TEST NUMBER 72-CI-15
DICALCIUM PHOSPHATE
BORDEN CHEMICAL COMPANY
PLANT CITY, FLORIDA
FEBRUARY 22 - 23, 1972
-------
PEDCo-ENVIRONMENTAL
SUITE B • ATKINSON SQUARE
CINCINNATI. OHIO -4 5 2 4 6
513 777 1-433O
TEST NUMBER 72-CI-15
DICALCIUM PHOSPHATE
BORDEN CHEMICAL COMPANY
PLANT CITY, FLORIDA
FEBRUARY 22 - 23, 1972
Prepared by
Richard W. Gerstle, P.E,
By
PEDCo-Environmental Specialists, Inc,
•Cincinnati, Ohio
Contract No. 68-02-0237, Task 1
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TABLE OF CONTENTS
SECTION PAGE
I. INTRODUCTION 1
II. SUMMARY OF RESULTS 3
III. DICALCIUM PHOSPHATE PROCESS 6
IV. SAMPLING PROCEDURES 7
V. ANALYTICAL PROCEDURES 10
VI. APPENDIX 11
Appendix A - Emission Calculations
and Results
Appendix B - Field Data
Appendix C - Test Log
Appendix D - Project Participants
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I. INTRODUCTION
Stack emission tests were conducted, and related process
samples were taken during the period February 22 to 25/ 1972,
at the Borden Chemical Company's phosphate animal feed plant
in Plant City Florida. Three tests were made to determine
total fluoride emissions on the dicalcium phosphate operations
during the period of February 22 and 23.
According to the terms of PEDCo's contract with EPA, only
stack gas measurements, selected feed and product samples,
and scrubber water samples were to be taken by PEDCo. Stack
gas samples were taken in the duct leaving the kiln (before the
cyclones) and in the stack after the scrubber. Figure 1 shows
the location of the sampling points. Three simultaneous sets
of samples were taken at these sites to determine total fluoride
content of the gas streams. Moisture, carbon dioxide, and
oxygen content of the gas streams were also measured; and
velocity, temperature, and total gas flow were determined for
each test. Samples of phosphate rock feed, limestone, phosphoric
acid, product and scrubber water were also taken during each run.
Each stack gas sample on the dicalcium process extended over a
two hour period. All.process data and operating procedures
were obtained by EPA personnel. Sample analyses and emission
calculations were also to be performed by EPA staff.
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65"
:— Sediment 15"
aeep at center
22.5% of area is blocked
Detail of Sampling Site C
(Inlet)
Burner
Product
Feed
Detail of Sampling Site E
(Outlet)
65"
Outlet Sampling
Site - Point
Double
Cyclone
IS'
Settling
Chamber
18" Bucket elevator vent
Recycle
Exit Stacl
Scrubber
FIGURE 1. DIAGRAM OF DICALCIUM PHOSPHATE PROCESS
AND SAMPLING SITES
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II. SUMMARY OF RESULTS
The plant was operating under normal process conditions
during all of the test runs. No major sampling problems were
encountered; however, two irregularities should be mentioned.
First, at the inlet to the scrubber a thick layer of sediment
was found in the bottom of the duct. This sediment layer was
2
measured and although the real area of the duct was 19.7 Ft ,
2
the effective area was estimated at 15 Ft . Secondly, during
the first run at the outlet, one of the glass impinger connectors
cracked. The sampling was stopped and the cracked connector
replaced before continuing the test. It should be noted that
the insoluble fluorides listed for this sample are extremely
high compared to the other test runs, and it is likely that
the sample was contaminated.
A complete summary of stack gas conditions and emission
levels for each test run are given in Tables 1 and 2.
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TABLE 1. SUMMARY OF RESULTS—SCRUBBER INLET
Run Number
Date
Stack pressure, inches Hg
Stack gas moisture, % volume
Average stack gas temperature, °F.
Stack gas flow rate @ S.T.P.*, SCFM
Vol. gas sampled @ S.T.P.*, SCF
Fluoride, water soluble, mg
Fluoride, total, mg
Fluoride, water soluble, gr/SCF
Fluoride, total, gr/SCF
Fluoride, water soluble, gr/CF stk. cond.
Fluoride, total, gr/CF stk. cond.
Fluoride, water soluble, Ib/hour
Fluoride, total, Ib/hour
Fluoride, water soluble, Ib/ton P20r Fed.
Fluoride, total, Ib/ton P,,05 Fed.
1
2/22/72
30.54
7.1
265
27003
81.39
12.1
176.1
0.002
0.033
0.002
0.023
0.53
7.71
0.13
1.93
2
2/23/72
30.43
5.2
227
29497
85.46
20.2
169.2
0.004
0.030
0.003
0.023
0.92
7.71
0.23
1.93
3
2/23/72
30.41
5.2
234
29889
85.79
20.4
70.4
0.004
0.013
0.003
0.009
0.94
3.24
0.23
0.81
Dry, 70°F., 29.92 inches Hg.
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TABLE 2. SUMMARY OF RESULTS-SCRUBBER OUTLET
Run Number
Date
Stack pressure, inches Hg
Stack gas moisture, % volume
Average stack gas temperature, F.
Stack gas flow rate @ S.T.P.*, SCFM
Vol. gas sampled @ S.T.P.*, SCF
Fluoride, water soluble, mg
Fluoride, total, mg
Fluoride, water soluble, gr/SCF
Fluoride, total, gr/SCF
Fluoride, water soluble, gr/CF stk. cond.
Fluoride, total, gr/CF stk. cond.
Fluoride, water soluble, Ib/hour
Fluoride, total, Ib/hour
Fluoride, water soluble, Ib/ton PpOr Fed.
Fluoride, total, Ib/ton
Scrubber efficiency, %
Fed.
1
2/22/72
30.6
8.1
122
30917
119.89
0.12
121.12
0.0000
Q-O/^-G,
0.0000
0.0133
0.004
4.12
0.001
1.03
46.5
2
2/23/72
30.5
8.1
120
29135
113.58
3.3
3.3
0.0004
0.0004
0.0004
0.0004
0.11
0.11
0.03
0.03
98.5
3
2/23/72
30.5
8.1
120
32260
124.53
3.5
3.5
0.0004
0.0004
0.0004
0.0004
0.12
0.12
0.03
0.03
96.2
Dry, 70°F., 29.92 inches Hg.
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III. DICALCIUM PHOSPHATE PROCESS
In this process, defluorinated phosphate rock, limestone,
andt phosphoric acid are fed to the upper end of a gas-fired,
inclined rotary kiln. Dried product leaves the kiln at the
lower burner end. Dust laden gases leave the charging end of
the kiln at a temperature of about 270°F, enter two large
diameter cyclones in parallel, a scrubber, and a 65 inch
diameter stack at a temperature of 100 to 110°F. The duct
leading from the kiln to the cyclones was filled with about
15 inches of sediment.
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IV. SAMPLING PROCEDURES
All gas streams were sampled isokinetically by using a
modified EPA particulate sampling train and following the
sampling procedures described in Method 5 of the Federal
Register of December 23, 1971. The sampling train as shown
in Figure 2 consisted of a stainless steel button-hook nozzle,
a heated Pyrex glass probe contained in a steel sheath, a
Greenburg-Smith impinger without a tip, a second impinger with
a tip, a third impinger without a tip, an 80 millimeter Whatman
No. 1 paper filter, and a final impinger containing approxi-
mately 200 grams of indicating type silica gel. The first
and second impingers contained 100 ml each of distilled water
at the beginning of each test. The third impinger was initially
dry. All impingers were.contained in an ice-water bath and the
temperature of the gases leaving the fourth impinger was in the
65 to 70°F range. The filter was not heated. An air tight
vacuum pump, dry gas meter, orifice, and associated valves,
connectors, thermometers, and manometers completed the train.
A stainless steel probe was used on the inlet site in the
defluorination process because of the high temperatures
encountered there. ;
A type 'S' pitot tube was attached to the probe to measure
the velocity head of the stack gas. The sampling rate was
continually adjusted to maintain isokinetic sampling rates by
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THERMOMETER
FlirbH HOLDfR
HEVERSE-TYPE
PITOT TUBE
STACK
CHECK
'VALVE
DRV TEST METER
FIGURE 2 . SAMPLING TRAIN USED TO DETERMINE
FLUORIDE CONCENTRATIONS
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means of a nomograph which related the pressure drop across the
orifice after the meter with the velocity head measured by the
pitot tube. Stack gas temperatures were measured with long
stem dial thermometers.
In a typical run to determine fluoride concentrations,
the train was assembled and checked for leaks by plugging the
first impinger and drawing a vacuum of 15" Hg. The probe and .
nozzle assembly was then attached to the impinger and the train
positioned at the first sampling point. Each point along the
stack diameter was sampled for ten minutes. A two hour sampling
period was used. At each point the velocity head, stack gas
temperature, final impinger temperature, meter temperatures,
meter reading, pump suction pressure, and orifice pressure drop
was measured and recorded. All data sheets for these tests are
attached in Part B of the Appendix.
Upon completion of sampling, the train was completely
disassembled, the condensate volume measured, and the silica
gel weighed on a triple beam balance at the site. The water
in the impingers was poured into plastic (Nalgene) wide mouth
bottles. The paper filter and all washings from the probe and
all glassware were also placed in this same container. When
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necessary the probe was also brushed to remove solid matter.
All train components were then dried with acetone and the train
reassembled for the next run. Each container was immediately
labeled.
Feed, product, and scrubber water samples were also placed
in plastic bottles and labeled. All samples were submitted
to Mr. J. Rom of EPA for future analysis.
Moisture content of the gas stream was determined by making
a preliminary run with this same train without a filter. This
was accomplished by running the train at a sampling rate of
approximately 0.75 cfm for 30 minutes and measuring the moisture
condensed and the weight gain of the silica gel.
Carbon dioxide and oxygen content of the gas stream were
measured with a standard Orsat apparatus by drawing samples
from the stack directly into the Orsat apparatus through a one-
quarter inch diameter stainless steel probe. The probe was
carefully purged with stack gas before taking the sample. This
procedure was deemed sufficiently accurate to determine the
molecular weight of the stack gases.
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V. ANALYTICAL PROCEDURES
Water soluble fluorides were determined by a sulfuric
acid distillation followed by the SPADNS-ZIRCONIUM LAKE METHOD,
Water insoluble fluorides were first fused with NaOH followed
by a sulfuric acid distillation then by the SPADNS-Zirconium
Lake Method.
10
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VI. APPENDIX
11
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APPENDIX A
EMISSION CALCULATIONS AND RESULTS
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NOMENCLATURE
PB - Barometric pressure, inches Hg
PS - Stack pressure, inches Hg
As - Stack area, sq. ft.
TS - Stack temperature, °R
TM - Meter temperature, R
H_ - Average square root of velocity head, /inches FLO
AH - Average meter orifice pressure differential, inches H?0
AN - Sampling nozzle area, square feet
CP - S-type pitot tube correction factor
VM - Recorded meter volume sample, cubic feet (meter conditions)
VC - Condensate and silica gel increase in impingers, mi Hi liters
Po - Pressure at the dry test meter orifice, PB + To~g- inches Hg
STP - Standard conditions, dry, 70°F, 29.92 inches Hg
VWV - Conversion of condensate in milliliters to water vapor in cubic feet (STP)
VSTPD - Volume sampled, cubic feet (STP)
VT - Total water vapor volume and dry gas volume samples, cubic feet (STP)
W - Moisture fraction of stack gas
FDA - Dry gas fraction
MD - Molecular weight of stack gas, Ibs/lb-mole (dry conditions)
MS - Molecular weight of stack gas, lbs/lb/-mole (stack conditions)
GS - Specific gravity of stack gas, referred to air
EA - Excess air, %
U - Stack gas velocity, feet per minute
OS _ Stack gas flow rate, cubic feet per minute (stack conditions)
OD - Stack gas flow rate, cubic feet per minute (dry conditions)
OSTPD - Stack gas flow rate, cubic feet per minute (STP)
PISO - Percent isokinetic volume sampled (method described in Federal Register)
Time - Total sample time, minutes
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EQUATIONS FOR CALCULATING FLUORIDE EMISSIONS
VWV = .(0.0474) x (VC)
VSTi'D = (17.71 x (VM) x (PB + —H_ ) -=- TM
'13.6
VI = (V'.-:V) H- (VSTI'D)
W = (WV)-h(VT)
FDA = (1.0) - (W)
MD - (0.44 x % CO,) + (0.32 x % 02) + (0.28 x % N2) + (0.28 x % CO)
MS = (MD x FDA) + (IS x W)
GS = (MS) 4- (28.99)
EA = [(100) .x (% 02 - £££)] -7- [(o.266 x % N'2) - (% 02 - ^£) ]]
U = (17A) x (CP) x (H) x v/(TS >: 22.92)-7-(GS x PS)
QS = (JJ) x (AS)
QD = (QS) x (FDA)
QSTPD = (530) x (QD)-H(TS).x (PS) v (29.92)
PISO = L(o-°°267 x VC x TS) V (p0 x TS x VM -J-TM)] -^- [(Time x U. x PS x A>i)]
Fluoride Enissions:
MG - Milligriir.-.s of fluoride fron lab analysis
Grains/SCF = (0.01543) x (MG) -I- VSTPD
Grains/CF, Stack Cond. = (17.71) x (PS) x (FDA) x (Grains/SCF) -7- (TS)
Lbs/iiour = (Graias/SCF) x (0.00357) x (QSTPD)
i^Oj Fed - To:is/lioi:i-, deicr:?.inod fror.i plcr.it: data
Lbii/Lon P90r Ftul = (Ibs/hour) ~ (Tons/hour P-,0,. Fed)
*~ J * *- .)
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EMISSION DATA
BORDEN CHEMICAL
DICALCIUM PHOSPHATE INLET
1) Run Number
2) Date
3) Time Began
4) Time End
5) Barometric Pressure, In Hg
6) Meter Orifice Pressure Drop, in H^O
7) Vol Dry Gas, Meter Cond . Cubic Feet
8) Average Gas Meter Temperature, Deg F
9) Vol Dry Gas, S.T.P., Cubic Feet
10) Total H20 Collected, Ml
11) Vol H20 Vapor Collected, S.T.P., Cu.Ft.
12) Stack Gas Moisture, Percent Volume
13) Assumed Stack Gas Moisture, Pet Vol
14) Percent C02
15) Percent 0^
16) Percent CO
17) Percent N2
18) Percent Excess Air
19) Molecular Weight of Stack Gas, Dry
20) Molecular Weight of Stack Gas, Stk Cond.
21) Stack Gas Specific Gravity
22) Avg. Square Root (Vel Head) , in H20
23) Average Stack Gas Temperature, Deg F
24) Avg. Square Root (Stk Temp x Vel Head)
25) Pitot Correction Factor
26) Stack Pressure, in Hg , Absolute
27) Stack Gas Vel, Stack Cond, F.P.M.
28) Stack Area, Sq. Feet
29) Effective Stack Area, Square Feet
30) Stack Gas Flow Rate, S.T.P., SCFMD
31) Net Time of Test, Minutes
32) Sampling Nozzle Diameter, Inches
33) Percent Isokinetic
34) Fluoride - Water Soluble, MG
35) Fluoride - Total, MG
36) Fluoride - Water Soluble, GR/SCF
37) Fluoride - Total, GR/SCF
38) Fluoride - Water Sol., GR/CF,STK CND .
39) Fluoride - Total, GR/CF , STK CND.
40) Fluoride - Water Soluble, LB/HOUR
41) Fluoride - Total, LB/HOUR
43) Fluoride - Water Sol., LB/TON P205 FED
44) Fluoride - Total, LB/TON P205 FED
1
2/22/72
14:25
16:25
30.6
1.33
86.22
116
81.39
131.9
6.25
7.1
2
0.8
19.2
0.2
79.8
898
28.9
28.12
0.97
0.665
265
17.899
0.83
30.54
2597.9
19.7
15
27003
120
0.25
110.5
12.1
176.1
0.0023
0.0333
0.0016
0.0231
0.5298
7.7109
0.1325
1.9277
2
2/23/72
10:30
12:30
30.5
1.39
87.987-
98.1
85.457
99.7
4.73
5.2
6
0.4
19.5
0.2
79.9
1047
28.84
28.28
0.98
0.696
226 .7
18.231
0.83
30.43
2643.6
19.7
15
29497
120
0.25
106.2
20.2
169.2
0.0036
0.0305
0.0027
0.0229
0.0202
7.7079
0.2301
1.324
3
2/23/72
15:25
16:25
30.5
1.46
89.159
103.5
85.785
100 .1
4.74
5^
. 2
6
0.5
19 .5
0.2
79.8
1062
28.86
28.29
0 .98
0.709
233 .7
18 .673
0 .83
30.41
2707.8
19.7
15
29889
120
0.25
105 . 2
20.4
70.4
0 .0037
0 .0126
0 .0027
0.0093
0 .9381
3 .2372
0 .2345
0.8093
***S.T.P. «-+DRY, 70 DEGREES F, 29.92 INCHES MERCURY***
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EMISSION DATA
BORDEN CHEMICAL
DICALCIUM PHOSPHATE OUTLET
1) Run Number
2) Date
3) Time Began
4 ) Time End
5) Barometric Pressure, In Hg
6) Meter Orifice Pressure Drop, in H-O
7) Vol Dry Gas, Meter Cond . Cubic Feet
8) Average Gas Meter Temperature, Deg F
9) Vol Dry Gas, S.T.P., Cubic Feet
10) Total H20 Collected, Ml
11) Vol H20 Vapor Collected, S.T.P., Cu.Ft.
12) Stack Gas Moisture, Percent Volume
13) Assumed Stack Gas Moisture, Pet Vol
14) Percent C02
15) Percent 02
16) Percent CO
17) Percent N2
18) Percent Excess Air
19) Molecular Weight of Stack Gas, Dry
20) Molecular Weight of Stack Gas, Stk Cond.
21) Stack Gas Specific Gravity
22) Avg. Square Root (Vel Head) , in H20
23) Average Stack Gas Temperature, Deg F
24) Avg. Square Root (Stk Temp x Vel Head)
25) Pitot Correction Factor
26) Stack Pressure, in Hg, Absolute
27) Stack Gas Vel, Stack Cond, F.P.M.
28) Stack Area, Sq. Feet
29) Effective Stack Area, Square Feet
30) Stack Gas Flow Rate, S.T.P., SCFMD
31) Net Time of Test, Minutes
32) Sampling Nozzle Diameter, Inches
33) Percent Isokinetic
34) Fluoride - Water Soluble, MG
35) Fluoride - Total, MG
36) Fluoride - Water Soluble, GR/SCF
37) Fluoride - Total, GR/SCF
38) Fluoride - Water Sol., GR/CF,STK CND .
39) Fluoride - Total, GR/CF,STK CND.
40) Fluoride - Water Soluble, LB/HOUR
41) Fluoride - Total, LB/HOUR
43) Fluoride - Water Sol., LB/TON ?205 FED
44) Fluoride - Total, LB/TON P205 FED
1
2/22/73
14:25
16:30
30.6
2.76
126.76
116.9
119.889
222.9
10.57
8.1
10
0.5
19
0.2
80.3
768
28.84
27.96
0.96
0.447
122.1
10.782
0.83
30.6
1567.8
23.04
23.04
30917
120
0.375
9711
0.12
121.12
0
0.0156
0
0.0133
0.0041
4.1223
0.001
1.0306
2
2/23/72
10:35
12:35
30.5
2.57
120.22
115.4
113.577
210.7
9.99
8.1
10
0.3
19.5
0.2
80
1032
28.83
27.95
0.96
0.421
120
10.138
0.83
30.5
1476.9
23.04
23.04
29135
120
0.375
97.6
3.3
3.3
0.0004
0.0004
0.0004
0.0004
0.1117
0.1117
0.0279
0.0279
3
2/23/73
14:25
16:25
30.5
3.06
130.16
108.9
124.529
232.9
11.04
8.1
10
0.4
19.6
0.2
79.8
1129
28.85
27.96
0.96
0..467
120
11.236
0.83
30.5
1636.4
23.04
23.04
32260
120
0.375
96.6
3.5
3.5
0.0004
0.0004
0.0004
0.0004
0.1197
0.1197
0.0299
0.0299
***S.T.P. <-->-DRY, 70 DEGREES F, 29.92 INCHES MERCURY***
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BORDEN CHEMICAL
DICALCIUM PHOSPHATE SCRUBBER EFFICIENCY
V.
/
SCRUBBER
\
/
Run No.
1
2
3
Flow
29497
29889
Total
Fluoride
27003 (DSCFM) 7.71 (#/hr)
7.71
3.24
Efficiency
46.5
98.5
96.2
Flow
30917
29135
32260
Total
F1 uoride
4.12
0.11
0.12
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APPENDIX B
FIELD DATA
-------
Preliminary velocity traverse data sheets and meter
data sheets for the moisture run and three fluoride determination
runs at the scrubber inlet and outlet sites are included in this
section for the dicalcium phosphate process. These data sheets
are presented as follows:
Preliminary velocity traverse at inlet to scrubber
Preliminary velocity traverse at outlet of scrubber
Meter data sheet for moisture determination at inlet to scrubber
Meter data sheet for moisture determination at outlet of scrubber
Meter data sheet for fluoride determination at inlet to scrubber
Test 1
Meter data sheet for fluoride determination at outlet to scrubber
Test 1
Meter data sheet for fluoride determination at inlet to scrubber
Test 2
Meter data sheet for fluoride determination at outlet to scrubber
Test 2
Meter data sheet for fluoride determination at inlet to scrubber
Test 3
Meter data sheet for fluoride determination at outlet to scrubber
Test 3
Velocity traverse data (taken from meter data sheets) Test 1
Inlet
Velocity traverse data (taken from meter data sheets) Test 1
Outlet
-------
Velocity traverse data (taken from meter data sheets) Test 2
Inlet
Velocity traverse data (taken from meter data sheets) Test 2
Outlet
Velocity traverse data (taken from meter data sheets) Test 3
Inlet
Velocity traverse data (taken from meter data sheets) Test 3
Outlet
Orsat Analyses
-------
GAS
VELOCITY TRAVERSE DATA
Point
1
2.
3
M-
C
L
V
R
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n
IZ
13
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IS"
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71
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Position
Inches3
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I.S
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Total
Average
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VELOCITY AND VOLUME DATA
Stack Inside Dimensions
Stack Area, A = EbT \S. (
s
Stack Gage Pressure =
S
OL.O.CK L?aS leiup. / J. ^ —
Molecular Weight of Stack
VI "7 A \/Ar> /"ri \/ T v *;
— J. / 1 y iip Cp y 1 X i
S S -
V = I^T ^ 'W\ /*• \&S M "^0^ * -
Test No. Pp^E \,\.^ \ *J IX R-V
Location Bo^tT^uS
, - TOuCT— D> Cft\
fc>0' 4> ( OifcT to COT-rovO
3 sq. ft.
-2(~} I "Hrr
O^/. L/» My
- o,^ "H^O
••'- • 0 4- P — ^f\ CT "^ " Hrr
— O i n n2U T- fw -PCJ . ^ _I> «g
13.6 b
7 U ^^ O T? -i- A £ n — r"" 7 /"\ CT O "D
s-H-j rT^ou — / c/ 3> *^
: Gas, M_ = 2.°[
9.92 x 29' ft/min.
P M
_«?_.. s
2>0,i3 * "2^
Q, Volume = 23ct°l ft/min. x \S.O sq. ft. =3*£ -5 5/Od).
nob
s"
"^V*— (i6"P"^
^f^"
gg_p,*r
Manometer 0-\,Q
Thermometer DiKL
Data Recorder R.A.
Date •Z-2.2-TZ.
PEDCo- ENVIRONMENTAL
SUITE 8 • ATKINSON SQUARE
CINCINNATI. OHIO 452-4-6
513 / 77 1-433O
-------
GAS VELOCITY AND VOLUME DATA
VELOCITY TRAVERSE DATA
Point
1
7.
3
4-
S
(*
1
&
q
10
i )
il
13
14
1?
!U
17
/ft
rt
zo
zf
Z2
23
z^f
Position
Inches3
l.d
2.1
?.§•
s-.i
t.8
a.fo
1 0, s"
IT, 63
15,0
1*7. fe
^l..z
zs.a
2°i.Z
4-3. fc
M^Z
50,0
S2t
S4,b
5S.8
58,3
t*0,d
frl.s
bl.O
teH".)
Total
Average
Reading, Ap
"H20
0,r
-3RT
,3^
.40(5
,«-/00
,uJZ«-l
-qzM
.Mi^/
.MU1
,4-47
4S&
.441
W47
,g?8
M£<3
U47
447
41/1
441
4^^
W47
ual
0./l~7
.1^72.
T op
s
no
I
i
i
/
vf
no
Test No.
Location
Stack Inside Dimensions
Stack Area, A = 23.04-
S "—' J - . -i..
Barometric Pressure, P, =
Stack Gage Pressure =
Stack Abs. Pressure, P =
sq. ft.'
"3Q.
O
O
_ "Hg
"H2°
"H20 + P,
T3T6
= "50.
"Hg
I 10
Stack Gas Temp., T =
S ~ ~~
Molecular Weight of Stack Gas, M =
9
°F + 460 =
V = 174 \/Ap* Cp V T0 x 29.92 x 29' ft/min.
Q, Volume =
30,0*0
ft/min. x Z3>.O_»f sq. ft. =
Vv
Standard Volume at 70°F and 29.92 "Hg (Wet Basis) =
30, (^ = 3
Q x 530 x P£ = 17.7 x 33f>C/.|
T 29.92 "^^
s
QB = Q x (100-W)/100 =
510
a) From outside of port to sampling point.
Pitot tube ^
Manometer 6-//0 " MT.O
_
Thermometer
Data Recorder
Date Z
- E.
PEDCo- ENVIRONMENTAL
SUITE 8 • ATKINSON SQUARE
CINCINNATI. OHIO 45346
513 / 77 1-433O
-------
PARTICULATE FIELD SAMPLING METER DATA
Plant
Filter No.
Run Number
Location I
\STUR\E.
Date 2.-7.'2.-r7 "^ Time \ 2 '.
Barometric Pressure, in. Hg "3<3- C.
Assumed Moisture, % —
Assumed Meter Temp.,
Operator 6-F .
Sample Train Number —
Meter Number —
AH@
l.SZ (p O.1S
Stack Gage Pressure - O,°( "E^
Probe Tip Diameter, in. —
Condensate Collected, ml. | 5". Co
'C1 Correction Factor —
Point
30"INJ
Total
Avg.
Time
Min.
•„
•*>o
•zo
Dry Gas Meter
Volume
ft3
Vm
70r7, 9^O
T36.97/
3\,OII
Inlet
Temp.
oF
^a
lie
IZZ-
33Z
1 1 1
Outlet
Temp.
oF
^2.
*\(*
\66
•Z8&
°I6,
Velocity
Head Ap
"H2°
—
__
—
—
—
Orifice AH
"H20
—
—
—
_ _
—
Pump
Vacuum
"Hg
\O
) 6
16
3o
\f)
Filter
Temp.
oF
_
—
— _-
—
—
Impinger
or
Condenser
Temp . , ° F
6*5*
-1 I
nz_
Zofc
(A
Stack Gas
Temp. , °F
T
s
"2 4*<0
i.(*a
?.(~a
VSC)
•2.LeC>
Leakage Rate @ lS"Hg =
/ 36.
cfm
PEDCo-ENVIRONMENTAL
SUITE 8 • ATKINSON SQUARE
CINCINNATI. OHIO 452.46
SI 3 IT7 1-433O
-------
PARTICULATE FIELD SAMPLING METER DATA
Plant
Filter No.
mo\STaeE TEST
- t>i Gv\
Run Number
Location
Date iL-~t1~~\"L. Time 1 7J. O Q
Operator LN& 1 T F 6-
Barometric Pressure, in._Hg
Assumed Moisture, % -
Assumed Meter Temp.,
Stack Gage Pressure
'F —
."H2°
Sample Train Number
Meter Number _ Z
AH@ i
Probe Tip Diameter, in.
(D
Condensate Collected, ml.
'C' Correction Factor
Point
30" IK/
Total
Avg.
Time
Min.
STAfcT
to
2.0
30
30
—
Dry Gas Meter
Volume
ft3
Vm
52^.^00
53^.400
5M-T, ^00
SfcO. «410
-^o.nno
—
Inlet
Temp.
OF
°iif
\\Z
131
1^
M^
\10
Outlet
Temp.
oF
08
88
^0
q^-
3L»(9
90
Velocity
Head Ap
"H2°
—
—
—
—
—
—
Orifice AH
"H2°
—
_
^~
—
—
—
Pump
Vacuum
"Hg
Ifi.O
\fe,O
18.0
13.0
kl.O
lt.A
Filter
Temp.
oF
—
—
— .
«-
—
—
Impinger
or
Condenser
Temp . , ° F
TZ.
G.I
(J\
T*>
21 S"
r^
Stack Gas
Temp . , ° F
Ts
\20
17.0
I7.O
\7.0
M-ftO
IZO
(Ti
Leakage Rate @ IS' "Hg =
O
cfm
PEDCo- ENVIRONMENTAL-
8 • ATKINSON SQUARE
CINCINNATI. OHIO 45246
513 /77 1-433O
-------
PARTICULATE FIELD SAMPLING METER DATA
Plant
Run Number
Time
Location Pi C*\
Date a-7
Operator
Sample Train Number
Meter Number
AH@
6- F
|. 52
Q.
Filter No.
Barometric Pressure, in. Hg 30.
Assumed Moisture, % 2L.
Assumed Meter Temp., °F
Stack Gage Pressure -
O
"H2°
"
Probe Tip Diameter, in. Q. 2.5
Condensate Collected, ml. |3 \.(
'C1 Correction Factor £>• ^
Point
1
2
3
4
5
&
7
«
°»
10
II
1?
Total
Avg.
Time
Min.
10
10
fo
10
10
10
10
10
(0
10
\6
10
\zo
Dry
Volume
ft3
Vm
n^^. L><4°i
T4-4. 12 ^>
14^. 70O
iSb^bO
^fe^. 310
Tll.ROO
Tn°i, 5.^0
TS7.450
^^.s. 41 ^}
fto??.3ad
an, ^\o
Aie. vzo
62?. 8^
8&.220
Gas Mete
Inlet
T^nn
OF
\os
\ \o
"4-
MA
\11L
123
I7«4-
\^a
\^o
\TO
\7Z
122
m2-4
m
sr
Outlet
rr^Tnri
oF
"to
\\o
\i 0
n«4
IM-
ifo
>7
1 R
)4
'4
12.
nz
I3(*/
113
Velocity
Head Ap
"H 0
H2U
0.7.fl
0, 2-^
£>, 3fl
0. H-Z
0. 4^
O.J3
o.s"U-
0,^2.
0.5^
^,^3
A 4-7
O.UU-
Orifice AH
"H2°
0. S3
o, n M-
1.12.
\. 3O
K>4O
1.^5"
\,(aO
ISO
1, f/,^3
I,«T*T
1,4-tf
1.31
\S.°IO
\.33
Pump
Vacuum
"Ha
ny
3
3
4
S"
5"
69
^7
T
«
A
A
A
64
5"
Filter
Temp.
op
—
—
—
_^
—
—
—
—
—
—
_
—
—
Impinger
or
Pn n r\ n n r n f •
Temp . , ° F
fefl
t,£
L>£
(*£
(al
<*<*
left
10
70
70
70
70
818
fc8
Stack Gas
Temp . , ° F
T
S
e^o
2Lfo(D
2.5--S"
2.6?O
•2L^S".
2.^^
Zfo5"
1 ^^
Z(«.r
2nr
z-^r
-270
3 I SO
2.^5"
Leakage Rate @ |5 "Hg =
Q cfm
5m
8). 00
PEDCo-ENVIRONMENTAL.
SUITE 8 ' ATKINSON SQUARE
CINCINNATI. OHIO 45246
513 /77 1-4330
-------
PARTICULATE FIELD SAMPLING METER DATA
Plant
Run Number
Time
Location P\-C*\
Date a-
Operator
Sample Train Number
Meter Number
AH@
Qu-V\g,4
Filter No.
Assumed Meter Temp., °F
Stack Gage Pressure Q
Barometric Pressure, in. Hg 30,
Assumed Moisture, % I 0
-"H2°
Probe Tip Diameter, in. 0,1"!
Condensate Collected, ml. 11.7. .<\
'C1 Correction Factor . ^S"
Point
/
Z
3
14
S
6,
<7
ft
9
10
II
IZ
Total
Avg.
Time
Min.
10
16
10
10
10
10
10
10
in
10*
10
10
\-2_O
Dry Gas Meter
Volume
ft3
Vm
sto.s'a
SVfZO
51 R.3O
5ftA,60
.Tss.i.n
40«i. 10
L.2.0, 6O
6)il.30
^4-2. GO
^S^.9<0
^6>s.^"0
^Hfo.no
^A1,3O
\1^,"76>
Inlet
Temp.
oF
°<^
no
12.0
\^i
I2fe
140
^1
IM-4
IM-fo
m1?
1 ^0
1 >43
!5Rv5
\33
Outlet
Temp .
oF
90
S2.
^a
^6,
en
I0/
104
ior
107
\OR
\O^J
\0fl
izn
IOI
Velocity
Head Ap
"H2°
o.lS"
o,i£
0,11
o,iS
0.7.1
0,2.1
O.XI
O.Zf?
0,72
0,24
O,7.2>
o.iq
Orifice AH
"H2°
2.IO
1,10
2.4O
2./«S
2AO
2.°iO
2,90
3. /O
3. 10
3,Z£
3,10
2.(fi>5"
?3,IS'
a.nc?
Pump
Vacuum
"Hg
to. n
10,0
n,£
I2.C>
13,^
N-o
>^.o
14.0
N,n
'K.O
\ir«.n
N»0
lS8,o
13. Z
Filter
Temp.
op
—
-
—
_
—
—
-
—
—
—
—
—
—
—
Impinger
»f
Temp. , °F
IZ
M
tol
^
laZ.
6>3
fe3
/»3
6,fc
/^Z
C.I
oa
T(»*7
^M-
Stack Gas
Temp . , ° F
Ts
|1O
1-ZuD
TZO
120
120
IZtf
17.0
\Z£-
I2T
\z.^
IIT
izr
iM^r
)^^
00
Leakage Rate @ 15 "Hg =
0
cfm
"iTOTPEO
PEDCo- ENVIRONMENTAL
SUITE 8 • ATKINSON SQUARE
CINCINNATI. OHIO 45246
513 / 77 1-4.330
-------
PARTICULATE FIELD SAMPLING METER DATA
Plant
Run Number
Location P, £ftl
Date 2.-23-T.2,
Operator R ft
Time \ Q ', "g, O
Sample Train Number
Meter Number 3
AH@
ft. 0,75
Filter No.
Barometric Pressure, in. Hg "SO,
Assumed Moisture, % k?
\ \0
Assumed Meter Temp., °F
Stack Gage Pressure - \,2- "H^O
Probe Tip Diameter, in. p.
Condensate Collected, ml.
'C1 Correction Factor Q, g>9
Point
1
z.
3
4
£
fe
1
8
_ 9
10
li
IL
Total
Avg.
Time
Min.
10
10
10
10
10
10
10
10
10
10
10
10
120
Dry
Volume
ft3
Vm
$?>0.nHO
PT3S, IOC)
?,u.o.fcq£
9M-(,.qi2L
853,850
SfoO.ciao
8^.230
8*7fl.-ac,o
8fi(«. 450
ac)'4.LV70
^OZ.550
910. ftftO
qifl,n6,7
87,qBV
Gas Met«
Inlet
Temp.
OF
32-
90
q«
I on
104
lofl
»IQ
1 10
1 1 0
114
\\S
11*7
IZ5&
105
=r
Outlet
Temp.
oF
80
81
R^
6^
8R
93
Q4
°m
q&
•
^a
6°!
7Z
7)
11
70
fe9
ni
T3
*7?
83Z
t^
Stack Gas
Temp . , ° F
Ts
zzS
ZlS"
2.1 S
230
23O
72?
•230
22£
Z20
23S
2^.C
23T
^<^2o
2.Z.7
Leakage Rate @ 15 "Hg = Q, 05"
= 87.^87 x
cfm
PEDCo - ENVIRONMENTAL
SUITE 8 • ATKINSON SQUARE
CINCINNATI. OHIO 45246
513 / 77 1-433O
-------
PARTICULATE FIELD SAMPLING METER DATA
Plant
Run Number
Location ^
Date o.
Time 10:35"
Operator
Sample Train Number
Meter Number 2.
Filter No.
Barometric Pressure, in. Hg
Assumed Moisture, % 10
Assumed Meter Temp., °F
Stack Gage Pressure
Probe Tip Diameter, in. Q ,
-"H2°
Condensate Collected, ml. 2. \0 t~7
'C1 Correction Factor
Point
1
2
3
if
5
(„
i
8
R
fO
II
IZ
Total
Avg.
Time
Min.
16
16
16
10
10
(O
10
10
16
( 0
\ o
10
1-z.O
Dry Gas Meter
Volume
ft3
Vm
6>ai,S2_
f'^^.OO
1A3,^O
TiZ^rt
nzi^o
^3-2,10
T42,^O
7S3. IO
7C,<4.ZC>
715.2O
78^,20
nqi. io
PsOT,T4-
120,21.
Inlet
Temp.
op
°C!L
\0(a
\l-4
\U4
\3S
\3<^
mo
m-Lf
ma
14^
\^
151
\Sff~l
1*32.
Outlet
Temp.
oF
RO
84
8R.
°ll
0,4..
°lA
100
164
IAA
MO
112.
H4-
M8S
99
Velocity
Head Ap
"H2°
rt.l|
0,13
0,13
O, Ik
O, IM,6
i4-:n
15,0
/fi.o
?0,<3
ZI.6
7J.O
11, 0
lai.s"
15-. i
Filter
Temp.
op
—
—
—
_
-^
-
—
—
-^
—
^^
—
—
—
Impinger
or-
Temp . , ° F
5 &
S8
61
(*3
hi
T)
13
//"7
6-7
*70
70
t,ft
^^3
G.(^
Stack Gas
Temp . , ° F
T
s
17.0
110
12<3
17.0
^O
1 7.0
110
12.0
l?<3
^^^
1^0
»7-<5
»<4-4-0
\"LC
NJ
O
Leakage Rate @ Ib" "Hg = 0. o|
cfm
PEDCo- ENVIRONMENTAL-
SUITE B • ATKINSON SQUARE
CINCINNATI. OHIO 45246
513 l~7~7 1-433O
-------
PARTICULATE FIELD SAMPLING METER DATA
Plant
Run Number
Location Di C*v\
Date '2L-'2'S-'"i2- Time
Operator R ^,, /\
Sample Train Number
Meter Number 3_
AH@ 1,52. (&> O.hg
6-.F.
I~u\eV
Filter No.
Barometric Pressure, in. Hg 30.
Assumed Moisture, % (a
Assumed Meter Temp., °F
Stack Gage Pressure
- l.Z "H20
Probe Tip Diameter, in. 6. "2.
Condensate Collected, ml. \QO . 1
'C1 Correction Factor p. 8ft
Point
1
2
3
v{-
*s
i*
7
a
9
10
n
12.
Total
Avg.
Time
Min.
ID
10
10
ID
\o
\o
IO
10
IO
10
\0
\o
\ZO
Dry Gas Meter
Volume
ft3
Vm
Cil9. SlM-
^ 7.14, 190
CfJO^ZO
S 38, 2feO
q^t.Tio
cl S'i . 32 0
^fc1?. no
OI^S-.D^O
982.480
^0.180
Tlfc.^SO
1062.^30
»om.ti3
fi^.l^
Inlet
Temp.
OF
R6,
102^
\oo-
\\u
l/)/»
IO//.
ir>^
I \o
no
110
loA
102.
im4-
I0(o
Outlet
Temp.
OF
102.
1^52.
10Z.
inM
(07.
102.
102.
102.
ir>2
•102.
/AO
9fl
)Z2O
102,
Velocity
Head Ap
"H20
0,38
0,2fo
A £~fl
o.to
0,^-8
O.SQ
0,5^
0-S"^
0,57
0,^9
<3..bS
O.M-2.
Orifice AH
"H20
1, ID
0,^7£
li — -
—
.
—
—
—
-
—
—
—
—
Impinger
ear
**J i I^AVv 1 1 O W- 3-
Temp. , °F
(^
faS
1*1.
6,\
UM-
fc2.
b^.
(r4
^3
U3
^0-
f^
n^S"
fo4-
Stack Gas
Temp . , ° F
T
s
220
ZZ7
23.7
Z4O
237
Z3£
2^0
235
23?
237
237
237
20014-
E3U-
Leakage Rate @ \S "Hg = 6.OU- cfm
^
TO
PEDCo- ENVIRONMENTAl-
8 • ATKINSON SQUARE
CINCINNATI. OHIO 4S246
513 / 77 1-433O
-------
PARTICULATE FIELD SAMPLING METER DATA
Plant
Run Number
Location _t
Date Q
Time
Operator LAE
Sample Train Number
Meter Number _ g.
AH@
6uT\
A.2S
O.Zs
2Z.
Orifice AH
"H2°
2^0
2.45"
2.fl
Z,A
3, ^
3.3
3.3
3,3
2,fo
3.5
3.<
3, I
3(^5
3,1
Pump
Vacuum
"Hg
n.g
°l.a
1 1
1 1
10.
)!-)-
1.5"
fb
19
26
2£»
l«
102.5
14,4
Filter
Temp.
oF
—
—
— .
—
—
—
—
—
—
—
—
—
—
—
Impinger
®*
Temp . , ° F
t/3
57
6.2.
CoS"
636?
0-3
S^
57
59
fed
58
66
12.9
M
Stack Gas
Temp. , °F
Ts
120
\2o
17.0
IZO
\ZO
\-LO
IZO
IZO
IZ 0
\-L6
\~lo
\Z£)
(440
17.0
to
NJ
Leakage Rate @ \£ "Hg =
cfm
PEDCo- EN VI RON MENTAL
SUITE S . ATKINSON SQUARE
CINCINNATI. OHIO 45246
513 / 77 1-433O
-------
GAS VELOCITY AND VOLUME DATA
oo
VELOCITY TRAVERSE DATA
Test No.
Point
1
^
3
4
S
6»
7
9
R
10
M
12.
Position
Inches3
\.15
4,oo
7,0*7
Ifl.tiO
IS", 00
11,30
SQDO
HS.OO
•49,10
S2.&O
£(o,00
5-fi.ao •
Total
Average
Reading, Ap
"H2°
4.Z8
o.zff
0,?A
6.HZ
o.in
0,53
0,£4
o,sx
O.S4
0,53
O-LT?
0,4^4
-
-
—
\/Ap
.52^
,5^>0
.^1(5
,G>48
,L>&1*
.IZS
.^35
.H2I
,T735
.728
,£p6fc
,^,(r3
^.sn^
,«*S"
T °F
s
?.CJO
16><3
15^
^(oO
26»5"
Z(a^
26s.C
Z^C
26,5"
2.1 5"
ZTs
2TO
31AO
-i^S1
Location D,-CF + 460 =
= 174 \fl£ Cp V T x 29.92 x 29* f t/min.
M
V =
s
Q, Volume =
f t/min. x
- Z(*1l
C0 sq. ft. =3
-------
GAS VELOCITY AND VOLUME DATA
£>.
VELOCITY TRAVERSE DATA
Point
)
2
3
M-
S
t
7
fl
9
I0
n
IZ.
Position
Inches3
1.3
"4.3
T7
I 1.5"
Ifr.Z
23.0
iva.o
H^.o
53.?
57.5"
4»0.?
fc-s-S"
Total
Average
Reading,Ap
«H20
0, \ ^
o, \ S"
0, 17
0, 1^
0,21
0,2-1
0,21
0.23
0.^3
0.2>4-
0^3
' o, n
-
-
-
\/Ap
.^ST
.381
.M-12.
,H%
.HS8
.4^5
,^S0
-f80
,^80
.4^0
,HBO
,M3fe
S,3(*TL
.HM-T
Ts°F
IZO
IZ^>
IZ^3
IZO
17.0
ao
^<0
\z^
/•2-S"
\es
1E5
iz£
)40> S"
I'ZZ
Test No.
1
Location y^
Stack Inside Dimensions ^5" §
23.0^ sg. ft.
30. k "H9
F + 460 =
582.
Molecular Weight of Stack Gas, M =
V = 174 V/Ap" Cp V T0 x 29.92 x 29' f t/min.
s s ~P FT
Q, Volume = }51T1
f t/min. x 23.DM- sq. ft. =
70°F and
= 17.7 x
Q , Standard Volume at 70°F and 29.92 "Hg(Wet Basis)=
Q x 530 x Pg
T 29.92
Qc - CD x (100-WJ/100 =
o W
a) From outside of port to sampling point.
Pitot tube "S"
Manometer
Thermometer
o — \,O
A L.
Data Recorder
Date i.-l'L-
Lft
PEDCo- ENVIRONMENTAL
SUITE 8 • ATKINSON SQUARE
CINCINNATI. OHIO 45246
513 IT7 1-433O
-------
GAS VELOCITY AND VOLUME DATA
NJ
Ul
VELOCITY TRAVERSE DATA
Test No.
Point
1
2
3
M-
£
fe
7
8
^
IO
1 1
12.
Position
Inches3
\.2b
M.OO
7.67
10,6,0
1^,00
21.30
38,70
VS.OO
H9./0
£2,90
5(*£>0
Sfl.AO
Total
Average
Reading, Ap
"H2°
0-2LO
0,32.
0.3"7
0-^7
O.S7
O.SS
Q^T-
0,SC
O.tfl
0,^<
/I, "52.
o.sa
-
-
\/Ap
.H-4T
>£^fe
.O08
• l5»8(»
,755"
,7^2.
,787
.HH-'Z.
,&2&
.T4Z
.Til
•i./-<70 x
x PS = 17.7 x ^p./4Q
29.92
Qs = Qw
(100-WJ/100 =
a) From outside of port to sampling point,
Pitot tube "S'' TMPE
Manometer
Thermometer
Data Recorder
Date CL
PA
6 f
PEDCo- ENVIRONMENTAL
SUITE 8 • ATKINSON SQUARE
CINCINNATI, OHIO 4524-6
513/77 1-433O
-------
GAS VELOCITY AND VOLUME DATA
VELOCITY TRAVERSE DATA
Test No.
to
CTi
Point
\
1
3
4
S"
6,
1
8
^
I o
II
IZ
Position
Inches3
1,3
4,3
H.T
11,5
ll/.Z
21, 3
42,5
41,0
S3.S
5TS
U.£
03. S '
Total
Average
Reading, Ap
"H2°
O.ll
0,13
0ii3
0, IU>
a,n
o.n
fl.iq
6.ZI
fl^l
fl.2.1
(3,7.1
0,7.)
-
-
-
\/Ap
.^Z
.361
.3*1
• Lk36
,M3(p
,M3^
,M3fc
.4^5
,M£8
.H-Sfl
,U5A
.M-S8
5,052.
M-2-1
T °F
s
IZO
IZO
IZ<3
fZO
IZO
\za
IZO
120
IZO
l?,0
IZO
12.0
IM-^O
1ZO
Stack Inside Dimensions (#£> " <$>
Stack Area, A_ = 23.0*4- sq .
Barometric Pressure, Pw = 30/6
Stack Gage Pressure = Q
Stack Abs. Pressure, ?„ = 6
Stack Gas Temp., T = \2-<0 °
s — • ' ••
Molecular Weight of Stack Gas, M
V = 174 \/Ap Cp V T,, x 29.92 x
5 P
Q, Volume = IK 63 ft/min. x
Q , Standard Volume at 70°F and
Q x 530 x PC; = 17.7 x
T 29.92
S
Qe = Q x (100-W)/100 =
Location D, CM ^cvAWv-
OAk*-E»oi«eoS
ft.
"Hg
"H00
"H20 + Pw = 3O. (a "Hg
13.6 ^
F + 460 = S&O °R
1 = Q.1^
s =^-J
29' ft/min.
M
«j
^- - m-8"?> ppm
Z3.OM- sq. ft. ='34)IC3S cfm
29.92 "Hg(Wet Basis)=
"b"-|^lG.P> x 3o, G =31^07
^e.o
a) From outside of port to sampling point,
Pitot tube "£,"
Manometer
Thermometer
Data Recorder LfVEl <
Date 9- 0.3-h 3-
PEDCo - ENVIRONMENTAL
SUITE B- • ATKINSON SQUARE
CINCINNATI. OHIO 4534-6
513 / 77 1-4330
-------
GAS VELOCITY AND VOLUME DATA
to
VELOCITY TRAVERSE DATA
Point
1
Z
3
4
5
£.
7
R
3
10
il
12.
Position
Inches3
l.2
,r«Wfl
8.5"A(c
•7rt^
T °F
s
^0
227
7*,7
2.4O
2-^^
2"iO
?.?n
235"
£37
257
237
237
ZBO^
234
Test No.
Location
Iw
Stack Inside Dimensions
Stack Area, A = \ S, O
5
5'-
Barometric Pressure, I
Stack Gage Pressure =
Stack Abs. Pressure, I
_sq. ft.
30. 5 "Hg
"H2°
= -Q.07
°F + 460 =
"H20 + PK = 30. IV-3 "Hg
13.6 b ~"
Stack Gas Temp., T =
S ^~ '
Molecular Weight of Stack Gas, M =
5
v
= 174 \/Zpl Cp V T x 29.92 x 29* ft/min.
M
s
Q, Volume =
ft/min. x )
sq. ft. =
) , Standard Volume at 70°F and 29.92 "Hg(Wet Basis)=
Q x 530 x Ps = 17.7 x •&/, Q ftS* x
TS 29.92
> = Q,, x (100-WJ/100 =
O Wr — - ~"
a) From outside of port to sampling point.
Pitot tube "s,"
Manometer
Thermometer
Data Recorder
Date
. A
PEDCo - ENVIRONMENTAL
SUITE 8 • ATKINSON SQUARE
CINCINNATI. OHIO 4524-6
513 / 7~7 1-4330
-------
GAS VELOCITY AND VOLUME DATA
to
CO
VELOCITY TRAVERSE DATA
Test No.
Point
1
a
3
VJ
s
(a
7
fl
q
10
n
ia
Position
Inches3
1/3
M.3
1.7
11, JT
Ife.Z
23,0
^2.0
H9.0
S3.T
J77.?
L,0^
k3,S
Total
Average
Reading, Ap
"H2°
0.\4-
0,17
0,10
0.10
0.1Z
0,7.q.
0.7.4
0,7. 4-
rt,Z6>
O.Zs
o/z£
0,22.
-
-
—
\/Ap
/374-
,412.
i4tn
,4H7
.14^
.4^0
,M^O
,4^0
• 5"hO
,b^0
,S"00
,m^
5,598
,ft>7
T °F
s
»2jfl
IZO
120
170
110
\20
\16
\?A
MO
I2fl
IZO
IZO
14-M-O
\ZO
Location P,C>vl
Stack Inside Dimensions _
Stack Area, A = 2"3, Q 4-
S -r"L ~"~
Barometric Pressure, P, =
Stack Gage Pressure =
Stack Abs. Pressure, P =
S
k?S
sq. ft.
30.5"
"Hg
\2.0
_D "H20 -
13.6
°F + 460 =
Stack Gas Temp., T =
S
Molecular Weight of Stack Gas, M =
t—^^^
V
= 30. Z "Hg
\ °R
= 174 \/Tp Cp V T x 29.92 x 29~" f t/min.
V =
s
V
sso<
Q, Volume =
ft/min. x
sq. ft. =
V
Standard Volume at 70°F and 29.92 "Hg(Wet Basis)=
Q x 530 x Ps = 17.7 x 37,^47 * 30.T = 35.320
x Ps = 17.7 x 37 °|47
29.92 '
= Qw x (100-W)/100 =
a) From outside of port to sampling point.
Pitot tube "s" TifPE
Manometer
Thermometer
Data Recorder
Date ^
PEDCo-EN VI RON MENTAL
SUITE 8 • ATKINSON SQUARE
CINCINNATI. OHIO 4S24-6
513 / 77 1 -4330
-------
PEDCo- ENVIRONMENTAL
SUITE 8 • ATKINSON SQUARE
CINCINNATI. OHIO AS2.46
513 /771-A330
COMBUSTION GAS ANALYSIS
Plant
(3 OP vs '-•
Location
Conunents
\'< fl 0\
Date Fi/ ~ 3 -I ?• 3 , /g/7?
Test
No . Time
3 ; 16'
/ lv L /: 7"
J: ^
/ Q '•> -// fr 7
//:?o
3 ///>. ,.'.; ''
n;&
0 o u ^ £ "
z:if
-3 /,// .' -^
3'. 30
O
° O^;'// <.' '/
%(co2)
0.*
6"?- -^
C>, ^
0. 3
a..r
d?. -^
%(02)
/ ^ ,;?
/1
< C?, 2.
< £?, 2
-i o, a
<• 0, 9
^ (?. 2
NOTE: Analyses are on a dry basis when performed by Orsat.
% EXCESS AIR = 100(%02-0.5%CO)
0.264(%N2) -
- 0.5%CO)
= 100-(%02 +
%co2 + %co)
29
-------
APPENDIX C
TEST LOG
-------
February 22, 1972 Clear 60-75°F
A.M.
8:00. Meet with Mr. Bruce Galloway of Borden and tour sampling
sites.
8:30 Begin unpacking and setting up equipment at dicalcium
phosphate process.
8:40 Process shut down - problem in crushing system. Make
physical measurements of ducts.
10:00 Leslie Evans of EPA arrives.
10:15 Process back on stream
10:30-11:00 Preliminary velocity traverses made simultaneously at
inlet and outlet sites. Bottom of inlet duct heavily
loaded with dirt. Plume opacity - 10 to 30%.
11:00-12:00 noon - Set-up sampling trains to prepare for moisture run
P.M.
12:00-12:30 Preliminary moisture run at inlet and outlet
12:30- 1:30 Measure water content and make calculations.
1:30 J. Rom arrives - discuss velocity traverse and
decide on 12 sampling points in each duct. Because
of poor access only .one diameter will be sampled.
2:25 Start first run for fluoride determination
2:35 First scrubber water sample Temp. - 112°F pH 3.7
2:40 Randy Mayfield, EPA Atlanta, arrives on site
-------
3:15 Orsat analysis
3:20 Second scrubber water sample. Temp. 112°F pH 3.7
4:10 Outlet train broke glass connector between first
and second impinger. Replaced connector. Stopped
sampling for about five minutes.
4:20 Third scrubber water sample Temp. 112°F pH 3.4
Stack opacity is <10%
4:25 Complete fluoride test
4:25-5:45 Remove samples from train and clean all equipment.
February 23, 1972 Clear 55-75°F
A.M.
8:00 Arrive at plant. Di cal plant is shut down because
of water leak around scrubber. Drilled small hole in
top of inlet duct in order to probe depth of dirt in
bottom of duct. Determine depth of dirt at center
of duct to be 15". Set up sampling equipment.
9:00-9:30 Process restarted. Leak on inlet train delayed start
of sampling.
10:35 Started test 2 for fluoride at inlet and outlet.
10:40 First scrubber water, sample -_Temp. 106°F pH 3.2.
11:20 Orsat analyses
•11:25 Second scrubber water sample Temp 108°F pH 3.1
Opacity <10% today
Borden's and State of Florida personnel on site today
-------
P.M.
12:20 Third scrubber water sample, Temp 108°F pH 3.0
12:35 Test 2 completed - no problem
12:40-2:15 Remove sample from trains and prepare for another run.
2:20 Leak check each train and begin fluoride test No. 3
2:40 Take scrubber water sample, Temp 106°F pH 3.0
3:00 Opacity of stack gases 0%
3:15 Take Orsat samples
3:25 Scrubber water sample Temp 106°F pH 3.0
4:20 Complete fluoride tests with no problem
4:20-5:45 Clean up trains and package samples
4:45 McDonald of Borden ' s . started fluoride test at outlet site
6:00 Leave plant
-------
APPENDIX D
PROJECT PARTICIPANTS
-------
Project Participants and Titles
PEDCO-ENVIRONMENTAL SPECIALISTS, INC.
Richard W. Gerstle, P.E., Engineer in charge of sampling
Larry A. Elfers, Chemist
Robert S. Amick, Engineer
Gene Forte, Technician
Joseph Geiger, Technician
EPA
J. Rom - In charge of sampling
L. Evans - In charge of process operations liaison
------- |