SN 16544.008
            Test Number FA-5
Union  Carbide Corporation
     Ferroalloys Division
     Alloy, West Virginia
                 by
          T.E. Eggleston / R.N. Allen


               June, 1972
        RESOURCES RESEARCH, INC.
        A SUBSIDIARY OF TRW INC.
        WESTGATE PARK • 7600 COLSHIRE DRIVE • McLEAN, VIRGINIA 22101
           Contract Number CPA 70-81

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                                     SN 16544.008
     Test Number FA-5



 Union Carbide Corporation

   Ferroalloys Division

   Alloy, West Virginia
            by


T. E. Eggleston/R. N.  Allen
         June, 1972
 Resources Research, Inc.
 A Subsidiary Of TRW Inc.
 Westgate Park
 7600'Col shire Drive
 McLean, Virginia  22101
 Contract Number CPA 70-81

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                          I.   TABLE OF CONTENTS
  II.

 III.

  IV.

   V.

  VI.

 VII.

VIII.
  IX.
INTRODUCTION 	
SUMMARY OF RESULTS 	
PROCESS DESCRIPTION 	
LOCATION OF SAMPLING POINTS 	
PROCESS OPERATION 	
SAMPLING PROCEDURES 	
DISCUSSION 	
A. Results 	
B. Operatino Conditions .... 	
C. Test Conditions 	
APPENDIX 	
A. Complete Parti cul ate Results with
Example Calculations
B. Complete Gaseous Results with
Page
... 3
. . . 6
. . . 15
. . . 19
. . . 24
. . . 25
. . . 26
. . . 26
. . . 29
. . . 30
. . . 36

                Example Calculations
          C.    Complete Operation Results
          D.    Field Data
          E-l.  Sampling Procedures
          E-2.  Cleanup and Analytical Procedures
          F.    Laboratory Report
          G.    Test Logs
          H.    Related Reports
          I.    Project Participants and Titles

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                             LIST OF TABLES

Table No.       	Title	       Page
   1            Collection Efficiency                              6
   2            Summary of Results - Inlet                         7
   3            Summary of Results - Outlet                        8
 Plus           Appendices A, B, C, D,  F, and G
                             LIST OF FIGURES
Figure No.
1
2
3
4
5
6
7
8
9
Title
Block Diagram - Sample Locations
Run No. 1 - Material Balance - 1/17/72
Run No. 2 - Material Balance - 1/18/72
Run No. 3 - Material Balance - 1/20/72
Process Flow Diagram
Exhaust Collection Layout
Baghouse Exhaust Sample Location
Sample Point Locations
Inlet Velocity Traverse Points
Page
4
12
13
14
16
17
20
21
23

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                            II.   INTRODUCTION

     Source emission tests are being performed on a  series  of electric
furnace installations, known as  reactive metals or ferroalloys,  for  the
Office of Air Programs, Environmental  Protection Agency.  This report
covers the tests performed at the Union Carbide Corporation plant, Alloy,
West Virginia, during the week of January 17, 1972.   The  tests at this
facility include grain loading measurements and carbon monoxide  determi-
nations.

     Emissions for this particular plant were determined  for a silicon
metal furnace (No. 7) rated at 17 megawatts.   This unit was hooded,  with
duct work leading to the induced draft fans,  that directed  exhaust fumes
to three individual baghouses in parallel.  Tapping  fumes were exhausted
through a separate uncontrolled system.

     The 58-foot long,7.5 foot wide monitor exhaust  from  baghouse 7B was
provided with twelve properly spaced ports for equal  area sampling.  The
11.5 foot square inlet duct had four properly spaced ports  provided  approxi-
mately 40 feet after a disturbance where the circular duct  became retangular.
Sample point locations are shown in Figure 1.  Further detailed  diagrams
and descriptions are included in Sections IV and V (Process Description  and
Location of Sampling Points).

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I ATMOSPHERE
                                                       (ATMOSPHERE^
      QUARTZ
       ORES
                               ELECTRICAL
                                 POWER
  CARBON
 REDUCING
  AGENTS
FLUXES, ETC.
                       ELECTRODES
            CHUTES
                                              CHUTES

                                              /HOOD
                       ELECTRIC ARC
                         FURNACE
                                                            DUST
                                                        COLLECTION
                                                          SYSTEM
TAPPING  EXHAUST
                                  HOOD
                          LADLE
                                                      0
                                                    SAMPLE
                                                  LOCATIONS
                         PRODUCT
                         MOLDS
       FIGURE!.
             BLOCK  D I AG R A M - S A M P L E LOG AT I O N S
             F UR NACE  NO. 7

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     The abatement equipment was a set of three baghouses  in  parallel;
the one sampled having Nomex bags, the others were equipped with  fiber-
glass cloth bags.   Three overall particulate collection efficiency  tests
were conducted.  Each exhaust test included four sample trains, each
covering one-fourth of the exhaust stack area.  These runs were believed
to be typical of normal operating conditions.

     During this particular survey particulate matter was  sampled using
a standard EPA train as described in Appendix E-l.  Through the courtesy
of Union Carbide one single sample was obtained at the inlet  duct with an
ASME train which overlapoed sample ABD-3 at the inlet duct (EPA test).
Combustion gases were measured using an Orsat analyzer. Ambient  air  and
baghouse exhaust particulate loadings were also measured using high volume
air samplers.  Carbon monoxide was measured at the inlet location using an
infrared analyzer.  The overall survey included 16 particulate emission
runs, two Orsat measurements, six Hi Vol samples,  triplicate  gas  velocity
measurements into all the baghouses, induced air measurements for all  bag-
houses, and a continuous measurement of CO emissions for two  hours.

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                                      III.   SUMMARY  OF  RESULTS

                   Shown below,  in Table I,  are the  results  and  averages  for  inlet and
              exhaust testing of the baghouse  system, along  with the  corresponding col-
              lection efficiencies.
                                               TABLE  I
                       Overall  Summary of Emissions and  Collection  Efficiency
                                                                      Combined
                	No.  7B Exhaust (Outlet)	   No. 7A,  7B.  7C  Inlet Duct
                 Filterable       Total     Compartment B-14    Filterable      Total         7B
1972     Run     Particulate   Particulate  Part.  Filtered    Particulate     Particulate   Percent
Date     No.    Ibs/hr - EPA  Ibs/hr - EPA  Ibs/hr -  Hi  Vol   Ibs/hr -  ASME Ibs/hr -  EPA  Efficiency
1/17/72  One         7.9           11.3           3.53            	           2870       99.1
1/18/72  Two         8.5           13.8           2.36            	           2010       98.5
1/19/72  Three       	          	           	           2020           2510       	
1/20/72  Four        4.4           10.3           2.06            	           2560       99.1
      Average        6.9           11.8           2.65            	           2360       98.9
                   Particulate emission summaries for the baghouse  inlet  duct  and monitor
              exhaust are shown in Tables 2 and 3 on the following  pages.   Flue  gas  condi-
              tions are included, and percent particulate matter in the impinger train  has
              been calculated.  This "condensible" portion was extremely  low prior to the
              collection system.

                   Gas temperatures and velocities within the monitor, at the  exhaust
              sampling location, remained ouite stable, but temperatures  on the  roof,

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                                 TABLE 2
                           BAGHOUSE INLET DUCT
                           SUMMARY OF RESULTS
Run Number
Date
Total Stack Flow Rate - SCFM* dry
% Water Vapor - % Vol.
°L C02 - Vol 7, dry

% 02 - Vol % dry

7» Excess air (? sampling point

SOp Emissions - ppm dry
NO Emissions - ppm dry
2£
Particulates
Probe, Cyclone, & Filter Catch
gr/SCF* dry (Can)
/-i
gr/CF @ Stack Conditions ( at)
Q
lbs./hr. (aw)
Particulate from impinger train
(% of total)
Total Catch
gr /SCF * dry ( ao)
Q
gr /CF @ Stack Conditions ( au)
lbs./hr. (°ax)
Stack Temperature, °F
ABD-1
1/17/72
407.000
0.3






NA
NA


0.815
0.562
2840
1.1

0.824
0.568
2870
300
ABD-2
1/18/72_
430.000
0.5






NA
NA


0.538
0.368
1980
1.3

0.545
0.373
2010
300
ABD-3
1/19/72
392.000
1.7






NA
NA


0.742
0.498
2490
0.6

0.746
0.501
2510
310
ABD-4
1/20/72
399.000
1.7






NA
NA


0.723
0.487
2470
3.4

0.748
0.504
2560
307
ORSAT
1/20/72


0 Q
u • y
on 7
L\J . 1
opn/1
OoUU












	























* 70°F, 29.92"  Hg

-------
                               TABLE 3
                           BAGHOUSE EXHAUST
                         SUMMARY OF RESULTS
Run Number
Date
Stack Flow Rate - SCFM * dry
% Water Vapor - % Vol.

% C02 - Vol 7» dry

% 02 - Vol 7o dry

7, Excess air & sampling point

S09 Emissions - ppm dry

NO, Emissions - ppm dry
'
Particulates
Probe, Cyclone, & Filter Catch
gr/SCF* dry
gr/CF @ Stack Conditions
Ibs./hr.
Particulate from impinger train
(% of total)

Total Catch
gr /SCF * dry

gr /CF @ Stack Conditions

Ibs./hr.
Stack Temperature °F
AEE-1
1/17/72
**
57,040
n







NA
lin
NA



0.0085
0.0070
4.15
07 c
o/ . D


.0136
n HITS

6.65-
IftO
ECE-1
1/17/72
**
57,040














0.0039
0.0032
1.90
oc r\
^0 . U

OAAC O
.0052
Onn/io
. UUHO
2.52
isn
WCE-l
1/17/72
**
57,040














0.0018
0.0015
0.88
01 7
c.\ , 1

Onnoo
.(JU^O
Onnio
. uu i :?
1.12
IftO
AWE-1
MM/12
57,040*














0.0019
0.0016
0.92
***
c 0
o. u

Onn^n
.UU^U
n nm fi
U . UU 1 D
0.98
IRQ
BAGHOUSE
TOTAL-1
MM/12
**
228,150














_
_
7.85







11.27






























  *70°F, 29.92" Hg
 **(Assumes 1/4 of total  flow was in each section)
***See Discussion
                                    8

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                             TABLE 3 (Cont.)
                        BAGHOUSE EXHAUST (cont.)
                          SUMMARY OF RESULTS
Run Number
Date
Stack Flow Rate - SCFM * dry
7» Water Vapor - % Vol.
7, C02 - Vol °L dry

7, 02 - Vol % dry

7o Excess air & sampling point

SO,, Emissions - ppm dry

NO Emissions - ppm dry

Particulates
Probe, Cyclone, & Filter Catch
gr/SCF* dry
gr/CF @ Stack Conditions
Ibs./hr.
Particulate from impinger train
(% of total)
Total Catch
gr /SCF * dry
gr /CF @ Stack Conditions

Ibs./hr.
Stack Temperature °F
AFF-2
1/18/72
70 .4l8*
0






MA
lin
MA
INM


0.0087
0.0067
5.25
22.3

0.0112
Onnc?
. uuo/
6.75
99n
ECE-2
1/18/72
70.41*)*
0












0.0018
0.0014
0.95
52.6

0.0038
On(i9Q
. \j\j£.y
2.30
99n
WCE-2
1/18/72
70,41$*
0












0.0023
0.0018
1.40
43.9

0.0041
Onnoo
. UUO£
2.47
99D
AWE-2
1/18/72
70,410*
0












0.0014
0.0011
0.85
63.2

0.0038
OnnoQ
. \J\JL. :3
2.30
9?n
BAGHOUSE
TOTAL- 2
1/18/72
281 ,650*
_













T
8.45





13.82



























 *70°F, 29.92" Hg
**(Assumes 1/4 of total  flow was in each section)

-------
                             TABLE 3 (Cont.)
                        BAGHOUSE EXHAUST (cont.)
                          SUMMARY OF RESULTS
Run Number
Date
Stack Flow Rate - SCFM * dry
7o Water Vapor - °L Vol.

7» CO 2 -Vol 7. dry

7,, 02 - Vol 7o dry

7» Excess air (? sampling point

'.'SO * Emissions - ppm dry
NO Emissions - ppm dry
X
Particulates
Probe, Cyclone, & Filter Catch
gr/SCF* dry
gr/CF @ Stack Conditions

Ibs./hr.
Particulate from impinger train
(% of total)

Total Catch
gr /SCF * dry
gr /CF @ Stack Conditions

Ibs./hr.
Stack Temperature °F
AEE-3
1/20/72
**
67.410
One
. uo






NA
MA


0.0026
Qnn?i
. UU£ 1
1.50
O7 O


0.0036
OnnoQ
. uu^iy
2.08
200
ECE-3
1/20/72
**
67.410
Ocn
• ou










0.0018
Onnol
. UU£ 1
1.05
Cft C


0.0059
Or\c\n~i
. LHr/4/
3.40
200
WCE-3
1/20/72
**
67,410
Ore
. 33










0.0017
Onm A
. UU 1 1
0.97
cc ^


0.0039
r n nmi
U . UU<3 1
2.25
200
AWE- 3
1/20/72
**
67,410
n n?
u. u/










0.0015
Onm ?
i UU 1 (.
.88
CO C


0.0040
Onm?
. UUoc
2.30
200
BAGHOUSE
TOTAL-.-?
1/20/72
269, 650*















4.40






10.03
	
OR SAT
_
_


n 9
U. i-
?n ?
£U . /
ci on
0 1 UU









~~




_
	
 *70°F, 29.92" Hg
**(Assumes 1/4 of total flow was in each section)
                                   10

-------
where equipment and personnel  were located, depended upon the weather and
wind direction.   Flue gas conditions at the combined inlet duct were also
rather stable.

     A comparison of one single EPA and ASME test, conducted on the inlet
duct, indicates that the ASME train collects 20% less particulate than the
EPA train.   Air flow measurements indicate that approximately 32% of the
effluent gas from B baghouse is induced air.  Carbon monoxide levels in
the inlet duct ranged from 25 to 190 ppm, but were generally around 50 ppm
with occasional peaks.  Fume capture at Furnace 7 is essentially 100%
during normal operation.

     The Hi Vol samples taken in compartment B-14 (MCE) ranged from 0.52
Ibs/hr to 0.88 Ibs/hr and averaged 0.66 Ibs/hr (assuming 1/4 total baghouse
flow to be in that comaprtment).  The corresponding samples taken with the
EPA train (WCE 1, 2 & 4), considering only the filterable fraction, ranged
from 0.88 Ibs/hr to 1.40 Ibs/hr and averaged 1.08 Ibs/hr.

     An overall presentation of the results are presented in material
balance format in Figures 2, 3, and 4 on the following pages.
                                    11

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                              21,900 scfm
                               0.824 gr/scf
                               154.7 Ib/hr
NORTH
                                                  AMBIENT

                                                  10,000 acfm
                                               BAGHOUSE
                                               SECTION
                                                 7C

                                               31,900  scfm
                                               0.0058  gr/scf
                                                 1.59  Ib/hr
                            y
                             163,000 scfm
                               0.824 gr/scf
                              1151.1 Ib/hr
                                207,200 scfm
                                  0.824 gr/scf
                                 1463.2 Ib/hr
                        AMBIENT

                        65,150 acfm
                        0.0005 gr/scf
                          0.28 Ib/hr
BAGHOUSE
SECTION
  7B

228,150 scfm
 0.0058 gr/scf
  11.27 Ib/hr
 _FURNACE #5_

 LEAKAGE        !
 16,000 scfm    L
   0.72 gr/scf  r
     99 Ib/hr.   i
 	 j
            TOTAL         i

            407,000  scfm
              0.824  gr/scf
               2870  Ib/hr
                        AMBIENT

                        113,900  acfm
                         0.0005  gr/scf
                           0.49  Ib/hr
     BAGHOUSE
     SECTION
       7A

   321,100 scfm
     0.0058 gr/scf
     15.96 Ib/hr
o o o o
                                      Assumptions:  a.
                                                    b.

                              Grain loading for No.  5 Furnace
                              same as No.  7 Furnace.
                              Baghouses A  & C operation identi-
                              cal  to B.
                   Figure  2.  Run No. 1 - Material Balance
                                         1/17/72
                                       12

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                                21,900 scfm
                                 0.545 gr/scf
                                 102.3 Ib/hr
NORTH
                                216,500 scfm
                                  0.545 gr/scf
                                 1011.2 Ib/hr
                                                      AMBIENT
                                                      10,000 acfm
                                                      0.0004 gr/scf
                                                       0.034 Ib/hr
                                                                         BAGHOUSE
                                                                         SECTION
                                                                           7C
                                                                         31,900 scfm
                                                                         0.0057 gr/scf
                                                                           1.56 Ib/hr
                                204,100 scfm
                                  0.545 gr/scf
                                  953.3 Ib/hr'
           TOTAL         |

           430,000 scfm
             0.545 gr/scf
              2010 Ib/hr
_ jFURNACE #_5

I   LEAKAGE

I   16,000 scfm
i     0.72
I       99
                          o o o o
                                                     AMBIENT
                                                     65,150 acfm
                                                     0.0004 gr/scf
                                                       0.24 Ib/hr
                                                     AMBIENT
                                                     113,900 acfm
                                                      0.0004 gr/scf
                                                        0.39 Ib/hr
                                                                         BAGHOUSE
                                                                         SECTION
                                                                           7B
                                                                         281,650  scfm
                                                                           0.0057  gr/scf
                                                                           13.82  Ib/hr
  BAGHOUSE
;  SECTION
:    7A

i318,000  scfm
  0.0057  gr/scf
   15.53  Ib/hr

             _. J
                                                      _.._._	I
                                      Assumptions:   a.
                                                    b.
                                                          Grain  loading for No. 5 Furnace
                                                          same as  No. 7 Furnace.
                                                          Baghouses A & C operation  identi-
                                                          cal to B.
                  Figure 3.  Run No. 2 - Material Balance
                                         1/18/72
                                       13

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                                21,900 scfm
                                 0.748 gr/scf
                                 140.4 Ib/hr
NORTH
                                204,500 scfm
                                  0.748 gr/scf
                                 1310.9 Ib/hr
  AMBIENT
  10,000 acfm
  0.0004 gr/scf
    0.034 Ib/hr
                                                                         BAGHOUSE
                                                                         SECTION
                                                                           7C
                                                                         31,900 scfm
                                                                         0.0044 gr/scf
                                                                           1.20 Ib/hr
                               204,100 scfm
                                 0.748 gr/scf
                                1308.4 Ib/hr
  AMBIENT
  65,150 acfm
  0.0004 gr/scf
    0.22 Ib/hr
                                                                         BAGHOUSE
                                                                         SECTION
                                                                           7B
                                                                         269,650 scfm
                                                                          0.0044 gr/scf
                                                                           10.03 Ib/hr
           TOTAL         I

           399,000 scfm  ;
             0.748 gr/scf
              2560 Ib/hr
 FURNACE #_5

 LEAKAGE
 16,000 scfm
   0.72 gr/scf  r
     99 Ib/hr   i
 	 j
                i	
 AMBIENT
 113,900 acfm
  0.0004 gr/scf
    0.39 Ib/hr
  BAGHOUSE
i  SECTION
    7A
:318,000 scfm
*  0.0044 gr/scf
   11.99 Ib/hr
                                      Assumptions:

a.  Grain loading for No.  5 Furnace
    same as No.  7 Furnace.
b.  Baghouses A & C operation identi-
    cal to B.
                    Figure 4.  Run No. 3 - Material Balance
                                          1/20/72
                                       14

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                        IV.   PROCESS DESCRIPTION

     Reactive metals are generally ferroalloys which are produced in
submerged arc electric furnaces.   The facility under consideration in
this report is an open furnace, with hooding and baghouse filtering
systems to reduce the emission of fumes and dust^following collection.
Figures 5 and 6 are process  flow diagrams indicating the actual  furnace
under test in this survey.

     The electric arc is employed as a concentrated source of heat.
Quartzite is added to the surface of the furnace through mechanized equip-
ment and chutes.  Additional carbon in the form of coke, wood chips,
etc., is an integral part of the furnace mix, along with specialized
fluxes, etc.  The mix is added directly to the surface of the furnace
through chutes and is then spread over the surface with stoking  machines.

     The very high temperatures produced initiate a reaction in  the
bottom of the furnace  and form a layer of metal which is tapped at
appropriate times.  As the ores and carbonaceous materials gradually
settle to the bottom of the furnace, the heat, in conjunction with a
lack of oxygen, causes the carbon to react with the oxide ores in order
to remove oxygen and thus produce the elemental metal.  Escaping gases,
composed largely of carbon monoxide, are burned at the surface of the
furnace in the so-called open units.
                                   15

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#7 Furnace
    I     I

    I     I
r	1
i_#5 Furnace J
                                       _^ #5 Baghouse
                                                             .SAMPLING PORTS
                                                                  VELOCITY

                                                                     PORTS
                                                                                  v^x

                                                                                  .  >
                                                                                              EXHAUST
                                                                                 UOI

                                                                                 M
                                                                                           INDUCED AIR
                                            Figure 5.  Process Flow Diagram
                                                           (side view)

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      North
Furnace #5
Furnace #7
        7\
                                Fan
                                          Baghouse Section 7C

Fan

r
AEE



ECE



WCE



AWE



                                          Baghouse Section 7B
                                  Fan
                      o o o o
           I
         \ I
         / i
                                             Baghouse  Section 7A
r
i
                                       i
                                       u
                                     Figure 6.  Exhaust Collection Layout
                                                      (top  view)
                                   17

-------
     Furnace 7 is a nominal 17 megawatt unit producing silicon metal
using prebaked rectangular electrodes in a line.   Induced draft fans  are
employed to pull  fumes into the exhaust system.   Gases and fumes from the
                                                                      i
normal  furnace operation are passed through three parallel baghouses  for
cleaning, prior to discharge into the atmosphere.  The collection of  fumes
around the furnace is almost 100 percent effective during normal operation.
A page of technical data is shown in Appendix C.

     The furnace is tapped at intervals of approximately two hours, depend-
ing upon the total power fed and thereby the amount of metal produced.
Molten metal and slag pour into ladles.  Fumes produced in this operation
are drawn off by a separate exhaust fan.  The collection of these fumes
was nearly 80 or 90 percent effective when observed, but this material  is
emitted to the atmosphere without subsequent cleaning.  Molten product is
poured into molds, after which it is broken into  usable sizes.
                                    18

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                     V.  LOCATION OF SAMPLING POINTS

     Sample port locations were selected where most satisfactory during
a presurvey inspection trip, and approved by the EPA Project Officer.  |
On the collector inlet side, four ports were selected on the top of  the
rectangular horizontal duct, in the middle of a straight section.  The
inlet duct required a framework to suspend the sampling train over the
ports, capable of moving the train horizontally and vertically.   As
shown in Figure 5 the cross section of this duct was divided into seven
equal layers, thus forming a sample profile with 28 equal  areas.  Partic-
ulate tests were conducted for five minutes at the centroid of each  area.

     Twelve ports were selected at the baghouse exhaust monitor.  These
locations were not ideal, but were in the only available location.  Special
platforms were required due to the slope of the roof.  All  sampling  ports
and platforms were provided by the Union Carbide plant.  Figures 6 and 7
show a simplified cross-section of the system under test and indicate the
relative location of sampling ports.  Four EPA trains were employed  at
this one location, one for each three ports.  Only two points were to be
sampled from each port, as shown in Figure 8.

     These downstream sampling locations were agreed upon as acceptable,
although they do not meet the normal criteria as established by EPA.  The
location should have no significant effect on the results due to the small
particle size and low concentration of emissions from baghouses.  Further
comments regarding these problems are found in the Discussion, Section VIII
                                    19

-------
ro
o

















FLOW i
i










i
i
r L o w
^
                  Baghouse 7C
Baghouse 7 B
                                         Figure 7-   Baghouse Exhaust Sample Location

-------
       A B D
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fr fi
o o
0 0
O 0
0 0
0 0
0 0
O 0

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o
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11


t

< 	 E
AEE ECE WCE AWE
r ^ f- ^ r ^\ f \
ABABCABCABC
ooooooooooo
o o o o o o o o o
< -fl' rl
« -0 »|
BA6HOUSE OUTLET
TOP UTFU
1 Ur V1LW
                                                                                                               T
                                                                                                               7'6'
                                                                                                               1
FURNACE EXHAUST DUCT
      END VIEW
                                   Figure 8.  Sample Point Locations

-------
     Because the Furnace 7 baghouse system actually contained three
separate "houses" and exhausts, yet the inlet was sampled for the
total  furnace emission, it became necessary to measure the split of
individual  gas volumes being directed into the three units.  Figure 9
indicates the cross sectional  view of the ducts leading into the respective
induced draft fans.

     High volume air samples were taken at two locations.  The ambient
samples were taken under the middle of "B" baghouse at about 8 feet above
the ground level.  The samples inside the baghouse were taken from a point
above the bags, in the exhaust gas stream inside compartment B-14 (sample
point WCE).
                                   22

-------
                   5'
olO
o 9
o 8
o 7
o 6
o 5
o 4
o 3
o 2
0 1
1-
A
0
o
o
o
o
o
o
o
o
o
H
B
o
o
o
0
0
o
o
o
o
o
hd
C
                                       10
Figure 9.   Inlet Velocity Traverse Points
                   23

-------
                         VI.   PROCESS OPERATION

     Practically all  sampling was carried out while the process was
running normally.  There were periods with furnace "blows" or minor
process load variations but these special conditions were considered
normal operating conditions.

    .Confusion existed as to  whether fumes from Furnace 5 were being
dampered out of the No. 7 furnace duct.  It was determined that part of
Furnace 5 fumes (5% of the total  flow in No. 7 duct) were, in fact,
being ducted into the No. 7 duct.  The damper was left in this configu-
ration for the remainder of the test period.  The leakage caused some
mixing of collected fumes going into the respective dust collection  silos.
This prevents accurate use of information supplied concerning weight of
material collected by the baghouses.  Figures supplied indicate that
43,400 Ibs. were collected in No. 5 silo in 79.5 hours and 68,440 Ibs.
were collected in No. 7 silo  in 68 hours.

     Appendix C tabulates the available operating data.  There were  some
fluctuations in the furnace load during testing, but these were considered
to be within normal operating conditions.  Tapping was conducted as  often
as necessary, depending upon the total power input to the furnace.
                                    24

-------
                        VII.   SAMPLING PROCEDURES



     Test methods were in accordance with the standard  methods  as  pub-

lished in the Federal Register,  Volume 36, Number  159,  Part  II, on August

17, 1971.  See Appendix E for pertinent sections of this  publication.



     Deviations from the above methods were as follows:
     1.  At the inlet, only 7 equal  area points  of 8 on  each  traverse
         were sampled. (Reason:   Duct too deep to reach  last  point
         with 10'  probe.)

     2.  Sampling was in  the monitor at the outlet.
         (Reason:  No stack available, criteria  not applicable.)
     Carbon monoxide was measured using a MSA LIRA*  model  200  infrared

analyzer and results were recorded continuously on a strip chart  recorder.



     High volume air samples were taken using standard  Hi  Vol  air samplers

with 8" x 10" glass fiber filters.  See Appendix E-l.
*Mention of a specific company or product does  not constitute  endorsement
 by EPA.
                                    25

-------
                            VIII.   DISCUSSION

A.  RESULTS
Collection Efficiency
     The efficiency of 7B baghouse was in the range of 98 - 99 percent.
Calculations are based upon the inlet concentration, and the Section 7B
exhaust concentration, along with some assumptions.  (It is necessary to
assume that the ratio of dust flow through 7B baghouse, versus the total
                                                              i
dust flow into all baghouses, is also proportional  to the measured gas
flow.)  Dust concentration in the ambient air induced into the baghouse
averaged 0.25 lbs/hr., which is less than 3% of the average total  emissions.
The calculation of efficiency includes the visible loss of dust from a
leaky bag in compartment 18 (sample point AEE).

Baghouse Emissions
     Each sample was calculated to give emission rates in Ibs/hr based
upon the air flow through each sample area, assuming the total air flow  was
equally split.  Concentration of emissions varied from sample point to sample
point as well as from run to run.   Considering the extremely small quantities
of material collected, the extremes of temperature, and other test problems
that created extremely difficult working conditions, the results appear  to
be reasonably uniform.  Whenever conditions dictate, as these did, that  the
sampling crews can only remain with their equipment a few moments  at a time
without seeking relief, thus preventing close attention to details of equip-
ment operation, it is reasonable to assume that there may be  some small
                                    26

-------
effect on the end results.   Specific observation of crew performance and
the results indicates that the effect, if any, was very slight.

     As expected, the sample obtained from the area with a leaky bag was
appreciably greater in emissions.   Ignoring the area containing  the leaky
bag, this collector appeared to be capable of reducing total  particulate
emissions to approximately 0.004 grains per standard cubic foot  or approxi-
mately 10 Ibs/hr.  The emission of particulate matter, as caught by the
probe and filter alone, was approximately half of this value of  five Ibs/hr.
Particulate concentrations as measured by the high volume air samples were
less than those measured by the front half of the EPA train.   This was
true when comparing only filterable particulate matter.  A partial explana-
tion for the difference may be the difficulty of obtaining accurate gas
flow in the Hi Vol under high temperature conditions.  Two of the Hi Vol
sample results were relatively similar, but the third value was  much greater
than either of the other two.  More than sufficient weight of particulate
matter was trapped on the large filter for accurate weighing, so unless the
sample position was getting less induced air, there is no explanation.

     The above emission values apply only during normal operation, and
cannot be extrapolated to a daily emission without considering the plant
operating factor.

Particulate Versus Total Catch
     The filterable particulate matter at the inlet duct ranged  from 97
to 99 percent of the total catch.   It amounted to approximately  three-
                                    27

-------
quarters of a grain per standard cubic foot or some 2500 Ibs/hr.   However,
at the exhaust monitor, after nearly 99 percent of the total  material  had
been removed, the soluble, nonfilterable portion composed an  average of
half the total weight.  Nonfilterable particulate matter at the exhaust
monitor had a very wide range of values, from approximately 1/4 to 3/4
of the total.  Part of this variation would be due to the recovery of
extremely small amounts of material, where accuracy becomes somewhat ques-
tionable.

Flue Gas Conditions
     The flue gas volume measured at the combined inlet duct  was  relatively
stable when considering the variation in normal operating conditions and
the wide variation in velocity within this particular duct.  No velocity or
flue gas volume measurements were possible at the exhaust monitor.  Total
exhaust flow was based upon the flue gas volume entering the  baghouse, in
addition to the induced air flow that was measured for each baghouse by
the use of a rotating vane anemometer.

Gaseous Emissions
     As expected, the Orsat analyses indicated very low earbon dioxide
content and correspondingly high oxygen concentrations.

     Carbon monoxide measurements were very stable except for occasional
peaks of short duration.  These peaks are believed to be due  to the normal
operational variations encountered during stoking operations.
                                    28

-------
ASME Test Method
     The results of the ASME test were made available through the courtesy
of Union Carbide Corporation, who authorized this sample during the EPA
contract.  The ASME test was conducted during and shortly following the
EPA Test No. ABD-3.  The ASME result of 2020 Ibs/hr would compare to the
EPA value of 2510 Ibs/hr for the period of time immediately following the
EPA test.

B.  OPERATING CONDITIONS
Baghouse System
     Early in the sampling survey, it was noted that the portion of the
baghouse being evaluated under samples AEE had a leaking bag, and visible
emissions.  The results of testing reflect this higher emission rate.  Other
than this single situation the operation of baghouse Section 7B appeared to
be completely normal.  Section 7C was leaking rather badly, and was partially
plugged, and the operation of the overall system was affected in that the
remaining two sections were loaded more heavily than usual.

Furnace 7
     There were occasional shutdowns, which caused some delay, but none
of these occurred during a sample.  Every particulate sample was timed
into the ordinary operating schedule, in order to include two tapping cycles
during the middle of this sample period.
                                   29

-------
Furnace 5
     Confusion existed during the first two days of testing,  as  to  whether
the No. 5 furnace was dampered out of the system under tests, as was  orig-
inally planned.   It was later discovered that some flow was entering  the
No. 7 system.   The velocity and flue gas volume in the duct entering  the
system under test was therefore measured to determine what portion  of the
gas was from Furnace 5.  Approximately 16,000 scfm (which  equals about 4%
of the measured total flow in the No. 7 duct) were coming  from Furnace 5
into the test system.

Silo System
     In conjunction with the emission test being performed, Union Carbide
personnel supplied measurements of dust collected during the  three  day
period.  This  collected dust from the No. 7 silo came to approximately
1600 Ibs/hr.  Although this rate figure is lower than the  measured  inlet
values, two factors play an important part in the difference.  Baghouse
7C had major leaks and was emitting a large amount of dust.   In addition,
there was considerable furnace down time during the overall period  in
which dust was being collected.  Taking these factors into consideration,
there is probably no appreciable difference between the two methods of
obtaining an inlet dust loading to the baghouse.

C.  TEST CONDITIONS
Inlet Duct
     Although there were only four equivalent pipe diameters  of straight
flow prior to the inlet sampling location, the duct prior  to  this obstruc-
                                   30

-------
tion was still in a straight line, but simply in a circular duct.  The
velocity traverse indicated that there were wide variations in the  flow
pattern, which was caused by channel  beams partially blocking flow  approxi-
mately one equivalent diameter before the sample location.   A good  trolley
arrangement provided excellent handling of the EPA train even in  the  ver-
tical position.

     After completion of the first test it was discovered that one  of
the four filters had been placed on the wrong side of the glass frit.
A- decision was made to attempt salvage of'the sample, but to repeat the
test in order to be sure of three good runs.  The frit was cleaned  in
acetone with an ultrasonic cleaner and the results would indicate,  that
if anything, the value was on the high side.  This would seem feasible
due to the possibility of the frit losing small amounts of the glass
particles.

Exhaust Duct
     The monitor configuration of the baghouse did not allow application
of normal procedures for sampling.  This phase of the test was a  monitor
study, not a normal stack sample.  A rough estimate of percent isokinetic
for the samples, assuming an average velocity calculated from the area and
stack flow, gives a range of 125% - 165% isokinetic, with an average of
145% isokinetic.  Past experience had shown that particulate matter escaping
from a baghouse is normally composed of very fine particle size,  thus
allowing a representative sample to be obtained under non-isokinetic con-
                                   31

-------
ditions.  Previous particle size measurements,  on  a  similar  installation,
have supported this position,  as well  as  emphasizing the  need for a
greater amount of material  to  be collected and  weighed.

     Only four 10-foot probes  were available, therefore the  AEE sample
series was conducted using a 5-foot glass lined probe, while the other
locations employed the 10-foot incaloy lined probe.   For this  reason,  only
the near (No. 1) points could  be sampled with this train.  Not  only was
this compromise necessary, but, due to the closeness of the  roof edge  and
lack of platform, one port in  this same AEE sample series could not be
reached.  While all other exhaust samples contained  six equal  areas, this
location represented only two  of those six equal  areas.  The first  sample
obtained at this location was  of particularly short  duration due to the
melted vacuum line in the umbilical cord.

Power
     Individual circuits were  available for all testing equipment so that
there were no problems of power failure at any of the five locations.

Filter Plugging
     Although the dust loading at the inlet duct was not as  great as had
sometimes been experienced at  similar plants, it was sufficient, so that
even with four inch filters, it was necessary to replace the  filter after
a single sample port had been  traversed.  This meant that four filters
were normally necessary for every test.  There were  no deviations necessary
from the standard testing procedures due to this dust loading  problem.   No
                                    32

-------
particle size evaluation is available, but it would appear that the  silicon
furnace may emit a particle that is particularly able to form a dense  mat
on a filter surface.

Induced Air
     Induced air was measured using a rotary vane anemometer to measure
the air flow around each bag compartment.   The anemometer was placed on
the grating, so that calculation of effective open area was necessary. ,
Every other compartment was tested for each of the three baghouses.  Each
compartment was measured at ten points within the open area.  Part of  the
open area was unobstructed but the remainder was covered with grating, i
which was measured at 80% effectively open area.  The total open area  was
therefore calculated using the above data.  The induced gas volume deter-
mined by these measurements was added to the respective measured volume  of
flue gas at the individual inlet to the baghouse.  This sum produced a
total baghouse exhaust volume.

Individual Velocity
     Flue gas volume entering each individual baghouse was measured  with
a pitot traverse of the duct immediately preceding that respective induced
draft fan.  The entrance pipe nipples on these ducts were somewhat awkward,
and made it very difficult to reach the extreme traverse points.  The
velocity appeared to be relatively uniform within each duct, however,
therefore it is believed that no significant errors were introduced  because
of this problem.
                                    33

-------
HI VOL Sampling
     High volume air samples were obtained without particular problem or
unusual conditions, except for temperature.  Procedures for the Hi  Vol
samplers have become quite standardized and straightforward.   The only
difficulty was in operation of the unit when placed inside the exhaust
duct from the baghouse.  This was physically difficult to position.  High
temperatures may have some effect upon the gas flow measurements and
induced air flow possibly was not well mixed with the exhaust gas flow.

Miscellaneous Problems
     Several problems concentrated upon a single area at the exhaust moni-
tor.  AEE samples did not cover the entire area originally designed, and
because of the short 5-foot probe there was an extreme to the already
severe temperature problem.  The first sample was considerably shortened
when the umbilical cord was melted and the sample line collasped.  Exhaust
gases  of 160° to 200°F were directed at each sample location.  Depending
upon the direction and temperature of the wind this hot exhaust gas was
very detrimental to both sampling equipment and personnel.  Throughout
the entire testing period, difficulty was encountered in keeping all pumps
running due to overheating.  It was not possible to operate the meter boxes
from any more acceptable location, and the sample boxes were continually
exposed to heat.  Even with makeshift heat deflectors it was not possible to
keep  samples properly  cooled.  In excess of 100 pounds of ice was used each
day,  but  some  samples  became so  hot that some of the impinger water evaporated.
The silica gel was not able to recover this loss at these high temperatures.
                                   34

-------
Silica gel normally collected only a small  amount of water,  therefore the
true moisture contents are in doubt.  Only during the last test,  taken on
a cold rainy day with favorable wind conditions, was there a gain in
condensate for these samples.

     While the exhaust location was uncomfortably warm, the opposite
extreme was present at the inlet duct.  Dry cell batteries in the ther-
mocouple potentiometer were actually freezing, and affecting thermocouple
readings.  All samples the last two days were conducted during rain.  Due
to an early misreading of inlet duct temperature, the nomograph was in-
correctly set and isokinetic rates were considerably greater than our
normal accuracy, although they are within the 20% allowance that has been
considered acceptable.  We were able to correct or adapt for the  problems
encountered with the extremes of weather and location and thus there were
no significant effects on the results of the tests.

     The water sample was lost by personnel handling error on exhaust
sample WCE-1, therefore, the amount of soluble particulate matter residue
was not in line with other samples.
                                    35

-------
IX.   APPENDIX
      36

-------
         APPENDIX A

COMPLETE PARTICULATE RESULTS
  WITH EXAMPLE CALCULATIONS

-------
REPORT NO.
                                    PAGE
                         OF
            PAGES
                       SOURCE TESTING CALCULATION FORMS
Test No.  One  to  Four



Name of Firm	Union Carbide
                                         No. Runs   Four
Location of Plant_




Type of Plant	
Alloy, West Virginia
Reactive Metals
Control Equipment
Baqhouse
Sampling Point Locations  Combined  Inlet Duct




Pollutants Sampled	Total  Particul ate
Time of Particulate Test:
Run No.  ABD-1
  Date    1/17/72
Begin   1112
End   1440
Run No.  ABD-2
  Date    1/18/72
Begin   1135
End   141 3
Run No.  ABD-3
  Date    1/19/72
Begin   0900
End   1145
Run No.  ABD-4
  Date    1/20/72
Begin   1416
End   1702
                           PARTICULATE EMISSION DATA
Run No.
P, barometric pressure, "Hg Absolute
P orifice pressure drop, "H-O
V volume of dry gas sampled @ meter
conditions, ft.3
T Average Gas Meter Temperature, °F
V Volume of Dry Gas Sampled @
std. Standard Conditions, ft.3
V Total H20 collected, ml., Impingers
& Silica Gel.
V Volume of Water Vapor Collected
gas ft.3 @ Standard Conditions*
ABD-1
29.94
1.93
97.93
88
95.15
5.7
0.27
ABD-2
29.80
2.25
101.58
91
97.78
11.2
0.53
ABD-3
29.97
1.97
98.84
106
93.08
33.6
1.59
ABD-4
29.99
2.03
102.49
106
96.60
34.4
1.63
















 * 70°F, 29.92" Hg.
                                      A-l

-------
PARTICULATE EMISSION DATA (CONT'D)
Run No.
7M-7, Moisture in the stack gas by
volume
Md - Mole fraction of dry gas
7. C02

7. 02
7. No

M W,j - Molecular weight of dry
stack gas
M W - Molecular weight of stack gas
A Ps - Velocity Head of stack gas,
In.H20
Ts - Stack Temperature, °F
&PS X(TS + 460) (Average)
Ps - Stack Pressure, "Hg. Absolute
Vs - Stack Velocity @ stack
conditions, fpm
2
As - Stack Area, in.
Qs - Stack Gas Volume @
Standard Conditions, *SCFM
Tt - Net Time of Test, min.
Dn - Sampling Nozzle Diameter, in.
%I - Percent isokinetic
mf - Particulate - probe, cyclone
and filter, mg.
mt - Particulate - total, mg
Can - Particulate - probe, cyclone,
and filter, gr/SCF
Cao - Particulate - total, gr/SCF
Cat " Particulate - probe, cyclone,
and filter,
gr/cf @ stack conditions
ABD-1
0.28
0.997





28.96
28.93
1.25
300
30.05
29.68
4460
19044
407,000
140
0.1875
115
5037.2
5091 . 3
0.8153
0.8240
0.5619
ABD-2
0.54
0.995


	


29.96
28.91
1.40
300
31.83
29.54
4740
19044
430,000
140
0.1875
112
3414.6
3459.2
0.5378
0.5448
0.3681
ABD-3
1.68
0.983


	 .


28.96
28.77
1.24
310
29.66
29.71
4410
19044
392,000
140
0.1875
117
4486.2
4511.8
0.7422
0.7464
0.4983
ABD-4
1.66
0.983


	 u . L


28.96
28.77
1.21
307
30.04
29.73
4470
19044
399,000
140
0.1875
119
4532.9
4691.8
0.7226
0.7480
0.4873
INLET
ORSAT


n Q

20.4
78.7











































                 A-2

-------
                     PARTICULATE EMISSION DATA  (cont'd)
Run No.
C - Particulate, total, gr/cf
@ stack cond.
C - Particulate, probe, cyclone,
aw and filter, Ib/hr.
C - Particulate - total, Ib/hr.
. £LX
% EA- % Excess air @
sampling point
ABD-1
0.5679
2842
2873

ABD-2
0.3729
1981
2007

ABD-3
0.5011
2493
2507
_
ABD-4
0.5045
2471
2556
_
ORSAT



3800





* 7r.o
TO°F, 29.92" Hg.
                                    A-3

-------
REPORT NO.
PAGE
OF
PAGES
                       SOURCE TESTING CALCULATION FORMS
Test No. One
Name of Firm
Location of Plant
Type of Plant
Control Equipment

Union Carbide
Alloy, West Virginia
Reactive Metals
Baghouse
No. Runs Four




Sampling Point Locations Across Area of Exhaust Monitor
Pollutants Sampled
Time of Particulate
Run No. AEE-1
Run No. ECE-1
Run No. WCE-1
Run No. AWE-1
Total Particulate
Test:
Date 1/17/72 Begin 1322
Date 1/17/72 Begin 1217
Date 1/17/72 Begin 1130
Date 1/17/72 Begin 1045

Eiid 1430
End 1735
End 1735
End 1 652
PARTICULATE EMISSION DATA
Run No .
P, barometric pressure, "Hg Absolute
P orifice pressure drop, "HpO
V volume of dry gas sampled @ meter
conditions, ft.3
T Average Gas Meter Temperature, °F
V Volume of Dry Gas Sampled @
std. Standard Conditions, ft. 3
V Total HpO collected, ml., Impingers
& Silica Gel.
V Volume of Water Vapor Collected
Wgas ft.3 @ Standard Conditions*
AEE-1
29.94
2.9
73.845
123
67.60
-15.3
-0.73
ECE-1
29.94
2.7
260.29
128
236.14
-64.9
-3.08
WCE-1
29.94
3.0
349.76
143
309.65
•176.2
-8.35
AWE-1
29.94
3.3
366.85
125
335.01
•112.8
-5.35
















 * 70°F, 29.92" Hg.
                                      A-4

-------
                        PARTICIPATE EMISSION DATA  (CONT'D)
Run No.
7M-7, Moisture in the stark gas by
volume
Md - Mole fraction of dry gas
7. C02

% Oo

7. No

M W
-------
                   PARTICULATE EMISSION DATA (cont'd)
Run No.
C - Particulate, total, gr/cf
@ stack cond.
C - Particulate, probe, cyclone,
aw and filter, Ib/hr.
'C - Particulate - total, Ib/hr.
3>X
% EA- % Excess air @
sampling point
AEE-1
0.0113
16.6
26.6

ECE-1
0.0043
7.6
10.1

WCE-1
0.0019
3.5
4.5

AWE-1
0.001-6
3.7
3.9











70°F, 29.92" Hg.
                                  A-6

-------
REPORT NO.
                                               PAGE
                         OF
            PAGES
                       SOURCE TESTING CALCULATION FORMS
Test No.
TWO
                  No. Runs    Four
Name of Firm
           Union Carbide
Location of Plant
Type of Plant	
           Alloy, West Virginia
           Reactive Metals
Control Equipment
           Baghouse
Sampling Point Locations Across Area of Exhaust Monitor
Pollutants Sampled	Total Participate	
Time of Particulate Test:
Run No.   AEE-2
Run No.   ECE-2
'Run No.   MCE-2
Run No.   AWE-2
             Date   1/18/72
             Date   1/18/72
             Date   1/18/72
             Date   1/18/72
Begin   1215
End   171 5
Begin   12QQ
End   1800
Begin   1U5
End   1749
Begin   1130
End   1730
                           PARTICULATE EMISSION DATA
Run No.
P, "barometric pressure, "Hg Absolute
P orifice pressure drop, "HpO
V volume of dry gas sampled @ meter
conditions, ft.3
T Average Gas Meter Temperature, °F
V Volume of Dry Gas Sampled @
mstd. Standard Conditions, ft.3
V Total HpO collected, ml. , Impingers
& Silica Gel.
V Volume of Water Vapor Collected
Wgas ft.3 @ Standard Conditions*
AEE-2
29.80
2.9
316.33
117
291.24
-35.0
-1.66
ECE-2
29.80
2.6
341.85
117
314.50
-48.6
-2.30
WCE-2
29.80
3.3
361 .95
133
324.57
-63.7
-3.02
AWE-2
29.80
3.2
364.72
117
336.04
-64.7
-3.07
















  * TO°F, 29.92" Hg.
                                      A-7

-------
                        PARTICULATE EMISSION DATA (CONT'D)
Run No.
7M -7, Moisture in the stack gas by
volume
M
-------
                PARTICULATE  EMISSION DATA  (cont'd)
Run No.
C - Particulate, total, gr/cf
§ stack cond.
C - Particulate, probe, cyclone,
aw and filter, Ib/hr.
C - Particulate - total, Ib/hr.
ax '
% EA- % Excess air @
sampling point
AEE-2
0.0087
21.0
27.0

ECE-2
0.0029
3.8
9.2

WCE-2
0.0032
5.6
9.9

AWE-2
0.0029
3.4
9.2











JF,  29.92"  Hg.
                                A-9

-------
REPORT NO.
                                    PAGE
                         OF
            PAGES
                       SOURCE TESTING CALCULATION FORMS
Test No.    Three
Name of Firm
                                         No. Runs    Four
Union Carbide
Location of Plant	Alloy. West Virginia
Type of Plant	Reactive Metals	
Control Equipment
Baqhouse
Sampling Point Locations Across Area of Exhaust Monitor
Pollutants Sampled	Total Participate	
Time of Particulate Test:
Run No.  AEE-3
Run No.   ECE-3
Run No.   WCE-3
Run No.  AWE-3
  Date   1/20/72
  Date   1/20/72
  Date   1/20/72
  Date   1/20/72
Begin   1405
End   2000
Begin   1430
End   1941
Begin   151Q
End   2000
Begin   1500
End	1952
                           PARTICULATE EMISSION DATA
Run No.
P, barometric pressure, "Hg Absolute
P orifice pressure drop, "HJD
V volume of dry gas sampled @ meter
conditions, ft. 3
T Average Gas Meter Temperature, °F
V Volume of Dry Gas Sampled @
std. Standard Conditions, ft. 3
V Total H20 collected, ml., Impingers
& Silica Gel.
V Volume of Water Vapor Collected
Wgas ft. 3 @ Standard Conditions*
AEE-3
29.99
2.4
336.53
121
309.28
2.9
0.14
ECE-3
29.99
2.9
309.09
125
282.46
32.4
1.54
WCE-3
29.99
3.1
276.80
108
260.65
32.1
1.52
AWE- 3
29.99
3.3
301.23
no
282.80
4.7
0.22
OUTLET
ORSAT















 * 70°F, 29.92" Hg.
                                    A-10

-------
                        PARTICULATE EMISSION DATA  (CONT'D)
Run No.
7M -% Moisture in the stack gas by
volume
Md - Mole fraction of dry gas
7. C02

% 02

% N2

M W(j - Molecular weight of dry
stack gas
M W - Molecular weight of stack gas
A Ps - Velocity Head of stack gas,
In.HoO

Ts - Stack Temperature, °F
&P8 X(TS + 460) , .
0 . lAveraee )
Ps - Stack Pressure, "Hg. Absolute
Vs - Stack Velocity @ stack
conditions, fpm
o
As - Stack Area, in.
Qs - Stack Gas Volume @
Standard Conditions, *SCFM
Tt - Net Time of Test, min.
D,j - Sampling Nozzle Diameter, in.
7,1 - Percent isokinetic
mf - Particulate - probe, cyclone
and filter, mg.
m^ - Particulate - total, mg
Can - Particulate - probe, cyclone,
and filter, gr/SCF
Cao - Particulate - total, gr/SCF
Cat - Particulate - probe, cyclone,
and filter,
gr/cf @ stack conditions
AEE-3
0.05
1.00






28.86
28.86


200


29.99
620*
62,640
269,650
333
.500
140*
51.4
73.0
0.0026
0.0036
0.0021
ECE-3
0.50
0.995






28.86
28.81


200


29.99
620*
62.640
269,650
281
.500
153*
32.4
109.1
0.0018
0.0059
0.0021
WCE-3
0.55
0.995






28.86
28.81


200


29.99
620*
62.640
269,650
247
.500
160*
29.4
66.5
0.0017
0.0039
0.0014
AWE-3
0.07
1.00






28.86
28.86


200


29.99
620*
62.640
269,650
292
.500
146*
28.3
73.1
0.0015
0.0040
0.0012
OUTLET
ORSAT


0 2

on 7
£U. /
70 i
















































*Approximate value.
                                        A-ll

-------
                     PARTICULATE EMISSION DATA (cont'd)
Run No.
C - Particulate, total, gr/cf
@ stack cond.
C - Particulate, probe, cyclone,
aw and filter, Ib/hr.
C - Particulate - total, Ib/hr.
ax ' .
% EA- % Excess air §
sampling point
AEE-3
0.0029
6.0
8.3

ECE-3
0.0047
4.2
13.6

WCE-3
0.0031
3.9
9.0

AWE-3
0.0032
3.5
9.2

OUTLET
ORSAT



fiinn





* 70°F, 29.92" Hg.
                                   A-12

-------
                     SAMPLE PARTICULATE CALCULATIONS
                              TEST ABD-T

1.  Volume.of dry  gas  sampled at standard conditions - 70°F,  29.92"
    Hg, ft3.
            17'7 x  Vm    PB + Pm
    \td
            17.7 X 97.93  (29.94

            	'*""   = 95.15
                 (88 + 460)
2.  Volume of water  vapor at 70°F and 29.92" Hg, Ft.3
    V     = 0.0474  X  V  = ft.3
     wgas             w
          = 0.0474  X 5.7  =  0.27
3.  % moisture in  stack gas
         100 X V
         	gas    = %
         'V     + V
          mstd    wgas
          100 X 0.27
        =  95.15 + 0.27   = °-28
                          A-13

-------
4.  Mole fraction of dry gas

    M  _ TOO - %M
    Md "    100
         100-0.28  _
                     "
5.  Average molecular weight of dry  stack  gas


    M W d = (%C02 X ,$)  + (%02 X  ^)  +  (%N2  X


     (0.9 X     ) +  (20.4 X     ) +  (78.7 X     ) - 28.96
6.  Molecular weight of stack gas


    M W = M W d X Md + 18 (1  - Md)


      28.96 X  .997 + 18  (1-.997) = 28.93
7.  Stack velocity @ stack conditions,  fpm
                                             _l/2
                  Average
       « 4350 XVAPS X (Ts  + 460)     p   X'M  M      = fpm



       = 4350 X (30.05) (,u ku 1 ,u ....  ) 1/2  = 4461.
                         A-14

-------
 8.  Stack gas volume @ standard conditions,  SCFM  (dry)

          0.123 X V  X A  X M ,  X P
     n  _ 	s    s    d     s   _  crFM
     Qs	(T  + 460)	SCFM
          0.123 X 4461 X 19,044 X .997 X 29.68
                      (300 + 460)                •"""
 9.  Percent isokinetic

          1032 X (T  + 460)  X V
          Vs X Tt X Ps  X M(j X (D/


        = 1032 X (300 + 460) X 95.15	

          4461 X 140 X 29.68 X .997 X (.1875)2
10.  Parti cul ate - probe,  cyclone,  and  filter, gr/SCF

                      Mf
     Can =  0.0154 X if-1 —  =  gr/scf
      on            V.—
                     mstd
         = 0.015 X        =  0.815
11.  Particulate total,  gr/SCF

                      Mt
     Cao = 0.0154 X Y~ i-  =  gr/SCF

                     mstd
         = 0.0154 X        = .824
                             A-15

-------
12.  Participate - probe, cyclone and filter,

     gr/CF at stack conditions
           17.7 X C   X P  X M ,
     r-   _    _   an    s    a

     Cat -- (Ts + 460) --
         - 17.7 X 0.815 X 29.68 X .997

               (300 + 460)          ~~ .
13.  Particulate - total, gr/CF @ stack conditions



           17.7 X C   X Pc X M .
     C   - __  30    S    a    ,,,«//-r

     Cau -- (Ty '+ 460) -- gr/CF
                 y
                 A
         - 17.7 X .824 X 29.68 X .997 = n ,-co

               (300 + 460)              U'ODO
14.  Particulate - probe,  cyclone filter filter,  Ib/hr.



     Caw = 0.00857 X Can X Qs  =  Ib/hr.
         = 0.00857 X 0.815 X 406856 = 2842
15.  Particulate - total,  Ib/hr.



     Cav = 0.00857 X C n X (D  =  Ib/hr.
      ax              ao    s
         = 0.00857 X 0.824 X 406856 = 2873
                            A-16

-------
16.  % excess air at sampling  point


               100 X % 0,
     *L FA a                    -  "I
     * c   (0.266 X % N2)-% 02   /e



          -    100 X 20.4         _
           (0.266 X 78.7)  - 20.4
                            A-17

-------
I
CO
                                                          AMBIENT*
Date
1/17/72
1/18/72
1/20/72
Net Weight
(gin)
0.3512
0.3641
0.3132
Avg. Flow
(cfm)
43
49
47
Volume
(ft3)
10,793
13,377
12,126
Time
(min. )
251
273
258
Concentration Emissions (as is)
yg/m3 gr/ft3 Ibs/hr
1148
961
912
0.000502
0.000420
0.000399
0.280
0.235
0.222
                                                        IN BAGHOUSE*
1/17/72
1/18/72
1/20/72
0.4986
0.4532
0.4524
39
35
39
5,148
9,170
9,750
                                                                    132
                                                                    262
                                                                    250
3420
1745
1639
0.001495
0.000763
0.000716
3.53
2.36
2.06
                                          HIGH VOLUME AIR SAMPLES DATA AND RESULTS
           *Locations:  Ambient Hi Vol suspended 8' above ground level beneath 7B baghouse.
                        Baghouse Hi Vol located beneath the general  position of EPA train WCE, center port
                        and front sample point (compartment B-14).

-------
EXAMPLE CALCULATION - GRAIN LOADINGS
(Ambient 1/17/72)

          43 ft3/min. x 251 min.  = 10,793 ft3
     .  0^3512  = 3>25 x 1Q-5 are  x 35>314 x 1(J6 = 1148
ft3     10'793                ft3

              x 15.432 = gr/ft3
                15.432 = 0.000502 gr/ft3
(Baghouse 1/17/72)

          39 ft3/min. x 132 min.  = 5,148 ft3
gms  =  0.4986  = g>69 x 1Q-5 gms  w  ,K Q1A v
ft3     -
                15.432 = gr/ft3
              x 15.432 = 0.001495 gr/ft3
HI VOL SAMPLE CALCULATION - MASS RATES
(Sample # 1 Ambient)
     x Vol (acfm) = gr/min.
gr/min. x 1.429 x 10~4 x 60 = Ibs/hr.
0.000502 x 65,150 = 32.71  Ibs/hr
32.71 x 1.429 x 10"4 x 60 = 0.280 Ibs/hr.
(Sample # 1  Baghouse)

Baghouse  T_(°R)    x      gr             gr
    STD  T™         ft3 as is     "    scf

      x Vol  (scfm) = gr/min.  x 1.429  x  10"4 x  60 =  Ibs/hr.
x °-001495 = 0.001805 gr/scf
                        60
                       A-19
0.001805 x 228,150 x 1.429 x 10"4  x  60 =  3.53  Ibs/hr.

-------
                ASME TEST RESULTS (ASD-1)*
       _  17.7 x 75.4 x 29.97   _ 7. D
Vm     ~        ~W          " 73'8
 mstd
V       = -0.94 (at standard conditions)
 wgas
%M      =0 (% moisture by volume)
Md      =1 (mole fraction of dry gas)
MWd     = 28.96 (dry molecular weight)
MW      = 28.77 (molecular weight)
V       = 4413 (stack velocity at stack conditions, fpm)  per EPA probe
Qs      = 392,069(stack gas volume at standard conditions) per EPA probe
Cao     =0.60 (particulate, grains/scf dry)
Cau     =0.41 (particulate, grains/scf @ stack conditions)
CauX    = 2016 (particulate, Ib/hr)
*Sample taken at inlet duct, trailing EPA sample on 1/19/72, using
 velocity at each equal area point as just obtained with EPA pi tot probe.
 The above data courtesy of The Union Carbide Corporation.
                                  A-20

-------
           SAMPLE CALCULATION - COLLECTION EFFICIENCY (Run #2)

A Baghouse Flow + B Baghouse Flow + C Baghouse Flow = Total Flow In
204,100+216,500+21,900=442,500

8            ™         % of flow' B
442 5oo  x  100 = 48.9 (or approximately 49%)
Ib/hr to B Baghouse = total Ib/hr in  x TO tallow in
                      2007 x .489 = 981 Ibs/hr.
Efficiency = 1b/hr t°1h  fr°m B x 100
                                  x 10° = 98<6% caPture Efficiency
                                   A-21

-------
                    APPENDIX B
COMPLETE GASEOUS RESULTS WITH EXAMPLE CALCULATIONS

-------
               BAGHOUSE EXHAUST VOLUME RESULTS
 Individual  inlet duct, scfm
 Compartments
 Induced Air Velocity, fpm
 Induced Air Flow, cfm ambient
 Total  Exhaust Volume, scfm


1/17/72
1/18/72
1/20/72



MM/12
1/18/72
1/20/72

A
207,200
204,100
--
10
127.4
113,900
321,100
318,000
--
Baghouse
B
163,000
216,500
204,500
8
91.1
65,150
228,150
281 ,650
269,650

C
21,900
21 ,900
--
3
160*
10,000**
31 ,900
31,900
--
 *Value of little use due to large areas  of plugged  grating.
** Estimated from velocity measured and area plugged.
                                     B-l

-------
            Sample Calculation - Baghouse Exhaust Volume (B)







Total Air flow area around each compartment (per diagram):




       ,     (2 x 1.5'  x 21.5') + (2 x 1.5'  x 14') = 106.5 ft2





Effective area = [(grating area x % open) + non grating  area] x  No.  Compartments




               = [(85.5 ft2 x 0.80) + 21.0 ft2] x 8




               =715.2 ft2





Air Induced    = Velocity x area




               = 91.1  fpm x 715.2 ft2




               = 65,150 cfm





Total Flow, Q  = Air entering inlet fan + Air induced




               = 204,500 scfm + 65,150 cfm ambient




               = 269,650 scfm*
*Assuming Ambient Equivalent To Standard.
                                   B-2

-------
     The following 8 pages are chart recordings  of the  results  from  the
carbon monoxide measurements made by infrared analyzer  at the inlet  duct
sampling location (ABD).   See notes on each page for explanation.
                                   B-3

-------
w

-------
I

-------
Continued from Preceding Page
                    I  ' I ' l :  i  i

-------
 1.
T
3
4
5!
                     T
                          t
                           I
        7!
         i I

-------
Continued from Preceding Page

-------
s?
h
10
fe
H

g
n
 2

 §
 o
 S

 S
 a
 c

-------
Highest
Level
Measured
193 ppm

-------
u
S
P
^



I

H
o

o
 o
8

-------
Part 10, p.  7 of 8
                                    ORSAT  FIELD  DATA
Location_
Date      j-  T-O -
Time
            Operator
                                                      Comments: &
Test
/
*>
3
y
A^ %



(co2)
Reading 1
/. d).
/, o
<9. ?* •'•
0.1
0.1?*



(o2)
Reading 2
c5/J'
^/•7
^-0,7
•20 J
56,a3



(CO)
Reading 3
P / ^ "
;^ /, 7
P 0,9 ' '•
^^).'' . '
0*7*



 NCAP-31  (12/67)
                                    B-12

-------
   t 10, p. 7 of 8
                                  ORSAT FIELD DATA
Location/^ L±.$Y  B
           n ,      *-A
           Date /--2-^-


           Time
           Operator
                    uej
                                                    Comments:
           Test
(co2)

Reading 1
                                 (o2)

                                 Reading 2
(CO)


Reading  3
                          ,3
                                •""' /
                                '  • / .
                            P-
                Z.I..D
NCAP-31^(12/67)
                                  B-13

-------
                     APPENDIX C



COMPLETE OPERATION RESULTS WITH EXAMPLE CALCULATIONS

-------
                                    FACT SHEET

                             FURNACE 7  DUST  COLLECTOR
                            ALLOY.  WEST VIRGINIA PLANT
                               FERROALLOYS DIVISION
                             UNION  CARBIDE CORPORATION
  I.   Manufacturer

-II.   Completion Date

III.   Installed Cost

 IV.   Performance Data

      a.   Furnace Type
      b.   Furnace Electrode Arrangement
      c.   Furnace Power
      d.   Furnace Product
      e.   Design Gas Flow
      f.   Design Gas  Temperature @ collector
      g.   Guaranteed Minimum Collection
          Efficiency
      h.   Fan Power Rating
      i.   Amount of Collected Fume

  V.   Physical  Data

      a.   Number of Bags
      b.   Bag-type
      c.
Size
    Bag

    1)  Diameter
    2)  Length

d.  Total  Cloth Area

e.  Method of Bag Cleaning
f.  Total  Number of Compartments
g.  Number of compartments on-l,ine
h.  Number of Bag Houses
      i.   Size of Bag House
          1)  Length
          2)  Width
          3)  Height

      j.   Total  Weight of Installation


          Silos #5 & #7
            Emptied #5:


            Emptied #7:
                                    Wheelabrator Corporation

                                    May 28,  1971

                                    $3,000,000
                                    Packet electrode
                                    Three-in-line
                                    25 Hz.
                                    Silicon alloys
                                    620,000 actual  cu.ft./min.
                                    310°F

                                    Greater than 99.5%
                                    4500 HP, 60 Hz.
                                    12 to 13 tons/day
                                    3744
                                    Fiberglass cloth,  graphite-silicone
                                      treated
                                                  11-1/2 inches
                                                  30-1/2 feet

                                                  344,000 square feet,  or
                                                  7.90 acres
                                                  shaking
                                                  26
                                                  24
                                                  3
                                            B
                        72 ft.-6 inches 58 ft.-O inches
                        53 ft.-8 inches 53 ft.-8 inches
                        77 ft.-O inches 77 ft.-O inches

                                    2,100,000 Ibs.,  or
                                    1,050 tons
                                                                 58 ft.-O inches
                                                                 53 ft.-8 inches
                                                                 77 ft.-O inches
                                         C-l
                                    1/17/72
                                    1/20/72

                                    1/17/72
                                    1/20/72
                                                     11:30 A.M.
                                                      7:00 P.M.

                                                     10:00 P.M.
                                                      6:00 P.M.
Dust: 43,400 Ibs
Dust: 68,440 Ibs

-------
APPENDIX D



FIELD DATA

-------
   Part 10, p. 4 of 8
PI ant
Run No.
Location ~

Dcte    v-
Oparator
                           PARTICULATE FIELD DATA


                     VERY IMPORTANT - FILLJR.ALL^ BLANKS

                     Read and record at the start of each
                     test point or, if single point
                     sampling, read and record every 5
                     minutes.
                      Sample Box Mo.

                           t Box No. _

                      Probe Length
                                                                             Me
                                                   Ambient Temp °F_

                                                   Bar. Press. "Hg
                      Proba Heater Setting
                                                   Assumed Moisture %_

                                                   Heater Box Setting,

                                                   Probe Tip Ola., In.
Point
          Clock
 Dry Gas
Keter, CF
 Pi tot
in. F,2°
   AP
                                             Orifice  AH
                                                in H-,0
                                           Desired
                                                      Actual
                                                               Dry Gas Temp.
Inlet   Outlet
 Pump
Vacuum
In. Hg
Gouge
Box
Temp.
 °F
                                                                                              Impinger
                                                                                               Tsmp
°F
Stcck
Press
in. rig
Stock
Temp
 op
           . /
      0 1
                                     /./ii
         in a a.
       \ll\H

                                                                                                (,0
                       . ID
                                    3. it)
*
        n •
              • ( o > •* »
                                         7 o
                                                                                                ('0
m   .uu.
                      . £ *
                                            1 pt
                                                                                        j/'
                                                                 1.0
±--c- 1  to; AS
               ,/»
                         ,  n
                                                                        7?
    2
                                                       /.
                                                      Tr
                                                                       to
    V
                                                    73L
        ya:«*>
                      . A
                          J.
                                                           V-  YJoo
                                        91.
       M :
                                 .
             I ,eu
                                                                                               s/
  ^J_
                                 -\—L
                                             >>->+
                                     I ?o
                                                               IPO
          . * :T   i
   • 7 o
                                 96
                                                                               r/
                                1 .*o\-\     1.7*
                                                        iL
                                                                             si/

-------
«? •• : jif. '
Point
sit' • '•
Hi -I
i 1-
! ' 3
•S M
^ 2"
i1 (r
r/U-S

L-




•





,
I ;
i

i
Clock
Tir:-,-
la 'o <
A&Vy *
/«/.'/ tf'
«y Ji»
/tf i i.r
j«:sa
w ', iy
/v; wo



	 ••--
T

Mo n/M
Dry Gas
Meter, CF

597. to"^
'to/^C
JeS'i/iC
.1
^

eo.^o
j»< I* ^
I 3. fl Sf
>sT« 9*y



— ~-- 	 - -
*?7.^ 3 ^

.
\











.












-






Pilot
in. H20
AP

a.«/o'>i
2.«70/.U'
1 » 3 *»;./*'
I , baj.ui
) , I il^
1. OT_ ,)''
y , o i^.0/




1 .2.5 '

Orifice AH
in H-,0
Desired

ty ,00
• ^,So
5. to
3 , oo
i tq if
i . I'D
I ,•) C





•
1
•7 1




























Actual

. //.a b
0 "k -50
Dry Gas Temp.
op
Inlet j Outlet

95-
1 e>*4
"\ ") >£«> 1 /<"/
V,^TO
. to
. ffi'
, aro
- .-,' . ^


J.q3s


-


IDL
lot.
lot.
J o L



• ''
^S ^
\
V



j
















1







? y
9 o
9 °
9 o
f)t^.
9 V-
4l-



--•:••••• • •
?? O ^
X
8

7 i .


PliHIp
Vacuum
In. Hg
Gouge

£.
if
/?5
^35^
JL^
21 JT
^^











1







I




















Box
Temp.

«3J





^

ro





^ .
























Impinger
- Temp
°r

& o





V






/

























Stack
Press
in. Hg

'stf}.6>&





^






/

























Stsck
Temp
°F





i
/
, W
1 "^



•-..











1





i
!
Ccitpents:



NCAP-37'(12/67)

-------
   Part.'ID-,  p. 4 of 8
                                             PARTI CULATE  FIELD DATA
                                 I  \   VERY IMPORTANT -  FILL  IN,ALL BLANKS
                                    }
PI ant
                                    Read and record at the start of each
                                    test point  or, if single point
                                    sampling, read and record every 5
                                    minutes.
Run No.

Location
                                               Box No.

                                        Meter Box No.

                                        Probe Length
                                                                             Ambient Temp  °F

                                                                             Bar.  Press. "H
                                                                                                    4/0
                                                     //'¥
Operator
                                     Probe  Heater Setting    . 3"e>
                                               Assumed Moisture %_

                                               Hecter Box Setting,

                                               Probe Tip Dia., In._
Point
          Clock
                Dry Gas
               Meter, CF
                               Pi tot
                              in. H20
           Orifice  AH
              in HoO
                                          Dos i red
                   Actual
                   Dry Gas  Temp.
                        op
                   Inlet 1  Outlet
 Pump
Vacuum
In. Hg
Gouge
Box
Tercp.
 °F
Impir.ger
 •Tsxp
   °r
Stcck
Press
in. rig
Stack
Temp
                                                     ?>?*
                                                                   6jL
                                                                      6,0
                                                            ,  ?•
        // : rC
                               -L~
                 3FV.
                                                          /CO
                                                                      73-'
                      , Wo
                            i .to
                                          f.tf
                                                                                               ±
                                       /.&P
                                                     1^0
                                     JL±.
±
                                                      . f
       //.'y-
L14.
JtHf
                                                            t.o
                                           a./*
                                                            JLSLj-
                          i   .;*
                                            .39-
                          !  i.io
                                                     &./*>
                                                                     SSL
        'H.i7
                                                      . 10
                                                         S'*-
                                                                      9*-
                             .92,
                                            J4-.
       rt-n    iya/f.  LQ
                                       i
-------
Point
Clock
Time
 Dry Gas
Meter, CF
 Pi tot
in.  H£0
  Ap
Orifice  AH
   in hUO
                                            Desired
         Actual
                                                             Dry Gas Temp.
Inlet !  Outlet
 Pump
Vacuum
In. Hg
Gauge
                                                                                       Box
                                                                                       Tercp.
                                                Impinger
                                                 Temp
                                                   °r
Cf.^^1.
JcuvK
Press
in. Ho
Stack
Ten-p
 °F
                      32.30
         3-fto
                                                       a.
                                                                //£•
                          jeo
                                  f , tfO
              13
a. 3s'
                          96
                                                                    \
Comments:

.'OP-37'( 12/67)

-------
        Part 10, p..4 of 8
     Plant
                                             PARTIC%ATE FIELD DATA


                                        VERY IMPORTANT - FILL  IN-ALL 'BLANKS

                                        Read and record at the start of each
                                        test point or, if single point       577^K *?r
                                        sampling, read and record every S      _ 3ti"
                                        minutes.                   .           ~~
     Run No.

     Location

     Dste
                                        SCT.ple Box No.

                                        Meter Box No.

                                        Probe Length
                                                                            Ambient Temp °F_

                                                                            Bar. Prejss. "Hg
                                                                            Assumed Moisture %    *^-
Oparator
     Point
                                             Probe Heater Setting
                                                                            Heater Box Setting, °

                                                                            Probe Ti'p Dia., In.
          Clock
         JlKS
                Dry Gas
              Meter, CF
 Pi tot
in.  K20
  AP
                                                Orifice
                                                   in H
                                                             . Dry Gas Tenip.
Desired  1  Actual  i Inlet  I Outlet
Vacuum
In. Hg
Gouge
Box
Temp.
 °F
                                                                                       Impinger
°F
Stcck
Press
in. h'g j
               Stack
 •XJ
                                                                                   _2_
                                                                                   JL
         -2-L
                                                                          TT
                                    ),
                                                                      90
        ot' 3.>"  ly?V< 37
                                                                           90
               : 30  l//?a .  ao.   |  I.LO
      CT  7
                                                  £11 oo
                                                                                              v/
                                                             68:
                                                                     ±2.
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                                                J-a-
            * t> :t
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                                                 7
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            //;
                                                                                          NJX

-------
   Part 10, p.  4 of 8
Plant
                        Vft .
                                              PARTICIPATE FIELD  DATA
                                        VERY IMPORTANT - FILL  IN.ALL BLANKS
                                        Read and record at the start of each
                                        test point or, if single  point
                                        sampling, read and record every 5
                                        minutes.
Run No.
Location
Date
                                         Sample Box No.
                                         Meter Box No. _
                                         Probe Length
J
Ambient Temp °F_
Bar. Press. "Hg
Oparator
                                         Probe Heater Setting
                      Assumed Moisture %_
                      Heater Box Setting,
                      Probe Tip Dia., In.
Point
, SfA^^
tr~— |
2-
3
1 u
<£
4
1
Clock
Tin:-
)i; i "
/ / ; / r
l) ! * o
1 1 : a*
ir, 10
V
Dry Gas
Meter, CF

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T^^t 11
S"£) , J o
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Pi tot
in. H20
AP

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H .%0
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1 1 S~o
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i








Orifice AH
in H^O
Desired

% ,90
•3, fo
3. 14 o
2 >fo
3 iSo
/. *? o
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1
3.9 a
3»T"0
3. MO
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Dry Gas Temp.
op
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Outlet
1
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lot.
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Vacuum
In. Hg
Gauge

•7
J?
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^
/ ^
9
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Temp.
°F
n? . jT O






Impinger
Temp
°F .
do
/

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/

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1
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Press
in. Hg

• -i c*.

















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Te-p
°F
-j)c,°
f
i
i
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h





;

V





I


-------
        10, p.  4 of 8
   Run No.

   Location

   D£te
              -7
                                             PARTICIPATE FIELD DATA

                                       VERY IMPORTANT-- FJLLJN-ALL^ BLANKS

                                       Read and record at the start of each
                                       test point or,  if single point
                                       sampling, read  and record every 5
                                       minutes.
                      Sample Box  No.

                      Meter Box No. _

                      Probe Length
                                                                                Ambient Temp  °F

                                                                                Bar.  Press. "Hg
                                                                                Assumed Moisture %   *J
                                                      H
Cparator
                                           Probe Heater Sotting
                            Heater Box Setting, °F

                            Probe Tip Dia., In. ^
          Clock
i
N
                       Dry Gas
                      Keter,  Cf
,- » I
             Pi tot
            in.  H20
              AP
                                         Orifice  AH
                                            in  HoO
         Dry  Gas Temp.
              or-
               r
                                          Desired
Actual  i  Inlet
                                                                  Outlet
                                          t. <
                                                                         /r
 Pu^ip
Vacuum
In. Hg
Gouge
Box
Tenp.
                                                                                           Ir.pinger
                                                                           Lff
 S*- -.-i,
 tuCK
Press
in. Hg
                                                                                                    l-lflt
Stack
Ten-.p
 °F
          : a
Sjt-LSL
              M
                                              t >
                                                     i •
                                                     ;.?/
       \in:i/t
                               ) . (**
                                 ,	ii.
                                                                                 So
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                                  I, *o
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                                                             2UL.
                 Lift 3?
                                                                 my
                                                            /D
                                          1.34
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    A_UiC_U£LJ
                                          h	/_
                                                           JJ_
                              1,00
                                             1.70
                                                   /*/
                                                                           H.
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-------
                                                                                                                   TW, :















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in Ho
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if, C 0
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o
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°F
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Terr.p.
°F

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Press
in. Hn
-•iri.









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Coinnjents:
NCAP-37'(12/67)

-------
Part 10, p.  4 of 8
                                           PARTICULATE FIELD DATA
                                     VERY IMPORTANT - FILL IN.ALL BLANKS

Plant AfW
Run No.
Alf£^ '\
Location iSo-a^^t 7^\l\&**+1
t-
K
'
• i
i
Date
Oparato
Point
•*£f/9/







Read and record at the start of each
test point or, if single point
sampling, read and record every 5
minutes.
Sample Box No. (~~E ~"~*~~
Meter Box No. fi^Z - ^
' *7 fa Probe Length ,£>"* '
Ak J L
» 1 DofAJC.

Clock
Itae
•#Wff*
f ?-7
?..'/ ^>
Dry Gas
Meter, CF

/ / o .^7
2-// . ^/ Z-
x^A io * -73, ¥V*5
1
1





r^




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I

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1

Probe Heater Setting
Orifice AH
in H-,0
Desired

x\ q


/I
///v-ftj' •
'


60

Dry Gas Temp.
op
Actual Inlet

^, ^


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,




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Ambient Te
Bar. Press
Assumed Ko
Heater Box
Probe Tip
Pump
Vacuum
In. Hg
Gauge

^-
-------
   Part 10, p.  4
Plant
                                              PARTICULATE FIELD DATA
                                        VERY IMPORTANT - FILL IN.ALL .BLANKS
                                        Read and record at the start of each
                                        test point or, if single point
                                        sampling, read and record  every 5
                                        minutes.
          Box No.
-7-Meter Box No. _
         Length
                                                          ^ T~
                                                          O  1 ^—
Ambient Temp "F_
Bar. Press. "Kg
Oparator
   Probe Haater Setting
Assumed Moisture %_
Ttester Box Setting,
Probe Tip Oia., In._
                                                                                                      °F

-------
   Part 10,  p.  4 of 8
                                              PARTICIPATE FIELD DATA
Plant
                                        VERY IMPORTANT - FILL IN. ALL- BLANKS

                                        Read and record at the start of each
                                        test point or, if single point
                                        sampling, read and record every, 5
                                        minutes.
Ambient Temp *F

Bar. Press. "Hg
                                         Sample Box No.

                                         Meter Box No.

                                         Prcbs Length
Assumed Moisture 2
Heater Box Setting, °F

Probe Tip Dia.. In.
                                         Probe Heater Setting

-------
f    Part 10, p. 4 of 8
                                                 PARTICULATE FIELD DATA
                                           VERY IMPORTANT - FILL IN.ALL BLANKS

                                           Read and record at the start of each
                                           test point or, if single point
                                           sampling, read and record every 5
                                           minutes.

-------
   PartilO, p. 4 of 8
                                              PARTICULATE FIELD DATA
Plant
                                        VERY  IMPORTANT - FILLJN.ALL^ BLANKS

                                        Read  and record at the start of each
                                        test  point or, if single point
                                        sampling, read and record every 5
                                        minutes.                    .
Run No.
Sample Box.No. _

Meter Box No. _/*C T ~

Probe Length
                                         Ambient Temp °F     /

                                         Bar. Press. "Hg   'Z-fr.
                                                                                  Assumed Moisture 2
Operator
Probe Heater Setting
Hecter Box Setting, °F

Probe Tip Pi a. .In.

-------
,   Part 10, p. 4 of 8
                                              PARTICULATE FIELD DATA
Plant
Run No.

Locati on

Date
                                        VERY IMPORTANT - FILL IN.ALL  BLANKS

                                        Read and record at the start  of each
                                        test point or, if single point
                                        sampling, read and record every 5
                                        minutes.
                                         Senipls Box No.

                                         Meter Box No.

                                         Probe Length
                                                               Ambient Temp °F_

                                                               Bar. Press. "Hg
                                     &X^_
                                                   Assumed Moisture %
Opsrator
                                         Probe Heater Setting
                                                               Heater Box Setting, °F

                                                               Probe Tip Dia., In._
Point
          Clock
          Ti8-.a
 Dry Gas
Keter, CF
 Pi tot
in.  H20
  AP
                                             Orifice  AH
                                                in
Dry Gas Temp.
     Op
 Pump
Vacuum
In. Hg
Gauge
Box
Tercp.
 °F
Impinger
  Temp
                                  °F
Stcck
Press
in. Hg
Stack
Tersp
 op

-------
   Part 10, p. 4 of 8
                                               PARTICULATE  FIELD DATA
Plant
                                         VERY  IMPORTANT  -  FILL JN..ALL, BLANKS

                                         Read  and  record at  the start of each
                                         test  point  or,  if single point
                                         sampling, read  and  record every 5
                                         minutes.
                      Sample Box No. 	

                      Meter Box No.     '

                      Probe Length         /£>
                                                    Ambient Temp

                                                    Bar.  Press.  '
Operator
                      Prc.be Kaater Sotting
                                                    Assumed  Moisture %_

                                                    Heater Box  Setting,

                                                    Probe Tip Dia.,  In._
                                                                                                         O
Point
  7PT
          Clock
          Tlise
 Dry Gas
Keter, CF
 Pi tot
in. H20
   AP
Orifice  AH
   in H^O
Desired  " Actual
                                                               Dry Gas Temp.
                  inlet  1 Outlet
 Pusn?
Vacuum
In. Hg
Gouge
Box
Terr.p.
 °F
Ircpinger
  TsT.p
   °F
Stack
Press
in. Hg
StaCk
Ten:p
 °F

-------
   Part 10, p.  4 of 8
                                              PARTICULATE FIELD DATA
Plant
                                        VERY IMPORTANT  -  FILL IN.ALL BLANKS
                                        Read and record at the start of each
                                        test point or,  if single-point
                                        sampling, read  and recoro*"every 5
                                        minutes.
Sample Box No.
Meter Box No.
Probe Length
        Temp °F_
Bar. Press. "Hg_
                                                            Jo
                                                                                 Assumed Moisture %
                                                         L
Operator
Probe Heater Setting
Heater Box Setting, °F
Probe Tip Dia., In.
                                                                                                                      'it

-------
Part 10, p.  4 of-8
                                           PARTICIPATE FIELD DATA
                                     VERY  IMPORTANT - FILL IN.ALL BLANKS
                                     Read and record at the start of e
                                     test point or, if single point
                                     sampling, read and.record every 5
                                     minutes.
Ambient Temp °f_
Bar. Press. "Hg
                                             Box No.
                                      Meter Box No. •
                                      Probe Length
Assumed Moisture %
Heater Box Setting, °F
Probe Tip Dia., In.
                                      Probe Heater Setting

-------
      Part 10, p. 4 of 8
   Plant
                                                             FIELD DATA
                      VERY  IMPORTANT - FILL IN.ALL .BLANKS

                      Read  and record at the start of each
                      test  point or, if single po.int
                      sampling, read and record every 5
                      minutes.                    .

                                                   V'
                                                   :Box fio.

                                            Heter Box No. -_

                                            Probe Length
                                                                         Ambient Te^ip °F

                                                                         BJr.  Press.  "K,
                                                                         Assumed  Moisture %
   Oparator
                                Probe Heater Setting
                                                               Heater Box Setting;

                                                               Probe Tip Oia., In._
c
   Point
"cio'ck
Titf*
 Dry Gas
Meter, CF
 Pi tot
in.  H20
  AP
                                                Orifice  AH
                                                   in  H^O
Dry Gas Temp.
     °F
 Pump
Vacuum
In. Kg.
Gouge
Box
Temp.
 °F
Impinger
  TCTP
                                                                                              Stcck
                                                                                             Stack *

-------
   Par*; 10, p. 4 of 8
Plant
Run No.

Location

Date.
                              ^jC
                           PARTICIPATE FIELD DATA •*%:


                     VERY  IMPORTANT - FILL IN-.ALL_ BLANKS

                     Read  and record at the start of each
                     test  point or, if single point
                     sampling, read and record every 5
                     minutes.
"-3 Sample Box No.     t~

    Meter Box No.      *f

    Probs Length	
                                                                Ambient Temp °F_

                                                                Bar.  Press.  "Hg
                                                              )0
Operator
                      Probe Heater Setting
    Assumed Moisture %_

    Hester Box Setting,

    Probe Tip DiaV, In._
                                                                                    °
          Clock
Point     Tin:?
 Dry Gas
Meter, CF
                                Pi tot
                               in.
        Orifice  AH
           in HoO
                                                               Dry Gas Temp.
                                           Desired
Actual  i Inlet  I Outlet
 Pump
Vacuum
In. Hg
Gauge
Box
Terr.p.
 °F
                                        Irr.pinger
                                          Tsxp
                                                           . °F
Stack
Press
in. Hg
                                                                                             Stck
                                                                                                                 ep

-------
          , ,.p. 4 Of $-_.;.-
                                    PARTICIPATE FIELD DATA
Plant
^C,
                                       VERY  IMPORTANT - FJLL_IN .ALL_ BLANKS

                                       Read  and record at the  start of each
                                       test  point or, if single point
                                       sampling,, read and record every 5,  "
                                       minutes.-
                               Sample Box No.

                               Keter Box tNo.

                               Probe Length
    Ambient Temp °F_

    Bar.  Press. "Hg
                                                                               Assumed Moisture %     O
                               Probe Heater Setting
                                                                               Heater Box  Setting, °F

                                                                               Probe Tip Dia.,  In.
                                           Orifice AH
                                              in H^O
Desired   " Actual   Inlet I  Outlet
                                                    Dry Gas  Temp.
 Pump
Vacuum
In. Hg
Gauge
Box
Tomp.
 °F
                                                 Impinger
                                                   Temp
                                                                                             °F
Stcck
Press
StaCk
Tenip
                                                                                                    °F
                                                        ^\?i
                                                     -
                                                    e'y
                                                                             "-
                                                                   '//  b
                                          .  ?.^
                                                                    ll 0
                                                                    lib
                                                                            7-0

-------
filter       /— /7- 7
•Run number:   ft B P~ f
Operator: _
Sanple box number:
                          c
                               PARTICULATE CLEANUP SHEET
                                            Plant:
                                                           •1
           Location of sample port:
           Barometric pressure:	2
           Ambient temperature:	-j_
liipinger
Volume after sampling
Impinger p^efilled withfrflp ml
Volume collected      — j/> ml
                                 Container No
                                 Extra No.
                     Ether-chloroform extraction
                       of implnger water _
                     Impinger water residue
                                                                                        «g
Impincjers and back half of
  filter, acetone wash:
Container No
Extra No.
                                                      Weight results.
                                                                                        mg
    probe and cyclone catch:
                                 Container
                                 Extra No.
                                                      Weight results
                                                       mg
Probe, cyclone, flask, and
  front half of filter,
  acetone wash:
Container No
Extra Mo.
                                                      Weight results
jng
           Filter Papers and Dry Filter Particulate
                        •   i / >f"                        —"'  -•' ' *"/'
  Filter number   CentaffiieV'hoif*''   Filter nunber  Container no.
                                                                   >v.;
                                                                  '•-'*/
                                                                 Filter particul "
                                                                   weight
                                 ^otdl."parti cul ate weight
Silica Gel
  Weight after test:
  Height before test:   iM
  Moisture weight collected:
  Container number:         1.
                                Moisture total
                                                                                        gm
Sample
Method determination:
                                               Analyze for:

-------
                               PARTICULATE CLEANUP SHEET
                                          Plant:
                                                                  ,  V f>
Run number:
Operator: ;..
Sample box number:
                                      _•   Location of sample port:
                                          Barometric pressure:
                                          Ambient temperature:	
Impinger
Volume after sampling
Impinger prefilled wi_
Volume collected      — .P. Oml
                        Container No
                        Extra  No.
                                                    Ether-chloroform extraction    ^
                                                    ~: of 1mP1n9er water - -/••*  "9
                                             Impinger water  residue
                                                                                     mg
Impingers and back half of
  filter, acetone wash:
                               Container
                               Extra No.
                                                      Weight results_
                                                                             _rog
Dry probe and cyclone catch:
                               Container No.
                               Extra No.
                                                      Weight results
                                                                              _mg
Probe, cyclone, flask, and
  front half of filter,
  acetone wash:
                                 Container No
                                 Extra Mo.
                                                    Weight results_
                                                                              _mg
           Filter Papers and Dry Filter Particulate
ntunbcr „  Contai/rer nor
  fcr ntuncr „
  V}itiLJtiZ--JL8£-~
/a;r/   ir e
                                \
                                \   .o.fiti
                                                  Container no.
                                       particulate weight
                                           7516/
                                                               Filter particulate
                                                                 weight     2>o8'ir\ mg
                                                                 t ftter    :
Silica Gel
  Weight after test^ ° °
  Weight before test:    /4V/
  Moisture weight collected:
  Container number:         1.
                           2.
                                          3.
                                                               Moisture total    II*1-  gm
Sample number:	
Method determination^
Comments;  '  ^,.
                                             Analyze for:
                                             D-22

-------
                               PARTICULATE CLEANUP SHEET
Date:
Run number:
Operator:
Sample box number:
                                            Plant:
                                            Location  of  sample port:
                                            Barometric pressure:__
                                            Ambient temperature:
Impinger
Volume after sampling  4.00 ml
Impinger prefilled with^ ml
Volume collected        o  ml
                                 Container No.
                                 Extra No.
          Ether-chloroform extraction   „_
          'of Impinger water        .>/
                                                       Impinger water residue
Impincjers and back half of
  filter, acetone wash:
                                 Container
                                 Extra No.
                                                      Weight  results,
                                            mg
Dry probe and cyclone catch:
                                 Container No.
                                 Extra No.
                                                       Weight  results
                                            J"9
Probe, cyclone, flask, and
  front half of filter,
  acetone wash:
                                 Container  No,
                                 Extra Mo.
          Weight results
           Filter Papers and Dry Filter Particulate     „
  Filter 4vumb€r   Container, no.    Filter number   Container no.
 • \     /      X .-..rjst-.i.J?l?:7^:>.'.  -|- •   ~ I                /•:. -,-:_ •?• .•••  .
                                                        1 '  ' 3     Filter particulate
                                                       - •/'? 2 '*> .     weight    3?7y»£   mg
                                       particulate weight
  f"~——  	-'    \
Silica Gel
  Weight after  test:          	
  Weight before test:    /A  f #?, 4
  Moisture weight collected:	
  Container number:          1.      2.
3.
                                                     4.
                                                                                         mg
                                                                  Moisture total   33. ^ gm
Sample number:_
Method determination:.
Comments;	   	
                                                Analyze for:
                                              D-23

-------
Date: _	
Run number:
Operator:
Sample box number:
                               PARTICIPATE CLEANUP SHEET
                                            plant:
                                            Location of sample port:
                                            Barometric pressure:_
                                            Ambient temperature:
Impinger H20
Volume after sampling
ml   Container No.
                                                     Ether-chloroform extraction
                                                       of impinger water
           Filter Papers and Dry Filter  Participate
 \F11ter number   Ce*4*tner-rro.     Filter  number  Container no.
                \   Q^±!'      |__	     '•
                                       particuTate weight
                                         rtlcula
                                         CPHfrP
                                                                                       mg
1III|J IIIVJCI ffCIIIICU Wl UI>f4>OIIII
Volume collected -c ml

Impintjers and back half of
filter, acetone wash:
Dry probe and cyclone catch:
Probe, cyclone, flask, and
front half of filter,
acetone wash:
CAtra iiu. _
Container No.^J
Extra No.

Container No._
Extra No.

Container No.^j
Extra Mo.
Impinger water residue SJit

&3
Weight results .2*7

V/eight results

Weight results 4e^«3
..
9 mg

mg

mg

mg

                                     Filter  particulate
                                      weigh t     W*]\v>Cf  mg
                                                        **  mg
Silica Gel
  Weight after test:
  Height before test:
  Moisture weight collected:
  Container number:         1.
                                     Moisture  total
                                   2.
                        4.
                                                                                       gm
Sample number:
Method determination:.
Comments;
                                              Analyze for:
                                            D-24

-------
  -ff
Date:    //S7/7Z.
                               PARTICULATE  CLEANUP SHEET
                                        •'   Plant:
Run number:
Operator: __
Sample box number:
                                            Location  of  sample port:
                                            Barometric pressure:	^
                                            Ambient temperature:
Impinger H20
Volume after sampling.
Impinger prefilled witlgfeaa  ml
Volume collected    —    /£ ml
                                 Container No.^ttlM   Ether-chloroform extraction
                                 Extra  No.              of  1mP1n9er water _
                                                      Impinger water residue     7.0
Impincjers and back half of
  filter, acetone wash:
                                 Container
                                 Extra  No.
                                                      Weight  results
                                                      jng
Dry probe and cyclone catch:
                                 Container  No.
                                 Extra  No.
                                                      Weight  results
                                                      jng
Probe, cyclone, flask, and
  front half of filter,
  acetone wash:
Container
Extra Mo.
                                                     Weight results_
//.v
jng
           Filter Papers and Dry Filter Participate
  Filter number
                 ~-f.f&
                                       JF number  Container no.
                                         ur  '•"
                             -  i
                                -Tota4-particu1ate weight
                                                                Filter particulate
                                                                  weight	  /£7   nig
                                                                                    	mg
Silica Gel
  Weight after test:          _
  Height before test:  - f  /9o.9
  Moisture weight collected:  _ __
  Container number:         1.      2.
                                                    4.
                                Moisture  total ^
                                                                                       gm
Sample number:	
Method determination:.
Comments:
                                              Analyze for:
                                             D-25

-------
           I
Date:
Run number;
Operator: j
PARTICIPATE CLEANUP SHEET
             Plant:
Sample box number:
                                           Location of  sample port:
                                           Barometric pressure:	
                                           Ambient temperature:	
Impinger
                        10 ml
Volume after sampling
Impinger prefilled
Volume collected       -TD  ml
Container No,
Extra No.
                       Ether-chloroform extraction
                       ~ of impinger water	O-O   mg
                                                      Impinger water residue
                                                        _mg
Impingers and back half of
  filter, acetone wash:
                                 Container  No
                                 Extra  No.
                                                     Weight results
                                                        _mg
Dry probe and cyclone catch:      Container  No._
                                 Extra  No.
                                                     Weight results
                                                        _mg
Probe, cyclone, flask, and
  front half of filter,
  acetone wash:
Container
Extra Mo.
                                                     Weight results
                                                        _mg
           Filt
  Filter number
                        'and Dry Filter Particulate
                             b.  .   F4Hcr number  Container no.
                                  •-/ , Ol £ f
                                                               - Filter particulate
                                                                  weight	
                                                                                       mg
                                 Tetat" parti cul ate weight
Silica Gel
  Weight after test:          _
  Weight before test:       r  nil
  Moisture weight collected:  __
  Container number:         1.       2.
                                                   4.
                                                                                       mg
                                  Moisture  total -
                                                                                       gni
Sample number:	
Method determination^
Comments;        	
                                              Analyze for:
                                           D-26

-------

Date: 	
Run number:
Operator:
                               PARTICULATE CLEANUP SHEET
                                         .-'   Plant:  //.
Sample box number: 	-•   \j    I
                                            Location of sample port:
                                            Barometric pressure:
                                            Ambient temperature :_i
Implnger H20
Volume after sampling
Implnger prefllled w1thVml
Volume collected     •""
-------
  Date:	
  Run number:
  Operator:
                                PARTICULATE CLEANUP SHEET
                                           Plant:
  Sample box  number:
                                           Location of sample port:
                                           Barometric pressure:
                                           Ambient temperature:
                                         Etr— /
  Impinger
  Volume  after  sampling
  Impinger prefilled
  Volume  collected
Container
Extra No.
                                                  -/ Ether-chloroform extraction
                                                     ~ of impinger water
                                                     Impinger water residue^
mg
                                                      mg
  Impingers  and back half of
  .  filter,  acetone wash:
                                 Container Ho
                                 Extra No.
                                                       Weight results
                                                      mg
  Dry probe  and cyclone catch:
                                 Container No.
                                 Extra No.
                                                       Weight results
                                                      mg
.
Probe, cyclone,
front half of
acetone wash:
flask, and
filter,
Filter Papers and Dry
Filter number Container^no.
tfLQd { fc~? ^IC,^"" ' I



1
1
i

Container \\o.UJ££~/
Extra Mo. Weight results )7» fa
•
Filter Particulate
Filter number Container no.


weight /&•*
ilotal -particulate weight PCfrf 5t*H
75"W *(&,*
mg

mg
mg
•*^
Silica Gel
  Weight after test:
  Weight before test:         /7% 4
  Moisture weight collected:
  Container number:         1
                                                                X4-
                                                                  MoisfuK total  -1763-
                                     2.
;  Sample number:_
                                              Analyze for:
                                                                               \
  Method determination:
  Comments;
                                               Z
                                          .  0-28
                                                                                    2.Z

-------
Date: 	
Run number:
Operator: _
                               PARTICIPATE CLEANUP  SHEET
                                            Plant;            /) /
Sample box number:
                                            Location of sample  port:
                                            Barometric pressure; e?
                                            Ambient temperature:

                                                                           /
Impinger
Volume after sampling "3Ok_ml
Impinger prefilled wi
Volume collected
                                 Container
                                 Extra No.
                                                  - ~l~ Ether-chloroform extraction
                                                      ":'of 1mP1n9er water
                                                      Impinger water residue
                                                                                       mg
Impincjers and back half of
  filter, acetone wash:
                                 Container No >X.fc7 ~Z_
                                 Extrfl No>    _   We1ght  resu1ts
                                                                              y 7,
                                                                                       mg
Dry probe and cyclone catch:
                                 Container No.
                                 Extra No.
                                                      V/eight results
                                                                                       mg
Probe, cyclone, flask, and
                                 Container No.
                                                             results
                                                                                 - 7
                                                                                       1
           Filter Papers and Dry Filter Particulate
  Filter number   Container* rfe.    -Pittermimrber  Container  no.
 OJ~fN  ^'c/
                                                                 Filter  particulate^
                                                                  weight	
                                 T^t^-particul/te weight
                                                                                       nig
Silica Gel
  Weight after test:          _
  Height before test:    <    /$'=>< 4
  Moisture weight collected:  _
  Container number:         1.      2.
                                                                Moisture  total ~d3»7 cmi
Sample number:
Method determination:
Comments ;
                                              Analyze  for:
7
                                             D-29

-------
                                PARTI GULATE CLEANUP SHEET
Date:
Run number:
Operator: ___
           ///?/??-.
Plant:
  Sample box number:
Location of sample port:
Barometric pressure:	
Ambient temperature:	__
  Impinger
  Volume after sampling  ___7___m1
  Impinger prefilled  wi th__4>_D_m1
  Volume collected     — 2— ml
                                 Container No
                                 Extra No.
Ether-chloroform extraction
'of Impinger water _
                                            mg
                                                      Impinger water residue
                                       ,0   mg
  Impincjers  and  back  half  of
    filter,  acetone wash:
                                 Container
                                 Extra No.
                                                       Weight results
                                            mq
  Dry probe and  cyclone  catch:
                                 Container No._
                                 Extra No.
                                                       Weight results
                                           jng
;  Probe,  cyclone,  flask,  and
j    front half of  filter,
j    acetone wash:
                                 Container No.oJC£'3
                                 Extra No.     	   Weight results
                                  fotat-T)articulate weight
                                           jng
             Filter P?P£rs  ^  Dry  Filter Particulate
    Filter number   Coinfliner''tfro.    Filter number  Container no.
                       SuT
                      u r\?£!	
                                                                  Filter particulate
                                                                    weight	/_f^7   «"g
Silica Gel
  Weight after test:         _
  Weight before test:       V77J
  Moisture weight collected: _  _
  Container number:         1.       2.
                                               
-------
                               PARTICULATE CLEANUP SHEET
Date:
       r /
Run number:
Operator:
              /7
Sample box number:
           Location  of sample  port:
           Barometric pressure:    ^ 9,
           Ambient temperature:^
Impinger H20
Volume after sampling  /'0%  ml
Impinger prefilled
Volume collected
Container No.fcXjt?-/  Ether-chloroform extraction
Extra No.            ~'of impinger water.	*£jng
                     Impinger water  residue
                                                                                      _mg
Impingers and back half of
  filter, acetone wash:
Container
Extra No.
                                                     Weight results_
                                                                                      mg
Dry probe and cyclone catch:
Container No._
Extra No.
                                                     Weight results_
                                                                                      _mg
Probe, cyclone, flask, and
  front half of filter,
  acetone wash:
                                Container
                                Extra Mo.
                     Vleight results
mg
           Filter Papers and Dry  FilterParticulate
  Filter number   Container no. XT liter nunrer  Container no.
                              o
                                      particulate
                                                               - Filter particulate. Q
                                                                  wei ght	/S'l
Silica Gel
  Weight after test:          	.__
  Weight before test:       /<£/./
  Moisture.v;eight collected:  	
  Container number:         1H 2.
             mi
                                           3.
                   4.
                                Moisture  total -6V*? gm
Sample number:	
Method determination^
Comments;
              Analyze for:
                                           D-31

-------
Date: 	
Run number:
Operator:
                               PARTICULATE CLEANUP SHEET
                                            Plant:
Sample box number:
     ~Jk.  Location of sample port:
           Barometric pressure:	
           Ambient temperature:
Implnger           ...         ^^
Volume after sampling  1&vmr   Container Noj£C&%_  Ether-chloroform extraction
Impinger prefilled withfe                           ~''of ™er water
Volume collected
                                                      Impinger water residue
                                                      _mg
Impingers and back half of
  filter, acetone wash:
                                 Container
                                 Extra No.
                                                      Weight results_
                                                      jug
Dry probe and cyclone catch:
                                 Container No.
                                 Extra  No.
                                                      Weight results_
                                                       mg
Probe, cyclone, flask, and
  front half of filter,
  acetone wash:
Container
Extra Ho.
                                                      Weight results
                                    nig
           Filter Papers \and f\Dry FilterPanticulate
                   A JdJiJ \J\ \r\     JW'P" bsi' /(fc/VV^
  Filter number   Cyf|6(Wep no.   xTillei1  nurteer  Container no.
     '               o ,  ii \ 1
                                                                - Filter particulate.
                                                                   weight      2~9'jf   mg
                                'Total -particulate weight
Silica Gel
  Weight after test:
  Weight before test:     f
  Moisture weight collected:
  Container number:         1.
                                    2.
           3.
4.
                                                                Jdpisture total «.
Sample number:	
Method determination^
Comments;
                                               Analyze for:.
                                           D-32

-------
Date: 	
Run number:
Operator: _
1
                               PARTICIPATE CLEANUP  SHEET
                                            Plant:
                               Location  of  sample  port:
                               Barometric pressure:	
Sample box number:
                               Ambient temperature:
                         y
Implnger
Volume after sampling
Implnger prefilled wi
Volume collected   ... -^H-  ml
                    Container No
                          No.
                                               K3
                                                      Ether-chloroform extraction
                                                        of 1mPin9er water -      *'7
                                                      Implnger  water  residue    ££*/
                                                                          mg
Impincjers and back half of
  filter, acetone wash:
                    Container
                    Extra No.
                                                      Weight  results
                                                                                       _mg
Ory probe and cyclone catch:
                    Container No. —7"
                    Extra No.
                                                 	   Weight  results
                                                                                       _mg
Probe, cyclone, flask, and
  front half of filter,
  acetone v;ash:
                                 Container N
                                 Extra f.'o.
                                         Weight  results
                                                                                         mg
           Filter Papers andjDry Filtcr.Particulatt
  Filter number   cUiWub.    jJrKp nMlSft'' Container no.
     O 1% ^       Q I
                                 Totol  particulate weiqht
                                                    Filter  particulate
                                                     we i ght	 Jf, y  mg
                                                                  •* •*  t*
                                                                       f  mg
1 Silica Gel
  , Weight  aftnr  test:
   Weight  before  test:    /*i%"
   Moisture weight collected:
   Container  number:         1.

 Sample number:	^__	
 Method determination:_	
 Comments;	
                                                                 Moisture  tot  1
                                    ?.
                               3.
                                                    4.
                                               Analy?o for
                                             D-33

-------
Date:
Run number:
Operator: _
PARTICULATE CLEANUP SHEET
             Plant:
Sample box number:    f-^T '~~
             Location of sample port:
             Barometric pressure:_
             Ambient temperature:
Impinger
Volume after sampling
  Container No,
                  Ether-chloroform  extraction
                    of impinger water         &y  nig
Aiiip i nyci y>i c i ii i cu i< i biF^^'w' mi
Volume collected *-^|,ml
Impingers and back half of
filter, acetone wash:
Dry probe and cyclone catch:
Probe, cyclone, flask, and
front half of filter,
acetone wash:
Filter Papers and Dry
Filter number Cort|juo>i» no.
V^^^xl
1
I
[.Alia I1U« ______
Container Mo.ft^C-
Extra No. 	
Container No. _______
Extra No. 	 	
Container No. __££_-
Extra Mo. 	
Filter .Parti oil ate
/ FilfcVl?urab(S:/vto


1
i • .
Impinger water residue 5^

Weight results /<£»'->

Weight results

Weight results 3/<» i

ntainer no.

weight £"• 1+*
^etal particulate weight JCf~F 37 */

£*^*9^I A

• mg

»
mg

mg

mg

mg
	 mg
Silica Gel
  Weight after test:
  Weight before test:  ; Y
  Moisture weight collected:
  Container number:
                                  Moisture total -A&3
2.
             3.
4.
Sample number:	
Method determination:
Comments;
                Analyze for:
                                           D-34

-------
*s*
\ ''•'••'".," PARTICULATE
/ ' * • ' •
Date: ///F/72—
/ * — •»
Run number: fj^e"c^ •
Operator:
Sample box number: G--L — /
I
CLEANUP SHEET
H~*=-
Plant: CSP
Location of sample
Barometric pressure
Ambient temperature
•••'•- ' • • ±1?3L ft '':'.- •'•'.
_^jy-.- 	 _..
/ ?^
~~3^
port: ££fc>-&g£^
^•^-cr
•
•
•

Impinger H£0
Volume after sampling
Impinger prefilled wit
Volume collected
                         Q ml
Container No..'
Extra No.
^•2_fther-chloroform extraction    ^
    "•'of impinger water	3-'  mg
                                                     Impinger water  residue
                                                      mg
Impingers and back  half of
  filter, acetone wash:
Container
Extra No.
                                                  ' 2-
                                                     Weight results_
                                                                                     _mg
Dry probe and cyclone  catch:
                                Container No._
                                Extra No.
                                                     Weight results
           Filter Papers  and Dry FiUgr. Paniculate
  Filter number   bonta-lner no. . ( Hifeei' nuMMr* Container no.
        yy
                             ::L'
    o, :Jj o <•{
                                                      mg

Probe, cyclone, flask, and
front half of filter,
acetone wash:
Container No .ft^6*:2^
Extra Mo. VJeight results
. 	 . _ . . .
>
/S3»fo mg

                                                              - Filter particulate
                                                                 weight _ & V
                                :Tetal particulate weight
                                                                                      mg
Silica Gel
  Weight after test:
  Weight before test:
  Moisture v/eight collected:
                                                                Moisture  total -
                                                      gm
Container number:
Sample number:
Method determination:
1. 	 2. 	 3. 	 4. 	
Analyze for: .

Comments: •
                                          D-35

-------
Date:
Run number:
Operator:
                               PARTICULATE CLEANUP SHEET
                                            Plant:
Sample box. number:
                                            Location of sample port:
                                            Barometric pressure:	
                                            Ambient temperature:	
                                                                                        •: J>
Impinger
                      tf If \               '   f\ i*~* *"  ^
Volume after sampling Sw / ml   Container Nonxte-- j Ether-chloroform extraction
Impinger prefilled with^^ml   Extra No.    	   '  of impinger water	
Volume collected       "~2.fr ml                        Impinger water residue	
Impingers and back half of
  filter, acetone v/ash:
                                 Container
                                 Extra No.
                                                      Weight results_
                                                                                       mg
                                            mg
Dry probe and cyclone catch:
                                 Container No._
                                 Extra No.
                                                      Weight results^
Probe, cycVone, flask, and
  front half of filter,
  acetone wash:
                                 Container No
                                 Extra Ho.
          Weii"; L results
                                            mg
mg
           Filter Pape
  Filter number
                                 Filter Participate
                                                  Container no.
                                                                 Filter particulate
                                                                   weight
                                                                                        mg
                                 I&ta^-particu]ate weight
Silica Gel
  Weight after test:
  Weight before test:     >  i
  Moisture weight collected:
  Container number:         1.
                                    2.
                                              J&3
3.
                                                                 Moisture total
Sample number:_	
Method determination^
Comments:
                                               Analyze for:
                                             D-36
                                                                                       -V

-------
    Part  10, p. 2 of 8
                               VELOCITY  TRAVERSE  FIELD DATA
          Date  /-/7-?2
'**
   - Calculation columns, not Field data
Con;ments:
NCAP-29 (12/67)
                                       D-37

-------
   Part  10, p. 2 of 8
                               VELOCITY TRAVERSE FIELD DATA
          Plant
          Test
          Location
          Date
          Operator
Clock
Time
I-/*












Point
* 4.
5f
1
4,
\
§.'•
1
-L
z
4
(,.
\
°t
10
C-
1
2.
I
i
1.0

AP, in. H20
Z ,o
>-i
i.l
^f $~
a.v
i-l
/.?
1..0
^..0
-L.O
^t,/
7..Z
7./J-
14
/.^
i I i
l,y
fc|

> - 2_
/..3

Stack
Temp., °F
^^5"



-








Stack
Pres. , In. Hg
// Q^^ |
	 -"fyy^
tf-&





•





AP x (T+460J*














^P x (T+^GO)*
31 rJ~
v^>/
Jilt- '
Kj 'f-f
&'t\
35.1.1
'
i?. 5: v
3? . S TVr ;
^?-r5 '
> y,y/
•*^-*s
?9.3»'
34 -too
v». r^
?T,-r^
1-2-^2^
.
• i
i,f.V-i_
3^.r5
35.^
s 5 f2-
l'^.**'
14-?^
-J5".t7_
1 IJ.C.T-
a^./o
3«.z-7
.
** /"-.I ~..l -4-.: ~~ ..^1 ..mn.. „«•*• Ci^^fl A-*+* \ / 	 1 1 -» £^^2* I*
Cori,ments:
NCAP-29 (12/67)
                                       D-38

-------
    Part  10,  p.  2 of 8
                               VELOCITY TRAVERSE FIELD DATA
          Plant
          Test
       Location
       Date    / ~ / 7
                         - 7  Z.
          Operator
Clock
Time
/7/5












Point
Av
-*
s




AP, 1n. H20
, 02.
-c^
.i^
.CZ
.*><*
,oZ.
,0/S'
.
• <>•?.&
.02.
.CI*
•0 i.
-£)•£-



Stack
Temp., °F
Z/o



-








Stack
Pres., In ily ^
•flf?S 7












=*P x (T+460J*














^P x (T+4GOr
3-^i
-j.t »
eJff
JM_ '
~t¥~
•sxc
'•<•! i
y.of '
?.<.*. ;
!
>i
>•
.» 1
4.01
*\fl
-II
i, 6»&
£/, a'? i
0,6.^
3.LL

\
r • • • i
•**
- Calculation columns, not Field data
                                                U

Comments:
NCAP-29 (12/67)
                                       D-39

-------
    Part 10,  p.  2 of 8
                               VELOCITY TRAVERSE  FIELD DATA
          Plant
          Test    / -
          Location  -/?

          Date       /
          Operator
     u
 Clock
 Time
    '
        Point
  Stack
Temp., °F
   Stack
Pres. ,
P x (T+^GOJ*
                                                                            •« A
x (T+46
                                                                              >./6
                          A
               2--V
               2.2.
                                                                              31 7*7*1^
   5'
                          /.S
   1
                                                                                          'i*
   - Calculation  columns,   ft Field data
•**
Consents:

NCAP-29 (12/67)

                                                 ""         '
                                            * . ^.r*?
                                           Jv •*;.:•:*•,
                                        D-40

-------
   Part 10, p. 2 of 8
                              VELOCITY TRAVERSE  FIELD DATA
         Test
 Location

 Date   /  •
                        -1
         Operator
 Clock
 Time
Point
  Stack
Temp., °F
   Stack
Pres. ,  In.  Hg
AP * (T+46nj
(T+4G(
x (T+4GOJ  j
               23
                    23  2,3
                    2Y
               21  t\  t.3
               /.     .
   - Calculation columns,  not  Field data
Comments:   <^

N'CAP-29 (12/67)
                                      0-41

-------
    Part 10, p. 2 of 8
                               VELOCITY TRAVERSE FIELD DATA
          Plant
          Test
•**
   - Calculation columns, not Field data
Consents:     •*&* A <,
NCAP-29 (12/67)
                                       D-42

-------
   Part 10, p. 2 of 8
                              VELOCITY TRAVERSE FIELD DATA
         Operator
 Clock
 Time
Point
Jl
  Stack
Temp., °F
   Stack
Pres.,  In.  Hg
&P x (T+460J
x (T+460}x;
                    ,?
                                                                        ,1 37,3
          Z
          S
         7
               l.Y *.
-------
   Part 10, p. 2 of 8
         Test
 Location

 Date
         Operator
                            VELOCITY TRAVERSE FIELD DATA
                         •
 Clock
 Time
Point
         Z-
  Stack
Temp.,  °F
   Stack
Pres, ,  In. Hg
                                          V1.3*
AP x  (T+46CVJi*
•'AP  x  (T+46C1)'
       /•s'
                                                                        1,1
                                                                       )/
                J+
•**
   - Calculation columns, not Field data
Comments:

NCAP-29 (12/67)
                                                       •A*
                                                                        /O^O
                                    0-44

-------
 10
o.
  x
    x
©,

©
               INDUCED AIR DATA
                  15
                  11
                  18
                         14
         COMPARTMENTS MEASURED
                   1.5'X 14'-
               Center  line
                  Full  Ope n —I
     \
      80% Open Mesh
                                          25
                                           24
                                    21
                                          20
X®,'''©;-*
                                          x
                                  ©
                                             U-1.5'X 21.5'
                                          x
                                  ©
©
                  1.5' X 14'
           MEASUREMENT POIN TS
                    D-45

-------
Induced Air Anemometer Readings,  *Ft.
          MEASUREMENT  POINT
COMPARTMENT
A 2
^
6
7
10

R11
14
15
18

**C20
21
24
oc
£0
























DATE
1/17/72
1/17/72
1/18/72
1/17/72
1/18/72

1/18/72
1/18/72
1/18/72
1/18/72

1/18/72
1/18/72
1/18/72
1 /1R/79
1 / 1 O/ / c.
























1
208
386
264
300
334

292
246
38
340

276




























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260
352
266
294
250

276
220
188
346

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314
108
184
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341

290
186
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470


























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182
172

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134
206
202

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/
L

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118
232
218
393
236

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420
340
190
336
216

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180
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133
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229
120
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340
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364
380
364
362
378

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178
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362























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                D-46

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-------
         APPENDIX E



STANDARD SAMPLING PROCEDURES

-------
        APPENDIX E-l



STANDARD SAMPLING PROCEDURES
              E-l

-------
15708
      PROPOSED RULE MAKING
Subparl  E—Standards  of  Perform-
   •  ante for Nitric Acid  Plants

S 466.50  Applicability and designation
    of affected facility.
  (a) The provisions of this subpart are
applicable to nitric acid plants.
  (b) For  purposes of J466.11(e), the
entire plant is the affected facility.

| 466.51  Definitions.
  As u.ed in this part, all terms not de-
fined herein shall have the meaning given
them in the Act:
  (a) "Nitric  acid  plant"  means any
facility producing weak nitric acid  by
either the pressure or atmospheric pres-
sure process.
  (b) "Weak  nitric acid"  means  acid
which is 50 to 70 percent in strength.

§ 466.52  Standard  for nitrogen  oxides.
  No person subject to the provisions of
this subpart shall cause or allow the dis-
charge Into the atmosphere of nitrogen
oxides  in the effluent which are:
  (a) In excess of 3 Ibs. per ton of acid
produced  (1.5  Kgm. per  metric ton),
maximum 2-hour, average, expressed as
NO.
  (b) A visible  ^emission  within  the
meaning of this part.

§ 466.53  Emission monitoring.
  (a) There shall  be Installed,  cali-
brated, maintained, and operated, in any
nitric acid plant subject to the provisions
of this subpart, an instrument for con-
tinuously   monitoring  and  recording
emissions of nitrogen oxides.
  (b) The Instrument installed and used.
pursuant  to this  section shall have a
confidence level of at least 95 percent and
be accurate within ±20 percent and shall
be  calibrated Jn  accordance with the
method(s)  prescribed  by the manufac-
turer (s) of such instrument; the instru-
ment shall  be calibrated at  least  once
per  year unless  the  manufacturer (s)
specifies or recommends  calibration at
shorter intervals, in  which  case  such
specifications or recommendations  shall
be followed.
  (c) The  owner or  operator  of any
nitric acid plant subject to the provisions
of this subpart shall maintain a file of all
measurements  required by  this subpart
and shall retain the record of any such
measurement for at least 1 year  follow-
ing the date of such measurement.

§ 466.54  Test methods and procedures.
   (a)  The provisions of this section are
applicable to performance tests for deter-
mining emissions of nitrogen oxides from
nitric acid plants.
   (b)  All performance tests shall be con-
ducted while  the  affected  facility  is
operating at or above the  acid product
rate for which such facility was designed.
   (c)  Test methods set forth in the ap-
pendix  to  this part  shall be used  as
follows:
   (1)  For each repetition the NO, con-
centration shall be determined by using
Method 7. The sampling location shall be
selected according to Method 1 and the
sampling point shall be  the centroid of
the  stack  or duct. .The sampling time
shall be 2  hours and four  samples shall
be taken during each 2-hour period.
  (2) The volumetric flow rate of the
total effluent shall be determined by us-
ing Method 2 and  traversing according
to Method 1. Gas analysis shall be per-
formed by Method  3, and moisture con-
tent shall be determined by Method 4.
  (d) Acid produced, expressed In tons
per hour of 100 percent weak nitric acid,
'shall be determined during each 2-hour
testing period by suitable flow meters and
shall be confirmed by a material balance
over the production system.
  (e) For  each repetition, nitrogen ox-
Ides  emissions, expressed  in  Ib./ton of
weak nitric acid, shall be determined by
dividing the emission rate in Ib./hr. by
the  acid produced. The emission rate
shall be determined by the equation, lb./
hr.=QxC,  where  Q=volumetric  flow
rate of the effluent in f t.'/nr. at standard
conditions, dry basis, as determined in
accordance  with   S 466.54 (d) (2),  and
C=NO, concentration in Ib./f t.', as deter-
mined in accordance with t 466.54(d) (1),
corrected  to  standard   conditions,  dry
basis.

Subpart  F—Standards  of   Perform-
     ance for Sulfuric Acid Plants
§ 466.60 Applicability  and designation
     of  affected facility.
  (a) The provisions of this subpart are
applicable to sulfur acid plants.
  (b) For purposes of § 466.11 (e) the en-
tire plant is the affected facility.
§ 466.61   Definitions.
  As used in this  part, all  terms not
defined  herein shall have the meaning
given them in the Act:
  (a) "Sulfuric acid plant" means any
facility  producing  sulfuric acid  by the
contact process by burning elemental sul-
fur,  alkylation  acid, hydrogen  sulflde,
organic sulfldes and mercaptans, or acid
sludge.
  (b) "Acid mist" means  sulfur acid mist,
as measured by test methods set forth
in this part.

§ 466.62  Standard for sulfur dioxide.
  No person subject to the provisions of
this subpart shall cause or allow the dis-
charge  into the atmosphere of sulfur di-
oxide in the effluent in  excess of 4 Ibs.
per  ton of acid produced  (2 kgm. per
metric ton), maximum 2-hour average.

§ 466.63  Standard for  acid  mist.
  No person subject to the provisions of
this subpart shall cause or allow the dis-
charge  into the atmosphere of acid mist
in the effluent which is:
  (a)  In excess of 0.15 lb. per ton of acid
produced (0.075 Kgm. per  metric  ton),
maximum 2-hour average,  expressed as
H,SO..
  (b)  A visible  emission within  the
meaning of this part.

§ 466.64  Emission monitoring.
  (a) There shall be Installed, calibrated,
maintained, and operated, in any x^f'.xric
acid  plant subject  to the provisions of
this subpart, an Instrument for continu-
ously monitoring  and recording emis-
sions of sulfur dioxide.
  (b) The Instrument installed and used
pursuant to this section shall have a con-
fidence level of at least 95 percent and be
accurate within ±20 percent end shall
be  calibrated in  accordance with  the
method (s)  prescribed  by  the manufac-
turer(s) of such instrument,  the instru-
ment shall be calibrated at least once per
year unless the manufacturer (s) speci-
fies or recommends calibration at shorter
intervals, in which case such specifica-
tions or recommendations shall be fol-
lowed.
  (c) The owner or operator  of any sul-
furic acid plant subject to the provisions
of this subpart shall maintain a file of
all  measurements  required by this sub-
part and shall  retain the record of any
such measurement for at least 1 year
following the date of such measurement.

§ 466.65  Test methods and  procedures.

  (a) The  provisions of this  section  are
applicable to performance tests for  de-
termining emissions of acid mist and sul-
fur dioxide from sulfuric acid plants.
  (b) All performance  tests shall be con-
ducted while the affected facility is op-
erating at or above the acid  production
rate for which such facility was designed.
   (c)  Test methods set  forth  in the
appendix to this part shall  be used  as
follows:
  (1) For each repetition the acid mist
and SOi  concentrations shall be deter-
mined by using Method 8 and traversing
according to Method  1.  The sampling
time shall be 2  hours, and sampling vol-
ume shall be 40 ft.* corrected to standard
conditions.
  (2) The  volumetric flow rate  of  the
total effluent shall be determined by us-
ing Method 2 and traversing according
to Method  1. Gas  analysis shall be per-
formed by Method 3.  Moisture  content
can be considered to be zero.
  (d) Acid produced,  expressed in tons
per  hour of 100  percent  sulfuric  acid
shall be determined  during each 2-hour
testing period  by suitable flow meters
and shall be confirmed by  a material
balance over the production system.
  (e) For each repetition, acid mist and
sulfur dioxide  emissions,  expressed  in
Ib./ton of sulfuric acid shall be deter-
mined by dividing the emission rate in
Ib./hr. by the acid produced. The emis-
sion rate shall be  determined  by  the
equation, lb./hr.=QxC, where Q=volu-
metric flow rate of the effluent in ft.'/hr.
at standard conditions, dry basis, as de-
termined in accordance with  8 466.65(d)
(2), and C=acid mist and SO, concen-
trations in Ib./ft." as determined in  ac-
cordance with  § 466.65(d)(l), corrected
to standard conditions, dry basis.
        APPENDIX—TEST METHODS
METHOD I	SAMPIJB  AND  VELOCITY TRAVERSES
         FOB STATIONARY SOURCES
  1. Principle and applicability.
  1.1  Principle.  A  sampling site  and  the
number of  traverse points  are selected to
aid In the  extraction of  a representative
sample.
  1.2  Applicability. This method should be
applied only when specified by the test pro-
cedures for  determining compliance  with
                               FEDEIAL IEGISTEH, VOL. 36,  NO.  15?—TUESDAY, AUGUST 17, 1971


                                                              E-2

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m
 i
          New  Source Performance  Standards. This
          method  la not  Intended  to apply to gas
          streams other than those emitted directly to
          the atmosphere  without further processing.
           2. Procedure.
           2.1  Selection of a sampling site and mini-
          mum number of traverse points.
           2.1.1  Select a sampling site that Is at
          least  eight stack or  duct  diameters  down-
          stream and two diameters upstream from
          any flow disturbance  such  as a bend, expan-
          sion,  contraction, or risible  flame.  For  a
          rectangular cross section,  determine an
          equivalent diameter  from  the  following
          equation:
         equivalent diameter=2|
                      "(length) (width) ~1
                        length-r-width J

                           equation 1-1

  2.1.2 When the above sampling site cri-
teria can be met, the minimum number  of
traverse points Is twelve (12).
  2.1 S  Borne sampling situations render the
above  sampling  site  criteria Impractical.
When this is the ease, choose a convenient
sampling  location and  use  Figure  1-1  to
determine the minimum number of traverse
points.
  2.1.4  To use Figure l-i first measure the
distance from the chosen sampling location
to the  nearest upstream and downstream
disturbances. Determine the corresponding
number of traverse points for each distance
from Figure 1-1. Select the higher of the two
numbers of traverse points, or a greater value,
such that for circular stacks the  number to
a multiple of four, and for rectangular stacks
the number follows the criteria  of section
2.2.2.
  2.2 Cross sectional layout and location of
traverse points.
  2.2.1   For circular stacks locate the traverse
points on two perpendicular diameters ac-
cording  to Figure 1-2 and Table 1-1.
                                      NUMBER OF DUCT DIAMETERS UPSTREAM'
                                              (DISTANCE A)
                     •FROM POINT OF ANY TYPE OF
                      DISTURBANCE (BEND. EXPANSION. CONTRACTION, ETC.)
                                                                                               Figure 1-2.  Cross section of circular stack showing location of
                                                                                               traverse points on perpendicular diameters.

0
	
o
•
o


0
......
o
	
o •
1

o

o
	 —
o


o

o •
	
a

                                                                                                                                                                               5
                                                                                                                                                                               5
                                                                                                                                                                               i
                                                                                   Figure 1-3.  Cross section of rectangular stack divided  Into 12 equal
                                                                                   areas, with traverse points at centroid of each area.
                                    NUtSER OF DUCTDIAMETERS DOWNSTREAM*
                                               (DISTANCE B)
                                 Figure 1-1. Minimum number or traverra t*>lnli.
                                                            FEDERAL REGISTER, VOL 36, NO. 159—TUESDAY, AUGUST 17, 1971
                                                                                                                                                                     cn
                                                                                                                                                                     -4
                                                                                                                                                                     s

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              Table 1-1. Location of traverse points in circular stacks
             (Percent of stack diameter from inside wall to traverse point)
Traversa
point
number
on a
diameter
1
2
3
4
5
6
7
8
• 9. '
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
Number of
6 8 10
4.4 3.3 2.5
14.7 10.5 8.2
29.5 19.4 14.6
70.5 32.3 22.6
85.3 67.7 34.2
95.6 80.6 65.8
89.5 77.4
96.7 85.4
91.8
97.5











.

.
12
2.1
6.7
11.8
17.7
25.0
35.5
64.5
75.0
82.3
88.2
93.3
97.9












traverse
14
1.8
5.7
9.9
14.6
20.1
26.9
36.6
63.4
73.1
79.9
85.4
90.1
94.3
98.2










points on a diameter
16
1.6
4.9
8.5
12.5
16.9
22.0
28.3
37.5
62.5
71.7
78.0
83.1
87.5
91.5
95.1
98.4








18
1.4
4.4
7.5
10.9
14.6
18.8
23.6
29.6
38.2
61.8
70.4
76.4
81.2
85.4
89.1
92.5
95.6
98.6






20
1.3
3.9
6.7
9.7
12.9
16.5
20.4
25.0
30.6
38.8
61.2
69.4
75.0
79.6
83.5
87.1
90.3
93.3
96.1
98.7




22
1.1
3.5
6.0
8.7
11.6
14.6
18.0
21.8
26.1
31.5
39.3
60.7
68.5
73.9
78.2
82.0
85.4
88.4
91.3
94.0
96.5
98.9


24
1.1
3.2
5.5
7.9
10.5
13.2
16.1
19.4
23.0
27.2
32.3
39.8
60.2
C7.7
72.8
77.0
80.6
83.9
86.8
89.5
92.1
94.5
96.8
98.9
  9.2.2.  Tar rectangular  stacks  divide the
croo« section into as many equal rectangular
area* as traverse points, such that the ratio
of the length to the width of the elemental
area* la between one and two. Locate the tra-
verse points at the centrold  of each equal
area according  to Figure 1-3.
  3. References. Determining  Dust  Concen-
tration In a Gas Stream. ASME Performance
Test Code #27. New York. 1957.
  Devorkln, Howard,  et  al.  Air Pollution
Source Testing Manual. Air Pollution Con-
trol District. Los Angeles. November 1963.
  Methods for  Determination of Velocity,
Volume, Dust  and Mist Content of Gases.
Western Precipitation Division of Joy Manu-
facturing Co. Los Angeles. Bulletin \.'F-50.
1988.
                                           not  be used In the case of nondlrectlonal
                                           now.
                                             2. Apparatus.
                                             2.1  Pilot tube—Type 8 (Figure 3-1), or
                                           , equivalent.
                                             2.2  Differential pressure  gauge—Inclined
                                           manometer, or equivalent,  to measure ve-
                                           locity head to within 10 percent of the mini-
                                           mum valve.
                                             2.3.  Temperature gauge—Thermocouples,
                                           bimetallic  thermometers, liquid  filled  sys-
                                           tems, or equivalent, to measure stack tem-
                                           perature to within 1.5 percent of  the mini-
                                           mum absolute >tack temperature.
                                             2.4  Pressure gauge—Mercury-Oiled U-tube
                                           manometer, or equivalent, to measure stack
                                           pressure to within 0.1 In. Hg.
                                             2.5  Barometer—To  measure atmospheric
                                           pressure to within 0.1 In. Hg.
                                             2.8  Qas analyzer—To analyze gas compo-
                                           sition  for determining molecular weight.
                                             2.7  PI tot  tube—Standard type, to cali-
                                           brate Type S pltot tube.
                                             3.-Procedure.
                                             3.1  Set up the apparatus as shown In Fig-
                                           ure 2-1. Make sure all connections are tight
                                           and leak free. Measure the velocity head at
                                           t.he traverse points specified by Method 1.
                                            '3.2  Measure the temperature of the stack
                                           /as. If the total temperature variation with
                                           time Is less than 50* F., a point measurement
                                           will sufflce. -Otherwise, conduct a tempera-
                                           ture traverse.
                                           •  3.3  Measure the  static  pressure In  the
                                           •stack.
                                             3.4  Determine  the  stack gas molecular
                                           weight by gas analysis and appropriate cal-
                                           culation as Indicated In Method 3.
                                             en
                                             »->
                                             O
                                                                                                                            PIPE COUPLING
                                                                                                           TUBING ADAPTER
' Standard Method for Sampling Stacks lor
Paniculate Matter. In:  1971 Book of ASTM
Standards, Part 23. Philadelphia, 1971. ASTM
Designation D-2928-71.

METHOD  I	DETERMINATION  OF  STACK  OAS
       VELOCITY (TYPE 8 PITOT TUBE)

  1. Principle and applicability.
  1.1  Principle.  Stack  gas velocity  Is de-
termined  from the  gas density and from
measurement  of  the  velocity head using a-
Type  S  (Stauschelbe  or reverse  type) pltot
tube.
  1.2  Applicability. This method should be
applied  only when specified by the test pro-
cedures for  determining  compliance with
New Source Performance Standards. Being a
directional Instrument,  a pltot tube should
   Figure 2-1.  Pilot tube - manometer assembly.
  4. Calibration.
  4.1  To calibrate the pltot tube, measure
the velocity head at some point In a flowing
gas stream with both a Type S pltot tube and
a standard type pltot tube with known co-
efficient.  The velocity  of  the  flowing  gaa
stream should be within the normal working
range.
                                                                                                                                                                              I
                                                                                                                                                                              o
                                                                                                                                                                              x'

                                                                                                                                                                              O
                                                       FEDERAL REGISTER, VOL. 36, NO.  159—TUESDAY, AUGUST 17,  1971

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                                                 PROPOSED  RULE  MAKING
                                                                                             15711
  4.2  Calculate the  pltot  tub* coefficient
using Equation 3-1.
                      APt.it equation 2-1
where:
  C»,..,=Pltot tube  coefficient of Type 6
           pltot tube.
   C,.u=Pitot tube  coefficient at  standard
           type pltot tube (if unknown, use
           0.99).
   AP,(4=Veloclty head measured by stand-
           ard type pltot tube.
  AP,..,=Velocity bead measured by Type S
           pltot tube.
  4.3  Compare the coefficients of the Type S
pltot tube determined first with one leg and
              then the other pointed downstream. Use the
              pltot tub* only tf the two coefficients differ
              by no more than 0.01.
                •f. Calculation*.
                 Use Equation 2-9 to calculate the stack £>i»
              velocity.
                           V.=K.C
                                               equation 2-2
tthere:
  V.-
                    8 tack gas velocity, feet per second (f.p.B.).
                        JJJ- (,D.mole_.R)
  A,
  P.-
  M
                         >/> when these unite
                            are used.
                    Pltot tube coefficient, dlraensionless.
                    Absolut* etack gas temperature, °R.
                    Veloclty head 01 stack fas, In UiO (see fig. 2-2).
                    Absolute stack gas pressure, in lip.
                    Molecular weight of stack gas, Ib./lb.-mole.
     PUNT	
     DATE
     RUN N0._
     STACK DIAMETER, In..
     BAROMETRIC PRESSURE, In. Hg._
    STATIC PRESSURE IN STACK (P.). In. Hg.
                             9        —
    OPERATORS	;	.
                             SCHEMATIC OF STACK
                                CROSS SECTION
            Traverse point
Velocity head,
   in. H2O
                                  AVERAGE:
                                                              Stack Temperature
  Figure 2-2 shows a sample recording sheet
for velocity traverse data. Use the averages In
the last two columns of Figure 2-2 to deter-
mine the  average  stack  gas velocity from
Equation 3-2.
  6. References.
  Mark,  L. 8. Mechanical Engineers' Hand-
book. McGraw-Hill Book Co., Inc., New York,
1951.
  Perry, J. H. Chemical Engineers' Handbook.
McGraw-Hill Book Co.,  Inc., New York, 1960.
  Shlgehara, B. T., W. F. Todd.  and W. S.
Smith. Significance of Errors In Stack Sam-
pling Measurements. Paper presented at the
Annual Meeting of  the  Air Pollution  Control
Association, St. Louis, Mo., June  14-19, 1970.
  Standard Method for Sampling Stacks for
Paniculate Matter. In: 1971 Book of ASTM
standards, Part 23. Philadelphia,  1971. ASTM
Designation D-2928-71.
  Vennard, J. K. Elementary Fluid Mechanics.
John Wiley and Sons, Inc., New York, 1947.
METHOD  3	GAS ANALYSIS FOR CARBON  DIOXIDE.
   KXCXSS AM, AND DBT  MOLECULAR WEIGHT
  1. Principle ana applicability.
  1.1  Principle. An Integrated or grab gas
sample is  extracted from a  sampling point
and analyzed for Its components using an
Great analyzer.
  1.2  Applicability. This method should be
applied only when specified by the test pro-
cedures for determining compliance with New
Source Performance Standards.
  3. Apparatus.
  2.1  Orab sample (Figure 3-1).
  3.1.1   Probe—Stainless steel  or  Fyrex»
glass, equipped with a filter to remove par -
tlculate matter.
  3.1.2   Pump—One-way squeeze bulb, or
equivalent, to transport gas sample  to ana-
lyzer.
  2.2  Integrated sample (Figure 3-2).
  2.2.1   Probe—Stainless steel  or  Pyrex1
glass equipped with a  filter to remove par-
ticulate matter.
  2.2.2   Air-cooled  condenser—To  remove
any excess moisture.
  3.2.3   Needle valve—To adjust flow rate.
  2.2.4  Pump—Leak-free, diaphragm  type,
or equivalent, to pull gas.
  2.2.5   Bate meter—To measure a flow range
from 0 to 0.035 c.f jn.
  2.2.6   Flexible bag—Tedlar,1 or equivalent,
with a capacity of 2 to  3 cu.  ft. Leak  test the
bag in the laboratory  before using.
  2.2.7  Pltot tube—Type S, or equivalent.
attached to the probe  so that the sampling
flow rate can be regulated proportional to the
stack  gas velocity  when velocity is  varying
with time or a sample  traverse is conducted.
   2.3  Analysis.
   2.3.1  Orsat analyzer, or equivalent.
   3. Procedure.
   3.1  Grab sampling.
   3.1.1  Set up the equipment as shown  in
Figure 3-1. Place the probe in the stack at a
campling point and purge the sampling  line.
                         Figure 2-2.  Velocity traverse data.
                                                                                           1 Trade name.
       Wo. 159—Ft II	3
     FEDERAL REGISTER,  VOL. 36,  NO. 159—TUESDAY, AUGUST 17, 1971


                                 E-5

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15712
                                                 PROPOSED RULE MAKING
                   PROBE
                                            FLEXIBLE TUBING
    ER(G
FILTER (GLASS WOOL)
              5. References
TO ANALYZER  Altshuller, A. P., et al.  Storage  of  Oases
            and Vapors  In Plastic Bags. Int.  J.  Air &
            Water Pollution. 6:75-81.1963.
              Conner. William D., and J. S. Nader Air
            Sampling with Plastic Bags. Journal of the
            American Industrial  Hygiene  Association.
            25:291-297. May-June 1964.    ,
              Devorkln,  Howard,  et al. Air  Pollution
            Source Testing Manual. Air Pollution  Con-
            trol District. Los Angeles. November  1963.
                                                                                        METHOD 4-
                                            SQUEEZE BULB
                          Figure 3-1.  Grab-sampling train.
                                            RATE METER
                                   VALVE
          AIR-COOLED CONDENSER

     PROBE
                                                                  QUICK-DISCONNECT
 FILTER (GLASS WOOL)
                                   RIGID CONTAINER'
                 Figure 3-2. Integrated gas - sampling train.
   3.1.2  Draw sample into the analyzer.
   3.2  Integrated sampling.
   3.2.1  Evacuate the flexible bag. Set up the
 equipment as shown In Figure 3-2 with the
 bag disconnected.  Place the probe  In the
 stack  and purge the sampling line. Connect
 the bag, making sure  that all connections
 are tight and that there are no leaks.
   3.2.2  Sample at a rate proportional to the
 stack gas velocity.
   3.3  Analysis.
   3.3.1  Determine the CO2, 02, and CO con-
 centrations as soon as possible. Make as many
 passes as are necessary to give constant read-
 Ings.  If more than 10 passes are necessary,
 replace the absorbing solution.
   3.3.2  For Integrated sampling, repeat the
 analysis  until three consecutive runs vary
 no more than 0.2 percent by volume for e&h
 component being analyzed.
   4. Calculations.
   4.1  Carbon  dioxide.  Average  the  three
 consecutive runs and report  result  to the
 nearest 0.1 percent CO*.
   4.2  Excess air. Use  Equation 3-1 to cal-
 culate excess air, and average the runs. Re-
 port  the  result to the  nearest 0.1  ;  rcent
 excess air.
                                            where:
                                               %EA=Percent excess air.
                                               %O,=Percent oxygen by volume, dry
                                                       basis.
                                               %N.=Percent nitrogen by  volume, dry
                                                       basis.
                                               %CO=Percent carbon  monoxide by vol-
                                                       ume, dry basts.
                                               0.264= Ratio of oxygen to  nitrogen  In air
                                                       by volume.
                                               4.3  Dry molecular weight. Use Equation
                                            3-2  to calculate dry molecular weight and
                                            average  the runs. Report the result  to the
                                            nearest tenth.
         (%0.)-0.5(%CO)
  0.2C4(% N,)-(
                              equation 3-1
                                                         .      CO,) +0.32(% O.)
                                                        + 0.28(%N,+ %CO)
                                                                          Equation 3-J
                                             where:
                                                 Ma = Dry  molecular   weight,  lb./lb.-
                                                        mole.
                                               % CO, = Percent carbon dioxide by volume,
                                                        dry basis.
                                                %O,= Percent  oxygen  by  volume,  dry
                                                       . basis.
                                                %N.= Percent nitrogen by volume, dry
                                                        basis.
                                                0.44= Molecular weight of carbon dioxide
                                                        divided by 100.
                                                0.32= Molecular   weight   of  oxygen
                                                        divided by 100.
                                                0.28= Molecular  weight  of  nitrogen
                                                        divided by 100.
                                                                                                  -DETERMINATION  OF MOISTURE

                                                                                                       STACK CASES
               1. Principle and applicability.
               1.1  Principle. Moisture Is removed from
             the gas stream, condensed, and determined
             gravlmetrically.
            .  1.2  Applicability.  This method Is appli-
             cable  for the determination of moisture in
             stack  gas only when  specified by test proce-
             dures  for determining compliance with New
             Source Performance Standards. This method
             does not apply when liquid droplets are pres-
             ent In the gas stream.*
               Other methods  such as drying tubes, wet
             bulb-dry bulb  techniques, and volumetric
             condensation techniques may be used sub-
             ject to the approval of the Administrator.
               2. Apparatus.
               2.1  Probe—Stainless steel or Pyrex' glass
             sufficiently heated to prevent condensation
             and equipped  with a niter  to  remove par-
             tlculate matter.
               2.2  Impingers—Two   midget  implngers,
             each with 30 ml.  capacity, or equivalent.
               2.3  Ice   bath   container—To  condense
             moisture in Implngers.
               2.4  Silica gel tube—To protect pump and
             dry gas meter!
               2.5  Needle  valve—To regulate gas  flow
             r»te.
               2.6  Pump—Leak-free, di""*"-""" type, or '
             equivalent, to pull gas through train.
               2.7  Dry gas meter—To measure to within
             . percent of the total sample volume.
               2.8  Rotameter—To measure  a flow range
             from 0 to 0.1 c.f.m.
               2.9   Balance—Capable of measuring to the
             nearest 0.1 g.
               2.10 Barometer—Sufficient   to   read  to
             within 0.1 In. Hg.
               2.11  Ptfcttube—Type S, or equivalent, at-
             tached to  probe  so  that the sampling flow
             rate  can  be regulated proportional  to the
             stack gas  velocity when velocity Is varying
             with time or a sample traverse is conducted.
               3. Procedure.
               3.1   Place about 5 ml. distilled  water  in
             each  Imptnger  and weigh the implnger and
             contents to the nearest  0.1 g. Assemble the
             apparatus  without the probe as shown In Pig-
             •ure 4-1. Leak check  by plugging the Inlet to
             the first Implnger and drawing a vacuum. In-
             sure  that flow through the dry gas meter is
             \\ess than  1 percent  of the sampling rate.
               3.2  Connect the  probe, and sample at  a
             constant rate of 0.075 c.f.m. or at a rate pro-
             portional to the stack gas velocity not to ex-
             ceed  0.075  c.f.m. Continue sampling until the
             dry gas meter registers 1 cu. ft. or until visible
             liquid droplets are carried over  from the first
             Impinger to the second.  Record temperature,
             pressure, and dry gas meter reading as re-
             quired by Figure 4-2.
               • 3.3  After collecting the sample, weigh the
             Impingers and their contents  again to the
             nearest 0.1 g.
                i Trade name.
                s If liquid droplets are present in the gas
              stream, assume the stream to be saturated,
              determine the average stack gas temperature
              (Method  1), and use a psychrometrle chart
              to obtain an approximation of the moisture
              percentage.
                                   FEDERAL REGISTER VOL. 36, NO.  159—TUESDAY, AUGUST 17, 1971

                                                                E-6

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  4. Calculation*.
  4.1  Volume of water collected.
                             eqaation 4-1
where:
  Vw,=Volume  of water vapor  collected
          (standard conditions), cu. ft.
      HEATED PI
FILTER'(GLASS WOOL)
                         PROPOSED RULE MAKING

                       Wt=Final  weight  of  implngers  and
                             contents, g.
                       Wi=Initial • weight  of Implngers  and
                             contents, g.
                        B=Ideal gas  constant, 31.83-ln. Hg—
                             cu. ft./lb. mole-* B.
                     T.u=Absolute  temperature at  standard
                             conditions, 630* B.
                     P. u=Pressure  at   standard   conditions,
                             39.92 In. Hg.
                      M»=Molecular  weight  of   water,   18
                             Ib./lb. mole.
                                                                         ROTAMETER
                                                                                                                         15713
                                                                   DRY GAS METER
           ICE BATH
           LOCATION.

           TEST

           DATE	
           OPERATOR.
 Figure 4-1.  Moisture-sampling train.

	 COMMENTS
           BAROMETRIC PRESSURE.
CLOCK TIME





GAS VOLUME THROUGH
METER, (Vm).
ft3




--
ROTAMETER SETTING,
tl'/min



-

METER TEMPERATURE,
"F





  4.2  Gas volume.
                                                                                       V.
       /1771   'it  \V-P.
       V   '   in. Hg/  T.
                                                                                                                    equation 4-2
where
   V.,

   V.

   P.

  P.,-



   Ti


  4.3
 =Dry gas volume through meter at
     standard conditions, cu. ft.
 =Dry gas volume measured by meter,
     cu. ft.
 =Barometric pressure at the dry gas
     meter, in. Hg.
,=Pressure  at   standard  conditions,
     29.92-ln. Hg.
 =Absolute  temperature at  standard
     conditions, 530° B.
 =Absolute   temperature  at  meter
     (•P.+460),'B.
 Moisture content.
                                                                                       B.0=
                                                                                               Y..
                                                                                            V.. + V..
                                                                              +B.
                                +<«•«*>
                          Figure 4-2. Field moisture determination.
                             equation 4-3
where:
   B». = Proportion  by  volume  of  water
          vapor In the gas stream,  dlmen-
          sionless.
   V.«=Volume of  water  vapor  collected
          (standard conditions), cu. ft.
   V.«=Dry  gas  volume  through  meter
          (standard conditions), cu. ft.
  B»n=i Approximate volumetric proportion
          of water vapor in the gas stream
          leaving the Impingers, 0.025.
  5. References.
  Air   Pollution    Engineering    Manual,
Danlelson, J. A.  (ed.).  U.S.  DHEW,  PHS,
National Center for Air Pollution  Control.
Cincinnati,   Ohio.   PHS   Publication  No.
999-Ap-40.1967.
  Devorkin,   Howard, et  al. Air Pollution
Source Testing Manual. Air Pollution  Con-
trol District. Lor Angeles, Calif.  November
1963.
  Methods for Determination  of  Velocity,
Volume,  Dust and  Mist  Content of Gases.
Western Precipitation Division of Joy Manu-
facturing Co.,  LOB  Angeles, Calif.  Bulletin
WP-50. 1968.
METHOD  B.	DETERMINATION OP PARTICULATE
     EMISSIONS FROM STATIONARY SOURCES
  1. Principle and applicability.
  1.1 Principle. Paniculate matter is with-
drawn Isokinetically from the source and its
weight is determined  gravlmetrlcally  after
removal of uncomblned water.
  1.2 Applicability. This method is applica-
ble  for  the determination  of particular
emissions from stationary sources only when
specified by  the test procedures for deter-
mining  compliance  with  New Source Per-
formance Standards.
  2. Apparatus.
  2.1 Sampling train. The design specifica-
tions of the paniculate sampling train used
by EPA  (Figure 5-1)  are described in APTD-
0581. Commercial  models of this train are
available.
  2.1.1  Nozzle—Stainless steel (316)  with
sharp, tapered leading edge.
  2.1.2  Probe—Pyrex ' glass with a heating
system capable of maintaining a gas tempera-
ture  of  260' P. at 'the exit end  during
sampling. When  temperature  or  length
limitations  are encountered,  316  stainless
steel, or equivalent, may be used, as approved
by the Administrator.
                                 FEDERAL REGISTER, VOL, 36, NO.  159—TUESDAY. AUGUST 17, 1971
                                                           E-7

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15714
     PROPOSED  RULE MAKING
  3.1.3  Pltot tube—Type  8. or equivalent.
attached  to probe  to monitor stack  gai
velocity.
  3.1.4  Filter  holder—Pyrex»  glass   with
heating system capable of maintaining any
temperature to a maximum of 225* F.
  3.1 £  Imptngere—Four  Implngers   con-
nected  In series with glass ball Joint fittings.
The Orat, third, and fourth Implngers are of
the Qreenburg-Smith design, modified by re-
placing the tip with a 14-Inch ID glass tube
extending to Vi-lnch from the bottom of the
flask. The second Implnger Is of the Green-
burg-Smlth design with the standard Up.
  2.1.8  Metering  system—Vacuum  -gauge,
leak-free  pump,  thermometers  capable of
measuring temperature  to within 6* F., dry
gas meter with 2 percent accuracy, and re-
lated equipment, or equivalent,  as required
to maintain an isokinetlc sampling rate and
to determine sample volume.
        PROBE
 REVERSE-TYPE
  PITOT TUBE
                             HEATED AREA  FILTER HOLDER   THERMOMETER   CHECK
                                                                  •I      ^.VALVE
                                        IMPINGERS            ICE BATH
                                               BY-PASS.VALVE
                                                                             VACUUM
                                                                               LINE
                                                                VACUUM
                                                                 GAUGE
                                                        MAIN VALVE
                          DRY TEST METER
 AIR-TIGHT
  PUMP
                           Figure 5-1. Paniculate-sampling train.
   2.1.T  Barometer—To measure atmospheric
  pressure to ±0.1 In. Hg.
   2.3  Sample recovery.
   3.3.1  Probe  brush—At  least as long  as
  probe.
   2.2.2  Glas» <»»8h bottles—Two.
   2.2.3  Glass sample storage containers.
   2.2.4  ursauated cylinder—250 mL
   2.3  Analysis.
   2.3.1  Ql «*• weighing dishes.
   2.3.2  'Desiccator.
   2.3.3  Analytical balance—To measure  to
  ±0.1 mg.
   2.3.4  Beakers—250 ml.
   •Trade name..
   2.3.6  Separatory  funnels—500  ml.  and
 1,000 ml.
   3.3.8 Trip balance—300 g. capacity,  to
 measure to ±0.05 g.
   2.3.7 Graduated cylinder—25 ml.
   3. Reagents.
   3.1  Sampling
   3.1.1 Filters—Glass fiber. MSA  1106 BH,
 or equivalent, numbered  for  Identification
 and preweighed.
   3.1.3 Silica gel—Indicating  type, 6 to 1«
 mesh, dried at 176* O. (360* F.) for 2 hours.
   •3.1.3 Water—Dfilonlzed. distilled.
   8.1.4 Crushed ice.
   8.2  Sample recovery
   3.2.1 Water—Deionlzed, distilled.
   3.2.2  Acetone—Reagent grade.
   3.3  Analysis
   3.3.1  Water—Delonized, distilled.
  3.3.2  Chloroform—Reagent grade.
  3.3.3  Ethyl ether—Reagent grade.
  3.3.4  Deslccant—Drlerite,1 indicating.
  4. Procedure.
  4.1  Sampling.
  4.1.1  After selecting the sampling site and
 the minimum number of sampling points,
 determine the stack pressure, temperature.
 moisture, and range of velocity head.
  4.1.2  Preparation  of  collection   train.
 Weigh  to  the nearest  gram approximately
 200 g. of silica  gel. Label a filter of proper
 diameter,  desiccate* for  at least 24  hours
 aud weigh to the nearest 0.5 nig. In a room
 where  the relative humidity  is  less than
 50 percent. Place 100 ml. of water In each of
 the first two impingers, leave the third Im-
 plnger  empty, and place  approximately  200
 g. of preweighed silica gel in the fourth Im-
 plnger. Save a portion  of the water for  use
 as a blank in the sample analysis. Set up the
 train without the probe as in Figure 6-1.
 Leak check the sampling train at the sam-
 pling site by plugging the inlet to the filter
 holder  and pulling a  15-ln. Hg vacuum.  A
," leakage rate not In excess of 0.02 c.f.m. at a
 vacuum of 15-ln. Hg Is  acceptable. Attach
 the probe and adjust the heater to provide a
 g&a temperature  of about  250*  F.  at  the
 probe outlet.  Turn on the filter heating sys-
 tem. Place crushed ice around the Impingers.
 Add more Ice during the run to keep the tem-
 perature  of  the gases  leaving the  last  Im-
 plnger at 70* F. or less.
   4.1.3   Partlculate train operation. For each
 run record the data required on the example
 sheet shown in Figure 5-2. Take  readings
 at each sampling point at least every 5 min-
 utes and when significant  changes  in stack
 conditions necessitate  additional  adjust-
 ments  in  flow rate. To begin sampling, po-
 sition the nozzle at the first traverse point
 with the tip  pointing  directly Into the gas
 stream. Immediately start the pump and ad-
 just the flow to isoklnetlc conditions. Main-
 tain Isokinetlc  sampling  throughout  the
 sampling  period.  Nomographs are available
 which  aid in the rapid adjustment of  the
 sampling  rate without other computations.
 APTD-0576 details the procedure for using
 ihese nomographs. Turn off the pump at the
 conclusion of each run and record the final
 readings. Remove the probe and nozzle from
 the stack and handle in accordance with the
 sample recovery process described In section
 4.2.
                                                                                          • Dry using Drierlte* at 70* ±10* F.
                                   KOEIAL REGISTEI, VOL. 36, NO.  159—TUESDAY, AUGUST 17, 1971


                                                                E-8

-------
                                                  PROPOSED RULE MAKING
                                                                               15715
          PLANT	

          LOCATION	

          OPERATOR	

          DATE	

          BUN NO.	

          SAMPLE BOX NQ._

          METER BOX N0._

          METER AHg	

          CFACTOR	
                                                   AMBIENT TEMPERATURE.

                                                   BAROMETRIC PRESSURED

                                                   ASSUMED MOISTURE, %_

                                                   HEATER BOX SETTING	

                                                   PROBE LENGTH, in.	

                                                   NOZZLE DIAMETER, in. _

                                                   PROBE HEATER SETTING.
      SCHEMATIC OF STACK CROSS SECTION
TRAVERSE POINT
NUMBER












TOTAL
SAMPLING
TIME
(«), mln.













AVERAGE
STATIC .
PRESSURE
(Ps). In. Hg.














STACK
TEMPERATURE
.








'





PRESSURE
DIFFERENTIAL
ACROSS
ORIFICE
METER
(AH),
In. H2O














GAS SAMPLE
VOLUME
IVm), ft3














GAS SAMPLE TEMPERATURE
AT DRV GAS METER
INLET
(TmjJ.'F












Avg.
OUTLET
ITn-out'-*11












Avg,
Av9.
SAMPLE BOX
TEMPERATURE,
»F














IMPINGER
TEMPERATURE,
"F






\







  4.2  Sample recovery. Exercise care in mov-
ing the collection train from the test site to
the sample recovery area to minimize the loss
of collected sample or the gain of extraneous
participate matter. Set aside portions of the
water and acetone used In the sample recov-
ery as blanks for analysis. Place the samples
in containers as follows:
  Container No.  1. Remove the filter from its
holder, place in  this container, and seal.
  Container No. 2. Place loose  paniculate
matter and acetone washings from all sam-
ple-exposed surfaces prior to the filter in this
container and seal. Use a razor blade, brush.
or rubber policeman to loosen adhering par-
ticles.
  Container No. 3.  Measure the volume of
water from the first three implngers  and
place the water In this container. Place water
                                                               Figure 5-2.  Participate field data.
rinsings of all  sample-exposed surfaces  be-
tween the filter and fourth impinger in this
container  prior to  sealing.
  Container No.  4. Transfer  the  silica  gel
from  the  fourth Impinger  to the original
container  and seal. Use a rubber policeman
as an aid in removing silica gel  from  the
impinger.
  Container No. 5. Thoroughly rinse all sam-
ple-exposed  surfaces between  the  filter and
fourth  Impinger with acetone,  place  the
washings In this  container,  and seal.
  4.3  Analysis. Record the data required on
the  example sheet shown  In  Figure 5-3.
Handle each sample container as follows:
  Container No. 1. Transfer the filter and any
loose  participate matter  from  the  sample
container to a tared glass weighing dish, dcs-
slcate, and dry to a constant weight. Report
results to the nearest 0.5 mg.
  Container  No. 2.  Transfer  the acetone
washings to a tared beaker and evaporate to
dryness at ambient temperature  and pres-
sure. Desslcate and dry to a constant weight.
Report results to the nearest 0.5 mg.
  Container No. 3. Extract organic particulate
from the Impinger solution with three 26 ml.
portions of chloroform.  Complete the  ex-
traction with three 25 ml. portions of ethyl
ether. Combine the ether and chloroform ex-
tracts, transfer to a tared beaker and evapo-
rate at 70* F. until  no solvent remains. Des-
sicate, dry to a constant weight, and report
the results to the nearest 0.5  mg.
  Container  No. 4.  Weigh the  spent  silica
gel and report to the nearest gram.
                                  FEDERAL REGISTER,  VOL.  36,  NO. 159—TUESDAY, AUGUST 17,  1971

                                                           E-9

-------
15716
PROPOSED  RULE MAKING
                             PIANT_

                             DATE	

                             BUNNO._
CONTAINER
NUMBER
1
2
3a"
3b*»
5
TOTAL
J - WEIGHT OF PARTICULATE COLLECTED,
mo
FINAL WEIGHT





Z^^^CL
TARE WEIGHT





^>=Denslty of water, l g./mi.
                                       MH,o=Molecular weight of water, 18 Ib./lb.
                                               mole.
                                          R= Ideal gas constant, 21.83 in Hg-cu.
                                               ft./lb. mole-°R.
                                         T,u==Absolute temperature  at standard
                                               conditions, 530° R.
                                         PtU= Absolute pressure at standard con-
                                               ditions, 29.92 in. Hg.

                                       6.1.4  Total gas volume.
                                         i
                                           equation 5-3

              where:
                V,.,,, =Total volume of gas sample (stand-
                        ard conditions) , cu. ft.
                V«i,,d=Volume  of gas through  dry gas
                        meter  (standard conditions), cu.
                        ft.
              '  Vwlttd
proved  by the Administrator to calibrate   »«,„,,= ¥»{ -rp—
the orifice meter, pilot tube,  dry  gas meter,
and probe heater.
  6. Calculations.
  6.1  Sample concentration  method.
  6.1.1  Average dry gas meter temperature.
See data sheet (Figure 6-2).
  6.1.2  Dry gas volume. Correct the sample
                                           volume measured by  the  dry  gas meter to
                                           standard conditions (70* F., 29.92 In. Hg)  by
                                           using Equation 5-1.
     mi
     17'71
                                                             /P   +^\
                                                           \(rt"'+13.6)
                                                           A   p.,-   /

                                                                       /P  0.AI
                                                            JR  Vv )(      ^
                                                           in.Hg^V-;\   P.,,
          A
       13.6 j


equation 5-1
                            equation 5-4

where:
    c'.=Concentratlon of partlculate matter
          In stack gas (Sample Concentra-
          tion Method) , gr./s.c.f.
    M.= Total amount of partlculate mat-
          ter collected, mg.
  V,.ul=Total volume of gas sample (stand-
          ard conditions) , cu. ft.
  6.2  Ratio of area method.
  6.2.1  Stack gas velocity. Collect the neces-
sary data as detailed in Method 2. Correct the
                                  HDiHAL REGISTER, VOL,  34, NO.  159—TUESDAY, AUGUST 17, 1971

                                                             E-10

-------
    stack  gas velocity  to  standard conditions
    (29.92 In. Hg, 530° R.) as follows:
Gi             ^*. Bta/1  \ * • f
CD        ^       «T>   \ /~\7 T> '
I        (17'71ra)(¥


1
                             equation 5-5
where:
  V.,,d=Stack gas velocity at standard con-
          ditions, ft./sec.
                                                Vi =Stack  gas  velocity  calculated by
                                                      Method a. Equation 2-2, ft./sec.
                                                P>=Absolute stack gas pressure. In. Hg.
                                              P.tti=Absolute pressure ait standard oon-
                                                      tlons. 29.92 In. Hg.
                                              T
-------
ASME PARTICULATE SAMPLING
     The ASME train consists of a stainless steel  filter holder containing
a preweighed alundum filter.  Its operation, briefly, is as follows:

     Sample gases are drawn through a stainless steel nozzle and filter
holder, placed within the stack, into a set of water filled Greenberg-
Smith impingers.  Isokinetic sampling rates are not determined during the
test but are precalculated from initial pitot and temperature readings.
Only the material collected by the alundum filter is normally considered
as particulate.  Only one ASME train was employed during this survey.

CARBON MONOXIDE SAMPLING
     Stack gas is drawn from the stack through a filter, into an MSA  Lira*
infrared analyzer.  This instrument is mated to a Brush* Chart-strip
recorder which reads out directly.  The unit is calibrated on-site with
a zero calibration gas (nitrogen) and a known span gas (252 ppm carbon
monoxide).

HIGH VOLUME AIR SAMPLING
     High volume air sampling was conducted using General Metal Works
Model 2000* high volume air samplers.  The method has become standard
through years of usage and there is no one single "standard".  The method
involves drawing air through an 8" x 10" glass fiber filter.  The gas flow
*Mention of a specific company or product does not constitute endorse-
 ment by EPA.
                                  E-12

-------
rate is measured at the beginning and end of each sample, using a calibrated
flow meter.  The average flow rate is used, in conjunction with the total
time sampled, to determine the sample volume.
                                   E-13

-------
                              APPENDIX E-2
                    CLEANUP AND ANALYTICAL PROCEDURES

ANALYSIS (HIGH VOLUME SAMPLES)
     The filters are handled in the same manner as are filters from the
EPA particulate train.
                                  E-14

-------
   APPENDIX F



LABORATORY REPORT

-------
SAMPLES
NO.
        LOCATION  and
          SAMPLE NO.
SAHPLE
WEIGHT
 TIT.
ALIQ.
MG it
ALIQ
-t-
     L
                                                                      0 ,0 /
   \±
                                                 12.82B9/
                                                          .33 if
    l
                            , n /
                                  0, // *f <•
                          0, $6 11-
                                                                       ,
                                                                      d.c
                                    .¥•< 63
  n
 Project No.
                        01
              Collection Date

              Analysis Date
                                                                           ^ I 7, .15 /
                                           F-l

-------
SAMPLES
   Is:
NO.
LOCATION  and
  SAMPLE HO.
SAMPLE
WEIGHT
 TIT.
ALIQ.
MS id
ALIQ

                                 /T5"
                                                                   , o s
   LL
                           7.--
    2.
                         0,6*1
                                                             0 /
     l
                          /SO
                                                                 o.oy
    i
        IAJ ^    -
                             .?/
\AJ t £
                                         o.o/rj
                                                                 0,
                                                          0,61
                                                                 0.05-5-1
                                                                 0-01
                                                                 0,04 3 7
              a -
                        8 ».'.V- / J
                          .t>l 3

                                                               1 6
                        ? O o ' "
                          '
 PC/--
                                        fattff
   it
                   .7277
                        0.011 1
                                                         0.0 I  I

                                                                 ft .00 J
    ft.
             l3 -3
                                                                  Q.otfff
 Project No.
                   ^ 
-------
SAMPLES
NO.
       LOCATION  and
         SAMPLE NO.
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APPENDIX G



 TEST LOGS

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                           TEST
  Date

1/15/72

1/16/72

1/17/72
1/18/72
1/19/72



1/20/72
1045-1735
P.M.
P.M.
1349-1800

1130-1800
1128-1601
A.M.
1500-1730
P.M.

0900-1145

1100-1410

1405-2000
1432-1855
P.M.
P.M.
1725-1735
         Acti vi ty

Arrived, located equipment.

Unpacked equipment,  placed equipment.

One set particulate  samples.
Baghouse inlets  velocity determination.
Began induced air measurements.
One set HiVol  samples.

One set particulate  samples.
One set HiVol  samples.
Completed induced air measurements.
Carbon monoxide  sampling.
Baghouse inlets  velocity determination.

Particulate sample on furnace exhaust
duct.
ASME test on furnace exhaust duct.
One set particulate  samples.
One set HiVol  samples.
B baghouse inlet velocity check.
Induced air spot checks.
Orsat samples  and analysis.
                              6-1

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  APPENDIX H



RELATED REPORTS

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     Related reports covering emissions  from reactive metals  furnaces,
under this same contract for the Environmental  Protection  Agency,  are
as follows:
Test Number    Survey Location

   FA-1     Foote Mineral Co.,
            Steubenville, Ohio

   FA-2     Union Carbide Corp.,
            Marietta, Ohio

   FA-3     AIRCO Alloys and
            Carbide, Niagara Falls,
            New York

   FA-4     AIRCO, Alloys and
            Carbide,
            Charleston, S.C.

   FA-5     Union Carbide Corp.,
            Alloy, W.Va.
   Emi ss i on
Control Device

    None


  Venturi
  Scrubber
  Baghouse

Electrostatic
Precipitator

  Baghouse
   Status

Issued August 1971
Issued October 1971
Revised December 1971
Issued November 1971
This report
                                    H-l

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         APPENDIX I



PROJECT PARTICIPANTS AND TITLES

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R. N. Allen, P.E., Project Manager
T. E. Eggleston, Industrial Hygienist,  Crew Leader
G. B. Patchell, Senior Technician
J. R. Avery, Technician
L. W. Baxley, Technician
W. A. Hernandez, Technician
R. H. Kilburne, Technician
J. R. McReynolds, Technician
                 1-1

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