TEST NUMBER FA-2
 UNION CARBIDE CORPORATION

  FERROALLOYS DIVISION

     MARIETTA, OHIO


           by

       R. N. Allen
Resources Research, Inc.
A Subsidiary of TRW Inc.
   7600 Colshire Drive
 McLean, Virginia 22101
Contract Number CPA 70-81

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                        I.    TABLE OF CONTENTS


                                                                    Page


II.          INTRODUCTION 	            3

III.         SUMMARY OF RESULTS	            6

IV.          PROCESS DESCRIPTION  	            13

V.           LOCATION OF SAMPLING POINTS	            17

VI.          PROCESS OPERATION  .....  	            21

VII.         SAMPLING PROCEDURES  	            22

VIII.        CLEANUP AND ANALYTICAL PROCEDURES  	            23

IX.          DISCUSSION	            24

             A.  Results	            24
             B.  Operating Conditions 	  .....            32
             C.  Test Conditions	            33

X.           APPENDIX	            39

      ;       A.  Complete Particulate Results with
                 Example Calculations
             B.  Complete Gaseous Results  with
                 Example Calculations
             C.  Complete Operation Results
             D.  Field Data
             E.I Sampling Procedures
             E.2 Cleanup and Analytical Procedures
             F.  Laboratory Report
             G.  Test Logs            - .
             H.  Related Reports
             I.  Project Participants and  Titles
             J.  Particle Sizing Samples
             K.  Chemical Analysis of Emissions

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                          LIST OF TABLES
Table No.
1
2
3
4
5
Title
Summary
Summary
Summary
Summary
General
of
of
of
of
Results
Results
Results
Results
Data MCA
and Scrubber Efficiency
- Scrubber Exhaust
- Scrubber Inlet
- Tapping Exhaust
- EPA Tests
Page
6
8-9
10-11
12
16
Plus Appendixes A, B, C, D, F, and G.
                          LIST OF FIGURES
Figure No.
1 .
2'
3
4
5
Title
Flow Diagram, Sample Locations
Process Flow Diagram - Furnace #1
Scrubber Inlet Duct - Sample Point Locations
Scrubber Exhaust Duct - Sample Point Locations
Tapping Exhaust - Sample Point Locations
Page
4
14
18
19
20

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                            II.  INTRODUCTION
     Source emission tests are being performed on a series of electric

furnace installations, known as reactive metals or ferroalloys, fpr the

Office of Air Programs, Environmental Protection Agency.  These surveys


include the determination of filterable and total particulate matter,

s,ulfur dioxide, particle size analyses and chemical analyses for a variety

of furnace formulations and control devices.  The series of tests, con-

tained in this report, were performed at the Union Carbide Corporation,

Ferroalloys Division, P. 0. Box 299, Marietta, Ohio, 45750.



     Emissions from this particular plant were determined for a silico-

manganese, 2% carbon grade furnace (No. 1).  This unit was hooded, with


two parallel Venturi type scrubbers leading to a single exhaust stack.


Two draft fans, located after each scrubber, forced the scrubbed gases

into the stack.  The 8 foot diameter exhaust stack was provided with a

single 3-inch sample port, while the horizontally mounted, rectangular

inlet duct was sampled through five properly spaced ports for equal area

sampling.


                                       »•
     In addition, two parallel tapping exhausts were tested.  These exhaust

gases involved no scrubbing device and the stacks were sampled through the

single port as provided.  All sample locations are shown in Figure 1 on the

following page.  Further detailed diagrams and descriptions are included in

Sections IV and V of this report (Process Description and Location of

Sampling Points).

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        EXHAUST  _|
        SAMPLE  L
       LOCATION
SCAFFOLDING
                                                                              INLET
                                                                             SAMPLE
                                                                            LOCATION
                                                 TWO
                                               SCRUBBERS
                                                  IN
                                                PARALLEL
                                                                                                            WEST TOP
                                                                                                            EXHAUST
                                 FIGURE 1. FLOW DIAGRAM, SAMPLE LOCATIONS

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                            II.  INTRODUCTION
     Source emission tests are being performed on a series of electric




furnace installations, known as reactive metals or ferroalloys, for the




Office of Air Programs, Environmental Protection Agency.  These surveys




include the determination of filterable and total particulate matter,




qulfur dioxide, particle size analyses and chemical analyses for a variety




of furnace formulations and control devices.  The series of tests, con-




tained in this report, were performed at the Union Carbide Corporation,




Ferroalloys Division, P. 0. Box 299, Marietta, Ohio, 45750.






     Emissions from this particular plant were determined for a silico-




manganese, 2% carbon grade furnace (No. 1).  This unit was hooded, with




two parallel Venturi type scrubbers leading to a single exhaust stack.




Two draft fans, located after each scrubber, forced the scrubbed gases




into the stack.  The 8 foot diameter exhaust stack was provided with a




single 3-inch sample port, while the horizontally mounted, rectangular




inlet duct was sampled through five properly spaced ports for equal area




sampling.






     In addition, two parallel tapping exhausts were tested.  These exhaust




gases involved no scrubbing device and the stacks were sampled through the




single port as provided.  All sample locations are shown in Figure 1 on the




following page.  Further detailed diagrams and descriptions are included in




Sections IV and V of this report (Process Description and Location of




Sampling Points).

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        EXHAUST  .-<
        SAMPLE  Li
       LOCATION
SCAFFOLDING
                                           NORTHEAST
                                                 TWO
                                               SCRUBBERS
                                                  IN
                                               PARALLEL
                                                                           WALL OF
                                                                           PLANT
                                                                             INLET
                                                                            SAMPLE
                                                                           LOCATION
                                                                                          EAST TOP
                                                                                          EXHAUST
                                                                                      DUCT
                                                                                              HOOD
                                                                                             FURNACE
                                                                                    HOOD
                                                                                      \J.
  WEST TOP
   EXHAUST
HOOD
                                 FIGURE 1.  FLOW DIAGRAM,  SAMPLE LOCATIONS

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     Within this survey period of July 27 to August 5, 1971, three different




scrubber conditions were tested.  Conditions A, B and C were set at scrubber




pressure drops of 57, 47, and 37 inches of water, respectively.  Normal




scrubber operation employs the 57 inch setting.






     During this particular survey particulate matter was sampled using the




EPA train as described in Appendix E-l.  Sulfur oxides were sampled using




the Shell Development method and integrated combustion gases were sampled




in a gas bag with analysis by standard Orsat.  Particle size was measured




in situ with an Andersen Sampler and a Brink Sampler.  The overall survey




included 26 particulate emission runs, 14 Orsat measurements, 11 sulfur




dioxide samples, 6 metal filters and 23 particle size distribution




analyses.

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                                                                                            k«
                           III.  SUMMARY OF RESULTS
        Shown below in Table 1 are the average results for each "in" and

   "out" scrubber condition and phe corresponding collection efficiencies.       .,


                                    Table 1

                  SUMMARY OF RESULTS AND SCRUBBER EFFICIENCY

                       Stack Exhaust (Outlet)      	Inlet Duct	
           Scrubber  Particulate Particulate S02   Particulate Particulate Percent
Date(1971) Condition grains/SCF	Ib/hr    ppro   grains/SCF     Ib/hr    Efficiency

7/31-8/1   A,AP        0.0101       9.76     1.       l.?5       1090        99.1
           =57" H20


8/1-8/2    B.AP        0.0166      16.7      1.       2.05       L790        99.1
           = 47" H20


8/3-8/4    C,AP        0.0479      44.0      1.       1.53       1190        96;. 3
           = 37" H20                                                    :
        Tjie apparent efficiencies were the same for Condition A and Condition

   B.  However, note that the highest scrubber pressure drop, during Condition

   A, was coupled with the lowest inlet particulate loading.  Condition C

   definitely indicated  the lowest collection efficiency.  During this

   particular condition, both the scrubber pressure drop and the inlet

   particulate loading were at very  low levels.

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     Particulate and gaseous emission summaries for scrubber exhaust,

scrubber inlet and tapping  exhaust locations are shown in Tables 2, 3,

and 4 on the following pages.  Flue gas conditions are included and

percent particulate matter in the impinger train has been calculated.


     SC>2 emission levels were extremely low.  Almost all individual

results were less than 1. ppm.  Other similar processes have indicated

SO- emission levels up to 20 ppm with no scrubbing devices (i.e., Foote

Mineral Company, Steubenville, Ohio).  In this particular survey, there

was no indication of any trend with SO  emission levels.


     Gas temperatures and velocities during the exhaust sampling remained

smooth, as expected for a location equipped with wet scrubber and con-

stant speed draft fans.  However, sharp variations were noted at the

inlet duct, especially the wide variation in temperature.  It is believed

that these variations were inherent in the furnace design.  Furthermore,

the inlet sampling location was unusually .close to the furnace itself.


     The east and west tapping exhaust stacks, provided with no scrubbing

devices, emitted average particulate levels of 19 and 48 pounds per hour,

respectively, but these are not continuous emissions.  Normal emission
                                     .-»*'.•"
from the continuously operated scrubber is approximately 10 pounds per

hour.


     Particle size of emissions (usually sub microns) are shown in Appendix J

and chemical analyses (quite variable) are shown in Appendix K.

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                                 TABLE 2
                           SUMMARY OF RESULTS - SCRUBBER EXHAUST
	 , 	 p.. 	
Run Number
Date
Stack Flow Rate -v SCFM * dry
% W^ter Vapor - 7« Vol.
% C02 - Vol % dry
% 09 - Vol % dry
*
7. Excess air (? sampling point
S0~ Emissions - ppm dry
NO Emissions - ppm dry
Particulates
Probe, Cyclone, & Filter Catch
gr/SCF* dry
gr/CF (§ Stack Conditions
lbs./hr..
Particulate from Impinger
Train (% of Total)
Total Catch
gr /SCF * dry
gr /CF @ Stack Conditions
lbs./hr.
Stack Temperature
MlE-1
7/27/71
113,000
18.5
2,1
19.2
1110
0.158
•!•
0.0103
0.00728
9.97
38.
0.0166
0.0117
16.1
140
**
M1E-2
7/29/71
112,200
15.4
3.4
18.3
723
5.21
-
0.00710
0.00520
6.83
T5.
0.0110
0.00805
10.5
140
M1E-3
7/30/71
122,100
12.9
1.9
18.6
729
0
-
0.0107
O.t)0839
11.2
1^..
0.0122
0.00956
12.8
118
M1E-4
7/31/71
116,800
15.8
2.8
18.8
917
0.266
- '
0.00813
0.00594
8.14
_L6.
0.00967
0.00706
9.68
139
MlE-5
7/31/71
110,200
17.2
3.3
18.4
757
0.302
-
0.00889
0.00684
8.39
15.
0.0105
0.00807
9.91
140
*
M1E-6
-
-
-
-
-
'
-
-

-
-

-
-
- .
-
        ** Plant running at approximate one half-load.
* 70°F, 29.92"  Hg

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                                 TABLE  2
                           SUMMARY OF RESULTS   - SCRUBBER EXHAUST  (CONTINUED)
Run Number
Date
Stack Flow Rate - SCFM * dry
% Water Vapor - 7» Vol.
% C02 - Vol % dry
% 0, - Vol % dry
• * *•
% Excess air @ sampling point
S0? Emissions -• ppm dry
NO Emissions - ppm dry
J\,
Particulates
Probe, Cyclone, & Filter Catch
gr/SCF* dry
g'r/CF & Stack Conditions
Ibs./hr.
Particulate from Impinger
Train (7» of Total)
Total Catch
gr /SCF * dry
gr /CF @ Stack Conditions
Ibs./hr.
Stack Temperature
M1E-7
8/1/71
118,100
16.1
3.0
18.6
827
-
- -
0.0150
0.0111
15.2
12.
0.0170
/
«t
0.0126
17.2 .
135
M1E-8
8/2/71
115,000
18.2
3.2
18.6
845
0.587

0.0180
0.0132
17.7
9.
0.0197
O."0144
19.4
127
MlE^-9
8/2/71
121,100
15.3
3.4
18.5
815
0.0340
- -
0.0114
O.t)0831
11.8
13.
0.0131
0.00955
13.6
134
M1E-10
8/3/71
114,300
17.6
3.2
18.8
964
0.737
-
0.0138
0.0100
13.5
4.
0.0144
0.0104
14.1
130
M1E-11
8/3/71
112,000
16.7
3.2
18.6
845
-
-
0.0369
0.0270
35.4
17.
0.0445
0.0326
42.7
133
M1E-12
8/4/71
103,200
17.6
3.1
18.7
890
-
-
0.0798
0.0576
70.6
6.
0.0849
0.0613
75.1
132
* 70°F, 29.92"  Hg

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                                 TABLE 3
                           SUMMARY OF  RESULTS  - SCRUBBER INLET
Run Number
Date
Stack Flow Rate - SCFM * dry
7o Water Vapor - °L Vol.
7» C02 - Vol % dry
% 09 - Vol % dry
• • ^
7o Excess air (? sampling point
S02 Emissions - ppm dry
NO^ Emissions - ppm dry
X
Particulates
Probe, Cyclone, & Filter Catch
gr/SCF* dry
gr/CF <
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                                 TABLE 3
                           SUMMARY OF RESULTS - SCRUBBER INLET  (CONTINUED)
Run Number
Date
Stack Flow Rate - SCFM * dry
7. Water Vapor - % Vol.
% C02 - Vpl % dry
7. 09 - Vol % dry
*• *>
7o Excess air (? sampling point
S0~ Emissions - ppm dry
NO^ Emissions - ppm dry
X
Particulates
Probe, Cyclone, & Filter Catch
gr/SCF* dry
gr/CF @ Stack Conditions
Ibs./hr.
Particulate from Impinger
Train (7. of Total)
Total Catch
gr /SCF * dry
gr /CF @ Stack Conditions
Ibs./hr,
Stack Temperature
MID- 10
8/3/71
91,000
4.61
N/A
ii
ii


0.965
0.431
752.6
1.7
0.982
0.438
765.9
655
MID-11
8/3/71
85,000
8.9
N/A
ii
ii


1.66
0.709
1209.
1.8
1.69
0.722
1231.
654
MID-12
8/4/71
94,900
4.8
N/A
ii
it


1.91
0.948
1553.
0.5
1.92














0.953
1562.
541












?























* 70°F, 29.92"  Hg
                                    11

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                                TABLE 4
                           SUMMARY OF RESULTS  - TAPPING EXHAUST
Run Number
Date
Stack Flow Rate - SCFM * dry
% Water Vapor - % Vol.
% CO 2 - Vol 7. dry
7» 09 - Vol 7. dry
^ *»
7« Excess air (? sampling point
S02 Emissions - ppm dry
N(3 Emissions - ppm dry
X
Particulates
Probe, Cyclone, & Filter Catch
gr/SCF* dry
gr/CF (§ Stack Conditions
lbs./hc.
Particulate from Impinger
Train (7, of Total)
Total Catch
gr /SCF * dry
gr /CF @ Stack Conditions
Ibs./hr.
Stack Temperature
ETE-1
8/5/71
70,100
4.95
f*
-
N/A
-
-
3.0358
0.0316
21.5
2.
0.0366
0.0323"
22.0
107
ETE-2
8/5/71
70,000
4.12
-
- '
N/A
/

D.0249
0.0224
14.94
10.
0.0275
0.0248
16.5
100
ETE-3
8/5/71
69,700
3.74
-
' -•
N/A
0-833
-
0.0284
0 .'0258
16.96
8.
0.031
WTE-1
8/5/71
64,250
3.11
0.2
21.2
N/A
3.703
-
0.128
0.114
70.5
20.
0.160
0.0282 ! 0.1429
18.5
97
88.2
111
WTE-2
8/5/71
61,800
3.32
0.1
20.9
N/A
0361
-
0.0483
0.0428
25.6
30.
0.0696
0.0616
36.9
115
WTE-3 .:•
8/5/71
64,700
2.72
0.1
21.2
N/A
-
-
0.0169
0.0153
9.37
48.
0.0329
0.0297
18.25
107
* 70°F, 29.92"  Hg
                                    12

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                        IV.  PROCESS DESCRIPTION
     Reactive metals are generally ferroalloys which are produced in


submerged arc electric furnaces.  The facility under consideration in


this report is an open furnace, with hooding and a scrubbing system to


reduce the emission of fumes and dust following collection.  Figure 2


is a qross sectional view process flow diagram indicating the actual


furnace under test in this survey.




     The electric arc is employed as a concentrated source of heat.


Chrome, manganese and other ores are added to the surface of the furnace


through mechanized equipment and chutes.  Additional carbon in the form


of coke, wood chips, etc., is an integral part of the furnace mix,


along with specialized fluxes, etc.  The mix is added directly to the


surface of the furnace through chutes and is then spread over the surface


with stoking machines.




     The very high temperatures produced initiate a reaction in the bottom


of the furnaces and form a layer of metal which is tapped at appropriate


times.  As the ores and carbonaceous materials gradually settle to the

                                      9*    '
bottom of the furnace, the heat, in conjunction with a lack of oxygen,


react with the oxide ores in order to remove oxygen and thus produce the


elemental metal.  Escaping gases, composed largely of carbon monoxide, are


burned at the surface of the furnace in the so-called open units.
                                    13

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(ATMOSPHERE
            ORES, ETC.
                   CHUTES
                       \
             EXHAUST
                   PRODUCT
                    MOLDS
                               (ATMOSPHERE )
ELECTRICAL
  POWER
     CARBON
     REDUCING
      AGENTS
    FLUXES, ETC.
                              ELECTRODES
              CHUTES

                HOOD
 x_ i r
A
                              ELECTRIC ARC
                                FURNACE
                                                                  DUST
                                                               COLLECTION
                                                                 SYSTEM
                                        J HOOD
                                 LADLE
                                                   SAMPLE
                                                  LOCATIONS
               SLAG
             DISPOSAL
                  FIGURE 2.  PROCESS FLOW DIAGRAM
                            FURNACE //I
                                 14

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     Furnace 1 is a 27 megawatt furnace producing a silico-manganese


product using Soderberg type electrodes, formed in place from a "paste",


rather than using prebaked carbon electrodes.  Induced draft fans are


employed to pull fumes from various hoods into the exhaust system.  Gases


and fumes from the normal furnace operation are passed through two


parallel venturi scrubber systems for cleaning, prior to discharge into


the atmosphere.  The collection of fumes around the furnace is almost


100 per cent effective during normal operation.



     The furnace is tapped at intervals of approximately one and a half


hours, depending upon the total power fed and thereby the amount of metal


produced.  Metal and slag pour into ladles and fumes are drawn off, without


collection devices, by hoods and two exhaust systems.  The slag is removed


from the ladle arid disposed of by various means.  Molten product is poured


into molds, after which it is broken into usable sizes.


     i- .
     Additional furnace and scrubber process data is shown in Table 5 on


the following page.
                                   15

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                                            TABLE  5
                                                                     August 6, 1971
                              GENERAL DATA MCA-EPA TESTS
Furnace:
Product:
Test Period:
Tap Time:
Estimated Weight of Raw
Materials Fed to Furnace
During Test:

Composition of Raw Material:
KW on Furnace During Test:

Water Recirculated to Each
Venturi (2) - GPM:
     Up Water Each -Venturi -
GPM:
Water Spray to Each Fan (2) -GPM:

Pressure Drop Across Venturi -
Inches of 1^0 :

Opacity at Stack after Moisture
Plume Dissipates:
No. 1 - Marietta, Ohio
Silico-Manganese  2% Carbon Grade
July 27 to August 5, 1971. (See recording
strip for actual dates)

See Strip Chart for Particulate Tests and Tapping Data
Sheet
25.5 Net Tons Per Hour

Manganese Ore and FeMn Slag, Coal and Coke,
Gravel and Dolomite, Misc. Remelt Material.

25 - 30,000 - See Strip Chart
800 - 900


360

40

Three Tests Made each at Approximately
57", 47", 37"

From None to a Trace
 SS:rb
                                            16

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                     V.  LOCATION OF SAMPLING POINTS











     Sample port locations were installed by plant personnel prior to the




arrival of the test team, and approved by the EPA project officer.  There




were five sample ports across the top of the inlet duct to the scrubber.




As shown in Figure 3 the cross section of this duct was divided into four




one-foot layers, thus forming a 20 equal area profile.  Particulate tests




were conducted for 3 minutes at the centroid of each area.  A pulley-trolley




attachment, located approximately fifteen feet above the duct, provided




vertical access to each sampling point in the duct.






     The single sample port at the exhaust stapk was large enough to allow




two sampling trains to be run simultaneously.  The stack was eight feet in




diameter at the sample profile and was divided into nine equal areas, as




shown in Figure 4.  Because the scaffolding was not long enough, points




1 and 2 could not be reached by the probe.






     There were two identical exhaust stacks for the tapping operation and




sample locations were placed on the fourth floor, inside the furnace




building.  The stacks were five feet in diameter, and were divided into




five equal areas, as shown in Figure ,.5.  Sampling trains rested on




scaffolding about six feet above the floor level.
                                   17

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oo
A B CD E
n n n n • • n
i i ITT
2 2 2 2 2
3 3 3 33
T . -
4 4 4 4 4

^ ^


A
4'
1




t
-0"
f
SOUTHEAST ^
V

                                     CROSS SECTIONAL VIEW OF DUCT,
                                     WHEN FACING THE EXHAUST STACK
                                     FIGURE  3. SCRUBBER INLET DUCT - SAMPLE POINT  LOCATIONS

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                                                       NORTHEAST
vo
                                                   CROSS SECTIONAL VIEW
                                    FIGURE 4.  SCRUBBER EXHAUST DUCT  -  SAMPLE POINT LOCATIONS

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                                                      NORTHEAST
K>
O
o • •  •   •     •  •
                    EAST TOP EXHAUST
                                                         WEST TOP EXHAUST
                                  FIGURE 5.  TAPPING EXHAUST  - SAMPLE POINT LOCATIONS

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                         VI.  PROCESS OPERATION
     Practically all sampling was carried out while the process was running




normally.  However, there were periods of furnace shut-downs or low process




loads.  These special conditions were rapidly communicated to the sampling




team by either the EPA project engineer or the testing crew leader, in




order to rapidly interrupt the sampling.






     The furnace was down practically all day or. July 28, a short period




in the afternoon of July 29, and shortly before noon on July 31.  Particulate




run M1E-2 was conducted during a half-load operation on July 30.







     Appendix C tabulates the tapping data and indicates the furnace load




during the sampling periods.  There were some fluctuations in the furnace




load during testing, but these were considered to be within normal operating




conditions.  Normal operating levels were indicated when the furnace operated




between 25 and 30 megawatts.  Tapping was conducted as often as necessary,




depending upon the total power input to the furnace.
                                   21

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                         VII.   SAMPLING PROCEDURES
      All  test procedures were discussed with the  Project  Officer in


 advance.   They were  essentially the same as those being issued by the


 Environmental Protection Agency for source  sampling.




      Preliminary velocity and temperature readings were obtained in order


 to select nozzle sizes for isokinetic sampling.   Particulate  sampling


 was conducted using  the EPA train as described in Appendix E-l.   The


 metals sampling train was essentially the same as the  ordinary particulate


 train,  but it specifically called for a glass-lined probe.




      Gas  sampling was also conducted in accordance with the proposed


 EPA Standard Source  Testing Methods.  Sulfur dioxide was  sampled with


 midget impingers using isopropyl alcohol and hydrogen  peroxide solutions.


•Combustion gases were sampled in plastic bags for immediate analysis with


 an Orsat  analyzer.



      Particle sizing was performed using the Andersen  sampler and the


 Brink impactor.  Further information and details  are included in Appendix J.



      Special care was taken,.not only to obtain all samples during normal
                                      ••

 operating conditions, but for each particulate test to include one tap


 cycle. Any deviation from the standard methods was either approved or


 recommended by the EPA project engineer at the site.
                                    22

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                VIII.  CLEANUP AND ANALYTICAL PROCEDURES
     The methods employed for cleanup of the EPA particulate train have




become relatively standardized through testing incinerators for




government approval.  Various sections of the sampling train were washed




with acetone and water.  The filter was removed carefully and each




portion of the collected particulate matter was placed in separate




containers.  All portions were then dried at ambient conditions and the




water was extracted for organic material, as well as being evaporated




to dryness.  These procedures are outlined in detail in Appendix E.2.







     SO,, samples used simple means of cleanup, using distilled deionized




water as a rinsing medium.  The analytical procedure is somewhat more




involved and details are outlined in Appendix E.2.  Both cleanup and




analytical procedures were conducted in accordance with approved methods.
                                   23

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                             IX.  DISCUSSION
A.   RESULTS

                        &
Scrubber Efficiency


     The efficiency of the venturi scrubber was determined under three

                                                                   /_
conditions.  Condition A employed a venturi pressure drop of 57 inches


of water; Condition B, 47 inches HO; Condition C, 37 inches HO.


Condition A, with the greatest pressure drop, was only slightly more


efficient than Condition B, however, the inlet grain loading under the


former condition was the lowest obtained at any time during the survey.



     As shown in Table 1 under the Summary of Results, the percent


efficiency at each successive condition was 99.1, 99.1, and 96.3.


Because of the difference in flue gas volume at standard conditions,


for the inlet and exhaust locations, the efficiencies were calculated


on the basis of pounds per hour of total particulate matter.



     During the 57" HO pressure drop, extra exhaust samples were


obtained because the inlet duct sampling was plagued with major problems.


Because extra results were available for the exhaust emission under this


condition, some results were not included in the average.  Run M1E-3 was


omitted because the plant was not running at full capacity.  Runs M1E-1


and MlE-2 were not employed since they were not taken simultaneously with


the inlet samples.
                                    24

-------
Scrubber Emissions


     Total particulate concentrations leaving the scrubber exhaust stack


were approximately 0.010 grains per standard cubic foot under normal


operating conditions (A, at 57 inches pressure drop).  When the venturi


pressure drop was reduced to 47" HO, the average emission concentration


was 0.016 grains/SCF.  At Condition C, with a pressure drop of 37" HO,


there was a noticeable change in the emission concentrations and these


averaged 0.048 grains/SCF.  Although the exhaust grain loading concen-


trations gradually increased with the decreased pressure drop across the


venturi, the inlet concentrations neither followed this pattern nor did


they remain constant.  Inlet grain loadings, respectively, were 1.25,


2.05 and 1.53 grains per standard cubic foot.  Note that Condition A


achieved its efficiency with this low inlet grain loading.



Tapping Emissions


     Samples were obtained from the two tapping exhaust stacks simul-


taneously.  Although the two systems were parallel, and apparently


identical, the tap hole and ladle being filled were much closer to the


west system.  Emissions from the unscrubbed stacks were greater than
                                            *

those from the furnace gases ,that had been scrubbed in the venturi system.


Emissions during the three taps sampled were not uniform either between


exhaust stacks or between one tap and the next.
                                    25

-------
     The first simultaneous tests were scheduled, and actually run, during




a period in which no tapping was conducted.  Due to some sort of process




malfunction, the normal tap was omitted for that period of time.  At the




advice of the EPA project officer the equipment was simply sealed (not




cleaned) and the following tapping cycle was sampled.  Since no dust was




emitted there should be little question about the sampling trains being




clean for the second trial.  However, the skipped cycle would have created




an unusual condition within the furnace, and this is believed to have




accounted for the unusual results obtained during the "first" tapping




samples.             (    '






     Emissions from Run WTE-1 were much greater than the comparable East




sample or from any following West sample.  Even during the following




sample (WTE-2) the emissions were still apparently above normal.  By the




third set of samples emissions were similar in both exhaust ducts.  It is




•believed that the third set of samples are more nearly "normal".




Apparently when an unusual amount of fumes are produced the tendency is




for this material to be ventilated through the nearest exhaust system;




but when more normal quantities are produced at the ladle, the fumes have




a chance to become more evenly dispersed, and thereby be emitted more or




less equally from the two exhaust systems.
                                   26

-------
Particulate vs. Total Catch




     The ratio of particulate trapped by the impingers, versus the total




catch, was quite different for samples collected at different locations,




or under different operating conditions.  With one exception, the inlet




duct samples contained less than 2 percent of the total catch as trapped




by the impingers.  These results are similar to those obtained on emissions




from an uncontrolled reactive metals furnace.






     The percentage of "condensible" material at the exhaust stack was




considerably greater, and varied with the operation of the scrubber.




With a scrubber pressure drop of 57" HO the condensibles ranged from




one third of the total to greater than 10 percent of the total.  At the




47 inch pressure drop the percentage was just slightly over 10 percent,




and at the 37 inch pressure drop, was less than 10 percent soluble matter.






     It is believed that the decreasing ratio of condensible material is




due ;to the carry-over of small water droplets from the scrubber system.




The water droplets would contain small amounts of soluble matter, and as




the pressure drop was reduced there would be less tendency for these




droplets to pass through the cyclonic collection chambers.






     Fumes from the tapping operation' have reason to be somewhat




different from the average material emitted from the top of the furnace,




but there are some very unusual results in regard to the solubility ratio




observed.  Those samples from the east exhaust duct were less than 10
                                   27

-------
percent soluble matter, yet the comparative samples (taken simultaneously)


ranged from 20 to 50 percent soluble matter.  In spite of the unusual


process conditions associated with the tapping cycle there appears to be


no logical explanation for the noted difference.



Flue Gas Conditions


     Considering the normal variation in operating conditions, and


observing gas flow from the furnace, the flue gas volume was considered


to be relatively stable between equivalent test runs.  There was a


noticeable increase in flue gas volume, at the same standard conditions,


between the inlet duct and exhaust stack locations.  Although no physical


examination was conducted it seems certain that there are minor points


of air leakage.  As the pressure drop was reduced across the venturi


scrubber there was a decre'ase in the flue gas volume.  This was not


particularly noticeable at the exhaust stack location and did not become


apparent at the inlet location until the lowest pressure drop was being


evaluated.



     Temperatures of the flue gas leaving the exhaust stack were rather


stable during any particular test.  There was relatively little variation


during the entire survey, especially in light of the wild temperature
                                    »•

variations which were encountered at the inlet duct.  Average temperatures


at the inlet duct were generally, and surprisingly, close together in most


cases.  The temperature at any particular moment could range from individual
                                   28

-------
readings between 400°F and 1300°/rduring operation which was considered to

be normal.  Temperature changes of several hundred degrees could occur

within the space of 5 or 10 minutes.
                          /

Gaseous Emissions

     With the exception of a single test, sulfur dioxide emissions were

less than 1 percent at all stack exhausts.  There was no appreciable

difference between those SO^ concentrations being emitted from the tapping

stacks and those from the exhaust stack.  It is doubtful that there was

much scrubbing of sulfur dioxide accomplished by the venturi system.

The .862  run»  with its impinger train, corresponding to particulate

test M1E-11, was accidentally dropped from the stack during a rainy

period.


     Carbon dioxide content from the tapping exhaust stacks was

essentially negligible.  These concentrations were so low, and the

calculation so inaccurate under those conditions, that the percent excess

air actually indicated negative in some instances.  Excess air from a

non-combustion process is simply not applicable.  Carbon dioxide

concentrations at the scrubber exhaust stack were relatively constant,

although there seemed to be a decrease as the pressure drop across the

unit was decreased.  This would imply'"that either there was greater air

leakage, or simply less furnace fumes being collected, as the pressure

drop was reduced.
                                    29

-------
     No carbon monoxide (CO) results are available.  The infrared analyzer

had been calibrated at the laboratory before the survey was begun, however,

within ten minutes after having started operation in the field it failed

to indicate properly. * After two weeks of repair it was discovered that

a completely new sensing unit was required and the unit was sent out for

a major overhaul.


Particle Sizing

     The particle size of material emitted from the exhaust stack is so

small that major differences are hard to determine.  The mass median

diameter (MMD) ranged between approximately 0.2 microns and 0.6 microns

in all tests.  The MMD of material collected at the inlet duct varied

from about 0.6 microns to  5. microns in diameter.


     It must be remembered that the sample time at the inlet duct was

only one or two minutes at a single point.  It is quite unlikely that

any single value would represent a true average of the material being

emitted from the furnace.                              ,  • •     '


     Two simultaneously samples were obtained at each of the tapping ducts.

During the first pair of tests the MMD ranged from 1.75 to 2.5 microns.
                                     »•
During the next set of tests the particle size MMD was only 0.8 or 0.9

microns, indicating the variation that could occur between tapping cycles.

Each of these tests was obtained for a duration of 20 minutes and would

therefore be more representative of an average emission.
                                   30

-------
     Exhaust samples were obtained during periods ranging from 10 minutes




to 55 minutes.  This time period was probably long enough for average




results.  However, the average particle size was so extremely small, that




it was difficult to obtain wholly satisfactory results.







     All of the above particle size results are explained in more




detail in Appendix J.  A graphical representation of each sample is




available in Sub-appendix J-l along with details of the date, operating




condition and time sampled.






Chemical Analyses




     Exhaust samples from the scrubber, and exhaust samples from tapping,




were analyzed by microscope, by qualitative electron beam X-ray micro Analysis




and atomic absorption. 'All samples had a problem due to the very small




quantities of material available for analysis.  Due to the intermixing of




the glass fiber in the filter with particulate matter imbedded in that




filter, it was not possible to analyze for silicon.  All samples obtained




for these chemical analyses were obtained through all-glass pyrex probes.




Details concerning the specific elements and quantities obtained are




found in Appendix J.
                                   31

-------
B.   OPERATING CONDITIONS



Venturi Scrubber
                         i

     As far as can be determined there were no problems with the operation


                          ^
of the scrubber during this test survey.  Whenever observed, the pressure



drop instruments were holding steady at the proper  AP for that series



of tests.





Furnace 1



     According to the megawatt chart, as shown in Appendix C, operating



conditions of the furnace were fairly uniform.  Furnace power was



normally kept between 25 and 30 megawatts, with little fluctuation



except for periods of down-time.  Unfortunately, the periods of down-time,



although low on an overall  24-hour basis, were very disruptive to the test



program.  Inlet and exhaust samples No. 2 and 4 were interrupted by



plant shut-down; but where  previous sampling had been satisfactory, these



were continued until completion of the sample after restarting the furnace.



There ^rere several other periods in which sampling was delayed due to



process shut-down.  Every particulate sample was timed into the ordinary



operating schedule, in order to include one tapping cycle during the



middle of the sample period.
                                  32

-------
C.   TEST CONDITIONS




Inlet Duct




     There was no other feasible location for sampling the inlet duct,




but this was a very poor location in nearly every respect.  The duct work




was obstructed by a series of I-beams about four feet above the top of




the duct.  There was little or no straight flow of gases prior to the




sample point and very little straight flow following the sample location.




The horizontal duct led to immediate stratification of the heavy particles,




and created a very difficult sampling situation with the EPA train in the




vertical position.  In addition the location was dangerously hot, very




dusty, and poorly lighted.






     Due to a misunderstanding, between the presurvey date and the time




of the test survey, many weeks later, the trolley rail was mounted too




low for satisfactory handling of the EPA train.  A bad pulley simply




added to the problems, along with the tendency for filters to become




clogged within minutes.  Nearly four days were eventually required,




including furnace down-time, before all equipment had been properly




situated and the above problems had been solved.  Meanwhile an ASME




type alundum thimble was tried without success, along with other




suggestions.                    .     *






     Until the trolley line was lifted to its proper position, a new




pulley with multiple leverage was purchased, and a smaller size nozzle
                                    33

-------
C.   TEST CONDITIONS

Inlet Duct

     There was no other feasible location for sampling the inlet duct,

but this was a very poor location in nearly every respect.  The duct work

was obstructed by a series of I-beams about four feet above the top of

the duct.  There was little or no straight flow of gases prior to the

sample point and very little straight flow following the sample location.

The horizontal duct led to immediate stratification of the heavy particles,

and created a very difficult sampling situation with the EPA train in the

vertical position.  In addition the location was dangerously hot, very

dusty, and poorly lighted.


     Due to a misunderstanding, between the presurvey date and the time

of the test survey, many weeks later, the trolley rail was mounted too

low for satisfactory handling of the EPA train.  A bad pulley simply

added to the problems, along with the tendency for filters to become

clogged within minutes.  Nearly four days were eventually required,

including furnace down-time, before all equipment had been properly

situated and the above problems had been solved.  Meanwhile an ASME

type alundum thimble was tried without success, along with other

suggestions.
                                     *•    '

     Until the trolley line was lifted to its proper position, a new

pulley with multiple leverage was purchased, and a smaller size nozzle
                                   33

-------
was employed for the EPA train, no satisfactory samples were obtained.


After the above corrections were completed, two inlet tests were conducted


each day according to schedule, in spite of several plant operating


delays.




Outlet Duct


     The vertical exhaust stack, with long straight flow before and after


the sampling location, should have provided good representative sampling.
                                                   1 •    I

A newly constructed, temporary platform was satisfactory except that it


was about one foot short, and therefore the first two positions inside


the stack could not be reached with the long ten foot probe.  The No. 3


position was sampled longer to represent the missed area.  There was a


problem in that only a single port was available for sampling, and this


port was required for particulate samples, for metals samples, and for


S0_ sampling, as well as for particle size sampling.  Only two probes


would fit into the hole.




     The platform was covered but there were several days of rain during


the test survey, and there was a severe problem with electrical shocks


and safety on this platform.  A telephone system connected the exhaust


stack location to the inlet location so that there were no problems of
                                  «•                    .

communication whenever troubles arose.
                                   34

-------
 Tapping Stacks




      Both tapping exhaust locations had excellent platforms located




 inside the building where rain was not a problem.  The fine particles,




 and vertical flow,  increased the possibility of representative sampling.




 Only a single hole was available at each stack but,  because there were




 two parallel systems,  the SO.  sample could be obtained from one stack




 while the metals sample was obtained from the opposite stack.






 Power Problems




      Individual circuits were not available for testing equipment at




 this plant location.  At the inlet duct there were power problems only




 on the first day or two when many simultaneous samples for particulate




 and particle size,  etc., were combined.  Subsequent to that time, all




 particle sizing was conducted when particulate matter samples were




 completed.  No metals  or gaseous samples were collected from that




• location.






      The exhaust location had particulate, sulfur dioxide, metals and




 carbon dioxide sampling, to be conducted simultaneously and offered




 almost continuous problems.  It was impossible to continue tests with




 the original power source, therefore, a second line was provided.




 However, at various times throughout the survey there were electrical




 failures that would delay sampling, especially during the rainy periods.




 There was a severe electrical safety problem during these rainy periods.
                                    35

-------
 Filter Plugging    '




      As was experienced during some samples at the Foote Mineral Company,




 in Steubenville,  Ohio,  there was a severe problem of plugging and vacuum




 buildup in the sample train because of the accumulation of fine




 particulate matter on the glass fiber filters.  (Larger, four inch




 filter holders were ordered but were not available at this time).




 Although several  solutions were suggested, the ultimate cure for the




 problem was to employ a small size nozzle ( 3/16 inch ) so that less




 overall sample was obtained.  Additional filter holders were prepared




 in advance, and these were changed whenever the pressure drop became too




 great for the maintenance of isokinetic conditions.  By having pre-prepared




 filters,  and placing them in the heated box for warmup, it was possible to




 continue sampling rapidly enough so that each test was completed before




 another tapping cycle would have forced shut-down of the train.






 Particle Sizing




;;     Analyses for the distribution of particle size were conducted with




 the Brink Cascade Impactor.  These tests were conducted at both inlet




 and exhaust locations,  as well as at both tapping exhausts.  There were




 many delays due to the lack of sufficient power, and-due to the lack of




 sufficient sample ports for simultaneous sampling with other tests.  As




 discussed in Appendix J, there were problems of high temperature at the




 inlet duct and problems of high moisture content at the exhaust stack.




 The need for high temperature heating tapes at the exhaust stack simply




 increased problems of power failure and made it absolutely impossible for




 simultaneous tests to be conducted.
                                    36

-------
 Tapping Samples

      Appendix D includes raw data for samples ETE-lA and  WTE-lA.   These

 samples correspond to the expected particulate samples  at both  east  and

 west tapping exhausts.  As previously mentioned these were false  runs


 because there was no tapping,  as had been expected.



      Each particulate test at the west tapping exhaust  was accompanied

 with an Orsat analysis.   Due to the rush,  and short  periods of  tapping,

 no analyses were performed for the east exhaust.   The west results were

 certainly satisfactory for any calculation of gas density, and  as has


 been discussed, the Orsat results indicate that all  analyses were

 unnecessary.



 Miscellaneous Problems

      Sulfur dioxide and metals runs were conducted only at the  exhaust

 stack.   These were obtained simultaneously with each particulate  test,

: but they alternated with each other because of the lack of platform

 space and sample port size.  Samples were alternated such that  there was

 one SO. and one metals test conducted under each scrubber condition.

 The metals test corresponding to particulate test M1E-12  was repeated,

 after the filter was ruined by condensed moisture.  Apparently  the heated
                                 I-
 probe was not in operation and this allowed condensation  to reach the

 filter.
                                    37

-------
     Inlet samples MlD-1, -2, -3, were unsatisfactory due to the previously




mentioned sampling problems.  Samples for scrubber Condition A (57" H.O)




were begun with the inlet duct on sample No. 4.  However, additional




samples had already been satisfactorily obtained at the exhaust location.




Sample M1E-6 from the exhaust stack, however, had to be discarded after




there was an electrical short and rheostat failure in the middle of that




run.  With other satisfactory samples available, it was not considered




necessary to repeat this test.






     No preliminary moisture sample was conducted at the inlet duct




after the sample train was destroyed due to unusually high heat on the




duct.  An estimate of only one or two percent was employed but results




indicated that a greater moisture content was normally present.  The




measured moisture contents were greater than would be expected under




the operating conditions of a furnace, but they were repeated in several




successive samples.  It is possible that part of this moisture was




generated by the water leaks which were prevalent around the furnace,




and also, both in and around the exhaust duct.
                                   38

-------
APPENDIX
   39

-------
                   APPENDIX B
COMPLETE GASEOUS RESULTS WITH EXAMPLE CALCULATIONS

-------
                                         SO-EMISSION DATA
Run No. ' • '
Date - -..'...
mg S09 	 . _ „...'.'. ..
j ^ ~ .
T - Average Gas Meter Temperature, °F
Pv - .Barometric Pressure, "Hg abs.
V - Volume of dry gas sampled @ meter
m conditions, ft.-*
• ppm_S02 ' .
l-E
7/27/71
0:31

75
29.5
31.64
0.158
2-E
7/29/71
2.5

68
29,5
6.98
5.21
3-E
7/3C/71
o

66
29.5
10:38
0
4-E
7/31/11
0.19

77
29.5
11.00
0.266
5-E
7/31/71
0.19

88
29.5
9.62
0.302








       Vacuum
- 5.0
                                                 2.9
                                                           3.4   3.7-   3.0
       Vstd  -  Volume of sampled gas converted  '    •                     •    t. •"  ."
              ..  to standard conditions            .25:7    6.21   9.14   9.36    8.24

                                                   Not used because the meter was
                                                   "under vacuum.
l-E-

  l-E
Vstd  -
.  ppm S02
                    fO'31)(13.1)
                    v   25)7
                            0.158
                                                25.7
                                                                         B-l

-------
Run No. ' . • '
Date
dig SOo _ 	 	 . ... ..... .' ....
T - Average Gas Meter Temperature, °F
IV - .Barometric Pressure, "Hg abs.
V - Volume of dry gas sampled @ meter
m conditions, ft.3
• ppm SOg " . ... .
8-E
8/2
0. 28
79
29.7
6.97
).587
9-E
8/2
0.06"
81
29.7
24.70
0.0340
10 -E
8/3
0.19
68
29.6
3.69
0.737
•

	











•






  Vacuum
.2.4
                                                     1.2     2.3
  Vstd -  Volume'of sampled gas converted

         .to standard condition's
 6V25    23.1
3.38
"::   :  -     0.7332 X mg S02 X  (Tm + 460)


 ppm S0? =   	'•	
    *- . * **                       •       "        .•
                                                                        B-2

-------
                                   SO •EMISSION  DATA
Run No. " •'•.-.
Date - . (197i)
mg SO, 	 . .
y c. ' 	
T - Average Gas Meter Temperature, °F
m
PV- .Barometric Pressure, "Hg abs.
V - Volume of dry gas sampled @ meter
m conditions, ft.^
' Ppm SO 2
WTE-l
8/5
Qpt90

75
29.6-
3.95
0703
WTE-2
8/5
0 000

79
29 ..6
2.45
0.361
ETE-3
8/5
)060

75
29.6
l.t)
0.833
*























  Vacuum
2.5
2.5  .   1.1
         _ Volume of.dry gas converted

          to standard conditions
3.54   2.1.8   0.944
>: -; •   '  .      0.7332 X mg  SO, X (T  + 460)
. „*.	.	                c. .    m


  fjpm S02  =   	:	;	



           -     ..,,-V XVm
                                                                         B-3

-------
ORSAT RESULTS
Test Number
M1E- 1
   - 2
   - 3

   - 5
   - 6
   - 7
   - 8
   - 9
   -10
   -11
   -12

WTE- 1
   - 2
   - 3
Date
7/27/71
7/29/71
7/30/71
7/31/71
7/31/71
Discarded
8/1/71
8/2/71
8/2/71
8/3/71
8/3/71
8/4/71
8/5/71
8/5/71
8/5/71
7» C02
2.1
3.4
1.9
2.8
3.3
-
3.0
3.2
3.4
3.2
3.2
3,1 ,
0.2
0.1
0.1
7, 02
19.2
18.3
18.6
18.8
18.4
'
18.6
18.6
18.5
18.8
18.6
18.7
21.2
20.9
21.2
                        7. CO
                        Negligible
                        Negligible
                        Negligible
                                            B-4

-------
                      APPENDIX A
COMPLETE PARTICULATE RESULTS WITH EXAMPLE CALCULATIONS

-------
                           SUMMARY OF RESULTS - SCRUBBER EXHAUST
• Run Number
Date
Stack Flow Rate - SCFM * dry
7. Water Vapor - % Vol.
% CO 2 - Vol % dry
% 07 - Vol % dry
* IS
7» Excess air (? sampling point
S(?2 Emissions - ppm dry
NO Emissions - ppm dry
X
Particulates
Probe, Cyclone, & Filter Catch
gr/SCF* dry
gr/CF (? Stack Conditions
Ibs./hr.
Particulate from Impinger
Train (7, of Total")
Total Catch
gr /SCF * dry
gr /CF (§ Stack Conditions
Ibs./hr.
Stack Temperature
M1E-1
7/27/71
113,000
18.5
2.1
19.2
1110
0.158
-
0.0103
0.00728
9.97
38.
0.0166
0.0117
«'
16.1
140
**
M1E-2
7/29/71
112,200
15. A
3.4
18.3
723
5.21
-
0.00710
0.00520
6.83
3S.
0.0110
0.00805
10.5
140
M1E-3
7/30/71
122,100
12.9
1.9
18.6
729
0
-
0.0107
O.t0839
11.2
n .
0.0122
0.00956
12.8
118
M1E-4
7/31/71
116,800
15.8
2.8
18.8
917
0.266
-
0.00813
0.00594
8.14
ifi.
0.00967
0.00706
9.68
139
M1E-5
7/31/71
110,200
17.2
3.3
18 i 4
757
0.302
-
0.00889
0.00684
8.39
15.
0.0105
0.00807
9.91
140
M1E-6
-
-
-
-
-
"
-
-

-
-

-
-
-
-
        ** Plant running at approximate  one  half-load.
* 70°F, 29.92"  Hg
                                                                         A-l

-------
                           SUMMARY OF RESULTS  - SCRUBBER EXHAUST  (CONTINUED)
Run Number
Date
Stack Flow Rate - SCFM * dry
7. Water Vapor - 7. Vol.
% C02 - Vol 7, dry
7. 09 - Vol 7» dry
^ A,
7o Excess air (? sampling point
S0« Emissions - ppm dry
NO Emissions - ppm dry
X
Particulates
Probe, Cyclone, & Filter Catch
gr/SCF* dry
gr/CF @ Stack Conditions
Ibs./hr.
Particulate from Impinger
Train (% of Total)
Total Catch
gr /SCF * dry
gr /CF @ Stack Conditions
Ibs./hr.
Stack Temperature
M1E-7
8/1/71
118,100
16.1
3.0
18.6
827
-
• -
0.0150
0.0111
15.2
12.
0.0170
0.0126
17.2 .
135
M1E-8
8/2/71
115,000
18.2
3.2
18.6
845
0.587
-
0.0180
0.0132
17.7
9.
0.0197
0.'0144
19.4
127
M1E-9
8/2/71
121,100
15.3
3.4
18.5
815
0.0340
-
0.0114
O.t)0831
11.8
13.
0.0131
0.00955
13.6
134
M1E-10
8/3/71
114,300
17.6
3.2
18.8
964
0.737
-
0.0138
0.0100
13.5
4.
0.0144
0.0104
14.1
130
M1E-11
8/3/71
112,000
16.7
3.2
18.6
845
-
-
0.0369
0.0270
35.4
17.'
0.0445
0.0326
42.7
133
M1E-12.J
8/4/71
103, 20C
17.6
3.1
18.7
890
-
-
0.0798
0.0576
70.6
6.
0.0849
0.0613
75.1
132
* 70°F, 29.92"  Hg
                                                                         A-2

-------
 REPORT NO.
                                      PAGE
                    OF
      PAGE
                               SOURCE TESTING CALCULATION FORMS
 Test. No.
                                         No. Runs    11
 Name of Firm
Union Cartide
.Location Of Plant   Marietta,  Ohio

 Type"Of Plant    -   Ferro Alloy
 Control Equipment   Scrubber -. Venturi"'-.Type-
 Sampling Point Locations    Scrubber Exhaust Stack

 Pollutants Sampled  .Participate	
 Time of Particulate Test:

 Run No.  MlE-l

 Run No.  M1E~2  '
      Date   7/27/71
Begin
      Date   7/29/71
Begin
        1035
 End   2112
 End
 Run No.  MiE-3
      Date   7/30/71
Begin   1815
          M1E-4
          M1E-5
         . .7/31/71.
            7/31/71
        1034
        1545
' End   1940
    .   1252
      - 1713
                               PARTICULATE EMISSION DATA
Run No. .. •
p barometric pressure, "Hg Absolute
p orifice pressure drop, "H,,0
f? . *•
V volume of dry gas sampled @ meter
m conditions, ft. 3
T Average Gas Meter Tempera tare, °F
V Volume of Dry Gas Sampled @ Standard
mstd. Conditions, ft. 3
V Total H?0 collected, ml., Impingers
w & Silical Gel.
V Volume of Water Vapor Collected
Wgas ft. 3 @ Standard Conditions*
MlE-l
29,5
2.03
58.61
84
56.6
269.
12.8_.
M1E-2
29.5
2.03
63.60
84
61.4 •
234.
11..1.:
MIE-3
29.5
2.20
64.09
92
61.10
190.9
9\05
i .
M1E-4
29.5
2.04
74.15
95
70.10
276.5
13.1
M1E-5
29.5 "
2.05
70.31
106
65.15
285.
13.5. •
'
M1E
,_ • *





1
i - •
                            * "Discarded
    * * 70°F, 29.92" Hg.  -  •=-•--•
                                                                       A-3

-------
REPORT NO.
PAGE
OF
PAGES
                              SOURCE TESTING CALCULATION FORMS
Test. No.
Name of Firm
""•'-- : .'•::. . No. Runs
1 ' ' " . *
Location of Plant • '
Type" of Plant
Control Equipment
Sampling Point Locations
Pollutants Sampled -
Time of Parti cul ate Test:
Run No. MiE-7
Run No. M1E'8 '
Run No.MiE-9
•M1E-10
V • •-•MlE-il ..-" '••'.' .
M1E-12 " i -.
. •• • • • *
"'. — - -^ ' "*
*
"• '
Date 8/1/71 Begin "1540 .. • End 1655
Date '8/2/71 ' Begin °945 End ins
Date 8/2/71 Begin 1805 • End 2000
8/3/71 1010 • - 1140
. • ' .8/3/71 - 1400 ,•';. 1530
. 8/4/71 " • • 1115 . 1245
PARTICULATE EMISSION DATA
Run No. . •
P. barometric pressure, "Hg Absolute
b
p orifice pressure drop, "H90
rt ' £
V volume of dry gas sampled @ meter
conditions, ft. 3
T Average Gas Meter Temperature, °F
V Volume of Dry Gas Sampled @ Standard
std. Conditions, ft. 3
V Total KLO collected, ml., Impingers
w & Silical Gel.
V Volume of Water Vapor Collected
wgas ft. 3 @ Standard Conditions*
M1E-7
29.7
2.19
68.99
110
64.0
259 . 2
12.3-
M1E-8
29.7
2.02
67.96
107
63.40
298.2
14.i'-'
M1E-9
29.7
2.01
70.95
106
66.25
253. -2
12.0
M1E-10
29.6
2.10
68.72
91
65.75
!95.4
14.0
M1E-1J
29.6 '
2.0
67.79
99
63.60
260.7
12.7
M1E-1
29.'5
1.7
62. 3S
90
59. 3C
268.2
1
;12.7
1
   • * 70 F, 29.92" Hg.  -   —
                                                                     A-4

-------
PARTICULATE EMISSION DATA (CONT'D)
Run No.
7M-7, Moisture in the stack gas by
volume
Md - Mole fraction of dry gas
7. C02
7. 02
7. N2
M W
-------
PARTICULATE EMISSION DATA (CONT'D)
Run No.
%M -7. Moisture in the stack gas by
volume
Md - Mole fraction of dry gas
7. C02
7o 02
7. N2
M Wd - Molecular weight of dry
stack gas
M W - Molecular weight of stack gas
APs - Velocity Head of stack gas,
In.H20
Ts - Stack Temperature, °F
&PS X(TS + 460)
Ps - Stack Pressure, "Hg. Absolute
Vs - Stack Velocity @ stack
conditions, fpm
o
As - Stack Area, in.
Qs -. Stack Gas Volume @
Standard Conditions, *SCFM
Tt - Net Time of Test, min.
Dn - Sampling Nozzle Diameter, in.
7ol - Percent isokinetic
mf - Particulate - probe, cyclone
and filter, mg.
mt - Particulate - total, mg
Can - Particulate - probe, cyclone,
and filter, gr/SCF
Cao - Particulate - total, gr/SCF
Cat - Particulate - probe, cyclone,
and filter,
gr/cf @ stack conditions
M1E-7
16.1
0.8"39
3.0
18.6
78.4
29.22
27.45
0.73
135
20.8
29.6
3180.
7235.
118,100
90
0.25
95%
62.4
70.9
0.0150
0.0170
0.0111
M1E-8
18.2
0.818
3.2
18.6
78.2
29.29
27.23
0.72
127
20.55
29.6
3140.
7235.
115,000
90
0.25
96.
74.3
81.3
0.0180
0.0197
0.0132
M1E-9
15.3
0.847
3.4
18.5
78.1
29.32
27.56
0.76
134
21.2
29.6
3230.
7235.
121,100
90
0.25
95.
49.2
56.2
0.0114
0.0131
0.00831
M1E-10
17.6
0.824
3.2
18.8
78.0
29.23
27.22
0.71
130
20.42
29.49
3120.
7235.
114,300
90
0.25
98.
58.8
61.6
0.0138
0.0144
0.0100
M1E-11
16.7
0.833
3.2
18.6
78.2
29.26
27.43
0.67
133
19.9
29.47
3040.
7235.
112,000
90
0.25
99.
152.4
184.1
0.0369
0.0445
0.0270
M1E-12 '
17.6
0.824
3.1
18.7
78.2
29.14.
27.17
0.58
132
18.5
29.38
2845.
7235.
103,200
90
0.25
99.
307.0
326.9
3.0798
3.0849
0.0576
                                                        A-6

-------
                       PARTICULATE EMISSION DATA (cont'd)
Run No. ' ' ...
C -Particulate, total, gr/cf
a G> stack cond. ' '
C . - Particulate, probe, cyclone,
aw and filter, Ib/hr.
C - Particulate - total, Ib/hr. •
ax
% EA - % Excess air G>
	 oump 1 1 iiy pu i ii u ,,„,,..,
M1E-1
0.0117
9.97
L6.1
L110.
M1E-2
D. 00805
6.83
10.5
723 1 .
M1E-3
3II5956
11.2
12.8
729_.
M1E-4
a00706
8.14
9.68
917.
WE -5
O.G0607
8.39
9.91
757. _.
M1E-6





70°F.  29.92" Hg.
                                                                   A-7

-------
                       PARTICIPATE EMISSION DATA (cont'd)
Run No. ' ' *
C - Parti cul ate, total, gr/cf . '••/_
@ stack cond.
C . - Parti cul ate, probe, cyclone,
aw and filter, Ib/hr.
C v - Parti cul ate - total, Ib/hr. • •
3X
% EA"- % Excess air @
	 buiup i i ny pj i ii u . 	
M1E-7
).0126
15,2
17.2
827.
M1E-8
aoiAi
17.7
19.4
845.
M1E-9
0.00955
11.8
13.6
815.

41E-10
0.0104
13.5
14.1
964.
MlE-11
).0326
35.4
42.7
845.
MLE-12
0.0613
70.6
75.1
890

70°F. 29.92" Hg.
                                                                  A-8

-------
                           SUMMARY OF RESULTS  - SCRUBBER INLET
Run Number
Date
Stack Flow Rate - SCFM * dry
% Water Vapor - % Vol.
% C02 - Vol % dry
7, 09 - Vol 7. dry
* A,
7o Excess air (? sampling point
S0? Emissions - ppm dry
NO Emissions - ppm dry
X
Particulates
Probe, Cyclone, & Filter Catch
gr/SCF* dry
gr/CF 
-------
                           SUMMARY OF RESULTS - SCRUBBER INLET   (CONTINUED)
Run Number
Date
Stack Flow Rate - SCFM * dry
% Water Vapor - 7. Vol.
7. C02 - Vol % dry
7. 0, - Vol 7» dry
^ *
% Excess air (? sampling point
S02 Emissions - ppm dry
NO Emissions - ppm dry
X
Particulates
Probe, Cyclone, & Filter Catch
gr/SCF* dry
gr/CF @ Stack Conditions
ibs./hr.
Particulate from Impinger
Train (7. of Total)
Total Catch
gr /SCF * dry
gr /CF @ Stack Conditions
Ibs./hr.
Stack Temperature
MID- 10
8/3/71
91,000
4.61
N/A
n
ii


0.965
0.431
752.6
1.7
0.982
0.438
765.9
655
MID-11
8/3/71
85,000
8.9
N/A
n
n


1.66
0.709
1209.
1.8
1.69
0.722
1231.
654
MID-12
8/4/71
94,900
4.8
N/A
ti
M


1.91
0.948
1553.
0.5
1.92














0.953
1562.
541
..











•














.








* 70°F, 29,92"  Hg
                                                                          A-10

-------
 REPORT NO.
                                     PAGE
OF
PAGES
                               SOURCE TESTING CALCULATION FORMS
 Test.  No.
                                        No. Runs
 Name of Firm
Union Carbide
. Location Of Plant   Marietta,' Ohio
 Type "of Plant	-
Ferro Alloy
 Control Equipment   Scrubber
 Sampling Point Locations  inlet duct  to  scrubber
 Pollutants Sampled -Particulate
 Time of Particulate Test:
 Run No.  MiD-4           Date   7/31/71
                           Begin   ib'ao •
   End  1257
Run No.
Run No.
• •—
MID- 5 '
MID- 6 '
•MID- 7
MID-8 ' .
' MID- 9 ' - ;
Date
Date
".
7/31/71
8/1/71
.8/1/71
8/2/71
8/2/71
Begin
Begin

1500
1100
1525
0945
1810
End
• End
.••"-•
1626
1247
1700
.1115
1929
                              PARTICULATE EMISSION DATA
Run No.
p. barometric pressure, "Hg Absolute
p orifice pressure drop, "H90
is *•
V volume of dry gas sampled @ meter
conditions, ft. 3
T Average Gas Meter Temperature^ °F
V Volume of Dry Gas Sampled @ Standard
std. conditions, ft. 3
V Total HpO collected, ml., Impingers
w & Silica! Gel.
V Volume of Water Vapor Collected
Wgas ft. 3 @ Standard Conditions*
MID-4
29.5
0.40
21.66
90
20.6
22.2
1.05--
MID-5
29.5
0.31
1-9.72
90
18.7 •
25.5
1.21 *
MID-6
29.5
0.42
21.54
90
20.4
25.7
1.22
MID-7
29.7
0.41
20.02
98
18.9
22.5
1.06
MID-8
29.7 "
0.38
20.05
94
19.05
24.6
MID-9
29 ."7
.•
0.37
20.96
94
19.85
25.2
1.16 :1.19
I
    ' * 70°F, 29.92" Hg.
                                                                       A-ll

-------
REPORT NO.
          PAGE
            OF
      PAGES
Test. No.
Name of Firm
Location of Plant_
Type"of Plant    •
Control Equipment_
Sampling Point Locations_
Pollutants Sampled -
                              SOURCE TESTING CALCULATION  FORMS
             No. Runs
Time of Particulate Test:
Run No.    MID-10        Date   8/3/71
Run No.    MID-11        Date   8/3/71
Run No.    M1D-12        Date   8/4/71
Begin   1006'
Begin_
1400
Begin
        1048
               End 1122
 End  1527
' End
                             PARTICULATE  EMISSION  DATA
Run No.
p. barometric pressure, "Hg Absolute
b
p orifice pressure drop, "H?0
"? *-
V volume of dry gas sampled @ meter
111 conditions, ft. 3
T Average Gas Meter Temperature, °F
V Volume of Dry Gas Sampled @ Standard
std. Conditions, ft. 3
V Total H?0 collected, ml., Impingers
w & Silica! Gel.
V Volume of Water Vapor Collected
wgas ft. 3 (3 Standard Conditions*
MID-10
29.6
0.31
20.65
91
19.65
20.0
0.95
MID- 11
29.6
0/27
17.93
92
17.0-
34.9
1.66 .
MID-12
29.5
0.31
18.02
86
17.23
18.6
0.87






	

-







"„•





1
   ' * 70°F, 29.92" Hg.  -  -----
                                                                       A-12

-------
PARTICULATE EMISSION DATA (CONT'D)
Run No.
7M -7« Moisture in the stack gas by
volume
Md - Mole fraction of dry gas
7. C02
7. 02
7. N2
M W<| - Molecular weight of dry
stack gas
M W - Molecular weight of stack gas
A Ps - Velocity Head of stack gas,
In.H20
Ts - Stack Temperature, °F
&PS X(TS + 460)
Ps - Stack Pressure, "Hg. Absolute
Vs - Stack Velocity @ stack
conditions, fpm
0
As - Stack Area, in.
Qs - Stack Gas Volume @
Standard Conditions, *SCFM
Tt - Net Time of Test, min.
Dn - Sampling Nozzle Diameter, in.
%I - Percent isokinetic
mf - Particulate - probe, cyclone
and filter, mg.
mt ~ Particulate - total, mg
Can - Particulate - probe, cyclone,
and filter, gr/SCF
cao ~ Particulate - total, gr/SCF
Ca(- - Particulate - probe, cyclone,
and filter,
gr/cf @ stack conditions
MID-4
4.85
0.952
-
-
-
29.14
28.36
0.53
599
23.62
29.42
3580
8976
104,500
60
0.187
112 "
1404.4
1416.3
1.05
1.06
0.491
MID-5
6.07
0.939
-
-
-
29.23
28.50
0.50
674
23.79
29.42
3590
8976
96,500
60
0.187
110
514.6
563.3
0.423
0.464
0.182
MID- 6
5.63
0.944
-
-
-
29.18
28.71
0.50
607
23.1
29.42
3500
8976
100,800
60
0.187
115
2942.6
2954.9 .
2.22
2.23
1.02
MID-7
5.30
0.947
-
-
-
29.22
28.65
0.58
631
25.15
29.42
3460
8976
97,900
60
0.187
112
2362.4
2394.4
1.92
1.95
0.866
MID- 8
5.74
0.942
-
-
-
29.26
28.63
0.55
633
24.6
29.42
3700
8976
103,200
60
0.187
95
2597.6
2628.9
2.10
2.12
0.942
MID-9
5.65
0.944
-
-
-
29.24
28.61
0.56
629
24.7
29.42
3710
8976
104,600
60
0.187
108
2654.9
2667.9
2.06
2.07
0.930
                                                      A-13

-------
PARTICULATE EMISSION DATA (CONT'D)
Run No.
7M-% Moisture in the stack gas by
volume
Md - Mole fraction of dry gas
% C02
7. 02
7. N2
M Wd - Molecular weight of dry
stack gas
M W - Molecular weight of stack gas
APs - Velocity Head of stack gas,
In.H20
Ts - Stack Temperature, °F
&PS X(TS + 460)
Ps - Stack Pressure, "Hg. Absolute
Vs - Stack Velocity @ stack
conditions, fpm
2
As - Stack Area, in.
Qs - Stack Gas Volume @
. Standard Conditions, *SCFM
Tt - Net Time of Test, min.
Dn - Sampling Nozzle Diameter, in.
%I - Percent isokinetic
mf - Particulate - probe, cyclone
and filter, mg.
Bit - Particulate - total, mg
Can - Particulate - probe, cyclone,
and filter, gr/SCF
Cao - Particulate - total, gr/SCF
Cat - Particulate - probe, cyclone,
and filter,
gr/cf (3 stack conditions
MID-10
4.61
0.954
-
.
-
29.23
28.73
0.43
655
21.9
29.50
3260
8976
91,000
60
0.187
122
1231.0
1252.5
0.965
0.982
0.431
MID- 11
8.9
0.911
-
-
-
29.18
28.18
0.40
654
21.1
29.51
3180
8976
85,000
60
0.187
114
1836.2
1862.8
1.66
1.69
0.709
MID-12
4.8
0.952
-
-
-
29.18
28.61
0.42
541
20.5
29.5
3060
8976
94,900
60
0.187
103
2141.7
2149.6
1.91
1.92
0.948





































































                                                        A-14

-------
                       PARTICIPATE EMISSION DATA (cont'd)
A
Run No. ' •' .
C - Parti cu-lete, total, gr/cf
@ stack cond. ' • ."
Ca - Parti cul ate, probe, cyclone,
aw and filter, Ib/hr.
C v - Parti cul ate - total, Ib/hr.
ax
% EA"- % Excess air 6» -
	 scuip liny point
MID-4
0.496
940:4
949.3
N7A
MID-5
0.200
349.8
383.7
H/A .
MLD-6
LT02
1918.
1926.
N/A_-.
MID-7
0.879
1611.
1636.
.N/A:.
MID-8
»
0.951
1857.
1875.
N/A_..
11D-9
0.934.
1846.
1856.
15_/A
70°F.  29.92" Hg.
                                                                  A-15

-------
                       PARTICIPATE  EMISSION DATA (cont'ci)
Run lio. • "' -* .
C - Participate, total, gr/cf
a @ stack cond.
C - Parti cul ate, probe, cyclone,
aw and filter, Ib/hr.
C „ - Parti cul ate - total, Ib/hr. •
ax
% EA - 2 Excess air @
	 ouinp iinypjiiiu
MID- 1C
0.438
752.6
765.9
N/A
MID-11
0.722
1209.
1231.
N/A.
MID-12
3 ."953
1553.
1562.
N/A,.






»


- ---

.




70°F. 29.92" Hg.
                                                                   A-16

-------
                           SUMMARY OF RESULTS   - TAPPING EXHAUST
Run Number
Date
Stack Flow Rate - SCFM * dry
% Water Vapor - 7. Vol.
% CO 2 - Vol 7, dry
7. 0, - Vol 7. dry
z *,
7» Excess air @ sampling point
S02 Emissions - ppm dry
NO Emissions - ppm dry
X
Particulates
Probe, Cyclone, & Filter Catch
gr/SCF* dry
gr/CF @ Stack Conditions
Ibs./hr.
Particulate from Impinger
Train (7. of Total)
Total Catch
gr /SCF * dry
gr /CF @ Stack Conditions
Ibs./hr.
Stack Temperature
ETE-1
8/5/71
70,100
4.95
-
-
N/A
-
-
X0358
0.0316
21.5
2.
0.0366
t.
0.0323
22.0
107
ETE-2
8/5/71
70,000
A. 12
-
-
N/A
-
-
X0249
0.0224
14.94
10.
0.0275
0'.0248
16.5
100
ETE-3
8/5/71
69,700
3.74
-
-
N/A
0-833
-
0.0284
0/0258
16.96
8.
0.031
WTE-1
8/5/71
64,250
3.11
0.2
21.2
N/A
D.703
-
0.128
0.114
70.5
20.
0.160
0.0282 0.1429
18.5
97
88.2
111
WTE-.2
8/5/71
61,800
3.32
0.1
20.9
N/A
0361
-
0.0483
0.0428
25.6
30.
0.0696
0.0616
36.9
115
FTE-3
8/5/71
64,700
2.72
0.1
21.2
N/A
-
-
0.0169
0.0153
9.37
48.
0.0329
0.0297
18.25
107
* 70°F, 29.92"  Hg
A-17

-------
REPORT NO.
                                     PAGE
OF
PAGES
                               SOURCE TESTING CALCULATION FORMS
Test. No.
                                        No. Runs
Name of Firm
Union Carbide
Location Of Plant_   Marietta^ Ohio

Type "of Plant	•_
Ferro Alloy - Reactive Metals
Control Equipment    Scrubber
Sampling Point Locations   East and West Tapping Exhausts
                                                   »
Pollutants Sampled  - ^articulate.  S02       	
Time of Particulate  Test:              .  .-     ''• ".
Run No. ETE-I   WTE-I     Date 8/5/71  8/5/71    Begin 113'6  •  113.0.
                                                  •End 1207 1207
Run No. ETE-2   WTE-2     Date 8/5/71  8/5/71    Begin 1^30    1430     EnjlSOl 1500

Run No. ETE-3   WTE-3     Date 8/5/71  8/5/71    Begin 1602    1604    • Endi632 1634
                              PARTICULATE EMISSION DATA
Run No. . -
p barometric pressure, "Hg Absolute
p orifice pressure drop, "H90
^, rt .- *-
V volume of dry gas sampled @ meter
conditions, ft. 3
T Average Gas Meter Temperature, °F
V Volume of Dry Gas Sampled @ Standard
std. Conditions, ft. 3
V Total H?0 collected, ml., Impingers
w & Silical Gel.
V Volume of Water Vapor Collected
wgas ft. 3 @ Standard Conditions*
ETE-l
29.7
1.76
30.19
104
28.22
31.0
1.47-
ETE-2
29.7
1.76
22.65
96
21.48
19.5
0 . 924
_
ETE-3
29.7
1.74
21.89
97
20.74
17.0
0.806
WTE-1
29.7
1.34
22.77
106
21.22
14.4
0.682
WTE-2
29.7 '
1.26
17.91
97
16.96
12.3
0.583
WTE-3
29'.J
1.33
t
18.63
1
101
1
I
17.52
10.4
0.493
_J
   ' * 70 F, 29.92" Hg.  -  ----
                                                                        A-18

-------
PARTICULATE EMISSION DATA (CONT'D)
Run No.
7M -7» Moisture in the stack gas by
volume
Md - Mole fraction of dry gas
% C02
% 02
% N2
M W,j - Molecular weight of dry
stack gas
M W - Molecular weight of stack gas
APs - Velocity Head of stack gas,
In.H20
Ts - Stack Temperature, °F
&PS X(TS + 460)
Ps - Stack Pressure, "Hg. Absolute
Vs - Stack Velocity @ stack
conditions, fpm
o
As - Stack Area, in.
Qs - .Stack Gas Volume @
Standard Conditions, *SCFM
Tt ~ Net Time of Test, min.
Dn - Sampling Nozzle Diameter, in.
%I - Percent isokinetic
mf - Particulate - probe, cyclone
and filter, mg.
mt ~ Particulate - total, mg
Can - Particulate - probe, cyclone,
and filter, gr/SCF
Cao - Particulate - total, gr/SCF
Cat - Particulate - probe, cyclone,
and filter,
gr/cf @ stack conditions
ETE-1
4.95
0.950
-
-
_
28.9
28.34
1.28
107
27.0
29.7
4052
2826
70,100
37
0.187
119
65.6
67.2
0.0358
0.0366
0.0316
ETE-2
4.12
0.959
-
-
-
28.85
28.41
1.24
100
26.4
29.7
3962
2826
70,000
31
0.187
106
34.7
38.4
0.0249
0.0275
0.0224
ETE-3
3.74
0.963
-
-
-
28.86
28.46
1.22
97
26.1
29.7
3905
2826
69,700
30
0.187
107
38.2
41.8
0.0284
0.031
1
0.0258
WTE-1
3.11
0.969
0.2
21.0
78.8
28.88
28.54
1.05
111
24.5
29.7
3666
2826
64,250
37
0.187
97.7
176.9
220.5
0.128
0.160
0.114
WTE-2
3.32
0.967
0.1
20.8
79.1
28.85
28.49
0.98
115
23.8
29.7
3561
2826
61,800
30
0.187
98.3
53.2
76.7
0.0483
0.0696
0.0428
WTE-3
2.72
0.973
0.1
21.1
78.8
28.86
28.57
1.05
107
24.4
29.7
3650
2826
64,700
30
0.187
98.6
19.2
37.4
0.0169
0.0329
0.0153
                                                       A-19

-------
                       PARTICIPATE EMISSION DATA (cont'd)
Run Mo. • ' * ' -
C - Parti cul ate, total, gr/cf
aj @ stack cond. '
C ' - Particulate, probe, cyclone,
aw and filter, Ib/hr. x .
C - Particulate - total, Ib/hr. •
a*
% EA - % Excess air @ .
	 SGiTipi ing point
ETE-1
0.0323
21. -5
22.0
N/A .
ETE-2
X0248
14.94
16.5
•N/A..
•TE-3
0.0282
16.. 96
18.5
M/A..
WTE-1
0.1429
70.5
88.2
JN./-A..
WTE-2
t
0.0616
25.6
36.9
N/A
JTE-3
3.0297
9.37
18.25
&/A
70°F.  29.92" Hg.
                                                                    A-20

-------
                    EXAMPLE PARTICULATE  CALCULATIONS
ETE-1 •
1.   Volume_of dry gas  sarapied  at  standard  conditions  - 70°F,  29.92"

     Hg, ftJ.
                  X V  /P_  +  P    \
                     m I  B     m    )

                       \      I1.fi/
        17.7
                m I  K.     m    I
V     = __ N     13.6 /  - Ft.

 mstd       (T  + 460)"
              sn

                                1.76

         (17.7)(30.19)(29.7 +  13.6   ")

                    564
              28.22
2.   Volume of water vapor  at  70°F  and  29.92"  Hg,  Ft.3
     V     = 0.0474 X V  =  ft.3
      w                w
       gas
            =(0.0474)(31.0)



            =  1.47









3.   % moisture  in  stack gas
          100 X V
                           «
                         " 7.
          V     + V
           m  ,_,    w
            std      gas
           (100)(1.47)

           28.22 + 1.47



           4.95
                                                                       A-21

-------
4.   Mole fraction of dry gas
          100 - %M
             100
          100 - 4.95
           100
                 = 0.950
5.   Average molecular weight of dry stack gas
M
         d = (%C°2

                                                       ) =   28.9
             For this  calculation,  data  from WTE-1 was used, as an
             Orsat  analysis was  not taken  for ETE-1.

6.   Molecular weight of stack gas


     M W = M W  , X M, + 18 (1 - Mj
               ad            d

         =  (28.9)(  .950) + 18(1  -  .950)

         «  28.34
7.   Stack velocity @ stack conditions, fpm
     V  = 4350 XVAP  X (T  •-+ 460)
      s             s     s      '
           (4350)(27

           4052
               .0)  1  (29.7)(28.
34)
                                   P  X M W
                                    s
                                    1/2
                                              1/2


                                                = fpm
                                                                    A-22

-------
8.   Stack gas volume @ standard conditions,  SCFK
          0.123 X Vs      X As X Md X P&
     Qs *       (T  + 460)
                  s
           (0.123)(4052)(2826)(0.950)(29.7)
                      567

        -  70,100
9.   Percent isokinetic

         1032 X  (T + 460) XV
     •J-r	SL
         V  XT  X P  X M, X (D
  .        s    t    s    d   ^ n

          (1032)(567)(30.19)
       =  (4052)(37)(29.7)(.950)(0.035l)
                          t
       =  119



10.  Particulate  - probe, cyclone,  and  filter,  gr/SCF

                      Mf
     C   =0.0154 X	  = gr/scf
      an            V
                     mstd

         _ (0.0154)(65.6)
               28.22

         =  0.0358

11.  Particulate  total, gr/SCF

                      Mt
     C   » 0.0154 X	  ,.= gr/SCF
      flO            V
                     mstd

            (0.0154)(67.2)                  '
                 28.22                               ^

         =  0.0366
                                                                      A-23

-------
12.  Particulate  - probe, cyclone and filter,

     gr/CF at stack conditions
           17.7 X C   X P  X M,
     c   K         an    s    d   _ a-/rp

     Cat       
-------
16.  7» excess air at sampling point

                 100 X % 0
            (0.266 X %
            (100X19.2)
            (0.266)(78.7) - 19.2

            1110
          this calculation, data from M1E-1 was used as % Excess
      air at sampling point is not applicable for the tapping
      exhausts.  •     .
                                                                     A-25

-------
                    APPENDIX C
COMPLETE OPERATION RESULTS WITH EXAMPLE CALCULATIONS

-------
                             TAP DATA - NO, 1 FURNACE - MARIETTA, OHIO
p
N
i
*>
•*
".
5
6
7
f,
D
a
0
i
A .

?
3
4
5
6
7
8
9
0
1
2

:3
4
>
•6
;7
;8
!9
'0
a
'2
•3
14
15
•6
'7
»3
'9
•0
• 1
'2
•3
i4
15
•6

Shift
8/4
8/4
fi/4
S/4
8/4
8/4
ft/12
ft/12
ft/12
ft/12
ft/12

12/8
12/8
12/8
12/8
12/8
ft/12
ft/12
ft/12
ft/12
ft/12
ft/12

12/8
12/8
12/8
12/8
12/8
8/4
8/4
8/4
8/4
8/4
ft/12
ft/12
ft/12
ft/12
ft/12
12/8
12/8
12/8
8/4
8/4
8/4
8/4
8/4
8/4

D;itc
7/27
7/27
7/27
7/27
7/27
7/27
7/27
7/27
7/27
7/27
7/27

7/28
7/28
7/28
7/28
7/28
7/28
7/28
7/28
7/28
7/28
7/28

7/29
7/29
7/29
7/29
7/29
7/29
7/29
7/29
7/29
7/29
7/29
7/29
7/29
7/29
7/29
7/30
7/30
7/30
7/30
7/30
7/30
7/30
7/30
7/30

Time
8:50
10:15
11:45
1:10
2:45
3:55
5:30
6:55
8:25
9:45
11:10

12:35
2:10
3:40
5:15
6:45
4:00
5:30
7:10
8:35
10:05
ll- 30

1:00
2:25
3:55
5:15
6:45 .
8:10
9:30
11:10
12:50
2:10
4:30
6:00
7:30
8:50
10:20
3:00
5:45
7:25
5:00
7:25
9:15
10:40
12:20
1:40
Tap
No.
207
208
207
210

211
212
213
214
215
216
217
218
219
220

221
222
223
224
225
226
227
228
229
230
231
232
233

234
235
236
237
238
239
240
241
242
243
244
245

246
247
248
249
250

Shi Ct
8/4
ft/12
4/12
ft/12

8/4
8/4
8/4
8/4
8/4
ft/12
ft/12
4/12
4/12
ft/12

12/8
12/8
12/8
12/8
8/4
8/4
8/4
8/4
4/12
ft/12
ft/12
ft/12
ft/12

12/8
12/8
12/8
12/8
12/8
8/4
8/4
ft/12
ft/12
ft/12
ft/12
4/12

12/8
12/8.
12/8
•12/8
12/8

Date
7/30
7/30
7/30
7/30

7/31
7/31
7/31
7/31
7/31
7/31
7/31
7/31
7/31
7/31

8/1
8/1
8/1
8/1
8/1
8/1
8/1
8/1
8/1
8/1
8/1
8/1
8/1

8/2
8/2
8/2
8/2
8/2
8/2
8/2
8/2
8/2
8/2
8/2
8/2

8/3
8/3
8/3
8/3
8/3

Time
3:15
4:50
6:20
7:45

9:20
10:45
1:00
2:20
3:50
5:20
7:00
8:25
10:00
11:25

1:25
2:20
5:00
. 7:10
10:50
11:35
1:05
2:35
4:10
5:45
7:05
9:05
10:35

1:10
3:10
4:40
6:10
7:40
9:10
11:00
5:35
7:05
8:40
10:05
11:40

1:10
2:40
4:10
5:45
7:10
Tap
No.
251
252
253
254
255
256
257
258
259

260
261
262
263
264
265
266
267
268
269
270
271
272
273
274

275
276
277
278
279
280
281
282
283
284
285
286
287
'288
289
290

291
292
293
294
295

Shift
8/4
8/4
8/4
8/4
8/4
ft/12
ft/12
ft/12
ft/12

12/8
12/8
12/8
12/8
12/8
8/4
8/4
8/4
8/4
8/4
ft/12
ft/12
ft/12
ft/12
ft/12

12/8
12/8
12/8
12/8
12/8
8/4
8/4
8/4
8/4
8/4
• 8/4
ft/12
ft/12
ft/12
ft/12
ft/12

12/8
12/8
12/8
12/8
12/8

n.ito
8/3
8/3
8/3
8/3
8/3
8/3
8/3
8/3
8/3

8/4
8/4
8/4
8/4
8/4
8/4
8/4
8/4
8/4
8/4
8/4
8/4
8/4
8/4
8/4

8/5
8/5
8/5
8/5
8/5
8/5
8/5
8/5
8/5
8/5
8/5
8/5
8/5
8/5
8/5
8/5

8/6
8/6
8/6
8/6
8/6

Time
8:45
10:15
11:45
1:20
2:55
4:30
6:00
7:25
11:00

12:35
2:15
3:25
5:15
6:40
8:15
9:35
11:30
1:00
2:45
4:45
6:35
8:05
9:50
11:20

1:00
2:25
4:05
5:4.0
7:15
8:40
10:00
11:34
1:10
2:30
3:55
5:15
7:10
8:55
10:05
11:30

1:30
3:10
4:40
6:15
7:40
12-8 Shift starts at 12:01 a.m. on the Date Indicated
                                                                                 C-l

-------
9PM

-------
 IFtf
KOGK
                                                                     C-3 '

-------

-------
8PM
7 PM

-------
IPM

-------
C-7.

-------
I PM
11 p
                                                                                     C-8

-------
C-9(

-------
C-10

-------
DP:*
6PM
                                                                        C-ll

-------
KCGS
IIAF

                                                                            c-12

-------
4PM
3PM
2PM
                                                    C-

-------
NGOii

-------
1PM
NGttt

-------
5PM
.4PH
 3PW
 2PM

-------
APPENDIX D
FIELD DATA

-------
      t 10, p. 4 of 8
                                       PARTICULAR FIELD'DATA
Plant
  U/C - HM  - Marietta
Run No.    Preliminary Traverse
Location   MIE
Date
7/27/71
                                        VERY  IMPORTANT - FILLJ^.ALL^ BLANKS
                                        Read  and record at the start of each
                                        test  point or, if single point
                                        sampling, read and.record every 5
                                        minutes.
Sample Box Mo.
Meter Box No.
Probe Length
Ambient Temp °F_
Bar. Press. "Hg
                                                                           Assumed Moisture %
Operator    CCG & LWB
                                 Probe Heater Setting
Heater Box Setting, °F_
Probe Tip Oia., In.	

Point
1 ]
2
3
i 4
5
6
7
8
9
10
11
12
! 13
i 14
i 15
16
Avg.
Static

t
i
i
t

Clock
Tir«
Iveyy 6 in







"















Dry Gas
Kster, CF
.























Pi tot
in. HgO
AP
0.68
0.72
0.73
0.72
0.73
0.73
0.73
0.73
0.73
0.76
0.76
0.78
0.80
0.80
0.78
0.74
0.75
+1.04






Orifice
in H-
Desired
























AH
0
Actual 4
























Dry Gas
Op
Inlet
























Temp.
Outlet
























Pump
Vacuum
In. Hg
Gouge
























Box
Tc^p.
op
























Impinger
Tcxp
°F





.








t









Stack
Press
in. rig

.



.


















Stack
Temp
or
140
140
140
140
140
140
140
140
140 .
140
140
140
14Q
UO
140
140
i








-------
    Jrt 10, p. 4 of 8
     PARTICUL,,-£ FIELD DATA
Plant   u/c - KM
                                         VERY  IMPORTANT -  £ILLJN_.ALL_ BLANKS

                                         Read  and  record at the  start of each
                                         test .point or, if single point
                                         sampling, read and record every 5
                                         minutes.
                                          Ambient Temp °F   74
Run No.   Moisture
Location  Marietta #1 Exhaust

Date   7/27/71	

Operator   CCG & LWB	
       BOX NO. Reg. Imp. Meter & Pump

Meter Box No. •	

Probe Length   6*- £ in.	

Probe Heater Sotting 	
Bar. Press. "Hg   29.5
Assumed Moisture £__

Heater Box Setting,

Probe Tip Dia., In._
Point
3' in
it
"





Clock
TiJBs
1149

1201


Dry Gas
Meter; CF
012.04 ,

022.60
10.56

Condensatje: 30 ml


i




1
i





i

i





























Pi tot
in. H20.
Ap





















Orifice AH
in HoO
Desired "












Actual


Dry Gas Temp.
op
Inlet


i






•


1








1
I
1

1
i
|

























Outlet
75
75
75
75




















Pump
Vacuum
In. Hg
Gouge
6.0
6.0
6.0
6.0














Box
Temp.
Op

















Impinger
Texp
°F
70
70
70
70


Stsck
Prsss
ir. . rig

,

Stack
T£".P
°F
140
140
140
1 140


1




1




. i
f




h

i




1

I
I
1
























|
!

k





-. i
i

-------
        M1E - Moisture Calculation   '    7/27/71
1,  Isokinetic Sampling  (Dry Gas)  (cfm)

                          2
    RJJJ «*  .33 x Tm x Vg x d  x    PS  t       •   Rm (corrected) = Rm x Me

               TS               Pb  "  Pm
                                *


Estimated Value:



Calculated Value:
2.  Water Vapor Volume  (cu.  ft.)


    Vv « .00267 x Vw *  TM       .00267 x 30 x 535 _ l 83
                  pb -  pm             23.5
3.  Condensate Correction  for Meter  Rate
                Vm + Vv
    1'bisture in Metered Gas  (cu.  ft.)


    ^ **    V.P. X Vq           .739 x 10.56  _  33
            ?b - P                  23.5
5.  Percent Moisture (7.) Stack Gas


    % Moisture «=   vv ^ '^m  x 100        1>83 + .33   = 2.16_  * 17 4%
                   Vv + Vm              ' 1.83 + 10.56  12.39
    Saturated at

-------
   Hrt 10, p. 4 of 8
                                               PARTICUL  £ FIELD DATA
PI £nt    HC/KM - Marietta
Run No.

Location
M1E-1
Stack Exhaust
                                         VERY  IMPORTANT - FILMM.ALL^ BLANKS

                                         Read  and record at the start of each
                                         test  point or, if single point
                                         sampling, read and record every 5
                                         minutes.
Sample Box No.

Meter Box No.
Ambient Temp °F     72

Bar. Press. "Hg     29.5
Assumed Moisture %    17.4
Date   7/27/71
                              Probe Length
                  10 .ft.-
Heater Box Setting, °F    250
Operator    CCG
                              Probe Heater Setting   50_
                                          Probe  Tip  Dia.,  In.

LJ
t
i
i
1
Point
E - 3
E - 4
E - 5
Clock
TiTO
1840
1845
1859
E - 6 off:i909
Dry Gas
Kster, CF
321.33
324.49 r
328.22
330.99
E - 7 od 1915-20?) 334.32
E - 8 ;:
E - 9
1925 .... ! 337.90
1930
E - 10 | 1935
(E - llodf 1939
(E - llod 2030-31
E - 12
E - 13
E - 14
E - 15
E - 16
E - 17
E - 18







2037
2042
2047
2052
341.62
345.20

348.00
351.84



2057 j
2002
2107
2112
Avg.







379.94
58.61
Pi tot
in. HgO
AP
.55
.55
.83
.65
.60
.67
.70
.62

.64
.74
.68
.70
.85
Orifice AH
in H^O
Desired "
1.60
1.60
2.30
1.85
1.70
1.90
2.00
Actual
1.60
1.60
Dry Gas Temp.
op
Inlet
76
76
. 2.30 ! 76
1.85
1.70
1.90
2.00
1.80 | 1.80
!
1.90 | 1.90
2.10 | 2.10
1.90 I 1.90
2.00 | 2.00
2.45
.78 j 2.20
.76
.88
.88
.71
!
ANY INTERRUPTION OTHER
2.45
2.20
2.18 | 2.18
2.50 ! 2.50
2.50 | 2.50
2.03 I 2.03
1
THAN POWER FAILURE DUE
TROUBLE AT I^LET. |


!
. !



76
90
98
102
106

108
80
80
98
102
Outlet
76
76
76
Pump
Vacuum
In. Hg
Gouge
-
-
-
76 | -
80
84
84
86

88
80
80
70
80
104 | 80
108
108
108
84
84
84
88 I 80

TO INLET




FILTER *



4.0
4.0
4.0
4.0

4.0
5.0
5.0
5.0
7.0
7.0
7.0
9.0
9.0
Box
Temp.
op
250
250
250
250
250
250
250 j
250

250
250
250 j
250
250
250
250
250
250
5.7 1 250
1
:LOG OR P



OLLEY



Ircpinger
Ts^p
70
70
70
70
70
Stack
Press
in. Hg
1.60
1.60 .
1.60
1.60 •
1.60
Stack
Temp
°F
140
140
140
140
140
70. 1.60 j 140
70 1.60
70 1.60

70 1.60
70 1.60
70 1.60
70
70
70
70
70
70
70
1.60
1.60
1.60
1.60
1.60
1.60
1.60
i








140
140
>
140
140
140
140
140
140
140
T40 .
140
140



!'


-------
    >t 10,  p.  4 of 8
                                     PARTICUUii*  FIELD DATA
Plant
UC/RM - Marietta
Run No.   M1E-2
Location  Exhaust"
                                        VERY  IMPORTANT - FILL IN.ALL BLANKS

                                        Read  and record at the start of each
                                        test  point or, if single point
                                        sampling, read and.record every 5
                                        minutes.
                               Sample Box No.

                               Meter Box No.
                                          Condensate  +210 ml
                                          Ambient Temp  °F    68
                                          Bar.  Press.  "Hg    29.5
                                         Assumed  Moisture  %
Date
7/29/71
Probe Length
Heater Box Setting, °F   250
        'Gonzalez & Baxley
                               Probs Heater Setting    50
                                         Probe Tip  01 a.,  In.   .25
Point
3
*4
5
*6
7
8
*g
10
**11
1416) 12
13
Clock
Ttoe
1035
1038
1050
1110
1115
1120
1125
1155
1205
1421
1426
14 1 1431
i 15
i 16
1 17
18
1436
1441
Dry Gas
Meter, CF
383.72 *
386.02
389.91
393.40
397.50
400.52
403.62
407.50
411.50
£2"$: ^2*
428.05
431.50
435.17
Pitot
in. K£0
0.73
0.73
0.73
0.76
0.76
0.51
0.51
0.71
0.63
0.73
0.73
0.76
0.82
439.20 i 0.73
1446 j 443.20 | 0.76
1451
i



i
i
i

(gO Min.)






447.32

63.60

0.70

0.66

* Power Off.
** Sampling |interrupte




-

Orifice AH
in HoO
Desired "
2.10
2.10
2.10
2.20
2.20
1.45
1.45
2.00
. 1.80
Actual
2.10
2.10
2.10
2.20
2.20
1.45
1.45
2.00
1.80
2.10 1 2.10
2.10
2.15
2.10
2.15
2.40 | 2.40
2.10
2.20
2.00

2.10
2.20
Dry Gas Temp.
Op
Inlet
72
72
72
84
84
84
84
86
86
86
90
98
102
108
108
2.00 108

2.03 | 2.03
1 .
1

89


1 - Complete fewer Failure.

-11 --i—






Outlet
90
90
90
72
72
72
72
74
74
70
76
80
80
80
80
80

78




,

Pump
Vacuum
In. Hg
Gouge
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
6.0
6.0
8.0
9..0
8.0
8.0
9.0

5.6






BOX
op '
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250

Irr.pinger
•F
60
60
60
60
60
60
60
60
60 J
60
60
60
60
60
; 60
60

250 | 60
1








•

Stack
Press
in. rig

.
Stack
'°F
140
140
| 140

140
i 140
! 140







"










140
140
140 .
140
L140
140
140
140
140
140
»
140




\


-------
   ">rt 10, p. 4 of 8
                                    PARTICIL./E FIELD DATA
Plant
UC/RM - Marietta
Run No.    M1E-3
Location   Exhaust

Dste       7/30/71
Operator  Gonzalez and Baxley
                                         VERY  IMPORTANT -  FILLJN.ALL^ BLANKS

                                         Read  and  record at  the  start of each
                                         test  point  or, if single point
                                         sampting, read and  record  every 5
                                         minutes.
                               Sample Box No.

                               Meter Box No.

                               Probe Length
                                                                                   Condensate 160 ml

                                                                                   Ambient Temp CF   68
                                                                                   Bar. Press. "Hg   .29.5
                                                                                   Assumed Moisture % 17.4
                                                                                   Heater Box Setting, °F   250
                               Probe Heater Setting   50
                                                                                   Probo Tip Dia., In.  .25





















-------
   /art 10, p. 4 of 8
                                      PARTICULafE FIELD DATA
Plant  DC/RM - Marietta
Run No. _

Location

Dcte
  M.E-4
   Exhaust
                                         VERY  IMPORTANT -  FILLJN.ALL^ BLANKS

                                         Read  and  record at  the  start  of  each
                                         test  point  or, if single point
                                         sampling, read and.record  every  5
                                         minutes.
Sample Box No.

Meter Box No.
                                                                          Condensate +240 ml

                                                                          Ambient Temp °F    80
Bar. Press. "Hg    29.5
Assumed Moisture %
7-31-71
           Baxley and Gonzalez
Probe Length      11'
Heater Box Setting, °F  ?sn
                                Prcba Heater Setting    70
                                          Probe Tip Dia., In.   0.25





















g
s
• 1
1
i

Point
Start
3
4
5
6
7
8
9
to
11
12
13
14
15
16
17
18



Start



Clock
Tira
1029
1034
1039
1044
1049
1054
1059
1104
1109
1114
1119
1124
1129
1134
1139
1144
1149



1237
1242
"iW
95 min.
Dry Gas
Keter, CF
549.14'
553.47
557.20
561.20
565.17
569.04
572.88
576.80
579.60
584.14
586.28
592.36
596.27
60Q.41
604.50
607.40
612.37

(PI
Re
612.37
616.20
fe%
-------
      Jrt 10, p. 4 of 8
                                                 PARTICULAR FIELD DATA
VERY IMPORTANT -
                                                                        BLANKS
:   Plant   UC/RM - Marietta
Run No.
Location
Date
M1E-5 •
'Exhaust
7-31-71
                                           Read and record at the  start of each
                                           test point or,  if single point
                                           sampling, read  and. record every 5
                                           minutes.
                                            Sample Box No.

                                            Meter Box No.

                                            Probe Length _
                                          Condensate +254 ml

                                          Ambient Temp  °F   70
                                          Bar. Press.  "Hg   29.5
                                          Assumed Moisture  %  17-6
                   11'4'
Mccter Box Setting, °F  25°
  Op2rator  Baxley and Gonzalez
 Probe Heater Setting   70
Probe Tip Oia., In.    .25

Point
Start
3
4
5
6
7
8
9
10
11
12
Pwr.Off 13
[Vr.On 13
14
15
16
17
18

1 AVG.



~~
Clock
Tin:-
1530
1545
1550
1555
1600
1605
1610
1615
1620
1625
1630
1634
1647-48
1653
1658
1703
1708
1713






Dry Gas
Meter, CF
623.61 '
635.10
638.59
642.49
646.47
650.34
654.14
657.97
661.62
665.32
669.50

673.80
677.99
682.17
686. 17
690.00
693.92

70.31




Pi tot
in. H20 •
AP

0.65
0.65
0.75
0.70
0.70
0.64
0.65
0.65
0.62
0.80

0.94
0.75
0.73
0.71
0.73
0.65

0.66



I
Orifice
in H^,
Desired

1.90
1.90 J
2.20'
2.00
2.00
1.85
1.90
1.90
1.80
2.30

2.60
2.20
2.10
?. in
?.in
1.90

2.05




AH
0
Actual
'
1.90
1.90
2.20
2.00
2.00
1.85
1.90
1.90
1.80
2.30

2.60
2.20
2.10
2.10
2.10
1.90

2.05




Dry Gas
Op
Inlet

84
104
110
110
116
116
120
120
120
120

122
l:»6
126
124
120
118

116




Temp.
Outlet

84
88
90
90
96
96
98
98
98
98

100
100
.100...
100
98
96

96




Pump
Vacuum
In. Hg
Gouge

3.0
3.0
4.0
4.0
4.0
4.5
5.0
5.0
5.0
6.0

7.0
6.0
6.0
6.0
6.0
6.0

5.0



.
Box
Temp.
°F

250
250
250
250
?sn
2.5Q
250
250
250
250

250
250
250
250
250
250

250




Ircpinger
Temp
°r

65
65
65
65
fiS •
65
65
65
65
65

65
65
•6'5
65
65
65

65


•

C* T<-
o i_uCi\
Press
in. Hq

0.11 .






















Stack
Ten-?
op

140
140
140
140
140
140
140
140 .
140
LI 40

140
140 !
140
140
140 •


140


f


-------
       |irt 10, p. 4 of 8
                                              PARTICUL..* FIELD DATA
Plant
                 - Marietta
;   Run No.   MlE-7
  Location  Exhaust'

  Dste       8-1-71
                                           VERY IMPORTANT - FILLJN .ALL, BLANKS

                                           Read and record at the start of each
                                           test .point or, if single point
                                           sampling, read and.record every 5
                                           minutes.
                                         Sample Box No.

                                         Meter Box No.
                       Ambient Temp  °F	86
                       Bar. Press.  "Hg    29.70
                       Assumed Moisture % 17.4.
  Op3ratOr   Schroeder and Gonzalez
                                         Probe Length
11'
Heater Box Setting, °F   250
                                         Prcbs Heater Sotting   70
                       Probe Tip Oia., In.   .250




















V
*i

• !
1


Point

3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18

AVG.





Clock
Tiisa
1525
1540
1545
1550
1555
1600
1605
1610
1615
1620
1625
1630
1635
1640
1645
1650
1655







Dry Gas
Meter, CF
455.83 -
-
-
-

_
-
-
-
_
-
_
-
-
-

524.82

68.99





Pi tot
in. H£0
Ap

0.75
0.75
0.75
0.75
0.75
0.75
0.75
0.68
0.68
0.70
0.70
0.73
0.75
0.70
0.70
0.80

0.73





Ori f i ce
in Ho
Desired "

2.10
2.10
2.10
2.10
2.10
2.10
2,10
1.90
1.90
1.95
1.95
2.05
2.10
2.00
2.00
2.30

2.19



, ,,-„,.. ._., -r
	 ^
AH '
0
Actual

2.10
2.10
2.10
2.10
2.10
2.10
2.10
1.90
1.94
1.95
1.95
2.05
2,10
2.00
2.00
2.30

2.19





Dry Gas
or
inlet
98
112
116
115
118
123
126
127
132
134
134
136
137
135
136
133
135

119





Temp.
Outlet
86
89
90
91
93
96
97
100
103
103
105
107
108
109
109
103 ..
109

101





Pun-.p
Vacuum
In. Hg
Gouge

4.5
4.5
5.0
5.0
5.0
5.0
5.5
6.0
6.0
6.0
6.2
6.5
6.7
7.0
7.0
7.5

5.2





Box
Tc.Tip.
°F

250
250
-
-
_
_
-
-
_
-
-

-
-
_
_







Iir.pinger
Tcn:p
°F

70
75
75
75
75 •
75
75 •
75
80
80
75
75
75
•75
75
75

75



•

$*• -~i,
cuCX
Press
in. He;

0.10 .
-
-
-
_
_
-
-
-
_

-
-
-
_
_







Stack
Te-p
°F

135
135
140
140
135
135
135
135 .
135
135
135
135
135
135
]35
1^ .

• 135






-------
    Jrt 10, p. 4 of 8
                                              PARTICUtait FIELD DATA
Plant
               - Marietta
Run No.   M1E-8
Location  Exhaust


Dcte      8-2-71
                                         VERY  IMPORTANT -  FILLJN .ALL. BLANKS

                                         Read  and  record at the  start of  each
                                         test  point or, if single  point
                                         sampling, read and.record every  5
                                         minutes.
                                         Sample Box No. 	2_

                                         Meter Box .No.      4
Condensate +265 ml

Ambient Temp °F     .78

Bar. Press. "Hg     29.70
Assumed Moisture *  14.7
Operator  Schroeder and Avery
                                         Probe Length 	IV
Heater Box Setting, °F
250
                                         Probe Heater Setting
Probe Tip Dia., In.    0.25
















1



o
%
1
• i

1

Point

3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18

AVG.





Clock
Tira
0945
1000
1005
1010
1015
1020
1025
1030
1035
1040
1045
1050
1055
1100
1105
1110
1115







Dry Gas
Kster, CF
525.91
536.48
539.62
542.84
547.27
550.32
554.61
558.73
563.34
566.69
570.47
574.30
578.15 j
583.00
586.78
589.88
593.87

67.96





Pi tot
in. H20
AP

0.6
0.7
0.7
0.75
0.75
0.80
0.80
0.7S
0.75
0.75
0.67
0.70
0.75
0.68
0.70
0.63

0.72





Orifice
in H^
Desired "

1.7
7.0
2.0
2.1
2.1
2.2
2.2
2.1
2.1
2.1
1.9
2.0
2.1
2.0
2.0
1.8

2.02





AH
0
Actual

1.7
7.0
2.0
2.1
2.1
2.2
2.2
9.1
2.1
2.1
1.9
2.0
.2,1
2.0
2.0
1.8

2.02





Dry Gas
°F
Inlet
72
94
102
110
115
117
120
120
120
125
129
132
134
135
136
138
139

123





Temp.
Outlet
70
74
76
80
82
88
88
90
90
92
94
96
99
100
102
105
106

91





Pun;?
Vacuum
In. Hg
Gauge

5
5
5
6
7
8
7
7
7
8
7.5
7.5
7.5
8
8.5
8

6.6





Box
Te-rp.
°F

250
250
250
250
250
250
250
2sn
250
300
300
300
300
300
300
300







Ircpinger
Temp
°F

75
75
80
80
86 .
86
80
80
80
80
80
74
90
•?5
95
95

83





Stcck
Press
in. Kg

0.10 .
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10

0.10





Stsck
TG-P
op

120
125
125
125
135
135
125
I'M .
130
130
125
125
125 !
125
125
1*25 .

127



1
1

-------
     .  >t 10, p. 4 of 8
                                                 PARTICIPATE FIELD DATA
!   P1 ant   UC/RM - Marietta


;   Run No.   MlE-9
  Location  Scrubber Exhaust

  Date'    8-2-71
  Op3ratOr   Schroedsr anH
                                           VERY IMPORTANT - FILLJK.ALL^ BLANKS

                                           Read and record at the start of each
                                           test point or, if single point
                                           sampling, read and.record every 5
                                           minutes.
Sraple Box No.

Meter Box No.

Probe Length

Prcba Heater
                                          Condensate +220 ml

                                          Ambient Temp  °F     78
>. 2
I*.
11'
Setting
70
Bar. Press. "Hg     29.70
Assumed Moisture % 14.7
Heater Box Setting, °F  300
Probe Tip Dia., In.__, 0.25

Point

3
4
5
6
7
* 8
9
10
11
12
1 13
i 14
15
16
17
18

AVG.

* S


r
L 	 .
Clock
Tiisa
1805
1820
1825
1830
1835
1840
1910
1915
1920
1925
1930
1935
1940
1945
1950
1953
2000



tODoed to



Dry Gas
Meter, CF
593.97 "















664.92

70.95

clean pftot li



Pi tot
in. HgO
AP

0.86
0.84
0.82
0.80
0.98
0.84
0.65
0.65
0.75
0.78
0.75
0.60
0.70
0.63 •
0.75 '
0.80

0.76

nes.



Orifice
in H,
Desired

2.40
2.35
2.30
2.25
2.80
2.35
1.85
1.85
2.10
2.15
2.10
1.70
2.00
.1.80
2.10
2.25

-2.ni





AH
0
Actual

2.40
2.35
2.30
2.25
2.80
2.35
1.85
1.85
2.10
2.15
2.10
1.70
2.. 00
1.80
2.10
2.25

2.01


,


Dry Gas
°F
|_lnlet
77
110
115
120
122
124
103
108
109
111
115
117
118
115
120
124
122

11 5





Temp.
Outlet
76
80
8?
85
90
91
89
89
90
90
90
91
91
91
92
93
95

%





Pump
Vacuum
In. Hg
Gouge

4.5
4.8
5.0
6.0
6.5
6.5
5.5
6.0
6.5
7.0
7.5
6.5
7.0
7.5
8.0
8.0

6.4





Box
Temp.
°F

300
_
—

-
-
-
-
-
_
-
-
_
-
_
_







Ircpinger
Tsxp
°F

80
80
80
80
80-
90
90
85
85
90
90
90
95
95
100
100

RR



•

Stcck
Press
in. no,

0.10.
_
_
- -
_
-
_
-
-
-
_
-
_
_
-
-







Stsck
Terr.?
°F

140
130
130
125
150
135
130
125 .
135
135
135
135
135 '
133
135
133 .

1 *U






-------
      t 10, p. 4 of 8
                                               PARTICULAit FIELD DATA
Plant  UC/BM - Marietta
Run No.   MIE  -  10
Location  Exhaust
                                         VERY IMPORTANT - FILLJN.ALL^ BLANKS

                                         Read and record at the start of each
                                         test'point or, if single point
                                         sampling, read and.record every 5
                                         minutes.
Sample Box No. _

Meter Box No.
                                          C = 0.8

                                         : Filter Number - 2FN-30A

                                          Condensate +262 ml

                                          Ambient Temp °F   75.
                       Bar, Press. "Hg   29.6
                       Assumed Moisture %  17.4
Date •  8-3-71
Probe Length
li1
Hester Box Setting, °F  200
Operator   Blessing
Probe Heater Setting   80
                       Probe Tip Oia., In.    1/4

Point
0
3
4
5
6
7
8
9
10
11
12
i 13
14
i 15
16
17
18

AVG.





Clock
lira
1010
1025
1030
1035
1040
1045
1050
1055
1100
1105
1110
1115
1120
1125
1130
1135
1140







Dry Gas
Meter, CF
665.87 *
676.51
-
-
687.82
691.57
695.64
700.07
-
708.11
711.70
715.32
• 719.18
723.12
727.20
731.00
734.59

68.72





Pi tot
in. HgO
AP
0.68
0.65
0.70
0.65
0.70
0.65
1.00
0.90
0.75
0.75
0.60
0.6Q
0.70
0.70
0.75
0.65
0.60

0.71





Ori f i ce
in Hx,
Desired *"
2.0
1.9
2.1 J
1.9
2.1
1.9
2.9
2.6
2.2
2.2
1.8
1.8
2.1
2.1
2.2
1.9
1.8

2.1



- .. ..........

AH
0
Actual
2.0
1.9
2.1
1.9_
2.1
1.9
2.9
2.6
2.2
2.2
1.8
1.8
2.1
2.1
2.2
1.9
1,8

2.1





Dry Gas
°F
inlet
70
93
96
96
98
98:
102
101
101
105
106
104
105
104
105
105
106

100





Temp.
Outlet
70
72
72
Jb
76
76
78
. 80
80
82
94
Qfi
96
86
85
85
85

8?





Pinnp
Vacuum
In. Hg
Gouge
3.0
3.5
4.0
4.0
4.5
5.0
7.0
6.5
6.0
6.5
6.0
fi.n
7.0
7.5
8.0
7.5
7.n

S.fl



.

Box
Temp.
op
300
300
300
300
300
300
300
300
300
300
300
inn
300
300
300
300
inn

son





Ircpinger
Tcn:p
o<-
75
75
75
75
75
75
75
75
75
7S
80
Qn
90
75
•15
75
7S

R1



•

Stcck
Press
in. rig
2.0
2.0 .
1.8
1.8 '
1.8
1.9
1.7
1.7
1.0
1 .7
1.1
1 .1
1.?
1.2
1.1
1.0
1 .1

1 .S



t

Stack
Te"P
°F
^120
130
130
130
130
130
135
135
1'30 .
nn
135
1 IS
130
135
130
130
I'm -

• nn


1
i
" 	 i

-------
Part 10, p. 4 of 8
                                           PARTICULATE FIELD DATA
                                     VERY  IMPORTANT - FILL IN.ALL BLANKS
1
1:
A
o
c
Plant UC/RM - Marietta
Run No.
M1E-11
Location Exhaust"
Date
8-3-71
Operator Blessing and Avery
Point
. 0
3
4
Clock
Tijsa
1400
1415
1420
5 1425
6 1430
7
8
9
1435
.1440
1445
10 ! 1450
Dry Gas
Keter, CF
735.36
746.70
749.87
753.61
Pitot
in. H£0
AP
0.95
0.65
0.60
0.65
756.98 0.60
761.10
-
768.82
772.85
11 1455 776.72
12
1500
13 1505
14 1510
15
0.75
0.65
0.70
0.70
0.65
780.30 0.60
784.16 0.65
787.72
0.65
1515 - . 0.70
16 1520
17
1525
Rea'd 'and record .at the start of each
test point or, if single point
sampling, read and record every 5
minutes.
Sample Box No. 4
Meter Box No. 4
Probe Length 11'
Probe Heater Setting
Orifice AH
in HoO
Desired
2.8
1.9
1.7
1.85
1.75
2.2
1.9
2.05
Actual
2.8
1.9
1.7
1.85
1.75
2.2
1.9
2.05
2.05 2.05
1.9 ! 1.9
1.75
1.9
1.75
1.9
1.9 1.9
2.05
0.70 2.05
799.22 0.70
18 i 1530 803.15
-.
Avg.









0.70

2.05
2.05
2.05
2.05
2.05 2.05
100
Dry Gas Temp.
Op
Inlet
76
100
104
107
108
110
111
112
114
Outlet
76
78
82
84
86
87
88
90
91
112 i 91
112
114
115
116
116
92
93
93
94
94
118 j 95
118
|
67.79 0.67 2.0 2.0
.


•






j

95

109 ' 89


1
1

C = .8
: Filter Num
Condensate
Ambient Te
Bar. Press
Assumed Mo
Mecter Box
' Probe Tip
Vacuum
In. Hg
Gauge
9.0
6.0
6.0
6.5
6.5
6.0
7.5
8.5
8.0
8.5
Box
Temp .
op
300
300
300
300
ber - 2FN-31A
+248 ml .
mp °F 75 '
. "Hg 29.6
isture % 17.4
Setting, °F 30°
Dia., In.
Impinger
Tcxp
°F
70
75
75
70
300 70
300
300
300
300
300
7.5 300
7.5
8.5.
10.0
10.0
10.5
10.5

300
300
300
300
300
300

65 .
65
1/4
Stack
Press
in. no,
1.8
1.6 .
1.7
1.6
1.8
Stack
Tessp
op
130
130
135
130
135
1.6 ! 130
1.7 130
70 1.7 135
70
2.0
t30 .
70 1.9 130
70
1.8
70 1.8
70
75
75
1.8
1.8
1.9
75 1.7
75
1.6

1.8



i
i








•





[ 135
135
135
135
135
135
1'35 .

133



- i
!

-------
     Irt 10, p. 4 of 8
                                  PARTICULali FIELD DATA
Plant  UC/RM - Marietta
Run No.
M1E-12
Location   Exhaust


Dcte       8/4/71
                                        VERY  IMPORTANT  -  FILLJN_.ALL. BLANKS

                                        Read  and  record at  the  start  of  each
                                        test  point  or,  if single point
                                        sampling, read  and.record every  5
                                        minutes.
Sample Box No.

Meter Box No.
 Condensate  '+233 ml

Ambient Temp CF      75

Ear. Press. "Kg
29.5
                                                                       Assumed Moisture %  17.4
                             Probe Length 	IT
                                          Jlecter Dox Setting, °F  300
           Blessing
                             Probe Heater Setting    90
                                          Probe Tip Oia., In.     1/4

Point
0
3
4
5
6
7
8
9
10
11
12
13
i 14
i 15
i 16
17
18



i

i

Clock
Tis:e
1115
1130
1135
1140
1145
1150
.1155
1200
1205
1210
1215
1220
1225
1230
1235
1240
1245


.




Dry Gas
Kster, CF
803.25 "
-
816.82
-
824.07
827.02
830.52
-
-
-
843.70
-
854.30
854.72 .
858.43
862.00
865.61

62.36





Pitot
in. H£0
AP
0.60
0.60
0.60
0.60
0.60
0.60
0.55
0.50
0.50
0.50
0.60
0.65
0.65
0.60
0.55
0.60
0.60

0.58
•




Orifice
in H/,
Desired "
1.8
1.8
1.8 	 |
1.8
1.8
1.8
1.6
1.5
1.5
1.5
1.5
1.9
1.9
1.8
1.6
1.8
1.8

1.7




	
AH
0
Actual
1.8
1.8
1.8
1.8
1.8
1.8
1.6
1.5
1.5
1.5
1.5
1.9
1.9
1.8
1,6_,
1.8
1.8

1.7





Dry Gas
°F
Inlet
66
86
88
90
88
94
94
98
104
106
106
108
116
116
118
118
118

101 '





Temp.
Outlet
66
68
68
70
71
74
74
76
78
78
78
78
86
88
SB
90
90

78





Pu^p
Vacuum
In. Kg
Gouge
4.5
5.0
•5.0
5.5
5.5
L 6.5
6.0
6.0
7.0
7.0
7.5
9.5
9.5
10.0
.. 9.0
10.0
10.0

72





Box
Temp.
°F
300
300
300
300
300
300
300
300
300
300
300
300
300
300
300 ^J
300
300

300





Ircpinger
TE^P
°F
70
70
70
70
70
80 .
80
75
70
70
75
75
85
90
*A
95
95

78





Stcck
Press
in. Hr;
1.8
1.7 .
1.7
1.5
1.5
1.4
1.3
1.4
1.8
1.6
1.7








i




Stack
Temp
«p
135
130
130
130
130
130
135
130
T35 .
130
130
130
130
130
l^n
130
T35 .

132



i
i

-------
         Part 10, p. 2 of 8
                                     VELOCITY TRAVERSE FIELD DATA
                Plant

                Test
UC/RM - Marietta
MID
                Location  Duct inlet
                Date
7/28/71
                Operator  Blessing & Schroeder	

          A  to  E • Left to r|.ght, facing exhaust stack.
Clock
Time
•












Point
A-l
A- 2
A-3
A-4
B-l
B-2
B-3
B-4
C-l
C-2
C-3
C-4
D-l
AP, In. H20
0.58
0.57
0.48
0.42
0.38
0.48
0.58
0.53
0.24
0.33
.0.33
0.32
•0.48
Stack
Temp., °F
603
522
598
608
698 '
705
648
562
726
751
829 '
805
772
Stack
Pres. , In. Hg




.
.

•





AP x (T+460T














'AP x (T+IGOTI
r
i
i
!
i
j
•
j
t
!


i
i
i
j

i
•
3epth
Feet

 0.5

 1.5

 2.5

 3.5
      Vsr*
         - Calculation columns, not Field  data
      Consents:

      NCAP-29  (12/67)
                                                                                   D-15

-------
    Part  10,  p.  2  of 8
                               VELOCITY TRAVERSE FIELD DATA
          Plant
          Test
          Location
          Date
Duct #1 Continued
7/28/71
          Operator
Clock
Time






-•
AVG.





Point
D-2
D-3
D-4
E-l
E-2
E-3
.E-4






AP, 1n. H20
0.48
0.56
0.55
0.72
0.70
0.72
0.63
0.50
-



•
Stack
Temp., °F
780
888
835
810
810
820
780
725





Stack
Pres. , In. Hg




.


• . •





AP x (T+460J*














•'AP x (T+460J*i
t
i
i
I
i
. • f
i
• 1
__ 1
i
i
"I

I


.
   - Calculation  columns,  not Field data

Corrjnents:                      •
NCAP-29 (12/67)         .          "  '
                                                                              D-16

-------
   .art 10, p. 4 of 8
                                             PARTICIPATE FIELD  DATA
                                       VERY IMPORTANT - FILLN .ALL BLANKS
PI ant	UC/RM - Marietta
Run No.  MlD-4-
                                       Read and record at the  start of each
                                       test point or,  if single point
                                       sampling, read  and. record every 5
                                       minutes.
       Box No.
                                         + 12  ml Condensate

                                         Ambient Temp °F   80
                                                                                 Bar. Press. "Hg
Location   Tni«»*  +•»
         7-31-71
Meter Box No.

Probo Length
                                                                                Assumed Moisture %  2.0
                                                          11'
                                                                                Heater Box Setting, °F 250
Oparator   Blessing
Prcbs Heater Setting    65
                                                                                Probo Tip Dia., In.   3/16
Point
0
Clock
Ttee
f 1030
A-41
A- 3

A-2|
A-l
-
0
B-4
1042
12
.1046

B-3i '
B-2
B-l
_ '
0
C-4


1055
1105

C-3t
C-2

c-1!
—
1117
Ol 1129
Dry Gas
Kster, CF
174.44
175.78
177.00
178.35
179.38
4.94
179.38
180.56
181.72
182.80
183.60.
.4.22:
183.60
184.47
184.40
186.22
186.80
.3.20
186.80
Pi tot
in. H20
AP
0.63
0.63
0.58
0.68
0.41
0.59
0.64
0.64
0.58
0.45
0.24
0.50
0^35
0.35
0.35
0.35
0.13'
0.31
0.73
H-41 ! 188.00 !• 0.62
D-3

D-2
	 -'-£-'1
-
'
189.20
190.32
— "IST.!*
	 1141 ' 	 4.32
0.55
0.48
0.15
Orifice AH
in HoO
Desired
0.55
0.55 .
0.50
0.59
0.36
0.51
0.45
0.45
0.45
0.33
0.18
0.37
0.23
0.23
0.23
0.23
0.10
0.20
0.51
0,43
0.39
0.49
0.16
0.53 1 0.40
Actual
0.55
0.55
Dry Gas Temp.
op
Inlet
84
85
0.51 , 87
0.59
0.36
0.51
0.45
0.45
0.45
0033
90
90
87
88
90
91
94
0.18 ! 95
0.37
0.23
0.23
0.23
...0.23...
0.10
0.20
0.51
0.43
0.39
0.49
0.16
0.40
92
90
91
.9.2
93
93
92
90 '
92
94
97
98
94
Outlet
82
83
83
83
84
83
84
84
85
86
86
85
86
88
..SB_...
89
89
88
90
90
90
90
91
90
Pump
Vacuum
In. Hg
Gouge
3.0
3.0
2.5
3.0
2.0
2.7
200
2.0
2.5
2.0
1.5
2.0
1.5
1.5
Box
Temp.
°F
250
250
250
250
250
250
250
250
250
250
250
250
250
250
.1.5 1 250
1.5
1.0
1.4
2.5
2.0
2.0
2.5
1.0
2.0 .
250
250
250
250
250
250
250
250
250
Impinger
Tcxp
°F
• -
-
-
-
—
90

—
-
Stcck
Press
in. He;
1.2
i
— .


Stack
leap
°F
500
495
480
480
475
1.2 486
-
—
-
1 -
- I -.
100

s •"
•;-
_
—
90
-

_
-
• -
90
1.2
1.1

_
_
—
1.1
1.2

_
-
-
505
555
830 .
680
L680
600
800
775 j
775
750
725 .
_J£5
695
650
325
280
280 j
1.2 I 446 |

-------

• •
Point
0
E-4
3
2
1
-






i
i














i

i


Clock
Tircs
1245
1


1257
12


60















1
1
i
1






Dry Gas
Meter, CF
191.40
192.56
193.74
195.20
196.38
4.98


21.66








.














•
Pitot
in. H20
AP
0.60
0.60
0.82
0.87
0.61
0.70


0.53























M1F>4
Ori f i ce
in H-j
Desired *
0.46
0.46 .
0.59
0-62
0.44
0.51


0.40




•
-

















cb^.Jnsq
AH
0
Actual
0.46
0.46
0.60
0.62
0.44
0.52


0.40
























Dry Gas
°F
Inlet
86
88
90
94
95
91


92
























Temp.
Outlet
87
87
87
88
88
87


87
























Pum?
Vacuum
In. Hg
Gouge
2.5
2.5
3.0
3.0
2.5
2.7


2.2
























BOX
Temp.
°F
250
250
250
250
250
250


250
























Inpinger
°r
_
-
-
_.
«•
80


90









•














Stcck
Press
in. Hr»
0.90

—
^ .
_
0.90


1.12
























Stsck
Tenip
op
625
680
710
710
268
699


'599.















1







Cor.ir.snts:

NCAP-37'(12/67)
o
Assumed moisture %-  2.0
Tm  = 80°

Ps/Pm = 99    29.49/29.50

Static = 0.007
C Factor -  1.35

-------
   Par/TO, p. 4 of 8
                                             PARTICULATE FIELD DATA
Plant
              . UC/EM - Marietta
  Run No.   MLD-5
:  Location  Inlet to Scrubber

  Dcte      7-31-71	

  Operator  Blessing	
                                       VERY IMPORTANT  - FILLJN.ALL. BLANKS

                                       Read and record at the start of each
                                       test point or,  if single point
                                       sampling,  read  and.record every 5
                                       minutes.
Sample Box No.

Meter Box No.

Probe Length
                                        +  1 ml Condensate
                                        Ambient Temp CF    90
>. 2
2
11'
Setting
65
                                                                                Bar. Press.  "Hg    29.5
                                                                                .      ,  „ . .  ,     _,   _  . /FROM C
                                                                                Assumed  Moisture %   6.41 HlB-
                                                                                Heater Box Setting,  °F
                                                                                Probe Tip Oia.,  In.   3/16

Point
0
A-4
A-3
A- 2
A-l
—
0
B-4
B-3
B-2
B-l
—
0
i C-4
' C-3
C-2
r-l
i
0
D-4
D-3
D-2
D-l
-
Clock
Tira
1500^
\
I
t
1512 3
12
1516 A
)
f
r
i us J
d.2}
1540 >

I
\
•52 J
12
1555^)
/
I
(
<607J
IT*
Dry Gas
Meter, CF
196.85
197.90
199.98
—
201.05
4.20
201.05
202.20
203.30
204.26
204.96
3.91
204.96
205.70
206.51
—
207 -flR
2.92
207.88
208.90
210.08
211.07
211.79
3.91
Pi tot
in. HgO
AP
h 0.50
0.52
0.53
0.65
0.36
0.52
0.65
0.63
0.56
0.41
0.21
0049
0.28
0.26
0.35 •
0.28
0.1=5
0.26
0.60
. 0.58
0.66
0.54
0.20
0.52
Orifice
in Hn
Desired "
0.38
0.40
0.38
0.48
0.27
0.38
0.46
0.44
0.40
0.28
0.14
0.34
0.16
0.16
0.22
0.18
n,i n
O.lfi
0.38
0.37
0.43
0.35
0.14
0.33
AH
0
Actual
0.38
0.40
0.38
0.48
0.27
0*38
0.46
0.44
0.40
0.28
0.14
0.36
0.16
0.16
0.22
0.18
n.i n
0T16
0.38
0.37
0.43
0.35
0.14
0.33
Dry Gas
Op
Inlet
90
90
91
94
94
92
94
96
98
98
98
97
95
96
96
98
QR
97
98
99
.101
102
102
iop
Temp.
Outlet
88
88
88
89
89
88
90
90
91
91
92
91
92
94
94
94
Q4
94
94
94
95'
96
	 96 	 ^
95
Pump
Vacuum
In. Hg
Gauge
2.0
2.0
2.5
3.0
2.5
2.4
3.0
3.0
4.0
4.0
3.0
3.4
2.0.
2.0
3.5
3.0
2 n
2.S
3.0
3B0
8.5
8.0
5.0
5.5 •,.
Box
Tornp.
L °F
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
2RO
2^0
250
2.50.
250
250
£™
250 ,
Impinger
Tcrrp
°F
_
—
-
-

80
—
—
-
_
_
100
_
—
. ;_
f
_

i nn
_
_
_
—
• —
100
Stcck
Press
in. Kg
1.1
1.1 .
1.1
1.1
1.1
1.1
1.1
1.1
1.1
1.1
1.1
1.1
1.0
1.0
1.0
1.0
i n
i"o
1.1
_
_
—
—
1.1
Stcck
Tcm?
°F
515
560
540
560
560
547
635
615
605 .
655
620
626
738
780
780
814
fi1 n .
744
725
740
694
635
700
699

-------
Point
0
E-4
E-3
Clock
1614


E-2
E-l
-


1626
12

60
!
i


i






Dry Gas
Kater, CF
211.79
213.00
214.13
215.39
216.57
4.78

19.72







• !




i





j

1
i












Pi tot
in. K20
AP
0.65
0.65
0.78
0,88
0.60
0.71

0.50







Orifice AH
in FUO
Desired
0.42
0.42
0.51
0.56
0.32
0.46

0-31



Actual
0,42
0.42
0.51
Dry Gas Temp.
°F
inlet 1 Outlet
100
100
103
0.52 i 105
0.40
0.46

0-31

1

1

•
106
107

98

96
96
96
Punip
Vacuum
In. Kg
Gouge
9.0
12.0
17.5
97 25.0
97
96

93

1



1
.



























•




















1
Box
Ter.p .
°F
250
250
250
250
20.0 |250
16.7

6,1







• |


1











'


















































250

250













Ircpir.ger
Tczp
°r
_
—
-
-

— .

_
C AA» <-'•
Press
in. no
1.1
_
Stsck
Tcr:.p
°F
737
745
710
-
—
1.1



1
|









































795
795
755

674
'












1











1







Comments:


NCAP-37'(12/67)
to
O

-------
        10, p. 4 of 8
                                   PARTICUU/E FIELD DATA
PI ant  PC/RM - Marietta
Run NO.  MlB-6
Location  inlet to  Scrubber
                                       VERY IMPORTANT  - FILLJOLL^ BLANKS

                                       Read and record at the start of each
                                       test-point or,  if single point
                                       sampling, read  and.record every 5
                                       minutes.
                              Sample Box Mo.

                              Meter Box No.
                                        +  12 ml Condensate

                                        Ambient Temp °F	78

                                        Bar. Press. "Hg__
                                         29.5
                                        Assumed Moisture %  6.0
Date
8-1-71
Probe Length
11'
Heater Box Setting,  °F 250
Operator 'Blessing
                              Probe Heater Setting    65
                                        Probe Tip Dia.,  In.      3/16

Point
0
A-4
A-3
A- 2
A-l
—
0
B-4
B-3
B-2
B-l

0
i C-4
! C-3
C-2
C-l
i
1 o
D-4
D-3
i D-2
1 D-,1

Clock
Tfae
1100




1112
1125




1137
1150




1202
1208

*

122Q

Dry Gas
Meter, CF
217.84 '
219.00
220.20
_
202.53
4069
222.53
-
—
226.00
226.27
4.24
226.77
227.70
228.50
229.35
229.87
3.10
229.87
231.03
237.24
233.43
234 3§
4.49
Pi tot
in. H20
AP
0.61
0.61
0.61
0.68
0.40
0.58
0.63
0.65
0.60
0.46
0.25
0.57
0.32
0,32
0.32
0.28
0.15
0.28
0.69
0.69
0.73
0.67
Q«26 i
0.61 1
Orifice
in H-j
Desired
0.48
0.48
0.52
0..58
0.35
0.48
0.54
0.56
0.47
0.39
0.18
0.43
0.24
0.24
0.22
0.20
0.11
0.20
0.48
0.48
0.54
0.50
P i 9
0.44
AH
0
Actual
0.48
0.48
0.52
- 0.58
0.35
0048
0.54
0.56
0.47
0.39
0.18
0.43
0..24
0.24
0.22
0.20
0,11
0.20
0.48
0.48
_0J!_5_2_ 	
0.50

0.44
Dry Gas
Op
inlet
82
83
85
88
90
86
86
88
90
92
93
90
90
92
92
94
94
92
93
94
96
93

94
Temp.
Outlet
80
81
81
81
82
81
84
84
85
85
86
85
87
87
88
88
89
88
90
90
90
91
91
90
Pump
Vacuum
In. Hg
Gouge
3.0
3.0
4.5
6.0
5.5
4.4
6.0
9.5
9.0
9.5
6.5
8.1
6.5
9.0
10.0
10.0
8.0
9.1
14.0
20'. 5
24.5
5.0

., 3.5,. 	
Box
op
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
25 0_^
250
-
250
250
250

250
Ircpinger
Tsxp
°F
-
-
—
_

90

-
-
-
-
100
_
—
• r

-
100
-
-
_
_.
' ^,
100
Stack
Press
i n . Kg
1.2
•
—
_

1.2
1.2
-
-
-

1.2
1.0
—
-
-
-
1.0
1.2
_
«.
__
-.
1.2
Stack
°F
555
495
500
505
465
504
485
550
4S5 .
555
I 565
530
715
785 \
805
690
703 .
740
.755
625
625
665
fa6"5 i
667 i

-------
MTfi-6 CONTINUED
Point
0
E-4
E-3
! E-2
E-l



Clock
Tircs
1235
'



Dry Gas
Meter, CF
234.36
_•
236.61
238,10
239.38
5.02

60
t
\





21.54



Pi tot
In. H^O
AP
0.60
0.60
0.82
0.85
0.70
Oo71

0.50






1















I
\
1






Orifice AH
in H00
De-sired *
.0.44
0»44
0.60
0.57
0.58
0..53

0.42
Actual
0.44
0B44 '
0.60
Dry Gas Temp.
op
Inlet 'Outlet
93
95
98
0.57 i 102
0.58 103
0.53

0.42
I
1


1
1
* Filtek: Changed. I
l .



















98

92

90
91
91
Pump
Vacuum
In. Kg
Gouge
7,0
7.5
10.0
Box
Temp.
°F
250
250
250
92 111.0 250
92
91

87










12.5 (250
9.6

8.9







I


!
!
1
' 1
i









1 1 i




•
I











•
.











1










[





t




250

250
























Ircpinger
Te:;:p
°r
-
—
-
-
—
100

98
S*. ^ ^ i.
UUwA.
Press
in. He;
Stcck
Tcrsp
op
1.4 680
—
650
595
-
-
520
515
1.4 592

1.2


































.





-




607
'















fc •





*

Corr.rr.2nts:

.NCAP-37-(12/67)
C = 1.13
% Moisture =6.0

Tm =  78°
AH @  = 1.95

PS/Pm = .997

-------
     rt 10, p. 4 of 8
                                              PARTICUL  .£ FIELD DATA
Plant
PC/RM - Marietta
Run No.  MiD-7
                                        VERY  IMPORTANT - FILLJN^.AU^ BLANKS

                                        Read  and record at the start of each
                                        test  point or, if single point
                                        sampling, read and record every 5
                                        minutes.                    .
                                   Box  No.
•f 10 ml Condensate

Pb - 29.7-

Ambient Temp °F	

Bar. Press. "Hg
                                             90
                                             29.7
Location   Inlet to Scrubber
Dcte   8/1/71
                           Meter Box  No.

                           Probe Length
                       Assumed Moisture  2     6.0
11
Heater Box Setting, °F   250
Operator   Blessing
                           Prcbs Heater Setting    65
                       Probe Tip Dia.,  In.   3/16

Point
0
A -4
A -3
A -2
A-l
_
0
B-4
B-3
B-2
B-l
- '
o
C-4
C-3
C-2
C-l
-
6
D-4
D-3
D-2
D-l
•'••"•"•-" 	 ;—•
Clock
Tfae
1525







•





.








1*43
Dry Gas
Meter, CF
239.45 -
-
241.71
242.98
244.06
4.61
244.06
-
246.37
247.44
248.15
4.07
248.13
249.04
249.90
250.67
251.27
.3.14
251.27
252.45
* 253.65
254.60
255.41
3.14
Pi tot
in. HgO
AP
0.66
0.61
0.63
0.75
0.45
0.62
0.60
0.63
0.60
0.50
0.22
0.51
0.32
0.32
0.32
0.28
0.15
0.28
0.72
0.72
,_ 0.78
0.73
0.29
0.65
Orifice
in H,
Desired v
0.48
0.44
0.49 J
0.47
0.38
0.45
0.45
0.47
0.47
0.34
0.16
0.38
0.26
0.26
0.22
0.20
0.10
0.21
0.48
0.48
0.52
0.49
0.20
0.43
AH
0
Actual
0.48
0.44'
0.49
0.47
0,38
0.45
0.45
0.47
0.47
0.34
0.16
0.38
0.26
0.26
0.22
0.20
0.10
0.21
0.48
0.48

0.49
0.20
0,43
Dry Gas
°F
Inlet
92
92
95
96
97
94
98
98
101
102
103
100
103
103
103
104
104
103
100 '
102
103
98
100
101
Temp.
Outlet
91
91
91
91
91
91
92
92
93
93
94
93
96
96
96
96
92
96
97
98
98
96
97
97
Pump
Vacuum
In. Hg
Gsuge
3.0
3,0
6.0
6.0
5.5
4.7
6.0
7.0
9.0
8.5
5.5
7.2 _j
8.0
8.5
8.5
9.0
7.0
8.2
16*5
20.5
25.0
4.0
3.0
13.8.
Box
Terrp.
L °F
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
Ir.pinger
°F
' _
-
-
-
-
100
-

-
.
_ .
100
-
'

-
-
90
-
_
"
-
• -
90
Stack
Press
in. Hg
1.3
-
-
-
-
.1.3
1.1
-
-
-
-
-
1.1

-
-
-
1.1
0.90
_
-
-
-
0.90
Stack
Temp
°F
430
540
515
454
454
479
550
510
505
550
550
593
520
720
650
705
7D5 .
660
725
705
727
695
680
706

-------
MID- 7 C6MT|K|(/£D
Point
0
E-4
E-3
Clock
Tirtt


Dry Gas
Meter, CF
255.41
-
258.03
E-2
E-l




-
260.47
1700 | 5.06



Pi tot
in. H20
AP
0.85
0.85
0.85
0.90
0.72
0.83

20.02 0.58
! ! i
i

.



i
>


* Filtet Changed

1
'
•1 I






I





•





.



Orifice AH
in HoO
Des i red '
•0.59
0.59
0.56
0.61
0.50
0.57.

0,41





•
••
Actual
0.59
0.59
0.56
Dry Gas Temp.
op
Inlet
98
100
103
0.61 104
0.50
0.57

104
102

0.41 100
1
• .





1
1












1




i









1
i
1






.


L Out let
97
97
98
Pump
Vacuum
In. Kg
Gouge
7.0
8.0
10.5
99 15.5
99
93

95










i














15.5
11.3

9.0


Box
Temp.
°F
250
250
250
250
250
250

250


Inpir.ger
Tcn:p
op
-
_
-


85

93


i i
i







'
i


,





1









1























,




I




































S* - «. i.
UUvA
Press
in. He
l.l
_
--
-
-
l.l










-

Stack
Tcn-p
op
670
800
730
730
660
718

631
t










I
















i







 Coirments:

 NCAP-371(12/67)
a
Assumed moisture %- 6.0
T   =  90
 m
Ps/Pm = 1.0
C Factor - 1.09

-------
   i-d'rt 10, p. 4 of 8
     PARTICULATE FIELD DATA
Plant  PCRM
Hun No.
Location  Inlet 'to Scrubber
          8/2/71
                                       VERY IMPORTANT - FILLJN - ALL. BLANKS

                                       Read and record at the start of each
                                       test point or,  if single point
                                       sampling, read and.record every 5
                                       minutes.
Sample Box No.

Meter Box No. •_

Probe Length
                                        + 12    Condensate

                                        Ambient Temp °F  SO^
                      Bar. Press. "Hg  29.7
                      Assumed Moisture %  6.0
11
Operator   Blessing
Probe Heater Setting    65
Heater Box Setting,  *F  250

Probe Tip Dia.,  In.    3/16

Point
0
A-4
A-3
A- 2
A-l
-
0
B-4
B-3
B-2
B-l
-
i 0
C-4
1 C-3
111 C-2
C-l
_
0
D-4
n-3
D-2
t 	 	 !r~r
L . rtf
I
Clock
Tira
0945




0957















— — — — — TC


Dry Gas
Keter, CF
260.65
261.70
262.85
264.05
264.94
4.29
264.94
266.17
267.38
-
269.00
4.06
269.00
269.65
270.38
—
271.61
2.61
271.61
272.83
27/1.13
275.16
27^.90
4.29
Pi tot
in. H£0
Ap
0.55
0.55
0.62
0.73
0.40
0.57
0.73
0.70
0.70
0.43
0.21
0.55
0.30
0.30
0.35
0.25
0.17
0.26
0.80
O.RO
0.90
0.55
0.34
0.66
Orifice
in Ho
Desired w
0.43
0.43
0.46
0.52
0.25
0.42
0.54
0.25
0.52
0.30
0.14
0.40
0.15
0.15
0.18
0.14
0.10
0.14
.0.53

0.65
0.32
	 	 	 0.17 	
0.44
AH
0
Actual
P. 43
0.43
0.46
0.52
0.25
0.42
0.54
0.52
0.52
0.30
0.14
0.40
0.15
0.15
0.18
0.14
0.10
0.14
0.53
0.53
0.59
0.32
',,0.17 ...
0.43
Dry Gas
°F
Inlet
82
87
88
90
92
88
91
93
94
97
97
94
95
97
97
98
98
97
9R
100
100
98
	 	 99 	
99
Temp.
Outlet
82
85
85
85
85
84
86
87
87
88
89
87
90
90
91
91
91
91
94
93
95
95
96
95
Pirap
Vacuum
In. Hg
Gouge
2.0
2.5
3.5
5.0
4.0
3.4
6.5
9.0
10.0
10.5
7.5
8.7
6.0
8.0
8.5
8.0
6.5
7.4.
17.0
-21.5 _^
25.0
1.5
2.0
13.4.
Box
Temp .
°F
250
250
250
250
250
250
250
250
250
250
250
250
. 250
250
250
250
250
250

250
250
250
250
250
Ircpinger
Tcn:p
°F
80
	
_
—
-
90
—
—
""
—

90
_
. —
• ; -
-
—
100


—
—
. -
100
Stack
Press
in. Hg
1.3
_
_
—

1.3
1.2

—
_

1.2
1.1
—
—
-
—
1.1
1 .1

_
-
-
1.1
Stack
Tea?
°F
490
545
625
800
492
492
550
545
670 .
700
810
655
1120
1050 !
845
445
500 .
797
700
640
750
640
650
672 1

-------
                                                    Ml

Point
0
E-4
E-3
E-2
E-l




i
1

i
i
i














\
!

Clock
TlKS
1103




1115


60




-


















Dry Gas
Mater, CF
275.90
277.16
278.40
279.68
2R0.70
4.80


20.05







-















Pitot
in. H20
AP
0.80
0.80
0.80
0.85
0.40
0.73


0.55



* Filte



















Orifice
in Ho
De-si red
0.55
0.55
0.52
0.56
0.33
0.50


0.38

.

r Changed-
•
.

















AH
0
Actual
0.55
0.55 '
0.52
0.56
0.33
0.50


0.38
V .
'


.

• •
















Dry Gas
°F
Inlet
98
100
103
104
104
102


96























Temp.
Outlet
95
96
97
97
98
97


91 ,























Pump
Vacuum
In. Kg
Gouge
4.0
6.0
L_7'°
10.0
9.0
7.2


8.0























Box
Terr.p.
°F
250
250
250
250
250
250


250























Irupinger
Tc:;:p
°F
-•
-
—
—
__
90


94























C*. ./.I.
OLliC/t
Press
in. Ho
1.3
—

—

1.3


1.2























Stsck
Ten-.?
°F
650
750
4bb
450
450
551


633















h







Co-ments:


NCAP-37-(12/67)
o
I
IsJ

-------
      t 10, p. 4 of 8
                                               PARTICULAR  FIELD DATA
Plan t    UC/RM - Marietta


Run No.    MID-9
                                         VERY IMPORTANT -  FILLJW .ALL. BLANKS

                                         Read and record at the  start of each
                                         test point or, if single  point
                                         sampling, read and record every 5
                                         minutes.
                                          Condensate  + 14 ml

                                          Ambient Temp °F	85
Location   Duct inlet
       Box No. _

Meter Box No.
                     Bar. Press.  "Hg   29.7
                     Assumed Moisture %   6
             8-2-71
Probe Length
11'
Heater Box Setting, °F  250
Operator    Blessing
Probe Heater Setting    65
                     Probe Tip Dia., In.   3/16




















VI
y
i
I
• 1

1

Point
0
A -4
3
2
1

0
B-4
3
2
1
'
0
C-4
3
i 2
1

0
D-4
3
2
1
Avg .
Clock
lira
1810
!


1822

1828



1840

1845




1857
1902




1914
Dry Gas
Meter, CF
280.70 •
281.87
283.10
284.29
285.21
4.51
285.21
286.57
_
288.78
289.58
4.37
289.58
290.46
291.33
292.13
292.70
3.12
292.70
293.90
295.04
296.17
297.33
	 " 4. 6 3
Pi tot
in. H20
AP
0.58
0.58
0.51
0.60
0.32
0.52
0.70
0.70
0.70
0.45
0.22
0.55
0.43
0.43
0.40 ._
0.30
0.16
0.34
0.68
0.68
0.65
0.65
0.65
0.66
Orifice
in Ho
Desired
0.42
0.42
0.52
0.52
0.27
0.43
0.67
0.67
0.45
0.34
0.20
0.42
0.26
0.26
0,25
0.22
0.10
0.22
n.Afi
0.48
0.45
0.45
0.45
0.46
AH
0
Actual

-------
M1L .9 CONTINUED
Point
0
E-4
3
Clock
Tin:-
1917


2
1
1929
1
I
Avg. |
i
Dry Gas
Meter, CF
297.33
298.43

Pi tot
in. H20
AP
0.65
0.65
0.84
o.;o
301.66
4.33

0.78
0.72

20.96 0.56









!

'




\







< \

i

•



Orifice AH
in H^O
De-sired "
.• 0.42
0.42
0.58
0.44
0.50
0.49

Actual
0.42
0.42-
0.47
Dry Gas Temp.
Op
inlet r Outlet
100
101
102
0.37 102
0.30
0.39

103
102

0.41 | 0.37 j 97









1 •



















1











95
95
96
Vacuum
In. Kg
Gouge
14.5
19.0
25.0
Box
Tcrr.p.
°F
250
250
250
Iir.pinger
op
100
100
100
96 25.0 250 100 .
92
96

91

26.0
21.4

9.1














250 100
250

250














! 1 1


























1

1 •

















i



















100.

95
StuCk
Press
in. !-in


Stack
Tcn-p
°F
700
730
! 730


810
850
764






i






'
.












bzy
»












i



















V







Comments:


.NCAP-37- (12/67)
ho
00

-------
   Fart 10, p. 4 of 8
                                               PARTICIPATE  FIELD  DATA
Plant   UC/RM - Marietta
Run No. MID-10
Location  No. 1 Duct Inlet
                                         VERY IMPORTANT -  FILL  IN.ALL  BLANKS

                                         Read and  record at  the  start  of each
                                         test point or, if single point
                                         sampling,  read and  record every 5
                                         minutes.
                               Sample Box Mo.

                               Meter Box No.
                                                                         Condensate 8 ml

                                                                         Ambient Temp °F    80
                                         Bar.  Press.  "Hg     29.6
                                         Assumed Moisture  %   6
Dcte
8/3/71
Probe Length
11'  plus
Hccter Box Setting,
°F
250
Operator  Gonzalez
                               Probe Heater Setting    65
                                         Probe Tip Dia.,  In.   3/16
o
1
Ni
VO
• i
1
1
Point
0
A-l
A- 2
A-3
A-4
0
B-l
B-2
B-3
B-4
o
C-l
C-2
C-3
C-4
0
D-l
D-2
D-3
D-4




Clock
Tin:*
1006
1009
1012
1015
1018
1021
1024
1027
1030
1033
1038
1041
1044
1047
Dry Gas
Keter, CF
301.80



306.81
-



310.51
-



1050 313.60
1053
1057
1100
1103
1106


.

-



318.10




Pi tot
in. H20
AP
0.60
0.68
0.72
0.35
0.35
0.55
0.50
0.35
0.14
0.15
0.32
0.34
0.30
0.15
.0.14 _
0.70
0.72
0.52
Orifice AH.
in HoO
Desired "
0.49
0.58
0.59
0.30
0.30
0.42
0.39
0.27
0.12
Actual
Dry Gas Temp.
op
Inlet
0.49 1 80
0.58
84
0,59 ! 86
0.30
0.30
0.42
0.39
0.27
0.12
0.12 | 0.12
0.22
0.24
0.22
0.24
0.20 I 0.20
0.10
n in
0.45
0.52
0.10
n in
0.45
88
88
84
88
88
88
92
90
90
92
94
Ok
92
0.52 1 96
0.39 | 0.39
0.15 I 0.11 1 0.11
0.15



0.11
0.11
96
Outlet
80
82
82
Pump
Vacuum
In. Hg
Gouge
2.5
4.0
4.0
82 ] 4.0
82
82
84
84
84
85
86
86
86
86
..86 ...
88
90
90
98 ' 90
98
I I
(CONTI1

1
JUED ON NE


XT PAGE)


90




4.0
4.0
5.0
5.0
3.0
3.0
3.5
4.0
3.5.
2.5
_? .5
6.0
7.0
7.0
4.0
4.0




Box
Tenp.
°F
250
250
250
250
Ircpinger
Tcxp
°F
80
80
80
80
250 I 80
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250




S" •> r- *r
lUs.lt
Press
in. fit;
0.1
0.1 .
Stack
Temp
°F
480
540
0.1 1 540
0.1 | 375
0.1 i 375
80 • I 0.1 ! 545
80 I 0.1
80
0.1
80 1 0.1
80 ! 0.1
80 t 0.1
80
80
80
•rf'n
0.1
0.1
0.1
n i
85 I 0.1
85
0.1
85 J 0.1
85
85




0.1
0.1



580
600
61.0 •
610
[ 670
710
815
810 !
800
760
640 .
740
580
580


i
i

-------
M4D-IO CQNT/NUeO
Point
0
E-l
E-2
Clock
Tiise
1110
1113
I 1116
I E-3 \ 1119
E-4

•

1122



\
!

j i
I 1
i 1
i
1
r
Dry Gas
Keter, CF




322.45

20.65







i
Pi tot
in. HgO
Ap
0.52
0.80
0.66
0.45
0.46

0.43


1-





Orifice AH
in H^O
Desired "
0.38
0.48
0.41
0.28
0.28

0.31






'

Actual
0.38
0.49
0.41
Dry Gas Temp.
•F.
Inlet
94
96
98
0.28 ! 98
0.28

0.31

98

92
.
'
.
.
-

.

! •! 1 1 1 i




i







i

'










• -




















i
i
i
	

i
















Outlet
88
90
92
PCT?
Vacuum
In. Hg
Gouge
<• . 6.0
10.0
9.5
94 1 8.0
94

90



..



.
8.0

5.0







Box
Terrp.
°F
250
250
250
250
250

250







1
1 I.I


!
j









"












I











1
1










I

1



















!




Ircpinger
Tcn:p
•°r
90
90
90
90
90
Stcck
Press
in. H«j
0.1
0.1
Stsck
Ten:?
°F
F680
805
0.1 1850
0.1 1875
0.1
1
85
.


0.1


'
t



•


1















.



875 1

655

»












i



'

i


*
'





t






i
 Comments:


 NCAP-37'02/67)
a
LJ
o

-------
   Part 10, p. 4 of 8
                                               PARTICIPATE  FIELD DATA
Plant    UC/RM - Marietta
Run No.    MlD-ll
Location    No.  1 "Duct Inlet

Date      8/3/71
                                         VERY  IMPORTANT  -  FILLJN.AJ4 BLANKS

                                         Read.and  record at  the start of each
                                         test  point  or,  if single point
                                         sampling, read  and.record every 5
                                         minutes.
Sample Box No.

Meter Box No.
                                          Condensate + 7 ml
                                          Ambient Temp °F
                    85
Bar; Press. "Hg    29.6
                                                                                   Assumed Moisture %  6
                                          Probe  Length
                    11'
Heater Box Setting,
°F
                                                                  250
Operator   Gonzalez
Prcbs Heater Setting  65
Probe Tip 01a., In.  3/16



















c
1
u
1 1
1
' 1
( 1
' 1

Point
0
A-4
3
2
1
O
B-4
3
2
1
0
C-4
3
2
1
0
D-4
3
2
1



•
Clock
Tis:a
1400
1403
1406
1409
1412
1415
.1418
1421
1424
1427
1430
1433
1436
1439
1442
1457
1500
1503
1506
1509




Dry Gas
Keter, CF.
322.45



326.59




330.06














Pitot
in. H£0
AP
0.45
0.50
0.56
0.37
0.36
0.53
0.57
0.35
0.22
0.20
0.34
0.30
0.28
0.15
0.15 •
0.58
0.60
0.32
0.25
0.25


J

Orifice
in Ho
Desired
0.27
0.38
0.43 J
0.28
0.28
0.41
0.38
0.24
0.12
0.12
0.23
0.20
0.17
0.09
0.09
0.38
0.39
0.21
. 0.17
0.17

CONTINUED TO


AH
0
Actual
0.27
0.38
0.43
0.28
0.28
0.41
0.38
0.24
0.12
0.12
0.23
0.20
0.17
0.09
—Q.J3.9 .....
0.38
0.39
0.21
0.17
0.17

NEXT PAG1


Dry Gas
°F
Inlet
86
88
90
90
92
92
94
94
94
94
94
96
96
96
96
94
94
94
94
96

]


Temp.
Outlet
86
88
88
88
88
88
88
88
90
90
90
90
90
90
90^
92
94
94
94
94




Pump
Vacuum
In. Hg
Gouge
2.5
3.0
4.0
4.5
4.5
5.5
7.5
7.0
5.0
5.0
7.5
7.5
7.5
6.0
6.0
10.5
15.0
24.0
20.0
20.0




Box
Te.^p.
L °F
250
250
250
250
250
250
250
250
250
250
250
250
250
2 SO
250 j
250
250
250
250
250




Irr.pinger
Texp
°F
95
95
95
95
95
95
95
95
95
95
95
95
95
95
•95
95
95
95
95
95




Stack
Press
in. He?
0.09
0.09 .
0.09
0.09
0.09
0.09
0.09
0.09
0.09
0.09
0-09
0.09
0.09
0.09
0.09
0.09
0.09
0.09
0.09
0.09




Stack
Ten-.?
or
480
490
490
500
500
500
655
600
6'70 .
660
660
650
690
710
710 i
710
7*00 .
690
595
560

• 1
1'


-------
                                                       MlO-M
• •
Paint
0
E-4
3
! 2
1

' AVR.


i
1


i
'
i




1






'
i
i
i

Clock
Tifi-,5!
1415
1 1418
1421
| 1424
1427





.





















Dry Gas
Meter,. CF




340.38

17.93

•























Pi tot
in. P^O
AP
0.62
0.75
0.50
0.45
0.45

0.40

























Orifice
in Hx,
DCS. i red
. 0.43
0.51
0.33
0.31
0.31

0.27






•













-


'

AH
0
Actual
0.43
0.51 '
0.33
0.30
0.30

0.27






















•


Dry Gas
or
Inlet
96
96
96
96
96

95











.













Temp.
Outlet
94
94
94
94
94

90

























Pump
Vacuum
In. Hg
Gouge
23.0
24.0
25.0
25.0
25.0





















,




>
Box
Tersp.
op
250
250
250
250
250

250



•





















Ircpinger
Tc:;:p
o —
95
95
95
9i>
95

95




.




















Stock
Press
in. Hr;
0.09
0.09
0.09
o.oy
0.09

0.09

























Stack
Tc"?
°F
670
720
550
i/0
605 1

654

V















»




. 1


 Comments:



 .NCAP-37-02/67)
o
i
CO

-------
Irt  10, p. 4  of 8
PARTICL'L.,'fe FIELD DATA
                                    VERY IMPORTANT - FILLJN.ALL^ BLANKS

                                    Read and record at the start of each
                                    test .point or, if single point

Plant UC/RM - Marietta
Run No.
MID- 12
Location NO: i inlet Duct
i
o
s
1
1
• i
1
Dcte
Operate
Point
0
A-4
A-3
A-2
A-l
0
L B-4
B-3
B-2
B-l
0
8/4/71
* Gonzalez

Clock
Ttae
1048
1051
1054
Dry Gas
Meter, CF
340.92 .


Pi tot
in. H20
AP
0.40
0.48
0.58
1057 0.40
1100
344.78
1103
.1106
1109
1112



1115 348.50
1117
C-4 1120
C-!3
C-2
1123
-


1126
C-l | 1129 j 351.18
0
0.38
0.56
0.48
0.39
0.35
0.35 _J
0.32
0.30
0.25
0.14
sampling, read and. record every 5
minutes.
Ssaple Box No. 2
Meter Box No. 2
Probe Length il1 plus
Probe Heater Setting
Orifice
in Ho
Desired
0.35
0.34
0.42
0.29
0.28
0.42
0.36
0.28
0.26
0.26
0.23
0.21
0.17
0.13
0.12 0.11
1132 | - 0.56
D-4 1135
D-3
D-2
1138
1141
D-l 1144
0 1200
E-4
0.62
0.52
0.38
0.41
0.34
0.22 | 0.19
354.91 1 0.23

1203

1
0.50
0.20
0.30
0.65 | 0.47
i (Corvtl
AH
0
Actual
0.35
0.34
65

Dry Gas Temp.
°F
Inlet Outlet
80
82
0.42 j 82
80
82
82
Condensate
Ambient Te
Bar. Press
Assumed Mo
Heater Box
Probe Tip
Pum?
Vacuum
In. Kg
Gouge
2.5
4.0
5.0
0.29 84 82 5.5
0.28 I 84
0.42
0.36
0.28
84
86
86
0.26 88
0.26 j 88
0.23
0.21
0.17
0..13
0.11
0.38
88
88
88
88
88
88
0.41 90
0.34 j 90
0.19
0.20
0.30
0..47
inued on
i
92
92
86
88
82 I 5.5
82 1 8.0
82 8.5
82
82
82
82
82
84
84
84
84
85
85
86
86
86
88
lext page!) ,
i
9.0
9.0
9.0
7.0
9.0
9.0.
9.0
8.5
15.0
20.0
25.0
Box
Temp.
OF
250
250
250
250
6 ml
mp °F 80
. "Kg 29.58
isture % 6
Setting, °F 250
Dia., In.
3/16

Ircpinger
Tcn:p
80
80
80
80
250 80
250
250
250
250
250
80 •
80
80
80
80
250 ) 80
250
250
250
250
250
250
250
19.0 i 250
19.0 J250
20.0
25.0


250
250


80
80
80
8JU
85
85
85
85
85
85
85


Stack
Press
in. Kg
0.08
0.08.
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08
0.08


Stack
T£"?
°F
370
550
600
570
560
520
595
640
555 .
520
L600
625
655
330
325
670
715 •
735
.330
330
720
610



-------
MID- ri. eoN7/Nt>e0
Point
E-3
E-2
E-l
Clock
TiKS
[ 1206
1209
Dry Gas
Hster, CF


1212 358.94

18.02




1
u
!
.


i
i




Pi tot
in. HgO
Ap
0.78
0.56
0.50

0.42












i
. i
i














i


r







Orifice AH
in HoO
Desired "
.0.57
0.46
0.41

0.31


Actual
0.57
0.46
0.41
Dry Gas Temp.
op
Inlet Outlet
88
88
88

0.31 86




88
88
88
Pump
Vacuum
In. Hg
Gouge
26.0
26.0
26.0

85


1




































•


















i












I
|

1


i





-

































1




















Box
Ternp.
op
250
250
250

250




Ircpinger
Tcrp
°F
85
85
85

85

S*. , x-l.
uu<./>
Press
in. r!q
0.08
0.08
'Stock
Tern?
op
590
410
0.08 410


0.08 541

I



1






















1




























.






»












i
i












t





i

 Comments:



 NCAP-37'(12/67)
u
I
OJ

-------
    Part 10,  p.  2 of 8
                               VELOCITY  TRAVERSE FIELD DATA
          Plant
          Test
UC/RM - Marietta
Preliminary Traverse (ETE)
          Location  East Tapping  Exhaust
          Date      8/4/71
          Operator   Schroeder
                              STATIC PRESSURE •= .51
Clock
Time
1505








1515

AVG.

Point
l
2
3
4
5
6
7
8
9
10



AP, in. H20
1.35 1.25
1.50 1.20
1.45 1.45
1.55 1.40
1.50 1.35
1.20 1.20
1.20 1.10
1.20 1.20
1.14 1.20
1.15 1,20



Stack
Temp., °F
90 99
95 99
98 99
99 99
99 99*
99 99
99 99
99 99
99 99
99 99
«







.


•





AVG.
1.30 ' 94
1.35 97
1.45 98
1.48 99
1.42 99
1.20 99
1.15 99
1.20 99
1.17 99
1.18 99

.1.29 98


/hP x (T+460J*
'


•
•

i
• j
*
i
i


.

-------
    irt 10, p. 4 of 8
     PARTICULM/E FIELD DATA
PI ant   UC/RM - Marietta

Run No.  ETE-IA
Location   East Tapping Exhaust

Date   8/5/71	

Ooarator ' Baxley
                                         VERY  IMPORTANT -  FILL  IN.ALL  BLANKS

                                         Read  and  record at  the start  of  each
                                         test.point  or, if single point
                                         sampling, read and.record  every  5
                                         minutes.
Sample Box No. •	3_

Meter Box No.    2
                                          (False Tap  Run)
                                           No Tapping
                                          Ambient Temp °F
                                            90
                        Ear.  Press.  "Hg     29.7
                        Assumed Moisture  2  3.4
Probe Length
H'41
Heater Cox Setting, °F   250
Probe Heater Setting    50
                        Probe Tip Dia.,  In.  3/16



















c
u.

(
• i



Point
Start
1
2
3 Off
3 On
4
5
6
7
8
9
10
4
4
4
4
4
4
4
4
4
4


Clock
lira
1015
1018
1021
1028
1031
1034
1037
1040
1043
1046
1049
1052
1055
1058
1101
1104
1107
1110
1113
1116
1119
1120


Dry Gas
Meter, CF
360.43 -
362.70
364.14

366.80
369.00
370.56
373.50
375.63
377.80
380.70
382.30
384.55
387.25 	 ,
389.75
392.30
394.78
397.32
399.80
403.20
405.70
406.95


Pi tot
in. HgO
Ap
-
1.20
1.30

1.40
1.40
1.40
1.40
1.20
1.20
1.10
1.10
1.40
1.40
1.40
1.40
1.40
1.40
1.40
1.40
1.40
1.40


Orifice
in Ho
Desired
> - -
1.60
1.80

1.85
1.85
1.85
1.85
1.60
1.60
1.45
1.45
1.85
1.85
1.85
1.85
1.85
1.85
1.85
1.85
1.85
1.85


AH
0
Actual

1.60
1.80

1.85
1.85
1.85
1.85
1.60
1.60
1/45
1.45
1.85
1.85
1.85
1.85
1.85
1.85
1.85
1.85
1.85
1..85


Dry Gas
°F
Inlet

68
68
.
76
86
90
90
90
100
102
102
104
112
114
114
116
116
118
120
120
120


Temp.
Outlet

68
68

70
L 70
72
72
72
76
76
76
76
76
80
84
86
86
88
88
88
88


Pump
Vacuum
In. Hg
Gauge

7.0
7.0

7.2
7.2
7.2
7.2
6.5
6.5
6.2
6.2
9..0
9.0
9.5
10.0
10.0
10.0
10.0
10.0
10.0
10.0


Box
Temp.
°F

250
250

250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250
250


Ircpinger
Ta:p
°F

65
65

65
65 .
65
65
65
65
65
65
65
65
45
65
65
65
65
65
65
65


Stcck
Press
in. ric;



'




















Stack
Ten:?
op

130
125

130
130
130
130
130 .
130
130
130
130
130
130
130
130 .
130
. 130
130
130
125



-------
   Part 10, p. 4 of 8
                                               PARTICIPATE FIELD DATA
Plant
UC/RM - Marietta
                                         VERY IMPORTANT -  FILL  IN.ALL  BLANKS

                                         Read and record at the start  of each
                                         test point or, if single point
                                         sampling, read and.record every 5
                                         minutes.
Run No.   ETE-I
Location  East  Tapping Exhaust


D£te
8/5/71
Operator  Baxley & Avery
Sessple Box No. 3
Meter Box No
Probe Length
Prcbs Heater
2
ll't
Setting

l"
50
Condensate +6 ml

Ambient Temp °F     90

Bar. Press. "Hg
                                                                                              29.7
                                                                         Assumed Moisture  %    3.4
Heater Cox Setting, CF   250
                                                                         Probe Tip Dia.,  In.   3/16















i
1


t
u

i
i
r
i

Point
Start
1
2
3
4
5
6
7
8
9
10
4
4
4

AVG.





i

1
Clock
TiTO
1130
1133
1136
1139
1142
1145
1148
1151
1154
1157
1200
1203
1206
1207

37








Dry Gas
Kster, CF
406.95
409.30
412.75
414.50
417.00
419.47
422.20 .
424.78
428.00
429.38
431.45
433.60
435.82
437.14

30.19








Pi tot
in. KgO
AP

1.30
1.30
1.30
1.40
1.40
1.30
1.10
1.10
1.10
1.10
1.40
L 1.40
1.40

1.28








Orifice
in H.
Desired

1.75
1.75
1.75
1.85
1.85
1.75
1.60
1.60
1,60
1.60
1.95
1.95
1.95

1.76








AH
0
Actual

1.75
1.75
1.75
1.85
1.85
1.75
1.60
1.60
1.60
1.60
1.95
1.95
1,95

1.76





.


Dry Gas
°F
Inlet

104
108
108
112
114
114
118
122
122
122
122
120
120

116








Temp.
Outlet

90
92
92
90
90
90
92
92
92
94
94
92
92

92








Pum?
Vacuum
In. Hg
Gouge

10.0
10.0
10.0
10.0
10.0
12.0
13.0
13.0
7.0
7.0
8.0
8..0
9.0

9.8






1
.
Box
Tcrr;p.
°F

250
250
250
250
250
250
250
250
250 _,
250
250
250
250

250








Irr.pinger
Tcxp
°F

65
65
65
65
65.
65
65
65
65
65
65
65
65
i
65








Stcck
Press
in. rig
























Stack
TG-P
°F

100
100
105
105
105
105
105
105 .
105
110
115
115
115
:
107
>





!
i

-------
   Hart !U, p.  4 Of 8
                                               PARTICUL/1'   FIELD DATA
Plant
'UC/RM - Marietta
Run No.    ETE-2
Location   East Tapping Exhaust


Date       8/5/71
                                         VERY  IMPORTANT  -  FILL JN. All  BLANKS

                                         Read  and  record at  the  start  of-each
                                         test  point  or,  If single point
                                         sampling, read  and.record  every  5
                                         minutes.
                               Sample Box No.

                               Meter Box No.

                               Probe Length
Condensate +8 ml

Ambient Temp *F     90

Bar. Press. "Hg     29.7
Assumed Moisture %   3.4
Heater Box Setting,  °F  250
Operator   Baxley & Avery
                               Probe Heater Setting     50
Probe Tip Dia., In.   3/16
Point
Start
1
2
3
4
Clock
Tir^
1430
1433
1436
1439
1442
5 | 1445
6
7
.1448 '
1451
8 j 1454
, 9
10
1457
1501
1
j AVG.
I
1
31

Dry Gas
Keter, CF
437.23
439.58
441.22
443.65
446.11
448.55
450.76
453.00
455.02
457.10
459.88

22.65


1

i


1

1


!









Pi tot
in. K20

1.20
1.30
1.40
1.40
1.40
1.20
1.20
1.10
1.10
1.05

1.24






|.







Orifice. AH
in HoO
Desired

1.70 .
1.85
2.00
2.00
2.00
1.70
1.70
1.60
1.60
1.50

1.76
Actual

1.70
Dry Gas Temp.
op
Inlet

80
1.85 ! 86
2.00
2.00
2.00
1.70
1.70
1.60
1.60
90
96
98
102
110
112 j
114
1.50 116
1
1.76
1 .





1




1


1



100











Outlet

80
80
80
80
82
82
84
84
84
86

82











Pump
Vacuum
In. Hg
Gouge

6.2
6.2
7.2
7.2
7.2
5.2
5.2
5.0
5.0
5.0

5,9











BOX
To^p.
°F

250
250
250
250
250
250
250
250
250
250

250

Ircpinger
V

65
65
65
65
65
65
65
65
65
65

65

1 ,''




1













-------
    irt 10, p.  4 of 8
                                     PARTICUL i FIELD DATA
Plant
UC/RM - Marietta
Run No.   ETE-3
Location  East Tapping Exhaust


Date      8/5/71	


Operator ' Avery & Baxley
                                         VERY  IMPORTANT -  FILL JN.. ALL. BLANKS

                                         Read  and  record at the start of each
                                         tes.t  point  or, if single point
                                         sampling, read and.record  every 5
                                         minutes.
                                         Sample  Box  No.  	3_

                                         Meter Box No.     2
                                                                                    Condensate +4 ml

                                                                                    Ambient Temp °F   90
                                                                          Bar.  Press.  "Hg   29.7
                                                                         Assumed Moisture % 3.4
                                         Probe Length      ll'4"
                                                                         Heater Cox  Setting,  er   250
                                         Probe Heater Setting     50
                                                                         Probe Tip  Dia.,  In.   3/16
















1

r
it
u
^

i
• i



Point
Start
1
2
3
4
5
6
7
8
9
10

AVG.











Clock
TiKS
1602
1605
1608
1611
1614
1617
.1620
1623
1626
1629
1632

30











Dry Gas
Meter, CF
459.88 .
461.96
464.18
466.58
468.74
471.15
473.30
475.50
477.64
479.70
481.77

21.89











Pi tot
in. HgO
AP

1.20
1.40
1.40
1.40
1.30
1.20
1.20
1.05
1.05
1.05

1.22










1
Orifice
in H.
Desired ~

1.70
2.00
2.00
2.00
1.85
1.70
1.70
1.50
1.50
1.50

1.74




'






AH
0
Actual

1.70
2.00
2.00
2.00
1.85
1.70
1.70
1.50
1.50
1.50

1.74





.





Dry Gas
°F
Inlet
85
85
88
90
100
110
110
110
116
120
120

103





•





Temp .
Outlet
85
85
86
90
90
92
92
92
94
92
90
.
90











Pump
Vacuum
In. Hg
Gauge
5.0
5.0
5.5
6.0
6.0
6.0
6.0
6.0
5.0
5.0
5.0

5.5











Box
Tc.^p.
op
250
250
250
250
250
250
250
250
250
250^
250

250











Irr.pinger
Tcn:p
°F
65
/ 65
65
65
65
65
65
65
65
65
65

65

• '.









$*• - /•>,
l_U-_/S
Press
in. h'g





.


















Stack
Tc-p
°F
100
100
100
100
95
95
95
95
•95 .
95
95

97
f
!

k




I
i
	 i

-------
    Part 10,  p.  2 of 8
                               VELOCITY TRAVERSE  FIELD  DATA
          Plant
          Test
UC/RM - Marietta
Preliminary Traverse  (WTE)
          Location  West Tapping Exhaust
          Date      8/4/71
          Operator   Schroeder
                                    STATIC =  -0.44 in.  H20
Clock
T i me
1440








1500



Point
1
2
3
4
5
6
7
8
9
10

AVG.

AP, in. H20
1.05 0.76
0.83 0.75
0.86 0.55
0.78 0.86
1.00 0.84
1.20 1.25
1.10 1.10
1.20 1.20
1.40 1.40
1.60 1.60



Stack
Temp., °F
110 110
110 110
115 110
115 110
115 110
115 110
119 110
119 115
119 115
119 119
«



Avg. 0.90
0.79
0.70
" 0.82
• " 0.92
•1.22
1.1
" ' 1.2
1.4
1.6

1.06


110
110
112
112
112
112
115
115
115
. H9

113

I
•V x (Tracer;
;
i
i
1
',
t
- i
i
t
i
t
i
i
i
i
i
I
i
i
!
1 • • • t
•**
   - Calculation  columns,  not Field data
Consents:
NCAP-29 (12/67)
                                                                              D-40

-------
                                RESOTTRCES RESEARCHA INC,
                                                                 PAGE 1  OF 2
                                      Personnel
                                                  Baxley
Plant Conditions, etc..	
PI an t       '	UC/RM - Mar ietta
                            Entered_
                            Checked
                                                          Pate    8/4/71
Sample Location^
                    WTE - Moisture Determination
r Time
1443
1453
1503
1513
AVG




,.










Sample
Number









Meter #_ L HAS MKTER CONDITIONS Pi«f.r *
Cu.Ft,
Reading
585.40
597.10
608.10
618.10
32.70















Cu.Pt.(Vm)
Difference




















Elapss
Min.

10
10
10
30










.




(Km)
C.F.M.




















(-J460=Ttn)
'etnp °P
68
70
74
74
72















I^Q
Condensate,ml (Vw)     5 ml
                           °P+460=T8
°R
Estimated Rm(Corrected)	
Calculated Rjn(Corrected)_
Sample Nozzle Dla,,In.(d)_
% Moiattrre of Gas	
                                29.6
    Avg.Gas Velocity,fpm(Vsx60)_
    Vs=(2.9 xF.) x xTS" 3t Vf"
               S  •             ~
          or
         2.46
                                                                                D-41

-------
                                                               PAGE 2 OF 2

                                        WTE- 4

                              TRIAL MOISTURE CALCULATIONS
1.  Isokinetic Sampling  (Dry Gas)  (cfm)

                          2
    1^ - .33 x Tm x Vg x d  x    PS         :  Rm  (corrected)  =  Rm x  Me

               TS              Pb  - Pm
                               t


Estimated Value:



Calculated Value:
2.  Water Vapor Volume  (cu. ft.)


    Vv «= .00267 X YW x  ?"*           .00267 x -5 x 532.  = 0.329
                  ^b -  pva                      27<6
3.  Condensate Correction  for Meter Rate


    MC °           Vm	      32.70     _  32.70
                Vm •!- Vv            32.70        32.37
    Moisture in Metered Gas  (cu.  ft.)


    IL. e    V.P. x Vn           .522 x 32.70   =   79
            p  _ p                  21.6
             o    m
5.  Percent Moisture  (%) Stack Gas   .


    % Moisture =   vv * '^V  x 100       .33 + .79
                                                        1.12
                   vv * Vm              .33 + 32.70  ~  55^3 =3.38




    Saturated at	%       .           '           -                       'n-42

-------
        10, p. 4 of 8
     PARTICULrtfE FIELD DATA
Plant     UC/RM - Marietta
Run No.   WTE-IA
Location  West Tapping Exhaust


Dcte      8/5/71	


Operator '  Schroeder & Hall
                                         VERY IMPORTANT - FILL  IN.ALL  BLANKS

                                         Read and  record at the start  of each
                                         test'point or, if single point
                                         sampling,  read and.record  every 5
                                         minutes.
Sample Box No.

Meter Box No.
                                         (False  Tap Run)
                                          No Tapping   '

                                          Ambient Temp °F    . 70
                       Bar. Press. "Hg     29.60
                       Assumed Moisture %   3.4
Probo Length
11'
Heater Box Setting, °F  250
Probe Heater Setting    60
                       Probe Tip Oia., In.    3/16
*
M
Point
Start
1
Clock
Tis:s
1045

2 | *
3 1
4

5 I
6
7
8


Dry Gas
Meter, CF
865.12 •
867.20







9 I 884.40
10
888.60
7 1
7
1120 903.78



1
1
!


I
1



r 	 	









"



Pitot
in. H20
AP

1.15
1.10
1.10
0.90
[ 0.87
0.98
1.20
1.25
1.25
1.30
1.20
1.20











Orifice AH
in mo
Desired

1.45
1.40
1.40
1.15
1.10
1.25
1.50
Actual

1.45
Dry Gas Temp.
°F
Inlet
73
75
1.40 75
1.40 i 84
1.15
1.10
1.25
1.50
1.55 J 1.55
1.55
2.65
1.50
1.50


1.55
90
93
98
103
106
111
2.65 i 114
1.50
1.50


1
120
120



3 min. pe)|_j>oint extept 7
* Stopped j 5 min.


i
1
I


'
t







Outlet
70
72
72
73
75
75
76
77
80
83
86
93
95'











Pump
Vacuum
Tn ua
* 1 1 • * ' j
Gouge

1.5
1.5
1.5
1.2
1.0
1.2
1.5
1.75
1.75
Box
Torsp.
°F

200
200
200
200
200
200
200
200
200
2.0 j 200
1.5 1 200
1.5





200

_i




f








Ircpinger
Temp
°F






S*. .. -I.
i.CCi^
Press
in. no,


Stack
TC.TP
or

65
\ 81
1 90
•





90
90
90
90
90
90
1 90



• j





















85
90



V






'•

-------
        10, p. 4 of 8
                                     PARTI Cl
                                                           FIELD  DATA
Plant
UC/RM - Marietta
                                         VERY  IMPORTANT  -  FILLJ^.ALL^ BLANKS

                                         Read  and  record at  the  start of  each
                                         test  point  or,  if single  point
                                         sampling, read  and  record every  5
                                         minutes.
Run No.   WTE-I
Location  West Tapping Exhaust

D^te      8/5/71	

          Schroeder
       Box No.

Meter Box No. •_

Probe Length
Condensate  -12 ml

Ambient Temp °F_

Bar. Press. "Hg
                                                               70
                                                                                               29.60
                                                                         Assumed Moisture %     3.4
                                                  11'
Heater Box Setting, °F  250
                                Probe  Heater Setting   60
Probe Tip Dia., In.   3/16

Point
Start
1
2
3
4
5
6
7
8
9
10
{ 7
I
i AVG.
i


i

i




Clock
Tin:*
1130









1200
1207

37









1
Dry Gas
Meter, CF
903.78








,

926.55

22.77










Pi tot
in. H20
AP

1.20
1.20
0.85
1.00
0.90
0.95
1.00
1.10
1.10
1.15
1.10
-
1.05




'





Orifice
in H*.
Desired

1.50
1.50
1.15
1.25
1.20
1.23
1.25
1.40
1.40
1.45
1.40

1.34




.





AH
0
Actual

1.50
1.50
1.15
1.25
1.20
1.23
1.25
1.40
1.40
1.45
1.40

1.34










Dry Cos
°F
Inlet

107
109
112
115
116
118
119
121
122
123
L 123

116










Temp.
Outlet

93
94
94
96
96
94
95
95
96
95
95

95










Pump
Vacuum
In. Hg
Gouge

1.5
1.5
2.0
3.5
3.0
4.0
4.0
4.5
4.5
4.5
4.5

3.4










BOX
Temp.
°F

250
250
250
250
250
250
250
250
250
250
250

250










1
Impinger
Temp
°F





.








/







•

Stack
Press
in. Hg




•
-


















Stack
T£~P
°F

77
95
105
120 1
126
120
118
115
115
115
118

111 |
!
.
V

(
J


I

1

-------
rart 10, p.  4 of 8
                                           PARTICULATE FIELD DATA
                                     VERY IMPORTANT - FILL IN.ALL BLANKS

                                     Read and record at the start of each
                                     test point or, if single point
Plant UC/RM - Marietta
Run No.
WTE-2
Location West Tapping Exhaust
Date
8/5/71
Operator Schroeder
Point
[ Start
Clock
1430
Dry Ga'S
Meter, CF
.926.45
1 i
2
Pi tot
in. H20
AP

1.20
1.20
3 1.10
4
1 5

6
7




0.95
0.89
0.90
0.95
8 ! I 0.87
9 0.85
10

AVG.



1500

30
944.36 0.90

17.91



i

( 	




0.98

sampling, read and record every 5
minutes.
Sample Box No. 2
Heter Box No. 4
Probe Length 11'
Probe Heater Setting 60
Orifice
in H/-
Desired "

1.50
1.50
1.40
1.25
1.15
1.15
1.25
1.15
1.10
1.15

1.26








AH
Actual

Dry Gas Temp.
Op
Inlet

1.50 86
Outlet

84
1.50 ! 91 84
Condensate
Ambient Te
Bar. Press
Assumed Mo
Heater Box
Probe Tip
Pump
Vacuum
In. Hg
Gouge

4.0
4.0
1.40 98 | 85 4.0
1.25
1.15
1.15
105
105
110
1.25 112
1.15 118
1.10
1.15

1.26
120
120

106
1


i


85
85
87
89
90
91
90

87

4.0
3.5
3.5
3.5
3.5
3.5
3.5

3,7

Box
Temp.
°F

250
250
250
250
250
250
250
250
250
250

250

I i



• ! i
i i
!
j
|
i !
i i






-2 ml
mp °F 75
. "Hg 29.60
isture % 3.4
Setting, °F 250
Dia., In.
Ircpinger
Temp
°F


3/16
Stack
Press
in. Kg


Stack
Te-p
op

105
115









125
128
125



120
115
112 .
110

i
i







1
1 . .
i
I
i
!
i
i



!



i






L 108

115
I


I








-------
rart 10, p.  4 of 8
                                           PARTICIPATE FIELD DATA
VERY IMPORTANT -
                                                                  BLANKS
Plant
Run No.
Location
Dcte
Operator '
UC/RM - Marietta
WTE-3
West Tapping Exhaust
8/5/71
Schroeder
                                     Read and record at the start of each
                                     test point or, if single point
                                     sampling, read and. record every 5
                                     minutes.
                                      Sample Box No.

                                      Meter Box No.

                                      Probe Length
                                          Condensate +2 ml

                                          Ambient Temp °F     70
                                          Bar. Press. "Hg     29.60
                                          Assumed Moisture %   3.4
                  11'
Heater Dox Setting, °F   250
                                      Prcbe Heater Setting    60
                                          Probe Tip Dia., In.   3/16




















a
£•
'

)
f

Point
Start
1
2
3
4
5
6
7
8
9
10
'
AVG.











Clock
Tir:;o
1604








•
1634

30











Dry Gas
Kster, CF.
944.36









962.99

18.63









•

Pi tot
in. K20
AP

1.05
1.05
1.05
1.05
0.97
0.95
1.00
1.10
1.10
1.20

1.05











Orifice
in H/-
Desired

1.30
1.30
1.30
1.30
1.25
1.25
1.28
1.40
1.40
1.50

1.33











AH
0
Actual

1.30'
1.30
1.30
1.30
1.25
1.25
1.28
1.40
1.40
1.50

1.33
.




.





Dry Gas
°F
Inlet

96
99 -
104
106
111
113
117
119
121
120

110











Temp.
Outlet

90
90
90
91
92
92
93
95
95
96

92











Pump
Vacuum
In. Hg
Gouge

1.5
1.5
1.5
1.5
2.0
2.0
2.0
2.0
2.0
2.2

1.8











Box
Temp.
L °F

250
250
250
250
250
250
250
250
250
250

250











Impinger
To:p
°F














•I









$•*• -fif
Lti»_K
Press
in. Kg
























Stack
Ten:?
°F

85
85
117
117
115
113
112
1]>2
lUb
1UD

1U7
|
!

>





--


-------
                                RESOURCES, RESEARCH^ INC,
                                      Personnel
                                                    Entered_
                                                    Checked
Plant Conditions, etes   Metals  Run
Plant   _-'•     UC/RM -Marietta	
                                      Date   8-1-71
Sample Location,
M1E - 6M
  APCO Sample Box #4
, Time
1100
1110
1120
1130
1140
1150; .
1200
1210
1220
, 1230
1240
1245








Sample
Number
M1E-6









Meter $_
Cu.Ft.
Reading
289.55










365.92
76.37







GAS METER CONDTTTHWR P,,«>p #
Cu.Ft.(Vm)
Difference
-
-


















Slaps*
Min.

10
10
10
10
10





•








(Km)
C.F.M.
-



















(4460=Tm)
Temp °F
76
76
78
84
98
100




100
100









-------
        10, p.  4 of 8
                                               PARTICIPATE  FIELD DATA
Plant UC/BM - Marietta
Run NO.   M1E- 7  Metal Test
                                        VERY  IMPORTANT  - FILL  IN.ALL  BLANKS

                                        Read,  and  record at the start  of each
                                        test  point  or,  if single point
                                        sampling, read  and.record every 5
                                        minutes.
                                SCT.pl e Box Mo.
                                          Condensate  +240 ml

                                          Ambient Temp °F	

                                          Bar.  Press.  "Hg	
         Taken along with MLE-7 Particulate
Location                       Test      f-tetar Box No.
                                                                          Assumed Moisture %
Dste
8-1-71
Probe Length
Operator
                                Prcba Heater Setting
Heater Box Setting, °F_

Probe Tip Dia., In.	




















c
*•
IX
•

1

Point
3 feet
from
edge








•












Clock
Tirr.s
1525
1535
1545
1555
1605
1615
1.625
1635
16'45
1655














Dry Gas
Keter, CF
374.96








453.71
78.75













Pi tot
in. HgO
A?















•








Orifice
in Hn
Desired














•




"




AH
0
Actual













.

f
-





.


Dry Gas
°F
Inlet



'




















Temp.
Outlet
80
82
86
90
92
86
86
86
86
86














Pump
Vacuum
In. Hg
Gouge
3.5
3.6
3.8
4.0
4.2
4.6
5.0
5.0
5.0
5.2




.._..









Box
Temp.
°F
























Impinger
Temp
°F
75 •
75
75
75
75
75
75
75
75
75




j







•

Stack
Press
in. He;
























Stack
T£"?
°F








i





\
I
h




i



-------
     Irt 10, p. 4 of 8
     PARTICUU,-E FIELD DATA
Plant    UC/RM  - Marietta
Run NO.  M1E-12  Metal


Location  Exhaust"
D£te    8-4-71
                                         VERY  IMPORTANT  -  FILL  IN.ALL  BLANKS

                                         Read  and  record at  the start  of  each
                                         test  point  or,  if single point
                                         sampling, read  and.record every  5
                                         minutes.
Sample Box No.

Meter Box No. •_

Probe Length
                                          Ambient Temp °F
Bar. Press. "Hg   29.5
Assumed Moisture %
Operator  Blessing
Probe Heater Setting   90
Heater Box Setting, °F    250

Probo Tip Oia., In.	-




















n
i

_

!

Point
























Clock
Tin:-
1411
1450






















Dry Gas
Kster, CF
573.87 '
619.82






















Pitot
in. H20
AP
























Orifice
in Hn
Desired
























AH
0
Actual
























Dry Gas
or
Inlet



.




















Temp.
Outlet
66
82









.












Pumo
Vacuum
In. Hg
Gouge
7.0
11.4






















Box
Temp.
L °F
























Ircpinger
Temp
°F

.'












• ;'









S* ""''
Press
in. l-ig

















•






Stack
Temp
°F








>




i
:

i






l

-------
                                RESOURCES RESEARCHt INC,
                                      Personnel  Avery & Baxley
                                                Entered,
                                                Checked
Plant Conditions, etcs  Metals Run
Plant        	     UC/RM - Marietta
                                   Date   8/5/71
Sample Location,
East Tap Exhaust
, Time
1015
1022 -Po
1027 -Po
1040
1054
1105
1115 '•
1120



1130
1140
1150
1200
1206





Sample
Number
ETE-1A
er Off
er On



ETE-1







Meter # GAS MHTER nONTiTTTOWS ftm,p #
Cu.Ft.
Reading
783.46
790.37
790.37
807.44
823.73
837.93
850.20
859.14



859.14
872.40
883 .80
900.30
908.51





Cu*Ft,(Vm)
Difference








FALSE '












ElapSv
Min.
0
7

13
14
11
10
5
'AP RUN


0
10
10
10
6





(Rm)
C.F.M.





















(-l460=TTa)
Temp °F
66
66
66
66
66
66
66
66



66
66
67
68
68





(Hn)
Vacuum"Hg
5.5
5.5
5.5
5.3
5.0
5.0
4.8
4.8



4.9
5.5
5.8
5.9
5.9






130
130

130



130



105
105
105
105
105





Thimble
Number



D-50



-------
                                RESOURCES RESEARCH.
                                      Personnel Avery & Baxley
                                                                         Entered_
                                                                         Checked
Plant Conditions, etc..   Metals Run
Plant   UC/RM - Marietta
                                                           Date
                                                                   8/5/71
Sample Location  East Tap Exhaust 2
( Time
1430
1440
1450
1500





,










Sample
Number
ETE-2



Meter # GAS METER CONDITIONS Putw #
Cu.Ft,
Reading
908.52
921.84
934.12
949.29
















Cu.Pt,(Vm)
Difference




















ElapSv
Min.
0
10
10
10








«







(Rm)
C.F.M.




















(4460=Tm)
Temp °F
75
75
74
74
















(Hn)
Vacuuming
5.3
5.3
5.3
5.2

















Stack
Temp.
105
105
105
105
















Thimble
Number


D-51


-------
                                RESOURCES RESEARCH>  INC,
                                      Personnel   Schroeder
              Entered,
              Checked
Plant Conditions, etc>   Metals  Runs
Plant.	   UC/RM -  Marietta '	
Date    8/5/71
Sample Location   West  Tapping Exhaust
f Time
1610
1640


















Sample
Number
WTE-3









Meter # ^ 	 ___ _ GAS METER CONDITIONS PunTO #-. „
Cu.Ft.
Reading
34.83
77.02


















Cu.Pt.(Vm)
Difference




















ElapSv
Min.




















(Rm)
C.F.M.




















(4460=Tm)
Temp °F
80
8.0



















-------
                                RESOURCES  RESEARCHt INC,
                                      Personnel  Gonzalez  & Baxley
              Entered
                                                                        Checked
Plant Conditions, etc-     SOo	




Plant	U/C - RM   -  Marietta
Date   7/27/71
Sample Location   S0? . - IE
, Time
1505
1515
1525
1535
1545
1555
1605
1615
1625
, 1635
1645
1655
1705
1715
1725


AVG.



Sample
Number
so2-i












Meter #_ ._ ^ GAS METER CONDTTTfWS ftmp *
Cu.Ft.
Reading
030.61













062.25


31.64



Cu.Ft.(Vm)
Difference





















Elapss
Min.

10
10
10
10
10
10
10
10
10
10
10
10
10
10


140



(Rm)
C.F.K.





















(+460=Tra)
Temp °F
78
78
78
76
76
76
76
74
74
74
72
72
72
72
72


75



(Hn)
Vacuum"Ife
5.5
5.5
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0


5.0



Imp.
Temp.
70 As




















Thimble
Number
umed




D-53

-------
                                RESOURCES RESEARCH^ INC,
                                      Personnel  Gonzalez & Baxley
              Entered,
              Checked
Plant Conditions, etcs '    S03
Plant     '   UC/RM  -  Marietta
Date   7/29/71
Sample Location	Exhaust   SO -2E
sJEias— -
1015
1025
1035
1045
1055
1105
1115
1125
1135
1145
1155
1205
1215


AVG.





Sample
Number












Meter #_
Gu.Ft,
Reading
65.30
66.00


68.00







72.28


6.98

Power v



	 GAS MFTR* rnimrrTfWS P,,v*?#
Cu.Ft.(Vm)
Difference

















ent off and



Elapss
Min.
-
10
10
10
10
10
10
10
10
10
10
10
10




n 3 time



(RnO
C.F.M.

















during



(+460=Tm)
Temp °F
66
66
66
66
68
68
70
70
70
70
70
70
70


68

his test.



<»n)
Vacuum"H£
2.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0
3.0


2.9




























Thimble
Number



D- 54

-------
                                RESOURCES RESEARCH> INC,
                                      Personnel  Gonzalez & Baxley
                                         Entered
                                                                         Checked
Plant Conditions3 etc..	




Plant	UC/RM..-.Marietta.
SO.
                           Date
7/30/71
Sample Location    MlE-3 Exhaust
                             S02-3E
r Time
1815
1825
1835
1845
1855
1905
1915
1925 .
1935
,1945


AVG.








Sample
Number
MlE-3






Meter # GAS METEP rnrmTTTft^fi *,11W #.
Cu.Ft.
Reading
072.28








82.60











Cu.Pt.(Vm)
Difference





















Elapss
Min.
_
10
10
10
10
10
10
10
10
10


90








(Rm)
C.F.M.





















(+460=Tm)
Temp °F
64
64
64
66
66
66
66
66
66
66











(Rn)
Vacuum"!fe
3.2
3.2
3.0
3.0
3.5
3.5
3.0
3.5
4.0
4.0











Imp.
Temp .
60 As
60
60
60
60
60
60
60
60
60


60








Thimble
Number
sumed

-
D>55

-------
                                RESOURCES RESEARCH..  INC,
                                      Personnel  Gonzalez
                                                  Entered,
                                                  Checked
Plant Conditions, etc- '
Plant          UC/RM - Marietta
                                    Date
                                            7-31-71
Sample Location
M1E-4    S02 - 4E
r Time
0940
0950
1000
1010
1020
. 1030
1040
}.050
1100
, 1110
1120
1130
1140







Sample
Number
M1E-4
S02



Meter # GAS METER CONDTTT^NS Pimp # ,
Cu.Pt.
Reading
082.95











093.95
11:00






Cu,Ft.(Vm)
Difference




















Elaps..
Min.

10
10
10
10
10
10
10
10
10
10
.10
10
120






(Rm)
C.F.M.







-












(+460=Tra)
Temp °F
70
70
72
74
76
76
76
76
78
78
80
80
80







(Rn)
Vacuum"Pfe
3.0
3.0
3.2
3.2
3.2
3.2
3.4
4.0
4.0
4.0
4.2
4.2
4.2







IMP.
60
60


















Thimble
Number


D-56

-------
                                RESOURCES RESEARCH^ INC,.

                                      Personnel     Gonzalez
                                                 Entered,
                                                 Checked
Plant Conditions, etCs     S02
Plant UC/RM  ~ Marietta
                                   Date  7-31-71
Sample Location
S02 - E5
                                    M1E-5
. Time
1440
1450
1500
1510
1520
1530
1540
1550
1600
. 1610
1620
1630










Sample
Number
ttE-5
so2








Water # GAS METER CONDITIONS Purrm *
Cu.Pt.
Reading
275.29










284.91

9.62







Cu.Ft.(Vm)
Difference





















ElspSs
Min.

10
10
10
10
10
10
10
10
10
10
10

110
t






(Rm)
C.F.M.





















(+460=Tra)
Temp °F
86
86
86
88
88
88
90
90
90
88
88
88

88







(Bn)
Vacuum"HK
3.0
3.0
3.0
2.8
2.8
2.8
3.0
3.0
3.0
3.0
3.0
3.0

3.0








IMP
70




















Thimble
Number


D-57

-------
                                RESOURCES RESEARCH„ INC,
                                      Personnel
                              Schroeder
                                                    Entered_
                                                    Checked
Plant Conditions, etCn__
Plant   UC/RM Exhaust
                                      Date
8-2-71
Sample Location,
M1E -8  SC-2
, Time
0920
0940
1010
1030
1050
1110



.










Sample
Number
M1E-8
so2






Meter # _ GAS METER CONDITIONS Pump #_ ~.
CuJPt.
Reading
458.10




465.07














Cu.Pt.(Vm)
Difference




















Elaps s
Min.













.






(Rm)
C.F.M.




















(-f460=Ttn)
Temp °F
70
75
79
82
84
84














(Bn)
VacuuuinHg
2.0
2.8
2.8
2.2
2.2
2.0




































Thimble
Number




D-58
-

-------
Plant Conditions,
Plant.  UC/RM  - Marietta
                                RESOURCES RESEARCH^ INC,
                                      Personnel
                       Schroeder
                                            Entered.
                                            Checked
SO?
                              Date   8-2-71
Sample Location   Exhaust    M1E-9  S02
^ Time
1730
1805
1850
1917
1942
1952



,










Sample
Number












Meter # GAS METER CONDITIONS Pv«r #-
Cu.Ft,
Reading
466.08
473.61
479.57
482.96
488.84
490.78














Cu.Ft.(Vm)
Difference




















Elapsv
Min.












t







(Km)
C.F.M.




















(-»460=Tta)
Temp °F
78
79
84
82
82
80














(Rn)
Vacuum"Hg
1.6
1.6
1.5
1.0
1.0
0.8














— —




















Thimble
Number


D-59

-------
RESOURCES RESEARCH,. INC,
Plant Conditions,
Plant UC/RM -
Sample Location
' Personnel Blessing
etc. S02
Marietta Date
M1E-10 S02
Entered
Checked

8-3-71

. Time
0957
1025
1055
1130
















Sample
Number





Meter # GAS METER CONDITIONS Pump #-
Cu.Ft,
Reading_
497.91
499.92
501.00
501.60
















Cu,Ft.(Vm)
Difference




















Elapsv
Min.












, .







(Rm)
C.F.M.




















(+460=Tra)
Temp °F
66
68
69
68
















(Hn)
VacuumnHe
2.6
2.4
2.2
2.0






































Thimble
Number



Dff\
-ou

-------
                                RESOURCES RESEARCH> INC,
                                      Personnel    Schroeder & Avery
                                                     Entered.
                                                     Checked
Plant Conditions, etc..   SO? Field Data
Plant   	UC/RM - j-iarie'tta	
                                       Date   8/5/71
Sample Location_
Tapping Exhausts
f Time
1128
1140
1207

1430
1500


1607
1620
1630
1635









Sample
Number
WTE-1

WTE-2

ETE-3






Meter # GAS METER nOTTOTTTONS T^y, #. r
Cu.Ft,
JReading__
28.40
30.50
32.35

32.38
34.83


962.77
963.16
963.55
963.77









Cu.Ft.(Vm)
Difference





















ElapSv
Min.





















(Rm)
C.P.Mv





















(-f460=Tn>)
Temp °P
73
76
77

78
79


75
75
75
75









(Bn)
Vacuu-m"Hg
3.0
2.5
2.0

2.5
2.5


1.0
1.0
1.2
1.2









Pb
29.60
29.60
29.60

29.60
29.60


29.60
29.60
29.60
29.60









Thimble
Number



-
D-.61



-------
Part lu, p. 7 of 8
                                    ORSAT FIELD DATA
            Location_    MIE-I
            Date	
            Time
7/27/71
With Particulate
            Operator    Gonzalez
                               Comments:
Test
M1E-IA
MlE-lB
AVG.
•




(co2)
Reading 1
2.1
2.1
2.1 . .


«


(02)
Reading 2
19.2
19.3
19.2





(CO)
Reading 3
Nil • •
Nil'
Nil





 NCAP-31  (12/G7)
                                                                        D- 62

-------
                                    ORSAT FIELD DATA
            Location^    MiE-2
            Date
            Time
7/29/71
With Particulate
            Operator    Gonzalez
                                Comments:
Test
M1E-2A
MIE-2B
MIE-2C
AVG.




(co2)
Reading 1
3.2
3.6
3.6
3.4

«


(02)
Reading 2
18.4
18.2
18.2
18.3




(CO)
Reading 3
Nil
Nil
Nil
Nil




NCL'\P-31  (12/07)
                                                                           D-63

-------
                                    ORSAT FIELD DATA
            Location	MiE-3
            Date	
            Time
7/30/71
With Particulate
           Operator   Gonzalez
                                Comments:
Test
- M1E-3A
M1E-3B
AVG.






(co2)
Reading 1
1.9
1.9
1.9


#



(o2)
Reading 2
18.6
. 18.6
18.6

•




(CO)
Reading 3
Nil ' "
Nil
Nil






NCAP-31  (12/67)
                                                   D- 64

-------
Part 10, p. 7 of 8
                                    ORSAT FIELD DATA
            Location   Exhaust  M1E-4
            Date	   7/31/71
            Time
With Particulate
            Operator   Gonzalez
                                Comments:
Test
M1E-4A
M1E-4B
AVG.
•





(co2)
Reading 1
2.8
2.8
2.8
•

4


•
(o2)
Reading 2
18.8
18.8
18.8






(CO)
Reading 3
Nil
Nil
Nil






 NCAP-31  (1P./G7)
                                                    D-65

-------
Part 10, p. 7 of 8
                                    ORSAT FIELD DATA
            Location  Exhaust    M1E-5
            Date   7-31-71
            Time  With Particulate
            Operator Gonzalez
Comments:
Test
M1E- 5A
- 5B






(co2)
Reading 1
3.2
3.4
3.3





(02)
Reading 2
18.5
18.3
18.4





(CO)
Reading 3
Nil
it
it





NCAP-31  (12/67)
                                                                          D-66

-------
Part 10, p. 7 of 8
                                    ORSAT FIELD DATA
            Location_
            Date	
            Time
    M1E- 7
    8-1-71
With Partic.ulate
            Operator    Gonzalez
Comments:
Test
M1E - 7A
- 7B
AVG.






(co2)
Reading 1
3.0 .
3.0
3.0






(o2)
Reading 2
18.6
18.6
1.8.6,

.




(CO)
Reading 3
Nil
Nil
Nil






NC<\P-3)  (12/67)
                                                                           D-67

-------
Part 10, p. 7 of 8
                                    ORSAT FIELD DATA
            Locatlon  UP/KM - Marietta

            Date_

            Time
Scrubber Exhaust
8-2-71	
                     D945 - 1100.
            Operator  Schroeder
                                 Comments:
Test
M1E- 8
-

-




(co2)
Reading 1
3.2
3.2
3.2

*



(o2)
Reading 2
21.7
21.8
2.1.8





(CO)
Reading 3
Negligible
ti
ii





 NCAP-31  (12/07)
                                                 D-68

-------
Part 10, p. 7 of 8
                                    ORSAT FIELD DATA
            Location  Scrubber Exhaust
            Date   8-2-71
            Time
6.15 - 8:15
            Operator   Schroeder
                                    Comments;
Test
M1E- 9 A
-9B
Avg.






(co2)
Reading 1
3.4 .
3.4
3.4






(02)
Reading 2
18.5
18.5
18.5






(CO)
Reading 3
Negligible
ii
ti






NCAP-31  (12/07)
                                                                       D-69

-------
Part 10, p. 7 of 8
                                    ORSAT FIELD DATA
            Location  Scrubber Exhaust
            Date
UC/RM - Marietta
 8-3-71
            Time    1010-1110
            Operator   Blessing
                                 Comments:
Test
M1E-10-A
-B
AVG.





(co2)
Reading 1
3.2 -
3.2
3.2

. • .



(o2)
Reading 2
22.0
22. '0
22.0

•



(CO)
Reading 3
w
•>
Nil





Nd\P-31  (12/G7)
                                                                        D-70

-------
Part 10, p. 7 of 8
                                    ORSAT FIELD DATA
            Location   Exhaust  M1E-11
            Date     8-3-71
            Time     1400 - 1530
            Operator   Blessing  and Avery
Comments:
Test
M1E-11A
•B
AVG.






(co2)
Reading 1
3.2
3.2
3.2






(o2)
Reading 2
18.6
18.6
18.6






(CO)
Reading 3
-
-
Nil






NCL'\P-31  (12/67)
                D-71

-------
Part 10, p. 7 of 8
                                    ORSAT FIELD DATA
            Location     Scrubber Exhaust



            Date	8/4/71	



            Time
With?articulate
            Operator   Gonzalez
                                 Comments:
Test
M1E - 12







(co2)
Reading 1
3.1



, ' *



(02)
Reading 2
18.7
'


- .



(CO)
Reading 3
Nil

•





NCAP-31  (12/G7)
                                                                           D- 72

-------
Part 10, p.  7 of 8
                                   ORSAT FIELD DATA
Location WTE-I Comments:
Date 8/5/71
Time With Particular^
Operator Schroeder .

Test
WTE-1







(C02)
Reading 1
0.2







(o2)
Reading 2
21.2







... ..
(CO)
Reading 3
Nil ' '







 NOVP-31  (12/67)
                                                                        D-73

-------
Part 10, p. 7 of 8
                                    ORSAT FIELD DATA
            Location   WTE-Z
            Date	
            Time
8/5/71
With Particulate
            Operator    Schroeder
                                Comments:
Test
WTE-2


-




(co2)
Reading 1
0.1

. .

.



(o2)
Reading 2
20.9







(CO)
Reading 3
Nil •,• '







NC/VP-31  (12/G7)
                                                                         D-74

-------
Part 10, p. 7 of 8
                                    ORSAT FIELD DATA
            Location    WTE-3
            Date  -   8-5-71
            Time     During particulate
            Operator   Schroeder
Comments:
Test
WTE-3A
-3B
AVG






(co2)
Reading 1
0.1
0.1
0.1 .






(o2)
Reading 2
21.2
21.2
21.2






(CO)
Reading 3
Nil
Nil
Nil






Nd\P~31  (12/67)
                                                                         D-75

-------
        APPENDIX E
STANDARD SAMPLING PROCEDURES

-------
                               APPENDIX E-l




                        STANDARD  SAMPLING  PROCEDURES






 PARTICULATE  SAMPLING




     With an unstable plant  operation  a trial  run is often conducted.  If




 the  trial turns  out to be satisfactory it may  be considered a part of the




 final  testing.   Preliminary  data is  obtained for gas velocity, temperature,




 moisture  content and  other variables which might affect the isokinetic




 sampling  rate.   Each  sample  port traverse is divided into a number of




 equal  areas  for  each  location.   Each test run  is designed to obtain simul-




 taneous samples  at each location,  for  such a period of time that plant




 operation will be representative,  and  that sufficient material will have




 been obtained for accurate analysis.






     Particulate samples are obtained  using the equipment and test




 procedures as stipulated in  "Sample  Collection Procedures," published




 by GAP.   The sampling train  is basically  the same as that designed




.by the Control Development Program of  CAP (formerly the Air Pollution




 Control Office),  "Gas Stack  Sampling Improved  and Simplified with




 New  Equipment,"  and described in Paper No. 67-119, presented at the




 Air  Pollution Control Association meeting at Cleveland, Ohio, in June,




 1967.






     The  above sample equipment  is referred to in this report as the




 EPA  train.   It is essentially the same as that recently described in




 Federal Register, Volume 36,  Number  159,  August 17, 1971, Part II as




 Test Method  5.   Its operation, briefly, is as  follows:
                                                                            l-l

-------
determined by using the nomographs presented in APCA Paper No. 67-119.




This nomograph relates stack gas velocity, temperature, and moisture




content to the flow rate required for isokinetic sampling.






     The ASME train, run in parallel with the EPA train, consists of a




stainless steel filter holder containing a pre-weighed alundum filter.




Its operation, briefly, is as follows:




     Sample gases are drawn through a stainless steel nozzle and filter




holder, placed within the stack, into a set of water filled Greenburg-




Smith impingers.  Isokinetic sampling rates are not determined during




the test but are precalculated from initial pitot and temperature




readings.  Only the material collected by the alundum filter is normally



considered as particulate.  No ASME train was employed during this survey.







SULFUR DIOXIDE SAMPLING




     Sulfur dioxide emission tests are normally conducted at the same




location as the exhaust particulate tests.  Sample gas is drawn through




a glass wool filter into an electrically heated glass probe, followed




by a coarse frit midget impinger and a second glass wool filter.  The




filter leads to three midget impingers in an ice bath, followed in turn




by a silica gel tube drier, vacuum gauge, dry gas meter and vacuum pump.






     The midget bubbler contains 15 milliliters of 80 percent isopropyl




alcohol.  The first two impingers contain 15 milliliters of three percent




hydrogen peroxide solution and the third is operated dry.  Equipment is




leak tested before each run.  The three percent hydrogen peroxide is




prepared the day of the test by dilluting 10 milliliters of 30 percent




reagent grade hydrogen peroxide with 90 milliliters of distilled water.

-------
     Temperatures, vacuum and gas meter readings are taken and tabulated

in order to calculate standard volumes.  After sampling,  the train is

purged with clean air in order to carry over any SO. trapped in the

isopropyl alcohol.                     ,


NITROGEN OXIDES SAMPLING

     Nitrogen oxides sampling is normally carried out at the same exhaust

location as the sulfur dioxide and particulate tests.  The sample gas is

pulled through a glass wool filter and a glass probe into an evacuated

two-liter flask containing dilute sulfuric acid-hydrogen peroxide solution.

This is prepared according to EPA directions for nitrogen oxides sampling.

The flask is fitted with a three-way stopcock and a pump is employed to

evacuate the flask and purge the probe lines.  Vacuum present in the flask

is measured by a vacuum gauge and the sampling train is leak tested by

pulling a vacuum of 27 inches Hg and observing the pressure gauge.  Initial

and final.readings of pressure, flask temperature and atmospheric pressure

are recorded after the probe is purged. After collecting the sample the

flask is sealed and shaken for 5 minutes, then allowed to stand overnight,

before being washed into sample containers for transfer to the laboratory.


ORSAT SAMPLING
                                      •
     An integrated gas sample is obtained with a mylar bag and a peristaltic

pump with adjustable flow rate.  The gases are filtered and cooled prior to

reaching an all plastic and glass flow meter where the sampling rate is

monitored.   Gas samples are taken during the same period during which veloc-

ities, temperatures, and particulate samples are obtained.  Analyses are per-

formed at the site immediately after each sample is collected.
                                                                     E-4

-------
                               APPENDIX E.2




                    CLEANUP AND ANALYTICAL PROCEDURES







CLEANUP (EPA PARTICULATE TRAIN)




Probe, Nozzle, Cyclone, and Front Half of Filter Holder




     The nozzle, probe, cyclone, flask, and front half of the filter




holder are washed with reagent grade acetone, the washings collected




in a container and transported to the laboratory for analysis.  A




brush and/or rubber policeman is used with the acetone to remove any




particles adhering to the cyclone walls or the flask.  The reagent




acetone used for washing is tested to determine the blank or residue




upon evaporation.







Filter




     The tared circular MSA type 1106BH filter paper is carefully




removed from the fritted glass support and transferred to a glass




petri dish for later weighing.







Impingers




     Water in the first three impingers (the original water plus the .




condensate) is measured, then emptied into a polyethylene container.




The impingers are then water washed and the washings combined with the




condensate and original water.







Acetone Train Wash




     The rear half of the filter holder, including the fritted glass




support, the impingers, and impinger connections up to but excluding the
                                                                           E-5

-------
fourth impinger, are washed with acetone.  These washings are collected




in a polyethylene  (since changed to glass) bottle and sealed for later




analysis.




Silica Gel




     Silica gel is transferred (dry) from the fourth impinger to an air-




tight container and sealed.  The impinger is then washed with acetone,  the




acetone being discarded because it contains fine silica gel particles.






CLEANUP (S02 TRAIN)




     The impinger containing 80 percent isopropyl alcohol is discarded and




the impingers containing three percent hydrogen peroxide are saved.  These




latter impingers contain SC^ gas in the form of H^SO^.  A glass jar is used




as a sample container for transportation to the laboratory.






CLEANUP (NOX TRAIN)




     After storage overnight and shaking for another two minutes the con-




tents are rinsed into glass containers for shipment to the laboratory.






ANALYTICAL PROCEDURES (EPA PARTICULATE TRAIN)






Acetone Washings




     The acetone washings from the nozzle, probe, cyclone, flask, and filter




front; from the fritted glass, filter back and impinger train; are analyzed




separately by evaporation and drying at .ambient temperatures.






Filter Particulate




     The filter and particulate collected thereon are dried for 24 hours in




a desiccator at ambient temperature and weighed.  Tare weight of the filter




is then deducted.
                                                                           E-6

-------
Impinger Water

     Water collected in the impingers,  along with the water washings  of the

impingers, is extracted with ether and  chloroform.   The extracts  are  trans-

ferred to a tared dish and evaporated to dryness at room temperature.   After

extraction, the remaining water and solvent are evaporated to dryness on a

steam bath and this additional net weight is added to the total weight of

participate matter.


SPECIAL NOTE

     All samples are now dried in 250 ml beakers to a constant weight.


ANALYSIS (ORSAT MEASUREMENTS)

     Orsat measurements for determination of carbon dioxide, oxygen and

carbon monoxide are made using a Burrell Industrial Gas Analyzer  or

equivalent.                        -


ANALYSIS (S02 TRAIN)

     S02 samples are analyzed by the modified Shell Development method.

Barium perchlorate is used instead of barium chloride (as in the  new EPA

source testing Method 6) because of the sharper titration end point obtain-

able with the former reagent.

                                   »
ANALYSIS (NOV TRAIN)

     Samples are analyzed by the standard phenoldisulfonic acid method.

This is now incorporated in the new EPA source testing Method 7.
                                                                           E-7

-------
   APPENDIX F
LABORATORY REPORT

-------
.SAMPLES
                                                        tfc t
          V/£   - g, jj.
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                                                                  I ^ ?/
                                                                             F-l

-------
j5AMH£S
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-------
SAMPLES
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                                      Analysis Date _ ^
                                                                             F-3

-------
SAMPLES
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                                          Collection  Date_

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                                                                                  F-4

-------
                                                          £, F.
SMILES
U/t   - £.
 Project Ko.
                                     Collection Date  7/27  -




                                     Analysis Date 	
                                                                            F-5

-------
SAMPLES
OJG.   -A.M.       tita^M
Project No.
                                      Collection Date




                                      Analysis Date
                                                                              F-6

-------
                                                              G,
                                                                                   To
Project Koe
Collection Date   7/27   -




Analysts Date
                                                                                F-7

-------
SAMPLES
           u/e
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                                                            7/?7 -
                                            Analysis Date
                                                 ' 157
                                                                7/
                                                                          F-8

-------
SAHPIES
                                                             AC


80.
       LOCATION  imd
         SAMPUS KO.
                   SAIiPIZ
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                                Collection Date_

                                Analysis Date ___
                                                                            F-9

-------
SAMPLES
NO.
       LOCATION  and
               NO.
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                             WEIGHT
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ALIQ.
KG iri
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-------
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-------
SAHPIES
                                                                                       cot.
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Collection Cat e_




Analysis Date ,__
                                                                       7  -
                                                                                  F-12

-------
SAMPLES
                                                                                      *  *
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NO.
        LOCATION  and
          SAMPI£ NO.
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                                                                                  F-13

-------
                                                             lit. wfl t v £> £
SAMPLES
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                                                                                 F-14

-------
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-------
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-------
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                                                                                  F-17

-------
SAMFIES
         ole   -  rt.&t.
Project No.
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                                                                        F-18

-------
SAMPLES
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-------
                                            So.
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                    - * A~ .

            Analysis Date ^_
                                                                    /
                                                                      T-20

-------
SAMPLES
                                                                                 •  (,
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                                         Analysis Date __
                                                                         -21   /
                                                                                P-21

-------
APPENDIX G
 TEST LOG

-------
                                                 APPENDIX G  - TEST LOG
Date(197iy
7/27
7/29
7/30 ***
7/31
8/1
8/2
8/3
8/4
8/5
Location Sample No.
Exhaust M1E-1
Inlet MID-1
Exhaust M1E-2
Inlet MID -2
Exhaust MlE-3
Inlet MID-3
Exhaust M1E-4, 5
Inlet MID-4,5
Exhaust MlE-6,7
Inlet ' . MID-6,7
Exhaust . MlE-8,9
Inlet MID-8,9
Exhaust MlE-10,11
Inlet MID-10,11
Exhaust M1E-12
Inlet MID-12
East Tapping Exh. ETE-1,2,3
West Tapping Exh. WTE-1,2,3
Note: All tests except particle sizing follow
* : Filter
** : Meter
*** : Plant
and pulley problems.
box failure. Sampling interrupted
Particulate Orsat S02 Metal Particle Size
X
*
X
*
X
*
XX
XX
**x
XX
XX
XX
XX
XX
X
X
XXX
XXX
the order

shortly
operation at one -half load. Exhaust tests
X X
xx-
X X
XX XX XX
**X XX X
X
XX XX X
--..--• -- '. XXX
xx x Lost xx
'-- -- -- xxxxx
X X XXXX
	 — x xx- xx on 8/4
xxx xx- --x xx on 8/4
of each sample number, as shown. On 7/28 plant was down

after started.
conducted anyway.
o

-------
  APPENDIX H
RELATED REPORTS

-------
     Related reports covering emissions from reactive metals  furnaces,

under this same contract for the Environmental Protection Agency,  are

as follows:
                                            Emission
Test Number  	Survey Location	   Control Device   	Status	

  FA-1       Foote Mineral Co.,              None         Issued Aug.,1971
             Steubenville, Ohio

  FA-2       Union Carbide Corp.,       Venturi Scrubber  This Report
             Marietta, Ohio

  FA-3       Airco Alloys and Carbide,  Baghouse          Issued Oct.,1971
             Niagara Falls, N.Y.

  FA-4       Airco,                     Electrostatic     In Progress
             Charleston, S.C.           Precipitator

  FA-5                                                    Future

                                                          Future
                                                                           H-l

-------
          APPENDIX I







PROJECT PARTICIPANTS AND TITLES

-------
 PROJECT PARTICIPANTS AND TITLES
R. N. Allen, P.E., Project Leader

N. A. Blessing,    Chemist

C. C. Gonzalez,    Chemist

W. E. Schroeder,   Chemist

J. R. Avery,       Technician

L. W. Baxley,      Technician

W. C. Hall,        Technician

G. Hogan, M.S., (Particle Size Determination)

G. Patchell, Senior Technician,
             (Particle Size Determination)

T. J. Wright, PhD., (Particle Size Determination)
                                                  1-1

-------
      APPENDIX J
PARTICLE SIZING SAMPLES

-------
                 PARTICLE  SIZE  DISTRIBUTION  OF METAL FUME









                               INTRODUCTION









      Determinations  of  particle  size  distribution  of  fume  emissions




 at  the  Ferroalloy Division  Plant of Union Carbide, in Marietta, Ohio,




 were  conducted  from  July  27 through August  4, 1971.   Emissions  from




 the No.  1  furnace were  evaluated at the  following  points:   in the




 furnace  hood  exhaust duct prior  to emission control,  in the exhaust




 stack after emission control,  and in  the two stacks from the tap




 exhaust  hood.







                                  METHODS






      A  Brink  cascade impactor  was employed  to obtain  data  on size  dis-




 tribution  in  this study.  Two  samples were  collected  using the




'Andersen Stack  Sampler  but  90  percent of the particles gathered on the




 filter  and not  enough data  points were available  to provide the desired




 information.  As a result the  Andersen Stack Sampler  was discarded in




 favor of the  Brink cascade  impactor.






      The Brink  impactor,  followed by  a 47 millimeter  glass fiber filter,




 was mounted on  a probe  and  connected  to  a vacuum  pump by a length  of




 rubber  tubing.   The  inlet side of the pump  was  fitted with a vacuum gauge,




 calibrated in inches of mercury, and  a flow controlling valve.  The outlet




 side  of the pump was connected to a dry  gas meter  whenever samples were




 collected  for periods longer than two minutes.
                                                                   J- 1

-------
     Prior to collecting samples in the field, the impactor was calibrated


to determine air flow rates at various operating conditions.  Rates were


determined by assembling the particle sizing train as shown in Figure 1.


Air was drawn through the impactor for 10 minutes at each pressure drop


(A?) of five inches of Hg, seven inches of Hg, and 10 inches of Hg.  The


corresponding volume of air flow for each sample was measured by the dry


gas meter.  A calibration curve was constructed by plotting the pressure

drop across the impactor versus the air flow rate.



     Volumetric flow rates for the short duration samples, of one and two


minutes, were measured by the A? across the impactor.  For samples of


longer duration than two minutes, volume was measured by a dry gas meter.


A AP of five inches of Hg was maintained during all sampling.  The


impactor was grounded, either to the stack or building, to prevent electro-


static deposition of particles.



     As high temperatures were encountered, in the furnace hood exhaust


duct, the plugged impactor was inserted into the duct for at least five


minutes, to allow time for thermal equilibrium.  The impactor was then


removed from the duct, the plug removed, and reinserted into the duct for


sample collection.  Samples were collected from each of the five ports on

                                      *
the upper surface of the duct, at a depth of 24 inches into the duct.


Difficulties were experienced in collecting these samples due to the dense


concentration of the particles in that duct.  Samples were first collected


for 10 minutes, but these were not satisfactory because too many particles


deposited on the collection plates.  Sampling time was then reduced to


five minutes with the results being the same.
                                                                     J-2

-------
      A dilution air  apparatus was  placed  in  series with  the Brink impactor

 to dilute  the  particles  before  they  entered  the  first  stage.  This process

 also proved unsatisfactory  because the  extreme temperatures in  the duct

 (up to 1300 F)  melted  the silver soldered joints  of  the  dilution air

 apparatus  as well  as oxidizing  the inner  surfaces of the unit.  Finally,

 the sampling time  was  reduced to one and  two minutes without dilution,

 and this procedure was found  to be satisfactory.


      In order  to prevent condensation,  with  the  high moisture content of

 the furnace exhaust  gases,  following passage through the venturi

 scrubber/cyclone control device, it  was necessary to preheat the impactor

 and filter holder  to a temperature above  the dew point.  This was

 accomplished by wrapping the  entire  impactor and filter  holder  assembly

 with electrical heating tape, insulated with asbestos  tape and  aluminum

 foil.  The tape was  plugged into a 120  volt  AC line  and  allowed to heat

• the sampling device  for  at  least 15  minutes  prior to sampling.


      Exhaust emission  samples were collected from a  3  inch port approxi-

 mately 70  feet above ground level, and  36 inches into  the stack, for

 periods of 30  to 55  minutes.  At least  two samples were  taken at pressure

 drops of 37 inches of  water,  47 inches  of water,  and 57  inches  of water
                                     •             .
 across the venturi scrubbers.
                                                                        J-3

-------
     Simultaneous samples were collected for 20 minutes, in each of the




two tap hood exhaust stacks, during furnace tapping.  These samples were




collected at ports located on the fourth floor of the furnace building,




at a distance of 30 inches into the stacks.







                                 RESULTS







     Graphical results are shown in Sub Appendix 1 and the field data




sheets are included in Sub Appendix 2.  The characteristic diameter of




an aerosol particle for each impactor stage (Dpc) has been calculated




for a pressure drop across the impactor of five inches of mercury,




assuming particles of unit density (1 gram/cubic centimeter), using the




equation described by * J. A. Brink,  Jr.  The characteristic diameters




are as follows:




                    Stage No.          Dpc, microns
1
2
3
4
5
3.40
2.00
1.36
0.69
0.42
     Graphical presentation of the data, that is, log-probability plots




of cumulative percent less than stated micron size versus the Dpc for each




stage in microns, is shown for each sample in the following section.  A




graphically determined mass median diameter (HMD) and geometric standard




deviation ( 0- g) for each sample are presented in the following Table A.






* Industrial Engineering and Chemistry, Vol..50, April 1958, pp 645-648.







                                                                     J-4

-------
                                                 TABLE A


Date

7/31/71
7/31/71

8/1/71
8/3/71
8/3/71
8/2/71

8/4/71
8/4/71
8/4/71
8/4/71

Sample
Number

A
C

E
N
P
H

DD
U
W
AA

Location of Port
Sample Number

Exhaust Stack
it

n
it
ii
n

n
"
ii
it
Duration of
Sampling
(Min.)

10 '
30

34
45
50
30

50
55
45
55
AP Across
Venturi Scrubber HMD
(in.H^O) microns
2 - - .. .
57 0.325
" 0.21

" « 0.42*
11 «0.42*
" 0.68
47 0.34

" 0.31
37 0.57
0.44
" 0.60

6~ g
microns

3.85
2.19

*
*
1.80
3.59

3.06
2.41
2.78
2.27


Remarks


Furnace
sample



Furnace
sample









tapped during
collection



tapped during
collection




8/2/71
8/2/71
8/2/71
8/1/71
8/3/71
8/3/71
8/3/71
8/3/71
8/4/71
8/4/71
8/4/71
8/4/71
I
J
L
D
U
0
R
S
X
EE
Y
ZZ
              Inlet Duct
              Tapping Ducts
                    Jl
                    II
1
1
2
3
3
4
5
5

East

West
 1
 1
 1
 2
 2
 2
 2
 2


20
20
20
20
47
it
ti
                                                         37
                                                         57
57
0.82
0.56
5.4
3.4*
0.9
0.79
2.35
0.60
1.75
0.86
2.50
0.83
2.23
2.63
4.50
*
2.14
3.80
1.45
1.25
3.60
3.90
4.28
3.86
Data points are at the extremities of the graphs, either less than 15%, or greater than 85% of
stated size.  Reliable particle sizes could therefore not be determined from this data.

-------
        SUB-APPENDIX J-l
GRAPHICAL PRESENTATION OF RESULTS
                                                       J-6

-------
              PARTICLE SIZE SAMPLES
EXHAUST STACK
INLET DUCT
Sample
A P = 57" H^O Number
/
A
C
E
N
P
AP = 47" H^O H
DD
A P - 37" H.O U
j i . 2
W
AA
TAPPING
Sample
East • Number
; X
EE
West Y
Z
Date
Time
Sampled
7/31 1340-1350
7/31 1720-1750
8/1 0303-0837
8/3 0755-0840
8/3 1709-1759
8/2 2025-2055
8/4 1857-1947
8/4 0740-0835
8/4 0847-0932
8/4 1621-1706
EXHAUSTS
Date
8/4
8/4
8/4
8/4
Time
Sampled
1642-1702
2010-2030
1641-1701
2010-2030

10
30
34
45
50
30
50
55
45
45

20
20
20
20
Time
min.
•->.
min.
min.
min.
min.
min.
min.
min.
min.
min.
Time
min.
min.
min.
min.
Sample
Port #1 Number
I
J
Port #2 L
Port #3 D
T
U
Port #4 0
Port #5 R
S
Date
8/2
8/2
8/2
8/1
8/3
8/3
8/3
8/3
8/3
Time
Sampled
1105-1106
1108-1109
1852-1353
1720-1722
1945-1947
1950-1952
1410-1412
1738-1740
1742-1744
Time
1 min.
1 min.
1 min.
2 min.
2 rnin.
2 min.
2 min.
2 min.
2 min.
                                                            J-7

-------

-------
  PERCENTAGE

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2%
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STAGE
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-------
SUB-APPENDIX J-2
   FIELD DATA
                                      J-30

-------
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                                       o.  1       (6, a          6^3
                                                                         J-50




                                                                               ~  -t

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                   	                                       Date
          Stack No.  '
          Sample
OcWv-«V
           1
   <•
        filter
                                                                      Cum. %
             e     Post Wt.    Pre Wt.      Wt Gain       %        less than Doc
           2     -3.^3-1    -7'*i->l       0.  a.	H.-5           7 |   3


                                    d       O.f-          "7,1           /
           	o.\           l.l           36.7
l.34i
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Stack No.

Sample No.



STAGE
POST. WT.     PRE. WT.     WT.
                                                       Date
                                                               CUM.  #
                                                            LESS  THEN Dpc
3
                        /i,S S 1 3
                             O.
                        . G  o 1o
7
8
Filter
                                                  ID- 2-

                                                                      J-52

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          T      L  &J>Jh
       >.   >^P Q^f\^eL^y- t-'        LESS THEN Dpc
             U27V
            rfr^fe
                                                                 7
               >?>
                                        o,
  8    f.
Filter  -J t^*1          .| U
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           APPENDIX K
CHEMICAL ANALYSIS OF EMISSIONS

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                       PREFACE
     The following report, covering chemical analysis




of emissions from reactive metal smelting operations




at Marietta, Ohio, has been prepared by the technical




staff of TRW Systems Group, One Space Park, Redondo Beach,




California.
                     Principal Contributors:  D. F.  Carroll




                                              M. L.  Kraft




                                              W. B.  Hewitt









                     Approved By:             J. R.  Ogren
                                                                 K-l

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                     CHEMICAL ANALYSIS OF EMISSIONS




                                  FROM




                   REACTIVE METAL SMELTING OPERATIONS
1.    INTRODUCTION




     Particulate fumes and gaseous emissions are generated during the




smelting and pouring of a commercially important class of ferro alloy




materials called reactive metals.  The particulate portion of these




emissions has been collected on glass fiber filters, strategically




placed in the air stream of an exhaust system.  Six such filters from




the Union Carbide Corporation (Marietta, Ohio) were analyzed micro-




scopically, by qualitative electron beam X-ray microanalysis, and




atomic absorption.  The analytical results are presented in the




following sections.






2.    TEST RESULTS




2.1  Optical Examination




     The specimens were examined at magnifications up to SOX.  The




particulate matter could be seen intimately mixed with the quartz filter




fibers and it was obvious that the particulate matter could not be




physically separated from the filter pad upon which it had been collected.




Under tungsten filament the specimens appeared as follows:M1E-6 (light




gray), M1E-7 (dark gray), M1E-12 (yeHow-brown) and ETE-2 (partly dark




brown, partlylight brown).
                                                                          K-2

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2.2  Electron Beam X-Ray Microanalysis




     The electron microprobe is an advanced piece of equipment which uses




a small beam of electrons to produce characteristic X-ray emissions from




a sample volume with a radius of -1 micron.  Curved crystal X-ray




spectrometers are used to analyze the resultant characteristic X-ray




spectra.  In these analyses, the electron beam was defocused to a diameter




of 150 microns (0.006 inch) to cover a relatively large area of each




specimen and thereby obtain data which would be representative of the




entire sample.  The electron beam impinged in vacuum upon the untouched




sample surface.  An examination was made of the complex spectrum of X-rays




given off by the specimen under electron beam excitation, and it was found




that the entire spectrum could be identified uniquely on the basis of the




elements shown in Table 1.  All portions of the X-ray spectrum in the




wavelength range 1-100A covering all elements except H, He, Li, and Be




were taken into account.






   :  The analyses were conducted on small portions of the filter pads which




were not later digested for the atomic absorption analyses.  The small




samples for electron probe analyses are still intact.  The qualitative




analysis results are summarized in Table 1.  Several points seem germane:







     1.  The major elements are manganese, magnesium, calcium, and




         potassium.  The silicon signal could have come from either




         the filter pad or from the particulate matter.  The fibers




         of the pad were visible in the optical microscope which is




         attached to the electron probe.
                                                                           K-3

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     2.   Distinct signals,  equivalent to several  weight  percent,




         were found for sulfur,  chlorine,  carbon, sodium,  and




         potassium.












     3.   The presence of sodium  and chlorine frequently  suggests




         salt and could have come from handling with bare  hands.




         However, it must be stated that the filters were  not




         handled with bare  hands during the chemical analysis




         effort.







2.3  Atomic Absorption Analyses




         Atomic Absorption (A.A.) means that a cloud of  atoms  in  the




     un-ionized and unexcited state is capable of absorbing radiation




     at wavelengths that are specific in nature and characteristic of




     the element in consideration.  The atomic absorption  spectre-




     photometer used in these analyses consists of a series of lamps




     which emit the spectra of the elements determined,  a  gas  burner




     to produce an atomic vapor  of the sample, a  monochromator to




     isolate the wavelengths of  interest,  a detector to  monitor the




     change of absorption due to the specimen, and a readout meter to




     visualize this change in absorption.
                                                                          K-4

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    The filters with samples were weighed,  and the sample  weights




calculated by subtracting the tare weights  written on the  outside




of the Petri dish sample containers from the total weights.




Specimen identifications were as follows:   MlE-6,  MlE-7, MlE-12,




and a composited specimen consisting of filters WTE-3,  ETE-1,




and ETE-2.
                                                                     K-5

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                Table 1.    Qualitative Electron Beam X-Ray Microanalyses
Specimen
No.
M1E-6
M1E-7
M1E-12
ETE-2
Cr
-
-

T
Mn
H
H
H
H
Mq
M
H
H
H
Fe
L
L
L
L
Al
T
M
H
H
Ca
H
H
H
H
Ba
-
T
M
'M
Na
M
H
H
H
K
H
H
H
H
Zn
L
T
-
T
Cl
H
•H
L
L
S
M
H
L
M
Si
M
H
H
H
C
L-M
L-M
L-M
L-M
KEY:   H = greater than 20 wt%  •
       M = 10-20 wt%
       L = 1-10 wt%
       T = less than 1  wt%

      NOTE:   Sample ETE-2  was  later  composited with WTE-2  and  ETE-1  in  the  atomic
             absorption analyses.  The  compositing operation in  this particular
             case involved digesting three  filter pads,  with their  particulate
             matter, in one common acid solution.  The microprobe analyses  were
             performed  on  a portion  of  ETE-2  that was not  digested.
ro
CO
•
«^J
««l
—4
01

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                                                         4742.3.71-145
     The filters (both pad and parti cul ate) were extracted for 2 hours with
50 mis of 1:1 HgSO^; this solution was decanted and saved.  The filters were
then extracted for 2 hours with a boiling dilute Aqua Regia solution.*  This
solution was then combined with the H2SO. solution, filtered, taken to con-
stant volume in a volumetric flask, and analyzed by A. A.  The instrumental
parameters used for the individual elements are given in Table 2, and the
results of the A. A.** analyses are shown in Table 3.

     The A. A. results are normalized to compensate for the portion removed
for electron beam X-ray microanalyses.  Silica (Si Op) analyses were not per-
formed since the entire Si02 filter pad with the intimately mixed specimen
was digested in acid in each case.  In order to determine if the acid diges-
tion process chemically attacks the Si Op filter, an unused filter will be
exposed to the digestion process and A. A. analyses run on a blank to deter-
mine background concentrations.  A remote possibility exists that some K or
Na could have come from the filter material if it is not pure
     Note also that in Table 3 only one specimen (M1E-6) adds up to 100%.
The other specimens most likely consist of metal oxides or a mixture of
metals and metal oxides; oxygen and silicon are therefore the likely
missing chemical components needed to bring the totals in all four cases
to 100%.           .                                      •

     A comparison of these results with the results reported in Part 1
(Foote Mineral Corporation-Steubenville, Ohio) immediately brings to light
certain differences between the two emissions.  The Union Carbide (Marietta,
Ohio) emissions contain, in general, l£ss chromium but more manganese,
sodium, potassium, chlorine, and to be particularly noted, sulfur, than do
the Foote Mineral Corporation emissions.
    R. J. Thompson, G. B. Morgan, and L.  J.  Purdue, "Analysis of Selected Ele-
    ments in Atmospheric Particulate Matter by Atomic Absorption", Atomic
    Absorption NEWS Letter, Volume 9, No. 3, 1970
**
    Walter Slavin, Atomic Absorption Spectroscopy> Interscience Publishers,
    New York, New York, pp 79-189, 1968.
                                                                              K-7

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                                    4742.3.71-145
Table 2.   Instrumental Parameters
Element
Cr
Mn
Mg
Fe
Al
Ca
Ba
Na
K
Zn
Wavelength
(AT
3579
2801
2852
2483
3093
4227
5536
. 5890
7665
2139
Fuel Oxidizer
System
Air-Acetylene
Air-Acetylene
NpO-Acetylene
Air-Acetylene
N20-Acetylene
NgO-Acetylene
^O-Acetylene
Air-Acetylene
Air-Acetylene
Air-Acetylene
Slit
Width (A)
2
2
7
2
7
7
7
20
20
7
Hollow Cathode
Current (Ma)
10
10
4
12
13
8
7
10
10
8
                                                       K-8

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               Table 3.    Atomic Absorption Analysis Results Elemental Concentration  (Wt%)
Specimen
No.
M1E-6
M1E-7
M1E-12
Comoosite
(WTE-3, ETE-1,
and ETE-2)
Cr
0.09
0.04
0.09
0.1
,
Mn
27.6
7.6
7.7
21.8

Mq
2.3
1.2
1.2
0.6

Fe
1.0
• 0.2
0.3
1.0

Al
0.6
0.6
0.9
0.7

Ca
0.6
0.9
. 0.4
0.4

Ba
-
-
-
-

Na
21.3
44.4
37.8
<0.05

K
37.3
18.2
14.8
6.0
•
Zn
1.9
0.2
^.01
0.3

Total (%}
94.2
73.3
63.2
30.9

NOTE:   Silicon analyses not performed.

SPECIAL NOTE:  The values have been corrected, at the last minute, to account for contributions from
               the collector pad.                                                           .,
                                                                                                           -J
                                                                                                           -R»
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