M1V-? X3tS*'~- •*
FBS6-216470
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Unitec3 States Procedures for Sampling and
Analysis of. Hasardouo Waste
Systems, Science and Software, San Diego,-
CA
Prepared £or
Environmental Protection Agency, Cincinnati, OH
Jul 86
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U.S.
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86-128
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PB86-216470
EPA/600/D-86/123
July 1986
UNITED STATES PROCEDURES FOR SAMPLING AND ANALYSIS OF HAZARDOUS WASTE
by
Eugene Burns
Systems, Science & Software
San Diego, CA 92121-1095
EPA Project Officer
Clyde J. Dial
HAZARDOUS WASTE ENGINEERING RESEARCH LABORATORY
OFFICE OF RESEARCH AXD DEVELOPMENT
U.S. ENVIRONMENTAL PR01ECTION AGENCY
CINCINNATI, OH 45263
KPSODIJCfO B»
NATIONAL TECHNICAL
\ INFORMATION SERVICE
(I.S. DEP*»W»: OF COMMERCE
SPRIHGflflB, »». 22161
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«. A J —^' —
TECHNICAL RK?OHT DATA
(Pleau read Instructions on the reverse he fore corr.ple.ing/
1. FEPORT NO.
EPA/600/D-36/128
3. RECIPIENT'S ACCESSION WDf"H If.?
PE3 6 >> 1 {-> - < U /ftS
a. TITLE ANDSUBTITLE
United States Procedures for Sampling and
Analysis of Hazardous Waste
5. REPORT DATE
July 1936
6. PERFORMING ORGANIZATION COOS
7. ALITHOR1S)
Eugene Burns
8. PERFORMING ORGANIZATION REPORT NO.
B. PERFORMING ORGANIZATION NAME AND ADDRESS
Systems, Science & Software
3398 Carmel Mt. Rd
San Diego, CA 92121-1095
12 SPONSPRING AG6NCV NAME ANO ADnacCC
Hazardous Waste Engineering ;\esearch Laboratory
Office of Research and Development
I'.S. Environmental Protection Agency
Cincinnati , OH 452f>8
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
13. TYPE OF REPORT AND PERIOD COVERED
14 SPONSORING AGENCY CODE
EPA/600/12
15. SUPPLEMENTARY NOTES
16. ABSTRACT
This naper WAS prepared for presentation at a joint US/Spain Seminar on /-:/ardous
Waste Management, to be held in Madrid, Spain, on May 19-22, 1936.
Topics include identifying hazardous compounds, sampling methods, analysis
methods and quality assurance approaches/procedures.
KCY WORDS AND DOCUMENT ANALYSIS
DESCRIPTORS
18. DISTRIBUTION STATEMENT
RELEASE TO PUBLIC
b.lDENTIFIERS/OPEN ENDED TERMS C. COS* Tl Field/Group
19. SECURITY CLASS ITha Keport/
Unclassified
20. SECURITY CLASS (Tha pagt)
Unclassified
21. NO. OF PAGES
112
22. PRICE .
EPA Form 2230-1 (R«r. 4-77) PRCVIOUS EDITION IS O«IOLEie -•
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;
NOTICE
This document has been reviewed in accordance with the U. S. Environmental
protection Agency policy and approved for publication Mention of trade names
or commercial products does not constitute endorsement or recommendation for
use.
11
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FOREWORD
Tooay's rapidly developing and changing technologies and industrial
products and practices frequently carry with them the increased generation
of solid and hazardous wastes. These materials, if improperly dealt with,
can threaten both public health and the environment. Abandoned waste sites
and accidental releases of toxic and hazardous substances to the environment
also have important environmental and public health Implications. The
Hazardous Waste Engineering Research Laboratory assists ;n providing an
authoritative and defensible engineering basis for assessing and solving
these problems. Its products support the policies, programs and regulations
of the Environmental Protection Agency, the permitting and other responsi-
bilities of State end local governments and the needs of both large and small
businesses in handling their wastes responsibly and economically.
This report identifies hazardous compounds, sampling and analytical
methods for measuring these compounds, and procedures that can be used to
assure the quality of data obtained. This report should be useful to those
who are faced with assessing the extent of hazardous compounds or determining
the efficiency of control approaches.
For further information, please contact the Alternative Technologies
Division of the Hazardous Waste .Engineering Research Laboratory.
David G. Stephen, Director
Hazardous Waste Engineer! ny Research Laboratory
iii
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• ABSTRACT
I ' .
ji
^ Hazardous waste may oe stored, treated and disposed in i. variety of
i!
[ • ways. Treatment technology exists today for detoxification or destruction
ft
-f of wastes in an environmentally acceptable manner through physical, chemical
V
' and biological means. This paper identifies hazardous compounds, sampling
and analytical methods for measuring these compounds, and procedures that
' can be used to assure the quality of dat? obtained. This report should be
| useful to those who are faced with assessing the extent of hazardous compounds
: or determining the efficiency of control approaches.
1v
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CONTENTS
i
Foreword . . lii
Abstract iv
Tables ............. vi
Figures vii
." SECTION 1 1
Li
i Introduction I
: SECTION ?
[ Scope--! Jenti fied Hazardous Compounds .......'... 5
t
\ SECTION 3 8
I, Sampling Methods 8
| Sol-.ds 9
| Liquids : 13
i Gases . 16
I SECTION 4 ' '21
Analysis Methods 24
Survey Analysis 30
Sample Preparation Procedures ...... . 33
Organic Constituents 34
Inorganic Constituents •. 38
Organic Analysis Methods . 39
Monitoring 42
Inorganic Constituents 43
SECTION 5 .48
Quality Assurance ana Qua^ty Control Procedures 48
REFERENCES ' 56
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rtr
TABLES
Page
Table 1.
Table 2.
Table 3.
Table 4.
Table 5.
Table 5.
Table 7.
Table 3.
Table 9.
Table 10.
Table 11.
Table A.I
Source Lists for ITD/RCP.A Analytes . .
Choice of Samplers for Hazardous Waste
Sampling Points . . . . .
6
10
11
Sampling Methods for Effluent Streams ........ 12
Waste Evaluation Procedures
25
Threshold Levels of Contaminants in the
Extraction Procedure Toxicity Test .
28
Proximate Analysis of Wastes 31
Sample Preparation Procedures . . 35
Routine/Monitoring Organic Analytical Methods ......... 44
RCRA Methods for Metal Analysis of Wastes . 46
Essential Flements of a QA Project Plan 49
ITD/RCP.A Compound Data 59 - 104
v1
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FIGURES
Page
-..---**
Figure 1. Modified Method 5 Train (HM5) . . ., 2:0
Figure 2. Volatile Organic Sampling Train (VOST) 23
Figure 3. Diagram of a sampling and analysis procedure whicn
uses replicate samples to provide information on
sources of variance 54
vii
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SECTION 1
INTRODUCTION
( Under the Resource Conservation and Recovery Act (RC8A), the United
i
i States Environmental Protection Agency (EPA) has promulgated proposed,
1 interim, and final regulations for owners/operators of hazardous waste
; treatment, storage and disposal facilities (TSOFs) These regulations state
i ' .
'• that generators of hazardous waste are responsible frcra "cradle to grave" for
t
; these materials. Additionally, under the Comprehensive Environmental
s
\ Response, Compensation and Liability Act (CERCLA), the EPA has promulgated
f regulations which govern the cleanup of hazardous wastes at abandoned or
] uncontrolled disposal sites. Tnis law antS the associated regulations provide
; legal mechanisms for (1) assessing actual or threatened releases of hazardous
substances at uncontrolled sites, (2) implementing clean-up activities, and
j
\ (3) recovering cleanup and resource restoration costs from the parties
? responsible for the hazardous wastes.
Key to the identification of a hazardous waste site or hazardous waste is
*
i
j
i
i
! the confirmation that specific chemical species which have br.en listed by EPA
i
I as hazardous are present (Ref, 1-4). This is determined by (1) prior cxperi-
i '
j ence of the operator/owner in knowinq what is present
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Specifically, these strategies roust be designed to ensure that the data
generated meets the quality requirements and intended purpose of tie waste
characterization effort. If a measurement activity is performed in
conjunction with a hazardous waste permit prog"am, for example. &V\
information needed to establish compliance should t>e generated. As a
consequence, the wast<» characterization strategies may vary significantly,
depending upon the Intended use of the information.
Clearly, the waste cfu racterizatlon strategy will include consideration
of sairpling procedures and the selection of suitable chemical analysis
procedures, together with Information regarding sample preservation,
packaging, storage and shipping to the analysis laboratory. The strategy will
also. Include a procedure to ensure that ,. an effective chain-of-custody
procedure is incorporated Into the saspllng protocol. Other important
considerations Include the sarnie size to be collected (e.g., sufficient
sample roust be obtained 1n order to make measurements In the need-z.s
concentratlon range). The .sampling protocol will also contain explicit
provisions for ensuring the safety of the personnel collecting tha samples at
the sampling site.
The collected raw or treated waste will be evaluated using a set of
regulation-specified physical and chemical tests to determine whether 1t insets
the definition of a hazardous waste. The owner/operator of the hazardous
waste treatment, storage, and disposal facility (TSDF) first determines 1f his
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rr .7. „'_"._ "~. r ~' ' ~""'
waste 1s excluded .1n Section 261.4 cr specifically listed under Subpart D of
the RCRA regulation. If the waste ii not excluded and not listed, then he
must evaluate his waste 1n terms of four hazardous characteristics: ignit-
sbillty. corrrsivity, reactivity, and EP Toxldty, unless he can property
evaluate the waste based on his own knowledge of the waste.
The definition of hazardous taste specified 1n 40 CFR 261.1 for toxic
constituents In the extraction procedure are IR the process of expansion to
cover a wide range of generally recognized toxic Inorganic end oroanic com-
pounds and nnstures. For hazardous waste Incineration processes, for example,
clear-cat regulations requiring the destruction of 99.99* percent of the
principal hazardous constituent have been defined 1n 40 CFR 264 (f'enaitting
Stanoirts] and 40 CFR 2f>5 (Interim Status Standards). !P sany cases, defini-
tive analytical- sathods and regulatory concentration levels have not yet been
established and each waste is considered on a case-by-case basis.
The objective of this paper is to provide a managenvent overview of the
current status of procedures used in the United States for sampling the myriad
of hazardous waste form and for obtaining maaningful concentration measure-
ments at trace and macro levels of identified hazardous compounds in the waste
nutrix. Detailed and generalized discussions of these rstethods are presented
1n References 1-4. This paper presents discussions on sores specific and
generalized analytical Bsethods which are currently used and descriees
promising analytical techniques directed toward cofspounds for which
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non-validated methods exist. Finally, Information is provided on quality
assurance and quality control procedures which are required to ensure that
data generated are complete, representative, comparable, valid, of known
precision and accuracy, and legally defensible.
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f
\
[ SECTION 2
SCOPE - IDENTIFIED HAZARDOUS COMPOUNDS
Since 1971, the United States EPA has been Identifying specific chemical
compounds which are considered environmentally toxic. As a result of the 1976
Consent Decree, a comprehensive list of toxic water pollutants was generated -
the priority pollutant list. In the intervening years, it has been determined
th?t additional compounds and classes of compounds also provide a toxic concern
and need to be added to the list of hazardous materials. Presented as an appen-
dix to this paper is the most recent list; namely, the Industrial Technology
Division/Resource Conservation Recovery Act (ITD/RCRA) list which defines the
compounds to be analyzed in the ITO/RCRA Sewage Study project (Ref. 5). This
list includes all compounds on the RCRA Appendix VIII list (40 CFR 261.33,
Appendix VIII), the proposed addition to that list (Michigan Petition, 49 FR
49793. 21 December 1984), the priority pollutants, the Super-fund compounds
(Hazardous Substance List) the Paragraph 4C and Appendix C compounds, and
additional specific compounds which are part of the class or group of com-
pounds entered on one of the above lists. There are a total of 676 compounds
or classes of compounds on this list, with considerable overlap among the
source lists. Table 1 lists the number of compounds or classes of compounds
Identified in each of the source listings. The compounds on the source lists
total 946, but when redundancies are eliminated, the total is 676.
The ITO/RCRA "list of lists* shown in the Appendix contains empirical
formulas for the compounds, when possible, chemical abstract system ('CAS")
registry numbers, and other unique identifying numbers when no CMS number has
5
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been assigned, an indication of the type of analysis that is known or is
probably applicable, the promulgated EPA method, when there is one. and
reference to a RCRA method, when applicable. Identification of new and/or
modified analytical methods is under way, and this information is being
updated as methods are validated.
TABLE 1. SOURCE LISTS FOR ITO/RCEA ANALYTES
Source List Number of Compounds ITD/RCRA List
RCRA Appendix VIII 427
Hazardous Substance List 128
Priority Pollutant List 154
Michigan Petition • 121
Paragraph 4C 56
Appendix C 23
Sewage 37
TOTAL 946
676
The ITD/RC8A list of 676 compounds is clearly the most comprehensive
listing of regulatory-Identified hazardous compounds or classes of compounds
assembled to date. An objective of the ITD/RCRA Sewage Study project is to
Identify and validate sampling and analytical methods which would permit
quantitation of these pollutants in either trace or macro quantities in
hazardous wastes. It should also be recognized that several of the 676
compounds hydrolyze or react with water, which if present in the waste
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SECTION 3
SAMPLING METHODS
The sampling methods which are required for the ultimate analysis of the
ITD/RCRA list of compounds in hazardous waste must be applicable to a veriety
of media and waste forms. Hazardous waste forms may be solid, liquid, slurry,
or sludge. Hazardous waste from effluent process streams may also be gaseous
or particulste-laden gases, and in this context particulate matter includes
discrete particles from both solids and liquid aerosols.
The essential part of any sampling method 1s to assure that a sample is
acquired which Is representative of the waste that is being analyzed. The
analytical result 1s only as good as the sample which has been collected. For
waste thet contains two phases, and ones that contain particles of varying
sizes, it is essential that a maans for making such a heterogeneous mixture as
close to homogeneous as possible be employed. A means for agitating the waste
1s useful to ensure that a representative sample is acquired. Alternatively,
1f discrete phase.layers exist within a sample, it 1s also possible to obtain
a representative sample frora each layer and then by determining the relative
volume and/or weight of the layer within the waste, a calculated value of the
chemical constituents 1ri the combined separated waste can be made. In most
cases, an easier prospect is to use the prior approach of mixing a hetero-
geneous mixture and collecting as representative a sample as possible. For
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complicates their analysis. A classic example.>s the case of bis-chloromethyl
ether, which has a half-life in water of seconds. Because of the !?ck of
validated methods for many of the ITD/RCRA compounds, those compounds are not
now being used for regulatory purposes. The "11st of lists" is presented here
because it shows the direction to which the EPA 1s moving.
.^
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TABLE 2. CHOICE OF SAFJ'IERS FOR 5SAZARDOUS WASTE
Waste Type
Liquids, sludges and slurries.
in drums, vacuum trucks, bar-
rels, and similar containters
Liquids end sludges In ponds,
pits or 1639003
Wastes in storage tanks
Dry wastes (in shallow con-
tainers) and sjrface soil
Waste piles
Source - Reference 2
(b) Class
(o) Dipper
(b) Weighted Bottle
Weighted BHtlo
Powdered or granular solids in (a) Tliiof
bags, drums or containers
(b) Trisr
Trowel
Wasto Pile Sampler
L i a i to t ions/CommonIs
Nat tor containers X.&ia deep.
Hot for Bastes conjoining ketonus, nitrobenzene,
dioethylformamide, aoaityl oxide, or t.etrahydro-
furan.
Mot for oastss containing hydrofluoric acid and
concentrated alfciiii solutions.
Cannot be used to collect samples beyond 3.5m;
dip and rotriov:- eapplor sioojy to avoid
bending tho t~.ti'.;;«r aluoinua handle.
May be difficult to uso on viscous liquids; the
bottle may also bo used 83 Uio samp Io
container.
Uay be difficult to use on viscous liquids; the
bolt Id day also bo used as tho sample container.
Liaitod application for sampling ncist and
sticky no I ids end when the diameter of thr>
oolids is greater than 0.6 era.
Uay incur difficulty in retaining a core sample
of very dry granular materials during sampling.
Nob applicable to sampling cloopor than 8 cm.
Difficult to obtain c reproducible samplo mass.
Hot applicable to sampling solid castes nith
dimansions greater than one-half the diameter of
the sampling tube.
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effluent streams that have good points of mixing within the pipeline, the
collected proportional sample is a ready means for sample collection and
assumes a homogeneous mixtures has been acquired.
The preferred method for sampling hazardous waste depends upon the exact
form of the waste. Table 2 presents a summary description of general methods
which are to be used for the sampling of hazardous waste. Table 2 summarizes
the sampling devices appropriate for the hazardous waste sampling, and Table 3
summarizes sampling locations .'or most waste containers. Table 4 identifies
preferred methods for sampling effluent waste streams as a function of waste
type.
SOLIDS
A wide variety of sampling tools and equipment are available for the
sampling of solid materials. The methods most used for sampling of solid
hazardous waste are the sample corer (trier), the grain sampler (thief), and
the trowel, scoop or shovel.
The trier or sample corer consists of a long tuba with a slot that
extends nearly the entire length of the tube. The waste pile sampler Is
essentially a large sample corer. These samplers are easily fabricated from
sheet matal or plastic (PVC) pipe. The Up ani edgas of the tute slot are
sharpened to allow the corer to cut a core of material to be sampled when
rotated after insertion into the material. The sampler is inserted into the
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CONTAINER
bruit (bung on one ond)
Drum (bung on side)
TABLE 3. SAMPLING POINTS
SAMPLING POIHf
.Withdraw sauplo through the bung oponing.
Lay druir. on side eith bung up; BiUidra
bung
Barrels, fiberdrums, buckets, sacks, or
bags
Vacuum truck (or sienilar)
Ponds, pits, lagoons
Waste piles
Storage tanks
Soi Is
sample through the
Withdraw samples through the top uf Ijarrols, fiberdrums,
buckets, ond ,»irailar containers, or through Hi) openings of
bags and sucks; aithdrao sample through t!i(j contsr of the
containers and to different point? diagonally opposite the
point of entry.
Hithdraa sample through open hatch; maple nil other hat.hcs.
Divide surface oroo into an Imaginary grid;* take three
samples, if possible: one sample near surface, one sample at
mid-depth or at center, and one sample at the bottom; repeat
the sampling at each grid over tho ontiro pond or site.
subsurface sairple through at least three different
points near the top of pile to points diagonally opposite the
point of entry.
Withdraw cample from the top through the sampling hole.
Divide the surface area into an Imaginary grid;« sample each
grid.
«llie number of grids is determined by the desired nurr.ber of samples to be collected ohich, nhen combined,
will give a representative sample of tho naste.
Source - Reference 2
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TABLE 4. SAMPLING METHODS FOR EFFLUENT STREAMS
Waste Type Methods
Solids Scoops, Trowels
Liquids Proportional Samplers, Tap Sampler
Sases Gas Bulbs, Sas Bag Sampling, Fence line Monitors
Slurries Dippers, Tap Samplers
Particulate*-Laden Gases Stack Gas Methods:
Hodified Method 5 (MM5)
Source Assessment Sampling Systems (T.ASS). or
Volatr.e Organic Sampling Train (VOST)
*Includes solids and liquid aerosols.
waste at an oblique angle to a depth established by the sampling protocol to
ensure statistical- representation. The sampler 1s rotated and then withdrawn
with the open portion of the trier pointed upwards. The trier 1» the
preferred method whcri powdered or granulated material to be sampled is moist
or sticky. At any case, to ensure homogeneity for solid samples, cone and
quartering procedures are employed to reduce the total solid waste collected
dcwn to a size manageable for analytical measurements.
Alternatively, an auger can be used to obtain samples. It 1i particularly
useful for hard or packed solid waste or soil. An auger consists of sharpened
spiral blades attached to a hard metal central shaft. To obtain samples at
specified depths within i waste sample, 1t is usually necessary to drill down
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to a specified d-ipth and either isolate or discard the waste for the depths of
no interest and then proceed to use the auger for the desired additional depth
of the sample.
The grain sampler, also called a thief, consists of two slotted
telescoping tubes, usually made of brass or stainless steel. The outer tube
has a conical pointed tip on one end, which permits the sampler to penetrate
the rtaterfal being sampled. The sampler is opened and closed by rotating the
inner tube. While open, the sampler is shaken to pernit a free-flowing sample
to fill the interior of the sampler. The grain samp'ler is useful for
obtaining multiple samples at different depths within the free-flowing
hazardous waste sample.
The trowel. scoop and shovel procedures are often used to acquire samples
from conveyor belts. The laboratory scoop is similar to a trowel, except the
blade on the trowel is more curved and has a closed upper lip to permit thf.
containment of the material. An ordinary zinc-plated garden trowel can oe
used in some cases to sample dry, granular or powdered materials in bins or
other shallow containers. Tha laboratory scoop, however, is a better device
because it Is usually reade of materials less subject to corrosion or chemical
rsactions, thus minimizing sample contamination.
LIQUIDS
Liquid samplers that are most used for hazardous wastes include the
Coliwana, a weighted bottle (thief), a dipper, or pond sampler and a tap.
13
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The Coliwasa is a device employed to sample free-flowing liquids and
slurries contained in drums, shallow open-top tanks, lagoons, pits, and
similar containers. It is especially usefu1 for sampling waste that consists
of several immiscible liquid phases. The Coliwasa consists of a glass,
plastic, or matal tube equipped with an end closure that can be opened and
closed while the tube is submerged in the material to be sampled. Coliwasa
samples can be collected rapidly, thus minimizing exposure of the sample
collector to the potential hazards of the waste. In addition, the Coliwasa
sampler is simple to fabricate and inexpensive enough that contaminated parts
can be discarded after a single use if the parts cannot be cleaned easily. The
selection of the sampling tube material (PVC or porosilicate glass tubing) for
particular waste 1s determinc-d by the components of the waste (see Table 2).
fc
To. collect the waste sample, open the sampler by piacing the stopper rod
handle, push the rod down until the handle sits against the sampler's locking
block. Slowly lower the sampler into the waste at a rate that equalizes the
level of liquids cutside and inside the .sampler. If the level of waste in the
sampler is lower inside than outside, the sampling rate would be too fast and
will produce a non-representative sample. When the sampler Is submerged to
the desired depth or hits the bottom of the waste cylinder, push the sampler
tube down to close and lock the stopper by turning tha *T" handle until it 1s
upright and one end rests on the locking block. The Coliwasa 1s withdrawn
from the waste and wiped dry with a disposable cloth or rag. The waste sample
is transferred to a storage container and the process is repeated until a
14
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requisite quantity of sample has been collected. The use of Coliwasa is
limited to sample depths less than 1.5 meters. However, this is adequate for
waste containers, shallow lagoons, and drums, barrels, or tanks.
The weighted bottle sampler consists of a glass or plastic bottle,
sinker, stopper and a line that, .is used to lower, raise and open the bottle.
The weighted bottle samples liquid and free-flowing slurries from samples
contained in storage tanks, wells, sumps, and other containers which cannot be
sampled adequately with other liquid sampling devices. To acquire a- liquid
sample using a weighted bottle, the bottle is lowered to the appropriate
depth, uncapped, and after completely filled the sample is withdrawn. Once out
of the waste, the bottle 1s capped, rinsed off, and used as a sample storage
container. The sampler cannot be used to collect liquids that are Incom-
patible with or chemically reset with the weight sinker or the control lines.
The dipper ojr pond sampler consists of a glass or plastic beaker clamped
to the end of a two- or three-piece telescopic aluminum or fiberglass pole
(which serves as a handle). The dipper samples liquids and free-flowing
slurries from ponds, pits, tanks with open tops, and lagoons. Dipper samples
are collected from open streams such as sluices, or from open tanks where
there is sufficient access to permit the insertion and removal of the dipper.
The sample 1s collected by Inverting the beaker and Insertion of the pole into
the waste liquid or slurry at an oblique angle. At the appropriate depth, the
beaker is turned right-side up and allowed to fill completely, as evidenced
by the cessation of air bubbles at the top surface of the waste. The dipper
is raised and the sample is transferred to an appropriate storage container.
15
i.-i.-i a^..
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Tap sampling is the appropriate method for sampling liquid wastes in
static or effluent pipes or ducts. Coliwasa sampling is not appropriate to
the collection of liquids from moving streams. For liquids in motion, such as
Industrial discharges or scrubber waste mixtures, a tap either in the process
line or in the storage reservoir permits acquisition of a representative
sample. Commercial proportional samplers are often used to open and close
valves periodically and provide a time-aversged sample. In this method, a tap
1s attached to the waste stream line and a portion of the flowing liquid is
diverted Into a sampling bottle. When sampling non-volatile liquid products,
the sampling apparatus should be filled and allowed to drain before acquiring
the actual sample. If the actual sample 1s to be transferred to another
container, the sample container should be rinsert with sorae of the product to
be sailed and drained before it is filled with the actual sample. A propor-
tional saucer usually provides this rinsing ooeration automatically.
GASES
Hazardous waste gases are collected by a variety of techniques, depending
if they are from a static or flowing source. For static gases, it is first
necessary to know the pressure within the container. Hazardous /ilgh-pressure
gas under static conditions is sampled by allowing the gas to blow down into
either an evacuated vessel or a gas bag sampling system.
For gas bulb sampling, a glass bulb is evacuated prior to connection to
the sample line. The gas bulb is connected to the a valve on the container to
be sampled, and usually the volume between the tank valve and the gas sampling
16
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valve 1s evacuated. The gas storage tank valve Is opened and then the gas
sampling bulb valve is carefully cracked open and allowed to fill to
approximately 1 atra. A rsanon^ter 1s used to ensure that this pressure Is not
exceeded. If a corrosive gas 1s sampled, the pressure fssasuring device
contact surface must be cheia'.cally cofspat'ib'e with the toxic gas. It is
Important to not let the glass bulb pressure excsect 1 ats when siting a
high-pressure gas source oecause the high pressure could fracture the glass, or
blow out the valve stopcocks and hence lose the sample.
For Tow-pressure hj>--rdous gas s.'rsples (less than one
pressure), tne evacuated bulb 1s connected to the vessel and the volume
between the two valves 1s evacuated. Then tha tank 1'» opened -incs the sealing
bulb is opened and allowed to equilibrate at & reduced pressure. In this
Instance, however. If it 1s seen that any liquid 1n the gas changer begins to
froth, Indicating volatilisation of optional liquid, the sampling should
terminate and the pressure of the storags container and the glass bu'J> should
not be equilibrated; a non-representative sample of the gas above tfte liquid
could result 1f It were 3 slxturs of liquid waste compounds. Pnce the bulb 1s
filled, the sample valve Is closed and Mrra1y seeled. The bulb 1s removed and
shipped to the laboratory for analysis. It is desirable to have the glass gas
bulb to be contained 1n a box having an outer Uyrafoera jacket to provide
thermal Insulation during handling and for sample safety during shipping.
For aas. bag s amp 1 1nc. a non-reactive probe 1s attached to the
high-pressure hazardous gas container with a bag 1n the deflated position.
The tank is opened and the gas is Died into the gas bag, which is allowed to
17
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inflate. Gas bags are usually nade of Tedlar, which has been shown to be
compatible with most hazardous gas samples collected from the environment or
froiB effluent combustion streams. However, gas bag sampling should only be
used for those chemical constituents for which it is validated. Also, it is
Important that field blank gas bag samples are collected at the same time that
the field samples are acquired.
Fenceline monitoring systems are often used to acquire gaseous samples
which are emitted from open and closed hazardous waste storage areas and to
acquire fugitive emissions from industrial plants. Typically, these sampling
systeras consist of Tenax and/or XAO-2 sorbents through which the sample is
collected by a small pump which collect* and concentrates the sample over an
extended period of time. Tne trap/sorbent module is sealed and it is sent to
the laboratory for detailed analysis. For gaseous inorganic hazardous
constituents, charcoal, and in some cases, impingers filled with reactive
scrubbing solution are used to collect specific hazardous gases.
For f 1 owir.q gases such as that in incinerator combustion stacks or from
sources such as fossil fuel comhustors, several detailed sampling trains have
been specified by EPA to ensure collection of representative samples of the
gas and paniculate matter that may be present in this complex mixture. These
methods are used for regulatory purposes to ensure that an incinerator, for
exo.7.pVs, does its intended job of removing S9.995 of the principal organic
hazardous constituents (FOHCs) in the hazardous waste. During trial burns,
for example, the measurement of PGHCs in the stack gas effluent is an integral
18
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-------
port of the calculation of the destructive and removal efficiency (ORE! values
to determine whether the incinerator meets its performance criteria.
Similarly, flue -gas desulfurization control processes are sampled by these
procedures to ensure that regulatory removal efficiencies of sulfur in the
fuel are achieved. .
In general, the sampling of a stack gas is the most important part to
determining whether regulatory limits have been achieved. The sampling
apparatus consists of three major components:
e An extraction probe which must be resistant to the physical and
chemical reactions of the gas being sampled,
e One or more thermostatted compartments to maintain the gas at
temperatures consistent with thi collection medium, usually hot
(greater than 200"C) for particulate collection, and cool (less than
20°C) for sorbent collection of the more volatile constituents, and
e The sample collector.
The three major stack gas sampling trains for measurement of emissions are:
• The Hcdified Method 5 train (KH5).
9 The Source Assessment System (SAS), and '
a The Volatile Organic Sampling Train (VOST).
In addition, gas bulb and gas bag sampling systems have often been used.
^t.j^^.i^^v:^ .^
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The Modified Method 5 (KHS) sampling train is based on the design of
units which are used for sampling under EPA Method 5 (Ref. 6). The modified
system (Ref. 2) consists of a probe, an optional cyclone, a high-efficiency
glass or quartz fiber filter stage, a sorbent module, four impingers, and some
control hardware. A diagram of this system Is shown 1n Figure 1. The Method 5
procedure has been modified by Including & sorbent module which permits trap-
ping of volatile organic vapors and is mounted vertically atop the first
Impinger of the train. The first impinger Is empty and is used to collect the
cof^densate which percolates through the sorbent train module. Details of the
operation of this train for use 1n samollng hazardous waste combustion pro-
ducts are described 1n Reference 2.
Qjoott C?alK
Tftertaomotor
Vaoaora
Line
Vol»e
Dry Qo« Alr-TigSt
Mot-ar Patae
Figure 1. Modified Method 5 Train (MM5)
20
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By careful control of the temperatures within the train, organic
combustion products and POHCs are collected in the sorbent module. Typically,
the sorbent module is filled with XAD-2 resin, a porous polymer capable of
absorbing a broad range of organic chemical species. This sorbent module
provides efficient collection of vapor-phase organic materials with boiling
points >100°C. An oversized Impinger is placed just below the sorbent module
to collect high-moisture streams for subsequent organic analysis. The second
impinger is a modified version of the Greenburg-Smith design filled with
scrubbing solution. The selection of the scrubbing solution depends on the
type of vapors that are suspected of being contained in a stack gas. A
caustic solution such as sodium hydroxide or sodium acetate is used to collect
acidic gases such as HC.1, For collecting volatile metals, such as mercury,
arsenic or selenium, a strongly oxidizing solution such as silver catalyzed
ammonium persulfate must be employed. The third- impinger is a Sreenburg-SmHh
impinger with a tip with an appropriate scrubbing solution. The fourth
impinger is typically rilled with silica gel to absorb eny moisture in the
stack gas. Moisture removal is important to ensure accurate gas flow
measurements and to prevent damage to the pumping system.
The Source Assessment Sampling System, first utilized in 1972, is an
alternative integrated stack gas sampling system. It is essentially a
five-fold scale-up of the HM5 train and collects a larger sample, which
permits measurement of lower concentrations of trace-level emissions. In
addition, the SASS train also incorporates three cyclones and a filter in an
oven module to permit large co1lection capacities for particulate matter
kk'^a^&^fexa r;j^'^.^
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nominally size classified into three ranges: >10v,7i, 3ym to lO^m, and l^m to
3vflJ. By means of. a standard 142-flm or 233-ftmi filter, a fourth cut less than
lyro can also be obtained. This system is usually used more for industrial
sources when particularly dirty particulate emissions are generated.
In 1982, a new sampling train, the Volatile Organic Sampling Train
(VOST), was developed and tested and shown to be most effective in determining
volatile hazardous constituents in incinerator effluents. This system was
developed as an alternative to the uss of the integrated gas bag sampling
device or the gas bulb sampling system for the collection of volatile PCHCs.
A schematic diagram of this train is shown in Figure 2. In this system, the
first trap contains Tenax absorbent, which is preceded by a gas cooler/
condenser and followed by an impinger for condensate collection. A second
trap, containing a section of Tenax and a section of charcoal absorbent, is
located after the impinger. The purpose of the second trap is to collect very
volatile compounds 'tertich readily break through the initial Tenax trap. The
method for use cf the VOST also requires reolacing both pairs of traps with
fresh traps every 20 minutes (when a 1-L/min flow rate is employed ovsr a
two-hour sampling period for a total of six pairs of traps). The serial col-
lection of several pairs of traps assures that the more volatile components
will not pass through both the first Tenax trap and the Tenax/charcoal trap.
The six pairs of traps are usually combined for subsequent desorptlon and
analysis.
As discussed earlier, it is essential to collect representative samples
for analysis. For the sampling of physical forms of solids, liquids, gases,
22
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Wool
Portlcolata Fitter
Ezhouot *
1 M«or/ralrt
Coesdonoato
trap itaptttgor
Empty Silica
Gel
MOTE:
Botn tropo eftould be c
out every 20 ralrietes over
2 hoer psr'od.
Figure 2. Volatile Organic Sampling Train (VOST)
and combinations in slurries, sludges, and particulate-laden gases, specific
sampling protocols usually provide for acquiring representative samples. After
a sample has been acquired and transferred to the proper sample container, the
container must be tightly capped as quickly as possible to prevent loss of
volatile components and to exclude possible oxidation from the atmosphere. In
general, samples of organic hazardous waste are stored in glass containars and
samples of hazardous metals are stored in plastic containers. Organic samples
are usually stored at 4-6°C to preserve their chemical composition. Water
samples used for metal analyses are usually preserved with nitric acid,
depending on the metals of question. A discussion of sampling and sample
preservation of hazardous materials in water and wastewater is provided in
Reference 7, dealing with industrial wastewater. municipal wastewaters,
agricultural discharges, surface water, sludges, and suspended solid samples.
23
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SECTION 4
ANALYSIS METHODS
As r-mntione«S briefly 1n the Introduction, the RCRA regulations require
that a waste to 045 Identified as 'hazardous" roust have at least one of the
following four characteristics:
(1) Ignitability,
(2) Corros1v1ty,
(3) Reactivity, and/or
(4) IP Toxicity
The isethods used to classify a waste for the:;e four characteristics and the
criteria employed are summarized in Table 5. Detailed procedures for these
laeisur-ments are given 1n Test Methods for Evaluating Solid Waste - Physical/
Cfieraica'i Methods, SW-84& (Ref. 1). These procedures are used to determine
whether the wastes exhibit the characteristics of a hazardous waste as defined
by Sactlon 3001 of RCRA.
Tha objective of the Ignltabilitv Characteristic is to identify wastes
•that ara either present fire hazards under routine storage, disposal and
transportation, or are capable of severely exacerbating a fire once started.
A solid waste is considered to exhibit the characteristic of 1gn1tab1lity 1f a
representative sample of the waste has any of the following properties:
24
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I'-
CHARACTERISTIC
ICNITAB1LITY
rv>
ui
REACTIVITY
TABLE 5. HASTE EVALUATION PHOCEDURES
METHOD/CRITERIA
I. Flash Point <60* -
• Pansfcy Mortens Closed Cup (RCRA 10JO) , or
• SataH ash Closed Cup (RCRA 1020)
CORROSIVITY 1. pit *2 or J12.6 - RCRA 040, or
2. Corrodus SAE 1020 Steal >6.35 emfyr - RCRA 1110
Professional Judgement: °
forms potentially
Undergoes violent chemical ciienges,
Reacts violently with H^O or
explosive) mix'-ures with I^O,
Generates toxic furtias with "IjO, or in the cose of
cyanida or sulfio'e nsslos nhsn exposed to oildly acidic
or basic conditions,
Explodes at normal temperatures and pressures, or alien
subjected to a 3tror:-tf initiating force ,: at eleval.nd
temporflturo, or
Is a DOT Class A or Ctoss 0 Fnplosivo.
EP fOXICITY Waste extract cocposition exceeds ony of 14 specific chemical concentration levels
(8 metals, 4 pesticides and 2 herbicides); Extraction Procedure (EP) defined in
RCRA 1310; Metal Methods 7060, 7080, 7130, 7190, 7420, 7470. 77<0, and 7760;
Pesticides 80GO; and Herbicides 8150.
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o It 1s a liquid other than an aqueous solution, containing less than 24
percent alcohol by volume and has a flash point of less than 60°C.
o It 1s not a liquid but is capable, under standard temperature and
pressure, of causing fire through friction, adsorption of moisture, or
spontaneous chemical changes, and, when Ignited, burns vigorously.
e It 1s an 1gn1table compressed gas; or
e It Is an oxidizer.
The objective of the Corrosivity Characteristic 1s to identify wastes which
raight pose a hazard to human health or xo the environment because of its
ability to:
o Itobilize toxic metals 1f discharged into a landfill,
o Corrode handling, storage, transportation, and management equipment, or
o Destroy human or animal tissue 1n the event of inadvertent contact.
Solid waste is considered to exhibit the characteristic of corrosivity if a
representative sample has either of the following properties: It 1s
aqueous and has a pH *1 or >12.5; or 1s a liquid and corrodes steel at the
rate of >6.3S ram/year at a test temperature of 55"C.
Tne Reactivity Characteristic of a hazardous waste defines a reactive
waste as one having any of the following properties:
o Readily undergoes violent chemical change,
e Reacts violently or forms potentially explosive mixtures with water,
26
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^
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e Generates toxic fumes when mixed with water, or in the cas? "f
cyanide- or sulfide-bearing wastes when exposed to mild acidic or
basic conditions. :..
e Explodes when subjected to a strong initiating force,
9 Explodes at normal temperatures and pressures, or
& Fits within the Department of Transportation's Class A or Class 8
Explosive classification.
Reactivity 1s determined by applying the best professional judgements to the
available data. There are no explicit" experimental test procedures for
determining this characteristic.
The Extraction Procedure Toxlcity Characteristic is determined by a test
designed to simulate the leaching a waste will undergo If disposed of in an
improperly designed sanitary landfill. Tnis laboratory test consists of
extracting a representative sample of waste with distilled water maintained at
a pH of 5 using acetic acid. The extract obtained from the EP (the "EP
Extract") is then analy:r.d to determine if any of the thresholds established
for the eight elements (arsenic, .barium, cadmium, chromium, lead, mercury.
selenium, silver), four pesticides (endrln, Undane, roethoxychlor, toxaphene),
and two herbicides (2,4,5-trich1orophenoxypropionlc acid, 2,4-
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TABLE 6. THRESHOLD LEVELS OF CONTAMINANTS IN THE
EXTRACTION PROCEDURE TOXIC1TY T'-ST
Contaminant
Metals
Arsenic
BaMuaj
Cadmium
Chromium
Lead
Wercury
Selenium
Silver
Pesticides
EndMn
Lindane
Hethoxytiilor
Toxaphene
Kert>1c1dos
2,4-01ehlorophenoxyacet1c add
2.4,5-Trlchlonjphenoxypropionic add
Threshold Level (mg/L)
" S.O
100.0
1.0
5.0
5.0
0.2
1.0
5.0
0.0?
0.4
10.0
. 0.5
10.0
1.0
RCRA Method
7060
7080
7130
7190
7420
7470
7740
7760
8080
8080
8080
8080
8150
8150
28
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In the extraction procedure, a waste containing unbound liquid is
filtered and if the solid waste is less than half a percent of the waste, the
solid phase is discarded and the filtrate analyzed for trace elements.
pesticides and herbicides. If the waste contains more than 0.5 percent
solids, the solid phase is extracted and the liquid phase stored for later
use. Prior to extraction, the solid material must pass through an O.S-RCT
standard sieve. If the waste consists of a single piece, it must be subjected
to the structural integrity procedure (SIP), which is used to demonstrate the
ability of the waste to remain intact after disposal. If the waste does not
meet one of these conditions, it must be ground to pass a 9.5-ron sieve. After
extraction, the liquidrsolid ra\'.^ is adjusted to a 20:1 v/v and the resulting
liquid extract is separated by filtration. The solid is discarded and the
liquid extract is combined with any filtrate obtained during the initial
separation.
Currently, the EPA Office of Solid Waste is examining an alternative
procedure called the Toxic;ty Characteristic (.caching Procedure (TCI?), which
uses a zero headspace extractor and generates analysis samples for volatile
and serai-volatile organic constituents, pesticides, and metal species. This
new procedure is undergoing interlaboratory validation prior to publication
for public comant.
29
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SURVEY ANALYSES
The hazardous waste characteristics have been stipulated as regulatory
requirements. Often, 1t 1s desirable to obtain survey Information regarding a
hazardous waste 1n order to guide the detailed characterization of specific
chemical species In the waste. Th.2 survey Information often consists of
proximate analysis of the waste, as well as survey analysts of organic and
Inorganic species.
Proxiraate analysis Includes determination of physical properties such as
moisture, solid, and ash content, as well as determination of such chemical
properties as the total organic carbon, total organic halogen, eleraantal
coar; . ivion. viscosity, and heating value of the waste. TMj latter paranseter
\r, particularly important when the waste 1s to be considered for disposal by
Incineration techniques. These mathods are listed in Table 7. Proximate
analysis provides the data relating to the physical form of the waste and
provides an approximate mass balance of Its composition. This Information
meets the waste analysis requirement of 40 CFR 264, Subpart 0 regulation, and
1s also responsive to the general weste analysis re
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TABLE ?. PROXIMATE ANALYSIS Or WASTES
Characteristic Method
Moisture Content Loss to constant weight on oven drying
at 103'C for one hour.
Solids Content Calculated ai residual weight after oven
drying.
Ash Content Solid residue after ignition of sajfiple
at 60Q°C for 30 minutes.
Elemental Cotnposition Determined by standard microchefljicsi
Pregl train methods
Total Organic Carbon TOC Analyzer measures C02 if-A CH^ on
combustion of sample.
Total Organic Halide TOX Analyzer measures acic! x-iides
forrsed during comoustion of jjppte.
Viscosity (of liquids) Kinematic (Ostwalrf) Visccnseter at con-
stant temperature.
Heating Value Ad1atat1t bomb c
Survey chemical analyses are designed to provide an overall description
of the sample i:: terras of (1) the major types of organic comaounds, and (2)
the major inorganic elements (rcetals) that are present. The survey analysis
package includes determination of:
& Total organic content by chromatographic (TCO) and gravimetric (GHAV)
procedures.
e Organic compound class types present Cy infrared (18). and orobe mass
spectrcroetric procedures.
. 31
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9 Major organic componants by gas chrcmatography/niass spectrometric
(GC/KS) or high performance liquid chromatographic/lnfrared (HPLC/IR)
or high performance liquid chromatographic ,-nass spectrometric
(HPLC/MS) procedures, and
s Metals by Inductively coupled argon plasma emission spectroscoplc
(ICAPJ and atomic absorption spectroscoplc (AAS) procedures.
The type and data generated by survey analysis provides a qualitative
description of the overall chemistry of the sample. TMs information 1s
Important 1n deciding which of the hazardous constituents it, the ITD/RCRA list
are present 1n the waste, and may lead to the prediction ar,fl/-<" identification
of alternative, previously unsuspected constituents in the wr.3t».
In recent years, the use of survey analysis procedures has diminished
significantly because of major enhancements 1n the capillary column gas
chronatographic/mass spectrometric/data system (CCGC/HS/DS) techniques and the
use of specific stable labeled internal standards. The use of improved data
system. „ target compound search computer software has also significantly
Improved and its cost has diminished so that often analysts prefer to go
directly to a quantitative/seroi-quantitatlve procedure without employing a
survey method. In addition, tha use and application of HPLC, improved
detection systems and ICAP have also Improved markedly so that it is more
cost-effectlva to go directly to the direct compositional analysis. The
reader is referred to Reference 2 for additional details regarding the use and
application of the survey'methods.
32
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SAMPLE PREPARATION PROCEDURES
Samples collected in the field usually roust be treated by a series of
special techniques to permit their- conversion into a matrix which is
compatible with the final analysis methods needed for measurement of the
specific hazardous constituent. The techniques vary significantly and depend
on whether the hazardous species under question is organic or inorganic in
nature, and the nature of the waste itself, whether a gas, liquid, or solid.
The sample preparation scheme for analysis of the organic components may
require extraction of the sample, concentration of an extract, and/or the
cleanup of a sample extract to remove potential interferences. Surrogate and
standard addition methods are often used to facilitate quantitation, determine
the degree of recovery of the species in question from the matrix, and provide
information regarding the precision and accuracy of the resulting data.
Digestion of a sample is necessary prior to the analysis of metal inorganic
constituents. For aqueous wastes, ii is not necessary to digest the sample
for metal or anion analyses.
The sample preparation method often depends on the final oesirad
analytical method of choice. In general, because of the high sensitivity/
selectivity of fused silica capillary column GC/MS, this procedure is
generally the analytical procedure of choice. Because of its wide
applicability and generally good quantification capability, this method has
been selected by EPA's Office or Emergency and Remedial Response as the
primary procedure for characterization of o-ganic constituents in hazardous
wastes (Ref. 8). In their procedures, the sample preparation technique is
33
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relatively simple and straightforward. However, if other procedures, such as
packed column gas chroroatographic methodology with specific detectors other
than mass spectrometry are employed, often other clean-up techniques are
required to remove potential interfering compounds which could cause confusion
in the characterization of the specific target chemical compound. The
generally used sample preparation procedures are delineated in Table 8 and are
discussed below.
ORGANIC CONSTITUENTS
Liquid/liquid extraction is the primary method used to extract non-
volatile and serai-volatile organic compounds from liquid samples. Liqjid/
solid extraction is used to extract these compounds from solid samples.
Hethylene chloride is the preferred low-boiling solvent used to extract
aqueous matsrials using either sap&ratory funnels (RCRA 3510) or continuous
liquid/liquid extractors (RCRA 3520). The continuous liquid/liquid extractor
is advantageous compared to the separatory funnel method because it minimizes
the formation of emulsions and can be performed with minimum labor.
The classes of organic compounds in aqueous-based waste are separated by
regulating the pH of the aqueous phase prior to extraction with nethylene
chloride. Sample preparation for the pesticide/PCS constituents In aqueous
wastes are accomplished by extraction with methylene cnloride of a sample that
has been treated to be neutral (acidity between pH 5 and 9). Separately,
sample preparation for extractable base/neutral and acid fractions are
34
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Constituents
TABLE 8. SAHPLE PREPARATION PROCEDURES
Method
fi'l
K. .
li
CO
cn
Inorganic:
Acid Digestion
RCRA 3010; IIN03 digestion of uaiapKa; dissolvo digoatato in 1:1 MCI.
RCRA 3020; IIN03 dif)ostioii of ttampla; dissolve di floats te in 0.63 v/v H?1Q3.
RCRA 3030; Digest ion of samples containing oils, greases, or BDMOS using
and
Organic Solvent Dissolution
Alkaline Digestion
Organic:
Liquid-Liquid Extraction
Soxhlet Extraction
Sonication Extraction
Purge and Trap
Head Space
RCRA 30.C0; IINOa/lioOj digssticn of sludges; digastate is aolubitized cith either IICI or
HN03.
RCHA 3040; Use xyleno or mothyl isobutyl ketone to dissolve oils, grease or «ax
samples; organomctol I ic standards nro used.
RCRA 3060; Digestion of oarnpla cit>. No2C03 and NaOII to dotorraina Cr<5.
RCRA 3510; Adjust pli, extract «ith oothylere clilorido using acparatory fuiinol; obtain
three froctiona A/0/Nt dry nith Na/jSO^ and concontrato.
RCRA 3520; Alternative to RCRA 3510, but uses a continuous extractor.
RCRA 3540; Soxhlet extraction of soils/sludges; extract is dried and concentrated;
methyfana cliloriu'n cthor, acolono/hexana, and ber.!one/tnotl>anol common
extraction solvents.
RCRA 3550; AJto.i^tivn to RCRA 3540. but uses sonication to so'uhiliza sample.
RCRA 5030; Volatile organic spocies arc uuparatod from samp I « by purging with He and
sorbed on Tona* sorbont; sorbont is then heatod, backflushcd eith Ito onto
GC column,
RCRA 5020; Ullacjo votutae of vaste container is sampled using a gas syringe acid
injected into CC.
I!
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accomplished by adjusting a measured volume of the sample, first to a pH
greater than 11 and then extracting with raethylene chloride, and then
adjusting the acidity of t.he aqueous phase to a pH less than 2 and extracting
it with a separate second portion of methylene chloride. The methylene
chloride extracts are generally concentrated and dried by treatment with
anhydrous sodium sulfate and concentrated using a Kuderna-Danish methodology
to a final volume of 1.0 ml (Ref. 8),
Surrogate standard spiking solutions and base/neutral acid matrix
standard spiking solutions are employed to permit calculation of (1) the
aqueous soil surrogate percent recoveries, (2) the matrix spike and matrix
spike duplicate percent recovery results, and (3) the relative percent
difference between duplicate analyses. A method blank is run concurrently
r '
using an equivaTent volume of deionized distiller, lasor?.tory water for water
samples,' or a ourified solid matrix for soil/sed-ment samples carried through
the entire analytical scheme of extraction, concentration and analysis. The
metnod olank volume or weight must be approximately equal to sample volumes or
sample weights being processed. Surrogate standard determinations are
performed on all samples and blanks.
All saraples and blanks are fortified with surrogate spiking compounds
before purging or extraction in order to monitor preparation and analysis of
•samples. In order to evaluate the matrix effects of the sample upon the
analytical methodology, the USEPA has developed standard mixes to be used for
matrix spikes and matrix spike duplicate analyses.- The surrogate spike method
36
^^^M^^^^£^^^^^s^^:^£i.^^^^
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blank and matrix spike duplication analyses are i -d as Quality assurance
procedures to ensure that the data generated are complete, representative,
comparable, valid, of kncun precision and accuracy, and legally defensible.
The CERCLA regulatory procedure- for preparing soil sables consists of
ultrasonic extraction of dried soils/solids with methyl?;ne chloride after
surrogate standards are added to all samples, spikes and blanks. A matrix
standard spiking solution is added to two 1-gtn portions of the sample chosen
for spiking. After sorsication for two minutes at 100-vatts power with pulse
set at 50 percent., the methylene chloride extract is separated from the soil by
filtering through glass wool and then concentrated to a final volume of 1 ml
by & nitrogen blow-down technique.
Pargeable (volatile) organic compounds in these • samples are first
screened on a gas chroraatographic/flame ioniration detector (GC/FIQ) to
determine the approximate concentration of organic constituents in the
samples. The actual sample preparation is based on a purge and trap method
(RCRA 5030). For the sediment/soil samples, the purge device is heated. For
water samples, an inert gas is bubbled through a 5-rL sample contained in a
specifically designed purging chamber a*, ambient temperature. The purgeable
constituents are efficiently transferred from an aqueous phase to the vapor
phase. The vapor is swept through a sorbent column where the purgeables are
trapped. After purging is completed, the sorbent column is heated and
backflushed with an Inert gas to desorb the purge&bles onto a gas
chromatograohic column. The gas chromatograph is temperature programmed to
37
.-..."-,. . ,<,-•• • •••-' ••'- - -• ' •' •--
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separate the purgeables-which are then detected with a mass spectrometer. For
sediment/soil samples, an Inert gas 1s bubbled through a mixture of a 5-s
sarcple and reagent water contained in an especially designed purging chamber
maintained at elevated temperatures.
For sorae samples, the level of Interfering compounds is sufficiently high
to preclude successful analysis of the analytes of Interest. For these
samples, one or more clean-up steps should be considered to facilitate the
final analysis step. Clean-up, methods such as size.exclusion chromatography,
liquid column chromatography, using columns filled with silica gel, Forisil,
activated alumina, charcoal, etc.; solvent partitioning and filtration may be
used alone or in coraijlnacion to cleanup the samples for analysis. A ceranon
solvent partitioning technique* used for the cleanup of polychlorinated
biphenyl compounds consists of treating the sample with a mixture of
concentrated sulfurlc add and hexane. In this case, the PCBs are partitioned
into the hexane layer and aqueous constituents and many organic compounds are
retained in the sulfuric acid layer by reacting with the sulfuric acid and
farming a sulfuric acid soluble product.
IMORSAWIC CONSTITUENTS ' "
Preparation procedures for all wastes containing metals include a
digestion step unless it 1s an aqueous waste and can be used directly. The
digestion procedures, RCRA Methods 3010, 3020. 3030, and 3050, are acid
digestions, with varying degrees of acid strengths and oxidizing capabilities.
38
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Alternatively, oils, grease and waxes can be solubilized, often using xylene
or methyl Isobutyl ketone as solvents. In this case, organometallic standards
are used for the metallic species. In the special case of determining the
amount of chromium 1n the +6 valence state, alkaline digestions are employed,
using basic carbonate media.
ORGANIC ANALYSIS METHODS
The EPA Superfund (CERCLA) regulatory procedures consist of using a
comprehensive capillary column gas chromatographlc/mdss spectrometric/data
system technique for characterizing a wide range of analytes (Ref. 8). This
has been proven to be the most cost-effective way to characterize a wide range
of analyte chemical classes. As discussed in the sample preparation section,
the wastes are Isolated into four separate fractions by extraction and purge
and trap techniques. These fractions, the pesticide fraction, the acid
fraction, the base/neutral fraction, and the volatile organic constituents
(VOCs) fraction a-e analyzed by capillary column gas chromatographic/mass
spectrometric/data system (CCSC/MS/OS) techniques.
The CC6C/KS/DS. method is extremely powerr'ul because it can provide both
qualitative and jemi-qualitative results. The mass spectrometer used must be
capable of scanning from 35 to 500 amu e>,;*v one second or less, utilizing 70
volts nominal electron energy 1n the electron impact ionization mode and
producing a nwss spectrum which meets all the requirement's and criteria when
50 ng of decafluorotripheny Iphospfiine (0CTPP> is injected through the GC
Inlet. A computer data system must be interfaced with the mass spectrometer
39
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that .allows continuous acquisition and storage on machine-readable media of
all mass spectra obtained throughout the duration of the chrosnatographic
program. T.ie computer must have software that allows searching any GC/MS data
file for Ions of specific mass and plotting such ion abundances versus time or
scan number. This type of plot 1s defined as an extracted 1on current profile
(EICP). Software roust be available that alloys integrating the abundance in
any EICP between specified time tr scsn r.uwUr- limits..
A key factor 1n the use of computerized r::'.ss spectra search systems 1s
the data base. Tentative identifications are obtained from the GC relative
retention time Information and the examination of specific mass spectra for
the individual gas chroraatographic peak of either a pure compound or certainly
a limited num&er of confounds, and comparison with the data base usually
provides uneculvocal characterization of the ccrnpounds. The computerized
reverse-search systems have been enhanced so that a series of target compounds
can be Identified with search routines requiring less than throe seconds per
target compound (e.g., a-search of TOO compounds in less than five minutes).
Algorlthras for goodness-of-flt parameters and the values associated with
specific levels of confidence in the identification vary, depending upon the
particuUr software employed. For this reason, it 1s essential to also use
the professional judgement of the mass spectroscopist to verify that all
compound identifications are accurate.
40
I. V
fcii^&I&aE^
-------
Since 1980, the use of stable labeled surrogates as internal standards in
combination with the CCGC/MS/OS characterization of pollutants has been a
further significant enhancement of the analysis of samples containing
hazardous compounds. In this method, the stable labeled analog behaves
chromatographlcally Identical to the target compound; however, its mass
spectrum is clearly distinguishable from the non-labeled compound in the
sample. In EPA Methods 1624 and 1625 (Ref. 9), a total of 32 and 65 s~?cific
stable labeled Isotopes, respectively, are used in an isotope dilution mode as
internal quantitation standards. This approach has resulted in enhanced
precision and accuracy of analysis; it has also been determined thet the
calculated percent recoveries using Isotope dilution are uniformly unaffected
by the sample matrix. The availability of stable labeled analyte standards
has increased significantly since Its Initial examination for pollutant
analysis purposes. The commercially available useful stable labeled compound:
has grown from 36 to over 107, and 1t appears that additional compounds will
be available to support the analysis of many of the pollutants listed in the
ITO/RCRA list (see Appendix).
Detailed CCSC/MS/OS procedures for the analysis of chlorinated dibenzo-p-
dioxlns and dibenzofurans are given in RCRA Hethod 8280 (Ref. 10). This
method utilizes an analytical extraction clean-up procedure, a CCGC/MS/DS
method and 7C1 stable labeled internal standards. If interfering
substances are still presen-c after the initial clean-up steps, the analyses
are separated from the interfersnces using an HPtC clean-up procedure.
S^^^^
-------
Hany of the high-molecular weight, non-CCGC separable compounds listed 1n
the Appendix can be analyzed by high-performance liquid chromatography (HPLC).
This method uses specific hardware consisting of reservoirs for the elution
solvent(s) which may have a system for blending two solvents using a gradient
mixing device, pumps, injection port, columns, detection, and rsad-out
devices, and thermostats for the colutsn and detector. These components are
consBercially available as Individual modules or for incorporation into a
«
complete HPLC system. The most common HPLC detectors utilize ultra-violet
absorption or fluorescence emission at a single wavelength. Polynuclear
aromatic hydrocarbons are often analyzed by HPLC methods whon those are the
primary constituents in the waste (RCRA Method 8310).
Another analytical method that is receiving considerable Interest in
analyzing complex mixtures is one of liquid chrofratography/oass spectrorcetry.
In this case, a separation 'Of non-volatile materials occurs by liquid chroiw-
tography and then a thermosprgy injection technique is used for introduction
of the liquid compound Into the mass spectrometer. This advanced methodology
is currently under considerable research at the present time. It Is believed
that sorse analytical procedures for specific compounds will be recommended for
use 1n the near future.
KONITORIHG
For many hazardous wastes generated routinely in industrial operations,
or where the waste is relatively well known, monitoring techniques can be most
useful! In this case, the high-resolution, comprehensive capability of the
42
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CCGC/MS/DS 1s not required and less sophisticated and less costly methods,
such as packed column gas chromatography with specific detector capabilities.
can be 'employed successfully. These methods were initially tested and
validated for use in characterizing organic wastes in wastewaters, surt'aca
waters and industrial discharges to satisfy the Clean Water Act requirements
and the National Pollution Discharge Elimination System (HPDES). Procedures
coftsnonly used for monitoring organic constituents after use of specific
clean-up methodology are listed in Table 9.
INORGANIC CONSTITUENTS
Inorganic constituents of wastes are categorized as metal or metal-
containing, anion-containing, or gases. Met.jl-containIng species in wastes
are usually analyzed by atomic absorption spectroscopy (AAS) or Inductively
coupled plasma emissions spectroscopy (ICAP) techniques. Two modes of
analysis are used for these species; direct analysis from solution, or coal
vapor/hydride evolution. The choice of analysis technique depends upon the
specific metal of interest and required detection sensitivities.
For all the metals, except arsenic,, selenium, and mercury, the solution
resulting from the digestion preparation procedure may be aspirated directly
Into the flama AAS or into the plasma for ICAP, or injected directly into the
furnace for Nameless AA analysis at a wevelength which is specific to the
element under Investigation. The spectrometer is adjusted so that only the
specific wavelength(s) of interest are detected at the photomultiplier
detector. The amount of absorption or emission which occurs during the AAS or
ICAP experiment Is directly related to the concentration of the metal present.
43 .
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j
V
TABLE 9. RmJTINE/KOH/TORIKn ORGANIC ANALHICAL KETMODS
Organic Spocies
llalogenalod Volctlle Ccejx/undc,
Volatile Organic Compound*
Volatile Aroootic Compounds
Acroloin, Acrylonitrilo, Acetonitrilo
Phenols
f'hthatato Ester*
Organochlorido Pesticides ft PCOa
Ni'.ro arooatic compounds end
Cyclic kgtones
Polynuclear Arcaotic Compounds
Chlorinated Hydrocarbons
Qrganophosplwruo poalicidos
CMori.;atod Herbicides
Method
RCRA SOlO-Puryo end trap Injection irito pecked cnluon CC/CCD
RCIIA OOlS-Puroo and If no 'r. joe I ion into packed column progrr.CTt.od CC/I ID
HCBA 80?0-Pjf6O end trap Injection into packed coluan progrnoraod CC/FJO
RCRA 8030-Purr
-------
For selenium and arsenic, the solution resulting from the digestion of
the sarr/ple 1s treated w4th stannous chloride to forra Intermediate reduced
species, As02 and SeO,. The solution 1s then treated with zinc
rectal, converting the reduced species to the volatile hydride. The hydride 1s
then detected by the A.AS method. For rsercury, the solution resulting from the
digestion of the saaple 1s treated with stJp.nous sulfate, which reduces the
Ionic csrcury in the sample to the atomic species. The volatile atomic
raercury 1s swept from the sample in a closed system to an absorption cell to a
scrubber trap. The level of (cercury 1n the vapor is obtained from the Inte-
grated AAS signal foraad during ns evolution fron the Sereple.
External calibration curves £ -e prepared by plotting the absarbance (AAS)
or transmittance (IC/'-f-J versus concentration for a series of standards which
span the linear working range of the analytical Instrument. On comparing the
measured absorptions (or transmittance) of the sample analyzed under the sam?
conditions as trie standarti, the concentration of material in the sample can be
interpolated from a calibration curve. Table 10 lists the KC2A procedure used
to characterize the hazardous metal content of. wastes.
SOJES of the inorganic species listed 1n the ITO/RCRA list (sec Appendix)
are hazardous because of the anionic portion of the confound. These com-
pounds. which contain either cyanide, phosphide, or sulfide, are analyzed by a
single method for that anion. The general procedure for the determination of
anions in solution employs 1on chronatography as the preferred analytical
technique. It should be noted that some of the sample preparation methods can
45
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TABLE 10. RCRA METHODS FOB RETAL ANALYSIS OF WASTES
RCRA Method Number
Ketal
Antimony
Arsenic
Bariura
Beryllium
Cadmium
Chromium
Copper
Lead
Mercury
fHcfcel
Osnri urn
Selenium
Silver
Thallium
Vanadium
Z1nc
*€aseous Hydrlda
**Cold Vapor
AAS
7040
7061*
7080
7090
7130
7190
7210
7420
—
7520
7550
7741»
7760
7840
7910
7350
Kethod
AAS-GF
7041
7060
7081
7091
7131
7191
7211
7421
—
7521
7521
7740
7761
7841
7911
7951
ICAP Other
6010
6010
6010
6010
6010
6010
6010
6010
— 7440**
6010
6010
~
6010
6010
6010
6010
46
fcaaesa;
-------
convert these compounds to volatile species, which could be removed from the
waste inadvertently. Care must be exercised during the sample treatment
effort to either intentionally trap these volatile species or use an
alternative method (alkaline digestion/extraction) to ensure their retention
in the sample.
Scrubbing the effluent from the acid treatment of waste containing
cyanide with sodium hydroxide solution permits retention of the cyanide, which
subsequently can t
-------
SECTION 5
QUALITY ASSURANCE AND QUALITY CONTROL PROCEDURES
An essential part of any sampling and analysis program 1s the provision
for procedures which maintain the quality of the data throughout the sampling
and analysis effort. The level of quality assurance applied to a specific
activity depends upon the project objectives and the end ^ses of the data
generated. Usually, a flexible program is generated which also ensures that
all data are of sufficient and appropriate quality to meet sampling and
analysis project requirements. It is essential that these data are complete.
representative, comparable, valid, of known precision and accuracy, anu
legally defensible. Quality assurance (QA), therefore, represents the total
Integrated program for assuring the reliability of monitoring and measurement
information. The assurance of this reliability 1s, in turn, maintained
through the use of discrete quality control (QC) functions wnlch involve the
routine application of procedures for obtaining prescribed sampling and.
analysis standards of performance.
The US EPA has established a requirement that all measurement activities
are covered by a Quality Assurance Project Plan (QAPP). This section provides
a brief description of the essential elements to this plan which satisfy the
mandatory EPA requirements (Ref. 11). These 16 essential elements are listed
1n Table 11. The first three elements of the QAPP are self-explanatory. The
project description is typically presented in some detail, whether the plan be
primarily an analysis of waste provided by EPA contracted sampler organiza-
tions, or the activity be an application of a control technology such as
48
; ;'^^I^
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TAbLE 11. ESSENTIAL ELEMENTS OF A QA PROJECT PLAN
1. Title Page
2. Table of Contents
3. Project Description
4. Project Organization and Responsibility
5. QA Objectives
6. Sampling Procedures
7. Sample Custody
8. Calibration Procedures and Frequency
9. Analytical Procedures
10. Data Reduction, Validation, and Reporting
11. Internal Quality Control Checks
12. Performance and System Audits
13. Preventive Maintenance
14. Specific Routine Procedures Used to Assess Data
Precision, Accuracy, and Completeness
15.. - Corrective Action
16. Quality Assurance Reports to Management
incineration or landfilling. A brief summary of the project, a list of the
waste to be treated, specific analyses to be performed, and target analyte
detection limits are usually provided.
In the project organization and responsibility section, Individuals who
have responsibility for the following functions in specifying the QA/QC
program are identified:
49
L&^v^lfe^.;^
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e Project Manager,
o The Quality Assurance Coordinator,
i
0 The Analysis Coordinator,
o The Sampling Coordinator, and
e The Quality Control and Sata Manager.
*
These individuals all have specific functions in conducting the measurement
activities which need to be described in the QA Project Plan,
The quality assurance objectives of the measurement activity are sum-
marized in terms of precision, accuracy, completeness, representativeness, and
comparability for each measurement parameter. Quality assurance objectives
for accuracy and precision will' be based on prior knowledge of the measuremint
' «,
system employed and methods validatio'/i • study using replicates, spikes,
.standards, calibration, recovery studies,^ etc., and the requirements of the
specific effort.
For each major measurement parameter^}, including all pollutant mea-
surement systems, the sampling procedures will be described. To be included
are descriptions of techniques or guidelines, use of selected sampling sites,
inclusion of specific sampling procedures, charts, flow diagrams or tables
delineating sampling program operations, and a description of containers,
procedures, reagents, etc., used for sample collection, preservation, trans-
port and storage. Also included are special conditions for the preparation of
sampling equipment and containers, sample preservation methods and holding
50
£^ai^lsa*&^ .
-------
times, time consideration for shipping samples, sample custody or chain-of-
custody procedures, and forms, notebooks and procedures to be used to record
the sampling history, sampling conditions, the analysis to be performed.
Sample custody information is required, and when used for legal purposes.
"chain-of-custody" procedures must be described. At a minimum, detailed
documentation of procedures for field sampling operations and laboratory
operations are required.
Calibration procedures and frequency informatijn is needed for both the
sampling and analysis efforts. Incorporated in the QAPP for each major
measurement parameter, including all pollutant measurement systems, is
information on the frequency plan for recalibration, as well as calibration
standards and their sources.
For each major measurement parameter, including all pollutant measurement
systems, standard operating analytical procedures need to be citetf or written
descriptions given. ' Hany specific analytes have yet to be valitisted, and
hence, QC data on analysis of surrogetes, duplicates and spiked samples serve
as indicators of the performance of the sample preparation and analytical
methods.
Explicit information is required in the QAPP regarding data reduction.
validation and reporting procedures. For each measurement parameter,
including all pollutant measurement systems, information is required regarding
51
32siteM!^^
-------
the planned data reduction scheme to be used to calculate the concentration or
value of the measured parameter and reporting units. The principal criteria
that will be used to validate the data integrity should be reported as well as
tBethods used to Identify and treat outlying data. Data flow or reporting
sche
-------
The following types of preventive maintenance items should be considered
and addressed 1n the QAPP:
o A schedule of Important preventive maintenance tasks that must be
carried out to minimize downtime of both the sampling and measurement
systems, and
e A list of any critical spars parts that should be on hand tn minimize
downtime.
A series of specific routine procedures must be developed and documented
to assess data precision, accuracy, and. completeness. Mean values and
estimate of precision are provided by normal statistical means using the
relative standard deviation as the precision measurement. The accuracy is
assessed by mean recovery of surrogate compound and/or, in the case of stable
labeled compound (e.g., Method 1624/1625), by use of the stable labeled
standard addition analyts. -When it is determined that the causes of variance
need to be assessed, it is accomplished vypically using the sampling and
analysis procedure shown in Figure 3. The analysis of a minimum of seven
samples prepared as shown in Figure 3 penults estimation of the causes of
variance from cither sampling, preparation and measurement (Ref. 12), e.g..
s2 '. s2 + s2 -i- s2
Total = Sampling Preparation Measurement
S3
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Preparation Analysis
Figure 3. Diagram of a sampling and analysis procedure which uses
replicate sair.ples to provide information on sources of variance
Corrective action procedures must be described for each project, which
Includes the following elements:
o Predetermined limits for data acceptability beyond which corrective
action 1s required,
• Procedures for corrective action-, and
a Identification of the responsible individual for initiating the
corrective action and the individual responsible for approving the
corrective action, 1f necessary.
54
sai
^IiH^'>...;> irt-^J^jl&MJ^^^^^
-------
Corrective actions may also be initiated as a result of other QA activities,
Including performance audits, systems audits, laboratory/interfield comparison
studies, and QA program audHs conducted by the EPA Quality Assurance
Management Staff.
Quality assurance reports are initiated during regular meetings among the
Quality Assurance Officer, the Project Manager, and key staff responsible for
sampling, analysis, QC, and data management to review the QC data summaries,
documentation ar.J other aspects of the project quality assurance performance.
The Quality Assurance Officer's assessment of the adequacy of project quality
control/quality assurance performance 1s then summarized in a memorandum
distributed to upper corporate/institutional management, as well as to the
Project Manager and the cognirant line management.
55
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REFERENCES
1. 'Test Methods for Evaluating Solid Waste - Physical/Chemical Methods."
SW-84&, Sacond Edition, U.S. Environmental Protection Agency, Washington,
D.C., 1982.
2. Harris, 3.C., D.L. Larsen, C.E. Rechsteiner, and K.E. Thrum, 'Combustion
of Hazardous Wastes - Sampling and Analysis Methods," Hayes Publications,
Park Ridge. NJ, 1965.
3. Proposed Sapling and Analytical Methodologies for Addition to Test
Retnods for Evaluating Solid Haste - Physical/Chemical Methods. 5&-S46,
Setond Edition, U.S. L'nvironmsntal Protection Agency, Washington, Q.C.,
1984.
4. 40 CFR 261. Appendices III, VII, VIII, X, July 15. 1985.
5. W.E. TelHard, ITD/RCEA Compound Analyses, Privete Communication, 21
October 1985.
5. 40 CFR 60. Appendix A (1980).
7. Handbook for Sampling and Sample Preservation of Water and Wastevater,
U.S. EPA Environmental Monitoring and Support Laboratory, Cincinnati, OH.
56
t>.,-.. ^•,-x,r.".^,.^""--/;5r- " '•-".. ""••-. - ~ ~~~~~'" - - "
-------
8. US EPA Contract Laboratory Program. Exhibit 0. Analytical Methods for
Organic Analysis; Hultlmadia/f-iultlconcentration. 1385.
9. Rethod 1624, Volatile Organic Corepounds by Isotope Dilution GC/MS. and
Method 1625, Semi-Volatile Organic Comoounos by Ir.otope Dilution GC/HS,
49 Federal Register 43234, October 16, 1984.
10. 40 CFR 261, Appendix X, Juiy 15, 1985.
11, Interim Guidelines and Specifications for Preparing Quality Assurance
Project Plans, CAMS 005/00, Office of Monitoring Systems and Quality
Assurance, Decentber 29, 1980.
12. B-H. Colby and a.£. Picker, "EstaolisMng Destruction Efficiency for
Hazardous Waste Incinerators,0 Submitted to ASTO Journal February 27,
1984.
57
£^^^ -.
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APPENDIX
This apoe.-dix is a comprehensive compilation of specific coraoounds that
have been 1dent1,M««i as hazardous in EPA regulations, or in proposed additions
to regulations thav nay exist in. waste materials (Ref. 5). This list includes
all cofispounds 1n the RCRA Appendix VIII list, the proposed addition to that
list (N1'-hio»ft Petition), the CERClA Hazardous Substance List, the Priority
Pollutant U*«t. -Appendix C Pollutants, and High Priority Paragraph 4(c)
Pollutants, together with confounds not specifically identified in the llscS
'ited above but are covered by compound class citations in the Appendix YIU
11st The empirical formula and CAS registry number are presented for eacn
coispW-d. together with-an indication of known analysis methods or probable
applicable aethods. the promulgated EPA nssthod, and applicable RCRA method.
vhen known.
Analysis and other information is coded 1n the table as shown below:
CVAA *>' Cold vapor atomic absorption spectroscopy
DiOXIM « Analysis for dibenzo-p- 6as chroiEatography with electron capture detector
SCHS ° Sas chromatography/mass ipectrotnetry
S(;-^?0 = Gas chronatography with nitrogen-phosphorous detector
KPLC » H1qh performance liquid chromatography
HPLC-UV = HPLC with ultra-violet detector
JCP . inductively coupled argon plasma soectrometry
MAS - Determined using Master Analytical Scheme
K5-PK08 • Probably determined using mass spectrometry
KO SCJ^ - Cannot be determined using SCMS
TEH - Transmission electron microscopic analysis
y£T " Classical wet method
SRC - Denotes this analyte will be identified by computer search of
an analyte-specific library in 6CMS data
H - Artalyte hydrolyzes in water
58
aa^aJ^iSk^^^^
I : •
-------
w^r.w - •
•i \
1
f" J
H'-L
^ "• ' '
$$
1? '
&'•
!V .
IV'
* * '
b" • i
[Jr
,''"'..'
;"r
I .', /
"i' r"
I?'''.
1'
i: •
1:
^.
v
A
*
i':
Namtt in Regulation
Acenophlhenu
Acenaphthene, 5-nitro
Acoriaphthy lene
Acetnraide N- (4-5-ni tro-22-f ury ))-
Uiiazolyl)
Acetic acid, (4- [bis(2-chloroethy 1)
ami no] plicmy 1 ) -clio 1 estory 1 estor
Acetoni Lr i lo
3- (a Ipha- Ace tony 1 benzyl ) -4-
hydroxycoumar in and salts
AcelophoMOite
AcoLyl chloride
1-Acel.y 1 -2- tli ir. urea
2-A.cety lami nof luorono
Acroleiri
Aery 1 amido
Aery loni tr i lo
Table A.I ITO/RCRA f.OMPOUIJD DATA
Emfiricol Arta lysis RCRA
forp.ulo CAS Number Typo Molhc/d GeUiod Other
C12!!io 83-32-9 GCMS 1626 0270
C12HgH°2 602-67-9 MS-PROO SRCH
C1?H8 208-SG-9 CCMS 1625 8270
C0II7N302S 631-02-8 HPLC
C30!I59CI2H02 35-16-10-9 ItTLC
C2!I3N 75-07-8 CCUS SRCH
C13!lJ604'Na 129-06-6
C0i!00 08-85--2 MS-PHOO SRCH
C2II3CIO 95-36-5 -- — II
C3H6N2OS 591-08-2 H5-PROQ SRCH
clb"j3NO '1V364-30-6 MS-PROD SRCH
C3H40 107-02-8 GCMS 1624 82-10
C3H3N 79-06-1 MAS SRCH
C3M3N 107-13-1 GCHS 1624 8240
Ed
-------
ToMo A.I ITD/RCRA COUPGUHD DATA (Continued)
Nome in Regulation
Actinonycin 0
Af Is toxins
Aldrin '
Ally) alcohol
Aluminum phosphide
(hydroxym othy 1 ) -8a-raethoxy-5-methy 1 -
carbamata az irino[2* ,3* :3,4]pyrrolo
[1 ,2a] indole-4,7~dione, (ester)
3-Amino-9-ethyl carbazolo
4-Aminobipheny 1
5- (ami nomothy 1 )-3- isoxazolol
Amitrole
Ammonium salt (of saccharin)
Ammonium, (4-(p-(dimethy lamino)-alpho-
Empiricol
Formula
C62H86W12°16
C17nl2-l°6-7
C12H8CI6
c3»6o
AIP
Cl5»10f«4°5
Cj2H,4N
C12llnN
C4H6N20
C2H4N4
C7H5N03S»H3N
C23II2,N2.CI
CAS Wunber
50-76-0
1402-62-2
309-00-2
107-18-6
203S9-73-8
60-07-7
132-32-1
92-37-1
2763-96-4
61-82-G
6301-61-9
569-64-2
Anglyaio RCRA
Type £iothod MothotJ Otlior
HPLC
Nf;-GO(S —
CCEC 608 0080
MAS SRCH
ICP — 1610
HPLC-UV —
MS-PROB SP.CH
MS-PROB SRCH
HPLC
__
H
—
phenyl benzylidine)-2,6- cyIcohoxadion-
1-yIidene)-dimethyl-, chloride
Aniline ^G"?^
62-63-3
CCMS
SRCH
60
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Teble A.I ITO/RCRA COMPOUfO DATA (Continued)
Name in Regulation .-.
Aniline, 2,4,5-trimethyl-
Aniline, 4,4'-mothy lenebis (2-methy 1}-
Aniline, 4 ,4 '-methy lenebis (N,N-
di methy 1)-
Aniline, 4,4'-thiodi-
Aniline, p-(pheny lazo)-
o-Anisidino
o-Anisidine hydroch 1 or i do
o-Anisidine, 5-mcthyl
o-Anisidine, 5-nitro
Anthracene
Anthraquinone, l-amino-2-roethy 1
Anthraquinone, 2-amino
Anthraquinone, 2-methy l-l-ni tro
Antimony
Antimony (I I I) chloride
Empirical
Formula
C9H13N
Cl5H18N2
C17M14M2
C12H12N2S
C6llnN2
CgllgNO
C9II10NCIO
C10HHNO
C10H0N203
C14fi10
C15"lO
C14II9N02
C15H9N04
Sb
SbCI,
Analysla RCRA
CAS Number Type Method Method Other
1377-17-7 MS-PROD
838-00-0 MS-PROD
101-61-1 MS-PROD
139-65-1 IIPLC
60-09-3 HPLC
90-04-0 NS-PROD
134-29-2
120-71-8
99-59-2 MS-PHOB
120-12-7 GCMS
120-12-7 GCMS
117-79-3 MS-PROD
129-15-7
7440-36-0 FURN-AA
10025-91-9 FURN-AA
SRCH
SRCII
SRCH
--
--
SRCH
H
II
SRCH
1625 8?70
1625 8270
SRCII
--
7041
7041
61
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Tnbla A.I ITD/RCRA COMPOUND DATA (Continued)
Namo in Regulation
Antimony (V) chloride
Araroi bo
Arsenic
Arsenic acid
Arsenic pentoxide
Arsenic trioxido
Asbestos
Auramine
Azsser ine
Barbituric acid, 5-othy l-5-pheny 1
Barium
Barium cyanide
Benz(c)acr idine
Benzanthrone
Benzenamine hydrochlor ide
Benzeno
Empirical
Formula
SbCI5
C15H23CI04S
As
H3As04
As205
As203
—
C17H21N3
C5H-/N304
C12H12N203
Da
C2BaN2
C17HUN
C16H10°
C6Hflf!CI
Cfi|(R
CAS Nutaber
7647-18-9
140-57-8
7440-38-2
7778-39-4
1303-28-2
1327-63-3
13322-21-4
2465-27-2
115-02-6
50-06-6
7440-39-3
543-62-1
255-51-4
82-05-3
142-04-1
71-43-2
Analysis RCRA
Type Method Method Other
ICP ~ 6010
MS-PROB SRCH
FURN-AA . — 7060
FURM-AA — 7080
FURN-AA — 7060
rURN-AA — 7060
FBI
CCMS SRCH
HPLC — -
MS-PROB SRCH
ICP — 6010
WET
MS-PROB SRCH
CCMS SRCH
II
GCMS 1624 8240
62
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Table A.I ITD/RCRA COMPOUND DATA (Continued)
Name in Regulation
Benzene, 1 ,2-(methy lenedioxy) -4-(2-
(octy loul f iny l)propy 1)-
Benzene, dichloromethy 1-
Denzenearsonic acid
Beozenethiol
Benzidine suifate
2-Beru imidazolccarbamic acid,
1- (buty 1 carbamoy 1)-, methyl ester
Donzo (a) anthracene
Benzo(a)pyrene
Oenzo(b) f luorant'iene
Benzo(ghi)pery lene
Oenzo(j) f luoranthene
Benzo(k) f luoranthene
2,3-Benzof luorene
Benzoic a<_id
Benzoni tr i lo, 3,5-dibromo-4-hydroxy-
Empir icol
Formula
C18.,28o3s
C7II6CI2
A6ll;As03
c6"6s
C,2tl]2N2»H204S
C14!I18N2°3
Clf!M12
C20H12
C20H,2
C24"l4
C20H12
C20M12
Cl/"l4
C7H602
C7!l3N»r20
CAS Number
120-62-7
98-87-3
998-05-6
92-87-5
531-886-2
17804-35-2
56-B5-3
60-32-8
205-99-2
191-24-2
205-82-3
207-08-0
243-17-4
65-85-0
1689-84-E
Typ«
-..
MS-PROB
HPLC
CCMS
._
HPLC-UV
GCMS
(iCMS
GCMS
GCMS
GCMS
CCMS
CCMS
CCW
GCMS
sis RCRA
Method &lathod Other
H
SRCH
— ' .
1625 8270
—
—
1625 8270
1625 8270
1625 8270
1625 8270
SRCH
1625 8270
SRCH
SRCH
SRCH
63
-------
Tabla A.I ITD/RCRA COMPOUND DATA (Continued)
Empirical
Nemo in Regulation Formula
(l)-Beniopyrano(3(4-b)furo(2,3-h)(l) C23H22°6
berizopyran-6(6aH)-one, 1,2,12,128-
tetr ahydro-2-a 1 pha- i sopropeny 1-6,9-
dimethoxy
p-Benzoquinone CgH/j02
Benzotri chloride CjHgClg
Benzyl alcohol CyllgQ
Benzyl chloride C-jHyCI
Bery 1 1 i urn Be ,
gamma -BIIC CgHgClg .
alpha-BHC C6H6Clp
beta-BHC ^gllgClg
delta-BIIC C6''6CI6
Biplienyl ^12*'lO
Oiphenyl, 4-nitro ^12"9^2
4,4'-Bipyridinium, 1,1 '-dimethy I-, C12"l4N2CI2
di chloride
4-Bromo-l ,2-dichlorohenzene C()lf3Cl2flr
CAS Muaber
83-79-4
106-51-4
08-07-7
100-51-6
100-44-7
7440-41-7
7440-41-7
319-84-6
319-05-7
319-86-8
32-57-4
92-93-3
1910-42-5
18282-E9-2
Anolyoio RCRA
Typo Method Hathod Other
HPLC-UV
P-POLL
MS-PROO
SRCH
MS-PROB
ICP
GCEC
GCEC
CCEC
GCEC
tiCMS
MS-PROB
—
MS-PR03
--
SRCH
SRCH H
—
SRCH II
6010
608 8080
608 8080
608 _ 6080
608 6080
1625 8270
SRCH
--
SRCH
-------
Tab to A.I ITO/RCRA COMPOUND DATA (Continued)
Empirical
Natno in Regulation Forrculo
l-Bromo-2-chlorobenzene CgH^CIBr
l-Broroo-3- chlorobenzeno Cgll^CIBr
4-Cromo-3-chlorophenol CgH^CIBrO
2-Bromo-4-chIoropbenol C6H4CIBrO
2 -Br omo- 4 -tert- butyl phenol CjoUjgOrO
Bromoacetone CoiLBrQ
Oromodicli loromo tdane CMCI2Br
Bromome thane CH^Br
4-Bromopheny 1 phenyl ether Cj2HgBrO
Brucine ^23"26^2^4
1,3-Butadiene, 2-chloro C4"5CI
1-Butanol, 4-(buty Initroroamino)- '•B"l8^2f'2
2-Butanone ^4"o0
2-Butanono peroxide ^B"l6^4
Butyl benzyl phthalate <-]Q"20^4
2-sec-buty 1 -4 ,6-d i r. i tropbenol C in" 12^2^5
CAS Number
694-00-4
1008-37-2
13631-21-5
695-96-5
2198-66-5
690-31-2
75-27-4
74-83-9
10:-55-3
357-57-3
126-t.J-?
3tJ17-ll-6
73-63-1
1332-73-4
05-68-7
88-85-7
Ar.olyoU RCRA
Typo HothoJ Hetbod Other
CCMS
CCMS
MS-PR3B
MS-PROB
MS-PROB
MS-PROB
CCMS
CCMS
CCMS
HPLC
MS-PROB
._
CCMS
--
CCMS
CCEC
SRCH
SRCH
S^CH
SRCH
SRCH
SRCH
1624 8240
1624 8240
1625 0270
--
SRCH
—
1624 8240
II
1625 8270
615 G090
65
-------
Tab la A.I ITD/RCRA COMPOUND OATA (Continuad) .
Memo In Regulation
Cadmium
Calcium chroma te
Calcium cyanide
Calcium salt (of saccharin)
Carbamic acid, diethy Mi thio,
2-chlorual ly 1 ester
Carbamic acid, m-chloro,4-chloro-2-
butynyl ester
Carbamic acid, methyl-, 1-naphthyl
ester
Carbarr/ic acid, methyl-, 2,3-
(d i me thy 1 mo thy 1 ened i oxy) pliany 1 ester
Carbamic acid, methyl-, 2,2-dihydro-
2 ,2- dimethyl -7-benzof urany 1 ester
Carbamic acio', methyl-, 4-dimethyl-
amino-3,5~xy !y 1 ester
Carbazole
Carbon disulf ide
Carbon oxyfluoride
Eraplr icol
Formula CAS flmaber
Cd 7440-43-0
Ca«CrH204 13765-10-0
C2CaN9 EQ2-01-8
C7ll5N03S»l/2Co 6405-34-3
C8IIHCINS2 85-06-7
C11H9N02CI2 101-27-9
C12HnN02 63-25-2
formula 22781-23-3
C12H13rj°3 1563-66-2
1 ** 1 8 2 2 315-18-4
C12H9N 86-74-8
CS2 75-1B-0
CF20 3353-60-4
Anolyoio flCHA
Type Method Kathod Other
ICP — 6010
ICP — 6010 II
WET
II
CCHS SRCJ;
HPLC-UV 632
HPLC-UV 632
-_
HPLC-UV 632
IIPLC-UV 632
GCMS 1625 0270
CCUS SRCH
._
66
-------
Table A.I ITD/RCRA COMPOUND DATA (Continued)
Nam- in Regulotion
Chloral
Chlorambuci 1
Clilordane
Chlorinated benzenes, NOS
Chlorinated ethane, NOS
Chlorinated f luorocarbons, NOS
Chlorinated napthalene, NOS
Chlorinated phenol, NOS
Chlorine
l-Chloro-2,3-epoxy propane
4-Chloro-2-ni troani 1 ine
l-Chloro-3,5-dibromobenzeno
4-Chloro-3-methy Ipher.ol
l-Chloro-3-ni trobenzone
2 -Chloro-4-t-bufcy 1 phenol
6-Chloro-o-cresol
Empirical
Formulo
C2HCI30
C,4II19CI2N02
C10M6CI6
C6»6-«C'x
C2»6-xC'x
--
cio"o-xcls
c6"6-,
-------
Table A.I ITO/KCRA COMPOUND DATA (Continued)
Home in Regulation
Ch 1 oroaceta 1 dehyda
Chloroacotoni tri le
Chloroallcylethei-s, NOS
p-Chiuroani 1 ino
Chlorobenzene
Chlorobenzi late
Chloroe thane
bis(2-Chloroothoxy)mothane
bis(2-Chloroethyl) ether
N,N-Bis(2-chloroethyl)-2-naphthylaoine
2-Chloroethy 1 vinyl ether
Chloroform
Ch 1 ore < socyanotobenzene
bi s (2-Chloroi sopropy 1) ether
Chloromethano
Chloromethy 1 methyl ether
Empirical
Formula
C2II3CIO
C2II2NCI
--
C6H6HCI
W
C16Hi4CI2°3
C2H6CI
C6H10CIV02
C4HUC!20
C14H15CI2N
C4HVCIO
CHCI3
CVH4NCIO
C6H,2CI20
CII3CI
C2!I5CIO
CAS Nuabor
107-20-0
107-14-2
108-47-8
10Q-90-7
610-16-5
75-00-3
111-01-1
111-44-4
494-02-1
110-75-0
67-66-3
51124-03-3
108-60-1
74-87-3
107-30-2
Anolyoio
Typo Hothod
--
CCMS
GCMS
CCMS
GCMS
GCE.C
CCMS
ecus
GCMS
MS-PROB
CCMS
ccys
MS-PROO
GCMS
CCMS
--
—
SRCH
—
SRCH
1624
6081
1624
1625
1625
SRCH
1624
1624
SRCH
1625
1624
--
RCRA
ttSaihod Other
8240
8240
8270
8270
8240
8240
8270
8240
II
-------
Table A.I ITD/RCRA COMPOUND DATA (Continued)
Warns in Regulation
Bis(chloromethy 1) ether
1 - (Cli 1 orome thy 1 ) naphtha 1 one
2-Chloronaphtha*. ene
2-Clilorophenol
p-Chlorophenol
m-Chlorophcnol
1- (o-Chloropheny 1) thiouroa
4-Chlorophony Ipheny 1 ether
3-Chloropropene
?-Chloropropioni tr i le
Cholesterol
Chromium
Clirysone
Citrus red No. 2
Coal tars
Cobalt (II) chloride
Empirical
Formula
C2U4CI20
C,0l(gCI
C10M7CI
C6HbCIO
C6H5CIO
C6H6CIO
C7II,M2C'S
C,2li9CIO
C3»5CI
C3II4NCI
C27H460
Cr
CJ8"l2
C10H,6N203
--
CoCIo
CAS Numbor
6542-88-1
86-52-2
91-58-7
95-S/-8
106-48-9
108-43-0
."344-82-1
7005-72-3
107-05-1
542-76-7
57-88-5
7440-47-3
2168-01-9
6358-63-8
8007-45-2
7646-79-9
Analysis RCRA
Typo Method Method Othor
GCMS
GCMS
GCMS
GCMS
CCMS
fiCMS
GCMS
CCMS
MS-PROB
MS-PROB
GCMS
JCP
GCM5
IIPLC
CCMS
ICP
SRCH H
SRCH
1625 ' 8270
1625 8270
SRCH
SRCH
SRCH
1625 8270
SRCH
SRCH
SRCH
6010
J625 8270
--
—
6010
69
-------
Tcbla A.I ITD/RCRA COMPOUND DATA (Continued)
Name in Regulation
Cobalt, when in the form of par ides
100 microns or less
Coppar
Copper cyan i do
Copper cyan i da
Coumar i n, 3-ch 1 oro-7-hydroxy-4-«sethy 1 - ,
0-aster *ith c,o-diothyl
py rophosphoroth i oste
Creosote
o-Cresol
p-Cresol
ra-Cresol
Cresols
CroLona 1 dehyde
Crotonic acid, 2- (1 -methy (hopty l)-4, 6-
Eciplrical
Formula
Co
Cu
CNCu
C2N2C«
Cg|)602
—
C,H80
C7HB0
C7»lftO
C7H80
C4"6»
C,8H2,N206
CAS Nurior
7440-48-4
7440-68-8
644-92-3
147c»3-77-0
56-72-4
8021-39-4
05-48-7
10S-44-5
103-38-4
1319-77-3
4170-30-3
3U300-45-3
Anolyoio RCRA
Type Mathod Mathod OLhsr
ICP
ICP
ICP
ICP
GC-NPD
CCMS
OCMS
CCMS
ecus
CCMS
MS-PROB
CC-PROB
6010
6010
6010
6010
622 M
SRCH
SRCH
SRCfl
SRCH
SRCH
SRCH
SRCH
dinitrophenyI ester
Crotonic acid, 3-hydroxy, alpha-
methyl ben/y! eftter, dinethy I
phosphate (£)-
7700-17-6
CCMS
SRCH
70
-------
Teblo A.I I10/RCRA COMPOUND DATA (Continued)
Name in Regulation
Crotonic acid, 3-hydroxy, methyl ester,
dimethyl photphato (E)-
Cyanides (soluble salts and
complexes) NQS
Cyanogen
Cyanogen bromide
Cyanogen chloride
Cycasin
4-Cyclohoxcne-l,2-dicarboxii!)ida N-
((1 1,1,2, 2-tetrach loroethy 1) thio) -
4-Cyclohexone-l,2-dicarboxitnide N-
(tricJilorometnyl)lnio-
2~Cyc 1 ohexy 1 -4 , 6-di n i tropheno 1
Cy cl ophospham i da
p-Cymeno
Daunornycin
4,4'-DOO
4, 4 'DDE
£jnp i r i ci? 1
Forouia
C7HI306P
—
C2H2
CNDr
CNCI
C8((16W207
C,0M5N02CI4S
C9M4N02CI35
C12HHN206
C7H15N2CI2OP
ClOH14
C27H29MO,0
C14»IOCI4
Ci4MBCI4
CAS Number
7786-34-7
52-17-5
460-19-5
G03-68-3
606-77-4
14901-08-7
2425-08-1
133-06-2
1131-89-5
50-18-0
99-87-5
20020-81-3
'2-54-8
722-56-9
Anolynii?
Type Kothod
GC-NPO
WET
—
--
—
HPLC
CC-PROB
CCEC
GC-PR08
HS-PR03
CCMS
HPLC
GCEC
CCEC
SRCH
—
--
—
--
—
SRCH
617
SRCH
SRCH
1625
--
500
608
RCRA
Mothod Other
H
II
H
8270
8080
8CQO
71
-------
Tebla A.I ITD/RCRA COMPOUND DATA (Continued)
Nacio In Regulation
4, A 'DDT
Docach 1 orob i pheny 1
n-Decane
Oi-n-butyl ph thai ate
Oi -n-propylni trosamine
2,6-di-tert-Buty l-p-benzoquinono
Dial late
2 , 6-D i aro i no to 1 uene
0 i benx (a , It) acr i d 1 ne
Dibenz(a, j)acr idina
Oiben/o(a,e)pyrena
Dibonro (a, h) anthracene
Dibinzo(a,h)pyrone
7*i -Diboruo (c , g)carba/olo
Dib«iuo( uran
Dibon/oth iophone
Esip J r i c o 1
Formula
CMllgC!5
C12CI10
C10M22
CI6"22°4
C6HHN20
CHH130
C10II|7CIKOS
C4II10N2
C21H13N
C2,H13N
C24M12
C22H,4
C24"l4
C20"!3N
C,2II80
c,2;ifls
CAS Murobor
60-29-3
2051-24-3
124-18-5
117-84-0
621-64-7
719-22-2
2303-16-4
823-40-5
226-36-8
224-42-0
182-85-4
53-70-3
.189-64-0
194-60-2
132-64-9
132-65-0
Analysis
Typo Method
GCEC
MS-PROB
ecus
CCMS
GCMS
ecus
--
GCMS
MS-PROB
MS-PROO
GCMS
CCMS
GCMS
MAS
CCMS
CCMS
COS
SRCH
1625
1626
1625
SRCH
--
SRCH
SRCIi
SRCH
SRCH
1625
SRCH
-_
1626
1625
RCRA
Method Other
8080
8270
8270
8270
8270
8270
0270
72
-------
Table A.I ITO/RCRA COMPOUND DATA (Continued)
Nsmo in Regulation
1 ,2-DiOromo-3-cMoropropano
1 ,3-Dibrorcobenjena
Dibromochlorcmothano
1 ,2-DtbromooUiano
DibroraorocUiane
trans- 1 ,2-DicMoroelhcne
2,3-DicMoro-l-propanoI
trans 1 ,4-D»chl
-------
Tabla A.I ITD/RCRA COMPOUND DATA (Cc.vtinued)
Natno in Regulation
1,4-Dichloro^enzene
1,3-Dichlorobenzeno
Dictiloroben/one, NOS
3, 3 ' -D i cli 1 oroben* i d i ne
Dicblcrodif luororoe thane
1 , 1 -D i ch 1 oroottoane
1 ,2-Dichloroethane
1, 1-Dichloroethene
cis-1 ,2-Dirhloroethylene
Dichloroothylene, NOS
2, 3-Oichloronophtha lone
2,3-Dichloroni t-robenzeiie
2,6-Oichloroplionol
2,4-Oichloroplienol
2,5-Oichlorophenol
Empirical
Forsiulo CAS Ku^bor
C6H4CI2 106-46-7
C6H,jCI2 541-73-1
C6II4CI2 25321-22-6
C12II10N2CI2 91-94-1
CCI2F2 75-71-8
C2M2CI2 75-34-3
C2H4CI2 107-06-2
C2H2CI2 7S-3S-4
C2H2CI2 156-59-2
C2H2CI2 25323-30-2
C10i:6CI2 2050-75-1
C6H3NCI202 3209-22-1
Cgl^CI^' 67-65-0
CCII4CI20 120-83-2
C6II4CI-.0 583-78-8
Anolysia
Type Method
GCMS
GCMS
GCMS
ecus
CCMS
CCMS
GCMS
CCMS
CCMS
CCMS
CCMS
GCMS
CCMS
CCMS
MS-PROB
1626
1625
—
J625
SRCH
1624
1624
1624
SRCH
—
SRCH
SRCH .
SRCH
1625
SRCH
RCHA
Method Other
8270
0270
8270
8240
8240
8240
8270
-------
Tablo A.I ITO/RCRA COMPOUND DATA (Contlnuad)
Nemo 'n Hogulotion
2,4-Dichloroplienoxyacetic acid, salts
and esters
Dichloropheiy larsino
1,2-Dichloropropane
1,3-Dichloropropane
Dichloropropane, NOS
Dichloropropanol , NOS
1,3-Oichloropropone
cis-1 ,3-Oictiloropropone
trans-1 ,3-Oichloropropene
Dichloropropene, NOS
Dioldr i n
1 , 2:3,4- Dicpoxy butane
Di ethyl other
Dicttiyl ph thai ate
0,0-Di ethyl S-methyl ester of
Empirical
Formula
cait6ci2o3
C6!l5AsCI2
C3II6CI2
C3H6CI2
C3H6CI2
C3n6ci2o
C3H4CI2
C3n4lci2
C3I(4CI2
C3M4CI2
C12H8CIS0
C4!I602
c2H6n
Cl2"H°'l
Cbll,302PS2
CAS Humbor
94-76-7
G96-28-6
78-87-6
26638-19-7
--
--
542-75-6
10061-01 -F
10061-02-6
26952-23-8
60-57-1
1464-53-5
60-29-7
84-66-2
3288-50-2
Analyoia RCRA
Type Method Method Other
GCEC
-- '
GCMS
GCMS
GCMS
GCMS
GCMS
GCMS
GCMS
GCMS
CCEC
GCMS
GCMS
CCMS
MS-PROB
615 B150 M
H
1624 8240
SRCH
. __
• •
SRCM
SRCH
SRCU
SRCH
508 8080
SRCH
1624 8240
1625 0270
SRCH
phosphorodithioic acid
75
-------
Tab Io A.I ITO/RCRA COMPOUND DATA (Continued)
Nemo in Regulation
0-0-Diethyl-0-(2-pyrazinyl)
phosphoro th i oate
Diethy tarsine
N.N ' -0 i ethy 1 hydraz i no
0,0-Diethy Iphosphoric acid, 0-p-nitro-
phenyl ester
DieUiylsti tbesterol
1 ,3-Dt f luornbenzene
Dihydro;af role
3 , 4-D i hydroxy-a 1 pha- (methy 1 awi ;
-------
Table A.I ITD/RCRA COMPOUND DATA (Continued)
Mama in Regulation
Dimethyl plithalato
Di methyl sulfate
Dimethyl sulfono
Dimethyl sulfoxide
3, 3-D i mo thy 1 - 1 - (ma thy 1 th io) -2-butanono-
0-[ (methyl ami no) carbonyl] oxlse
p-DimeUiy lami noazobenzono
7,12-Dimethylbenz(a)anthracene
3 , 3 ' -D i me thy 1 ben i \ J i ««
Dimcthy Icarbamoy ! chloride
N,N-Di methyl formamido
1, 1-D into thy Ihydrazine
1 , 2-D i methy 1 hy dr a z i ne
3, 6-D i methy 1 plicnan thread
2, 7-Dimethy Iphcnanthrene
a Ipha, alpha -Dime thy Iphnnsthy Icmine
Err.piricel
Formula
C10H10n4
C2II604S
C2II6502
C2M6SO
C0II20N202S
^14"i5N3
C20il16
CHH16N2
r3nr>Ncio
C3H7NO
C2ll(jN2
C2llflN2
r3G"l4
C10"14
C10''I5N
CAS Number
131-11-3
77-78-1
67-71-0
67-68-5
31916-18-4
60-11-7
57-97-6
119-93-7
79-44-7
68-12-2
57-14-7
540-73-8
1576-67-6
1576-59-8
122-09-8
Analysis RCRA
Type Method Hotltod Other
GCMS
--
GCMS
GCMS
--
GCMS
ecus
MS-PROB
—
CCMS
GCMS
CCMS
GCMS
CCMS
MS-PROB
162S 8270
II
SRCH
SRCH
—
SRCH
SRCH
SHCII
H
SRCH
SRCH
SRCH
SRCH
SRCH
SRCH
77
-------
Table A.I ITD/RCRA COMPOUND DATA (Continued)
Name in Regulation
2 , *-D i TOO liiy ! p!i£f:u I
4,6-Dini tro-o-crasoi
1 , 3-D i n i Lrobenzene
f)ini trobenicr.z, KUS
2,4-Dini tropiiuiiu!
2 ,4-Dini trotoluente
2,6-Dini trotoluuno
1,4-Dioxan.e
Diphenyl •stlier
Dipheny iodine
Dip'icr.yls.Tiins, 4-nifcroso-
Oipheny Misulf ido
1 ,2-Dipheny Ihydi azino
DJSIJ! foton
2,4-Oi Lliiobi uret
n-Oocosane
Erapiricol
Formula CAS rJ'xnbor
C8H100 105-67-9
C7!I6M205 R34-B2-1
CCI!4N?°4 100-25-4
C^I^NoO^ 1-16-4
C6I!4N205 51-28-5
C7H6w204 121-14-2
C7H6N204 606-20-2
C4H802 123-01-1
C12fl100 101-84-8
Ci'/»!jN 122-39-4
C12(I10N2° 156-10-5
1. 1 o> • j ** j"7 co2""33~ /
C1?H,?N7 122-66-7
Ca!!,g02PS3 298-04-4
C2HSN3S2 541-53-7
C9otl4fi 629-97-0
Analysis
Type Hothod
CCMS
CCMS
CCMS
CCMS
CCMS
ecus
ecus
GCMS
GCMS
CCMS
GCMS
CCMS
CCMS
CCN-PO
HPLC
CCMS
1625
1525
SRCH
—
1625
1625
1625
1624
1625
1625
SRCH
SRCH
1625
622
—
1625
RCRA
Method Other
8270
8270
8270
8270
8270
8240
8270
8270
8270
8140
8270
78
-------
Tobla A.I ITD/RCRA COMPOUND DATA (Continued)
. Empirical
Ncma in RoQiiletion Formula
n-Dodecane • ^-12"2£
n-Eicosane . *-"o"42
Endosul fan CgllgClgO^S
Endosul fan sulfato CgM6CI604S
Endosul fan-I C^CI^CjC
Endosulfan-II C6llgCI603S
Endrin Cj2i!8ClgO
Endrin alcohol C12l!flClgO
Endrin aldehydo -l^'a^'o-
Endrin and metabolites
Endrin ketone ^12"s-'6^
Etlianol. 2-chloro- C2I!5CIO
Ether, 2,4-dichloropheny 1 p-ni tropheny 1 - Cj'jII/NC^Oj
Ethyl carbamate CgllyNf^
Ethyl cyanide . CjllcN
Ethyl tncthacry lato ^-G"lo"2
CAS Number
1.'.2 10-3
112-S5-8
115-29-7
1031-07-8
»»y-98-8
33213-S5-9
72-20-fl
33058-12-7
7421-93-4
.
63494-70-5
107-07-3
1836-76-5
51-79-6
107-12-0
07-63-2
Anolyolo
Type Method
CCM5
GCMS
GCEC
CCEC
GCEC
GCEC
GCEC
--
GCEC
GCEC
—
MS-PROB
--
MS-PROB
MS-PROD
CCMS
1626
1625
608
608
608
608
608
--
608
608
—
SRCH
—
SRCU
SRCU
SRCU
RCRA
Uathod Other
8270
8270
8080
8080
8080
8080
8080
8080
79
-------
f«b!s A.I ITD/RCRA COMPOUND DATA (Continued)
Name in Rogulotion
Ft-.hyl raethanesulfonate
<•' >yl benzene
Ethyl ene oxido (oxirane)
Ethy lenobisdi thiocarbamic acid,
salts and esters
Ethy lonebisdi thi oca rbaraic acid,
-manganese salt
Ethy lenebi.jdi thi carbamic acid,
-sodium salt
Ethy lenebi sdi thi ocarbaroic acid,
-zinc sait
Ethy icneimino
Ethy ! enoth i ourea
bis(2-Ethylhexyl) phthalete
Fluoranthene
Fluorono
Fluorine
2-Fluoroacctarr>ide
Empirical
formula CAS Number
C3Ha03S 62-50-0
CeHJO 100-41-4
C2M40 76-21-8
C4!iaN2S4 111-64-6
C4H6N2S4Mn 12427-38-2
C4H6N2S(|Na2 142-59-6
C4H5N2S4Zn 12122-67-7
C2H5N 151-56-4
C3II6N2S 96-45-7
C24H3B°4 117-81-7
C!£HIO 206-44-0
C13MU) B6-73-7
F2 7782-41-4
C9!idNFO 640-19-7
Aiialyolo RCRA
Typa Method Method Other
—
GCMS
CCMS
HPLC
CC-PROB
CS2
CS2
MAS
HPLC
GCMS
GCMS
CCMS
--
MS-PROB
H
1624 8240
SRCH
__
SRCH
630
630
—
—
1626 8270
1625 8770
1625 8270
._
SRCH
80
-------
Table A.I ITD/RCRA COMPOUND DATA (Continued)
Empirical
Name in Regulation •'• formula
Fluoroacelic acid, sodium salt C'^^fQrflz
Formaldehyde CI^O
Formic acid CII202
Forsic acid, 2-(4-(5-ni tro-2-fury 1)- Cg(!6N404S
2-thiazolyl)hydrazido
(2,3,4-gt»)f'yrr°l izine-2,6(3H)dione, formula
(4,5,8,10,12,13,13a,13b-octahydro-
4 , 5-di shyoroxy-3,4,E-tr iroothy !••
2t.'-(l,6) dio-.acycloundoci'.o-
Glutarimtdo, 3-(2-(3,5-diiaethy 1-2- C15i!?3"94
oxocyc 1 ohexy 1 ) -2-hydroxyethy 1
G.'yc idyl aldehyde C3M402
Holomethars, NOS r.H3X
iioptachlor ^lo"s^'7
Ijpi/achlor epoxide ^lo"5^'7^
lleptachlor epoxide (alpha, beta, and
Anolyoio
CAS Number Typ« Method
62-7-1-8 line
50-00-0
64-18-6
3S70-76-0
3l«5-22-0
f>6-8t-9 IIPLC
765-3-S-4
1-19-3 CCMS
76-44-8 GCtC 608
1024-57-3 GCEC 603
1-19-5 GCEC 608
RCRA
. Mathod Other
II
H
8080
8080
8000
gamma isomors)
8,fla-liexahydro-l ,4:6,8-ondo, cndo-
dinietlianonaphthatene
C12H6CIG
-165-73-6
GCCC
608
3080
81
-------
Tab I« A.I ITD/RCRA COMPOUND DATA (Continued}
Name In Regulation
Moxachlorobeiuene
Hexachlorobutadiene
Hexechlorocyctohoxane (all isooors)
Hexach 1 orocyc 1 opontad i one
Hexach 1 or odibenzo-p-di ox ins
Hexach lorodibeiizof urans
llexacliloroet.hano
Hexach 1 otophone
Hoxachloropropene
n-Moxacosano
n-Hoxadecane
Hexaethy 1 tetraphosphate
2-Hexanone
Hydantoin, 5,5-diphonyl-
Hydantoin, 5,5-diphony l-monosodium salt
Hydrazino
Empirical
Formula
V«6
C4CI6
C6'%CI6
C5CI6
C12H2CI602
C12H2CI60
C2CI6
C13H6CI602
^'6
C2GH54
C16»(34
C12!I30°13P
CC»12°
f15H12N202
Clbl(12N2°2*N8
42
CAS Kuabor
116-74-1
07-68-3
608-73-1
77-47-4
1-20-0
70-30-4
67-72-1
70-30-4
1888-71-7
6EO-01-3
644-76-3
757-50-4
591-76-6
67-41-0
630-93-3
302-01-2
Analysis RCRA
Type L'othodl CJIetihod Other
CCMS
CCWS
GCEC
CCMS
CLP
CLP
CCMS
HPLC
MS-PROS
CCMS
CCMS
HPLC
ecus
GCMS
—
HPLC
1625 8270
1625 8270
608 8000
1625 6270
—
—
1625 B270
H
SRCH
1625 8270
1625 8270
—
SRCH
SRCH
—
..
-------
Tub)a A.i ITD/RCRA COMPOUND DATA (Continuod)
Norao >n Regulation
Hydrocyanic acid
Hydrofluoric acid
Hydrogen sulfide
Hydroquinona
Hydroxydimelhy Inrsine oxido
N- (2-hydroxy ethyl) ethyl enoimi no
Hydroxyalmine, N-ni troso-N-pheny I-,
ammonium salt
Hyf.ochlorous acid, calcium salt
Hypochlorous acid, sodium salt
2-lm\>ii\zo\ idinono, l-(5-ni tro-2-
thiazoly 1)-
Indeno(l ,2,3-cd)pyreno
lodomotliano
Iron-doxtran complex
Isobutyl alcohol
Isocyanic acid, methyl oster
Empirical
Formula
Cl IN
(IF
H2S
C6II602
C2ll7Ar,02
C4H9NO
C6H6M202«H3M
CI202Ca
ClOHa
C6M6M403S
C22H]2
CII3I
Unknown
C4H100
C2!I3NO
CAS Wurabor
74-90-8
7664-39-3
7763-06-4
123-31-9
75-60-6
1072-52-2
135-20-6
7770-54-3
7681-52-9
61-57-4
193-39-5
74-88-5
9004-66-4
78-03- J
624-83-9
Anolycio RCRA
Typo ilQthod tioifiod Other
• -- .
WET
WET
_.
HPLC
HPLC
(IFLC
1VET — II
H
HPLC
CCMS 1G25 8270
CCMS SRCH
ICP — 6010
CCMS , SRCH
II
83
-------
Toble A.I ITD/RCRA COMPOUND DATA (Continued)
Name In Regulation
Isonicotinic acid hydrazido
IsopSorone
2-Isopropy 1 naphtha 1 one
Isosafroii)
Kopono
Kclene
Lastocarpine
Lead
Load acetate
Lead phobpliate
Load subacetatu
L i Lh i uifl
Longi felons
Ma laic anhydride
Ualeic hydrazide
Malononi tr t le
Empirical
Forraule
C6M,N30
C9H140
C13"l4
C10li10°2
C10!IJ00
C2fl20
C21»33°7
Pb
C4l!604Pb
04P2Pb
C4n,0n0pb3
Li
' C15'»24
C4»2°3
C4II4«202
GJUN9
CAS Nuaiber
64-85-3
78-59-1
2027-17-0
120-58-1
143-bO-O
463-R1-4
303-34-4
7439-02-1
301-04-2
7446-27-7
1335-32-6
7439-93-2
476-20-7
108-31-6
123-33-1
103-77-3
AnalyaU RCRA
Typo Method Usthorf Ochor
-.
-„
GCMS SRCH
ya-PROB SRCH
US-PRQB SRCH
--
HPLC
FURN-AA — 7421
FURN-AA -- 7421
FURW-AA — 74?1
FUf.iN-AA -- 7421
ICP — 6010
CCMS SRCH
II
IIPLC
MS-PROB SRCH
-------
Table A.I ITD/RCRA COMPOUND DATA (Continued)
Name in Regulation
kielphalan
Mercury '
Mercury fulminate
Uothacry looi tri le
Mothanethiol
Methapyr i lone
1,3,4-Motheno-lH-cyclobutafcd)
pentalene, i , Ja, 2,2,3 ,3a, 4,6,5, 5a,
5b,6,-dodecachlorooctahydro-
Motliomyl
Mothcxychlor
Methyl hydrazine
Methyl mothacry late
Methyl mothonesul fonate
Methyl pa rath ion
2-Mothy 1 -2- (me thy 1 thio)propion-
E/np i r i c o 1
Foraiulo
C13H!8N2CI2°2
Hg
C2N202Hg
C4H5N
CH4S
C14HigN3S
C10CI12
C5H10N202S
C16l!15Cl3°?
CII4H2
C6"e°2
C2I!6035
Cell10fW5PS '
C7HUN20?S
CAS Number
140-82-3
7430-97-6
628-GS-4
126-98-7
74-93-1
91-80-5
2385-65-5
16752-77-5
72-43-6
60-34-4
80-62-6
66-27-3
298-00-0
116-06-3
Analysis
Typo Method
HPLC
CV-AA
CV-AA
MAS
GCMS
GCMS
CCEC
HPLC-UY
CCEC
ItPLC
CCMS
MS-PROB
GC-NPO
CC-PROB
._
—
.__
SRCH
SRCH
SRCH
617
632
608
--
SRCH
SRCH
672
SRCH
RCRA
Method Other
7440
7440
8080
aldchyde-0-(raethyIcarbonyI) oxime
-------
Tablo K.I ITD/RCRA COMPOUND DATA (Contlnuod) .
tapir ica!
Nniao in Regulation Formula
4-Methy 1 -2-pentanone CgHj^O
M-Uethyl-N'-ni tro-N-Ni trosoguaoidino ^"s^S^S
2-Mothy \aiir idine £3"^
2-Metbylben/otliioa/olo Cgll/NS
WeUiy Ichlorocarbonate C2li;jCI02
3-Mothy Icholanthrene . ^2l"i6
Hethyleno chloride CH2CI2
4,5-Mothy lone pfienanthrene ^lb"lO
4,4'-yotliy lono-bis(2-chlorooni 1 ino) ^13")'>'-'2^2
4 Mot'iy 1 fluorene ^H*'l2
1-Methylf luorcne M4f'i2
2-Wott.yllactonitri le C^H/NO
2-Methy 1 n.iplitha lono ^il'(10
1-Uothy IpKunanthrene ^Ib"l2
9-MoUiy Iplionantlvi er.o ^!5")2
2-(iyiothylLhio)bonzoUiia2ole C^i/ffS.^
CAS f-Jtobor
108-10-1
70-25-7
76-65-8
120-76-2
79-22-1
66-J0-5
'76-09-2
203-64-5
101-14-4
155C-99-S
1730-37-6
/5-M-6
91-57-6
032-63-9
083-20-6
615-22-6
Anolyols RCPA
Typo Llotliod Mclhcdl Older
CCMS
W'LC
MAS
CCMS
—
CCMS
CCMS
CCMS
CCMS
CCMS
CCMS
...
ecus
ecus
CCMS
CCMS
SRCH
—
SSCH
SRCH
__
SRCH
1624 82-10
SRCH
SRCH
SRCH
SRCH
H
SRCH
SRCH
SRCH
SRCH
-------
TobloA.J ITD/RCRA COLSPOUXD DATA (Continuod)
fJoa!o in Regulation
Uolhy 1 tli i otirac i (o
Mustard gas
Naphthalene
1 .S-Njplilhslenediamine
1 , 4 -Napl.lliocjutDorio
1 , 4 -Wapiitlioqu i (tone, 2, 3-di ch 1 or o-
l-Naplitliyl-2-Uiiour«a
boto-N.iplit.liy 1 ami no
1-Haphtliy laaine
Nickel
Nickel carbemyl
Nickol cyanide
Kicotino and salts, NOS
Nicotine oxoiate
Nitric oxide
Nitrites
Erapiricol
Foraulo CAS Hirr&er
C6!I6N2OS 56-04-2
C4flaCI2S 605-60-2
CJ0lla 91-20-3
C10MIOM2 2243-C2-1
C101I602 130-16-4
Ca"4CI2°2 117-80-6
Cll"lON2S 86-eO-»
C10/igp; oi-59-e
C|(yi^< 134-32-7
Hi 7440-C2-0
C404Ni 13463-39-3
C?N2Ni 5S/-19-7
<",0II14H2 54-11-5
C,0il,4N2»KC2l)204 23r58-42-l
NO 10102-43-0
H797-G5-0
Anolyaia RCRA
Typo Method tlolhod Other
KPLC
M
CCMS 1625 0270
WS-PROB SRCH
us-pnoo sncn
CC-PROO SRCil
IIPLC
CCMS 1625 0270
CCUS SRCH
ICP -- 6010
ICP -- 6010
ICP — 6010
MS -PROD SRCIi
It
..
Rt?
-------
To&ta A.t ITO/RCflA CCWPKBSO BATA
Ec^irtcai
Mono In Regulation Foreulo
5-Nitro-o-toluidina *-7"e^2"2
2-Ni troani 1 ine ^&^6^2^2
3-Nitroani 1 ine CgHcN^Oo
p-Ni troani 1 ine Cgtlgf^f^
Nitrobenzene Cgligiii^
Nitrogen dioxide MQ2
Nitrogen mustard C^H^jC^N
Nitrogen mustard and hydrochlorida salt CgHj2f '3N
Nitrogen mustard N-oxide CgH||CI2NQ
Nitrogen mustard N-oxide, hydro- Cglli2CI3NO
chloride salt
Nitroglycerin C3HgM3Qg
2-Ni t roplieno 1 CgHgN03
4-Nitroptienol CgMgt^
4-Nitroquinol ihe-1-oxide ^Q^6^2^3
Ni trossmine, NOS
CAS Minsbor
09-55-3
flS-74-fl
80-09-2
100-01 -6
90-95-3
10102-4^-0
51-75-2
1-26-2
126-35-2
302-70-5
B5-63-0
88-7S-5
100-02-7
B8-67-5
35578-91-1
Analysis
Typo Method
GCMS
.CCMS
CCMS
ecus
ocys
—
—
—
MS-PROB
--
MAS
GCMS
ccys
CCMS
_.
SRCH
SRCH
SRCH
SRCH
1625
—
_.
—
SRCH
--
SRCH
162S
1625
SRCH
__
RCRA
Method Other
8270
II
II
H
H
8270
8270
88
-------
Tab I o A.I ITD/RCRA CDfiPCU?iD DATA (Continued)
Nama in Regulation
N-Ni troso-N-othy 1 urea
N-N i troso-N-methy I urea
N-Ni troso-N-methy 1 urethana
1 N-N i trosod i -n-bu ty 1 ami ne
N-Ni trosod i ethano 1 ami ne
N-N i trosod i ethy 1 ami ne
N-Ni trosod imethy famine
N-N i trosod i phe ty 1 an i ne
N-N i trosomethy 1 ethy 1 ami no
N-N i trosomethy 1 pheny 1 ami na
N-N i trosomethy 1 y i ny 1 ami ne
N-Nitrosomorphol ine
N-Ni trosonorni co tine
N-N i trosop i per i d i ne
N-Wi trososarcosino
Empirical
For c?,u 1 a
C3H7N302
C2HSN302
C4HBN203
C8H10N20
4 1(^2 3
C *Ht iy»2"
C2H6N20
C12H10N20
C3H8N20
C7H0N20
C3H6N20
C4H8N202
C9"llN30
C5II10N20
C3H6N203
CAS Nuabor
76S-73-9
684-93-5
615-53-2
024-IS-3
1HS-S4-7
S5-18-6
62-75-9
Bo-30-6
10595-95-6
£14-00-6
4S49-40-0
B9-8S-2
16533-55-8
100-76-4
132B6-22-9
Ann! pole RCRA
Typo Hothod Wothoc! Other
HPLC
JfLC
J1PLC
CCHS SRCH
HPLC
GCMS SRCH
GCMS 1325 8270
GCMS 1625 8270
GCMS SRCH
GCMS SRCH
HPLC
HPLC
ItPLC
MS-PROD SRCH
HPLC
-------
fab Ia * 1 ITD/RCRA COMPOUND DATA (Continued)
Nama in Regulation
17-alpha-19-Norpregnp-l,3,6(10)-
trien-20-yn-17-OI, 3-methoxy-
n-Octacosane
n-Octadecane
OctaraethylpyrpphosphoraEiide
Osmiura totroxide
7-Oxal)icyclo[2.2.1]heptane-2,3-
iiicarboxyl ic acid
2-Oxetanone
4,4'-Oxydiani 1 ine
Paraldehyde
Parathion
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
Ewpiricnl
Fornufo CAS fcalbor
C21fl26°2 72-33-3
C28H58 830-02-4
C18U38 593-45-3
C8H24N4°3P2 152-16-9
040s 20816-12-0
C8H1005 145-73-3
C3H402 57-57-8
c12n14M2o ioi-eo-4
C6Hi203 123-63-7
C10H14N05PS B6-38-2
. 12674-H-2
11104-28-2
11141-16-6
63460-21-9
12672-20-6
Analyst o
Typo Kothod
MS-PROB
COSS
CCMS
HPLC
KP
CC-PROB
MS-PROB
—
—
CCNPD
CCEC
CCEC,
CCEC
CCEC
CCEC
SRCfJ
162S
1625
—
—
SRCH
SRCH
—
--
614
60S
608
608
603
608
(2C3A
Method
8270
8270
6010
8140
8030
6080
8080
8080
8080
Other
II
. II
II
-------
Table A.I ITD/RCRA C063POUMD DATA (Continued)
Namo in Regulation
PCB-1254
PCD- 1260
Pentaclilorobenzene
Pen.tach 1 orod i benzo-p-d i ox i ns
Pentach 1 orod ibunzofurans
Pentach 1 oroe thane
Pentach 1 oron i trobenzeno
Pentoch 1 orophono 1
Pentaf luorobenzene
Pentaf luorobromobenzeno
PentatneUiy 1 benzene
Peroxyacetic acid
Pory lone
Phenacetin
Phenanthrene
Phono 1
Enpirkol
Forcuilo CAS fJualbor
11097-69-1
11006-82-5
C6!ICI5 603-03-5
C,2H302CI5 1-28-9
Cj2H3OCI5 1-29-0
C^fClg 76-01-7
C6N02CI5 82-68-8
C6HOCI5 87-8S-5
C6»!F5 363-72-4
C6BrF6 344-04-7
C||H16 700-12-9
C2H^03 79-21-0
2^ 12 1U8-55-0
Cj()H|3N02 62-44-2
^14^10 85-01-8
Cgi'jO 108-95-2
Ana lye ie RCRA
lypo MothoJ Mothod Other
GCEC
CCEC
MS-PROB
OIOXIN
DIOXIN
GCMS
CCEC
CCMS
MS-PROB
MS-PROB
CCMS
--
GCMS
MS-PROB
GCMS
cans
608 8000
608 8080
SRCH
CLP 8280
CLP 8280
SRCH
617
1625 8270
SRCH
SRCH
SRCH
H
SRCH
SRCH
1625 8270
1625 0270
01
43l^^
-------
T«blo A.I ITD/RCRA CG!3POUH® DATA (Continued)
t&».*i*'Mi:
Mama in Ragulotlcn
Phenqthiazine
Pheny 1 ened i am i ne
o-Pheny 1 ened i ami ne
P-Pheny 1 ened i am i ne
in-Phony 1 ened i am i ne
o-Pheny 1 ened i ami ne, 4-chloro-
ra-Pheny 1 ened i ami ne, 4-methoxy- , su 1 i ota
Pheny (mercury acetate
1 -Pheny Injphthalene
2-Pheny.l naphtha 1 eno
N-Pheny 1 th i ourea
Phosgene
Phosphine
Phosphoramidothioic acid, acetatnidoy 1 ,
Q,0-bis(p~chlorophenyl) ester
Phosphoric acid, (2,2,2-trichloro-l-
hydroxyelhyl)-, dimethyl ester
, ... ....
Empirical
Formula
CgH7NOS
C6H8N2
CGH8N2
C6H8N2
C6H8N2
C6H7N2CI
C7H12N205S
CflHaHg02
C16»12
C16H12
C7II8W2S
cc»2o
H3P
C14»13C«2N2°2PS
C4ii8o4ci3p
CAS Huabor
92-84-2
1-29-6
' 05-54-5
106-50-3
108-45-2
65-83-0
39156-41-7
62-38-4
605-02-7
812-94-2
1103-85-5
75-44-5
7B03-61-2
4104-14-7
52-68-6
92
Analysis
Type ttathod
GCMS
—
MS-PROb
GCMS
MS-PROB
GCMS
CV-AA
GCMS
GCMS
IIPLC
—
WET
MS-PROB
GC-PROB
SRCH
—
SRCH
SRCH
SRCH
SRCH
.«
SRCI;
SRCH
"
"
--
SRCH
SRCH
RCRA
Method Othor
j
-i
I
1
i
^
•j
i
H
7440
II
'
V
1
1
• i
.'1
.i!
•4
1
. ,1
<'•
^1
i
;|
. . . • J.
. % * • . 'x
-------
Table A.I ITD/RCRA COHPCUWD DATA (Continued)
Nemo in Regulation
Empirical Analysis RCRA
Formula CAS PJuabsr Typa Eflafr.hod Method
Phosphoric acid, l,2-dibromo-2,2-
dichloroethyl dimethyl ester
Phosphoric acid, 2,2-dichlorovinyI
dimethyl este-
Phosphoric acid, 2-chloro-l-(2,4,5-
trichlorophenyl)vinyI dimethyl ester
Phosphoric acid, 2-chloro-l-2(2,4-
dichlorophenyl)vinyl dimethyl ester
Phosphoric acid, dimethyl ester, estor
with (E)-3-hydroxy-N,N- dimethyl-
crotonamido
Phosphoric acid, dimethyl ester, ester
with (E)-3-hydro«y-N-
methylcrotonamide
Phosphoric acid, dimethyl ester, ester
with 2-chloro-N-N-diethyl- 3-
hydroxycrotonamido
Phosphoric acid, tri-o-tolyl ester
Phosphoric acid, trimethyl ester
Phosphoric, acid, hexamethyl-
C4H703CI2P
C10H903CI4P
C10H10°3C'3P
C7H14N05P
C10"i9N05C«P
C2lll^04P
300-76-5 GC-NPD 622
62-73-7 CC-NPO 62?
911-11-5 GC-HPD 622
470-90-6 GC-PROB SRCH
141-66-2 GC-PROB SRCS
6923-22-4 GC-PROB SRCH
1317J-21-6 CC-PROB SRCH
78-36-8 MS-PROQ SRCH
B12-b6-l MS-PROB SRCH
630-31-9 GCMS SRCH
03
Other
I *\J
I -I
i .-2:
il
;.
-------
Tobla A.I ITD/RCRA COBPCIJHO DATA (Continusd)
in Regulation
Foroulo
CAS
Analysis)
Typo Method
Phosphorodi thioic acid, 0,0-diethyl
ester, S-ester with 3-(morc£ipto-
iaothyl)-l,2,3-bocuotria2in-4(3H)-one
Phosphorodi thioic acid, Q-0-diethyf
0-(2-(ethylthiu)ethyi) astar misted
' with 0,0-diethyl S-(2-(ethylthio)
ethyl) ester (7:3)
Phosphorodi thioic acid, 0,0-diethyl
0- (2- i sopropy I -6-Biothy I -4-
pyriraidinyl) ester
Phosphorodi thioic acid, 0,0-diothyl
0-(3,5,6-trichloib-?-pryidyl) ester
Phosphorodi thioic acid, 0,0-diethyl
0-(p-(methycul f iny I) phony I ester
Phosphorodi thioic acid, 0,0-diethyl
S- [ (ethy I thio) methyl] ester (phorate)
Phosphorodi thioic acid, 0,0-diethyl-
S-[(l , i-dimethy (athyi)th(o] mo thy I
ester
Phosphorodi thioic acid, 0,0-dimethy I
ester, S-cster with 3-(mercaptomothy I)-
1 , 2, 3-benzotr i az i n-4 (3H) -one
2642-71-9 GC-PROB SRCH
8065-48-3 GC-NPO 622
333-41-5 CC-MPO 622
clo"uN03C3PS
2921-63-2
116-80-2
298-02-2
13071-79-8
GC-NPD
CC-NPO
GC-NPD
,,
622
622
622
»
86-50-0 GC-NPO 622
94
Othor
**«'i^^**'«'i^^^^Xaj^^
-------
1
i ^
t *
1 "
Tub la A.I ITD/RCRA COMPOUND DATA (Continued) :
i
Name in Regulation
Phosphorodi thioic acid, 0,0-disiothyl
ester, S-ester with N-(morcaptomothyf)
phthalimide
Phosphorodi thioic acid, 0.0-dimethyl-,
0-(4-meththio)-ro-toly 1) ester
Phosphorodi thioic acid,s(((p-chloro-
pheny 1 {-hi o) methyl) 0,0-diethyl estor
Phosphorodi thioic acid, S,S'-mothylen»
0,0,0',0'-tetraethyl esfcnr
Phosphorodi thioic acid, S.S'-p-dioxono-
2,3-dryl 0,0,0',0'-tetraethyl ester
Phosphorodi thioic acid, S-(2-(ethyl-
sulf inyl)ethyl) 0,0-dimethyl ester
Phosphorothioic acid, 0,0-diroethyl
0-[p-[(ddimethy lamino)sul fony 1)
phenyl] ester
Phosphorothioic acid, phenyl, 0-(4-
bromo-2,5-dichlorophenyl)
0-methyl ester
Phosphorothioic acid, phenyl-, 0-ethyl
0-(p-ni tropheny 1) estor
Phthalic acid esters, KOS
Eoplricel
Forrculo CAS Wuinbor
C11H12N04PS2 732-11-6
c10Jilso3PS2 Bs-an-9
C11H16°2PS3 766-19-6
C9H22°4P2S4 563-12-2
C12H26°6P2S4 78-34-2
C6M15°452P 301-12-2
C10H16N05PS2 52-85-7
C13"lO°2CI2BrpS 21609-90-5
CHHHN02PS 2104-64-5
1-30-3
95
•tnwrvmaauiclMMi&jMbUfliiiUa&.a^'i ''^^-'^
CC-NPD 614 8140 \ •
.]
CC-NPD 701
•/
CC«S SRCH j
CC-PROB SRCH ! 'j
!|
"" ""* $
•I
.* -* ! ';,
*.*•!
' 'i
GCMS « |
,c!
A
\
•'•• * •-•*,, <- iy,
" ' . ~: T -.'," • -t;
-------
n
Table A.I 1TO/RCRA COHfGUf® DATA (Continued)
Empirical
Name in Regulation Forctuhi
Phthalic anhydride Cgll^03
2-Picoline C8H?N
Polybroeiinated biphenyls, NOS
Polycdlorinated bi phony), NOS
Polychlorinated biphenyl, NOS
Potass Jura cyanide CNK
Potassium silver cyanide C2N2AgX
Pronaraide CjoHjjK!JOCi2 •
1,3-Propane sulfone C3Hg03S
2-Propanone C3MgO
Propionitri le, 2-hydroxy- C3llgNO
n-Propylamine ^3^9^
2-Propyn-l-ol C3H^O
Pyrene C16H10
Pyridine CgHgH
lBtttii>iBt^^»iffi»?ia»Saa2ii^<£ai»afa^»ie-a^^ i^.£l;;it -'luS"''"
CAS ^uGsfooir
85-44-9
109-OS-8
59533-65-1
1-30-0
133S-3S-3
151-50-8
503-61 -6
23050-58-5
1120-71-4
67-64-1
78-97-7
107-10-8
107-19-7
129-00-0
110-86-1
96
.„,..,,..._. •
Anolyola RCRA
Typo Mothod Hothod Other
« II
GCMS 1625 8270
CCMS SRCH
GCEC 608 8080
GCEC 608 8080
ffET
ICP — 6010
GCMS SRCH
II
GCMS If 24 8240
—
MAS SRCH
MAS SRCH
GCUS 1625 8270
MS-PR'JB SRCH
*""*" ' ""' ' -*>»'-'-A-'"-'»p«(
!
l
-------
Tab lo A.I ITD/RCftA COMPOUND DATA (Continued)
Nome in Regulation
Pyridino, 2,6-diamino-3-(phony lazo)-,
monohydroclt 1 or i do
Pyridino, 3-chloroifiethyl-,
hydrochior ide
Reserpine
Resorcinol
Saccharin and salts
Safrole
Sal icylani 1 ide, 2'5-dichloro-4'-nitro,
compound with 2-arcinoethano! (1:1)
Solenious acid
So 1 en i um
Selenium sulfide (SaS)
Selenium sulfide (SeS2)
Solenourea
Semi carbaz ide
Silver
*bi Oft^i»ri^'iV^^u\Ml^tJL.>^»V^!:£i,&£ittBJa'fr' s'rtV-r'pv^^ti^ia^uatx't
Eopirkai
Formula
C12H12N6CI
C6H7NCI2
C33H4oN209
C7H5N03S
C10*J10°2
C16H14N305CI2
H203Se
Se
SSe
S2So
CH4N2So
CH5N30
Ag
CAS Munib®r
13S-40-3
6959-48-4
50-55-5
100-46-3
81-07-2
04-59-7
14200-40-8
7783-00-8
7782-49-2
7446-34-6
7488-56-4
630-10-4
57-56-7
7440-22-4
97
dU^^-'in^-U-' ji-VrW^A:.
Anoiyoia . ROiA
Type: Method KathorS Othar
-- H
-- H
HPLC-IV —
HPLC''\ —
ItPLC
MS-PROB SRCH
MS-PROB SRCH
( ':
f -p
\ ,
")
1
;]
';'
^
1
1
' '
FWN-AA -- 7740 1 '•
i _jj
FURN-AA -- 7740 ' ; j
ft
FUflN-AA — 7740 ! 1
FURW-AA -- 7740 j -\
i ^
FURN-AA — 7740 { .•*
'-I
i '-•'i
ICP — 6010 '
•
• ' '. |
f-4JUi*itJi^^jiwLki^Jhfti^iwj>— .•*^
. *.
-. .\
• i
>i
•J
i^.
-------
Table A.I ITD/RCRA CflSPOUSD DATA (Continued)
Empirical
Noraa in Regulation Formula
Silver cyanide AgCN
Sodium cyanide MaCN
Sodium salt, dihydrate (of saccharin) CyllfcNt^S^^O'
Equal ene C3(flsQ
Streptozotocin ^8"l5^3^7
Strontium sulfide SSr
Strychnine and salts ^21^22^2^2
: Styrene ^gHg
' < Succinic acid, mercapto-, di ethyl ^10^19^6^^2
ester, S-ostor with 0,0-di methyl
phosphorod i th i oa te
Sulfuric acid, di ethyl ester C^H^O^S
alpha-Terpineol ^lo"
Tetrachloroethene ^-2^4
1,2,4,5-Tetrachlorobenzene CgH2CI4
1.,2,3,4-Tetrachlorobenzene ^6^2^-'4
1 ,2,3,5-Tetrachlorobonzene CgH2CI4
WtiAiiliiui&ii^^^
CAS Wusljar
EOS-64-9
143-33-9
•No 6165-67-3
7683-64-9
. 18883-66-4
1314-96-1
57-24-9
100-42-5
121-75-5
64-67-5
98-55-5
127-1B-4
95-84-3
634-66-2
634-90-2
98
.,; , . ,.-.. .
Anslyoio RCRA
Type Method Method Other
ICP
WET
CCHS
HPLC
ICP
GCMS
GCMS
PEST
~
GCMS
GCMS
GCMS
GCMS
GCMS
„. _
6010
—
SRCH
—
6010
SRCH
1625 8270
614 8140
H
1625 8270
1624 8240
SRCH
SRCH
SRCH
i
"* ' «-«;•*•—. — •— — -- - - ..... .. ... — • -, ***„ ._ •^n.^- »-<-.. .^^.,.y. „».,,_„ »„, ^.i ,i ••. •- ^.
V
•
:
t '"
s
••}
'• ,1
\l
• .
,(
-']
1
.;
1
|
.1
1
-------
I
!
I . ' Table
i
I
1 . •• •
Nemo in Regu'ntion
2,3,7, 8-Tetrach 1 orod i benzo-p-d i ox i n
Tetrach 1 orod i benzo-p-d i ox i ns
Tetrach 1 orod i benzof urans
1,1, 2 ,2-Tetrachl oroethane
1 , I , 1 ,2-Tetrach 1 oroethane
Tetrachloroethano, NOS
Totracli lor one thane •
2,3,5,6-Tetrachloroni trol>onzene
2,3,4,6-Tetrachlorophenrl
2,3,5,6-Tetrs«chlorophenol
2,3,4, 5-Tetrach 1 oropheno 1
n-Tetracosane
' pi
n-Tetradecane
Tetraefchyl lead
Tetraethy 1 d i th i opyrophosphate
Tetraethy ipyrophosphdte
\ ' • ' ' . ' ' ' '•
••'*>•. '.
1 • ' • \ '
'•• \ •
'•'.-. \
BwflliiBBBii*ff&ii't < n rail t-^sS&^^.^i^i^^A^^.'i'S^^Mj^S&i^^iia^^^^
A.I ITD/RCRA
Empirical
Formula
C12n4ci4o2
C12H4CI402
r n c(40
C2H2CI4
C2H2CI4
C2H2CI4
CCI4
C6IIN02C<4
C6H2OCI4
C6H2OCI4
C6H2OCI4
C24H50
C14U30
C8H20Pb
C8H20°5P2S2
C8H2007P2
fWOUND DATA
(Continued)
'1
1
:i
t
4
-»
i
Analysis RCRA •{
CAS dumber
1746-01-6
1-33-1
1-33-2
79-34-5
630-30-6
25322-20-7
S6-23-5
117-18-0
53-90-2
035-95-5
4901-51-3
648-31-1
623-59-4
78-00-2
3689-24-5
107-49-3
99
-j&J&&&^^£*i£^*^^
Tyss
OIUXIN
DIOXIN
DIOXIN
GCMS
GCMS
GCMS
GCMS
MS-PROB
GCMS
GCMS
GCMS
GCMS
GCMS
FURN-AA
GC-PROO
HPLC
Method Ue'-.hod Other
613 8280
\
'4
i •
•1
CLP 8280 P
CLP 8280 i I
I »
1624 8240
SRCH
SRCH
1624 8240
SRCH
;]
,"i
\
\
\
1
SRCH ;S
SRCH . ; I
SRC-I j^
1625 8270 i }
\ ''
1625 8270 I 5
7421 1
) "',
SRCH j i.|
H
' i
i
4
3
1
.y<
^
:j
••' • '.'•'.. .. • -jt''V-V" ' " '.'ij ''V^'li'1 '^{k*'"i"'i'v|
-2k:»Jkt^J~^,-'»i-iw^4otvV:^:Jwi^iSiiiiii*!i^ ^l^iJ^j^if»CiSSiisiisJi»^iijtA
-------
Tcblo A.I ITD/RCRA COMPOUND DATA (Continued)
Namo in Regulation
Tetramethy 1 lead
Tetran i tromethane
Tha 1 1 i c ox i de
Tha 1 1 i urn
Tha 1 1 i urn se 1 en i to
Thai 1 ium(I)acetato
Thai 1 ium(I)carbonate
Thai 1 ium(I)cMoride
Thai 1 ium(I)ni trate
Thai 1 ium(I)sulfate
Thianaphthene ,
Thioacetamide
Thiosemicarbazide
Thiourea
Thioxanthen-9-one
Thiram
-:^';&;,i^ :;-: -:.*> .'•>.•&*:. ; .^M^.-MJ&J, a<^? .,,>:
Empirical
Formu 1 a
C4HJ2Pb
CN408
03TI2
Tl
SeTI
C2H402»TI
C03TI2
LIT!
N03TI
04STI2
CaH6S
. C2H5NS
CH5N3S
CH2N2S
C13»8°5
C6H12N2S4
.••;*v -.•;•!. ~^-y\.'.-i:-".
CAS Mumbor
7S-74-1
609-14-8
1314-32-5
7440-28-0
12039-52-0
563-68-8
6533-73-fi
7791-12-0
10102-45-1
10031-69-1
95-15-8
62-65-1
79-19-6
62-56-68
492-22-8
137-26-8
100
Analysis
Type . Method
FURN-AA —
__
ICP
FURN-AA —
FURN-AA ~
FURN-AA —
FURN-AA -
FURN-AA --
FURN-AA —
FURN-AA —
GCMS SRCH
_.
HPLC
HPLC
CCMS SRCH
CS2 630
»•'** VV'i .i^.n-<.-«rtV *"-•«„
RCRA
Mothod Other
7421
6010
7841
7841
7841
7841
7841
7841
7841
H
.••j-isT.i-tvr' • • »•
-------
Table A.I ITD/RQU COMPOUND DATA (Continued)
|,
«\
timss&teM;^':^,
Nemo in Regulation
Toluene
Toluene diamine
'> Toluene, 2,4-dinmino-
\ • ;
3 , 4 -To 1 uened i am i no
o-V^luidine
\
V
o-Tolu<.dino hydrochloride
\
o-Toluidme, 4-(o-toly IBZO)-
o-To 1 u i d i no ;\5-ch 1 oro-
\
p-Toluidine, atpha, alpha, alpha-
trif 1 uoro-2.6-iJ.ini tro-N,W-dipropy 1 -
p-Toluidino, N-(2-ciSloroelhy l)-2,6-
dinitro-N-propyl-afpha, alpha,
. alp!ia-tr if luoro-
\
Tolyleno Oi isocyanate \
\
Total xy lanes
Toxajjliene
n-Triacontano .
\ •
\ . •
. ErcpiricoJ
Forraula
C7Ha
Cy *"i/y*2
7102
Witfh
C7II10KCI
C7H0NCI
Cl3»I6W3
C9H6N202
C8»10
C10H,0Clfl
C30II62
CAS Mtrabar
108-68-3
25376-4B-3
65-80-7
496-72-0
05-53-4
636-21-5
97-50-3
95-70-4
15B2-09-8
33245-39-5
26471-62-5
3-25-0
E001-35-2
638-BQ-3
101
Analyolo RCRA
Typa Uothod Mothod Other
CCMS 1624 8240
—
GCfcSS SRCH
OCMS SRCH
MS-PROB SRCH
MS-PROB SRCH
MS-PROb SRCH
MS-PROO SRCH
CCEC 617
II
CCUS SRCH
CCrC 608 8060
CCMS 1625 0270
i, . .,
-------
[*-. •
y
Table
Mams In Regulation
Tri ozone, 3,3-diraethyJ-l-(p-ch!oro-
phonyl)-
S-Triazine, 2,4-dichloro-6-(o-chloro-
ani liin
Trihroiaoaia thane
1 , 1 , 2-Tr i ch loro-2-f 1 uorosthana
1,2,3-Trichlorobanzone
1,3,5-Trichlorobanzena
1,2,4-Trichlorobenzena
1,1,1-Tr icMorcethane
1,1, 2-Tr icMoroathana
ji Trichloroetheno
Trichloromethanothiol
1 Trichloromonof luoromethone
\ 2,4,6-Trichlorophenol
a 2,4,5-Trichlorophenol
^- 2,3,6-TrichJoropbenol
1
'» • .:
K.I ITO/ROSA CO&Ot&D DATA {Continued)
Ecpirif.sl Anajyolo RCRA
FcrauJo CAS tafrfjstr Typo tbthod doihod Other
C6Hi0CIM3 7203-BO-O
C^%M3C3 101-05-3 GC-PRQ8
CHBr3 75-25-2 CCMS
C2H2CI3F 369-28-4 GCtiS
C6H3CI3 87-81 -S CCfcSS
CG^'S 10S-70-3 GCMS
C6H3CI3 120-82-1 GCyS
C2H3CI3 71-55-6 GCMS
C2H3CI3 79-00-5 GCMS
C2HCI3 79-01-8 GCMS
CHCI3S 75-07-7 GCMS
CCI3F 75-69-4 GCMS
C6H3CI30 68 -OS -2 CCMS
C6H3CI30 er-9S-4 GCMS
C6H3CI30 933-75-5 CCMS
102
V
SRCH |
1
1624 8240 |
SRCH
1625 8270
SRCH
1625 8270 I
1624 8240 [
1624 8240
1624 8240
SRCH •
SRCH
1625 8270
1625 8270
SRCH [
w _.;lu
-------
\
CJ
I
f,
^*.
^
,','.
Y.
i',
1 • i'' .' " ' '. •
Toblo
I • •
Name in Regulation
2,3,4-Trichlorophsnol
•:' ! 2,4,5-Tricblorophenoxyacetic acid
ic
2,4,5-Trichlorophenoxypropionic acid
fe.
j '. 1,2,3-Trichloropropane
;••• Trichloropropane, NOS
>r i
'! -1
K •- 0,0,0-Triethylphosphorothioate
V' 3,4,5-Tr imethoxybenzaldehyde
_*'•
1
i
[-•
^;-
1,2,3-Trimethoxy benzene
sym-Tri nitrobenzene
Tr i pheny 1 ene
Tr ipropy lencglycol methyl ether
Tris(l-azridinyl)phosphine sulf ide
,'• Tris(2,3-dibromopropyl)phosphata .
!•' ..
!•''
1,3,5-Trithiano
i) Try pan blue
C: • ' .
fc'j Uracil mustard
1: : • '
A.I ITD/RCRA
Eapiricol
Foraulo
C6H3CI30
C8»5Cf303
C9H7CI303
C3H5CI3
W3PS
C10H1204
C8H1203
C6H3N306
C18H12
C10fl21°3
C6N12N3PS
C9H1504Br6P
C3H6^3
C34H24N6014S4f
C8HllCI2N302
COMPOUND DATA
CAS Nudber
15950-65-0
93-70-5
83-72-1
96-18-4
1-37-1
126-68-1
8S-81-7
634-38-6
99-35-4
217-59-4
20324-33-8
62-24-4
126-72-7
291-21-4
Js4 72-57-1
66-75-1
(Continued)
AnaJyeio RCRA
Typa Uothod Method Othar
GCMS
CCEC
GCEC
GCMS
GCMS
MS-PROB
GCMS
CCMS
HPLC
CCMS
GCMS
HPLC
MS-PROB
CCMS
HPLC
HPLC
SRCH
615 8150
615 8150
SRCH
SRCH
SRCH
SRCH
~
SRCH
SRCH
SRCH
SRCH
—
ww
103
-------
f:
i/
Tab Io A.I ITD/RCRA
DATA (Continued)
Kama in Regulation
Ursa, l-ethyl-3-(5-nitro-2-thia/olyl)-
Vanadic acid (ammonium salt of)
Vanadium pentoxide ' ' '''
Vinyl acetate
Vinyl chloride
Warfarin (potassium salt)
Zinc
Zinc bis(dimethyldithiocarbamato)-.
Zinc cyanide '
Zinc phosphide
Zinc phosphide
Empirical
Formula
C7!I10N2OS
H4H«03V
W2
C4H602
C2H3CI
C19H16°4K
Zn
C6H12N2S4Zn
C2N2Zn
P2Zn3
P2Zn
. CAS Mumbor
B1-52-S
7603-55-6
1314-82-1
108-OS-4
75-01-4
2160-86-8
7440-66-S
137-30-4
557-21-1
*
1314-84-7
12037-79-5
Ann lysis
Typo CSathod
HPLC
ICP — •
GCMS SRCH
GCMS SRCH
GCMS 1624
—
ICP
CS2 630
ICP -- ••••
ICP
ICP
RCRA .
fJssthod Othor
6010
8240
H
6010
6C10
6010
6010
104
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