WAS 1995'S OZONE SEASON IN TEXAS EXCEPTIONAL?
                Air Quality Analysis Section
          Multimedia Planning and Permitting Division
                      EPA Region 6
                    January 26, 1996

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PREFACE

      The purpose of this analysis is to present a review of meteorological and air quality data used to answer the question,
"Was the 1995 Texas Ozone Season  exceptionally stagnant and hot?"

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EXECUTIVE SUMMARY
      The U.S. Environmental Protection Agency (EPA) Region 6 analyzed ambient air monitoring and meteorological data
to determine if the 1995 ozone season was significantly different than previous summers for El Paso, Beaumont-Pt. Arthur,
Houston, Dallas, and Longview. The meteorological data from selected monitoring sites within these five areas were compared
with the long-term average summer seasonal temperatures, wind speed, and wind direction data. The following is a summation
of findings:
      1.
      2.
      3.
Dallas:
El Paso:
Houston:
      4.    Longview:
Meteorological data from the summer of 1995 were not significantly different than the long term
average.  For Dallas, the summer of 1995 was very similar to the previous summers of 1986 and
1990.  In addition, the ozone exceedances for these three summers were comparable as well. The
summer of 1995 was a little warmer than usual, but similar to the summers of 1982, 1986, 1988,
and 1990.

The summer of 1995 was cooler than average in El Paso.  In addition, wind speeds were higher
than average.

There were more winds from the northeast during the summer of 1995.  In addition, as in 1986 and
1991, there was a higher than average amount of low wind speeds, 0-4 miles per hour (mph).

There were more winds from the northeast during the summer of 1995. In addition, the amount
of resultant wind directions out of the northwest was above average.
      5.    Beaumont:   There were more winds from the northwest during the summer of 1995.
      The analysis of the selected sites shows that the Texas summer of 1995 was not extraordinarily stagnant or hot.  The
El Paso monitors measured higher wind speeds and cooler temperatures which contributed to lower ozone concentrations
recorded in the area.  Also, key wind direction changes impacted the ozone concentrations recorded in Beaumont, Houston,
and Longview, while the summer of 1995 in Dallas was meteorologically similar to 1990 and 1986.

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INTRODUCTION

      The summer of 1995 in Texas produced a significant amount of days in the Houston, Beaumont, Dallas-Fort Worth,
and Longview areas where the ozone National Ambient Air Quality Standards (NAAQS) of 0.124 parts per million were
exceeded.  Concerns about the significant increase in the amount  of  ozone NAAQS exceedance days in major Texas
metropolitan areas were expressed in a Wall Street Journal article of August 9, 1995, entitled "Clouding the Air:  Cities in
Texas Suffer Record Ozone Pollution." These increases in ozone  NAAQS exceedances resulted in the need for an analysis
to determine if the  1995 ozone season was significantly warmer or more stagnant than usual. Data from the following six sites
in five areas were analyzed:

      (1) the Georgia at Cunningham site in Beaumont;
      (2) the Nuestra Drive site in Dallas;
      (3) the El Paso Rim Road and Ascarate Park sites in El Paso;
      (4) the Aldine Mail Road site in Houston; and
      (5) the Gregg County Airport site in Longview.

      Data from these sites were analyzed by the following means:

      (1)   Box Plots and Graphs
      (2)   Meteorologically Adjusted Ozone Trends by Cox and Chu


RESULTS AND DISCUSSION

(1) Box Plots and Graphs

      For each site, box plots were produced displaying June-August ozone concentrations, temperature data, wind speed data,
wind direction data, and other pollutant data.  The measurements date  from the early 1980's to 1995 (Appendix A). Each box
plot displays the 25th to 75th quartile in the shaded rectangle with whiskers extending out to the 99th percentile.  Outliers are
depicted as unshaded boxes. These plots provide a trends analysis of the entire ozone, temperature, wind speed, wind direction,
and other pollutants, summer data sets.  In addition,  each year  of data can be compared to all other years in order  to
determine if a certain year of data comprises a significant anomaly.  For example, the summer of 1995 produced a high number
of days in the Dallas-Fort Worth and Houston  areas where the ozone NAAQS of 0.124 parts per million were exceeded

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(Appendix B). One hypothesis to account for the significant increase in ozone exceedances would be that the summer of 1995
was an anomaly as compared to previous summer meteorological conditions. Preliminary results from examining the wind
speed and temperature data, though, do not support that hypothesis.  As can be seen in the graphs of temperatures above 90
degrees F for the six selected Texas sites, the summer 1995 readings do not appear to be significantly higher than the long term
trend (Appendix C).  In addition, as seen in the wind speed graphs for each site, the percentage of very low wind speeds for
1995 does not appear to be significantly high. Highlights from each site analysis follow below:

Beaumont
o     The monitor recorded a significantly higher amount of resultant wind directions from the northwest quadrant (21%
      versus a  12% long-term average).

Dallas
o     Ozone, nitrogen oxides (NOx), and nitrogen dioxide (NO2) concentrations have significantly increased between  1993
      and 1995 at the Nuestra Drive site.

o     Meteorological conditions and ozone concentrations recorded in the summer of 1995 were very similar to those recorded
      in the summers of 1990 and 1986 at the Nuestra Drive site.

El Paso
o     The Rim Road University of Texas at El Paso (UTEP) and Ascarate Park sites recorded a  significantly lower than
      average amount of hours of temperatures greater than or equal to (>=) 100  degrees F.

o     The Rim Road UTEP and Ascarate Park sites recorded a significantly greater than average amount of hours of high
      wind speeds (>= 10 mph).

o     The Rim Road UTEP site recorded a significantly higher amount of resultant wind directions from  the northeast
      quadrant (30% versus a 13% long-term average).

Houston
o     Ozone and NO2 concentrations have significantly increased between  1993 and 1995 at the Aldine site.

o     The Aldine monitor recorded a sig lificantly higher amount of resultant wind directions from the northeast quadrant
      (38% versus a 22% average).

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o     The Aldine monitor, as in 1986 anH 1991, recorded a higher than average amount of the low wind speeds, 0-4 mph.

Longview
o     Ozone concentrations have significantly increased between 1993 and 1995 at the. Longview monitor.

o     The Longview monitor recorded a significantly higher amount of resultant wind directions from the northeast quadrant
      (32% versus an 18% average). Also, the amount of resultant wind directions out of the northwest quadrant was above
      average (14% versus 8%).

(2) Meteorologically Adjusted Ozone Trends by Cox and Chu

      Also attached to this analysis are graphs by Cox and Chu of the U.S. EPA Office of Air Quality Planning and Standards
which adjust ozone values due to meteorological variations for the following areas:  Baton Rouge, Louisiana, and Beaumont,
Dallas, El  Paso, and Houston, Texas. Meteorological parameters such  as surface temperature, wind speed, relative humidity,
mixing height, and cloud cover are accounted  for in the adjustments for the years 1984-1994. Please reference the plots and
an accompanying article by Cox  and Chu in Appendix D.

CONCLUSION

      This analysis was used to study trends of pollutant concentrations and certain meteorological parameters at specific sites
in Texas ozone nonattainment areas. The analysis has shown, at these sites, that the summer of 1995 was not an extraordinary
stagnant or hot summer (e.g. like the summer of 1980 in Dallas which produced an exceptional amount of hours above 100
degrees F).  Indeed, when viewing the meteorological data graphs in this anal} -is, the distributions of temperatures and wind
speeds recorded during the summer of 1995 have also been recorded in earlier years at these sites.  In addition, this analysis
provides valuable meteorological information  as one examines the change in ozone concentrations between 1995 and 1994.
For instance, the El Paso monitors measured higher wind speeds and cooler temperatures which contributed to lower ozone
concentrations recorded  in  the  area.  Also,  key wind direction changes impacted the  ozone concentrations recorded  in
Beaumont, Houston, and Longview, while the summer of 1995 in Dallas was meteorologically similar to  1990 and 1986.

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APPENDIX A

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t—»
t)
S. 10
a
a
a
a
a
a
a
               a
               a
               a
               a
               a
a
a
a
a
a
a
a
                                    ..



             84
       85
       86
       88
       89      90
          YEflR
91
92
93
94
                                                              95

-------
                            El Paso (6950 Alameda Ave. Ascarate Park) Site
                               B48-141-0023 June-flugust Resultant  Wind Directions
                                                   Percent i i e
  400
  300-
o
I)

CD
O
•o
c
o
4*
3
c
o
D

0

O
  100
   0-
                                             „

              84      85      86       8?      88      89      90      91      92      93      94      95


                                                       YEflR

-------
 0.20



 0.19



 0.18



 0.17



 0.16



 0.15



 0.14



 0. 13



 0.12



 0. 1 1
.
.

 0.10



 0.09H



 0.08



 0.07



 0.06



 0.05



 0.04-



 0.03-



 0.02-



 0.01 •



 0.00-
                                      El Paso  (Rim  Road UTEP) Site
                                  ff4S-141-0037 June-rtugust Ozone Concentrations
                                                99th Percent i le
                                                               a


                                                               8
                                                                     a

                                                                     B
                                                               a

                                                               a
                                                               a

                                                               a

                                                               a


                                                               8

                                                               a
              81
82
83
84
85
86
87
 88

YEfiR
89
90
                               91
                                                                                   92
                                                                     93
                                                                     94
                                                                     95

-------
                                      El Paso (Rim Road UTEP) Site
                                   t-tS-1 41-0037 June-flugust  NOx Concentrations
                                               99th Percent i 1e
  0.6
  8.5
  8.4
x
o
                                                                                  a

                                                                                  a
  8.3
                                                                                              a

                                                                                              a
  8.2 •
                                                                                a
                                                                                a
  8.1 •
  8.8-
                          a
                          a
                          a
                          a
                                       a
                                       a
                                       a
                         a
                         a
                         a
                         a
                         a
                                     a
                                     a
                                     a
                                     a
                                                              i
                                     a
                                     a
                                     a
                                     a
                                     a
                                     a
                                     a
                                                                                                    §
                                                                                                    B
                                     a
                                     a
                                     a
                                     a
                                     a
                                     a
                                           a
                                           a
                                           a
                                           a
—1—
 98
              81
82
83
84
85
86
87
 88

YEflR
89
                                                                           91
                                                             92
                                                                                       93
                                                                          94
                                                                          95

-------
  0. 11
  0.10
  0.09
  0.08
  0.07-
~ 0.06
a
a
nj
  0.05-
  0.04
  0.03-
  0.03
  0.01
  0.00
                      a     a
                                       El Paso (Rim  Road UTEP) Site
                                    ff-»S-1 41-0037 June-fluguat M02 Concentrations
                                                 99th Percent!ie
                      a     a
                                         a      a
                a      a     a     a      a      a
                                                                  a      a
                                                                  a      a
                                       a
                                       a
                                       a

                                       a
                                       a
                                       a
                                                                                                       a
                                                                                                       a
               81    82     83     84    85    86     87
 88

YEflR
89    90    91     98     93    94     95

-------
  0.31
  0.30
  0.89
  0.28
  0.27
  0.26
  0.25
  0.24
  0.23
  0.22
  0.21
  0.20
  0.191
  0.18
~ 0.17
E
0.0. 16
Q.
~ 0.15
o
r 0.14
  0.13
  0.12
  0.11
  0.10
  0.09H
  0.08
  0.07H
  0.06
  0.05
  0.04-
  0.03 •
  0.02 •
  0.01 •
  0.00
                                        El Paso (Rim Road UTEP) Site
                                     B4S-1-H-0037  June-flugust MO  Concentrations
                                                  99th Percenli ie
a
T
      a
      a
      a
      a
 a
 a
 a
 a
 a
a
a
a
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                                             a
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                                                          a
                                                          a
                                                          a
                                                                      a
                                                                      a
a
a
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81     82     83     84     85     86    87     88     89
                                            YEflR
                                                                         90
                                                                               91
                                                          92
                                                         93
                                                  94
                                                  95

-------
  10
E
a

3  5
                                     El Paso (Rim  Road UTEP) Site
                                  tt-fS-1 41 -0037 June-fluqust  CO Concentrations
                                              99th Percentile
                                                                                                 a
                                                                                                 a
                                                                                           a

                                                                                           8

                                                                                           8
                                                                                           a
                                                                                           a
                                                                               a
                                                                               a
                                                                               a
            81
82
                        83
            84
85
86
87
                  88


                 YEflR
89
                        98
                              91
                                    93
                                                                                                 95

-------
0.9
0.8
0.7
                                   El Paso (Rim Road UTEP) Site
                               &48-141-9037 June-fluquat 502 Concentrations
                                           99th PercenLile
0.6
                                   D
                                   a

„ 0.5-
e
a
a.
*^

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o
tn 0.4-







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0.0-

a
a
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81 82 . 83 84 85 86 87 88 89 98 91 92
YEflR














a


a a

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a
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a a
i a |
I 	 ]_
93 94 95


-------
                                      El Paso  (Rim Road UTEP) Site
                                  ff^3 - 14 I -0037 Junc-flugust flmbient  Temperatures
                                                99th Percent i le
  120
  110
  100-
   90
o  80
o
o
O>
o
TJ
I)
(_
3
   70
O


S  60
   50 •
   40
   30
   S0-
                                                                      a
                                                                      a
              a
              a
                           a
                           a
                   3
                   e
                                                                                                         -t-
              81
83
84
85
86
87
 88

YEflR
89
90
91
                                                              93
                                                                                              94
                                                                          95

-------
  30
                                      El Paso (Rim Road  UTEP) Site
                                 B4S-1 41 -0037 June-fluqust Resultant  Uind Speeds
                                               99th Terccntile
|
TJ
O
O
a
en
TJ
c
O
3
D
£. 10
a
a
a
a
a
a
a
a
                                                                                  a
                                                                                  a
                                                                                  a
                                                              a
                                                              a
                                                              a
                                                  a
                                                  a
                                                  a
                                                  a
                                                  a
                                                  a
                                                  a
                                                  a

                                                  a
                                                  a
                                                  a
                                                  a
                                                  a
                                                  a
                                                  a
             81
      83
      84
85
86
87
 88
YEflR
89
90
91
93
                                                                    94
                                                  95

-------
                                     El Paso  (Rim Road UTEP) She
                              B48-1 41 -0037 June-_ftugust Resultant Uind  Directions
                                                  Percent i1e
  408
  300
A
O
O
L
O)
I)
TJ
C
O
O
£200
TJ
C
C
O
3
A
O
K.

  100
   0 •
                                                 a
             81
83    84    85     86
 88

YEflR
                                                             89
90
91
                                                     93    93    94
                                                                                                95

-------
  0.24


  0.23

  0.22


  0.21


  0.20


  0. 19


  0. 18

  0.17


  0. 16


  0.15

  0.14
^\

|0.13
o.

~ 0.12-
i>

o 0.11
N
O
  0.10

  0.09


  0.08

  0.07


  0.06


  0.05

  0.04


  0.03


  0.02

  0.01


  0.00
 a

 a

 a

 a

 a
                        Houston (AJdine Mail  Road) Site
                    1(48-501-0024 June-flugu j t Ozone Concentrations
                                   99th
                               Percent i Ie
                            a

                            a
                                                               a

                                                               a
 a

 a

 a

 a
          a

          a

          a

          a
          a

          a
          a

          a

          a

          a
                   a

                   a

                   a

                   a

                   a
                                                                                          a
                                                                                          a
                                             B

                                             8
                   a
                   a
                                                                        a
                                                                        a

                                                                                          f
85
86
87
88
89
 90

YEflR
                                                                     91
92
                                                                        93
                                                                                 94
                                                                                 95

-------
  0.22

  8.21

  0.28

  0.19

  0. 18

  0. 17

  0. 16

  0.15

  0.1-H
  0.13

^ 0.12
Q.
3-e.li H
X
g 0.10

  0.09

  0.08 -

  0.07 •

  0.06 -

  0.05

  0.04 -

  0.03 •

  0.02-

  0.01 -

  0.00 •
                                       Houston  (Aldine Mail Road) Site
                                     B48-201 -0024 June-flugust  NOx  Concentrations
                                                  99th Percent i ie
         a

         a
                                                                                 a
                                                                                 a
a
a

               85
        86
87
88
89
 90
YEHR
91
92
93
                           94
                                                               95

-------
  0.08
  0.07H
                                      Houston (Aldine  Mail Road) Site
                                    B48 -20 1 -0024  June-fluquat HOE Concentrations
                                                 99th Percent i le
                                                                                                       a

                                                                                                       a
  0.06H
  0.05
(U
o
  0.0-H
  0.03
  0.02^
  0.01 ^
  0.00
                                                                                                       a
                                                                                                       a
                                                                                                       a
                                                                                                       a
                                                                                                       a
                                                                                                       a
                                                                                                       a
                                                                                                       a
                                                                                                       T
               85
86
                                87
88
89
 90

YEflR
                                                                   91
92
93
94
95

-------
                                    Houston (Aldine Mail Road) Site
                                  B43-201-0024 June-fiugust CIO Concentrations
                                              99bh Percent ile
0.17





0.16




0.15




0. 14




0.13





0.12




0.11




0. 10
a
a
a



a
e 0.09-
Q.
a
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0.07-

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0.05-
0.04-
0.03-
0.02-
0.01 -
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85 86 8? 88 89 90 91 92 93 94 95
YEflR

-------
                                      Houston  (Aldine Mail Road) Site
                                    B48-201-0024  June-Ruqust  CO Concentrations
                                                99th  Percentile
                                                                  a

                                                                  a
  4 •
             a
             a
                                       a
                                       a
                                                a
                                                a
                                       a
                                       a
                                       a
e
a
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o
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                           a

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                           a
                           a
                           a
                           a
                           a
                           a
                           a
            85
86
88
89
 90       91

YEflR
                                            93
                                                                                            94
                                                                                95

-------
                                      Houston (Aldine  Mail Road) Site
                                  548-201-0024 June-flugust Hmbient Temperatures
                                                99th Percenti le
  110
                                                          a
                                                          a
                                                          a
  100
                       a
                       a
   90
0
o
o
L
O)
O
TJ
O
L
3
*>
O
L
O
                                        a
                                        a
                                        a
                                        .
                           a
                           a
                           a
                           T
   80
                          „
   70
              a
              a
 a
 a
 a
 a
                                        o
                                        a
                                        a
                                   a
                                   a
                                   a
                                                                      a
                                                                      a
                                                                      a
                                                             a
                                                             a
                                                             a
                                                             ,.
   60-
                           a
                           a
                           a
                           a
                           a
                  a
                  a
                  a
                  a
                  a

                  a
                  o
a
a
a
        1
        a
        a
        a
a
a
a
a
                                                                                                    a
                                                                                                    a
                                                                                                    a
  50-
              85
86
88
                                                89
                                                         90

                                                        YEflR
                                           91
                                                    92
                —r-
                93
                                                                     94
                                                                              95

-------
                                      Houston (Aldine  Mail Road) Site
                                  148-201-0024 June-rtuqust Resultant Wind Speeds
                                                 99th Tercentile
  30
  20
a
•a
o
c
3
a
*>
o
a
a
         a
         a
                                        a
                                        a
                                                 a
                                                 o
                                                 a
                                                 a
  10
          a
          a
          a
          a
          a
          a
          a
                                                                       a
                                                                       a
                           a
                           a
                                                          i
             85
        86
                                        88
89
 90
YEflR
91
92
93
                                                                                                      95

-------
  408
                                      Houston (Aldine Mail Road) Site
                                B4S-201-0824 Junc-fluguab Resultant Uind  Directions
                                                 99tTn Percent i Ic
  300
O
o
o

I
•C
o
£200
73
C
C
o
3
A
O
Q£

  100
              „
                                I
                                   I        I
'


              85
        86
                               S7
88
89
 90

YEflR
91
                                            93
                                                                                                      95

-------
              Longview Site
tt4S~133-000l June-August Ozone  Concentrations
     99th Percentile  Cno data for 1986)
0. 16'
0.15-
0.14
0. 13'

0.18

0. 11 •
0.1.0
~ 0.09 •
Q.
Q.
" 0.08
O
O
£ 0.07-
0.06-
0.05 •
0.04 •
0.03-
0.02-
0.01 •
0.00 •
o
a a
8
a a a a
a a a a a Q a
Q
Q a a aa aag
a §
B ^
a a a a a Q a a a a a a
B














.







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r a a a a a
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a


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' §
80 81 88 83 84 85 86 ST 88 89 90 91 92 93 94 95
                       YEflR

-------
                                                   Longview Site
                                    !HS- I 33-0001  June-fluqu.5 t rimbient  Temperatures
                                          99th  Percentile  (no data for 1986)
  110
  100
                           a
                           a
                           a
                     a
                     a
                     a
                   a
                   a
                   a
                   a
                   a
                   a
                   a
                                                                a
                                                                a
                                                                a
                                                                a
                                                                a
                                                        a
                                                        a
                                                        a
                                                        a
             a
             a
             a
                                  a
                                  a
  90-
                                       ..
o
o
u
CD
o
y
o
o
%
0
  80-
  70-

                     a
                     a
                     a
  60-
       a
       a
       a
       a
       a
       a
                                      a
                                      a
                         a
                         a
 a
 a
 a
 a
 O
 D
a
a
a
a
a
a
a
                               a
                               a
                               a
                               a-
                                                                       ..
                                                          a
                                                          a
                                                                 a
                                                                 a
                                            a
                                            a
                                                                 o
                                                                 a
                                                                           a
                                                                           a
                                                                           a
                                                                           a
                                                                           a
                                                                           a
                                                  a
                                                  a
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                                     a
                                     a
                                     a

                                                                                   a
                                                                                   a
                         a
                         a
                         a
                         o
                   a
                   a
                   a
                   a
                   a
                                      a
                                      a
                                      a
                                      a
                                      a
                                      a
                                      a
                   a
                   a
                   a
                   a
                                                                                         a
                                                                                         a
                                                                                         a
                         a
                         a
                         a
                         a
                         a
                                                                 a
                                                                 a
  50-
               80
81
83
                   84
      85
86
87    88

  YEflR
                                                                      89
                                           90
91
93
                                                        95

-------
  140
  138
  120
  110
  100
a
o
a
tf>
c

3
o
-p
   90
   80
   70
   60
o  50
o
   40
   30
   20

                                                   Longview Site
                                    B48-1S3-0001 June-ftuqust Resultant (Jind Speeds
                                          99th  Percent Me (no data for 1986)

                                                          o     a
                     i     i    i     n
                                                                                   C
               80     81     82    83    84    85     86     87    88    89    90    91    92     93     94    95


                                                            YEflR

-------
                                                   Longview Site
                                  B43-1S3-0001 June-fluqusfc Resultant Uind Directions
                                          93th Percenttle l no data for 1986)
  400
  300
o
o
o

0)
c
0
TJ
C
C
0
I)
(K
                            „     .
  100 •
    0-
                               „

                                                                              ..
                                                                                                I
                                                                                                a
                                                               8
                                                               a

                                                               f
                                                                        I     I
               80    81
83
                                              85
86
88
                                     89
90
91
93
                         94
                         95
                                                             YEflR

-------
APPENDIX B

-------
         Beaumont-Port Arthur O3 Episodes
              # days > NAAQS from 1986-1995
    # days
      86
94
95
                          # days
Source: AIRS
Ozone NAAQS • .124 ppm

-------
                 Beaumont O3 Episodes
               # days > NAAQS from 1980-1995
                      (Site #48-245-0009)
   12

   10

   8

   6
     # days
   0
     80  81  82  83  84  85  86 87 88 89 90 91 92  93  94  95
                           Year
Source: AIRS
Ozone NAAQS » .124 ppm

-------
       Dallas-Fort Worth-Arlington O3 Episodes
              # days > NAAQS from 1980-1995
  25


  20


  15


  10
     # days
     80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95
                           Year
Source: AIRS
Ozone NAAQS • .124 ppm

-------
           Dallas  Nuestra Drive  O3 Episodes
               # days > NAAQS from 1980-1995
                       (Site #48-113-0045)
     # days
   12
   10


   8
   0
     80  81  82  83 84 85 86 87  88  89  90 91  92 93  94  95

                            Year
Source: AIRS
Ozone NAAQS • .124 ppm

-------
   14

   12

   10

   8

   6

   4

   2

   0
     # days
                  El  Paso O3 Episodes
              # days > NAAQS from 1385-1995
      85  86
87  88   89  90   91
            Year
92
93  94
95
Source: AIRS
Ozone NAAQS • .124 ppm

-------
         El Paso (Ascarate  Park) O3 Episodes
               # days > NAAQS from 1980-1995
                      (Site #48-141-0028)
     # days
   12
   10


   8
     80  81  82  83  84  85 86 87 88 89 90  91  92  93  94  95

                           Year
Source: AIRS
Ozone NAAQS • .124 ppm

-------
         El Paso (UTEP Rim  Rd) O3 Episodes
              # days > NAAQS from 1981-1995
                      (Site #48-141-0037)
    # days
     81  82 83  84  85 86  87  88 89  90  91 92  93  94  95
                           # days
Source: AIRS
Ozone NAAQS - .124 ppm

-------
      Houston-Galveston-Brazoria O3 Episodes
             # days > NAAQS from 1985-1995
    # days
                  88
89  90  91
   Year
92   93
94
95
Ozone NAAQS - .124 ppm

-------
             Houston (Aldine) O3  Episodes
               # days > NAAQS from 1980-1995
                      (Site #48-201-0024)
     # days
     80  81  82  83  84 85 86 87 88  89  90  91  92 93 94 95

                            Year
Source.- AIRS
Ozone NAAQS a .124 ppm

-------
                 Longview O3 Episodes
               # days > NAAQS from 1980-1995
                      (Site #48-183-0001)
    # days
   5
                             J	I
     80  81  82  83  84  85  87  88  89  90  91  92 93  94  95

                            Year





no data for 1986
Source: AIRS
Ozone NAAQS « .124 ppm

-------
APPENDIX C

-------
   25



   20



   15



   10
               Beaumont  Site #482 450009
             Ambient Temperature 90-99 degrees F
                            June-August

     % hourly ambient Temp. 90-99 degrees F
   1981 1982 1983 1984 1986 1988 1989 1990 1991 1992 1993  1994 1995

                               Year
                                                                      2.5
   1.5
                                                                      0.5
               Beaumont Site  #482450009
              Ambient Temperature >• 100 degrees F
                            June-August

     % hourly ambient Temp. >• 100 degrees F
    1981 1982 1983 1984 1988 1988 1989  1990 1991  1992 1993 1994  1996

                               Year
                       % of total
1988 and 1987 data captur* did not
m»«t 76% criterion uaad In thU «ntly«l«
Av*rag*% • 13%; 1994% • 7%; 1996% • 14%
                                     Average
                                                                                           % of total
1986 and 1987 data capture did not
moat 76% criterion uted In thla analyala
Average* • 0%; 1994% • 0%; 1996% • 0%
                                     Average %

-------
   100
                   Beaumont  Site  #482450009
                     Resultant Wind Speeds 0-4  mph
                                   June-August

       % hourly resultant wind speeds 0-4 mph
      1981  1982 1984 1986 1988 1989 1990  1991  1992 1993 1994 1995
                                       Year
                             % of total
1983,1986,1987 data capture did not
meet 75% criterion used in this analysis
Average* - 65%; 1994% • 56%; 1996% - 60%
Average %
                                                                                              Beaumont Site #482450009
                                                                                               Resultant Wind Speeds 6-9 mph
                                                                                                         June-August
                                                                                      % hourly resultant wind *peadi 6-9 mph
                                       1981 1982 1984 19S8 1988 1989 1990  1991  1992  1993 1994 1995
                                                              Xsar

                                                    	* ol total  -*- Average *

                                    tBB3.ia8C.1BB7 d«t« uptun did not
                                    ra*«t 78* oilttilon UMd In this U
                                    A»»r«B«* • 30V 1984* • 37V 1S86* - 33*
                                                                                              Beaumont Site #482450009
                                                                                               Resultant Wind Speeds >• 10 mph
                                                                                                         June-August
                                                                                      % hourly resultant wind speeds >- 10 mph
                                                                                     1981  1982 1984 1986 1988 1989 1990 1991 1992 1993 1994 199S
                                                                                                           •rear
                                                                                                               - Average %
                                                                                  1BU.iaU.»a7 liti o«ptun did not
                                                                                  mil 76* CTlmlon UMd In th» «n«ly«u
                                                                                  Artc«g»» • 8V ta>4* - 0V 1BB6* - 7*

-------
               Beaumont Site #482450009
             Resultant Wind Directions NW Quadrant
                            June-August
               Beaumont Site #482450009
             Resultant Wind Directions NE Quadrant
                            June-August
   25


   20


   15


   10
     % hourly resultant wind dir. NW Quad.
    19B1  1982  1984  1986  1988  1989  1990  1991  1992  1994  1995
                               Year
   30

   25

   20

   15

   10

    5
     % hourly resultant wind dir. NE Quad.
    1981  1982  1984  1988  1988  1989  1990  1991  1992  1994  1995
                               Year
                       % ol total
                                     Average
                                                                                             % o< total
                                     • Average %
1983,1986.1987.1893 data capture did not
meet 76% criterion uaed In thla analyala
Average% > 12%: 1994% • 9%; 1995% • 21%
1983.1986.1987.1993 data capture did not
meet 76% criterion uaed in thia analyala
Avenge* • 20%; 1994% - 19%; 1995% - 21%
               Beaumont Site #482450009
             Resultant Wind Directions SW Quadrant
                            June-August
               Beaumont Site #482450009
             Resultant Wind  Directions  SE Quadrant
                            June-August
   50


   40


   30


   20


   10
     % hourly resultant wind dir. SW Quad.
    1981  1982  1984  1986  1988  1989  1990  1991  1992  1994   1996
                               Year
   50

   40


   30


   20


   10
     % hourly resultant wind dir. SE Quad.
    1981  1982  1984  1986  1988  1989  1990  1991   1992  1994  1995
                                Year
                       % o! total
                                     • Average %
                                                                                             % of total
                                      Average %
1983,1986.1987,1993 data capture did not
meet 76% criterion uaed In thla analyaia
Average* • 36%; 1994% • 41%: 1995% - 30%
1983.1986,1987,1993 data capture did not
meet 76% criterion uaed In this analyala
Average* • 32%; 1994% • 30%; 1995% • 28%

-------
   30

   25

   20

   16

   10
         Dallas Nuestra Drive Site #481130045
             Ambient Temperature 90-99 degrees F
                            June-August

     % hourly ambient Temp. 90-99 degrees F
   1980 1981 1982 1983 1984 1986 1988 1989 1990 1991 1992 1993 1994 1995
                               Year
   14

   12

   10

    8

    6

    4
         Dallas  Nuestra Drive Site #481130045
              Ambient Temperature >• 100 degrees F
                            June-August

     % hourly ambient Temp. >- 100 degrees F
   1980 1981 1982 1983 1984 1988 1988 1989 1990 1991 1992 1993 1994 1995
                               Year
                       % of total
                                     Average %
                                                                                            % of total
                                    • Average
19S6 and 1987 data capture did not meet
76% criterion u*ed In thl* analyala.
Average* • 23*; 1994% • 24%; 1996% • 23%
1986 and 1987 data capture did not meet
76% criterion uaed In thla analytla.
Average* • 3%; 1994% • 1%; 1996% • 4%

-------
           Dallas  Nuestra  Drive  Site  #481130045
                    Resultant Wind Speeds  0-4 mph
                                   June-August
      % hourly resultant wind speeds 0-4 mph
    1980 1981 1982 1983 1984 1986 1988 1989 1990 1991 1992 1993 1994 1995
                                       Year
                             % of total
1986 and 1987 data capture did not meet
76% criterion uaed in this analyaia.
Average* - 66%; 1994% - 82%; 1996% - 60%
Average %
                                        60

                                        50

                                        40

                                        30

                                        20

                                        10
                                                                                           Dallas Nuestra Drive Site #481130045
                                                                                                 Resultant Wind Speeds 6-9 mph
                                                                                                           June-Au0uit

                                                                                        % hourly retultant wind (peed* 6-9 mph
                                         1980 1981 1982 1983 1984 1986 1988 1989 1990 1991 1992 1993 1994 199S
                                                                Ytar
                                                                                                      • % of total
                                                                                    1988 ind 1987 dm ciptura did not oiMt
                                                                                    78% criterion uMd In thl« entry*!*.
                                                                                    AMftgct • 37V t9»4% - 32*; 18OT% • 38*
                                                                                                                 • Avcraga %
26


20


15


10


 5
                                              Dallas Nuestra Drive Site #481130045
                                                   Resultant Wind Speeds >• 10 mph
                                                             June-Auauit

                                          % hourly reaulunt wind tp«edi >• 10 mph
                                                                                       1980 1981 1982 1983 1984 1986 1988 1989 1990 1991 1992 1993 1994 1998
                                                                                                              •fear
                                                                                                      - % of total
                                                                                    18SS 
-------
r
                          10

                           8

                           e

                           4
                                 Dallas Nuestra Drive Site #481130045
                                    Resultant Wind Directions  NW Quadrant
                                                    June-August

                            % hourly resultant wind dir. NW Quad.
V..  .
                           1980 1981 1982 1983 1984 1986 1988 1989 1990 1991 1992 1993 1994 1995
                                                       Year
                                                                         30

                                                                         25

                                                                         20

                                                                         15

                                                                         10

                                                                          5
                                    Dallas Nuestra Drive  Site  #481130045
                                        Resultant Wind  Directions NE Quadrant
                                                       June-August

                                % hourly resultant wind dlr. NE Quad.
                              1980 1981 1982 1983 1984 1988 1988 1989 1990 1991 1992 1993 1994 1995
                                                           Year
                                               % ol total
                                                            • Average
                                                                                                                    • % of total
                                                                • Average
                       1885 and 1987 data capture did not meet
                       76% criterion uaed In thla analyala.
                       Average* - 6%; 1984% - 2%: 1996% • 6%
                           1985 and 1987 data capture did not meet
                           76% criterion uaed In thla analytla.
                           Average* • 12%: 1994% • 11%; 1995% • 13%
                          80
                          60
                          40
                          20
                                 Dallas Nuestra Drive Site #481130045
                                    Resultant Wind Directions SW Quadrant
                                                    June-August

                             % hourly resultant wind dir. SW Quad.
                           1980 1981 1982 1983 1984 1986 1988 1989 1990 1991 1992 1993 1994 1995
                                                       Year
                              60

                              50

                              40

                              30

                              20

                              10
                                    Dallas Nuestra  Drive Site  #481130045
                                        Resultant Wind Directions SE Quadrant
                                                        June-August

                                % hourly resultant wind dir. SE Quad.
                              1980 1981 1982 1983 1984 1986 1988 1989 1990 1991 1992 1993 1994 1996
                                                           Year
                    	% of total


1986 and 1987 data capture did not meet
76% criterion uaed In thla analyala.
Average% • 62%; 1994% - 37%; 1996% • 44%
                                                            • Average %
                                                                                                                     % of total
                                                                                              1986 and 1987 data capture did not meet
                                                                                              76% criterion uaed In thla analyala.
                                                                                              Average% • 31%: 1994% - 60%; 1995% • 38%
                                                                 Average %

-------
  30
  25
  20
  15
  10
       El Paso (Ascarate Park) Site #481410028
             Ambient Temperature 90-99 degrees F
                           June-August
     % hourly ambient Temp. 90-90 degrees F
   1986
          1988   1989
                        1990
1991
Year
                                      1992
                                            1993   1994   1995
                                        16
                                        14
                                        12
                                        10
                                        8
                                        6
                                        4
                                        2
                                            El Paso (Ascarate Park)  Site  #481410028
                                                  Ambient Temperature >• 100 degrees F
                                                                June-August
                                          % hourly ambient Temp. >• 100 degrees F
                                                                       1986    1988    1989
                                                                                           1990
1991
Year
                                                                                                         1992   1993   1994
                                                                                                                              1995
                       % of total
                                    • Average
                                                                                          % ot total
                                                                         • Average %
1984.19BS.1987 data capture did not
meet 76% criterion uaed In thli analyal*
Average* • 23%; 1994% • 28%; 1996% • 24%
                                     1984.198S.1987 data capture did not
                                     meet 76% criterion uaed In thl« analyil*
                                     Average% • 6%; 1994% • 16%; 1996% • 2%

-------
        El Paso  (Ascarate Park) Site #481410028
                    Resultant Wind Speeds  0-4 mph
                                  June-August
      % hourly resultant wind speeds 0-4 mph
    1986    1988
                                                               1994
                           1995
                            % of total
1984.1986,1987 data capture did not
meet 75% criterion used in thia analyaia
Average* • 56%; 1994% • 71%; 1995% - 46%
Average %
                                       60


                                       40


                                       30


                                       20


                                       10
                                                                                        El Paso (Ascarate Park) Site #481410028
                                                                                               Resultant Wind Speeds 5-9 mph
                                                                                                         June-AuQuat

                                                                                      % hourly raaultant wind ipeed* 6-9 mph
                                                                                     1986  1988   1989   1990   1991   1992  1993   1994   1996
                                                                                                    - % of total
                                                                                  1984.1900.1967 DlU otptur* dM not
                                                                                  iM«t TSfc crlurlon uttd In thlt a
                                                                                  Anr«Q** - 36V 1M4% - SO*: 1990* • 41*
                                                                                                               - Awag* %
  El Paso (Ascarate Park) Site #481410028
         Resultant Wind Speeds >• 10 mph
                  June-August

% hourly resultant wind tpeedi >- 10 mph
                                                                                     1986   1988   1888   1990
                                                                                                            1991
                                                                                                            •fear
                                                                                                    - % of total
                                                                                  1U4.19U.t98T d«u ciplun did not
                                                                                  nw«l 76% criterion uMd In this antl
                                                                                  Anrtgi* • 7V 1W4* - 3v »H« • 14%
                                                                                                                 1892   1983   1894   1986
                                                                                                               - Awrag*

-------
r
                          30

                          25

                          20

                          15

                          10

                           5
                              El  Paso  (Ascarate Park) Site  #481410028
                                    Resultant Wind Directions NW Quadrant
                                                   June-Auguat

                            % hourly resultant wind dir. NW Quad.
                           1986     1988     1989     1990     1991     1993
                                                       Year
                                                                           1094
                                                                                   1996
       El Paso  (Ascarate Park) Site #481410028
             Resultant Wind Directions NE Quadrant
                            June-August
     % hourly resultant wind dir. NE Quad.
                                                                                                1988
                                                                                                        1988
                                                                                                                 1989
                            1990     1991
                                Year
1993
        1994
                1995
                                                of total   —•— Average %
                                                                                                                    % of total
                                      Average %
                       1984,1986.1887.1892 data captura did not
                       mtat 76% criterion u»ed In thll «n»lyll»
                       Average* - 18%: 1984% - 20%; 1986% - 12%
1984.1986,1987.1992 data capture did not
meat 76% criterion u«ed In thli analyala
Average* - 20%; 1994% • 23%; 1996% • 24%
                          30

                          25

                          20

                          15

                          10

                           5
                              El  Paso  (Ascarate  Park) Site #481410028
                                    Resultant Wind Directions SW Quadrant
                                                   June-August

                            % hourly resultant wind dir. SW Quad.
                           1988     1988     1989     1990     1991     1993     1994     1995
                                                       Year
                                                                                                50
   40
   30
   20
   10
       El  Paso  (Ascarate Park) Site #481410028
             Resultant Wind Directions SE Quadrant
                             June-August

     % hourly resultant wind dir. SE Quad.
                                                                                                 1986
                                                                                                         1988
                                                                                                                 1989
                            1990     1991
                                Year
                                                                                                                                         1993
                                                    1994
                                                            1995
                                           	% of total   —•— Average %
                                                                                                                    % of total
                                      Average %
                       1984,1986,1987.1992 data captura did not
                       meat 76% criterion uied In thll analyils
                       Average* • 17%; 1994% - 8%; 1996% • 26%
1984.1985,1987.1992 data captura did not
meet 76% criterion uaad In thll analyala
Average* • 46%; 1994% • 43%; 1995% • 39%

-------
   40
  30
   20
   10
      El Paso (Rim Road UTEP)  Site #481410037
             Ambient Temperature 90-99 degrees F
                           June-August

     % hourly ambient Temp. 90-99 degrees F
   1982 1983 1984 1986  1988 1989  1990  1991  1992  1993  1994  1995
                               Year
      El Paso (Rim Road UTEP) Site #481410037
             Ambient Temperature >- 100 degrees F
                           June-August
     % hourly ambient Temp. >• 100 degrees F
   1982 1983 1984 1986 1988 1989  1990 1991  1992 1993 1994 1996
                               Year
                      % of total
                                    • Average
                                                                                          % of total
                                    • Average %
1981.1986.1987 data capture did not
meet 76% criterion uaed In thla analyala
Average% • 24%t 1994% • 37%; 1996% • 26%
1981.1986,1987 data capture did not
meet 76% criterion uaed In thla analyala
Average% • 6%; 1994% • 11%; 1996% • 1%

-------
       El Paso  (Rim Road  UTEP) Site #481410037
                    Resultant Wind Speeds 0-4  mph
                                  June-August
      % hourly resultant wind speeds 0-4 mph
    1982  1983  1984  1986 1988  1989  1990  1991  1992  1993  1994  1995
                                      Year
                            % of total
1981,1986.1087 data capture did not
meet 75% criterion used in this analysis
Average* • 37%; 1994% - 31%; 1995% - 16%
Average %
                                       TO
                                       60
                                       so
                                       40
                                       30
                                       20
                                       10
                                                                                      El Paso (Rim Road UTEP) Site #481410037
                                                                                               Resultant Wind Speeds 6-9 mph
                                                                                                        June-August
                                                                                      % hourly retultint wind ipeeda 5-9 mph
                                        1982  1983 1984  1986  1988  1989 1990 1991 1992 1993 1994 1996
                                                              •fear
                                                                                                 	% of total

                                                                                  igei.igae.iga7 dm c«piur« tu not
                                                                                  nw«t 7B% criterion uwd In thU inirytl*
                                                                                  AMr>g«% • 82V 1994* - 87%: 1896* - 69*
                                                                                                               • Average %
30
25
20
IS
10
                                          El Paso (Rim Road UTEP) Site #481410037
                                                  Resultant Wind Speeds >• 10 mph
                                                           June-August
                                         % hourly reiultant wind ipeedt >• 10 mph
                                                                                    1982 1983 1984 1986  1988  1989  1990 1991  1992 1993 1994 199S
                                                                                                           toar

                                                                                                 	% of total   — Average %

                                                                                  18811908.1887 Hit! ctptun dM not
                                                                                  root 78% orlmlon uMd In thU «nity«l«
                                                                                  Anrig>% - tlV 1994* - Q%: 1S96* - 28%

-------
      El Paso (Rim Road UTEP) Site #481410037
             Resultant Wind Directions NW Quadrant
                            June-August
     % hourly resultant wind dir. NW Quad.
   1082 1983 1984 1986 1988 1989 1990  1991 1992  1993  1994  1995
                               Year
                                                                       36
                                                                       30
                                                                       25
                                                                       20
                                                                       15
                                                                       10
                                                                        5
      El Paso (Rim Road UTEP) Site #481410037
             Resultant Wind Directions NE Quadrant
                            June-Auguat
     % hourly resultant wind dir. NE Quad.
   1982 1983 1984 1988 1988 1989  1990  1991  1992  1993  1994  1996
                               Year
                       % of total
                                    • Average
                                                                                            % ol total
                                     Average %
1981.1986.1967 dmti capture did not
meet 76% criterion used In this analyala
Avenge* • 31%; 1994% • 30%; 1996% • 21%
1981.1986.1987 dill capture did not
meet 76% criterion uaed In thla analyala
Average% - 13%; 1994% • 11%; 1995% - 3O%
   20
   15
   10
      El Paso (Rim Road UTEP) Site #481410037
             Resultant Wind Directions SW Quadrant
                            June-Auguat
     % hourly resultant wind dir. SW Quad.
   1982 1983 1984 1988 1988 1989 1990  1991  1992  1993  1994  1995
                               Year
   70
   60
   50
   40
   30
   20
   10
      El Paso (Rim Road UTEP) Site #481410037
             Resultant Wind Directions SE Quadrant
                            June-August
     % hourly resultant wind dir. SE Quad.
   1982 1983 1984 1988 1988 1989  1990  1991  1992  1993  1994  1996
                               Year
                       % ol total
                                    • Average %
                                                                                            % ol total
                                     Average %
1981.1986.1987 data capture did not
meet 76% criterion uaed In thia analyaia
Average* - 12%; 1994% - 9%; 1996% • 16%
1981.1986.1987 data capture did not
meet 76% criterion uaed In thla analyaia
Average* • 46%; 1994* - 60%; 199S* • 35*

-------
  30

  25

  20

  16

  10

    5
      Houston Aldine Mail Road Site #482010024
             Ambient Temperature 90-99 degrees F
                           June-August

     % hourly ambient Temp. 90-09 degrees F
   198B
           1988
                   1989
1990    1991
    Year
                                          1992
                                                  1994
                                                          199S
                       % of total
1980.1987,1993 data capture did not
meet 76% criterion used In thla analyala
Average* • 18%; 1994% • 13%; 1996% • 18%
                                    Average %
                                           2.6


                                             2


                                           1.6

                                             1


                                           0.6
                                               Houston Aldine  Mail Road Site #482010024
                                                      Ambient Temperature >• 100 degrees F
                                                                    June-August

                                              % hourly ambient Temp. >• 100 degrees F
                                                                       1986     1988     1989    1990
                                                                                                      1991
                                                                                                              1992
                                                                                                                      1994
                                                                                                                              1996
                                                                                                  Year
                                                                                          % of total
                                         19S8.1987.1993 data capture did not
                                         meet 76% criterion used In thla analysis
                                         Average% • 1%; 1994% • O%: 1996% - 0%
                                                                             Average %

-------
   80
       Houston Aldine Mail Road  Site  #482010024
                    Resultant Wind Speeds 0-4 mph
                                  June-August

      % hourly resultant wind speeds 0-4 mph
   40
   20
    1986
1988
1989
1990      1991
     Year
1992
1994
                                                                       1995
                            % of total
1986,1987,1993 data capture did not
meet 75% criterion used in this analyaia
Average* - 81%; 1994% • 64%; 1996% - 87%
                               Average
                                                                      60


                                                                      40


                                                                      30


                                                                      20


                                                                      10
                                                                                      Houston Aldine Mail Road Site #482010024
                                                                                               Resultant Wind Speeds 5-9 mph
                                                                                                        Jura-Auguat

                                                                                      % hourly reaultant wind apoeda 5-9 mph
                                                                       1986   1988   1989    1990
                                                                                                1991
                                                                                                       1982
                                                                                                             1994
                                                                                                                   1996
                                                                                                           \tear
                                                                                                 	% oi total


                                                                                  19e6.1987.1093 dm captura did not
                                                                                  m«t 70% crlttrlon uMd In this •nBtyila
                                                                                  Araragl* - 36%t 18*4% • 42V 1996* - 29*
                                                                                                              - Awrag* %
 Houston Aldine Mail Road Site #482010024
         Resultant Wind Speeds >• 10 mph
                   June-Auguat

% hourly reaultant wind ipeadt » 10 mph
                                                                                    1986
                                                                                          1988
                                                                                                 1989
                                                                                                       1990    1991
                                                                                                          tbar
                                                                                                                    1992
                                                                                                                          1994
                                                                                                                                 199S
                                                                                                 	% o« total  —— Avorao* %
                                                                                  198e.ig87.1M3 d.u c«ptu» did not
                                                                                  iM«t 76* eilurlon uMd In trill 
                                                                                  AMt«g«* - 4%: 1994* - 6»; «96* - 3*

-------
   30

   25

   20

   15

   10

    5
      Houston  Aldine Mail Road Site #482010024
             Resultant Wind Directions NW Quadrant
                            June-August

     % hourly resultant wind dlr. NW Quad.
   1986    1988    1989    1990    1991     1992
                               Year
                                                   1994
                                                           1996
                                                Houston Aldine  Mail  Road  Site #482010024
                                                       Resultant Wind Directions NE Quadrant
                                                                      June-August
                                               % hourly resultant wind dir. NE Quad.
                                                                        1988
                                                                                1988
                                                                                        1989
                                                                     1990     1991
                                                                         Year
                                                                                                                1992
                                                                                                                        1984
                                                                                                                                1995
                       % of total
                                    • Average %
                                                                                            * of total
                                                                               Average
198S.1887.iaQ3 data capture did not
meet 76% criterion u«ed In this analyala
Average* • 14%; 1994% - 6%; 1996% • 11%
                                          1986.1987.1993 data capture did not
                                          meat 76% criterion uaed In this analyaia
                                          Average% • 22%: 1994% - 21%; 1996% - 38%
   40
   30
   20
   10
      Houston Aldine Mail Road Site  #482010024
             Resultant Wind Directions SW  Quadrant
                            June-August

     % hourly resultant wind dir. SW Quad.
   1988
           1988
                   1989
1990    1991
    Year
                                           1992
                        1994
                                                           1995
                                            50


                                            40


                                            30


                                            20


                                            10
                                                Houston  Aldine Mail  Road  Site  #482010024
                                                       Resultant Wind Directions SE  Quadrant
                                                                      June-August

                                               % hourly resultant wind dir. SE Quad.
                                                                        1986
                                                                                1988
                                                                                        1989
1990    1991
    Year
1992
                                                                                                                        1994
1996
                       % of total
                                    • Average %
                                                                                            % of total
                                                                              • Average %
1986.1987.1993 data capture did not
meet 76% criterion ueed In thie analyaia
Average% • 30%; 1994% • 36%: 1996% • 22%
                                          1986,1987.1993 data capture did not
                                          meet 76% criterion uaed In thli analyaia
                                          Avenue* • 36%: 1994% • 37%; 1996% • 29%

-------
                                                                                                                                              ~l
                Longview Site #481830001
             Ambient Temperature 90-99 degrees F
                    June-August (no data for 1986)
     % hourly ambient Temp. 90-90 degrees F
                                                Longview  Site  #481830001
                                             Ambient Temperature >• 100 degrees F
                                                    June-August (no data tor 1986)

                                    % hourly ambient Temp. >* 100 degrees F
                                                                                                  V
   1980 1981  1982 1983 1984 1988 1989 1990  991 1992 1993 1994 1995
                               Year
                                  1980 1981  1982  1983 1984 1988  1989 1990 1991  1992  1993 1994 1995
                                                               Year
                   	% of total
• Average %
                                                                                           % of total
                                                                                                         Average
1986 and 1987 data capture did not meet
76% criterion uaed In Ihl» analytli.
Average* • 21%; 1994% • 21%; 1996% • 21%
                                198' and 1987 data capture did not meet
                                76% criterion used In thla analyala.
                                Average* • 2%; 1994% • 0%; 1996% • 4%

-------
                    Longview Site  #481830001
                     Resultant  Wind  Speeds 0-4  mph
                          June-August (no data for 1986)
      % hourly resultant wind speeds 0-4 mph
    1980 1981  1982 1983 1984 1988 1989  1990  1991 1992 1993  1994  1995
                                       Year
                             % of total
1986 and 1987 data capture did not meet
75% criterion used in this analysis.
Average% . 68%; 1994% - 76%; 1996% - 70%
Average %
                                                                                                  Longview Site #481830001
                                                                                                  Resultant Wind Speeds 6-9 mph
                                                                                                     June-Auguat (no data for 1988)

                                                                                         % hourly reaultant wind apeeda 5-9 mph
40

30
20
10
n
\ /\ /^^ X\ 	
v ^/ *- ' \ '
!- - \.
. .. 	 	
-. -.. . __ 	 	
                                                                                       1980 1981 1982 1983 1984 1988 1989 1990 1991 1992 1993 1994 1996
                                                                                                       - % of total
                                                                                     1Q8B and 1887 data capture did not ra*«t
                                                                                     76* criterion mad In IhU analytic
                                                                                     Avtriga* • MV 1894% • 29%: 18881k • 27%
                                                   Longview Site #481830001
                                                   Resultant Wind Speeds >• 10 mph
                                                       Juna-Auguat (no data for 1986)

                                           i hourly reaultant wind apeeda »• 10 mph
                                                                                       1980 1981 1982 1983 1984 1988 1989 1990 1991 1992 1993 1994 1990
                                                                                                              \fcar
                                                                                                       • % of total
                                                                                     1996 and 1887 data capture did not naat
                                                                                     76% criterion uaad In thla anafyala.
                                                                                     Anraga* - 4fc 1884* • 0V 1888* - 3*
                                                                                                                  - Average %

-------
   16
   14
   12
   10
    8
    6
    4
    2
                Longview Site  #481830001
             Resultant Wind Directions NW Quadrant
                     June-August (no data lor 1986)
     % hourly resultant wind dlr. NW Quad.
   1980 1981 1982  1983 1984 1988 1989 1990 1991 1992  1993 1994 1995
                                Year
   35
   30
   25
   20
   15
   10
    6
                Longview Site #481830001
             Resultant Wind Directions NE Quadrant
                     June-August (no data lor 1986)
     % hourly r. aultant wind dlr. NE Quad.
   1980 1981 1982 1983 1984 1988 1989 1990  1991 1992 1993 1994  1995
                                Year
                       • % of total
                                      Average
                                                                                             • % of total
                                     • Average
1985 and 1987 d«U capture did not meet
76% criterion used In thl* analyale.
Average% • 8%; 1994% - 6%: 1995% - 14%
1985 and 1987 data capture did not meet
76% criterion tiled In thla analyili.
Average% • 18%: 16 14% - 21%: 1995% - 32%
                Longview Site #481830001
             Resultant Wind Directions SW Quadrant
                     June-August (no data for 1986)
     % hourly resultant wind dir. SW Quad.
    19BO 1981 1982 1983 1984 1988 1989 1990  1991 1992 1993  1994 1995
                                Year
                                                                         60
                                                                         50
                                                                         40
                                                                         30
                                                                         20
                                                                         10
                Longview Site #481830001
              Resultant Wind Directions SE Quadrant
                     June-August (no data for 1986)
     % hourly resultant wind dlr. SE Quad.
    1980 1981 1982 1983 1984 1988 1989 1990  1991 1992 1993 1994 1996
                                Year
                        % of total
                                      Average
                                                                                              % of total
                                     • Average
1985 and 1987 data capture did not meet
76% criterion uaad In thla analyiii.
Average% • 33%; 1984% • 36%; 1995% • 28%
1986 and 1987 da « capture did not meet
75% criterion uied In thla analysis.
Avorage% • 41%: 1994% • 39%: 1996% • 28%
                                                                                                                                                  _

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APPENDIX D

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             BATON ROUGE OZONE TRENDS
     95 TH PERCENTILE—DAILY MAXIMUM 1 HOUR (MAY-OCT)
  280 J
  250:
GQ
Q_
LJ
o
M
O
   190^
   160:
   130
   100:
   70-'
ACTUAL
ADJUSTED
95% CONF
                                     TREND (%/YR): 0.2
                                          STD ERR: 0.3
                                        ...
       1984 1985 1986  1987 1988 1989 1990 1991 1992 1993 1994

                            YEAR

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          BATON ROUGE MODEL PERFORMANCE
     95 TH PERCENTILE—DAILY MAXIMUM 1 HOUR (MAY-OCT)
QQ
CL
LJ

O
M
O
  280 4
  250-
  22CH
  190:
160-
   130:
   100:
   70:
        ACTUAL
        MODELED
        95% CONF
                                     TREND (%/YR): 0.2
                                         STD ERR: 0.3
                                   • i i i I i i i i I i i i i j r r i
       1984 1985 1986  1987 1988 1989 1990 1991 1992 1993 1994

                            YEAR

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             BATON  ROUGE OZONE TRENDS
     95 TH PERCENTILE—DAILY MAXIMUM 3 HOUR (MAY-OCT)
CD
CL
Ld
o
M
O
  280 -\
  250:
  22°
   190:
   160-
   130-
   100:
   70:
ACTUAL
ADJUSTED
                                     TREND (%/YR):  0.9
                                          STD ERR: 0.2
         I I 1 I
                               T I I I I
                                               I I I I I I
       1984 1985 1986 1987 1988  1989 1990 1991  1992 1993  1994

                            YEAR

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          BATON ROUGE MODEL PERFORMANCE
     95 TH PERCENTILE—DAILY MAXIMUM 8 HOUR (MAY-OCT)
  280 J
  250:
  220 ]
DQ
Q_
LJ

o
M
O
160
   130-
   100-
   70J
        ACTUAL
        MODELED
        95% CONF
                                    TREND (%/YR):  0.9
                                         STD ERR: 0.2
        1 I I t TllTII|li1lllill|llit|l
                                     I I I I I I I I I I I I
                                               1 I
      1984 1985 1986 1987  1988 1989 1990 1991  1992 1993 1994

                            YEAR

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             BEAUMONTJX OZONE TRENDS
     95 TH PERCENTILE—DAILY MAXIMUM 1 HOUR (MAY-OCT)
  280 -I
  250:
  220 -I
CD
Q_
O
M
O
   160-
   1301
   100i
   70 i
ACTUAL
ADJUSTED
95% CONF
                                     TREND (%/YR): 0.4
                                         STD ERR: 0.3
      1984 1985 1986 1987 1988 1989 1990 1991 1992 1993 1994

                            YEAR

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          BEAUMONT,TX MODEL PERFORMANCE
     95 TH PERCENTILE—DAILY MAXIMUM 1 HOUR (MAY-OCT)
GO
CL
Ld
o
M
O
  280-I
  250:
  220 ^
   1901
   160:
   130-
   100
   70-
ACTUAL
MODELED
95% CONF
                                     TREND (%/YR):  0.4
                                         STD ERR: 0.3
                    • i • • T • i • • • • i • • • • I • • • • i • • • • i • •
      1984 1985 1986 1987 1988 1989 1990  1991  1992 1993 1994

                            YEAR

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             BEAUMONTJX OZONE TRENDS
     95 TH PERCENTILE—DAILY MAXIMUM F HOUR (MAY-OCT)
QQ
Q_
LJ

o
M
O
  280 -\
  250:
  2201
   1901
160:
   130
   100-
   70:
         ACTUAL
         ADJUSTED
         95% CONF
                                     TREND (%/YR): 0.5
                                         STD ERR: 0.3
        r i r r i I i i I i I t ) i i i i i iiiii i i i i i ii iiiiiii i i i i t i i i i i i I T i

      1984 1985 1986 1987 1988 1989 1990 1991 1992 1993 1994

                            YEAR

-------
          BEAUMONTJX MODEL PERFORMANCE
     95 TH PERCENTILE—DAILY MAXIMUM 8 HOUR (MAY-OCT)
GO
OL
LJ
o
M
O
  280 -I
  250:
  220 -1
   190 i1
   160:
   130
   100-
   70-
ACTUAL
MODELED
95% CONF
                                    TREND (%/YR): 0.5
                                         STD ERR: 0.3
                      i i i
      1984 1985 1986 1987 1988 1989 1990 1991 1992 1993 1994

                            YEAR

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                 DALLAS OZONE TRENDS
     95 TH PERCENTILE — DAILY MAXIMUM 1 HOUR (MAY-OCT)
CD
Q.
LJ

O
M
O
  280 -j
  250:
  2201
   190-
160-
   130:
   100
   70:
         ACTUAL
         ADJUSTED
         95% CONF
        I ' ' ' ' I T ' ' '
                                      TREND (%/YR): -1.8
                                          STD ERR:  0.2
                                          i i i i i i I
       1984 1985 1986 1987 1988 1989 1990  1991 1992 1993 1994

                             YEAR

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             DALLAS MODEL PERFORMANCE
     95 TH PERCENTILE—DAILY MAXIMUM 1  HOUR (MAY-OCT)
DQ
DL
O
M
O
  280-I
  250-
  220 ^
   190^
   160
   130-
   100-
   70-
ACTUAL
MODELED
95% CONF
                                     TREND (%/YR): -1.8
                                          STD ERR:  0.2
              T
        -J-I—T i i | i i i i | i i i i
       1984 1985 1986 1987 1988  1989 1990 1991  1992 1993 1994

                            YEAR

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                 DALLAS OZONE TRENDS
      95 TH PERCENTILE—DAILY MAXIMUM 3 HOUR (MAY-OCT)
CD
CL
Ld

O
M
O
   280 -\
  250:
   220 H
   190
160
   130:
   100J
   70:
ACTUAL
ADJUSTED
95% CONF
                                   TREND (%/YR): -1.5
                                        STD ERR:  0.2
             |-r i i i | i i i i
                                     i i i
       1984 1985  1986 1987  1988 1989 1990 1991 1992 1993 1994

                             YEAR

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             DALLAS MODEL PERFORMANCE
     95 TH PERCENTILE—DAILY MAXIMUM 8 HOUR (MAY-OCT)
CD
CL
O
M
O
  280 J
  250:
  220 ^
   190
   160:
   130:
   100:
   70-
ACTUAL
MODELED
95% CONF
TREND (%/YR): -1.5
     STD ERR:  0.2
        riiiijiiitiiiiiiii *| i i i i I i i i i iiiii ii ii i I I i i i I r i T T |^

      1984 1985 1986  1987 1988 1989 1990 1991 1992 1993 1994

                            YEAR

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                EL PASO OZONE TRENDS
     95 TH PERCENTILE—DAILY MAXIMUM 1  HOUR (APRIL-OCT)
CD
Q_
Ld

O
M
O
   280 J
  250:
  2201
   1901
160:
   130:
   100:
   70-
         ACTUAL
         ADJUSTED
         95% CONF
                                      TREND (%/YR): -0.6
                                          STD ERR:  0.3
        j i r iiriiiiiiiiiiiiiiiiiiijtiiiiiiiiiiifiiiiii i i i T i |

       1984 1985  1986 1987  1988 1989 1990 1991 1992 1993 1994

                             YEAR

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             EL PASO MODEL PERFORMANCE
     95 TH PERCENTILE—DAILY MAXIMUM 1 HOUR (APRIL-OCT)
QQ
Ld
o
M
O
  280 -I
  250:
  220 ^
   190^
   160:
   130:
   100-
   70-
ACTUAL
MODELED
95% CONF
                                     TREND (%/YR): -0.6
                                          STD ERR:  0.3
       1984 1985 1986 1987 1988 1989 1990 1991 1992 1993 1994

                            YEAR

-------
                EL PASO OZONE TRENDS
     95 TH PERCENTILE—DAILY MAXIMUM 8 HOUR (APRIL-OCT)
QQ
Q_
Ld

O
M
O
  280
  250-
  2201
   190-
160
   130:
   100
   70:
         ACTUAL
         ADJUSTED
         95% CONF
                                      TREND (%/YR): -1.0
                                          STD ERR:  0.3
            y\
       1984 1985  1986 1987 1988 1989 1990 1991 1992 1993 1994

                             YEAR

-------
            EL PASO MODEL PERFORMANCE
     95 TH PERCENTILE—DAILY MAXIMUM 8 HOUR (APRIL-OCT)
m
CL
O
M
O
  280 -I
  250:
  220 ^
  190
   160-
   130:
   100:
   70 H
ACTUAL
MODELED
95% CONF
       ^^====^-4-=
                                    TREND (%/YR): -1.0
                                         STD ERR:  0.3
      1984 1985 1986 1987  1988 1989 1990 1991  1992 1993 1994

                            YEAR

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                HOUSTON OZONE TRENDS
     95 TH PERCENTILE—DAILY MAXIMUM 1  HOUR (MAY-OCT)
CD
CL
UJ

O
M
o
  280 -I
  250:
  220 1
   1901
160
   130-
   100-
   70-
         ACTUAL
         ADJUSTED
         95% CONF
                                     TREND (%/YR): -1.8
                                          STD ERR:  0.3
        I I I I I |IIII|1III|IIII|IIII|II<1|IIII|I1II|IIIIIII1IT

       1984 1985 1986 1987 1988  1989 1990 1991  1992 1993 1994

                            YEAR

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            HOUSTON MODEL PERFORMANCE
     95 TH PERCENTILE—DAILY MAXIMUM 1 HOUR (MAY-OCT)
00
Q_
Ld

O
M
O
  280 -I
  250:
  220 :
   190-
160:
   130-
   I00:
   70:
        ACTUAL
        MODELED
        95% CONF
                                     TREND (%/YR): -1.8
                                         STD ERR: 0.3
      1984 1985 1986 1987 1988 1989 1990 1991 1992 1993 1994

                            YEAR

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                HOUSTON OZONE TRENDS
     95 TH PERCENTILE — DAILY MAXIMUM 8 HOUR (MAY-OCT)
GO
GL
Ld
o
M
O
  280 -\
  250:
  220 H
   1901
   160:
   130-
   100:
   70-
ACTUAL
ADJUSTED
95% CONF
                                     TREND (%/YR): -1.5
                                          STD ERR:  0.3
        I ' ' ' ' I ' ' r ' I ' ' ' ' I ' ' ' ' I ' ' ' ' I ' ' ' ' I ' ' ' ' I ' ' ' ' I ' ' ^' 1^^ T T |

       1984 1985 1986 1987 1988 1989 1990 1991 1992 1993 1994

                            YEAR

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            HOUSTON MODEL PERFORMANCE
     95 TH PERCENTILE—DAILY MAXIMUM 8 HOUR (MAY-OCT)
oo
OL
UJ
o
M
O
  280 -I
  250:
  220-
   190
   160:
   100
   70
ACTUAL
MODELED
95% CONF
                                     TREND (%/YR): -1.5
                                         STD ERR:  0.3
        I ' ' ' ' I ' ' ' ' I ' ' ' ' I T^^ i
      1984 1985 1986 1987 1988 1989 1990  1991  1992 1993  1994

                            YEAR

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Meteorologically Adjusted Ozone Trends In Urban Areas:
A Probabilistic Approach
William M. Cox and Shao-Haag Chu
U.S. Environmental Protection Agency
Technical Support Division.  MD-14
Research Triangle Park. NC 27711
ABSTRACT

       A method has been developed that explicitly accounts for the effect of meteorological
fluctuations on the annual distribution of (round level ozooe in urban areas.  The model
includes a trend component that adjusts the maul rate of change in ozone for concurrent
impacts of meteorolofical conditions. Including surface temperature and wind speed.  The
model was applied osiog available data from 23 eastern U.S. urban areas where ozone levels
frequently exceed the National Ambient Air Quality Standard. .The results suggest that the
meteorologically adjusted 99th perccntile of ozone is deaeasiflf in most urban areas over the
period  from  I9SI through 1990.  The median rate of change was -I.I percent per year.
indicating that ozone levels have decreased apptoilmately 10 percent over this time period.
Trends estimated by Ignoring the meteorological touTMMiH appear to underestimate the rate
of improvement in ozone primarily because of the uneven year-to-year distribution of
meteorological conditions favorable to ozone.
INTRODUCTION

      Meteorological conditions, including daily temperature and wind speed, are known1'* •
to play an important role in determining the severity of ground-level ozone concentrations.  '
Because annual variations in meteorological conditions can be substantial, year-to-year
fluctuations in annual ozone statistics can also be quite large. The effect of SK* rotations Is
lo mask any long-term trends*4 in ozone that might reasonably be related; to changes in
precursor emissions (VOC, NO.).
                                                                  ••  •       i<
      A method has been developed that explicitly accounts for the effect of yearly
meteorological fluctuations on the annual frequency distribution of ground-level ozone levels.
The method is based on a probability model in which the frequency distribution of ozone is
described in terms of daily meteorological parameters and a  trend component.  The parame-
ters are estimated using the method of maximum likelihood in which measured dally
maximum ozone levels are quantitatively related to daily maximum temperature and other
daily weather conditions.

      The method has been applied lo dabi collected in 23 urban areas in the eastern portion
of the U. S.  Trends in ozone concentration* over the 10-year period from 1981-1990 are
estimated for  each city.  In addition,  the model has been used to calculate expected annual
ozone air quality statistics estimated using annual meteorological data that have been adjusted
lo a reference period.  The bootstrap method is used to determine standard errors associated
with the parameter estimates and to calculate confidence limits for the annual adjusted ozone
concentrations statistics.
                                                          •
DATA BASH

      Hourly average concentrations of ozone were obtained from EPA's AIRS data base for
an available monitoring stations within each of the 25 Metropolitan Statistical Areas (MSA)
where ozone levels have been historically high.  The data were selected for the time period
1981 through 1990 and include the months during which daily maximum ozone levels were
likely lo be near or above EPA's National Air Quality Standard (120 ppb). Typically these
months spanned from June through September in more northerly areas (e.g., Chicago, New
York, Boston) and from April through  October in more southerly areas (e.g.. Houston and
Miami).  For each day, the maximum hourly average ozone value was selected from all
available station-hours.                                              '

      The meteorological data base was assembled from hourly average data obtained from
the National Weather Service.  Both surface and upper air data were wed to umati  approsi-
autely 100 daily meteorological parameters' that might be potentially Inynrtant pradanon of
duly ozone levels. These parameters encompass many of those tint nave been previously
identified with high ozone levels such as daily maximum surface'teaaperaOre, relative
humidity, nixing height, and cloud cover.  Daily  maximum ozone vanes for each wbaai area
were paired with corresponding meteorological data at the nearest surface and upper air
nation.

-------
       The data weie scicciicd osbg graphical and ngif itlofl methods to determine which
meteorological parameters teemed to be nod strongly iitnriatml whh day-to-day fluctuations
in daily maximum I-hour ozone. Generally, ft wu fouod that 6 meteorological panroeten
explained moa of the variability b daily ozone concentration*.  These 6 variables were (I)
daily maximum surface temperature (positive association), (2)  manias average wind speed
(negative), ())  afternoon average wind speed (negative), (4)  relative humidity (negative). (5)
opaque cloud cover (negative) and.. (6) moraiag mixing height (negative).

       Figure I shows box plots of the anaml distributions for each of the 6 meteorological
parameters in the  Chicago urban area.  Median and upper percentUei of daily maximum
temperatures were higher to 19(3 and 1988 than for any of the other yean. Since tempera-
lure shows a strong positive association with oame, ozone levels b these 2 yean would be
expected to be higher.  Also, relative humidity and cloud cover for 1988 was significantly
tower than for any other year during the 10 year span.  Since relative hmnidiiy and cloud
cover are generally negatively related to ozone,  ozone levels In 1988 would be expected to
be higher as a result. Although wind speeds and mixing height are Important predictor* of
diy-to-day changes in ozone, the annual distribution of wind speeds and mixing height across
the 10 year period is relatively flat.  Thus, annual variations in these 3 parameters appear to
be less important  in terms of accounting for year-to-year changes in ozone levels b Chicago.

       While a  qualitative link was evident between meteorology and daily ozone, a more
quantitative association  is desirable.  Such • quantitative link is established by modeling the
probability distribution of daily maximum ozone levels as a function of daily meteorological
parameters.

PROBABILISTIC MODELING

       A probability model Is proposed that incorporates the effects of dafly meteorological
conditions on the  probability distribution of oxone concentration levels.  The probability
model is based on the Weitml] distribution b which the scale patameltr is allowed to vary
rroro day to day b response to changes b meteorological conditions favorable to ozone.
With this model structure, annual ozone statistics may be computed by simply combining
daily ozone distributions fitted from the model. Thus, it is passible to quantitatively explain
bow shifts b  the annual distribution of say, temperature, affect the animal distribution of
ozone. Conversely, (he distribution of ozone under more typical conditions may be predicted
stiTiDiy oy yupsmupjtf pctPOfOiOtfiCa^i coooiuOGS uuo IDC i^iood atflo
distribution of ozone. The basic form of the probability model is:
                      frol,\y>
(1)
                                    where        Prob   -  Probability that daily ozone exceeds Y
                                                  a,    =  Scale Parameter for day i
                                                  X    =  Shape Parameter
                                                                                                             •
                                    The scale parameter for any given day is allowed to vary as a function of the soeteorotogical
                                    conditions b the following manner:           •                   •
                                                                                                  i       •
Kxp
                                                                               « I'T )
                                                                                                       (at
                                    where        8,     -  Regression coefficient for parameter j                •
                                                  M,    "  Meteorological parameter j on day I
                                                   (     =  Annual Trend Rate
                                                   T    =  Year (T- 1,2... .10)

                                           This model is designed to account for the effects of dally variations at meteorological
                                    conditions and slowly changing trends that may take place over a number of years. The
                                    advantage is that meteorological and trend effects are estimated rfamiiMMamiy 19 avoid
                                    potential confounding between the  2 types of effects. The model was applied «sbg the data
         Maximum

                                                                                                     of flag iiataaMttii
base assembled for the Chicago MSA.
were obtained Cram code prepared usbg the SAS Interactive Matrix Language* (IML).
Results shown  b Table I include the parameter estimates,  standard errors and t ratio. The 6
meteorological parameters represent the most significant predictors of prone over toe
geographic region containing the 15 urban areas used in ibis analysis. Tie tattnctioa km
formed between temperature and morning average wind speed was beaded to accoua* for Ike
combined effects of these parameters. The trend component was positive aad marginally
significant (t-2.2).

      Because the scale parameter is expressed exponentially, the ftrwr*** estimates
represent a fractional change per unit change b the independent variable.  For fiampte. the
afternoon wind speed coefficient is -0.021 which means that each 1 meter per second bouse
b afternoon wind speed produces a 2.1 percent decrease b me sola paiaiatatr. • The Ibear
trend parameter was estimated at 0.0074 which means that on average, ozone Is estimthM to
be Increasing at slightly less than I percent per year over the ten-year period.

      To assess the validity of the model, the measured- and aaodel-predkted 95tfc sad 99m
percentiles of daily maximum ozone  levels were compared for each of Ike M years.
Predicted vakaes were obtained by substituting parameter estimates and sorvbg for Ike value
of Y such that the sum  of the probabilities given b equation (I)  is equal to Ike product N*P,
where N is the number  of ozone measurements b a year and P is Ike percmtDe cjujmird as
a friction.  For 95th percentiles. the model fits the observed data faHy well for cnck of the

-------
 10 yon.  For 99th pereeatiles. the predicted values woe underestimated (approximately 10
percent) In 1988 ind slightly overestimated (approximately 3 percent) in 1989 and 1990.

ADJUSTED OZONE STATISTICS

       While the meteorologically adjusted annual tread rate ii e*Ja*xed at approximately
 40.7 percent per year, ft is visually more appealing to display the meteorologically adjusted
oione perceoliles for each of the years. Meteorologically adjusted coat* percentiles are
computed by using typical Meteorological data in place of we actual meteorological condi-
tioos for each year. For convenJeace,  a refereace meteorolo|ical period is defined la lemu
of meteorological coodkioets that occur over at least a 10 year period.  The reference period
is characterized ist terms of avenges aad standard deviations of meteorolotical parameters
that are found to be important ozone predictors.  For example, the mean relative humidity for
the reference period is computed as the mean of the daily relative humidities across the 10
year period from 1981 through 1990.  Similarly, the standard deviation for the reference
period is computed as the avenge of the 10 yearly standard deviations  of daily relative
humidity.

       The method used to adjust the meteorological data Involves translation of meteorologi-
cal parameters such that each parameter has the same mean and standard deviation as the
 refereace period. Effectively, data values within each year are scaled such that they become
centered over the distribution of meteorological parameters corresponding to the reference
period. Noutionally.  the calculation of scaled meteorological data is as follows:
             Y - Mr + (Xb'- Mb)*(Sr/Sb).
where
      Mb     -  Mean value for the given period
      Sb      -  Standard deviation for the given period
      Mr     -  Meaa value for the reference period
      Sr      -  Standard deviation for the reference period
      Xb     <•  Daily meteorolotical parameters for the given year
      Y      -  Scaled meteorolotical parameters  for the given year

       As before, model-predicted values of ozone are obtained by substituting parameter
estimates and solving for the value of Y such that the sum of the probabilities given in
equation (I) is equal to the product N*P. where N is the number of ozone measurements in a
year aad P is the perceatik expressed as a fraction.  The meteorology used in this calculation
Is the scaled meteorology such that H has the same mean and standard deviation as the
reference period.    •

       Figure 2 shows the result of Ibis adjustment for Chicago along with the original 99ih
perceab'les. The adjusted result for any given year may be interpreted as the expected value
for the ozone statistic  if the distribution of meteorology in that year had resembled the long
term (10-year) average. Overall, the year-to-year changes in the adjusted 99lh percentiles are
 much less abrupt and convey a smoother sense of trends over the 10 year period.  Upper aad
 lower 93 percent confidence bounds on the 99th percentile were obtained using the buoutiap
 technique which is described below.                                ••   •

 BOOTSTRAP ESTIMATE OP ERRORS                        . .
      One of the important assumptions twwlait*! with
that the  individual observations (days) are independent. Because of
                                                                            persis-
 tence. this is usually not the case.  The effect of non-independence among the daily values b
 to bias the estimate of standard errors associated with the parameter estimates.  Because of
 the positive association among daily values, the effect is to cause the asymptotic standard
 oron to be underestimated.  A more realistic estimate of the standard error of the parameters
 can be obtained wing a resampling scheme such as the Bootstrap or Jackknife'-".  Because of
 its simplicity, the blocked bootstrap is used as the procedure to estimate the sampling errors.
 The sampling strategy involved first partitioning the days into consecutive 3-day blocks.  This
 was done to preserve the dependence that usually exists among  meteorological conditions and,
 of course, resulting ozone levels.

        Next, annual bootstrap samples were chosen by randomly selecting (with replacement)
 data in 3-day blocks until a complete annual (ozone season) sample bad been formed.  For
 each annual sample (ozone and accompanying meteorological data) the parameter estimate*
 were obtained along with the adjusted meteorological data and adjusted ozone statistics.  This
 step was repeated until 100 annual samples had been constructed.  The standard errors of
 parameter estimates (Table I  . nd Table 2) were computed as simply the standard deviation of
• the bootstrap estimates of the parameters.  Typically, the bootstrap estimates of the standard
 error were 30 to 40 percent larger than the asymptotic results.

 URBAN AREA RESULTS

        The model was applied using data for 25 urban areas (Table 2) located throughout the
 eastern portion of the U.S. The same 6 meteorological parameters, including wind speed aad
 teTiperanire interaction, were included in the model.  Model performance showed some
 vuiation among the urban areas.  Model performance is typically good in all areas except for
 southern coastal cities including Miami, Tampa, and Jacksonville, Florida. For these areas,
 source/receptor alignment ind meso-scale meteorological effects (land/sea breezes) not
 accounted for may be related to poorer model performance.

        Table 2 shows the estimated trend parameter along with the booUUap adjusted
 standard error and t ratio. The urban areas are sorted such that cities at the top of the list
 show the most marked improvements while cities near the bottom of the list show the least
 improvements over time.  The I ratio statistic  provides a measure of the significance of the •
 trend rate.  Absolute values of the t ratio greater than 2.0 indicate significance at approxi-
 mately the 95 percent level.

        Three of the uiban areas displayed  improvements that exceeded 2 percent per year
 (Houston, Louisville, and Dallas) while another 10 urban areas had rates of Improvement

-------
better than I percent per year. Seven! cMesBfled oar Ike bottom of Ike list actually
thowed slight ioactses m ozone over the 10-year period.  Tke mediaa Me of change among
the 25 urban areas indicates • I.I percent per year decrease In ozone which b equivalent to
to improvement of approximately 10 percent over die 10-year period.
       For i
                                        i to me 25 arbao ami were
                                                                         led using
the Weitwll probability •ode) wim oaly ike linear ntad compooenr tended in the scale
panmeier.  The purpose for this cilcolttioa was to cootnst the dill eraace between estioaied
trend rates with and without consideration of annual meteorological fluctuations.  For 21 of
the 25 urban areas, the adjusted tread rate was lower Una the Bnadhtsted rate.  The median
rate of change for the unadjusted trends was a 0.5 percent decrease per year indicating that
improvdnents after adjustment are mrHUnrMy greater dun before adjustment.  Clearly, the
adjusted ozone trends provide M indication Ibal national efforts to. reduce tbe seventy of the
uitMn ozone problem nave been more productive man would otberwbe be suggested  from the
data.

CONCLUSIONS

      A statistical model has been developed for describing day-to-day chutes in the
probability distribution of ground level ozone as a function of meteorological conditions. The
model includes a long-term trend component coca that meteorological effects are accounted
for directly in the estimation procedure. The model was applied to data available from 25
urban areas for the summer period covering 1991 through 1990. :The performance of the
model was evaluated by comparing measured- and model-predicted 95th and 99th percentiles.
Overall, the measured- and model-predicted pe
latitudes but performed less well in south
conditions are suspected to dominate.
                                             tiles tracked closely in the northern
                                          stal areas where meso-scale meteorological
      Generally, the adjusted 99th pt
                                     miles hi
                                                ttsJdenbry ten year-to-year variability
than do the unadjusted 99th percentiles. The median rale of change la daily maximum l-bour
ozone levels among the 25 Eastern U.S. urban areas reflected a 1.1 percent per year decrease
over the period from 1981 through 1990.  Since annual changes la neteorotogicai conditions
are directly considered,  die method produces adjusted trend rates that are less influenced by
meteorology than those produced without consideration of meteorological fluctuations.
                                                                                                    REFERENCES
                                                                                                    10.
I.    S. M. Bnmtz. W. S. Cleveland. T. E. Oraedel. B. Kleiner and J. L. Waratr. *Oaoae
      Concentrations in New Jersey and New York: Statistical AsaodarJoa win Related
      Variables.* Science, 186 (1974).                          ;. ,, .
                                                             *.
2.    B. Lamb. A Goenther. D. Oay and H Wesdxrg, *A National bmatary of Blogeak
      Hydrocarbon Emissions.* Atmospheric Pnvimamm  21 (1917).

3.    V. Pagnotti. 'Seasonal Ozone Levels and Control by Seasonal Meteorology,* l^Ak
      W«te Umnifemml Ameimtian 40 (1990).
                                                                ••  I
4.    U.S. 'EPA. Nltkxul Air flmlity «nd P«nl«dnn TrfnAt P>pnrt I OHO EPA-450/4-91-
      003. U.S. Environmental Protection Agency. Research Triangle Park, NC, 1990.

3.    •• E. Sjoccfccnius tod A. B. Huotscbcwskyi, &nj3t&OtmfLQtttA*SXSttu&jSH
      Metenmtoflc.1 v«riitinn, SYSAPP-9CV008.  Systems AppUcatioas,  lac., San Rafael,
      CA. 1990.    .                                                           .

6.    P. O. Wakim. *I9SI to 1988 Ozone Trends Adjusted to Meteorological CondHoai
      for 13 Metropolitan Areas,' 83rd AWMA Annual Meeting and ExaMtkM. June 1990.
      Paper 190-97.9.                                                    •      :

7.    W. M. Cox, and S. Cmi, 'Using Meteorological/Ozone Kclatoifhjpi to EttabOsk M
      Index of Potential Ozone Severity.' 84th AWMA Annual Meeting and ExkMtioa.
      June 1991. Paper 191-119.14

8.    SA5 Institute Inc., SAS/IML Software:  Usage and Reference, Version 6. First
      Edi  jo, Cary, NC: SAS Institute Inc.,  1989.
                                                                                                    9.    B. Ifron. The JtrHmifc, the Bn
                                                                                                          Industrial and Applied Mathematics. Philadelphia. PA, 1982  .

                                                                                                          J. W. Tukey. Kimfa nf Rmmtrat mit
                                                                                                                                                                .Him, Society for

                                                                                                          University. 1987.
                                                                                                                                DmT Technical Report No. 292. Dept of Statistics, Priacetan

-------
      MAX
           TEA*
                                 DEI HUIIIOITT
                                      TfAl
                                                           CIOUD  com
                                                                     \/
                                                                TEA*
      UNO into—AH
           TEA*
                                •mo
                                                            VIXINS HEIGHT
                                      TtAD
                                                                TEAR
                      FIGURE 1.   Chicago Meteorological Data
   220


   200


   180


S160
§
S 120


   100


   80


   60
                         CHICAGO OZONE TRENDS
                  99 TH PERCENT1LE—DAILY UAXJUUU (JUNE-SDT)
ACTUAL
ADJUSTED
95XCONF
        1981   1982   '1983   1984   1985 "  1986  1987   1988   1989   1990

                                      YEAR
            flCURZ  2.  ozon* Trtnd statistics with 93% Confid«ac« Liaits

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                       TADLC 1


      Parameter Estimates and Standard Errors (Chicago)
Variable*
Lambda*
1
Constant
Maximum Sfe Temperature
Mind Spaad (7-10 AH)
Tamp x Mind Spaed (AM)
Mind Spaed (1-4 PM)
Relative Humidity (10-4PM)
Opaque Cloud Cover
Mixing Height (AH)
Year
Parameter
Estimates
4.3800
1.2126
0.0433
0.2313
-0.0038
-0.0213
-0.0010
-O.0004
-0.00009
O.0074
Standard
Errore
0.1780
0.2000
0.0023
0.0468
0.0006
0.0070
0.0011
0.0003
0.00005
O.OO34
T Ratio
24. C
6.1
18.8
5.9
-6.8
-3.0
-0.9
-1.3
-1.8
2.2
Motet  Standard Error* ere based on 100 bootstrap replications.
      They ere approxlmaely 30 to 40 percent larger than
      asymptotic results.
                                                                                    TABLE 2
 OZONE TRENDS ADJUSTED FOR METEOROLOGY  ,
EASTERN U.S URBAN AREAS-1981 THROUGH 19901


HOUSTON
LOUISVILLE
DALU i
NEWYJW
PITTSBURGH
8T LOUIS
TAMPA
BIRMINGHAM
CLEVELAND
DETROIT
CINCINNATI
PHILALOPHIA
BALTIMORE
MILWAUKEE
KANSAS CITY
WASHINGTON
BATON ROUOE
CHARLOTTE
BOSTON
TULBA
COLUMBIA
JACKSONVILLE
MIAMI
CHICAGO
ATLANTA

TREND RATE
(PERCENT/YEAR)
•2.8
•2.6
•2.3
•1.0
•1.7
•1.8
•1.5
•1.4
•1.3
•1.3
-1.2
•1.0
•1.1
. -0.7
•O.7
•O.4
•O.4
•O.4
•0.2
-0.1
0.2
0.0
0.6
0.7
0.8
t
STANDARD,
ERROR I
0.43
0.87
0.29
O.30
0.32
0.27
0.32
0.28
0.37 '
0.31
0.43
OJt
0.34
0.4O
0.38
0.37
0.38
0.21
0.38
0.23 ',
0.24 ,
0.38
0.44
0.34
058

T-RATK)
1
• *
• 4.8
.. -4.6
•7.9
-4.0
-8.3
•9.9
•4.7
•0.0
•33
•4.1
•2.7
•3.9
•3.2
•1.8
•1.8
•1.1
•1.1
•1.9
•0.6
•0.4
0.6
1.6
\A
2.1
3.1
                                                             Note: Dark lines separate cities with
                                                                  no change (middle) or upward
                            downward trends (top)
                            trends (bottom)

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