SOURCE TEST REPORT
EPA TEST NO.:  71-CI-22

PLANT TESTED:  Speedring, Inc.
               Cullman,  Alabama
TESTOR:  Environmental  Engineering,  Inc.
         2324 Southwest 34 Street
         Gainesville,  Florida        32601
         AC 904/372-3318
CONTRACT NO: 'CPA 70-82,  Modification No.  1  to
              Task Order  No.  2,  Second of  Three  Plants

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                     TABLE OF CONTENTS


                                                   Page No.

INTRODUCTION                                            !

SUMMARY OF TEST RESULTS            .                     2

PROCESS DESCRIPTION AND OPERATION                       5

LOCATION OF SAMPLING POINTS                             9

SAMPLING AND ANALYTICAL PROCEDURES                     n
          %
    Procedure for Sampling and Analyzing Beryllium
    from Stationary Sources

APPENDIX

    Code to Sample Designations   •                     13

    Complete Beryllium Test Results                     14

    Sampling Procedures Used for
    Beryllium Sampling                                 20

    Sampling and Analytical Procedures
    Prescribed by EPA                                  25  •

    Results of Laboratory Analyses for Beryllium       31

    Project Participants                               32

    Field Data"                                         33

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                         INTRODUCTION

                                 /
       Beryllium emission tests were performed on  three  sources  located
at Speedring, Incorporated, in Cullman, Alabama, on  August 10, 11,  and
12, 1971.
       Speedring is a beryllium metal and beryllium  oxide  ceramics
machining plant, and utilizes bag collectors  for controlling  beryllium
dust emissions.   All three sources were tested at  locations following
the control units.   Two separate sampling trains were used to test  each
source simultaneously.   Two separate test runs were  performed on the
North and South  stacks, while only one test run was  performed on the
middle stack.
                             - 1  -

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                   SUMMARY  OF TEST RESULTS

      Summarized test results of stack parameters  and  beryllium
emission rates for all  three plants tested  are  included  in  Tables  1
through 3.   Complete stack  parameter and beryllium emission test
results are included in the appendix.   The  tests  indicate that the
Speedring Manufacturing Company emits  0.14  grams  of beryllium per
8-hour day.
     The following code was used to characterize  sample  data:
     SI - Speedring, Inc.,  Division of Schiller Industries,
          Cullman, Alabama
      N - North Stack
      M - Middle Stack
      S - South Stack
      1 - Run #1
      2 - Run #2
      3 - Run #3
      G - Gelman type A filter
     MP - Millipore AA filter
     GB - Gelman type A filter (when used as  a  backup)
     Be - Beryllium sample
    IGB - Impinger and back half acetone and  water and rinses, and
          backup filter combined.
     I  - Impinger and back half acetone and  water rinses combined
     P  - Probe particulate and probe  acetone wash combined
     F  - Filter

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              TABLE 1
SUMMARY OF BERYLLIUM EMISSION DATA
  SPEEDRING MANUFACTURING COMPANY
         CULLMAN,  ALABAMA
            NORTH  STACK
Run Number
Date
Stack Flow Rate @ Stack
Conditions, CFM
Stack Gas Moisture, %
Volume
Stack Gas Temperature, °F .
Test Time, Minutes
Beryllium Emissions, Total Catch
yg/m @ Stack Conditions
grams/8-hr. day
N-l-MP
8/10/71
2850
0.96
116
120
3.20
0,12
N-2-MP
8/10/71
3037
0.4
114
120
0.41
0.02
N-l-G
8/10/71
2923 '
0.7
119.5
120 ,
2.77
0.11
N-2-G
8/10/71
3049
0.3
114
120
0.86
0.04
               - 3 -

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              TABLE 2
SUMMARY OF BERYLLIUM EMISSION DATA
  SPEEDRING MANUFACTURING COMPANY
         CULLMAN, ALABAMA  .
          MIDDLE  STACK
Run Number
Date
Stack Flow Rate 0 Stack
Conditions, CFM
Stack Gas Moisture, %
Volume
Stack Gas Temperature, . F
Test Time, Minutes
Beryllium Emissions, Total Catch
yg/m @ Stack Conditions
grams/8-hr. day
M-l-MP
8/11/71
876
0.9
120
120
0.42
0.01
M-l-G
8/11/71
892
1.1
120
120
0.41
0.01
               - 4 -

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              TABLE 3
SUMMARY OF BERYLLIUM EMISSION DATA
  SPEEDRING MANUFACTURING COMPANY
         C.ULLMAN, ALABAMA
           SOUTH  STACK
Run Number
Date
Stack Flow Rate @ Stack
Conditions, CFM
Stack Gas Moisture, %
Vol ume
Stack Gas Temperature, F
Test Time, Minutes
Beryllium Emissions, Total Catch
yg/m @ Stack Conditions
grams/8-hr. day
S-l-MP
8/11/71
1980
0.8
• 123
120
4.18
0.11
S-2-MP
8/12/71
1752
1.6
115
120
2.10
0.05
S-l-G
8/11/71
1949
2.0
123
120
2.58
0.07
S-2-G
8/12/71
1794
1.3
115
120
0.61
0.01
               - 5 -

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                 PROCESS DESCRIPTION AND OPERATION

          The Speedring Corporation is a machining facility engaged in
the production of high tolerance parts from specialty metals such as
beryllium and beryllium oxide.   The machining operations performed in-
clude cutting, turning, grinding, drilling, ultra-sonic machining, and
other similar processes.  A major portion of Speedring's operations are
performed wet, including ultra-sonic machining and most roughing operations
          Each operating machine is serviced by one or more high velocity
hose pick-ups located at the tool point.  Mhen a machine is not in ser-
vice, the vacuum hose to that specific machine is capped.
          A table of pertinent information for the control  equipment
preceeding the three emission points tested is included in  Table 4.  The
control equipment is listed under the exhaust system it services.  A bag-
house controlled emissions from each of the stacks tested.   The following
table lists the weights collected as determined by weighing the baghouse
catch.
                            3         *TotaT Weight (Ibs.)  of Be Collected
            Avg. Cone, (yg/m )  of         By the Baghouse Preceeding
               Be in Stack Gas                 The Stack Sampled	
North                1.94                             12.0
Middle               0.48                               0
South                2.6                                0
The zero weights recorded for the Middle and South baghouses can be
attributed to the type of operations they service.  The majority of these
operations are performed wet while the operations serviced  by the North

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baghouse are performed dry.   The wet beryllium collected  by  the  Middle
and South baghouses apparently is caked on the bag  material  and  not  easily
separated.   The conclusions  in this  instance  are  that wet machining  oper-
ations did not reduce stack  emissions to a level  lower  than  dry  machin-
ing, and that weight collected from  baghouses is  not representative  of
emissions.
                                -7-

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                                                             TABLE 4

                                             BAGHOUSE OPERATIONS  AT SPEEDRING,  INC.
I

CO

I
                                                                                                            Weight Checks
                                                                                                               Day of
Exhaust Emission
Turbine Exhaust Flow Rate Temperature Number Bag Dimensions Test
Equipment H.P. Duct ACFM °F Bags Dia. (in.) x Length (in.) Ibs. Be
Baghouse 30 South 1875 120 40
Baghouse 30 Middle 920 163 40
Baghouse 40 North 2960 115 62
3.75 x 54 0
3.75 x 54 0
3.75 x 54 12.0

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                 LOCATION OF SAMPLING POINTS

      Stack extensions were connected to the existing effluent stacks
from the baghouses so that the sampling locations would be approximately
eight stack diameters downstream from any disturbance.
      Circular metal  stack extensions were used on all sources tested
at Speedring Manufacturing Company, Inc.  In all  cases, the sampling
location was eight stack diameters downstream and two stack diameters
upstream from any disturbance.  Figures 1 and 2 are typical diagrams
of the stack extensions used.  The stack diagram shown in Figure 2
represents only the South Stack at Speedring.  Figure 3 shows the select-
ed sampling points for all sampling.
                            -  9 -

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                                LOCATION OF SAMPLING POINTS
T
D
I
o
        20
                 80
                                        FIGURE NO.  1
1

o

3D ' 80
J
A
           Port #1
                           Port tf 2
                          FIGURE NO. 2

                              SAMPLE POINT DISTANCE FROM INSIDE STACK WALL

                                     Point No.   12" I.D.
                                        1
                                        2
                                        4
                                        5
                                        6
 1 3/4"
 3 1/2"
 8 1/2"
10 1/4"
11 1/2"
        FIGURE NO.  3
                           -10-

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              SAMPLING AND ANALYTICAL PROCEDURES

       All sources were tested in such a manner as to comply
with the Environmental Protection Agency's (EPA) Proposed Reg-
ulations on National Emission Standards for Five Stationary Source'
Categories, published in the Federal  Register (36 F.R.  5931,
March 31, 1971).  A copy of these procedures from the August 20,
1971 Environment Reporter is presented in the appendix.
       Specific testing procedures and modifications of the
prescribed EPA method are also included in the appendix.
       All samples collected were sent to EPA personnel  in
North Carolina for Beryllium analysis.  Laboratory results are
presented in the appendix following.
                         -II-

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APPENDIX

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                   CODE TO'SAMPLE-DESIGNATIONS
 SI - Speedring,  Inc.,  Division  of  Schiller  Industries,
      Cullman,  Alabama
  N - North  Stack
  M - Middle Stack
  S - South  Stack
  1 - Run .#1
  2 - Run #2
  3 - Run #3
  G - Gelman Type A filter
 MP - Millipore AA filter
 GB - Gelman type AA filter (when used  as  a  backup)
 Be - Beryllium sample
IGB - Impinger  and back half acetone  and water  and  rinses,  and
      backup filter combined.
  I - Impinger  and back half acetone  and water  rinses  combined
  P - Probe  particulate and probe acetone  wash  combined
  F - Filter
                             -13-

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                                      SOURCE TEST DATA
E.P.A. Test No.	
Name of Firm	Speedring Manufacturing Company
                            No. of Runs
Location of Plant    Cullman. Alabama
Type of Plant      Beryllium Machinery
Control Equipment  Baghouse
Sampling Point Location   North stack
Pollutants Sampled	
Beryllium Dust
Run No.
Date
'Time Began
Time End
Barometric Pressure, "Hg. Absolute
Meter Orifice Pressure Drop, "h^O
Volume of Dry Gas Meter @ Meter Cond., ft3
Ave. Meter Temp. , F
Volume of Gas Sampled @ Stack Cond., ft3
Volume of H20 Collected in Impingers &
Silica Gel, ml2
Volume of Water Vapor Collected & Stack
Cond., ft3 •
Stack Gas Moisture, % Volume
Mole Fraction of Dry Stack Gas
N-l-MP
8/10/71
0915
1125
29.95
3.790
145.767
91.6
152.51
28.5
1.47
0.96
0.9904
N-l-G
8/10/71
0923
1133
29.95
3.480
135.916
90.0
143.28
20.5
1.06
0.74
0.9926
N-2-MP
8/10/71
1405
1615
29.95 -
4.220
158.101
87.0
165.09
12.5
0.64
0.39
0.9961
N-l-G
8/10/71
1410
1620
29.95
3.900.
145.179
86.0
151.82
8.0
0.41
0.27
0.9973
                                             -14-

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Run No.
Molecular Weight of Stack Gas, @ Stack Cond.
Molecular Weight of Stack Gas, Dry
Stack Gas Sp. Gravity, Ref. to Air
Ave. Sq. Root of Velocity Head, "H20
Ave. Stack Gas Temp., °F
Pi tot Corr. Factor
Stack Pressure, "Hg Absolute
Stack Gas Velocity @ Stack Cond., fpm
Stack Area, ft2
Stack Gas Flow Rate @ Stack Cond., cfm
. Net Time of Test, min.
Sampling Nozzle Diameter, in.
Percent Isokinetic
Beryllium Catch, Probe, yg
Beryllium Catch, Filter, yg
Beryllium Catch, Total, yg
Beryllium Concentration, Probe, Stack
Cond.., yg/m3
Beryllium Concentration, Filter, Stack
Cond. , yg/m3
Beryllium Concentration, Total, Stack
Cond. , yg/m-5

28.86
28.97
1.00
1.023
116.0
0.85
.29.9
3632
0.78
2720
120
0.250
102.7
0.45
0.30
13.80
0.10
0.07
3.20
(Sam<
28.89
28.97
1.00
1.046
119.5
0.85
29.9
3725
0.78
2800
120
0.250
94.0
3.13
0.15
11.23
0.77
0.04
2.77
)
28.93
28.97
1.00
1.092
114.0
0.85
29.9
3869
0.78
2920
120
0.250
104.3
0.00
0.00
1.90
0.00
0.00
0.41

28.94
28.97
1.00
1.096
114.0
0.85
29.9
3885
0.78
2939
120
0.250
95.5
3.05
0.31
3.70
0.71
0.07
0.86
-15-

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                                      SOURCE TEST DATA
E.P.A. Test No.	
Name of Firm	Speedring Manufacturing Company
                               No.  of Runs
Location of Plant_
Type of Plant	
                      Cullman, Alabama
Beryllium Machinery
Control Equipment     Baghouse
Sampling Point Location  Middle Stack
Pollutants Sampled     Beryllium Dust
Run No.
Date
Time Began
Time End
Barometric Pressure, "Hg. Absolute
Meter Orifice Pressure Drop, "H20
Volume of Dry Gas Meter @ Meter Cond. , ft3
Ave. Meter Temp. , °F
Volume of Gas Sampled @ Stack Cond., ft3
Volume of ^0 Collected in Impingers &
Silica Gel, ml2
Volume of Water Vapor Collected & Stack
Cond. , ft3
Stack Gas Moisture, % Volume
Mole Fraction of Dry Stack Gas
M-l-MP
8/11/71
0750
1000
29.90
1.720
101.874
80.0
109.96
19.5
1.01
0.92
0.9908
M-l-G
8/11/71
0754
1004
29.9
1.810
101.344
81.0
125.61
23.0
-1.37
1.09
.9891






















-



                                             -16-

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Run No.
Molecular Weight of Stack Gas, @ Stack Cond.
Molecular Weight of Stack Gas, Dry
Stack Gas Sp. Gravity, Ref. to Air
Ave. Sq. Root of Velocity Head, "H20
Ave. Stack Gas Temp. , °F
Pi tot Corr. Factor
Stack Pressure, "Hg Absolute
Stack Gas Velocity @ Stack Cond., fpm -
Stack Area, ft2
Stack Gas Flow Rate @ Stack Cond., cfm
Net Time of Test, min.
Sampling Nozzle Diameter, in.
Percent Isokinetic
Beryllium Catch, Probe,. yg
Beryllium Catch, Filter, yg
Beryllium Catch, Total, yg
Beryllium Concentration, Probe, Stack
Cond. ,. yg/m3
Beryllium Concentration, Filter, Stack
Cond. , yg/m3
Beryllium Concentration, Total, Stack
Cond. , yg/m3
(San
28.87
28.97
1.00
0.313
120
0.85
29.9
1116
0.78
855
120
0.375
107.1
0.20
0.05
1.30
0.06
0.02
0.42
e)
28.85
28.97
1.00
0.320
120
0.85
29.9
1222
0.78
935
120
0.375
103.9
0.60
0.00
1.45
0.17
0.00
0.41






















"

















-17-

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                                      SOURCE TEST DATA
E.P.A. Test No..
Name of Firm
                              No. of Runs
Speedring Manufacturing Company
Location of Plant_
Type of Plant	
Cullman, Alabama
Beryllium Machinery
Control Equipment^
                      Baghouse
Sampling Point Location South stack
Pollutants Sampled_
Beryllium Dust
Run No.
Date
Time Began
Time End
Barometric Pressure, "Hg. Absolute
Meter Orifice Pressure Drop, "H^O
Volume of Dry Gas Meter @ Meter Cond., ft3
Ave. Meter Temp. , °F
Volume of Gas Sampled @ Stack Cond., ft3
Volume of ^0 Collected in Impingers &
Silica Gel, ml2
Volume of Water Vapor Collected & Stack
Cond., ft3
Stack Gas Moisture, % Volume
Mole Fraction of Dry Stack Gas
S-l-MP
8/11/71
1445.
1655
29.90
1.650
100.112
95.0
105.54
15.5
0,81 .
0.77
0.9923
S-l-G
8/11/71
1342
1552
29.9
1.560
96.572
95.0
103.09
39.0
2.04
1.98
0.9802
S- 2-MP
8/12/71
0830
1040
29.90
1.650
90.240
79.0
97.50
29.5
1.51
1.55
0.9845
S-2-G
8/12/71
0833
1043
30.0
T.340
88.260
78.0
95.29
24.0
1.23
1.29
0.9871
                                                 -18-

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Run No.
Molecular Height of Stack Gas, @ Stack Cond.
Molecular Height of Stack Gas, Dry
Stack Gas Sp. Gravity, Ref. to Air
Ave. Sq. Root of Velocity Head, "H20
Ave. Stack Gas Temp., °F
Pi tot Corr. Factor
Stack Pressure, "Hg Absolute
Stack Gas Velocity @ Stack Cond., fpm
«
Stack Area, ft2
Stack Gas Flow Rate @ Stack Cond., cfm
Net Time of Test, min.
Sampling Nozzle Diameter, in.
'Percent Isokinetic
Beryllium Catch, Probe, yg
Beryllium Catch, Filter, yg
Beryllium Catch, Total, yg
Beryllium Concentration, Probe, Stack
Cond. , yg/m3
Beryllium Concentration, Filter, Stack
Cond. , yg/nr
Beryllium Concentration, Total, Stack
Cond. , yg/m3

28.88
28.97
1.00
0.706
123.0
0.85
29.9
2523
0.78
'1882
120
0.250
102.3
0.95
1.00
12.50
0.32
0.33
4.18 '
( Sarm
28.75
28.97
0.99
0.695
123
0.85
29.9
2484
0.78
1853
120
0.250
101.5
1.68
0.25
7.53
0.53
0.09
2.58
)
28.80
28.97
1.00
0.629
115.2
0.85
30.0
2232
0.78
1721
120
0.250
107.1
1.10
0.45
5.80
0.40
0.16
2.10

28.83
28.97
1.00
0.644
115.3
0.85
30.0
2285
0.78
1765
120
0.250
102.3
0.55
0.00
1.65
0.20
0.00
0.61
-19-

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  COMPLETE SAMPLING PROCEDURES USED FOR BERYLLIUM SAMPLING

      Prior to performing the actual beryllium particulate runs,
certain preliminary stack and stack gas parameters had to be deter-
mined for each source.   This preliminary data included the average
temperature, velocity head, moisture content, and the stack diameter
at the point where the tests were being performed.
      The stack gas temperature was determined by using bimetallic
thermometers and mercury bulb thermometers.
      Velocity head measurements were determined across the stack
diameter by using a calibrated S-type pi tot tube with an inclined
manometer.  This data was used to select the sampling nozzle diameter.
      The approximate moisture content of the stack gas was determined
by the wet-bulb and dry-bulb thermometer technique since the stack
gas temperature was below 212°F.
      The sampling traverse points were selected so that a represen-
tative sample could be extracted from the gas stream.  The traverse
points for circular stacks were located in the center of the annular
equal area circles selected, which were dependent upon diameter and
duct diameters downstream from flow disturbances.
      The basic modification of the EPA particulate sampling train for
beryllium sampling was the selection of filter media.  Tests were
performed with the standard glass fiber filter and also with a type AA
millipore filter.  A schematic diagram of the sampling train used is
shown in Figure A-l.

                               -20-

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      The gases sampled were collected through the following train:
a stainless steel  nozzle; a glass probe; a filter; two impingers  with
100 ml of distilled water; one dry impinger; one impinger with 180
grams of silica gel (the second impinger had a standard tip, while
the first, third,  and fourth impingers had modified tips with 1/2-inch
ID opening); a flexible sample line; an air-tight pump; a dry test
meter; and finally, a calibrated orifice.
      At Speedring, Inc., two sampling trains were used simultaneously
at the fabricated  effluent stack from the baghouse.  One train contained
only a glass fiber filter and the other contained a mi Hi pore filter
backed up by a glass fiber filter.
      Each test run consisted of sampling for a specified time at each
traverse point through either a vertical or a horizontal sampling
position for the first half of the test run, and then switching to the
other sampling position for the second half of the run.  Duplicate
samples were taken from all sources except for one source.   In all
cases, the train using a millipore filter was placed in the'vertical
position (port opening located at top of horizontal duct),  starting
with the sampling  point nearest the bottom of the duct.  The sampling
train containing the glass fiber filter always started in the horizontal
position at the traverse point nearest the port opening.  After gases
were withdrawn at  the selected six points, the probes (still attached
to their respective trains) were switched from vertical to horizontal
positions and vice versa.  Both trains were used simultaneously.
                               -21-

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                                  18
1.  Nozzle (stainless steel)
2.  Probe (Pyrex glass tubing inside stainless steel shaft)
3.  Filter
 4
 5

 6.
 7.
 8.

 9.
10.
11
12
13
14.
15
16.
17.
18.
    Ice bath
    Impinger with 100 ml distilled water
      (modified tip)
    Impinger with 100 ml distilled water
    Impinger, dry (modified tip)
    Impinger with silica gel
     (modified tip)
    Thermometer
    Flexible sample line
    Vacuum gauge
    Main control valve
    Air tight vacuum pump
    By-pass control valve
    Dry test meter
    Calibrated orifice
    Inclined manometer
    "S" type pitot tube
                                                    FIGURE A -1  BERYLLIUM SAMPLING TRAIN

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          Sample recovery for all beryllium tests was  accomplished by the

following procedure:

          1.   Each filter was removed from its  holder  and placed
              in Container No.  1 and sealed.

          2.   All sample-exposed surfaces  prior to  the filter were
              washed with acetone and placed into Container No.  2
              and sealed.

          3.   The volume  of water in the first  three impingers
              was measured and then  placed into Container No. 3.
              The water rinsings of  all sample-exposed surfaces
              between  the back half  of the filter holder  and
              fourth impinger were also placed  into Container
              No.  3 prior to  sealing.

          4.   The used silica gel from the fourth impinger was
              transferred to  the original  tared container and
              sealed.

          5.   All sample-exposed surfaces  between the  back half
              of the filter holder and the fourth impinger were
              rinsed with acetone and the  rinsings  were placed
              into Container  No. 5 and sealed.
                                     -23-

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                                PARTICULATE TEST CALCULATIONS
                                                                             .  Date  &-/O-7/
Plant Sfee-clrirtc* M-fft.  Co.	,  Stack,
Mr. Press. 29. ff£ "Hgt Stack Press. 29. 9£  "Hg.  Stack Dia. /Z  in.. Stack Area	£?.
Ave. Stack Tenp. //fo  °F.  Ave. Meter Temp. yX£°F. Ave.A/TT_^£££"H20, Nozzle Dia.  O* 2,
                                                                                             f
                                                                                             in
                                                                                               2
I
                                                                     ml. Sample Time
                                                               Ave. Orifice AH
                                                                                       "H20
 O.B3. Meter Vol. /<££ 7£7    ft^.  Moisture plus Silica Gel.
 sat AnalysisIv  CCb  -   #.  0? -   %. CO -  ^.  N?  —  ^                      	
 fzzle Dia. and Areai   1/4 in.	0.0003^1  ft2,  3/8 in.	0.000767 ft2,   1/2 in.	0.0013 ft2

 ) VHV = (0*0474) -x.  (Moisture + Silica Gel)ml   ,                             a   /• 357

   Vstpd= (17-71) x (Po +^K-) x (Vm)

3) vt = (vw) + (vstpd)
                                                                                            min.
  8)
I
I
  8
I
I,
i
L2)
     FDA =(1.0) -  (W)
    M
                             [(0.32)x( _ 5J02)] + [To.28)x(
       = &Id) x  (FDA)j
    Q  =    J
     s    28.99
  ) Excess Air,  EA =
                       [O.266)x(
                                                                     x 100
    U =  (1?^) x  (Cp) x

    Q3« (0)x (As)

    Qd = (Qs) x  (FDA)
                                                   '29.92
I
i
I!
                                         70
    \\ = (D) x (An)  :c (FDA)  x (Tims)  x (  ^ ^
                                          S
                                   x  100
                           Ar    \
    Percent Isokinetic =  •• ^^

                            Vi   '
                                            (5.626) x (T5 + 460) x (O
    Percent Isokinetic by the  EPA Method ="(f) x (Time) x (?s) x (?DA)'X (An)   =	

                                18)  E12  .  (12L; ffi^    19) EW =  (W  X ^1C^ * S^-
         _   (15.43) x  (Y)
                          x  (0.00857)
                                                                             150
                                                                                             _fp~
I
  Particulate Lab Analysis
                  (I)
                              Particulate Concentrations,
                                     f-   \        /
                                     Ustp)
                                                                          Emission Rate,  Ibs/hx
                                                                                    (E>a)
                  7.
  Total
                                                  -24-

-------
 CURRENT DEVELOPMENTS
                                                                                                                  481
 Subparl  E—Standards  of  Perform-
      ance  for Nitric Acid  Plants

 § 466.50  Applicability and designation
     of affected facility.
   (a)  The provisions of *Ns subpart are
 applicable to nitric acid piants.
   (b)'For purposes of §4GG.ll(e), the
 entire plant is the affected facility.

 §466.51  Definitions.
  As u.ert in this part, all terms not de-
 fined herein shall have the meaning given
 them in the Act:
   (a)  "Nitric acid  plant"  means  any
 facility producing  weak nitric acid  by
 either the pressure or atmospheric pres-
 sure process.
  • (b)  "Weak nitric  acid"  means  acid
 which is 50 to 70 percent in strength.

 § 466.52  Standard  for nitrogen  oxides.
  No person subject to the provisions of
 this subpart shall cause or allow the dis-
 charge into the  atmosphere of nitrogen
 oxides in the eflluent which are:
  (a)  In  excess  of 3 Ibs. per ton of  acid
 produced  (1.5 Kgm. per metric ton),
 maximum 2-hour average, expressed as
 NO.
  (b)  A  visible  emission  within   the
 meaning of this  part.     . .

 § 466.53  Emission monitoring.
  (a)  There  shall  be  installed,  cali-
 brated, maintained, and operated, in any
 nitric acid plant subject to the provisions
 of vhis subpart,  an instrument for  con-
 tinuously   monitoring  and  recording
 emissions  of nitrogen oxides.
  (b)  The instrument installed and  used'
 pursuant  to this  section shall have  a
 confidence level of at least 95 percent and
 be accurate within ±20 percent and  shall
 be  calibrated in  accordance  with  the
 method (s) prescribed by  the  manufac-
 turer^) of such instrument; the instru-
 ment shall  be calibrated at least  once
 per  year  unless  the  inanufacturer(s)
 specifies or  recommends  calibration  at
 shorter intervals, in which case  such
 specifications or recommendations shall
 be followed.
  (c) The owner or operator of  any
 nitric acid plant  subject to the provisions
 of this subpart shall maintain a file of all
 measurements required  by this subpart
 and shall  retain the record  of any  such
 measurement for at least  1 year fojlow-
 ing the date of such measurement.

 § -166.5-1  Tost methods and procedures.
  (a)  The provisions of this section are
 applicable to performance tests for deter-
 mining emissions of nitrogen oxides from
 nitric acid plants.
  (b)  All  performance tests shall be  con-
 ducted  while the  affected  facility  is
 operating at or  above the acid product
 rate for which such facility \vas designed.
  (c) Test methods set  forth in the ap-
pendix  to this  part shall  be  used  as
 follows:
  (1) For each repetition the NO,  con-
 centration shall  be determined by using
 Method 7. The sampling location shall be
 selected according to Method 1 and the
 sampling  point shall be the centroid  of
 the stack or duct. The  sampling time
 shall be 2 hours and four samples shall
 be taken during each  2-hour period.
   (2)  The volumetric  flow rate of the
 total efiluent shall  be determined by us-
 ing Method 2 and traversing according
 to Method 1. Gas analysis shall  be per-
 formed by Method 3, and moisture con-
 tent shall be determined by Method 4.
   (d)  Acid produced,  expressed  in tons
 per hour of 100 percent weak nitric acid,
 shall be determined during each 2-hour
 testing period by suitable flow meters and
 shall be confirmed by a material balance
 over the production system.
   (e) For each  repetition, nitrogen ox-
 Ides emissions, expressed in  Ib./ton  of
 weak nitric acid, shall be determined by
 dividing the emission rate in ib./hr.  by
 the acid  produced. The emission rate
 shall be determined by the equation, lb./
 hr.=QxC,  where  Q=volumetric  flow
 rate of the effluent in ft.yhr. at standard
 conditions, dry basis, as  determined in
 accordance  with  ! 466.54(d) (2),  and
 C=NO< concentration in Ib./f t.3, as deter-
 mined in accordance with § 4G6.54(d) (1),
 corrected to standard conditions, dry
 basis.

 Subpart  F—Standards  of  Perform-
     ance for Sulfuric Acid Plants

 § 466.60  Applicability  and designation
     of affected facility.
   (a) The provisions of this subpart are
 applicable to sulfur acid plants,
   (b).,For purposes of § 466.11 (e) the en-
 tire plant is the affected facility.
 § 466.61  Definitions.
  As  used in this part,  all terms not
 defined herein shall have the meaning
 given them in the Act:
   (a) "Sulfuric  acid plant" means any
 facility  producing sulfuric acid  by the
contact process by burning elemental sul-
 fur, alkylation acid, hydrogen sulfide,
 organic sulfides and mercaptans, or acid
 sludge.
   (b) "Acid mist" means sulfur acid mist,
as measured by  test methods set forth
in this part.

 § 466.62  Standard for sulfur dioxide.
  No person subject to the provisions  of
 this subpart shall cause  or allow the dis-
charge into the atmosphere of sulfur di-
oxide in the eiTHient in excess of 4 Ibs.
per ton of acid  produced (2  kgm. per
metric ton), maximum 2-hour average.

§ 166.63  Standard for acid mist.
  No person subject to the provisions  of
this subpart shall cause or allow the dis-
charge into the atmosphere of acid mist
in the eflluent which is:
  (a) In excess of 0.15 lb. per ton of acid
produced  10.075  Kgm.  per metric ton),
maximum 2-hour average, expressed  as
H;SO,.
  (b) A   visible  emission  within  the
meaning of this part.

§ -tfi6.64-  Emission monitoring.
  (a) There shall be installed, calibrated,
maintained, and operated, in any sulfuric
acid plant subject  to the provisions  of
this subpart, an instrument for continu-
 ously  monitoring and recording emis-
 sions of sulf ur dioxide.
   (b)  The instrument installed and used
 pursuant to this section shall have a con-
 fidence level of at least 95 percent and be
 accurate  within  ±20  percent end shall
 be calibrated  in accordance  with  the
 method (s) prescribed by the manufac-
 turcr(s) of such instrument, the instru-
 ment shall be calibrated at least once per
 year unless the manufacturers) speci-
 fies or recommends calibration at shorter
 intervals, in which  case such speciilca,-
 tions or recommendations shall be fol-
 lowed.
   (c) The owner or operator of any sul-
 furic acid plant subject to the provisions
 of  this subpart shall maintain  a file of
 all measurements required by  this sub-
 part and shall retain  the record of any
 such  measurement  for at least 1 year
 following the date of such measurement.
 § 466.65   Test methods and procedures.
   (a)  The provisions of this section  are
 applicable to performance tests  for  de-
 termining emissions of acid mist and sul-
 fur dioxide from sulfuric acid plants.
   (b) All performance tests shall be con-
 ducted while the affected facility is op-
 erating at or above  the acid production
 rate for which such facility was designed.
   (c)  Test methods  set forth  in  the
 appendix to this part shall  be used as
 follows:
  (1) For each repetition the acid mist
 and SO: concentrations shall be deter-
 mined by using Method 8  and traversing
 according to Method  1.  The sampling
 time shall be 2 hours, and sampling vol-
 ume shall be 40 ft.3 corrected to standard
 conditions.
   (2) The volumetric flow rate of the
 total effluent shall be determined by us-
 ing Method 2 and traversing according
 to Method 1. Gas analysis shall be per-
 formed by Method  3.  Moisture content
 can be considered to be zero.
  (d) Acid produced,  expressed in tons
 per hour of 100 percent sulfuric acid
 shall be determined  during each 2-hour
 testing  period  by suitable flow  meters
 and shall be  confirmed by  a  material
balance over the production system.
  (e)  For each repetition, acid mist and
 sulfur  dioxide  emissions,  expressed  in
Ib./ton  of sulfuric acid shall be deter-
mined  by dividing the emission  rate in
Ib./lir. by the  acid produced. The emis-
sion rate shall  be  determined  by  the
equation,  lb./hr.=QxC, where Q=volu-
 metric flow rate of the effluent in ft.Vhr.
at standard conditions, dry basis, as de-
 termined in accordance with  5 -iljG.GSCd)
 (2), and C=acid mist and SO;  concen-
trations in lb./ft.: as determined in ac-
cordance  with  § 46G.G5(d) (1), corrected
to standard conditions, dry basis.
        APPENDIX—TEST METHODS
 METHOD I	SAMPLE AND  VELOCITY  TUAVEI1SES
          FOR STATIONARY SOURCES
  1. Principle and applicability.
  1.1 Principle.  A sampling site  and  the
number of traverse points  arc selected to
aid  In  the extraction of a representative
sample.
  1.2  Applicability. This method should bo
applied only when specified by the lest pro-
cedures  for determining compliance  with
                                 Copyright © 1971 by The Bureau ol Notional Affairs, Inc.

-------
m
3
73
re
•o
o
     Now  Source Performance  Standards.  This
     method  Is  not  Intended to apply  to gas
     streams other than those emitted directly to
     the atmosphere  without further processing.
       2. Procedure.
       2.1  Selection  of a sampling site and mini-
     mum number of  traverse points.
       2.1.1  Select a sampling site  that Is  at
     least  eight  stack or duct diamerers down-
     stream  and  two diameters  upstream  from
     a:>.y How disturbance such ns a bend, expan-
     sion,  contraction, or visible llamc. For  a
     rectangular  cross  section,  determine an
     equivalent  diameter  from  the  following
     equation:
     equivalent
                         ength
                                             J
                                  equation 1-1
       2.1.2  v/hen the above sampling site cri-
     teria  can be met, the minimum number of
     , traverse points Is twelve (12).
  2.1.3  Some sampling situations render th<5
above  sampling  site  criteria  Impractical.
When this  Is the case, choose a convenient
sampling location tmd  use Figure 1—1  to
determine the minimum number of traverse
points,
  2.1.4  To use  Figure 1-1 flrst measure the
distance from the chosen sampling location
to the  nearest upstream  and  downstream
disturbances. Determine the  corresponding
number or  traverse points  for each distance
from Figure 1-1. Select the higher of the two
numbers of traverse points, or a greater value.
such that for circular stacks the number Is
a multiple of four, and for rectangular stacks
the number follows  the criteria of section
2.2.2.
  2.2  Cross sectional layout and location of
traverse points.
  2.2.1   For circular stacks locate the traverse
points  on two  perpendicular  diameters ac-
cording to Figure 1-2 and Table 1-1.
           0.5
                             1.0
                             NUMBER Of DUCT DIAMETERS UPSTREAM'
                                     (DISTANCE A)

                                          1.5                2.0
                                                                                    2.5
         50
2   40
O
         30
          20
          10
Y
A
j
T
B
1



T

4
7DISTURBANCE

_ SAMPLING
"" SITE

DISTURBANCE
                  •FROM POINT OF ANY TYPE OF
                   DISTURBANCE (BEND, EXPANSION; CONTRACTION, ETC.)
                                                                                        Figure 1-2.  Cross, section of circular stack showing location of
                                                                                       traverse points on perpendicular diameters.
1
1
0 S 0
1
1
______ p— _
1
1
O 1 O
I
1
	 T 	
1
1
O I O
1
f
1
•

0





o


	


o





o





e


	


c



                                                                                     Figure 1-3.  Cross section of rectangular stack divided  into 12  equal
                                                                                     areas, with traverse points at centroid of each area.
                                                                                                                                                                                 •a
                                                                                                                                                                                 O
                                                                                     10
                                  NUMBER OF DUCT DIAMETERS DOWNSTREAM*
                                             (DISTANCE B)
                               Figure 1-1. Minimum number of traversa points.
                                                                                                                                                                            33
                                                                                                                                                                            m
                                                                                                                                                                            -o
                                                                                                                                                                            O
                                                                                                                                                                            33
                                                                                                                                                                            H
                                                                                                                                                                            m
                                                                                                                                                                            33

-------
                  Table 1-1.  Location of traverse points in circular stacks
                (Percent of stack diameter from inside v/all to traverse point)
n
o
•a
-sj
H
•3-
!3
Traverse
point
number
on a
diameter
1
2
3
4
5
6
7
3
9
10
11
12
13
n
15
15
17
18
13
20
21
22
23
24
Number of
6 8 10
4.4 3.3 2
14.7 10.5 8
29.5 19.4 14
70.5 32.3 22
85.3 67.7 34
95.6 80.6 65
89.5 77
95.7 85
91
97














5
2
6
6
2
8
4
4
8
5














"12
2.1;
6.7
11.8
17.7
25.0
35.5
64.5
75.0
82.3
83.2
93.3
97.9












traverse
14
1.8
5.7
9.9
14.6
20.1 •
26.9
35.6
63.4.
73.l'
79.9
85.4
90.1
94.3
98.2










points
16
1
4
8
12
16
22
28
37
62
71
78
83
87
91
95
98








6
9
5
5
9
0
3
5
5
7
0
1
5
5
1
4








on a
18
1.4
4.4
7.5
10.9
14.6
18.8
23.6
29.6
38.2
61.8
70.4
76.4
81.2
85.4
89.1
92.5
95.6
98.6






diameter
20
1
3
3.9
6
9
12
16
20
25
30
38
61
69
75
79
83
87
90
93
96
98




7
7
9
5
4
0
6
8
2
4
0
6
5
1
3
3
1
7




22
1.1
3.5
6.0
8.7
11.6
14.6
18.0
21.8
26.1
31.5
39.3
60.7
68.5
73.9
78.2
82.0
85.4
88.4
91.3
94.0
96.5
98.9


24
1.1
3.2
5.5
7.9
10.5
13.2
16.1
19.4
23.0
27.2
32.3
39.8
60.2
67.7
72.8
77.0
80.6
83.9
86.8
89.5
92.1
94.5
35.8
98.9
                                           not  be vised In the case of nondlrecttonal
                                           flow.
                                             2. Apparatus.
                                             2.1  Pltot tube—Type S  (Figure 2-1). or
                                           equivalent.
                                             2.2  DiScrential pressure gauge—Inclined
                                           manometer, or equivalent, to measure ve-
                                           locity head to within 10 percent of the mlnl-
                                           ' mum valve.
                                             2.3.  Temperature gauge—Thermocouples,
                                           bimetallic thermometers, liquid filled  sys-
                                           tems, or equivalent, to measure  stack  tem-
                                           perature to within 1.5 percent of the mini-
                                           mum absolute stack temperature.
                                             2.4  Pressure gauge—Mercury-filled U-tube
                                           manometer, or equivalent, to  measure stack
                                           pre:;sure to within 0.1 In. Hg.
                                             2.5  Barometer—To  measure atmospheric
                                           pressure to within 0.1 In. Hg.
      2.2.2.  For rectangular  stacks  divide the
    cross section Into as many equal rectangular
    areas as traverse points, such that the ratio
    of the length to the width of the elemental
    areas Is bef.vcen one and two. Locate the tra-
    verse points at the centrold of each equal
    area according to Figure 1-3.
      3. References. Determining Dust  Concen-
    tration In a Gas Stream. ASME Performance
    Test Code #21. New York. 1957.
      Devorkln.  Howard,  ct  al. Air Pollution
    Source  Testing Manual. Air Pollution  Con-
    trol District. Los Angeles. November 1963.
      Methods  for Determination  of Velocity,
    Volume, Dust and Mist Content of  Gases.
    V.'eitern Precipitation Division of Joy Manu-
    facturing  Co.  Los Angeles.  Bulletin V/P-50.
    19(58.
  Standard Method lor Sampling Stacks for
Fartlculate Matter. In: 1971  Book of ASTM
Standards, Part 23. Philadelphia, 1971. ASTM
Designation D-2923-71.

METHOD  2—DETERMINATION   Of  STACK  OAS
       VELOCITY (TYPE S PITOT TUBE)'

  1.  Principle and applicability.
  1.1  Principle.  Stack gas  velocity  Is  de-
termined  from  the  gas density and from
measurement  of  the  velocity head using a
Type S (Stauschetbe  or reverse type) pltot
tube.
  1.2  Applicability. This method should be
applied only when specified by the test pro-
cedures  for  determining  compliance with
New Source  Performance Standards. Being a
directional Instrument, a pltot tube should
                                             2.0  Gas analyzer—To analyze gas compo-
                                           sition for determining  molecular  weight.
                                             2.7  Pltot  tube—Standard  type,  to cali-
                                           brate Type S pltot tube.
                                             3. Procedure.
                                             3.1  Set up the apparatus as shown In Fig-
                                           ure 2-1. Muke  sure all connections are tight
                                           and leak free.  Measure the velocity head at
                                           the traverse  points specified by Method 1.
                                             3.2  Men-sure the temperature of the stack
                                           gas. If the total  temperature variation with
                                           time Is less than  50' P., a point measurement
                                           will suillce.  Otherwise, conduct e. temperu-
                                           turo  traverse.
                                             3.3  Measure the  static pressure  In tho
                                           stack.
                                             3.4  Determine the  stack  gas molecular
                                           weight by gas  analysis and appropriate cal-
                                           culation as Indicated In Method 3.
                                                                                                                                PIPE COUPLING
                                                                                                            TUBING ADAPTER
   Figure 2-1.  Pilot tube - manometer assembly.
  4.  Calibration.
  4.1 To calibrate the pitot tube, measure
tho velocity head at some point In a flowing
gas stream with both a Type S pltot tube and
a standard type pltot tube with known co-
efficient. The velocity of the  flowing gas
stream should be within the normal working
range.

-------
 484
                                                                                                  ENVIRONMENT  REPORTER
  43  Calculate the  pltot  tube coefficient   then the other pointed downstream. Use the
using Equation 2-1.                          P'tot tube only If the two coefficients differ
                                            by no more than 0.01.
                                              6. Calculations.
                                              Use Equation 2-2 to calculate the stack gas
where:
  Cple., = Pilot tube  coefficient of Type S
           pltot tube.
   C,,M=Pltot tube  coefficient of standard
           type pltot tube (if unknown, use   *'"«:
           0.99).
   ap.u=Vcloclty head measured by  stand-
           ard type pltot tube.
  AP,.it = Velocity head measured by Type S
           pltot tube.
velocity.

            V.=KpCp-y p-,^     equation :-2

  V.=Stock gas velocity, feet per second (f.p.s.).
                            when these units
                            arc used.
  4.3   Compare the coefficients of the Type S
pltot tube determined first with one leg and
  Cp = Pitot tube eoi'flicient, diniPiisionlcss.
  T. = Absolute stack ras trmpcrature, °H.
  4p=Vel(K-ily head of stack ens. in II;O (sec fig. 2-2).
  P*=Absolute stack p»3 pressure, in lip.
  Mi**Mulecular Wtiulit 01 stuck BUS, lb..lb.-niole.
     PLANT,
     DATE
     RUN NO.
     STACK DIAMETER, in.__
     BAROMETRIC PRESSURE, in.
    STATIC PRESSURE IN STACK (Pg|, in. Hg._

    OPERATORS	
              SCHEMATIC OF STACK
                 CROSS SECTION
Traverse point
number





















Velocity head,
in. H20












•








AVERAGE:
v£7






















Stack Temperature
(%1,'F






















Figure 2-2. Velocity traverse data.
  Figure 2-2 shows a sample .recording sheet
for velocity traverse data. Use the averages In
the last two  columns of Figure 2-2 to deter-
mine the  average stack gas  velocity from
Equation 2-2.
  6. References.
  Mark,  L. S. Mechanical Engineers' Hand-
book. McGraw-Hill Book Co., Inc., New York,
1951.
  Perry, J. H. Chemical Engineers' Handbook.
McGraw-Hill Book Co., Inc., New York, 1900.
  Shlgehara. R. T., W.  F.  Todd. and  W. S.
Smith. Significance of Errors in Stack Sam-
pling Measurements.  Paper presented at  the
Annual Meeting of the Air Pollution Control
Association.  St. LOuis, Mo.,  June 14-19, 1970.
  Standard Method for Sampling Stacks for
Partlculate Matter. In:  1971  Book of ASTM
standards. Part 23. Philadelphia, 1971. ASTM
Designation D-2928-71.
  Vennard, J. K. Elementary Fluid Mechanics.
John Wiley and Sons, Inc., New York, 1947.
METHOD 3	CAS ANALYSIS FOR CARBON DIOXIDE,
   EXCESS AIR, AND DRY  MOLECULAR WEIGHT
  I. Principle and- applicability,
  1.1  Principle.  An  Integrated  or  grab  gas
sample Is extracted from a sampling  point
and analyzed for Its  components using an
'Orsat analyzer.
  1.2  Applicability. This method should be
applied only when specified by the  test pro-
cedures for determining compliance with New
Source Performance Standards.
  2. Apparatus.
  2.1  Grab sample (Figure 3-1).
  2.1.1  Probe—Stainless  steel  or  Pyrex'
glass, eqxiipped with  a filter to remove par-
tlculate matter.
  2.1.2  Pump—One-way squeeze, bulb,  or
equivalent, to transport gas sample  to ana-
lyzer.
  2.2  Integrated  sample (Figure 3-2).
  2.2.1  Probe—Stainless  steel  or  Pyrex»
glass equipped with a filter to remove par-
tlculate matter.
  2.2.2  Air-cooled  condenser—To   remove
any excess moisture.
  2.2.3  Needle valve—To adjust flow rate.
  2.2.4  Pump—Leak-free,  diaphragm  type,
or equivalent,-to pull gas.
  2.2.5  Rate motor—To measure a flow range
from 0 to 0.035 c.f jn.
  2.2.G  Flexible bag—Tedlar,* or equivalent,
•with ti capacity of 2 to 3 cu. ft. Leak test  the
bag In the laboratory before using.
  2.2.7  Pitot tube—Type S, or equivalent,
attached to the probe so that the sampling
flow rate can be regulated proportional to the,
etack gas velocity when velocity is varying
with time or a sample traverse is conducted.
  2.3  Analysis.
  2.3.1  Orsat analyzer, or equivalent.
  3. Procedure.
  "3.1  Grab sampling.
  3.1.1  Set  up the equipment as shown In
Figure 3-1. Place the probe In the stack at a
campling point and purge the sampling line.
                                                                                          1 Trade name.
                                                       Environment Reporter

-------
 CURRENT  DEVELOPMENTS
                                                                                                                              485
                    PROBE
KV
                          FLEXIBLE TUBING
 FILTER (GLASS WOOL]
                                            SQUEEZE BULB
                          Figure 3-1.  Grab-sampling train.

                                             RATE METER
                                   VALVE
          AIR-COOLED CONDENSER
     PRODE
                                                                  QUICK DISCONNECT
 FILTER (GLASS WOOL)
                Figure 3-2.  Integrated gas - sampling train.

                                            where:
  3.1.2  Draw sample into  the  analyzer.
  3.2  Integrated sampling.
  3.2.1  Evacuate tlie flexible bag. Set up the
equipment as shown In Figure  3-2  with the
bag  disconnected. Place the probe In the
stack and purge the sur.ipling line. Connect
the  bag, making sure that all  connections
(ire tight and that there arc no leaks.
  3.2.2  Sample at a rate proportional to the
stack gas velocity.
  3.3  Analysis.
  3.3.1  Determine the CO-. Oo. and CO con-
centrations as soon as possible. Make ar.  many
passes as arc  necessary to give constant read-
Ings. If more than 10 passes are necessary,
replace the absorbing solution.
  3.3.2  For integrated sampling, repeat the
analysis  until three  consecutive runs vary
no more than 0.2 percent by volume for each
component being analyzed.
  4.  Calculations.
  4.1  Carbon dioxide.  Average  the  three
consecutive  runs and report result to the
nearest 0.1 percent CO-'.
  4.2  Excess air. Use Equation 3-1 to cal-
culate excess air,  and average the runs. Re-
port the result  to  the  nearest 0.1 percent
excess uir.
                          ^cEA = Percent excess air.
                           ?iO.,=Percent  oxygen  by  volume,  dry
                                  basis.
                           %N.,r:Pcrccnt  nitrogen by  volume,  dry
                                  basis.
                          •X CO = Percent  carbon  monoxide by vol-
                                  ume, dry basis.
                          0.2G4 = Ratlo  of oxygen to  nitrogen in air
                                  by volume.

                          4.3   Dry molecular weight. Use Equation
                        3-2 to calculate dry molecular -weight and
                        average the runs.  Report the result  to  the
                        nearest tenth.

                               Md:=0.44(% CO..) -|-0.32(% O,)
                                   + 0.28(% N,+ % CO)
                                                      Equation 3-2
                        where:
                               d = Dry   molecular
                                    mole.
OsH-O.oCVi CO)X10°
          equation 3-1
                                         carbon dioxide by .volume,
                                   dry basis.
                           %O.,:= Percent  oxygen  by  volume, dry
                                   basis,
                           ?iN., = Pcrccnt  nitrogen by volume, dry
                                   basis.
                           0.44 = Molecular weight of carbon dioxide
                                   divided by 100.
                           0.32 = Molecular   weight   of   oxygen
                                   divided by 100.
                           0.28 = Molccular  weight   of  nitrogen
                                   divided by 100^
               5. Reference}
TO ANALYZER   Altshullcr,  A.  P., et al. Storage of Oases
             and Vapors in Plastic  Bags.  Int. J. Air &
             Water Pollution. 6':75-3l. 19U3.
               Conner, William D., and J. S.  Nader.  Air
             Sampling with Plastic Bags.  Journal of  the
             American Industrial Hygiene Association.
             25:291-297. May-June 1964.
               Dovorkin,  Howard, et  al.   Air  Pollution
             Source Testing Manual. Air Pollution Con-
             trol District. Los  Angeles. November 19G3.

             METHOD 1—DETERMINATION OF  MOISTUKE  IN
                            STACK CASES
               1. Principle and applicability.
               1.1  Principle. Moisture Is  removed from
             the gas stream, condensed, and determined
             gravlmotrically.
               1.2  Applicability.  This  method Is appli-
             cable for the determination  of moisture in
             stack gas only when  specified by test proce-
             dures for determining compliance with New
            Source Performance Standards. This method
            does not apply when liquid droplets are pres-
            ent In the gas stream.2
              Other methods such as  drying tubes, wet
            bulb-dry bulb techniques, and volumetric
            condensation  techniques may  be  used sub-
            ject to the approval of the Administrator.
              2. Apparatus.
              2.1  Probe—Stainless steel or Pyrex l glass
            sufficiently heated  to prevent conder.sai.ion
            and equipped with a filter to remove par-
            tlculate matter.
              2.2  Impingers—Two  midget   Implngers,
            each with 30 ml. capacity, or  equivalent.
              2.3 Ice   bath  container—To   condense
            moisture In impingers.
              2.4: Silica gel tube—To protect'pump and
            dry gas meter.
              2.5 Needle valve—To regulate  gas flow
            rate.
              2.6 NPump—Leak-free, diaphragm type, or
            equivalent, to pull gas through train.
              2.7 Dry gas meter—To measure to within
            1 percent of the total sample  volume.
              2.8 Rotamcter—To measure a flow range
            from 0 to 0.1 c.f.in.
              2.9 Balance—Capable of measuring to the
            .nearest 0.1 g.
              2.10   Barometer—Sufficient   to   read  to
            within 0.1 in. Hg.
              2.11   Pilot tube—Type S. or  equivalent, at-
            tached  to  probe  so that the  sampling now
            rate can be regulated proportional  to  the
            stack gas velocity  when velocity  Is varying
            with time or a sample  traverse Is conducted.
              3. Procedure.
              3.1 Place about 5 ml. distilled  water in
            each implnger and weigh the implm-er and
            contents to the nearest  0.1 g.  Assemble the
            apparatus without the probe as shown in Fig-
            ure 4-1.  Leak check by plugging the inlet to
            the first  Implnger and drawing a vacuum. In-
            sure that flow through the dry gas meter is
            less  than 1 percent of the sampling rate.
              3.2 Connect the probe,  and sample at a
            constant rate of 0.075 c.f.m. or'at a rate pro-
            portional to the stack gas velocity  not to ex-
            ceed 0.075 c.f.m. Continue sampling until the
            dry gas meter registers 1 cu. ft. or until visible
            liquid droplets arc carried over from the lirst
            Implnger to the second. Record temperature,
            pressure, and  dry gas meter reading as re-
            quired by Figure 4-2.
              3.3  After collecting the sample, weigh the
            Impingers and their  contents  again  to  the
            nearest 0.1 g.
                                                  weight,  lb./lb.-
                                                                                          i Trade name.
                                                                                          - If  liquid droplets arc present In  the  gas
                                                                                        stream, assume the stream to be saturated,
                                                                                        determine the average stack gas temperature
                                                                                        (Method  !). and  use a  psychromctrlc  chart
                                                                                        to obtain nn  approximation of the moisture
                                                                                        percentage.
                                    Copyright <£ 1971 by The Bureau of National  Affairs, Inc.

-------
 486
                                                                                                ENVIRONMENT REPORTER
  1. Calculation}.
  4.1  Volume of water collected.
                   (o.0474 — )(Wf-\V,)
                   \       D* /

                            equation 4-1
where:
  Vwo=Volume  of water  vapor collected
          (standard conditions), cu. ft.
                     Wt=Flnal  -weight  of  Implngcrs  and
                            contents, p.
                     Wi.=:lnltlal  weight  of  lonpingers  and
                            contents, g.
                      R= Ideal gas constant. 21.83-ln. Hg —
                            cu. ft./lb. mole-* R.
                    T,,4=.' 'isolute temperature  at standard
                            conditions, 530° R.
                    P. 14=: Pressure  at  standard   conditions,
                            29.92 in. Hg.
                     M»=Molecular  weight  of   water,   18
                            Ib./lb. mole.
   4.2  Gas volume.
                                        SILICA GEL TUBE
      HEATED PROBE
FILTER'(GLASS Y/OOL)
                                                                        ROTAMETER
                                                                  DRY GAS METER
           ICE BATH
           LOCATION.
           TEST	
           DATE	
           OPERATOR.
Fiflure 4-1. Moisture-sampling train.

       ._  . .                    COMMENTS
           BAROMETRIC PRESSURE,
CLOCK TIME





GAS VOLUME THROUGH
METER, ivmi,
it3





ROTAMETER SETTING,
Ii3/min





METER TEMPERATURE.
°F





               in. Hg/  ,Tm   equation 4-2
 where:
   Voc=Dry gas volume through meter at
           standard conditions, cu. ft.
    Vm=Dry gas volume measured by meter,
           cu. ft.
    PH=:Barometric  pressure at the  dry gas
           meter, In. Hg.
   P.,d=Prcssure  at  standard  conditions,
           29.92-in. Hg.
   T,td=Absolute temperature  at standard
           conditions, 530° R.
    Tin =: Absolute  temperature   at   meter
           ("F.+4GO), °R.
   4.3  Moisture content.
                                                                                      B.
                                                                                           "vwo+vn
                                                                                             -+ (0.025)
                         Figure 4-Z. Field moislurc dctermlnalion.
                              equation 4-3
 where:
   Bwo=ProportIon  by  volume  of  water
          vapor  in  the  gas  stream, dimen-
          slonless.
   Vwc =;Volume  of water  vapor  collected
          (standard conditions), cu. ft.
   Vme=Dry  gas  volume   through  meter
          (standard conditions), cu. ft.
  B»m=Approximate volumetric proportion
          of water vapor in the gns stream
          leaving the  Impingers, 0.02S.
  6. References.
  Air   Pollution   Engineering   Manual,
Danlclson,  J. A.  (ed.).  U.S. DHEW, PUS,
National  Center  for Air Pollution Control.
Cincinnati,   Ohio.  PHS  Publication  No.
999-Ap-30. 1967.
  Devorkln,  Howard,  et al.  Air  Pollution
Source Testing Manual.  Air  Pollution Con-
trol  District.  LOF Angeles, Calif. November
1963.
  Methods  for Determination  of  Velocity,
Volume,  Dust and  Mist Content  of Gases.
Western Precipitation Division of Joy Manu-
facturing Co., Los  Angeles,  Calif.  Bulletin
WP-50. IOCS.
METHOD  5.	DETERMINATION  OF PARTICULATE
     EMISSIONS FROM STATIONARY SOURCES

  1. Principle and applicability.
  1.1  Principle.  PartlculrUe  matter is with-
drawn isokinetlcnlly from the source and its
weight Is determined  gravimctrlcally after
removal of uncomblncd water.
  1.2  Applicability. This method is applica-
ble  for  the  determination  of paniculate
omissions from stationary sources only when
specified by the  test procedures for deter-
mining compliance  with New  Source  Per- .
formancc Standards.
  2. Apparatus.
  2.1  Sampling train. The design specifica-
tions of the participate sampling train used
by EPA (Figure 5-1) are  described in AFTD-
0581. Commercial models of this  train  arc
available.
  2.1.1  Noszle—Stainless  steel  (31G)  with
sharp, tapered leading cdne.
  2.1.2  Probe—Pyrcx» (;lass  with a  heating
system capable of maintaining a gas tempera-
ture of  250° F.  (U the  exit  end during
sampling.  When  temperature  or  length
limitations  are  encountered, 310 stainless
steel, or equivalent, may bo used, as approved
by the Administrator.
                                                     Environment Reporter

-------
CURRENT DEVELOPMENTS
                                                                                      487
  2.1.3  Pilot  tube—Type S. or equivalent,
attached to  probo  to  monitor  stack  gas
velocity.
  2.1.4  Filter  holder—Pyrex1  glass  with
beating system capable of maintaining any
temperature to a maximum of 225° F.
  2.1.5  Implngers—Four  Implngers  con-
nected In series with glass ball Joint fittings.
The first, third, and fourth Impingers are of
the Greenburg-Smith design, modified by re-
     placing the tip with a Vi-lnch m glass tube
     extending to  ',2-Inch from the bottom of the
     flask. The second implnger Is of the Grcen-
     burg-Smith design with the standard tip.
       2.1.0  Metering  system—Vacuum  gauge,
     leak-free  pump, thermometers capable  of
     ...--•asuring temperature to within 5° F., dry
     gas meter with 2 percent accuracy, and re-
     lated equipment, or equivalent, as required
     to maintain an isokineUc sampling rate and
     to determine sample volume.
       PROBE
REVERSE-TYPE
 PITOT TUBE
                             HEATED AREA  FyILTER HOLDER    THERMOMETER    CHECK
                                                                            VALVE
                                                                             VACUUM
                                                                               LINE
             PITOT MANOMETER

                      ORIFICE
IMPINGERS             ICE BATH
        BY-PASS VALVE

          J/
         rtXh-
                                                               VACUUM
                                                                GAUGE
                                                     I. MAIN VALVE
                                   y-
                        DRY TEST METER
     AIR-TIGHT
       PUMP
                          Figure 5-1.  Particulatc-sampling train.
  2.1.7  Barometer—To measure atmospheric
pressure to ±0.1 in. Hg.
  2.2  Sample recovery.
  2.2.1  Probe  brush—At least  as long ag
probe.
  2.2.2  Class wash bottles—Two.
  2.2.3  Glass sample storage containers.
  2.2.4  Graduated cylinder—250 ml.
  2.3  Analysis.
  2.3.1  Glass weighing dishes.
  2.3.2  Desiccator.
  2.3.3  Analytical balance—To  measure to
±0.1 ing.
  2.3.4  Beakers—250 ml.
  1 Trade name.
       2.3.5  Separatory  funnels—500  ml.  and
     1,000 ml.
       2.3.G  Trip balance—300  g.  capacity, to
     measure to ±0.05 g.
       2.3.7  Graduated cylinder—25 ml.
       3. Reagents.
       3.1  Sampling
       3.1.1  Filters—Glass  fiber, MSA  1106 BH,
     or equivalent, numbered for  Identification
     and prewclghcd.
       3.1.2  Silica gel—Indicating  type, 6  to 16
     mesh, dried at 175° C. (350° F.)"for 2 hours.
       3.1.3  Water—Deionlzed, distilled.
       3.1.4  Crushed Ice.
       3.2  Sample recovery
       3.2.1  Water—Delonized, distilled.
   3.2.2  Acetone—Reagent grade.
   3.3  Analysis
   3.3.1  Water—Dclonteed, distilled.
   3.3.2  Chloroform—Reagent grade.
   3.3.3  Ethyl ether—Reagent grade.
   3.3.4  Desiccant—Drlerlte,1 Indicating.
   4. Procedure.
   4.1  Sampling.
   4.1.1  After selecting the sampling site and
 the  minimum number of sampling points,
 determine the stack pressure,  temperature,
 moisture, and range of velocity head.
   4.1.2  Preparation   of  collection  train.
 Weigh to  the nearest  gram approximately
 200  g. of silica gel. Label a niter  of proper
 diameter, desiccate3 for at least  24 hours
 and weigh to the nearest  0.5 mg. in a room
 where the  relative humidity  Is  less  than
 50 percent. Place 100 ml. of water in each of
 the  first two  Impingers. leave the  third 1m-
 plnger empty, and place approximately  200
 g. of prcweighed silica  gel in the fourth im-
 plnger. Save  a portion of  the  water for  use
 as a blank in  the sample analysis. Set up  the
 train without the probe  as in Fitrure  5-1.
 Leak check the sampling  train at "the sam-
 pling site by  plugging  the inlet to the filter
 holder and  pulling a  15-in. Hg vacuum. A
 leakage rate  not in excess of 0.02 c.f.m. at a
 vacuum  of  15-in.  Hg  Is acceptable. Attach
 the probe and adjust the heater to  provide a
 gas  temperature  of  about  250°  F.  at  the
 probe  outlet.  Turn on the filter heating sys-
 tem. Place crushed Ice around the Impingers.
 Add more Ice during the run to keep the tem-
 perature of the  gases  leaving  the last im-
 plnger at 70° F. or less.
   4.1.3  Partlculate train operation. For each
 run  record the data required on the example
 sheet  shown  In  Figure 5-2. Take  readings
 at each sampling point at least  every 5 min-
 utes and when significant changes 'in stack
 conditions  necessitate  additional  adjust-
 ments in flow rate. To  begin sampling, po-
 sition  the nozzle at the first traverse point
.with the tip  pointing  directly  into the gas
 stream. Immediately start the pump and aci-
 Just the  flow  to IsokineUc  conditions. Main-
 tain  Isokinetlc  sampling  throughout  the
 sampling period. Nomographs  are  available
which  aid In the rapid adjustment of the
sampling  rate without other computations.
APTD-057G details the procedure for  using
 these nomographs. Turn off the  pump at the
 conclusion of  each run and record  the final
readings. Remove the probe and nozzle from
the stack and  handle in accordance with the
sample recovery process described in section
4.2.
                                                                                         "Dry using Drlerlte' at 70"±10' F.
                                   Copyright £  1971 by The  Bureau of Notional Affairs,  Inc.

-------
.488
                                                                                             ENVIRONMENT REPORTER
          KANT	

          IOCATIOM	

          OPERATOR	

          DATE	i__

          RUN.NO.	

          SAMPLE BOX N0j_

          DETER BOX N0._

          METER AH,	
                 *i"
          C FACTOR	
                                                . AMBIENT TEMPERATURJE.

                                                 BAROMETRIC PRESSURE.

                                                 ASSUMED MOISTURE.'.',_

                                                 HEATER BOX SETTING	

                                                 PROBE LENGTH, in.	

                                                 NOZZLE DIAMETER, in. _

                                                 PROBE HEATER SETTING,
                                                SCHEMATIC OF STACK CROSS SECTION
TRAVERSE POINT
NUMBER











-
TOTAL
SAMPLING
TIME
(«). min.













AVERAGE
STATIC
PRESSURE
(P^l. in. Hg.














STACK
TEMPERATURE
|T5).'F














VELOCITY
HEAD
I * PS'.














PRESSURE
DIFFERENTIAL
ACROSS
ORIFICE
METER
1 a HI.
in. H20














GAS SAMPLE
VOLUME
(Vm). It3














GAS SAMPLE TEMPERATURE
AT DRY GAS METER
INLET
ITminl.°F












Avg.
OUTLET
""oui'-'F












Avg.
Awg.
SAMPLE BOX
TEMPERATURE.
°F








•





IMPINGER
TEMPERATURE.
"F














                                                           Figure 5-2.  Paniculate field data.
  4.2  Sample recovery. Exercise care In mov-
ing the collection train from the. test site to
tho sample recovery area to minimize the loss
of collected sample  or the gain of .extraneous
participate  matter.  Set aside portions of  the
water and acetone used in the sample recov-
ery as blanks for analysis. Place the samples
In containers as follows:
  Container No.  1. Remove the  filter from its
holder, place in  this container, and seal.
  Container No. 2. Place loose  paniculate
matter and acetone washings from all sam-
ple-exposed surfaces prior to the niter in this
container and seal.  Use a razor blade, brush,
or rubber policeman to loosen adhering par-
ticles.
  Container No. 3.  Measure  the  volume of
water from  the first three  impingers and
place the water in this container. Place water
rinsings of all sample-exposed surfaces be-
tween the filter and fourth impinger in tills
container  prior to  sealing.
  Container No. 4.  Transfer  the silica gel
from  the  fourth impinger  to the  original
container  and  seal. Use a rubber policeman
as an aid In removing silica gel from the
impinger.
  Container No. 5. Thoroughly rinse  all  sam-
ple-exposed surfaces between  the filter and
fourth Impinger with  acetone,  place  the
washings in this container, and seal.
  4.3  Analysis. Record the data-required on
the example  sheet  shown  In Figure 5-3.
Handle each sample container as follows:
  Container No. 1. Transfer the filter  and any
loose  paniculate matter  from the  sample
container to a tared glass weighing dish, des-
slcate, and dry to a constant weight. Report
results to the nearest 0.5 mg.
  Container No.  2. Transfer  the acetone
washings to a tared beaker and evaporate to
dryness at ambient temperature and  pres-
sure. Dessicate and dry to a constant weight.
Report results to the nearest 0.5 mg.
  Container No. 3. Extract organic paniculate
from the Impinger solution with three 25 ml.
portions of chloroform.  Complete  the ex-
traction with three  25  ml. portions of  ethyl
ether. Combine the ether and chloroform ex-
tracts, transfer to a  taj-cd beaker and evapo-
rate at 70° F. until nn solvent remains. Des-
sicate, dry to a constant weight, and report
the results to the nearest 0.5 mg.
Evaporate the  rr-.-maining
wator  portion  at  2l2°Fo
Dessicato the  residue, dry
to a constant weight,  and
report   the  results  to  the
nearest  0<>5 rog°
  Container  Noo  4o   Weigh the
spent  silica  gel  and report
to the   nearest  gram.
                                                   Environment Reporter

-------
 CURRENT DEVELOPMENTS
                                                                                 489
                             PLANT.

                             DATE
                             RUN N0._
CONTAINER
NUMBER
1
2
3a«
3b'»
5
TOTAl
WEIGHT OF PARTICULATE COLLECTED,
mg
FINAL \VEIGHT





Z^x^I.
TARE WEIGHT





z^xci
WEIGHT GAIN






                           *3a - ORGANIC EXTRACT FRACTION.
                          *'3b • RESIDUAL WATER FRACTION.

FINAL
INITIAL
LIQUID COLLECTED
TOTAL VOLUME COLLECTED
VOLUME OF LIQUID
WATER COLLECTED
IMPINGER
VOLUME,
ml




SILICA GEL
WEIGHT,
g



9* ml
    •CONVERT WEIGHT OF WATER TO VOLUME BY DIVIDING TOTAL WEIGHT
     INCREASE BY DENSITY OF WATER.  (1 g/ml):
                                              g
                                         g/ml)
                                                 = VOLUME WATER, ml
                       Figure 5-3. Analytical data.
  Container No.  5.  Transfer  the  acetone
washings to a tared beaker and evaporate to
dryncss at, nmbicnt temperature and pres-
sure. Desiccate, dry to a constant weight, and
report  the results, to the nearest 0.5 jng.
  5. Calibration.
  Use stand.ird  methods and equipment ap-
proved  by the  Administrator to  calibrate
the orllice meter,  pilot tube, dry gas meter,
and probe heater.
  C. Calculations.
  0.1   Sample concentration method.
  6.1.1   Average dry gas meter temperature.
See data sheet (Figure 5-2).
  C.1.2   Dry gas volume. Correct the sample
volume  measured by  the dry gr\s meter to
standard conditions (70° P., 29.92 in. HE) by
using Equation 5-1.
                                            where:
                                             Vm,w=Volume of gas sample through the
                                                      dry  gas  meter (standard condi-
                                                      tions), cu. ft.
                                                Vm=Volumc of gas sample through the
                                                      dry gas meter (meter conditions) ,
                                                      cu. ft.
                                               T,M=:Absolute temperature at  standard
                                                      conditions, 530 °R.
                                                Tm = Avernge dry gas meter temperatxire,
                                                      °R.
                                               PH,= Barometric  pressure nt the orifice
                                                      meter, In. Hg.
                                                AH=Pressure  drop  across  the orifice
                                                      meter, In H.O.
                                               13.6=Spcclfic gravity of mercury.
                                               P.ta= Absolute pressure at standard con-
                                                      ditions, 29.92 In. Hg.
                                             6.1.3  Volume of Water vapor.
                                                                                      v    -
                                                                                       "•ld~
                                                                   (0.
                                                                                                                .0474
                                                                                                                   equation 5-2
                                           where:
                                             Vw,(d=Volume of water vapor In the gas
                                                      sample (standard conditions) , cu.
                                                      ft.
                                               Vic=Total volume of liquid collected In
                                                      Implngers and silica gel (see Fig-
                                                      ure 5-3) , ml.
                                               pnao=Denslty of water, 1 g./ml.
                                              Mn.,o = Molecular weight of water, 18 Ib./lb.
                                                      mole.
                                                 R=Ideal gas constant, 21.83 In Hg-cu.
                                                      ft./lb. mole-°R.
                                               T.,j = Absolute temperature  at standard
                                                      conditions, 530" R.
                                               P,(d:= Absolute pressure at standard con-
                                                      ditions. 29.92 In. Hg.
                                                                                        6.1.4  Total gas volume.
                                                                                      where:
                                                                                        v
                                                                                                                    equation 5-3
                                               «ot.i— Total volume of gas sample (stand-
                                                      ard conditions) , cu. ft.
                                             Vmild=: Volume  of  gas through  dry  gas
                                                      meter  (standard conditions), cvi.
                                                      ft
                                             V«-,ld— Volume of water vapor In the gas
                                                      sample (standard conditions) , cu.
                                                      ft.
                                             0.1.5  Total participate weight. Determine
                                           the total partlculatc catch from the sum of
                                           the weights on the analysis  data sheet (Fig-
                                           ure 5-3).
                                             6.1.6  Concentration.
                                                   c.'=(o.
                                            015-l-t--   rf-~
                                                                                                           ing
                                                         cquation .">—i
                            where:
V    =v   -'•'•'•
'"'"•'   Vl"VTm
          17.71
—'M(v
in."]lB/°'
                                   mr»
                             equation 5-1
    c'i = Concentratlon of partlculatc matter
           In stack gas (Sample Concentra-
           tion Method), gr./s.c.f.
    Mn=Total amount of partlculate  mat-
           ter collected, mg.
  V,oU1=:Total volume of gas sample (stand-
           ard conditions), cu. ft.
  6.2  Ratio of area method.
  C.2.1  Slack Ras velocity. Collect the neces-
sary data ns detailed In Method 2. Correct the
                                   Copyright C 1971 by  The Bureau of Notional  Affairs, Inc.

-------
    s-cack  gas velocity to  standard conditions
    (29.92 in. Kg. 530'' R.) as follows:
a
•°   y..*-1
                _
                in. Ji
                             -
                           T. /   equation 5-5
"3
^   where:
I1"1     V.,,d = Stack gas velocity at standarc". con-
              ditions, ft./sec.
u

             Mn  A,
    . _M._ 9   A
                                                V.=Stack  gas velocity calculated by
                                                       Method 2,  Equation  2-2, ft./sec.
                                                P.=Absolute stack gas pressure. In. Hg.
                                               P. ti=Absolute pressure at standard con-
                                                       tions. 29.92 In. Hg.
                                               T,,,,=Absolute  temperature  at  standard
                                                       conditions. 530° R.
                                                T. = Ab-;o!ute  stuck  gas   temperature
                                                       (average),  '-R.

                                              6.2.2  Concentration.
m
3
T>
O
    where:
         Ci = Concentration of paniculate matter
               in  the stack gas (Ratio  of Area
               Method), gr./s.c.f.
        M.=Particulate mass flow rate through
               the stack (standard conditions),
               mass/time.
        Q.=Vo!umetrlc now rate of gas stream
               through the stack (standard con-
               ditions) . volume/time.
                                                     Mn = Total amount of partlculate matter
                                                           collected by train, mg.
                                                       6 = Total sampling time, mln.
                                                     Ai = Cross-sectional area of stack, sq. ft.
                                                     Ar, = Cross-sectional area of nozzle, sq. ft.
                                                   V.^rrStack gas  velocity at standard con-
                                                           ditions, ft. /sec.

                                                   6.3   Isokinetlc variation.
                                                    X100 =
  c'. = Concentration of partlculate matter
        In the stack gas (Sample Concentra-
        tion Method), gr./s.c.f.
7. References.
  Addendum to Specifications for Incinerator
Testing at Federal  Facilities.  PHS, NCAPC.
Dec. 6, 1967.
  Martin. Robert M. Construction Details of
Isokinetlc Source Sampling Equipment. En-
vironmental  Protection  Agency,  APTD-0581.
  Rom,  Jerome J. Maintenance,  Calibration,
and Operation  of Isokinetlc Source Sampling
Equipment.    Environmental    Protection
Agency. APTD-O576.
  Smith,  W. 'S.; R.  T. Shlgehara, and W. F.
Todd. A Method of  Interpreting Stack Sam-
pling  Data. Paper prc.sp.nlcd at  the  6:!d
Annual Meeting of the Air Pollution Control
Association, St. Louis. June 14-19.  1U70.
  Smith. W. S.. i:-t al. Stack Gas Sampling Im-
proved sind Slmplilied with New Equipment.
APCA Paper No. 67-119. 19G7.
  Specifications for Incinerator  Testing at
Federal Facilities. PHS, NCAPC. 1907.

METHOD 6—DETERMINATION OF SULFUR DIOXIDE
    EMISSIONS  FROM STATIONARY  SOUP.CES

  1. Principle  and applicability.
  1.1  Principle. A gas sample  Is  extracted
from the sampling point In the stack, and
the acid mist' Including sulfur trioxide  Is
separated from the sulfur dioxide. The sulfur
dioxide fraction Is measured by  the barluin-
thorln tltratlon method.
  1.2  Applicability. This method Is appllca-
                                    flV.P.A.

where:
      I = Percent of isokinetlc sampling.
    Ct = Concentration of particulate matter
           In  the  stack gas (Ratio of-Area
           Method), gr./s.c.f.
    C ; =Concentration of particulate matter
           in the stack gas  (Sample Concen-
           tration Method), gr./s.c.f.
    Vic = Total  volume of liquid  collected In
           impingers and silica gel (see  Fig-
           ure 5-3) .ml.
   CM '< = Den.si-.y of water. 1  g./ml.
     R = Iolea!  gas constant. 21.83 in. Hg-cu.
           ft./lb. mole-' R.
  MM_.o=Molecular weight of water, 18 Ib./lb.
           mole.
    Vm = Volume of gas sample thro\:gh  the
           dry gas meter (meter conditions),
           cu. ft.
    Tm = Absolute average dry  gas meter tem-
           perature (see Figure 5-2). "R.
   Pl,.t=Baromotric  pressure at  sampling
           site, in  Hg.
    AH=Aver:ige pressure drop across the ori-
           fice (see Figure 5-2). in HSO.
    T. = Abso!ute  average stack ga.i tempera-
           ture (see Figure 5-2), 'R.
                                                                               equation 5—7

                                                       6 — Total sampling time, mln.
                                                     V. = Stack  gas  velocity  calculated  by
                                                            Method 2,  Equation 2-2, ft./sec.
                                                     P. = Absolute stack gas pressure, In. Hg.
                                                     An = Cross-sectional area of nozzle, sq. ft.
                                                   6.4   Acceptable  results.  The   following
                                                 range sets the limit on acceptable  Isoklnetio
                                                 sampling results:
                                                 If 82 percent  glass,  approximately
5-6 nun. ID, with a heating system to prevent
condensation and a filter to remove partlcu-
late matter Including sulfurlc acid mist.
  2.1.2  Midget  bubbler—One,  with  glass
wool packed iu top to prevent sulfurlc acid
mi.st carryover.
  2.1.3   Glass wool.
  2.1.4   Midget Impingers—Three.
  2.1.5   Drying tube—Packed  with 6  to  16
mesh  Inciicatlng-type  silica  gel  or equiva-
lent, to dry the sample.
  2.1.6  Pump—Leak-free, vacuum type.
  2.1.7  Rate meter—Rotameter, or equiva-
lent, to measure a 0-10 s.c.f.h.  flow range
  2.1.8  Dry gas meter—Sufficiently accurate
to  measure  the  sample volume  within  1
percent.
  2.1.9  Pilot tube—Type  ^. or equivalent,
necessary  only if a  sample traverse  Is  re-
quired or If stack gas velocity  varies with
 time.
   2.2   Sample recovery.
   2.2.1  Glass wash bottles—Tv/o.
   2.2.2  Polyethylene  storage   bottles—To
store Impingcr samples.
   2.3   Analysis.
                                                                                                                                             1 Trade name.
   PROBE (END PACKED
   WITH QUARTZ OR
   PYREX WOOL)
                                                                                                                         STACK WALL

                                                                                                                                   MIDGET BUBBLER MIDGET IMPINGERS'

                                                                                                                             GLASS WOOL
                                                                                                                                                                 SILICA GEL DRYING TUBE
                                                                                                              V-
                                                                                                               /
                                                                                                   TYPE S PITOT TUBE
                                   /
                        PITOT MANOMETER
                                                                                                                                DRY GAS METER    ROTAMETER
                                                                                                                              Figure 6-1. S02 sampling train.
                                                                                                                                                                                         m
                                                                                                                                                                                         •z.
                                                                                                                                                                                         <
                                                                                                                                                                                         3!
                                                                                                                                                                                         O
                                                                                                                                                                                         •z.
                                                                                            H
                                                                                            3)
                                                                                            m
                                                                                            -o
                                                                                            O
                                                                                            33
                                                                                            m
                                                                                            33

-------
                RESULTS OF LABORATORY  ANALYSES FOR BERYLLIUM
Sample No.
37
38
39
40
41
42
42A
43
44
45
46
47
48
48A
49
50
51
52
53
54
54A
55
56
57
58
59
60
60A
61
62
63
64
65
66
66A
69
70
Code
Be-SI-N-1-G
Be-SI-N-1-G-F
Be-SI-N-1-G-I
Be-SI-N-1-MP-P
Be-SI-N-1-MP-F
Be-SI-N-1-MP-I
Be-SI-N-1-GB
Be-SI-N-2-G-P
Be-SI-N-2-G-F
Be-SI-N-2-G-I
Be-SI-N-2-MP-P
Be-SI-N-2-MP-F
Be-SI-N-2-MP-I
Be-SI-N-2-GB
Be-SI-M-1-G-P
Be-SI-M-1-G-F
Be-SI-M-1-G-I
Be-SI-M-1-MP-P
Be-SI-M-1-MP-F
Be-SI-M-1-MP-I
Be-SI-M-GB
Be-SI-S-1-G-P
Be-SI-S-1-G-F
Be-SI-S-l-G~I
Be-SI-S-1-MP-P
Be-SI-S-1-MP-F
Be-SI-S-1-MP-I
Be-SI-S-1-GB
Be-SI-S-2-G-P
Be-SI-S-2-G-F
Be-SI-S-2-G-I
Be-SI-S-2-MP-P
Be-SI-S-2-MP-F
Be-SI-S-2-MP-I
Be-SI-S-2-GB
Be-SI-G-Blank
Be-SI-MP-Blank
yg Be *Total yg Be
3.13~\
0.15 V * H.23N
7.95 J L **
0.45"^ f
0.30 1 * 13 80 J
12.50 f I<3>OU J
0.55J
3.05^ _n^
0.30 \ * 3.70^
0.35 J I **
0.00^ {
0.00 L * 1>90 J
1.90 (
0.00 J
°-60 ^ i A* -^
0.00 \ * K45^
0.85 J > **
0.20S
0.05 1 * 1.30 J
0.90 f
0.15J
1 .68 S _ c~
0.25 (• * 7.53^\
5.60J / ^
0.95"N [
^'QQ > * 12 50 }
10.00 f l*'w
0.55J
0.55-^
0.00 > * 1-65-N
1-ioJ L **
I \
0.45 J- * 5.80 )
0.95
3.30J
0.40
0.15
 * Total yg Be per run
** Denotes that the two particulate runs  were accomplished at the same time, in the
   same stack with a separate  probe (two  probes total)  for each run.

                                       -31-

-------
                   PROJECT PARTICIPANTS
Name
Title
John Koogler, Ph.D., P.E.
John Dollar, E.I.T., MS
Ray Black, B.S.
Joe Yarborough,  B.S.
Robert Durgan, Tech.
Project Director
Project Manager
Environmental Specialist
Environmental Specialist
Environmental Specialist
                              -32-

-------
                                              SOURCE SAMPLING FIELD DATA SHEET
Plant.
Sampling Location.
Dato    «g"" /O ~
Time Starts/a:.
Sampling Time/Point
Moisture

Barcmotric Press
Weather

Temp.
Samplo Box Ho.
                           Dansity Factor,

                          Stack Press. 	
                        _"Hg
               LUW/D    —.    . W/S
                    ., Meter Box No
Meter A H§
Nozslo Dia.
                Pitot Corr. Factor
_in.f Proba Length.
                                             ft
Probe Heater Setting   " "*
Stack Dimensionsi   Inside  Diameter
                   Inside Area
                   Height He&i
                                     lift
                                ar  _J***  ,
                                on%5<4
                        __i°
                        _ft2
                          ft
                                                 Sketch Of Stack i
                                                                             Mat*l Processing Rate	
                                                                             Final Gas Meter Reading.
                                                                             Initial Gas Meter Reading.
                                                                             Total Condensate In Impingers_
                                                                             Moisture  In Silica Gel.2S&O- 237. ^ *"
                                                                             Silica Gel Container Mo. /  .Filtor No.
                                                                             Orsati   C02    <	

                                                                                      °2     	
                                                                                      CO     	
                                                                                                                      .ft3
                                                                                                                       ml
                                                                                     N2
                                                                                     Excess
                                                                                        Air
                                                                             Test Conducted Byi
                                                                            Remarks t
Port And
Traverse
Point No.
            Distance
            From End
            Of Port
             (in)
                       Clock
                       Time
           Gas >feter
           Reading
            (ft3)
Stack
Velocity
Head
("H20)
Meter
Orifice
Press. Diff.
  C'H?0).
                                                      Calc.  victual
Stack Gas
Temperature
    CT)
Gas Sample
Temp. @ Dry
Gas Motor
                                                                                  In
                                                                                        Out
Sample
Box
Temp.
 (F)
Last
Impinger
Temp.
 (F)
Vacuum On
s'ajnple Train
  ("Hg)
                                                                      no
                                                                       10
                                          0:
                                                                       1L2L.
                                                                       112^.
                                                                       11

                               ILL
                                                                       116
                                                                       III
                               Uk
                               7t
                                                                       ILL.
                                           4.3.0
                                                                       /AT"

-------
Port And
Traverse
Point No.
          Distance
          From End
          Or Port
           (in)
        Clock
        Time
        Gas Meter
        Reading
         Cft3)
Stack
Velocity
Head
("H20)
Motor
Orifice
Press .Diff.
                                                Calco
                                                     Actual
Stack Gas
Temperature
Gas Sample
Temp. @ Dry
Gas Meter
                                                              In
Sample
Box
Temp»
 ( F)
Last
Impinger
Temp.
 ( F) .
Vacuum On
Sample Train
  ( " Hg)
T"
                                        luO
                      - /a
                                     jL
                                    (&SL
                                    *•? s&3
                                  _v.J/^_."
                                                                  v
                                                     ¥1
                                                     ir
                                        j&
                                         xb
                                                                                                        *  -8
   t*
                                                                               91
                   2*1.
                                                                   5/
                                                                  it
                                    ,_A
                                                                •11%
  "T"
   2,
                                                                           7'
                                                                                                     3-8
                                                          dh!
                                                                         (r>3
il^
//•^
                                 . 0
                                                                                                      3.$-

-------
                                               SOURCE SAMPLING FIELD DATA SHEET
Sampling^Location_
Date	TV
                                Kun No«-
Timo Start
                           Time  End
Sampling Time/Point ^"2,

DB /I£PF. WD*7<£_0F. I  	           	
Moisture /» ff7^.FDAC?..ff/J?Gas Density Factor  —
                              VF 3  DP
                                             "Hg
Barometric Press ^7*
            Hf'
                           Stack  Press.
Weather

Temp..
               \ W/D_
Sample Box
Meter A Ha
                         -   . W/S    —
                       Meter Box  No.
Nozzlo Dia.
                 Pitot Corr.  Factor
                   _in.f Probs Length_
                                              ft
Probe Heater Setting    ""**
Stack Dimensions I  Inside Diameter	[_.
                   Inside Area
                   Height

                                            _in
                                            _ft2
                                            9 ft
                                                  Sketch Of Stack i
                                                                              Mat'l Processing Rate	
                                                                              Final Gas Meter Reading:
                                                                              Initial Gas Meter Reading
                                                                              Total Condensate In Impingers
                                                                              Moisture In Silica Gel
                                                                                                                  - /2,-
                                                                                                                          ml

                                                                                                                         ~m
                                    Silica Gel Container No.J3  .Filter No(
                                    Orsati   C02    ,	
                                            02     	
                                            CO     	
                                                                                       N2
                                                                                       Excess
                                                                                          Air
                                                                              Test Conducted Byi
                                                                              Remarksi
                                                                    ^
Port And
Traverse
Point No.
            Distance
            From End
            Of Port
             (in)
                       Clock
                       Time
                               Gas Meter
                               Reading
                                (ft3)
Stack
Velocity
Head
("H20)
Meter
Orifice
Press. Diff.
  (••H20)
                                                       Calc.   Actual
Stack Gas
Temperature
    CF)
Gas Sample
Temp. @ Dry
Gas Meter
                                                                                   In
                                                                                         Out
Sample
Box
Temp.
 (F)
Last
Impinger
Temp.
 (F)
Vacuum On
Sample Train
  ( " Hg)
                      -2//O
                                            I-3Q
   s*
                                                                                           2
                                                              6^0
                                                                                  32

-------
Port And
Traverse
Point No.
Distance
From End
Of Port
 (in)
Clock
Time
Gas Meter
Reading
 (ft3)
Stack
Velocity
Head
("H20)
Motor
Orifice
Press .Diff.
                               Calc. [Actual
Stack Gas
Temperature
    CT)
Gas Sample
Temp. @ Dry
Gas Moter
                                                                                In
                                                                          Out
Sample
Box
Temp e
 ( F)
Last
Impinger
Temp.
 ( F)
Vacuum On
Sample Train
  ( " Hg)
                                                                                         T
                                                    3-/0
                                                                      ii
                                                                      //
                                                                      //
                                                                      1L
                                         I-
                                                                      'LL3L
                                                                          215
low
                                   7
                                             rx
                                   \
                                            D
                                                                     ifl

-------
                                              .SOURCE SAMPLING FIELD DATA SHEET
 Time Start
     	, Time End__	
Time/Point /O ff])^  ('Ted'flL~/2bnt/*h
                 i1,  DP&2. °F. VF 3 DP 0..S^9  "Hg
Moisture/* %7%.FDAfl,#/3 .Gas Density Factor;	

Barometric PrassCffi'ffi'HK. Stack Press.      "Hg
V/eather    /nQ/  "- 'HumCt	
Tenp.5?7-9^°Ft W/D	, V//S	
Sample Box Mo.  *~"    . Meter Box Mo..
Meter A Hg/I fo (9 , Pitot Corr. Factor	^
Nozzle Dia. £>.'2^>   in..  Probe I.-e-i[:th_

/rcbe Heater Setting	
Stack Dimensionsi   Inside Diameter   JJL     in
                   Inside Area  ^>. ~~?%^   ft^
                   Height   A/ert \f>r*-f-
-------
Port .And
Traverse
Point Ho.
Distance
From End
Of Port
 (in)
Clock
Time
Gas Meter
Reading
 (ft3)
Stack
Velocity
Head
("H20)
Meter
Orifice
Press.Diff •
  ("H20.).
Stack Gas
Temperature
    CT)
Gas Sample
Temp. @ Dry
Gas Motor
Sample
Box
Temp.
 ( F)
Last
Impinger
Temp.
 ( F)
Vacuxim On
Sample Train
  ( " Hg)

-------
                                               SOURCE SAMPLING FIELD DATA SHEET
Sampling Location,
Date    &~  /&—"7/
                           •*SraCN.
                                Uun No.
Time Start
             4-
                            Time End
Sampling Time/Point,
 D3
      'F, WB_
               _°F,  DP	°F,  VF 3 DP	
Moisture     ^.FDA	,Gas Density Factor.

B-iromotric Pressv^fl^'^R. Stack Press.
V/eather
  "Hg
                                            "Hf*
Temp. ?7-93^F. W/D            W/S	
Sanple DDK Mo.  ~    .  Meter Box No.   £ E- '3!—'
            J- *
           ...fo?X Pitot  Corr. Factor   Q
 Nozzlo Dia.
                   _in., Probe Length_
Probe Heater Setting	
Stack Dimensionsi  Inside Diameter
                                     \ t.
                   Inside Area
                   Height	
                                    '78
                                             ft
                                               in
                                             ft2
                                           ZLft
                                                   Sketch Of Stack i
                                   Mat'l Processing Rate	
                                   Final Gas Meter Reading_
                                                                                                         S*2l.. /*7
                                                                               Initial Gas Meter Reading_

                                                                              Total Condensate  In  Impingers     <£X <
                                                                              Moisture  In Silica Gel^Zl^-
                        Silica Gel Container No. &,. .
                        Orsatt   CO;

                                °2
                                CO
                                                                   ft>
                                                                  rt^
                                                                  _ml
                                                                  _gra
                                                                                                          Filter No.  J2-
                                                                                        N2   '
                                                                                        Excess
                                                                                           Air
                                                                               Test Conducted Byi
                                                                                                         fQ
                                                                               Remarks i
                                                     A&vo  HlT-frr
Port And
Traverse
Point No
             Distance
             From End
             Of Port
              (in)
                       Clock
                       Time
                               Gas Meter
                               Reading
                                (ft3)
Stack
Velocity
Head
("H20)
Meter
Orifice
Press. Diff.
  C'H20)
                                                      Calc.  Actual
Stack Gas
Temperature
Gas Sample
Temp. <§ Dry
Gas Meter
                                                                                   In
                                                                                          Out
Sample
Box
Temp.
 (F)
Last
Impinger
Temp.
 (F)
Vacuum On
      i Train
  ( " Hg)
m
                                  . coo
                                                                                                                  T&
                                           6*13
                              112^
                                                                                    \£
                                           i
                                                                          ii
                                                                         \L
                                           U
                                                                                                                   f/>0
                                                                                                                  IL6

-------
Tvrt Arxl
Traverse
Point No
       Distance
       From End
       Of Port
        (in)
Clock
Time
Gas Meter
Reading
 (ft3)
Stack
Veloc ity
Head
("H20)
Meter
Orifice
Press.Diff .
                                                       C'H20)
                               Calc•  Actual
Stack Gas
Temperature
    CT)
Gas Sample
Temp. @ Dry
Gas Meter
                                                                                In
                                                                                 Out
Sample
Box
Tempo
 ( F)
Last
Impinger
Temp.
 ( F)
Vacuum On
Sample Train
  ( " Hg)
                                          Ju
                                                                                                                Q.ST
                                                                                                          JL&
.!_

                                                                      m
                                                                                                     -79
                                                                                   a
                                            Ma
                                                                                                          1*L
                                                                                                               1-
                                                                                                             , 6
                                                                                                                /L.
     A
      6
                                                                   i.

-------
                                               SOURCE SAMPLING FIELD DATA SHEET
Sampling Location     fr\ / O
Date    &-))-"}'!   _ s Hun No
Time Start
                                          
                                                                                                              D-
                                                                                                               //
                                   Total Condensate In Impingers_
                                   Moisture In Silica Gel^5/.^- 223.0 ~
                                   Silica Gel Container No.^^"".Filter  No.

                                   OrsatI   C0£

                                            °2
                                            CO
                                                                             Test Conducted Byi
                                                                             Remarks I
                                             ft
Port Ani
Traverse
Point No.
            Distance
            From End
            Of Port
             (in)
                       Clock
                       Time
      Gas Meter
      Reading
       Cft3)
Stack
Velocity
Head
("H20) .
 eter
Orifice
Press.Diff .
  C'HpO)
                                                      Calc.  Actual
Stack Gas
Temperature
Gas Sample
Temp. @ Dry
Gas Meter
                                                                                        Out
                                                                                  In
Sample
Box
Temp.
 (F)
Last
Impinger
Temp.
 (F)
                                                                                                                         ft-
                                                                                                                         ml
                                                                                                                         gm
Vacuum On
Sample Train
  ( " Hg)
                                                     4^
                                                                         ts'
                                                                                 .31

                                                                        i
                      08- IS
                                               1
                                           O./O

                                                                        IIS
                                                                                  7*
                                                               7
                                                                         1t3
                                                                                       33
                                                                         113
                                                                                  B-o

-------
Fort And
Traverse
Point No.
Distance
From End
Of Port
 .(in)
         Clock
         Time
Gas Meter
Reading
 (ft3)
Stack
Velocity
Head
("H20)
Meter
Orifice
Press.Diff .
                                                 Calc.
                                             Actual
Stack Gas
Temperature
   CF)
Gas Sample
Temp. @ Dry
Gas Meter
                                                                In
                                                     Out
Sample
Box
Tempo
 ( F)
Last
Impinger
Temp.
 ( F)   .
Vacuum On
Sample Train
  ( " Hg)
  n
                                       a.og
                                                                                             1 -
 _L_
                                U
                               j^L
                                 S.
             ^
             3r jf/y.  /
                                        iai
                                      ZM
712
                                                                                   t
                 -
                                       O-/0
                                      /.
         Z^
                                       a
                                      A
                                                                 A

-------
                                               SOURCE SAMPLING FIELD DATA SHEET
Plant <«7TtJe -PTfC) V^ I VY fO V> M II A" <• ni * J
Sampling Location/i|/°F. VF 3 DP £
t
. /
&S$
/20fcrM
\&4- "HK
MoisturejJi/4p1&.FDA .Gas Density Factor
«\O 9
Barometric Press ^7* 7 "Hg. Stack Press.
VJeather \^

                              4|A;
                                                                           7^   i   -
                                                                                                                   - O

-------
Port And
Traverse
Point Ho t
Distance
From End
Of Port
 (in)
Clock
Time
                         Gas Meter
                         Reading
                          (ft3)
Stack .
Velocity
Head
("H20)
Meter
Orifice
Press. Diff .
                          ualc.  Actual
Stack Gas
Temperature
Gas Sample
Temp. @ Dry
Gas Moter
                                                                     In
                                                                Out
Sample
Box
Tempo
 ( F)
Last
Impinger
Temp.
 (  F)
Vacuum On
Sample Train
  ( " Hg)

2E
 ert
    "~Z_

                                                                      [_
                                                                 7
                                                                          7.7
                                                             '1
                                                      3.3~
                                                      -23-
                  au2
                                                                          79
                          ^33.0
                                            P*Z'ti
                                            f t v^, !^
                                           —\j—yj~
                                            / TXS*
                                            I • &G
                                                           J-%0
                                                                     &7] 'So
                                                             /ZO
                                                           96
                                           M,
                                          / i^r
                                          / » -a>«=3
                                                             /
                                                                             77
                                                                                      23.
                                                      m^
                                                                               .0'
                         -a-
                                               '*

-------
                                              SOURCE SAMPLING FIELD DATA SHEET
Plant »»
Sampling Location	

Date        ?f- /. - "7 7
                              _, Itun No
Timo Start
Sampling Time/Point,

DB
                        , Time End^
                            4@?)t
                          F.  VF
                                            "H
             £.FDA<3/?%Gas Density Factor^

BarOIMtrie Press £^.~l"Hg. Stack Press.	"Hg
We a ther    C^OdST"-
        n*\ _
Temp.	& Q Jb
Sample DDK Kc
Meter &H9_/,"
              -, w/y   —    .
                    _, Meter Box  Mo
Nozzlo Dia.
                Pitot Corr. Factor
                   _in.f Probe Length_
                                            ft
Probe Heater Setting
Stack Dimensionsi  Inside Diameter
                  Inside Area
                .  Height
                                             in
                                                 Sketch Of Stacki
                                                                            Mat'l Processing Rate
                                                                            Final Gas Meter Reading
                                                                            Initial Gas Meter Reading
                                  Total Condensate In Impingers	

                                  Moisture In Silica GelJ^33.<3-
                                  Silica Gel Container No.

                                  Orsati   C02    ,	i_
                                           02     	

                                           CO     	
                                                                                                                      ft3
                                                                                                                     ft3
                                                                                                                      ml
                                                                                                        .Filter No.  ^
                                                                                     N2
                                                                                     Excess
                                                                                        Air

                                                                            Test Conducted
                                                                            Remarksi
                                                                                                   &
                                                                                              4A
Port \nd
Traverse
Point No.
            Distance
            Frcm End
            Of Port
             (in)
                      Clock
                      Time
                              Gas Meter
                              Reading
                               (ft3)
Stack
Velocity
Head
("H20)
Meter "
Orifice
Press.Diff .
  C"H?0).
                                                     Calc.  Actual
Stack Gas
Temperature
Gas Sample
Temp. © Dry
Gas Meter
   CF)
 In    Out
Sample
Box
Temp.
 (F)
Last
Lmpinger
Temp.
 (F)
•
Vacuum On
Sample Train
  ( " Hg)
            7S
                                  . 763
                                  . 0
                                                    ux
                                                                     &&
                                                                                                                -4^
                              ^"7^
                                                     /XT
                                                                                           1    —
                                                                                                                 3-5-
            3/2.
                                          0-38
                                                            Mo
                                                                                                                 3-3

-------
Fort And
Traverse
Point 'Mo.
Distance
From End
Of Port
 (in)
Clock
Time
Gas Meter
Reading
 (ft3)
Stack
Velocity
Head
("H20)
Meter
Orifice
Press.Diff.
Stack Gas
Temper at ure
Gas Sample
Temp. @ Dry
Gas Meter
Sample
Box
Tempe
 ( F)
Last.
Impinger
Temp.
 (
Vacuum On
Sample Train
  ( " Hg)

-------
                                                S.T£j5 S/^niSG FIELD DATA SHEET
Plant
Sampling Location
Date _ j?—/2r"7/
                               , Kun No.
Time Start
Sampling Time/Point
                                              Hg
Moist ire-  ^.FDA Otf£.Gas Density Factor Q-9?

B-irom-itric Press s3O_"Hg, Stack Press. O? Q "Hg
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Sample Box No. •rTv-b   , Meter Box No._
Meter t l§/*~7<£-, Pitot Corr. Factor	
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                   Inside Area    Q* 7£5y
                                                   Sketch Of Stack i
                                                Mat'l Processing Rate	
                                                Final Gas Meter Reading   /3l •
                                                        Initial Gas Meter Reading
                                                        Total Condensate In Impingers_
                                                        Moisture In Silica Gel;
                                                                               Silica Gel Container Mo.^  .Filter No,
                                                                               Orsat t   C0£
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                                                                               Test Conducted Byt
                                                                               Remarks t
                                                                                                                 r
                   Height
                                              f t

                                                                                                    ft
                                                                                                                           ml
Port A-xi
Tra-/er;5e
Point -ro
            Distance
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              (in)
Clock
Time
Gas Meter
Reading
 (ft3)
Stack
Velocity
Head
("H20)
Meter
Orifice
Press .Diff.
  C'H?0)
                                Calc•  Actual
Stack Gas
Temperature
Gas Sample
Temp. @ Dry
Gas Motor
                                                                                    In
                                                                                          Out
Sample
Box
Temp.
 (F)
Last
Impinger
Temp.
 (F)
Vacuum Cn
Sample Train
  ( " Hg)
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                                  -, ,„

-------
Port And
Traverse
Point No.
Distance
From End
Of Port
 (in)
Clock
Time
Gas Meter
Reading
 (ft3)   '
Stack
Velocity
Head
("H2Q)
Meter
Orifice
Press .Diff .
Stack Gas
Temperature
Gas Sample
Temp. @ Dry
Gas Meter
Sample
Box
Temp*
 ( F)
Last
Impinger
Temp.
 C F)
Vacuum On
Sample Train
  ( " Hg)

-------
                                              SOURCE SAMPLING FIELD DATA SHEET
Plant ra=.C.Uf£[M  !![}-<=>..
Sampling Location ^JO£f// ^fflZtcJ^
Date • 0^" ///"^ "7 f . Hun No. /
Timo Start /3^ "2* . Tinie End 14^4-2*



Sampline Time/Point }t> fffil*. CTBr& fa f '2&J
Da£§fc>°F. Vra^2-°F. DP^<^°F. VF Q DPd>.6-6
Moisture^.^ l^.FDA ty£ .Gas Density FactorO-
Earomotrio Press 
-------
  Port And
  Traverse
  Point No.
       Distance
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        (in)
Clock
Time
Gas Hetor
Reading
 Cft3)
Stack .
Velocity
Head
("H20)
Metcr
Orifice
Press.Diff .
                                                            Actual
Stack Gas
Temperature
    CT)
Gas Sample
Temp. @ Dry
Gas Meter
                                                                           In
                                                                Out
Sample
Box
Temp»
 ( F)
Last
Iinpinger
Temp.
Vacuum On
Sample Train
  ( " Hg)
_.
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                                                                            -fJ
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-------
SOURCE SAMPLING FIELD DATA SHEET
Sampling L
Date &-
Timo Start
ocation ^=5O\Jn"Vi ^p>Vf^ On**-
- I'Z.-'-?! . llun No. Z-
CT#.JL3 . Time End
Sampling Time/Point lO AMU~ TOt&L |'5°F. W?D ' — . W/S '"~
No.
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Clock
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Stack Gas
Temperature

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-------
Port And
Traverse
Point No.
Distance
From End
Of Port
 (in)  .
Clock
Time
Gas Meter
Reading
 Cft3)
Stack
Velocity
Head
("H20)
Meter
Orifice
Press.Diff.
  ("H^
  >i—.-..•r.>Lj
Stack Gas
Temperature
    CF)
Gas Sample
Temp. @ Dry
Gas Meter
Vacuum On
Sample Train
  ( " Hg)

-------