&EPA
United States
Environmental Protection
Agency
Office of Research and
Development
Washington, DC 20460
EPA/600/R-99/020
February 1999
Gamma in Water
Performance
Evaluation Study
A Statistical Evaluation of
the November 6, 1998 Data
-------
Gamma in Water
Performance Evaluation Study
November 6, 1998
Environmental Protection Agency
National Exposure Research Laboratory
Environmental Sciences Division
Las Vegas, Nevada
-------
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
OFFICE OF RESEARCH AND DEVELOPMENT
NATIONAL EXPOSURE RESEARCH LABORATORY
ENVIRONMENTAL SCIENCES DIVISION-LAS VEGAS
P.O. BOX 93478
LAS VEQAS, NEVADA 89193-3478
(702/798-2100)
Dear Participant,
Enclosed are the results of the Environmental Sciences Division (ESD-LV)
Performance Evaluation Study for Gamma in Water; November 6, 1998.
The known value for each analysis was determined by gravimetric methods,
checked by chemical analyses performed by ESD-LV's Radiochemistry Laboratory,
and compared to the participating laboratories' grand average.
The expected precision, determined by the known value, was taken from
'Table 3. Laboratory Precision: One Standard Deviation Values and Control Limits
for Various Analyses", which is based on data accumulated over the years by the
Performance Evaluation Program, and can be found in the Environmental Radioactivity
Performance Evaluation Studies Program and Radioactive Standards Distribution
Program information brochure.
Please take a few minutes to review this report and the analytical data your
laboratory submitted to us. If there are any apparent discrepancies, please notify us
immediately.
We encourage you to make use of the computer-automated data-entry system
that has been in place for some time now. As the number of participants increases,
and it becomes unrealistic for us to receive results by mail or FAX, the computer
system will be our only avenue for accepting data.
If you have any questions or comments, please send a message via the data-entry
system or contact Stephen Pia at 702/798-2102 or Patricia Honsa at 702/798-2141.
Sincerely,
Stephen Pia
Team Leader
RADQA Program
Enclosure
-------
NOTICE
This material has been funded wholly by
the U.S. Environmental Protection Agency.
It has been subjected to the Agency's review,
and has been approved for publication as
an EPA document.
-------
ESD-LV Performance Evaluation: Gamma in Water, 6-Nov-1998 1/37
The following pages consist of separate sections for each of the nuclides in this study with four
parts per section. After the first, each part is separated from the next by a new page or a thick
horizontal bar. The first page of each section is a statistical summary for the nuclide and starts
with a statement of the known value, the control limits, and the warning limits.
The warning limits are placed at two normalized standard deviations above and below the
known value and the control limits are three normalized standard deviations above and below
the known value. If you keep control charts, these values will be useful for anticipating problems
with the accuracy of your analytical methods.
The coin shaped pie chart at the top of the summary page shows the fate of all the samples
sent out in number and percentage terms. The pie chart starts at the top and rotates clockwise.
The first sector represents those participants who submitted analytical results within both the
warning and control limits. The next sector represents those who are in the warning region but
not out of control. The third sector represents those who are out of control, but have passed
the outlier test. The fourth sector represents those who have failed the outlier test. The last
sector represents those participants who have failed to respond properly. This is the case if no
analytical results were returned, or less than three determinations were reported, or if the results
were received too late. The reeding on the edge of the coin is spaced at one percent intervals, and
the sector shading becomes darker as the data reliability decreases. Sectors with zero width are
not shown.
The table in the center shows a number of statistical quantities calculated from the submitted
data based on the mean and median values in relation to the known value, both before and after
outlier removal. The lower pie chart uses the same construction as the upper chart and shows
the distribution of properly submitted data in terms of deviation from the known value divided
into sectors representing one, two, three, and greater than three normalized standard deviations.
The second part is an alphabetical listing, in lab-code order, of submitted data and several
calculated quantities. An entry that is shaded has been rejected because of one of the reasons
listed above or failure of the outlier test. The fifth and sixth columns are a measure of laboratory
precision. The Range analysis is a normalized value that you may use to keep precision control
charts. The eighth and ninth columns are the differences from the mean of all non-outliers and
from the known value, respectively. If this value is between 2.0 and 3.0, your analytical process
precision is in the warning zone; if it exceeds 3.0 it is out of control. A tag symbol may appear in
the last column. Each page with tags has a symbol definition summary at the bottom. If there is
no tag symbol, the data is within the control limits, but it may be in the warning zone.
The third part is a three-column listing of result average, tag symbol, and lab-code in average
order excluding those labs not responding properly. In this order, all outliers and out-of-control
results appear at the top or bottom of the list.
The last part is two bar chart displays showing frequency distributions of responding
participants. The first chart places the known value at the center and a bar at each 0.2 unit of
expected precision. The second chart places the mean of the reported measurements at the center
and a bar at each 0.2 unit of standard deviation. In both cases, a bar includes those results within
0.1 unit up to the maximum of six. Any results more than six units from the center value are
shown cumulatively by a shaded bar one past the sixth unit. If the central tendency of the known
value distribution falls away from the center, an error in accuracy is indicated. If the distribution
is broad, poor precision is indicated. The mean value distribution is similar but uses the average
and standard deviation of reported results as its basis.
-------
2/37 ESD-LV Performance Evaluation: Gamma in Water, 6-Nov-1998
The Range Analysis(R + SR) is calculated from the range, mean range and standard error of
the range values. The range is the difference between the maximum and minimum results for the
laboratory. The mean range is calculated by multiplying the expected precision by 1.693(for three
results). The standard error of the range is calculated by multiplying the mean range by 2.576(for
three results), subtracting the mean range from this product, and dividing the result by 3. If the
range is greater than the mean range, then the range analysis is calculated by subtracting the
mean range from the range, dividing the result by the standard error of the range and adding 1.
If the mean range is greater than or equal to the range, then the range analysis is calculated by
dividing the range by the mean range.
The normalized deviation of the mean from the grand average is calculated from the deviation
of the mean from the grand average and the standard error of the mean values. The deviation of
the mean from the grand average is calculated by subtracting the grand average from the
average of the laboratory's three results. The standard error of the mean is calculated by
dividing the expected precision by the square root of 3(the number of results). The normalized
deviation of the mean from the grand average is calculated by dividing the deviation of the mean
from the grand average by the standard error of the mean.
The normalized deviation of the mean from the known value is calculated from the deviation of
the mean from the known value and the standard error of the mean values. The deviation of the
mean from the known value is calculated by subtracting the known value from the average of the
laboratory's three results. The standard error of the mean is calculated by dividing the expected
precision by the square root of 3(the number of results). The normalized deviation of the mean
from the known value is calculated by dividing the deviation of the mean from the known value by
the standard error of the mean.
A complete explanation of the statistical calculations involved in the report may be found in
the Environmental Radioactivity Performance Evaluation Studies Program information brochure
[Draft Revision of EPA-600/4-81-004], available from Patricia Honsa, ESD-LV, 702/798-2141.
-------
ESD-LV Performance Evaluation: Gamma in Water, 6-Nov-1998
3/37
Cobalt-60 Statistical Summary 166 Participants
The known value of this nuclide is 38.0 pCi/1 with an expected precision of 5.0; the control limits
are 29.3 to 46.7; the warning regions are 29.3 to 32.2 and 43.8 to 46.7
29(17.5 %) Failed to respond
5(3.O %) Outliers •
Statistic
127(76.5 %) Within all limits
5(3
Respondents
.0 %) In warning zone
but within control
Non-outliers
Mean
Std. Dev.
Variance
%Coef. ofVar.
% deviation of mean from known value
Norm. dev. of mean from known value
Median
% deviation of median from known value
Norm. dev. of median from known value
44.12
67.92
4613.47
153.96
16.10
0.09
38.00
0.00
0.00
Grand Avg 38.17
2.38
5.67
6.24
0.44
0.07
38.00
0.00
0.00
6(4.4 %) More than 3 norm. S.D. ..^
4(2.9 %) Between 2 and 3 norm. S.D.
11O(8O.3 %) Within 1 norm. S.D.
of known value
17(12.4%) Between 1 and 2 norm. S.D.
-------
4/37 ESD-LV Performance
Evaluation: Gamma in Water, 6-Nov-1998
Cobalt-60
Lab
A
AE
AF
AH
**^r 2*'^'^ s.
Res. 1
40.0
39.0
41.0
37.0
'^^S^ij s A >i- 1 ^ ''"•ip'-ft s
Res. 2
39.0
41.0
39.0
33.0
s"^ ^"^^l ""^Z?
Res. 3
39.0
37.0
39.0
31.0
^S1^?^* i ("^S^S^SSi^^s'.;
Exper.
Sigma
0.58
2.00
1.15
J1.06
^ s\ ^^i*y%^'^^ .^ %
Rng anal
(R + SR) Average
0.118
0.473
0.236
0.709
^^^CCCj^?*./^.
j***"/i ^4 <<&^5%yp^,i^> i&V'^^^is^l^^ t^;f j^f':?:^',:/ "C^ ^rVr
AJ
AK
AL
11 jk^rt * %
Vft**&
AU
AW
AY
AZ
BA
BB
BC
,. f \ "
''^R^i ''
" iP^F "s
BH
BK
BL
BM
BN
BO
C
^CA
lC$Xj'
D
DD
DE
DH
DO
DR
DT
E
"•** A'*
* JuLfjL*^
EB
EL
*. p. -*.•»•. f
viEW
EX
46.0
39.0
43.0
: si- \ s^V JsC^:S\o^ ,'' <
^•ftSvXcxC^^'f-1?
38.0
37.0
34.0
36.0
36.0
39.0
35.0
"•£?; „ *>; y^F-^yvp/Vt^'s-j',
' fV(t ^ ' /^^fei^X « * '
\ ^ \s^£j^ ^X^*^, [^ s
38.0
40.0
42.0
37.0
45.0
38.0
37.0
40.0
I^M^W"^
'36.6
42.0
38.0
37.0
38.0
^!'?2l'>0v'^
38.0
38.0
36.0
38.0
40.0
41.0
35.0
38.0
-- -s-i:,>;:~,^f^?-1
'"•' * ••* < ''•' ViVs* s'' ' **
43.0
38.0
Vff SS.SV WSS^SSS SJ ^.^ff^ff,-.
'"^'^"^'
35.0
41.0
39.0
44.0
i'^X ). '" ' '''VV * '
%*?.-^ftrc*t
37.0
37.0
34.0
35.0
37.0
38.0
35.0
;, w.f vs%ss«/*^.ssyw
X%s ' ^Xxs. '•''
"•v¥Xs'*^ /'5f'!'\C
37.0
40.0
44.0
38.0
37.0
38.0
35.0
38.0
's 'V^s-V v s>""?A
40.0
40.0
46.0
40.0
37.0
K§|2|$4
38.0
37.0
37.0
36.0
36.0
36.0
40.0
40.0
• Y> '^'-L^C^
> I i '•"•. V ^ * NS ^
44.0
37.0
\ * i \ XA As * *y*\* * *
~ Af^->*'"
38.0
43.0
38.0
38.0
s 'Vsjf'^VfvS*'1'^ &\ & '
'-''ST* t^Swfi!^
35.0
37.0
33.0
32.0
34.0
39.0
35.0
ssss*ss^.ys,Mws v<\ s s>s ^J^ jw.^.%
JSl •.* *s % s\\ %k«.'V>'*As '
v &•> ssX^C^s"«'/ '^Hi*
38.0
41.0
37.0
38.0
35.0
37.0
35.0
_ 3Z-P~.
s? ^^^^;
37.0
37.0
41.0
39.0
37.0
5[f<^19:0"^
36.0
35.0
37.0
37.0
39.0
40.0
36.0
38.0
j5»» ^'.^vvjjg; j,* ^
>s^" j" ff X'X' %^'^ ^^'X +*'' ""
43.0
36.0
r*Vf'f s--^ tfffff.fH.lfffi,vfyM^>
A^. ^;...,-;^;-s^
34.0
• s No data submitted
0 =
Insufficient
data
X S
2.52
0.58
3.21
t \ S-X y$FP^\ J. '•• '•<^ ^
A' ' • *i\'' 'C \*v',\
1.53
0.00
0.58
2.08
1.53
0.58
0.00
AN s-s^ssvwy,«s..^s,(.'.S'ij. ^ f.
'*" "• •* i&rz&tytt* ,tSSf
'^''^'^'s &]f£&''s\ ,""' ••""
0.58
1.00
*thV-f ? ^WfS^wi^'V"*** »w«
A^X1"-". /;i-
2.08
0.591
0.118
0.709
' vs"1' t v< sv'
/^x-^^^'l ^
0.354
0.000
0.118
0.473
0.354
0.118
0.000
fff"T^'v^' ^'^
">''&' ""Vv*
v rtit^'^^w, v,'
0.118
0.118
0.827
0.118
1.345
0.118
0.236
0.354
'->H^;*t
0.473
0.591
0.945
0.354
0.118
?^2S6
0.236
0.354
0.118
0.236
0.473
0.591
0.591
0.236
Kr-lt-niStysA'tj
""^ ** t '/••jj'f' t •*•*•
0.118
0.236
ASSSSV SS^SSSV^.SSS,S>>V
•-'*• -;-;:*, -f
0.473
39.33
39.00
39.67
33.67
••: •.-,, s^ ' ^> ^t*^^^^ '^vjy^ ^
•Jfcyv^H'^' <•->' K
43.33
38.67
41.67
Vfjj^ <^' v' S''%V" ••, •i'C ' ' '^ v '
'•fr1^^,.^" ~'o?!, J'^,^
36.67
37.00
33.67
34.33
35.67
38.67
35.00
SSA.S.SSSVV A sw'^'v ™ /wv,^sw
^A ^ ^ J A ^s s* % % j" ** '
'%% s/ ''S ss .- '^ A'w rt\s'1™
37.67
40.33
41.00
37.67
39.00
37.67
35.67
,3833
t£ f *' f,'-?f V-'W.i"' %VvX X* ^ s ^
•j^1' 4^>?'s ^^x 'tt ~" '"'yi' *** ""/•
37.67
39.67
41.67
38.67
37.33
,/iX^i3l^
37.33
36.67
36.67
37.00
38.33
39.00
37.00
38.67
r-,,'-,-"-'"?^"-^:^"
' i "j, ••""••' f-^-f"^. ^^"'""^ ^Ti" '
43.33
37.00
v v ,'*''*• r"%"*s !'w/ivx'5s^!"i?7s-s^
,- ^'fP -3'.y IH^Mfue;
35.67
TAG SYMBOLS
Determined to be an
outlier
Normalized deviation
(grand-avg) (known) Tag
0.40
0.29
0.52
_-1.56
•^ ^f^ffi-"^ v^f^fvf^ffy "A s> ^
"Vj -^r'V- :''^"';
1.79
0.17
1.21
Jis s^1" > V&s ^ s •>"' s> ^
vfVS.if1' • v f '• > '' "
-0.52
-0.40
-1.56
-1.33
-0.87
0.17
-1.10
s A- f.fffffffff^a^f.^yyvjvf ss %SW^
< '"'' i* ** \ ""''"•' v s^'s f
v^'f ?C '''^sv^J-^' s' ^ /s ^.''! "
-0.17
0.75
0.98
-0.17
0.29
-0.17
-0.87
0.06
^T^~l!'*l
-0.17
0.52
1.21
0.17
-0.29
^"' 'rt*4*< ei'--' r"'^*j'
^, ss ^?v^lO'' **%*<&'
-0.29
-0.52
-0.52
-0.40
0.06
0.29
-0.40
0.17
^ V"-V ^5T 1->^C *
i" ' *V''"''^ ''s'"'^ ^^ ' ' X^^v
1.79
-0.40
«V^. ^VJ^VVAVjS SSSSAS-S^^SV f
K^v;4Vvr -<:'-^^
-0.87
ft s Above
li = Below
0.46
0.35
0.58
-1.50
SSS*.SSS^ •..SSVS.JSS^VV V-. SS.WAS.-y. VSSS
f '•:><*Kl,' - ;:- *
1.85
0.23
1.27
' ""'••'?'•> ' *IA Ji1%
x&,'^v ,' : ,'v; , .
-0.46
-0.35
-1.50
-1.27
-0.81
0.23
-1.04
vq.tf*f}ftjr.ftftv. ^ ^ f.Mf. f,f,
•. ^ ff ' *ff* jL's , %
%*N .",<£, -Xj^^ s TA "
-0.12
0.81
1.04
-0.12
0.35
-0.12
-0.81
0.12
PfP^'W?^
-0.12
0.58
1.27
0.23
-0.23
MX:: x;,v;
-0.23
-0.46
-0.46
-0.35
0.12
0.35
-0.35
0.23
JT;/";' ~,~ yr " " '" "
' "•"^ ' 'J%3f ^}>^ v •,' ^ 9 '"" *
1.85
-0.35
••SSS'S V .SSSSSSSjSSS S ^ •• '
"''•''**'•.*•.'• ^ " ,
-0.81
control limit
control limit
-------
ESD-LV Performance Evaluation: Gamma in Water, 6-Nov-1998
6/37
Cobalt-60
Lab Res. 1
Res. 2
Res. 3
Exper.
Sigma
Rnganal
(R + SR)
Average
Normalized deviation
(grand-avg) (known) Tag
FE
FJ
FL
JE
JG
JM
JS
JY
K
KH
KL
KX
L
LE
LF
LR
M
MP
MT
MV
MX
N
NH
NJ
OB
OM
OT
P
37.0
38.0
35.0
40.0
45.0
37.0
38.0
40.0
39.0
38.0
38.0
37.0
40.0
38.0
39.0
36.0
34.0
41.0
38.0
40.0
37.0
40.0
36.0
38.0
38.0
46.0
38.0
38.0
37.0
38.0
39.0
40.0
38.0
38.0
1.73
0.00
2.08
0.354
0.000
0.473
38.00
38.00
37.33
-0.06
-0.06
-0.29
38.0
41.0
37.0
38.0
39.0
37.0
40.0
38.0
39.0
37.0
38.0
38.0
37.0
39.0
41.0
38.0
41.0
38.0
39.0
35.0
37.0
38.0
44.0
38.0
38.0
40.0
37.0
41.0
37.0
37.0
37.0
47.0
37.0
37.0
40.0
38.0
38.0
38.0
37.0
38.0
37.0
37.0
1.15
2.08
0.58
0.00
0.58
1.15
1.53
0.58
1.15
1.73
5.20
1.00
0.58
3.21
1.73
0.00
1.53
0.58
1.00
1.00
0.58
0.236
0.473
0.118
0.000
0.118
0.236
0.354
0.118
0.236
0.354
1.120
0.236
0.118
0.709
0.354
0.000
0.354
0.118
0.236
0.236
0.118
38.67
43.33
37.33
38.00
39.67
37.67
39.67
37.67
37.67
38.00
41.00
38.00
36.67
37.67
40.00
38.00
39.67
37.33
39.00
36.00
37.33
0.17
1.79
-0.29
-0.06
0.52
-0.17
0.52
-0.17
-0.17
-0.06
0.98
-0.06
-0.52
-0.17
0.64
-0.06
0.52
-0.29
0.29
-0.75
-0.29
39.0
45.0
36.0
38.0
37.0
45.0
39.0
41.0
1.00
0.58
1.53
1.73
0.236
0.118
0.354
0.354
38.00
45.33
37.67
39.00
-0.06
2.48
-0.17
0.29
0.00
0.00
0.23
1.85
-0.23
0.00
0.58
-0.12
0.58
-0.12
-0.12
0.00
1.04
0.00
-0.46
-0.12
0.69
0.00
0.58
-0.23
0.35
-0.69
-0.23
0.00
2.54
-0.12
0.35
0
No data submitted
Insufficient data
y. s
TAG SYMBOLS
Determined to be an outlier
ft & Above control limit
•II s Below control limit
-------
6/37 ESD-LV Performance Evaluation: Gamma in Water, 6-Nov-1998
.
Cobalt-60
Lab
PD
Res. 1
38.0
Res. 2
40.0
Res. 3
40.0
Exper.
Sigma
1.15
;-S^;/* "''^^v;i >^^ %H- V?r-
PM
PW
PX
Q
QM
QP
QT
QU
QW
QX
QZ
R
RK
RO
38.0
36.0
39.0
39.0
37.0
37.0
35.0
34.0
33.0
40.0
40.0
38.0
42.0
36.0
37.0
36.0
32.0
42.0
39.0
34.0
34.0
32.0
33.0
40.0
40.0
39.0
36.0
36.0
40.0
36.0
39.0
41.0
40.0
32.0
36.0
37.0
34.0
41.0
38.0
38.0
37.0
37.0
1.53
0.00
4.04
1.53
1.53
2.52
1.00
2.52
0.58
0.58
1.15
0.58
3.21
0.58
Rnganal
Normalized deviation
(R + SR) Average (grand-avg) (known) Tag
0.236
,V - ^ ^jv^^*.^^ M/ <^M.W^W.SWA *% -^ -"'^w r v...
*' Him/'
Mffv1
'< ", , ,',s
BX^
^T*£S^
S '"
SD
SF
SI
SM
SN
SR
ss
sv
sx
T
TC
TD
ivrsss*^
* t-**!*t
TO
TQ
TR
TW
U
\UM"
UP
'%w •ii''*
Tv'XJIl\
uv
^ux
"jncc
> # ^-' '*$£ \j<-'f^'y 4$'?
£$?3$^j^>
c '''*" » ¥T*-' v? .*&s
40.0
^?al|&5'
•*•—"-
36.0
40.0
37.0
42.0
37.0
38.0
38.0
39.0
37.0
38.0
37.0
38.0
"srj^Kyr^*^^.'^
i^'ST , ~ V'if^4-£!
29.0
37.0
30.0
44.0
40.0
j--~y^^7^
4o!o
A*, ^ ^X"*1 ">"*wys ^i
vf ; Vf r ^T-
37.0
_36.0
;t; m'v?^/,A ',,
^ ^ «*.>" v; " /••
** * f'"'1 *' ''.'/••'• ^^ * ^ ^
••'' ' *w^sfX<;^«<4&vx
41.0
/ ''£"'??* ^^^(\^<^
37.0
38.0
36.0
44.0
36.0
36.0
32.0
41.0
39.0
40.0
37.0
38.0
49.0
" •>-™'^*Tr^j"TO~'
'*'^' V^?-'? VH>'
54.0
37.0
30.0
41.0
40.0
A»%^«. ^.•.•^-^;f.ff^^fy-f-
'"£i£*'JN^
38.0
' " * 'V"*^* * ws ^
,v , \Y}^ "M'",
37.0
39.0
";"7 i-^Cu1
•• «*V "''•."}•, ^'%\ fv
'-^'^^
*, "t"^-/1'"^?^
39.0
•$." ^f^s^y-y^,
' 'JwA\ J. At / l\fj&
" 31.0
37.0
35.0
41.0
42.0
32.0
36.0
39.0
38.0
38.0
37.0
37.0
41.0
;ri'TF-T'y~, ~ ^
,«.. "/'^Jf'o'V
50.0
34.0
28.0
51.0
38.0
^S-t:^^
37.0
'* , - (XX-w* ,* " * "-A
^--' ^ ;*/x,^
36.0
37.0
•s';:%'j?, • l'~,.
• = No data submitted
0 =
Insufficient
data
X =
"•"•* f- fs-vi' ' ' •.
*^'^-x '•&?'• •£ <'% ' ' ' S'A%
I/ ***• ^ ^* J!> % , j; v^;'
1.00
^i^S?
0.58
1.00
2.65
3.51
3.46
2.65
3.06
1.53
0.58
1.53
0.58
0.58
5.69
«. «WA..,V™,X^ Aw^yv,,^
^'* ^"^^^vir'^"'
13.43
1.73
1.15
5.13
1.15^
FTlBJy- ;;^
V ' ""'f '" 'V's " " , ~" ^
0.236
^/i&KJ^P
"aii's
0.236
0.591
0.827
0.709
0.591
0.709
0.354
0.118
0.354
0.118
0.118
1.570
*~; T5""'^/""',/^-' ™^f
-- :\^j'"''-"f'-~ '->-«",
4.721
0.354
0.236
1.345
0.236
XT^^i'^
0.354
'"•?• •- -,!»-' 4, ,,.-,: •;';,'"-;.
"'/l?/^5', -- "'?•»'• 'r
0.118
0.354
% '^'^ '' "'?'i : l
* V>"C *'
tw, SS's.' ,"*}/-' <*
; ^A* ', *, ' v
'' !0'v ^/f'"!'' '•' -"
40.00
iiiasli?
36.67
37.00
37.00
40.67
40.00
35.00
35.33
39.33
38.67
38.33
37.33
37.33
42.67
t82i$pn3K?$
~'''&'^'^1'".^',
44.33
36.00
29.33
45.33
39.33
(~sj?pp
38.33
\. 'S K ""' *t* '
*^'; - ''>';- v
36.67
37.33
\ , * 1- I..
TAG SYMBOLS
Determined to be an outlier
' s' < *v * , A'<. •••.''
'iflSSS^--'
***'» <*&®£^7,v- "; '"-.vr
\^'^f.^'f": > l> '
2.14
-0.75
-3.06
2.48
0.40
i~-^:<^~^S
0.06
f ' A "' *^"_w, - "SX "• ^
*'-; *"**&. - ;V A-^'
-0.52
-0.29
,'f';*' "i?1-',;', ,
It s Above
II = Below
>> /^^ ' A d| •. V
''" "x':-^ '^'k
- , J'-'; ' ' , >""•';,"
0.69
\§iK*yx"%
-0^46
-0.35
-0.35
0.92
0.69
-1.04
-0.92
0.46
0.23
0.12
-0.23
-0.23
1.62
AAV^^^^v,™ ^AA,' N S^<
v ^v,fF %s's"" "*;' * *
2.19
-0.69
-3.00
2.54
0.46
"fg>n / » : !
0.12
A ' ,•• <"\ ^S % X ' ' ^ '
f\" -'' - • >.
-0.46
-0.23
,.':3- „;>- ' *•''
control limit
control limit
-------
ESD-LV Performance Evaluation: Gamma in Water, 6-Nov-1998
7/37
Gobalt-60
Lab Res. 1
Exper. Rng anal Normalized deviation
Res. 2 Res. 3 Sigma (R + SR) Average (grand-avg) (known) Tag
S*» ^^*Vfti^?"^ ^T. ^V>*xs ^4VJ^-i'V|:?*r-f^^'^;'>f ^ ''K^HX ^ <*' "*" ^fi^v
0.118 40.67 0.87 6.92
37.00 -0.40
38.67
40.00
W$L-,v ^ ,-<, --N,^-
1^\-,., \\ \^ V"
42.0 40.0 5.86 1.570 37.67 -0.17
39.0 37.0 1.15 0.236 37.67 -0.17
38.0 36.0 1.15 0.236 36.67 -0.52
38.0 38.0 0.58 0.118 37.67 -0.17
vc
VE
VH
VI
41.0
37.0 37.0
39.0 37.0
40.0 41.0
31.0
37.0
36.0
37.0
41.0
37.0
40.0
39.0
0.58
0.00 0.000
1.53 0.354
1.00 0.236
At ^f&w^C* ***?* y&sffpH^ss -"'
\'V * «>j"i% *\^*.*'«•••
0.17
0.64
0.92
-0.35
0.23
0.69
r.ws o
&K*
.^. .. « ^ A-1
l%|
ww
5'
X
XA
XB
^ai
XD
XF
37.0
37.0
39.0
40.0
37.0
41.0
37.0
:«^;V^X'l*5s\.^-^SpwTwK" \'U"Y» "'•!,! -x=v' , >\ s. -' - ~s > -;A« -VLis",^^"• V^-ok^vvl ~- «V'
.-^»_»,_™ - ""™0;354 "37;g3""" ^.0 29 '" T6.23
"~ vxssj^^BSxjft^jj' \-V""'"'"^*"^ " '•Vb™ \»>V ^Ki,-- a **%^*C^",t^ ^^ v^ T"H. ^"^s.^^?1 'v "jv"V^ ^ f *-<^"~>.^. \\w5%
^^S^;M-%^-;^€X- -: \ «\-;v ;-v-^;^44^,v^^v^fe^5^^
38.0 1.00 0.236 38.00 -0.06 0.00
^*vXrt^^*Tyi^'^ h^s*V- - ;:v-^;- ^M^^V.swv%i*«. -. % •Si'tA ^ •.rfivf'v. sU\ fa' v,V.%«\ 5 •, \-TrffOs'. S •, M.V. * % •. * i -.X \\ ^« s 4N VAI iV " ^ V S* ^X ^ s
44.0 4.16 0.945 45.33 2.48 2.54
At t\ f\ KQ A 1 1 O Af\ CH f\ OH f\ nrt
;!>«•••>:
t^>- ^-^
41.6 39.0
35.0 38.0
**t.VJ •*. JLO U.»«tU
41.0 0.58 0.118 *v».oi u.o
36.0 0.58 0.118 36.67 -0.5!
t^l^Wf^^^r;r^vV^-'Xvt"-;^;^^^^^^^v ;/';
?c«%f-^-4^", x H-vv^- v, -»*rky-/ ^-^*%V?^Ar> l!:¥f •"*
410 1.15 0.236 4033 O7!
2.48
0.87
,52
41.0
37.0
_.1.53_w_ J>-354
0.118
40.33
36.67
'-\v ?-'w\5' ••"
• •&o 4^"%f,^ x*\
36.67
40.67
0.75
-0.52
2.54
0.92
-0.46
- -*~, v >*- -.^^.^LW-^XS X
«', - \v >>S>A->••*•« ,v
•_•»- -..^- »;-;x—-X ,• ~?J
0.81
^-0.46^__
V -6.46
0.92
38.0
35.
37*0 0.58 0.118 36.67 -o"52 "-6.46
^ 42.0 __, JJSl_w,JD^7JL^, t J*i§7 9-87, °-9?
Il^sl^^ IM^
'I^S'? .^Lj^^llj^^iLrZZlJH^
36.6 1.53 6.354 36.33'"" -0.64 -0.58
Average
Tag
Data sorted by Laboratory Average
Lab \ Average Tag Lab \ Average
Tag
Lab
20.33
28.33
29.33
33.33
33.67
33.67
34.33
34.33
34.33
35.00
35.00
x
x
CX
RZ
TB
QW
AY
AH
QU
QP
AZ
SN
QT
35.00
35.33
35.67
35.67
35.67
35.67
36.00
36.00
36.00
36.00
36.33
BC
SR
I
EX
C
BA
TQ
PW
NP
NH
Y
36.33
36.67
36.67
36.67
36.67
36.67
36.67
36.67
36.67
36.67
36.67
RO
XI
XF
XB
W
uv
s
PX
LR
DE
DD
• = No data submitted
0 s Insufficient data
TAG SYMBOLS
x = Determined to be an outlier
It s Above control limit
& = Below control limit
-------
8/37
Cobalt-60
ESD-LV Performance Evaluation: Gamma in Water, 6-Nov-1998
Data sorted by Laboratory Average
Average
36.67
37.00
37.00
37.00
37.00
37.00
37.00
37.00
37.00
37.33
37.33
37.33
37.33
37.33
37.33
37.33
37.33
37.33
37.33
37.33
37.33
37.67
37.67
37.67
37.67
37.67
37.67
37.67
37.67
37.67
37.67
37.67
37.67
37.67
Tag Lab
AU
XT
VE
SF
SD
EL
DT
DH
AW
WR
TJX
TC
T
NJ
MX
JM
ffl
HE
FL
D
CS
WD
vs
vo
OT
M
KX
KL
K
GL
CE
BO
BM
BH
Average Tag
38.00
38.00
38.00
38.00
38.00
38.00
38.00
38.00
38.00
38.00
38.33
38.33
38.33
38.33
38.33
38.33
38.33
38.33
38.67
38.67
38.67
38.67
38.67
38.67
38.67
38.67
39.00
39.00
39.00
39.00
39.00
39.33
39.33
39.33
39.33
• s No data submitted TAG SYMBOLS
0 = Insufficient data x = Determined to be an
Lab
WW
OB
MT
LF
L
JS
HK
GQ
FJ
FE
UP
sx
RK
R
PM
IU
DO
CA
VH
sv
QM
JE
E
CP
BB
AK
P
N
DR
BN
AE
U
SS
QZ
PD
Average Tag
39.33
39.67
39.67
39.67
39.67
39.67
39.67
40.00
40.00
40.00
40.00
40.00
40.33
40.33
40.33
40.67
40.67
40.67
40.67
40.67
41.00
41.00
41.67
41.67
42.67
43.33
43.33
43.33
44.33
45.33
45.33
45.33
51.33 x
74.33 x
831.67 x
ft & Above control
outlier 11 & Below control
Lab
A
O
MV
KH
JY
CJ
AF
VI
SM
RX
MP
HL
XD
QX
BK
XK
XA
VC
SI
Q
LE
BL
CO
AL
TD
JG
EB
AJ
TO
X
TW
OM
NO
OA
XU
limit
limit
-------
ESD-LV Performance Evaluation: Gamma in Water, 6-Nov-1998 9/37
Cobalt-60
% responding labs Frequency distribution
20
10H
•••I.-.
-6 -4 -2 0 +2 +4 +6
Normalized deviation of the mean from the known value
% responding labs Frequency distribution
20-
10
ulillIJi
-6 -4 -2 0 +2 +4 +6
Normalized deviation of the mean from the grand average
-------
ESD-LV Performance Evaluation: Gamma in Water, 6-Nov-l998
10/37
Zinc-65 Statistical Summary 166 Participants
The known value of this nuclide is 131.0 pCiA with an expected precision of 13.0; the control limits
are 108.4 to 153.6; the warning regions are 108.4 to 116.0 and 146.0 to 153.6
3O(18.1 %) Failed to respond ^
7(4.2 %) Outliers •
2(1.2 %) Out of control •"
but not an outlier
Statistic
, 112(67.5 %) Within all limits
Respondents
"• 15(9.O %) In warning zone
but within control
Non-outliers
Mean
Std. Dev.
Variance
%Coef. ofVar.
% deviation of mean from known value
Norm. dev. of mean from known value
Median
% deviation of median from known value
Norm. dev. of median from known value
163.02 Grand Avg 137.21
303.49 7.65
92103.49 58.45
186.16 5.57
24.44 4.74
0.11 0.81
137.33 137.33
4.83 4.83
0.02 0.83
9(6.6 %) More than 3 norm. S.D. ..^
15(11.O %) Between 2 and 3 norm. S.D.
• 7O(51.5 %) Within 1 norm. S.D.
of known value
42(30.9 %) Between 1 and 2 norm. S.D.
-------
11/37 ESD-LV Performance Evaluation: Gamma in Water,
6-Nov-1998
Zinc-65
Lab
A
AE
AF
AH
™ V"j;«5^
&A*! V^t^y'^
153.0
133.0
129.0
^SC^fi*!^
122X)
135.0
135.0
132.0
120.0
145.0
139.0
"rr;%*t*7*^;;
154.0
152.0
130.0
135.0
136.0
136.0
130.0
116.0
« .. nw vJJ. %A^,-»1S-.%
,>.. , ""' ^ 0 A. ^A ' ,. V
138.0
153.0
145.0
143.0
140.0
'.yWV^T&O'?.'
140.0
137.0
134.0
127.0
146.0
138.0
144.0
140.0
• , :r
Y^-dWolv
133.0
' /3 ;r vrv*
130.0
Res. 2
143.0
130.0
143.0
139.0
tS "S* '<§w^sK^C~s
'i^'-^Cf^
135.0
136.0
127.0
"^^I^
mo
132.0
134.0
139.0
128.0
143.0
138.0
>p^7*^"
151.0
152.0
130.0
134.0
150.0
136.0
139.0
117.0
< S s , *•*. f «, 'jff
',:;<•&$
134.0
132.0
162.0
154.0
141.0
!t^yj$&
138.0
140.0
135.0
128.0
141.0
144.0
136.0
143.0
"• .~,-^ < -
r 170.0
128.0
'•/Vv?:-
118.0
Res. 3
140.0
140.0
140.0
121.0
~.y, , . «,,,* **""£.>' ^
^ixfo-- J$^*ft^ *- '
135.0
137.0
^ 131.0
S;r^4^vCi^"-!
131.0
130.0
127.0
134.0
130.0
143.0
138.0
^,,v^"£v,™.'
155.0
152.0
137.0
140.0
132.0
130.0
133.0
130.0
"" "" \ •? "* *•#*"** V%^*'
>:-!;^ ,'/^/. >?lJ
140.0
137.0
150.0
142.0
U2.0
;:'*T/;fi;<£7,
137.0
135.0
135.0
125.0
122.0
130.0
141.0
142.0
':) ' ,',O"' '"'i
^ »:, -:-<>-/ ' >*
,: 170.0;
132.0
Vv^C'^;^
136.0
• = No data submitted
0 =
Insufficient
data
X 3
Exper.
Sigma
1.53
5.03
2.08
11.36
' ' /' jf^jK* **•'• V-
f - 1*1*^,: ' '^
10.39
2.08
2.00
^W^l^-'^t
5.86
2.52
4.36
3.61
5.29
1.15
0.58
•^Tllv* \''-
2.08
0.00
4.04
3.21
9.45
3.46
4.58
7.81
•• s s<% •.' ' fff f"."- ^ '/
.-- ;>*;' -,• \~i^
3M
10.97
8.74
6.66
1.00
x-.-;:'"iv6o /-
1.53
2.52
0.58
1.53
12.66
7.02
4.04
1.53
Rnganal
(R + SR)
0.136
0.454
0.182
0.954
4^- 'C /••"-' .~v"
;s '"s>^^-4*-f* ,** '5
0.818
0.182
0.182
Q^y ^~ ,, -"'"
0.500
0.227
0.363
0.318
0.454
0.091
0.045
-'£'>*: :~^ » £
0.182
0.000
0.318
0.273
0.818
0.273
0.409
0.636
'•- ""' * 'r J •-•.
" ' '- -•'•f, 'l-*
0.273
0.954
0.772
0.545
0.091
0.091 ,;
0.136
0.227
0.045
0.136
1.172
0.636
0.363
0.136
Normalized deviation
Average
141.33
134.67
140.67
126.00
V^' \\*"t«^fl*-'V w
^'»^; *j^^
141.00
135.33
129.00
-%,-,>_, ^-f;
128.67
132.33
132.00
135.00
126.00
143.67
138.33
X'&4'T!T
153.33
152.00
132.33
136.33
139.33
134.00
134.00
121.00
, S% ^ , S V
-..,._< i1 ; ;
137.33
140.67
152.33
146.33
141.00
^-1v7i.66
138.33
137.33
134.67
126.67
136.33
137.33
140.33
141.67
(grand-avg) (known) Tag
0.55
-0.34
0.46
-1.49
9_
''-X ,,';^'^x- .-\
-1.14
-0.65
-0.69
-0.29
-1.49
0.86
0.15
i' cr'T^''-'^' '-
2.15
1.97
-0.65
-0.12
0.28
-0.43
-0.43
-2.16
, ,./•., >vf , }f%yf g , A __ • -.j,^
*,'i ^^/^rt''^'-, " ',-j
0.02
0.46
2.02
1.22
0.51
v;/«-v'r^82'"- 'v,
0.15
0.02
-0.34
-1.40
-0.12
0.02
0.42
0.59
1.38
0.49
1.29
-0.67
m-y^,^ -y^^.,,,-.^, ,
'V'XlA'1' ' ,'r'sf •'*'?i'"
1.33
0.58
-0.27
:.4>^'^ ,- »x '-*
-0.31
0.18
0.13
0.53
-0.67
1.69
0.98
>~ j:x'-' ^-,;,/
2.98
2.80
0.18
0.71
1.11
0.40
0.40
-1.33
<,V.W f > f, f- ,_f •• ' .•_.«. ^
• *% .,'' >»>. :'
0.84
1.29
2.84
2.04
1.33
>^fi99^"'>^r
0.98
0.84
0.49
-0.58
0.71
0.84
1.24
1.42
\ ." H?'.* -f^fl^^f^ - -x^v : ''Vr'-, ;; ,"j''~K"?& '', '/;" •^-;;>v'"^ ^"' '_ B' ,-
^-vioSlO"1
2.65
- rpl/:\ \ ',"' ,
9.17
:^KOOO ~
0.227
;r"^?y>""
0.818
/ 170,00
131.00
' i'"-' '/
128.00
TAG SYMBOLS
Determined
to be an outlier
*• >* ' * ' "'
' :V?^87'/-/
-0.83
--^=rSi-^' -r
-1.23
IT = Above
$ = Below
6.26 X
0.00
-"^; .' •' %
-0.40
control limit
control limit
-------
ESD-LV Performance
Zinc-65
Lab Res. 1
FE
FJ
FL^
GL
GQ
HE
m
HK
HL
US
JL,.,
JE
JG
JM
JS
JY
K
KH
KL
KX
L
LE
LF
LR
M
MP
MT
MV
MX
N
NH
NO
NP
^0 ^
'SQB3
OM
OT
P
• =
0 e
120.0
143.0
_ 137.0 ^
-^"Y4i.oT~
139.0
134.0
130.0
141.0
131.0
"JljiMLl
._„.„ _^
160.0
132.0
137.0
146.0
138.0
127.0
138.0
140.0
141.0
180.0
150.0
134.0
144.0
134.0
142.0
140.0
120.0
134.0
145.0
137.0
*t^P^^
150.0
131.0
^_J140.0_
^1: v ~;i|\^'^
141.6
129.0
__ 131.0 _
Res. 2
130.0
140.0
139.0
" 135.6 "
139.0
134.0
126.0
139.0
135.0
ms?z
~~43.Q~"~
162.0
135.0
141.0
150.0
136.0
130.0
139.0
137.0
128.0
135.0
140.0
138.0
146.0
130.0
144.0
133.0
126.0
136.0
146.0
135.0
~"l55.0
141.0
142.0^
4^|fex^A\f-
145.0
119.0
127.0
Res. 3
140.0
136.0
^J45JO_
* "l36.0
139.0
136.0
125.0
144.0
134.0
iii
" 143.0
159.0
135.0
139.0
151.0
138.0
130.0
137.0
126.0
136.0
145.0
150.0
135.0
152.0
137.0
138.0
141.0
124.0
142.0
148.0
136.0^
160.0
133.0
142.0^
if ;|^;2^]biOp
fe4\^%§;
~ 148.6
142.0
125.0
No data submitted
Insufficient
data
x s
Evaluation: Gamma in Water, 6-Nov-1998
Exper.
Sigma
10.00
3.51
_4-16_^
3.21
0.00
1.15
2.65
2.52
_J2.08
£ijp"
1.53
1.73
2.00
2.65
1.15
1.73
1.00
7.37
6.56
23.63
5.77
2.08
4.16
3.51
3.06
4.36
3.06
4.16
1.53
1.00
sioo
5.29
^_Hl-~,
J?^^-^^i~4
"""sir"
11.53
3.06
12/37 1
Rng anal Normalized deviation
(R + SR) Average (grand-avg) (known) Tag
0.909
0.318
_OJt63
0.273
0.000
0.091
0.227
0.227
^p-isji
6.136
r^.«ar
4i^^!A>v
"*O091
0.136
0.136
0.182
0.227
0.091
0.136
0.091
0.636
0.591
2.990
0.454
0.182
0.363
0.318
0.273
0.363
0.273
0.363
0.136
0.091
0.454
0.454
0.091
^?227
i;4|,*|ivr
0.318
1.086
0.273
130.00
139.67
^_Jt4O33iiw
137.33 T
139.00
134.67
127.00
141.33
133.33
•wy^wyr-^ " st*v%s^;*yMs^ss^<^f^<
^"J_132.67/^
iSie'T ,
160.33
134.00
139.00
149.00
137.33
129.00
138.00
134.33
135.00
153.33
146.67
135.67
147.33
133.67
141.33
138.00
123.33
137.33
146.33
w»._i2§-°?^.
155.00
135.00
141.33
sw^'^A-y^'-^^'*"'*?'.^'** • •. v. ^"^.*O
?15;63-'<-,X'.S-.
^ ^ % t - ^^ v *^ '"'"'
Teg"™
3.91 ft
0.40
1.07
2.40
0.84
-0.27
0.93
0.44
0.53
2.98
2.09
0.62
2.18
0.36
1.38
0.93
-1.02
0.84
2.04
3.20 ft
0.53
^ 1.38 _
v-'.xV-: -' '"•'^
1.82
-0.13
-0.44
control limit
control limit
-------
13/37 ESD-LV Performance Evaluation: Gamma in Water, 6-Nov-1998
Zinc-65
Lab
.^L
PM
PW
PX
Q
QM
QP
QT
QU
QW
QX
QZ
R
RK
RO
:M^w"*y <**
vHR'1
''•TOTT^-
',JvU>'<
RX
RZ
S
SD
SF
SI
SM
SN
SR
ss
sv
sx
T
TC
TO.
TO
TQ
TR
^•.^—-•s
??t'JLW^
U
;UM"
UP
*;ttw
UV
ux
'"Vtv'"'
/&*,* ^
• =
0 s
Res. 1
_ J14OO_
*"— £j7j0j""
133.0
127.0
129.0
138.0
130.0
134.0
116.0
116.0
142.0
143.0
141.0
150.0
153.0
v^T^T*-??^^ ~ ~^-
"'i.'*^^^^'?^
J?"r'%/':.-'^<;-'^-,""
'-/ , ^"f/"-"
124.0
126.0
134.0
141.0
135.0
146.0
144.0
137.0
134.0
137.0
143.0
150.0
120.0
130.0
_128.0_
~i3ao
134.0
123.0
",;; ~*'^ Ko'*v~ '
* ' ' - " ^ylO,O»v C,r~
134.0
T"; i-^'^""
137.0
,v* , - "•strr- rr
?„ sk ^<*,x.«™Ai
"ST- ' ^ *isi '-"? JLtU ;r^ 'stff^tt
' -,s \> s > ! '"•><
139.0
••ss^ r,n~-»7j ^
115.0
145.0
" " "^ J\ * ^\'"" - ? * '
*V is ^S '**'"' > * ^
Res. 3
125.0_v
144.0
131.0
132.0
125.0
143.0
127.0
134.0
119.0
116.0
136.0
144.0
142.0
140.0
15J7.0_
?' *W^\ ^^''^s ^
l^-'^'f *-^i%^
,*s,\','X.% /-""^^J'*' ,
125.0
148.0
133.0
142.0
133.0
141.0
143.0
116.0
132.0
148.0
137.0
135.0
139.0
130.0
^J43X)_
" 155.0
143.0
134.0
-•'xiy^art V\\
^^•^ijjJosUj '^.7v>.^Tr
''•Y - ''Ivs^W" • •*'
''•V^-'^K'l '
i"1^/'..' ^"x *,"'
1.00
11.06
1.00
2.65
4.73
5.51
6.08
11.36
3.61
7.37
6.51
7.64
11.27
1.15
,.^.64^
*" 18.45
4.73
6.35
^''r^ij/QR''-"
*f?i?'"i''*&tvO *V,V-
q.58_ __
, '"Tf^fjT;;^;^
1.53
? ' !fj s <>w v **Jjk*<,<£
A>iX S"s^ ""-^ s-^. s ''A^' *^/
9.02
4.51
+,?<*.'$ "%**"' "f'x'^
^''X''V ' "" V« *'•'''•'
Rng anal Normalized deviation
(R + SR) Average (grand-avg) (known) Tag
J).682
0.863
0.136
0.227
0.182
0.363
0.318
0.045
0.136
0.182
0.273
0.045
0.136
0.909
1.086
t3S*&-fff^?f'&i'yf
*A^ *%^'^h
% ^"w""^% s
' J^' ^ ** ' >f ,;
0.091
1.000
0.091
0.227
0.409
0.500
0.500
0.954
0.318
0.636
0.591
0.682
0.909
0.091
-^IJr
2.211
0.409
0.500
' i'f&vi
•* »'*4-«vUO
0.045
's^-?'^^-*™
0.136
0.818
0.409
, \*rf^|^;
" - v ' .^
134.67 _^
139!67
131.33
129.00
127.67
142.33
130.33
134.33
117.67
117.33
138.67
143.67
142.33
140.00
148.00
^'?!V^";" " "Jv/^?"-^^ '
*''•<;' ^vO-r.-' • '• '"V,'
* 'v^> ^ j S-.V $*
-•""I""",1, '.^
"',-": « ,-^-;'frS1''''', '"**
124.00
137.67
134.00
140.00
131.33
146.33
140.00
129.00
135.00
145.33
136.67
143.33
133.00
129.33
139.00
150.33
137.67
126.67
'' I '?• '-' -i m; qo". ; '
*/'?'",>'./ J-Ov»«>«J' ' ' ',
134.33
v:~™7>^^-5
138.67
A-V -—•--- -,'5'- ^»- "T;* ,"••*
123.67
140.33
-\Ai-" >x"it%^\-- ^~ ' '»
" '' * x . ".
TAG SYMBOLS
Determined
to be an
outlier
^_-0.34_
0^33
-0.78
-1.09
-1.27
0.68
-0.92
-0.38
-2.60
-2.65
0.19
0.86
0.68
0.37
1.44
P«y^™™
'- '*<•" "'
• -?;, a;,-1'!^
><• ^j"'^*1' ' '"
-1.76
0.06
-0.43
0.37
-0.78
1.22
0.37
-1.09
-0.29
1.08
-0.07
0.82
-0.56
-1.05
..JtH* ....„,.
1.75
0.06
-1.40
"" "o'7|-" "* '
,"- ^ Ov'O ;", o1""-
_-0.38_^
,v7A'- CT?; .'-'«.
0.19
mVr«' Vfrp'y.;?!' '
-1.80
0.42
A, ^ ' ' " y/^ ' ••' ' %
' ' .. 'f V -'
tt s Above
Ji s Below
AIL.
£15
0.04
-0.27
-0.44
1.51
-0.09
0.44
-1.78
-1.82
1.02
1.69
1.51
1.20
2.26
••^^^ww ; «A~~« .~w
'Vv™''^'"- x',^'*'l' ••'{'
^?\i*ri^&L' '•'
'% " ' v s •.''•"'
-0.93
0.89
0.40
1.20
0.04
2.04
1.20
-0.27
0.53
1.91
0.75
1.64
0.27
-0.22
\ff]
2.58
0.89
-0.58
V, " ' %* " <" *
^ jljO i ' X ;*
0.44
Cs™'.;.» '"
1.02
'-"'".;rv^v • ' »^---™~
-0.98
1.24
'' '• •
• . , ' ' «< '
control limit
control limit
-------
ESD-LV Performance Evaluation: Gamma in Water, 6-Nov-1998
14/37
Zinc-65
Lab Res. 1
Exper. Rng anal Normalized deviation
Res. 2 Res. 3 Sigma (R + SR) Average (grand-avg) (known) Tag
3.51 0.318 147.33 1.35 2.18
0.727 149.67 1.66 2.49
151.0
141.0
145.0
146.0
144.67
145.67
134.0 145.0 7.77 0.682 136.33 -0.12 0.71
^y«^^^^^X*<««^*^ < * "• w* "• "• x t«W^*^<™' ^wic-wif w^ SJJJyv ft "W*^ f {• V «•«* •"•*X£«\ •<••*< ^^!»wjM«1*V«rtvvw.«\sx^. ww^x-^t •«'••*•'«'••** AVW,,.™*!"^ W^-A v«.\ ^NW^W>V >>t*w^!p. ™*
B^ "•: ,^JjW StS-^ Ss- A; ;?: Ir^^^^-^S^?^
115.6 147.6 16.17 1.865 132.33 -0.65 0~18
157.0 126.0 17.62 1.778 146.33 1.22 2.04
_6-66,^ 0.545 ....... IJf-OT... ..... ^0.99 ^^^
4.04 0.363 142.33 0.68
1.82
8.02
0.727
'^"*^*/^-> ;£'" V-- •i-Xi'Ci ^ <• Vs1"1-' ""^ "^ "' «0">V*T)T/*.,''
140.0 6.66 "0.006
148.0 4.73 0.409
^'^^^^p^^
,,, ...j^,..„ _. ..
137.33
0.02
uo.oo .37
144.33 0.95
"
1.51
0.84
4.16
.363
Average
Tag
Data sorted by Laboratory Average
Lab Average Tag Lab | Average
Tag
Lab
13.67
71.00
107.33
117.33
117.67
121.00
123.33
123.67
124.00
126.00
126.00
x
x
X
IU
CX
WR
QW
QU
CA
MX
UV
RX
BA
AH
126.67
126.67
127.00
127.67
127.67
127.67
128.00
128.67
129.00
129.00
129.00
TR
DH
HI
W
Q
P
EX
AU
SN
PX
KH
129.00
129.33
129.33
130.00
130.00
130.33
131.00
131.00
131.00
131.33
131.33
AL
Y
TC
OT
FE
QP
WD
VO
EL
SF
PW
• e No data submitted
0 s Insufficient data
TAG SYMBOLS
x s Determined to be an outlier
ft = Above control limit
$ = Below control limit
-------
15/37 ESD-LV Performance Evaluation: Gamma
Zinc-65
in Water, 6-Nov-1998
n
Data sorted by Laboratory Average
Average Tag
1 132.00
132.33
132.33
132.33
132.67
133.00
133.33
133.67
134.00
134.00
134.00
134.00
134.33
134.33
134.33
134.67
134.67
134.67
134.67
135.00
135.00
135.00
135.00
135.33
135.33
135.67
136.00
136.33
136.33
136.33
136.67
137.33
137.33
137.33
% responding labs
10-
° -6 ' -'4
Lab
AY
X
BL
AW
I
T
HL
MP
S
JM
C
BO
U
QT
KX
PD
HOE
DE
AE
SR
NP
L
AZ
VS
AK
LR
NJ
WW
DO
BM
sv
XF
N
K
Average Tag
137.33
137.33
137.33
137.33
137.67
137.67
138.00
138.00
138.33
138.33
138.67
138.67
138.67
139.00
139.00
139.00
139.33
139.67
139.67
140.00
140.00
140.00
140.00
140.33
140.33
140.33
140.67
140.67
141.00
141.00
141.33
141.33
141.33
141.33
Frequency distribution
. Mil
: ... iiliimll
-'2 T J T
Lab
GL
DR
DD
CE
TQ
RZ
MV
KL
D
BC
XT
UP
QX
TD
JS
GQ
BN
PM
FJ
XI
SM
SD
RK
UX
FL
DT
CJ
AF
CS
AJ
O
MT
HK
A
Average Tag
141.67
142.33
142.33
142.33
143.33
143.67
143.67
143.67
144.33
144.67
144.67
144.67
145.33
145.67
146.33
146.33
146.33
146.33
146.67
147.33
147.33
148.00
149.00
149.67
150.33
152.00
152.33
153.33
153.33
155.00 ft
160.33 ft
165.33 x
170.00 x
274.33 x
3669.33 x
"J
••_.._ _ _ _
J2 ' 4
Lab
E
XD
R
QM
SX
QZ
JE
BB
XK
XB
VH
OM
ss
VI
XA
SI
NH
CP
LF
VC
M
RO
JY
VE
TO
BK
CO
LE
BH
NO
JG
TW
EB
OA
XU
m
+6
Normalized deviation of the mean from the known value
• = No data submitted
0 s Insufficient data
TAG SYMBOLS ft = Above control
x = Determined to be an outlier U = Below control
limit
limit
-------
ESD-LV Performance Evaluation: Gamma in Water, 6-Nov-1998 16/37
Zinc-65
% responding labs Frequency distribution
10
-6 -4 -20 +2 +4 +6
Normalized deviation of the mean from the grand average
-------
ESD-LV Performance Evaluation: Gamma in Water, 6-Nov-1998
17/37
Cesium-134 Statistical Summary 166 Participants
The known value of this nuclide is 105.0 pCi/1 with an expected precision of 5.0; the control limits
are 96.3 to 113.7; the warning regions are 96.3 to 99.2 and 110.8 to 113.7
3O(18.1 %) Failed to respond ^
5(3.O %) Outliers •'
6O(36.1 %) Out of control
but not an outlier
Statistic
t. 43(25.9 %) Within all limits
Respondents
28(16.9 %) In warning zone
but within control
Non-outliers
Mean
Std. Dev.
Variance
% Coef. of Var.
% deviation of mean from known value
Norm. dev. of mean from known value
Median
% deviation of median from known value
Norm. dev. of median from known value
105.32
98.90
9781.94
93.91
0.30
0.00
96.67
-7.94
-0.08
Grand Avg 97.11
6.14
37.67
6.32
-7.52
-1.29
96.67
-7.94
-1.36
69(50.7 %) More than 3 norm. S.D.;
24(17.6 %) Between 2 and 3 norm. S.D. -
,-17(12.5 %) Within 1 norm. S.D.
of known value
26(19.1 %) Between 1 and 2 norm. S.D.
-------
18/37 ESD-LV Performance Evaluation: Gamma in Water, 6-Nov-1998
Gesium-134
Lab
A
AE
AF
AH
AJ
AK
jSJL^
._.
AW
AY
AZ
BA
BB
BC
fiilf-p
»pbH#i|
BH
BK
BL
BM
BN
BO
C
CA
itppl
^HK-X'VV:':^
CE
CJ
CO
CP
cs
D
DD
DE
DH
DO
DR
DT
E
^SS-WW-i-WSS
ifEAlP
EB
EL
K^w.m^"-::y.y
flEWS
£•***;**«
EX
Res. 1
106.0
102.0
100.0
99.0
^^S;^^?^S^*S^?S^^
__j^J
94.0
112.0
95.0
94.0
91.0
101.0
98.0
102.0
96.0
fe?^^AWfi^':^S^Aiifiii:iii^:ii
104.0
105.0
94.0
101.0
95.0
111.0
98.0
85.0
"^Tostxf*"
103.0
93.0
101.0
95.0
*&V&-tt'<^:-ysf:&A-tt-toSZ-&.#<&v
103.0
105.0
99.0
102.0
96.0
91.0
88.0
98.0
"SliW^iiSS:^.^^.^^^::;:"
100.0
104.0
89.0
Res. 2
108.0
102.0
100.0
104.0
$$m$m88$m$m
t%^feSi?:^^lw^
95.0
94.0
124.0
5:ffi^HS&^::::-:^::;AW
97.0
94.0
94.0
108.0
97.0
102.0
96.0
&f»»JS:S:$$iJSi^fc&&:
97.0
106.0
94.0
103.0
100.0
109.0
105.0
91.0
104.0
101.0
96.0
100.0
97.0
99.0
107.0
100.0
103.0
98.0
92.0
94.0
101.0
^S^SSfitjKSSSS^S^iS:!
ii^^iSiHl
166.0
104.0
99.0
Res. 3
107.0
97.0
94.0
93.0
'^wmsss-s?^^^^^'
^S^^M^S^jiii!!^^^
95.0
94.0
110.0
-— __
94.0
93.0
103.0
96.0
103.0
96.0
93.0
104.0
94.0
101.0
91.0
103.0
98.0
97.0
'"""96.6"""
105.0
98.0
98.0
94.0
^^i'.SS^^iJ:^.?^'''^^:'^^^
102.0
104.0
100.0
101.0
100.0
97.0
93.0
98.0
166.6
101.0
'S8S?«!W^55i^KiS^SSV
|Si||gs^gS4«^**s||i
90.0
• s No data submitted
0 =
Insufficient
data
vy »—
Exper.
Sigma
1.00
2.89
3.46
5.51
3®$$8m3m?$®$$g
^&m$3$&m$#m£t?f
0.00
0.00
7.57
2.66
0.00
1.53
3.61
1.00
0.58
0.00
""""' "5.57"
1.00
0.00
1.15
4.51
4.16
4.04
6.00
rajS^^SiM^KST-Si'i?:?:
silmifeSlliPHh?
il^^^iii
4.36
2.00
2.52
1.53
1.53
2J08'
1.53
0.58
1.00
2.00
3.21
3.21
1.73
$&ffiy$£if&^f£ffiv$8$$
i^^Bin^^^
0.00
1.73
_,__
Rnganal
(R + SR)
0.236
0.591
0.709
1.570
^S^Wt^^tSSWSKl??
.___*,.
0.000
2.245 _v<
^S'i^iiiii^ft^^^
'^473"
0.000
0.354
0.827
0.236
0.118
0.000
^;|PII§^^p^^^||f^ixtli|
1.570
0.236
0.000
0.236
1.120
0.945
0.827
^JL.795^..
"6'.945
0.473
0.591
0.354
0.354
0.473
0.354
0.118
0.236
0.473
0.709
0.709
0.354
0.000
^jH5,!-,^
jii^^^ii^pS;^^:^^^^^^^^
L345
Normalized deviation
Average
107.00
100.33
98.00
98.67
^MiSS^IllSSf
„„,_,„„.„
94.00
115.33
97.66
94.00
92.67
104.00
97.00
102.33
__96.00v m
98.00
105.00
94.00
101.67
95.33
107.67
100.33
91.00
101.00
103.00
95.67
99.67
95.33
101.33
105.33
99.67
102.00
98.00
93.33
91.67
99.00
IlllHstfllliltll
100.00
103.00
Hli;H!ifB!S!til
"92.67
TAG SYMBOLS
Determined to be an outlier
(grand-avg) (known) Tag
3.43
1.12
0.31
0.54
^^^^^^^i^|;;^^||||
~a73
-1.08
6.31
'"""x"-6.64
-1.08
-1.54
2.39
-0.04
1.81
-0.38
i^Si^^^^^S
^^^iiS^^^S^S^^^M^
0.31
2.73
-1.08
1.58
-0.61
3.66
1.12
-2.12
.._.,,.._...,
2.04
-0.50
0.89
_-0-61,
'"""V""T46
2.85
0.89
1.70
0.31
-1.31
-1.88
_0&5__
^p-i^^^^i^^^i^-ili^il^:-
1.00
2.04
<&%$$&&¥:^ffi%&%$$3f$:$3'
t^^i^^^^^^£^^^^
-L54
ft s Above
U s Below
0.69
-1.62
-2.42
-2.19
^S^i^^j^SiJ^^^W^SMx;
•$$}^^&&s&rkw&^®$-&
-3.46 Jl
-3.81 11
3.58 ft
"-i??"
-3.81 II
-4.27 U
-0.35
-2.77
-0.92
JUL-.JL-
"-2A2
0.00
-3.81 U
-1.15
-3.35 U
0.92
-1.62
-4.85 U
i^^s^lli^^l^i
i^^ft^PIP:^i|!»pS!
-1.39
-0.69
-3.23 U
-1.85
JMto_J^^
"-L2T
0.12
-1.85
-1.04
-2.42
-4.04 li
-4.62 11
-2.08
^^^^vf^^'^'yfiM:'%'i^ff}i^
liillllffl llllll
""-i/i3
-0.69
•™^Kfff^^^ft^.^^f^^^ftf
''&$£&^$$w?$$s$ ^-f->^-9Jf^K^:
-4.27 Ji
control limit
control limit
-------
ESD-LV Performance Evaluation: Gamma in Water, 6-Nov-1998
19/37
Cesium-134
Lab Res. 1
Exper. Rng anal Normalized deviation
Res. 2 Res. 3 Sigma (R + SR) Average (grand-avg) (known) Tag
FE
FJ
FL
sss
Sf?fts
GL
GQ
HE
ffl
HK
HL
JE
JG
JM
JS
JY
K
KH
KL
KX
L
LE
LF
LR
M
MP
MT
MV
M. * i-
PWP
N
NH
NJ
Sp
NO
NP
O
97.0
94.0
98.0
90.
108
108
93
100
102
110.0
93.0
96.0
"89.0
108.0
107.0
94.0
98.0
98.0
94.0
94.0
96.0
^'/''Vlx
^v^l
85.6
108.0
106.0
96.0
101.0
101.0
8.50
0.58
1.15
2.695
0.118
0.236
100.33
93.67
96.67
^v;s^?^^SS:
1.12
-1.19
-0.15
-1.62
-3.93
2.89
2.65
0.00
1.00
1.53
1.53
2.08
0.591
0.000
0.236
0.354
0.354
0.473
88.00
108.00
107.00
94.33
99.67
100.33
-3.15
3.77
3.43
-0.96
0.89
1.12
-5.89
1.04
0.69
-3.70
-1.85
-1.62
101.
108.
90.
99.
92.
101.
84.
98.
101
97
106
100
91
97
97
91
ioa
99
90
93.
'fr'&WSSJ*
rail
99,
90,
99.
97.0
113.0
91.0
100.0
92.0
103.0
83.0
102.0
100.0
97.0
104.0
110.0
88.0
96.0
93.0
93.0
10LO
101.0
91.0
92.0
105.0
88.0
99.0
100.0
111.0
89.0
98.0
91.0
102.0
84.0
96.0
100.0
99.0
116.0
99.0
96.0
96.0
96.0
94.0
97.0
351
100.0
89.0
91.0
^.•rf\\ vtv"1 \ "*
If*- *\^
ilLO
100.0
100.0
2.08
2.52
1.00
1.00
0.58
1.00
0.58
3.06
0.58
1.15
6.43
6.08
4.04
0.58
2.08
1.53
2.08
»*3-Wa>,^-^ >iP^,-;
105.00
92.67
99.33
0.77
4.70
-2.46
0.66
-1.88
1.70
-4.66
0.54
1.12
0.19
4.00
2.04
-1.88
-0.27
-0.61
-1.54
•HL
!^:fll
1.00
-2.46
-1.77
KWMMVWMW?
!$iPV
2.73
-1.54
0.77
-1.96
1.96
-5.20
-2.08
-4.62
-1.04
-7.39
-2.19
-1.62
-2.54
1.27
-0.69
-4.62
-3.00
-3.35
-4.27
-1.96
i2Ql4l
-1.73
-5.20
-4.50
rj^-T"
^;A>
0.00
-4.27
-1.96
li
!::>^
li
II
li
"'X "
',<•:
II
• & No data submitted
0 = Insufficient data
TAG SYMBOLS
Determined to be an outlier
ft s Above control limit
•H s Below control limit
-------
20/37
ESD-LV Performance Evaluation: Gamma in Water,
Cesium-134
Lab
PD
^JKEk
PM
PW
PX
JU
'|QM:
QP
QT
QU
QW
QX
QZ
R
RK
RO
?Wn'J
*"••**',
••^ V^V'T
!'. XV U
RX
RZ
s
SD
SF
SI
SM
SN
SR
ss
sv
sx
T
TC
TD
•y. p. -., A
TTfo
v. ^\ii
TO
TQ
TR
TW
U
:UM
UP
JUR
uv
ux
'W-
Res. 1
_ 96.0
i^v^CWI^!
90.0
93.0
106.0
_ ^87.0
^f^ff-Q
101.0
97.0
95.0
96.0
97.0
90.0
98.0
96.0
96.0
IfSSil
't ^ •• * t'.'f'^'-f jf ^
x/%^ - '*V"S'-"
102.0
111.0
96.0
91.0
82.0
104.0
90.0
98.0
97.0
105.0
83.0
100.0
99.0
78.0
88.0
rr*1^ *?y "^f
•f.fff. tXv&]§£i?.\
98.0
95.0
88.0
103.0
103.0
,;; r:^K
97.0
V?,;'?-^
85.0
98.0
^V-f.' "\-W' "• ^
Res. 2
98.0
^VfJV. ^ •kWM^«MM4M«¥"}»O y/.-fl.'A.'A^
y *V?' *•. A > W ^Tf^-sV'-* *
94.0
96.0
107.0
91.0
'| , 5? ^ ' * -^ ' '* , s V* \^s / "^0'^?
11 V •sV 's '' '.•' «oAixC^' >
^f** . ^xV^iT^
101.0
112.0
97.0
88.0
84.0
110.0
88.0
95.0
99.0
103.0
85.0
100.0
93.0
79.0
101.0
f**ttJffS s VA s "^t ^'vv* v^' ?*** v
*' ^ ^v\v'A?<*Cisl--^''w
S "•"'*£ jiv.ff <. N**-«?A*%S%W
123.0
93.0
89.0
94.0
102.0
;;' ;j^x^"\'^
^98.0
^ •; , -,&„{• >%-x'^
87.0
88.0
d-.,- ^'^.^^ftS
Res. 3
93.0
ri^^i^r
~91.0
93.0
110.0
93.0
109.0
96.0
99.0
98.0
95.0
91.0
98.0
91.0
93.0
Vjt^KKJ
1 ^V'" "•'*'«?•'' '/%"\
*i''>\'i>v ^' * •, j~-V'f 't*
/"jf ^l^t N*^%jr^,%
103.0 "
114.0
97.0
87.0
81.0
98.0
89.0
106.0
96.0
104.0
82.0
102.0
95.0
75.0
100.0
WAV^W^VAVM fffftf V^VA
OiM S''^ J1 * V'V '
V s''*' ^ SSVrt l^l'-' >
113.0
88.0
90.0
104.0
103.0
;^>7f§,«'^y
99.0
'""v^^g
93.0
90.0
Exper.
Rnganal
Sigma (R + SR) Average
,_JS
^v-fW^^;-;:V^
2.08
1.73
2.08
^^3.06^^
^P-3;b'S^ '
4.04
1.00
2.00
1.00
1.15
1.53
1.15
5.51
1.73
^&vs:.'>~-
'\^ s \V ' .. J "* *" * /^ <
, V f,* ^"^ <, ^ s /
" -' S'SVjV \ '
£00
1.53
0.58
2.08
1.53
6.00
1.00
5.69
1.53
1.00
1.53
1.15
3.06
2.08
__J.23
V.*1" /* '-.<-.•.' •.
12.58
3.61
1.00
5.51
0.58
•'T-r^vr^'^'
1.00
"v^^*'^
4.16
5.29
J0.691
s^^.'^r,*1
0.473
0.354
0.473
^0.709_
TToTOs"
0.945
0.236
0.473
0.236
0.236
0.354
0.236
1.570
0.354
'"'f^^'l
-. -f* ffjS" ^^
"~*f X"*^ ^'i^
.-^"-'''V^'X^"
0.236
0.354
0.118
0.473
0.354
1.795
0.236
1.570
0.354
0.236
0.354
0.236
0.709
0.473
2.020
"• ff ^"-ffffff.ff.
# yfy$yt*Z$ff
•. '"• -.-. '*-.
4.721
0.827
0.236
1.345
0.11£
•^^r
0.236
r^^i:;
0.945
1.345
C^x ,-L ' <• ;Vvv ,' -,^ 'St.« , - - ;: •$•:; -'^
• s No data submitted
0 s
Insufficient data
X S
_?5.67v
^7'i;"v«',l^Vr
91.67
94.00
107.67
90.33
^;V7"/,<7^|Q0*
104.67
96.00
97.00
97.00
96.33
91.33
98.67
90.67
94.00
^s!'^'
102.00
112.33
96.67
88.67
82.33
104.00
89.00
99.67
97.33
104.00
83.33
100.67
95.67
77.33
96.33
w. *,,*.„ ^ y.gfp.#&. ^w
'fy'^',,'. ^*\ ^1--!;,
x * •" f\ -. \ X ff. •.
111.33
92.00
89.00
100.33
JL02.67
-\"VXr"' •*•
98.00
;^V-vT ';^1\
88.33
92.00
/', j i/fy \-> •• ' v •.
TAG SYMBOLS
Determined
to be an
outlier
6-Nov-1998
]
Normalized deviation
(grand-avg) (known)
_ -0.50
'Sv^^S-,,"^- :
-1.88
-1.08
3.66
_ _-2.35
•3-^v<^gj§5^y "*?'». !
2.62
-0.38
-0.04
-0.04
-0.27
-2.00
0.54
-2.23
^08, __
;' " * ' *•.'' f* ;> $ ?•$< '' * ""' •.'
?• ^ t\ * "• *$• X^v"" %" * '^ %
f "' ^ ' * f "• \ x<«<^'' % sv f^
'"'V;Y ' "^'"' ' f ' "v" *
1.70
5.27
-0.15
-2.92
-5.12
2.39
-2.81
0.89
0.08
2.39
-4.77
1.23
-0.50
-6.85
-0.27
ffffl, yt^tT-rgfft.rtfttHprf.'Mpip. f ssv v
^.'VtA x y<^V-;"^ '^\^
•. *• \ •,•'•. J\*' w ^% %X % %
4.93
-1.77
-2.81
1.12
1.93
'3$'M^~;- "?^,
0.31
;„'"; ~'^ ".,? * v ^ ~-~^-\ ;-
'•'•""„ •" -'''y^iC'''^ •-' -\
-3^04
-1.77
':r:S->£^A-''-
ft H Above
Jl = Below
-3.23
^J'^y,:-";"1
-462
-3.81
0.92
/5-CMr
^lOifi™"
-612
-3.12
-2.77
-2.77
-3.00
-4.73
-2.19
-4.97
-3.81
vr^p^-j
^ ff f %£?&'
'•."• ' ' J *'Sv> ^C '^
^ 5^^x
-1.04
2.54
-2.89
-5.66
-7.85
-0.35
-5.54
-1.85
-2.66
-0.35
-7.51
-1.50
-3.23
-9.58
-3.00
VA f^vvffff, rrf.tr
\l "^' ^ ,
* ^
2.19
-4.50
-5.54
-1.62
-0.81
"-."^ T^
-2.42
' •. ** f^M "w '
-5.77
-4.50
"'-'/^*
control
control
Tag
Jl
"/TV*"?
'T
ji
...L.
SI x^>
Jl
Jl
Jl
H
V^'-^7
•T"1 4 "*'•, '' ^
,- , ,• - \ \
Jl
Jl
Jl
Jl
Jl
Jl
ff.rttt-.tf£tf
' 4 9 ',
Jl
Jl
• '"•'
' •
T
Jl
„, *„
limit
limit
-------
ESD-LV Performance Evaluation: Gamma in Water, 6-Nov-1998
21/37
Cesium-134
Lab Res. 1
Exper. Rng anal Normalized deviation
Res. 2 Res. 3 Sigma (R + SR) Average (grand-avg) (known) Tag
102.0
93.0
101.0
91.0
1030
92.0
97.0
103.0
94.0
99.0
91.0
102.67
93.00
99.00
91.67
-0.81
-4.16
-2.08
-4.62
s x
93.00
93.00
96.00
-
-1.42 -4.16 if"
-1.42 -4.16
-0.38 -3.12
92.0
92.0
94.0
1.00
1.00
2.00
2.00
93.0
93.0
96.0
98.0
96.0
.709
0.354
0.354
94.67
95.67
101.00
3.58
3.23
1.39
0.236
0.000
99.00
94.00
91.00
96.67
0.354
9400
-1.31
j^!i^Iy§9^8T?PS
t •. \Uvss vs i •. ^ ^ , •, 0 „ .•••»•. wsi
-1.08 -3.81
Average
Tag
Data sorted by Laboratory Average
Lab Average Tag Lab | Average
Tag
Lab
46.00
50.00
74.00
77.33
82.33
83.33
83.67
83.67
88.00
88.33
88.67
x
x
X
II
li
U
MX
CX
QM
TC
SF
sv
p
KH
GL
UV
SD
89.00
89.00
90.00
90.00
90.00
90.33
90.67
91.00
91.00
91.33
91.67
u
u
TR
SM
OT
NH
JM
Q
RK
XI
CA
QZ
VI
91.67
91.67
91.67
91.67
92.00
92.00
92.00
92.67
92.67
92.67
92.67
li
II
PM
LR
JY
DT
UX
TQ
NJ
NP
MT
EX
AY
• e No data submitted
0 s Insufficient data
TAG SYMBOLS
s Determined to be an outlier
tt s Above control limit
II s Below control limit
-------
22/37
Cesium-134
ESD-LV Performance Evaluation: Gamma
in Water, 6-Nov-1998
Data sorted by Laboratory Average
Average
93.00
93.00
93.00
93.33
93.33
93.67
94.00
94.00
94.00
94.00
94.00
94.00
94.00
94.33
94.67
95.00
95.00
95.00
95.33
95.33
95.33
95.67
95.67
95.67
95.67
96.00
96.00
96.00
96.00
96.33
96.33
96.33
96.33
96.67
Tag
II
II
U
II
U
II
II
U
II
II
II
II
II
II
II
U
II
II
II
II
II
II
II
II
II
II
II
II
II
% responding labs
II -• •
° -'6
I_^__
L1
Lab
VS
vo
VE
XT
DR
FJ
Y
XF
RO
PW
BL
AW
AK
m
X
ww
I
AJ
MP
CS
BN
XA
T
PD
CO
WD
W
QT
BC
WR
TD
QX
M
XK
Average Tag
96.67
96.67
97.00
97.00
97.00
97.00
97.33
97.67
98.00
98.00
98.00
98.00
98.33
98.67
98.67
98.67
99.00
99.00
99.00
99.00
99.00
99.33
99.33
99.33
99.67
99.67
99.67
99.67
100.00
100.00
100.33
100.33
100.33
100.33
Frequency distribution
l.llil.
i.TH-.i... •_
"4 -'2 ' 6
Lab
S
FL
QW
QU
BA
AU
SR
L
UP
DO
BH
AF
IU
R
KL
AH
XD
VB
OM
JS
E
0
MV
JE
SN
HK
DE
CP
N
EB
TW
KX
HL
FE
Average Tag
100.33
100.33
100.67
101.00
101.00
101.33
101.67
102.00
102.00
102.00
102.33
102.67
102.67
103.00
103.00
103.00
104.00
104.00
104.00
104.67
105.00
105.00
105.33
107.00
107.00
107.67
107.67
108.00
108.67
110.67
111.33
112.33
115.33 ft
190.33 x
1242.00 x
V2 ' +4
Lab
C
AE
sx
XB
CE
D
BM
RX
K
DH
BB
VC
U
LF
EL
CJ
ss
SI
AZ
QP
NO
BK
DD
HE
A
PX
BO
GQ
LE
JG
TO
RZ
AL
OA
XU
m
+6
Normalized deviation of the mean from the known value
• = No data submitted
0 s Insufficient data
TAG SYMBOLS ft s Above control
x = Determined to be an outlier II = Below control
limit
limit
-------
ESD-LV Performance Evaluation: Gamma in Water, 6-Nov-1998 23/37
Cesium-134
% responding labs Frequency distribution
OJ»r
-6 ' -4 -20 +2 " +4 " +6
Normalized deviation of the mean from the grand average
-------
ESD-LV Performance Evaluation: Gamma in Water, 6-Nov-1998
24/37
Cesium-137 Statistical Summary 166 Participants
The known value of this nuclide is 111.0 pCi/1 with an expected precision of 6.0; the control limits
are 100.6 to 121.4; the warning regions are 100.6 to 104.1 and 117.9 to 121.4
29(17.5 %) Failed to respond .%
7(4.2 %) Outliers •
11 (6.6 %) Out of control'
but not an outlier
Statistic
98(59.0 %) Within all limits
Respondents
• 21(12.7 %) In warning zone
but within control
Non-outliers
Mean
Std. Dev.
Variance
%Coef. ofVar.
% deviation of mean from known value
Norm. dev. of mean from known value
Median
% deviation of median from known value
Norm. dev. of median from known value
129.91 Grand Avg 113.38
190.93 5.42
36455.89 29.43
146.97 4.78
17.04 2.15
0.10 0.44
113.33 113.33
2.10 2.10
0.01 0.43
18(13.1 %) More than 3 norm. S.D.
21 (15.3 %) Between 2 and 3 norm. S.D. •
,65(47.4 %) Within 1 norm. S.D.
of known value
•33(24.1 %) Between 1 and 2 norm. S.D.
-------
25 / 37 ESD-LV Performance
Evaluation: Gamma in Water, 6-Nov-1998
;N
Cesium-137
Exper. Rng anal
Lab
A
AE
AF
AH
ll|i|pil
::*.^s£.&j$&
,,_.
AK
i^tfS'WSfiwsftjsj'
•i&B^iiSi
$$&§ir&§$
:;|8fluEf;||
,„_
AW
AY
AZ
BA
BB
BC
wgstfftS&yf'S®'
BH
BK
BL
BM
BN
BO
C
CA
mzrm®
CE
CJ
CO
CP
CS
D
DD
DE
DH
DO
DR
DT
E
'"TEL"'
«:•:•:::»:*•-••:•:*••:•,
llf§tji^l
„,.
• =
0 B
Res. 1
115.0
114.0
122.0
107.0
120.0*
110.0
^$ffit$ft$®SS$$ffff&fi%&p§!3f$f'fffi'.
___
112.0
96.0
111.0
110.0
114.0
112.0
^f^f^S^S^^^f^&^f^
119.6
123.0
109.0
112.0
122.0
113.0
100.0
103.0
123.0
114.0
117.0
111.0
112.0
112.0
123.0
113.0
113.0
118.0
112.0
116.0
^JLU-O^,
113.0
&#$&$&^<&$®&$t%&&3$.
mo"
Res. 2
116.0
115.0
114.0
120.0
""i25!b
^ J1LO_
i^i^ii^^g^i^S^:^^^^:
:;$£|Pp$i;g«p»
SK^^^ii^^^^P^
._„_
112.0
96.0
108.0
103.0
114.0
113.0
^i^^p^JSg^^^SS^S'!!
""•""•120.0
125.0
104.0
111.0
116.0
112.0
110.0
113.0
SSPisSiiMiS**
*i2o;or~"
115.0
113.0
116.0
^M&O^
nib
119.0
114.0
111.0
117.0
114.0
114.0
117.0
iitililililiiil|ipli
111.0
yv.^.^:fltyft^^^^::wMW5W'KJ'(£
^MMtaiw
^feSSiiiiStigl®
111.0
106.0
103.0
106.0
110.0
107.0
113.0
t^SSl-^SJ'iJSSSSJ^SSS!^
120.0
125.0
110.0
113.0
121.0
112.0
100.0
113.0
118.0
117.0
118.0
114.0
114.0
106.0
121.0
114.0
112.0
113.0
113.0
119.0
119.0
[ 'ifMuT
ibib
No data submitted
Insufficient
data
X =
Sigma (R
1.00
0.58
4.00
6.81
^Zfig'"""*""""
0.58
$¥ffi^#«ffiWK8S^*A^^
«tW»Wi«»Piifci'
1.00
3.46
4.04
2.52
4.04
4.04
0.58
<$^$3^^$^$$^$$$$'$&$if
.,,,,.,,,^._
1.15
3.21
1.00
3.21
0.58
5.77
.,.^~.$J!L~~W..
*"'"""2sz"* ~
1.53
2.65
2.52
^m^1.15^_
^,..,,,,,^,^.,...,,,,.,,
2.00
0.58
1.00
2.65
1.00
2.52
,,,.,^.|.2..,,r,^
^^^iisi^^^^^i^i^^:^pi^
^^ii^^M^S^ifeww^^Jl^Siiiii
"""sLob"
2.65
+ SR)
0.197
0.098
0.788
1.533 _ _
Ki^^^iillli
0.492
0..098
«slSsllil*H
•SKiSSwKWwxfei^wisJi'iW
0.197
0.591
0.689
0.492
0.689
0.689
0.098
Sw^':¥:$SS:$feS:$S-:^:;Sx$:
0.098
0.197
0.591
0.197
0.591
0.098
0.984
0.984
0.492
0.295
0.492
0.492
p.l97__
b".691
0.394
0.098
0.197
0.492
0.197
0.492
0.492
0.394
•$$&$li$$8$$ffi$$&$&
a492
Average
116.00
114.67
118.00
114.67
122.00
JL10.67
sssl^i^sftiSpisI
S^Ss*®S5!S5igKS
112.00
110.00
98.33
108.33
107.67
111.67
112.67
^^SWft^r-S^iWWSSft*:?
119.67
124.33
107.67
112.00
119.67
112.33
103.33
109.67
__™«
115.33
116.00
113.67
,,J12.6.L,.
109.67
121.00
113.67
112.00
116.00
113.00
116.33
116.67
111.00
4^«^^^«Sft^wsffiSS¥j:rv
101.00
TAG SYMBOLS
Determined to
be an outlier
Normalized deviation
(grand-avg) (known) Tag
0.76
0.37
1.33
0.37 '
R^^^PI^pl^^^ffil
liii^lS^^S;!
2.49
-0.78
SJWJWffflSSS^ft^W^yfti^Jt-S^j^Wft
^^;^^ii^^pi^^^il|l;iili
M^i^^i^liil^
-bib* '
-0.98
-4.34
-1.46
-1.65
-0.50
-0.21
1.81
3.16
-1.65
-0.40
1.81
-0.30
-2.90
-1.07
^i:^:;^g^^^^^^A;;:.:.:.^
2.01
0.56
0.76
0.08
_^-0.21^^^
-1.0?
2.20
0.08
-0.40
0.76
-0.11
0.85
0.95
ISS^^iiS^i^SKH'ii^^SiiiiSiiiiij
^S&S:&:W:$f:&"
-0^69
^&$^#i&%!&sffffffffff!tjiptaxttffi$
-3.57
ft s Above
U s Below
1.44
1.06
2.02
_J.06_^_
^^iii^^^:|^^::li^i^*^?i^-i^
"'"3.18 ft""""
j:°^>xt$*;£: *««.:«*x- *:•;«•:•:•: :•:•:•:•;•:•:•:•:•:-: :•:
-2.89
control limit
control limit
-------
ESD-LV Performance Evaluation: Gamma in Water, 6-Nov-1998
26/37
Cesium-137
Lab
Res. 1 Res. 2
Exper. Rng anal Normalized deviation
Res. 3 Sigma (R + SR) Average (grand-avg) (known) Tag
GL
GQ
HE
m
HK
HL
JE
JG
JM
JS
JY
K
KH
KL
KX
L
LF
LR
M
MP
MT
MV
108.0
111.0
109.0
121.0
119.0
117.0
117.0
107.0
116.0
114.0
116.0
114.0
115.0
115.0
112.0
120.0
109.0
119.0
117.0
110.0
126.0
109.0
108.0
111.0
109.0
115.0
109.0
108.0
113.0
110.0
118.0
112.0
0.58
0.00
1.15
0.58
3.00
4.04
0.000
0.197
0.098
0.591
0.689
109.33
108.00
111.67
109.33
118.00
116.67
-1.17
-1.55
-0.50
-1.17
1.33
0.95
114.0
136.0
108.0
115.0
117.0
120.0
111.0
116.0
117.0
111.0
115.0
119.0
111.0
112.0
116.0
121.0
114.0
118.0
115.0
111.0
110.0
108.0
118.0
106.0
111.0
122.0
119.0
119.0
118.0
111.0
116.0
1.53
10.44
2.08
2.08
1.53
2.65
1.73
1.53
1.15
0.58
5.77
6.08
0.58
6.66
0.58
5.03
0.295
2.658
0.394
0.394
0.295
0.492
0.295
0.295
0.197
0.098
0.984
1.158
0.098
1.345
0.098
0.984
115.33
124.00
108.67
114.33
115.67
119.00
113.00
116.33
115.67
111.33_
116.67
112.00
118.67
113.67
110.67
121.33
0.56
3.07
-1.36
0.27
0.66
1.62
-0.11
0.85
0.66
-0.59
iPff;
6.95
-0.40
1.53
0.08
-0.78
2.30
-0.48
-0.87
0.19
-0.48
2.02
1.64
1.25
3.75
-0.67
0.96
1.35
2.31
0.58
1.54
1.35
0.10
1.64
0.29
2.21
0.77
-0.10
2.98
IT
N
NH
NJ
NO
NP
JO
OB
OM
OT
P
110.0
110.0
114.0
119.0
108.0
41L9.0
12^1.6
116.0
120.0
117.0
114.0
109.0
111.0
115.0
110.0
117.0
2.65
0.58
3.00
0.492
0.098
113.00
109.67
114.00
-0.11
-1.07
0.18
123.0
108.0
J19.0
"ll4.0
120.0
99.0
93.0
127.0
117.0
118.0
Pg289l«
113.0
122.0
114.0
95.0
4.00
6.20
0.58
1.53
1.15
9.64
3.06
0.788
0.886
0.098^
6.295
0.197
2.470
0.591
123.00
111.00
118.67
^Spl
114.33
120.67
110.00
95.67
2.78
-0.69
,M5L
0.27
2.10
-0.98
-5.11
0.58
-0.38
0.87
3.46
0.00
2.21
J4;83"
0.96
2.79
-0.29
-4.43
• s No data submitted
0 = Insufficient data
TAG SYMBOLS
x e Determined to be an outlier
ft s Above control limit
JJ s Below control limit
-------
27 /
37 ESD-LV Performance
Evaluation: Gamma
in Water,
6-Nov-1998
Cesium-137
Lab
PD
%#X&fW!yM£
,.„..
PW
PX
Q
QM
QP
QT
QU
QW
QX
QZ
R
RK
RO
SiSpsw^t
am
RX
RZ
S
SD
SF
SI
SM
SN
SR
ss
sv
sx
T
TC
TD
Res. 1
_^ JL18.0 _
i^^^M^^^ptfli
__„.
111.0
106.0
106.0
97.0
113.0
107.0
110.0
113.0
115.0
111.0
120.0
116.0
119.0
iliBltiillliPlllpl
"imP
127.0
111.0
106.0
101.0
122.0
112.0
113.0
106.0
118.0
108.0
119.0
106.0
109.0
110.0
^^W^^^W^^^^^^^^1
iwi^lxK^S!
TO
TQ
TR
TW
U
in
UP
waul
uv
ux
<3iT:Ti&<
Sj»Ms*iB;
• =
0 B
ipHlipiiliiiiS
™ ^^f*™
115.0
111.0
114.0
115.0
112.0
UllllPlllSipiiiS
105.0
112.0
Res. 2
J20.0
,,,,,,_..
110.0
108.0
105.0
105.0
112.0
109.0
110.0
108.0
116.0
114.0
119.0
102.0
119.0
~^113.6~
121.0
110.0
109.0
101.0
127.0
114.0
117.0
110.0
123.0
105.0
136.0
106.0
110.0
110.0
&^$$$?&$$:$f?f££&
128.0
114.0
109.0
113.0
115.0
"^^fffSf^fffffff-^Xf^fS&i
__114.0
103.0
113.0
'•Q-Z.-MfftySZ&itt^g&X
Res. 3
116.0
117.0
111.0
107.0
107.0
101.0
116.0
114.0
112.0
109.0
115.0
114.0
119.0
110.0
114.0
lill^^SsS'i^il&i^ipl
"ll'slT"
123.0
112.0
111.0
104.0
116.0
118.0
117.0
107.0
120.0
100.0
112.0
104.0
108.0
116.0
lil|illltlilllill|
'<""""'l27j"1"
117.0
101.0
117.0
116.0
115.0
^^v^^^^^^S^ffl^J^
105.6""
^J01.0_
No data submitted
Insufficient
data
X s
Exper.
Sigma
rw_2-00^
'"3.79"
0.58
1.00
1.00
4.00
2.08
3.61
1.15
2.65
0.58
1.73
0.58
7.02
2.89
lllllSlilll
;^^-LS¥SxS5?i^:^:^;^^^:^^iS^
ifS^wi^S^^Si^iii^Si^iWi.
0.58
3.06
1.00
2.52
1.73
5.51
3.06
2.31
2.08
2.52
4.04
12.34
1.15
1.00
3.46
_,,,.
1.53
5.29
2.08
_^J;B8_
i!^^^&S^^S::5i:M^§^
"""1.53
" 1~15'*"
6.66
S»w*iS§isssS;iisl8!
Rnganal
(R + SR)
_Jg^9jL»
„.„__...„
0.098
0.197
0.197
0.788
0.394
0.689
0.197
0.492
0.098
0.295
0.098
1.720
0.492
§ft;H!lMiS*i|lii
0.098
0.591
0.197
0.492
0.295
1.158
0.591
0.394
0.394
0.492
0.788
3.596
0.197
0.197
_J).591_
0.886
0.295
0.984
0.394
_JW9|_
_^^0.295
0.197
1.345
li^B^ii^S
Jisi§ltei|felilili^lsg
Normalized deviation
Average
1JL8.00_
IllllSlllltlllli!
""""112.67
110.67
107.00
106.00
101.00
113.67
110.00
110.67
110.00
115.33
113.00
119.33
109.33
117.33
Ip^lIpSillliilii
l|illll!illilil
112.67
123.67
111.00
108.67
102.00
121.67
114.67
115.67
107.67
120.33
104.33
122.33
105.33
109.00
112.00
iplili^lH
124.67
115.33
107.00
114.67
_JL16.32^
113.67
IIIIIIPIIIIII
J^|iS!5^||;^SgS|i;;^
104.33
^J.08.67
i^f^f^^ffi^f!i^«^fw<^ff^
TAG SYMBOLS
Determined
to be an outlier
(grand-avg) (known) Tag
,.^_Ji,,
._
-0.78
-1.84
-2.13
-3.57
0.08
-0.98
-0.78
-0.98
0.56
-0.11
1.72
-1.17
1.14
-6.21"
2.97
-0.69
-1.36
-3.29
2.39
0.37
0.66
-1.65
2.01
-2.61
2.58
-2.32
-1.26
-0.40
3.26
0.56
-1.84
0.37
0.56__
ISpi^^ii^^ftiUliS
.........._._....
"-2L61
-1.36 __
^iftfessifcllffll^Pl^B'
tt s Above
U s Below
JMKZ^
QA8
-0.10
-1.15
-1.44
-2.89
0.77
-0.29
-0.10
-0.29
1.25
0.58
2.41
-0.48 '
1.83
fm%m$!Wemi
-------
ESD-LV Performance Evaluation: Gamma in Water, 6-Nov-1998
28/37
Cesium-137
Lab Res. 1
Exper. Rng anal
Res. 2 Res. 3 Sigma (R + SR)
Normalized deviation
Average (grand-avg) (known) Tag
VC
VE
VH
VI
¥« XJ"^«
SHU
vo
vs
w
WD
118.0
110.0
121.0
118.0
?:ilk€\d
107.0
108.0
112.0
117.0
117.0
111.0
119.0
116.0
J^IS-'y-l
116.0
109.0
116.0
115.0
118.
108.
122.
115.
*^K
-^
118.
109
112.
116
0.58
1.53
1.53
1.53
t'^fpss
536
0.58
2.31
1.00
0.098
0.295
0.295
0.295
K-^-;^-"
^»>>*x;-
vv.1- *v,^ ^ •.
1.158
0.098
0.394
0.197
117.67
109.67
120.67
116.33
^^•s^^ r^5^
-- ? -!>.<.$««; -~ —?xj> » ;•,*-;; -,^!«»",x^-^
2.08 0.394 115.67 6.66
120.33
111.67
110.33
117.00
110.67
£!^^;*y>x:; ;<$$&••
110.00 -0.98
126.00 3.64
0.38
2.01
-0.50
-0.88
1.04
-0.78
1.35
2.69
0.19
-0.19
1.73
-0.10^
^i;-^M^
-0.29
«^J*:,3.^. ^
113.0
108.0
109.0
2.65-
0.492
-0.29
Average
Tag
Data sorted by Laboratory Average
Lab \ Average Tag Lab \ Average
Tag
Lab
55.33
59.00
93.67
95.67
98.33
101.00
101.00
102.00
103.33
104.33
104.33
x
x
X
u
MX
CX
AL
P
AY
QM
EX
SF
C
sv
105.33
106.00
107.00
107.00
107.67
107.67
107.67
108.00
108.33
108.67
108.67
T
Q
TR
PX
SR
BL
BA
GQ
AZ
VS
ux
108.67
108.67
109.00
109.33
109.33
109.33
109.67
109.67
109.67
109.67
110.00
SD
JM
TC
RK
HI
GL
VE
NH
D
CA
Y
• s No data submitted
0 = Insufficient data
TAG SYMBOLS
x s Determined to be an outlier
ft s Above control limit
II = Below control limit
-------
29/37 ESD-LV Performance Evaluation: Gamma
..
Cesium-137
in Water, 6 -No v- 19 98
Data sorted by Laboratory Average
Average Tag
110.00
110.00
110.00
110.00
110.00
110.00
110.33
110.67
110.67
110.67
110.67
110.67
111.00
111.00
111.00
111.33
111.67
111.67
111.67
112.00
112.00
112.00
112.00
112.00
112.33
112.33
112.67
112.67
112.67
112.67
113.00
113.00
113.00
113.00
% responding labs
Lab
XI
QW
QT
OT
FJ
AW
XB
XF
QU
PW
MT
AK
S
NP
EL
L
XA
HE
BB
TD
LR
DH
BM
AU
WR
BO
RX
PM
CS
BC
QZ
N
KH
DR
Average Tag
113.33
113.33
113.67
113.67
113.67
113.67
113.67
113.67
113.67
114.00
114.00
114.33
114.33
114.67
114.67
114.67
114.67
115.33
115.33
115.33
115.33
115.33
115.67
115.67
115.67
115.67
116.00
116.00
116.00
116.00
116.33
116.33
116.33
116.67
116.67
Frequency distribution
Lab
XT
w
VO
UP
QP
MP
I
DE
CP
NJ
IU
OB
JS
TW
SM
AH
AE
U
TQ
QX
JE
CJ
WW
SN
EX
JY
WD
DO
CO
A
VI
EL
DT
LF
HL
Average
116.67
117.00
117.00
117.33
117.67
118.00
118.00
118.00
118.67
118.67
119.00
119.33
119.67
119.67
120.00
120.33
120.33
120.33
120.67
120.67
121.00
121.33
121.67
122.00
122.33
123.00
123.67
124.00
124.33
124.67
126.00
136.33
140.00
231.67
2342.67
Tag
ft
ft
ft
ft
ft
ft
ft
ft
ft
X
X
X
X
Lab
E
XD
FL
RO
VC
PD
HE
AF
0
M
E
R
BN
BH
FE
X
ss
CE
VH
OM
DD
MV
SI
AJ
sx
NO
RZ
JG
BE
TO
XE
LE
EB
OA
XU
° -'6 T -4
. . .•.llllllllll
I T I T
||H|H|H-.
+2
74
n
+6
Normalized deviation of the mean from the known value
• = No data submitted
0 = Insufficient data
TAG SYMBOLS ft
x = Determined to be an outlier It
s Above control
s Below control
limit
limit
-------
ESD-LV Performance Evaluation: Gamma in Water, 6-Nov-1998 30/37
Cesium-137
% responding labs Frequency distribution
10-f
• — -
0-l^T-
-4 -2 6 ' +2 ' *'4 +6
Normalized deviation of the mean from the grand average
-------
ESD-LV Performance Evaluation: Gamma in Water, 6-Nov-1998
31/37
Barium-133 Statistical Summary 166 Participants
The known value of this nuclide is 56.0 pCi/1 with an expected precision of 6.0; the control limits
are 45.6 to 66.4; the warning regions are 45.6 to 49.1 and 62.9 to 66.4
3O(18.1 %) Failed to respond »%^
6(3.6 %) Outliers '
4(2.4 %) Out of control •
but not an outlier
Statistic
. 1O9(65.7 %) Within all limits
Respondents
*• 17(10.2 %) In warning zone
but within control
Non-outliers
Mean
Std. Dev.
Variance
%Coef. ofVar.
% deviation of mean from known value
Norm. dev. of mean from known value
Median
% deviation of median from known value
Norm. dev. of median from known value
72.55
228.21
52079.28
314.55
29.56
0.07
53.67
-4.17
-0.01
Grand Avg 53.11
3.64
13.23
6.85
-5.16
-0.80
53.67
-4.17
-0.64
1O(7.4 %) More than 3 norm. S.D. »w%
17(12.5 %) Between 2 and 3 norm. S.D
7(56.6 %) Within 1 norm. S.D.
of known value
32(23.5 %) Between 1 and 2 norm. S.D.
-------
32 / 37 ESD-LV Performance
Barium-133
Lab Res. 1
A
AE
AF
AJ
AK
^AL^
AU
AW
AY
AZ
BA
BB
TJ^"1
MJ\J
BH
BK
BL
BM
BN
BO
C
CA
CE
CJ
CO
CP
cs
b
DD
DE
DH
DO
DR
DT
E_
EB
EL
'^EW'
EX
• =
0 s
56.0
54.0
53.0
62.0 ^
"49.6"*
51.0
., V,|4-P_,
53.0 ~
54.0
54.0
59.0
51.0
49.0
48.0
"''V4xS^
52.0
55.0
55.0
58.0
53.0
54.0
55.0
~69.6'
46.0
54.0
56.0
57.0
56.0
60.0
55.0
55.0
59.0
53.0
55.0
"l't
58.0
63.0 _
55.0
Res. 2
55.0
57.0
56.0
53.0^
42.6
51.0
^ J*4.p_ .
52.0
52.0
54.0
56.0
49.0
55.0
48.0
VjJS,X. ( V X<. ^W^WfWW W«. •? "•
50.0
50.0
55.0
57.0
57.0
57.0
53.0
55.0
56.0
44.0
57.0
58.0
63.0_
54.0
60.0
56.0
57.0
54.0
57.0
59.0
^ 56.0
58.0
__56.0_
57.0
No data submitted
Insufficient data
Res. 3
53.0
55.0
50.0
,,J60LO_
51.0
51.0
"~ 50.0
53.0
55.0
57.0
46.0
47.0
^j48.0_
"48.0
50.0
55.0
57.0
55.0
48.0
53.0
54.0
k^v*^
57.0
49.0
54.0
57.0
56.0
52.0
57.0
56.0
55.0
61.0
52.0
56.0
55.0
58.0
_J>2J>
56.0
X s
Evaluation: Gamma in Water, 6-Nov-1998
Exper.
Sigma
1.53
1.53
3.00
.4j36....
3.61
0.00
4.04
1.53
1.00
0.58
1.53
2.52
4.16
^_0.00_
5.29
1.15
0.00
1.15
1.53
4.51
0.58
0.58
1.53
2.52
1.73
1.00
2.08
2.00
1.73
0.58
1.15
3.61
2.65
2.08
1.00
0.00
„ Jl-Pj!?. „
1.00
Rng anal Normalized deviation
(R + SR) Average (grand-avg) (known) Tag
0.295
0.295
0.591
0.788m
0.689
0.000
j).689
0.295
0.197
0.098
0.295
0.492
0.788
0.000
6.984
0.197
0.000
0.197
0.295
0.886
0.098
0.098
0.295
0.492
0.295
0.197
?0.394
' ' -fV ^JttK
' "v«^**7v
0.394
0.295
0.098
0.197
0.689
0.492
0.394
_0.197
0.000
0.394
0.197
TAG SYMBOLS
Determined to be an
54.67
55.33
53.00
55.00
45.00
51.00
46.33
51.67
53.00
54.33
57.33
48.67
50.33
J8.W
46.00
50.67
55.00
56.33
56.67
52.67
53.33
54.67
57.33
46.33
55.00
57.00
55.33
54.00
59.00
55.67
55.67
58.00
54.00
56.67
_ 55.00
58.00
53.67
, * •-"'<;'*",:• V-''-V •' *'-/'*^
56.00
outlier
0.45
0.64
-0.03
J).55 __
-2.34
-0.61
w-L96
-0.42
-0.03
0.35
1.22
-1.28
-0.80
j-1.47 ^
-2.05
-0.70
0.55
0.93
1.03
-0.13
0.07
0.45
1.22
-1.96
0.55
1.12
0.64
0.26
1.70
0.74
0.74
1.41
0.26
1.03
JS^L
"L41
^0.16_t _
0.83
ft s Above
li = Below
-0.38
-0.19
-0.87
J).29^_
-3.18 II.
-1.44
-2.79
y f •• >t v « ^y-. < "*/ "
-1.25
-0.87
-0.48
0.38
-2.12
-1.64
j-ML™
-2^89
-1.54
-0.29
0.10
0.19
-0.96
-0.77
-0.38
0.38
-2.79
-0.29
0.29
-0.19
-0.58
0.87
-0.10
-0.10
0.58
-0.58
0.19
0.58
-0.67
0.00
control limit
control limit
-------
ESD-LV Performance Evaluation: Gamma in Water, 6-Nov-1998
33/37
Barium-133
Lab
Res. 1 Res. 2
Res. 3
Exper. Rng anal Normalized deviation
Sigma (R + SR) Average (grand-avg) (known) Tag
FE
FJ
FL
GL
GQ
HE
HI
HK
HL
JE
JG
JM
JS
JY
K
KH
KL
KX
L
LE
LF
LR
M
MP
MT
MV
63.0
61.0
64.0
54.0
58.0
55.0
52.0
53.0
4.93
1.53
2.52
0.886
0.295
0.492
60.67
52.33
55.67
2.18
-0.22
0.74
1.35
-1.06
-0.10
49.0
56.0
56.0
52.0
52.0
56.0
46
56.0
57.0
54.0
51.0
58.0
54.0
56.0
59.0
52.0
52.0
57.0
4.04
0.00
1.53
1.15
0.58
1.00
0.788
0.000
0.295
0.197
0.098
0.197
49.67
56.00
57.33
52.67
51.67
57.00
-0.99
0.83
1.22
-0.13
-0.42
1.12
-1.83
0.00
0.38
-0.96
-1.25
0.29
55.0
56.0
51.0
51.0
57.0
61.0
46.0
51.0
54.0
56.0
61.0
60.0
49.0
52.0
50.0
45.0
55.0
55X)
56.0
52.0
51.0
56.0
59.0
46.0
50.0
54.0
55.0
60.0
61.0
41.0
53.0
44.0
45.0
58.0
55.0
58.0
49.0
50.0
55.0
57.0
48.0
55.0
54.0
54.0
60.0
58.0
48.0
50.0
43.0
45.0
56.0
0.00
1.15
1.53
0.58
1.00
2.00
1.15
2.65
0.00
1.00
0.58
1.53
4.36
1.53
3.79
0.00
1.53
0.000
0.197
0.295
0.098
0.197
0.394
0.197
0.492
0.000
0.197
0.098
0.295
0.788
0.295
0.689
0.000
0.295
55.00
56.67
50.67
50.67
56.00
59.00
46.67
52.00
54.00
55.00
60.33
59.67
46.00
51.67
45.67
45.00
56.33
0.55
1.03
-0.70
-0.70
0.83
1.70
-1.86
-0.32
0.26
0.55
2.09
1.89
-2.05
-0.42
-2.15
-2.34
0.93
-0.29
0.19
-1.54
-1.54
0.00
0.87
-2.69
-1.15
-0.58
-0.29
1.25
1.06
-2.89
-1.25
-2.98
-3.18
0.10
II
N
NH
NO
NP
O
OM
OT
P
56.0
54.0
51.0
56.0
48.0
54.0
54.0
55.0
54.0
54.0
54.0
53.0
1.15
0.58
1.53
.197
0.098
0.295
54.67
54.33
52.67
58.0
48.0
54.0
60.0
53.0
54.0
2.00
2.89
0.00
0.394
0.492
0.000
58.00
49.67
54.00
0.45
0.35
-0.13
1.41
-0.99
0.26
-.38
-0.48
-0.96
0.58
-1.83
-0.58
58.0
51.0
54.0
54.0
48.0
53.0
54.0
39.0
53.0
2.31
6.24
0.58
0.394
1.345
0.098
55.33
46.00
53.33
0.64
-2.05
0.07
-0.19
-2.89
-0.77
• = No data submitted
0 = Insufficient data
TAG SYMBOLS
x = Determined to be an outlier
tt = Above control limit
$ = Below control limit
-------
34/37 ESD-LV Performance
Evaluation: Gamma in Water,
6-Nov-1998
Barium-133
Lab
PD
^•pJg'S
PM
PW
PX
Q
QM
QP
QT
QU
QW
QX
QZ
R
RK
RO
^fiJR.'"
•'Kir':
RX
RZ
S
SD
SF
SI
SM
SN
SR
ss
sv
sx
T
r^T^P
TD
-'"TF^-,
TO
TQ
TR
TW
U
"uwf
UP
vUR^
uv
ux
•- ^ _•"*•> w
; TTV
V*%A ^
• =
0 =
Res. 1
>t 56.0 rm
^ivT^^^A
5LO
50.0
55.0
52.0
52.0
49.0
44.0
50.0
49.0
52.0
49.0
52.0
47.0
50.0
,. y"5^*^25t']^
"l^^f
"$ti/6^lO^.;-
53.0
56.0
56.0
46.0
52.0
57.0
55.0
51.0
56.0
52.0
59.0
52.0
^5^2439?
47.0_
,;>|^f3If^f
54To
53.0
54.0
52.0
55.0
Res. 2
583 _
"*-"", /;\^^C^
51.6
50.0
58.0
53.0
58.0
50.0
43.0
50.0
50.0
52.0
53.0
53.0
42.0
5j2.0_
&»^v"'^?- "^
i^^f'j,
\^:Mi'J):^
55.0
55.0
52.0
48.0
56.0
51.0
51.0
52.0
48.0
52.0
55.0
54.0
r "^Mom
._^48^
W5'™;?^'
61.0
51.0
50.0
55.0
55.0
Res. 3
Exper.
Sigma
i57.0 __1-00_
-;^^-'^V^"": "' V-'-, I> -s^k|
53.0
51.0
58.0
52.0
57.0
46.0
47.0
48.0
46.0
53.0
57.0
52.0
45.0
__49:0_
^?^^k^r "•'
spfS
-^^t-ot-
57.0
58.0
52.0
48.0
53.0
58.0
45.0
56.0
49.0
53.0
56.0
55.0
oHio?
48.0
C^-V-r^'r
63.0
51.0
50.0
52.0
53.0
s "«*S\-»S»fi*i •»." «.V
1.15
0.58
1.73
0.58
3.21
2.08
2.08
1.15
2.08
0.58
4.00
0.58
2.52
w_jy>3
|v,s\'!^^,V^,'"
i^fl^i
,\",v,«0-?8 :<'
2.00
1.53
2.31
1.15
2.08
3.79
5.03
2.65
4.36
0.58
2.08
_1.53_
jjjTf'. "?'j"/» "«S"*"'
-, „'- •"?' y^\J.vvt v"
«... 0_.5if _
~^^^|^'"-
^4^73
1.15
2.31
1.73
1.15
V^VV^ -'/ s-^V^^^-'-^^R1'^ -^r^^vV''1-?
55~0
"rr^v'^V1'
50.0
58.0
" O'\s v^ ^ft^^V" '
' '^ ^ ,A' ^V- ' ^ * "* ^
"<.v^\' •>*''" ^<^ ^
56.0
; ;--;\-,{;: v
48.0
55.0
'v; ,.# '%*&", ;' t^.s
^ ^ % i j^j w^
N ^ "" '"V". >
„ .,65A,
^-."-1's^X- V'
49.0
52.0
,.„ ;w <":'A ^ /•' * "
* s \ " / ?
/•* Vjftft.*.'- ^ .-..•"•
No data submitted
Insufficient
data
X s
. ,.,0;,6A_
-,. Vf-— \'-V"''^
1.00
3.00
^> %> <>•*&•<' -.^ %' w/"*;\ '
°\ - - " " " ""
* '..••. ^^^^^
Rnganal
(R + SR)
0.197
?; ', , *\ - , .. -
0.197
0.098
0.295
0.098
0.591
0.394
0.394
0.197
0.394
0.098
0.788
0.098
0.492
_J1295_ _
*s ''^I^V'ft?-' V,\;
11 ' t ' ' ' '''
"•"C11 s '"''''* ' ** ' ''i'
*• '- Q,i698;i;--- /i
0.394
0.295
0.394
0.197
0.394
0.689
0.984
0.492
0.788
0.098
0.394
0.295
1^098??, •-'
0.098
;"'% ---',,-, ',>;'
0.886
0.197
0.394
0.295
0.197
ft/-^ ' ,y v Vf*^11*'.
0.098
,t«-.^.: >^-',;-:
0.197
0.591
*" "' * X * * ' f '* '
t4 \f *-*f ' , ^t
""••• ' . •;'. ff * ,
Normalized deviation
Average
57.00
"'/C^/'"-"
51.67
50.33
57.00
52.33
55.67
48.33
44.67
49.33
48.33
52.33
53.00
52.33
44.67
50.33
.'v,.',^"' *~ ."f'-l
;';;'-'\ V, ••-,
•. '£t£t d ^7 •.'
' «. ^ xrO*^/ f T
55.00
56.33
53.33
47.33
53.67
55.33
50.33
53.00
51.00
52.33
56.67
53.67
c-?:iiM
47.67
' r^y^>"
59.33
51.67
51.33
53.00
54.33
\;-ff;'"A>:,' -,-
55.33
;->l'',;'.?%,ir
49.00
55.00
* & ^'X
""^ * %•*•• v
TAG SYMBOLS
Determined
to be an outlier
(grand-avg) (known) Tag
1.12
Vt"!;4^^v '". ' :~
-0.42
-0.80
1.12
-0.22
0.74
-1.38
-2.44
-1.09
-1.38
-0.22
-0.03
-0.22
-2.44
:°JKL_. „.
"•^"I'V , f^;\^T " •.
^M^fy^^
v*r 3'J91"',y' "
0.55
0.93
0.07
-1.67
0.16
0.64
-0.80
-0.03
-0.61
-0.22
1.03
0.16
'7:''"^i2J^'^
,'J^!^?L,'l
^^JTJ-^^ ;r\~
1.80
-0.42
-0.51
-0.03
0.35
,?,: v>XNsf^-'ivv'x _ V
VI0.:64.. J
:^>^-]':'/;.' -v>-
-1.19
0.55
' < •Jiv>''"V5iX£ " "-V '
- ,' !• / \ X -,
' **"; fttfSf. •: . •«*
ft s Above
11 s Below
0.29
1 ' v . • »
-1.25
-1.64
0.29
-1.06
-0.10
-2.21
-3.27 U
-1.92
-2.21
-1.06
-0.87
-1.06
-3.27 U
-1.64
^ '-y'-N// \vw*,, • s
\"v"/ly^
??3M,^:x
-0.29
0.10
-0.77
-2.50
-0.67
-0.19
-1.64
-0.87
-1.44
-1.06
0.19
-0.67
':-&6&, ~JxH
:2.41_^ _
"- »''-!' ' V'*'
0.96
-1.25
-1.35
-0.87
-0.48
j-T <,;'',; ' ' • ,
-0.19
- V:s:v -'"-• ,';
-2.02
-0.29
' ' *y ?*' '
-. f'-Sf'f ' * 0
control limit
control limit _,
-------
ESD-LV Performance Evaluation: Gamma in Water, 6-Nov-1998
35/37
Barium-133
Lab Res. 1
Exper. Rng anal Normalized deviation
Res. 2 Res. 3 Sigma (R + SR) Average (grand-avg) (known) Tag
VC
1.15
2.00
2.08
0.00
r^—r--
0.197
0.394
0.394
0.000
55.33
52.00
54.33
51.00
50.0 _ 9-°°_w ,MT°_ _^_59-°°t „ 1-70 _^
49.~"*"1o!bo*"0'^ 6.666 """""" *"' ^""^"
Y 53.0 53.0 56.6 1.73 0.295 54.00 6.26 -6.58
Average
Tag
Data sorted by Laboratory Average
Lab Average Tag Lab | Average
Tag
Lab
24.67
25.33
26.33
44.67
44.67
45.00
45.00
45.67
46.00
46.00
46.00
x
X
TC
CX
MX
RK
QT
MT
AJ
MP
OT
LR
BH
46.33
46.33
46.67
47.33
47.67
47.67
48.00
48.33
48.33
48.67
49.00
CJ
AL
KH
SF
XI
TD
BC
QW
QP
BA
XT
49.00
49.00
49.33
49.33
49.67
49.67
50.33
50.33
50.33
50.33
50.67
XB
UV
XF
QU
NP
GL
SN
RO
PW
BB
JS
• = No data submitted
0 = Insufficient data
TAG SYMBOLS
= Determined to be an outlier
ft = Above control limit
Jl = Below control limit
-------
36/37 ESD-LV Performance Evaluation: Gamma
Barium-133
Average Tag
50.67
50.67
51.00
51.00
51.00
51.33
51.67
51.67
51.67
51.67
51.67
52.00
52.00
52.33
52.33
52.33
52.33
52.33
52.33
52.33
52.67
52.67
52.67
52.67
52.67
53.00
53.00
53.00
53.00
53.00
53.00
53.33
53.33
53.33
% responding labs
10-
o m
° -6 ' -4
• = No data submitted
0 = Insufficient data
Ds
Lab
JM
BK
VI
SS
AK
TR
TQ
PM
M
HK
AU
VE
KL
X
WR
SV
R
QX
Q
FJ
XD
XA
NJ
HI
BO
TW
SR
QZ
I
AW
AF
SD
P
C
in Water, 6-Nov-1998
ita sorted by Laboratory Averag
Average Tag Lab
53.67
53.67
53.67
54.00
54.00
54.00
54.00
54.00
54.00
54.33
54.33
54.33
54.33
54.67
54.67
54.67
54.67
55.00
55.00
55.00
55.00
55.00
55.00
55.00
55.00
55.00
55.00
55.33
55.33
55.33
55.33
55.33
55.33
55.67
Frequency distribution
_
• f 1
• •-•••-IllllllllllH--
T
SI
EL
Y
WD
O
KX
DR
D
VH
U
NH
AY
VS
N
CA
A
W
UX
RZ
L
JE
IU
E
CO
BL
AH
VC
UP
SM
OM
cs
AE
WW
fe
Average Tag
55.67
55.67
55.67
55.67
56.00
56.00
56.00
56.33
56.33
56.33
56.67
56.67
56.67
56.67
57.00
57.00
57.00
57.00
57.00
57.33
57.33
57.33
58.00
58.00
58.00
59.00
59.00
59.00
59.33
59.67
60.33
60.67
66.67 x
107.00 x
2713.00 x
Normalized deviation of the mean from the known value
TAG SYMBOLS ft e Above control
x s Determined to be an outlier li = Below control
Lab
QM
FL
DH
DE
JY
GQ
EX
S
MV
BM
sx
JG
DT
BN
VO
PX
PD
HL
CP
HE
CE
AZ
NO
EB
DO
XK
K
DD
TO
LF
LE
FE
RX
OA
XU
m
+6
limit
limit
-------
ESD-LV Performance Evaluation: Gamma in Water, 6-Nov-1998 37/37
Barium-133
% responding labs Frequency distribution
10-
• 1 •••••••lilllllL i.
-6 -4 -2 0 +2 +4 +6
Normalized deviation of the mean from the grand average
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