ATMOSPHERIC
EMISSION
EVALUATION
U.S.ENVIRONMENTAL PROTECTION AGENCY
Office of AirQuaNty Planning and Standards
Emission Measurements Branch, Field Test Sect ion
Thomas E.Ward, Project Test Officer
Test Number 72-CI-34CGRN)
MAYFLOWER FARMS
GRAIN & FEED MILLING PLANT
PORTLAND, OREGON
Contract No.68-02-0236 Task Order No. 2
VALENTINE, FISHER &TOMLINSON Consulting Engineers
520 Lloyd Building  Seattle,Washington 98101 (206) 623-0717

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          VALENTINE,   FISHER   &   TDMLINSDN
                                 CONSULT ING ENGINEERS
                                  A.D.H.H.A. C., A.A.A.B.. G , A. M. C., 1. 11, B .
                          S2O LLOYD BUILDING"  MAIN3-O71.7
                              SEATTLE, WASHINGTON s> B i a i
WM. M. VALENTINE, M.E.
ARTHUR K. FISHER, M.E.
GEORGE D. TOMLINSON, E.E.

SR. ASSOCIATES
WAYNE A.  HANSON, M.E.
DOUGLAS W. PASCOE. E.E.
P. "CHIC" CICCHETTI
ASSOCIATES:
PHILIP W. WOODRUFF
DENNIS W. FINLAYSON
HENRY L. ROYCE, ILLUM.
THOMAS G. JOHNS. M.E.
WILLIAM T. MCDONALD
DEAN A. H ANNIG
DUANE A. SHOFSTALL
ROGER C. HUNTLEY
WESLEY D: SNOWDEN, A.P.
February 8, 1973
                                            PURPOSE
         This atmospheric  emission  evaluation report is an account of our findings
         from stack  gas  samples  taken from the exhaust gases of Attrition and Hammer
         Grinders  at Mayflower Farms  in Portland,  Oregon.   The evaluation was
         conducted at  the  request of  the U.S. Environmental Protection Agency,
         Office  of Air Programs, Emission Testing  Branch under Contract No. 68-02-0236
         for the purpose of  generating background  information to esablish emission
         regulations on  Grain and Feed Milling plants.  EPA and Hi-Vol sampling trains
         were used simultaneously for comparison of measured emission.
                                            SUMMARY
         The  three  stack gas  samples  collected were found to have concentrations of
         0.0068,  0.0022,  and  0.0023 grains per standard cubic foot from the EPA
         sampling train and 0.0036, 0.0022, and 0.0012 grains per standard cubic foot
         from the Hi-Vol sampling train.   An additional Hi-Vol sample taken during
         limited  alfalfa pellet milling was found to have a concentration of 0.0163
         grains per standard  cubic foot.   The standard cubic foot is reported at
         70°F., 1 atmosphere  pressure and dry.  Plant production rates during the
         evaluations were recorded at 7.8, 4.0, 9.9 and 6.3 tons per hour for
         Runs 1,  2, 4 and 5 respectively.  Emissions calculated on the basis of pounds
         per  ton  of production are 0.040, 0.010 and 0.015 for Runs 1, 4 and 5
         respectively with the EPA-train and 0.020, 0.101, 0.010 and 0.009 for
         Runs 1,  2, 4 and 5 respectively with the Hi-Vol train.
                                                  Wesley D. Snowden, P.E.
                                                  Manager, Environmental Services
         WDS/vc

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                            DISCUSSION OF RESULTS


Run #1 included simultaneous samples with the EPA train and the Hi-Vol train.
Run #2 was taken with the Hi-Vol only.  Projections based on Runs 1, 4 and 5
on what the EPA train would have recorded for Run #2 indicate that the emission
concentration could be as high as 0.03 grains per standard cubic foot.  The
atmospheric emissions during Run $2 were noticeably greater when the plant
was milling alfalfa pellets.  Run #3 was terminated when production was curtailed
15 minutes into a desired 108 minute run so run #3 sample was discarded.  Run
numbers 4 and 5 included simultaneous EPA and Hi-Vol samples.

The two trains were operated with +10% isokinetic.  The Hi-Vol technique did
not consider the changes in orifice pressure deflection due to the presence
of moisture.  The actual cubic feet passing through the Hi-Vol filter was
determined by assuming dry air passed through the orifice at 60°F. and then'
adjusting for temperature changes.  Hi-Vol standard cubic feet per minute
dry was calculated at standard temperature and pressure, excluding water vapor.

The average actual flow rate for Runs 1, 2,4 and 5 was 5507 acfm.  The square
footage of dacron felt fabric was 792 square feet so the air to cloth ratio
was 6.95.

Production rates during sampling were determined to be:  Run #1 - 2 tons
of Oats and 12 tons of Barley/108 min.  (7.8 tons/hour);  Run #2 - 7.2 tons
Alfalfa pellets/108 minutes (4.0 tons per hour); Run #4 - 6 tons of Oats,
9 tons of Corn, and 2 tons of Barley/103 minutes (9.9 tons per hour); and
Run #5 - 7 tons of Corn, 5 tons of Wheat, 6 tons of Oats, 1 ton of Barley/
180 minutes (6.3 tons per hour).

The atmospheric emissions measured with the EPA train per Method //5 of the
Federal Register, Vol. 36, No. 247 averaged 0.0038 grains per standard
cubic foot and 0.0023 grains per standard cubic foot with the Hi-Vol train
(See Table 1).  Note in Table I that the EPA train per Method 5 reported
emissions approximately 60% higher than the Hi-Vol sampling train and Run #2
Hi-Vol emissions were 7 times higher than the average when the plant was milling
alfalfa pellets.  The inclusion of condenser water hydrocarbon extraction and
water evaporation portions in the total particulate of the EPA train increases
emissions on the average of 24%.

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                                                TABLE I
                              MAYFLOWER FARMS GRAIN & FEED MILLING PLANT
                                       COMPILATION OF EMISSIONS
RUN NO.

1
2
4
5.
1,4 & 5
TOTALS
1,4 & 5
AVERAGES
CONCENTRATION
GRAINS /SCF
EPA-//5*
0.0068

0.0022
0.0023
0.0113
0.0038
EPA-COND.0
0.0080
0.0163
0.0027
0.0029
0.0136
0.0045
HI-VOL
0.0036

0.0022
0.0012
0.0070
0.0023
POLLUTANT MASS RATE
POUNDS /HOUR
EPA-//5*
0.309

0.102
0.097
0.508
0.168
EPA-COND.0
0.364

0.127
0.121
0.612
0.204
HI-VOL
0.159
0.728
0.101
0.055
0.315
0.105
PROCESS WEIGHT RATE
POUNDS/TON
EPA- #5*
0.040

0.010 '
0.015
0.065
0.022
EPA-COND . °
0.047

0.012
6.019
0.0784

HI-VOL.
0.020
0.101
0.010
0.009
0.039
0.013
EPA
RATIO
COND.///5
1.179

1.241
1.312
3.732
1.244
* Total Particulate determined by EPA Method #5 - Federal Register, Vol. 36, No. 247.
Total Particulate by Including Condenser Water Extraction & Evaporation Portions.

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                                PROCEDURE
This atmospheric emission evaluation was conducted simultaneously with
two sets of sampling equipment.  The primary set of equipment was designed
by the United States Environmental Protection Agency (EPA) and the comparison
set of sampling equipment was designed by Oregon State University refered to
as the Hi-Vol procedure.  The EPA equipment and procedures used on this
evaluation are detailed in the Federal Register, Vol. 36, No. 247, Method 5
and the Hi-Vol equipment and procedures used on this evaluation are partially
described in "A High Volume Stack Sampler", Boubel, R.W., Air Pollution Control
Association Journal, December 1971, Vol. 21, No. 12, pp. 783-787.

The EPA sampling train was started first because a longer sampling time was
established for its use.  The Hi-Vol sampling train was started within 15
minutes and located in the sampling port 90° away from the EPA train.  The'
EPA train was operated from 2 to 3 hours on each sample and the Hi-Vol train
was operated for 18 minutes on each sample.

The two sampling ports spaced 90° apart were located six diameters above the
last, obstruction (fan outlet) and 2 diameters below the stack outlet.  The EPA
train collected its sample from two 18 point traverses (36 points total) and
the Hi-Vol train collected its sample from one six point traverse (limited
number because sample time was short and velocity readings were not as
accurate as with the EPA inclined manometer).

The stack gas velocity was calculated from velocity readings taken during
sampling.  Preliminary stack temperature, pressure and velocity readings
were taken to size the sampling nozzle on the EPA train.  With moisture
content of 3% determined by wet bulb-dry bulb technique, an EPA-designed nomograph
detailed in the "Specifications for Incinerator Testing at Federal Facilities"
was used to select a 1/4" diameter nozzle.  The Hi-Vol nozzle selected from
a group of 4 graphs was a 1.875 inch diameter.  The four nozzle and orifice
deflection selection graphs are enclosed in the back of this report.  Combustion
products and/or chemicals were not present in the exhaust gases so the
dry weight of the exhaust gases was assumed to be that of air.

Isokinetic velocities were maintained on the Hi-Vol train by establishing a
"C" factor on the EPA-designed nomograph by trial pitot and orifice
deflections.  Maximum and minimum pitot tube readings were used in the
4 calibrated Hi-Vol manufacturer graphs to determine maximum and minimum
orifice readings.  The two readings crossed the "C" factor line at one place
which established the swivel point between velocity to orifice readings.
Rapid adjustment of the rate meter reading was possible utilizing the
nomograph.                                                           •       •

Schematics of the EPA designed and Hi-Vol stack gas sampling trains used on
this evaluation project are enclosed in this report.  Both trains were
calibrated prior to use on this project.  The "S" type pitot tube used on
this project was calibrated and found to be 0.83.

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                       CLEAN-UP AND ANALYSIS
Clean-up of the EPA train was performed by carefully  removing the filter
and placing it in a container marked "Run X,  Container A".   Reagent  grade
acetone and brushes were used to clean the nozzle,  glass probe and
pre-filter connections.  The acetone wash was placed  in a container  marked
"Run X, Container B" .   The volume of water in the impinger and bubblers
(glassware) was weighed in their respective containers to the nearest
0.1 gram.  The original weights which included approximately 100 ml  in
the bubbler and 100 milliliters in the impinger were  then subtracted
and the difference added with the water weight gain of the silica gel
constituted the amount of water collected during the  run.  The silica
gel was weighed in a bubbler before and after the run.  The water from the
glassware and a water rinse of the glassware were placed in a container
marked "Run X, Container C".  An acetone rinse of the glassware and •'
all post-filter glassware (not including the silica gel container) was
performed and placed in a container marked "Run X,  Container D".    i

Analysis of the samples in each container was performed according to the
following:                                                          I

Run X, Container A - Transfer the filter and any loose particulate from
the sample container to a tared glass weighing dish and desiccate
for 24 hours in a desiccator or constant humidity chamber containing
a saturated solution of calcium chloride or its equivalent.  Weigh
to a constant weight and report the results to the nearest 0.1 milligram.

Run X, Container B - Measure the volume to the nearest 0,1 milliliter.
Transfer acetone washings from container into a tared beaker and
evaporate to dryness at ambient temperature and pressure.  Desiccate
for 24 hours and weigh to a constant weight.   Report the result to the
nearest 0.1 milligram.

Run X, Container C - Measure the volume to the nearest 0.1 milliliter.
Extract organic particulate from the water solution with three 25 milliliter
portions of chloroform and three 25 milliliter portions of ethyl ether.
Combine the ether and chloroform extracts and transfer to a tared beaker.
Evaporate until no solvent remains at about 70°F.  This can be accomplished
by blowing air that has been filtered through activated charcoal over
the sample.  Desiccate for 24 hours and weigh to a constant weight.   Report
the results to the nearest 0.1 milligram.  After the extraction, evaporate
the remaining xvater to dryness and report the results to the nearest
0.1 milligram.

Run X, Container D - Measure the volume to the nearest 0.1 milliliter.
Transfer the acetone washings to a tared beaker and evaporate to dryness
at ambient temperature and pressure.  Desiccate for 24 hours and weigh
to a constant weight.  Report the results to the nearest 0.1 milligram.

Blanks were taken on the acetone, ether, chloroform, and deionized water
and subtracted from the respective sample volumes.  The filter paper used
with the EPA train was a Mine Safety Appliance 1106 BH, heat treated glass
fiber  filter mat.

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                               CLEAN-UP AND ANALYSIS

        Clean-up  of  the Hi~Vol sampling train was performed by first carefully
        removing  the 8" x 10"  filter,  folding collection side in and placing it
        in its  tared 6-1/2"  x  9-1/2" manila envelope.   An acetone rinse and
        brushing  was performed on the  front half of the filter holder,  probe and
        nozzle  and placed in a water-tightly sealed, teflon liner glass jar for
        shipment  to  the laboratory.

        Analysis  of  each sample was  performed according to the following
        procedure:
                                        /
        Filter  -  Desiccate the sample  filter and blanks in their tared envelope to
        dryness for  at least 24 hours.   Weigh the filters in their manila envelope
        to a constant weight and report the results to the nearest 0.1 milligram.

        Acetone Rinse - Measure the  volume to the nearest 0.1 milliliter.  Transfer
        acetone washings from  container into a tared beaker and evaporate to dryness
        at ambient  temperature and pressure.  Desiccate for 24 hours and weight to
        a  constant weight.   Report the result to the nearest 0.1 milligram.

        Blanks  were  taken on the acetone and a proportion of weight based on sample
        volume  was subtracted  from the sample weights.  The filter paper used with
        the Hi-Vol  train was a Mine  Safety Appliance 1106 BH, heat treated glass
        fiber filter mat.
QUICK
DISCONNECT
COUPLING
FILTER HOLDER ASSEMBLY
                                                         PRESSURE AND
                                                      TEMPERATURE GAUGES
                                            CONTROL VALVE
                                                                                FLEXIBLE
                                                                                 HOSE
                                                                 TEMP.

                                                                    SUCTION BLOWER

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       CAP. TO
        U
fit/A/Mff.

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  NOZZLE
"S" Type pitot.
integral with
sampling probe
                                          rHEATED BOX
                         STACK WALL
                         ' HEATED PROBE-7
                                      K  /	J	
                                                                                          TEMPERATURE
                                                                                                UMBILICAL
                                                                                                CORD
                                                  EPA STACK  GAS  SAMPLING. TRAIN
                                                        (PARTICULATE)

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                                                   0 ' 5 P
                                                    5 -^ 7
                                             17-851793
                                                                 •102336  PMR
                                                   i:  N
                                                                             AVG

-------
VALENTINE, FISHER &TOMLINSON
CONSULTING ENGINEERS         /  COMPUTER PRINT-OUT OF ATMOSPHERIC EMISSION DATA
JOB NAME
PREPARED BY

SUBJECT-
         1 -4  M
   C-^£6COC  MF

      30-13 PSN
         5 - 0  TSTD
         539  TM
          1ST
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-------
VALENTINE, FISHER &TOMLINSON
CONSULTING ENGINEERS
CORSPUTEK PRBWT-QUTOF ATMOSPHERIC EMISSION DATA

                              
-------
 VALENTINE, FISHER &TOMLINSON  /
 CONSULTING ENGINEERS            COMPUTER PRINT-OUT OF ATMOSPHERIC EMISSION DATA
PREPARED BY

1 • 4
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-------
                               TABLE 1

      PARTICULATE CONCENTRATION AND PMR CALCULATION TERMINOLOGY

VOLm      = Dry gas meter volume @ meter temperature and pressure, dry - acf

Pm        = Dry gas meter pressure (recorded as inlet deflection accross orifice
            meter) - "Hg

Tin        = Dry gas meter temperature (average of inlet and outlet)

PSTD      = Standard atmospheric pressure (29.92" Hg)

TSTD:      = Standard Temperature  (520 or 530° R)

VOLW      = Volume of water collected (expressed as vapor at standard temperature
            and pressure) - scf

M         = % water, calculated from amount the train collected in impinger$-
            bubblers, and on silica gel
        i                                    .       .               •    •
        I                                                           •
MF        = Mole fraction of dry gas

WD        = Molecular weight of dry stack gas - Ib/lb mole

Wy        = Molecular weight of wet stack gas - Ib/lb mole

Wa        = Molecular weight of air - Ib/lb mole

Cp        = Velocity correction coefficient for gas density

P gjj       = Stack pressure  (static + .barometric) - "Hg

Cg        = Velocity correction coefficient for stack pressure

VHn       = Pitot tube pressure differential - "l^O

Vo        = Stack velocity @ stack conditions - fps

Qo        = Stack flow rate at stack conditions - acfm      „    .        •

Tg        = Average stack temperature - CR

QQS       - Stack flow rate at standard conditions - scfm

T         = Time over which sample was collected - minutes

Vn        = Velocity of gases inside nozzle during sampling - fps

I         = % isokinetic (+ 10% desirable)

CQ        = Particulate concentration - grains/scf

N         = % CO 2 by volume in stack  (12  indicatesno  %  C02  correction  is  to
            be made)

-------
                                                                   Page 2
                                TABLE 1

       PARTICULATE CONCENTRATION AND PMR CALCULATION TERMINOLOGY
 C         = Particulate concentration corrected to 12% C00

 PMRp      = Pollutant mass rate - "concentration method" - Ib/hr

 PMR.,,     = Pollutant mass rate - "area ratio method" - Ib/hr

           = Average pollutant mass rate - Ib/hr

 C         = Particulate concentration corrected for non-isokinetic sampling
             condition-grains/scf

 Pip        = Total Particulate collected by sampling train - mg

 As        = Area of Stack - FT2

 An        = Area of Nozzle - FT2


-VH        = Velocity head readings for  pitot tube - inches water

           =  Standardized gas  that passed through the sampling train -
              cubic feet,  70s  F,,  1 atmosphere pressure,  and dry.

           =  Velocity correction coefficient for type pitot tube - dimensionless
              0.83 to 0.87 for "S" type  pitot tube normally and 1.0 for  "P"
              type pitot tube.

-------
            PARTICULATE CONCENTRATION  &  PMR CALCULATIONS
      VOL
                (VQLm)  (Pm)'(TSTD)
         STD'
      M
      MF
                     
                  (100)
                 VOL
                    STD
 100 - M
    100
                  (WD)  (MF) +  18  (1-MF)
                   Wa*
6.
                                           15.   PMR,
                                           16.
                                           17.   PMR
                                             (Qos>  (0.008571)
                                         T~A —  (0.000132)
                                                   AVG
18.  C

*    PSTD

     "a
=  FMRAVG
   Q^—  Ci4oo;

=  29.92" Hg.    |
                 I
=  28.95 LB/LB MOLE
7.    K
                       n
                   2.9  (Ka)  (Cp)  (CD)  (CS)
9.
 (V0) (As) (60)
,10.   Qos
11.   V
       n
12.   I
                    O  (TSTD)  (PSN)
                  (VOLSTD)  (PSTD)(TS)
                             __
(MF) (TSTD)  (PSN)  (T)  (AN)  (60)
(100) _J1
13'   C0       "   VOLi^- (°-0154)
14.   C
CQ (12%).
   N

-------
             HI-VOL PARTICULATE CONCENTRATION & PMR CALCULATION
1.    MF = 1 ~ M/100
2.  '  VOLSTD =  (ACFMm)(T)  TSTD   PSN (MF)
4.
                         15.
                                           16.  FMRAR
                                                          (C0)  (Qos)  (0.008571)
                                                          PT
                                                                   (0.000132)
                                  PSTD     17.
3.    M =  (100)(VOLl.7)/(VOLSTD +
6.
7.    K
              =   (WD)  (MF)  4- 18 (1-MF)
                                                PMR
                                                   'AVG
                                           18.  C
                                         T  An

                                         PMRp+PHRAR
                                      =  —2


                                      =  "«AVG
                                         Qb^N	 ("00)

                                      =  29.92" • Hg.

                                      -•=  28.95 LB/LB MOLE
                                                      = Flow through orifice ®
                                                temperature..        •   i  •
                                                Pg^j assumed equal  to orifice
                                                pressure.
                        n
8.
                   2.9  (KJ- (Cp) (CD) (CS)
9'    Qr
                   (V0)  (As)  (60)
10.   Qos
11.
       n
                  (VOLSTD)  (PSTD)(TS)
(MF)  (TSTD) (PS
                                        (AN)  (60)
12,
13.   C,
14.
       0
                  (100)  jn
                  '  J5T
                          (0.015A)
                 C0  (12%)
                     N

-------
VALENTINE, FISHER & TOMLINSON
     SEATTLE, WASHINGTON
CI
LC
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-------
CLIENT
VALENTINE, FISHER & TOMLINSON
     SEATTLE, WASHINGTON

  PARTICULATE FIELD DATA (CONTINUED)
                                                                                                    V.F.T./AP1C

-------
                    STACK MOISTURE CONTENT DATA AND  CALCULATIONS
     CLIENT

     LOCATION

     DATE
H20 CONDENSED IN IMPINGERS, ml  (1 ml =  1 gm)
H20 ABSORBED BY SILICA GEL, ml
TOTAL H20 COLLECTED, ml
VOL. OF H20 VAPOR @  70° F. AND  1 ATM.
0.0474 x TOTAL H20
                     q   1'
MOISTURE IN STACK GAS,
MOLE FRACTION OF DRY GAS
MOLECULAR WT. OF  STACK GAS
                                                              RUN NO.     (
                                                      LJL3JLL
                                                            Final
                                                                        ••21  A 6
% MOISTURE IN  STACK GAS  -
                            VOL.  DRY GAS + VOL.  WET GAS
MOLE FRACTION OF DRY  GAS  =  100-% MOISTURE IN STACK GAS
                                   .  100

MOLECULAR WT. .OF STACK GAS  -   AVG. DRY MOL.  WT.  OF GAS x MOLE FRACTION +
                               18 x  (1-MOLE FRACTION)
BUBBLER (//I)


IMP ING ER (//?.)


BUBBLER (//3)


   . TOTALS
                   FINAL (gm)
                    (   /

                    	   (ml)

__(Dry)     -	
                                                                    3,7
                                  	(ml)

                                  'Z./,$  (ml)
                   2    o,

-------
PART IV
                                     VALENTINE, FISHER & TOMLINSON
                                      VELOCITY TRAVERSE DATA SHEET
CLIENT __

DATE     8 'S/- 7Z.   TIME

SAMPLING PORT LOCATION

STACK AREA, FT.2

REFERENCE POINT _

OPERATOR
                                                       RUN NO. A6*
TYPE PITOT TUBE USED   S" '  W SS~//f

BAROMETRIC PRESSURE
                                                          , ff J*
STATION
7
2.
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6,
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AVERAGES
DIST. FROM
REF. PT.
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VH ("H20)


















STACK
TEMP(°F)


















TS (°R)


















STACK PRESS.
("Hg)


















VH x TS

















*
/VH x Ts




i













     *"P" type pitot tube velocity read from velocity tables at stack temperature
     and vel. head values using the following equation (Ref. Western Precipitation
    • Bulletin WP50):          /j	
                      V = 2.9\VVH x Tc

     Tg = Absolute Stack Temperature, °R                     •   •
     VH = Velocity Head, in.H20          .            •
     V =  Point Velocity (fps)

     Velocity correction for; "S" type pitot tube = 0.855 x "P" type, gas density

    \/(28.95 Ib/lb mole) air/Mol. Wt. Stack Gas, Stack Pressure Correction =

    >/29.92"Hg./Stack Pressure.
                            T  7~&
     VFT/AP2A

-------
         VALENTINE, FISHER & TOMLINSON
LABORATORY ANALYSIS AND TOTAL PART ICULATE  SHEET
CLIENT
EVALUATION LOCATION

EVALUATION DATE
                 /5&C/WS       DATE OF ANALYSIS

                                          RUN NO.      /
                                               CLEAN-UP SET NO.
                                                     /
I.   EVAPORATION OF
                          OQ
                  (ml) OF
     RINSE & BRUSHING OF NOZZLE,  PROBE  AND GLASSWARE BEFORE
     FILTER.                             ,             '   •

          FINAL .&86<£2,8  (mg)  -  TARE   &fiO//,Z.    •   (mg)

          -BLANK (( <2, 0/^3- mg/mi)  ( ^ O O    mp  =  ^^  mg)

II.  FILTER CATCH  /$S/$ /^&&/ &J **/&&? (Media  Type)  '

          .FINAL  /ST&Q  (mg)  -  TARE      / 
-------
                                             VALENTINE, FISHER & TOMLINSON

                                                  SEATTLE, WASHINGTON . .
CLIENT




7 '•./-• » rriT/"--.T
JJJ^:\.i J.C*<




T\ A r"1
Xy."i. j. £j





OPERATOR/S





PUN NO.
                         tx-  o/c. &<:?
                                              PARIICULATE FIELD DATA
                                        VERY IMPORTANT:  FILL III ALL BLANKS
PILTr^-i NO.   :..;-.—
      AMBISN'T -TEMP.



      BAR.  PRESSURE



      ASSUMED MOISTURE



      HEATER BOX SETTI1IG



      PROBE NOZZLE DIA.



      PROBE LENGTH



      PROBE HEATER SETTING
                                                                                                        SOQ
                                                                                                          3
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!  TIME
             DRY GAS METER
             (CUBIC FEET
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                                                                   POINT
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                                                                                      ORIFICE


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-------
                                                'itMi- " ' i. 1'.' ••'•'iK ic
                                                   SEATTLE, WASMI
         CLIENT
                                                PARTICULATK FIELD DATA (CONTINUED)

UJ-LIUX
TIME
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(CUBIC FEET)
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                                                        TEMP.
                                                     POINT
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                                                                                   DESIRED j  ACTUAL
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-------
                        STACK MOISTURE  CONTENT  DATA AND  CALCULATIONS
        CLIENT
        DATE     8
H20 CONDENSED IN IMPINGERS, ml (1 ml = 1 gin)
   H20 ABSORBED  BY  SILICA GEL,  ml
   TOTAL H20  COLLECTED,  ml
   VOL. OF H20  VAPOR @  70°.F.  AND 1 ATM.
   0.0474 x  TOTAL H20
   MOISTURE  IN STACK GAS,  %
   HOLE  FRACTION OF DRY GAS
   MOLECULAR WT.  OF STACK GAS
                                                      /
                                                                 RUN NO.
                                                                   FxnaT
                                                                              Jiat.
   % MOISTURE IN STACK GAS =  100 x VOL.  H20 VAPOR
                               VOL.  DRY GAS -f VOL. WET GAS
   MOLE  FRACTION OF DRY GAS = 100-% MOISTURE IN STACK GAS
                                        100
   MOLECULAR WT.  OF STACK GAS =  AVG. DRY MOL. WT. OF GAS x MOLE FRACTION +
   V                      .         18 x (1-MOLE FRACTION)
   BUBBLER (//I)
                      FINAL (gm)

                          3-  I
                               -  TARE
       IMPINGER(//2)
                                        fJ<<
       BUBBLER ()/'3)  3 'O.^'

          . TOTALS   . / 2 3 3.
            NET WATER  (gm)  (1 gm =  1 ml)

_(W/water) = __	'&, 8    (ml)

_(W/wat:er) =	C > Q	(ml)

_(Dry)     =	6,*2.	(ml)

           «	/5To	(ml)
/ i.

-------
                         VALENTINE,  FISHER  &  TOMLINSON
                LABORATORY ANALYSIS  AND  TOTAL PARTICULATE SHEET
CLIENT     -'/^-y^d^^'^e^ S _ DATE OF ANALYSIS
EVALUATION LOCATION  /V/erZS/S/3 ,   /P&t^               RUN NO.
                                _

EVALUATION DATE       & ~^ ? 3 "              CLEAN-UP SET NO.
I.   EVAPORATION OF   <£  TO      (ml)  OF
     RINSE & BRUSHING OF NOZZLE,  PROBE  AND  GLASSWARE BEFORE
     FILTER.
    '      FINAL 57mg)  -  TARE      //      .     (mg)

          -BLANK (( 4£/;/ymg/ml)  (_^5l_ ml)  =  ^'l5   mg)           //, ?   mg.

II.  FILTER CATCH 4f-S^ //£>£$// <£jt>JS//^£e (Media Type)     ,  •

          •FINAL S'^7, /   (mg)  -  TARE   / ^5 / / _ (mg)      =    ^ -0     mg.

III. HYDROCARBON OBTAINED  BY  ETHER-CHLOROFORM  EXTRACTION ON
     WATER IN IMPINGER AND BUBBLERS.

          FINAL/j#?57, ?  (mg)  -  TARE 6 ? 9 5" ^ / 7      (mg)

          -BLANK  (    £> .  9 _ mg)    .                       =    0 ,3    mg.
IV.  PARTICULATE  FROM EVAPORATION OF     fr^ _ (ml) WATER
     IN IMPINGER  AND  BUBBLERS  FOLLOWING EXTRACTION -
          FINAL  £~83&.   (mg)  - TARE ^~#<'  o,         (mg)

          -BLANK (( 6f6QS/  mg/ml) (   J* &$~._ _ ml initial-

          ~      / 5^   ml  CONDENSED =  ^^^   ml) =  / ^  *7 mg)   =     & '3    mg.

V.   PARTICULATE FROM //^ ^  (ml)  OE /VG-&&AJ6    RINSE OF IMPINGER,
     BUBBLERS, AND  CONNECTORS AFTER FILTER:

          FINAL ^/f£^5"(mg) - TARE £/f77/^       (mg)

          -BLANK («j>dMTing/ml) (  /^ ^   ml) ==  Z >4' mg)       =     2.7    mg

VI.  TOTAL  PARTICULATE = I + II -f III + IV + V                     =   / 7, O   mg
                           -                                           '3- ?  Stz
     BLANKS
                                                                FINAL ___ mg.
     ACETONE  = __, _ mg/ _ ml = _<
-------
                                            VALENTINE, FISHER & TOMLINSON
                                                 SEATTLE, WASHINGTON
CLIENT

LOCATION

DATS

OPERATOR/S

RUN NO.

EQUIPMENT

FILTER NO.
                                      ' VERY IMPORTANT:  FILL IN ALL BLANKS
                I/
              #
                *7 sr/,£.**
                                                    AMBIENT TEMP.

                                                    BAR. PRESSURE

                                                    ASSUMED MOISTURE

                                                    HEATER BOX SETTING

                                                    PROBE NOZZLE DIA.

                                                    PROBE LENGTH

                                                    PROBE HEATER SETTING
                                                                                                                         "H*
                                                                                                                         in.
                                                                    Ft
   CLOCK
   TI1-S
   /,; oz
  // :o 7
DRY GAS IffiTER

(CUBIC FEET)
  /ff  f
IMPINGER
 TEMP.
                                                         23-
                                               :3t>
                                                 0
                                       POINT
                                                                    •^
                                                                    4-
                                                                     6"
PITOT A P

 ("H20)
ORIFICE AH
                                                                       JJISISEir:
                                                                  ..jTuarn  ("Hg)
                                                                r7777/T7T7T
                                                               0 , ? t?
STACK
PRESS
 "
                                                                                            __2j
                                                                                    Z, (JO
STACK
TZMP,
REMARKS:
                                                                                                             V.F..T.//v?lB

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CLIENT

VALENTINE, FISHER & TOMLINSON
     SEATTLE, WASHINGTON,

  PARTICIPATE FIELD DATA (CONTINUED)
                                                                                                    V.F.T./AF1C

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                           STACK MOISTURE CONTENT DATA MID CALCULATIONS
            CLIENT
LOCATION

DATE    <
                       ~ 2 •$ ~~ 7
       KoO CONDENSED IN IHPINGERS, ml (1 ml - 1 gui)
       H20 ABSORBED BY SILICA GEL, ml
       TOTAL K20 COLLECTED, ml
       VOL.  OF H20 VAPOR @ 70° F. AND 1 ATM.
       0.0474 x TOTAL K20
       MOISTURE IN STACK GASS %
       MOLE FRACTION OF DRY GAS
       MOLECULAR WT. OF STACK GAS
                                                                     RUN NO.
                                                                       FilTal
                                                                                    2 a
       % MOISTURE IN STACK GAS =-   100 x VOL.  H20 .VAFOR
                                   VOL. DRY GAS -f  VOL.  WET GAS
       MOLE FRACTION OF DRY GAS =  igOz%_MOISTURE IN STACK GAS  '
                                            100

       MOLECULAR WT. OF STACK GAS  =   AVG.  DRY MOL.  WT.  OF GAS x MOLE FRACTION
                                      18  x  (1--MOLE FACTION)
                          FINAL (gm)   -  TARE

                           J*  *—~ **~) -L-T,
          "BUBBLER  (#1)    *T-5 // C,


          IMPINGER(//2)
          BUBBLF.R  (//3)    3*2-&f

              TOTALS
                                                      NET WATER (gm) (1 gm = 1 ml)

                                          _(W/water)  = 	     '?> 7	(ml)

                                          _(W/water)  =	tf'S	(ml)

                                          _(Dry)      = 	'^/5^	(ml)

                                                              ZO  ' O  •	(ml)
VFT/AP3)]

-------
                         VALENTINE, FISHER & TOMLINSON
                LABORATORY ANALYSIS AND TOTAL  P ARTICULATE  SHEET
CLIENT        V     /r/m/yMf  tfeMf     DATE  OF ANALYSIS      e $- - 207 Z
                                                                   /          T~   — —
                       f?          -,
EVALUATION LOCATION  /^yZ/0^  Os?£&<7/J __ _ RUN NO.     £>   _
EVALUATION DATE      ~<-<>CLEAN-UP  SET  NO.
I.   EVAPORATION OF  '2 &$       (ml) OF
     RINSE & BRUSHING OF NOZZLE, PROBE AND GLASSWARE  BEFORE
     FILTER.

          FINAL 67&<&7, 7 (mg) - TARE  6-78 ?&* ?       (mg)

          -BLANK ((£>, 6//^"mg/ml)  (  Z ^y  ml) = S , &  mg)       =   / 7*      mg

II.  FILTER CATCH /jfffl//fl& Sfl &S?SS/7£££(Ke.& ja Type)

          .FINAL  /-5"/.Z  (mg) - TARE   /<&<#<• 7 _ (mg)       =
        i                           •                              ;       .
III. HYDROCARBON OBTAINED  BY ETHER-CHLOROFORM EXTRACTION ON
     WATER IN IMPINGER AND BUBBLERS.
          FINAL ^ £5"^,' 7 (mg) - TARE   &Q tt / „ ?       (mg)

          -BLANK  (     Of f _ mg)                                 /' *?   mg.
IV.  PARTICULATE FROM EVAPORATION  OF          _ (ml)  WATER
     IN IMPINGER AND BUBBLERS  FOLLOWING EXTRACTION -
FINAL           (mg) - TARE
                                        6 6 ^7, ?-       (mg)
          -BLANK ((Otd&l   mg/ml)  (    <£ d _ ml initial

          -   •  "2 £    ml CONDENSED  =  ^SQ  ml)  =  /* ^ mg)   =     O,*3   mg.
V.   PARTICULATE FROM  / ? £* (ml) OF  /Vg-gTZAJf  RINSE  OF  IMPINGER,
     BUBBLERS, AND CONNECTORS AFTER FILTER:
FINAL <£<^5 //,
' -BLANK ((£,d/
-------
VALENTINE, FISHER &  TOKLINSON
•HI-VOL PARTICULATS DATA  SHEET
                                           7/8
CLIENT £ rtf (e> /y//?^t#^£X' Sr4/?/H s
LOCATION '/'O/ZTZ./JA.'P . &/?&&a/J
DATE &-?>/- 7 2
OPERATOR/
HUN if
FILTER ?
TIMS
2k HR
/ ** ^-^
y/<*f' b"(j
/<£'//
./£'&
/<£>'/ 6
/4:.y?
/<£,' 2£
/ <>
#, 35' .
6 ,.35'
^4$
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x*S (L^f
o,5e
^35'










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fpra
NOZZLE SIZE ' '° IN.
STACK ARE
WB ^8 °F
DB 7 G °F
A^oV = A.-V- ••--_}•••:*•• •^••••.•••.v"^:*a~-'i> =


















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ORIFICE
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21,6.
• $ 7,3
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. <££,3~


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L 25
1,75
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^?'^i-

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                             VALENTINE, Pi3HER  & TOMLINSON
CLIENT
                     HI-VOL PART'XGi/LAT•••:DATASHEET

                                              N02ZLE SIZE
                                   /7/s
                              IN,
LOCATION
 ATE
0-2Z-7Z
                                                        ^
                                                        2
                             DB
OPERATOR /S
                                             STACK  AREA
                                                FT2
                                                       "•.•f[\O   WJK'CiC!
                                                      <'i/iUa«  racoo e	-
                                                                          .IN. Kg
FILTER
                                             PROCESS  TYPE O»
  TIME
  24 HR
°F  ;
                 TRAV.
 VH
"H20
                                    fpra
                _ 9 6-
ORIFICE;
 FLOW
  cfm
                                                   i  4-2,&
ORIFICE
 FLOW
 scfm
ORIFICE
,  A?
STACK
PRESS.
                                                                             sfefiij;
                                                  4-

              .1.
                 ,/7
                                                                                       ^^
                                                                              .__:

-------
                              VALENTINE, FISHER & TOMLINSON
                             ^ HI-VOL PARTICULATa DATA SHEET
CLIENT
                                                      NOZZLE SIZE

LOCATION



DATE
           c9 - ^ S  - 7 2
OPERATOR/S



RUN #.	
fffij r\
/Ofl^\J i
STACK
ATtfOS
/<£ WB
DB
AREA 20
, PRESS.
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.75 7.7 c ' 
-------
                              VALENTINE, FISHER & TOMLINSON
CLIENT
LOCATION
DATS
OPgRATOH/S  -
FILTER
                             •HI-VOL PARTICTJLATE DATA  SHEET
NOZZLE SIZE
   AA&
           WB
           DB
STACK AREA^a'
 n-jrs. PRESS . r^ •. •-.«
PROCESS TYPE
 IN.
_F
 FT2
                                                                                    JN.. Kg
TIMS '
V± HR
K'lc^
• 7 "?
// ' ^
1 '
//• 26
. ,
_JL?3__
/(*31L
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/ '* •''ff^
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1
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°F POINT
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,., .
ORIFICE
P
"H 0
2

0.7^"
<5d**~
O /o*t>
/*> jS "?
O f Q /
•
<~->' S&r^-
<3 ,"Sr~^
A X O
0 
-------
                       VALENTINE, FISHER & TOML1NSON
                                 111 - VOL
                       PART1CULATE L^C/.IATORY SHEET
CLIENT
LOCATION-
                                  DATE OF ANALYSIS

                                    JN NO.         /
DATE OF SAMPLE
                             72
                                  CLEAN-UP REFERENCE
RUN
NO.
  I
  ^
 4
FILTER I  FINAL
  NO.
       i 678/6,3 j 67 7/4,?    /0/>4-   j
                       '     ^2,4   i
                                                      •2,7
VFT/AP15

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vhT IV
                                   VALENTINE, FISHKR & TOML1NSON
                                    VELOCITY TRAVERSE DATA SHEET
         SAMPLING PORT LOCATION
         STACK AREA, FT.2
         REFERENCE POINT   JAJ5/pe

         OPERATOR
TYPE PITOT TUBE USED

BAROMETRIC PRESSURE

60
                                                /  Ca
                                                -  4---U •"- I— u_i_i
STATION
1
Z.
3
4 _
5"
4- -











AVERAGES
DIST. FROM
REF. ;'PT.
0,88
2,^4
S,96
/ 4, / o
i*l,6(*
Jfb'z
•. ' '











VH ("H20)


















STACK
TEMP(°F)









O








TS (°R)


















STACK PRESS.
("Hg)













•\




VH x TS


















/VH x Ts


















    "X'"P"  type  pitot tube velocity  read from velocity tables  at stack temperature
    and vel. head  values using  the folloving  equation (Ref .  Western Precipitation
    Bulletin WP50):          / / - \
                    V  = 2.9^VVH x Ts-Javg.

    Tg  =  Absolute  Stack Temperature,  °R
    VH  =  Velocity  Head, in.H20
    V =  Point Velocity (fps)     .        •

    Velocity correction for; "S" type pitot tube  =  0.855 x "P" type, R&S density =

  \/(20.95  lb/.lb mole)  air/Mol. Wt. Stack  Gas,  Stack Pressure Correction =
  \/29.92"Hg. /Stack  Pressure.
    VFT/AP2A

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                                                          LOGARITHMIC       /16 7323
                                                          2X8 CYCLES          M.oc is u. 5.«. o
                                                             KCUFFffL ft E.19CR CO.

o   s-
.4     .5    .6  .7  ,8  ,9  1.0
                                          .04   .05  .06  .07 .Oa.09  .

-------
                                                     NOZZLELMULB
                                               }:!:f.j.is;::-:-.:-.!-;-:,; HO :^:.j-~-^-i
     ;: i j.!; r, i.; :'.:.•;.]:.] ij'i f:nn:l..!-!ii |:i:::!"l. i j:! ;.:!t:j:j:rv! |T.!. I ri-jT'iJ.
    TFSTACK"   " :  :'"l'"^'J'':"""!!' ;'"'4":"""']^""11    	"^
-ember 197J
                                                      -;• t ; -i • -: i •   	i l r i •
                                                      -t ;••'-! M'M -"-••' ••'•'',
Pa KG 16

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                                                                     . rAFER NO. 101r
                       ORIFICE-nTEMR
J i-i4 20
             . H.t M.j_. i ! ;•-;--] f,-H


                  , • : vnvr  :0t I

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              :  : : i i 7"i'! t i ! I  i"! ;~ i" r
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                                                             UOOAf'ITHMIC
                                                             2 X i> C/CLFS
                                                                                         7323
jbi
4.      i.    i    1.   !\   -i  1O.

-------