SRC- I demonstration plant will
consist of a 73.3/22.2/4.5 weight percent blend of middle distillates from
the SRC, LC-Finer and coker units, respectively (Reference 100).
"^Determined via ASTM D-1744 (Karl Fischer reagent method).
650
-------
Material
Coal raw
middle
distillates
Table 288. Color
Process Coal Type Value"1' Sample Description/Source Reference
SRC-I* KY No. 9
KY No. 9
KY No. 9
KY No. 9
EDS
H-Coal
IL No. 6
IL No. 6
(Burning
Star
Mine)
IL No. 6
(Monterey
Mine)
Coal raw
middle
distillate
blends
(light
fuel oils)
NA
(medium
brown)
(extremely
dark
brown)
4.5
(medi urn
to dark
amber)
2.25
(dark
yellow to
light
amber)
>8 (very
dark
brown)
Brownish
black
Brownish
black
Wilsonville pilot plant,
SRC unit (Run No. 220,
APCI Sample No. 1897CB)
Wilsonville pilot plant,
SRC unit (Run No. 225,
APCI Sample No. 1911CB)
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1941CB-1)
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1949CB)
Raw 350-650°F
late from one
pilot plant
distil-
tpd
Derived from PDU atmos-
pheric still overhead
and vacuum still overhead
streams, fuel oil mode
(analyzed by BETC)f
Derived from PDU atmos-
pheric still overhead
and vacuum still over-
head streams, syncrude
mode (analyzed by
BETC)f
82
82
82
82
99
97
97
(Continued)
651
-------
Table 288 (Concluded)
Material Process Coal Type Value* Sample Description/Source Reference
Hydro-
treated
distillates
(jet/diesel/
other light
fuel oils)
EDS
IL No. 6 >8 Partially hydrotreated
(very 350-650° distillate from
dark one tpd pilot plant
brown)
IL No. 6 3 From low severity
(light hydrotreatment of
amber) partially hydrotreated
350-650°F distillate
from one tpd pilot
plant
IL No. 6 2 From moderate severity
(dark hydrotreatment of
yellow) partially hydrotreated
350-650°F distillate
from one tpd pilot
plant
IL No. 6 1 From high severity
(pale hydrotreatment of
yellow) partially hydrotreated
350-650°F distillate
from one tpd pilot
plant
99
NA
99
99
99
Hydro-
treated
middle
distillate
blends
(light
fuel oils)
Explanatory Notes
*The raw middle distillate from the proposed SRC-I demonstration plant will
consist of a 73.3/22.2/4.5 weight percent blend of middle distillates from
the SRC, LC-Finer and coker units, respectively (Reference 100).
"•"Determined via ASTM D-1500.
fSee General Comments section, Note 3, for summary of operating conditions
used.
652
-------
Table 289. Oxygen Content
Material Process Coal Type
Coal raw SRC-I* KY No. 9
middle
distillates
KY No. 9
KY No. 9
KY No. 9
Value
(wt %)
3.39
2.97
0.23
0.1
Sample Description/Source Reference
SRC-II NA
4.65
Wilsonville pilot plant,
SRC unit (Run No. 220,
APCI Sample No. 1897CB)
Wilsonville pilot plant,
SRC unit (Run No. 225,
APCI Sample No. 1911CB)
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lumrnus Run No. 2-LC
Finer-29, APCI Sample
No. 1941CB-1)
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1949CB)
Ft. Lewis pilot plant
82
82
82
82
84
H-Coal
Pittsburg
No. 8
(Powhattan
Mine)
NA
NA
IL No. 6
5.43"1" Ft. Lewis pilot plant
101
Wyodak
NA
3.89
3.8t
1.03
1.24
1.2
(Continued)
Ft. Lewis pilot plant
Ft. Lewis pilot plant
380-650°F distillate
from PDU Run 5, Run
130-82, Period 29?
30-65QOF distillate
from PDU Run 6, Run
130-83, Period 17§
>450-650°F distillate
from PDU
102
126
111
112
84
653
-------
Table 289 (Continued)
Material Process
Coal raw H-Coal
middle
distillates
Coal raw SRC- 1 1
middle
distillate
blends
(light
fuel oil)
Coal Type
IL No. 6
NA
IL No. 6
Wyodak
W. KY
No. 11
NA
Pittsburg
No. 8
(Powhattan
Mine)
NA
NA
Value
(Wt %)
0.94
2.08
1.64
1.0
0.7
1.6
4.021"
4. 18*
4.35
3.74*
4.35*
4.18f
Sample Description/Source
450-650°F distillate from
PDU, syn crude mode
260-552°F distillate
derived from atmos-
pheric still overhead
streams (analyzed by
Truesdail and Graphic
Science for EPRI)
PDU, syn crude mode
PDU, syn crude mode
POU, syn crude mode
5.75/1 medium/heavy
distillate blend from
Ft. Lewis pilot plant
2.9/1 medium/heavy
distillate blend from
Ft. Lewis pilot plant
5/1 medium/heavy
distillate blend from
Ft. Lewis pilot plant
5/1 medium/heavy
distillate blend from
Ft. Lewis pilot plant
(analyzed by Truesdail,
Mobil for EPRI, and Gulf)
Reference
98
108
109
109
109
101
101
84
108
NA
2.02 2.9/1 medium/heavy
distillate blend, UOP
Sample No. 3777-6
(Continued)
113
654
-------
Table 289 (Continued)
Material
Coal raw
middle
distillate
blends
(light
fuel oil)
Process
SRC-11
Hydro-
treated
middle
distillates
(jet/diesel/
other light
fuel oil)
EDS
Coal Type
NA
NA
NA
NA
IL No. 6
IL No. 6
IL No. 6
IL No. 6
Value
(wt %}
1.73
4.38
3.8t
2.It
1.1700
0.1300
0.1700
NA
Sample Description/Source Reference
2.9/1 medium/heavy 113
distillate blend, UOP
Sample No. 3777-7
5.75/1 medium/heavy 121
distillate blend
3/1 medium/heavy 126
distillate blend, from
Ft. Lewis pilot plant
2/1 medium/heavy 126
distillate blend, from
Ft. Lewis pilot plant
Partially hydrotreated 99
350-650°F distillate
from one tpd pilot plant
From low severity hydro- 99
treatment of partially
hydrotreated 350-650°F
distillate from one tpd
pilot plant
From moderate severity 99
hydrotreatment of
partially hydrotreated
350-650°F distillate
from one tpd pilot plant
From high severity, hydro- 99
treatment of partially
hydrotreated 350-650°F
distillate from one tpd
pilot plant
(Continued)
655
-------
Table 289 (Concluded)
Material
Hydro-
treated
middle
distillate
blends
(light
fuel oils)
Process Coal Type
SRC-11 NA
Value
(wt %)
1.08
NA
0.98
NA
0.67
NA
0.83
Explanatory Notes:
Sample Description/Source Reference
Moderately hydrotreated 113
2.9/1 medium/heavy
distillate blend, whole
liquid product, UOP
Sample No. 3777-21
Moderately hydrotreated 113
2.9/1 medium/heavy
distillate blend, 400°F+
liquid product, UOP
Sample No. 3777-34
Severely hydrotreated 113
2.9/1 medium/heavy
distillate blend, whole
liquid product, UOP
Sample No. 3777-28
Severely hydrotreated 113
2.9/1 medium/heavy
distillate blend, 400°F+
liquid product, UOP
Sample No. 3777-41
*The raw middle distillate from the proposed SRC-I demonstration
plant will consist of a 73.3/22.2/4.5 weight percent blend of
middle distillates from the SRC, LC-Finer and coker units,
respectively (Reference 100).
+By difference.
fSee General Comments section, Note 4, for summary of operating
conditions used.
§See General Comments section, Note 5, for summary of operating
conditions used.
656
-------
Table 290. Sulfur Content
Value
Material Process Coal Type (wt %} Sample Description/Source Reference
Coal raw SRC-I* KY No. 9 0.38
middle
distillates
KY No. 9 0.45
KY No. 9 0.082
EDS
H-Coal
KY No. 9
SRC-11 NA
Pittsburg
No. 8
(Powhattan
Mine)
NA
NA
NA
IL No. 6
IL No. 6
(Burning
Star Mine)
IL No. 6
(Burning
Star Mine)
0.03
0.21
0.20
Wilsonville pilot plant,
SRC unit (Run No. 220,
APCI Sample No. 1897CB)
Wilsonville pilot plant,
SRC unit (Run No. 225,
APCI Sample No. 1911CB) -
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer -29, APCI Sample
No. 1941CB-1)
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1949CB)
Ft. Lewis pilot plant
Ft. Lewis pilot plant
0.19 Ft. Lewis pilot plant
0.20 Ft. Lewis pilot plant
0.3 Ft. Lewis pilot plant
0.7870 Raw 350-650°F distillate
from one tpd pilot plant
0.29 Derived from PDU atmos-
pheric still overhead
and vacuum still over-
head streams, syncrude
mode (analyzed by BETC)1"
0.371 PDU (Ashland Oil sample)
(Continued)
657
82
82
82
82
84
101
102
122
126
99
97
96
-------
Table 290 (Continued)
Material
Coal raw
middle
distillates
Process Coal Type
H-Coal IL No. 6
(Monterey
Mine)
Wyodak
NA
IL No. 6
IL No. 6
(Burning
Star Mine)
NA
IL No. 6
Wyodak
Value
(wt %)
0.35
<0.03
0.09
0.18
0.094
0.14
0.1
0.02
Sample Description/Source Reference
Derived from PDU atmos- 97
pheric still overhead
and vacuum still overhead
streams, syncrude mode
(analyzed by BETC)t
380-650°F distillate from
PDU Run 6, Run 130-83,
Period 17f
>450-650°F distillate from
PDU
450-650°F distillate from
PDU, syncrude mode
0.0371 PDU (Ashland Oil sample)
W.KY No. 11 0.1
260-552°F distillate
derived from atmos-
pheric still overhead
streams (analyzed by
Truesdail and Graphic
Science for EPRI)
PDU, syncrude mode
PDU, syncrude mode
PDU, syncrude mode
112
84
98
96
108
109
109
109
Coal raw
middle
distillate
blends
(light
fuel oi1)
SRC- I I NA
0.26
Pittsburg 0.26
No. 8
(Powhattan
Mine)
NA
5.75/1 medium/heavy
distillate blend from
Ft» Lewis pilot plant
2.9/1 medium/heavy
distillate blend from
Ft. Lewis pilot plant
0.23
(Continued)
658
5/1 medium/heavy
distillate blend from
Ft. Lewis pilot plant
101
101
84
-------
Table 290 (Continued)
Material
Coal raw
middle
distillate
blends
(light
fuel oil)
Hydro-
treated
middle
distillates
(jet/
diesel/
other
light
fuel oil)
Process
SRC- 1 1
Coal Type
NA
EDS
NA
NA
NA
NA
NA
NA
IL No. 6
(Monterey
Mine)
IL No. 6
Value
(wt %)
0.22
0.23
0.19
0.3300
0.3815
0.30
0.22
0.2
0.4
0.004
0.0270
Sample Description/Source Reference
5/1 medium/heavy 108
distillate blend from
Ft. Lewis pilot plant
(analyzed by Truesdail ,
Mobil for EPRI, and Gulf)
2.9/1 medium/heavy 113
distillate blend, UOP
Sample No. 3777-6
2.9/1 medium/heavy 113
distillate blend, UOP
Sample No. 3777-7
Medium and heavy 114
distillate blend
5.75/1 medium/heavy 121
distillate blend
3/1 medium/heavy 126
distillate blend, from
Ft. Lewis pilot plant
2/1 medium/heavy 126
distillate blend, from
Ft. Lewis pilot plant
Partially hydrotreated 104
350-650°F distillate
from one tpd pilot
plant
Partially hydrotreated 99
350-650°F distillate
from one tpd pilot
plant
(Continued)
659
-------
Table 290 (Continued)
Material
Hydro-
treated
middle
distillates
(jet/
diesel/
other
light
fuel oil)
Process Coal Type
EDS IL No. 6
Value
(wt %)
0.0015
IL No. 6
ND
IL No. 6
NO
Hydro-
treated
middle
distillate
blends
(light
fuel oils)
SRC-11 NA
0.0129
NA
0.0106
NA
0.0098
Sample Description/Source Reference
From low severity hydro- 99
treatment of partially
hydrotreated 350-650°F
distillate from one tpd
pilot plant
From moderate severity 99
hydrotreatment of partially
hydrotreated 350-650°F
distillate from one tpd
pilot plant
From high severity hydro- 99
treatment of partially
hydrotreated 350-650°F
distillate from one tpd
pilot plant
Moderately hydrotreated 113
2.9/1 medium/heavy
distillate blend, whole
liquid product, UOP
Sample No. 3777-21
Moderately hydrotreated 113
2.9/1 medium/heavy
distillate blend, 400°F+
liquid product, UOP
Sample No. 3777-34
Severely hydrotreated 113
2.9/1 medium/heavy
distillate blend, whole
liquid product, UOP
Sample No. 3777-28
(Continued)
660
-------
Table 290 (Concluded)
Process Coal Type
SRC-11 NA
Value
(wt %)
0.0109
Sample Description/Source Reference
Severely hydrotreated
2.9/1 medium/heavy
distillate blend, 400°F
liquid product, UOP
Sample No. 3777-41
Material
Hydro- SRC-II NA 0.0109 Severely hydrotreated 113
treated
middle
distillate
blends
(light
fuel oils)
Explanatory Notes:
*The raw middle distillate from the proposed SRC-I demonstration plant
will consist of a 73.3/22.2/4.5 weight percent blend of middle distillates
from the SRC, LC-Finer and coker units, respectively (Reference 100).
"''See General Comments section, Note 3, for summary of operating condi-
tions used.
tSee General Comments section, Note 5, for summary of operating
conditions used.
661
-------
Table 291. Nitrogen Content
Material
Coal raw
middle
distillates
Process Coal Type
SRC-I1
EDS
H-Coal
KY No. 9
KY No. 9
KY No. 9
KY No. 9
SRC-11 NA
Pittsburg
No. 8
(Powhattan
Mine)
NA
NA
NA
IL No. 6
IL No. 6
(Burning
Star Mine)
IL No. 6
(Burning
Star Mine)
Value
(wt %)
0.75
0.93
0.18
0.22
0.91
0.85
Sample Description/Source Reference
Wilsonville pilot plant 82
SRC unit (Run No. 220,
APCI Sample No. 1897CB)
Wilsonville pilot plant 82
SRC unit (Run No. 225, APCI
Sample No. 1911CB)
Wilsonville pilot plant 82
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1941CB-1)
Wilsonville pilot plant 82
Lummus LC-Finer unit
(Lummus Run No. 2LC
Finer-27, APCI Sample
No. 1949CB)
Ft. Lewis pilot plant 84
Ft. Lewis pilot plant 101
0.95 Ft. Lewis pilot plant 102
0.87 Ft. Lewis pilot plant 122
0.9 Ft. Lewis pilot plant 126
0.6700 Raw 350-650°F 99
distillate from one
tpd pilot plant
0.446 Derived from PDU atmos- 97
pheric still overhead
and vacuum still over-
head streams, syncrude
mode (analyzed by BETC)1"
0.1800 PDU (Ashland Oil sample) 96
(Continued)
662
-------
Table 291 (Continued)
Material
Coal raw
middle
distillates
Process Coal Type
H-Coal IL No. 6
(Monterey
Mine)
IL No. 6
Wyodak
NA
IL No. 6
IL No. 6
(Burning
Star Mine)
NA
IL No. 6
Wyodak
Value
(wt %)
0.871
0.52
0.23
0.33
0.42
0.1800
0.31
0.26
0.4
0.3
W.KY No. 11 0.5
Coal raw
middle
distillate
blends
(light
fuel oil)
SRC- I I NA
Pittsburg
No. 8
(Powhattan
Mine)
NA
0.84
0.92
0.91
(Continued)
663
Sample Description/Source Reference
Derived from PDU atmos- 97
pheric still overhead
and vacuum still over-
head streams, syncrude
mode (analyzed by BETC)1"
380-650°F distillate from
PDU Run 5. Run 130-82,
Period 29f
380-650°F distillate from
PDU Run 6. Run 130-83,
Period 17§
>450-650°F distillate
from PDU
450-650°F distillate
from PDU, syncrude mode
PDU (Ashland Oil sample)
111
112
84
98
96
108
260-552°F distillate
derived from atmos-
pheric still overhead
streams (analyzed by
Truesdail and Graphic
Science for EPRI)
PDU, syncrude mode 109
PDU, syncrude mode 109
PDU, syncrude mode 109
5.75/1 medium/heavy 101
distillate blend from
Ft. Lewis pilot plant
2.9/1 medium/heavy 101
distillate blend from
Ft. Lewis pilot plant
5/1 medium/heavy 84
distillate blend from
Ft. Lewis pilot plant
-------
Material
Coal raw
middle
distillate
blends
(light
fuel oil)
Process
Table 291 (Continued)
Value
Coal Type (wt %) Sample Description/Source Reference
SRC-11 NA
Hydro-
treated
middle
distillates
(jet/
diesel/
other
light
fuel oil)
EDS
NA
NA
NA
NA
NA
NA
IL No. 6
(Monterey
Mine)
IL No. 6
IL No. 6
0.86 5/1 medium/heavy 108
0.91 distillate blend from
0.93 Ft. Lewis pilot plant
(analyzed by Truesdail ,
Mobil for EPRI, and Gulf)
0.8100 2.9/1 medium/heavy 113
distillate blend, UOP
Sample No. 3777-6
0.9040 2.9/1 medium/heavy 113
distillate blend, UOP
Sample No. 3777-7
0.97 Medium and heavy 114
distillate blend
1.02 5.75/1 medium/heavy 121
distillate blend
0.9 3/1 medium/heavy 126
distillate blend, from
Ft. Lewis pilot plant
0.9 2/1 medium/heavy 126
distillate blend, from
Ft. Lewis pilot plant
<0.001 Partially hydrotreated 104
350-650°F distillate
from one tpd pilot
plant
0.170 Partially hydrotreated 99
350-650°F distillate
from one tpd pilot
plant
0.0185 From low severity hydro- 99
treatment of partially
hydrotreated 350-650°F
distillate from one tpd
pilot plant
(Continued)
664
-------
Table 291 (Concluded)
Material
Hydro-
treated
middle
distillates
(jet/
diesel/
other
light
fuel oil)
Hydro-
treated
middle
distillate
blends
(light
fuel oils)
Process Coal Type
EDS
IL No. 6
IL No. 6
SRC-II NA
NA
NA
NA
Explanatory Notes:
Value
(wt %)
0.130
<0.0100
0.5510
0.6000
0.1900
0.1730
Sample Description/Source Reference
From moderate severity
hydrotreatment of
partially hydrotreated
350-650°F distillate
from one tpd pilot plant
From high severity hydro-
treatment of partially
hydrotreated 350-650°F
distillate from one tpd
pilot plant
Moderately hydrotreated
2.9/1 medium/heavy
distillate blend, whole
liquid product, UOP
Sample No. 3777-21
Moderately hydrotreated
2.9/1 medium/heavy
distillate blend, 400°F+
liquid product, UOP
Sample No. 3777-34
Severely hydrotreated
2.9/1 medium/heavy
distillate blend, whole
liquid product, UOP
Sample No. 3777-28
Severely hydrotreated
2.9/1 medium/heavy
distillate blend, 400°F
liquid product, UOP
Sample No. 3777-41
99
99
113
113
113
113
*The raw middle distillate from the proposed SRC-I demonstration plant will
consist of a 73.3/22.2/4.5 weight percent blend of middle distillates
from the SRC, LC-Finer and coker units, respectively (Reference 100).
"''See General Comments section, Note 3, for summary of operating conditions used.
fSee General Comments section, Note 4, for summary of operating conditions used.
§See General Comments section, Note 5, for summary of operating conditions used.
665
-------
Table 292. Carbon Content
Material
Coal raw
middle
distillates
Process Coal Type
SRC-I* KY No. 9
KY No. 9
KY No. 9
SRC-II
H-Coal
KY No. 9
Wyodak
IL No. 6
Value
(wt %)
86.56
87.79
89.62
89.98
NA
Pittsburg
No. 8
(Powhattan
Mine)
NA
IL No. 6
85.9
84.59
85.77
87.54
!.63
88.3
Sample Description/Source Reference
Wilsonville pilot plant,
SRC unit (Run No. 220,
APCI Sample No. 1897CB)
Wilsonville pilot plant
SRC unit (Run No. 225,
APCI Sample No. 1911CB)
Wilsonville pilot plant,
lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1941CB-1)
Wilsonville pilot plant
Lummus LC-Finer unit
(Lummus Run No. 2LC
Finer-27, APCI Sample
No. 1949CB)
Ft. Lewis pilot plant
Ft. Lewis pilot plant
Ft. Lewis pilot plant
380-650°F distillate
from PDU Run 5, Run
130-82, Period 291"
380-650°F distillate
from PDU Run 6, Run
130-83, Period 17f
450-650°F distillate
from PDU, syncrude
mode
82
82
82
82
126
101
102
111
112
98
(Continued)
666
-------
Table 292 (Continued)
Material
Coal raw
middle
distillates
Process Coal Type
H-Coal
Coal raw
middle
distillate
blends
(light
fuel oil)
NA
Value
(wt %)
86.20
86.53
IL No. 6
Wyodak
88.8
86.6
W.KY No. 11 88.5
SRC-11 NA
Pittsburg
No. 8
(Powhattan
Mine)
NA
NA
NA
NA
NA
NA
NA
85.64
86.15
86.09
84.69
85.93
85.83
86.13
85.91
85.50
86.2
87.5
Sample Description/Source Reference
260-552°F distillate 108
derived from atmospheric
still overhead streams
(analyzed by Truesdail
and Graphic Science for
EPRI)
PDU, syncrude mode 109
PDU, syncrude mode 109
PDU, syncrude mode 109
5.75/1 medium/heavy 101
distillate blend from
Ft. Lewis pilot plant
2.9/1 medium/heavy 101
distillate blend from
Ft. Lewis pilot plant
5/1 medium/heavy 108
distillate blend from
Ft. Lewis pilot plant
(analyzed by Truesdail,
Mobil for EPRI, and Gulf)
2.9/1 medium/heavy 113
distillate blend, UOP
Sample No. 3777-6
2.9/1 medium/heavy 113
distillate blend, UOP
Sample No. 3777-7
Medium and heavy dis- 114
tillate blend
5.75/1 medium/heavy 121
distillate blend
3/1 medium/heavy 126
distillate blend, from
Ft. Lewis pilot plant
2/1 medium/heavy 126
distillate blend, from
Ft. Lewis pilot plant
(Continued)
667
-------
Table 292 (Continued)
Material
Hydro-
treated
middle
distillates
(jet/
diesel/
other
light
fuel oil)
Process
EDS
Coal Type
IL No. 6
IL No. 6
IL No. 6
IL No. 6
Hydro-
treated
middle
distil late
blends
(light
fuel oils)
SRC-II NA
NA
NA
Value
(wt %)
89.58
88.86
87.98
87.10
86.91
86.84
87.17
(Continued)
Sample Description/Source Reference
Partially hydrotreated
350-650°F distillate
from one tpd pilot
plant
From low severity hydro-
treatment of partially
hydrotreated 350-650°F
distil late from one
tpd pilot plant
From moderate severity
hydrotreatment of
partially hydrotreated
350-650°F distillate
from one tpd pilot
plant
From high severity hydro-
treatment of partially
hydrotreated 350-650°F
distillate from one tpd
pilot plant
Moderately hydrotreated
2.9/1 medium/heavy
distillate blend, whole
liquid product, UOP
Sample No. 3777-21
Moderately hydrotreated
2.9/1 medium/heavy
distillate blend, 400°F+
liquid product, UOP
Sample No. 3777-34
Severely hydrotreated
2.9/1 medium/heavy
distillate blend, whole
liquid product, UOP
Sample No. 3777-28
99
99
99
99
113
113
113
668
-------
Table 292 (Concluded)
Process Coal Type
SRC-11 NA
Value
(wt %)
84.86
Sample Description/Source Reference
Severely hydretreated
2.9/1 medium/heavy
distillate blend, 400°F
liquid product, UOP
Sample No. 3777-41
Material
Hydro-
treated
middle
distil late
blends
(light
fuel oils)
Explanatory Notes
*The raw middle distillate from the proposed SRC-I demonstration plant
will consist of a 73.3/22.2/4.5 weight percent blend of middle dis-
tillates from the SRC, LC-Finer and coker units, respectively
(Reference 100).
'''See Part I, General Comments section, Note 4, for summary of operat-
ing conditions used.
113
Part I, General Comments section, Note 5, for summary of
operating conditions used.
669
-------
Table 293. Hydrogen Content
Material
Coal raw
middle
distillates
Process Coal Type
SRC-I* KY No. 9
KY No. 9
KY No. 9
SRC-II
H-Coal
KY No. 9
Wyodak
Value
(wt %)
8.68
8.20
10.09
9.51
NA
Pittsburgh
No. 8
(Powhattan
Mine)
NA
NA
NA
IL No. 6
8.83
8.84
9.20
9.07
9.0
9.57
10.69
Sample Description/Source Reference
Wilsonville pilot plant 82
SRC unit (Run No. 220,
APCI Sample No. 1897CB)
Wilsonville pilot plant
SRC unit (Run No. 225,
APCI Sample No. 1911CB)
Wilsonville pilot plant
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-19, APCI Sample
No. 1941CB-1)
Wilsonville pilot plant
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1949C.B)
Ft. Lewis pilot plant
Ft. Lewis pilot plant
Ft. Lewis pilot plant
Ft. Lewis pilot plant
Ft. Lewis pilot plant
380-650°F distillate
from PDU Run 5, Run
130-82, Period 291"
380-650°F distillate
from PDU Run 6, Run
130-83, Period 17f
82
82
82
84
101
102
122
126
111
112
(Continued)
670
-------
Table 293 (Continued)
Material
Coal raw
middle
distillates
Value
Process Coal Type (wt %) Sample Description/Source Reference
H-Coal NA
IL No. 6
NA
Coal raw
middle
distillate
blends
(light
fuel oil)
SRC- II
IL No. 6
Wyodak
W.KY No. 11
NA
Pittsburg
No. 8
(Powhattan
Mine)
NA
NA
NA
NA
10.03 >450-650°F distillate 84
from PDU
9.7 450-650°F distillate 98
from PDU, syncrude mode
11.19 260-552°F distillate 108
11.43 derived from atmos-
pheric still overhead
streams (analyzed by
Truesdail and Graphic
Science for EPRI)
9.7 PDU, syncrude mode 109
10.6 PDU, syncrude mode 109
9.3 PDU, syncrude mode 109
9.24 5.75/1 medium/heavy 101
distillate blend from
Ft. Lewis pilot plant
8.48 2.9/1 medium/heavy 101
distillate blend from
Ft. Lewis pilot plant
8.70 5/1 medium/heavy 84
distillate blend from
Ft. Lewis pilot plant
9.08 5/1 medium/heavy 108
8.70 distillate blend from
8.64 Ft. Lewis pilot plant
(analyzed by Truesdail,
Mobil for EPRI, and Gulf)
8.68 2.9/1 medium/heavy 113
distillate blend, UOP
Sample No. 3777-6
8.72 2.9/1 medium/heavy 113
distillate blend, UOP
Sample No. 3777-7
(Continued)
671
-------
Table 293 (Continued)
Material
Coal raw
middle
distil late
blends
(light
fuel oil)
Process Coal Type
SRC-11 NA
NA
NA
NA
Hydro-
treated
middle
distillates
(jet/
diesel/
other
light
fuel oil)
EDS
EDS
IL No. 6
(Monterey
Mine)
IL No. 6
IL No. 6
IL No. 6
IL No. 6
Value
(wt %)
8.74
8.86
8.9
8.5
13
9.10
10.97
11.84
12.83
Sample Description/Source Reference
Medium and heavy dis- 114
til late blend
5.75/1 medium/heavy
distillate blend
3/1 medium/heavy dis-
til late blend, from
Ft. Lewis pilot plant
2/1 medium/heavy dis-
til late blend, from
Ft. Lewis pilot plant
Partially hydrotreated
350-650°F distillate
from one tpd pilot
plant
Partially hydrotreated
350-650°F distillate
from one tpd pilot
plant
From low severity, hydro-
treatment of partially
hydrotreated 350-650°F
distillate from one tpd
pilot plant
From moderate severity
hydrotreatment of
partially hydrotreated
350-650°F distillate
from one tpd pilot
plant
From high severity
hydrotreatment of
partially hydrotreated
350-650°F distillate
from one tpd pilot
plant
121
126
126
104
99
99
99
99
(Continued)
672
-------
Table 293 (Concluded)
Value
Material Process Coal Type (wt %) Sample Description/Source Reference
Hydro-
treated
middle
distillate
blends
(light
fuel oil)
SRC-11 NA
NA
NA
NA
Explanatory Notes:
10.38 Moderately hydrotreated
2.9/1 medium/heavy dis-
tillate blend, whole
liquid product, UOP
Sample No. 3777-21
9.98 Moderately hydrotreated
2.9/1 medium/heavy dis-
tillate blend, 400°F+
liquid product, UOP
Sample No. 3777-34
11.18 Severely hydrotreated
2.9/1 medium/heavy
distillate blend, whole
liquid product, UOP
Sample No. 3777-28
10.59 Severely hydrotreated
2.9/1 medium/heavy dis-
tillate blend, 400°F
liquid product, UOP
Sample No. 3777-41
113
113
113
113
*The raw middle distillate from the proposed SRC-I demonstration plant will
consist of a 73.3/22.2/4.5 weight percent blend of middle distillates from the
SRC, LC-Finer and coker units, respectively (Reference 100).
'''See General Comments section, Note 4, for summary of operating conditions
used.
fSee General Comments section, Note 5, for summary of operating conditions
used.
673
-------
Table 294A. Trace Elements Content (Qualitative Data)
Material Process Coal Type Trace Metals Present Sample Description/Source Reference
Coal raw SRC- I*
middle
distillates
KY No. 9 Major
Minor
Trace
KY No. 9 Major
Minor
Trace
KY No, 9 Major
Minor
Fe.Si
Ca,K,Zn,
T1.A1
Cr.Mn.N1,
Cu.As.Zr.Mo
Al.S1.Fe
K.Ca.Mo,
Ti,Zn
Cr.Mn.Ni.Zr,
Cu.As.Pb.Sr
Si.Fe
Al.K.Ca,
Wilsonville pilot plant,
SRC unit (Run No. 220,
APCI Sample No. 1897CB)
Wilsonville pilot plant,
SRC unit (Run No. 225,
APCI Sample No. 1911CB)
Wilsonville pilot plant,
Lummus LC-F1ner unit
82
82
82
cr>
~j
.£»
KY No. 9
Ti.Zn
Trace V.Ni.Cu.Ga,
Ge.As.Pb.Sr,
Zr and Ba
Major Si,Ca
Minor Al.Fe.Ti,
K,Cu,Zn,Zr
Trace Mn.Ni.As
(Lummus Run No. 2-LC
Finer-29, APCI Sample No.
1941CB-1)
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample No.
1949CB)
Explanatory Notes:
82
*The raw middle distillate from the proposed SRC-I demonstration plant will consist of a
73.3/22.2/4.5 weight percent blend of middle distillates from the SRC, LC-Finer and
coker units, respectively (Reference 100).
-------
Table 294B. Trace Elements Content (Quantitative Data)(ppmw)
Material Process
Coal raw SRC- I I
•Iddle
distillates
H-Coal
cn
^J
CD
Coal raw SRC* 1 1
•Iddle
distillate
blends
(light
fuel oil)
Hydrotreated
•Iddle
distillates
(Jet/diesel/
other light
fuel oil)
Hydrotreated
alddle
distillate
blends
(light
fuel oil)
Coal Type
NA
HA
NA
HA
HA
II No. 6
(Burning
Star Nine
IL NO. 6
Uyodak
U. KY 11
IL No. 6
(Burning
Star
Nine)
NA
NA
NA
NA
NA
Tl
<0.1
<0.012
<0.1
NA
0.02
HA
NA
N0(2)
N0(2)
0.01
NA
0.5
NA
0.85
0.5
NA
NA
Na
5.0
S.I
0.67
0.15
HA
1.1
NA
0.2
0.39
8.1
NA
1.4
0.39
<0.10
1.4
NA
NA
K
2.0
0.19
0.26
HA
HA
0.20
NA
0.03
0.05
5.7
NA
l.S
NA
NA
l.S
NA
HA
Ca
0.52
0.3S
0.29
0.31
0.18
NA
NA
0.10
0.11
0.38
NA
1.6
1.5
l.S
1.6
NA
NA
V Pb
0.12 0.29
<0.02 <0.16
<0.1 0.14
<0.04 NA
0.003 0.27
HA NA
0.2 NA
0.2 0.1
0.1 0.1
<0.02 <0.15
0.2 NA
0.23 0.12
<1.0 HA
0.03 0.17
0.23 0.12
NA NA
NA NA
Fe
2.1
0.69
3.7
38. 0
52.0
3.3
1.0
2.2
0.8
1.7
1.0
13
13.0
13.0
13.0
HA
HA
P
<0.01
-------
Table 294B (Concluded)
6
NA
0.1
NA
NA
0.06
NA
NA
NA
NA
NA
HA
NA
NA
0.31
Ho Ag
NA NA
<0.08 <0.06
NA NA
NA NA
0.05 0.001
NA NA
NA NA
NO NA
(0.01)
NO NA
(0.06)
<0.02 NA
NA NA
NA NA
NA NA
0.03 0.002
Co
NA
<0.04
NA
NA
0.005
NA
NA
NO
(0.01)
0.3
<0.04
NA
NA
NA
0.02
Al
NA
<0.4
NA
NA
0.50
NA
NA
1.5
1.9
1.1
NA
NA
NA
13.0
As
NA
0.004*
NA
NA
NA
NA
NA
0.005
0.005
0.018
NA
NA
NA
NA
J«a_
NA
NO
NA
NA
NA
NA
NA
0.14
Sb
NA
0.003*
NA
NA
HA
NA
NA
NA
NO NA
(0.007)
0.04
NA
NA
NA
NA
NA
NA
NA
NA
NA
Ba
NA
0.02
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Be
NA
<0.006
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
B1
NA
1.0
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Se
NA
0.002
NA
NA
HA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Sr
NA
NO
NA
NA
HA
NA
NA
NA
NA
NA
NA
NA
NA
NA
U
NA
NO
NA
NA
HA
NA
NA
NA
NA
NA
NA
NA
NA
NA
U
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA NA NA NA NA
NA
NA
NA
NA
NA
NA
Sample Description/Source Reference
Ft. Lewis pilot plant
Ft. Lewis pilot plant
>450-650*F distillate
from POU
260-552'F distillate
derived fro* atmos-
pheric still overhead
streams (analyzed by
Truesdall and Graphic
Science for EPRl)*.'
PDU (Ashland Oil Sample)
POU syncrude mode
PDU syncrude node
POU syncrude Mode
POU (Ashland oil sample)
5/1 iwdIurn/heavy distil-
late blend fro* Ft.
Lewis pilot plant
5/1 nedlun/heavy distil-
late blend from Ft.
Lewis pilot plant
(2 samples analyzed by
Truesdall and one
sample by Mobil for
EPRI)*.f
84
125
84
108
96
109
109
109
96
84
108
NA NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Explanatory Notes
•All values In first 2 rows by wet chemical method.
*A11 values In third row by spectographlc oethod.
^Determined by flameless AAS. All other elements were determined by ICP.
NA
NA
NA NA
NA
-------
Table 295. Ash Content (by Ultimate Analysis)
Material Process Coal Type Value (wt %) Sample Description/Source Reference
Coal raw SRC-II NA 0.10 Ft. Lewis pilot plant 126
middle
distillates NA 0.60 2/1 medium/heavy distil- 126
late blend, from Ft.
Lewis pilot plant
Coal raw NA
middle
distillate
blend
(light
fuel
oil)
Hydro- NA
treated
middle
distillates
(jet/diesel
other light
fuel oil)
Hydro- NA
treated
middle
distillate
blends
(light
fuel oils)
677
-------
Material
A. Saturates
Coal raw
middle
distillates
Table 296. Saturates, Olefins and Aromatics Contents
Value
Process Coal Type (vol %) Sample Description/Source Reference
SRC-I* KY No. 9
KY No. 9
KY No. 9
KY No. 9
EDS
Coal raw
middle
distillate
blends
(light
fuel oil)
SRC-11
IL No. 6
IL No. 6
NA
61.98* Wilsonville pilot plant, 82
(wt %) SRC unit (Run No. 220, APCI
Sample No. 1897CB)
62.581" Wilsonville pilot plant, 82
(wt %) SRC unit (Run No. 225, APCI
Sample No. 1911CB)
86.091" Wilsonville pilot plant 82
(wt %) Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1941CB-1)
87.571" Wilsonville pilot plant 82
(wt %} Lummus LC-Finer unit
(Lummus Run No. 2 LC
Finer-27, APCI Sample
No. 1949CB)
22.2* Raw 350-650°F distill- 99
ate from one tpd pilot
plant
42 450-650°F distillate 98
from POU, syncrude mode
9.9 2.9/1 medium/heavy dis- 113
til late blend, UOP
Sample No. 3777-6
9.4 2.9/1 medium/heavy dis- 113
til late blend, UOP
Sample No. 3777-7
(Continued)
678
-------
Table 296 (Continued)
Material
Hydro-
treated
middle
distil lates
(jet/
diesel/
other
light
fuel oil)
Process Coal Type
EDS IL No. 6
IL No. 6
IL No. 6
IL No. 6
Hydro-
treated
middle
distillate
blends
(light
fuel oils)
SRC-II NA
NA
NA
NA
Value
(vol %)
14.2*
17.2*
26.0*
84.2*
21.2
10.7
42.9
26.1
Sample Description/Source Reference
Partially hydrotreated 99
350-650°F distillate
from one tpd pilot plant
From low severity, hydro- 99
treatment of partially
hydrotreated 350-650°F
distillate from one tpd
pilot plant
From moderate severity 99
hydrotreatment of parti-
ally hydrotreated
350-650°F distillate from
one tpd pilot plant
From high severity hydro- 99
treatment of partially
hydrotreated 350-650°F
distillate from one tpd
pilot plant
Moderately hydrotreated 113
2.9/1 medium/heavy dis-
til late blend, whole
liquid product, UOP
Sample No. 3777-21
Moderately hydrotreated 113
2.9/1 medium/heavy dis-
tillate blend, 400°Ft
liquid product, UOP
Sample No. 3777-34
Severely hydrotreated 113
2.9/1 medium/heavy dis-
til late blend, whole
liquid product, UOP
Sample No. 3777-28
Severely hydrotreated 113
2.9/1 medium/heavy dis-
tillate blend, 400°F
liquid product, UOP
Sample No. 3777-41
(Continued)
679
-------
Table 296 (Continued)
Material
B. Olefins
Coal raw
middle
distillates
Hydro-
treated
middle
distillates
(jet/
diesel/
other
light
fuel oil)
Process Coal Type
EDS
EDS
IL No. 6
IL No. 6
Hydro-
treated
middle
distillate
blends
(light
fuel oils)
Coal raw
middle
distil late
blends
(light
fuel oil)
IL No. 6
IL No. 6
IL No. 6
NA
NA
Value
(vol %)
9.2f
0.9?
5.5*
1.7f
3.9f
Sample Description/Source Reference
Raw 350-650°F distill-
ate from one tpd pilot
plant
Partially hydrotreated
350-650°F distillate
from one tpd pilot
plant
From low severity hydro-
treatment of partially
hydrotreated 350-650°F
distillate from one tpd
pilot plant
From moderate severity
hydrotreatment of
partially hydrotreated
350-650°F distillate
from one tpd pilot plant
From high severity hydro-
treatment of partially
hydrotreated 350-650°F
distillate from one tpd
pilot plant
99
99
99
99
99
(Continued)
680
-------
Material
C. Aromatics
Coal raw
middle
distillates
Process
Table 296 (Continued)
Value
Coal Type (vol %) Sample Description/Source Reference
Coal raw
middle
distillate
blends
(light
fuel oil)
Hydro-
treated
middle
distillates
(jet/
diesel/
other
light
fuel oil)
SRC-I* KY No. 9
KY No. 9
KY No. 9
KY No. 9
EDS
SRC-11
EDS
IL No. 6
IL No. 6
NA
NA
IL No. 6
IL No. 6
21.82*
(wt X)
16.67*
0.20*
1.06*
68.6f
58
90.1
54.4
84.gf
77.3f
Wilsonville pilot plant,
SRC unit (Run No. 220,
APCI Sample No. 1897CB)
Wilsonville pilot plant,
SRC unit (Run No. 225,
APCI Sample No. 1911C8)
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1941CB-1)
Wisonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1949CB)
Raw 350-650°F distillate
from one tpd pilot plant
450-650°F distillate
PDU, syncrude mode
from
2.9/1 medium/heavy dis-
tillate blend, UOP Sample
No. 3777-6
2.9/1 medium/heavy dis-
tillate blend, UOP Sample
No. 3777-7
Partially hydrotreated
350-650°F distillate
from one tpd pilot plant
From low severity hydro-
treatment of partially
hydrotreated 350-650°F
distillate from one tpd
pilot plant
82
82
82
82
99
98
113
113
99
99
(Continued)
681
-------
Material
Hydro-
treated
middle
distillates
(jet/
diesel/
other
light
fuel oil)
Hyd ro-
treated
middle
distillate
blends
(light
fuel oil)
Table 296 (Concluded)
Value
Process Coal Type (vol %)_ Sample Description/Source Reference
EDS
IL No. 6
IL No. 6
SRC-11 NA
NA
NA
NA
Explanatory Notes:
72.3^ From moderate severity
hydrotreatment of
partially hydrotreated
350-650°F distillate
from one tpd pilot plant
11.9f From high seventy hydro-
treatment of partially
hydrotreated 350-650°F
distillate from one tpd
pilot plant
59.1 Moderately hydrotreated
2.9/1 medium/heavy dis-
tillate blend, whole
liquid product, UOP
Sample No. 3777-21
69.9 Moderately hydrotreated
2.9/1 medium/heavy dis-
tillate blend, 400°F+
liquid product, UOP
Sample No. 3777-34
50.8 Severely hydrotreated
2.9/1 medium/heavy dis-
tillate blend, whole
liquid product, UOP
Sample No. 3777-28
73.9 Severely hydrotreated
2.9/1 medium/heavy dis-
tillate blend, 400°F+
liquid product, UOP
Sample No. 3777-41
99
99
113
113
113
113
*The raw middle distillate from the proposed SRC-I demonstration plant
will consist of a 73.3/22.2/4.5 weight percent blend of middle distill.
ates from the SRC, LC-Finer and coker units, respectively (Reference
100).
tDetermined via APCI absorption chromatography method.
analysis
682
-------
Table 297. Detailed Hydrocarbon Class/Compound Analysis'*
Material
Coal raw
•Iddle
distillates
Process Coal Type
SRC-It Kt No. 9
Value
Compound Class
Phenanthrene
naphthalene
2-Hethyl-Naphthalene
2-«ethy1 -1-PropyI-Naphtha1ene
a Dimethyl-Naphthalene
Mt I Saaple Description/Source . Reference
KY No. 9 Phenanthrene
2-Methyl-Naphthalene
Naphthalene
Dlbenzofuran
a OlMthyl-Naphthalene
9H-F1uorene
1,2,3,4-Tetrahydro-
Niphthalene
1,2-01hydroxy-Ace-Naphthalene
a Nethyl-9H-nuorene
l,l'-B1phenyl
1-Methyl-Naphthalene
2-Ethyl-Naphthalene
5-/6-ttethyl-Tetnhydro-
Naphthalene
a D1«ethyl-Naphthalene
a Propyl-Naphthalene
Hexadecane
a Hethyl-9H-F1uorene
(Continued)
5.2f
4.5
3.7
2.2
2.1
1,2,3,4-Tetrahydro.Napnthtlene 1.3
2-Ethyl-Naphthalene US
Te trade cane 1.7
a Hethyl-9H-F1uorene 1.6
a B-Nethyl-Naphthalene l.S
2-Isopropyl-Naphthalene 1.3
Heptadecane 1.2
4-Methy1-l,l-B1pheny1 1.2
Dibenzofuran 1.2
C2-Alkyl-B1phenyl 1.2
an n-Propyl Naphthalene 1.1
5- or 6-Hethyl-Tetrahydro- 1.1
Naphthalene
Ullsonville pilot plant,
SRC unit (Run No. 220,
APCI Saaple No. 1897CB)
32
9.if H1lsonv1lle pilot plant,
7.1 SRC unit (Run No. 22S,
6.1 APCI Sample No. 1911CB)
3.4
2.8
2.7
2.6
2.3
2.3
2.1
1.5
1.5
1.5
1.2
1.0
1.0
1.0
82
683
-------
Table 297 (Continued)
Material
Coal r*w
middle
distillates
Process
SRC-It KY No. 9
KY No. 9
Value
Compound Class
2-ftutyl-Naphthalene
Phenanthrene
Methyl -Tetr shydrojty
Chen ant hrene
a 01methyl-81phenyl
C4-Alkyl-Tetrahydro-
Naphthalene
a Dlmethyl-Blphenyl
Kt I Sample Description/Source Reference
3.8*
3.4
3.2
3.0
3.0
2.4
2.2
a Hethyl-Blphenyl
a Methyl-Phenanthrene 2.2
a C2-Alkyl-B1phenyl 2.2
a Methyl-Tetrahydro- 2.2
Naphthalene
1,2.3,4-Tetrahydro- 2.1
Naphthalene
a Methyl-Tetrahydro- 2.2
Naphthalene
C2-Alkyl-Octahydro-Phenanthrene 2.0
4 component mixture 2.0
4 component Mixture 1.9
Octahydro-Phenanthrene 1.9
2-Methyl-Naphthalene 1.7
peak not part of 1.5
assembled MS
B-Tetrahydro-Naphthalene
Propyl-Olhydro-Naphthalene 1.4
2-Butyl-Naphthalene 4.2t
Perlnaphthrene 3.6
1.2.3,4-Tetrahydro- 3.2
Naphthalene
Phenanthrene 3.1
a Methy1-9H-Fluorene 2.6
5-/6-Methyl-l,2,3, 2.5
4-Tetrahydro-Naphthalene
C4-Alkyl-Tetrahydro- 2.3
Naphthalene
2-Methyl-Naphthalene 2.2
Unknown H-aromat1c 2.0
Octahydro-phenanthrene 1.9
Methyl-B-Naphthalene 1.9
a D1-Methyl-B1phenyl 1.8
Unknown mixture 1.4
(Continued)
Wllsonvllle pilot plant
Lunmus LC-Finer unit
(Lummus Run No. 2-LC
Mner-29, APCI Sample
to. 1941C8-1)
82
Ullsonvllle pilot plant,
LIMWS LC-Flner unit
(Lunnus Run No. 2-LC
F1ner-27, APCI Sample
No. 1949CB)
82
684
-------
Table 297 (Continued)
Material
Coal PI*
•1ddle
distillates
Process
SRC-1^ KY Ho. 9
H-Coal IL No. 6
Value
Compound Class
9H-F1uorene
Octahydro-phenanthrene
M-Tetrahydro-PheMiithrene
Unknown Mixture
3-T-Butyl-l-2
01hydro-Naphtha1ene
Unknown Mixture
Z No. -8
TetraHns
Wt I Sample Description/Source Reference
1.4
1.4
1.4
1.4
1.3
1.3
1.3
Carbon
No.
Cg
C7
ca
ClO
Cll
Cl2
Cl3
Cl4
Cl5
Cl6
Cl7
Cl8
Cio
C20
C21
C22
C23
C24
C2s
Total
Z No. -10
01 naphthenobenzenes
C6
C7
C8
C9
ClO
Cll
Cl2
Cl3
Cl4
Cl5
Cl6
Cl7
CIB
Cl9
C2o
C21
C22
C23
C24
C25
Total
Pet
NA
NA
NA
0.2
2.5
6.6
4.6
3.5
3.3
1.9
0.8
0.5
0.2
0.1
0.0
0.0
0.1
0.0
0.0
0.0
24.7
or Indenes
NA
NA
NA
0.0
0.0
0.0
0.8
2.2
2.9
1.7
1.1
0.6
0.3
0.1
0.0
0.0
0.1
0.0
0.0
0.0
9.8
380-650*F distillate fro«
POU Run 5, Run 130-82,
Period 29§
111
(Continued)
685
-------
Table 297 (Continued)
Material
Coal raw
middle
distillates
Process
H-Coal IL No. 6
Value
Compound Class
Z No. -14
Biphenyls and Acenaphthenes
Carbon
No. Pet
Ht < Sample Description/Source Reference
C?
£8
£
CIQ
&3
r14
c15
j"
r18
C19
el?
CZ2
r23
CZ4
Total
NA
NA
NA
NA
NA
0.5
2.9
3.6
2.3
1.2
0.7
0.3
0.1
0,0
0.1
0.0
0.0
0.0
JL£
12.0
Z No. -16
Fluorines and Acenaphthenes
1
I
r12
Cl3
Cl4
r15
r16
Cl7
r18
CW
C20
&1
C22
r23
r24
C2S
Total
(Continued)
NA
NA
NA
NA
NA
NA
0.1
0.5
1.2
0.9
0.9
0.7
0.3
0.1
0.0
0.0
0.0
0.0
0.0
0^0
4.9
686
-------
Table 297 (Continued)
Material Process Coal Type
Coal rn H-Coal IL No. 6
»1ddle
distillates
Value
Compound Class
Z No. -18
Phenanthrenes and Anthracenes
Carbon
*>• Pet
Cc NA
C; NA
Co NA
Cq NA
C10 NA
&1 "*
Cl7 "*
C13 NA
CM °-7
C15 0.4
Cj6 0.2
Cj7 0.1
Cia 0.0
Ci9 0.0
Czo 0.0
C21 0.0
C?? 0.0
CZ3 0.0
Cj4 0.0
Cjs 0.0
Total TIT
tft I Saaple Description/Source Reference
H-Coal Wyodak
Paraffins
Monocycloparaff1ns
D1cycloparaff1ns
Trtcycloparafflns
Total
Alkylbenzenes
Indans and Tetrallns
D1naphthenooenzenes
CIQ Naphthalene
CM* Naphthalene
Blphenyls, etc.
Flourenes, etc.
Tr1 cyclic AroMtlcs
Total AroMtlcs
(Continued)
16.7 380-650-F distillate
15.4 from PDU Run 6, Run
5.7 130-83. Period 17*
1.1
•3O
10.5
20.8
4.9
1.4
8.2
7.8
4.8
2.7
61.1
T5OO
112
687
-------
Table 297 (Continued)
Material Process Coa? Typ«
Coal raw
middle
distillates
tt-Coal IL No. 6
Uyodak
V«lue
Compound Class
X Class
HonoaroMtlcs
-6 Alkyl Benzenes
-8 Naphthene Benzenes
-10 DI-Naphthene Benzenes
D1aromatic;
-12 Naphthalenes
-14 Acenaphthenes, Blphenyls
-16 Fluorenes
Tr1aro»at1cs
-18 Phenanthrenes
-20 Naphthene Phenan-
threnes
Tetraaromatlcs
-22 Pyrenes, Fluoranthrenes
-24 Chrysenes
Pentaaromatlcs
-26 Benzofluoranthrenes
-28 Perylenes
-30 Olbenzanthracenes
X Class
Honoaromatlcs
-6 Alkyl Benzenes
-8 Naphthene Benzenes
-10 01-Naphthene Benzenes
Olaraaatlcs
-12 Naphthalenes
-14 Acenaphthenes, Blphenyls
-16 fluorenes
TrlaroMUcs
-18 Phenanthrenes
-20 Naphthene Phenan-
threnes
Tetraaroaatlcs
-22 Pyrenes, Fluoranthrenes
-24 Chrysenes
Pentaarcnatics
-26 Benzofluoranthrenes
-28 Perylenes
-30 D1benzanthracenes
(Continued)
Ht 1 Sarople Description/Source Reference
PDU, syncrude node 109
7.0
22.9
12.6
15.7
10.6
3.4
1.2
0.0
0.0
0.0
0.0
0.0
0.0
PDU, syncrude node
109
9.2
26.9
6.7
12.3
4.0
1.1
0.3
0.0
0.0
0.0
0.0
0.0
0.0
688
-------
Table 297 (Continued)
Material
Coal raw
middle
distillates
Process Coal Type
H-Coal W. KY 11
en
oo
<£>
Value Compound Class
X Class**
Monoaromatics
-6 Alkyl Benzenes
-8 Naphthene Benzenes
-10 Di-Naphthene Benzenes
Dlaromatics
-12 Naphthalenes
-14 Acenaphthenes, Biphenyls
-16 Fluorenes
Triaromatics
-18 Phenanthrenes
-20 Naphthene Phenan-
threnes
Tetraaromatics
-22 Pyrenes, Fluoranthrenes
-24 Chrysenes
Pentaaromatics
-26 Benzofluoranthrenes
-28 Perylenes
-30 Dibenzanthracenes
Wt % Sample Description/Source Reference
5.6
16.8
8.4
15.2
10.5
5.0
2.5
0.1
0.0
0.0
0.0
0.0
0.0
POU, syncrude mode
109
(Continued)
-------
Table 297 (Concluded)
10
o
Material
Coal raw
•Iddle
distillate
blends
(light
fuel oils)
Process Coal Type i No.
Hydrocarbon Types
Analysis Compound
Types
SRC-II NA
z--2
z-0
i-Z
z-4
1-6
z No.
Paraffins
1 Ring Naphthenes
2 Ming Naphthenes
3 Ring Naphthenes
4 Ring Naphthenes
Total Saturates
Aromatic
Hydrocarbons Compound
Types CnH2n.z»t
ut t
3.6
1.3
1.8
1.3
0.4
8.4
0.9
10.3
2.7
12.1
7.5
4.4
6.7
2.6
4.7
0.9
0.3
0.6
<0.1
T
T
T
53.8
Average
Molecular
Weight
226
224
208
206
190
216
158
165
185
159
185
205
197
227
223
246
276
280
292
NO
NO
NO
186
Sample Description/Source Reference
2.9/1 medium/heavy distillate
blend. UOP Sample No. 3777-6
113
•6 Benzenes
•8 Indans/Tetrallns
•10 Dlnaphthene Benzenes
•12 Naphthalenes
•14 Acenaphthenes/Blphenyls
•16 Fluorenes
•18 Phenanthrenes
•20 Aceanthrenes
•22 Pyrenes
•24 Chrysenes
•26 flenzofluoranthenes
•28 Benzopyrenes
•30 Dlbenzanthracenes
•32 Benzoperylenes
•34 Oibenzopyrenes
•36 Coronenes
Total Aromatic Hydrocarbons
Hydrotreated NA —
•tddle
distillates
(jet/dlesel/
other light
fuel oil)
Hydrotreated HA —
middle dis-
tillate
blends (light
fuel oils)
Explanatory Notes
*A1I values by MS analyses
*The raw middle distillate from the proposed SRC-1 demonstration plant will consist of a 73.3/22.2/4.5 weight percent
blend of middle distillates from the SRC. LC-Flner and coker units, respectively (Reference 100).
lvalues by GC/HS; compounds listed are the twenty most prevalent compounds present In the sample.
&See General Comments section. Note 4, for summary of operating conditions used.
'See General Comments section. Note 5, for summary of operating conditions used.
••From the molecular formula: CnH2n+x
ttSuggested compound types; multIheteroartxnatlcs normalized out of results.
-------
Table 298. Nitrogen-, Oxygen-, and Sulfur-Containing Compound1
Material
Process Coal Type
Coal raw SRC-It KY No. 9
•Iddle
distillates
KY No. 9
ICY No. 9
KY No. 9
KY No. 9
KY No. 9
Value
Compound Class
a C3-AUyl -Phenol
a C5-A1 Icy 1-81 phenol
3- & 4-Methyl-Phenol
Total Phenols
3- S 4-Methyl-Phenols
an Ethyl-Methyl-Phenol
Total Phenols
01benzoth1ophene
Total Phenols
Total Phenols
Phenol
0-Cresol
•tp-Cresol
2,6-Xylenol
0-EthyI phenol
3.4- I 2,5-Xylenol
•ftp-Ethyl phenol
2,3-Xylenol
3,4-Xylenol
Heavier Phenol1es
Total
Phenol
0-Cresol
•Ip-Cresol
2,6-Xylenol
0-Ethy1 phenol
2.4- S 2,5-Xylenol
•Ap-Ethylphenol
2.3-Xylenol
3,4-Xylenol
Heavier phenol1c$
Wt I Sample Description/Source Reference
2.0
1.6
1.4
15.87
1.9
1.6
12.58
1.3
7.56
1.91
0.38
0.10
1.21
0.06
0.16
0.94
1.91
0.15
0.21
7.47
12.59
Wllsonvllle pilot plant, 82
SRC unit (Run No. 220,
APCI Sample No. 1897CB)
Wllsonvllle pilot plant, 82
SRC unit (Run No. 225,
APCI Sanple No. 19UCB)
Wllsonvllle pilot plant 82
LUMWS LC-F1ner unit
(Lunws Run No. 2-LC
Finer-39, APCI Saaple
No. 1941C8-1)
Wllsonvllle pilot plant, 82
Lunws LC-Flner unit
(Lunus Run No. 2-LC
F1ner-27. APCI Staple
No. 1949CB)
Wllsonvllle pilot plant, 82
SRC unit (Run No. 220,
APCI SMple No. 1899CB).
Caustic extraction with
201 NaOH. (l/l-v/v);GC
analysis of extract
Wllsonvllle pilot plant, 82
SRC unit (Run No. 225,
APCI Sanple No. 1911C8).
Caustic extraction with
20t NaOH, (1/1-v/v); SC
analysis of extract
Total
18.91
(Continued)
691
-------
Table 298 (Continued)
Material
Process Coal Type
Coal raw SRC-Jt
distillates
No. 9
KY No. 9
H-Coal IL No. 5
Value
Coaoound Class
Phenol
0-Cresol
•Ap-Cresol
2.6-Xylenol
0-Ethylphenol
2.4- I 2,5-Xylenol
•ftp Etnylphenol
2,3-XylenoI
3,4-Xylenol
Heavier phenollcs
Phenol
0-Cresol
•tp-Cresol
2,6-Xylenol
0- Ethyl phenol
2,4- ft 2.5-Xylenol
•ip Ethylphenol
2,3-Xylenol
3.4-Xylenol
Heavier phenollcs
Total
Caustic
tt X
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
0.37
OT37
Extract
from Ataospherfc
Overhead
Phenol s Product^
Yields. W I
of Dry Coal
7 Mesh Components
Phenol
0-Cresol
•ip-Cresol
0-Ethylphenol
2,6-Xylenol
•ip- Ethyl phenol
Unknown
2,3. 1 4,5-Xylenol
3,4-Xylenol
Heavier Components
Total
0.02
0.55
0.33
0.85
0.09
0.04
0.39
0.25
0.24
0.06
1.20
4.0
Sample Description/Source
W1! sonvflle pilot plant,
litmus LC- Finer unit
(Lumnus Run No. 2-LC
Finer- 39, APCI Sample
No. 1941CB-1). Caustic
extraction with 20S
NaOH. 1/1-v/v, SC
analysis of extract
M1lsonv11le pilot plant,
Lwmus LC-F1ner unit
(Lunmis Run No. 2-LC
F1ner-27, APCI Sample
No. 1949CB). Caustic
extraction with 201
NaOH, 1/1-v/v, 8C
analysis of extract
380-650*F distillate fro»
POD Run 5. Run 130-82,
Period 29§
(17 compounds)
Reference
82
82
111
(Continued)
692
-------
Table 298 (Continued)
Material
Coal raw
middle
distillates
Process Coal Type
H-Coal Wyodak
a NO. s
IL No. 6
Wyodak
U.KY 11
Value
Compound Class
Phenols
Phenols
X Class**
Aromatic Sulfur
Types
-10 Benzoth lo-
phenes
-16 Olbenzo-
th lophenes
-22 Naphthobenzo-
thiophene
Unidentified
X Class§
Aromatic Sulfur
Types
-10 Benzoth lo-
phenes
-16 Dlbenzo-
th lophenes
-22 Naphthobenzo-
thlophene
Unidentified
X Class §
Aro»at1c Sulfur
Types
-10 Benzoth 1o-
phenes
-16 Dlbenzo-
th lophenes
-22 Naphthobenzo-
thlophene
Unidentified
Wt t
5.0
17.0
0.1"
0.0
0.0
0.0
0.0
0.0
0.0
0.2n
0.1
0.0
0.0
Sample Description/Source Reference
112
360-650*F distillate from
POU Run 6. Run 130-83,
Period 17*
450-650'F distillate
fro« POU, syncrude node
POU, syncrude node
98
109
POU, syncrude node
109
POU, syncrude node
109
(Continued)
693
-------
Table 298 (Continued)
Material
Coal raw
•Iddle
dlstlllite
blends
(light
fuel otls)
Process Coal Type
SRC-11 NA
Aromatic Oxygens Compound
• ID
z No.
•6
•8
-10
•12
•14
•16
-18
-20
-22
-24
z No.
•6
-14
•16
•18
•20
Z No.
z-6
z-12
1-14
Types. S CnH2n-z°"
Phenols
Haphthenophenols
Benzofurans
Naphthols
Naphthenonaphthol s
Dlbenzofurans
Hydroxyanthracenes
Kydroxynaphthenoanthracenes
Hydroxypyrenes
Hydroxychrysenes
Total
Aromatic 01 oxygenates
Compound Types.
CnH2n-z02>*
Hydroxy phenols
Hydroxynaphthenonaphthol s
Hydroxydlbenzofurans
Othydroxyanthracenes
D1 hydroxynaphthenonanthra-
cenes
Total
Aromatic Trloxygenates
Compound Types.
CnH2n-z°3"
01 hydroxy phenols
Dlhydroxynaphthol
01 hydroxynaphthenonaphthol s
(wt X) Sample Description/Source
14.4 2.9/1 medium/heavy distil
5.7 late blend. UOP Sample
0.6 No. 3777-6
<0. 1
3.2
2.6
0.3
0.2
0.5
T "
2775
0.3§§
0.7§§
0.5§§
<0. 1§§
<0.1§§
1.7
<0.1§§
0.2§§
T §§
Reference
113
-------
Table 298 (Continued)
Material
Coal raw
•Iddl*
distillate
blends
(light
fuel oils)
Process Coal Type
SRC-II KA
a\
UD
en
z No.
•SN
•7N
•9N
-UN
-13N
•15N
-17N
-19N
»21N
-23N
•25N
•27N
Average
Aromatic Nitrogens Compound Molecular
Types, CnH2n-zNff Ut I Height Staple Description/Source Reference
Pyrldtnes
Naphthenopyrldtnes
Indoles
Qulnollnes
Naphthenoqulnollnes
Carbazoles
Acrtdtnes
Naphthenobenzoqutnollnes
Benzocarbazoles
Benzacrldlnes
Naphthenobenzacrtdl nes
Olbenzocarbazoles
1.5
1.1
0.6
1.3
0.6
0.6
0.6
<0.1
o.s
<0.1
T
T
130
153
152
156
198
191
202
222
228
254
NA
NA
z No.
Z-6S
z-as
z-lOS
Z-12S
Z-14S
Z-16S
Z-18S
Z-20S
Z-22S
Z-24S
Z-26S
Total
AroMtlc Sulfurs Compound
Types,
Benzenethtols
01 hydroth1onaphthenes
Benzothlophenes
Naphthenobenzothlophenes
Indenothtophenes
01 benzothtophenes
Acenaphthenotht ophenes
Huorenothl ophenes
Trlbenjothlophenes
Acephenanthrylenethto-
phenes
Pyrenothtophenes
Total
7.0
Ht If
T
0.2
T
T
0.6
T
T
T
1.2
167
NA
199
172
NA
NA
20S
239
NA
250
NA
NA
209
(Continued)
-------
Table 298 (Concluded)
Material
Coal raw
•1ddle
distill at*
blends
(light
fuel oils)
Process Coal Type
SRC-11 NA
NA
NA
Value
Compound Class
Phenol
Phenol
Ht I Sample Description/Source Reference
2.0 Medium and heavy distil- US
late blend, before water
wash, Chevron Sample
No. SGQ-7559
1.7 Medium and heavy distil- US
late blend, after water
wash. Chevron Saaple
No. WOW-45S1
Hydro-
treated
middle
distillates
(jet/
dlesel/
other
light
fuel oil)
Hydro- NA — —
treated
middle
distillate
blends
(light
fuel oils)
Explanatory Notes
•All values by MS analysis.
tThe raw Middle distillate fro* the proposed SRC-I demonstration plant Mill consist of a 73.3/22.2/4.5
weight percent blend of Middle distillates froM the SRC, LC-Flner and coker units, respectively
(Reference 100).
f9.5 VI (11.0 wt %) of atoosplwrlc still overhead.
§Set General CoMMnts section. Not* 4, for siMury of operating conditions used.
'See General Consents section. Note S, for suMMry of operating conditions used.
**FroM the Molecular formula: Cjn+x-
^Analysis by GC/NS.
ffSuggested compound types. Hult1heteroarooat1cs normalized.
§§EstlMates due to lack of sensitivity data.
"T - trace, £ O.OSX
696
-------
Table 299. Compound Class Analysis Obtained by Solvent Fractionation (wt
Heutrel Fraction
Ether Ether Cthcr . fautrtl
Coil In- Soluble Insoluble Soluble Insoluble Uiutri) Kcutrtl foly- Ikutral
Material Process Type Volatile* solubles Acids Acids lasts lists Saturates Aro.n Ics Aromtlct folirt Totil i«p»rl«enUI Si^ntttm »«co»»ry S»ol« Dcnrl»t ton/Source >«ftrencc
• Coil rw MA — — — — -- -- -- -- — — ~
•iddlc
Coil r«. SRC- 1 1 M
• Iddle
distil Itte
blends
(Ililil
fuel oil)
3.0
NA
3.8
O.I
S.(
0.1
6.0
M.I
0.2 M 2 «.S 71.S (1.1 ft. l«ls pilot pluit. 136
fuel oil bltrul. DOC
Ho. 1710
CTl
IO
Hydro- NA
treated
•iddle
distillates
(jet/diesil/
Other light
fuel oil)
Hydro- HA
treated
•iddle
distllUte
blends
(light
fuel olli)
C»pl>ruiory Halt
•Thii solvent fr«ct lonitlon schcw Involves i coablnttlon of liquid-liquid e« tract ions ind coluan cbroutogriphy Otferenci 13C).
-------
Table 300. General Physical and Chemical Properties of Various Distillation Fractions
of Coal Raw Middle Distillates
Material Process
Coil raw SRC- 1 1
•Iddle
distillates
Coal raw HA
•iddle
distillate
blends
(light
gj fuel oils)
CO
Hydro- HA
treated
middle
distillates
(jet/dlesel/
other light
fuel oil)
Hydro- HA
treated
•Iddle
distillate
blends
(light
fuel oils)
D1FrlcU0n°n V«">r Temperature, 'f
Coal Type No. 5X Mt. off SOX wt. off 95* wt. off
Powhattan 7 419 428 456.8
"°- 5 8 476.6 485.6 519.8
8HC* 478.4* 482 485.6*
9 516.2 527 548.6
10 537.8 572 599
11 618.8 647.6 701.6
11HC* 638.6* 649.4 662*
_.
—
-. --
Specific Pour Molecular Sample
Gravity Point Weight Description/
60"F/60 F 'F (cryoscopic) Source Reference
0.9622 <-65.2 140 PDU P-99 110
0.9761 -45.4 154
0.9718 HA HA
0.9802 -29.2 HA
0.9972 -0.4 HA
1.0392 41 HA
1.0359 HA NA
—
._
Explanatory Hotes
'Heart cut fron secondary fractionalIon
*Full boiling range
-------
Table 301. Elemental Composition Data for Various Distillation Fractions
of Coal Raw Middle Distillates
Material
Coal TIM
•Iddle
distillates
Process Coal Type
SRC-11 PoMtuttan
No. 5
Coal rav
•Iddle
dlstniite
blends
(light
fuel oil)
Hydro-
treated
•tddle
distillates
(jet/dtesel/
other light
fuel oil)
Hydro-
treated
•Iddle
distillate
blends
(light
fuel oils)
NA
NA
NA
Distillation M», wt. Off
Fraction Temperature,
No.
9
10
11
Elemental Composition. Ht I (Dry Basis)
C H N 0 S
Sample Description/Source Reference
110
428
485.6
527
572
647.6
84.61
86.12
87.35
88.33
88.84
9.35
9.25
9.64
8.96
8.13
0.72
1.17
0.85
0.76
1.10
5.19
3.15
1.95
1.78
1.59
0.13
0.31
0.21
0.17
0.34
POU P-99
-------
Table 302. General Physical and Chemical Properties of Secondary Coal-Derived
Middle Distillates and Jet/Diesel Fuels
Value
Material
Middle
distillate
from hydro-
treated
whole coal
liquid
SRC-II
O
O
Coal Type
KY No. 9
and 14,
11 No. 6
(River
King
Mine)
and
Pitt-Seams
WV (Black-
vllle Ho.
2 Mine)
Parameter
Gravity. 'API
Aniline Point. 'F
Smoke Point, m
Freeze Point, 'F
TfiP Distillation. *F
(Simulated by Chronatography)
St/5
10/30
50
70/90
95/99
ASTN 0 86 Distillation, *F
St/5
10/30
50
70/90
9S/EP
% Overhead
Viscosity
cSt at -40'F
cSt at -4*F
cSt at 100'F
Density at 70'C
Molecular Weight
Refractive Index at 80*C
Existent Gum. ppn
Flash Point. D 56, *F
Neutralization No. (acid).
"3/9
Period 1*
34.6
122.3
22
<-94
266/304
316/365
404
451/504
520/560
342/357
363/380
399
427/472
488/531
99
12.79
MA
NA
0.8130
155
1.4362
NA
132
0.019
Period 2*
28.5
60.3
11
-76
264/313
332/382
419
460/510
526/550
340/358
366/389
412
440/478
494/531
99
13.17
NA
1.591
0.8443
154
1.4611
NA
142
0.034
Period 3*
27.3
41.8
11 '
-76
NA
NA
NA
NA
NA
346/353
358/394
415
441/478
491/516
99
NA
NA
NA
0.8507
152
1.4668
NA
142
0.05
Period 4*
33.3
110.2
20
-81
277/312
329/373
403
442/497
516/542
344/356
362/378
398
425/474
495/533
99
11.92
NA
1.640
0.8182
146
1.4407
0
134
0.05
(Continued)
Ft. Lewis pilot plant;
300-550'F product from
hydrotreating of SRC-II
whole coal liquid with
ICR 106 catalyst; Run No.
76-165. Operating
conditions: Period 1.
Run Hours 251-275. 750'F
catalyst temperature 0.55
LHSV, 2300 psla H2;
Period 2. Run Hours
539-563. 750*F catalyst
temperature, 1.51 LHSV.
2300 psia H?; Period 3.
Run Hours 2339-2351.
768*F catalyst tempera-
ture, 1.52 LHSV, 2300
psla H?; Period 4, Run
Hours 2709-2733, 776'F
catalyst temperature,
0.49 LHSV. 2300 psla
"2-
B6
-------
Table 302 (Continued)
Mater 1*1
Middle
distillate
froa hydro-
treated
whole co*l
liquid
Coal-derived
Jet fuel
froa hydro-
treated
whole coal
liquid
Process Coal Type
SRC- II KY Ho. 9
and 14.
IL No. 6
(diver
King
Mine) and
Pitt-Sean*
UV (fllack-
ville No.
Z Mine)
SRC-II KY No. 9
and 14,
IL No. 6
(River
King
Mine) and
Pitt-Seams
MV (Buck.
ville No.
2 Mine)
Chevron Sample No.
Gravity. 'API
Aniline Point, 'f
Saoke Point. MI
Freeze Point. *F
TBP Distillation
(Simulated by Chroaatography)
St/5
10/30
50
70/90
9S/99
ASTM 0 86 Distillation, 'f
St/S
10/30
SO
70/90
95/EP
X Overhead
Viscosity
At -40*F. cSt
At 130*F, cSt
API Gravity
Aniline Point. *F
Saoke Point, «•
Pour Point, 'F
TBP Distillation
(Simulated by Chroaatography)
IBP/5
10/30
50
70/90
95/99
ASTM 0 86 Distillation
IBP/5
10/30
50
70/90
95/EP
Value
SGQ 6547
27.5
48. 4
11
-71
222/305
328/386
423
462/509
525/549
360/365
368/380
402
434/474
482/520
98.5
12.59
1.219
Period 1*
32.0
69.2
13
-79
32/235'F
295/364*F
405 -F
442/493'F
515/551'F
212/278
312/364
392
420/464
483/510
SGQ 6581
26.5
33.3
9
NA
242/309
332/393
429
467/516
533/554
340/358
368/395
420
444/483
498/530
98.5
NA
1.229
Period 2* Period 3*
33.4 38.7
78.0 93.2
15 17
-76 -81
85/232*F 38/140'F
286/360'F 174/296*F
401*F 355*F
437/489'F 408/474*F
510/552'F 499/552'F
NA NA
NA NA
NA NA
NA NA
NA NA
SGQ 6588
24.6
<22
8
NA
239/312
335/399
429
464/509
525/549
NA
16.12
1.250
Period 4*
40.3
93.5
17
-83
37/99'F
168/286
348'F
402/467
494/547
NA
NA
NA
NA
NA
•F
•F
"f
Sample Description/Source Reference
Ft. Lewis pilot plant;
300-550'F product from
partial hydrotreatlng
of SRC-II whole coal
liquid
86
Ft. Lewis pilot plant;
fro* hydrofinishlng of
Chevron Sample No. SGQ
6547 (300-550'F produuct
froa partial hydrotreat-
Ing of SRC-II whole coal
liquid) with ICR 113
catalyst. Operating
conditions for Periods 1
through 4, respectively:
Run Hours, 402-414
426-438. 4SO-462. 462-486,
average catalyst tempera-
ture. *F. 701. 700, 750.
751; LHSV. 2.03, 1.02,
1.00, 1.01; total pressure
pstg, 1350, 1346. 1703,
1700; H? mean pressure,
psla, 1215. 1209. 1521.
1518.
86
(Continued)
-------
Table 302 (Continued)
Value
Coal-derived
jet fuel
from hydro-
treated
whole coal
liquid
SRC-11
o
ro
Coal Type
KY No. 9
and 14.
IL No. 6
(River
King
Nine) and
Pitt-Seams
UV (Black-
vtlle No.
2 Mine)
Parameter
API Gravity
Aniline Point, 'f
Snoke Point, m
Freeze Point, 'f
TBP Distillation
(Simulated by Chromatography)
IBP/5
10/30
SO
70/90
95/99
Period 1*
33.9
74.3
12
-76
42/169*F
221/323'F
37B*F
432/495'F
518/567*F
Period 2*
29.9
62.4
12
-66
45/285*F
318/373*
409*F
448/500*
520/554*
F
F
F
Period 3*
30.4
66.8
12
-67
46/281 *F
316/371*
408*F
446/499*
520/554*
F
F
F
Period 4*
31.4
69.3
12
-76
30/258*F
306/367*F
406*F
444/496*F
518/S55*F
Period 5*
34.1
79.7
13
-81
19/208*F
277/353*
392 *F
428/485*
509/530*
F
F
F
Period 1* Period 2* Period 3* Period 4« Period 5* Period 6*
KY No. 9 API Gravity 39.4
and 14. Aniline Point. *F NA
IL No. 6 Saoke Point, m 24
(River Freeze Point. *F -81
King
Mine) TBP Distillation
and (Simulated by
39.3
122.2
23
-90
36.5
110.9
22
-84
34.1
102.0
17
-77
32.5
86.2
14
-74
33.1
84.4
14
-72
Pitt-Seams Chromatography)
UV (Black-
vllle No.
2 Nine)
IBP/5
10/30
50
70/90
95/99
50/192*F
248/340*F
376*F
406/462*F
486/530'F
30/200*F
261/344*F
376*F
407/465*F
490/536*F
31/228*F
291/358*F
388 'F
419/476*F
500/546 *F
45/270*F
309/367 *F
396*F
432/488*F
508/552*F
42/272*F
310/368*F
402*F
439/491*F
512/556*F
28/233*F
293/361*F
395*F
431/489*F
509/556'F
Ft. I
from
Chevi
6581
from
Ing {
llqu
cata
cond
throi
Run 1
140-1
212-1
tempt
727.
1.02,
1.91
Ft. Lewis pilot plant; 86
from hydrofinishlng of
Chevron Sample No. SGQ
6547 (300-550'F product
from partial hydrotreat-
Ing of SRC-II whole coal
liquid) with ICR 113
catalyst. Operating
conditions for Periods 1
through 5 respectively:
Run Hours, 498-510.
522-524. 546-558. 570-582.
594-606; average catalyst
temperature, *F, 750,
701. 725. 750. 775; LHSV.
1.00, 0.99. 1.03, 1.07,
0.98; total pressure
pslg. 1713. 2096,
2099, 2050. 2099; H?
me in pressure psig, 1535,
1912. 1887. 1834, 1874.
Ft. Lewis pilot plant; 86
from hydrofInlshing of
ample No. SGQ
6581 (300-550*F product
from partial hydrotreat-
Ing of SRC-II whole coal
liquid) with ICR 106
Operating
conditions for Periods 1
through 6, respectively:
Run Hours 92-104. 104-128.
140-152. 164-176, 188-200.
212-224; average catalyst
nature, *F. 724, 727.
704, 704, 728; LHSV.
1.00, 2.00, 1.99.
2.00; total pressure
1699. 1697, 1696,
1694. 1379. 1399; H2
mean pressure, psig,
1528, 1528, 1527. 1535.
1250, 1251.
(Continued)
-------
Table 302 (Concluded)
Material Process Coal Type
Value
Coal -derived SRC-II
jet fuel
from hydro-
treated
whole coal
liquid
Explanatory Notes
Pitt-Seams
WV
(Black-
ville No.
2 Mine)
API Gravity
Aniline Point, "F
Copper Strip
Corrosion
Smoke Point, mm
Freeze Point, "F
Existent Gum, ppm
Thermal Stability
36.3
>100
No. 1
22
-75
2
No. 1
Sample Description/Source Reference
From single stage hydro- 88
treating of SRC-II
syncrude using ICR-113
catalyst, operating
conditions: catalyst
temperature, 750°F, LHSV,
0.5, H2 partial pres-
sure, 2306 psig.
*Each period refers to a run time having a characteristic set of operating conditions.
o
CO
-------
Table 303. General Physical and Chemical Properties of Jet/Diesel/Heating Fuels from
Various Distillation Cuts of H-Coal Syncrudes
Part A. Fron Severe Hydrotreatnent over Fresh ICR 106 Catalyst for Jet/Diesel Fuel Production (Reference 95)
O
-p.
Coal Type
Operating Conditions:
Catalyst Temperature
LHSV
Run (Hours)
Boiling Range, *F
Gravity. 'API
Aniline Point. *F
Refractive Index at ZO'C
Density at 20*C
Molecular Height
Snoke Point, ••
Cetane No.
Freeze Point. °F
Pour Point. *F
Cloud Point. *F
Flash (Tag Closed).
Flash (P-H). *F
Cu Strip Corrosion
Viscosity. cSt
At -4-F
At 100'F
Distillation. LV t.
St/5
10/30
50
70/90
95/EP
°f
IJllnol
750
0.5
76-171
250+
36.3
128.2
1.4584
0.8414
167
23
NA
-53
NA
HA
108
116*
1A*
*1-.C«»A
(222-246)
300
34.3
130.1
1.4631
0.8511
169
22
HA
-45
NA
-70*
133
HA
NA
Rerun
Illinois
H-Coal
748
t.S
76-173 (463-473)
350+ 250+
32.4 37.8
132.2 121.8
1.4677
0.8509
185
21 21
42.5* NA
-41 -51
-60* HA
-50* HA
NA NA
HA NA
1A* NA
6.478
1.678
7.434
1.898
0 86 TBP*
298/316 286/311
330/367 430/370
402 407
443/511 468/559
S44/589 612/756
9.860
2.206|
TBP*
314/355
365/394
434
482/547
584/666
4.707
1.523
TBP*
211/257
273/338
382
428/496
519/575
Uyodak H-Coal
752
1.0
76-173 (331-355)
250+
39.7
131.7
1.4517*
0.8252*
154*
21
HA
-31
-60
NA
NA
NA
1A*
4.549
1.441
D 86
295/313
320/344
378
420/490
526/594
300+
37.3
350+
35.4
134.0 137.5
NA
NA
NA
21
NA
HA
-60
-20
HA
NA
HA
6.153
1.701
D 86
344/352
358/380
400
433/499
532/602
HA
HA
HA
HA
HA
NA
NA
HA
HA
NA
NA
8.184
1.999
TBP*
313/352
362/388
418
463/527
571/677
(Continued)
-------
Table 303 (Continued)
Part B. From Severe Hydrotreatment over Aged ICR 106 Catalyst for Jet/Diesel Fuel Production (Reference 95)
Coal Type
Operating Conditions:
Catalyst Temperature
LHSV
Run (Hours)
Boiling Range, °F
Gravity, °API
Aniline Point, °F
Refractive Index at 20°C
Density at 20°C
Molecular Weight
Smoke Point, mm
Cetane No.
Freeze Point, °F
Pour Point, °F
Cloud Point, °F
Cu Strip Corrosion
Viscosity, cSt
At -4°F
At 100°F
Distillation, LV %, °F
St/5
10/30
50
70/90
95/EP
Illinois
774
0.5
76-171
H-Coal
(3191-3215)
250+
34.5
116.8
1.4646
0.8487
157
19
39. 3t
<-94
NA
NA
NA
5.656
1.665
D 86
291/312
326/361
404
450/526
581/596
350+t
29.1
109.8
NA
NA
NA
NA
37.7
NA
NA
-54
1A
D 86
400/400
400/417
440
492/551
600/646
Rerun
Illinois
H-Coal
802
1.5
76-174
(364-376)
250+
38.7
117.4
NA
NA
NA
19
35.8
-68
<-80
NA
NA
4.375
1.570
D 86
296/313
318/348
379
415/471
496/530
Wyodak H-Coal
802
1.0
76-174
Rerun
(208-232)
250-260
38.0
115.2
NA
NA
NA
19
NA
-61
<-80
-80
NA
4.186
1.352
D 86
298/300
318/342
377
420/476
500/546
250+t
39.4
111.7
1.4591
0.8327
155
18
NA
-27
<-80
+10
IB
NA
1.342
D 86
287/305
313/340
374
417/482
518/591
250+
39.3
118.4
NA
NA
NA
20
NA
<-94
NA
NA
NA
4.019
1.310
NA
Wyodak H-Coal
803
1.5
76-174
(604-616)
300+
37.2
120.3
NA
NA
NA
NA
NA
NA
<-80
<-80
NA
5.169
1.536
NA
350+
35.3
122.1
NA
NA
NA
NA
NA
NA
NA
NA
NA
6.770
1.780
TBP*
313/348
358/385
411
449/505
532/589
(Continued)
-------
Part C.
Table 303 (Continued)
From Moderate Hydrotreatment over Fresh ICR-106 and
113 Catalysts for Heating Fuels Production
(Reference 95)
Coal Type/Catalyst
Operating Conditions:
Catalyst Temperature, °F
LHSV
Run (Hours)
Boiling Range, °F
Gravity, °API
Aniline Point, °F
Refractive Index at 20°C
Density at 20°C
Cloud Point, °F
Pour Point, °F
Freeze Point, °F
Flash Point (P-M), °F
Cu Strip Corrosion
Viscosity at 1000°F, cSt
D-86 Distillation, LV %, °F
St/5
10/30
50
70/90
95/EP
Illinois H-Coal/ICR 106
775
1.5
(1967-1991)
250+
27.7
49.2
NA
NA
-50
NA
NA
116
1A
1.646
311/324
339/381
430
483/560
601/664
300+
25.4
46.0
NA
NA
-38
NA
NA
148
NA
1.969
360/366
376/400
441
487/562
605/685
350+
23.0
40.8
1.5105
0.9157
-58
NA
NA
176
NA
2.294
397/413
418/439
466
508/586
642/667
Wyodak
H-Coal/
ICR 113
747
1.5
(1366-1390)
250+
32.7
72.3
NA
0.8656
+20
-45
+19
114
1A
1.500
299/316
325/357
401
448/527
573/659
(Continued)
706
-------
Table 303 (Concluded)
Part 0. From Moderate Hydrotreatment over Fresh ICR 106 Catalyst for Fuel Oil Production (Reference 95)
Operating Condtttons 2500 pslg 2000 pslg 2000 pslg
Run (Hours)
Catalyst leaf-. *f
LHSV
Total Pressure, pslg
H2 Pressure, psla
BoUlng Range. *F
Gravity. 'API
Aniline Point. *F
Refractive Index, 20*C
Density. 20*C
Molecular Height
Cloud Point. *F
Pour Point. *F
Freeze Point. *F
Saoke Point, tm
Flash Point (P-M). *F
Cu Strip Corrosion
Viscosity. cSt
at -4'f
at 100'F
Distillation. LV S. *F
St/S
10/30
50
70/90
95/EP
76-171 (654-678)
750
1.5
2493
250+
28.1
51.4
1.4599
0.8455
170
NA
<-80
<-94
7
112
NA
12.67
1.767
D 86
294/315
334/380
429
477/562
593/675
2231
300+
25.8
46.0
1.5026
0.9029
165
NA
-65
<-94
8
142
NA
21.64
2.085
0 86
342/362
373/407
445
492/568
618/662
350*
23.6
42.8
1.5096
0.9151
173
HA
-55
-80
7
152
NA
NA
2.308
TBP*
325/364
377/422
466
518/603
654/755
76-171 (1535-1559)
750
1.5
2001
250+
26.8
45.1
1.4968
0.8920
162
NA
<-80
NA
9
104
NA
NA
NA
D 86
290/310
328/374
426
478/573
NA
1778
300*
24.6
39.8
NA
NA
NA
<-80
NA
10
130
NA
NA
NA
0 86
340/352
360/400
441
489/574
NA
350*
22.2
33.3
1.5130
0.9136
171
NA
-70
NA
9
165
NA
30.06
2.448
0 86
380/393
403/429
458
502/580
NA
76-171 (1967-1991)
775
1.5
2073
250*
27.7
49.2
NA
NA
-50
NA
NA
NA
116
1A
NA
NA
D 86
311/324
339/381
430
483/560
601/664
1859
300*
25.4
46.0
NA
NA
-38
NA
NA
NA
148
NA
NA
NA
0 86
360/366
376/400
441
487/562
605/685
350*
23.0
40.8
1.5105
0.9157
190
-58
NA
NA
NA
176
NA
NA
NA
D 86
397/413
418/439
466
508/586
642/667
Explanatory Notes
•Simulated by chromatography.
^Measured at other hours but at these conditions.
-------
Table 304. Elemental Composition of Secondary Coal-Derived Middle Distillates
and Jet/Diesel Fuels
Value (wt %)
Material Process Coal Type Parameter Period 1* Period 2* Period 3* Period 4* Sample Description/Source Reference
Middle
distillate
from hydro-
treated
whole coal
liquids
SRC-11 KY No. 9 Nitrogen
and 14,
IL No. 6
(River
King
Hlne) and
Pitt-Seams
WV (Black-
vt11e No.
2 Mine)
Oxygen
HA
NA
.0019
.0970
NA
.14
NA
NA
O
00
Coal-
derived
jet fuel
fron
hydro-
treated
whole
coal
liquid
Chevron Sample No.
Sulfur, ppa
Total Nitrogen
Basic Nitrogen
Oxygen
Hydrogen (wt I)
SRC- 1 1 KY No. 9 Sulfur
and 14.
IL No. 6 Nitrogen
(River
King Oxygen
Mine) and
Pitt-Seams
WV (Black-
vine No.
2 Mine)
SGQ 6547 SGQ6581 SGQ6588
NA .00029 .00074
.0012 .0173 .0838
NA .0185 NA
.0600 .2400 .07400
NA .001141 HA
0.00018 NA NA NA
0.000028 0.000022 0.000019 0.000021
0.0110 0.0090 0.0090 0.0170
ft. Lewis pilot plant; 86
300-550°F product from
hydrotreatlng of SRC-II
whole coal liquid with
ICR 106 catalyst; Run
No. 76-165. Operating
conditions: Period 1.
Run Hours 251-275. 750'F
catalyst temperature.
0.55 LHSV. 2300 psU
H2; Period 2. Run
Hours 639-663. 750°F
catalyst temperature.
1.51 LHSV, 2300 psla
H2; Period 3, Run
Hours 2339-2351. 768*F
catalyst temperature,
1.52 LHSV. 2300 psla
H2; Period 4, Run
Hours 2709-2733. 776"F
catalyst temperature,
0.49 LHSV. 2300 psla
H;,.
Ft. Lewis pilot plant; 86
300-550'F product from
partial hydrotreatlng of
SRC-11 whole coal
liquid
Ft. Lewis pilot plant; 86
fron hydroflnlshlng of
Chevron Sample No. SGQ
6547 (300-550°F product
from partial hydrotreat-
lng of SRC-11 whole
coal liquid) With ICR
113 catalyst. Operating
conditions for Periods 1
through 4. respectively:
Run Hours, 402-414,
426-438. 4SO-462, 462-486;
average catalyst tempera-
ture, "F. LHSV. 2.03.
1.02, 1.00. 1.01; total
pressure psig, 1350,
1346, 1703. 1700; H2
mean pressure, psla.
1215, 1209. 1521, 1518.
-------
Table 304 (Concluded)
Value (wt t)
Material Process Coal Type Parameter Period 1* Period 2* Period 3* Period 4* Period 5* Sample Description/Source Reference
Coal-
derlved
jet fuel
from
hydro-
treated
whole
co«l
liquid
SRC-11
KY No. 9
and 14.
IL No. 6
(River
King
Htne)
and
Pitt-Seams
UV (Black-
vllle No.
2 Nine)
Nitrogen 0.000026 0.000020 0.000018 0.000035 NA Ft. Lewis pilot plant:
from hydrofInlshing of
Oxygen 0.0190 NA NA NA NA Chevron Sample No. SGQ
6547 (300-550'F product
from partial hydrotreatlng
of SRC-II whole coal
liquid) with ICR 113
catalyst. Operating
conditions for Periods 1
through 5 respectively:
Run Hours, 498-510,
522-524. 546-558. 570-582.
594-606; average catalyst
temperature. *F, 750,
701, 725. 750, 775; LHSV.
1.00, 0.99, 1.03, 1.07,
0.98; total pressure
pslg, 1713. 2096. 2099,
2050, 2099; HZ mean
pressure psig, 1535.
1912. 1887. 1834. 1874.
KY No. 9
«nd 14.
IL No. 6
(River
King
Mine)
and
Pitt-Seams
HV (Black-
vllle No.
2 Htne)
Period 1* Period 2* Period 3* Period 4* Period 5* Period 6*
Nitrogen 0.000014 0.000044 0.000015 0.000012 0.000016 0.000015
Ft. Lewis pilot plant;
from hydrofinishlng of
Chevron Sample No. SGQ
6581 (300-550'F product
from partial hydrotreatlng
of SRC-II whole coal
liquid) with ICR 106
catalyst. Operating
conditions for Periods 1
through 6 respectively:
Run Hours. 92-104.
104-128. 140-152,
164-176. 188-200. 212-224;
average catalyst tempera-
ture. 'F. 724. 727, 727.
704. 704. 728; LHSV.
1.02. 1.00, 2.00, 1.99,
1.91, 2.00; total pressure
pslg, 1699, 1697. 1696,
1694, 1379, 1399; H2
mean pressure psig, 1528,
1528. 1527, 1535. 1250.
1251.
Explanatory Note
•Each period refers to a run having a characteristic set of operating conditions.
86
86
-------
Table 305. Elemental Composition of Jet/Diesel/Heating Fuels From
Various Distillation Cuts of H-Coal Syncrudes
Part A.
Fran Severe Hydrotreate
(Reference 95)
ent over Fresh ICR 106 Catalyst for Jet/Diesel Fuel Production
Coal Type
Operating conditions:
Catalyst temperature, 'F
LHSV
Run (Hours)
Boiling Range, *F
Sulfur, wt X
Nitrogen, we J
Oxygen, wt J
Illinois H-Coal
750
0.5
76-171 (222-246)
250* 300+ 350*
.0008 .0006 .00045
NA NA NA
NA MA NA
Part B.
Fro* Severe Hydrotreatment over Aged ICR 106 Catalyst for Jet/01esel Fuel Production
(Reference 95)
Coal Type
Operating conditions:
Catalyst temperature,
LHSV
Run (Hours)
Boiling Range. *f
Sulfur, wt X
Hyodak
802
1.0
76-174 (208-232)
250-600 250*«
.000274 .00049
Rerun Myodafc
803
1.5
76-174 (604-616)
250+ 300* 350*
.000061 .000045 .000053
Part C.
From Moderate Hydrotreatment over Fresh ICR 106 and 113 Catalysts for Heating Fuels Production
(Reference 95)
Coal Type/catalyst
Operating conditions:
Catalyst temperature,
LHSV
Run (Hours)
Boiling Range. *F
Sulfur, wt t
Nitrogen, we X
Illinois
H-Coal/ICR 106
775
1.5
76-171 (1967-1991)
250* 300* 350*
NA NA NA
NA .0018 NA
Uyodak
H-CoalI/ICR IB
747
l.S
66-203 (1366-1390)
250*
.000076
.00066
Part 0. From Moderate Hydrotreament over Fresh ICR 106 Catalyst for Fuel 011 Production
(Reference 95)
Coal Type
Operating conditions:
Run (Hours)
Catalyst Temperature *F
LHSV
Total Pressure, pslg
Hj Pressure, psla
Bolting Range, °F
Sulfur, wt I
Oxygen, wt X
Nitrogen, we I
Explanatory Note;
2500 pslg
IU No. 6
76-171 (654-678)
750
1.5
2493
2231
250* 300* 350*
.00020 .00040 .00020
.0590 .0650 .0440
NA NA NA
2000 pslg
IL No. 6
76-171 (1535-1559)
750
1.5
2001
1773
250
.00016
.1400
NA
300
.00020
.1300
NA
350
NA
.1400
NA
2000 pslg
IL. No. 6
76-171 (1967-1991)
775
1.5
2073
1859
250
NA
NA
NA
300
NA
NA
NA
350
NA
NA
NA
•Measured at other hours but these conditions.
710
-------
Table 306. Hydrocarbon Compound Class Properties of Secondary Coal-Derived Middle Distillates
and Jet/Diesel Fuels
Value (IV I)
Material
Middle
distillate
tram hydro-
treated
whole co«l
liquids
Coal-
derlved
jet fuel
fro*
hydro-
treated
whole
coal
Itqutd
Process Coal Type Parameter Period 1*
SRC- 11 KV No. 9 Group
and 14. Type.
IL No. 6 Saturates 95.9
(River AroMttcs 4.0
King
Nine) and
Pltt-SeaM
HV (Black-
vllle No.
2 Hint)
Chevron Saople No. S6Q 6547
Group Typt,
Saturate! 44.1
AroMtlct 55.9
SRC- II KV No. 9 Group Type
and 14.
|L No. 6 Saturates 56.2
(River
King AroMttcs 43.8
Htne) and
PHt-Seans
UV (Black-
vDle No.
2 Mine)
Period 2* Period 3* Period 4* Sample Description/Source
Ft. Lewis pilot plant;
300-550'F product froa
51.1 41.0 85.0 hydrotreatlng of SRC-II
48.8 59.0 15.0 whole coal liquids with
ICR 106 catalyst; Run
No. 76-165. Operating
conditions: Period 1,
Run Hours 251-275. 750'F
catalyst temperature,
0.55 LHSV. 2300 psta
H2; Period 2. Run
Hours 539-563, 750°F
catalyst tenperature.
0.51 LHSV. 2300 psla
H2; Period 3. Run
Hours 2339-2351. 768'F
catalyst tenperature,
1.52 LHSV. 2300 psla
H2; Period 4. Run
Hours 2709-2733. 776'F
catalyst temper* ture.
0.49 LHSV. 2300 psla
H2.
SGQ6581 S6Q6588 Ft. Lewis pilot plant;
300-550'F product froa
36.7 31.2 partial hydrotreatlng of
63.3 68.8 SRC-II whole coal
liquid
Ft. Lewis pilot plant;
froa hydrof Inlshlng of
63.6* 70.2 70.3 Chevron Sanple No. SQG
6457 (300-550°F product
36.4 29.8 29.7 from partial hydrotreat-
lng of SRC-II whole
coal liquid) with ICR
113 catalyst. Operating
conditions for Periods 1
through 4, respectively:
Run Hours. 402-414,
426-438. 450-462. 462-486;
average catalyst tempera-
ture. °F, 701. 700. 750.
751; LHSV. 2.03. 1.02,
1.00. 1.01; total
pressure pslg, 1350,
1346, 1703, 1700; H2
mean pressure, psla,
1215, 1209, 1521, 1518.
Reference
86
86
86
(Continued)
-------
Table 306 (Concluded)
Value (tit t)
Material Process Coal TV
Parameter Period I*
Coal-
derived
jet fuel
from
hydro-
treated
whole
coal
liquid
SRC-11
ro
KY No. 9 Saturates 58.0
and 14,
IL No. 6 Aromatics 42.0
(River
King
Mine)
and
Pitt-Seams
WV (Black-
vllle No.
2 Mine)
Period 3* Period 4*
54.0
46.0
56.1
43.8
Period 5* Sample Description/Source Reference
61.5 Ft. Lewis pilot plant; 86
from hydrofInlshing of
38.5 Chevron Simple No. SGQ
6547 (300-550'f product
froa partial hydrotreattng
of SRC-11 whole coal
liquid) with ICR 113
catalyst. Operating
conditions for Periods 1
through 5 respectively:
Run Hours. 498-510,
522-524. 546-558. 570-582.
594-606; average catalyst
temperature, *F. 750,
701, 725, 750. 775; LHSV.
1.00, 0.99. 1.03, 1.07,
0.96; total pressure
pslg, 1713, 2096. 2099,
2050, 2099; H2 mean
pressure pslg, 1535,
1912. 1887, 1834. 1874.
Period 1* Period 2* Period 3* Period 4* Period 5* Period 6*
ICY No. 9 Saturates 94.3
and 14,
IL No. 6 Aroaatlcs 5.7
(River
King
Nine)
and
Pitt-Seams
WV (Slack-
vine No.
2 Hine)
94.1
5.9
86.4
13.6
79.9
20.1
67.9 65.9 Ft. Lewis pilot plant; 86
froa hydrofInlshing of
32.1 34.2 Chevron Sample No. SGQ
6581 (300-550'F product
from partial hydrotreatIng
of SRC-11 whole coal
liquid) with ICR 106
catalyst. Operating
conditions for Periods 1
through 6 respectively:
Run Hours, 92-104,
104-128. 140-152.
164-176, 188-200. 212-224;
average catalyst tempera-
ture. *F. 724. 727. 727.
704. 704, 728; LHSV,
1.02. 1.00. 2.00. 1.99.
1.91. 2.00; total pressure
pslg. 1699. 1697. 1696.
1694, 1397, 1399; H2
mean pressure, psig, 1528.
1528. 1527. 1535. 1250.
1251.
Explanatory Note
•Each period refers to a run having a characteristic set of operating conditions.
tQata may be questionable
-------
Table 307.
Hydrocarbon Compound Class Properties of Jet/Diesel/Heating
Fuels From Various Distillation Cuts of H-Coal Syncrudes
Part A. From Severe Hydrotreatment over Fresh ICR 106 Catalyst In Jet/Diesel Fuel Production
(Reference 95)
Coal Type
Operating condition:
Catalyst temperature, "F
LHSV
Run (Hours)
Soiling Range. 'F
Group Types by US, IV X
Saturates
Aromatics
Illinois H-Coal
750
0.5
76-171 (222-246)
250* 300* 350*
97.7
2.3
97.8
2.3
97.5
2.5
Rerun Illinois
H-Coal
748
1.5
76-176 (463-475)
250*
94.3
5.7
Wyodak H-Coal
752
1.0
76-173 (331-355)
250* 300* 350*
96.4 96.1 96.2
3.6 3.9 3.8
Part B. From Severe Hydrotreatment over Aged ICR 106 Catalyst for Jet/Ofesel fuel Production
(Reference 95)
Coal Type
Operating conditions:
Catalyst temperature, *F
LHSV
Run (Hours)
Boiling Range, *F
Group Types by MS, LV X
Saturates
Aronatics
Wyodak H-Coal
Rerun Wyodak
H-Coal
Illinois H-Coal
Rerun Illinois
H-Coal
302 803 774 302
1.0 1.5 0.5 1.5
76-174 (208-232) 76-174 (604-616) 76-171 (3193-32) 76-174 (364-376)
250-600 250** 250* 300* 350* 250* 350** 250*
80.6
19.4
76.3
23.7
85.8 85.4 76.1 39.1
14.2 14.6 23.9 10.9
81.5
18.5
34.5
15.6
Part C. Fran Moderate Hydrotreatment over Fresh ICR 106 and 113 Catalysts for Heating
Fuels Production (Reference 95)
Coal Type/Catalyst
Operating conditions:
Catalyst temperature, *F
LHSV
Run (Hours)
Boiling Range, *F
Group Types, LV X
Saturates
Aromatics
Illinois H-Coal/ICR 106
775
1.5
76-171 (1967-1991)
250* 300* 350*
46.5
53.5
43.9
56.0
41.4
58.6
Wyodak H-Coal/ICR 113
747
1.5
66-203 (1366-1390)
250*
50.8
49.2
Part 0. From Moderate Hydrotreatment over Fresh ICR 106 Catalyst for Fuel Oil Production
(Reference 95)
Coal Type
Operating conditions:
Run (Hours)
Catalyst temperature, "F
LHSV
Total Pressure, pslg
H? Pressure, psla
Boiling Range, *F
Group Types by MS, LV X
Saturates
Aromatics
^Measured at other hours but these conditions.
2500 pslg
IL
76-171
250*
42.6
57.4
. NO.
6
(654-678)
750
1.5
2493
2231
300+
40.6
59.4
350*
42. S
57.5
2000 pslg
IL,
76-171
250
46.9
53.1
. No. 6
(1535-1559)
750
1.5
2001
1773
300
43.3
56.6
350
40.0
60.0
2000 pslg
IL
76-171
250
46.5
53.5
. NO.
6
(1967-1991)
775
1.5
2073
1859
300
43.9
56.0
J50
41.4
53.5
713
-------
GENERAL COMMENTS
1. Additional data for SRC-I coal raw middle distillates (Reference 82):
(a) Wilsonville pilot plant SRC unit, Run No. 220, APCI Sample No.
1897CB: compatibility (via ASTM D-2781), 1; DuPont stability rate;
good/8+.
(b) Wilsonville pilot plant SRC unit, Run No. 225, APCI Sample No.
1911CB: compatibility (via ASTM 0-2781), 1; OuPont stability rating,
good/8+.
(c) Middle distillate from the Lummus LC-Finer unit for the Wilsonville
pilot plant, Lummus Run No. 2-LC Finer-29, APCI Sample No. 1941CB-1:
compatibility (via ASTM D-2781), 1; DuPont stability rating, fair/8.
(d) Middle distillate from the Lummus LC-Finer unit for the Wilsonville
pilot plant, Lummus Run No. 2-LC Finer-27, APCI Sample No. 1949CB:
compatibility (via ASTM D-2781), 1; DuPont stability rating, good/5.
2. Surface tension of SRC-II middle distillate from Ft. Lewis pilot plant
was 33.3 dynes/cm at 60°F (Reference 102).
3. Data cited for Reference 97 for H-coal naphtha derived from PDU atmospheric
and vacuum still overhead streams are for the following operating condi-
tions: 2.245 psig at the reactor outlet and 850°F reactor temperatures.
In the fuel oil mode of operation, a coal feed rate of 62.4 lbs/hr/ft3
reactor with hot separator reactor slurry recycle of 1.045 Ibs/lb coal
and a distillate recycle of 1.40 Ibs/lb coal yielded a feed slurry
containing 29.03 weight-percent coal. The blend of material produced by
the reactor operation consisted of 27.9 weight-percent overhead produce
(distillate) and 72.1 weight-percent vacuum bottoms product. In the
syncrude mode of operation, a coal feed rate of 31.2 lbs/hr/ft3 reactor
with a hot separator reactor slurry recycle of 3.98 Ibs/lb coal and a
distillate recycle of 0.40 Ibs/lb coal yielded a feed slurry containing
20.08 weight-percent coal. The blend of material produced by the reactor
in the syncrude mode of operation consisted of 48.2 weight-percent
overhead product and 51.8 weight-percent vacuum bottoms product. The
amount of reacted hydrogen in the fuel oil and the syncrude mode of
operation were determined to be 12.2 and 15.2 Mscf/ton coal, respectively.
The catalyst used in both processes was American Cyanamid HDS-2A.
4. Summary of operating conditions for H-Coal PDU Run 5, Run 130-82, Period 29
using IL No. 6 coal (catalyst-American Cyanamid HDS-1442A, 1/16-in.
evenudates, HRI 3830, 96.7 Ibs dry initial charge, reactor liquid phase
depth 19 feet, volume 7.49ft3), as follows (Reference 111):
714
-------
Period 29
Date, End of Period (1977) 10/3
Hours of Run - Beginning 669
End 693
Catalyst Inventory, Beginning, Lbs 100.8
Catalyst Added 3.75
Catalyst Withdrawn 4.26
Catalyst Age (End), Lbs Dry Coal/lb Catalyst
Average* 1102
Original Charge"1" 1645
Catalyst Added, Cumulative, Lbs/Ton Dry Coal 1.06
Coal Feed (Dry), Lbs/Hr/Ft3 Reactor Volume 31.56
Moisture, W % 3.04
Ash, % (Dry Basis) 10.85
Recycle Flows, Lbsfib Solids
Atmospheric Still Bottoms 0.552
Vacuum Still Overhead 0.000
Inventory Change -0.005
Hydroclone Overflow (Oil) 1.041
Make-Up Oil 0.000
Total 1.598
Temperature, °F
Coal Preheater Outlet 741
Reactor Liquid Phase - Average 851
Maximum 861
Separator 801
Hydroclone 532
Vacuum Still Flash Zone 539
Pressure in Vacuum Flash, Torr 2.0
Pressure, psig
Unit Back Pressure 2700
Hydrogen Make-Up 2950
Hydrogen Partial Pressure
(Reactor Outlet) 1920
Recycle Gas, MSCF/Ton Dry Coal 39.9
Vent Gas, MSCF/Ton Dry Coal 7.85
Hydrogen Purity of Recycle Gas & Vent, % 85.7
Total Hydrogen, MSCF/Ton Dry Coal
(Reactor outlet) 42.4
715
-------
Make-Up Hydrogen + Recycle Hydrogen
MSCF/Ton Dry Coal 62.0
V % of Make-Up & Recycle Gas 91.6
Hydrogen Partial Pressure, psig 2720
Hydrogen Consumption^
MSCF/Ton Dry Coal 19.6
W % Dry Coal 5.19
Oil Additions
Make-Up Oil - Lbs/Lb Dry Coal 0.000
Lbs/H-XFt3 Reactor 0.000
Flush Oil, Lbs/Lb Dry Coal 0.0033
*Average age weighted by proportions of catalyst of various ages in bed
"''Age of portion of original catalyst remaining in bed
fOrifice for fresh hydrogen, meter for product gases with analysis
5. Summary of operating conditions for H-Coal PDU Run 6, Run 130-83, Period
17, using Wyodak coal (Catalyst-American Cyanamid HDS-1442A, 1/16-in.
extrudates, HRI 3830, reactor liquid phase depth 19 feet, volume 7.49
ft3), as follows (Reference 112):
Period 17
Date, End of Period (1977) 11/30
Hours of Run - Beginning 377
End 400
Catalyst Inventory, Beginning, Lbs 95.90
Catalyst Added 4.88
Catalyst Withdrawn 0.0
Catalyst Age (End), Lbs Dry Coal/Lb Catalyst
Average* , 669
Original Charge''' 849
Catalyst Added, Cumulative, Lbs/Ton Dry Coal 1.08
Coal Feed (Dry), Lbs/Hr/Ft3 Reactor Volume 30.1
Moisture, W % 18.19
Ash, % (Dry Basis) 9.33
Recycle Flows, Lbs/Lb Solids
Atmospheric Still Bottoms 0.990
Vacuum Still Overhead 0.024
Inventory Change 0.026
Hydroclone Overflow (Oil) 0.568
Make-Up Oil 0.000
Total 1.556
716
-------
Temperature, °F
Coal Preheater Outlet 615
Reactor Liquid Phase - Average 838
Maximum 852
Separator 797
Hydroclone Overflow 544
Vacuum Still Flash Zone 497
Pressure in Vacuum Flash, Torr 25
Pressure, psig
Unit Back Pressure 2805
Hydrogen Make-Up 2905
Hydrogen Partial Pressure
(Reactor Outlet) 1620
Recycle Gas, MSCF/Ton Dry Coal 33.48
Vent Gas, MSCF/Ton Dry Coal 8.86
Hydrogen Purity of Recycle Gas & Vent, % 83.8
Total Hydrogen, MSCF/Ton Dry Coal
(Reactor outlet) 37.33
Make-Up Hydrogen + Recycle Hydrogen
MSCF/Ton Dry Coal 62.19
V % of Make-Up & Recycle Gas 91.98
Hydrogen Partial Pressure, psig 2690
Hydrogen Consumption!
MSCF/Ton Dry Coal 24.87
W % Dry Coal 6.60
Oil Additions
Make-Up Oil - Lbs/Lb Dry Coal 0.000
Lbs/H-XFt3 Reactor 0.000
Hush Oil, Lbs/Lb Dry Coal 0.0036
*Average age weighted by proportions of catalyst of various ages in bed
"''Age of portion of original catalyst remaining in bed
fOrifice for fresh hydrogen, meter for product gases with analysis
6. Data cited for Reference 88 for SRC-II single-stage hydrotreated <554°F
distillate were obtained under the following operating conditions:
Catalyst ICR-113
Catalyst temperature 750°F
Hydrogen partial pressure 2306 psig
LHSV 0.5
Recycle gas rate 13,752 SCF/bbl
717
-------
7. Data cited for Reference 88 for H-Coal single-stage hydrotreated <544°F
distillate were obtained under the following operating conditions:
IL No. 6 Coal
Catalyst ICR-113
Catalyst temperature 750°F
Hydrogen partial pressure 2232 psig
LHSV 0.5
Recycle gas rate 7,921 SCF/bbl
Wyodak Coal
Catalyst ICR-113
Catalyst temperature 752°F
Hydrogen partial pressure 2257 psig
LHSV 1.0
Recycle gas rate 7,743 SCF/bbl
8. The following additional data provided for SRC-II medium and heavy distillate
blends (Reference 115):
Before water wash After water wash
Chevron Sample No. SGQ-7559 WOW-4551
H/C Ratio 1.24 1.22
N/C Ratio x 103 8.7 8.9
S/C Ratio x 103 1.11 L.13
0/C Ratio x 103 28.6 41.9
718
-------
Part X. Raw and Hydrotreated Heavy Distillates (Heavy Fuel Oils) and Residua
719
-------
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Table 308. Specific Gravity
Process Coal Type Value Sample Description/Source Reference
SRC-1
KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
NA
1.0921*
1.1085'
1.0404*
1.0736*
1.219
KY No. 9 1.221
1.213
0.985
(450°F/
60°F)
(Continued)
Wilsonville pilot plant, 82
heavy distillate from
SRC unit (Run No. 220,
APCI Sample No. 1898CB)1"
Wilsonville pilot plant, 82
heavy distillate from
SRC unit (Run No. 225,
APCI Sample No. 1912CB)1"
Wilsonville pilot plant, 82
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1942CB-1)1"
Wilsonville pilot plant, 82
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1950CB)+
Wilsonville pilot plant, 116
heavy SRC (Run No. 225,
APCI Sample No. 1914CB)
Wilsonville pilot plant, 116
heavy SRC (Run No. 220,
APCI Sample No. 1916CB)
Wilsonville pilot plant, 116
heavy SRC (Run No. 209,
APCI Sample No. 1917CB)
Wilsonville pilot plant, 120
heavy SRC (Catalytic Inc.
Sample No. SN-2651, Run
No. 6, Drum No. 120,
Babcock & Wilcox Sample
No. C-13994)
720
-------
Table 308 (Continued)
Material
Process Coal Type Value Sample Description/Source Reference
Coal raw SRC-I
heavy
distillates
(heavy
fuel oils)
and
residua
NA
KY No. 9
and 14
1.005
(450'F/
60'F)
1.24
Wilsonville pilot plant,
heavy SRC (Catalytic Inc.
Sample No. SN-2651, Run
No. 7D, Drum No. 97,
Babcock & Wilcox Sample
No. C-13995)
Ft. Lewis pilot plant,
heavy SRC
120
83
EDS
IL No. 6
IL No. 6
Wyodak
Wyodak
IL No. 6
IL No. 6
IL No. 6
IL No. 6
IL No. 6
1.0100 One tpd pilot plant,
(60/60°F) 350 to 1000'F distillate
blend from "typical" run
1.0800 One tpd pilot plant,
(60/60'F) 350°F+ distillate bl
from "typical" run
end
1.0306 One tpd pilot plant,
(60/60'F) 350 to 1000'F distillate
blend from "typical" run
1.1370
(60/60°F)
1.0397
1.0435
IL N,o. 6 1.0752
1.0173
1.0143
1.0173
One tpd pilot plant,
350°F+ distillate
blend from "typical" run
One tpd pilot plant,
heavy distil late*
One tpd pilot plant,
heavy distil later
One tpd pilot plant,
heavy distillate*
One tpd pilot plant,
heavy distillate, UOP
Sample No. 3532-lf
One tpd pilot plant,
heavy distillate, UOP
Sample No. 3532-2*
One tpd pilot plant,
heavy distillate, UOP
Sample No. 3523-3*
(Continued)
721
99
99
99
99
99
99
99
99
99
99
-------
Material
Table 308 (Continued)
Process Coal Type Value Sample Description/Source Reference
Coal raw EDS
heavy
distillates
(heavy
fuel oils)
and
residua
H-Coal
Wyodak
Wyodak
Wyodak
IL No. 6
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
(Mine)
Wyodak
Wyodak
Wyodak
IL No. 6
1.0321
1.1195
1.1320
1.3717
(60/60°F)
1.47+
0.12
(60/60°F)
1.37+
0.05"
(60/60°F)
1.3849
(60/60°F)
1.38+
0.04
(60/60°F)
1.40+
0.05
(60/60°F)
1.0932+
(77°F)
One tpd pilot plant,
heavy distillate*
One tpd pilot plant,
heavy distillate**
One tpd pilot plant,
heavy distillate**
One tpd pilot plant,
vacuum bottoms from
"typical" run (Run A-l)
One tpd pilot plant,
vacuum bottoms, average
of three operating condi-
tions (840°F reactor
temperature, 15-40 minues
residence time)
One tpd pilot plant,
vacuum bottoms; operat-
ing conditions: 840°F
reactor temperature;
40 minutes residence
time, average of ten
yield periods
One tpd pilot plant,
vacuum bottoms from
"typical" run (Run A-l)
One tpd pilot plant,
vacuum bottoms, average
of six operating condi-
tions (800-840°F
reactor temperature,
40-100 minutes residence
time)
One tpd pilot plant,
vacuum bottoms; operat-
ing conditions: 840°F
reactor temperature, 60
minutes residence time,
average of seven yield
periods
Heavy distillate from
PDU Run 8, syn crude mode
99
99
99
99
99
99
99
99
99
109
(Continued)
722
-------
Material
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and
residua
Table 308 (Continued)
Process Coal Type Value Sample Description/Source Reference
SRC-1
KY No. 9 1.184
KY No. 9 1.217
KY No. 9 1.175
KY No. 9 1.189
EDS
IL No. 6
0.9522
IL No. 6
0.9129
Wilsonville pilot plant, 116
two-stage liquefaction
(TSL) SRC from low con-
version operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1943CB)
Wilsonville pilot plant, 116
two-stage liquefaction
(TSL) SRC from high con-
version operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1951CB)
Wilsonville pilot plant, 117
two-stage liquefaction
(TSL) SRC from low con-
version operation of SRC
hydrocracker (H-Oil) unit
(Wilsonville Run No. 235,
APCI Sample No. 1983CB)
Wilsonville pilot plant, 117
two-stage liquefaction
(TSL) SRC from high con-
version operation of SRC
hydrocracker (H-Oil) unit
(Wilsonville Run No. 235,
APCI Sample No. 1991CB)
From first stage hydro- 99
cracking of UOP raw 400°F+
heavy distillate, Sample
No. 3532-3f
(UOP Sample No. 3532-9)?
From first stage hydro- 99
cracking of UOP raw 400°F+
heavy distillate Sample
No. 3532-2f (UOP
Sample No. 3532-4)f
(Continued)
723
-------
Material
Hydro- EDS
treated
heavy
distillates
(heavy
fuel oils)
and
residua
Explanatory Notes
Table 308 (Concluded)
Process Coal Type Value Sample Description/Source Reference
IL No. 6 0.8044 From second stage hydro- 99
cracking of UOP hydro-
cracked Sample No. 3532-4
(UOP Sample No. 3532-17)
IL No. 6 0.7981 From second stage hydro- 99
cracking of UOP hydro-
cracked Sample No. 3532-4
(UOP Sample No. 3532-18)
determined via ASTM D-1298.
"''The raw heavy distillate from the proposed SRC-1 pilot plant will con-
sist of a 29.0/71.0/0.0 weight percent blend of heavy distillates from
the SRC, LC-Finer and coker units, respectively (Reference 100).
fA blend of raw naphtha, vacuum gas oil, and raw process solvent
having a nominal boiling point of 400-1000°F.
§A blend of vacuum gas oil, raw process solvent and coker liquid
having a nominal boiling point of 400°F+.
#A full range (350 to 1000°F) distillate consisting of a blend of raw
naphtha, vacuum gas oil and raw process solvent.
**A blend of raw naphtha, vacuum gas oil, raw process solvent and coker
liquid having a nominal boiling point of 350°F+.
^Determined via ASTM D-70.
724
-------
Table 309. API Gravity
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
Value
(degrees)
Sample Description/Source Reference
SRC-I KY No. 9 -2.0*
KY No. 9 -4.1*
KY No. 9 4.5*
KY No. 9 0.3*
NA
-22.0
Kentucky -18
SRC-II Pittsburgh 1.3
No. 8
(Powhattan
Mine)
NA
0.2
NA 0.9
Kentucky +3/+6
Wilsonville pilot plant,
heavy distillate from SRC
unit (Run No. 220, APCI
Sample No. 1898CB)t
Wilsonville pilot plant,
heavy distillate from SRC
unit (Run No. 225, APCI
Sample No. 1912CB)t
Wilsonville pilot plant,
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1942CB-l)t
Wilsonville pilot plant,
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1950CB)1"
Wilsonville pilot plant,
heavy SRC
Heavy SRC
Ft. Lewis pilot plant,
heavy distillate
Ft. Lewis pilot plant,
heavy distillate
Ft. Lewis pilot plant,
heavy distillate
Ft. Lewis pilot plant,
482-860°F heavy dis-
tillate
82
82
82
82
119
98
101
84
84
98
(Continued)
725
-------
Table 309 (Continued)
Material
Value
Process Coal Type (degrees) Sample Description/Source Reference
Coal raw SRC- I
heavy
distillates
(heavy
fuel oils)
and
residua
EDS
KY No. 9
and 14,
IL No. 6
(River
King Mine)
and
Pitt-Seams
WV
(Black-
ville
No. 2 Mine)
IL No. 6
(Monterey
Mine)
Wyodak
IL No. 6
IL No. 6
IL No. 6
IL No. 6
IL No. 6
IL No. 6
10.7
0
10.3
3.5
8.0
4.6
4.1
0.1
7.6
IL No. 6
IL No. 6
8.0
7.6
400°F+ distillate, Ft.
Lewis pilot plant,
Chevron Sample No.
WOW-3751
86
One tpd pilot plant,
heavy distillatef
One tpd pilot plant,
heavy distillate§
One tpd pilot plant,
heavy distillate, as
receivedf
One tpd pilot plant,
rerun heavy distillatef
One tpd pilot plant,
heavy distillate*
One tpd pilot plant,
heavy distillate*
One tpd pilot plant,
heavy distillate^
One tpd pilot plant,
heavy distillate, UOP
Sample No. 3532-1*
One tpd pilot plant,
heavy distillate, UOP
Sample No. 3532-2*
One tpd pilot plant,
heavy distillate, UOP
Sample No. 3532-3*
104
101
123
123
99
99
99
99
99
99
(Continued)
726
-------
Table 309 (Continued)
Material
Process Coal Type
Value
(degrees) Sample Description/Source
Reference
Coal raw EDS
heavy
distillates
(heavy
fuel oils)
and
residua
IL No. 6
IL No. 6
Wyodak
Wyodak
Wyodak
Wyodak
8.6
-0.5
5.6
-5.1
-6.0
5.8
One tpd pilot plant, 350
to 1000'F distillate
blend from "typical" run
One tpd pilot plant, 350°F+
distillate blend from
"typical" run
One tpd pilot plant,
heavy distillate*
One tpd pilot plant,
heavy distillate**
One tpd pilot plant,
heavy distillate**
One tpd pilot plant,
99
99
99
99
99
99
IL No. 6 -29.5
IL No. 6 -28.3
350 to 1000'F distillate
blend from "typical" run
Wyodak -7.1 One tpd pilot plant, 350°F+ 99
distillate blend from
"typical" run
One tpd pilot plant, 124
residuum (flexicoker
vacuum bottoms)
One tpd pilot plant, 99
vacuum bottoms from
"typical" run (Run A-l)
IL No. 6 -34.56+_ One tpd pilot plant, 99
(Monterey 7.82 vacuum bottoms; average
(Mine) of three operating con-
ditions (840°F reactor
temperature; 15-40 min-
utes residence time)
IL No. 6 -28.34+ One tpd pilot plant, 99
(Monterey 3.63 vacuum bottoms; operat-
Mine) ing conditions: 840°F
reactor temperature, 40
minutes residence time,
average of ten yield
periods
(Continued)
727
-------
Table 309 (Continued)
Value
Material Process Coal Type (degrees) Sample Description/Source Reference
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
EDS
Wyodak
Wyodak
-29.3
-28.74+_
3.13
Wyodak
-29.97+
3.72"
H-Coal NA
IL No. 6
(Burning
Star Mine)
IL No. 6
IL No. 6
IL No. 6
9.2
5.4
5.0
1.3
<0
IL No. 6 -5.9
Wyodak
NA
NA
3.9
7.4
(60°F)
8.9
(60°F)
One tpd pilot plant, 99
vacuum bottoms from
"typical" run (Run A-l)
One tpd pilot plant, 99
vacuum bottoms, average
of six operating con-
ditions (800-840°F reactor
temperature; 40-100 min-
utes residence time)
One tpd pilot plant, 99
vacuum bottoms; operating
conditions: 840°F react-
or temperature, 60
minutes residence time,
average of seven yield
periods
400-900°F heavy distil- 101
late from POU
Heavy distillate from 96
PDU (Ashland Oil sample)
650-975°F heavy distil- 98
late from PDU, syncrude
mode
Heavy distillate from 109
PDU, syncrude mode
Heavy distillate from 109
PDU Run 8, syncrude mode"'"''
650-975°F heavy distil- 111
late from PDU Run 5, Run
130-82, Period 29ff
650-975°F heavy distil- 112
late from PDU Run 6, Run
130-83, Period 17§§
400°F+ fuel oil product 123
from PDU, as received
400°F+ fuel oil product
from PDU, rerun
123
(Continued)
728
-------
Table 309 (Continued)
Value
Material Process Coal Type (degrees) Sample Description/Source Reference
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and
residua
H-Coal IL No. 6 -12.9
SRC-11
EDS
Wyodak
-15.7
Pittsburgh 4.7
No. 8
(Powhattan
Mine)
IL No. 6 17.1
IL No. 6 23.5
IL No. 6 44.4
IL No. 6 45.8
975°F+ residue from PDU
Run 5, Run 130-82,
Period 29
975°F+ residue from PDU
Run 6, Run 130-83,
Period 17§§
0.4/1 middle/heavy
distillate blend, Ft.
Lewis pilot plant
From first strage hydro-
cracking of UOP raw 400°F+
heavy distillate Sample
No. 3532-3# (UOP Sample
No. 3532-9)
From first stage hydro-
cracking of UOP raw 400°F+
heavy distillate Sample
No. 3532-2# (UOP Sample
No. 3532-4)
From second stage hydro-
cracking of UOP
hydrocracked Sample No.
3532-4 (UOP Sample No.
3532-17)
From second stage hydro-
cracking of UOP
hydrocracked Sample No.
3532-4 (UOP Sample No.
3532-18)
111
112
101
99
99
99
99
(Continued)
729
-------
Table 309 (Concluded)
Explanatory Notes
determined via ASTft D-1287.
'''The raw heavy distillate from the proposed SRC-I pilot plant will consist
of a 29.0/71.0/0.0 weight percent blend of heavy distillates from the
SRC, LC-Finer and coker units, respectively (Reference 100).
tA blend of vacuum gas oil, raw process solvent and coker liquid having
a nominal boiling point of 400°F+.
§A full range (350 to 1000°F) distillate consisting of a blend of raw
naphtha, vacuum gas oil and raw process solvent.
*A blend of raw naphtha, vacuum gas oil, and raw process solvent having a
nominal boiling point of 400-1000*F.
**A blend of raw naphtha, vacuum gas oil, raw process solvent and coker
liquid having a nominal boiling point of 350°F+.
^Determined via ASTM D-1298 (by hydrometer).
Part IX, General Comments section, Note 4, for summary of
operating conditions used.
§§See Part IX, General Comments section, Note 5, for summary of operating
conditions used.
730
-------
Table 310. Density
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
SRC- I NA
KY No. 9
and 14
Kentucky
SRC- I I Kentucky
EDS IL No. 6
NA
Value
(g/ml)
29.9
28.0
38.1
(bulk)
430-
440
(Ib/bbl)
360-
368
(Ib/bbl)
1.08
1.15
Sample Description/Source
Wilsonville pilot plant,
heavy SRC, C-E Sample
No. 2440-C
Wilsonville pilot plant,
heavy SRC, C-E Sample
No. 2441-C
Ft. Lewis pilot plant,
heavy SRC
Heavy SRC
Ft. Lewis pilot plant,
482-860°F heavy
distillate
One tpd pilot plant,
heavy distillate*
One tpd pilot plant,
Reference
118
118
83
98
98
89
91
vacuum bottoms (DuPont
"Notebook" Sample No.
16928)
Coal raw NA
heavy
distillate
blends
(heavy
fuel oils)
Hydro- SRC-I
treated
heavy
distillates
(heavy
fuel oils)
and
residua
KY No. 9 1.182
Wilsonville pilot plant,
two-stage liquefaction
(TSL) SRC from low con-
version operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1943CB)
116
(Continued)
731
-------
Table 310 (Concluded)
Material
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
SRC-1
KY No. 9
Value
(g/mi)
1.206
(g/cm3)
KY No 9
1.176
(g/cm3)
KY No. 9 1.183
(g/cm3)
EDS
Explanatory Note
IL No. 6 1.01
Sample Description/Source Reference
Wilsonville pilot plant,
two-stage liquefaction
(TSL) SRC from high con-
version operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1951CB)
Wilsonville pilot plant,
two-stage liquefaction
(TSL) SRC from low con-
version operation of SRC
hydrocracker (H-Oil) unit
(Wilsonville Run No. 235,
APCI Sample No. 1983CB)
Wilsonville pilot plant,
two-stage liquefaction .
(TSL) SRC from high con-
version operation of SRC
hydrocracker (H-Oil) unit
(Wilsonville Run No. 235,
APCI Sample No. 1991CB)
Hydretreated
till ate from
pilot plant*
400°F+ dis-
one tpd
116
117
117
89
*A blend of vacuum gas oil, raw process solvent and coker liquid having a
nominal boiling point of 400°F+.
732
-------
Table 311. Reid Vapor Pressure
Material Process Coal Type Value Sample Description/Source Reference
Coal raw SRC-I KY No. 9 0.0* Wilsonville pilot plant, 82
heavy heavy distillate from SRC
distillates unit (Run No. 220, APCI
(heavy Sample No. "
fuel oils)
and
residua
Coal raw NA
heavy
distillate
blends
(heavy
fuel oils)
Hydro- NA
treated
heavy
distillates
(heavy
fuel oils)
and
residua
Explanatory Notes
*Determined via ASTM D-323
raw heavy distillate from the proposed SRC-I pilot plant will con-
sist of a 29.0/71.0/0.0 weight percent blend of heavy distillates from the
SRC, LC-Finer and coker units, respectively (Reference 100).
733
-------
Table 312. Distillation Data
Value
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
SRC-I* KY No. 9
KY No. 9
KY No. 9
Evapora-
tion) Sample Description/Source Reference
640°F-
IBP*
664°F-10
670eF-15
672°F-20
696'F-30
718°F-40
740'F-50
788"F-60
834°F-70
NA-80
880°F-90
NA-EP
650*F-
IBP*
672'F-IO
678"F-15
679'F-20
688°F-30
702°F-40
714°F-50
737°F-60
750"F-70
774"F-80
835'F-90
850°F-EP
624°F-
IBP*
679°F-10
NA-15
6788F-20
6768F-30
677°F-40
678°F-50
677°F-60
684°F-70
687°F-80
714°F-90
742'F-EP
(Continued)
Wilsonville pilot plant,
heavy distillate from SRC
unit (Run No. 220, APCI
Sample No. 1898CBV
82
Wilsonville pilot plant,
heavy distillate from SRC
unit (Run No. 225, APCI
Sample No. 1912CB)11
82
Wilsonville pilot plant,
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1942CB-l)t
82
734
-------
Table 312 (Continued)
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
SRC-I* KY No. 9
SRC-II
Pitts-
burgh
No. 8
(Pow-
hattan
Mine)
Value
(*
Evapora-
tion)
Sample Description/Source Reference
619°F-
IBP*
672°F-10
NA-15
672"F-20
671'F-30
674'F-40
674°F-50
670°F-60
671°F-70
681°F-80
711'F-90
741'F-EP
454"F-
IBPf
552'F-IO
570°F-20
5848F-30
596°F-40
620°F-50
642°F-60
668°F-70
712°F-80
NA-90
7208F-EP
NA§-
IBP*
NA§-10
NA§-20
559°F-30
570°F-40
6158F-50
629'F-60
658"F-70
698°F-80
777°F-90
658°F-EP
(Continued)
Wilsonville pilot plant,
heavy distil late from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, AP'CI Sample
No. 1950CB)1"
82
Ft. Lewis pilot plant,
heavy distillate
101
Ft. Lewis pilot plant,
heavy distil late
101
735
-------
Table 312 (Continued)
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
SRC-11 NA
MA
EDS
KY No. 9
and 14,
IL No. 6
(River
King
Mine)
and
Pitt-
Seams WV
(Black-
ville
No. 2
Mine)
IL No. 6
Value
(X
Evapora-
tion)
367°F-
IBPf
490°F-5
527°F-10
572°F-30
603°F-50
658°F-70
745°F-90
796°F-95
930°F-EP
533°F-
569°F-5
589°F-10
608°F-30
632°F-50
678°F-70
750°F-86
ND-95
ND-EP
393/413-
IBP/5
427/448-
10/30
471-50
506/590-
70/90
662/847-
95/EP
477°F-10
694°F-50
811°F-90
Sample Description/Source Reference
Ft. Lewis pilot plant,
heavy distillates
84
Ft. Lewis pilot plant,
heavy distillate
84
400°F+ distillate,
Ft. Lewis pilot plant,
Chevron Sample No.
WOW-3751
86
One tpd pilot plant,
heavy distillate
89
(Continued)
736
-------
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
EDS
Wyodak
IL No. 6
IL No. 6
IL No. 6
Table 312 (Continued)
Value
Evapora-
tion) Sample Description/Source
NA-IBP*
398'F-10
414°F-20
4378F-30
476°F-40
52CTF-50
574°F-60
626"F-70
698°F-80
8678F-90
396°F-
IBP*
592°F-50
1043'F-EP
403°F-
IBP*
696°F-50
1043°F-EP
4067
428°F-
IBP/5*
4357
452°F-
10/20
4697
511'F-
30/40
561/
619°F-
50/60
720/
825°F-
70/80
908/
955°F-
90/95
978°F-EP
(Continued)
One tpd pilot plant,
heavy distillate#
Reference
101
One tpd pilot plant,
heavy distillate**
99
One tpd pilot plant,
heavy distil late"1"*"
99
One tpd pilot plant,
heavy distillate, UOP
Sample No. 3532-1**
99
737
-------
Table 312 (Continued)
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
EDS
IL No. 6
IL No. 6
IL No. 6
IL No. 6
Value
(X
Evapora-
tion)
4087
436 °F-
IBP/5*
4437
460 °F
10/20
4907
531°F-
30/40
5747
630"F-
50/60
7307
842°F-
70/80
915°F-
90/95
NA-EP
400/
424'F-
IBP/5*
436/
460°F
10/20
490/
521'F
30/40
567/
631'F
50/60
730/
822°F
70/80
915°F-
90/95
NA-EP
392'F-5
5208F-50
867°F-95
430 °F- 5
696°F-50
1010°F-95
Sample Description/Source
One tpd pilot plant,
heavy distillate, UOP
Sample No. 3532-2**
One tpd pilot plant,
heavy distillate, UOP
Sample No. 3532-3**
One tpd pilot plant,
350 to 1000'F dis-
til late blend from
"typical" run
One tpd pilot plant,
350°F+ distillate blend
from "typical" run
Reference
99
99
99
99
(Continued)
738
-------
Table 312 (Continued)
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
Value
(X
Evapora-
tion)^ Sample Description/Source
EDS
Wyodak
Wyodak
405°F-10
568'F-50
845°F-95
399°F-10
714°F-50
943"F-95
IL No. 6 10000F-3.6
IL No. 6
(Monterey
Mine)
IL No. 6
(Monterey
Mine)
Wyodak
Wyodak
Wyodak
5.36+
1.54~
(1000'F
minus
content)
3.59+
1.41"
(1000'F
minus
content)
6.8-
1000°F
6.04+
1.32
(1000'F
minus
content)
6.84+
0.62
(1000°F
minus
content)
(Continued)
739
One tpd pilot plant,
350 to 1000°F distil-
late blend
One tpd pilot plant,
350F+ distillate
blend
One tpd pilot plant,
bottoms from "typical"
run (Run A-l)
One tpd pilot plant,
vacuum bottoms; average
of three operating con-
ditions (840° F reactor
temperature; 15-40 min-
utes residence time)
One tpd pilot plant,
vacuum bottoms; operat-
ing conditions: 840°F
reactor temperature,
40 minutes residence
time, average of ten
yield periods
One tpd pilot plant,
vacuum bottoms from
"typical" run (Run A-l)
One tpd pilot plant,
vacuum bottom, average
of six operating con-
ditions (800-840"F
reactor temperature; 40-
100 minutes residence
time)
One tpd pilot plant,
vacuum bottoms; operat-
ing conditions: 840*F
reactor temperature, 60
minutes residence time,
average of seven yield
periods
Reference
99
99
99
99
99
99
99
99
-------
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
EDS
Wyodak
Wyodak
H-Coal NA
NA
Table 312 (Continued)
Value
/ Q/
\
Evapora-
tion) Sample Description/Source
584+_ 75 Ib per day development
36°F-5 unit, vacuum bottoms;
788+_ average of eight operat-
44°F-50 ing conditions
952+ (800-880°F reactor
20°F-95 temperature, 25-100 min-
utes residence time)
653+ 75 Ib per day development
30°F-5 unit, vacuum bottoms;
787+^ operating conditions
29eF-50 880"F reactor tempera-
936+_ ture, 25 minutes
24°F-95 residence time, average
of six yield periods
452'F-IBP* 400-900°F heavy distil-
527°F-10 late from PDU
548°F-20
573°F-30
586°F-40
619°F-50
633'F-60
691"F-70
736°F-80
795'F-90
894'F-EP
Reference
99
99
101
481° F-
IBP*
519°F-10
533'F-20
552°F-30
572*F-40
594°F-50
618°F-60
NA-70
NA-80
NA-90
694°F-EP
(Continued)
400-900"F heavy distil-
late from PDU
101
740
-------
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
Table 312 (Continued)
Value
Evapora-
tion) Sample Description/Source
EDS
IL No. 6
(Burning
Star
Mine)
IL No. 6
Wyodak
Coal raw
heavy
distil late
blends
(heavy
fuel oils)
SRC-II
Pitts-
burgh
No. 8
(Pow-
hattan
Mine)
Heavy distillate from
PDU (Ashland Oil sample)
682'F-5
688°F-10
699"F-20
706°F-30
722°F-40
737°F-50
756°F-60
783°F-70
843°F-80
896°F-90
944°F-95
NA-EP
342'F-
IBP*
397°F-10
697°F-50
834eF-58
(cracked)
688°F-IBP 650-975'F heavy distil-
719'F-5 late from PDU Run 6,
732°F-10 Run 130-83, Period 17ft
Reference
96
Heavy distillate from PDU
Run 8, syncrude mode
109
112
779°F-30
783°F-40
800"F-50
817°F-60
849°F-70
8768F-80
944°F-90
986'F-95
995°F-EP
153°F-
IBP*
441°F-10
516°F-20
552°F-30
565aF-40
602°F-50
637°F-60
666°F-70
698°F-80
755°F-90
901°F-EP
0.4/1 middle/heavy dis-
tillate blend, Ft. Lewis
pilot plant
101
(Continued)
741
-------
Table 312 (Continued)
Value
Material
Process Coal Type
Evapora-
tion) Sample Description/Source Reference
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
SRC-11
Pitts-
burgh
No. 8
(Pow-
hattan
Mine)
Hydro-
treated
distillates
(heavy
fuel oils)
and
residua
EDS
IL No. 6
IL No. 6
388°F-
IBPf
461°F-10
490°F-20
530°F-30
559°F-40
590°F-50
618°F-60
NA-70
NA-80
NA-90
694°F-EP
462°F-10
657°F-50
774°F-90
0.4/1 middle/heavy dis-
tillate blend, Ft. Lewis
pilot plant
101
Hydrotreated 400°F+ dis-
tillate from one tpd
pilot plantt
89
366/
410°F-
IBP/5
431/
457°F-
10/20
480/
509°F-
30/40
548/
586°F-
50/60
635/
700°F-
70/80
797/
849°F-
90/95
925°F-EP
(Continued)
From first stage hydro-
cracking of UOP raw 400°F+
heavy distillate, Sample
No. 3532-3** (UOP
Sample No. 3532-9)
99
742
-------
Table 312 (Continued)
Material
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
EDS
IL No. 6
IL No. 6
Value
Evapora-
tion)^^ Sample Description/Source
Reference
No.
No.
307/
391°F-
IBP/5
413/
437°F-
10/20
460/
483°F-
30/40
512/
543°F-
50/60
575/
621°F-
70/80
689/
740°F-
90/95
810°F-EP
161/
187°F-
IBP/5
200/
222°F-
10/20
244/
270°F-
30/40
302/
341°F-
50/60
385/
432°F-
70/80
504/
540°F-
90/95
560°F-EP
(Continued)
From first stage hydro-
cracking of UOP raw 400°F+
heavy distillate Sample
No. 3532-2** (UOP Sample
"- 3532-4)
99
From second stage hydro-
cracking of UOP
hydrocracked Sample
No. 3532-4 (UOP Sample
No. 3532-17)
99
743
-------
Table 312 (Concluded)
Value
(%
Evapora-
Material
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type tion)
EDS IL No. 6 1647
184°F-
IBP/5
1967
215°F-
10/20
2347
256°F-
30/40
2827
317°F-
50/60
360/
407°F-
70/80
474/
514°F-
90/95
540°F-EP
Sample Description/Source
From second stage hydro-
cracking of UOP Sample
No. 3532-4 (UOP Sample
No. 3532-18)
Reference
99
Explanatory Notes
*Determined via ASTM D-1160.
'''The raw heavy distillate from the proposed SRC-1 pilot plant will consist
of a 29.0/71.0/0.0 weight percent blend of heavy distillates from the SRC,
LC-Finer and coker units, respectively (Reference 100).
^Determined via ASTM D-86
§Results were questionable due to presence of water in the sample.
#A full range (350 to 1000°F) distillate consisting of a blend of raw
naphtha, vacuum gas oil and raw process solvent.
**A blend of raw naphtha, vacuum gas oil, and raw process solvent having
a nominal boiling point of 400-1000"F.
blend of vacuum gas oil, raw process solvent and coker liquid having
a nominal boiling point of 400°F+.
Part IX, General Comments section, Note 5, for summary of oper-
ating conditions used.
744
-------
Table 313. GC Simulated Distillation Data
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
SRC-I KY No. 9
KY No. 9
KY No. 9
Boiling
Point
Range
548°F-
IBP*
653°F-10
663°F-15
672°F-20
688'F-30
705°F-40
722T-50
742°F-60
765°F-70
795°F-80
841°F-90
959°F-EP
605'F-
IBP*
6460F-10
658°F-15
667'F=20
681°F-30
693°F-40
709°F-50
726'F-60
749°F-70
778°F-80
821°F-90
938'F-EP
634BF-
IBP*
658°F-10
663°F-15
668°F-20
677°F-30
685"F-40
693°F-50
700°F-60
709°F-70
720°F-80
739°F-90
821eF-EP
(Continued)
Sample Description/Source Reference
Wilsonville pilot plant,
heavy distillate from
SRC unit (Run No. 220,
APCI Sample No. 1898CB)1"
82
Wilsonville pilot plant,
heavy distillate from
SRC unit (Run No. 225,
APCI Sample No. 1912CB)11
82
Wilsonville pilot plant,
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1942CB-1)1"
82
745
-------
Table 313 (Continued)
Boiling
Point
Material Process Coal Type Range Sample Description/Source Reference
Coal raw SRC-I KY No. 9 624°F- Wilsonville pilot plant, 82
heavy IBP* heavy distillate from
distillates 649°F-10 Lummus LC-Finer unit
(heavy 656"F-15 (Lummus Run No. 2-LC
fuel oils) 661*7-20 Finer-27, APCI Sample
and 671°F-30 No. 1950CB)1"
residua 681°F-40
689°F-50
695°F-60
702"F-70
715°F-80
736"F-90
831'F-EP
KY No. 9 712*F- Wilsonville pilot plant, 82
IBP* Alcoa coker unit (APCI
762°F-10 Sample No. ISggCB)1"
774°F-15
784°F-20
802"F-30
823BF-40
846"F-50
871"F-60
897"F-70
925BF-80
966°F-90
1158'F-EP
KY No. 9 242'F- Wilsonville pilot plant, 117
IBP* heavy SRC (Run No. 225,
258°F-5 APCI Sample No. 1914CB)
688*F-10
722'F-15
754"F-20
807°F-30
848'F-40
885°F-50
920sF-60
952°F-70
988"F-80
1032'F-90
1057°F-95
108L°F-EP
(Continued)
746
-------
Table 313 (Continued)
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
SRC-I KY No. 9
KY No. 9
SRC-II NA
Boiling
Point
Range
Sample Description/Source Reference
241°F-
IBP*
246'F-5
498'F-10
6798F-15
725°F-20
786°F-30
834°F-40
877°F-50
917'F-60
952°F-70
989°F-80
1033°F-90
1057"F-95
1081°F-EP
241"F-
IBP*
247°F-5
636'F-IO
710°F-15
755°F-20
819°F-30
870°F-40
911°F-50
944°F-60
9?6°F-70
1010°F-80
1047°F-90
1065'F-95
1082'F-EP
367°F-
IBP*
490°F-5
527°F-10
5?2"F-30
603°F-50
658°F-70
745°F-90
796°F-95
930°F-EP
(Continued)
Wilsonville pilot plant,
heavy SRC (Run No. 220,
APCI Sample No. 1916CB)
117
Wilsonville pilot plant,
heavy SRC (Run No. 209,
APCI Sample No. 1917CB)
117
Ft. Lewis pilot plant,
heavy distil late
84
747
-------
Table 313 (Continued)
Material Process
Coal raw SRC- 1 1
heavy
distillates
(heavy
fuel oils)
and
residua
Coal Type
NA
KY No. 9
and 14,
IL No. 6
(King
River
Mine)
and
Pitt-Seams
WV (Black-
ville No.
2 Mine)
Boiling
Point
Range
533°F-
IBP*
569°F-5
589°F-10
608°F-30
632°F-50
678°F-70
750°F-90
ND-95
ND-EP
233/366-
IBP/5
382/430-
10/30
477-50
527/639-
70/90
707/849-
75/99
EDS Wyodak
Wyodak
H-Coal IL No. 6
Sample Description/Source Reference
Ft. Lewis pilot plant,
heavy distillate
84
400°F+ distillate,
Ft. Lewis pilot plant,
Chevron Sample No.
WOW-3751
86
361°F-
IBP*
568°F-50
1009°F-EP
355°F-
IBP*
714°F-50
1083°F-EP
604°F-
IBP*
624°F-5
634°F-10
651°F-20
661°F-30
671°F-40
681°F-50
688°F-60
700°F-70
714°F-80
746°F-90
784°F-95
883°F-EP
(Continued)
748
One tpd pilot plant,
heavy distillate!
One tpd pilot plant,
heavy distillate§
Heavy distillate from
PDU, syncrude mode
99
99
109
-------
Table 313 (Continued)
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
H-Coal Wyodak
W. KY
No. 11
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
Hydro-
treated
heavy
distillate
(heavy
fuel oils)
and
residua
NA
NA
Boiling
Point
Range
596°F-
IBP*
620°F-5
634°F-10
652°F-20
665°F-30
676°F-40
691°F-50
704°F-60
726°F-70
755°F-80
809°F-90
862°F-95
966°F-EP
530°F-
IBP*
640°F-5
652°F-10
671°F-20
688°F-30
704°F-40
719°F-50
738°F-60
761°F-70
790°F-80
842°F-90
898°F-95
1014°F-EP
Sample Description/Source Reference
Heavy distillate from
PDU, syncrude mode
109
Heavy distillate from
POU, syncrude mode
109
(Continued)
749
-------
Table 313 (Concluded)
Explanatory Notes
'''The raw heavy distillate from the proposed SRC-I pilot plant will consist
of a 29.0/71.0/0.0 weight percent blend of heavy distillates from the SRC,
LC-Finer and coker units, respectively (Reference 100).
determined via ASTM D-2887.
?A full range (350-1000"F) distillate consisting of a blend of raw
naphtha, vacuum gas oil and raw process solvent.
§A blend of raw naphtha, vacuum gas oil, raw process solvent and coker
liquid having a nominal boiling point of 350°F+.
750
-------
Table 314. Refractive Index
Material
Coal raw
heavy
distillate
(heavy
fuel oils)
and
residua
Process Coal Type Value Sample Description/Source Reference
SRC-II
H-Coal
KY No. 9 1.5340
and 14, (176°F)
IL No. 6
(River
King
Mine)
and
Pitt-Seams
WV
(Black-
vine
No. 2
Mine)
IL No. 6 1.556
(68°F)
400°F+ distillate,
Lewis pilot plant,
Chevron Sample No.
WOW-3751
Ft.
86
IL No. 6
Wyodak
1.644
1.5784
650-975°F heavy distil-
late from PDU, syncrude
mode
650-975°F heavy distil-
late from PDU Run 5,
Run 130-82, Period 29*
650-975°F heavy distil-
late from POU Run 6,
Run 130-83, Period 17t
98
111
112
NA
NA
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
and
residua
Hydro-
treated
heavy
distillates
(heavy fuel
oils) and
residua
Explanatory Notes
*See Part IX, General Comments section, Note 4, for summary of operating condi
tions used.
'''See Part IX, General Comments section, Note 5, for summary of operating condi
tions used.
751
-------
Table 315. Molecular Weight
Value
Material Process Coal Type (g/mole) Sample Description/Source Reference
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
SRC-1
SRC-II
KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
and 14,
IL No. 6
(River
King
Mine)
and
Pitt-Seams
WV
(Black-
vine
No. 2
Mine)
275 Wilsonville pilot plant, 82
heavy distillate from
SRC unit (Run No. 220,
APCI Sample No. 1898CB)*
235 Wilsonville pilot plant, 82
heavy distillate from
SRC unit (Run No. 225,
APCI, Sample No. 1912CB)*
215 Wilsonville pilot plant, 82
heavy distillate from
Lumrnus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1942CB-1)*
150 Wilsonville pilot plant, 82
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1950CB)*
595 Wilsonville pilot plant, 116
heavy SRC (Run 225, APCI
Sample No. 1914CB)
605 Wilsonville pilot plant, 116
heavy SRC (Run 220, APCI
Sample No. 1916CB)
610 Wilsonville pilot plant, 116
heavy SRC (Run 209, APCI
Sample No. 1917CB)
69 400°F+ distillate, Ft. 86
Lewis pilot plant, Chevron
Sample No., WOW-3751
(Continued)
752
-------
Table 315 (Concluded)
Material
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
NA
Value
(g/mole)
SRC-1
KY No. 9
455
KY No. 9
445
EDS
IL No. 6
238
Explanatory Notes
Sample Description/Source Reference
Wilsonville pilot plant,
two-stage liquefaction
(TSL) SRC from low con-
version operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1943CB)
Wilsonville pilot plant,
two-stage liquefaction
(TSL) SRC from high con-
version operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1951CB)
From first stage hydro-
cracking of UOP raw 450°f
heavy distillate Sample
No. 3532-3* (UOP Sample
No. 3532-9)
116
116
99
*The raw heavy distillate from the proposed SRC-I pilot plant will consist
of a 29.0/71.0/0.0 weight percent blend of heavy distillates from the SRC,
LC-Finer and coker units, respectively (Reference 100).
1"A blend of raw naphtha, vacuum gas oil, and raw process solvent having a
nominal boiling point of 400-1000°F.
753
-------
Table 316. Total Acid Number
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
SRC-I KY No. 9 25.7*
Value
(mg
KOH/g)
KY No. 9 21.6*
KY No. 9
KY No. 9 5.29*
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and
residua
H-Coal IL No. 6 1.15
NA
Sample Description/Source Reference
Wilsonville pilot plant,
heavy distillate from
SRC unit (Run No. 220,
APCI Sample No. 1898CB)t
Wilsonville pilot plant,
heavy distillate from
SRC unit (Run No. 225,
APCI Sample No. 1912CB)1"
Wilsonville pilot plant,
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1942CB-l)t
Wilsonville pilot plant,
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1950CB)1"
Heavy distillate from
PDU Run 8, syncrude mode
82
82
82
82
109
NA
(Continued)
754
-------
Table 316 (Concluded)
Explanatory Notes
*Determined via ASTM D-664
'''The raw heavy distillate from the proposed SRC-I pilot plant will consist
of a 29.0/71.0/0.0 weight percent blend of heavy distillates from the SRC,
LC-Finer and coker units, respectively (Reference 100).
755
-------
Table 317. Gum Content
Value
(mg/
Material Process Coal Type 100 ml) Sample Description/Source Reference
Coal raw NA
heavy
distillates
(heavy
fuel oils)
and
residua
Coal raw NA
heavy
distil late
blends
(heavy
fuel oils)
Hydro- EDS IL No. 6 596 From first stage hydro- 99
treated
heavy
distillates
(heavy
fuel oils)
and
residua
Explanatory Notes
*A blend of raw naphtha, vacuum gas oil, and raw process solvent having a
nominal boiling point of 400-1000'F.
From first stage hydro-
cracking of UOP raw 400"F+
heavy distillate Sample
No. 3532-3* (UOP Sample
No. 3532-9)
756
-------
Table 318. Viscosity
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process
SRC-I
Coal Type
KY No. 9
KY No. 9
KY No. 9
KY No. 9
SRC-II
Kentucky
Pitts-
burgh
No. 8
(Pow-
hattan
Mine)
NA
NA
Value
(centi-
stoke)
325
(150'F)*
40
(210'F)
1684
(100°F)*
270
(150'F)
27
(210'F)
158.8
(68'F)*
36.7
(104'F)
14.0
(140*F)
19.4
(140°F)*
8.24
(167'F)
5.94
(194°F)
Solid
(100'F)
67.2 (SSU
at 140eF)
41.3 (SSU
at 210'F)
44.54
(104'F)
4.06
(212°F)
30.76
(1048F)
3.45
(212°F)
Sample Description/Source Reference
Wilsonville pilot plant,
heavy distillate from
SRC unit (Run No. 220,
APCI Sample No. 1898CB)t
Wilsonville pilot plant,
heavy distillate from
SRC unit (Run No. 225,
APCI Sample No. 1912CB)t
Wilsonville pilot plant,
heavy distillate from
Lumrnus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1942CB-l)t
Wilsonville pilot plant,
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1950CB)1"
Heavy SRC
Ft. Lewis pilot plant,
heavy distillate
82
82
82
82
98
101
Ft. Lewis pilot plant,
heavy distillate
Ft. Lewis pilot plant
heavy distillate
84
84
(Continued)
757
-------
Table 318 (Continued)
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Value
(centi-
stoke)
7-10
(100°F)
4.213
(100°F)
1.238
(210°F)
Process Coal Type
SRC-II Kentucky
KY No. 9
and 14,
IL No. 6
(River
King
Mine)
and
Pitt-Seams
WV
(Black-
ville
No. 2
Mine)
EDS IL No. 6 158(SSU
(Monterey at
1220°F)
Mine)
Wyodak
IL No. 6
IL No. 6
IL No. 6
IL No. 6
Wyodak
37.7
(150°F)
21.0
(100°F)
3.1
(210°F)
440
(100°F)
10.4
(210°F)
5.5
(100°F)
2.0
(210°F)
4.6
(210°F)
10.4
(100°F)
2.3
(210°F)
Sample Description/Source Reference
Ft. Lewis pilot plant,
482-860°F heavy distil-
late
400°F+ distillate, Ft.
Lewis pilot plant, Chevron
Sample No. WOW-3751
One tpd pilot plant,
heavy distillate!
One tpd pilot plant.
heavy distillate§
One tpd pilot plant.
heavy distillate*
One tpd pilot plant.
heavy distillate!
One tpd pilot plant,
350 to 1000°F distil-
late blend from "typical
run
One tpd pilot plant,
350°F+ distillate blend
from "typical" run
One tpd pilot plant,
heavy distillate§
(Continued)
98
86
104
101
99
99
99
99
99
758
-------
Table 318 (Continued)
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Value
(centi-
Process Coal Type stoke)
EDS Wyodak 2920
(100°F)
26.0
(210°F)
Wyodak 11.3
(100°F)
2.3
(210°F)
Wyodak 10,300
(150°F)
269
(210°F)
IL No. 6 800 (cp
at 600°F,
21.4-
sec-1)
IL No. 6 100,000
(440°F)
1,000
(550°F)
Wyodak 10,000
(520°F)
2,500
(690°F)
Wyodak 68+78
(poise,
at
550°F)
Wyodak 10+4
(poise,
at
550°F)
Sample Description/Source
One tpd pilot plant,
heavy distillate**
One tpd pilot plant,
350 to 1000°F distil-
late blend from "typical"
run
One tpd pilot plant,
350°F+ distillate blend
from "typical" run
One tpd pilot plant,
residuum (flexicoker
vacuum bottoms)
One tpd pilot plant,
vacuum bottoms from
"typical" run (Run A-l)
One tpd pilot plant,
vacuum bottoms from
"typical" run (Run A-l)
75 Ib per day development
unit, vacuum bottoms;
average of eight operat-
ing conditions (800-880°F
reactor temperature, 25-
100 minutes residence time]
75 Ib per day development
unit, vacuum bottoms;
operating conditions:
880°F reactor temperature,
25 minutes residence time,
average of six yield
periods
Reference
99
99
99
124
99
99
99
I
99
(Continued)
759
-------
Table 318 (Continued)
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
Process Coal Type
H-Coal NA
IL No. 6
IL No. 6
Wyodak
W. KY
No. 11
IL No. 6
IL No. 6
IL No. 6
SRC- I I Pitts-
burgh
No. 8
(Pow-
hattan
Mine)
Value
(centi-
stoke)
43.5
(140°F)
35.7
(210°F)
35
(210°F)
121.7
(104°F)
6.368
(212°F)
113.1
(104°F)
11.13
(212°F)
597.3
(104°F)
11.24
(212°F)
30,400
(122°F)*
66.1
(212°F)*
33 (SSU
at 210°F)
9900 (cps
at 450°F)
880 (cps
at 500°F)
46.7 (SSU
at 140°F)
35.2 (SSU
at 210°F)
Sample Description/Source
400-900°F heavy distil-
late from PDU
650-975°F heavy distil-
late from PDU, syncrude
mode
Heavy distillate from
PDU, syncrude mode
Heavy distillate from
PDU, syncrude mode
Heavy distillate from
PDU, syncrude mode
Heavy distillate from
PDU Run 8, syncrude mode
650-975°F heavy distil-
late from PDU Run 5,
Run 130-82, Period 29 tt
975°F+ residue from PDU
Run 5, Run 130-82,
Period 29tt
0.4/1 middle/heavy dis-
tillate blend, Ft. Lewis
pilot plant
Reference
101
98
109
109
109
109
111
111
101
760
-------
Table 318 (Concluded)
Valu-e
(centi-
Material Process Coal Type stoke) Sample Description/Source Reference
Hydro- NA
treated
heavy
distillates
(heavy
fuel oils)
and
residua
Explanatory Notes
determined via ASTM D-445.
'''The raw heavy distillate from the proposed SRC-I pilot plant will con-
sist of a 29.0/71.0/0.0 weight percent blend of heavy distillates from the
SRC, LC-Finer and coker units, respectively (Reference 100).
fA blend of vacuum gas oil, raw process solvent and coker liquid
having a nominal boiling point of 400'F"1".
§A full range (350 to 1000'F) distillate consisting of a blend of raw
naphtha, vacuum gas oil and raw process solvent.
#A blend of raw naphtha, vacuum gas oil, and raw process solvent having
a nominal boiling point of 400-1000'F.
**A blend of raw naphtha, vacuum gas oil, raw process solvent and coker
liquid having a nominal boiling point of 3508F+.
''"''See Part IX, General Comments section, Note 4, for summary of operating
conditions used.
761
-------
Table 319. Pour Point
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
Value
CF)
SRC-I
KY No. 9 93.2*
KY No. 9 69.0*
KY No. 9 -30*
KY No. 9 -8*
NA
350
NA
355
Sample Description/Source Reference
Wilsonville pilot plant,
heavy distillate from
SRC unit (Run No. 220,
APCI Sample No. ISgSCB)1"
Wilsonville pilot plant,
heavy distillate from
SRC unit (Run No. 225,
APCI Sample No. 1912CB)1"
Wilsonville pilot plant,
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample No.
1942CB-l)t
Wilsonville pilot plant
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1950C8)t
Wilsonville pilot plant,
heavy SRC (Catalytic Inc.
Sample No. SN-2651, Run
No. 6, Drum No. 120,
Babcock & Wilcox Sample
No. 13994)
Wilsonville pilot plant,
heavy SRC (Catalytic Inc.
Sample No. SN-2651, Run
No. 7D, Drum No. 97,
Babcock & Wilcox Sample
No. C-13995)
(Continued)
82
82
82
82
120
120
762
-------
Table 319 (Continued)
Value
Material
Process Coal Type
Coal raw SRC- 1 1
heavy
distillates
(heavy
fuel oils)
and
residua
EDS
H-Coal
KY No. 9
and 14,
IL No. 6
(River
King
Mine)
and
Pitt -Seams
WV
(Black-
ville
No. 2
Mine)
NA
NA
IL No. 6
(Monterey
Mine)
IL No. 6
Wyodak
Wyodak
IL No. 6
IL No. 6
Wyodak
W. KY
No. 11
IL No. 6
-50 4
L
S
0 F
h
0 F
h
40 0
h
25 0
h
45 0
h
75 0
h
86 6
1
m
50 H
P
90 H
P1
70 H
P
115* H
P
(Continued)
763
Sample Description/Source Reference
400°F+ distillate, Ft. 86
Lewis pilot plant, Chevron
Sample No. WOW-3751
Ft. Lewis pilot plant, 84
heavy distillate
Ft. Lewis pilot plant, 84
heavy distillate
One tpd pilot plant, 104
heavy distillate!
One tpd pilot plant, 99
heavy distillate!
One tpd pilot plant, 99
heavy distillate§
One tpd pilot plant, 99
heavy distillate*
650-975°F heavy distil- 98
late from PDU, syncrude
mode
Heavy distillate from 109
PDU, syncrude mode
Heavy distillate from 109
PDU, syncrude mode
Heavy distillate from 109
PDU, syncrude mode
Heavy distillate from 109
PDU Run 8, sun crude mode
-------
Table 319 (Concluded)
Material Process Coal Type
Coal raw H-Coal IL No. 6
heavy
distillates
(heavy
fuel oils) Wyodak
and
residua
Coal raw NA
heavy
distillate
blends
(heavy
fuel oils)
Hydro- NA
treated
heavy
distillates
(heavy
fuel oils)
and
residua
Explanatory Notes
Value
CF)
75
95
Sample Description/Source Reference
650-975°F heavy distil-
late from POU Run 5,
Run 130-82, Period 29**
650-975'F heavy distil-
late from PDU Run 6,
Run 130-83, Period I7t1"
111
112
*Determined via ASTM D-97.
'''The raw heavy distillate from the proposed SRC-I pilot plant will consist
of a 29.0/71.0/0.0 weight percent blend of heavy distillates from the SRC,
LC-Finer and coker units, respectively (Reference 100).
fA blend of vacuum gas oil, raw process solvent and coker liquid having
a nominal boiling point of 400°F+.
§A full range (350 to 1000'F) distillate consisting of a blend of raw
naphtha, vacuum gas oil and raw process solvent.
*A blend of raw naphtha, vacuum gas oil, raw process solvent and coker
liquid having a nominal boiling point of SSO'F*.
**See Part IX, General Comments section, Note 4, for summary of operating
conditions used.
''"''See Part IX, General Comments section, Note 5, for summary of operating
conditions used.
764
-------
Table 320. Carbon Residue
Value
Material Process Coal Type (wt %} Sample Description/Source Reference
Coal raw SRC-I KY No. 9 7.2* Wilsonvi1le pilot plant, 82
heavy heavy distillate from
distillates SRC unit (Run No. 220,
(heavy APCI Sample No. 1898CB)1"
fuel oils)
and KY No. 9 3.4* Wilsonville pilot plant, 82
residua heavy distillate from
SRC unit (Run No. 225,
APCI Sample No. 1912CB)1"
KY No. 9 0.012* Wilsonville pilot plant, 82
heavy distillate from
Lumrnus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1942CB-l)t
KY No. 9 0.006* Wilsonville pilot plant, 82
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1950CB)1"
KY No. 9 57.0*,f Wilsonville pilot plant, 116
heavy SRC (Run No. 225,
APCI Sample No. 1914CB)
KY No. 9 50.74*,f Wilsonville pilot plant, 116
heavy SRC (Run No. 220.
APCI Sample No. 1916CB)
KY No. 9 52.46*,f Wilsonville pilot plant, 116
heavy SRC (Run No. 209,
APCI Sample No. 1917CB)
KY No. 9 55.3*,f Wilsonville pilot plant, 117
heavy SRC (Run No. 235,
APCI Sample No. 1982CB)
NA 56.5f Wilsonville pilot plant 120
heavy SRC (Catalytic Inc.
Sample No. SN-2651, Run
No. 6, Drum No. 120,
Babcock & Wilcox Sample
No. C-13994)
(Continued)
765
-------
Table 320 (Continued)
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
SRC-1
EDS
NA
Value
(wt %)
53.lt
SRC-11 NA
NA
KY No. 9
and 14,
IL No. 6
(River
King
Mine)
and
Pitt-Seams
WV
(Black-
ville
No. 2
Mine)
IL No. 6
IL No. 6
IL No. 6
IL No. 6
IL No. 6
IL No. 6
2.15*
0.85*
0.81§
6.60*
0.95*
3.6*
10.0*
4.02*
3.84*
Sample Description/Source Reference
Wilsonville pilot plant, 120
heavy SRC (Catalytic Inc.
Sample No. SN-2651, Run
No. 7D, Drum No. 97,
Babcock & Wilcox Sample
No. C-13995)
Ft. Lewis pilot plant,
heavy distillate
Ft. Lewis pilot plant,
heavy distillate
400°F+ distillate, Ft.
Lewis pilot plant, Chevron
Sample No. WOW-3751
One tpd pilot plant,
heavy distillate, as
received*
One tpd pilot plant,
rerun heavy distillate*
One tpd pilot plant,
heavy distillate**
One tpd pilot plant,
heavy distillate*
One tpd pilot plant,
heavy distillate, UOP
Sample No. 3532-1**
One tpd pilot plant,
heavy distillate, UOP
Sample No. 3532-2**
(Continued)
766
84
84
86
123
123
99
99
99
99
-------
Table 320 (Continued)
Material Process
Coal raw EDS
heavy
distillates
(heavy
fuel oils)
and
residua
Coal Type
IL No. 6
Wyodak
Wyodak
IL No. 6
Value
(wt %)
3.55f
3. SBf
17. Of
57.0
Sample Description/Source
One tpd pilot plant,
heavy distillate, UOP
Sample No. 3523-3**
One tpd pilot plant,
heavy distillate"'"''
One tpd pilot plant,
heavy distillateff
One tpd pilot plant,
Reference
99
99
99
124
H-Coal IL No. 6 4.4§
IL No. 6 25.9*,f
IL No. 6 9.2§
Wyodak 3.8§
NA
NA
IL No. 6
0.41
<0.01
70. 2§
Wyodak
70.1§
residuum (flexicoker
vacuum bottoms)
650-975°F heavy distil- 98
late from PDU, syncrude
mode
Heavy distillate from 109
PDU Run 8, syncrude mode
650-975°F heavy distil- 111
late from PDU Run 5,
Run 130-82, Period 29§§
650-975°F heavy distil- 112
late from PDU Run 6,
Run 130-83, Period 17##
400°F+ fuel oil product 123
from PDU, as received
400°F+ fuel oil product 123
from PDU, rerun
975°F+ residue from 111
PDU Run 5. Run 130-82,
Period 29§§
975°F-K residue from 112
PDU Run 6,..Run 130-83,
Period l'i
(Continued)
767
-------
Table 320 (Concluded)
Material
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
NA
Value
(wt %)
Samele Description/Source Reference
SRC-I KY No. 9 37.2$
KY No. 9 44.lt
EDS
Wilsonville pilot plant, 116
two-stage liquefaction
(TSL) SRC from low con-
version operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1943CB)
Wilsonville pilot plant, 116
two-stage liquefaction
(TSL) SRC from high con-
version operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1951CB)
IL No. 6 0.08$ From first stage hydro- 99
cracking of UOP raw 400°F+
heavy distillate Sample
No. 3532-3** (UOP
Sample No. 3532-9)
Explanatory Notes
*Determined via ASTM D-189
iThe raw heavy distillate from the proposed SRC-I pilot plant will con-
sist of a 29.0/71.0/0.0 weight percent blend of heavy distillates from the
SRC, LC-Finer and coker units, respectively (Reference 100).
$Conradson carbon residue.
§Ramsbottom carbon.
#A blend of vacuum gas oil, raw process solvent and coker liquid having
a nominal boiling point of 400°F+.
**A blend of raw naphtha, vacuum gas oil, and raw process solvent having
a nominal boiling point of 400-1000°F.
full range (350 to 1000°F) distillate consisting of a blend of raw
naphtha, vacuum gas oil and raw process solvent.
$$A blend of raw naphtha, vacuum gas oil, raw process solvent and
coker liquid having a nominal boiling point of 350°F+.
§§See Part IX, General Comments Section, Note 4, for summary of operating
conditions used.
##See Part IX, General Comments Section, Note 5, for summary of operating
conditions used.
768
-------
Table 321. Bottom Sediment and Water
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
SRC-I KY No. 9
KY No. 9
KY No. 9
KY No. 9
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
SRC-II
Pittsburg
No. 8
(Powhattan
Mine)
Value
[ml
Sample Description/Source Reference
0.05*
4.5*
0.05*
SRC- II
EDS
H-Coal
Pittsburg
No. 8
(Powhattan
Mine)
Wyodak
NA
IL No. 6
1.5
0.13f
0.60
NA#
Wilsonville pilot plant,
heavy distillate from
SRC unit (Run No. 220,
APCI Sample No. 1898CB)1"
Wilsonville pilot plant,
heavy distillate from
SRC unit (Run No. 225,
APCI Sample No. 1912CB)"1"
Wilsonville pilot plant,
heavy distillate from
Lummus LC-Finer unit
(Lumrnus Run No. 2-LC
Finer-29, APCI Sample
No. 1942CB-1)1"
NA* (Not Wilsonville pilot plant,
enough heavy distillate from
sample Lummus LC-Finer unit
for (Lummus Run No. 2-LC
analysis) Finer-27, APCI Sample
No. 1950CB)t
Ft. Lewis pilot plant,
heavy distillate
One tpd pilot plant,
heavy distillate§
400-900°F heavy
distillate from PDU
Heavy distillate from
PDU Run 8, syncrude mode
0.4/1 middle/heavy
distillate blend,
Ft. Lewis pilot plant
82
82
82
82
101
1.0
101
101
109
101
(Continued)
769
-------
Table 321 (Concluded)
Value
Material Process Coal Type (ml) Sample Description/Source Reference
Hydrotreated NA
heavy
distillate
(heavy
fuel oils)
and residua
Explanatory Notes
*Determined via ASTM D-1796.
'''The raw heavy distillate from the proposed SRC-I pilot plant will consist of
29.0/71.0/0.0 weight percent blend of heavy distillates from the SRC, LC-Finer
and coker units, respectively (Reference 100).
?Moisture determined via ASTM D-95 and sediment determined by hot filtration.
§A full range (350 to lOOO'F) distillate consisting of a blend of raw
naphtha, vacuum gas oil and raw proces solvent.
^Sediment determined by extraction (ASTM D-473) is 30.3 wt percent.
770
-------
Table 322. Freeze Point
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
SRC-I KY No. 9
Value
CF)
104*
Sample Description/Source Reference
KY No. 9
69*
KY No. 9
-17*
KY No. 9
-13*
Wilsonvill-e pilot plant,
heavy distil late from
SRC unit (Run No. 220,
APCI Sample No. 1898CB)t
Wilsonville pilot plant,
heavy distillate from
SRC unit (Run No. 225,
APCI Sample No. 1912CB)1"
Wilsonville pilot plant,
heavy distillate from
Lummus LC-Finer unit
(Lumrnus Run No. 2-LC
Finer-29, APCI Sample
No. 1942CB-1)1"
Wilsonville pilot plant,
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1950CB)1"
NA
82
82
82
82
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
Hydrotreated NA
heavy
distillate
(heavy
fuel oils)
and residua
Explanatory Notes
Determined via ASTM D-2386
'The raw heavy distillate from the proposed SRC-I pilot plant will consist of
a 29.0/71.0/0.0 weight percent blend of heavy distillates from the SRC, LC-
Finer and coker units, respectively (Reference 100).
771
-------
Table 323. Flash Point
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
SRC-I KY No. 9
Value
KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
NA
Sample Description/Source Reference
>230*
>230*
>230*
>230*
Wilsonville pilot plant,
heavy distillate from
SRC unit (Run No. 220,
APCI Sample No. 1898CB)1"
Wilsonville pilot plant,
heavy distillate from
SRC unit (Run No. 225,
APCI Sample No. 1912CB)1"
Wilsonville pilot plant,
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1942CB-1)1"
Wilsonville pilot plant,
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1950CB)1"
No flash Wilsonville pilot plant,
point, heavy SRC (Run No. 225,
heavy APCI Sample No. 1914CB)
vapors at
572°Ff
No flash Wilsonville pilot plant,
point, heavy SRC (Run No. 220,
heavy APCI Sample No. 1916CB)
vapors at
572'Ff
No flash Wilsonville pilot plant,
point, heavy SRC (Run No. 209,
heavy APCI Sample No. 1917CB)
vapors at
572'Ff
360
Wilsonville pilot plant,
heavy SRC (Catalytic Inc.
Sample No. SN-2651, Run
No. 6, Drum No. 120,
Babcock & Wilcox Sample
No. C-13994)
(Continued)
772
82
82
82
82
116
116
116
120
-------
Table 323 (Continued)
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
SRC-1
SRC-II
EDS
NA
Pittsburg
No. 8
(Powhattan
Mine)
NA
NA
Kentucky
IL No. 6
(Monterey
Mine)
IL No. 6
IL No. 6
Wyodak
Wyodak
Value
CF)
360
265
285
290
168
196
198
196
Wyodak
Wyodak
172
158
196
>415
(Continued)
773
Sample Description/Source Reference
Wilsonville pilot plant, 120
heavy SRC (Catalytic Inc.
Sample No. SN-2651, Run
No. 7D, Drum No. 97,
Babcock & Wilcox Sample
No. C-13995)
Ft. Lewis pilot plant, 101
heavy distillate
Ft. Lewis pilot plant, 84
heavy distil late
Ft. Lewis pilot plant, 84
heavy distillate
Ft. Lewis pilot plant, 98
heavy distillate
One tpd pilot plant, 104
heavy distillate§
One tpd pilot plant, 99
350 to 1000°F distillate
blend from "typical" run
One tpd pilot plant, 350°F+ 99
distillate blend from
"typical" run
One tpd pilot plant, 101
heavy distillate*
One tpd pilot plant, 99
350 to 1000°F distillate
blend from "typical" run
One tpd pilot plant, 350°F+ 99
distillate blend from
"typical" run
One tpd pilot plant, 99
vacuum bottoms from
"typical" run (Run A-l)
-------
Table 323 (Concluded)
Value
Material
Coal raw
heavy
distil lates
(heavy
fuel oils)
and
residua
Process Coal Type
EDS IL No. 6
IL No. 6
Wyodak
Wyodak
(°F)
198**
204t1>
158ff
200§§
H-Coal
NA
280
230
Sample Description/Source Reference
One tpd pilot plant, 99
heavy distillate
One tpd pilot plant, 99
heavy distillate
One tpd pilot plant, 99
heavy distillate
One tpd pilot plant, 99
heavy distillate
400-900'F heavy distillate 101
from POU
0.4/1 middle/heavy 101
distillate blend,
Ft. Lewis pilot plant
Coal raw SRC-II Pittsburgh
heavy No. 8
distillate (Powhattan
blends Mine)
(heavy.
fuel oils)
Hydrotreated NA
heavy
distillates
(heavy
fuel oils)
and residua
Explanatory Notes
*Determined via ASTM D-96.
'''The raw heavy distillate from the proposed SRC-I pilot plant will consist of
29.0/71.0/0.0 weight percent blend of heavy distillates from the SRC, LC-Finer
and coker units, respectively (Reference 100).
fDetermined via ASTM D-92.
§A blend of vacuum gas oil, raw process solvent and coker liquid having a
nominal boiling point of 400°F+.
#A full range (350 to 1000°F) distillate consisting of a blend of raw naphtha,
vacuum gas oil and raw process solvent.
**A blend of raw naphtha, vacuum gas oil, and raw process solvent having a nomin*
boiling point of 400-1000°F+.
blend of vacuum gas oil, raw process solvent and coker liquid having a nomirv
boiling point of 4008F+.
full range (350 to 1000°F) distillate consisting of a blend of raw naphtha,
vacuum gas oil and raw'process solvent.
§§A blend of raw naphtha, vacuum gas oil, raw process solvent and coker liquid
having a nominal boiling point of 350°F+.
774
-------
Table 324. Heat of Combustion
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
SRC-I KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9 15,825f
KY No. 9
KY No. 9
NA
NA
Value
(Btu/lb) Sample Description/Source
16,930* Wilsonville pilot plant,
heavy distillate from
SRC unit (Run No. 220,
APCI Sample No. ISgSCB)1"
16,679* Wilsonville pilot plant,
heavy distillate from
SRC unit (Run No. 225,
APCI Sample No. 1912CB)T
18,000* Wilsonville pilot plant,
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1942CB-l)t
17,572* Wilsonville pilot plant,
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1950CB)1"
Wilsonville pilot plant,
heavy SRC (Run No. 225,
APCI Sample No. 1914CB)
16,021? Wilsonville pilot plant,
heavy SRC (Run No. 220,
APCI Sample No. 1916CB)
15,977? Wilsonville pilot plant,
heavy SRC (Run No. 209,
APCI Sample No. 1917CB)
13,970
(HHV)
13,670
(HHV)
(Continued)
Wilsonville pilot plant,
heavy SRC, C-E Sample
No. 2440-C
Wilsonville pilot plant,
heavy SRC, C-E Sample
No. 2441-C
Reference
82
82
82
82
116
116
116
118
118
775
-------
Table 324 (Continued)
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
SRC-I NA
Value
(Btu/lb)
Sample Description/Source Reference
SRC-II
EDS
NA
Kentucky
KY No. 9
and 14
Pittsburg
No. 8
(Powhattan
Mine)
NA
NA
Kentucky
NA
IL No. 6
(Monterey
Mine)
IL No. 6
IL No. 6
16,000
(HHV)
16,000
(HHV)
17,120
(HHV)
16,420
(LHV)
17,259
17,071
17,300
(HHV)
17,050
16,700
17,122
(HHV)
17,500
(Continued)
776
15,770.0 Wilsonville pilot plant, 120
(moisture heavy SRC (Catalytic Inc.
and ash Sample No. SN-2651, Run .
free) No. 6, Drum No. 120,
Babcock & Wilcox Sample
No. C-13994)
15,810.0 Wilsonville pilot plant, 120
(moisture heavy SRC (Catalytic Inc.
and ash Sample No. SN-2651, Run .
free) No. 70, Drum No. 97,
Babcock & Wilcox Sample
No. C-13995)
Heavy SRC 98
Ft. Lewis pilot plant, 83
heavy SRC
Ft. Lewis pilot plant, 101
heavy distillate
Ft. Lewis pilot plant, 84
heavy distillate
Ft. Lewis pilot plant, 84
heavy distillate
Ft. Lewis pilot plant, 98
482-860"F heavy distillate
Ft. Lewis pilot plant, 126
heavy distillate
One tpd pilot plant, 104
heavy distillate§
One tpd pilot plant, 89
heavy distillate§
One tpd pilot plant, 99
350 to 1000'F distillate
blend from "typical" run
-------
Table 324 (Continued)
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
EDS
H-Coal
IL No. 6
Wyodak
Wyodak
Wyodak
Wyodak
IL No. 6
IL No. 6
IL No. 6
Wyodak
Value
(Btu/lb)
16,700
17,770
(HHV)
17,600
16,700
12,300
11,400
NA
IL No. 6
Wyodak
W. KY
No. 11
17,860
(HHV)
17,030
(LHV)
17,420
17,849
17,261
Sample Description/Source Reference
One tpd pilot plant, 350°F+ 99
distil late blend from
"typical" run
One tpd pilot plant,
heavy distillate#
One tpd pilot plant,
350 to lOOO'F distillate
blend from "typical" run
One tpd pilot plant, 350°F+
distillate blend from
"typical" run
One tpd pilot plant,
vacuum bottoms from
"typical" run (Run A-l)
One tpd pilot plant,
vacuum bottoms from
"typical" run (Run A-l)
400-900'F heavy distillate
from PDU
Heavy distillate from PDU,
syncrude mode
Heavy distillate from PDU,
syncrude mode
Heavy distillate from PDU,
syncrude mode
16,847** Heavy distillate from PDU,
Run 8 syncrude mode
16,742
17,486
(Continued)
777
650-975°F heavy distillate
from PDU Run 5, Run
130-82, Period 29t1"
650-975"F heavy distillate
from PDU Run 6, Run
130-83, Period 17??
101
99
99
99
99
101
109
109
109
109
111
112
-------
Table 324 (Continued)
SRC-II
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
Hydrotreated SRC-I
heavy
distillates
(heavy
fuel oils)
and residua
Process Coal Type
H-Coal IL No. 6
IL No. 6
Pittsburg
No. 8
(Powhattan
Mine)
KY No. 9
KY No. 9
KY No. 9
KY No. 9
Value
(Btu/lb) Sample Description/Source Reference
16,225
16,108
17,000
(HHV)
16,260
(LHV)
16,993
16,878
16,870
16,175
975°F distillate from PDU 112
Run 6, Run 130-83, Period 17tf
975°F+ residue from PDU 111
Run 5, 130-82, Period 29
0.4/1 middle/heavy 101
distil late blend,
Ft. Lewis pilot plant
Wilsonville pilot plant, 116
two-stage liquefaction
(TSL) SRC from low con-
version operation of Lumrnus
LC-Finer unit (lumrnus Run
No. 2-LC Finer-29, APCI
Sample No. 1943CB)
Wilsonville pilot plant, 116
two-stage liquefaction
(TSL) SRC from high con-
version operation of Lummus
LC-Finer unit (Lummus Run
No. 2-LC Finer-27, APCI
Sample No. 1951CB)
Wilsonville pilot plant, 117
two-stage liquefaction
(TSL) SRC from low con-
version operation of SRC
hydrocracker (H-Oil) unit.
(Wilsonville Run No. 235,
APCI Sample No. 1983CB)
Wilsonville pilot plant, 117
two-stage liquefaction
(TSL) SRC from high con-
version operation of SRC
hydrocracker (H-Oil) unit.
(Wilsonville Run No. 235,
APCI Sample No. 1991CB)
(Continued)
778
-------
Table 324 (Concluded)
Value
Material Process Coal Type (Btu/lb) Sample Description/Source Reference
Hydrotreated EDS IL No. 6 18,112 Hydrotreated 400°F+ 89
heavy (HHV) distillate from one tpd
distillates pilot plant§
(heavy
fuel oils)
and residua
Explanatory Notes
determined via ASTM D-240.
raw heavy distillate from the proposed SRC- I pilot plant will consist of
29.0/71.0/0.0 weight percent blend of heavy distillates from the SRC, LC-Finer
and coker units, respectively (Reference 100).
f Determined via ASTM D-2015.
§A blend of vacuum gas oil, raw process solvent and coker liquid having a
nominal boiling point of 400°F+.
#A full range (350 to 1000°F) distillate consisting of a blend of raw naphtha,
vacuum gas oil and raw process solvent.
determined via ASTM D-2382.
Part IX, General Comments section, Note 4, for summary of operating condi-
tions used.
Part IX, General Comments Section, Note 5, for summary of operating
conditions used.
779
-------
Material Process
Coal raw SRC- 1 1
heavy
distillates
(heavy
fuel oils)
and
residua
EDS
Coal raw NA
heavy
distillate
blends
(heavy
fuel oils)
Hydrotreated NA
heavy
distillates
(heavy
fuel oils)
and residua
Table 325.
Coal Type
KY No. 9
and 14,
IL No. 6
(River
King
Mine)
and
Pitt-Seams
WV
(Black-
ville
No. 2
Mine)
IL No. 6
IL No. 6
Wyodak
Wyodak
...
Brom
Value
69
7.2
40.2
22.6
54.6
• _
Sample Description/Source Reference
400°F+ distillate, Ft.
Lewis pilot plant, Chevron
Sample No. WOW-3751
86
One tpd pilot plant,
heavy distillate*
One tpd pilot plant,
heavy distillate1"
One tpd pilot plant,
heavy distillate^
One tpd pilot plant,
heavy distillate§
99
99
99
99
(Continued)
780
-------
Table 325 (Concluded)
Explanatory Notes
*A blend of raw naphtha, vacuum gas oil, and raw process solvent having a
nominal boiling point of 400-1000°F+.
^A blend of vacuum gas oil, raw process solvent and coker liquid having a
nominal boiling point of 400°F+.
fA full range (350 to 1000°F) distillate consisting of a blend of raw naphtha,
vacuum gas oil and raw process solvent.
blend of raw naphtha, vacuum gas oil, raw process solvent and coker liquid
having a nominal boiling point of 350°F+.
781
-------
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
SRC-I KY No. 9
Table 326. Copper Strip Corrosion
Sample Description/Source Reference
Value
("F)
KY No. 9
KY No. 9
KY No. 9
la* Wilsonville pilot plant,
heavy distillate from
SRC unit (Run No. 220,
APCI Sample No. 1898CB)T
la* Wilsonville pilot plant,
heavy distillate from
SRC unit (Run No. 225,
APCI Sample No. 1912CB)11
la* Wilsonville pilot plant,
heavy distillate from
Lummus LC-Finer unit
(Lumrnus Run No. 2-LC
Finer-29, APCI Sample No.
1942CB-l)t
la* Wilsonville pilot plant
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
NO. 1950CB)1"
NA
NA
82
82
82
82
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and
residua
Explanatory Notes
determined via ASTM D-130.
'''The raw heavy distillate from the proposed SRC-I pilot plant will consist
of a 29.0/71.0/0.0 weight percent blend of heavy distillates from the SRC,
LC-Finer and coker units, respectively (Reference 100).
782
-------
Table 327. Moisture
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
SRC-I KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
NA
NA
Value
(Wt %)
0.12*
0.11*
0.03*
0.05*
o.oet
0.10*
0.4
0.3
Sample Description/Source Reference
Wilsonville pilot plant,
heavy distillate from
SRC unit (Run No. 220,
APCI Sample No. 1898CB)t
Wilsonville pilot plant,
heavy distillate from
SRC unit (Run No. 225,
APCI Sample No. 1912CB)1"
Wilsonville pilot plant,
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample No.
1942CB-l)t
Wilsonville pilot plant
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1950CB)1"
Wilsonville pilot plant,
heavy SRC (Run No. 225,
APCI Sample No. 1914CB)
Wilsonville pilot plant,
heavy SRC (Run No. 220,
APCI Sample No. 1916CB)
Wilsonville pilot plant,
heavy SRC (Run No. 209,
APCI Sample No. 1917CB)
Wilsonville pilot plant
heavy SRC, C-E Sample No.
2440-C
Wilsonville pilot plant
heavy SRC, C-E Sample No.
2441-C
82
82
82
82
116
116
116
118
118
(Continued)
783
-------
Table 327 (Concluded)
Material
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
Process Coal Type
NA
Value
(wt %)
Sample Description/Source Reference
Hydrotreated SRC-t
heavy
distillates
(heavy
fuel oils)
and residua
KY No. 9
0.01
KY No. 9
0.08
Wilsonville pilot plant, 116
two-stage liquefaction
(TSL) SRC from low con-
version operation of Lummus
LC-Finer unit (Lummus Run
No. 2-LC Finer-29, APCI
Sample No. 1943CB)
Wilsonville pilot plant, 116
two-stage liquefaction
(TSL) SRC from high con-
version operation of Lummus
LC-Finer unit (Lummus Run
No. 2-LC Finer-27, APCI
Sample No. 1951CB)
Explanatory Notes
determined via Karl Fischer method.
'''The raw heavy distillate from the proposed SRC-I pilot plant will consist
of a 29.0/71.0/0.0 weight percent blend of heavy distillates from the SRC,
LC-Finer and coker units, respectively (Reference 100).
fDetermined via ASTM D-3302.
784
-------
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and residua
Process Coal Type
SRC-I KY No. 9
KY No. 9
KY No. 9
NA
Table 328. Sintering Temperature
Sample Description/Source Reference
228.2
199.4
215.6
Wilsonville pilot plant,
heavy SRC (Run No 225,
APCI Sample No 1914CB)
Wilsonville pilot plant,
heavy SRC (Run No. 220,
APCI Sample No. 1916CB)
Wilsonville pilot plant,
heavy SRC (Run No. 209,
APCI Sample No. 1917CB)
SRC-I
KY No. 9
202
Wilsonville pilot plant,
two- stage liquefaction
(TSL) SRC from high con-
version operation of SRC
hydrocracker (H-Oil) unit
(Wilsonville Run No. 235,
APCI Sample No. 1991CB)
116
116
116
117
785
-------
Table 329. Melting (Fusion) Point
Value
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Procass Coal Type
SRC-I KY No. 9
KY No. 9
KY No. 9
KY No. 9
and 14
NA
320
275
293
324
330-350
Sample Description/Source Reference
Wilsonville pilot plant 116
heavy SRC (Run No. 225,
APCI Sample No. 1914CB)
Wilsonville pilot plant
heavy SRC (Run No. 220,
APCI Sample No. 1916CB)
Wilsonville pilot plant,
heavy SRC (Run No. 209,
APCI Sample No. 1917CB)
Ft Lewis pilot plant,
heavy SRC
Heavy SRC
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and residua
NA
SRC-1
KY No. 9
253
Wilsonville pilot plant,
two-stage liquefaction
(TSL) SRC from high con-
version operation of SRC
hydrocracker (H-Oil) unit
(Wilsonville Run No. 235,
APCI Sample No. 1991CB)
116
116
83
98
117
786
-------
Table 330. Softening Point
Material
Coal raw
heavy
distillates
(heavy fuel
oils) and
residua
Process Coal Type
SRC-1
KY No. 9
KY No. 9
KY No. 9
KY No. 9
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and residua
NA
SRC-1
KY No. 9
KY No. 9
H-Coal IL No. 6
Wyodak
Value
356
310
332
338
318
325
360
350
Sample Description/Source Reference
Wilsonville pilot plant,
heavy SRC (Run No. 225,
APCI Sample No. 1914CB)
Wilsonville pilot plant,
heavy SRC (Run No. 220,
APCI Sample No. 1916CB)
Wilsonville pilot plant,
heavy SRC (Run No. 209,
APCI Sample No. 1917CB)
Wilsonville pilot plant,
heavy SRC (Run No. 235,
APCI Sample No. 1982CB)
Wilsonville pilot plant,
two-stage liquefaction
(TSL) SRC from low con-
version operation of
lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1943CB)
Wilsonville pilot plant,
two-stage liquefaction
(TSL) SRC from high con-
version operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1951CB)
975°F+ residue from POU
Run 5, Run 130-82,
Period 29*
975°F+ residue from PDU
Run 6, Run 130-83,
Period 17t
116
116
116
117
116
116
111
112
Explanatory Notes
*See Part IX, General Comments Section, Note 4, for summary of operating condi-
tions used.
'''See Part IX, General Comments Section, Note 5, for summary of operating
conditions used.
787
-------
Table 331. Free Swelling Index
Value
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and residua
Process Coal Type
SRC-I KY No. 9
KY No. 9
KY No. 9
NA
1
1/2*
SRC-I KY No. 9
1/2*
KY No. 9
1/2*
KY No. 9
Sample Description/Source Reference
Wilsonville. pilot plant,
heavy SRC (Run No. 225,
APCI Sample No. 1914CB)
Wilsonville pilot plant,
heavy SRC (Run No. 220,
APCI Sample No. 1916CB)
Wilsonville pilot plant,
heavy SRC (Run No. 209,
APCI Sample No. 1917CB)
Wilsonville pilot plant,
two-stage liquefaction
(TSL) SRC from low con-
version operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1943CB)
Wilsonville pilot plant,
two-stage liquefaction
(TSL) SRC from high con-
version operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1951CB)
Wilsonville pilot plant,
two-stage liquefaction
(TSL) SRC from low con-
version operation of SRC
hydrocracker (H-Oil) unit
(Wilsonville Run No. 235,
APCI Sample No. 1983CB)
116
116
116
116
116
117
(Continued)
788
-------
Table 331 (Concluded)
Value
Material Process Coal Type (°F) Sample Description/Source Reference
Hydro- SRC-I KY No. 9 1 Wilsonville pilot plant, 117
teated two-stage liquefaction
heavy (TSL) SRC from high con-
distillates version operation of SRC
(heavy hydrocracker (H-Oil) unit
fuel oils) (Wilsonville Run No. 235,
and APCI Sample No. 1991CB)
residua
Explanatory Note
*Determined via ASTM D-720
789
-------
Table 332. Heat Capacity
Material Process
Coal raw SRC- I
heavy
distillates
(heavy
fuel oils)
and
residua
Coal
KY No
KY No
Type
. 9
. 9
KY No. 9
KY No. 9
and 14
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and residua
NA
SRC-I KY No. 9
KY No. 9
0.37
0.43
0.36
Sample Description/Source Reference
Wilsonville pilot plant, 116
heavy SRC (Run No. 225,
APCI Sample No. 1914CB)
Wilsonville pilot plant,
heavy SRC (Run No. 220,
APCI Sample No. 1916CB)
Wilsonville pilot plant,
heavy SRC (Run No. 209,
APCI Sample No. 1917CB)
0.319 Ft. Lewis pilot plant,
(100°F) heavy SRC
0.494
(400°F)
0.557
(700°F)
0.42
(212°F)
0.56
(392°F)
0.74
(572°F)
0.55
(752°F)
0.38
(212°F)
0.50
(392°F)
0.65
(572°F)
0.55
(752°F)
(Continued)
790
Wilsonville pilot plant,
two-stage liquefaction
(TSL) SRC from low con-
version operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1943CB)
Wilsonville pilot plant,
two-stage liquefaction
(TSL) SRC from high con-
version operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1951CB)
116
116
83
116,117
116,117
-------
Table 332 (Concluded)
Value
(Btu/
Material
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
SRC-1
KY No. 9
0.35
(212°F)
0.46
(392°F)
0.51
(572°F)
0.60
(752°F)
Sample Description/Source Reference
Wilsonville pilot plant,
two-stage liquefaction
(TSL) SRC from high con-
version operation of SRC
hydrocracker (H-Oil) unit
(Wilsonville Run No. 235,
APCI Sample No. 1991CB)
117
791
-------
Table 333. Ash Content (by Proximate Analysis)
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and residua
Process Coal Type
SRC-I KY No. 9
KY No. 9
KY No. 9
NA
NA
NA
Value
(wt %)
0.039
0.044
0.044
0.2
0.1
Sample Description/Source Reference
SRC-1
KY No. 9
0.019
KY No. 9
0.019
(Continued)
792
Wilsonville pilot plant,
heavy SRC (Run No. 225,
APCI Sample No. 1914CB)
Wilsonville pilot plant,
heavy SRC (Run No. 220,
APCI Sample No. 1916CB)
Wilsonville pilot plant,
heavy SRC (Run No. 209,
APCI Sample No. 1917CB)
Wilsonville pilot plant,
heavy SRC, C-E Sample
No. 2440-C
Wilsonville pilot plant,
heavy SRC, C-E Sample
No. 2441-C
Wilsonville pilot plant,
two-stage liquefaction
(TSL) SRC from low con-
version operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1943CB)
Wilsonville pilot plant,
two-stage liquefaction
(TSL) SRC from high con-
version operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1951CB)
116
116
116
118
118
116
116
-------
Table 333 (Concluded)
Value
Material Process Coal Type (wt %) Sample Description/Source Reference
Hydro- KY No. 9 0.12 Wilsonvi1le pilot plant, 117
treated two-stage liquefaction
heavy (TSL) SRC from low con-
distillates version operation of SRC
(heavy hydrocracker (H-Oil) unit
fuel oils) (Wilsonvilie Run No. 235,
and residua APCI Sample No. 1983CB)
KY No. 9 0.08 Wilsonville pilot plant, 117
two-stage liquefaction
(TSL) SRC from high con-
version operation of SRC
hydrocracker (H-Oil) unit
(Wilsonville Run No. 235,
APCI Sample No. 1991CB)
793
-------
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and residua
Table 334.
Process Coal Type
SRC-I KY No. 9
KY No. 9
KY No. 9
NA
NA
NA
Volatiles Content
Value
63.30
68.17
60.22
64.4
61.9
SRC-1
KY No. 9
76.40
KY No. 9
74.70
Sample Description/Source Reference
Wilsonville pilot plant, 116
heavy SRC (Run No. 225,
APCI Sample No. 1914CB)
Wilsonville pilot plant,
heavy SRC (Run No. 220,
APCI Sample No. 1916CB)
Wilsonville pilot plant,
heavy SRC (Run No. 209,
APCI Sample No. 1917CB)
Wilsonville pilot plant,
heavy SRC, C-E Sample
No. 2440-C
Wilsonville pilot plant,
heavy SRC, C-E Sample
No. 2441-C
Wilsonville pilot plant,
two-stage liquefaction
(TSL) SRC from low con-
version operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1943CB)
Wilsonville pilot plant,
two-stage liquefaction
(TSL) SRC from high con-
version operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1951CB)
116
116
118
118
116
116
(Continued)
794
-------
Table 334 (Concluded)
Value
Material Process Coal Type (*F) Sample Description/Source Reference
Hydro- SRC-I KY No. 9 27.29 Wilsonville pilot plant, 117
treated two-stage liquefaction
heavy (TSL) SRC from low con-
distillates version operation of SRC
(heavy hydrocracker (H-Oil) unit
fuel oils) (Wilsonville Run No. 235,
and APCI Sample No. 1983CB)
residua
KY No. 9 73.90 Wilsonville pilot plant, 117
two-stage liquefaction
(TSL) SRC from high con-
version operation of SRC
hydrocracker (H-Oil) unit
(Wilsonville Run No. 235,
APCI Sample No. 1991CB)
795
-------
Table 335. Fixed Carbon
Value
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and residua
Process Coal Type
SRC-I KY No. 9
KY No. 9
KY No. 9
NA
NA
NA
SRC-1
KY No. 9
KY No. 9
36.60
31.71
39.47
25.7
26.0
23.71
25.20
Sample Description/Source Reference
Wilsonville pilot plant, 116
heavy SRC (Run No. 225,
APCI Sample No. 1914CB)
Wilsonville pilot plant,
heavy SRC (Run No. 220,
APCI Sample No. 1916CB)
Wilsonville pilot plant,
heavy SRC (Run No. 209,
APCI Sample No. 1917CB)
Wilsonville pilot plant,
heavy SRC, C-E Sample
No. 2440-C
Wilsonville pilot plant,
heavy SRC, C-E Sample
No. 2441-C
Wilsonville pilot plant,
two-stage liquefaction
(TSL) SRC from low con-
version operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1943CB)
Wilsonville pilot plant,
two-stage liquefaction
(TSL) SRC from high con-
version operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1951CB)
116
116
118
118
116
116
(Continued)
796
-------
Table 335 (Concluded)
Value
Material Process Coal Type (°F) Sample Description/Source Reference
Hydro- SRC-I KY No. 9 72.59 Wilsonville pilot plant, 117
treated two-stage liquefaction
heavy (TSL) SRC from low con-
distillates version operation of SRC
(heavy hydrocracker (H-Oil) unit
fuel oils) (Wilsonville Run No.^235,
and APCI Sample No. 1983CB)
residua
KY No. 9 26.02 Wilsonville pilot plant, 117
two-stage liquefaction
(TSL) SRC from high con-
version operation of SRC
hydrocracker (H-Oil) unit
(Wilsonville Run No. 235,
APCI Sample No. 1991CB)
797
-------
Table 336. Oxygen Content
Material Process Coal Type Value (wt %) Sample Description/Source Reference
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
SRC-I KY No. 9 3.33 Wilsonville pilot plant,
heavy distillate from SRC
unit (Run No. 220, APCI
Sample No. 1898CB)*
KY No. 9 2.75 Wilsonville pilot plant,
heavy distillate from SRC
unit (Run No. 225, APCI
Sample No. 1912CB)*
KY No. 9 0.15 Wilsonville pilot plant,
heavy distillate from
Lumrnus LC-Finer unit
(Lummus Run No. 2-LC-
Finer-29, APCI Sample No.
1942CB-1)*
KY No. 9 <0.1 Wilsonville pilot plant,
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample No.
1950CB)*
KY No. 9 2.25 Wilsonville pilot plant,
heavy distillate from
Alcoa coker unit (APCI
Sample No. 1899CB)
KY No. 9 4.28 Wilsonville pilot plant,
heavy SRC (Run No. 225,
APCI Sample No. 1914CB)
KY No. 9 3.98 Wilsonville pilot plant,
heavy SRC (Run No. 220,
APCI Sample No. 1916CB)
KY No. 9 3.71 Wilsonville pilot plant,
hpavv
-------
Material
Table 336 (Continued)
Process Coal Type Value (wt %} Sample Description/Source Reference
Coal raw SRC- I
heavy
distillates
(heavy
fuel oils)
and
residua
SRC- I I
EDS
NA
Kentucky
IL No. 6
KY No. 9
and 14
Pittsburgh
No. 8
(Powhattan
Mine)
NA
NA
Kentucky
NA
KY No. 9
and 14,
IL No. 6
(River
King
Mine) and
Pitt-Seams
WV (Black-
vine No.
2 Mine)
IL No. 6
Wyodak
5.lt
4.3
5.00
3.93
1.9
2.04
1.80
2.5-3.6
l,6t
3.63
1.83
1.59
Wilsonville pilot plant,
heavy SRC, C-E Sample No.
244 1-C
Heavy SRC
Wilsonville pilot plant,
heavy SRC
Ft. Lewis pilot plant,
heavy SRC
Ft. Lewis pilot plant,
heavy distillate
Ft. Lewis pilot plant,
heavy distillate
Ft. Lewis pilot plant,
heavy distillate
Ft. Lewis pilot plant,
482-860°F heavy distillate
Ft. Lewis pilot plant,
heavy distillate
400°F+ distillate, Ft.
Lewis pilot plant,
Chevron Sample No.
WOW-3751
One tpd pilot plant,
heavy distillate!
One tpd pilot plant,
heavy distillate§
118
98
145
83
101
84
84
98
126
86
89
101
(Continued)
799
-------
Material
Table 336 (Continued)
Process Coal Type Value (wt %) Sample Description/Source Reference
Coal raw EDS
heavy
distillates
(heavy
fuel oils)
and
residua
IL
IL
IL
IL
IL
IL
No.
No.
No.
No.
No.
No.
6
6
6
6
6
6
1.93
2.84
2.61"
3.1
2.9
0.9100
One tpd pilot plant,
heavy distillate, as
received?
One tpd pilot plant,
rerun heavy distillate?
One tpd pilot plant,
heavy distillate*
One tpd pilot plant
heavy distillate?
One tpd pilot plant,
heavy distillate*
One tpd pilot plant,
123
123
99
99
99
99
IL No. 6
IL No. 6
IL No. 6
IL No. 6
Wyodak
Wyodak
Wyodak
2.6 0
h
2.4 0
h
2.9 0
h
(Continued)
heavy distillate, UOP
Sample No. 3532-1*
2.8000 One tpd pilot plant, 99
heavy distillate, UOP
Sample No. 3532-2*
1.9800 One tpd pilot plant, 99
heavy distillate, UOP
Sample No. 3523-3*
1.90 One tpd pilot plant, 99
350 to 1000°F distil-
late blend from "typical"
run
2.51 One tpd pilot plant, 99
350°F+ distillate blend
from "typical" run
One tpd pilot plant, 99
heavy distillate§
One tpd pilot plant, 99
heavy distillate**
One tpd pilot plant, 99
heavy distillate**
800
-------
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Table 336 (Continued)
Process Coal Type Value (wt %) Sample Description/Source Reference
EDS Wyodak 2.60 One tpd pilot plant, 99
350 to 1000°F distil-
late blend from "typical"
run
Wyodak 2.90 One tpd pilot plant, 350°F+ 99
distillate blend from
"typical" run
EDS IL No. 6 2.42 One tpd pilot plant, 99
vacuum bottoms from
"typical" run
(Run A-l)
IL No. 6 3.24+0.45 One tpd pilot plant, 99
(Monterey vacuum bottoms, average
Mine) of three operating condi-
tions (840°F reactor
temperature; 15-40
minutes residence time)
IL No. 6 2.42+0.58 One tpd pilot plant, 99
(Monterey vacuum bottoms; operat-
Mine) ing conditions: 840°F
reactor temperature, 40
minutes residence time,
average of ten yield
periods
IL No. 6 2.44+0.80 75 Ib per day development 99
(Monterey unit, vacuum bottoms;
Mine) average of six operating
conditions (800-880°F
reactor temperature;
25-100 minutes residence
time)
IL No. 6 1.92_+0.53 75 Ib per day development 99
(Monterey unit, vacuum bottoms;
Mine) operating conditions:
840°F reactor tempera-
ture; 40 minutes residence
time, average of 21 yield
periods
(Continued)
801
-------
Table 336 (Continued)
Material Process Coal Type Value (wt %) Sample Description/Source Reference
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
EDS
Wyodak
Wyodak
EDS
Wyodak
Wyodak
Wyodak
NA
H-Coal NA
IL No. 6
Wyodak
3.86
4.30+0.90
3.86+0.77
3.37+1.33
2.26+0.43
3.59
1.68+
1.3
1.6
One tpd pilot plant,
vacuum bottoms from
"typical" run (Run
A-D
One tpd pilot plant,
vacuum bottoms, average
of six operating condi-
tions (800-840°F reactor
temperature; 40-100
minutes residence time)
One tpd pilot plant,
vacuum bottoms; operat-
ing conditions: 840°F
reactor temperature; 60
minutes residence time,
average of seven yield
periods
75 Ib-per day development
unit, vacuum bottoms,
average of eight operating
conditions (800-880°F
reactor temperature,
25-100 minutes residence
time)
75 Ib per day development
unit, vacuum bottoms;
operating conditions:
880°F reactor temperature,
25 minutes residence
time, average of six
yield periods
One tpd pilot plant,
vacuum bottoms (DuPont
"Notebook" Sample No.
16928)
400-900°F heavy distil-
late from PDU
Heavy distillate from
PDU, syncrude mode
Heavy distillate from
PDU, syncrude mode
(Continued)
802
99
99
99
99
99
91
101
109
109
-------
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Table 336 (Continued)
Process Coal Type Value (wt %) Sample Description/Source Reference
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and
residua
H-Coal W.KY No. 11
NA
IL No. 6
H-Coal IL No. 6
Wyodak
IL No. 6
Wyodak
SRC-II
SRC-1
Pittsburgh
No. 8
(Powhattan
Mine)
NA
KY No. 9
2.2
0.84t
1.20
0.97
2.00
1.37
2.85
3.471"
1.3f
1.16
Heavy distillate from
PDU, syncrude mode
400°F+ fuel oil product
from PDU; operating
conditions: 851°F, 2,500
psig
650-975°F heavy distil-
late from PDU, syncrude
mode
650-975°F heavy distil-
late from PDU Run 5,
Run 130-82, Period 29ft
650-975°F heavy distil-
late from PDU Run 6,
Run 130-83, Period 17ft
975°F+ residue from PDU
Run 5, Run 130-82, period
29tt
975°F+ residue from PDU
Run 6, Run 130-83, Period
0.4/1 middle/heavy
distillate blend, Ft.
Lewis pilot plant
1/2 middle/heavy distil-
late blend, Ft. Lewis
pilot plant
Wilsonville pilot plant,
two-stage liquefaction
(TSL) SRC from low
conversion operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample No.
1943CB)
109
154
98
111
112
111
112
101
126
116
((Continued)
803
-------
Table 336 (Continued)
Material Process Coal Type Value (wt %) Sample Description/Source Reference
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and
residua
SRC-1 KY No. 9
KY No. 9
KY No. 9
EDS
IL No. 6
IL No. 6
IL No. 6
IL No. 6
0.72 Wilsonville pilot plant, 116
two-stage liquefaction
(TSL) SRC from high
conversion operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample No.
1951CB)
1.61 Wilsonville pilot plant, 117
two-stage liquefaction
(TSL) SRC from low
conversion operation of
SRC hydrocracker (H-Oil)
unit (Wilsonvil1e Run
No. 235, APCI Sample No.
1983CB)
2.24 Wilsonville pilot plant, 117
two-stage liquefaction
(TSL) SRC from high
conversion operation of
SRC hydrocracker (H-Oil)
unit (Wilsonville Run No.
235, APCI Sample No.
1991CB)
0.32 Hydrotreated 400"F+ 89
distillate from one tpd
pilot plantf
0.2980 From first stage hydro- 99
cracking of UOP raw
400°F+ heavy distillate
Sample No. 3532-3# (UOP
Sample No. 3532-9)
0.0167 From first stage hydro- 99
cracking of UDP raw
400^ heavy distillate
Sample No. 3532-2* (UOP
Sample No. 3532-4)
0.0226 From second stage hydro- 99
cracking of UOP hydro-
cracked Sample No. 3532-4
(UDP Sample No. 3532-17)
(Continued)
804
-------
Table 336 (Concluded)
Material Process Coal Type Value (wt %) Sample Description/Source Reference
Hydro- EDS IL No. 6
treated
heavy
distillates
(heavy
fuel oils) H-Coal IL No. 6
and
residua
0.0197 From second state hydro-
cracking of UOP hydro-
cracked Sample No. 3532-4
(UOP Sample No. 3532-18)
0.94 POU, fuel oil mode, from
low severity hydrotreat-
ment of 375-1000°F
distillate (DOE Sample
No. 1617)
99
151
H-Coal IL No. 6
IL No. 6
0.74 PDU, fuel oil mode, from 151
medium severity hydro-
treatment of 375-1000°F
distillate (DOE Sample
No. 1618)
0.44 PDU, fuel oil mode, from 151
high severity treatment
of 375-1000°F distillate
(DOE Sample No. 1619)
Explanatory Notes
*The raw heavy distillate from the proposed SRC-I pilot plant will consist of a
29.0/71.0/0.0 weight percent blend of heavy distillate from the SRC, LC Finer and
coker units, respectively (Reference 100).
1"By difference.
fA blend of vacuum gas oil, raw process solvent and coker liquid having a
nominal boiling point of 400°F+.
§A.full range (350 to 1000°F) distillate consisting of a blend of raw naphtha,
vacuum gas oil and raw process solvent.
*A blend of raw naphtha, vacuum gas oil, and raw process solvent having a
nominal boiling point of 400-1000°F.
**A blend of raw naphtha, vacuum gas oil, raw process solvent and coker liquid
having a nominal boiling point of 350°^.
^See Part IX, General Comments section, Note 4, for summary of operating conditions
used.
ffSee Part IX, General Comments section, Note 5, for summary of operating condi-
tions used.
805
-------
Table 337. Sulfur Content
Material Process Coal Type Value (wt %) Sample Description/Source Reference
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
SRC-1
KY No. 9
0.61
KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
NA
NA
NA
Kentucky
0.56
0.01
<0.01
0.47
1.12
1.12
1.04
0.85
0.8
0.7
0.7-0.8
(Continued)
806
Wilsonville pilot plant,
heavy distillate from SRC
unit (Run No. 220, APCI
Sample No. 1898CB)*
Wilsonville pilot plant,
heavy distillate from SRC
unit (Run No. 225, APCI
Sample No. 1919CB)*
Wilsonville pilot plant,
heavy distillate from
Lumrnus LC-Finer unit
(Lummus Run No. 2-LC-
Finer-29, APCI Sample No.
1942CB-1)*
Wilsonville pilot plant,
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample No.
1950CB)*
Wilsonville pilot plant,
heavy distillate from
Alcoa coker unit (APCI
Sample No. 1899CB)
Wilsonville pilot plant,
heavy SRC (Run No. 225,
APCI Sample No. 1914CB)
Wilsonville pilot plant,
heavy SRC (Run No. 220,
APCI Sample No. 1916CB)
Wilsonville pilot plant,
heavy SRC (Run No. 209,
APCI Sample No. 1917CB)
Wilsonville pilot plant,
heavy SRC
Wilsonville pilot plant,
heavy SRC, C-E Sample No.
2440-C
Wilsonville pilot plant,
heavy SRC, C-E Sample No.
2441-C
Heavy SRC
82
82
82
82
82
116
116
116
119
118
118
98
-------
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residue
Table 337 (Continued)
Process Coal Type Value (wt %) Sample Description/Source Reference
SRC-1
SRC-II
NA
NA
IL No. 6
KY No. 9
and 14
Pittsburgh
No. 8
(Powhattan
Mine)
NA
NA
Kentucky
0.67
0.75
0.39
0.42
0.35
0.2-0.4
NA
KY No. 9
and 14,
IL No. 6
(King
River
Mine) and
Pitt-Seams
WV (Black-
ville No.
2 Mine)
0.91" Wilsonville pilot plant, 120
heavy SRC (Catalytic Inc.
Sample No. SN-2651, Run
No. 6, Drum No. 120,
Babcock and Wilcox Sample
No. C-13994)
Wilsonville pilot plant, 120
heavy SRC (Catalytic Inc.
Sample No. SN-2651, Run
No. 70, Drum No. 97,
Babcock and Wilcox Sample
No. C-13995)
Wilsonville pilot plant, 145
heavy SRC
Ft. Lewis pilot plant, 83
heavy SRC
Ft. Lewis pilot plant, 101
heavy distillate
Ft. Lewis pilot plant, 84
heavy distillate
Ft. Lewis pilot plant, 84
heavy distillate
Ft. Lewis pilot plant, 98
482-860°F heavy
distillate
0.5 Ft. Lewis pilot plant, 126
heavy distillate
0.25 400°F+ distillate, Ft. 86
Lewis pilot plant,
Chevron Sample No.
WOW-3751
(Continued)
807
-------
Material Process Coal Type
Table 337 (Continued)
Value (wt %) Sample Description/Source Reference
Coal raw EDS
heavy
distillates
(heavy
fuel oils)
and
residua
IL No. 6
(Monterey
Mine)
IL No. 6
Wyodak
IL No. 6
IL No.
IL No.
IL No.
IL No.
IL No.
6
6
6
6
6
0
0
0
0
0
.20
.60
.54
.87
.6500
IL No. 6
IL No. 6
IL No. 6
IL No. 6
0.8 One tpd pilot plant,
heavy distillatef
0.41 One tpd pilot plant,
heavy distil later
0.29 One tpd pilot plant,
heavy distillate§
0.49 One tpd pilot plant,
heavy distillate, as
received!
One tpd pilot plant,
rerun heavy distillate!
One tpd pilot plant,
heavy distillate*
One tpd pilot plant,
heavy distillate*
One tpd pilot plant,
heavy distillate!
One tpd pilot plant,
heavy distillate, UOP
Sample No. 3532-1*
0.6710 One tpd pilot plant,
heavy distillate, UOP
Sample No. 3532-2*
0.6510 One tpd pilot plant,
heavy distillate, UOP
Sample No. 3523-3*
0.38 One tpd pilot plant,
350 to 1000'F distillate
belnd from "typical"
run
0.60 One tpd pilot plant,
350'F+ distillate blend
from "typical" run
(Continued)
808
104
89
101
123
123
99
99
99
99
99
99
99
99
-------
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Wyodak
IL No. 6
IL No. 6
0.15
2.3
2.30
99
124
99
Table 337 (Continued)
Process Coal Type Value (wt %} Sample Description/Source Reference
EDS Wyodak 0.10 One tpd pilot plant, 99
heavy distillate§
Wyodak 0.18 One tpd pilot plant, 99
heavy distillate**
Wyodak 0.15 One tpd pilot plant, 99
heavy distillate**
Wyodak 0.10 One tpd pilot plant, 99
350 to 1000°F distillate
blend from "typical"
run
One tpd pilot plant, 350°F+
distillate blend from
"typical" run
One tpd pilot plant,
residuum (flexicoker
vacuum bottoms)
One tpd pilot plant,
vacuum bottoms from
"typical" run (Run
A-l)
IL No. 6 2.37+0.07 One tpd pilot plant, 99
(Monterey vacuum bottoms, average
Mine) of three operating con-
ditions (840°F reactor
temperature; 15-40
minutes residence time)
IL No. 6 2.30+0.10 One tpd pilot plant, 99
(Monterey vacuum bottoms; operat-
Mine) ing conditions: 840°F
reactor temperature; 40
minutes residence time,
average of ten yield
periods
IL No. 6 2.24+0.15 75 Ib per day development 99
(Monterey unit, vacuum bottoms;
Mine) average of six operating
conditions (800-880°F
reactor temperature;
25-100 minutes residence
time)
(Continued)
809
-------
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residue
Table 337 (Continued)
Process Coal Type Value (wt %) Sample Description/Source Reference
EDS IL No. 6 2.48+0.17 75 Ib per day development 99
IL No. 6
(Monterey
Mine)
Wyodak
Wyodak
Wyodak
Wyodak
Wyodak
NA
75 Ib per day development
unit, vacuum bottoms;
operating conditions: 840°F
reactor temperature,
40 minutes residence time,
average of 21 yield
periods
0.34 One tpd pilot plant, 99
vacuum bottoms from
"typical" run (Run
A-l)
0.39+0.06 One tpd pilot plant, 99
vacuum bottoms; operat-
ing conditions: 800-840°F
reactor temperature;
40-100 minutes residence
time
0.34+0.11 One tpd pilot plant, 99
vacuum bottoms; operat-
ing conditions: 840°F
reactor temperature; 60
minutes residence time,
average of seven yield
periods
0.54+0.14 75 Ib per day development 99
unit, vacuum bottoms,
average of eight operating
conditions (800-880°F
reactor temperature,
25-100 minutes residence
time)
0.60+0.09 75 Ib per day development 99
unit, vacuum bottoms;
operating conditions: 880°F
reactor temperature, 25
minutes residence time,
average of six yield
periods
1.22 One tpd pilot plant, 91
vacuum bottoms (DuPont
"Notebook" Sample No.
16928)
(Continued)
810
-------
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Table 337 (Continued)
Process Coal Type Value (wt %) Sample Description/Source Reference
H-Coal
NA
IL No. 6
Wyodak
W.Ky No. 11
IL No. 6
(Burning
Star
Mine)
IL No. 6
IL No. 6
Wyodak
IL No. 6
Wyodak
0.075
0.2
0.2
0.2
0.1500
0.22
0.14
<0.03
0.37
0.13
NA
NA
NA
0.19
0.16
0.14
400-900°F heavy distil-
late from POU
Heavy distillate from
PDU, syn crude mode
Heavy distillate from
PDU, syn crude mode
Heavy distillate from
PDU, syn crude mode
Heavy distillate from
PDU (Ashland Oil Sample)
650-975°F heavy distil-
late from PDU, syncrude
mode
650-975°F heavy distil-
late from PDU Run 5,
Run 130-82, Period 29™
650-975°F heavy distil-
late from PDU Run 6,
Run 130-83, Period 17ft
975°F+ residue from PDU
Run 5, Run 130-82, Period
2gtt
975°F+ residue from PDU
Run 6, Run 130-82, Period
PDU, heavy distillate
PDU, heavy distillate
400°F+ fuel oil product
from PDU; operating
conditions: 851°F, 2500
psig
101
109
109
109
96
98
111
112
111
112
153
153
154
(Continued)
811
-------
Table 337 (Continued)
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type Value (wt %)
0.10
H-Coal NA
NA
SRC-II
SRC-1
Pittsburgh
No. 8
(Powhattan
Mine)
NA
KY No. 9
0.08
0.34
0.4
0.21
KY No. 9
0.05
KY No. 9
0.28
Sample Description/Source Reference
400°F+ fuel oil product 123
from PDU, as received
400"F+ fuel oil product 123
from PDU, rerun
0.4/1 middle/heavy 101
distillate blend, Ft.
Lewis pilot plant
Ft. Lewis pilot plant, 126
1/2 middle/heavy distil-
late blend
Wilsonville pilot plant, 116
two-stage liquefaction
(TSL) SRC from low
conversion operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample No.
1943CB)
Wilsonville pilot plant, 116
two-stage liquefaction
(TSL) SRC from high
conversion operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample No.
1951CB)
Wilsonville pilot plant, 117
two-stage liquefaction
(TSL) SRC from low
conversion operation of
SRC hydrocracker (H-Oil)
unit. (Wilsonville Run
No. 235, APCI Sample No.
1983CB)
(Continued)
812
-------
Table 337 (Continued)
Material Process Coal Type Value (wt %) Sample Description/Source Reference
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and
residua
SRC-I KY No. 9
EDS
IL No. 6
IL No. 6
IL No. 6
IL No. 6
IL No. 6
IL No. 6
IL No. 6
IL No. 6
0.33 Wilsonville pilot plant, 117
two-stage liquefaction
(TSL) SRC from high
conversion operation of
SRC hydrocracker (H-Oil)
unit (Wilsonville Run No.
235, APCI Sample No.
1991CB)
0.04 Hydrotreated 400°F+ 89
distillate from one tpd
pilot plant!
0.0267 From first stage hydro- 99
cracking of UOP raw
400°F+ heavy distillate
Sample No. 3532-3* (UOP
Sample No. 3532-9)
0.0013 From first stage hydro- 99
cracking of UOP raw
400°F+ heavy distillate
Sample No. 3532-2# (UOP
Sample No. 3532-4)
0.0365 From second stage hydro- 99
cracking of UOP hydro-
cracked Sample No. 3532-4
0.0261 From second stage hydro- 99
cracking of UOP hydro-
cracked Sample No. 3532-4
(UOP Sample No. 3532-18)
0.059 PDU, fuel oil mode, from 151
low severity hydrotreat-
ment of 375-1000°F distil-
late (DOE Sample No. 1617)
0.039 PDU, fuel oil mode, from 151
medium severity hydro-
treatment of 375-1000°F
distillate (DOE Sample
No. 1618)
0.011 PDU, fuel oil mode, from 151
high severity hydrotreat-
ment of 375-1000°F
distillate (DOE
Sample No. 1619)
(Continued)
813
-------
Table 337 (Concluded)
Explanatory Notes
*The raw heavy distillate from the proposed SRC-I pilot plant will consist of a
29.0/71.0/0.0 weight percent blend of heavy distillate from the SRC, LC-Finer and
coker units, respectively (Reference 100).
^Determined using solid fuel ASTM procedures.
fA blend of vacuum gas oil, raw process solvent and coker liquid having a
nominal boiling point of 400"F+.
§A full range (350 to 1000'F) distillate consisting of a blend of raw naphtha,
vacuum gas oil and raw process solvent.
#A blend of raw naphtha, vacuum gas oil, and raw process solvent having a
nominal boiling point of 400-1000'F.
**A blend of raw naphtha, vacuum gas oil, raw process solvent and coker liquid
having a nominal boiling point of 350°F+.
''"''See Part IX, General Comments section, Note 4, for summary of operating conditions
used.
ffSee Part IX, General Comments section, Note 5, for summary of operating conditions
used.
814
-------
Table 338. Nitrogen Content
Material Process Coal Type Value (wt %) Sample Description/Source Reference
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
SRC-I KY No. 9
0.96
KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
NA
NA
NA
Kentucky
1.18
0.22
0.29
1.29
2.17
2.09
2.07
1.97
1.5
1.6
2.1-2.2
(Continued)
815
Wilsonville pilot plant, 82
heavy distillate from SRC
unit (Run No. 220, APCI
Sample No. 1898CB)*
Wilsonville pilot plant, 82
heavy distillate from SRC
unit (Run No. 225, APCI
Sample No. 1912CB)*
Wilsonville pilot plant, 82
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC-
Finer-29, APCI Sample No.
1942CB-1)*
Wilsonville pilot plant, 82
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample No.
1950CB)
Wilsonville pilot plant, 82
heavy distillate from
Alcoa coker unit (APCI
Sample No. 1899CB)
Wilsonville pilot plant, 116
heavy SRC (Run No. 225,
APCI Sample No. 1914CB)
Wilsonville pilot plant, 116
heavy SRC (Run No. 220,
APCI Sample No. 1916CB)
Wilsonville pilot plant, 116
heavy SRC (Run No. 209,
APCI Sample No. 1917CB)
Wilsonville pilot plant, 119
heavy SRC
Wilsonville pilot plant, 118
heavy SRC, C-E Sample No.
2440-C
Wilsonville pilot plant, 118
heavy SRC, C-E Sample No.
2441-C
Heavy SRC 98
-------
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Table 338 (Continued)
Process Coal Type
SRC-I NA
SRC-II
Value (wt %} Sample Description/Source Reference
1.8t
NA
IL No. 6
KY No. 9
and 14
Pittsburgh
No. 8
(Powhattan
Mine)
NA
NA
Kentucky
NA
KY No. 9
and 14,
IL No. 6
(River
King
Mine) and
Pitt-Seams
WV (Black-
ville No.
2 Mine)
Wilsonville pilot plant,
heavy SRC (Catalytic Inc.
Sample No. SN-2651, Run
No. 6, Drum No. 120,
Babcock and Wilcox Sample
No. C-13994)
2.0"1" Wilsonville pilot plant,
heavy SRC (Catalytic Inc.
Sample No. SN-2651, Run
No. 7b, Drum No. 97,
Babcock and Wilcox Sample
No. C-13995)
2.00 Wilsonville pilot plant,
heavy SRC
2.15 Ft. Lewis pilot plant,
heavy SRC
1.03 Ft. Lewis pilot plant,
heavy distillate
0.98 Ft. Lewis pilot plant,
heavy distillate
0.94 Ft. Lewis pilot plant,
heavy distillate
1.1-1.4 Ft. Lewis pilot plant,
482-860°F heavy
distillate
1.1 Ft. Lewis pilot plant,
heavy distillate
0.99 400°F+ distillate, Ft.
Lewis pilot plant,
Chevron Sample No.
WOW-3751
120
120
145
83
101
84
84
98
126
86
(Continued)
816
-------
Material
Table 338 (Continued)
Process Coal Type Value (wt %) Sample Description/Source Reference
Coal raw EDS
heavy
distillates
(heavy
fuel oils)
and
residua
IL No. 6
(Monterey
Mine)
IL No. 6
Wyodak
IL No. 6
IL No. 6
IL No. 6
IL No. 6
IL No. 6
IL No. 6
1.0
0.66
0.39
0.71
0.49
0.55
0.62
0.80
0.4580
One tpd pilot plant,
heavy distil latef
One tpd pilot plant,
heavy distil later
One tpd pilot plant,
heavy distillate*
One tpd pilot plant,
heavy distillate, as
received!
One tpd pilot plant,
rerun heavy distillatef
One tpd pilot plant,
heavy distillate*
One tpd pilot plant,
heavy distillate*
One tpd pilot plant,
heavy distillatef
One tpd pilot plant,
104
89
101
123
123
99
99
99
99
IL No. 6
IL No. 6
IL No. 6
IL No. 6
heavy distillate, UOP
Sample No. 3532-1*
0.4950 One tpd pilot plant,
heavy distillate, UOP
Sample No. 3532-2*
0.5050 One tpd pilot plant,
heavy distillate, UOP
Sample No. 3532-3*
0.49 One tpd pilot plant,
350 to 1000'F distillate
blend from "typical"
run
0.77 One tpd pilot plant,
350°F+ distillate blend
from "typical" run
(Continued)
817
99
99
99
99
-------
Material
Table 338 (Continued)
Process Coal Type Value (wt %) Sample Description/Source Reference
Coal raw EDS
heavy
distillates
(heavy
fuel oils)
and
residua
Wyodak
Wyodak
Wyodak
Wyodak
0.44
0.86
0.89
0.48
One tpd pilot plant,
heavy distillate*
One tpd pilot plant,
heavy distillate**
One tpd pilot plant,
heavy distillate**
One tpd pilot plant,
99
99
99
99
350 to 1000'F distillate
blend from "typical"
run
Wyodak 0.89 One tpd pilot plant, 99
350'F+ distillate
from "typical" run
IL No. 6 1.5 One tpd pilot plant, 124
residuum (flexicoker
vacuum bottoms)
IL No. 6 1.45 One tpd pilot plant, 99
vacuum bottoms from
"typical" run (Run
A-l)
IL No. 6 1.29+0.28 One tpd pilot plant, 99
(Monterey vacuum bottoms, average
Mine) of three operating con-
ditions (840"F reactor
temperature; 15-40
minutes residence time)
IL No. 6 1.45+0.04 One tpd pilot plant, 99
(Monterey vacuum bottoms; operat-
Mine) ing conditions: 840"F
reactor temperature; 40
minutes residence time,
average of ten yield
periods
IL No. 6 1.39+0.07 75 Ib per day development 99
(Monterey unit, vacuum bottoms;
Mine) average of six operating
conditions (800-880'F
reactor temperature;
25-100 minutes residence
time)
(Continued)
818
-------
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Table 338 (Continued)
Process Coal Type Value (wt %) Sample Description/Source Reference
EDS
IL No. 6
(Monterey
Mine)
Wyodak
Wyodak
Wyodak
Wyodak
Wyodak
NA
1.35+0.09 75 Ib per day development 99
unit, vacuum bottoms;
operating conditions:
840°F reactor temperature,
40 minutes residence time,
average of 21 yield
periods
1.04 One tpd pilot plant, 99
vacuum bottoms from
"typical" run (Run
A-D
1.18+0.1Z One tpd pilot plant, 99
vacuum bottoms, average
of six operating condi-
tions (800-840°F
reactor temperature;
40-100 minutes residence
time)
1.04+0.08 One tpd pilot plant, 99
vacuum bottoms; operat-
ing Conditions: 840°F
reactor temperature; 60
minutes residence time,
average of seven yield
periods
1.19+0.05 75 Ib per day development 99
unit, vacuum bottoms;
average of eight operating
conditions (800-880°F
reactor temperature,
25-100 minutes residence
time)
1.16+0.05 75 Ib per day development 99
unit, vacuum bottoms;
operating conditions: 880°F
reactor temperature, 25
minutes residence time,
average of six yield
periods
1.31 One tpd pilot plant, 91
vacuum bottoms (DuPont
"Notebook" Sample No.
16928)
(Continued)
819
-------
Material
Table 338 (Continued)
Process Coal Type Value (wt %} Sample Description/Source Reference
Coal raw H-Coal
heavy
distillates
(heavy
fuel oils)
and
residua
NA
IL No. 6
Wyodak
W.KY No. 11
IL No. 6
(Burning
Star
Mine)
IL No. 6
IL No. 6
Wyodak
IL No. 6
Wyodak
IL No. 6
Wyodak
NA
NA
NA
0.57
1.3
1.4
1.2
0.3600
1.01
1.10
1.04
1.95
1.20
0.68
0.64
0.87
0.35
0.41
400-900°F heavy distil-
late from PDU
Heavy distillate from
PDU, syn crude mode
Heavy distillate from
PDU, syn crude mode
Heavy distillate from
PDU, syn crude mode
Heavy distillate from
PDU (Ashland Oil Sample)
650-975°F heavy distil-
late from PDU, syncrude
mode
650-975°F heavy distil-
late from PDU Run 5,
Run 130-82, Period 29tt
650-975°F heavy distil-
late from PDU Run 6,
Run 130-83, Period 17ft
975°F+ residue from PDU
Run 5, Run 130-82, Period
29tt
975°F+ residue from PDU
Run 6, Run 130-82, Period
17ft
PDU, heavy distillate
PDU, heavy distillate
400° F+ fuel oil product
from PDU; operating
conditions: 851°F, 2500
psig
400°F+ fuel oil product
from PDU, as received
400°F+ fuel oil product
from PDU, rerun
101
109
109
109
96
98
111
112
111
112
153
153
154
123
123
(Continued)
820
-------
Material
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and
residua
Table 338 (Continued)
Process Coal Type Value (wt %) Sample Description/Source Reference
SRC-II
SRC-1
Pittsburgh
No. 8
(Powhattan
Mine)
NA
KY No. 9
KY No. 9
KY No. 9
KY No. 9
IL No. 6
0.96 0.4/1 middle/heavy 101
distil late blend, Ft.
Lewis pilot plant
1.0 Ft. Lewis pilot plant, 126
1/2 middle/heavy distil-
late blend
1.00 Wilsonville pilot plant, 116
two-stage liquefaction
(TSL) SRC from low
conversion operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample No.
1943CB)
1.10 Wilsonville pilot plant, 116
two-stage liquefaction
(TSL) SRC from high
conversion operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample No.
1951CB)
1.85 Wilsonville pilot plant, 117
two-stage liquefaction
(TSL) SRC from low
conversion operation of
SRC hydrocracker (H-Oil)
unit. (Wilsonville Run
No. 235, APCI Sample No.
1983CB)
1.85 Wilsonville pilot plant, 117
two-stage liquefaction
(TSL) SRC from high
conversion operation of
SRC hydrocracker (H-Oil)
unit (Wilsonville Run No.
235, APCI Sample No.
1991CB)
0.24 Hydrotreated 400°F+ 89
distillate from one tpd
pilot plantf
(Continued)
821
-------
Table 338 (Continued)
Material Process Coal Type Value (wt %) Sample Description/Source Reference
Hydro- EDS
treated
heavy
distillates
(heavy
fuel oils)
and
residua
IL No. 6
IL No. 6
IL No. 6
IL No. 6
H-Coal IL No. 6
IL No. 6
IL No. 6
0.0844 From first stage hydro- 99
cracking of UOP raw
400'F+ heavy distillate
Sample No. 3532-3# (UOP
Sample No. 3532-9)
0.0007 From first stage hydro- 99
cracking of UOP raw
400'F+ heavy distillate
Sample No. 3532-2* (UOP
Sample No. 3532-4)
0.00002 From second stage hydro- 99
cracking of UOP hydro-
cracked Sample No. 3532-4
0.00002 From second stage hydro- 99
cracking of UOP hydro-
cracked Sample No. 3532-4
(UOP Sample No. 3532-18)
0.58 PDU, fuel oil mode, from 151
low severity hydrotreat-
ment of 375-100eF distillate
(DOE Sample No. 1617)
0.55 PDU, fuel oil mode, from 151
medium severity hydro-
treatment of 375-100°F
distillate (DOE Sample
No. 1618)
0.30 PDU, fuel oil mode, from 151
high severity Hydrotreat-
ment of 375-100'F
distillate (DOE Sample
No. 1619)
(Continued)
822
-------
Table 338 (Concluded)
Explanatory Notes
*The raw heavy distillate from the proposed SRC-I pilot plant will consist of a
29.0/71.0/0.0 weight percent blend of heavy distillate from the SRC, LC-Finer and
coker units, respectively (Reference 100).
^Determined using solid fuel ASTM procedures.
$A blend of vacuum gas oil, raw process solvent and coker liquid having a
nominal boiling point of 400°F+.
§A full range (350 to 1000°F) distillate consisting of a blend of raw naphtha,
vacuum gas oil and raw process solvent.
#A blend of raw naphtha, vacuum gas oil, and raw process solvent having a
nominal boiling point of 400-1000°F.
**A blend of raw naphtha, vacuum gas oil, raw process solvent and coker liquid
having a nominal boiling point of
Part IX, General Comments section, Note 4, for summary of operating conditions
used.
ffSee Part IX, General Comments section, Note 5, for summary of operating conditions
used.
823
-------
Table 339. Carbon Content
Material Process Coal Type Value (wt %) Sample Description/Source Reference
Coal raw SRC-I
heavy
distillates
(heavy
fuel oils)
and
residua
KY No. 9
87.08
KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
IL No. 6
NA
NA
Kentucky
J.13
91.08
91.62
88.34
86.92
86.72
87.38
86.90
78.8
75.3
86.9
(Continued)
824
Wilsonville pilot plant, 82
heavy distillate from SRC
unit (Run No. 220, APCI
Sample No. 1898CB)*
Wilsonville pilot plant, 82
heavy distillate from SRC
unit (Run No. 225, APCI
Sample No. 1912CB)*
Wilsonville pilot plant, 82
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC-
Finer-29, APCI Sample No.
1942CB-1)*
Wilsonville pilot plant, 82
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample No.
1950CB)*
Wilsonville pilot plant, 82
heavy distillate from
Alcoa coker unit (APCI
Sample No. 1899CB)
Wilsonville pilot plant, 116
heavy SRC (Run No. 225,
APCI Sample No. 1914CB)
Wilsonville pilot plant, 116
heavy SRC (Run No. 220,
APCI Sample No. 1916CB)
Wilsonville pilot plant, 116
heavy SRC (Run No. 209,
APCI Sample No. 1917CB)
Wilsonville pilot plant, 145
heavy SRC
Wilsonville pilot plant, 118
heavy SRC, C-E Sample No.
2440-C
Wilsonville pilot plant, 118
heavy SRC, C-E Sample No.
2441-C
Heavy SRC 98
-------
Table 339 (Continued)
Material Process Coal Type Value (wt %} Sample Description/Source Reference
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
SRC-1
SRC-II
NA
NA
KY No. 9
and 14
Pittsburgh
No. 8
(Powhattan
Mine)
KY No. 9
and 14,
IL No. 6
(King
River
Mine) and
Pitt-Seams
WV (Black-
ville No.
2 Mine)
Kentucky
NA
87.
87.lt
87.26
88.98
86.61,
86.18
86.8-
87.6
88.9
Wilsonville pilot plant,
heavy SRC (Catalytic Inc.
Sample No. SN-2651, Run
No. 6 Drum No. 120,
Babcock and Wilcox Sample
No. C-13994)
Wilsonville pilot plant,
heavy SRC (Catalytic Inc.
Sample No. SN-2651, Run
No. 7D, Drum No. 97,
Babcock and Wilcox Sample
No. C-13995)
Ft. Lewis pilot plant,
heavy SRC
Ft. Lewis pilot plant,
heavy distillate
120
120
83
101
400°F+ distillate,
Lewis pilot plant,
Chevron Sample No.
WOW-3751
Ft.
86
Ft. Lewis pilot plant,
482-860°F heavy distillate
Ft. Lewis pilot plant,
heavy distillate
98
126
(Continued)
825
-------
Table 339 (Continued)
Material Process Coal Type Value (wt %) Sample Description/Source Reference
Coal raw EDS
heavy
distillates
(heavy
fuel oils)
and
residua
IL
No.
6
Wyodak
IL
IL
IL
IL
IL
IL
No.
No.
No.
No.
No.
No.
6
6
6
6
6
6
89
88
89
87
87
87
87
86
.40
.66
.22
.93
.98
.39
.39
.00
One tpd pilot plant,
heavy distillatef
One tpd pilot plant,
heavy distil late§
One tpd pilot plant,
heavy distil late, as
receivedf
One tpd pilot plant,
rerun heavy distillatef
One tpd pilot plant,
heavy distil late*
One tpd pilot plant,
heavy distillate*
One tpd pilot plant,
heavy distillatef
One tpd pilot plant,
89
101
123
123
99
99
99
99
heavy distillate, UOP
Sample No. 3532-1*
IL No. 6 86.45 One tpd pilot plant, 99
heavy distillate, UOP
Sample No. 3532-2*
IL No. 6 87.61 One tpd pilot plant, 99
heavy distillate, UOP
Sample No. 3532-3*
IL No. 6 88.50 One tpd pilot plant, 99
350 to 1000°F
distillate blend
IL No. 6 87.67 One tpd pilot plant, 99
350°F+ distillate blend
(Continued)
826
-------
Table 339 (Continued)
Material Process Coal Type Value (wt %) Sample Description/Source Reference
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
EDS
Wyodak
Wyodak
Wyodak
Wyodak
Wyodak
IL No. 6
88.58
89.21
88.98
L69
!.92
69.43
IL No. 6 70.41+0.87
(Monterey
Mine)
IL No. 6 69.43+0.53
(Monterey
Mine)
IL No. 6 71.41+1.74
(Monterey
Mine)
IL No. 6 68.39+0.97
(Monterey
Mine)
One tpd pilot plant,
heavy distillate§
One tpd pilot plant,
heavy distillate**
One tpd pilot plant,
heavy distillate**
One tpd pilot
350 to 1000°F
blend
plant,
distillate
One tpd pilot plant,
distillate blend
99
99
99
99
350°F+ 99
One tpd pilot plant, 124
vacuum bottoms from
"typical" run (Run A-l)
One tpd pilot plant, 99
vacuum bottoms, average
of three operating con-
ditions (840°F reactor
temperature; 15-40
minutes residence time)
One tpd pilot plant, 99
vacuum bottoms; operat-
ing conditions: 840°F
reactor temperature; 15-40
minutes residence time,
average of ten yield
periods
75 Ib per day development 99
unit, vacuum bottoms;
average of six operating
conditions (800-880°F
reactor temperature;
25-100 minutes residence
time)
75 Ib per day development 99
unit, vacuum bottoms;
operating conditions: 840°F
reactor temperature;
40 minutes residence
time, average of 21
yield periods
(Continued)
827
-------
Table 339 (Continued)
Material Process Coal Type Value (wt %} Sample Description/Source Reference
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
EDS
Wyodak
Wyodak
75.87
75.47+1.01
Wyodak
75.87+1.42
Wyodak
75.96+1.62
Wyodak 75.59+0.52
NA
H-Coal NA
IL No. 6
Wyodak
85.84
1.52
89.2
86.6
W.K No. 11 89.0
One tpd pilot plant, 99
vacuum bottoms from
"typical" run (Run
A-l)
One tpd pilot plant, 99
vacuum bottoms, average
of six operating condi-
tions (800-840°F reactor
temperature; 40-100
minutes residence time)
One tpd pilot plant, 99
vacuum bottoms; operating
conditions: 840°F reactor
temperature; 60 minutes
residence time, average
of seven yield periods
75 Ib per day development 99
unit, vacuum bottoms,
average of eight operating
conditions (800-880°F
reactor temperature,
25-100 minutes residence
time)
75 Ib per day development 99
unit, vacuum bottoms;
operating conditions:
880°F reactor temperature,
25 minutes residence
time, average of six
yield periods
One tpd pilot plant, 91
vacuum bottoms (DuPont
"Notebook" Sample No.
16928)
400-900°F heavy distil- 101
late from PDU
Heavy distillate from 109
PDU, syncrude mode
Heavy distillate from 109
PDU, syncrude mode
Heavy distillate from 109
PDU, syncrude mode
(Continued)
828
-------
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Table 339 (Continued)
Process Coal Type Value (wt %) Sample Description/Source Reference
H-Coal NA
IL No. 6
IL No. 6
Wyodak
IL No. 6
Wyodak
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and
residua
SRC-I KY No. 9
KY No. 9
89.82
90.0
89.70
89.61
88.47
90.17
Coal raw SRC- I I
heavy
distillate
blends
(heavy
fuel oils)
NA
Pittsburgh
No. 8
(Powhattan
Mine)
NA
89.32
87.16
89.1
90.95
92.33
40CTF fuel oil product
from POD; operating con-
ditions: 851°F, 2500
psig
650-975 °F heavy distil-
late from PDU, syncrude
mode
650-975°F heavy distil-
late from PDU Run 5,
Run 130-82, Period 29™
650-975°F heavy distil-
late from POU Run 6,
Run 130-83, Period 17ff
975'F+ residue from PDU
Run 5, Run 130-82, Period
29tt
975°F+ residue from PDU
Run 6, Run 130-83, Period
400'F+ fuel oil product
from PDU, rerun
0.4/1 middle/heavy
distillate blend, Ft.
Lewis pilot plant
Ft. Lewis pilot plant,
1/2 middle/heavy distil-
late blend
Wilsonville pilot plant,
two- stage liquefaction
(TSL) SRC from low
conversion operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample No.
1943CB)
Wilsonville pilot plant,
two- stage liquefaction
(TSL) SRC from high
conversion operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample No.
1951CB)
151
98
111
112
111
112
123
101
126
116
116
(Continued)
829
-------
Table 339 (Continued)
Material Process Coal Type Value (wt %) Sample Description/Source Reference
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and
residua
SRC-I KY No. 9
KY No. 9
EDS
IL No. 6
IL No. 6
IL No. 6
IL No. 6
IL No. 6
89.61 Wilsonville pilot plant, 117
two-stage liquefaction
(TSL) SRC from low
conversion operation of
SRC hydrocracker (H-Oil)
unit (Wilsonville Run
No. 235, APCI Sample No.
1983CB)
89.37 Wilsonville pilot plant, 117
two-stage liquefaction
(TSL) SRC from high
conversion operation of
SRC hydrocracker (H-Oil)
unit (Uilsonville Run No.
235, APCI Sample No.
1991CB)
90.80 Hydrotreated 400°F+ 89
distillate from one tpd
pilot plantf
88.58 From first stage hydro- 99
cracking of UOP raw
4008F+ heavy distillate
Sample No. 3532-3* (UOP
Sample No. 3532-9)
87.53 From first stage hydro- 99
cracking of UOP raw
400^ heavy distillate
Sample No. 3532-2* (UOP
Sample No. 3532-4)
86.03 From second stage hydro- 99
cracking of UOP hydro-
cracked Sample No. 3532-4
86.72 From second stage hydro- 99
cracking of UOP hydro-
cracked Sample No. 3532-4
(UOP Sample No. 3532-18)
(Continued)
830
-------
Table 339 (Concluded)
Explanatory Notes
*The raw heavy distillate from the proposed SRC-I pilot plant will consist of a
29.0/71.0/0.0 weight percent blend of heavy distillate from the SRC, LC Finer and
coker units, respectively (Reference 100).
^Determined using solid fuel ASTM procedures.
fA blend of vacuum gas oil, raw process solvent and coker liquid having a
nominal boiling point of 400°F+.
§A full range (350 to 1000°F) distillate consisting of a blend of raw naphtha,
vacuum gas oil and raw process solvent.
#A blend of raw naphtha, vacuum gas oil, and raw process solvent having a
nominal boiling point of 400-1000°F.
**A blend of raw naphtha, vacuum gas oil, raw process solvent and coker liquid
having a nominal boiling point of 350°F+.
Part IX, General Comments section, Note 4, for summary of operating conditions
used.
Part IX, General Comments section, Note 5, for summary of operating conditions
used.
831
-------
Table 340. Hydrogen Content
Material Process Coal Type Value (wt %) Sample Description/Source Reference
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
SRC-1
KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
NA
NA
NA
Kentucky
7.58
7.15
8.67
7.50
7.03
5.75
6.03
5.73
5.80
5.0
5.2
5.8
(Continued)
832
Wilsonville pilot plant, 82
heavy distillate from SRC
unit (Run No. 220, APCI
Sample No. 1898CBJ*
Wilsonville pilot plant, 82
heavy distillate from SRC
unit (Run No. 225, APCI
Sample No. 1912CB)*
Wilsonville pilot plant, 82
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC-
Finer-29, APCI Sample No.
1942CB-1J*
Wilsonville pilot plant, 82
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample No.
1950CB)*
Wilsonville pilot plant, 82
heavy distillate from
Alcoa coker unit (APCI
Sample No. 1899CB)
Wilsonville pilot plant, 116
heavy SRC (Run No. 225,
APCI Sample No. 1914CB)
Wilsonville pilot plant, 116
heavy SRC (Run No. 220,
APCI Sample No. 1916CB)
Wilsonville pilot plant, 116
heavy SRC (Run No. 209,
APCI Sample No. 1917CB)
Wilsonville pilot plant, 119
heavy SRC
Wilsonville pilot plant, 118
heavy SRC, C-E Sample No.
2440-C
Wilsonville pilot plant, 118
heavy SRC, C-E Sample No.
2441-C
Heavy SRC 98
-------
Material Process Coal Type
Table 340 (Continued)
Value (wt %) Sample Description/Source Reference
Coal raw SRC- 1 NA
heavy
distillates
(heavy
fuel oils)
and
residua
5. 5* Wilsonville pilot plant,
(Catalytic Inc. Sample
No. SN-2651, Run No. 6,
Drum No. 120, Babcock
and Wilcox Sample No.
C-13994)
120
NA
SRC-II
IL No. 6
KY No. 9
and 14
Pittsburgh
No. 8
(Powhattan
Mine)
NA
NA
Kentucky
NA
KY No. 9
and 14,
IL No. 6
(King
River
Mine) and
Pitt-Seams
WV (Black-
ville No.
2 Mine)
S.g Wilsonville pilot plant, 120
heavy SRC (Catalytic Inc.
Sample No. SN-2651, Run
No. 70, Drum No. 97,
Babcock and Wilcox Sample
No. C-13995)
5.75 Wilsonville pilot plant, 145
heavy SRC
5.77 Ft. Lewis pilot plant, 83
heavy SRC
7.64 Ft. Lewis pilot plant, 101
heavy distillate
7.13 Ft. Lewis pilot plant, 84
heavy distillate
7.22 Ft. Lewis pilot plant, 84
heavy distillate
7.6-8.5 Ft. Lewis pilot plant, 98
482-860°F heavy
distillate
7.3 Ft. Lewis pilot plant 126
heavy distillate
8.77,9.54 400°F+ distillate, Ft. 86
Lewis pilot plant,
Chevron Sample No.
WOW-3751
(Continued)
833
-------
Material
Table 340 (Continued)
Process Coal Type Value (wt %) Sample Description/Source Reference
Coal raw EDS
heavy
distillates
(heavy
fuel oils)
and
residua
IL
No.
6
Wyodak
IL
IL
IL
IL
IL
IL
No.
No.
No.
No.
No.
No.
6
6
6
6
6
6
7
9
8
8
8
8
8
8
.70
.14
.66
.97
.26
.26
.05
.73
One tpd pilot plant,
heavy distil later
One tpd pilot plant,
heavy distillate*
One tpd pilot plant,
heavy distillate, as
receivedf
One tpd pilot plant,
rerun heavy distillate^
One tpd pilot plant,
heavy distil late*
One tpd pilot plant,
heavy distillate*
One tpd pilot plant,
heavy distil later
One tpd pilot plant,
89
101
123
123
99
99
99
99
IL No. 6
IL No. 6
IL No. 6
heavy distillate, UOP
Sample No. 3532-1*
8.87 One tpd pilot plant,
heavy distill ate, UOP
Sample No. 3532-2*
8.99 One tpd pilot plant,
heavy distillate, UOP
Sample No. 3532-3*
8.70 One tpd pilot plant,
350 to 1000'F distillate
blend from "typical"
run
IL No. 6
One tpd pilot plant,
350°F distillate blend
8.01
from "typical" run
(Continued)
99
99
99
99
834
-------
Table 340 (Continued)
Material Process Coal Type Value (wt %) Sample Description/Source Reference
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
EDS Wyodak 8.23 One tpd pilot plant,. 99
heavy distillate§
Wyodak 7.33 One tpd pilot plant, 99
heavy distillate**
Wyodak 7.05 One tpd pilot plant, 99
heavy distillate**
Wyodak 8.13 One tpd pilot plant, 99
350 to 1000'F distillate
blend from "typical"
run
Wyodak 7.05 One tpd pilot plant, 99
350'F+ distillate
from "typical" run
IL No. 6 4.32 One tpd pilot plant, 99
vacuum bottoms from
"typical" run (Run
A-l)
IL No. 6 4.54+0.20 One tpd pilot plant, 99
(Monterey vacuum bottoms, average
Mine) of three operating con-
ditions (8408F reactor
temperature; 15-40
minutes residence time)
IL No. 6 4.32+0.12 One tpd pilot plant, 99
(Monterey vacuum bottoms; operat-
Mine) ing conditions: 840*F
reactor temperature; 15-
40 minutes residence time,
average of ten yield
periods
IL No. 6 4.52+0.24 75 Ib per day development 99
(Monterey unit, vacuum bottoms;
Mine) average of six operating
conditions (800-880'F
reactor temperature;
25-100 minutes residence
time)
IL No. 6 4.45+0.13 75 Ib per day development 99
(Monterey unit, vacuum bottoms;
Mine) operating conditions:
8408F reactor temperature;
40 minutes residence
time, average of 21 yield
periods
(Continued)
835
-------
Table 340 (Continued)
Material Process Coal Type Value (wt %) Sample Description/Source Reference
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
EDS Wyodak 4.15 One tpd pilot plant, 99
vacuum bottoms from
"typical" run (Run
A-l)
Wyodak 4.41+0.24 One tpd pilot plant, 99
vacuum bottoms, average
of six operating condi-
tions (800-840°F reactor
temperature; 40-100
minutes residence time)
Wyodak 4.15+0.13 One tpd pilot plant, 99
vacuum bottoms; operating
conditions: 840°F reactor
temperature; 60 minutes
residence time, average
of seven yield periods
Wyodak 4.73+0.57 75 Ib per day development 99
unit, vacuum bottoms,
average of eight operating
conditions (800-880°F
reactor temperature,
25-100 minutes residence
time)
Wyodak 4.29+0.07 75 Ib per day development 99
unit, vacuum bottoms;
operating conditions: 880°F
reactor temperature, 25
minutes residence time,
average of six yield
periods
NA 12.04 One tpd pilot plant, 91
vacuum bottoms (DuPont
"Notebook" Sample No.
16928)
9.14 400-900°F heavy distil- 101
late from PDU
IL No. 6 8.0 Heavy distillate from 109
PDU, syncrude mode
Wyodak 9.0 Heavy distillate from 109
PDU, syncrude mode
W.KY 7.4 Heavy distillate from 109
No. 11 PDU, syncrude mode
(Continued)
836
H-Coal NA
-------
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
H-Coal IL No. 6
Wyodak
IL No.. 6
IL No. 6
Wyodak
IL No. 6
Wyodak
NA
NA
SRC-II Pittsburgh
No. 8
(Powhattan
Mine)
NA
SRC- I KY No. 9
Value (wi
9.48
10.54
7.6
7.13
8.01
5.47
5.56
8.33
9.14
8.04
7.9
6.55
Table 340 (Continued)
Value (wt %]_ Sample Description/Source Reference
PDU, heavy distillate 153
POD, heavy distillate 153
650-975°F heavy distil- 98
late from PDU, syncrude
mode
650-975'F heavy distil- 111
late from PDU Run 5,
Run 130-82, Period 29tf
650-975'F heavy distil- 112
late from PDU Run 6,
Run 130-83, Period 17?f
975"F+ residue from PDU 111
Run 5, Run 130-82, Period
29tt
975°F+ residue from PDU 112
Run 6, Run 130-83, Period
17ft
400^ fuel oil product 154
from PDU; operating
conditions: 851°F, 2500
psig
400"F+ fuel oil product 123
from PDU, rerun
0.4/1 middle/heavy 101
distillate blend, Ft.
Lewis pilot plant
Ft. Lewis pilot plant, 126
1/2 middle/heavy distil-
late blend
Wilsonville pilot plant, 116
two-stage liquefaction
(TSL) SRC from low
conversion operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample No.
1943CB)
(Continued)
837
-------
Table 340 (Continued)
Material Process Coal Type Value (wt %) Sample Description/Source Reference
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and
residua
SRC-I KY No. 9
KY No. 9
KY No. 9
EDS
IL No. 6
IL No. 6
IL No. 6
IL No. 6
IL No. 6
5.72 Wilsonville pilot plant, 116
two-stage liquefaction
(TSL) SRC from high
conversion operation of
Lummus LC-Finer unit
(Lumrnus Run No. 2-LC
Finer-27, APCI Sample No.
1951CB)
6.71 Wilsonville pilot plant, 117
two-stage liquefaction
(TSL) SRC from low
conversion operation of
SRC hydrocracker (H-Oil)
unit (Wilsonville Run
No. 235, APCI Sample No.
1983CB)
6.62 Wilsonville pilot plant, 117
two-stage liquefaction
(TSL) SRC from high
conversion operation of
SRC hydrocracker (H-Oil)
unit (Wilsonville Run No.
235, APCI Sample No.
1991CB)
8.60 Hydrotreated 400°F+ 89
distillate from one tpd
pilot plant!
10.85 From first stage hydro- 99
cracking of UOP raw
400°^ heavy distillate
Sample No. 3532-3# (UOP
Sample No. 3532-9)
11.85 From first stage hydro- 99
cracking of UOP raw
400°^ heavy distillate
Sample No. 3532-2* (UOP
Sample No. 3532-4)
13.39 From second stage hydro- 99
cracking of UOP hydro-
cracked Sample No. 3532-4
13.34 From second stage hydro- 99
cracking of UOP hydro-
cracked Sample No. 3532-4
(UOP Sample No. 3532-18)
(Continued)
838
-------
Material
Table 340 (Concluded)
Process Coal Type Value (wt %) Sample Description/Source Reference
Hydro H-Coal IL No. 6
treated
heavy
distillates
(heavy)
fuel oils) IL No. 6
and
residua
9.17 PDU, fuel oil mode, from
low severity hydrotreat-
ment of 375-100°F distillate
(DOE Sample No. 1617)
9.22 PDU, fuel oil mode, from
medium severity hydro-
treatment of 375-100°F
distillate (DOE Sample
No. 1618)
151
151
IL No. 6
9.67 PDU, fuel oil mode, from
high severity hydrotreat-
ment of 375-100°F
distillate (DOE Sample
No. 1619)
151
Explanatory Notes
*The raw heavy distillate from the proposed SRC- I pilot plant will consist of a
29.0/71.0/0.0 weight percent blend of heavy distillate from the SRC, LC-Finer and
coker units, respectively (Reference 100).
'''Determined using solid fuel ASTM procedures.
fA blend of vacuum gas oil, raw process solvent and coker liquid having a
nominal boiling point of 400°F"1".
§A full range (350 to 1000°F) distillate consisting of a blend of raw naphtha,
vacuum gas oil and raw process solvent.
#A blend of raw naphtha, vacuum gas oil, and raw process solvent having a
nominal boiling point of 400-1000°F.
**A blend of raw naphtha, vacuum gas oil, raw process solvent and coker liquid
having a nominal boiling point of 350°F+.
t^See Part IX, General Comments section, Note 4, for summary of operating conditions
used.
Part IX, General Comments section, Note 5, for summary of operating conditions
used.
839
-------
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Table 341A. Trace Elements Content (Qualitative Data)
Process Coal Type Trace Metals Present Sample Description/Source Reference
SRC-I*
Hydro-
treatd
distillates
(heavy
fuel oils)
and
residua
SRC-1
KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
KY No. 9
Major
Minor
Trace
Major
Mi nor
Trace
Major
Minor
Major
Minor
Trace
Major
Minor
Trace
Major
Minor
Trace
Major
Minor
Trace
Major
Mi nor
Major
Fe,Si
Al ,Ti,Ca,
K,Cu,Zn
Cr,Mn,Ni
Cu,As,Pb,Zr
Al,Si,K,Ti
Ca,Cr,Cu,
Zn.Ce
Ni,Ca,As,Pb,
Rb,St,Zr,Sr
Si,Fe
Ca,Ti,K,
Zn,Mn,Ni ,
Cr.Zr
Si,Ca,Fe
K,Ti,Zn,
Cr,Mn,Ni,Cu
Al,Si,K,
Ca,Ti,Fe
Zn
Cr,Mn,Ni,
Ce
Al,Ca,TisFe
Si.K.Zn
Cr,Mn,Ni,Ga,
As.Pb
Al,Si,K,Ca,
Ti.Fe.Zn
Zn,Ga,Si,
Cr,Mn,Ni
Fe,Si,Ti,
Al,Ca
K,V,Cr,Mn,
Ni,Cu,Zn,Zr
Ga,Ge,As,
Pb,Mo
Wilsonville pilot plant, 82
heavy distillate from SRC
unit (Run No. 220,
APCI Sample No. 1897CB)*
Wilsonville pilot plant, 82
heavy distillate from
SRC unit (Run No. 225,
APCI Sample No. 1912CB)*
Wilsonville pilot plant, 82
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample No.
1942CB-1)
Wilsonville pilot plant, 82
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample No.
1949CB)*
Wilsonville pilot plant, 116
heavy SRC unit (Run No.
225, APCI Sample No.
1914CB)
Wilsonville pilot plant, 116
heavy SRC (Run No. 220,
APCI Sample No. 1916CB)
Wilsonville pilot plant, 116
heavy SRC (Run No. 209,
APCI Sample No. 1917CB)
Wilsonville pilot 116
plant, two-stage
liquefaction (TSL) SRC
from low conversion
operation of Lummus
LC-Finer unit (Lummus
Run No. 2-LC finer-29,
APCI Sample No. 1943CB)
(Continued)
840
-------
Table 341A (Concluded)
Material Process Coal Type Trace Metals Present Sample Description/Source Reference
Hydro-
treated
distillates
(heavy
fuel oils)
and
residua
SRC-1
KY No. 9
Major
Minor
Trace
KY No. 9 Major
Minor
Trace
KY No. 9
Major
Mi nor
Trace
Fe,Sc,Ti,
Al, Ca
K,V,Cr,MN,
Ni ,Cu,Zn,Mo
Cu,Ga,Ge,Pb,
Rb,Y,Nb
Ni,Fe,Ti,Si,
Al, Ca
V,Cr,MN,Zn
Sr,Zr,Mo
S,Fe,Ti,Si,
Al, Ca
V,Cr,Mn,Na,
Mg
P,Ce,Ni,Cu,
Zn,Sr,Zr,Ga,
Ge,As,Pb
Wilsonville pilot plant, 116
two-stage liquefaction
(TSL) SRC from low con-
version operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1951CB)
Wilsonville pilot plant, 117
two-stage liquefaction
(TSL) SRC from low con-
version operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1983CB)
Wilsonville pilot plant, 117
two-stage liquefaction
(TSL) SRC from low con-
version operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample
No. 1991CB)
841
-------
Table 341B. Trace Elements Content (Quantitative Data) (ppmw)
00
-p.
ro
Material Process Coal Type Tt Na
heavy
distillates
and
heavy fuel
oils) and
residua
Ca
Pb Fe
Cd
Hn Mo, HI Zn Cu SI _Sn__ JB ___
Coal raw
heavy
distillate
blends
(heavy fuel
oils) and
residua
Hydro-
treated
heavy
distillates
(heavy fuel
oils) and
residua
SRC-II NA
KY No. 9
KY No. 9
ICY No. 9
NA
NA
NA
NA
a NO. «
Hyodak
U. KY It
IL No. 6
(Burning
Star
N1n«)
NA
NA
NA
NA
NA
7.1
2.7
0.35
MD(2)
18.6
t.O
NA
NA
NA
NA
a.s
NA
31.0
14.0
1.1
9
26
1.6
NA
NA
NA
NA
HA
NA
63.0
7.2
0.9
3
5.0
1.6
NA
NA
NA
NA
HA
0.4
25.0
9.1
2.1
11
5.07
2.5
NA
HA
NA
NA
NA
NA
2.3
0.23
0.07
0.2
1.3
NO
(0.02)
0.2
NA
NA
NA
NA
<1
0.54
0.1
<0.16
0.2
0.5
0.2
NA
NA
NA
NA
270
300
155
85.0
51
115
175
550
1.0
NA
NA
NA
NA
NA
<0.01
0.04
-------
Table 341B (Continued)
Ho Ag Co Al As Hj_ Sb Bt Be Bl Se _Sr___ W U St. La_ Ce_ P£ Nd Sa ^ Gd
NA
NA
NA
NA
NA
NA
NA
0.77
ND
0° (0.8)
CO
NO
(5)
ND
(0.02)
NA
NA
NA
NA
NA
NA
NA
<0.06
NA
NA
NA
NA
NA
NA
0.26
NA
NA
NA
<0.04
NO
(0.8)
20
0.1
NA
NA
NA
NA
NA
NA
NA
7.7
4.9
327
6.3
NA
NA
NA
2.1
i.a
NA
HA
0.006§
0.04
0.047
0.19
NA
NA
NA
0.02
NA
NA
NA
ND
NO
(0.03)
NO
(0.07)
ND
(0.04)
NA
NA
NA
0.066
NA
NA
NA
<0.3
NA
NA
NA
NA
NA
NA
0.14
NA
NA
NA
0.04
NA
NA
NA
NA
NA
NA
NA
NA
HA
HA
<0.006
NA
NA
NA
NA
NA
HA
NA
NA
NA
NA
<1.0
NA
NA
NA
NA
NA
NA
0.17
NA
NA
NA
0.003
NA
NA
NA
NA
NA
NA
0.96
NA
NA
NA
0.05
NA
HA
NA
NA
NA
NA
NA
NA
HA
NA
ND
NA
NA
NA
NA
NA
NA
0.54
NA
HA
NA
NO
NA
NA
NA
NA
NA
NA
0.45
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.10
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.4
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.045
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.27
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.11
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.02S
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.14
NA
NA
NA
NA
NA
NA
NA
NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
NA NA NA NA NA HA HA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
(Continued)
-------
Table 341B (Concluded)
Tb
NA
NA
NA
0.026
NA
HA
NA
NA
NA
NA
NA
NA
Ho
NA
NA
NA
0.030
NA
NA
HA
NA
NA
NA
NA
HA
Er
NA
NA
NA
0.065
HA
NA
NA
HA
NA
NA
HA
HA
Ta
NA
HA
NA
0.016
HA
HA
HA
NA
HA
HA
NA
NA
Yb
NA
NA
NA
0.094
1.8
HA
NA
NA
HA
HA
HA
HA
Lu
NA
HA
HA
0.014
HA
NA
HA
HA
NA
NA
NA
NA
Hf
HA
HA
HA
0.054
HA
HA
NA
NA
HA
HA
HA
HA
Ti
NA
NA
NA
0.043
NA
HA
HA
HA
HA
HA
HA
HA
Th
HA
HA
HA
0.19
HA
NA
HA
NA
NA
HA
NA
HA
Kb
NA
NA
NA
HA
<0.4
NA
NA
NA
HA
HA
NA
NA
Cs
NA
NA
NA
0.012
HA
NA
NA
HA
NA
NA
HA
NA
Br
NA
NA
HA
4.7
4.8
HA
HA
HA
HA
HA
NA
NA
Sample Description/Source
Ullsonvllle pilot plant.
heavy SRC (Run Ho. 225.
APCI Sample No. 1914CB)
Utlsonvllle pilot plant.
heavy SRC (Run No. 220.
APCI Sample No. 1916CB)
Ullsonvtlle pilot plant.
heavy SRC (Run Ho. 209.
APCI Sample Ho. 1917CB)
Ft. Lewis pilot plant,
heavy Sftd
Ft. Lewis pilot plant
Ft. Lewis pilot plant
Ft. Lewis pilot plant
POD. syncrude node
POU, syncrude Mode
POD, syncrude mode
Heavy distillate fron
116
116
116
146
84
84
125
(-JQ iiAiviiMiuiiMiuiuiiuinniwiiAiui ruu, »yni.iuue nuae 109
109
96
....... 96
POU (Ashland Oil Sample)
NAHANANAHAHAHANANANAHAHA —
Explanatory Notes
•The raw heavy distillate from the proposed SRC-I pilot plant wll) consist of a 29.0/71.0/0.0 weight percent blend of
heavy distillate from the SRC, LC-Flner and coker units, respectively (Reference 100).
Determined by flameless AAS. All other elements were determined by ICP.
{Determined by neutron activation analysis and X-ray fluorescence.
§ACPI method.
-------
Table 342. Ash Content (by Ultimate Analysis)
Material Process Coal Type Value (wt %) Sample Description/Source Reference
Coal raw SRC- I KY No. 9 0.10
heavy
distillates
(heavy
fuel oils) KY No. 9 0.05
and
residua
Wilsonville pilot plant,
heavy SRC (Run No. 225,
APCI Sample No. 1914CB)
Wilsonville pilot plant,
heavy SRC (Run No. 220,
APCI Sample No. 1916CB)
116
116
SRC-II
KY No. 9
NA
NA
NA
Pittsburgh
No. 8
(Powhattan
Mine)
NA
NA
KY No. 9
and 14
(King
River
Mine)
and
Pitt-Seam
WV (Black-
vine No.
2 Mine)
0.05
0.09
0.12
0.08
0.058
0.14
0.03
0.010
(Continued)
845
Wilsonville pilot plant,
heavy SRC (Run No. 209,
APCI Sample No. 1917CB)
Wilsonville pilot plant,
heavy SRC
Wilsonville pilot plant,
heavy SRC (Catalytic Inc.
Sample No. SN-2651, Run
No. 6, Drum No. 120,
Babcock & Wilcox Sample
No. C-13994)
Wilsonville pilot plant,
heavy SRC (Catalytic Inc.
Sample No. SN-2651, Run
No. 7D, Drum No. 97,
Babcock & Wilcox Sample
No. C-13995)
Ft. Lewis pilot plant,
heavy distillate
Ft. Lewis pilot plant,
heavy distillate
Ft. Lewis pilot plant,
heavy distillate
400°F+ distillate,
Lewis pilot plant,
Chevron Sample No.
WOW-3751
Ft.
116
119
120
120
101
84
84
86
-------
Material
Table 342 (Continued)
Process Coal Type Value (wt %) Sample Description/Source Reference
Coal raw SRC- 1 1
heavy
distillates EDS
(heavy
fuel oils)
and
residua
H-Coal
Coal raw SRC- 1 1
heavy
distillate
blends
(heavy
fuel oils)
NA
Wyodak
IL No. 6
IL No. 6
Wyodak
Wyodak
IL No. 6
NA
IL No. 6
Wyodak
W. KY
No. 11
IL No. 6
Pittsburgh
No. 8
(Powhattan
Mine)
NA
0.6
0.008
0.027
0.30
0.01
0.07
17.7
0.017
0.12
0.06
0.16
0.13
0.031
0.3
Ft. Lewis pilot plant
One tpd pilot plant,
heavy distillate*
One tpd pilot plant,
heavy distillate1'
One tpd pilot plant,
heavy distillate^
One tpd pilot plant,
heavy distillate*
One tpd pilot plant,
heavy distillate§
One tpd pilot plant,
residuum (flexicoker
vacuum bottoms)
400-900°F heavy distil-
late from PDU
Heavy distillate from,
PDU, syn crude mode
Heavy distillate from
PDU, syn crude mode
Heavy distillate from
PDU, syn crude mode
Heavy distillate from PDU
Run 8, syncrude mode
0.4/1 middle/heavy
distillate blend, Ft.
Lewis pilot plant
Ft. Lewis pilot plant,
126
101
99
99
99
99
124
101
109
109
109
109
126
1/2 middle/heavy distil-
late blend
(Continued)
846
-------
Material
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and
residua
Table 342 (Concluded)
Process Coal Type Value (wt %) Sample Description/Source Reference
SRC-1
KY No. 9
0.09
KY No. 9
0.08
KY No. 9
0.29
KY No. 9
0.17
Explanatory Notes
Wilsonville pilot plant, 116
two-stage liquefaction
(TSL) SRC from low
conversion operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample No.
1943CB)
Wilsonville pilot plant, 116
two-stage liquefaction
(TSL) SRC from high
conversion operation of
Lummus LC-Finer unit
(Lummus Lc-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample No.
1951CB)
Wilsonville pilot plant 117
two-stage liquefaction
(TSL) SRC from low
conversion operation of
SRC hydrocracker (H-Oil)
unit (Wilsonville Run No.
235, APCI Sample No.
1983CB)
Wilsonville pilot plant 117
two-stage liquefaction
(TSL) SRC from low
conversion operation of
SRC hydrocracker (H-Oil)
unit (Wilsonville Run No.
235, APCI Sample No.
1991CB)
*A full range (350 to 1000'F) distillate consisting of a blend of raw naphtha,
vacuum gas oil and raw process solvent.
*A blend of raw naphtha, vacuum gas oil and raw process solvent having a
nominal boiling point of 400-1000*F.
fA blend of vacuum gas oil, raw process solvent and coker liquid having a
nominal boiling point of 4008F+.
§A blend of raw naphtha, vacuum gas oil, raw process solvent and coker liquid
having a nominal boiling point of 350*F+.
847
-------
Table 343. Saturates, Olefins and Aromatics Content
Material Process Coal Type Value (wt %) Sample Description/Source Reference
A. Saturates
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
SRC-I KY No. 9
KY No. 9
KY No. 9
KY NO. 9
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
Hydro-
treated
heavy
distillates
(heavy fuel
oils) and
residua
H-Coal
NA
IL No. 6
Wyodak
IL No. 6
IL No. 6
9.49
2.06
47.34
16.90
7.9
12.6
28.8§
(vol %)
54.8§
(vol %)
Wilsonville pilot plant,
heavy distillate from SRC
unit (Run No. 220, APCI
Sample No. 1898CB)*
Wilsonville pilot plant,
heavy distillate from SRC
unit (Run No. 225, APCI
Sample No. 1912CB)*
Wilsonville pilot plant,
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC-
Finer-29, APCI Sample No.
1942CB-1)*
Wilsonville pilot plant,
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample No.
1950CB)
PDU, heavy distillate1"
PDU, heavy distillate1"
82
82
From first stage hydro-
cracking of UOP raw
400°F+ heavy distillate
Sample No. 3532-3#
(UOP Sample No. 3532-9)
From first stage hydro-
cracking of UOP raw
400°F+ heavy distillate
Sample No. 3532-2*
(UOP Sample No. 3532-4)
(Continued)
848
82
82
153
153
99
99
-------
Table 343 (Continued)
Material Process Coal Type Value (wt %) Sample Description/Source Reference
B. Aromatics
Coal raw SRC-I
heavy
distillates
(heavy
fuel oils)
and
residua
KY No. 9
KY No. 9
KY No. 9
KY No. 9
H-Coal
NA
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
NA
40.54*
47.40**
42.07**
69.60**
IL No. 6
IL No. 6
Wyodak
NA
86§
(vol %)
76.8
74.2
91
90
Wilsonville pilot plant, 82
heavy distillate from SRC
unit (Run No. 220, APCI
Sample No. 1898CBJ*
Wilsonville pilot plant, 82
heavy distillate from SRC
unit (Run No. 225, APCI
Sample No. 1912CB)*
Wilsonville pilot plant, 82
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC-
Finer-29, APCI Sample No.
1942CB-1)*
Wilsonville pilot plant, 82
heavy distillate from
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample No.
1950CB)*
One tpd pilot plant, 123
heavy distillate; as
received1"1"
PDU, heavy distillate1' 153
PDU, heavy distillate1" 153
400°F+ fuel oil product 123
from PDU, as received
400°F+ fuel oil product 123
from PDU, rerun
(Continued)
849
-------
Table 343 (Concluded)
Material Process Coal Type Value (wt %) Sample Description/Source Reference
B. Aromatics
Hydro-
treated
heavy
distillates
(heavy fuel
oils) and
residua
(Continued)
IL No.
IL No. 6
71.2 From first stage hydro-
(vol %) cracking of UOP raw
400°F+ heavy distillate
Sample No. 3532-3#
(UOP Sample No. 3532-9)
45.2 From first stage hydro-
(vol %) cracking of UOP raw
400°F+ heavy distillate
Sample No. 3532-2*
(UOP Sample No. 3532-4)
99
99
Explanatory Notes:
*The raw heavy distillate from the proposed SRC-I pilot plant will consist of a
29.0/71.0/0.0 weight percent blend of heavy distillate from the SRC, LC-Finer
and coker units, respectively (Reference 100).
'''Additional data, nonhydrocarbons 15.3 wt %.
fAdditional data, nonhydrocarbons 13.2 wt %.
§Flame ionization analysis.
#A blend of raw naphtha, vacuum gas oil, and raw process solvent having a
nominal boiling point of 400-1000°F.
**Determined via APCI adsorption chromatography method.
blend of vacuum gas oil, raw process solvent and coker liquid having a
nominal boiling point of 400°F+.
850
-------
Table 344. Detailed Hydrocarbon Class/Compound Analysis
00
01
Material
Coal raw
heavy
distillates
(heavy fuel
oils) and
residua
Value
Process Coal Type Compound Class
SRC- 1 KY No. 9
9H-carbazole*.t
A Methyl phenanthrene
An Ethyl phenanthrene
H n it
Pyrene
1-Phenyl naphthalene
A Methyl pyrene
n n n
Docosane
Trlcosane
Tetracosane
Pentacosane
Hexacosane
Heptacosane
Nonacosane
TMacontane
Hentrlacontane
Dotriacontane
Trltriacontane
(Continued)
(wt %) Sample Description/Source Reference
Wllsonvllle pilot plant, 82
heavy distillate from
SRC unit (Run No. 220,
APCI Sample No. 1898CB)f
-------
Table 344 (Continued)
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Value
Process Coal Type Compound Class
(wt %) Sample Description/Source Reference
00
in
SRC-I KY No. 9 Phenanthrene*»t
9H-Carbazole
A methylphenanthrene
4H-Cyclopenta(def)
Phenanthrene
2-Phenyl-Naphthalene
An-Ethyl-Phenanthrene
A Dimethyl-Phenanthrene
Fluoranthene
Acephenanthrylene
Pyrene
1-Phenyl-Naphthalene
1-Methyl-Pyrene
Docosane
A Terphenyl
Tricosane
Benzo(b)Naphtho-
(2,l-d)Thiophene
Chrysene
Tetracosane
Pentacosane to
Tetratriacontane
Wilsonville pilot plant,
heavy distillate from
SRC unit (Run No. 225,
APCI Sample No. 1912CB)f
82
(Continued)
-------
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Value
Process Coal Type Compound Class
Table 344 (Continued)
(wt %) Sample Description/Source Reference
SRC-1
NA
00
in
CO
-Octane ND
-Nonane ND
-Decane ND
-Undecane 0.0004
-Dodecane 0.0010
-Tridecane 0.0008
-Tetradecane 0.0007
-Pentadecane 0.0012
-Hexadecane 0.0008
-Heptadecane 0.0003
-Octadecane 0.0003
-Nonadecane 0.0022
-Eicosane ND
-Heneicosane ND
-Docosane ND
-Tricosane ND
-Tetracosane ND
-Pentacosane ND
-Hexacosane 0.0005
-Heptacosane 0.0002
-Octacosane 0.0002
-Nonacosane 0.0001
-Triacontane 0.0001
-Hentriacontane 0.0001
-Dotriacontane ND
-Tritriacontane ND
Ft. Lewis pilot plant,
heavy SRC
146
(Continued)
-------
Table 344 (Continued)
Value
Material Process Coal Type Compound Class
Coal raw
heavy
distillates
(heavy fuel
oils) and
residua
H-Coal IL No. 6 X Class§
00
tn
Monoaromatics
- 6 Alkyl Benzenes
- 8 Naphthene Benzenes
-10 Oi-Naphthene Benzenes
Diaromatics
-12 Naphthalenes
-14 Acenaphthenes,
Biphenyls
-16 Fluorenes
Triaromatics
-18 Phenanthrenes
-20 Naphthene
Phenanthrenes
Tetraaromatics
-22 Pyrenes,
Fluoranthrenes
-24 Chrysenes
Pentaaromatics
-26 Benzofluoranthrenes
-28 Perylenes
-30 Dibenzanthracenes
(wt %) Sample Description/Source Reference^
0.1
8.6
6.5
7.9
12.6
16.3
9.8
2.5
3.7
0.1
0.2
0.2
0.1
Heavy distillate from
PDU, syncrude mode
109
(Continued)
-------
Table 344 (Continued)
Value
Material Process Coal Type Compound Class
Coal raw
heavy
distillates
(heavy fuel
oils) and
residua
H-Coal IL No. 6 X Class§
00
en
en
Monoaromatics
- 6 Alkyl Benzenes
- 8 Naphthene Benzenes
-10 Di-Naphthene Benzenes
Diaromatics
-12 Naphthalenes
-14 Acenaphthenes,
Biphenyls
-16 Fluorenes
Triaromatics
-18 Phenanthrenes
-20 Naphthene
Phenanthrenes
Tetraaromatics
-22 Pyrenes,
Fluoranthrenes
-24 Chrysenes
Pentaaromatics
-26 Benzofluoranthrenes
-28 Perylenes
-30 Dibenzanthracenes
(wt %) Sample Description/Source Reference
0.5
3.9
4.0
2.4
6.4
9.8
7.8
3.9
6.1
1.6
1.4
0.5
0.0
Heavy distillate from
POD, syncrude mode
109
(Continued)
-------
Table 344 (Continued)
Value
Material Process Coal Type Compound Class
Coal raw
heavy
distillates
(heavy fuel
oils) and
residua
H-Coal IL No. 6 X Class§
00
tn
a\
Monoaromatics
- 6 Alkyl Benzenes
- 8 Naphthene Benzenes
-10 Di-Naphthene Benzenes
Diaromatics
-12 Naphthalenes
-14 Acenaphthenes,
Biphenyls
-16 Fluorenes
Triaromatics
-18 Phenanthrenes
-20 Naphthene
Phenanthrenes
Tetraaromatics
-22 Pyrenes,
Fluoranthrenes
-24 Chrysenes
Pentaaromatics
-26 Benzofluoranthrenes
-28 Perylenes
-30 Dibenzanthracenes
(wt %) Sample Description/Source Reference
0.0
2.7
2.0
0.3
5.3
9.3
9.3
6.9
13.2
3.6
2.2
0.3
0.0
Heavy distillate from
PDU, syncrude mode
109
(Continued)
-------
Table 344 (Concluded)
Value
Process Coal Type Compound Class
NA
NA
Material Process Coal Type Compound Class (wt %) Sample Description/Source Reference
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and
residua
Explanatory Notes
*The following compound types were present. Quantitative data not available.
"^Compounds listed are the twenty most prevalent compounds present in the sample.
fThe raw heavy distillate from the proposed SRC-I pilot plant will consist of a 29.0/71.0/0.0 weight
percent blend of heavy distillate from the SRC, LC-F1ner and coker units, respectively (Reference 100).
§X - from the molecular formula: CnH2n + x«
-------
Table 345. Additional Detailed Individual Hydrocarbon Compound Analysis
Mass
Spec.
Peak Molecular
Material Process Coal Type Number Height
Coal raw
heavy
distillates
(heavy
fuel oils)
and residua
SRC- 1
HA
CO
01
CO
1
2
3
4
5
6
7
9
10
11
12
16
17
18
19
20
21
24
25
26
27
30
32
34
35
128
142
142
154
156
156
170
154
166
168
168
180
182
182
180
180
180
182
182
178
194
194
194
204
194
192
Concentration
Form* la
CIQTIQ
CU.HIQ
Cj 1"10
C12H10
C12H12
C12JJ12
CI^HIQ
C}3^10
{•13^12
C13H12
C14H12
C14H14
C14H12
C14H12
Cl4«12
C14HU
C14H10
C15H14
C15JJ14
CitHi?
C15H12
Cl5«12
(parts per
thousand)
NA
NA
NA
0.10
NA
NA
NA
NA
0.56
0.16
0.10
0.27
0.09
0.15
0.34
0.30
0.63
0.31
0.73
27.00
0.47
0.18
0.25
0.30
4.30
6.40
Possible Compound Types
Naphthalene
2-Methy(naphthalene
1-Methylnaphthalene
Biphenyl
2-Ethylnaphthalene
2.6-Oimethy(naphthalene
and propylnaphthalene
Acenaphthene
Fluorene
Allylnaphthalene*
Allylnaphthalene*
9-Methylfluorene
1,1-Oiphenylethane
2.2'-Oimethylbiphenyl.
2.3'-Diinethylbiphenyl.
2.4'-Otiiiethylbiphenyl.
2*Methyldiphenylnethane.
4-Hethyldtphenylinethane
9,10-Oihydroanthracene
2-MethyIfluorene
1-MethyIfluorene
3,4'-Di«ielhylb(phenyl
Ethylbiphenyl'
Phenanthrene
Ethylfluorene*
EthylftuoreneJ
£thy Ifluorene'
1-Phenylnaphthalene
3-Hethylphenanthrene
2-MethyIphenanthrene
Sample Description/Source Reference
Uilsonville pilot plant,
heavy SRC
147
(Continued)
-------
Table 345 (Continued)
00
in
10
Material Process
Coal ra« SRC- I
heavy
distillates
(heavy
fuel oils)
and residua
Mass
Spec.
Peak
Coal Type Number
NA 36
37
38
45
46
47
48
49
50
51
53
54
55
56
57
58
59
60
Molecular
Weight
190
192
192
206
206
206
206
206
206
202
208
202
204
22Q
218
218
218
220
Formula
CisHiO
<45Hl2
CISHII
C16H14
C16H14
C16H14
Cl6»»14
CI&HU
C1&H14
Cj6HlQ
C16Hi6
Ci6Hi6
C16H12
CI/HU
C17H14
C17H14
C17HU
C17H16
Concentration
(parts per
thousand)
0.69
1.55
1.79
0.99
0.64
0.89
0.80
0.65
0.96
17.20
0.99
32.00
3.60
0.60
0.26
0.02
0.51
0.23
Possible Compound Types
4H-Cyclopenta(def)
phenanthrene
9-Hethylphenanthrene
1-Methylphenanthrene
9-Ethylphenanthrene
2-Ethylphenanthrene
3.6-Dimethylphenanthrene
2,7-Dimethylphenanthrene
Ethylanlhracenet or
ethy Iphenanthrene'
Ethylanthracene^ or
ethy Iphenanthrene'
Fluor anthene
2-Phenyl-1.2.3.4-tetrahydro-
naphthalene
Pyrene
Dtbenzoheptafulvene
PropylphenanthreneT or
propylanthracepef
Ethyl-Ci6H12J.|
Ethyl-Ci6H12'-|
Ethyl-Ci6Hi2t.$
9-Methy 1 -10-ethy Iphenan-
Sample Description/Source Reference
Uilsonvflle pilot plant.
heavy SRC
147
threne
(Continued)
-------
Table 345 (Continued)
Haterlal Process
Coal r*w
heavy
distillates
(heavy
fuel oils)
and residua
SRC-1
NA
00
CTt
O
Mass
Spec.
Peak
Huafaer
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
82
84
85
86
88
89
Concentration
Molecular (parts per
Weight
218
218
216
220
216
216
216
228
216
216
232
232
232
230
230
230
230
230
230
232
232
228
228
242
242
Fomula thousand)
C17«14
C|;Hi2
C}7Hj(
C\jH\2
Ci;Hj2
Cj;Hi2
'17^14
C17H12
C17H12
C"H"
CjgHj^
Cia"l4
C,8HU
CigHj4
Ci&Hj4
*-18HU
Cl7Hl6
CigHi?
CjgHij
C,9HM
C19H,4
(Continued)
NA
0.52
2.88
0.32
4.20
2.98
a. 10
3.40
4.30
2.72
0.86
0.67
0.61
0.17
0.24
2.61
1.09
2.62
0.66
1.10
0.31
2.43
9.60
0.24
1.87
Possible Coapound Types
Ethyl-C16Hi2M
Ethyl-CigHi2i>§
Benzo(a)fluorene
Propylphenanthrenef or
propylanthracenef
Benzo(b)fluorene
Benzofluorene
4-Hethylpyrene
Propylphenanthrenef or
propylanthracenef
2-Methylpyrene
1-Hethylpyrene
Propyl-Ci5Hi2f§
Propyl-C15Hi2f|
Propyl-Ci5Hi2f5
5,12-01hydronaphthacen*
Ethylpyrene* or
ethylfluoranthene^
Ethylpyrene* or
ethylfluoranthene*
1-Ethylpyrene
Ethylpyrene* or
ethylfluoranthene*
Ethylpyrene^ or
ethylfluoranthene'
Propy1-C16H12t.§§
Benz(a)anthracene
Trlphenylene and chrysene
Propylpyrenef or
propy1f1uoranthenef
2-Hethyltrlphenylene
Sample Description/Source Reference
Wllsonvllle pilot plant.
heavy SRC
147
-------
Table 345 (Continued)
00
CTt
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and residua
Mass
Spec.
Peak
Process Coal Type Number
SRC- I HA 90
92
93
94
95
96
97
98
99
100
101
102
103
104
105
106
107
108
109
110
111
112
113
114
115
116
117
118
119
120
121
122
123
124
Molecular
Height
258
242
242
242
242
242
242
242
242
254
256
254
254
256
256
256
256
256
256
256
252
252
268
252
252
252
266
266*
280
266
266
266
266
266
266
Foray la
C20H18
Cl9"l4
CgH14
CieHM
Ci9H,4
C19H14
Cl9»14
CuHu
CuHu
C20H14
C20Hl6
C2QH14
CzflHja
C20"16
C20"16
C20H16
C20Hi6
C20Hl6
C20"16
C20Hifi
C20Hi2
C20Hi2
C2I"16
C20M12
C20H12
C20H12
C21«14
C21H14
C22"16
C21H14
C2i"u
C21"14
C2lHl4
C21H14
C21H14
Concentration
(parts per
thousand)
0.56
0.78
0.43
0.63
3.10
2.21
1.91
1.49
0.67
0.53
0.81
1.06
0.46
0.46
0.52
1.30
0.63
0.91
0.64
5.70
0.75
0.40
3.60
3.40
0.91
0.48
1.82
2.31
1.96
1.11
1.77
2.47
(Continued)
Possible Compound Types
HA
ll-Hethy)benz(a)anthracene
2-Hethylbenzja}anthracene
l-Hethylben*(a)anthracene
1-Hethyltrlphenylene
3-Hethylchrysene
12-Hethy 1 benz ( a (anthracene
4-Hethy 1 benz (a)anthracene
or 5-nethylchrysene
6-Hethylchrysene or
4-oethylchrysene
Phenylphenanthrene
Ethyl-ClaHi2t'
2.2'-B1naphthyl
Pheny 1 phenanthrene
Ethyl-C18M12t<
Ethyl-C18M,2t»
Ethyl-C18H12t«
Ethyl-C,flH12tl
Ethyl-C18H12t«
Ethyl-C18H12tl
Ethyl-Cj8Hi2tl
Benzo(1)fluoranthene
Benzofluoranthene
Methylblnaphthyl
Benzo(e|pyrene
Benzo(a)pyrene
Perylene
Methyl-C20Hi2«
Methyl-C20Hi2*
Ethyl -C20Hi2*. *
Methyl-C20Hi2*
MethyI-C20H12*
Methyl-C20Hi2*
Methyl-C20Hi2*
Methyl -C20Hi2*
Methyl -C20H12*
Sample Oescrlptton/Source Reference
WlUonvllle pilot plant.
heavy SRC
147
-------
Table 345 (Continued)
00
en
ro
Material Process
Coal raw SRC-1
heavy
distillates
(heavy
fuel oils)
and residua
SRC- 1
Mass
Spec.
Peak
Coal Type Number
NA 125
126
127
128
129
130
131
132
133
134
136
136
137
138
139
140
141
142
143
144
145
146
HA Iff
2
3
4
5
6
7
8
9
10
11
12
13
14
Molecular
Height
268
266
266
282
280
280
280
280
280
280
280
268
276
278
278
276
276
292
292
292
292
290
226
240
254
268
282
296
310
324
338
352
366
380
394
408
Formula
C2lHu
C21H14
C21><14
C22Hia
C22H16
C22Hi6
C«Hi6
C22M16
C22HU
C22H16
C22Hl6
C22H14
C22H12
C22HU
C22H14
C22j|i2
C23H16
C23H16
C23H16
C23"14
-Cjj
-Cj7
-Cj8
-Cl9
-C2Q
-C2,
-C22
-C23
-C24
-C25
-C26
-C27
-c28
-C29
Concentration
(parts per
thousand)
0.62
0.60
0.54
0.44
NA
NA
1.49
0.67
0.39
0.46
0.52
1.12
0.40
NA
2.23
0.67
0.279
0.89
0.84
1.81
NA
HA
HA
HA
NA
NA
NA
HA
NA
NA
NA
NA
HA
NA
NA
Possible Compound Types
Methyl cholanthrenc
Methy1-C2nHi2"
Methyl-C2oHi2**
Ethyl-C2n.Hi2*«*
Ethyl-C2oH)2J'
Ethyl -C20Hi2J."
Ethyl -C20Hi2t««
Ethyl -C2flHi2^**
Ethyl-C20Hi2t"
pibenzanthracene
TT
Benzo(b)chrysene
Pjcene
tt
Methyl -C22Hj4H
Methyl -C22H14ff
Methyl-C22Hl4tt
Methyl -C22H14H
Methyl-C22H14tt
Methyl-C22U12H
NA
NA
NA
NA
NA
HA
NA
NA
NA
NA
NA
NA
NA
NA
Saaple Description/Source Reference
Ullsonvtlle ptlot plant. 147
heavy SRC
(Continued)
-------
Table 345 (Continued)
Material Process Coal Type
Coil rait
he ivy
distillates
(heivy
fuel otts)
and residua
SRC-11 HA
CO
cr>
co
Mass
Spec.
Peak
Number
!•••
2
3
4
S
6
7
8
9
10
11
12
13
14
IS
16
1?
18
19
20
21
22
23
24
25
26
2?
Molecular
Height
142
156
170
154
154
168
166
168
168
184/180
182
182
180/182
198/194
184
182
196
178
196
204
192
204
206
202
202
216
216
216
230
228
228
Fonaula
NA
MA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
HA
NA
HA
HA
NA
HA
NA
HA
NA
NA
NA
NA
Concentration
(parts per
thousand)
NA
NA
NA
NA
NA
HA
NA
NA
NA
HA
NA
NA
NA
NA
NA
NA
NA
NA
NA
HA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Possible Compound Types
Cj-naphthalene
Cj-naphthalene
C)-naphthilene
blphenyl
acenophthene
dlbenzofuran
fluorene
Ci-blphenyl/Ci-acenaphthen*
Ci-btphenyl/Ci-aceniphthene
C4-naphthalene/Ci-fluorene
Ci-dlbenzofuran
C2-btphenyl
Ci-fluorene/Cj-blphenyl
Cs-naphthalene/Cj-fluorene
dlbenzothiophene
tetrahydrophenanthrene
Ci-blphenyl
phenanthrene
C3-b1pheny)/
Ci-dtbenzothtophene
1-pheny1 naphtha)ene
Cj-phenanthrene
2-phenylnaphthilene
C?-phenanthren«
fluoranthene
pyrene
not tdent(fled
benzoLaJfluorene
benzo[b]fluorene
Cj-pyrene/
Ci-fluoranthene
C2-pyrene/
C2-f)uoranthene
benz[ajanthracene
chrysene
Sample Description/Source Reference
UtlsonvtlU pilot pi int.
heavy SRC
132
(Continued)
-------
Table 345 (Continued)
Material
Coal r*w
heavy
distillates
(heivy
fuel oils)
ind residua
Mass
Spec.
Peak Molecular
Nuaber Height
SRC-1
NA
28
29
30
S«C-11 NA
00
a\
242
252
252
NA
NA
NA
Concentration
(parts per
thousand)
NA
NA
NA
Possible Compound Types
C|-benz[a]anthracene/
Cj-chrysene
benzofluoranthene
benzopyrene
Hoi. wt
Compound
Aliphatic hydrocarbon fraction A-l
n-C16
n-C2Q
n-C2i
n-C22
n-C23
n-C24
n-C26
n-C2;
n-C28
n-C29
PAC fraction A-2
Cj-naphthalene
C2-naphthalen«
Cv-naphthalen*
biphenyl
acenaphthene
dtbenzofuran
fluorene
Ci-btphenyl/C}-acenaphthene
Ci-blphenyl/Cj-acenaphthene
Cj-naphthalene/Ci-fluorene
Ci-dtbenzofuran
C2-b1phenyl
Ci-fluorene/C2-b1phenyl
Cc-haphthalene/C2-f1uorene
dibenzothiophene
tet rahydrophenanthrene
Ci-blphenyl
pnenanthrene
Sanple Description/Source Reference
Wllsonvllle pilot plant. 147
heavy SRC
Pentafluoropropyl
Parent
226
240
254
268
282
296
310
324
338
352
366
380
394
408
142
156
170
154
154
168
166
168
168
184/180
182
182
180/182
198/194
184
182
196
178
Derivative
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Ft. Lewis pilot plant,
heavy distillate
132
(Continued)
-------
Material Process
Mass
Spec
Peak
Coal Type Muaber
Coal raw
heavy
distillates
(heavy
fuel oils)
and residua
SRC-11 NA
00
Ctt
Oi
Coal rait
heavy
distillate
blends
(heavy
fuel oils)
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and
residua
NA
NA
Table 345 (Concluded)
wt
Coapound
PAC Fraction A-2
Cj-bepheny1/Ci-d1benzoth t ophene
1-phenylnaphtnalent
C|-phenanthrene
2-phenylnaphthalene
C?-phenanthrene
fluoranthene
pyrene
not identified
benzo[a]fluorene
benzo[b]fluorene
Cj-pyrene/C|-fluoranthene
Cj-pyrene/Cj-fluoranthene
benz[a]anthraceni
chrysene
Ci-benz[a]anthracene/Cj-chrysenes 242
benzofluoranthene
benzopyrene
"Penfa fTuoropropyT
Parent Derivative
196
204
192
204
206
202
202
216
216
216
230
228
228
242
252
252
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Saaple Description/Source Reference
Ft. Lewis pilot plint.
heavy distillate
132
Explanatory Notes:
•Good visual fit MS shown to standard spectrum of allylnaphthalene. However, aethylacenaphthene cannot be ruled out tn absence of standard
spectrua
'May also be dinethyI
{May also be trlaethyl or ethylaethyl
§Posslble isoaers of CjgHiz Include the following: 4H-cyclopenta(def)-phenanthrene, benzacenaphthene, or phenyl naphthalene
'Possible isoaers of C\$H\2 Include: chrysene. b«nz(a)anthracene. and trlphenylene
"Possible Isoaers of CjoHiz Include: benzofluoranthene. benzo(e)pyrene, benzo(a)pyrene, and, perylene
ttConpounds with HU 276 could be Isouters of the following: tndenopyrene, Indenofluoranthene. aceperylene. phenanthrofluorene, acenaph-
thacenaphylene, dlbenzofluoranthene. benzoaceperylene. or acefluoranthylene
ffPossible Isoaers of C^HU Include: dlbenzanthracene, benzo(b)chrysene, and ptcene
§§Detera1ned via - alumina - silicic acid fracttonatlon followed by GC-HS analysis
"Aliphatic-hydrocarbon fraction
•••Polycycllc aronatlc coapound fraction
-------
Table 346. Additional Hydrocarbon Class Analysis Obtained by Solvent Fractionatlon*
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
SRC-I KY No. 9
CO
cr>
SRC-11
KY No. 9
KY No. 9
Kentucky
Kentucky
KY No. 9
and 14,
IL No. 6
(King
River
Mine)
and
Pitt-Seams
WV (Black-
ville No.
2 Mine)
3.7
63.3
33.0
0.0
Value
011s
Asphaltenes
Preasphaltenes
Residue
Oils
Asphaltenes
Preasphaltenes
Residue
011s
Asphaltenes
Preasphaltenes
Residue
011s 4-6
(propane solubles)
Oils 99+
(propane solubles)
(wt %) (mol wt) Sample Description/Source Reference
Hot heptane
asphaltenes
Benzene
Insolubles
180
570
1360
NA
11.7
62.0
26.3
0.0
5.0
65.7
27.3
0.0
220
490
1840
NA
560
480
NA
NA
NA
NA
Wilsonville pilot plant,
heavy SRC (Run No. 225,
APCI Sample No. 1914CB)
Wilsonville pilot plant,
heavy SRC (Run No. 220,
APCI Sample No. 1916CB)
Wilsonville pilot plant,
heavy SRC (Run No. 209,
APCI Sample No. 1917CB)
Heavy SRC
Ft. Lewis pilot plant,
482-860°F heavy distillates
116
116
116
0.2200 NA
<0.03 NA
400°F+ distillate,
Lewis pilot plant,
Chevron Sample No.
WOW-3751
Ft.
98
98
86
(Continued)
-------
Table 346 (Continued)
00
cr>
Material Process
Coal raw H-Coal
heavy
distillates
(heavy
fuel oils)
and
residua
Coal raw NA
heavy
distillate
blends
(heavy
fuel oils)
Coal Type
IL No. 6
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and
residua
SRC-I
KY No. 9
Value
Asphaltenes
Toluene
Insolubles
IL No. 6 Asphaltenes
Toluene
Insolublesf
Oils
Asphaltenes
Preasphaltenes
Residue
(wt %)
36.40
0.29
12.8
0.17
(mol wt) Sample Description/Source Reference
64.6
24.0
11.4
NA
NA
NA
NA
NA
NA#
NA#
NA#
NA
650-975°F heavy distillate
from PDU Run 5, Run
130-82, Period 29+
650-975°F heavy distillate
from PDU Run 6, Run 130-83,
Period 17§
111
112
Wilsonville pilot plant,
two-stage liquefaction
(TSL) SRC from low
conversion operation of
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-29, APCI Sample No.
1943CB)
116
(Continued)
-------
CO
CTi
00
Material Process Coal Type
Table 346 (Concluded)
Value (wt %) (mol wt) Sample Description/Source Reference
Wilsonville pilot plant,
two-stage liquefaction
(TSL) SRC from high
conversion operation of
Lununus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample No.
1951CB)
Hydro- SRC-I KY No. 9 Oils 60.3 NA Wilsonville pilot plant, 116
treated Asphaltenes 28.9 NA
heavy Preasphaltenes 10.8 NA
distillates Residue NA NA
(heavy
fuel oils)
and
residua
Explanatory Notes:
*Sample obtained via solvent fractionation methods are defined as follows: The asphaltene fraction is
that portion of certain crude oil distillation fractions that is insoluble in n-pentane but soluble
in benzene. The carbene fraction is that portion of the crude oil distillation fractions that is
insoluble in benzene but soluble in carbon disulfide; the carboid fraction is that portion that is
insoluble in both benzene and in carbon disulfide. Resins are polar materials in maltenes (that por-
tion of the crude oil distillation fractions that is soluble in n-pentane) that are retained by adsorbents
in a standard SARA technique recycle chromatographic column. Oils are resins-free maltenes (Reference
59, 82).
Part IX, General Comments section, Note 4, for summary of operating conditions used.
^Precipitated in toluene prior to asphaltenes
§See Part IX, General Comments section, Note 5, for summary of operating conditions used.
#Not complete.
-------
Table 347. Elemental Composition Data for Hydrocarbon Classes Obtained
by Solvent Fractionation
Material Process Coal Type Value (wt %} Sample Description/Source Reference
Coal raw
distillates
(heavy fuel
oils) and
residua
H-Coal IL No. 6
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
NA
Oil
carbon 89.54
hydrogen 9.18
nitrogen 0.45
sulfur <0.05
oxygen
0.83*
Resin
carbon 89.39
hydrogen
nitrogen
sulfur
oxygen
7.
1.
07
13
0.14
2.27*
Asphaltene
carbon 86.88
hydrogen 5.91
nitrogen 1.61
sulfur 0.64
oxygen 4.96*
Carbene
carbon
hydrogen
nitrogen
sulfur
oxygen
87.18
5.05
1.93
0.94
4.90*
Carboid
carbon 86.09
hydrogen 4.87
nitrogen
sulfur
oxygen
1.51
0.97
6.56*
(Continued)
400°F+ fuel oil product
from POD; operating
conditions: 851°F, 2500
psig.
154
869
-------
Table 347 (Concluded\
Material
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and
residua
Explanatory Note
*By difference
Process Coal Type
NA
Value (wt %) Sample Description/Source Reference
870
-------
Table 348. Nitrogen-, Oxygen- and Sulfur-Containing Compounds*
00
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
SRC-I KY No. 9
KY No. 9
KY No. 9
KY No. 9
Value
Compound Class
Phenols
Phenols
Phenols
Phenols
Wt % Sample Description/Source Reference
44.77
40.56
3.40
6.90
Wilsonville pilot plant,
SRC unit (Run No. 220,
APCI Sample No.
Wilsonville pilot plant,
SRC unit (Run No. 225,
APCI Sample No. 1912CB)*
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lununus Run No. 2-LC
Finer-29, APCI Sample
No. 1942CB-l)t
Wilsonville pilot plant,
Lummus LC-Finer unit
(Lummus Run No. 2-LC
Finer-27, APCI Sample
No. 1950CB)t
82
82
82
82
(Continued)
-------
Table 348 (Continued)
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Process Coal Type
SRC-I KY No. 9
CO
^4
ro
NA
NA
Kentucky
Value
Compound Class
Phenol
o-Cresol
m+p-Cresol
2,6-Xylenol
o-Ethylphenol
2,4- and 2,8-
Xylenol
m+p-Ethyl-
phenol
2,3-Xylenol
3,4-Xylenol
Heavier
phenolics
Total
Sulfur Forms,
Pyrltic
Organic
Sulfate
Sulfur Forms,
Pyritic
Organic
Sulfate
Sulfur,
-Organic
-Pyritic
-Sulfate
Wt % Sample Description/Source Reference
ND
0.12
1.52
0.09
0.21
0.98
1.79
0.17
0.31
9.66
14.85
0.01
0.85
0.00
0.00
0.79
0.00
(0.7-0.8)
Trace
Nil
Wilsonville pilot plant,
heavy distillate from
Alcoa coker unit (APCI
Sample No. 1899CB).
Caustic extraction with
20% NaOH, 1/1-v/v, GC
analysis of extract
82
Wilsonville pilot plant,
heavy SRC, C-E Sample
No. 2440-C
Wilsonville pilot plant,
heavy SRC, C-E Sample No.
2441-C
Heavy SRC
82
118
98
(Continued)
-------
Table 348 (Continued)
Material Process Coal Type
Coil raw
heavy
distillates
(heavy
fuel otls)
and
residua
SRC-1
NA
OO
^J
CO
Peak Retention
Ho. Tine (*1n)
1
2
3
4
S
6
7
17
27
28
32
35
36
37
38
42
44
45
46
47
48
50
52
53
55
58
59
62
63
64
68
70
73
74
75
78
80
81
86
88
89
90
96
102
112
9.6
9.7
10.0
10.9
11.1
11.5
11.9
14.9
17.3
17.9
19.1
19.8
20.0
20.6
20.9
22.2
23.1
23.4
23.7
24.0
24.5
25.1
26.0
26.8
27.5
28.3
28.6
29.6
29.7
29.8
31.1
32.1
33.0
33.2
33.3
34.1
35.0
35.1
37.0
37.1
37.2
37.4
39.0
41.6
43.0
2-
2-
2,
N,
2,
2,
2,
N,
1,
2-
1,
2-
3-
6-
ai
4-
3-
5-
N
3-
d!
V
2-
I
2-
m
d:
1-
7
4
si
d
8
si
B
5
b
2
p
N
P
m
N
b
a
Compound
2-oethylpyrldlne
2-«ethyl-5-propylpyr1d1nt
2,3.5-trtmethylpyrtdlne
N.N'-dlethylanlltne
2.4-d1»ethyl-5-ethylpyr1d1ne
2,6-d1«ethyl-4-ethylpyrldlne
2.4.6-trlmethylpyrldlne
N.N1-dinethy1-4-ethylanlline
1,2.3,4-tetrahydroqutnollne
2-Mthyl-1.2.3.4-tetrahydroqu1nollne
1.2-dl«ethyl-2.3-d1hydrolndoU
2-Mthyl-2.3-d1hydro1ndole
3-nethyl-2.3-d1hydro1ndole
6-«ethyl-l,2,3.4-tetrahydroqu1nol1w
aniline
4-nethylanlltne
3-nethylanlllne
5-anlno-1.2,3.4-tetrahydronaphthalen«
N-ethylanlHne
3-nethyl-1.2,3,4-tetrahydroqu1nol1ne
dimethyl an)line (any Isooer)
qulnollne
2-nethylqulnollne
1-nethyllsoqulnoltne
2-ethylqulnollne
•ethylqulnollne (any Isooer)
thylqutnollne (any Isomer)
1-ethyllsoquIncline
7-ethylqulnollne
4-1 sopropy1qulnollne
straight chain butylqulnollne (any Isoaer)
dtbenzofuran
8-propylqutnollne
straight-chain butylqulnollne (any Isoaer)
oethyl-ethylqulnollne (any Isomer)
S-butylqulnollne
butylquinoline (any Isomer)
2.3.4-trinethylqulnollne
pnenyl-p-tolylamlne
M'-dlphenyl-ethylanlne
phenoxazlne
methyl-blphenylamine
N.N'-dlphenyl-methyUnlne
blphenylamlne
trlmethyl benzoqulnollne (Isomer)
Total
Ion
count
<0.5
-------
Table 348 (Continued)
Material
Coil raw
heavy
disunites
(heavy
fuel oils)
and
residua
Process Coal Type
SRC-1
HA
00
SRC-11 NA
peak (let ens Ion
No. Tine («1n) Compound
US 43.8 benzo1[f]qu1nollne
118 45.0 a Methyl benzoqulnollne (Isoaer)
119 45.2 benzo[h]qutnoltne
120 45.7 phenanthrldlne
124 47.6 acrldlne
125 48.3 a Methyl benzoqulnollne (Isomer)
126 48.9 Methyl benzoqulnollne (any IsoMer)
127 49.6 Methyl benzoqulnollne Isomer
128 50.0 Methyl benzoqulnollne Isomer
|29 50.2 Methyl benzoqulnollne tsoner
134 52.6 Methyl benzoqulnollne Isoaer
135 53.2 Methyl benzoqulnollne Isoaer
150 60.0 an ethyl benzoqulnollne Isoaer
CoMpound Class
Hydrocarbons. N-alkylated pyrrol Ic conpounds
OlarylaMlnes, Indolts. carbazoles
Mono- and dtarylaatnes
Aniline types, hindered pyrldlnes
Pyrldtne benzologs
Aatnes, aMldes. blfunctlonals
Total
(Continued)
Total
Ion
count
(»)
-------
Table 348 (Continued)
00
^4
O1
Material Process
Coal raw SRC- I I
heavy
distillates
(heavy
fuel oils)
and residua
H-Coal
i
i
Coal Type
Kentucky
KY No. 9
and 14,
IL No. 6
(River
King
Mine) and
Pitt-Seams
WV (Black-
ville No.
2 Mine)
IL No. 6
Wyodak
Compound Class
Sulfur,
- organic (0.
- pyrltlc
Basic nitrogen
X Classf
Aromatic Sulfur Types
-10 Benzothiophenes
-16 Dlbenzothiophenes
-22 Naphthobenzothiophene
Unidentified
X Classt
Aromatic Sulfur Types
-10 Benzothiophenes
-16 Dlbenzothiophenes
-22 Naphthobenzothiophene
Unidentified
wt %
2-0.4)
NA
0.82
2.3§
0.0
0.1
0.0
1.9§
1.0
0.2
0.0
Sample Descrlption/Soi
Ft. Lewis pilot plant
482-860°F heavy dlstl
400°F+ distillate, Ft
Lewis pilot plant,
Chevron Sample No.
WOW-3751
Heavy distillate from
PDU syncrude mode
Heavy distillate from
PDU syncrude mode
Reference
98
86
109
109
(Continued)
-------
Table 348 (Concluded)
Material Process Coal Type
Coal raw
heavy
distillates
(heavy
fuel oils)
and residua
H-Coal W. KY. 11
Compound Class
X Class§
Aromatic Sulfur Types
-10 Benzothlophenes
-16 D1benzoth1ophenes
-22 Naphthobenzothlophene
Unidentified
(wt %) Sample Description/Source Reference
Heavy distillate from
PDU, syncrude mode
109
2.0§
1.2
0.0
0.0
NA
NA
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
oo Hydro-
& treated
distillates
(heavy
fuel oils)
and
residua
Explanatory Notes
*A11 values by MS analysis.
*The raw middle distillate from the proposed SRC-I demonstration plant will consist of a 29.0/71.0/0.0 weight
percent blend of heavy distillate from the SRC, LC-Finer and coker units, respectively (Reference 100).
fFrom the molecular formula:
§Analysis by GC/MS.
-------
Table 349. Detailed Individual Nitrogen- and Sulfur-Containing Compounds
Hoi Mt
Material Process Co«l Type
Coal raw SRC-11 NA
heavy
distillates
(heavy
fuel oils)
and residua
00
Compound
aalnotndan
Ci-aalnotndan
anlnonaphthalene
C|-a*tnonaphtha)ene
Cj-anl nonaphthal ene
Cj- a«1 nonaphtha 1 ene
wlnoqulnollne
Ci-aalnoqulnottw
C2-aBtnoqu1nollne
C3-antnoqulnollne
C4-a>1noqu1nol1ne
Ml noa cenaphthy 1 ene/
anlnoblphenyl
Cl-aalnoa cenaphthy lene/
aoilnoblphenyl
C2-antnoacenaphthy1ene/
amlnobtphenyl
€3- a«l noa cenaphthy 1 ene/
anlnoblpheny)
C4-amtnoacenaphthylene/
amlnoblphenyl
aalnofluorene
Ci-a«lnofluorene
C2-a«1nofluorene
C3-aalnofluorene
C4-anlnof)uorene
aalnocarbazole
Ci-aalnocarbazole
C2-a>lnocarbazole
C3-aninocarbazole
Mfnoanthracene/
ami nophenanthrene
GI -a»1 noanthracene/
ami nophenanthrene
C2-am1noanthracene/
anil nophena'nthrene
1
Parent
131
US
143
157
171
185
144
158
172
186
200
169
183
197
211
225
181
195
209
223
237
182
196
210
224
193
207
221
?entafluoropr<
Derivative
277
291
289
303
317
331
290
304
318
332
346
315
329
343
357
371
327
341
355
369
383
328
342
356
370
339
353
367
Method of Identification*
GC/HS.UIMS
LRNS
GC/ECD.GC/HS.LRHS
GC/ECD.GC/MS.LRHS
GC/ECD.GC/HS.LRHS
LRMS
LRHS.HRHS
LRHS.HRHS
LRHS.HRMS
HRHS
HHMS
GC/ECD.GC/HS.LRMS
GC/ECD.GC/HS.LRNS
GC/ECD,GC/MS.LRMS.HRMS
LRMS
LRMS
fiC/ECD.GC/MS.LRMS.HRHS
GC/HS,LRHS.HRHS
GC/MS.LRMS.HRMS
LRMS
LRHS
LRHS.HRHS
LRHS.HRMS
LRMS
LRMS
GC/ECD. GC/MS.LRMS
GC/HS.LRHS.HRHS
GC/HS.LRHS.HRHS
Sample
Concn.t Description/
Ag/g Source Reference
204.3§
100.6
95.2
237.3»
155.8
102.7
121.2
ft. Lewis 131
pilot plant,
heavy
distillate*
153.2*
(Continued)
-------
Table 349 (Continued)
Hoi wt
CD
^-J
CO
J Ullp 1 c
Pentafluoropropyl . Concn.f Description/
Haterial Process Coal Type
Coil ran SRC-II NA
heavy
distillates
(heavy
fuel oils)
and residua
Compound
C3-aalnoanthracene/
ami nophenanthrene
04- ami noanthr acene/
anlnophenanthrene
Cj- ant noanthr acene/
ant nophenanthrene
aninophenanthrldtne/
anlnoacridtne
Cj-anlnophenanthrldine/
aminoacridlne
(•2- ami nophenanthr idl ne/
aminoacridine
C3-aninophenanthr1dtne/
aminoacridine
Ml nopheny 1 naphth a) ene
Cj-aminophenylnaphthalene
Cj-aminophenylnaphthalene
C3-amt nopheny Inaphthalene
C4-amtnophenylnaphthalene
aminofluoranthene/
aninopyrene
C^-aninofluoranthene/
anlnopyrene
Cj- ant nof luoranthene/
anlnopyrene
03- an 1 nof 1 uoranthene/
aminopyrene
€4- ami nof luoranthene/
aninopyrene
amtnochrysene/
wlnobenzanthr acene
Cj-antnochrysene/
anlnobenzanthracene
C2-aolnochrysene/
ami nobenzanthr acene
Parent
235
249
263
194
210
224
238
219
233
247
261
275
217
231
245
259
273
243
257
271
Derivative
381
395
409
340
354
368
382
365
379
393
407
421
363
377
391
405
419
389
403
417
Method of Identification' 9/9 Source Reference
LRHS.HRHS Ft. Lewis 131
pilot plant,
LRHS.HRHS heavy
distillate*
LRHS.HRHS
LRHS
LRHS.HRHS
LRHS.HRNS
LRHS.HRHS
GC/HS.LRHS
GC/HS.LRHS
GC/HS.LRHS
GC/HS.LRHS
LRHS
GC/ECD. GC/HS.LRHS 49.0**
GC/HS. LRHS.HRHS
GC/HS. LRHS.HRHS
LRHS.HRHS
LRHS
GC/ECD. GC/HS. LRHS 18.7
LRHS.HRHS
LRHS.HRHS
(Continued)
-------
Table 349 (Continued)
Ho) wt
Material Process Coal Type
Coal rax SRC-11 HA
heavy
distillates
(heavy
fuel oils)
and residua
CO
^J
vo
Compound
C3-Minochrysene/
Mlnobenzanthracene
Ca-aatnochrysene/
Mlnobenzanthracene
Mtnobenzo[ghl]fluoranth*ne
Ml nocyc lopent apyrene
Ci-Mtnobenzo[ght]-
fluoranthene/
ami nocyc lopent apyrene
C2-a»lnobenzo[ghl]-
fluoranthene/
Mtnocyc lopent apyrene
C3-Mlnobenzo[gh1J-
fluoranthene/
Ml nocyc lopent apyrene
fluoranthene/
an I nocyc lopent apyrene
Ml nobenzopyrene/
Mlnoperylene/
Mtnobenzof luoranthene
Ci - ami nobenzopyrene/
Mlnoperylene/
Mlnobenzof luoranthene
Cj- Ml nobenzopyrene/
Mlnoperylene/
Mlnobenzof luoranthene
€3- aal nobenzopyrene/
Mlnoperylene/
Ml nobenzof luoranthene
C4- M! nobenzopyrene/
Mlnoperylene/
Ml nobenzof ) uoranthene
anlnodtbenzopyrene/
Mlnodlbenzof luoranthene
C^- ami nod) benzopyrene/
Ml nodlbenzof luoranthene
Pentafluoropropyl
Parent Derivative Method of Identification*
285
299
241
255
269
283
297
267
281
295
309
323
317
331
431
387
387
401
415
429
443
413
427
441
45S
469
463
477
LftHS
LRMS
LRMS
LRMS
LRMS
LRMS
LRMS
LRMS.HRMS
LRMS.HRMS
LRMS
LRMS
LRMS
LRMS
LRMS
Sample
Conen,f Description/
9/9 Source Reference
Ft. Lewis 131
pilot plant,
heavy
distillate-
(Continued)
-------
Table 349 (Continued)
Hoi wt
Material Process Coal Type
Coal raw SRC-11 HA
heavy
distillates
(heavy
fuel oils)
and residua
CO
00
o
Conpound
Nitrogen Poly cyclic aronatlc compounds
Ci-lndole
Cj-qulnollne
Cz-lndole
Ca-lndole
Cj-dlphenyl ether
Cj-qulnoltne
tet rahydrobenioqul nol 1 ne
phenanthrene
benzoquinolfne
benzoqulnollne
Ci-tetrahydrobenzoqulnol Ine
tetrahydrocarbazole/benzoqulnollne
Ci-tetrahydrobenzoqulnoltne
ctrbazole
Ci-benzoqutnollne
Ci-tetrahydrocarbazole
Ci-benzoqulnoltne
Ci-carbazole/Ci-benzoqutnoltne
Ci-benzoqutnoltne/Cj-benzoqulnoltne
C}-carbazole
Ci-benzoqutnollne
C2-benzo<(u1nollne
Cj-carbazole
Cj-benzoqulnoltne
Cj-carbazole
Cj-carbazole
C3-carbazole
azafluoranthene
azapyrene
C4-carbazole
Ci-azapyrene/Cj-azafluoranthene/
'•S-carbazole
C2-azapyrene/C2*azafluoranthene/
tetrahydrobenzocarbazole
naphthoqulnollne
benzocarbazole
C}-benzocarbazole
Pentafluoropropyl
Parent Derivative Staple Oescrlptton/Soui
, Fraction A- 3
131
157
US
159
198
185
183
178
179
179
197
171/179
197
167
193
185
193
181/193
193/207
181
193
207
195
207
195
195
209
203
203
223
217/237
231
221
229
217
231
Ft. Lewis pilot plant.
M heavy dlstlllatett
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Reference
132
(Continued)
-------
Table 349 (Continued)
Material Process Coal Type
Coal raw SRC-II NA
heavy
distillates
(heavy
fuel oils)
and residua
CO
CO
Compound
Hydroxyl polycycllc aromatic hydrocarb
Cj-tndanol
hydroxyblphenyl
C;-lndano1
Ci-hydroxybtphenyl
(4 -hy droxyb 1 pheny 1
C3-lndanol
C^-hydroxyblphenyl
hydroxyblphenyl
hydroxyblphenyl
C4-lndano1
C3-hydroxyb 1 pheny 1
Ci-hydroxyblphenyl/Cg-tndanol
Ci-hydroxybl pheny 1
Cj-hydroxyblphenyl
C3-hydroxyblphenyl
hydroxyfluorene
C^-hydroxybl pheny 1
hydroxyfluorene
hydroxyfluorene
Cj-hydroxyblphenyl
hydroxyfluorene
C^-hydroxybt pheny 1
C4-hydroxyb1phenyl/Ci-hydroxyfluorene
C3~hydroxyb1phenyl
C3-hydroxyblphenyl/Ci-hydroxyfluorene
naphthylphenol
C4-hydroxyblphenyl/C2-hydroxyfluorene
Cj -naphthylphenol
Cs-hydroxyblphenyl/C3-hydroxyfluorene
naphthylphenol
naphthylphenol
Cj -naphthylphenol
Parent
Hoi Mt
Pentaf luoropropyl
Derivative
ons, Fraction A-4
148
170
162
184
184
176
198
170
170
190
212
184/204
184
184
212
182
198
182
182
198
182
198
226/196
212
212/196
220
226/210
234
240/224
220
220
234
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Sample Description/Source Reference
Ft. Lewis pilot plant,
heavy distillateff
132
(Continued)
-------
Table 349 (Continued)
Hoi wt
Material Process Coal Ty
Coal raw SRC-11 NA
heavy
distillates
(heavy
fuel oils)
and residua
00
00
ro
Compound
Pent af 1 uoropropy 1
Parent Derivative Sample Description/Source Reference
Polyanwatlc sulfur heterocycles subfractlon A- 26
fluorene
C]-fluorene
tetrahydrodlbenzothlophene
dibenzothlophene
phenanthrene
anthracene
Ci-dtbenzothtophene
C?-d1benzothlophene
f luoranthene
Cj-dtbenzothlophene
phenanthro[4,5-bcd]thlophene
pyrene
C}-phenantho[4.5-bcd]th1ophene
benzonaphthoth tophene
C) -benzonaphthoth tophene
Cj-benzonaphthoth tophene
Secondary nitrogen polycycllc aromatic
Cj-lndole
C3-tndole
Ci-dlphenyl ether
C4-lndole
C?-dtphenyl ether
pnenanthrene
tetrahydrocarbazole
Cj-dlphenyl ether
carbazole
carbazole Isoaers
Cj-carbazole
C2-carbazole
C3-carbazole
C^-carbazole
Cs-carbazole
benzocarb azote
benzocarbazote
Ci-benzocarbazole
Cj-benzocarbazole
166
180
186
184
178
178
198
212
202
206
208
202
222
234
248
262
heterocycles
145
159
184
173
198
178
171
212
167
167
181
195
209
223
237
217
217
231
245
Ft. Lewis pilot Plant, 132
NA heavy distillate!!
NA
NA
NA
NA
NA
NA
NA
NA
NA
HA
NA
NA
NA
NA
NA
fraction S-l
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
(Continued)
-------
Table 349 (Continued)
Material Process Coal Type
Coil rut SRC-11
heavy
distillates
(heavy
fuel oils)
and residua
NA
00
CO
CO
Compound
Parent
Enriched aatno polycycltc aromatic hydrocarbons
naphthylamine
aminobiphenyl
Ci-amlnoblphenyl
Cj-anlnobtphenyl
nlnof luorene
benzo[h]qulnoltne§§
carbazple
Ci-benzoqutnollne
amlnophenanthrene/antnoanthracene
Cj-benzoqutnollne
C3-benzoqutnoltne/Ci-anlnophenanthrene
C4-benzoqulnollne
tetrahydronaphthoqutnotine
am 1 nopyrene/ am t nof 1 uor anthene
tetrahydronaphthoautnollne
naphthoqulnoltne (possibly
benz[c]acridine)W
Cj-aint nopyrene/C}- ami nof lour anthene
naphthoqutnollne (possibly
benz[c]acridln«j§§
benzanthrone
Ci-benzanthrone
ph thai ate ester
143
169
183
197
181
179
167
193
193
207
221/207
23S
233
217
233
229
231
229
230
244
Hoi Mt
Pentaf luoropropyl
Derivative
fraction S-2
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Tertiary nitrogen polycycllc aromatic het recycles fraction S-2
Cj-qutnollne
C3~qu1nol1ne
C^-qulnollne/unldentlfled peaks
Cg-quinollne
tetrahydroqul nol 1 ne
acrldlne'9
phen anthr 1 d 1 ne§§/benzo[f ]qu 1 no 11 ne§§
Cj-t etrahydroqutnol tne
Cj-bertzoqulnoltne
C^-benzoquino 1 1 ne/azaf luoranthene
C3-benzoqutnoltne
azapyrene
C^-azapyrene/Ci-azaf luoranthene
naphthoqulnollne
157
171
185/158/
183
199
183
179
179
197
193
207/203
221
203
217
229
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Sample Description/Source Reference
Ft. Lewis pilot plant.
heavy distillate!!
132
(Continued)
-------
Table 349 (Continued)
00
00
Material Process Coal Type
Coal raw SRC- 1 1 NA
heavy
distillates
(heavy
fuel oils)
and residua
Peak
Number
8
13
14
IS
22
23
28
29
31
33
39
40
41
42
43
44
52
S3
80
81
83
87
91
93
94
96
97
Molecular
Height
168
182
182
182
196
184
198
198
198
198
212
212
212
212
206
212
205
208
234
234
230
248
248
242
242
242
242
formula
C,2H100
CUH100
C}3H,00
Cl4«120
CjjHgS
C|3HjQS
C13H10S
CUH10S
CijHjgS
C14Hi20
CUH12S
CMH,2S
C14H12S
C,4"16S
C,4H,2*
C15HUN
C16H16
C|(HjQS
C|gHjo^
CI^HIQS
CjjH^S
CMH12S
Cj9HMS
Ci0Hi4S
Cj9Hi4S
CiqHiiS
Concentration
(parts per
thousand)
0.28
0.21
0.28
0.08
0.29
2.12
0.27
0.32
0.88
1.14
0.17
0.24
0.28
2.11
0.58
0.22
0.32
0.99
0.91
0.50
0.32
0.61
0.43
0.43
0.63
2.21
1.91
Possible Coapound T/pjs SajvJ.e.-0eJc£iP-t?
-------
Table 349 (Concluded)
Mol Mt
Pentaf1uoropropyl
Material Process Coal Type Compound Parent Derivative Sample Description/Source Reference
Coal raw NA
heavy
distillates
(heavy
fuel oils)
Hydro- NA
treated
heavy
distillates
(heavy
fuel oils)
and
residua
CO
oo Explanatory Notes
en —• *
'Compounds Identified 1n anino polycyclic aromatic hydrocarbons (APAH) fraction from alumina-silicic acid column separation.
*GC/ECD * capillary gas chromatography/electron capture detector (retention data), GC/MS - capillary gas chromatography/mass
spectrometry, LRMS - low-resolution mass spectrometry, HRNS « high-resolution mass spectrometry.
fConcentration In pg/g of APAH in crude SRC-II heavy distillate. Average value of two determinations using an Internal standard
of 1-amlnonaphthalene. APAH for which quantitative data are not presented are lower in concentration than 15 ug/g.
§Two Isomers of amlnonaphthalene were identified by retention data: (1) 1-amlnonaphthalene, 42.9 pg/g; (2) 2-amlnonaphthalene,
161.4 pg/g.
'Two Isomers of amlnoblphenyl were identified by retention data: (1) 3-amlnoblphenyl, 141.5 pg/g; (2) 4-amlnoblphenyl, 95.6 pg/g.
+*Three different Isomers detected: (1) 48.0 pg/g. (2) 58.0 pg/g, (3) 47.2 pg/g.
ttjwo different Isomers detected: (1) 31.0 ug/g, (2) 18.0 pg/g.
ffDetermlned via alumina-silicic acid fractlonatlon followed by GC-NS analysis.
§§Poss1b1e structures assigned by retention data comparisons with standard compounds.
"Hay also be dimethyl.
-------
Table 350. Compound Class Analysis Obtained by Solvent Fractionation
Hatertal
Coal raw
heavy
distillates
(heavy
fuel otls)
and
residua
Process Coal Ty
SRC-I wyodak
Value
C»
00
CTV
n-hexane soluble (oils)*.*
coapound-class fraction (wt
Fraction 1 hydrocarbons
Fraction 2 nitrogen heterocycles
Fraction 3 hydroxyl aromatics
Fraction total (1+2+3)
Fraction 4 polyfuncttonal compounds
Solvent derived fractions (wt % in SRC)
Sample Description/Source Reference
Toluene soluble n-hexane*.'
Insoluble (asphaltenes)
compound-class fraction
Fraction 1 hydrocarbons
Fraction 2 nitrogen heterocycles
Fraction 3 hydroxyl aromattcs
Fraction total (1+2+3)
Fraction 4 polyfunctianal compounds
Solvent derived fractions (wt X In SRC)
Pyridine soluble-toluene*'*
Insoluble (preasphaltenes)
compound-class fraction
FfactIon 1 hydrocarbons
Fraction 2 nitrogen heterocycles
Fraction 3 hydroxyl aromatics
Fraction total (1+2+3)
Fraction 4 polyfuncttonal compounds
Solvent derived fractions (wt X in SRC)
SRC F-45*.t
compound-class fraction
Fraction 1 hydrocarbons
Fraction 2 nitrogen heterocycles
Fraction 3 hydroxyl aromatics
Fraction total (1+2+3)
Fraction 4 polyfuncttonal compounds
Solvent derived fractions (wt X In SRC)
X in SRC)
11.4
4.4
3.9
19.7
NA
19.7
Utlsonvllle pilot plant.
heavy SRC
ISO
X in SRC)
0.3
16.1
23.2
39.6
NA
39.6
X in SRC)
NA
2.6
9.4§
31.3*
40.7
(wt
X in SRC)
10.6
23.4
34.1
68.1
31.9
100.0
(Continued)
-------
Table 350 (Concluded)
00
CO
Material Process Coal Type Value
Coal raw NA
heavy
distillate
blends
(heavy
fuel oils)
Hydro- MA
treated
heavy
distillates
(heavy
fuel oils)
and
residua
Explanatory Notes
'Determined via solvent extraction procedure and gas chromatography.
^Determined via chromatographlc separation procedure using switching column technique.
fDetermined via chromatographlc separation procedure using dual column system.
§Chloroform soluble-toluene Insoluble portion of preasphaltene.
'Determined by difference to 1001.
Sample Description/Source Reference
-------
Table 351. General Physical and Chemical Properties of Various Distillation Fractions of
Raw and Hydrotreated Heavy Distillates and Residua
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
00
00
00
Process Coal Type Cut No.
SRC- 11 Powhattan 12
No. 5 n
14
15
16
16HC*
17
17HC*
18
19
19HC-A*
19HC-B*
450/650
650/900
Vapor
5* Wt off
690.8
732.2
404.6
629.6
694.4
712.4t
743
789. 8t
815
892.4
919. 4t
964. 4 t
444. 2*
653
Temperature
50» wt off
710.6
748.4
570.2
696.2
757.4
728.6
820.4
798.8
890.6
969.8
942.8
982.4
527
757.4
, °F
95* wt off
739.4
771.8
710.6
809.6
843.8
744.8*
905
809. 6t
1000.4
1074.2
964. 4t
1000. 4t
649.4*
957.2
Specific
Gravity
(60°F/60°F)
1.0793
1.0918
1.0184
1.0773
1.0973
1.0910
1.1195
1.1204
1.1733
1.1950
1.1792
1.1971
0.9951
1.09
Pour
Point, °F
64.4
84.2
15.8
69.8
84.2
NA
100.4
NA
150.8
210.2
NA
NA
NA
NA
Molecular
Weight
(cryoscoplc)
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Sample Description/Source Reference
POU P-99, heavy distillate 110
PDU P-99, residuum 110
(Continued)
-------
Table 351 (Concluded)
Mlttrlll
Hydro-
trtittd
*t««y
dlttllllttl
[h.t.y
futl Bill)
•ml
rtildui
ProctM Cot I Typt
EOS II No. (
SptclMc VUcotlty Noliculir Pour
tri.lty (cSt) yjljjjt Point.
00
00
IO
25.0 0.9042
17.) fl.»SO»
53.« 0.7*45
27.4 0.8MS
53.5 0.7(4*
27.* 0.8877
2.37
(100'f)
M.I
120
<-7*
75
Dlltlllitlon
•F) (I tviponlloo)
36I/39CF-IBP/S*
412/42«'F/10/20
443/4S6*F-30/40
470/486'F- 50/60
S02/5ZO-F- 70/80
545/56S-F-W/95
592'f-Ef
51Z/631'F- IBP/5*
•49/656-F/IO/ZO
MO/667 -F- 30/40
«73/S83'F-iO/M
7I5/744-F-70/80
7B9/UCF-M/H
M
M
M
M
M
I.M
t«pl«n>tor> Hotet
*Hc«rt cut from stcondarjr frtctlonallon
•Full tnlllng rugt
tOttcralned »!• »STH 0-86
iOetimlned >ll A5TN 0-1160
161/187'F- IIP/5
200/222'F/10/20
244/270-F-30/40
302/34CF.50/M
385/432^-70/60
504/540'F 90/95
5WF-F.P
»7/408'F-leP/5«
4I6/423-F/10/20
430/439'F- 30/40
450/4«4*F-50/60
48C/5I2'F- 70/80
539/560-F-90/95
585'F-fP
l«4/!84*F-IIP/5t
196/215'F/lO/ZO
234/2M-F-30/40
282/3I7-F-50/40
360/407'F- 70/60
474/514-F-90/95
540'F-Ef
400/404'F- IBP/5»
406/4II-F/IO/20
419/423'F- 30/40
433/448-F-50/60
464/503*F-70/80
S40/S63-F-90/9S
583'F-Er
Flith
136
MA
NA
•tittrch
Octint 8ri»lnt fiu. Contint
No. Indtn 1.9/100 «l) Suplt Oticrlptlon/Soiirc«
NA NA NA IIP to 600-F cut fro. flr>t-st<9e
hydrocncklng of UOP rw 40u*F*
heivy dlstlllilt Saplt No. 3532-4
(UOP Suplt No. 3532-7)
NA
M M M MO'F» cut tram flnt itigt
kydracrtcklng of UOP r«« 4WF*
twivy dlitlllitt S»pU No. 3532-4
(UOP Swplt No. 3532-8)
72.1 92 If I8P to 375'F cut fro. sico«d->t<9t
hydrocrtcklng of UOP SnpU No.
3532-8 (UOP Suplt No. 3S32-I7)
NA NA 375'F* cut fro. lecond ttijt
hydracriclilM of IMP S«plc No.
3S32-I (UOP !u*>lt No. 3532-17)
74.4 57 10 IIP-375'F cut fro. itcood tttgt
hydrocr.cklnj of Supl* No. 3432-8
(IMP Su*>U No. 3532-18)
NA NA NA 375'F* cut fro. second ftlgt
bydrocrtcklng of UOP Suplt No.
3532-8 (UOP Suplt No. 3532-18)
-------
Table 352. Elemental Composition Data of Various Distillate Fractions of Heavy Distillates and Residua
Value
Sample Description/Source Reference
CO
o
SOt wt * Off
Temperature —
Material Process
Coal raw SRC- I I
heavy
distillates
(heavy
fuel oils)
and
residua
Coal raw NA
heavy
distillate
blends
(heavy
fuel oils)
Hydro- EDS
treated
heavy
distillates
(heavy
fuel oils)
and
residua
Coal Type Cut No.
Powhattan 12
No. 5 13
14
15
16
17
Powhattan 18
No. 5 19
„
IL No. 6 NA
It
710.6
748.4
570.2
696.2
757.4
820.4
890.6
969.8
„
NA
Elemental Composition, wt 1
C
89.08
90
88
88
89
88
88
89
„
87
.38
.12
.66
.10
.70
.63
.31
.80
H
7.68
7.70
8.37 (
7.66
7.34
7.27
7.02
6.32
_.
N
.13 1.
.28 0.
).90 2.
.31 1.
.39 1.
.56 2.
.75 1.
.82 1.
»
12.03 0.00006 0.
, (Dry Basis)
0
87
27
29
90
81
03
99
98
0718
S
0.24
0.37
0.32
0.47
0.36
0.44
0.61
0.57
_-
0.0002
IL No. 6 NA NA 88.61 11.70 0.00083 0.0900 0.0030
IL No. 6 NA NA 86.03 13.39 0.00002 0.0226 0.0365
IL No. 6 NA NA 86.93 12.17 0.00006 0.0723 0.0084
IL No. 6 NA NA 86.72 13.34 0.00002 0.0197 0.0261
IL No. 6 NA NA 87.93 12.20 0.00002 0.0415 0.0137
PDU P-99. heavy distillate
PDU P-99. residuum
IBP to 600*F cut from
first-stage hydrotreat-
Ing of UOP raw 400°F
heavy distillate Sample
No. 3532-4 (UOP Sample
No. 3532-7)
600*F* cut from first-
stage hydrocracklng of
UOP raw 400°F+ heavy
distillate Sample No.
3532-4 (UOP Sample
No. 3532-8)
IBP to 375'F cut from
second-stage hydrotreat-
-------
Material
Coal raw
heavy
distillates
(heavy
fuel oils)
and
residua
Coal raw
heavy
distillate
blends
(heavy
fuel oils)
Hydro-
treated
heavy
distillates
(heavy
fuel oils)
and
residua
Table 353. Hydrocarbon Class Properties (Aromatics and Saturates
Content) of Various Distillate Fractions of Heavy
Distillates and Residua
Value
(vol %)
Process Coal Type Aromatics Saturates Sample Description/Source Reference
NA
NA
EDS
IL No. 6
59.2
IL No. 6
9.9
IL No. 6
11.6
40.8 600°F+ cut from first-
stage hydrocracking
of UOP raw 400°F+
heavy distillate Sample
No. 3532-4 (UOP Sample
No. 3532-8)
90.1 IBP to 375'F cut from
second-stage hydrocrack-
ing of UOP Sample No.
3532-8 (UOP Sample No.
3532-17)
88.4 IBP-375°F cut from
second-stage hydrocrack-
ing of UOP Sample
No. 3532-8 (UOP Sample
No. 3532-18)
99
99
99
891
-------
Table 354. General Physical and Chemical Properties of Secondary Coal-Derived Heavy Distillates
Value
Heavy
distillate
from
hydro-
treated
whole
coal
liquids
SRC-II
oo
to
ro
Coal Type
KV No. 9
and 14,
11 No. 6
(River
King
Nine)
and
Pitt-Seams
MV (Black-
vllle No.
2 Mine)
Parameter
Gravity, "API
Aniline Point. °F
TBP Distillation,
Period 1*
26.4
156.0
•F
Period 2*
20.7
115.5
Period 3*
17.2
71.0
Period 4*
26.0
146.5
(simulated by chromatography)
St/5
10/30
50
70/90
95/99
Viscosity
cSt at 100°F
cSt at 210°F
Density at 70°C
Molecular Weight
Refractive Index
398/534
550/582
604
625/655
668/694
6.93
1.99
0.8619
237
1.4625
378/528
547/588
616
648/685
700/722
8.41
2.14
0.8934
228
1.4872
427/539
551/586
608
630/658
669/691
>.339
NA
NA
NA
NA
346/518
541/579
602
624/653
664/681
6.29
1.60
0.8627
238
1.4659
at 80°F
Explanatory Note
*Each period refers to a run time having a characteristic set of operating conditions.
Ft. Lewis pilot plant;
SSO'F* product from
hydrotreatlng of SRC-II
whole coal liquid with
ICR 106 catalyst; Run No.
76-165. Operating condi-
tions: Period 1, Run
Hours 251-275, 750°F
catalyst temperature 0.55
LHSV, 2300 psla H2;
Period 2, Run Hours
539-563, 750°F catalyst
temperature, 1.51 LHSV,
2300 psla H2; Period 3,
Run Hours 2339-2351,
768°F catalyst temperture,
1.52 LHSV, 2300 psla
HZ; Period 4, Run
Hours 2709-2733, 776°F
catalyst temperature,
0.49 LHSV, 2300 psla
H2.
86
-------
Table 355. Elemental Composition of Secondary Coal-Derived Heavy Distillates
Value (wt t)
Material Process Coal Type
Parameter
Period 1* Period 2* Period 3* Period 4* Sample Description/Source Reference
Heavy
distillate
from
hydro-
treated
whole
coal
liquids
SRC-II KY No. 9 Nitrogen
CO
UD
CO
and 14,
IL No. 6
(River
King
Mine)
and
Pitt-Seam
WV (Black-
vllle No.
2 Mine)
Oxygen
NA 0.0035 0.0068 NA Ft. Lewis pilot plant;
NA 0.1600 NA NA 550°F+ product from
hydrotreatlng of SRC-11
whole coal liquid with
ICR 106 catalyst; Run No.
76-165. Operating condi-
tions: Period 1, Run
Hours 251-275, 750°F
catalyst temperature 0.55
LHSV, 2300 psla H2;
Period 2, Run Hours
539-563, 750°F catalyst
temperature, 1.51 LHSV,
2300 psla HZ; Period 3,
Run Hours 2339-2351,
768°F catalyst temperature,
1.52 LHSV, 2300 psla
\\2i Period 4, Run
Hours 2709-2733, 776°F
catalyst temperature,
0.49 LHSV, 2300 psla
H2.
Explanatory Note
*Each period refers to a run time haying a characteristic set of operating conditions.
86
-------
Table 356. Hydrocarbon Class Properties (Saturates and Aromatics Contents)
of Secondary Coal-Derived Heavy Distillates
Value
Material Process Coal Type
Heavy
distillate
from
hydro-
treated
whole
coal
liquids
SRC-II
CO
10
-£»
KY No. 9
and 14,
IL No. 6
(River
King
Nine)
and
Pitt-Seams
UV (Black -
vllle No.
2 Nine)
Parameter
Saturates
Aromatics
Period 1* Period 2* Period 3* Period 4* Sample Description/Source Reference
93.9 70.3 53.7 87.6 Ft. Lewis pilot plant;
6.0 29.7 46.4 12.4 550°F+ product from
hydrotreatlng of SRC-II
whole coal liquid with
ICR 106 catalyst; Run No.
76-165. Operating condi-
tions: Period I, Run
Hours 251-275, 750°F
catalyst temperature 0.55
LHSV, 2300 psla H2;
Period 2, Run Hours
539-563, 750"F catalyst
temperature, 1.51 LHSV.
2300 psla H2; Period 3,
Run Hours 2339-2351,
76B°F catalyst temperature,
1.52 LHSV, 2300 psla
H?; Period 4, Run
Hours 2709-2733, 776"F
catalyst temperature,
0.49 LHSV. 2300 psla
H2.
86
-------
General Comments
1. Benzo(a)pyrene and 2-aminoanthracene have been detected in SRC-II heavy
distillate, with mutagenic activities of 114 and 4,326 revertants/ug,
respectively (Reference 133).
895
-------
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