APPLY PESTICIDES CORRECTLY A GUIDE FOR COMMERCIAL APPLICATORS SEED TREATMENT U.S. ENVIRONMENTAL PROTECTION AGENCY OFFICE OF PESTICIDE PROGRAMS WASHINGTON, O.C. 20460 ------- TABLE OF CONTENTS Page Acknowledgments 1 Preface 1 Introduction 2 Seeds Commonly Treated 2 Seed Pests 2 Nonchemical Control of Pests 2 Chemical Control of Pests 2 Seed Treatment Formulations 2 Pesticide Labels 3 Application Equipment 3 Coloring Treated Seed 3 Labeling Treated Seed 4 Safety and Environmental Precautions ... 4 Appendix 5 1976 i ------- ACKNOWLEDGMENTS PREFACE This guide has been developed by Kansas State Uni- versity under U.S. Environmental Protection Agency (EPA) contract number 68-01-2693. This contract was issued by the Training Branch, Opera- tions Division, Office of Pesticide Programs, EPA. The leader of this group effort was Frank G. Bieberly, Kansas State University. Editors were Mary Ann Wamsley, EPA, and Donna M. Ver- meire, North Carolina State University. Contributors were: E. L. Poland, E.I. duPont de Nemours & Company, Wilmington, Delaware Dell E. Gates, Kansas State University Earl D. Hansing, Kansas State University Claude L. King, Kansas State University W. H. Lange, University of California Harold D. Loden, American Seed Trade Associa- tion, Washington, D.C. Harvey Lowery, Georgia Crop Improvement Asso- ciation, Athens, Georgia John J. MacFarlane, Jr., Gustafson, Inc., Dallas, Texas Don McGillivray, Funk Seeds International, Bloom- ington, Illinois Foil McLaughlin, North Carolina Crop Improve- ment Association, Raleigh, North Carolina Glenn D. Moore, Northrup, King & Company, Eden Prairie, Minnesota Richard F Moorer, U.S. Environmental Protection Agency Earl Olson, Lynk Brothers and Baird Company, Marshalltown, Iowa M. L. (Curt) Palmer, Corn States Hybrid Service. Inc., Des Moines, Iowa Otto E. Schultz, Cornell University Walter Walla, Texas A&M University Robert T. Wallace, Chevron Chemical Company, San Francisco, California William G. Willis, Kansas State University Federal regulations establish general and specific standards that you must meet before you can use or supervise the use of certain pesticides. Your State will provide material which you may study to help you meet the general standards. This guide contains basic information to help you meet the specific standards for applicators who are engaged in seed treatment pest control. Because the guide was prepared to cover the entire nation, some information important to your State may not be included. The State agency in charge of your train- ing can provide the other materials you should study. This guide will give you information about: • types of seeds that may require chemical protec- tion against pests, « seed treatment pesticide formulations, • seed treatment methods, • labeling treated seed, and • safety and environmental precautions. ------- INTRODUCTION Seed treatment, as defined by the Federal Seed Act, means: " given an application of a substance or subjected to a process designed to reduce, control, or repel disease organisms, insects, or other pests which attack seeds or seedlings growing therefrom." It includes control of pests while the seed is in stor- age and after it has been planted. A person treating seed should know: • the kinds of seeds which should be treated, and • the correct use of seed treatment pesticides. The kinds of pesticides used vary according to lo- cality. Get specific information from the local Co- operative Extension Service or the pesticide manu- facturer. Registered chemical products are effective and safe when used as directed. Match each seed treatment pesticide with equip- ment that can apply it correctly. The manufacturer can provide you information on how to use and maintain the equipment. SEEDS COMMONLY TREATED The kinds of seeds usually treated include: wheat, barley, rye, oats, rice, sorghums and sorghum-Sudan grass hybrids, field corn and sweet corn, cotton, sugar beets, soybeans, sunflowers, peas and beans, and peanuts. SEED PESTS Major kinds of seed pests are: • fungi and bacteria (such as seed rots, seedling blight, and smuts of grains), • soil insects (such as the seed corn beetle and wire- worms), and • storage insects (including weevils, moths, and beetles). NONCHEMICAL CONTROL OF PESTS Although most seed protection is done with chemi- cals, you also should know about nonchemical methods, such as: • development of plant and crop varieties whose seeds are resistant to pests, • use of low humidity and low temperature in stor- age areas to inhibit the growth of bacteria, mold, and mildew, and to slow the growth of insect pests, and • use of good sanitation practices (such as remov- ing waste seed and seed particles from the storage area) to reduce food and shelter for pests. CHEMICAL CONTROL OF PESTS There are three types of chemical control for seed diseases and insects: • Seed surface disinfestation—complete covering of the seed with a pesticide which kills spores and other disease agents on the surface of the seed. • Seed protection—applying a pesticide to the seed to protect the seed and young seedling from dis- ease agents or insects in the soil or in storage. • Systemic treatment—applying a pesticide which penetrates the seed and/or extends into the plant as it grows. It repels or kills certain types of fungi or insects, or keeps them from causing damage. SEED TREATMENT FORMULATIONS ACTIVE INGREDIENTS—The label lists the names of all active ingredients and tells what per- cent of the formulation each makes up. INERT INGREDIENTS—Seed treatment pesticide formulations often contain carriers, binders, wetting agents, emulsifiers, suspending agents, and dyes. These materials are inert ingredients, which do not have to be listed individually on the label. They are added to the formulation to: « improve appearance, 8 increase coverage, • increase adherence, • prevent dusting-off, and • provide hazard recognition. ------- They have little or no effect on seed germination. TYPICAL SEED TREATMENT PESTICIDE FORMULATION Active Ingredient: Inert Ingredients: Total: Chemical Name 80% Wetting Agent 3% Dyes 2% Suspending Agents 3% Carriers 6% Stickers 2% Oils 4% 100% COMPATIBILITY—Most seed treatment pesticides are compatible when mixed together. Consult the pesticide label or the pesticide manufacturer for compatibility information. To test compatibility, make a small slurry mixture of the materials in the correct ratio before starting the actual mixing. Check compatibility information before applying a pesticide to inoculated seed. PESTICIDE LABELS Before using any seed treatment pesticide, read and analyze the information on the label. The label con- tains detailed information about: • active ingredients, • safety precautions, • antidotes, • type of seed the pesticide can be used on, • application rate, • pests the product will control, and • care in handling and use of treated seed. APPLICATION EQUIPMENT Commercial seed treaters are designed to apply ac- curately measured quantities of pesticides to a given weight or volume of seed. Too much of a pesticide may injure seed, and too little is often not effective, To perform accurately, a seed treater: • must be adjusted correctly at all times, and • must be given continuous preventive maintenance. Check often during use to see that the amount of formulation that has been used is in the correct pro- portion to the amount of seed that has been treated. There are three basic types of commercial seed treaters: LIQUID TREATERS—for all formulations not re- quiring agitation during application. Advantages: • no agitation needed, • pesticide can be pumped directly from pesticide container into equipment, e machines require less space than other types, • give good seed penetration. Limitations: • limited to liquid pesticide formulations, • useful mainly on cottonseed and small grains, • require a fume collection system. SLURRY TREATERS—for formulations requiring agitation during application. Advantages: • can be used to treat many seed types and varieties, • give good coverage and are accurate, • are economical. Limitations: • pesticides used need vigorous and continuous agi- tation, • require a dust and/or fume collection system, • limited to wettable powders or emulsifiable con- centrates. DUST TREATERS—for dry formulations. Advantages: • add no moisture to the seed, • easy to clean and operate. Limitations: • limited to dust formulations, • sometimes inaccurate, • dust drifts easily. The operator's manual supplied by the manufacturer will guide you in the correct use and maintenance of the equipment. COLORING TREATED SEED Food and Drug Administration regulations require that all food grain seeds treated with seed treatment pesticide formulations be dyed to prevent their use as food or feed. Most seed treatment pesticides for in-plant use come from the manufacturer with the color added. Color- ing is not required for planter-box formulations. Some seed processors prefer to add more dye to get ------- the color they want. Dyes approved for this purpose have little or no effect on seed germination and pre- sent little or no danger to people who process or use the seed. LABELING TREATED SEED The Federal Seed Act regulates the labeling of treated seed. (See Appendix.) The following infor- mation, in type no smaller than 8 points, is required on treated.seed containers: • A statement indicating that the seed has been treated. • Name of the seed treatment pesticide used—either the common name, chemical (generic) name, or abbreviated chemical name. • Seed treated with highly toxic substances requires a label bearing a skull and crossbones and a pre- cautionary statement, such as "This Seed Treated With Poison." The skull and crossbones must be at least twice the size of the type on the label. The precautionary statement must be in red letters on a contrasting background. THIS SEED TREATED WITH POISON Treatment Used: Phorate Federal Seed Act regulations contain a list of the substances considered highly toxic. Seed treated with most substances not on the highly toxic substances list requires a label with an appropriate precautionary statement, such as "Do not use for food, feed, or oil purposes." This Seed Treated With Captan Do not use for food, feed or oil purposes Federal Seed Act regulations list the treatment substances and rates of occurrence for which no warning statement is necessary. This information may appear on a separate tag or seed analysis tag, or it may be printed conspicuously on the side or top of the seed container. These are minimum labeling requirements. Some seed treat- ment pesticide labeling recommends additional in- formation that should be added to the label on the treated seed. You also should check for your own State's requirements for these treated seed container labels. SAFETY AND ENVIRONMENTAL PRECAUTIONS Some suggested precautions for seed treatment in- clude: • The seed treatment area should have an approved exhaust and dust-collecting system to remove toxic vapors and dust. Do not allow pesticide dust or fumes to reach unprotected employees or to reach commodities to be used for food, feed, or oil purposes. • To avoid contaminating seed with an incorrect pesticide, the seed treating equipment must be throughly cleaned before the treating process be- gins. Consult the pesticide manufacturer for the names of cleansers and directions for their use. • Do not run water containing pesticides into a stream or public sewer. Handle it as you would an excess pesticide. Check with local authorities when you have large amounts of such waste water. • Dispose of empty treated seed containers and un- used treated seed as you would excess pesticides. Contact the Board of Health or other local au- thority for requirements and disposal areas. • Special tightly woven bags, or polyethylene or foil-lined bags, are recommended for seed that have been treated with some highly toxic pesti- cides. • Handle treated seed in accordance with instruc- tions on the label of the pesticide that was applied to the seed. • Store treated seed in labeled containers away from unprotected persons and food or feed products. Treated seed must never be mixed with food and feed products. • Provide customers with copies of pertinent label- ing information for the pesticide applied. ------- APPENDIX The production of organo mercurial pesticides for seed treatment was prohibited by EPA on February 17, 1976. However, stocks formulated prior to that date may be sold and used until exhausted. Further action by EPA and other interested parties is to be anticipated. The following is excerpted from the Federal Seed Act (Title 7, Ch. I, Part 201 of the Code of Federal Regulations), for specific information about label- ing of treated seed. LABELING IN GENERAL 201.31a Labeling treated seed.— (a) Contents of label.—Any agricultural seed or any mixture thereof or any vegetable seed or any mixture there- of, for seedling purposes, that has been treated shall be labeled in type no smaller than 8 points to indi- cate that the seed has been treated and to show the name of any substance or a description of any process (other than application of a substance) used in such treatment, in accordance with this section; for example, Treated with (Name of substance or process) or treated. (Name of substance or process) If the substance used in such treatment in the amount remaining with the seed is harmful to hu- mans or other vertebrate animals, the seed shall also bear a label containing additional statements as required by paragraphs (c) and (d) of this section. The label shall contain the required information in any form that is clearly legible and complies with the regulations in this part. The information may be on the tag bearing the analysis information or on a separate tag, or it may be printed in a conspicuous manner on a side or top of the container. bonate, cuprous oxide, zinc hydroxide, hexachloro- benzene, and ethyl mercury acetate. The terms "mercury" or "mercurial" may be used in labeling all types of mercurials. Examples of commonly ac- cepted abbreviated chemical names are: BHC (1,2,3,-4,5,6,-Hexachlorocyclohexane) and DDT (dichloro diphenyl trichloroethane). (c) Mercurials and similary toxic substances.— (1) Seed treated with a mercurial or similarly toxic substance, if any amount remains with the seed, shall be labeled to show a representation of a skull and crossbones at least twice the size of the type used for information required to be on the label under paragraph (a) and shall also include in red letters on a background of distinctly contrasting color a statement worded substantially as follows: "This seed has been treated with Poison," "Treated with Poison," "Poison treated," or "Poison." The word "Poison" shall appear in type no smaller than 8 points. (2) Mercurials and elude the following: Aldrin, technical Demetron Dieldrin p-Dimethylamino- benzenediazo sodium sulfonate Endrin Ethion Heptachlor similarly toxic substances in- Mercurials, all types Parathion Phorate Toxaphene O-O-Diethyl-0- (isopropyl-4-methyl- 6-pyrimidyl) thiophosphate O,O-Diethyl-S-2- (ethylthio) ethyl phosphorodithioate Any amount of such substances remaining with the seed is considered harmful within the meaning of this section. (b) Name of substance.—The name of any sub- stance as required by paragraph (a) of this section shall be the commonly accepted coined, chemical (generic), or abbreviated chemical name. Com- monly accepted coined names are free for general use by the public, are not private trademarks, and are commonly recognized as names of particular substances; such as thiram, captan, lindane, and dichlone. Examples of commonly accepted chemi- cal (generic) names are: bluestone, calcium car- (d) Other harmful substances.—If a substance, other than one which would be classified as a mer- curial or similarly toxic substance under paragraph (c) of this section, is used in the treatment of seed, and the amount remaining with the seed is harmful to humans or other vertebrate animals, the seed shall be labeled with an appropriate caution state- ment in type no smaller than 8 points worded sub- stantially as follows: "Do not use for food," "Do not use for feed," "Do not use for oil purposes," or ------- "Do not use for food, feed, or oil purposes." Any Allethrin—2 p.p.m. Piperonyl butoxide—8 amount of any substance, not within paragraph (c) Malathion—8 p.p.m. p.p.m. on oat and of this section, used in the treatment of seed, which Methoxychlor—2 p.p.m. sorghum and 20 remains with the seed is considered harmful within p.p.m. on all other the meaning of this section when the seed is in seeds. containers of more than 4 ounces, except that the Pyrethrins—1 p.p.m. on following substances shall not be deemed harmful oat and sorghum and when present at a rate less than the number of parts 3 p.p.m. on all other per million indicated: seeds. GPO 906-287 ------- |