-------
GALBRAITH® LABORATORIES, INC.
Accuracy with speed - since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID
9002A Z-4552-53
ANALYSIS
Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
As
Received
11.86
44.08
6.77
1.11
0.11
2.54
140.00
73.00
<170
9.00
34.84
7601
Report Date:
Lab I.D.:
%
%
%
%
%
%
ppm
ppm
ppm
ppm
%
Btu/lb
Dry
50.01
6.19
1.26
0.12
2.88
160.00
83.00
<200
10.00
39.52
8624
1 1/20/98
Z-4550-53
I! Method
ASTMD-5142
% ASTM D-5373
% ASTM D-5373
% ASTM D-5373
% ASTM D-4239
% ASTMD-5142
ppm EPA SW-846
5050/9056
ppm ASTMD-3761
ppm EPA SW-846
5050/9056
ppm ASTM D-3 869
% ASTM D-3 176
Btu/lb ASTM D- 1989
BUILDING
PARTNERSHIPS
FOR CONTINUOUS iMntovtMENT
This report shall not be reproduced, except in full, without trie written approval of the laboratory.
U.S. Mail: P.O. Box 51610 Knoxvi/le, TN 37950-1610
Other Carriers: 2323 Sycamore Drive Knoxville, TN 37921-1750
Tel: (423) 546-1335 • Fax:(423)546-7209
Page 4 of 7
APPENDIX C
43
-------
GALBRAITH® LABORATORIES, INC.
Accuracy with speed since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ED LAB ID ANALYSIS
9002A Z-4552-53 Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
Report Date:
Lab I.D.:
As
Received
410
<9
<9
<4
<4
<4
<4
320
<9
730
30
O.043
<0.044
O.043
<4
0.67
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
Dry
470
<10
<10
<5
<5
<5
<5
360
<10
830
34
O.049
<0.050
<0.049
<5
0.76
11/20/98
Z-4550-53
pppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
BUILDING
PARTNERSHIPS
FOR CONTINUOUS IMPROVEMENT
This report shall not be reproduced, except in full, without the written approval of the laboratory. Page 5 01 7
U.S. Mail: P.O. Box 51610 Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive Knoxville, TN 37921-1750
Tel: (423) 546-1335 • Fax: (423) 546-7209
APPENDIX C 44
-------
GALBRAITH® LABORATORIES, INC.
Accuracy with speed since 1950
LABORATORY REPORT
.David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
9002A Z-4552-53 Selenium
Silver
Sodium
Vanadium
Zinc
Report Date: 1 1/20/98
Lab I.D.: Z-4550-53
As
Received
<9 ppm
<0.9 ppm
90 ppm
<4 ppm
14 ppm
Dry I! Method
<10 ppm EPA SW-846
3050B/6010
<1 ppm EPA SW-846
3050B/6010
100 ppm EPA SW-846
3050B/6010
<5 ppm EPA SW-846
3050B/6010
16 ppm EPA SW-846
3050B/6010
PARTNERSHIPS
KM CONTINUOUS IMPROVEMENT
This report shall not be reproduced, except in full, without the vwitten approval of the laboratory. Page 6 of 7
U.S. Mail: P.O. Box 51610 • Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive Knoxville, TN 37921-1750
Tel: (423) 546-1335 • Fax: (423) 546-7209
APPENDIX C
45
-------
GALBRAITH® LABORATORIES, INC.
Accuracy with speed - since 1950
LABORATORY REPORT
David Alburty Report Date: 11/20/98
Midwest Research Institute Lab I.D.: Z-4550-53
Note
The original Chain of Custody is included with the mailed report.
Preparation Confirmation
As requested, Lab ID#s Z-4550-53 were refrigerated prior to analysis. The samples were also dried and ground prior to analysis to
provide a more homogeneous sample for testing.
PAC :yd TOs report shall not be reproduced, except in full, without the written approval of the laboratory. Page 7 of 7
3. Mail: P.O. Box 51610 Knoxville, TN 37950-1610
^SSp, Other Carriers: 2323 Sycamore Drive Knoxville, TN 37921-1750
FOKCo^TiNuousiMriravEMEwr Tel: (423) 546-1335 • Fax: (423) 546-7209
APPENDIX C
46
-------
GALBRAITH® LABORATORIES, INC.
Accuracy with speed - since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
425 Volker Blvd.
Kansas City MO 64110
SAMPLE ID LAB ED ANALYSIS
9001 A Repeat A-2 183-84 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Reanalysis Request:
Previous Lab ID:
Report Date:
Purchase Order #:
Fax Number:
As
Received
11.72 (a)
44.32
6.66
1.11
0.088
2.61
123.00
13
<90
15
34.78
7672
350
<6
<6
<4
<4
<4
<4
310
<6
%
%
%
%
%
%
ppm
ppm
ppm
ppm
%
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Dry
50.20
6.07
1.26
0.10
2.96
139.00
14
<100
17
39.40
8691
400
<7
<7
<4
<4
<4
<4
350
<7
1 1/30/98
Z-4550-53
12/18/98
A035822
816-531-0315
%
%
%
%
%
ppm
ppm
ppm
ppm
%
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
1 Method
ASTMD-5142
ASTM D-5373
ASTM D-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTM D-3 869
ASTM D-3 176
ASTM D- 1989
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
This report shall not be reproduced, except in full, without the written approval of ths laboratory.
Page 1 Of 5
19%
BUILDING
PARTNERSHIPS
KIR COvmUOUS IMPROVEMENT
U.S. Mail: P.O. Box 51610 Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive Knoxville, TN 37921-1750
Tel: (423) 546-1335 • Fax: (423) 546-7209
APPENDIX C
47
-------
GALBRAITH® LABORATORIES, INC.
Accuracy with speed since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
9002A Repeat A-2 185-86 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Reanalysis Request:
Previous Lab ID:
As
Received
11.86 (a)
44.29
6.68
1.09
0.078
2.64
96
16
<90
6
34.67
7623
400
<7
<7
<4
<4
<4
<4
330
<7
%
%
%
%
%
%
ppm
ppm
ppm
ppm
%
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Dry
50.25
6.08
1.24
0.089
2.99
110
18
<100
7
39.34
8649
450
<8
<8
<5
<5
<5
<5
380
<8
11/30/98
A-2183-A-2186
%
%
%
%
%
ppm
ppm
ppm
ppm
%
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
It Method
ASTMD-5142
ASTM D-5373
ASTMD-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTM D-3869
ASTM D-3 176
ASTMD-1989
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
This report shall not be reproduced, except in full, without the written approval of the laboratory.
L/.S. Mail: P.O. Box 51610 Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive Knoxville, TN 37921-1750
Tel: (423) 546-1335 . Fax: (423) 546-7209
APPENDIX C
Page 3 of5
48
-------
GALBRAITH® LABORATORIES, INC.
Accuracy with speed since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
425 Volker Blvd.
Kansas City MO 64110
SAMPLE ED LAB ED ANALYSIS
8001A Z-5069 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine , 3 ,„„
-, ' j f 1
i\*.p^t iz/i^/fS'
Bromine
Iodine
Oxygen (by diff)
HHV
Mercury
Report Date:
Sample Received:
Purchase Order #:
Fax#:
As
Received
11.14
11.43
46.02
45.89
6.83
6.75
<0.44
O.44
0.049
0.037
1.29
1.32
<89
<89
22
24
<89
<89
3
4
35.33
35.52
7778
8288
O.043
0.043
<0.044
<0.042
<0.043
<0.043
%
%
%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm
Dry
51.87
51.73
6.29
6.20
O.50
O.50
0.055
0.042
1.45
1.49
<100
<100
25
27
<100
<100
3
5
39.82
40.03
8767
9342
<0.048
O.049
<0.050
<0.047
<0.049
<0.049
12/04/98
09/29/98
A035822
816-531-0315
%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm
Method
ASTMD-5142
ASTM D-5373
ASTM D-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTM D-3 761
EPA SW-846
5050/9056
ASTM D-3 869
ASTM D-3 176
ASTM D- 1989
EPA SW-846
7471
This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 1 of3
BUILDING
PARTNERSHIPS
KM CON11SUOUS lMrKOVEM€NT
U.S. Mail: P.O. Box 51610 Knoxvi/le, TN 37950-1610
Other Carriers: 2323 Sycamore Drive Knoxville, TN 37921-1750
Tel: (423) 546-1335 • Fax: (423) 546-7209
APPENDIX C
49
-------
GALBRAITH® LABORATORIES, INC.
Accuracy with speed since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
8002A Z-5070 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine -?/,„<
A«/VWf IZ/LtfC'%
Bromine
Iodine
Oxygen (by difi)
HHV
Mercury
Report Date:
Lab I.D.:
As
Received
11.57
11.61
45.65
45.81
6.72
6.81
<0.44
<0.44
0.038
0.034
1.23
1.31
<88
<88
82
80
<88
<88
2
2
35.61
35.28
8036
8213
<0.042
O.044
<0.042
<0.043
<0.043
<0.044
%
%
%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm
Dry
51.63
51.82
6.15
6.25
<0.50
<0.50
0.043
0.038
1.39
1.48
<100
<100
93
91
<100
<100
2
2
40.28
39.91
9089
9290
<0.048
O.050
<0.048
<0.049
<0.049
<0.050
12/04/98
Z-5069-70
%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm
I! Method
ASTMD-5142
ASTMD-5373
ASTMD-5373
ASTM D-5373
ASTMD-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTMD-3869
ASTM D-3 176
ASTM D- 1989
EPA SW-846
7471
19%
BUILDING
PARTNERSHIPS
FOR CONTINUOUS iMrwovrwcHT
This report shall not be reproduced, except in full, without the written approval of the laboratory. Page 2 of 3
U.S. Mail: P.O. Box 51610 Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive Knoxville. TN 37921-1750
Tel: (423) 546-1335 • Fax: (423) 546-7209
APPENDIX C
5O
-------
GALBRAITH® LABORATORIES, INC.
Accuracy with speed since 1950
LABORATORY REPORT
David Alburty Report Date: 12/04/98
Midwest Research Institute Labl.D.: Z-5069-70
Note
The original Chain of Custody is included with the mailed report.
Preparation Confirmation
As requested, Lab ID#s Z-5069 and Z-5070 were refrigerated prior to analysis. The samples were also dried and ground prior to
analysis to provide a more homogeneous sample for testing.
PACiyd This report shall not be reproduced, except in full, without the written approval of the laboratory. Page 3 of3
L/.S. Mail: P.O. Box 51610 Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive Knoxville, TN 37921-1750
Tel: (423) 546-1335 • Fax: (423) 546-7209
APPENDIX C 51
-------
GALBRAITH® LABORATORIES, INC.
Accuracy with speed since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
425 Volker Blvd.
Kansas City MO 64110
SAMPLE DD LAB ED ANALYSIS
1 00 1 A Z-3 778 - 79(a) Karl Fischer
Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
Density
Viscosity
CORRECTED REPORT
Date Corrected: 12/16/98
Sample Received: 09/18/98
Original Report Date: 1 2/04/98
Purchase Order #: A035822
Fax Number: 816-531-0315
As
Received
0.042 (d)
0.040 (d)
79.86
79.95
10.72
10.79
<0.50
<0.50
0.73
0.67
1.31
1.20
<92
<98
78
i 74
<92
<98
4
4
6.87
6.88
16756
17244
1.017
1.017
207.29
207.16
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
Btu/lb
Btu/lb
g/cmj
g/cm3
cSt (c)
@100°C
Dry
79.89 %
79.98 %
10.72 %
10.79 %
<0.50 %
<0.50 %
0.73 %
0.67 %
1.31 %
1 .20 %
<92 ppm
<98 ppm
78 ppm
74 ppm
<92 ppm
<98 ppm
4 ppm
4 ppm
6.87 %
6.88 %
16763 Btu/lb
17251 Btu/lb
Method
ASTMD-5142
ASTM D-5373
ASTM D-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTM D-3761
EPA SW-846
5050/9056
ASTM D-3869
ASTM D-3 176
ASTM D-1989
ASTM D-445
BUILDING
PARTNERSHIPS
FOR CONTINUOUS IMPROVEMENT
This report shall not be reproduced, except in full, without the written approval of the laboratory.
L/.S. Mail: P.O. Box 51610 Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive Knoxville, TN 37921-1750
Tel: (423) 546-1335 • Fax:(423)546-7209
Page I of II
APPENDIX C
-------
GALBRAITH® LABORATORIES, INC.
Accuracy with speed since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
1001A Z-3778 - 79(a) Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
Corrected Report Date:
Lab I.D.:
As
Received
8
9
<7
<6
<7
<6
<4
<4
<4
<4
<4
<4
<4
<4
330
330
<7
<6
11
10
13
13
<0.050
<0.049
<0.047
<0.046
<0.050
<0.049
<4
<4
270
260
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Dry
8
9
<7
<6
<7
<6
<4
<4
<4
<4
<4
<4
<4
<4
330
330
<7
<6
11
10
13
13
<0.050
<0.049
<0.047
O.046
<0.050
<0.049
<4
<4
270
260
12/16/98
Z-3778-87
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
I! Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
PARTNERSHIPS
FOR CONTINUOUS IMrROVEMENT
This report shall not be reproduced, except m full, without the written approval of the laboratory.
U.S. Mail: P.O. Box 51610 • Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive Knoxville, TN 37921-1750
Tel: (423)546-1335 • Fax:(423)546-7209
Page 2 of 11
APPENDIX C
53
-------
GALBRAITH® LABORATORIES, INC.
Accuracy with speed since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
1001A Z-3778-79(a) Selenium
Silver
Sodium
Vanadium
Zinc
Corrected Report Date:
As
Received
<7
<4
<1
<1
0.37
0.37
<4
<4
9
8.
Lab I.D.:
ppm
ppm
ppm
ppm
%
%
ppm
ppm
ppm
ppm
12/16/98
Z-3778-87
Dry
<7
<4
<1
<1
0.37
0.37
<4
<4
9
8
ppm
ppm
ppm
ppm
%
%
ppm
ppm
ppm
ppm
1 Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
This report shall not ba reproduced, except in full, without (He written approval of the laboratory
Page 3 of 1 1
U.S. Mail: P.O. Box 51610 Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive Knoxville. TN 37921-1750
Tel: (423) 546-1335 • Fax:(423)546-7209
APPENDIX C
54
-------
GALBRAITH® LABORATORIES, INC.
Accuracy with speed since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
1002A Z-3780-81(a) Karl Fischer
Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
»?f>?c.-t (,\- 2-c*. yfl ''l\
Bromine
Iodine
Oxygen (by diff)
HHV
Density
Viscosity
Corrected Report Date:
Lab I.D.:
As
Received
0.059 (d)
0.040 (d)
79.64
79.68
10.54
10.76
<0.50
<0.50
0.60
0.65
1.44
1.43
<92
<95
10
9
<92
<95
2
3
7.27
6.98
17085
17044
1.023
1.022
202.44
202.47
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
Btu/lb
g/cmj
g/cm3
cSt (c)
@100°C
Dry
79.68
79.72
10.54
10.76
<0.50
<0.50
0.60
0.65
1.44
1.43
<92
<95
10
9
<92
<95
2
3
7.28
6.98
17093
17052
12/16/98
Z-3778-87
1 Method
ASTMD-5142
% ASTM D-5373
% ASTM D-5373
% ASTM D-5373
% ASTM D-4239
% ASTMD-5142
ppm EPA SW-846
ppm 5050/9056
ppm ASTMD-3761
ppm
ppm EPA SW-846
ppm 5050/9056
ppm ASTM D-3869
ppm
% ASTM D-3 176
Btu/lb ASTM D- 1989
ASTM D-445
BUILDING
PARTNERSHIPS
FOR CONTINUOUS IMPHOVEMENT
This report shall not be reproduced, except in full, without the written approval of the laboratory.
L/.S. Mail: P.O. Box 51610 Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive Knoxville, TN 37921-1750
Tel: (423) 546-1335 • Fax: (423) 546-7209
Page 4 of 1 1
APPENDIX C
55
-------
GALBRAITH® LABORATORIES, INC.
Accuracy with speed - since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
1002 A Z-3780-81(a) Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
Corrected Report Date:
Lab I.D.:
As
Received
10
9
! <7
<8
<7
<5
<4
<5
<4
<5
<4
<5
<4
340
340
<8
<7
13
10
13
13
O.049
<0.047
<0.047
<0.051
<0.047
<0.048
<5
<4
270
270
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Dry
10
9
140
<7
<8
<7
<5
<4
<5
<4
<5
<4
<5
<4
340
340
<8
<7
13
10
13
13
<0.049
<0.047
<0.047
<0.051
<0.047
<0.048
<5
<4
270
270
12/16/98
Z-3778-87
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
This report shall not be reproduced, except m full, without the written approval of the laboratory.
U.S. Mail: P.O. Box 51610 Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive Knoxville, TN 37921-1750
Tel: (423) 546-1335 • Fax: (423) 546-7209
APPENDIX C
Page 5 of II
56
-------
GALBRAITH® LABORATORIES, INC.
Accuracy with speed since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE EO LAB ED
Corrected Report Date:
Lab I.D.:
ANALYSIS As Dry
Received
12/16/98
Z-3778-87
1 Method
1002A Z-3780-81(a) Selenium
Silver
Sodium
Vanadium
Zinc
4003 A Z-3782(a) Chlorine
Fluorine
Bromine
Iodine
<8
<7
-------
GALBRAITH® LABORATORIES, INC.
Accuracy with speed since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
4002A Z-3784-85 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
Aluminum
Antimony
Corrected Report Date: 12/16/98
Lab I.D.: Z-3778-87
As
Received
96.44
96.44
1.83
1.81
10.93
10.93
0.27
0.27
0.026
0.027
0.52
0.51
0.049
0.045
2.76
2.88
-------
GALBRAITH® LABORATORIES, INC.
Accuracy with speed - since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
Corrected Report Date:
Lab I.D.:
As Received
Dry
12/16/98
Z-3778-87
|| Method 1
4002A Z-3784-85 Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
Selenium
Silver
Sodium
Vanadium
Zinc
<0.3
<0.3
0.2
0.2
O.2
<0.2
1.0
1.0
0.68
0.69
0.022
0.022
<0.3
0.3
0.0036
0.0039
4
4
0.0021
O.0018
0.0018
O.0018
0.0017
O.0018
1.9
1.9
0.0035
0.0035
O.3
0.3
O.04
O.04
0.10
0.10
O.2
O.2
4
4
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
ppm
ppm
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
ppm
ppm
ppm
ppm
%
%
ppm
ppm
ppm
ppm
<8
<8
<5
<5
<5
<5
29
29
19
19
0.62
0.63
<8
<8
0.10
0.11
100
100
0.058
O.051
O.051
O.051
O.049
O.050
53
53
0.098
0.099
<8
<8
<1
<1
2.69
2.74
<5
<5
100
100
ppm
Ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
ppm
ppm
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
ppm
ppm
ppm
ppm
%
%
ppm
ppm
ppm
ppm
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
BUILDING
PARTNERSHIPS
FOR CONTINUOUS IMPROVEMENT
This report shall not be reproduced, except in full, without the written approval of the laboratory
U.S. Mail: P.O. Box 51610 Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: (423) 546-1335 • Fax: (423) 546-7209
Page 8 01 1 1
APPENDIX C
59
-------
GALBRAITH® LABORATORIES, INC.
Accuracy with speed since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ED LAB ED ANALYSIS
4001 A Z-3786-87 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Corrected Report Date:
Lab I.D.:
As
Received
96.49
96.46
1.86
1.85
10.94
10.94
0.27
0.27
0.028
0.026
0.50
0.50
0.053
0.054
3
3
<16(b)
<18(b)
0.2
0.2
0.60
0.61
352
361
0.0063
0.0063
<0.3
<0.3
<0.3
<0.3
<0.2
<0.2
<0.2
<0.2
%
%
%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Dry
52.66
52.46
6.14
6.53
7.65
7.57
0.79
0.75
14.27
14.21
1.49
1.54
77
80
<470(b)
<500(b)
6
5
17.00
17.34
9973
10227
0.18
0.18
<8
<8
<8
<8
<5
<5
<5
<5
12/16/98
Z-3778-87
%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
I! Method
ASTMD-5142
ASTM D-5373
ASTMD-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTM D-3869
ASTM D-3 176
ASTM D-1989
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
This report shall not be reproduced, except in full, without the written approval of the laboratory.
U.S. Mail: P.O. Box 51610 Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive Knoxville, TN 37921-1750
Tel: (423) 546-1335 • Fax: (423) 546-7209
Page 9 of 11
APPENDIX C
60
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GALBRAITH® LABORATORIES, INC.
Accuracy with speed since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
Corrected Report Date:
Lab I.D.:
As
Received
Dry
12/16/98
Z-3778-87
Method
4001A Z-3786-87 Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
Selenium
Silver
Sodium
Vanadium
Zinc
0.96
0.93
0.67
0.66
0.023
0.022
<0.3
<0.3
0.0042
0.0039
4
4
O.017
0.017
O.018
O.017
O.018
O.018
2
2
0.0036
0.0037
0.3
O.3
O.04
0.03
0.10
0.093
0.2
O.2
3
3
ppm
PPrn
ppm
ppm.
%
%
ppm
ppm
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
ppm
ppm
ppm
ppm
%
%
ppm
ppm
ppm
ppm
27
26
19
19
0.65
0.62
<8
<8
0.12
0.11
100
100
O.049
O.049
O.051
O.049
O.051
0.051
53
51
0.10
0.10
<8
<8
<1
<1
2.84
2.65
<5
<5
99
99
ppm
ppm
ppm
ppm
%
%
ppm
ppm
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
ppm
ppm
ppm
ppm
%
%
ppm
ppm
ppm
ppm
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
BUILDING
PARTNERSHIPS
FOR CONIINUOUS IMPROVEMENT
This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 10 of 11
U.S. Mail: P.O. Box 51610 Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive Knoxville, TN 37921-1750
Tel: (423) 546-1335 • Fax: (423) 546-7209
APPENDIX C
61
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GALBRAITH® LABORATORIES, INC.
Accuracy with speed since 1950
LABORATORY REPORT
David Alburty Corrected Report Date: 12/16/98
Midwest Research Institute Lab I.D.: Z-3778-87
General Note
The original Chain of Custody is included with the mailed report.
Preparation Confirmation
As requested, Lab ID#s Z-3778-87 were refrigerated prior to analysis. The samples were also dried and ground, unless otherwise
noted, prior to analysis to provide a more homogeneous sample for testing.
Technical Note
(a)Lab ID#'s Z-3778-83 were analyzed on an as received basis.
^ The detection limit for Bromine is elevated due to the presence of high levels of nitrate in samples.
This result was inadvertantly omitted from the original Laboratory Report. We apologize for any inconvenience our error may
have caused.
(d) This result was inadvertantly omitted.
PACiyd This report shall not be reproduced, except in full, without the written approval of the laboratory. Page 11 of 11
U.S. Mail: P.O. Box 51610 Knoxville, TN 37950-1610
MM™ Other Carriers: 2323 Sycamore Drive Knoxville, TN 37921-1750
raRcoN-^'SLSS.viMEKT Tel: (423) 546-1335 • Fax: (423) 546-7209
APPENDIX C
-------
GALBRAITH® LABORATORIES, INC.
Accuracy with speed - since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
425 Volker Blvd
Kansas City MO 64110-2299
SAMPLE ID LAB ID ANALYSIS
11001A Repeat A-4361 Fluorine
11001A Repeat A-4362 Antimony
11002A Repeat A-4363 Fluorine
11001C Repeat A-4364 Chlorine
11002C Repeat A-4365 Chlorine
Reanalysis Request: 12/18/98
Previous Lab I.D.: A4361-65
Report Date: 01/07/99
Fax Number: 816-531-0315
RESULT(S)
0.18
0.19 (a)
72
82 (b)
280
240 (a)
66
100 (c)
71
37 (c)
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
'OS
19%
BL1LDINC
PAKINERSMIPS
FOR COVmt-OUS IMrWOVEMEVT
This report snail not be reproduced, except in full, without the written approval of the laboratory.
U.S. Mail: P.O. Box 51610 Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive Knoxville. TN 37921-1750
Tel: (423) 546-1335 • Fax: (423) 546-7209
Page 1 of2
APPENDIX C
63
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GALBRAITH® LABORATORIES, INC.
Accuracy with speed since 1950
LABORATORY REPORT
David Alburty Report Date: 01/17/99
Midwest Research Institute Labl.D.: A-4361-A-4365
Technical Notes
(a) The retest confirms the fluorine levels found in the original analyses.
^ The retest confirms the presence of antimony in sample 11001 A. The antimony appears to be heterogeneously distributed in the
sample.
(c)
The retest results indicates the chlorine does not appear to be evenly distributed throughout the sample.
PAClle /^^/iLwS/^^wf ™S rBPOrt Sha" "°t ^repfoduced'except" (ul|.*ithou the written approval of the laboratory. Page 2 of 2
r\ _* -. U.S. Mail: P.O. Box 51610 Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive Knoxville, TN 37921-1750
Tel: (423) 546-1335 • Fax: (423) 546-7209
APPENDIX C Ka
-------
GALBRAITH® LABORATORIES, INC.
Accuracy with speed since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
425 Volker Blvd.
Kansas City MO 64110
Reanalysis Request:
Previous Lab I.D.:
Report Date:
Fax#:
12/18/98
Z-3778, Z-3780-81
12/28/98
816-531-0315
SAMPLE ED
I001A Repeat
1002A Repeat
1002A Repeat
LAB ED
A-4201
A-4202
A-4203
ANALYSIS
Fluorine
Fluorine
Antimony
62
20
<9
RESULTS
ppm
ppm
* ppm
DUPLICATE METHOD
RESULTS
58 ppm ASTMD-3761
16 ppm ASTMD-3761
<10 * ppm EPASW-846
3050B/6010
ee\
PARTNERSHIPS
ran Cor^TiNuous IMCKOVE.MECT
This report shall not be reproduced, except in full, without the written approval of the laboratory.
U.S. Mail: P.O. Box 51610 Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive Knoxville, TN 37921-1750
Tel: (423) 546-1335 • Fax: (423) 546-7209
Page 1
APPENDIX C
65
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GALBRAITH® LABORATORIES, INC.
Accuracy with speed since 1950
LABORATORY REPORT
David Alburty Reanalysis Report Date: 12/28/98
Midwest Research Institute Lab I.D.: A-4201-A-4203
Note
*
As requested, Lab ID#s A-4201-03 were refrigerated prior to analysis.
Technical Note
* The original sample 1002A appears to have been contaminated with antimony prior to analysis. There is no charge for the repeat
antimony analysis.
P AC: le This report shall not be reproduced, except in full, without the written approval of the laboratory. Page 2 of 2
q«%
^^.y (On* •^ij^h>j.
^*y L? toaf. H
L/.S. Mail: P.O. Box 51610 Knoxville, TN 37950-1610
I-..TNEUH.PS Other Carriers: 2323 Sycamore Drive Knoxville. TN 37921-1750
racoN^SSSmMEwr Tel: (423) 546-1335 • Fax: (423) 546-7209
PARTNERSHIPS
APPENDIX C 66
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GALBRAITH® LABORATORIES, INC.
Accuracy with speed since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ED ANALYSIS
9001A Repeat A-2I83-84 Magnesium
Manganese
Mercury
Nickel
Potassium
Selenium
Silver
Sodium
Vanadium
Zinc
Reanalysis Request:
Lab I.D.:
As
Received
770
28
<0.045
<0.043
O.041
<4
0.61
<6
<2
120
<4
9
ppm
ppm
ppm
ppm
ppm
ppm
%
ppm
ppm
ppm
ppm
ppm
Dry
880
32
<0.051
<0.049
O.047
<4
0.69
<7
<2
140
<4
10
12/18/98
A-2183-A-2186
ppm
ppm
ppm
ppm
ppm
ppm
%
ppm
ppm
ppm
ppm
ppm
I! Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
BUILDING
PARTNERSHIPS
FOR COVIIMJOUS I WrROVEME.VT
This report shall not be reproduced, except in full, without the written approval of the laboratory. Page 2 of 5
U.S. Mail: P.O. Box 51610 Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive Knoxville, TN 37921-1750
Tel: (423) 546-1335 • Fax: (423) 546-7209
APPENDIX C 67
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GALBRAITH® LABORATORIES, INC.
Accuracy with speed since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
9002A Repeat A-2 185-86 Magnesium
Manganese
Mercury
Nickel
Potassium
Selenium
Silver
Sodium
Vanadium
Zinc
As
Received
790
29
<0.043
O.042
O.043
<4
0.59
<7
<2
130
<4
9
Reanalysis
Lab I.D.:
ppm
ppm
ppm
ppm
ppm
ppm
%
ppm
ppm
ppm
ppm
ppm
Request:
Dry
890
33
O.049
O.048
O.049
<5
0.67
<8
<2
150
<5
10
12/18/98
A-2183-A-2186
ppm
ppm
ppm
ppm
ppm
ppm
%
ppm
ppm
ppm
ppm
ppm
1 Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
BUILDING
PARTNERSHIP
FOR COSTINUOtS [MfHOVEMEVT
This report shall not be reproduced, except in full, without the written approval of the laboratory. Page 4 of 5
U.S. Mail: P.O. Box 51610 Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: (423) 546-1335 • Fax:(423)546-7209
APPENDIX C 68
-------
GALBRAITH® LABORATORIES, INC.
Accuracy with speed since 1950
LABORATORY REPORT
David Alburty Reanalysis Report: 12/18/98
Midwest Research Institute Lab I.D.: A-2183-A-2186
General Note
As requested, Lab ID#'s A-2183-85 were refrigerated prior to analysis. The samples were also dried and ground prior to analysis to
provide a more homogeneous sample for testing.
(l) The moisture results reported with these samples were determined under Lab ID #'s Z-4550-53. Each sample was dried in its entirety
for the initial testing.
LE:le Th's report shall not be reproduced, except in full, without the written approval of the laboratory. Page 5 of 5
L/.S. Mail: P.O. Box 51610 Knoxville, TN 37950-1610
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Tel: (423) 546-1335 • Fax:(423)546-7209
APPENDIX C
69
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GALBRAITH® LABORATORIES, INC.
Accuracy with speed since 1950
LABORATORY REPORT
David Alburty Reanalysis Request: 12/20/98
Midwest Research Institute Previous Lab I.D.: Z-3923-24
425 Volker Blvd. Report Date: 12/28/98
Kansas City MO 64110 Fax#: 816-531-0315
SAMPLED) LAB ID ANALYSIS RESULTS
6001 A Repeat A-4204 Fluorine 10 ppm
DUPLICATE METHOD
RESULTS
18 ppm ASTMD-3761
6002A Repeat A-4205
Fluorine
53
ppm
48
ppm
ASTM D-3761
BUILDING
PARTNERSHIPS
FOR CONTINUOUS JMDIOVEM£NT
TWs report shall not be reproduced, except in full, without the written approval of the laboratory.
U.S. Mail: P.O. Box 51610 Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive Knoxville, TN 37921-1750
Tel: (423) 546-1335 • Fax: (423) 546-7209
APPENDIX C
Pag'i
70
-------
GALBRAITH® LABORATORIES, INC.
Accuracy with speed since 1950
LABORATORY REPORT
David Alburty Reanalysis Report Date: 12/28/98
Midwest Research Institute Lab I.D.: A-4204-A-4205
Note
As requested, Lab ID#s A-4204-05 were refrigerated @4°C prior to analysis.
Analyses were performed on a dried and ground basis.
PAC:le This report shall not be reprodjced, except in full, without the wiitlen approval of the laboratory. Page 2 Of2
B|
1 U.S. Mail: P.O. Box 51610 Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive Knoxville, TN 37921-1750
Tel: (423) 546-1335 • Fax: (423) 546-7209
APPENDIX C 7T
-------
GALBRAITH® LABORATORIES, INC.
Accuracy with speed since 1950
LABORATORY REPORT
David Alburty Reanalysis Request: 12/20/98
Midwest Research Institute Previous Lab I.D.: Z-5069-70
425 Volker Blvd. Report Date: 12/28/98
Kansas City MO 64110 Fax#: 816-531-0315
SAMPLED) LAB ID ANALYSIS RESULTS
8001 A Repeat A-4206 Fluorine 13 ppm
DUPLICATE METHOD
RESULTS
19 ppm ASTMD-3761
8002A Repeat A-4207
Fluorine
71
ppm
66
ppm
ASTMD-3761
BUILDING
PARTNERS KIPS
FOB CONTINUOUS IMPROVEMENT
This report shall not be reproduced, except in full, without the written approval of the laboratory.
U.S. Mail: P.O. Box 51610 • Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive Knoxville, TN 37921-1750
Tel: (423)546-1335 • Fax:(423)546-7209
APPENDIX C
Page I
72
-------
GALBRAITH® LABORATORIES, INC.
Accuracy with speed since 1950
LABORATORY REPORT
David Alburty Reanalysis Report Date: 12/28/98
Midwest Research Institute Labl.D.: A-4206-A-4207
Note
As requested, Lab ID#s A-4206-07 were refrigerated @4°C prior to analysis.
Samples 8001A and 8002A were analyzed on the dried and ground basis.
PAClle This report shall not be reproduced, except in full, without ttie written approval of the laboratory. Page 2 of 2
U.S. Mail: P.O. Box 51610 Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive Knoxville. TN 37921-1750
Tel: (423) 546-1335 • Fax: (423) 546-7209
APPENDIX C 73
-------
GALBRAITH® LABORATORIES, INC.
Accuracy with speed - since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
425 Volker Blvd.
Kansas City MO 64110
SAMPLE ID LAB DD
9001 A Z-4550-51
ANALYSIS
Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
As
Received
11.72
44.01
6.64
1.14
0.11
2.96
110
18
<170
23
34.72
7423
Report Date:
Sample Received:
Purchase Order #:
Fax#:
%
%
%
%
%
%
ppm
ppm
ppm
ppm
%
Btu/lb
11/20/98
09/24/98
A035822
816-531-0315
Dry
49.85
6.05
1.29
0.12
3.35
120
20
<200
26
39.33
8409
%
%
%
%
%
ppm
ppm
ppm
ppm
%
Btu/lb
1 Method
ASTMD-5142
ASTMD-5373
ASTMD-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTM D-3761
EPA SW-846
5050/9056
ASTM D-3869
ASTM D-3 176
ASTM D-l 989
Thii report shall not be reproduced, except in full, without the written approval of the laboratory. Page 1 of 7
L/.S. Mail: P.O. Box 51610 Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive Knoxville, TN 37921-1750
Tel: (423) 546-1335 • Fax:(423)546-7209
APPENDIX C 74
-------
GALBRAITH® LABORATORIES, INC.
Accuracy with speed since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
9001 A Z-4550-51 Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
Report Date:
Lab I.D.:
As
Received
530
<9
<9
<4
<4
<4
<4
350
<9
790
31
<0.040
O.044
O.043
<4
0.72
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
Dry
600
<10
<10
<5
<5
<5
<5
400
<10
890
35
O.045
<0.050
<0.050
<5
0.81
1 1/20/98
Z-4550-53
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
BUILDING
PARTOERSHIPS
FOR CONTINUOUS IMPROVEMENT
Tills report shall not b« reproduced, except in full, without the written approval of the laboratory. Page 2 of 7
U.S. Mail: P.O. Box 51610 • Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive Knoxville. TN 37921-1750
Tel: (423) 546-1335 • Fax:(423)546-7209
APPENDIX C 75
-------
GALBRAITH® LABORATORIES, INC.
Accuracy with speed since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
9001A Z-4550-51 Selenium
Silver
Sodium
Vanadium
Zinc
Report Date: 11/20/98
Lab I.D.: Z-4550-53
As
Received
<9 ppm
<0.9 ppm
95 ppm
<4 ppm
16 ppm
Dry 1 Method
I
<10 ppm EPA SW-846
3050B/6010
<1 ppm EPA SW-846
3050B/6010
110 ppm EPA SW-846
3050B/6010
<5 ppm EPA SW-846
3050B/6010
18 ppm EPA SW-846
3050B/6010
This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 3 of 7
BUILDING
PARTNERSHIPS
FOR CONTINUOUS IMPROVEMENT
U.S. Mail: P.O. Box 51610 Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive Knoxville, TN 37921-1750
Tel: (423) 546-1335 • Fax:(423)546-7209
APPENDIX C Z6
-------
Galbraith Laboratories, Inc.
Accuracy with Speed - Since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
425 Volker Blvd.
Kansas City MO 64110
SAMPLE ED LAB ED
10001A Z-4375-6
AMENDED REPORT
Date Amended
Sample Received:
01/08/99
09/23/98
Original Report Date: 1 1/24/98
ANALYSIS
Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
As
Received
3.26
3.85
46.92
6.76
<0.48 w
0.14
2.53
35.48
34
<180
<1
4.53
10008
Fax Number:
%
%
%
%
%
%
%
%
ppm
ppm
ppm
%
Btu/lb
816-531-0315
Dry
48.65 %
6.60 %
<0.50(e) %
0.15 %
2.62 %
36.79 %
35 ppm
<190 ppm
<1 ppm
4.69 %
10377 Btu/lb
Method
ASTMD-5142
ASTM D-5373
ASTM D-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
9253
ASTMD-3761
EPA SW-846
5050/9056
ASTM D-3869
ASTM D-3 176
ASTM D- 1989
This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 1 of 28
U.S. Mail: P. O. Box 51610 » Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive » Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 • Internet: www.galbraith.com » e-mail: labinfo@galbraith.com
APPENDIX C
77
-------
Galbraith Laboratories, Inc.
— • di '
•^^^^^^H Accuracy with Speed - Since 1 950
KjEniECIIj^H
BlIIIIIIIIIIIIIIM LABORATORY REPORT
David Alburty Report Date:
Midwest Research Institute
I SAMPLE ID LAB ID ANALYSIS
I
10001A Z-4375-6 Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
As
Received
14
<7
<7
<5
10
71
79
14
<7
34
<5
<0.048
<0.048
<0.048
15
160
Lab I.D.:
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
01/08/99
Z-4375-94
Dry
15
<8
<8
<5
10
73
82
15
<8
35
<5
<0.050
<0.050
<0.050
16
160
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
This report shall not be reproduced, except In full, without the written approval of the laboratory
Page 2 of 28
U.S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 » Fax: 423/546-7209 • Internet: www.galbraith.com • e-mail: labinfo@galbraith.com
APPENDIX C
78
-------
Galbraith Laboratories, Inc.
Accuracy with Speed - Since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
Report Date:
Lab I.D.:
01/08/99
Z-4375-94
SAMPLE ID LAB ID
ANALYSIS
As
Received
Dry
Method
10001A
Z-4375-6
Selenium
<7
ppm
<8
ppm
EPA SW-846
3050B/6010
Silver
1.4
ppm
1.4
Sodium
490
ppm
510
Vanadium
<5
ppm
<5
ppm
ppm
ppm
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
Zinc
320
ppm
330
ppm
EPA SW-846
3050B/6010
This report shall not be reproduced, except in full, without the written approval of the laboratory
Page 3 of 28
U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 » Fax: 423/546-7209 • Internet: www.galbraith.com • e-mail: labinfo@galbraith.com
APPENDIX C
79
-------
Galbraith Laboratories, Inc.
Accuracy with Speed - Since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
10002A Z-4377-800 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
Report Date:
Lab I.D.:
As
Received
2.29 %
3.85 %
46.58 %
46.73 %
6.62 %
6.66 %
<0.48(e) %
<0.48 M %
0.059 %
0.058 %
2.65 %
2.67 %
36.54 %
36.75 %
34 ppm
38 ppm
<180 ppm
<180 ppm
<2 ppm
<2 ppm
4.40 %
3.98 %
10115 Btu/lb
9977 Btu/lb
01/08/99
Z-4375-94
Dry
48.06 %
48.21 %
6.48 %
6.52 %
<0.50(e) %
<0.50 (e) %
0.061 %
0.060 %
2.73 %
2.75 %
37.69 %
37.92 %
35 ppm
39 ppm
<190 ppm
<180 ppm
<2 ppm
<2 ppm
4.54 %
4.10 %
10435 Btu/lb
10293 Btu/lb
Method
ASTMD-5142
ASTM D-5373
ASTM D-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
9253
ASTMD-3761
EPA SW-846
5050/9056
ASTM D-3869
ASTM D-3 176
ASTM D- 1989
This report shall not be reproduced, except in full, without tne written approval of the laboratory.
Page 4 of 28
U. S. Mail: P. O. Box 51610 « Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive « Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 . Internet: www.galbraith.com • e-mail: labinfo@galbraith.com
APPENDIX C
80
-------
Galbraith Laboratories, Inc.
"' '"• ^g • "
•••••^^•••^l Accuracy with Speed -Since 1950
mmmmuutiB LABORATORY REPORT
David Alburty Report Date:
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
10002A Z-4377-8 Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
As
Received
11
15
<7
<7
<7
<7
<4
<4
<4
6.00
98
98
99
99
33
33
<7
13
34
42
<4
<4
<0.047
<0.047
<0.050
<0.050
<0.051
<0.048
17
24
0.67
Lab I.D.:
ppm
ppm
ppm
PPm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
PPm
ppm
ppm
ppm
PPm
ppm
ppm
ppm
PPm
ppm
%
01/08/99
Z-4375-94
Dry
12
15
<7
<7
<7
<7
<4
<5
<4
6.00
100
100
100
100
34
34
<7
13
35
43
<4
<5
<0.049
O.048
<0.052
<0.052
<0.053
<0.050
17
25
0.76
PPm
PPm
PPm
PPm
PPm
PPm
PPm
ppm
ppm
PPm
PPm
ppm
ppm
ppm
PPm
PPm
PPm
PPm
PPm
PPm
ppm
PPm
PPm
PPm
ppm
ppm
ppm
ppm
ppm
ppm
%
1 Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 5 of 28
U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 « Internet: www.galbraith.com • e-mail: labinfo@galbraith.com
APPENDIX C
81
-------
Galbraith Laboratories, Inc.
Accuracy with Speed - Since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
Report Date:
Lab I.D.:
01/08/99
Z-4375-94
SAMPLE ID LAB ED
ANALYSIS
As
Received
Dry
Method
10002 A Z-4377-8 Selenium
Silver
Sodium
Vanadium
Zinc
<7
<7
<0.9
<0.9
450
530
<4
<4
280
380
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
<7
<7
<0.9
<0.9
470
550
<4
<5
290
390
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 6 of 28
U. S. Mail: P. O. Box 51610 • Knoxvilie, TN 37950-1610
Other Carriers: 2323 Sycamore Drive • Knoxvilie, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 • Internet: www.galbraith.com • e-mail: labinfo@galbraith.com
APPENDIX C
82
-------
Galbraith Laboratories, Inc.
Accuracy with Speed - Since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID
11001A Z-4379-80
„
ANALYSIS
Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
As
Received
1.86
2.74
13.34
13.49
1.75
1.71
<0.49(e)
<0.49«
0.10
0.10
91.21
92.86
890
350
0.21
0.21
<93
<94
<2
<2
4104
3997
Report Date:
Lab I.D.:
I
%
%
%
%
% (b)
ppm
ppm
%
ppm
ppm
ppm
ppm
(b)
Btu/lb
Btu/lb
01/08/99
Z-4375-94
Dry
13.65 %
13.81 %
1.53 %
1.49 %
<0.50(e) %
<0.50(e) %
0.10 %
0.10 %
93.36 %
95.05 %
900 ppm
360 ppm
0.22 %
0.22 %
<95 ppm
<96 ppm
<2 ppm
<2 ppm
4201 Btu/lb
4091 Btu/lb
Method
ASTMD-5142
ASTM D-5373
ASTM D-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTM D-3869
ASTM D-3 176
ASTM D- 1989
This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 7 of 28
U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 • Internet: www.galbraith.com • e-mail: labinfo@galbraith.com
APPENDIX C
83
-------
Galbraith Laboratories, Inc.
— • ^^J
M555^.j5i!^H Accuracy with Speed - Since 1 950
• m'imiiiiriiiiB LABORATORY REPORT
David Alburty Report Date:
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
11001A Z-4379-80 Aluminum
Antimony
faft'r** ff. 72 -t-y'2 fp'
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
As
Received
140
140
<9
i 35.00
<9
<9
<4
<5
<4
<5
0.64
0.64
9
9
0.18
0.20
<9
<9
0.11
0.11
64
74
<0.049
<0.048
<0.049
<0.049
<0.047
<0.048
7.39
7.77
0.14(f)
0.14(0
Lab I.D.:
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
PPm
ppm
PPm
PPm
ppm
ppm
ppm
ppm
PPm
PPm
ppm
ppm
ppm
ppm
ppm
PPm
o/0(B)
o/0(g)
%
%
01/08/99
Z-4375-94
Dry
140
140
<9
(c) 36.00
<9
<9
<4
<5
<4
<5
0.65
0.66
9
9
0.18
0.21
<9
<9
0.11
0.12
65
75
0.050
O.049
O.050
O.050
O.048
O.049
7.57
7.95
0.14 W
0.14(f)
ppm
ppm
ppm
PPm
PPm
ppm
PPm
ppm
ppm
PPm
ppm
ppm
ppm
PPm
ppm
ppm
ppm
PPm
PPm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
PPm
PPm
o/0(g)
o/0(8)
%
%
1 Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
This report shall not be reproduced, except in full, without the written approval of the laboratory
Page 8 of 28
U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 » Internet: www.galbraith.com « e-mail: labinfo@galbraith.com
APPENDIX C
84
-------
Galbraith Laboratories, Inc.
Accuracy with Speed - Since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID
ANALYSIS As
Received
Report Date:
Lab I.D.:
Dry
01/08/99
Z-4375-94
I! Method
11001 A Z-4379-80 Selenium
Silver
Sodium
Vanadium
Zinc
<9
<9
<0.9
14
140
180
<4
<5
66.69
72.08
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
0/0te)
o/0(g)
<9
<9
<0.9
14
140
190
<4
<5
68.25
73.78
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
o/0(fi)
o/0(g)
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 9 of 28
U.S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 » Internet: www.galbraith.com » e-mail: labinfo@galbraith.com
APPENDIX C
85
-------
Galbraith Laboratories, Inc.
LABORATORY REPORT
Accuracy with speed - Since 1950
David Alburty
Midwest Research Institute
I SAMPLE ID LAB ID ANALYSIS
11 002 A Z-4381-82 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
"'-/""•c Zt
Fluorine .
Bromine
Iodine
Oxygen (by diff)
HHV
Report Date:
Lab I.D.:
As
Received
2.23
1.88
11.90
11.70
1.48
1.49
<0.50 Ce)
<0.50 (e)
0.10
0.11
90.76
94.66
750
550
240
280
<94
<95
7
7
3964
3786
%
%
%
%
/Q
/O
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Btu/lb
Btu/lb
Dry
12.15
11.95
1.28
1.29
0.51 w
0.51 (e)
0.10
0.11
(b) 92.66
96.65
760
560
240
280
<96
<97
7
7
(b)
4047
3865
01/08/99
Z-4375-94
/Q
/O
/O
/O
/O
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Btu/lb
Btu/lb
I! Method
ASTMD-5142
ASTM D-5373
ASTM D-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTM D-3761
EPA SW-846
5050/9056
ASTM D-3869
ASTM D-3 176
ASTM D- 1989
This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 10 of 28
U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive • Knoxville TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 • Internet: www.galbraith.com . e-mail: labinfo@galbraith.com
APPENDIX C
86
-------
Galbraith Laboratories, Inc.
— • di —
B£"!^ZZz"J|IH Accuracy with Speed - Since 1950
•mimiiimiiM LABORATORY REPORT
David Alburty Report Date:
Midwest Research Institute
SAMPLE ID LAB ED ANALYSIS
11002A Z-4381-82 Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
As
Received
100
99
<10
<10
<10
<10
<5
<5
<5
<5
0.66
0.65
8
7
550
540
<10
<10
0.12
0.11
19
19
<0.048
<0.047
<0.049
<0.049
<0.049
<0.049
111
7.75
0.14
0.13
Lab I.D.:
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%to
0/0(s)
%
01/08/99
Z-4375-94
Dry
110
100
<10
<10
<10
<10
<5
<5
<5
<5
0.67
0.66
8
7
560
550
<10
<10
0.12
0.11
20
19
<0.049
<0.048
<0.050
<0.050
<0.050
<0.050
7.93
7.91
0.14
0.14
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%(•>
o/0GO
%
Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
This report shall not be reproduced, except in lull, without the wntten approval of the laboratory.
Page 11 of 28
U. S. Mail: P, O. Box 51610 • Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive « Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 « Internet: www.galbraith.com • e-mail: labinfo@galbraith.com
APPENDIX C
87
-------
Galbraith Laboratories, Inc.
Accuracy with Speed - Since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
Report Date:
Lab I.D.:
01/08/99
Z-4375-94
SAMPLE ID LAB ID
ANALYSIS
As
Received
Dry
Method
11002A Z-4381-82 Selenium
Silver
Sodium
Vanadium
Zinc
<10
<10
<1
<1
191
163
<5
<5
70.77
72.28
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
o/0(g)
o/000
<10
<10
<1
<1
195
166
<5
<5
72.25
73.79
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%w
0/0(g)
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 12 of 28
U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 • Internet: www.galbraith.com • e-mail: labinfo@galbraith.com
APPENDIX C
88
-------
Galbraith Laboratories, Inc.
Accuracy with Speed -Since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
11001C Z-4383-84 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine "
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
As
Received
7.40
8.10
57.60
57.63
9.50
9.85
3.82
3.85
0.41
0.42
0.34
0.18
310
350
-------
Galbraith Laboratories, Inc.
_^_ I
•S^^^^^^B Accuracy with Speed - Since 1 950
j^AmjjLLm
B LABORATORY REPORT
David Alburty Report Date:
Midwest Research Institute
I SAMPLE ID LAB ED ANALYSIS
11001C Z-4383-84 Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
As
Received
79
130
<8
<9
<8
<9
<4
<4
<4
<4
<4
<4
<4
<4
55
88
<8
<9
14
16
<4
<4
O.046
<0.045
<0.046
<0.044
<0.045
O.044
15
4
43
55
Lab I.D.:
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
01/08/99
Z-4375-94
Dry
86
142
<9
<9
<9
<9
<5
<5
<5
<5
<5
<5
<5
<5
60
95
<9
<9
15
18
<5
<5
<0.050
<0.049
<0.050
<0.048
<0.049
<0.048
17
5
46
38
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 14 of 28
U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 • Internet: www.galbraith.com • e-mail: labinfo@galbraith.com
APPENDIX C
90
-------
Galbraith Laboratories, Inc.
Accuracy with Speed - Since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
Report Date:
Lab I.D.:
01/08/99
Z-4375-94
SAMPLE ED LAB ED
ANALYSIS
As
Received
Dry
Method
11001C
Z-4383-84
Selenium
<8
<9
ppm
ppm
<9
<9
ppm
ppm
EPA SW-846
3050B/6010
Silver
ppm
ppm
ppm
ppm
EPA SW-846
3050B/6010
Sodium
130
150
ppm
PPm
150
170
ppm
PPm
EPA SW-846
3050B/6010
Vanadium
<4
<4
ppm
PPm
<5
<5
ppm
ppm
EPA SW-846
3050B/6010
Zinc
130
30
PPm
ppm
140
32
ppm
PPm
EPA SW-846
3050B/6010
This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 15 of 28
U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive » Knoxville, TN 37921-1750
Tel: 423/546-1335 « Fax: 423/546-7209 • Internet: www.galbraith.com • e-mail: labinto@galbraith.com
APPENDIX C
91
-------
Galbraith Laboratories, Inc.
Accuracy with Speed - Since 1 950
LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
11002C Z-4385-86 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
_ Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
As
Received
6.65
7.36
58.44
58.50
9.63
9.94
5.31
5.57
0.20
0.22
0.69
0.52
160
140
<\l
<94
<94
<2
<2
19.49
19.02
12024
11840
Report Date:
Lab I.D.:
°/°
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
Btu/lb
Btu/lb
01/08/99
Z-4375-94
Dry
62.84
62.91
9.52
9.85
5.71
5.99
0.22
0.24
0.74
0.56
180
150
<17
<100
<100
<2
<2
20.96
20.45
12930
12732
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
Btu/lb
Btu/lb
1 Method
ASTMD-5142
ASTM D-5373
ASTM D-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTM D-3869
ASTM D-3 176
ASTM D-1989
This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 16 of 28
U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 . Internet: www.galbraith.com • e-mail: labmfo@galbraith.com
APPENDIX C
92
-------
Galbraith Laboratories, Inc.
A»-*^AI LABORATORY REPORT
•S-TTTTTTTTTT^B Accuracy with Speed - Since 1 950
^^^^^^^^^^^TQ^^^^^^^^I
David Alburty Report Date:
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
11002C Z^1385-86 Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
As
Received
130
130
<9
<9
<9
<9
<5
<5
<5
<5
<5
<5
<5
<5
86
130
<9
<9
63
75
10
13
<0.046
O.045
<0.046
<0.046
<0.044
<0.046
7
<5
370
460
Lab I.D.:
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
01/08/99
•^^^^m^mmmmm
Z-4375-94
Dry
144
141
<10
<10
<10
<10
<5
<5
<5
<5
<5
<5
<5
<5
92
140
<10
<10
68
81
11
14
<0.049
<0.048
<0.049
O.049
<0.047
<0.049
8
<5
400
490
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Ppm
Ppm
Ppm
ppm
ppm
ppm
ppm
ppm
ppm
Ppm
Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
This report shall not be reproduced, except in full, without the written approval of the laboratory
Page 17 of 28
U. S. Mail: P. O. Box 51610 » Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 • Internet: www.galbraith.com « e-mail: labinfo@galbraith.com
APPENDIX C
93
-------
Galbraith Laboratories, Inc.
Accuracy with Speed - Since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
Report Date:
Lab I.D.:
01/08/99
Z-4375-94
SAMPLE ID LAB ID
ANALYSIS
As
Received
Dry
Method
11002C Z-4385-86 Selenium
Silver
Sodium
Vanadium
Zinc
<9
<9
<1
<1
140
120
<5
<5
51
25
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
<10
<10
<1
<1
160
120
<5
<5
55
27
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 18 of 28
U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 • Internet: www.galbraith.com • e-mail: labinfo@galbraith.com
APPENDIX C
94
-------
Galbraith Laboratories, Inc.
&_*^AI LABORATORY REPORT
fS^f^jSS^M Accuracy with Speed - Since 1 950
David Alburty Report Date:
Midwest Research Institute
SAMPLE ID LAB H) ANALYSIS
11003B Z-4387-88 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
Lab I.D.:
As
Received
10.71 %
12.86 %
59.47 %
59.32 %
8.27 %
8.32 %
4.62 %
4.65 %
0.14 %
0.15 %
0.11 %
0.08 %
<88 ppm
<95 ppm
17 ppm
16 ppm
<88 ppm
<95 ppm
6 ppm
3 ppm
16.91 %
16.99 %
11716 Btu/lb
11392 Btu/lb
Dry
67.41
67.25
7:89
7.95
5.24
5.27
0.16
0.17
0.12
0.09
<100
<110
19
18
<100
<110
6
3
19.17
19.26
13281
12914
01/08/99
Z-4375-94
I! Method
ASTMD-5142
% ASTM D-5373
%
% ASTM D-5373
%
% ASTM D-5373
%
% ASTM D-4239
%
% ASTMD-5142
%
ppm EPA SW-846
ppm 5050/9056
ppm ASTMD-3761
ppm
ppm EPA SW-846
ppm 5050/9056
ppm ASTM D-3869
ppm
% ASTM D-3 176
%
Btu/lb ASTM D- 1989
Btu/lb
This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 19 of 28
U. S. Mail: P, O. Box 51610 • Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 • Internet: www.galbraith.com • e-mail: labinfo@galbraith.com
APPENDIX C
95
-------
Galbraith Laboratories, Inc.
^L^^mM LABORATORY REPORT"
•5*;i~_"5^H Accuracy with Speed - Since 1 950
•*TiU:l:n77T^B
David Alburty Report Date:
Midwest Research Institute Lab I.D.:
I SAMPLE ID LAB ID ANALYSIS
11003B Z-4387-88 Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
As
Received
6
6
<7
<7
<7
<7
<5
<4
<5
<4
<5
<4
<5
<4
6
6
<7
<7
5
<5
<5
<4
<0.047
<0.048
<0.046
<0.048
<0.047
<0.046
<5
<4
<7
<7
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Dry
7
7
<8
<7
<8
<7
<5
<5
<5
<5
<5
<5
<5
<5
7
7
<8
<7
5
<5
<5
<5
<0.053
<0.053
<0.052
<0.054
<0.053
<0.052
<5
<5
<8
<7
01/08/99
Z-4375-94
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Ppm
Ppm
Ppm
ppm
ppm
ppm
Ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Ppm
Ppm
ppm
ppm
ppm
ppm
Ppm
1 Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 20 of 28
U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 • Internet: www.galbraith.com • e-mail: labinfo@galbraith.com
APPENDIX C
96
-------
Galbraith Laboratories, Inc.
^t_*^^H LABORATORY REPORT
•?Trr7!SJ Accuracy with Speecf- Since 1 950
David Alburty Report Date:
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
11004B Z-4389-90 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
Lab I.D.:
As
Received
9.73 %
11.49 %
57.63 %
57.50 %
8.32 %
8.28 %
4.87 %
4.84 %
0.21 %
0.21 %
0.12 %
0.08 %
530 ppm
260 ppm
<9 ppm
36 ppm
<93 ppm
<93 ppm
3 ppm
4 ppm
19.36 %
19.63 %
11116 Btu/lb
11008 Btu/lb
01/08/99
Z-4375-94
Dry
64.47
64.32
7.99
7.94
5.45
5.42
0.24
0.24
0.13
0.09
590
290
<10
41
<100
<100
3
4
21.66
21.96
12435
12315
/O
/O
/O
/O
%
%
p/
%
o/
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
I! Method
ASTMD-5142
ASTM D-5373
ASTM D-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTM D-3869
ASTM D-3 176
ASTM D- 1989
This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 22 of 28
U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 • Internet: www.galbraith.com « e-mail: labinfo@galbraith.com
APPENDIX C
98
-------
Galbraith Laboratories, Inc.
Accuracy with Speed - Since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
Report Date:
Lab I.D.:
01/08/99
Z-4375-94
SAMPLE ID LAB ID
ANALYSIS
As
Received
Dry
Method
11003B Z-4387-88 Selenium
Silver
Sodium
Vanadium
Zinc
<7
<7
<1
<1
130
120
<5
<4
<5
<4
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
<8
<7
<1
<1
150
130
<5
<5
<5
<5
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
This report shall not be reproduced, except in full, without the wntten approval of the laboratory.
Page 21 of 28
U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
TPI- a^/^K i«= °'herCarriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel. 423/546-1335 • Fax: 423/546-7209 • Internet: www.galbraith.com . e-mail: labinfo@galbraith.com
APPENDIX C
97
-------
Galbraith Laboratories, Inc.
LABORATORY REPORT
Accuracy with Speed - Since 1
1950
David Alburty
Midwest Research Institute
Report Date:
Lab I.D.:
01/08/99
Z-4375-94
SAMPLE ED LAB ED
ANALYSIS
As
Received
Dry
Method
11004B Z-4389-90 Selenium
Silver
Sodium
Vanadium
Zinc
<7
<6
<1
<1
130
140
<4
<4
7
7
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
<8
<7
<1
<1
141
151
<5
<4
8
8
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
This report shall not be reproduced, except In full, without the written approval of the laboratory.
Page 24 of 28
U. S. Mail: P. O. Box 51610 « Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 • Internet: www.galbraith.com • e-mail: labinfo@galbraith.com
APPENDIX C
100
-------
Galbraith Laboratories, Inc.
BSt^C355^B Accuracy with Speed - Since 1 950
•HHafiSB LABORATORY REPORT
David Alburty Report Date:
Midwest Research Institute
I SAMPLE ID LAB ID ANALYSIS
I
11004B Z-43 89-90 Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
As
Received
7
7
<7
<6
<7
<6
<4
<4
<4
<4
<4
<4
<4
<4
9
10
<7
<6
7
9
<4
<4
O.045
<0.043
<0.046
<0.046
<0.046
<0.046
<4
<4
7
6
Lab I.D.:
ppm
ppm
ppm
ppm
ppm
ppm
PPm
ppm
ppm
PPm
ppm
ppm
PPm
ppm
ppm
ppm
PPm
ppm
ppm
ppm
PPm
PPm
ppm
ppm
PPm
ppm
ppm
PPm
ppm
PPm
PPm
ppm
01/08/99
Z-4375-94
Dry
8
8
<8
<7
<8
<7
<5
<4
<5
<4
<5
<4
<5
<4
10
12
<8
<7
8
11
<5
<4
<0.050
<0.048
O.052
<0.052
<0.052
<0.052
<5
<4
8
7
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
PPm
ppm
ppm
ppm
ppm
ppm
PPm
ppm
ppm
PPm
PPm
PPm
ppm
ppm
PPm
ppm
ppm
PPm
Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 23 of 28
Tel: 423/546-1335
U. S. Mail: P. O. Box 51610 » Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
« Fax: 423/546-7209 • Internet: www.galbraith.com « e-mail: labinfo@galbraith.com
APPENDIX C
-------
Galbraith Laboratories, Inc.
A^^^M LABORATORY REPORT
•CSTTTTTTrS^B Accuracy with Speed - Since 1 950
^^^^^^^Q2V"MJ£fj^^^^^^l
David Alburty Report Date:
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
10001B Z-4391-92 Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
As
Received
13
13
<7
<7
<7
<7
<5
<4
<5
<4
150
160
130
140
19
19
<7
<7
44
41
<5
<4
<0.045
O.046
<0.046
26
28
220
240
Lab I.D.:
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
01/08/99
Z-4375-94
Dry
13
14
<8
<8
<8
<8
<5
<5
<5
<5
160
160
140
140
20
20
<8
<8
46
43
<5
<5
(d) <0.048
<0.048
<0.048
27
29
240
260
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 26 of 28
U. S. Mail: P. O. Box 51610 « Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 • Internet: www.galbraith.com « e-mail: labinfo@galbraith.com
APPENDIX C
1O2
-------
Galbraith Laboratories, Inc.
LABORATORY REPORT „
Accuracy with Speea - Since 1950
David Alburty
Midwest Research Institute
SAMPLE DD LAB ID ANALYSIS
1000 IB Z-4391-92 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
As
Received
5.42
4.16
44.65
44.54
6.58
6.45
<0.48
<0.48
0.15
0.10
2.51
2.65
34.70
34.57
140
120
<96
<96
11
9
37.90
38.06
9727
9251
Report Date:
Lab I.D.:
%
%
%
%
%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
Dry
46.90
46.78
6.35
6.22
<0.50
<0.50
0.16
0.11
2.64
2.78
36.44
36.31
150
130
<100
<100
12
9
39.81
39.98
10216
9716
01/08/99
Z-4375-94
%
%
%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
Method
ASTMD-5142
ASTM D-5373
ASTM D-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
9253
ASTM D-3761
EPA SW-846
5050/9056
ASTM D-3869
ASTM D-3 176
ASTMD-1989
This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 25 of 28
nth UrS'Mail: R0- Box 51610 » Knoxville, TN 37950-1610
Tel: 423/546-1335 .^.C^^S^tTO>r8DrlVe ' Kn°XVille-TN ^ 175°
rax. 423/546-7209 . Internet: www.galbraith.com . e-mail: labinfo@galbraith.com
APPENDIX C
101
-------
Galbraith Laboratories, Inc.
LABORATORY REPORT
Accuracy with Speed - Since 1
iCcuracy with Speed - Since 1950
David Alburty Report Date: 01/08/98
Midwest Research Institute Labl.D.: Z-4375-92
Preparation Confirmation
As requested, Lab ID#'s Z-4375-92 were refrigerated prior to analysis. The samples were also dried and ground, unless otherwise noted,
prior to analysis to provide a more homogeneous sample for testing.
Note
The original Chain of Custody form is included with the mailed report.
Technical Note
(a) As we discussed, Lab ID#s Z-4377-78 (Sample 10002A) were analysed in duplicate due to stannous chloride contamination of Lab ID#
Z-4393-94 (Sample 10002B) prior to grinding.
*' As we discussed, these ash results exhibit a potential high bias due to the high levels of zinc and nickel in the sample. During the ashinig
of the sample metal oxides form which result in high ash values. This also effects the oxygen result since it is a calculated value.
(c) The antimony replicate for this sample seems out of line with the sample trend; however, the concentration was confirmed on two
wavelengths.
(d) The digested solutions for this sample were diluted prior to analysis for mercury due to interferences in other samples in the set. This
results in elevated quantitation limits for mercury in this sample. The aliquots used for the mercury determination was taken from the field
duplicate (Sample 10001 A, Lab ID #Z-4375-76) due to the insufficient sample remaining on Sample 10001B.
w Our original laboratory report was sent without the appropriate less than symbolism for the nitrogen results. We apologize for any
inconvenience our error may have caused.
m The original laboratory report indicated potassium results of 0.67% (as received) and 0.76% (on dry). The correct values have been
included in this report. We apologize for any inconvenience this error may have caused.
^ The original laboratory report indicated ppm units on these results. The correct units are % as reflected in this report. We apologize for
any inconvenience this error may have caused.
PAC:yd TWs report shall not be reproduced, except in full, wilhout the written approval of the laboratory. Page 28 of 28
U. S. Mail: P. O. Box 51610 « Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 » Fax: 423/546-7209 « Internet: www.galbraith.com • e-mail: labinfo@galbraith.com
APPENDIX C 1O4
-------
Galbraith Laboratories, Inc
Accuracy with Speed - Since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
Report Date:
Lab I.D.:
01/08/99
Z-4375-94
SAMPLE ID LAB ED
ANALYSIS
As
Received
Dry
Method
10001B
Z-4391-92
Selenium
<7
<7
ppm
PPm
<8
<8
ppm
PPm
EPA SW-846
3050B/6010
Silver
ppm
PPm
ppm
PPm
EPA SW-846
3050B/6010
Sodium
450
450
ppm
ppm
480
480
ppm
ppm
EPA SW-846
3050B/6010
Vanadium
<5
<4
ppm
ppm
<5
<5
ppm
PPm
EPA SW-846
3050B/6010
Zinc
320
250
ppm
ppm
340
260
ppm
ppm
EPA SW-846
3050B/6010
This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 27 of 28
U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 • Internet: www.galbraith.com • e-mail: labinfo@galbraith.com
A DDCMftT V I"!
-------
Galbraith Laboratories, Inc
Accuracy with Speed - Since 1950
LABORATORY REPORT
David Alburty Report Date: 1/13/99
Midwest Research Institute Lab I.D.: A-5601
Technical Notes
As requested, Sample ID#11001A was refrigerated at 4°C prior to analysis.
Analysis was performed on the dried and ground sample.
One replicate of the original sample appears to have been contaminated with silver during preparation. These results indicate the
absence of silver in the sample. There is no charge for this repeat analysis.
PAClSmC This report shall not be reproduced, except in full, without the written approval of the laboratory. Page 2 01 2
U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 » Fax: 423/546-7209 • Internet: www.galbraith.com • e-mail: labinfo@galbraith.com
APPENDIX C 1O6
-------
Galbraith Laboratories, Inc.
Accuracy with Speed - Since 1950
LABORATORY REPORT
David Alburty
Midwest Research Institute
425 Volker Blvd
Kansas City MO 64110-2299
Additional Request:
Previous Lab I.D.:
Report Date:
Fax Number:
1/11/99
A-4361
01/13/99
816-531-0315
SAMPLE ID
LAB ID ANALYSIS
RESULT(S)
11001A Add
A-5601 Silver
< 2
< 2
ppm
ppm
C9
This report shall not be reproduced, except in full, without the written approval of the laboratory.
U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
lei: 423/546-1335 • Fax: 423/546-7209 . Internet: www.galbraith.com • e-mail: labinfo@galbraith.com
APPENDIX C
105
-------
Reference Material Result (% of Value)
Applicable to Samples
Z-391 7 through Z-3928
Z-5356 through Z-5367
Z-3474 through Z-3479
Z-3479, Z-3474, Z-3277
Z-5069, Z-5070
Z-3778 through Z-3787
Z-4550 through Z-4553
Z-4375 through Z-4394
HHV
100%
100%
100%
102%
100%
100%
100%
100%
Ash
101%
100%
95%
95%
101%
101%
100%
Viscosity SpGr
16.63/(?)% 100%
Applicable to Samples
Matrix Spikes for Halides
Bromine Chlorine Fluorine Iodine
Z-3917 through Z-3928
Z-5356 through Z-5367
Z-3474 through Z-3479
Z-3479, Z-3474, Z-3277
Z-5069, Z-5070
Z-3778 through Z-3787
Z-4550 through Z-4553
Z-4375 through Z-4394
89%
89%
94%
23%
80%
85%
Controls for Halides
Applicable to Samples
Bromine Chlorine Fluorine Iodine
Z-391 7 through
Z-5356 through
Z-3474 through
Z-3479, Z-3474
Z-5069, Z-5070
Z-3778 through
Z-3782, Z-3783
Z-4550 through
Z-4375 through
Z-4376
A-2183, A-2186
A-4365
Z-3928
Z-5367
Z-3479
, Z-3277
Z-3787
Z-4553
Z-4394
, A-4201 - A-4207
75%
82%
83%
82%
>70%
53%
82%
87%
18%
62-92%
101%
93%
95%
101%
>70%
79%
>70%
82%
98-104%
101%
102%
96%
96%
96%
96%
96%
101%
280%
274%
276%
274%
276%
274%
274%
APPENDIX C
1O8
-------
Controls for Metals
Applicable to Samples
Ag Al As Be Cd Cr Cu Fe Hg K Mg Mn Na
Ni
Pb Sb Se
Zn
Z-3917 through Z-3928
Z-5356 through Z-5367
Z-3474 through Z-3479
Z-3479, Z-3474, Z-3277
Z-5069, Z-5070
Z-3778 through Z-3787
Z-4550 through Z-4553
Z-4375 through Z-4394
A-2183, A-2186, A-4201
A-5601
A-4365
97% 101% 99% 99% 99% 99% 101% 102% 100% 101% 100% 100% 100% 99% 99% 99% 98%
94% 97% 101% 98% 99% 98% 98% 91% 107% 91% 95% 95% 498% 95% 97% 97% 96% 95% 94%
94% 97% 101% 98% 99% 98% 98% 91% 99% 92% 95% 95% 100% 95% 97% 97% 96% 95% 94%
83%
97% 101% 99% 99% 99% 99% 101% 99% 103% 100% 100% 101% 100% 100% 100% 99% 99% 99% 98%
99% 97% 98% 98% 98% 100% 98% 98% 96% 100% 99% 99% 99% 99% 100% 98% 98% 98%
97% 99% 97% 98% 98% 98% 100% 101% 96% 100% 99% 99% 99% 99% 100% 98% 98% 98%
•A-4207 104% 98% 99% 97% 99% 96% 97% 94% 100% 98% 93% 97% 101% 96% 100% 98% 99% 95% 97%
80%
94%
•o
TJ
m
z
o
M
X
o
Matrix Spikes for Metals
Applicable to Samples
Ag Al
As
Be Cd Cr Cu Fe Hg'
K
Mg Mn Na
Ni
Pb Sb Se
Zn
Z-391 7 through Z-3928 (MS)
Z-391 7 through Z-3928 (MSD)
RPD
Z-5356 through Z-5367
Z-3474 through Z-3479
Z-3479, Z-3474, Z-3277
Z-5069, Z-5070
Z-3778 through Z-3787
Z-4550 through Z-4553 (MS)
Z-4550 through Z-4553 (MSD)
RPD
81%
82%
1%
18%
43%
81%
74%
78%
5%
91%
97%
6%
90%
92%
2%
90%
92%
2%
88%
89%
1%
78%
79%
1%
87%
88%
1%
86%
88%
2%
89%
90%
1%
94%
98%
5%
94%
95%
1%
88%
105%
18%
104%
109%
5%
109%
102%
103%
110%
102%
91%
94%
2%
90%
92%
2%
90%
110%
20%
88%
89%
1%
90%
92%
2%
89%
90%
2%
89%
89%
0%
77% 94%
77% 96%
1% 3%
83% 92%
88% 94%
6% 2%
89% 85%
92% 93%
3% 9%
86% 104%
88% 101%
2% 3%
Z-4375 through Z-4394
109%
' Multiple spikes were performed for Hg, did not show all here.
-------
Appendix D
MRI Analysis Reports
MRJ-AEDW951 -01 -02-OSTR. wpd
-------
Appendix D-1
Organic Analysis
(Ds/Fs and PAHs)
MRl-A£DV4951-01-02-05TR.wpd
-------
To: John Hosenfeld
From: Kathy Boggess
Subject: EMC Alternative Boiler Fuel Sludge Samples
This memo contains a brief description of the sample preparation procedures and the results of the two
sludge samples (prepared in duplicate) submitted for PAH and dioxin and furan analysis. The sample IDS
are 1005 and 1006.
PAHs
The samples were a dark brown viscous material that were un pourable at room temperature. With
warming, the samples were liquefied enough to aliquot with a disposable serological pipet. At this point,
the material was stringy, must like a thick molasses material. The analyst attempted to weigh a Ig aliquot
of each sample in duplicate into a 40-mL vial. In some cases, the sample size was closer to 2 g.
The 1-g samples were fortified with 25-ug dlo fluorene and dlo pryene as surrogates to assess the affect of
the matrix on cleanup and GC/MS analysis. Other quality control samples included a solvent only method
blank, a com oil laboratory control blank and a com oil laboratory control spiked sample fortified with 5 ug
of the target PAHs.
The ~ 1 g samples and QC samples were diluted with methylene chloride and put through size exclusion
gel permeation chromatography (GPC) cleanup using a column packed with SX-3 biobeads. The system
was calibrated with com oil and a standard mixture containing a phthalate, methoxychlor, perylene, and
sulfur. The collect fraction was set to isolate the PAHs from the com oil calibration standard. A UV
detector was interfaced to the automated GPC cleanup to monitor response for potential interferences
during collection of the fraction designated for analysis. The UV trace indicated incomplete removal of the
matrix. The molecular weight of the major contaminants were lighter than the com oil used for calibration
of the instrument, and the UV showed that these interferences overlapped in the same fraction as the target
analytes. Therefore, a serial GPC cleanup was performed to reduce the oil interferences. The GPC
cleanup removed the dark color of the samples, and the final extracts were a light amber color. The
dilution factor of the extracts for GC/MS analysis was 10 mL methylene chloride for each 1 g sample.
The sample extracts and quality control samples were analyzed according to modifications of EPA Method
8270. The modifications included a lower calibration range than required by the method and the use of
dueterium labeled PAHs as surrogates. The internal standard recommended in EPA Method 8270 was
added to a 1.0 mL aliquot of the extracts just before analysis.
Results
None of the samples contained PAHs above instrumental reporting limit based on the lowest calibration
standard (0.1 ug/mL). The sample detection limit was 4 ug g/g based on the sample size and dilution
factor. Table 1 summarizes the target PAHs and sample results.
The quality control results were within the acceptable limits. The two surrogates recovered within the 60 to
120% recovery objective as shown in Table 2. Recoveries of the native PAHs from the com oil laboratory
control sample, which was subjected to the same GPC cleanup, and analysis are shown in Table 3.
Recoveries were good with the exception of the latest eluting compound, benzo (g,h,i) perylene.
-------
Table 1. PAH Sample Results (ug/g)
PAH
1005
1006 1006 dup
Nitrobenzene
Naphthalene
Acenaphthylene
Acenapthene
Flourene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benz(a) anthracene
Chrysene
Benzo(b) fluoranthene
Benzo (k) fluoranthene
Benzo (e) pyrene
Indeno (1,2,3-cd) pyrene
Dibenz (a,h) anthracene
Benzo (g,h,I) perylene
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
Table 2. Surrogate Recoveries %
Sample
Solvent Blank
Com Oil Method Blank
Com Oil LCS
1005
1005 dup
1006
1006 dup
dlO Fluorene
90
62
90
103
96
105
105
dlO Pvrene
68
64
73
78
68
77
73
Table 3. Com oil LCS Recoveries
PAH
Nitrobenzene
Naphthalene
Acenaphthylene
Acenapthene
Flourene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benz(a) anthracene
Chrysene
Benzo(b) fluoranthene
Benzo (k) fluoranthene
Benzo (e) pyrene
Benzo (a) pyrene
Indeno (1,2,3-cd) pyrene
Dibenz (a,h) anthracene
Benzo (g,h,I) perylene
Spike Level ug
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
% Recovery
100
93.8
104
101
100
96.8
97.4
78.6
76
76
78.2
80
69.6
74.4
75.8
64.8
64.2
45.6
APPENDIX D-T
-------
PCDDs/PCDFs
The PCDD and PCDF analyses were performed according to EPA Method 8290. Initially a 10 g sample
size was spiked with the 13C12 PCDDs/PCDFs IQS , diluted in hexane and put through an acidified silica
slurry cleanup procedure. This oily matrix overloaded the silica cleanup, requiring the addition of more
acid silica. Then the samples were processed through carbon and neutral alumina cleanup as described in
Method 8290 and analyzed by HRGC/HRMS. Preliminary results indicated low recovery for the lower
chorinated 13C12 IQS. Therefore the preparation was repeated with I g sample size to reduce the matrix
effect on the cleanup procedures.
Results
The results from the repeated analysis will be available on Wednesday. Mark Davis will forward tables to
you. If you are interested in the results from the JO g sample as well, the data have been put in the 4951
project folder on the network.
APPFNDTX o-i
-------
PCDD/F Narrative
MIDWEST RESEARCH INSTITUTE
November 25, 1998
To: John Hosenfeld
From: Mark Davis
Subject: Analysis Narrative for EMC Pine Tar Samples
Sample Preparation
Samples were heated and weighed out in duplicate in two weight groups (10 grams and 1
gram) for dioxin/furan analysis. A mineral oil method blank (MB), a mineral oil laboratory
control sample (LCS), and a solvent blank were also prepared for both weight groups. All
samples were fortified with appropriate quantitation standards. The 1 -gram samples were
archived (to be used if the matrix of the 10-gram samples proved to be too difficult). The ten
gram samples were diluted in hexane, fortified with 37C1-2378 TCDD clean-up standard and
subjected to a 2 hour acid silica slurry step (40% H2SO4 on silica gel) followed by a acid/neutral
silica column. Heavy reactions with both the slurry and column steps were noted. The extract
was then concentrated for carbon column clean up. It was discovered that mineral oil used for
the MB and LCS was not sufficiently cleaned in the silica steps and would not successfully go
through the rest of the clean-up procedures. The MB and the LCS were re-prepared using com
oil for both weight groups. The solvent blank originally started with the samples remained the
same. The re-prepared LCS and Method Blank were put through the same silica steps and
continued through a .5 gram 18% Carbopack C carbon column, and a neutral alumina column
with the rest of the samples. All samples were concentrated under prepurified nitrogen to
approximately 100 uL. 20 uL of recovery standard was added and evaporation continued to a
final volume of 20 uL. All procedures are documented in detail in SOP MRI-5201 revision 1.
After analysis of the 10-gram sample, it was decided that the 1-gram samples should be
analyzed to reduce matrix effects. The 1 - gram samples were prepared with the corn oil MB and
LCS in the same manner discussed above.
Sample Analysis
Analysis was performed on the VG70-250s mass spectrometer at 10,000 resolution
interfaced with a HP5890 gas chromatograph. A 60m DB-5ms (0.25mm ID, 0.25um film) fused
silica capillary column was used for chromatographic separation. The samples were analyzed
following the requirements in SOP MPJ-5405 USEPA Method 8290. An initial calibration of 5
points ranging from 0.5-200pg/uL, and an ending standard were run in the analytical sequence.
The initial and daily calibrations, instrument resolution and GC column performance met the
criteria specified in the SOP. Analysis records of performance and raw data have been included
in the data package.
Data Reduction
The data was reduced using the Excalibur 2.1 program. The initial calibration was used to
generate relative response factors for sample quantitation. USEPA Method 8290 quantitation was
followed to quantitate native concentrations with one exception. After looking over the sample
raw data, it was noticed that the 13C-123789HxCDF recovered extremely well. In method 8290,
this is not the labeled analog used for native quantitation. A deviation from the method was
performed to quantitate the native 123789HxCDF from its own labeled analog which gave much
better results for that isomer. The initial calibration curve was re-generated to produce the new
APPENDIX 0-1
-------
response factor. Excaiibur output files and a spreadsheet showing final concentrations has been
included in the data package.
The one gram sample data is a better data set due to the significantly better labeled analog
recovery. Both data sets for 10 and 1 gram samples are included.
APPENDIX D-1
-------
Table 1. Native Results for 1 gram Samples (pg/g)
•o
•o
,n
z
0
H
X
Isomer
2378TCDD
12378PECDD
123478HXCDD
123678HXCDD
123789HXCDD
1234678HPCDD
123467890CDD
2378TCDF(a)
12378PECDF
23478PECDF
123478HXCDF
123678HXCDF
234678HXCDF
123789HXCDF
1234678HPCDF
1234789HPCDF
123467890CDF
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Field ID corn oil
Extract ID 41040
MS File K24V12RPT
Matrix Method Blank
U( 3.57)
U( 3.95)
U( 3.92)
U( 3.76)
U( 3.63)
11.3
115
U(2.16)
U(2.5)
U(2.1)
U( 3.62)
5.26
U(4.21)
U( 9.68 EMPC)
5.51
U( 5.02 EMPC)
14.9
U( 3.57)
U( 2.42)
U( 3 77)
18.3
U(2.16)
U( 2.27)
5.4
9.71
None
41039
K24V18.RPT
Solvent Blank
U( 2.54)
U( 4.02)
U(2.91)
U{ 2.78)
U( 2.69)
U( 6.06 EMPC)
51.3
U(1.75)
U( 1.88)
U(1.59)
U(1.12)
U(2.11 EMPC)
U( 1.7 EMPC)
U( 5.82 EMPC)
U(1.51)
U( 1.67)
5.66
U( 2.54)
U( 1.86)
U( 2.79)
63
U( 1.75)
U(1.71)
U(1.11)
U( .74)
1005 A
41035
K24V14.RPT
oil
U(8.13)
U( 18.3)
U( 24.9 EMPC)
U( 24 EMPC)
72.4 (J)
632
4430
U(812)
U(5.18)
U(4.37)
U( 10.7)
U(104)
U( 24 EMPC)
4.31
10.8
U( 5.04 )
9.28
U(813)
U(11.5)
118(J)
989
U(8.12)
U(4.7)
49.5
17.2
1005ADup
41036
K24V15.RPT
oil
U( 5.43JJ
U( 6.94)J
U( 8.43)
U( 15 3 EMPC)
30.7
639
4600
U( 8.44JJ
U( 3.87)
U( 3.26)
l)( 3.8)
U(4.19)
U( 8 96 EMPC)
U( 7.02 EMPC)
10.5
U(311)
13
U(5.43)
U( 3.53)J
31.9
1080
U( 8.44)J
U( 3.52)
U( 3.77)
11
1006A
41037
K24V16.RPT
oil
U( 2.02)
U( 4.2)
U( 4.73 EMPC)
14.4
U( 25.7 EMPC)
610
4430
U( 2.24)
U{1.43)
U(1.21)
U( 3.28)
U(3.17)
U( 3.49)
5.49
8.21
U{ 5.47 EMPC)
667
U( 2.02)
U( 2.37)
56.3
1030
U( 2.24)
U(1.3)
5.49
14.3
1006ADup
41038
K24V17.RPT
oil
U(1.67)
U( 3.04)
U( 4.07 EMPC)
11.9
U( 12.9 EMPC)
614
4480
U( .906)
U(1.34)
U(1.13)
U( .894)
U( 1.33 EMPC)
3.24
3.79
5.36
U( .949)
9.13
U(1.67)
U(1.57)
51.5
995
U( .906)
U(1.22)
7.5
11.6
U - Undetected at the noise based detection limit
EMPC - A peak was detected that did not meet the identification criteria.
The peak areas were used to calculate an Estimated Maximum
Possible Concentration for the detection limit
J • Corresponding labeled analog outside of the MRI criteria of 25-150%.
a - Concentrations for this isomer should be consider a maximum.
The GC column used is not specific for this isomer.
-------
Table 2. Labeled Analog Results 1 gram Samples (%)
Labeled Analog
C13 2,3,7,8-Substituted
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,6,7,8-HxCDD
1,2,3,4.6,7,8-HpCDD
1,2,3,4.6,7,8,9-OCDD
C1 3 2,3,7,8-Substituted
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3.7,8,9-HxCDF
1.2,3,4,6,7,8-HpCDF
Method
Blank
Dioxins
58.2
55.6
82
86.2
82.6
Furans
63.8
63.2
78.8
85.1
99.1
Solvent
Blank
68.3
67.7
94.1
112
121
65.3
88.4
100
121
124
1005A
10.5(J)
7.16(J)
10.1(J)
62.2
94.4
5.76(J)
15.6(J)
9.78(J)
95.6
53.8
1005ADup
33.1
22.6(J)
33.3
96.9
96.1
17(J)
45.5
33.5
96.7
101
1006A 1006ADup LCS
61
41.5
37.9
94.3
93.8
34.4
68.4
34.3
104
90
75.4
66.4
74.9
110
104
70.3
85.9
80.2
113
99.9
69
60.5
89.7
95.2
93.6
69
66.6
83.4
95.1
108
Average
53.6
45.9
60.3
93.8
97.9
46.5
61.9
60.0
101
96.5
Standard
Deviation
23.4
23.3
32.8
16.6
11.9
27.1
25.0
33.6
12.2
21.6
J>
•o
m
z
o
H
X
o
J - Recovery outside MRI criteria of 25-150%.
-------
Table 4. Laboratory Control Spike Results
Spike Level Field ID LCS Percent
pg/g Extract ID 41041 Recovery
Isomer MS Filename K24V13.RPT
2378TCDD
12378PECDD
123478HXCDD
123678HXCDD
123789HXCDD
1234678HPCDD
12346789OCDD
2378TCDF (a)
12378PECDF
23478PECDF
123478HXCDF
123678HXCDF
234678HXCDF
123789HXCDF
1234678HPCDF
1234789HPCDF
12346789OCDF
200
1000
1000
1000
1000
1000
2000
200
1000
1000
1000
1000
1000
1000
1000
1000
2000
231
1190
1120
975
1100
755
1990
189
1070
1060
1250
1240
1070
978
909
831
1930
116
119
112
97.5
110
75.5
100
94.5
107
106
125
124
107
97.8
90.9
83.1
96.5
a - Concentrations for this isomer should be consider a maximum.
The GC column used is not specific for this isomer.
Page 1
-------
Table 1. Native Results (pg/g)
fO
-------
T..ble 2
Analog Recovery (%), 10 Gram Sample
Labeled Analog
13C2378TCDF
13C2378TCDD
13C12378PeCDF
13C12378PeCDD
13C123478HxCDF
13C123789HxCDF
13C123678HxCDD
13C1234678HpCDF
13C1234678HpCDD
13C12346789OCDD
Field ID 1005A
Extract ID 40822
MS File J25VQ18.RPT
9.86 (J)
12.7 (J)
22.1 (J)
8.35 (J)
5.33 (J)
74.7
6.27 (J)
13.5 (J)
24.2 (J)
55.9
1005 A Dup
40823
J25VQ111.RPT
10.7 (J)
11.7 (J)
13.3 (J)
7.97 (J)
5.64 (J)
55.7
7.07 (J)
9.2 (J)
14.9 (J)
21. 3 (J)
1006 A
40824
J25VQ17.RPT
4.78 (J)
6.22 (J)
7.51 (J)
3.87 (J)
2.6 (J)
45.5
3.3 (J)
5.07 (J)
10.3 (J)
15.3 (J)
1006 A Dup
40826
J25VQ110.RPT
2.6 (J)
3.12 (J)
3.45 (J)
1.97(J)
1.19{J)
31.6
1.37 (J)
1.97(J)
4.02 (J)
9.14 (J)
Method Blank
40827
J25VQ16.RPT
72.7
67.3
82.5
61.6
81.4
105
91.9
125
118
127
Solvent Blank
40829
J25VQ15.RPT
33.9
31.2
39.5
30.2
44.2
52.2
44.7
66.5
58.5
63.9
LCS
40828
J25VQ14RPT
74.6
70
78.3
61.7
83.1
96.5
89.3
134
124
126
(J) - Recovery of labeled analog outside MRI criteria of 25-150%.
4951Table 2 10g.xls
-------
Table 2. Labeled Analog Recovery (%)
10 Sk,,,^
Field 10
Extract ID Standard
Labeled Analog _ MS File Average Deviation
13C2378TCDF
13C2378TCDD
13C12378PeCDF
13C12378PeCDD
13C123478HxCDF
13C123789HxCDF
13C123678HxCDD
13C1234678HpCDF
13C1234678HpCDD
13C12346789OCDD
53.3
49.3
61.0
45.9
62.8
60.8
68.3
95.8
88.3
82.3
27.4
25.5
30.4
22.2
26.3
25.8
33.4
41.4
42.1
38.9
•o
•o
m
z
o
H
X
-------
Table 4. Laboratory Control Spike Results
10 ::- £
Spike Level Field ID LCS Percent
pg/g Extract ID 40828 Recovery
Isomer MS Filename J25VQ14.RPT
2378TCDD
12378PECDD
123478HXCDD
123678HXCDD
123789HXCDD
1234678HPCDD
12346789OCDD
2378TCDF (a)
12378PECDF
23478PECDF
123478HXCDF
123678HXCDF
234678HXCDF
123789HXCDF
1234678HPCDF
1234789HPCDF
12346789OCDF
20
100
100
100
100
100
200
20
100
100
100
100
100
100 ' -'
100
100
200
22.2
131
110
104
117
79
200
21.1
107
93.7
130
125
112
105
92.8
87.9
181
111
131
110
104
117
79.0
100
106
107
93.7
130
125
112
105
92.8
87.9
90.5
0-1
12
-------
Appendix D-2
Elemental Analysis
MRI-AED\r4951 -01 -02-05TR.wpJ
-------
mwm %*rt* mmWm Mmm Linking Technology to Solutions
A Division of Midwest Research Institute
Materials and Chemistry Laboratory
Post Office Box 5808
Oak Ridge, Tennessee 37831
Telephone: (423) 576-4138
Fax: (423) 576-8558
Novembers, 1998
Mr. David Alburty
Midwest Research Institute
425 Volker Boulevard
Kansas City, MO 64110
Dear Dave:
The two samples were analyzed by Scanning Electron Microscopy (SEM) with Energy
Dispersive Spectrometry (EDS) and X-Ray Fluorescence Spectrometry (XRF). These
techniques allow for observation of samples at high magnifications (over 100,000.x) and
chemical analysis of the samples. The characterization of these two samples was done on the
as-received samples and on samples that were heated for three hours in a muffle furnace at
825-850°C.
The results of the characterization of the as-received samples by SEM and EDS analysis is
shown in Figures 1 through 7. Figure 1 is a 60x view of the broken surface of sample 11004A.
This area is in the center of the disk and a result of the dimpling when the sample was taken
from the pipe. The central light area in this secondary electron image (SEI) view is the
substrate steel and the darker area is the surface coating. EDS analyses of the central area of
Figure 1 and of the darker coating area are shown in Figures 2 and 3, respectively. The
substrate steel contains iron with a very small amount of aluminum (Figure 2). The coating
material contains iron, silicon, carbon, phosphorus, aluminum, zinc, chlorine, potassium,
calcium, titanium, and manganese (Figure 3). Figure 4 is an SEI view of the cross-section of
the coating material. The material is approximately 35 micrometers thick. The upper surface
(the upper portion of Figure 4) is smooth while the inside of the coating contains a
heterogeneous mixture of particles in the 1 to 8 micrometer size range. Figure 5 is the EDS of
the cross-section. Note that the zinc content registers much higher on the cross-section
analysis than on the top analysis (Figure 3). This is because the electron beam only penetrates
approximately 3 micrometers into the surface of the material. Figures 6 and 7 are from the top
and bottom half of the cross-section, respectively. These two analyses also illustrate the
heterogeneous nature of the coating. The upper portion of the coating is richer in silicon,
carbon, phosphorus, aluminum, chlorine, potassium, calcium, titanium, and manganese while
the lower portion is richer in zinc, nickel, and chromium.
APPENDIX D-2
-------
The XRF was employed to determine the composition of the coating material. The XRF
penetrates into the coating material deeper that the SEM. Tables 1 and 2 contain the results of
the XRF analyses. The original analyses of these as-received samples included 73 elements
from sodium through uranium. The final list of the shown in Tables 1 and 2 include those
elements of presence or interest. The coating material is compostionally zinc and iron with
other minor elements present. The values shown in Tables 1 and 2 are in terms of milligrams
of coating (13millimeter diameter disk) on the sample. These numbers are based on the
loading of elements on thin film standards. The calculated values of mg/cm2 are based on
these milligram values.
The heated samples were also characterized by SEM with EDS and XRF. After heating, the
samples did not revert to the iron substrate but instead either had a high zinc content brown-
black uneven surface or a blue-black or blue-gray coating with lower zinc content, but more
than in the original substrate (Figure 2).
Please call me with any questions.
Sincerely,
Dr. Robert J. Stevenson
MCL-MRI
RJS/di
_A_PPp wnT Y n . ^
-------
Analyses of As-Received Samples, Convex Side
Table 1 Sample 11003A
Elem
ent
Na
Mg
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Zn
11003A
First Run
(mg)
<1ug
<1ug
0.0542
0.0698
0.0504
<1ug
0.0111
0.0090
0.0040
0.0257
0.0019
0.0402
0.0295
2.6603
0.3946
3.4326
11003A
Second Run
(mg)
<1ug
<1ug
0.0533
0.0664
0.0492
<1ug
0.0111
0.0089
0.0039
0.0254
0.0015
0.0402
0.0305
2.6232
0.3859
3.3816
Average
(mg)
<1ug
<1ug
0.0537
0.0681
0.0498
<1ug
0.0111
0.0090
0.0040
0.0256
0.0017
0.0402
0.0300
2.6417
0.3903
3.4071
Standard
Deviation
0.0006
0.0024
0.0009
0.0000
0.0001
0.0001
0.0002
0.0002
0.0001
0.0008
0.0262
0.0061
0.0361
Average
(mg/cm2)
O.001
<0.001
0.040
0.051
0.038
<0.001
0.008
0.007
0.003
0.019
0.001
0.030
0.023
1.990
0.294
2.567
APPENDIX D-2
-------
Analyses of As-Received Samples, Convex Side
Table 2 Sample 11004A
Element
Na
Mg
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Zn
11004A
First Run
(mg)
<1ug
<1ug
0.0535
0.0666
0.0501
<1ug
0.0117
0.0095
0.0041
0.0253
0.0020
0.0401
0.0297
2.7278
0.3473
3.2235
11004A
Second Run
(mg)
<1ug
<1ug
0.0517
0.0628
0.0481
<1ug
0.0116
0.0093
0.0040
0.0254
0.0017
0.0373
0.0297
2.6037
0.3383
3.1164
Average
(mg)
<1ug
<1ug
0.0526
0.0647
0.0491
<1ug
0.0117
0.0094
0.0041
0.0253
0.0018
0.0387
0.0297
2.6657
0.3428
3.1699
Standard
Deviation
0.0013
0.0027
0.0014
0.0001
0.0002
0.0001
0.0001
0.0002
0.0020
0.0000
0.0878
0.0064
0.0757
Average
(mg/cm2)
<0.001
<0.001
0.040
0.049
0.037
<0.001
0.009
0.007
0.003
0.019
0.001
0.029
0.022
2.008
0.258
2.388
APPENDIX D-2
-------
Figure 1. SEI photograph of an area of the center of the convex side of sample 11004A.
MCL-MRI
Oak Ridge, Tennessee
APPENDIX D-2
-------
Fe
Fe Al
o.o
2.0
4.0
6.0
8.0
10.0
keV
Figure 2. EDS composition of the iron substrate of the convex side of sample 11004A.
0.0
10.0
Figure 3. EDS composition of the coating on the convex side of sample 11004A.
MCL-MRI
Oak Ridge, Tennessee
APPENDIX D-2
-------
Figure 4. SEI photograph of a view of the cross-section of the convex side of sample
11004A.
MCL-MRI
Oak Ridge, Tennessee
APPENDIX D-2
-------
o.o
10.0
Figure 5. EDS composition of the of the entire coating of the cross-section of the coating on
the convex side sample 11004A.
Fe
0.0
10.0
Figure 6. EDS composition of the of the top of the cross-section of the coating on the convex
side sample 11004A..
MCL-MRI
Oak Ridge, Tennessee
APPENDIX D-2
-------
Zn
o.o
10.0
Figure 7. EDS composition of the of the bottom half of the cross-section of the coating on the
convex side sample 11004A.
MCL-MRI
Oak Ridge, Tennessee
APPENDIX D-2
-------
Appendix D-3
Particle Sizing
MRI-AED\r4951 -01 -02-05TR. wjxl
-------
MIDWEST RESEARCH INSTITUTE
Sieve Analysis'
Date
* ™
MRI Project*.
Recorded by
Sample ID No.: toOG^fl: uP//
Sample wieght: (p%* 0
Material:
Number of Splits:
Comments:
Analytical Balance:
Capacity:
' **
Smallest Division: 0. f
Date of Last Mfg. Calibration: ^"
Calibration Logbook No.: ^> t~~~ /
Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.
Weight (pan only)
'3%&' 3
?$l. o
37 (• °
SIZE DISTRIBUTION
Screen
Tare Weight
(Screen)
Final Weight
(Screen + Sample)
Net Weight
(Sample)
4 mesh
10 mesh
ft.*
20 mesh
40 mesh
/?-/£•
100 mesh
360.1
200 mesh
3*3.0
Pan
*AII unit weights are in grams unless otherwise specified
APPENDIX D-3
-------
MIDWEST RESEARCH INSTITUTE
Sieve Analysis*
Date
MRI Project*.
^T^ecorded
Sample ID No.:
Sample wieght:
Material:
Number of Splits:
Comments:
Analytical Balance:
Capacity:
C/— "5
Smallest Division: v Q, f
Date of Last Mfg. Calibration: _^
Calibration Logbook No.:^/. -
Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.
Weight (pan only)
386. %
>§v. o
?>VI,0
SIZE DISTRIBUTION
Screen
Tare Weight
(Screen)
Final Weight
(Screen + Sample)
Net Weight
(Sample)
4 mesh
04
10 mesh
20 mesh
40 mesh
K.I
**•
100 mesh
353.5
200 mesh
Pan
*AII unit weights are in grams unless otherwise specified
APPENDIX D-3
-------
MIDWEST RESEARCH INSTITUTE
Sieve Analysis*
Date
Project #
O ^Recorded by
Sample ID No.:
Sample wieght:
Comments:
£>£>
//?//
Material:
Number of Splits:
Analytical Balance:
Capacity: 4/0 O>.
Smallest Division: O, /
Date of Last Mfg. Calibration:
Calibration Logbook No.:
~~
Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.
Weight (pan only)
37
-------
Date T^C
Sample ID N
Sample wieg
Comments:
MIDWEST RESEARCH INSTITUTE
Sieve Analysis* ^
'"f^ MRI Project* *fl50~0$'0S Recorded bv /^^L^-^^f2-
o • tfitf /f faZ^ Material:
ht: #'$ "~ Number of Solits: /
Analytical Balance: ^s*&-s~-r&> o— <•'< — db>
Capacity: c
tlOO ^~
V /••> /
Smallest Division: f' '
Date of Last
Calibration L
Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
Pan
Mfq. Calibration: Z_ - Z^f - ^ ^
ogbook No.: ^^." f
S
Tare Weight
(Screen)
<32--^
// / /^ <*"
f ^ 5 '_X
¥^. 5"
<»P<> ?~. 0
?^/.^
37^-^-
Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.
Weight (pan only)
~r*>7-2.?
^j mr^{? * _^^
^*^ ~~/_ Cf j
ZE DISTRIBUTION
Final Weight
(Screen + Sample)
<35-3>
y0 2- . V-
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5~/0 • 0
3^s 7 ^>
fc-/ ^- » Jx
37^.^
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(Sample)
2-. 5"
3 ^.2.
^3'^-
r^>. ^
(t.f
$><{
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%
2,.$
tf/.{
3?. 2.
//.S
Q.tf
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*AII unit weights are in grams unless otherwise specified ' ^
APPENDIX D-3
-------
Date i " 3(
MIDWEST RESEARCH INSTITUTE
Sieve Analysis*
/7 / ^~ <'*-^-^>
Capacity:
^(00 ^
Smallest Division: 0, (
Date of Last
Calibration L
Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
Pan
Mfg. Calibration: 2 - 2-°/ "" 9 ^
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S
Tare Weight
(Screen)
5"5x£ . ?
tf-fiZ-.Z-
Wf'1
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2£Z.<20^
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ZE DISTRIBUTION
Final Weight
(Screen + Sample)
5"5?' $
5~3c?< ?
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'fOO, 3
3><6?2-- •?
3f2 . ^
^^ O.C?
Net Weight
(Sample)
/. (
*{$, ?
n.
-------
MIDWEST RESEARCH INSTITUTE
Sieve Analysis"
Rat*
MRI Project*
Recorded by
Sample ID No.: _£
Sample wieght: fc>3.
Comments:
Material:
Number of Splits: /_
Analytical Balance:
Capacity: _
*?
$•!
Smallest Division:
Date of Last Mfg. Calibration: 2- - iff- 9
Calibration Logbook No.: <"'L- "I
Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.
Weight (pan only)
-^^S ff
3>'3-%.cft
<$ 7^, $
^£"S>-3
3 7?--0
%L 8>0
333,0
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Final Weight
(Screen + Sample)
573.^
i/f£&33rre? $$
-------
MIDWEST RESEARCH INSTITUTE
Sieve Analysis*
Date - 0-
MRI Project #
-0f-0f Recorded by
Sample ID No.: 6 OQ% 4 ffrl)
Sample wieght: -fy
Material:
Number of Splits: /[_
Comments:
Analytical Balance:
Capacity:
<~)
Smallest Division: fit f
Date of Last Mfg. Calibration:
Calibration Logbook No.:
$&
~~ /
Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.
Weight (pan only)
*?•?• i? ^f
"? ^fi'%
5 2— P ^
SIZE DISTRIBUTION
Screen
Tare Weight
(Screen)
Final Weight
(Screen + Sample)
Net Weight
(Sample)
4 mesh
532.
10 mesh
20 mesh
M.te
40 mesh
2..1-
100 mesh
200 mesh
Pan
37-^.5
0,1
*AII unit weights are in grams unless otherwise specified
APPENDIX D-3
-------
Sample ID N
Sample wieg
Comments:
Analytical Ba
Capacity:
MIDWEST RESEARCH INSTITUTE
Sieve Analysis"
•^?^MRI Project # WSO "0?~ ^Recorded bV.^^6c^^— ' <*.
o.: f,OOV A fO'L?) Material:
ht: fatf-rf' " ^ Number of Splits: /
lance: **-~±&^' '-4—s> • / v_*«^--5
rffOti ^
Smallest Division: 0 0, f
Date of Last
Calibration L
Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
Pan
Mfq. Calibration: <2-- Z-rf ~~ ^^
oqbook No.: £L- ~~ /
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Tare Weight
(Screen)
5"J ?-• %
ifid'O
¥32* ">
*bl T^' 0
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3^'^
Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.
Weight (pan only)
3?-^- ^
'Z'T-tf.y
2>3-£,£
ZE DISTRIBUTION
Final Weight
(Screen + Sample)
£?tf 7
£*£/ ^1 &
//£/ ^
*2 €i G "7
%G $ - 1"
333.J2
3"? ^
Net Weight
(Sample)
/' <
b3.%
Ik- 0
^ 5
0- :h
O.J
O.I
%
l'$
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/J.f
tr-l-
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0-1
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APPENDIX D-3
-------
MIDWEST RESEARCH INSTITUTE
Sieve Analysis*
MRIProiect#
Recorded by
Sample ID No.:
Sample wieght:
Comments:
(Of)
Material:
Number of Splits: /_
r
Analytical Balance:
Capacity:
Smallest Division: U• /
Date of Last Mfg. Calibration:
Calibration Logbook No.: _
Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.
Weight (pan only)
29-6. i
3?-£,ff
3 ?-6, f
SIZE DISTRIBUTION
Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
Pan
Tare Weight
(Screen)
^ p jo *3—
c/ / ^ i
/f 3 , y-
313.2-
31J.I
5j~(j?.L'
Final Weight
(Screen + Sample)
£U».3
Vf/3
3^X3"
"35" Z, ^
3 ^-6, f
Net Weight
(Sample)
/33. t
/^ C^*
^ /9 — -r
£.4
^-i
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0>5
%
70. V
13. V
] /} i
*7 tf
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*AII unit weights are in grams unless otherwise specified
APPENDIX D-3
-------
Date 7" 7
Sample ID N
Sample wieg
Comments:
^* /o^1
V
Analytical Bs
Capacity:
MIDWEST RESEARCH INSTITUTE
Sieve Analysis*
/° /j0
0 ' /& MRI Project # /?$# "&$ ^Recorded bv Cs^^^2J> -,.,,--^_ ^^^^— ^-
-<^2^^- t/o^^&JJLs^Jl**^
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lance: ^-^^'"r'5 f~ (
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i
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Smallest Division: ^' '
Date of Last
Mfq. Calibration: 2- - 2-/- f 5"
Calibration Logbook No.. > L- ~ f
Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
Pan
S
Tare Weight
(Screen)
5£2.3~~
f£. /
fJ / f-f Q
T c»
-------
Date 9"^
MIDWEST RESEARCH INSTITUTE
Sieve Analysis*
1'1* MRI Project # f f// ^ 0? "^Recorded by ^^^t^-i<^-
Sample ID No.: £0/2-4 ^Ol^) Material:
Sample wieqht: 2-6^,3 Number of Splits: /
Comments:
4o Are.
r
-^.^ o,«^-,, -v^^- ^_ -.
^-£-JL.L>4 ^L^^^v
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(/
Analytical Balance: r"~ i '<*r=5
Capacity: /
HOC ^
Smallest Division: " O, /
Date of Last
Calibration L
Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
Pan
Mfq. Calibration: 2- " 2./^ ^ %
oqbook No.: ^- /^ ~" /
S
Tare Weight
(Screen)
f *9 ~~1 *~J —
» c ^i . /^
^^^. ^
^3^. >
3 1 iS£
3^,^,0
335,6
3f #,4
Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.
Weight (pan only)
? T2-^. ^
2>^JtO
33-f, *f
ZE DISTRIBUTION
Final Weight
(Screen + Sample)
^D/. ^
^2-^.7
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V"<9?-.5
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33<4. ^"
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APPENDIX D-3
-------
MIDWEST RESEARCH INSTITUTE
Sieve Analysis*
Pat* 7"' MRIPrnjPrt* f ffC^^t^'^r Rernrried bYOaC-X^S/^V<2.
Sample ID N
Sample wieg
Comments:
Analytical Ba
Capacity: ^
/>
o.: IP 01 "2^ A CD\^) Material:
ht: ££. f " " Number of Splits: /
lance: $r^v-~'f-*>^ < i — ^5>
A/^^c^.
Smallest Division: ^ #, /
Date of Last
Calibration L
Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
Pan
Mfg. Calibration: 2~ - ^^"'r $
ogbook No.: ^?£ — /
S
Tare Weight
(Screen)
JT331.7
MZI
m.f
3f 3.2-
5^3.2^
5^/^6
3^6.^
Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.
Weight (pan only)
3T^,¥
39-^-?
3?-^. 6
3^f./
37-^^
ZE DISTRIBUTION
Final Weight
(Screen + Sample)
•9-0V. /,
500**
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*f63/b
1*f?-*.*
Net Weight
(Sample)
/W/9
^^.^
33-^
/D,Y
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/•Y
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%
^r?
13.1
n~
-------
MIDWEST RESEARCH INSTITUTE
Sieve Analysis*
Date ~3O- 7ft MRI Project # Yftf " #2 '^Recorded bv f ^c^^-^^J .
Sample ID No.: 7-0034 Cvl^> Material:
Sample wieqht: SZY-^" Number of Splits: /
Comments:
Analytical Ba
Capacity:
lance: <~2a-~s~4-ovr~~ i • — -5
4/00 ^
V
Smallest Division: €>. f
Date of Last
Mfq. Calibration: 2,- Z-^/— ^ *
Calibration Logbook No.: 5 L- ~ (
Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
Pan
S
Tare Weight
(Screen)
532~^
te.3
VIS.O
*<**.?-
35-z. Y
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^^o.°\
Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.
Weight (pan only)
S^-^'
y-wr-
^x^^'
¥/£.Z-
¥/?-./
ZE DISTRIBUTION
Final Weight
(Screen + Sample)
£23tf
ItZ.'i
^3?.?
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ffl'V
5 7-2,. 5"
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Net Weight
(Sample)
o.o
0.1
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%
0.0
0-0
1,4
IS.z
30,0
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APPENDIX D-3
13
-------
MIDWEST RESEARCH INSTITUTE
Sieve Analysis*
Date 3-20-1$ MRI Project*
- Recorded bv
Sample ID No.:
Sample wieght:
Material-
Number of Splits: /_
Comments:
Analytical Balance:
Capacity:
Smallest Division 0 . /
Date of Last Mfg. Calibration:
Calibration Logbook No.:
2.
- f
Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.
Weight (pan only)
•p •T-/ "
•5 ~r(0f /
/0(p' f
<-ff&,3~
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SIZE DISTRIBUTION
Screen
Tare Weight
(Screen)
Final Weight
(Screen + Sample)
Net Weight
(Sample)
4 mesh
O.O
10 mesh
20 mesh
40 mesh
393.3
•W.
100 mesh
200 mesh
2-2.. 1
Pan
*AII unit weights are in grams unless otherwise specified
APPENDIX D-3
-------
Date ^x '
Sample ID No.: JJ.
MIDWEST RESEARCH INSTITL
Sieve Analysis*
' MRI Project* (^0"0(r^Reco\
JTE
•ded by L^^ — ^-c^^-/^^ .
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Sample wieqht: 3/2_-2- Number of Splits: /
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Capacity: tf/6O
f ,
Smallest Division:
Date of Last Mfg. C
Calibration Logboo
Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
Pan
^-it-v^T^9 ^ '( t*-^
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kNo.: $L.- 1
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Tare Weight
(Screen)
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APPENDIX D-3
15
-------
MIDWEST RESEARCH INSTITUTE
Sieve Analysis* ._ /i
// & ^>{
Date ^-30" Iff MRI Project* , /
Date of Last Mfq. Calibration: ^-~ "^^ "" t ^
Calibration Loqbook No.: *£ I— ~~ /
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Screen (Screen)
4 mesh ^? 5Z.- ^
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20 mesh '^^3. if-
40 mesh 3 3. 5
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10 min.
20 min.
30 min.
40 min.
Weight (pan only)
3 "7^*^ /7
y^?^, f
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ZE DISTRIBUTION
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(Screen + Sample)
£~32-.,T
y#£.3
L/.£fft<£
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27. £>
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32-.^
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fe.o
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^^
APPENDIX D-3
16
-------
MIDWEST RESEARCH INSTITUTE
Sieve Analysis*
Date
-
MRI Project #
ecorded by<
Sample ID No.: ^OC3A Cu£) Material:
Sample wieqht: V^GP. Z- Number of Splits: 2-
Comments:
Analytical Ba
Capacity: ^
lance: j-v—s- ~i&-v*~ fv*^*^
'foo^ ~~
Smallest Division: <2» /
Date of Last
Calibration L
Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
Pan
Vlfq. Calibration: 2- -~ «- */•*" ? 5
oqbook No.. ^£. ~ /
S
Tare Weight
(Screen)
532. i^
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if/Lf ^
3^7-9-
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(Sample)
/ 7 I • (a
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-------
Date Y$
Sample ID N
Sample wieg
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Analytical Ba
Capacity: *
MIDWEST RESEARCH INSTITUTE
Sieve Analysis*
^"i MRI Proiect# *ff $0" Of "&J Recorded bv ^ — /6*~^i/ ^*—
0#3 fr (o'L) Mptoriai-
ht: 5" 3 ?. $? Number nf Splits: £2-
lance: ^>&^f~-j~f>/~ i c^-^S
'-HOC <^-
Smallest Division: & 0 , 1
Date of Last
Calibration L
Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
Pan
Mfq. Calibration: ^- — Z^/ -^^^
oqbook No.: *^Z_ - /
S
Tare Weight
(Screen)
5"32.. ?-
y^ 5-3
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10 min.
20 min. ,
30 min.
40 min.
Weight (pan only)
3^.^
l^f-t-b
^fc^elz^'3 ^4 t 3
ZE DISTRIBUTION
Final Weight
(Screen + Sample)
fnz^S.S
LI "7~?f /
tf52.y
cfO'Z'.Lt
3V%< I
3S2-.f
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Net Weight
(Sample)
¥f2.. g
11.1
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f . ^
if. f
//£
Q,^
%
9A/
2.2
3.
-------
MIDWEST RESEARCH INSTITUTE
Sieve Analysis*
Date
"
MRI Project #
0tf-0> Recorded by
Sample ID No.:
Sample wieght:
7/9 f /
Comments:
Material:
Number of Splits:
Analytical Balance:
Capacity:
*
Smallest Division: fy. I
Date of Last Mfg. Calibration: 2>-
Calibration Logbook No.: 5- (~
~ t
Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.
Weight (pan only)
3-tH-Y
3T-C,.?
31-6.1
SIZE DISTRIBUTION
Screen
Tare Weight
(Screen)
Final Weight
(Screen + Sample)
Net Weight
(Sample)
4 mesh
43 2,
37-Z.
10 mesh
5", 3
ID.?
20 mesh
rt.
if
40 mesh
100 mesh
200 mesh
3*1.1,
I?,*-
Pan
*AII unit weights are in grams unless otherwise specified
APPENDIX D-3
19
-------
MIDWEST RESEARCH INSTITUTE
Sieve Analysis*
Date
MRI Project*
- OS Recorded by
Sample ID No.:.
Sample wieght:
Material:
Number of Splits:
/
Comments:
Analytical Balance:
Capacity:
l/l/Ucj
ivisiotr
Smallest Division: 0, (
Date of Last Mfg. Calibration:
Calibration Logbook No.:
Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.
Weight (pan only)
3 ?0. ?
j^fftrZ- 3 ?/. 3 '
•y i //
-^ O If i
l*f
\l*il
SIZE DISTRIBUTION
Screen
Tare Weight
(Screen)
Final Weight
(Screen + Sample)
Net Weight
(Sample)
4 mesh
5
m
.
10 mesh
ft.
20 mesh
40 mesh
3 ?y-
100 mesh
1.Z-
200 mesh
f.lr
o.'b
Pan
ad.
*AII unit weights are in grams unless otherwise specified
APPENDIX D-3
20
-------
Date ^-3i
MIDWEST RESEARCH INSTITUTE
Sieve Analysis*
1 " °l$ MRI Project # <-f q < - 4f-#Recorded bv (sJ^-^^^J<
Sample ID No.: $00 3 /
Sample wieght: H'T-I.
Comments:
"2^f^0**~— 5
I/
/*-/- <~0//l
-^•-h Uv
1
Analytical Balance: ^«c
Capacity:
tffOO c
X^ >^ "N. tx"
f Z^-L J Material:
-> Number of Splits: ^^
^ -/o ^^_ *L^.'^^. <^^&*
G^)^_^ ^L- 5^?-^ ^ C*^Sl
# // /
//
^/-h^ I'L^
•3^
Smallest Division: d.l"
Date of Last Mfq. Calibration: t " Z- ^f — *} ^
Calibration Logbook No.:
Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
Pan
Z i-- 1 '
s
Tare Weight
(Screen)
^5 3J2. ^
tl«?< -2_
\0^)> '
2_
V^3. .5
3f^.^
O / £ Q
^^^^T^ 333. c
39-<^.f
Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.
Weight (pan only)
334.4
3-?-^ ^
-2,3-3.2-
3 ^f,j5"
2^_^ ^i
ZE DISTRIBUTION
Final Weight
(Screen + Sample)
732.. (f
4qV. ?•
>e-^ 3 •?" ^
3? .0
33^.5
^"-M^ ^
Net Weight
(Sample)
3 ? f'f
flTr /?
y; ^,
2-'^-
,3. 6?
/• 3
/. 3^_.
%
tf¥>t
z.l
!• '
J5» t
0,7-
0,3
0'3>
*AII unit weights are in grams unless otherwise specified '
_
/
APPENDIX D-3
21
-------
MIDWEST RESEARCH INSTITUTE
Sieve Analysis*
Date
f /
MRI Project #
Sample ID No.: ?OOJ A
Sample wieght:
aterial:
WZ.*
Analytical Balance:
Capacity: _
/"
-^
Smallest Division: v (? , /
Date of Last Mfg. Calibration: j
Calibration Logbook No.: _
- 2
"
Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.
Weight (pan only)
Z^-tf, 0.
3 ?~f • (P
3 SO. O
3 ?o. (
3ff^ *?
O <-'• ^—
SIZE DISTRIBUTION
Screen
Tare Weight
(Screen)
Final Weight
(Screen + Sample)
Net Weight
(Sample)
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
. 3
200 mesh
. 3
I- 0
Pan
*AII unit weights are in grams unless otherwise specified
APPENDIX D-3
22
-------
Date ^^
MIDWEST RESEARCH INSTITl
Sieve Analysis*
7" 1f MRI Project # /£0 " ^/ '^/Reco
JTE
rded by
f.
/u^C^2^-lr-
Sample ID No.: HOOjfi (Dl) Material:
Sample wieght: V^Y 2- Number of Splits:
Comments:
I
Analytical Balance: &-*<-^'~rvr~i'u^>
Capacity: 4
WO*.
Smallest Division: O. f
Date of Last
Calibration L
Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
Pan
Mfq. Calibration: Z-2--£*l
tLs * 1
tf3-(e*0
LftftS.
5O ^^ ^}
]/ / * v '**'
^-j /• / ^^'
J^S. ^
3 "7-^.^
Net Weight
(Sample)
^63. *f
^. *7
/ 0
b • rt
^
f,0
•f'-L
2^^
>,
%
36*1-
I'tf
0. 9
d- 5
o.d>
0^3
0.3
-na 7 G
*AII unit weights are in grams unless otherwise specified ' '
APPENDIX D-3
23
-------
Date ?- 2/0
Sample ID N
Sample wieg
Comments:
Analytical Be
Capacity: ^
MIDWEST RESEARCH INSTITUTE
Sieve Analysis*
" ft MRI Project # ty tJt'fffcO} Recorded bv ( ^<^^^^^—
o.: $00 i //- fi>dO Material:
ht: Lj(p3..<& Nur
ilance: j^-z^^T9 ^ ~ 1 ^~~~5
'/£>£> ^
nberof J
Splits: f? ,
Smallest Division: (?» /
Date of Last
Calibration L
Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
Pan
Mfa. Calibration: 2- " 2- /— 1 %
oqbook No.: ^ '/^ — /
S
Tare Weight
(Screen)
$?>l. T-
H-yZ-*]
y /y 9
^ I 0 p -7
*^> ^ S~\ £J
3^,1.5"
^^0. #
Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.
Weight (pan only)
370.
r^L. ^
i- f
5, t?
2- ^
/-^
%
f^.?
I '(a
0^
0. (*
0, (,
(9.3
/; «,
*AII unit weights are in grams unless otherwise specified }(0^-' \
APPENDIX D-3
24
-------
MIDWEST RESEARCH INSTITUTE
CHAIN-OF-CUSTODY FORM
MRI Project No.
Check Only Those Samples Transferred:
Code: MRI-5003
Revision: 1
Effective: 3/27/98
Page: 15 of 17
261
#1 #2
^Sr n 21
ra n^y
p D
G? n
jk n
0L n
w- n
]ZP n
M n
Sample Identifier #1
osz^n? / -70 ow n
Do*fS-^ -70*^ D
^y/ *\ "^ ^ 1 " ~ ~l
^opy/4- D
6o/(A D
*• (i A- n
^ -s ->^ A n
b <2 o /TJ 1 — 1
6"^ n
/ •> A n
b B 0 J /"]> 1 — 1
#2 Sample Identifier
n
a
a
a
a
a
a
a
n
a
a a
Please sign the form; initials are not acceptable. Please use military time
designations (e.g., 13:23). For field samples returning to the sample custodian,
indicate the storage area in the comments section. The comments section should
indicate the sample type and purpose of the transfer (e.g., GC/MS analysis).
#1 Relinquished by:
Received by:
Date and Time:
Comments:
#2 Relinquished by:
Received by:
Date and Time:
Comments:
MRl-QAVMRl- 5003.DOC
APPENDIX D-3
25
-------
Code: MRI-5003
Revision: 1
Effective: 3/27/98
Page: 15 of 17
MIDWEST RESEARCH INSTITUTE
CHAIN-OF-CUSTODY £ORM
MRI Project No.
Check Only Those Samples Transferred:
#1
a:
n
a
a
a
a
a
#2 Sample Identifier
n &<9 y/r
n
n
n
n
n
n
n
n
n
n
n
n
n
n
n
n
n
n
#2 Sample Identifier
n
n
n
n
n
n
n
n
n
n
Please sign the form; initials are not acceptable. Please use military time
designations (e.g., 13:23). For field samples returning to the sample custodian,
indicate the storage area in the comments section. The comments section should
indicate the sample type and purpose of the transfer (e.g., GC/MS analysis).
#1 Relinquished by:
Received by:
Date and Time:
Comments:
#2 Relinquished by:
Received by:
Date and Time:
Comments:
MRI-QAVWRI-W03.DOC
APPENDIX D-3
26
-------
TECHNICAL REPORT DATA
(Please read Instructions on reverse before completing)
1. REPORT NO. 2.
EPA-454/R-99-038
4. TITLE AND SUBTITLE
Waste Materials Testing in Support of Regulatory Development For
Industrial, Commercial, And Institutional Boilers
7. AUTHOR(S)
EMAD
9. PERFORMING ORGANIZATION NAME AND ADDRESS
U.S. Environmental Protection Agency
Office of Air Quality Planning and Standards
Research Triangle Park, NC 27711
12. SPONSORING AGENCY NAME AND ADDRESS
Director
Office of Air Quality Planning and Standards
Office of Air and Radiation
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
3. RECIPIENTS ACCESSION NO.
5. REPORT DATE September, 1999
6. PERFORMING ORGANIZATION CODE
g. PERFORMING ORGANIZATION REPORT NO.
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
Midwest Research Institute
EPA Contract # 68-D-98-027
13. TYPE OF REPORT AND PERIOD COVERED
final test report
14. SPONSORING AGENCY CODE
EPA/200/04
15. SUPPLEMENTARY NOTES
16. ABSTRACT
The purpose of this test program was to obtain data to support the development of National Emission
Standards for Hazardous Air Pollutants. This test program included sampling and analysis of waste material
combusted in 1 1 boilers or burnoff ovens and were taken from 1 1 different facilities. This data will be used in
conjunction with other information to characterize materials combusted in boilers.
1 7.MACT Rule Support KEY WORDS AND DOCUMENT ANALYSIS
a. DESCRIPTORS
18. DISTRIBUTION STATEMENT
Release Unlimited
b. IDENTIFIERS/OPEN ENDED TERMS c. COSATI Field/Group
Air Pollution control, MACT
Support for Industrial, Commercial,
And Institutional Boilers
19. SECURITY CLASS (Report) 21. NO. OF PAGES
Unclassified 258
20. SECURITY CLASS (Page) 22. PRICE
Unclassified
EPA Form 2220-1 (Rev. 4-77) PREVIOUS EDITION IS OBSOLETE
-------