& EPA
          United States
          Environmental Protection
          Agency
             Office of Air Quality
             Planning and Standards
             Research Triangle Park, NC 27711
EPA-454/R-99-038
September 1999
          Air
WASTE MATERIALS TESTING IN SUPPORT OF
REGULATORY DEVELOPMENT FOR
INDUSTRIAL, COMMERCIAL, AND
INSTITUTIONAL BOILERS

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 Preface
    This document was prepared by Midwest Research Institute (MRI) for the U.S.
 Environmental Protection Agency (EPA) under EPA Contract No. 68-D-98-027, Work
 Assignment No. 2-01 (continuation of work performed under Work Assignment
 No. 1-08). Mr. Terry Harrison is the EPA Work Assignment Manager. In this report,
 MRI presents a description of the sources sampled, the sampling and analysis procedures,
 quality assurance and quality control activities, reporting and data reduction, sample and
 data handling procedures.

    This document contains one technical volume entitled, "Waste Materials Testing in
 Support of Regulatory Development for Industrial, Commercial, and Institutional
 Boilers" (250 pages).

    The test program was conducted in MRI's Applied Engineering Department under the
 leadership of Mr. John Hosenfeld, Work Assignment Leader and Program Manager, who
 will provide oversight to technical and administrative aspects of this work assignment.

                                               MID WEST RESEARCH INSTITUTE
                                               Johrf Hosenfeld      I/
                                               Program Manager
 Approved:
 Thomas J. Grant, Ph.D., P.E.
 Director
 Applied Engineering
 September 29, 1999
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 Contents
 Preface  	  ii
 Tables	  vii

Section 1. Introduction	1-1
     1.1 Background and Purpose  	1-1
     1.2 Project Summary	1-1
     1.3 Key Personnel	1-2

Section 2. Process Description and Sampling Locations	2-1
     2.1 Process Description  	2-1
     2.2 Sampling Locations  	2-1

Section 3. Sampling and Analytical Procedures  	3-1
     3.1 Sampling Procedures and Methods Summary 	3-1
     3.2 Analytical Methods Summary  	3-7

Section 4. Test Results	4-1
     4.1 Objectives and Test Matrix	4-1
     4.2 Test Changes and Problems  	4-3
     4.3 Test Results	4-5

Section 5. Quality Assurance/Quality Control Activities  	5-1
     5.1 Data Audit	5-1
     5.2 Data Assessment	5-1

 Appendices

 Appendix A—Sample Traceability Data
 Appendix B—Sampling Data
 Appendix C—Galbraith Analysis Reports
 Appendix D—MRI Analysis Reports
            Appendix D-l—Organic Analysis (Ds/Fs and PAHs)
            Appendix D-2—Elemental Analysis
            Appendix D-3—Particle Sizing
MRI-AEDVR4951 WA 2-01.wpd

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 Tables
Table 1-1. Facility Contacts and Schedule	1-3

Table 4-1. Samples Analyzed for Fuel Material Characterization	4-3
Table 4-2. Feed Characteristics  	4-6
Table 4-3. Halogens (mg/L)	4-8
Table 4-4. Particle Size  	4-10
Table 4-5a. Multiple Metals Results, Excluding Mercury (ppm) 	4-11
Table 4-5b. Mercury Results (ppm)	4-13
Table 4-6. PAH Results (jug/g), Pitch Material  	4-14
Table 4-7. PCDD/PCDF Results (pg/g), Pitch Material  	4-15

Table 5-1. Specific Objectives for Measurement Data  	5-2
MR1-AED\R495I WA2-01.wpd                         Vll

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 Section  1.
 Introduction
    This report presents the results of sampling and analysis of various non-fossil
 materials combusted in boilers. Testing background and purpose, and project summary,
 below, provide more information regarding this test. Test locations and descriptions of
 materials tested are provided in Section 2, sampling and analytical procedures are
 summarized in Section 3, test results are found in Section 4, and internal QA/QC
 activities are discussed in Section 5.
 1.1  Background and  Purpose

    The purpose of this testing is to obtain data to support the development of National
 Emission Standards for Hazardous Air Pollutants (NESHAP) emission standards for
 industrial, commercial, and institutional boilers.  Testing was to be conducted in two
 phases. Phase 1 included sampling and analysis  of waste material from 11 boilers or
 bumoff ovens.  Phase 2 was to include performance of emission testing and reporting on
 one boiler to fill data gaps and prioritize follow-on activities by EPA. This report
 addresses Phase I, the waste material analysis for 11 boilers or burnoff ovens taken from
 11 different facilities.

    The results of both phases of testing will be used by EPA to:

    •    Characterize the various materials combusted in boilers
    •    Focus and prioritize emission testing during follow-on activities by EPA
    •    Determine the effectiveness of an add-on control device to reduce hazardous air
        pollutant (HAP) emissions
    •    Determine the effects of co-firing non-fossil waste materials with primary fuels
        (wood or coal)
    •    Determine into which subcategory co-fired units should be placed
 1.2  Project Summary

    Six different types of waste-derived materials (high Btu content) were sampled at
 11 facilities across the continental United States. The waste-derived materials used for
 testing were: (1) tall oils and turpentine sludges, (2) activated sludge, (3) SIC 28 waste,
 (4) SIC 37 waste, (5) agricultural waste, and (6) PVC and non-PVC coatings. At each
 facility sampled the above materials were co-fired in their boiler or bumoff oven on-site.
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    The sampling methods used were dependent upon the physical form of the
 waste-derived material (solid or sludge). Sampling procedures are derived from
 EPA-600/8-84-002, "Sampling and Analysis Methods for Hazardous Waste Combustion"
 and conform to SW-846 "Test Methods for Evaluating Solid Waste," Chapter Nine;
 ASTM methods were also used for guidance, when appropriate. Duplicates of each
 sample were taken in every case; some material required additional samples to ensure
 representati veness.

    All samples were analyzed for ultimate analysis, metals, heat content, and halogens;
 some samples were analyzed for additional parameters such as specific gravity, viscosity,
 or organic materials.
 1.3  Key Personnel

    The following individuals are the key personnel in the management and execution of
 this test program. Table 1-1 contains the facility contacts and date that each facility was
 sampled.

    The EPA Work Assignment Manager is:

    Mr. Terry Harrison
    U.S. EPA; Office of Air Quality Planning and Standards
    Emissions, Monitoring, and Analysis Division; Source Characterization Group
    MD-19, Research Triangle Park, NC 27711
    Phone:(919)541-5233
    Email: harrison.terry@epa.gov

    The MRI Work Assignment Leader for this test program is:

    Mr. John Hosenfeld
    Midwest Research Institute
    425 Volker Blvd.
    Kansas City, MO 64110
    Phone: (816) 753-7600, ext. 1336
    Email: jhosenfeld@mriresearch.org
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                        Table 1-1. Facility Contacts and Schedule
            Facility address
          Facility contact
Sampling dates,
 September '98
  Sylvachem Corp./Arizona Chemical
  Highway 98
  Port St. Joe, FL 32456
  Attn: Ann Jeffries
Phone 850-229-8271 ext. 206
Fax 904-229-8519
sixnewts@aol.com
      16
  Trigen Colorado Energy Corp.
  12th Ford (Valley Complex)
  Golden, CO
  Mr. Charlie Abbot
Phone 303-277-2051x2626
Fax 303-277-5629
cabbot@trigen.com
      18
  Hercules, Inc.
  2801 Cook Street
  Brunswick, GAS 1520
  Attn: Mr. Kevin Wileman
Phone 912-265-3550x3452
Fax 912-261-3515
kwileman @ herc.com
      25
  Monsanto Agricultural Co.
  2500 Wiggins Rd.
  Muscatine, IA 52761
  Attn: Mr. Jim Fowler or Mr. Tom Ward
Phone 319-262-7434
Fax 319-262-7132 or 262-5683
     16-17
  General Motors Corporation
  NAO Flint Mfr. Operations
  Mail Code 485-185-030
  902 E. Hamilton Ave.
  Flint, Ml 48550
  Attn: Mr. John Moldovan
Phone 810-236-3780
Fax 810-236-7391
LNUSBCY1J2H1 M0@gmeds.com
      15
  Corn Products
  4501 Overdale Rd
  Winston-Salem, NC 27107-6145
  Attn: Mr. Bruce Hedrick
Phone 336-785-8805
Fax 336-785-8809
bruce.hedrick@cornproducts.com
      18
  Agrilectric Power Partners LTD Plant #1
  POB 3716, Lake Charles, LA 70602
  Attn: Mr. Carl Kiser
Phone 318-421-6330
Fax 318-421-6329
carlk@frmco.com
      14
  Georgia Pacific
  Great Southern Paper Woodlands Oper.
  GA Highway 273
  Cedar Springs, GA
  Attn: Mr. Dave Massengill
                                           23
Phone 912-372-5541, ext. 5/5541
Fax 912-372-5163
DGMASSEN @ gapac.com
  Rack Processing Co., Inc.
  2350 Arbor Blvd.
  Dayton, OH 45439-1724
  Attn: Mr. Phil Lantz
Phone 937-294-1911
Fax 937-294-7153
      24
  Rack Processing Co., Inc.
  170 Fox Drive
  Piqua, OH
  Attn: Mr. Phil Lantz or Mr. Craig Coy
Phone 937-773-0725
Fax 937-773-0726
      22
  Tri Valley Growers
  2260 Tenaya Drive
  Modesto, CA 95354
Phone 209-572-5953
Fax 209-572-5982
      28
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 Section 2.

 Process Description and Sampling Locations


 2.1  Process Description

    A distinction should first be made between ongoing facility processes and those
 processes which are related to boiler waste materials storage and feed. Only those
 processes related to feeding and storing the boiler waste feed materials are relevant to this
 test. Eleven facilities were sampled, all of which utilized various storage and feed
 methods, depending upon the type of material used.  Alternative  feed materials were
 either solids or sludges.  Solid materials were stored in pits, covered piles, or
 dumpsters/carts and fed to boilers through the use of a conveyer system, pneumatic feed
 line, or in batch. Sludge materials were stored in tanks and piped to burners.

    Because sampling procedures are inter-related with material storage and feed
 procedures, these are discussed together in Section 3.1, Sampling Procedures, to provide
 a more comprehensive picture of the overall testing activities.


 2.2  Sampling Locations

    All alternative feed materials were sampled at a location nearest to the boiler intake.
 Locations are discussed in more detail in Section 3.1, Sampling Procedures.
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 Section 3.
 Sampling and Analytical  Procedures
    Material storage, feed, and sampling procedures are described in Section 3.1 below.
 Analytical procedures are included in Section 3.2.
 3.1  Sampling Procedures and Methods Summary

    Because sampling procedures employed were a combination of the methods cited in
 Section 4.1 and are interrelated with material storage and feed processes, they are
 described in detail below.
 3.1.1   Tall Oils and Terpentine Sludges

    This category included pitch. Pitch was provided by Arizona Chemical Company,
 Port St. Joe, Florida.  Pitch is the bottom cut from the first refining step of Tall Oils.
 There are commercial uses for pitch, so it is not normally burned as fuel unless there is a
 natural gas curtailment. Tall oils are produced by accumulating black liquor soap as a by-
 product of paper manufacturing, and are pumped to the distillation plant for refining.

    Pitch material was sampled from a tap on the line from the bottom of the first steam
 distillation tower to the accumulation tank used to load tank cars. As sampled, the pitch
 was a dark brown, nearly black liquid at approximately 200°F. As it cooled, it became
 extremely viscous (nearly solid).

    Because the pre-cleaned sample jars provided by MRI were destroyed in shipping,
 1-qt sample jars provided by the facility were used as sample containers. The waxed
 cardboard lid liners were discarded, replaced with aluminum foil, and the foil, lids and
 jars were rinsed with hexane and oven dried. The hot pitch was obtained on 9/16/98
 using special equipment supplied by the plant from a tap using procedure MRI S-7. A
 long-handled container holder built to hold a 50-mL disposable paper cup was used to
 obtain each increment of six parallel composite samples. Ten increments were taken  at
 ten-minute intervals.  Two samples (1001 A, 1002A) were taken for analysis in duplicate
 by Galbraith Laboratories for ultimate analysis, metals, halogens, heat content, viscosity,
 and specific gravity; two samples (1005A, 1006A) were taken for analysis in duplicate by
 MRI for PAH, dioxins, and furans; and two samples (1001B,  1002B) were left with the
 plant as shipping backups.
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 3.1.2  Brewery Sludge

    This category included activated sludge from brewery wastes. The sludge is typically
 about 80% solids, of a grey material with peanut butter-like consistency. Activated
 sludge was obtained from Trigen Energy Corporation, in cooperation with Coors Brewing
 Company, Golden, Colorado.

    Sludge was sampled on 9/18/98 using procedure MRI S-7 from a tap. Two samples
 (2001 A, 2002A) were taken for analysis in duplicate by Galbraith Laboratories for
 ultimate analysis, metals, and heat content.  Two samples (2003A, 2004A) were taken for
 analysis in duplicate by Galbraith Laboratories for halogens. Four samples (2001B,
 2002B, 2003B, and 2004B) were left with the plant as shipping backups.
 3.1.3  SIC 28

    This category included rosins, spent wood chips, and wastewater treatment plant
 lagoon sludge, as well as sludge from industrial wastewater treatment of
 acrylonitrile-butadiene-styrene and pesticide production wastes. In all, four materials
 were sampled from this category; two rosins, one spent wood chips, and one wastewater
 treatment sludge.
 Extracted Wood and Scrap Rosins

    Wood and scrap rosins were provided by Hercules Chemical Company, Brunswick,
 Georgia. Wastewater treatment sludge was originally planned to be taken, but was not
 available during this visit.  Crown wood (pine stumps) is shredded and extracted using
 methylisobutylketone (MIBK), and the extracts used for commercial products. The
 extracted wood is mixed with hardwood sawdust (approximately 85% extracted wood
 and 15% hardwood, to adjust moisture and other properties of the fuel blend) and burned
 as fuel in two of the facilities boilers.  Scrap rosins are also mixed with hardwood
 sawdust at approximately a 1:100 ratio and burned in the boilers once or twice per week.

    At the time of sampling on 9/25/98, rosins were not being burned but were being
 accumulated in the scrap rosin bin. Two types of rosins were present, a white powder
 material and a crystalline yellow material. The production manager at the facility
 indicated that the two materials were fundamentally different.

    Scrap rosins were scooped from the scrap rosin bin using procedure MRI S-9. The
 white material was on the south side of the bin, and the yellow material was on the north
 side of the bin and in the middle of the bin.  Two composite samples consisting of
 15 scoops were collected of each material (four composites) in plastic buckets, and
 thoroughly mixed. Each composite was then split into two samples, one split each for
 duplicate chemical analysis by Galbraith Laboratories (3003A, 3003C white rosin;

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 3004A, 3004C yellow rosin) for ultimate analysis, metals, heat content, and halogens; and
 the other held in storage by the facility as a shipping backup (3003B, 3004B white rosin;
 3003D, 3004D yellow rosin).

    Extracted wood was sampled directly from the moving conveyor belt system, just
 prior to the sawdust blending point, using procedure MRI S-9 (scooping). The dark
 brown, warm, moist wood splinters were approximately the size of match sticks, and
 smelled  slightly of MIBK. Ten, approximately equal, increments were taken in each of
 two plastic buckets with a 200 cc plastic scoop for each of two composite samples. The
 lids were replaced on the buckets between increments. Each of the two composite
 samples were thoroughly mixed and split into two samples, one for chemical analysis in
 duplicate (3001 A, 3002A) by Galbraith Laboratories for ultimate analysis, metals, heat
 content, and halogens; and the other (3001B, 3002B) held in storage by the facility as a
 shipping backup.
 ABS/Pesticide Sludge

    Combined industrial sludge was provided by Monsanto Agricultural Company,
 Muscatine, Iowa. The material is the effluent from multiple plant processes, including
 the combined acrylonitrile-butadiene-styrene (ABS) plastic and herbicide production
 WWTP sludges.  At the time the material was sampled on 9/16/98 and 9/17/98, it was
 being fed to the east gun of Boiler No. B-8 at an average feed rate of approximately
 3 gpm.

    Eleven increments were taken for each sample; in all, eight samples were collected.
 Two samples (4003 A, 4004B) were sent to Galbraith Laboratories for duplicate analysis
 for halogens; two samples (4001 A, 4002A) were sent to Galbraith for analysis in
 duplicate for ultimate analysis, metals, and heat content; and four samples (4001B 4002B,
 4003B, 4004A) were held in storage by the facility as a shipping backup.
 3.1.4  SIC 37

    This category included industrial wastewater treatment plant sludge.  Combined
 industrial sludge was provided by General Motors Corporation, Buick Plant, Flint,
 Michigan. The material is the effluent from multiple processes at multiple plants in the
 Flint complex.  At the time the material was sampled on 9/15/98, it was being fed from
 two agitated 30,000 gal day tanks to Boiler No. 2 at the powerhouse at approximately
 16.8 gpm. Upon sitting, the material separated into an oily phase and an aqueous phase
 with entrained solids.

    Eleven increments were taken for each sample; in all, eight samples were collected.
 Two samples (5003A, 5004A) were sent to Galbraith Laboratories for duplicate analysis
 for halogens; two samples (5001 A, 5002A) were sent to Galbraith for analysis in
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 duplicate for ultimate analysis, metals, and heat content; and four samples (5001B,
 5002B, 5003B, and 5004B) were held in storage by the facility as a shipping backup.
 3.1.5  Agricultural Waste

    This category included several waste materials from agricultural product processing
 including com products, rice husks, peach pits, and peanut hulls. In all, five materials
 were sampled from this category; three corn by-products (gluten, germ, and cleanings),
 and one each of the above mentioned.
 Corn By-Products

    Com by-products were provided by Com Products International, Winston-Salem,
 North Carolina. Three different by-products were sampled; com cleanings, com germ,
 and corn gluten. All three materials were obtained from Number 2 yellow dent com.
 Samples were collected on 9/18/98.

    Corn Cleanings: Prior to processing, the com is cleaned in a shaker, which separates
 the corn kernels from broken kernels, dust, cobs, and leaves. This material falls into a
 metal roll-off container and is used as boiler fuel.  Two plastic buckets were used to
 collect samples. Forty-two  increments were taken into each bucket over a 6 x 7 grid,
 from below the surface of the material. Each bucket was thoroughly mixed and
 subsamples withdrawn for duplicate chemical analysis by Galbraith Laboratories (6009A,
 6010A for ultimate analysis, mercury, heat content, and halogens).  Shipping backup
 subsamples (6009B,  601 IB) and subsamples for the facilities' use (6009C, 6011C) were
 also withdrawn. The remainder of each composite sample was then sent to MRI for
 duplicate particle sizing analysis (6011 A, 6012A).

    Corn Germ: During the milling and separation of No. 2 yellow dent com, the germ
 portion of the corn kernel is separated and removed. The  corn germ is then dried in a
 rotary steam tube dryer. After drying, the com germ is shipped to a processor where com
 oil is removed. Any  corn germ that is deemed unfit for corn oil processing is collected
 for use as boiler fuel. Two plastic buckets were used to collect samples. Twenty-
 five increments were taken into each bucket over a 5 x 5  grid, from below the surface of
 the material. Each bucket was thoroughly mixed and subsamples withdrawn for duplicate
 chemical analysis by Galbraith Laboratories (6005A, 6006A) for ultimate analysis,
 mercury, heat content, and halogens. Shipping backup subsamples (6005B, 6007B) and
 subsamples for the facilities' use (6005C, 6007C) were also withdrawn. The remainder
 of each composite sample was then sent to MRI for duplicate particle sizing analysis
 (6007A,  6008A).

    Corn Gluten:  After the com kernel is milled and the germ is removed, additional
 parts of the corn kernel, including the hull (crude fiber), gluten (high protein material),

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 and starch are milled and separated. Corn gluten feed, which is manufactured from the
 separated crude corn fiber, is sold as feed for animals. Any com gluten feed that is
 determined to be unfit for use as an animal feed is collected for use as a boiler fuel.
 Twenty-five increments were taken into each bucket over a 5 x 5 grid, from below the
 surface of the material.  Each bucket was thoroughly mixed and subsamples withdrawn
 for duplicate chemical analysis by Galbraith Laboratories (6001A, 6002A) for ultimate
 analysis, mercury, heat content, and halogens. A shipping backup subsample (600IB)
 and a subsample for the facilities' use (6001C) were also withdrawn. The remainder of
 each composite sample (6003A, 6004A) was then sent to MRI  for duplicate particle
 sizing analysis.
 Rice Husks

    Rice husks were provided by Agrilectric Power, Inc., Lake Charles, Louisiana.  Rice
 husks are removed from the rice at processing plants, then transferred by pneumatic lines
 or shipped by truck to the facility, where they are used as fuel.

    The husks were sampled from a pneumatic feed line prior to the fuel inlet to the
 boilers using procedure MRI S-9 (scooping). A hinged clean out door was unfastened in
 the down-flowing portion of the feed line, which was under positive pressure. The feed
 line was completely filled with flowing rice husks, which were collected in a clean
 ceramic sample collector supplied by the facility. Ten increments were collected at
 ten-minute intervals into two sets of zipper locking plastic bags (due to rain on-site while
 the samples were being collected on 9/14/98). Each set of bags was turned inside out and
 flicked into separate, new, plastic 5-gal buckets and subsampled to provide samples for
 duplicate chemical analysis by Galbraith Laboratories (7001A and 7002A) for ultimate
 analysis, mercury, heat content, and halogens; and the remainder of the material (7003A
 and 7004A) was transferred to 1-gal buckets with lids for duplicate particle sizing at MRI.
 Peach Pits

    Peach pits were provided by Tri-Valley Growers of Modesto, California. The peach
 pits are dried and then stored outdoors in multiple piles and are the only fuel source for
 the boiler. Samples were collected on 9/28/98.

    Thirty two increments were taken into plastic buckets from evenly spaced positions
 below the surface of the piles for each of two samples.  The samples were then
 thoroughly mixed and subsamples withdrawn for duplicate chemical analysis by
 Galbraith Laboratories (8001A, 8002A) for ultimate analysis, metals, heat content, and
 halogens. Additional subsamples were obtained for the facility's use (8001C) and
 shipping backup (8001B, 8002B, 8003B, and 8004B) which were placed in storage at the
 facility.  A final subsample (8003A and 8004A) was submitted to MRI for duplicate
 particle sizing.
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 Peanut Hulls

     Pelletized peanut hulls were provided by Georgia Pacific Great Southern Paper
 Company, Inc., Cedar Springs, Georgia.  The peanut hulls are fed to process boilers on a
 conveyor belt system which also handles shredded tires. At the time of sampling on
 9/23/98, the peanut hulls were stored outdoors in a concrete bin in four piles, which
 smelled like vinegar.

     Fifty increments were taken into plastic buckets  from evenly spaced positions below
 the surface of the piles for each of two samples. The samples were then mixed
 thoroughly and each sample was subsampled to provide samples to Galbraith
 Laboratories (9001 A, 9002A) for duplicate chemical analysis for ultimate analysis,
 metals, heat content, and halogens; for facilities' use (9001C); and shipping backup
 samples (9001B, 9002B) which were placed in storage at the facility. The remaining
 portion of each composite sample (9003A, 9004A) was submitted to MRI for duplicate
 particle sizing.
 3.1.6   PVC Coatings

     Polyvinyl chloride (PVC) coatings were provided by Rack Processing Company,
 Incorporated, of Morraine, Ohio (near Dayton). PVC rack coatings are a thick resilient
 plastic coating which is used to protect and electrically insulate electroplating racks
 during plating operation. A 5-7 mm-thick PVC coating is applied and when the useful
 lifespan of the coating comes to an end, the racks are recycled by thermally stripping
 them in  a gas-fired oven. Samples were collected on 9/24/98.

     The  rack coatings were discolored from use, and had a thin layer of oxidized material
 ranging  in color from almost white to gray, and shades of pink or blue. During sampling,
 the coatings were found to be extremely tough and durable and were difficult to remove
 manually.  The use of plastic implements to remove the coatings proved to be futile, so
 sharp stainless steel blades were used to carve pieces of the coatings from the racks
 without  scraping into the metal structure of the racks.  Four differently discolored racks
 were sampled (10001 A, 10001B, 10002A, and 10002B), and each of the samples sent to
 Galbraith Laboratories for single analyses for ultimate analysis, metals, heat content, and
 halogens (not enough material could be obtained to allow for duplicate analysis).
 3.1.7  Non-PVC Coatings

    Non-PVC coatings were supplied by Rack Coating Co., Inc., of Piqua, Ohio, which
 removes non-PVC coatings from defectively coated parts such as filler tubes and oil pans
 using gas-fired ovens. Other metal objects such as paint booth grates are also treated to
 remove built up coating materials. Samples were collected on 9/22/98. Three coating
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 materials were sampled. Duplicate samples of each coating were sent to Galbraith
 Laboratories for duplicate analyses and for storage at the facility as a shipping backup, or
 for archive at MRI.

    The first coating sent to Galbraith (11001A, 11002A) for ultimate analysis, metals,
 heat content, and halogens; and kept in storage (11001B, 11002B) was a dark gray, or
 black, primer applied to metal tubes. The coating did not meet application specifications,
 and had formed hard globs, which were broken off by hand wearing nitrile gloves. Ten
 globs were broken off of separate pipes from the bin of pipes to be treated for each
 sample. Attempts at chemical removal of two additional coated pipes (with thinner
 coatings) on-site using xylene, toluene, methylene chloride, and methylethylketone
 proved unsuccessful. These samples (11003A, 11004A) were taken to MRI and a small
 section removed by cutting with a tubing cutter and punching a '/2-in diameter piece for
 duplicate elemental analysis by X-ray diffraction.

    The second coating sent to Galbraith (11001C, 11002C) for ultimate analysis, metals,
 heat content, and halogens; and kept in storage (11001D, 11002D) was a clear to white
 resilient "acrylic" type of material which had formed a one  to two cm-thick buildup on
 metal ventilation grates. This material was peeled off of the grates using sharp plastic
 trowels. Ten chunks were removed from separate grates for each sample.

    The third coating sent to Galbraith (11003B, 11004B) for ultimate analysis, metals,
 heat content, and halogens; and kept in storage (11003C, 11004C) was similar to the
 white material, but was bright red in color.  It was also peeled off the grates with sharp
 plastic trowels. Ten chunks were removed from separate grates for each sample.
 3.2 Analytical Methods Summary

 3.2.1   PAH Procedures

    PAH sample preparation and results are briefly discussed here.  The samples were a
 dark brown viscous material that were unpourable at room temperature. With warming,
 the samples were liquefied enough to aliquot with a disposable serological pipet. At this
 point, the material was stringy, must like a thick molasses material. The analyst
 attempted to weigh a Ig aliquot of each sample in  duplicate into a 40-mL vial.  In some
 cases, the sample size was closer to 2 g.

    The 1-g samples were fortified with 25-/xg d,0fluorene and dlo pryene as surrogates to
 assess the affect of the matrix on cleanup and GC/MS analysis. Other quality control
 samples included a solvent only method blank, a corn oil laboratory control blank and a
 com oil laboratory control spiked sample fortified with 5 jug of the target PAHs.

    The approximately 1-g samples and QC samples were diluted with methylene
 chloride and put through size exclusion gel permeation chromatography (GPC) cleanup
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 using a column packed with SX-3 biobeads.  The system was calibrated with corn oil and
 a standard mixture containing a phthalate, methoxychlor, perylene, and sulfur. The
 collect fraction was set to isolate the PAHs from the corn oil calibration standard. A UV
 detector was interfaced to the automated GPC cleanup to monitor response for potential
 interferences during collection of the fraction designated for analysis. The UV trace
 indicated incomplete removal of the matrix.  The molecular weight of the major
 contaminants were lighter than the corn oil used for calibration of the instrument, and the
 UV showed that these interferences overlapped in the same fraction as the target analytes.
 Therefore, a serial GPC cleanup was performed to reduce the oil interferences.  The GPC
 cleanup removed the dark color of the samples, and the final extracts were a light amber
 color.  The dilution factor of the extracts for GC/MS analysis was 10 mL methylene
 chloride for each 1 g sample.

    The sample extracts and quality control samples were analyzed according to
 modifications of EPA Method 8270.  The modifications included a lower calibration
 range than required by the method and the use of deuterium labeled PAHs as surrogates.
 The internal standard recommended in EPA Method 8270 was added to a 1.0 mL aliquot
 of the extracts just before analysis.
 Results

    None of the samples contained PAHs above instrumental reporting limit based on the
 lowest calibration standard (0.1 /ig/mL). The sample detection limit was 4 /ig g/g based
 on the sample size and dilution factor. The target PAH sample results are summarized in
 Section 4.

    The quality control results were within the acceptable limits.  The two surrogates
 recovered within the 60% to 120% recovery objective.  Recoveries of the native PAHs
 from the corn oil laboratory control sample (LCS) were good with the exception of the
 latest eluting compound, benzo(g,/z,/)perylene. LCSs were subjected to the same GPC
 cleanup and analysis as test sample.
 3.2.2  Dioxin/Furan Procedures

    Dioxin and furan sample preparation and results are briefly discussed here. Samples
 were heated and weighed out in duplicate in two weight groups (10 grams and 1 gram) for
 dioxin/furan analysis. A mineral oil method blank (MB), a mineral oil laboratory control
 sample (LCS), and a solvent blank were also prepared for both weight groups. All
 samples were fortified with appropriate quantitation standards. The 1-gram samples were
 archived (to be used if the matrix of the 10-gram samples proved to be too difficult). The
 10-gram samples were diluted in hexane, fortified with 37Cl-2,3,7,8- TCDD clean-up
 standard and subjected to a  2-hour acid silica slurry step (40%H2SO4 on silica gel)
 followed by a acid/neutral silica column. Heavy reactions with both the slurry and

MRI-A£D\R4951 WA2-Ol.wpd                        3-8

-------
 column steps were noted.  The extract was then concentrated for carbon column clean up.
 It was discovered that mineral oil used for the MB and LCS was not sufficiently cleaned
 in the silica steps and would not successfully go through the rest of the clean-up
 procedures.  The MB and the LCS were re-prepared using corn oil for both weight
 groups. The solvent blank originally started with the samples remained the same. The re-
 prepared LCS and Method Blank were put through the same silica steps and continued
 through a .5  gram 18% Carbopack C carbon column, and a neutral alumina column with
 the rest of the sample.  All samples were concentrated under prepurified nitrogen to
 approximately 100 /iL.  Twenty microliters of recovery standard was added and
 evaporation continued to a final volume of 20 /xL. All procedures are documented in
 detail in SOP MRI-5201, Revision 1.

    After analysis of the 10-gram sample, it was decided that the 1-gram samples should
 be analyzed to reduce matrix effects. The 1-gram samples were prepared with the corn
 oil MB and LCS in the same manner discussed above. The  samples were analyzed
 following the requirements in SOP MRI-5405 and USEPA Method 8290.
 Results

    The data was reduced using the Excalibur 2.1 program.  The initial calibration was
 used to generate relative response factors for sample quantitation.  USEPA Method 8290
 quantitation was followed to quantitate native concentrations with one exception. After
 looking over the sample raw data, it was noticed that the 13C-l,2,3,7,8,9-HxCDF
 recovered extremely well. In Method 8290, this is not the labeled analog used for native
 quantitation. A deviation from the method was performed to quantitate the native
 1,2,3,7,8,9-HxCDF from its own labeled analog which gave much better results for that
 isomer. The initial calibration curve was re-generated to produce the new response
 factor.  Excalibur output files and a spreadsheet showing final concentrations has been
 included in the data package.

    The 1-gram sample data is a better data set due to the significantly better labeled
 analog recovery.  Both data sets for 10- and 1-gram samples are included in
 Appendix D-l. Dioxin and furan sample results for 1-gram sample are summarized in
 Section 4.
MR1-AED\R495I WA2-01,wpd
                                       3-9

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 Section  4.

 Test  Results


 4.1  Objectives and Test Matrix

    The objectives of this test were to characterize the various materials combusted in
 boilers by obtaining representative samples and analyzing them for the designated
 parameters. The data quality objectives and criteria are discussed in Section 5, Internal
 QA/QC Activities. The sampling and analysis protocol is summarized in Table 4-1, and
 includes the types and numbers of samples taken, the facility locations, and sampling
 frequencies, sample matrices, measurement parameters of interest. Additional sample
 information is provided in the Appendix A, Sample Traceability Data. Sampling and
 analytical methods are listed below.

    Samples were obtained using MRI operating procedures, which are derived from
 EPA-600/8-84-002, Sampling and Analysis Methods for Hazardous Waste Combustion,
 and conform to SW-846 Chapter Nine.  ASTM methods used for guidance were as
 follows:

    •   ASTM D 140, Standard Practice for Sampling Bituminous Materials;

    •   ASTM D 346, Standard Practice for Collection and Preparation of Coke Samples
        for Laboratory Analysis;

    •   ASTM D 2234, Standard Test Methods for Collection of a Gross Sample of Coal,
        and;

    •   ASTM D 4057, Standard Practice for Manual Sampling of Petroleum Products.

    Analytical Methods used were as follows:

     • All materials sampled were submitted to Galbraith Laboratories (Knoxville, TN)
       for Ultimate Analysis by ASTM 3176; sample preparation by ASTM D 2013.
       Ultimate analysis consists of the following determinations:

       1.   Carbon and hydrogen by controlled combustion according to ASTM
            Methods D 3178, or E777,

       2.   Sulfur by Eschka Method according to ASTM D 3177, or by bomb washing
            according to ASTM D 775,

       3.   Ash by controlled combustion according to ASTM D 3174, or D1102

       4.   Moisture by drying  according to ASTM D 3173, or D 871

MRI-AED\R495I WA2-Ol.wpii                       4-1

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        5.    Oxygen by difference. There is no satisfactory ASTM test method for
             determining oxygen, and it was calculated by subtracting the sum of other
             components of the ultimate analysis;

        All materials sampled were submitted to Galbraith for Metals Analysis by
        SW 846 6010 (all elements except mercury), SW-846 7470 (for mercury, liquid
        samples), and SW-846-7471 (mercury, for solid samples). Samples were
        prepared according to SW-846 Method 3050A. Metals analyzed were: arsenic,
        beryllium, antimony, cadmium, total chromium, copper, lead, magnesium,
        mercury, nickel, manganese, selenium, silver, zinc, aluminum, iron, and
        potassium;

        All materials sampled were submitted to Galbraith for Heat Content (Btu)
        analysis using a bomb calorimeter according to ASTM D 1989;

        All materials sampled were submitted to Galbraith for Halogens (Chlorine,
        Bromine, Fluorine, and Iodine) analysis according to SW-846 5050/9056 for
        Chlorine and Bromine, ASTM D 3761 for Fluorine, and ASTM D 3869 for
        Iodine;

        All agricultural waste materials (corn by-products, rice husks, peach pits, and
        peanut hulls) sampled were submitted to MRI for particle sizing by sieve analysis
        according to Section C of AP-42;

        Pitch samples from tall oil distillation were submitted to Galbraith for Viscosity
        determination by using a capillary viscometer according to ASTM D 445;

        Pitch samples from tall oil distillation were submitted to Galbraith for Specific
        Gravity determination by using a glass hydrometer according to ASTM D  1298;

        Pitch samples from tall oil distillation were submitted to MRI for Dioxins and
        Furans analysis by using GC/MS according to SW-846 8290.  Dioxins and
        Furans include all tetra- through octa- congener groups and specifically for all
        2,3,7,8-isomers;

        Pitch samples from tall oil distillation were submitted to MRI for Polyaromatic
        Hydrocarbons (PAHs) analysis by using GC/MS according to SW-846 8270C.
        PAHs include all those identified in the referenced method.
MRI-AED\R495I WA2-Ol.wpd                         4-2

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          Table 4-1. Samples Analyzed for Fuel Material Characterization
Matrix
Sludge
Solids
Category
Tall Oils and
Turpentine
Sludges
Brewery
Sludge
SIC 28
SIC 37
Ag Waste
pvc coatings
non-pvc
coatings
Facility
Sylvachem Corp.
Port St Joe, FL
(1 material)
Trigen
Golden, CO
(1 material)
Hercules
Bmnswick,GA
(3 materials)
Monsanto
MuscatineJA
(1 material)
NAO Flint
Flint.MI
(1 material)
Com Products
Winston-Salem.NC
(3 materials)
Agrilectric
LakeChas.LA
(1 material)
Tri-Valley Growers
Modesto, CA
(1 material)
GP
Cedar Springs, GA
(1 material)
Rack Proc.
Dayton, OH
(1 material)
Rack Proc.
Piqua, OH
(1 material)
Description
pitch, coproduct of tall
oil distillation
activated sludge from
brewery waste
wood chips
white rosin
yellow rosin
combined sludge from
ABS/ herbicide mfg. +
plastic solids removed
from ABS wastewater
industrial wastewater
treatment plant sludge
corn gluten feed,
com germ,
and com cleanings
rice husks
peach pits
peanut hulls
pvc rack coatings
non-pvc rack coatings
Sample Nos.
1005A, 1006A, 1001 A,
1002A
2001 A, 2002A, 2003A,
2004A
3001 A, 3002A,
3003A, 3003C,
3004A, 3004C
4001 A, 4002A, 4003A,
4004B
5001 A, 5002A, 5003A,
5004A
6001 A, 6002A, 6003A,
6004A
6005A, 6006A, 6007A,
6008A,
6009A, 601 OA, 6011 A,
6012A
7001 A, 7002A, 7003A,
7004A
8001 A, 802A, 8003A,
8004A
9001 A, 9002A, 9003A,
9004A
10001 A, 10001B,
10002A
11001A, 11001C,
11002A, 11002C,
11003B, 11004B
Parameters
+Ultimate
-i-Metals
+Heat Content
-t-Halogens
+Viscosity
+Specific Grav.
+Dioxin/Furan
+PAHS
-t-Ultimate
+Metals
+Heat Content
+Halogens
^Ultimate
•fMetals
+Heat Content
+Halogens
+Particle size
+Ultimate
+Metals
+Heat Content
+Halogens
4.2 Test Changes and Problems

4.2.1   Sample Collection

   Samples were obtained as previously indicated in Section 3.1 and Table 1-1. With the
following exceptions sample collection was as indicated in the test plan and QA plan.
MRI-AED\R495I WA2-Ol.wpd
                                    4-3

-------
       Sample jars for sampling pitch from tall oils at Sylvachem facility were destroyed
       in shipping. One-quart, glass sample jars provided by the facility were used
       instead. These containers were cleaned and hexane-rinsed according to the QA
       plan. Additionally, because the pitch is so hot coming from the heated tank
       (200°F) that it would instantly crack or shatter any glass it contacted, an unwaxed
       paper sample transfer container was used to obtain sample aliquots from the tap
       for placement into the pre-cleaned glass jars.

       The test plan and QA plan indicated that SIC 28 material obtained from Hercules
       would include wood, rosins, and industrial wastewater treatment sludge. At the
       time of the visit to this facility, no industrial wastewater treatment sludge was
       available for collection.

       Attempts at chemical removal of two additional coated pipes (with thinner
       coatings) on-site using xylene, toluene, methylene chloride,  and
       methylethylketone proved unsuccessful. These samples (11003A, 11004A) were
       taken to MRI and a small section removed for metals analysis by X-ray
       diffraction.

       Due to the difficulty encountered in obtaining an adequate sample amount of PVC
       coatings at the Rack Processing Co., in Dayton, Ohio, only enough was collected
       to allow the performance of singular analysis (10001 A,  1000IB). The coating had
       to be manually scraped from the substrate and was extremely difficult to remove.

       No sample traceability was performed on samples left at each facility for a
       shipping backup, nor for samples left at two facilities for internal facility analyses.
4.2.2  Sample Analysis

   Samples were analyzed as previously indicated in Section 4.1 and Table 1-1. With the
following exceptions sample analysis was as indicated in the test plan and QA plan.

       Sample 10002A analyzed in duplicate due to lab contamination of 10002B with
       stannous chloride. Sample no. 10002B archived (not analyzed).

   •   Samples numbered 10001A and 10001B were not analyzed in duplicate due to the
       difficulty encountered in obtaining enough quantity for this.

   •   Attempts at chemical removal of two additional coated pipes (with thinner
       coatings) on-site using xylene, toluene, methylene chloride, and
       methylethylketone proved unsuccessful. These samples (11003A, 11004A) were
       taken to MRI and a small section removed for metals analysis by X-ray
       diffraction.
MR1-ABD\R4951 WA2-0!.wpd                        4-4

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4.3  Test Results

    All test results are presented and briefly discussed in this section. Samples were
analyzed by the methods discussed in Section 4.1 of this report.
4.3.1   General Feed Characteristics

    General feed characteristics analyzed included: water, carbon, hydrogen, nitrogen,
sulfur, ash, and oxygen, heat content, specific gravity, halogens, and particle size.
Table 4-2 provides results of all feed characteristics analyses, except for halogens and
particle size.  Halogens and particle size results are provided in Tables 4-3 and 4-4.

    Particle sizing results are based on sieve diameters listed below. Any particulate
matter found in the pan would have diameters less than that of the smallest mesh used (in
this case, 200 mesh, or 0.075 mm).

                    Mesh#                  Sieve Opening (mm)
                      4                          4.75
                     10                          2.00
                     20                          0.850
                     40                          0.425
                    100                          0.150
                    200                          0.075
                    pan                         <0.075
4.3.2   Metals Analysis Results

    Multiple metals analyzed include: aluminum (Al), antimony (Sb), arsenic (As),
beryllium (Be), cadmium (Cd), chromium (Cr), copper (Cu), iron (Fe), lead (Pb),
magnesium (Mg), manganese (Mn), nickel (Ni), potassium (K), selenium (Se), silver (Ag),
sodium (Na), vanadium (V), zinc (Zn), and mercury (Hg). Results for all multiple metals,
except for mercury are shown in Table 4-5a.  Mercury results are shown in Table 4-5b.
The values given are to be considered preliminary results pending completion of an
assessment of the supporting data.
4.3.3   Organic Analysis Results

   The organic compounds analyzed included polyaromatic compounds (PAHs) and
dioxins/furans.  Results of the PAH analysis are shown in Table 4-6. Results of the
dioxin/furan analysis are shown in Table 4-7.  The target analytes are shown in the first
column of each  table.
MRI-AEDVR4951 WA2-OI.wpcl
                                       4-5

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                                                                                          a,b
Sample Water Carbon
Number (%) (%)
Pitch
1001 A 0.041 79.91
1002A 0.050 78.16
1001 A Density 1.017
1002A (g/cm3) -i 023
Brewery Sludge
2001 A 95.28 1.76
2002A 95.43 1 .69
Wood Chips
3001 A 49.33 23.61
3002A 56.89 19.28
Wood Chips/Rosins d
3003A8 5.51 83.37
3003C" 0.87 79.79
3004A6 11.02 77.51
3004C9 2.45 77.69
SIC 28, Industrial Sludges
4001 A 96.48 1.86
4002A 96.44 1 .82
SIC 37, Industrial Sludges
5001 A 97.53 1.53
5002A 97.31 1 .69
Agricultural/Corn Products
6001 A 13.63 38.31
6002A 13.82 37.83
6005A 47.41 32.54
6006A 47.39 32.00
6009A 13.87 40.08
601 OA 13.41 40.17
Agricultural/Rice Husks
7001 A 8.68 36.40
7002A 8.79 35.33
Agricultural/Peach Pits
8001 A 11.29 45.96
8002A 1 1 .59 45.73
Agricultural/Peanut Hulls
9001 A 11.72 44.16
9002A 11.86 44.18
Hydrogen
10.76
10.65


10.85
10.87

8.36
8.78

10.66
10.23
10.64
10.18

10.94
10.93

11.09
11.09

7.17
7.01
10.20
10.17
7.17
7.21

5.94
5.85

6.79
6.77

6.65
6.73
Nitrogen
<0.50
<0.50
Viscosity
(cSt) @

0.27
0.26

0.26
0.22

<0.47
<0.50
<0.44
<0.49

0.27
0.27

0.027
0.031

3.05
3.14
1.18
1.08
0.51
0.57

0.55
0.54

<0.44
<0.44

1.12
1.10
Sulfur
0.70
0.63
207.23
202.46

0.05
0.04

0.01
0.0063

0.08
0.10
0.00
0.01

0.027
0.027

0.026
0.03

0.43
0.41
0.12
0.12
0.07
0.06

0.06
0.06

0.043
0.036

0.10
0.09
Ash
1.26
1.44

1.40
1.38

6.00
4.76

0.23
0.29
0.27
0.34

0.50
0.52

0.47
0.51

7.17
7.12
0.66
0.62
1.06
1.18

16.78
16.80

1.31
1.27

2.78
2.59
Oxygen
6.88
7.13

0.96
0.93

17.91
16.38

0.29
8.31
1.34
9.10

0.61
0.67

0.14
0.15

31.57
32.05
13.16
13.88
38.63
38.77

32.48
33.51

35.43
35.45

34.75
34.75
HHV
(Btu/lb)
17000
17065

330
285C

4175
3643

13751
16020
5100
13328

357
347

346
383

7014
6820
6605
6574
6878
6805

5794
6207

8033
8125

7548
7612
MRI.A£D\R4951 WA 2-01 wpd
                                                               4-6

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                                  Table 4-2 (Continued)
Sample
Number
PVC Coatings
10001Ae
10001B
10002A'
Water Carbon Hydrogen Nitrogen Sulfur

3.56
4.79
3.07
Non-PVC Coatings
11001A" 2.30
11002A0 2.06
11001C
11002C
11003B
11004B
7.75
7.01
11.79
10.61

46.92
44.60
46.66
13.41
11.80
57.61
58.47
59.40
57.56

6.76
6.52
6.64
1.73
1.49
9.67
9.78
8.30
8.30

<0.48
<0.48
<0.48
<0.49
<0.50
3.83
5.44
4.64
4.86

0.14
0.13
0.06
0.10
0.11
0.42
0.21
0.15
0.21
Ash Oxygen HHV
(%) (%) (Btu/lb)

2.53
2.58
2.66
92.04°
92.71°
0.26
0.60
0.09
0.10

4.53
37.98
3.63
g
g
21.31
19.26
16.95
19.50

10008
9489
10046
4051
3875
11643
11932
11554
11062
     Feed Characteristics in this table are limited to: Ultimate Analysis, heat content, specific
     gravity, viscosity.
     Halogens and particle size are found in the following tables, respectively.
     Results shown are averages of duplicate analyses, except where noted.
     Result is single analysis, there was insufficient sample to perform HHV in duplicate.
     Results for all Rosins are single analysis to provide more information on homogeneity.
     Except for moisture, results shown are for single analysis only.
     Sample 10002A was analyzed in duplicate due to stannous chloride contamination of
     10002B.
     Ash results exhibit potential high bias due to high levels of stannous chloride contamination.
     This also affects oxygen result since it is a calculated value.
MRI-AED\R495I WA2-Ol.v|xl
                                            4-7

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                             Table 4-3. Halogens (mg/L)a
Sample No
Pitch
1001 A
1002A
Brewery Sludge0
2003A
2004A
Wood Chips
3001 A
3002A
3003A d
3003C d
3004A d
3004C "
Chlorine

<98
<95

<96
141

<51
<44
<95
140
<89
<98
Analysis
Fluorine Bromine

b
76
b
10

<10
<9

9
41
<10
<10
29
<9

<98
<95

<96
<100

<51
<44
<95
<99
<89
<98
Iodine

4
3

<1
<1

<1
2
3
5
<2
<2
SIC 28 Industrial Sludge0
4003A
4004B
SIC 37 Industrial
5003A
5004A
Agricultural/Corn
6001A

6002A
6005A
6006A
6009A
601 OA
Agricultural/Rice
7001A
7002A
592
554
Sludge0
160
170
Products
1,840

1,695
94
73
1,425
1,275
Husks
840
947
< 12
<10

15
30

b
<15
b
92
<9
41
20
<15

20
18
<98
<98

<96
<100

<160

<170
<100
<100
<160
<180

<92
<85
31
26

100
30

3

<2
<1
4
4
3

2.74
<2
MRl-AED\R4951 W A 2-01 wpd
                                         4-8

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                                     Table 4-3 (Continued)
Sample No Chlorine
Agricultural/Peach Pits

8001 A <89

8002A < 88
Agricultural/Peanut Hulls
9001 A1 117
9002A1 118
PVC Coatings
10001 A1
10001B 346,350
10002A0 366,450
Non-PVC Coatings

11 001 A 620

11002A 650
h
1 1 001 C 330
h
11002C 150
11003B <95
11004B 395
Analysis
Fluorine Bromine

b
23
b
81

16
45


130
36

b
2100
b
260

<17

<17
17
36


<89

<88

<170
<170


<96
<180


<94

<95

<91

<94
<95
<93
Iodine


4

2

19
8


10
<2


<2

7

<2

<2
5
4
             a Results shown are for duplicate analysis, unless otherwise indicated.
             b Reanalysis confirms original result shown.
             0 An additional set of samples (contained in sample bottles for different analyses
               and inappropriate for halides) were inadvertently analyzed. These data are
               provided in Appendix C, but are not representative of the feed and should not
               be used.
             d Results for all rosins are single analysis only to provide more information on
               homogeneity.
             8 High detection limit due to presence of high levels of nitrate.
             '  Results are for single analysis only.
             a Sample 10002A analyzed in duplicate due to stannous chloride contamination
               of 10002B.
             h Reanalysis is slightly lower than original result shown; appears to be non-
               homogenous sample.
MRI-AED\R495I WA2-01.wpd
                                                4-9

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Sample
No.
4
Corn Gluten
6003A 0.7
6004A 2.9
Corn Germ
6007A 1 .7
6008 A 2.1
Corn Cleanings
6011 A 70.4
601 2A 63.7
Rice Husks
7003A 0.0
7004A 0.0
Peach Pits
8003A 94.8
8004A 96.2
Peanut Hulls
9003A 91.6
9004A 90.8
Analysis
10

27.7
38.8

76.3
75.6
13.8
15.5

0.0
0.1

2.1
1.4

2.2
2.6
?n

40.9
38.0

18.7
18.6
10.9
13.6

7.4
8.7

1.1
0.9

3.2
3.4
40

18.0
11.9

2.5
2.5
2.9
4.0

45.2
42.1

0.6
0.5

1.7
1.8
Weight % per Screen Mesh
Duplicate Analysis
100

11.7
7.5

0.5
0.7
1.3
2.3

30.0
32.1

0.7
0.6

0.9
1.0
POO

0.7
0.5

0.2
0.3
0.5
0.6

6.2
7.0

0.3
0.3

0.3
0.2


0.3
0.3

0.2
0.1
0.3
0.4

11.2
10.0

0.3
0.3

0.1
0.1
4 10

0.6 28.9
2.8 41.1

1.4 76.0
1.8 75.3
67.8 14.0
65.9 13.7

0.0 0.0
0.0 0.1

95.8 1.4
95.7 1.6

91.4 2.2
89.1 2.4
20 40

40.4 17.7
37.2 11.3

19.2 2.4
18.9 2.7
12.6 3.5
12.8 4.0

8.5 43.1
8.2 43.0

1.0 0.6
0.9 0.6

3.4 1 .7
4.4 2.5
100

11.3
7.2

0.6
0.8
1.0
2.3

30.3
31.6

0.6
0.6

0.9
1.2
200

0.6
0.4

0.3
0.4
0.8
0.5

7.0
6.4

0.2
0.3

0.2
0.3
pan

0.3
0.1

0.0
0.1
0.3
0.8

11.1
10.8

0.3
0.3

0.1
0.1
MR1-AEDVR495I WA2-Ol.wpd
                                                         4-10

-------
                            Table 4-5a. Multiple Metals Results, Excluding Mercury (ppm)
Sample
Number Al
Pitch
1001A 8
9
1002A 10
9
Brewery Sludge
2001 A 41
37
2002A 37
35
Wood Chips
3001 A 660
510
3002A 560
560
White Rosin
3003A 26
3003C 63
Yellow Rosin
3004A 33
3004C 72
Sb

<7
<6
<9
<10

<0.4
<0.4
<0.4
<0.4

<5
<5
<4
<4

<9
<10

<8
<10
As

<7
<6
<8"
<7

<0.4
<0.4
<0.4
<0.4

<5
<5
<4
<4

<9
<10

<8
< 10
Be

<4
<4
<5
<4

<0.2
<0.2
<0.2
<0.2

<3
<2
<2
<2

<4
<5

<4
<5
Cd

<4
<4
<5
<4

<0.2
<0.2
<0.2
<0.2

<3
<2
<2
<2

<4
<5

<4
<5
Cr Cu

<4 <4
<4 <4
<5 <5
<4 <4

1.4 4.5
1.2 4.5
1.0 4
1.0 4

8 <3
8 <2
9 <2
9 <2

<4 <4
<5 <5

<4 <4
<5 <5
Fe

330
330
340
340

94
94
92
92

610
610
600
560

24
65

47
120
Pb

<7
<6
<8
<7

<0.4
<0.4
<0.4
<0.4

<5
<5
<4
<4

<9
<10

<8
<10
Mg

11
10
13
10

730
780
860
860

78
76
72
69

10
35

14
37
Mn

13
13
13
13

1.5
1.5
1.5
1.5

7
8
7
7

<4
<5

<4
<5
Ni

<4
<4
<5
<4

0.7
0.7
0.9
0.6

<3
<2
3
3

<4
<5

<4
<5
K

270
260
270
270

150
160
150
160

60
59
54
55

14
8

15
11
Se

<7
<4
<8
<7

<0.4
<0.4
<0.4
<0.4

<5
<5
<4
<4

<9
<10

<8
<10
Ag

< 1
<1
< 1
< 1

<0.04
<0.05
<0.05
<0.05

<0.5
<0.5
<0.5
<0.5

< 1
< 1

< 1
< 1
Na

3700
3700
3700
3800

90
94
92
96

123
121
120
100

140
180

130
190
V

<4
<4
<5
<4

0.6
0.5
0.5
0.5

<3
<2
<2
<2

<4
<5

<4
<5
Zn

9
8
10
8

3.6
3.9
3.4
3.3

4
4
4
4

7
30

<4
23
SIC 28, Industrial Sludges
4001 A 63
63
4002A 50
50
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
0.96 0.67
0.93 0.66
1.0 0.68
1.0 0.69
230
220
220
220
<0.3
<0.3
<0.3
<0.3
42
39
36
39
4
4
4
4
2
2
1.9
1.9
36
37
35
35
<0.3
<0.3
<0.3
<0.3
<0.04
<0.03
<0.04
<0.04
1000
930
1000
1000
<0.2
<0.2
<0.2
<0.2
3
3
4
4
SIC 27, Industrial sludges
5001 A 350
5002A 400
<0.5
<1
<0.5
<1
<0.3
<0.5
<0.3
<0.5
2.6 6.3
3.1 7.4
440
560
12
14
210
230
47
59
11
13
42
40
<0.5
<1
<0.05
0.12
170
140
<0.3
<0.5
59
78
MRI-AEDVR495I WA2-Ol.wpd
                                                         4-11

-------
                                                        Table 4-5a (Continued)
Sample
Number Al
Agricultural/Peanut
9001 A 530
350
9002A 410
400
PVC Coatings
10001A 14
10001B 13
13
10002A 11
15
Non-PVC Coatings
11001A 140
140
11002A 100
99
11001C 79
130
11002C 130
130
11003B 6
6
11004B 7
7

11003A 0.040
11004A 0.040
Sb
As
Be
Cd Cr Cu Fe
Pb
Mg
Mn
Ni
K Se
Ag
Na
V
Zn
Products
<9
<6
<9
<7

<7
<7
<7
<7
<7

<9b
35"
< 10
<10
<8
<9
<9
<9
<7
<7
<7
<6



<9
<6
<9
<7

<7
<7
<7
<7
<7

<9
<9
< 10
<10
<8
<9
<9
<9
<7
<7
<7
<6
By X-Ray


<4
<4
<4
<4

<5
<5
<4
<4
<4

<4
<5
<5
<5
<4
<4
<5
<5
<5
<4
<4
<4
< 4 < 4 < 4 350
<4 <4 <4 310
<4 <4 <4 320
<4 <4 <4 330

10 71 79 14
<5 150 130 19
<4 160 140 19
<4 98 99 33
6 98 99 33

<4 0.64 9 0.18
<5 0.64 9 0.20
<5 0.66 8 550
<5 0.65 7 540
<4 <4 <4 55
<4 <4 <4 88
< 5 < 5 < 5 86
<5 <5 <5 130
<5 <5 <5 6
<4 <4 <4 6
<4 <4 <4 9
<4 <4 <4 10
Fluorescence Spectrometry (XRF),


0.030 1.990
0.029 2.008
<9
<6
<9
<7

<7
<7
<7
<7
13

<9
<9
<10
<10
<8
<9
<9
<9
<7
<7
<7
<6
mg/cm2


790
770
730
790

34
44
41
34
42

0.11
0.11
0.12
0.11
14
16
63
75
5
<5
7
9

<0.001
<0.001
31
28
30
29

<5
<5
<4
<4
<4

64
74
19
19
<4
<4
10
13
<5
<4
<4
<4

0.023
0.022
<4
<4
<4
<4

15
26
28
17
24

73900
77700
77700
77500
15
4
7
<5
<5
<4
<4
<4

0.294
0.258
7200 < 9
6100 <6
6700 < 9
5900 < 7

160 <7
220 <7
240 <7
130 <7
140 <7

1400 <9
1400 <9
1400 < 10
1300 < 10
430000 < 8
350000 < 9
370 <9
460 <9
<7 <7
<7 <7
7 <7
6 <6

0.007
0.007
<0.9
<2
<0.9
<2

1.4
<1
< 1
<0.9
<0.9

<0.9
14
< 1
<1
< 1
<1
<1
< 1
< 1
<1
< 1
<1



95
120
90
130

490
450
450
450
530

140
180
191
163
130
150
140
120
130
120
130
140

<0.001
<0.001
<4
<4
<4
<4

,5
<5
<4
<4
<4

<4
<5
<5
<5
<4
<4
<5
<5
<5
<4
<4
<4

0.001
0.001
16
9
14
9

320
320
250
280
380

666900
720800
707700
722800
130
30
51
25
<5
<4
7
7

2.567
2.388
 ' Result shown is reanalysis value.
 6 Non-homogeneity confirmed with reanalysis.
MR1-AED\R4951 WA 2-01 .wpj
                                                                    4-12

-------
                         Table 4-5b. Mercury Results (ppm)
Sample
Number
Pitch
1001 A < 0.050
1002A < 0.049
Brewery Sludge
2001 A < 0.0024
2002A < 0.0024
Wood Chips
3001 A < 0.025
3002A < 0.0022
White Rosin
3003A < 0.47
3003C < 0.48
Yellow Rosin
3004A < 0.44
3004C < 0.48
Analysis

< 0.049
< 0.047

< 0.0025
< 0.0023

< 0.026
< 0.0021

<0.47
<0.46

<0.44
<0.49
Duplicate Analysis

< 0.047
< 0.047

< 0.0024
< 0.0023

< 0.025
< 0.0022

<0.47
<0.49

<0.44
<0.47

< 0.046
< 0.051

< 0.0025
< 0.0024

<0.024
< 0.0021







< 0.050
< 0.047

< 0.0024
< 0.0024

< 0.025
< 0.0022







< 0.049
< 0.048

< 0.0024
< 0.0023

< 0.025
< 0.0021






SIC 28, Industrial sludges
4001 A < 0.01 7
4002A 0.0021
< 0.01 7
< 0.001 8
< 0.01 8
< 0.001 8
< 0.01 7
< 0.001 8
< 0.01 8
< 0.001 7
< 0.01 8
< 0.001 8
SIC 37, Industrial sludges
5001 A < 0.001 2
5002 A < 0.00 13
< 0.001 3
< 0.001 3
< 0.001 2
< 0.001 3
< 0.001 3
< 0.001 3
< 0.001 2
< 0.001 3
< 0.001 2
< 0.001 3
Agricultural/Corn Products
6001 A < 0.043
6002A < 0.043
6005A < 0.026
6006A < 0.025
6009A <0.042
601 OA < 0.043
< 0.042
< 0.042
< 0.026
< 0.025
<0.042
< 0.042
< 0.043
< 0.042
< 0.026
< 0.025
<0.042
< 0.043
< 0.043
< 0.041
0.031
< 0.024
<0.042
< 0.044
< 0.043
< 0.041
< 0.026
< 0.025
<0.041
< 0.043
< 0.043
< 0.041
< 0.026
< 0.026
<0.042
< 0.043
Agricultural/Rice Products
7001 A < 0.045
7002A < 0.044
< 0.046
< 0.046
< 0.045
< 0.047
< 0.047
< 0.046
< 0.047
< 0.045
< 0.046
< 0.045
Agricultural/Peach Pits
8001 A < 0.043
8002A < 0.042
< 0.043
< 0.044
< 0.044
< 0.042
< 0.042
< 0.043
< 0.043
< 0.043
< 0.043
< 0.044
Agricultural/Peanut Products
9001 A < 0.040
9002A < 0.043
PVC Coatings
10001 A < 0.048
10001B < 0.045
10002A < 0.048
Non-PVC Coatings
11 001 A < 0.049
11002A < 0.048
11001C < 0.046
11002C < 0.046
11003B < 0.047
11004B < 0.045
< 0.044
< 0.044

< 0.048
< 0.046
< 0.048

< 0.048
< 0.047
< 0.045
< 0.045
< 0.048
< 0.043
< 0.043
< 0.043

< 0.048
< 0.046
< 0.048

< 0.049
< 0.049
< 0.046
< 0.046
< 0.046
< 0.046
< 0.045
< 0.043



< 0.048

< 0.049
< 0.049
< 0.044
< 0.046
< 0.048
< 0.046
< 0.043
< 0.042



< 0.048

< 0.047
< 0.049
< 0.045
< 0.044
< 0.047
< 0.046
< 0.041
< 0.043



< 0.048

< 0.048
<0.049
< 0.044
< 0.046
< 0.046
< 0.046
MRI-A£D\R4951 WA2-Ol.wpd
                                        4-13

-------
                      Table 4-6. PAH Results (ug/e), Pitch Material
Target Compound
Acenaphthene
Acenaphthylene
Anthracene
Benz[a]anthracene
Benzo[a]pyrene
Benzo[b]fluoranthene
Benzo[g,h,i]perylene
Benzo[k]fluoranthene
4-Bromophenyl phenyl ether
1 -Chloronaphthalene
Chrysene
Dibenz[a,h]anthracene
Dibenzothiophene
Fluoranthene
Fluorene
Hexachlorobenzene
lndeno(1 ,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
Sample No.
1005A 1006A
Analysis Duplicate Analysis Duplicate
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
Average
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
MRI-AED\R495i WA2.01.wpd
                                           4-14

-------
                                        Table 4-7.  PCDD/PCDF Results (pg/g), Pitch Material
Isomer
2,3,7,8-Substituted Dioxins
2378TCDD
12378PECDD
123478HXCDD
123678HXCDD
123789HXCDD
1234678HPCDD
12346789OCDD
2,3,7,8-Substituted Furans
2378TCDF(a)
12378PECDF
23478PECDF
123478HXCDF
123678HXCDF
234678HXCDF
123789HXCDF
1234678HPCDF
1234789HPCDF
12346789OCDF
Dioxln Homologs
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Furan Homologs
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Method Blank

U( 3.57)
U( 3.95)
U( 3.92)
U( 3.76)
U( 3.63)
11.3
115

U(2.16)
U( 2.5)
U(2.1)
U( 3.62)
5.26
U(4.21)
U( 9.68 EMPC)
5.51
U( 5.02 EMPC)
14.9

U( 3.57)
U( 2.42)
U{ 3.77)
18.3

U(2.16)
U( 2.27)
5.4
9.71
Solvent Blank

U( 2.54)
U( 4.02)
U(2.91)
U( 2.78)
U( 2.69)
U( 6.06 EMPC)
51.3

U(1.75)
U(1.88)
U(1.59)
U(1.12)
U(2.11 EMPC)
U( 1.7 EMPC)
U( 5.82 EMPC)
U(1.51)
U(1.67)
5.66

U( 2.54)
U(1.86)
U( 2.79)
6.3

U(1.75)
U(1.71)
U(1.11)
U( .74)
1005 A

U(8.13)(J)
U(18.3)(J)
U( 24.9 EMPC)(J)
U( 24 EMPC)(J)
72.4 (J)
632
4430

U(8.12)(J)
U(5.18)(J)
U( 4.37)(J)
U( 10.7)(J)
U( 10.4)(J)
U( 24 EMPC)(J)
4.31
10.8
U( 5.04 )
9.28

U(8.13)(J)
U(11.5)(J)
118{J)
989

U(8.12)(J)
U( 4.7)(J)
49.5 (J)
17.2
1005 A Dup

U( 5.43)
U( 6.94){J)
U( 8.43)
U( 15.3 EMPC)
30.7
639
4600

U( 8.44)(J)
U( 3.87)
U( 3.26)
U( 3.8)
U(4.19)
U{ 8.96 EMPC)
U( 7.02 EMPC)
10.5
U(3.11)
13

U( 5.43)
U( 3.53)(J)
31.9
1080

U( 8.44)(J)
U( 3.52)
U( 3.77)
11
1006A

U( 2.02)
U{ 4.2)
U{ 4.73 EMPC)
14.4
U( 25.7 EMPC)
610
4430

U( 2.24)
U(1.43)
U(1.21)
U( 3.28)
U(3.17)
U( 3.49)
5.49
8.21
U( 5.47 EMPC)
6.67

U( 2.02)
U( 2.37)
56.3
1030

U( 2.24)
U(1.3)
5.49
14.3
1006A Dup

U( 1 .67)
U( 3.04)
U( 4.07 EMPC)
11.9
U( 12.9 EMPC)
614
4480

U( .906)
U(1.34)
U(1.13)
U( .894)
U( 1.33 EMPC)
3.24
3.79
5.36
U( .949)
9.13

11(1.67)
U(1.57)
51.5
995

U( .906)
U(1.22)
7.5
11.6
        U - Undetected at the noise based detection limit
        EMPC - A peak was detected that did not meet the identification criteria. The peak areas were used to calculate an Estimated
        Maximum Possible Concentration for the detection limit.
        J - Corresponding labeled analog outside of the MRI criteria of 25-150%.
        a - Concentrations for this isomer should be consider a maximum. The GC column used is not specific for this isomer.
MRI-AEDVR495I WA2-OI wpJ
                                                                       4-15

-------
 Section 5.
 Quality Assurance/Quality Control Activities
     The QA/QC procedures and DQOs for this test are summarized in this section. The
 QA/QC procedures and requirements specified in the EPA methods and MRI standard
 operating procedures were used. These procedures include, but are not limited to,
 (1) procedural elements of the methods, and (2) the use of QC samples and analytical
 procedures such as reagent blank samples, laboratory control  samples, and surrogate
 spiking.  The performance and results of all QC procedures were recorded on appropriate
 forms, data sheets, or field and laboratory notebooks as appropriate.

     Specific QC procedures were followed to ensure the continuous production of useful
 and valid data.  Table 5-1 presents a summary of the specific  criteria used for assessing
 overall data quality along with the results of these determinations.
 5.1  Data Audit

     The data audit was conducted to evaluate the analytical data generated during this
 work assignment. The quality of the analytical data was evaluated against the quality
 objectives for the measurement process, which was presented in the QAPP and the
 specified test methods. The analytical data this work assignment were audited by the
 QAU. The data met the DQO and measurement objectives for this  work assignment as
 noted in Table 5-1 with some minor exceptions.
 5.2  Data Assessment

    An assessment of the overall quality of the data generated for this work assignment
 was conducted. The data assessment included a review of the sample collection data,
 preparation, and analysis data including calibration, surrogate recoveries, laboratory
 control spike sample, and precision measurements. The data generated for this report are
 traceable and of known and acceptable quality.
MRI-AEDXR4951 WA2-01.wpd
                                      5-1

-------
Table 5-1. Specific Obj
Test parameters
Heating value
Carbon/hydrogen
Sulfur
Moisture
Ash
Viscosity
Total chlorine,
fluorine, and/or
bromine iodine
Specific gravity
Matrix
All indicated
waste feeds
All indicated
waste feeds
All indicated
waste feeds
All indicated
waste feeds
All indicated
waste feeds
All indicated
waste feeds
All indicated
waste feeds
All indicated
waste feeds
Method of determination
Duplicate analysis
Analysis of reference material
Duplicate analysis
Duplicate analysis
Duplicate analysis
Duplicate analysis
Analysis of reference material
Duplicate analysis
Analysis of reference material
Duplicate analysis
Matrix spike at least at 10X the estimated
detection limit
Analysis of performance sample
Duplicate analysis
ectives for Measurement Data
Frequency
One sample per matrix or for every
ten samples whatever is more
frequent
Once
One sample per matrix or for every
ten samples whatever is more
frequent
One sample per matrix or for every
ten samples whatever is more
frequent
One sample per matrix
One sample per matrix
Once
One sample per matrix or for every
ten samples whatever is more
frequent
Once
One sample per matrix or for every
ten samples whatever is more
frequent
Once per each matrix or for every
twenty samples, whatever is more
frequent.
Once for each halide
One sample per matrix or for every
ten samples whatever is more
frequent
Accuracy
NA
90%- 110%
(of reference value)
NA
NA
NA
NA
90%-110%
(of reference value)
NA
90%- 110%
(of reference value)
NA
70%-130%
recovery
90%- 110%
(of audit value)
NA
Precision
< 10% RPD
NA
< 10% RPD
< 10% RPD
< 10% RPD
< 10% RPD
NA
< 10% RPD
NA
< 10% RPD
NA
NA
< 10% RPD
Objective met?
Yes
Yes
Yes
Yesb
Yesc
Yesd
Yes
Yes
Yes"
No: failed one or more
Halogen on 26 out of
36 samples
Yes
Not submitted
Yes
MRI-AEDXR4951 WA2-Ol.wpd
                                                                                           5-2

-------
                                                            Table 5-1 (Continued)
Test parameters
PAHs
PCDDs/PCDFs
Metals
Matrix
All indicated
waste feeds
Blanks
All indicated
waste feeds
Blanks
All indicated
waste feeds
Method of determination
Duplicate analysis of homogenized
composites
Surrogates spiked before sample
preparation
Method blank carried through all sample
preparation and analysis
Duplicate analysis of homogenized
composites
Surrogates spiked before sample
preparation
Method blank carried through all sample
preparation and analysis
Duplicate analysis
Matrix spike at least at 10X the estimated
detection limit
Control sample (blank reagent) spiked at
least at 10X the estimated detection limit
Frequency
One sample per matrix or for every
ten samples whatever is more
frequent
Every sample
Once per each analytical batch of
samples for demonstration of
noncontamination and system
control
One sample per matrix or for every
ten samples whatever is more
frequent
Every sample
Once per each analytical batch of
samples for demonstration of
noncontamination and system
control
One sample per matrix or for every
ten samples whatever is more
frequent
Once per each matrix
Once per matrix
Accuracy
NA
50%- 150%
recovery
NA
NA
25%- 150%
recovery
NA
NA
70%- 130%
recovery
70%- 130%
recovery
Precision
< 35% RPD
NA
NA
< 25% RPD
NA
NA
< 35% RPD
NA
NA
Objective met?
Yes
Yes
Yes
Yes6
Yesh
Yes'
Yes'
Yes9
Yes
   This footnote is no longer applicable.
   Objective not met for the following matrices: Rice husks, peanut hulls, PVC coatings and non-PVC coatings.
   Objective not met for the following matrices: Pitch, wood chips, wood chips/rosin, PVC coatings and non-PVC coatings.
   Objective not met for the following matrices: wood chips, SIC 37, peanut hulls, and non-PVC coatings.
   Objective not met for 1,2,3,7,8,9-HxCDF and 1,2,3,4,6,7,8-HpCDF and for HxCDF sample 1006A and for the total HpCDF in sample 1005A. OCDF did not meet the
   criteria in either sample.
   Objective not met for the following matrices: Brewery sludge, white rosin, yellow rosin, peanut hulls, PVC coatings and non-PVC coatings.
   Objective not met for Aluminum.
   Objective not met for some labeled compounds in sample 1005A and 1005A DUP
   Objective not met for HxCDF, HpCDF, and OCDF
MRI-AEDVR495I WA2-OI.wpJ
                                                                        5-3

-------
                                          Appendix A
                          Sampling Traceability Data
MRI-AED\r495l-OI-02-05TR.wpJ

-------
                       Galbraith Labs Sample and Analysis Matrix

                               Material: Pitch From Tall Oils
Sample
1001A
1002A
Dup.
Analysis
X
X
Ultimate
Analysis
X
X
Metals
X
X
Heat
content
X
X
Viscosity
X
X
Specific
gravity
X
X
Halogens
(individual)
X
X
                                 Material; Brewery Sludge
Sample
2001A
2002A
2003A
2004A
Dup. Analysis
X
X
X
X
Ultimate
Analysis
X
X
xb
xb
Metals
X
X


Heat content
X
X


Halogens
(individual)
X"
X"
X
X
* Sample not intended for analysis but was inadvertantly analyzed; results are reported.
b Sample was inadvertantly analyzed for moisture; results are reported.


                         Material: SIC 28, Wood Chips and Rosins
Sample
3001A
3002A
3003A
3003C
3004A
3004C
Material
wood
wood
w rosin
w rosin
y rosin
y rosin
Dup.
Analys
X
X




Ultimate
Analysis
X
X
X
X
X
X
Metals
X
X
X
X
X
X
Heat content
X
X
X
X
X
X
Halogens
(individual)
X
X
X
X
X
X
                            Material: SIC 28, Industrial Sludges
Sample
4001A
4002A
4003A
4004A
Dup. Analysis
X
X
X
X
Ultimate
Analysis
X
X


Metals
X
X


Heat content
X
X


Halogens
(individual)
Xa
X'
X
X
1 Sample not intended for analysis but was inadvertantly analyzed; results are reported.
                                          APPENDIX  A

-------
                    Galbraith Labs Sample and Analysis Matrix (cont.)


                           Material: SIC 37, Industrial Sludges
Sample
5001 A
5002A
5003A
5004A
Dup. Analysis
X
X
X
X
Ultimate
Analysis
X
X


Metals
X"
X"


Heat content
X
X


Halogens
(individual)
X"
Xb
X
X
8 Duplicate analysis not performed.
" Sample not intended for analysis but was inadvertantly analyzed; results are reported
                          Material: Agricultural/Corn Products
Sample
6001A
6002A
6005A
6006A
6009A
601 OA
Material
gluten
gluten
germ
germ
clean
clean
Dup.
Analys
X
X
X
X
X
X
Ultimate
Analysis
X
X
X
X
X
X
Metals
(Hg only)
X
X
X
X
X
X
Heat content
X
X
X
X
X
X
Halogens
(individual)
X
X
X
X
X
X
                       Material: Agricultural Material/Rice Husks
Sample
7001A
7002A
Dup. Analysis
X
X
Ultimate
Analysis
X
X
Metals
(Hg only)
X
X
Heat content
X
X
Halogens
(individual)
X
X
                            Material; Agricultural/Peach Pits
Sample
8001 A
8002A
Dup. Analysis
X
X
Ultimate
Analysis
X
X
Metals
(Hg only)
X
X
Heat content
X
X
Halogens
(individual)
X
X
                       Material; Agricultural Material/Peanut Hulls
Sample
9001A
9002A
Dup. Analysis
X
X
Ultimate
Analysis
X
X
Metals
(Hg only)
X
X
Heat content
X
X
Halogens
(individual)
X
X
                                         APPENDIX  A

-------
                    Galbraith Labs Sample and Analysis Matrix (cont.)

                              Material:  PVC  Rack Coatings
Sample
10001A
10001 B
10002A"
10002B"
Dup. Analysis


X"

Ultimate
Analysis
X
X
X
X
Metals
X
X
X
X
Heat content
X
X
X
X
Halogens
(individual)
X
X
X
X
• Sample 10002A analyzed in duplicate due to lab contamination of 10002B with stannous chloride.
b Sample no. 10002B archived (not analyzed) due to lab contamination.


                               Material: Non-PVC Coatings
Sample
11001 A
11002A
11001C
11002C
11003B
11004B
Material
grey
grey
white
white
red
red
Dup.
Analys
X
X
X
X
X
X
Ultimate
Analysis
X
X
X
X
X
X
Metals
X
X
X
X
X
X
Heat content
X
X
X
X
X
X
Halogens
(individual)
X
X
X
X
X
X
                                         APPENDIX A

-------
SEP 18 MOB ^~-> / /* -VI
D CHAIN OF CUSTODY RECORD
DIMPLE TRACEABILITY RECORD
Hontainpr (Coo|pr) No •//^//^?
Paqe / of / Transfer No.
Checked by (Initials)/Date
Lock or Seal Intact (Yes or No)/Time
EMC 4950-08 1001 A
Galbraith
EMC 4950-08 1002 A
Galbraith
For disposal contact: J. Hosenfeld
MIDWEST RESEARCH INSTITUTE








Relinquished By: Received By:
jO,M~^ F*0
2
3
4
Reason for Transfer:
7t>-^_^xfrTf ^tVy



                                                       93-4 SEV surm wkshl 020293
APPENDIX  A

-------
SEP 2 11998
D CHAIN OF CUSTODY RECORD
JZT SAMPLE TRACEABILITY RECORD
Hnntainpr (Hnnlfir) No. ^J m
Paqe / of / Transfer No.
Checked by (Initia!s)/Date
Lock or Seal Intact (Yes or No)/Time
EMC 4950-08 2001 A
Galbraith
EMC 4950-08 2002A
Galbraith
EMC 4950-08 2003 A
Halogens
EMC 4950-08 2004A
Halogens
For disposal contact. J. Hosenlelu
MIDWEST RESEARCH INSTITUTE






Relinquished By: Received By:
^a>XA^/ /?$& ,
#fcJtL~
1 '

Field Sample Custodian:
$S»r"&L. /Jg.?^




Storage Requirements:
JZf Ice water, < 4°C
d Dry ice
C] Room Temp., < 26°C
CD Other:





Remarks:


Remarks:


Remarks:


Remarks:


Remarks:


Remarks:


Remarks:


Remarks:


Remarks:


Remarks:


Remarks:
Sample Transfers:
Date Time No.
?^tf'?8 1
9fa/W f:&* 2
3
4
Reason for Transfer:
Zfri/o 75. &*#



                                                   93-4 SEV surmwkshl 020293
          APPENDIX  A

-------
D CHAIN OF CUST<
"P SAMPLE TRACE
Container (Cooler)
Paqe ( of
DDY RECORD
(VBILITY RECORD
No rfA
Transfer No.
Checked by (Initials)/Date
Lock or Seal Intact (Yes or No)/Time
EMC 4950-08
Galbraith
r — ..
I EMC 4950-08
'"JalJiraith/RalocrenS
EMC 4950-08
Galbraith/Halogens
PVw A: 	 i
EMC 4950-08
Galbraith/Halogens
1 EMC 4950-08
Gal bra i th /Ha 1 n OPT
EMC 4950-08
Galbraith/Halogens
MIDWEST RESE/
3001A
3002A
3003A
3004A
3003C
c
3004C
t- T TTr^cAnf^lH
LRCH INSTITUTE




Relinquished By:
/Qa&^<^




Received By:
/Yl^C^ft/d^f'^
} V tssv^1^-


Field Sample Custodian:
1
l3f\^l/i<^
	 — T —
^
UU!



'& jyyb



Storage Requirements:
G2 Ice water, < 4°C
D Dry ice
CH Room Temp., < 26°C
n Other:





Remarks:
iX



Remarks: .
i. V
^



Remarks:
\^~

Remarks:
^ Hir^rt''t **

9-




&<.**& ~«* o-T-


Remarks:




Remarks:




Remarks:




Remarks:




Remarks:




Remarks:




Remarks:
Sample Transfers:
Date
7/z
-------
   SEP 18
2 ~
D CHAIN OF CUSTODY RECORD
0 SAMPLE TRACEABILITY RECORD
rnptainpr (Hnnlpr) No. ///^
Paae / of / Transfer No.
Checked by (Initials)/Date
Lock or Seal Intact (Yes or No)/Time
(S EMC 4950-08 4001 A
Galbraith
EMC 4950-08 4002A
Galbraith
EMC 4950-08 4003A
Halogens
EMC 4950-08 4004^
Halogens
For disposal contact: J. Hosenfeld
MIDWEST RESEARCH INSTITUTE






Relinquished By: Received By:
^a^^^J fcrc&.



Field Sample Custodian:
<./jCfj/Q<- A/VO^




Storage Requirements:
J^lce water, <4°C
CD Dry ice
n Room Temp., < 26°C
CH Other:





Remarks:


Remarks:


Remarks:


Remarks:


Remarks:


Remarks:


Remarks:


Remarks:


Remarks:


Remarks:


Remarks:
Sample Transfers:
Date Time No.
'f'll-fy; ro'.tf 1
2
3
4
Reason for Transfer:
J>/cP fa £1?



                                    93-4 SEV surmwksht 020;
APPENDIX A

-------
SEP 18 1998
2-J/7/-2L
D CHAIN OF CUSTODY RECORD
E] SAMPLE TRACEABILITY RECORD
rinntainpr /Hnnlph No ////>
Paae / Of / Transfer No.
Checked by (Initials)/Date
Lock or Seal Intact (Yes or No)/Time
EMC 4950-08 5001A
Galbraith
EMC 4950-08 5002A
Galbraith
EMC 4950-08 5003A
Halogens
EMC 4950-08 5004A
Halogens
For disposal contact: J. Hosenfeld
MIDWEST RESEARCH INSTITUTE






Relinquished By: Received By:
&*«f'..A/?^ fefifr



Field Sample Custodian:

4* W%'






Storage Requirements:
CST Ice water, < 4°C
EH Dry ice
CH Room Temp.. < 26°C
n Other:





Remarks:



Remarks:



Remarks:



Remarks:



Remarks:



Remarks:



Remarks:



Remarks:



Remarks:



Remarks:



Remarks:
Sample Transfers:
Date Time No.
?-tf-?£ /£•'** 1
2
3
4
Reason for Transfer:
St"* f° £*tf



                        93-4 SEV surm wkshl 020293
  APPENDIX A

-------
SEP 2 i 1998
'  391
D CHAIN OF CUSTODY RECORD
[^SAMPLE TRACEABILITY RECORD
P.nntainfir (Cooler) No. X///3
Page / of ( Transfer No.
Checked by (Initials)/Date
Lock or Seal Intact (Yes or No)/Time
(Samp1- ""•-' — ' -u-"
EMC 4950-08 6001 A
Galbraith
EMC 4950-08 6002A
Galbraith
^ - j* ! • *
EMC 4950-08 6005 A
Galbraith/Halogens
EMC 4950-08 6006A
Galbraith/Halogens
EMC 4950-08 6009A
Galbraith/Halogens
EMC 4950-08 6010 A
Galbraith/Halogens
~ — ror disposal contact. J. Hosenfeld
MIDWEST RESEARCH INSTITUTE




Relinquished By: Received By:
£>.OU*^ /?&>**
>^ |,/jw 	 tA.
^

Field Sample Custodian:
/
^74///-
/*j/)
*S
Storage Requirements:
Hlce water, < 4°C
CH Dry ice
d Room Temp., < 26°C
CH Other:





Remarks:
I/

Remarks:
vX

Remarks:
•/

Remarks:
s
*/

Remarks:
S

Remarks:


Remarks:


Remarks:


Remarks:


Remarks:


Remarks:
Sample Transfers:
Date Time No.
?//^ -yz- (£)
^ilf^ M(/(5 2
3
4
Reason for Transfer:
rr^^^.n*
A^l/st-5"


                                                            93-4 SEV surmwksht 020293
                        APPENDIX A

-------
D CHAIN OF CUSTODY RECORD
EXAMPLE TRACEABILITY RECORD
Container (Cooler) No. SJ//Q
Paqe /of J Transfer No.
Checked by (Initials)/Date
Lock or Seal Intact (Yes or No)/Time
<&•
EMC 4950-08 7001 A
Galbraith/Halogens
EMC 4950-08 7002A
Galbraith/Halogens
For disposal contact: J. Hosenteld
MIDWEST RESEARCH INSTITUTE








Relinquished By: Received By:
_£). 4fa*r f&et
i>^/r, 1^—^


Field Sample Custodian:
^43, <3-iLr^£\T
SEP 1 5 1998
/
&frifa
/*/*
^








Storage Requirements:
GEJ Ice water, < 4°C
CD Dry ice
CD Room Temp., < 26°C
CD Other:





Remarks: , . ,
>/



Remarks:
t >




Remarks:



Remarks:




Remarks:




Remarks:



Remarks:



Remarks:




Remarks:


Remarks:



Remarks:
Sample Transfers:
Date
l/il-
^llSfaK


Time
^
/^r


No.
^T>
2
3
4
Reason for Transfer:
T» (r#<-tfr **«- *"«^
JVvaly/;S


                                                       93-4 SEV surm wkshl 020293
APPENDIX  A

-------
 SEP 2 9 1993
2
96
D CHAIN OF CUSTODY RECORD
@ SAMPLE TRACEABILITY RECORD
HnntflinAr (Honler) No. SJ/A

Paae / Of / Transfer No.
Checked by (Initials)/Date
Lock or Seal Intact (Yes or No)/Time
(Sample Container Label)
go* (A

$062- A



















Relinquished By: Received By:
^>. <3&~-+ — ' /^<£0£?K-
yjfoflJL"^
i/

Field Sample Custodian:
P. A^^^ry

/
QAJ/zf
SV-A at Ha
^
Remarks:
/Utf'vJ e-*4et*>r«-ao*}
*/
Remarks:
4 '

Remarks:
1
Remarks:

Remarks:

Remarks:

Remarks:

Remarks:

Remarks:

Remarks:

Remarks:
Sample Transfers:
Date Time No.
7/zr ^iz<>+ CD
^ 9-A<«r ;/UbA« 2
3
4
Storage Requirements:
IS Ice water, < 4°C
CD Dry ice
L7J Room Temp., < 26°C
d Other:



























Reason for Transfer:
T6 'l F&t. /)fJ*L-T'SlS



                                    93-4 SEV surmwksht 020293
APPENDIX A
                                            11

-------
                                     J2.
D CHAIN OF CUSTODY RECORD
P SAMPLE TRACEABILITY RECORD
Hnntainpr (Honlph No /^/^
Paqe / of ' Transfer No.
Checked by (Initials)/Date
Lock or Seal Intact (Yes or No)/Time
e-*V
SEP241998
\
m 9 As
/V
-------
D CHAIN OF CUSTODY RECORD
0 SAMPLE TRACEABILITY RECORD
Container (Cooler) No. S-*r$ &>

Paae / Of / Transfer No.
Checked by (Initials)/Date
Lock or Seal Intact (Yes or No)/Time
(Sar
EMC 4950-08 10001A
Galraith/Halogens

] EMC 4950-08 10002A
Galraith/Halogens
For disposal contact: J. Hosenfeld
MIDWEST RESEARCH INSTITUTE

















Relinquished By: Received By:
/Q. &JUsVlss(£^ /^tS'fiG^jC.
tOv<*» — ~^\


Field Sample Custodian:

/
&A t/?z
AJ^
^
Remarks:
tX
Remarks:
1 1

Remarks:

Remarks:

Remarks:

Remarks:

Remarks:

Remarks:

Remarks:

Remarks:

Remarks:
Sample Transfers:
Date Time No.
?/^ r/» ©
?A3/«r Wo 2
3
4
Storage Requirements:
CU Ice water, < 4°C
CD Dry ice
ja' Room Temp., < 26°C
CH Other:





t^c^-sr





















Reason for Transfer:
^
hArt(ilti)
"''

                                                   93-4 SEV surmwkshl 020293
APPENDIX  A
                                                              13

-------
D CHAIN OF CUSTODY RECORD
JB> SAMPLE TRACEABILITY RECORD
nnntninpr fHnnlpr^ No ^-~
Paqe / of / Transfer No.
Checked by (Initials)/Date
Lock or Seal Intact (Yes or No)/Time
(? EMC 4950-08 10001B
Galraith/Halogens
EMC 4950-08 10002B
Galraith/Halogens
Foi disposal contact: 3. Hosenielu
MIDWEST RESEARCH INSTITUTE








Relinquished By: Received By:
jna/l*Jt ttc^L
^)^^\


Field Sample Custodian:
/
&fl ?/**
^A
^
Storage Requirements:
CU Ice water, < 4°C
CH Dry ice
S?Room Temp., < 26°C
CU Other:





Remarks:
iX

Remarks:


Remarks:


Remarks:


Remarks:


Remarks:


Remarks:


Remarks:


Remarks:


Remarks:


Remarks:
Sample Transfers:
Date Time No.
Vez- $nf*<2)
ft^rttr /s/o 2
3
4
Reason for Transfer:
TO G'XfT- /3 f
/W
-------
      D CHAIN OF CUSTODY RECORD
         SAMPLE TRACEABILITY RECORD
      Container (Cooler) No.
      Page   /  of  /
                         Transfer No
                                     Field Sample Custodian:
                                                       
-------
MRI Sample and Analysis Matrix
Sample
Number
1005A
1006A
6003A
6004A
6007A
6008A
6011 A
601 2A
7003A
7004A
8003A
8004A
9003A
9004A
11003A
11004A
Material
pitch
pitch
Ag/corn
gluten
Ag/com
gluten
Ag/corn germ
Ag/corn germ
Ag/corn clean
Ag/corn clean
Ag/rice husk
Ag/rice husk
Ag/peach pits
Ag/peach pits
Ag/peanut
Ag/peanut
Non-PVC,
grey/black
Non-PVC,
grey/black
Duplicate
Analysis
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
Elemental














X
X
Particle size


X
X
X
X
X
X
X
X
X
X
X
X


Dioxins
Furans
X
X














PAHs
X
X














           APPENDIX A
                                                   16

-------
n CHAIN OF CUSTODY RECORD
[^SAMPLE TRACEABILITY RECORD
Container (Cooler) No. AJ/4-
Paae / Of / Transfer No.
Checked by (Initials)/Date
Lock or Seal Intact (Yes or No)/Time
(Sa
EMC 4950-08 1005 A
Dioxins/Furans
EMC 4950-08 1006A
Dioxins/Furans
For disposal contact: J. Hosenfeld
MIDWEST RESEARCH INSTITUTE








Relinquished By: Received By:
/D,^6W^~ /^GTPery:
Fid&s fWh ^Xfr#w) _
(7

Field Sample Custodian:
^
-------
                                                                       Code: MRI-5003
                                                                            Revision:  1
                                                                       Effective: 3/27/98
                                                                          Page: 8 of 17
                            SAMPLE RECEIPT CHECKLIST
                       MRI Project No..
Samples Received by:
Airbill No.
                                                              Date:  0*t[(t [^7
                                                Chain-of-Custody No.
                                                                     No
Airbill present?         ffes) No    Chain-of-Custody present?     (Q
Shipping container intact?  (^eij> No  Container type   C-o o \  No    Seals intact?  ^^  No   Seal Location:/.'^
                                                                 Yes
C-O-C properly filled out?  Yes  No   Does C-O-C indicate sample type?       $Ij2> No
Ice packsOC
                                        APPENDIX  A

-------
                                                                               Sample Master LEV1S
                                                                               Sample Login Report
           Customer Name:  Engineering Department
                Project ID:  4950.8.5 lX
          Order Comment:  Shipped by D. Alburn-, received by M.Cheramyf
                                                                                  Order ID:    980900015
                                                                                Order Date:       9/18/98
                                                                                       Page:         1 of 1
         MRI Sample ID    Customer Sample ID
                                                Matrix
Quantity    Date Collected
                              Date Received
                                                Test
                                                                Test Group
                                                                               Method
                                                                                                                                                              Due Date
98003139

98003139

98003140

98003140

1005A I/
Pitch
1005 A \y
Pitch
1006 A \/
Pitch
1006 A ^/
Pitch
Liquid

Liquid

Liquid

Liquid

1 9/1 8/98 12:00 AM

1 9/18/98 12:00 AM

1 9/18/98 12:00 AM

1 9/18/98 12:00 .AM

9/18/98 2:24 PM

9/18/98 2:24 PM

9/18/98 2:24 PM

9/18/98 2:24 PM

test_pcdd/f t/

test_smv (./

test_pcdd'f {/

test_smv_^^^

t
T)
m
z
o
H
X.
      SAMPLE CONDITION RECORD
                  Are samples submitted with a chain of custody?  Yes <-/
Are the number of samples the same as stated on the chain of custody?  Yes 
-------
D CHAIN OF CUST
EXAMPLE TRACE
Container (Cooler)
Pace l of 1
ODY RECORD
ABILITY RECORD
No A->/3&
Transfer No.
Checked by (Initials)/Date
Lock or Seal Intact (Yes or No)/Time
(Samr 	 • • "
EMC 4950-08
Particle Size
EMC 4950-08
Particle Size
EMC 4950-08
Particle Size
6003A y
6004A ^
6007A ^
rt- T ITnQpnfplH
EMC 4950-08 6008At//
Particle Size
EMC 4950-08 601 1 A -X
Particle Size
EMC 4950-08
Particle Size
^.f . T tJrt.n«.«^U1 J
MIDWEST RESEARCH INSTITUTE




Relinquished By:
jQ.Stet-^-




Received By:
\%J^fJvw^
u


Field Sample Custodian:
/Q <&f&-t~£T_
1
&A°[f\?'
^"
•'""




Storage Requirements:
H^lce water, < 4°C
CZI Dry ice
CH Room Temp., < 26°C
L~H Other:





Remarks:
^


Remarks:
^X'


Remarks:
tX


Remarks:



Remarks:



Remarks:



Remarks:



Remarks:



Remarks:



Remarks:



Remarks:
Sample Transfers:
Date Time No.
n(Wv \)\-\x _/f?
2
3
4
Reason for Transfer:
A^lvJrj-
"


                                                       93-4 SEV surmwkshl 020293
APPENDIX   A
                                                                   20

-------
                                                                        Code: MRI-5003
                                                                            Revision:  1
                                                                       Effective:  3/27/98
                                                       tL>                 Page: 8 of 17
                            SAMPLE RECEIPT CHECKLIST
                       MRI Project No._
Samples Received by:  /V- &L_   6/uxti^.^ _  Date:
Airbill No. _     Chain-of-Custody No.
Airbill present?        /syNo    Chain-of-Custody present?       s   No
Shipping container intact?  fi^es) No  Container type  && ° «
Custody seals present?   Yes  (No/  Seals intact?   Yes (No)  Seal Location:.
C-O-C properly filled out?  Yes) No   Does C-O-C indicate sample type?      (^es) No
Ice packs or ice frozen?    /^£r No Samples cold?   (fes) No        Temperature °C: ^Vj~
Sample containers intact?   (^es) No Labels permanently affixed?    (fes)   No
Sample containers leaking? Yes (No) Container type indicated?         Yes  (So)
Are all samples properly labeled and accounted for?      $es2 No
Are samples stored as indicated by the project leader?  (Yes/ No
Is the C-O-C filled out completely, signed, and dated? Yes   No
                                                               I.
If pH check upon receipt is required,  indicate where it is recorded.  ^ l/\	
Sample storage location:
COMMENTS
                        5;,
MR1-QA\MRI-5003.DOC
                                         APPENDIX A                                21

-------
                                                                                 Sample Master LEMS
                                                                                 Sample Login Report
            Customer Name: Engineering Department
                  Project ID: 4950.8.5 •
            Order Comment: Delivered by D. Alburty 9/21/98 to 330-E.
          MRI Sample ID    Customer Sample ID
                                                 Matrix
           <><^,-v,
Quantity    Date Collected
                 Order ID:    980900017
               Order Date:        9/21/98u
                      Page:          1 of 1
                                                                                               Date Received
                                                                                                                  Test
Test Group     Method
                                                                                                                                                               Due Date
98003155

98003156

98003157

98003158

98003159

> 98003160
T
m . . .,
z
o
H
X
6003A -
Ag. Material
6004AV-^
Ag. Material
6007A ^
Ag. Material
6008A ^
Ag. Material

Ag. Material

Ag. Material

Ljqflld C,u I t( 1 9/14/98 12:00 .AM

Liquid

litfSif

UqUid

y't~£^
\

SAMPLE CONDITION RECORD



Are sampli

•s submitted with a chain of
; ,/- (u >? 1
custody? Yes "^ ^ J 1 2- (. 1 6 \^'
                                                                  Are the number of samples the same as stated on the chain of custody?  Yes
                                                                                       Are bottle caps tight and securely In place?  M/A1-/
                                                                                        Were all containers intact when received?  Yes
             L  k*JZ
                                                                                         Were samples submitted In an ice chest?  Yes
                                                                                                  Were samples received cold?  Yes •
                                                                        Were samples within the holding time for the requested test(s)?  Yes
                                                                   Is the volume of sample submitted sufficient for the requested test(s)?  Yes '
                                                                        Are all samples for volatile organic analyses free of headspace?  N/A-

N)
H

-------
D CHAIN OF CUSTODY RECORD
B-SAMPLE TRACEABILITY RECORD
Container (Cooler) No. /^>/A

Paqe / Of Transfer No.
Checked by (Initials)/Date
Lock or Seal Intact (Yes or No)/Time
TJA/rr1 ACKO OR /fill i/\
illVlV., H^JU-UO / VrVf*-/.*. *.
Particle Size
EMC 4950-08 7004A
Particle Size
For disposal contact: J. Hosenfeld ~
MIDWEST RESEARCH TN9TTTT TTF


















Relinquished By: Received By:
£>, aa^Jt^ ^x*>£*.
0/lAJU^f'^'
'

Field Sample Custodian:

* 0?
&*?/'•< ^°(*\6k'
/^M ]
^ ' \S
Remarks:
/VdT~ "hctz^ft-f^u<> . 3
•X S
Remarks:

Remarks:

Remarks:

Remarks:

Remarks:

Remarks:

Remarks:

Remarks:

Remarks:

Remarks:
Sample Transfers:
Date Time No.
*)/,* r^. &
yii&w io^o CD
3
4
Storage Requirements:
CH Ice water; <4°C
d Dry ice
23 Room Temp., < 26°C
d Other:





-TMS^**^***^





















Reason for Transfer:
r^AVi, A,,L.<3>iXj*<-<~-
1 oJo re-cL


                                                   93-4 SEV  surmwkshl 020293
APPENDIX  A
                                                              23

-------
                                                                       Code:  MRI-5003
                                                                           Revision: 1
                                                                      Effective: 3/27/98
                                                                          Page: 8 of 17
                            SAMPLE RECEIPT CHECKLIST
MRI Project Nn
     c  J  I  f "6T I _   Date:   H~\5 "7g
Samples Received by:         c  J   f
Airbill No.    
C-O-C properly filled out?\Yes) No  Does C-O-C indicate sample type?
                               _                       	                      n >  >«
Ice packs or ice frozen?     Yes (UQ) Samples cold?   Yes (^)     Temperature °C: /^/T~
Sample containers intact?  (Yes) No  Labels permanently affixed?   (^es)  No
Sample containers leaking? Yes /No) Container type indicated?         Yes
Are all samples properly labeled and accounted for?     ?"^§\  No
Are samples stored as indicated by the project leader?    Y§sj   No
Is the C-O-C filled out completely, signed, and dated? £?e§)  No
If pH check upon receipt is required, indicate where it is recorded.	r~-^ rr
Sample storage location: 	O .
COMMENTS
                 JM£J^_SL f
                         uocnn
MR1
-------
                                                                             Sample Master LIMS
                                                                             Sample Login Report
           Customer Name: Engineering Department
                Project ID: 4950.8.5
           Order Comment: 4950 FOR HOSENFELD-"
                                                                               Order ID:   980900012
                                                                             Order Date:      9/15/98
                                                                                   Page:        1 of 1
MRI Sample ID
98002957

98002958

Customer Sample ID
7003A
part. Size -^
7004A -^
part Size ^
Matrii
-fciqTiid „
CjoU0
Li^uM-
So^xCl
Quantity
1

1

Date Collected
9/14/98 12:00 AM

9/14/98 12:00 .AM

Date Received
9/1 5/98 4:43 PM

9/1 5/98 4:43 PM

Test Test Group Method
test_engineering /^

lest_engineering

Due Date




 •o
 •o
 m
 z
 o
      SAMPLE CONDITION RECORD
                 Are samples submitted with a chain of custody?  Yes
Are the number of samples the same as stated on the chain of custody?  Yes
                    Are bottle caps tight and securely in place?  Yes
                     Were all containers intact when received?  Yes
                      Were samples submitted In an ice chest?  No
                               Were samples received cold?  No
      Were samples within the holding time for the requested test(s)?  Yes
 Is the volume of sample submitted sufficient for the requested test(s)?  Yes
      Are all samples for volatile organic analyses free of headspace?  N/A
01

-------
D CHAIN OF CUSTODY RECORD
El SAMPLE TRACEABILITY RECORD
Container (Cooler) No s^/A

Paqe / of ' Transfer No.
Checked by (Initials)/Date
Lock or Seal Intact (Yes or No)/Time
(Sample Container Label)
%0<3A.

&>*«A



















Relinquished By: Received By:
£>.tu~~— F*-0**-.
ft_
^
Remarks:

Remarks:

Remarks:

Remarks:

Remarks:

Remarks:

Remarks:

Remarks:

Remarks:

Remarks:
Sample Transfers:
Date Time No.
//£-rf" '*/Zo« CJP
0*%i%&(?S? OC3-*'tA9 >2l
3
•4
Storage Requirements:
H1 Ice water, < 4°C
CH Dry ice
CH Room Temp., < 26°C
CD Other:



























Reason for Transfer:
TO ^*, ^ /v—W.J
PexrrJyt^ ^Jo Avv*^^


                                                     93-4 SEV surmwkshl 020293
APPENDIX  A
                                                                 26

-------
                                                                       Code: MRI-5003
                                                                            Revision: 1
                                                                      Effective: 3/27/98
                                                                          Page:  8 of 17
                            SAMPLE RECEIPT CHECKLIST

                       MRI Project No.
Samples Received by:

Airbill No.
                                                              Date:
                                "7 3"?
                                                 Chain-of-Custody No.
Airbill present?         WesyNo

Shipping container intact?  \^

Custody seals present?   Yes  jNo
                                  Chain-of-Custody present?
                                                                     No
                                  Container type.
                                            i>^£
                                  Seals intact?  tfes\No   Seal Location:
                                                                            e\i
C-O-C properly filled out?  fe&> No   Does C-O-C indicate sample type?
                                                                            No
                          es)No Samples cold?  (YeT)>No
Ice packs oNiceJrpzen?J

Sample containers intact?   ^es?  No Labels permanently affixed?

Sample containers leaking? Yes /N'cpContainer type indicated?

Are all samples properly labeled and accounted for?     $&$) No

Are samples stored as indicated by the project leader?  CYes) No
                                                 	—s
Is the C-O-C filled out completely, signed, and dated/Yes/ No

If pH check upon receipt is required, indicate where it is recorded.	

Sample storage location:

COMMENTS
                                                                Temperature °C:.

                                                                     No

                                                                 Yes
MRI-QA\MRI-5003XIOC
                                         APPENDIX  A
                                                                                        27

-------
                                                                              Sample Master LIMS

                                                                              Sample Login Report
           Customer Name:  Engineering Department ^^


                 Project ID:  4950.8.5 \^/


           Order Comment:  Received 9/29/98 by MCheramy.,
                                                                                Order ID:    980900026


                                                                              Order Date:        9/30/98


                                                                                    Page:         1 of 1
MRI Sample ID
98003241

98003242

Customer Sample ID
8003A »/ ,
.Ag Material •/
8004A 

i

i

Dale Collected
9/28/98 12:00 AM

9/28/98 12:00 .AM

Date Received
9/29/98 10:07 AM ~"

9/29/98 10:07 AM ^

Test Test Group Method
lest_engineering • —

test engineering'^^

Due Dale




 •o
 •o
 m
 z
 o
                                                                      SAMPLE CONDITION RECORD
                 Are samples submitted with a chain of custody? Yes


Are the number of samples the same as stated on the chain of custody? Yes


                     Are bottle caps tight and securely in place? Yes


                      Were all containers Intact when received? Yes<-/


                       Were samples submitted in an ice chesl? Yes
-------
D CHAIN OF CUSTODY RECORD
@ SAMPLE TRACEABILITY RECORD
Container (Cooler) No. ^,T\
Paqe / of / Transfer No.
Checked by (Initials)/Date
Lock or Seal Intact (Yes or No)/Time

-------
                                                                       Code: MRI-5003
                                                                            Revision:  1
                                                                       Effective:  3/27/98
                                                                          Page: 8 of 17
                            SAMPLE RECEIPT CHECKLIST

                       MRI Project Mn       P - o
Samples Received by:  /*?.'&-  CJ*-<\*.? _   Date:  7/2.
Airbill No.  %S"7  ££>*?  *~)l ?  13  _     Chain-of-Custody No.
Airbill present?         <5ip No    Chain-of-Custody present?     Yes   No

Shipping container intact? (£es) No   Container type  C*><>
Custody seals present?   Yes (Nd>   Seals intact?   Ye^ No   Seal Location:
C-O-C properly filled out? (^es) No   Does C-O-C indicate sample type?     Q£§§)  No

Ice packs or jcejrozen?    <^|s) No  Samples cold? (^Y_e§) No       Temperature 0G:

Sample containers intact?  (Y^es) No  Labels permanently affixed?   (Yej^)  No

Sample containers leaking? Yes  ^jg^ontainer type indicated?         Yes <^

Are all samples properly labeled and accounted for?     &§?  No

Are samples stored as indicated by the project leader?   (Yesy No

Is the C-O-C filled out completely, signed, and datedT^e^)  No

If pH check upon receipt is required, indicate where it is recorded,   h^ //>

Sample storage location:

COMMENTS
MRI-QA\MRI-3003JXX
                                         APPENDIX  A                                 30

-------
                                                                                   Sample Master LEMS

                                                                                   Sample Login Report
Customer Name: Engineering Department " X Order ID: 98090001 9 u/
Project ID: 4950.8.5 l X Order Date: 9/24/98 ^
Order Comment: Samples retrieved from MRI dock by M.Cheramy. \S *-/( 7 H 1 '") *>' '' '" ' L "^ Page: 1 of 1
MRI Sample ID
98003172

98003173

Customer Sample ID
9003A i^/
Peanut Hulls
/
9004A ^/
Peanut Hulls
Matrix Quantity Dale Collected Date Received Test Test Croup Method Due Date
^iqula" Sjl.'^j 1 -9/23/98 12:00 .AM "9/24/98 1 1 :07 AM test engineering ^

C > 1 i _/
Liqata >O(.UV ] v- 9/23/98 12:00 .AM -9/24/98 11:07 .AM test_engineering <--

 •0
 m
 z
 o
 H
 X
      SAMPLE CONDITION RECORD



                  Are samples submitted with a chain of custody?  Yes


Are the number of samples the same as stated on the chain of custody?  Yes


                      Are bottle caps tight and securely in place?  Yes <-^


                       Were all containers intact when received?  Yes -/


                        Were samples submitted in an ice chest?  Yes L/


                                 Were samples received cold?  Yes i-/


      Were samples within the holding time for the requested test(s)?  Yes t/


 Is the volume of sample submitted sufficient for the requested tcst(s)?  Yes LX


      Are all samples for volatile organic analyses free of headspace?  N/A —'
                                                                                                                                                          u*
^
                                                                                                                                                       p»
U

-------
D CHAIN OF CUSTODY RECORD
@ SAMPLE TRACEABILITY RECORD
Container (Cooler) No. AS/A

Paqe / of / Transfer No.
Checked by (Initials)/Date
Lock or Seal Intact (Yes or No)/Time
(Sample Container Label)
/*»?*

f/o* ¥A



















Relinquished By: Received By:
x£> Oto^- MT$^**O->
/L^£^/W
fO/M^^^^ ,6,^— %
/). Mi^,
Field Sample Custodian:

/
PA <*/,<.
effo
^
Remarks:
^
Remarks:

Remarks:

Remarks:

Remarks:

Remarks:

Remarks:

Remarks:

Remarks:

Remarks:

Remarks:
Sample Transfers:
Date Time No.
/*/* e<>ir 
«? f/ffop fO.'T^ ^
u/S'/fV n \-s~o A 3
/V/c/Tr /«-v. 4
Storage Requirements:
CH Ice water, <4°C
CH Dry ice
^ Room Temp., <26°C
O Other:





f/O'feJ

" /*'f*s



















Reason for Transfer:
*<.r*^*r* r~«^
fit-tfl ySxj~
nf^Sr^tf^ 17) ^C.tfQ
re ?**r ^-^
                                                       93-4  SEV  surm wkshl 020293
APPENDIX  A
                                                                 32

-------
                                                                       Code: MRI-5003
                                                                            Revision:  1
                                                                       Effective:  3/27/98
                                                                           Page: 8 of 17
                            SAMPLE RECEIPT CHECKLIST

                       MRI Project No.
Samples Received by:

Airbill No.   M hry"
/*: A.
Date
  :   9/
                                                                        3'°
                                                 Chain-of-Custody No.
Airbill present?         Yes  MjO---Chain-of-Custody present?     1
-------
                                                                               Sample Master LIMS

                                                                               Sample Login Report
           Customer Name:  Engineering Department

                Project ID:  4950.8.5  ^-/

          Order Comment:  Received by M.Cheramy from D. Alburty
                                                                                                                         Order ID:    980900027

                                                                                                                       Order Date:       9/30/98 -

                                                                                                                              Page:         1 of 1
         MRI Sample ID
Customer Sample ID
                                                Matrix
Quantity    Date Collected
                                                                                              Date Received
                                                                                                                Test
Test Group
                                                                                                                                              Method
                                                                                                                                                             Due Date
98003243

98003243

98003244

98003244

11003AC/
Pipe
11003A
Pipe
11004A1^
Pipe
11 004 A
Pipe
Other

Other

Other

Other

1 9/22/98 12:00 AM

1 9/22/98 12:00 AM

1 9/22/98 12:00 .AM

1 9/22/98 12:00 .AM

9/30/98 11:05 .AM

9/30,98 11:05 .AM

9/30/98 11:05 .AM

9/30/98 11:05 .AM

test metals v_^/
/
lest voa

test metals '
/*
tesl_voa

 •o
 •o
 m
 2
 O
 H
 X
                                                                                                   y
       SAMPLE CONDITION RECORD


                  Are samples submitted willi a chain of custody?  Yes

 Are the number of samples the same as stated on the chain of custody?  Yes

                      Are bottle caps tight and securely hi place?  N/A

                      Were all containers intact when received?  N/A

                        Were samples submitted hi an Ice chest?

                                Were samples received cold?  N/A IX

      Were samples within the holding lime for the requested test(s)?  N/A

 Is the volume of sample submitted sufficient for the requested test(s)?  Yes

      Are all samples for volatile organic analyses free ofheadspace?  N/A *	/
                                                                                                                                   5

W

-------
                                    Archive Samples
Archive Location
Sylvachem
Trigen
Hercules
Monsanto
General Motors
Corn Products Intnl.
Tri-Valley Growers
Georgia Pacific
Rack Processing
Galbraith Labs
Material
pitch from tall oil
brewery sludge
white rosin
yellow rosin
wood chips
SIC 28 Sludge
SIC 37 Sludge
Ag/corn gluten
Ag/corn germ
Ag/corn clean'g
Ag/peach pits
Ag/peanut hull
Non-PVC, grey/black
Non-PVC, red
Non-PVC, white
PVC Coating
Sample Number
1001 B, 1002B
2001 B, 2002B, 2003B, 2004B
3003B, 3004B
3003D, 3004D
3001B.3002B
4001 B, 4002B, 4003B, 4004A
5001 B, 5002B, 5003B, 5004B
6001 B
6005B, 6007B
6009B, 6011B
8001 B, 8002B, 8003B, 8004B
9001B, 9002B
11001B, 11002B
11003C, 11004C
11001D, 11002D
10002Ba
Sample originally intended to be analyzed, but was archived instead due to lab contamination
                                   Additional Samples
Sample Location
Corn Products Intl.; analysis to
be determined by facility
Tri-Valley Growers; analysis to
be determined by facility
Georgia Pacific; analysis to be
determined by facility
Material
Ag/corn gluten
Ag/corn germ
Ag/corn clean'g
Ag/peach pits
Ag/peanut hull
Sample Number
6001 C
6005C, 6007C
6009C, 601 1C
8001C
9001 C
                                         APPENDIX  A
                                                                                        35

-------
D CHAIN OF CUSTODY RECORD
13 SAMPLE TRACEABILITY RECORD
/;/
Oontflinpr (Ooolpr) N<~> • *J I ft
Paqe / of / Transfer No.
Checked by (Initials)/Date
Lock or Seal Intact (Yes or No)/Time
EMC 4950-08 2001B
Galbraith
EMC 4950-08 2002B
Galbraith
EMC 4950-08 2003B
Halogens
EMC 4950-08 2004B
Halogens
For disposal contact: J. Hosenfeld
MIDWEST RESEARCH INSTITUTE






Relinquished By: Received By:
<£Uw r;^ j%r&£r ' cfr



Field Sample Custodian:












Storage Requirements:
23 Ice water, < 4°C
CD Dry ice
CD Room Temp.. <26°C
CD Other:





Remarks:




Remarks:




Remarks:




Remarks:




Remarks:




Remarks:




Remarks:




Remarks:




Remarks:




Remarks:




Remarks:
Sample Transfers:
Date
?-/#-?£



Time




No.
1
2
3
4
Reason for Transfer:
s* M- /— / '
t^>-ff/ft-f7sr~"^ryA[fcJh^fJ



                                                         93-4 SEV surmwksht 020293
APPENDIX   A
                                                                   36

-------
D CHAIN OF CUSTODY RECORD
Q'SAMPLE TRACEABILITY RECORD
Container (Cooler) No. JL
Paae t Of / Transfer No.
Checked by (Initials)/Date
Lock or Seal Intact (Yes or No)/Time
(SB*--" ~ 	
EMC 4950-08 11001B
Galraiih/Halogens
EMC 4950-08 11002B
Galraith/Halogens
EMC 4950-08 11 00 ID
Galraith/Halogens
F
1 EMC 4950-08 11002D
Galraith/Halogens
EMC 4950-08 11003C
Halogens
;;;««*» HO°4C
. Halogens rinsenfeld
l^S'S^c^W^.




Relinquished By: Received By:
/r\ si / J- ft«.<-^ vYcc«.£$v/V,
XC/. (stLvtvrfi. £-&"& rfV<" J



Field Sample Custodian:
*^^^6>
>^>4 /
9/ax-
SJ//I
•""
Storage Requirements:
£2l Ice water, < 4°C
CD Dry ice
CH Room Temp., < 26°C
CH Other:





Remarks: ^
/*>c—s^c <- /3/S.t. H- i i/^-^ ^ <• y/~Z-J~
^-

Remarks:
^>
^

Remarks: ^^,
~/

Remarks:
y

Remarks:
f2^-£~D — /^^C(-^.xv(f


Remarks:
f^-(£O -- /^-i£-C(-/ 1 s^iT'


Remarks:


Remarks:


Remarks:


Remarks:


Remarks:
Sample Transfers:
Date Time No.
?/Z-Z_ / /^<* CD
2
3
4
Reason for Transfer:
"V A '
/"^ c^"^ •* /'irc>>i(/«j.



                                                   93-4 SEV surmwkshl 020293
APPENDIX  A
                                                             37

-------
                                          Appendix B
                                       Sampling Data
MRl-AEDV495l-OI-02.05TR.wjxJ

-------
                                      PITCH MATERIAL SAMPLING DATA
  MRI Project No.   4950.08
    Client/Source:   Sylvachem/Arizona Chemical Co.
 Source Location:   Port St. Joe, FL

 SAMPLING LOCATION: Tanker filling area
 SAMPLING METHOD: Composite samples representative of the material being used to load tank cars taken from the tap on
 the In-line Busing MRI S-7., Use ASTM D 4057 for guidance as necessary. Four sample replicates taken directly into 32 oz.
 jfeetearTecf, amb££glass bottles for physicaj/diemjcal analysis.  Each increment should be " 50 mL to collect a total sample
 volume of " 500 ml. BottleJrsealed with J^tet^-lme'tTscrew caps.  Ona -^nrnp10 sflT anri ritiplinntr irt inmnlrrl into 10 ml
SAMPLING FREQUEr.'CY^Six jffl or twelve (1 2?composite samples each consisting of ten (10) increments over a 100 minute


SAMPLE PRESERVATION: Samples stored at near ice temperature or colder (i.e., <;4°C).

Date Sampled:  ^//fr/^g
                                                                                                               Jlo-rrt-t.1

h







Sample
no.
1001 A
1001B
1001C
10010




Analysis
_&**_

/heo*






-p»P
,/
.urT





Lab | Sample
— Ci'M 0 r -j 	 ___
(j~ \ ' 002A
' 	 "=
^ ; 1 0028
j" ii)U2C —
10020
i
i
i
\ ••
i
Analysis
Single

=====
Af^i






Dup.
r^^
^^^^•~—






Lab
G/M/B/F
G~\
~7T>>
—

i



Sample

,^-,.
1003B
1003C
10030
^
1005 A
1005B
1005C
10050
Analysis
Single



=^^=



Dup.
^


•^•^•^•^•I^IB



Lab
G/M/B/F
n


	 i



Sample

"iee*A •
1004B
1004C
1004D
^^^•1™*
1006A
1006B
1006C
10060
'3
                                                    APPENDIX B

-------
                                           er^
                             INDUSTRIAL SLUDGE MATERIAL SAMPLING DATA
  MRI Project No.  4950.08
    Client/Source:  Trigen Energy Corp.
 Source Location:  Golden, CO

SAMPLING LOCATION: Day tank line to boiler

SAMPLING METHOD: Composite samples representative of the material being used to fire the boiler taken from the tap on
the day tank line using  MRI S-7.  Use ASTM D 4057 for guidance as necessary.  One sample set and replicate set taken
directly into 32 oz. precleaned, amber glass bottles for physical/chemical analysis.  Each increment should be " 50 ml to
collect a total sample volume of " 500 mL.  Bottles  sealed with Teflon®-lined screw caps.  One sample set and replicate set
sampled into 40 mL VOA vials, then each set separately composited and subsampled into single 40 mL VOA vials for halogens
analysis.

SAMPLING FREQUENCY: Four (4) or eight (8) composite samples, depending on homogeneity of material, each consisting of
ten (10) increments over a 100 minute period.

SAMPLE PRESERVATION: Samples stored at near ice temperature or colder (i.e., s4°C).
Date Sampled:
Sampler(s):
Sample
no.
2001 A
2001 B
2001 C
20010
Analysis
Single




Dup.
Y,



Lab
G/M/B/F
AA\L
-ft


Sample
no.
2002A
2002B
2002C
20020
Analysis
Single




Dup.




Lab
G/M/B/F




Sample
no.
2003A
2003B
2003C
2003D
Analysis
Single




Dup.
Y



Lab
G/M/B/F
f^SL
&


Sample

2004A
2O04B
2004C
2004D
Analysis
Single




Oup.




Lab
G/M/B/F




G = Galbraith Laboratories; see sampling and analysis matrix for analytical requirements.
M = MRI; see sampling and analysis matrix for analytical requirements.
B = Backup archived at facility; to be used in case Galbraith or MRI sample is compromised in sample shipping process only.
F = Facility; analysis to be determined by donor facility.
Source and Description of Material:.


                Time       	
                                               &&


                                                                                                         CO
   Grab
   No.
                                                       Interruptions/Comments
1
2
3
4
5
6
7
8
9
10
Relinquished By    U/A
    Received By   A//A.
                                                                                Date/Time
SAMPBS.WPD  September 11, 1998
                                                   APPENDIX  B

-------
                            INDUSTRIAL SLUDGE MATERIAL SAMPLING DATA
  MR1 Project No.  4950.08
    Client/Source:  Trigen Energy Corp.
 Source Location:  Golden, CO

 SAMPLING LOCATION: Day tank line to boiler

 SAMPLING METHOD: Composite samples representative of the material being used to fire the boiler taken from the tap on
 the day tank line using MRI S-7. Use ASTM D 4057 for guidance as necessary.  One sample set and replicate set taken
 directly into 32 oz. precleaned,  amber glass bottles for physical/chemical analysis. Each increment should be " 50 mL to
 collect a total sample  volume of " 500 mL.  Bottles sealed with Teflon®-lined screw caps. One sample set and replicate set
 sampled into 40 mL VOA vials, then each set separately composited and subsampled into single 40 mL VGA vials for halogens
 analysis.

 SAMPLING FREQUENCY:  Four (4) or eight (8) composite samples, depending on homogeneity of material, each consisting of
 ten (10) increments over  a 100  minute period.

 SAMPLE PRESERVATION: Samples stored at near ice temperature or colder (i.e., ^4°C).
Date Sampled:
                                     Samolerts):
Sample
no.
2001 A
2001 B
2001 C
2001 D
Analysis
Single




Dup.




Lab
G/M/B/F




Sample

2002A
20028
2002C
2002D
Analysis
Single




Dup.
X



Lab
G/M/B/F
SojtL
&


Sample
no.
2003A
2003B
2003C
2003D
Analysis
Single




Dup.




Lab
G/M/B/F




Sample

2004A
2004B
2004C
2004D
Analysis
Single




Dup.
X



Lab
G/M/B/F
£t5-P_
-$


G = Galbraith Laboratories; see sampling and analysis matrix for analytical requirements.
M = MRI; see sampling and analysis matrix for analytical requirements.
B = Backup archived at facility; to be used in case Galbraith or MRI sample is compromised in sample shipping process only.
F = Facility; analysis to be determined by donor facility.

Source and Description of  Material:	
   Grab
    No.
               Time
 1
 2
 3
 4
 5
 6
 7
 8
 9
 10
Interruptions/Comments
Relinquished By  AJ(/4
                                         Received By
N/A
Date/Time
SAMPBS.WPD  September 11.1998
                                                   APPENDIX  B

-------
                                          (OW)  MATERIAL SAMPLING DATA
  MRI Project No.  4950.08
    Client/Source:  Hercules, Inc.
 Source Location:  Brunswick, GA

 SAMPLING LOCATION: Fuel feed conveyor.

 SAMPLING METHOD: Composite samples\representative of the material being used to load stoker scooped from the feed
 conveyor according to MRI S-9. Use ASTM]D 346 for subsampling guidance.  Samples subsampled and placed into a 32 oz.
 precleaned, wide mouth, glass bottles.  Bottles sealed with Teflon®-lined screw caps.
                     ^"^	>k       /a*\
 SAMPLING FREQUENCY: (Two (2)jor four (4f composite samples, depending on the homogeneity of the material, each sample
 consisting of ten 00) grabVttOrmg normal operation.

 SAMPLE PRESERVATION: Samples for chemical analysis stored at neafice temperature or colder (i.e., s4°C).

 Date Sampled:   92£~	  Sampler(s):     tt>***&.5    0.
* ^~
Sample
no.
3001 A
3001 B
3001 C
3001 D
Analysis
Single

A/U«*


Oup.
<^
if


Lab
G/M/B/F
&•
g


Sample
\
3002A
3002B\
3002C \
3002D
Analysis
Single

#u*

\
Dup.
•^
!u
-------
                            SCRAP ROSIN (OS) MATERIAL SAMPLING DATA (SIC-28)
     MRI Project No.  4950.08
      Client/Source:  Hercules, Inc.
    Source Location:  Brunswick, GA

   SAMPLING LOCATION: Scrap rosin bin.

   SAMPLING METHOD: Composite samples representative of the material being used to load stoker scooped from the scrap rosin
   bin according to MRI S-9.  Use ASTM D 346 for subsampling guidance.  Samples subsampled and placed into a 32 oz.
   precleaned, wide mouth,  glass bottles. Bottles sealed with Teflon®-lined screw caps.
                              £»V  x	-•„
   SAMPLING FREQUENCY: .Twe-(2) or iour (4), composite samples, depending on the homogeneity of the material, each sample
   consisting of ten (10) grabs during norrnaToperation.    •*-  •i-^~~f>tj  ^ I~U,L_,  ^ ^.
                                                     T  2~ Si^v-ji^i.? .-/  Y* lU-\~> cr^
   SAMPLE PRESERVATION: Samples for chemical analysis stored at near ice temperature or colder (i.e., i4°C).
   Date Sampled:
                                     Sampler(s):  P. .At. ^
Sample
no.
3003A
3003B
3003C
3003D
Analysis
Single
V
^/^.
\,s
A AC
Dup.

\fȣ


Lab
G/M/B/F
o-
,3
6"
3
Sample

3004A
30048
3004C
3004D
Analysis
Single
i/
/^/t-<-
•S
/•I iZ. »y
Dup.

./.i/.-'

IV/i'
Lab
G/M/B/F
cl-
/3
Cr
2
-S^ple^




.^-
Analysis
anBTe—



-^
-..Dup.
"^~-

^- 	

Lab
G/M/B/F
\^
_^^
'

Sample


xC^


Analysis
Single
^^

^--

Dj*^


^^

>^
G/M/B/F



~- --o
I  <
:i
   G — Galbraith Laboratories; see sampling and analysis matrix for analytical requirements.
   M = MRI; see sampling and analysis matrix for analytical requirements.
   B - Backup archived at facility; to be used in case Galbraith or MRI sample is compromised in sample shipping process only.
   F - Facility; analysis to be determined by donor facility.
Source and Description of Material:
                                                                 --  12.
     Grab
      No.
               Time
                   Interruptions/Comments
   1
   2
   3
   4
   5
   6
   7
   8
   9
   10
jV-^v-'-.°'j  &F*
                                                                                                  (re  .-,<-<
                                                                             • ^ JP C~7L,
                                SIt-"<> T~T
                                                     ff'-l
  Relinquished By.
                                          Received By
                                            Date/Time  3/z
  SAMPOS.WPO November 30, 1998
                                                      APPENDIX  B

-------
                         Sic,
                  COMBINED INDUSTRIAL WWTP SLUDGE MATERIAL SAMPLING DATA
  MRI Project No.  4950.08
    Client/Source:  Monsanto Agricultural Co.
 Source Location:  Muscatine, IA

SAMPLING LOCATION: Circulated day tank line to boiler

SAMPLING METHOD: Composite samples representative of the material being used to fire the boiler taken from the tap on
the day tank feed line using MRI S-7. Use ASTM D 4057 for guidance as necessary. One sample set and replicate taken
directly into 32 oz. precleaned, amber glass bottles for physical/chemical analysis.  Each increment should be " 50 mL to
collect a total sample volume of " 500 mL. Bottles sealed with Teflon®-lined screw caps.  One sample set and replicate set
sampled into 40 mL VOA vials, then each set separately composited and subsampled into single 40 mL VOA vials for halogens
analysis.

SAMPLING FREQUENCY: Four (4) or eight (8) composite samples each consisting of ten (10) increments over a 100 minute
period.

SAMPLE PRESERVATION:  Samples stored at near ice temperature or colder (i.e., s4°C).
Date Sampled:
                      y
                                     Sampler(s):
Sample
no.
4001A
4001 B
4001 C
4O01D
Analysis
Single




Oup.




Lab
G/M/B/F




Sample
no.
4002A
4002B
4002C
4002D
Analysis
Single




Dup.
X



Lab
G/M/B/F
&$>
&


Sample
no.
4003A
4O03B
4003C
4003D
Analysis
Single




Dup.




Lab
G/M/B/F




Sample
no.
.,V
^
4£Vfi
4004C
40040
Analysis
Single




Dup.
*



Lab
G/M/B/F
fr^L
£


G = Galbraith Laboratories; see sampling and analysis matrix for analytical requirements.
M ** MRI; see sampling and analysts matrix for analytical requirements.
B «• Backup archived at facility; to be used in case Galbraith or MRI sample is compromised in sample shipping process only.
F = Facility; analysis to be determined by donor facility.

Source and Description of Material:  /Zf O/O3/9/&/£   ft USC-fyT/JU£. •£>?  /yf C/Zy T^  $<>A_ 8 -ft*
   Grab
   No.
                Time
Interruptions/Comments
1
2
3
4
5
6
7
8
9
10
                              .0 i
Relinquished By    /J/A
                                         Received Bv  /J M
                                                                               Dat^/Time  AJ/
EAMFTPS.WPD September 11,  1998
                                                  APPENDIX  B

-------
                  COMBINED INDUSTRIAL WWTP SLUDGE MATERIAL SAMPLING  DATA
  MRI Project No.  4950.08
    Client/Source:  Monsanto Agricultural Co.
 Source Location:  Muscatine, IA

SAMPLING LOCATION: Circulated day tank line to boiler

SAMPLING METHOD: Composite samples representative of the material being used to fire the boiler taken from the tap on
the day tank feed line using MRI S-7.  Use ASTM D 4057 for guidance as necessary.  One sample set and replicate taken
directly into 32 oz. precleaned, amber glass bottles for physical/chemical analysis.  Each increment should be " 50 mL to
collect a total sample volume of " 500 mL.  Bottles sealed with Teflon®-lined screw caps. One sample set and replicate set
sampled into 40 mL VOA vials, then each set separately composited and subsampled into single 40 mL VOA vials for halogens
analysis.

SAMPLING FREQUENCY: Four (4) or eight (8)  composite samples each consisting of ten (10) increments over a 100 minute
period.

SAMPLE PRESERVATION: Samples stored  at near ice temperature or colder (i.e.,

Date Sampled:  7//(0//£^'     Sampler(s):   3 • A3l
Sample
no.
4001 A
4001 B
4001 C
40010
Analysis
Single




Dup.
y.



Lab
G/M/B/F
CxtfL
A


Sample

4002A
4002B
4002C
4002D
Analysis
Single




Dup.




Lab
G/M/B/F




Sample

4003A
4003B
4003C
4003D
Analysis
Single




Dup.
X



Lab
G/M/B/F
cWL
-B


Sample

4004A
4004B
4004C
40O4D
Analysis
Single




Dup.




Lab
G/M/B/F




G = Galbraith Laboratories; see sampling and analysis matrix for analytical requirements.
M = MRI; see sampling and analysis matrix for analytical requirements.
6 = Backup archived at facility; to be used in case Galbraith or MRI sample is compromised in sample shipping process only.
F = Facility; analysis to be determined by donor facility.

Source and Description of Mtari.,1:
                                                                                                       &
                                                       Interruotions/Comments
                                                                                               U
                                                                                                         /
Relinquished By
                                         Received By
Date/Time
N/fi
SAMPTPS.WPD September 11.1998
                                                   APPENDIX  B

-------
                                 vj
                          s i
                   COMBINED INDUSTRIAL WWTP SLUDGE MATERIAL SAMPLING DATA
  MRI Project No.  4950.08
    Client/Source:  General Motors Corporation, NAO
 Source Location:  Flint, Ml

 SAMPLING LOCATION: Circulated day tank line to boiler

 SAMPLING METHOD: Composite samples representative of the material being used to fire the boiler taken from the tap on
 the day tank feed line using MRI S-7.  Use ASTM D 4057 for guidance as necessary.  One sample set and replicate set taken
 directly into 32 oz. precleaned, amber glass bottles for physical/chemical analysis.  Each increment should be  " 50 ml to
 collect a total sample volume of "  500 mL.  Bottles sealed with Teflon®-lined screw caps. One sample set and replicate set
 sampled into 40 mL VOA vials, then each set separately composited and subsampled into single 40 mL VOA vials for halogens
 analysis.

 SAMPLING FREQUENCY: Four (4) or eight (8) composite samples each consisting of ten (10) increments over a  100 minute
 period.

 SAMPLE PRESERVATION: Samples stored at near ice temperature or colder (i.e., 


Sample
no.
5002A
5002B
5002C
S002D
Analysis
Single




Dup.
_l^




Lab
G/M/B/F
JT* A




Sample
no.
5003A
50038
5003C
50O3D
Analysts
Single




Dup.
Y



Lab
G/M/B/F
*&,£)
1ft '


Sample

5004A
50048
5004C
50040
Analysis
Single




Dup.




Lab
G/M/B/F




G = Galbraith Laboratories; see sampling and analysis matrix for analytical requirements.
M = MRI; see sampling and analysis matrix for analytical requirements.
B = Backup archived at facility; to be used in case Galbraith or MRI sample is compromised in sample shipping process only.
F = Facility; analysis to be determined by donor facility.

Source and Description of Material:.
   Grab
    No.
Time
Interruptions/Comments
1
2
3
4
5
6
7
8
9
10
Relinquished By
                          Received By.
                         Date/Time
SAMPIWS.WPD  September 11, 1998

-------
                                  3  /
                  COMBINED INDUSTRIAL WWTP SLUDGE MATERIAL SAMPLING DATA
  MRI Project No.  4950.08
    Client/Source:  General Motors Corporation, NAO
 Source Location:  Flint, Ml

SAMPLING LOCATION: Circulated day tank line to boiler

SAMPLING METHOD: Composite samples representative of the material being used to fire the boiler taken from the tap on
the day tank feed line using MRI S-7. Use ASTM D 4057 for guidance as necessary. One sample set and replicate set taken
directly into 32 oz. precleaned, amber glass bottles for physical/chemical analysis. Each increment should be " 50 mL to
collect a total sample volume of " 500 mL.  Bottles sealed with Teflon®-lined screw caps. One sample set and replicate set
sampled into 40 mL VOA vials, then each set separately composited and subsampled into single 40 mL VOA vials for halogens
analysis.

SAMPLING FREQUENCY: Four (4) or eight (8) composite samples each consisting of ten (10) increments over a 100 minute
period.

SAMPLE PRESERVATION: Samples stored at near ice temperature or colder (i.e.,  <;4°C).

Date Sampled:     (/'^ / /cT       Sampler(s):      ^)-
Sample
no.
5001 A
5001B
5001 C
5001 D
Analysis
Single




Dup.




Lab
G/M/B/F




Sample

5002A
S002B
6002C
5002D
Analysis
Single




Dup.
^



Lab
G/M/B/F
/W)/L
_&


Sample

5003A
6003B
5003C
5003D
Analysis
Single




Dup.




Lab
G/M/B/F




Sample
no.
S004A
S004B
5004C
5004D
Analysis
Single




Dup.
X



Lab
G/M/B/F
6-
£


G = Galbraith Laboratories; see sampling and analysis matrix for analytical requirements
M •= MRI; see sampling and analysis matrix for analytical requirements.
B = Backup archived at facility; to be used in case Galbraith or MRI sample is compromised in sample shipping process only.
F = Facility; analysis to be determined by donor facility.
Source and Description of Material:
                                          %//-) T^A
Grab
 No.
               Time
                                                       Interruptions/Comments
 1
 2
 3
 4
 5
 6
 7
 8
 9
 10
Relinquished By
                                         Received By
                                                                             Date/Time
SAMPIWS.WPD September 11,1998
                                                   APPENDIX  B

-------
                             CORN GLUTEN FEED MATERIAL SAMPLING DATA
  MRI Project No.  4950.08
    Client/Source:  Corn Products International.
 Source Location:  Winston Salem, NC

SAMPLING LOCATION: Corn gluten feed dumpster

SAMPLING METHOD: Composite samples representative of the material being used to fire boiler scooped from the storage
dumpster according to MRI S-9.  Use ASTM D 140, ASTM D 346, ASTM D 2234 and ASTM 4057 for guidance as necessary.
Two samples subsampled and placed into  a 32 oz. precleaned, wide mouth,  glass  bottlesfor physical/chemical analysis.
Bottles sealed with Teflon®-lined screw caps.  Two samples subsampled into 1 -gal containore for particle sizing.
SAMPLING FREQUENCY: (Four (OF
                                         composite samples each consisting of t
                                                                                     grabs during normal operation.
SAMPLE PRESERVATION: Samples for chemical analysis stored at near ice temperature or colder (i.e., <;4°C).  Samples for
particle sizing packed to minimize shock.
Date Sampled:
                                     Sampler(s):
Sample
no.
6O01A
6001 B
6001 C
6001 D
Analysis
Single




Dup.
^L£ c&
•G"£A

Sample

6O04A
60O4B
6004C
60O4D
Analysis
Single




Dup.
~S



Lab
G/M/B/F
M



G = Galbraith Laboratories; see sampling and analysis matrix for analytical requirements.
M B MRI; see sampling and analysis matrix for analytical requirements.
B - Backup archived at facility; to be used in case Galbraith or MRI sample is compromised in sample shipping process only
F = Facility; analysis to be determined by donor facility.
Source and Description of Material:
                                         >-  3 * f   0Ui**pSTirtt-
   Grab
    No.
                Time
                                                       Interruptions/Comments
 1
 2
 3
 4
 5
 6
 7
 8
 9
 10
                                      .  6.CC2.A
Relinquished By
                                         Received By    /y//
-------
                                  CORN GERM MATERIAL SAMPLING DATA
  MR1 Project No.  4950.08
    Client/Source:  Corn Products International.
  Source Location:  Winston Salem, NC
 SAMPLING LOCATION: Reject corn germ accumulation dumpster

 SAMPLING METHOD: Composite samples representative of the material being used to fire boiler scooped from the storage
 dumpster according to MRI S-9.  Use ASTM D 140, ASTM D 346, ASTM D 2234 and ASTM 4057 for guidance as necessary.
 Two samples subsampled and placed into a 32 oz. precleaned, wide mouth,  glass bottles for physical/chemical analysis.
 Bottles sealed with Teflon®-lined screw caps.  Two samples subsampled into  1-gal mdfaVp SififaaneTor particle sizing.
                       /}                                               >.
 SAMPLING FREQUENCY^Four (4/oi' dylil tffi composite samples each consisting of ten (10) grabs during normal operation.

 SAMPLE PRESERVATION: Samples for chemical analysis stored at near ice temperature or colder (i.e., s4°C).  Samples for
 particle sizing packed to minimize shock.
 Date Sampled:
                      Sampler(s):   /?, AL- A'u
-------
                              CORN CLEANINGS MATERIAL SAMPLING DATA
  MRI Project No.  4950.08
    Client/Source:  Corn Products International.
 Source Location:  Winston Salem, NC

SAMPLING LOCATION: Corn cleanings accumulation dumpster

SAMPLING METHOD: Composite samples representative of the material being used to fire boiler scooped from the storage
dumpster according to MRI S-9. Use ASTM D 140, ASTM D 346, ASTM D 2234 and ASTM 4057 for guidance as necessary.
Two samples subsampled and placed into a 32 oz. precleaned, wide mouth,  glass bottles for physical/chemical analysis.
Bottles sealed with Teflon®-lined screw caps. Two samples subsampled into 1 -gal metal paint cans for particle sizing.

SAMPLING FREQUENCY:(^our (4l;or eight (8) composite samples each consisting of ton^TQ) grabs during normal operation.
SAMPLE PRESERVATION: Samples for chemical analysis stored at near ice temperature or colder (i.e., s4°C).  Samples for
particle sizing packed to minimize shock.
Date Sampled:
Sampler(s):   A.
                                                         G u fl.T'r'
Sample
no.
6009A
6009B
6009C
60090
Analysis
Single




Dup.
X



Lab
G/M/B/F

-------
                                 RICE HUSKS MATERIAL SAMPLING DATA
  MRI Project No.  4950.08
   Client/Source:  Agrilectric Power, Inc.
 Source Location:  Lake Charles, LA

SAMPLING LOCATION: Fuel feed inlet
                                                                                               i*V
SAMPLING METHOD: Composite samples representative of the material being used to fire boiler seeSoelJ from the pneumatic
feed system-tnfeTaccording to MRI S-9. Use ASTM D 140, ASTM D 346, and ASTM 4057 for guidance as necessary. Two
replicate samples subsampled and placed into a 32 oz. precleaned, wide mouth, glass bottles for physical/chemical analysis.
Bottles sealed with Teflon®-lined screw caps. Two replicate samples subsampled into 1-gal containers for particle sizing.
                         	^_|            .t £fl I W

SAMPLING FREQUENCY: ^gurJ47 or etgnTTSTcomposite samples, depending on fuel homogeneity, each consisting of ten (10)
grabs during normal operation.

SAMPLE PRESERVATION: Samples for chemical  analysis stored at near ice temperature or colder (i.e., s4°C).  Samples for
particle sizing packed to minimize shock.

                9//V  /?*-
Date Sampled:
Sampler(s):
                                                                         cJ
Sample
no.
7001 A
7001B
7001C
70010
Analysis
Single




Dup.
S



Lab
G/M/B/F
h-



Sample

7002A
70028
7002C
7002D
Analysis
Single




Dup.
s
_


Lab
G/M/B/F
Cr



Sample

7003A
7003B
7003C
7003D
Analysis
Single




Dup.
^



Lab
G/M/B/F
V*



Sample

7004A
7004B
7004C
7004D
Analysis
Single




Dup.
*s



Lab
G/M/B/F
/"<



G = Galbraith Laboratories; see sampling and analysis matrix for analytical requirements.
M = MRI; see sampling and analysis matrix for analytical requirements.
B = Backup archived at facility; to be used in case Galbraith or MRI sample is compromised in sample shipping process only.
F «= Facility; analysis to be determined by donor facility.
Source and Description of Material:.
   Grab
    No.
                                                               Qv
                                                                   l
               Time
                                                      Interruptions/Comments
1
2
3
4
5
6
7
8
9
10
             Qclf?
            0
                                                                                      -fc I
                                                             fit-
                                                                                               1 rt AC
Relinquished By
                                          Received By.
                                                                               Date/Time /V/A
SAMPRH.WPD  September 11, 1998
                                                   APPENDIX  B
                                                                                                     13

-------
                                 PEANUT HULL MATERIAL SAMPLING DATA
  MRI Project No.  4950.08
    Client/Source:  Georgia Pacific Great Southern Paper, Inc.
 Source Location:  Cedar Springs, GA

SAMPLING LOCATION: Storage building

SAMPLING METHOD: Composite samples representative of the material being used to fire boiler scooped from the pile in the
storage area according to MRI S-9.  Use ASTM D 140, ASTM D 346, ASTM D 2234 and ASTM 4057 for guidance as
necessary.  Two samples  subsampled and placed into a 32 oz. precleaned, wide mouth,  glass bottles for physical/chemical
analysis. Bottles sealed with Teflon®-lined screw caps.  Two samples subsampled into 1-gal containers for particle sizing.

SAMPLING FREQUENCY:  Four (4) or eight (8) composite samples each consisting of  twenty five (25) grabs from just below
the surface of the pile.

SAMPLE PRESERVATION: Samples for chemical analysis stored at near ice temperature or colder (i.e., s4°C).  Samples for
particle sizing packed to minimize shock.
Date Sampled:
                                     Sampler(s):
Sample
no.
9001 A
9001 B
9001 C
• JUU I U ^
Analysis
Single

/Vauf.

fc-
Dup.
^
u
-------
                             PVC RACK COATING MATERIAL SAMPLING DATA
  MRI Project No.  4950.08
    Client/Source:  Rack Processing Co., Inc.
 Source Location:  Dayton, OH

 SAMPLING LOCATION: Rack stripping area

 SAMPLING METHOD: Composite samples representative of the material being used to load stripping ovens scraped with Rlastic
 implements from the  racks according to MRI S-9.  Use ASTM D 140, ASTM D 346, and ASTM 4057 for guidance. Samples
               placed into a 32 oz. precleaned, wide mouth, glass bottles.  Bottles sealed with Teflon®-lined screw caps.
 SAMPLING FREQUENCY: Isffo (Dhar {pur(41x:ornposite samples, depending on the homogeneity of the material, each sample
 consisting of ten (10) grabs during normal operation.               U-^rCo  v*  •*/(-#. y<_  /./ f-j^jyiit c e. jr ^ -r
 SAMPLE PRESERVATION: Samples stored at near ice temperature or colder (i.e.,  s4°C).   £-*?. ^a ,^j . rvt
Date Sampled: *? '/ 2f-
               • i •  '
                                     Sampler(s):  r>  A.
                                                  —
                                                                    D .  ^ ciAr<—
                                                                    ^.,..
Sample
no.
10001$
10001^1
*^B601 6 C.
10001 P"

Analysis
Single
IS
) ^
T3«-

ta]
Dup.




Lab
G/M/B/F
(^
6^


Sample

loooaXi-
^^
rffinpM —
-innn?p f
Analysis
Single
> ^
l
PA-
4*
JSrAr-
Dup.




Lab
G/M/B/F




 G = Galbraith Laboratories; see sampling and analysis matrix for analytical requirements.^ .
 M - MRI; see sampling and analysis matrix for analytical requirements.               \fr\i
 B = Backup archived at facility; to be used in case Galbraith or MRI sample is compromised in sample shipping process only.
 F = Facility; analysts to be determined by donor facility.
Source and Description of Material:  c,/>>tL>>c(>  r
                                                     (LA
   Grab
    No.
 1
 2
 3
 4
 5
 6
 7
 8
 9
 10
               Time
                                                       Interruptions/Comments
                  oil*
                                              / 0-0-0
Relinquished By  /U- (&ti-w^
                                          Received By   fZ
Date/Time
                                                                                                       * f>»\
SAMPPVC.WPD  September 11, 1998
                                                   APPENDIX B
                                                                                                      15

-------
                                      RACK COATING MATERIAL SAMPLING DATA
     MR1 Project No.  4950.08
       Client/Source:  Rack Processing Co., Inc.
    Source Location:  Piqua, OH
   SAMPLING LOCATION: Rack stripping area                                                                        -*«,

   SAMPLING METHOD: Composite samples representative of the material being used to load stripping ovens scraped with plastic  \
   implements from the racks according to MRI S-9.  Uae_p.aint fitrippar iLnrrpssary (and take solvent blank(o) in VOA vialloDV
    Use ASTM D 140, ASTM D 346, and ASTM 4057 for guidance.  Samples subcamplcd ffnefplaced into a 32 oz.  precleaned,
   wide mouth,  glass bottles.  Bottles sealed with Teflon®-lined screw caps.
                                                V *»£.!.•
    SAMPLING FREQUENCMPrwo (2i)-orQpur (4j/composite samples, depending on the homogeneity of the material, each sample
    consisting of ten (10) grabs~3urmg norrnaToperation. Ifuaatorial cannot be arlpgiiritply pwnporatod, uae VOA vioh fnr hnlogcn.
    analycic samples.  Solvent blank idktjll once per conlainei Of iiTatciiaLusgcr'^PA

    SAMPLE PRESERVATION: Samples stored at near ice temperature or colder (i.e., ^4°C).

                                         Sampler(s):  £),
0
®
  1100ZD




Analysis
Single

A&u
•M*W—
^*




Dup.
•<-^
IS
t





Lab
G/M/B/F
J>S7 '
sl^ {
p> '





Sample
no.
0 i
•"T1004A
>11004B
3*10040
.M004PA




Analysis
Single
We

*
-------
                                           Appendix C
                                    Galbraith Reports
MRI-AEDV4951-01-02-OSTR.wpd

-------
GALBRAITH® LABORATORIES, INC.
            Accuracy with speed since 1950
         LABORATORY REPORT
David Alburty
Midwest Research Institute
425 Volker Blvd.
Kansas City MO 64110
SAMPLE ID LAB ID ANALYSIS
2001A Z-3917-18 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
Report Date: 11/19/98
Sample Received: 09/21/98
Purchase Order #: A035822
Fax#: 816-531-0315
As
Received
95.30 %
95.25 %
1.77 %
1.76 %
10.85 %
10.85 %
0.28 %
0.27 %
0.05 %
0.05 %
1.40 %
1 .40 %
45.5 ppm
37.7 ppm
4.0 ppm
3.9 ppm
<9 ppm
<10 ppm
0.7 ppm
0.9 ppm
0.96 %
0.97 %
330 Btu/lb
329 Btu/lb
Dry

37.38 %
37.30 %
5.68 %
5.68 %
5.84 %
5.77 %
1.08 %
1.07 %
29.67 %
29.56 %
964 ppm
798 ppm
84 ppm
82 ppm
<190 ppm
<210 ppm
14 ppm
19 ppm
20.25 %
20.54 %
6985 Btu/lb
6966 Btu/lb
Method
ASTMD-5142
ASTM D-5373
ASTM D-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTM D-3 869
ASTM D-3 176
ASTM D- 1989
      This report shall not be reproduced, except in full, without the written approval of the laboratory.
                                                                  Pagel of 13
    BUILDING
   PARTNERSHIPS
FOR CONTINUOUS IMPROVEMENT
        U.S. Mail: P.O. Box 51610  •  Knoxvi/le, TN 37950-1610

        Other Carriers: 2323 Sycamore Drive    Knoxville, TN 37921-1750
        Tel: (423) 546-1335 •  Fax: (423) 546-7209
               APPENDIX C

-------
GALBRAITH® LABORATORIES,  INC.
            Accuracy with speed - since 1950
         LABORATORY REPORT
David Alburty
Midwest Research Institute
I SAMPLE ID LAB ED ANALYSIS
I
2001 A Z-3917-18 Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
Report Date:
Lab I.D.:
As
Received
41
37
<0.4
<0.4
<0.4
<0.4
<0.2
<0.2
<0.2
<0.2
1.4
1.2
4.5
4.5
0.0094
0.0094
<0.4
<0.4
0.073
0.078
1.5
1.5
O.0024
O.0025
<0.0024
O.0025
<0.0024
<0.0024
0.7
0.7
0.015
0.016

ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
ppm
ppm
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Dry
878
783
<8
<8
<8
<8
<5
<5
<5
<5
29
25
96
94
0.20
0.20
<8
<8
1.55
1.66
32
31
<0.051
<0.052
<0.050
<0.052
<0.051
<0.051
16
14
0.32
0.33
11/19/98
Z-3917-22

ppm
ppm
ppm
ppm
Ppm
ppm
ppm
ppm
Ppm
ppm
Ppm
ppm
ppm
ppm
%
%
ppm
ppm
%
%
ppm
ppm
ppm
PPm
ppm
ppm
PPm
ppm
PPm
PPm
%
%
II Method
II
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
     This report shall not be reproduced, except in full, without the written approval of the laboratory.
                                                                    Page 2 of 13
    BUILDING
   PARTNERSHIPS
FOR CONTINUOUS IMPROVEMENT
       U.S. Mail: P.O. Box 51610  •  Knoxville, TN 37950-1610

       Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1 750
       Tel: (423) 546-1335   Fax: (423) 546-7209
               APPENDIX C

-------
                         GALBRAITH® LABORATORIES,  INC.
                                      Accuracy with speed - since 1950
David Alburty
Midwest Research Institute
                                   LABORATORY REPORT
                 Report Date:
                 Lab I.D.:
11/19/98
Z-3917-22
SAMPLED)
LAB ID
ANALYSIS
As
Received
Dry
Method
2001 A Z-3917-18 Selenium
Silver
Sodium
Vanadium
Zinc
<0.4
<0.4
<0.04
<0.05
0.0090
0.0094
0.6
0.5
3.6
3.9
ppm
ppm
ppm
ppm
%
%
ppm
ppm
ppm
ppm
<8
<8
<1
<1
0.19
0.20
12
10
76
82
ppm
ppm
ppm
ppm
%
%
ppm
ppm
ppm
ppm
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
                              This report shall not be reproduced, except in full, without the written approval of the laboratory.
                                               Page 3 of 13
                  BUIt-DlrSfG
                 PARTNERSHIPS
             FOR CONTINUOUS iMrRO
U.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
Tel: (423) 546-1335  • Fax: (423) 546-7209
                                         APPENDIX  C

-------
           GALBRAITH® LABORATORIES, INC.
                        Accuracy with speed  since 1950
                     LABORATORY REPORT
David Alburty
Midwest Research Institute
I SAMPLE ID LAB ID ANALYSIS
I
2002A Z-3919-20 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
Report Date: 11/19/98
Labl.D.: Z-3917-22
As
Received
95.41 %
95.44 %
1.70 %
1.69 %
10.86 %
10.87 %
0.26 %
0.26 %
0.04 %
0.04 %
1.39 %
1.38 %
113 ppm
92 ppm
12 ppm
11 ppm
<9 ppm
<9 ppm
0.4 ppm
0.3 ppm
0.92 %
0.94 %
Dry

37.14 %
36.91 %
5.68 %
5.86 %
5.60 %
5.62 %
0.86 %
0.90 %
30.30 %
30.07 %
2460 ppm
2000 ppm
250 ppm
240 ppm
<200 ppm
<190 ppm
9.3 ppm
7.2 ppm
20.17 %
20.44 %
Method
ASTMD-5142
ASTMD-5373
ASTMD-5373
ASTMD-5373
ASTMD-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTMD-3869
ASTMD-3176
           HHV
        285
Btu/lb
6236
                                             (a)
Btu/lb
ASTMD-1989
    BUILDING
   PARTNERSHIPS
FOR CONTINUOUS IMPROVEMENT
                 This report shall not be reproduced, except in full, without the written approval of the laboratory.
U.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610

Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
Tel: (423) 546-1335 •  Fax: (423) 546-7209



        APPENDIX C
                                                 Page 4 of 13

-------
           GALBRAITH® LABORATORIES,  INC.
                       Accuracy with speed  since 1950
                     LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
2002A Z-3919-20 Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
Report Date:
Labl.D.:
As
Received
37
35
<0.4
<0.4
<0.4
<0.4
O.2
<0.2
<0.2
<0.2
1
1
4
4
0.0092
0.0092
<0.4
<0.4
0.086
0.086
1.5
1.5
O.0024
<0.0023
0.0023
<0.0024
<0.0024
<0.0023
0.9
0.6
0.015
0.016

ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
ppm
ppm
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Dry
820
770
<8
<8
<8
<8
<5
<5
<5
<5
29
25
96
93
0.20
0.20
<8
<8
1.89
1.87
33
32
<0.052
<0.051
0.051
0.052
0.052
O.051
19
13
0.33
0.35
11/19/98
Z-39 17-22

ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
ppm
ppm
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
    BUILDING
   PARTNERSHIPS
FOR cormNUOus IMPROVEMENT
                 This report shall not be reproduced, except in full, without the written approval of the laboratory.
U.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive  • Knoxville, TN 37921-1750
Tel: (423) 546-1335  •  Fax:(423)546-7209


        APPENDIX C
                                                Page 5 of 13

-------
                         GALBRAITH® LABORATORIES,  INC.
                                     Accuracy with speed  since 1950
                                  LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS


Report Date:
Lab I.D.:
As
11/19/98
Z-39 17-22
Dry

Received
2002A Z-39 19-20 Selenium
<0.
4
<0.4
Silver

Sodium
<0
<0
05
05
ppm
ppm
ppm
ppm
0.0092 %
0.0096 %
Vanadium

Zinc

0.5
0.5
3.4
3.3




ppm
ppm
ppm
ppm
<8
<8
<1
<1
0.20
0.21
11
10
74
71
ppm
ppm
ppm
ppm
%
%
ppm
ppm
ppm
ppm
Method

EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
2003 A
Z-3921
2004A
Z-3922
Moisture
Moisture
95.53
93.81
ASTMD-5142
Chlorine
Fluorine
Bromine
Iodine
<85
<96
<8
<85
<96
<|
ppm
ppm
Ppm
ppm
Ppm
ppm
Ppm
ppm
<2000
<2100
<180
<220
<1900
<2100
<20
<20
Ppm
ppm
Ppm
ppm
Ppm
ppm
ppm
ppm
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTMD-3869
ASTMD-5142
Chlorine
Fluorine
Bromine
Iodine
127
155
<9
<8
<100
<93

-------
           GALBRAITH® LABORATORIES,  INC.
                       Accuracy with speed - since 1950
                    LABORATORY  REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
3001A Z-5356-57 Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
Report Date:
Lab I.D.:
As
Received
0.066
0.051
<5
<5
<5
<5
<3
<2
<3
<2
8
8
<3
<2
0.061
0.061
<5
<5
78
76
7
8
<0.025
<0.026
<0.025
<0.024
<0.025
O.025
<3
<2
60
59

%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Dry
0.13
0.10
<10
<10
<10
<10
<5
<5
<5
<5
16
16
<5
<5
0.12
0.12
<10
<10
153
150
14
15
O.050
<0.051
<0.049
<0.048
<0.050
0.050
<5
<5
118
117
1 1/20/98
Z-5356-67

%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
     19%
    BUILDING
   PARTNERSHIPS
FOR CONTINUOUS IMPROVEMENT
                This report shall not be reproduced, except in full, without the written approval of the laboratory.
U.S. Mail: P.O. Box 51610  • Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
Tel: (423) 546-1335  •  Fax: (423) 546-7209
                                                 Page 2 of 19
                           APPENDIX C

-------
            GALBRAITH® LABORATORIES,  INC.
                       Accuracy with speed - since 1950
                     LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ED LAB ED ANALYSIS
6001A Z-3923 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Ri/^'.'.T iVz./fj- /0,,?,,(
Bromine
Iodine
Oxygen (by diff)
HHV
Mercury

As
Received
13.51
13.75
38.32
38.29
7.17
7.17
3.07
3.03
0.43
0.42
7.17
7.18
1820
1860
<15
<15
<160
<160
3
3
31.53
31.61
7103
6925
O.043
O.042
<0.043
O.043
<0.043
<0.043
Report Date:
Labl.D.:

%
%
%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm

Dry

44.37
44.33
6.55
6.55
3.56
3.51
0.50
0.49
8.30
8.31
2110
2160
<17
<17
<180
<180
4
4
36.51
36.59
8225
8018
O.050
O.049
<0.050
<0.050
<0.050
<0.050
11/19/98
Z-3923-28


%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm

Method
ASTMD-5142
ASTMD-5373
ASTMD-5373
ASTMD-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTMD-3869
ASTM D-3 176
ASTM D- 1989
EPA SW-846
7471
                 TTiij report shall not be reproduced, except in full, without the written approval of the laboratory.
                                               Page 7 of 13
*^^^^*p"'  Rimnih:*--
L/.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
Tel: (423) 546-1335  • Fax: (423) 546-7209


        APPENDIX C

-------
           GALBRAITH® LABORATORIES,  INC.
                       Accuracy with speed  since 1950
                    LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
6002 A Z-3924 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine s'3^13"1
Bromine
Iodine
Oxygen (by diff)
HHV
Mercury

As
Received
13.66
13.97
37.38
38.27
6.85
7.16
3.22
3.05
0.41
0.41
7.10
7.14
1710
1680
95
89
<160
<170
<2
<2
32.58
31.51
6919
6721
0.043
0.042
O.042
O.041
0.041
O.041
Report Date:
Lab I.D.:

%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
Btu/lb
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm

Dry

43.37
44.41
6.17
6.53
3.74
3.54
0.48
0.48
8.24
8.28
1980
1940
110
103
<190
<190
<2
<2
37.80
36.57
8028
7798
0.050
O.049
O.049
O.048
0.047
O.048
11/19/98
Z-3923-28


/Q
/Q
/O
%
%
/Q
ppm
ppm
ppm
ppm
ppm
ppm
ppm
PPm
%
Btu/lb
Btu/lb
ppm
ppm
PPm
PPm
PPm
ppm

Method
ASTMD-5142
ASTM D-5373
ASTM D-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTMD-3869
ASTM D-3 176
ASTM D- 1989
EPA SW-846
7471
                 This report shall not be reproduced, except in full, without the written approval of the laboratory.
                                               Page 8 of 13
    BALDING
   PARTNERSHIPS
FOB COVTTrfUOt/S (MPROVEMEVT
U.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
Tel: (423) 546-1335  - Fax: (423) 546-7209
                          APPENDIX C

-------
GALBRAITH® LABORATORIES,  INC.
            Accuracy with speed - since 1950
         LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
6005A Z-3925 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
Mercury

As
Received
46.95
47.86
32.69
32.39
10.23
10.16
1.21
1.14
0.12
0.12
0.65
0.66
110
77
<9
<9
<100
<100
<1
<1
12.95
13.38
6692
6518
<0.026
<0.026
<0.026
0.031
<0.026
<0.026
Report Date:
Lab I.D.:

%
%
%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm
11/19/98
Z-3923-28
Dry

62.15
61.58
9.44
9.31
2.30
2.17
0.23
0.23
1.24
1.26
200
150
<16
<17
<190
<200
<2
<2
24.62
25.44
12723
12393
O.050
O.049
<0.050
0.058
<0.050
<0.049


%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm
II Method
'1
ASTMD-5142
ASTMD-5373
ASTMD-5373
ASTMD-5373
ASTMD4239
ASTMD-5142
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTMD-3869
ASTMD-3176
ASTMD-1989
EPA SW-846
7471
    BUILDING
   PARTNERSHIP
FOR CONTINUOUS IMPROVEMENT
     This report shall not be reproduced, except in full, without the written approval of the laboratory.
        L/.S. Mail: P.O. Box 51610    Knoxville, TN 37950-1610

        Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
        Tel: (423) 546-1335 •  Fax: (423) 546-7209
                                                                    Page 9 of 13
               APPENDIX C
                                                      1O

-------
           GALBRAITH® LABORATORIES, INC.
                      Accuracy with speed  since 1950
                    LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
6006A Z-3926 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
Mercury

As
Received
47.56
47.21
31.93
32.06
10.12
10.22
1.13
1.04
0.12
0.13
0.61
0.64
69
77
42
39
<100
<98
3
4
13.97
13.80
6615
6533
O.025
O.025
O.025
<0.024
<0.025
O.026
Report Date:
Lab I.D.:

%
%
%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm
11/19/98
Z-3923-28
Dry

60.69
60.93
9.22
9.41
2.14
1.97
0.23
0.24
1.16
1.21
131
147
79
74
<200
<190
5
7
26.55
26.23
12573
12416
<0.048
O.047
<0.047
O.046
<0.047
<0.049


%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm
I! Method
ASTMD-5142
ASTM D-5373
ASTM D-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTM D-3869
ASTM D-3 176
ASTM D- 1989
EPA SW-846
7471
    BUILDING
   PARTNERSHIPS
FOR COr^TlNUOUS IMPROVEMEI'n'
                This report shall not be reproduced, except in full, without the written approval of the laboratory.         Page 10 of 13
U.S. Mail: P.O. Box 51610 •  Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
Tel: (423) 546-1335  •  Fax: (423) 546-7209
                           APPENDIX C
                                                                 11

-------
           GALBRAITH® LABORATORIES, INC.
                       Accuracy with speed - since 1950
                    LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ED ANALYSIS
6009A Z-3927 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
i
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diflf)
HHV
Mercury

As
Received
13.62
14.12
40.00
40.16
7.15
7.20
0.56
0.47
0.07
0.07
1.06
1.07
1440
1410
23
17
<160
<160
3
5
38.69
38.56
6943
6813
O.042
<0.042
O.042
O.042
O.041
<0.042
Report Date:
Lab I.D.:

%
%
%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm

Dry

46.44
46.63
6.51
6.57
0.65
0.54
0.08
0.09
1.23
1.24
1670
1640
27
20
<190
<190
4
6
44.93
44.77
8061
7910
O.049
O.049
O.049
O.049
<0.048
O.049
11/19/98
Z-3923-28


%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm

Method
ASTMD-5142
ASTMD-5373
ASTMD-5373
ASTMD-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTMD-3869
ASTM D-3 176
ASTM D- 1989
EPA SW-846
7471
    BUILDING
   PARTNER-SHIPS
FOR COSTISLOL'S IMfHOV
                  TWs report shall not be reproduced, except in full, wilhout the written approval of the laboratory.      Page 11 of 13
U.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
Tel: (423) 546-1335  •  Fax: (423) 546-7209
                          APPENDIX C

-------
GALBRAITH® LABORATORIES,  INC.
            Accuracy with speed  since 1950
         LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ED ANALYSIS
601 OA Z-3928 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
Mercury

As
Received
13.19
13.62
40.12
40.22
7.27
7.15
0.64
0.49
0.058
0.059
1.17
1.20
1160
1390
<14
<15
<160
<180
3
3
38.72
38.82
6825
6785
0.043
<0.042
O.043
<0.044
0.043
0.043
Report Date:
Lab I.D.:

%
%
%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm

Dry

46.33
46.45
6.67
6.54
0.74
0.57
0.067
0.068
1.35
1.38
1340
1610
<16
<17
<180
<200
3
3
44.71
44.83
7882
7835
O.050
O.049
O.050
0.051
0.050
0.050
11/19/98
Z-3923-28


%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm

Method
ASTMD-5142
ASTMD-5373
ASTMD-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTM D-3869
ASTM D-3 176
ASTM D- 1989
EPA SW-846
7471
    BUILDING
   PARTNERSHIPS
FOR CONTINUOUS IMPROVEMENT
     This report shall not be reproduced, except in full, without the written approval of the laboratory.         Page 12 of 13
        U.S. Mail: P.O. Box 51610 •  Knoxville, TN 37950-1610
        Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
        Tel: (423) 546-1335  •  Fax:(423)546-7209


                APPENDIX  C                           13

-------
                            GALBRAITH®  LABORATORIES,  INC.
                                         Accuracy with speed   since 1950
                                      LABORATORY REPORT
David Alburty                                            Report Date:               11/19/98
Midwest Research Institute                                   Lab I.D.:                  Z-3923-28
                                             General Note


The original Chain of Custody is included with the mailed report.



                                       Preparation Confirmation


As requested, Lab ID#s Z-3917-28 were refrigerated prior to analysis. The samples were also dried and ground, unless otherwise
noted, prior to analysis to provide a more homogeneous sample for testing.


                                            Technical Note

(a)There was insufficient sample to perform the Heat of Combustion analysis in duplicate.

(b> Lab ID#'s Z-3921 and Z-3922 were analyzed on an as received basis.
PAC :yd                            ™» report shall not be reproduced, except in full, without the written approval of the laboratory.           Page 13 of 13
              «»/
              \1 Q>rtw«iwletMvi*blr        U.S. Mail: P.O. Box 51610    Knoxviile, TN 37950-1610
                                     Other Carriers: 2323 Sycamore Drive  •  Knoxviile, TN 37921-1750
                                     Tel: (423) 546-1335  •  Fax: (423) 546-7209


                                              APPENDIX  C                               14

-------
GALBRAITH® LABORATORIES,  INC.
            Accuracy with speed  since 1950
         LABORATORY  REPORT
David Alburty
Midwest Research Institute
425 Volker Blvd.
Kansas City MO 64110
SAMPLE ID LAB ID ANALYSIS
3001A Z-5356-57 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by difl)
HHV
Report Date:
Sample Received:
Purchase Order #:
Fax#:
As
Received
48.61 %
50.04 %
23.73 %
23.49 %
8.35 %
8.37 %
0.26 %
0.26 %
0.01 %
0.01 %
5.64 %
6.37 %
<51 ppm
<51 ppm
8 ppm
9 ppm
<51 ppm
<51 ppm
<1 ppm
<1 ppm
18.17 %
17.64 %
4187 Btu/lb
4164 Btu/lb
Dry

46.82
46.36
5.67
5.70
0.51
0.51
0.02
0.02
11.12
12.58
<100
<100
16
18
<100
<100
<2
<2
35.85
34.82
8263
8216
1 1/20/98
10/02/98
A035822
816-531-0315
1 Method
ASTMD-5142
% ASTM D-5373
% ASTM D-5373
% ASTM D-5373
% ASTM D-4239
% ASTMD-5142
ppm EPA SW-846
ppm 5050/9056
ppm ASTMD-3761
ppm
ppm EPA SW-846
ppm 5050/9056
ppm ASTM D-3 869
ppm
% ASTM D-3 176
Btu/lb ASTM D- 1989
Btu/lb
    BUILDING
   PARTNERSHIPS
FOR cownNuous IMPROVEMENT
      This report shall not be reproduced, except in full, without the written approval of the laboratory.
        U.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610

        Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750

        Tel: (423)546-1335  •  Fax:(423)546-7209
                                                                  Page 1 of 19
                APPENDIX  C
                                                       15

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           GALBRAITH® LABORATORIES,  INC.
                       Accuracy with speed  since 1950
                    LABORATORY REPORT
David. Alburty
Midwest Research Institute
SAMPLE ID LAB ID

3001A Z-5356-57











ANALYSIS

Selenium

Silver

Sodium

Vanadium

Zinc



As
Received
<5
<5
<0.5
<0.5
123
121
<3
<2
4
4
Report Date:
Lab I.D.:


ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm


Dry

<10
<10
<1
<1
243
240
<5
<5
8
8
1 1/20/98
Z-5356-67
1
1
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm


Method

EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
                TWs report shall not be reproduced, except in full, without the written approval of the laboratory.
                                             Page 3 of 19
    BUILDING
   PARTNERSHIPS
FOR CONTINUOUS IMPROVEMENT
U.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610

Other Carriers: 2323 Sycamore Drive   Knoxville. TN 37921-1750
Tel: (423) 546-1335  •  Fax: (423) 546-7209



        APPENDIX  C

-------
           GALBRAITH® LABORATORIES,  INC.
                       Accuracy with speed  since 1950
                    LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ED ANALYSIS
3002A Z-5358-59 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by difi)
HHV

As
Received
53.97
59.80
19.57
19.00
8.71
8.84
0.22
0.22
0.0060
0.0065
4.99
4.54
<44
<44
42
40
<44
<44
2
1
15.94
16.83
3725
3562
Report Date:
Lab I.D.:

%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
I
Btu/lb
Btu/lb

Dry

45.38
44.07
5.54
5.85
0.51
0.51
0.014
0.015
11.58
10.52
<100
<100
97
94
<100
<100
4
2
36.98
39.04
8639
8262
11/20/98
Z-5356-67
I! Method
ASTMD-5142
% ASTM D-5373
% ASTM D-5373
% ASTM D-5373
% ASTMD-4239
% ASTMD-5142
ppm EPA SW-846
ppm 5050/9056
ppm ASTM D-3761
ppm
ppm EPA SW-846
ppm 5050/9056
ppm ASTM D-3869
ppm
% ASTM D-3 176
Btu/lb ASTM D- 1989
Btu/lb
                 This report shall not be reproduced, except in full, without the written approval of the laboratory.
                                               Page 4 of 19
    BUILDING
   PARTNERSHIPS
FOR CONTINUOUS IMPROVEMENT
U.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610

Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
Tel: (423) 546-1335  •  Fax: (423) 546-7209
                          APPENDIX C
                                                                 17

-------
           GALBRAITH®  LABORATORIES, INC.
                       Accuracy with speed  since 1950
                    LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
3002A Z-5358-59 Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
Report Date:
Lab I.D.:
As
Received
0.056
0.056
<4
<4
<4
<4
<2
<2
<2
<2
9
9
<2
<2
0.060
0.056
<4
<4
72
69
7
7
O.0022
O.0021
<0.0022
<0.0021
<0.0022
<0.0021
3
3
54
55

%
%
ppm
ppm
ppm
ppm
ppm
Ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
ppm
PPm
ppm
ppm
PPm
ppm
PPm
PPm
PPm
PPm
PPm
PPm
ppm
ppm
ppm
PPm
Dry
0.13
0.13
<10
<10
<10
<10
<5
<5
<5
<5
21
21
<5
<5
0.14
0.13
<10
<10
167
160
17
16
O.050
O.049
<0.050
<0.049
<0.050
<0.048
6
6
126
128
1 1/20/98
Z-5356-67

%
%
PPm
PPm
ppm
PPm
ppm
ppm
ppm
ppm
PPm
PPm
ppm
ppm
%
%
PPm
PPm
ppm
ppm
ppm
ppm
PPm
PPm
PPm
PPm
PPm
PPm
ppm
PPm
ppm
ppm
Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
    BUILDING
   PARTNERSHIPS
FOR CONTINUOUS IMPROVEMENT
                Thi» report shall not be reproduced, except in full, without the written approval of the laboratory.
L/.S, Mail: P.O. Box 51610 •  Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
Tel: (423) 546-1335  • Fax: (423) 546-7209
                                               Page 5 of 19
                          APPENDIX  C
                                                                -I*

-------
                          GALBRAITH® LABORATORIES, INC.
                                      Accuracy with speed  since  1950
                                   LABORATORY REPORT
David Alburty                                          Report Date:              11/20/98
Midwest Research Institute                                 Lab I.D.:                 Z-5356-67
SAMPLED)
LAB ID
ANALYSIS
As
Received
Dry
Method
3002A         Z-5358-59     Selenium         <4         ppm         <10       ppm     EPA SW-846
  	<4	ppm	<10	ppm     3050B/6010
                         Silver            <0.5        ppm         <1        ppm     EPA SW-846
                         	<0.5	ppm	<1	ppm     3050B/6010
                         Sodium          120        ppm         280       ppm     EPA SW-846
                         	100	ppm	240	ppm     3050B/6010
                         Vanadium         <2         ppm         <5        ppm     EPA SW-846
                         	<2	ppm	<5	ppm     3050B/6010
                         Zinc             4          ppm         9         ppm     EPA SW-846
                         	4	ppm	8	ppm	3050B/6010
                               This report shall not be reproduced, excapt in full, without the written approval of the laboratory.         Page 6 Of 19


                                  U.S. Mail: P.O. Box 51610 •  Knoxville, TN 37950-1610
                                  Other Carriers: 2323 Sycamore Drive  •  Knoxville, TN 37921-1750
                                  Tel: (423) 546-1335 •  Fax: (423) 546-7209


                                          APPENDIX  C                            no

-------
                         GALBRAITH® LABORATORIES, INC.
                                     Accuracy with speed - since 1950
                                  LABORATORY REPORT
David Alburty
Midwest Research Institute
Report Date:
Lab I.D.:
11/20/98
Z-5356-67
SAMPLE ID LAB ID ANALYSIS
3003A Z-5360-61 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diflf)
HHV
As
Received
5.9 %
5.12 %
83.37 %
10.66 %
<0.47 %
0.076 %
0.23 %
<95 ppm
<10 ppm
<95 ppm
3 ppm
0.29 %
13751 Btu/lb
Dry

88.23
10.63
O.50
0.080
0.24
<100
<11
<100
3
0.31
14553
I! Method
ASTMD-5142
% ASTMD-5373
% ASTM D-5373
% ASTM D-5373
% ASTM D-4239
% ASTMD-5142
ppm EPA SW-846
5050/9056
ppm ASTM D-3761
ppm EPA SW-846
5050/9056
ppm ASTM D-3869
% ASTM D-3 176
Btu/lb ASTMD-1989
                               Thu report shall not be reproduced, except in full, without the written approval of the laboratory.          Page 7 of 19
                                 L/.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610
                                 Other Carriers: 2323 Sycamore Drive    Knoxville, TN 37921-1750
                                 Tel: (423) 546-1335  •  Fax: (423) 546-7209

                                         APPENDIX C                           2O

-------
GALBRAITH® LABORATORIES, INC.
            Accuracy with speed - since 1950
         LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ED LAB BO ANALYSIS
3003 A Z-53 60-61 Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury

As
Received
26
<9
<9
<4
<4
<4
<4
24
<9
10
<4
O.47
<0.47
<0.47
Report Date
Lab I.D.:

ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm

Dry
27.84
<9
<9
<5
<5
<5
<5
26
<9
10.11
<5
<0.49
<0.50
<0.49
1 1/20/98
Z-5356-67

ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm

Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B-6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
    BUILDING
   PARTNERSHIPS
FOR COf^TlNL'OUS IMPROVEMENT
      This report shall not be reproduced, except in full, without the wttten approval of the laboratory.
        U.S. Mail: P.O. Box 51610 •  Knoxville, TN 37950-1610
        Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
        Tel: (423) 546-1335  •  Fax: (423) 546-7209
                                                                  Page 8 of 19
                APPENDIX  C
                                                      21

-------
GALBRA1TH® LABORATORIES,  INC.
            Accuracy with speed - since 1950
         LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ED ANALYSIS
3003A Z-5360-61 Nickel
Potassium
Selenium
Silver
Sodium
Vanadium
Zinc
Report Date
Lab I.D.:
As
Received
<4 ppm
14 ppm
<9 ppm
<1 ppm
140 ppm
<4 ppm
7 ppm

Dry
<5
14
<9
<1
140
<5
8
1 1/20/98
Z-5356-67

ppm
ppm
ppm
ppm
ppm
ppm
ppm

Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
    BUILDING
   PARTNERSHIPS
FOR CONTINUOUS IMPROVEMENT
     This report shall not be ruproduced. except in full, without the written approval of the laboratory.
        U.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610

        Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
        Tel: (423) 546-1335  •  Fax: (423) 546-7209



                APPENDIX  C
                                                                    Page 9 of 19
                                                       22

-------
                         GALBRAITH® LABORATORIES, INC.
                                      Accuracy with speed  since 1950
                                   LABORATORY REPORT
David Alburty

Midwest Research Institute
                                     Report Date:

                                     Lab I.D.:
11/20/98

Z-5356-67
SAMPLE ID LAB ID ANALYSIS
3003C Z-5362-63 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
As
Received
0.89 %
0.84 %
79.79 %
10.23 %
<0.50 %
0.10 %
0.29 %
140 ppm
<10 ppm
<99 ppm
5 ppm
8.31 %
16020 Btu/lb
Dry

80.49
10.22
<0.50
0.10
0.29
140
<10
<100
5
8.39
16160
|| Method
II
ASTMD-5142
% ASTM D-5373
% ASTM D-5373
% ASTM D-5373
% ASTM D-4239
% ASTMD-5142
ppm EPA SW-846
5050/9056
ppm ASTMD-3761
ppm EPA SW-846
5050/9056
ppm ASTM D-3 869
% ASTM D-3 176
Btu/lb ASTM D- 1989
     19%
    BUILDING
   PARTNERSHIPS
FOR CONTINUOUS IMPROVEMENT
                                     This report shall not be reproduced, except in full, without the written approval of the laboratory.
                                  U.S. Mail: P.O. Box 51610 •  Knoxville, TN 37950-1610

                                  Other Carriers: 2323 Sycamore Drive    Knoxville, TN 37921-1750
                                  Tel: (423) 546-1335 •  Fax: (423) 546-7209
                                                                       Page 10 of 19
                                          APPENDIX  C
                                                                                   23

-------
           GALBRAITH® LABORATORIES,  INC.
                       Accuracy with speed - since 1950
                    LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
3003C Z-53 62-63 Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury

As
Received
63
<10
<10
<5
<5
<5
<5
65
<10
35
<5
0.48
<0.46
<0.49
Report Date.
Lab I.D.:

ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm

Dry
64
<10
<10
<5
<5
<5
<5
66
<10
35
<5
<0.49
<0.47
<0.50
11/20/98
Z-5356-67

ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm

Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B-6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
                This report shall not be reproduced, except in full, without the written approval of the laboratory.
                                                Page 11 of 19
    BUILDING
   PARTNERSHIPS
FOR CONTINUOUS IMPROVEMENT
aS. Mail: P.O. Box 51610   Knoxville, TN 37950-1610

Other Carriers: 2323 Sycamore Drive  • Knoxville, TN 37921-1750
Tel: (423) 546-1335  •  Fax: (423) 546-7209



        APPENDIX C                           24

-------
           GALBRAITH® LABORATORIES,  INC.
                       Accuracy with speed - since 1950
                    LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ED LAB ID ANALYSIS
3003C Z-5362-63 Nickel
Potassium
Selenium
Silver
Sodium
Vanadium
Zinc
Report Date
Lab I.D.:
As
Received
<5 ppm
8 ppm
<10 ppm
<1 ppm
180 ppm
<5 ppm
30 ppm
11/20/98
Z-5356-67
Dry
<5 ppm
8 ppm
<10 ppm
<1 ppm
180 ppm
<5 ppm
31 ppm

Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
      ee
   PARTNERSHIPS
FOR CONTINUOUS IMPROVEMENT
                This report shall not be reproduced, except in full, without the written approval of the laboratory.
U. S. Mail: P. O. Box 51610   Knoxville, TN 3 7950-1610

Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
Tel: (423) 546-1335  •  Fax: (423) 546-7209
                                                Page 12 of 19
                           APPENDIX  C
                                                                 25

-------
                          GALBRAITH® LABORATORIES, INC.
                                      Accuracy with speed - since 1950
                                       LABORATORY REPORT
David Alburty
Midwest Research Institute
                                     Report Date:
                                     Lab I.D.:
11/20/98
Z-5356-67
SAMPLE ID LAB ID ANALYSIS
3 004 A Z-53 64-65 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
As
Received
11.05 %
10.98 %
77.51 %
10.64 %
<0.44 %
0.0042 %
0.27 %
<89 ppm
29 ppm
<89 ppm
<2 ppm
1.34 %
5100 Btu/lb
Dry

87.10
10.58
<0.50
0.0047
0.30
<100
32
<100
<2
1.51
5732
Method
ASTM D-5142
% ASTMD-5373
% ASTM D-5373
% ASTM D-5373
% ASTM D-4239
% ASTM D-5142
ppm EPA SW-846
5050/9056
ppm ASTM D-3761
ppm EPA SW-846
5050/9056
ppm ASTM D-3869
% ASTM D-3 176
Btu/lb ASTM D- 1989
    BUILDING
   PARTNERSHIPS
FOR CONTINUOUS iMraovEMErvr
                                This report shall not be reproduced, except in full, without the written approval of the laboratory.
                                  U.S. Mail: P.O. Box 51610  • Knoxville, TN 37950-1610
                                  Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
                                  Tel: (423) 546-1335  •  Fax: (423) 546-7209
                                                                      Page 13 of 19
                                          APPENDIX  C
                                                                                   26

-------
           GALBRAITH® LABORATORIES,  INC.
                       Accuracy with speed  since 1950
                    LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ED LAB ID ANALYSIS
3004A Z-5364-65 Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury

As
Received
33
<8
<8
<4
<4
<4
<4
47
<8
14
<4
<0.44
<0.44
<0.44
Report Date:
Lab I.D.:

ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
11/20/98
Z-5356-67
Dry
37
<10
<10
<5
<5
<5
<5
53
<10
15
<5
<0.50
<0.50
<0.50

ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
[Method 1
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B-6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-8"46
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
      ee
    BUILDING
   PARTNERSHIPS
FOR CONTINUOUS IMPROVEMENT
                This report shall not be reproduced, except in full, without the written approval of the laboratory.          Page 14 of 19
U.S. Mail: P.O. Box 51610  • Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
Tel: (423) 546-1335  •  Fax: (423) 546-7209

        APPENDIX  C                           27

-------
   GALBRAITH® LABORATORIES,  INC.
               Accuracy with speed - since 1950
            LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID
3004A Z-5364-65


ANALYSIS
Nickel
Potassium
Selenium
Silver
Sodium
Vanadium
Zinc
Report Date:
Lab I.D.:
As Dry
Received
<4 ppm <5
1 5 ppm 1 7
<8 ppm <10
<1 ppm 1
130 ppm 150
<4 ppm <5
<4 ppm <5
1 1/20/98
Z-5356-67

ppm
ppm
ppm
ppm
ppm
ppm
ppm

Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 15 of 19
           U.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610
           Other Carriers: 2323 Sycamore Drive    Knoxville, TN 37921-1750
           Tel: (423) 546-1335  • Fax: (423) 546-7209


                   APPENDIX C                          28

-------
                         GALBRAITH® LABORATORIES,  INC.
                                     Accuracy with speed - since 1950
                                   LABORATORY REPORT
David Alburty
Midwest Research Institute
                 Report Date:
                 Lab I.D.:
11/20/98
Z-5356-67
SAMPLE ID LAB ID ANALYSIS
3004C Z-5366-67 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
As
Received
2.39 %
2.51 %
77.69 %
10.18 %
<0.49 %
0.011 %
0.34 %
<98 ppm
<9 ppm
<98 ppm
<2 ppm
9.10 %
13328 Btu/lb
Dry

79.64 %
10.16 %
<0.50 %
0.011 %
0.35 %
<100 ppm
<9 ppm
<100 ppm
<2 ppm
9.33 %
13663 Btu/lb
Method
ASTM D-5142
ASTM D-5373
ASTM D-5373
ASTM D-5373
ASTM D-4239
ASTM D-5142
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTM D-3869
ASTM D-3 176
ASTM D- 1989
                               This report shall not be reproduced, except in full, without the written approval of the laboratory.
                   ee

                  BUILDING
                 PARTNERSHIPS
             FOB CONTINUOUS IMPROVEMENT
                                                 Page 16 of 19
  3. Mail: P.O. Box 51610   Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive  •  Knoxville, TN 37921-1750
Tel: (423) 546-1335  •  Fax: (423) 546-7209

        APPENDIX  C                            29

-------
GALBRAITH® LABORATORIES, INC.
           Accuracy with speed  since 1950
         LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ED LAB ED ANALYSIS
3004C Z-5366-67 Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury

As
Received
72
<10
<10
<5
<5
<5
<5
120
<10
37
<5
<0.48
<0.49
<0.47
Report Date
Lab I.D.:

ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
1 1/20/98
Z-5356-67
Dry
74
<10
<10
<5
<5
<5
<5
120
<10
37
<5
<0.49
<0.50
<0.48

ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
1 Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B-6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
     TWs report shall not be reproduced, except in hill, without the written approval of the laboratory.         Page 17 of 19



       U.S. Mail: P.O. Box 51610  • Knoxville, TN 37950-1610
       Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
       Tel:  (423) 546-1335 •  Fax: (423) 546-7209


               APPENDIX C                          30

-------
           GALBRAITH® LABORATORIES, INC.
                       Accuracy with speed  since 1950
                    LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
3004C Z-5366-67 Nickel
Potassium
Selenium
Silver
Sodium
Vanadium
Zinc
Report Date
Labl.D.:
As
Received
<5 ppm
11 ppm
<10 ppm
<1 ppm
190 ppm
<5 ppm
23 ppm
1 1/20/98
Z-53 56-67
Dry
<5 ppm
11 ppm
<10 ppm
<1 ppm
200 ppm
<5 ppm
23 ppm

Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
                 This report shall not be reproduced, except in full, without the written approval of the laboratory.
                                              Page 18 of 19
   PARTNERSH1FS
FOR CONTINUOUS IMPROVEMENT
U.S. Mail: P.O. Box51610   Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
Tel: (423) 546-1335  •  Fax: (423) 546-7209
                           APPENDIX C
                                                                 31

-------
                            GALBRAITH® LABORATORIES,  INC.
                                         Accuracy with speed  since 1950
                                      LABORATORY REPORT



 David Alburty                                            Report Date:               11/20/98
 Midwest Research Institute                                   Lab I.D.:                  Z-5356-67



                                             General Note


 The original Chain of Custody is included with the mailed report.



                                       Preparation Confirmation


 As requested, Lab ID#s Z5356-67were refrigerated prior to analysis. The samples were also dried and ground, unless otherwise noted,
 prior to analysis to provide a more homogeneous sample for testing.
PAC:yd                  This report shall not be reproduced, except in full, without the written approval of the laboratory.         Page 19 of 19
                                     U.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610
                                     Other Carriers: 2323 Sycamore Drive •  Knoxville, TN 37921-1750
                                     Tel: (423) 546-1335  •  Fax:(423)546-7209


                                              APPENDIX  C
                                                                                         32

-------
           GALBRAITH® LABORATORIES,  INC.
                       Accuracy with speed  since 1950
                    LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
5002A Z-3476-77(a) Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV

As
Received
97.31
97.31
1.68
1.69
11.09
11.09
0.030
0.031
0.027
0.027
0.52
0.51
5.9
4.6
6.2
6.1
<3
<3
0.22
0.30
0.15
0.15
378
387
Report Date:
Lab I.D.:

I
%
%
%
%
%
PPm
ppm
ppm
ppm
ppm
PPm
ppm
Ppm
%
Btu/lb
Btu/lb
1 1/20/98
Z-3474-79
Dry

62.55 %
62.82 %
10.42 %
10.38 %
1.12 %
1.16 %
1.00 %
1.00 %
19.31 %
18.96 %
220 ppm
170 ppm
230 ppm
230 ppm
<100 ppm
<100 ppm
8 ppm
11 ppm
5.60 %
5.68 %
14059 Btu/lb
14405 Btu/lb

Method
ASTMD-5142
ASTM D-5373
ASTM D-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTM D-3 869
ASTM D-3 176
ASTM D- 1989
    BUILDING
   PARTNERSHIPS
TOR CONTINUOUS (MntOVEMENT
                 Thij report shall not be reproduced, except in full, without the written approval of the laboratory.
U.S. Mail: P.O. Box 51610 •  Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
Tel: (423) 546-1335  •  Fax: (423) 546-7209
                                               Page 4 of 7
                           APPENDIX C
                                                                33

-------
           GALBRAITH® LABORATORIES, INC.
                      Accuracy with speed  since 1950
                    LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
5002A Z-3476-77(a) Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
Report Date:
Lab I.D.:
As
Received
0.040

-------
     GALBRAITH® LABORATORIES, INC.
                 Accuracy with speed  since 1950
              LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID

ANALYSIS As
Received
Report Date:
Lab I.D.:
Dry
11/20/98
Z-3474-79
1 Method
5002A Z-3476-77(a) Selenium
Silver
Sodium
Vanadium
Zinc
5003A Z-3478(b) Chlorine
Fluorine
Bromine
Iodine
5004A Z-34790" Chlorine
Fluorine
Bromine
Iodine
<1
0.12
0.014
<0.5
0.0078
160
160
14
15
<96
<94
100
100
180
160
30
29
<100
<100
30
29
ppm
ppm
%
ppm
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
<41 ppm EPA SW-846
3050B/6010
4.5 ppm EPA SW-846
3050B/6010
0.52 % EPA SW-846
3050B/6010
<20 ppm EPA SW-846
3050B/6010
0.29 % EPA SW-846
3050B/6010
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTM D-3869
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTM D-3869
cei
          This report shall not be reproduced, except in full, without the written approval of the laboratory.        Page 6 of 7
             U.S. Mail: P.O. Box 51610 •  Knoxville, TN 37950-1610
             Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
             Tel: (423) 546-1335  •  Fax: (423) 546-7209


                    APPENDIX  C                          35

-------
                             GALBRAITH® LABORATORIES, INC.
                                          Accuracy with speed - since 1950
                                       LABORATORY REPORT
David Alburty                                             Report Date:               11/20/98
Midwest Research Institute                                   Labl.D.:                  Z-3474-79
                                                  Note

As previously noted, a Chain of Custody form was not included with these samples.



                                        Preparation Confirmation

As requested, Lab ID#s Z-3474-79 were refrigerated prior to analysis. The samples were also dried and ground, unless otherwise
noted, prior to analysis to provide a more homogeneous sample for testing.


                                             Technical Note



-------
           GALBRAITH® LABORATORIES,  INC.
                       Accuracy with speed  since 1950
                    LABORATORY REPORT
David Alburty
Midwest Research Institute
425 Volker Blvd.
Kansas City MO 64110
SAMPLE ID LAB ID ANALYSIS
5001A Z-3474-75(a) Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by difi)
HHV
Report Date: 1 1/20/98
Sample Received: 09/16/98
Purchase Order # : A03 5 822
Fax#: 816-531-0315
As
Received
97.55 %
97.51 %
1.53 %
1.54 %
11.09 %
11.09 %
0.026 %
0.028 %
0.025 %
0.026 %
0.47 %
0.48 %
146 ppm
142 ppm
6.1 ppm
7.2 ppm
<5.3 ppm
<4.1 ppm
0.40 ppm
0.30 ppm
0.15 %
0.13 %
340 Btu/lb
351 Btu/lb
Dry

61.83 %
62.27 %
10.33 %
10.29 %
1.05 %
1.15 %
1.03 %
1.04 %
19.09 %
19.24 %
5930 ppm
5740 ppm
250 ppm
290 ppm
<220 ppm
<170 ppm
16 ppm
12 ppm
6.08 %
5.44 %
13768 Btu/lb
14208 Btu/lb
Method
ASTMD-5142
ASTM D-5373
ASTM D-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTMD-3869
ASTM D-3 176
ASTM D- 1989
           \
   PARTNERSHIPS
FOR CONTINUOUS IMPROVEMENT
                  This report shall not be reproduced, except in full, without the written approval of trie laboratory.
U.S. Mail: P.O. Box 51610 •  Knoxville, TN 37950-1610

Other Carriers: 2323 Sycamore Drive   Knoxville. TN 37921-1750
Tel: (423) 546-1335  •  Fax: (423) 546-7209
                                                Page 1 of 7
                           APPENDIX C
                                                                 37

-------
GALBRAITH® LABORATORIES, INC.
           Accuracy with speed  since 1950
         LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
5001 A Z-3474-7500 Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
Report Date:
Lab I.D.:
As
Received
0.035
<0.5
<0.5
<0.3
<0.3
2.6
6.3
0.044
12
0.021
0.0047
O.0012
O.0013
<0.0012
<0.0013
0.0012
O.0012
11
0.0042

%
ppm
ppm
ppm
ppm
ppm
ppm
%
ppm
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
Dry
1.41
<20
<20
<10
<10
110
260
1.77
470
0.87
0.19
<0.047
<0.051
<0.047
O.051
<0.050
<0.049
440
0.17
11/20/98
Z-3474-79

%
ppm
ppm
ppm
ppm
ppm
ppm
%
ppm
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
I! Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010

     This report shall not be reproduced, except in full, without the written approval of the laboratory.          Page 2 of 7
        U.S. Mail: P.O. Box 51610    Knoxville, TN 37950-1610
        Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
        Tel: (423) 546-1335  • Fax: (423) 546-7209


               APPENDIX C                          38

-------
                          GALBRAITH® LABORATORIES,  INC.
                                       Accuracy with speed - since 1950
                                    LABORATORY REPORT
David Alburty
Midwest Research Institute
                                       Report Date:
                                       Lab I.D.:
                                  11/20/98
                                  Z-3474-79
SAMPLE ID   LAB ID
             ANALYSIS
   As
Received
Dry
Method
5001A
Z-3474-75(a)    Selenium
<0.5
                                         ppm
  <20
                                                                            ppm
 EPA SW-846
 3050B/6010
                          Silver
                          Sodium
                              <0.05
                                                      ppm
                        <2
                              0.017
                        0.67
                          Vanadium
                              <0.3
                                                      ppm
                                                               ppm
                                                               ppm
                    EPA SW-846
                    3050B/6010
                    EPA SW-846
                    3050B/6010
                                           EPA SW-846
                                           3050B/6010
                          Zinc
                              0.0059
                        0.24
                    EPA SW-846
                    3050B/6010
                               This report shall not be reproduced, except in full, without the written approval of the laboratory.
                                                                       Page 3 of 7
                    ee
                  BUILDING
                 PARTNERSHIPS
              FOR CONTINUOUS IMPROVEMENT
                      U.S. Mail: P.O. Box 51610    Knoxville, TN 37950-1610
                      Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921 -1750
                      Tel: (423)546-1335  •  Fax:(423)546-7209
                                           APPENDIX  C
                                                                                      39

-------
GALBRAITH® LABORATORIES,  INC.
            Accuracy with speed  since 1950
         LABORATORY REPORT
David Alburty
Midwest Research Institute
425 Volker Blvd.
Kansas City MO 64110
SAMPLE ED LAB ID ANALYSIS
7001 A Z-3276 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
Mercury
Report Date:
Sample Received:
Purchase Order #:
Fax#:
As
Received
8.62
8.74
36.42
36.37
6.06
5.82
0.56
0.54
0.06
0.05
16.72
16.83
830
850
20
20
<92
<92
2.74
2.74
32.38
32.58
5832
5755
O.045
O.046
<0.045
<0.047
<0.047
<0.046

%
%
%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm
Dry

39.88
39.83
5.58
5.32
0.61
0.59
0.07
0.06
18.31
18.43
910
930
(a) 22
(a) 22
<100
<100
3.00
3.00
35.46
35.68
6386
6302
<0.049
O.050
<0.049
0.051
<0.051
O.050
1 1/20/98
09/15/98
A035822
816-531-0315


%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm
Method
ASTMD-5142
ASTM D-5373
ASTM D-5373
ASTM D-5373
ASTMD-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTM D-3869
ASTM D-3 176
ASTM D- 1989
EPA SW-846
7471
      This report shall not be reproduced, except in full, without the written approval of the laboratory.
                                                                   Page 1 of3
    BUILDING
   PARTNERSHIPS
FOR COSTIMJOUS IMPROVEMENT
        L/.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610
        Other Carriers: 2323 Sycamore Drive    Knoxville, TN 37921-1750
        Tel: (423) 546-1335 •  Fax: (423) 546-7209
                APPENDIX C
                                                       4O

-------
           GALBRAITH® LABORATORIES,  INC.
                      Accuracy with speed - since 1950
                    LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
7002A Z-3277 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
Mercury
Report Date:
Lab I.D.:
As
Received
8.74
8.84
35.35
35.31
5.77
5.93
0.54
0.54
0.06
0.06
16.76
16.84
951
942
16
20
<83
<85
<2
<2
33.61
33.42
6176
6238
O.044
O.046
O.047
O.046
0.045
O.045

%
%
%
%
%
%
ppm
ppm
ppm (a
ppm (a
ppm
ppm
ppm
ppm
%
Btu/lb
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm
Dry

38.76
38.71
5.26
5.43
0.59
0.59
0.07
0.07
18.37
18.46
1040
1030
18
22
<93
<2
<2
36.84
36.64
6771
6839
<0.048
O.050
O.051
O.050
O.049
O.049
11/20/98
Z-3276-77


%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
Btu/lb
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm
Method
ASTMD-5142
ASTM D-5373
ASTM D-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTM D-3 869
ASTM D-3 176
ASTM D- 1989
EPA SW-846
7471
    BU1UXNC
   PARTNERSHIPS
FOR CONTINUOUS IMntOVEMEriTr
                          This report shall not be reproduced, except in full, without the written approval of the laboratory.  Page 2 of 3
U.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive  • Knoxville, TN 37921-1750
Tel: (423) 546-1335  •  Fax: (423) 546-7209
                           APPENDIX C
                                              41

-------
                             GALBRAITH® LABORATORIES, INC.
                                          Accuracy with speed - since 1950
                                       LABORATORY REPORT



David Alburty                                             Report Date:               11/20/98
Midwest Research Institute                                   Lab I.D.:                  Z-3276-77


                                                 Note

The original Chain of Custody is included with the mailed report.


                                        Preparation Confirmation


As requested, Lab ID#s Z-3276 and Z-3277 were refrigerated prior to analysis. The samples were also dried and ground prior to
analysis to provide a more homogeneous sample for testing.



                                             Technical Note


-------
           GALBRAITH® LABORATORIES,  INC.
                       Accuracy with speed - since 1950
                    LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID
9002A Z-4552-53


ANALYSIS
Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV

As
Received
11.86
44.08
6.77
1.11
0.11
2.54
140.00
73.00
<170
9.00
34.84
7601
Report Date:
Lab I.D.:

%
%
%
%
%
%
ppm
ppm
ppm
ppm
%
Btu/lb

Dry

50.01
6.19
1.26
0.12
2.88
160.00
83.00
<200
10.00
39.52
8624
1 1/20/98
Z-4550-53
I! Method
ASTMD-5142
% ASTM D-5373
% ASTM D-5373
% ASTM D-5373
% ASTM D-4239
% ASTMD-5142
ppm EPA SW-846
5050/9056
ppm ASTMD-3761
ppm EPA SW-846
5050/9056
ppm ASTM D-3 869
% ASTM D-3 176
Btu/lb ASTM D- 1989
    BUILDING
   PARTNERSHIPS
FOR CONTINUOUS iMntovtMENT
                 This report shall not be reproduced, except in full, without trie written approval of the laboratory.
U.S. Mail: P.O. Box 51610   Knoxvi/le, TN 37950-1610

Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
Tel: (423) 546-1335  •  Fax:(423)546-7209
                                                Page 4 of 7
                           APPENDIX  C
                                                                 43

-------
GALBRAITH® LABORATORIES,  INC.
            Accuracy with speed  since 1950
         LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ED LAB ID ANALYSIS
9002A Z-4552-53 Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
Report Date:
Lab I.D.:
As
Received
410
<9
<9
<4
<4
<4
<4
320
<9
730
30
O.043
<0.044
O.043
<4
0.67

ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
Dry
470
<10
<10
<5
<5
<5
<5
360
<10
830
34
O.049
<0.050
<0.049
<5
0.76
11/20/98
Z-4550-53

pppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
    BUILDING
   PARTNERSHIPS
FOR CONTINUOUS IMPROVEMENT
      This report shall not be reproduced, except in full, without the written approval of the laboratory.          Page 5 01 7




       U.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610

       Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750

       Tel: (423) 546-1335  • Fax: (423) 546-7209



               APPENDIX  C                           44

-------
          GALBRAITH® LABORATORIES, INC.
                      Accuracy with speed  since 1950
                    LABORATORY REPORT
.David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
9002A Z-4552-53 Selenium
Silver
Sodium
Vanadium
Zinc
Report Date: 1 1/20/98
Lab I.D.: Z-4550-53
As
Received
<9 ppm
<0.9 ppm
90 ppm
<4 ppm
14 ppm
Dry I! Method
<10 ppm EPA SW-846
3050B/6010
<1 ppm EPA SW-846
3050B/6010
100 ppm EPA SW-846
3050B/6010
<5 ppm EPA SW-846
3050B/6010
16 ppm EPA SW-846
3050B/6010
   PARTNERSHIPS
KM CONTINUOUS IMPROVEMENT
               This report shall not be reproduced, except in full, without the vwitten approval of the laboratory.        Page 6 of 7
U.S. Mail: P.O. Box 51610 •  Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
Tel: (423) 546-1335  • Fax: (423) 546-7209
                          APPENDIX C
                                                                45

-------
                            GALBRAITH® LABORATORIES,  INC.
                                         Accuracy with speed - since  1950
                                      LABORATORY  REPORT




David Alburty                                           Report Date:              11/20/98
Midwest Research Institute                                  Lab I.D.:                 Z-4550-53



                                                Note


The original Chain of Custody is included with the mailed report.



                                       Preparation Confirmation


As requested, Lab ID#s Z-4550-53 were refrigerated prior to analysis. The samples were also dried and ground prior to analysis to
provide a more homogeneous sample for testing.
PAC :yd                           TOs report shall not be reproduced, except in full, without the written approval of the laboratory.             Page 7 of 7




                                      3. Mail: P.O. Box 51610   Knoxville, TN 37950-1610
                   ^SSp,            Other Carriers: 2323 Sycamore Drive    Knoxville, TN 37921-1750
                FOKCo^TiNuousiMriravEMEwr         Tel: (423) 546-1335  •  Fax: (423) 546-7209
                                             APPENDIX  C
                                                                                        46

-------
            GALBRAITH® LABORATORIES, INC.
                        Accuracy with speed - since 1950
                     LABORATORY REPORT
David Alburty
Midwest Research Institute
425 Volker Blvd.
Kansas City MO 64110
SAMPLE ID LAB ED ANALYSIS
9001 A Repeat A-2 183-84 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Reanalysis Request:
Previous Lab ID:
Report Date:
Purchase Order #:
Fax Number:
As
Received
11.72 (a)
44.32
6.66
1.11
0.088
2.61
123.00
13
<90
15
34.78
7672
350
<6
<6
<4
<4
<4
<4
310
<6

%
%
%
%
%
%
ppm
ppm
ppm
ppm
%
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Dry

50.20
6.07
1.26
0.10
2.96
139.00
14
<100
17
39.40
8691
400
<7
<7
<4
<4
<4
<4
350
<7
1 1/30/98
Z-4550-53
12/18/98
A035822
816-531-0315


%
%
%
%
%
ppm
ppm
ppm
ppm
%
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
1 Method
ASTMD-5142
ASTM D-5373
ASTM D-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTM D-3 869
ASTM D-3 176
ASTM D- 1989
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
This report shall not be reproduced, except in full, without the written approval of ths laboratory.
                                                                    Page 1 Of 5
     19%
    BUILDING
   PARTNERSHIPS
KIR COvmUOUS IMPROVEMENT
  U.S. Mail: P.O. Box 51610    Knoxville, TN 37950-1610
  Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
  Tel: (423) 546-1335 •  Fax: (423) 546-7209
                            APPENDIX C
                                                                    47

-------
GALBRAITH® LABORATORIES, INC.
           Accuracy with speed  since 1950
        LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
9002A Repeat A-2 185-86 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Reanalysis Request:
Previous Lab ID:
As
Received
11.86 (a)
44.29
6.68
1.09
0.078
2.64
96
16
<90
6
34.67
7623
400
<7
<7
<4
<4
<4
<4
330
<7

%
%
%
%
%
%
ppm
ppm
ppm
ppm
%
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Dry

50.25
6.08
1.24
0.089
2.99
110
18
<100
7
39.34
8649
450
<8
<8
<5
<5
<5
<5
380
<8
11/30/98
A-2183-A-2186


%
%
%
%
%
ppm
ppm
ppm
ppm
%
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
It Method
ASTMD-5142
ASTM D-5373
ASTMD-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTM D-3869
ASTM D-3 176
ASTMD-1989
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010

      This report shall not be reproduced, except in full, without the written approval of the laboratory.



       L/.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610
       Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
       Tel: (423) 546-1335  .  Fax: (423) 546-7209


              APPENDIX  C
Page 3 of5
                                                   48

-------
           GALBRAITH® LABORATORIES, INC.
                       Accuracy with speed since 1950
                    LABORATORY REPORT
David Alburty
Midwest Research Institute
425 Volker Blvd.
Kansas City MO 64110
SAMPLE ED LAB ED ANALYSIS
8001A Z-5069 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine , 3 ,„„
-, ' j f 1
i\*.p^t iz/i^/fS'
Bromine
Iodine
Oxygen (by diff)
HHV
Mercury
Report Date:
Sample Received:
Purchase Order #:
Fax#:
As
Received
11.14
11.43
46.02
45.89
6.83
6.75
<0.44
O.44
0.049
0.037
1.29
1.32
<89
<89
22
24
<89
<89
3
4
35.33
35.52
7778
8288
O.043
0.043
<0.044
<0.042
<0.043
<0.043

%
%
%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm
Dry

51.87
51.73
6.29
6.20
O.50
O.50
0.055
0.042
1.45
1.49
<100
<100
25
27
<100
<100
3
5
39.82
40.03
8767
9342
<0.048
O.049
<0.050
<0.047
<0.049
<0.049
12/04/98
09/29/98
A035822
816-531-0315


%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm
Method
ASTMD-5142
ASTM D-5373
ASTM D-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTM D-3 761
EPA SW-846
5050/9056
ASTM D-3 869
ASTM D-3 176
ASTM D- 1989
EPA SW-846
7471
                 This report shall not be reproduced, except in full, without the written approval of the laboratory.
                                                Page 1 of3
    BUILDING
   PARTNERSHIPS
KM CON11SUOUS lMrKOVEM€NT
U.S. Mail: P.O. Box 51610   Knoxvi/le, TN 37950-1610
Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
Tel: (423) 546-1335  •  Fax: (423) 546-7209
                           APPENDIX C
                                                                 49

-------
GALBRAITH® LABORATORIES, INC.
            Accuracy with speed  since 1950
         LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
8002A Z-5070 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine -?/,„<
A«/VWf IZ/LtfC'%
Bromine
Iodine
Oxygen (by difi)
HHV
Mercury
Report Date:
Lab I.D.:
As
Received
11.57
11.61
45.65
45.81
6.72
6.81
<0.44
<0.44
0.038
0.034
1.23
1.31
<88
<88
82
80
<88
<88
2
2
35.61
35.28
8036
8213
<0.042
O.044
<0.042
<0.043
<0.043
<0.044

%
%
%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm
Dry

51.63
51.82
6.15
6.25
<0.50
<0.50
0.043
0.038
1.39
1.48
<100
<100
93
91
<100
<100
2
2
40.28
39.91
9089
9290
<0.048
O.050
<0.048
<0.049
<0.049
<0.050
12/04/98
Z-5069-70


%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
ppm
ppm
ppm
ppm
ppm
ppm
I! Method
ASTMD-5142
ASTMD-5373
ASTMD-5373
ASTM D-5373
ASTMD-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTMD-3869
ASTM D-3 176
ASTM D- 1989
EPA SW-846
7471
     19%
    BUILDING
   PARTNERSHIPS
FOR CONTINUOUS iMrwovrwcHT
                This report shall not be reproduced, except in full, without the written approval of the laboratory. Page 2 of 3
       U.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610

       Other Carriers: 2323 Sycamore Drive   Knoxville. TN 37921-1750
       Tel: (423) 546-1335  •  Fax: (423) 546-7209
                APPENDIX C
                                                      5O

-------
                           GALBRAITH®  LABORATORIES, INC.
                                        Accuracy with speed  since 1950
                                     LABORATORY REPORT
David Alburty                                           Report Date:               12/04/98
Midwest Research Institute                                  Labl.D.:                 Z-5069-70
                                               Note

The original Chain of Custody is included with the mailed report.


                                      Preparation Confirmation

As requested, Lab ID#s Z-5069 and Z-5070 were refrigerated prior to analysis. The samples were also dried and ground prior to
analysis to provide a more homogeneous sample for testing.
 PACiyd                           This report shall not be reproduced, except in full, without the written approval of the laboratory.         Page 3 of3
                                   L/.S. Mail: P.O. Box 51610    Knoxville, TN 37950-1610
                                   Other Carriers: 2323 Sycamore Drive    Knoxville, TN 37921-1750
                                   Tel: (423) 546-1335  •  Fax: (423) 546-7209

                                            APPENDIX C                              51

-------
GALBRAITH® LABORATORIES,  INC.
            Accuracy with speed since  1950
         LABORATORY REPORT
David Alburty
Midwest Research Institute
425 Volker Blvd.
Kansas City MO 64110
SAMPLE DD LAB ED ANALYSIS
1 00 1 A Z-3 778 - 79(a) Karl Fischer
Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
Density
Viscosity
CORRECTED REPORT
Date Corrected: 12/16/98
Sample Received: 09/18/98
Original Report Date: 1 2/04/98
Purchase Order #: A035822
Fax Number: 816-531-0315
As
Received
0.042 (d)
0.040 (d)
79.86
79.95
10.72
10.79
<0.50
<0.50
0.73
0.67
1.31
1.20
<92
<98
78
i 74
<92
<98
4
4
6.87
6.88
16756
17244
1.017
1.017
207.29
207.16

%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
Btu/lb
Btu/lb
g/cmj
g/cm3
cSt (c)
@100°C
Dry

79.89 %
79.98 %
10.72 %
10.79 %
<0.50 %
<0.50 %
0.73 %
0.67 %
1.31 %
1 .20 %
<92 ppm
<98 ppm
78 ppm
74 ppm
<92 ppm
<98 ppm
4 ppm
4 ppm
6.87 %
6.88 %
16763 Btu/lb
17251 Btu/lb


Method
ASTMD-5142
ASTM D-5373
ASTM D-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTM D-3761
EPA SW-846
5050/9056
ASTM D-3869
ASTM D-3 176
ASTM D-1989

ASTM D-445
    BUILDING
   PARTNERSHIPS
FOR CONTINUOUS IMPROVEMENT
      This report shall not be reproduced, except in full, without the written approval of the laboratory.



       L/.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610

       Other Carriers: 2323 Sycamore Drive   Knoxville,  TN 37921-1750
       Tel: (423) 546-1335 •  Fax:(423)546-7209
                                                                  Page I of II
               APPENDIX  C

-------
           GALBRAITH® LABORATORIES, INC.
                      Accuracy with speed since 1950
                   LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
1001A Z-3778 - 79(a) Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
Corrected Report Date:
Lab I.D.:
As
Received
8
9
<7
<6
<7
<6
<4
<4
<4
<4
<4
<4
<4
<4
330
330
<7
<6
11
10
13
13
<0.050
<0.049
<0.047
<0.046
<0.050
<0.049
<4
<4
270
260

ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Dry
8
9
<7
<6
<7
<6
<4
<4
<4
<4
<4
<4
<4
<4
330
330
<7
<6
11
10
13
13
<0.050
<0.049
<0.047
O.046
<0.050
<0.049
<4
<4
270
260
12/16/98
Z-3778-87

ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
I! Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
   PARTNERSHIPS
FOR CONTINUOUS IMrROVEMENT
               This report shall not be reproduced, except m full, without the written approval of the laboratory.
U.S. Mail: P.O. Box 51610  • Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
Tel: (423)546-1335 •  Fax:(423)546-7209
                                              Page 2 of 11
                          APPENDIX C
                                                               53

-------
GALBRAITH® LABORATORIES, INC.
           Accuracy with speed  since 1950
        LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS

1001A Z-3778-79(a) Selenium

Silver

Sodium

Vanadium

Zinc

Corrected Report Date:

As
Received
<7
<4
<1
<1
0.37
0.37
<4
<4
9
8.
Lab I.D.:


ppm
ppm
ppm
ppm
%
%
ppm
ppm
ppm
ppm
12/16/98
Z-3778-87
Dry

<7
<4
<1
<1
0.37
0.37
<4
<4
9
8


ppm
ppm
ppm
ppm
%
%
ppm
ppm
ppm
ppm
1 Method

EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
This report shall not ba reproduced, except in full, without (He written approval of the laboratory
                                                 Page 3 of 1 1
       U.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610
       Other Carriers: 2323 Sycamore Drive   Knoxville. TN 37921-1750
       Tel: (423) 546-1335 •  Fax:(423)546-7209


               APPENDIX C
                                                   54

-------
GALBRAITH® LABORATORIES,  INC.
            Accuracy with speed  since 1950
         LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
1002A Z-3780-81(a) Karl Fischer
Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
»?f>?c.-t (,\- 2-c*. yfl ''l\
Bromine
Iodine
Oxygen (by diff)
HHV
Density
Viscosity
Corrected Report Date:
Lab I.D.:
As
Received
0.059 (d)
0.040 (d)
79.64
79.68
10.54
10.76
<0.50
<0.50
0.60
0.65
1.44
1.43
<92
<95
10
9
<92
<95
2
3
7.27
6.98
17085
17044
1.023
1.022
202.44
202.47

%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
Btu/lb
g/cmj
g/cm3
cSt (c)
@100°C
Dry

79.68
79.72
10.54
10.76
<0.50
<0.50
0.60
0.65
1.44
1.43
<92
<95
10
9
<92
<95
2
3
7.28
6.98
17093
17052


12/16/98
Z-3778-87
1 Method
ASTMD-5142
% ASTM D-5373
% ASTM D-5373
% ASTM D-5373
% ASTM D-4239
% ASTMD-5142
ppm EPA SW-846
ppm 5050/9056
ppm ASTMD-3761
ppm
ppm EPA SW-846
ppm 5050/9056
ppm ASTM D-3869
ppm
% ASTM D-3 176
Btu/lb ASTM D- 1989

ASTM D-445
    BUILDING
   PARTNERSHIPS
FOR CONTINUOUS IMPHOVEMENT
                 This report shall not be reproduced, except in full, without the written approval of the laboratory.
        L/.S. Mail: P.O. Box 51610    Knoxville, TN 37950-1610
        Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
        Tel: (423) 546-1335 •  Fax: (423) 546-7209
                                                       Page 4 of 1 1
                APPENDIX C
                                                      55

-------
GALBRAITH® LABORATORIES, INC.
           Accuracy with speed - since 1950
        LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
1002 A Z-3780-81(a) Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
Corrected Report Date:
Lab I.D.:
As
Received
10
9
! <7
<8
<7
<5
<4
<5
<4
<5
<4
<5
<4
340
340
<8
<7
13
10
13
13
O.049
<0.047
<0.047
<0.051
<0.047
<0.048
<5
<4
270
270

ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Dry
10
9
140
<7
<8
<7
<5
<4
<5
<4
<5
<4
<5
<4
340
340
<8
<7
13
10
13
13
<0.049
<0.047
<0.047
<0.051
<0.047
<0.048
<5
<4
270
270
12/16/98
Z-3778-87

ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
    This report shall not be reproduced, except m full, without the written approval of the laboratory.
       U.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610
       Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
       Tel: (423) 546-1335 •  Fax: (423) 546-7209


               APPENDIX  C
Page 5 of II
                                                   56

-------
           GALBRAITH® LABORATORIES, INC.
                       Accuracy with speed  since 1950
                    LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE EO LAB ED
Corrected Report Date:
Lab I.D.:
ANALYSIS As Dry
Received
12/16/98
Z-3778-87
1 Method
1002A Z-3780-81(a) Selenium
Silver
Sodium
Vanadium
Zinc
4003 A Z-3782(a) Chlorine
Fluorine
Bromine
Iodine
<8
<7

-------
           GALBRAITH® LABORATORIES,  INC.
                       Accuracy with speed  since 1950
                    LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
4002A Z-3784-85 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
Aluminum
Antimony
Corrected Report Date: 12/16/98
Lab I.D.: Z-3778-87
As
Received
96.44
96.44
1.83
1.81
10.93
10.93
0.27
0.27
0.026
0.027
0.52
0.51
0.049
0.045
2.76
2.88

-------
           GALBRAITH® LABORATORIES,  INC.
                       Accuracy with speed - since 1950
                    LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
Corrected Report Date:
Lab I.D.:
As Received

Dry
12/16/98
Z-3778-87

|| Method 1

4002A Z-3784-85 Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
Selenium
Silver
Sodium
Vanadium
Zinc
<0.3
<0.3
0.2
0.2
O.2
<0.2
1.0
1.0
0.68
0.69
0.022
0.022
<0.3
0.3
0.0036
0.0039
4
4
0.0021
O.0018
0.0018
O.0018
0.0017
O.0018
1.9
1.9
0.0035
0.0035
O.3
0.3
O.04
O.04
0.10
0.10
O.2
O.2
4
4
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
ppm
ppm
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
ppm
ppm
ppm
ppm
%
%
ppm
ppm
ppm
ppm
<8
<8
<5
<5
<5
<5
29
29
19
19
0.62
0.63
<8
<8
0.10
0.11
100
100
0.058
O.051
O.051
O.051
O.049
O.050
53
53
0.098
0.099
<8
<8
<1
<1
2.69
2.74
<5
<5
100
100
ppm
Ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
ppm
ppm
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
ppm
ppm
ppm
ppm
%
%
ppm
ppm
ppm
ppm
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
    BUILDING
   PARTNERSHIPS
FOR CONTINUOUS IMPROVEMENT
This report shall not be reproduced, except in full, without the written approval of the laboratory
  U.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610
  Other Carriers: 2323 Sycamore Drive  • Knoxville, TN 37921-1750
  Tel: (423) 546-1335 •  Fax: (423) 546-7209
                                                                  Page 8 01 1 1
                          APPENDIX C
                                                                59

-------
GALBRAITH® LABORATORIES,  INC.
            Accuracy with speed  since 1950
         LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ED LAB ED ANALYSIS
4001 A Z-3786-87 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Corrected Report Date:
Lab I.D.:
As
Received
96.49
96.46
1.86
1.85
10.94
10.94
0.27
0.27
0.028
0.026
0.50
0.50
0.053
0.054
3
3
<16(b)
<18(b)
0.2
0.2
0.60
0.61
352
361
0.0063
0.0063
<0.3
<0.3
<0.3
<0.3
<0.2
<0.2
<0.2
<0.2

%
%
%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Dry

52.66
52.46
6.14
6.53
7.65
7.57
0.79
0.75
14.27
14.21
1.49
1.54
77
80
<470(b)
<500(b)
6
5
17.00
17.34
9973
10227
0.18
0.18
<8
<8
<8
<8
<5
<5
<5
<5
12/16/98
Z-3778-87


%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
I! Method
ASTMD-5142
ASTM D-5373
ASTMD-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTM D-3869
ASTM D-3 176
ASTM D-1989
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
    This report shall not be reproduced, except in full, without the written approval of the laboratory.
       U.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610
       Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
       Tel: (423) 546-1335  •  Fax: (423) 546-7209
Page 9 of 11
               APPENDIX  C
                                                     60

-------
            GALBRAITH® LABORATORIES, INC.
                       Accuracy with speed  since 1950
                    LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
Corrected Report Date:
Lab I.D.:
As
Received

Dry
12/16/98
Z-3778-87


Method

4001A Z-3786-87 Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
Selenium
Silver
Sodium
Vanadium
Zinc
0.96
0.93
0.67
0.66
0.023
0.022
<0.3
<0.3
0.0042
0.0039
4
4
O.017
0.017
O.018
O.017
O.018
O.018
2
2
0.0036
0.0037
0.3
O.3
O.04
0.03
0.10
0.093
0.2
O.2
3
3
ppm
PPrn
ppm
ppm.
%
%
ppm
ppm
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
ppm
ppm
ppm
ppm
%
%
ppm
ppm
ppm
ppm
27
26
19
19
0.65
0.62
<8
<8
0.12
0.11
100
100
O.049
O.049
O.051
O.049
O.051
0.051
53
51
0.10
0.10
<8
<8
<1
<1
2.84
2.65
<5
<5
99
99
ppm
ppm
ppm
ppm
%
%
ppm
ppm
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
ppm
ppm
ppm
ppm
%
%
ppm
ppm
ppm
ppm
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
    BUILDING
   PARTNERSHIPS
FOR CONIINUOUS IMPROVEMENT
                This report shall not be reproduced, except in full, without the written approval of the laboratory.
                                               Page 10 of 11
U.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
Tel: (423) 546-1335  •  Fax: (423) 546-7209
                           APPENDIX  C
                                                                 61

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                              GALBRAITH®  LABORATORIES, INC.
                                            Accuracy with speed  since 1950
                                        LABORATORY REPORT
David Alburty                                              Corrected Report Date:       12/16/98
Midwest Research Institute                                    Lab I.D.:                  Z-3778-87
                                               General Note

The original Chain of Custody is included with the mailed report.


                                         Preparation Confirmation


As requested, Lab ID#s Z-3778-87 were refrigerated prior to analysis. The samples were also dried and ground, unless otherwise
noted, prior to analysis to provide a more homogeneous sample for testing.


                                              Technical Note

(a)Lab ID#'s Z-3778-83 were analyzed on an as received basis.

^ The detection limit for Bromine is elevated due to the presence of high levels of nitrate in samples.

 This result was inadvertantly omitted from the original Laboratory Report. We apologize for any inconvenience our error may
have caused.
(d) This result was inadvertantly omitted.
PACiyd                             This report shall not be reproduced, except in full, without the written approval of the laboratory.           Page 11 of 11
                                       U.S. Mail: P.O. Box 51610    Knoxville, TN 37950-1610
                     MM™              Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
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                                                 APPENDIX C

-------
            GALBRAITH® LABORATORIES, INC.
                       Accuracy with speed - since 1950
                  LABORATORY REPORT
David Alburty
Midwest Research Institute
425 Volker Blvd
Kansas City MO 64110-2299
SAMPLE ID LAB ID ANALYSIS
11001A Repeat A-4361 Fluorine
11001A Repeat A-4362 Antimony
11002A Repeat A-4363 Fluorine
11001C Repeat A-4364 Chlorine
11002C Repeat A-4365 Chlorine
Reanalysis Request: 12/18/98
Previous Lab I.D.: A4361-65
Report Date: 01/07/99
Fax Number: 816-531-0315
RESULT(S)
0.18
0.19 (a)
72
82 (b)
280
240 (a)
66
100 (c)
71
37 (c)

%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
'OS
 19%
BL1LDINC
     PAKINERSMIPS
  FOR COVmt-OUS IMrWOVEMEVT
This report snail not be reproduced, except in full, without the written approval of the laboratory.


 U.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610
 Other Carriers: 2323 Sycamore Drive   Knoxville. TN 37921-1750
 Tel: (423) 546-1335  •  Fax: (423) 546-7209
                                                                    Page 1 of2
                           APPENDIX C
                                                               63

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                          GALBRAITH® LABORATORIES, INC.
                                        Accuracy with speed  since 1950
                                       LABORATORY REPORT
David Alburty                                             Report Date:               01/17/99
Midwest Research Institute                                   Labl.D.:                  A-4361-A-4365
                                            Technical Notes
(a) The retest confirms the fluorine levels found in the original analyses.

^  The retest confirms the presence of antimony in sample 11001 A. The antimony appears to be heterogeneously distributed in the
sample.
(c)
  The retest results indicates the chlorine does not appear to be evenly distributed throughout the sample.
PAClle       /^^/iLwS/^^wf       ™S rBPOrt Sha" "°t ^repfoduced'except" (ul|.*ithou the written approval of the laboratory.             Page 2 of 2

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                                            APPENDIX C                               Ka

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                          GALBRAITH®  LABORATORIES, INC.
                                       Accuracy with speed  since 1950
                                    LABORATORY REPORT
David Alburty
Midwest Research Institute
425 Volker Blvd.
Kansas City MO 64110
                  Reanalysis Request:
                  Previous Lab I.D.:
                  Report Date:
                  Fax#:
12/18/98
Z-3778, Z-3780-81
12/28/98
816-531-0315
SAMPLE ED
I001A Repeat
1002A Repeat
1002A Repeat
LAB ED
A-4201
A-4202
A-4203
ANALYSIS
Fluorine
Fluorine
Antimony

62
20
<9
RESULTS
ppm
ppm
* ppm
DUPLICATE METHOD
RESULTS
58 ppm ASTMD-3761
16 ppm ASTMD-3761
<10 * ppm EPASW-846
3050B/6010
                    ee\
                 PARTNERSHIPS
              ran Cor^TiNuous IMCKOVE.MECT
                                      This report shall not be reproduced, except in full, without the written approval of the laboratory.
U.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive    Knoxville, TN 37921-1750
Tel: (423) 546-1335  •  Fax: (423) 546-7209
                                                            Page 1
                                           APPENDIX  C
                                                   65

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                             GALBRAITH® LABORATORIES, INC.
                                          Accuracy with speed  since 1950
                                       LABORATORY  REPORT
David Alburty                                            Reanalysis Report Date:       12/28/98
Midwest Research Institute                                  Lab I.D.:                  A-4201-A-4203
                                                 Note
   *
As requested, Lab ID#s A-4201-03 were refrigerated prior to analysis.


                                            Technical Note

*  The original sample 1002A appears to have been contaminated with antimony prior to analysis.  There is no charge for the repeat
antimony analysis.
P AC: le                             This report shall not be reproduced, except in full, without the written approval of the laboratory.             Page 2 of 2
            q«%
               ^^.y (On*    •^ij^h>j.
               ^*y L?  toaf.      H
                     L/.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610
    I-..TNEUH.PS            Other Carriers: 2323 Sycamore Drive   Knoxville. TN 37921-1750
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                    PARTNERSHIPS
                                              APPENDIX  C                              66

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            GALBRAITH® LABORATORIES, INC.
                       Accuracy with speed  since 1950
                    LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ED ANALYSIS
9001A Repeat A-2I83-84 Magnesium
Manganese
Mercury
Nickel
Potassium
Selenium
Silver
Sodium
Vanadium
Zinc
Reanalysis Request:
Lab I.D.:
As
Received
770
28
<0.045
<0.043
O.041
<4
0.61
<6
<2
120
<4
9

ppm
ppm
ppm
ppm
ppm
ppm
%
ppm
ppm
ppm
ppm
ppm
Dry
880
32
<0.051
<0.049
O.047
<4
0.69
<7
<2
140
<4
10
12/18/98
A-2183-A-2186

ppm
ppm
ppm
ppm
ppm
ppm
%
ppm
ppm
ppm
ppm
ppm
I! Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
    BUILDING
   PARTNERSHIPS
FOR COVIIMJOUS I WrROVEME.VT
This report shall not be reproduced, except in full, without the written approval of the laboratory.         Page 2 of 5




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   Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750

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           APPENDIX C                          67

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           GALBRAITH® LABORATORIES, INC.
                      Accuracy with speed  since 1950
                   LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
9002A Repeat A-2 185-86 Magnesium
Manganese
Mercury
Nickel
Potassium
Selenium
Silver
Sodium
Vanadium
Zinc

As
Received
790
29
<0.043
O.042
O.043
<4
0.59
<7
<2
130
<4
9
Reanalysis
Lab I.D.:

ppm
ppm
ppm
ppm
ppm
ppm
%
ppm
ppm
ppm
ppm
ppm
Request:
Dry
890
33
O.049
O.048
O.049
<5
0.67
<8
<2
150
<5
10
12/18/98
A-2183-A-2186

ppm
ppm
ppm
ppm
ppm
ppm
%
ppm
ppm
ppm
ppm
ppm
1 Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
    BUILDING
   PARTNERSHIP
FOR COSTINUOtS [MfHOVEMEVT
This report shall not be reproduced, except in full, without the written approval of the laboratory.          Page 4 of 5


   U.S. Mail: P.O. Box 51610    Knoxville, TN 37950-1610
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          APPENDIX C                           68

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                             GALBRAITH® LABORATORIES,  INC.
                                          Accuracy with speed  since 1950
                                       LABORATORY  REPORT
 David Alburty                                            Reanalysis Report:           12/18/98
 Midwest Research Institute                                   Lab I.D.:                  A-2183-A-2186
                                             General Note


 As requested, Lab ID#'s A-2183-85 were refrigerated prior to analysis. The samples were also dried and ground prior to analysis to
 provide a more homogeneous sample for testing.


 (l) The moisture results reported with these samples were determined under Lab ID #'s Z-4550-53. Each sample was dried in its entirety
 for the initial testing.
LE:le                               Th's report shall not be reproduced, except in full, without the written approval of the laboratory.             Page 5 of 5
                                     L/.S. Mail: P.O. Box 51610    Knoxville, TN 37950-1610
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                                     Tel: (423) 546-1335  •  Fax:(423)546-7209
                                              APPENDIX C
                                                                                          69

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                          GALBRAITH® LABORATORIES, INC.
                                      Accuracy with speed  since 1950
                                   LABORATORY REPORT
David Alburty Reanalysis Request: 12/20/98
Midwest Research Institute Previous Lab I.D.: Z-3923-24
425 Volker Blvd. Report Date: 12/28/98
Kansas City MO 64110 Fax#: 816-531-0315
SAMPLED) LAB ID ANALYSIS RESULTS
6001 A Repeat A-4204 Fluorine 10 ppm
DUPLICATE METHOD
RESULTS
18 ppm ASTMD-3761
6002A Repeat    A-4205
           Fluorine
53
                                     ppm
48
                               ppm
ASTM D-3761
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FOR CONTINUOUS JMDIOVEM£NT
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                                 U.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610

                                 Other Carriers: 2323 Sycamore Drive    Knoxville, TN 37921-1750

                                 Tel: (423) 546-1335  •  Fax: (423) 546-7209



                                         APPENDIX C
                                                                           Pag'i
                                                                                70

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                           GALBRAITH® LABORATORIES, INC.
                                       Accuracy with speed  since 1950
                                    LABORATORY REPORT
 David Alburty                                          Reanalysis Report Date:      12/28/98
 Midwest Research Institute                                 Lab I.D.:                 A-4204-A-4205
                                              Note


 As requested, Lab ID#s A-4204-05 were refrigerated @4°C prior to analysis.


 Analyses were performed on a dried and ground basis.
PAC:le                            This report shall not be reprodjced, except in full, without the wiitlen approval of the laboratory.            Page 2 Of2


                        B|

                           1        U.S. Mail: P.O. Box 51610    Knoxville, TN 37950-1610
                                   Other Carriers: 2323 Sycamore Drive   Knoxville, TN 37921-1750
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                                            APPENDIX C                             7T

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                         GALBRAITH® LABORATORIES, INC.
                                     Accuracy with speed  since 1950
                                  LABORATORY REPORT
David Alburty Reanalysis Request: 12/20/98
Midwest Research Institute Previous Lab I.D.: Z-5069-70
425 Volker Blvd. Report Date: 12/28/98
Kansas City MO 64110 Fax#: 816-531-0315
SAMPLED) LAB ID ANALYSIS RESULTS
8001 A Repeat A-4206 Fluorine 13 ppm
DUPLICATE METHOD
RESULTS
19 ppm ASTMD-3761
8002A Repeat    A-4207
Fluorine
71
                         ppm
66
                               ppm
ASTMD-3761
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               APPENDIX C
                                                                                       Page I
                                                                               72

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                           GALBRAITH® LABORATORIES, INC.
                                        Accuracy with speed  since 1950
                                    LABORATORY REPORT
David Alburty                                          Reanalysis Report Date:      12/28/98
Midwest Research Institute                                 Labl.D.:                 A-4206-A-4207
                                              Note

As requested, Lab ID#s A-4206-07 were refrigerated @4°C prior to analysis.

Samples 8001A and 8002A were analyzed on the dried and ground basis.
PAClle                           This report shall not be reproduced, except in full, without ttie written approval of the laboratory.             Page 2 of 2


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                                            APPENDIX C                              73

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GALBRAITH® LABORATORIES,  INC.
           Accuracy with speed - since 1950
         LABORATORY REPORT
David Alburty
Midwest Research Institute
425 Volker Blvd.
Kansas City MO 64110
SAMPLE ID LAB DD
9001 A Z-4550-51


ANALYSIS
Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV

As
Received
11.72
44.01
6.64
1.14
0.11
2.96
110
18
<170
23
34.72
7423
Report Date:
Sample Received:
Purchase Order #:
Fax#:

%
%
%
%
%
%
ppm
ppm
ppm
ppm
%
Btu/lb
11/20/98
09/24/98
A035822
816-531-0315
Dry

49.85
6.05
1.29
0.12
3.35
120
20
<200
26
39.33
8409


%
%
%
%
%
ppm
ppm
ppm
ppm
%
Btu/lb
1 Method
ASTMD-5142
ASTMD-5373
ASTMD-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTM D-3761
EPA SW-846
5050/9056
ASTM D-3869
ASTM D-3 176
ASTM D-l 989
      Thii report shall not be reproduced, except in full, without the written approval of the laboratory.        Page 1 of 7



        L/.S. Mail: P.O. Box 51610   Knoxville, TN 37950-1610
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        Tel: (423) 546-1335  •  Fax:(423)546-7209


                APPENDIX  C                          74

-------
          GALBRAITH® LABORATORIES,  INC.
                      Accuracy with speed  since 1950
                    LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
9001 A Z-4550-51 Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
Report Date:
Lab I.D.:
As
Received
530
<9
<9
<4
<4
<4
<4
350
<9
790
31
<0.040
O.044
O.043
<4
0.72

ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
Dry
600
<10
<10
<5
<5
<5
<5
400
<10
890
35
O.045
<0.050
<0.050
<5
0.81
1 1/20/98
Z-4550-53

ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
    BUILDING
   PARTOERSHIPS
FOR CONTINUOUS IMPROVEMENT
                Tills report shall not b« reproduced, except in full, without the written approval of the laboratory.           Page 2 of 7
U.S. Mail: P.O. Box 51610  • Knoxville, TN 37950-1610
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Tel: (423) 546-1335  •  Fax:(423)546-7209


        APPENDIX  C                           75

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           GALBRAITH®  LABORATORIES, INC.
                       Accuracy with speed  since 1950
                    LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
9001A Z-4550-51 Selenium
Silver
Sodium
Vanadium
Zinc
Report Date: 11/20/98
Lab I.D.: Z-4550-53
As
Received
<9 ppm
<0.9 ppm
95 ppm
<4 ppm
16 ppm
Dry 1 Method
I
<10 ppm EPA SW-846
3050B/6010
<1 ppm EPA SW-846
3050B/6010
110 ppm EPA SW-846
3050B/6010
<5 ppm EPA SW-846
3050B/6010
18 ppm EPA SW-846
3050B/6010
                This report shall not be reproduced, except in full, without the written approval of the laboratory.
                                             Page 3 of 7
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       APPENDIX  C                          Z6

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              Galbraith Laboratories, Inc.
                          Accuracy with Speed - Since 1950
                       LABORATORY REPORT
David Alburty
Midwest Research Institute
425 Volker Blvd.
Kansas City MO 64110

SAMPLE ED LAB ED
10001A Z-4375-6














AMENDED REPORT




Date Amended
Sample Received:
01/08/99
09/23/98


Original Report Date: 1 1/24/98

ANALYSIS
Moisture

Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine

Fluorine
Bromine

Iodine
Oxygen (by diff)
HHV

As
Received
3.26
3.85
46.92
6.76
<0.48 w
0.14
2.53
35.48

34
<180

<1
4.53
10008
Fax Number:

%
%
%
%
%
%
%
%

ppm
ppm

ppm
%
Btu/lb
816-531-0315
Dry


48.65 %
6.60 %
<0.50(e) %
0.15 %
2.62 %
36.79 %

35 ppm
<190 ppm

<1 ppm
4.69 %
10377 Btu/lb
Method
ASTMD-5142

ASTM D-5373
ASTM D-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
9253
ASTMD-3761
EPA SW-846
5050/9056
ASTM D-3869
ASTM D-3 176
ASTM D- 1989
                    This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 1 of 28
                U.S. Mail: P. O. Box 51610 » Knoxville, TN 37950-1610
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Tel: 423/546-1335  • Fax: 423/546-7209 • Internet: www.galbraith.com » e-mail: labinfo@galbraith.com

                             APPENDIX  C
                                                                     77

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             Galbraith  Laboratories, Inc.
— • di 	 ' 	
•^^^^^^H Accuracy with Speed - Since 1 950
KjEniECIIj^H
BlIIIIIIIIIIIIIIM LABORATORY REPORT
David Alburty Report Date:
Midwest Research Institute
I SAMPLE ID LAB ID ANALYSIS
I
10001A Z-4375-6 Aluminum

Antimony

Arsenic

Beryllium

Cadmium

Chromium

Copper

Iron

Lead

Magnesium

Manganese

Mercury


Nickel

Potassium


As
Received
14

<7

<7

<5

10

71

79

14

<7

34

<5

<0.048
<0.048
<0.048
15

160

Lab I.D.:


ppm

ppm

ppm

ppm

ppm

ppm

ppm

ppm

ppm

ppm

ppm

ppm
ppm
ppm
ppm

ppm

01/08/99

Z-4375-94
Dry

15

<8

<8

<5

10

73

82

15

<8

35

<5

<0.050
<0.050
<0.050
16

160



ppm

ppm

ppm

ppm

ppm

ppm

ppm

ppm

ppm

ppm

ppm

ppm
ppm
ppm
ppm

ppm

Method

EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471

EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
                  This report shall not be reproduced, except In full, without the written approval of the laboratory
Page 2 of 28
                U.S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
             Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 » Fax: 423/546-7209 • Internet: www.galbraith.com • e-mail: labinfo@galbraith.com

                             APPENDIX C
                                                                     78

-------
                            Galbraith  Laboratories, Inc.
                                         Accuracy with Speed - Since 1950
                                      LABORATORY REPORT
David Alburty
Midwest Research Institute
                                        Report Date:
                                        Lab I.D.:
                                                   01/08/99
                                                   Z-4375-94
SAMPLE ID   LAB ID
             ANALYSIS
                   As
                Received
                      Dry
                  Method
10001A
Z-4375-6
Selenium
<7
                                                        ppm
<8
                                                                 ppm
EPA SW-846
3050B/6010
                           Silver
                               1.4
                                                        ppm
                                          1.4
                           Sodium
                              490
                                                        ppm
                                         510
                           Vanadium
                              <5
                                                        ppm
                                         <5
                                                                 ppm
                                                                 ppm
                                                                 ppm
                                           EPA SW-846
                                           3050B/6010
                                           EPA SW-846
                                           3050B/6010
                                           EPA SW-846
                                           3050B/6010
                           Zinc
                              320
                                                        ppm
                                         330
                                                                 ppm
                                           EPA SW-846
                                           3050B/6010
                                 This report shall not be reproduced, except in full, without the written approval of the laboratory
                                                                         Page 3 of 28
                               U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
                           Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
              Tel: 423/546-1335 » Fax: 423/546-7209 • Internet: www.galbraith.com • e-mail: labinfo@galbraith.com
                                             APPENDIX  C
                                                                                        79

-------
              Galbraith Laboratories, Inc.
                          Accuracy with Speed - Since 1950
                       LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
10002A Z-4377-800 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV
Report Date:
Lab I.D.:
As
Received
2.29 %
3.85 %
46.58 %
46.73 %
6.62 %
6.66 %
<0.48(e) %
<0.48 M %
0.059 %
0.058 %
2.65 %
2.67 %
36.54 %
36.75 %
34 ppm
38 ppm
<180 ppm
<180 ppm
<2 ppm
<2 ppm
4.40 %
3.98 %
10115 Btu/lb
9977 Btu/lb
01/08/99
Z-4375-94
Dry

48.06 %
48.21 %
6.48 %
6.52 %
<0.50(e) %
<0.50 (e) %
0.061 %
0.060 %
2.73 %
2.75 %
37.69 %
37.92 %
35 ppm
39 ppm
<190 ppm
<180 ppm
<2 ppm
<2 ppm
4.54 %
4.10 %
10435 Btu/lb
10293 Btu/lb

Method
ASTMD-5142
ASTM D-5373
ASTM D-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
9253
ASTMD-3761
EPA SW-846
5050/9056
ASTM D-3869
ASTM D-3 176
ASTM D- 1989
                    This report shall not be reproduced, except in full, without tne written approval of the laboratory.
Page 4 of 28
                U. S. Mail: P. O. Box 51610 « Knoxville, TN 37950-1610
             Other Carriers: 2323 Sycamore Drive « Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 . Internet: www.galbraith.com • e-mail: labinfo@galbraith.com

                             APPENDIX C
                                                                       80

-------
              Galbraith  Laboratories,  Inc.
"' '"• ^g 	 • " 	
•••••^^•••^l Accuracy with Speed -Since 1950
mmmmuutiB LABORATORY REPORT
David Alburty Report Date:
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS

10002A Z-4377-8 Aluminum

Antimony

Arsenic

Beryllium

Cadmium

Chromium

Copper

Iron

Lead

Magnesium

Manganese

Mercury





Nickel

Potassium


As
Received
11
15
<7
<7
<7
<7
<4
<4
<4
6.00
98
98
99
99
33
33
<7
13
34
42
<4
<4
<0.047
<0.047
<0.050
<0.050
<0.051
<0.048
17
24
0.67

Lab I.D.:


ppm
ppm
ppm
PPm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
PPm
ppm
ppm
ppm
PPm
ppm
ppm
ppm
PPm
ppm
%

01/08/99
Z-4375-94
Dry

12
15
<7
<7
<7
<7
<4
<5
<4
6.00
100
100
100
100
34
34
<7
13
35
43
<4
<5
<0.049
O.048
<0.052
<0.052
<0.053
<0.050
17
25
0.76



PPm
PPm
PPm
PPm
PPm
PPm
PPm
ppm
ppm
PPm
PPm
ppm
ppm
ppm
PPm
PPm
PPm
PPm
PPm
PPm
ppm
PPm
PPm
PPm
ppm
ppm
ppm
ppm
ppm
ppm
%

1 Method

EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471




EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
                   This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 5 of 28
                U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
             Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 « Internet: www.galbraith.com •  e-mail: labinfo@galbraith.com

                             APPENDIX C
                                                                     81

-------
                           Galbraith Laboratories, Inc.
                                       Accuracy with Speed - Since 1950

                                    LABORATORY REPORT
David Alburty
Midwest Research Institute
                          Report Date:
                          Lab I.D.:
                                 01/08/99
                                 Z-4375-94
SAMPLE ID    LAB ED
ANALYSIS
   As
Received
Dry
Method
10002 A Z-4377-8 Selenium
Silver
Sodium
Vanadium
Zinc
<7
<7
<0.9
<0.9
450
530
<4
<4
280
380
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
<7
<7
<0.9
<0.9
470
550
<4
<5
290
390
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
                                This report shall not be reproduced, except in full, without the written approval of the laboratory.
                                                          Page 6 of 28
                             U. S. Mail: P. O. Box 51610 • Knoxvilie, TN 37950-1610
                          Other Carriers: 2323 Sycamore Drive • Knoxvilie, TN 37921-1750
             Tel: 423/546-1335 • Fax: 423/546-7209 • Internet: www.galbraith.com • e-mail: labinfo@galbraith.com

                                           APPENDIX  C
                                                                                    82

-------
              Galbraith  Laboratories,  Inc.
                         Accuracy with Speed - Since 1950
                       LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID
11001A Z-4379-80
„

ANALYSIS
Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV

As
Received
1.86
2.74
13.34
13.49
1.75
1.71
<0.49(e)
<0.49«
0.10
0.10
91.21
92.86
890
350
0.21
0.21
<93
<94
<2
<2

4104
3997
Report Date:
Lab I.D.:

I
%
%
%
%
% (b)
ppm
ppm
%
ppm
ppm
ppm
ppm
(b)
Btu/lb
Btu/lb
01/08/99
Z-4375-94
Dry

13.65 %
13.81 %
1.53 %
1.49 %
<0.50(e) %
<0.50(e) %
0.10 %
0.10 %
93.36 %
95.05 %
900 ppm
360 ppm
0.22 %
0.22 %
<95 ppm
<96 ppm
<2 ppm
<2 ppm

4201 Btu/lb
4091 Btu/lb

Method
ASTMD-5142
ASTM D-5373
ASTM D-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTM D-3869
ASTM D-3 176
ASTM D- 1989
                    This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 7 of 28
                U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
             Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 • Internet: www.galbraith.com • e-mail: labinfo@galbraith.com

                             APPENDIX  C
                                                                      83

-------
             Galbraith  Laboratories, Inc.
— • ^^J 	
M555^.j5i!^H Accuracy with Speed - Since 1 950
• m'imiiiiriiiiB LABORATORY REPORT
David Alburty Report Date:
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS

11001A Z-4379-80 Aluminum

Antimony
faft'r** ff. 72 -t-y'2 fp'
Arsenic

Beryllium

Cadmium

Chromium

Copper

Iron

Lead

Magnesium

Manganese

Mercury





Nickel

Potassium


As
Received
140
140
<9
i 35.00
<9
<9
<4
<5
<4
<5
0.64
0.64
9
9
0.18
0.20
<9
<9
0.11
0.11
64
74
<0.049
<0.048
<0.049
<0.049
<0.047
<0.048
7.39
7.77
0.14(f)
0.14(0
Lab I.D.:


ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
PPm
ppm
PPm
PPm
ppm
ppm
ppm
ppm
PPm
PPm
ppm
ppm
ppm
ppm
ppm
PPm
o/0(B)
o/0(g)
%
%
01/08/99
Z-4375-94
Dry

140
140
<9
(c) 36.00
<9
<9
<4
<5
<4
<5
0.65
0.66
9
9
0.18
0.21
<9
<9
0.11
0.12
65
75
0.050
O.049
O.050
O.050
O.048
O.049
7.57
7.95
0.14 W
0.14(f)


ppm
ppm
ppm
PPm
PPm
ppm
PPm
ppm
ppm
PPm
ppm
ppm
ppm
PPm
ppm
ppm
ppm
PPm
PPm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
PPm
PPm
o/0(g)
o/0(8)
%
%
1 Method

EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471




EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
                   This report shall not be reproduced, except in full, without the written approval of the laboratory
Page 8 of 28
                U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
             Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 » Internet: www.galbraith.com « e-mail: labinfo@galbraith.com

                             APPENDIX C
                                                                     84

-------
              Galbraith  Laboratories,  Inc.
                          Accuracy with Speed - Since 1950

                       LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID

ANALYSIS As
Received
Report Date:
Lab I.D.:
Dry
01/08/99
Z-4375-94
I! Method
11001 A Z-4379-80 Selenium
Silver
Sodium
Vanadium
Zinc
<9
<9
<0.9
14
140
180
<4
<5
66.69
72.08
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
0/0te)
o/0(g)
<9
<9
<0.9
14
140
190
<4
<5
68.25
73.78
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
o/0(fi)
o/0(g)
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
                  This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 9 of 28
                U.S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
             Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 » Internet: www.galbraith.com » e-mail: labinfo@galbraith.com


                             APPENDIX C
                                                                     85

-------
               Galbraith  Laboratories,  Inc.
                       LABORATORY REPORT
                          Accuracy with speed - Since 1950
David Alburty
Midwest Research Institute
I SAMPLE ID LAB ID ANALYSIS
11 002 A Z-4381-82 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
"'-/""•c Zt
Fluorine .
Bromine
Iodine
Oxygen (by diff)
HHV
Report Date:
Lab I.D.:
As
Received
2.23
1.88
11.90
11.70
1.48
1.49
<0.50 Ce)
<0.50 (e)
0.10
0.11
90.76
94.66
750
550
240
280
<94
<95
7
7

3964
3786

%
%
%
%
/Q
/O
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm

Btu/lb
Btu/lb
Dry

12.15
11.95
1.28
1.29
0.51 w
0.51 (e)
0.10
0.11
(b) 92.66
96.65
760
560
240
280
<96
<97
7
7
(b)
4047
3865
01/08/99
Z-4375-94


/Q
/O
/O
/O
/O
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm

Btu/lb
Btu/lb
I! Method
ASTMD-5142
ASTM D-5373
ASTM D-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTM D-3761
EPA SW-846
5050/9056
ASTM D-3869
ASTM D-3 176
ASTM D- 1989
                    This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 10 of 28
                U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
             Other Carriers: 2323 Sycamore Drive • Knoxville TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 • Internet: www.galbraith.com . e-mail: labinfo@galbraith.com

                              APPENDIX C
                                                                       86

-------
             Galbraith  Laboratories, Inc.
— • di —
B£"!^ZZz"J|IH Accuracy with Speed - Since 1950
•mimiiimiiM LABORATORY REPORT
David Alburty Report Date:
Midwest Research Institute
SAMPLE ID LAB ED ANALYSIS

11002A Z-4381-82 Aluminum

Antimony

Arsenic

Beryllium

Cadmium

Chromium

Copper

Iron

Lead

Magnesium

Manganese

Mercury





Nickel

Potassium


As
Received
100
99
<10
<10
<10
<10
<5
<5
<5
<5
0.66
0.65
8
7
550
540
<10
<10
0.12
0.11
19
19
<0.048
<0.047
<0.049
<0.049
<0.049
<0.049
111
7.75
0.14
0.13
Lab I.D.:


ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%to
0/0(s)
%

01/08/99

Z-4375-94
Dry

110
100
<10
<10
<10
<10
<5
<5
<5
<5
0.67
0.66
8
7
560
550
<10
<10
0.12
0.11
20
19
<0.049
<0.048
<0.050
<0.050
<0.050
<0.050
7.93
7.91
0.14
0.14


ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%(•>
o/0GO
%

Method

EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471




EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
                  This report shall not be reproduced, except in lull, without the wntten approval of the laboratory.
Page 11 of 28
                U. S. Mail: P, O. Box 51610 • Knoxville, TN 37950-1610
             Other Carriers: 2323 Sycamore Drive « Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 « Internet: www.galbraith.com • e-mail: labinfo@galbraith.com

                             APPENDIX C
                                                                      87

-------
                            Galbraith  Laboratories, Inc.
                                        Accuracy with Speed - Since 1950

                                     LABORATORY  REPORT
David Alburty
Midwest Research Institute
                          Report Date:
                          Lab I.D.:
                                 01/08/99
                                 Z-4375-94
SAMPLE ID   LAB ID
ANALYSIS
   As
Received
Dry
Method
11002A Z-4381-82 Selenium
Silver
Sodium
Vanadium
Zinc
<10
<10
<1
<1
191
163
<5
<5
70.77
72.28
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
o/0(g)
o/000
<10
<10
<1
<1
195
166
<5
<5
72.25
73.79
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%w
0/0(g)
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
                                This report shall not be reproduced, except in full, without the written approval of the laboratory.
                                                           Page 12 of 28
                               U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
                            Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
               Tel: 423/546-1335 • Fax: 423/546-7209 •  Internet: www.galbraith.com • e-mail: labinfo@galbraith.com

                                            APPENDIX  C
                                                                                      88

-------
              Galbraith Laboratories,  Inc.
                         Accuracy with Speed -Since 1950

                      LABORATORY  REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
11001C Z-4383-84 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine "
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV

As
Received
7.40
8.10
57.60
57.63
9.50
9.85
3.82
3.85
0.41
0.42
0.34
0.18
310
350

-------
              Galbraith  Laboratories,  Inc.
_^_ I
•S^^^^^^B Accuracy with Speed - Since 1 950
j^AmjjLLm
	 B LABORATORY REPORT
David Alburty Report Date:
Midwest Research Institute
I SAMPLE ID LAB ED ANALYSIS

11001C Z-4383-84 Aluminum

Antimony

Arsenic

Beryllium

Cadmium

Chromium

Copper

Iron

Lead

Magnesium

Manganese

Mercury





Nickel

Potassium


As
Received
79
130
<8
<9
<8
<9
<4
<4
<4
<4
<4
<4
<4
<4
55
88
<8
<9
14
16
<4
<4
O.046
<0.045
<0.046
<0.044
<0.045
O.044
15
4
43
55
Lab I.D.:


ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%

01/08/99

Z-4375-94
Dry

86
142
<9
<9
<9
<9
<5
<5
<5
<5
<5
<5
<5
<5
60
95
<9
<9
15
18
<5
<5
<0.050
<0.049
<0.050
<0.048
<0.049
<0.048
17
5
46
38


ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%

Method

EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471




EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
                  This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 14 of 28
                U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
             Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 • Internet: www.galbraith.com • e-mail: labinfo@galbraith.com

                             APPENDIX C
                                                                     90

-------
                            Galbraith  Laboratories, Inc.
                                         Accuracy with Speed - Since 1950

                                     LABORATORY  REPORT
David Alburty
Midwest Research Institute
                                        Report Date:
                                        Lab I.D.:
                                                  01/08/99
                                                  Z-4375-94
SAMPLE ED    LAB ED
             ANALYSIS
                   As
                Received
                      Dry
                  Method
11001C
Z-4383-84
Selenium
<8
<9
                                                       ppm
                                                       ppm
<9
<9
                                                                ppm
                                                                ppm
EPA SW-846
3050B/6010
                           Silver
                                                       ppm
                                                       ppm
                                                                ppm
                                                                ppm
                                                            EPA SW-846
                                                            3050B/6010
                           Sodium
                              130
                              150
                                                       ppm
                                                       PPm
                                         150
                                         170
                                  ppm
                                  PPm
                   EPA SW-846
                   3050B/6010
                           Vanadium
                              <4
                              <4
                                                       ppm
                                                       PPm
                                         <5
                                         <5
                                  ppm
                                  ppm
                   EPA SW-846
                   3050B/6010
                           Zinc
                              130
                              30
                                                       PPm
                                                       ppm
                                         140
                                         32
                                  ppm
                                  PPm
                   EPA SW-846
                   3050B/6010
                                This report shall not be reproduced, except in full, without the written approval of the laboratory.
                                                                         Page 15 of 28
                              U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
                           Other Carriers: 2323 Sycamore Drive » Knoxville, TN 37921-1750
             Tel: 423/546-1335 « Fax: 423/546-7209 • Internet: www.galbraith.com • e-mail: labinto@galbraith.com
                                            APPENDIX  C
                                                                                       91

-------
              Galbraith  Laboratories, Inc.
                          Accuracy with Speed - Since 1 950

                       LABORATORY REPORT
David Alburty
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
11002C Z-4385-86 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
_ Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV

As
Received
6.65
7.36
58.44
58.50
9.63
9.94
5.31
5.57
0.20
0.22
0.69
0.52
160
140
<\l
<94
<94
<2
<2
19.49
19.02
12024
11840
Report Date:
Lab I.D.:

°/°
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
Btu/lb
Btu/lb
01/08/99
Z-4375-94
Dry

62.84
62.91
9.52
9.85
5.71
5.99
0.22
0.24
0.74
0.56
180
150
<17
<100
<100
<2
<2
20.96
20.45
12930
12732


%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
Btu/lb
Btu/lb
1 Method
ASTMD-5142
ASTM D-5373
ASTM D-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
5050/9056
ASTMD-3761
EPA SW-846
5050/9056
ASTM D-3869
ASTM D-3 176
ASTM D-1989
                   This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 16 of 28
                U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
             Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 . Internet: www.galbraith.com • e-mail: labmfo@galbraith.com

                             APPENDIX C
                                                                      92

-------
               Galbraith  Laboratories, Inc.
A»-*^AI LABORATORY REPORT
•S-TTTTTTTTTT^B Accuracy with Speed - Since 1 950
^^^^^^^^^^^TQ^^^^^^^^I
David Alburty Report Date:
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS

11002C Z^1385-86 Aluminum

Antimony

Arsenic

Beryllium

Cadmium

Chromium

Copper

Iron

Lead

Magnesium

Manganese

Mercury





Nickel

Potassium


As
Received
130
130
<9
<9
<9
<9
<5
<5
<5
<5
<5
<5
<5
<5
86
130
<9
<9
63
75
10
13
<0.046
O.045
<0.046
<0.046
<0.044
<0.046
7
<5
370
460
Lab I.D.:


ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
01/08/99
•^^^^m^mmmmm
Z-4375-94
Dry

144
141
<10
<10
<10
<10
<5
<5
<5
<5
<5
<5
<5
<5
92
140
<10
<10
68
81
11
14
<0.049
<0.048
<0.049
O.049
<0.047
<0.049
8
<5
400
490


ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Ppm
Ppm
Ppm
ppm
ppm
ppm
ppm
ppm
ppm
Ppm
Method

EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471




EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
                   This report shall not be reproduced, except in full, without the written approval of the laboratory
Page 17 of 28
                U. S. Mail: P. O. Box 51610 » Knoxville, TN 37950-1610
             Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 • Internet: www.galbraith.com « e-mail: labinfo@galbraith.com

                             APPENDIX C
                                                                     93

-------
                            Galbraith Laboratories, Inc.
                                        Accuracy with Speed - Since 1950

                                     LABORATORY  REPORT
David Alburty
Midwest Research Institute
                          Report Date:
                          Lab I.D.:
                                 01/08/99
                                 Z-4375-94
SAMPLE ID   LAB ID
ANALYSIS
   As
Received
Dry
Method
11002C Z-4385-86 Selenium
Silver
Sodium
Vanadium
Zinc
<9
<9
<1
<1
140
120
<5
<5
51
25
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
<10
<10
<1
<1
160
120
<5
<5
55
27
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
                                This report shall not be reproduced, except in full, without the written approval of the laboratory.
                                                           Page 18 of 28
                              U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
                          Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
             Tel: 423/546-1335 •  Fax: 423/546-7209 • Internet: www.galbraith.com • e-mail: labinfo@galbraith.com

                                           APPENDIX  C
                                                                                     94

-------
              Galbraith  Laboratories, Inc.
&_*^AI LABORATORY REPORT
fS^f^jSS^M Accuracy with Speed - Since 1 950
David Alburty Report Date:
Midwest Research Institute
SAMPLE ID LAB H) ANALYSIS
11003B Z-4387-88 Moisture

Carbon

Hydrogen

Nitrogen

Sulfur

Ash

Chlorine

Fluorine

Bromine

Iodine

Oxygen (by diff)

HHV

Lab I.D.:
As
Received
10.71 %
12.86 %
59.47 %
59.32 %
8.27 %
8.32 %
4.62 %
4.65 %
0.14 %
0.15 %
0.11 %
0.08 %
<88 ppm
<95 ppm
17 ppm
16 ppm
<88 ppm
<95 ppm
6 ppm
3 ppm
16.91 %
16.99 %
11716 Btu/lb
11392 Btu/lb

Dry


67.41
67.25
7:89
7.95
5.24
5.27
0.16
0.17
0.12
0.09
<100
<110
19
18
<100
<110
6
3
19.17
19.26
13281
12914
01/08/99
Z-4375-94
I! Method
ASTMD-5142

% ASTM D-5373
%
% ASTM D-5373
%
% ASTM D-5373
%
% ASTM D-4239
%
% ASTMD-5142
%
ppm EPA SW-846
ppm 5050/9056
ppm ASTMD-3761
ppm
ppm EPA SW-846
ppm 5050/9056
ppm ASTM D-3869
ppm
% ASTM D-3 176
%
Btu/lb ASTM D- 1989
Btu/lb
                   This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 19 of 28
                U. S. Mail: P, O. Box 51610 • Knoxville, TN 37950-1610
             Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 • Internet: www.galbraith.com • e-mail: labinfo@galbraith.com


                             APPENDIX C
                                                                     95

-------
               Galbraith  Laboratories,  Inc.
^L^^mM LABORATORY REPORT"
•5*;i~_"5^H Accuracy with Speed - Since 1 950
•*TiU:l:n77T^B
David Alburty Report Date:
Midwest Research Institute Lab I.D.:
I SAMPLE ID LAB ID ANALYSIS
11003B Z-4387-88 Aluminum
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
As
Received
6
6
<7
<7
<7
<7
<5
<4
<5
<4
<5
<4
<5
<4
6
6
<7
<7
5
<5
<5
<4
<0.047
<0.048
<0.046
<0.048
<0.047
<0.046
<5
<4
<7
<7

ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Dry
7
7
<8
<7
<8
<7
<5
<5
<5
<5
<5
<5
<5
<5
7
7
<8
<7
5
<5
<5
<5
<0.053
<0.053
<0.052
<0.054
<0.053
<0.052
<5
<5
<8
<7
01/08/99
Z-4375-94

ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Ppm
Ppm
Ppm
ppm
ppm
ppm
Ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Ppm
Ppm
ppm
ppm
ppm
ppm
Ppm
1 Method
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
                   This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 20 of 28
                U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
             Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 • Internet: www.galbraith.com • e-mail: labinfo@galbraith.com

                              APPENDIX C
                                                                       96

-------
              Galbraith  Laboratories, Inc.
^t_*^^H LABORATORY REPORT
•?Trr7!SJ Accuracy with Speecf- Since 1 950
David Alburty Report Date:
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS
11004B Z-4389-90 Moisture

Carbon

Hydrogen

Nitrogen

Sulfur

Ash

Chlorine

Fluorine

Bromine

Iodine

Oxygen (by diff)

HHV

Lab I.D.:
As
Received
9.73 %
11.49 %
57.63 %
57.50 %
8.32 %
8.28 %
4.87 %
4.84 %
0.21 %
0.21 %
0.12 %
0.08 %
530 ppm
260 ppm
<9 ppm
36 ppm
<93 ppm
<93 ppm
3 ppm
4 ppm
19.36 %
19.63 %
11116 Btu/lb
11008 Btu/lb
01/08/99

Z-4375-94
Dry


64.47
64.32
7.99
7.94
5.45
5.42
0.24
0.24
0.13
0.09
590
290
<10
41
<100
<100
3
4
21.66
21.96
12435
12315



/O
/O
/O
/O
%
%
p/
%
o/
%
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb
I! Method
ASTMD-5142

ASTM D-5373

ASTM D-5373

ASTM D-5373

ASTM D-4239

ASTMD-5142

EPA SW-846
5050/9056
ASTMD-3761

EPA SW-846
5050/9056
ASTM D-3869

ASTM D-3 176

ASTM D- 1989

                   This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 22 of 28
                U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
             Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 • Internet: www.galbraith.com «  e-mail: labinfo@galbraith.com

                             APPENDIX C
                                                                     98

-------
                            Galbraith  Laboratories, Inc.
                                        Accuracy with Speed - Since 1950

                                    LABORATORY REPORT
David Alburty
Midwest Research Institute
                          Report Date:
                          Lab I.D.:
                                  01/08/99
                                  Z-4375-94
SAMPLE ID   LAB ID
ANALYSIS
   As
Received
Dry
Method
11003B Z-4387-88 Selenium
Silver
Sodium
Vanadium
Zinc
<7
<7
<1
<1
130
120
<5
<4
<5
<4
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
<8
<7
<1
<1
150
130
<5
<5
<5
<5
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
                                This report shall not be reproduced, except in full, without the wntten approval of the laboratory.
                                                           Page 21 of 28
                             U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
            TPI- a^/^K i«= °'herCarriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
            Tel. 423/546-1335 • Fax: 423/546-7209 • Internet: www.galbraith.com .  e-mail: labinfo@galbraith.com

                                          APPENDIX  C
                                                                                    97

-------
                           Galbraith  Laboratories, Inc.
                                    LABORATORY  REPORT
                                       Accuracy with Speed - Since 1
                  1950
David Alburty
Midwest Research Institute
          Report Date:
          Lab I.D.:
           01/08/99
           Z-4375-94
SAMPLE ED   LAB ED
                          ANALYSIS
   As
Received
Dry
Method
11004B Z-4389-90 Selenium
Silver
Sodium
Vanadium
Zinc
<7
<6
<1
<1
130
140
<4
<4
7
7
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
<8
<7
<1
<1
141
151
<5
<4
8
8
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
                  This report shall not be reproduced, except In full, without the written approval of the laboratory.
                                 Page 24 of 28
                             U. S. Mail: P. O. Box 51610 « Knoxville, TN 37950-1610
                          Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
             Tel: 423/546-1335 • Fax: 423/546-7209 • Internet: www.galbraith.com • e-mail: labinfo@galbraith.com
                                           APPENDIX  C
                                                                                    100

-------
               Galbraith Laboratories, Inc.
BSt^C355^B Accuracy with Speed - Since 1 950
•HHafiSB LABORATORY REPORT
David Alburty Report Date:
Midwest Research Institute
I SAMPLE ID LAB ID ANALYSIS
I
11004B Z-43 89-90 Aluminum

Antimony

Arsenic

Beryllium

Cadmium

Chromium

Copper

Iron

Lead

Magnesium

Manganese

Mercury





Nickel

Potassium


As
Received
7
7
<7
<6
<7
<6
<4
<4
<4
<4
<4
<4
<4
<4
9
10
<7
<6
7
9
<4
<4
O.045
<0.043
<0.046
<0.046
<0.046
<0.046
<4
<4
7
6
Lab I.D.:


ppm
ppm
ppm
ppm
ppm
ppm
PPm
ppm
ppm
PPm
ppm
ppm
PPm
ppm
ppm
ppm
PPm
ppm
ppm
ppm
PPm
PPm
ppm
ppm
PPm
ppm
ppm
PPm
ppm
PPm
PPm
ppm
01/08/99

Z-4375-94
Dry

8
8
<8
<7
<8
<7
<5
<4
<5
<4
<5
<4
<5
<4
10
12
<8
<7
8
11
<5
<4
<0.050
<0.048
O.052
<0.052
<0.052
<0.052
<5
<4
8
7


ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
PPm
ppm
ppm
ppm
ppm
ppm
PPm
ppm
ppm
PPm
PPm
PPm
ppm
ppm
PPm
ppm
ppm
PPm
Method

EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471




EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
                 This report shall not be reproduced, except in full, without the written approval of the laboratory.
                                                          Page 23 of 28
Tel: 423/546-1335
   U. S. Mail: P. O. Box 51610 » Knoxville, TN 37950-1610
Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
« Fax: 423/546-7209 • Internet: www.galbraith.com « e-mail: labinfo@galbraith.com
                             APPENDIX C

-------
              Galbraith  Laboratories, Inc.
A^^^M LABORATORY REPORT
•CSTTTTTTrS^B Accuracy with Speed - Since 1 950
^^^^^^^Q2V"MJ£fj^^^^^^l
David Alburty Report Date:
Midwest Research Institute
SAMPLE ID LAB ID ANALYSIS

10001B Z-4391-92 Aluminum

Antimony

Arsenic

Beryllium

Cadmium

Chromium

Copper

Iron

Lead

Magnesium

Manganese

Mercury


Nickel

Potassium


As
Received
13
13
<7
<7
<7
<7
<5
<4
<5
<4
150
160
130
140
19
19
<7
<7
44
41
<5
<4
<0.045
O.046
<0.046
26
28
220
240
Lab I.D.:


ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
01/08/99

Z-4375-94
Dry

13
14
<8
<8
<8
<8
<5
<5
<5
<5
160
160
140
140
20
20
<8
<8
46
43
<5
<5
(d) <0.048
<0.048
<0.048
27
29
240
260


ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
Method

EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
EPA SW-846
7471

EPA SW-846
3050B/6010
EPA SW-846
3050B/6010
                   This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 26 of 28
                U. S. Mail: P. O. Box 51610 « Knoxville, TN 37950-1610
             Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
Tel: 423/546-1335 • Fax: 423/546-7209 • Internet: www.galbraith.com « e-mail: labinfo@galbraith.com

                             APPENDIX C
                                                                    1O2

-------
               Galbraith  Laboratories, Inc.


                        LABORATORY REPORT  „
                          Accuracy with Speea - Since 1950
David Alburty
Midwest Research Institute
SAMPLE DD LAB ID ANALYSIS
1000 IB Z-4391-92 Moisture
Carbon
Hydrogen
Nitrogen
Sulfur
Ash
Chlorine
Fluorine
Bromine
Iodine
Oxygen (by diff)
HHV

As
Received
5.42
4.16
44.65
44.54
6.58
6.45
<0.48
<0.48
0.15
0.10
2.51
2.65
34.70
34.57
140
120
<96
<96
11
9
37.90
38.06
9727
9251
Report Date:
Lab I.D.:

%
%
%
%
%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb

Dry

46.90
46.78
6.35
6.22
<0.50
<0.50
0.16
0.11
2.64
2.78
36.44
36.31
150
130
<100
<100
12
9
39.81
39.98
10216
9716
01/08/99
Z-4375-94


%
%
%
%
%
%
%
%
%
%
%
%
ppm
ppm
ppm
ppm
ppm
ppm
%
%
Btu/lb
Btu/lb

Method
ASTMD-5142
ASTM D-5373
ASTM D-5373
ASTM D-5373
ASTM D-4239
ASTMD-5142
EPA SW-846
9253
ASTM D-3761
EPA SW-846
5050/9056
ASTM D-3869
ASTM D-3 176
ASTMD-1989
                   This report shall not be reproduced, except in full, without the written approval of the laboratory.
Page 25 of 28
            nth UrS'Mail: R0- Box 51610 » Knoxville, TN 37950-1610



Tel: 423/546-1335 .^.C^^S^tTO>r8DrlVe ' Kn°XVille-TN ^ 175°
              rax. 423/546-7209 . Internet: www.galbraith.com . e-mail: labinfo@galbraith.com





                             APPENDIX C
                                                                    101

-------
                                 Galbraith  Laboratories, Inc.
                                            LABORATORY REPORT
                                               Accuracy with Speed - Since 1
                                                 iCcuracy with Speed - Since 1950


David Alburty                                                   Report Date:                  01/08/98
Midwest Research Institute                                        Labl.D.:                     Z-4375-92


                                             Preparation Confirmation

As requested, Lab ID#'s Z-4375-92 were refrigerated prior to analysis. The samples were also dried and ground, unless otherwise noted,
prior to analysis to provide a more homogeneous sample for testing.


                                                        Note

The original Chain of Custody form is included with the mailed report.

                                                   Technical Note

(a) As we discussed, Lab ID#s Z-4377-78 (Sample 10002A) were analysed in duplicate due to stannous chloride contamination of Lab ID#
Z-4393-94 (Sample 10002B) prior to grinding.

*' As we discussed, these ash results exhibit a potential high bias due to the high levels of zinc and nickel in the sample. During the ashinig
of the sample metal oxides form which result in high ash values. This also effects the oxygen result since it is a calculated value.

(c) The antimony replicate for this sample seems out of line with the sample trend; however, the concentration was confirmed on two
wavelengths.

(d) The digested solutions for this sample were diluted prior to analysis for mercury due to interferences in other samples in the set. This
results in elevated quantitation limits for mercury in this sample. The aliquots used for the mercury determination was taken from the field
duplicate (Sample 10001 A, Lab ID #Z-4375-76) due to the insufficient sample remaining on Sample 10001B.

w Our original laboratory report was sent without the appropriate less than symbolism for the nitrogen results. We apologize for any
inconvenience our error may have caused.

m The original laboratory report indicated potassium results of 0.67% (as received) and 0.76% (on dry). The correct values have been
included in this report.  We apologize for any inconvenience this error may have caused.

^ The original laboratory report indicated ppm units on these results. The correct units are % as reflected in this report. We apologize for
any inconvenience this error may have caused.
PAC:yd                                TWs report shall not be reproduced, except in full, wilhout the written approval of the laboratory.             Page 28 of 28
                                   U. S. Mail: P. O. Box 51610 « Knoxville, TN 37950-1610
                               Other Carriers: 2323 Sycamore Drive • Knoxville, TN  37921-1750
               Tel: 423/546-1335  » Fax: 423/546-7209 « Internet:  www.galbraith.com  • e-mail: labinfo@galbraith.com

                                                    APPENDIX  C                                  1O4

-------
                            Galbraith  Laboratories, Inc
                                        Accuracy with Speed - Since 1950

                                     LABORATORY REPORT
David Alburty
Midwest Research Institute
                                       Report Date:
                                       Lab I.D.:
                                                  01/08/99
                                                  Z-4375-94
SAMPLE ID   LAB ED
             ANALYSIS
                   As
                Received
                      Dry
                                                                       Method
10001B
Z-4391-92
Selenium
<7
<7
                                                       ppm
                                                       PPm
<8
<8
ppm
PPm
EPA SW-846
3050B/6010
                           Silver
                                                       ppm
                                                       PPm
                                                               ppm
                                                               PPm
                                                           EPA SW-846
                                                           3050B/6010
                           Sodium
                             450
                             450
                                                       ppm
                                                       ppm
                                        480
                                        480
                                  ppm
                                  ppm
                   EPA SW-846
                   3050B/6010
                           Vanadium
                             <5
                             <4
                                                       ppm
                                                       ppm
                                        <5
                                        <5
                                  ppm
                                  PPm
                   EPA SW-846
                   3050B/6010
                           Zinc
                             320
                             250
                                                       ppm
                                                       ppm
                                        340
                                        260
                                  ppm
                                  ppm
                   EPA SW-846
                   3050B/6010
                                This report shall not be reproduced, except in full, without the written approval of the laboratory.
                                                                         Page 27 of 28
                              U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
                           Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
             Tel: 423/546-1335 • Fax: 423/546-7209 • Internet: www.galbraith.com • e-mail: labinfo@galbraith.com
                                            A DDCMftT V  I"!

-------
                              Galbraith  Laboratories, Inc
                                           Accuracy with Speed - Since 1950


                                        LABORATORY REPORT
David Alburty                                               Report Date:                1/13/99
Midwest Research Institute                                    Lab I.D.:                   A-5601
                                             Technical Notes



As requested, Sample ID#11001A was refrigerated at 4°C prior to analysis.

Analysis was performed on the dried and ground sample.

One replicate of the original sample appears to have been contaminated with silver during preparation. These results indicate the
absence of silver in the sample.  There is no charge for this repeat analysis.
PAClSmC                            This report shall not be reproduced, except in full, without the written approval of the laboratory.              Page 2 01 2
                               U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
                            Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
              Tel: 423/546-1335 » Fax: 423/546-7209 • Internet: www.galbraith.com • e-mail: labinfo@galbraith.com

                                               APPENDIX C                              1O6

-------
                         Galbraith  Laboratories,  Inc.
                                      Accuracy with Speed - Since 1950
                                LABORATORY REPORT
David Alburty
Midwest Research Institute
425 Volker Blvd
Kansas City MO 64110-2299
                            Additional Request:
                            Previous Lab I.D.:
                            Report Date:
                            Fax Number:
      1/11/99
      A-4361
      01/13/99
      816-531-0315
 SAMPLE ID
LAB ID   ANALYSIS
RESULT(S)
 11001A Add
A-5601    Silver
<  2
<  2
                                                                              ppm
                                                                              ppm
      C9
                            This report shall not be reproduced, except in full, without the written approval of the laboratory.

                           U. S. Mail: P. O. Box 51610 • Knoxville, TN 37950-1610
                       Other Carriers: 2323 Sycamore Drive • Knoxville, TN 37921-1750
          lei: 423/546-1335 • Fax: 423/546-7209 . Internet: www.galbraith.com • e-mail: labinfo@galbraith.com
                                         APPENDIX  C
                                                                                  105

-------
              Reference Material Result (% of Value)
Applicable to Samples
Z-391 7 through Z-3928
Z-5356 through Z-5367
Z-3474 through Z-3479

Z-3479, Z-3474, Z-3277
Z-5069, Z-5070
Z-3778 through Z-3787
Z-4550 through Z-4553
Z-4375 through Z-4394
HHV
100%
100%
100%
102%
100%
100%

100%
100%
Ash
101%
100%
95%

95%
101%

101%
100%
Viscosity SpGr






16.63/(?)% 100%


Applicable to Samples
                     Matrix Spikes for Halides
Bromine    Chlorine  Fluorine   Iodine
Z-3917 through Z-3928
Z-5356 through Z-5367
Z-3474 through Z-3479
Z-3479, Z-3474, Z-3277
Z-5069, Z-5070
Z-3778 through Z-3787
Z-4550 through Z-4553
Z-4375 through Z-4394
  89%
  89%
  94%
23%
80%
85%
                        Controls for Halides
Applicable to Samples
Bromine    Chlorine  Fluorine   Iodine
Z-391 7 through
Z-5356 through
Z-3474 through
Z-3479, Z-3474
Z-5069, Z-5070
Z-3778 through
Z-3782, Z-3783
Z-4550 through
Z-4375 through
Z-4376
A-2183, A-2186
A-4365
Z-3928
Z-5367
Z-3479
, Z-3277

Z-3787

Z-4553
Z-4394

, A-4201 - A-4207

75%
82%
83%

82%
>70%
53%
82%
87%
18%


62-92%
101%
93%
95%
101%
>70%

79%
>70%


82%

98-104%
101%
102%
96%
96%

96%
96%

96%
101%

280%

274%
276%
274%

276%
274%

274%

                                          APPENDIX C
                                                      1O8

-------
                                                                   Controls for Metals
          Applicable to Samples
        Ag    Al    As   Be   Cd   Cr   Cu    Fe    Hg   K   Mg   Mn   Na
                                                         Ni
                                                         Pb   Sb   Se
                                              Zn
          Z-3917 through Z-3928
          Z-5356 through Z-5367
          Z-3474 through Z-3479
          Z-3479, Z-3474, Z-3277
          Z-5069, Z-5070
          Z-3778 through Z-3787
          Z-4550 through Z-4553
          Z-4375 through Z-4394
          A-2183, A-2186, A-4201
          A-5601
          A-4365
        97% 101%  99%  99%  99%  99% 101% 102%           100% 101% 100% 100% 100%  99%  99%  99%  98%
        94%  97% 101%  98%  99%  98%  98%  91% 107%  91%  95%  95% 498% 95%  97%  97%  96%  95%  94%
        94%  97% 101%  98%  99%  98%  98%  91%  99%  92%  95%  95% 100% 95%  97%  97%  96%  95%  94%

                                                  83%
        97% 101%  99%  99%  99%  99% 101%  99% 103% 100% 100% 101% 100% 100% 100%  99%  99%  99%  98%
             99%  97%  98%  98%  98% 100%  98%  98%  96% 100%  99%  99% 99%  99% 100%  98%  98%  98%
        97%  99%  97%  98%  98%  98% 100%      101%  96% 100%  99%  99% 99%  99% 100%  98%  98%  98%
•A-4207 104%  98%  99%  97%  99%  96%  97%  94% 100%  98%  93%  97% 101% 96% 100%  98%  99%  95%  97%
        80%
                                                                                      94%
•o
TJ
m
z
o
M
X
o
                                                                 Matrix Spikes for Metals
          Applicable to Samples
        Ag    Al
As
Be   Cd    Cr    Cu   Fe   Hg'
K
Mg   Mn   Na
Ni
Pb   Sb   Se
Zn
Z-391 7 through Z-3928 (MS)
Z-391 7 through Z-3928 (MSD)
RPD
Z-5356 through Z-5367
Z-3474 through Z-3479
Z-3479, Z-3474, Z-3277
Z-5069, Z-5070
Z-3778 through Z-3787
Z-4550 through Z-4553 (MS)
Z-4550 through Z-4553 (MSD)
RPD
81%
82%
1%








18%
43%
81%





74%
78%
5%
91%
97%
6%





90%
92%
2%
90%
92%
2%





88%
89%
1%
78%
79%
1%





87%
88%
1%
86%
88%
2%





89%
90%
1%
94%
98%
5%





94%
95%
1%








88%
105%
18%
104%
109%
5%
109%
102%
103%
110%

102%


91%
94%
2%





90%
92%
2%








90%
110%
20%
88%
89%
1%





90%
92%
2%
89%
90%
2%





89%
89%
0%
77% 94%
77% 96%
1% 3%





83% 92%
88% 94%
6% 2%
89% 85%
92% 93%
3% 9%





86% 104%
88% 101%
2% 3%
          Z-4375 through Z-4394
                                                                               109%
                                     ' Multiple spikes were performed for Hg, did not show all here.

-------
                                       Appendix D
                             MRI Analysis Reports
MRJ-AEDW951 -01 -02-OSTR. wpd

-------
                                     Appendix D-1
                                  Organic Analysis
                                 (Ds/Fs and PAHs)
MRl-A£DV4951-01-02-05TR.wpd

-------
To: John Hosenfeld
From: Kathy Boggess
Subject: EMC Alternative Boiler Fuel Sludge Samples

This memo contains a brief description of the sample preparation procedures and the results of the two
sludge samples (prepared in duplicate) submitted for PAH and dioxin and furan analysis.  The sample IDS
are 1005 and 1006.

PAHs

The samples were a dark brown viscous material that were un pourable at room temperature. With
warming, the samples were liquefied enough to aliquot with a disposable serological pipet. At this point,
the material was stringy, must like a thick molasses material. The analyst attempted to weigh a Ig aliquot
of each sample in duplicate into a 40-mL vial. In some cases, the sample size was closer to 2 g.

The 1-g samples were fortified with 25-ug dlo fluorene and dlo pryene as surrogates to assess the affect of
the matrix on cleanup and GC/MS analysis.  Other quality control samples included a solvent only method
blank, a com oil laboratory control blank and a com oil laboratory control spiked sample fortified with 5 ug
of the target PAHs.

 The ~ 1 g samples and QC samples were diluted with methylene chloride and put through size exclusion
gel permeation chromatography (GPC) cleanup using a column packed with SX-3 biobeads. The system
was calibrated with com oil and a standard mixture containing a phthalate, methoxychlor, perylene, and
sulfur. The collect fraction was set to isolate the PAHs from the  com oil calibration standard.  A UV
detector was interfaced to the automated GPC cleanup to monitor response for potential interferences
during collection of the fraction designated for analysis.  The UV trace indicated incomplete removal of the
matrix.  The molecular weight of the major contaminants were lighter than the com oil used for calibration
of the instrument, and the  UV showed that these interferences overlapped  in the same fraction as the target
analytes. Therefore, a serial GPC cleanup was performed to reduce the oil interferences.   The GPC
cleanup removed the dark color of the samples, and the final extracts were a light amber color.  The
dilution factor of the extracts for GC/MS analysis was 10 mL methylene chloride for each 1 g sample.

The sample extracts and quality control samples were analyzed according to modifications of EPA Method
8270. The modifications included a lower calibration range than required by the method and the use of
dueterium labeled PAHs as surrogates.  The  internal standard recommended in EPA Method 8270 was
added to a 1.0 mL aliquot of the extracts just before analysis.

Results

None of the samples contained PAHs above  instrumental reporting limit based on the lowest calibration
standard (0.1 ug/mL). The sample detection limit was 4 ug g/g based  on the sample size and dilution
factor.  Table 1 summarizes the target PAHs and sample results.

The quality control results were within the acceptable limits.  The two surrogates recovered within the 60 to
120% recovery objective as shown in Table 2. Recoveries of the native PAHs from the com oil laboratory
control sample, which was subjected to the same GPC cleanup, and analysis are shown in Table 3.
Recoveries were good with the exception of the latest eluting compound,  benzo (g,h,i) perylene.

-------
Table 1. PAH Sample Results (ug/g)
PAH
1005
1006   1006 dup
Nitrobenzene
Naphthalene
Acenaphthylene
Acenapthene
Flourene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benz(a) anthracene
Chrysene
Benzo(b) fluoranthene
Benzo (k) fluoranthene
Benzo (e) pyrene
Indeno (1,2,3-cd) pyrene
Dibenz (a,h) anthracene
Benzo (g,h,I) perylene
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
ND<4
Table 2. Surrogate Recoveries %
Sample
Solvent Blank
Com Oil Method Blank
Com Oil LCS
1005
1005 dup
1006
1006 dup
dlO Fluorene
90
62
90
103
96
105
105







dlO Pvrene
68
64
73
78
68
77
73







Table 3. Com oil LCS Recoveries
PAH
Nitrobenzene
Naphthalene
Acenaphthylene
Acenapthene
Flourene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benz(a) anthracene
Chrysene
Benzo(b) fluoranthene
Benzo (k) fluoranthene
Benzo (e) pyrene
Benzo (a) pyrene
Indeno (1,2,3-cd) pyrene
Dibenz (a,h) anthracene
Benzo (g,h,I) perylene



















Spike Level ug
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5



















% Recovery
100
93.8
104
101
100
96.8
97.4
78.6
76
76
78.2
80
69.6
74.4
75.8
64.8
64.2
45.6
                                       APPENDIX  D-T

-------
PCDDs/PCDFs

The PCDD and PCDF analyses were performed according to EPA Method 8290.  Initially a 10 g sample
size was spiked with the 13C12 PCDDs/PCDFs IQS , diluted in hexane and put through an acidified silica
slurry cleanup procedure.  This oily matrix overloaded the silica cleanup, requiring the addition of more
acid silica. Then the samples were processed through carbon  and neutral alumina cleanup as described in
Method 8290 and analyzed by HRGC/HRMS. Preliminary results indicated low recovery for the lower
chorinated 13C12 IQS. Therefore the preparation was repeated with I g sample size to reduce the matrix
effect on the cleanup procedures.

Results

The results from the repeated analysis will be available on Wednesday. Mark Davis will forward tables to
you. If you are interested in the results from the JO g sample as well, the data have been put in the 4951
project folder on the network.
                                          APPFNDTX  o-i

-------
                                  PCDD/F Narrative


                 MIDWEST RESEARCH INSTITUTE
                                 November 25, 1998


To: John Hosenfeld

From: Mark Davis

Subject: Analysis Narrative for EMC Pine Tar Samples

Sample Preparation
       Samples were heated and weighed out in duplicate in two weight groups (10 grams and 1
gram) for dioxin/furan analysis. A mineral oil method blank (MB), a mineral oil laboratory
control sample (LCS), and a solvent blank were also prepared for both weight groups. All
samples were fortified with appropriate quantitation standards.  The 1 -gram samples were
archived (to be used if the matrix of the 10-gram samples proved to be too difficult). The ten
gram samples were diluted in hexane, fortified with 37C1-2378 TCDD clean-up standard and
subjected to a 2 hour acid silica slurry step (40% H2SO4 on silica gel) followed  by a acid/neutral
silica column.  Heavy reactions with both the slurry and column steps were noted.  The extract
was then concentrated for carbon column clean up.  It was discovered that mineral oil used for
the MB and LCS was not sufficiently cleaned in the silica steps and would not successfully go
through the rest of the clean-up procedures. The MB and the LCS  were re-prepared using com
oil for both weight groups. The solvent blank originally  started with the samples remained the
same. The re-prepared LCS and Method Blank were put through the same silica steps and
continued through a .5 gram 18% Carbopack C carbon column, and a neutral alumina column
with the rest of the samples. All samples were concentrated under prepurified nitrogen to
approximately 100 uL. 20 uL of recovery standard was added  and evaporation continued to a
final volume of 20 uL.  All procedures are documented in detail in SOP MRI-5201 revision 1.
       After analysis of the 10-gram sample, it was decided that the 1-gram samples should be
analyzed to reduce matrix effects.  The 1 - gram samples were prepared with the corn oil MB and
LCS in the same manner discussed above.

Sample Analysis
       Analysis was performed on the VG70-250s mass spectrometer at 10,000 resolution
interfaced with a HP5890 gas chromatograph. A 60m DB-5ms (0.25mm ID, 0.25um film) fused
silica capillary column was used for chromatographic separation. The samples  were analyzed
following the requirements in SOP MPJ-5405 USEPA Method 8290.  An initial calibration of 5
points ranging from 0.5-200pg/uL, and an ending standard were run in the analytical sequence.
The initial and daily calibrations, instrument resolution and GC column performance met the
criteria specified in the SOP. Analysis records of performance and raw data have been included
in the data package.

Data Reduction
       The data was reduced using the Excalibur 2.1 program. The initial calibration was used to
generate relative response factors for sample quantitation. USEPA Method 8290 quantitation was
followed to quantitate native concentrations with one exception. After looking over the sample
raw data, it was noticed that the 13C-123789HxCDF recovered extremely well. In method 8290,
this is not the labeled analog used for native quantitation. A deviation from the method was
performed to quantitate the native 123789HxCDF from its own labeled analog  which gave much
better results for that isomer.  The initial calibration curve was  re-generated to produce the new
                                      APPENDIX 0-1

-------
response factor. Excaiibur output files and a spreadsheet showing final concentrations has been
included in the data package.
       The one gram sample data is a better data set due to the significantly better labeled analog
recovery.  Both data sets for 10 and 1 gram samples are included.
                                        APPENDIX D-1

-------
                                                                Table 1. Native Results for 1 gram Samples (pg/g)
 •o
 •o
,n
z
0
H
X
Isomer
2378TCDD
12378PECDD
123478HXCDD
123678HXCDD
123789HXCDD
1234678HPCDD
123467890CDD
2378TCDF(a)
12378PECDF
23478PECDF
123478HXCDF
123678HXCDF
234678HXCDF
123789HXCDF
1234678HPCDF
1234789HPCDF
123467890CDF
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Field ID corn oil
Extract ID 41040
MS File K24V12RPT
Matrix Method Blank
U( 3.57)
U( 3.95)
U( 3.92)
U( 3.76)
U( 3.63)
11.3
115
U(2.16)
U(2.5)
U(2.1)
U( 3.62)
5.26
U(4.21)
U( 9.68 EMPC)
5.51
U( 5.02 EMPC)
14.9
U( 3.57)
U( 2.42)
U( 3 77)
18.3
U(2.16)
U( 2.27)
5.4
9.71
None
41039
K24V18.RPT
Solvent Blank
U( 2.54)
U( 4.02)
U(2.91)
U{ 2.78)
U( 2.69)
U( 6.06 EMPC)
51.3
U(1.75)
U( 1.88)
U(1.59)
U(1.12)
U(2.11 EMPC)
U( 1.7 EMPC)
U( 5.82 EMPC)
U(1.51)
U( 1.67)
5.66
U( 2.54)
U( 1.86)
U( 2.79)
63
U( 1.75)
U(1.71)
U(1.11)
U( .74)
1005 A
41035
K24V14.RPT
oil
U(8.13)
U( 18.3)
U( 24.9 EMPC)
U( 24 EMPC)
72.4 (J)
632
4430
U(812)
U(5.18)
U(4.37)
U( 10.7)
U(104)
U( 24 EMPC)
4.31
10.8
U( 5.04 )
9.28
U(813)
U(11.5)
118(J)
989
U(8.12)
U(4.7)
49.5
17.2
1005ADup
41036
K24V15.RPT
oil
U( 5.43JJ
U( 6.94)J
U( 8.43)
U( 15 3 EMPC)
30.7
639
4600
U( 8.44JJ
U( 3.87)
U( 3.26)
l)( 3.8)
U(4.19)
U( 8 96 EMPC)
U( 7.02 EMPC)
10.5
U(311)
13
U(5.43)
U( 3.53)J
31.9
1080
U( 8.44)J
U( 3.52)
U( 3.77)
11
1006A
41037
K24V16.RPT
oil
U( 2.02)
U( 4.2)
U( 4.73 EMPC)
14.4
U( 25.7 EMPC)
610
4430
U( 2.24)
U{1.43)
U(1.21)
U( 3.28)
U(3.17)
U( 3.49)
5.49
8.21
U{ 5.47 EMPC)
667
U( 2.02)
U( 2.37)
56.3
1030
U( 2.24)
U(1.3)
5.49
14.3
1006ADup
41038
K24V17.RPT
oil
U(1.67)
U( 3.04)
U( 4.07 EMPC)
11.9
U( 12.9 EMPC)
614
4480
U( .906)
U(1.34)
U(1.13)
U( .894)
U( 1.33 EMPC)
3.24
3.79
5.36
U( .949)
9.13
U(1.67)
U(1.57)
51.5
995
U( .906)
U(1.22)
7.5
11.6
                                                        U - Undetected at the noise based detection limit
                                                        EMPC - A peak was detected that did not meet the identification criteria.
                                                         The peak areas were used to calculate an Estimated Maximum
                                                         Possible Concentration for the detection limit
                                                        J • Corresponding labeled analog outside of the MRI criteria of 25-150%.
                                                        a - Concentrations for this isomer should be consider a maximum.
                                                         The GC column used is not specific for this isomer.

-------
                               Table 2. Labeled Analog Results 1 gram Samples (%)
Labeled Analog
C13 2,3,7,8-Substituted
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,6,7,8-HxCDD
1,2,3,4.6,7,8-HpCDD
1,2,3,4.6,7,8,9-OCDD
C1 3 2,3,7,8-Substituted
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3.7,8,9-HxCDF
1.2,3,4,6,7,8-HpCDF
Method
Blank
Dioxins
58.2
55.6
82
86.2
82.6
Furans
63.8
63.2
78.8
85.1
99.1
Solvent
Blank

68.3
67.7
94.1
112
121

65.3
88.4
100
121
124
1005A

10.5(J)
7.16(J)
10.1(J)
62.2
94.4

5.76(J)
15.6(J)
9.78(J)
95.6
53.8
1005ADup

33.1
22.6(J)
33.3
96.9
96.1

17(J)
45.5
33.5
96.7
101
1006A 1006ADup LCS

61
41.5
37.9
94.3
93.8

34.4
68.4
34.3
104
90

75.4
66.4
74.9
110
104

70.3
85.9
80.2
113
99.9

69
60.5
89.7
95.2
93.6

69
66.6
83.4
95.1
108
Average

53.6
45.9
60.3
93.8
97.9

46.5
61.9
60.0
101
96.5
Standard
Deviation

23.4
23.3
32.8
16.6
11.9

27.1
25.0
33.6
12.2
21.6
J>
•o

m
z
o
H
X

o
J - Recovery outside MRI criteria of 25-150%.

-------
             Table 4. Laboratory Control Spike Results
Spike Level Field ID LCS Percent
pg/g Extract ID 41041 Recovery
Isomer MS Filename K24V13.RPT
2378TCDD
12378PECDD
123478HXCDD
123678HXCDD
123789HXCDD
1234678HPCDD
12346789OCDD
2378TCDF (a)
12378PECDF
23478PECDF
123478HXCDF
123678HXCDF
234678HXCDF
123789HXCDF
1234678HPCDF
1234789HPCDF
12346789OCDF
200
1000
1000
1000
1000
1000
2000
200
1000
1000
1000
1000
1000
1000
1000
1000
2000
231
1190
1120
975
1100
755
1990
189
1070
1060
1250
1240
1070
978
909
831
1930
116
119
112
97.5
110
75.5
100
94.5
107
106
125
124
107
97.8
90.9
83.1
96.5
a - Concentrations for this isomer should be consider a maximum.
 The GC column used is not specific for this isomer.
                            Page 1

-------
                                                                          Table 1.  Native Results (pg/g)



                                                                                     fO 
-------
          T..ble 2
Analog Recovery (%), 10 Gram Sample
Labeled Analog
13C2378TCDF
13C2378TCDD
13C12378PeCDF
13C12378PeCDD
13C123478HxCDF
13C123789HxCDF
13C123678HxCDD
13C1234678HpCDF
13C1234678HpCDD
13C12346789OCDD
Field ID 1005A
Extract ID 40822
MS File J25VQ18.RPT
9.86 (J)
12.7 (J)
22.1 (J)
8.35 (J)
5.33 (J)
74.7
6.27 (J)
13.5 (J)
24.2 (J)
55.9
1005 A Dup
40823
J25VQ111.RPT
10.7 (J)
11.7 (J)
13.3 (J)
7.97 (J)
5.64 (J)
55.7
7.07 (J)
9.2 (J)
14.9 (J)
21. 3 (J)
1006 A
40824
J25VQ17.RPT
4.78 (J)
6.22 (J)
7.51 (J)
3.87 (J)
2.6 (J)
45.5
3.3 (J)
5.07 (J)
10.3 (J)
15.3 (J)
1006 A Dup
40826
J25VQ110.RPT
2.6 (J)
3.12 (J)
3.45 (J)
1.97(J)
1.19{J)
31.6
1.37 (J)
1.97(J)
4.02 (J)
9.14 (J)
Method Blank
40827
J25VQ16.RPT
72.7
67.3
82.5
61.6
81.4
105
91.9
125
118
127
Solvent Blank
40829
J25VQ15.RPT
33.9
31.2
39.5
30.2
44.2
52.2
44.7
66.5
58.5
63.9
LCS
40828
J25VQ14RPT
74.6
70
78.3
61.7
83.1
96.5
89.3
134
124
126
(J) - Recovery of labeled analog outside MRI criteria of 25-150%.
                         4951Table 2 10g.xls

-------
                                                           Table 2. Labeled Analog Recovery (%)

                                                                   10        Sk,,,^
                                                                          Field 10

                                                                        Extract ID          Standard

                                                    Labeled Analog _ MS File Average Deviation
13C2378TCDF
13C2378TCDD
13C12378PeCDF
13C12378PeCDD
13C123478HxCDF
13C123789HxCDF
13C123678HxCDD
13C1234678HpCDF
13C1234678HpCDD
13C12346789OCDD
53.3
49.3
61.0
45.9
62.8
60.8
68.3
95.8
88.3
82.3
27.4
25.5
30.4
22.2
26.3
25.8
33.4
41.4
42.1
38.9
•o
•o
m
z
o
H
X

-------
Table 4. Laboratory Control Spike Results
                        10  ::-  £
Spike Level Field ID LCS Percent
pg/g Extract ID 40828 Recovery
Isomer MS Filename J25VQ14.RPT
2378TCDD
12378PECDD
123478HXCDD
123678HXCDD
123789HXCDD
1234678HPCDD
12346789OCDD
2378TCDF (a)
12378PECDF
23478PECDF
123478HXCDF
123678HXCDF
234678HXCDF
123789HXCDF
1234678HPCDF
1234789HPCDF
12346789OCDF
20
100
100
100
100
100
200
20
100
100
100
100
100
100 ' -'
100
100
200
22.2
131
110
104
117
79
200
21.1
107
93.7
130
125
112
105
92.8
87.9
181
111
131
110
104
117
79.0
100
106
107
93.7
130
125
112
105
92.8
87.9
90.5
                          0-1
                                                           12

-------
                                       Appendix D-2
                                 Elemental Analysis
MRI-AED\r4951 -01 -02-05TR.wpJ

-------
mwm %*rt* mmWm Mmm           Linking Technology to Solutions
    A Division of Midwest Research Institute
                                                               Materials and Chemistry Laboratory
                                                                        Post Office Box 5808
                                                                   Oak Ridge, Tennessee 37831
                                                                     Telephone: (423) 576-4138
                                                                         Fax: (423) 576-8558
Novembers, 1998
Mr. David Alburty
Midwest Research Institute
425 Volker Boulevard
Kansas City, MO 64110

Dear Dave:

The two samples were analyzed by Scanning Electron Microscopy (SEM) with Energy
Dispersive Spectrometry (EDS) and X-Ray Fluorescence Spectrometry (XRF).  These
techniques allow for observation of samples at high magnifications (over 100,000.x) and
chemical analysis of the samples.  The characterization of these two samples was done on the
as-received samples and on samples that were heated for three hours in a muffle furnace at
825-850°C.

The results of the characterization of the as-received samples by SEM and EDS analysis is
shown in Figures 1 through 7. Figure 1 is a 60x view of the broken surface of sample 11004A.
This area is in the center of the disk and a result of the dimpling when the sample was taken
from the pipe.  The central light area in this secondary  electron image (SEI) view is the
substrate steel and the darker area is the surface coating. EDS analyses of the central area of
Figure 1 and of the darker coating area are shown in Figures 2 and 3, respectively. The
substrate steel contains iron with a very small amount of aluminum (Figure 2). The coating
material contains iron, silicon, carbon, phosphorus, aluminum, zinc, chlorine, potassium,
calcium, titanium, and manganese (Figure 3).  Figure 4 is an SEI view of the  cross-section of
the coating material.  The material is approximately 35 micrometers thick. The upper surface
(the upper portion of Figure 4) is smooth while the inside of the coating  contains a
heterogeneous mixture of particles in the 1 to 8 micrometer size range.  Figure 5 is the EDS  of
the cross-section. Note that the zinc content registers  much higher on the cross-section
analysis than on  the top analysis (Figure 3).  This is  because the electron beam only penetrates
approximately  3 micrometers into the surface of the  material. Figures 6 and  7 are from the top
and bottom half of the cross-section, respectively. These two analyses also  illustrate the
heterogeneous nature of the coating.  The upper portion of the coating is richer in silicon,
carbon, phosphorus, aluminum,  chlorine, potassium, calcium, titanium,  and manganese while
the lower portion is richer in zinc, nickel, and chromium.
                                      APPENDIX  D-2

-------
The XRF was employed to determine the composition of the coating material. The XRF
penetrates into the coating material deeper that the SEM.  Tables 1 and 2 contain the results of
the XRF analyses. The original analyses of these as-received samples included 73 elements
from sodium through uranium.  The final list of the shown in Tables 1 and 2 include those
elements of presence or interest. The coating material is compostionally zinc and iron with
other minor elements present.  The values shown in Tables 1 and 2 are in terms of milligrams
of coating (13millimeter diameter disk) on the sample. These numbers are based on the
loading of elements on thin film standards. The calculated values of mg/cm2 are based on
these milligram values.

The heated samples were also characterized by SEM with EDS and XRF.  After heating, the
samples did not revert to the iron substrate but instead either had a high zinc content brown-
black uneven surface or a blue-black or blue-gray coating with lower zinc content,  but more
than in the original substrate (Figure 2).

Please call me with any questions.

Sincerely,
Dr. Robert J. Stevenson
MCL-MRI

RJS/di
                                    _A_PPp wnT Y  n . ^

-------
Analyses of As-Received Samples, Convex Side
          Table 1 Sample 11003A
Elem
ent
Na
Mg
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Zn
11003A
First Run
(mg)
<1ug
<1ug
0.0542
0.0698
0.0504
<1ug
0.0111
0.0090
0.0040
0.0257
0.0019
0.0402
0.0295
2.6603
0.3946
3.4326
11003A
Second Run
(mg)
<1ug
<1ug
0.0533
0.0664
0.0492
<1ug
0.0111
0.0089
0.0039
0.0254
0.0015
0.0402
0.0305
2.6232
0.3859
3.3816
Average
(mg)
<1ug
<1ug
0.0537
0.0681
0.0498
<1ug
0.0111
0.0090
0.0040
0.0256
0.0017
0.0402
0.0300
2.6417
0.3903
3.4071
Standard
Deviation


0.0006
0.0024
0.0009

0.0000
0.0001
0.0001
0.0002
0.0002
0.0001
0.0008
0.0262
0.0061
0.0361
Average
(mg/cm2)
O.001
<0.001
0.040
0.051
0.038
<0.001
0.008
0.007
0.003
0.019
0.001
0.030
0.023
1.990
0.294
2.567
                APPENDIX D-2

-------
Analyses of As-Received Samples, Convex Side
          Table 2 Sample 11004A
Element
Na
Mg
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Zn
11004A
First Run
(mg)
<1ug
<1ug
0.0535
0.0666
0.0501
<1ug
0.0117
0.0095
0.0041
0.0253
0.0020
0.0401
0.0297
2.7278
0.3473
3.2235
11004A
Second Run
(mg)
<1ug
<1ug
0.0517
0.0628
0.0481
<1ug
0.0116
0.0093
0.0040
0.0254
0.0017
0.0373
0.0297
2.6037
0.3383
3.1164
Average
(mg)
<1ug
<1ug
0.0526
0.0647
0.0491
<1ug
0.0117
0.0094
0.0041
0.0253
0.0018
0.0387
0.0297
2.6657
0.3428
3.1699
Standard
Deviation


0.0013
0.0027
0.0014

0.0001
0.0002
0.0001
0.0001
0.0002
0.0020
0.0000
0.0878
0.0064
0.0757
Average
(mg/cm2)
<0.001
<0.001
0.040
0.049
0.037
<0.001
0.009
0.007
0.003
0.019
0.001
0.029
0.022
2.008
0.258
2.388
               APPENDIX  D-2

-------
Figure 1.  SEI photograph of an area of the center of the convex side of sample 11004A.
                                                                                   MCL-MRI
                                                                           Oak Ridge, Tennessee
                                        APPENDIX  D-2

-------
                                                   Fe
              Fe   Al
          o.o
                      2.0
                                   4.0
                                                6.0
                                                              8.0
                                                                         10.0
                                         keV
Figure 2.  EDS composition of the iron substrate of the convex side of sample 11004A.
          0.0
                                                                         10.0
Figure 3. EDS composition of the coating on the convex side of sample 11004A.
                                                                                 MCL-MRI
                                                                          Oak Ridge, Tennessee
                                       APPENDIX D-2

-------
Figure 4. SEI photograph of a view of the cross-section of the convex side of sample
11004A.
                                                                                   MCL-MRI
                                                                            Oak Ridge, Tennessee
                                        APPENDIX  D-2

-------
          o.o
                                                                         10.0
Figure 5. EDS composition of the of the entire coating of the cross-section of the coating on
the convex side sample 11004A.
                                                   Fe
          0.0
                                                                          10.0
Figure 6. EDS composition of the of the top of the cross-section of the coating on the convex
side sample 11004A..
                                                                                 MCL-MRI
                                                                          Oak Ridge, Tennessee
                                       APPENDIX  D-2

-------
                Zn
          o.o
                                                                           10.0
Figure 7. EDS composition of the of the bottom half of the cross-section of the coating on the
convex side sample 11004A.
                                                                                   MCL-MRI
                                                                           Oak Ridge, Tennessee
                                        APPENDIX D-2

-------
                                           Appendix D-3
                                          Particle Sizing
MRI-AED\r4951 -01 -02-05TR. wjxl

-------
                      MIDWEST RESEARCH INSTITUTE
                               Sieve Analysis'
Date
            * ™
                 MRI Project*.
             Recorded by
Sample ID No.:  toOG^fl:   uP//
Sample wieght:    (p%* 0	
                                       Material:
                                       Number of Splits:
Comments:
Analytical Balance:
Capacity:	
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Smallest Division:   0. f
Date of Last Mfg. Calibration: ^"
Calibration Logbook No.:  ^> t~~~ /
Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.
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                            SIZE DISTRIBUTION
  Screen
               Tare Weight
                 (Screen)
   Final Weight
(Screen + Sample)
Net Weight
 (Sample)
   4 mesh
  10 mesh
                                                     ft.*
  20 mesh
  40 mesh
                                                     /?-/£•
 100 mesh
                                 360.1
 200 mesh
                                 3*3.0
      Pan
*AII unit weights are in grams unless otherwise specified
                                 APPENDIX  D-3

-------
                      MIDWEST RESEARCH INSTITUTE
                               Sieve Analysis*
Date
MRI Project*.
                                         ^T^ecorded
Sample ID No.:
Sample wieght:
                                       Material:
                                       Number of Splits:
Comments:
Analytical Balance:
Capacity:
                                C/— "5
Smallest Division:  v  Q, f
Date of Last Mfg. Calibration: _^
Calibration Logbook No.:^/. -
Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.
Weight (pan only)
386. %
>§v. o
?>VI,0


                            SIZE DISTRIBUTION
  Screen
               Tare Weight
                (Screen)
                 Final Weight
              (Screen + Sample)
Net Weight
 (Sample)
   4 mesh
                                                     04
  10 mesh
  20 mesh
  40 mesh
                                                    K.I
                                                    **•
 100 mesh
                                353.5
 200 mesh
      Pan
*AII unit weights are in grams unless otherwise specified
                                 APPENDIX D-3

-------
                      MIDWEST RESEARCH INSTITUTE
                               Sieve Analysis*
Date
                     Project #
                                        O ^Recorded by
Sample ID No.:
Sample wieght:

Comments:
                 £>£>
                          //?//
                                       Material:
                                       Number of Splits:
Analytical Balance:
Capacity:  4/0 O>.
Smallest Division:   O, /
Date of Last Mfg. Calibration:
Calibration Logbook No.:
                           ~~
Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.
Weight (pan only)
37
-------


Date T^C

Sample ID N
Sample wieg
Comments:


MIDWEST RESEARCH INSTITUTE
Sieve Analysis* ^
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o • tfitf /f faZ^ Material:
ht:  o— <•'< — db>

Capacity: c
tlOO ^~


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Smallest Division: f' '

Date of Last
Calibration L
Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
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Mfq. Calibration: Z_ - Z^f - ^ ^
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Tare Weight
(Screen)
<32--^
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f ^ 5 '_X
¥^. 5"
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10 min.
20 min.
30 min.
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Weight (pan only)
~r*>7-2.?
^j mr^{? * _^^
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ZE DISTRIBUTION
Final Weight
(Screen + Sample)
<35-3>
y0 2- . V-
f ^.2-
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APPENDIX    D-3

-------

Date i " 3(

MIDWEST RESEARCH INSTITUTE
Sieve Analysis*
/7 /  ^~ <'*-^-^>

Capacity:
^(00 ^


Smallest Division: 0, (

Date of Last
Calibration L
Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
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Mfg. Calibration: 2 - 2-°/ "" 9 ^
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(Screen)
5"5x£ . ?
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Wf'1
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2£Z.<20^
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ZE DISTRIBUTION
Final Weight
(Screen + Sample)
5"5?' $
5~3c?< ?
f 2^(e»^>
'fOO, 3
3><6?2-- •?
3f2 . ^
^^ O.C?
Net Weight
(Sample)
/. (
*{$, ?
n.
-------
                       MIDWEST RESEARCH INSTITUTE
                                Sieve Analysis"
Rat*
                 MRI Project*
Recorded by
Sample ID No.: _£
Sample wieght:   fc>3.
Comments:
                                        Material:
                                         Number of Splits:	/_
Analytical Balance:
Capacity: _
                  *?
                   $•!
Smallest Division:	
Date of Last Mfg. Calibration:    2- - iff- 9
Calibration Logbook No.:  <"'L- "I	
Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.
Weight (pan only)
-^^S ff
3>'3-%.cft
<$ 7^, $
^£"S>-3
3 7?--0
%L 8>0
333,0
^^^.^
Final Weight
(Screen + Sample)
573.^
i/f£&33rre? $$
-------
                      MIDWEST RESEARCH INSTITUTE
                               Sieve Analysis*
Date   - 0-
                 MRI Project #
     -0f-0f Recorded by
Sample ID No.:  6 OQ% 4   ffrl)
Sample wieght:  -fy
                                       Material:
                                       Number of Splits:	/[_
Comments:
Analytical Balance:
Capacity:
                           <~)
Smallest Division:   fit f
Date of Last Mfg. Calibration:
Calibration Logbook No.:
                                   $&
                           ~~ /
Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.
Weight (pan only)
*?•?• i? ^f
"? ^fi'%
5 2— P ^


                            SIZE DISTRIBUTION
  Screen
               Tare Weight
                 (Screen)
   Final Weight
(Screen + Sample)
Net Weight
 (Sample)
   4 mesh
              532.
  10 mesh
  20 mesh
                                                                    M.te
  40 mesh
                                                      2..1-
 100 mesh
 200 mesh
      Pan
                                 37-^.5
                      0,1
*AII unit weights are in grams unless otherwise specified
                                 APPENDIX  D-3

-------




Sample ID N
Sample wieg
Comments:



Analytical Ba
Capacity:
MIDWEST RESEARCH INSTITUTE
Sieve Analysis"
•^?^MRI Project # WSO "0?~ ^Recorded bV.^^6c^^— ' <*.

o.: f,OOV A fO'L?) Material:
ht: fatf-rf' " ^ Number of Splits: /




lance: **-~±&^' '-4—s> • / v_*«^--5
rffOti ^


Smallest Division: 0 0, f

Date of Last
Calibration L
Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
Pan
Mfq. Calibration: <2-- Z-rf ~~ ^^
oqbook No.: £L- ~~ /
S
Tare Weight
(Screen)
5"J ?-• %
ifid'O
¥32* ">
*bl T^' 0
5(,f,0
^^3, 0
3^'^

Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.

Weight (pan only)
3?-^- ^
'Z'T-tf.y
2>3-£,£


ZE DISTRIBUTION
Final Weight
(Screen + Sample)
£?tf 7
£*£/ ^1 &
//£/
-------
                       MIDWEST RESEARCH INSTITUTE
                                Sieve Analysis*
                  MRIProiect#
     Recorded by
Sample ID No.:
Sample wieght:
Comments:
                      (Of)
Material:
                                         Number of Splits:	/_
                                                                               r
Analytical Balance:
Capacity:
Smallest Division:     U• /
Date of Last Mfg. Calibration:
Calibration Logbook No.: _
Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.
Weight (pan only)
29-6. i
3?-£,ff
3 ?-6, f


                             SIZE DISTRIBUTION
Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
Pan
Tare Weight
(Screen)
^ p jo *3—
c/ / ^ i
/f 3 5
%
70. V
13. V
] /} i
*7 tf
\>*
o.$
0,'t
*AII unit weights are in grams unless otherwise specified
                                   APPENDIX  D-3

-------


Date 7" 7

Sample ID N
Sample wieg
Comments:
^* /o^1
V

Analytical Bs
Capacity:
MIDWEST RESEARCH INSTITUTE
Sieve Analysis*
/° /j -,.,,--^_ ^^^^— ^-
-<^2^^- t/o^^&JJLs^Jl**^
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lance: ^-^^'"r'5 f~ ( 
t-f/QO %- -
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Smallest Division: ^' '

Date of Last
Mfq. Calibration: 2- - 2-/- f 5"


Calibration Logbook No.. > L- ~ f


Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
Pan
S
Tare Weight
(Screen)
5£2.3~~

-------

Date 9"^

MIDWEST RESEARCH INSTITUTE
Sieve Analysis*
1'1* MRI Project # f f// ^ 0? "^Recorded by ^^^t^-i<^-

Sample ID No.: £0/2-4 ^Ol^) Material:
Sample wieqht: 2-6^,3 Number of Splits: /

Comments:
4o Are.
r

-^.^ o,«^-,, -v^^- ^_ -.
^-£-JL.L>4 ^L^^^v
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Analytical Balance: r"~ i '<*r=5

Capacity: /
HOC ^


Smallest Division: " O, /

Date of Last
Calibration L
Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
Pan
Mfq. Calibration: 2- " 2./^ ^ %
oqbook No.: ^- /^ ~" /
S
Tare Weight
(Screen)
f *9 ~~1 *~J —
» c ^i . /^
^^^. ^
^3^. >
3 1 iS£
3^,^,0
335,6
3f #,4

Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.

Weight (pan only)
? T2-^. ^
2>^JtO
33-f, *f


ZE DISTRIBUTION
Final Weight
(Screen + Sample)
^D/. ^
^2-^.7
^ ^ ^,3
V"<9?-.5
5 9-V. /
33<4. ^"
^9-(f,0
to,*
LI.

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%
63,3
\^s
(?»(P
i*ft
i-??
Jl(o
o.y
*AII unit weights are in grams unless otherwise specified ' 2^* ' '^
APPENDIX   D-3

-------
MIDWEST RESEARCH INSTITUTE
Sieve Analysis*
Pat* 7"' MRIPrnjPrt* f ffC^^t^'^r Rernrried bYOaC-X^S/^V<2.



Sample ID N
Sample wieg
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Analytical Ba
Capacity: ^
/>
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ht: ££^ < i — ^5>
A/^^c^.


Smallest Division: ^ #, /

Date of Last
Calibration L
Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
Pan
Mfg. Calibration: 2~ - ^^"'r $
ogbook No.: ^?£ — /
S
Tare Weight
(Screen)
JT331.7
MZI
m.f
3f 3.2-
5^3.2^
5^/^6
3^6.^

Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.

Weight (pan only)
3T^,¥
39-^-?
3?-^. 6
3^f./
37-^^
ZE DISTRIBUTION
Final Weight
(Screen + Sample)
•9-0V. /,
500**
Ml-.S
*f63/b
1*f?-*.*
Net Weight
(Sample)
/W/9
^^.^
33-^
/D,Y
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/•Y
^•/

%
^r?
13.1
n~
-------
MIDWEST RESEARCH INSTITUTE
Sieve Analysis*
Date  Material:
Sample wieqht: SZY-^" Number of Splits: /

Comments:



Analytical Ba
Capacity:




lance: <~2a-~s~4-ovr~~ i • — -5
4/00 ^


V
Smallest Division: €>. f

Date of Last
Mfq. Calibration: 2,- Z-^/— ^ *


Calibration Logbook No.: 5 L- ~ (


Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
Pan
S
Tare Weight
(Screen)
532~^
te.3
VIS.O
*<**.?-
35-z. Y
zzzj
^^o.°\

Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.

Weight (pan only)
S^-^'
y-wr-
^x^^'
¥/£.Z-
¥/?-./
ZE DISTRIBUTION
Final Weight
(Screen + Sample)
£23tf
ItZ.'i
^3?.?
*&*^S14.0
ffl'V
5 7-2,. 5"
y-/^/
Net Weight
(Sample)
o.o
0.1
z.3.7
m.3
^.. 0
-bb.T-

%
0.0
0-0
1,4
IS.z
30,0
^
\\^
3^3-^
*AII unit weights are in grams unless otherwise specified
APPENDIX   D-3
                                                                                   13

-------
                       MIDWEST RESEARCH INSTITUTE
                               Sieve Analysis*
Date  3-20-1$ MRI Project*
                                         - Recorded bv
Sample ID No.:
Sample wieght:
                                       Material-
                                        Number of Splits:	/_
Comments:
Analytical Balance:
Capacity:
Smallest Division   0 .  /
Date of Last Mfg. Calibration:
Calibration Logbook No.:
                          2.
                           - f
Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.
Weight (pan only)
•p •T-/ 
-------

Date ^x '



Sample ID No.: JJ.
MIDWEST RESEARCH INSTITL
Sieve Analysis*
' MRI Project* (^0"0(r^Reco\

JTE
•ded by L^^ — ^-c^^-/^^ .
00^- A ^0 Material:
Sample wieqht: 3/2_-2- Number of Splits: /

Comments:







Analytical Balance:
Capacity: tf/6O
f ,
Smallest Division:
Date of Last Mfg. C
Calibration Logboo

Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
Pan




^-it-v^T^9 ^ '( t*-^
^-
'' &' /
)alibration: 7. - 2-Y"- 9^
kNo.: $L.- 1
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Tare Weight
(Screen)
t ( i s < f •• ""~> &
f'fff j/ f *-) ->&-*O
UL£f
^U 9-
52J2. (p
¥?/. °f
Zff, I
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Net Weight
(Sample)
0.0
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0,0
O'l
(f.9-
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*AII unit weights are in grams unless otherwise specified
APPENDIX    D-3
                                                                                    15

-------
MIDWEST RESEARCH INSTITUTE
Sieve Analysis* ._ /i
// & ^>{
Date ^-30" Iff MRI Project*  , /
Date of Last Mfq. Calibration: ^-~ "^^ "" t ^
Calibration Loqbook No.: *£ I— ~~ /
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Tare Weight
Screen (Screen)
4 mesh ^? 5Z.- ^
10 mesh ^4-^L>e 1
20 mesh '^^3. if-
40 mesh 3 
%y,°\
*2 ^^ ^7 ^
*^? ^? ^^~ • ^^^
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Net Weight
(Sample)
27. £>
€>.1s
t^S, I
iZl-tT
Ifa.tf
\\,$
32-.^
.• ••
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*•
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%
f)i0
0,1
fi.ls
fe.o
3/.6?
b»f
/0,6
^^
APPENDIX   D-3
                                                                                       16

-------
               MIDWEST RESEARCH INSTITUTE
                        Sieve Analysis*
Date
-
          MRI Project #
ecorded by<
Sample ID No.: ^OC3A Cu£) Material:
Sample wieqht: V^GP. Z- Number of Splits: 2-
Comments:




Analytical Ba
Capacity: ^
lance: j-v—s- ~i&-v*~ fv*^*^
'foo^ ~~


Smallest Division: <2» /
Date of Last
Calibration L
Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
Pan
Vlfq. Calibration: 2- -~ «- */•*" ? 5
oqbook No.. ^£. ~ /
S
Tare Weight
(Screen)
532. i^
H>V2~2
if/Lf ^
3^7-9-
35*2. ?0,
3f&. 2-
"3 £3, z>
^^/. 3>
Net Weight
(Sample)
/ 7 I • (a
I' *
tf.O
'T'-b
*&•%
I.I
<9. 5

%d,p
£$r7^'
-------


Date Y$
Sample ID N
Sample wieg
Comments:



Analytical Ba
Capacity: *
MIDWEST RESEARCH INSTITUTE
Sieve Analysis*
^"i MRI Proiect# *ff $0" Of "&J Recorded bv ^ — /6*~^i/ ^*—
&^f~-j~f>/~ i c^-^S
'-HOC <^-


Smallest Division: & 0 , 1

Date of Last
Calibration L
Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
Pan
Mfq. Calibration: ^- — Z^/ -^^^
oqbook No.: *^Z_ - /
S
Tare Weight
(Screen)
5"32.. ?-
y^ 5-3
Ll?)Lj.4
3 C]3: /^
3 13. 'Z,
3 ^'.6
5O / {^/
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Elapsed Time
Start (Tare Weight)
10 min.
20 min. ,
30 min.
40 min.

Weight (pan only)
3^.^
l^f-t-b
^fc^elz^'3 ^4 t 3


ZE DISTRIBUTION
Final Weight
(Screen + Sample)
fnz^S.S
LI "7~?f /
tf52.y
cfO'Z'.Lt
3V%< I
3S2-.f
s y~6>*tf
Net Weight
(Sample)
¥f2.. g
11.1
IB- V
f . ^
if. f
//£
Q,^

%
9A/
2.2
3.
-------
                      MIDWEST RESEARCH INSTITUTE
                               Sieve Analysis*
Date
              "
MRI Project #
                                     0tf-0> Recorded by
Sample ID No.:
Sample wieght:
                7/9 f /
Comments:
                                       Material:
                      Number of Splits:
Analytical Balance:
Capacity:
                   *
Smallest Division:   fy. I
Date of Last Mfg. Calibration: 2>-
Calibration Logbook No.:  5- (~
                                  ~ t
Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.
Weight (pan only)
3-tH-Y
3T-C,.?
31-6.1


                            SIZE DISTRIBUTION
  Screen
               Tare Weight
                 (Screen)
                 Final Weight
               (Screen + Sample)
Net Weight
 (Sample)
   4 mesh
               43  2,
                                   37-Z.
  10 mesh
                   5", 3
                                   ID.?
  20 mesh
                                                   rt.
                                                    if
  40 mesh
 100 mesh
 200 mesh
              3*1.1,
                                                    I?,*-
     Pan
*AII unit weights are in grams unless otherwise specified
                                 APPENDIX  D-3
                                                                      19

-------
                       MIDWEST RESEARCH INSTITUTE
                               Sieve Analysis*
Date
                 MRI Project*
                       - OS Recorded by
Sample ID No.:.
Sample wieght:
                                        Material:
                       Number of Splits:
                                                         /
Comments:
Analytical Balance:
Capacity:
          l/l/Ucj
         ivisiotr
Smallest Division:  0, (
Date of Last Mfg. Calibration:
Calibration Logbook No.:
Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.
Weight (pan only)
3 ?0. ?
j^fftrZ- 3 ?/. 3 '
•y 
-------


Date ^-3i

MIDWEST RESEARCH INSTITUTE
Sieve Analysis*
1 " °l$ MRI Project # <-f q <^ "N. tx"
f Z^-L J Material:
-> Number of Splits: ^^
^ -/o ^^_ *L^.'^^. <^^&*
G^)^_^ ^L- 5^?-^ ^ C*^Sl
# // /
//

^/-h^ I'L^
•3^


Smallest Division: d.l"
Date of Last Mfq. Calibration: t " Z- ^f — *} ^
Calibration Logbook No.:


Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
Pan

Z i-- 1 '
s
Tare Weight
(Screen)
^5 3J2. ^
tl«?< -2_
\0^)> '
2_

V^3. .5
3f^.^
O / £ Q
^^^^T^ 333. c
39-<^.f

Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.

Weight (pan only)
334.4
3-?-^ ^
-2,3-3.2-
3 ^f,j5"
2^_^ ^i
ZE DISTRIBUTION
Final Weight
(Screen + Sample)
732.. (f
4qV. ?•
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3? .0
33^.5
^"-M^ ^
Net Weight
(Sample)
3 ? f'f
flTr /?
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/• 3
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tf¥>t
z.l
!• '
J5» t
0,7-
0,3
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                                                                                       _
                                                                              /
APPENDIX  D-3
21

-------
                       MIDWEST RESEARCH INSTITUTE
                               Sieve Analysis*
Date
             f /
MRI Project #
Sample ID No.: ?OOJ A
Sample wieght:
                                         aterial:
                WZ.*
Analytical Balance:
Capacity: _
                           /"
                  -^
Smallest Division:    v (? , /
Date of Last Mfg. Calibration: j
Calibration Logbook No.: _
                            -  2
                             " 
-------

Date ^^

MIDWEST RESEARCH INSTITl
Sieve Analysis*
7" 1f MRI Project # /£0 " ^/ '^/Reco

JTE
rded by
f.

/u^C^2^-lr-

Sample ID No.: HOOjfi (Dl) Material:
Sample wieght: V^Y 2- Number of Splits:

Comments:







I









Analytical Balance: &-*<-^'~rvr~i'u^>

Capacity: 4
WO*.




Smallest Division: O. f

Date of Last
Calibration L
Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
Pan
Mfq. Calibration: Z-2-£*l
tLs * 1
tf3-(e*0
LftftS.
5O ^^ ^}
]/ / * v '**'
^-j /• / ^^'
J^S. ^
3 "7-^.^


Net Weight
(Sample)
^63. *f
^. *7
/ 0
b • rt
^

f,0
•f'-L

2^^
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%
36*1-
I'tf
0. 9
d- 5
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0^3
0.3
-na 7 G
*AII unit weights are in grams unless otherwise specified ' '
APPENDIX   D-3
23

-------


Date ?- 2/0

Sample ID N
Sample wieg
Comments:



Analytical Be
Capacity: ^
MIDWEST RESEARCH INSTITUTE
Sieve Analysis*
" ft MRI Project # ty tJt'fffcO} Recorded bv ( ^<^^^^^—


o.: $00 i //- fi>dO Material:
ht: Lj(p3..<& Nur




ilance: j^-z^^T9 ^ ~ 1 ^~~~5
'/£>£> ^
nberof J
Splits: f? ,






Smallest Division: (?» /

Date of Last
Calibration L
Screen
4 mesh
10 mesh
20 mesh
40 mesh
100 mesh
200 mesh
Pan
Mfa. Calibration: 2- " 2- /— 1 %
oqbook No.: ^ '/^ — /
S
Tare Weight
(Screen)
$?>l. T-
H-yZ-*]
y /y 9
^ I 0 p -7
*^> ^ S~\ £J
3^,1.5"
^^0. #


Elapsed Time
Start (Tare Weight)
10 min.
20 min.
30 min.
40 min.
Weight (pan only)
370. 
r^L. ^
i- f
5, t?
2- ^
/-^

%
f^.?
I '(a
0^
0. (*
0, (,
(9.3
/; «,
*AII unit weights are in grams unless otherwise specified }(0^-' \
APPENDIX   D-3
                                                                                       24

-------
                      MIDWEST RESEARCH INSTITUTE
                        CHAIN-OF-CUSTODY FORM
                       MRI Project No.
Check Only Those Samples Transferred:
                                                             Code: MRI-5003
                                                                 Revision: 1
                                                            Effective: 3/27/98
                                                               Page:  15 of 17
                                            261
#1 #2
^Sr n 21
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G? n
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Sample Identifier #1
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#2 Sample Identifier
n
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a
a
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a
n
     a
a  a
 Please sign the form;  initials  are  not  acceptable.  Please  use military  time
 designations (e.g., 13:23).  For field samples returning to the sample custodian,
 indicate the storage area in the comments section.  The comments section should
 indicate the sample type and purpose of the transfer (e.g., GC/MS analysis).

       #1 Relinquished by:
             Received by:
           Date and Time:
              Comments:
       #2 Relinquished by:
             Received by:
           Date and Time:
              Comments:
 MRl-QAVMRl- 5003.DOC
                                   APPENDIX D-3
                                      25

-------
                                                             Code: MRI-5003
                                                                 Revision: 1
                                                             Effective: 3/27/98
                                                               Page: 15 of 17
                      MIDWEST RESEARCH INSTITUTE
                        CHAIN-OF-CUSTODY £ORM
                       MRI Project No.
Check Only Those Samples Transferred:
#1
a:
n
a
a
a
a
a
#2 Sample Identifier
n &
-------
TECHNICAL REPORT DATA
(Please read Instructions on reverse before completing)
1. REPORT NO. 2.
EPA-454/R-99-038
4. TITLE AND SUBTITLE
Waste Materials Testing in Support of Regulatory Development For
Industrial, Commercial, And Institutional Boilers
7. AUTHOR(S)
EMAD
9. PERFORMING ORGANIZATION NAME AND ADDRESS
U.S. Environmental Protection Agency
Office of Air Quality Planning and Standards
Research Triangle Park, NC 27711
12. SPONSORING AGENCY NAME AND ADDRESS
Director
Office of Air Quality Planning and Standards
Office of Air and Radiation
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
3. RECIPIENTS ACCESSION NO.
5. REPORT DATE September, 1999
6. PERFORMING ORGANIZATION CODE
g. PERFORMING ORGANIZATION REPORT NO.
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
Midwest Research Institute
EPA Contract # 68-D-98-027
13. TYPE OF REPORT AND PERIOD COVERED
final test report
14. SPONSORING AGENCY CODE
EPA/200/04
15. SUPPLEMENTARY NOTES
16. ABSTRACT
The purpose of this test program was to obtain data to support the development of National Emission
Standards for Hazardous Air Pollutants. This test program included sampling and analysis of waste material
combusted in 1 1 boilers or burnoff ovens and were taken from 1 1 different facilities. This data will be used in
conjunction with other information to characterize materials combusted in boilers.
1 7.MACT Rule Support KEY WORDS AND DOCUMENT ANALYSIS
a. DESCRIPTORS

18. DISTRIBUTION STATEMENT
Release Unlimited
b. IDENTIFIERS/OPEN ENDED TERMS c. COSATI Field/Group
Air Pollution control, MACT
Support for Industrial, Commercial,
And Institutional Boilers
19. SECURITY CLASS (Report) 21. NO. OF PAGES
Unclassified 258
20. SECURITY CLASS (Page) 22. PRICE
Unclassified
EPA Form 2220-1 (Rev. 4-77)    PREVIOUS EDITION IS OBSOLETE

-------