United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park, NC 27711
EPA-454/R-99-043
September 1999
Air
©EPA
Final Report
Manual Testing and Continuous
Emissions Monitoring, Lime Kiln
Nos. 3 and 4 Baghouses
Chemical Lime Company
Montevallo, Alabama
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FINAL REPORT
MANUAL TESTING AND CONTINUOUS
EMISSIONS MONITORING
LIME KILN NOS. 3 AND 4 BAGHOUSES
CHEMICAL LIME COMPANY
MONTEVALLO, ALABAMA
EPA Contract No. 68D70069
Work Assignment No, 2-17
Prepared for:
Mr. Michael L. Toney (MD-19)
Work Assignment Manager
SCGA, EMC, OAQPS
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
September 1999
Submitted by
PACIFIC ENVIRONMENTAL SERVICES, INC.
5001 S. Miami Blvd., Suite 300
Post Office Box 12077
Research Triangle Park, NC 27709-2077
(919)941-0333
FAX (919) 941-0234
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DISCLAIMER
This document was prepared by Pacific Environmental Services, Inc. (PES) under EPA
Contract No. 68D70069, Work Assignment No. 2-17. This document has been reviewed
following PES' internal quality assurance procedures and has been approved for distribution.
The contents of this document do not necessarily reflect the views and policies of the U.S.
Environmental Protection Agency (EPA). Mention of trade names does not constitute
endorsement by the EPA or PES.
11
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GENERAL DISCLAIMER
This document may have problems that one or more of the following disclaimer
statements refer to:
This document has been reproduced from the best copy furnished by the
sponsoring agency. It is being released in the interest of making
available as much information as possible.
This document may contain data which exceeds the sheet parameters. It
was furnished in this condition by the sponsoring agency and is the best
copy available.
This document may contain tone-on-tone or color graphs, charts and/or
pictures which have been reproduced in black and white.
The document is paginated as submitted by the original source.
Portions of this document are not fully legible due to the historical nature
of some of the material. However, it is the best reproduction available
from the original submission.
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TABLE OF CONTENTS
Page
1.0 INTRODUCTION 1-1
2.0 SUMMARY OF RESULTS 2-1
2.1 EMISSIONS TEST LOG 2-1
2.2 PCDDs/PCDFs 2-1
2.3 AIRFLOWRATES 2-3
2.4 HCL AND THC 2-4
3.0 PROCESS DESCRIPTION 3-1
4.0 SAMPLING LOCATIONS 4-1
4.1 KILNNO. 3 BAGHOUSE INLET 4-1
4.2 KILN NO. 4 BAGHOUSE INLET 4-1
4.3 KILN NO. 3 BAGHOUSE AND KILN NO. 4 BAGHOUSE STACK 4-5
4.4 CO2 BUBBLER SLIPSTREAM 4-5
5.0 SAMPLING AND ANALYTICAL PROCEDURES 5-1
5.1 LOCATION OF MEASUREMENT SITES AND
SAMPLE/VELOCITY TRAVERSE POINTS 5-1
5.2 DETERMINATION OF AIR STREAM VOLUMETRIC
FLOW RATE 5-1
5.3 DETERMINATION OF AIR STREAM MOISTURE CONTENT 5-3
5.4 DETERMINATION OF PCDDs/PCDFs 5-3
5.5 DETERMINATION OF HYDROGEN CHLORIDE 5-3
5.6 DETERMINATION OF CARBON DIOXIDE, OXYGEN, AND
TOTAL HYDROCARBONS 5-6
6.0 QUALITY ASSURANCE/QUALITY CONTROL PROCEDURES AND
RESULTS 6-1
6.1 CALIBRATION OF APPARATUS 6-1
6.2 ON-SITE MEASUREMENTS 6-4
6.3 EPA METHOD 23 PCDDs/PCDFs LABORATORY ANALYSES 6-6
111
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TABLE OF CONTENTS (Concluded)
APPENDIX A RAW FIELD DATA
Appendix A. 1 Raw Field Data, Kiln No. 3 Baghouse Inlet
Appendix A.2 Raw Field Data, Kiln No. 4 Baghouse Inlet
Appendix A.3 Raw Field Data Kiln No. 3 Baghouse and Kiln No. 4 Baghouse
Stack
Appendix A.4 Raw Field Data, CO2 Bubbler Slipstream
APPENDIX B CEMs AND ANALYTICAL DATA
Appendix B.I CEMs and Analytical Data, CEMs, Methods 3A, 25A, and
Proposed Method 322
Appendix B.2 CEMs and Analytical Data, Method 23 Analytical Data
APPENDIX C CALCULATIONS
APPENDIX D CALIBRATION DATA
APPENDIX E PARTICIPANTS
IV
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LIST OF TABLES
TABLE 2.1
TABLE 2.2
TABLE 2.3
TABLE 2.4
TABLE 2.5
TABLE 2.6
TABLE 2.7
TABLE 2.8
EMISSIONS TEST LOG
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA .
PCDDs/PCDFs SAMPLING AND AIRSTREAM PARAMETERS
KILN NO. 3 BAGHOUSE INLET AND STACK
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA .
PCDDs/PCDFs CONCENTRATION AND EMISSION RATES
KILN NO. 3 BAGHOUSE INLET AND STACK
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA .
2-2
2-6
2-7
PCDDs/PCDFs CONCENTRATIONS AND 2378-TCDD TOXIC
EQUIVALENT CONCENTRATIONS ADJUSTED TO 7 PERCENT
OXYGEN KILN NO. 3 BAGHOUSE INLET AND STACK
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA ...
PCDDs/PCDFs SAMPLING AND AIRSTREAM PARAMETERS
KILN NO. 4 BAGHOUSE INLET AND STACK
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA .
PCDDs/PCDFs CONCENTRATIONS AND EMISSION RATES
KILN NO. 4 BAGHOUSE INLET AND STACK
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA .
2-8
2-9
2-10
PCDDs/PCDFs CONCENTRATIONS AND 2378-TCDD TOXIC
EQUIVALENT CONCENTRATIONS ADJUSTED TO 7 PERCENT
OXYGEN KILN NO. 4 BAGHOUSE INLET AND STACK
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA ...
2-11
AIR STREAM PARAMETERS
DURING PCDDs/PCDFs TESTING ON OPPOSITE KILN
KILN NO. 3 BAGHOUSE AND KILN NO. 4 BAGHOUSE
INLETS
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA
2-12
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age
LIST OF TABLES (Concluded)
TABLE 2.9 AIR STREAM PARAMETERS DURING PCDDs/PCDFs TESTING
CO2 BUBBLER SLIPSTREAM OFF KILN NO. 3 AND KILN NO. 4
STACK
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA 2-13
TABLE 2.10 AIR STREAM PARAMETERS DURING EXTRA HCL TESTING
KILN NO. 3 BAGHOUSE AND KILN NO. 4 BAGHOUSE STACK
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA ........ 2-14
TABLE 2.11 HCL AND THC CONCENTRATIONS AND EMISSION RATES
KILN NO. 3 BAGHOUSE AND NO. 4 BAGHOUSE INLETS AND
STACK
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA 2-15
TABLE 5.1 SUMMARY OF SAMPLING LOCATIONS, TEST PARAMETERS,
SAMPLING METHODS, AND NUMBER AND DURATION OF TESTS
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA 5-2
TABLE 6.1 SUMMARY OF TEMPERATURE SENSOR CALIBRATION DATA
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA 6-2
TABLE 6.2 SUMMARY OF PITOT TUBE DIMENSIONAL DATA
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA 6-3
TABLE 6.3 SUMMARY OF DRY GAS METER AND ORIFICE CALIBRATION
DATA CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA ... 6-4
TABLE 6.4 SUMMARY OF CALIBRATION GAS CYLINDERS
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA 6-5
TABLE 6.5 SUMMARY OF EPA METHOD 23 FIELD SAMPLING QA/QC DATA
CHEMICAL COMPANY - MONTEVALLO, ALABAMA 6-7
TABLE 6.6 SUMMARY OF EPA METHOD 23 STANDARDS RECOVERY
EFFICIENCIES
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA 6-9
VI
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LIST OF FIGURES
Page
Figure 1.1 Key Personnel and Responsibility for Testing at Chemical Lime
Company - Montevallo, Alabama 1-2
Figure 4.1 Kiln No. 3 and Kiln No, 4 Process Flow Schematic Showing Testing
Locations, Chemical Lime Company - Montevallo, Alabama 4-2
Figure 4.2 Kiln No. 3 Baghouse Inlet Test Location and Traverse Point
Locations, Chemical Lime Company - Montevallo, Alabama 4-3
Figure 4.3 Kiln No. 4 Baghouse Inlet Test Location and Traverse Point
Locations, Chemical Lime Company - Montevallo, Alabama 4-4
Figure 4.4 Kiln No. 3 Baghouse and Kiln No. 4 Baghouse Stack Test Location
and Traverse Point Locations
Chemical Lime Company - Montevallo, Alabama 4-6
Figure 4.5 CO2 Bubbler Slipstream Off Kiln Nos. 3 & 4 Baghouses Stack Test
Location and Traverse Point Locations, Chemical Lime Company -
Montevallo, Alabama 4-7
Figure 5.1 Sampling Train Schematic for EPA Method 23 5-4
Figure 5.2 Sampling Train Schematic for Proposed EPA Method 322 5-5
Figure 5.3 Sampling Train Schematic for EPA Methods 3A and 25A 5-7
VII
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1.0 INTRODUCTION
The U.S. Environmental Protection Agency (EPA) Emission Standards Division (BSD) is
investigating the lime manufacturing industry to identify and quantify hazardous air pollutants
(HAPs) emitted from lime kilns, BSD requested that EPA's Emissions, Monitoring and Analysis
Division (EMAD) conduct the required testing. EMAD issued a work assignment to Pacific
Environmental Services, Inc. (PES) to conduct a screening test to collect air emissions data as
specified in the BSD test request. The planning and initial preparation activities of the program
were conducted through EPA Contract No. 68-D7-0002, Work Assignment No. 0/005.
Remaining preparation, testing, and generation of the Draft Final Report were completed under
EPA Contract No. 68-D7-0002, Work Assignment No. 1/007. Generation of the Final Report,
incorporating EPA's comments on the Draft Final Report, was completed under EPA Contract
No. 68D70069, Work Assignment No. 2-17.
The primary objective was to characterize HAP emissions from two lime kilns at the
Chemical Lime Company's facility located in Montevallo, Alabama. Based on the pollutant
concentrations and emission rates calculated from the results of the screening tests, some of the
kilns may be selected by EPA for further testing.
The tests were conducted to quantify the uncontrolled and controlled air emissions of
hydrogen chloride (HC1), total hydrocarbons (THC), and polychlorinated dibenzo-p-dioxins and
polychlorinated dibenzofurans (PCDDs/PCDFs). Emissions from each kiln were controlled by a
baghouse dedicated to each kiln. Over a two-day period, testing was conducted at each baghouse
inlet and at the common stack. Inlet and outlet runs on each kiln were conducted simultaneously.
Oxygen (O2) and carbon dioxide (CO2) were also monitored at each location. During the testing,
Research Triangle Institute (RTI), an BSD contractor, recorded plant operational data.
PES used three subcontractors for this effort: Air Pollution Characterization and Control
Ltd. (APCC), of Toland, Connecticut; Triangle Laboratories, Inc. (TLI), of Durham, North
Carolina; and Atlantic Technical Services, Inc. (ATS), of Chapel Hill, North Carolina. APCC
provided equipment and manpower for quantification of HC1, O2, CO2, and THC; TLI provided
analytical services for the analysis of the PCDDs/PCDFs samples; and ATS provided technical
support for preparation of the Quality Assurance Project Plan (QAPP), Site Specific Test Plan
(SSTP), for reduction of the test data, and for preparation of the Draft Final Report.
The field testing program organization and major lines of communication are presented in
Figure 1.1. The PES Task Manager communicated directly with the EPA Work Assignment
Manager (WAM) and coordinated all of the on-site testing activities.
1-1
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Chemical Lime Company
David R, Christiansen
Environmental, Health & Safety Manager
(817)732-8164
EPA/EMC
Work Assignment Manager
Michael L, Toney
(919)541-5247
EPA/ESD
Lead Engineer
Joseph P, Wood
(919)541-5466
PES
Program Manager
John T. Chehaske
(919)941-0333
PES
Corporate QA/QC Officer
Jeffery L. Van Atten
(703)471-8383
PES
Project Manager
Frank! Phoenix
(919)941-0333
BSD Contractor
Research Triangle Institute
Cybelle M, Brockman
(919)990-8654
Pretest Site Survey
PES
SSIP
PES
-
QAPP
PES
Subcontractor
Atlantic Technical Sevices, Inc.
_
Subcontractor
Atlantic Technical Services, Inc.
Field Testing
PES
-
Subcontractor
Air Pollution
Characterization & Control, Ltd
Analysis
PES
-
Report Preparation
PES
Subcontractor
Triangle Laboratories, Inc.
-
Subcontractor
Atlantic Technical Serivces, Inc.
Figure 1,1 Key Personnel and Responsibility for Testing at Chemical Lime Company - Montevallo, Alabama
1-2
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2.0 SUMMARY OF RESULTS
This section provides summaries of the test results for testing at the Chemical Lime
Company in Montevallo, Alabama. Included are results of the tests conducted for
PCDDs/PCDFs, HC1, and THC emissions at the Kiln No. 3 baghouse inlet, Kiln No. 4 baghouse
inlet, and the Kiln No. 3 and Kiln No. 4 baghouses shared stack.
2.1 EMISSIONS TEST LOG
Testing was conducted on Kiln No. 4 on the first day, and on Kiln No. 3 on the second
day. During the testing on a kiln, a velocity traverse was conducted on the other kiln to quantify
the air flow contribution of both kilns to the combined outlet (stack). In addition, velocity
traverses were conducted on a gas slipstream which branches off prior to the stack sampling
location. Additional velocity traverses, THC, and HC1 testing were conducted at the stack
location due to difficulties encountered with the Quality Assurance spikes associated with the
HC1 sampling. These issues are discussed in Section 2.4
Sampling was performed on March 23,24, and 25,1998. Table 2.1 presents the
emissions test log. Presented are the run numbers, test dates, pollutants, run times, and
downtimes for response times and port changes.
2.2 PCDDs/PCDFs
PES employed EPA Method 23 for the measurement of PCDDs and PCDFs. The results
of the PCDD/PCDF results are presented in Tables 2.2 through 2.7. PCDDs/PCDFs results are
presented as 1) actual concentrations and mass emission rates,'2) concentrations adjusted to 7
percent (%) O2, and 3) concentrations adjusted to 7 % O2 and 2378 tetra-chlorinated dibenzo-p-
dioxin (TCDD) toxic equivalent basis. Adjustment of the congeners to a 2378 toxic equivalent
basis was calculated using the Toxic Equivalency Factor (TEF) values developed by the NATO
Committee on the Challenges of Modern Society, August 1988.
The Method 23 sample fractions consisted of a sample train front-half solvent rinse, a
particulate filter, a back-half solvent rinse, and an XAD®-2 sorbent resin module. During
analysis, each of the sample fractions was extracted, concentrated, combined, and analyzed using
a Gas Chromatograph with a Mass Spectrometer detector (GC/MS), according to the procedures
outlined in Method 23. During analysis, the combined sample extract was separated with a DB-5
capillary column. Where the results of that analysis indicated the presence of 2378 TCDF
congeners, the analysis was repeated using a DB-225 capillary column so that the TCDF
congeners could be more readily separated and quantified.
2-1
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TABLE 2.1
EMISSIONS TEST LOG
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA
Run No.
Date
Pollutant
Run Time
Downtime,
Minutes *
Kiln No. 4 Baghouse Inlet
M23-I-1
M3A-I-1
M25A-I-1
M322-I-1
M2-4-I-2
Kiln No. 3 Baghouse Inlet
M2-3-I-1
M23-I-2
M3A-I-2
M25A-I-2
M322-I-2
03/23/98
03/23/98
03/23/98
03/23/98
03/24/98
PCDDs/PCDFs
CO2/O2
THC
HC1
Air Flow Rate
1400-1808
1425-1800
1425-1800
1425-1800
1430-1450
68
125
125
125
-
03/23/98
03/24/98
03/24/98
03/24/98
03/24/98
Air Flow Rate
PCDDs/PCDFs
CO2 / O2
THC
HC1
Kiln No. 3 Baghouse & Kiln No. 4 Baghouse Stack
M23-O-1
M3A-O-1
M25A-O-1
M322-O-1
M23-O-2
M3A-O-2
M25A-O-2
M322-O-2
M2-O-3
M322-O-3
CO-, Bubbler Slipstream
_
M2-CBS-1
M2-CBS-2
03/23/98
03/23/98
03/23/98
03/23/98
03/24/98
03/24/98
03/24/98
03/24/98
03/25/98
03/25/98
PCDDs/PCDFs
CO2/O2
THC
HC1
PCDDs/PCDFs
CO2/O2
THC
HC1
Air Flow Rate
HC1
1440-1455
1332-1709
1350-1725
1350-1725
1350-1725
-
37
125
125
125
1400-1806
1400-1740
1400-1740
1400-1740
1332-1709
1330-1705
1330-1705
1330-1705
0910
0855-0910
66
125
125
125
37
125
125
125
0
03/23/98
03/24/98
Air Flow Rate
Air Flow Rate
1440-1455
1430-1450
4 The CEMs sample acquisition system operated on a time-shared basis, switching between the baghouse inlet
and stack locations after 15 minutes of sampling. This applies to Methods 3A, 25A, and 322.
2-2
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The results of the analyses indicated the presence of several congeners that were qualified as
Estimated Maximum Possible Concentrations, or EMPCs. From time to time during the Method
23 analyses, a peak elutes at the position expected for a particular congener, but the peak fails
validation based on the theoretical split of chlorine isotopes. That is to say that the number of
Cl35 isotopes and the number of Cl37 isotopes attached to the PCDDs/PCDFs congeners should
agree with the C135/C137 ratio found in nature. For each congener, this ratio must agree within
15%. If the mass ratio of chlorine isotopes does not agree with the natural chlorine isotope ratio,
then the peak is flagged as an EMPC.
The values presented as "Total PCDDs" are the sum of the " 12346789 OCDD"
polychlorinated dibenzo-p-dioxin and all of the dioxins labeled "Total"; "Total PCDFs" values
are the sum of the "12346789 OCDF" polychlorinated dibenzofuran and all of the furans labeled
"Total". "Total PCDDs + Total PCDFs" values are the sum of the "Total PCDDs" and "Total
PCDFs" values. Values that have been qualified as being EMPC have been included in the
sums. Concentrations and emission rates based on or including EMPC values are denoted by
braces ( { }).
2.2.1 Kiln No. 3
Tables 2.2,2.3, and 2.4 summarize the PCDDs/PCDFs test results from the Kiln No. 3
baghouse inlet and stack. Table 2.2 summarizes the PCDDs/PCDFs emissions sampling and air
stream parameters. Table 2.3 presents the PCDDs/PCDFs air stream concentrations and
emission rates. The PCDDs/PCDFs concentrations and 2378-TCDD toxic equivalent
concentrations adjusted to 7% oxygen are tabulated in Table 2.4.
2.2.2 Kiln No. 4
Tables 2.5,2.6, and 2.7 summarize the PCDDs/PCDFs test results from the Kiln No. 4
baghouse inlet and stack. Table 2.5 summarizes the PCDDs/PCDFs emissions sampling and air
stream parameters. Table 2.6 presents the PCDDs/PCDFs air stream concentrations and
emission rates. The PCDDs/PCDFs concentrations and 2378-TCDD toxic equivalent
concentrations adjusted to 7% oxygen are tabulated in Table 2.7.
2.3 AIR FLOW RATES
2.3.1 Kiln No. 3 Baghouse Inlet & Kiln No. 4 Baghouse Inlet
A velocity traverse was performed at the Kiln No. 3 Baghouse Inlet while the Method 23
testing was being performed on Kiln No. 4; on the next day, a velocity traverse was done at the
Kiln No. 4 Baghouse Inlet during the Kiln No. 3 Method 23 testing. Results of the two velocity
traverses are presented in Table 2.8. The moisture, CO2, and O2 content at each inlet location
were assumed to be unchanged from the results generated by the Method 23 testing.
2-3
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2.3.2 CO; Bubbler Slipstream
The results of the velocity traverses conducted at the CO2 Bubbler Slipstream during both
tests at the stack are presented in Table 2.9, Moisture, CO2, and O2 content of the slipstream
were estimated to be the same as that measured during the two tests conducted at the stack.
2.3.3 Kiln No. 3 Baghouse & Kiln No. 4 Baghouse Stack
During the additional Proposed Draft Method 322 data acquisition on 3/25/98, air flow
rate parameters were measured; the results are tabulated in Table 2,10. The moisture was
estimated to be 14%. Method 3 A was used to measure the CO2, and O2 content.
2.4 HCL AND THC
Table 2.11 presents the results of the HC1 and THC measurements conducted by APCC at
the Kiln No, 3 and Kiln No, 4 baghouse inlets, and at the stack. HC1 and THC data collected
over a three-day period are presented in this table. Also presented in the table are mass emission
rate data.
APCC encountered significant QA/QC problems during the analyte spiking of the HC1
sampling system. The curves generated during calibration of the HC1 analyzer met the method
requirements of no greater than 7.5 % (of span) calibration error. HC1 recoveries during analyte
spiking on Kiln No. 4 were 38% and 56% for the inlet and outlet locations, respectively. HC1
recoveries on Kiln No. 3 were 0% at the inlet location, since no HC1 was detected during analyte
spiking, and 29% at the outlet location. None of these recoveries met the method requirement of
±30% recovery of the analyte spike. Additional testing was conducted at the stack location on
March 25, and the HC1 analyte spike recovery was 88%. On March 25, the sampling system was
modified and the sample flowrate was increased to approximately 15 liters per minute; the
sample flowrate was approximately 8 liters per minute during the testing on March 23 and March
24. A more detailed discussion of the QA/QC issues may be found in APCC's letter of April 30,
1998, which may be found in Appendix B.I.
The low HC1 recovery efficiencies observed during the testing on March 23 and March
24 suggest that the measured HC1 concentrations may be biased low compared to the true in-
stack concentrations. The additional testing on March 25, for which an acceptable analyte spike
was observed, indicated an increase in the in-stack HC1 concentration of approximately 35%,
however, it is impossible to ascertain if this ratio is an accurate measurement of any negative bias
of the HC1 measurements.
Corrections of the HC1 and THC concentrations from the wet basis to dry basis used the
moisture values from the concurrent PCDDs/PCDFs testing at the same locations. Volumetric
flow rates for emission rate calculations are also from the PCDDs/PCDDFs testing. During the
HC1 and THC testing conducted on March 25, velocity traverses were conducted, but moisture
values were assumed from the data developed over the previous two days.
2-4
-------
Three of the five runs conducted for THC resulted in measured concentrations of THC
below the nominal detection limit of the THC analyzer of 1 part per million (ppm). Concurrently
with these three runs, the post-run calibration checks of the THC analyzer demonstrated a zero-
drift of approximately -4 % of span, or -4 ppm. The analyzer zero drift, combined with a
negative span drift during the three runs, most likely resulted in a negative bias in the
measurement of THC concentrations at the baghouse inlet during testing on Kiln No. 4, as well
at the stack location during testing on both kilns.
2-5
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TABLE 2.2
PCDDs/PCDFs SAMPLING AND AIR STREAM PARAMETERS
KILN NO. 3 BAGHOUSE INLET AND STACK
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA
Run No.
Sampling Location
Date
Total Sampling Time, minutes
Average Sampling Rate, dsefm b
Sample Volume:
dscf°
dscm"
Average Exhaust Gas Temperature, °F
O2 Concentration, % by Volume
CO2 Concentration, % by Volume
Moisture, % by Volume
Exhaust Gas Volumetric Flow Rate:
acfm*
dscrm"
dscmmf
Isokinetic Sampling Ratio, %
M23-3-I-2
Baghouse Inlet
3/24/98
180
0,566
101.881
2.885
902
5.3
26.6
7.8
152,000
54,300
1,540
104.2
M23-O-2
Stack a
3/24/98
180
0.629
113.279
3.208
416
10.0
18.6
14.4
277,000
141,000
4,000
102.8
* The outlet sampling location was downstream of the point where the kiln exhausts merged. Therefore
depending on the parameter, the data presented is either the sum (e.g. flow rate) or the weighted
average (e.g., gas temperature) of the two kilns.
b Dry standard cubic feet per minute at 68° F (20° C) and 1 atm.
0 Dry standard cubic feet at 68° F (20° C) and 1 atm.
d Dry standard cubic meters at 68° F (20° C) and 1 atm.
e Actual cubic feet per minute at exhaust gas conditions.
f Dry standard cubic meters per minute at 68° F (20° C) and 1 atm.
2-6
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TABLE 2.3
PCDDs/PCDFs CONCENTRATIONS AND EMISSION RATES
KILN NO. 3 BAGHOUSE INLET AND STACK
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA
CONGENER
DIOXINS:
2378 TCDD
Total TCDD
12378PeCDD
Total PeCDD
123478 HxCDD
123678 HxCDD
123789 HxCDD
Total HxCDD
1234678 HpCDD
Total HpCDD
1 2346789 OCDD
Total PCDDs
FURANS:
2378 TCDF
Total TCDF
12378 PeCDF
23478 PeCDF
Total PeCDF
123478 HxCDF
123678 HxCDF
234678 HxCDF
123789 HxCDF
Total HxCDF
1234678 HpCDF
1234789 HpCDF
Total HpCDF
12346789 OCDF
Total PCDFs
Total PCDDs + PCDFs
CONCENTRATION 8
(ng/dscm, as measured)
M23-3-I-2
Baghouse Inlet
(0,0139)
0.0867
(0.0243)
{0.0381}
(0.0312)
(0.0277)
(0.0277)
0.0243
(0.0347)
(0.0347)
{0.101}
(0.284)
0.177
4.19
0.0728
0.0728
0.936
0.0347
{0.0173}
(0.0208)
(0.0243)
0.114
{0.0173}
(0.0347)
{0.0173}
(0.0347)
(5.30)
(5.58)
M23-O-2
Stack
(0.00187)
0.0249
(0.00281)
0,00935
(0.00312)
(0.00312)
(0.00312)
(0,00312)
0.00312
0.00312
{0.00935}
(0.0499)
0.00312
0.0779
(0,00187)
(0.00187)
0.00624
(0.00249)
(0.00218)
(0.00281)
(0.00312)
{0.00218}
{0,00312}
(0.00624)
{0.00312}
(0,00935)
(0.0988)
(0.149)
EMISSION RATE "
(Hg/hr)
M23-3-I-2
Baghouse Inlet
(1,28)
7.99
(2.24)
{3.52}
(2.88)
(2.56)
(2.56)
2.24
(3.20)
(3.20)
{9.27}
(26.2)
16.3
387
6.71
6.71
86.3
3.20
{1.60}
(1.92)
(2,24)
10.6
{1.60}
(3.20)
{1-60}
(3.20)
(489)
(515)
M23-O-2
Stack
(0.449)
5.98
(0.673)
2,24
(0.748)
(0.748)
(0.748)
(0.748)
0.748
0.748 .
{2.24}
(12.0)
0.748
18.7
(0.449)
(0,449)
1.50
(0.598)
(0.523)
(0.673)
(0.748)
{0.523}
{0.748}
(1.50)
{0.748}
(2.24)
(23.7)
(35.7)
a Nanogram per dry standard cubic meter at 20°C and 1 atm.
b Micrograms per hour.
() Not Detected. Value shown is the detection limit and is included in totals.
{ } Estimated Maximum Possible Concentration. EMPC values are included in totals.
2-7
-------
TABLE 2.4
PCDDs/PCDFs CONCENTRATIONS AND 2378-TCDD TOXIC EQUIVALENT
CONCENTRATIONS ADJUSTED TO 7 PERCENT OXYGEN
KILN NO. 3 BAGHOUSE INLET AND STACK
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA
CONGENER
DIOXINS:
2378 TCDD
Total TCDD
12378 PeCDD
Total PeCDD
123478 HxCDD
123678 HxCDD
123789 HxCDD
Total HxCDD
1234678 HpCDD
Total HpCDD
12346789 OCDD
Total PCDDs
FURANS:
2378 TCDF
Total TCDF
12378 PeCDF
23478 PeCDF
Total PeCDF
123478 HxCDF
123678 HxCDF
234678 HxCDF
123789 HxCDF
Total HxCDF
1234678 HpCDF
1234789 HpCDF
Total HpCDF
12346789 OCDF
Total PCDFs
Total PCDDs + PCDFs
CONCENTRATION "
(ng/dscm, adjusted to 7 percent O2)
M23-3-I-2
Baghouse Inlet
(0.0124)
0.0772
(0.0216)
{0.0340}
(0.0278)
(0.0247)
(0.0247)
0.0216
(0.0309)
(0.0309)
{0.0896}
(0.253)
0.158
3.74
0.0649
0.0649
0.834
0.0309
{0.0154}
(0.0185)
(0.0216)
0.102
{0.0154}
(0.0309)
{0.0154}
(0.0309)
(4.72)
(4.97)
M23-O-2
Stack
(0.00239)
0.0318
(0.00358)
0.0119
(0.00398)
(0.00398)
(0.00398)
(0.00398)
0.00398
0.00398
{0.0119}
(0.0636)
0.00398
0.0994
(0.00239)
(0.00239)
0.00795
(0.00318)
(0.00278)
(0.00358)
(0.00398)
{0.00278}
{0.00398}
(0.00795)
{0.00398}
(0.0119)
(0.126)
(0.190)
2378-TCDD
Toxicity
Equivalence
Factor
1.000
0.500
0.100
0.100
0.100
0.010
0.001
Total PCDDs TEQ
0.100
0.050
0.500
0.100
0.100
0.100
0.100
0.010
0.010
0.001
Total PCDFs TEQ
Total TEQ
2378 TOXIC EQUIVALENCIES
(ng/dscm, adjusted to 7 percent O2)
M23-3-I-2
Baghouse Inlet
(0.0124)
(0.0108)
(0.00278)
(0.00247)
(0.00247)
(0.000309)
(0.0000896)
(0.0313)
(0.0158)
(0.00324)
(0.0324)
(0.00309)
(0.00154)
(0.00185)
(0.00216)
(0.000154)
(0.000309)
(0.0000309)
(0.0416)
(0.0729)
M23-O-2
Stack
(0.00239)
(0.00179)
(0.000398)
(0.000398)
(0.000398)
0.0000398
{0.0000119}
(0.00542)
0.000398
(0.000119)
(0.00119)
(0.000318)
(0.000278)
(0.000358)
(0.000398)
{0.0000398}
(0.0000795)
(0.0000119)
(0.00268)
(0.00809)
a Nanogram per dry standard cubic meter at 20°C and 1 atm and corrected to 7 percent oxygen.
() Not Detected. Value shown is the detection limit and is included in totals.
{ } Estimated Maximum Possible Concentration. EMPC values are included in totals.
2-8
-------
TABLE 2.5
PCDDs/PCDFs SAMPLING AND AIR STREAM PARAMETERS
KILN NO. 4 BAGHOUSE INLET AND STACK
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA
Run No.
Sampling Location
Date
Total Sampling Time, minutes
Average Sampling Rate, dscfin b
Sample Volume:
dscfc
dsemd
Average Exhaust Gas Temperature, °F
02 Concentration, % by Volume
CO2 Concentration, % by Volume
Moisture, % by Volume
Exhaust Gas Volumetric Flow Rate:
acfm"
dscftnb
dscmmf
Isokinetic Sampling Ratio, %
M23-4-I-1
Baghouse Inlet
3/23/98
180
0.640
115.145
3.261
878
8,1
20.1
4.6
166,000
61,900
1,750
103.3
M23-O-1
Stack a
3/23/98
180
0.604
108.805
3.081
417
10.0
19.0
14.4
282,000
145,000
4,110
96.0
° The outlet sampling location was downstream of the point where the kiln exhausts merged. Therefore
depending on the parameter, the data presented is either the sum (e.g. flow rate) or the weighted
average (e.g., gas temperature) of the two kilns.
b Dry standard cubic feet per minute at 68° F (20° C) and 1 atm.
c Dry standard cubic feet at 68° F (20° C) and 1 atm.
d Dry standard cubic meters at 68° F (20° C) and 1 atm.
e Actual cubic feet per minute at exhaust gas conditions.
f Dry standard cubic meters per minute at 68° F (20° C) and 1 atm.
2-9
-------
TABLE 2.6
PCDDs/PCDFs CONCENTRATIONS AND EMISSION RATES
KILN NO. 4 BAGHOUSE INLET AND STACK
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA
CONGENER
DIOXINS:
2378 TCDD
Total TCDD
12378 PeCDD
Total PeCDD
123478 HxCDD
123678 HxCDD
123789 HxCDD
Total HxCDD
1234678 HpCDD
Total HpCDD
12346789 OCDD
Total PCDDs
FURANS:
2378 TCDF
Total TCDF
12378 PeCDF
23478 PeCDF
Total PeCDF
123478 HxCDF
123678 HxCDF
234678 HxCDF
123789 HxCDF
Total HxCDF
1234678 HpCDF
1234789 HpCDF
Total HpCDF
12346789 OCDF
Total PCDFs
Total PCDDs + PCDFs
CONCENTRATION "
(ng/dscm, as measured)
M23-4-I-1
Baghouse Inlet
(0.00920)
(0.00920)
(0.0153)
(0.0153)
(0.0184)
(0.0184)
(0.0184)
(0.0184)
(0.0276)
(0.0276)
(0.0307)
(0.101)
{0.00215}
0.0276
(0.00920)
(0.0123)
{0.0184}
(0.0123)
(0.0123)
(0.0123)
(0.0153)
(0.0123)
(0.0184)
(0.0245)
(0.0184)
(0.0307)
(0.107)
(0.209)
M23-O-1
Stack
(0.00325)
0.00974
(0.00649)
(0.00649)
(0.00649)
(0.00649)
(0.00649)
(0.00649)
(0.00974)
(0.00974)
(0.0162)
(0.0487)
(0.00325)
{0.00649}
(0.00325)
(0.00325)
(0.00325)
(0.00325)
(0.00325)
(0.00325)
(0.00325)
(0.00325)
(0.00649)
(0.00649)
(0.00649)
(0.0130)
(0.0325)
(0.0811)
EMISSION RATE b
(Hg/hr)
M23-4-I-1
Baghouse Inlet
(0.968)
(0.968)
(1.61)
(1.61)
(1.94)
(1.94)
(1.94)
(1.94)
(2.90)
(2.90)
(3.23)
(10.6)
{0.226}
2.90
(0.968)
(1.29)
(1.94)
(1.29)
(1.29)
(1.29)
(1.61)
(1.29)
(1.94)
(2.58)
(1.94)
(3.23)
(11.3)
(21.9)
M23-O-1
Stack
(0.800)
2.40
(1.60)
(1.60)
(1.60)
(1.60)
(1.60)
(1.60)
(2.40)
(2.40)
(4.00)
(12.0)
{0.800}
{1.60}
(0.800)
(0.800)
(0.800)
(0.800)
(0.800)
. (0.800)
(0.800)
(0.800)
(1.60)
(1.60)
(1.60)
(3.20)
(8.00)
(20.0)
" Nanogram per dry standard cubic meter at 20°C and 1 atm.
b Micrograms per hour.
() Not Detected. Value shown is the detection limit and is included in totals.
{ } Estimated Maximum Possible Concentration. EMPC values are included in totals.
2-10
-------
TABLE 2.7
PCDDs/PCDFs CONCENTRATIONS AND 2378-TCDD TOXIC EQUIVALENT
CONCENTRATIONS ADJUSTED TO 7 PERCENT OXYGEN
KILN NO. 4 BAGHOUSE INLET AND STACK
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA
CONGENER
DIOXINS:
2378 TCDD
Total TCDD
12378 PeCDD
Total PeCDD
123478 HxCDD
123678 HxCDD
123789 HxCDD
Total HxCDD
1234678 HpCDD
Total HpCDD
12346789 OCDD
Total PCDDs
FURANS:
2378 TCDF
Total TCDF
12378 PeCDF
23478 PeCDF
Total PeCDF
123478 HxCDF
123678 HxCDF
234678 HxCDF
123789 HxCDF
Total HxCDF
1234678 HpCDF
1234789 HpCDF
Total HpCDF
12346789 OCDF
Total PCDFs
Total PCDDs + PCDFs
CONCENTRATION "
(ng/dscm, adjusted to 7 percent O2
M23-4-I-1
Baghouse Inlet
(0.00999)
(0.00999)
(0.0167)
(0.0167)
(0.0200)
(0.0200)
(0.0200)
(0.0200)
(0.0300)
(0.0300)
(0.0333)
(0.110)
{0.00233}
0.0300
(0.00999)
(0.0133)
{0.0200}
(0.0133)
(0.0133)
(0.0133)
(0.0167)
(0.0133)
(0.0200)
(0.0266)
(0.0200)
(0.0333)
(0.117)
(0.226)
M23-O-1
Stack
(0.00414)
0.0124
(0.00828)
(0.00828)
(0.00828)
(0.00828)
(0.00828)
(0.00828)
(0.0124)
(0.0124)
(0.0207)
(0.0621)
(0.00414)
{0.00828}
(0.00414)
(0.00414)
(0.00414)
(0.00414)
(0.00414)
(0.00414)
(0.00414)
(0.00414)
(0.00828)
(0.00828)
(0.00828)
(0.0166)
(0.0414)
(0.103)
2378-TCDD
Toxicity
Equivalence
Factor
1.000
0.500
0.100
0.100
0.100
0.010
0.001
Total PCDDs TEQ
0.100
0.050
0.500
0.100
0.100
0.100
0.100
0.010
0.010
0.001
Total PCDFs TEQ
Total TEQ
2378 TOXIC EQUIVALENCIES
(ng/dscm, adjusted to 7 percent O2)
M23-4-I-1
Baghouse Inlet
(0.00999)
(0.00833)
(0.00200)
(0.00200)
(0.00200)
(0.000300)
(0.0000333)
(0.0246)
{0.000233}
(0.000500)
(0.00666)
(0.00133)
(0.00133)
(0.00133)
(0.00167)
(0.000200)
(0.000266)
(0.0000333)
(0.0128)
(0.0375)
M23-O-1
Stack
(0.00414)
(0.00414)
(0.000828)
(0.000828)
(0.000828)
(0.000124)
(0.0000207)
(0.0109)
(0.000414)
(0.000207)
(0.00207)
(0.000414)
(0.000414)
(0.000414)
(0.000414)
(0.0000828)
(0.0000828)
(0.0000166)
(0.00391)
(0.0148)
" Nanogram per dry standard cubic meter at 20°C and 1 arm and corrected to 7 percent oxygen.
() Not Detected. Value shown is the detection limit and is included in totals.
{} Estimated Maximum Possible Concentration. EMPC values are included in totals.
2-11
-------
TABLE 2.8
AIR STREAM PARAMETERS
DURING PCDDs/PCDFs TESTING ON OPPOSITE KILN
KILN NO. 3 BAGHOUSE AND KILN NO. 4 BAGHOUSE INLETS
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA
Run No.
Date
Sampling Location
Average Exhaust Gas Temperature, °F
O2 Concentration, % by Volume a
CO2 Concentration, % by Volume a
Estimated Moisture, % by Volume a
Exhaust Gas Volumetric Flow Rate:
acfmb
dsctmc
dscmmd
M2-3-I-1
3/23/98
Kiln No. 3
934
5.3
26.6
7.8
189,000
65,500
1,860
M2-4-I-2
3/24/98
Kiln No. 4
885
8.1
20.1
4.6
175,000
65,400
1,850
a O2, CO2, and moisture data taken from non-concurrent Method 23 test performed at same location.
b Actual cubic feet per minute at exhaust gas conditions.
0 Dry standard cubic feet per minute at 68° F (20° C) and 1 atm.
d Dry standard cubic meters at 68° F (20° C) and 1 atm.
2-12
-------
TABLE 2.9
AIR STREAM PARAMETERS
DURING PCDDs/PCDFs TESTING
CO2 BUBBLER SLIPSTREAM OFF KILN NO. 3 AND KILN NO. 4 STACK
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA
Run No.
Date
Average Exhaust Gas Temperature, °F
O2 Concentration, % by Volume a
C02 Concentration, % by Volume a
Estimated Moisture, % by Volume a
Exhaust Gas Volumetric Flow Rate:
acrmb
dscfin0
dscmm d
M2-CBS-1
3/23/98
303
10.0
19.0
14.4
9,260
5,480
155
M2-CBS-2
3/24/98
315
10.0
18.6
14.4
8,230
4,790
136
Average
309
10.0
18.8
14.4
8,750
5,140
146
* O2, CO2, and moisture date taken from concurrent Method 23 test performed at stack location.
Actual cubic feet per minute at exhaust gas conditions.
c Dry standard cubic feet per minute at 68° F (20° C) and 1 atm.
d Dry standard cubic meters at 68° F (20° C) and 1 atm.
2-13
-------
TABLE 2.10
AIR STREAM PARAMETERS
DURING EXTRA HCI TESTING
KILN NO. 3 BAGHOUSE AND KILN NO. 4 BAGHOUSE STACK
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA
Run No.
M2-O-3
Sampling Location
Date
Average Exhaust Gas Temperature, °F
O2 Concentration, % by Volume
CO2 Concentration, % by Volume
Estimated Moisture, % by Volume
Exhaust Gas Volumetric Flow Rate:
acfm"
dscfmc
dscmmd
Stack a
3/25/98
409
10.0
17.7
14.0
272,000
142,000
4,020
a The outlet sampling location was downstream of the point where the kiln exhausts merged.
Therefore depending on the parameter, the data presented is either the sum (e.g., flow rate)
or the weighted average (e.g., gas temperature) of the two kilns.
b Actual cubic feet per minute at exhaust gas conditions.
c Dry standard cubic feet per minute at 68° F (20° C) and 1 atm.
d Dry standard cubic meters per minute at 68° F (20° C) and 1 atm.
2-14
-------
TABLE 2.11
HCL AND THC CONCENTRATIONS AND EMISSION RATES
KILN NO. 3 BAGHOUSE AND KILN NO. 4 BAGHOUSE INLETS AND STACK
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA
Run No.
Date
Kiln Tested
Sampling Location
Total Sampling Time, minutes
02 Concentration, % by Volume
CO2 Concentration, % by Volume
Estimated Moisture, % by Volume
Volumetric Flow Rate, dscfin
Hydrogen Chloride:
Formula Weight, Ib/lb-mole
Concentration, ppmvw
Concentration, ppmvd c
Concentration, ppmvd @ 7% O2 d
Emission Rate, Ib/hr e
Total Hydrocarbons (as methane):
Formula Weight, Ib/lb-mole
Concentration, ppmvw b
Concentration, ppmvd °
Concentration, ppmvd @ 7% O2 d
Emission Rate, Ib/hr e
Total Hydrocarbons as Propane:
Formula Weight, Ib/lb-mole
Concentration, ppmvw b
Concentration, ppmvd c
Concentration, ppmvd @ 7% O2 d
Emission Rate, Ib/hr e
3-1-2 O-2
3/24/98 3/24/98
No. 3 Nos. 3 & 4
Inlet Stack
90 90
5.3 10.0
26.6 18.6
7.8 14.4
54,300 141,000
36.47 36.47
68.5 37.9
74.3 44.3
66.2 56.5
22.9 35.5
16.04 16.04
3.8 (1.0)
4.1 (1.2)
3.7 (1.5)
0.56 (0.4)
44.09 44.09
11.4 (3.0)
12.4 (3.5)
11.0 (4.5)
4.61 (3.4)
4-1-1 0-1
3/23/98 3/23/98
No. 4 Nos. 3 & 4
Inlet Stack
90 95
8.1 10.0
20.1 ' 19.0
4.6 14.4
61,900 145,000
36.47 36.47
10.2 20.4
10.7 23.8
11.6 30.4
3.76 19.6
16.04 16.04
(1.0) (1.0)
(1.0) (1.2)
(1.1) (1.5)
(0.2) (0.4)
44.09 44.09
(3.0) (3.0)
(3.1) (3.5)
(3.4) (4.5)
(1.3) (3.5)
O-3
3/25/98
Nos. 3 & 4
Stack
15
10.0
17.7
14.0
142,000
36.47
27.9
32.4
41.4
26.2
16.04
3.1
3.6
4.6
1.3
44.09
9.3
11
14
11
' Dry standard cubic feet per minute at 68° F (20° C) and 1 atm.
b Parts per million by volume wet.
0 Parts per million by volume dry.
d Parts per million by volume dry, corrected to 7% oxygen.
e Pounds per hour.
() Not Detected. Value shown is the detection limit and is included in averages.
2-15
-------
3.0 PROCESS DESCRIPTION
During the testing, an EPA BSD contractor, Research Triangle Institute, monitored and
recorded kiln process operation data. The Chemical Lime Company has made a claim of
confidentially regarding this data, and EPA designated this data as Confidential Business
Information (CBI). Therefore, no process information or operations data has been included with
this report.
3-1
-------
4.0 SAMPLING LOCATIONS
As stated previously, source sampling was conducted to determine uncontrolled and
controlled emissions of HC1, PCDDs/PCDFs, and THC from two lime kilns located at Chemical
Lime Company's Montevallo, Alabama facility. Testing was conducted at the inlets of each kiln
baghouse, and at the stack common to both baghouses. Figure 4.1 presents the process air stream
schematic showing the testing locations. Descriptions and schematic diagrams of the test
locations are presented below.
4.1 KILN NO 3 BAGHOUSE INLET
The Kiln No. 3 baghouse inlet measurement site was located in a 98-inch inside diameter
(ID) round, vertical duct, 540 inches (5.5 duct diameters) downstream of the nearest flow
disturbance (90° bend) and 420 inches (4.3 duct diameters) upstream of another bend in the duct.
According to EPA Method 1 criteria, this site required 20 sample traverse points, 10 along each
of two perpendicular diameters.
Only two ports were available to accommodate the Method 23 and the CEM sampling
probes. Because of the limited access to the ports, the Method 23 sampling was done using only
one of the traverse diameters. The traverse was conducted twice to achieve the desired test time.
Figure 4.2 shows a simplified schematic of the inlet measurement site and the sample traverse
point locations.
4.2 KILN NO. 4 BAGHOUSE INLET
The baghouse inlet measurement site was located in a 98-inch inside diameter (ID) round,
vertical duct, 540 inches (5.5 duct diameters) downstream of the nearest flow disturbance (90°
bend) and 420 inches (4.3 duct diameters) upstream of the nearest flow disturbance, a bend in the
duct. According to EPA Method 1 criteria, this site required 20 sample traverse points, 10 along
each of two perpendicular diameters. The Method 23 sampling was performed using four ports
to access the two traverse diameters (a half-axis per port). Figure 4.3 shows a simplified
schematic of the inlet measurement site and the sample traverse point locations.
A check for the presence of non-parallel flow was conducted as specified in Section 2.4
of EPA Method 1. The average yaw angle of 2.5 degrees was less than the Method 1
requirement of 20 degrees.
4-1
-------
Test Location
Method 23
/^Test LocationX
( (Method 23 & }
\. Velocity)/
/Test Locations*
(Method 23 &
Kiln
No. 3
Kiln
No. 4
VV
Figure 4.1 Kiln No. 3 and Kiln No. 4 Process Flow Schematic Showing Testing Locations,
Chemical Lime Company - Montevallo, Alabama
4-2
-------
Cross Sectional View
To Quench
420"
540"
a B
GEM
Port
98"
Traverse
Point
Number
1
2
3
4
5
6
7
8
9
10
Distance From
Inside Wall
(inches)
21/2
8
141/4
22
331/2
64 Vz
75%
83%
90
951/2
Note: Due to port
limitations, only one
axis was traversed;
each of the ten points
was sampled twice.
From Kiln No. 3
Figure 4.2 Kiln No. 3 Baghouse Inlet Test Location and Traverse Point Locations,
Chemical Lime Company - Montevallo, Alabama
4-3
-------
Cross Sectional View
C
O 0 O O O OOOOOjjR
To Quench
1
^M*
A
03 —
i
\ —
mm***
i.
420"
[_ Traverse
k Point
Number
^
2
540" 3
4
5
Distance From
Inside Wail
(inches)
2Vz
8
141/4
22 1/4
33 Vi
r
•HUH
From Kiln No. 4
Figure 4.3 Kiln No. 4 Baghouse Inlet Test Location and Traverse Point Locations,
Chemical Lime Company - Montevallo, Alabama
4-4
-------
4.3 KILN NO. 3 BAGHOUSE AND KILN NO. 4 BAGHOUSE STACK
The stack location was located in a 120-inch ID round, vertical stack. Sampling ports
were located 864 inches (7.2 duct diameters) downstream of the CO2 bubbler slipstream
breeching and 422 inches (3.5 duct diameters) upstream of the exhaust to atmosphere.
According to EPA Method 1 criteria, this site required 12 sample traverse points, six along each
of two perpendicular diameters; for purposes of sampling, each of the four half-axes were
accessed using four ports, with three points per half-axis. Figure 4.4 is a schematic of the outlet
test location and the sample traverse point locations.
A check for the presence of non-parallel flow was conducted as specified in Section 2.4
of EPA Method 1. The yaw angle averaged 2.6 degrees, which is less than the EPA Method 1
requirement of 20 degrees.
4.4 CO2 BUBBLER SLIPSTREAM
The slipstream traversing location was located in a 29.5-inch ID round duct between the
common stack servicing Kiln Nos. 3 and 4 baghouses and the CO2 bubbler. Traversing ports
were located 300 inches (10.2 duct diameters) downstream of a bend and 96 inches (3.3 duct
diameters) upstream of the fan. Figure 4.5 is a schematic of the slipstream test location and the
sample traverse point locations.
4-5
-------
Cross Sectional View
120"
Traverse
Point
Number
1
2
3
Distance From
Inside Wall
(inches)
5 1/2
17 1/2
35 1/2
ToCO2
Bubbler
422"
864"
192"
From
Baghouse
Figure 4.4 Kiln No. 3 Baghouse & Kiln No. 4 Baghouse Stack Test Location and Traverse
Point Locations, Chemical Lime Company - Montevallo, Alabama
4-6
-------
Cross Sectional View
A
29"
Traverse
Point
Number
1
2
3
4
5
6
To CO2 Bubbler
96"
300"
Distance From
Inside Wall
(inches)
8%
20%
25%
281/4
Kiln
Nos.
3&4
Stack
Figure 4.5 CO2 Bubbler Slipstream Off Kiln Nos. 3 & 4 Baghouses Stack Test Location
and Traverse Point Locations, Chemical Lime Company - Montevallo,
Alabama
4-7
-------
5.0 SAMPLING AND ANALYTICAL PROCEDURES
Source sampling was performed at the two baghouse inlets and the shared baghouses
stack to determine the concentrations and mass emission rates of HC1, THC, and PCDDs/PCDFs.
One three-hour test run was performed at each location. During the PCDDs/PCDFs testing at
each kiln, velocity measurements were made at the baghouse inlet not being tested, hi addition,
velocity measurements were made at the slipstream from the stack to the CO2 bubbler.
HC1 and THC results are presented in parts per million (ppm), and pounds per hour
(Ib/hr). PCDDs/PCDFs results are presented in nanograms per dry standard cubic meter
(ng/dscm), nanograms per dry standard cubic meter corrected to 7 % oxygen (ng/dscm @ 7% O2)
and micrograms per hour (ug/hr). In Table 5.1, the parameters measured, the sampling methods,
the number of tests performed, and the duration of each test are presented. Brief descriptions of
the sampling and analysis procedures used are presented below.
5.1 LOCATION OF MEASUREMENT SITES AND SAMPLE/VELOCITY
TRAVERSE POINTS
EPA Method 1, "Sample and Velocity Traverses for Stationary Sources," was used to
establish velocity and sample traverse point locations. The process ductwork, and locations of
measurement sites and traverse points are discussed in Section 4,0 of this document.
5.2 DETERMINATION OF AIR STREAM VOLUMETRIC FLOW RATE
EPA Method 2, "Determination of Stack Gas Velocity and Volumetric Flow Rate (Type S,
Pitot Tube)," was used to determine exhaust gas velocity. A Type S Pitot tube, constructed
according to Method 2 criteria and having an assigned coefficient of 0.84, was connected to an
inclined-vertical manometer and used to measure the velocity pressure (Ap) at each traverse
point. The air stream temperature was also recorded at each traverse point using a Type K
thermocouple. The average gas velocity was calculated from the average square roots of the
velocity pressure, average air stream temperature, air stream molecular weight, and absolute
stack pressure. The volumetric flow rate is the product of velocity and the cross-sectional area of
the duct/stack at the sampling location.
5-1
-------
TABLE 5.1
SUMMARY OF SAMPLING LOCATIONS, TEST PARAMETERS,
SAMPLING METHODS, AND NUMBER AND DURATION OF TESTS,
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA
Sampling Location
Baghouse Inlets
(KilnNos.3&4)
Baghouses' Stack
CO2 Bubbler Slipstream
Parameter
Air Stream Flow
Rate
CO2 & O2
Moisture Content
PCDDs/PCDFs
THC
HC1
Air Stream Flow
Rate
CO2 & O2
Moisture Content
PCDDs/PCDFs
THC
HC1
Flue Gas Flow Rate
Sampling Methods
EPA Method 2
EPA Method 3A
EPA Method 4
EPA Method 23
EPA Method 25A
EPA Proposed
Method 322
EPA Method 2
EPA Method 3A
EPA Method 4
EPA Method 23
EPA Method 25A
EPA Proposed
Method 322
EPA Method 2
Number of
Tests
2
1
1
1
1
1
2
2
2
2
2
2
2
Duration,
(minutes)
180
90
180
180
90
90
180
90
180
180
90
90 / 95
20
5-2
-------
5.3 DETERMINATION OF AIR STREAM MOISTURE CONTENT
EPA Method 4, "Determination of Moisture Content in Stack Gases," was used to
determine the air stream moisture content. EPA Method 4 was performed in conjunction with
each EPA Method 23 test run. Integrated, multi-point, isokinetic sampling was performed.
Condensed moisture was determined by recording pre-test and post-test weights of the impingers,
reagents, and silica gel.
5.4 DETERMINATION OF PCDDs/PCDFs
EPA Method 23, "Determination of Poly chlorinated Dibenzo-P-Dioxins and
Polychlorinated Dibenzofurans from Stationary Sources," was used to collect dioxins and fiirans
at each location. In addition, the proposed rales amending Method 23 as published in the Federal
Register, Volume 60, No. 104, May 31, 1995 were incorporated. These proposed rales correct
existing errors in the method, eliminate the methylene chloride rinse, and clarify the quality
assurance requirements of the method.
A multi-point integrated sample was extracted isokinetically from the traverse points
shown in Section 4.0. At each traverse point, sampling was performed for 7.5 (at the baghouse
stack) or 15 (at the baghouse inlet) minutes for a total ran time of 180 minutes per test. The EPA
Method 23 samples were extracted through a glass nozzle, a heated glass-lined probe, a
precleaned and heated glass fiber filter, a water cooled condenser coil and an adsorbent trap
containing approximately 40 g of XAD®-2 adsorbent resin. The EPA Method 23 sampling train
is shown in Figure 5.1.
TLI prepared the filters and adsorbent traps and performed the analyses. The samples
were extracted and analyzed according to EPA Method 23 and the above mentioned proposed
rales amendment. The sample components (filter, XAD, and rinses) were Soxhlet extracted and
combined. The sample was then split with half being archived and the other half analyzed.
Analysis was performed on a high resolution GC/MS.
5.5 DETERMINATION OF HYDROGEN CHLORIDE
EPA Proposed Method 322, "Measurement of Hydrogen Chloride Emissions from
Portland Cement Kilns by GFC/IR," was used to monitor HC1 emissions at each location. The
stack gas sample was extracted from the sampling locations and transported to the HC1 analyzer
(a Perkin Elmer (PE) MCS-100) through a heated sample probe, heated sample line, and a heated
sample pump. Sampling components were maintained at a minimum temperature of 375°F. A
heated three-way valve was attached to the probe assembly .to allow for sampling of stack gas or
for the introduction of HC1 calibration standards. The sample exits the pump and passes through
a heated rotameter and into the analyzer containing the gas filter correlation infrared
spectrometer (GFC/IR). A schematic of this system is presented in Figure 5.2.
5-3
-------
Button Hook
Nozzle
Gas
Flow
TypeS
Pilot Tube
Gas
Exit
Temperature
Sensor
Condenser
Stack
Wall
Heated Glass
Liner
Temperature
Sensor
Inclined Reeireulation
Manometer PumP
Temperature
Sensors
Empty 100 mi HPLC Water Empty Silica Gel
Vacuum
Line
Inclined
Manometer
Vacuum
Pump
Figure 5.1 Sampling Train Schematic for EPA Method 23
-------
Heated
(mln. 3TS»F) Heated Filter Box
Sample line Heated Sample/Calibration Line
PM-10
Cyclon
In-SItu Matrix
Spiking (In*
Perkln-Elmer
Microprocessor
DDDD
Qaa Filter CoirelaUon
Infrared Analyzer
Infrared
Detector
Figure 5,2 Sampling Train Schematic for Proposed EPA Method 322.
5-5
-------
HC1 in the sample cell attenuates an infrared light source. The intensity of the attenuated
beam is measured by a detector positioned at the end of the cell. The amount of HC1 in the
sample gas stream is related to the amount of light attenuated.
5.6 DETERMINATION OF CARBON DIOXIDE, OXYGEN, AND
TOTAL HYDROCARBONS
Continuous Emission Monitoring (CEM) was performed at each baghouse inlet and the
common stack. All CEM data was recorded using a Tracor/Westronics 3000 automatic digital
data logger. The CEM system was housed in the APCC Environmental Monitoring Laboratory
positioned at the base of the exhaust stack. Stack gas was drawn from the stack through a heated
Teflon® sample line (320°F nominal), and sample conditioning system (except the THC sample)
to remove moisture from the gas stream. A leakless Teflon® diaphragm pump then drew the
sample through an unheated dry Teflon® sample line and pump, and through a manifold under
slightly positive pressure with a bypass to the atmosphere. CO2 and O2 samples were
continuously drawn from this manifold to their respective analyzers. A heated sample was
introduced directly to the THC analyzer. Figure 5.3 shows a schematic of the sampling system.
5.6.1 Carbon Dioxide and Oxygen
EPA Method 3 A, "Determination of Oxygen and Carbon Dioxide Concentrations in
Stationary Sources," was used to determine the CO2 and O2 concentrations at both test locations.
An Horiba CMA 321 NDIR analyzer was used to monitor CO2 and O2 concentrations.
This instrument operates on the principle of CO2 having a known characteristic absorption
spectra in the infrared range. Radiation absorbed by CO2 in the sample cell produces a
capacitance change in the detector which is proportional to the CO2 concentration. Oxygen was
measured using the paramagnetic analytical procedure.
5.6.2 Total Hydrocarbons
EPA Method 25 A, "Determination of Total Gaseous Organic Concentration using a
Flame lonization Analyzer," was used to determine the THC concentrations at both test
locations. A VIG Industries Total Hydrocarbon Analyzer, which utilizes a flame ionization
detector (FID), was used to measure hydrocarbons. Approximately 5.0 liters per minute (1pm) of
sample gas is drawn from the source through a heated Teflon® sample line. The sample gas is
drawn through a heated filter and valves by a heated pump. The sample gas is introduced into
the FID chamber and any hydrocarbons in the sample are ionized by a hydrogen flame. The
flame is positioned between two charged plates, and the associated electric field induces the
migration of the ions towards the charged plates. The ion migration results in the generation of a
current, which is directly proportional the amount of hydrocarbons present in the sample.
The analyzer was calibrated using methane calibration gas standards; therefore, the THC
concentrations are in methane-equivalents.
5-6
-------
Stack
Wall
Heated Filter
Sample By-Pass
Vent
By-Pass Flow
Control Valve
\
Total
Analyzer
1
I
I
Data
Acquisition
Figure 5.3 Sampling Train Schematic for EPA Methods 3A and 25A
-------
5.6.3 Data Acquisition and Handling
All data was monitored by a Tracor/Westronics 3000 digital data logger which recorded
using its integral color printer. Trends were monitored using the strip chart mode with averages
printed digitally for 5-minute intervals and/or the test period. Emissions data was "sampled" by
the data logger at 5-second intervals.
5-8
-------
6.0 QUALITY ASSURANCE/QUALITY CONTROL
PROCEDURES AND RESULTS
This section describes the specific QA/QC procedures employed by PES in performing
this series of tests. The procedures contained in the "Quality Assurance Handbook for Air
Pollution Measurement Systems, Volume III, Stationary Source Specific Methods," EPA/600/R-
94/03 8c, and in the reference test methods served as the basis for performance for all testing and
related work activities in this project.
6.1 CALIBRATION OF APPARATUS
The preparation and calibration of source sampling equipment is essential in maintaining
data quality. Brief descriptions of the calibration procedures used by PES follow.
6.1.1 Barometers
PES used aneroid barometers which are calibrated against a station pressure value
reported by a nearby National Weather Service Station corrected for elevation.
6.1.2 Temperature Sensors
Bimetallic dial thermometers and Type K thermocouples were calibrated using the
procedure described in Calibration Procedure 2a of EPA/600/R-94/038c. Each temperature
sensor was calibrated over the expected range of use against an ASTM 3C or 3F thermometer.
Table 6.1 summarizes the type of calibrations performed, the acceptable levels of variance, and
the results. Digital thermocouple displays were calibrated using a thermocouple simulator
having a range of 0-2400 °F.
6.1.3 Pitot Tubes
Type S pitot tubes constructed to EPA Method 2 specifications were used. Pilot tubes
meeting these specifications are assigned to a baseline coefficient to 0.84 and need not be
calibrated. The dimensional criteria and results for each pitot tube used are summarized in Table
6.2.
6-1
-------
TABLE 6.1
SUMMARY OF TEMPERATURE SENSOR CALIBRATION DATA
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA
Temp.
Sensor
I.D.
4E
4F
MB-10
RMB-15
Usage
Stack Gas
Stack Gas
Meter Box
Inlet
Outlet
Meter Box
Inlet
Outlet
Temperature, °R
Reference
534
498
663
799
536
498
664
801
493
536
666
492
536
666
493
534
668
493
534
668
Sensor
534
498
662
800
536
498
664
802
494
536
665
494
537
665
495
534
670
493
535
668
Temperature
Difference
0.0%
0.0%
-0.15%
0.13%
0.0%
0.0%
0.0%
0.12%
0.20%
0.0%
-0.15%
0.40%
0.19%
-0.15%
0.40%
0.0%
0.30%
0.00%
0.19%
0.00%
Tolerances
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
6-2
-------
TABLE 6.2
SUMMARY OF PITOT TUBE DIMENSIONAL DATA
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA
Measurement
a,
«2
Pi
P2
T
e
A
z
w
p,
A/2D,
Criteria
<10°
<10°
<5°
<5°
-
-
-
5 0.125"
£ 0.03125"
0.1875" *
Dt<
0.375"
1.05D,*
As 1.50D,
Acceptable
Assigned Coefficient
Results
Pitot Tube Identification
4E
0
1
1
3
0
1
0.973
0
0.017
0.375
1.30
Yes
0.84
4F
1
0
1
0
1
0
0.94
0.017
0
0.375
1.25
Yes
0.84
RP-21
0
1
1
0
1
0
1.023
0.0179
0
0.375
1.364
Yes
0.84
6-3
-------
6.1.4 Differential Pressure Gauges
PES used Dwyer inclined/vertical manometers to measure differential pressures. The
differential pressures measurements included velocity pressure, static pressure, and rneter orifice
pressure. Manometers were selected with sufficient sensitivity to accurately measure pressures
over the entire range of expected values. Manometers are primary standards and require no
calibration.
6-1-5 Dry Gas Meters and Orifices
The EPA Method 23 dry gas meters and orifices were calibrated in accordance with
Sections 5.3.1 and 5.3.2 of EPA Method 5. This procedure involves direct comparison of the dry
gas meter to a reference dry test meter. The reference dry test meter is calibrated annually using
a wet test meter. Before its initial use in the field, the metering system was calibrated over the
entire range of operation as specified in EPA Method 5. After field use, the metering system was
calibrated at a single intermediate setting based on the previous field test. Acceptable tolerances
for the initial and final dry gas meter factors and orifice calibration factors are ± 0.05 and ± 0.20
from average, respectively. The results for the gas meter and orifice used in this test program are
summarized in Table 6.3.
TABLE 6.3
SUMMARY OF DRY GAS METER AND ORIFICE CALIBRATION DATA
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA
Meter
No.
MB-10
RMB-15
Y
Pre-test
1,021
1.000
Post-test
0.985
1.002
% Diff.
-3.6
0.2
EPA Criteria
± 5%
±5%
Orifice Coefficient
Average
1.72
1.56
Range
1.59-1.79
1.56-1.56
EPA Criteria
1.72 ±0.20
1.56 ±0.20
6.2 ON-SITE MEASUREMENTS
The on-site QA/QC activities include:
6.2.1 Measurement Sites
Prior to sampling, the stack and inlet duct were checked dimensionally to determine
measurement site locations, location of velocity and sample test ports, inside stack/duct
dimensions, and sample traverse point locations. Inside stack/duct dimensions were checked
through both traverse axes to ensure uniformity of the stack/duct inside diameter. The inside
stack/duct dimensions, wall thickness, and sample port depths were measured to the nearest 1/16
inch.
6-4
-------
6.2.2 Velocity Measurements
All velocity measurement apparatus were assembled, leveled, zeroed, and leak-checked
prior to use and at the end of each determination. The static pressure was determined at a single
point near the center of the stack or duct cross-section.
6.2.3 Method 3A (Air Stream Composition) / Method 25A
The field QA/QC activities for Method 3 A and Method 25 A included the use of EPA
Protocol calibration gases; pretest calibration error tests, system bias checks, and response time
tests; and post-test zero and calibration drift determinations. Table 6.4 lists the calibration gas
cylinder numbers, concentrations, and expiration dates. Calibration error tests, system bias
checks, calibration drift checks, and response time checks are shown in Appendix D,
TABLE 6.4
SUMMARY OF CALIBRATION GAS CYLINDERS
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA
Cylinder Number
A018685
A018704
AO 18749
A017718
CC79006
SX-27307
CC46103
CC84096
CC84096
CC60029
CC60029
Contents
10.7 ppm HC1 in nitrogen
26,0 ppm HC1 in nitrogen
37.6 ppm HC1 in nitrogen
101 . ppm HC1 in nitrogen
29.97 ppm CH4 in nitrogen
51.1 ppm CH4 in nitrogen
84.8 ppm CH4 in nitrogen
10.99 % CO2 in N2/O2/CQ2
11.05%O2inN2/O2/CO2
20.2%CO2inN2/O2/CO2
20.4%O2inN2/O2/CO2
Expiration Date
08-26-98
08-12-98
08-25-98
08-12-98
none listed
08-20-99
none listed
03-02-01
03-02-01
04-03-99
04-03-99
6-5
-------
6.2.4 Moisture
The EPA Method 23 sampling train was used to determine the flue gas moisture content.
During sampling, the exit gas of the last impinger was maintained below 68 °F to ensure
complete condensation of flue gas water vapor. The total moisture was determined
gravimetrically using an electronic platform balance with 0.1 gram sensitivity. The XAD®
adsorbent module from the EPA Method 23 sampling train was also weighed and its weight
included in the moisture catch.
6.2.5 Method 23
Table 6.5 summarizes the EPA Method 23 critical field sampling QA/QC measurements
made and the EPA's acceptability criteria. All pre- and post-test sample train leaks met the
acceptance criteria. The isokinetic sampling rates deviated by no more than 4% from 100%,
thereby meeting the method criteria of 90-110%.
EPA Method 23 field blanks were collected near each of the sampling locations to check
for any sample contamination at the sites. Sample trains were assembled and pre- and post-test
leak checks were conducted. The sample trains were recovered in the same manner as the actual
sample runs. Each field blank train was subjected to a minimum of one leak check in the
laboratory and three to five at the sampling site, depending on the location.
6.2.6 Proposed Method 322
Quality control and quality assurance procedures conducted by APCC in the
determination of HC1 by GFCIR are discussed in detail in the narrative which accompanies the
APCC report which was reproduced and is presented in Appendix B-l,
6.3 EPA METHOD 23 PCDDs/PCDFs LABORATORY ANALYSES
Prior to the field testing program, TLI prepared PES' XAD®-2 adsorbent traps and
precleaned the glass fiber filters. TLPs laboratory QA/QC program consisted of adding
isotopically labeled standards to each sample at various stages of the project to determine
recovery efficiencies. The following types of standards were used;
Surrogate Standards were spiked in the TLI laboratory on the XAD®-2 resin prior to the
field sampling program. Recovery efficiencies for these surrogate compounds provided a
measure of the sample collection efficiency and an indication of any analytical matrix
effects.
6-6
-------
TABLE 6.5
SUMMARY OF EPA METHOD 23 FIELD SAMPLING QA/QC DATA
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA
Date
03/23/98
03/24/98
Sampling
Location
Kiln 4 Baghouse
Inlet
Kiln Nos. 3 & 4
Baghouses Stack
Kiln 3 Baghouse
Inlet
Kiln Nos. 3 & 4
Baghouses Stack
Run No.
M23-4-I-1
M23-O-1
M23-3-I-2
M23-O-2
Sample Train Leak Checks
Pre-Test
(acfm)
0.004 @1 5" Hg
0.003 @1 5" Hg
0.003 @ 17" Hg
0.003 @ 15" Hg
Post-Test
(acfm)
0.004 @ 12" Hg
0.001@6"Hg
0.009 @1 8" Hg
0.001 @ 6" Hg
EPA
Criteria
(acfm)
0.02
0.02
0.02
0.02
Isokinetic Ratio
Actual
(%)
102.8
97.4
103.7
102.3
EPA Criteria
(%)
90-110%
90-110%
90-110%
90-110%
0\
•ij
-------
Internal Standards were spiked in the TLI laboratory after the field sampling program and
prior to sample extraction. Recovery efficiencies for these compounds were used in
quantifying the actual PCDDs/PCDFs isomers measured in the samples,
Alternate Standards were spiked in the TLI laboratory after the field sampling program
and prior to sample extraction. Recovery of these compounds indicated the extraction
efficiencies.
Recovery Standards were added in the laboratory after extraction just prior to GC/MS
analysis.
Table 6,6 summarizes the recovery efficiencies for the various standards and the
respective quality control limits. In general, the recovery efficiencies for the XAD® blank, field
blank, and samples were all within the method QC limits. Refer to TLPs case narrative for their
discussion of any quality control anomalies.
6-8
-------
TABLE 6.6
SUMMARY OF EPA METHOD 23 STANDARDS RECOVERY EFFICIENCIES
CHEMICAL LIME COMPANY - MONTEVALLO, ALABAMA
FULL SCREEN
ANALYSIS
Internal Standards
2378-TCDF
2378-TCDD
12378-PeCDF
12378-PeCDD
123678-HxCDF
123678-HxCDD
1234678-HpCDF
1234678-HpCDD
12346789-OCDD
Surrogate Standards
2378-TCDD
23478-PeCDF
123478-HxCDF
123478-HxCDD
1234789-HpCDF
Alternate Standards
123789-HxCDF
234678-HxCDF
CONFIRMATION
ANALYSIS
Internal Standards
2378-TCDF
Percent Recovery
TLI
M23
Blank
65.8
67.9
68,6
99.4
68.1
78.7
83.7
92.5 '
83.0
87,9
106
108
114
90,1
84.5
81.8
69.2
M23
-4-
1-1
71,2
78.1
68.5
71.8
119
115
115
116
103
83.3
89.3
78.3
75.5
83.6
82.4
114
80,4
M23
-3-
1-2
73.1
74.0
64.9
68.3
87.9
93.0
100
107
95.4
84.7
88.8
81.0
75.6
85.1
90.3
78.2
73.5
M23
O-l
22.9
22.3
25.6
31.3,
35.4
36.3
33.7
38.7
25.1
92.6
107
91.3
99,4
84.8
38.5
39.2
21.4
M23
O-2
57.4
54.3
54.4
62.6
74.0
71.9
67.7
77.0
47.7
87.1
98,8
91.0
95.9
82,2
66.8
73.2
54,0
FB-1
74.4
63.1
70,1
83.6
72.8
91.7
80.5
106
119
93.5
106
90.4
92,9
110
84.9
87.4
*
FB-2
70.4
66.2
72.1
95.3
96.7
104
102
133
114
92.1
107
84.6
85,0
82.6
85,6
87.6
73.7
RB
1-4
66.0
59.9
62.5
76.1
81.6
97.6
82.8
101
115
83.8
101
82.5
82.5
95.2
87.7
89.1
*
QC Limits
40-130%
40-130%
40-130%
40-130%
40-130%
40-130%
25-130%
25-130%
25-130%
70-140%
70-140%
70-140%
70-140%
70-140%
40-130%
40-130%
40-130%
: Confirmation analysis was not necessary on these samples since no TCDF's were detected in the full screen analysis.
6-9
-------
APPENDIX A
RAW FIELD DATA
-------
Appendix A. 1
Raw Field Data
Kiln No. 3 Baghouse Inlet
-------
TRAVERSE POINT LOCATION FOR CIRCULAR DUCTS
Plant:
Date:
2 V
*r? -7-
Sampling Location: /<:t» 3 ^
Inslde of Far Wall to Outside of Nipple:
Inside of Near Wall to Outside of Nipple (Nipple Length):.
Stack I.D.: 1&'' -> 5^--
Distance Downstream from Flow Disturbance (Distance B):
inches / StacKiD, - $•$ dd
Distance Upstream from Flow Disturbance (Distance A):
^26 inches / Stack I.D. - **
Calculated Bv:
dd
Sampling Location
Traverse
Point
Number
r
-Z-
3
Y
^
c-
•7
f
?
^0
Fraction
of
Length
.O2.C
.C§2_
f^G
.Z.2.O
• 5^Z
• 058
.TTf
.SS^f
,Js?.6
/oo y-z^
-------
GAS VELOCITY AND VOLUMETRIC FLOW RATE
Plant: Ck>«*:<-u\ L.^, iHeM-autUa Date: 3~25-£$
Sampling Lg
Dim^t* J2—C
cation; XHn^3 JT^OH- , Clock Time: ^^5
fc P... i^t
nun *. _Tk3t. Tf~~ i\ i«v
Barometric F
Moisture, %:
Stack Dimen
Wet Bulb, °F
Travtre*
Point
Number
A /
2
3
y
5
Is
1
'7
5
Is
7
%
d>.S^
QAl
(^4^
(§^
634 -
H/
^p-M^r
Stack
T»mp.
Op
-
801
K4f
*m
0^4
s^
q<^/
-
W\
<^
QtCf
<\(f
j^qio
*-%&'
rt&-,>f*«r ^-7^
e1: ^f* Side 2:
Bulb, °F:
Md - (0.44x%CXDfe) + (0.32 X%0^) + (0.28 X%f^)
Md - (0.44X ^2. } + (0.32xf ) + (0.28x 5
Md-
% H.O % ^0
Me-Mdx(1 1QO ) + «( 10(J ,)
y/M.-( y4X(l--155-)+18(-j3r)
M»»
T5- °F- °R(0F + 460)
-^? Pn » Pb t 8-Pl - { ) + — "-
1S.S 13.S
P»- in. He
flP.
^ .^^rp
t^O^TZQ .... Ta^R)
^cy-'M^xcpx&px-y p,xMt
X?.6>d)
Yfc _ 85,49 x ( ) y ( ) * < /.„ „. _„_
Vc- ft/s
A.- «2
Qa-VsxAsxeOs/m
Qs- x xeo
Q,- hO ^3 acfm
Pa %H,O
Q.rtd-Q,x17.e47x — x(1.-j^-)
Q, „. X17.647X x(1 )
«td -joo
Q»«»d- 16 ^S^jLcfm
-------
FIELD DATA SHEET
Sampling Locatiojri '
Run Number: -OT~
Dale:
Pretest Leak Rate: . oO3 efm @ £J_ in. Hg.
Pretest Leak Check: Ptol: s/Orsal: —-
Sample Type: t
Pbar: 3o,s
C02: JZ_
n-E?i Operator: ~Tfr/Mw\
Ps:
02:
_. / <4
i t f
°\
Probe Length/Type:
Slack Diameter: ' ffi *
Pitot #:
As: 5z.3.g...
Nozzle ID: ,3l Thermocouple
Assumed Bws: ,ak Filter #:
Y:
Meter Box #: /O
Post-Test Leak Rate: ,c?oj>_ cfrn @/|_ in. Hg.
Post-Test Leak Check: Pilot: wOrsat: ~—
Tramrae
Point
Numbe
0
Samplinf
Time
(mln)
TJ
CSockTIme
(24-hour
ckxA)
Gas Meter
Reading
(Vm)ft3
Velocity'
HeadJ^p
inH2O
Pressurn Oiflerenttal
In H2O
Desired
Actual
Stack
T»mp,
(Ts|
Temperature
O c
F
Filter
Impinger
Temp.
Op
Dry Gas Meier Temp.
Intel
(Tm in°F)
Outlet
(Tm out°F)
Pump
Vacuum
(in. Hg)
-35
l.V
S
/r
l.l
353-^
_Z2_
'•Z.
_^1
.35
1,
7
37* '
//t
57
I--L
SC
/O
_!
9S
/O
389, 270
&>
/c
.fo
,9
-55
^20.
2fO
1.2
. -Z.
1. I
7
HIJ. :•
hi
-//£,
2.4 1
47
1,4
£.#0
•V7
7.S
16
7
76
12.
ni
J.L
7-T
2^0
^=102-
Tm=
-------
MULTI-METALS SAMPLE RECOVERY DATA
3Iant: CW-uiwe wWvfuvr^c* Run No.: VV\l"5-r'i-
Date: 3/24 {%% Sample Box No.: Job No.: fa\*l , QXL
Sample Location: bfVfci-tou-Si? Wctr . • ^ (^ A s
SampleType: US -ISJ^ $W«i> ~*>
Sample Recovery Person: v\AOfl^
Container Description Volume, ml
Sealed/Level Marked
Front Half ':"""' " ' ' "' * ! *• ':-' ** -"'"" """' °"-: "-"- ^"^t "'"' ^
1 Filter No.(s)
2 Acetone Rinse
3 Nitric Rinse
4 Nitric Rinse - Imp. 1 ,2,3, + Back 1/2 Filter
5A Nitric Rinse - Impinger No. 4
5B KMNO4/H2O Rinse - Impingers 5 & 6
5C HCl Rinse - Impingers 5 & 6
Moisture^ Datai^ff ^":> "" '"' /": *7- !A ^-:\ '""-;*.' "' ' :'" *'
Impinger
No.
YAO
(
^
1
4
Total
Contents
V(V^ «?,«
¥-0.
\*ijC3
i\^C|
^G\
Initial
Volume, ml
_
t>
ISO
O
-
Weight, grams
Initial
tn-
8B9.C
Net
Comments:
-------
Appendix A.2
Raw Field Data
Kiln No, 4 Baghouse Inlet
-------
I30E3
TRAVERSE POINT LOCATION FOR CIRCULAR DUCTS
Plant:
Date:
3
Sampling Location: & ^ IT
inside of Far Wall to Outside of Nipple: A3 4^
,, /' »
Inside of Near Wall to Outside of Nipple (Nipple Length): 7 +2
Stack I.D.:
Distance Downstream from Flow Disturbance (Distance B):
* HC SHO inches / Stack I.D. = 5" S dd
Distance Upstream from Flow Disturbance (Distance A):
inches / Stack 1.0. =
dd
Calculated By:
/(=
\
Schematic of
Sampling Location
Traverse
Point
Number
i
Z
3
1
_5
Fraction
of
Length
<5.cu6
. o?2.
.^6
.•feo
5^Z
Length
(inche^
i%
\
i
Product of
Columns 2 & 3
(To nearest 1/8")
2 &
£.
/^^
- 2^ *V
33 ^
Nipple
Length
(inches)
U"
i,
U
Traverse Point
Location
(Sum of Col. 4 & 5)
• •$?&_
^
2£>J^_
;#>/
3rf A
-------
GAS VELOCITY AND VOLUMETRIC FLOW RATE
^i*i#
S
o
o
"7
S
0
1
1
i(
a
b
H
^
£?
H
*i
D
H
C;
O
6
O
t>
^
JS
S
&ts/L.
^w
C 0^
£ i"
(_ i^
^M>
^ uy
r,&
/i.^
^— ^.
>
Plant: A^,^(L - CIK^Un^ Date: 3-22-v*
Sampling Lo
Run#: jfe
Barometric F
Moisture, %:
Stack Dimen
Wet Bulb, °F
Trnnret
Point
ft? Nymbw
/ /
£
3
f
5
G
* f
3-
4
f
5
6
i i
z
';
*t
5
k
3 /
• I-
3
t
5
Cft
&* I
HI
cation: 3^6.-+ -K«^*M- Clock Time: <352-
UmnMi Ooerators: T'f/tf"7
1^/1
,5O
•^
.^3
-21
^p". ^£Jl/^
Stack
T*mp,
°F
-Kf&
1 %l y-v
76/
6?S
6gc
566
^•DD
' 7«o
T7I
7S2.
7Cc>,
65^
*?n
1€£
^}
-tft-
1H
1,35
1st
in
9,76
"7?G
OZ-3
5fO
?•-
,3/-?3"
e1: Side 2:
Bulbr°F:
Md • (0,44 X %CO£) 4- (0.32 X KO^,) -I- (0.28 x %Nfe)
Md-(0.44x ) + (0.32x ) + (0.28x )
Md-
IJHgO %HgO
Urn _ HM vH. .* 1 l. 1H ( • * ^
Ms-MdxO -iw )+«( 10Q )
M.-( )X(1.__)+18(__)
M»-
Ti- °F- 8R(°F + 4K«
Pt - Pb +J5:E:_ - { ) + -
n "» + 13J i JT 138
Pi- In. Hg
€F-
^ J Ta^Ffl
V.-W,.4»xCpx^P^
-------
GAS VELOCITY AND VOLUMETRIC FLOW RATE
Plant:
Sampling Location: K .'M
Run#:_.
I \ o
Date: 5-
Clock Time:
Barometric Pressure, in. Hg: 30.Q
Moisture, %: /«. Q Molecular wt., Dry:.
Stack Dimension, in. Diameter or Side 1:
Wet Bulb, °F: Dry Bulb,°F:_
Operators:.
Static Pressure, in. HgO:__
_____ Pitot Tube, Cp:.
' Side 2:
Travtrw
Point
Number
I
2,
'3
H
£
i
Z
3
y
^
t
z
3
H
5
1
2-
3
V
^
Velocity
H«ad
In.H^O
,Sf
«3Tx, ~^
•38
• lu
* /?
/«5
.21
.36?
,32
./f
" .45
.42.
.5D
. ^6?
.2i
,7
<\oo
^15
^oV
?1o
^63
oj/O
^lO
^6>
f£D
TS-^f^
Md » (0.44 X KCQy) + (0.32 x %O2) 4- (0.28 x %l^}
Md - (0.44 X (rZ- ) + (0.32 X T }-l-(0.2ax )
Md- 3O-Z^
«H.O %H_0
* \ j. p / •*
15- °F-
p..pb+J^..(
i3.e
P.. 22. In.HB
) +
13.S
V«-85.48 X(
v8- S7.o w
A.- 57.5? «s
Qa » VsxAsxBOa/m
Q»« x
i
)x(
T«f^
)x
\
x60
100
•td
X17.B47X-
too
-------
FIELD DATA SHEET
Operator;
Sampling Location _gTV>UaHr Kiln'
RunNumber: if- I Date: ?>-%
Sample Type: _
Pbar: 30.00
CO2:
72
Pretest Leak Rate: ^CD£_ cfrn @ /.5 in. Hg.
Pretest Leak Check: PHot:
-------
MULTI-METALS SAMPLE RECOVERY DATA
^23 -T *J.
/•"> | * A ,
Plant: Ofen-tw^ tvvw&utkjuo . fyl^ Run No.: IVH^e-ak'sI
Date: ?/??/ 6tofa/*U ^:Vr'-v^, - .,-"- "^ v -if "• iJ-* v^^*-- V " v>^ : Jx>' v;i
Nitric Rinse - Imp. 1,2,3, + Back 1/2 Filter
Nitric Rinse - Impinger No. 4
KMNO4/H2O Rinse - Impingers 5 & 6
HCI Rinse - Impingers 5 & 6
Impinger
No.
IM.
\
-i
3
4-
*~
Total
Contents
!B,t7
¥.0
or \^*
f)l vka
WTT
^ 6*1.
Initial
Volume, ml
—
D
\cw
VO^
0
—
Weight, grams
Initial
^"5.6
4-^.1
6^,>
G^o
6^-c
A^.5
Final
?\6-l
^Si€
(s8^- 1
(0Qo^
Net
r.-7
57.7
^.6.C
^7.^*-
7S
^Z$~f * >^»
. x\ c^
1 i *-^L^**^'
Comments:
-------
MULTI-METALS SAMPLE RECOVERY DATA
lant:
SL Wl»Ato4ftvuf
Run No.: WiV\*-l
Date:
Sample Box No.:
Job No.:
Sample Location: i
M:
Sample Type: \NW»
vW>
ample Recovery Person: V\M)if$\
Container Description
Volume, ml Sealed/Level Marked
FroritHalf'
1
Filter No.(s)
Acetone Rinse
Nitric Rinse
Nitric Rinse - Imp. 1 ,2,3, + Back 1/2 Filter
5A
Nitric Rinse - Impinger No. 4
5B
KMNO4/H2O Rinse - Impingers 5 & 6
5C
HCl Rinse - Impingers 5 & 6
Impinger
No.
Contents
Initial
Volume, ml
Weight, grams
Initial
Final
Net
HM
iko
0
530.6
ea
Total
Comments:
-------
Appendix A.3
Raw Field Data
Kiln No. 3 Baghouse and Kiln No. 4 Baghouse Stack
-------
TRAVERSE POINT LOCATION FOR CIRCULAR DUCTS
Plant:.
Date:
L>*C
D
Sampling Location: fc
Inside of Far Wall to Outside of Nippla: \ > G 74-
Inside of Near Wall to Outside of Nipple (Nipple Length):
Stack I.D.: [±
Distance Downstream from Flow Disturbance (Distance B):
inches / Stack I.D. = 7>
Fraction
of
Length
, 044-
. Ufe
v^A
Length
(inches)
Uo
V
Product of
Columns 2 & 3
(To nearest 1/8")
5-^0
I a j
3y-jr
Nipple
Length
(inches)
cff
V
Traverse Point
Location
(Sum of Col. 4 & 5)
I/. 7*
3L3 , >^
^-(. 7^
-------
50
Duct Diameters Upstream From Row Disturbance* (Distance A)
0.5 1.0 1.5 2.0 2.5
£30
1
i
20
10
T
T
I
24
20
16
Velocity (Non-Particulate)
1
16
12
8
1
1
1
Flew
DrturiMiiem
2 3 4 56 7 8 9 10
Duct Diameters Downstream From Row Disturbance* (Distance B)
* From Point of Any Typ« of DMuifeanc* (i*nd, Expunion, Contraction, Me)
LOCATION OF TRAVERSE POINTS IN CIRCULAR DUCTS
(Fraction of Stack Diameter from Inside Wall to Traverse Point)
Traverse
Point
Number
on a
Diameter
1
2
3
4
5
6
7
8
9
10
11
12
Number of Traverse Points on a Diameter
4
0.067
0.250
0.750
0.933
6
0.044
0.146
0.296
0.704
0.854
0.956
*
8
0.032
0.105
0.194
0.323
0.677
0.806
0.895
0.968
10
0.026
0.082
0.146
0.226
0.342
0.658
0.774
0.854
0.918
0.974
12
0.021
0.067
0.118
0.177
0.250
0.356
0.644
0.750
0.823
0.882
0.933
0.979
-------
GAS VELOCITY AND VOLUMETRIC FLOW RATE
3
^
JT
e
6
G
5
f
7
c
C
C
b
Q
O
S
&|
°l
CV
cation: & *-4 ^-n— Clock Time: * <*"-'0 .
;R£l(Mf/ofvxr. • ^'" Ooerators: "T^
3ressure, in.
i3,6>
Ha: Static Pressure, in. HnO: ^ , *72-
Molecular wt. Drv: Pitot Tube" Cry ,&4
ision, in. Diameter or Sid
-: Dry
Vatadly
Haad
In. H20
0?
.^f
,//^
.-7S
.-77
.^/
^Z
.^
.30
'19
' >f&
.*7. - { } + -
13.8 ' 13.8
Pa - In. Hg
^P-
== J Ta^R)
Va - 85.49xCpx &P x ^| — p>xMa
Va-aSJayf )»( )r x xeo
Qa - acfm
Pa %K,0
0^-0«1TMrx~xei.-JL-)
o-rtd- X17-M7X « (1 - -^-)
Q«Btd" dacfm
-------
GAS VELOCITY AND VOLUMETRIC FLOW RATE
Plant: £ncm KAL LIME
n>1o»jTe.vfcL.i.o
Date: 3-
Samplino Location:
Run#; m2- £?-
j **¥
Clock Time; J-/0
Operators:
Barometric Pressure, in. Hg: 30.0 _ Static Pressure, in. HUP: -
Moisture, %: _ Molecular wt,, Dry: _ PitotTube, Cp;
Stack Dimension, in. Diameter or Side 1: /&' '- /zo" Side 2:
Wet Bulb,°F:^
Dry Bulb,°F;
TravcrM
Point
Numbtr
A /
Z
3
& I
2
2
c /
^
3
h /
^
^
V«k>dty
H«ad
ln.H20
0.1*1
8,B2>
o$o
0.s4
0> 1g
O.BI
A.4O
#, b2
O.L4
f)<47
Q,k>2
0.13
^F-^a?7y
Stack
Temp.
°F
407
4/3
^11
3M.
4/S
4/4
3B2
401
4/0
4o^
4l2~
t/l,
TS- Wf
Md • (0.44X%CX%) +
Md>(0,44x ) + (0.32x
Md-
(O.Z8x
M»-
TS- °F-
^islfl "
Pi- In. Hg
ff-
v»-a5.4oxCpx
Vs-65.48 x(
vt- n/a
Ai- ft
Qt - VsxAsxeOa/m
Qt-
Of
..
•W
acfm
Pa
MMHIIIIWWM'
Tt
x 17.047 x-
13.0
PsxMa
X60
%^0
100
100
dacfm
-------
FIELD DATA SHEET
Plant
Sampling Location
Run I
> i .,
j-£u
-\ Date: h 3>-v^
Pretest Leak Rate: ,00%, cfm @ jS_ in. Hg.
Pretest Leak Check: Pitot: y Orsat: *.„.
Sample Type: jO->
Pbar: J>o.G
CO2:
Operator: _Q'
Ps: - . 4?
. \V 02: i.
ProbeLength/Type: VC^o^..^
Stack Diameter: ir\' As:
Nozzle ID: _{_X$__Thermocouple #: f
Assumed Bws: | > Filter #:
Meter Box #.T~nO-i5
i. °?^
Pitot
Post-Test Leak Rate: ( dp^ cfm @ Q in.
Post-Test Leak Check: Pitot: lX Orsat: ^
Point
Nunber
SamplinB
Tkno
(rrtn)
Clock Time
(24-hour
Gas Meier
Rending
(Vm)tt3
Valocrty
Headjfip)
inH2O
Oifloe Pressure OHtoranttal
(AH) in HZO
Desired
Actual
Stack
Temp,
Temperafyr*
Op
Probe
Fitter
Impinger
Tamp.
°F
Dry Gas Meter Temp,
Met
(Tm in°F)
Outfet
(Tm out°F)
Pump
Vacuum
(in. Hg)
T.QO
C.C
A » \ -
V of- \ ^
VN
S3
s
ovs-v
\ L-
fcl
s
A^_
5.
53,5
0
'v-S
Vo*
Co
J"
66
s
TO
-TO
67.
3-
/.V
S3
(bV
61
J ")
ill
Us
J4^
fe-J
fol
JT
t. 3
Co
bl
6-7
los
Vlt.s
fcl
6?
3-
V-b
^n
T-S I
i£L
11
G1
G.1
JL
ro
/o
Ci
j"
\QCp-0
5"
41
\\o ,
, is
-7-53
JJL
13
10
13
So
=F
So
^O.
vap
-------
FIELD DATA SHEET
\ciyi
Plank
Sampling Location
Run Number:
Pretest Leak Rate:
-3-Date:
cfm
Pretest Leak Check: Pilot:
JL 'n. Hg.
i/Orsat:
Sample Type:
Pbar: ^ °
C02: \
Operator:
Ps: -
\L>- 02:
Probe Length/Type: V GU,
Nozzle ID:
<=• /. ^£?C7 .&,,;,•
Thermocouple^ *: f fc
Filter #:
y:
Pitoi
Bws: _
Meter Box #: ^n
Post-Test Leak Rate: ,00) cftn @G_ in, Hg.
Post-Test Leak Check: Pilot: (/ Orsat;
Oriflca Pr«s&um Difterentiai
(AH) in H2O
-------
MULTI-METALS SAMPLE RECOVERY DATA
Plant:
: ( Iten ti
i?vi&
Run No.:
Date: 3
Sample Box No.:
E
Job No.:
Sample Location:
Afctatf?
( ^ € »M
Sample Type: US ePA Vl/WnW) 1?
Sample Recovery Person:
Container Description
Volume, ml Sealed/Level Marked
FroitHafr
1
Filter No.(s)
Acetone Rinse
Nitric Rinse
Nitric Rinse - Imp. 1,2,3, + Back 1/2 Filter
5A
Nitric Rinse - Impinger No. 4
5B
KMNO4/H2O Rinse - Impingers 5 & 6
5C
HCI Rinse - Impingers 5 & 6
Impinger
No,
Contents
Initial
Volume, ml
Initial
Weight, grams
Final
Net
vrvo
4A2.0
. >
3 5 3, |
1. 5
6
2-
Total
Comments:
-------
MULTI-METALS SAMPLE RECOVERY DATA
Plant:
Run No.;
~c z
Date:
Sample Box No.:
Job No.: £to. - ou"£-
Sample Location:
3-H-j-
Sample Type: U£
Sample Recovery Person:
Container Description
Volume, ml Sealed/Level Marked
FfontHalf
1
Filter No.(s)
Acetone Rinse
Nitric Rinse
Nitric Rinse - Imp. 1 ,2,3, + Back 1/2 Filter
5A
Nitric Rinse - Impinger No. 4
5B
KMN04/H20 Rinse - Impingers 5 & 6
5C
HCI Rinse - Impingers 5 & 6
Impinger
No.
Contents
Initial
Volume, ml
Weight, grams
Initial
Final
Net
o
.0
Total
Comments:
-------
MULTI-METALS SAMPLE RECOVERY DATA
Plant: 1 <^MA. - I irvxe uWtevAHt-e
Date: ?/?*
. -r^i'-vH1- " , ". . • '- • v /1; -"
Impinger
No.
Xi\D.
»
I
?
4
. 5
Total
Contents
W V^vM
K.b
4^e Vkd
A 6
yv\r
^G*l
Initial
Volume, ml
~
6
V(X>
\u>
o
_
Weight, grams
Initial
m-*
W5A
•^78,5
lil.6
q?e.<^
^12-8
6»4.8
Cftl.R
Net
Comments:
-------
Appendix A.4
Raw Field Data
CO2 Bubbler Slipstream
-------
TRAVERSE POINT LOCATION FOR CIRCULAR DUCTS
Plant:
Date:
Sampling iocatfon:
_$ /i
Inside of Far Wall to Outside of Nipple:.
Inside of Near Wall to Outside of Nipple (Nipple Length):.
Stack I.O.:
2-7.5"'
Distance Downstream from Flow Disturbance (Distance B):
2$' inches/StackI.D. = fo.Z- dd
Distance Upstream from Flow Disturbance (Distance A):
^ inches / Stack I.D. « J^_
Calculated By:
dd
8
Schematic of
Sampling Location
/
Traverse
Point
Number
i
2-
3
f
I
2-
"J
M
r
t
Fraction
of
Length
"^TD^
a % Co
o-^ro
^.133-^
.0^
o.iML
O.V^tr
o.foM-
o^cH
o-^ce
Length
(Indies)
2.0
h*f ~
22.1 ^
-"2T?
^.r
71,C
VJ.C
n<"
^i-
to. V*-
*C(1
ZS>o
Nipple
Lengtti
(inches)
4-
— ^_
f-
1
H
f
¥
f
tf-
Traverse Point
Location
(Sum of Col. 4 & 5)
^^r^
II %
xC
^^^T^-i^
$ %
g'/f
IT. %
•»(^
•2-1 '/S
S^.Vf
-------
<3AS VELOCITY AND VOLUMETRIC FLOW RATE
Plant:
Date:
Sampling Lo
Run #: 1
Barometric P
Moisture, %:
Stack Dlmen
Wet Bulb, °F
Travarea
Point
Number
fc i
1_
3
4
r .
6.
£ '
7-
1
M
<•
c,
cation: C£>i_ IStJEgteR. (V//k;/>-e*/*iJ Clock Tirrfe:
C\k
3%o
.-
T«- 3^2*
31: »?•$> , Side 2:
3ulbr°F:
Md«(0,44X ) + (0.32X ) + (0.28x )
Md-
%H_0 %H,0
Mn <• Md * M > _. --— ^ + 18 f " — ^
1CX5 iOO
Ma-
li- °F- 0R(°F + 460)
tke 13.1
Pt - in. Hg
_ f T«^if
Vs - 85.48xCpx /AP x "U — STxMa —
Va-^4?K< ^4 }*{ ^ )xil ^"^
V ^«X-^)
Ai« 4^^ *Z
Qs «» Vs x As x 60 s/m
08= X XflO
Oi- 1 s 13 •**"
P» *K,0
Qi^j-Ctoxt 7.847 x x(1- =— )
•ta ft 100
•w -](^ 100
-------
\/
: CtteH -
Plant:
Sampling Location:
Run#: wi-E-
GAS VELOCITY AND VOLUMETRIC FLOW RATE
Date:
Clock Time:
Operators:
Barometric Pressure, in. Hq: 3o.lf _ Static Pressure, in.
Moisture, %: _ Molecular wt., Dry: _ PitotTube, Cp:
Stack Dimension, in. Diameter or Side 1 : _ Side 2:
Wet Bulb, °R.
Traversa
Point
Numb«r
A-J-
- 1
- A
6
fo-l
-C
-6
Velocity
Head
in. H20
Stack
Temp.
DryBulb,°F:
Md-
2,80
331
s-
Md - (0.44 X
Md-
Ma-(
Ms-
15-
) + (0.32 X ) + (0.28 X
°R (°F + 480)
13.8
laHfl
V»- 85.40 xCpX
Vs- 85.40 x(
As-
Pax Ma
)x
ft/8
Qa = VaxAsx60a/m
xOO
Qs-
acfm
Q»atd-
X 17.647 X-
dscfrn
100
-------
APPENDIX B
CEMS AND ANALYTICAL DATA
-------
Appendix B.I
CEMs and Analytical Data
CEMs, Methods 3A, 25A, and 322
-------
AIR POLLUTION
CHARACTERIZATION
AND CONTROL, LTD.
Mr. Frank J. Phoenix, PE
Pacific Environmental Services, Inc.
POBox 12077
Research Triangle Park, NC 27709-2077
919-941-0234 FAX
Dear Frank:
30 April 1998
APCC Project 98018 Revision (1)
Air Pollution Characterization and Control, Ltd. (APCC) was retained by Pacific Environmental
Services (PES) to perform Hydrogen Chloride emission measurements utilizing Draft EPA Method 322
and gas filter correlation infrared (GFCIR) technology. APCC performed these measurements with a
Perkin Elmer (PE) MCS-100 GFCIR during the week of 23 March 1998. It should be noted that APCC
developed and successfully validated the test method for HCI by GFCIR, now tentatively identified as EPA
Method 322, during a project performed for the cement industry and in conjunction with Portland Cement
Association (PCA),
PES was contracted by US EPA OAQPS Emission Measurement Center, Emissions Standards
Division to perform emission measurements from Lime Kilns in Alabama. Measurements were performed
at the following facilities;
Company
Location
Chem Lime
Chem Lime
• Dravo
Alabaster, AL
Montevallo, AL
Saginaw, AL
Kilnf
Kilns 3 & 4
Kiln 4
— ~""~' *- i"'t*i»»*»ii»
Wet Scrubber
Baghouse
Baghouse
It was planned to perform a single 180-mlnute test to determine emission concentrations of HCI by
the GFCIR method at each source. The instrumentation was modified at the request of PES and EPA to
operate on a time shared basis, split between the inlet and outlet of air pollution control equipment at each
source (15-minutes on inlet/outlet) to equal 90-minutes of sampling at each location. In hindsight, this
modification may have been the cause of some of the difficulties encountered during the test program.
Kiln Nos. 3 and 4 at the Chemical Lime's Montevallo plant were sampled and analyzed at the inlet
and outlet consecutively over a two day period of time. It should be noted that while all calibrations to the
MCS-100 were successful (HCI calibrations were within the ±7.5% of span), significant trouble was
encountered in attaining the in-sftu matrix spike required by the method. This is described in detail below.
APCC attempted to recover the in-situ matrix spike at the Montevallo facility on 4 occasions while
sampling the outlet for periods ranging from 15 minutes to 1.5 hours. Two unsuccessful attempts to
recover the matrix spike were performed at the inlet sampling system. In order to overcome a possible
filter/lime dust interference the spike gas flowrate was increased to 3 Ipm, but no spike was recovered.
Another unsuccessful attempt of the spike was performed which required the probe to be pulled from the
stack and ambient air drawn through while spiking. Due to time constraints this procedure was only
performed for a period of 15 minutes.
Calibration determinations for the ©2, CO2, and THC analysis were performed in accordance with
EPA Methods 3A and 25A, respectively. The THC analyzer had significant drift (instrument calibrations
exceeding ±5.0%}during the sampling periods on the outlet of Kiln No. 4 at the Montevallo facility. The
instrument drift can be attributed to the length of time between calibrations, significant temperature
changes in the trailer, and pressure changes. Methods 3A and 25A calibration information can be found
on attached Tables C-3 through C-5.
60 Industrial Park Road West
Tolland, Connecticut 06084
(860) 871-8557
(860) 871-8675 FAX
93 Warren Avenue
Portland, Maine 04103
(207) 797-7313
FAX (207) 878-3536
-------
Upon completion of the required test program at the Montevallo facility, APCC modified the outlet
sampling system to achieve the necessary percent recovery associated with the in-situ matrix spike
required by the method. On 25 March 1998, APCC modified the sampling system in order to achieve 15
Ipm sample flow. A single in-situ spike matrix procedure was performed. After an hour of sampling, the
spike indicated an 88% spike recovery, 2.5 ppm of the expected 6.5 ppm was detected. Further
discussion on this issue is presented below. The data are presented in attached Table A-1.
Chemical Lime's Alabaster plant was not sampled, due to process upsets during the GFCIR
equilibrium period that flooded the instrument with scrubber liquor in an aerosol form and caused
significant damage to the PE MCS-100. The instrument was moved to the next facility before the final
repairs and adjustments were completed. No data, therefore, are presented
Kiln No. 4 at the Dravo Lime Company's Saginaw plant was sampled at the outlet only. This was due
to the restricted amount of time remaining after final instrument repairs (time restrictions were imposed by
the plant). It should be noted that not all final calibrations to the instrument were not successful (37.6 ppm
HCI calibration drift exceed the ±7.5% of span). It should be noted that the low end calibration drift was
acceptable. Excess drift was probably due to the rapid schedule which eliminated the analyzer
stabilization period (recommended twelve hours).
Calibrations would indicate that the data was biased high at the upscale end (typical emissions
measured approximately 6 ppm) of the instrument range (0 - 50 ppm). However the instrument was
recalibrated and demonstrated the same concentration (once stabilization was complete HCI was sampled
for 10 minutes) when sampling from the stack. This would indicate that the measurements taken during
the 1.5-hour sampling period would be representative of actual stack gas concentrations at this facility with
limits of the draft method. Data from this facility is presented in Table A-2.
Attached Tables A-1 and A-2 present the results of the sampling periods run for the Chemical
Lime's Montevallo plant and the Dravo Lime Company's Saginaw plant. No data from Chemical Lime's
Alabaster plant was collected. The calibration error/drift tests and in-situ matrix spikes are presented in
Tables C-1 and C-2, respectively.
Calibration and operation of the MCS-100 GFCIR analyzer were straightforward and successful, with
the exception of performance spike recoveries which were demonstrated successful at Morrtevalto on 25
March 1998 only. Based on lessons learned during the PCA method development program discussed
above, a hot sampling system (>375°F) without any cold spots was used to minimize HCI losses. Only one
spike recovery (at Montevallo) met the 100%±30% criteria. This could be the result of a number of factors,
which are discussed below and which also could, most likely, be rectified for further test programs given a
little engineering research and development.
HCI spike gas was introduced into the actual sample stream at the back of the probe and
preceding the heated filter before and following each test performed. All spike recoveries were
negligible with one exception of 88% test spike recovery, as discussed above along with
procedures to improve recovery. Reasons for the consistently low or nonexistent spike
recoveries, when higher than 100% was expected (Method equations tend to bias recovery
efficiency high), are still not known at this time, but there are at least four possible explanations:
• It may be, in part, that the overall flowrate through the sample train played a significant role. Due to
the significantly smaller inside diameter of the plumbing utilized to accommodate the dual
sampling systems, as well as additional heated sample lines provided by PES (1/4" tube vs. 3/8"
typically used), a lower f lowrate than originally operated was achieved by the instrument.
While the PE MCS-100 was designed to operate at 15 Ipm (nominal), the modification utilized to
convert to a time shared system reduced this flowrate to approximately 8 Ipm, slightly more than
half the design flowrate. While performing a matrix spike at the APCC laboratory, it was
determined that a conditioning period of approximately 1-hour at 15 Ipm was required before the
spike could be recovered.
-------
While this worked fine in the laboratory, as well as in the field for calibration purposes; it essentially
doubled the residence time of the sample gas in the sample conditioning system and allowed time
for reactions (i.e. HCI disassociatlon) to take place that may not have occurred with shorter
residence times.
While the chemistry of a lime kiln is significantly different from that encountered during the PCA
program discussed above (i.e. absorption and reactivity of HCI), these differences may be less
significant at increased sample fiowrates and decreased residence times in the sample
conditioning system.
Incomplete spike recoveries were attempted during the initial and final stages of sampling at the
inlet/outlet of Kiln Nos. 3 and 4 at the Chemical Lime facility located Montevallp. Upon completion
of the sampling periods for both kilns, APCC modified the sampling system in order to increase
the sample flowrate. Upon establishment of sampling system equilibrium, the matrix spike
procedure attempted. The spike percent recovery was determined to be 88%, which is well within
the 100% ±30% recovery. Due to time constraints APCC was unable to perform further matrix
spikes.
* A theory was hypothesized on-site that ammonia present in the gas stream could be dissociating
and then reacting to form ammonium chloride with the pure HCI introduced in the spike gas. This
could be verified by calibrating the MCS-100 to measure and record the NHa concentration during
the analytical spike procedures to determine if the NHa is present to interfere with the HCI spike
gas.
• An experiment was performed (at the Chemical Lime facility at Montevallo) using the actual probe,
filter, and heated sample line from the outlet of the lime kiln at Montevallo. Ambient air was drawn
through the system while injecting spike gas to determine the matrix spike recovery. This spike
procedure was performed lor a duration of 15 minutes. During the ambient spiking procedure,
the MCS-100 sample flowrate was still below 10 Ipm, which also caused a slow response. No
spike recovery was not achieved. Had the experiment been allowed to continue, spike recovery
may have been achieved.
• Calibration standards are accurate to ±5%, and are expected to degrade quite rapidly. The gases
utilized for this program should be recertified, as they are beyond the 30-day window specified by
Method 322. It is possible that the actual concentration within the bottle actually is below the
measured analytical standard.
APCC is confident that the difficulties encountered during this initial program can be resolved, as
many were already resolved in the field. The system flowrate problem was resolved in the field by
eliminating the time-shared aspect. Further modifications can achieve both design flowrate as well as time-
sharing. Other modifications prior to subsequent field efforts would include an additional level of refined
filtration. APCC is looking forward to working with PES and EPA and subsequent field efforts for this
project. It was a pleasure performing this test program for you and PES. Feel free to contact me if you
have any comments, questions, or require additional information.
Sincerely,
APCC, Ltd.
Eric C. Dithrich
Senior Engineer
cc: Michael Toney, US EPA
John H. Powell
Principal
-------
Table A-1
HCI Emission Measurements from Two Lime Kilns
Chemical Lime Montevallo Plant
Morrtevallo, Alabama
3/23/98 thru 3/25/98
'ime
Date
inlet/Outlet
HCI
ppmW'
THC
ppmw
02
%
C02
%
Kiln No. 4 &ws Ute**
14:25-14:40
15:05-15:20
15:45-16:00
16:25-16:40
17:05-17:20
17:45-18:00
3/23/98
3/23/98
3/23/98
3/23/98
3/23/98
3/23/98
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Average
10.4
10.7
1p.2
10.1
10.1
9.5
10.2
<1,0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
8.4
7.5
7.9
8.0
8.3
8.4
8.1
19.4
21.7
21.1
20.5
19.2
18.7
20.1
Kiln No. 4
14:00-14:20
14:45-15:00
15:25-15:40
16:05-16:20
16:45-17:00
17:25-17:40
3/23/98
3/23/98
3/23/98
3/23/98
3/23/98
3/23/98
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Average
20.2
21.7
22.0
17.3
21.3
19.7
20.4
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
10.1
10.1
9.8
10.0
10.0
10.1
10.0
18.5
19.1
19.8
19.5
19.0
18.1
19.0
Kiln No. 3
13:50-14:05
14:30-14:45
15:10-15:25
15:50-16:05
16:30-16:45
17:10-17:25
3/24/98
3/24/98
3/24/98
3/24/98
3/24/98
3124m
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Average
80.3
71.9
65.2
57.5
71.4
64.8
68.5
3.7
1.7
5.4
2.1
4.6
5.2
3.8
5.4
5.3
5.2
5.2
5.2
5.2
5.3
25.8
27.3
27.4
26.7
26
26.4
26.6
Kiln No. 3
13:30-13:45
14:10-14:25
14:50-15:05
15:30-15:45
16:10-16:25
16:50-17:05
3/24/98
3/24/98
3/24/98
3/24/98
3/24/98
3/24/98
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Average
0855-0910
3/25/98
Outlet
49.9
46.8
38.5
33.9
30.4
28.1
37.9
27.9
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
3.1
10
9.9
9.9
10
10
10
10.0
10.0
17.8
18.2
19.1
19.2
18.8
18.5
18.6
17.7
NOTE: Ibs/hr calculations include a flowrate of 155,000 dscfm @ 8.0% H2O for the outlet and 63,000 dscfm
@5.0% H2O for kiln #4 70,900 dscfm @ 5.0% H2O for kiln #3.
-------
Table C-1
Montevallo and Saglnaw Calibration Table
Montwallo
CALIBRATION ERROR TESTtMETHOD 6C-6.3) 3/23/98
Kiln *4 Initial Outlet
ZEROQAS
LOW RANGE
MID RANGE
HIGH RANGE
ACTUAL CONC
0
10.7
26
37.6
RESPONSE
0,4
10.7
27.7
38.2
DIFFERENCE
0.4
0
1.7
0.6
% OF SPAN
0,80%
0.00%
3.40%
1.20%
Kiln 14 Final Outlet
ZEROQAS
LOW RANGE
MID RANGE
HIGH RANGE
ACTUAL CONC
0
10.7
26
37.6
RESPONSE
1.1
10.8
27.8
37.5
DIFFERENCE
1.1
0.1
1.8
0.1
% OF SPAN
2.20%
0.20%
3.60%
0.20%
Kiln *4 Initial Inlet
ZERO GAS
LOW RANGE
MID RANGE
HIGH RANGE
ACTUAL CONC
0
10.7
26
37.6
RESPONSE
0.3
8.3
27.4
38.1
DIFFERENCE
0.3
2.4
1.4
0.5
% OF SPAN
0.60%
4.80%
2.80%
1.00%
Kiln *4 Final Inlet
ZEROQAS
LOW RANGE
MID RANSE
HIGH RANGE
Saglnnw
ACTUAL CONC
0
10.7
26
37.6
RESPONSE
1.2
10.2
26.9
38.3
DIFFERENCE
1.2
0.5
0.9
0.7
% OF SPAN
2.40%
1.00%
1.80%
1.40%
CALIBRATION ERROR TESTtMETHOD 6C-6.31 3/26/98
Kiln t4lnlllal Outlet
ZEROQAS
LOW RANGE
MID RANGE
HIGH RANGE
ACTUAL CONC
0
10.7
26
37.6
RESPONSE
0
12.5
24.9
37.6
DIFFERENCE
0
1.8
1.1
0
% OF SPAN
0.00%
3.60%
2.20%
0.00%
Kiln f 4 Final Outlet
ZEROQAS
LOW RANGE
MID RANGE
HIGH RANGE
ACTUAL CONC
0
10.7
26
37.6
RESPONSE
25
12.2
29.5
43.5
DIFFERENCE
25
15
3J
5.9
% OF SPAN
5.00%
3.00%
7.00%
11.80%
Montevallo
QALIBRATION ERROR TESTfMETHOD 60-6.3) 3/24/98
Kiln 13 Initial Outlet
ZERO GAS
LOW RANGE
MID RANGE
HIGH RANGE
ACTUAL CONC
0
10.7
26
37.6
RESPONSE
0.8
10.9
26.3
37.5
DIFFERENCE
0.8
0.2
0.3
0.1
% OF SPAN
1.60%
0.40%
0.60%
0.20%
Kiln tt Final Outlet
ZERO GAS
LOW RANGE
MID RANGE
HIGH RANGE
ACTUAL CONC
0
10.7
26
37.6
RESPONSE
1.1
11.4
28.5
38.9
DIFFERENCE
1.1
0.7
25
1.3
% OF SPAN
2.20%
1.40%
5.00%
2.60%
Kiln 13 Initial Inlet
ZERO GAS
LOW RANGE
MID RANGE
HIGH RANGE
ACTUAL CONC
0
10.7
26
37.6
RESPONSE
0.8
10.9
26.3
37.5
DIFFERENCE
0.8
02
0.3
0.1
% OF SPAN
1.60%
0.40%
0.60%
020%
Klin *3 Final Inlet
ZERO GAS
LOW RANGE
MID RANGE
HIGH RANGE
ACTUAL CONC
0
10.7
26
37.6
RESPONSE
1.7
10.7
25.5
37.2
DIFFERENCE
1.7
0
0.5
0.4
% OF SPAN
3.40%
0.00%
1,00%
0.80%
-------
Table C-2
HCI In-Situ Matrix Spike
Recovery Efficiencies
Plant
Date
Project No.
Tesfl
Initial
Chem Lime Montevallo.AL
24-Mar-98
97018
Su-Native Concentration (ppm)
Qt-Analyzer Ftow 0pm)
Qs-Dilutfon Rate (1pm)
Sm-Observed Concentration (ppm)
Ce-Expected Concentration (ppm)
Spike
Recovery (%)
Cs-Spike Gas Cone, (ppm) 101
28.1
15
1.5
30.6
34.7
88%
-------
Table C-3
Montevallo Klin #4
Continuous Emissions Monitoring Data Sheet
EPA Mathoda 3A, 6C, 7E, 10, and 25A
23-Mar-98
INLET
Analyzer
Qxygm
Range
Gas Cone.
0-25%
11.1
Pro Test
Sys. Cal,
0.5
11.3
Cal. Bias
% of Span
2.0%
0.8%
Post Test
Sys. Cal.
0.3
11.2
Cal. Bias
% of Span
1.2%
OA%
Drift
% of Span
0.8%
04%
Carbon Dkndda
0-40%
0.2
0.1
03%
0.3%
20,4
20.8
1.0%
18.8
-4.0%
5.0%
Total Hydrocarbon
Q-IOOppm
-1.1
•1.1%
-4.0
-4.0%
51.1
50.5
•0.6%
46.1
•S.0%
44%
±5%
±5%
±3%
OUTLET
Analyzer
Oxygen
Range
Gas Cone.
0-25%
11.1
P re Test
Sys. Cal.
0.4
11.3
Cal. Bias
% of Span
1.6%
0.8%
Post Test
Sys. Cal.
0.5
11.3
Cal. Bias
% of Span
2.0%
0.8%
Drift
% of Span
-0.4%
0.0%
Carbon Dioxide
0-40%
0.1
0.3%
0.1
0.3%
0.0%
20.4
20.4
0.0%
18.8
•4.0%
4.0%
Total Hydrocarbon
0-100ppm
•0.3
-4.4
-4.4%
4.1%
51.1
50.8
•0.3%
43.3
•7.8%
ZS%
±5%
Analyzer Calibration Check
±5%
Analyzer
02 Hi*
O2 Mid
O2 zero
CO2High
CO2Mid
CO22BTO
THCHIgh
THCMid
THC Hi*
THC zero
Gas Cone.
20.2
11.1
0.0
20.4
11.0
0.0
84.8
51.1
30.0
0.0
Response
20.1
11.3
0.4
20.4
11.0
0.1
83.8
50.8
27.0
-2.4
Error
-0.40%
040%
1.60%
0.00%
0.02%
025%
-1.00%
•0,30%
•2.99%
•2.40%
-------
Table C-4
Montevallo Kiln #3
Continuous Emissions Monitoring Data Sheet
EPA M»tho
-------
-------
INLET
HCI In-Situ Matrix Spike
Recovery Efficiencies
Plant ChemUme Montevallo
Date 23-MarJ98
Project No. . 9801S !
Cs-Spike Gas Cone, (ppm) 101
Testl
Initial
Su-Nati^e Concentration (ppm)
Qt-Anafyzer Flow (Ipm)
Qs-Dilution Rate (Ipm)
Sm-Obierved Concentration (ppm)
Ce-Expected Concentration (ppm)
Spike Recovery (%)
21,7
6
1.5
144
37.6
38%
-------
HUG-04-iyyti
IUU_HNU
Outlet
HCI In-Situ Matrix Spike
Recovery Efficiencies
Plant ChtrnUmt Montevallo
Date 23-Mar-l98
Project No. 9S01GJ
Cs-Spike Gas Cone, (ppm) 101
Tesll
Initial
Concentration (ppm)
Qt-Ana^zer Row (Ipm)
Qs-Dilution Rate (Ipm)
Sm-Observed Concentration (ppm)
Ce-ExpjectecJ Concentntlon
Spite Recovery (%)
18.1
10
U
16.1
28.9
§6%
-------
HUU—m—
I-KUI'I
IUUI.NIW
Outlet
HCI Jn-Situ Matrix Spike
Recovery Efficiencies
Plant
Date
Prefect No.
ChemUme Montevallo
24-Mar|
Cs-Spike Gas Cone, (ppm) 101
Testl
Initial
Su-Nat^e Conoenfration Qapm)
Qt-Ant|?zsr Row Opm)
Qs-Dilujtion Rate (Ipm)
Sm-Obierv»d Concentratfon (ppm)
Ce-Expksed Coicentratton (ppm)
Spike Recovery {%)
4.5
10
1.5
4.9
17.1
29%
-------
Appendix B.2
CEMs and Analytical Data
Method 23 Analytical Data
-------
CASE NARRATIVE
Analysis of Samples for the Presence of
Poly chlorinated Dibenzo-p-Dioxins and Dibenzofurans by
High-Resolution Chromatography / High-Resolution Mass Spectrometry
Method 23 (6/93)
Date:
Client ID:
P.O. Number:
TLI Project Number:
April 21,1998
Pacific Environmental Services
104-98-0159
45399
This report should only be reproduced in full. Any partial reproduction of this report requires permission from
Triangle Laboratories, Inc.
Rev. 11/19/97
Triangle Laboratories, Inc.
801 Cap/to/a Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
919-544-5729 Fax # 919-544-5491
001
-------
Triangle Laboratories, Inc. April 21, 1998
Case Narrative 45399
Overview
The sample(s) and associated QC samples were extracted and analyzed according to
procedures described in Method 23 (6/93). Any particular difficulties encountered during
the sample handling by Triangle Laboratories will be discussed in the QC Remarks section
below. This report contains results only from the Method 23 dioxin/furan analyses of the
M23 sample(s).
Quality Control Samples
A laboratory method blank, identified as the TLIM23 Blank, was prepared along with the
samples.
Quality Control Remarks
This release of this particular set of Pacific Environmental Services analytical data by
Triangle Laboratories was authorized by the Quality Control Chemist who has reviewed
each sample data package following a series of inspections/reviews. When applicable,
general deviations from acceptable QC requirements are identified below and comments
are made on the effect of these deviations upon the validity and reliability of the results.
Specific QC issues associated with this particular project are:
Sample receipt: Twelve M23 sample(s) were received from Pacific Environmental
Services in good condition on April 01, 1998 at ambient temperature and stored in a
refrigerator at 4 °C. On the sample labeled M23-0-1-2, acetone was marked through and
toluene was written above it. On the sample labeled M23-0-1-3, toluene was marked
through and acetone was written above it. Neither of these labels agreed with the clients'
chain of custody.
Sample Preparation Laboratory: None
Mass Spectrometry: None
Data Review: Sample M23-O-1 indicated low internal standard recoveries. However, the
signal-to-noise ratio is above ten-to-one in all cases and all standards are valid for
quantitation. TCDF was the only analyte detected in this sample and is below Target
Detection Limit (TDL).
-------
Triangle Laboratories, Inc. April 21, 1998
Case Narrative 45399
Other Comments: No 2,3,7,8-substituted target analytes were detected in the TLI Blank
above the target detection limit (TDL).
The analytical data presented in this report are consistent with the guidelines of EPA
Method 23 (6/93). Any exceptions have been discussed in the QC Remarks section of
this case narrative with emphasis on their effect on the data. Should Pacific
Environmental Services have any questions or comments regarding this data package,
please feel free to contact our Project Scientist, Rose West, at 919/544-5729 ext. 270.
For Triangle Laboratories, Inc.,
Released by
Girgis Mikhael
Report Preparation Chemist
The total number of pages in the data package:
-------
TRIANGLE LABORATORIES, INC.
LIST OF CERTIFICATIONS AND ACCREDITATIONS
ENVIRONMENTAL
American Association for Laboratory Accreditation. Accredidation pending. Certificate
Number 0226-01. Accreditation for technical competence in Environmental Testing. (Including
Waste Water, Sol/Haz Waste,, Pulp/Paper, and Air Matrices) Parameters are AOX/TOX, and
Dioxin/Furan. Method 1613 for Drinking Water.
State of Alabama, Department of Environmental Management Expires December 31. 19SS,
Laboratory I.D. # 40950. Dioxin in drinking water.
State of Alaska, Department of Environmental Conservation. Expires Decamber 21. 19S8.
Certificate number OS-Q0397. Dioxin in drinking water.
State of Arizona, Department of Health Services. Expires May 26. 1998. Certificate 2AZQ423.
Drinking Water for Dioxin, Dioxin in WW and S/H Waste.
State of Arkansas, Department of Pollution Control and Ecology. Expires February 18,1999.
Pulp/paper, soil, water, and Hazardous Waste for Dioxin/Furan; AOX/TOX, Volatiles, Semi-
volatiles, and Metals.
State of California, Department of Health Services. Expires August 31, 1999. Certificate
#1922. Selected Metals in Waste Water; Volatiles, Semi-volatiles, and Dioxin/furan in WW and
Sol/Haz Waste. Dioxin in drinking water.
State of Connecticut, Department of Health Services. Expires September 30. 1999.
Registration #PH-Q117. Dioxin in drinking water. ...
Delaware Health and Social Services. Expires December 31,1998. Certificate #NC 140. Dioxin
in drinking water.
Florida Department of Health and Rehabilitative Services. Expires June 30, 1998. Dioxin in
DW. Drinking Water ID HRS# 87424. Metals, Extractable Organics (GC/MS), Pesticsdes/PCS's
(GC) and Volatiles (GC/MS) in Environmental Samples. Environmental water ID HRS* E87411.
Revised 3/2/98 RM
y:eertific\certiistmem
-------
Hawaii Department of Health. Expires March 1, 1999. Dioxin in drinking water. "Accepted"
status for regulatory purposes.
Idaho Department of Health and Welfare. Expires December 31, 1998. Dioxin in drinking
water.
State of Kansas, Department of Health and Environment Expires January 31, 1999,
Environmental Analyses/Non portable Water and Solid and Hazardous Waste. Method 1613 for
drinking water. ID #"s - Drinking water and/or pollution control - E-215. Solid or Hazardous Waste -
E-1209.
Commonwealth of Kentucky, Department for Environmental Protection. Expires
December 31,1998. ID#9Q060." Dioxin in drinking water.
Maryland Department of Health and Mental Hygiene. Expires September 30, 1998.
Certification #235. Drinking water by Method 1613A.
State of Michigan, Department of Public Health. Expires June 3, 1998. Drinking water by
Method 1613.
Mississippi State Department of Health. No expiration date. Dioxin in drinking water.
Montana Department of Health and Environmental Services. Expires December 31, 1998.
Dioxin in drinking water.
State of New Jersey, Department of Environmental Protection and Energy. Expires June 30,
1998. ID #87851. BNAs and Volatites. Dioxin in drinking water.
State of New Mexico, Environment Department Recertification pending. Dioxin in drinking
water.
New York State Department of Health. Expires April 1, 1998. ID #11026. Environmental
Analyses of non-potable Water, Solid and Hazardous Waste. Method 1613 in DW.
«
» *
State of North Carolina, Department of Environment Health and Natural Resources Expires
August 31,1999. Certificate # 37751. Djpxin in drinking water.
State of Norm Carolina, Department of Environment, Health, and Natural Resources,
Division of Environmental Management Expires December 31, 2000. Certificate # 485.
Metals, pesticides & PCBs, semi-volatiies and volatiles; TCLP.
North Dakota State Department of Health and Consolidated Laboratories. Expires
December 31,1998. Certificate # R-076. Effective October 4,1993. Dioxin in drinking water.
Revised 3/2/98 RM
y:certrfic\eertl!stmem
-------
State of West Virginia, Department of Health. Expires December 31, 1398. Certificate No.
9923(C). Dioxin in drinking water.
State of Wisconsin, Department of Natural Resources. Expires August 31,1998. Laboratory
ID Number 999869530. Certification for the following categories of Organics: Purgeable,
Base/Neutral, Add, PCBs, and Dioxin. Expires November 14, 1999. Laboratory ID 999869530.
Dioxin in drinking water.
PHARMACEUTICAL
Drug Enforcement Agency (DEA). Expires November 30, 1998, Registration number
RT01195835. Controlled substance registration for schedules 1,2,3,3N,4,5.
N.C. Department of Human Resources. Expires October 31,1998, Registration number
NC-PT 0000 0031, North Carolina controlled substances registration. Application submitted for
renewal.
Food & Drug Administration (FDA) Registration. Expires June 1998. ID #s 001500 1053481.
Annual registration of drug establishment. Annual registration of drug establishment.
OTHER
Clinical Laboratory Improvement Amendments (CLIA) Registration. Expires May 30, 1999.
ID # 34D0705123. Department of Health & Human Services, Health Care Financing
Adminjsfration.
U.S. EPA Large Quantity Hazardous Waste Generator. No expiration date. EPA ID
#NCD982156879. Permit indicates that the laboratory is a large generator of hazardous waste.
North Carolina General License for Radiation Protection. No. expiration date. License No.
032-875-OG. The general license applies only to radioactive material contained in devices which
have been manufactured and labeled in accordance with specific requirements.
Revised 3/2/98 RM
y:certific\certistrnem
-------
DOCUMENT
CONTROL
Triangle Laboratories, Inc.
801 Capitola Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Parit, NC 27709-3485
919-544-5729 Fax f 919-544-5491
-------
PACIFIC ENVIRONMENTAL SERVICES, INC.
Central Park West
5001 South Miami Boulevard, P,O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919)941-0333 FAX: (919) 941-0234
Chain of Custody Record
'ojecl Num
1012.002
Project Name
US EPA Lime Kiln Screening - Alabama Lime
implers:
Abernathy, Gay, Marel, Phoenix, Siegal
Date
3/23/98
3/23/98
3/23/98
3/23/98
3/24/98
3/24/98
3/24/98
3/24/98
3/26/98
3/26/98
3/26/98
3/26/98
3/28/98
3/28/98
3/28/98
3/28/98
•*/23/98
3/23/98
3/23/98
Time
Field Sample ID
M23--1-1
M23--1-2
M23--1-3
M23--1-4
M23- -2-1
M23- -2-2
M23- -2-3
M23- -2-4
M23- -3-1
M23- -3-2
M23- -3-3
M23- -3-4
M23-I-4-1
M23-I-4-2
M23-W-3
M23-M-4
M23-O-1-1
M23-O-1-2
M23-O-1-3
Sample Description
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Analysis Requested
M*
«s»
«*»
-------
>Y
PACIFIC ENVIRONMENTAL SERVICES. INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919)941-0333 FAX: (919) 941-0234
Chain of Custody Record
'roject Mum
r01 2.002
Project Name
US EPA Lime Kiln Screening - Alabama Lime
Samplers:
Abernathy, Gay, Maret, Phoenix, Siegal
Date
3/23/98
3/24/98
3/24/98
3/24/98
3/24/98
3/26/98
3/26/98
3/26/98
3/26/98
3/28/98
3/28/98
3/28/98
3/28/98
3/23/98
3/23/98
3/23/98
3/23/98
3/24/98
3/24/98
Time
Field Sample ID
M23-O-1-4
M23-O-2-1
M23-O-2-2
M23-O-2-3
M23-O-2-4
M23-O-3-1
M23-O-3-2
M23-O-3-3
M23-O-3-4
M23-O-4-1
M23-O-4-2
M23-O-4-3
M23-O-4-4
M23-FB-1-1
M23-FB-1-2
M23-FB-1-3
M23-FB-1-4
M23-FB-2-1
M23-FB-2-2
Sample Description
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Analysis Requested
Vs
§
«_>
<=V.
*
t
*
*
*
•
•
«
•
*
*
*
*
*
•
*
•
*
*
Vrv
"&
o
OT-
•
*
*
*
*
*
*
*
•
*
•
«
*
*
*
«
*
*
•
,
Remarks
I
FIELD BLANK 1
FIELD BLANK 1
FIELD BLANK 1
FIELD BLANK 1
FIELD BLANK 2
FIELD BLANK 2
4/1/98
Page 2 of 3 Pages
-------
PACIFIC ENVIRONMENTAL SERVICES. INC.
Centraf Park West
5001 South Miami Boulevard, R.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919) 941-0333 FAX: (919) 941-0234
Chain of Custody Record
reject Num
rOI 2.002
Project Name
US EPA Lime Kiln Screening - Alabama Lime
amplers:
Abernalhy, Gay, Maret, Phoenix, Siegal
Date
3/24/98
3/24/98
3/26/98
3/26/98
3/26/98
3/26/98
3/27/98
3/27/98
3/27/98
3/27/98
Time
Field Sample ID
M23-FB-2-3
M23-FB-2-4
M23-FB-3-1
M23-FB-3-2
M23-FB-3-3
M23-FB-3-4
M23-RB-1
M23-RB-2
M23-RB-3
M23-RB-4
telinquished by: (Signature)
. n
telinqu|sWiky: (S/^nature)
rZ^6p
Date/Time
Date/Time
ftlof.
Sample Description
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Received by: (Signature)
Receped-fbrllls BJt (Signature)
sf&6£rfzZ:&\\ ^P Ti^/A
Analysis Requested
_Vs
<2s
•^
•O
r>-
»
•
»
*
*
*
*
*
*
*
\*
vi,
"3*.
o
CL,
*
•
*
*
•
*
»
•
»
•
Relinquished by: (Signature)
Date/Tltne
Remarks
FIELD BLANK 2
FIELD BLANK 2
FIELD BLANK 3
FIELD BLANK 3
FIELD BLANK 3
FIELD BLANK 3
REAGENT BLANK
REAGENT BLANK
REAGENT BLANK
REAGENT BLANK
Deceived by: (Signature)
REMARKS
4/1/98
Page 3 of 3 Pages
-------
| Custody Seal :
|| Chain of Custody :
II Sample Tags :
| Sample Tag Numbers:
I SMO Forms :
|| Ice Chest/Box
|TLI Number Client
BmR/H-.CPM Clie
Absent
Present
Absent
Not Listed
N/A
Sample ID
nt COC ID.
Sample Seals: Absent
Container. . . : Intact
on Chain of Custody
NO COOLANT
Mat
.... * Location, . . .
rix To LAB To STORAGE]
Date/Init Date/Init
LiOU IN KCCUKU/CHftl!
i
TLI Project Number 45399
Client: PES03 - Pacific Environmental Services
, , , , - '
Date Received j 04/01/98
i
1
Carrier and Number |
i
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Book (I
204 ||
Page ||
II
92 ||
Hi
TO LAB TO STORAGE) TO LAB TO STORAGE) TO LAB TO STORAGE | DISPOSED |j
Date/Init Date/Init Date/Init Date/Init Date/Init Date/Init Date/Init II
|TLI Number Client Sample ID Matrix
|mR/K:CPM. Client COC ID * Location
II
II
||204-92-lA M23-I-1-1 FILTER
| M23-I-1-1 C02
||204-92-lB M23-I-1-2 ACETONE RINSE
II M23-I-1-2 C02
II
II
J204-92-1C M23-I-1-3 TOLUENE RINSE
|| M23-I-1-3 C02
II
||204-92-ID M23-I-1-4 XAD
|| M23-I-1-4 C02
R204-92-2A M23-I-2-1 FILTER
IJ M23-I-2-1 C02
J204-92-2B M23-I-2-2 ACETONE RINSE
K M23-I-2-2 C02
(204-92-2C M23-I-2-3 TOLUENE RINSE
| M23-I-2-3 C02
||204-92-2D M23-I-2-4 XAD
|j M23-I-2-4 C02
p04-92-3A M23-I-3-1 FILTER
1 M23-I-3-1 C02
U204-92-3B M23-I-3-2 ACETONE RINSE
H M23-I-3-2 C02
||204-92-3C M23-I-3-3 TOLUENE RINSE
I M23-I-3-3 C02
fl
it
||204-92-3D M23-I-3-4 XAD
|| M23-I-3-4 C02
U-,
IJ204-92-4A M23-I-4-1 FILTER
|| . M23-I-4-1 C02
ii
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Date/Init
Hi
V/*/*r
||204-92-4B M23-I-4-2 ACETONE RINSE) jj/)v/
II M23-I-4-2 C02 | ^""/ifaf
To STORAGE
Date/Init
U*
J
/
^
To LAB
Date/Init
To STORAGE
Date/Init
To LAB
Date/Init
To STORAGE
Date/Init
To LAB
Date/Init
To STORAGE
Date/Init
| DISPOSED ||
Date/Init jj
It
1!
ii
ii
II
' II
«"
«
11
ii
ii
II
II
ii
ii
11
11
ii
II
II
II
II
ii
ii
II
II
ii
( II
II
1!
11
II
' '• II
II
II
II
II
--
II
II
II
II
II
|| Receiving Remarks: ON SAMPLE LABlL:M23~0-l-2, ACETONE WAS MARKED THROUGH AND TOLUENE WRITTEN ABOVE IT; TOLUENE WAS
|| • ' MARKED THROUGH WITH ACETONE WRITTEN ABOVE FOR SAMPLE M23-0-1-3; NEITHER AGGREED WITH CLIENT'S COC,
II
|| Archive Remarks:
sForm Revised 05/27/1997 -- Page 1 OF 4=
-------
|| Custody Seal :
1 Chain of Custody :
jj Sample Tags :
)| Sample Tag Numbers :
|| SMO Forms :
|| Ice Chest/Box
||TLI Number Client
BmR/H:CPM Clie
Absent
Present
Absent
Not Listed
N/A
Sample ID
nt COC ID.
Sample Seals: Absent
Container. . . : Intact
on Chain of Custody
NO COOLANT
Matrix
.... * Location
TLI Project Number 45399
Client: PESOS - Pacific Environmental Services
i i .
Date Received | 04/01/98 | By.^feJ' ^r ^JKb
Carrier and Number |
i
To LAB To STORAGE) To LAB To STORAGE) To LAB To STORAGE) To IAB To STORAGE
Date/Init Date/Init Date/Init Date/Init Date/Init Date/Init Date/Init Date/Init
| Book ||
' I II
. • 1 204 ||
1 1!
I
- — -"i Page ||
'Hm 1
i**^ 1 U
1 92 I
DISPOSED ||
Date/Init II
M
||TLI Number Client Sample ID Matrix) To L
|jmR/H:CPM. Client COC ID * Location | Date
II 1
.AB
/Init
||204-92-4C M23-I-4-3 TOLUENE RINSE) f / .
|| M23-I-4-3 C02 | M ^M^
II • I
||204-92-4D M23-I-4-4 XAD|
|| M23-I-4-4 C02 |
II
II 1
||204-92-5A M23-0-1-1 FILTER)
I) M23-0-1-1 C02 j
II i
II 1
||204-92-SB M23-0-1-2 TOLUENE RINSE
|| M23-0-1-2 C02 I
1]
II
||204-92-SC M23-O-1-3 ACETONE RINSE|
|| M23-0-1-3 C02 I
Hi
1
)|204-92-SD M23-0-1-4 XAD
|| M23-O-1-4 C02
II 1
||204-92-6A H23-O-2-1 FILTER)
|| M23-O-2-1 C02 j
II
II 1
J204-92-6B M23-O-2-2 ACETONE RINSE)
1 M23-O-2-2 C02
||204-92-6C M23-O-2-3 TOLUENE RINSE)
§ M23-0-2-3 C02 |
I!
U
||204-92-6D M23-O-2-4 XAD)
|| M23 -0-2-4 C02 |
it
II
||204-92-7A M23-0-3-1 FILTER)
1) M23-0-3-1 C02
H
II
||204-92-7B M23-O-3-2 ACETONE RINSE|
jj M23-0-3-2 C02
i
11
||204-92-7C M23-O-3-3 TOLUENE RINSE)
jj M23-O-3-3 C02 ,
||
||204-92-7D M23-0-3-4 XAD j/^>
jj M23-0-3-4 C02 ^* J
tir
To STORAGE
Date/Init
M^
)
i
wu/
.. j
| To LAfl
Date/Init
,
To STORAGE
Date/Init
!
| To LAB
Date/Init
.
s
To STORAGE
Date/Init
| To IAB
Date/Init
To STORAGE
Date/Init
i
DISPOSED ||
Date/Init ||
II
II
II
II
' II
H
II
I
II
II
II
II
II
II
II
II
1
fl
II
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II
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n
II
1
n
ii
n
n
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|| Receiving Remarks:
I) Archive Remarks:
ON SAMPLE LABEL:H23-0-l-2, ACETONE WAS MARKED THROUGH AND TOLUENE WRITTEN ABOVE IT; TOLUENE WAS
•HARKED THROUGH WITH ACETONE WRITTEN ABOVE FOR SAMPLE M23-O-1-3; NEITHER AGGREBD WITH CLIENT'S COC.
=Form Revi3ed,-OS/27/1997 -- Page 2 OF 4=
-------
-TRIANQIiE LABORATORIES, INC. -- LOG FN RECORD/CHAIN OP CUSTODY=
|| Custody Seal i Absent Sample Seals: Absent
|| Chain of Custody : Present Container...: Intact
jj Sample Tags : Absent
| Sample Tag Numbers: Not Listed on Chain of Custody
|| SMO Forms : N/A
||
II
|| Ice Chest/Box NO COOLANT
UTLI Number Client Sample ID . Matrix
jjmR/H:CPM Client COC ID * Location
n - -
II
||204-92-BA M23-0-4-1 FILTER
|| M23-0-4-1 C02
n
II
H204-92-8B M23-0-4-2 ACETONE RINSE
jj M23-0-4-2 C02
II
II
j|204-92-8C M23-0-4-3 TOLUENE RINSE
|| M23-0-4-3 C02
»-
||204-92-8D M23-0-4-4 XAD
1 M23-0-4-4 C02
,
-
|204-92-9A M23-FB-1-1 FILTER
|| M23-FB-1-1 C02
».
IJ204-92-9B M23-FB-1-2 ACETONE RINSE
|| M23-FB-1-2 C02
n
II
||204-92-9C M23-FB-1-3 TOLUENE RINSE
| ' M23-FB-1-3 C02
||204-92-9D M23-FB-1-4 XAD
jj M23-FB-1-4 C02
||204-92-10A M23-FB-2-1 FILTER
|| M23-FB-2-1 C02
1
g2Q4-92-10B M23-FB-2-2 ACETONE RINSE
|| M23-FB-2-2 C02
H.
[204-92-10C M23-FB-2-3 TOLUENE RINSE
|| M23-FB-2-3 C02
[2Q4-92-10D M23-FB-2-4 XAD
jj M23-FB-2-4 C02
|204-92-llA M23-FB-3-1 FILTER
jj M23-FB-3-1 C02
||
To LAB
Date/Init
MI i
||204-92-llB M23-FB-3-2 ACETONE RISE) |j jl }
jj M23-FB-3-2 C02 j 1 p-lf f
| TLI Project Number 45399 | Book ||
j Client: PESOS - Pacific Environmental Services ') jj
.1 ., | 204 ||
1 ' ' J II
j Date Received j 04/01/98 j &Y$yf A f^g^r — "l Page j|
I 1 '"'ID
| Carrier and Number | | 92 ||
To STORAGE
Date/Init
*
.
\
\
TJ
U£*-*
To LAB
Date/Init
•
To STORAGE
Date/Init
1
To LAB
Date/Init
-
To STORAGE
Date/Init
To LAB
Date/Init
To STORAGE
Date/Init
i
DISPOSED ||
Date/Init jj
II
II
II
' II
«'
II
1
«'
II
II
II
II
n
II
II
II
||
II
II
II
n
II
II
II
«'
i II
II
11
11
II
• '• II
ii
II
J
11
II
1
II
1
II
II
Receiving Remarks: ON SAMPLE LABEL:M23~O-l-2, ACETONE HAS MARKED THROUGH AND TOLUENE WRITTEN ABOVE IT; TOLUENE WAS
MARKED THROOGH WITH ACETONE WRITTEN ABOVE FOR SAMPLE M23-O-1-3; NEITHER AGGREED WITH CLIENT'S COC.
Archive Remarks:
=Forin Revised 05/27/199? »- Page 3 OF 4=
-------
|| Custody Seal :
|| Chain of Custody :
Jl Sample Tags :
1 Sample Tag Numbers:
K SMO Forma :
||
|| Ice Chest/Box
1!
Absent
Present
Absent
Not Listed
N/A
Sample Seals.- Absent
Container..,.- Intact
on Chain of Custody
NO COOLANT
TLI Project Number 45399
Client: PES03 - Pacific Environmental Services
Date Received
1
i
i
Carrier and Number J
04/01/98 By 7W, y ^
j / LStsff j<*j
• !
... \
d^-H"
Sw^JH
1
Book I
II
204 ||
||
— II
Page ||
II
92 i|
IJTLI Number. . . , . .Client Sample ID. . Matrix
IJmR/H-CPM Client COC ID * Location
||204-92-llC M23-FB-3-3 TOLUENE RINSE
|| M23-FB-3-3 C02
tt
11
||204-92-llD M23-FB-3-4 XAD
1 H23-FB-3-4 C02
||204-92-12A H23-RB-1 - FILTER
|j M23-RB-1 C02
((204-92-128 M23-RB-2 ACETONE RINSE
|| M23-RB-2 C02
||204 -92-12C M23-RB-3 TOLUENE RINSE
| M23-RB-3 C02
||204~92-12D M23-RB-4 XAD
|| • M23-RB-4 C02
-
II
II
-
II
II
II
II
II
II
«.
II
II
II
II
-
II
1!
II
II
II
To LAB
Date/Init
M
I
(,
)..
To STORAGE
Date/Init
u*
\
te
u
Jl
C4
| To LAB
Date/Init
To STORAGE
Date/Init
| To LAB
Date/Init
-
To STORAGE
Date/Init
-
| To LAB
Date/Init
To STORAGE
Date/Init
| DISPOSED ||
Date/Init ||
II
1
«"
1
' II
«"
II
II
8*
II
II
n
11
II
II
«'
II
II
II
II
II
II
it
II
II
II
n
II
II
II
11
II
i
n
II
II
II
n
11
II
II
|| Receiving Remarks.- ON SAMPLE LABEL:M23-O-l-2, ACETONE WAS MARKED THROUGH AND TOLUENE WRITTEN ABOVE IT; TOLUENE WAS
MARKED THROUGH WITH ACETONE WRITTEN ABOVE FOR SAMPLE M23-0-1-3; NEITHER AGGREED WITH CLIENT'S COC,
Archive Remarks:
=Forni Revised 05/27/1997 -- Page -4^-OF 4=
-------
TRIANGLE LABORATORIES, INC.
SAMPLE TRACKING AND PROJECT MANAGEMENT FORM
ADMINISTRATIVE INFORMATION •
TLI Projff: 45399- Samples: 12 TurnAround. : 21 Day(s)
Prod Code: D23451 Matrix.: M23 Hold Time..: 30 Day(s)
DetectLim: 0.05 ng Type...: A Start Date.: 04/02/98
Recvd..: 04/01/98 Ship By....: 04/21/98
DWL Due Dt.: 04/09/98
Analyte List.: Tetra-Octa CDDs/CDFs
Method.......: Method 23: T-0, Toluene Combined
Client Proj..: r012.002/Lime Kiln
Client : Pacific Environmental Services (PES03)
P.O. No : 104-98-0159 Collect Dt/Tm: SeeCOC
Contact : Mike Maret Phone : 919-941-0333
Proj . Mgr. . . . : Rose West Fax : 919-941-0234
Sample Origin: AL
SPECIAL INSTRUCTIONS / QA REQUIREMENTS •
Prep Project: 04228 Prespike Standard: USF-CS
Prespike Amount..: 4.Ong
Extraction Exp...: 04/22/98
-------------------------- REPORTING REQUIREMENTS
Reporting Format : Report Option II
See MILES for Instructions/Communications .
Completed by: -HrttV-tt' _ DATE:
Reviewed by: KS/gQ _ DATE: 4-Z-9& (PMGT0197
15
-------
" PROJECT COMMUNICATION TRACKING FORM '
page
TLJ Project Number:
Use this form to record all exchanges of information between production units as well as personnel
handling this project. Decisions, corrective actions and recommendations must aiso appear on this
tracking document
Name
Comment / Decision / Resolution / Action / Observation
PESOS-Paclflc Environmental Services
M23-I-3-4
Pr-ojesct : 4-5399
2O«4-— 92— 3D
rflabama Lime - R012.002
Triangle Partt, Worth Carolina
int module
Trianal-: Laboraioriss
TLI ISO J~TT" 504223
DATE; •'JT—.T-OS
.SPIKE: 'USFTC -u !J5F-;1
SPIKE: _^T-.^_
PHEPEt ^ ?- - AC
PES03-Pacific Environmental Services
M23-I-4-4
3Ct : -4-5399
4-— 92 — «4-D
US EPA Lime Kin Screening - Abfc
i pacific EmrirooniBnttlSBwices, BUR
• -Research Triangle Park, North
•HunNexMZW-t
-------
Git* *
PES03-Pac1fic Environmental Services
M23-0-1-4
Pr-ojeo-t- : -4-5339
2O4-— 92— S D
US S>A Unw Kin Screening - Alabama Lime - R012.002
Pmjfc€nvfcmnne»tal Services, Inc.
•RMaaichTrtangte Partc, North Carolina
«unNo.H23-O~1
ffTintllntf Mo. lttS-O-1-4 XAD sorb ent module
Triangle Laboratories, Inc.
TLI PROJECT #04228
DATS: 03-17-98
SPIKE: USFrC & USF-3
SPTKER. ^dT
PREPSD BTiAC
PACIFIC ENVIRONMENTAL
PESOS-Pacific Environmental Services
M23-0-2-4
2O4-— 92— SO
I USB*AIJmeKnnSc«enina-AlabaraaLime-R012002 ^Ja v/ d«
I Pacific Environmental Sovtoe*, ft*.
fe Research Triangle Partt, North
I Run No. M23rO-2
4 XAD
Triangle Laboratories, Inc.
TLI PEOJECT #04228
DATE: 03-17-98
SPIKE: USFrC & QSF-S
SPIKER TPB».A
PRIPED BT AC " 5 \ ,
PACIFIC ENVIR01.145SITAL
000 -
Triangle Laboratories, Inc.:
TLI PROJECT #04228
DATE: 03-17-98 TLI BLANK
SPIKE: USF-C & OSP-S
SPIKER
,PREPID BY AC
PACIFIC ENVrROMMBMTAL
1?
-------
' PROJECT COMMUNICATION TRACKING FOflM
page of
-
TU Project Number: ^b 3 -f °l
Use this form to record ail exchanges of information between production units as well as personnel
handling this project. Decisions, corrective actions and recommendations must also appear on this
, ' tracking document
Date
*t/4?
•,
•
-
•
Name
— —
-
••
•
Comment / Decision / Resolution / Action / Observation
10sw'e #**)
2vi -c\ S-'ldAdplter * WKJ/C . JTAP- ,\ ..^f ' ( 5«-^t # (o)
.-JO^'^Z-SIA P ^Htr fsarwi.'x/tf ,i »Xi (^^pkffjj
• 2oM -12'I^.D A1^ i ^^' /AP.i wk,'V (^-fu^l)
M "^2-74 "Q Alfcr ,'5^*4 /^Ot'; ,,kk f ^j,' fr>1
1,4 .. ,,-, /• i ' -. ' I, ^C^/LM ' - j -i ( , _,_ \
x<51 H2.-44 ft <;-|Kr ^ TWHilc ^p^g u ^k | ^Wrtl? * £ )
l . ' ' ' • r
'.w V/2/^
20*1 -4:2- 5flf D ^|-|d^. i^Wjoj/wL'V ,//V 0 ^^te (.' s«~ f f* l^,5'/
2.0M^2-5A 9 crlkr ,,<^ 00^rfo,w!kr) ^AV) t^kk ts^.k^?)
i . < J I - - / '
^ f^«r 19S3
-------
PROJECT COMMUNICATION TRACKING FOflM
page
of
TLJ Project Number:
Use this form to record all exchanges of information between production units as well as personnel
handling this project. Decisions, corrective actions and recommendations must also appear on this
tracking document
Date
Name
Comment / Decision / Resolution / Action / Observation
•^
(J
d - "Tl- fi /k~
-/
t
SQ» Ma.
to Ne*»mo»r 1993
-------
Date: 04/03/98
Time: 11:41
Sample
ft crd TliI_Mumber, , Customer.Sample. Id
000 TLI Blank TLI M23 Blank
001 204-92-1A-D M23-I-1
002 204-92-2A-D M23-I-2
003 204-92-3A-D M23-I-3
004 204-92-4A-D H23-I-4
005 204-92-5A-D H23-O-1
006 204-92-6A-D M23-O-2
007 204-92-7A-D M23-0-3
008 204-92-8A-D M23-0-4
009 204-92-9A-D M23-FB-1
010 204-92-10A-D M23-FB-2
Oil 204-92-11A-D M23-FB-3
012 204-92-12A-D M23-RB-1-4
013 TLI LCS TLI LCS
014 TLI LCSD TLI LCSD
TRIANGLE LABORATORIES, INC.
Met Lab MM5/PUF Observations
Project: 45399
PRDPERC V4.01
Page: 1
o
P.
No
0
1
1
1
1
1
1
1
1
1
1
1
1
0
0
XAD
Color
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
Filter
Color
NA
GREY
GREY
GREY
BROWN
WHITE
WHITE
GREY
GRAY
WHITE
WHITE
WHITE
WHITE
NA
NA
Glass
Color
NA
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
NA
NA
Wool PDF
Color
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Odor
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
NONE
Air
Q No Entered
04228 WHIGHAM
04228 WHIGHAM
04228 WHIGHAM
04228 WHIGHAM
04228 WHIGHAM
04228 WHIGHAM
04228 HHIGHAM
04228 WHIGHAM
04228 WHIGHAM
04228 WHIGHAM
04228 WHIGHAM
04228 WHIGHAM
04228 WHIGHAM
Nft WHIGHAM
NA WHIGHAM
Date.... Time..,
04/03 10:59 F
04/03 10:59 F
04/03 10:59 F
04/03 10:59 F
04/03 10:59 F
04/03 10:59 F
04/03 10:59 F
04/03 10:59 F
04/03 10:59 F
04/03 10:59 F
04/03 10:59 F
04/03 10:59 F
04/03 10:59 F
04/03 10:59 F
04/03 10:59 F
. S
*** End of Report ***
-------
| TRIANGLE LABORATORIES, INC. PAGE 1 OP 2
| Dioxin Sample Preparation Tracking & Management Form
| Project: 45399 Client: Pacific Environmental Services (PES03)
I Solvent !s)/Acid!s> : ~T»{*i&Vl? / f
\ Lot Numbers: V-9kv jCvyft'i/ /
| IS Spike: 40 M! cone: 0.1000 ng/jil
1 SS Spike: M! cone: . ng/Ml
| MS Spike: 0 M! cone: 0.0000 ng/Ml
| LCS Spike: 0 Ml cone: 0.0000 ng/Ml
| OPE Spike: 20 M! cone: _0.01 ng/Ml
| | TLI / | GROSS | SS
|S#.crd SAMPLE / CLIENT | WEIGHT S
| | ID / SAMPLE ID | Before After | %.
\ TLI Blank |
|OOQ | TLI M23 Blank | ~ | "~ |
| 2Q4-92-1A-D 111
|001 | M23-I-1 1 | |
| | 204-92-2A-D | | |
(002 j M23-I-2 |
1 204-92-3A-D | | |
|003 M23-I-3 | \ ' — |
| | 204-92-4A-D | | |
|004 1 M23-I-4 | | |
| | 204-92-5A-D | , | |
|005 i M23-0-1 | | ' " |
| 204-92-6A-D | | |
|006 M23-0-2 | | |
1 204-92-7A-D | | j
|007 | M23-Q-3 | | |
| 204-92-8A-D | | |
|008 | M23-O-4 | ' — — | ' |
| | 204-92-9A-D | | |
009 | M23-FB-1 | ~~ | [
Method: Method 23: T-O, Toluene Combined Matrix: nflD
Extraction Date : 0*1 / O% I *?¥
I ^flkJ *\ JZW ] *7tu7 j ^jP/^"~ ichemist
i ®0/y£ i 54*o T i «/vr | (?££}£ i spike #
1 frsF-jr | u<,f=~Js \ " Tilne
1ZE i 6-t ng/Ml 1 O.Ot ng/Ml I 0-< nq/Ml ! €>/ / nq/Ml 1 " Cone.
4-«&. 1 % Ml 1 ^0 Ml 1 ^ Ml ! M 111 1 " Vol.
| | i | |ftny Left
1 1 1 1 |Any Left
I | | |Any Left
i 1 1 I 1 (Any Lett
i 1 1 1 I (Any Left
\ | | 1 I |Any Left
i 7 I yes<9
jyDrK Jy2/r^
I 1 1 1 1 |Any Left
1 ' / 6 ' ' ' S/ 'toy LSft
Gross weight of sample container + sample before/after aliquot removal.
I
Comments:
2.
7ULCS
Initials:
Date:
of both SPIKER AND OBSERVER must be entered.
XXXXX - Gross Weight not provided for WATER Samples.
REV 05/27/97 (PSTMF 7)-
-------
; Project: 45399
Solvent ( s ) / Acid ( s ) : ">«\
Lot Numbers: tf|~4<
IS Spike: 40 ftl cone
1 SS Spike : Ml cone
| MS Spike-. 0 ill cone
| LCS Spike : 0 M! cone
] OPR Spike : 20 jil cone
I | TLI /
|S#.crd| SAMPLE /
1 | ID / S
| | 204-92-10A-0
010 |
| | 204-92-11A-D
1011 1
| | 204-92-12A-D
|012 |
| | TLI LCS
)013 1
] | TLI LCSD
|014 |
I 1
1 1
1 I
1 I
t
1 1
1 1
I 1
1
i
TRISNGJUS LABORATORIES, INC, PAGE 2 OF 2 j
Dioxin Sample Preparation Tracking & Management Form |
Client: Pacific Environmental Services (PES03! |
fji^i- 1 1 Method: Method 23: T-0, Toluene Combined Matrix: S\ *1jJ |
3 t*fH-?/ / Extraction Date: 0*J / SJ/ TO |
, , .
ng/Ml I :7ZV I 7^7 i ^Ttk) | J5*h | chemist
: 0.0000 ng/Ml | 6$ '^ & \ 5"<» 7* "T | 5" % \H f \ 2$ £>"]> b [Spike # |
: 0.0000 ng/Ml 1 ^P -J- | U"$ F-Al/ | U^P- C3 | (/£/?'$ • | '»' ID I
: _o.01 ng/Ml | 12 / *_£ /^§ j JZ / 0£_ /W | _i(_ / ZV ^g_ | /// _^ /_£? | " Expir|
, + . j. . A a / .s /OS l ft 3 / d"5 / 98> I <7^l*f"3 /"r< 1 ^ / ¥ /<& « n*r*
| GROSS | SAMPLE | \\ : Jji^^, U : l§n,^ ji_ : 2J0«1~" = " Time
CLIENT I WEIGHT I SIZE I «• / nq/Ml ! *-£* ng/Ml I 0 • I nq/j«l t «>»/' ng/Ml I " Cone.
AMPLE ID I Before After | ,q 4 ml I Y° «1 I >J(> Ml I Vo Mi | *f0 Ml I " Vol. I
I __^ I _ I | I I ' // |ADY Left|
M23-FB-2 | "| j ' | -5^^. I I I ^0/^% yes/^5~)
I I | | | | | _ |Any Left
M23-FB-3 | • I ' | f j rv\ S^^^
I I I . I I | | Any Left]
M23-RB-1-4 | | | I | [ | | V^/V~" yes@)'
I I I ' x ^ '^ ' ^ ^S7. Le£t
I I I . \/fi ^ ^ ' // lAjjyLeft!
I I I I II I [Any Left |
III III yes/no
I I I I I I I |Any Left
I I I I I I I I yes/no |
I | | | | | [Any Left)
I I I I ill yes/no |,
I | | | | | j | Any Left |
| | | | | | | | yes/06 |
i | I | | | ] [Any Left)
| | | | ] | | | yes/no |
coss weight of sanqple container + sample before/after aliquot removal.
mments:
72
Initials:
Date:
/ _ /_
•>f both SPIK1R AND OBSERVER must be entered.
XXXXX • Gross Weight not provided for WATER Samples.
, REV 05/27/97 iPSTMF 7!-
-------
PAGE 1 OF 1
TRIANGLE LABORATORIES, INC.
DIOXIN SAMPLE EXTRACTION and CLEANUP TRACKING FORM
TLI Project No.: 45399
Ext Sft.crd and
TLI Number
000
TLI Blank
001
204-92-1A-D
t ! £ ! V. ! 7 ! *
002
204-92-2A-D
003
204-92-3A-D
fUSp
004
204-92-4A-D
DOS I
204-92-5A-D |
006
204-92-6A-D
•* + *-T +—f—--+
I I I / 111
, , «. j, _ _«t. .j j. i_ ..
— -. — ™^.«.™ - — — __™^«™ — — __™™ — ^.— «™_ — — — -,^~~ — — — — -.^^— — ™ — — -,-, — ^~ — »
007
204-92-7A-D
003
204-92-8A-D
009
204-92-9A-D
Enter the procedure number below into the box at the top of each column to signify the step performed.
Initial and date each sample for each numbered procedure performed.
# PROCEDURE SOP.#. .V. . DETAILS (circle)
ffi EXTRACTION Time On : Time Off :
<§oSSy/ Jar / Sep Funnel / Steam Dist / Cont LL / ASE / Waste Dilution
(2)) SPIKE AFTER EXT'N
/f}) ADD TRIDECANE Lottt "ffif
Of ROTOVAP
(£T) COMBINE
§^I^/LIP. DETERM.
SOLVENT EXCHANGE
/fj CLEANUP
Qy TRANSFER
10) ADDITIONAL CLEANUP
11) FINAL TRANSFER
00 L
5mL/20tnL Other_
5mL/2
Iso-Octane Lot# -1 t\(fo Heptane Lottt
CT fc?
/ DSP 225 / DSP 115 / DSP 215 / DSP 267 '/ Other f_
Mod. DSP 260 / DSP 225 / DSP 115 / DSP 215 / DSP 267 / DSP260(10g)
Comments:
====Rev 11/25/97 (PSTMF 4)==+
-------
PAGE 2 OP 2
TRIANGLE LABORATORIES, IMC.
DIOXIN SAMPLE EXTRACTION and CLEANUP TRACKING FORM
TLI Project No.; 45399
«-" ' J I ' /
5 \ "*> \ (0
Ext S#.crd and
TLI Number
/ ' (/ ' ' ' ' V ' '
f--4 ....( 4 1 1 ..| 4.
I I
I I
Enter the procedure number below into the box at the top of each column to signify the step performed.
Initial and date each sample for each numbered procedure performed.
# PROCEDURE. . . . SOP.i. .v.. DETAILS (circle)
EXTRACTION Time On __ : Time Off ;
Jar / Sep Funnel / Steam Dist / Cont LL / ASI / Waste Dilution
(2j) SPIKE AFTER EXT'N
(••fy ADD TRIDECANE Lottt JKl / ' £ / 7/
gP ROTOVAP
^ COMBINE
"^ DETERM. 20%/80% (§0%/50%\ 5mL/20mL Other__
SOLVENT EXCHANGE Iso-Octane Lot# ^? /7/tf^f Heptane Lot#
, C ' ^ I 'i-^
CLEANUP
TRANSFER
gSP_260j>/ DSP 225 / DSP 115 / DSP 215 / DSP 267 / Other
10) ADDITIONAL CLEANOP
11) FINAL TRANSFER
Mod. DSP 260 / DSP 225 / DSP 115 / DSP 215 / DSP 267 / DSP260(,10g)
Comments:
11/25/5*7 (PSTMF 4)= = -*
-------
PAGE 1 OF 1
TRIANGLE LABORATORIES, INC.
Transfer Chain-of-Custody Form
Project 45399
Transfer From: DWLH5 To: DMS5
Initials . . Date Time . . . '
Released by
\L-
M/J_/5fe tbu^ >-
v \, v ' " —
Accepted by: \K7x~ H / * / \\ o : ^^
MILES. ID
45399-
45399-
45399-
45399-
45399-
45399-
45399-
45399-
45399-
45399-
45399-
45399-
45399-
45399-
45399-
-000
-001
-002
-003
-004
-005
-006
-007
-008
-009
-010
-Oil
-012
-013
-014
TLI
TLI
204
204
204
204
204
204
204
204
204
204
204
204
TLI
TLI
No ......
Blank
-92-1A-D
-92-2A-D
-92-3A-D
-92-4A-D
-92-5A-D
-92-6A-D
-92-7A-D
-92-8A-D
-92-9A-D
-92-10A-D
-92-11A-D
-92-12A-D
LCS
LCSD
Cust . Id. .
TLI M23 Blank
M23-I-1
M23-I-2
M23-I-3
M23-I-4
M23-O-1
M23-O-2
M23-O-3
M23-O-4
M23-FB-1
M23-FB-2
M23-FB-3
M23-RB-1-4
TLI LCS
TLI LCSD
y-FT-rrsr Cp^r ii/m/Q4J — i
Additional comments or instructions:
-------
PAGE 1 OF 2
1
| Methc
| Reqiu
t
1 1
|S#.crd|
1 1
1 1
IOOQ |
1 i
|001 |
1 1
|002 !
003
[004 |
1 1
[DOS |
t 1
|006 |
1
[007 |
1 1
[008 |
1 1
|009 |
i I
|oio |
1
(Oil
TRIANGLE U
d- Method 23- T-0 Toluene Combined HR GC/H8
red Detection Limit : 0 . 05 ng
SAMPLE
1ST COLUMN
TLI / | GC/MS FILENAME [CONFIRM
SAMPLE ID / CLIENT | COLUMN: jX^, j |
/ SAMPLE ID [ |
TLI Blank j |
TLI M23 Blank | I (A**
204-92-1A-D 1 |
204-92-2A-D | |
204-92-3A-D | |
M23-I-3 |^ . 1 <~ 1 i V
204-92-4A-D | |
, j \i
M23-I-4 "TQ^I *{<%} ' 1
204-92-5A-D | |
M23-0-1 | ^1% 1^*7^ 1 Y
204-92-SA-D | I j
M23-0-2 | ~^£iyl*lV*J! | J
204-92-7A-D | |
M23-O-3 C 3( Cfl,"1) i) 4 | \J
2Q4-92-8A-D | | .
M23-0-4 | S^I/^Gt? | I
204-92-9A-D | |
M23-FB-1 | ^^^Vb0"! 1 V^
204-92-10A-D | |
M23-FB-2 j C^«y 1,'>)ij
-------
PAGE 2 OF 2
| TRIANGLE LABORATORIES, INC.
| Required Detection Limit: 0.05 ng
| SAMPLE INFORMATION
| 1ST COLUMN 2ND COLUMN
| | TLI / | GC/MS FILENAME | CONFIRM | CONFIRM FILENAME OSF-RS
|S».crd| SAMPLE ID / CLIENT | COLUMN: I I COLUMN: 156?Tl 1 VOLUME
|| / SAMPLE ID | || ISOLN ID
| 204-92-12A-D j | ] j ^Wt
|012 | M23-RB-1-4 | Cfl Q- ^ 1 (J 1 1 ^V t "*53-1 '
| TLI LCS ]| | \
|U13 TLI LCS '5^*5 t^H 1 " " " \J
| | TLI LCSD | II 1 'ty&.fl
I I TLI IA.oD | . ll[ j s ^ | -f^ | 1^ | , /y
+ \Jr"^ •* *''
1 1 I
11 III t
II III 1
1 1 1 1 1
1 ,
II III 1
11 III 1
1 1111
1 1 1 1 1
1 III 1
11 111 1
II 111 1
II 111 1
II 1 II 1
1 111
II III 1
II 111 1
11 111 1
1
| Comments :
1
1
1
1
i
1
| PROJECT: 45399 |
RS Cone |
20 jil 9 100.0 PG/^1 |
IUSF-RS [ANALYSIS |
| INIT . | COMMENTS |
IDATE | |
ifr; i
iji i
i ]/ i i
i ,' / i i
i t-f/y '(j i i
i
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"Type: A I
1
1
i
Spike File: SPMIT204 I
1
Amt of Extract: 50% 1
.- PRV m/m/OR [PRTMU fil 1-
27
-------
Triangle Laboratories, Inc.
Run Log
Instrument ID
Column Type Column ID Ptot Name Ini. Vol. Acquisition
M3L-^— —
Signature
G/C
MDESV?
M/ yft,
Date
Transcribed from chromatographic data
Dated initials required
ConCal Due:
ConCal Due:
srvrl/qa/forms/hrrunlog doc (02/05/97)
tf i Vrt
Page:
-------
Triangle Laboratories, Inc.
Run Log
Instrument ID Column Type Column ID Plot Name Ini. Vol. Acquisition
"lO4} -CX?^ J5(?3^'Ml ~j~tfc>\ oh5AA>i. U*S
G/C
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Signature
Date
Filename
Date*
Time*
Project #
Sample*
No.
Client Sample ID
Syr
332
Operator/Date
Comments
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** Dated initials required
srvrVqa/forms/hrrunlog doc (02/05/97)
ConCal Due:
ConCal Due:
Page:
-------
Run Log
Instrument ID Column Type Column ID Plot Name
10T fogfi "7^1^35 T?^x
In). Vol. Acquisition
j^
Signature
G/C
fv/bfiS^S
V/W
Date u
Filename
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** Dated initials required
srvr1/qa/forms/hrrunlog.doc (02/05/97)
ConCal Due:
ConCal Due:
Page:.
-------
Triangle Laboratories, Inc.
Run Log
Instrument ID Column Tvpe Column ID Plot Name
*~7£>T nB^S" ~?l/M535 ~T2Q
Ini. Vol. Acquisition QIC
f^t /VW, «/
-------
Triangle Laboratories, Inc.
f Log
Instrument ID Column Tvpe Column fD Plot Name
ibiA 7)&~5 n&igfan TOA
Inj. Vol. Acquisition
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Date
Filename
QWIhs
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No
Client Sample ID
Syr 332
Operator/Date
1—
Comments**
y>
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1 '-11
TU
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(cStoo
UWB
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45413
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* Transcribed from chromatographic data
** Dated initials required
srvrl/qa/forms/hrrunlog doc (02/05/97)
ConCal Due
ConCa! Due:
-------
Triangle Lrhoratories, Inc.
.F Log
Instrument ID Column Type Column ID Plot Name In). Vol. Acquisition
^OU^ ^vS"-^ ^-sBCo^-^T TfiT-*- ,3.0 JL^ fj£>&O*v±
G/C
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** Dated initials required
6fw1/qa/formB/hfruntog.doc (02/05/97)
ConCal Due:
ConCal Due:
Paae: «^o &
-------
Triangle Laboratories, Inc.
Run Log
Instrument ID Column Type Column ID Plot Name Inl. Vol. Acquisition
G/C
jo pas- u$
U\_ 4/;r/tf
Signature
' Date
Filename
Date*
Time*
Project #
Sampled
No.
Client Sample ID
Syr
332
Operator/Date
Comments
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** Dated initials required
srvr1/qa/forms/hmjn!og.doe {02/05/17}
ConCal Due: T.Z. .
ConCal Due:
Page:.
20
-------
Triangle Laboratories, Inc.
Run Log
Instalment ID
Column Type
Column ID
Plot Name
In. Vol.
Acquisition
G/C
/ y !?y
-^ ff^&^f^—-
Signature
Date
Filename
Date"
Time*
Project #
Sample#
No.
Cllenl Sample ID
Syr
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Operator/Date
Comments*
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-------
Triangle Laboratories, Inc.
Run Log
Instrument ID Column Tvpe Column ID
•n D r~^ „ x-"" X"
TO r ^)^ i -i f ~>£ J? 99 1 s
Plot Name Inj, Vol. Acquisition
r< f J-^JL. ^-T,-V<"
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Signature
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Filename
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Time*
Project #
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Client Sample ID
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Operator/Date
Comments*
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* Transcribed from chromatographic data
*" Dated initials required
sn/r1/aa/forms/hrrunlog.doc (02/05/97)
ConCal Due:
ConCal Due:
-------
SAMPLE
DATA
Triangle Laboratories, Inc.
801 Capttola Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
919-544-5729 Fax * 919-544-5491
37
-------
TRIANGLE LABORATORIES OF RTF,
Sample Result Summary for Project
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
TOTAL TCDD
TOTAL PeCDD
TOTAL HxCDD
TOTAL HpCDD
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDF
TOTAL HpCDF
Method MIT2
U980780
TLI M23 Blank
ng
04/03/98
04/15/98
U
XAD
Soxhlet
(0,002)
(0.002)
(0.003)
(0.002)
(0.002)
(0.003)
0.01 J
{0.004}J
(0.002)
(0.002)
(0.002)
(0.002)
(0.002)
(0.002)
(0.002)
(0.002)
(0.003)
(0.002)
(0.002)
(0.002)
(0.003)
{0.004}
(0.002)
(0.002)
(0.002)
Analysis (DB-5)
W981017
M23-I-1
ng
04/03/98
04/16/98
W
M23
Soxhlet
(0.03)
(0.05)
(0.06)
(0.06)
(0.06)
(0.09)
(0.1)
0.05 B
(0.03)
(0.04)
(0.04)
(0.04)
(0.04)
(0.05)
(0.06)
(0.08)
(0.1)
(0.03)
(0.05)
(0.06)
(0.09)
0.09
{0.06}
(0.04)
(0.06)
INC.
45399
W981018
M23-I-2
ng
04/03/98
04/16/98
W
M23
Soxhlet
(0.04)
(0.07)
(0.09)
(0.08)
(0.08)
(0.1)
{0.29}
1.5
0.21
0.21
0.10 J
{0.05} J
(0.06)
(0.07)
{0.05} J
(0.1)
(0.1)
0.25
{0.11}
0.07
(0.1)
12.1
2.7
0.33
{0.05}
Page 1
04/21/98
T981957
M23-I-3
ng
04/03/98
04/18/98
T
M23
Soxhlet
(0.003)
(0.004)
(0.007)
(0.007)
(0.007)
(0.01)
{0.03} JB
0.02 B
(0.003)
(0.003)
{0.007}J
{0.004}J
(0.004)
(0.005)
0.009 J
(0.008)
(0.02)
0.01
(0.004)
(0.007)
(0.01)
0.11
0.02
0.01
0.009
Other Standards Percent Recovery Summary (% Rec)
37C1-TCDD 87.9 83.3 84.7
Other Standards Percent Recovery Summary (% Rec)
13C12-PeCDF 234 106 89.3 88.8
13C12-HxCDF 478 108 78.3 81.0
13C12-HxCDD 478 114 75.5 75.6
13C12-HpCDF 789 90.1 83.6 85.1
Other Standards Percent Recovery Summary (% Rec)
13C12-HXCDF 789 84.5 82.4 90.3
13C12-HxCDF 234 81.8. 114 78.2
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF 65.8 71.2 73.1
13C12-2378-TCDD 67.9 78.1 74.0
84,9
94.9
87.6
90.8
68.1
80.1
94.0
76.6
71.7
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:23 04/21/98
-------
TRIANGLE LABORATORIES OF RTF, INC.
Sample Result Summary for Project 45399
Method MIT2 Analysis (DB-5)
Page 2
04/21/98
Data File
Sample ID
U980780
TLI M23 Blank
W981017
M23-I-1
W981018
M23-I-2
T981957
M23-I-3
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
ng
04/03/98
04/15/98
U
XAD
Soxhlet
ng
04/03/98
04/16/98
W
M23
Soxhlet
ng
04/03/98
04/16/98
W
M23
Soxhlet
ng
04/03/98
04/18/98
T
M23
Soxhlet
Internal Standards Percent Recovery Summary (% Rec)
13C12-PeCDF 123 68.6 68.5 64.9
13C12-PeCDD 123 99.4 71.8 68.3
13C12-HXCDF 678 68.1 119 87.9
13C12-HxCDD 678 78.7 115 93.0
13C12-HpCDF 678 83.7 115 100.0
13C12-HpCDD 678 92.5 116 107
13C12-OCDD 83.0 103 95.4
72.6
80.1
101
93 .2
99.8
101
65.6
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:231
-------
T981958
M23-I-4
ng
04/03/98
04/18/98
T
M23
Soxhlet
T981959
M23-0-1
ng
04/03/98
04/18/98
T
M23
Soxhlet
T981960
M23-O-2
ng
04/03/98
04/18/98
T
M23
Soxhlet
S982305
M23-0-3
ng
04/03/98
04/18/98
S
M23
Soxhlet
TRIANGLE LABORATORIES OF RTP, INC. Page 3
Sample Result Summary for Project 45399 04/21/98
Method MIT2 Analysis (DB-5)
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDD (0.003) (0.01) (0.006) (0.006)
12378-PeCDD (0.004) (0.02) (0.009) (0.009)
123478-HxCDD (0.006) (0.02) (0.01) (0.01)
123678-HxCDD (0.005) (0.02) (0.01) (0.01)
123789-HxCDD (0.005) (0.02) (0.01) (0.009)
1234678-HpCDD 0.008 J (0.03) 0.01 J (0.01)
OCDD 0.04 JB (0.05) {0.03} JB (0.02)
2378-TCDF 0.34 {0.02} B 0.03 B {0.007}JB
12378-PeCDF 0.04 J (0.01) (0.006) (0.006)
23478-PeCDF 0.04 J (0.01) (0.006) (0.006)
123478-HxCDF 0.01 J (0.01) (0.008) (0.006)
123678-HxCDF 0.008J (0.01) (0.007) (0.006)
234678-HxCDF 0.008J (0.01) (0.009) (0.007)
123789-HxCDF (0.004) (0.01) (0.01) (0.008)
1234678-HpCDF 0.007 J (0.02) {0.01} J (0.01)
1234789-HpCDF (0.007) (0.02) (0.02) (0.01)
OCDF (0.02) (0.04) (0.03) (0.01)
TOTAL TCDD 0.02 0.03 0.08 (0.006)
TOTAL PeCDD {0.003} (0.02) 0.03 (0.009)
TOTAL HxCDD 0.01 (0.02) (0.01) (0.01)
TOTAL HpCDD 0.02 (0.03) 0.01 (0.01)
TOTAL TCDF 2.6 {0.02} 0.25 {0.007}
TOTAL PeCDF 0.38 {0.01} 0.02 (0.006)
TOTAL HxCDF 0.05 (0.01) {0.007} (0.007)
TOTAL HpCDF 0.007 (0.02) {0.01} (0.01)
Other Standards Percent Recovery Summary (% Rec)
37C1-TCDD 88.9 92.6 87.1 96.7
Other Standards Percent Recovery Summary (% Rec)
13C12-PeCDF 234 96.0 107 98.8 102
13C12-HxCDF 478 92.2 91.3 91.0 97.4
13C12-HxCDD 478 93.2 99.4 95.9 96.5
13C12-HpCDF 789 76.0 84.8 82.2 95.2
Other Standards Percent Recovery Summary (% Rec)
13C12-HxCDF 789 76.1 38.5 V 66.8 62.9
13C12-HxCDF 234 75.6 39.2 V 73.2 65.3
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF 60.6 22.9 V 57.4 54.8
13C12-2378-TCDD 53.7 22.3 V 54.3 49.0
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitals Drive • Durham, North Carolina 27713 Printed: 11:23 04/21/98
Phone: (919) 544-5729 • Fax: (919) 544-5491 <|.Q
-------
TRIANGLE LABORATORIES OF RTF, INC.
Sample Result Summary for Project 45399
Method MIT2 Analysis (DB-5)
Page 4
04/21/98
Data File
Sample ID
T981958
M23-I-4
T981959
M23-0-1
T981960
M23-O-2
S982305
M23-0-3
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
ng
04/03/98
04/18/98 .
T
M23
Soxhlet
ng
04/03/98
04/18/98
T
M23
Soxhlet
ng
04/03/98
04/18/98
T
M23
Soxhlet
ng
04/03/98
04/18/98
S
M23
Soxhlet
Internal Standards Percent Recovery Summary (% Rec)
13C12-PeCDF 123 63.2
13C12-PeCDD 123 69.5
13012-HxCDF 678 72.2
13C12-HXCDD 678 70.5
13C12-HpCDF 678 65.5
13C12-HpCDD 678 68.4
13C12-OCDD 40.3
25
31.3
35.4
36.3
33
38
V
V
V
V
,7
.7
25.1
54.4
62.6
74.0
71.9
67.7
77.0
47.7
55.4
59.7
63.9
72,6
54.3
65.5
63.1
Triangle Laboratories, Inc.® Analytical Services Division
801 CapKola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:23 04/21/98
-------
TRIANGLE LABORATORIES OF RTF, INC.
Sample Result Summary for Project 45399
Method MIT2 Analysis (DB-5)
Page 5
04/21/98
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
S982306
M23-O-4
ng
04/03/98
04/18/98
S
M23
Soxhlet
S982307
M23-FB-1
ng
04/03/98
04/18/98
S
M23
Soxhlet
S982308
M23-FB-2
ng
04/03/98
04/18/98
S
M23
Soxhlet
S982309
M23-FB-3
ng
04/03/98
04/18/98
S
M23
Soxhlet .
Analytes
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
TOTAL TCDD
TOTAL PeCDD
TOTAL HxCDD
TOTAL HpCDD
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDF
TOTAL HpCDF
(0.004)
(0.006)
(0.008)
(0.007)
(0.007)
{0.01} J
0.05 JB
0.02 JB
(0.004)
(0.004)
(0.005)
(0.005)
(0.006)
(0.006)
(0.007)
(0.01)
(0.01)
(0.004)
(0.006)
{0.009}
{0.01}
0.17
0.01
0.008
(0.008)
(0.003)
(0.005)
(0.005)
(0.005)
(0.004)
(0.005)
(0.006)
(0.002)
(0.004)
(0.004)
(0.003)
(0.003)
(0.004)
(0.004)
(0.004)
(0.005)
(0.004)
(0.003)
(0.005)
(0.005)
(0.005)
(0.002)
(0.004)
(0.004)
(0.005)
Other Standards Percent Recovery Summary (% Rec)
37C1-TCDD 91.8 93.5
Other Standards Percent Recovery Summary (% Rec)
13C12-PeCDF 234 89.7 106
13C12-HXCDF 478 93.4 90.4
13C12-HxCDD 478 83.8 92.9
13C12-HpCDF 789 104 110
Other Standards Percent Recovery Summary (% Rec)
13C12-HxCDF 789 87.0 84.9
13C12-HxCDF 234 86.1 87.4
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF 79.7 74.4
13C12-2378-TCDD 64.1 63.1
(0.004)
(0.005)
(0.006)
(0.006)
(0.006)
(0.006)
(0.009)
0.005 JB
(0.004)
(0.004)
(0.004)
(0.004)
(0.004)
(0.004)
(0.005)
(0.006)
(0.006)
(0.004)
(0.005)
(0.006)
(0.006)
0.005
(0.004)
(0.004)
(0.005)
92.1
107
84.6
85.0
82.6
85.6
87.6
70.4
66.2
(0.003)
(0.005)
(0.005)
(0.005)
(0.005)
(0.006)
(0.008)
(0.002)
(0.004)
(0.004)
(0.004)
(0.003)
(0.004)
(0.004)
(0.005)
(0.006)
(0.006)
(0.003)
(0.005)
(0.005)
(0.006)
(0.002)
(0.004)
(0.004)
0.008
93.8
99.6
83.7
90.3
85.4
88.0
87.6
63.8
63.4
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:2304/21/98
-------
TRIANGLE LABORATORIES OF RTF, INC.
Sample Result Summary for Project 45399
Method MIT2 Analysis (DB-5)
Page 6
04/21/98
Data File
Sample ID
S982306
M23-0-4
S982307
M23-FB-1
S982308
M23-FB-2
S982309
M23-FB-3
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
ng
04/03/98
04/18/98
S
M23
Soxhlet
ng
04/03/98
04/18/98
S
M23
Soxhlet
ng
04/03/98
04/18/98
S
M23
Soxhlet
ng
04/03/98
04/18/98
S
M23
Soxhlet
Internal Standards Percent Recovery Summary (% Rec)
13C12-PeCDF 123 70.7
13C12-PeCDD 123 68.3
13C12-HxCDF 678 80.5
13C12-HxCDD 678 95.3
13C12-HpCDF 678 74.4
13C12-HpCDD 678 87.2
13C12-OCDD 93.8
70.1
83.6
72.8
91.
80,
106
119
.7
,5
72.1
95.3
96.7
104
102
133
114
.2
.3
.5
64,
74.
84.
97.8
82.6
99.2
104
Triangle Laboratories, Inc.® Analytical Services Division
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Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:23 04/21/98
43
-------
TRIANGLE LABORATORIES OF RTF, INC.
Sample Result Summary for Project 45399
Method MIT2 Analysis (DB-5)
Page 7
04/21/98
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
S982310
M23-RB-1-4
ng
04/03/98
04/18/98
S
M23
Soxhlet
Analytes
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
TOTAL TCDD
TOTAL PeCDD
TOTAL. HxCDD
TOTAL HpCDD
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDF
TOTAL HpCDF
(0.003)
(0.004)
(0.004)
(0.004)
(0.004)
(0.004)
(0.005)
(0.002)
(0.003)
(0.003)
(0.003)
(0.003)
(0.003)
(0.003)
(0.003)
(0.004)
(0.004)
(0.003)
(0.004)
(0.004)
(0.004)
(0.002)
(0.003)
(0.003)
(0.004)
Other Standards Percent Recovery Summary (% Rec)
37C1-TCDD 83.8
Other Standards Percent Recovery Summary (% Rec)
13C12-PeCDF 234 101
13C12-HxCDF 478 82.5
13C12-HXCDD 478 82.5
13C12-HpCDF 789 95.2
Other Standards Percent Recovery Summary (% Rec)
13C12-HxCDF 789 87.7
13C12-HXCDF 234 89.1
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF 66.0
13C12-2378-TCDD 59.9
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:23 04/21/98
-------
TRIANGLE LABORATORIES OF RTF, INC. Page 8
Sample Result Summary for Project 45399 04/21/98
Method MIT2 Analysis (DB-5)
Data File S982310
Sample ID M23-RB-1-4
Units ng
Extraction Date 04/03/98
Analysis Date 04/18/98
Instrument S
Matrix M23
Extraction Type Soxhlet
Internal Standards Percent Recovery Summary (% Rec)
13C12-PeCDF
13C12-PeCDD
13C12-HxCDF
13012-HxCDD
13C12-HpCDF
13C12-HpCDD
13C12-OCDD
123
123
678
678
678
678
62
76
81
97
82
101
115
.5
.1
.6
,6
.8
{Estimated Maximum Possible Concentration}, {Detection Limit).
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitals Drive • Durham, North Carolina 27713 Printed: 11:23 04/21/98
Phone: (919) 544-5729 • Fax: (919) 544-5491
-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project 45399
Method 23X (DB-225)
Page 1
04/20/98
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
P981305
TLI M23 Blank
ng
04/03/98
04/16/98
P
XAD
Analytes
2378-TCDF
P981306
M23-I-1
04/03/98
04/16/98
P
M23
P981307
M23-I-2
ng
04/03/98
04/16/98
P
M23
P981308
M23-I-3
ng
04/03/98
04/16/98
P
M23
(0.005)
{0.007}JB
0.51
{0.007}JB
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF 69.2 80.4
73.5
79.7
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 21:38 04/20/38
4(
-------
TRIANGLE
Sample Result
LABORATORIES , INC .
Summary for Project
45399
Page 2
04/20/98
Method 23X (DB-225)
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
P981309
M23-I-4
ng
04/03/98
04/16/98
P
M23
P981310
M23-0-1
ng
04/03/98
04/16/98
P
M23
P981311
M23-O-2
ng
04/03/98
04/16/98
P
M23
P981312
M23-O-3
ng
04/03/98
04/16/98
P
M23
Analytes
2378-TCDF
0.14
(0.01)
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF 56.1 21.4 V
0.01 JB
54.0
(0.007)
60.0
Triangle Laboratories, Inc.® Analytical Services Division
801 Captola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 21:38 04/20/98
-------
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDF
TRIANGLE
Sample Result
Meth
P981317
M23-0-4
ng
04/03/98
04/17/98
P
M23
(0.005)
LABORATORIES, INC.
Summary for Project 45399
.od 23X (DB-225)
P981319
M23-FB-2
ng
04/03/98
04/17/98
P
M23
(0.005)
Page 3
04/20/98
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF 75.5 73.7
(Estimated Maximum Possible Concentration), (Detection Limit)
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 21:38 04/20/98
-------
Method 8290 Sample Calculations:
Analyte Concentration
The concentration or amount of any analyte is calculated using the following expression.
Qa)-
Ap *
* W
Where:
C((J) = concentration or amount of a given analyte
A
-------
Data Flags
In order to assist with data interpretation, data qualifier flags are used on the final reports.
Please note that all data qualifier flags are subjective and are applied as consistently as
possible. Each flag has been reviewed by two independent Chemists and the impact of the
data qualifier flag on the quality of the data discussed above. The most commonly used
flags are:
A 'B' flag is used to indicate that an analyte has been detected in the laboratory method
blank as well as in an associated field sample. The 'B' flag is used only when the
concentration of analyte found in the sample is less than 20 times that found in the
associated blank. This flag denotes possible contribution of background laboratory
contamination to the concentration or amount of that analyte detected in the field sample.
An 'E' flag is used to indicate a concentration based on an analyte to internal standard
ratio which exceeds the range of the calibration curve. Values which are outside the
calibration curve are estimates only.
An 'I' flag is used to indicate labeled standards have been interfered with on the GC
column by coeluting, interferent peaks. The interference may have caused the standard's
area to be overestimated. All quantitations relative to this standard, therefore, may be
underestimated.
A ' J' flag is used to indicate a concentration based on an analyte to internal standard ratio
which is below the calibration curve. Values which are outside the calibration curve are
estimates only.
A 'PR' flag is used to indicate that a GC peak is poorly resolved. This resolution problem
may be seen as two closely eluting peaks without a reasonable valley between the peak
tops, overly broad peaks, or peaks whose shapes vary greatly from a normal distribution.
The concentrations or amounts reported for such peaks are most likely overestimated.
A 'Q' flag is used to indicate the presence of QC ion instabilities caused by quantitative
interferences.
An 'RO' flag is used to indicate that a labeled standard has an ion abundance ratio that is
outside of the acceptable QC limits, most likely due to a coeluting interference. This may
have caused the percent recovery of the standard to be overestimated. All quantitations
versus this standard, therefore, may be underestimated.
An 'S' flag indicates that the response of a specific PCDD/PCDF isomer has exceeded the
normal dynamic range of the mass spectrometer detection system. The corresponding
signal is saturated and the reported analyte concentration is a 'minimum estimate'. When
the 'S' qualifier is used in the reporting of 'totals', there is saturation of one (not
Data Flags Page 1 of 2
Rev. 11/19/97
5(
-------
necessarily from a specific isomer) or more saturated signals for a given class of
compounds.
A 'U* flag is used to indicate that a specific isomer cannot be resolved from a large, co-
eluting interferent GC peak. The specific isomer is reported as not detected as a valid
concentration cannot be determined. The calculated detection limit, therefore, should be
considered an underestimated value.
A 'V flag is used to indicate that, although the percent recovery of a labeled standard may
be below a specific QC limit, the signal-to-noise ratio of the peak is greater than ten-to-
one. The standard is considered reliably quantifiable. All quantitations derived from the
standard are considered valid as well.
An 'X' flag is used to indicate that a pentachlorodibenzofuran (PCDF) peak has eluted at
the same time as the associated diphenyl ether (DPE) and that the DPE peak intensity is at
least ten percent of the total PCDF peak intensity. Total PCDF values are flagged 'X' if
the total DPE contribution to the total PCDF value is greater than ten percent. All PCDF
peaks that are significantly influenced by the presence of DPE peaks are either reported as
"estimated maximum possible concentration (EMPC) values without regard to the isotopic
abundance ratio, or are included in the detection limit value depending on the analytical
method.
Data Flap Page 2 of 2
Rev. 11/19/97
51
-------
Method 23 Sample Calculations:
Analyte Concentration
The concentration or amount of any analyte is calculated using the following expression.
Where:
w
An%,5 = amount of a given analyte, expressed in nanograms (ng) or picograms
(Pg).
AC = integrated current for the characteristic ions of the analyte
Ap = integrated current of the characteristic ions of the corresponding
internal standard
Qp = amount of internal standard added to the sample before extraction
RRF(0) = mean analyte relative response factor from the initial calibration
W = sample weight or volume (W = 1 .0 for Method 23 samples)
Detection Limits
The detection limit reported for a target analyte that is not detected or presents an analyte
response that is less than 2.5 times the background level is calculated by using the
following expression. The area of the analyte is replaced by the noise level measured in a
region of the chromatogram clear of genuine GC signals multiplied by an empirically
determined factor. The detection limits represent the maximum possible concentration of
a target analyte that could be present without being detected.
2 * 2.5 * (F * H) * Q*
Where:
DL(0) :
2.5
F
H
Ap
Qp
RRF(0)
w
estimated detection limit for a target analyte, expressed in ng or pg
minimum response required for a GC signal
an empirical number that approximates the area to height ratio for a
GC signal. (F = 3.7 for all dioxin/furan analyses)
height of the noise
integrated current of the characteristic ions of the corresponding
internal standard
amount of internal standard added to the sample before extraction
mean analyte relative response factor from the initial calibration
sample weight or volume
Rev. 11/19/97
52
-------
TLI Project: 45399
Client Sample: TLI M23 Blank
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U980780
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
r012.Q02/Lime Kiln
XAD
TLI Blank
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
/ /
04/03/98
04/15/98
n/a
U980780
ML
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPMIT204
UF51058
U980771
n/a
n/a
n/a
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8,-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
ND
ND
ND
ND
ND
ND
0,01
EMPC
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.002
0.002
0.003
0.002
0.002
0.003
0.002
0.002
0.002
0.002
0.002
0.002
0.002
0.002
0.003
0.86
38:23
0.004
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
ND
ND
ND
ND
EMPC
ND
ND
ND
0.002
0.002
0.002
0.003
0.002
0.002
0.002
0.004
Page 1 of 2
MO7_PSR vl.04, LARS 6.11.00
Triangle Laboratories, Inc.®
801 Capitola Drive » Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:40 04/20/98
53
-------
TLI Project: 45399
Client Sample: TLI M23 Blank
Method 23 PCDD/PCDF Analysis (a)
Analysis File: U980780
'3Ci2-2,3,7,8-TCDF
13Ci2-2,3J,8-TCDD
13Ci2-l,2,3,7,8-PeCDF
l3C,2-l,2,3J,8-PeCDD
l3C,2-l,2,3,6,7»8-HxCDF
13C,2-l,2,3,6,7,8-HxCDD
l3Ci2-l,2,3,4,6,7,8-HpCDF
I3Cp-l,2,3,4,6,7,8-HpCDD
"CP-1,2,3,4,6,7,8,9-OCDD
°Ci2-2,3,4J,8-PeCDF
13Cp-l,2,3,4,7,8-HxCDF
13C,2-l,2,3,4,7,8-HxCDD
13C,2-l,2,3,4,7,8,9-HpCDF
Ull
2.6
2.7
2.7
4.0
2,7
3.1
3.3
37
66
tiii
4.2
43
4.6
3.6
|f|l|
65.8
67.9
68.6
99.4
68.1
78.7
83.7
92.5
83.0
106
108
114
90.1
40%-130%
40%- 130%
40%- 130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
40%- 130%
40%-130%
40%-130%
25%-130%
- 0.77
0.81
1.48
1.50
0.50
1.23
0.39
LOO
0.87
1.46
0.49
1.22
0.42
23:21
24:07
27:32
28:38
31:15
31:57
34:04
35:03
38:22
28:17
31:10
31:53
35:30
37Cl4-2,3,7,8-TCDD
3.5
87,9
40%-130%
24:08
13C12-l,2,3,7,8,9-HxCDF
13G,2-2,3,4,6,7,8-HxCDF
3.4
3.3
84.5
81.8
40%-130%
40%-130%
0.50
0.50
32:30
31:46
13C,rl,2,3,4-TCDD
13C12-l,2,3J,8,9-HxCDD
0.82
1.20
23:55
32:16
Data Reviewer
Page 2 of 2
04/20/98
Mmj>SR vl .04, LARS 6.11.00
Triangle Laboratories, Inc.®
801 Capitola Drive»Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:40 04/20/98
54
-------
Initial
....Date.
Data Review By:
Calculated Noise Area:
4.07
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
04/20/98
Listing of U980780B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
DC NL 0 :
23:
00
22
0.
RO
RO
65-0.89
0.
0.
62
45
1 Peak
DC NL 0:
DC WL 22:
22:
23:
23:
00
13
54
21
49
0.
RO
RO
15.
32.
32.
06
25 14.03
25
65-0.89
1.
0.
0.
0.
0.
3 Peaks
DC NL 0:00
DC SN 23:20
D
D SN 24:08
DC SN 24:21
DC SN 24:30
320-322
37C1-TCDD
328
0.
RO
RO
RO
RO
RO
96
76
87
77 27,
99
27,
65-0.89
0.
3.
0.
1.
1.
63
39
43
36
,70
0 Peaks
6.
318.
121.
052.
69.
21
34
02 56.22
70 11,732.50
14 38.57
0.844-
0.
31.51 1.
0.957-
0.
0.
64.80 0.
15,320.20 1.
39.06 1.
1.086
000
001 2378-TCDF
1.043
000
951
981
000 13C12-2378-TCDF
020
AN
ISO
242.86
4.
90
8.18
18.
85
2.60
2.16
0.878-1.050
0.
0.
1.
1.
1.
000
968
001 2378-TCDD
010
016
AN
0.00
0.917-1.083
DC NL 0:00
22:
:37
1.39
17.02 17.02
24:08
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
2 Peaks
DC NL 0
22
23
24
24
:00
:53
:55
:07
:29
0.
RO
RO
18
18
,717
,734
.10 18,717.10
.12
.65-0.89
2
1
0
0
0
4 Peaks
DC NL 0
DC SN 25
DC SN 25
DC SN 26
:00
:29
:4S
:05
1
RO
RO
RO
RO
.10
.12
.82 28
.81 21
.79
49
.32-1.78
0
2
0
0
.84
.89
.72
.47
13
104
,009
,268
318
.54
.54 66.07
.20 12,615.40
.95 9,538.45
.23 140.18
0.000
0
1
.938
.001 37C1-TCDD
CLS
0.917-1.083
0
59.06 0
15,393.80 0
11,730.50 1
178.05 1
.000
.949
.992 13C12-1234-TCDD
.000 13C12-2378-TCDD
.015
RSI
I SI
,700.92
TCDD / PeCDF Follows —
4
5
3
3
.33
.38
.36
.64
0.917
0
0
0
0
-1.068
.000
.926
.937
.947
Triangle Laboratories, Inc.® Analytical Services Division
801 Cap'rtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:40 04/20/98
55
-------
Pacje No.
04/20/98
Listing of U98Q780B.db£
Matched GC leaks / Ratio / Ret. Time
Compound/
M_Z..., QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.I.,
Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
340-342
13C12-PeCDF
352-354
352-354
PeCDD
356-358
D
D
356-358
13C12 -PeCDD
368-370
368-370
HxCDF
374-376
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
D
DC
D
DC
DC
DC
DC
DC
DC
DC
DC
DC
SM
SN
SM
SN
SN
SN
SN
SN
SN
SN
0
NL
7
NL
SN
SN
SN
SH
SN
SN
WH
WH
0
NIL
4
NL
SN
SN
SN
26:26 RO
26:39 RO
26:49
26:58 RO
27:10 RO
28:11
28:17 RO
28:25
29:14 RO
29:20 RO
Peaks
i.:
0:00
26:38
27:10
27:32
27:51
28:17
28:38
29:16
Peaks
1.
0:00 RO
26:55 RO
27:32 RO
27:39
28:17
28:36 EO
29:05 RO
29:22 RO
29:38 RO
Peaks
1.
0:00 SO
27:32
28:38
28:46
29:00 RO
, Peaks
1
0:00
31:11
31:53 RO
31:56 RO
0.16
0.57
1.43
0.43
0.52
1.73
2.08
1.50
0.99
0.72
J2-1.78
1.46
1.49
1.34
1.48 21,
1.53
1.46 22,
1.66
1.58
45,
32-1.78
0.69
0.59
1.08
1.72
1.77
2.08
0.93
0.36
1.17
32-1.78
0.98
1.64
1.50 16
1.53 1
3.03
17
.05-1.43
1.30
1.07
0.71
0.25
1.07
5.74
1,65
2.50
5.91
4.61
5.99
4.95
4.95
2.50
0,00
3.27
515.16 308.00
43.38 24.88
926.89 13,102.30
168.38 101.84
359.52 13,285.30
44.32 27.66
65.71 40.27
123.36
]@CDF / PeCDD Follows -— •
1.83
5.26
15.14
3.13
15.90
3.70
4.28
2.37
6.70
0.00
2.39
28.72 17.85
,427.29 9,847.36
,424.21 860.99
13.36 15.88
,893.58
PeCDD / HxCDF Follows — -
10.44
8.09
4.15
3.16
0.960
0.968
0.974
0.979
0.987
1.024
1.027 23478-PeCDF
1.032
1.062
1.065
0.855-1.145
0.000
207.16 0.967
18.50 0.987
8,824.59 1.000 13C12-PeCDF 123
66.54 1.012
9,074.22 1.027 13C12-P6CDF 234
16.66 1.040
25.44 1.063
0.928-1.022
0.000
0.940
0.962
0.966
0.988
0.999 12378-PeCDD
1.016
1.026
1.035
0.860-1.140
0.000
10.87 0.962
6,579.93 1.000 13C12-PeCDD 123
563.22 1.005
5.24 1.013
0.959-1,047
0.000
0.998 123478-HxCDF
1.020
1.022
KS
IS2
SUR1
AN
I S3
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capttola Drive « Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:40 04/20/98
-------
Page No.
04/20/98
Listing of U980780B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Confound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total,Area... Area.Peak.1.. Area.Peak.2,. Rel.RT Conpound, Name.. ID.. Flags.
D
374-376
13C12-HXCDF
384-386
384-386
DC SN 32:04 RO 0.34
DC SN 32:07 RO 2.02
DC SN 32:11 RO 3.67
DC SN 32:29 RO 0.73
D SN 32:31 1.11
DC WH 32:55 RO 0.42
0 Peaks
0.43-0.59
DC NL 0:00 RO 1.27
30ilO 0.45
30:18 0.47
31:10 0.49
31:15 0.50
31:46 0.50
32:30 0.50
6 Peaks
1,64
2.93
2.53
6.20
11.58
3.54
0.00
11.01
211.83 66.19
252.65 80.95
19,894.83 6,563.63
22,345.35 7,415.55
24,229.50 8,099.80
19,282.44 6,456.14
86,216.60
1.026
1.028
1.030
1.039 123789-HxCDF
1.041
1.053
0.872-1.128
0.000
145.64 0.965
171.70 0.970
13,331.20 0.997 13C12-HXCDF 478
14,929.80 1,000 13C12-HXCDP 678
16,129.70 1.017 13C12-HXCDF 234
12,326.30 1.040 13C12-HXCDF 789
AN
SDR2
1 34
ALT2
ALT1
HxCDD
390-392
D
D
390-392
13C12-HXCDD
402-404
402-404
HpCDF
408-410
408-410
13C12-HpCDF
418-420
418-420
1.05-1.43
DC NL 0:00 RO 0.83
D SN 31:10 RO 1.95
D SN 31:16 RO 2.30
DC SH 31:47 RO 3.01
DC WH 32:30 RO 8.36
0 Peaks
1.05-1 .43
DC NL 0:00 RO 1.03
31:22 1.17
31:53 1.22
31:57 1.23
32:16 1.20
9.45
13.75
13.53
9.61
4.75
0.00
15.99
76.16 40.99
15,985.15 8,798.58
19,092.35 10,538.10
24,384.70 13,317.20
0.955-1.014
0.000
0.975
0.979
0.995
1.017
0.969-1.031
0.000
35.17 0.982
7,186.57 0.998 13C12-HXCDD 478
8,554.25 1.000 13C12-HxCDD 678
11,067.50 1.010 13C12-HXCDD 789
SOR3
IS5
RS2
4 Peaks 59,538.36
0.88-1.20
DC NL 0:00 RO 2.42
DC SN 34:06 RO 2.70
DC SN 35:27 1.08
DC SN 35:36 RO 3.00
DC WH 35:43 RO 2.77
0 Peaks
0.37-0.51
DC ML 0:00 SO 0.60
34:04 0,39
35:30 0.42
2 Peaks
4.92
6.94
3.32
4.75
3.53
0.00
9.13
16,774.71 4,735.81
12,127.45 3,608.54
28,902.16
0.995-1.047
0.000
1.001 1234678-HpCDF
1.041
1.045
1.048
0.941-1,117
0.000
12,038.90 1.000 13C12-HpCDF 678
8,518.91 1.042 13C12-HpCDF 789
AN
IS6
SUR4
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:4004/20/98
-------
Page No.
04/20/98
Listing of U980780B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z,.,. QC.Log Ondt Why ,.RT. OK Ratio Total,Area... Area,Peak.1., Area.Peak,2., Rel.RT Compound.Name.. ID.. Flags.
Above: HpCDF / HpCDD Follows
HpCDD
424-426
424-426
0.88-1.20
DC NL 0:00 RO 0.36 1.61
DC ML 34:03 RO 2.59 10.38
DC SN 34:38 RO 4.74 2.33
0 Peaks 0.00
0.975-1.005
0.000
0.971
0.988
13C12-HpCDD 0.88-1.20
436-438 DC NL 0:00 SO 1.38 13.63
34:21 RO 1.30 80.62
35:03 1.00 16,382.49
436-438 2 Peaks 16,463.11
51.37
8,187.87
0.971-1.029
0.000
39.52 0.980
8,194.62 1.000 13C12-HpCDD 678 IS7
OCDF
442-444
442-444
OCDD
458-460
458-460
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SH
SN
SN
SN
SN
SN
SN
SN
1
NL
1
0:
34:
34:
35:
35:
35:
35:
35;
36:
38:
40:
40
40
00
34
39
03
29
37
48
:54
:54
:51
:39
:46
:55
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
76-1.02
0.
1.
0,
1.
1,
1.
1
0
2
0
2
1
1
97
.05
.72
.89
,15
.35
.10
.63
.02
. 35
.08
.91
.18
Peak
0
38
:00
:23
0.
RO
.76
2
0
-1.02
.18
.86
Peak
Above: HpCDD / Octa-CDD and CDF Follows
4.97
1.78
4.16
10.05
6.41
3.74
4.16
6.99
3.59
1.34
1.49
1.08
2.91
10.05
2.10
37.20
37.20
10.07
17.20
0.896-1.104
0.000
0.901
0.903
5.32 0.914
0.925
0.928
0.933
0.936
0.962
1.013
1.060
1.063
1.066
0.896-1.104
0.000
20.00 1.000 OCDD
AN
13C12-OCDD 0.76-1.02
470-472 DC NL 0:00 RO 2.50 1.91
38:22 0.87 22,056.70
470-472 1 Peak 22,056.70
10,248.60
0.995-1.004
0.000
11,808.10 1.000 13C12-OCDD
IS8
Column Description.
"Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
. .RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
*«* End of Report **«
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
File:U980780 #1-893 Acq:15-APR-1998 20:48:51 GC EI+ Voltage SIR 70S Noise:3276
03.9016 F:2 BSUB(256,30,-3 .0) PKD( 9,5, 3, 0 .10%, 13104 . 0, 1. 00%, F, T) Exp:NDB5US
TRIANGLE LABS Text:TLI M23 BLANK TLI#45399
1004 A1.40E5
20:00 21:00 22:00 23:00 24:00
File:U980780 #1-893 Acq:15-APR-1998 20:48:51 GC EI+ Voltage SIS 70S Noise:5246
305.8987 F:2 SSUS(256, 30,-3.0) PKD( 9,5, 3, 0.101,20984 . 0,1. 00%,f ,T) Exp:NDB5US
TRIANGLE LABS Text: TLI M23'BLANK TLI#45399
1003) A3. 5E5
8 01
601
401
201
OJ
20:00 21:00 22:00 2J.-00 24:00
F±le:U980780 #1-893 Acq:15-APR-1998 20:48:51 GC EI+ Voltage SIR 70S Noise:3441
315.9419 F:2 BSUB(256,30,-3 .0) PKD(9,5,3, 0.10%, 13764 . 0,1. 00%,f, T) Exp:NDB5US
TRIANGLE LABS Text:TLI M23 BLANK TLI#45399
1004 A1.J.7E8
aoi
601
401
201
01
801
601
401
201
OJ
A5.26E4
20:00 21:00. 22:00 23:00 24:00
File:U980780 #1-893 Acq:15-APR-1998 20:48:51 GC EI+ Voltage SIR 70S No±se:1753
317.9389 F:2 BSUB(256,30,-3.0) PKD(9, 5, 3, 0 .10%, 7012. 0,1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Text:TLI M23 BLANK TLI#45399
Al.j>3E8
8 01
601
401
201
01
20:00 21:00 22:00 2J.-00 24:00
File:U980780 #1-893 Acq:l'5-APR-1998 20:48:51 GC EI+ Voltage SIR 70S
330.9792 F:2 Exp:NDB5US
TRIANGLE LABS Text:TLI M23 BLANK TLI#45399
100% 20:23 21:10 „ 21:4.3 11.57 2-3:1.3 24:10 24j
80j
601
401
201
01
25:00
25:00
25:00
25:00
20:00 21:00 22:00 23:00
F±le:U980780 #1-893 Acq:15-APR-1998 20:48:51 GC EI+ Voltage SIR 70S
375.8364 F:2 Exp:NDB5US •. .
TRIANGLE LABS TextiTLI M23 BLANK TLI#45399
1004
24 : 00
801
601
401
201
01
20:25 20:45
21.- 06
21:59
22:36
23:58
22:59
24:21
25:00
[24:58
3.5E4
2.8E4
2.1E4
1.4E4
7.1E3
O.OEO
Time
.8.3E4
.6.6E4
.5.0E4
.3.3E4
.1. 7E4
.O.OEO
Time
.2.7E7
.2.2E7
.1 . 6E7
.1.1E7
.5.4E6
O.OEO
Time
.3.5E7
2.8E7
2.1E7
1.4E7
.6.9E6
.O.OEO
Time
.5.4E7
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Tim
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22:00
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24 : 00
25:00
O.OEO
Tim
-------
Lle:U9807BO #1-833 Acq:15-APR-1998 20:48:51 SC EI+ Voltage SIS 70S Koiae:1065
19.8965 F.-2 BSOB(256,3Q,-3.0) PKD( 7,5,3, 0.10%,4260.0,1,00%,F, T) Exp:lO}B5US
TRIANGLE LABS TextsTLI M23 BLANK TLI#45399
004 ' .. A1.57E5
22:00 23:00 24:00 25:00
±le:U980780 #1-893 Acq:15-APR-1998 20:48:51 GC EI+ Voltage SIR 70S Noiae:1687
21.8936 F:2 BSUB(256,30,-3.0) PKD(7,5,3,0.10%, 5748. 0,1.00%,F,2M ExpsNOBSUS
TRIANGLE LABS TextsTLI M23 BLANK TLI#45399
OOS . _ A1.92E5
22:00 , 23i00 24:00 25:00
File:U980780 #1-893 Acq:15-APR-1998 20:48:51 GC EI+ Voltage SIR 70S Noise:8036
331.9368 Fs2 BSUB(256,30,-3'.0) PKD(7,5,3, 0.10%,32144 . 0,1. 00%,f ,T> ExpsOOBSUS
TRIANGLE LABS TextsTLI M23 BLANK TLI#45399
1003s .al.26.E8
80J •' -
60J • •
40J
201
22:00 23:00 24:00 25:00
File:U980780 #1-893 AcqslS-APR-1998 20:48:51 GC EI+ Voltage SIR 70S Noise:3327
333.9338 F:2 BSUB(256, 30, -3 . 0) PKD(7, 5,3, 0 .10%, 15308. 0, 1. 00%,JP,TJ ExpsNDBSUS
TRIANGLE LABS Text: TLI M23 BLANK TLI #45399
1004
22:00 23:00 24:00
F±le:U980780 #1-893 Acq:15-APR-1998 20:48:51 GC EH- Voltage SIR 70s Noise:696
327.8847 F:2 BSUB(256, 30, -3. 0) PKD(7, 5,3, 0.10^,2784 . 0,1. 00%,F, T) Exp:NDB5aS
25:00
TRIANGLE LABS
1003,
TextsTLI M23l BLANK TLI#45399
File:(7380780 #1-893 Acqsl5-APR-1998 20:48:51 GC EH- Voltage SIR 70S
330.9792 F:2 ExpsNDBSUS
TRIANGLE LABS TextsTLI M23 BLANK TLI#45399
I0°iv^v~, 2il43 £2.101 ~ '22:31 22:54 23[1323',29 23:54.24:10,
'• v^H*w~wA-~^w^*C!^-~\ ^.A^fJwv*-***.
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-------
.File:US80780 #1-893 AcqslS-APR-1998 20:48:51 GC EI+ Voltage SIS 70S Noiae:1317
39.85S7 rt2 BSUS(256,30,-3.0) PKD(7,5,3, 0.10%, 5258. 0,1.00%, T,T) ExpsMDSSUS
TRIANGLE LABS TextsTLI M23 BLANK TLIi45399
1004 A6.09E4
A3 . 78E4
8Cj
26s00 27:00 28:00
file.-0380780 #1-893 Acq: 15-APR-1998 20:48:51 GC EI+ Voltage SIR 70S Noise:1568
341.8567 F:2 BSVB(256,30,'-3, 0) PKV(7, 5,3, 0.10%, 6272.0,1. 00%,F, T) Exp-.NDBSVS
TRIANGLE LASS TextsTLI M23 BLANK TLI#45399
100%
26:00 27:00 SB's 00
File:U9S0780 #1-893 Acq:15-APS-1998 20:48:51 GC EI+ Voltage SIS 70S Noise:971
351.9000 F:2 BSUB(256, 30, -3. 0) PKD{7, 5,3, 0.10%, 3884. 0,1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Texts HI M23 BLANK TLI#45399
1003,
60:
40.
20:
o:
A4.89E4
52E4
29:00
A7.27E4
29:00
26:00 27:00 28:00
File:U980780 #1-893 Acq:15-APS-1998 20:48:51 GC EH- Voltage SIS 70S Wo±ss:666
353.8970 F-.2 BSUB(256, 30, -3. 0) PKS(7, 5,3, 0.10^,2664 . 0,1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS TextiTLI M23 BLANK TLI#45399
100*
29:00
26s00 27:00 28:00
File:U9807aO #1-893 Acqsl5-APR~1998 20:48:51 SC SI+ Voltage SIK 70S
330.9792 F:2 Exp:NDB5US '
TRIANGLE LABS Teit:TLI M23 BLANK TLI#45399
100% 25:3125:47 26:09 27:00 27:45 28:17
60:
40,
20:
0.
29:00
28:38 28:56
-2.7E4
'-2.1E4
Ll. SE4
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Time
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\ 1
I
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Time
~2.6E7
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-1.5E7
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"-4.6E7
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26:00 27:00 28:00
FileiU980780 #1-893 Acq:15-APS-1998 20:48:51 GC EI+ Voltage SIS 70S
409.7974 F:2 Exp:NDB5US
TRIANGLE LABS TsxtiTLI H23 BLANK TLI#45399
29:00
tO. OEO
Tim,
26:00
27:00
28:00
29:00
61
-------
•ile:U9B0780 #1-993 Acqsl5-APK-rS98 2Q:M:51 G& £1+ Voltage"StX 70s KoiaesSSS
55.5546 Ts2 BSUS(256,30, -3.0) PKD(5,5,3,0.051,2220.0,1.00*,r,T) ExpiNDBSVS
TRIANGLE LABS TeitsTLI M23 BLANK TLI§45399
OOA
SOL
27:00 28:00 29:00
ile:U980780 #1-69,3 AcqslS-APS-1998 20:48:51 GC EI+ Voltage SIS 70S NoisesBOl
57.8516 Fi2 BSUS(25S,30r-3.0} PKB(S,5,3, 0.05%,3204.0,1.00%,f, T) EipsNDBSOS
TRIANGLE LABS Text:III M23 SLAIfK TLI#45399
003k A5.40E4
27:00 28:00 29:00
'ile:U98Q7BO #1-893 Acq;15-APR-1998 20:48:51 GC EI+ Voltage SIS 70S No±se:727
367.8949 F:2 BSUB(256, 30,-3 .0) PKD(5,5,3, 0.051,2908. 0,1. 00\fF ,T) Eip:NDB5US
TRIANGLE LABS Text:TLI M23 BLANK TLI045399
1003i A9.S5E7
801
so:
40:
20:
8.61ES
27:00 2S:00 29:00
File.-0980780 #1-893 Acq:15-APR-1998 20:48:51 GC EI+ Voltage SIS 70S No±aes740
369.8919 F-.2 BSUB(256,30, -3 .0) PKD(5,5,3,Q.05\,296Q.Q,1,QQ*,F,T) ExpiNDBSUS
TRIANGLE LABS Texts III M23 BLANK XLH45399
1004 A6.58E7
801
601
40.
201
0.
5.63E6
27:00 • ,28:00
File:U9S0790 #1-853 Acqsl>5-APR-1998 20:48:51 GC EH- Voltage SIR 70S
330.9792 Fi2 ExpsNDBSUS
TRIA&GLS LASS Texts TLI M23 BLANK TLI#45399
27:00 „.,, 27:45
801
601
401
201
0.
29:00
3.0E7
2.4E7
".1.8E7
-1.2E7
"-6.1E6
.O.OEO
Tim
2. OE7
'.1. 6E7
'.1.2E7
17.9E6
'.4.QE6
.O.OEO
Tim
'.4.6E7
"-3.4E7
12.3JT7
11.1JT7
27:00
28:00
29 s 00
.O.OEO
Tim
-------
File:tJ980780 #1-413 Acq:15-APR-1998 20:48:51 SC EI+ Voltage SIR 70S Noiaes2952
73.8208 F:3 SSUB(256,30, -3.0) PKD(7,5,3, 0.101,1.1808.0,1. 00%,F,T) EzpsNDBSUS
TRIANGLE LABS TextsTLI M23 BLANK TLI#45399
004 A4.19E4
30:00 30:12 30:24 30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
File:U9B0780 #1-413 Acq-.15-APR-1998 20:48:51 GC EI+ Voltage SIR 70S tfoiae:2272
375.8178 F:3 BSUB(256r 30, -3. 0) PKD(7, 5,3, 0.10%, 9088. 0,1. 00%,F, T) Exp:KDB5US
TRIANGLE LASS TextiTLI M23 BLANK TLI#45399
1004 A3.90E4 Al
A4. 73E4
30-00 30sl2 30:24 30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
File; 17980780 #1-413 Acg:15-APR-1998 20:48:51 GC EI+ Voltage SIR 70S Noiae:4632
383.8639 F:3 BSUS(256, 30, -3. 0) PKS(7, 5,3, 0.10^,18528. 0, 1. 00\,F,T) ExpsNOBSUS
TRIANGLE LABS Text:TLI H23 BLANK TLI#45399
IOCS A8.10E7
O.OEO
32:48 33:00 Time
80:
40.
0:
OOE5
A4.72E4
A1.29E4
^2.7E4
-2.1E4
-1. 6E4
-1.1E4
-5.4E3
40.
A6.56E7
A6.4SE7
O.OEO
32:48 33:00 Time
-2. 7E7
"-2.1E7
Ll - 6E7
'-1.1E7
15.4E6
.'•.O.OEO
Time
30sOO 30:12 30:24 30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00 32tl2 32:24 32:36 32:48 33:00
File.-0580780 #1-413 Acq:15-APX-1998 20:43:51 GC EI+ Voltage SIR 70S Noiaes3646
385.8610 F:3 BSUB(256,30, -3. 0) PKD( 7, 5, 3, C.10%,14534. 0,1. 00%,f,T; Exp'.NDBSDS
TRIANGLE LABS TextiTLI M23 BLANK TLI#45399
1004
aol
60:
40'
20!
Al.49S8
A1.2BE8
-5.2E7
-4.1E7
-3.1E7
-2.1E7
.1. OE7
O.OEO
30-00 30:12 30:24 30:36 30:48 31:00 31:12 31:24 31:36 31s48 32:00 32:12 32:24 32:36 32:48 33sOO
File:V980780 #1-413 AcgslS-APR-1998 20:48:51 GC EI+ Voltage SIR 70S
392.9760 F:3 Exp-.NDBSUS : '
TRIANGLE LABS TextsTLI M23 BLANK TLI#45399
Time
1003
aol
60:
40:
20:
0:
30:17
30:38
30:57
31:24 31:3531:45
2.5E7
•-2.0E7
':!. 5E7
Ll. OE7
is. OE6
I I I I I k t I [ 1 1 > I I I I 1 t I" ! I ' i '"I I t 1 [ 1 I I I t j 1 1 t I I t I 1 I 1 1 I I 1 t t 1 t I ! t I I [' I t I I ! I 1 I t I I [ I I
30.-00 30.-12 30:24 30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24
File:U980780 #1-413 Acq:15-APS-199S 20:48:51 SC EI+ Voltage SIS 70S
445.7555 F:3 Exp:m>B5US
TRIANGLE LABS Tsxt:TLI H23 BLANK TLI045399
........i... ,.Mro-°E°
32:36 32:48 33:00 Tim,
30-00 3011.2 30\24' 30\36"30\'
-------
ile:U9B07aO 11-413 Acq:15-APR-159B 20:4ffsSl Gt EI+ voltage SIS 7Q"S' KoTae:2614
89.8156 F:3 BSDB(2S6, 30,-3.0) PKD(7,5,3, 0.101,10456. 0,1.00*,F, T) ExpsUDBSUS
TRIANGLE LASS TMtiXZT M23 BLANK TLI#45399
004 A1.39ES
801
30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
ile:U980780 #1-413 Acq:15-APR-1998 20:48:51 GC Eli- Voltage SIS 70S Noiae:3167
91.8127 F:3 BSUB{256,30, -3. 0) PKD(7, 5,3, 0.10%, 12558.0,1.00\,r,T) EipiKDBSUS
TRIANGLE LABS XezttXLI H23 BLANK TLH45399
00* . A6.14E4
O.OEO
Time
30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
File:U980780 §1-413 AcyslS-APR-1998 20:48:51 SC EH- Voltage SIS 70S Noises4424
01.8558 T:3 BSUB(25S,30,-3.0) PKD(7,5,3rO,10%,17696.0,1.00%,FfT! Exp:M)B5US
TRIANGLE LABS TextsTLI M23 BLANK TLI#45399
;00i A1.33E8
801
601
401
201
Al. 05E8
".3.2E7
.2.4E7
.1. 6E7
.8.1E6
30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00 32sl2 32:24 32:36
File:U9807BO #1-413 Acqil5-APR-1998 20:48:51 SC EI+ Foltagre SIS 70S No±se:4307
403.8529 F:3 BSUB( 256, 30,-3. 0) PKD(7, 5,3, 0,10%, 17228.0,1.00%,F,T; EtpsNDBSUS
TRIANGLE LABS Text:TLI M23 BLANK TLI#45399
100* . A1-11E8
.O.OEO
Time
801
601
40.
20.
A8.55E7
30:36 30:48 31:00 .. 31:12 31:24 31i36 31:48 32:00
file:U980780 §1-413 Acqsl5-APS-1998 20:48:51 SC Eli- Voltage SIR 70S
392.9760 F:3 ExpsNDBSUS !
TRIANGLE LABS TextiTLI M23 BLASK TLIH45399
1003: 30i38 . 30:57. 31:06 31:24
32:12 32:24
32:36
801
601
40.
201
31:35
32• °° 32:11 32:19 J2:3032 „
.3.4E7
.2. 7E7
.2.0E7
.1. 3E7
.6.7E6
.O.OEO
rim
-2.5E7
12.0E7
_1.5£7
_1. 0£7
.5.0E6
30:36 30:48
31:00 , 31:12
31:24
31i36 31:48
32:00
32:12 32:24
32:36
O.OEO
Tim
-------
File:U9S0780 #1-662 Acq:15-APR-1998 20:48:51 GC EI+ Voltage SIS 703 Noiae:2920
07.7818 rs4 BSUB(256,30,-3.0) PKD(7,5, 3, 0.10%, 11680.0,1.00%, F, IF,) ExpsNDBSUS
TRIANGLE LASS TextiTZI H23 BLANK HI#45359
1003
80: A9.19E4 , A1.72E4
sol
401
20:
0J
34:00 34s 12 34:24 34:36 34:43 35:00 35:12 35:24 35:36
File .-17980780 #1-662 Acq:15-APR-1998 20:48:51 GC EI+ Voltage SIS 70S Noiae:1203
409.7789 F:4 BSUB(256,3Q, -3.0) PKD(7,5,3, 0.101,4812. 0,1.00%,F, T) EipsNDBSUS
TRIANGLE LASS TextsTLI M23 BLANK TLI#4S399
100S AS. 8E4
aol
sol
401
201
34:00 34:12 34:24 34:36 34-48 35:00 35:12 35:24 35:36
File:U980780 #1-662 Acq:15-APS-199a 20:48:51 GC EI+ Voltage SIS 70S Noiae:1898
417.8253 F:4 BSUS(256,30,-3.0) PKD(7,5,3, 0.10%, 7592. 0,1 -00%,P,TJ Eip:NDB5US
TRIANGLE LABS Teit-.TLI M23 BLANK 2X1 #45399
A4. 79E4
.4.2E4
"-3.4E4
L2.5E4
-1. 7E4
.8.4E3
35:48
36s
O.OEO
00 Time
2.6E4
''.2.1E4
Ll - 6E4
_1. 1E4
_5. 3£3
35:48
File:U980780 #1-662 Acqtl5-APR-1998 20.-48.-51 GC EI+ Voltage SIR 70S Woiae.-3168
419.8220 Fs4 BSUB(256,30,-3 .0) PKD(7, 5,3, 0.10^,12672. 0,1. 00%,F, T) Elp-.NDBSUS
TRIANGLE LABS Text.iTLI M23 BLANK TLH45399
File:(79807SO #1-662 J5ccr:lS-APB-1998 20:48:51 SC EI+ Voltage SIR 70S
430.9729 F:4 Exp:NDB5US
TRIANGLE LABS Teit:TLI M23 BLANK TLI#45399
100% 34.-05 34:16
60J
40J
201
ol
3S.-47
34.-00 34;12 34:24 34:36 34s4fl 35sOO 35:12 35:24
F±le:U980780 #1-662 AcqilS-APS-1998 20:48:51 SC EI+ Voltage SIS 70S
479.7165 F:4 Eip:NDB5US
TRIANGLE LABS TeitsTLI M23 BLANK TLI#45399
1003j '• 35105
aol
601
401
20.
ol
35136
35:48
34.- 00
34s 12
34:24
34:36
34:48
35:00
35:12
35:24
35:36
35:48
36:
O.OEO
00 Tine
003
ao:
601
401
2ol
Q-
A4 . 74E7
A
/
\ A3 . 61E7
.1.4E7
Ll . 1E7
L8.5E6
L5.7E6
L2.8JE6
• 0 . OEO
34:00 34:12 34.-24 34:36 34:48 35:00 35:12 35:24 35:36 35:48 36:00 Ti
ui/3
60:
40:
201
^iJL . -SU.C.O
I \ A8.52E7
1 \ A
/ \ A
' 34:00' ' '34:12' ' '3'4«24' ' ' 34136' ' ' 34\48 ' '3S:do' ' ' 35\12' ' ' 35\24 ' 35:36' ' ' 35\4a' ' ' 36\
"-2.7E7
"-2.0S7
"•-1.4E7
"-6.8E6
"• 0 . OEO
00 Time
_1. 7E7
Ll,3£7
Ll. OE7
L6.6E6
l3. 3E6
''.O.OEO
36:00 Time
_5.6£4
E.4.5S4
-3.4E4
_2,3E4
..1.1S4
.0.OEO
36:00 Tim
-------
ile:U9a0780 H-662 Ae
-------
File;-.11980780 #1-662 Acq:15-AfR-1998 20:48:51 GC EI+ Voltage SIS 70S Noiae:1226
41,7428 F:4 BSOS(256, 30, -3 . 0) PXD( 7, 5,3, 0.10%,4904 . 0,1. 00%, T, T) SxpiSDBSUS
TRIANGLE LABS Text = 2X1 M23 BLANK TLH45399
1004 A1.01E5
34'sOO 35"iOO , 36-00 37-00 38-00 39:00 40:00
File:U980780 #1-662 Acqil5-APR-1998 20:48:51 GC EH- Voltage SIS 70S Noise:1262
443.7399 F:4 BSUB(256,30, -3 . 0) PKV(7,5,3, 0.10%, 5048. 0,1. QQ\,F, T) Exp:NDB5US
TRIANGLE MBS Texts III M23 BLANK TLI#45399
A1.64E4 A2.93E4
1.J.3E4
O.OEO
00 riffle
41:27
34sOO 35:00 36:00 37:00 38:00 39:00 40:00
File:U9S07SO #1-662 Acq:15-APR-1998 20:40:51 SC EI+ Voltage SIR 70S
430.9729 F:4 Eip-.lfDSSUS
TRIANGLE LABS TextsTLI H23 BLANK TLI#45399
100% 34:05. ™. =„ 36:02 -,-,.„-, ,„ ,^ 39:22
40:22
901
aoi
701
sol
sol
402
301
20.
101
0.
41: 00
1. 7E7
Ll. 5E7
•
ll. 3E7
L1.2E7
Ll. OE7
ia.3E6
16.6E6
IS.OE'S
13.3E6
Ll. 7E6
34:00 35:00 36:00 37:00 38sOO 39:00
F±le:U9BQ780 #1-6S2 Mcij:15-APR-1998 20:48:51 SC JEX+ Voltage SIS 70S
513.6775 Fs4 ExptSSBSUS
TRIANGLE LABS TertiTLI M23 BLANK TLI#45399
lOOjk
40:00
411 00
42
LO.OEO
: 00 Tim,
34 : 00
35:00
36:00
37:00
39:00
40:00
41:00
42
IO.OEO
00 Tim
67
-------
±le:U980780 #1-662 Acq:15-APR-l99B 20:46:51 sc EI+ Voltage SIR 70s Noiae:12ll
57.7377 F-.4 BSUS(256, 30, -3 . 0) PKD(7, 5,3, 0.10*, 4844. 0,1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Text:TLI M23 BLANK TLI#45399
003, Al. 72E5
BO:
eo:
40.
20.
38 12 38:18 38:24 38:30 38:36 38:42
ile:U980780 #1-662 Acq:15-APB-1998 20:48:51 GC EI+ Voltage SIS 70S Noise:556
59.7348 F-.4 BSUB(256 , 30,-3 . 0 ) PKD(7, 5, 3, 0.101,2224 . 0,1. 00%,f, T) Exp:NDB5US
TRIANGLE LABS Text-.TLI M23 BLANK TLI#45399
003, A2.00E5
60:
40:
20:
38:48
A9.06E3
38:12 38:18 . 38:24 38:30 38:36 38:42
File:U980780 #1-662 Ac
-------
CD
Peak Locate Examination:15-APR-1998:20:47 File:U980780
Experiment:NDB5US Function:2 Reference:PFK
-------
TLI Project: 45399 Method 23 TCDD/TCDF Analysis (DB-225)
Client Sample: TLI M23 Blank Analysis File: P981305
Client Project:
Sample Matrix:
TLI ID:
r012.002/Lime Kiln
XAD Date Received: / /
TLI Blank Date Extracted: 04/03/98
Date Analyzed: 04/16/98
Spike File: SPC2NF04
ICal: PF24098
ConCal: P981302
Sample Size:
Dry Weight:
GC Column:
1.000
n/a
DB-225
Dilution Factor: n/a
Blank File: U980780
Analyst: BJG
% Moisture: n/a
% Lipid: n/a
% Solids: n/a
2,3,7,8-TCDF
0.005
»Cn-2,3,7,S-TCDF
2.8
69.2
40%-130%
0.75
22:23
l3Cu-l,2,3,4-TCDD
0.78
21:17
Data Reviewer.
Page 1 of 1
04/20/98
C2NFJ>SR «.02, URS 6.11.00
Triangle Laboratories, inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 21:27 04/20/98
70
-------
Data Review By!
Calculated Noise Area:
0.13
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No,
04/20/98
Listing of P981305B,dbf
Hatched GC Peaks / Ratio / Eet. Time
Compound/
M_Z QC.Log Omit Why ..ST. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Confound.Name.. ID.. Flags.
TCDF
304-306
304-306
0.65-0.89
DC HL 0:00 RO 1.00
0 Peaks
0.14
0.00
0.790-1.102
0.000
13CX2-TCDF
316-318
316-318
13C12-TCDD
332-334
332-334
DC
DC
DC
DC
DC
DC
NL 0:00
HL 20:58
HL 21:14
22:23
SN 23:02
WH 24:25
1 Peak
NL 0:00
19t54
21:00
21sl7
22:00
4 Peaks
0.65-0.89
RO 1.13
0.88
0.75
0.75
RO 1.40
0.87
0.65-0.89
RO 1.22
RO 1 . 04
0.78
0.78
0.75
0.14
0.81
2.19
257.47 110.10
0.27
2.62
257.47
Above: TCDF / TCDD Follows -
0.16
0.42
181.15
276.72
1.45
459.74
0.25
79.63
121.27
0.62
0.955-1.045
0.000
0.937
0.949
147.37 1.000 13C12-2378-TCDF ISO
1.029
1.091
0.905-1.095
0.000
0.24 0.948
101.52 1.000 13C12-2378-TCDD IS1
1S5.45 1.013 13C12-1234-TCDD RSI
0.83 1.048
Column Description.
"Why" Code Description OC Log Desc.
K_Z -Nominal Ion Mass(es) WL-Below Retention Time Window A-Peak Added
..RT. -Retention Time {mtmssS WH-Above Retention Tine Window K-Peak Kept
Rat.l -Ratio of M/M+2 Ions SN-Below Signal to Noise Level D-Peak Deleted
OK -RO=Ratio Outside Limits
-------
rile:t>9ai305 II-IUM AcytlS-ApA-lSSB 1S:43:JJ> Ei+ yoltage Sl» JUP
303.9016 Eicp:DB225
TRIANGLE LASS Texts III M23 BHUOC TLI045399
1004 22 24
SSl
90.
85:
80:
75:
70:
65.
60l
55:
50J
45:
40:
35.
301
25.
20:
I5^
10:
5:
0
21
File
315.
CTZfl
100J
9Sl
90;
85_
80.
75.
70.
65.
60.
55.
50.
45.
40.
35
30
25
20
15
10
5
0
21
21 : 59
•- • 2,2:08
I i nfl A 1 I 1 ii L Jl 1
I J^N |1 mjk 1 jJ ni J fll vn f
HyT !^! V 1 IHfly ' y
23:14
22:34 22=49 33.07\ "I28
] i 1 Tli, 1 23i"53
LA nl llidl I k3i44m
Tiyii^^ w ipyw^ ^
y • • • i
i/:.v*"V-¥K .»'f- 5.C3-
JUc M:fi4|^J
i
S.1E2
8.2E2
7.8E2
.7.3E2
.6.8E2
.6.4E2
t. OP3
.5.5£2
.5.0E2
.4.ff£2
.4.1E2
.3 . 6E2
.3.2E2
-2.7E2
-2.3E2
_1 . 8E2
L1.4E2
IS.lEl
-.4.6E1
- 0 . OEO
•00 21812 21:24 2lijff' 2li48 22loO izi'jii ' 32»24 ' 22s35 22 .-48 23:00 23:12 23!-24 23l-3e 23:48 24 00 Time
-.P981305 #1-1006 Acg:lS-APB-19S8 15.-42.-3S El* Vbltagre SJJ? 70l>
9419 £rp.-£B225
JTCLE lABS Text.-XCJ M23 BIANIT HI #45399
2 -.23 2.5E5
J ! '
- '
**
-."• -
.r ;
i
' J
' 00 21:12 21t24 21:3$ 21:48 22:00 22:12 22:24 22:3fi 22>48 23:00 23clJ 23:24 23:3ff 23:48 24
'•.2.4ES
.2.2S5
'-.3.1X5
12.0E5
L1.9E5
.1 . 7E5
Ll.SES
LI.5Z5
Ll.4£5
L1.2E5
Ll.125
Li . OES
.8.7E4
L7.5E4
LS.2E4
L5.0£4
-.3 . 7E4
L2.5E4
L1.2JE4
: 00 Tim
72
-------
'H
-------
#1-1006 Acg:16-APS-199B 15:42:39 EI+ Voltage SIS 70P Noiae:4l)
19.8965 BSOS(2S6,30,-3.0) PKD( 5,3,1, 0. 10%, 160.0,0. 00%, T, T) Exp:DB225
TRIANGLE LABS Text.-TEX M23 BLANK TLI#45399
DOS,
19:00 20:00 21:00 22:00 23:00
ile:P98130S #1-1006 Acq:16-APS-1998 15:42:39 EI+ Voltage SIS 70P Noise:34
21.8936 BSOB(256,30,-3.0) PKD( 5,3,1,0.10%, 136.0,0. 00*,f,F) Exp:DB225
TRIANGLE LABS Text:TLI M23 BLANK TLI845399
004
so:
so:
40:
20.
A865.02 M1g,70
A325.27
19:00 20:00 21:00 22:00 23:00
File:P981305 #1-1006 Acq:16-APS-1998 15:42:39 EI+ Voltage SIR 70P Noiae:47
27.8847 BSUB(256,30,-3.0) PKD(5, 3,1, 0.101,188.0,0. 00*,F,F) Exp:DB225
TRIANGLE LABS Text.-TEX M23 BLANK TLI#45399
1003, Al. E6
so:
so:
40.
20.
19:00 20:00 21:00 22:00 23:00
rile:P981305 #1-1006 Acqil6-APR-1998 15:42:39 EH- Voltage SIR 70P Noiae:54
331.9368 BSUB(256,30,-3.0) PKD(5,3,1, 0.101,216.0, 0. 00\,F,F) Exp:DB225
TRIANGLE LABS Text.-IXJ M23 BLANK TLI#45399
1004 A1.21E6
80.
60.
40.
20.
A7.96E5
19:00 20:00 21:00 22:00 23:00
rile:P981305 #1-1006 Acqrl6-APR-1998 15:42:39 EI+ Voltage SIR TOP Noiae:43
333.9338 BSUB(256,30,-3.0) PJO>(5,3, 1, 0.101,172.0, 0. 00\,r,F) Exp:DB225
TRIANGLE LABS rext.-TLJ M23 BLANK TLI#45399
1004 A1.55E6
80.
60.
40:
20.
0.
Al.02E6
24:00
24 : 00
24:00
24: 00
-3.1E2
-2.3E2
.1.6E2
-7.8E1
O.OEO
Time
-4.3E5
.3.5E5
-2.6E5
_1. 7E5
.B.7E4
.O.OEO
Tim'
-2.9E5
-2.3E5
11. 8E5
.1.2E5
.5. 9E4
O.OEO
Tia
^3. 7E5
-3.0E5
.2.2E5
.1.5E5
.7.4E4
19:00
2Q: 00
21:00
22:00
23:00
24:00
O.OEO
Tia
74
-------
ile:P9S130S #1-1006 Acq:16-APR-1998 15:42:39 EI+ Voltage SIR 70P
03,9016 ExpsDB225
TRXAHGLE LASS TextiTLI H23 BLANK TLH4S399
18,00 19s00 20:00 21:00
yils.-PS81.305 fl-1006 Acq:16-APR-1998 15:42:39 EH-
15.9419 Exp:DB225
TRIANGLE LABS Text.:TLI H23 BLANK TZH45399
ao:
so:
40:
20:
o:
18:00 19:00 20:00 21:00 22:
FilesP981305 fl-1006 Acq:16-APR-1998 15:42:39 EH- Voltage
319.8965 Exp:DB225
TRIANGLE LABS Text: TLI If23 BLANK TLI#45399
1003
ao:
001
80:
60:
40:
20:
o:
17:54
19^3630:01
2A:36
20:59
21:59
21:38
23'14
23:53 24:28
7.5E2
.5.6S2
L3.7E2
•.1.SE2
33:
00
SIR 70P
23:00
24:00
25:
•-0, OEO
00 Time
-.2.5E5
•-2.0E5
ll, 5E5
.1. OE5
•-S.OE4
00
SIS 70P
23:00
24 : 00
25:
f.O.OEO
00 Time
18:00 19:00 20:00 21:00 22,
File:P981305 01-1006 Acq:16-APR-19S8 15:42:39 EX+ Voltage
331.9368 Ezp:DB225
TRIANGLE LABS Text:TLI ff23 BLANK TLI#45399
100S 21*17
00
SIX 70P
23:00
24:00
25:
80:
40:
20:
o:
21:00
-2.9E5
1.2.3E5
.1.8E5
.1.2E5
.5.9E4
J \
O.OEO
18:00 19s00 20:00 21:00 22:00
File:P981305 fl-1006 Acq:16-APS-lS98 15:42:39 J5J* Voltage SIS 70P
292.9825 Efp:DS225
TRIANGLE LABS Texts3X1 H23 BLANK TLI#45399
1003! 18-26 19:21 19,59 ,_ 31:09^.21,35 22:12 22ji
^*-*tf**
eo:
so:
40:
20:
0:
23:00
24:00
23:13 33:5024:15 24i47
25:00 Time
^4.7E5
.3.7E5
-2.8E5
'•.1.9X5
.9.4E4
18:00 19:00 20:00 31:00 22:00
f±le:P981305 #1-1006 Acg:16-APX-199S 15:42:39 EI+ Voltage SIR 70P
330.9792 Exp:DB225
TRIANGLE LABS TextiTZI M23 BLANK TLI#4S399
100* 1S.-50 21:24 21:59 22;
J _ j^^tart* *"«SJ»*
80.
60:
401
20:
0:
23:00
44
24:00
25:
O.OEO
00 Tim.
23140
24:31
isVoo
sol oo
21-00
22:00
23s 00
-i—i—r—i—r-
24:00
.4.1E5
'•.3.1E5
•-2.QE5
Ll. OE5
25
O.OEO
00 Tim
-------
ft!P981385
tef. lass 232,3825 Peak top
Heiojt ,87 volts Span 288 ppi
Systei file naie
file naie
Resolution
Qroupnuibef
lonlzatusn ndt
Sultchuig
Ref. lasses 232,3825,
315,9413
wm
321,8936
327,884;
338,9792
292,9825
383,9816
J
K
L
1
1
El*
mm
338,9761
338,9792
333,9338
375,8364
I 338,9792 Peak top
,87 wits Span Seeppi
-------
TLI Project:
Client Sample: M23-I-1
Method 23 PCDD/PCDF Analysis (a)
Analysis File: W981017
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
r012,002/Lime Kiln
M23
204-92-1A-D
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
04/01/98
04/03/98
04/16/98
n/a
U980780
WK
Spike File:
KM:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPMIT204
WF53178
W981012
n/a
n/a
n/a
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeGDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
ND
ND
ND
ND
ND
ND
ND
0.05
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.03
0.05
0.06
0.06
0.06
0.09
0.1
0.03
0.04
0.04
0.04
0.04
0.05
0.06
0.08
0.1
0.67
26:23 B_
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
ND
ND
ND
ND
0.09
EMPC
ND
ND
0.03
0.05
0.06
0.09
0.04
0.06
0.06
Page 1 of 2
Mm_PSR vl.04. LARS 6.11.00
Triangle Laboratories, Inc.?
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:40 04/2
-------
TLI Project: 45399
Client Sample: M23-I-1
Method 23 PCDD/PCDF Analysis (a)
Analysis File: W981017
l3Ci2-2,3,7,8-TCDF
13C12-2,3(7,8-TCDD
13CI2-l,2,3J,8-PeCDF
13C12-l,2,3J,8-PeCDD
13C,2-l,2,3,6,7,8-HxCDF
l3Ci2-l,2,3A7,8-HxCDD
13C12-l,2,3,4,6»7,8-HpCDF
'3Ci2-1,2,3,4,6,7,8-HpCDD
13e12-l,2,3,4,6,7,8,9-OCDD
2.8
3,1
2.7
2.9
4.8
4.6
4,6
4.6
8.3
71.2
78.1
68.5
71.8
119
115
115
116
103
40%-130%
40%-130%
40%-13Q%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
0.75
0.82
1.50
1.51
0.49
1.19
0.45
1.10
0.90
26:19
27:01
30:10
31:10
33:40
34:20
36:35
37:38
41:20
!3C12-2,3,4,7,8-PeCDF
13C12-l,2,3,4,7,8-HxCDF
1JCi2-l,2,3,4,7,8-HxCDD
13e,2-l,2,3,4,7,8,9-HpCDF
3.6
3.1
3.0
3.3
89.3
78.3
75.5
83.6
40%-130%
40%-130%
40%-130%
25%-130%
1.56
0.50
1.22
0.42
30:50
33:34
34:16
38:09
3.3
83.3
40%-130%
27:02
Alternate Standards (Type A)
1JC,2-l,2,3,7,8,9-HxCDF
13C,2-2,3,4,6,7,8-HxCDF
Recovery Standards
13C,2-1,2,3,4-TCDD
13Ci2-l,2,3J,8,9-HxCDD
Ami (ng)
3.3
4.5
% Recovery
82.4
114
QC Limits
40%-130%
40%-130%
Ratio
0.49
0.51
Ratio
0.79
1.19
RT
34:56
34:09
RT
26:51
34:40
Flags
—
Flags
—
Data Reviewer
04/20/98
Page 2 of 2
M1T2J>SR vl.04. LARS 6.11.00
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:40 04/20/98
-------
Initial . . . .Date. . ,
Data Review By:
M'tt
Calculated Noise Area:
1.58
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
04/20/98
Listing of W981Q17B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1,. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
A
M
304-306
13C12-TCDF
316-318
316-318
TGDD
320-322
320-322
37C1-TCDD
328
328
13C12-TCDD
332-334
332-334
DC NL 0:00
24:22
DC SN 25:55
26:23
2 Peaks
DC NL 0:00
DC ML 25:18
26:19
1 Peak
DC NL Os 00
DC SN 24:32
DC WH 28:30
0 Peaks
DC NL 0:00
DC WL 24:42
DC WL 24:52
25:42
DC SN 25:54
DC SN 26:41
27:02
27:26
DC SN 27:35
DC SN 27 : 43
DC SN 27:56
3 Peaks
DC NL 0:00
26:51
27:01
27:19
3 Peaks
0.65-0.89
RO 1 . 44
0.74
RO 1.46
0.67
0.65-0.89
0.87
0.78
0.75
0.65-0.89
RO 1.21
0.70
0.84
0.65-0.89
RO 2 . 08
0.79
0.82
RO 0.51
1
2.83
7.23 3.08
2.51
8.95 3.60
16.18
2.77
8.01
600.62 256.46
600.62
WTW / TyTir^ 17 r\l 1 nujc
1.84
2.64
2.10
O.OQ
0.91
0.58
0.68
7 . 87 7 . 87
0.86
0.36
423.24 423.24
4.90 4.90
1.28
0.83
1.54
436.01
2.09
606.53 268.63
495.22 222.39
5.72 2.49
,107.47
frnn / T>or- ns1 17^1 1 ™.»e
•0.878-1.072
0.000
4.15 0.926
0.985
5.35 1.003 2378-TCBF
0.962-1.038
0.000
0.961
344.16 1.000 13C12-2378-TCDF
0.903-1.042
0.000
0.908
1 . 055
0.926-1.074
0.000
0.914
0.920
0.951
0.959
0.988
1.001 37C1-TCDD
1.015
1.021
1.026
1.034
0.926-1.074
0.000
337.90 0.994 13C12-1234-TCDD
272.83 1.000 13C12-2378-TCDD
4,86 1.011
AN
ISO
CLS
RSI
IS1
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:40 04/20/98
79
-------
Page No.
04/20/98
Listing of W981017B.«a>£
Matched GC Peaks / Ratio / Rec. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Araa.Peak. 1. . Area. Peak. 2. . Rel.RT Compound. Name.. ID.. Flags.
PeCDF
340-342
D
340-342
13C12-PeCDF
352-354
352-354
PeCDD
356-358
356-358
13C12-PeCDD
368-370
368-370
HxCDF
374-376
374-376
DC
DC
D
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
WH
WH
1
NL
SN
SN
SN
SN
SN
SN
4
NL
SN
0
NL
SN
2
NL
SN
SN
SN
SN
WH
0
0:
28:
28:
29:
29:
29:
31:
31:
32:
32:
00
04
15
12
20
27
47
57
04
17
1.
RO
RO
RO
RO
RO
RO
RO
32-1.78
0.
0.
1.
1.
1.
1.
0.
0.
1.
1.
72
64
33
45
31
43
63
65
95
08
Peak
0:
28:
28:
28:
29:
29:
30:
30:
30:
30:
32:
00
29
33
58
18
49
01
10
26
50
06
1.
RO
RO
RO
RO
RO
RO
1.
1.
4.
2.
6.
3.
1.
0.
1.
1.
6.
48
07
80
06
38 3.88
14
40
87
58
61
38
32-1.78
0.
0.
1.
2.
1.
1.
0.
1.
1.
1.
0.
Peaks
0:
29:
00
24
1.
RO
RO
89
35
53
48
49
28
25
50
59
56
49
1.
0.
1.
1.
9.
2.
0.
435.
6.
374.
0.
824.
IfcaJ-'TYC
32-1.78
1.
0.
26
90
Peaks
0:
29:
31:
31:
00
20
10
18
1.
RO
RO
2.
45
44
01
96
07 5.43
75
48
21 260.95
16 3.78
22 228.19
95
66
* / p»f nn i?rti 1 <"M*ie — — —
02
1.89
0.930-1.060
0.
0.
0.
0.
2.96 0.
0.
1.
1.
1.
1.
000
930
936
968
972
976
054
059
063
070
0.867-1.133
0.
0.
0.
0.
3.64 0.
0.
0.
174.26 1.
2.38 1.
146.03 1.
1.
000
944
946
960
971
988
995
000 13C12-PeCDF 123 IS2
009
022 13C12-PeCDF 234 SOR1
064
0.939-1.020
0.
0.
000
943
0.00
32-1.78
1.
0.
1.
1.
Peaks
0:
32:
33:
00
58
02
1.
RO
RO
RO
33:12
35:06
35:
;21
RO
19
70
51
41
1.
96
0.84
252.15 151.74
32.94 19.28
0.872-1.128
0.
000
0.941
100.41 1.000 13C12-PeCDD 123 IS3
13.66 1.004
285.09
•B— /••«« / t*u^«t> T^t—1 1 ....._
05-1.43
1.46
2.68
1.59
1.20
1.
.19
0.48
Peaks
2.42
0.69
0.38
1.10
1.29
1.57
0.964-1.045
0.
.000
0.979
0.981
0.986
1.043
1.050
0.00
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:40 04/20/98
80
-------
Page No.
04/20/98
Listing of W981017B.db£
Matched GC Peaks / Ratio / Het. Time
Compound/
M_Z.... QC.Log Omit Why . .RT. OK Ratio Total-Area,.. Area. Peak. 1. . Area.Peak.2. . Rel.RT Coirapound, Maine.. ID,. Flags.
13C12-HXCDF
384-386
384-386
HxCDD
390-392
390-392
13C12-HXCDD
402-404
402-404
HpCDF
408-410
408-410
13C 12 -HpCDF
418-420
418-420
HpCDD
424-426
424-426
13C12-HpCDD
436-438
436-438
DC HL 0
DC SN 32
DC SN 32
33
33
34
34
;00
:44
:50
:34
:40
:09
:56
0.
RO
RO
43-0.59
0.
0.
0.
0.
0.
0.
0.
4 Peaks
DC NL 0:
1 00
1.
RO
64
44
76
50
49
51
49
05-1.43
0.
84
0 Peaks
DC NL 0:
34:
34;
34:
:QO
rie
;20
:40
1.
RO
2
3
0
284
352
319
175
.91
.17
.51
.21 95.01
.74 116.51
.35 107.65
.34 57.94
0.
189.20
236.23
211.70
117.40
881-1.119
0
0
0
• o
1
1
1
.000
.972
.975
.997 13C12-HXCDF 478
.000 13C12-HXCDF 678
.014 13C12-HXCDF 234
.038 13C12-HXCDF 789
SDE2
134
ALT2
ALT1
1,131.64
2
0
.26
.00
05-1.43
0.
1.
1.
1.
3 Peaks
DC NL 0:
DC SN 36:
DC SN 36:
;00
:35
: 47
0.
RO
RO
94
22
19
19
88-1.20
1.
3.
0.
08
51
39
0 Peaks
DC NL 0:
36:
DC SN 36:
38:
:00
•35
48
09
0.
RO
3
181
258
230
.43
.66 99.82
.65 140.79
.55 125.31
0.
0.
31.84
117.86
105.24
958-1.013
0
.000
971-1.029
0
0
1
1
.000
.998 13C12-HXCDD 478
.000 13C12-HXCDD 678
.010 13C12-HXCDD 789
SUR3
IS5
RS2
670.86
HxCDD / HnCDF" Po 1 !_ ows
2
1
0
0
.25
.00
.31
.00
37-0.51
0.
0.
0.
0.
2 Peaks
DC NL 0:
DC WH 38:
DC WH 38:
:00
:22
32
0.
RO
85
45
47
42
1
198
0
121
319
Uw*^*TY
88-1.20
1.
1.
0.
11
65
SI
0 Peaks
DC NL 0:
37:
DC WH 38:
DC WH 39:
:00
:38
40
:02
0.
RO
RO
EO
2
0
1
0
.97
.52 61.78
.69
.32 36.13
.84
.09
.94
.26
.00
88-1.20
1.
1.
1.
3.
36
10
89
68
1 Peak
2
175
1
0
175
.02
.47 91.96
.24
.57
.47
0,
0.
136.74
85.19
0.
0.
83.51
996-1.048
0
1
1
.000
.000 1234678-HpCDF
.005
AN
945-1.109
0
1
1
1
976
0
1
1
973
0
1
1
1
.000
.000 13C12-HpCDF 678
.006
.043 13C12-HpC0F 789
-1.004
.000
.019
.024
-1.027
.000
.000 13C12-HpCDD 678
.027
.037
1 36
SOR4
IS7
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:40 04/20/98
81
-------
Page No.
04/20/98
Listing of W981017B.dbf
Matched GC Peaks / Ratio / Eet. Time
Compound/
H_Z.... QC.Log Omit Why . .RT, OK Ratio Total.Area.,. Area.Peak.1.. Area.Peak.2,. Rel.RT Compound.Name.. ID.. Flags.
Above: HpCDD / Octa-CDD and CDF Follows
OCDF
442-444
442-444
OCDD
458-460
458-460
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
ML
WL
WL
WL
ML
SM
SB
SN
SH
SN
SN
SN
SN
SN
SN
SN
0
NL
0
0:
35:
36:
36:
36:
37:
37:
38:
38i
38:
33:
39:
39:
41:
41:
41:
00
42
15
28
31
22
28
09
15
25
45
03
43
19
28
32
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
76-
0.
li
1.
2.
2.
0.
0.
0.
0.
0.
0.
0.
1.
2.
0.
0.
1.02
86
39
58
00
38
28
34
07
77
24
74
21
40
13
41
36
Peaks
0:
00
0.
RO
.76-1.02
1.
08
Peaks
2.62
1.64
2.17
0.6S
0,74
0.57
0.45
0.30
1.88
1.02
1.97
1.21
1.58
1.64
0.64
1.15
0.00
1.80
0.00
0.903-1.097
0.000
0.864
0.877
0.882
0.883
0.904
0.906
0.923
0.925
0.929
0.938
0.945
0.961
.000
.003
1.
1.
1.005
0.903-1.097
0.000
13C12-OCDD 0.76-1.02
470-472 DC NL 0:00 RO 1.14 1.78
41:20 0.90 1S6.QO
DC WH 41:35 RO 0.43 2.31
470-472 1 Peak 196.00
92.84
0.996-1.004
0.000
103.16 1.000 13C12-OCDD
1.006
I S3
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass{es)
. .RT. -Retention Time (iran:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio outside Limits
Rel.RT-Relative Retention Time
**» End of Report **«
HL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
File:tf981017 #1-798 Acq:16-AFR-199B 16:19:38 SC EI+ Voltage SIS 70SE No±se:1153
303.9016 F:2 BSUB(256r 30, -3. 0) PKD(9,5,5, 0.10\,4612, 0,1. 00%,JF, T) ExpiNDBSUS
TRIANGLE LASS Tsxt'.M23-I-l TLX#45399
1004
.-00 ' 25s 00 26:00 27:00
File:W981017 #1-758 Acq:16-APR-1998 16:19:38 SC JET*- Voltage SIR 70SE Noise:802
305.8987 Fi2 BSUB(256,30,-3 .0) fKD(9, 5,5,0 .10^,3208. 0,1. 00%,r,T) Eip:NDB5aS
TRIANGLE LASS Text. :M2 3-1-1 TLX #45399
1004 '-• - »7. 4S4
aol
20
o
24:00 25:00 26:00 27:00
FilerW981017 #1-798 Acqil6-AfK-1998 16:19:38 GC XX + Voltage SIS 7QSE Soises647
315.9419 Ts2 BSUS(256,30,-3.0) PKD(9,5,5,0.10\,2588.0,1. 00\r,T) Eip:lO)B5US
TRIANGLE LABS Text:M23-I-l'- TLI#45399
1004 A2.56ES
801
sol
401
20:
24:00 '•• |, 25^00 26.-00 27.-00
F±le:tfS81017 #1-798 Acqil6-APR-1998 16:19:38 SC XX+ Voltage SIS 70SE Ko±aes738
317.9389 T:2 BSDB(256,30,\-3,,0) PKD(9,5,5,0.10\,2952.0,1.0Q\rr,T) Eip:SDB5US
TRIANGLE LABS TexttM23-£-l~- TLI#4S399
100S ;' '- A3.44E6
aol
eol
401
201
Q!
24:00 . 25:00 26:00 27iOO
rile:W981017 #1-798 Acqsl6-RfR-1998 16:19:38 GC EH- Voltage SIS 70SE
330.9792 Ft2 ExpiHDSSUS ,
TRIANGLE LABS TextsM23-l'-l . TLI#45399
100$ 23^27 ._24_jJ)6___•_ 24 -.4024^58 _J5j^6_ _2_5:51 26:36
28:00
28:00
28:00
28:00
_1.6E4
'-1.3E4
-9.8E3
•-6.5E3
'.3.3E3
LO.OEO
Time
7.0E5
1.5.6E5
"-4.2E5
.2.8E5
11.4E5
O.OEO
Time
-9. 4E5
1.7.5E5
"•.5.6E5
"-.3. 7E5
ll.9E5
801
60l
401
201
ol
27:11 27:32 27:57 28:22
O.OEO
Time
-1.9X7
ll. 6E7
"-1.2E7
"-7.8E6
'.3. 9E6
24s00 . 25:00 26:00 27-00
#1-798 &cq:16-APR-1999 16:19:38 GC EX+ Voltage SIX 70SE
375.8364 Fs2 ExpsNDSSUS
TRIANGLE LASS TextsM23-r-l'-' TLI#45399
1003,
28:00
LO.OEO
Time
24: 00
25:00
26:00
27:00
28:00
83
-------
FilesM981017 #1-798 AcqslS-APS-1998 16:19:38 SC SX+ Voltage SIX 70SE Noise: 629 ,X1»'V{"'
319.3965 F:2 BSOB(256,30, -3.0) PKD(7, 5, 3, 0.101,2516. 0,1. 00%, F,Tj ExpsNDBSUS ~+.l ~3\ ) ^
TRIANGLE LABS Text:M23-I-l TLI#45399 , -»O V '
1002,
aol
60:
40"
20:
o-
I
MJ
A1.32E4
W^w^\
A3. • OOE4 I 1
'Vf^/w ^YyJ™
A 14^
w\
-------
29:00 30:00 31:00
File:tf981017 #1-758 Aaqtl6-APR-199B 16:13:38 GC EI+ Voltage SIS 70SE Noise:625
341.8567 Fs2 BSUS(25S,30, -3. 0) FKD(7,5,3, 0.10%,2500.0,1.00%,J>,T> ExpiNDBSUS
TRIANGLE LASS Xeit:H23-I-l TLH45399
1004 • A2.96E4
29:00 30s00 31:00
File:ffS81017 #1-798 Acq:16-APX-199S 16:19:38 GC EI+ Voltage SIS 70SE Noises442
351.9000 F:2 BSUB(256,30, -3.0) PKD(7,5,3,0.10%,176S.O,1 ,00*,F,T) ExpsKDBSUS
TRIANGLE LASS Teit:M23-I-l TLI#4539$
1004 A2.61E6 A2.28E6
801
60l
401
File >V9 81017 #1-798 Acq:16-APR-199S 16:19:38 GC EX+ Voltage SIR 70SE Noise:450
339.8597 F:2 BStm{256,30, -3. 0) PKD(7, 5,3, 0.101,1800. 0,1. 00%,7, T) Ex
TRIASSZE JDSBS Text :M23-1-1 TLH45399
1003,
A3.
32:00
.OEO
Time
32:00
,7E5
.2ES
.6E5
,1ES
.5E5
.OEO
25:00 30:00 31:00
rilesW981017 #1-798 Acq:16-APS-1998 16:15:38 SC EI+ Voltage SIX 70SE Noise:494
353.8970 F:2 BSDB(256, 30, -3. 0) FJCDf 7,5,3, 0.10%, 1976. 0,1 . 00%, F,T) SxpsSDBSOS
TRIANGLE IABS Text:M23-I.-l'. TLI#45399
1004 Al. 4E6
A1.4SES
soJ
40
20:.
32:00
o
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29:00 30:00 31:00
File:M981017 tl-798 &cqs!6-APK-lS98 16sl9s3S GC EH- Voltage SIS 70SE
330.9792 F:2 Exp:ffl)B5aS
TRIANGLE LABS Text :M23-I-l' TLH45399
8j22 .. _^i8j59 29:25 30.03 3f>.t
1003
aol
60:
401
201
0:
32:00
31:47 32:09
29:00 30:00 31:00
FileifT981017 #1-798 Acq:16-APS-1998 1S.-19.-J8 GC EI+ Voltage SIS 70SE
409.7974 F:2 Exp:M)B5US
TRIANGLE LABS Text:M23-I~l TLI#4539S
1003
80:
601
401
201
ol
32:00
32:09
28:171 28:44 29l01 29:16
29:00
30:00
31:00
,1E5
.1E5
.1E5
,OE5
,OE5
,OEO
Time
,9E7
.5E7
,1E7
,5E6
.7E6
.OEO
Time
,3E4
.OE4
,8E3
,2E3
,6E3
,OEO
Time
85
-------
-.vg81017 '#l-?96'"AcqslS-APR-lS9B 16:15:36 GC EI+""Voltage 'SIS 70SE '
355.8546 Ti2 BSOB(2S6, 30, -3. 0) PKD( 7, 5, 3, 0.10*,2468. 0,1. 00%, F, T) ExpsKUBSUS
TXIAWGLE LABS Text:M23-I-l TZH45399
100$
29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00
FilesWS81017 #1-798 Acq:16-APS-1998 16:19:38 GC EI+ Voltage SIS 70SE Noime:489
357.8516 f:2 BSUB(256,30,-3.0) PKD( 7,5,3, 0,101,1956.0,1.00%,y,T) EipsKDBSVS
TRIANGLE LASS TextsM23-Irl, TZH45399
1004
80J
601
40.
204 . Al A.A/1 AA _ IIUA JTV/TA/ MVisjr.
so:
6Qi
40:
201
Al.15E4
A1.2SE4
A2.S2E3 ,. ':jll.30E4
i AS . 94E3
29:24 29:36 29:48 30:00 30sl2 30:24 30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00
File:W981017 #1-798 Acq:16-APS-1998 16:19:38 GC EH- Voltage SIS 70SE Noiae:S97
367.8949 fs2 BSVB(2S6,30,-3.Q) PJOJf 7,5, 3, 0.10\,23S8.0,1.00%,r,T) Eip-.KDSSOS
TRIANGZS LABS Text:M23-I-l' TLI#45399
1004 A1.?2E6
801
601
401
II
.93M5
29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00 31:12 31s24 31:36 31:48 32:00
File:ff981017 #1-796 Acg:16-APK-1998 16:19:38 GC EI+ Voltage SIS 70SE Noiae:501
369,8919 F:2 3502(256,30;-3.0 ) PKD( 7,5,3,0.10\,2004.0,l.QO*rf,T) Exp:NDBSVS
TRIANGLE LABS Text:M23-I-l TI,I#45399
lOOi, A1.00E6
801
601
401
201
37ES
L4.3E3
-3.2E3
.2.2E3
11, 1E3
O.OEO
Time
.1. 2E4
.9. SE3
.7.2E3
.4. 8E3
.2.4E3
.O.OEO
Time
.5.0E5
.4. OE5
.3. OE5
.2.0ES
.9. 9E4
.O.OEO
Time
3.2E5
'.2.6E5
11, SES
11. 3E5
16.4E4
.O.OEO
29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00 Time
rile:mSlQ17 #1-798 &cq:16-APX-1998 16:19:38 GC Ell- Voltage SIS 70SE
330.9792 f:2 Exp:NDB5aS
TRIANGLE LABS Text;]f23-I-l TLI#4S399
lOOSi, 2/JL25^ 30:OJ 30:46 ^.--«- ,,_,„ .-1.8.E7
so:
601
401
201
0.
t r""| r*"f""i""f'"I I i i r"!""r "["'""> ' i i""'1 | t i' r *>""<• t i i f t""t" j' i i i" i "T'l T"t T i '•^^-T^-iiM¥-iiii'iiT^r|T*T^r-T-|~r'r"iriT'TT i i i i r"i i i * i-T*T*rr"t i r r"i i i i
39*24 29:36 29t48 30:00 30:12 30:24 30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00
-1.5X7
-1.1X7
L7.3E6
L3.7E6
'.O.OEO
Tim:
86
-------
File:ff981017 #1-354 Acq:16-APS-1998 16:19:38 SC EI+ Voltage SIS JOSE .Noise: 788
373,8208 F-.3 BSU3(256, 30, -3. 0) PKD(7f 5, 3, 0.10%, 3152.0,1 .00%,f, T) EzptUDBSUS
TRIANGLE LABS TextsM23-I-l TLI#45399
1004 A8.33E3
sol
60:
40:
32:36 32:48 33:00 33:12 33:24 33:36 33i48 34:00 34:12 34:24 34:36 34:48 35:00 35:12 35:24
File:ff981017 #1-354 Acg:16-APS-1998 16:19:38 SC EI+ Voltage SIS 70SE No±se:538
375.8178 F:3 BSUB(256r30, -3, 0) PKD(7,5,3, 0.101,2152. 0,1. 00*,F,T) Eip:NDB5US
TRIANGLE LABS Text:M23-I-l TLI#45399
1003
80:
60:
32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00 35:12 35:24
FiletW9Bl017 #1-354 Acgsl6-APK-1998 16:19:38 SC EI+ Voltage SIS 7QSE Noise-.618
383.8639 F:3 BSUB(256,30r -3.0) PKD(7,5,3, 0.101,2472. 0,1. 00\,r, T) Eip-.NDBSOS
TRIANGLE LABS Text:M23-I-l TLI#45399
o
A8.71S3
8.SE3
.6.8E3
.5. 1E3
.3. 4E3
.1. 7E3
.O.OEO
Time
1003
aoj
601
401
Al.
.OSES
A5.79E5
32:36 32:48 33:00 !33:12 33s24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00 35:12 35:24
File.-US81017 #1-354 Acq:16->APR-1998 16:19:38 SC £1+ Voltage SIS 70SE Noiae-,963
385.8610 F:3 BSUB(256,3Q,'-3 .0) PXD(7,5, 3,0.10*,3852.0,1.00\rFrT) Elp:NDB5OS
TRIANGLE LABS TeJCt.-W23-J-l TLI#45399
100$
A2.12E6
8fld
601
401
20:
o
A1.17E6
.3 . 7E5
.3 . OE5
.2.2E5
.1.5E5
.7.4E4
.O.OEO
Time
.7.2E5
.5.8E5
.4.3E5
.2.SE5
.1 . 4E5
.0 . OEO
32:36 32:48 33sOO 33:12 33:24 33:36 33:48 34:00 34tl2 34:24 34:36 34:48 35-00
File.-WS81017 #1-354 AcgrslS-APX-1998 15:19:38 SC EX+ Voltage SIS 70SE
392.9760 F:3 JExp.-JSBBSOS
TRIANGLE LABS TextiM23-I-l TLI#45339
35-12 35:24
1003
sol
601
401
20:
ol
32:40 32:51
33:14 33,25
35:11 35:24
32:36 32:48 33:00 33:12 33s24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00 35:12 35:24
FileiWSSlOl? #1-354 &cqi!6-APS-199B 16:19:38 SC EI+ Voltage SIM 70SE
445.7555 F:3 Exp:SDB5US
TRIANGLE LABS TextsM23-I-l TLI#45399
1004 35fll 35:21
sol
501
401
20:
ol
32:
32:36 32:48 33s 00 33:12 33s24 33:36
.-OO 3412 34:24 34: 36 34148 35 -00
35:24
.9.8E6
.7.9E6
.5.9E6
.3.9E6
.2.0E6
.O.OEO
Time
.1.3E4
.1 . OE4
.7.6E3
.5.1E3
.2.5E3
.O.OEO
Time
87
-------
?ile:tfS810JL7 #1-354 Acq:lS-APS-1998 16:19:38 GC EI+ Voltage SIS 70SE Noise:626
389.8156 F:3 BSUS(256,30, -3. 0) PKD(7,5, 3, 0.10%,2504 .0,1. 00%,T, T) ExpiWBSUS
TSIASSLE LABS Text.stt23-I-l TZ.I&45399
IOCS A7.41E3
33'tOO 33-12 33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00
FilesWS81017 §1-354 Roqsl6-KPB-1998 15:19:38 SC EI+ Voltage SIS 70SE Noise: 741
391.8127 f:3 BStm(256,30,-3.0) pm(7,5,3,0.10%,2964.0,1.00*,F,T) Exp:lO)B5US
TRXAHSI.E IASS TexttM23-I-l TLW45399
1003
ao:
so:
40:
20L
33iOO 33:12 33:24 33i3S 33:48 34sOO 34:12 34:24 34:36 34:48 35sOO
#1-354 AcqilS-AfS-1338 16:19:38 SC SH- Voltage SIS 70SE No±mes9SO
401.8558 rs3 BSUB(256,30;-3.0) PKS(7,5,3, 0.10%,3800.0,1,00*,F,T) ExpsNDBSUS
TRIANGLE LABS Text:M23-I-l TLH45399
1003s A1.41E6
so:
so:
40:
20:
A1.25E6
33:00 33:12 33:24, 33:36 33:48 34sOO 34il2 34:24 34:36 34:48
File:H981017 #1-354 Acq:16-APK~lSS8 16:19:38 GC EI+ Voltage SIS 70SE Noise; 1014
403.8529 F:3 BSUB(256,30,-3.0) tJO)(7,5,3,0.10\r4056.0,1.00\,W,T) ExpsNDBSUS
TRIANGLE LABS TextsM23-I-l TLIV45399
1004 A1.J.8S6
35:00
so:
40.
20.
A1.05E6
3.3100 33:12 33:24 33:36 33:48 34:00 34:12 34:24 34:36
FJ.letWS81017 #1-354 Acq:16-APS-1998 16:19:38 SC EI+ Voltage SIS 70SE
392.9760 F:3 ExpsNDBSOS
TSIA«SI,E IASS Tei-tiH23-I-l
34:48 35:00
80.
60.
6.BE3
5.5E3
4.1E3
2.1 S3
1.4S3
O.OEO
Time
.S.3E3
.4.3E3
.3.2E3
',2.1X3
'.1.1E3
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rime
4.3E5
3.4E5
2.6E5
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Time
3. 6E5
".2.8m5
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Time
_S.8£6
7.9E6
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"'33! oo"
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33:36
33:48
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34:00
34112
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34:24
34 s 36
34:48
i i i i
35:00
.O.OEO
Time
-------
F±le:W981017 #1-590 Acq:16-APS-1998 16:19:38 GC EH- Voltage SIS 70SE Noise:587
407.7818 F:4 SSUB(256,30,-3.0) PXD( 7,5, 3, 0.101,2348. 0,1.00%, F,T) ExpiNDBSUS
TSIASGZE LABS Text:M23-I-l TLI#45399
1004
36:36 36-48 37-00 37:12 37:24 37:36 37:48 38:00 38:12
File:W981017 #1-590 Acgil6-APS-1998 16il9:38 GC EI+ Voltage SIS 70SE Noises539
409.7789 F:4 BSVB(256, 30, -3. 0) PKDf 7,5,3, 0.10^,2156. 0,1.00%, F,T) Exp:SDB5US
TRIANGLE LABS Text iff2 3-1-1.' TLIf 45399
1003:
38:24
80.;
601
401
201
A4.85E3
36:36 36:48 37:00 37:12 37:24 37:36 37:48 38:00 38:12
F±le:if9al017 #1-590 Acq:16-APK-1998 16:19:38 GC EH- Voltage SIS 70SE Noise: 581
417.8253 F:4 BSUB(256,30,-3.0) PKD(7, 5,3,0 .101,2324 .0,1. 00*,F,T) Eip:NDB5VS
TRIANGLE LASS XeitsM23-I-l TLH45399
38:24
1004
ao
40
A6.J.BE5
A3.61E5
36i3S 36:48 .37:00 37:13 37:24 37:36 37:48 38:00 38:12
#1-590 Acq:16-APK-l99B 16:19:38 GC EI+ Voltage SIS 70SE Noiae:686
419.8220 F:4 BSUS(256,30,.-3.0) PKD(7,5,3,0.101,2744.0,1.00%,f,T) Sxp:NDB5US
TRIANGLE LABS Xext:M23-i-l TLI#45399
38:24
1003
aol
601
401
20.
0-
A1.37E6
A8.52E5
36:36 36:48 37:00 37:12 37:24 37:36 37:48 38:00
F±lesW9B1017 #1-590 Acq:16-AfX-lS9B 16:19:38 GC JPI-f Voltage SIX 70SE
430.9729 F:4 ExptNDBSUS
TRIANGLE LABS Tsxt:M23-I-l TLH45399
38:12
38:24
38:36
•.O.OEO
Time
5.5E3
.4,4E3
.3.3E3
.2.2E3
.1.1E3
38:36
.O.OEO
Time
.1.7E5
-1.3E5
.1. OE5
-6.7E4
.3.4E4
38:36
O.OEO
Time
3.8E5
13.0E5
.2.3E5
•.1.5E5
.7.6E4
38:36
O.OEO
Time
003
ao:
401
20:
0'
•N-~^4£s£L_^__^=45 '36,59 37:09 37:24 37:33 37:49 38i04 38:14 3B£?2
36:36 36:46 37:00 37:12 37:24 37:36 37:48 38:00
FiletW981017 #1-590 Acg:16-APS-1998 16:19:38 GC EI+ Voltage SIS 70SE
479.7165 F:4 ExptXDBSIJS
TRIANGLE LABS Text:M23-I-l TLI#45399
100*. 36:43
38:12
38:24
38:36
60
401
201
0:
37:15
38:05
36:59
37 si
36:36
36:48
37:00
37:12
37:24
37:36
37:48
38:00
38:12
38:24
38:36
.6.3E6
.4.7E6
'-.3.2E6
Ll. 6E6
•.O.OEO
Time
-1.XE4
.8.8E3
'.6.6E3
.4. 4E3
.2.2E3
.O.OEO
Time
89
-------
fiJ.esW'981017 #1-530 Acq:16-APJt-19S8 16sl9:38 BC EC+ Voltage SIR 70SEJfoi.se:549
423.7766 F:4 BSOB(256,30, -3.0) PKE(7,5,3,0.10%,2196.0,1.00%,F, T) ExpiNDBSCJS
TRIANGLE LABS TextsM23-I-l TLI&45399
1004 A7. 3S3
37-00 38sOO 39:00
File:tf981017 #1-590 Acqil6-APS-1998 16:19:38 SC EI+ Voltage SIS JOSE Noises497
425.7737 F:4 BSUB(256,30,-3.0) PKD(7,5,3,0.10%, 1388.0,1. 00\,T, T) ExpsMDBSUS
TKIAtiSLE LABS Text:M23-I-l TLI#45399
100* A1.23S4 &3.Q7E3
SOJ
eo:
40:
201
AB.56E3
A1.17E4
37sOO 38iOO 39s00
rilestf981017 #1-590 AcqsL6-APS-199t !Ssl9:3B SC EH- Vtoltage SIR 70SE NoisesG77
435.8189 f:4 BSUB(256,30,-3.0) PKD(7,5,3,0.101,2708.0,1.00%,F,T) Exp:M)B5US
TRIANGLE LABS Text:M23-I-l TLH45399
1003k A9.20E5
80.
60.
40.
20.
37 tOO .-. 38s 00 39s 00
FilesW981017 #1-590 Acq:16-APS-1998 16tl9:38 SC EH- Voltage SIS 70SE Noi.ses493
437.8140 F:4 BSm(256,30,~3.0) PKD(7,5,3,0.101,1972.0,1.00%,J1, T) EipiNDBSUS
TRIANGLE LABS TttxtsM23-X-l-- TLH45399
1004 A8.35E5
ao:
eo:
40:
20:
37 sOO 38tOO 39:00
F±lesti981017 #1-590 Acqil6-AfS-1998 16:19:38 GC EH- Voltage SIS 70SE
430.9729 T:4 ExpiMDBSUS
TRIANGLE LABS Text:M23-I-l TLIt45399
36i59 37:33 37s49 . 38:14^ 38^32 _ 39:05 _
801
so:
40:
20:
0.
O.OEO
Time
.4.7E3
.3. 8E3
.2.8E3
.1.9E3
.9. 4E2
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Time
.2.2E5
.1.8E5
.1. 3E5
.9. OE4
.4.5E4
.0. OEO
ris
.2.1E5
.1. 7E5
.1.2E5
.8.3E4
.4.1E4
.O.OEO
rime
37:00
38s 00
39100
.7.5E6
.6.0E6
.4.5E6
.3. OE6
.1.5E6
.O.OEO
Time
90
-------
FileitfSBlOl? #1-590 Acq:16-APK-1998 16:19:38 GC EH- Voltage SIR 70SE Noise:606
441.7426 Fi4 SSm(2S6,30, -3.0) PXD(7,S,3,0,10\,2424.Q,1.00*,?,T) ExptODBSOS
TRIWSLE LASS Text:M23-I-l TL1#45399
100%
36s00 37:00 38:00 39:00 40:00 41:00
File:W981017 #1-590 Acq:16-APK-1998 16.-I9.-3S SC EI+ Voltage SIS 70SE No±se:707
443.7399 F:4 BSUB(256,30f -3.0) PJDJf 7,5,3,0.101,2828.0,1. 00\,F,X) Exp-.UDBSUS
TRIANGLE LASS Text:M23-I-l TLI#45399
1003, Al.$2£4
O.OEO
42:00
43:00 Time
A6.24E3
JU..73E4
M.3.01E1
36:00 37-00 30:00 39:00 40:00
JPi.lssH9a.I017 #1-590 &cq:16-APM-1998 16sl9s38 SC EI+ Voltage SIX 70SE
430.9729 f:4 ExpsNDBSUS
TRIKKGX.E LASS Text:M23-I-l' XLI445399
1003
90\
801
701
601
sol
401
301
201
10!
01
36:04
41:52
42:33
8.5E6
''•.7.7S6
-6.8E6
.S.OE6
.5.1E6
L4.3E6
'.3. 4E6
.2.6ES
11. 7E6
-8.SB5
O.OEO
36:00 37:00 38:00 39:00 40:00
F±letW9B1017 H-S90 Acg:16-AfR-1998 1S:19:38 SC EI+ Voltage SIS 70SE
513.6775 Fs4 Exp:Nl}B5US
TRIANGLE LABS T&ft!H23-I-l . TLI#45399
1003
901
41: 00
42:00
43:00 Tine
35:00
37:00
38:00
39:00
40:00
41:00
O.OEO
431:00 Time
91
-------
Flle-.tfSBlSl? m-59'0 Acq:l6-APR-199B LSi3.S-.3S GC EI+ Voltage SIS 7t)SE NoiaeiSIS
457.7377 F:4 BSUB(2S6, 30, -3.0) PJOJf7,5, 3, 0.101,2064.0,1.00%,!', T) ExpiXDBSUS
TRIANGLE LABS TextsM23-I-l 1X1*45.399
100*
flOJ
SO.
401
20:
41:12 41:18 41:24 41:30 41:36 41:42
File:W981017 #1-590 Acqsl6-APS-1998 16:19:38 GC £1+ Voltage SIS JOSE Noiae:474
459.7348 f:4 BSUB(256,30,-3.0) PXB(7,5,3,0.101,1896.0,1.00\,F,T) ExpsUDBSUS
TSIANSLS LABS Text:M23-I-l- TLI#45399
100* R7.74E4
80.
60.
40.
20.
41:12 41:18 41.-24 41:30 41:36 41:42
Fils:W981017 #1-590 Ac
-------
CD
Peak Locate Examination:16-APR-1998:16:17 File:W981017
Experiment:NDB5US Function:2 Reference:PFK
Volts
0.2251
292.95315 292.98245 293,01175
Volts
0.1959
330.94615 330.97925 331.01235
Volts
0.0473
416;93435 416.97604 417.01774
-------
cr.-
File:W981017 #1-798 Aeq:16-APR-1998 16:19:38 GC EI+ Voltage SIR 70SE
303,9016 F:2 Exp:NDB5US
Sample Text;M23-I-l TLI#45399 File Text:TRIANGLE LABORATORIES, INC,
100% A3.
80 j
60l
40
20 j
0
DBS: :
24:00 25:00 26:00
File:W981017 #1-798 Acq:16-APR-1998 16:19:38 GC EI+ Voltage SIR 70SE
305.8987 F:2 Exp:NDB5US
Sample Text:M23-I-1 TLI#45399 File Text:TRIANGLE LABORATORIES, INC,
100%
80J
40 j
A4.15E4
DBS: :
A5.35E4
24:00 25:00 26:00
File:W981017 #1-798 Acq:16-APR-1998 16:19:38 GC EI+ Voltage SIR 70SE
315.9419 F:2 Exp:NDB5US
Sample Text:M23-I-l TLI#45399 File Text:TRIANGLE LABORATORIES, INC,
100*
80 j
601
40
20J
OJ
DBS: :
26:19
24:00
25:00
26:00
.2.4E4
.1.9E4
.1.5E4
.9.7E3
.4.9E3
.O.OEO
Time
.2.4E4
.1.9E4
.1.4E4
.9.4E3
.4.7E3
.O.OEO
Time
.7.0E5
.5.6E5
.4.2E5
.2.8E5
.1.4E5
.O.OEO
Time
-------
TLI Project: 45399
Client Sample; M23-I-1
Method 23 TCDD/TCDF Analysis (DB-225)
Analysis File: P981306
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
r012.002/Lime Kiln
M23
204-92-1A-D
1.000
n/a
DB-225
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
04/01/98
04/03/98
04/16/98
n/a
U980780
BJG
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPC2NF04
PF24098
P981302
n/a
n/a
n/a
Analytes
Amt (HSJ
1 m.
£MPO
Ratio \
TT Flags
2,3,7,8-TCDF
EMPC
0.007
JB_
13Cn-2,3,7,8-TCDF
3.2
80,4
40%-130%
0.76
22:23
Recovery Standard
Ratk)
BT
Flags
13C12-1,2,3,4-TCDD
0.81
21:17
Data Reviewer
Page 1 of 1
04/20/98
C2NFJPSR v2.0i LARS 6.11.00
Triangle Laboratories, Inc.®
801 Cap'rtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
95
Printed: 21:27 04/20/98
-------
Data Review By:
Initial Date...
VO «V -.a **
V /__/ Calculated Noise Area:
0.14
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page Mo.
04/20/93
Listing of P981306B.dbf
Matched GC Peaks / Ratio / Ret. Time
compound/
M_Z.... QC.Log Omit Why .,RT, OE Ratio Total.Area... Area.Feak.1.. Area.Peak.2. . Rel.RT Compound.Name .. ID.. Flags.
TCDP
304-306
0.65-0.89
DC HL 0:
17:
18:
18:
19:
DC SN 19:
DC SN 19:
19:
DC SN 19:
DC SN 20 :
20:
20:
20:
DC SN 21:
21:
21:
21:
00 RO
50
50 RO
58 RO
OS RO
17 RO
34 RO
43 RO
52 RO
02 RO
11 RO
34 RO
59
05 RO
14 RO
27
52
22:17 RO
22:25 RO
22:39
DC SH 22 :
:57
23:05
DC SN 23:49 RO
304-30S
13C12-TCDF
316-318
316-318
13C12-TCDD
332-334
332-334
1.00
0.66
0.56
0.64
0.52
0.52
0.37
0.59
0.31
0.16
1.33
0.64
0.72
0.63
0.52
0.73
0.78
0.96
0.59
0.87
0.68
0.72
0.50
15 Peaks
DC NL 0
DC WL 20
DC WL 21
22
DC WH 24
0.
:00
:58
:14 RO
:23
-.25
65-0.89
0.89
0.87
0,90
0.76
0.72
1 Peak
DC HL 0
19
21
21
22
0,
:00 RO
:53 RO
-.01
:17
:00
ve
,65-0.89
1.38
0.92
0.80
0.81
0.78
4 Peaks
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
16
53
44
41
80
32
25
80
21
32
32
93
81
11
60
71
71
44
46
56
32
62
14
0.
0.
0,
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
21
19
18
35
35
24
34
34
26
30
31
24
20
26
.26
0.790-1.102
0.32
0.34
0.28
0.67
0.59
0.18
1.32
0.47
0.50
0.41
0.40
0.25
0.34
0.30
0.36
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
000
797
841
847
853
852
874
881
888
895
902
919
937
942
949
958
977
996
001 2378-TCDF AN
012
025
031
064
J
J
J
J
J
J
J
J
J
J
J
J
J
J
10.14
0.955-1.045
0.17
0.86
1.52
255.83
110
.67
145.16
2.60
0.
0.
0.
1.
1.
,000
.937
.949
,000 13C12-2378-TCDF ISO
.091
255.83
TCDF / TCDD
0
0
184
236
1
423
.14
.42
.52
.75
.51
.20
P 11 s
0
82
105
0
.22
.03
.64
.66
0.
0.24
102.49
131.11
0.85
905-1.095
0
0
1
1
1
.000
.946
.000 13C12-2378-TCDD IS1
.013 13C12-1234-TCDD RSI
.047
Triangle Laboratories, Inc.® Analytical Services Division
801 Cap'rtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 » Fax: (919) 544-5491
Printed: 21:27 04/§h§8
-------
Page No. 2 Listing of F981306B.dbf
04/20/98 Matched QC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak. 2. . Rel.RT Compound.Name.. ID.. Flags.
Column Description "Why" Code Description QC Log Desc.
M_2 -Nominal Ion Mass(es) WL-Below Retention Time Window A-Peak Added
..RT. -Retention Time (mm:ss) WH-Above Retention Time Window K-Peak Kept
Rat.1 -Ratio of M/M+2 Ions SN-Below Signal to Noise Level D-Peak Deleted
OK -RO=Ratio Outside Limits
-------
F±Te:pSai306 #1-1(3(35 Aoqt'IS-APX-li&B 16:30iOO EI+ Voltage SIM 70P
303.9016 Exp:DB225
TRIANGLE LASS
1003
95l
sol
asl
801
75l
',
701
'.
65'
~
601
55.
sol
45.
40.
35l
30j
25l
20.
15-
101
51
0.
Text.sM23-I-l !TLI#45393
21. -14
21s 52
i
1 21:27 1
J ,
« N
n /
W
i"
21 00 21
j
•2
39
(H II 11 22.-17 li
:12
FiIe:P9B1306
.,
\J
.
/
\X^r
21; 24 21 s36 21
J 1
I
48
_
1 '
V V %v/u
22:00 22:
#1-1006 Acq:16-APR-199B 16:30.
ft
A
/
J
K
1
\22l
„ / A
S A
V
12' 22:24' 22
u
'
jl
3
22
1
I
22:49
U hkl
vyvv
23
-.57
1
f
1
V
V
1
1 36' 22J48' 2jlo<
:05
2J.-49
A
23-20 l\ I
I 1 1 \ |
\ i! j!n A *AA/\ ll/ 1
W^| yVN/VrVN yyl
.1 . 8JT3
.1.7F3
.1 , 6£3
.1 . 5JJ3
.1 . 4E3
.1 . 3E3
-1.2E3
.1.2E3
.1 . 1£3
_5.8£2
.8.9E2
.8.0E2
"-7.1E2
-.6.2E2
L5 . 3£2
-.4.4E2
13.5E2
"-2.7E2
Ll . BE2
LB.9E1
: 0 . OEO
3 '23:12 iJiii' 2J-36 23 1 4 a' 24 00 Time
00 Eli- Voltage SIR 7 OF
315.9419 EzpiDB225
TRIANGLE LABS TextiM23-I-l TLIH45399
IOCS
95l
901
asl
80l
751
70.
651
sol
55-
sol
451
40l
35l
301
25.
201
151
101
5.
0
21 00 21
__ ^
Tl2 21
•1
r
•f
•i
I24'2ii35-'2i
fc
•48 '22 .-00 22-
2
I
23
^y \
12' 22124' 221: 36' 22:48' 23 .-0
p2.7ES
"-.2.5E5
"-2.4E5
"-2.3ES
'-2 . 1E5
"-2.0E5
11.9E5
Ll . 7E5
Ll . 6E5
Ll . 5J?5
L1.3JS5
L1.2JS5
Ll.1^5
L5.4fT4
L8.0B4
":6.7S4
".
"-5.4E4
'-.4.0E4
'.2.7S4
Ll . 3£4
o' 23.-12' 23:24' 23.-J5' 23:48 ' 24 00 WJBS
-------
?ile:P981306 #1-1006 Acq:16-APR-1998 16:30sOO EI+ Voltage SIM 70P No±ae:46
303.9016 BSUB(25S,30,-3.0) PKD(5, 3,1, 0.10%,184 . 0, 0. 00%,f, F) ExpsDB225
TRIANGLE LABS Tsxt:M23-I-l TLI#45399
IOCS ' • A8.40E3
18:00 19-00 20:00 21100 22:00 23s00
File:P98130S #1-1006 Acq:16-APR-1998 16:30:00 EI+ Voltage SIR 70P No±se:45
305,8987 BSOB(256,30,-3.0) PKD{5,3,1,Q.10%,190.0,0.00*,I', F) Exp:DB225
TRIANGLE LABS Text:M23-I-l TLI&45399
100* A1.32E4
19:00 20.-00 21J 00 22:00 23:00
File:P981306 #1-1006 AcqflS-APR-1998 16:30:00 EH- Voltage SIR 70P No±ses3B
315.9419 BSUB(256,30,-3.0) PKS( 5, 3,1, 0.10%,15.2. 0, 0. 00%, F,F) Exp:DB22S
TRIANGLE LABS Text:M23-I-l TLI#45399
1004 • A1.11E6
801
60J
40:
20;
24: 00
18:00 19:00 20-00 Jl.-OO 22:00 23:00
File:P9813Q6 #1-1006 Acg:16-APR-1998 16:30:00 EI+ Voltage SIR 70P Noise:44
317.9389 BSaB(256,30,-3.0) PKD(5, 3,1, 0.101,176. 0, 0.00%,JP, T) Exp:DB225
TRIANGLE LABS Text:M23-I-l TLI#45399
1004 A1.4SE6
801
60:
40:
20:
24:00
18:00 19:00 , 20:00 21:00 22:00 23:00
File:P981306 il-lOOS Acq:lSrAPX-1998 16:30:00 EI+ Voltage SIR 70P
375.8364 ExpsDB225
TRIANGLE LABS Text:M23-I-l TLI#45399
1004
24 : 00
25:
0.0£0
00 Time
25:
O.OEO
00 Time
2.7E5
"-2.1E5
'-1.6E5
'.1. 1E5
-5.3E4
25:
".O.OEO
00 Time
_3. 6E5
-2.8E5
12.1E5
11. 4E5
L7.1E4
25:00 Time
18:00
19:00
20:00
21:00
22:00
23:00
24:00
25:1
-------
'ile:P$61306 #1-1006 Acqil6-APR-19$8 I$s30:00 XX+ Voltage SIX 70P Jfoise."33
319.8965 BSUB(256,30,-3.0) PKD{5,3,1,0,10%,15S.O,0.00%,F,F) Exp:DB225
TRIANGLE IABS Text:M23-I-l TLI#45399
1004
19s00 20i00 21:00 22:00 23:00
T±le:P981306 #1-1006 Acq:16-APX-1998 16:30:00 EI+ Voltage SIS 70P Noiae:45
321.8936 BSUB(256,30r-3.Q) PXP(5,3,1,0..10%,180. 0, 0, 00%,F,.F) Exp:DB225
TRIANGLE LABS Teit:M23-I-l TLI#4S399
1004 ,
19:00 , 20:00 21s00 22:00 23:00
F±le:P981306 #1-1006 Acq:16rAPR-1998 16:30 sOO EI+ Voltage SIX 70P Noise: 37
327.8847 BSUB(256, 30, -3.0) PKD(S,3,1, 0.101,148.0,0.00*, f,F) £xpiDB225
TSIJUfSZE L&BS I'ezt:M23-I-l TLI#45399
1004 A1.63E6
80.
60:
40.
20:
ISsOO .20:00 21:00 22:00 23:00
F±ls:P981306 #1-1006 Acqsl6-APS-1998 16:30:00 EI+ Voltage SIR 70P Jfoise:57
331.9358 BSUB(256t30,-3.0) PKD(5,3,lr 0,10%, 228.0, 0. 00%,F, F) Exp:DB22S
TRIANGLE LABS Text:M23-I-l TLH45399
100% A1.Q6E6
80.
60.
40.
201
A8.20ES\
19s00 20:00 21:00 22:00 23s00
File:P98130S #1-1006 Acq:16-APR-1998 16s30sOO EI+ Voltage SIM 70P Noise:42
333.9338 BSOB(256,30r-3.0) PKD(5,3,l,0.10%,iSfl.0,0.00%,F,F) SxpiDB225
TRIANGLE IABS Text:M23-I-l TLI#45399
1004 R1.31E6
so:
66'.
401
201
0.
Al . 02E6 [
191 00
20\00
UA,
21100
24 : 00
24:00
~_3.6E5
12. 7E5
11. 8E5
"-9.1E4
24:00
O.OEO
Time
12.2X5
11. 6E5
11. 1E5
.5.5E4
241 00
O.OEO
Tim,
22 loo
i 1 "~
23s 00
-! r i '—i 1 i
24 : 00
12. 7E5
-2.0E5
~1.4E5
O.OEO
-------
File:P981306 #1-1006 Acq:16-APK-1998 16:30:00 EH- Voltage SIR 70P
303.9016 Elp:DB225
TRIANGLE LABS Text :M23-J-1 TLI#45399
100$ 20:34
20:02 ft 20.-5S
1S.-43J1 Hi || 21:52
ISiOO 1S.-00 20:-00 21:00 22iOO 23iOO
File:P981306 #1-1006 Acq:16-APR-1998 16:30:00 EI+ Voltage SIR 70P
315.9419 Elp:DB225 •"
TRIANGLE LABS Text.-M23-T-1'. TLI#45399
22:23
18:00 13:00 20:00 21:00 22:00 2.3:00
File:P981306 #1-1006 Acq:16-APR-1998 16:30:00 EI+ Voltage SIR 70P
319.8965 Exp:DB225
TRIANGLE LABS Text:M23-I-l TLI#45399
24: 00
80J
60J
401
201
25:00 Time
2. 7E5
.2.1E5
_1. 6E5
_1. 1E5
_5.4E4
O.OEO
24:00
25:00 Time
18:00 13:00 ; 20:00 21:00 22:00
File:P981306 #1-1006 Acq: 16-APR-1998 16:30:00 EI+ Voltage SIR 70P
331.9368 Exp:DB225
TRIANGLE LABS Text:M23-I-l TLI#45399
1003
80J
60J
40J
23:00
24:00
OJ
25:00 Time
2.7E5
I2.2r5
Ll. 6E5
Ll. 1E5
i.5. 5E4
O.OEO
18:00 19:00 20:00 21:00 22:00 23:00
File:P981306 #1-1006 Acq: 16-APR-1998 16:30:00 EI+ Voltage SIR 70P
292.9825 Exp:DB225
TRIANGLE LABS Text:M23-I-l TLI#45399
1003, ,„.,„ 1S:25 19:58 20:26 _ 21x-24 ^21 :56 22.-2S
24:00
25:00 Time
50
40J
20J
ol
18:20
24:38
4.1E5
.3.3E5
.2.4E5
.1. 6E5
•-8.1E4
O.OEO
18:00 1S.-00 20:00 21:00 22:00
File:P981306 #1-1006 Acq:16-APR-1998 16:30:00 EI+ Voltage SIR 70P
330.9792 Ezp:DB225
TRIANGLE LABS Text:M23-I-1 TLH45399
23: 00
24: 00
25: 00 Time
' 79.55 21:21 22:02 22:48 23:22 24:08 24:44
^^^^^
60
40J
20J
OJ
4.4E5
:3. 5E5
.2.7E5
.1. 8E5
-8.8E4
O.OEO
18:00
19:00
20:00
21: 00
22:00
23: 00
24:00
25:00 Time
-------
feF, lass 292,9825 Peak top
,86vdts Span 288ppi
Systtt file nan
Data file naie
Resolution
Mzatlon iode
Ref, lasses 292,3825,
R
1.9816
D 315,9419
E
F
321,8336
H 327,8847
338,9792
J
K
L
fl
1
II*
VOLTfiGE
388,3761
333,9338
£5,8364
Channel
Height
I 338,9792 Peak top
,86 volts fyan 288 ppi
-------
Services
TLI Project:
Client Sample:
45399
M23-I-2
Method 23 PCDD/PCDF Analysis (a)
Analysis File: W981018
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
r012.002/Lime Kiln
M23
204-92-2A-D
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
04/01/98
04/03/98
04/16/98
n/a
U980780
KAS
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPMIT204
WF53178
W981012
n/a
n/a
n/a
Analytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
Totafc
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Arat (og)
ND
ND
ND
ND
ND
ND
EMPC
1.5
0.21
0.21
0.10
EMPC
ND
ND
EMPC
ND
ND
Arot (ng)
0.25
EMPC
0.07
ND
12.1
2.7
0.33
EMPC
PL
0.04
0.07
0.09
0.08
0.08
0.1
0.06
0.07
0.1
0.1
Number PL
2
1
0.1
14
11
3
EMPC
0.29
0.05
0.05
€ltflPC
0.51
0.11
3.0
0.37
0.05
Ratio RT Rags
—
0.75 26:22
1.55 30:11
1.60 30:51
1.15 33:34 J_
J_
J_
Flags
—
Page 1 of 2
MTT2_PSR vl.04, LARS 6.11.00
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:40
-------
TLI Project: 45399
Client Sample: M23-I-2
Method 23 PCDD/PCDF Analysis (a)
Analysis File: W981018
Internal Standards
13C,2-2,3,7,8-TCDF
13C,2-2,3,7,8-TeDD
I3Ci2-l,2,3,7,8-PeCDF
13Ci2-l,2,3,7,8-PeCDD
13Ci2-l,2,3,6,7,8-HxCDF
l3Ct2-l,2,3,6J,8-HxCDD
l3C,2-l,2,3,4,6,7,8-HpCDF
13C,2-l,2,3,4,6,7,8-HpCDD
13C12-1,2,3,4,6,7,8,9-OCDD
Arot, {ng}
2.9
3.0
2.6
2.7
3.5
3.7
4.0
4.3
7.6
% Recovery
73.1
74.0
64.9
68.3
87.9
93.0
100.0
107
95.4
QC Limits
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
Ratio
0.77
0.82
1.46
1.55
0.50
1.24
0.45
1.03
0.91
RT
26:19
27:01
30:10
31:10
33:40
34:20
36:35
37:38
41:20
Flags
—
—
liiiiiiiM^iiali^KlpiWiiiiMii
*:wx*x rf:**^>:->:^
13C12-2,3,4,7,8-PeCDF
13Ci2-l,2,3,4,7,8-HxCDF
13C,2-l,2,3,4,7,8-HxCDD
"Cu-l&lAl^-HpCDF
3.6
3.2
3.0
3.4
88.8
81.0
75,6
85.1
40%-130%
40%-130%
40%-130%
25%-130%
1.49
0.50
1.20
0.47
30:50
33:34
34:16
38:09
37Clt-2,3,7,8-TCDD
3.4
84.7
40%-130%
27:02
I3Cu-l,23,7,8,9-HxCDF
13C,2-2,3,4,6,7,8-HxCDF
3.6
3.1
90.3
78.2
40%-130%
40%-130%
0.50
0.51
34:56
34:09
13e,2-l,2,3,4-TCDD
13C,2-l,2,3,7,8,9-HxCDD
0.83
1.21
26:51
34:39
Data Reviewer
04/20/98
Page 2 of2
MTT2J»SR vl.04. LARS 6.11.00
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed
:13:40(J/fi)/98
-------
Initial
....Date..
Data Review By;
Calculated Noise Area: 2.89
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
04/20/98
Listing of W981018B.dbf
Matched GC Peaks / Ratio / Ret, Time
Compound/
M_Z.... QC.Log Oinit Why ..RT. OK Ratio Total,Area... Area.Peak. 1. . Area. Peak. 2.. Rel.RT Compound. Name. . ID.
Flags.
TCDF
304-306
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
D
D
DC NL 0 :
23:
23:
24:
24:
24:
25:
25:
25:
25:
26:
26:
26:
26:
27:
0.
00 RO
16
46
00
22
38
04
20
38
56
10
22
45
58
13
65-0.89
1.
0.
54
73
0.69
0.72
0.73
0.74
0.
,72
0.76
0,
.76
0.81
0
.73
0.75
0.72
0
0
14 Peaks
IX NL 0:
DC WL 23:
DC ML 24:
DC WL 24:
DC WL 25;
26;
DC SN 26;
DC WH 27;
0.
00
;57
:22 RO
;37
:18 RO
•.19
:44 RO
:36
.70
.72
2
3.
151.
80.
56.
541.
330.
281.
263.
316.
171.
120.
361 .
147.
72.
15.
,911.
26
09
46
38
91
80
82
46
83
61
49
02
54
73
19
.33
63.
32.
23.
228.
140.
118.
113.
136.
76.
50.
154.
61.
30,
6.
75
98
69
97
55
13
70
57
76
92
.46
,68
.01
,38
87.
47.
32.
312.
190.
163,
149.
180.
94.
69.
206.
85.
42.
8.
65-0.89
0
0
1
0
0
0
1
o
.89
.80
.28
.77
.55
.77
.22
.87
1 Peak
DC NL 0
24
24
DC SB 25
DC SN 25.
25
D SN 26
DC SN 26
DC SN 26
26
D SN 27
DC SN 27
0,
:00 RO
:34 RO
:56
:03 RO
!l5
:52
:08 RO
.-31 RO
:48 RO
:56 RO
:02
:11 RO
,65
1
0
0
1
0
0
0
" 0
0
1
0
1
-0.89
.24
.93
.88
.33
.89
.75
.93
.48
.32
.49
.88
.52
2.
3
1.
3,
6.
799,
5,
2,
799
,72
,33
,95
.03
.57
.72
,20
.84
.72
347.
.96
451,
0.878-1.072
34
48
69
94
25
69
76
26
85
57
56
86
72
81
0.000
0.884
0.903
0.912
0.926
0.936
0,953
0.963
0.974
0.985
0.994
1.002 2373-TCDF AN
1,016
1.025
1.034
0.962-1.038
.76
0.000
0.910
0.926
0.935
0.961
1.000 13C12-2378-TCDF ISO
1.016
1.049
1
30
18
1
3
28
14
4
2
10
7
-2
.77
.92
.31
.35
,67
.95
.04
.32
.37
.87
,74
.53
16
8
12
9
.29
.57
.44
.17
17
9
16
6
0.
,47
.74
.51
.14
903-1.042
0.000
0,909
0.923
0,927
0.935
0,957
0.967
0.981
0.992
0.997
1.001 2378-TCDD AN
1.006
Triangle Laboratories, Inc.® Analytical Services Division
801 Capttola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax; (919) 544-5491
Printed: 13:40
04/21/98
-------
Page Ho.
04/20/98
Listing of W981Q18B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.,.. QC.Log Omit Why ..RT. OK Ratio Total.Area.., Area.Peak.1., Area.Peak.2. . Rel.RT Compound.Name,. ID.
Flags.
320-322
37C1-TCDD
328
DC '
DC
27:22 RO 0.90
SN 27:59 0.74
SN 28:06 EO 1.50
5 Peaks
8.28
3.59
1.13
97.33
4.22 4.68 1.
1.
1.
013
036
040
0.926-1.074
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
ML
WL
WL
Wt,
WL
WL
WL
WL
WL
SN
SN
SH
SN
SN
SH
SH
SN
SN
SN
SN
SN
0:
24:
24:
24:
24:
24:
24:
24:
24:
25:
25:
25:
25:
25:
25:
25:
00
20
26
38
38
46
52
56
58
05
17
18
25
25
32
42
25:51
26:01
26:02
26:19
26:24
26:31
26:50
27:02
27:25
328
13C12-TCDD
332-334
332-334
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SH
SH
4
NL
SH
SN
SH
3
27:47
27
28
28
:55
:09
:25
Peaks
0
26
27
27
27
28
28
0.65-0.89
:00 RO 1.67
:51 0.83
:01 0.82
:20 RO 1.21
:49 RO 1.54
:10 RO 6.84
:16 RO 3.34
Peaks
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
15.
08
87
59
88
66
74
34
50
94
79
59
64
58
91
36
73
1.19
0.49
0.32
0,
0,
.52
,61
1.09
3.70
529
11
1
3
0
1
560
.61
.92
.01
.02
.45
.60
.96
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
15.73 0.
0.
0.
0.
0.
0.
0.
3.70 0,
529.61 1,
000
901
904
912
912
917
920
923
924
928
936
936
941
941
945
951
957
963
964
974
977
,981
,993
,001 37C1-TCDD CLS
11.92 1.015
1.028
1.
1
1
.033
.042
.052
0.926-1.074
2
787
609
10
2
0
1
1,406
.87
.29
.11
.46
.51
.90
.65
.86
uv1".«**m . trt*Tvr\ / D*I/™
PeCDF
340-342
DC
DC
NL
SN
1.32-1.78
0:00 RO 0.95
28:06 RO 0.98
JW i A \~LJLJ I t c:v-
1
1
.79
.73
0
356.19 431.10 0
274.01 335.10 1
7.14 5.91 1
1
1
1
•
.000
.994 13C12-1234-TCDD RSI
.000 13C12-2378-TCDD IS1
.012
.030
.043
.046 .
"
0.930-1.060
0
0
.000
.931
Triangle Laboratories, Inc.® Analytical Services Division
801 Capttola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:4004/2
-------
Page No.
04/20/98
Listing of W981018B,db£
Matched GC Peaks / Ratio / Ret.
Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total,Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.
ID.. Flags.
A
M
340-342
13C12-PeCDF
352-354
352-354
FeCDD
356-358
356-358
13C12-PeCDD
368-370
368-370
DC
DC
DC
DC
"DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
EC
DC
DC
DC
DC
13
NL
SN
SN
SN
SN
SN
SN
2
NL
SN
SN
SN
SM
SN
1
NL
SN
SN
SN
SN
SN
2
28:14
29:12
29:20
29;30
29:44
29:48
29:55
30:06
30:11 '
30:20
30:27
30:51
30:59
Peaks
0:
28:
28:
28:
28:
30:
30:
30:
30:
00
19
37
49
59
10
25
36
50
RO
RO
1,
RO
RO
RO
RO
RO
RO
RO
1.
1.
1.
1.
1.
1.
1.
1.
1.
1,
1.
1,
2.
47
41
58
.31
35
59
,40
,56
•55
,33
,61
,60
,13
50.
29.
124.
25.
12.
17.
23.
10.
29.
19.
29.
29.
16.
419.
80 30.22
77 17.40
46 76.15
85 15.71
32 7 . 07
62 10.83
33 13.61
68 6.51
60 18.00
46 11.11
56 18.25
33 18.05
78 14.02
56
32-1.78
0.
0.
2
0,
1.
1,
0
1
1
Peaks
0:
29:
29i
30i
30;
30;
31
;00
;27
;42
:08
:16
:27
:01
1.
RO
RO
RO
RO
RO
RO
32-
1
1
0
0
2
1
5
.90
.60
.23
.89
.86
.46
.98
.21
.49
-1.78
.17
.15
.76
.96
.52
.71
.13
Peak
0
30
31
31
31
31
31
32
:00
:16
:10
:18
:28
:34
:57
:03
1,
RO
RO
RO
RO
,32
1
0
1
1
0
1
0
1
Peaks
-1.78
.58
.65
.55
.70
.83
.93
.95
.52
1.
1.
3.
0.
2.
535.
4.
1.
457.
56
53
06
39
17
25 317.49
61
60
87 274.15
20.58 0
12.37 0
48.31 0
12.00 0
5.25 0
6.79 0
9.72 0
4.17 0
11.60 1
8.35 1
11,31 1
11.28 1
6,58 1
.936
.968
.972
.978
.986
.988
.992
.998
.001 12378-PeCDF AN
.006
.009
.023 23478-PeCDF AH
.027
0.867-1.133
0
0
0
0
0
217.76 1
1
1
183.72 1
.000
.939
.949
.955
.961
.000 13C12-PeCDF 123 IS2
.008
.014
.022 13C12-PeCDF 234 SUR1
993.12
PsCDF / P©CDO follows
i.
11.
i.
5,
2,
6,
0
11
2
1
311
38
2
2
1
3
349
*>e»rn'
,99
,37 6.91
.07
.00
.55
.88
.79
.37
.04
.37
.17 189.04
.07 23.96
.45
.35
.35
.18
.24
n / HWnF Pntlnuio
0.939
0
6.02 0
0
0
0
0
0
0.872
0
0
122.13 1
14.11 1
1
1
1
1
-1.020
.000
.945
.953
.967
.971
.977
.995
-1.128
.000
.971
.000 13C12-PeCDD 123 IS3
.004
,010
.013
.025
.028
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:40 04/2
-------
Page Ho.
04/20/98
Listing of W981018B.dbC
Matched GC Peaks / Ratio / Ret. Time
Cornpouiad/
M_2,... QC.Log Omit Why ..RT. OK Ratio Total.Area.,
. Area.Peak.1.. toea.Peak.2,. Rel.RT Compound.Name.. ID.. Flags.
HxCDF
374-376
K
K
374-376
13C12-HXCDF
384-385
384-386
HxCDD
390-392
K
390-392
13C 12 -HxCDD
402-404
402-404
DC NL 0:
32:
32:
DC SN 32;
DC SN 33:
33:
33:
DC SN 33:
DC SN 33:
DC SN 34 :
DC WH 35:
00
37
46
56
03
.34
40
47
57
09
21
1.
RO
RO
RO
RO
RO
05-1.43
1.
1.
1.
1
1.
1.
,41
.33
.08
.02
.23
.15
0.86
0
1
1
1
.35
.50
.40
.74
4 Peaks
DC NL 0:
DC SN 32 :
33:
33:
34:
34:
DC SN 35:
00
44
34
40
09
:56
:09
0,
RO
RO
RO
2.
6.
21.
2.
3.
12.
6.
0.
2.
4.
2.
47.
39
60 3.77
28 11.06
93
14
67 6.77
49 3.59
69
82
41
42
04
43-0.59
0
0
0
0
0
0
0
4 Peaks
DC NL 0
33:
DC SN 34
DC WH 34
DC WH 34
DC WH 35
:00
:32
:39
:51
-.56
:03
1.
RO
RO
RO
RO
.05
0
1
5
1
0
0
.85
.79
.50
.50
.51
.50
.38
-1.43
.85
.08
.23
.05
.67
.94
1 Peak
DC NL 0
34
34
34
DC SN 34
DC SN 34
:00
:16
:20
:39
-.52
:57
1
RO
RO
2.
3.
359.
430.
363.
317.
3.
67
61
29 119.97
85 144.02
76 122.43
95 106.34
55
0.964-1.045
0,
2.83 0
10.22 0
0
0
5.90 0
4.16 1
1
1
1
1
.000
.969
.973
.978
,982
.997 123478-HxCDF MJ
.000 123678-HxCDF AM
.003
.008
.014 234678-HXCDF KS
.050
a
j
j
0.881-1,119
0
0
239.32 0
286.83 1
241.33 1
211.61 1
1
.000
.972
.997 13C12-HXCDF 478 SDR2
.000 13C12-HXCDF 678 IS4
.014 13C12-HXCDF 234 ALT2
.038 13C12-HXCDF 789 ALT1
.044
1,471.85
• WvfTW / HvPnn TPr-il 1 /-*T»F«I
2.
5.
0.
0.
0.
0.
5 _
,11
92 3.07
87
,82
.92
.61
,92
.05-1.43
1
1
1
1
0
0
.15
.20
.24
.21
.29
.59
3 Peaks
- .- *__ Ahoxm
2.49
243.57 132.81
346.26 191,90
381,
,59 208.61
1.32
2
971
: Hvnm
.85
.42
D / HnfDP Follows ---
0.958-1.013
0
2.85 0
1
1
1
1
0.971
0
110.76 0
154.36 1
172.98 1
1
1
.000
.977
.009 123789 -HxCDD AN.
.015
.017
.021
-1.029
.000
.998 13C12-HXCDD 478 SOR3
.000 13C12 -HxCDD 678 IS5
.009 13C12-HXCDD 789 RS2
.016
.018
j
HpCDF
408-410
408-410
0.88-1.20
DC NL 0:00 RO 1.30
36:36 RO 1.30
DC SN 37:02 RO 0.71
1 Peak
1.92
5.63
1.61
5.63
3.58
0.996-1.048
0.000
2.76 1.000 1234678-HpCDF
1.012
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capttola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:40 04/2
-------
Page No.
04/20/98
Listing of W981018B,dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z,... QC.Log Omit Why .,RT. OK Ratio Total.Area... Area.Peak.1. . Area.Peak.2.. Rel.RT Compound.Name.. ID,. Flags.
13C12-HpCDF
418-420
418-420
HpCDD
424-426
424-426
13012-HpCDD
436-438
436-438
OCDF
442-444
442-444
OCDD
453-460
458-460
13C12-OCDD
470-472
470-472
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
2
NL
SN
SN
SN
SN
WH
0
NL
SN
SN
SN
WH
1
NL
SN
SN
SN
SN
0
NL
1
NL
WH
1
0:00
36:35
38:09
Peaks
0:00
36:53
37:13
37:34
37:39
38:52
Peaks
0:00
37:25
37:38
37:57
38:00
39:38
Peak
0:00
37:50
41:19
41:26
41:33
Peaks
0:00
41:19
Peak
0:00
41:20
41:42
Peak
0.
RO
0.
RO
RO
RO
RO
0.
RO
RO
RO
0.
RO
RO
RO
0.
RO
0
RO
RO
37-0.51
1.
0.
0.
88-
0.
1.
10.
0.
0.
0.
38-
1.
1.
1.
0.
0.
2.
12
45
47
1.20
99
64
74
33
93
70
1.20
15
10
03
41
67
19
,76-1.02
0.
0.
0.
1.
1.
90
70
92
22
52
1.
284.
177.
462.
74
92 88.09
28 56.99
20
0.945-1.109
0
196.83 1
120.29 1
.000
.000 13C12-HpCDF 678
.043 13C12-HpCDF 789
IS6
SUR4
2.
2.
0.
0.
2.
1.
0.
2.
1.
268.
0.
1.
1.
268.
19
73
39
82
95
47
00
34
03
06 136.33
98
51
06
06
• H0CDD / Octet— CDD and CDF
2.
1.
3.
1.
3.
0.
26
64
48
40
14
00
.76-1.02
0.
0,
98
,56
1.
12.
12,
,84
.66 5.96
,66
.76-1.02
1.
0,
0,
.24
,91
.16
1.
299,
,47
,27 142.28
0.66
0.976
0
0
0
0
1
1
0.973
0
0
131.73 1
1
1
1
0.903
0
0
1
1
1
0.903
0
10.59 1
0.996
0
156.99 1
1
-1.004
.000
.980
.989
,998
.000 123467 8-HpCDD
.033
-1.027
.000
,994
.000 13C12-HpCDD 678
.008
.010
.053
-1.097
.000
.915
,000
.002
.005 OCDF
-1.097
,000
,000 OCDD
-1.004
.000
.000 13C12-OCDD
.009
AN
IS7
AN
AN
IS8
299.27
Triangle Laboratories, inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:4004/2i
f§9
-------
Page Ho. 6 Listing of W981018B,dbf
04/20/98 Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es) WL-Below Retention Time Window A-Peak Added
. .RT. -Retention Time (mtiuss) WH-Above Retention Time Window K-Peak Kept
Rat.l -Ratio of M/M+2 Ions SH-Below Signal to Noise Level D-Peak Deleted
OK -RO=Ratio Outside Limits
-------
File:ff981018 #1-798 Acq:16-APR-1998 17:16:52 GC EI+ Voltage SIR 70SE Noise:1417
303.9016 F:2 BSUB(256, 30, -3.0) PKD(9, 5,5, 0 .10%, 5558. 0,1 . 00%, F, T) Eip:NDB5US
TRIANGLE LABS Text:M23-I-2 TLI#45399
1004
80J
40J
20J
0
A2.
AA3.30E5
AA /
24 .-OO'
>9E6
Al.
A1.14E6
A1.41E6 A1.18E6l\ A7.68E5
L / 1 A/1 l\ A1'jiJE6 A
'25.-00' ' ' ' 26i-0o'
4.4£5
54E6
A
1 A6.17E5
\ /i
'27.'oo 2al-oo'
-_2.7E5
-1 . 8E5
'•L8.9E4
'-O.OEO
Time
File:W981018 #1-798 Acq:16-APR-1998 17:16:52 GC EI+ Voltage SIR 70SE Noise:918
305.8987 F:2 BSUB(256, 30, -3 .0) PKD(9,5, 5, 0 .10%, 3672. 0,1 . 00%,F, T) Exp:NDB5US
TSIANGLE LABS Text:M23-I-2 TLI#45399
1004
80J
601
401
20-
o'
A3.
A A4 . 75E5
A A A /
24:00
13E6
\
'
A1.50E6
\A1.90X6A1.64E6h A9.49E5
\l\ Al\y\!(j\]
25:00 ' 26\0o'
6.1£5
07E6
\
A8.59E5
I /\A. „
27:00 ' ' ' '28-00'
-4.9E5
-3 . 7E5
_2.4E5
.1.2E5
O.OEO
Time
File:W981018 #1-798 Acq:16-APR-1998 17:16:52 GC EI+ Voltage SIR 70SE Noise:639
315.9419 F:2 BSUB(256, 30, -3.0) PKD(9,5, 5, 0 .10%, 2555. 0,1 . 00%,F, T) Eip:NDB5US
TRIANGLE LABS Tart -.M23-I-2 TLI#45399
100%
80J
60J
401
20J
o:
241-00'
Al..
'
1
251-00 26:00
1E6 9 . 8E5
27:00 281-00
L7.8E5
"--5 . 9E5
'-3 . 9E5
-2.0E5
• o . OEO
Time
File:W981018 #1-798 Acq: 16 -APR- 19 9 8 17:16:52 GC EI+ Voltage SIS 70SE Noise: 722
317.9389 F:2 BSUB( 256, 30, -3.0 ) PKD(9, 5,5, 0 .10%,2888 . 0, 1 . 00%,F, T) Eip:NDB5US
TRIANGLE LABS Teit:M23-I-2 TLI#45399
1003,
60-
601
40.
201
o'
241-00'
A4
:,-.
|
25:00 26:00
>2£6
L
'271-00 28: OO'
1.2E6
.9 . 7E5
.7.3E5
-4.9E5
-2.4E5
O.OEO
Time
File:ff981018 #1-798 Acq:16-APR-1998 17:16:52 GC EI+ Voltage SIS 70SE
330.9792 F:2 Exp:NDB5US
TRIANGLE LABS Teit:M23-I-2 TLI#45399
1003
80J
601
40~-
201
o-
u_^^~^^~-54*45-—
'24.-00'
_24/t2.9__24J^55i25:^14^_^25Jj44_26:06
'25l- 00 26.' OO'
26:4027:00 27:35 27:5728:16
fr~f~~ — *~w~C^-~ ^^w — \/~r~ *^ ' ~V*-**AS~~
"
'27-00 28- OO'
1.9E7
-.1.5E7
.1.1E7
-7.4E6
.3 . 7E6
O.OEO
Time
File:ff981018 #1-798 Acq:16-APS-199S 17:16:52 GC EI+ Voltage SIR 70SE
375.8364 F:2 Eip:NDB5US
TRIANGLE LABS Teit:M23-I-2 TLI#45399
1001
aol
401
201
o'
1 23:41 24
24:°°'
28:02 1.4E4
-18 1 to.** 27 31 27:4g I I
• 24:36\ 25[10 I 25:5B 26:25 A 27:18 ll ft I ft
A H /\ in hi in i A! lS^J J?^ i/l HA lA /^uA/tafl^^AArAn JL i Ai tiL f\ AIL A Jl 11 A
IJ \M^\T**J(J\J\J^ vl/V^UU
T*
.J t
' ' ' ' '25^00' ' ' ' '26l-0fl'
j, ^v,, «,-„ -,.^ -^vn/vrui/'y w'y" v vUk/W
27:00 28:00
-1.1E4
-8.2E3
-5 . 5E3
-2.7E3
O.OEO
Time
-------
F±le:tfSai018 #1-798 Aog:16-APS-199a 17:16:52 SC EI+ Voltage SIS 70SE Noise:622
19.8965 F.-2 BSUB(25S,30,-3 .0) PKD(7, 5,3, 0 .10%,2488 .0,1 .QO%,F,T) ExpiUDBSOS
TSIAKGZ.E LABS TeItiM23~I-2 TLI04S399 . ._ , _ ry
1001A1.63X5 "* /,T - " 0
25:00 26:00 27:00
File:W981018 #1-798 Acqsl6-APR-1998 17:16:52 GC EI+ Voltage SIR 70SE Noise:502
321.8936 F:2 BSUB(256, 30, -3.0) PXD(7,5,3,0.101,3008.0,1.001,r,T) ExpiNDBSOS
TRIANGLE LABS Text:M23-I-2 TLI#45399
1003iA1.75E5
25': 00 26:00 27:00
File:ff981018 #1-798 Acq:16-APR-1998 17:16:52 GC EI+ Voltage SIR 70SE Noise:1356
331.9368 F:2 BSUB(256, 30, -3. 0) PKD( 7, 5,3, 0 .10%, 5424 . 0,1. 001,F, T) Exp:KDS5US
TRIANGLE LABS Text:tt23-I-2. TLI#45399
A3. S6E6
A
.2, 74£6
40J
28 ,-00
28.- 00
od
25.-OQ 26:00 27:00
File:W981018 #1-798 Acq:16-APR-1998 17:16:52 GC EI+ Voltage SIR 70SE
333.9338 Fs2 BSOB(256,30, -3.0) PKD(7,5,3, 0.10%, 3236. 0,1. 001, F, T) Exp:
TRIANGLE LABS Text:M23-I-2, TLH45399
IDOJj ' A4.31S6
A
28:00
Noise:809
KDB5US
80-
601
401
R3.35E6
25:00 26:00 27:00
Filestf981018 #1-798 Acq:16-APR-199B 17:16:52 GC EI+ Voltage SIR 70SE
327.8847 F:2 BSUBf 256, 30, -3 . 0) PKD(7, 5,3, 0.101,2168. 0,1. 00\,F,T) Exp:
TRIANGLE LABS Text.itQ3-T-3. TLH45399
1004 - '- A5.30E6
801
6ol
401
28:00
Noiae:542
NDB5OS
20;
ol
-f^.
25:00 26:00 27:00
Fileitf981018 #1-798 Acq:16-APS-1998 17:16:52 SC EI+ Voltage SIS 70SE
330.9792 F:2 Eip:NDB5OS
TRIANGLE LABS Teit:M23-I-2 TLH45399
23:00
801
601
401
201
ol
25 1 00
26-00
27:00
28:00
9.9E5
.7.9E5
.5.9E5
O.OEO
Time
.1. 3E6
.7.5E5
.5.0E5
.2.5E5
. 0.OEO
Time
.1.5E6
.1.2E6
.9. OE5
.6.0E5
.3, OE5
O.OEO
Tim
1.5E7
.1.1E7
.7.4E6
.3. 7ES
.O.OEO
Time
lit
-------
File :W9 81 01 8 #1-798 Acq: 16-APR-199B 17:16:52 GC EI+
339.8597 F:2 BSUB(256, 30, -3 .0 ) PKD(7, 5, 3, 0 .101,2180
Voltage SIR 70SE Noise -.545
0,1.001,F,T) Eip:NDB5VS
TRIANGLE LABS Text:M23-I-2 TLI#45399
1002
801
601
401
201
0
A7.6
ft
A3 . 02E5
A
A -'i
JL : jv
29\00
1E5
1 . 8E5
, ,,„ A2.50E5 A1.81E5
J-r - r^i-HES A
WJ^A/V /V/IA/V Ayv _^ ^
3ol-00
File:W981018 #1-798 Acq:16-APR-1998 17:16:52 GC EI+
341.8567 F:2 BSUB(256, 30, -3 . 0 ) PKD(7, 5,3, 0.10%, 2292
'-1.4E5
Ll . 1E5
-7.2E4
-3 . 6E4
' 0 . OEO
31:00 ' ' ' ' 32l:00 ' Time
Voltage SIR 70SE Noise:573
.0,1.00*,F,T) Exp:NDB5US
TRIANGLE LABS Text:M23-I-2 TLI#45399
1003,
aoi
601
401
201
A4 . 6
.
A2.06E5
1
A. \ A1.74E5 A1.13E5
A
JY
29:00
1 A A9-72E4 1
\J V_^A-/\/\/V
30:00
File:W981018 #1-798 Acq: 16-APR-1998 17:16:52 GC EI+
351.9000 F-.2 BSUB(256,30,-3.0) PKD( 7, 5, 3, 0 .10%, 1S04
\ A1.13E5
I A Al /
v/\^ __ __ .
.1 . 3E5
_1 . 1E5
-8.0E4
-5.3E4
.2 . 7E4
O.OEO
31 .-00 32: 00 Time
Voltage SIR 70SE Noise: 476
. 0,1.00%,F, T) Exp:NDB5US
TRIANGLE LABS Text : M23-I-2 TLI#45399
1003,
•
801
601
401
201
0
2S.-00
A3.
30 1-00
File:W981018 #1-798 Acq: 16-APR-1998 17:16:52 GC EI+
353.8970 F:2 BSUB(256, 30, -3 . 0) PKD( 7, 5,3, 0 . 10%, 2092
7E6
_S . 6E5
A2 . 74E6
V 1
I
_ 7 . 7E5
.5.8E5
_3 . 8E5
_1 . 9E5
O.OEO
3li-00 321-00 ' Time
Voltage SIR 70SE Noise: 523
.0,1.00*,F,T) Exp:NDB5US
TRIANGLE LABS Text:M23-I-2 TLI#45399
1003
-
aol
eoi
401
201
o-
: '
29-00
A2.18E6 ^6.8E5
1
30:00
File:W98101^ #1-798 Acq:16-APR-1998 17:16:52 GC EI+
330.9792 F-.2 Eip:NDB5VS
A1.84E6
V^ y
L
.5.4E5
-4.1E5
.2.7E5
.1 . 4E5
O.OEO
31 .-00 321-00 ' Time
Voltage SIR 70SE
TRIANGLE LABS Text .-M23-J-2 TLI#45399
1003
80.
60.
40.
20.
0
25 1-00
•20 29-39
*~~ — ^ — ^ — ^£AX£-
30. -00
•*s3^2£—^___^_^
1 . 7E7
lPj^6__3i:JL4__ 31:35 ^^~~* —
_1 . 4E7
.1 . OE7
.6.9E6
.3.4E6
O.OEO
31 .-00 321-00 ' Time
File:W981018 #1-798 Acq:16-APR-1998 17:16:52 GC EI+ Voltage SIR 70SE
409.7974 F:2 Exp:NDB5US
TRIANGLE LABS Text:M23-I-2 TLI#45399
1003
80.
60.
40.
20.
0
".
I 29:05
I 28:23 1 fl i 1\
•JL AA/\MlA J\AA M /NA/V A/1 thj(
'^V ^/VVV\//V'^/U|VV vVXJV [fsfl^j
29:00
| 29:52 h
m fv n/\. A/A.AAyLy
\J'^WvVwU V/VV V
3ol-00
I
H .1 A 1 30:
^WMJUMA
V " v^jfj^^«v
31 .-54
I
AO 31:08 31.-4fiS
49. i 11 ,yt ill l(
A^\ArV/UL/vV\ArVvA/KA\Vvl U A MA*
'M^/v v ^/^Aw ^•\/v^/v * A./'y l/ij'\/ v-0
1.2E4
.9 . 8E3
17.3E3
.4 . 9E3
•-2.4E3
0 . OEO
31 1-00 ' ' ' 32:00 ' Time
113
-------
TRIANGLE
100* AS
801
i 29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00
'He:if981018 #1-798 Acq:16-APS-1998 17:16:52 GC EI+ Voltage SIS JOSE No±se:514
357.8516 Fi2 BSUB(25Sr30,-3 .0) PXD(7, 5,3, 0.101,2056. 0,1. 00%, f, T) Sxp:W>B5VS
TRIANGLE LABS Text:M23-I-2, 0X1*45399
A6.02E4 ' r_1.7B4
"d.le:tf98l01S #1-798 Acqsl-6-ApR-lSS'S T7"s'16s52'GC SI+ Voltage SIS 70SE Na±se:665
55.8546 F:2 BSUB(256,30f-3.0) PKDf 7, St 3, 0.101,2420, 0,1. 00%,F, T) ExpiSDBSVS
TIXANGLE LABS Text:M23-I-2 TLH45333
2 . 2E4
'.1 . 8E4
A2.01E4
A1.82S4 A1_59E4
29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00
O.OEO
File:K981018 #1-738 Acg:16-APR-1998 17:16:52 GC EI+ Voltage SIS 70SE No±ae:627
367.8949 F:2 BSUB(256,30,-3 .0) PKD(7,5,3, 0.10*,2508. 0,1. 00%,F, T) Exp:Nl)B5aS
TRIANGLE LABS TeXt:M23-I-2 TLI&45399
1004 A1.89E6
so:
401
201
Time
^6.OSS
L4.SZ5
-3.6E5
.2. 4E5
-1.2S5
2.40E5
O.OEO
29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00 Time
File:W981018 §1-798 Acqil6-APS-1998 17:16:52 GC EI+ Voltage SIR 70SE Noise:397
369.8919 F:2 BSUB(256, 30, -3 '. 0) PKDf 7, 5,3, 0 .101,1508. 0,1. 00%,F, T) Eip:NDB5VS
TRIANGLE IABS Text:M23-I-2 TLH45399
1003* A1.22E6 _3.AE5
801
601
401
20,
0.
'.3. 1E5
12.3S5
'.1. 6E5
17.8E4
.O.OEO
23:24 29:36 29:48 30^00 30:12 30-24 301-35 30:48 3l'sOO 31:12 31:24 31:36 31:48 32-Oo' ' Tim.
File:W9810ia #1-798 Acq:16-APS-1998 17:16:52 GC EI+ Voltage SIS 70SE
330.9792 fi2 Exp:lO}B5US
TSIAWSZE LABS Text:M23-I-2 TLI94S399
100*
SOI
601
40.
20.
0.
29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 31tOo' 31 -12' 311-24' 31:36' 31:48'
^1.6E7
-1.3E7
19. 8E6
.6.SE6
_3. 3E6
O.OEO
Time
1M
-------
'ile:WS81018 #1-355 Acqi 16-APR-199S 17:16:52 GC EI+ Voltage SIX 70SE Noise:7QO
373.820B W:3 BSUB(256,30,-3:.0) PKD(7,5,3r 0.10%,2800.0,1. 00%,FrT) SxpsSDBSUS
TRIANGLE LABS Text:M23-I-2 TLI#45399
1003
aoj
32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00
file:W9810ia #1-355 Acq:16-APR-1998 17:16:52'GC EI+ Voltage SIR JOSE Noise:493
375.8178 F:3 BSUB(256,30,-3.0) PKD( 7,5,3, 0.10^,1972.0,1. 00%,F, T) JBxptODBSVS
TRIANGLE LABS Text:M23-i-2:" TLI&45399
1004 A1.02E5
32:36 32:48' 33:00 33-12 331-24 33:35 33:48 34:00 34:12 34:24 34:36 34:48 35:00
File:W981018 #1-355 Acq:16-APR-1998 17:16:52 GC EI+ Voltage SIR 70SE Noise:749
383.8639 Fs3 BSUB(256,30,-3.0) PKD(7,5,3,0.10^,2996. 0,1. 00%,f,T) Exp-.NDBSOS
TRIANGLE LABS Teit.:M23-I-2 TLI#45399
1004
801
601
401
201
01
A2.83E4
A5.90E4
Al.41E4
1.59E4^A7.93E3
80;
601
401
201
A1.44E6
A1.22E6
Al. 06E6
32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00
File:tf981018 #1-355 Acq:16-APR-1998 17:16:52 GC EH- Voltage SIR 70SE Noise:886
385.8610 F:3 BSUB(256, 30, -3 . 0) PKD(7, 5, 3, 0 .10%, 3544 . 0,1. 00%, F, T) Exp:M)B5US
TRIANGLE LABS Text:M23-I~2. TLI#45399
1003, ' A2.S7E6
aoj . . A A2.41E6
35:12 35:24
601
401
201
01
i f
A2.12E6
r I —
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32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00
file:W981018 #1-355 Acq:16-APX-1998 17:16:52 GC EI+ Voltage SIR 70SE
392.9760 F:3 Exp:NDB5US
TRIANGLE LABS Text:M23-I-2 TLI#45399
i • i i i i i i i I i i
35:12 35:24
aoi
601
401
201
01
32.-3S 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00
File:W981018 #1-355 Acq:16-APR-1998 17:16:52 GC EH- Voltage SIR 70SE
445.7555 Fs3 Exp:NDB5US
TRIANGLE LABS Text:M23-I-2 TLI#45399
1004 34,-34
801
601
401
201
oi
35:12 35:24
O.OEO
Time
.3. 1E4
.2.5E4
.1.9E4
.1. 3E4
.6.3E3
O.OEO
Time
.4 . 8E5
.3. 8E5
.2.9E5
.1.9E5
.9. 5E4
.O.QEQ
Time
.9.3E5
. 7. 4E5
.5.6E5
.3.7E5
.1. 9E5
.O.OEO
Time
.8.5E6
.6.8E6
.5.1E6
,3. 4E6
.1. 7E6
32:36 32:48 33:00 33:12 33:24 33:38 33:48 34:00 34:12 34:24 34:36 34:48 35:00
35:12 35:24
O.OEO
Time
.1.2E4
.9.4E3
.7.1E3
4. 7E3
.2.4E3
.O.OEO
Time
^>
-------
•ileiw961016 #1-355 Acg:16-APS-1998 17:16:52 GC Elf Voltage SIS 70SE Noise:584
89.8156 F:3 BSUB(256, 30/-3.0) PKD(7,5,3, 0.10%,2336. 0,1. 00%, F, I) ExpsODBSUS
TRIANGLE LABS Tezt:M23-I-2 XLI04S399
A3.07E4
so:
33'sOO 33:12 33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00
File:W981018 #1-355 AcqilS-APS-1998 17:16:52 SC EI+ Voltage SIS 70SE Wo±se:687
391.8127 F:3 BSUB(256,30,-3.0) PKD(7,5,3, 0.10%,2748.0,1. 00%,F,T; Exp:NDB5US
TRIANGLE LABS TextsM23-I-2 TLI#45399
100% A2.$5E4
so:
40:
20.
A2.04E4
AS.06E3
rr
~r
T
I.OE4
.8.4E3
.6.3E3
.4.2E3
.2. 1E3
.O.OEO
TJJR&
33:00 33:12 33':24 33':3S 33:48 34:00 34:12 34:24 34:36 34:48
File.-WSSlOlS #1-J55 Acq:16-APK-1998 17:16:52 SC EH- Voltage SIS 70SE Noise:666
401.8558 Fs3 BSUB(25S,30, -3.0) PKD(7,5,3, 0.101,2664 . 0,1. 00%,F, T) Exp:M>S5US
TRIANGLE LABS Text:M23-I-2 TZI#45399
10 04 Al. 92E6 A2. Q9E6
80.
60.
40.
20.
35:00
33:00 33:12 33:24 , 33:36 33:48 34:00 34:12 34:24 34:36 34:48
File:ff981018 #1-355 Acy:16~APR-1998 17:16:52 SC EI+ Voltage SIS 70SE No±se:581
403.8529 F:3 BSOB(256, 30,-3.0) PKD(7,5,3, 0.10%,2324. 0,1. 00%, F, T) Exp:W)B5US
TRIANGLE LABS Text:M23-I-2 TLI#45399
35:00
#1-355 Rcq:16-APR-1998 17:16:52 GC EI+ Voltage SIS 70SE
392.9760 F:3 Exp:NDS5US
TRIANGLE LABS Text:M23-I-2 TLX#45399
33:09
80.
so:
40:
20.
0.
33:21
33:00
33:12
33:24 , 33:36 33:48 34:00 34:12 34:24
34:36
34:48
35:00
2.0E3
. 0. OEO
Time
.5.7E5
.4.6E5
.3.4E5
.2.3E5
.1. 1E5
.O.OEO
Time
100%
so:
40:
20:
0'
A1.54E6 A1.73E6
k n
d ft
V
I I-
33:00 33:12 33,-24 ; 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35;00
4.8£5
3.8JJ5
2.9E5
1.9E5
9.6E4
O.OEO
Time
.8.5E6
.6.8E6
.5.1E6
.3.4E6
.1. 7E6
.O.OEO
Tim.
116
-------
File:ff981018 #1-589 Acq: 16-APS-1998 17:16:52 GC EH- Voltage SIR 70SE Noise:609
407.7818 F:4 BSUB(256, 30,-3.0 ) PKD( 7, 5,3, 0 .101,2436. 0,1. 00%,f, T) Exp:NDB5US
TRIANGLE LABS Text:M23-I-2 TLI#45399
100* A3.58E4
80:
36:36 36:48 37:00 37:12 37:24 37:36 37:48 38:00 38:12
File:ff981018 #1-589 Acq:16-APR-1998 17:16:52 GC EH- Voltage SIR 70SE Noise:472
409.7789 F:4 BSUB(256, 30,-3.0) PKD( 7,5,3, 0 .101,1888. 0,1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Text:M23-I-2 TLI#45399
1004 A2.76E4
36:36 36:48 37:00 37:12 37:24 37:36 37:48 38:00 38:12
File:W981018 #1-589 Acq:16-APR-1998 17:16:52 GC EH- Voltage SIR 70SE Noise:674
417.8253 F:4 BSUB(256, 30,-3. 0) PKD(7, 5,3, 0.101,2696. 0,1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Teit:M23-I-2 TLI#45399
1003i A8.81E5
38:36
38:36
80:
60:
40:
20:
0:
A5.70E5
36:36 36:48 37:00 37:12 37:24 37:36 37:48 38:00 38:12
File:W981018 #1-589 Acq:16-APR-1998 17:16:52 GC EH- Voltage SIR 70SE No±se:605
419.8220 F:4 BSUB(256, 30, -3. 0) PKD( 7, 5,3, 0.101,2420. 0,1. 00%, F, T) Exp:M)B5US
TRIANGLE LABS Text:M23-I-2 TLI#45399
lOOS, A1.?7E6
_1. 9E5
_1. 4E5
-9.6E4
.4 . 8E4
38:24
38:36
O.OEO
Time
80:
60:
401
20:
ol
A1.20E6
_5. 3E5
-4.3E5
.3.2E5
.2. 1E5
.1.1E5
36:36 36:48 37:00 37:12 37:24 37:36 37:48 38:00
File:tf981018 #1-589 Acq:16-APR-1998 17:16:52 GC EH- Voltage SIR 70SE
430.9729 F:4 Exp:NDB5US
TRIANGLE LABS Text:M23-I-2 TLI#45399
1003j 36:37 36:51 37^1837:26 37:34 _ 38:04
-~-
80:
60:
40:
20:
0:
38:12
38:24
38:24.
38:36
O.OEO
Time
-7.4E6
-5. 9E6
-.4.4E6
:.2.9E6
_1. 5E6
36:36 36:48 37:00 37:12 37:24 37:36 37:48 38:00
File:W981018 #1-589 Acq: 16-APR-1998 17:16:52 GC EH- Voltage SIR 70SE
479.7165 F:4 Exp-.NDBSUS
TRIANGLE LABS Text:M23-I-2 TLI#45399
37:30 37:55
I II A •";-••*
80:
60:
40:
20:
0:
38:12
38:24
38:36
O.OEO
Time
38:20
1. 1E4
-8.4E3
L6.3E3
-4.2E3
.2.1E3
36:36
36:48
37:00
37:12
37:24
37:36
37:48
38:00
38:12
38:24
38:36
O.OEO
Time
117
-------
#1-583 Ac>jil6-APR-l99S 17:15:52 GC E1+ Voltage' SIS 70SE Noise:S43
23.7766 Fs4 BSUB(256,30f-3.0) fXD(7,5,3,0.10\,2172.0,1.00\,F,T) Exp:NDB5US
TRIANGLE LABS Text:M23-I-2 TLH45399"
1003>
37:00 38s00 39:00
'ile:tr981018 #1-589 Acg:16-APR-199B 17:16:52 GC EI+ Voltage SIR 70SE Noise:549
425.7737 F:4 BSUB(256,30, -3 . 0) PKD(7,5,3, 0.101,2196. 0,1. 00\,F,T) Exp-.NDBSOS
TRIANGLE LABS Text:M23-I-2- TLI#45399
1004 A3.32E3
A1.33E4
601
60.
a 01
601
401
201
A2.20E4
Al. 42E4
.S.83E3
37:00 , 38:00 33:00
F±le:K93101B #1-589 Ac
-------
File:W981018 #1-589 Acq:16-APR-1998 17:16:52 GC EH- Voltage SIR JOSE Noise:536
441.7428 F:4 BSVB(256,30,-3.0) PKD(7, 5,3, 0 .101,2144 . 0,1. 00%,F, T) Exp:NDB5VS
TRIANGLE LABS Text:M23-I-2 TLH45399
36:00 37:00 38:00 39:00 40:00 41:00
File:W981018 #1-589 Acq:16-APR-1998 17:16:52 GC EH- Voltage SIR 70SE No±se:595
443.7399 F:4 BSUB(256, 30, -3. 0) PKD(7, 5,3, 0 .101,2380 . 0,1. 001,F, T) Exp:NDB5US
TRIANGLE LABS Text:M23-I-2 TLH45399
100S A1.51E4
42:00
O.OEO
43:00 Time
36:00 37:00 38:00 39:00 40:00 41:00 42:00
File:W981018 #1-589 Acq: 16-APR-1998 17:16:52 GC EI+ Voltage SIR 70SE
430.9729 F:4 Exp:NDB5US
TRIANGLE LABS Text:M23-I-2 TLI#45399
1003,
37:34
801
701
601
501
401
301
20.
40:05 40:4441:08
36,2336,5!
O.OEO
43:00 Time
,.8.0E6
..7.2E6
_6.4E6
_5.6E6
-4.8E6
_4.0E6
.3.2E6
L2.4E6
Ll. 6E6
L8.0E5
36:00 37:00 38:00 39:00 40:00
File:»981018 #1-589 Acq:16-APR-1998 17:16:52 GC EH- Voltage SIR 70SE
513.6775 F:4 Ejcp:NDB5US
TRIANGLE LABS Text:M23-I-2. TLI#45399
37:13
41:00
1003
901
801
701
601
501
401
301
201
101
01
38:36
36:30
39:44
42:00
41:55
43
_O.OEO
00 Time
36:00
37:00
38:00
39:00
40:00
41: 00
42:00
43
1. OE4
19. 2E3
L8.2E3
L7.2E3
L6.1E3
15. 1E3
14.1E3
13. 1E3
12.0E3
Ll. OE3
'•.O.OEO
00 Time
119
-------
'He:ff98lOl8 #1-58$ Acq:16-APX-L99U 17:16:52 GC EI+ Voltage SIR 70SE Noiae:457
57.7377 F:4 BSUB(256, 30,-3 .0 ) PKD(7, 5,3 , 0.10*, 1828. 0,1. 00*,F,T) Exp:NDB5US
TRIANGLE LABS Text:M23-T-2 TLH45399
1003, A5.96E4
41:12 41:18 41:24 41:30 41:36 41:42
File:W981018 #1-589 Acq:16-APS-1998 17:16:52 GC EI+ Voltage SIR 70SE Noise:467
459.7348 F-.4 BSDB(256, 30,-3. 0) PKD(7, 5,3, 0 .101,1868. 0,1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Text:M23-I-2< TLI#45399
1004 A1.Q6E5
801
so:
401
201
01
41:12 4l':18: 41:24 41:30 41:36 41:42
File:tf981018 #1-585 Acq: 16-APR-1998 17:16:52 GC EI+ Voltage SIR 70SE Noise:484
469.7779 F:4 BSUB(256, 30,-3 . 0) PKD(7, 5,3, 0.10%, 1936. 0,1. 00*,F, T) Exp:NDB5US
TRIANGLE LABS Text:M23-I-2 TLH45399
1003, A1.42E6
T
-r
T"
~T
~T
41:12 41:18 41:24 41:30 41:36 41:42
File:W981018 #1-589 Acq:16-APR-1998 17:16:52 GC EI+ Voltage SIR 70SE No±se:390
471.7750 F:4 BSUB(256, 30,-3.0 ) PKD(7, 5,3 , 0 .10*, 1560 .0,1.00*,F,T) Ezp:NDB5US
TRIANGLE LABS Text:M23-I-2 TLI#45399
100$ A1.57E6
41:12 41:18 41:24 41:30 41:36
File:W981018 #1-589 Acq:16-APR-1998 17:16:52 GC EI+ Voltage SIR 70SE
430.9729 F:4 Exp:NDB5US
TRIANGLE LABS Text:M23-I-2 TLI#45399
1003, ' 41.2g 41:38
41:42
eo:
601
40.
201
0.
41 .-18
41 !• 30
41:36
~"—I—"""
41: 42
O.OEO
41:48 Time
1. 6E4
.1. 3E4
.9. 5E3
.6.4E3
'.3.2E3
41:48
O.OEO
Time
41:48
_2 . 6E5
-2.1E5
-1 . 6E5
1.1 . OE5
L5.2E4
O.OEO
Tim,
-2.3E5
11 . 7E5
'.1 . 1E5
'.5. 7E4
'.O.OEO
41:48 Time
41:46
-6.3E6
-4.7E6
'.3.1E6
'.1. 6E6
'.O.OEO
Time
120
-------
File:W981018 #1-798 Acq:16-APR-1998 17:16:52 GC EI+ Voltage SIR 70SE
339.8597 F;2 Exp:NDB5US
Sample Text:M23-I-2 TLI#45399 File Text:TRIANGLE LABORATORIES, INC.:: DBS::
100%
80J
60 j
40J
20
OJ
-i—i—j—i—i—I—r—I—]—i—I—I—i—i—i—i—i—i—i—i—|—i—i—i—i—i—i—i—i—i—i—i—|—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—|—i—i—i—i—i—j—i—I—I—I—I—|—I—i-
29:36 29:42 29:48 29:54 30:00 30:06 30:12 30:18 30:24 30:30 30:36 30:42
File:W981018 #1-798 Acq:16-APR-1998 17:16:52 GC EI+ Voltage SIR 70SE
341.8567 F:2 Exp:NDB5US
Sample Text:M23-I-2 TLI#45399 File Text:TRIANGLE LABORATORIES, INC.:: DBS::
100% A1.16E5
80 J
60J
20J
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29:36 29:42 29:48 29:54 30:00 30:06 30:12 30:18 30:24 30
File:W981018 #1-798 Acq:16-APR-1998 17:16:52 GC EI+ Voltage SIR 70SE
351.9000 F:2 Exp:NDB5US
Sample Text:M23-I-2 TLI#45399 File Text:TRIANGLE LABORATORIES, INC,
100% 30;10
80
60_:
40J
20J
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DBS
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29:48
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.4.7E4
.3.5E4
.2.4E4
.1.2E4
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Time
.4.4E4
.3.5E4
.2.6E4
.1.7E4
.8.7E3
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.9.6E5
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.5.8E5
.3.9E5
.1.9E5
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Time
-------
CvJ
c:
File:W981018 #1-589 Acq:16-APR-1998 17:16:52 GC EI+ Voltage SIR 70SE
457.7377 F:4 Exp:NDB5US
Sample Text:M23-I-2 TLI#45399 File Text:TRIANGLE LABORATORIES, INC.:: DBS:
39:00 40iOO 41iOO 42:00
File:W981018 #1-589 Acq:16-APR-1998 17:16:52 GC EI+ Voltage SIR 70SE
459.7348 F:4 Exp:NDB5US
Sample Text:M23-I-2 TLI#45399 File Text:TRIANGLE LABORATORIES, INC.:: DBS:
100% 41;21
80J
40 j
201
OJ
39:38
39:01 39
42:44
2.0E4
L.1.6E4
L1.2E4
L7.9E3
T
T
39:00 40:00 41:00 42:00
File:W981018 #1-589 Acq:16-APR-1998 17:16:52 GC EI+ Voltage SIR 70SE
469.7779 F:4 Exp:NDB5US
Sample Text:M23-I-2 TLI#45399 File Text:TRIANGLE LABORATORIES, INC.:: DBS:
100%, 41; 20
801
601
40
39:33
39:00
40:00
41:00
42:00
JLO.OEO
Time
2.7E5
L2.1E5
1.6E5
il.1E5
L5.3E4
.O.OEO
Time
-------
TLI Project: 45399
Client Sample: M23-I-2
Method 23 TCDD/TCDF Analysis (DB-225)
Analysis File: P981307
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
r012.002/Lime
M23
204-92-2A-D
1.000
n/a
DB-225
Kiln
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
" Blank File:
Analyst:
04/01798
04/03/98
04/16/98
n/a
U980780
ML
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPC2NF04
PF24098
P981302
n/a
n/a
n/a
Anajytes
Ami (ngj
Di
EMPC
Ratfo
RT
Hags
2,3,7,8-TCDF
0.51
0.78
22:25
Internal Standard
AffiL (ngj
% Recovery
QC Limits
Ratio
RT
Flags
13C12-2,3,7,8-TCDF
2.9
73.5
40%-130%
0.78
22:24
Recovery Standard
Ratio
RT
Flags
13Cirl,2,3,4-TCDD
0.80
21:18
Data Reviewer
04/20/98
Page 1 of 1
C2NF_PSR V2.02, LARS 6.11.00
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 21:2j
-------
Data Review By:
Initial ....Date...
*^ /1P_/ !_ Calculated Noise Area:
0.14
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
04/20/98
Listing of P981307B.dbf
Matched GC Peaks / Ratio / Ret. Time
Cotnpound/
M_Z,... QC.Log Omit Why ..FT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.KT Compound.Name.. ID,. Flags,
TCDF
304-306 DC NL 0:
17:
DC SN 18:
DC SN 18:
DC SN 18:
18:
18:
19:
19:
19:
19:
19:
20:
20:
20:
20:
DC SN 20 :
21:
21:
0.65-0.89
00 RO
52
08 RO
IS RO
28 RO
51
59
07
18
34
43
52
02 RO
12 RO
33
38
46 RO
00
•06 RO
21:15
21:28
21:
21
42
:52
DC SN 22:04 RO
22:17
22
22
22
23
23
DC SN 23
23
DC SN 24
24
:25
:39
:57
:05
:15 RO
:32 RO
:50
:05
:32
1.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
00
77
07
18
61
76
75
76
78
72
77
75
0.58
0.48
0.
77
0.76
5.00
0.76
0,
0
0
0
0
1
0
0
0
0
0
0
1
0
0
0
.58
.73
.75
.78
.75
.00
.75
.78
.73
.77
.76
.63
.00
.75
.69
.73
304-306 26 Peaks
13C12-TCDF
316-318 DC NL 0
DC ML 20
DC WL 21
22
23
DC WH 23
0.
:00 RO
:59
;14
:24
:04 RO
:28 RO
65
1
0
0
0
1
3
-0.89
.11
.67
.69
.78
.15
.76
0.
48.
0.
0.
0.
103.
44.
56.
42.
27.
45.
19.
87.
16.
67.
46.
0.
62.
5,
. 56.
46.
3
33
0
14
60
25
05
39
15
53
64
31
92
46
04
63
44
70
.58
05
.96
,65
.37
.36
.62
.87
.19
32.31
46
29
24
62
0
0
21
0
3
1,034
0
1
1
367
0
0
.03
.88
.14
.23
.46
.07
.52
.22
.15
.55
.16
.00
.40
.86
.48
.44
21.
44.
19.
24.
18.
11.
19.
8.
38.
7,
29.
20.
27,
2.
23
19
1
14
13
20
12
10
26
0
9
1
161
0
19
43
06
51
56
67
72
.17
.12
,15
.41
.15
.18
.46
.75
.94
.59
.49
.81
.11
.56
.49
.82
.20
.23
.33
.58
.31
27.
58.
25.
32.
23.
16.
25.
10.
65.
14,
38.
26.
35
4
32
26
2
19
18
25
17
13
35
0
12
1
206
0
0.790-1.102
41
72
47
13
,75
,25
,74
.87
.42
.84
,29
.43
.78
.23
.62
.42
.03
.38
.50
.92
.32
.65
.41
.32
.29
.82
0.
.28
.27
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0,
0,
0,
0,
0.
0
0.
0
1
1
1
1
'1
1
1
1
1
000
798
810
817
824
842
847
853
862
874
880
887
894
.902
917
921
927
.938
.942
.949
.958
.969
.976
.985
.995
.001 2378-TCDF AN
.011
.025
.031
.038
.051
.064
.075
.095
955-1.045
0
0
0
I
1
1
.000
.937
.943
.000 13C12-2378-TCDF ISO
.030
.048
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 21:27
-------
Page No.
04/20/98
Listing of P9S1307B.db£
Matched GC Peaks / Hatio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area.., Area.Peak.1.. Area.Peak.2.. Eel.RT Compound.Hame.. ID.. Flags.
316-318
13C12-TCDD
332-334
332-334
DC WH 24:26 RO 1.03
2 Peaks
DC
NL 0:00
21:01
21:18
22:02
3 Peaks
0.65-0.89
RO 1.25
0.78
0.80
0.87
4.96
368.34
Above: TCDP / TCDO Follows
1.25
0.78
0.80
0.87
0.14
274.67
372.60
" ' 2.28
649.55
119.98
165.60
1.06
1.091
0.905-1.035
0.000
154.69 1.000 13C12-2378-TCDD IS1
207.00 1.013 13C12-1234-TCDD RSI
1.22 1.048
Column Description.
"Why" Code Description......... QC Log Desc.
M_Z -Nominal Ion Mass(es)
. .RT, -Retention Time (numiss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio outside Limits
Rel-RT-Relative Retention Time
End of Report ***
WL-Below Retention Time Window
WH-Above Retention Time Window
SH-Below Signal to Hoise Level
-------
:P981307 #1-1006 Acq:16-APR-199B 18:12:16 EI+ Voltage SIR 70P
03.9016 Elp:DB225
TRIANGLE LABS TextiM23-I-2 TLI#45399
100*
21:00 21:12 21:24 21:36 21:48 22:00 22:12 22:24 22:35 22:48 23:00 23:12 23:24 23:
36 23:48 24
File:P981307 #1-1006 Acq:16-APR-1998 18:12:16 EI+ Voltage SIR 70P
315.9419 Exp:DS225
TRIANGLE LABS Text:M23-I-2 TLI#45399
1004 22:24
POJ
85J
80J
75J
70J
65J
60.
55.
50.
45.
40.
35.
25.
20.
15.
5j
4.2Z5
L4.0Z5
L3.8Z5
i3 . 6E5
L3. 4Z5
L3.2F5
12.9E5
'-.2.7E5
.2.5E5
'.2.3E5
'.2.1E5
L1.9E5
':! . 7E5
':!. 5E5
-1. 3E5
'.1. 1E5
-8.4E4
'.6.3E4
'.4.2E4
'-2.1E4
21 00 21:12 21:24 21:36 21:48 22:00 22:12 22:24 22:36 22:48 23:00 23:12 23:24 23:36 23:48 24
.O.OEO
00 Time
126
-------
'ile:P981307 #1-1006 Ac
-------
i±e:P98l307 il-lOOg Acq:16-APR-lSSB 16:12:16 EI+ Voltage SIS 70P Noiee:37
19.8965 BSUB(256,30,-3.0) PKD(5, 3, 1, 0.10%, 148 . 0, 0. 001,T,T) Eip:DB225
TRIANGLE LABS Text:M23-I-2 TLI#45399
1003.
19:00 20:00 21:00 22:00 23:00
•ile:P981307 #1-1006 Acq:16-APR-1998 18:12:16 EI+ Voltage SIR 70P Noise:37
321.8936 BSUB(256,30,-3.0) PKD(5, 3,1, 0.10%, 148. 0, 0 . 00%,F, F) Exp:DB225
TRIANGLE LABS Text:M23-I-2 TLI#45399
1003.
ao:
60.
40.
20.
A2.1BE4
Al.63E4
A1.53E4
A9.46E3
A8.37E3
\A1. 69E3
j. j /
A
_1. 1E4
_8.7E3
-6.5E3
.4.4E3
.2.2E3
A3.35E3
24: 00
O.OEO
Time
ao:
60.
40.
20.
A2.83E4
A2.38E4
A1.90E4
A1.24E4
A
A1.22E4
\A2.96E3
L .44
A
A6.73E3
1. 5E4
.1.2E4
.8.7E3
.5.8E3
.2.9E3
19:00 20:00 21:00 22:00 23:00
File:P981307 #1-1006 Acq:16-APR-1998 18:12:16 EI+ Voltage SIR 70P No±se:37
327.8847 BSUB( 256, 30, -3. 0) PKD( 5, 3, 1, 0.10%, 148. 0, 0. 00*,F,F) Eip:DB225
TRIANGLE LABS Text:H23-I-2 TLI#45399
1003i A2.45E6
ao:
eo:
40:
20L
15:00 20:00 21:00 22:00 23:00
File:P981307 #1-1006 Acq:-16-APR-1998 18:12:16 EI+ Voltage SIS 70P Noise:48
331.9368 BSUB(256,30,-3.0) PKD(5,3, 1, 0.10%, 152. 0, 0 . 00%,F,F) Elp:DB225
TRIANGLE LABS Text:M23-I-2 TLIH45399
1003, A1.66E6
ao:
eo:
40.
20.
A1.20E6
19:00 20:00 21:00 22:00 23:00
File .-PS 813 07 #1-1006 Acq:16-APR-1998 18:12:16 EI+ Voltage SIR 70P Noise:38
333.9338 BSUB(256,30,-3.0) PKD(5,3, 1, 0.10%, 152. 0, 0 . 00*,F,F) Elp:DB225
TRIANGLE LABS Text:M23-I-2 TLI#45399
1004 A2.07E6
80.
eo:
40.
20.
0.
A1.55E6
24 : 00
24 : 00
24 : 00
O.OEO
Time
_6.3E5
is.ors
_3.8£5
.2.5E5
.1. 3E5
O.OEO
Time
13. 6E5
-2.7E5
11. 8E5
.9. OE4
O.OEO
_5. 6E5
_4.4E5
-3.3E5
-2.2E5
_1. 1E5
19:00
20:00
21:00
22:00
23:00
24 : 00
.O.OEO
Tim
128
-------
jrile.-PS81.307 #1-1006 Acq:16-APR-1998 18:12:16 EI+ Voltage SIR 70P
303.9016 Elp:DB225
TRIANGLE LABS Text:M23-I-2 TLI#45399
1003
40.
201
01
18:00 19:00 20:00 21:00 22:00 23:00
File:P981307 #1-1006 Acq-.16-APR-1998 18:12:16 EI+ Voltage SIR 70P
315.9419 Eip:DB225
TRIANGLE LABS Teit:M23-I-2 TLI#45399
1003, 22; 24
aoi
601
201
oi
18:00 19:00 20:00 21:00 22:00 23:00
File:P981307 #1-1006 Acq:16-APR-1998 18:12:16 EI+ Voltage SIR 70P
319.8965 Eip:DB225
TRIANGLE LABS Teit:M23-I-2 TLI#45399
18:51
20: 02
20:33 21:00
23:05
23:50
A
24 .-00
24-00
ISiOO 15:00 201-00 21:00 22:00 23:00
File:P981307 #1-1006 AC(J.-16-APJ?-1SS8 18:12:16 EI+ Voltage SIR 70P
331.9368 Eip:DB225
TRIANGLE LABS Teit:M23-I-2.TLI#45399
1003, 21:18
24-00
80,
60-
4oi
201
01
21: 01
18:00 19:00 20:00 21:00 22:00 23:00
File:P981307 #1-1006 Acq:16-APR-1998 18:12:16 EI+ Voltage SIR 70P
292.9825 Eip:DB225
TRIANGLE LABS Teit:M23-I-2 TLI#45399
1003, ia:i8 19:36 20:21 21:20 21:52 22.;37
aoi
eoi
401
201
01
24:00
_1. 2E5
Ll. OJT5
L 7. 5E4
L5.0E4
'.2.5E4
•-O.OEO
25:00 Time
4.2E5
-2.5E5
.1. 7E5
-8.4E4
0. OEO
251-00 Time
25: 00 Time
4.5E5
.3.6E5
-2.7E5
.1. 8E5
-9.1E4
O.OEO
25:00 Time
23:15
24:44 3.0E5
pt
_2.4J?5
_1. 8E5
-6.0E4
-O.OEO
18:00 19:00 • 20:00 21:00 22:00 23:00 24:00
File:P981307 #1-1006 AC(j:16-APJ?-15S8 18:12:16 EI+ Voltage SIR 70P
330.9792 Eip:DB225
TRIANGLE LABS Teit:M23-I-2 TLI#45399
1004 lg.31 20:22 21:09 . 22:01 22j_39, 23:14 23:45 24:25..
1 1°-10 .. -*.*.*,s^v^jfiMs*
80.
25:00 Time
'a , „ __ 19.31 20:22 n:vy 4^:uj. 4£}jy 4J-.J.9 4J:45 44:43
•:^(^y^^^
601
40-
201
oi
3. 1E5
-2.5E5
'.1.9E5
-1.2E5
-6.2E4
•-O.OEO
a.-OO
15:00
2o-00
21:00
22:00
23 - 00
24-00
25:00 Tine
-------
tef, lass 282.9825 Peak top
Htlght ,85 wits Span 388 ppi
Systa File naie
Data File nate
Resolution
Gropnuiber
Mzatlon
Switching
ief, lasses
R 292,9825
383,9818
385,8987
315,9419
317,9389
319,8985
321,8936
327,8847
338,9792
J
K
L
1
1
El*
VOLTftGE
388,9761
338,9792
331,1388
333,9338
375,8384
Channel I 338,9792 Peak top
Height ,84 wits Span 288 p
-------
Pages 131 through 187 from the Triangle Laboratories, lac. analytical report
have been excluded by PES since these pages present results for samples
collected at another lime kiln facility during the same mobilization.
-------
TLI Project: 45399
Client Sample: M23-O-1
Method 23 PCDD/PCDF Analysis (a)
Analysis File: T981959
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
r012.002/Lime Kiln
M23
204-92-5A-D
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
04/01/98
04/03/98
04/18/98
n/a
U980780
HLM
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPMIT204
TF51308
T981946
n/a
n/a
n/a
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
Totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
ND
ND
ND
ND
ND
ND
ND
EMPC
ND
ND
ND
ND
ND
ND
ND
ND
ND
Ami {ng
0.03
ND
ND
ND
EMPC
EMPC
ND
ND
0.01
0.02
0,02
0.02
0.02
0,03
0.05
0.02 B__
0.01
0.01
0.01
0.01
0.01
0.01
0,02
0.02
0.04
1 ftomber Ot, SfltPC Bags'
1
0.02
0.02
0.03 ,
0.02
0.01
0.01
0.02
Page 1 of2
Mrr2_PSRvl.W. LARS 6.11,00
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 21:2404/;
-------
TLI Project: 45399
Client Sample: M23-O-1
Method 23 PCDD/PCDF Analysis (a)
Analysis File: T981959
Internal Standards Amt (ng)
»C,2-2,3,7,S-TCDF
I3Ci2-2,3,7,8-TCDD
13Cn-l,2,3,7,8-PeCDF
13C,2-l,2,3,7,8-PeCDD
!3Ci2-l,2,3,6,7,8-HxCDF
13Cp-l,2,3,6,7,8-HxCDD
13Ci2-l,2,3,4,6,7,8-HpCDF
13C12-l,2,3,4,6J,8-HpCDD
I3CP-1,2,3,4,6J,8,9-OCDD
0,92
0,89
1.0
1.3
1.4
1.5
1.3
1.5
2.0
P5»5:g^
13Ci2-2,3,4,7,8-PeCDF
l3Ci2-l,2,3,4J,8-HxCDF
13Cl2-l)23,4,7>8-HxCDD
i3C,2-l,2,3,4,7,8,9-HpCDF
Other Standard
37ei4-2,3,7,8-TCDD
Alternate Standards (Type A)
l3C,2-l,2,3,7,8,9-HxCDF
l3C,2-2,3,4,6,7,8-HxCDF
4.3
3.7
4.0
3.4
Amt {ng>
3.7
Amt. (ngj
1.5
1.6
% Recovery
22.9
22.3
25.6
31.3
35.4
36.3
33.7
38.7
25.1
107
91.3
99.4
84.8
% Recovery
92.6
% Recovery
38.5
39.2
QC Limits
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130% '
25%-130%
25%-130%
40%-130%
40%-130%
40%-130%
25%-130%
QC Limits
40%-130%
QC Limits
40%-130%
40%-130%
13C,Z-1,2,3,4-TCDD
13C12-l,2,3,7,8,9-HxCDD
Ratio
0.75
0.77
1.42
1.50
0.49
1.20
0.43
1.03
0.85
•1
1.41
0.49
1.21
0.42
Ratio
0.49
0.49
RT Flags
25:23 V
26:07 V
29:23 V
30:26 V
32:57 V
33:38 V
35:47
36:49
40:21
30:05
32:51
33:33
37:18
,RT , Flags
26:08
RT : Ffegs
34:11 V
33:26 V
mmmmmmmmmmwmmmmmmmmm
0.81
1.21
25:56
33:56
Data Reviewer
04/20/98
Page 2 of 2
MIT2_PSR vlM, LARS 6.11.00
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 * Fax: (919) 544-5491
Printed: 21:2404/;
-------
Initial
....Date...
Data Review By;
Calculated Noise Area: 0.22
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
04/20/98
Listing of. T981959B.dbf
Matched GC Peaks / Ratio / Ret. Tim*
Compound/
M_Z.... QC.Log Omit Why ..ST. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name,. ID.. Flags.
TCDP
304-306
D
AH
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
320-322
37C1-TCDD
328
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
DC HL 0:00
D SN 24:20
25:24
1 Peak
DC ML 0:00
DC WL 24:20
24:57
25:23
2 Peaks
DC HL 0 : 00
23:32
DC SH 23; 41
DC SN 23; 55
I Peak
DC NL 0:00
24:44
DC SN 24:52
26:08
DC SN 26:32
DC SN 26:36
26:44
27:26
4 Peaks
DC ML 0:00
25:56
26:07
2 Peaks
DC HL 0:00
DC SN 27:13
0.65-0.89
0.75
0.67
RO 0.59
0.65-0,89
RO 1.17
0.66
0.69
0.75
0.65-0.89
RO 1.00
0.71
RO 0.50
RO 0.96
0.65-0.89
RO 2.02
0.81
0.77
1.32-1.78
RO 0.71
RO 0.21
0.49
0.85
1.13 0.49
1.13
0.32
2.81
1.10 0.45
167.91 72.03
169.01
WOP / TT'nn Pr*1 1 r»t*f d - —
0.21
1.16 0.48
0.09
0.42
1.16
0.12
0.94 0.94
0.21
121.33 121.33
0.26
0.23
0.31 0.31
0.28 0.28
122.86
0.78
493.80 221.27
125.94 54.85
619.74
ITTWJ / PffltfTBi? Iffrsl 1 <-«»7«3 •*
0.16
0.21
0.868-1,077
0.000
0.959
0.83 1.001 2378-TCDF
0.961-1.039
0.000
0.959
0.65 0.983
95.88 1.000 13C12-2378-TCDF
0.896-1.045
0.000
0.68 0.901
0.907
0.916
0.924-1. 076
0.000
0.94?
0.952
1.001 37C1-TCDD
1.016
1.019
1.024
1.050
0.924-1.076
0.000
272.53 0.993 13C12-1234-TCDD
71.09 1.000 13C12-2378-TCDD
0.926-1.063
0.000
0.926
AH
ISO
CLS
RSI
I SI
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 21:24 04/2
-------
Page No.
04/20/98
Listing of T981959B.dbf
Matched GC Peaks / Ratio / Ret. Time
Confound/
M_Z.,.. QC.Log Omit Why ,.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Mame.. ID.. Flags.
K
340-342
13C12-PeCDF
352-354
352-354
PeCDD
356-358
356-358
13C12-PeCDD
368-370
27:24
1 Peak
DC ' NL 0:
28:
DC SN 29 1
: 29:
29:
30:
31:
00
31
00
23
40
05
04
RO
1.
RO
RO
0.
81
0.
0.
.41 0.25
41
32-1.78
0.
1.
2.
1.
1,
1.
1.
89
45
00
42
54
41
45
5 Peaks
DC NL 0 :
DC SN 28:
DC SN 29:
00
37
50
1.
RO
RO
RO
32-
1.
0.
0.
1.78
00
67
80
0 Peaks
DC NL 0 :
DC SN 29 :
DC SN 29:
00
20
29
1.
RO
RO
30:26
30:34
DC SN 30:43
RO
DC SN 31:12
368-370
HxCDF
374-376
374-376
13C12-HXCDF
384-386
0.
4.
0.
156.
1.
168.
0.
332.
13
76 2.82
,23
.28 91.79
,78 1.08
.59 98.75
.71 0.42
.12
0.31 0
.933
0.864-1.136
0
1.94 0
0
64.49 1
0.70 1
69.84 1
0.29 1
.000
.971
.987
.000 13C12-PeCDF 123
.010
.024 13C12-PeCDF 234
.057
IS2
SUR1
0.
0.
0.
0
.16
.16
•13
.00
32-1.78
1.
0.
1.
1.
1.
3.
1.
00
79
38
50
51
21
43
2 Peaks
DC NL 0
DC SN 32
DC SN 32
DC SN 32
DC SN 32
DC SN 33
DC SN 33
:00
:03
:12
:16
:22
:26
-•32
1.
05-1.43
1.10
RO
RO
RO
RO
1.
0,
1,
.38
,60
.60
0.67
1.
.14
1.67
0 Peaks
DC NL 0
31
32
32
32
33
33
DC SN 33
:00
:52
:01
:51
:57
:11
-.26
:44
0
RO
RO
RO
0.
0,
0.
105
12
0
0
117
.16
.31
.31
.91 63.62
.03 7.23
.36
.17
.94
0.936-1.021
0
0
0
.000
.940
.980
0.869-1.131
0
0
0
42.29 1
4.80 1
1
1
.000
.964
.969
.000 13C12-PeCDD 123
.004
.009
.025
I S3
* PsCDD / HxCDF follows *»*»«»
0
0
0
0
0
0
0
0
.21
.38
.05
.11
.04
.15
.07
.00
.43-0,59
1
0
0
0
0
0
0
0
.13
.45
.45
.49
.49
.64
.49
.42
0
1
2
146
167
1
174
0
.12
.71 0.53
.25 0.70
.92 48.51
.31 55.04
.13 0.48
.61 57.51
.80
0.963-1.045
0
0
0
0
0
1
1
0.879
0
1.18 0
1.55 0
98.41 0
112.27 1
0.75 1
117.10 1
1
.000
.973
.977
.979
.982
.015 234678-HxCDF
.018
-1.121
.000
.967
.972
.997 13C12-HXCDF 478
.000 13C12-HXCDF 678
.007
.015 13C12-HXCDF 234
.024
AN
SOR2
IS4
ALT2
Triangle Laboratories, Inc.® Analytical Services Division
801 Cap'rtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 21:24 04/20/98 .
- 191
-------
Page No.
04/20/98
Compound/
M_Z .... QC.
384-386
HxCDD
390-392
390-392
13C12-HxCDD
402-404
Listing of T981959B.dbf
Matched GC Peaks / Ratio / Ret, Time
Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound. Name.. ID.. Flags.
402-404
HpCDF
408-410
408-410
13C12-HpCDF
418-420
418-420
HpCDD
424-426
424-426
13C12-HpCDD
436-438
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
7
NL
SN
0
NL
SN
5
NL
SN
SN
0
NL
SN
SN
SN
SN
2
NL
0
NL
SN
SN
34:02
34:11
34:41 RO
Peaks
1.
0:00 SO
32:49
Peaks
1,
0:00 SO
33:02
33:33
33:38
33:56
34:23 RO
34:25
Peaks
0.
0:00
35:47 RO
35:54 RO
Peaks
0.
0:00 RO
35;47
36:04 RO
36:11
37:18
37:42 SO
37:45 RO
Peaks
0
0:00
Peaks
0
0:00
36:05
36:49
37:13 RO
37:20
0.
0.
0.
46
49
94
n1«.».wv« .
05-1.43
0.
1.
75
36
0.
132.
0.
626.
19
88 43.99
24
81
1.
88.89 1,
1.
033
037 13C12-HXCDF 789
053
ALT1
0.
0.
0.
16
26
00
05-1.43
0.
1.
1.
1.
1.
93
05
21
20
21
0.39
1.20
88-1.20
1.13
3.00
1.40
0.
0.
109.
131.
359.
0.
0.
602.
25
76 0.39
34 59.96
53 71.76
76 197,13
33
88 0.48
27
0.958-
0.
0.
0.970-
0.
0.37 0.
49.33 0.
59.77 1.
162.63 1,
1.
0.40 1.
1.013
000
976
1,030
000
982
998 13C12-HXCDD 478
000 13C12-HXCDD 678
009 13C12-HXCDD 789
022
023
SUR3
IS5
SS2
0.17
0.18
0.10
0.996-1.047
0.
1.
1.
000
000 1234678-HpCDF
003
AN
0.00
.37-0.51
0
0
0
0
0
0
0
.88
1
.88
1
1
1
3
0
.92
.43
.32
.48
.42
.62
.72
ove.
-1.20
.00
-1.20
.00
.00
.03
.00
.90
0
89
0
0
54
0
0
144
HPCD:
.17
.68 27.02
.62
.34
.97 16,38
.30
.26
.65
0.944-1.112
0.
62.66 1,
1.
1,
38.59 1,
1,
1
,000
.000 13C12-HpCDF 678
,008
.011
.042 13C 12 -HpCDF 789
.054
.055
IS6
SOR4
0.976-1.005
0
0
.16
.00
0
,000
0.973-1,027
0
0
84
0
0
.18
.66 0,33
.73 42.99
.24
.19
0
0.33 0
41.74 1
1
1
.000
,980
.000 13C12-HpCDD 678
.011
.014
IS7
Triangle Laboratories, Inc.® Analytical Services Division
801 Cap'rtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 21:24 04/20/98
t.q
-------
Page No.
04/20/98
Confound/
M_Z.... QC.
436-438
OCDF
442-444
442-444
Listing of T981959B.dbf
Matched GC Peaks /' Ratio / Ret. Time
Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2. . Rel.RT Compound.Name.. ID.. Flags.
2 Peaks 85.39
Above: HpCDD / Octa-CDD and CDF Follows
0.76-1.02
DC NL 0;00 1.00
DC SN 41:26 RO 0.58
DC SN 41:57 RO 9.00
0 Peaks
0.18
0.15
0.02
0,00
0.901-1.099
0.000
1.027
1.040
OCDD
458-460
458-460
0.76-1.02
DC NL 0:00 1.00
0 Peaks
0.14
0.00
0.901-1.099
0.000
13C12-OCDD 0.76-1.02
470-472 DC NL 0:00 1.00 0.16
40:21 0.85 73.77
470-472 1 Peak 73.77
33.99
0.996-1.004
0.000
39.78 1.000 13C12-OCDD
I S3
Column Description.
"Why" Code Description QC Log Desc.
M^_S -Nominal Ion Mass(es)
. .RT. -Retention Time (mnuss)
Rat.l -Ratio of M/M+2 Ions
OK -RQ=Ratio Outside Limits
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
File:T981S59 #1-720 Acq:18-APR-1998 07:45:55 EH- Voltage SIR JOT Noise:106
303.9016 T:2 BSVB(256,30, -3. 0) PKE(9, 5,5, 0. 05%,424 , 0, 1 . 00%,F, T) Exp:NDB5US
TRIANGLE LABS Teit:M23-O-l TLIf45399 INT. TIME =
100J
80J
sol
40.
20:
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A4 , 63E3
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jj I A3.06E3 J
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305.8987 F:2 BSUB(256,30f-3lO) PKD(9,5,5r0.05\,S64.0r1.001rr,T) Exp:NDB5US
TRIANGLE LABS Text:M23-0-l' TLI#453S9 INT. TIME =
loos
80J
sol
40:
20:
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J,«.J«
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File : r9S1959 #1-720 Acq:18-APR-199a 07:45:55 £1+ Voltage SIS 70T Noise:106
315.9419 Fs2 BSUB(256, 30, -3. 0} PKD(9,5,5, 0 . 05%, 424. 0,1. 00%,F, T) Exp:NBB5US
TRIANGLE LABS Text:M23-0-l TLI#45399 INT. TIME =
1003.
80J
60J
40J
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1.9JT5
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317.9389 F:2 BSUB(256,30,-3 !0) PKD(9, 5,5, 0, 05%, 3SO. 0, 1 . 00%,F, T) Exp:NDB5US
TRIANGLE LABS Zext:M23-0-l TLI#45399 INT. TIME =
100S - A9.59E5
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601
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330.9792 F:2 Exp-.NDBSUS
TRIANGLE LABS Text:M23-0-l XX,If45399 INT. TIME -
1003
80_
60.
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20.
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_ 22:34 23_iOl ' j^_^_— £-^2 _ ^3*Ji££^ -^V. — ^^_ . —
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27:00 Time
07:46
26il8 26:53 -1.3ES
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Fi.le:T981959 #1-720 Acq:18-APR-1998 07:45:55 EI+ Voltage SIR 70T
375.8364 T:2 ElpiNDBSUS
TRIANGLE LABS TeXtiM23-O-l TLI#45399 INT. TIME =
1003, 23(10 -
80.
60.
40.
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0.
; ,' 25:32
I ' ^ 24 : 08
22:26 2J;|PJ - t J3f5J i I24!34 25I17 I
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2J:OflT 24\0^ ' ' " ' 25\ 00 ' ^ ' *26Too' ' " ' * 27\0o' ' ' ' Time
194
-------
File:T981959 #1-720 Acq: 18-APR-1998 07:45:55 EI+ Voltage SIR
70T Noise: 58
319.8965 F:2 BSUB(256, 30, -3 . 0) PKD( 7, 5, 3, 0 . 05%, 232. 0, 1 . 00%, F, T) Exp:NDB5US
TRIANGLE LABS Text:M23-0-l TLI#45399 INJ~. TIME - 07:46
1004
aoi
601
401
201
01
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1 . -
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I \ 1 A1.40E3
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24:00 25:00 26:00 27:00
File:T981959 #1-720 Acq:18-APR-199S 07:45:55 EI+ Voltage SIR
-9 . 6E2
_7.2E2
-4.8E2
-2.4E2
O.OEO
Time
70T Noise: 61
321.8936 F:2 BSUB(256, 30, -3 . 0) PKD(7, 5, 3, 0 . 05%, 244 . 0, 1 . 00%, F, T) Eip:NDB5US
TRIANGLE LABS Text:M23-0-l TLI#45399 INJ~. TIME = 07:46
1004
801
601
401
2di
b:
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A2.43E3 "
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24:00 25:00 26-00 27:00 Time
File:T981959 #1-720 Acq:18-APR-1998 07:45:55 EI+ Voltage SIR
70T Noise: 44 3
331.9368 F : 2 BSUB(256,30, -3.0) PKD( 7, 5,3, 0. 05%, 1772. 0,1 . 00%, F, T) Exp:NDB5US
TRIANGLE LASS Text:M23-0-l TLI#45399 INJ~. TIME = 07:46
1003
aoi
601
401
;
20J
o:
A2.21E6
A
6.1E5
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-4.9E5
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'-2.4E5
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"- o . OEO
24:00 25:00 26:00 27:00 Time
File:T9S1959 #1-720 Acq: 18-APR-1998 07:45:55 EI+ Voltage SIR
70T Noise: 220
333.9338 F:2 SSUB(256, 30, -3 . 0) PKD( 7, 5, 3, 0 . 05%, 880. 0,1 . 00%, F, T) Eip:NDB5US
TRIANGLE LABS Text:M23-0-l TLI#45399 INJ. TIME = 07:46
1004
aoi
601
401
20.
A2.73E6
ft
•
7.5E5
.17.11175
; ;\A
.6.0E5
.4.5E5
-3.0E5
-1.5E5
O.OEO
24:00 ' ' . ' '25:00 2ffl-00 271-00 ' Time
File:T981959 #1-720 Acq:18-APR-1998 07:45:55 EI+ Voltage SIR
70T Noise: 58
327.8847 F:2 BSUB(256, 30, -3 , 0) PKD( 7, 5, 3, 0 . 05%, 232. 0, 1 . 00%, F, T) Eip:NDB5US
TRIANGLE LABS Teit :M23-O~1 A TLI#45399 INJ. TIME = 07:46
1003
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60i
401
201
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24:00 ' ' ' ' ' 25:00 26: 00 27:00 ' Time
File:T981959 #1-720 Acq: 18-APR-1998 07:45:55 EI+ Voltage SIR
330.9792 F:2 Exp:NDB5US
70T
TRIANGLE LABS Teit:M23-O-l TLI#45399 INJ. TIME = 07:46
1003
aoi
60i
401
201
o-
24 ; 09 24 : 55 ^5-<^^ 26 z 0
— ^^-^~/^"^~^^^
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.8.0E5
.5.3E5
-2.7E5
0 . OEO
24:00 ' ^ ' ' ' 251-00 ' ' ' ' ' 2fil-00 ' ' "~ 27^0 r ' ' Time
195
-------
•ilesT981959 #1-720 Acq:18-APR-19S8 07:45:55 EI+ Voltage SIS 70T Noise:50
39.8597 f:2 BSUB(256, 30, ~3. 0) PXD( 7, 5,3, 0. 05%,200. 0, 1. 00%,?, T) Exp:HDB5US
TRIANGLE LABS Teit:M23-O-l TLJ#45399 ZK7. TIME = 07:46
100% . A4.}OZ3 A2.22E3
28':00 29:00 30:00
'ile:T9S1959 #1-720 Acq:18-APR-1998 07:45:55 EI+ Voltage SIR 70T Noise:69
341.8567 f;2 BSVB(256,30r-3.0) PKH(7,5, 3, 0. 05%, 276.0,1.00%, f,T) Exp:m)B5US
TRIANGLE LABS Text;M23-0-l TLI#4S399 JJffJ. TIME = 07:46
1004
80:
60:
40:
20:.
o:
28:00 29:00 30:00
File:T981959 #1-720 Acq:18-APR-1998 07:45:55 EI+ Voltage SIM 70T Noise:42
351.9000 f:2 BSVB(256,3Q,-3 .0 ) FKD( 7,5, 3, 0. 051,168. 0, 1. 00%, g, T) Exp:NDB5VS
TRIANGLE LABS Text:M23-O-l TLI#45399 DKT. TIME = 07:46
1004 A9.87E5
31 s 00
31:00
80;
60J
40:
20:
A9.18E5
\
1 1 1 1-———r—!—i *i*" i 1 [ I *l ^ i 1 p 1" I1 I—
28:00 29:00 30:00
File:T981959 #1-720 Acq:18-APR-1998 07:45:55 EH- Voltage SIR 70T Noise:46
353.8970 Fi2 BSUB(256,30,.-3.0) PKS(7,5,3, 0. 05%, 184 .0,1. 00%,F,T) Exp-.NSBSUS
TRIANGLE LABS Text-.M23-O.-1 .' TLI#45399 IKT. TIME = 07:
IOCS ' ' A6.$8£5
'. ' A6.45E5
ao:
60:
40:
20:
0 • ^
31:00
46
LL
28:00 . 29:00 30:00
File:T981959 #1-720 Acqtl'8-APX-1998 07:45:55 EI+ Voltage SIX 70T
330.9792 F-.2 Eip-.NDBSUS .
TRIANGLE LABS Text:M23-0-l' TLI#45399 INJ". TIME " 07
1003, 27:36 28:11 _ 28^41 29:10 _?9j33 _ 30:0530:20
Xjirf"""'1""1"'*'^
80J
60:
40:
20:
0.
-.00
-.46
30:47 31:08
28:00 29:00 30:00
File:T981959 #1-720 Aoqs 18-APR-1998 07:45:55 EX+ Voltage SIR 70T
409.7974 F:2 Exp:NDB5US
TRIANGLE LABS Text:M23-O-l TLI#45399 IKT. TIME
100*
31 a 00
07:46
80:
60:
40:
20:
ol
31:01
29:21
30:46
28:00
29s 00
.9.4E2
.7.5E2
.5. 6E2
.3.8E2
.1. 9E2
.O.OEO
Time
.3 . OE5
.2.4E5
.1. 8E5
.1.2E5
.6.0E4
.O.OEO
Time
.2.2E5
.1. 7E5
.1. 3E5
.8.6E4
4.3E4
30:00
31; 00
O.OEO
Tim i
,1. 3E6
.1.1E6
.8.1E5
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.2.7E5
. 0 , OEO
Time
.1. OE3
.8.1E2
.6.1E2
.4. 1E2
.2.0E2
.O.OEO
Time
190
-------
"Fil.e:T9"6l95$ tl-720 Acq:1S-APX-1998 OY:45:55 EI-f Voltage SIS 701 Noise:50
555.8545 F:2 BSUB(256, 30f-3.0) PKD{7, 5, 3, 0. 05%,200 . 0, 1. 00%,F,T) ExpiNDBSUS
TRIANGLE LASS Text:M23-O-l TLI#45399 lifj. TINE = 07:46
1004
80.
601
401
201
0. OEO
2Bs3s' 28:48' 25:00' 29:12' 29:24 ' 29: 3&' 29: 48 ' 30:00' 30:12' 30:24 ' 30: 36' 30:48' 31:bb' 31s 12' 31: 24 Time
F±letT981959 #1-720 Acq:lS-APR-1998 07:45:55 EH- Voltage SIS JOT Noiae:49
357.8516 F:2 BSUB(256, 30, -3. 0) PKB(7,5,3, 0 . 05%, 196. 0, 1. 00%,F, T) Exp-.NVSSUS
TRIANGLE LABS Text:M23-O-l TLI#45399 . XMT. TIME = 07:46
100%
I i ¥ r"i'"i i '!• {—c-f~j—r—r~r-i i'i t i""i r"i .ft—rT"T~i ! r1 r i i i ! i i i 'i t""f [ i i T—rT"r"r"r'T"T*"r"r"T"r"i"t't" | i t -r't i r r r i i i i i i rj 'i i""i i i i
28\36 28:48 29sOO 29:12, 29:24 29:36 29:48 30sOO 30:12 30:24 30:36 30:48 31:00 31:12 31:24 Time
F±le:T981959 #1-720 Acq: 18-APR-1998 07:45:55 EI+ Voltage SIX JOT Wolse.-51
367.8949 F:2 BSUB(256, 30r-3 . 0) PKE(7, 5, 3, 0. 05%, 204 . 0, 1. 00%,?, T) Exp:NDB5US
TRIANGLE LASS Text:M23-O-l TLI#45399 TJffiT. TIME " 07:46
1003k A6.36E5 _1, 9E5
,5.0E2
.3. 8E2
"-2.5E2
11.3E2
801
601
401
20.
6.5E2
"-5.2E2
-3.9E2
.2.6E2
-1.3E2
.O.OEO
a ol
601
40.
20.
7.23E4
_1.6E5
.1. 2E5
.7 .BE 4
_3.9E4
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28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00
File:T981959 #1-720 Acqtl8-APB-1998 07:45:55 EI+ Voltage SIX 701 No±se:49
369.8919 F:2 BSUB(256, 30,-3.0 ) PKS(7, 5,3, 0 . 05%, 196. 0, 1. 00%,F, T) Exp:NDB5US
TRIANGLE LASS Text:M23-O-l TLI#45399 ZMJ. TIMS = 07:46
1004 A4.23E5
80.
601
401
201
31: 24 Time
-1.3E5
-1.0E5
_ 7. 6E4
_5. 1E4
-2.5E4
4 .80E4
31 • 00
0 . OEO
31 :24 Tirae
28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 31
File:T9819S9 #1-720 Acq:18-APS-1998 07:45:55 EI+ Voltage SIS 70T
330.9792 T:2 Exp:NDB$US '
TRIANGLE LABS Text:M23-O-l TLI#45399 XNIT, TIME = 07:46
1003j 28:41 29:10 _ 29^3329^44 30:06 30:20 30^35 30_s47 31sQB 31,19 1.3E6
801
601
401
201
0.
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18.1E5
'.5,4ES
2.7E5
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28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00 31:12 31:24 Ziffle
1 Q7
-------
'±le:T981959 #1-425 Acq: 18-APR-1998 07:45:55 EI+ Voltage SIR 70T Noise:56
73.8208 F:3 BSUB(256 , 30,-3 .0 ) PKD( 7, 5,3, 0 . 05%,224 . 0, 1. 00%, F, T) Eip:NDB5US
TRIANGLE LABS Text:M23-O-l TLI#45399 JTJVJ. TIME = 07:46
1003
aol
60J
40J
20:
I i i i i i I L i i i i I i i L i i I i i i i i I i i i i i I i i i i i I i i i i i I i i i i i I i i i i i I i i i i i I i i i i i I i i i i i I i i ' i i I i i i
31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34:12 34:24 34:36
File:T981959 #1-425 Acq:18-APR-1998 07:45:55 EI+ Voltage SIR 70T Noise:52
375.8178 F:3 BSUB(256,30,-3.0) PKD( 7, 5, 3, 0 . 051,208. 0, 1. 00%,F, T) Exp:NDB5US
TSIANGLE LABS Teft:M23-O-l' TLI#45399 JTJVJ. TIME = 07:46
1003k / A1.62E3
aol
31-48' 32l-bo' 321:12' 32:24 32:36 32:48 33:00 33-12 33:24 33:36 33:48 34:00 34:12 34:24 34:36
File:T981959 #1-425 Acq:18-APR-1998 07:45:55 EI+ Voltage SIR 70T Noise:44
383.8639 F:3 BSUB(256r 30,-3 .0 ) PKD( 7, 5, 3, 0 . 05%, 176. 0, 1. 00%,F, T) Eip:NDB5US
TRIANGLE LABS Text:M23-0-l TLI#45399 INJ. TIME = 07:46
1003, A5.50E5 A5.75E5
A2.17E3
M.33E3
A834.39
6.5E2
.5. 2E2
-3.9E2
•.2.6E2
11. 3E2
34
•.O.OEO
48 Time
34
80:
60:
40:
20:
OJ
A4.40E5
O.OEO
48 Time
1. 8E5
.1. 4E5
Ll. 1E5
-7.1E4
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31-48 32:00 32:12 32:24 32:36 32:48 33:00 3.3:12 JJ.-24 33:36 33:48 34:00 34:12 34:24 34:36
File:T981959 #1-425 Acq: 1B-APR-1998 07:45:55 EI+ Voltage SIR 70T Noise:41
385.8610 F:3 BSUB(256, 30, -3 . 0; PKD( 7, 5,3, 0 . 05%, 164 . 0,1. 00%,F, T) Eip:NHB5US
TKIANGLE LABS Teit:M23-0-l TLI#45399 UfJ. TIME = 07:46
1004 • A1.12E6 A1.17E6
34
; O.OEO
48 Time
80J
60J
40J
20J
OJ
A8.89E5
^3.5E5
.2.8E5
-2.1E5
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Jll-48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34:12 34:24 34:36
File:T981959 #1-425 Acq: 1S-APR-199S 07:45:55 EI+ Voltage SIR 70T
392.9760 F:3 Exp:NDB5US
TSIANGLE LABS Teit:M23-0-l TLI#45399 INJ. TIME = 07:46
1_:51 32:14 32_:45 _33;11 33.-J4 33;53 .34:06
1003
80J
60:
40J
20:
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34
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_6.5E5
'-5.2E5
_3. 9E5
.2. 6E5
-1.3E5
31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34:12 34:24 34:36
File:T981959 #1-425 Acq:18-APR-1998 07:45:55 EI+ Voltage SIR 70T
445.7555 F-.3 Eip:NDB5US
TRIANGLE LABS Telt:M23-O-l TLI#45399 JJW. TIME = 07:46
32:40 33:54 ,
34 :26
O.OEO
:48 Time
31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34:12 34:24 34:36 34
O.OEO
48 Tim
-------
"flle:T$'6T55$ #1-435 AcqslS-APS-1998 07:45:55 EH- Voltage SIS 70T Noise:45
389.8156 F:3 BSUB(256,30,-3.0 ) PKD(7, 5, 3, 0. 05%, 180. 0,1, 00%,F, T) ExpsNDBSVS
TRIANGLE LABS Teit:M23-O-l TLI#45399 INJ. TIME = 07:46
32:24 32':36 32:48 33:00 33:12 33:24 33:36 33:48 34:00
FilesT981959 #1-425 Acq:18-APK-1998 07:45:55 EH- Voltage SIS 70T Noise:60
391.8127 F:3 BSUB(256, 30,-3 .0) PKD( 7, 5,3, 0. 051,240. 0, 1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Text:M23-O-l' TLH45399 JMJ. TIMS = 07:46
100% A1.J.2S3
Al.12S3
32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00
Tile:T981959 #1-425 Acg:18-APR-1998 07:45:55 EI+ Voltage SIS 70T Noise:71
401.8558 Fs3 BSUB(256,30,-3 .0) PXD(7, 5,3, 0. 05%,284, 0,1.00%,Jf, T) ExpsNDBSUS
TRIANGLE LABS Text:M23-O-l TLI#45399 INJ. TIME - 07:46
1004
. 6E3
34:12
-O.OEO
34124 Etste
34:12
34:24
O.OEO
Time
003
so:
eo:
40:
20:
0'
A1.S7E6
l\
A7.18E5 \
A A
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32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34:12 34:2
5.7E5
'.4.6E5
-3.4E5
.2.3E5
LI . 1E5
' 0 . OEO
4 Time
F±le:T9B1959 #1-425 Ac
-------
F±le:T981959 #1-629 Acq:18-APR-1998 07:45:55 EI+ Voltage SIR 70T Noise:47
07.7818 F:4 BSUB(256,30, -3 . 0) PKD( 7, 5,3, 0 . 05%,188. 0, 1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Text:M23-O-l TLI#45399 INJ. TIME = 07:46
1003, A2.68E3
35':48 36:00 36':12 36:24 36:36 36:48 37:00 37:12
•ile:T981959 #1-629 Acq:18-APR-1998 07:45:55 EI+ Voltage SIR 70TNoise:42
409.7789 F:4 BSUB(256,30,-3.0) PKD(7, 5, 3, 0 . 05%, 168. 0, 1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Text:M23-O-l TLI#45399 INJ. TIME= 07:46
1003, A912.49
35:48 36:00 36:12 36':24 36:36 36:48 37:00 37': 12 37:24
File:T981959 #1-629 Acq:18-APR-1998 07:45:55 EI+ Voltage SIR 70T Noise:53
417.3253 F:4 BSUB(256, 30,-3 .0 ) PKD( 7, 5,3, 0. 051,212. 0, 1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Text:M23-0-l TLI#45399 INJ. TIME = 07:46
37:24
37:36
801
60J
401
201
A1.29E3
T
T
~T
T
37:36
.O.OEO
37:48 Time
,.3 . 9E2
L3.2E2
L2.4E2
'•LI. 6E2
L 7. 9E1
•.O.OEO
Time
37:48
003:
a oi
601
401
201
A2.70E5
n
A
*/r
/ V /V
35:48 35:00 J6.-12 36:24 J6.-36 36:48 J7.-00 37:12 37:24 37:36 37:4
-7.6E4
'-6.1E4
'•L.4.6E4
'.3.0E4
'.1.5E4
•.O.OEO
8 Time
File:T981959 #1-629 Acq:18-APR-1998 07:45:55 EI+ Voltage SIR 70T Noise:58
419.8220 F:4 BSUB( 256, 30,-3 .0 ) PKD( 7, 5, 3, 0 . 051,232. 0, 1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Text:M23-O-l TLI#45399 INJ. TIME = 07:46
003
a 01
601
401
201
01
A«.«E5
A • •
1 \ ' A3.86E5
A
!v /V
i . 7r5
.1.3Z5
.1 . or5
_6.6r4
13.3E4
0 . OEO
35:48 36.-00 36:12 36.-24 36.' 36 361-48 37.-00 37.-12 37.-24 371-36 371-48 Time
File:T981959 #1-629 Acq:18-APR-1998 07:45:55 EI+ Voltage SIR 70T
430.9729 F:4 Ejcp:NDB5US
TRIANGLE LABS Text:M23-0-l TLI#45399 INJ. TIME = 07:46
UU3
801
40:
201
0"
JO^UO Ji-ii Jo:^y JQJ^J/ _jo:3j J/.-06 J/:±3 37:23 J/: JU J/:9±
-
35:48 36:00 .36:12 36:24 36:36 J6.-48 37:00 37:12 37:24 37:36 37:4
_4 . JE3
L3.4E5
.1 . 7E5
.8.6E4
O.OEO
8 Ti
File:T981959 #1-629 Acq:18-APR-1998 07:45:55 EI+ Voltage SIR 70T
479.7165 F:4 Ejcp:NOB5US
TRIANGLE LABS Text:M23-O-l TLI#45399 INJ. TIME
100*
07:46
801
601
401
201
01
36:02
36:48
35:47
_S. OE2
'-7.2E2
'-5.4E2
-3. 6E2
r.1 . 8E2
35:48
36:00
36:12
36:24
36:36
36:48
37:00
37177
37:24
37:36
.O.OEO
37': 48 Time
2,10
-------
File:T9t>1959 #1-629 Acq:18-APR-l99a 07:45:55 EI+ Voltage SIR 70T Noise:40
423.7766 F:4 BSUB(256, 30,-3. 0 ) PKD(7, 5, 3, 0 . 05%, 160 . 0, 1. 00%,F, T) Exp:NDS5US
TRIANGLE LABS Text:M23-O-l TLI#45399 INJ. TIME = 07:46
1003,
I i i i i i I i i i i i i I i i i i i I i i i i i I i i i i i i I i i i i i I | i i i i i | i i i i i I i i i i i I
36:00 36:06 36:12 36:18 36:24 36:30 36:36 36:42 36:48 36:54 37:00 37:06 37:12 37:18
File:T981959 #1-629 Acq:18-APR-1998 07:45:55 EI+ Voltage SIR 70T Noise:39
425.7737 F:4 BSUB(256, 30,-3 .0 ) PKD(7, 5,3, 0 . 05%, 156. 0, 1. 00%,f, T) Exp:NDB5US
TRIANGLE LABS Text:M23-O-l TLI#45399 INJ. TIME = 07:46
100$ A1.27E3 A494.23
O.OEO
Time
^3.5E2
36':00 36:06 36:12 36': 18 36':24 36:30 36:36 36:42 36:48 36:54 37:00 37:06 37:12 37:18
F±le:T981959 #1-629 Acq:18-APR-1998 07:45:55 EI+ Voltage SIR 70T Noise:45
435.8169 F:4 BSUB(256, 30,-3 . 0) PKD(7, 5,3, 0 . 05%, 180 . 0, 1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Text:M23-O-l TLI#45399 INJ. TIME = 07:46
100$ A4.30E5
40.
20:
36:00 36:06 36:12 36:18 36:24 36:30 36:36 36:42 36:48 36:54 37:00
File:T981959 #1-629 Acq:18-APR-1998 07:45:55 EI+ Voltage SIR 70T Noise:47
437.8140 F:4 BSUB(256, 30,-3 .0 ) PKD(7, 5, 3, 0 . 05%,188. 0, 1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Text:M23-O-l TLIX45399 INJ~. TIME = 07:46
1003, A4.17E5
eo:
60:
40.
20.
37:06 37:12 37:18
36:00 36:06 36:12 36:18 36:24 36:30 36:36 36:42 36:48 36:54 37:00 37:06 37:12 37:18
File:T981959 #1-629 Acq:18-APR-1998 07:45:55 EI+ Voltage SIR 70T
430.9729 F:4 Exp:NDB5US
TRIANGLE LABS Text:M23-O-l TLI#45399 INJ'. TIME = 07:46
1003, __ 36^06 36:18 36:29 36:37 36:43 36:53 37:06 37:15
so:
60.
40:
20J
0.
36:00 36:06 36:12 36:18 36:24 36:30 36:36 36:42 36:48 36:54 37:00 37:06 37:12 37:18
9 . 8E4
7. 9E4
5.9E4
3.9E4
.2.0E4
.O.OEO
Time
.9.8E4
.7.8E4
.5.9E4
.3.9E4
.2.0E4
.O.OEO
Time
.4.3E5
.3.4E5
.2.6E5
.1. 7E5
.8.6E4
.O.OEO
Time
201
-------
File:T98195S #1-629 Acq:18-APR-1998 07:45:55 EH- Voltage SIS 70T Noise:43
441.7428 F:4 BSUB(256,30f-3.0) PKD( 7, 5, 3, 0. 05%, 172. 0, 1 . 00%,F, T) Eip:NDB5US
TRIANGLE L&BS Text:M23-0-l" 2U #45399 TOT, TIME - 07:46
1004 ' • -2.2E4
901
801
701 ' ;
601
501
401
301
201
101
n:Tn,,, I,,!,,, ,,,,,-r -- - -, d|T '. ,L,— j— f—p,.,,- ,r- ->,, i-...
36:00 ' ' 37:00 ' ' ' 38:00 ' 39:00 40:00 41:00 42:00
file :T9 81959 41-629 Acq:18-APS-1998 07:45:55 EI+ Voltage SIR 70T Noise:45
443.7399 F.-4 BSUB(256,30,-3.0) PKS( 7,5,3, 0. 05%, 180. 0,1 . 00%, F, T) SxpsSDBSOS
TRIANGLE LABS Text:M23-O-l TLIH5399 IKJ. TIME = 07:46
1004
901
a 01
701
601
501
401
301
201
36:00 ' 37:00 ' ' ' 38:00 ' 39:00
File:T981959 #1-629 Acq:18-APR-1998 07:45:55 EI+ Voltage
430.9729 F:4 Exp-.NDSSVS
TRIANGLE LABS Text:M23-O-l TLI#45399
^^f^^^^^J^^^l^ 3?:15 38:°° 3B"'44 39
801
701
601
soi
401
301
201
101
0
36-00 37:00 38:00 39:00
F±le:TS81959 #1-629 acg:18-APK-1998 07:45:55 EH- Voltage
513.6775 F:4 Eip:NDB5US
TRIANGLE LABS Teit:M23-0-l . TLI#45399
1003
90j
80J
70J
60J
501
401
301
20--. 35:55 36:47 37:2° 58VI5 38:53
1 0 J WVM^jtt^jtfy^^dj**^^
0
36:00 ' ' ' 37:00 ' ' ' 38.-00 ' ' ' 39:00
40\00 ' ' 4ll-00 ' ' 42:00
SIR 70T
IKT. TIME = 07:46
40:00 ' ' ' il-00 ' ' ' 42i" 00
SIR 70T
IKT. TIME « 07:46
4Q[°l 40:40 41:28 42:13
'*~«^^»^W1«K^wAwl-^^v^u^^
40:00 41:00 42:00
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-1 . 5J-T4
.1.3E4
-1.1E4
.8.6E3
.6.5E3
"-4.3S3
"-2.2E3
O.OEO
Time
_1 . 6E4
L1.5E4
L1.3E4
"-1.1E4
L9.8E3
L8.1E3
L6.5E3
L4.SE3
L3 . 3E3
- 0 . OEO
Time
L3 . 9£5
L3.5£5
L3 . QE5
-.2.6E5
12.2E5
Ll . 7Z5
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L8.7E4
14.3E4
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Time
4.5E3
'.4.0E3
13.6E3
13 . 1S3
L2.7E3
L2.2E3
Ll . 8E3
Ll . 3£3
L8.9£2
: 0 . OJEO
Time
202
-------
File:T9Sl959 #1-529 Acq:18-APX-1998 07:45:55 EI+ Voltage SIS 70T S6ise:37
457.7377 F:4 BSUB(256, 30, -3 . 0) PKD(7, 5, 3, 0. 05%,148, 0, 1. 00%,F, T) Elp:NDB5US
TRIANGLE LABS Text:M23-O-l' TLH45399 INjr. TIME = 07:46
1004 A1.35E3
801
60.
401
201
40:18 40:24 40:30 40:36 40:42
F±le:T981959 #1-629 Acq:lS-APS-1998 07:45:55 EI+ Voltage SIS JOT Noise:35
459.7348 Fs4 B3aS(256,30,-3.0) PKD( 7,5,3, 0.05%, 140. 0, 1,00%,F,T) Exp:NDB5US
TRIANGLE LABS Text:M23-O-l TLI#45399 INJ". TIME - 07:46
1004 A1.41E3
801
601
401
201
A490.23
01
40:48
A445.73
40tl8 40:24 40:30 40:36 40:42
File.-2*581555 #1-629 Acq:18-APR-1998 07:45:55 EI+ Foltajre SIS 70T No±se:41
469.7779 Fs4 BSUB(256,30, -3 . 0) PKD(7, 5, 3, 0. 05%, 164, 0, 1. 00%,F» I) ExpsKOBSUS
TRIANGLE LABS TextsM23-O-l TLI#45399 INJ. TIME = 07:46
1004 A3.40E5
801
601
401
201
40:48
40tl8 40:24 40:30 40:36 40:42
File:T981959 #1-629 Acq:18-APR-1998 07:45:55 EI+ Voltage SIR 70T Noise:38
471.7750 Fi4 BSUB( 256, 30,-3. 0) PKO( 7, 5, 3, 0. 05%, 152. 0, 1. 00%,F, T) Exp:MDB5US
TSIANGLE LABS Text:M23-O-l TLI#45399 INJ". TIME = 07:46
1004 A3^9JE5
80.
601
401
201
40:48
40:42
40:16 • 40:24 40:30 40:36
File.-TS81.9S3 #1-629 Acqil8-APR-1998 07:45:55 EI+ Voltage SIR 70T
430.9729 Fs4 Exp;M>B5US
TRIANGLE LABS Teit:M23-O-l TLH45399 INJ". TIME = 07:46
100% ~__ 40:21 40:35 40:45
801
601
401
201
01
40:48
40:18
40:24
40:30
40:36
40:42
40:48
-4.4E2
.3. 5E2
.2.6E2
.1. 7E2
.8.7E1
.O.OEO
Time
.4.9E2
.3. 9E2
.2.9E2
.1.9E2
.9. 7E1
.O.OEO
Time
.S.3E4
.5. 1E4
.3. 8E4
.2.5E4
.1.3E4
.O.OEO
Time
.7.0E4
.5.6E4
.4.2E4
.2.8E4
.1. 4E4
.O.OEO
Time
.4.3SS
.3. 4E5
.2.6E5
.1. 7E5
.S.5S4
.O.OEO
Time
203
-------
told. I 3$,3792 Ptaktop
Height ,70 volts Span 2ippi
file nm
Data fill nans
Rtsdution
Groupnuater
Imiiatlon node
Snitching
Rfef, lasses £92,3825,
R 233 j 331
K 332
L 334
I 348
H 342
0 352
P 354
Q 356
tef.'iass 416,97i Puictop
.17 volts Span iip
1^9
2
H*
VOlTfiGE
416,9768
S 368
T 371
y 378
V 418
204
-------
fct*
CL
C.'
File:T981959 #1-720 Acq:18-APR-1998 07:45:55 EI+ Voltage SIR 70T
319.8965 F:2 Exp:NDB5US
Sample Text:M23-0-l TLI#45399
100%
60 j
40J
20 j
OJ
INJ. TIME = 07:46 File Text:M23
25;53 26:12 1
2b '. 66
0-1 TLI#»
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L4.0E2
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LO.OEO
24:00 • 25:00 26:00
File:T981959 #1-720 Acq:18-APR-1998 07:45:55 EI+ Voltage SIR 70T
321.8936 F:2 Exp:NDB5US
Sample Text:M23-0-l TLI#45399 INJ. TIME =
10 OS, AK 24:54
... .4:02 , [\ ^\^ 25:56
80.
07:46 File
26:18
27:00 Time
Text:M23-O-l TLI#»
_8.3E2
24:00 25:00 26:00
File:T981959 #1-720 Acq:18-APR-1998 07:45:55 EI+ Voltage SIR 70T
331.9368 F:2 Exp:NDB5US
Sample Text:M23-O-l TLI#45399 . •—-c LO - ; :.:: ;t<.l-NJ. TIME =
100% • :- 25; 56
80J
60 j
40 j
20 j
0.
O.OEO
27:00 Time
07:46 File Text :M23-0;-1-:-KTLI#»
6.1E5
U.9E5
24:00
25:00
26:00
i.2. 4E5
L1.2E5
LO.OEO
27:00 Time
-------
File:T981959 #1-720 Acq:18-APR-1998 07:45:55 EH- Voltage SIR 70T
303.9016 F:2 Exp:NDB5US
Sample Text:M23-0-l TLI#45399 INJ. TIME = 07:46 File Text:M23-O-l
100%, A4.89E3 _2
80 j
60J
OJ
L1
L1
L8
L4
F n
26:00
26:12
26:24
24:24 24:36 24:48 25:00 25:12 25:24 25:36 25:48
File:T981959 #1-720 Acq:18-APR-1998 07:45:55 EI+ Voltage SIR 70T
305.8987 F:2 Exp:NDB5US
Sample Text:M23-O-l TLI#45399 INJ. TIME = 07:46 File Text:M23-0-l
100% A8.32E3 2
i2.
1,
Ll.
is.
0,
40j
20 J
OJ
|
T 1 T""~T T~
25:36
~I
. . . I
26:00
TLI#»
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.6E2
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6E3
0E3
5E3
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26:12
24i24 24-136 24:48 25:00 25:12 25:24 25:36 25:48
File:T981959 #1-720 Acq:18-APR-1998 07:45:55 EI+ Voltage SIR 70T
315.9419 F:2 Exp:NDB5US
Sample Text:M23-O-l TLI#45399 INJ. TIME = 07:46 File Text;
100% 25;23
80 J
601
20 J
..
26:24
OJ
M23-O-l
1
Ll
Ll
L7
L3.
LO
24:24
24:36
24:48
25:00
25:12
25:24
25:36
25:48
26:00
26:12
26:24
Time
TLI#»
,9E5
5E5
1E5
5E4
8E4
OEO
Time
-------
Rtf , lass Peak top
Help]* ,18 volts Span 286 ppi
Systti file m& OB22S
Ma fits naie fl!P981389
Resolution 188%
Group note1 i
loniiation Nde El*
VOLTAGE
388, 97$ 1
338.9792
333,3338
ief, issse
J
K
L
1
B 292.S
e
0
E 317,9389
F
G 321,8936
H 317,8847
I 338,9792
Channel I 338,9792 Peak top
Mght ,21 wits Span 288 ppi
207
-------
TLI Project: 45399
Client Sample: M23-O-1
Method 23 TCDD/TCDF Analysis (DB-225)
Analysis File: P981310
Client Project:
Sample Matrix:
TLI ID:
r012.0Q2/Lime Kiln
M23 Date Received: 04/01/98
204-92-5A-D Date Extracted: 04/03/98
Date Analyzed: 04/16/98
Spike File: SPC2NF04
ICal: PF24098
ConCal: P981302
Sample Size:
Dry Weight:
GC Column:
1.000
n/a
DB-225
Dilution Factor: n/a
Blank File: U980780
Analyst: ML
% Moisture: n/a
% Lipid: n/a
% Solids: n/a
2,3,7,8-TCDF
ND
0.01
l3Ci2-2,3,7,8-TCDF
0.86
21.4
40%-130%
0.76
22:24
»Ci2-l,2,3,4-TCDD
0.80
21:18
Data Reviewer:
Page 1 of 1
04/20/98
C2NF.PSR V2.02, LARS 6.11.00
Triangle Laboratories, Inc.®
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 21:28 04/20/98
208
-------
Initial
,,.Date,.
Data Review By;
Calculated Noise Area:
0.13
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No,
04/20/98
Listing of F9S1310B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit: Why ,,RT. OK Ratio Total. Area... Area. Peak. 1. . Area.Peak.2.. Rel.RT Compound. Name,. ID.
Flags.
TCDF
304-306
304-306
13C12-TCDF
316-318
O.S5-0.89
316-318
13C12-TCDD
332-334
332-334
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
0
NL
WL
WL
SN
SN
WH
WH
WH
WH
1
NL
3
Oi
19:
20;
21:
21:
00
:07
:02
01
:16
SO
RO
RO
RO
1.
0.
0.
0.
0.
00
78
60
64
56
Peaks
0:
20:
21:
21:
22:
23:
23:
24:
24:
24;
00
59
:14
31
24
;07
:45
;05
;26
;50
0.
RO
RO
RO
RO
RO
RO
65-0.89
1.
1.
0.
1.
0.
1.
0.
1.
0.
0.
00
06
33
00
76
07
67
33
93
75
Peak
0;
21:
21:
22;
:00
:01
;18
:02
0.
RO
RO
65-0.89
1.
0.
0.
0.
25
81
80
64
Peaks
0.14
0.16
0.21
0.21
0.11
0.00
0.16
0.30
0.99
0.05
96.68 41.87
0.25
o.os
0.05
1.86
0.07
96.68
TCDF / TCDD Follows -
0.14
74.07
336.38
0.53
410.98
33.25
149.33
0.23
0.790-1.102
0.000
0.853
0.894
0.938
0.949
0.955-1.045
Q.OOO
. 0.937
0.948
0.961
54,81 1.000 13C12-2378-TCDF ISO
1.032
1.060
1.075
1.091
1.109
0.905-1.095
0.000
40.82 1.000 13C12-2378-TC0D IS1
187.05 1.013 13C12-1234-TCDD RSI
0.36 1.048
Column Description "Why" Coda Description OC Log Desc.
M_Z -Nominal Ion Mass(es)
. ,RT. -Retention Time (inm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Eelative Retention Time
»** End of Report **»
WL-Below Retention Time Window
WH-Above Retention Tiros Window
SH-Below Signal to Noise Level
-------
'Flle-.PSaaiO #1-1666 Acq:l6-APS-l99d SOsfffTSV"EI+ Voltage SIS 70P
303.9016 Eip:DS225
TRIANGLE LABS Text.:M23-0-l TLI#45399
1003.,
21:00 21:12 21J24 21s36 21.-48 22««0 22.-12 22:24 22:35 22:48 23.-00 23:12 23:24
Filesf981310 #1-1006 Acqsl6-APS-lS98 20s38s38 Eli- Voltage SIS 70F
315.9419 Ezp:DS225
TRIANGLE LASS Tezt:M23-0-l 1X1*45399
1003
95:
90:
85:
80:
60:
55:
50:
45:
35:
101
22:24
24
LO.OEO
00 Time
_1. 1H5
.1. OE5
.9. 6E4
-9.1E4
-8.5E4
.8.0E4
.7.5E4
-6.9E4
.6.4E4
-5.9E4
15. 3E4
-4.8E4
'.4.3E4
.3. 7E4
_3.2£4
":2,7E4
'-.2.1E4
;1. 6E4
.1.1E4
15.3E3
21-00
' ' I ' ' ' t ' I r""r""r i"i i i i t i i | j i i i i i i i i i i i i i i i i | j i i t i i i i j i i i i i T i i i i i i i i i j i j i i i i i i i i i i i i
21:24 21:36 21:48 22:00 22:12 22:24 22:36 22:48 23:00 23:12 23:24 23:35 23.-48
24
O.OEO
00 Time
210
-------
#1-100V AcqtlS-APX-199'8 2fl.-Jfl.-ja EI+ voltage SIR 7'OP NoTse:~3V"
303,9016 BSUB(256,30,-3.0) PKD(5,3,1, 0.101,152. 0, 0. 00%,T,F) Exp:DB225
TRIANGLE LABS TexttM23-O-l TLHf45399
100$
8 01
601
401
201
18:00 19:00 20:00 21:00 22:00 23:00
File:P981310 #1-1006 Acq:16-AfS-1998 20:38:38 EI+ Voltage SIS 70P Koiaes39
305.8987 BSUB(256,30,~3.Q) PXD(5, 3,1, 0.101,156.0, 0. 00*,F,F) Exp:DB225
TRIRSSLE LABS TextsM23-O-l TZI#45399
100* A888.14
24! 00
18:00 19tOO 20:00 21:00 22:00 23:00
FilesP981310 #1-1006 Acq;16-ATS-1998 20:38:38 EH- Vtoltagre SIS 70P !Toise:43
315.9419 BSUB(256,30,-3.0) PKD(5,3,1,0.10%,172.0,0.QO*,F,F) ExpsDB225
TRISSGLE IABS Text.itf23-O-l ZLX#45399
1004 A4.J.9E5
801
601
401
201
24:00
18:00 19:00 20:00 21:00 22:00 23:00
FilesP9S1310 #1-1006 Acgsl6-AfS-1998 20:38:38 EI+ Voltage SIS 70P Noia«s44
317.9389 SSOB(256,30r-3,0) PXD(5,3,lr0.10%,176.0,0.00*,FrF) Exp:I>B22S
TRIANGLE LABS TextsM23-O-l TLX#45399
1004 A5.48E5
801
601
40.
201
24:00
18:00 19:00 20:00 21:00 22:00 23:00
File:P981310 #1-1006 Acqsl6+APX-199B 20:38:38 EX+ Voltage SIS 70S
375.8364 Exp:DB22S
TRIANGLE LABS Text.:l€23-O-l XLX645399
100*17 55
24:00
O.QEO
25iOO
25 .-00 Time
-l.lfS
".8.5E4
-6.4E4
.4.2E4
.-2.1E4
25:
0.0EO
00 Tixe
-1.4S5
-1.1E5
.8.4E4
-5.6E4
.2.8E4
25:
O.OEO
00 Time
18:00
19:00
20:00
21:00
22:00
23 • 00
24:00
25:(
211
-------
'File:P981310 $1-1006 Acq:lS-APS-lSSa 20:36:38 EI+ Voltage SIR 70P Noise:35
319.8965 BStm(256,30,-3.0) PKD(5,3,lr 0.10^,140.0,0. 00%,F,F) Elp:DB225
TSIANGLM LABS TejctsM23-0-l TLI#45399
100S
19-00 20:00 21:00 22s00 23:00
File:P981310 #1-1006 Acqil6~APM-199S 20:38:38 EX+ Voltage SIS 70P Noise:38
321.893S BSm(256,3Qr-3.0) PKD(5,3,1,0.10^,152.0,0.00\,F,F) ExpsDB225
TRIANGLE LABS Text:M23-O-l TLH45399
1004
24 100
137.41 A376.35 A299.2
19:00 20:00 21:00 22s00 23:00
r±le:P9ai310 01-1006 Acqsl6-APX-1998 20:38:38 EI+ Voltage SIM 70P Noise: 42
327.8847 SSVS(256r30,-3.Q) PXD(5,3,1,0.101,168.0,0,00*,F,f) Sxp:DB225
TRIANGLE LABS TextlM23-0-l TLH45399
1003, A7.82E5
80.
60.
40.
20.
OJ
: 13.-00 20.-00 21sOO 22:00 23:00
File:P9S1310 #1-1006 Acq:16rAPS-1998 20:38:38 Eli- Voltage SIS 70P SOise:50
331.9368 BSUB(256,30,-3.0) PKD(5,3,1,0.101,200.0,0. 00%,F,F> Exp:DB225
ZRIANGLE LABS Text:M23-O-l TLH45399
1001 A1.49E6
801
so:
401
20:
0.
A3.32E51
A
IStOO 20.-00 21:00 22:00 23:00
FilesP981310 #1-1006 Acqsl6-APS-199S 20:38:38 EX+ Voltage SIS 70P Soiae}38
333.9338 BSOB(256,30, -3.0} PKD(5,3,lf0.10\,152.Q,Q.OO*,F,T) Exp:SS225
TSIA8GLE LABS Text.sH23-O-l TLI#45399
1004 A1.87E6
80.
60.
40.
20.
0.
A4.08E5]
19:00
20:00
21:00
221 00
23:00
24:00
24 : 00
24 : 00
.2.2E5
.1. 8E5
.1.3E5
.8.8E4
.4. 4E4
.O.OEO
Time
.4.3ES
.3.4E5
.2.6E5
.1. 7E5
.8.6E4
.O.OEO
Time
.5.2E5
.4.1E5
.3.1E5
.2.1E5
.1. OE5
24100
O.OEO
Time
212
-------
F±le:P981310 #1-1006 Acq:16-AfS-1998 20:38:38 EI+ Voltage SZR 70P
303.9016 Exp:DB22S
TRIANGLE LABS TexttM23-O-l TLI#45399
100% 19:07 „.„ „_
80j. 'I • ia.ii l> . ll I i .1 fl . (\, . M ., *!.-••'•' 22:3923:05 '
60:
401
20:
ol
IS:00 19:00 20:00 21:00 22:00 23:00
File:PS81310 #1-1006 Acef:16-APB-lSS8 20:38:38 EI+ Voltage SIR 70P
315.9419 Sxp:DB22S
TRIANGLE LABS Text:M23-O-1 TZIt45399
1001
QJ
Filet :P9 81310 #1-1006 Acq:16-APS-1998 20:38:38 EI+ Voltage SIS 70P
319.8965 Exp:DS225
TRIANGLE LABS Bajtt.'MSJ-O-l ZEI#45JSS
24:20
9, OE2
•-7.2E2
'.5.4E2
L3.6X2
"'.1.8E2
24 i 00
25-.
'.O.OEO
00 Time
22:24
II
18:00 ISsOO J0;00 ill 00 iaioO 23.-00 24:00 25:
-1.1ES
.8.5E4
-6.4E4
-4.3E4
.2.1E4
O.OEO
00 Time
18:00 19:00 i 20tOO 21:00 22:00 23:00
T±l«tP981310 #1-1006 Acq:16-APR-1998 20:38:38 EI+ Voltage SIR 70P
331.9368 E*psDB225
TRIANGLE LABS TeJCt:H2J~O-li TLH45399
24:00
25:
10 OS,
21.-18
«'
18:00 19:00 20:00 21:00 22:00 23:00 24:00 25:
'•.3.4E5
.2.6E5
-1.7E5
.8.6E4
.O.OEO
00 T±m
r±le:P981310 #1-1006 Acq: 16-APS-1998 20:38i38 EI+ Voltage SIR 70P
292.9825 Exp:DS225
TRIANGLE LABS T®xt:M23-O-l TZH45399
JLJj23 20:16 _ _ 21:03 22:23 22:_52 23:28
.24: 02 24:2_8 _9. 7E5
-7.8E5
18:00 19:00 v 20:00 21:00 22:00 2J.-00
P581J10 #1-1006 Acq:16-APS~1998 20:38:38 EI+ Voltage SIR 70P
330.9792 SxpsDB225
TRIANGLE LABS Text.:M23-O-l TL1#45399
1003, 18:3619:0319:29 20:16 21:04 22i3£. ^23:27
^f^*J^JY^Ir\
80:
601
40":
20:
0:
24:00
25:00 Ziiae
2.JJ5T5
O.OEO
13:00
19:00
20:00
21: 00
22s 00
23100
24:00
25s 00 Time
-------
Ref, lass 292,9825 Peak top
Height .15 wits Span 298 pp*
Systei flit nan
Data fllenae
itsaliiun
loniion lode
Switching
lasses
fl 292.9825
I 383.9816
C 385 t 8987
0 315.9419
I 317,339
319,3985
6 321,8338
H 327,8847
I 330,9792
fl'P88l3l8
'}
J
K
L
1
1
El*
VOLM
388,3761
31.9792
331,9368
375,8364
I 338.9732 Piaktop
,19ggUs Span 2ippi
214
-------
Services
TLI Project:
Client Sample:
45399
M23-O-2
Method 23 PCDD/PCDF Analysis (a)
Analysis File: T981960
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
r012.002/Lime
M23
204-92-6A-D
1.000
n/a
DB-5
Kiln
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
" Blank File:
Analyst:
04/01/98
04/03/98
04/18/98
n/a
U980780
HLM
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPMIT204
TF51308
T981946
n/a
n/a
n/a
Analytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
Totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Amt (ng)
ND
ND
ND
ND
ND
0.01
EMPC
0.03
ND
ND
ND
ND
ND
ND
EMPC
ND
ND
Arat >(ng)
0.08
0.03
ND
0.01
0.25
0.02
EMPC
EMPC
DL £MPC
0.006
0.009
0.01
0.01
0.01
0.03
0.006
0.006
0.008
0.007
0.009
0.01
0.01
0.02
0.03
Number Dt EMPC
2 0.11
2
0.01
1
9 0.28
1 0.04
0.007
0.01
Ratio RT Flags
1.04 36:49 J_
JB_
0.76 25:25 B_
H
Flags
—
Page 1 of 2
MIT2_PSR vl.04. LARS 6.11.00
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:4004/20/98
-------
TLI Project: 45399
Client Sample: M23-O-2
Method 23 PCDD/PCDF Analysis (a)
Analysis File: T981960
13C!2-2,3J,8-TCDF
13C!2-2,3J,8-TCDD
13Ci2-l,2,3,7,8-PeCDF
13Ci2-l,2,3,7»8-PeCDD
l3Ci2-l,2,3,6,7,8-HxCDF
13Ci2-l,2,3,6J,8-HxCDD
13C,2-l,2,3,4,6,7,8-HpCDF
13C,2-l,2,3,4,6»7,8-HpCDD
!3Ci2-l,2,3,4,6,7,8,9-OCDD
2,3
2.2
2.2
2.5
3.0
2.9
2.7
3.1
3.8
57.4
54.3
54.4
62.6
74.0
71.9
67.7
77.0
47.7
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
0.74
0.80
1.41
1.49
0.51
1.21
0.44
1.05
0.87
25:23
26:07
29:23
30:26
32:58
33:38
35:47
36:49
40:21
13C,2-2,3,4,7,8-PeCDF
13e,2-l,2,3,4J,8-HxCDF
13C,2-l,2,3,4,7,8-HxCDD
l3e,2-l,2,3,4,7,8,9-HPCDF
4.0
3.6
3.8
3.3
98.8
91.0
95.9
82.2
40%-130%
40%-130%
40%-130%
25%-130%
1.41
0.50
1.22
0.42
30:06
32:52
33:33
37:18
37CL,-2,3,7,8-TCDD
3.5
87.1
40%-130%
26:08
lllS^ig^^w^Wii^llii^^i^ftilliB^
SilSSsSgSSj^
'3Ci2-l,2,3,7,8,9-HxCDF
l3e,2-2,3,4,6,7,8-HxCDF
2.7
2.9
66.8
73.2
40%-130%
40%-13Q%
0.50
0.51
34:11
33:26
13Cr_-l,2,3,4-TCDD
13C12-l,2,3,7,8,9-HxCDD
0.82
1.21
25:56
33:56
Data Reviewer
04/20/98
Page 2 of 2
vi,«, LARS s.i i .00
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:40 04/20/98
O1
-------
Data Review By;
..,.Date..*
Calculated Noise Area:
0.25
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
04/20/98
Listing of T98196QB.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why .,RT. OK Ratio Total.Area.., Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
M
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
320-322
37C1-TCDD
328
0.
DC NL 0:00
22:09
22:41 RO
22:56 RO
23:20
23:40
24:05
24:21
24:46
24:59
25:14
25:25
25:51 RO
26:05 RO
13 Peaks
0.
DC NL 0:00 RO
DC WL 24:20
24:58
25:23
25:50 RO
3 Peaks
0.
DC NL 0:00 RO
23:32
23:56 RO
DC SN 24:14 RO
24:57
DC SN 25:39 RO
DC SN 25:51 RO
26:03 RO
DC SN 26:08 RO
4 Peaks
DC NL 0:00
24:45
26:08
26:31
65-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
65-
1.
0.
0.
0.
0.
0.89
72
79
55
97
87
84
78
86
68
88
75
76
90
95
0.89
18
74
79
74
50
.65-0.89
1.
0.
0.
0.
0.
3.
0,
1,
00
81
90
55
.72
.71
.44
.51
0.30
0.868-1.077
0.31
2.33
1.06
1.31
6.59
4.32
3.68
3.48
4.25
2.25
1.33
4.68
1.84
0.99
38.11
1.
0.
0.
3.
1.
1.
1.
1.
1.
0.
2.
0.
0.
03
46
72
07
97
61
61
72
05
57
02
94
.53
1.
0.
0.
3.
2.
2.
1.
2.
1.
0.
2.
1.
0.
30
83
74
52
35
07
87
53
.20
.76
,66
,04
,56
0
0
0
0
0
0
0
0
0
0
0
1
1
1
0.961
0.30
5.87
2.42
439.62
1,82
443,86
0.19
6.56
2.39
0.25
1.72
0.12
0.09
0.76
0.21
11.43
0.12
2.41
291.40
0.71
1.
186.
0,
.07
.97
.79
1,
252.
1.
.35
.65
.57
0
0
0
1
1
.000
.873
.894
.903
.919
.932
.949
.959
.976
,984
.994
.001 2378-TCDF AN
.018
.028
-1.039
.000
.959
.984
,000 13C12-2378-TCDF ISO
.018
J
J
J
J
J
J
J
J
J
J
J
J
2,
1
0
0
2
291
0
.94
.22
.72
.65
,41
.40
.71
3
1
1
0
0.
.62
.35
.00
.43
0.
896
0
0
0
0
0
0
0
0
1
924
0
0
1
1
-1.045
.000
.901
.916
.928
.955
,982
.990
.997
.001 2378-TCDD AN
-
-1.076
.000
.948
.001 37C1-TCDD CLS
.015
J
J
JT
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:41 04/20/98
21
-------
Page No.
04/20/98
Listing of T981960B.dbf
Matched OC Peaks / Ratio / Ret. Time
Cotrtpouncl/
M_Z.,.. QC.Log Omit Why ,.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2,. Rel.RT Compound.Name.. ID.. Flags.
328
3 Peaks
294.52
13C12-TCDD
332-334
332-334
PeCDF
340-342
D
DC NL 0:
25:
26:
26:
00
56
07
27
0.
RO
RO
65-
,2.
0.
0.
0,
3 Peaks
DC NL 0:
D SH 27 :
27:
DC SN 27:
DC SN 27:
DC SN 28:
28:
DC SN 28:
DC SN 29:
DC SN 29:
DC SN 29:
00
13
24
44
52
23
32
42
02
06
41
DC SN 29:57
D
D SN 30:06
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
DC SN 30:13
DC SN 31:02
340-342
13C12-PeCDF
352-354
352-354
PeCDD
356-358
356-358
13C 12 -PeCDD
368-370
RO
0.89
55
82
80
63
_
32-1.78
0.
0.
0.
1.
77
44
68
57
0.33
0.84
1.
1.
1.
2,
1,
2
1.
1
0
.76
,53
,67
,60
.19
.38
.03
.48
.44
2 Peaks
DC NL 0
28
29
29
29
30
31
:00
:32
:00
:23
-.40
:06
:03
1.
RO
RO
RO
RO
0.924-1.076
0.
516.
321.
4,
74
66 232.44
70 143,11
37 1,90
0.
284.22 0.
178.59 1.
3.00 1.
000
993 13C12-1234-TCDD
000 13C12-2378-TCDD
013
RSI
IS1
842.73
0.
3.
2.
0.
0.
0,
1.
0.
0.
0,
0,
0.
0.
0,
0.
3,
16
45
02 1.23
18
13
35
71 1.09
43
40
38
.51
20
.56
.62
,13 .
,73
32-1.78
0
1
1
1
1
1
0
6 Peaks
DC NL 0
28
29
DC WH 31
-.00
:40
:22
:11
1.
RO
RO
.32
0
1
1
3
.89
.40
.30
.41
.25
.41
.79
-1.78
,64
.52
.50
.75
2 Peaks
DC NL 0
29
DC SN 29
:00
:21
:31
1
RO
RO
.32
1
1
1
-1.78
.13
.00
.67
0.13
8.85 5.17
0
.71 0.43
347.08 203.19
3
344
0
.18 1.93
.32 201.19
.79 0.48
0.926-1.063
0.000
0.
1.80 0.
926
.933
0.944
0.948
0,
0.62 0,
0.
0,
0.
1
1
1
1
1
.966
,971
,977
,988
,990
.010
.019
.024 23478-PeCDF
.028
.056
AH
0.864-1.136
0
3.68 0
0.33 0
143.89 1
1.55 1
143.13 1
0.61 1
,000
.971
.987
,000 13C12-PeCDF 123
.010
.024 13C12-PeCDF 234
.057
132
SOR1
704,93
0
1
1
0
2
0
0
0
.15
.11 0.67
.15 0.69
.10 '
.26
.15
.53 0.32
.56
0.936-1.021
0
0.44 0
0.46 0
1
0.869
0
0.32 0
0
.000
.942
.965
.025
-1.131
.000
.964
.970
Triangle Laboratories, inc.® Analytical Services Division
801 Cap'rtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 * Fax: (919) 544-5491
Printed: 15:41 04/20/98
-------
Page No.
04/20/98
Listing of T9S1960B.db£
Matched GC Peaks / Ratio / Ret, Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... firea.Peak.1,. Area.Peak.2.. Rel.ET Compound.Name.. ID.. Flags.
368-370
HxCDP
374-376
374-376
13C12-HXCDF
384-386
384-386
HxCDD
390-392
390-392
13C12-HxCDD
402-404
402-404
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
D
DC
DC
DC
DC
DC
SN
3
HL
SN
1
NL
SN
SS
SN
9
NL
SN
SN
SN
SN
SN
0
NL
SN
SN
6
30:26
30:34
30:56
Peaks
0:00
32:03
32:52
Peak
0:00
31:53
32:01
32:52
32:58
33:14
33:26
33:41
33:47
33:50
34:11
34:27
34:33
Peaks
0:00
32:51
32:58
33:27
33:34
33:44
Peaks
0:00
33:03
33:08
33:12
33:18
33:33
33:38
33:56
34:24
Peaks
RO
1.
RO
RO
RO
0.
RO
RO
SO
RO
1.
RO
RO
RO
RO
RO
1
RO
RO
1O
RO
RO
1.
1.
2.
05-
0.
1.
1.
49
58
14
1.43
92
60
50
221.
26.
0.
46 132.69
36 16.14
18
88.77
10.22
1.
1.
1.
000 13C12-PeCDD 123
004
016
I S3
24S.35
• 1?©C DE5 / HxCDF Fo 1 1 ows «™ «» •"—
0.
0.
0.
0.
43
56 0.40
58
56
43-0.59
1.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
07
53
50
50
51
29
51
19
43
71
50
46
59
.05-1.43
1.
1.
2.
1.
0.
3
.19
.50
.22
.00
.32
.86
0.
3.
3.
256.
292.
0.
272.
0.
0.
0.
193,
2.
2,
1,026.
23
03 1.05
73 1.25
24 85.69
55 98.79
86
53 91.64
82 0.64
.67
57
.06 64.24
.14 0.67
,05 0.76
.15
0.963-
0.25
0.
0.
0.
0.879-
1.98
2.48
170,55
193.76
180.89
0.54
128.82
1.47
1.29
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.045
000
972 .
997 123478-HxCDF
1.121
000
967
971
997 13C12-HXCDF 478
000 13C12-HXCDF 678
008
014 13C12-HXCDF 234
022
025
026
037 13C12-HXCDF 789
045
048
ftN
S0R2
IS4
ALT2
ALT1
' HxCDlP / HicCOD Follows *" •"""• -• *'
0,
0.
0,
0.
0
0
0
.46
.63
.20
.58
.13
.16
.00
.05-1.43
0
1
1
1
0
1
1
1
1
.69
.56
.00
.22
.71
.22
.21
.21
.56
0
1
0
0
0
174
218
300
1
696
.43
.28 0.89
.16
.20
.58 0.32
.69 96.10
.00 119.36
.78 164.85
.37 0.95
.70
0.
0.
0.57
0.45
78.59
98.64
135.93
0.61
958-
0.
0.
0.
0.
0.
1.
1.013
000
977
980
995
998 123478-HxCDD
003
AN
970-1.030
0.
0.
0.
0.
0.
0.
1.
1.
1.
000
983
985
987
990
.998 13C12-HXCDD 478
000 13C12-HXCDD 678
.009 13C12-HXCDD 789
.023
SOR3
IS5
RS2
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:41 04/20/98
219
-------
Page No. 4
04/20/98
Compound/
M_Z .... QC . Log
HpCDF
408-410
M
408-410
13C12 -HpCDF
418-420
418-420
HpCDD
424-426
K
424-426
13C 12 -HpCDD
436-438
436-438
OCDF
442-444
442-444
OCDD
458-460
K
458-460
13C12-OCDD
470-472
470-472
Listing of T981960B
Matched GC Peaks /
Omit Why ..RT. OK Ratio Total
0.88-1.20
DC NL 0:00 RO 1.36
35:50 RO 1.37
DC SN 36:01 RO 0.29
1 Peak
0.37-0.51
DC NL 0:00 RO 1.07
35:47 0.44
37:18 0.42
DC SN 37:38 RO 1.27
2 Peaks
0.88-1.20
DC NL 0:00 RO 1.30
36:49 1.04
1 Peak
0.88-1.20
DC NL 0:00 0.94
36:05 RO 0.84
DC SN 36:18 RO 2.67
36:49 1.05
2 Peaks
ove
0.76-1.02
DC NL 0:00 1.00
0 Peaks
0.76-1.02
DC NL 0:00 RO 1.27
40:23 RO 0.61
1 Peak
0.76-1.02
DC NL 0:00 RO 1.08
40:21 0.87
DC WH 40:42 RO 0.63
DC WH 40:52 RO 0.63
1 Peak
.db£
Ratio / Ret. Time
.Area... Area. Peak. 1 . . Area. Peak. 2
0.29
0.61 0.41 0.
0.08
0.61
0.20
150.68 45.80 104.
89.59 26.59 63.
0.16
240.27
0.20
0.47 0.24 0.
0.47
0.31
0.94 0.48 0.
0.06
140.81 72.02 68.
141.75
: HpCDD / Octa-CDD and CDF Follows
0.24
0.00
0.21
0.42 0.20 0
0.42
0.23
117.42 54.50 62
0.89
0.25
117.42
t
. . Rel.RT Compound. Name. . ID..
0.996-1.047
0.000
30 1.001 1234678-HpCDF AN
1.007
0.944-1.112
0.000
88 1.000 13C12-HpCDF 678 136
00 1.042 13C12-HpCDF 789 SDS4
1.052
0.976-1.005
0.000
23 1.000 1234678-HpCDD AN
0.973-1.027
0.000
57 0.980
0.986
79 1.000 13C12-HpCDD 678 IS7
0.901-1.099
0.000
•
0.901-1.099
0.000
.33 1.001 OCDD AN
0.996-1.004
0.000
.92 1.000 13C12-OCDD IS8
1.009
1.013
Flags.
J
J
J
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:41 04/20/98
- 220
-------
Page No. 5 Listing of T9S196QB.dbf
04/20/98 Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area.,. Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es) WL-Below Retention Time Window A-Peak Added
. .RT, -Retention Time (tnuuss) WH-Above Retention Time Window K-Peak Kept
Rat.l -Ratio of M/M+2 Ions SN-Below Signal to Noise Level D-Peak Deleted
OK -RO=Ratio Outside Limits
-------
'±le:T981960 #1-720 AcqslB-APR-1998 06:32:29 EI+ Voltage SIS 70T Noise:64
303.9016 F:2 BSUB(256t 30, -3. 0) PKD(9, 5,5, 0. 05%,256. 0, 1. 00\,F, T) Exp-.NDSSUS
TSIANGLE LABS Text:M23-O-2 TEI#45399 HKT. TIME = 08:32
1004 M3.07E4
A3. 02E4
23:00 24:00 25:00 26:00
File:T9B1960 #1-720 Acq:lS-APR-1998 08:32:29 EI+ Voltage SIR 70T NoiseiSS
305.8987 F:2 BSUB(256f 30, -3 . 0) PKD(9, 5,5, 0. 05%, 352. 0, 1. 00%,F, T) Exp:NDB5US
TSIANGLE LABS Text :M23-0-2 TLI#45399 IttJ". TIME = 08:32
1003, A3.J2E4
„ -• A2.66E4
23:00 24:00 25:00 26:00
File:T9B1960 #1-720 Acq:18-APR-1998 08:32:29 EI+ Voltage SIR 70T Noises99
315.9419 F:2 BSUB(256,3Q, -3.0) PKD(9, 5, 5, 0. 05%, 396. 0, 1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS TextiM23-O-2 TLI#45399 INJT. TIME = 08:32
1004 A1.87E6
aol
601 . '
401
20.
oH , — , -
27s 00
40
20.
ol
Al.04E4
•. 61E3
A2.08E3
27:00
LA
23:00 24:00 25:00 26:00
File:T9B1960 #1-720 Ac
-------
File:T9S1960 #1-720 Acq:18-APS-199S 08:32:29 Eli- Voltage SIR JOT Noise:56
319.8965 F:2 SSVB( 256, 30, -3 . 0) PKD( 7, 5, J, 0 . 05%,, 224. 0, 1 . 00%,F, T) ExpsNDBSUS
TRIANGLE LABS Text:M23-O-2 TLI&45399
1003, ,
801
601
401
201
;
o-
i
Al . 22E4
A- '
•
A1.13E3, ' f\ A2.57E3
INJ. TIME = 08:32
_ 7 . 1E3
A/A
"".5.7E3
"".4.3E3
"-2.9E3
11 . 4E3
lO.OEO
24:00 ' 25.-00 26\00 ' 27:00 ' Time
File:T981960 #1-720 Acg-:18-APJ?-1998 08:32:29 EI+ Voltage SIR JOT Noise:54
321.8936 F-.2 BSUB{256, 30r~3 .0) PKX>(7, 5,3, 0 . 05%, 216. 0,1 . 00%,F, T) Exp:NDB5US
TRIANGLE LABS Text:M23-0-2 TLI#45399
1003
aol
60l
401
201
0"
^.
Al . 35E4
INJ. TIME = 08:32
9 . 3E3
A ' Al. OOE4
\ f\ A4.27E3
I \ A1.96E3 1 \ Al . MJETJjyA^ __..
17. 4E3
"•.5.6E3
13 . 7.E3
-.1.9E3
• o . OEO
24:00 25:00 26:00 27:00 Time
File:T981960 #1-720 ^cg-.-18-APJ?-1998 08:32:29 EI+ Voltage SIR 70T Noise:535
331.9368 P:2 BSUB(256,30, -3.0) PKD(7,5,3, 0. 05%,2140. 0,1 . 00%,F, T) Exp:NDBSUS
TRIANGLE LABS Text:M23-0-2 TLI#45399
100*
aol
'
601
401
201
o-
A2.
I
INJ". TIME = 08:32
32E6
\
A1.43E6
A
Ul
r6.2E5
14.9E5
"-3.JE5
L2.5E5
•-1.2E5
" 0 . OEO
24:00 ' ' . ' 25:00 26:00 ' 27:00 Time
Fil^:T981960 #1-720 Acq:18-APR-1998 08:32:29 EI+ Voltage SIR JOT Noise:20B
333.9338 F:2 BSVB(256, 30, -3.0) PKD( 7, 5, 3, 0 . 05%, 832. 0, 1 . 00%,F, T) Exp:NDB5US
TRIANGLE LABS Text: H23-O-2 TLIt45399
1003
801
601
401
201
o:
A2.
1
IWJ. TIME = 08:32
84E6
Ul . 79E6
\ h
Ul
- 7 • 6E5
".6.1E5
"-4.5E5
'.3 . OSS
Ll . 5E5
•O.OEO
24:00 ' ' ' 25:00 ' ' 26:00 ' 27:00 ' ' ' Time
File;T981960 #1-720 Acg-:18-AP.R-1998 08:32:29 EI+ Voltage SIR JOT NoiseiSl
327.8847 F:2 BSUBf 256, 30, -3 . 0) PKD( 7, 5, 3, 0. 051,244 . 0, 1 . 00%, F, T) Exp:NDS5US
TRIANGLE LABS Text:H23-O-2 TLI#45399
1003
801
601
401
20.
0.
INJ. TIME = 08:32
A2.91E6 8.3E5
'
1 V
"-6.6E5
15.0JT5
13.3^5
Li . 7£5
• O.OEO
' 24\0o' ' ' ' 25:00 ' ' ' ' ' 26:00 ' 27^00 ' Time
File:T981960 #1-720 Acg: 18-APR-1998 08:32:29 EI+ Voltage
330.9792 F:2 Exp-.NDBSUS
TRIANGLE LABS Text:M23-0-2 TLI#45399
1003| 23^3623:52 24:1524:31 2^l°J- jjij,^^ 3
aol
sol
401
20.
Q.
•
24\00" -"•'•• 25\:00 ' ' r ' r^
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INJ". TIME = 08:32
5:59 26:25 BSj^f^^^2J-'-2-2~^~-.r-1--2E6
19 . 4E5
L7.0E5
"-4.JE5
1.2.3E5
• 0 . OEO
'6:00 27:00 Time
223
-------
File:T981S60 #1-720 Acq: 18-APR- 1998 08:32:29 EI+ Voltage SIS
339.8597 F:2 SSUB( 256,30, -3. 0) PKD( 7, 5,3, 0. 05%,204 . 0, 1. 00%,F,
70Z* Noise -.51
T) Exp:NDB5US
TRIANGLE LABS Text:M23-O-2 TLH45399 INJ". TIME = 08:32
1004
SOJ
sol
401
20J
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i Al . 09E4
A ?
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\ ,
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28:00
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A2.56E3 t A3.83JT3
1 A lAJK . /%2.26Jte
25:00
File:T981960 #1-720 Acq:18-APR-1998 08:32:29 EI+ Voltage SIR
341.8567 F:3 BSUB(256,30, -3.0) PKD(7, 5,3, 0. 05%,25J. 0,1 . 00%,jF,
2.9E3
A3.45E3
. A (L A795.45
JUV V \A -AA-A-^ _^A/\/\^A/v
-------
File:T98196Q #1-720 Acq:1B-APR-1998 08:32:29 EI+ Voltage SIR 70T Noise:47
355.8546 F:2 BSUB(256, 30, -3 . 0) PKD(7, 5, 3, 0. 05%,188. 0,1. 00%,f, T) Exp:NDB5US
TRIANGLE LABS Text:M23-O-2 TLI#45399 JWJ. TIME = 08:32
100% A6.95E3
A6.68E3
BO:
28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00 31:12 31
File:T981960 #1-720 Acq: 18-APR-1998 08:32:29 EI+ Voltage SIR 70T Noise:72
357.8516 F:2 BSUB(256, 30,-3 . 0) PKD(7, 5,3, 0 . 05%,288. 0, 1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Teit:M23-O-2 TLI#45399 INJ. TIME = 08:32
1003.A4.40E3
O.OEO
28.'36 28 .-48 29': 00 251-12 29': 24 29': 36 29:48 JO Ir 00 30 ': 12 30:24 3o':36 JO.' 48 31: 00 ' 31 • 12 3l':24 Time
File:T981960 #1-720 Acq: 18-APR-1998 08:32:29 EI+ Voltage SIR 70T Noise:46
367.8949 F:2 BSUB(256r 30,-3.0 ) PKD(7, 5, 3, 0 . 05%, 184 . 0, 1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Teit:M23-O-2 TLI#45399 INJ. TIME = 08:32
10 OS A1.33E6
so:
601
40:
201
A4.57E3
A462.81
0. OEO
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_1. 2E3
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-5.8E2
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801
601
401
201
0.
1. 61E5
4.1E5
-3.3E5
12.5E5
.1.6E5
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Time
28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00 31:12 31:24
File:T981960 #1-720 Acq:18-APR-1998 08:32:29 EI+ Voltage SIR 70T Noise:38
369.8919 F:2 BSUB(256, 30,-3 .0 ) PKD(7, 5, 3, 0 . 05%, 152. 0,1. 00%,F, T) Eip:NDB5US
TRIANGLE LABS Teit:M23-O-2 TLI#45399 INCT. TIME = 08:32
100$ A8.88E5 ^2.7E5
801
601
401
201
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1. 02E5
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11.1E5
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28:36 28:48 29:00 29:12. 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00 31:12 31:24 Time
File:T981960 #1-720 Acq:18-APR-1998 08:32:29 EI+ Voltage SIR 70T
330.9792 F:2 Exp:NDB5US
TRIANGLE LABS Teit:M23-O-2 TLI#45399 JWJ. TIME = 08:32
<~^_28:47 29:05 29:1929:30 29:48 30.50 30:17 30-29 in <:•; ,, nf
" • ^*" ' — -^""^ — -^ ' — ' — ' ^N / — ^ — • — s«^_^c^ — i^ s^s* .^ — ^LJ. — ^ , — -^* JL/:OD 31:06 31-19
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28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00 31:12 31:24 Time
-------
F±le:T981960 #1-425 Acq:18-APR-1998 08:32:29 £1+ Voltage SIS 70T Noise:120
73.8208 F:3 BSVB(256, 30,-3 .0) PXD(7,5,3,0.05%,480.0, 1.00%,F,T) ExpsKDBSUS
TRIANGLE LABS Text:M23-0-2 TLI#45399 INJ. TIME = 08:32
1003 A4.00E3 A3.86E3
31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34:12
'±le:T981960 #1-425 Acq:18-&FR-1998 08:32:29 EI+ Voltage SIR 70T Noise:131
375.8178 F:3 BSOB(256,30,'-3'.0) tXD(7,5,3,0 .05\,524.0,1.00%,F,T) Exp:MDB5US
TRIANGLE LABS Text:M23-0-2 . TLI#45399 JTO7. TIME = 08:32
100S A2.51E3
31s48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34:12
F±le:T981960 #1-425 Acqs18-APR-1998 08:32:29 EI+ Voltage SIX 70T Noise:78
383.863S T;3 BSUB(256, 30, -3.0) PKD(7,5, 3, 0. 05%, 312. 0,1. 00%,F, T) Exp:NDB5US
TRIANGLE LASS Text:M23-O-2 TLI#45399 XWT. TIME = 08:32
1004 A9.S8E5 A9.16E5
34:24 34:36 34-48 Time
80.
60:.
401
201
0-
A6.42E5
O.OEO
48 Time
_2.9E5
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11. 7E5
'-1.2E5
-5.8E4
O.OEO
31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34:12
File:T981960 #1-425 Acq:18-APR-1998 08:32:29 EI+ Voltage SIR 70T Noise:73
385.8610 F:3 BSUB(256, 30, -3 . 0} PKD(7, 5, 3, 0. 05%,292. 0, 1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Tsxt:M23-O-2 TLI045399 IJKT. TIMS = 08:32
1004 A1.S4E6 A1.81E6
80.
601
401
201
OJ
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34:24 34:36 34:48 Time
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J1.-48 32:00 32.-12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00
File:T9B1960 #1-425 Acg:18-APR-1998 08:32:29 EI+ Voltage SIS 70T
392.9760 F:3 Exp:NDB5US
TRIANGLE LABS Text:M23-0-2 TLI#45399 IKT. TIME = 08:
1003
80~-
40-
o-
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34': 12 34':24 34':36 34 48 Tint
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-4.5E5
-3. 4E5
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-1. 1E5
31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33-36 33:48 34:00 34
File:T981960 #1-425 Acqsl8-APR-1998 08:32:29 EI+ Voltage SIR 70T
445.7555 F:3 Exp:NDB5US
TRIANGLE LABS Text:M23-0-2 TLI#45399 IKT. TIME = 08:32
34s24 34s36 34
so
6ol
40-
201
o
34 125
34:39
.O.OEO
48 Tim.
_5.4E2
-7.1E2
_4.7£2
-2.4E2
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31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33s36 33:48 34:00 34-12
t.....|... .. | O.OEO
34:24 34:36 34 48 Tim.
22fi
-------
File:T3S1960 #1-425 Acq:18-APR-l998 08:32:29 EI+ Voltage SIS 70? Woise.-i.24
389.8156 F:3 BSUB(256, 30, -3 . 0) PKD( 7, 5, 3, 0 . 05%, 496. 0,1. 00%,.F, T) Exp:NI>B5US
TRIANGLE LABS Tezt:M23-O-2 TLI#45399 INJ. TIME = 08:32
1003s A4.25E3
32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00
File:T981960 #1-425 Acq:18-APR-1998 08:32:29 EI+ Voltage SIR 70T Noise:106
391.8127 F-.3 BSUB(256, 30, -3 . 0) PKD( 7, 5, 3, 0 . 05%, 424 . 0, 1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Text:M23-O-2 TLI#45399 INJ. TIME = 08:32
100$
32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00
File:T981960 #1-425 Acq:18-APR-1998 08:32:29 EI+ Voltage SIR 70T Noise:119
401.8558 F:3 BSUB(256,30,-3.0) PKD( 7, 5, 3, 0. 05%, 4 76. 0, 1. 001,F, T) Exp:NDB5US
TRIANGLE LABS Text:M23-O-2 TLI#45399 INJ. TIME = 08:32
1003 A1.65E6
34:12
.O.OEO
34:24 Time
^1. 4E3
34 :12
so:
60.
40.
20.
A1.19E6
32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00
File:T9S1960 #1-425 Acq: 1S-APR-1998 08:32:29 EI+ Voltage SIR 70T Noise:174
403.8529 F:3 BSUB(256, 30, -3 . 0) PKD( 7, 5, 3, 0 . 05%, 696. 0,1. 00%,F, T) Exp:NI>B5US
TRIANGLE LABS Text:M23-O-2 TLI#45399 INJ. TIME = 08:32
1001, A1.36E6
34:12
so:
eo:
A9.86E5
LO.OEO
34:24 Time
4.6E5
~_3. 7E5
12.8E5
'.I. 9E5
'.9.3E4
-4-0. OEO
34:24 Time
3. 9E5
.3. 1E5
.2.3E5
'.1. 6E5
.7.8E4
O.OEO
32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48
File:T981960 #1-425 Acq:18-APR-1998 08:32:29 EI+ Voltage SIR 70T
392.9760 F:3 Exp:NDB5US
TRIANGLE LABS Text:M23-O-2 TLI#45399 INJ~. TIME =
1004 ^1232^32:3932,48 33:01 ,„,„ 33:3933:47
- —'^~r v—^_
801
601
401
201
0.
34:00
34:12
34:24 Time
08:32
34:02 34:11 34:
20
5.5E5
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.2.2E5
.1.1E5
O.OEO
32:24
32:36
32:48
33:00
33:12
33:24
33:36 33:48
34:00 34:12
34:24 Time
227
-------
B5US
TRIANGLE LABS Text:M23-0-2'- TLH45399 INJ. TIME
35:47 35:58 36^15 36:24 36:36 36:52. 37.'OS
801
601
401
201
oi
2.8E5
12.2E5
ll. 7E5
ll.lES
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37:24
08:32
37:19 37:26
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37:36
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37:43
37i37 37^46 4,1E5
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-2.4E5
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35:48 36:00 36:12 36:24 36:36 36:48 37:00 37:12
File:T981960 #1-629 Acq:18-APR-1998 08:32:29 EI+ Voltage SIR 70T
479.7165 F:4 Exp:NI>B5US
TRIANGLE LABS Text:M23-0-2 TLI#45399 INJ'. TIME =
1004
37:24
08:32
801
601
401
20.
01
37:36
37:37
37:08
35:49
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37:48 Tim
1.1E3
-9.1E2
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L4.5E2
L2.3E2
35:48
36:00
36:12
36:24
36s36
36:48
37:00
37:12
37:24
37:36
[•• 0 - OEO
37:48 Tin
228
-------
Fi±e:T981960 #1-629 Acq:18-APR-1998 08:32:29 EI+ Voltage SIR 70T Noise:64
423.7766 F:4 BSUB(256, 30,-3 .0 ) PKD(7, 5, 3, 0 . 051,256. 0, 1. 00%,JF, T) Exp:NDB5US
TRIANGLE LABS Text:M23-O-2 TLI#45399 INJ. TIME = 08:32
1003t A2.44E3
A2. 65E3
801
601
401
20:
36:00 36:06 36:12 36:18 36:24 36:30 36:36 36:42 36:48 36:54 37:00
File:T981960 #1-629 Acq:18-APR-1998 08:32:29 EI+ Voltage SIR 70T Noise:52
425.7737 F:4 BSUB(256 , 30, -3 .0) PKD(7, 5,3, 0. 051,208 . 0, 1 . 00%,F, T) Exp:NDB5US
TRIANGLE LABS Text:M23-0-2 TLI#45399 INJ~. TIME = 08:32
100% A2.32E3
801
601
401
201
37:06 37:12 37:18
.6.4E2
.5.1E2
.3 . 8E2
.2. 6E2
.1. 3E2
.O.OEO
Time
.4 . BE2
.3 . 6E2
.2.4E2
.1.2E2
0.
36:00 36:06 36:12 36:18 36:24 36:30 36:36 36:42 36:48 36:54 37:00
File:T981960 #1-629 Acq:18-APR-1998 08:32:29 EI+ Voltage SIR 70T Noise:76
435.8169 F:4 BSUB(256, 30,-3.0 ) PKD(7 , 5,3, 0. 051, 304 . 0 , 1.00*,F, T) Exp:NDB5US
TRIANGLE LABS TeXt:M23-O-2 TLI#45399 INJ. TIME = 08:32
1004 A7.20E5
37:06 37:12 37:18
40.
201
36:00 36:06 36:12 36:18 36:24 36:30 36:36 36:42 36:48 36:54 37:00
File:T981960 #1-629 Acq:18-APR-1998 08:32:29 EI+ Voltage SIR 70T Noise:81
437.8140 F-.4 BSUB(256, 30,-3 .0 ) PKD(7, 5, 3, 0. 05%, 324 . 0, 1. 00%,JF, T) Exp:NDB5US
TRIANGLE LABS Text:M23-0-2 TLIX45399 INJ-. TIME = 08:32
100S A6.88E5
80.
60.
401
20.
37:06 37:12 37:18
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36:06
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36:12 36:18 36:24 36:30 36:36 36:42 36:48
i i i i i i i i i I i 1' i i i i i i i i i i i i i i i i i i
36:54 37:00 37:06 37:12 37:18
36:00
File:T981960 #1-629 Acq:18-APS-1998 08:32:29 EI+ Voltage SIR JOT
430.9729 F:4 Exp:NDB5US
TRIANGLE LABS Teit:M23-O-2 TLI#45399 INJ. TIME = 08:32
100% 36:05 36:15 36:24 36:30 36:36 36:52 37:00 37:06
801
601
401
201
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Time
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Time
.1. 7E5
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Time
36:00 36:06 36:12 36:18 36:24 36:30 36:36 36:42 36:48 36:54 37:00 37:06 37:12 37:18
2.4E5
.1. 6E5
.8.0E4
O.OEO
Time
-------
File:T9S1960 #1-629 Acq: 18 -APR- 19 9 8 08:32:29 EH- Voltage SIR 70T Noise:60
441.7428 F:4 BSUB( 256, 30, -3 .0 ) PKD(7, 5 , 3, 0 .051,240 . 0, 1. 00*,F,T) Exp:NDB5US
TRIANGLE LABS Text:M23-O-2 TLI#45399 INJ. TIME = 08:32
100% 2.2E4
901
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701
601
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40.
301
20.
101
'
36\00 ' ' ' '37(:00 ' ' jfll-00 ' ' ' Jsl-00 ' ' ' 40:00 ' ' ' 41 i 00 ' ' ' 421-00
File:T981960 #1-629 Acq:18-APR-1998 08:32:29 EI+ Voltage SIS 70T Noise:59
443.7399 F:4 BSUB(256, 30, -3 . 0) PKD( 7, 5, 3, 0. 051,236. 0, 1 . 00*, F, T) Exp:NDB5US
TRIANGLE LABS Text:M23-0-2 TLI #45399 INJ. TIME = 08:32
1003
901
801
701
601
501
401
301
20j
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File
430.
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1003
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801
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101
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513.
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36:00 ' 37\00 38:00 39:00
•-T981960 §1-629 Acq: 18-APR-1998 08:32:29 EI+ Voltage
9729 F:4 Exp:NDB5US
NGLE LABS Text:M23-O-2 TLI#45399
j j^WMiLthft A AJtAA-AiWV/^^SJ^j jQ^i/^*w/V^V^VvVjTi
J5.-00 J7-00 J8.-00 JS-OO
•.T981960 #1-629 Acq: 18-APR-1998 08:32:29 EI+ Voltage
6775 F-.4 Exp:NDB5US
NGLE LABS Text:M23-O-2 TLI#45399
36:41
35:50 36.27\ 37:34 38:0.738:35 39:14
^f^jLj^^^tfj^,^^^ Aw-U^fL
36\00 ' J71-00 ' J8:00 ' Jsl-00
40.- 00 ' ' ' 4ll-00 42:00
SIR 70T
INJ. TIME =08:32
40:00 ' ' 41.-00 ' . ' 421-00 '
SIR 70T
INJ-. TIME = 08:32
»
42: OS
39:43 40J22t l^/00 41:2841:551 42:45
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40:00 4lioO 42.' 00
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.1 . 5E4
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.8.7E3
-6.5E3
-4.4E3
-2.2E3
.O.OEO
Time
.1 . 6E4
.1 . 5E4
.1.3E4
.1.2E4
-9.9E3
-8.2E3
,6.6E3
-4.9E3
-3.3E3
_1 . 6E3
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Time
4.1E5
•-3.7E5
':3 . 3E5
'.2.9E5
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.2.0E5
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Time
4.5E3
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-.3 . 6E3
'-3.2E3
-2.7E3
.2.3E3
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-1.4E3
{9 . 1E2
4.5E2
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Time
230
-------
File:T981960 #1-629 Acq:1B-APR-1998 08:32:29 EI+ Voltage SIS 70T Noise:68
457.7377 F:4 BSUB(256, 30,-3 .0 ) PKD(7, 5, 3, 0 . 05%,272. 0, 1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Text:M23-O-2 TLI#45399 INJ. TIME = 08:32
lOOZ A2.Q4E3
80.
60.
40.
201
40:18 40:24 40:30 40:36 40:42
F±le:T9S1960 #1-629 Acq: 18-APR-199B 08:32:29 EI+ Voltage SIR 70T Noise:53
459.7348 F:4 BSUB<256 , 30,-3 .0) PKD( 7, 5, 3, 0 . 05%,212. 0, 1. 00%,f, T) Exp:NDB5US
TRIANGLE LABS Text:M23-O-2 TLI#45399 INJ~. TIME = 08:32
100% A3.28E3
40':18 40:24 40:30 40:36 40:42
File:T981960 #1-629 Acq:18-APR-199B 08:32:29 EI+ Voltage SIR 70T Noise:64
469.7779 F:4 BSUB(256, 30,-3 . 0) PKD( 7, 5, 3, 0 . 05%, 256. 0, 1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Text:M23-0-2 TLI#45399 INJ. TIME = 08:32
10 OS, A5.4.5E5
40:48
40:48
40:18 40:24 40:30 40:36 40:42
File:T9B1960 #1-629 Acq: 18-APR-199B 08:32:29 EI+ Voltage SIR 70T Noise:58
471.7750 F:4 BSUB(256, 30,-3.0) PKD( 7, 5, 3, 0. 05%, 232. 0, 1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Text-.M23-0-2 . TLI#45399 INJ~. TIME = 08:32
1003, A6.29E5
80.
60.
40.
20.
40:48
6.BE2
5.5E2
4.1E2
2. 7E2
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Time
40:18 40:24 40:30 40:36 40:42 40:48
File:T981960 #1-629 Acq: 18-APR-199B 08:32:29 EI+ Voltage SIR 70T
430.9729 F:4 Exp:NDB5US
TRIANGLE LABS Text-.M23-O-2 TLI#45399 INJ. TIME = 08:32
100$ 40^15 _ 40:29 40:37 40:51
801
6QL
40.
20.
0.
40:18
40:24
40:30
40:36
40:42
40:48
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Time
.1.2E5
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Time
.4.1E5
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Time
231
-------
Chamel I 339,9792 Peak top
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-------
TLI Project:
Client Sample:
45399
M23-O-2
Method 23 TCDD/TCDF Analysis (DB-225)
Analysis File: P981311
Client Project:
Sample Matrix:
TLI ID:
rQ12.002/Lime Kiln
M23 Date Received: 04/01/98
204-92-6A-D Date Extracted: 04/03/98
Date Analyzed: 04/16/98
Spike File: SPC2NF04
ICal: PF24098
ConCal: P981302
Sample Size:
Dry Weight:
GC Column:
1.000
n/a
DB-225
Dilution Factor: n/a
Blank File: U980780
Analyst: ML
% Moisture: n/a
% Lipid: n/a
% Solids: n/a
2,3,7,8-TCDF
0.01
0.67
22:25
JB
3Ci2-2,3,7,8-TCDF
2.2
54.0
40%-130%
0.79
22:24
13Ci2-l,2,3,4-TCDD
0.79
21:18
Data Reviewer:
04/20/98
Page 1 of 1
C2NF.PSR V2.02, LARS 6.11.00
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 21:28 04/20/98
23?
-------
Initial ....Date...
Data Review By:
Calculated Noise Area:
0.15
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
04/20/98
Listing of p9813llB.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.,.. QC.Log Omit Why . ,RT, OK Ratio Total.Area... Area.Peak.1,. Area.Peak.2.. Rel.ET Compound.Name.. ID.. Flags.
TCDF
304-306
304-306
DC
DC
DC
DC
DC
DC
DC
HL 0:
17:
18:
SN 19:
19:
SN 19:
SN 19;
19:
SN 19:
20;
20:
21
21
SN 21
21
SN 22
22
23
00
52
51
00
06
18
33
•43
:52
:02
:33
:00
:14
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:52
:18
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0.
EO
RO
RO
RO
RO
RO
RO
SO
RO
RO
65-0.89
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0,
0.
0.
0
0
1
0
0
90
93
69
19
70
55
74
59
50
,86
,71
.58
.48
.82
.92
.07
.67
.66
11 Peaks
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0,
0
0
0
0
0
0
8
18
74
81
11
78
39
33
55
11
,95
.66
.60
.57
.40
.44
.27
.70
.48
.28
0.790-1.102
0.
0.
0.
0.
0,
0,
0,
0
0
0
0
39
33
32
24
,44
,69
.26
.25
.23
.28
.19
0.
0.
0.
0,
0
0
0
0
0
0
0
,42
48
.46
.41
.51
.97
.45
.52
.25
.42
.29
0.
0.
0,
0.
0.
0.
0.
0.
0,
0,
0
0
0
0
0
0
1
1
000
,798
842
848
853
862
.873
,880
.887
.894
.917
.938
.948
.958
.976
.996
,001 2378-TCDF
.031
J
J
J
J
J
J
J
J
AN J
J
13C12-TCDF 0.65-0.89
316-318 DC Nt OtOO RO 1.00 0.18
DC WL 20:59 0.84 0.81
DC WL 21:14 0.83 2.38
22:24 0.79 229.80
23:04 0.81 0.49
DC WH 23:27 RO 2.28 0.32
DC WH 24:25 0.73 3.71
316-318 2 Peaks 230.29
101.27
0.22
0.955-1.045
0.000
0.937
0.948
128.53 1.000 13C12-2378-TCDF ISO
0.27 1.030
1.047
1.090
Above: TCDF / TCDD Follows
13C12-TCDD-
332-334
332-334
0.65-0.89
DC NL OsQO RO 1.11 0.16
19:53 RO 0.97 0.55
21:01 0.75 169.88
21:18 0.79 316.91
22:01 0.75 1.38
4 Peaks 488.72
0.30
72.68
139.63
0.59
0.905-1.095
0,000
0.31 0,946
97.20 1.000 13C12-2378-TCDD ISl
177.28 1.013 13C12-1234-TCDD RSI
0.79 1.048
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 21:28 04/20/98
-------
Page Ho.
04/20/98
Listing of Pi81311B,dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total. Area... Area.Peak.1.. Area.Peak.2. . Rel.RT Compound.Name.. ID.. Flags.
Column Description.
"Why" Code Description,........ QC Log Desc.
M_Z -Nominal Ion Hassles) ML-Below Retention Time Window A-Peak Added
..RT. -Retention Time (mm:ss) WH-Above Retention Time Window K-Peak Kept
Rat.l -Ratio of M/M+2 Ions SN-Below Signal to Uoise Level D-Peak Deleted
OK -RO=Ratio Outside Limits
-------
File:P98l311
41-1006 Acq:'l6-APR-l998 21:24:46
EI+ Voltage SIX 7 OP
303.9016 Exp:DB225
TRIANGLE LABS Text:M23-O-2 TLI#45399
1003
951
90l
85J
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75.
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46 EI+ Voltage SIR 7 Op
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1004
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240
-------
File:P981311 #1-1006 Acq:16-APR-1398 21:24:46EI+ Voltage SIS 7 Of Noises 45
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TRIANGLE LABS Text:M23-O-2 TLI#45399
100$
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80.
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TRIANGLE LABS TextiM23-O-2 TLI#45399
1004 ' . &9.6SE3
aoj
24:00
18:00 19:00 • '- 20:00 21:00 22:00 23:00
File:P981311 #1-1006 Acq:16rAPX-1998 21:24:46 EI+ Voltage SIR 7QP tfaise:48
315.9419 BSim(2S6,30,-3.0) PKD(5,3,1, 0.10%,1S2.0,0.00%, J-, JF) ExpsDB22S
TRIANGLE I&BS Text:M23-O-2 TI,I#45399
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File:P981311 #1-1006 Acq?16-XPK-1998 21:24:46 EH- Voltage SIR 70f NoiaesSl
317.9389 BSVB(256,30,-3.0) PKD(Sr3,l,0.10%,204.0,0.00*,I'rF) ExpiDB225
TRIANGLE LABS Text:M23-O-2 TLI#45399
1003, A1.29E6
801
601
401
201
01
18:00 19:00 ... 20:00 Jl.-OO 22sOO JJsOO
File:P981311 #1-1006 Acq:16+APR-1998 21:24:45 EI+ Voltage SIR 70f
375.8364 £xp:DB225
TRIANGLE LABS TexttM23-0-2 TLI#45399
1004
25:
as it
2.6ES
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11. OE5
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25:
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25
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18:00
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20:00
21:00
22:00
23:00
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25:00 Tim
241
-------
File
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333
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VGLE LASS Text:M23-Q-2 TLI#45399
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NGLE LABS TextsM23-0-2' TLI #45399
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'
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NGLE LABS Text iM23 -0-2 TLI #4 5399
Al ,
J
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00 22:00 23:00 24:00 Time
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9368 BSOB(2S6,30,-3.0) jPKDC5,3,l,0,10%,208.0,0.00%,P,PJ SxpsDBSSS
WGLE LABS Text:M23-O-2 ' TLI#45399
A1.40E6
I
A7.27E5
t.,
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111
'laloO ' ' ' ,'20:00' ' ' '21:08 ' ' ' '22:00 23(: 00 ' ' ' ' 24\ 00
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9338 BSUB(256r30e-3,0) PKD(5, 3, 1,0.101,172. 0,0. 00*,F,F) ExpiBB225
WGLE LABS Text:fi23-0-2 TLI#45399
I Al, 77E6
ft
A9 . 72E5
A { E
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111
13 . 6E5
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17.5E4
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Time
4 . 7E5
13 . 7E5
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.1 . 9E5
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' 0 . OEO
'l9:00' ' ' ' '2oioo' ' 'jlsOO* ' ' ' '.22*00 23-00 24<0o' Time
-------
file .-PS 81311 #1-1006 Acq:16-APS-1998 21:24:46 EI+ Voltage SIR 70P
303.9016 Exp:DB225
TRIANGLE LABS Text:M23-0-2 TLI#45399
100$ 18:51 20; 02
ISiOO 19:00 . ,; 20iOO 21:00 22:00 23:00
File:P981311 #1-1006 Acq:16-?APR-1998 21:24:46 EI+ Voltage SIR 70P
315.9419 £xp:DB225 .; ••
TRIANGLE LABS Text:M23-6-2, TLI#45399
1004 22,-24
40
18:00 15:00 20:00 21:00 22:00 23:00
File:PS81311 #1-1006 Acq:16-APR-1998 21:24:46 EI+ Voltage SIR 70P
319.8965 Exp:DB225
TRIANGLE LABS Text:M23-0-2, TLI345399
24:00
25 si
C2.6E5
12. 1E5
Ll.5E5
Ll,OE5
15.1E4
24:00
25s
f. 0. OEO
00 Time
18:00 19:00 ' 20:00 21:00 22:00 23:00
File:P981311 #1-1006 Acq:16-APR-1998 21:24:46 EI+ Voltage SIR 70P
331.9368 Exp:DB225
TRIANGLE LABS Text:M23-0-2- TLI#45399
1004 ' 21 ,-18
24:00
25:(
80J
601
4bl
201
21: 01
.3.0E5
-2.3E5
Ll. 5E5
L7.5E4
18:00 15:00 20:00 21.-00 22;00 2J:00
File,-PS81311 #1-1005 Acq:16-APR-1998 21:24:46 EI+ Voltage SIX 70P
292.9825 Exp:DB225
TRIANGLE LABS Text:M23-0-2- TLI#45399
80J
24:00
25:
tO.OEO
00 Tim
18:00 19.-00 20:00 21sOO 22.-00
File:P981311 #1-1006 Acq:16-APR-1998 21:24:46 EI+ Voltage SIS 70P
330.9792 Exp:DB225 . •,
TRIANGLE LABS Text:M23-O-2 TLI#45399
23:00
24:00
25:
1003
80J
401
20:
ol
18:08 18:40
19:55
20:55 21:32 22:0722:34
23
'2123:47 24:1724^43 ,.9.9E5
A
-7.9E5
-2.0 £5
18:00
19s 00
20\00
21 s 00
22-00
T 1 1—
23:00
-T 1 1 1—
24100
0. OEO
25! 00 Xui
-------
Ref, uss 292,9825 Peak top
Height ,13 volts Span 208 ppi
Systea file naae
Data file nase
Resolution
fjpoup muter
lonlzatlon Hde
Switching
ief, lasses 292.9825,
A 292,3821
i 383,9816
C 385,8987
D 315,9413
I 317,9389
F
6 321,8936
H 327,8847
I 338,9792
J
K
L
H
1
El*
WLffff
381,3761
338,9792
331,9368
333,3338
375,8364
Channel I 338,9792 Peak top
Helpjt .17 volts Span 288 ppi
r-44
-------
Pages 245 through 297 from the Triangle Laboratories, Inc. analytical report
have been excluded by PES since these pages present results for samples
collected at another lime kiln facility during the same mobilization.
-------
TLI Project; 45399
Client Sample: M23-FB-1
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S982307
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
r012.002/Lime
M23
204-92-9A-D
1.000
n/a
DB-5
Kiln
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
04/01/98
04/03/98
04/18/98
n/a
U980780
DL
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPMIT204
SF51078
S982303
n/a
n/a
n/a
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.003
0.005
0.005
0.005
0.004
0.005
0.006
0.002
0.004
0.004
0.003
0.003
0.004
0.004
0.004
0.005
0.004
Totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Aral, (ng)
ND
ND
ND
ND
Number Pi il/IPC
0.003
0.005
0.005
0.005
Flags
—
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
ND
ND
ND
ND
0.002
0.004
0.004
0.005
Page 1 of2
MTO.PSR »I,«, LARS S.I 1.00
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:27 04/20/98
f. <*
-------
TLI Project: 45399
Client Sample: M23-FB-1
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S982307
Internal Standards
l3Ci2-2,3,7,8-TCDF
l3C12-2,3,7,8-TCDD
13Ci2-l,2,3J,8-PeCDF
13C12-l,2,3,7,8-PeCDD
BCP-l,2,3,6,7,8-HxCDF
DCi2-l,2,3,6J,8-HxCDD
13C,2-l,2,3>4,6,7,8-HpCDF
13Ci2-l,2,3,4,6,7,8-HpCDD
13CP-1,2,3,4,6,7,8,9-OCDD
13C,r2,3,4,7,8-PeCDF
13Cp-l,2,3,4,7,8-HxCDF
'3Ci2-l,2,3,4,7,8-HxCDD
13C,2-l,2,3,4,7,8,9-HpCDF
Amt {ng}
3.0
2.5
2.8
3.3
2.9
3.7
3.2
4.2
9.5
4.2
3.6
3.7
4.4
% Recovery
74.4
63.1
70.1
83.6
72.8
91.7
80.5
106
119
lli;«li;til^iciiiiil
^sffmm^f^mmmimmm
106
90.4
92.9
110
QC Limits
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
40%- 130%
40%- 130%
40%-130%
25%-130%
Ratio
0.72
0.80
1.52
1.48
0.50
1.21
0.41
1.02
0.86
1.54
0.50
1.21
0.42
RT Flags
25:15
25:58
29:11
30:13
32:45
33:27
35:46
36:51
40:45
29:53
32:39
33:22
37:23
37CL,-2,3,7,8-TCDD
3.7
93.5
40%-130%
25:59
ISIIIiratllSi^^
&:%w:::::::-::x::#^
13C,2-l,2,3,7,8,9-HxCDF
l3C12-2,3,4,6,7,8-HxCDF
3.4
3.5
84.9
87.4
40%-130%
40%-130%
0.50
0.50
34:04
33:16
!3Ci2-l,2,3,4-TCDD
13Ci3-l,2,3,7,8,9-HxCDD
0.81
1.21
25:47
33:47
Data Reviewer,.
04/20/98
Page 2 of 2
MTT2_PSR vi.
-------
Initial
. . . .Date. . .
Data Review By:
Calculated Hoise Area:
0,15
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
04/20/98
Listing of S982307B.dbf
Matched GC feaks / Satio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ,,RT. OK Ratio Total.Area... Area.teak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
320-322
37C1-TCDD
323
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
0.
DC NL 0:00 RO
DC SN 24:42 RO
DC WH 27 1 24 SO
0 Peaks
0.
DC NL 0:00 RO
DC WL 24:13
24:51
25:15
25:41
3 Peaks
0.
DC NL 0:00 RO
DC SN 25:15 SO
DC SN 25:26 RO
DC SN 25:59 RO
DC SN 26:16 RO
DC SN 26:27 RO
0 Peaks
DC NL 0:00
24:37
25:59
26:39
3 Peaks
0
DC NL 0:00 RO
24:49 RO
25:47
25:58
26:17 RO
4 Peaks
1
DC NL 0:00 RO
65-0.89
1.11
1.27
1.60
65-0.89
0.59
0.69
0.76
0.72
0.73
65-0.39
1.00
3.10
1.00
0.41
1.17
1.75
'
.65-0.89
2.36
1.11
0.81
0.80
0.93
.32-1.78
1.00
0.16
0.19
0.18
0.00
0.23
9.05
2.97 1.28
547.80 229.40
1.87 0.79
552.64
0.14
0.18
0.14
0.37
0.11
0.07
0.00
0.13
1.67 1.67
316.86 316.86
0.37 0.37
318.90
0.19
1.54 0.97
513.06 229.03
357.14 158.88
4.73 2.47
876.47
TYT^n / T>tf*fTYl7 Pi~\l 1 f\t fc-
0.13
0.873-1.075
0.000
0.978
1.085
0.960-1.040
0.000
0.959
1.69 0.984
318.40 1.000 13C12-2378-TCDF
1.08 1.017
0.899-1.046
0.000
0.972
0.979
1.001 2378-TCDD
1.012
1.019
0.923-1.077
0.000
0.948
1.001 37C1-TCDD
1.026
0.923-1.077
0.000
0.87 0.956
284.03 0.993 13C12-1234-TCDD
198.26 1.000 13C12-2378-TCDD
2.67 1.012
0.928-1.063
0.000
ISO
AN
CLS
RSI
I SI
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:27 04/20/98
200
-------
Page Mo.
04/20/98
Listing of S982307B,dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z,... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
DC SN 27 :
DC SN 29 :
09
53
DC SN 30:03
RO
RO
RO
DC SN 30:09
340-342
13C12-PeCDF
352-354
0.
1,
1.
1.
44
00
18
33
0 Peaks
DC NL 0:00
1.
RO
28:19
28:48
29:
ill
. 29:19
RO
29:28
29;
i 53
DC SN 30:14
RO
30:51
352-354
PeCDD
356-358
32-
1.
1.
1.
1.
1.
1.
1.
3.
1.
7 Peaks
DC NL 0 : 00
DC SN 29
:32
DC SN 30:13
1.
RO
RO
RO
DC SN 30:47
DC WH 31:04
DC WH 31:11
356-358
13C12-PeCDD
368-370
368-370
HxCDF
374-376
374-376
13C12-HXCDP
384-386
RO
32-
0.
2.
1.
1.
1.
3.
1.78
00
45
66
52
30
35
54
13
68
1.78
90
73
83
67
63
00
0 Peaks
DC NL 0
29
29
30
30
:00
i 09
:16
:13
:21
1.
0
0
0
0
0
0
, 12
0
387
2
2
397
0
1
.13
.10
.21
.14
.00
.15
.41 7.34
.85 0.53
.08 233.77
.01 1.22
.58 1.48
.87 241.02
.38
.10 0.69
0.
1.
1.
1.
0.863-
0.
5 . 07 0 .
0.32 0.
153.31 1.
0,94 1.
1.10 1.
156.85 1,
1.
0.41 1.
930
024 23478-PeCDF
030
033
1.137
000
970
987
000 13C12-PeCDF 123
005
010
024 13C12-PeCDF 234
035
057
AN
IS2
SOR1
803.90
0
0
0
0
0
0
0
.15
.28
.15
.24
.21
.10
.00
32-1.78
1.
1.
1.
1.
1.
50
42
59
43
47
4 Peaks
DC NL 0
DC SN 31
DC SN 31
DC SN 32
DC SN 32
0 Pe
DC NL 0
31
31
32
:00
:50
:58
ill
:40
aks
:00
:41
:48
:39
1.
RO
RO
.05-1.43
1.
.33
2.00
5.00
1.20
RO
0
RO
0,
.62
0
0
0
256
21
278
.15
.58 0.34
.70 0.43
.04 152.79
.10 12.57
.42
0.937-
0.
0.
1.
1.
1.
1.
0.868-
0.
0.24 0.
0.27 0.
103.25 1.
8.53 1.
1.022
000
977
000 12378-PeCDD
019
028
032
1.132
000
965
969
000 13C12-P6CDD 123
004
AN
IS3
• PeCDD / HxCDF Follows — ™—
0
0
0
0
0
0
.21
.20
.02
.11
.14
.00
.43-0.59
0,
0.
0,
0.
,80
.44
.50
.50
0
3
5
321
.30
.76 1.15
.57 1.86
.34 107.51
0.963-1.048
0.
0.
0.
0.
0.
000
972
976
983
997 123478-HxCDF
AN
0.878-1.122
0.000
2.61 0.967
3.71 0.
971
213.83 0.997 13C12-HXCDF 478
STJR2
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 » Fax: (919) 544-5491
Printed: 20:27 04/20/98
30*
-------
Page No.
04/20/98
Listing of S982307B.db£
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ,.RT. OK Ratio Total.Area.,. Area.Peak,1.. Area.Peak.2.. Rel.BT Compound.Name.. ID.. Flags.
384-386
HxCDD
390-392
390-392
13C12-HXCDD
402-404
402-404
HpCDF
408-410
D
408-410
13C12-HpCDF
418-420
418-420
32:45
33:04
33:16
33:26
34:04
8 Peaks
1.
DC NL 0:00
DC SN 32:40 RO
DC SN 32:45 RO
DC SN 32:50 RO
DC SN 33:16 RO
DC SN 33:24
DC SN 33:33 RO
DC SN 33:41 RO
DC SN 33:51 RO
DC SN 33:54 SO
0 Peaks
1.
DC NL 0:00
32:52
33:22
33:27
33:47
34:04
34:13
6 Peaks
0.
DC NL 0:00
d SN 35:45 RO
DC SN 36:10
0 Peaks
0
DC NL 0:00 RO
35:46
37:23
2 Peaks
0.50
0.48
0.50
0.51
0.50
1
05-1.43
1.13
2.30
5.00
1.50
3.00
1.17
0.67
0.60
1.50
0.17
05-1.43
1.30
1.24
1.21
1.21
1.21
1.32
1.24
.88-1.20
1.00
0.84
1.10
.37-0.51
0.79
0.41
0.42
349.73 116.36
0.62 0.20
415.42 138.46
0.98 0.33
324.41 108.00
,421.83
0.17
0.22
0.11
0.13
0.18
0.13
0.07
0.05
0.04
0.04
O..QO
0.23
1.50 0.83
272.54 149.14
319.20 175.05
376.77 205.99
0.51 0.29
0.56 0.31
971.08
0.24
1.20
0,21
0.00
0.27
256.84 74.52
226.13 66.79
482.97
233.37 1.000 13C12-HXCDF 678
0,42 1.010
276.96 1.016 13C12-HXCDF 234
0.65 1.021
216.41 1.040 13C12-HXCDF 789
0.958-1.014
0.000
0.977
0.979
0.982
0.995
0.999 123478-HxCDD
1.003
1.007
1.012 123789-HxCDD
1.013
0.970-1.030
0.000
0.67 0.983
123.40 0.998 13C12-HXCDD 478
144.15 1.000 13C12-HXCDD 678
170.78 1.010 13C12-HXCDD 789
0.22 1.018
0.25 1.023
0.997-1.051
0.000
1.000
1.011
0.944-1.112
0.000
182.32 1.000 13C12-HpCDF 678
159.34 1.045 13C12-HpCDF 789
IS4
ALT2
ALT1
AN
AN
SOR3
135
RS2
136
SUR4
HpCDD
424-426
DC NL
DC SN
DC SN
0.
0:00 RO
36:53 RO
37:01
88-1.20
1.25
0.42
0.88
: nfcH- jjr /
0.16
0.16
0.15
/ HpCDD Follows
0.976-1.005
0.000
1.001 1234678-HpCDD AN
1.005
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 « Fax: (919) 544-5491
Printed: 20:27 04/20/98
-------
Page No.
04/20/98
Listing of S982307B.db£
Matched GC Peaks / Ratio / Ret. Time
Compound/
MJZ.... QC.iog Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name,. ID.. Flags.
424-426
DC
DC
WH 37:08
WH 37:17 RO
0 Peaks
1.00
2.67
0.16
0,06
0.00
1.008
1.012
13C12-HpCDD 0.88-1.20
436-438 DC NL 0:00 1.06 0.33
36:51 1.02 294.43
DC SN 37i08 RO 1.67 0.37
436-438 1 Peak 294.43
148.47
0.973-1.027
0.000
145.96 1.000 13C12-Hfc>CDD 678 IS7
1.008
OCDF
442-444
442-444
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
WL
SN
SN
SN
SN
SN
SN
SN
SN
0
Oi
36:
36:
37:
40:
40:
40:
40:
42:
42:
;00
:38
:46
:53
:10
:34
:37
:55
:29
;42
0.
RO
RO
RO
RO
RO
SO
RO
RO
76-1.02
0.
0,
0.
0.
0.
0.
0,
0.
0.
1.
.90
.41
.38
,38
,29
,23
,67
,29
.70
.00
Peaks
Above: HpCDD / OeCa-CDD and CDF Follows
0.902-1.098
0.19 0.000
0,19 0.899
0.06 0.902
0.11 0.930
0.08 0.986
0.06 0.996
0.08 0.997
0.23 1.004
0.15 1.043
0,20 1.048
0.00
OCDD
458-460
458-460
0.76-1.02
DC NL 0:00 1.00
d SN 40:48 RO 1.24
0 Peaks
0,16
0.47
0.00
0.902-1.098
0.000
1.001
13C12-OCDD 0.76-1.02
470-472 DC NL 0:00 1.00 0.14
40:45 0.86 449.78
DC WH 41:17 RO 0.53 0,64
470-472 1 Peak 449.78
207.59
0.996-1.004
0.000
242.19 1.000 13C12-OCDD
1.013
IS8
Column Description. "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time jmrtussj
Rat.1 -Ratio of M/M+2 Ions
OK -RO=Raeio Outside Limits
Rel.RT-Relative Retention Time
End of Report ***
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
ile:S9S2307 #1-746 AcqsiB-APR-1998 12:55:25 Eli- Voltage SIB 70S Noise:49
03.9016 Fi2 BSUB(256r30,-3.0) PKB(9r5,5, 0 , 05%,196. 0, 1. 00%,F, T) ExpsNDBSUS
TRIANGLE lABS Text:TLI#45399 M23-FB-1 JIW. TIME = 12s58
1003, -'•, ,
23':00 24:00 25:00 26:00
File:S982307 #1-746 Acq:lS-APS-199S 12:55:25 EI+ Voltage SIS 70S Noise:46
305.8987 F:2 BSUB(256f 30, -3. 0) fXD(9,5,5r 0.05%, 184.0, 1. 00%, F, T) Exp:M!B5US
TRIANGLE LABS Text :TLI*45 399 H23-FS-1 , - . - TMT
100% " A3.25E3
TT
23:00 24:00 25:00 26:00
F±le:S982307 #1-745 Acqtl8-APS-1998 12:55:25 EI+ Voltage SIS 70S Noiae:48
315,9419 Fs2 BSUB(256,30,-3.0) PKD(9, 5, 5,0. 051,192. 0,1.00*,r,T) Exp:m>B5US
TKIANSLS LABS Text:'n,I#4$399 M23-FB-1 HKT. TIME = 12:58
1001 ; A2.29E6
ao'- I :;•
40:.
23:00 24:00 25:00 \ 26:00
File:S9B2307 #1-746 Ac
-------
File:S9a2307 #1-746 Acq:18-APR-1998 12:55:25
EI+ Voltage
SIS JOS Noise -.41
319.8965 F-.2 BSOB(256,30r-3.0) PKD< 7, 5,3, 0 . 05%,1S4 . 0,1 . 00%,F , T) ExpsNDBSUS
TRIANGLE LABS Text:TLI#45399 M23-FB-1
1003
aol
sol
401
201
0'
A3.
A1.64E3
IA337.17 ' i It
-1 1 1 , 1 1 , 1 1 1 1 1 —
24:00 • 25:00
File:S982307 #1-746 Acq:18-APR-1998 12:55:25
14E3
A726.66
I i
SMv;
:::::«":::":t::::::":::: ( , ----•
EI+ Voltage
INJ. TIME = 12:58
Al . 03E3
A1.5BE3 I i
I i M 4/S50 34 1 jl 1 1
J1fwv^MvM^
-8.1E2
'-6.5E2
"-4.9E2
13 . 3E2
11 . 6E2
\O.OEO
26:00 ' 27:00 Time
SIS 70S Noise: 41 ,-~r\ ^,
321.8936 F:2 BSUB(256, 30, -3 '. 0) PKD(7, 5,3, 0 . 05%,1<>4 . 0,1. 00%, F, T} Sxp:NDB5US vC, V^i
TRIANGLE LABS Text:TLI#45399 M23-FB-1 INJ. TIME = 12:58 C\ % ^
1004
80:
601
401
201
'
,
fel V^V^A/^^^A-^-A^^^V^^V^ VV/VAW-~V/
24:00 ' ' '-' ' ' 25:00
File:S982307 #1-746 Acq: 18-APR-1998 12:55:25
A804.69
VlwHyv"^
EI+ Voltage
Lv 1 . 6E3
*^*'
-------
File:S9S2307 #1-746 Acq:18-APK~1998 12:55:25 EH- Voltage SIS 70S Noise:41
39.8597 Fs2 BSUB(256,30, -3.0) PKZ>(7,5,3,0.05%,164.0,1.00*,F,T) ExpsNDBSUS
TRIANGLE LABS Text:TLI#45399 M23-FB-1 JMT. TIME = 12:58
100% A1.27E3
28:00 29:00 30:00
File :S9 8.23 07 #1-746 Acq:18-APR-1998 12:55:23 EI+ Voltage SIR 70S Noise:42
341.8567 F:2 BSUB( 256, 30, -3 . 0) PKD(7,5,3,0 .051,168.0,1.OOl,F,T) EzptNDBSUS
TRIANGLE LABS Text:TLI#45399 M23-FB-1 XNJ. TIME = 12:58
28:00 29:00 30:00
F±le:SS82307 #1-746 Acqil8-APR-1998 12:55:25 EI+ Voltage SIS 70S Noise:47
351.9000 F:2 BSUB(256, 30,-3.0) PKD(7,5,3, 0. 054,188. 0,1. 00%, F, T) Exp-.SEBSUS
TRIANGLE LABS Text:TLI#45399 M23-FB-1 IJK7. TIME = 12:58
A547.88 A1.31E3
A827.ll
31:00
1003
40
201
Al. 79E3
A1.44E3
A6B0.41
Al. 76E3
~r
~r
31:00
!00*
80J
601
401
201
OJ
A2.34E6
A2.41E6
LL
28:00 .- 29:00 30:00
File:S982307 #1-746 Acq:18-APR-1998 12:55:25 EI+ Voltage SIR 70S Noise:46
353.8970 F:2 BSUB(256, 30/-3'. 0) PKD(7, 5,3, 0. 05%,184, 0,1. 00%,f, T) ExpsNDBSUS
TRIANGLE LABS Tezt:TLI#45399 M23-FB-1 INJ. TIME - 12s58
31: 00
1004
80J
40
o
Al.53E6
R1.57E6
28tOO 29:00 30:00
File:S9S2307 #1-746 Acq:18-APR-1998 12:55:25 EH- Voltage SIR 70S
330.9792 F:2 Eip:NDB5US
TRIANGLE LABS Teit:TLI#4'5399 M23-FB-1 JKJ. TIME = 12:58
1004 ' ' 29:20 30.og
27:14 27:31 27:48 '•• 28:J.4 28±3828iS2 29:10/\ ,3?-.38 29:54 /V 30s26
80S
601
201
oJ
31:00
~r
~r
28:00. 29:00 30:00
File:S982307 #1-746 Acqsl8-APR-199B 12:55:25 EI+ Voltage SIR 70S
409.7974 F:2 Eip:NDB5US
TRIANGLE LABS Teit:TLI#45399 M23-FB-1 IKT. TIME = 12:58
Jl.- 00
100S
80J
60J
40-
201
0.
28:24
29:10
28:00
29:00
30:00
31:00
6.7E2
IS, 4E2
L4.0E2
L2.7E2
11,3E2
LO.OEO
Time
.6.5E2
.5.2E2
.3 . 9E2
.2.6E2
.1. 3E2
.O.OEO
Time
.7.4E5
.5. 9E5
.4.4E5
.3.0E5
.1.5E5
.O.OEO
Time
.4.9E5
.3.9E5
.2.9E5
.2.0E5
.9.8E4
.O.OEO
Time
.1. 3E6
.1. OE6
.7.7E5
.5.1E5
.2.6E5
.O.OEO
Tim>
.2.0E3
.1. 6E3
.1.2E3
.8.0E2
.4.0E2
.O.OEO
Tim
306
-------
File:S$82307 #1-746 Acq:18-APR-l996 12:55:25 EH- Voltage SIR 70s Noise:44
355.8546 F:2 BSUB(256, 30, -3 . 0) PKD( 7, 5,3, 0 . 05%, 1 76. 0,1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-FB-1 INJ. TIME = 12:58
1003
SO:
A3.
O.OEO
28': 24 28': 36 28-48 29:00 29:12 29-24 29': 36 29-48 30-00 30-12 30:24 30':36 30':48 31-00 311-12 Time
File:S9S2307 #1-746 Acq:1S-APR-1998 12:55:25 EI+ Voltage SIR 70S Noise:52
357.8516 F:2 BSUB(256, 30,-3 . 0) PKD( 7,5,3,0 .05^,208.0 , 1.00%,F,T) Exp:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-FB-1 ZWJ. TIME = 12:58
1003 -7.5E2
O.OEO
28-24 28:36 28-48 29:00 29': 12 29': 24 29:36 29:48 30:00 30:12 30:24 30': 36 30':48 31:00 31:12 Time
F±le:S982307 #1-746 Acq:18-APR-1998 12:55:25 EI+ Voltage SIR 70S Noise:43
367.8949 F:2 BSUB(256, 30, -3 . 0) PKD( 7, 5,3, 0 . 05%, 1 72. 0, 1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-FB-1 INJ. TIME = 12:58
100% A1.53E6 r.4.8E5
.3. 8E5
-2.9E5
11.9E5
'.9. 5E4
401
20",
01
O.OEO
. 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00
File:S982307 #1-746 Acq: 18-APR-1998 12:55:25 EI+ Voltage SIR 70S Noise:32
369.8919 F:2 BSUB(256,30,-3 .0 ) PKD( 7, 5,3, 0 . 05*,128 . 0, 1. 00%,F, T) Eip:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-FB-1 INJ. TIME = 12:58
31:12 Time
003
so:
601
40_
20_
0
Al . 03E6
'• n
' f\
\ AS . 53E4
7 \/V
-3.2E5
_2.5E5
_1 . 9E5
_1 . 3E5
_6.4E4
O.OEO
28:24 28:36 28:48 29:00. 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00
File:S982307 #1-746 Acq:18-APR-1998 12:55:25 EI+ Voltage SIR 70S
330.9792 F-.2 Eip:NDB5US '
TRIANGLE LABS Text:TLI#45399 M23-FB-1 IWJ. TIME = 12:58
1003, 29:20 ,- -„
/\ 29-32 30:09
28^38 28:52 29:10 / V /V^^_ 25:47 29j 58 yX-^_ 30:26 30:40 30:53 31_
so:
601
401
201
0.
31:12 Time
05
1. 3E6
11. OE6
17.7E5
15.1E5
12.6E5
.O.OEO
i 28:24 28:36 28:48 29:00; 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00 31:12 Time
307
-------
'ile:S982307 #1-465 Acq:18-APS-199B 12:55:25 EH- Voltage SIS 70S NoiseiSS
'73.8208 r-.3 BSUB(256r30,-3.0) PKD( 7,5, 3, 0 . 05%,236. 0, 1. 00%,F, T) Exp:NDB5US
TRIANGLE LASS Text:TLX#45399 M23-FB-1 J1KT. TIME = 12:58
i i i i i [ i i i i i I t i i t i | i i i i i I i i i '' i j1 ( I ' ' ' 1 ' ' i ' ' 1 ' ..... i I ..... ; i i i i i I i i i i i i'1'i i > i i i i i i i r'l
31:36 31-43 32:00 32:12 32:24 32:36 32:43 33:00 33:12 33:24 33:36 33:48 34:00 34:12 34:24 34:36
File:S982307 #1-465 Acq:18-APR-199B 12:55:25 EI+ Voltage SIS 70S Naisei45
375.8178 F:3 BSUB(256, 30, -3.0) PKE{ 7,5,3, 0. 05%, 180. 0,1. 00%,F, T) Exp:NBBSUS
TRIANGLE LABS Text : TLX #4 5 3 9 9 M23-FB-1 IJKT. TIME = 12s 58
1003, A926.83
76E3
A758.74
A6S5.65 A458.91
A324.23
i I
,6E2
,1E2
.6E2
.1E2 '
.5E2
,OEO
Time
A808.36
A479.45A48B.43
31:36 31-48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34:12 34:24 34:36
F±le:S982307 #1-465 Acq:18-APR-1998 12:55:25 EI+ Voltage SIS 70S Noise:S2
383.8639 Fs3 BSUB(256,30,-3.0) PKD(7,5,3, 0 . 05%, 328. 0, 1, 00%,F, T) Exp:NDB5US
TRIANGLE LASS Text:TLH45399 M23-FB-1 . JKT, TIME = 1,2:58
A1.38E6
A1.16E6
60
40J
201
OJ
A1.08E6
-3.
13.
'.2
11.
10
31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34:12 34:24 34:36
File:S982307 #1-465 Acq:lB-APR-199B 12:55:25 EI+ Voltage SIR 70S Noise:101
385.8610 Fs3 BSUB(256, 30, -3. 0) PKD( 7, 5, 3, 0 . 05%, 404. 0,1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Text:TLIt45399 M23-JFB-1 JKT. TIME = 12:58
1003j A2.77E6
A2.33E6
40
201
ol
A2.16E6
31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34:12 34:24 34:36
File:S9S2307 #1-465 Acq:lB-APS-199S 12:55:25 EI+ Voltage SIR 70S
392.9760 F:3 Ezp:NDB5US
TRIANGLE LABS Text:TLX#45399 M23-FB-1 JKT. TIME = 12:58
100^ 31:49 tj.nK ,- --Pi]?5 33:16 11.10 33:51
.^.^X^X-^ ffi! a£-17^ 32:31 _ l£jj!?XV -~^- 33:2a
80J
60J
40J
20J
ol
•31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34:12 34:24 34:36
file:S982307 #1-465 Acq:18-APR-1998 12:55:25 EX+ Voltage SIR 70S
445.7555 F:3 Exp:NDB5US
TRIANGLE LASS Text:TLHf45399 M23-FS-1 INJ. TIME = 12:58
1003k ' ••
3i-*s 32'04 ;. 3T -=02
9E5
1E5
4E5
6E5
SE4
OEO
Time
OE5
,4E5
,8E5
.2E5
.6E5
.OEO
Time
.8E5
.7E5
.5E5
,3E5
,2E5
.OEO
Time
ao
eol
401
201
ol
31:431
32:18
34:25
31':36' 311-48' 32.1 Oo'32:12'32!24'32l36'32Us' 33! 00'33:12' 331-24' 33:36'
34:00 34:12 34:24 34:36
5E3
2E3
1E2
1E2
OE2
OEO
Tim,
-------
File:S982307 #1-465 Acq:18-APR-1998 12:55:25 EI+ Voltage SIR 70S Noise-.43
389.8156 F:3 BSUB(256, 30,-3 .0 ) PKD(7, 5, 3, 0 . 05%, 1 72. 0, 1. 001,F, T) Exp:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-FB-1 INJ. TIME = 12:58
1003:, A2.5.1E3
80.
eo:
40:
20L
—i—i—I—i—i—i—i—i—I—i—P-T—i—i—1—i—i—i—i—i—1—i—i—i—i—i—|—i—i—i—i—i—I—i—i—r—i—i—1—i—i—i—i—i—I—i—i—i—i—i—I—i—i—i—i—i—I—i—i—i—i—i—I—i—r
32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34:12
F±le:S982307 #1-465 Acq:18-APR-1998 12:55:25 EI+ Voltage SIR 70S Noise:41
391.8127 F:3 BSUB(256, 30,-3 .0) PKD( 7, 5, 3, 0 . 051,164 . 0, 1. 001,F, T) Exp:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-FB-1 INJ. TIME = 12:58
100$
Al. 79E3
374.24
9.1E2
7.3E2
.5.5E2
.3.6E2
.1. 8E2
.O.OEO
Time
32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48
F±le:S982307 #1-465 Acq: 18-APR-1998 12:55:25 EI+ Voltage SIR 70S Noise:63
401.8558 F:3 BSUB(256 , 30 ,-3 .0 ) PKD(7,5,3,0.051,252.0 , 1.001,F,T) Exp:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-FB-1 INJ. TIME = 12:58
1003, A2.Q6E6
Al. 75E6
801
601
40:
20.
34 : 00
34:12
32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48
File:S982307 #1-465 Acq:18-APR-1998 12:55:25 EI+ Voltage SIR 70S Noise:50
403.8529 F:3 BSUB(256, 30,-3 .0 ) PKD(7, 5, 3, 0 . 05%,200 . 0, 1. 001,F, T) Exp:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-FB-1 INJ. TIME = 12:58
1003, A1.71E6
; A1.44E6
so:
60-
40:
20:
oj '
34 : 00
34:12
32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48
File:S982307 #1-465 Acq:18-APR-1998 12:55:25 EI+ Voltage SIR 70S
392.9760 F:3 Exp:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-FB-1 INJ. TIME = 12:58
100%
80.
60.
40.
20.
0.
33:51
34 : 00
34:00
34:12
32:12 32:24 32:36
32:48
33:00
33:12 33:24 33:36 33:48
34 : 00
34:12
.O.OEO
Time
.5.3E5
.4.2E5
.3.2E5
.2.1E5
.1.1E5
.O.OEO
Time
.4.5E5
.3. 6E5
.2.7E5
.1. 8E5
.8.9E4
.O.OEO
Time
.5.8E5
.4.7E5
.3.5E5
.2.3E5
.1. 2E5
.O.OEO
Time
-------
'ile:S982307 #1-569 Acgs 18-APR-1998 12:55:25 EI+ Voltage SIR 70S Noiae:61
07.7818 Fs4 BSUB(256,3Q, -3 ;0) PKD(7,5,3, 0. 051,244 . 0, 1. 00%,F, T) Exp:lH>B5US
TRIANGLE LABS Text:TLI#45399 M23-FB-1 XK7. TIME = 12:58
1003,
35:48 36:00 36:12 36:24
File;S982307 #1-569 Acg:18-APR-1998 12s
409.7769 F:4 BSUBf 256, 30, -3 . 0) PKD(7,5,
TRIANGLE LABS Text:ZLI#45399 M23-FB-1
IOCS A7.29E3
801
60:
J5.-48 36.-00 36:12 3S.-24
FilesS982307 #1-569 Acq:18-APK-1998 12
417.8253 F:4 BSOB(256,30,-3.0) PKD(7,5
TRIANGLE LABS Teit:TLI#45399 M23-FB-1
100* A7.45E5
a 01
601
401
201
01
36i36 36:48 37:00 37:12 37:24
55:25 EI+ Voltage SIS 70S Noise:62
3,0.05%,248.Q,1.QO\,W,T) Exp:NDB5US
IMT. TIME = 12:58
37:36 37:48
401
20:
Al.03E3
>Wx
' '36136' ' '36148 ' '37^00 ' '37^12 ' '37\24
155:25 EH- Voltage SIS 70S Noise: 77
.3,0.05%, 308. 0,1. 00%,F,T) Exp'.NVBSUS
INJ-. TIME = 12:58
A6.68E5
37:36
'37^48
35:48 36:00 36:12 36:24
F±le:S982307 #1-569 Acq:18-APR-1998 12
419.8220 F:4 BSUB(256, 30, -3.0) PKD(7,5
TRIANGLE LABS Teit:TLI#45399 M23-FB-1
1003, A1.82E6
8 Ol
36:36 36:48 37:00 37:12 37:24
:55:25 EI+ Voltage SIR 70S Noise:95
,3, 0.05%, 380.0,1. 00%,F, T) Exp:m>B5US
INJ-. TIME = 12.-58
Al.59E6
37:36
37:46
35:48 36:00 36:12 36:24
F±le:S9B2307 #1-569 Acq:ia-APR-1998 12.
430.9729 F:4 Exp:NDB5VS
TRIANGLE LABS Text:TLI#45399 M23-FB-1
36:36 36:48 37:00
55i25 EI+ Voltage SIR 70S
37-12 37':24
37:36
37:48
801
601
401
201
Ol
ISKT. TIME = 12:58
37:16 37:28
. 0. OEO
riffle
2.3E3
.1. 9E3
.1. 4E3
.9. 3E2
.4 . 7E2
.O.OEO
Time
.1. 5E5
.1.2E5
.8.9E4
.5.9E4
.3. OE4
.O.OEO
Tint i
3.5E5
2.8E5
2.1E5
LI. 4E5
1?.1E4
O.OEO
i i i * i—r-T—i—t i i—i—r~|—i—E~~I—i—T~™T—T—r
35:48 36:00 36:12 36:24
File:S982307 «-569 AcqslB-APR-1998 12
479.7165 f:4 Exp:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-FB-1
1003,
i i I i "' i ' <• I i 'i"" i i i | i i i i i i- i i i i -I i i""i i i i i i i i i i
36:36 36:48 37:00 37:12 37;24 37:36 37.-4S
.3. S.E5
.3. OJJ5
.2.3E5
.1. 5E5
.7.5E4
55:25 EI+ Voltage SIS 70S
35:48
36:00
36:12 36:24
36:36 3646
310
-------
File:S982367 $1-569 Acqs'l'a"-APR-li96":l2!55:V5 SI+ Voltage SIM 70S Noise:50'
423.7766 F.-4 BSUB( 256, 30, -3 . 0) PKD( 7, 5, 3, 0. 05%, 200. 0,1. 00%, f, T) Exp:NDB5US
TRIANGLE LASS Text:TLI#45399 M23-FB-1 IKJ. TIME = 12:58
1004
so:
6ft
401
20:
36-00 36:06 36-12 36-18 36:24 36:30 36:36 36:42 36:48 36:54 37:00 37:06 37:12 37:18
File:S982307 #1-569 Acqiia-APX-1998 12:55:25 EH- Voltage SIS 70S Noiae;4Q
425.7737 F;4 BSUB(256,30,-3.0) PKD(7, S,3, 0. 05%,ISO. 0,1. 00%,F, T) Eip:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-FB-1 ZWJ. TIME = 12:58
100*
19. 3E2
17.0E2
"-4.6E2
12.3E2
80.
601
401
20.
Al.90E3
A766.47
AB03.87
A446.38
R347.7'
i i i i i i i i i i i i i i i i i i I i i i i -i'1-r'TT i i 'i i' i i i i | i i i i i ) i i i i i | i i i i i | i i i < i i <-i i i i ) i i i-i-i i -i \ i i i | i i i
36:00 36:06 36:12 36:18 36:24 36:30 36:36 36:42 36:48 36:54 37:00 37:06 37:12 37:18
F±le:S982307 #1-569 Acq: 1B-APR-1998 12:55:25 EI+ Voltage SIS 70S Noises83
435.8169 Fs4 BSUB(256,30, -3. 0) PKV( 7, 5,3, 0 . 05%, 332. 0, 1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-FB-1 IKJ. TIME = 12:58
1004 A1.48E6
801
601
401
201
i r T' l""T'"T*"j i i i i i i i l l i i i \ i i i r;""i"i ft i i i i i i i 1 i'' i i i | i i P i i i i i i i i \ i i i i i i i' i 'l"'!| i i i i i i i i""i "] I" I i I i i i
36:00 36:06 36:12 36:18 36:24 36:30 36:36 36:42 36:48 36:54 37:00 37:06 37:12 37:18
F±lesS982307 #1-569 flcgr:18-^PJ?-1998 12:55:25 £1+ Voltage SIS 70S Noise-.Sl
437.8140 F:4 BSUB(256,30,-3 .0 ) PKD{ 7,5,3, 0. C5%,324 . 0,1. 00%,F, T) Eip:NDB5US
TRIANGLE LABS Texts TLIf 45399 M23-FB-1 IKJ. TIME - 12:58
1004 A1.46E6
801
601
01
36:00 36:06 36:12 36:18 36:24 36:30 36:36 36:42 3
-------
File:S982307 #1-565 Acqsl8-APS-1998 12:55:25 SI+ Voltage SIS 70S Jfoise:47
441.7428 F.-4 BSUB(2S6,30, -3. 0) PKD< 7, 5,3, 0.05%, 188. 0, 1. 00%,F, T) Exp:NDB5VS
TRIANGLE LABS Text:TLI#45399 M23-FB-1 INJ. TIME = 12:58
1002j ' 2.5E4
901
801
701
601
501
401
30.
20.
101
0
file
443.
TKIAj
1003
901
801
701
601
sol
401
301
201
10.
o'-
File
430.
TSIA
1003
901
801
701
601
501
401
301
201
101
0
File
513.
TRIA
1003
901
ao'i
701
601
SOI
401
301
201
101
0-
-
~36{:00 ' ' ' 37:00 ' ' ' 38:00
•.S982307 #1-559 Acg;18-APX-199S 13:
7399 F:4 BSUB(256,30f-3.0) PKD(7,5,
MGLE LABS Text sTLI #45399 M23-FB-1
,
.
36:00 37:00 38:00
:S982307 #1-569 Acg:lS-APK-1998 12:
9729 Fs4 EXp:NDB5US
NGLE LABS Text:TLI#45399 M23-FS-1
35:53 36l32 37:28 f^
l/V'XAv^/*^^^
36:00 ' ' ' 37-00 ' ' ' 38.- 00
-.S982307 #1-569 Acq:18-APS-1998 12
6775 F:4 Exp:NDB5VS
JTGLE LABS TextsTLI#45399 M23-FB-1
36:04 ": 38
^v<**A-AA»~%jb>A4jU/'<'^v^^
36:00 ' ' 37:00 ' ' 38:00
~JU.
_2.2£4
_2.0E4
_1 , 7E4
_1 . 5E4
_1.2E4
-9 . 9E3
-7.5E3
_5 . OE3
L2.5JT3
: 0 . 0£0
39:00 ' ' ' 40;00 ' ' ' 41:00 ' ' 42:00 Time
55:25 EH- Voltage SIM 70S Soiae:49
3,0.05%, 196. 0,1. 00%, F,T) ExpiNDBSUS
IKJ. TIME = 12:58
1 . 8E4
^^JSvVv,,^^ A.
39:00 40:00 41:00 42:00
55:25 EI+ Voltage SIS 70S
JJKT. TIME = 12:58
10 38-37 39:54 40:38 41:35
^^S*V*^n^M^^^
1 I 1 i j i s -I I tl f t . , i j 1 1 1 1 1 1 T- 1 1 1
35:00 40:00 41:00 42:00
55:25 EI+ Voltage SIS 70S
JKT. TJME = 12:58
.-13 39:00 39..JI , j 41.-28
4*•~vM^»A^vA•*AA^rf**A4^JU^
39sOO ' ' ' 4o!-00 ' ' ' 4l!-00 ' ' ' 42:00
Ll . 6E4
L1.4E4
Ll . 3E4
"-1.1E4
L9.1E3
L 7 . 2E3
L5 . 4E3
L3.6£3
Ll . 8E3
: 0 . OEO
Time
3 . 9E5
13.5E5
L3.1E5
L2.7E5
L2.3E5
L2.0£5
Ll . 6E5
Ll . 2E5
L7.SE4
L3.9E4
"• 0 . OEO
Time
4.0E3
L3 . 6E3
_3.2E3
.2.8E3
.2.4E3
.2.0E3
.1 , 6E3
'.1.2E3
-8.1E2
L4 . OE2
'• 0 . OEO
Time
31
-------
FiIe:S9S2307 #1-569 Acq:lB-APR-1998 12:55:25 EI+ Voltage SIR 70s Noise:40
457.7377 F:4 BSUB(256, 30,-3 . 0) PKD(7, 5, 3, 0 . 05%, 160. 0, 1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-FB-1 INJ. TIME = 12:58
1003s . A3.06E3
40-36 40-42 40:48 40:54 41:00 41:06
File:S982307 #1-569 Acq:18-APR-199B 12:55:25 EI+ Voltage SIR 70S Noise:39
459.7348 F-.4 BSUB(256, 30, -3 . 0) PKD(7,-5,3, 0 . 05%,156. 0, 1. 00%,F, T) Eip:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-FB-1 INJ. TIME = 12:58
100% A2.52E3
A1.91E3
41:12
40-36 40-42 40:48 40:54 41:00 41:06
F±le:S9B2307 #1-569 Acq:18-APR-199B 12:55:25 EI+ Voltage SIR 70S Noise:34
469.7779 F:4 BSUB(256, 30,-3 .0 ) PKV(7, 5, 3, 0 . 05%, 136. 0, 1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Text: TLI#45399 M23-FB-1 INJ. TIME = 12:58
100S A2.Q8E6
41:12
40-36 40:42 40-48 40:54 41:00 41:06
File:S982307 #1-569 Acq:18-APR-1998 12:55:25 EI+ Voltage SIS 70S Noise:35
471.7750 F-.4 BSUB(256, 30, -3 . 0) PKV(7, 5, 3, 0. 05%, 140. 0, 1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-FB-1 INJ. TIME = 12:58
1002, A2.12E6
801
601
401
201
41:12
40-36 40:42 40:48 40:54 41:00
File:S982307 #1-569 Acq: 18-APR-1998 12:55:25 EI+ Voltage SIS 70S
430.9729 F-.4 Ejcp:NDB5US
TRIANGLE LABS Teit.:TLI#45399 M23-FB-1 INJ~. TIME =
1003, 40jJ}8 40-44 40s52 40:55
41:06
41:12
12:58
401
201
41:10
4.9E2
4 . OE2
3 . OE2
2.0E2
9.9E1
O.OEO
Time
40-36
40:42
40:48
40:54
41: 00
41:06
41:12
.O.OEO
Time
2.0E5
1. 6E5
.1. 2E5
.8.0E4
.4.0E4
.O.OEO
Time
.3. 8E5
.3. OE5
.2.3E5
.1. 5E5
.7.5E4
.O.OEO
Time
31T
-------
Channel I 338,3792 Peak top
Help}* ,33 volts Span 288 opt
Systet file naieiH"
Data filename fi=S982384
Resolution
Group nuiber
lonlzatlm Mde
Switching
a
EI+
VOLlffi
Ref, lasses 282,9825, 416,9788
fl 293 J 331 S 388
K 332
L 334
B 384
C 386
D 316
I 313
F 328
6 322
H 328
I 331
1 348
N 342
0 352
P 354
6 356
i 358
T m
U 371
V 418
Ref, uss 416,9768 Peak top
Height ,88 volts .Span 288 pp
314
-------
TLI Project: 45399
Client Sample: M23-FB-2
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S982308
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
r012.Q02/Lime Kiln
M23
204-92-10A-D
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
04/01/98
04/03/98
04/18/98
n/a
U980780
DL
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPMIT204
SF51078
S982303
n/a
n/a
n/a
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
rotate
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
ND
ND
ND
ND
ND
ND
ND
0.005
ND
ND
ND
ND
ND
ND
ND
ND
ND
Arnt (ng)
ND
ND
ND
ND
0.005
ND
ND
ND
0.004
0.005
0.006
0.006
0.006
0.009
0.65 25:16 JB_
0.004
0.004
0,004
0.004
0.004
0.004
0.005
0.006
0.006
Number m, EMPC Flags
0.004
0.005
0.006
0.006 .
1
0.004
0.004
0.005
Page 1 Of 2 MnXPSRvl,04,LARS6.1l.OO
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:27,04^20/98
315
-------
TLI Project: 45399
Client Sample: M23-FB-2
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S982308
13Ci2-2,3J,8-TCDF
l3C,2-2,3,7,8-TCDD
I3C12-l,2(3,7,8-PeCDF
13C,i-l,2,3,7,8-PeCDD
'3C,2-l,2,3,6,7,8-HxCDF
13C,2-l,2,3,6,7,8-HxCDD
l3C,2-l,2,3A6,7,8-HpCDF
13C,2-l,2,3,4,6J,8-HpCDD
13C12-1,2,3,4,6,7,8,9-OCDD
2,8
2.6
2.9
3.8
3.9
4,2
4.1
5.3
9.1
70.4
66.2
72.1
95.3
96.7
104
102
133
114
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
0.72
0.79
1.50
1.45
0.52
1.20
0.42
0.98
0.84
25:15
25:57
29:10
30:13
32:45
33:27
35:46
36:51
40:44
13C,2-2,3,4J,8-PeCDF
'3Ci2-l,2,3,4,7,8-HxCDF
13C,2-l,2,3,4,7,8-HxCDD
l3Ci2-l,2,3A7J,9-HpCDF
4.3
3.4
3.4
3.3
107
84.6
85.0
82.6
40%-130%
40%-130%
40%-130%
25%-130%
1.51
0.48
1.21
0.41
29:52
32:39
33:22
37:23
37Cl4-2,3,7,8-TCDD
3.7
92.1
40%-130%
25:58
gp?:^:;!;Hi:^^^g$g;^gmgg^^g^^^^^^s;j^M^^^^
13Cl2-l,2,3,7,8,9-HxCDF
13Cir2,3,4,6,7,8-HxCDF
3.4
3.5
85.6
87.6
40%-130%
40%-130%
0.50
0.50
34:03
33:15
dill
13C,2-1,2,3,4-TCDD
13Ci2-l!2,3,7,8,9-HxCDD
0.80
1.20
25:47
33:47
Data Reviewer:
04/20/98
Page 2 of 2
MTT2_PSR vl .04. LARS 6,11.00
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:27
-------
Initial
. .Date. . .
Data Review By:
Calculated Noise Area:
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
0,16
Page No.
04/20/98
Listing of S982308B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why .,RT. OK Ratio Total.Area... Area.Peak.1., Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
304-306
13C12-TCDF
316-318
316-318
TCDO
320-322
320-322
37C1-TCDD
328
DC NL 0:
25:
00
16
0.
RO
65-
1.
0.
0.89
27
65
1 Peak
DC NL 0 :
DC WL 24:
24:
24:
25:
25:
00
12
31
50
15
40
0.
RO
RO
65-
1.
0.
0.
0.
0,
0.
4 Peaks
DC NL 0:
DC SN 23 :
DC SN 23:
DC SN 25:
DC SN 25:
DC SN 25:
DC SN 26:
DC SN 26:
DC WH 27:
00
44
51
14
19
59
:06
54
30
0.
RO
RO
RO
RO
RO
RO
RO
RO
65-
0.
2.
1.
5.
2.
0.
1.
4.
0.
0.89
00
79
73
75
72
93
0.89
90
00
29
75
50
35
75
50
88
0 Peaks
0.873-1.075
0.
0.
0.
0.
12.
1.
3.
484.
1.
491.
Tf^rvP
I \-LtE
0.
0.
0.
0.
0.
0,
0.
0.
0.
0.
19
84 0.33
84
21
96
47 0.62
35 1.44
83 202.35
43 0.75
08
18
11
12
07
04
21
14
04
32
,00
0.
0.51 1.
0.960-
0.
0.
0.85 0.
1.91 0.
282.48 1.
0,81 1.
0,899-
0.
0.
0.
0.
0.
1.
I.
I.
1.
000
001 2378-TCDF
1.040
000
958
971
983
000 13C12-2378-TCDF
017
1.046
000
915
919
972
976
001 2378-TCDD
006
037
060
AN
ISO
AN
0.923-1.077
DC NL 0:
24:
:00
:37
25:58
26:
:17
26:37
328
13C12-TCDD
332-334
332-334
4 Peaks
DC NL 0
24
25
25
26
:00
:47
:47
:57
0
RO
0,
1.
306.
0.
0,
308,
.12
,45 1.45
.20 306.20
,21 0.21
.35 0.35
,21
.65-0.89
1,
,92
0.88
0.
.80
0.79
:17 0.70
4 Peaks
0
2
480
350
5
837
.21
.29 1.07
.06 213.44
.28 155.00
.21 2.15
.84
0.
0.
1.
1.
1.
000
949
001 37C1-TCDD
013
026
CLS
0.923-1.077
0.
1.22 0.
266.62 0.
000
955
994 13C12-1234-TCDD
195.28 1.000 13C12-2378-TCDD
RSI
IS1
3.06 1.013
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:27 04/20/98
-------
Page No. 2
04/20/98
Compound/
M_Z .... QC, Log
PeCDF
340-342
340-342
13C12-PeCDF
352-354
352-354
PeCDD
356-358
356-358
13C12-PeCDD
368-370
368-370
Omit
Why
Listing of S9823Q8B.<3bf
Matched GC Peaks / Ratio
...RT. OK Ratio Total. Area.
/ Ret , Time
. . Area. Peak. 1 . . Area . Peak . 2 . . Rel
1.32-1.78
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
ML
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
6
NL
SN
SN
SN
SN
SN
SN
SN
SN
WH
HH
0
NL
SN
OiOO
28:19
28:39
28:48
29:11
29:35
29:48
29:52
30:02
30:12
30:26
30:33
30:59
Peaks
0:00
28:19
28:48
29:10
29:27
29:52
30:51
Peaks
0:00
28:25
28:31
28:40
28:53
29:09
29:22
29:36
30:28
30:54
31:00
Peaks
0:00
29:08
29:17
30:13
30:20
30:42
RO
RO
RO
RO
RO
SO
RO
RO
RO
RO
RO
RO
1.
RO
SO
0.
1.
0.
1.
3.
0.
0.
3.
0.
0.
0.
0,
0.
78
17
73
36
21
64
67
17
39
33
56
92
88
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
12
35
13
26
36
15
10
15
23
08
08
18
12
00
32-1.78
0.
1.
1.
89
62
00
1.50
1.55
RO
1.
,51
1.15
0.
22.
0.
13
49 13.89
89 0.54
372.42 223.57
3.72 2.26
386.
.14 232.37
1.25 0.76
.RT Compound. Name. . ID.. Flags
0.928-1.063
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
000
971
982
987
001 12378-PeCDF
014
022
024 23478-PeCDF
030
035
043
047
062
AN
AN
0.863-1.137
0.
8.60 0.
0.54 0.
148.85 1.
1.46 1.
153.77 1.
0.66 1
000
.971
.987
,000 13C12-PeCDF
.010
.024 13C12-PeCDF
.058
123 IS2
234 SDR1
786.91
1.
RO
RO
RO
RO
RO
RO
RO
RO
1
RO
RO
RO
RO
32-1.78
1
0
0
1
0
1
2
2
1
1
1
.50
.18
.83
.20
.73
.67
.33
.33
.06
.22
.71
0
0
0
0
0
0
0
0
0
0
0
0
.15
.07
.08
.20
.13
.32
.23
.08
.30
.18
,19
.00
.32-1.78
1
0
1
1
1
1
.14
.78
.28
.45
.45
.00
4 Peaks
0
0
0
273
23
0
297
.13
.63 0.38
.97 0.59
.08 161.56
.29 13.79
.31
.97
0.937-1.022
0
0
0
0
0
0
0
0
1
1
1
0.868
0
0.49 0
0.46 0
111.52 1
9.50 1
1
.000
.940
.944
.949
.956
.965
.972
.980
.008
.023
.026
-1.132
.000
.964
.969
.000 13C12-PeCDD
.004
.016
123 IS3
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:27 04/20/98
Q1 o
-------
Page No,
04/20/98
Listing of S982308B.dbt
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area,.. Area.Peak.1., Area.Peak.2, . Rel.RT Compound.Hame.. ID.. Flags.
HXCDF
374-376
D
374-376
13C12-HXCDF
384-386
384-386
HXCDD
390-392
390-392
13C12-HXCDD
402-404
"
DC
DC
DC
d
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SH
SN
SN
WH
0
NL
SN
SN
SN
9
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
SN
0:00
31:48
32:45
33:18
33:51
34:27
Peaks
0:00
31:40
31:48
32:39
32:45
33:06
33:15
33:25
34:03
34:20
34:23
34:27
34:34
Peaks
0:00
32:19
32:25
32:28
32:32
32:39
32:46
32:51
32:55
33:05
33:06
33:39
Peaks
0:00
32:49
33:05
33:22
33:27
33:47
33:59
1.
RO
RO
0.
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1
RO
RO
RO
RO
05-1.43
1.
1.
1.
1,
0.
0.
06
.33
.14
.18
.53
,58
0.
0.
0.
0.
0.
0.
0.
33
35
30
48
16
20
00
43-0.59
0.
0.
0,
0.
0,
0,
0,
0.
0,
0.
0
0
0
.94
.46
.51
.48
.52
.75
.50
.55
.50
.96
.50
.45
.28
05-1.43
1
0
0
0
1
1
6
4
1
0
1
0
.05
0
1
0
1
1
1
2
.13
.18
.83
.75
.20
.71
.20
.00
.00
.44
.50
.50
-1.43
.61
.46
.69
.21
.20
.20
.57
0.
5.
8.
303.
352.
0.
316.
1.
248.
0.
0.
0.
0.
1,235,
26
52 1.75
65 2.94
01 98.09
38 120.39
36
21 105.28
01 0.36
00 82.59
41 0.26
.66 0.22
45
.24
.85
0.963-
0.
0.
1.
1.
1.
1.
1.048
000
971
000 123678-HxCDF
017 234678-HxCDF
034
052
AN
AM
0.878-1.122
0.
3.77 0.
5.71 0.
204.92 0.
231.99 1.
1.
210,93 1.
0.65 1.
165.41 1.
0.27 1.
0.44 1.
1.
1.
000
967
971
997 13C12-HXCDF 478
000 13C12-HXCDF 678
Oil
015 13C12-HXCDF 234
020
040 13C12-HXCDF 789
048
050
052
055
SUR2
IS4
<2
ALT!
0,
0,
0,
0.
0.
0
0
0
0
0
0
0
0
,34
,04
.09
.05
.11
.38
.11
.04
.11
.07
.09
.13
.00
0.958-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
I.
1.014
000
966
969
971
973
976
980
982
984
989
990
006
f
0.970-1.030
0
2
0
214
274
285
0
.34
.11 1.37
.36
.22 117.48
.38 149.68
.94 156.10
.52 0.59
0.
0,94 0.
0.
96.74 0.
124.70 1.
000
981
989
998 13C12-HXCDD 478
000 13C12-HXCDD 678
129.84 1.010 13C12-HXCDD 789
0.23 1.
016
SUR3
IS5
RS2
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:27 04/20/98
319
-------
Page No.
04/20/98
Listing of S982308B,db£
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total. Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
402-404
HpCDF
408-410
408-410
13C12-HpCDP
418-420
418-420
HpCDD
424-426
424-426
13C12-HpCDD
436-433
436-438
DC SN 34:12 RO
DC SN 34:17
5 Peaks
0.
DC NL 0:00 RO
DC SN 35:55 RO
DC WH 37:38 RO
0 Peaks
0.
DC NL 0:00 RO
35:46
DC SN 36:01 RO
DC SN 36:10 RO
DC SN 36:21 80
37:23
2 Peaks
0
DC NL 0 : 00
DC SN 36:04
DC SN 36:11 RO
DC WH 37:19 RO
0 Peaks
0
DC NL 0:00
36:04
36:51
2 Peaks
0.74
1.07
88-1.20
1.25
4.50
2.71
37-0.51
1.44
0.42
0.69
1.20
1.25
0.41
.88-1.20
1.09
1.00
0.40
2.36
.88-1.20
1.12
1.08
0.98
0.36
0.29
777.17
0.33
0.20
0.14
0.00
0.23
246.67 72.85
0.37
0.22
0.17
163.17 47.48
409.84
0.23
0.26
0,08
0.22
0.00
0.36
2.93 1.52
281.68 139.70
284.61
1.022
1.025
0.997-1.051
O.OOQ
1.004
1.052
0.944-1.112
0.000
173.82 1.000 13C12-HpCDF 678 IS6
1.007
1.011
1.016
115.69 1.045 13C12-HpCDF 789 SUR4
0.976-1.005
O.OOQ
0.979
0.982
1.013
0.973-1.027
0,000
1.41 0.979
141.98 1.000 13C12-HpCDD 678 IS7
OCDF
442-444
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
WL
WL
WL
WL
WL
WL
SN
SN
SN
SN
SN
SN
0:
35:
35:
36:
36:
36:
36;
36:
36:
38;
38;
38:
41
00
43
49
13
:16
;21
;41
;49
:52
:12
:16
:32
:21
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
76-1.02
1.
0.
0.
1,
0,
0
3
0
2
6
2
4
1
.20
.75
.35
,33
.71
.80
.50
.92
.50
.00
.50
.25
.13
0.
0.
0.
0.
0.
0.
0.
0.
0.
0,
0,
0.
0
19
19
17
11
.11
.27
.04
.25
.08
.08
.04
.08
.15
Above: HpCDD / Octa-CDD and CDF Follows
0.902-1.098
0.000
0.877
0.879
0.889
0.890
0.892
0,901
0.904
0.905
0.938
0.939
946
1.015
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:27 04/20/9^
U
-------
Page No.
04/20/98
Compound/
M_S.... QC,
442-444
OCDD
458-460
458-460
13C12-OCDD
470-472
470-472
Listing of S982308B.dbC
Matched GC Peaks / Ratio / Ret, Time
Log Omit Why ..RT. OK Ratio Total.Area,.. Area.Peak.1.. Area. Peak. 2. , Rel.RT Compound,Name., ID.. Flags.
0 Peaks 0.00
0.76-1.02
DC HL 0:00 RO 1.11 0.17
DC SN 40:53 RO 0.58 0.15
0 Peaks 0.00
0.76-1.02
DC NL OiOO RO 1.30 _ 0.19
40:44 0.84 326.16
1 Peak 326.16
149,34
0.902-1.098
0.000
1.004
0.996-1.004
0.000
176.82 1.000 13C12-OCDD
IS8
Coluitai Description.
"Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
WL-Below Retention Time Window
WH-Above Retention Time Window
SM-Below Signal to Noise Level
-------
File:SS8,2308 #1-746 Acq:18-APR-1998 13:41:31 EH- Voltage SIR 70S Noise:69
03.9016 Fi2 BSUB(2S6f30r-3.0) PXD(9,S, 5,0.051,276.0,1.00*,F,T) Exp-.SDBSUS
TRIANGLE IJIBS TextiTLI#45399 M23-FB-2 IKJ". TIME = 13(44
1004 A3.25E3
23': 00 24:00 25:00 26:00
F±le:S9S2308 #1-746 Acgil8-APR-1998 13s 41:31 EH- Voltage SIR 70S Noise:SS
305.8987 F:2 BSUB(256, 30, -3.0) PXD( 9,5,5, 0. 05%,220, 0,1. 00%, F, T) ExpsNDBSUS
TRIANGLE LABS Text:TLIt45399 M23-FB-2 INJ, TIME = 13s44
1004 AS.J.3E3
sol
23:00 24:00 25:00 26:00
FilesS982308 #1-746 Acq:18-APR-1998 13:41:31 EI+ Voltage SIS 70S NoisesSS
315.941S Fs2 BSUB(256,30,-3.0) PKD( 9, 5,5, 0. OSt.,232. 0,1 . 00%, r, T) Exp:NDB5VS
TRIANGLE LABS Text:TLI#45399 M23-FS-2 XKT. TIME = 13:44
1004 A2.02E6
sol
40
201
o
-,' ' ' 23 loo'' '' '24:0o'25:00 26:00
File:S982308 #1-746 Acq:18-APR-1998 13:41:31 EI+ Voltage SIR 70S Noise:59
317.9389 F:2 BSUB(256,30,,-3. 0) PKD(9,5,5rO .051,236.0,1.OOl,JF,T) ExpsSDBSVS
TRIANGLE LABS Text:TLI#45399 M23-FB-2 IKJ. TIME = 13:44
1002, : A2.82E6
aol ; •
401
201
27:00
27:00
27\00
, , , j , . 1'* i 1 1 . i f T 1 1 1—>—i 1 1 1 1 1 1 r
23:00 24:00 25:00 2
-------
File:SS82308 #1-746 Acqs 18-APS-1998 13:41:31 EI+ Voltage SIR 70S No±se:45
319.8965 F:2 BSUB(256, 30, -3. 0) PKD( 7, 5,3, 0. 05%, 180. 0,1. 00%,F, T) Exp:W>B5US
TRIANGLE LABS Text:TLI#45399 M23-FB-2 IJKT. TIME = 13:44
1004 A2.35.E3
80:
24iOO 25:00 26:00
File:S982308 #1-746 Actj:18-APR-1998 13:41:31 EI+ Voltage SIR 70S Noise:51
321.8936 Fs2 BSUBf 256, 30, -3 . 0) PKD(7,5,3, 0. 051,204 . 0,1. 00%,F, T) ExpsKDSSOS
TRIANGLE LABS TextiTLI#45399 M23-FB-2 INT. TIME = 13:44
1004 . A2.65E3
27:00
0.^
24'-.00 25:00 26:00
File:S982308 #1-746 Acq:l:B-APR-1998 13:41:31 EI+ Voltage SIR 70S No±se:115
331.9368 F:2 BSUB(25S, 30, -3. 0) FJO>( 7, 5,3, 0. 05%, 460.0,1. 00%,F, T) Exp:KDB5OS
TRIANGLE LABS Text:TLI#45399 M23-FB-2 INJ". TIME = 13:44
1004 ' A2.J.3E6
27:00
80:
60:
40:
20:
ol
l . 55E6
J \J
24:00 25:00 26:00
File:S982308 #1-746 Acq:18-APR-1998 13:41:31 EI+ Voltage SIR 70S No±se:62
333.9338 F:2 BSUB(256, 30, -3 . 0) PKD( 7, 5, 3, 0. 05%,248 . 0, 1. 00%,F, Tj Exp:KDB5as
TRIANGLE LABS Text:TLI#45399 M23-FB-2 INJ~. TIME = 13:44
1004 A2.67E6
27-00
80:
60:
401
20:
0:
Al . 95E6
/ u
24:00 25:00 26:00
File:S982308 #1-746 AcqilB-APR-1998 13:41:31 EI+ Voltage SIR 70S No±se:58
327.8847 F:2 BSUB(256, 30,-3. 0) PKD(7, 5,3, 0 . 05%,232. 0, 1. 00%,F, T) Exp:NDB5VS
TRIANGLE LABS Text:TLI#f539-9 M23-FB-2 JJW. TIME = 1J.-44
1004
so: (.• si
60l ; ';•
40:
20: ' ,'
oj ; ''
27:00
24:00 25:00 26:00
F±le:S9B2308 #1-746 Acq:lB-APX-1998 13:41:31 EI+ Voltage SIR 70S
330.9792 F:2 Ejcp:NDB5OS
TRIANGLE LABS Text:TLI#45399 M23-FB-2 INJT. TIME - 13:44
1003 - _ 25x14 25:49 _,_0j!6:17 26:37,
BOJ
60:
40:
201
ol
27-00
,_1. 1E3
-3.4E5
O.OEO
Time
.5.BE5
.4.4E5
.2.9E5
.1.SE5
.O.OEO
Time
24:00
25:00
26:00
27:00
9.0E5
7.2E5
5.4E5
3. 6E5
1. BE5
.O.OEO
Time
.1. 4E6
.1. LE6
.8.1E5
.5.4E5
.2.7E5
.O.OEO
Time
-------
FilesS982308 #1-746 Acq: 18-APX-199S 13:41:31 EI+ Voltage SIM 70S Noise:35
339.8597 T:2 BSUB(256,30,-3..0) PKE(7r 5, 3, 0 . 05%,140. 0, 1. 00%, F, T) ExpsNOBSUS
TRIANGLE LABS Text:TLI#45399 M23-FB-2 ItKT. TIME => 13:44
100% Al. 1E3 A4.46E3
A1.47E3
28:00 " 29:00 30:00
'iJ.e:S982308 #1-746 AcgslB-APS-1998 13:41:31 EI+ Voltage SIX 70S Noiae:46
341.8567 F:2 BSOB(256,30, -3.0) PXD(7,5,3,0.051,184.0,1.00*,r,T) Exp:NDB5US
TRIANGLE LABS Text-.TLH4S399 M23-FB-2 IKT. TIME = 13:44
100S
80J
401
OJ
A1.86E3
A1.12E3
A75.6.
28:00 29:00 30:00
F±le:S982308 #1-746 Acq:18-APR-1998 13:41:31 EI+ Voltage SIR 70S Noise:41
351.9000 F:2 BSUB(256,30, -3. 0) PKD(7,5,3, 0. 05\,164 , 0, 1.00%,!", T) ExpsNEBSUS
TRIANGLE LABS Text:TLHt45399 M23-FB-2 IKT. TIME = 13:44
100S ._ A2.32E6
80J
601
401
20.
OJ
A2.24E6
28:00 ' 2S.-00 J0.-00
File:S982308 #1-746 Acq:18-APS-1998 13:41:31 EI+ Voltage SIR 70S No±se:45
353.8970 F:2 BSOB(256,30f-3.0) PKD(7,5, 3, 0, OS%,180. 0,1. 00%,F,T) Exp-.SVBSUS
TRIANGLE LABS Taxt:TLI#45399 M23-FB-2 JKT. TIME = 13:44
10031 - '•;
80J
601
401
201
Al.
28:00 29:00 30:00
File:S982308 #1-746 Acq:ia-APX-1998 13:41:31 EI+ Voltage SIR 70S
330.9792 F:2 Exp:NJ}B5US
TRIANGLE LABS Text:TLI#45399 M23-FB-2 INJ. TIME =
J00S
80j
60:
401
201
ol
13:44
31:00
31: 00
31:00
31: 00
~r
28:00 29:00 30:00
File:S982308 #1-746 Acg:18-APR-19S8 13:41:31 EI+ Voltage SIS 70S
409.7974 F:2 Exp:M)B5US
TRIANGLE LABS Text:TLI#45399 M23-FB-2 IWJ. TIME =
100S -• •-
31." 00
13:44
80J
sol
4oi
201
ol
30:38
29:06
28:00
29500
30:00
31100
.7.2E2
.5, 8E2
.4.3E2
.2.9E2
.1.4E2
.O.OEO
Time
7.6E5
6.1E5
.4.6E5
.3.0E5
.1, 5E5
.O.OEO
Time
.5.1E5
.4.0E5
.3. OE5
.2. OE5
.1. OE5
.O.OEO
Timi
.1.4E6
.1.1E6
.8.4ES
.5. 6E5
.2.8E5
.O.OEO
Tims
.2.1E3
,1. 7E3
.1. 2E3
.8.3E2
.4.1E2
.O.OEO
Time
324
-------
File:S$6230a #1-746 Acq:l8-APR-l998 13:41:31 EI+ Voltage SIR 70s Noise:43
355.8546 F:2 BSUB(256,30,-3.0) PKV(7, 5, 3, 0 . 05%, 172. 0, 1. 00%,F, T) Eip:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-FB-2 INJ. TIMS = 13:44
1003s A2.23E3
801
.O.OEO
28':24 28':3628':48 29:00 29:12 29':24 29:36 29:48 30':00 30:12 30:24 30:36 30:48 31:00 31:12 Time
File:S982308 #1-746 Acq: 18-APB-1998 13:41:31 EI+ Voltage SIR 70S Noise:31
357.8516 F:2 BSUB(256, 30,-3 . 0) PKD( 7, 5, 3, 0.051,124 .0, 1.00*,F,T) Exp:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-FB-2 INJ. TIME = 13:44
100$
A949.76
r.7.6E2
28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00 31:12
File:S982308 #1-746 Acq:18-APR-1998 13:41:31 EI+ Voltage SIR 70S Noise:40
367.8949 F:2 BSUB(256, 30,-3 . 0 ) PKD(7, 5,3 , 0. 051, 160 . 0, 1. 001,F, T) Exp:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-FB-2 INJ. TIME = 13:44
1003, A1.62E6
80.
60.
40.
20.
-5.3E5
_4.2E5
.3.2E5
.2.1E5
.1. 1E5
1.38E5
O.OEO
28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00 31:12 Time
File:S982308 #1-746 Acq:18-APR-1998 13:41:31 EI+ Voltage SIR 70S Noise:35
369.8919 F:2 BSUB(256, 30,-3.0 ) PKD(7, 5,3, 0 . 05%, 140. 0, 1. 00%,F, T) Eip:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-FB-2 INJ. TIME = 13:44
1004 A1.12E6 -3.5E5
80J
601
401
201
9.50E4
'.2.8E5
'.2.1E5
11. 4E5
17.1E4
.O.OEO
28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00
File:S982308 #1-746 Acq:18-APR-1998 13:41:31 EI+ Voltage SIR 70S
330.9792 F:2 Exp:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-FB-2 INJ. TIME = 13:44
100%
31:12 Time
„„ ^ 25-18 29:53 30:07 30:26 30:57 ^ J
28:34 28:55 25:06^ ^A^^-- ~^^ « "V1^ — ^-^^ — -v
t
- •
_1 . 4E6
_1 . 1E6
-8.4E5
.5 . 6E5
.2.8E5
O.OEO
28:24 28:36 28:48 29:00:29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00 31:12 Time
<.' V-
-------
'ile:S982308 #1-465 Acqi18-APS-1998 13:41s31 EI+ Voltage SIS 70S Noiae:85
73.8208 F:3 BSUB(256, 30,-3. 0) PKD(7,5,3, 0. 05%,340. 0,1. 00%,V, T) ElpsNOBSUS
TRIANGLE LABS Text:TLIf45399 M23-FB-2 IK7. TIME = 13i44
004 A2.QOE3
•ile:S982308 #1-465 Acq:18-APS-1998 13:41:31 EI+ Voltage SIR 70S NoisesBO
375.8178 Ts3 SSUB(256, 30, -3.0) PXD( 7,5, 3, 0, 051,320,0,1.00%,I>,T) ExpsNDBSUS
TSIANGLE LABS Text:TLI#45399 M23-FB-2 INT. TIME = 13:44
1004
' A1.71E3
20.;
A2.65E3
S4E3
'i i i i i i i i i i i 4 i i < i i i i i i i i i i i i i i i i i * i t i i i i i i i t i ' ' ' ' ' i i'"i' 'i * ' i i i i i i i i i i i i i i i i i i i 11 i i i i i i i i i | i i i i i i i I *
31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34:12 34:24 34:36
_1,
-1
31:36 31:48 32:00 32:12 32:24 32:36 32:48 33sOO 33:12 33:24 33:36 33:48 34:00 34:12 34:24 34:36
File:S982308 #1-465 Acq:18-APR-1998 13:41:31 EI+ Voltage SIX 70S Noise:81
383.8639 F:3 BSUB(256,30,-3.0) PKD(7,5,3, 0 . 05%, 324 . 0, 1. 00%,F, T) ElpiNDBSUS
TRIANGLE LABS Text:TLI#45399 M23-FB-2 IKT. TIME - 13:44
1004 A1.20E6 A1.05E6
A8.26E5
20
31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34:12 34:24 34:
File:S982308 #1-465 Acq:18-APR-1998 13:41:31 EI+ Voltage SIR 70S Noiae:85
385.8610 F:3 BSUB(256, 30,-3.0) PKD(7, 5, 3, 0 . 05%,340. 0, 1. 00\,F, T) Eip:NVB5US
TRIANGLE LABS TextsTLI«453'99 M23-FB-2 IJKT. TIME = 13:44
1004 ' A2.3.2E6 A2.11E6
36
80J
601
401
201
OJ
Al. 65E6
6.
Ls.
LJ,
1.2.
Li,
31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34:12
File:S982308 #1-465 Acq:18-APR-1998 13:41:31 EI+ Voltage SIR 70S
392.9760 F:3 Exp:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-FB-2 IWJ. TIME = 13:44
32:05
60
401
201
OJ,
_-0.
:36
.6E2
,7E2
,7E2
,BE2
.9E2
OEO
Time
,5E3
2E3
• 2E2
.2E2
.1X2
OEO
Time
,2E5
.SE5
,9E5
.3E5
.4E4
.OEO
Time
3E5
1E5
8E5
5E5
3E5
OEO
Time
7.
is.
4.
'.2.
11.
31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34:12
eile:S982308 #1-465 Acq:18-APR-lS98 13:41:31 EI+ Voltage SIS 70S
445.7555 F:3 Exp:NDB5OS
TRIANGLE LABS Text:TLI#45399 M23-FB-2 J«J. TIME " 13:44
33 46
34:24 34:
10.
36
OSS
.6E5
.2E5
.8E5
,4E5
.OEO
line
31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33-48 34:00 34:12 34:24 34:
320
-------
sj.le:S98230a #1-465 Acq'sT8'-APX-l99'6 13:41:31 EX+ Voltage SIS 70S WOise191
385,8156 Fs3 BSUB( 256, 30, -3. 0) PKD( 7,5,3, 0. 05%, 364 . 0,1. 00%,?, T) Exp:SDB5US
TRIANGLE LABS Text:TLI#45399 M23-FB-2 IKT. TIME » 13:44
100% " -
A2.40E3
80J R3.12E3
32sl2 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00
File:S982308 #1-465 Acq:18-APS-1998 13:41:31 EI+ Voltage SIS 70S Noise:S2
391.8127 F:3 BSUB(25Se30,-3.0) PKD( 7, 5, 3, 0. 05%, 328. 0, 1. 00%, F, T) Exp:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-FB-2 ' INJ. TIME = 13s44
1002,
so:
601
401
201
601
40.
20.
Al.62E3
1
,A203.43
I 1 "I ' '
32:36
T"
32'sl2 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00
File:S982308 #1-465 Acq:18~APR-1998 13:41:31 EI+ Voltage SIX 70S jNipise:9J
401.8558 Fs3 BSUB(256, 30,.-3: 0) PKD(7,5,3, 0. 05%, 372. 0, 1. 00%,F, T) Exp:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-FB-2 JWJ. TIME = 13:44
100% A1.50E6 A1.56E6
A1.17E
601
401
201
32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34-00
File:S982308 #1-465 Acq:18-APR-1998 13:41:31 EI+ Voltage SIS 70S No±se:154
403.8529 F:3 BSUB(256, 30,'-3. Oj PKD( 7,5,3, 0. 05%, 616.0,1. 00%,F, T) Exp:fTDB5US
TSIANSLE LABS Text:TLIt45399 M23-FB-2 INJ". TIME = 13:44
1003i •• A1.25E6 A1.30E6
801
601
401
20.
A9.67E
32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48
J?ile:S982308 #1-465 Acq:18~APK-199i 13:41:31 EH- Voltage SIS 70S
392.9760 F:3 Exp:NDB5US
TSIANSLE LABS TextiTLIi45399 M23-FB-2 JJKT, TIMS = 13:44
100*
so:
601
401
201
0.
32:17
32:28 32:38
32:54
33: 03
33:34
33:47
32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34:12
ii
\MJIli
HI
d ' '34 sis'
i
1
f^Mh n.
A iryl/U y
0' ' '34 sis'
0 ' ' 34\12
10 34 {: 12
,02 34:13
^s~^/-vV^~^
id ' '34 sis'
-1.3E3
11 . 1E3
If ,OE2
IS.4E2
12 . 7E2
' o . OEO
Time
_1 . 7E3
~_1.4E3
11 . OE3
~_6.8E2
~_3.4E2
' 0 . OEO
Time
13. 3E5
12.5E5
11. 6E5
'.8.2E4
" 0 . OEO
Time
3 . 3E5
".2. 7E5
12. OSS
11 , 3E5
".6.7E4
" O.OEO
Time
6 . 7E5
15.4E5
14.0E5
"-2.7E5
11 . 3E5
" 0 , OEO
Time
-------
•ile:S98230S #1-569 AC
-------
File:S9a2306 #1-565 Acq:l8-APR-l998 13:41:31 EI+ Voltage SIS 70s Noise:62
423.7766 F:4 BSUB(256, 30,-3 . 0 ) PKD( 7, 5, 3, 0 . 051,248. 0, 1. 001,F, T) Eip:NVB5US
TRIANGLE LABS Teit:TLI#45399 M23-FB-2 JJW. TIME = 13:44
1003,
File:S982308 #1-569 Acq:18-APX-1998 13:41:31 EI+ Voltage SIR 70S Noise:54
425.7737 JT:4 BSUB( 256, 30,-3 .0 ) PKD( 7 , 5,3 , 0 .051,216.0, 1.001,F, T) Exp:NDB5US
TRIANGLE LABS Teit:TLI#45399 M23-FB-2 JJW. TIME = 13:44
1004 . A1.27E3
A813.09 A485.34
36:00 36:06 36:12 36:18 36:24 36:30 36:36 36:42 36:48 36:54 37:00 37:06 37:12 37:18
36:00 36:06 36':12 36': 18 36:24 36:30 36:36 36:42 36:48 36:54 37:00 37:06 37:12 37:18
File:S982308 #1-569 Acq:18-APR-1998 13:41:31 EI+ Voltage SIR 70S Noise:96
435.8169 F:4 BSUB(256, 30,-3 .0 ) PKV( 7, 5, 3, 0 . 05%, 384 . 0, 1. 001,F, T) Exp:NDB5US
TRIANGLE LABS Text: TLI#45399 M23-FB-2 INJ. TIME = 13:44
1004 A1.40E6
80L
eo:
40:
20:
36:00 36:06 36:12 36:18 36:24 36:30 36:36 36:42 36:48 36:54 37:00 37:06 37:12 37:18
File:S982308 #1-569 Acq:18-APR-199S 13:41:31 EI+ Voltage SIR 70S Noise:84
437.8140 F:4 BSUBf 256, 30,-3 .0 ) PKD( 7, 5,3, 0 . 05%, 336. 0, 1. 001,F, T) Exp:NDB5US
TRIANGLE LABS Teit:TLI#45399 M23-FB-2 INJ. TIME = 13:44
100% A1.42E6
80.
eo:
40.
20.
36:00 36:06 36:12 36:18 36:24 36:30 36:36 36:42 36:48 36:54 37:00 37:06 37:12 37:18
File:S982308 #1-569 Acq:18-APR-1998 13:41:31 EH- Voltage SIR 70S
430.9729 F:4 Eip:NDB5US •
TRIANGLE LABS Teit:TLI#45399 M23-FB-2 INJ. TIME = 13:44
xx-—-~
80.
60.
40.
20.
0.
36:00 36:06 36:12 36:18 36:24 36:30 36:36 36:42 36:48 36:54 37:00 37:06 37:12 37:18
6.8E2
5.5E2
4.1E2
2.7E2
1.4E2
O.OEO
Time
.2.4E5
.1. 9E5
.1.4E5
.9. 5E4
.4.7E4
.O.OEO
Time
.2.5E5
.2.0E5
.1.5E5
.9. 8E4
.4.9E4
.O.OEO
Timt
.5. 4E5
.4.3E5
.3.2E5
.2.2E5
.1.1E5
.O.OEO
Time
-------
File :SS 823 08 #1-569 Acq: 18-APR-1998 13:41:31
441.7428 T:4 BSUB(256,30,'-3.0) PKD(7, 5,3, 0 .05
TRIANGLE LASS Text :TI,I#4 5399 M23-FB-2
1003
90j
801
701
601
501
401
301
201 - -'•
101 j-
35:00 37:00 38:00
file. -S3 82308 #1-569 Acqsl8-APR-199B 13:41:31
443.7399 F:4 SSUB(256, 30, -3. 0) PKD(7, 5,3, 0 .0.
TRIANGLE IABS Tejct:TLI#45399 M23-FB-2
1002,
901
801
701
601
501
40.
301
201
10.
36:00 37s 00 38:00
File:S982308 #1-569 Acq:lB-APR-1998 13:41:31
430.9729 F:4 Ejcp:NDB5US
TRIANGLE LABS TextsTLI#45399 M23-FB-2
IOCS 36:08 36.3g
o^HnAHVVV'Y^W.ju *7L3° 38:01
90-.\ ^^^s*~^~WVw^/%,204.0,1.00%,F,T; ExpsNDBSUS
ZKT. TIME = 13:44
Al . 23E3
39:00 40:00 41:00 42-00
EI+ Voltage SIR 70S
mar. TIME =• 13:44
1 3S.-59 39:42
W/V^\v^f>^W*v»^'Vf*V^A^^^ ^i/v21 41s 58
W rv^^ u Hy >r'sNV'y^s"yi»JVyi VVV^^
39s 00 ' ' 40: 00 ' ' ' 41:00 ' ' 42:00
EI+ Voltage SIR 70S
INJ-. TIME = . 13:44
39:13 40:29
. 39:42 1
1 11 ii A 1 41:02 (41-32 42- OB
•^^MVMjJ^M\^
39:00 40:00 41:00 42:00
.2.5E4
.2.2E4
.2.0E4
.1 . 7E4
.1.5E4
-1.2E4
-9.9E3
_ 7 . 4E3
-.4.9E3
"L2.5E3
": 0 . OEO
Time
_1 . SE4
Ll . 6E4
L1.5E4
L1.3E4
I.1.1E4
L9.1E3
L7.3E3
L5.4E3
L3.6E3
Ll , SE3
- 0 . OEO
Time
5 . 4E5
L4.9E5
.4 .3E5
.3 . 8E5
-3.3E5
L3.7E5
12 . 2E5
Ll - 6E5
ll.lES
L5 . 4£4
: 0 . OEO
Time
3.9E3
13 . 5E3
13 . 1E3
12 . 8E3
12.4E3
L2.0E3
11 . 6E3
Ll . 2JT3
L7.9£2
L3.9E2
: 0 . OEO
Time
320
-------
•ile:S$82308 41-569 Acq:lB-APR-19S8 13:41:31 EI+ Voltage SIR 70S Noise:51
457.7377 F-.4 BSUB(256, 30,-3 .0 ) PKV(7, 5, 3, 0 . 05%,204 . 0, 1. 00%,F, T) Exp:NDB5DS
TRIANGLE LABS Text.: TLI#45399 M23-FB-2 INJ. TIME = 13:44
1004 A2.79E3
40 36 40:42 40:48 40:54 41:00 41:06
File:S982308 #1-569 Acq:18-APS-1998 13:41:31 EI+ Voltage SIS 70S Noise:47
459.7348 F:4 BSUB(256, 30, -3 . 0) PKD(7, 5,3, 0. 05%, 188 . 0, 1. 00%,?, T) Exp:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-FB-2 INJ~. TIME = 13:44
1004 . A1.44E3
41:12
40 36 40':42 40:48 40:54 41:00 41:06
File:S982308 #1-569 Acq:18-APR-1998 13:41:31 EI+ Voltage SIR 70S Noise:64
469.7779 F:4 BSUB(256,30,-3>0) PKD(7, 5,3, 0 . 05%,255. 0, 1. 00%,r, T) Exp:NHB5US
TRIANGLE LABS Text:TLI#45399 M23-FB-2 INJ~. TIME = 13:44
1004
41:12
40 36 40:42 40:48 40:54 41:00 41:05
File:S982308 #1-569 Acq:18-APR-1998 13:41:31 EI+ Voltage SIR 70S No±se:51
471.7750 F:4 BSUB(256,30,-3>.0) PKV( 7, 5,3, 0. 05%, 204 . 0, 1. 00%,f, T) Exp:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-FB-2 INJ. TIME = 13:44
1004 Al.j
80J
41:12
40J
20.
40:36 40:42 ; 40:48 40:54 41:00
F±le:S982308 #1-569 Acq:18-APR-1998 13:41:31 EI+ Voltage SIR 70S
430.9729 F:4 Exp:NDB5US '
TRIANGLE LABS Text:TLI#45399 M23-FB-2 INJ. TIME =
1003,
so:
eo:
40J
20L
41: 06
41:12
6. 7E2
5.4E2
4.0E2
2. 7E2
1.3E2
.O.OEO
Time
40-36
40:42
40:48
40:54
41: 00
41:12
.1.3E5
.1. 1E5
.8.0E4
.5.4E4
.2.7E4
.O.OEO
Time
.4.4E5
.3.5E5
.2. 7E5
.1. 8E5
.8.9E4
.O.OEO
Time
-------
Chamel i 338,3782 Peak top
Height ,33 volts Span 288 ppi
Systa fill rm
Data file naae
Resolution
Grop nuber
lonlzatlon Kde
Mtehlng
Ref. lasses 232,Svw}
R 233 J 331
NDB5US
B 384
C 386
0 316
E 318
r m
6 m
H 328
! 331
K 332
L 334
n tfW
N 342
0 352
P 354
fl 356
R 358
a
0*
VGLTfli
416,9768
S 388
T 378
II 376
V 418
Ref, lass 416,9768 Peak top
Height ,88 volts .Sp E88 p
-------
TLI Project:
Client Sample:
45399
M23-FB-2
Method 23 TCDD/TCDF Analysis (DB-225)
Analysis File: P981319
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
r012.002/Lime
M23
204-92-10A-D
1.000
n/a
DB-225
Kiln
Date Received: 04/01/98
Date Extracted: 04/03/98
Date Analyzed: 04/17/98
Dilution Factor: n/a
" Blank File: U980780
Analyst: KB
Spike File:
ICal:
ConCal:
% Moisture
% Lipid:
% Solids:
SPC2NF04
PF24098
P981314
: n/a
n/a
n/a
Kv^sflmmmmmffmm
2,3,7,8-TCDF
l3Cl2-2,3,7,8-TCDF
Recovferv Staridaj
l3Ci2-l,2,3,4-TCDD
ND 0.005
2.9 73.7 40%-130%
0.78
0.83
—
22:22
21:16
Data Reviewer
Page 1 of 1
04/20/98
C2NFJ>SR »102. LARS 6.11.00
Triangle Laboratories, Inc.®
801 Capttola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 21:29 04/20/98
33.1
-------
Initial
....Date..,
Data Review By:
Calculated Hoise Area:
0.1.0
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
04/20/98
Listing of P981319B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ,.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak,2. . Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
304-306
0.65-0.89
DC NL 0:00 0.69
0 Peaks
0.22
0.00
0.789-1.101
0.000
13C12-TCDF
316-318
0.65-0.89
DC NL 0:00 0.73
DC WL 20:31 RO 1.00
DC WL 20:57 RO 0.62
DC WL
21:13
22:22
0.83
0.78
316-313
DC SN 23:02 RO 2.55
DC WH 23:26 RO 4.29
DC WH 23:38 RO 1.92
DC WH 24:25 RO 0.57
1 Peak
0.19
0.27
1.08
5.34
188.67
0.19
0.12
0.23
1.95
188.67
82.73
0.955-1.045
0.000
0.917
0.937
0.949
105.94 1.000 13C12-2378-TCDF ISO
1.030
1.048
1.057
1.092
Above: TCDF / TCDD Follows
13C12-TCDD
332-334
332-334
0.65-0.89
DC NL 0:00 RO 1.44 0.16
DC SN 19:53 RO 0.31 0.11
21:00 0.82 135.18
21:16 0.83 190.53
22:00 RO 1.04 0.97
3 Peaks 326.68
60.97
86.43
0.57
0.905-1.095
0.000
0.947
74.21 1.000 13C12-2378-TCDD IS1
104.10 1.013 13C12-1234-TCDD RSI
0.55 1.048
Column Description.
"Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
. .RT, -Retention Time (mnuss)
Rat.l -Ratio of M/M+2 Ions
WL-Below Retention Time Window A-Peak Added
WH-Above Retention Tine Window K-Peak Kept
SN-Below signal to Noise Level D-Peak Deleted
OK -RO=Ratio Outside Limits
-------
File:P931319 41-1006 Acq: 17 '-APS- 199 8 04:18:22 EI+ Voltage SIR 70P
303.9016 Elp:DB225
TRIANGLE LABS Teit:M23-FB-2 TLI#45399
1004
953
903
85]
80J
75 :
70J
65l
601
551
sol
45l
40l
35l
30l
25l
20j
15-
10!
5l
0:
21
File
315.
TRIA
1003
95l
90l
85.
aol
75l
70l
65l
601
55l
sol
45l
401
351
30l
25.
20.
15.
101
21
21:15 I 2I;U 22
W |W^
1 If -. 1 1 l n
23 : 11
24 1 I
Jlc2 : 55 n it 23 : 22 23 : 3 7
i (yii^^ r \|H
PI
;
/ / /l/^ ft®
0
i
j(7'T
/ /
// (Lnnlr,^
sf> ll'lio
\ I
1
1 4E3
Ll . 4E3
Ll . 3Z3
1.2E3
.1.1E3
.1 . OE3
.9.2E2
.8.5E2
.7.8E2
.7.1E2
-6.4E2
.5.7E2
-5.0E2
'•-4.3E2
'.3 . 6E2
.2.8E2
'.2.1E2
Ll . 4£2
L7.1Z1
: o . oro
•00 21\12 2i.-24 2ll-J6 211-48 221-00 22:12 221-24 221-36 22.-48 2J:bb 2J.'l2 2J1-24 2J.-J6 2J.-48 24 00 Time
-.P981319 #1-1006 Acq:17-APR-1998 04:18:22 EI+ Voltage SIR 70p
9419 Eip:DB225
NGLE LABS Text:M23-FB-2 TLI#45399
22:22 2.0E5
ft
1
00 21.'i2 2ll-24 2ll-J6 21:48 221-00 22:12 221-24 22.-J5 22.-4S 231-00 23:12 23:24 23.-36 2J.-48 24
':! . 9E5
Li . sr5
Li . 7r5
Ll . 6E5
Ll . 5r5
L1.4Z5
Ll . 3r5
L1.2Z5
Li.irs
Ll . ors
'-.9.0E4
'-.8.0E4
'-.7.0E4
'.6.0E4
L5 . OZ4
L4.0Z4
L3 . or4
L2.0Z4
Li . or4
: 00 lime
n ^
-------
File:P9ai3l9 tl-WOg Acgsl7-APS-l!iiiB 04's'f$TS2 EI+ Voltage SIR ?'0> Noiae:44
03.9016 BSUB(256,30r-3.0) PKD(5,3,1,0.101,176.0,0.QQ\,F,F) Exp:OB225
TRIANGLE LABS TextiM23~FB~2 TLI#45399
1004 A422.2B
18:00 1S.-CO 20-00 21iOO 22-00 23:00
File:P981319 #1-1006 Acq:17-APS-1998 04:18:22 EI+ Voltage SIR 70'P NoiaetSS
305.8987 BSUB(25S,30,-3.0) PKS( 5,3,1,0.10%,264. 0, 0. QQ1rF,F) Exp:OB225
TRIANGLE LABS Text;M23-FB~2 TLI#45399
1004 A62?.26 A482.65
18:00 19:00 • 20:00 21:00 22:00 23:00
F±le:P981319 #1-1005 Acq:17rAPR-1998 04:18:22 EH- Voltage SIR 70P NO±9e:38
315.9419 SSVB(256,30r-3.Q) PKD(5,3,1,0.101,152.0,0.00\,F,F) Exp:BS225
TRIANGLE LABS Text:M23-FB~2 TLI445399
A8.27E5
24:00
24:00
BO:
eo:
401
20:
18:00 19:00 '. 20:00 21:00 22:00 23:00
File:P981319 #1-1006 Acqil7-APR-1998 04:18:22 EI+ Voltage SIR 70P No±se:57
317.9389 BSUB(256,30,-3.0) fKD(5,3,1,0.101,228.OfO.OO*,F,F) Exp:DS225
TSIASSLE LABS Text;M23-FB-2 TLH45399
100S Al. 6E6
so:
so:
40:
20.
24:00
, 18:00 19:00 . . 20:00 21:00 22:00 23:00
File:P981319 #1-1006 Acg:17-APR-1998 04:18:22 EX+ Voltage SIS 70P
375.8364 Exp:DS225 - .:
TKIASGLE LABS Text:M23-FB-2 TLI#45399
1003,17.55
24:00
O.OEO
25:00 Time
S.1E2
"-4.0E2
13. OE2
.2. OE2
1.0E2
O.OEO
25:00 Time
-2.OE5
11.6E5
11.2E5
".8.0E4
'-4.0E4
25
.O.OEO
00 Tinn
2.6E5
'.2.1E5
11. 6E5
11. OE5
'.5.2E4
25.
.O.OEO
00 Tim
18:00
19:00
20:00
21:00
22:00
23:00
24:00
.'.O.OEO
:00 Tin*
33G
-------
File:P981319 #1-1006 Acq: 17-APR-1998 04:18:22 EI+ Voltage SIR 70P Noise:52
319.8965 BSUB(256,30,-3.0) PKD(5, 3,1, 0.10*,208. 0, 0 . 00%, F,F) Ezp:DB225
TRIANGLE LABS Text:M23-FB-2 TLI#45399
1003, A819.21
A670.40
19:00 20:00 21:00 22:00 23:00
File:P981319 #1-1006 Acq: 17-APR-1998 04:18:22 EI+ Voltage SIR 70P Noise:51
321.8936 BSUB(256,30,-3.0) PKD(5, 3, 1,0.101,204 . 0, 0 . 00%, F, F) Eip:DB225
TRIANGLE LABS Text:M23-FB-2 TLH45399
1003i A783.05
so:
60.
40.
20.
A260.85
19:00 20': 00 21:00 22:00 23:00
File .-PP 8131S #1-1006 Acq: 17-APR-1998 04:18:22 EI+ Voltage SIR 70P Noise:61
327.8847 BSUB(256, 30,-3 . 0) PKD(5, 3,1, 0.10%, 244 . 0, 0 . 00%, F,F) Eip:DB225
TRIANGLE LABS Text:M23-FB-2 TLI#45399
File:P981319 #1-1006 Acq:17'-APR-1998 04:18:22 EI+ Voltage SIR 70P No±se:64
331.9368 BSUB(256,30,-3.0) PKD(5, 3, 1, 0.10%, 255. 0, 0 . 00%,f, F) Eip:DB225
TRIANGLE LABS Text:M23-FB-2 TLI#45399
F±le:P981319 #1-1006 Acq:17-APR-1998 04:18:22 EI+ Voltage SIR 70P No±ae:47
333.9338 BSUB(256, 30,-3 . 0) PKD(5, 3, 1, 0.10%, 188. 0, 0. 00%, F,F) Eip:DB225
TRIANGLE LABS Teit:M23-FB-2 TLI#45399
1004 A1.04E6
80.
eo:
401
20-
0.
A7.42E5
19:00
20:00
24:00
O.OEO
Time
24 : 00
005
so:
eo:
40.
20.
0
A1.36E6
'
l\
19 1-00 20. -00 21 1-00 22 .-00 23 : 00 241-00
_J . 7E5
.3 . OE5
.2 . 2E5
.1 . 5E5
L 7 . 4E4
O.OEO
Time
003
801
601
40.
20.
0
A6.
J
'isi-Oo' ' ' ' '2ol-00 21
A8.64E5
rt
OE5\\
•
\}\
:00 22.' 00 2J.-00 24-00
_2 . 3E5
_1 . 8E5
_1 . 4E5
.9 . 1E4
.4 . 6E4
O.OEO
Tim
2.8E5
-2.2E5
LI. 7E5
LI. 1E5
'.5.6E4
21: 00
22:00
23: 00
24 : 00
O.OEO
Time
-------
File:P581319 #1-1005 Ac
t *
18:00 19:00 , 20:00 21:
ffjt Voltag-e SIR 70P
S^l^^^g^J^g^ 23:50 '24j23^^ 4. 2E6
-
_3 . 4E6
.2.5E6
.1 . 7E6
-8.4ES
O.OEO
00 221-00 ' ' ' 231-00 ' ' ' 241-00 25 00 Time
EX+ Voltage SIM 70P
21:31 22:11 22:47 23:20 23:51 24:23 4.9S6
o/'^rt/W^V^W^rMJi^^Si/W'W i^^^^j^vv^iAirfvvVVl7
^r iv y T-y y» T * V tf^V *'' • *y I/I Wy ¥M| * '
'•.3.9E6
'-2.9ES
''.2.0E6
IS . 8E5
• 0 . OEO
00 22:00 ' ' ' 23-00 24; 00 ' ' ' 25 00 Time
338
-------
fief, MSS ^32,3825 tak top
Height ,51 volts Span EM p
Systaflle
Data file nm
Resolution
Group nuter
lonlzilon Mde
SuUtchlng
tef. wsses 232,3825,
ft 292.3^5 J
B 383.9816 K
c mm i
D 1
E
1
El*
VOLTOE
3^,3781
338,9732
331.9388
333.3338
375,8364
-------
Pages 340 through 357 from the Triangle Laboratories, Inc. analytical report
have been excluded by PES since these pages present results for samples
collected at another lime kiln facility during the same mobilization.
-------
TLI Project: 45399
Client Sample: M23-RB-1-4
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S982310
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
r012.002/Lime Kiln
M23
204-92-12A-D
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank Hie:
Analyst
04/01/98
04/03/98
04/18/98
n/a
U980780
DL
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPMIT204
SF51078
S982303
n/a
n/a
n/a
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.003
0.004
0.004
0.004
0.004
0.004
0.005
0.002
0.003
0.003
0.003
0.003
0.003
0.003
0.003
0.004
0.004
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
ND
ND
ND
ND
ND
ND
ND
ND
0.003
0.004
0.004
0.004
0.002
0.003
0.003
0.004
Page 1 of2
MTT2.PSR vl.04. LARS 6.II.OO
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:28 04/20/98
358
-------
TLI Project: 45399
Client Sample: M23-RB-1-4
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S982310
13Ci2-2,3,7,8-TCDF
13C,2-2,3,7,8-TCDD
13e,rU,3,7,8-PeCDF
13Ci2-U,3J,8-PeCDD
°C,2-l,2,3,6J,8-HxCDF
13Ci2-l,2,3,6J,8-HxCDD
13CI2-U,3,4,6,7,8-HpCDF
13C,2-1,2,3,4,6,7,8-HpCDD
13C,2- 1,2,3,4,6,7,8,9-OCDD
2.6
2.4
2.5
3.0
3.3
3.9
3.3
4.0
9.2
66.0
59.9
62.5
76.1
81.6
97.6
82.8
101
115
40%430%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
0.71
0.80
1.57
1.48
0.50
1.21
0.42
1.01
0.85
25:14
25:57
29:10
30:13
32:44
33:27
35:44
36:52
40:42
13Ci2-13,4,7,8-PeCDF
!3C12-l,2,3A7,8-HxCDF
13Ci2-!,2,3,4,7,8-HxCDD
13C,2-l,2,3,4,7,8,9-HpCDF
4.0
3.3
3.3
3.8
101
82.5
82.5
95.2
40%-130%
40%-130%
40%-130%
25%-130%
1.53
0.50
1.20
0.43
29:52
32:38
33:22
37:22
"OrWJ.S-TGDD
3.4
83.8
40%-130%
25:58
13Ci2-l,23J,8,9-HxCDF
13C,2-2,3,4,6J,8-HxeDF
3.5
3.6
87.7
89.1
40%-130%
40%-130%
0.51
0.50
34:03
33:15
Recovery Standards
Ratio
HT
Flags
13C12-1,2,3,4-TCDD
13CI2-l,2,3,7,8,9-HxCDD
0.79
1.19
25:46
33:47
Data Reviewer
04/20/98
Page 2 of2
MTTUPSR vl ,04, LARS 6.! 1,00
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:28 04/20/98
359
-------
Initial
... Date.,
Data Review By;
Calculated Boise Area: 0.10
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No,
04/20/98
Listing of S982310B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
H_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1. . Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
0
320-322
37C1-TCDD
328
328
13C12-TCDD
332-334
DC NL 0
:00
0.
RO
65
1
-0.89
.23
0 Peaks
DC NL 0
DC ML 23
DC ML 24
24
24
25
25
:00
:15
:12
:31
:50
:14
:40
0.
RO
RO
0
0
.23
.00
65-0,89
1
1
0
0
0
0
0
.00
.46
,71
.88
.71
.71
.86
4 Peaks
DC NL 0
DC SN 23
DC SN 23
DC SN 23
DC SN 23
DC SN 24
DC SN 24
d SN 24
DC SN 25
DC SN 25
DC SH 25
:00
-.26
:34
:43
:53
:12
:26
:46
:30
:44
:59
0.
RO
SO
RO
RO
SO
RO
RO
RO
RO
H !__,._ .
65-0.89
0
4
0
0
0
0
0
1
1
3
0
.90
.00
.43
.67
.40
.83
.18
.00
.20
.75
.37
0 Peaks
DC NL 0
24
DC SN 25
25
26
27
tOO
:35
:07
:S8
slO
:27
4 Peaks
DC NL 0
24
25
25
:00
:46
:46
i57
0.
RO
RO
.65
1
0
0
0
-0.89
.27
.94
.79
.80
0
0
12
1
3
434
1
440
.28
.42
.07
.05 0.49
.00 1.25
,08 180.06
.90 0.88
.03
0.873-
0.
1.075
000
0.960-1.040
0.
0.
0.
0.56 0.
1.75 0.
254.02 1.
1,02 1.
000
921
959
972
984
000 13C12-2378-TCDF
017
ISO
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
240
0
0
242
0
1
458
302
.18
.04
.07
.10
.05
.11
.07
.39
.09
,07
.16
.00
.13
.40 1.40
.12
.64 240.64
.28 0.28
.16 0.16
.48
.27
.54 0.82
.13 202.61
.52 134.10
0.899-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.923-
0.
0.
0.
1.
1.
1.
0.923-
0.
0.87 0.
255.52 0.
168.42 1.
1.046
000
903
908
914
920
933
942
954
983
992
001 2378-TCDD
1.077
000
947
968
001 37C1-TCDD
008
058
1,077
000
954
993 13C12-1234-TCDD
000 13C12-2378-TCDD
AN
CLS
RSI
I SI
Triangle Laboratories, inc.® Analytical Services Division
801 Capitoia Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:28 04/20/98
- 3GO
-------
Page No.
04/20/98
Listing of S982310B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z..., QC.Log Omie Why ..RT. OK Ratio Total,Area... Area.Peak.1.. Area.Peak,2.. Rel.RT Conposmd.Hame.. ID.. Flags.
332-334
PeCDF
340-342
340-342
13C12-PeCDF
352-354
352-354
PeCDD
356-358
356-358
13C12-PeCDD
368-370
26:
17
0.
.89
4 Peaks
DC NL 0:
DC SN 29:
DC SN 29:
DC SN 29:
DC SN 29:
DC SN 29:
DC SN 30:
00
20
30
39
45
54
08
1.
RO
RO
RO
RO
RO
RO
32-1.78
1,
1,
0
0
0
0
0
.00
.75
.17
.50
.60
.73
.38
0 Peaks
DC NL 0:
28:
28:
29:
29:
29:
29:
30;
30:
00
19
47
10
:20
:27
:52
:14
49
1.
RO
RO
RO
RO
RO
4.
766.
44 2.09
63
2.35
1,013
0.
0.
0.
0.
0.
0,
0.
0,
.13
,11
,12
,05
,10
.13
.05 -
.00
.32-1.78
1
1
1
1
0
1
1
I
I
.11
.51
.80
.57
.89
.34
.53
.09
.00
8 Peaks
DC NL 0:
DC SN 29:
DC SN 29:
:00
;37
:49
1
RO
RO
RO
.32-1.78
1
2
1
.00
.00
.22
0 Peaks
DC NL 0;
29:
29
30
30
;00
:07
:17
:13
:20
DC SN 30:45
363-370
HxCDF
374-376
1
RO
RO
RO
RO
0.
18,
0
308
1
2
301
0
0
633
.16
.55 11.15
.89 0.63
.06 188.06
.28 0.78
.78 1.59
.10 182.19
.41 0.25
.92 0.56
.99
0.928-1.063
0.000
1.006
1.011
1
.017
1.020
1
.025 23478-PeCDF AN
1.033
0.863-1.137
0.000
7.40
0.35
120.00
0.88
1.19
118.91
0.23
0.56
0
.971
0.987
1
1
1
1
1
1
.000 13C12-PeCDF 123 IS2
.006
.010
.024 13cl2-PeCDF 234 SOR1
,037
.057
0
0
0
0
.13
.13
,18
.00
.32-1.78
0
1
2
1
1
2
4 Peaks
DC NL 0
DC SN 31
DC SN 32
DC SN 32
DC SN 33
:00
:50
:1S
:20
:02
1
RO
RO
RO
RO
RO
.89
.00
.74
.48
.44
.11
0
0
0
208
17
0
226
^*-.rrv
.05-1.43
0
2
0
0
1
.90
.00
.67
.33
.50
0
0
0
0
0
.13
.48 0.29
.59 0.63
.19 124.24
.71 10.45
.23
.97
F1 / HhrffYB1 I?/*! "\ 1 ("Hire
.16
.16
.04
.02
.04
0.
0.
0.29
0,23
83.95
7.26
0.
937-1.022
0
0
0
,000
.980
.987
868-1.132
0
0
0
1
1
1
.000
.964
.969
.000 13C12-PeCDD 123 IS3
.004
.018
963-1.048
0
0
0
0
1
.000
.973
.985
.988
.009
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:28 04/20/!
-------
Page No,
04/20/98
Listing of S982310B.dbf
Matched GC Peaks / Ratio / Ret, Time
Compound/
M_Z. . . . QC.Log Omit Why . ,RT. OK Ratio Total. Area. . . Area-Peak.1,. Area. Peak. 2, * Rel.RT Coi^pound-Same.. ID,. Flags,
374-376
13C12-HXCDF
384-386
384-386
HXCDD
390-392
D
390-392
13C12-HXCDD
402-404
402-404
HpCDF
408-410
D
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
d
DC
DC
DC
DC
DC
DC
DC
DC
DC
d
SN
WH
WH
0
NL
SN
SN
SN
SN
8
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
6
NL
SN
SN
33:05
34:34
34:38
Peaks
0:00
31:40
31:47
32:38
32:44
32:58
33:01
33:03
33:15
33:29
33:32
34:03
34:22
Peaks
0:00
32:26
32:34
32:38
32:43
32:49
32:58
33:03
33:09
33:17
Peaks
0:00
32:50
33:22
33:27
33:47
34:01
34:13
Peaks
0:00
35:50
35:55
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
0.
RO
RO
1
0
3
43
0
0
0
0
0
0
0
0
0
0
0
0
' 0
.38
.40
,50
-0.59
.87
.60
.54
.50
.50
.23
.27
.18
.50
.42
,69
.51
.67
0.
0.
0.
0.
19
04
04
00
1
1
1
.011
.056
.058
0.878-1.122
0.
3.
6.
254.
303.
0.
0.
0.
327.
0.
0,
259.
0.
1.156.
tr**r^r*T!
05-1.43
1
3
1
1
2
1
0
0
0
2
.29
.00
.00
,00
.13
,20
.60
.70
.75
.44
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
23
47 1.37
79 2.39
40 84 . 46
42 101.46
18
09
18
85 109.60
56 0.19
20
19 87.04
32 0.14
00
16
04
07
25
18
22
05
13
05
20
00
05-1.43
1
1
1
1
1
1
1
.56
.46
.20
.21
.19
.39
.94
0.
1.
199.
262.
291.
0.
0.
756.
,88-1.20
0
2
0
,81
.75
.90
0.
0.
0.
20
57 1.02
35 108,74
94 143.85
63 158.76
86 0.50
38 0.33
73
i / Mri!™ TVE? tr/O 1 ntftis
26
08
40
0
2.30 0
4.40 0
169.94 0
201.96 1
1
1
1
218.25 1
0.45 1
1
172.15 1
0.21 1
.000
.967
.971
.997 13C12-H3CCDF
.000 13C12-HXCDF
.007
.009
.010
.016 13C12-HXCDF
.023
.024
.040 13C12-HXCDF
.050
478 SUR2
678 IS4
234 ALT2
789 ALT1
0.958-1.014
0
0
0
0
0
0
0
0
0
0
.000
.970
.974
.976
.978
.981
.986
.988
.991
.995
0.970-1.030
0
0.70 0
90.61 0
119.09 1
132.87 1
0.36 1
0.17 1
.000
.982
.998 13C12-HXCDD
.000 13C12-HXCDD
.010 13C12-HXCDD
.017
.023
478 SUS3
678 IS5
789 RS2
0.997-1.051
0
1
1
.000
.003
.005
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitoia Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:28 04/20/98
J n.-.:
-------
Page No.
04/20/98
Listing of S982310B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Confound.Name.. ID.. Flags.
408-410
0 Peaks
0.00
13C12-HpCDF
418-420
418-420
HpCDD
424-426
424-426
13C12-HpCDD
436-438
436-438
DC NL 0:00
35:44
36:07
37:22
3 Peaks
DC NL 0:00
DC SN 36:13
DC SN 37:02
0 Peaks
DC NL 0:00
36:04
36:52
2 Peaks
0.37-0.51
RO 0.93
0.42
RO 0.95
0.43
0.88-1.20
RO 1.25
RO 4.50
RO 0 . 67
0.88-1.20
1.14
0.94
1.01
0.22
204.45 60.09
0.32 0.21
155.83 46.84
360.60
0.16
0.04
0.08
0.00
0.30
2.41 1.17
217.46 109.39
219.87
0.944-1.112
0.000
144.36 1.000 13C12-HpCDF 678
0.22 1.011
108.99 1.046 13C12-HpCDF 789
0.976-1.005
0.000
0.982
1.005
0.973-1.027
0.000
1.24 0.978
108.07 1.000 13C12-HpCDD 678
IS6
SUR4
IS7
OCDF
442-444
442-444
OCDD
458-460
458-460
13C12-OCDD
470-472
470-472
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
. DC
DC
DC
NL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
SN
SN
SN
SN
SN
0
NL
1
0:
36
37
37
38
38
38
38
39
39
39
:00
:37
:50
:55
:01
:38
:43
:50
:08
:15
:18
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
76-1.02
1.
0.
0.
3.
1.
0.
2.
0.
0.
0.
0.
00
75
75
50
67
40
00
19
71
10
31
Peaks
0
40
40
40
41
41
:00
:41
:54
:54
:06
:12
0.
RO
RO
RO
RO
RO
0
0
0
0
0
0
0
0
0
0
0
0
.16
.19
.13
.04
.17
.04
.09
.06
.11
.02
.08
.00
76-1.02
1.
6.
0.
0.
0.
0.
00
50
75
43
50
50
Peaks
0
40
:00
:42
0.
RO
0
0
0
0
0
0
0
.16
.04
.06
.06
.08
.02
.00
.76-1.02
1.
0.
13
85
Peak
0
337
337
.15
.69
.69
Above: HpCDD / Octa-CDD and CDF Follows
.902-1.098
0.000
0.900
0.930
0.932
0.934
0.949
0.951
0.954
0.962
0.964
0.966
0.902-1.098
0.000
1.000 OCDD
1.005
1.005
1.010
154.89
1.012
0.996-1.004
0.000
182.80 1.000 13C12-OCDD
138
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:28 04/20/98
363
-------
Page No.
04/20/98
Listing of S982310B,dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omit Why ..ST. OK Ratio Total.Area.., Area,Peak.1., Area,Peak.2.. Rel.RT Confound. Hame,. ID., Flags.
Column Description.
"Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time !mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio outside Limits
Rel.RT-Relative Retention Time
*** End of Report ***
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
evel
A-Peak Added
K-Peak Kept
D-Peak Deleted
T-Time Changed
M-Peak Area Changed
N-Naine Changed
X-Ether Interference
Triangle Laboratories, Inc.® Analytical Services Division
801 Capiiola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:28 04/20^9
-------
File ;SS 823 10 #1-746 Acqs 1B-APR-1998 15:13:36 EI+ Voltage SIR 70S No±se:78
303.9016 F:2 BSUB(256,30, -3. 0) rXD(9,5,5f 0,05%,312.0,1.00%,F, T) ExpsNDSSUS
TRIANGLE LABS Text : TL 1*4539 9 M23-RB-1-4 JJKT. TIME = 15:16
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8987 F:2 BSUS{256,30, -3.0) Pm(9,5,5, 0 .QS\,252.0,l.QO%rF, T) Exp:NDB5US
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9419 F:2 BSVB(256,3Q, -3.0) PKD(9, 5,5,0. 05%,324. 0,1. 00%,F,T; Exp:NDB5US
NGLE LABS Text:TLI#45399 M23-RB-1-4 INJ. TIME " 15:16
Al . fOES
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365
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24.-00 25s 00 26s 00
File:S982310 #1-746 AcqslS-APS-1998 15:13:36 EI+ Voltage SIS 70S Noisei96
331.9368 F:2 BSUB(2S6,30, -3.0) PKD(7,5,3, 0.05%,384.0,1.00%,F, T) Exp:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-RS-1-4 IUKT. TIME = 15:16
1001 A2.03E6
l.34S6
File:S982310 #1-746 Acq:18-APR-lS98 15:13:36 EI+ Voltage SIR 70S Noise:43
319.8965 F:2 BSUB(256r30,-3.0) PKD( 7,5,3, 0.051,172.0,1.00%, F, T) Exp:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-RB-1-4 IJKT. TIME = ISilS
1004
80J
24s00 25:00 26:00
File:S982310 #1-746 Acqsl8-APR-1998 15:13:36 EH- Voltage SIR 70S Noise:52
321.8936 F:2 BSaB(256,30, -3.0) PKD(7,5, 3,0.05%,208.0,1.00%,F, T) Exp:NDB5US
TRIANGLE LASS TextsTLI#45399 M23-RB-1-4 INJ. TIME = 15:16
1004 A626.47
27:00
27-00
401
201
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24s 00 25:00 26:00
File:S982310 #1-746 AcgslB-APS-1998 15:13:36 EH- Voltage SIS 70S Sbise:75
333.9338 Fs2 BSUB(256,30,'--3. 0) PKD(7,5, J,0.05%,304.0,1.00%,F,T) Exp-.NDBSUS
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1004 >• A2.56E6
27-00
801
601
401
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24:00 25:00 26i00
File.-SS82310 #1-746 &cq:18-APR-1998 15:13:36 EH- Voltage SIS 70S Noise:67
327.8847 F:2 BSUB(256,30,.-3.0) ¥KD(7,S,3,0.05\,26&,Orl.QQ%,F,T) Exp:NDB5US
TRIANGLE LABS TextsTLI#45399 M23-RB-1-4 IWJ. TIME - 15:16
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601
401
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24:00 25:00 26:00
File,-SS82310 #1-746 Aoq:lB-APR-lS98 15:13:36 EH- Voltage SIS JOS
330.9792 f:2 ExpsXDBSCFS
TRIANGLE LABS Text:TLIf45399 M23-SS-1-4 JWT. TIME
1004
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-------
File:S38-2310 #1-746 Acq:18-APR-1998 15:13:36 EI+ Voltage SIR 70S JKt±ae:39
339.8597 F:2 BSUB(256, 30, -3 . 0) WOJf 7,5,3, 0. 05%,15ff, 0,1. OQ%,F, T) ElpiNOBSUS
TRIASSLE LABS Text:TLI#45399 M23-RB-1-4 HOT. TIME = 15:16
1003,
28:00 29:00 30:00
File:S982310 #1-746 Acq:lB-APR-1998 15:13:36 EI+ Voltage SIS 70S Noi.ae-.41
341.8567 F:2 BSUB(25S,30, -3.0) PXD( 7,5,3, 0.051,164,0,1. 00\,F,T) Exp:Nt>B5US
TRIANGLE LABS Text:TLI#45399 M23-MB-1-4 ZJKT. TIME = 15:16
1004 A4. 3S3
28800 . 29:00 30:00
File:S982310 #1-746 Acq:18-APR-1998 15:13:36 EI+ Voltage SIS 70S Noiae:49
351.9000 F:2 BSUB(256,30^-3 .0) PJO>(7, 5,3, 0. 05%,1S(5. 0,1.00\,F, T) Elp.-WDBSCTS
TRIANGLE LABS Tezt:TLI#45399 M23-SB-1-4 INJ". TIME = 15:16
1004 A1.88E6 A1.$2E6
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353.8970 F:2 BSUB(256,30, -3.0) PXD(7,5,3, 0.05%,176. 0,1.00t,F, T) ExpsNIIBSUS
TRIANGLE LABS Teit:TLI#45399 M23-RB-1-4 ZNU. TIME ' 15116
A1.20E6 A1.19E6
80J
40:
20:
0:
31: 00
28:00 29:00 30:00
File:S982310 #1-746 Acq:18-APR-1998 15sl3s36 EH- Voltage SIM 70S
330.9792 F:2 Exp:NDB5US
TRIANGLE LABS Teit:TLI#45399 M23-RB-1-4 UKT. TIME = 15:16
27:20 27:44 2*A16 29:00 ^ 21,35 30:OS
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TRIANGLE LABS Text:TLI#45399 M23-RB-1-4 IJKT. TIME = 15:16
100* 29:46
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60:
40:
20:
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31:00
31:02
Time
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30:00
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367
-------
File;S932310 '91-746' Ac
-------
File:SSS2310 #1-465 AcqilS-APR-1998 15:13:36 EI+ Voltage SIS 70S Noisse:44
373,8208 F:3 BSUB(256,30, -3. 0) PKB(7,5,3, 0.05%,176. 0,1.00\,f, T) ExpsNDBSUS
TRIANSLE LABS Text.:TLI#45399 M23-SB-1-4 JUST. TIMS = 15:16
10C3j.S530.26
31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 331-35 331-48 341-00 34:12 34:24 34.-36
File:S382310 #1-465 Acq:18-APS-1998 15:13:36 EI+ Voltage SIR 70S Noige:48
375.8178 F:3 BSUS(256,30t-3.0) PKD(7,5,3,0.05%,152.0,1.QO\,rrT) Exp:m>B5US
TRIANGLE LABS Text :TLX1t4 5399 M23-SB-1-4 INj; TIME - 15s 16
100*
31-36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34:12
File:S982310 #1-465 Acq:18-APR-1998 15:13:36 Eli- Voltage SIR 70S Noiae:66
383,8639 F:3 BSUSf256,30, -3. 0) PKD(7,5,3, 0.05%,264.0,1.00%,.P, T) Exp:NDB5US
TRIANGLE LABS Ttuct:TLI#45399 M23-RB-1-4 IlKT, TIME = 15:16
10i» A1.01E6 MJ..10XS
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Time
34:24 34:36
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31:36 31.-48 32:00 32:12 32:24 32:36 32:48 33:00 33:12 33:24 33:36 33:48 34:00 34:12 34:24 34:36
File:S982310 #1-465 Acg:l'8-APR-1998 15:13:36 EI+ Voltage SIR 70S »oise:74
385.8610 F:3 SSUB(256,30,-3.0) PKD(7,5,3, 0.051,296.0,1.00\,F,T) ExpsNDBSUS
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FilesS982310 #1-465 AcqtI8-APS-199S 15:13:36 EH- Voltage SIR 70S
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TRIANGLE LABS TextsTLI#45399 M23-RB-1-4 XJKT, 33MB = 15sl6
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TRIANGLE LASS Text:TLI#45399 M23-RB-1-4 XIKT. TIME =
1004
15:16
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401.8558 F:3 BSUB(256,30, -3.0) PKD(7,5,3,0.051,272.0,1.00*,F,T) EjcpsNVSSUS
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-------
FilesS9B2310 #1-569 Acq:18-APS-1998 15:13:36 EH- Voltage SIS JOS Soisei64
407.7318 F:4 BSUB(256,30, -3. 0) PKS(7, 5,3, 0. 051,256.0,1. 00%,JT, T) Exp:NDB5US
TXIAWSLS LABS Text:TLI#45399 M23-BB-1-4 1ST. TIME = 15s 16
1003, •' -
t\ :
35:48 36:00 36:12 36:24 36:36 36:48 37:00 37:12 37:24
File.-S382310 #1-569 Acq:18-APR-1998 15:13:36 Ell- Voltage SIR 70S Mbise:79
409.7789 Fs4 BSUB( 256,30,-3 .0 ) PKD( 7, 5,3, 0, 05%,316.0,1.00%,F, T) Exp:lTDB5US
TSIAKSLS LABS Text;TLI#45399 M23-SB-1-4 IWJ. TIME - 15:16
1003
SO:
60
40:
20:
35:48 35:00 36:12 36:24 36:36 36:48 37:00 37:12 37:24
File:S982310 #1-565 Acq:18-APR-1998 15:13:36 Eli- Voltage SIX JOS Hbise:69
417.8253 F:4 BSUB(256,30, -3. 0) FKD(7, 5,3, 0. 05%,276. 0,1.00*,F,T) Exp:NDB5US
TRIANGLE LABS TextiTLIf45399 M23-SB-1-4 IffiJ. TIME = 15:16
100i.A6.giE5
37:36 37:48
80:
60:
40:
20:
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A4.68E5
35:48 36:00 36:12 36:24 36:36 36:48 37:00 37:12 37:24
FilesS9B2310 #1-569 acg:18-APB-1998 15.-13.-36 EX-*- Voltage SIS 70S J9bise:74
419.8220 Fs4 BSOB(256,30,~3.0) PKD(7,5,3, 0. 051,296.0,1. 00%,F, T) Exp:KDB5US
TRIANGLE LABS TextiTLI#4'5399 M23-RB-1-4 INJ. TIME - 15:16
100JUil.44.E6
so:
60:
40:
20:
0:
Al.09E6
35s48 36s 00 36.-12 36:24 36:36 36;48 37:00 37.-12 37:24
File:S982310 #1-569 Acg-slB-APS-1998 15:13:36 EH- Voltage SIR 70S
430.9729 fs4 Exp:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-RB-1-4 INJ. TIME = 15:16
1003
so:
60:
40:
20:
o:
37:36 37:48
T
T
I I I I I
37s 12
35:48 36:00 36:12 36:24 36:36 36i48 37:00
File:S982310 #1-569 Acq:18-APR-1998 15:13:36 EH- Voltage SIS 70S
479.7165 Fi4 ExpiXDBSUS
TRIANGLE LABS Tex-t:TLI#45399 M23-XB-1-4 INJ', TIME =
1003j
i * 36:11
'37t36 ' 37\4S
15:16
so:
60:
40:
20:
o:
36:22
36:54
35:48
36:00
36s12 ' '38:24
36:36
36:48
37:00
' I i i i i i I i i
37:12 37:24
i i i"i'"i i i i i I i i
37:36 37:48
1.1E3
8.7E2
6.6E2
.4.4E2
2.2E2
O.OEO
Time
1.2E5
.9. 7E4
.7.3E4
4.9E4
.2.4E4
.O.OEO
Time
.3. QES
.2.4E5
.1. 8B5
.1.2JB5
.5.9E4
.O.OJJO
Euae
.3.6E5
.2.9E5
.2.2ES
.1. 5E5
.7.3E4
.O.OEO
Time
.1. 7E3
.1. 4E3
.1. OE3
.6.BE2
.3.4E2
.O.OEO
Time
-------
FilB5nS
TRIANGLE LABS Text:TLH45399 M23-MS-1-4 IKT. TIME = 15sl6
1004 A1.Q8E6
so:
60.
20:
O.OEO
Time
1.6E5
,1. 3E5
.9. 7E4
6.5E4
.3.2E4
O.OEO
Time
_1. 6E5
1. 3E5
9.5E4
6.3E4
3.2E4
ryffil1 ! 1 rTf"! I t'l I f 1 1 f"f"! I 'I'""I '!""t ft 'r'T'yr'rT I'! |m| t'TT"T"T-T'T' 1~fT-"r { f"*-^T^""1 r't l"» I I 1 T t jg'irfl'T rml 'I f T""f ^""t T"T"T""T"1
3£.'0£ J5.-06 J5.-12 3SslS 36:24 36:30 36:36 3$s42 3£t48 36:54 37:00 3?s06 37sl2 37:18
.O.OEO
Time
File:S982310 #1-569 Acqsl8-APX-1998 15:13:36 EH- Voltage SIX 70S
430.9729 F:4 Exp-.NDBSUS
TRIANGLE LABS Text:TLI#45399 M23-RB-1-4 INJ. TIME
15:16
1002
80J
eo:
40:
20:
o1
36:08 36:14 36-41 36:53 37:08 37:19
3 . 5E5
12.8E5
12.1E5
11 . 4E5
".7.0E4
" 0 . OEO
36:00 36:06 36:12 36:18 36:24 36:30 36:36 36:42 36:48 36:54 37:00 37:06 37:12 37:18
70
I ««
-------
File:S982310 #1-569 Acq;ia-APK-lS98 15:13
441.7428 F:4 BSOS(256, 30, -3.0) PKD(7r5,3,
TRIANGLE LABS Text:TZI#45399 M23-S.B-1-4
1003
901
801
701
sol
sol
401
301
201
101
0:
File
443.
TSIA
1001
901
sol
701
601
sol
401
301
201
101
0
rile
430.
TSIA
1004
901
a 01
701
601
501
401
301
201
10J
o-
File
513.
TSIA
1003
901
601
701
601
501
401
301
201
101
o-
36:00 37:00 38:00
.-S982310 #1-569 Acqsl8-APS-1998 15:13
7399 F:4 SSUB(256r30, -3 .0) PKD(7,5,3,
HSLE LABS Text:TLI#45399 H23-MB-1-4
^v^ m ..t
36:00 ' ' ' 37sOO ' ' ' 38:00
:S982310 #1-569 Acg:18-APS-1998 15sl3
9729 F:4 ExpiNDBSVS
W3LE LABS Text:TLIt45399 M23-RB-1-4
M,SfS 37:08^7:34 38:06
"^^^vvA^vvJfifv^^^
1 1 ¥
i36 EI+ Voltage SIM 70S Noise:41
0. 051,164. 0,1.00*,F,T) ExpiNDBSUS
OTT. TIME - 15:1S
2 . 4E4
39[:00 ' ' 40-00 ' ' ' 41:00 ' ' ' 421-00
:36 EI+ Voltage SIS 70S lK>iae:41
0,05%,164.0,1.00%,F,:r; Exp:W)S5US
IfKJ. TIME = 15:16
^J^^^-^ fl,,, -- — ---..- ^ „ J _ „- - ,.. A ^ x _^_A-.
3S:00 ' ' ' 40:00 41:00 42:00
-.36 EH- Voltage SIS 70S
INJ-. TIME = 15:16
38:33 39:01 3a.36 40:51
fiJ^dH^t^W^
JffsOO ' ' ' J7.-00 ' ' ' J8.-00 ' ' ' 33-00 ' ' " 40:00 ' ' ' 41:00 ' ' ' 42:00
:S982310 il-569 Acq:ia-APS-199S 15:13:36 EH- Voltage SIS 70S
6775 F:4 ErpsHDB5OB
OGLE LABS Text;TZXt45399 M23-SB-1-4 JWJ, TIME - 15tl6
,36l3,6 ' , 37:34 38\06
Wv^jJ™s*^^^
JS-OO J7.-00 38-00
41:46
39:03 39:49 40,15 4°l41 4J. : 09 , j i
V>^'*i*sv~il**^'*i™***J*A^
39:00 40:00 41:00 42:00
-.2.2E4
LI . 9E4
ll . 7E4
_1,4E4
JL.2E4
^9.6E3
-7.2E3
14.8E3
L2.4E3
- 0 . OEO
Time
_1 . 7E4
•-1 . 6E4
L1.4JE4
L1.2JET4
Ll . OJET4
1.8.7E3
-7.0E3
:.5.2E3
.3.5E3
.1 . 7E3
O.OEO
Time
^3.6E5
-3.3E5
.2.9E5
-2.6E5
.2.2E5
.1 . BE5
.1.5E5
.1.1E5
-7.JE4
-3.6E4
O.OEO
Time
3.8E3
.3.SE3
-3.1E3
.2.7E3
-2.3E3
.1.9E3
.1.5EJ
.1.2E3
-7.7E2
,3 , 8E2
O.OEO
Time
-------
File:3962310 il-565 '"Acq: 18-APX-1998 15-.13-.3S Ef+ Voltage" SIX 70s wSi5e:J3
457,7377 F:4 SSVS(256r30,-3,0) PKD( 7,5,3, 0. 05%,156. 0,1. 00%, T, T) Exp:NDB5US
TRIANGLE LASS Text:TLI#45399 M23-XB-1-4 ZKT. TIME = 15:16
1004 A1.34E3
40 36 40:42 40:48 40:54 41:00 41:05
File:S982310 #1-569 Acq:18-APR-1998 15:13:36 EH- Voltage SIX 70S Noise:43
469.7779 F:4 BSUB(256r30,-3.0) PfJ>(7,5,3, 0. 05%, 172. 0,1. 00f 7, 5,3, 0. 05%, 152. 0,1. 00%, f, T) Exp:NDB5US
TRIANGLE LABS Text:TLI#45399 M23-BB-1-4 INJ~. TIME = 15s 16
100%
A245.59
eo:
40:
2.0.
41:12
40 36 40:42 * 40:48 40:54 41:00 41:06
F±leiS982310 #1-569 Acq:18-&fX-1998 15:13:36 EH- Foltagre SIX 70S W}±se:41
471.7750 F.-4 BSm(2S6,30;-3>.0) fJO>( 7,5, 3,0. 05%, 164,0,1.00%, F,T) ExpiXDBSUS
TRIANGLE LABS Text.:TLI#45399 M23-RB-1-4 INJ~, TIME = 15:16
1003. A1.83E6
40:36 40:42 40:48 40:54 41:00 41:06
F±le:SS82310 #1-569 Acq:18-APS-1998 15:13:36 EI+ Voltage SIX 70S
430.9729 F:4 ExpsNDBSVS
TRIANGLE LABS TeXt:TLI#45399 M23-XB-1-4 INJ. TIME = 15:16
1004 40:41 fOj51 41:00
so:
eo:
40:
20.
0.
41sl2
41s 12
40 36
40:42
40:48
40:54
41:00
41:06
'41sl2
.2.7E2
.2.2E2
.1. 6E2
.1.1E2
.5.5E1
.0. OEO
Time
.1. 7E5
.1.3E5
.9.9E4
.6.6E4
.3.3E4
.O.OEO
Time
.1.9E5
.1.5E5
J..2E5
.7.7E4
.3. 9E4
.0 . OEO
Time
.3.5E5
.2.815
.2.1E5
.1.4E5
.7.0E4
.0. OEO
Time
3 fn*j
I
-------
Chanel I 338,9792 Peak bop
Height ,33 volts Span 298 ppi
Systea file nae NDB5US
Data filera* frS982384
Resolution 18668
Group nmber 2
lomzatlon nde El*
Sultchlng VOLTffiE
lasses 292,9825, 416,9768
J 331 S 368
K 332 T 378
L 334 U 376
H 348 V 418
N 342
0 352
P 354
Q 356
R 358
, uss 416,9768 Peak top
Height ,88 volts .Span 288 ppi
37-
-------
CALIBRATION
DATA
Triangle Laboratories, Inc.
801 CapHola Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
919-544-5729 Fax # §19*44-5491
370
-------
Analysis Date
Instrument
Analytas
Total MCDF
Total MCDD
Total DCDF
Total DCDD
Total TriCDF
Total TriCDD
1368-TCDF
2378-TCDF
TOTAL TCDF
1368-TCDD
1379-TCDD
2378-TCDD
TOTAL TCDD
12373-PeCDF
23478-PeCDF
•TOTAL PeCDF
12373-PeCDD
TOTAL PeCDD
123473-HxCDF
123678-HxCDF
234678-HxCDF
123739-HxCDF
TOTAL HxCDF
"123478-HxCDD
123678-HxCDD
123739-HxCDD
TOTAL HxCDD
1234678-HpC
1234789-HpC
TOTAL HpCDF
1234678-HpC
TOTAL HpCDD
QCDF
OCDD
37C1-TCDD
Initial Calibration Summary for UF51Q58
Method.,....: MIT2
• tJ
RF SD
0.000 0.000
0.000 0.000
0.000 0.000
0.000 0.000
:DF o.ooo o.ooo
:DD o.ooo o.ooo
1.298 0.073
1.240 0.132
1.240 0.132
0.715 0.032
0.360 0.021
1.240 0.160
3 1.240 0.16Q
DF 1.051 0.090
DF 1.019 Q.078
DF 1.035 0.084
DD 1.333 0.125
DD 1.333 0.125
ZDF 1.0C7 0 .074
ZDF 1.253 0.089
ZDF 0.985 0.082
ZDF 0.870 0.047
DF 1.029 0.071
CDD 0.765 0.051
CDD 0.976 0.079
CDD 0.941 0.068
DD 0.894 0.064
pCDF 1.410 0.098
pCDF 1,095 0.071
DF 1,253 0.084
pCDD - 0.995 0.051
:DD 0.995 0.051
1.377 0.070
1.108 0.080
indards RF SD
) 1.001 0.056
:DF 234 0.966 0.010
ZDF 478 0.825 0.042
:DF 234 0.902 0.043
ZDF 789 0.695 0.042
2DD 478 0.732 0.024
ZDF 789 0.802 0.016
%RSD
100%
100%
100%
100%
100%
100%
6%
11%
11%
4%
6%
13%
13%
9%
3%
8%
9%
9%
7%
7%
8%
5%
7%
7%
8%
7%
7%
7%
6%
7%
5%
5%
5%
7%
%RSD
6%
1%
5%
5%
6%
3%
2%
RT
21:
24:
22:
23:
25:
28:
29:
29:
32:
32:
32:
33:
32:
32:
33:
35
36
36
39
39
26
36
46
10
19
3 3
14
34
01
07
36
:22
:43
:47
:Q6
:00
:31
:01
:47
:35
RT
25
29
32
32
33
32
36
:19
:14
-.01
:35
:21
-.42
:30
RT/LO
4:35
5:18
11:35
12:18
15:35
17:
23:
24:
24:
25:
23:
28:
30
32
35
35
18
35
18
32
34
06
:47
:59
:00
:34
:34
RT/LO
23
26
32
:18
:32
:59
RT/HI Ratio 1 Ratio2
18:35
19:18
19:35
20:18
22:35
23:
30:
31:
32:
33 :
36:
36:
38
40
43
43
18
35
18
32
34
06
;47
:59
:00
:34
:34
RT/HI
27
30
38
:18
:32
:59
0.
0.
0.
0.
0.
0.
0.
1.
1,
1.
1.
1.
1.
1.
1.
1.
1.
1,
1,
1
1
1
1
1
1
1
0
0
745
743
744
776
786
787
781
525
530
S2S
530
530
233
245
262
,263
.262
.257
.211
.234
.232
.060
.049
.055
.028
.023
.891
.836
Ratiol Ratio2
1
0
0
0
1
0
.498
.509
.508
.504
.214
.431
N
0
0
0
0
0
0
6
6
6
6
6
6
6
5
6
6
5
6
8
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
N
6
6
6
6
6
6
6
Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Roc (919) 544-5491
Printed: 15:16
-------
Internal Standards
13C12-2378-TCDF
13C12-237S-TCDD
13C12-5eCDF 123
13C12-PeCDD 123
13C12-EXCTF 678
13C12-HxCDD S78
13C12-HpCDF S78
13C12-HpCDD 678
13C12-OCDD
Recovery Standards
13C12-1234-TCDD
13C12-ExCDD 789
RF
1.467
1
1
0
1
0
0
0
Q
1
1
.113
.142
.590
.346
.995
.822
.726
.545
RF
.000
.000
0
0
Q
0
Q
0
Q
0
0
0
0
SO
.053
.049
.075
.043
.038
.017
.013
.011
.038
SD
.000
.000
%RSD
4%
4%
7%
8%
3%
2%
2%
2%
7%
%RSD
0%
0%
RT
24:35
25
28
29
32
32
34
36
39
25
33
:18
:32
:34
:Q6
:47
:59
:00
:34
RT
:Q8
:05
RT/LQ
23:35
23:
24:
25:
28:
31:
32:
35:
37:
13
32
34
06
47
59
00
34
RT/LQ
RT/HI
25:35
27:18
32:32
33:34
36:06
33:47
38:59
37:00
41:34
RT/HI
Ratio 1
0.7SS
0.807
1.478
1.506
0.506
1.216
0.434
1.018
0.861
Ratio 1
0.812
1.210
Ratia2
6
6
6
6
6
6
6
6
6
N
6
6
*** End of Report ***
Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftoia Drive * Durham, North CaroBna 27713
Phone: (919) 544-5729 * Fax: (919) 544-5491
Printed: 15:16
0*37
-------
Dace: U4/13/3S
TK.UUWJJLI& LiAtfUKATUKljeS Uif KTf, IMC.
Continuing Calibration for U980771
Operator :
Xnit Calibration. •
ICal Date :
Analyte Summary
Name
Total MCDF
Total MCDD
Total DCDF
Total DCDD
Total TriCBF
Total TriCDD
1368-TCDF
2378-TCDF
TOTAL TCDF
1368-TCDD
1379-TCDD
2378-TCDD
TOTAL TCDD
12378-PeCDF
23478-PeCDF
TOTAL PeCDF
12378-PeCDD
TOTAL PeCDD
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
W/ *.<~t 1 •* \J
DL
W51Q58
01/05/98
RF Ratio
1&2
0.000
0.000
0.000
0.000
0.000
0.000
1.285 0.76
1.227 0.77
1.227 0.76
0.702 0.79
0.321 0.78
1.125 0.78
1.125 0.78
1.081 1.51
1.056 1.49
1.069 1.50
1.250 1.61
1.250 1.61
1.210 1.26
1.267 1.24
1.053 1.28
1.031 1.30
RT
Lo/High
3:22
17:22
4:08
18:08
10:22
18:22
11:08
19:08
14:22
21:22
16:08
22:08
19:43
25:22
21:12
25:20
25:16
29:26
26:35
29:17
30:00
32:44
Page
Instrument. . : tJ
Std Cone . . . . :
ICal I
RT Rel. RT RF
0.000
0.000
0.000
0.000
0.000
0.000
19:55 0.8524 1.298
23:23 1.0007 1.240
1.240
21:24 0.8867 0.715
21:50 0.9047 0.360
24:09 1.0007 1.240
1.240
27:34 1.0006 1.051
28:18 1.0272 1.019
1.035
28:39 1.0000 1.333
1.333
31:10 0.9968 1.007
31:17 1.0005 1.253
31:46 1.0160 0.985
32:30 1.0394 0.870
1
10.00
telta
RF %D
0.000 100.0%
0.000 100.0%
0.000 100.0%
0.000 100.0%
0.000 100.0%
0.000 100.0%
-0.013 -1.0%
-0.013 -1.1%
-0.013 -1.1%
-0.013 -1.9%
-0.039 -10.3%
-0.115 -9.3%
-0.115 -9.3%
0.030 2.9%
0.037 3,6%
0.034 3.2%
-0,083 -6.2%
-0.083 -6.2%
0.203 20.2%
0.014 1.1%
0.068 6.9%
0.161 18.5%
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:20 04/15/98
-------
Date: 04/15/98
TRIANGLE LABORATORIES OP RTP, INC.
Continuing Calibration Cor U9 80771
TOTAL HxCDF
123478-HxCDD
123678-HxCDD
123789-HxCDD
TOTAL HxCDD
123467 8-HpCDF
1234789-HpCDF
TOTAL HpCDF
1234678-HpCDD
TOTAL HpCDD
OCDF
OCDD
1.140 1.27
0.878 1.21
0.916 1.22
0.910 1.22
0.901 1.21
1.377 1.06
1.115 1.06
1.246 1.06
1.008 1.02
1.008 1.02
1.279 0.91
1.001 0.87
30:31 31:53 0.9979
32:24
31:58 1.0005
32:16 1.0099
33:54 34:05 1.0005
35:41
35:31 1.0426
34:10 35:04 1.0005
35:13
34:23 38:34 1.0048
42:23
34:23 38:24 1.0004
42:23
Other Standard Summary
Name
37C1-TCDD
13C12-PeCDF 234
13C12 -HxCDF 478
13C 12 -HxCDF 234
13C 12 -HxCDF 789
13C 12 -HxCDD 478
13C 12 -HpCDF 789
RF Ratio
1&2
0.972
0.932 1.47
1.005 0.51
0.977 0.50
0.834 0.49
0.939 1.20
0.866 0.42
RT RT Rel. RT
Lo/High
22:08 24:09 1.0007
26:08
23:33 28:17 1.0266
31:33
31:10 0.9968
31:46 1.0160
32:30 1.0394
31:53 0.9979
32:04 35:31 1.0426
38:04
Internal Standard Summary
Name
13C12-2378-TCDF
13C12-2378-TCDD
13C12-PeCDF 123
RF Ratio
1&2
1.484 0.76
1.121 0.81
1.085 1.49
RT RT Rel. RT
Lo/High
22:22 23:22 1.0000
24:22
22:08 24:08 1.0000
26:08
23:33 27:33 1.0000
31:33
Page 2
1.029 0.111 10.8%
0.765 0.113 14.8%
0.976 -0.060 -6.1%
0.941 -0.031 -3.3%
0.894 0.007 0.8%
1.410 -0.033 -2.3%
1.096 0.019 1.7%
1.253 -0.007 -0.6%
0.995 0.013 1.3%
0.995 0.013 1.3%
1.377 -0.098 -7.1%
1.108 -0.107 -9.6%
ICal Delta
RF RF %D
1.001 -0.029 -2.9%
0.966 -0.034 -3.5%
0.825 0.180 21.9%
0.902 0.075 8.3%
0.695 0.139 20.0%
0.732 0.207 28.3%
0.802 0.064 8.0%
ICal Delta
RF RF %D
1.467 0.017 1.2%
1.118 0.003 0.2%
1.142 -0.057 -5.0%
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:20 04/15/98
-------
13C12-PeCDD 123
13C12-HXCDF 678 1.289 0.51
13C12-HXCDD 678 1.043 1.23
13C12-HpCDF 678 0.879 0.43
13C12-HpCDD 678 0.741 1.06
13C12-OCDD 0.569 0.88
Continuing Calibration Cor 0980771
0.607 1.46 24:39 28:39 1.0000 0.590 0.017 2.8%
32:39
27:16 31:16 l.OOOQ 1.346 -0.057 -4.3%
35:16
30:57 31:57 1.0000 0.995 0.048 4.8%
32:57
32:04 34:04 l.OOQO 0.822 0,057 6.9%
38:04
34:03 35:03 l.OOQO 0.726 0.015 2.1%
36:03
38:12 38:23 1,0000 0.545 0.024 4.3%
38:32
Recovery Standard Summary ICal
Name RF Ratio RT RT Rel. RT KF
1&2 Lo/High
23:56 0.9917
Delta
RF
13C12-1234-TCDD
13C12-HXCDD 789
1.000 0.82
1.000 1.20
32:15 1.0094
1.000 0.000
1.000 0.000
%D
0.0%
0.0%
QC Front End Check:
1.5693
Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtota Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:20 04/1 S/9&
-------
APPENDIX C
CALCULATIONS
-------
-------
Summary of Stack Gas Parameters and Test Results
Air Emissions Screening Test
Chemical Lime Company - Montevallo, Alabama
US EPA Test Method 23 - PCDDs / PCDFs
Kiln No. 3 Baghouse Inlet
Page 1 of 6
RUN NUMBER
RUN DATE
RUN TIME
M23-3-I-2
3/24/98
1332-1709
\1I2
MEASURED DATA
Y Meter Box Correction Factor
AH Avg Meter Orifice Pressure, in. H20
Ptor Barometric Pressure, inches Hg
Vm Sample Volume, ft3
Tm Average Meter Temperature, °F
Pstatie Stack Static Pressure, inches H2O
Ts Average Stack Temperature, °F
Vte Condensate Collected, ml
CO2 Carbon Dioxide content, % by volume
O2 Oxygen content, % by volume
N2 Nitrogen content, % by volume
Cp Pilot Tube Coefficient
Ap1c Average Square Root Ap, (in. H20)1
0 Sample Run Duration, minutes
Dn Nozzle Diameter, inches
CALCULATED DATA
An Nozzle Area, ft2
Vm(5tdj Standard Meter Volume, dscf
Vm(sWS Standard Meter Volume, dscm
Ps Stack Pressure, inches Hg
B^s Moisture, % by volume
VvYsa Standard Water Vapor Volume, ft3
1-BWS Dry Mole Fraction
Md Molecular Weight (d.b.), Ib/lb-mole
Ms Molecular Weight (w.b.), Ib/lb-mole
Vs Stack Gas Velocity, ft/s
A Stack Area, ft2
Qa . Stack Gas Volumetric flow, acfm
Qs Stack Gas Volumetric flow, dscfm
Qs(cmm) Stack Gas Volumetric flow, dscmm
I Isokinetlc Sampling Ratio, %
1.021
1.23
30,00
101.856
81.8
-1.90
902
184.0
26.6
5.3
68.1
0.84
0.5592
180
0.310
0.00052
101.881
2.885
29.86
7.8
8.661
0.922
32.47
31.33
48.4
52.38
152,264
54,286
1,537
104.2
E:\r012.002\Monteval.lo\Data\M23monte.xls, sum K3-I-M23-2
-------
Summary of Stack Gas Parameters and Test Results
Chemical Lime Company - Montevallo, Alabama
US EPA Test Method 23 - PCDDs / PCDFs
Kiln No. 3 Baghouse Inlet
Page 2 of 6
ng
ng/dscm
ug/hr
ng
ng/dscm
Mg/hr
ng
ng/dscm
Mg/r«"
"9
ng/dscm
Mg/hr
ng
ng/dscm
Mg/hr
ng
ng/dscm
M9/hr
RUN NUMBER
RUN DATE
RUN TIME
EMISSIONS DATA
D1OXINS:
2378 TCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, ug/hr
Total TCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, ug/hr
12378 PeCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, ug/hr
Total PeCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, Mg/hr
123478 HxCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, Mg/hr
123678 HxCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, M9/hr
M23-3-I-2
3/24/98
1332-1709
(0.04)
(0.0139)
(1.28)
0.25
0.0867
7.99
(0.07)
(0.0243)
(2.24)
{0.11}
{0.0381}
{3.52}
(0.09)
(0.0312)
(2.88)
(0.08)
(0.0277)
(2.56)
() Not Detected. Value shown is the detection limit and is included in totals.
{} Estimated Maximum Possible Concentration. EMPC values are included in totals.
E:\r012.002\Monteval.lo\Data\M23monte.xls, sum K3-I-M23-2
-------
Summary of Stack Gas Parameters and Test Results
Chemical Lime Company - Montevallo, Alabama
US EPA Test Method 23 - PCDDs / PCDFs
Kiln No. 3 Baghouse Inlet
Page 3 of 6
RUN NUMBER
RUN DATE
RUN TIME
M23-3-I-2
3/24/98
1332-1709
EMISSIONS DATA -Continued
DIOXINS - Continued
123789 HxCDD
ng Catch, ng (0.08)
ng/dscm Concentration, ng/dscm, as measured (0.0277)
ug/hr Emission Rate, ug/hr (2.56)
Total HxCDD
ng Catch, ng 0.07
ng/dscm Concentration, ng/dscm, as measured 0.0243
ug/hr Emission Rate, ug/hr 2.24
1234678 HpCDD
ng Catch, ng (0.1)
ng/dscm Concentration, ng/dscm, as measured (0.0347)
ug/hr Emission Rate, |jg/hr (3.20)
Total HpCDD
ng Catch, ng (0.1)
ng/dscm Concentration, ng/dscm, as measured (0.0347)
ug/hr Emission Rate, ug/hr (3.20)
OCDD
ng Catch, ng {0.29}
ng/dscm Concentration, ng/dscm, as measured {0.101}
ug/hr Emission Rate, ug/hr {9.27}
Total PCDD
ng Catch, ng (0.82)
ng/dscm Concentration, ng/dscm, as measured (0.284)
ug/hr Emission Rate, ug/hr (26.2)
() Not Detected. Value shown is the detection limit and is included in totals.
{} Estimated Maximum Possible Concentration. EMPC values are included in totals.
E:\r012.002\Monteval.lo\Data\M23monte.xls, sum K3-I-M23-2
-------
Summary of Stack Gas Parameters and Test Results
Chemical Lime Company - Montevallo, Alabama
US EPA Test Method 23 - PCDDs / PCDFs
Kiln No. 3 Baghouse Inlet
Page 4 of 6
RUN NUMBER
RUN DATE
RUNTIME
M23-3-I-2
3/24/98
1332-1709
EMISSIONS DATA - Continued
FURANS
2378 TCDF
ng Catch, ng 0.51
ng/dscm Concentration, ng/dscm, as measured 0.177
ug/hr Emission Rate, ug/hr 16.3
Total TCDF
ng Catch, ng 12.1
ng/dscm Concentration, ng/dscm, as measured 4.19
ug/hr Emission Rate, ug/hr 387
12378 PeCDF
ng Catch, ng 0.21
ng/dscm Concentration, ng/dscm, as measured 0.0728
ug/hr Emission Rate, ug/hr 6.71
23478 PeCDF
ng Catch, ng 0.21
ng/dscm Concentration, ng/dscm, as measured 0.0728
ug/hr Emission Rate, ug/hr 6.71
Total PeCDF
ng Catch, ng 2.7
ng/dscm Concentration, ng/dscm, as measured 0.936
ug/hr Emission Rate, ug/hr 86.3
123478 HxCDF
ng Catch, ng 0.10
ng/dscm Concentration, ng/dscm, as measured 0.0347
ug/hr Emission Rate, ug/hr 3.20
() Not Detected. Value shown is the detection limit and is included in totals.
{} Estimated Maximum Possible Concentration. EMPC values are included in totals.
E:\r012.002\Monteval.lo\Data\M23monte.xls, sum K3-I-M23-2
-------
Summary of Stack Gas Parameters and Test
emical Lime Company - Montevallo, Alabama
US EPA Test Method 23 - PCDDs / PCDFs
Kiln No. 3 Baghouse Inlet
Page 5 of 6
RUN NUMBER
RUN DATE
RUN TIME
EMISSIONS DATA - Continued
Furans - Continued
123678 HxCDF
ng Catch, ng
ng/dscm Concentration, ng/dscm, as measured
ug/hr Emission Rate, ug/hr
234678HxCDF
ng Catch, ng
ng/dscm Concentration, ng/dscm, as measured
ug/hr Emission Rate, ug/hr
123789 HxCDF
ng Catch, ng
ng/dscm Concentration, ng/dscm, as measured
ug/hr Emission Rate, ug/hr
Total HxCDF
ng Catch, ng
ng/dscm Concentration, ng/dscm, as measured
ug/hr Emission Rate, ug/hr
1234678 HpCDF
ng Catch, ng
ng/dscm Concentration, ng/dscm, as measured
ug/hr Emission Rate, ug/hr
1234789 HpCDF
ng Catch, ng
ng/dscm Concentration, ng/dscm, as measured
ug/hr Emission Rate, ug/hr
Results
M23-3-I-2
3/24/98
1332-1709
{0,05}
{0.0173}
{1.60}
(0.06)
(0.0208)
(1.92)
(0.07)
(0.0243)
(2.24)
0.33
0.114
10.6
{0.05}
{0.0173}
{1.60}
(0.1)
(0.0347)
(3.20)
() Not Detected. Value shown is the detection limit and is included in totals.
{} Estimated Maximum Possible Concentration. EMPC values are included in totals.
E:\r012.002\Monteval.lo\Data\M23monte.xls, sum K3-I-M23-2
-------
Summary of Stack Gas Parameters and Test Results
Chemical Lime Company - Montevallo, Alabama
US EPA Test Method 23 - PCDDs / PCDFs
Kiln No. 3 Baghouse Inlet
Page 6 of 6
RUN NUMBER
RUN DATE
RUN TIME
M23-3-I-2
3/24/98
1332-1709
EMISSIONS DATA - Continued
Furans - Continued
Total HpCDF
ng Catch, ng {0.05}
ng/dscm Concentration, ng/dscm, as measured {0.0173}
ug/hr Emission Rate, ug/hr {1.60}
OCDF
ng Catch, ng (0.1)
ng/dscm Concentration, ng/dscm, as measured (0.0347)
ug/hr Emission Rate, ug/hr (3.20)
Total PCDF
ng Catch, ng (15.28)
ng/dscm Concentration, ng/dscm, as measured (5.30)
ug/hr Emission Rate, ug/hr (489)
Total PCDD + PCDF
ng Catch, ng (16.10)
ng/dscm Concentration, ng/dscm, as measured (5.58)
ug/hr Emission Rate, ug/hr (515)
() Not Detected. Value shown is the detection limit and is included in totals.
{} Estimated Maximum Possible Concentration. EMPC values are included in totals.
E:\r012.002\Monteval.lo\Data\M23monte.xls, sum K3-I-M23-2
-------
Summary of Stack Gas Parameters and Test Results
Air Emissions Screening Test
Chemical Lime Company - Montevallo, Alabama
US EPA Test Method 23 - PCDDs / PCDFs
Kiln No. 4 Baghouse Inlet
Page 1 of 6
RUN NUMBER
RUN DATE
RUN TIME
M23-4-M
3/23/98
1400-1808
Y
AH
Pbar
static
Ts
Vlc
CO2
02
N2
Ap
0
rp
1/2
v,
v«
m(std)
1-BW
Md
Ms
Vs
A
Qa
Q,
Us(cm
I
MEASURED DATA
Meter Box Correction Factor 1.021
Avg Meter Orifice Pressure, in. H2O 1.42
Barometric Pressure, inches Hg 30.00
Sample Volume, ft3 113.011
Average Meter Temperature, °F 72.2
Stack Static Pressure, inches H2O -3.40
Average Stack Temperature, °F 878
Condensate Collected, ml 118.9
Carbon Dioxide content, % by volume 20.1
Oxygen content, % by volume 8.1
Nitrogen content, % by volume 71.8
Pitot Tube Coefficient 0.84
Average Square Root Ap, (in. H2O)1/2 0.6080
Sample Run Duration, minutes 180
Nozzle Diameter, inches 0.310
CALCULATED DATA
Nozzle Area, ft2 0.00052
Standard Meter Volume, dscf 115.145
Standard Meter Volume, dscm 3.261
Stack Pressure, inches Hg 2i.75
Moisture, % by volume 4.6
Standard Water Vapor Volume, ft3 5.597
Dry Mole Fraction 0.954
Molecular Weight (d.b.), Ib/lb-mole 31.54
Molecular Weight (w.b.), lb/ib*mo!e 30.91
Stack Gas Velocity, ft/s 52.7
Stack Area, ft2 52.38
Stack Gas Volumetric flow, acfm 165,516
Stack Gas Volumetric flow, dscfm 61,921
Stack Gas Volumetric flow, dscmm 1,753
Isokinetic Sampling Ratio, % 103.3
E:\r012.002\Monteval.lo\Data\M23rnonte:x!s, sum K4-I-M23-1
-------
Summary of Stack Gas Parameters and Test Results
Chemical Lime Company - Montevallo, Alabama
US EPA Test Method 23 - PCDDs / PCDFs
Kiln No. 4 Baghouse Inlet
Page 2 of 6
RUN NUMBER
RUN DATE
RUN TIME
M23-4-I-1
3/23/98
1400-1808
EMISSIONS DATA
DIOXINS:
2378 TCDD
ng Catch, ng (0.03)
ng/dscm Concentration, ng/dscm, as measured (0.00920)
pg/hr Emission Rate, ug/hr (0.968)
Total TCDD
ng Catch, ng (0.03)
ng/dscm Concentration, ng/dscm, as measured (0.00920)
ug/hr Emission Rate, ug/hr (0.968)
12378PeCDD
ng Catch, ng (0.05)
ng/dscm Concentration, ng/dscm, as measured (0.0153)
ug/hr Emission Rate, ug/hr 0-61)
Total PeCDD
ng Catch, ng (0.05)
ng/dscm Concentration, ng/dscm, as measured (0.0153)
ug/hr Emission Rate, ug/hr (1.61)
123478 HxCDD
ng Catch, ng (0.06)
ng/dscm Concentration, ng/dscm, as measured (0.0184)
ug/hr Emission Rate, ug/hr (1.94)
123678 HxCDD
ng Catch, ng (0.06)
ng/dscm Concentration, ng/dscm, as measured (0.0184)
ug/hr Emission Rate, ug/hr (1.94)
() Not Detected. Value shown is the detection limit and is included in totals.
{} Estimated Maximum Possible Concentration. EMPC values are included in totals.
E:\r012.002\Monteval.lo\Data\M23monte.xls, sum K4-I-M23-1
-------
Summary of Stack Gas Parameters and Test Results
Chemical Lime Company - Montevallo, Alabama
US EPA Test Method 23 - PCDDs / PCDFs
Kiln No. 4 Baghouse Inlet
Page 3 of 6
RUN NUMBER
RUN DATE
RUN TIME
M23-4-I-1
3/23/98
1400-1808
ng
ng/dscm
ug/hr
ng
ng/dscm
ug/hr
ng
ng/dscm
ug/hr
ng
ng/dscm
pg/hr
ng
ng/dscm
pg/hr
ng
ng/dscm
ug/hr
EMISSIONS DATA -Continued
DIOXiNS - Continued
123789 HxCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, ug/hr
Total HxCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, ug/hr
1234678 HPCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate,
Total HpCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, ug/hr
QCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, ug/hr
Total PCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, ug/hr
(0,06)
(0.0184)
(1 -94)
(0.06)
(0,0184)
(1 ,94)
(0.09)
(0.0276)
(2.90)
(0.09)
(0.0276)
(2,90)
(0.1)
(0.0307)
(3.23)
(0,33)
(0.101)
(10.6)
() Not Detected. Value shown is the detection limit and is included in totals.
{ } Estimated Maximum Possible Concentration. EMPC values are included in totals.
E:\r012.002\Monteval.lo\Data\M23monte.xls, sum K4-I-M23-1
-------
Summary of Stack Gas Parameters and Test Results
Chemical Lime Company - Montevallo, Alabama
US EPA Test Method 23 - PCDDs / PCDFs
Kiln No. 4 Baghouse Inlet
Page 4 of 6
RUN NUMBER
RUN DATE
RUN TIME
M23-4-I-1
3/23/98
1400-1808
EMISSIONS DATA - Continued
FURANS
2378 TCDF
ng Catch, ng {0.007}
ng/dscm Concentration, ng/dscm, as measured {0.00215}
ug/hr Emission Rate, ug/hr {0.226}
Total TCDF
ng Catch, ng 0.09
ng/dscm Concentration, ng/dscm, as measured 0.0276
ug/hr Emission Rate, ug/hr 2.90
12378 PeCDF
ng Catch, ng (0.03)
ng/dscm Concentration, ng/dscm, as measured (0.00920)
ug/hr Emission Rate, ug/hr (0.968)
23478 PeCDF
ng Catch, ng (0.04)
ng/dscm Concentration, ng/dscm, as measured (0.0123)
ug/hr Emission Rate, ug/hr (1.29)
Total PeCDF
ng Catch, ng {0.06}
ng/dscm Concentration, ng/dscm, as measured {0.0184}
ug/hr Emission Rate, ug/hr {1.94}
123478 HxCDF
ng Catch, ng (0.04)
ng/dscm Concentration, ng/dscm, as measured (0.0123)
ug/hr Emission Rate, ug/hr (1.29)
() Not Detected. Value shown is the detection limit and is included in totals.
{} Estimated Maximum Possible Concentration. EMPC values are included in totals.
E:\r012.002\Monteval.lo\Data\M23monte.xls, sum K4-I-M23-1
-------
Summary of Stack Gas Parameters and Test Results
Chemical Lime Company - Montevallo, Alabama
US EPA Test Method 23 - PCDDs / PCDFs
Kiln No. 4 Baghouse Inlet
Page 5 of 6
RUN NUMBER
RUN DATE
RUN TIME
M23-4-I-1
3/23/98
1400-1808
EMISSIONS DATA - Continued
Furans - Continued
123678 HxCDF
ng Catch, ng (0.04)
ng/dscm Concentration, ng/dscm, as measured (0,0123)
pg/hr Emission Rate, ug/hr (1,29)
234678 HxCDF
ng Catch, ng (0.04)
ng/dscm Concentration, ng/dscm, as measured (0.0123)
ug/hr Emission Rate, pg/hr (1,29)
123789 HxCDF
ng Catch, ng (0,05)
ng/dscm Concentration, ng/dscm, as measured (0.0153)
pg/hr Emission Rate, ug/hr (1.61)
Total HxCDF
ng Catch, ng (0.04)
ng/dscm Concentration, ng/dscrn, as measured (0.0123)
ug/hr Emission Rate, ug/hr (1.29)
1234678 HoCDF
ng Catch, ng (0.06)
ng/dscm Concentration, ng/dscm, as measured (0.0184)
ug/hr Emission Rate, pg/hr (1.94)
1234789 HoCDF
ng Catch, ng (0.08)
ng/dscm Concentration, ng/dscm, as measured (0.0245)
pg/hr Emission Rate, pg/hr (2.58)
() Not Detected. Value shown is the detection limit and is included in totals.
{} Estimated Maximum Possible Concentration. EMPC values are included in totals.
E:\r012.002\Monteval.lo\Data\M23monte.xls, sum K4-I-M23-1
-------
Summary of Stack Gas Parameters and Test Results
Chemical Lime Company - Montevallo, Alabama
US EPA Test Method 23 - PCDDs / PCDFs
Kiln No. 4 Baghouse Inlet
Page 6 of 6
RUN NUMBER
RUN DATE
RUN TIME
M23-4-I-1
3/23/98
1400-1808
EMISSIONS DATA - Continued
Furans - Continued
Total HpCDF
ng Catch, ng (0.06)
ng/dscm Concentration, ng/dscm, as measured (0.0184)
ug/hr Emission Rate, ug/hr (1.94)
OCDF
ng Catch, ng (0.1)
ng/dscm Concentration, ng/dscm, as measured (0.0307)
ug/hr Emission Rate, ug/hr (3.23)
Total PCDF
ng Catch, ng (0.35)
ng/dscm Concentration, ng/dscm, as measured (0.107)
ug/hr Emission Rate, ug/hr (11.3)
Total PCDD + PCDF
ng Catch, ng (0.68)
ng/dscm Concentration, ng/dscm, as measured (0.209)
ug/hr Emission Rate, ug/hr (21.9)
() Not Detected. Value shown is the detection limit and is included in totals.
{} Estimated Maximum Possible Concentration. EMPC values are included in totals.
E:\r012.002Wlonteval.lo\DataWI23monte.xls, sum K4-I-M23-1
-------
Summary of Stack Gas Parameters and Test Results
Air Emissions Screening Test
Chemical Lime Company - Montevallo, Alabama
US EPA Test Method 23 - PCDDs / PCDFs
Kiln No. 3 Baghouse & Kiln No. 4 Baghouse Stack
Page 1 of 6
RUN NUMBER
RUN DATE
RUN TIME
M23-0-1
3/23/98
1400-1806
Ap
0
Dr
'p
1/2
MEASURED DATA
j Meter Box Correction Factor 1.000
AH Avg Meter Orifice Pressure, in. H20 1.48
Pbar Barometric Pressure, inches Hg 30.00
Vm Sample Volume, ft3 108.116
Tm Average Meter Temperature, °F 67.8
Pstatie Stack Static Pressure, inches H2O -0,98
Ts Average Stack Temperature, °F 417
V,c Condensate Collected, ml 390,3
CO2 Carbon Dioxide content, % by volume 19.0
O2 Oxygen content, % by volume 10.0
N2 Nitrogen content, % by volume 71.0
Pilot Tube Coefficient 0.84
Average Square Root Ap, (in. H2O)1/2 0.8349
Sample Run Duration, minutes 180
Nozzle Diameter, inches 0.250
CALCULATED DATA
Nozzle Area, ft2 0.00034
Standard Meter Volume, dscf 108.805
Standard Meter Volume, dscm 3,081
Ps Stack Pressure, inches Hg 29.93
B^ Moisture, % by.volume 14.4
VWSM Standard Water Vapor Volume, ft3 18.371
1-BWS Dry Mole Fraction 0.856
Md Molecular Weight (d.b.), Ib/lb-mole 31.44
Ms Molecular Weight (w.b.), !b/lb«mole 29.50
Vs Stack Gas Velocity, ft/s 59.7
A Stack Area, ft2 78.54
Qa Stack Gas Volumetric flow, acfm 281,552
Qs Stack Gas Volumetric flow, dscfm 145,044
Qstcmm) Stack Gas Volumetric flow, dscmm 4,107
I Isokinetic Sampling Ratio, % 96.0
V
m(sW)
E:\r012.002\Monteval.lo\Data\M23monte.xls, sum K3&4-S-M23-1
-------
Summary of Stack Gas Parameters and Test Results
Chemical Lime Company - Montevallo, Alabama
US EPA Test Method 23 - PCDDs / PCDFs
Kiln No. 3 Baghouse & Kiln No. 4 Baghouse Stack
Page 2 of 6
RUN NUMBER
RUN DATE
RUN TIME
M23-0-1
3/23/98
1400-1806
EMISSIONS DATA
DIOXINS:
2378 TCPD
ng Catch, ng (0.01)
ng/dscm Concentration, ng/dscm, as measured (0,00325)
|jg/hr Emission Rate, ug/hr (0.800)
Total TCDD
ng Catch, ng 0.03
ng/dscm Concentration, ng/dscm, as measured 0.00974
|jg/hr Emission Rate, ug/hr 2.40
12378 PeCDD
ng Catch, ng (0.02)
ng/dscm Concentration, ng/dscm, as measured (0.00649)
jjg/hr Emission Rate, ug/hr (1.60)
Total PeCDD
ng Catch, ng (0.02)
ng/dscm Concentration, ng/dscm, as measured (0.00649)
|jg/hr Emission Rate, (jg/hr (1.60)
123478 HxCDD
ng Catch, ng (0.02)
ng/dscm Concentration, ng/dscm, as measured (0.00649)
ug/hr Emission Rate, ug/hr (1.60)
123678 HxCDD
ng Catch, ng (0.02)
ng/dscm Concentration, ng/dscm, as measured (0.00649)
|jg/hr Emission Rate, ug/hr (1.60)
() Not Detected, Value shown is the detection limit and is included in totals.
{} Estimated Maximum Possible Concentration, EMPC values are included in totals.
E:\r012.002\Monteval.lo\Data\M23monte.xls, sum K3&4-S-M23-1
-------
Summary of Stack Gas Parameters and Test Results
Chemical Lime Company - Montevallo, Alabama
US EPA Test Method 23 - PCDDs / PCDFs
Kiln No. 3 Baghouse & Kiln No. 4 Baghouse Stack
Page 3 of 6
RUN NUMBER
RUN DATE
RUN TIME
M23-O-1
3/23/98
1400-1806
ng
ng/dscm
|jg/hr
ng
ng/dscm
ng
ng/dscm
pg/hr
ng
ng/dscm
Mg/hr
ng
ng/dscm
|jg/hr
ng
ng/dscm
ug/hr
EMISSIONS DATA -Continued
DIOXINS - Continued
123789 HxCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, ug/hr
TotalHxCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, Mg/hr
1234678 HpCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
Total HpCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, ug/hr
OCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate,
Total PCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, Mg/hr
(0.02)
(0.00649)
(1 .60)
(0.02)
(0.00649)
(1.60)
(0.03)
(0.00974)
(2.40)
(0.03)
(0.00974)
(2.40)
(0.05)
(0.0162)
(4.00)
(0.15)
(0.0487)
(12.0)
() Not Detected. Value shown is the detection limit and is included in totals.
{} Estimated Maximum Possible Concentration. EMPC values are included in totals.
E:\r012.002\Monteval.lo\Data\M23monte.xls, sum K3&4-S-M23-1
-------
Summary of Stack Gas Parameters and Test Results
Chemical Lime Company - Montevallo, Alabama
US EPA Test Method 23 - PCDDs / PCDFs
Kiln No. 3 Baghouse & Kiln No. 4 Baghouse Stack
Page 4 of 6
ng
ng/dscm
Mg/hr
ng
ng/dscm
Mg/hr
ng
ng/dscm
|jg/hr
ng
ng/dscm
Mg/hr
ng
ng/dscm
Mg/hr
ng
ng/dscm
Mg/hr
RUN NUMBER
RUN DATE
RUN TIME
EMISSIONS DATA - Continued
FURANS
2378 TCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, Mg/hr
Total TCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, ug/hr
12378 PeCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, M9/hr
23478 PeCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, Mg/hr
Total PeCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, Mg/hr
123478 HxCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, ug/hr
M23-O-1
3/23/98
1400-1806
(0.01)
(0.00325)
(0.800)
{0.02}
{0.00649}
{1.60}
(0.01)
(0.00325)
(0.800)
(0.01)
(0.00325)
(0.800)
{0.01}
{0.00325}
{0.800}
(0.01)
(0.00325)
(0.800)
() Not Detected. Value shown is the detection limit and is included in totals.
{} Estimated Maximum Possible Concentration. EMPC values are included in totals.
E:\r012.002\Monteval.lo\Data\M23monte.xls, sum K3&4-S-M23-1
-------
Summary of Stack Gas Parameters and Test Results
Chemical Lime Company - Montevallo, Alabama
US EPA Test Method 23 - PCDDs / PCDFs
Kiln No. 3 Baghouse & Kiln No. 4 Baghouse Stack
Page 5 of 6
RUN NUMBER
RUN DATE
RUN TIME
M23-O-1
3/23/98
1400-1806
EMISSIONS DATA - Continued
Furans - Continued
123678 HxCDF
ng Catch, ng (0.01)
ng/dscm Concentration, ng/dscm, as measured (0.00325)
ug/hr Emission Rate, ug/hr (0.800)
234678 HxCDF
ng Catch, ng (0.01)
ng/dscm Concentration, ng/dscm, as measured (0.00325)
ug/hr Emission Rate, ug/hr (0.800)
123789 HxCDF
ng Catch, ng (0.01)
ng/dscm Concentration, ng/dscm, as measured (0.00325)
ug/hr Emission Rate, ug/hr (0.800)
TotalHxCDF
ng Catch, ng (0.01)
ng/dscm Concentration, ng/dscm, as measured (0.00325)
ug/hr Emission Rate, ug/hr (0.800)
1234678 HpCDF
ng Catch, ng (0.02)
ng/dscm Concentration, ng/dscm, as measured (0.00649)
ug/hr Emission Rate, ug/hr (1.60)
1234789 HpCDF
ng Catch, ng (0.02)
ng/dscm Concentration, ng/dscm, as measured (0.00649)
ug/hr Emission Rate, ug/hr (1.60)
() Not Detected. Value shown is the detection limit and is included in totals.
{ } Estimated Maximum Possible Concentration. EMPC values are included in totals.
E:\r012.002\Monteval.to\Data\M23monte.xls, sum K3&4-S-M23-1
-------
Summary of Stack Gas Parameters and Test Results
Chemical Lime Company - Montevallo, Alabama
US EPA Test Method 23 - PCDDs / PCDFs
Kiln No. 3 Baghouse & Kiln No. 4 Baghouse Stack
Page 6 of 6
RUN NUMBER
RUN DATE
RUN TIME
M23-O-1
3/23/98
1400-1806
EMISSIONS DATA - Continued
Furans - Continued
Total HpCDF
ng Catch, ng (0,02)
ng/dscm Concentration, ng/dscm, as measured (0.00649)
ug/hr Emission Rate, jjg/hr (1.60)
OCDF
ng Catch, ng (0.04)
ng/dscm Concentration, ng/dscm, as measured (0.0130)
ug/hr Emission Rate, ug/hr (3.20)
Total PCDF
ng Catch, ng (0.10)
ng/dscm Concentration, ng/dscm, as measured (0.0325)
ug/hr Emission Rate, ug/hr (8.00)
Total PCDD * PCDF
ng Catch, ng (0.25)
ng/dscm Concentration, ng/dscm, as measured (0.0811)
ug/hr Emission Rate, ug/hr (20.0)
(} Not Detected. Value shown is the detection limit and is included in totals.
{} Estimated Maximum Possible Concentration. EMPC values are included in totals.
E:\r012.002\Monteval.loVData\M23monte.xls, sum K3&4-S-M23-1
-------
Summary of Stack Gas Parameters and Test Results
Air Emissions Screening Test
Chemical Lime Company - Montevallo, Alabama
US EPA Test Method 23 - PCDDs / PCDFs
Kiln No. 3 Baghouse & Kiln No. 4 Baghouse Stack
Page 1 of 6
RUN NUMBER
RUN DATE
RUN TIME
M23-O-2
3/24/98
1332-1709
Y
AH
Pbar
"static
Ts
V,c
CO2
02
N2
Ap
0
Dn
rp
1/2
Vm(std)
PS
BWS
Vwstd
1-BWS
Md
Ms
Vs
A
Qa
Qs
**s
\1/2
MEASURED DATA
Meter Box Correction Factor
Avg Meter Orifice Pressure, in. H2O
Barometric Pressure, inches Hg
Sample Volume, ft3
Average Meter Temperature, °F
Stack Static Pressure, inches H2O
Average Stack Temperature, °F
Condensate Collected, ml
Carbon Dioxide content, % by volume
Oxygen content, % by volume
Nitrogen content, % by volume
Pilot Tube Coefficient
Average Square Root Ap, (in. H2O)1
Sample Run Duration, minutes
Nozzle Diameter, inches
CALCULATED DATA
Nozzle Area, ft2
Standard Meter Volume, dscf
Standard Meter Volume, dscm
Stack Pressure, inches Hg
Moisture, % by volume
Standard Water Vapor Volume, ft3
Dry Mole Fraction
Molecular Weight (d.b.), Ib/lb-mole
Molecular Weight (w.b.), Ib/lb-mole
Stack Gas Velocity, ft/s
Stack Area, ft2
Stack Gas Volumetric flow, acfm
Stack Gas Volumetric flow, dscfm
Stack Gas Volumetric flow, dscmm
Isokinetic Sampling Ratio, %
1.000
1.58
30.00
115.075
79.7
-6.20
416
406.0
18.6
10.0
71.4
0.84
0.8163
180
0.250
0.00034
113.279
3.208
29.54
14.4
19.110
0.856
31.38
29.45
58.8
78.54
277,133
141,129
3,996
102.8
E:\r012.002\Monteval.lo\Data\M23monte.xls, sum K3&4-S-M23-2
-------
Summary of Stack Gas Parameters and Test Results
Chemical Lime Company - Montevallo, Alabama
US EPA Test Method 23 - PCDDs / PCDFs
Kiln No. 3 Baghouse & Kiln No. 4 Baghouse Stack
Page 2 of 6
RUN NUMBER
RUN DATE
RUN TIME
M23-O-2
3/24/98
1332-1709
EMISSIONS DATA
DIOXINS:
2378 TCDD
ng Catch, ng (0.006)
ng/dscm Concentration, ng/dscm, as measured (0.00187)
ljg/hr Emission Rate, ug/hr (0.449)
Total TCDD
ng Catch, ng 0.08
ng/dscm Concentration, ng/dscm, as measured 0.0249
ug/hr Emission Rate, ug/hr 5.98
12378 PeCDD
ng Catch, ng (0.009)
ng/dscm Concentration, ng/dscm, as measured (0.00281)
ug/hr Emission Rate, ug/hr (0.673)
Total PeCDD
ng Catch, ng 0.03
ng/dscm Concentration, ng/dscm, as measured 0.00935
ug/hr Emission Rate, ug/hr 2.24
123478 HxCDD
ng Catch, ng (0.01)
ng/dscm Concentration, ng/dscm, as measured (0.00312)
ug/hr Emission Rate, ug/hr (0.748)
123678 HxCDD
ng Catch, ng (0.01)
ng/dscm Concentration, ng/dscm, as measured (0.00312)
ug/hr Emission Rate, ug/hr (0.748)
() Not Detected. Value shown is the detection limit and is included in totals.
{} Estimated Maximum Possible Concentration. EMPC values are included in totals.
E:\r012.002\Monteval.lo\Data\M23monte.xls, sum K3&4-S-M23-2
-------
Summary of Stack Gas Parameters and Test Results
Chemical Lime Company - Montevallo, Alabama
US EPA Test Method 23 - PCDDs / PCDFs
Kiln No. 3 Baghouse & Kiln No. 4 Baghouse Stack
Page 3 of 6
RUN NUMBER
RUN DATE
RUN TIME
M23-O-2
3/24/98
1332-1709
EMISSIONS DATA -Continued
DIOXINS - Continued
123789 HxCDD
ng Catch, ng (0.01)
ng/dscm Concentration, ng/dscm, as measured (0.00312)
[jg/hr Emission Rate, ug/hr (0.748)
TotalHxCDD
ng Catch, ng (0.01)
ng/dscm Concentration, ng/dscm, as measured (0.00312)
ug/hr Emission Rate, ug/hr (0.748)
1234678 HpCDD
ng Catch, ng 0.01
ng/dscm Concentration, ng/dscm, as measured 0.00312
(jg/hr Emission Rate, ug/hr 0.748
Total HoCDD
ng Catch, ng 0.01
ng/dscm Concentration, ng/dscm, as measured 0.00312
ug/hr Emission Rate, ug/hr 0.748
OCDD
ng Catch, ng {0.03}
ng/dscm Concentration, ng/dscm, as measured {0.00935}
ug/hr Emission Rate, ug/hr {2.24}
Total PCDD
ng Catch, ng (0.16)
ng/dscm Concentration, ng/dscm, as measured (0.0499)
ug/hr Emission Rate, ug/hr (12.0)
() Not Detected. Value shown is the detection limit and is included in totals.
{} Estimated Maximum Possible Concentration. EMPC values are included in totals.
E:\r012.002\Monteval.lo\Data\M23monte.xls, sum K3&4-S-M23-2
-------
Summary of Stack Gas Parameters and Test Results
Chemical Lime Company - Montevallo, Alabama
US EPA Test Method 23 - PCDDs / PCDFs
Kiln No. 3 Baghouse & Kiln No. 4 Baghouse Stack
Page 4 of 6
ng
ng/dscm
ug/hr
ng
ng/dscm
ug/hr
ng
ng/dscm
ug/hr
ng
ng/dscm
ug/hr
ng
ng/dscm
ug/hr
ng
ng/dscm
ug/hr
RUN NUMBER
RUN DATE
RUN TIME
EMISSIONS DATA - Continued
FURANS
2378 TCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, ug/hr
Total TCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, ug/hr
12378 PeCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, ug/hr
23478 PeCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, ug/hr
Total PeCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, ug/hr
123478 HxCDF
Catch, ng
Concentration, ng/dscm, as'measured
Emission Rate, ug/hr
M23-O-2
3/24/98
1332-1709
0.01
0.00312
0.748
0.25
0.0779
18.7
(0.006)
(0.00187)
(0.449)
(0.006)
(0.00187)
(0.449)
0.02
0.00624
1.50
(0.008)
(0.00249)
(0.598)
() Not Detected. Value shown is the detection limit and is included in totals.
{} Estimated Maximum Possible Concentration. EMPC values are included in totals.
E:\r012.002\Monteval.lo\Data\M23monte.xls, sum K3&4-S-M23-2
-------
Summary of Stack Gas Parameters and Test Results
Chemical Lime Company - Montevallo, Alabama
US EPA Test Method 23 - PCDDs / PCDFs
Kiln No. 3 Baghouse & Kiln No. 4 Baghouse Stack
Page 5 of 6
RUN NUMBER
RUN DATE
RUN TIME
M23-0-2
3/24/98
1332-1709
EMISSIONS DATA - Continued
Furans - Continued
123678 HxCDF
ng Catch, ng (0.007)
ng/dscm Concentration, ng/dscm, as measured (0.00218)
ug/hr Emission Rate, ug/hr (0.523)
234678 HxCDF
ng Catch, ng (0.009)
ng/dscm Concentration, ng/dscm, as measured (0,00281)
ug/hr Emission Rate, ug/hr (0.673)
123789 HxCDF
ng Catch, ng (0.01)
ng/dscm Concentration, ng/dscm, as measured (0.00312)
ug/hr Emission Rate, ug/hr (0.75)
Total HxCDF
ng Catch, ng {0.007}
ng/dscm Concentration, ng/dscm, as measured {0.00218}
ug/hr Emission Rate, ug/hr {0.523}
1234678 HpCDF
ng Catch, ng {0,01}
ng/dscm Concentration, ng/dscm, as measured {0.00312}
ug/hr Emission Rate, ug/hr {0.748}
1234789 HoCDF
ng Catch, ng (0.02)
ng/dscm Concentration, ng/dscm, as measured (0.00624)
ug/hr Emission Rate, ug/hr (1.50)
() Not Detected. Value shown is the detection limit and is included in totals.
{ } Estimated Maximum Possible Concentration. EMPC values are Included in totals.
E:\r012.002\MontevalJo\Data\M23monte.xls, sum K3&4-S-M23-2
-------
Summary of Stack Gas Parameters and Test Results
Chemical Lime Company - Montevallo, Alabama
US EPA Test Method 23 - PCDDs / PCDFs
Kiln No. 3 Baghouse & Kiln No. 4 Baghouse Stack
Page 6 of 6
RUN NUMBER
RUN DATE
RUN TIME
M23-O-2
3/24/98
1332-1709
EMISSIONS DATA - Continued
Furans - Continued
Total HpCDF
ng Catch, ng {0.01}
ng/dscm Concentration, ng/dscm, as measured {0.00312}
jjg/hr Emission Rate, (jg/hr {0.748}
OCDF
ng Catch, ng (0.03)
ng/dscm Concentration, ng/dscm, as measured (0.00935)
ug/hr Emission Rate, ug/hr (2.24)
Total PCPF
ng Catch, ng (0.317)
ng/dscm Concentration, ng/dscm, as measured (0.0988)
jjg/hr Emission Rate, ug/hr (23.7)
Total PCDD + PCDF
ng Catch, ng (0.477)
ng/dscm Concentration, ng/dscm, as measured (0.149)
[jg/hr Emission Rate, ug/hr (35.7)
() Not Detected. Value shown is the detection limit and is included in totals.
{ } Estimated Maximum Possible Concentration. EMPC values are included in totals.
E:\r012.002\Monteval.lo\Data\M23monte.xls, sum K3&4-S-M23-2
-------
Summary of Stack Gas Parameters and Test Results
Air Emissions Screening
Test
Chemical Lime Company - Montevallo, Alabama
US EPA Test Methods 2 - Volumetric Air Flow Rates
Astatic
Pbar
cp
Ap1/2
Ts
CO2
02
N2
Dia
PS
BWS
1-BWS
Md
Ms
vs
A
Qa
Qs
Qs
Kiln No. 3 Baghouse and Kiln No. 4
Page 1 of 1
RUN NUMBER
RUN DATE
RUN TIME
MEASURED DATA
Stack Static Pressure, inches H2O
Barometric Pressure, inches Hg
Pitot Tube Coefficient
Average Square Root Ap, (in. H2O)1/2
Average Stack Temperature, °F
Carbon Dioxide content, % by volume
Oxygen content, % by volume
Nitrogen content, % by volume
Estimated Moisture, %
Diameter or Dimensions, inches
CALCULATED DATA
Stack Pressure, inches Hg
Moisture, % by volume
Dry Mole Fraction
Molecular Weight (d,b,), lb/lb*mole
Molecular Weight (w.b.), Ib/lb»mole
Stack Gas Velocity, ft/s
Stack Area, ft2
Stack Gas Volumetric flow, acfm
Stack Gas Volumetric flow, dscfm
Stack Gas Volumetric flow, dscmm
Baghouse Inlets
Kiln No. 3
Baghouse Inlet
M2-3-I-1
3/23/98
1440-1455
-3.4
30.00
0.84
0.6841
933.7
26.6
5.3
68.1
7.80
98.00
29.75
7.80
0.922
32.47
31.34
60.1
52.38
188,771
65,537
1,856
Kiln No. 4
Baghouse Inlet
M2-4-I-2
3/24/98
1430-1450
-2.6
30.00
0.84
0.6426
884.8
20.1
8.1
71.8
4.60
98.00
29.81
4.60
0.954
31.54
30.92
55.7
52.38
175,191
65,354
1,851
E:\r012.002\Montevai.Io\Data\M2&4mont,xIs, Sum3&4ln!ets
-------
p
r static
Pbar
Cp
.1/2
Ap
Ts
CO2
02
N2
Dia
PS
BWS
1-Bws
Md
Ms
Vs
A
Qa
Qs
Qs
Summary of Stack Gas Parameters and Test Results
Air Emissions Screening Test
Chemical Lime Company - Montevallo, Alabama
US EPA Test Methods 2 - Volumetric Air Flow Rates
Kiln No. 3 Baghouse & Kiln No. 4 Baghouse Stack
Page 1 of 1
RUN NUMBER
RUN DATE
RUN TIME
MEASURED DATA
Stack Static Pressure, inches H2O
Barometric Pressure, inches Hg
Pitot Tube Coefficient
Average Square Root Ap, (in. H2O)1/2
Average Stack Temperature, °F
Carbon Dioxide content, % by volume
Oxygen content, % by volume
Nitrogen content, % by volume
Estimated Moisture, %
Diameter or Dimensions, inches
CALCULATED DATA
Stack Pressure, inches Hg
Moisture, % by volume
Dry Mole Fraction
Molecular Weight (d.b.), lb/lb»mole
Molecular Weight (w.b.), Ib/lb-mole
Stack Gas Velocity, ft/s
Stack Area, ft2
Stack Gas Volumetric flow, acfm
Stack Gas Volumetric flow, dscfm
Stack Gas Volumetric flow, dscmm
M2-O-3
3/25/98
0910-0915
-0.65
30.00
0.84
0.8074
409.0
17.7
10.0
72.3
14.0
120.00
29.95
14.0
0.860
31.23
29.38
57.6
78.54
271,519
141,973
4,020
E:\r012.002\Monteval.lo\Data\M2&4mont.xls, Sum3&4Stk
-------
Summary of Stack Gas Parameters and Test Results
Air Emissions Screening Test
Chemical Lime Company - Montevallo, Alabama
US EPA Test Methods 2 - Volumetric Air Flow Rates
Pstatic
Pbar
cp
AP1/2
Ts
C02
02
N2
Dim
PS
Bws
1-BWS
Md
Ms
Vs
A
Qa
Qs
Qs
CO2 Bubbler Slipstream Off Kiln No. 3 & Kiln
Page 1 of 1
RUN NUMBER
RUN DATE
RUN TIME
MEASURED DATA
Stack Static Pressure, inches H2O
Barometric Pressure, inches Hg
Pitot Tube Coefficient
Average Square Root Ap, (in. H2O)1/2
Average Stack Temperature, °F
Carbon Dioxide content, % by volume
Oxygen content, % by volume
Nitrogen content, % by volume
Estimated Moisture, %
Diameter or Dimensions, inches
CALCULATED DATA
Stack Pressure, inches Hg
Moisture, % by volume
Dry Mole Fraction
Molecular Weight (d.b.), Ib/lb-mole
Molecular Weight (w.b.), Ib/lb-mole
Stack Gas Velocity, ft/s
Stack Area, ft2
Stack Gas Volumetric flow, acfm
Stack Gas Volumetric flow, dscfm
Stack Gas Volumetric flow, dscmm
No. 4 Stack
M2-CBS-1
3/23/98
1440-1455
-1.5
30.00
0.84
0.4868
302.7
19.0
10.0
71.0
14.40
29.50
29.89
14.40
0.856
31.44
29.50
32.5
4.75
9,258
5,479
155
M2-CBS-2
3/24/98
1430-1450
-1.5
30.00
0.84
0.4285
315.4
18.6
10.0
71.4
14.40
29.50
29.89
14.40
0.856
31.38
29.45
28.9
4.75
8,226
4,788
136
E:\r012.002\Monteval.lo\Data\M2&4mont.xls,SumCO2Bub
-------
Example Calculations
Chemical Lime Company- Montevallo, Alabama
US EPA Method 23-PCDD/PCDF
(Using Data from Run M23-O-1)
Note: Discrepancies may exist between the computer generated reported results, which use
more significant figures, and the values manually calculated from the displayed values.
1. Volume of dry gas sampled corrected to standard conditions of 68 °F, 29.92 in. Hg, ft3.
Vm(std) = 17-64VmY
bar
AH
13.6
460 + t
Vm(std) = (17.64)(108.116)(1.000)
30.0 +
1.475
13.6
( 460 + 67.75 J
Vm(std) = 108.805 dscf
2. Volume of dry gas sampled corrected to standard conditions of 68 °F, 29.92 in. Hg, m3.
Vm(std)m3 - Vm(std)(0.028317)
= (108.805)(0.028317)
Vm(std)m3 = 3.081 dscm
3. Volume of water vapor at standard conditions, ft3.
Vw(std) = 0.04707V1C
vw(std) - (0.04707)(390.3)
Vw(std) = 18-371 scf
-------
4. Moisture content in stack gas.
v
n ._ w(std)
T_ __
m(std) v
B = 18.371
ws 108.805 + 18.371
Bws = 0.1445
5. Dry molecular weight of stack gas, Ib/lb-mol.
Md = 0.440 (%CO2) + 0.320 (%O2) + 0.280 (%N2+%CO)
M. = 0.440(19.0) + 0.320(10.0) + 0.280(71 +0)
Md =31.44 Ib/lbmol
6. Molecular weight of stack gas, Ib/lb-mol.
Ms = Md(l -Bws) + 18(BWS)
Ms = 31.44(1-0.1445) + 18(0.1445)
Mq = 31.44(0.8555) + 18(0.1445)
Ms = 26.89692 + 2.601
Ms = 29.50 Ib/lbmol
-------
7. Absolute stack gas pressure, in. Hg.
p
p _ p + static
s " bar 13.6
P = 30.0 +
13.6
P = 29.93 inches Hg
8. Stack velocity at stack conditions, fps.
V = 85.49 C
avg
\
Ts + 460
MSPS
Vs = (85.49) (0.84) (0.8349)
(416.75+460)
(29.50) (29.93)
Vs = 59.75 fps
9. Isokinetic Variation.
0- (6) W P -B»)
o/0i = (108.805) (416.75+460) (17.32)
(59.75) (0.250)2 (180) (29.93) (1-0.1445)
= 96.0
-------
10. Stack gas volumetric flow rate at stack conditions, acfm
= (60) (A) (Vs) '
Qs = (60) (78.54) (59.75)
Q, = 281,552 acfm
11. Dry stack gas volumetric flow rate at standard conditions, dscfm.
Qscstd) = 17-64 Qs £ (1 -Bj
[TO QQ )
y'y3 (1-0.1445)
417+460 v ;
Qs(std) = 145'044
12. Dry stack gas volumetric flow rate at standard conditions, dscmm.
Qs(std)m3/min = Qs(std) °'028317
QS(std,m'/min = (145,044) (0.028317)
Qs(std)m'/min = 4'107
-------
13. Pollutant (2378 TCDD) concentration, ng/dscm.
ng/dscm = —
*m(std)m3
ng/dscm = —-
3.081
ng/dscm = 0.00325 ng/dscm
14. Pollutant (2378 TCDD) concentration, ng/dscm adjusted to 7 percent oxygen.
ng/dscm@7%O2 = (ng/dscm)
ng/dscm@7%O2 = (0.00325)
(20.9 - %02)
13.9
(20.9 - 10.0)
ng/dscm@7%O2 = 0.00414 ng/dscm@7%O2
15. Pollutant (23 78 TCDD) emission rate, ug/hr.
__ (60) (ng) (Qs(5td))
do3) (vm(std))
= (60) (0.01) (145.044)
(103) (108.805)
= 0.800
-------
APPENDIX D
CALIBRATION DATA
-------
-------
1of2
O PACIFIC ENVIRONMENTAL, SERVICES, INC.
Centra! Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919)941-0333 FAX: (919) 941-0234
9/1/97
Initial Dry Gas Meter Calibration Form (English Units)
Date:
Ptar, in Hg
Calibrator: Tom McDonald
Meter Box No.: MB-10
30.16
Reference Meter Correction Factor: 1.0049 (8/28/96)
AH = 0.5
Trial
1
2
3
Trial
Duration
(min)
19
19
19
Dry Gas Meter MB-10
Gas Volume
Initial
(ft3)
994.409
1001.982
1009.513
Final
(ft3)
1001.982
1009.513
1017.050
Net
(ft3)
7.573
7.531
7.537
Meter Temperatures
Initial, Inlet
CF)
74
77
80
Final, Inlet
CF)
78
80
81
Avg. Inlet
CF)
76
78.5
80.5
Initial, Outlet
CF)
73
75
77
inal, Outle
CF)
75
77
78
Avg. Outlet
CF)
74
76
77.5
Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
600.523
608.185
615.801
Final
(ft3)
608.185
615.801
623.430
Net
(ft3)
7.662
7.616
7.629
Meter Temperature
Initial
(°F)
72
74
76
Final
(°F)
74
76
77
Avg.
(°F)
73
75
76.5
Meter Box
Correction
Factor
r
1.019
1.019
1.021
Reference
Orifice Press
AHe
(in. H2O)
1.71
1.74
1.74
AH = 0,75
Trial
1
2
3
Trial
Duration
(min)
15
15
15
Dry Gas Meter MB-10
Gas Volume
Initial
(ft3)
17.220
24.350
31.563
Final
(ft3)
24.350
31.563
38.780
Net
(ft3)
7.130
7.213
7.217
Meter Temperatures
Initial, Inlet
(°F)
80
82
82
Final, Inlet
(°F)
82
83
83
Avg. Inlet
CF)
81
82.5
82.5
Initial, Outlet
<°F)
78
79
79
inal, Outle
CF)
79
79
81
Avg. Outlet
CF)
78.5
79
80
Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
623.622
630.833
638.141
Final
(ft3)
630.833
638.141
645.425
Net
(ft3)
7.211
7.308
7.284
Meter Temperature
Initial
CF)
77
78
78
Final
CF)
77
78
78.5
Avg.
CF)
77
78
78.25
Meter Box
Correction
Factor
T
1.020
1.021
1.018
Reference
Orifice Press
AH@
(in. H2O)
1.82
1.77
1.79
AH= 1.0
Trial
1
2
3
Trial
Duration
(min)
10
10
10
Dry Gas Meter MB-10
Gas Volume
Initial
(ft3)
38.946
44.490
50.050
Final
(ft3)
44.490
50.050
55.585
Net
(ft3)
5.544
5.560
5.535
Meter Temperatures
Initial, Inlet
CF)
81
83
84
Final, Inlet
CF)
83
84
84
Avg. Inlet
CF)
82
83.5
84
Initial, Outlet
CF)
80
80
80
inal, Outle
CF)
80
80
80
Avg. Outlet
CF)
80
80
80
Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
645.614
651.220
656.829
Final
(ft3)
651.22
656.829
662.435
Net
(ft3)
5.606
5.609
5.606
Meter Temperature
Initial
CF)
78
78
78
Final
CF)
78
78
78
Avg.
CF)
78
78
78
Meter Box
Correction
Factor
T
1.019
1.018
1.023
Reference
Orifice Press
AH@
(in. H2O)
1.79
1.78
1.78
10 09017.xls
Printed: 6/10/98
-------
2 of 2
/ n
O PACIFIC ENVIRONMENTAL, SERVICES.
INC,
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919) 941-0333 FAX: (919) 941-0234
AH = 2.0
Trial
1
2
3
Trial
Duration
(min)
10
10
10
Dry Gas Meter MB-10
Gas Volume
Initial
(ft3)
55.868
63.519
71.182
Final
(ft3)
63.519
71.182
78.845
Net
(ft3)
7.651
7.663
7.663
Meter Temperatures
Initial, Inlet
(°F)
84
86
86
Final, Inlet
(T)
86
86
87
Avg. Inlet
CF)
85
86
86.5
Initial, Outlet
(T)
81
81
81
inal, Outle
(°F)
81
81
81
Avg. Outlet
CF)
81
81
81
Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
662.729
670.472
678.244
Final
(ft3)
670.472
678.244
686.010
Net
(ft3)
7.743
7.772
7.766
Meter Temperature
Initial
CF)
78
78
78
Final
(°F)
78
78
78
Avg.
(T)
78
78
78
Meter Box
Correction
Factor
r
1.021
1.025
1.024
Reference
Orifice Press
AHe
(in. H2O)
1.87
1.86
1.86
AH = 4.0
Trial
1
2
3
Trial
Duration
(min)
8
8
8
Dry Gas Meter MB-10
Gas Volume
Initial
(ft3)
79.058
86.620
94.185
Final
(ft3)
86.620
94.185
101.754
Net
(ft3)
7.562
7.565
7.569
Meter Temperatures
Initial, Inlet
(°F)
85
87
89
Final, Inlet
CF)
88 •
89
89
Avg. Inlet
CF)
86.5
88
89
Initial, Outlet
CF)
81
82
82
inal, Outle
CF)
82
82
82
Avg. Outlet
CO
81.5
82
82
'Trial
1
2
3
Reference Meter
Gas Volume
Initial
P3)
686.208
693.895
701.558
Final
(ft3)
693.895
701.558
709.244
Net
(ft3)
7.687
7.663
7.686
Meter Temperature
Initial
CF)
78
78
78
Final
CF)
78
78
78
Avg.
CF)
78
78
78
Meter Box
Correction
Factor
T
1.023
1.021
1.025
Reference
Orifice Press
AH@
(in. H2O)
2.44
2.45
2.43
Calibration Results
AH ,
0.50
0.75
1.0
2.0
4.0
r A^@
1.020 1.73
1.020 1
79
1.020 1.78
1.023 1
1.023 2
86
44
Dry Gas Meter MB-10 on 09/01/97
Meter Box Calibration Factor
Meter Box Reference Orifice Pressure
1.021
1.92
10 09017.xls
Printed: 6/10/98
-------
OPAC
PACIRC ENVIRONMENTAL SERVICES, INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919) 941-0333 FAX: (919) 941-0234
Posttest Dry Gas Meter Calibration Form (English Units)
Pretest Calibration Factor
System Vacuum Setting, (in Hg)
Reference Meter Correction Factor
Date: 5/2/98 Pbar, in Hg
1.021
16
1.0077
29.94 Calibrator:
D. Holzschuh
Meter Box No.
MB-10
AH= 1.41
Trial
1
2
3
Duration
(min)
15
8
8
Dry Gas Meter
Initial
(ft3)
902.1
912.624
917.493
Final
(ft3)
912.624
917.993
923.154
Net
(ft3)
10.524
5.369
5.661
Initial, Inlet
(°F)
75
76
76
Final, Inle
(°F)
76
76
76
Avg. Inlet
(°F)
75.5
76
76
Initial, Outlet
(°F)
74
74
74
Final, Outlet
(°F)
74
74
74
Avg. Outlet
(°F)
74
74
74
Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
320.645
331.244
336.545
Final
(ft3)
331.244
336.545
341.865
Net
(ft3)
10.601
5.301
5.32
Meter Temperature
Initial
(°F)
75
72
73
Final
CF)
75
73
73
Avg.
(°F)
75
72.5
73
Meter Box
Correction
Factor
y
1.011
0.996
0.947
Reference
Orifice Press
AH@
(in. H2O)
1.59
1.79
1.78
10 09017.xls
PostTest050298
6/10/98
-------
1 of 2
Q PACIFIC ENVIRONMENTAL SERVICES. INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
.(919) 941-0333 FAX: (919) 941-0234
Date: 10/13/97
Pbar, '" Hg
29.86
Calibrator: MMD
Meter Box No.: RMB-15
Reference Meter Correction Factor: 1.0077 (10/5/97)
AH = 0.5
Trial
1
2
3
Trial
Duration
(min)
15
13
12
Dry Gas Meter RMB-15
Gas Volume
Initial
(ft3)
48.833
54.722
59.821
Final
(ft3)
54.722
59.821
64.544
Net
(ft3)
5.889
5.099
4.723
Meter Temperatures
Initial, Inlet
(°F)
73
78
80
Final, Inlet
(°F)
77
80
83
Avg. Inlet
(T)
75
79
81.5
Initial, Outlet
(°F)
72
74
76
inal, Outle
(T)
75
75
77
Avg. Outlet
(T)
73.5
74.5
76.5
Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
34.044
39.829
44.843
Final
(ft3)
39.829
44.843
49.463
Net
(ft3)
5.785
5.014
4.620
Meter Temperature
Initial
(T)
70
71
71
Final
(°F)
70
70
71
Avg.
fF)
70
70.5
71
Meter Box
Correction
Factor
y
0.997
1.001
0.999
Reference
Orifice Press
AH®
(in. H2O)
1.86
1.86
1.86
M = 0.75
Trial
1
2
3
Trial
Duration
(min)
8
21
13
Dry Gas Meter RMB-15
Gas Volume
Initial
(ft3)
69.524
73.327
83.322
Final
(ft3)
73.327
83.322
89.571
Net
(ft3)
3.803
9.995
6.249
Meter Temperatures
Initial, Inlet
(°F)
74
77
78
Final, Inlet
(°F)
74
83
82
Avg. Inlet
(T)
74
80
80
Initial, Outlet
(°F)
77
76
78
inal, Outie
(°F)
75
77
74
Avg. Outlet
(°F)
76
76.5
76
Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
54.365
58.108
67.912
Final
(ft3)
58.108
67.912
74.036
Net
(ft3)
3.743
9.804
6.124
Meter Temperature
Initial
(°F)
72
72
73
Final
(°F)
72
73
73
Avg.
(°F)
72
72.5
73
Meter Box
Correction
Factor
y
0.996
0.997
0.995
Reference
Orifice Press
AH@
(in. H2O)
1.91
1.91
1.88
AH = 1 .0
Trial
1
2
3
Trial
Duration
(min)
19
8
16
Dry Gas Meter RMB-15
Gas Volume
Initial
(ft3)
89.777
100.214
104.614
Final
(ft3)
100.214
104.614
113.404
Net
(ft3)
10.437
4.400
8.790
Meter Temperatures
Initial, Inlet
(°F)
82
85
85
Final, Inlet
<°F)
86
87
88
Avg. Inlet
fF)
84
86
86.5
Initial, Outlet
<8F)
79
81
82
inal, Outle
(°F)
80
81
83
Avg. Outlet
(•F)
79.5
81
82.5
Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
74.254
84.440
88.743
Finai
(ft3)
84.44
88.743
97.302
Net
(ft3)
10.186
4.303
8.559
Meter Temperature
Initial
(T)
73
73
73
Final
(°F)
73
73
73
Avg.
(°F)
73
73
73
Meter Box
Correction
Factor
y
0.997
1.002
1.000
Reference
Orifice Press
AH@
(in. H2O)
1.92
1.91
1.92
15 10137.xls
Printed: 6/10/98
-------
2 of 2
O PACIFIC ENVIRONMENTAL SERVICES, INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919) 941-0333 FAX: (919) 941-0234
AH = 2.0
Trial
1
2
3
Trial
Duration
(min)
9
7
7
DryGasMeterRMB-15
Gas Volume
Initial
(ft3)
13.863
20.884
26.372
Final
(ft3)
20.884
26.372
31.871
Net
(ft3)
7.021
5.488
5.499
Meter Temperatures
Initial, Inlet
CF)
87
90
90
Final, Inlet
(°F)
91
92
93
Avg. Inlet
(•F)
89
91
91.5
Initial, Outlet
CF)
83
84
84
inal, Outle
<°F)
83
84
84
Avg. Outlet
<°F)
83
84
84
Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
97.749
104.591
109.929
Final
(ft3)
104.591
109.929
115.281
Net
(ft3)
6.842
5.338
5.352
Meter Temperature
Initial
CF)
73
73
73
Final
(°F)
73
73
74
Avg.
(°F)
73
73
73.5
Meter Box
Correction
Factor
Y
1.001
1.002
1.002
Reference
Orifice Press
AHe
(in. H2O)
1.90
1.89
1.88
AH = 4.0
Trial
1
2
Trial
Duration
(min)
6.5
15.5
DryGasMeterRMB-15
Gas Volume
Initial
(ft3)
32.371
39.484
Final
(ft3)
39.484
56,484
Net
(ft3)
7.113
17.000
Meter Temperatures
Initial, Inlet
<°F)
92
93
Final, Inlet
<°F)
94
97
Avg. Inlet
CF)
93
95
Initial, Outlet
CF)
85
87
inal, Outle
CF)
85
87
Avg. Outlet
CF)
85
87
Trial
1
2
Reference Meter
Gas Volume
Initial
(ft3)
15.775
22.732
Final
(ft3)
22.732
39.287
Net
(ft3)
6.957
16.555
Meter Temperature
Initial
CF)
73
73
Final
CF)
74
73
Avg.
CF)
73.5
73
Meter Box
Correction
Factor
r
1,004
1.005
Reference
Orifice Press
AHa
(in. H2O)
1.92
1.92
Calibration Results
A
Dry Gas Meter RMB-15 on 10/13/97
0.50 0.999 1.86
0.75 0.996 1.90
1.0 1.000 1.92
2.0 1.002 1.89
4.0 1.004 1.92 <— Two Trial Average
Meter Box Calibration Factor
Meter Box Reference Orifice Pressure
1.000
1.90
15 10137.xls
Printed: 6/10/98
-------
O PACIFIC ENVIRONMENTAL SERVICES, INC.
Posttest Dry Gas Meter Calibration Form (English Units)
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919) 941-0333 FAX: (919) 941-0234
Pretest Calibration Factor
System Vacuum Setting, (in Hg)
Reference Meter Correction Factor
Date: 5/2/98 Pbar, in Hg
1.000
12
1.0077
29.94 Calibrator:
D. Holzschuh
Meter Box No.
MB-15
AH= 1.41
Trial
1
2
3
Duration
(min)
8
8
11
Dry Gas Meter
Initial
(ft3)
776.09
781.709
787.439
Final
(ft3)
781.709
787.439
795.344
Net
(ft3)
5.619
5.730
7.905
Initial, Inlet
(•F)
71
73
73
Final, Inle
(T)
73
73
73
Avg. Inlet
(°F)
72
73
73
Initial, Outlet
(°F)
69
70
71
Final, Outlet
(°F)
70
71
71
Avg. Outlet
(°F)
69.5
70.5
71
Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
343.209
348.9
354.597
Final
(ft3)
348.9
354.597
362.414
Net
(ft3)
5.691
5.697
7.817
Meter Temperature
Initial
(°F)
72
72
72
Final
(°F)
72
72
72
Avg.
(°F)
72
72
72
Meter Box
Correction
Factor
y
1.015
0.998
0.993
Reference
Orifice Press
AH@
(in. H2O)
1.56
1.56
1.56
15 10137.xls
PostTest50298
6/10/98
-------
REFERENCE METER CALIBRATION
ENGLISH REFERENCE METER UNITS
Barometric Pressure 29.82
Meter Yw 1.00000
K < deg R/ Inches Hg) 17.64
Dry Gas Meter
Time Pressure Meter Readings
(rain) (in. H20)
20.50
s.oo
11.00
8.50
27.50
26.50
14.00
11.50
12.50
23.50
17.50
15.00
32.00
15. CD
15.00
-8.000
-8.000
-8.000
-5.400
-5.400
-5.400
-1.800
-3.800
-3.800
-2.400
-2.400
-2.400
-1.600
-1.600
-1.600
Initial
742
768
774
790
798
825
850
861
951
962
976
986
995
1008
1022
.719
.193
.402
.575
.821
.423
.983
.899
.219
.970
.611
.740
.413
.596
.986
DON Serial * 6841495
Date 10/5/97 Filename: F:\DATAFILE\CALIBRAT\CAL MENU.DSKNDGM REF.
Revised: 06/08/95
(DGH) Temperature Wet Test Meter (WTM) DGM Coefficient Flow
Yolune Initial Final Meter Readings Volume Temp Coefficient Variation Rate
Final (cubic feet) (deg F) (deg F)
768.193
774.402
790.575
798.821
825.423
850.983
861.899
873.960
962.970
976.611
986.740
995.411
1008.596
1022.986
1029.158
25.474
6.209
16.173
8.246
26.602
25.560
10.916
12.061
9.751
13.641
10.129
8.673
13.183
14.390
6.172
78.0
79.0
79.0
79.0
79.0
80.0
81.0
81.0
86.0
86.0
87.0
87.0
88.0
89.0
89.0
79.0
79.0
79.0
79.0
80.0
81.0
81.0
82.0
86.0
87.0
87.0
88.0
89.0
89.0
90.0
Initial
671.890
697.180
703.325
719.309
727.485
753.809
779.025
789.820
879.651
889.205
902.599
912.545
921.069
934.025
948.175
Final (cubic feet) (deg F) Yds Yds-(Avg.Yds) (CFM)
697.180
703.325
719.309
727.485
753.809
779.025
789.820
801.740
889.205.
902.599
912.545
921.069
934.025
948.175
954.255
25.290 77.0 1.016 0.002 1.208
6.145 77.0 1.013 0.000 1.204
15.984 77.0 1.012 -0.002 1.204
Max Yds - Min Yds =0.003626886 Must be no greater than 0
Average Yds «1. 013636253 Must be between 0.95 to 1
8.176 77.0 1.009 0.001 0.942
26.324 77.0 1.008 0.000 0.938
25.216 77.0 1.006 -0.001 0.932
Max Yds - Min Yds =0.002262496 Must be no greater than 0
Average Yds =1.007525980 Must be between 0.95 to 1
10.795 77.0 1.006 0.001 0.755
11.920 77.0 1.006 0.001 0.753
9.554 78.0 1.004 -0.001 0.747
Max Yds - Min Yds -0.002245979 Must be no greater than 0
Average Yds « 1.005 164 785 Must be between 0.95 to 1
13.394 78.0 1.003 -0.001 0.557
9.946 78.0 1.004 0.000 0.556
8.524 78.0 1.006 0.002 0.556
Max Yds - Nin Yds =0.002785363 Must be no greater than 0
Average Yds -1.004591811 Must be between 0.95 to 1
12.956 78.0 1.006 -0.002 0.396
14.150 78.0 1.007 0.000 0.395
6.080 78.0 1.010 0.002 0.396
.030
.05
.030
.05
.030
.05
.030
.05
Max Yds - Min Yds -0.004205886 Must be no greater than 0.030
Average Yds -1.007822494 Must be between 0.95 to 1.05
Overall Average Yds -1.007748265
I certify that the above Dry Gas Meter was calibrated in accordance with E.P.A. Method 5 , paragraph 7.1 ;CFR 40 Part 60,
using the Precision Wet Test Meter # 11AE6, which In turn was calibrated using the American Bell Prover i 3785,
certificate # F107, uhje^f is traceable to the National Bureau of Standards (H.I.S.T.).
Signature
Date
-------
REFERENCE METER CALIBRATION
ENGLISH REFERENCE METER UNITS
DGM Serial f 6841495
Barometric Pressure 29.73 Date 8/28/96 Filename: F:\DATAFILE\CALIBRAT\CAL HiNU.OSKXDSH REF.
Heter Yw 1.00000 Revised: 06/08/95
K ( deg R/ inches Hg) 17.64
Dry Gas Meter
-------
TtbUC-1
Montavrila end Stgliww duration TiM*
MWrt««Jla CALIBRATION EBBDB TESTtMETHOO 80-8.3) 3q3.fi
ACTUAL CONC RESPONSE DIFFERENCE % OF SPAM
ZERO GAS 9 04 0.4
LOW RANGE 10.7 10.7 0
MID RANGE 20 27.7 1.7 140%
HIGH RANGE 374 384 04
KitaMFIiulOuttal
ACTUAL CONC RESPONSE DIFFERENCE
% OF SPAN
ZERO GAS
LOW RANGE
MID RANGE
NWH RANGE
0
10.7
24
374
1.1
104
274
37 S
1.-.
0.'.
1.1
0.1
KUiMfnlttoHntet
ACTUAL CONC RESPONSE DIFFERENCE
ZERO GAS 0 0,3 0,9
LOW RANGE 10.7 9.3 2,4
MIO RANGE 26 274 1.4
HIGH RANGE 374 3*.1 OJ
KMM HMl talM
ACTUAL. CONC RESPONSE DIFFERENCE
ZERO GAS
LOW RANGE
MIC RANGE
HMH RANGE
0
10.7
20
37.1
10.2
284
38,3
U
OJ
0.9
o.r
940%
M0%
* OF SPAN
•40%
440%
240%
1.00%
% OP SPAN
2.40%
140%
140%
1.40%
CALIBRATION EHEoq TEartMETHoo aoe.a^ aaaag
% OF SPAN
040%
140%
KHnMfnMMCuiiM
ACTUAL CONC RESPONSE OIFFEFHNCE
ZEROGAS 000
LOW RANGE 10.7 124 14
MID RANGE M 244 I.I
HIGH RANGE 374 374 0 0.00%
Kilt 14 Final OlltM
ACTUAL CONC RESPONSE DIFFERENCE % OF SPAN
ZERO GAS 0 24 25 $.00%
LOW RANGE 107 12.2 15 3.00%
MID RANGE 26 294 34 7.00%
KI6H RANGE 174 484 « 11.00%
CALIBRATION ERBQB TfeSTfMETHQD 6&a.31 3fl4/ga
Win « WtW Ou««l
ACTUAL CONC RESPONSE DIFFERENCE % OP SPAN
ZERO GAS 0 04 04 140%
LOW RANGE 10.7 10,9 02 340%
MIO RANGE 26 26.3 04 140%
HNGH RANGE 374 374 0.1 BJO%
KKnfJFJmriOUIW .
ACTUAL CONC RESPONSE OIFFEREMCE % OP SPAM
ZERO9AS 0 1.1 1.1 2JMTK
LOW RANGE 10.7 11.4 0.7 140%
MID RANGE 2fl 26.S 24 5.00%
HIGH RANGE 874 3HB 1.3 240%
ramfunRuuntH
ACTUAL CONC RESPONSE DIFFERENCE % OP SPAN
ZERO GAS 0 04 04
LOW RANGE 10.7 10.9 04
MID RANGE
HIGH RANGE
20
i74
264
374
04
0.1
140%
0.40%
040%
KltoHRMlfntot
ACTUAL CONC RESPONSE DIFFERENCE % OF SPAN
ZEROOAS 0 1.7 1.7 S40%
OW RANGE 10.7 10.7 0 040%
MID RANGE 26 254 0.5 140%
HIGH RANGE 374 37.2 0.4 040%
-------
Scott Specialty Gases
lipped
From:
1290 COMBERMERE STREET
TROY MI 48083
Phone: 248-585-2950
CERTIFICATE OF
Fax: 243-589-2134
ANALYSIS
PACIFIC ENVIRONMENTAL SERVICES
JOHN POWELL
C/0 AIR POLUTION.C & C LT
60 INDUSTRIAL PARK RD W.
TOLLAND CT 06084
PROJECT #: 05-23193-001
P0#: 104-98-0125
ITEM #: 0502243202 5A
DATE: 2/25/98
CYLINDER #: A018685
FILL PRESSURE: 200Q PSI
ANALYTICAL ACCURACY: +/-5%
PRODUCT EXPIRATION: 8/26/1998
BLEND TYPE : CERTIFIED WORKING STD
REQUESTED GAS
COMPONENT CONG MOLES
HYDROGEN CHLORIDE 10. PPM
NITROGEN ' BALANCE
ANALYSIS
(MOLES)
10.7
PPM
BALANCE
CERTIFIED WORKING STANDARD
ANALYST:
-------
Scott Specialty Gases
[pped
From:
1290 COMBI1MER1 STREET
TROY MI 48083
Phone: 248-589-2950
CERTIFICATE OF
Fax: 248-589-2134
ANALYSIS
PACIFIC ENVIRONMENTAL SERVICES
JOHN POWELL
C/0 AIR POLUTION C & C LT "
60 INDUSTRIAL PARK RD W.
TOLLAND CT 06084
PROJECT'S: 05-23193-002
PO#: 104-98-0125
ITEM #: 0502243202 5A
DATE: 2/13/98
CYLINDER #: AQ18704
FILL PRESSURE: 2iOO PSI
ANALYTICAL ACCURACY: +/-5%
PRODUCT EXPIRATION: 8/12/1998
BLEND TYPE : CERTIFIED WORKING STD
REQUESTED GAS
COMPONENT « * COHC MOLES
HYDROGEN CHLORIDE 25. PPM
NITROGEN ' . BALANCE
ANALYSIS
(MOLES)
26.0
PPM
BALANCE
CERT IFIED WORKING • STANARD
ANALYST:
-------
ipped
From: ?•
Scott Specialty Gases
1290 COMBERMERE STREET
TROY «: MI 48083
Phone: 248-589-2950
CERTIFICATE OF
Fax: 248-589-2134
ANALYSIS
PACIFIC ENVIRONMENTAL SERVICES
JOHN POWELL
C/0 AIR POLUTION C & C LT
60 INDUSTRIAL PARK T?D W.
TOLLAND CT 06084
PROJECT #; 05-23193-003
P0#: 104-98-0125
ITEM #: 0502243202 5A
DATE: 2/25/98
CYLINDER #: A018749
FILL PRESSURE: 200Q PSI
ANALYTICAL ACCURACY: +/-5%
PRODUCT EXPIRATION: 8/25/1998
BLEND TYPE
COMPONENT
CERTIFIED WORKING STD
REQUESTED GAS
CONG HOLES
ANALYSIS
(MOLES)
HYDROGEN CHLORIDE
NITROGEN
40.
PPM
BALANCE
37.6
PPM
BALANCE
CERTIFIED WORKING STANDARD
ANALYST:
;.-,-'.
-------
Scott Specialty Gases
upped
From:
12 90'COMBERMERE STREET
TROY MI 48083
Phone: 248-589-2950
CERTIFICATE
O P
Fax: 248-589-2134
ANALYSIS
PACIFIC ENVIRONMENTAL SERVICES
JOHN POWELL
C/O AIR POLUTION C & C LT
60 INDUSTRIAL PARK RD W.
TOLLAND CT 06084
PROJRCT #: 05-23193-004
PO#: 104-98-0125
ITEM f: 05022430 5A
DATE: 2/12/98
CYLINDER #: A017718
PILL PRESSURE: 2000 PSI
ANALYTICAL ACCURACY: -t-/-5%
PRODUCT EXPIRATION: 8/12/1998
BLEND TYPE : CERTIFIED WORKING STD
REQUESTED GAS
COMPONENT CONG MOLES
ANALYSIS
(MOLES)
HYDROGEN CHLORIDE
NITROGEN
100.
PPM
BALANCE
101,
PPM
BALANCE
CERTIFIED WORKING STANDARD
ANALYST:
-------
325
OW
Pbon
FAX: (205)250-664?
Date:
Record Number
Customer Name:
Purchase Order #:
Grade of Product:;
CERTIFICATE OF ANALYSIS
11/4/87
3350
Akgas Cheshire
127383
Primsty Standard
Required
Actual
Cylinder Number.
CC7iQ06
Component
Methane
Nitrogen
Concentration
30 ppm
Balance
Concentration
29.97 ppm
Balance
Uncertainty Of Analytical Result
1 %
Approval Sig
cp
-------
02/28/9?
.-43
Coos
asProduots
CERTIFICATE OF ANALYSIS CALMA1 ilAit,Y
CBSTOMIls ABCQ WddtngaradladitsGcM
CYLUCDCKilh SX-27307
CY1JM)EEPBJESST7RE: 2000 grig
AFXLYSB DATE: 8^20/96
RXPTB ATION DATE: 8OJV99
! 109-51S46
CALMAT DAIL-Vi 3
COMPONENTS
COWC: SLlfpra
COMPONENT:
CONC:
CXUMPONENT:
COlfCi
BAJLANOCGAS: Nttrogcn
B£f£RI3tCl *:
CYLINDER*;
SKNM73O
SX-20007
MTTHOD*
Mctlaun
I-140S-04-T1
2151A92*I3
OC-PJD
LAST CAUBRAT1CW:
THIS CERTinCATKSI WAS fERKHMEDMXXJRDINOTO SIAIiDA3iI3ClaERA311iClf1IOCEiXJKES AMD IS
TRACEABLE TO AN MIST ST««IDARD,
ANALYST
/2^^
DAIS
twPi
TwifMfeun, Onto 4WB7
Tofl Pw* (too) 4e»M27
02/25/97 09:43
TX/RX NO,2452
P. 006
-------
FAX: (203) 250-6842
Date:
Customer Name:
Address:
CERTIFICATE OF ANALYSIS
03-5-97 ^Record Number:
NORTHEAST A1RGAS CHESHIRE
Purchase Order*: 98537
Grade of Product Primary Standard
Cvtinder Number
CC43103
Component
METHANE
NITROGEN
JReguired
^Concentration
85 PPM
BALANCE
-*.
1
1987
Actual
Concentration
84.8 PPM
BALANCE
Uncertainty of Analytical Result: ± 1 %
1
-------
Airgas
Airgas Specialty Gases
325 MeCauslareJ Court
Chesftire.CT 05*10
Ptwn* (203) 250-6827
FAX; (203}25!N»I2
Certificate of Analysts: E.P.A. Protocol Gas Mixture
Red*
Cylinder No:
Cylinder Pressure:
Certification Date
4149
CC84096
2000
Purchase Order f
Expiration Date:
Laboratory:
139680
3/2/01
Cheshire, CT
Reference. Stan daniMormattoii:
Tyflg Component
GMIS Carbon Dioxide
GMIS Oxygen
Cyj. Number
CC34977
CC19914
Concentration
14.08%
20.98%
Instrumentation:
No.
Rosemount/'NGA2000/Rack#1
Servomex/2447701/488
Analytical Principle
ND1R
Parmagrtette
Analytical Methodology does not require correction for analytical interferences.
Certified Concentrations:
Analytical Results:
1st Analysis Date:
R 3.259
S
2
0.266
2nd Component;
1st Analysis Date:
R _ 173.630
S
Z
91.30
1.8SO
2/1&98
S
R
3/2/98
S
Z
R
2.8%
3.298
Z 0.305
R —
S
91.150
1.420
173.&30
Z
R
S
3.305
1.480
91JTO
Cone
Cone
Cone
AVG:
Cone
Cone
Cone
AVG:
10.896 %
11.066%
10.987%
11.060%
11.000 %
11.032 %
11.051 %
Certification performed in accordance with 'EPA Traceabiiity Protopol {Jan. 1998)" using the assay
procedures listed.
Do not use cylinder below 150 pskj.
' Approved for Release
-------
NATIONAL SPECIALTY GASES
630 immp DRIVE
DURHAM, NC
CERTIFICATE Or ANALYSIS 1 EPA PROTOCOL MIXTURES
REFERENCE*: St-WttS
6XP. DATE: 4/3,99
METHOD: ANALYZED AI
1993:0-1 THIS STANDARD SHOl
COMPONENT: CARBON DV,
STANDARD
SRM* I675B
CYLtt CLMM81 J
CONC: 14.01% '
INSTRUMENT: ROSEMOUNT
MODEL*: ISO
SERIAL *: 2000418
LASTCAL.: 3/2t«*
MEANCONC.: 20
REPLICATE COKC.
DATE: 4/1/96
20J %
20.1 %
20.2 %
CYLINDER 1: CCCT029 fcYL, I RESSURi: 1000 PSIG P.0.#: 11771
LAST ANAL VS.S DATE: 4/3/96 CUSTOMER: CONNECTICUT AIRGAS
,D NOT BE USED WHEN ITS GAS PRESSURE IS BELOY/ 1.0MEOAPA5CALS (I5C-PSIG).
ODE
[
NDIR
.214 +/- 0.2 %
DATE:
COMPONENT: OXYGEl
STANDARD
SRMtf: 2659A
CYL,* ^ CLMW:
CONC: * 20.72 K
1NSTHUMENT: BECKM
MODEL*: 735
SERIAL 1: 1001419
tASTCAL.: 4/1 W :
[MEAN CONC: '""'""1
IREPUCATE CONC. I
DATE: W/96 ;
20.4 ' H |
20.4 fi
20.5 « ;
BALANCE GAS: NITROGEN
REPLICATE DATA
DATE: 43/96
Z 0 ft
R 14.0 Z
Z 0 C
I RE
N.I C 20.)
o c 20.;
20 J R 14.!
ANALYST: 'KVl^H^H' 1"^^
PLICATE DATA
DATE: 43/96
Z 0
R 3*4
Z 0 !
,-••-.•••••
.
kN PARAMAGNETIC
20,4?i *.'• 0.2%
DATE:
| REPLICATE DATA
»
R. 394 C 390
Z 0 C 392
C 390 R 394
Z-ZERO C=CANOIDKTE R-REfERENCB \J) fJ(fi 1
| APPROVED BY; $BUMAJomHWM/r
COMMCIMN wrw nm MfMir, NATMWAI, IMCIM-T* GAIM w*u n*vt MO tnra.iit w EXOHOI m
-------
4E
PACIFIC ENVIRONMENTAL SERVICES, INC.
4700 Duke Drive,
Suite 150
Mason, Ohio 45040
Phone:(513)398-2556
Fax (513) 398-3342
www.pes.com
Pitot Tube Number:
Effective Length:
4E
49"
Pitot Tube Openings Damaged?
Pitot Tube Assembly Level?
a , = 0
P, = L
Y= 0
z = A sin Y =
w = A sin 6 =
0
0.0170
PA =
Pn =
Date:
Calibrated By:
YES
| YES I
°(< 10°)
INOI
NO
2 =
6=
1
A=
cm (in.) 0.32 cm ( < 1/8 in.)
cm (in.) 0.08 cm ( < 1/32 in.)
0.487 cm (in.)
0.486
0.375
cm (in.)
cm (in.)
12/23/97
S. Simon
0.973
.......w..4
(0)
The types of face-opening misalignment shown above will not affect tie baseline value of Cp(s) so
long as a, and "s is less than or equal to 1 O°, (it and IJ2 is less than or equal b 5°, z is less than or
equal toO.32 cm (1/8 in.), and w is less than or equal to O.O8 cm(1/32 in.) (refenonce 11.O in
Recfinn -1 6 DV
Assigned Pitot Coefficient:
0.84
'(< 10°)
Pitot Tube Calibration Form
1998 Yearly Calibration
-------
4F PACIFIC ENVIRONMENTAL SERVICES, INC. 470° D
Mason. <
Phone: (513
Fax (5 12
wv,
Pilot Tube Number: 4F Date: 12/23/97
Effective Length: 49"
Pitot Tube Openings Damaged".' YES
Calibrated By; S. Simon
n^~i
Pilot Tube Assembly Level? C YES | NO
a , - 1 "(< 10°) a j - 0
P, - 1 9«5IJ) P, = 0
-Y=> 1 0
z - A sin Y = 0-017
w » A sin 0 = 0.
PA =
>P-
D,=
V i
1*1
• n N. i in .' i ,m.i»....iii»j«f«»ii»».«»..»g*»«~»* —
i B ^J>~'^..Va"- "•"
1* ^ ,">"^ll ,
(.1
- JL."l n -rT~T^~'- .
C J..WLJ-. — " .', ^SC^T^ , w I
7
lM^"'""d"
p.FW»»>~
in 8 ID
fn* typflK of fiefl-op*nlng mlsatfgnm *nt
lonfi 91 a, «nc a, It ttsi inin or >«uil 10
equal u 0.32 cm <1/( In.;, ana « is Ian
Section 16.0).
i no» n BBS** «iii not *ff*ei tn* baidlni *ciu* at c p(t j 10
10*. a, ifid a, la ikii m«n or iquil la t', t It !•»• inin or
ui«n or equ»i 10 O.OB cm(1/3Z In.) (r»f«rtrc»M .0 In
Suite ISO
hio 45040
398-2556
398-3342
www.pes.com
*(< 10")
«5°)
Pitot Tube Calibration Form
1998 Yearly Calibration
-------
RP-21
PACIFIC ENVIRONMENTAL SERVICES, INC.
4700 Duke Drive,
Suite 150
Mason, Ohio 45040
Phone:(513)398-2556
Fax (513) 398-3342
www.pes.com
Pitot Tube Number:
Effective Length:
RP-21
Pitot Tube Openings Damaged?
Pitot Tube Assembly Level?
O i = 0_
Pi = L
Y = l
YES
I YES I
°(< 10°)
9=
Date: _
Calibrated By:
I N0 »
NO
a 2 =
A =
z = A sin Y =
w = A sin 6 =
0.0179
0.0000
cm (in.) 0.32 cm
cm (in.) 0.08 cm
7/14/98
J. Brown
1.023
'(< 10°)
H
IA
Dt =
^7
(d)
0.5115
0.375
3, B
cm (in.)
cm (in.)
> .......... .V B2(* or-)
«,--",",",.l! _______ .Zk.Sist <"• ->
(a)
The Vpes of face-operrfng misalignment shewn above will not affectthe bas«lin@ value of Cp(s) so
long as <*, and°S is less than or equal to 1O°. O, and Bz is less than or equal to S", z is less than or
equal toO.32cm(1& in.), and w islesstfianorequalto O.O8 cnrt(1 &2 in.) (refrarancel 1,O in
Section 1 6-QV. __^ ^
Assigned Pitot Coefficient, Cp:
0.84
Pitot Tube Calibration Form
1998 Yearly Calibration
-------
TEMPERATURE SENSOR CALIBRATION FORM
Temperature Sensor No.
Ambient Temp. °F
Sensor Type
5=
-------
e
TEMPERATURE SENSOR CALIBRATION FORM
Temperature Sensor No.
Ambient Temp. °F 7
Reference Temp. Sensor:
Sensor Type fc-Tc. Length
Barometric Pressure, "Hg
t &/
Date
Vlo-IV
•*r
if
Ref.
Point
No.
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
Temp.
Source
ic€
M»-o
^Mft,
M/2-
l3*t<-
K<-o
Temp. °F
Ref.
Sensor
31-
70
*L&<*>
Test
Sensor
3f-
17
2^€"
Temp.
Diff. %
.^oc.
JS'c.
o/SO
Within
Limits
Y/N
y
y
X
Calibrated
By
)iu^
1^
^^
. Diff - (Ref '
B
(Ref. Temp. +• 460)
100 « l.S
-------
TEMPERATURE SENSOR CALIBRATION FORM
^.fAYS-* -> i
Temperature Sensor No. Dc>M -1P Sensor Type N -TC Length i
Ambient Temp. °F
Reference Temp. Sensor:
Barometric Pressure, "Hg lo.z,*^-''
Date
Hs-^lr
c,
a
Ref.
Point
No.
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
Temp.
Source
nto
tv*£'
^ o>\<-«
l-^l, \J
Temp. °F
Ref.
Sensor
31
IT
ZoV
Test
Sensor
^
7^
-z-t o
Temp.
Diff. %
.404.
o
.tn
Within
Limits
Y/N
M
V
X
Calibrated
By
\v&
iV^B
XU^
% Temp. Diff - (J?ef • Temp + 460) " ( Test
* (Ref. Temp. + 460)
460)
x 100 « 1.5 %
-------
TEMPERATURE SENSOR CALIBRATION FORM
u -
Temperature Sensor No. Pc^-oof Sensor Type K - ic Length
Ambient Temp. °F 7^ Barometric Pressure, "Hg
Reference Temp. Sensor:
Date
i~lS--1*
/.
•'
Ref.
Point
No.
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
Temp.
Source
Hz»
|'\AV&
nti'
Temp. °F
Ref.
Sensor
S3
•7-t .
i-otj
Test
Sensor
33
-7.*"
•2.0TT
Temp.
Diff. %
0
. 1*7
o
Within
Limits
Y/N
V
Y
Y
Calibrated
By
r\W^>
^u^>
Hu)\
% Temp. I3iff =
(Ref- TemP + 460) ~ ( Teat Temp.
460)
(Ref. Temp. + 460)
x 100 s x 5
-------
Q5/04/9S 12:57
PACIFIC ENVIRONMENTAL SERVICES.INC.
4700 Duke Drive,
Suite 150
Mason, Ohio
Phone: (513) 398-2S56
Fax: (513)3S83342
www.pes.com
TEMPERATURE SENSOR CALIBRATION DATA
FOR STACK THERMOCOUPLES
THERMOCOUPLE NUMBER:
4E
DATE:
12/23/97
BAROMETRIC PRES.(ln.Hg):
AMBIENT TEMP, °F:
29.52
74
REFERENCE:
Mercury-in-g lass:
Other:
"CALIBRATOR:
ASTM-3F
G.Gay
Reference
point
number
1
2
3
4
Source8
(Specify)
Ambient Air
Cold Bath
Hotiath
Hot Oil
Reference
Thermometer
Temperature,°F
74
38
203
339
Thermocouple
Potentiometer
Temperature,°F
74
33
202
340
Temperature
Difference,"
%
(XQO
0.00
0,15
0.13
Type of calibration used.
bf ref. tsmo gF+46QWtest thermometer temp.flF+460i
X100
reftemp,
-------
PACIFIC ENVIRONMENTAL SERVICES,INC.
4700 Duke Drive,
Suite 150
Mason, Ohio
Phone: (513) 398-2556
Fax:(513)3983342
www.pes.eotn
TEMPERATURE SENSOR CALIBRATION DATA
FOR STACK THERMOCOUPLES
THERMOCOUPLE NUMBER:
4F
DATE:
12/23/97
BAROMETRIC PRES.(ln.Hg):
AMBIENT TEMP. °F:
29.52 •
76
_ REFERENCE:
'Mercury-in-glass:
Other:
'CALIBRATOR:
ASTM-3F
J.C.
Reference
point
number
1
2
3
4
Source*
(Specify)
Ambient Air
Cold Bath
Hot Bath
Hot Oil
Reference
Thermometer
Temperature,BF
76
38
204
341
Thermocouple
Potentiometer
TemperatuiB,BF
76
38
204
342
Temperature
Difference, "
%
0.00
0,00
0.00
0.12
*Type of calibration used,
"fref. tsfno_flF+460Wtest thermometer temD.aF+4601
X100
reftemp,aF+460
Comments:
100<1.5%
STACK THERMOCOUPLE CALIBRATION FORM
1 i98 Yearly Calibration
-------
APPENDIX E
PARTICIPANTS
-------
PROJECT PARTICIPANTS
Name
Affiliation
Responsibility
Michael L, Toney
Frank J. Phoenix
Troy Aberaathy
Paul Siegel
Gary Gay
Mike Maret
US EPA Emissions Measurement Center
Pacific Environmental Services, Inc.
Pacific Environmental Services, Inc
Pacific Environmental Services, Inc
Pacific Environmental Services, Inc
Pacific Environmental Services, Inc
Cybelle Brockman Research Triangle Institute
Eric Dithrich1 APCC
Terry Thorn asson1 APCC
Work Assignment Manager
Project Manager
Site Leader/Console Operator
Site Leader/Console Operator
Sampling Technician
Sampling Technician/Sample
Recovery
Process Data Recorder
CEM Team Leader
CEM Sampling Technician
Subcontractor to Pacific Environmental Services, Inc.
-------
TECHNICAL REPORT DATA
Please read instructions on the reverse before completing
1. REPORT NO.
EPA-454/R-99-043
2,
4. TITLE AND SUBTITLE
Final Report
Manual Testing and Continuous
Emissions Monitoring, Lime Kiln
Nos. 3 and 4 Baghouses
Chemical Lime Company
Montevallo, Alabama
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Pacific Environmental Services, Inc.
Post Office Box 12077
Research Triangle Park, North Carolina 27709-2077
12. SPONSORING AGENCY NAME AND ADDRESS
U.S. Environmental Protection Agency
Office of Air Quality Planning and Standards
Emissions, Monitoring and Analysis Division
Research Triangle Park, North Carolina 2771 1
3. RECIPIENT'S ACCESSION NO.
5. REPORT DATE
September 1999
6. PERFORMING ORGANIZATION CODE
8. PERFORMING ORGANIZATION REPORT NO.
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-D-70069
13. TYPE OF REPORT AND PERIOD COVERED
Final
1 4. SPONSORING AGENCY CODE
EPA/200/04
15. SUPPLEMENTARY NOTES
16. ABSTRACT
The United States Environmental Protection Agency (EPA) Emission Standards Division (ESD) is investigating the lime manufacturing industry to
identify and quantify hazardous air pollutants (HAPs) emitted from lime kilns. ESD requested that EPA's Emissions, Monitoring and Analysis Division
(EMAD) conduct the required testing. EMAD issued a work assignment to Pacific Environmental Services, Inc. (PES) to conduct a screening test to
collect air emissions data as specified in the ESD test request. The primary objective of the testing program was to characterize HAP emissions from two
lime kilns at the Chemical Lime Company's facility located in Montevallo, Alabama. Based on the pollutant concentrations and emission rates calculated
from the results of the screening tests, the kilns may be selected by EPA for further testing.
The tests were conducted to quantify the uncontrolled and controlled air emissions of hydrogen chloride (HCI), total hydrocarbons (THC), and
polychlorinated dibenzo-p-dioxins and polyclorinated dibenzofurans (PCDDs/PCDFs). Emissions from each kiln were controlled by a baghouse
dedicated to each kiln. Over a two-day period, testing was conducted at each baghouse inlet and at the common stack. Inlet and outlet runs on each
kiln were conducted simultaneously. Oxygen (OJ and carbon dioxide (CO2) were also monitored at each location.
During the testing program another EPA contractor monitored and recorded process and emission control system operating parameters, and
prepared Section 3.0, Process Description, of this report.
17.
a. DESCRIPTIONS
Baghouse
Dioxins/Furans
Hazardous Air Pollutants
Hydrogen Chloride
Total Hydrocarbons
18. DISTRIBUTION STATEMENT
Unlimited
KEY WORDS AND DOCUMENT ANALYSIS
b. IDENTIFIERS/OPEN ENDED TERMS
19. SECURITY CLASS (This Report)
Unclassified
20. SECURITY CLASS (This page)
Unclassified
c. COASTI Field/Group
21. NO. OF PAGES
436
22. PRICE
EPA Form 2220-1 (Rev. 4-77) PREVIOUS EDITION IS OBSOLETE
F:\U\FMeadows\TRD.Frrn\WP 6.1
-------
TECHNICAL REPORT DATA
Please read instructions on the reverse before completing
1. REPORT NO.
EPA^54/R-99-043
2.
4. TITLE AND SUBTITLE
Final Report
Manual Testing and Continuous
Emissions Monitoring, Lime Kiln
Nos. 3 and 4 Baghouses
Chemical Lime Company
Montevallo, Alabama
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Pacific Environmental Services, Inc.
Post Office Box 12077
Research Triangle Park, North Carolina 27709-2077
12. SPONSORING AGENCY NAME AND ADDRESS
U.S. Environmental Protection Agency
Office of Air Quality Planning and Standards
Emissions, Monitoring and Analysis Division
Research Triangle Park, North Carolina 2771 1
3. RECIPIENT'S ACCESSION NO.
5. REPORT DATE
September 1999
6. PERFORMING ORGANIZATION CODE
8. PERFORMING ORGANIZATION REPORT NO.
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-D-70069
13. TYPE OF REPORT AND PERIOD COVERED
Final
14. SPONSORING AGENCY CODE
EPA/200/04
15. SUPPLEMENTARY NOTES
16. ABSTRACT
The United States Environmental Protection Agency (EPA) Emission Standards Division (ESD) is investigating the lime manufacturing industry to
identify and quantity hazardous air pollutants (HAPs) emitted from lime kilns. ESD requested that EPA's Emissions, Monitoring and Analysis Division
(EMAD) conduct the required testing. EMAD issued a work assignment to Pacific Environmental Services, Inc. (PES) to conduct a screening test to
collect air emissions data as specified in the ESD test request The primary objective of the testing program was to characterize HAP emissions from two
lime kilns at the Chemical Lime Company's facility located in Montevallo, Alabama. Based on the pollutant concentrations and emission rates calculated
from the results of the screening tests, the kilns may be selected by EPA for further testing.
The tests were conducted to quantity the uncontrolled and controlled air emissions of hydrogen chloride (HC1), total hydrocarbons (THC), and
polychlorinated dibenzo-p-dioxins and polyclorinaied dibenzofurans (PCDDs/PCDFs). Emissions from each kiln were controlled by a baghouse
dedicated to each kiln. Over a two-day period, testing was conducted at each baghouse inlet and at the common stack, inlet and outlet runs on each
kiln were conducted simultaneously. Oxygen (0;) and carbon dioxide (CO;) were also monitored at each location.
During the testing program another EPA contractor monitored and recorded process and emission control system operating parameters, and
prepared Section 3.0, Process Description, of this report
1 7. KEY WORDS AND DOCUMENT ANALYSIS
a. DESCRIPTIONS
Baghouse
Dioxins/Furans
Hazardous Air Pollutants
Hydrogen Chloride
Total Hydrocarbons
18. DISTRIBUTION STATEMENT
Unlimited
b. IDENTIFIERS/OPEN ENDED TERMS
19. SECURITY CLASS (This Report)
Unclassified
20. SECURITY CLASS (This page)
Unclassified
c. COASTI Field/Group
21. NO. OF PAGES
436
22. PRICE
EPA Form 2220-1 (Rev. 4-77) PREVIOUS EDITION IS OBSOLETE
F:\U\FMeadows\TRD.Frm\WP 6
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