TEST NUMBER 72-CI-14
ROCK DEFLUORINATION
BORDEN CHEMICAL COMPANY
PLANT CITY, FLORIDA
FEBRUARY 24 - 25, 1972
-------
PEDCo- ENVIRONMENTAL
SUITE 8 ATKINSON SQUARE
CINCINNATI. OHIO 45248
513 IT7 1-433O
TEST NUMBER 72-CI-14
ROCK DEFLUORINATION
BORDEN CHEMICAL COMPANY
PLANT CITY, FLORIDA
FEBRUARY 24 - 25, 1972
Prepared by
Richard W. Gerstle, P.E,
By
PEDCo-Environraental Specialists, Inc
Cincinnati, Ohio
Contract No. 68-02-0237, Task 1
-------
TABLE OF CONTENTS
SECTION PAGE
I. INTRODUCTION 1
II. SUMMARY OF RESULTS 3
III. DICALCIUM PHOSPHATE PROCESS 6
IV. SAMPLING PROCEDURES 7
V. ANALYTICAL PROCEDURES 10
VI. APPENDIX 11
Appendix A - Emission Calculations
and Results
Appendix B - Field Data
Appendix C - Test Log
Appendix D - Project Participants
Appendix E - Recommendations
-------
I. INTRODUCTION
Stack emission tests were conducted, and related process
samples were taken during the period February 22 to 25, 1972,
at the Borden Chemical Company's phosphate animal feed plant
in Plant City, Florida. Three tests were made to determine
total fluoride emissions on the rock defluorination operations
during the period of February.24 and 25.
According to the terms of PEDCo's contract with EPA, only
stack gas measurements, selected feed and product samples,
and scrubber water samples were to be taken by PEDCo. Three
simultaneous sets of samples were taken to determine the
fluoride content of the kiln exit gases before and after the
spray chamber/scrubber section at the locations shown in
Figure 1. In addition, samples of the rock feed, clinker
product, and scrubber water were taken during each run.
Moisture, carbon dioxide, and oxygen contents of the gas
streams were also measured as well as gas velocity, temperature,
and total volume. All process data and operating procedures
were obtained by EPA personnel. Sample analyses and emission
calculations were also to be performed by EPA staff.
-------
6" Refractory Brick
Lining
Detail of Sampling Site L
(Inlet)
Detail of Sampling Site M
(Outlet)
urner
Product Clinker
Inlet Sampling
Site Point L
Rock
Feed
Transition
Section
Settling
Chamber
Spray
Chamber -
Packed
Scrubber'
Outlet/^
Sampling Fan
Site-Point M
FIGURE 1. DIAGRAM OF ROCK DBFLUORINATION PROCESS AND
SAMPLING SITES
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II. SUMMARY OF RESULTS
The plant was operating under normal process conditions
during all of the test runs. Two sampling problems were
encountered while testing the scrubber inlet and should be
noted. First, the probe clogged during all runs. Due to
this problem, the first run was cut short; the probe was
cleared of particulate during the other two runs. Secondly,
the silica gel turned a dark color during the test runs at
the inlet. A visible fume was noticed passing through the
first three impingers and the filter and apparently was
reacting with the silica gel. Also, it should be noted that
the emission levels for the second run at the outlet are
considerably higher than for the other two runs.
A complete summary of stack gas conditions and emission
levels for each test run are given in Tables 1 and 2.
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TABLE 1. SUMMARY OF RESULTSSCRUBBER INLET
Run Number
Date
Stack pressure, inches Hg
Stack gas moisture, % volume
Average stack gas temperature, °F.
Stack gas flow rate @ S.T.P.*, SCFM
Vol. gas sampled @ S.T.P.*, SCF
Fluoride, water soluble, mg
Fluoride, total, mg
Fluoride, water soluble, gr/SCF
Fluoride, total, gr/SCF
Fluoride, water soluble, gr/CF stk. cond.
Fluoride, total, gr/CF stk. cond.
Fluoride, water soluble, Ib/hour
Fluoride, total, Ib/hour .
Fluoride, water soluble, Ib/ton P205 Fed.
Fluoride, total, Ib/ton P00C Fed.
C D
1
2/24/72
30.24
15.3
726
18394
48.43
9100
9324
2.9
3.0
1.1
1.1
456
467
157
161
2
2/24/72
30.24
15
724
15258
17.05
2800
2893
2.5
2.6
1.0
1.0
331
342
114
118
3
2/25/72
30.25
8.4
758
17283
33.89
5000
5112
2.3
2.3
0.9 .
1.0
336
344
116
119
Dry, 70°F., 29.92 inches Hg.
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TABLE 2. SUMMARY OF RESULTSSCRUBBER OUTLET
Run Number
Date
Stack-pressure, inches Hg.
Stack gas moisture, % volume
Average stack gas temperature, °F.
Stack gas flow rate @ S.T.P.*, SCFM
Vol. gas sampled @ S.T.P.*, SCF
Fluoride, water soluble, mg
Fluoride, total, mg
Fluoride, water soluble, gr/SCF
Fluoride, total, gr/SCF
Fluoride, water soluble, gr/CF stk. cond.
Fluoride, total, gr/CF stk. cond.
Fluoride, water soluble, Ib/hour
Fluoride, total, Ib/hour
Fluoride, water soluble, Ib/ton P00C Fed.
L 0
Fluoride, total, Ib/ton P00C Fed.
L 0
Scrubber efficiency, %
1
2/24/72
29.73
4.5
88
42608
52.53
2.9
2.9
0.0009
0.0009
0.0008
0.0008
0.31
0.31
o.-n
0.11
99.9
2
2/24/72
29.73
4.9
93
42390
50.70
10.6
10.6
0.0032
0.0032
0.0029
0.0029
1.17
1.17
0.40
0.40
99.6
3
2/25/72
29.43
4.4
90
41001
51.34
2.2
2.2
0.0007
0.0007
0.0006
0.0006
0.23
0.23
0.08
0.08
99.9
Dry, 70UF., 29.92 inches Hg.
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III. ROCK DEFLUORINATION PROCESS
In the defluorination process, phosphate rock is charged
to a gas-fired rotary kiln and heated to approximately 2500°F.
Exit gases containing fluorides pass through a settling chamber,
a round transition section, a spray chamber, a packed bed
scrubber containing Tellerettes, a fan, and a 200 foot high
stack. A large opening in the duct between the scrubber and
fan allowed ambient air to enter the duct and caused considerably
higher gas.flows to occur at the outlet test site as compared to
the inlet site.
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IV. SAMPLING PROCEDURES
All gas streams were sampled isokinetically by using a
modified EPA particulate sampling train and following the
sampling procedures described in Method 5 of the Federal
Register of December 23, 1971. The sampling train as shown
in Figure 2 consisted of a stainless steel button-hook nozzle,
a heated Pyrex glass probe contained in a steel sheath/ a
Greenburg-Smith impinger without a tip, a second impinger with
a tip, a third impinger without a tip, an 80 millimeter Whatman
No. 1 paper filter, and a final impinger containing approxi-
mately 200 grams of indicating type silica gel. The first
and second impingers contained 100 ml each of distilled water
at the beginning of each test. The third impinger was initially
dry. All impingers were contained in an ice-water bath and the
temperature of the gases leaving the fourth impinger was in the
65 to 70°F range. The filter was not heated. An air tight
vacuum pump, dry gas meter, orifice, and associated valves,
connectors, thermometers, and manometers completed the train.
A stainless steel probe was used on the inlet site in the
defluorination process because of the high temperatures
encountered there.
A type 'S' pitot tube was attached to the probe to measure
the velocity head of the stack gas. The sampling rate was
continually adjusted to maintain isokinetic sampling rates by
-------
THERMOMETER
r ii tin HOI.Din
PEVERSE-TYPE
PITOI TUBE
STACK
BY-PASS VALVE VACUUM
MAIN VALVE GAU<3E
DRY TEST METER
FIGURE 2 .. SAMPLING TRAIN USED TO DETERMINE
FLUORIDE CONCENTRATIONS
-------
means of a nomograph which related the pressure drop across the
orifice after the meter with the velocity head measured by the
pitpt tube. Stack gas temperatures were measured with long
stem dial thermometers.
In a typical run to determine fluoride concentrations,
the train was assembled and checked for leaks by plugging the
first impinger and drawing a vacuum of 15" Hg. The probe and
nozzle assembly was then attached to the impinger and the train
positioned at the first sampling point. Each point along the
stack diameter was sampled for ten minutes. A two hour sampling
period was used, except at the inlet site where a 90 minute
sampling period was used because of heavy fluoride concentrations.
At each point the velocity head, stack gas temperature, final
impinger temperature, meter temperatures, meter reading, pump
suction pressure, and orifice pressure drop was measured and
recorded. All data sheets for these tests are attached in
Part B of the Appendix.
Upon completion of sampling, the train was completely
disassembled, the condensate volume measured, and the silica
gel weighed on a triple beam balance at the site. The water
in the impingers was poured into plastic (Nalgene) wide mouth
bottles. The paper filter and all washings from the probe and
-------
all glassware were also placed in this same container. When
necessary the probe was also brushed to remove solid matter.
All-train components were then dried with acetone and the train
reassembled for the next run. Each container was immediately
labeled.
Feed, product, and scrubber water samples were also placed
in plastic bottles and labeled. All samples were submitted
to Mr. J. Rom of EPA for future analysis.
Moisture content of the gas stream was determined by making
a preliminary run with this same train without a filter. This
was accomplished by running the train at a sampling rate of
approximately 0.75 cfm for 30 minutes and measuring the moisture
condensed and the weight gain of the silica gel.
Carbon dioxide and oxygen content of the gas stream were
measured with a standard Orsat apparatus by drawing samples
from the stack directly into the Orsat apparatus through a one-
quarter inch diameter stainless steel probe. The probe was
carefully purged with stack gas before taking the sample. This
procedure was deemed sufficiently accurate to determine the
molecular weight of the stack gases.
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V. ANALYTICAL PROCEDURES
Water soluble fluorides were determined by a sulfuric
acid distillation followed by the SPADNS-ZIRCONIUM LAKE METHOD,
Water insoluble fluorides were first fused with NaOH followed
by a sulfuric acid distillation then by the SPADNS^Zirconium
Lake Method.
10
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VI. APPENDIX
11
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APPENDIX A
EMISSION CALCULATIONS AND RESULTS
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NOMENCLATURE
PB - Barometric pressure, inches Hg
PS - Stack pressure, inches Hg
As -. Stack area, sq. ft.
TS - Stack temperature, °R
TM - Meter temperature, R
H_ - Average square root of velocity head, /inches H?0
AH - Average meter orifice pressure differential, inches H?0
AN - Sampling nozzle area, square feet
CP - S-type pitot tube correction factor
VM - Recorded meter volume sample, cubic feet (meter conditions)
VC - Condensate and silica gel increase in impinqers, milliliters
Po - Pressure at the dry test meter orifice, PB + TO~F inches Hg
STP - Standard conditions, dry, 70°F, 29.92 inches Hg
VWV - Conversion of condensate in milliliters to water vapor in cubic feet (STP)
VSTPD - Volume sampled, cubic feet (STP)
VT - Total water vapor volume and dry gas volume samples, cubic feet (STP)
W - Moisture fraction of stack gas
FDA - Dry gas fraction
MD - Molecular weight of stack gas, Ibs/lb-mole ('dry conditions)
MS - Molecular weight of stack gas, lbs/lb/-mole (stack conditions)
GS - Specific gravity of stack gas, referred to air
EA - Excess air, %
U - Stack gas velocity, feet per minute
OS _ Stack gas flow rate, cubic feet per minute (stack conditions)
OD - Stack gas flow rate, cubic feet per minute (dry conditions)
OSTPD - Stack gas flow rate, cubic feet per minute (STP)
PISO - Percent isokinetic volume sampled (method described in Federal Register)
Time - Total sample time, minutes
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KQUAT1UNS FOR CALCULATING i-LUOKIDli LMlSSlONf;
WV = .(0.0474) x (VC)
VSTi'D = (17.71 x (VM) >: (PB + S- )-^ TM
13.6
VI = (VV.'V) + (VSTi'D)
W = (W.-V)-r(VT)
FDA = (1.0) - (W)
HD - (0.44 x % C02) + (0.32 x % 0£) + (0.28 x % N2) <- (0.28 x % CO)
MS = (:-:D x FDA) + (18 x w)
GS = (MS) -~ (28.99)
EA = [(100) .x (% 02 - ^)] -r- [(o.266 x % N,) - (% 02 - ±
U_ = (174) x (CP) x (H) x V(TS x 29.92)~(GS x PS)
QS = (U_) x (AS)
QD = (QS) x (FDA)
QSTPD = (530) x (QD)-r-(TS) x (PS) v (29.92)
PISO = [(o.oo267 x VC x TS) -J- (PQ x TS x VM -;- TM)]] -~- [(Time x £ x PS x AN)
Fluoride Emissions:
XG - Milligrar.is of fluoride from lab analysis
Grsins/SCF = (0.01543) x (MG) -]- VSTPD
Crains/CF, Stack Cond. = (17.71) x (PS) x (FDA) x (Grains/SCF) - (TS)
Lbs/hour = (GrnJaa/SCF) x (0.00357) x (QSTPD)
i"V')5 i'ed - Tons/iiour , dcLcrr.iinoc: fror.i plant dam
Lbii/Uni P20r Fed-" (Ibs/i.our) -^- (Tons/hour P20,. Fed)
-------
EMISSION DATA
BORDEN CHEMICAL
ROCK DEFLUORINATION
OUTLET
1) Run Number
2) Date
3) Time Began
4) Time End
5) Barometric Pressure, In Hg
6) Meter Orifice Pressure Drop, in H-0
7) Vol Dry Gas, Meter Cond . Cubic Feet
8) Average Gas Meter Temperature, Deg F
9) Vol Dry Gas, S.T.P., Cubic Feet
10) Total H20 Collected, Ml
11) Vol H20 Vapor Collected, S.T.P., Cu.Ft.
12) Stack Gas Moisture, Percent Volume
13) Assumed Stack Gas Moisture, Pet Vol
14) Percent C02
15) Percent 02
16) Percent CO
17) Percent N2
18) Percent Excess Air
19) Molecular Weight of Stack Gas, Dry
20) Molecular Weight of Stack Gas, Stk Cond.
21) Stack Gas Specific Gravity
22) Avg. Square Root (Vel Head) , in H^O
23) Average Stack Gas Temperature, Deg F
24) Avg. Square Root (Stk Temp x Vel Head)
25) Pitot Correction Factor
26) Stack Pressure, in Hg , Absolute
27) Stack Gas Vel, Stack Cond, F.P.M.
28) Stack Area, Sq. Feet
29) Effective Stack Area, Square Feet
30) Stack Gas Flow Rate, S.T.P., SCFMD
31) Net Time of Test, Minutes
32) Sampling Nozzle Diameter, Inches
33) Percent Isokinetic
34) Fluoride - Water Soluble, MG
35) Fluoride - Total, MG
36) Fluoride - Water Soluble, GR/SCF
37) Fluoride - Total, GR/SCF
38) Fluoride - Water Sol., GR/CF,STK CND .
39) Fluoride - Total, GR/CF,STK CND.
40) Fluoride - Water Soluble, LB/HOUR
41) Fluoride - Total, LB/HOUR
43) Fluoride - Water Sol., LB/TON P205 FED
44) Fluoride - Total, LB/TON P205 FED
1
2/24/72
12:01
14:01
30.3
0.47
54.57
97.2
52.526
52.4
2.48
4 .5
6
2.8
16
0.2
81
282
29.09
28.59
0.99
1.519
87.6
35.548
0.83
29.73
5186.3
8.95
8.95
42608
120
0.125
107.8
2.9
2.9
0.0009
0.0009
0.0008
0.0008
0.3105
0.3105
0.1071
0.1071
2
2/24/72
16:20
18:20
30.3
0.47
51.94
90.5
50.699
55.3
2.62
4.9
5
2.2
15.8
0.2
81.8
259
28.98
28 .44
0 .98
1.521
93
35.761
00 *)
. 83
29.73
5230.5
8.95
8.95
42390
120
0.125
104.7
10.6
10.6
0.0032
0.0032
0.0029
0.0029
1.1697
1.1697
0.4033
0.4033
3
2/25/72
9:10
11:10
30
0.44
52.59
85
51.335
49.7
2.36
4 A
. 4
6
1.8
16
0 .2
82
269
28.93
O O A C
£ 0 . 4b
On o
. y o
1A C. C.
. 4b b
Q n
y u
34.388
Op o
O J
29 .43
f f\ C~ A f\
5054 . 9
8.95
8.95
41001
120
0.125
109.6
2.2
2.2
0.0007
0.0007
0.0006
0.0006
0.2319
0.2319
0.08
0.08
***S.T.P. «~*DRY, 70 DEGREES F, 29.92 INCHES MERCURY***
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EMISSION DATA
BORDEN CHEMICAL
ROCK DEFLUORINATION
INLET
1) Run Number
2) Date
3) Time Began
4) Time End
'5) Barometric Pressure, In Hg
6) Meter Orifice Pressure Drop, in H_0
7) Vol Dry Gas, Meter Cond . Cubic Feet
8) Average Gas Meter Temperature, Deg F
9) Vol Dry Gas, S.T.P., Cubic Feet
-±0) Total H20 Collected, Ml
11) Vol H20 Vapor Collected, S.T.P., Cu.Ft.
2) Stack Gas Moisture, Percent Volume
.3) Assumed Stack Gas Moisture, Pet Vol
14) Percent C02
'5) Percent ©2
6) Percent CO
17) Percent N2
^8) Percent Excess Air
9) Molecular Weight of Stack Gas, Dry
20) Molecular Weight of Stack Gas, Stk Cond.
_21) Stack Gas Specific Gravity
2) Avg. Square Root (Vel Head) , in H20
-^.3) Average Stack Gas Temperature, Deg F
J?4) .Avg. Square Root (Stk Temp x Vel Head)
.5) Pitot Correction Factor
6) Stack Pressure, in Hg , Absolute
27) Stack Gas Vel, Stack Cond, F.P.M.
^8) Stack Area, Sq . Feet
:9) Effective Stack Area, Square Feet
~30) Stack Gas Flow Rate, S.T.P., SCFMD
r-31) Net Time of Test, Minutes
;2) Sampling Nozzle Diameter, Inches
-J3) Percent Isokinetic
J34) Fluoride - Water Soluble, MG
H5) Fluoride - Total, MG
16) Fluoride - Water Soluble, GR/SCF
37) Fluoride - Total, GR/SCF
^.8) Fluoride - Water Sol., GR/CF , STK CND .
, !9) Fluoride - Total, GR/CF, STK CND.
'"40) Fluoride - Water Soluble, LB/1IOUR
-41) Fluoride - Total, LB/MOUR
13) Fluoride - Water Sol., LB/TON P->05 FED
44) Fluoride - Total, LB/TON P205 FED
1
2/24/72
11:52
30.3
1.18
49.87
94.2
48.433
185.2
8.78
15.3
15
4
14.5
0.2
81.3
199
29.22
27.5
0.95
0.534
725.6
18.398
0.83
30.24
2713.7
17.72
17.72
18394
90.1
.375-. 25
97.5
9100
9324
2.8935
2.9647
1.1059
1.1331
456.115
467.3424
157.281
161.1526
2
2/24/72
16:37
18:32
30.3
0.3
17.257
83.5
17.054
63.7
3.02
15
15
3
15.3
0.2
81.5
235
29.09
27.42
0.95
0 .441
725
15.167
0 .83
30.24
2240.2
17.72
17.72
15258
58
0.25
100.1
2800
2893
2.5284
2.6123
0.9711
1.0033 '
330.6146
341.5957
114.005
117.7916
3
2/25/72
8:00
30.3
0.32
34.07
80
33.89
65.5
3.1
8.4
15
3.2
15.3
0.2
81.3
237
29.12
28.19
0.97
0.476
758
16 .615
0 .83
30.25
2420
17.72
17.72
17283
96
0.25
106 .2
5000
5112
2.2721
2.3229
0.915
0 .3355
336.5176
344.0556
116.0405
118.6399
r**S.T.P. «-+DRY, 70 DEGREES F, 29.92 INCHES MERCURY***
-------
BORDEN CHEMICAL
ROCK DEFLUORINATION
SCRUBBER EFFICIENCY
SCRUBBER
Run 1
Flow: 18394 (DSCFM) Efficiency: 99.9
Total Fluoride: 467 (#/hr)
Flow: 42608
Total Fluoride: 0.31
Run 2
Run 3
Flow: 15258
Total Fluoride:
342
Flow: 17283
Total Fluoride: 344
Efficiency: 99.6
Efficiency: 99.9
Flow: 42390
Total Fluoride: 1.17
Flow: 41001
Total Fluoride: 0.23
-------
APPENDIX B
FIELD DATA
-------
Velocity Traverse data (taken from meter data sheets) Test 2
Inlet
Velocity traverse data (taken from meter data sheets) Test 2
Outlet
Velocity traverse data (taken from meter data sheets) Test 3
Inlet
Velocity traverse data (taken from meter data sheets) Test 3
Outlet
Orsat Analyses
12
-------
Preliminary velocity traverse data sheets and meter data
sheets for the moisture run and three fluoride determination
runs at the scrubber inlet and outlet sites are included in
this section for the defluorination process. These data sheets
are presented as follows:
Preliminary velocity traverse at inlet to scrubber
Preliminary velocity traverse at outlet of scrubber
Meter data sheet for moisture determination at inlet to scrubber
Meter data sheet for moisture determination at outlet to scrubber
Meter data sheet for fluoride determination at inlet to scrubber
Test 1
Meter data sheet for fluoride determination at outlet to scrubber
Test 1
Meter data sheet for fluoride determination at inlet to scrubber
Test 2
Meter data sheet for fluoride determination at outlet to scrubber
Test 2
Meter data sheet for fluoride determination at inlet to scrubber
Test 3
Meter data sheet for fluoride determination at outlet to scrubber
Test 3
Velocity traverse data (taken from meter data sheets) Test 1
Inlet
Velocity traverse data (taken from meter data sheets) Test 1
Outlet
-------
GAS VELOCITY AND VOLUME DATA
Test No.
CO
o
V £JJJW\_ J. i i J. JVf\V Iji\OI^ Ui-lii-l
Point
1
7
3
x-|
5"
(,
1
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10
(1
IZ
(3
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I
3.1 Y-
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6.00
n,
ty.2O
11. \O
15.10
is:so
1&. MO
Z'z.no
3^40
33. (rO
»4 1. s^o
i4<4.00
M6.00
UlOO
49. £0
51.00
52, SO
54.0^)
££.20
S6>,30
Total
Average
Reading, Ap
"H2°
O.t*?
0. \ft
O. )9
(^.70
0.7.1
0,"Z?
0."ZO>
O,Z1
0.2A
0,"Z.8
O.Z'R
0.3O
0,~23
(3.Z/
O.70
<3. Ift
0.17
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Q.ZO
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0. IS
o>m-
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-
-
VAP
. HlZ,
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4$#
.H-8><5
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.>-/80 ^
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."4*41
.^714
.q 12.
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-38-7
.ST4/ '
.??z
0,014
O,4^3
T °F
s
10{)
100
Location 1WV_£T- DtfUidf? .
Stack Inside Dimensions *f\" r,D.
Stack Area, A^ = jr
Barometric Pressure, P
Stack Gage Pressure =
Stack Abs. Pressure, P
7.7^ sq. ft/
-^v. 'X " U/-r
, 3^. 3 Hg
-O.^lg "H^O
/O ^ ^* "W^D 4. D CZO "7"^ "H/-r
C/. i ;> 112^ *^ "w O1-^' ^- ' ny
13.6 b
^7/1 /^ °'ci-i.4#;n ii//n °D
[UU E T 4OU 1 1 (^j * Pn \/ T
V J./4 V np cp V -"-g
Q, Volume = 22.1 0
Q , Standard Volume at
w
Q x 530 x Ps
T 29.92
Q - Q x (100-W)/100
O in
/ / / v
u
a) From outside of port to sampling point. \\
Pitot tube "$,' ^-
Manometer
x 29.92 x 29' ft/min.
P M
s s
t &&t *fr . 2^0
ft/min. x lr?.r]2. sq. ft. L(.6,"ZZ^/- cfm
70 °P snr? ?Q Q? "Hn ^We>+- naci o^
- 17.7 x ^-0^2 14. x 3,0.23 - iQCO-t
m.o
1 f1"'
fcx '
4W-
Thermometer
Data Recorder 6, f,
Date 1.
-z<4-nz_
PEDCo- ENVIRONMENTAL
SUITE 8 ATKINSON SQUARE
CINCINNATI. OHIO 45246
513 /77 1-4330
-------
GAS VELOCITY AND VOLUME DATA
U)
VELOCITY TRAVERSE DATA
Point
1
z
3
M
S
(,
7
&
s
10
II
17
13
14
i§"
Ik
Total
Averac
Position
Inches3
O,L£
-?.oo
3.Zs
S.IO
l,AO
9, oo
ll.SO
IS.7S
zs,5o
23.00
M.TS"
3^),oo
3SMS
B'l.ZO
3B,SO
ii-0,00
re
Reading,Ap
"H20
1.^0
~Z,OO
1,90
Z, 00
L>00
i,i o
Z.JO
Z./ 0
2/Z.C
1.30
2,140
2.4-0
Z.^D
Z.7-6
i.ZO
Z.Z<9
-
-
\/Ap
1,318
,4-1.4-
.318
1.WH4-
I.MIW
l,i4M-^
.44=1
,W^t
,^00
.SIC»
.b^
b^'l
,s&l.
,482
;a83
>aa3
23^a*»
I.H^ft
T
s
0
o
T
^
oF
o
/
0
Test No.
Location
Stack Inside Dimensions 40.S
Stack Area, A = 8 .VS!
OU"vv_ET-
sq
Barometric Pressure, P, =
Stack Gage Pressure = n .1 ^
Stack Abs. Pressure, P = -~1 .~1 5"
S
ft.
30.S "Hg
"H2°
"H20 + Ph = 2fl,13 "Hg
13.6
Stack Gas Temp., T =
O
AO
'F + 460 =
550
(R
Molecular Weight of Stack Gas, M =
V = 174
s
V =
Cp V T x 29.92 x f9~* ft/min.
P M
__s s
^ - 510 S
Q, Volume = SlQ8' ft/min. x
sq. ft. = 45.111 cfm
Q , Standard Volume at 70°F and 29.92 "Hg(Wet Basis)=
Q x 530 x Ps = 17.7 x HJTp 11 x _2
T 29.92
= Qw x (100-W)/100 =
a) From outside of port to sampling point,
Pitot tube -^__
Manometer
Thermometer
Data Recorder
Date 2-
PEDCo- ENVIRONMENTAL.
SUITE S ATKINSON SQUARE
CINCINNATI. OHIO 45346
513 17~7 1-4330
-------
PARTICULATE FIELD SAMPLING METER DATA
Plant 5QRDEVJ S
Filter No.
Run Number r<\0 \ £>T
Location
Date
Time \ Q ; o Q
Operator
Sample Train Number
Meter Number ^
AH@
Barometric Pressure, in. Eg "5O. "3>
Assumed Moisture, %
Assumed Meter Temp., °F
Stack Gage Pressure
= "H20
Probe Tip Diameter, in.
Condensate Collected, ml. (g S
'C1 Correction Factor
Point
36" IM
Total
Avg.
Time
Min.
-bO
30
Dry Gas Meter
Volume
ft3
Vm
°l.(ySO
\^.70O
2(,MSS
Ik.ftOS
Inlet
Temp.
OF
-ia
^0
°((*
1(j>\±
SB
Outlet
Temp.
oF
Ik
Tft
9SL
Z3U
19
Velocity
Head Ap
"H2°
,
Orifice AH
"H2°
_
Pump
Vacuum
"Hg
11
n
ZZ
56
19
Filter
Temp.
OF
Impinger
e*
Temp . , ° F
C^S"
70
-1^
2.10
ID
Stack Gas
Temp . , ° F
T
-?<36
~7OQ
-H6
21IO
7^3
U)
NJ
Leakage Rate @ 10 "Hg = Q,O|
cfm
3O.3.Q
PEDCo- ENVIRONMENTAL
SUITE 8 ATKINSON SQUARE
CINCINNATI. OHIO 45246
513 IT7 1-433O
-------
PARTICULATE FIELD SAMPLING METER DATA
Plant
Filter No.
Run Number
Location
Date Z-
Barometric Pressure, in. Hg
Assumed Moisture, %
Time ^ '.00-^:30
Operator LftE~
Assumed Meter Temp., °F
Stack Gage Pressure 1. *"? ST
Sample Train Number 2.
Meter Number _ 2.
AH@
-"H2°
Probe Tip Diameter, in.
Condensate Collected, ml. 2 if. 8
'C1 Correction Factor
Point
£o"iu
Total
Avg.
Time
Min.
; '.
»o
20
30
30
Dry Gas Meter
Volume
ft3
Vm
^36,10
^Wh.O/i
A gsrzo
^tl.^o
Z^.ftO
Inlet
Temp.
op
cf>4
IOL,
no
310
J03
Outlet
Temp.
oF
n\
^4
m
2^^-
^5
Velocity
Head Ap
"H20
^~~
Orifice AH
"H20
Pump
Vacuum
"Hg
m-
)<4
m-
M-Z
/4-
Filter
Temp.
oF
'"'
Impinger
er
Temp . , ° F
S3
sz
SI
\(ffS
Sh"
Stack Gas
Temp . , ° F
T
95
9s
85"
^
-------
PARTICULATE FIELD SAMPLING METER DATA
Plant
Run Number
Location
Date p.
Operator
Sample Train Number
Meter Number 3
AH@ l
Filter No.
Barometric Pressure, in. Hg
Assumed Moisture, % _ j_5
Assumed Meter Temp., °F
Stack Gage Pressure Q.
I QQ
-"H2°
Probe Tip Diameter, in.
1
Condensate Collected, ml.
"C1 Correction Factor Q, *~/ uf-
,2.
Point
1
2
3
4 -3K
£
fc
7
«
9
10
1 1
IZ.
Total
Avg.
Time
Min.
IO
10
10
fO
\o
to
\0
10
10
10
5S ££
30-I
Dry Gas Meter
Volume
ft3
Vm
2^.54-0
33.6.2.0
M2.32C?
S'O-^OO
SA. 560
62.- H7-O
Ut.^SO
10. fe3O
14. 1^0
TGr.«4-»rt
M^.fl'VO
Inlet
Temp.
oF
065
<^V
lOfo
\0b
q?_
qt-
IOO
102.
IOZ
Aft!
CJ
\(>.0
i.n
8.0
9.0
ft 1,5"
q. i
Filter
Temp.
oF
.
_
~
Impinger
or
Temp . , ° F
^2.
(e(ff
(f~l
LA
12.
69
no
92.
VZ
6,18
fo9
Stack Gas
Temp . , ° F
Ts
nio
*l^O
nio
T-^O
110
T30
130
73O
r72C
(p£30
7^^
OJ
Leakage Rate @ 15 "Hg = O, Q|
jjf-CHAKJ6E.t> TO V1-*'' WOZZLE. - (
~32 hfinO"!^ *=>£C ^ £>? L?Lf CF
^ 20" Ha. ~
cfm
Fli-TtR. ^ FI^-ttR.
PEDCo- ENVIRONMENTAL
SUITE 8 ATKINSON SQUARE
CINCINNATI. OHIO 4524C
513 / 77 1-.433O
- 4-8.
-------
PARTICULATE FIELD SAMPLING METER DATA
Plant
Run Number
\
Location PEFLUO^. - OUTLET
Date 2-74-7Z Time 12 :pl
Operator L.t\£ - TF 6-
Sample Train Number 2.
Meter Number 2.
AH@ 1.3^ r»
0.7S
Filter No.
Barometric Pressure, in. Hg
Assumed Moisture, % L>
. "3
Assumed Meter Temp., °F i QQ
Stack Gage Pressure *7. 7 5"
Probe Tip Diameter, in.
'/8
"H^O
Condensate Collected, ml. 52.
'C' Correction Factor
p.
Point
1
z
3
4
5
(a
7
A
°l
10
II
IZ
Total
Avg.
Time
Min.
10
10
10
10
10
10
10
(0
10
10
10
!<3
IZO
Dry
Volume
ft3
Vm
^kfl.0"3
Q12.30
CT?fe, 7O
S 80, 8O
°|8S,O(9
^a^.^o
qs?.qo
qm (no
1063, 3O
1005. (00
1012., ^O
ion. 70
10ZZ.SO
54. 4-7
Gas Mete
Inlet
T^TTftT"!
oF
Aft
<=»:*)
^A
loo
lr>^
IOM-
m4
lOCs
lOfo
1 10
\ if)
1 10
no
13H--L
103
2r
Outlet
rPf^TnT>
oF
Qb
VP>
ftA
°IO
°IO
qi
92.
^2.
q:*>
q^
^M-
94
9M
M8fe
°ii
Velocity
Head Ap
"H n
2,0
2.Z
\.8
2.0
-2.1
2.3
2.6"
i.S
2,£
2,7
2.7
2.5"
Orifice AH
"H20
0,4-1
0.45
0,37.
d.Wf
0,43
0.^7
0,SO
O.SO
o.So
O.S4
n.s4
O.S'O
5,^
.47
Pump
Vacuum
"Her
ng
5
5
5
£
$
S
«T
5"
,?
^
fc.r
7.5
(*4o
&3
Filter
Temp.
op
-
-K
Impinger
&₯
Temp . , ° F
S(»
vb4
57
S(e
SL>
SLo
Sb
sk
5^7
S'-l
til
5"7
(^7^
.«sfa
Stack Gas
Temp . , ° F
T
s
ftl
H7
57
qn
^0
90
67
fl7
<5S
?57
«"7
67
rosi
ftft
OJ
U1
Leakage Rate @ »S "Hg = Q.Q cfm
PEDCo- EN VI RON MENTAL
SUITE 8 ATKINSON SQUARE
CINCINNATI. OHIO 4524C
SI 3 /7~7 1-A33O
-------
PARTICULATE FIELD SAMPLING METER DATA
Plant
Run Number
Location
Date Z-2a-nz. Time ^-' 37S>'
Operator 6- P * fc S» f\
Sample Train Number
Meter Number
AH@ 1.^2 @ O.ng
Filter No.
Barometric Pressure, in. Hg
Assumed Moisture, % \_S_
Assumed Meter Temp., °F IQQ
Stack Gage Pressure - p,ng
Probe Tip Diameter, in. 0,
-"H2°
Condensate Collected, ml.
'C' Correction Factor fl.i if
Point
1
I
3
4
s
L
7
K
_ e»
10
n
IT.
Total
Avg.
Time
Min.
6
fi
6
fi
A *
ft**
6-s^c-^
2.
,
«.
58
Dry Gas Meter
Volume
ft3
Vm
-TB.S^S
AO, 51 d9
fi 3 . 31 0
6 C, , 4fl 0
89, IG5O
<=»7. 0-9.0
qs\ oio
qb. 8^^
n.257
Inlet
Temp.
OF
B4- .
flfe
Sfo
SA
&t
P>0
5"0fe
94
Outlet
Temp.
oF
8-4-
B4
8«4
fl3
8Z
ao
4^1
ft^
Velocity
Head Ap
"H2°
6 . IG,
0. 22.
0, ^7
fl.Ofl- '
0,2$
O.Z7
d,^3
^3,ZI
o.n
0,11
0,17
0, It
Orifice AH
"H2°
O.-ZM-
o.-bl
o.s'i
^-
l 0
\\- ^1
S
1^
zr
1(0
\1Z
i-f
Filter
Temp.
oF
Impinger
*&₯
gondonoor
Temp . , ° F
15
12.
^
<*<=),
*10
no
HIS"
11
Stack Gas
Temp . , ° F
Ts
1Z$
m£
17^3
1Z£
120
720
SOCKS'
H2.4
Leakage Rate @ IS" "Hg
Teir i o$- ~TO
0,01
cfm
To
PEDCo- ENVIRONMENTAL
SUITE 8 . ATKINSON SQUARE
CINCINNATI. OHIO 45246
513 I T7 1-433O
v s-n) * P EP fxO
-------
PARTICULATE FIELD SAMPLING METER DATA
Plant
Run Number
Location PE FLUOR. Qg-rv.-eT
Date Z-"Z4~n2. Time 14 -.70 -(,70
Operator LFS E I
Sample Train Number
Meter Number
AH@
2.
Filter No.
Barometric Pressure, in. Eg 30,3
Assumed Moisture, % £"
loo
Assumed Meter Temp., °F ^_
Stack Gage Pressure - ~i,n
10
1 0
I 0
10
IZ.O
Dry Gas Meter
Volume
ft3
Vm
2Z,C.O
2,6. --(-0
10. "bO
34,3^-
^s.^o
142.45
4G>.^<0
G\,00
SS.80
(fO,<4O
(at- 1^
70. OO
^^.sw-
Sl^^4-
Inlet
Temp.
op
ft (a
90
RA
( OQ
\C>0
1 0 0-
loo
ioz_-
IOZ
102
IdZ.
100
1 IBZ
9S
Outlet
Temp .
oF
60
AO
ftO
H5L
flLf.
RU-
flw-
ftW
AM-
83
ftZ
80
^87
8i
Velocity
Head Ap
"H2°
1,^
2.0
1,0
2..0
Z.O
Z.I
2,^
2,U>
2,-)
2.7
2,R
2.5*
Orifice AH
"H2°
O.I&S
0 «HI
(3 ,<4 1
rJ ,HJ
^,«4»
O.M1?
0, SO
^5,S3
0,^-4
tf, i?4
5,^T
£5.S^3
SikM-
,41
Pump
Vacuum
"Hg
fD;f\
L><
ri.Q
*1. s
7.S
?,0
8.C
^.^
q.o
9.0
9,0
*1,0
T^,O
8,0
Filter
Temp.
oF
__
_
_
_
_
~
-
-
-~
Impinger
&₯
CondonGor
Temp. , °F
5^
Slo.
Siff
Sb.
Sb.
5-5-.
$^
5-4-
SS
52.
si-
^Z.
L>s^
s±
Stack Gas
Temp. , °F
Ts
^0
^0
qn
°LO
°(0
Q?
qs
^
°(Z
<\$
q5
^5-
M IS"
CJ3
OJ
Leakage Rate @ 15 "Hg = Q,Q cfm
PEDCo - ENVIRONMENTAL
SUITE 8 ATKINSON SQUARE
CINCINNATI. OHIO 45246
513 l~7~7 1-433O
-------
PARTICULATE FIELD SAMPLING.METER DATA
Plant
Run Number
Location
Date 2-'2.S'-~l'L Time
Operator g<>t\ i.
Sample Train Number
Meter Number 3
AH@
Filter No.
Barometric Pressure, in. Hg 30,3
Assumed Moisture, % ib
10
Assumed Meter Temp., °F
Stack Gage Pressure 0,10 "H^O
Probe Tip Diameter, in. p. ~L
Condensate Collected, ml. _k
'C' Correction Factor Q,]
Point
1
2
3
M
r
(*
1
5
<»
10
il
17.
Total
Avg.
Time
Min.
6
A
ft.
a
&
p,
p,
p>
8
P) X
S,
&
°lb
Dry Gas Meter
Volume
ft3
Vm
9k, 73
W. 9M-
lOZ.qO-
ibk,o<}
16^. ZZ
1 IZ,6.O
1 IS.fNO
118 ,bO
1^1.3*7
11?. 8Z
/26,.0^
128, (oO
130, P>0
m.cn
Inlet
Temp.
oF
t^
17
^A
80
8Z
«6»
ftfc
91
M
68
8S
86.
^0
1675
fi3
Outlet
Temp.
oF
U'i
^
70
13
^7S
^7
7A
7S
So
sr
QZ.
m
8^-
^^q
17
Velocity
Head Ap
"H2°
.31 -9 ,7.0
0 ,Z1
/O ,Z^
0,7.7
o.za
0,7.7
tf-T-O
6, 17
O.lfl
0,1^
o.l~7
0, \ 9
O.ZD
Orifice AH
"H2°
.^^-^ .26
0,38
O.Vi
O.'iS
0.^
^,lfi
C. 7.ft
0, Z4-
6,769
0,Z7
0,?M-
O.Z-7
A.Z^
M.49
0.3Z
Pump
Vacuum
"Hg
b
W-
^
5
£
i
5"
6>
5
k~ 18
M-
L> -in
10
IO
r,fl
(ati
(o^
(^
10
70
7(0
892.
C=^
Stack Gas
Temp. , °F
Ts
7<^O
no
76>5
n/o5
7/o.S"
76 0
7^^
7^^
7 SO
7S1D
7 SO
79T
75"7
985Z-
TS8
00
CO
Leakage Rate @ | £ "Hg
TO
cfm
PEDCo-ENVIRONMENTAL
SUITE 8 ATKINSON SQUARE
CINCINNATI. OHIO -45246
513 l~7~7 1-433O
-------
PARTICULATE FIELD SAMPLING METER DATA
Plant
Run Number
Location
Date Z--Z
Time C\ :\p
Operator L(\E \
Sample Train Number
Meter Number
AH@
(a
Filter No.
Barometric Pressure, in. Hg 30. o
Assumed Moisture, % L>
Assumed Meter Temp., °F
Stack Gage Pressure ^_-~
100
"H2o
Probe Tip Diameter, in. . 1Z
Condensate Collected, ml.
'C' Correction Factor
Point
i
2
3
+
5"
<*
1
8
°\
\O
II
IZ.
Total
Avg.
Time
Min.
16
10
10
10
lo
10
\0
\0
10
|Q
10
10
12,0
Dry Gas Meter
Volume
ft3
Vm
1M-, fcH-
T8. M-0
AZ.OO
fts.q o
sq.ft-S
°fM, OO
^6,30
103. |0
1 0 1. ^ 0
nz, ao
in. Bo
12Z, 5-W-
\71.Z-3
52, b^
Inlet
Temp.
oF
^a
60.
64
QPv
=10
<^3
^T
100
100
\02_-
105
103
IUZ.
93
Outlet
Temp.
oF
6»fe>
76
V£
^77.
^fo
n^
to
fl/
8/
flZ
au
aW
^2S
^
Velocity
Head Ap
"H2°
/.£
/. S"
/,~7
/,7
2.^)
2.2.
z.s1
2,1
in
i,-}
Z,5"
z,^
Orifice AH
"H2°
0.-32.
O.32-
d.35
6\3£
fl. M 'I
^.a^
0.SO
0.5>4
O.S>4
0, S^A
O.S'd
0.0-^
S3!
. ,4f
Pump
Vacuum
"Hg
5
5
5"
^
5
f»
<^
6
6.
6
1
7
fc^.o
5,5
Filter
Temp.
op
-,
_-
_
_
_
_
.^
Impinger
»r
Condonoo-y
Temp . , ° F
Hfi
SO
5 1
5)
5? 2-
5" 2.
S3
S3
53
54
£(*
57
^
030
53
Stack Gas
Temp . , ° F
Ts
Q0
^0
qo
Sn
°\o
3r>
qo
r!rt
90
QO
^a
«70
lOflrt
C(f)
U)
VD
Leakage Rate @ 15 "Hg = p. p
cfm
PEDCo-EN VI RON MENTAL-
SUITE 6 . ATKINSON SQUARE
CINCINNATI. OHIO 45246
S1 3 l~7~7 1-433O
-------
GAS VELOCITY AND VOLUME DATA
VELOCITY TRAVERSE DATA
Test No.
Point
1
2
. 3
4 -v
5
(*
7
8
1
10
II
12-
Position
Inches3
M+7- $.7
3.3+7 --/0.S
/.7V7.-/3.7
/OJf?.-ni
/-?.2*7..;?A2
2 0.2+ 1*??.*
Sf.Zii.-ofcS
4W);W
44. &-):&.$
^0^7* -S^-l
<2.0'7-fo.Q
J&. &):&$
Total
Average
Reading, Ap
"H2°
O.2G7
0.31
6,30
0,31
0,3s"
(0.37
0.2S"
0,22.
0-7.2.
_
-
-
\/Ap
SIO
.557
.548
,557
.S^Z
,^08
,500
.0
7 /O
736
730
730
77.0
-
-
-
fe53O
72 £9
Location PEFLUOI?. IULET
Stack Inside Dimensions 57'
Stack Area, A = \r
Barometric Pressure, P, =
b
Stack Gage Pressure =
sg. ft.
"Eg
"H2°
Stack Abs . Pressure, P = . 0
S "j
Stack Gas Temp., T =
5 -
Molecular Weight of Stack Gas, M =
V = 174
°F + 460 =
Pb =
118
"Hg
Cp V T0 x 29.92 x 29' ft/min.
~P M~~
V =
s
ft/min. x 17, TZ sq. ft. = LJTTJ^O cfm
Q, Volume = _
Q , Standard Volume at 70°F and 29.92 "Hg(Wet Basis)=
Q x 530 x Pg = 17.7 x -14-1 q5Y> x
T 29.92
s
Qs = Qw x (100-WJ/100 =
a) From outside of port to sampling point,
Pitot tube "$"
Manometer
Thermometer
Data Recorder
Date z
PEDCo- ENVIRONMENTAL
SUITE 8 ATKINSON SQUARE
CINCINNATI. OHIO 45246
513 IT7 1-433O
-------
GAS VELOCITY AND VOLUME DATA
VELOCITY TRAVERSE DATA
Test No.
Point
1
z.
3
4
5"
(a
7
R
9
10
li
IZ
Position
Inchesa
0. 8
?-7
4.V
7.2-
/o./
14,4
76.1
30-4
33. V-
3S. %
37. -8
3^.6 '
Total
Average
Reading, Ap
"H2°
2,0
2,2
1.8.'
2.0
2.1
2,3.
?.:>
2, £
2,s
2,7
2.-?,
2,r
-
-
\/Ap
1.^14
1.483
1.341-
/,4l4
/.-HM-9-
i.SlT
l.sflf-
f.sBt-
),<^y|
l,(/43
1,^43
I.SV")
.
\8.22fl
I,S"H
T °F
s
87
HI
B7
^0
°\n
Srt
87
A7
B5T
R7
fl7
87
IDS'/
68
Location pe.FL.uog - OUTLET
Stack Inside Dimensions 140.$ " (h
Stack Area, A = 9,^ £" sq . ft.
S '"
Barometric Pressure, P, = 30,3
t>
Stack Gage Pressure = - V, 7 S"
Stack Abs. Pressure, P = - 7.1>
S
"Hg
88
Stack Gas Temp., T =
s
Molecular Weight of Stack Gas, M =
_ S
v
"H20 -
13.6
460 =
"Hg
= 174 \/Ap' Cp V T x 29.92 x 29* ft/min.
M
vs =
Q, Volume = -52.7
Q...
ft/min. x 8,'
sq. ft. =
cfm
Standard Volume at 70°F and 29.92 "Hg(Wet Basis)
x "3*1.13 =
Q x 530 x PS = 17.7 x H7 12.Q
T 29.92
Q = Q
ws. vw
(100-W)/100 =
a) From outside of port to sampling point.
Pitot tube "5"
Manometer
Thermometer
Data Recorder LA- g"
Date 2- a^ --70-
PEDCo - ENVIRONMENTAL
SUITE 8 ATKINSON SQUARE
CINCINNATI. OHIO -453.46
513 /7V 1-4330
-------
GAS VELOCITY AND VOLUME DATA
NJ
VELOCITY TRAVERSE DATA
Point
i
Z
3
4
?
6
n
8
C|
10
it
\-L
Position
Inches3
Total
Average
Re ad ing, Ap
"H2°
£>,l<0
Q,ZZ
b.11
f).C>& 7
b.~Z^
h.in
0.-Z3
0.7-1
Q.\°t
0, 17
0, H
0,1 (e
-
\MP
.400
*(,*
.5*6
\ja '\i>
,JD0
,520
,480
.U58
,45^7
.m-2.
.412.
.U00
-
?,007
,4S5
T °F
s
120
1?,S
^?S
^^o
nzs
I~LO
lio
Sb(t>$
TZW-
Test No.
Location
Stack Inside Dimensions
Stack Area, A = 11,12-
S *
sn' T.P.
sq. ft.
Barometric Pressure,
"3>o ,"
Stack Gage Pressure =
Stack Abs. Pressi
Stack Gas Temp.,
~ 6 <~\
Stack Abs. Pressure, P = - , p Q
5
"Hg
"H2°
"H20 + P. =
I3?6 b *
F + 460 = II 9 M-
11 Hg
R
Molecular Weight of Stack Gas, M = 2^
V = 174 V^ Cp V T x 29.92 x 29"* ft/min.
M
Q, Volume =
ft/min. x 11,12, sq. ft. =
cfm
Q , Standard Volume at 70°F and 29.92 "Hg(Wet Basis)=
Q x 530 x P^ = 17.7 x M-0. flQ9 x ^o."Z^- = }l
T 29.92 ilflg-
Qs = Qw
(100-W)/100 =
a) From outside of port to sampling point,
Pitot tube "6" TM P E
Manometer
Thermometer
Data Recorder RSft >'
Date 2 -CW-TO
PEDCo-ENVIRONMENTAL
SUITE 8 ATKINSON SQUARE
CINCINNATI. OHIO 45246
513 IT7 1-4330
-------
PEDCo- ENVIRONMENTAL
SUITE 8 ATKINSON SQUARE
CINCINNATI. OHIO 45246
51 3 IT7 1-433O
PARTICULATE SOURCE SAMPLING CALCULATIONS
TEST NO.
DATE
LOCATION
Vm = 17.71 Vx (P, +
m m n
S (460
V , Condensate Volume, (V,. - V.) =
c i i
ml. (From Sample Train)
Equiv. Cond. Vapor Vol., V = 0.0474 x V = 0.0474 x
at 70°F. c
scf
Total Gas Volume, V =
Net Sample Wt., M =
t w
s c
gms.
Concentration, C = M x 15.43
V7
scf
grains/scf at 70°F and
29.9" Hg, stack conditions
Emission Rate = C
x Qw
x 0.00857 =
Ibs/hr. of Particulate
-------
VELOCITY TRAVERSE DATA
Point
1
-2
3
4
£"
6
1
8
s^{
T °F
s
=/o
90
^0
^0
^^
9T
99
9T
^s
qc
^^
^5-
IMS
^3
GAS VELOCITY AND VOLUME DATA
Test No.
Location
Stack Inside Dimensions \4Q .^" s = Qw
(100-WJ/100 =
a) From outside of port to sampling point,
Pitot tube ~'s"
Manometer
Thermometer
Data Recorder
Date 3.-
LAG:
TV- 6-
PEDCo- ENVIRONMENTAL
SUITE 8 ATKINSON SQUARE
CINCINNATI. OHIO 45246
513 / 77 1-4330
-------
GAS VELOCITY AND VOLUME DATA
£>.
VELOCITY TRAVERSE DATA
Point
1
2.
3
4
-b
(o
1
6
°\
ID
\l
IZ.
Position
Inches3
Total
Average
Reading, Ap
"H20
,31 -?> .ZO
0.17
0,1ft
0.11
o,i&
0,11
A, 10
o, n
d.lA
0, \9
0,\1
0,1°)
-
-
\/Ap
,500
,>10
,*>1°*
,510
,52.<3
,^O
,447
.4I1
M2-^
,430»
412-
-H?>k
5.6-85"
,MT4
T °F
s
7(^0
^no
nt/)0
nr«^
"1^5
"J^O
n^s"
^ss
ns~o
^^0
^?s6
^/ss
n^7
qftsi
^ft
Test No.
Location
lULbT
Stack Inside Dimensions __ST__rvp.
i-in2. sg. ft.
Stack Area, A =
O
Barometric Pressure, P. = ^2,0 ,3
Stack Gage Pressure = -~ Oil 6
Stack Abs. Pressure, P = - p ,~l Q
Stack Gas Temp., T =
s
^SA
Molecular Weight of Stack Gas, M =
V = 174 \/Ap* Cp \r>
"Hg
"H2°
"H20 + PK = 30, l£ "Hg
13.6 b
°F + 460 = \2 1 & °R
2.^
x 29.92 x 29' ft/min.
M
Q, Volume =
Q x 530 x Pg = 17.7 x
T 29.92
s
Qc = 0 x (100-W)/100 =
S Wr i i .
ft/min. x |"?.1Z sq. ft. = 14.3,113 cfm
'Hg (Wet Basis
113
Q , Standard Volume at 70°F and 29.92 "Hg(Wet Basis)=
w
a) From outside of port to sampling point,
Pitot tube "c." T
Manometer
Thermometer
Data Recorder
Date -L- 1?- 12,
ft t-
PEDCo-ENVIRONMENTAL
SUITE 8 ATKINSON SQUARE
CINCINNATI. OHIO 4.524.6
513 /771-433O
-------
GAS VELOCITY AND VOLUME DATA
VELOCITY TRAVERSE DATA
Test No.
Point
1
2
3
4
S
It
7
fl '
S
\0
M
IZ
Position
Inches3
Total
Average
Reading, Ap
"H2°
i,S
\.s
1.1
1,7
2,0
2.Z
2,5
2,1
2,1
2,1
2.5
2,4
-
\/Ap
l,2Zi
i.rzs
1,303
1.303
miM-
t-4P>3
i.ssi
i,6>43
I.fc43
l,(*43
I.S8/
I.SM9
11,^3
|.4&fc
T °F
S
^0
3o
qo
°io
^10
^0
qo
^o
^»o
°/o
10
qo
\oe>o
qo
Location Q>EFVUQg.- OUTLET
Stack Inside Dimensions M-0,5"
Stack Area, A = Q,°( S
S
Barometric Pressure, P, =
D
Stack Gage Pressure =
Stack Abs. Pressi
Stack Gas Temp.,
sq. ft.
"Hg
- 1,
Stack Abs. Pressure, P =
S
"H20 -
13.6
460 =
"Hg
Molecular Weight of .Stack Gas, M -
S
v
= 174 \/Tp Cp V T x 29.92 x 29^ ft/min.
M
V =
S
Q, Volume =
Q x 530 x P£
T 29.92
ft/min. x
70°F and
= 17.7 x
sq. ft. =
Q , Standard Volume at 70°F and 29.92 "Hg(Wet Basis)=
Vi
. M-3 =
43 q.^, Q
Qc = QTT x (100-W)/100 =
o W
a) From outside of port to sampling point,
Pi tot tube ''S" TifPE
Manometer
Thermometer
Data Recorder
Date
LAE
PEDCo-ENVIRONMENTAL
SUITE 8 ATKINSON SQUARE
CINCINNATI. OHIO 45246
513 / 77 1-4330
-------
PEDCo- ENVIRONMENTAL
SUITE 8 ATKINSON SQUARE
CINCINNATI. OHIO A5246
513 777 1-433O
COMBUSTION GAS ANALYSIS
Plant
J £ "'*' > Comments
Location fa.tftJ7 C/T'Y
Date pi; ft , Q'tf* 3.S t /' T* 7&-
Operator 1? . <^£ /? ,s 7/ <-'
Test
No . Time
//^7 '.'*>/»
/ /9 y /?- A" 7
O i>" ^'Zn
3Mfter
3frt-Q
/f/t.E7 vi*>-
Sou?,,r
%(co2)
^0
y.t
.$> o
3,i
3.2.
/.r
%(02)
/C^C; ~)
/to
,S.3
/*:?
/<73
//. c?
0£FLL>0
%(CO)
-< o, a
^^.?
-^ ,-:;. 2..
< '
-------
APPENDIX C
TEST LOG
-------
February 24, 1972 Partly Cloudy 60-75°F
A.M.
7:45" Arrive at plant and set up equipment at defluorination
process.
8:30 Make preliminary pitot and temperature traverse.
Inlet site is only at 700°F - checked with thermocouple
and dial thermometer. Less gas flow measured at inlet
when compared to outlet.
9:30-10:30 Make moisture runs.
11:55 Start fluoride test 1 on this process. Use 1/2"
stainless steel probe at inlet site.
P.M.
12:00 Scrubber water samples taken. Inlet scrubber water
is taken in lagoon at pump suction, temp.=80°F.
Discharge is taken in pipe leading to pond.
12:35 Inlet sampling train can't maintain flow due to plugged
nozzle. Change from 3/8 to 1/4" nozzle. Wash out
3/8" nozzle into sample container.
1:00 Orsat Sample.
1:45 Inlet nozzle and/or probe is plugged on inlet train
again. Replaced nozzle, but still plugged. Stop
sampling after 58 minutes of sample time.
2:00 Complete outlet test.
2:15 Take scrubber water samples.
-------
2:30- 3:00 State of Florida sampling at outlet site.
4:20 Start test no. 2 at outlet.
4:35 Start test no. 2 at inlet - use 12 points at 8 minutes
each since train cannot contain a 2 hour sample.
4:45 Scrubber water samples.
5:00 Inlet train plugged again. Changed to new^nozzle
and probe; continued "for another, hour.
6:00 Opacity <10%.
6:20 Complete outlet sample and discontinue inlet sampling.
6:25 Scrubber water sample 91°F at inlet to scrubber
104°F at discharge of scrubber
6:30 Orsat analyses
NOTE: Outlet train filter was greenish-yellow in color.
8:00 Leave plant.
February 25, 1972 Partly Cloudy 60-75°F
A.M.
7:45 Arrive at plant.
9:00 Start Run 3, inlet train to run 8 minutes at each of
12 points.
9:20 Scrubber water sample. Water inlet 85°F pH - 6.5
Water outlet 100°F pH * 3.2
9:50 Orsat analyses..
-------
NOTE: Visible fume is passing through first three impingers
and filter on inlet train and is apparently reacting
with silica gel. Silica gel very dark at completion
of test.
10:25 Scrubber water sample.
10:30 Opacity = 10%.
Inlet probe requires tapping with screwdriver to
prevent plugging.
10:45 Complete inlet sample.
11:00 Complete outlet sample.
11:00-12:30 Clean up trains and pack all equipment.
12:30 Leave plant.
-------
APPENDIX D
PROJECT PARTICIPANTS
-------
Project Participants and Titles
PEDCO-ENVIRONMENTAL SPECIALISTS, INC.
Richard W. Gerstle, P.E., Engineer in charge of sampling
Larry A. Elfers, Chemist
Robert S. Amick, Engineer
Gene Forte, Technician
Joseph Geiger, Technician
EPA
J. Rom - In charge of sampling
L. Evans - In charge of process operations liaison
-------
APPENDIX E
RECOMMENDATIONS
-------
Recommendations
The sampling train used during these tests was apparently
not.capable of absorbing high concentrations of fluorides.
This was evident at the inlet sampling site on the defluor-
ination process where the silica gel in the fourth impinger
became very dark in color and was apparently affected by
fluorides passing into this impinger. We recommend a strong
reducing agent such as sodium arsenite and/or a strong basic
solution be used in the impingers whenever high concentrations
of fluorides and free fluorine are suspected. As used in
these tests, the collection efficiency of the sampling train
is probably less than 95%. Further studies of sampling
fluorides in percentage quantities appears necessary.
------- |