Air Pollution Emission Test: Project Report No. 74-HAS-1, Reserve Mining Company (Silver Bay, Minnesota)

74-HAS-l (REPORT NUMBER) AIR POLLUTION EMISSION TEST RESERVE MINING COMPANY (PLANT NAME; Silver Bay, Minnesota (PLANT ADDRESS) U. S. ENVIRONMENTAL PROTECTION AGENCY Office of Air and Water Programs Office of Air Quality Planning and Standards Emission Standards and Engineering Division Emission Measurement Branch Research Triangle Park, N. C. 27711 ------- Emission Testing Report EMB Report No. 74-HAS-l RESERVE MINING COMPANY Silver Bay, Minnesota. Environmental Protection Agency Office of Air Quality Planning and Standards Research Triangle Park, North Carolina 27711 June 1974 ------- INTRODUCTION Page Number(s) I. INTRODUCTION 1-3 Figure. 1 - Sampling Locations .. .„ ......... . 3 II. SUMMARY AND DISCUSSION OF.RESULTS 4-24 Tables 1-18 - Participate Summary in English and Metric Units 7-24 III. SUMMARY AND DISCUSSION OF PROCESS SAMPLE ANALYSIS . 25 IV. PROCESS DESCRIPTION 26-28 V. PROCESS OPERATION DURING TEST 29-32 VI. LOCATION OF SAMPLING POINTS 33-34 VII. SAMPLING AND ANALYTICAL PROCEDURES '. . • 35-36 APPENDICES APPENDIX A - Sample Calculations APPENDIX B - Field Data APPENDIX C - Laboratory Report. APPENDIX D - Test Log APPENDIX E - Project Participants ------- INTRODUCTION This report describes an emission and process sampling program conducted at the Reserve Mining Company taconite processing facilities located in Silver Bay, Minnesota, during the week of September 10, 1973. The plant processes taconite: ore and produces pellets which are ideally suited for blast furnace feed. Approximately 85,000 tons per day of ore are received in railroad cars from the mine at Babbitt, Minnesota where it has been crushed to minus 4-inch size. The processing facility re- duces the ore to minus 3/4-inch size by ten sets of cone crushers. The crushed ore is then delivered by belt to the Concentrator Building where it is ground and separated by 22 parallel units. Each unit consists of the following items operated in series: "a rod mill, a rougher magnetic separator, a ball mill, a cleaner magnetic separator, a regrind ball mill, a finisher magnetic separator, and a disc filter. The filter cake is mixed with a small amount of bentonite clay and delivered to 36 large rotating drums which roll it into balls of about 1/2" diameter. The balls are then fed into 8 traveling grate pelletizing machines where they are first dried, then heated to over 2200°F, then passed through an oxidizing section, then a cooling section. This transforms them into hard pellets. Four emission points were sampled for particulate matters-exhaust stack No. 110 on the west No. 104 fine crusher, waste gas stack on pelletizer No. 5, hood vent stack on pelletizer No. 5, east concentrator stack No. 118, These locations are shown in Figure 1. In addition, process samples .were obtained at the outlet of the crusher, and from the conveyor belts which feed the pelletizer. The primary purpose of the test was to identify and quantify possible asbestos emissions. ------- Samples obtained were subjected to a series of analytical techniques designed to identify chemical composition and physical form. Specific emphasis was placed upon the identification and characterization of asbestos minerals. Techniques employed include X-ray diffraction, light microscope, 'and electron microscope".procedures. ' . • Emission samples were obtained by a Battelle (Columbus Laboratories) test team under contract and directed by EPA. Emission samples were analyzed by Battelle and by McCrone Associates. Process samples were analyzed by Battelle. Prior stack tests to determine particulate matter emission rates have been conducted by the Company and by the State of Minnesota. Reserve Mining results of particulate matter stack tests run on #6 pelletizer waste gas hood and exhaust stacks during February and March 1973, average 0.19 and 0.068 grains/scf for waste gas and hood exhaust, respectively. Company calculations give a dust load of 194.5 Ibs/hr from #6 waste gas stack when its concentration was 0.215 grains/scf. The State of Minnesota made tests on the waste gas stacks of #5 and #6 pelletizer furnaces. At 135 wet tons/hr ball feed, the results were 0.52 and 0.61 grains/scf, respectively. ------- DUMP "IM 7)3 T DUMP ^y " , • ® ®_ ® ® ® '•© h/£5T A-/A/£" CKuZHPR ©@@ $ ® c i 0 0 r^c- 1 s y (2)) 0 (,n) 0 u <>!// rcE. #•5 / -^~\ 0 .0 H 4 0 0 \ o o ^ =5 00 ' ' 1 o o ret. ^ ^ © 0 o Fee. tt i © ( 3 © © ( • o Fee. •* it /•""• ^ > ''" \ -" •> /""\ /""^ (li7\ (/if} (tt<)}-.17.0} (/?.<) (izz) V_y v x v x' -. ' v—/ x- s O Figure 1: Sampling Locations, Reserve Mining Company, Silver Bay, Minnesota ------- SUMMARY AND DISCUSSION OF RESULTS Under Environmental Protection Agency direction, Battelle personnel collected a total of" eleven participate samples from four process emission locations at the Reserve Mining facility. Three samples were collected downstream of the control device serving one of the ten fine crusher lines; four samples were collected from the waste gas stack serving pelletizer No. 5; three samples were collected from the hood vent stack serving pelletizer No. 5; and one sample was collected after the control device serving one of the concentrator- storage bin systems. The collected samples were then transported to EPA laboratories in Durham, North Carolina where the filter fractions were weighed. The samples froin Run Nos. 1 (fine crusher), 6 (waste gas), and 10 (hood vent) were then sent to BatteTle Columbus Laboratories for total particulate and asbestos analysis. The results of these analysis are covered in this report. The samples from Run Nos. 2 (fine crusher), 5 (waste gas), 9 (hood vent), and 11 (concentrator) were sent to McCrone Associates, for asbestos analysis, and the results will be reported separately by the Office of Technical Analysis, EPA. The remaining samples have been stored for possible future analysis. The sampling data for each of the eleven runs is summarized in Tables A-l to A-10 in Appendix A. These summaries include sampling parameters and stack flow rate data. ------- The results of testing for the three runs that were analyzed * by Battelle are summarized in Tables 1-18. The total particulate emissions found are given in Tables 1-3. The total asbestos emissions are given in Tables 4-6, and the amphibole emissions are given in Tables 7-9. Tables 10-18 are duplications in English units of the information presented in Tables 1-9. The total particulate concentration found in the fine crusher 3 3 exhaust was 11.3 mg/NM . At a stack flow rate of 471 NM /min, the particulate mass flow rate was 0.32 kg/hr. Total asbestos accounted for 5.8 percent of the total mass in the sample, with essentially all of the asbestos being of the amphibole form. Only 0.02 percent of the asbestos was of the chrysotile form. The asbestos concentration o and rate in the emissions was 0.65 mg/NM and 0.02 kg/hr. At the waste gas stack, the total particulate concentration was 3 3 355 mg/DNM at 3270 NM /min flow, resulting in a particulate mass rate of 69.7 kg/hr. The asbestos weight was 0.2 percent of the total sample, with essentially all of the asbestos being amphibole. Chrysotile accounted for only 0.36 percent of the total asbestos. The asbestos emissions 3 were at a concentration of 0.81 mg/NM resulting in an emission rate of 0.16 kg/hr. mg/NM - Milligram/normal cubic meter, 21.1°C, 760 mmHg, dry ------- At the hood vent location, the total participate concentration was 127.7 mg/NM3 at a flow ra'te of 2700 NM3/min. This results in a mass flow rate of 20.7 kg/hr. The weight of asbestos found in this sample was 0.35 percent of the .total particulate weight. The asbestos concen- 3 tration in the emission was 0.37 mg/NM and the asbestos mass emission rate, was 0.06 kg/hr...^ The asbestos was identified as the amphibole form, with no chrysotile being found. The results reported for the fine crusher runs included the impinger water portion of the total sample, while results for the waste gas and hood vent locations do not. However, it is demonstrated by the results of Run 1 that essentially all (99.9%)of the asbestos was collected in the probe wash and filter portions of the sample, and that the addition of the asbestos mass coll^".;!r''~'^'i:i'^'ir.>KLl.-vr;".jF-ra does not significantly effect the calculated results. ' • "•" • •' The sampling and analytical procedures are detailed in Section VII, and the complete laboratory report is given in Appendix C. ------- TABLE 1 -». i r t — -a lj I /\ nj t i J LOCATioN:' OPERATOR: __ FINE CRUSHER STACK lib,"' TOTAL PART I CURATE EMISSIONS ENVIRONMENTAL PROTECTION AGENCY PART ICULATE DESCRIPTION DATE OF RUN SUMMARY IN METRIC UNITS UNITS 3 AVERAGE STACK AREA NET TIME OF RUN BAROMETRIC PRESSURE AVG ORIFICE PRES D VOL DRY GAS-METER AVG GAS METER TEMP VOL DRY GAS-STD COND TOTAL H20 COLLECTED VOL H20 VAPOR-STD C PERCENT MOISTURE BY MOLE FRACTION DRY G PERCENT C02 BY VOL,. PERCENT 02 BY VOLX PERCENT CO BY VOLX PERCENT N2 BY VOLX MOLECULAR V/T-DRY ST MOLECULAR WT-STK GA AVG STACK TEMPERATURE NET SAMPLING POINTS STACK PRESSURE/ ABS AtX\ f •• K f\ I / r\ A r »f»-i ^>rtl AVU O I HOf\ UM5 V C.LUO I STK FLOWRATE, DR ACTUAL STACK FLOWRATE PERCENT ISOKINETIC PARTICULATE NT-PAR PART ICULATE WT-TOTAL PERC IMPINGER CATCH PART. LOAD-PTL/STD PART. LOAD-TTL/STD PART. LOAD-PTLXSTD PART. LOAD-TTL/STD PART. LOAD-PTL/STK PART. LOAD-TTLXSTK PART 1C EMIS-PARTIAL PART 1C EMIS-TOTAL PART EMIS/WT PRO FD PART EMIS/WT PRD FD PERCENT EXCESS AIR 9-11-73 iop :OND ID 1 :OND ' VOL iAS . DRY DRY DRY DRY 'K GAS iS IRE ;OLUTE ; i TY ;TD CN iTE "IAL iL 1 CN CN CN @ CN @ CN CN ) PTL ) TTL M2 MIN MM . HG . MM.H20 DM3 DEG.C DNM3 ML NM3 DEG.C MM . HG M/S DNM3/M ' AM3/M MG MG MG/NM3 MG/NM3 12% C02 12% C02 MG/AM3 MG/AM3 KG/HR KG/HR KG/MTON KG/MTON 0.-369 120.0 739.11* 11. 701* 2.65 29.2 2.52 19.2 0.03 1.0 0.990 0.0 21.0 0.0 79.0 28.81* 28.73 15.9 1 739.11* ^ «• «• x> ^» £. i . /On 171. 181. 98.1 26.70 28.«8 6.3 10.57 11.27 ********* 21.706 171. 181. 98.1 26.70 28.18 6.3 10.57 11.27 ****** **************** 10.35 11.01* 0.30 0.32 0.00073 0.00078 10.35 11.01* 0.30 0.32 . 0.00073 0.00078 ****************** 7 ------- TAB PLANT: RESERVE MINING CO"., SiLVhK BAY, MiNN. LOCATION: WASTE GAS STACK, PELLET IZER NO. 5, OPERATOR: ENVI'ORNMENTAL PROTECTION AGENCY TOTAL PARTICIPATE EMISSION PART ICULATE SUMMARY IN METRIC UNITS DESCRIPTION DATE OF RUN STACK AREA NET TIME OF RUN BAROMETRIC PRESSURE AVG ORIFICE PRES DROP VOL DRY GAS-METER COND AVG GAS METER TEMP VOL DRY GAS-STD COND TOTAL H20 COLLECTED VOL H20 VAPOR-STD COND PERCENT MOISTURE BY VOL MOLE FRACTION DRY GAS . PERCENT C02 BY VOL, DRY PERCENT 02 BY VOL, DRY PERCENT CO BY VOL, DRY PERCENT N2 BY VOL, DRY MOLECULAR WT-DRY STK GAS MOLECULAR WT-STK GAS «£ AVG STACK TEMPERATURE NET SAMPLING POINTS STACK PRESSURE, ABSOLUTE AVG STACK GAS VELOCITY STK FLOWRATE, DRY,STD CN ACTUAL STACK FLOWRATE PERCENT ISOKINETIC PARTICULATE WT-PARTIAL PART ICULATE WT-TOTAL PERC IMPINGER CATCH PART. LOAD-PTL,STD CN PART. LOAD-TTL,STD.CN PART. LOAD-PTL,STD CN @ PART. LOAD-TTL,STD CN @ PART. LOAD-PTL,STK CN PART. LOAD-TTL,STK CN PARTIC EMIS-PARTIAL PART 1C EMIS-TOTAL PART EMIS/WT PRO FD PTL PART EMIS/WT PRO FD TTL PERCENT EXCESS AIR UNITS M2 -M IN- MM.HG MM.H20 D.M3 DEG.C DNM3 ML NM3 UCU.V. >V,,',.-HC M/S DNM3/M AM3/M MG MG MG/NM3 MG/NM3 2% CU2 MG/AM3 MG/AM3 KG/HR KG/HR KG/MTON KG/MTON 6 09-12-73 2.590 37.0 743.71 46.990 0.85 22,, 9 0.83 53.8 0.07 8.0 0.920 0.8 20.0 0.0 79.2 28.93 180.4 1 740.16 36.252 3274. 5634. 105.4 294.30 294.30 0.0 355.02 355.02 5325.33 ,53.25.33 206.18 206.18 69.74 69.74 0.63534 0.63534 2200.7 AVERAGE 36.252 3274. 5634. 105.4 294.30 294.30 0.0 355.02 355.02 5325.33 5325.33 206.18 206.18 69.74 69.74 0.63534 0.63534 2200.7 KhADY ------- iABLb 3 . . • PLANT: RESERVE MINING CO., SILVER BAY, MINN, LOCATION: HOOD VENT STACK, PELLETIZER NO. 5, TOTAL PARTICULATE EMISSION OPERATOR: ENVIORNMENTAL PROTECTION AGENCY PARTICULATE SUMMARY IN METRIC UNITS DESCRIPTION DATE OF RUN .UNITS STACK AREA M2 NET TIME OF RUN MIN BAROMETRIC PRESSURE MM.HG AVG ORIFICE PRES DROP MM.H20 VOL DRY GAS-METER COND DM3 AVG GAS METER TEMP DEG.C VOL DRY GAS-STD COND DNM3 TOTAL H20 COLLECTED ML VOL H20 VAPOR-STD COND NM3 PERCENT MOISTURE BY VOL MOLE FRACTION DRY GAS PERCENT C02 BY VOL, DRY 02 BY VOL, DRY CO BY VOL, DRY N2 BY VOL, DRY WT-DRY STK GAS V/T-STK GAS TEMPERATURE PERCENT PERCENT PERCENT MOLECULAR HGLECULAR AVG STACK DEG.C NET SAMPLING POINTS STACK PRESSURE, ABSOLUTE MM.HG AVG STACK GAS VELOCITY M/S STK FLOWRATE, DRY,STD CN DNM3/M ACTUAL STACK FLOWRATE AM3/M PERCENT ISOKINETIC PARTICULATE WT-PARTIAL MG PARTICULATE WT-TOTAL MG PERC IMPINGER CATCH PART. LOAD-PTL,STD CN MG/NM3 PART. LOAD-TTL,STD CN MG/NM3 PART. LOAD-PTL,STD CN (3 12?j C02 PART. LOAD-TTL,STD CN @ 12% C02 PART. LOAD-PTL,STK CN MG/AM3 PART. LOAD-TTL,STK CN MG/AM3 PART 1C EMIS-PARTIAL KG/HR PART 1C EMIS-TOTAL KG/HR PART EMIS/WT PRO FD PTL KG/MTON PART EMIS/WT PRO 'FD TTL KG/MTON PERCENT EXCESS AIR io •• 09-13-73 2.572 36.0 745.24 30.480 0.55 25.6 0.63 31.2 0.04 6.2 0.938 0.0 21.0 0.0 79.0 28.17 120.0 1 742.70 25.542 2705. 3942. 99.7 81.10 81.10 0.0 127.74 127.74 AVERAGE 25.542 2705. 3942. 99.7 81.10 81.10 0.0 127.74 127.74 * * * * * * ********* ******* 87.59 87.59 20.73 20.73 0.16679 *** 87.59 87.59 20.73 20.73 0.16679 0.16679 0.16679 ************** READY 9 ------- TABLE 4 PLANT: RESERVE MINING COMPANY.; SILVER liAV, MINNESOTA LOCATION: FINE CRUSHER STACK 110, TOTAL ASBESTOS EMISSIONS OPERATOR: ENVIRONMENTAL PROTECTION AGENCY PART ICULATE SUMMARY IN METRIC UNITS DESCRIPTION UNITS DATE OF RUN STACK AREA M2 NET TIME OF RUN MIN BAROMETRIC PRESSURE MM.HG AVG ORIFICE PRES DROP MM.H20 VOL DRY GAS-METER COND DM3 AVG GAS METER TEMP DEG.C VOL DRY GAS-STD COND DNM3 TOTAL H20 COLLECTED ML VOL H20 VAPOR-STD COND NM3 PERCENT MOISTURE BY VOL MOLE FRACTION DRY GAS PERCENT C02 BY VOL, DRY PERCENT 02 BY VOL, DRY PERCENT CO BY VOL, DRY -PERCENT N2 BY VOL, DRY MOLECULAR WT-DRY STK GAS MOLECULAR WT-STK GAS v - „.< -• .-.-.•• - AVG STACK TEMPERATURE '"'DEG.C' NET SAMPLING PO I'NTS STACK PRESSURE, ABSOLUTE MM.HG AVG STACK GAS VELOCITY M/S STK FLOWRATE, DRY,STD CN DNM3/M ACTUAL STACK FLOWRATE AM3/M PERCENT ISOKINETIC PART ICULATE WT-PARTIAL MG PART ICULATE WT-TOTAL MG PERC IMPINGER CATCH PART. LOAD-PTL,STD CN MG/NM3 PART. LOAD-TTL,STD CN MG/NM3 PART. LOAD-PTL,STD CN @ 12% C02 PART. LOAD-TTL,STD CN @ 12% .CO? PART. LOAD-PTL,STK CN MG/AM3 PART. LOAD-TTL,STK CN MG/AM3 PART 1C EM IS-PARTIAL KG/HR PART 1C EMIS-TOTAL KG/HR PART EMIS/WT PRO FD PTL KG/MTON PART EMIS/WT PRO FD TTL KG/MTON PERCENT EXCESS -AIR AVERAGE 9-11-73 0.369 120.0 739.14 44.704 2,65 29.2 2.52 19.2 0.03 1.0 0.990 0.0 21.0 0.0 79.0 .28.84 "'""'""""'15.9 1 739.14 21.706 471. 481. 98.1 1.65 1.65 0.1 0.65 0.65 21.706 471. 481. 98.1 1.65 1.65 0.1 0.65 0.65 ************** ************** 0 0.64 0.64 0.02 0.02 00005 0.00005 0.64 0.64 0.02 0.02 0.00005 0.00005 **************** ------- PLANT.: RESERVE MINING CO., SILVER BAY, MINN. LOCATION: WASTE GAS STACK, PELLET IZER NO. 5, TOTAL ASBESTOS EMISSIONS OPERATOR: ENVIORNMENTAL PROTECTION AGENCY PART ICULATE SUMMARY IN METRIC UNITS DESCRIPTION UNITS DATE OF RUN STACK AREA M2 NET TIME OF RUN MIN BAROMETRIC PRESSURE MM.HG AVG ORIFICE PRES DROP MM.H20 VOL DRY GAS-METER COND " DM3 AVG GAS METER TEMP DEG.C VOL DRY GAS-STD COND DNM3 TOTAL H20 COLLECTED ML VOL H20 VAPOR-STD COND NM3 PERCENT MOISTURE BY VOL MOLE FRACTION DRY GAS PERCENT C02 BY VOL, DRY PERCENT 02 BY VOL, DRY PERCENT CO BY VOL, DRY PERCENT N2 BY VOL, DRY MOLECULAR WT-DRY STK GAS MOLECULAR WT-STK GAS -^V-'~?;-. AVG STACK TEMPERATURE DEG,C NET SAMPLING POINTS STACK PRESSURE, ABSOLUTE MM.HG AVG STACK GAS VELOCITY M/S STK FLOWRATE, DRY,STD CN DNM3/M ACTUAL STACK FLOWRATE AM3/M PERCENT ISOKINETIC PART ICULATE WT-PARTIAL MG PARTICULATE WT-TOTAL MG PERC IMPINGER CATCH PART. LOAD-PTL,STD CN MG/NM3 PART. LOAD-TTL,STD CN MG/NM3 PART. LOAD-PTL,STD CN @ 12% C02 PART. LQAD-TTL,STD CN @ 12% C02 PART. LOAD-PTL,STK CN MG/AM3 PART. LOAD-TTL,STK CN MG/AM3 PARTIC EMIS-PARTIAL KG/HR PART 1C EMIS-TOTAL KG/HR PART EMIS/WT PRO FD PTL KG/MTON PART EMIS/WT PRO FD TTL KG/MTON PERCENT EXCESS AfR 6 09-12-73 2.590 37.0 743.71 46.990 0.85 22,9 0.83 53.8 0.07 8.0 0.920 0.8 20.0 0.0 79.2 . ?8, 93. .JSO.'J 1 740.16- 36.252 3274. 5634. 105.4 0.67 0.67 0.0 0.81 0.81 12.09 •'••"•-T2-. 09 0.47 0.47 0.16 0.16 0.00144 0.00144 2200.7 AVERAGE 36.252 3274. 5634. 105.4 0.67 0.67 0.0 0.81 0.81 12.09 12.09 0.47 0.47 0.16 0.16 0.00144 0.00144 2200.7 READY ------- TABLE 6 PLANT: RESERVE MINING CO., SILVER BAY,- MINN, LOCATION: HOOD VENT STACK,. PELLETIZER NO. 5, OPERATOR: ENV I ORNMENTAL PROTECTION AGENCY TOTAL ASBESTOS EMISSIONS PART I CD LATE SUMMARY IN - METRIC UNITS DESCRIPTION DATE OF RUN STACK AREA NET TIME OF RUN BAROMETRIC PRESSURE AVG ORIFICE PRES DR VOL DRY GAS-METER C AVG GAS METER TEMP VOL DRY GAS-STD COND TOTAL H2.0 COLLECTED VOL H20 VAPOR-STD C PERCENT MOISTURE BY MOLE FRACTION DRY G PERCENT C02 BY VOL, PERCENT 02 BY VOL, PERCENT CO BY VOL, PERCENT N2 BY VOL, MOLECULAR WT-DRY ST MOLECULAR VJT-STK GA AVG STACK TEMPERATURE NET SAMPLING POINTS- STACK PRESSURE, ABS AVG STACK GAS VELOC STK FLOWRATE, DRY,S ACTUAL STACK FLOWRATE PERCENT ISOKINETIC PART ICULATE WT-PAR PARTICULATE WT-TOTAL PERC IMPINGER CATCH LOAD-PTL,STD LOAD-TTL,STD LOAD-PTL,STD LOAD-TTL,STD LOAD-PTL,STK LOAD-TTL,STK C EM IS-PARTIAL C EMIS-TOTAL EMIS/WT PRD FD EMIS/WT PRD FD PART PART PART PART PART PART PART PART PART PART UNITS M2 MIN MM.HG OP MM.H20 OND DM3 DEG.C D DNM3 ML OND NM3 VOL AS DRY DRY DRY DRY K GAS ,S RE DEG.C OLUTE MM.HG ITY M/S TD CN DNM3/M TE AM3/M IAL MG ,L MG 1 CN MG/NM3 CN MG/NM3 CN @ 12% C02 CN @ 12% C02 CN MG/AM3 CN MG/AM3 KG/HR KG/HR I PTL KG/MTON I TTL KG/MTON 10 09-13-73 2.572 36'. 0 745.24 30.480 0.65 25.6 0.63 31.2 0.04 6.2 0.938 0.0 21.0 0.0 79.0 28.84 28.17 120.0 1 742.70 25.542 2705. 3942. 99.7 0.24 0.24 0.0 0.37 0.37 AVERAGE 25.542 2705. 3942. 99.7 0.24 0.24 0.0 0.37 0.37 *************** ************** 0.26 0.26 0.06 0.06 0.00049 0.00049 0.26 0.26 0.06 0.06 0.00049 0.00049 1 O ------- PLANT: RESERVE MINING COMPANY; SILVER BAY, LOCATION: FINE CRUSHER STACK 110, AMPHIDOI.F. OPERATOR: ENVIRONMENTAL PROTECTION AGENCY MINNESOTA ASBESTOS EMISSIONS PART ICULATE SUMMARY IN METRIC UNITS DESCRIPTION . . UNITS DATE OF RUN STACK AREA M2 NET TIME OF RUN MIN BAROMETRIC PRESSURE MM.HG AVG ORIFICE PRES DROP MM.H20 VOL DRY GAS-METER COND - - DM3 AVG GAS METER TEMP DEG.C VOL DRY GAS-STD COND - DMM3 TOTAL H20 COLLECTED ML VOL H20 VAPOR-STD COND NM3 PERCENT MOISTURE BY VOL MOLE FRACTION DRY GAS PERCENT C02 BY VOL, DRY PERCENT 02 BY VOL, DRY PERCENT CO BY VOL, DRY PERCENT N2 BY VOL, DRY MOLECULAR WT-DRY STK GAS MOLECULAR WT-STK GAS AVG STACK TEMPERATURE DEG.C NET SAMPLING POINTS STACK PRESSURE, ABSOLUTE MM.HG AVG STACK GAS VELOCITY M/S STK FLOWRATE, DRY,STD CN DNM3/M ACTUAL STACK FLOWRATE AM3/M PERCENT I SDK I NET 1C PARTICULATE WT-PARTIAL MG PART ICULATE WT-TOTAL MG PERC IMPINGER CATCH PART. LOAD-PTL,STD CN MG/NM3 PART. LOAD-TTL,STD CN MG/NM3 PART. LOAD-PTL,STD CN @ 12% C02 PART. LOAD-TTL,STD CN @ 12% C02 PART. LOAD-PTL,STK CN MG/AM3 PART. LOAD-TTL,STK CN MG/AM3 PART 1C EM IS-PARTIAL KG/HR PART 1C EMIS-TOTAL KG/HR PART EMIS/WT PRO FD PTL KG/MTON PART EMIS/WT PRO FD TTL KG/MTON PERCENT EXCESS AIR 3 AVERAG.E. ' . ' ~ " ; 9-11-73 ~ -;• 0.369 120.0 739.14 44.704 2.65 — 29.2 2.52 19.2 " 0.03 - 1.0 0.990 0.0 -21.0 0.0 "79.0 28.84 28.73 15.9 1 739.14 21.706 •••"• 471. 481. ' 98.1 - 1.65 1.65 - o.i 0.65 0.65 ******** ******** 0.64 0.64 0.02 0.02 0.00005 0 0.00005 0 — — --' •--• '" •-. - •• — • — .. - -. •- . 21.706 - • ! ' 471. '481. ~ • "• v • 98.1 1.65 "•" -;••'•• 1.65 — • o.i .---.- 0.65 . '•• i ••-:••;<-".• • ••"•••--. "0.65 . — - , - ..., ** . -.-••;- ** ---• - - _ . ... .. 0.64 ••'-. 0.64 " ". ----•• 0.02 0. 02 " . .00005 K"---. ': .00005 ~ -•.--,-- -;-.-. • ..;. ************** 13 ------- TABLE 8 PLANT: RESERVE MINING CO., SILVER BAY, MINN. LOCATION: WASTE GAS STACK, PELLET I ZER NO. 5, OPERATOR: ENVIORNMENTAL PROTECTION AGENCY AMPHIBOLE EMISSIONS PART ICULATE SUMMARY IN METRIC UNITS READY DESCRIPTION • . UNITS DATE OF RUN STACK AREA M2 NET TIME OF RUN MIN BAROMETRIC PRESSURE MM.HG AVG ORIFICE PRES DROP MM.H20 VOL DRY GAS-METER COND DM3 AVG GAS METER TEMP DEG.C VOL DRY GAS-STD COND DNM3 TOTAL H20 COLLECTED ML VOL H20 VAPOR-STD COND NM3 PERCENT MOISTURE BY VOL MOLE FRACTION DRY GAS PERCENT C02 BY VOL, DRY PERCENT 02 BY VOL, DRY PERCENT CO BY VOL, DRY PERCENT N2 BY VOL, DRY MOLECULAR WT-DRY STK GAS MOLECULAR WT-STK GAS AVG STACK TEMPERATURE DEG.C NET SAMPLING POINTS STACK PRESSURE, ABSOLUTE MM.HG AVG STACK GAS VELOCITY M/S STK FLOWRATE, DRY,STD CN DNM3/M ACTUAL STACK FLOWRATE AM3/M PERCENT ISOKINETIC PARTICULATE WT-PARTIAL MG PARTICULATE WT-TOTAL MG PERC IMPINGER CATCH PART. LOAD-PTL,STD CN MG/NM3 PART. LOAD-TTL,STD CN MG/NM3 PART. LOAD-PTL,STD CN @ 12% C02 PART. LOAD-TTL,STD CN @ 12% C02 PART. LOAD-PTL,STK CN MG/AM3 PART. LOAD-TTL,STK CN MG/AM3 PART 1C EM IS-PARTIAL KG/HR PART 1C EMIS-TOTAL KG/HR PART EMIS/WT PRO FD PTL KG/MTON PART EMIS/WT PRO FD TTL KG/MTON PERCENT EXCESS AIR 6 09-12-73 2.590 37.0 743.71 46.990 0.85 22.9 0.83 53.8 0.07 8.0 . 0.920 0.8 20.0 0.0 79.2 28.93 A A ^ f L 0 . U 3 180.U 1 740.16 36.252 3274. 5634. 105.4 0.64 0.64 0.0 0.78 0.78 11.67 11.67 0.45 0.45 0.15 0.15 0.00139 0.00139 2200.7 AVERAGE 36.252 3274. 5634. 105.4 0.64 0.64 0,0 0.78 0.78 11.67 11.67 0.45 0.45 0.15 0.15 0.00139 0.00139 2200.7 ------- TABLE 9 PLANT: RESERVE MINING CO., SILVER BAY, MINN LOCATION: HOOD VENT STACK, PELLET I ZER NO. 5, OPERATOR: ENVI ORNMENTAL PROTECTION AGENCY AMPHIBOLE EMISSIONS PART ICULATE SUMMARY IN METRIC UNITS DESCRIPTION DATE OF RUN STACK AREA NET TIME OF RUN BAROMETRIC PRESSURE AVG ORIFICE PRES D VOL DRY GAS-METER AVG GAS METER TEMP VOL DRY GAS-STD COND TOTAL H20 COLLECTED VOL H20 VAPOR-STD C PERCENT MOISTURE BY MOLE FRACTION DRY G PERCENT C02 BY VOL, PERCENT 02 BY VOL, PERCENT CO BY VOL, PERCENT N2 BY VOL, MOLECULAR WT-DRY ST MOLECULAR WT-STK G AVG STACK TEMPERATURE NET SAMPLING POINTS STACK PRESSURE, ABS AVG STACK GAS VELOC STK FLOWRATE, DRY,S ACTUAL STACK FLOWRATE PERCENT ISOK1NETIC PART ICULATE WT-PAR PART ICULATE WT-TOTAL PERC IMPINGER CATCH PART. LOAD-PTL,STD PART. LOAD-TTL,STD PART. LOAD-PTL,STD PART. LOAD-TTL,STD PART. LOAD-PTL,STK PART. LOAD-TTL,STK PART 1C EM IS-PARTIAL PART 1C EMIS-TOTAL PART EMIS/WT PRO FD PART EMIS/WT PRO FD PERCENT EXCESS-AIR OP OND D OND VOL AS DRY DRY DRY DRY K GAS RE OLUTE ITY TD CN TE IAL L CN CN CN @ CN @ CN CN PTL TTL UN 1 TS M2 MIN MM . HG MM.H20 DM3 DEG.C DNM3 ML NM3 D EG « C MM . HG M/S DNM3/M AM3/M MG MG MG/NM3 MG/NM3 12% C02 m cor MG/AM3 MG/AM3 KG/HR KG/HR KG/MTON KG/MTOM .10 09-13-73 2.572 36.0 745.24 30.480 0.65 25.6 0.63 31.2 0.04 6.2 0.938 0.0 21.0 0.0 79.0 _^ v .2^.84 12olo 1 '• 742.70 25.542 2705. 3942. 99.7 0.24 0.24 0.0 0.37 P. 37 ******* AVERAGE 25.542 2705. 3942. 99.7 0.24 0.24 0.0 0.37 0.37 ***** , . : .;,*. ********* 0.26 0.26 0.06 0.06 0.00049 0.00049 0.26 0.26 0006 0.06 0.00049 0.00049 ************** READY 1 ------- -r n. n ! r 1 r> ! .M.L'!_C. i U PLANT: RESERVE MINING; SILVER BAY, MINNESOTA LOCATION: FINE CRUSHER STACKI10, TOTAL PARTICIPATE OPERATOR: ENVIRONMENTAL PROTECTION AGENCY EM ss ONS PART ICULATE SUMMARY IN ENGLISH UNITS DESCRIPTION DATE OF RUN STACK AREA NET TIME OF RUN BAROMETRIC PRESSURE AVG ORIFICE PRES DROP VOL DRY GAS-METER COND AVG GAS METER TEMP VOL DRY GAS-STD COND TOTAL H20 COLLECTED VOL M20 VAPOR-STD COND PERCENT MOISTURE BY VOL MOLE FRACTION DRY GAS PERCENT C02 3Y VOL, DRY PERCENT 02 BY VOL, DRY PERCENT CO BY VOL, DRY PERCENT N2 BY VOL, DRY MOLECULAR NT-DRY STK GAS MOLECULAR WT-STK GAS AVG STACK TEMPERATURE NET SAMPLING POINTS STACK PRESSURE, ABSOLUTE AVG STACK GAS VELOCITY STK FLOV.'RATE, DRY,STD CN ACTUAL STACK FLOWRATE PERCENT ISOKINETIC PART ICULATE WT-PARTIAL PART ICULATE WT-TOTAL PERC IMPINGER CATCH LOAD-PTL,STD CN LOAD-TTL,STD CN LOAD-PTL,STD CN @ LOAD-TTL,STD CN @ LOAD-PTL/STK CN LOAD-TTL,STK CN UNITS' FT2 MIN IN.HG IN.H20 DCF D EG. F DSCF ML SCF PART, PART, PART, PART, PART, PART, PART 1C EM IS-PARTIAL PART 1C EMIS-TOTAL PART EMIS/WT PRD FD PART EMIS/V/T PRD FD PERCENT EXCESS AIR PTL TTL DEG.F ' IN.HG FPS DSCFM ACFM MG MG GR/DSCF GR/DSCF 125 C02 12% C02 GR/ACF GR/ACF LB/HR LB/HR LB/TON LB/TON 3 9-11-73 3.976 120.0 29.10 1.760 93.70 84.6 89.06 19.2 0.91 1.0 0.990 0.0 21.0 0.0 79.0 28.84 28.73 60.7 1 29.10 71.214 16644. 16989. 98.1 26.70 28.48 6.3 0.00462 0.00493 **** AVERAGE 71.214 16644. 16989. 98.1 26.70 28.48 6.3 0.00462 0.00493 ****** **************** 0.00452 0.00482 0.66 0.70 0.00146 0. 00452 0.00482 0.66 0.70 0.00145 0.00156 0.00156 • **************** ------- PLANT: I nr* A T i nn . L. W V>/~\ I I VJ I* • OPERATOR: RESERVE I.I AC Tr TABLE 11 MINING CO SILVER BAY, MINN. ACK, PELLET IZER NO. 5, ENVIORNMENTAL PROTECTION AGENCY TOTAL PARTICIPATE PART ICULATE SUMMARY IN ENGLISH UNITS DESCRIPTION UNITS DATE OF RUN STACK AREA FT2 NET TIME OF RUN MIN BAROMETRIC PRESSURE IN.HG AVG ORIFICE PRES DROP IN.H20 VOL DRY GAS-METER COND DCF AVG GAS METER TEMP DEG.F VOL DRY GAS-STD COND DSCF TOTAL H20 COLLECTED ML VOL H20 VAPOR-STD COND SCF PERCENT MOISTURE BY VOL MOLE FRACTION DRY GAS PERCENT C02 BY VOL, DRY PERCENT 02 BY VOL, DRY PERCENT CO BY VOL, DRY PERCENT N2 BY VOL, DRY . MOLECULAR WT-DRY STK GAS MOLECULAR WT-STK GAS AVG STACK TEMPERATURE • DEG.F NET SAMPLING POINTS STACK PRESSURE, ABSOLUTE IN.HG AVG STACK GAS VELOCITY FPS STK FLOWRATE, DRY,STD CN DSCFM ACTUAL STACK FLOWRATE ACFM PERCENT ISOKINETIC PART ICULATE WT-PARTIAL MG PART ICULATE WT-TOTAL MG PERC IMPINGER C#TCH PART. LOAD-PTL/STD CN GR/DSCF PART. LOAD-TTL,STD CN GR/DSCF PART. LOAD-PTL,STD CN @ 12% C02 PART. LOAD-TTL,STD CN @ 12% C02 PART. LOAD-PTL,STK CN GR/ACF PART. LOAD-TTL,STK CN GR/ACF PARTIC EMIS-PARTIAL LB/HR PART 1C EMIS-TOTAL LB/HR PART EMIS/WT PRO FD PTL LB/TON EMIS/WT PRO FD TTL LB/TON PART PERCENT EXCESS AIR 6 09-12-73 27.882 37. 0 29.28 1.850 29.90 73.2 29.21 53.3 2.55 8.0 0.920 0.8 20.0 0.0 79.2 ••> o 01 £. 0 • Cl J 28.05 356.8 1 29.1U 118.936 115621. 198972. 105.4 294.30 294.30 0.0 0.15514 0.15514 2.32712 2J32712 0.09010 0.09010 153.75 153.75 1. 27068 1.27068 2200.7 AVERAGE 118.936 115621. 198972. 105.4 294.30 294.30 0.0 0.15514 0.15514 2.32712 2.32712 0.09010 0.09010 153.75 153.75 1.27068 1.27068 2200.7 ------- TABLE 12 PLANT: RESERVE MINING CO., SILVER BAY, MINN. LOCATION: HOOD VENT STACK, PELLETIZER MO. 5, TOTAL PARTICULATE EMISSIONS OPERATOR: ENV!ORNMENTAL PROTECTION AGENCY PARTICULATE SUMMARY IN ENGLISH UNITS DESCRIPTION DATE OF RUN STACK AREA NET TIME OF RUN BAROMETRIC PRESSURE AVG ORIFICE PRES DR VOL DRY GAS-METER C AVG GAS METER TEMP VOL DRY GAS-STD COND TOTAL H20 COLLECTED VOL H20 VAPOR-STD C PERCENT MOISTURE BY MOLE FRACTION DRY G PERCENT C02 BY VOL, PERCENT 02 BY VOL, PERCENT CO BY VOL, PERCENT N2 BY VOL, MOLECULAR WT-DRY ST MOLECULAR WT-STK GA AVG STACK TEMPERATURE NET SAMPLING POINTS STACK PRESSURE, ABS AVG STACK GAS VELOC STK FLOWRATE, DRY,S ACTUAL STACK FLOWRATE PERCENT ISOKINETIC PARTICULATE WT-PAR PARTICULATE WT-TOTAL PERC IMPINGER CATCH PART. LOAD-PTL,STD PART. LOAD-TTL,STD PART,, LOAD-PTL,STD PART., LOAD-TTL,STD PART., LOAD-PTL,STK PART,, LOAD-TTL,STK PART 1C EM IS-PARTIAL PART 1C EMIS-TOTAL PART EMIS/WT PRO FD PART EMIS/WT PRD FD PERCENT EXCESS AIR OP OND D OND VOL AS DRY DRY DRY DRY K GAS S RE OLUTE ITY TD CN TE IAL L CN CN CN @ CN @ CN CN > PTL ' TTL UNITS • FT2 MIN 1 M . HG IN.H20 DCF DEG.F DSCF ML SCF DEG.F IN.HG FPS DSCFM ACFM MG MG GR/DSCF GR/DSCF 12% C02 12% C02 GR/ACF GR/ACF LB/HR LB/HR LB/TON LB/TON 10 - 09-13-73 27.688 36.0 29.34 1.200 23.10 78.1 22.37 31.2 1.48 6.2 0.938 0.0 21.0 0.0 79.0 28.84 28.17 248.0 1 29.24 83.800 95509. 139214. 99.7 81.10 81.10 0.0 0.05582 0.05582 **** * **4 AVERAGE 83.800 95509. 139214. 99.7 81.10 81.10 0.0 0.05582 0.05582 ***** ************** 0.03828 0.03828 45.70 45.70 0.33357 0.33357 0.03828 0.03828 45.70 45.70 0.33357 0.33357 **************** IH ------- PLANT: RESERVE MINING COMPANY; SILVER BAY, MINNESOTA : .-..- ."..- :/•.?.!_ r: : MC rr>\ ;c i!rt? :T n. r.<-; i 1 r\ ~<"AT A ; AC a CCTOC CM i CC L. vv w M i I w 1-4 • t i 111_ \s , \^ ^ » t» v • .,»-.. i i. v , :*:.—. i- r-. .-..• i ..-•-• t-r • • • • •_• OPERATOR: ENVIROMMENiAL PROTECTION AGENCY TABLE 13 PART ICULATE SUMMARY IN ENGLISH UNITS DESCRIPTION DAT.E OF RUN UNITS 9-11-73 AVERAGE STACK AREA FT2 NET TIME OF RUN MIN BAROMETRIC PRESSURE IN.HG AVG ORIFICE PRES DROP IN.H20 VOL DRY GAS-METER COND DCF AVG GAS METER TEMP DEG.F VOL DRY GAS-STD COND DSCF TOTAL H20 COLLECTED ML VOL H20 VAPOR-STD COND SCF PERCENT MOISTURE BY VOL MOLE FRACTION DRY GAS PERCENT C02 BY VOL, DRY PERCENT 02 BY VOL, DRY PERCENT CO BY VOL, DRY PERCENT N2 BY VOL, DRY MOLECULAR WT-DRY STK GAS MOLECULAR WT-STK GAS AVG STACK TEMPERATURE DEG.F NET SAMPLING POINTS STACK PRESSURE/ ABSOLUTE IN.HG AVG STACK GAS VELOCITY FPS STK. FLOWRATE, DRY/STD CN DSCFM ACTUAL STACK FLOWRATE ACFM PERCENT ISOKINETIC PART ICU LATE WT- PARTIAL MG PART ICU LATE WT-TOTAL MG PERC IMPINGER CATCH PART. LOAD-PTL/STD CN GR/DSCF PART. LOAD-TTL,STD CN GR/DSCF PART. LOAD-PTL,STD CN @ 12% C02 PART. LOAD-TTL/STD CN @ 12% C02 PART. LOAD-PTL/STK CN GR/ACF PART. LOAD-TTL,STK CN GR/ACF PART 1C EMIS-PARTIAL LB/HR PART 1C EMIS-TOTAL LB/HR PART EMIS/WT PRO FD PTL LB/TON PART EMIS/WT PRO FD TTL LB/TON PERCENT EXCESS AIR 3.976 120.0 29.10 ' 1.760 93.70 84.6 89.06 19.2 0.91 1.0 0.990 0.0 21.0 0..0 79.0 28.84 28.73 60.7 1 29.10 71.214 16644. 16989. 98.1 1.65 1.65 0.1 0.00029 0 0.00029 0 71.214 16644. 16989. 98.1 1.65 1.65 0.1 .00029 .00029 **************** ************** 0.00028 0 0.00028 0 0.04 0.04 0.00009 0 0.00009 0 ******** .00028 .00028 0.04 0.04 .00009 .00009 **** ------- TABLE. 14 PLANT: RESERVE MINING CO., SILVER BAY, MINN. LOCATION: WASTE GAS STACK, PELLETiZER NO. 5, TOTAL ASBESTOS EMISSIONS OPERATOR: ENVIORNMENTAL PROTECTION AGENCY PARTICIPATE SUMMARY IN ENGLISH UNITS DESCRIPTION DATE OF RUN STACK AREA NET TIME OF RUN BAROMETRIC PRESSURE AVG ORIFICE PRES DROP VOL DRY GAS-METER COND AVG GAS METER TEMP VOL DRY GAS-STD COND TOTAL H20 COLLECTED VOL H20 VAPOR-STD COND .PERCENT MOISTURE BY VOL MOLE FRACTION DRY GAS PERCENT C02 BY VOL, DRY PERCENT 02 BY VOL, DRY PERCENT CO BY VOL, DRY PERCENT N2 BY VOL, DRY MOLECULAR WT-DRY STK GAS MOLECULAR WT-STK-GAS AVG STACK TEMPERATURE NET SAMPLING POINTS STACK PRESSURE, ABSOLUTE AVG STACK GAS VELOCITY STK FLOWRATE, DRY,STD CN ACTUAL STACK FLOWRATE PERCENT ISOKINETIC PART ICULATE WT-PARTIAL PARTICIPATE WT-TOTAL PERC IMPINGER CATCH. PART. LOAD-PTL,STD CN PART. LOAD-TTL,STD CN PART. LOAD-PTL,STD CN @ PART. LOAD-TTL,STD CN @ PART. LOAD-PTL,STK CN PART. LOAD-TTL,STK CN PART 1C EM IS-PARTIAL UNITS FT2 MIN .1 N. HG IN.H20 DCF DEG.F DSCF ML SCF PART 1C EMIS-TOTAL PART EMIS/WT PRD'FD PART EMIS/WT PRO FD PERCENT EXCESS AIR PTL TTL DEG.F I N. HG FPS DSCFM ACFM MG MG GR/USCF G"R/D,S£.F 1 0 ft •;• f>-f- -t • X £ 'j Vj* vr* /j 12% C02 GR/ACF GR/ACF LB/HR LB/HR IB/TON LB/TON 6 09-12-73 27.882 37.0 29.28 1.850 29.90 73.2 29.21 53.8 2.55 8.0 0.920 0.8 20.0 • 0.0 £73., '2 28.93 28.05 * 356.8. 1 29.U 118.936 115621. 198972. 105.U 0.67 0.67 0.0 0.00035 0.0-0035 0.00528 0.00528 0.00020 0.00020 0.35 0.35 0.00288 0.00288 2200.7 AVERAGE 118.936 115621. 198972. 105.1* 0.67 0.67 0.0 0.00035 0.00035 0.00528 0.00528 0.00020 0.00020 0.35 0.35 0.00288 0.00288 2200.7 20 ------- TABLE 15 PLANTS RESERVE MINING CO., SILvtR BAY, MINN. LOCATION: HOOD VENT STACK', PELLETIZER NO. 5, TOTAL ASBESTOS EMISSIONS OPERATOR: ENVIORNMENTAL PROTECTION AGENCY PARTICULATE SUMMARY IN ' ENGLISH UNITS DESCRIPTION DATE OF RUN STACK AREA NET TIME OF RUN BAROMETRIC PRESSURE AVG ORIFICE PRES DR VOL DRY GAS-METER C AVG GAS METER TEMP. VOL DRY GAS-STD COND TOTAL H20 COLLECTED VOL H20 VAPOR-STD C PERCENT MOISTURE BY MOLE FRACTION DRY G PERCENT C02 BY VOL, PERCENT 02 BY VOL, PERCENT CO BY VOL, PERCENT N2 BY VOL, MOLECULAR WT-DRY ST MOLECULAR WT-STK GA AVG STACK TEMPERATURE NET SAMPLING POINTS STACK PRESSURE, ABS AVG STACK GAS VELOC STK FLOWRATE, DRY,S ACTUAL STACK FLOWRATE PERCENT ISOKINETIC PARTICULATE WT-PAR PARTICULATE WT-TOTAL PERC IMPINGER CATCH PART. LOAD-PTL,STD PART. LOAD-TTL,STD PART. LOAD-PTL,STD PART. LOAD-TTL,STD PART. LOAD-PTL,STK PART. LOAD-TTL,STK PART 1C EM IS-PARTIAL PART 1C EMIS-TOTAL PART EMIS/WT PRO FD PART EMIS/WT PRD FD PERCENT EXCESS AIR OP OND D OND VOL AS DRY DRY DRY DRY K GAS S RE OLUTE ITY TD CN TE IAL L CN CN CN @ CN @ CN CN PTL TTL UNITS . FT2 MIN IN.HG IN.H20 DCF DEG.F DSCF ML SCF DEG.F IN.HG FPS DSCFM ACFM MG MG GR/DSCF GR/DSCF 12? C02 12% C02 GR/ACF GR/ACF LB/HR LB/HR LB/TON LB/TON 10 09-13-73 27.688 36.0 29.31* 1.200 23.10 78.1 22.37. 31.2 1 . I* 8 6.2 0.938 0.0 21.0 0.0 79.0 28. 8U 28.17 218.0 1 29.21 83.800 95509. 139211. 99.7 0.2U 0.21 0.0 0.00016 0.00016 AVERAGE 83.800 95509. 1392U. 99.7 0.21* 0.2t* 0.0 0.00016 0.00016 **************** ************** 0.00011 0.00011 0.13 0.13 0.00098 0.00098 0.00011 0.00011 0.13 0.13 0.00098 0.00098 ************** 21 ------- PLANT: .RESERVE MINING COMPANY; SILVER BAY, MINNESOTA LOCATION: FINE CRUSHER STACK 110, AMPHIBOLE ASBESTOS EMISSIONS OPERATOR; ENVIRONMENTAL PROTECTION AGENCY PART ICULATE SUMMARY IN ENGLISH UNITS DESCRIPTION DATE OF RUN STACK AREA NET TIME OF RUN BAROMETRIC PRESSURE AVG ORIFICE PRES DROP VOL DRY GAS-METER COND AVG GAS METER TEMP VOL DRY GAS-STD COND TOTAL H20 COLLECTED VOL H20 VAPOR-STD COND PERCENT MOISTURE BY VOL MOLE FRACTION DRY GAS PERCENT C02 BY VOL, DRY PERCENT 02 BY VOL, DRY PERCENT CO BY VOL, DRY PERCENT N2 BY VOL, DRY MOLECULAR WT-DRY STK GAS MOLECULAR WT-STK GAS AVG STACK TEMPERATURE NET SAMPLING POINTS STACK PRESSURE, ABSOLUTE AVG STACK GAS VELOCITY STK FLOWRATE, DRY,STD CN ACTUAL STACK FLOWRATE PERCENT ISOKINETIC •PART I CU LATE WT-PARTIAL PART ICULATE WT-TOTAL PERC IMPINGER CATCH PART. LOAD-PTL,STD CN PART. LOAD-TTL/STD CN PART. LOAD-PTL,STD CN @ PART. LOAD-TTL,STD CN @ PART. LOAD-PTL,STK CN PART. LOAD-TTL,STK CN PART 1C EMIS-PARTIAL PART 1C EMIS-TOTAL PART EMIS/WT PRO FD PTL PART 'EMIS/WT PRO FD. TTL PERCENT EXCESS AIR UN 1 TS FT2 MIN ' IN.HG IN.H20 DCF DEG.F DSCF ML ._.. SCF . DEG.F : IN.HG FPS i DSCFM ACFM MG MG GR/DSCF GR/DSCF 12% C02 12% C02 GR/ACF GR/ACF LB/HR LB/HR LB/TON LB/.TON 3. 9-11-73 3.976 120.0 29.10 1.760 93.70 8U.6 89.06 19.2 0.91 "" 1.0 0.990 0.0 21.0 0.0 79.0 " 28.8U 28.73 60.7 1 29.10 71. 2U 1.66UI4. 16989. 98.1 1.65 1.65 0.1 0.00029 0.00029 ***** ******* 0.00028 0.00028 O.OU 0.01* 0.00009 0.00009 AVERAGE. . • . ... ...... . . .. . . - . .... • ._. .. . _. . . -.- 71.2lk 166^4. ' . 16989. 98.1 1.65 1.65 0.1 0.00029 0.00029 ******* ******* 0.00028 0.00028 o.ou 0.01* 0.00009 — 0.00009 **************** 00 LA i- ------- PLANT: RESERVE MINING CO., SILVER BAY, MINN. LOCATION: WASTE GAS STACK, PELLETIZER NO. 5, AMPHIBOLE EMISSIONS OPERATOR: ENVIORNMENTAL PROTECTION AGENCY PART ICULATE SUMMARY IN ENGLISH UNITS DESCRIPTION • . DATE OF RUN STACK AREA NET TIME OF RUN BAROMETRIC PRESSURE AVG ORIFICE PRES DROP ! VOL DRY GAS-METER COND AVG GAS METER TEMP VOL DRY GAS-STD COND TOTAL H20 COLLECTED VOL H20 VAPOR-STD COND PERCENT MOISTURE BY VOL MOLE FRACTION DRY GAS PERCENT C02 BY VOL, DRY PERCENT 02 BY VOL, DRY PERCENT CO BY VOL, DRY PERCENT N2 BY VOL, DRY MOLECULAR WT-DRY STK GAS MOLECULAR WT-STK GAS AVG STACK TEMPERATURE NET SAMPLING POINTS STACK PRESSURE, ABSOLUTE AVG STACK GAS VELOCITY STK FLOWRATE, DRY,STD CN ACTUAL STACK FLOWRATE PERCENT ISOKINETIC PARTICULATE WT-PARTIAL PART ICULATE WT-TOTAL PERC IMPINGER CATCH PART. LOAD-PTL,STD CN PART. LOAD-TTL,STD CN PART. LOAD-PTL,STD CN @ PART. LOAD-TTL,STD CN @ PART. LOAD-PTL,STK CN PART. LOAD-TTL,STK CN PART 1C EM IS-PARTIAL UNITS FT2 MIN I N. HG N.H20 DCF DEG.F DSCF ML SCF PARISC EM!S-TOTAL PART EMIS/WT PRO FD PTL PART EMIS/WT PRO FD TTL PERCENT EXCESS AIR DEG.F I N. HG FPS DSCFM ACFM MG MG GR/DSCF GR/DSCF 12% C02 12% C02 GR/ACF GR/ACF LB/HR L5/HP. LB/TON LB/TON 6 09-12-73 27.882 37.0 29.28 1.850 29.90 73.2 29.21 53.8 2.55 8.0 0.920 0.8 20.0 0.0 79.2 28.93 28.05 356.8 1 29.14 118.936 115621. 198972. 105.4 0.64 0.64 0.0 0.00034 0.00034 0.00510 0.00510 0.00020 0.00020 0.34 0.34 0.00278 0.00278 2200.7 AVERAGE 118.936 115621. 193972. 105.4 0.64 0.64 0.0 0.00034 0.00034 0.00510 0.00510 0.00020 0.00020 0.34 n . 311 0.00278 0.00278 2200.7 23 ------- TABLE 18 PLANT: RESERVE MINING CO., SILVER BAY, MINN. LOCATION; HOOD VENT STACK,PELLETiZER NO. 5, AMPHIBOLE OPERATOR: ENVIORNMENTAL PROTECTION AGENCY EMISSIONS PART ICULATE SUMMARY IN ENGLISH UNITS DESCRIPTION UNITS DATE OF RUN STACK AREA FT2 NET TIME OF RUN MIN BAROMETRIC PRESSURE IN.HG AVG ORIFICE PRES DROP IN.H20 VOL DRY GAS-METER COND DCF AVG GAS METER TEMP DEG.F VOL DRY GAS-STD COND DSCF TOTAL H20 COLLECTED ML VOL H20 VAPOR-STD COND . SCF PERCENT MOISTURE BY VOL MOLE FRACTION DRY GAS PERCENT C02 BY VOL, DRY PERCENT 02 BY VOL, DRY PERCENT CO BY VOL, DRY PERCENT N2 BY VOL, DRY •«• ;-• •: " MOLECULAR WT-DRY STK GAS MOLECULAR WT-STK-GAS AVG STACK TEMPERATURE NET SAMPLING POINTS STACK PRESSURE, ABS AVG STACK GAS VELOCITY STK FLOWRATE, DRY,STD ACTUAL STACK FLOWRATE PERCENT ISOKINETIC PARTICULATE WT-PARTIAL PARTICULATE WT-TOTAL PERC IMPINGER CATCH PART. LOAD-PTL,STD C PART. LOAD-TTL,STD C PART. LOAD-PTL,STD C PART. LOAD-TTL,STD C PART. LOAD-PTL,STK C PART. LOAD-TTL,STK C PART 1C EM IS-PARTIAL PART 1C EMIS-TOTAL PART EMIS/WT PRO -FD PART EMIS/WT PRO FD PERCENT EXCESS AIR 10 09-13-73 27.688 36.0 29.34 1.200 23.10 78.1 22.37 31.2 1.48 6.2 0.938 0.0 21.0 0.0 AVERAGE IE DEG.F ILUTE IN.HG TY FPS 'D CN DSCFM 'E ACFM AL MG MG :N GR/DSCF !N GR/DSCF - :N @ 12% C02 IN @ 12% C02 IN GR/ACF IN 'GR/ACF LB/HR LB/HR PTL IB/TON TTL LB/TON 28.17 248.0 1 29.24 83.800 95509. 139214. 99.7 0.24 0.24 0.0 0.00016 --XL-OOP 16 83.800 95509. 139214. 99.7 0.24 0.24 0.0 0.00016 0.00016 ************** ************** 0.00011 0.00011 0.13 0.13 0.00098 0.00098 0.00011 0.00011 0.13 0.13 0.00098 0.00098 **************** 24 ------- SUMMARY AND DISCUSSION OF PROCESS SAMPLE ANALYSIS Process samples were obtained at two locations on the same days that the stacks at these respective facilities were tested. Samples of the output from this crusher group were collected at the discharge of the conveyor in the concentrator building on September 11, 1973. It was not possible to sample the output from an individual crusher set. Samples were taken using the established plant sampling technique. A sampling pan, about 1 1/2" wide x 12" long, x 12" deep, was inserted in the belt discharge stream at the middle and both sides. Duplicate samples were taken, one for EPA and one retained by the company. Samples were taken every hour on the hour from 8:00 a.m. to 3:00 p.m. Samples of the green.p.el.lets were taken on September 12, 1974, from -':\.. '• '• 2:'.'"."":'™ - .'Jr. . .•: the three conveyor belts wbJch, discharge .to the conveyor which feeds this pelletizer. Samples were taken every hour on the hour from 10:00 a.m. to 5:00 p.m. inclusive. Duplicate samples were taken for EPA and the company. A report of the analysis of these samples has been prepared separately and is entitled "Sample Process Material at Taconite Plant" final report Task 22, Contract No. 68-02-0230, by R. J. Kuryvial and C. W. Metton, February 1974. This report is%v#s8&Me"Tfrom the Office of Technical Analysis, EPA. or: ------- PROCESS DESCRIPTION A schematic flow diagram of the process is attached (Figure III-l). The ore is received in railroad cars from the mine where it has been crushed to minus 4-inch size. The ore is crushed to minus 3/4-inch size by cone type crushers. It is then ground wet in rod mills and ball mills and separated by magnetic separators into concentrate and tailings. The tailings ar,e pumped into Lake Superior. The concentrate is mixed with a small amount of bentonite clay and introduced into large rotating drums which roll it into balls of about 1/2" diameter. The balls are fed into a traveling grate pelletizing machine where they are first dried, then heated to over 2200°F, passed through an oxidizing -section, then a cooling section. This transforms them into hard pellets, ideally suited for blast f ;Y^££,;£eec!, The raw ore is about 24 ;percent iron and the'concentrate if 65 percent iron. The asbestos type mineral in the ore is said to be amosite and said to range from 20 to 30 percent in content. Detailed descriptions of the operations and controls are given in the following sections. a. Car Dumping and Fine Crushing The ore is received frora .the.uiifie..in railroad ore cars. It has been crushed at the mine to minus 4-inch size. A rotary car dumper lifts two cars at a time and dumps their contents into two receiving pits. Water sprays are actuated when cars are being dumped to suppress dust emissions. The pits are each ventilated by a fan of 50,000 cfm capacity which is vented to a multiple cyclone collector (multiclone). ------- From the dump pits the-ore is fed to a belt conveyor, and transported to storage bins in the fine crusher building. From the storage bins, a system of belt conveyors delivers the ore to ten sets of crushers in parallel. Each set.consists of two cone type-crushers, in series,'with a vibrating screen between the crushers. The ore is crushed to minus 3/4-inch size. The conveyor belt transfer points are controlled by ten multiclones, each with its own stack. Each of the ten sets of crushers, with its screens, is controlled by a Type W Rotoclone. The crushers discharge to two belt conveyors which deliver the crushed ore to two transfer bins in the concentrator building. These bins transfer the ore to two conveyors which discharge to 22 storage bins, each of which feeds a rod mill. The transfer points in this system are vented by 24 multiclones, each with its own stack. Water is added at the rod mills and all the subsequent grinding, magnetic separation and regrinding is done in slurry form. b. The Palletizing Furnaces There are eight furnaces which bake the moist iron oxide balls from the balling drums, turning them into hard FepCU (hematite) pellets, suitable for blast furnace feed. Furnaces 1 - 6 operate at about 135 wet tons/hr. Furnaces 11 and 12 are larger and operate at about 290 wet tons/hr. The amount of bentonite additive in the moist balls is very small, only in the range of 18 - 27 Ibs/hr. The moist load disappears into the totally enclosed furnace where it first contacts about 90,000 scfm of hot combustion gases recirculated 27 ------- from the ignition section. This gas passes upward through the ball bed and exits from the "hood stack"'at about 225°F. The balls are thus gently dried, then they move into an ignition section. Here, several oil burners force combustion gases downward through the bed and maintain a temperature of about 2350°F on top of the bed. The hot air from this operation plus part of the drying hot air is discharged at about 400 - 500°F through the waste gas stack and amounts to about 110,000'scfm. A following section is called the "induration section," where no oil is burned, but where an exothermic reaction with oxygen of the air occurs and heats all the bed to 1 . a yellow heat. This is due to oxidation of ferrous iron at the bed tempera- ture. 4 (Fe 0. Fe203) + 02 -• 6 Fe2 03 magnetite hematite Other forms of ferrous iron are also oxidized. Air passes downward through the bed. The exhaust from these sections is reused in the drying and ignition sections. The final operation is cooling of the pellet bed. Air goes downward and is partly reused for drying and partly discharged from the second stage cooling stack at about 20,000 scfm. The plant produces ten million tons/yr of pellets. The gas emission from all eight pelleting furnaces is 1,900,000 scfm. There are no emission controls. There are six stacks per furnace on the roof of the pelletizing furnace building. They are, in order: hood exhaust; waste gas; recuperation (capped); 1st stage cooler; 2nd stage cooler; pellet dump end. 9 P ------- PROCESS OPERATION DURING TEST a. Fine Crusher Test. 9-11-73 The ten sets of crushers are-divided into two groups. Each group discharges to a belt conveyor which delivers the crushed ore to the concentrator building. Each crusher set consists of the following items in series: a vibrating screen, a primary cone crusher, a vibrating screen, a secondary cone crusher. Each of these four devices is enclosed and all vented to a Type W Rotoclone, size 30. The crusher set tested was no. 104. The dust collector .was no. 110. The feed rate to the crusher was measured and recorded on a circular chart. The readings fluctuated considerably. An eye-ball average was made of the chart traces for the following periods, in tons per hour: 11:00 - 11:00 : 550 3:00 - 4:00 : 500 11:00 - 12:00 : 500 4:00 - 5:00 : 450 1:00 - 2:00 : 600 5:00 - 6:00 : 450 2:00 - 3:00 : 550 Opacity readings of the collector stack were read at various times. Readings were made with the sun at my back. Readings were recorded at the following times: 10:00 : 15% 4:00 : 10% 10:30 : 15% 4:30 : 10% 1:30 : 10% 5:00 : 10% 2:30 : 10% 5:30 : 10% 3:30 : 10% When the plume was observed looking towards the sun, the opacity appeared to be very much greater. ------- b. Pelletizing Furnace Stack Test. 9-12-73 The flue gas (waste gas) stack was sampled on September 12, 1973. The unit tested was pelletizer no. 5. This unit and two others had been modified by the addition of ,a. roll screen to remove fines from the green pellet feed in an effort to reduce emissions. The pelletizer operator recorded the average feed rate each hour. The following readings, in tons per hour, were taken from his log sheet: 9:00 - 10:00 : 137 2:00 - 3:00 : 115 10:00 - 11:00 : 137 3:00 - 4:00 : 121 11:00 - 12:00 : 135 4:00 - 5:00 : 121 12:00 - 1:00 : 132 5:00 - 6:00 : 131 1:00 - 2:00 : 120 6:00 - 7:00 : 136 Opacity readings were taken at various times from the roof, with the. ."if ' • -. -- X/ -.." sun to the observer's back. It was noted that the position of the sun made little difference in thc.^:7;r.^;-.#te?-a<:-7.:-:«ts4l:;-the plume. The weather was clear and cool with a breeze estimated as 15 MPH. The following opacities were recorded: 10:30 : 15% 5:10 : 5% 11:15 : 15% 6:15 : 5% 11:30 : 10%' 6:30 : 5% 3:15 : 10% 7:00 : 5% 3:45 : 10% 30 ------- c. Dryer (hood) Stack Test.- 9-13-73 The pellet feed rates in tons per hour from the operator's log sheet were as follows: 6:00 - 7:00 : 134 . 11:00 - 12:00 : 13.3 • ... '. 7:00 - 8:00 : 136 . 12:00 - 1:00 : 137 8:00 -.9:00 : 132 1:00 - 2:00 : 138 9:00 -10:00 : 136 2:00 - 3:00 : 137 10:00 -11:00 : 134 Visible emissions from the stack were very light. The weather was clear and cool with a brisk wind. The following opacity readings were recorded: 10:00 a.m. 10:15 10:30 10:40 10:50 11:00 11:15 12:10 p.m. 12:30 12:40 Visible emissions from the stacks of the other pelletizers were casually observed, but not recorded. Nearly all the other pelletizers had emissions of greater opacity than the one being tested. Several had emissions which were in the range of 15-30% opacity most of the time, with occasional periods of much higher rates — up to 100% opacity for a few minutes, several times' a day. 31 5% 0 5% 5% 0 0 5% 5% 5% 5% 12:50 p.m. 2:00 2:15 2:30 2:45 2:50 2:53 2:55 3:00 : 5% : 5% : 0 : 0 : 0 :10% :15% : 0 : 0 ------- d. Concentrator Stack Test. 9-13-/3 Collector system no. 118 in the East Concentrator Building was tested in the late afternoon of September 13, 1973. No ore samples were collected, and no material flow rates were available. However, the average discharge rate of each bin is about 160 tons/hr. based on an average of 85,000 tons/day of ore received at the plant. No visible emissions were observed from the stack being tested, nor from any of the other 21 stacks in, the two concentrator buildings. The ore appeared to be damp and no visible dust was observed when the tripper was filling a bin. ------- LOCATION OF SAMPLING POINTS 1. Fine Crusher No. 10 Sampling was conducted downstream of the Rotoclone serving the number 104 fine crusher set, on s-tack No. 110.. . The ports-were . . . . located 127" (4.7 diameters) downstream of the nearest disturbance' and 24" (0.89 diameters) upstream of the exit to the atmosphere. The 27" diameter crossection was divided into 16 equal areas and sampling was to be conducted at the centroid of each area. However, since the outmost points on each diameter were less than 1 inch from the stack wall, sampling was not conducted at point 1 and 8 on each diameter. Method 1 (Federal Register, Vol. 36, No. 247, December 23, 1971) requires 36 sampling points for a location such as was available here; however, only a 12-point traverse was used. Because of the relatively small stack diameter, the reduction of traverse points should not effect the represen- tativeness of the sample. 2. Haste Gas Stream, Pelletizer No. 5 Sampling was conducted on the uncontrolled waste gas stream at a location approximately 75' (~12 diameters) downstream of the nearest disturbance and 50' (~8 diameters) upstream of the exit to the atmosphere. The 71 1/2-inch diameter stack was divided into 12 equal areas and sampling was conducted at the centroid of each equal area. 3. Hood Vent Exhaust, Pelletizer No. 5 Sampling was conducted on the uncontrolled stack serving the hood vent stream at a location approximately 48' (8.1 diameters) downstream of the nearest disturbance and 40' (6.8 diameters) upstream of the exit to 33 ------- the atmosphere. The 71 1/4" diameter cross-section was divided into 12 equal areas and sampling was conducted .at the centroid of each equal area. 4. Concentrator Location-.. •• • • . -..'.•' .-.•••••• Sampling was conducted on the control system No. 118 serving the No. 11 and 12 bins and their'conveying systems. The sampling ports were located 32' (9.8 diameters) downstream of the nearest disturbance and 26' (7.8 diameters) upstream of the exit to the atmosphere. The 39 3/4" diameter cross-section was divided into 12 equal areas and sampling was conducted at the centroid of each'equal area. Vi U '•ji ------- SAMPLING AND ANALYTICAL PROCEDURES The procedures used to collect the samples were essentially identical to those outlined in Method 5 (Federal Register, December 23, 1971) with the .following exceptions: . ... .... 1. A Mi Hi pore type AA membrance filter was substituted for the MSA 1196 BH glass fiber filter. 2. Filter and probe heating was not maintained at 225°F since maximum temperature allowable for the membrane filter is ~200°F. This temperature was maintained at 150-180°F, which was above the dew point of all 'streams sampled. 3. No acetone washings were used in the train cleanup. The probe was washed with water only and was kept separate from the impinger contents and wash. At the fine crusher location sampling was conducted for five minutes at each of 12 traverse points for a total test time of 60 minutes. At the waste gas and- hood vent locations, sampling was conducted for three minutes at each of 12 traverse points for a total run time of 36 minutes for each test. At the concentrator location, sampling was conducted for ten minutes at each of 12 traverse points for a total test time of 120 minutes. Prior to each run, the sampling train was leak-checked and any leakage was corrected prior to the start of testing. After sampling the train was sealed and moved to the cleanup area intact. There it was disassembled and the filter was placed in a glassene envelop and sealed. 35 ------- The probe and front half of the filter holder were washed with distilled, deionized water and placed in a glass shipping bottle. The back half of the filter and the remainder of the impinger train were rinsed with water and added to the impinger contents in a separate shipping bottle. These containers were sealed and packed for shipment. Upon return to the EPA laboratories in Durham, the filters were weighed and the samples were separated for shipment to .several laboratories for analysis. Runs 3, 6, and 10 were sent to Battelle Columbus for asbestos identification and analysis by electron microscope. The complete analysis procedure is given in Appendix C in Battelle's laboratory report, ------- APPENDIX A COMPLETE CALCULATION RESULTS AND SAMPLE CALCULATIONS ------- . TABLE A-l ' PLANT: RESERVE MINING FINE CRUSHER STACK DO.10 LOCATION: SILVER RAY MINN. OPERATOR: EPA SUMMARY IN ENGLISH UNITS DESCRIPTION UNITS DATE OF RUM STACK AREA FT2 NET TIME OF RUN MIN BAROMETRIC PRESSURE IN.HG AVG ORIFICE PRES DROP IM.H20 VOL DRY GAS-METER COND DCF AVG GAS METER TEMP DEG.F VOL DRY.GAS-STD COND DSCF TOTAL H20 COLLECTED ML VOL H20 VAPOR-STD COND SCF PERCENT MOISTURE BY VOL" " MOLE FRACTION DRY GAS . PERCENT C02 BY'VOL, DRY PERCENT 02 BY VOL, DRY -PERCENT CO BY VOL, DRY PERCENT M2 BY VOL, DRY .MOLECULAR VJT-DRY STK GAS MOLECULAR V/T-STK GAS AVG STACK TEMPERATURE DEG.F MET .SAMPLING POINTS STACK PRESSURE, ABSOLUTE IN.HG AVG STACK GAS VELOCITY FPS STK FLOWRATE, DRY,STD CN DSCFM. ACTUAL STACK FLOWRATE ACFM PERCENT ISOKINETIC 1 9-11-73 3.976 60.0 29.08 1.800 16.70 76.2 15.06 13.1 0.62 l.U 0.386 0.0 21.0 0.0 79.0 28. 81* 28.69 67.6 29.08 72.M7 1663U. 17276. ,99. l* 2 9-11-73 3.976 120.0 29.08 1.790 94.90 79.1 91.07 21.3 1.01 1.1 0.989 0.0 21.0 0.0 79.0 28. 8U 28.72 62.0 29.08 71.90U 16738. 17153. 99.8 3 9-11-73 3.976 120.0 29.10 1.760 93.70 8U. 6 89.06 19.2 0.91 1.0 0.990 0.0 21.0 0.0 79.0 28.81* 28.73 60.7 29.10 71.211* 16GUI. 1G989. 98.1 ------- TABLE A-2 PLANT: RESERVE MINING FINE CRUSHER STACK NO.10 LOCATION: SILVER BAY MINN. ' ' . OPERATOR: EPA SUMMARY IN METRIC UNITS • DESCRIPTION UNITS 1 DATE OF RUN 9-11-73 STACK.AREA M2 0.369 NET TIME OF RUN MIN . 60.0 BAROMETRIC PRESSURE MM.HG 738.63 AVG ORIFICE PRES PROP MM.H20 U5.720 VOL DRY GAS-METER COND DM3 1.32 AVG GAS METER TEMP DEG.C 21. 6 VOL DRY GAS-STD COND DNM3 1.28 TOTAL H20 COLLECTED ML 13.1 VOL H20 VAPOR-STD COND NM3 0.02 PERCENT MOISTURE BY VOL . . 1.1* MOLE FRACTION DRY GAS 0.986 PERCENT C02 BY VOL, DRY 0.0 PERCENT 02 BY VOL, DRY 21.0 PERCENT CO BY VOL/ DRY 0.0 PERCENT N2 BY VOL, DRY 79.0 MOLECULAR WT-DRY STK GAS 28.81* MOLECULAR VIT-STK GAS 28.69 AVG STACK TEMPERATURE DEG.C 19.8 MET SAMPLING POINTS STACK PRESSURE, ABSOLUTE MM.HG 738.63 AVG STACK GAS VELOCITY M/S 22.073 STK FLOWRATE, DRY,STD CN DNM3/M 171. ACTUAL STACK FLOV/RATE AM3/M 189. PERCENT ISOKINETIC 99.U 2 9-11-73 0.369 120.0 738.63 15.166 2.69 26.2 2.58 21.3 0.03 1.1 0.989 0.0 21.0 0.0 79.0 28.8U 28.72 16.7 738.63 21.916 171. 486. 99.8 3 9-11-73 0.369 120.0 739. Ik 11. 701* 2.65 29.2 2.52 19.2 0.03 1.0 0.990 0.0 21.0 0.0 79.0 28.8U 28.73 15.9 739.11* 21.706 171. 181. 98.1 AVERAGE 21.898 ' 172. 185. 99.1 ------- • TABLE A-3 PLANT: RESERVE MINING WASTE GAS STACK NO.29 (SHORT RUN DUE TO MOISTURE PROBLEM LOCATION: SILVER BAY MINN. OPERATOR: EPA SUMMARY IN ENGLISH UNITS DESCRIPTION UNITS U AVERAGE DATE OF RUN . 9-12-73 STACK AREA FT2 27.882 --. -- NET TIME OF RUN MIN 20.0 BAROMETRIC PRESSURE IN.HG 29.28 AVG ORIFICE; PRES DROP IN.H20 1.780 -. — VOL DRY GAS-METER COND• DCF 16.70 AVG GAS METER TEMP DEG.F 66.7 VOL DRY GAS-STD COND DSCF ' 16.51 TOTAL H20 COLLECTED ML 30.9 VOL H20 VAPOR-STD COND ' SCF 1.U6 PERCENT MOISTURE BY VOL 8.1 MOLE FRACTION DRY GAS 0.919 PERCENT C02 BY VOL, DRY 0.8 PERCENT 02 BY VOL, DRY 20.0 ; • PERCENT CO BY VOL, DRY 0.0 PERCENT H2 BY VOL, DRY 79.2 ' MOLECULAR V.'T-DRY STK GAS 28.93 MOLECULAR WT-STK GAS . - < 28.0^ AVG STACK TEMPERATURE DEG.F 323.0 MET SAMPLING POINTS STACK PRESSURE, ABSOLUTE IN.HG - 29:llr AVG STACK GAS VELOCITY FPS 112.761 112.761 STK FLOK'RATE, DRY,STD CN DSCFM 111201+. 11U20U. ACTUAL STACK FLOWRATE ACFM 188611. 188611. PERCENT ISOKINETIC - 111.6 111,6 ------- TABLE A-4 PLANT: RESERVE MINING HASTE GAS STACK NO.29 (SHORT RUN DUE TO MOISTURE PROBLEM LOCATION: SILVER RAY MINN. OPERATOR: EPA • • . . SUMMARY IN METRIC UNITS DESCRIPTION DATE OF RUN STACK AREA NET TIME OF RUN BAROMETRIC PRESSURE AVG ORIFICE PRES DROP VOL DRY GAS-METER COND AVG GAS METER TEMP VOL DRY GAS-STD COND. TOTAL H20 COLLECTED VOL H20 VAPOR-STD COND PERCENT MOISTURE BY VOL MOLE FRACTION DRY GAS PERCENT C02 BY VOL, DRY PERCENT 02 BY VOL, DRY PERCENT CO CY VOL, .DRY PERCENT N2 BY VOL,- DRY MOLECULAR VJT-DRY STK GAS MOLECULAR VHT-STK GAS AVG STACK TEMPERATURE PET SAMPLING POINTS STACK PRESSURE, ABSOLUTE AVG STACK GAS VELOCITY STK FLOV/RATE, DRY,STD CN "CTI'AL STACK FLOV.'PATE DERCENT ISOKINETIC UNITS AVERAGE 9-12-73 M2 M 1 N MM.HG M.M.H20 . DM3 DEG.C DNM3 ML NM3 DEG.C MM.HG M/S DMM3/M AM3/M 2.590 20.0 7U3.71 - U5.212 O.U7 19.3 O.U7 30.9 0.0l» 8.1 0.919 0.'8 20.0 0.0 79.2 28.93 28. OU 161.7' 7U0.16 5U.370 32314. 53U2. lll.G 3U.370 3234. 53U2. 111.6 ------- TABLE A-5 PLAN": RESERVE f'.INING V?ASTE GAS STACK NO. 29 LOCATION: OPERATOR; SILVER EPA BAY, MINN. SUMMARY IN ENGLISH UNITS DESCRIPTION UNITS DATE OF RUN STACK AREA FT2 NET TIME OF RUN MIN BAROMETRIC PRESSURE IN.HG AVG ORIFICE PRES DROP IN.H20 VOL DRY GAS-METER COND DCF AVG GAS METER TEMP DEG.F VOL PRY GAS-STD COND DSCF TOTAL H20 COLLECTED ML VOL H20 VAPOR-STD COND SCF PERCENT MOISTURE BY VOL MOLE FRACTION DRY GAS PERCENT C02 BY VOL, DRY PERCENT 02 BY VOL, DRY PERCENT CO BY VOL, DRY PERCENT N2 BY VOL, DRY .MOLECULAR V.'T-DRY STK GAS MOLECULAR V/T-STK GAS AVG STACK TEMPERATURE DEG.F NET SAMPLING POINTS STACK PRESSURE, ABSOLUTE IN.HG AVG STACK GAS VELOCITY FPS STK FLOV/RATE, DRY,STD CN DSCFM ACTUAL STACK .FLOWRATE ACFM PERCENT ISOKINETIC 5 9-12-73 27.882 36.0 29.28 1.950 29.00 76.1 28.19 54.6 2.59 8.1 0.916 0.8 20.0 0.0 79.2 28.93 28.01.. 358.6 29.14 118.007 113992. 197417. 106.0 6 9-12-73 < 27.882 37.0 29.28 1.850 29.90 73.2 29.21 53.8 2.55 s;o 0.920 0.8 20.0 0.0 79.2 28.'93 28.05 356.8 29. Ik 118.936 115621. 198972. 105.4 AVERAGE 9-12-73 27.882 36.0 29.28 2.070 30.20 84.7 28.90 63.4 3.01 9.4 0.906 0.8 20.0 0.0 79.2 28.93 27.90 335.1 29.14 120.024 118051. 200792. 104.9 118.989 115888. 199060. 105.5 ------- TABLE A-6 PLANT: RESERVE M I'M I NG 'WASTE GA-S STACK MO.29 LOCATION: SILVER BAY, MINN. OPERATOR: EPA SUMMARY IN METRIC UNITS ' DESCRIPTION UNITS DATE OF RUN STACK AREA - M2 NET TIME OF RUM MIN BAROMETRIC PRESSURE. MM.HG AVG ORIFICE PRES DROP MM.H20 VOL DRY GAS-METER COMD DM3 AVG GAS METER TEMP DEG.C VOL DRY GAS-STD COMD DNM3 TOTAL H20 COLLECTED ML VOL H20 VAPOR-STD COND NM3 PERCENT MOISTURE BY VOL MOLE FRACTION DRY GAS PERCENT C02 BY VOL, DRY PERCENT 02 BY VOL, DRY PERCENT CO BY VOL, DRY .PERCENT H2 RY VOL, DRY MOLECULAR WT-DRY STK GAS .MOLECULAR WT-STK GAS AVG STACK TEMPERATURE DEG.C MET SAMPLING POINTS STACK PRESSURE, ABSOLUTE MM.HG AVG STACK GAS VELOCITY M/S STK FLOWRATE, DRY,STD CN DNM3/M ACTUAL STACK FLOV-'RATE AM3/M PERCENT ISOKINETIC 9-12-73 9-12-73 2.590 36.0 743.71 49.5"30 0.82 2k. 5 0.80 54.6 0.07 8.4 0.916 0.8 ' 20.0 0.0 79.2 28.93 28.01 181.U 710.16 35.968 3228. 5590. 106.0 2.590 37.0 7143.71 46.990 0.85 22.9 0.83 53.8 0.07 8.0 0.920 0.8 20.0 0.0 79.2 28.93 28.05 180.4 710.16 36.252 3274. 5634. 105.4 7 9-12-73 2.590 36.0 7U3.71 52.578 0.86 29.5 0.82 63.4 0.09 9.4 0.906 0.8 20.0 0.0 79.2 28.93 27.90 168.4 740.16 36.583 3343. 5686. 104.9 AVERAGE - - 36.26 3282 5637 105. ------- TABLE A-7 ' " PLANT: RESERVE MINING PELLETIZER HOOD EXHAUST STACK NO.32 LOCATION: SILVER BAY, -MINN. -. . • .• "-v OPERATOR: EPA . . ' . . . SUMMARY IN ENGLISH UNITS DESCRIPTION UNITS DATE OF RUN STACK AREA FT2 NET TIME OF RUN MIN BAROMETRIC PRESSURE IN.HG AVG ORIFICE PRES DROP IN.H20 VOL DRY GAS-METER COND DCF AVG GAS METER TEMP DEG.F VOL DRY GAS-STD COND DSCF TOTAL H20 COLLECTED. ML VOL !!20 VAPOR-STD COND SCF PERCENT MOISTURE BY VOL MOLE FRACTION DRY GAS PERCENT C02 BY VOL, DRY 02 BY VOL, DRY CO BY VOL, DRY N2 BY VOL, DRY WT-DRY STK GAS WT-STK GAS 10. 9-13-73 9-13-73 9-13-73 AVERAGE PERCENT PERCENT PERCENT MOLECULAR MOLECULAR AVG STACK TEMPERATURE DEG.F NET SAMPLING POINTS STACK PRESSURE, ABSOLUTE IN.HG AVG STACK GAS VELOCITY FPS STK FLOWRATE, DRY,STD CN DSCFM ACTUAL STACK FLOWRATE ACFM PERCENT ISOKINETIC 27.688 36.0 29.37 1.250 23.70 81.5 22.81 31.2 1.18 6.1 0.939 0.0 21.0 0.0 79.0 28.81 28.18 237.0 29.27 81.750 98311. H0792. 98.9 27.688 36.0 29.31* 1.260 23.70 76.1* 23.03 30.9 1.16 6.0 0.9UO 0.0 21.0 0.0 79.0 28. 8k 28.19 239.6 29.21 85.789 99183. 112518. 98.9 27.688 36.0 29. 31 1.200 23.10 78.1 22.37 31.2 1.18; 6.2 0.938 0.0 21.0 0.0 79.0 28. 81 28.17 218.0 29.21 83.800 95509. 13921£. 99.7 81.780 97677. 1U0841. 99.1 ------- TABLE A-8 PLANT: RESERVE MIMING PELLETIZER HOOD EXHAUST STACK NO.32 LOCATION: SILVER BAY, MINN. OPERATOR: EPA . . SUMMARY IN METRIC UNITS DESCRIPTION DATE OF RUN STACK AREA NET TIME OF RUN BAROMETRIC PRESSURE AVG ORIFICE PRES DROP VOL DRY GAS-METER COND AVG GAS METER TEMP VOL DRY GAS-STD COND TOTAL H20 COLLECTED VOL H20 VAPOR-STD COND . PERCE?VJT MOISTURE BY VOL MOLE FRACTION DRY GAS PERCENT C02 BY VOL, DRY PERCENT 02 DY VOL, DRY PERCENT CO BY VOL, DRY PERCENT N2 BY VOL, DRY MOLECULAR WT-DRY STK GAS MOLECULAR V.T-STK GAS AVG STACK TEMPERATURE MET SAMPLING POINTS STACK PRESSURE, ABSOLUTE AVG STACK CAS VELOCITY STK FLOWRATE, DP.Y,STD CN ACTUAL STACK FLOWRATE PERCENT ISOKIMETIC UNITS M2 MIN MM.HG MM.H20 DM3 DEG.C DNM3 ML NM3 DEG.C MM.HG M/S DNM3/M AM3/M 8 9-13-73 2.572 36. 0 7U6.nO 31.750 0.67 27.5 0.65 31.2 O.Oi* 6,1 0.939 0.0 21.0 0.0 79.0 28.81* 28.18 113.9 7U3. UP 25.832 2785. 3987. 98.9 9 9-13-73 2.572 36.0 7U5.21* 32.004 0.67 21. 7 0.65 :30.9 O.Oi 6S0 0.940 0.0 21.0 0.0 79.0 28.81* 28.19 115.3 7U2.70 26.119 2809. U036. . . 98.9 ,. 10 9-13-73 2.572 36.0 715.21* 30.180 0.65 25.6 0.63 31.2 o.ot 6,2 0.938 0.0 21.0 0.0 79.0 28.81* 28.17 120.0 712.70 25.512 2705. 39U2. 99.7 AVERAGE 25.811 2766. 3988. 99.1 ------- TABLE A-9 PLANT: RESERVE MINING CONVEYOR STACK NO.20 LOCATION: SILVER BAY, MINN. OPERATOR: EPA SUMMARY IN ENGLISH UNITS DESCRIPTION UNITS . 11 AVERAGE DATE OF RUN 9-13-73 STACK AREA . FT2 8.618 MET TIME OF RUN MIN 120.0 BAROMETRIC PRESSURE IN.HG 29.25 AVG ORIFICE PRES DROP IM.H20 2.600 VOL DRY GAS-METER COND DCF 112.40 AVG GAS METER TEMP DEG.F 63.5 VOL DRY GAS-STD COND DSCF 111.95 TOTAL H20 COLLECTED ML 12.0 VOL H20 VAPOR-STD COND SCF 6.57 . •• PERCENT MOISTURE BY VOL . 0.5 . MOLE FRACTION DRY GAS 0.995 PERCENT CO2 BY VOL, DRY OtO PERCENT 02 BY VOL, DRY 21.0 PERCENT CO BY VOL, DRY 0.0 . PERCENT M2 BY VOL, DRY 79.0 MOLECULAR WT-DRY STK GAS 28.84 MOLECULAR WT-STK GAS .28.79 AVG STACK TEMPERATURE DEG.F 74.7 NET SAMPLING POINTS . . STACK PRESSURE, ABSOLUTE IN.HG 29.21 AVG STACK GAS VELOCITY FPS 52.119 52.119 STK FLOWRATE,, DRY,STD CN DSCFM 25940. 25940. ACTUAL STACK FLOV/RATE ACFM 26949. 26949. PERCENT ISOKINETIC . . 102.9 102.9 ------- TABLE A-'lp' ' PLANT:: RESERVE MINING CONVEYOR STACK MO. 20 LOCATION: SILVER BAY, MINN. OPERATOR: EPA SUMMARY IN METRIC UNITS DESCRIPTION DATE OF RUN STACK AREA MET TIME OF RUN BAROMETRIC PRESSURE AVG ORIFICE PRES DROP VOL DRY GAS-METFR COND AVG GAS METER TEMP VOL'DRY GAS-STD COND TOTAL H20 COLLECTED VOL H20 VAPOR-STD COND PERCENT MOISTURE BY VOL MOLE FRACTION DRY GAS PERCENT C02 BY VOL, DRY PERCENT 02 BY VOL, DRY PERCENT CO BY VOL, DRY PERCENT N2 BY VOL, DRY MOLECULAR NT-DRY STK GAS MOLECULAR VIT-STK GAS AVG STACK TEMPERATURE NET SAMPLING POINTS STACK PRESSURE, ABSOLUTE AVG STACK GAS VELOCITY STK FLOWRATE, DRY,STD CM ACTUAL STACK FLOWRATE PERCENT ISOKINETIC UNITS AVERAGE 9-13-73 . M2 MIN MM.HG MM. H 2.0 DM3 DEG.C DNM3 ML NM3 DEG.C MM.HG M/S DNM3/M AM3/M 0.801 120.0 7U2.95 c e ./»«,.« D O •>•&<. jj -•'• 3=18 17:, 5 3.17 12.0 0.02 0.5 0.995 0.0 21.0 0.0 79.0 28. 81 28.79 23.7 7U1.93 15.886 735. 763. 102.9 15.886 735. 763. 102.9 ------- APPBID1X A. SAMPLE CALCULATIOIIS Nomenclature P. Barometric Pressure, niin. Hg. P Average Orifice Pressure Drop, mm. H?0 T Average.Dry Gas Meter Temperature, °C V Volume of Dry Gas Sampled at Meter Conditions, Am m .^ Volume of Dry Gas Sampled at Standard Conditions , Nm V Total hUO Collected in Impingers and Silica Gel, ml v; , , Volume of Water Vapor Collected at Standard Conditions^ , Nm %M Percent Moisture in Stack -Gas, by Volume M, Hole Fraction Dry Stack Gas %C^2 Percent C0? by volume, dry %0p Percent 0? by volume, dry %CQ Percent CO by volume, dry %Mp Percent N? by volume, dry MW, Molecular Weight of Dry Stack Gas, gm/gm-mole MW Molecular Weight of Wet Stack Gas, gm/gm-mole C ' Pitot Tube Coefficient P • Stack Gas Pressure, mm. Hg., absolute T Stack Gas Temperature, °C D T Average Stack Gas Temperature, °C AP Velocity head, mm. I-LO ^ C. V. Average Stack Gas Velocity, Stack Conditions, Ain/s r> A -Stack Area, in' (1} 3 Q. Stack Gas Flov; Rate at Standard Conditions , dry Nm /min ------- Q Stack Gas Flov/ Rate at Stack Conditions, Anf/nnn a T. Net Time of Test, min. L D Sampling Nozzle Diameter, rnm. ti %l Percent Isokinetic inf Particulate Collected i'n Probe, cyclone and-filter', mg: in,. Total Particulate Collected, mg. u I. Percent of Particulate Caught in Impingers C r Particulate Concentrations at Standard Conditions^ , dry, sf 3 based on probe, cyclone and filter catch, mg/Nm C . Particulate Concentration at Standard Conditions^ , dry, 3 • • • based on total catch, mg/Nm C f Particulate Concentration at Stack Conditions, based on 3 probe, cyclone and filter catch, mg/Am C Particulate Concentration at Stack Conditions, based on total at j catch, nig/Am Ef Particulate Emission Rate, based on probe, cyclone and filter catch, kg/hr E. Particulate Emission Rate, based on total participate catch, kg/hr P Unit Process Rate, Crusher feed rate or Green pellet feed rate, . Mton/hr. PEf Particulate Emission Rate on a Process Basis, probe,-cyclone • and filter catch, kg/_Mtqn PE. Particulate Emission Rate on a Process Basis, total catch kg/ Mton %EA Percent Excess Air in Stack Gas ------- Kun Nu. d 1. Volume of Dry Gas Sampled at Standard Conditions^ ' Vm tH * !'3875 ^n^ (Pb + Vl^l = 0.3875 x 2.65 x(739.1* std • — \|T - 2-^y ^ ( 29.2 1-2731 = 2. 52 Mm3 2. Volume of' Water Vapor at Standard Conditions^ ' Vw = 0.0012 x V = 0.0012 x 19.2 = 0.03 Nm3 gas w 3. Percent. Moisture in Stack Gas by Volume on. 100 X V = 100 x 0-03 _ 1(J ~ ~ l ------- 7. Stack Gar, Velocity at Stack Conditions1^ y A x 106.35 8. Stack Gas Volumetric Flow Rate at Standard Conditions^ , dry n - ?V?q* v. x Ac x M, x Pc 23.25 x 21.7 _ x 0.369 x .99x739.14 ' ~ -- 471 Nin3/min 9. Stack Gas Volumetric Flow Rate at Stack Conditions 2.58 x Qs(Ts + 273) • 2.58 x 471 ( 15.9 + 273) ya PS x Md 739.14 x .99 481 Am3/min 10. Percent Isokinetic . 54,120 x (T + 273) x V x T x P x = 54,120 x ( 15.9+ 273) x 2.52 __ 'zrrr x 120. x 739. 14x .99 x 2 = 98.1 11. Particulate Concentration at Standard Conditions^ , dry, based on probe, cyclone and filter -catch !t_ = 26.7' __ = 10.57 mg/Nm3 " V - .. 2.52 mstd ------- 12. Particulate Concentration at Standard Conditions^ , dry, based on total catch Cst = mt = . 28.48 = . 11.27 mg/Nm3 mstd' ' ' ' : 13. Participate Concentration at Stack Conditions, based on probe, cyclone, and filter catch 0.3875 x Csf x Ps x Md W (Ts + 273) ' ( 15.9 + 273) 10.35 mg/Ani3 14. Particulate Concentration at Stack-Conditions, based on total catch 0.3875 x Csf x Ps x Hd -0.3875x11-27 x 739.14 x -99 11.04 nig/Am" 15. Particulate Emission Rate, based on probe, cyclone, and fil.ter catch Ef = 1,000,000 x C f x Qs = 1,000,000 x 10.57 x 471 --- 0.30 kg/hr 16. Particulate Emission Rate, based on total catch Et = 1,000,000 x C t x Qs = 1,000,000 x H-27 x 471 = 0.32 kg/hr 17. Particulate Emission Rate on a Process Basis, probe, cyclone, and filter catch PEv - _Ef = OJK) = O.OOQ73 kg/Mton crusher feed • "pu 409.5 Mton/hr ------- 18. Participate Emission Rate on a Process Basis, total catch PE Et = 0.032 = 0.00073 kg/Mton crusher feed .* . R~ . ~T69T5. U •:.•••••; ....'•. . • • . . 19. Asbestos emissions calculated in the same manner as Items 11-18. (1) Standard Conditions: 21.1°C, 760 mm. Hg. (2) /~AP>f (Tr + 273) is determined by averaging the square root s of the product of the velocity head (AP ) and the absolute stack temperature (T + 273) at each sampling point. o ------- APPENDIX B Field Data ------- TRAVERSE POINT LOCATION FOR CIRCULAR DUCTS p f r f >'-- f ,y,-;, /"/ J1 PLANT DATE SAMPLING LOCATION -'-•' •• INSIDE OF FAR WALL TO OUTSIDE OF NIPPLE, (DISTANCE A) _ INSIDE OF NEAR WALL TO OUTSIDE OF NIPPLE, (DISTANCE B) _ 'STACK I.D., (DISTANCE A - DISTANCE B). NEAREST UPSTREAM DISTURBANCE NEAREST DOWNSTREAM DISTURBANCE. CALCULATOR ' •.-.•;. 26 •"> •"* t f ~N. J A SCHEMATIC OF SAMPLING LOCATION TRAVERSE POINT NUMBER 1 7. ^ ^ f d r, ' P FRACTION OF STACK 1.0. .6-33 ,/Qv .323 ,(,77 t vS 0 v' <.> cp<- ,4tr STACK I.D. 27" J 7" PRODUCT OF COLUMNS 2 AND 3 (TO NEAREST 1/8 INCH) , 9f dM. z,$3 i' ^-y ^, 72- /§>, ay 2/. 76 23/9 2<^" / ctc&&- - 4- • ^" \ i " i - ii- o =^- ~^ rr j. •^ ^"" i . i V j '. t V \~~ \~ \ \ DISTANCE B r 3" 3" 3" J" 3" 3" J" ^ x^ TRAVERSE POINT LOCATION FROM OUTSIDE OF NIPPLE (SUM OF COLUMNS 4 & 5) — •57fr3 5 ^ ------- NOMOGRAPH DATA PLANT. DATE_ SAMPLING LOCATION ' v. ,• .•> CALIBRATED PRESSURE DIFFERENTIAL ACROSS . ORIFICE, in. H20 AVERAGE METER TEMPERATURE (AMBIENT + 20 °F),°F PERCENT MOISTURE IN GAS STREAM BY VOLUME BAROMETRIC PRESSURE AT METER, in. Hg STATIC PRESSURE IN STACK, in. Hg (Pm±0.073 i STACK GAUGE PRESSURE in in. H20) RATIO OF STATIC PRESSURE TO METER PRESSURE AVERAGE STACK TEMPERATURE, °F AVERAGE VELOCITY HEAD, in. H20 MAXIMUM VELOCITY HEAD, in. H20 C FACTOR CALCULATED NOZZLE DIAMETER, in. ACTUAL NOZZLE DIAMETER, in. REFERENCE Ap, in. H20 AH@ Tmavg. Bwo pm ps Ps/Pm savg. APavg. APmax. /. 72 '6f > >•«. ; ^/.^/ 3$or / 6$ /.^ 1.* 0. ------- FIELD DATA t/ / PLANT K.ts-frt,-e ////,•/, , DATF f-XX-^J- / PROBE LENGTH AND TYPE •^•/r 1 / .- / /r»^y Urpoz<- \ut-T-- SAMPLING LOCATION .'~/,fS /V/.- "',s - S/s . fs TRAVERSE POINT NUMBER _? 3 .~ f. 7 /.'J ,' / / ,V /'/ ./J' SAMPLE TYP RUN NUMBEF OPERATOR AMBIENT TE BAROMETRIC STATIC PRE FILTERNUM \. CLOCK TIME TIME.min ^\ /£££_ ^iJ2- JT ./.r- '£• _5 ' £f — r //? "•— r- 2a -j • / O y . /f> ' '' —~~~. ^S&JJL £" j£ Z- f . /t> ^ •'-'- . -* ~J 3 ' /& ' . 5- /.-> y^- jT ,'J a-~ f <£_£- F /.-••••-.',• ^> i (5PERATURE ."-"-"•' PRFSSIIRF t Q3 NOZZLE I.D ASSUMED MC SAMPLE BOJ METER BOX METER AH^ C FACTOR rt. / S 7. x ISTURF., ". 2 (NUMBER / NUMBER / f j' '--^. f? 7?? PROBE HEATER SETTING HEATER BOX SETTING SCHEMATIC OF TRAVERSE P READ AND RECORD ALL DATA EVERY GAS METER READING ^ ./.5 f-SS-/ 6- ? ('&>$ & S'J, 7 £ $ •>./, J + 6 f- 5" ££t.% ,?£$',<» t & ,f , f /<7J'2- x; 7#-.<5 VELOCITY HEAD (ips), in. H20 /3 /.j /.'/ /.7 /.3-.r Af >- 2 / 2. ^ 6? 70 ?£> /fl ~~- REFERENCE ES xi-o /^T£> An DRY GAS METER TEMPERATURE INLET (Tmin),°F (-£ 7^ X"rf> 7f y? %&> 75 J>L f>3 -'" . ij ••?,(J • ' OUTLET <:-2 72. 7-z 72 72. 72. 73 • 7-? 7Y 7S 75- / . :ll-^'~ PUMP VACUUM, in.Hg jT 5~ •2 z. 7 7 7 £> ^ /\ 7 p 'SAMPLE BOX TEMPERATURE. °F /J^P /•/ • /s-/ /.rs S %- /7/ y^5' • /^7 /•/•/ /•"/ A?/ /^/ * . IMPINGER TEMPERATURE,- °F L ^7 _-2. !' ------- ANALYTICAL DATA PLANT. DATE_ <- v -//- 7 3 SAMPLING .LOCATION SAMPLE TYPE RUN NUMBER SAMPLE BOX NUMBER . CLEAN-UP MAN_/L FRONT HALF WASH OF NOZZLE, PROBE, CYCLONE (BYPASS), FLASK, FRONT HALF OF FILTER HOLDER FILTER NUMBER / c1 8 v c> ------- FIELD DATA PLANT DATE TI_'<" °' PROBE LENGTH AND TYPE. NOZZLE I.D Q. SAMPLING LOCATION yy/v •<• SAMPLE TYPE /'•'•-,••'' RUN NUMBER - /^~ Is- /a .2^ "^-r-^ — -^r- /O '-• ja - 7-- ' j/> ?t£ r'0 2~- > o. T^- ,0 3& GAS METER READING (Vm), It3 ,<7^-/ ' f ?'./ 6 ?2 , 7 7 "/I "!. 0 7 2 5'. J ,!- 73^. 2 71Q. 7 -;<^, 7 7S'/.3 7f~3,3 77J,0> — " " Ttal ?K9 VELOCITY HEAD (Aps), in. H20 /. J /.3f /.1f J.l /z J.I /.2 ).! o.$S 1.0 Z./5- 2.t ORIFICE PRESSURE DIFFERENTIAL (AH), in. H20) DESIRED Lf /,SL /.&l 2Ji 2.0 /.9 J.f /.,?r J.o 3.1* !. &/ •&l (fi^ &l £1 . /^ 2- ^/ ^7 ^ 5- DRY GAS METER TEMPERATURE INLET (Tmjn),"F ------- ANALYTICAL DATA PLANT HATF .< -e r COMMENTS: SAMPLING LOCATION. SAMPLE TYPE _££< RUN NUMBER 2_ T£ SAMPLE BOX NUMBER. CLEAN-UP MAN. FRONT HALF ASEHJNBWASH OF NOZZLE, PROBE, CYCLONE (BYPASS), FLASK, FRONT HALF OF FILTER HOLDER FILTER NUMBER /on 0 O 0 V CONTAINER S-7?'Oov- Jbfa CONTAINER -?• LABORATORY RESULTS mg FRONT HALF SUBTOTAL .mg BACK HALF IMPINGER CONTENTS AND WATER WASH OF IMPINGERS, CONNECTORS, AND BACK HALF OF FILTER HOLDER MOISTURE IMPINGERS CONTAINER BACK HALF SUBTOTAL _mg .mg .mg .mg TOTAL WEIGHT mg FINAI Vni IIMF A C Y 'INITI/U vm IIMF X a a NETVflLUMF X SILICA GEL FINAL WFI^HT V $ %. ? INITIA' WFIP,HT H 7-J"t\ NFT WEIGHT / .? - 3s EPA (Dur) 231 4/72 ml ml. ml g 6 E g 6 E £ E E; TOTAL MOISTURE ------- FIELD DATA PLANT /(evtr-c- S//S/(ft. DATE f-//-7J? ' PROBE LENGTH AND TYF •* •" NOZZLE I.D. £ SAMPLING LOCATION fins (''>'" f !<•'' $U(L'thf J&V ) SAMPLE TYPF i'" >-/•<•« i* f- RUN NUMBER 3 • • : OPERATOR f 5-r li,t 1 ZL )S - b Fffli'c ' • AMBIENT TEMPERATURE -7ff TRAVERSE POINT NUMBER 2 3 f 6> 7 ID // • n /3 />/. /£ • BAROMETRIC STATIC PRE FILTER NUM ^"V CLOCK TIME - ->-___J_Jt** /£ 3 '-^ /^> /l£ //5 '/ '•£- /o ^-i1-^- to . 4'^. /a '"""" ,fs£! /O $°- M 5 "^ //) . 5'i2- /$ 5Z2- ' PRESSURE 17.10 SURF (P ) RFR(<:) /OOQO 0 5- SCHEf READ AND REC GAS METER READING (\). It3 775-2 ' 7£0> •7#7. & Ro?.(.•/. 3 Q *'sy t £ gyz. &±"i.i %&&.<~f _ ^^~~ 93. 7 VELOCITY HEAD (Aps), in. H20 1.3S y.3** ./#••>. IISTIJRF,?; 2. < NUMBER 3 NUMBER / A 7Z 0.9? ' PROBE HEATER SETTING HEATER BOX SETTING REFERENCE ATIC OF TRAVERSE POINT LAYOUT ORD ALL DATA FVFRY /O MINUTES ORIFICE PRESSURE DIFFERENTIAL (AH), in. H20) DESIRED J.? /.$ / 52 2JT, 2.0% /.'/ /,/i O. 72' 2 i ' r A 2j? 1. 35" ACTUAL y 5- j 5- /.5S- y.l 2.1 A'/ /-/ o.9 f 1,1 2,3~ STACK TEMPERATURE (TS).°F &^ Kg /f>0 £/ &/ r J~7 ^ i_ ^3 ^/ 63 /fa /J"iD An /.t-S' DRY GAS METER TEMPERATURE INLET (Tmin),°F £? 90 £>/ 9f ?f f/ 8^ Z2> $i z% V* OUTLET ^-2- 91 7? g£- fy / Q Cr» p& 85 77 7& 73 •?7 PUMP VACUUM. in. H\| 7^ r n ir 7 51 /O // //t • SAMPLE BOX TEMPERATURE, °F ysy /fi>S~ 767 / yy ;S3 jj-g. -JL3 / ty^ / 7 £f / £~ & /5'2. /SS IMPINGER TEMPERATURE. °F £3 £2 ^S' £7 6>y ss- 3 • £i 61 60 COMMENTS: . ' EPA (Our) 235 ' . 4 '72 % nl til 13* ------- ANALYTICAL DATA PLANT_4 DATE. d /- Y ?-//- SAMPLING LOCATION £_ SAMPLE TYPE ~l_ RUN NUMBER -3 SAMPLE BOX NUMBER CLEAN-UP MAN..// T2^. <7 FRONT HALF 4eS=0NE-WASH OF NOZZLE, PROBE, CYCLONE (BYPASS), FLASK, FRONT HALF OF FILTER HOLDER FILTER NUMBER / a * t, a c <:T COMMENTS: LABORATORY RESULTS CONTAINER S-73-QQ* CONTAINER mg FRONT HALF SUBTOTAL BACK HALF IMPINGER CONTENTS AND WATER WASH OF IMPINGERS, CONNECTORS, AND BACK HALF OF FILTER HOLDER A-eEfONE-WftSH-efHrflPINGERSr-eONNEGTORS, CONTAINER •EXTRACTION- CONTAINER BACK HALF SUBTOTAL .mg .mg .mg .mg WEIGHT mg MOISTURE IMPINGERS FINAL VOLUME JLj_£_ ml . fN.ITIAL VOLUME XoO ml NET VOLUME SL-.m\ SILICA GEL FINAL WEIGHT y ft-1 g INITIAL WEIGHT _ZZ£LcL g NET WEIGHT / '!-'< g EPA (Dur) 231 4/72 g g g, TOTAL MOISTURE / 9' - ------- DRY MOLECULAR WEIGHT DETERMINATION PLANT. DATE_ J..P f t ft COMMENTS: SAMPLING TIME (24-hr CLOCKS SAMPLING LOCATION / f S-rtrl!t#y- SAMPLE TYPE (BAG, INTEGRATED, CONTINUOUS). ANALYTICAL METHOD AMBIENT TEMPERATURE_ OPERATOR tint &<. ^\^^ RUN GAS ^^^ C02 02(NET IS ACTUAL 02 READING MINUS ACTUAL C02 READING) CO (NET IS ACTUAL CO READING MINUS ACTUAL 02 READING) N£ (NET IS 100 MINUS ACTUAL CO READING) 1 ACTUAL READING NET £> 21. V 0.0 79.0 2 ACTUAL READING &.& ^^.£> 21,0 13.0 NET 0 I/. 6 0.0 74.0 3- ACTUAL READING NET AVERAGE NET VOLUME 1 MULTIPLIER 44/100 1 • 32/100 L. J ' a/100 28/100 . MOLECULAR WEIGHT OF STACK GAS (DRY BASIS) Md, Ib/lb-mole TOTAL EPA (Our) 230 4/72 ------- lM^ .3 t» ., „. « TRAVERSE POINT LOCATION FOR CIRCULAR DUCTS PLANT. DATE _ ;/A.-. SAMPLING LOCATION ^r$ TRAVERSE POINT LOCATiCl-: FROM OUTSIDE OF NIPPLE (SUM OF COLUMNS 4 ft ^ £./ ------- PREI IMJNARY VELOCITY TRAVERSE PI ANT DATE -f>_ LOCATION STACK I.D._. BAROMETRIC PRESSURE, in. Hg_ STACK GAUGE PRESSURE, in. H20. . OPERATORS X £-/.,./ * ftifp-t! 29. SCHEMATIC OF TRAVERSE POINT LAYOUT TRAVERSE POINT NUMBER / z 3 ¥• r & AVERAGE VELOCITY HEAD (Aps), in.H20 3.0. 3J 2.* 2.1 ±,1 3,0 • • 2.? STACK TEMPERATURE (Ts), °F 3#5~ 3 AVERAGE VELOCITY HEAD (Aps), in.H20 0 STACK TEMPERATURE (Ts), °F ^X EPA (Dur) 233 4/72 ------- NOMOGRAPH DATA PLANT. DATE_ ' f LLU SAMPLING LOCATION k CALIBRATED PRESSURE DIFFERENTIAL ACROSS ORIFICE, in. H20 AVERAGE METER TEMPERATURE (AMBIENT + 20 °F),°F PERCENT MOISTURE IN GAS STREAM BY VOLUME BAROMETRIC PRESSURE AT METER, in. Hg STATIC PRESSURE IN STACK, in. Hg (Pm±0.073 x STACK GAUGE PRESSURE in in. H20) RATIO OF STATIC PRESSURE TO METER PRESSURE AVERAGE STACK TEMPERATURE, °F AVERAGE VELOCITY HEAD, in. H20 MAXIMUM VELOCITY HEAD, in. H20 C FACTOR CALCULATED NOZZLE DIAMETER, in. ACTUAL NOZZLE DIAMETER, in. REFERENCE Ap, in. H20 AH@ 'Tmavg. Bwo pm PS Ps/Pm savg. Pavg. APmax. /.7L 70 7 19.28 29JS $.99 307 2.? 3.1 O'J o,n 0./9Z l.tr EPA (Dur) 234 4/72 ------- FIELD DATA ' -f'f • Co PLANT £ DATE SAMPLING LOCATION. SAMPLE TYPE / RUN NUMBER , OPERATOR t- 9-/Z-.73 PROBE LENGTH AND TYPF . / AMBIENT TEMPERATURE . BAROMETRIC PRESSURE . 2 ?, Zfr STATIC PRESSURE, (P;) . 7-t, fJ FILTER NUMBER (s) /OOOf)O£, /*,; NOZZLE I.D ASSUMED MOISTURE, %. SAMPLE BOX NUMBER. METER BOX NUMBER _ METER iHg C FACTOR O- S'72. PROBE HEATER SETTING. HEATER BOX SETTING REFERENCE 4p 2.5- SCHEMATIC OF TRAVERSE POINT LAYOUT READ AND RECORD ALL DATA EVERY. MINUTES TRAVERSE POINT NUMBER / 2 3 V S~ £ 7 S ^~ 5 /o7 ~~r~~~ — - — u.^ 3 //^ C/, GAS METER READING (Vm), ft3 %t>7./ ft trs}sv S37O, VELOCITY HEAD (Aps), in. H20 3.o s. 66 &7 PUMP VACUUM, in. Hg /^ /^ 9 9 /z ^ 10 SAMPLE BOX TEMPERATURE. °F '9 /5-S- /sp /&/ Jtf /$~r /•7 IMPINGER TEMPERATURE, °F S~t> fY s-y ss> ft J# 4,0 COMMENTS: EPA (Out) 235 ------- ANALYTICAL DATA PLANT R G S € DATE 9 ~ / 2. - 73 SAMPLING LOCATION iAifi57£ €. fr<* SAMPLE TYPE RUN NUMBER SAMPLE BOX NUMBER CLEAN-UP MAN (L COMMENTS: FRONT HALF OF NOZZLE, PROBE, CYCLONE (BYPASS), FLASK, FRONT HALF OF FILTER HOLDER FILTER NUMBER LABORATORY RESULTS CONTAINER 5-?3-i mg CONTAINER FRONT HALF SUBTOTAL .mg BACK HALF IMPINGER CONTENTS AND WATER WASH OF IMPINGERS, CONNECTORS, AND BACK HALF OF FILTER HOLDER ^ CONTAINER 5 -73 -to V CONTAINER BACK HALF SUBTOTAL .mg .mg .mg .mg TOTAL WEIGHT _mg MOISTURE IMPINGERS FINAL VOLUME INITIAL VOLUME NET VOLUME 3 fc O O ml ml ml SILICA GEL FINAL WEIGHT V 7 9.?g INITIAL WEIGHT H 7 S~.0l NET WEIGHT V 7 g EPA (Dur) 231 4/72 g g g: TOTAL MOISTURE ; A ------- FIELD DATA PLANT /••.r"P}r-r S'S.->* --,-'«• £-:, DATE -7 /;? ' x;.' >"' SAMPLING LOCATION' W-'W -• / /- S? 6 r S-ff,r TRAVERSE POINT NUMBER 7 ,f 9 /# // /2. / 1 y g~ 6, SAMPLE TYP RUN NUMBEF OPERATOR AMBIENT TE BAROMETRIC STATIC PRE FILTER NUM \. CLOCK TIME ~ ~~ 2^. ? f ¥ 3 2 "^ ? ' 2^- 3 2^ 3 2- slj -C — — ~ ^-i- _2 £^ ^ J? ~- ~~~ .3 ^JL- 3 • 3e£ ? ' 3^ ? . -?^ F l'-'t,--','fft.'f.i ,- \ •r i I I .'•-• f. I •' / ' MPERATURE ^' &~f : PRESSURE :-r,'.~?f ;<;IIRF (P ) •= ->. /•.' RFR(c) / OG0Q& 7 PROBE LENGTH AND TYPE 7 > ^ ( NOZZLE I.D. (^> y^ J ASSUMED MOISTIIRF, ". 7 SAMPLE BOX NUMBER -5 METER BOX NUMBER / METER AH{ C FACTOR / •/ ? a.? PROBE HEATER SETTING HEATER BOX SETTING SCHEMATIC OF TRAVERSE P( READ AND RECORD ALL DATA EVERY GAS METER READING (V ) (t3 1 m'1 ^7/// f <* ACTUAL 1,0 Li 2.5- 2.dy 1.1 2' I / .7 /f 2.25" 7.0 DINT LAYOUT MINIIT STACK TEMPERATURE (TS),°F 3^7 3W 3S-& ?£l Ui J5& SS'^ 15Z 36 / J?£5 3S? REFERENCE ES yy^ ~f~-f-^ L ^ ^ ,, "/•?&' Ap x . -3 DRY GAS METER TEMPERATURE INLET (Tm in).0!7 7'/ ry r£> 77 79 7? 8TI £0 76 7& 79 7f OUTLET 7£, 7? 7Y 7S- 73 7& 76 7? 7&> 7/ PUMP VACUUM. in. Hg <£ 7 7~z. ^y /Y /77 J7& /7 ------- ANALYTICAL DATA PLANT g s -g /- e DATE - 73 SAMPLING LOCATION SAMPLE TYPE PAfeTU»iA-r£ RUN NUMBER ^ SAMPLE BOX NUMBER CLEAN-UP MAN ^ 7" r.J COMMENTS: FRONT HALF WASH OF NOZZLE, PROBE, CYCLONE (BYPASS), FLASK, FRONT HALF OF FILTER HOLDER FILTER NUMBER /OOP OG 1 _ LABORATORY RESULTS CONTAINERS-9-3 ------- FIELD DATA PLANT fr'.s >t "-T At rut" «., i DATE 7-/Z SAMPLING LOCATION _/'.<~Jr;s,,S. AMBIENT TEMPERATURE •/ BARnMFTRin PRFSSIIRF STATir PRFWIIRF (P ) FIITFRNI!MRFR(0 5 /< -r ? r/V /T ''/^ A /^, - - ^.7> 7^" 25?. 2 .* ? ••>. / v •?.tra#.v S f-f tf i ^ • L • jk £* PROBE LENGTH AND TYPE NOZZLE I.D ASSUMED MOISTURE,'.. SAMPLE BOX NUMBER _ METER BOX NUMBER _ METER AHg CFACTOR ss -Z- JL A 72 PROBE HEATER SETTING HEATER BOX SETTING REFERENCE ip SCHEMATIC OF TRAVERSE POINT LAYOUT READ AND RECORD ALL DATA EVERY. MINUTES TRAVERSE POINT NUMBER / 2 3 / 5" £ 7 ,e •9 /o // /? ^^\^ CLOCK TIME S3LING XcS^K) TIME, mm x^ — — -— — ^sj£p «'-+ 3 4'-^ 1. 4'-- •Tf > 1 y^- •( ¥ss 3 • #&-. ~~~~ — ;-~— . y -LL 3 V ~~ 3 22- ->, : «^ i v^ J . •?sS<'-^~: 1 ,^ GAS METER READING og, it3 9/9.6 92Z.3 ??d7 /7f J7 /#f , IMPINGER TEMPERATURE, "F 51 £/ ^J £3 &y zy s? 9 £0 sr 6 ------- ANALYTICAL DATA PLANT /? e C €• tr \f g DATE 3 ~ / 2. - 7 . SAMPLING LOCATION IQA6TE SAMPLE TYPE _ RUN NUMBER_ SAMPLE BOX NUMBER. CLEAN-UP i COMMENTS: FRONT HALF LABORATORY RESULTS A6EPOME WASH OF NOZZLE, PROBE, CYCLONE (BYPASS), CONTAINER 3-', FLASK, FRONT HALF OF FILTER HOLDER FILTER NUMBER / O & O O 6 ^ CONTAINER mg S-TJ-ooV-5-/? .mg SUBTOTAL .mg BACK HALF IMPINGER CONTENTS AND WATER WASH OF IMPINGERS, CONNECTORS, AND BACK HALF OF FILTER HOLDER •AND-BAeK-ttAtF-OFTILTEirHOL-DER- ET-HER=eHtOR0FQRIVU BACK HALF SUBTOTAL .mg .mg .mg .mg WEIGHT mg MOISTURE IMPINGERS FINAL VOLUME 2 ml INITIAL VOLUME 2 o O ml. NET VOLUME "V &> ml SILICA GEL FINAL WEIGHT INITIAL WEIGHT Y 7.H Qg NET WEIGHT _ ~L-Z g EPA (Dur) 231 4/72 • E .g -g g g g: TOTAL MOISTURE ------- FIELD DATA ~?^r^ •Co t TRAVERSE POINT • NUMBER -r F c 72 '/ .-• r // _^> ^ - PLANT P-flf — -- //;>:<", L f O^' DATE -'-.'.'•• .' :- - SAMPLING L •^ ^ SAMPLE TYP ),£> RUNNUfflBEF OPERATOR . AMBIENT TE • " BAROMETRIC . . " ' STATIC PRE. FILTER NUM • >v CLOCK TIME -~— £J^£ J &•- 3 • & * — o - b'-^ J <£ ^~ ? & 't-2- 3 £> W~ •" --S -.<& — ' ^ /,-•- ^ ' ^- ^— J . 7^- 5 • 7^ J 7 ^"" JCATION ' -; ' ' ' "' ' • • ' " •''•''•'• r '''• F ;-:':- -'-.-,. :,,-., i 7 ilPERATURE '/ ? PRESSURE 2 '"--' T- SIIRF (P ) -i •?./•'/ RFR(.) /,fff>r-fjo^ PROBE LENGTH AND TYPE . : ." f.C JV/i NOZZLE I.D. f. t'?l ASSUMED MniSTURF,"; . - T SA.MPLE BOX NUMBER '3 ' . ' ." .. SCHEMATIC OF TRAVERSE P READ AND RECORD ALL DATA EVERY GAS METER READING (Vm), It3 9J-3. y ^55. "L. rf£ 7. J 9?. I 96 1,7 '*' ?£'/•? ?£> 7.9 \!' •? 7^. P 973, y 97P.Z 9S'3,& • ••- -•': • " . VELOCITY HEAD (APS), in. H20 /y /,£ /- 7 3.Z 1.7 V.o 3.2 3,f> 2.3 2.S" 3,3 z.c< ORIFICE PRESSURE DIFFERENTIAL (AH), in. H20) DESIRED / Of y/2 /.!(. 7.7 ?.? :?.«/ 2- Z /./' y. PUMP VACUUM, in. Hj ^ 7 7 /f* '/& /2~ /Z /0\- S2, j2 SAMPLE BOX TEMPERATURE, °F .//jT 77 7 7^2. /?"•/ JZS" /'??' /77 y^jT y77 77-T IMPINGER TEMPERATURE.. "F ^> J^" 6't s^Z 72- 77 6 7 &5~ •£•'/ • 67 !-•? 7^ COMMENTS: EPA (Dur) 235 ^ . ^ "~~ 4 72 ' /=r ' y-?? yjf yj2 /3f ------- ANALYTICAL DATA PLANT ye.s DATF 9 - / 2 - 73 COMMENTS: SAMPLING LOCATION /.Jflfrs SAMPLE TYPE • • pfl g Til m ftr e RUN NUMBER 2 SAMPLE BOX NUMBER CLEAN-UP MAN d FRONTHALF LABORATORY RESULTS OF NOZZLE, PROBE, CYCLONE (BYPASS), FLASK, FRONT HALF OF FILTER HOLDER FILTER NUMBER /oo&oo °i _ ___ CONTAINER .>~ mg CONTAINER 5-7J-OOV - 5"2 O FRONT HALF SUBTOTAL .mg BACK HALF IMPINGER CONTENTS AND WATER WASH OF IMPINGERS, CONNECTORS, AND BACK HALF OF FILTER HOLDER AeETONE-WASH-QHMPINGERSreONNEeTORS, BACK HALF SUBTOTAL .mg .mg _mg _mg TOTAL WEIGHT mg MOISTURE IMPINGERS FINAL VOLUME ^? 5~ . INITIAL VOLUME 3L O o NET VOLUME • f ml ml ml SILICA GEL FINAL WEIGHT /** f g INITIAL WEIGHT Y7.T-P g NET WEIGHT 7-Y E EPA (Our) 231 4/72 g g g; TOTAL MOISTURE . ' f' '• •••• ------- DRY MOLECULAR WEIGHT DETERMINATION PLANT /f-rrms-C /sTintx-? S ~ COMM DATE ?-/2- SAMPLING TIME (24-hr CLOCK) SAMPLING LOCATION M/<* J SAMPLE TYPE (BAG, INTEGRATED, ANALYTICAL METHOD AMBIENT TEMPERATURE OPERATOR 2* - — 4 ' ..-, •x^r' // '& /& • — -~ // — <^t tf «^^ /^^j- Zftck. CONTINUOUS) 84 £?>' r/r, (/ jTT" 'j?^* F/-<. ""^-^ RUN GAS ^\^ C02 02(NET IS ACTUAL 02 READING MINUS ACTUAL C02 READING) CO(NET IS ACTUAL CO READING MINUS ACTUAL 02 READING) N2 (NET IS 100 MINUS ACTUAL CO READING) 1 ACTUAL READING &,? ^^.^ ZO-P 19.1. NET ^f 10.0 0.0 m 2 ACTUAL READING ^f- 2P.&- 2£>. f 7&TL NET a.? 20.0 0,0 ??.Z 3 ACTUAL READING NET AVERAGE NET VOLUME MULTIPLIER 44/100 32/100 T~H 28/ioo 28/ioo TOTAL MOLECULAR WEIGHT OF STACK GAS (DRY BASIS) Md, Ib/lb-mole 0.3f &.io G.0f> 2Z.' L?3* EPA (Dur) 230 4/72 ------- TRAVERSE POINT LOCATION FOR CIRCULAR DUCTS ' .'. PLANT ''-.I'. .^ DATE .. _____ ___?.-/£.:..? SAMPLING . LOCATION . __ ^^^- INSIDE OF FAR WALL TO -r OUTSIDE OF NIPPLE, (DISTANCE A^ INSIDE OF NEAR WALL TO ' '• ' • OUTSIDE OF NIPPLE, (DISTANCE. B) STACK I.D., '(DISTANCE A - DISTANCE B) NEAREST UPSTREAM DISTURBANCE _ NEAREST DOWNSTREAM DISTURBANCE. CALCULATOR ____ £" .jjut/z.- ^ ?7-V ft .i .SCHEMATIC.OF SAMPLING LOCATION TRAVERSE POINT NUMBER'- y i • 3 ' t/ __£ 6> * . . • . ' -• • FRACTION OF STACK I.D. - £Y / \-o .'. ' . _ 1 ^^^^^ i'": 1 up* ,. , 3 ^__ 1 \-S ""1 - '}'••' 1 ^' \ \ •' -f'MDar) 232 • •. " ' Lw! ^ v DISTANCES '• J'- '• . • , . ' . - / j f pfA 1 fa ' f) £ ' ' " fi O 1?^ V ' ' - TRAVERSE POINT LQCATIO:. 'FRO',: OUTSIDE. OF NIPPLE '(SUM OF COLUMNS 4 £ 5} ..;: £i/t/ n^- __2«j_ 3~. ¥ £4.o •r /. ^ . * ,,, • 4/72 ------- r^ r^ r* 1 i s r t >M Q~ c^ * • i • f * tiV C!_ !!'/'! !!'.:.'•! !\Y V' r ! i •" ^ f T~ ^ P f "~ V"~ ** r ! ! V ! F? w \.' !- R\ PLANT. i DATE LOCATION STAC K I. D Z/y 1 BAROMETRIC PRESSURE, in. H«_. STACK GAUGE PRESSURE, in. H20. .x SCHEMATIC OF TRAVERSE POINT LAYOUT TRAVERSE POINT NUMBER • ." '/ 2 •? • ¥ ' Js £ . 7 P 9 -'/.#'' //. ji. AVERAGE VELOCITY HEAD • (Aps), in. H?0 1 ./.3' ' ' J,f • /,? /,r .;,£ ,t " . J.S •J.f- 1,.O - /•«& /7 /7 . • • . • STACK' •TEMPERATURE (Ts), °F. - . 2-If-- ZL£ • ?? ?•• 22? - ••' 33-& ^LlP • 2}7 ^' 2 i i Z3& - ' • 231 2S2 ? ------- NOMOGRAPH DATA PLANT. DATE_ SAMPLING LOCATION Minute fa aeJ ZifLaftrf £}#£& CALIBRATED PRESSURE DIFFERENTIAL ACROSS ORIFICE, in. H20 . • ... .AVERAGE METER TEMPERATURE (A!YIBIENT + 20°F),°F PERCENT MOISTURE IN GAS STREAM BY VOLUME BAROMETRIC PRESSURE AT METER, in. Hg STATIC PRESSURE IN STACK,' in. Hg (Pm±0.073 x STACK GAUGE PRESSURE in in. H20) RATIO OF STATIC PRESSURE TO METER PRESSURE ' . AVERAGE STACK TEMPERATURE, °F ', AVERAGE VELOCITY HEAD, in. H20 MAXIMUM VELOCITY HEAD-, in, H20 ' '• C.FACTOR . .. . • • CALCULATED NOZZLE DIAMETER, in. - - ACTUAL NOZZLE DIAMETER, in. REFERENCE Ap, in. H20 , •. . AH@ Tmavg. Bwd • pn, - Ps . Ps/Pm . savg. APavg. APmax. 7.72 $* /2 29.37. •' 21.27 / - 22f /•7 '2fo -O.$f. &,/ ------- FIELD DATA » .PLANT Rrjri^^f M//t,tt.~ Ccr -• DATE ?-S3~73 •' '•••'• ' • SAMPLING L SAMPLE TYP RUN NUMBEF . OPERATOR . aCATION /^//ff-'f-r,- Mt>a rj £ f /Zr, -•/;,.,/«{-.* '.^ X J'- /t,f/T. 4?c& /0?/e<-c -..'•• ' - PROBE LENGTH AND TYPE 9-f^ SS.3J& •' '.-•'' - j f ( fa -/ • • AMBIENT TEMPERATURE. -6'O .. ' ' . •' - TRAVERSE POINT NUMBER 7 ff Q /& // /2 / • z ' - 3 y . y f f, • BAROMETRIC STATIC PRE :' . * FILTER NUM ^K CLOCK TIME SAMPLING^ CLOCK) TIME.niin x^ — -. Jo^/_ •2 - /^ ^T~~~~- — ~r^f~^ X // — '.PRESSURE 2 f. ?7~ KIIRF (P ) ' 2?. i 7 RFR («) / , / % £ ISTIIRF •; /?- ' .'•••' (NUMBER' 3 • NUMBER / /. 7-2 . . Q. g-$~ • -. -- • -• . . . PROBE HEATER SETTING '.- HEATER BOX SETTING //fl-t.S /•7t> ' ' * ' ' REFERENCE An 2'V • "SCHEMATIC OF TRAVERSE POINT LAYOUT READ.AND'RECORD ALL DATA EVERY__^I__ MINUTES • GAS METER READING (V 1 ft^ \ m'1 " . • fs^r. / ^fO.'L. ' J 92.-J, . •' • qqt/, 1 ., S6& 6.° , --•"" /&& /<7 y/7 • J.3 • /.7 /,£ /•? - '/.f J.S / J- . ORIFICE PRESSURE DIFFERENTIAL . (iH), in. H20) flESIRED D/. "• .= /• ^ : ).„ ACTUAL A3 /-V / if •i^ji- ]'/.2S- $fjt" '• / 35" %(,•#£, \ /,ff .•• /:- ; :-/j •./.2j'r- . j.iS' /,/• A:i,r //J- /,?> /,2 •/ J /./r—o.', A/-T J.tS" J./S' •'STACK TEMPERATURE // • 2.1^ 23& 2^2. . DRY GAS METER- TEMPERATURE . INLET (Tmin),°F .?/ ' ^•7 ^7 -f;? #* $y %3 Zl #/ #/•" ' 79' OUTLET Xt pi •#L • V2 : -.rz. •''•fZ' .' ^ ; /? & • SAMPLE BOX-. TEMPERATURE, °F JV '/?2 . /^ /<6o . /&( " /73 • : • . • .- IMPINGER TEMPERATURE, "F • vr 49 SO 6 & Co ~~o &o £>o • 60 60 60 COMMENTS: . • -%. £~-cJj>ef #& ' f/ttlis -...'• EPA (Our) 235 - ' ' . ' . • ; .'.''.• 472 ' '. ' . ^: //5- j~~ ------- .ANALYTICAL DATA PLANT nATF e 5 -e h y g SAMPLING LOCATION. SAMPLE TYPE 'p^£T>cu RUN NIIIHIRFR ft SAMPLE BOX NUMBER. CLEAN-UP / FRONT HALF WASH OF NOZZLE, PROBE, CYCLONE (BYPASS), FLASK, FRONT HALF OF FILTER HOLDER FILTER NUMBER COMMENTS: CONTAINER LABORATORY RESULTS mg CONTAINER S '73' 6 o .mg FRONT HALF SUBTOTAL BACK HALF IMPINGER CONTENTS AND WATER WASH OF IMPINGERS, CONNECTORS, AND BACK HALF OF FILTER HOLDER MOISTURE IMPINGERS FINAL VOLUME • INITIAL VOLUME 3-0 Q ml NET VOLUME f ml SILICA GEL FINAL WEIGHT JLULLJ-g INITIAL WEIGHT _4L2_£L? g NET WEIGHT S> - Z g EPA (Dur) 231 4/72 CONTAINER CONTAINER. BACK HALF SUBTOTAL .mg .mg .mg TOTAL mg g g g; (\ TOTAL MOISTURE 3 /. ------- FIELD DATA PLANT F.'.fo-~-r DATE £: - XJ? SAMPLING LOCATION /x//>;6 j--P.- SAMPLE TYPE Ps,rlic,, lfftx RUN NUMBER f OPERATOR £.fr/,.'f. /?' PROBE LENGTH AND TYPE. NQ7ZLF I.D. ' /. 9 P1~~ AMBIENT TEMPERATURE BAROMETRIC PRESSURE STATIC PRESSURE, (P ) FILTER NUMBER (s) ASSUMED MOISTURE/, SAMPLE BOX NUMBER. METER BOX NUMBER _ METER AHg CFACTOR 3 1 . I 2 "— 3 JfJL 3 . 72^- -.> /; ""-^ . - GAS METER READING (Vm), tf /jr^y _, /^/ • y^.2 ' /^ z . '!3 /;•- V S.lf /./.r A3 /-•/ /^•i" /'/ /«j ;.° • ACTUAL /.J /J /,J A2 J.l? ;./* /.r '•?- i,? AV ./. 3 AO STACK TEMPERATURE (TS).°F I// 2W 13 ' I 3S" 2^- I'/J j?VZ. 13V 7?5" ,? ^ J 2'// y?./ DRYGAS METER TEMPERATURE INLET (Tmin),"F ?o 7'/.. T/ 7& 7£ f-t. 7& 7C ?^ ty f-7. 77 OUTLET (Tmout).°F ?o '71 73 73 7Y •»/ 7S- 76> ?y 73 7 v' 7S~ PUMP VACUUM, in. Kg 7 •7 ' 7 7 7 7 •7 7 7 7 .•-» / fy SAMPLE BOX TEMPERATURE, °F ' /^5- xV' ^!?£3 /77. 77^3 J6ff / ~- ' ' //' >/? /^i //^ /// ///. /j /oJ--* /03 COMMENTS: EPA (Our) 235 4/72 ------- ANALYTICAL DATA PLANT. COMMENTS: DATE__ SAMPLING LOCATION HcnO l< &t->r .57VHK SAMPLE; TYPE RUN NUMBER SAMPLE-: BOX NUMBER CLEAN-UP 3L- 7 TJ^A.. FRONT HALF WASH OF NOZZLE, PROBE, CYCLONE (BYPASS), FLASK, FRONT HALF OF FILTER HOLDER FILTER NUMBER /a o aa I O _ CONTAINER ^ 7.3 CONTAINER 5' 73' 0 LABORATORY RESULTS mg SUBTOTAL BACK HALF IMPINGER CONTENTS AND WATER WASH OF IMPINGERS, CONNECTORS, AND BACK HALF OF FILTER HOLDER ACETONE WASH OF AND-BAGK-HAbF OF FILTER HOLDER CONTAINER. BACK HALF SUBTOTAL _mg .mg .mg .mg mg MOISTURE IMPINGERS FINAL VOLUME * 2 5" .ml INITIAL VOLUME %O P ml NET VOLUME . 3 ST m\| SILICA GEL FINAL WEIGHT 9 * & .7 g INITIAL WEIGHT f 7 T. 9 g NET WEIGHT 5~- 7 g EPA (Dur) 231 4/72 .g • g -g g g g; TOTAL MOISTURE - ? ------- FIELD DATA 'r'-c-h •PLANT fiff.cru •. Mnnilti C» DATE - J/ood £Tie'J & tf £ \ 'O- #'° >j 2/'& #'.'0.0 TRAVERSE POINT NUMBER • 7 z 9 y,/,-/?, .x^4> fell"}'. AMBIENT TEMPERATURE ' -65'- -" . .-"'• '."..-.' ' . . , BAROMETRIC ' • ; STATIC PRE FILTER NUM f ^^- CLOCK TIME SAMPLING ^VC'LQCK) TIME.njin -v^ —-r- -_____5J£X 3 • i — - ? .?J2- •2 7 ¥& .7'. 2 '-:i" °1~~~': ^£ ? 2^- J • . " J "-^ j •. • J^3 ? 3«J^ ^ • "^ J« y 5^ • J — ' •• PRESSURE ?-?,.?/ SURF, (Ps) • ^ <,?/ RFR(«)- /#k&&tt1. •••'•'. :' SCHEff . • . ' ' READ AND REC GAS METER READING- j.1"/ J^.5" ^ i-7 J. -3" AJT y /y - _ A PROBE LEN NOZZLE 1.0 ASSUMED MC SAMPLE BO METER BOX METER AH^ C FACTOR GTH AND TYf E ^ // ^-T JV£ x^ /t" -2 • .' ISTURE/i '• - <£ ->•'•''" (NUMBER ' '3 - ' • . '-- -• NUMBER" 7 '"-.'• /j. ' sir- i/ ., , / ? i>~- /i-T A.? /./S // » "' : STACK .' . ' TEMPERATURE -^JY Z3Y • >J7 - .''.i'^ y ss- 231 jy/^,._ j/^(X, 27 ! tf 7 ' j* c* j • ' i /J S/cv^? ' ' ' • . -/j-o An . • • 2 • y" . • ' " ' • ' • ' ' - .* '•( . DRY GAS METER • TEMPERATURE - • INLET (Tmjn).°F g.0 po 7f 7^ n %/ ?•? •?? #0 S'Z fz * OUTLET- n) out y ^ 7^ %; %.¥ fy * 5jT 77 7"» y y? /jr^1 • X-i'-T > 3T • y^~y '•/^•y /j-f '.iff /&f /<£.? 1 /^7 1 • v IMPINGER TEMPERATURE", &3 1 t^C, £ f ^7 fc? • • ' 6& ' • '&¥ • . 69 • 77 7J>ut,.jL • " (yj'Ji'S rfs»/> '• (LAtckf.? 0 K' . EPA(Dur}235 ' ". •"- .•'•''..' ...-;' / . ' . . '• • 4 72 • • . ' ' ' ' '?/ j'f. . //$• "Y ------- ANALYTICAL DATA PLANT nATF -/•?- 7 J SAMPLING LOCATION. SAMPLE. TYPE PflK RUN NUMBER IO. SAMPLE BOX NUMBER CLEAN-UP MAN. FRONT HALF WASH OF NOZZLE, PROBE, CYCLONE (BYPASS), FLASK, FRONT HALF OF FILTER HOLDER FILTER NUMBER /aO COIVI1VIENTS: LABORATORY RESULTS CONTAINER 5-73 OQV CONTAINER 5 mg .JEROaiT- HALF SUBTOTAL .mg BACK HALF IMPINGER CONTENTS AND WATER WASH OF IIKIPINGERS, CONNECTORS, AND BACK HALF OF FILTER HOLDER •ANB-BAGK-HAfcf-6F-fHLTER HOLDER MOISTURE IMPINGERS FINAL VOLUME 1 * * INITIAL VOLUME _2L2je_ NET VOLUME 2 (, SILICA GEL FINAL WEIGHT 7 INITIAL WEIGHT NET WEIGHT -*- EPA (Our) 231 4/72 HTIirD fU\|. ODDCIADM 1 1 ML.K-U1LUI ------- DRY MOLECULAR WEIGHT DETERMINATION PLANT. DATE_ ns?. /• r is f- sty/, tf .•<•"? COMMENTS: ~/3 ' 7? SAMPLING TIME (24-hr CLOCK). SAMPLING LOCATION /fr, — / 7 - •* ... f tfea et £~•-/,<•,<;? SAMPLE TYPE (BAG, INTEGRATED, CONTINUOUS). ANALYTICAL METHOD ' AMBIENT TEMPERATURE 6 3 OPERATOR #* / i ^-^^ RUN GAS ^^\ C02 Q£ (NET IS ACTUAL 02 READING MINUS ACTUAL C02 READING) ' CO(NET IS ACTUAL CO READING MINUS ACTUAL 02 READING) N2 (NET IS 100 MINUS ACTUAL CO READING) 1 ACTUAL READING a* 2l,o 11,0 79,° NET 0.0 Zi.o 2.0 79 2 ACTUAL READING A* 11. 0 2/,0 ?<}.& NET ^. 0 2>,v 0-0 77 3 . ACTUAL READING NET AVERAGE NET VOLUME MULTIPLIER 44/100 1 32/100 1 ~t 1 . 1 28/ioo 28/ioo. MOLECULAR WEIGHT OF STACK GAS (DRY BASIS) Md, Ib/lb-mole ^ <^,3 0 22.2- TOTAL ,^r EPA (Dur) 230 4/72 ------- i TRAVERSE POINT LOCATION FOR CIRCULAR DUCTS PLANT. DATE . SAMPLING LOCATION (/(" INSIDE OF FAR WALL TO OUTSIDE OF NIPPLE, (DISTANCE A) _ INSIDE OF NEAR WALL TO ' OUTSIDE OF NIPPLE, (DISTANCE B) _ STACK I.D., (DISTANCE A - DISTANCE B). NEAREST UPSTREAM DISTURBANCE NEAREST DOWNSTREAM DISTURBANCE,. CALCULATOR <~ -//iLc^L, ? J -ft .SCHEMATIC OF SAMPLING LOCATION TRAVERSE POINT NUMBER / 2 3 4' s~ & 7 f 4 •s'0 // /£ FRACTION OF STACK I.D. /.•/ ;'•/,/ If.* 7J,J' £-r? fc:& • STACK .D. j?4 -. PRODUCT OF COLUMNS I AND 3 fro NEAREST 1/3 INCH) /-^ Sz // - ' jy0 . . 'A ^' » f T ^ -j« _j j 1 i 1 j0^ ' \ i i 4 , DISTANCE B JT± 9~v ;Sir j/4 y/% ^p X TRAVERSE POINT LOCATiC1 FROM OUTSIDE OF NIPPLE (SUM OF COLUMNS ', & 5) PA (Dur) 232 V/2 ------- PRELIMINARY VELOCITY TRAVERSE PATF ?-/* • 7? LOCATION Csntvs^o- >f. /(',•. '': /£/-•//' i STA^K in ~'f ••-'' " BAROMETRIC PRES STACK GAUGE PRE! 51IRF, in. Hp ' V'. 2 T 5 // • /i AVfJiAGE VELOCITY HEAD (Aps),in.H20 0.?7 £,/ tfS-f- $. P 7 ,-:?.-cf ^17^ A 7? £.?# &.41 f f / / * 0,?? #'.£$' STACK TEMPERATURE (Ts), °F • ^y. • ^_r ^7 ^7 < ?'• \l& / C/? //o ^7 £7" 67 £ 7 68- :PA (Our) 233 ' 4/72 SCHBrtATIC OF TRAVERSE POINT LAYOUT .TRAVERSE• POINT NUMBER AVERAGE VELOCITY HEAD (Aps), in.H20 STACK TEMPERATURE (Ts), °F ^^ ------- NOMOGRAPH DATA PLANT DATE SAMPLING LOCATION tc Mt// CALIBRATED PRESSURE DIFFERENTIAL ACROSS ORIFICE, in. H20 AVERAGE METER TEMPERATURE (AMBIENT + 20 °F),°F PERCENT MOISTURE IN GAS STREAM BY VOLUME BAROMETRIC PRESSURE AT METER, in. Kg STATIC PRESSURE.IN STACK, in. Hg (Pm±0.073 x STACK GAUGE PRESSURE in in. H20) RATIO OF STATIC PRESSURE TO METER PRESSURE AVERAGE STACK TEMPERATURE, °F AVERAGE VELOCITY HEAD, in. H20 MAXIMUM VELOCITY HEAD, in. H20 C FACTOR CALCULATED NOZZLE DIAMETER, in. ACTUAL NOZZLE DIAMETER, in. REFERENCE Ap, in. H20 •AH@ Ttnavg. Bwo pm ps Ps/Pm savg; Apavg. APmax. /,72 ? ------- :IELD DATA PLANT. DATE_ KJ- f..- PROBE LENGTH AND TYPE. NOZZLE I.D &• SAMPLING LOCATION SAMPLE TYPE RUN NUMBER OPERATOR /. y 151, Pr /,, AMBIENT TEMPERATURE . BAROMETRIC PRESSURE . STATIC PRESSURE, (Ps)_ FILTER NUMBER (s) ,; ASSUMED MOISTURE,'',. SAMPLE BOX NUMBER. METER BOX NUMBER _ METER AHg C FACTOR /.71. /.a ?-?,.?/ PROBE HEATER SETTING. HEATER BOX SETTING REFERENCE Ap SCHEMATIC OF TRAVERSE POINT LAYOUT READ AND RECORD ALL DATA FVFRY MINUTES TRAVERSE POINT NUMBER 7 7 # "7 / 0 // 1 1- / 2 t> tJ _T ' /< \v CLOCK" TIME ^=\£S?i • TIME, mm \_ " ~~ -^--CLJ . • r ^ - - _/£->" /• '. s °° 6 k> • — / / ° JO ' o ~ /o. to'hfL 10 (?3^ 10 ff '.'" / c? ' o -53- "" — • ~, ^_., iJ. ^i ^'. so . i °-. /^ 7 - /<9- 7 2^r AO 7-- --'':•' \r> ";!^;- GAS METER READING (Vm), 1? i 1 •"> 1 V1 7?. 5 ,5>7.-c_ f (P' 7 /'! . bS -?!> . y.S 2. 7 3-.? 1 .? 2., '? ^?.» 2. , -vr -?. 2.7 1 7 1,'f 1 61 61 leZ^. (,^ • , -• t^~--> ^ PUMP VACUUM, in. Hg _ // // /2- /Z- /^ ? /^ /2 i rt 1 /<_r I Z- lit C\ SAMPLE BOX TEMPERATURE, °F _— /JO /J7 / ^7 /o-j / oo / 00 ;/s /if MS* i • "TJ i ! 7--' I O'~i IMPINGER TEMPERATURE, "F . — jT-i" ->",?• J>"7 5- F^P> pjrajlf Is.*;-' /= ?? ?'? 95~ °i3 1Z. ^0 ?£. •^ ------- ANALYTICAL DATA PLANT /f -e S e /• IA -e SAMPLING LOCATION SAMPLE: TYPE _ RUN NUMBER SAMPLE BOX NUMBER. CLEAN-UP MAN. FRONT HALF COMMENTS: &~ i?e0e,a /3 CONTAINER .6- LABORATORY RESULTS S3I _ mg CONTAINER S-73-Oal- .mg :FROU HALF SUBTOTAL BACK HALF IMPINGER CONTENTS AND WATER WASH OF IMPINGERS, CONNECTORS, AND BACK HALF OF FILTER HOLDER MOISTURE -EfHER^HtOROFORM BACK HALF SUBTOTAL TOTAL WEIGHT IMPINGERS FINAL VOLUME INITIAL VOLUME NET VOLUME - SILICA GEL FINAL WEIGHT INITIAL WEIGHT NET WEIGHT EPA (Dur) 231 4/72 / ? 6 2« v _ a ty/. ? ? c. < /a. • ml ml ml ••-•••• ^E E « ^ g g E g E ' E! TOTAL MOISTURE .mg .mg .mg mg ------- DRY MOLECULAR WEIGHT DETERMINATION PLANT. DATE_ COMMENTS: - 72 SAMPLING TIME (24-hr CLOCK). SAMPLING LOCATION ** SAMPLE TYPE (BAG, INTEGRATED, CONTINUOUS). ANALYTICAL METHOD AMBIENT TEMPERATURE OPERATOR ' \^ RUN GAS ^^^^ C02 02 (NET IS ACTUAL 02 READING MINUS ACTUAL C02 READING) CO(NET IS ACTUAL CO READING MINUS ACTUAL 02 READING) N£ (NET IS 100 MINUS ACTUAL CO READING) 1 ACTUAL READING NET 2 ACTUAL READING « 3 NET ;p AQTUAL' . •:lj RgDING ;. f NET AVERAGE NET VOLUME • MULTIPLIER 44/100 1 32/100 C"ll • 28/ioo • 28/ioo MOLECULAR WEIGHT OF STACK GAS (DRY BASIS) Md, Ib/lb-mole - TOTAL EPA (Dur) 230 4/72 ------- APPENDIX C Laboratory Report ------- UNITED STATES ENVIRONMENTAL PROTECTION AGENCY NATIONAL ENVIRONMENTAL RESEARCH CENTER RESEARCH TRIANGLE PARK, NORTH CAROLINA 27711 SUBJECT: Process Emission Samples From Duluth DATE: March 14, 1974 FROM: F. P. Scaringelli -^ Chief, ESAS * TO-. . R. L.- Ajax • ... .,.-.. Chief, EMB THROUGH: 0/D, QAEML As per your memorandum of February 5, 1974, we are transmitting for your use the following items: a) A xerox copy of the data sheets showing the ac- cumulative particulate matter and the weights of the filter from which these values were computed. These are pages copied from laboratory notes of Gary McAlister, Chemist. b) Documentation of Chain of Custody - Sampling handling log; Source Sample request and report; letter of transmittal of samples to Battelle with certified mail receipt superimposed; and the cover letter from the Battelle Analytical report. All other information that you require, has been re- quested from Battelle. They will be transmitted to you as soon as received. cc: Dr. Shearer D. Goodwin Ur. Thompson R. H. Jungers Enclosures EPA Form 1320-6 (Rev. 6-72) ------- o^-\, ci'n/ /•io. : l& $ft.i-:'}iL $. _ . ..••(. v.^-S'i.t-- ; /(. ^-J. /- . ------ I 'V T • .•/e^,,,,,. — -/UC L-: ^-.c-^ L.'t( y ,\J - v-(. . _____ O (^ -/- t, ^/ o. o /c> ts c- o o C / H (-> C- • ' v— ^ -• V? fj 6'. Mt I >' 0 .4tob ^ • W-/., o- • rs?4 .svV/ -5-Vi .^-3.^ s tTji 9 • ^ \ a ', _-yJ o • co 17 1 • — " •• ' --.-., 0', C l5-,i' o, o i -i'o • : o o4U^ 0,0 3>2^ >;.0-^'^ Ai J - .. <-/<,j<:: . fil ------- u. A. r.^,'n »~A i --—J—I .. . y.•;•••• -.",rT-7 - 3.. ' . ..-...^,.. 53 .43^0 - ->/ - $6 -57 '/- -/ 5" y i - / 7 - _zfI/_ "Z jL£lr_ - 5-5- - .-r'6 _42_oJ_ 4 Jv ------- Reserve Mining Test :?74-HAS-l Sample Identification Fine Crusher Stack Probe Filter Impinger Waste Gas Stack Probe Filter Impinger Hood Vent Stack Probe ' Filter Impinger Concentrator Stack . Probe Filter Impinger Run 1 501 502 503 Run 4 510 511 512 Run 8 .522 523 524 Run 11 531 532 533 Run 2 . 506 505 504 -Run "5 513 514 515 Run 9 525. 526 527 Run 3 507 508 509 Run 6 516 517 518 Run 10 528 529 530 Run 4 — Run 7 519 520 521 The numbers shown are the final three digits in an 8-number code: S-73-004-xxx (for example the probe wash for run #1, fine crusher is identified: S-73-004-501). ------- 3i .' iS ' J.I : 35 : Ji SAMPLING DATE YR\| MO I DAY 1 50 ! I I I ! I I I I ! I I , I I I 51 j M I !li I it I 55 \| ',6 I 57 i 58 I 59 60 I 61 62 61 64 65 \| 66 I 67 ! I 19 I .70 ! 71 I 72 ' 73 I 7« \| 75 \| 7li j 77 ' T. \ ?» • 80 ' SOURCE SAMPLE REQUEST & REPORT '(MUST BE FILLED OJ" TOR EACH TEST RUN) [FIRST IOENT. I NO. USED s 71 00^1 s [LAST IDENT. NO. USED 5 73 004 TEST HO__-.:.- RUN NO -4- lr INDUSTRY UNIT PfOCESS OPERATION __ C/PM .//£/?_. , ~ I •• \ " 1 ' ' } i - j i: ! ' = 1 "i"."! 'I CO?/:' ADD? SAMP MET- ' IDENT NO / "JO/" (V)t IKDLt M) ,rc, \£ iTO.ffe </;>ii/M\$'«V(i ' iyC^ . // i^ •' ' x.',\J .,/ /wi^ \ tji ffl' -. • . ./' : R DfiTT&tle ' PRntFP.T (IF APPLICABLE) •ST OATF AHA! YSIS OFFICER _// REQUESTED •\ •; '.• REQUEST L# / / jf/jj-ctJ J\Pt,Ly A RFUIEWFP PY --^-i y/n/Ti «' '•• \ ' . • • -S . DAT? OF RFQMFST r rr 11 i? (TO BE FILLED i;.' BY SSFABi ------- REPORT 01' ANALYSIS TRACE ELEMENTS pprn - (or si .id samples • ug/ml - for I quid samples Waik (xt lor specific onclysis Mark (x) in block to left of Ident. No. wfien reauesting ell analysis or, thai line 1C •;:••! No. 1 1 • f .H?l 1 \| -»M J L 1 1 ! 1 J L 1 ! 1 1 I i 1 I Be I \| J L J L 1 1 1 I J L 1 I 1 1 \ 1 1 1 1 Cd ! i J.L 1 1 1 1 J L 1 I 1 1 . 1 1 . As I \| J L 1 1 1 1 J L 1 1 1 I 1 1 1 1 V 1 I — . — J-L 1 1 l-l J L ] 1 ' 1 1 . 1 I •i 1 Mn I I J L J L 1 1 1 1 J L 1 I 1 i i 1 Ni 1 1 J L J L 1 I 1 I J L 1 1 1 1 1 1 1 1 Sb 1 I J L J L 1 1 1 1 i I 1 1 1 1 i 1 Cr 1 I J L J L 1 1 1 1 J L 1 1 1 1 1 1 1 1 Zn ! 1 J L J L 1 1 1 1 J L ! 1 1 1 1 1 1 1 Cu 1 I J L J L 1 1 1 I J L 1 1- 1 ! 1 1 1 1 Pb I 1 J L J L 1 1 l-l J L 1 1 1 1 1 1 1 1 Se I I J L. J L ! I 1 1 J L 1 1 1 1 1 1 1 ! B 1 I J L J L 1 I 1 I J L 1 1 1 1 1 I F • 1 \| _j L J L 1 I i \| -J L ! 1 ! 1 . l I- ! \| Li I \| J L J L I I 1 I J L 1 1 •1 1 1 1 1 I Ag 1 I _) L J L I I 1 \| J L ! 1 1 1 1 1 I I Sn 1 1 J L J L 1 1 1 1 J L 1 1 i 1 1 1 1 1 Fe 1 \| J L J L 1 I 1 I J L J L 1 1 1 1 J L Sr I \| J L J L 1 I 1 I J L 1 1 1 1 1 1 1 1 Ma 1 \| J L J L 1 1 1 1 J L 1 1 i 1 1 ! 1 1 K 1 I J L J L 1 1 1 1 J L 1 ! 1 1 1 1 1 1 Co I \| J L J L 1 1 1 1 -1 L l l 1 l 1 I 1 \| Si I I J L J.L 1 1 1 1 J L ! 1 1 I 1 1 1 1 Mg I \| J L J U 1 1 1 l J L 1 1 1 1 1 1 1 1 Ba I \| J L J L I I I 1 J L 1 1 1 1 1 1 1 1 1 1 L J L 1 I 1 1 J L J U 1 ! 1 1 J L I 1 J L J L 1 1 1 1 J L I i 1 1 • ! 1 1 1 1 1 J L J L I \| I 1 J L 1 ! 1 1 I 1 l [ I 1 JLi J L 1 1 1 ! j L J L ! 1 1 1 I 1 1- •',;( ysis l.'eih.ox !-'iiAA. 2-SSMS,-3-OES. •'••AA. 5-ASV, 6-XRF, end 7-oiher Comments: ! 0:-tri Analysis - Use Table B to fill analysis requested (above each column) Mark ui for specific Q.-.a'.'Sis req idem No. \| i ' ! 1 I' 1 ' 1 i [ \ \| . ' i -'C '/>' .'.'•.'•: -ico _J _J . J J J J J U J _! _J J . ,J J . J r-J _J _J J J J J J J J J J J J _J J _J _! J J J J J J J J U J U j j j j _j j j — i j U J J J J J J J U J LJ u • J J J J J J J J . J J J J U LJ U J U j j j • j j _ i j j ,_! J J J' J J _j Cc-rnmenis: ------- ! »r • 31 31 ' -'5 :•• it 3« i 39 • 40 j 41 \| 42 \| 43 f 44 [ 45 \| 46 j 47 \| 49 ]~« j SO T~>l I 5Z j 53 I 54 f 53 It 57 5B 59 60 61 62 63 III I • .SAV.PLiN?, DATE j ^' (1 \ lf\ lYR'i MO ' DAY1 FIRST IDENT. USED SOURCE SAMPLE REQUEST & REPORT (MUST BE FILLED OUT FOR EACH TEST-RUN) LAST IDENI NO. USED. II-DUSTRY (USE TABLE A) COMPANY K? £:££ '^ tl i.."kJ<. ow^sk /rM^i) -ft)^/' T t^oo o«c/\ ' ' TV.-. he ^::i^/- u;^sVv 1 ' . i SAM WT . ' (SOLID) MG PLE VOL '(LIQUID) ML i . ANALYSIS REQUESTED - GENERAL COMMENTS (APPROX CONCENTRATIONS - POSSIBLE INTERFERENCES ETC) (INDICATE SPECIFIC ANALYSIS ON BACKSIOEi «V\n/5< a4)f\v; $•$ 'btllCf ^lc>\nh' ' •( V <« • « . . I— -PROJECT OFFICER. (IF APPLICABLE) / REQUEST -REVIEWED DATE OF ?;:OUEST_._, _DATE ANALYSIS REQUESTED DATE OF REQUEST (TO BE FILLED !.': RY ^f-Aii ------- REPORT dF ANALYSIS TRACfi ELEMENTS ppm • for .solid samples ug/rril • for liquid samples Murk ixi lor r.jc-citic cr.ci'jSi: Work ixi in block tc lei! of idei;. Nj. when requesting oil analysis on :rv:t line ideal No. Hg J L J L J L J L J L J L J L J L J L TL Be LJ L U L J L J L J L J L J L r-J h Q-TJ J L Cd U L U L U L U L U L U L J L U L J L TTL As J L U L U U V J L J L U L U LU L U L U L U L J L U LJ L j Epm U L J L J L Mn J L U L U L U L U L J L J L J L J L J L Ni J L J L J L J L J L J L J L J L J"L Tn Sb J L J L U. L U L U L -1- L U L U J L L' J L Cr J L J L J L Zn J L J L rJ L J LU L U L -1 L J L n/ L- J L J L J L J L J L J L J L J L Cu J L J L\| Pb J L J L J LU L J L U L J L J L J i_ J L J L J L J L J L J L Se' J L J L J L J L J L J L J L J LjJ L J L J L J L U L B U L JL) u g L ~d . r J L ;:rt J L J L U LJ L U LJ L J L — .J L J s.-. H -H h J JJ,h iMilysis Method: 1-NA.A. 2-SSMS. 3-OtS. 4-AA, S-ASV, 6-XRF, end 7-other • i • •' Oiper Anc!y:;is • U:e Table B to fill- onciysis requested (above eoch column) idem No. — — i i — > I _l u :- _J • U • .' LJ ; ,-rCiyS! J J J J J J j '>:-c5 . \| J J _J _J ' • ,_J J J J u LJ J J J J J J J J U J J J LJ J J' J • Li U L :m J L J L J L J L J. L J L J L J L Ag J L U L J L J L J L U L U L J L J L J L Sn J L U L U L U L U L U L U L U L U L U L Fe U L U L U L U L U L U L U L U L J L J L Sr J L J L U L No U L U L U L J UJ L J L J L J L J L J L J L r U L J L K U L J L J L J L J L J L J L U 1 1 L J L J L J L J L Co U L U L U L J 1 U L U L Si J L U L Mg J L BG . V;f J J LJ U LU L 1 1 U L, J L J LU L J L U L U L ' Comments: J U J J J J J _j J J J u J J 1 U J J J J J J J _l J ' J J J LJ J H1- 1 1 M J L J L J L HL , •— 1 1 U L J L -J 1 i 1 II 1 ! ! 1 J I 1 • ' i j i i n ' M [I [ "' FT I [ i U LJ LU LU LJ L r i •• i ' i 1 1 1 ! 1 111 1 1 3T.U LU LU LU U J LJ LU LU LJ L i ! LU LU LLJ LU Li ( i ri 1 i i I Li i i i I l U 1 1 LJ 1 II 1 L i . • ^^ ! I t.'.ork ui for specifi: c:-,:i>:ls tQ~,.-i'.-.c J J U J J J J . J J J • 1 u u u u J U J LJ U J - LJ Ll. LJ • • L! - J LJ J U . J LJ Ccr.meo'.s: ------- r-i i i ' '! ! i J 3 ' 'SAMPLING DATE [7 3! 4 •e - r, INDU -- COM? ^* :: • HOOF --- • :-AMr ?. METi : ;- IDENT'ND 1 , "1 SCJ \ ;h~i^r i IYR! MO ;TRY I • DAY 'Af.'Y f^tr/Sen 1ESS' 5- LING M I Of -L _I ! J LJ , 4, \| 42 \| 4J j 44 \| 4S ! ! 1 Ml ! I '! 1 1 \| i ! i I! H SI i 52 91 54 55 \| 5« \| 57 ] 58 59 60 61 62 <) 64 65 66 \| 67 \| 6« [ 69 \| 70 \| 71 \| 72 \| 73 74 j 75 \| 76 j 11 \ 78 j ?» i <0 SOURCE SAMPLE REQUEST & REPORT . • (MUST BE FILLED OUT FOS EACH TEST RUN) TFST NO 7V M 5" 1 • (FIRST IDENT. j NO. USED • . (USE TABLE A) ^oe MJ^'.W^ ^ ^ EPA o (M ^ r 5 73 oo^ 5i>7 . o&Gi_ LAST IDENT. NO. USED 5 03 OO't SO 'p RUN Nn 0* 'UNIT PROCESS OPERATIC -AIR POLLUTION CONTRC . ' FUEL USE v G INLET JX 0 ') GAS VOLUME SAMPL (MEIER VOL IN FT^ DESCRIPTION OF SAMPLE OR SAMPLE FRACTION \A-\p£-' ' y^fix'tf-'r VA\ii$ K -T-//EI" (^'1 OOr/or/.-c/ v^pingc i»C -( le -dc.-vhiAA.'.cvA IL ^ b c-\\\t<> \ _- \| •; I I o 1 . i , 1 • - t - _ ' . „ i • '• : L ., I COMMENTS: ~\ ' 1, SAMPLING CONTSACTO DATE OF REQUE 3 Dr "SI •We Ke. (IF APPLICABLE) • DA PRO TE ANAl k SAMHI: WT. ' - (SOLID) . , MG ! VOL (LIQUID) ML j ( : i '• . JECT .YSIS OFFinFR (^A\L REQUESTED N \|~«v\€. (. v'xOnPi'' ,- /if' 94-, / . )l [•^nrf t^fV^MH' . (\0"tTJiJ.\li)/vP D H £U i fe. JTLET • :n /o. 7 . • • • ) ANALYSIS REQUESTED • GENERAL COMMENTS (APPROX CONCENTRATIONS • POSSIBLE INTERFERENCES ETC) (INDICATE SPECIFIC ANALYSIS ON BACKSIDE) -mm s,<.[>i> ------- REPORT )F ANALYSIS TRACE ELEMENTS ppm • for solid samples ug/ml - !or liquid samples Mar1' ixi fo: sij-ici'i: c'.:.'vs:s '.'.iff. ui n biotr. ;o !•:•!; c! !•-•::•:. .'. requesting oil or.cl',sis on thct line v,r.-:n -idem No. i Hg hJ L J L J L rJLi U L_ J L J L J L J L J L dfj'jlysis Me:had: Be J L r-l L J L J L J L J L J L J L F^ Cd J L J L J L J L J L J L J L J L J L As • J L r-l L J L ' V" J L J L J L J LLJ L ircr J L J L J L J L J L J L J L J JLJUJ L r f.'.n J L J L J L J L r1 L J L J L J L ITC Mi J L J L J L J L J L J L J L J L :m J L So J L J L J L J. L J L J L J L J 3' J L T Cr J L J L J L J L J L J L J L J L J i_ ire Zn J L J L J L J L J L J L J L J L J L J L Cu J L J L J L J L J L J'L J L J L J U L L Pb J L J L J L J L J L J L J L J L Se J L J L J L J L J L. J L J L J L J LJ L J L J L 8 j L J L J L. J L. J L J L. J L J J J L H H r J-L J L J L J L J L J L J U J L hJL r11- Li \| Ag J L J L J L J L J. L J L J. L J L J L J L J L J L J L J L J L J L J L J L J L J L Sn . J L J L J L J L J L J L J L J L j L J L Fe J L J L J L J L J L J L J L J L J U J L Sr J L J L J L J L J L J L J L J L J L J L No J L J L J L J L J L j L J L J L J L J L K Co J i J J L J L J .L H L J L J L J L J L J L L Si 1 1 J L J L J L J L JL^JL J L J L J L J L J L J L J L J L J U J L J LJJ^L Mg J L J L J L J L J L J L J L J L J L J L_ 3c J L J L J L J L J L J L J L J L ! :i-:£ ' J L 1 i ; i LUL, _ J L.J LJ LLJ Lj J 1 ! LU LJJ L J LLJ LLJ L-J L, _l LU LU L-J LJ i i i J Lpl L-jJ LJ L J LjJ 1 1 1 1 L _l LJ LLJ LLJ L r i "i J 1 11 1 LLJ LJJ Lj J i? ^ '-H H-' H 1-fiAA, 2-SSMS, 3-OLS, 4-AA, 5-ASV, 6-XRF, ond 7-other • Comments: . _ - t Otter- Analysis • Use Table B to fill ana ysis requested lobove each column) V.crV ui lor specific cr-c'-ysis re:-j?s-ed Iden; fio. ... I... ' /na!ysi 1 ?!hcd g j g j U g j j U g g g g _i g g g j g g g g g LJ j g j j g g g j j j j j g j j g • g g g g g g ^_\ g LI ' g g g g g i g g g g g g g g g g g U g g . g g g g j U' • j j. g g g - g g g _j g g g g g g g g g - • _j g _j g - g , i J Con-,me-;s: . . ------- ! i 1 ! 1 1 ! !•-: ! l-l 1 1 \| 1 ! 1 \| 1 1 1 i -1 1 MM M 1 M I M I .1 SOURCE SAMPLE REQUEST & REPORT • ' 1- (MUST BE FILLED OUT FOR EACH TEST RUN) ' L . . . ' ' • i_ 'SAMPLING DATE \m\ rv. SAf/PMHG fW. CPA 5^ M;iV.pr/e -^,lUr) • METHOD DESCRIPTION OF IDENT NO SAMPLE OR SAMPLE • , FRACTION £io. P:Y!H' tCtfJer t-orwk ^\|i !-Q".l-he.r (. l ooo orj^.) ' -V 'tc P /" "7 A -fj-lx>f\ • i ! _ ' UNIT PFCCr.SS OPERATIC AIR POL.UTION CONTRC FUEL USE .[] INLET fXO GAS VOLUME SAMPL! (METER VOL IN FT^ SAM WT (SOLID) MG I'LE VOL (LIQUID) ML N tOflSTt: .GAS VtA-lt r " I .JYO-M.^- ( ' -- •• . •••: • \| JTLET . _ ' . : - j" :n /^.7 i , ANALYSIS REQUESTED - GENERAL COMMENTS ' .• r (APPROX CONCENTRATIONS - POSSIBLE INTERFERENCES ' t— ETC) (INDICATE SPECIFIC ANALYSIS ON BACKSIDE) r- mil-Si' t a 4J>t'.ic > H ' •';"-•• "•• ' " ?(!, K»V^ p,»,t.Jftv5.-.l« ' \|~ • • rr i^ r^ i if , J f -. \ " * 1 ' "* 1 1 1 — ' j 1 i Cnv.MFNTS: • . P • -i — SAMPLING O It il. • • ~, J -ij \|j REQUEST // / / '- L_ r.O.'iTRACTOR- - - QiTl^U^ ' PRO IFf.T nFFICFR -U-^/,«Jnf-A \|\<°IL) RFVIFWFn RY AA 9/17/1) \ (IF APPLICABLE) '. . • \~ DATE OF REQUEST. .DATE ANALYSIS REQUESTED DATE OF REQUEST. (TOBE FlLLEOlJ EY SSFABi ------- REPORT OF AMALYSIS TRACE ELF.UENTS ppm • for <,o!id samples ug/rnl • lor liquid samples MOI'K (x) for Specific cr,cl,sis •r.i'jrV. Hi in fjioc'* to lei! o! iC'.' requesting oil cnclysis or. f.s; No. v;nen i;!en! No-. Hg \| Be i \| ' J L. - .... J L ITL. J UJ L J L J L J L J L J LU U I J i 1 i J L :m 1 1 TT Cd J L J L J L J L J L As j V J UJ L J~ULTE J LJJ L i J L J L J L J L J 1 J LJ L J L_ ITU ~rr JL\|JL_ — 1 — 1 — — PT~ ITL J L J L U L i Wn J L J L J L J L J L J L J L J L J L J L Ni J L 3"L J U J L J L J L J L J L J L J L Sb J L J~U J L J L J L J L J L J L J L Cr J L J L J L J L J L J L J L J L J L J L Zn J L J L J L J L J L J L J L J L J L J L Cu J L J L J L J L J L J L J L J' L J L J L Pb J L J L J L J L J L U L J L J L J L J L Se J L J L U L J L J L J L J !_ J L J L J L B J L J L J L J L -F J L DTI Pr IJ'L J-LjJ L U UJ'L, J L J L J L J LjJ L J LJJ L_ «:;>"..;n Vs.-.iiofl: l-.'iAA, 2-SS.V.S, 3-OfS, 4- A A, 5-A3V, b-XRF, end 7-otner Li J L J L :rc J L J L J L J L J L J L J L Ag J L J L J L J L J L J L, J L J L J L J L Sn J L J L J L J L J L J L J L J L J L J L Fe J L J L J L J L J L J L, J L J L J L J L Sr J L J L J L J L J L No J L J L J L J L J L J LU L J U J L J L J L J L J L J L J L K J L J L J L J L J L J L J L J L J L J.L Co J L Si J L J UJ L J I LJJ L J L J L J L J L J L U L pJ LLJ L JLUL J U J L J L J L Mg J L J L J L J L J L Bo J L J L \| J 1 i \ [ J L "li.'i'j' ' J LU LLJ LJJ t i L It'1 J L J L i ! J L J L\|J LLJ LpJ L U LJ LU LLJ LU L i i i J L J L J L J L J L UL] irn -l^rh J-L J L J L J L J7LU L inrni J L_U L i J LLJ L i J L r1^ ' J L J L J LLJ L—l L i i^ Comments: :,' : -•- -- T i ' t!,f?r Analysis • Use Table B to fill analysis requested lobove each column) f.'arV. ix) lor specific cr.aiysis rec^sste:! I'Jer.t flo. • ' • ------- 1 1 ' ! ! 1 I : : 1 .i : • '32 ' JJ ' 34 •' 35 16 J7 •. SAMPLING DATE \U h^! , // •> i -5 j~ "'"' •'i r ( • * f ~~ . .. , ..... - ' i — c - I [7 !" • • i 7 h~ c 0 i .Jl 1 Is ! 1 - JECT .YS'IS /V -L \J \] ' REQUEST ///7 y I nFFinFR />J. u\.y^-i"^ fC^-'i (u RFVIFWFD-BY ji^o '->/i7/l^> s REQUESTED DATF OF REQUEST ' 11 EPA(DURi245 (TO BE FILLED IN BY SSFA2) ------- REPORT 0- ANALYSIS • TRACK ELEMENTS ppm • for s>l id somples ug/ml-- hr iquid somples f.'.Gf'K ixi for spec.fic c.-:'.,-3is f,'.crt( ixi in b'cck io Isii ct Uor,:. ;;o. v.nen reouesting o!i cnclysis on ;.-,:: hne 1; •3ifi No. Hg J L J L J L J L J L Li L i ' Be J-L J L J L J _ J L Cd J L J L r1 L J L J L r As J L J L r1 L J L U L J i I IJJ L _! L , 1 L 1 - LJ U , Ul_ HL J J~ T L 1 1 1 T VTT r ~rr 'I i l J L^ £ V J L J L J J L E J L J L J L J L ini Mn J L J L J L J L J L JL mc J L JT: Ni J L J L J L J L J L J L me J L J L J L Sb J L J L J L J L J L J.L TT: J L J L Cr J L J L J L J L J L Zn J L J L r-l L J L J L .1 1 i 11 l J L -4 L J L J L J L J L J L J L Cu J L J L r1 L J L r1 L J L Pb J L J L^ J L J L J L Se • J L J L J L J L J L J LJ. L J Lj U JH J L J L J L J L B J L J L J1 L J L J L J L JLUL J L J L J L J L: J LTJ LTJ L; F J L TC J L J. L J L J L J L :rr: J L Li 1 Ag J LJU L J UJ L J i 1 L J LJ L J 1 I L J 1 1 L J 1 1 L J [ 1 L J 1 1 L J LJ L Sn J L _l L J. L J L J L J L J L J L J L J L Fe J L J L J L J L J L J L J L J L J L J L Sr J L J L rJ L J L J L J L J L J L J L J L No J L J L J L J L J L J L K J L Co J L J LU L 1 ' J1 L J L, j L! U L U l_U 1_ i J L J L J L J L -1 ,L J L J L J L J L J L Si J L J L Mg J L Ba J 1 ! L ! \| J LJ LU LJ_ J LJ L J L J L J L J L J L J LJ L_ i i ! 1 M 1 1 1 J LJ 'LJ L j LJ LJJ L J LJ LU LJ L 1 i J LU L_ J LJ LJ 1 J i_\|_! I_U L_U LU LL J UJ U J LU L J LJ L J L J L J LU I JLULL J LJ LJ L_ l J L FLU UJ L J LJJ L H.M 5 ;:;?.!',"' j LLJ LU U j LU Lu L 1 J LU LU L J 1 1 u U U i V^iyiis f.'.e'iiori: -NAA, 2-SSMS, 3-OES. 4-AA, 5-ASV. 6-XRF,- ond, 7-other . ••'; . Comments:. • C — • ... her AnoiysiS • Use Tcble B to fill analysis requested (obove each column) . 1 luC-nt No. U • • J J J r-J rnolySI '•'. etliofl J J J D j _J J _J U J U hJ • • J J J J J J J J J L J J , _J LJ LJ j j j LJ J Li J • J' u J J u J •. J . J J . J- J ,J i_J u 1 u J J J D J J J _J J • J LJ ,J J J Mark ix) for specific cr-c! J -U J :U 3 J J J LJ J ' U J LJ ' ' u J ,_! U u J u ysis req::»5:e5 J • u U U U M U U LJ . _J ".omments: ------- 12 , JJ I 19 \| ! I 55 i «J_= (MUST BE FILLED OUT FOR EACH TEST RUN) 1 7 ),. 59 60 61 (2 6J 64 05 66 1 67 I 68 \| \| 69 \| 70 j 71 ! 1 J ii iii I ! '• i 75 \| 74 ! 77 7. \| 7. ' 80 \| JEST & REPORT - ' \|lj SAMPLING DATE \|73! 9 12. i YR I MO i DAY' FIRST IDENT. NO. USED £ > 73 OC »M- tJK, I LAST IDENT. ! NO. USED J93 TEST NOj?J£Jt&5_ RUN NO &> ' (USE TABLE A) INDUSTRY _ COMPANY J^c ADDRESS S.lU<£ DOuH_)._J^!].lQlW. SAV.PI i?: METHOD 'UNIT PRCCtiSS 'AIR POLLUTION CONTROI ___ D.£&£ FUEL USED. . [] INLET R OUTLET GAS VOLUME SAMPLED (METER VOL IN FT3) IDENT :iO 3/fc , £' 'Loafer iAHi-->k ^:\|Wf»ooor,^fi\ .lr»\p'.vQf?r r'vicxc vd'>T-iv^.'>k (^2. bf'friP 5 1 WT (SOLID) MG I'LE VOL (LIQUID) ML " ANALYSIS REQUESTED - GENERAL COMMENTS (APPROX CONCENTRATIONS • POSSIBLE INTERFERENCES ETC) (INDICATE SPECIFIC ANALYSIS ON BACKSIDE) •vi/t/l; adf-Jtx • ' • ' it .- v' •' CVb i />'/' ""(•''/') . SAMPLING CONTRACTOR. .PROJECT OFFICER U^ REQUEST -REVIEWED-BY. (IF APPLICABLE) DATE OF REQUEST. EPA(DUP.C!5 .DATE ANALYSIS REQUESTED DATE OF REQUEST. (TO BE FILLED IN BY SSFABi ------- REPORT OF ANALYSIS TRACK ELEMENTS ppm - lei silid scrnplos ug/ml • f:r liquid samples Mc:k ixi lor soecilic cnoiysis MorV. («) in bloc tc left o! ICv-'t. N recuesting ci! ooclysis on tr.ct lire Idr-t Mo. — Hg 1 _ J U 1 j 1 — • j J L. J L J L ~rr Be J L J U J L J L J L J L Cd J L J.L Tp J L J L J L As ^h JL, LTD J L J L ,J L J LLJ LJ LU L i i p LJJLUL TIT J L J L i 1 1 1 J.L LTL J L V 1 -1 Mn I I J LJ L JT J L J.L -J-L J L J L J L Mi J L So J L J LjJ L J~C J L J L HVU J LJ LJ l_ mi— J-L ITU EL L JT: J L ^ J L J L J L J L J L J L J -L J L Cr J L J L J L J L J L J L im J L J L Zn J L J L U L J L J L J L J L J L J L J L Cu J L J U J L, J L J L J L Pb J L J L J L, J L J L J L J LU L • i J L J L J L Se J L J L J L J L, J L J L J L J LLJ L J L J L J L J L B J L J.L J L J L J L J.L J L J L J L F ...j i j-c J L 1 ! J L J L J L J L • Li r1 L J L h J L J L J L J L J L J L J 1J L Ag J L r j L LJ L J L J L J-L J L J L J 1_1 J L Sn J L J L J L J L J L J L J L J L J L J L Fe J L ! 1 i i J L J L J L J L J L J L J L Sr i-J L 1 1 _\| 1 J L J L J L No J L r-1 L J L J L J L J L K J L J L J U J L J L J L J LLJ LJ L J L J L J L J L J L J L J L J L J L Co J L J U Si J L Hg 1 1 J L J LLJ L J 1 1 L J LLJ L J L J L I 1 _j L_ J L J L J L J LJ LJ L J LJ LJJ L J LJJ L J.L J L J L J L Bo J L_ 1 1 i J LU L J LLJ LLJ L ,, J L J L^i L J LU" LU LU L J L J L J L J LrJ L J I 11 1 1 J LJ L 1 1 J L_ J LU LJ L J LU LJJ L, J L\|J LJ L J L J L J ^ J L J L OTLJL J L J L. J-U J L j L "\:',: V,5 J LJ -~ J L J-L A- ;lysi'/ Vet'r.c.d: -!iAA, 7-SSMS, .3-QHS, «-«A, 5-ASV, 6-XRF, end 7-cther ' Comments: j;i'er Analysis - Use Table B to fill cnoiysis requested tobove each column) Work ix) (or specific or-oiysis1 requested I i L: idem NO. , ;;,st - i.'VU J J • J • . J J U U J J U M u j _j j _i j j j • u- J • J J J J J J J hJ J J J 1 J J r-J _J J J J J J J -J J _J J ^1 ^ U J _J ,J J J _J J J J J J J J LJ u J J g j j j • j j j j j j j j j J ] j LJ LJ U J J J -J J J • J i J U • u _J i J rJ U ' J Ciimrr.er.ts: ------- ! 1 \| 58 ! 59 60 61 62 03 64 63 I .LI. . CS \| 67 \| k» \| « i ! i ! J M 1 ! i 70 1 71 i 72 ] 7> \| 74 j 7» \| J« i T> • It \ ?» ' «O : SOURCE SAMPLE REQUEST & REPORT ' SAMPLING DATE \|-- :Y - 1 I fj INDUSTRY _ 1 "! ' COMPANY :i ;"V ADDRESS , i :! ; METHOD -i — < • 3 j ;! IDENT NO • 1 = i ' :"i L_£Aj!7 IZ • TFST r;0 ?^/TW?/ Rj ,,0 DAY FIRST IDENT. ; LAST IDENT. NO. USED 5-?3-0£y -5;^ ;KO.USED3-?3-OOy- JT2/ RUM NO 7 (USE TABLE A) . •Si lOev -S!XH . K>v\»x . t l ^Ci G"PA o ^H'^Vipo.'ip \-« ur/") DESCRIPTION OF . SAMPLE OR SAMPLE FRACTION -cV U\>J-e/ lOrts( ' .(!€< Cicoon/-.a^ ,p..v P." o^ U.Jk .j».AiU f -j h^i\es) ' • _; i i • .j i i i pf)* ** ,£ 'T^' UNIT PRO-JESS OPERATIC AIR POLLUTION CONTRC FUEL USE D INLET j^ 0 GAS VOLUME SAMPL (METER VOL IN FT3 SAMPLE WT VOL (SOLID) (LIQUID) MG -ML • • • • , i 1 1 N (AVi'/e Q\\j Jc^T ii \J&+\p o • • " JTLET " ' • -n ox> , 2. ) . ANALYSIS REQUESTED • GENERAL COMMENTS (APPROX CONCENTRATIONS - POSSIBLE INTERFERENCES ETC) (INDICATE SPECIFIC ANALYSIS ON BACKSIDE) flAfl, /ll/lC'^'i '.I.-'' il - 3(, £ .-Atfd /-^ A-t5f.fr • • •- i - 1; SAMPLING ,: CONTRACTOR r\ LJ\\- ' ' \ \ .; It REQUEST uy / / H'"-^' ------- REPORT CF ANALYSIS' TRACE: iiti.iEfiT?,' pprn - lor : olid samples ug/ml • for liquid somples MurX Ul 'Of SP'iClIiC CT.I', t.'.CiV 1» in b'.Si'V to If:': C' !.:•;:-. i No. '-15 Be l 1 \|.L I ' h ^ L Cd J L J L U LJJ UJ L t J LJ LJJ L j J LU LU U J LU LU L i H 4^ - LJ LU L !J LJJ L "- iiiTrrt: ; i , J L 'AS' J U nv L J LJJ U f J UJ L Hh JL, J L U LU U i J L. Un i 2-SSf. -J H JTl J J L r MM r1 L J L J L J L un J LU L y J T LL! U U n J L J L Ni J L J L J L J L J L J~L J L J L Sb J L J L J L J L J L J~C J T i L P r Cr J L J L J L J L J L J L J L J L Hh Zn J L J L J L, J L\| Cu J L _, L J L J L J UJ L J i ! J U J U J L J L J 1 1 J L J U J U Pb J L Se J L J LU L J L J L J U 1 1 J U J U J U J L J L J L J L J L J L J L J L J L B J L J L J L 1 J L :3L~ J L J LJJ L t J LLJ L J LJU L J 1 1 U i J L J U J'L G; 3-OES, 4-AA, 5-ASV, 6-XRF, and 7-Other (7TI -J L Li J L J L J L J L J L J L_ J L J L J L J L Ag J L J L J L J L J L J L Sn J L Fe 1 J L J L J L J L J L J UJ L J L J L J L J L J L J L J L J L J L J L J L _j L J L J L J L Sr J L J L J L J L J L rJ L J L J L J L J L No J L J L J L J L J L J L J L J L J L K J L J L J L J L J L J L Co Si Mg Bo j ;',;:V. ' J 1 II 1 UJ UJ LU LU LU L J LU L_U UJ LU LU L-LTUJ U 1 !^ 1^ ] ! 1 JLJJLULJJLULULULUU ii i i l J UJ 1 11 1 UJ 1 1 UJ LJJ U r \ - i i i J UJ 1 1 1 1 1 1 LJJ LU LU Lj J UJ LU UJ LU UJ LiJ LU L_ J I_U LLJ LJ LJJ LU LLJ i ! LU U J L J l_J J LJJ L 1 J i i r T r . LJJ UJ 1 l U_i U l ^ .!..!_ J UJ 1 I UJ -1 i i 1 LU UJ U ! i i 1 U LU UJ -'UJ 1 1 LU LU LJJ U 1 i i : i Comments: •'"' ". ' • C.-'.r.f.t Ancr/:iS • Use Table B 10 fill analysis requested (otovq each column) U'?nt iio. ! U i : — 1 j . u • '• H • •• i D i- • u u i • • u : LJ • ^_ ! ] g 1 H ! L ! l U , -- ,s; '•'!? . T'C'j j U J J J - J g — ' j j j _] J • , g g J J g j j g I.Vf:ui«crspec;:,C3-:!y-J.3-rc.:.;!:-.r: . g g j n • n J J J J J . J J _j J g g j j J J U g. j J J J u J • i • • 1 J l ! J LJ J U J LJ g u j LJ g g . __ l j j j J • • U U . J J J J • g u u g u . .. i i ------- " 1 ! ! I -1 I ! i 1 I" ! ! 1 ! ! ! 1 ' 1 1 ! M \| ! I ! 1 ~;= • • , SOURCE SAMPLE REQUEST & REPORT • \|- -;; . : . (MUST BE FILLED OIT-FOR EACH TEST' RUN) •'• ' -SAMPLING DATE 7^! fl ! ;3 ' TFST NO 'jy tfA£~t i* JYR; ««o i DAY FIRST IOENT. LAST IDENT. ~7; • . ' L'" ' NO. USED 5- 7. 3 "CO V - ,5-2.2 • NO. USED S~93 c6r->lO j 1 \ * ™ ' 0^-71 ^/vxp^ y\C fy1" £ t-^ t'-V-k % H"^A^^/t\ { ^ ^1^1'^? 5 I I « v. / - -j • ! - - • i ' 1 ; '- 1 ' Ui UNIT PROCESS OPERATIC AIR POLLUTION CONTRC FUEL USE . -;:.i INLET .y o GAS VOLUME SAMPLi (METES VOL IN FT3 . SAMPLE WT VOL . (SOLID) • ; ' LIQUID) MG ' ML • 1 ' "Tj j COMMENTS: N l4trr,(I l/e^vr r ; j 11 k.V^-r\ P . U r ;— D JTLET _ 0 . rn c 3 • / • _ j ANALYSIS REQUESTED • GENERAL COMMENTS j (APPROX CONCENTRATIONS - POSSIBLE INTERFERENCES j- ETC) (INDICATE SPECIFIC ANALYSIS ON BACKSIDE) ' 1 r / Wv?> i (\;kc'')i->-. ', .. . 7 L^v I/ (I <. REQUEST ^/ / ^ J_ i (IF APPLICABLE.) ;"' DATE OF REQilFST DATF ANAI YSIS !": RFOIIFSTFn ' OATF OF RFOllFST ' ll '-1 EPAfDURi^S ' " ' " (TO BE FILLED IN BY SSFAB) j = -r— , " • J— ------- REPORT OF ANALYSIS TRACE ELEMENTS ppm • lo: soiid samples ug/rnl • k" liquid samples Mo I'd ui 'or specific. "Tis'.ysis f.'crk HI in block :o i!i '' !;•?"'. No. v.ren reaueslmg oil analysis on ;-.:! i;.ne lient No. Hg r • U L J L Be U L U L J LU U i i J L J L J L J L Cd J L J L J L u i_unj J L J L J L J L J LU L 1 . JJ LU LU L • U LU I r HL J L 1 \| TU As • J L J L J L J L J L J L J L J L TIL J~C V J L J L J L J L J L J L J U J L J L -J L_ Mn J L J L J L J L J L J L J' L im J L J L Mi J L J L J L J L J L J L J L J"L J L So J L J L J L J L J L J L J L J L ITL J L Cr J L J L J L J L J L J L J L J~C J L Zn J L J L J L J L J L J L J L J L J L J L Cu J L J L J L J L J L J L Pb J L J L J L J L J1 L J L J 1 1 L 1 J L J L J U J L J L J L Se J L J L J" L J L J L J L J L J L J L B J L ITT:: J L. 1 I J.L J L J L. j i J L F I \| _J L ..J L 1 \| J L J L\ J L J L 1 I J L Li J L J L J L J L J L J L J L J L J L J L .Ag J L J L Sn J L J.. L UELJ L 1 1 1 1 1 J L J L J L J L J L J L J L J L J L J L J L J L Fe J L J L J L J L J L J L J L J L J L Sr J L J L J L J L J L J L J L J L J L J L No J L J L J L J L J L J L j i_ J L J L J L K J L J L Co J L J L J 1 1 L J L J L r1 L J L Si J L J L Mg J L J L ULJL Be J L j \| \| L i J J LU LU LJ I t 1 J LU LU LU i 1 > J LU LU LU L J LU L J L J L J L J L J LU LLJ L J L J L JIUUL J LJJ L J L J L J L J -L J L J L U LU LU ! i J 1 \| i LJ J UJ LJ 1 ! J 1 i LU L i -i J L J LLJ L J IT J LJ LJ LU LJ J LU L J 1 1 L 1 ',:.".,- LJ L,. -Hh J L LUT: LU L LUL LJJ L_j J L A.KOiysis f.'et^cd: l-'iAA, 2-SSMS. 3-OF.S, 4-AA, 5-ASV, 6-XRF, and 7-other • ' Comments: J Lj ( • j C'ner Anc;/:.is - Use Toble B ;o fill cwiysis requested (above each column) Mark (xj !cr specific crc:;,sis .-eciesie.; j ) '-: Ident No. • . n:ys; rteA J U J J U j j LJ . J J J J J - _J J U J . ,J J J J J i J iJ J J U u J J _J J LJ J J J J J J J J _J _J LJ LJ J J J J J J J g J j j j j j j j j j j j u j j j • j j J _i j j j j- j u J J u J J J J 1 I J J I J u _i U ' u u i — I D j Ccrr.rnsr;;: ------- 44 I 41 \| 16 ! 47 \| 43 49 505I \| 12. 53 UJ-LLLJ I I LU-4- _L 156 I •>: i 58 I S3. \| 60 61 \| 62 \| 63 \| 64 I 65 66 \| 67 \| 68 \| 63 \| 7 SOURCE SAMPLE REQUEST & REPORT (MUST BE FILLED OUT FOR EACH TEST RUN) SAMPLING DATE \|;/-\|J_qJ )3_\|. jYR ; MO I DAY [FIRST '.DENT. I NO. It.'OUSTRY. (USE TABLE A) i\ I A. x COMPANY \^:.fr^r IA ADDRESS . f.F.THOD S i . X i ~1 H.AST IDENT. _J \|f!0. USED 3-f?3-gf'1' TEST N0___ RUN NO——^ ' UNIT PROCESS OPERATION AIR POLLUTION CONTROI FUEL USED O INLET TO OUTLET GAS VOLUME SAMPLED (METER VOL IN •13.-7 DESCRIPTION OF IOENT «() 1 ' SAMPLE OR SAMPLE . ' \| • FRACTION ! . , $2't \ prH'e L.«J.4f»- co'.^,k .... ^2h \ j^;-\nr,- ( \OC.i: f>(C\\ ^2? j U-^'^Pr' £ C-.v-T-V.V-k -4-LAj.-L-Jov-,.-,,':jj* I CO Vi ML NTS: SAMPLING CONTRACTOR \ DATE OF REQUEST -PROJECT OFFICER (IF APPLICABLE) CER Lf\ .sOWvy. YO t'l REQUEST .REVIEWED .DATE ANALYSIS REQUESTED DATE OF REQUEST, (TO BE FILLED IN BY SSFAS) ------- REPORT OF A'MUSIS TRACf: ELEMENTS ppm • !o( solid soinples ug/ml • dr liquid somples Mu.'k (xi !cr sciCi'ic Ci'.si.S'.s Vcr1'. IXi in il'iOCk to 12K C! iCC"-. '.'C. requesting oil cnclysis on that I me Ideni No. Kg Be Cd As V t J L.J 1 i UJ UJ L. J UU 1 1 LJJ -1 1 L J 1 1 1 1 1 I L 1 L J UJ LJJ UJ UJ L J UJ UJ UJ i 1 U l i i U LJJ UJ 1 i UJ L i ' i • U i \| J LU 1 1 [ T ^ i i H"1 ' — ' U LJJ LJJ LJJ LJJ i 1 l L r Mn J L Ni 1 1 U C J L J L J L J L J L J U HL LJ LJJ (UJ 1 i .1 1 UJ U J L J L J L un J L J L J L J L ^ Sh J L U L J L J L J L J L J U J u L H Cr J L J L J L J L J L J L J U J U J. L Zn J ' U L J L J L J L J L J L J L J U J L Cu i t U L J L J L J L J L J L J L J L TH Pb Se J LJ L J L J L J L J L r1 L J U J L J U J L J L J L J L J L. J L, J L J L J L J.L 8 IF jr.: J L J L. J L. J L. J L. J L. J 1 J L J L. 1 1 J L ..1 L ::m ..! L J L ..1 L i \| ! 1 .J L Li I \| J L. J L. J L, J L J L. J L. J L J L J L Ag J L J L J L J L J L J L J L J L J L J L Sn J L U L J L J L J L J L J L J L J L J L Fe J L U L J L U L J L_ U 'L J L 1 \| J L Sr J L J L J L J L J U J L J L^ U J U No J L U L J L J L J L J L J L J L J L F^KM1- K Ca Si f.'.g Oc ",;.::" 1 I 1 1 1 1 1 1 i 1 I ! i ' J UJ LJJ 1 II 1 J LJ LJ LJ 1 i l J LJ LJ LJJ LU 11 ! i \| 1 II III 1 Mil!: f t LJJ U LJJ U i LJJ U i i " i LJ ULJLLlLJI 1LJLJUJ ..M\| j j \| \| J LJJ_ UJ LJ LJ LJJ L_J UJ 1 1 U J 1 ! L .j ) I 1 1 . 1 1 1 \| 1 LJ JJ L, ' J L LJ LJ 1 1 UJ LJ LJ J LjJ LU 1 1 1 ! LJ 1 i LU J J I. l-j 1 ! 1 •] 1 i J 1 l \| \| 1 \| i 1 i LjJ LJ LLJ LJ U A;;c!ysis f.'5tr.od:.l-flAA. 2-SSMS. 3-OES..«-AA, L-ASV, 6-XRF. and 7-other • Comments: i .Direr Anc-ijsis • Use Table B to fill analysis requested (above each column) . I.'crk ui lor specific c^-lysis recjjes-vJ j Ident No. ' " 1 i. i t • • ' J u . g P ' g U u • g g • . g Ar.O!>SJ .vettoa - i _j j .j _j _j • _j _j _j J • J J J J J g j j LJ -J J - J _J g g j j j g — ' g j j g g j g g U g j . j j j j j j j J J J _J _\| _l J J J J _1 J J J J J J U g u j i i _J _J g. g u j j g : LJ J U J g J j g • u u • Comments: ------- 'MM 'SAMPLING DATE INDUSTf CQMPAr ADORES SAMPLI METHOC IDENT NO •52 ' ' 'f-f'tji ~~--> -, ; 1 \| ^•<\ hv YR'j' MO j DAY }Y ;G £rpA£ ) M M i j FIRST IDENT. j NO. USED i (USE. TABLE A) &- /Vjr™ ^l (ujfl;^ i i 5-03-00 ^iw . LJ_._L 1 _L1 I _J l-t-L.--!-. J— U- Ul- ' 1 L L'l '4 L SOURCE SAMPLE REQUEST & REPORT ' ^[' (MUST BE FILLED OUT (OR EACH TEST RUN) ' ' "i" TFST HO 7^ /^^ /_. I'! ILAST IDENT. • . ' :!. fzt INO.USED S-K-cotf - 36 . RIIH Nn /^ • -f , . DESCRIPTION OF SAMPLE OR .SAMPLE FRACTION 'rV.ii.£_ ' v.o.c ^-vVr_W_l© ,^ve,^ dW i,o,iax -fr^W^e; \J-vJO_, rt (^bc v_ , \| .^J i COMMENTS: UNIT PROCESS. OPERATIC AIR POLLUTION CONTRC FUEL USE C INLET fX.0 GAS VOLUME SAMPL (METIER VOL IN FT^ SAM WT. (SOLID) MG P.E VOL ~ (LIQUID) ML • n / ' j 4- • ' 4 N /Ni'm« U3^vX [.! IV* c' jj_j_ ii A^I(° [it. D r.f JTLET ^^ ^ ' T'i" -n 2 .-5 • 3 • • L ,_ ) j\|_ ANALYSIS REQUESTED - GENERAL COMMENTS 17 1 (APPROX CONCENTRATIONS • POSSIBLE INTERFERLNCES r-f ETC) (INDICATE SPECIFIC ANALYSIS ON BACKSIDE) • '\ * ) IflA.^^ />^?if'/."!fr>«: ' ! •» 1 / V/- ^- ^ J ,r \| ^i o I ** 1 iM tlj i •• i 17 ] j i "=1 3 ! •sl i ! -1- SAMPLING CONTRACTO DATE OF REQUi R 1ST * '•Ml* (IF APPLICABLE) HATF PROJECT UNALYSiS OFFICER L REQUESTED /wi^ kin, ;PEsn RV Ma/n/75 II ; DATE OF REOUFST ' ^J (TO BE FILLED IN BY SSFABi = j n ------- REPORT OF ANALYSIS TRAC€ ILEMENT3 ppm • kir -.olid samples ug/ml • for liquid samples Merit o.i lor sccci'ic or.jj'ysis- ' ' \:,'A (ti in biocX to !!; c! i;o".t. 'ij. v.i.er. requesting all cr.oiysis on tnct line Ident Mo. . Hg j L ' J L J L J L J Li Be J L . Cd J L J LJ L J L J L J U U LU L U L H L J-L J !_ j 1 J L J L J L J L J LJ J L As J L J L J L V _ J J L Mn J L LU L rujnTi J LU L J L 1 \| J LJ L UTL :rc J L TH J L i J L ITQ JL A:;ciyj:s f.'s'.r.os: 1-riAA, 2-SSMS. 3-Of.S J L J L J L J L J L J L ITL Ni J L J L J L J L J L J I., J L J L J L J L Sb J L J L J L J L J L J L J 1^ -I LJ J L Cr J L J L J L J L J L J L J L J L J L J L Zn J L -1 L, J L J L J L J L Cu J L J L J L J L J L Pb J L J L J L J L J L Li LU L J LU L J L J U J L J L J L J L J L J L J L J L Se J L J L J L J L J L J L J L J L J L J L , — . — J U J UH J L J L J L _l i_ J. L J u J L '• J L TL" J L J L J L 311 Li J L J L J L J L J L J L J LJJ L an J U [j L • J L J L J L Ag J L J L J L J L J L J L J L J L J L J L Sn J L Fe J L Sr J L J UJ LJJ L J UJ L J L U L J L J L J L J L J L J L J L J L J L J L J L J L J LU L J L J L J L J L J L J L No J L J L J L J L J L J L J L J L J L K J L J L J L J L J L Ca 1 1 Si 1 1 J LJ L J LU L nn J L J L J-L Mg J L J L J L J L J L. J LU LU LU L J LU LU L JLJJLJL J LJJ LLJ LJ J LU L JLJL J L Be J L ULJL J LU LJJ L J UJ LJJ L J UJ L j i 11 1 1 ! i J LU L J LU L 1 i J L M J L J L 1 ! J L J L ^ L J.L _i i_ Hu 1 1 J L 1 I;::' J L zrcj-Li "— i J L.J U J 1 J LI J L 1 J U 1 J LJ L J LU L_\| JUJL J LU U J LH ^r h , 4- A A, 5-ASV, 5-XRf, and 7-oliier . ;-' Comments: - : • . - ' - • . i Q;r-er Analysis • Use Tcble B lo (HI analysis requested (above each column) •'•' - ' . Work (xi for specific onsiysis rs>"uei;?a Iden! No. 1 I • ' J 1 J -• • J u _J . _J . J ^J • u U - LJ • u '• j A.-CiyS! . "5th3d J u _J J J J J J J ^J J u J J J J J _1 _j • • J J u - J J J J J. _J J ,J J J J • J J J J J J J J 1 J 1 u U - - J J J J _!• J. J u J : J U -J U j. j . j u u j j ri j j j . j j _J _j J L_J _J J LJ ' U LJ J J J LJ U u • - Comments: ------- [ -LLL.I J_LL! ! ! ! ____ _ _____ ___ j .11 • 31 .. 14 I JJ • 144-U_L-LJ_iJ _L _\| _\| 4 _LL J.. JJ \| «. f« ; .3 \| » j 45 I 4S I 47 \| 4. j 4, i iT\|v1 »T17rr>7r» \|.!.» \| S7 \| » \| 61 62 63 J JILLLJ _ 67 \| 6« I 69 \| 70 \ 71 \| 72 \| 7> \|">< SOURCE SAMPLE REQUEST & REPORT (MUST BE FILLED OUT I:OR EACH TEST RUN) •"! SAMPLING DATE j £,'• <\ j YR i V.O j DAY' FIRST IDEMT. NO. USED 00 if - 1LASTIDENT. !NO.USED s-93 TEST NO- RUN NO // ///]$ / INDUSTRY. COMPANY. ADDRESS . METHOD (USE TABLE A) \ UNIT PROCESS OPERATION.^, AIR POLLUTION CONTROL n/ \t> Q:T/ M' FUEL USED. FP fl S ( M> \ I .>rf W I 7 GIMLET -}C OUTLET GAS VOLUME SAMPLED // ^ ' ' (,VE;TZR VOL IN IDE.'iT NO S"J/ _^3->- . ^3=i DESCRIPTION OF • SAMPLE OR SAMPLE FRACTION prcbv \xA~e * \.^c\^ ^;)^,- / »or>r> &\~>} jvxp,V^er c^Ti^e^'S S-ivY\» -^fJb, ^-\| C'^^viv ' rriMMCKf?- h SAMPLING CONTRACTOR- -PROJECT OFFICER- . (IF APPLICABLE) REQUEST -REVIEWED rr DATE OF REQUEST. .DATE ANALYSIS REQUESTED . DATE OF REQUEST.. (TO EE FILLED IN BY SSFABi ------- REPORT IIP ANALYSE • TRACii -XEMEIiTS pprn - lor ;olid samples ug/m1 • lor liquid samples Mcf'i< (>i !ot sr,eci!>c C-M-I/S'* t.'.ci'K (xi in blow io lii'i of !•:•:":. '>o. -'..-en requesting cil Gr.G!',sis or, thai lire cnt Mo. ! i Kg hj "-i J L P L- J L Be J L Cd J L TC AS J L V J L 1TUUL J~LU L+J UJ L J LU L J r.j j L JLJJL I-ILUL p-E- .3 L J L J L J L J L _TL\|_rr frcprc LTTiu i_ 1 ! U L J L U L . U L 3-E ^ ITU J L J L U L J L J L ITU Mn J L J L J L J L J L J L J L J L J L Ni LJ L J L J L J L J L J L r J L J L Sb J L J~C J1 L J L J L 3 E J L JT- Cr J L J L r1 L J L J L J L J U U L J U In J L J L J L J L J L J L J L J L J L Cu J L J L r-1' L- J L J U J L J L J L J L J L Pb J L J L J L J L J L J L J U J L J L J L Se' J L J L J U J L J L J L J L J L J L J L B J L J L. J L J L J L J L J L J ;_ J 1~ . r' r J L J L J L J L J L .J L J L. lire J L nTrjii l':' } 1 Li J L J L J L J L J L J L J L J L J L Ag J L J L J L J L J L r-l L LJ L J L J L J L Sn J L U L Fe J L J L J UJ L J L J L J L J L J L J L J L J L J L _j L J L J L J LJJ L Sr J L J L r1 L \|J L J L J L J L J L J L J L No J L J L J L J L J L J L J L J L J L J L K J L J L J L J L J L J U J L J L J..L 4L Co J L J U Si J L Mg J L J LLJ L, J LU L 1 \| J L 1 1 J L J LU L _j (_ J L J L F^ J L J L J L Bo J 1 II 1 LU L J L l-r'-;' J UJ LU ! 1 LJJ U J LjJ LU LU LU LH J I \| LU LjJ LJJ L J LJJ L (J LU LU L i ! U UJ LU L ... i I j L J LU LJJ L i J L J L J LU LU LjJ L J L _J L JLH^ J .LU LU Lj J U zm J LU U ! l j LU H , J UJ LU L J LU L i i J L J U Analysis Method: 1-NAA, 2-SSt.'S, 3-Of.S, 4-AA, 5-ASV, 6-XRF, and 7-other Comments;.':'• r.ciyiis • Use loble S to fill- analysis requested (above occh column) ''. Iten! no. J ! i 1 ' ! . i •• ' 1 \| A".r.!yS! Method J J '- I-J - •' J J J u -J J J _l _J J ,_] • g j g j j _i j . j j _j _j j g g j j _j _j _j g j g j g H • •!$ i g j j j j g j g j Mar'* (xi Icr specific crvysis rer(-jes:ei j f J J J J J ' _J J UJ • J J •'i? J J J J J- J J- _l . J g J J J J J J J J J J J J J _J ! -J _j "in 1 _J -J U J U • J _J J ,_! J' J J J ' - Corr.rr.er.ts: ------- SAMPLE HANDLING LOG Task or Contract Nunher Z-^'V • • Source Identification Test Run Number Pollutant (s) in Sample Task . Sc.r-.pl ing Probe Technician Meter Technician Other Transport of Train to Cleanup C •? - '-, •~> -. UO Trai.n Disassembly Train Cleanout Packing and -Storage Shipment to .Analysis Site Lab Analysis V.'rite Up .Date / / ' •* • '• H It /» .O//>jh3 .7/,,j,3 ' 1 Time .' ••" sl- i. ~~~ . • " '' ,'J ' ' •'- 1 • .,;.••; i1..-. a-J-r /'--. :-'.' M--r.- >-..., , '....-:... ?{..,:< / ' />'.-. .- •••' ....... .. Personnel ^' Remarks . j i 1 ' ; •. jt-.J /:-.:U /• S,/,,-/:'- £fl. /;.:-,:;.,.- f r ^ j' '. ''. /''. .' • 1 • - ^. • .: • • . ' •. ^X ; / .'•' '"' "" Jf'iH / <'••'•'- 1 / /" Jf.J! It ' i ''• ''//•' ., ' "• ^JI:.',«. — KJ-"^' '1 •!'"..' ' •' '' / . ; • '.'' \i i • , / '•• 7t!£/ '-->'/•>•,• ;,; : " 7 ' C- ' - / /v %>* /^w ^ p/^ • ------- SAMPLE HANDLING LOG Task or Contract Number Source Identification Test Run Number Pollutant(s) in Sample //f.2/ J. ci S ."1 '. •',•/• '•^'•"'•ji -fZp'^ Sampling Probe Technician Meter Technician ' Other-- Transport of Train to Cleanup Site Train Disassembly • ' '. Train Cleanout : ; Packing and Storage Shipment to Analysis Site Lab Analysis VJr i te Up Date <; j;t,,, /.«."/ •- ! •' '". ' ' . • '" (,4A ^A'.--C '^."-" ------- SAMPLE HANDLING LOG Task, or Contract Number Tt.t ^r.^^/^>.2t fif&sr-f Source Identification x'">/•••..- / '.- .":.'••••• - 5/* Test Run Number _V Pollutant (s) in Sairp.le /''. .• •'...... '. /., //& Task ' Sampling .' .Probe Technician •Meter Technician ' Other '-'• ' ' • Transport. of Train to Cleanup Site* Train Disassembly Train Cleanout • Packing and Storage Shipment to Analysis Site Lab Analysis Write Up Date } • >. '• . Time .y Y^ T £? •• :. * • • ' §i ?' " ^5, " // !f • 9/-//73 ' -> : ' : .'••• :; <'' /'.' i ' ••' - i if fl r ------- SAMPLE HANDLING LOG Task -or Contract Number Source Identification Test Run Number Pollutant (s) in Sc.nole 1 n 1. _ -~"' Date 1 . i \| . Sampling ! • -Probe Technician Meter Technician ' ' Other ' Transport ..of Train to Cleanup Site Train Disassembly- Train Cleanout Packing and Storage Shipment to Analysis Site Lab Analysis Write Up . tf~/- ' '-$ ' if li I, Ir ,' f It ! ' . W/i ' • > f ' • ' '., --, •• / : 7 / ' ^ ' / . / ' ' Time . /<;? fd- A 1 ••- ^ // -- A \ • //-15- • * '* '". // / •' ' ''•'•> ! ;/%1', Personnel Remarks i ! /_•;:- Jj. ^••••// " yi [A)^~ ^',\| ' . '••-,' X i " • /- /? -• e/r.- :->£>; (:^«M'I 'w/~ '•'''• — J~^ft i L • *< " * •> ' •>',.'.. /'' ------- SAMPLE HANDLING LOG Task or Contract Number Source Identification . Test Run Number Pollutant(s) in Sample /; •/• r; s ," /v ( r Task ' Sampling •Probe Technician Keter Technician ' Other Transport .of Train to Cleanup Site Train Disassembly Train Cleanout Packing and Storage s Shipment to Analysis Site i '- . • Lab Analysis Write Up . Date Time w» •• il i! it • ' n 9/W/73 ' y/ -//?::' sii> NV X : j; -t£- /,' jl r '•- ,-'•' Personnel /.'!-.-/>. '';;•'-•'/ /•" , _ f >'•'•••'•' — //./.•••• f !''>'"• sjs<; '' "' •'"'' " ; .' i'fl ;< ~ ^ .'" ' ' ,-..-;/ - • - / t.j;,/v.:^cl( 1. ' '• " ' ' / - • ., /••• --'• ::- ; i-' Remarks i . ^^^T? '•• 'U: ^ -••...' ------- SAMPLE HANDLING LOG Task or Contract Number A Source Identification Test Run Number Pollutant(s) in Sample Task . Sampling Probe Technician Meter Technician ' Other ' • Transport of Train to Cleanup Site Train Disassembly- t Train Cleanout Packing and Storage' Shipment to Analysis Site Lab Analysis " Write Up Date 9-/-n - ": // // . #V?3 i '/'.'/ "' •• Time -; ^ /' .<--. f ' ?-• , • l> * • . / • .- ' .' .• - '• Personnel Remarks i '-''~'''J /: '"/ 1 Xf'"< ''«'""-' ir * 1 . j^,,, r»,fj- If '' if . j , !^ r\ • / / . ,).'"•/! v ; . -~r-,"-[\-.'''.i^ '" { 1 , ------- SAMPLE HANDLING LOG Task or Contract Number' Source Identification Te"st Run Number Pollutant(s) in Sample m — Q !_.. sa,,?li,g ; Probe Technician Meter Technician ' Other Transport of Train to Cleanup Site Train Disassembly Train Cleanout Packing and Storage Shipment to Analysis Site Lab Analysis Write U? . Date &../'.•-?? • II it if " /"'/•" Time i'p '^— '" - \ ' '' • '" . "" / Personnel Col- M ------- SAMPLE HANDLING LOG Task or Contract Nurrber Source Identification Test Run Number Pollutant(s) in Sample I Task" Date Tinv Personnel Remarks Sampling Probe Technician Meter Technician- " Other \ Transport of Train to Cleanup Site Train Disassembly Train Cleancut Packing and Storage- Shipment to Analysis Site • Lab Analysis 'Write UD 9-/3-7J At ' t •?// ------- SAMPLE HANDLING LOG Task or Contract Nurr.bc-jr Source Identification Test Run Number Pollutant(s) in Sample r/w Task . ' Sar/.piir.g • Pr'obe Technician Meter Technician Other Transport of Train to Cleanup Site Train Disassembly Train Cleanout Packing and Storage Shipment to. Analysis Site Lab Analysis V/rite U? Date o-a-7s ' tt ' tt » If ".. /, t///V/?3 tlp-ihi' Time -V ' jz f •// / <^s> . '. yj~ •/ i» 2fli,~ ' /:^/v.i_ - Personnel ^W- ftJi<,y ff,/,«f-^ £rf,- S-'b >-!) . /,/'.. i . . ,. Remarks • i • • „,':../• • ' '.' -' '< . % •••<> •: t s^s '.-•• .>. ( •' . .-.•' ' ------- SAMPLE HANDLING LOG Task or Contract Number Source Identification Test Run Number Pollutant(s) in.Sample- -T~. L S f'. •5 1 3'^ 1 : - " . it v;" . • Personnel _ ;•;• '\ j '. .< lf'f-.\ £ ..fj«'- U #.,« r» •«'<-- ,. JG/.H sv S-f<''~ .' / • ' f / 'l^O-'-y^O.^. }•"/,»/ /•'' tli i '•/" * "A \ f- * (i 1 (t I < * « ** f'-'J f I 1 '• i ' * ,' } ( '.f /~\ / • ^ ~j ' " \| ' ' ------- SAMPLE HANDLING LOG Task or Contract Nuirber 77"-rA Source Identification Test Run Number Pollutant(s) in Sample /"* / r> '/->/.• x- //-/'.••"••y ..-.>" j-f'f /i\s,( /•':;•• L. t ?••>•,, •.•./,.!'•:, ' Task ' ',- Sc.~pling Probe Technician Meter Technician % ' Other ' ' Transport of Train to Cleanup 1 Site Train Disassembly. 1 • Train Cleanout Packing and Storage, Shipment to Analysis Site • Lab Analysis 'Write Up Date Time i • W-v it „ ' if • •i * tf . Q}l	cC // if Jon if /'<••' l'J' "• is it // , 1 > X1 {.au:if., A...—,. R9iT:Cirks ( • ••c /" /• f "-','' 1 •..''' '-•''• «v i .1 ' ------- C j i o -) I / • CT 8- , s f o ^ en CM cc. n* 5-0- r-PT'.--^ M/\iL—30..- (plus postrr-J Li.-Ll±ll-—-1_-^-—" • T—^rT;" • -- 1 j--;lSr7«'n sit^fleColumbus Lab \| 505_Xin-c- Ayeriuja 'tCSIPT . ,„" 2. Shows to !«:".'•;'• 1 ~Jf V - '—" «; "-> •JvJ r> >is >i? 3 529 1) £} 3} T'^^r- > --fc » ^ •? T^^-V* "> ••:-•-- ^f-^ /? -T < 5--^-v %,-»•--•- • •«.---. * '4.O v'".- •-> >-W^» X ju.ij- O^i- .'-^ - -. : - \ V tl tA. ;.. i.> j. ,^V. x-A.t., .t i 4 / r^".'' '.-'•"• ' ^ cj^Or- ^-.^: .^, p"^?'i>^- ™ -o • .l-'«-~- i'-ft V* J^ 4.. ,-_<, V>^-*Vfi V J- -» . i- J..V.-.V -^irW ^j-/».•»»?---^ .-ny^^r* ,':rt r;';" ^">«?s? C5"r p^l^^-tlTD'"? «-.*;~sr^n" •'T * c- i- -i»- -^- .^ « — I -. • -at .'* •«/».£ •.' -1. • .. 1-.. \3 +? \lf ^1» 'i ; .," f-J" -^^> '4« «rf -ij ^ - •.' C;' ' — 'fi V* -.« P-";-'>-f'i ••;• •---"•; f» 1 "-•'.-•• •;•••!» •»• rrv" •? — -•»»• o rr ••.•"•-- "> --:j'";:5 f~ --•- —la w> - - -» v ^c E' -* \ »—rf- -v. ^ -* ,»i •. ~ v ' r-» r> ' ' ^ ^ ^ ^' :~* * !"t. »S-^T. ^? - "!/ \ ;-. .- ..-.i^.-.Cs C-: ,• i-,.-'- -.-••oo/, ..,.-..-J5 ivJit* •.-,:.;•»>x » Ti5n 'ir 11 t'r^ciii"•£; i"l-3.'Cii"Cii;io"-i of ^'i .'"• ii_c"r)t: (I/-'/) C7i a tsrcC r::^xbrci:ii; ,-;:.:-J -;oi•--'•-.it:"-; th2 clriGd r^rticuia:"; rr^atEcr cnu^ht n;^ .v-r.-v K:l A %'f *•; - ' 70 .-. -. •/ '""-.-> > -. S'-^-1 ^.^ .,• ,' --',,-.?,-•: ^ .'I* .- . * •_>•-.< / ..'*. -- -^ ' ' 4 ..-... ;. .. .„..".*}. CZ ^- , _^^^.-.V-» G-i;^pic:ij '.-507s v5I69 T?3£oP ^ticl v3G':> should'b: rsrt^rnL/d. C. liTl . Yoin: ucru-ti If you cr: ov- --/ill ba a&7?"C'C Sincerey ycstsrs, it ^ ^ -u f > ------- January 4, 1974 Dr. Richard J. Thompson Chief, Analytical Laboratory Branch Quality Assurance and Environmental. . . Monitoring Laboratory U.S. Environmental Protection Agency Research Triangle Park, North Carolina 27711 * Dear Dr. Thompson: • • . Analyses for ashestos content of Samples 507, 503, 509, 516, 517, 528 sr.d 529 , - j u. uo October 29, 1973. The analytical procedure and analytical results are presented in Appendix A. • . ' • • If you have any questions please call me at Extension 3397 or Carl Melton at Extension 2781. Very truly yours, . : R. E. Heffelfinger Associate Manager Analytical Chemistry Section REH:uha Enc. ------- APPENDIX A ; ANALYTICAL PROCEDURE Liquid Samples An aliquot from-each of the liquid samples numbered 597, 509, 516 and 528 was filtered on a tared membrane filter and the collected parti- culate matter was dried and weighed at 50% RH and 72C. Carbon was vapor deposited over the surface of the filter, the filter was dissolved away in acetone and the carbon film was placed in the 'transmission electron microscope where fiber counts and measurements of fiber lengths and widths were"made at 12COG x magnificat:ion over kncwa areas as defined by 200 mesh, openings in an electron microscope support grid1. Also in the electron microscope identi- fication of asbestos species was established by selected area electron diffractiur and fiber morphology. Only those particles having an aspect ratio of 3:1 or greater were defined as -fibers. The volume of each fiber was computed by multiplying the width squared times the length. The mass of asbestos species was obtained by multiplying its total volume in the sample times the density of'the asbestos species (density.of araphibole =3.4 and that, of chrycotile = 2.56). Then the weight percent of asbestos present in the sample was calculated by dividing the mass of the asbestos by the weight of the dried particulatc. Fiber length distribution is presented in graphical form which expresses cumulative percent by number vis. the average fiber lengths assigned to si::e classes. The point at whir1-, c'ae curve intersects 507. on ------- T on the graph indicator the mean particle length with respect to fiber popu- lation in the sample. Filter Samples Filter samples 503, 517 and 529 had been weighed by EPA and the weight was given on the sample envelope; consequently, no weighings of the collected particulate were made in this laboratory. Rather, to obtain an aliquo! of the sample for analysis, asmeasuxedirxadial section was taken from each filter sample. The aliquot was low-temperature asked and redeposited on a 25 mm membrane filter where it was coated with vapor deposited carbon. As in the case of the'water samples, the filter was dissolved away and the carbon film bearing the particulate was examined in the transmission electron microscope. Asbestos species were then identified, and.length- and width measurements were made for the purpose of expressing resx^V^^^yS'^iiai-^inglA'distribution and mass of asbestos present in each sample. ' . . ' Results of Analyses Analytical results are presented in Table I and Figures 1 through 8. Table I lists samples and mass of asbestos in each sample. The figures are plots of cumulative percent by number, vs. fiber length in Jim. ------- . TABLE I. ASBESTOS MASS DATA Weight of Dry Mass of Asbestos, ug "/, Asbestos in Ssr.ole Sample Description Sample Particulate Chrysotile Amphibole • Chrysotiie Amptnuole S-73-004-507 (Run No. 1-C) , f S-73-004-508 (1000005A, Run 3) S-73-004-509 ' , (Bubbler No. I, Test F6-3) S-73-004-509 (Bubbler Ko. 2, Run No. 1-C) S-73-004-516 .'- (Probe Wash P-3) S -73-004-517 -.':. . (1000003A, Run 6) .- S-73-004-528 • (Probe Wash P-7) . S-73-004-529 /•innnni9A Pi,n in} 0.0117 g ' 0 775. 0 6.6 7. " • " * 0.0150 g -0 875. 0- 5.8 7. 0.00122 .g . . ',.'• 0.17 ' 0.4 . . 0.013 .0.033. . 0.000562 g \5 • .. 0.14 1.5 0.025 0.27 0.2690 g ' 2.3 470, 0.0009 ' 0.2" 1 0.0253 g * 0 175. 0 ' 0.7 ' 0.0704 g 0 212. 0 0.33 0.0107 g' 0 71. 0 ; 0.7 ------- 09.0'.' [""JT' ijii • !: ! : ! ! • : ! l ! ! ! I i I ! V ! ' i ! ! : i I . V : . • :;;; : j ; _UJ--LU ' i i .;!.!!' ilii P9.0 III 1TH •H-T :\|: 99 98 95 90 QJ 53 e° 70 4J C o co J-l o> PH 50 0.4 0.& 0.0 0.0 I 334 Particle Length, Micrometers 6 7 0 ------- 09.'. ! I ! I ITt lli -U. ) t U4- 44- 99 Irrl "••H!" I 111! Tin 71V Jjfl 00 70 Q) o GO - -1-4 t::!:: "T" 50 ii rjrrirrt-:— i:n::~ :-:::.:::::::\| ..,.. •H 55! 20 10 '. I ; "i" zrqzn: i—!—»-(- m.lnn --4—^-.,- --i-t-t- ijisiir; 2' I 0.5 0.2 O.I 0.05 1 111! \\l' nr -4 i-f -1-iTr •rn I I I i -i-j-i-r- III ,4~t J-i- ii!. "Ul1' j !J"i nti "IT: i ! I Tin I) it j. i i I JC'.OI D.2 0.5 0.4 0. 5 0.6 0.0 I 2 3 « & 6 7 0 9 10 Particle Length, Micrometers FIGURE 2. 'Sample S-73-004-508, 1000005A, Run 3 Asbestos Type: Amphibole ------- I ! ! 1—r UJ-L 11 Jl t-; M i 99.9 ,„.. -! ! —i- .99 96 95 .90 00 70 60 50 d 50 •g C_> 20 10 i M ! ! "T TL! IT I i ! !.i.'z""i .Ttnrn T Ti i i t i lj~'" ' i -i_.H4 /t: IM p 0) J3 t^ rQ 4J c 0) o >-( 0) ^\|J^"\| ^HTZ -\|/u;::t.: -y--- -ft-Hi-ii: life :/: H- -H-:-:- ~-rj;1:::i.::::£ Z I 0.5 0.2 O.I 0.05 "TITT -id- T i ' J-4- rr i I M •rH II i i n - T ~pr: i ; • i I i Hi 0.4 0.5 O.G 0.0 I 254 Particle Length, Micrometers 6 7 0 9 10 FIGURE 3a. Sample S-73-004-509, Bubbler No. 1, Test FC-3 Asbextos Type: Amphibole ------- 09.99 99.9 Mil! J-l- TT i -t"l~. I im _p -H—r 70 8 CO to 60 0) •H 10 4J CtJ t-H '.ri i""" O on 10 .niij;::: E —1_ TT 1' ~z:!;un;~ UJl Illl 0.5 0.2 O.I 0.05 JO.OI 'lit ntt tin T "T TCI 1 I 11 till till. i ! fflj ! li TiTi :j± 11 O.E O.J 0.4 O.'j 0.& 0.0 I E 3 4 Particle Length, Micrometers c 7 o ------- "T 09.09 99/J .! J..JJ. MM' -IJJ. I ! U4 it rtii lul > ! l J !..- .99 1 1' M Q) 1 55 t^ .0 4J Till -H- J...L l -H-i- ;:^i 70 o rA o co 00 :::p:: \|tr 4J Jf) 20 10 -4-M-i- "" ~~; ;~' rii"""^"". ;..—'....zn. .i-.l T".._r. l-!ii T rn-r ^ii tr lit IT •Hi 0.2 O.I 0.05 Fff rm- HI; -l-i-H ill J_ i i! tifij 0.5 0.4 0.1) 0.6 O.U I 2 5 4 rj 0 7 0 9 10 Particle Length, Micrometers FIGURE 4a." Sample S-73-004-509, Bubbler No. 2, Run No. 1-C • 'Asbestos Type: Amphibole ------- ".n r.r. / V •!' / 09.0 •JU ......... 1 •• nil MM Trlr nr LU-i- U-JJ- i i n 1 ~t~' 90 95 ft IP 4-1 4 r r in: :i ..r_ r ;-\|- Mi }::::i::::\|:: m 00 ,0 70 g 0 umulati ro ------- 09,99 99.9 Mil!; :;±; I[ I....I :-t±: T1:' • 99 in-' 90 80 70 60. 50 .4-;..:_ 4J -H- 1 20 10 0.2 0.05 I IT rn JUi •flff . ..'. ;.... rjtt ::::;:::: -t- -1-,-if I'M O.OI 111 TIT -rr r 0.2 0.} 0.4 0.5 0.6 0.0 I 'i. i 4 Particle Length, Micrometers 6 7 0 9 10 FIGURE 5a. Sample S-73-004-516, Probe Wash P-3 Asbestos Type : Amphibole ------- ii9.D9r. JO.OI 0.0 I 23 Particle Length, Micrometers FIGURE 5b. Sample S-73-004-516, Probe Wash P-3 Asbestos Type: Chrysotile 20 ------- 09.90 99.9 ~t^y +rrtf^rt, I i j i ; I:, U •"' :3::;;^:;_. I I'M 11 ! 'I i 90 I J 4 -hi J_ T t~ -4-rH- 1 ill! .;.) j.^-L -JJJ-f 90 co 70 CO 50 "0 T,.t:r.: 4-1 4J BtilS: •i-t- -ti •K- i—^—i_ -in: 10 rr • IT iff! 1 httt: m 0.0 0.2 O.I 0.05 .11 -flr I i : I flli 'ift rh- rr; rr-!-r if! 'Mi JO.OI TT ' ' . ^ .!. . ....t ...!!.. i o.e o.s 0.4 o.o O.G o.o i 2 3 i o 6 i o 9 10 Particle Length, Micrometers FIGURE 6. S-73-004-517, 1000008A, Run 6 Asbestos Type: Amphibole. ------- ^liiiigzpifjqziif -•1 im ii\|3i "T Hii •• •- r~^ er O «>«>«?«> O O en (' -TK EiE; ijrdprrr m: ±tti : — j e HJ-f- •& O •r-l +J cd 50 •3 r\| 20 — O SS ::(=!: ttlt^l .iPiz s; ;-p: at Hi! • U> P to P — o O '.I 0.01 "I" • \| Trf: H LiHtKH rn I l f ill1 -4—T-^j- J—i—. rf n: rh i -TTT iT!" TlT' :l::::i:: ihi •!• :; ,'i.l,= iU : : V...1...1. :ti: bttt J.:. 0.2 0.3 0.4 0.0 O.G 0.0 I 2 3 4 & C '/ 0 » 10 Particle Length, Micrometers FIGURE 7. S-73-004-528, Probe Wash.P-7 Asbestos Type: Amphibolc 20 ------- 09.09 99.9 Tli -jli •l-l rr;T ^ •i i! i! -i~r II! . 1 4- 99 96 '-H-F4- IT .)....,....,.. 3E • "11 ll ! i i ~ 90 80 TO 60 SO 1 S PJL fl i±iit± %iiTn:nliT .Tllai ->-— j-. •'• -i....:—1._ P^- (I) 4J 1-1 30 I 0 20 10 :±W -i -t- ^trifc ; , j ' ] :_i± v"i~-\|';''i • — j :g :::±::~':T pi!= "E 2 I 0.5 0.2 O.I 0.05 S •:z!:; ,:::!..:. -t1 •• if =m ! T _U1 Jjj _i__i_.—1 »«.* UDlU!; ill ES itii !-'[^^^~i '—1"-'"X-i-"- I I -i-l- I ~" - i ! i 1 :\|:-?i.:_: ; mi -rr O.i 0.4 0.5 0.6 0.0 I 234 Particle Length, Micrometers FIGURE 8. S-73-004-529, 1000012A, Run 10 Asbestos Type: Aniphibole 6 7 0 9 10 ------- C'olunibii-. (.'Inn •' 1J01 Tek'pnoTio •''H- J'>'MT>1 March 13, 1974 T,-U.X.M-:,IV: Dr. Frank P. Scaringelli Environmental Sample Analysis Section Analytical Chemistry Branch Environmental Protection Agency Research Triangle Park, North Carolina 27711 Dear Dr. Scaringelli: This letter is in response to your request for clarification of data reported in the letter report to Dr. Thompson dated January 4, 1974. The report concerns samples 507, 508, 509, 516, 5175 528, and 529, which are described in Dr. Thompson's letter dated October 29, 1973. It is my understanding that you want to know (1) the original .volume of each liquid sample received (2) the calculations .employed to obtain reported values including aliquots taker.,, etc. and (3) an explanation of the cumulative size-frequency curves shown in Figures i chrougn 8. . The original volume of each liquid sample was measured and recorded and are given in Table 1; Subsequently, all samples as received were placed on rollers for one hour to disperse the particulate uniformly before removing an aliquot. Then an aliquot was removed, diluted with water, and 0.1% aerosol OT was added to promote the dispersion of particulate. The diluted aliquots in plastic bottles were rolled for three hours, and several aliquots from each sample were deposited on 25 mm Millipore HAWP (0.45 y, pore size) filters to be able to select a suitable concentration of particulate for counting and measuring asbestos fibers in the electron microscope. The filters bearing the deposited particulate were coated with a carbon film by vapor deposition, a piece was cut from each carbon-coated filter, and the filter was dissolved away to leave the particulate supported by the carbon film which was then placed in the transmission electron microscope where measurements and counts of amphibole and chrysotile asbestos fibers were made at 12000X ove.r areas delineated by 200-mesh electron microscope suppor t grid openings. The ratio of the area of the filter over which particulate was deposited to the area of the grid openings over which the measurements of fiber lengths and widths were made is the factor used to compute the total population and mass of asbestos in the aliquot deposited on the 25 mm filter. In each case the diameter of the deposit on the filter was 17.6 millimeters (8.8 mm or 8800 u radius) and the area of one grid 'opening was 90 x 90 u = 8100 ^m ------- Dr. Frank P. Scaringelli 2 March 13, 1974 Therefore, the calculation of the factor became TT (8800 u)2 8100 u2 x no. of grid openings; • •. • •-..-. •. • • 4 . .• ' ...-.••..• for one grid opening the factor is 3.0 x 10 which we have named grid area factor/filter. Further calculations to obtain the concentration of fibers in the original sample from the aliquots taken in the case of the liquid samples are exemplified by the following case (Sample 507); Step 1 - 30 ml were removed from original sample and • diluted to 200 ml Step 2 - A 5 ml aliquot x^as removed from the 200 ml diluted sample then diluted further with filtereddeionized water and the entire quantity of particulate contained in this 5 ml aliquot was deposited on the 25 mm filter to create the dispersion from which fiber counts were made. That volume of the original sample deposited over the effective filtering area was therefore: . 5 ml/filter/200 ml x 15 ml = 0.375 ml/filter. Consequently, -..'her. SO air.phibolc fibers were found over the area of 2 grid openings the calculation of tne numoer of "tibev ?>-per miiiiiiter or original sample is . 3 x 10 grid area factor/filter 80 fibers 0.375 ml/filter X 3 grid areas = 2.13 x 10 fibers/ml. Since the original volume of the sample was measured to be 108 ml, the number of fibers in the total sample is 108 ml sample x 2.13 x 106 fibers/ml = 2.31 x 108 fibers/sample. Length and width measurements to 0.1 y, were made on individual fibers and the volume of each fiber was computed by multiplying the length times the width squared. The volumes of all fibers measured within a sample were totaled, multiplied by the density (3.4 for amphiboles and 2.56 for chrysotile) to obtain the mass. Then the value obtained for r.he mass of fibers measured was multiplied by the aliquot factors to get the total mass of asbestos per ml of sample, and. in turn multiplied by the original sample volume to get the mass of asbestos in the sample. One cubic micron multiplied times the density yields results in picograms.which was more conveniently converted to micrograms for reporting. On this basis the 80 fibers measured in Sample 507 were computed to have a mass of 269 p.g.. Therefore the total mass of ------- Dr. Frank P. Scaringelli ' 3 ' March 13, 1974 4 i- • v i j _L i no i c _L. • • i 3 x 10 erid area factor •amphibole In the 108 ml of this sample were . —°-r-. x . v 3 grid area 108 ml/sample nrr. -, -,, •, rt8 „ / , -,-,f , . - —r-1 x 269 p.g. = 7.76 x 10 P g/sample = 776 ug/sample. Since it was found impractical to weigh accurately the small quantities of particulate filtered for electron microscopy, larger aliquots (approximately . 1/4 of the total sample volume) was deposited on tared filters and weighed. Then the particulate loading for each sample was calculated in ug/ml. This . figure was used to compute percent asbestos in the dry particulate. In the case of the filter samples submitted by EPA, the weights of collected particulate were obtained by EPA and were recorde'd on the sample envelopes. On the assumption that a radial section cut from the filter would provide a representative aliquot, a 45 radial section was cut from each filter. Because the filters contained nylon webbing support which is resistant to low-temperature ashing it was necessary to separate the deposit from the nylon webbing. This was done by placing the 45 filter section in a test tube where it was washed with acetone to dissolve the filter substrate and also to wash the overlying deposited particulate from the nylon support. The acetone was allowed to evaporate in a laminar flow clean hood and the test tubes containing the dried residue were placed in the low-temperature asher for 72 hours. Then the resulting ash residue was suspended, in 500 ml of filtered deionized water to which 0.17, Aerosol OT was added to promote the dispersion /?.• 1 „ «- .^ . ~ A. I. r. . 1 . — — 11 J f-~~. / t - _ _ .1 • 1 - ,..'. V • or paTtiCMlcttc C.G tr.c ccir-pic "rcic r^-1-.^o .v± -<• liuuiTa WHJ..LC UWULCIXIICU i.u a 1000 ml Nalgene plastic bottle. Afterwards aliquots were taken from the 500 ml suspension and filtered to deposit several different densities of particulate over. 25 irsn HAUP Millipore filters in order to be able to select an appropriate concentration for counting and measuring in the electron microscope. The fiber counts and measurements were made in the same manner as for the liquid samples; the calculation based on the ratio of effective filter area to area of the 200-mesh grid openings over which measurements were made is the same. Since 45 or 1/8 of the .filter was taken and the particulate dispersed in 500 ml of water from which aliquots were taken, this aliquot factor is 500 ml - . . . volume filtered The data required to make the discussed calculations are presented in Table 1. The size-frequency curves shown in Figure 1 through 7 in the January 4, 1974 report: were generated by assigning length measurements to size classes, calculating the percentage of the total number of fibers represented by each .size class and plotting the average length within a size class versus the cumulative percent by number to 'obtain a 'length distribution. Included in this report are clearer Xerox copies of the plots than were .supplied in the January 4, 1974 report. ------- Dr. Frank P. Scaringelli 4 • March 13, 1974 If you have need for further data please contact me at Extension 2781 or R. E. lleffelfinger at Extension 3397. Very truly yours , Carl W. Melton Staff Chemist Analytical and Physical Chemistry Section : aha Enc. ------- TABLE I. DATA A)ID CALCULATED RESULTS S«-ple No. S73-W-507 S73-OOi-503 S73-0'>;-503 (iiibbltr No. I) S73-'W-509 (r..jVjUr No. 2) S7J-004-S16 S73-CO'.-517 S73-00;-52e S73-C04-523' 573-00^-529 Ai Received Sample Vol. {nl) 108 nl ' - 179 ot 148 224 - . 241 «l, . - AHnuots Orlgln.il Sjrcplc Vol. Taken (or Filter Section) IS 'ml 45° Section 25 ml 25 nl 25 nl 45 Section 25 ml 10 ml 45° Section Diluted to 200 nl 1000 ml 100 nl 200 ml 600 nl 1000 nl 600 ml 400 ml 1000 ml Filtered Volume 5 ml 20 ml 70 nl 14S ml 2 nl 20 ml 2 ml ' 4 ml 20 nl Weight Of 1'articulate. in Orig. Sump; 11 100 ug/ml 0.0150 g/ftlt.r 6.86 eg/ml 3.8 kg/ml 1202 Hg/ml . 0.0253 g/fllttr 292 ug/ml 292 ug/ml 0.0107 g/fllUr Fibers Measured Ch Am 0 0 15 17 14 0 0 0 0 80/3 Grid Openings 101/2 Grid Opcnlnp.3 51/6 Grid Openings 57/5 Grid Openings * 28/8 Grid Openings 57/4 Grid Openings 14/6 Grid Openings 11/8 Grid Openings 18/7 Grid Openings Miss of Measured Fltier* Ch' An Pg 0 0 0.33 Pg 0.31 Pg 0.23 Pg 0 0 0 0 269 Pg 146 Pg 7.2 Pg 33.9 Pg 47.1 Pg 58.2 Pg 14.0 Pg 26.1 Pg 41.6 Pg No. of FlherWS.T.ple Ch Aa 0 0 7.7 x 10J 7.8 x 10S 1.4 x 108 0 0 0 0 2.3 x 108 6.1 x '10* 2.6 x 106 2.6 x 106 _ — - 2.8 x 108 1.71 x 108 2.0 x 108 1.0 x 108 3.1 x 10* f.v «/S,v.-le Ch 0.* 0 0.17 I.. 0.14 p.- 2.3 us 0 0 0 0 A3 775 ug • 875 wg O.J ug l.S ug 471 Mg ITS ug 201 ug 234 ug 71 ug * D-.pltcotc deterolnatlons. • Ch- C-.rysotllo ------- APPENDIX D Test Log ------- SAMPLING TASK LOG Plant A •/.•,-<' Plant Location Date -Hi i/7S . Comments $J'^r t' — , "i ••/ ;.:i,tf •/',£,•?,<"#• •j ' • l; 1 .' •'• i " - • - / /Jj--".[-i! y- ••'•'.:•.'.•••,'•• •?,/• '-•.•.(_ rM//.j/'c.iJ ? J • " r /! . ^' ' ^ J,,/i /,, ,;.,...,.. ".,,. .^ /...:,(<,/.,„. .. ./, . • - ,./:/>,v,// ,^,^.4;,;. ^ < /. / ' " • * Run 1 7' £ ;?_ ".' ^ 3 Recorded Sampling location (Port) /,--vu 2-7 " >l ' 1 (.', -^ //'—/ ^ •/" y f / ,_,,,;- 5 >o--/< -.•':.'/ ^7-C- />'i-f > ',;.''/,./ 7 ' by LO , Pollutant r-/- (/>.-" - .. ,. i. .. •. •/ l6-:"'Pi. '" Vi Clock Beqan f '- ic°-'r I a2-7 /-' n ° V j ------- Plant Date SAMPLING TASK LOG Plant Location Recorded by Q -Q rj />•<"/• ' -L \5 tft 'Comments Sampling location Run (Port) Clock Time Elapsed Sample Pollutant Began Ended Time (min) Nos. i 1 /• / ,' ' •' f' '/ ,;«.:t >f.'.i ,-;.>.-/ y. A-/,.-.-/5 /v' ' y v • /' • < O /A ;>'. .' '• , -.' :,','.-• (J ' \' A ::-r.&'v/ J ">; r /' •.•'•- -,/>-• .- V ,v . x ^ . v «. ";",( • , ' . ' ' ',' • ' ' ' ; ^ //-,../ ' ?hc-£ O.tf. •&,-/•< -:^.,,Jl:. ,/./,'/-/, A A'. ' ' U /nu/^^./ ^A.-V.-^ '/.S'V.'.-d A ' A ,- ' '/: • (_/>TVI r K/ /"/ v ••"> :•-• •• '-t. .' i- ^ no. / 1 v. • >!/ y / •, .,, v--- ,; '< ,.'{ .•• • - v7 ..'.• v>. .. \ t- r. . ; , K • V V 5 5 6 . C £ 6 "/' 7 ^ /-6 ' ^- 7 - / ?- ,-••'• /-£ / / • ^j /-6 ^.•f' '/-/? ' o/-/'2. ,.-/-- /-c- '/,/l 7_/? t7;/v •. -?YlAiA 'in^-' i ' „ ,., .. •• ;. ; t '.a •"'•' /.i? A:' /^' //-D/ ^ "r 3® J/a '/•3--' j/^ i/ " V- 4 ^ A7^- . /:, :-> /^^ II- -. ^S ii ^ .:/ '£/• -'/ ^ J./-& 6^ oy 7 " i / 7 3 !? >$ • 1? 12- — 7 ft IP . ' / -lib -'/-Si 2. V^/.>-f;-/5 '/5/6--X5'/ ------- SAMPLING TASK LOG Plant Kv;r--.'< •')]'.' •,;;•/•(' Date oA-:-'/ j.-'"' ,?/ /AvX ••'.•/' ,>''-/ .^ '/•'' • r /r /-• 'V i;/i"/ (" r ' ^ •' y ' -" V / •, ' ,.')•••• .' <- ' , . ' • — f ; l'.- r;. '.' iU ,.,.„',.: .;'••. .v. •'.> ->•.•:•. i'., V • >)!.fj< /.- r.-rfV '.^--. ••'"'.'i''. > •t'C^ /.yv • /) /••' . \>£'-i •;''<• i i^..&. ' ', : '>..-.'.. J-' j t'.\vv.-.j /v-/ . 7'/l:i^. by /, j, /K/^.y ' ' - • Clock Tine Elapsed Sample Pollutant Began Ended Time (min) Nos. . 7/^,00 r ,.. ii «, /• ,: i 1 II 1. , • 1 !^ u /t •'- /^ •"' /./ -' //'• /;-- It'8 n'11 '/ ~^. \ 0 3 ~~~~ ^ 5- # 5 -:' ^^ ^ •" }7 /£? - //C' II- /! -' // :- ' /,-' •' ' /25' 0'° :?•-• o 5 //9 /.- %J (o ** : j~ " 7 ^' /(;? / ------- .APPENDIX E Project Participants Winton E. Kelly --Environmental Protection Agency, .QAQPS., ESEDj EMB, Project Officer Edward Vincent -.Environmental Protection Agency, OAQPS, ESED, ISB Project Engineer Earl Schulz - Battelle-Columbus, Test Team Leader Bob Poling - Battelle-Columbus, Sampling Technician Ben Furnace - Battelle-Columbus, Sampling Technician John Faught - Battelle-Columbus, Sample Cleanup Technician -------


                                74-HAS-l
                               (REPORT NUMBER)
AIR  POLLUTION  EMISSION  TEST
                        RESERVE MINING COMPANY
                             (PLANT NAME;
                        Silver Bay,  Minnesota
                           (PLANT ADDRESS)
           U. S. ENVIRONMENTAL PROTECTION AGENCY
                 Office of Air and Water Programs
            Office of Air Quality Planning and Standards
            Emission Standards and Engineering Division
                  Emission Measurement Branch
               Research Triangle Park, N. C.  27711

-------
           Emission Testing Report

           EMB Report No.  74-HAS-l
 RESERVE   MINING   COMPANY

            Silver Bay, Minnesota.
       Environmental  Protection Agency
 Office of Air Quality Planning and Standards
Research Triangle Park, North Carolina  27711

                 June  1974

-------
                       INTRODUCTION


                                                           Page Number(s)

  I.  INTRODUCTION	    1-3

      Figure. 1 - Sampling Locations ..  .„ .........   .  3

 II.  SUMMARY AND DISCUSSION OF.RESULTS  	    4-24

      Tables 1-18 - Participate Summary in English and
                    Metric Units                              7-24

III.  SUMMARY AND DISCUSSION OF PROCESS SAMPLE ANALYSIS   .    25

 IV.  PROCESS DESCRIPTION  	    26-28

  V.  PROCESS OPERATION DURING TEST	    29-32

 VI.  LOCATION OF SAMPLING POINTS  	    33-34

VII.  SAMPLING AND ANALYTICAL PROCEDURES '. .  •	    35-36



APPENDICES

      APPENDIX A - Sample Calculations

      APPENDIX B - Field Data

      APPENDIX C - Laboratory Report.

      APPENDIX D - Test Log

      APPENDIX E - Project Participants

-------
                         INTRODUCTION

     This report describes an emission and process sampling program
conducted at the Reserve Mining Company taconite processing facilities
located in Silver Bay, Minnesota, during the week of September 10, 1973.
The plant processes taconite: ore and produces pellets which are ideally
suited for blast furnace feed.  Approximately 85,000 tons per day of ore
are received in railroad cars from the mine at Babbitt, Minnesota where
it has been crushed to minus 4-inch size.   The processing facility re-
duces the ore to minus 3/4-inch size by ten sets of cone crushers.  The
crushed ore is then delivered by belt to the Concentrator Building where
it is ground and separated by 22 parallel  units.  Each unit consists of
the following items operated in series: "a rod mill, a rougher magnetic
separator, a ball mill, a cleaner magnetic separator, a regrind ball mill,
a finisher magnetic separator, and a disc  filter.  The filter cake is mixed
with a small amount of bentonite clay and  delivered to 36 large rotating
drums which roll it into balls of about 1/2" diameter.  The balls are then
fed into 8 traveling grate pelletizing machines where they are first dried,
then heated to over 2200°F, then passed through an oxidizing section, then
a cooling section.  This transforms them into hard pellets.

     Four emission points were sampled for particulate matters-exhaust
stack No.  110 on the west No. 104 fine crusher, waste gas stack on
pelletizer No. 5, hood vent stack on pelletizer No. 5, east concentrator
stack No.  118,  These locations are shown  in Figure 1.  In addition,
process samples .were obtained at the outlet of the crusher, and from the
conveyor belts which feed the pelletizer.   The primary purpose of the test
was to identify and quantify possible asbestos emissions.

-------
     Samples obtained were subjected to a series of analytical  techniques
designed to identify chemical composition and physical form.  Specific
emphasis was placed upon the identification and characterization of
asbestos minerals.  Techniques employed include X-ray diffraction,
light microscope, 'and electron microscope".procedures.       ' .            •

     Emission samples were obtained by a Battelle (Columbus Laboratories)
test team under contract and directed by EPA.  Emission samples were
analyzed by Battelle and by McCrone Associates.  Process samples were
analyzed by Battelle.

     Prior stack tests to determine particulate matter emission rates
have been conducted by the Company and by the State of Minnesota.

     Reserve Mining results of particulate matter stack tests run
on #6 pelletizer waste gas hood and exhaust stacks during February and
March 1973, average 0.19 and 0.068 grains/scf for waste gas and hood
exhaust, respectively.  Company calculations give a dust load of 194.5 Ibs/hr
from #6 waste gas stack when its concentration was 0.215 grains/scf.  The
State of Minnesota made tests on the waste gas stacks of #5 and #6
pelletizer furnaces.  At 135 wet tons/hr ball feed, the results were
0.52 and 0.61 grains/scf, respectively.

-------
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                            Figure 1:  Sampling Locations, Reserve Mining Company, Silver Bay, Minnesota

-------
               SUMMARY AND DISCUSSION OF RESULTS

     Under Environmental Protection Agency direction, Battelle
personnel collected a total of" eleven participate samples from four
process emission locations at the Reserve Mining facility.  Three
samples were collected downstream of the control device serving one
of the ten fine crusher lines; four samples were collected from the
waste gas stack serving pelletizer No.  5; three samples were collected
from the hood vent stack serving pelletizer No. 5; and one sample was
collected after the control device serving one of the concentrator-
storage bin systems.

     The collected samples were then transported to EPA laboratories in
Durham, North Carolina where the filter fractions were weighed.  The
samples froin Run Nos. 1 (fine crusher), 6 (waste gas), and 10 (hood vent)
were then sent to BatteTle Columbus Laboratories for total particulate
and asbestos analysis.  The results of these analysis are covered in
this report.

     The samples from Run Nos. 2 (fine crusher), 5 (waste gas),
9 (hood vent), and 11 (concentrator) were sent to McCrone Associates,
for asbestos analysis, and the results will be reported separately by
the Office of Technical Analysis, EPA.   The remaining samples have been
stored for possible future analysis.

     The sampling data for each of the eleven runs is summarized in
Tables A-l to A-10 in Appendix A.  These summaries include sampling
parameters and stack flow rate data.

-------
     The results of testing for the three runs that were analyzed
                         *

by Battelle are summarized in Tables 1-18.  The total particulate


emissions found are given in Tables 1-3.  The total asbestos emissions


are given in Tables 4-6, and the amphibole emissions are given in


Tables 7-9.  Tables 10-18 are duplications in English units of the


information presented in Tables 1-9.



     The total particulate concentration found in the fine crusher

                      3                                  3
exhaust was 11.3 mg/NM *.  At a stack flow rate of 471 NM /min, the


particulate mass flow rate was 0.32 kg/hr.  Total asbestos accounted


for 5.8 percent of the total mass in the sample, with essentially all


of the asbestos being of the amphibole form.   Only 0.02 percent of the


asbestos was of the chrysotile form.  The asbestos concentration

                                        o
and rate in the emissions was 0.65 mg/NM  and 0.02 kg/hr.



     At the waste gas stack, the total particulate concentration was

          3           3
355 mg/DNM  at 3270 NM /min flow, resulting in a particulate mass rate


of 69.7 kg/hr.  The asbestos weight was 0.2 percent of the total sample,


with essentially all of the asbestos being amphibole.  Chrysotile accounted


for only 0.36 percent of the total asbestos.   The asbestos emissions

                                     3
were at a concentration of 0.81 mg/NM  resulting in an emission rate of


0.16 kg/hr.
*mg/NM  - Milligram/normal cubic meter, 21.1°C, 760 mmHg, dry

-------
     At the hood vent location, the total participate  concentration was
127.7 mg/NM3 at a flow ra'te of 2700 NM3/min.  This  results  in  a  mass
flow rate of 20.7 kg/hr.  The weight of asbestos  found in  this sample
was 0.35 percent of the .total particulate weight.   The asbestos  concen-
                                      3
tration in the emission was 0.37 mg/NM  and  the asbestos mass  emission
rate, was 0.06 kg/hr...^ The asbestos was identified as the amphibole form,
with no chrysotile being found.

     The results reported for the fine crusher runs  included  the impinger
water portion of the total sample, while results  for the waste gas and
hood vent locations do not.  However, it is  demonstrated by the  results
of Run 1 that essentially all (99.9%)of the  asbestos was collected in
the probe wash and filter portions of the sample, and  that  the addition
of the asbestos mass coll^".;!r''~'^'i:i'^'ir.>KLl.-vr;".jF-ra does not significantly
effect the calculated results.      '    • "•"   • •'

     The sampling and analytical procedures  are detailed in Section VII,
and the complete laboratory report is given  in Appendix C.

-------
                     TABLE 1
-». i  r t *—   -a
lj I /\ nj t *   i J

LOCATioN:'
OPERATOR:
                         __
          FINE  CRUSHER STACK lib,"' TOTAL PART I CURATE EMISSIONS
          ENVIRONMENTAL PROTECTION AGENCY
      PART ICULATE
  DESCRIPTION

DATE OF RUN
                    SUMMARY   IN  METRIC   UNITS
                           UNITS         3      AVERAGE
STACK AREA
NET TIME OF RUN
BAROMETRIC PRESSURE
AVG ORIFICE PRES D
VOL DRY GAS-METER
AVG GAS METER TEMP
VOL DRY GAS-STD COND
TOTAL H20 COLLECTED
VOL H20 VAPOR-STD C
PERCENT MOISTURE BY
MOLE FRACTION DRY G
PERCENT C02 BY VOL,.
PERCENT 02 BY VOLX
PERCENT CO BY VOLX
PERCENT N2 BY VOLX
MOLECULAR V/T-DRY ST
MOLECULAR WT-STK GA
AVG STACK TEMPERATURE
NET SAMPLING POINTS
STACK PRESSURE/ ABS
At*X\ f* •*• K f\ I / r\ A r* »f»-i ^>rtl
AVU O I HOf\ UM5 V C.LUO I
STK FLOWRATE, DR
ACTUAL STACK FLOWRATE
PERCENT ISOKINETIC
PARTICULATE NT-PAR
PART ICULATE WT-TOTAL
PERC IMPINGER CATCH
PART. LOAD-PTL/STD
PART. LOAD-TTL/STD
PART. LOAD-PTLXSTD
PART. LOAD-TTL/STD
PART. LOAD-PTL/STK
PART. LOAD-TTLXSTK
PART 1C EMIS-PARTIAL
PART 1C EMIS-TOTAL
PART EMIS/WT PRO FD
PART EMIS/WT PRD FD
PERCENT EXCESS AIR
                                     9-11-73



iop
:OND

ID
1
:OND
' VOL
iAS
. DRY
DRY
DRY
DRY
'K GAS
iS
IRE

;OLUTE
; i TY
;TD CN
iTE

"IAL
iL
1
CN
CN
CN @
CN @
CN
CN


) PTL
) TTL
M2
MIN
MM . HG .
MM.H20
DM3
DEG.C
DNM3
ML
NM3








DEG.C

MM . HG
M/S
DNM3/M
' AM3/M

MG
MG

MG/NM3
MG/NM3
12% C02
12% C02
MG/AM3
MG/AM3
KG/HR
KG/HR
KG/MTON
KG/MTON
0.-369
120.0
739.11*
1*1*. 701*
2.65
29.2
2.52
19.2
0.03
1.0
0.990
0.0
21.0
0.0
79.0
28.81*
28.73
15.9
1
739.11*
^ «• «• x> ^»
£. i . /On
1*71.
1*81.
98.1
26.70
28.«*8
6.3
10.57
11.27
**********




















21.706
1*71.
1*81.
98.1
26.70
28.1*8
6.3
10.57
11.27
*********
******************
10.35
11.01*
0.30
0.32
0.00073
0.00078
10.35
11.01*
0.30
0.32
. 0.00073
0.00078
                                     ******************
                                      7

-------
                            TAB
PLANT:  RESERVE MINING CO"., SiLVhK BAY, MiNN.
LOCATION:  WASTE GAS STACK, PELLET IZER NO.  5,
OPERATOR:  ENVI'ORNMENTAL PROTECTION AGENCY
                                                       TOTAL  PARTICIPATE EMISSION
               PART ICULATE  SUMMARY   IN  METRIC  UNITS
   DESCRIPTION

 DATE OF RUN

 STACK AREA
 NET TIME OF RUN
 BAROMETRIC PRESSURE
 AVG ORIFICE PRES DROP
 VOL DRY GAS-METER COND
 AVG GAS METER TEMP
 VOL DRY GAS-STD COND
 TOTAL H20 COLLECTED
 VOL H20 VAPOR-STD COND
 PERCENT MOISTURE BY VOL
 MOLE FRACTION DRY GAS   .
 PERCENT C02 BY VOL, DRY
 PERCENT 02 BY VOL, DRY
 PERCENT CO BY VOL, DRY
 PERCENT N2 BY VOL, DRY
 MOLECULAR WT-DRY STK GAS
 MOLECULAR WT-STK GAS  «£
 AVG STACK TEMPERATURE
 NET SAMPLING POINTS
 STACK PRESSURE, ABSOLUTE
 AVG STACK GAS VELOCITY
 STK FLOWRATE, DRY,STD CN
 ACTUAL STACK FLOWRATE
 PERCENT ISOKINETIC
 PARTICULATE WT-PARTIAL
 PART ICULATE WT-TOTAL
 PERC IMPINGER CATCH
 PART. LOAD-PTL,STD CN
 PART. LOAD-TTL,STD.CN
 PART. LOAD-PTL,STD CN @
 PART. LOAD-TTL,STD CN @
 PART. LOAD-PTL,STK CN
 PART. LOAD-TTL,STK CN
 PARTIC EMIS-PARTIAL
 PART 1C EMIS-TOTAL
 PART EMIS/WT PRO FD PTL
 PART EMIS/WT PRO FD TTL
 PERCENT EXCESS AIR
                                  UNITS
                                      M2
                                    -M IN-
                                   MM.HG
                                  MM.H20
                                     D.M3
                                   DEG.C
                                    DNM3
                                      ML
                                     NM3
                                   UCU.V.

                                  >*V,,',.-HC
                                     M/S
                                  DNM3/M
                                   AM3/M

                                      MG
                                      MG

                                  MG/NM3
                                  MG/NM3
                                  2% CU2
                                  MG/AM3
                                  MG/AM3
                                   KG/HR
                                   KG/HR
                                 KG/MTON
                                 KG/MTON
6
09-12-73
2.590
37.0
743.71
46.990
0.85
22,, 9
0.83
53.8
0.07
8.0
0.920
0.8
20.0
0.0
79.2
28.93
180.4
1
740.16
36.252
3274.
5634.
105.4
294.30
294.30
0.0
355.02
355.02
5325.33
,53.25.33
206.18
206.18
69.74
69.74
0.63534
0.63534
2200.7
AVERAGE




















36.252
3274.
5634.
105.4
294.30
294.30
0.0
355.02
355.02
5325.33
5325.33
206.18
206.18
69.74
69.74
0.63534
0.63534
2200.7
KhADY

-------
                            iABLb 3       .                             .   •
        PLANT:  RESERVE MINING  CO., SILVER BAY, MINN,
        LOCATION:  HOOD VENT STACK, PELLETIZER NO.  5,  TOTAL  PARTICULATE  EMISSION
        OPERATOR:  ENVIORNMENTAL PROTECTION AGENCY
               PARTICULATE  SUMMARY   IN  METRIC  UNITS
           DESCRIPTION
         DATE OF RUN
                         .UNITS
STACK AREA                   M2
NET TIME OF RUN            MIN
BAROMETRIC PRESSURE       MM.HG
AVG ORIFICE PRES DROP    MM.H20
VOL DRY GAS-METER COND      DM3
AVG GAS METER TEMP        DEG.C
VOL DRY GAS-STD COND       DNM3
TOTAL H20 COLLECTED          ML
VOL H20 VAPOR-STD COND      NM3
PERCENT MOISTURE BY VOL
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL, DRY
        02 BY VOL, DRY
        CO BY VOL, DRY
        N2 BY VOL, DRY
          WT-DRY STK GAS
          V/T-STK GAS
          TEMPERATURE
PERCENT
PERCENT
PERCENT
MOLECULAR
HGLECULAR
AVG STACK
                                   DEG.C
         NET SAMPLING POINTS
         STACK PRESSURE, ABSOLUTE  MM.HG
         AVG STACK GAS VELOCITY      M/S
         STK FLOWRATE, DRY,STD CN DNM3/M
         ACTUAL STACK FLOWRATE     AM3/M
         PERCENT ISOKINETIC
         PARTICULATE WT-PARTIAL       MG
         PARTICULATE WT-TOTAL         MG
         PERC IMPINGER CATCH
         PART. LOAD-PTL,STD CN    MG/NM3
         PART. LOAD-TTL,STD CN    MG/NM3
         PART. LOAD-PTL,STD CN (3 12?j C02
         PART. LOAD-TTL,STD CN @ 12% C02
         PART. LOAD-PTL,STK CN    MG/AM3
         PART. LOAD-TTL,STK CN    MG/AM3
         PART 1C EMIS-PARTIAL       KG/HR
         PART 1C EMIS-TOTAL         KG/HR
         PART EMIS/WT PRO FD PTL KG/MTON
         PART EMIS/WT PRO 'FD TTL KG/MTON
         PERCENT EXCESS AIR
io ••
09-13-73
2.572
36.0
745.24
30.480
0.55
25.6
0.63
31.2
0.04
6.2
0.938
0.0
21.0
0.0
79.0
28.17
120.0
1
742.70
25.542
2705.
3942.
99.7
81.10
81.10
0.0
127.74
127.74
AVERAGE



















25.542
2705.
3942.
99.7
81.10
81.10
0.0
127.74
127.74
* * * * * * * ***********
***********
87.59
87.59
20.73
20.73
0.16679
*******
87.59
87.59
20.73
20.73
0.16679
                                    0.16679   0.16679
                                   ******************
READY
                                             9

-------
                       TABLE 4
PLANT:  RESERVE MINING COMPANY.; SILVER liAV, MINNESOTA
LOCATION:   FINE CRUSHER STACK 110, TOTAL ASBESTOS  EMISSIONS
OPERATOR:   ENVIRONMENTAL PROTECTION AGENCY
       PART ICULATE  SUMMARY   IN  METRIC  UNITS
  DESCRIPTION            UNITS

DATE OF RUN

STACK AREA                   M2
NET TIME OF RUN            MIN
BAROMETRIC PRESSURE       MM.HG
AVG ORIFICE PRES DROP    MM.H20
VOL DRY GAS-METER COND       DM3
AVG GAS METER TEMP        DEG.C
VOL DRY GAS-STD COND       DNM3
TOTAL H20 COLLECTED          ML
VOL H20 VAPOR-STD COND       NM3
PERCENT MOISTURE BY VOL
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL, DRY
PERCENT 02 BY VOL, DRY
PERCENT CO BY VOL, DRY
-PERCENT N2 BY VOL, DRY
MOLECULAR WT-DRY STK GAS
MOLECULAR WT-STK GAS   v - „.< -• .-.-.•• -
AVG STACK TEMPERATURE    '"'DEG.C'
NET SAMPLING PO I'NTS
STACK PRESSURE, ABSOLUTE  MM.HG
AVG STACK GAS VELOCITY       M/S
STK FLOWRATE, DRY,STD CN DNM3/M
ACTUAL STACK FLOWRATE     AM3/M
PERCENT ISOKINETIC
PART ICULATE WT-PARTIAL       MG
PART ICULATE WT-TOTAL         MG
PERC IMPINGER CATCH
PART.  LOAD-PTL,STD CN    MG/NM3
PART.  LOAD-TTL,STD CN    MG/NM3
PART.  LOAD-PTL,STD CN @ 12%  C02
PART.  LOAD-TTL,STD CN @ 12%  .CO?
PART.  LOAD-PTL,STK CN    MG/AM3
PART.  LOAD-TTL,STK CN    MG/AM3
PART 1C EM IS-PARTIAL       KG/HR
PART 1C EMIS-TOTAL         KG/HR
PART EMIS/WT PRO FD PTL KG/MTON
PART EMIS/WT PRO FD TTL KG/MTON
PERCENT EXCESS -AIR
                                               AVERAGE
                                    9-11-73

                                       0.369
                                       120.0
                                      739.14
                                      44.704
                                        2,65
                                        29.2
                                        2.52
                                        19.2
                                        0.03
                                         1.0
                                       0.990
                                         0.0
                                        21.0
                                         0.0
                                        79.0
                                       .28.84

                                    "'""'""""'15.9
                                           1
                                      739.14
                                      21.706
                                        471.
                                        481.
                                        98.1
                                        1.65
                                        1.65
                                         0.1
                                        0.65
                                        0.65
         21.706
           471.
           481.
           98.1
           1.65
           1.65
            0.1
           0.65
           0.65
                                    ******************
                                    ******************
                                     0
 0.64
 0.64
 0.02
 0.02
00005
                                     0.00005
   0.64
   0.64
   0.02
   0.02
0.00005
0.00005
                                    ******************

-------
        PLANT.:  RESERVE MINING CO., SILVER BAY, MINN.
        LOCATION:  WASTE GAS STACK, PELLET IZER NO. 5, TOTAL ASBESTOS  EMISSIONS
        OPERATOR:  ENVIORNMENTAL PROTECTION AGENCY
               PART ICULATE  SUMMARY  IN  METRIC  UNITS
           DESCRIPTION            UNITS

         DATE OF RUN

         STACK AREA                   M2
         NET TIME OF RUN            MIN
         BAROMETRIC PRESSURE       MM.HG
         AVG ORIFICE PRES DROP    MM.H20
         VOL DRY GAS-METER COND   "   DM3
         AVG GAS METER TEMP        DEG.C
         VOL DRY GAS-STD COND       DNM3
         TOTAL H20 COLLECTED          ML
         VOL H20 VAPOR-STD COND      NM3
         PERCENT MOISTURE BY VOL
         MOLE FRACTION DRY GAS
         PERCENT C02 BY VOL, DRY
         PERCENT 02 BY VOL, DRY
         PERCENT CO BY VOL, DRY
         PERCENT N2 BY VOL, DRY
         MOLECULAR WT-DRY STK GAS
         MOLECULAR WT-STK GAS     *-^V-'~?;-.
         AVG STACK TEMPERATURE     DEG,C
         NET SAMPLING POINTS
         STACK PRESSURE, ABSOLUTE  MM.HG
         AVG STACK GAS VELOCITY      M/S
         STK FLOWRATE, DRY,STD CN DNM3/M
         ACTUAL STACK FLOWRATE     AM3/M
         PERCENT ISOKINETIC
         PART ICULATE WT-PARTIAL       MG
         PARTICULATE WT-TOTAL         MG
         PERC IMPINGER CATCH
         PART.  LOAD-PTL,STD CN    MG/NM3
         PART.  LOAD-TTL,STD CN    MG/NM3
         PART.  LOAD-PTL,STD CN @ 12% C02
         PART.  LQAD-TTL,STD CN @ 12% C02
         PART.  LOAD-PTL,STK CN    MG/AM3
         PART.  LOAD-TTL,STK CN    MG/AM3
         PARTIC EMIS-PARTIAL       KG/HR
         PART 1C EMIS-TOTAL         KG/HR
         PART EMIS/WT PRO FD PTL KG/MTON
         PART EMIS/WT PRO FD TTL KG/MTON
         PERCENT EXCESS AfR
6
09-12-73
2.590
37.0
743.71
46.990
0.85
22,9
0.83
53.8
0.07
8.0
0.920
0.8
20.0
0.0
79.2
. ?8, 93.
.JSO.'J
1
740.16-
36.252
3274.
5634.
105.4
0.67
0.67
0.0
0.81
0.81
12.09
•'••"•-T2-. 09
0.47
0.47
0.16
0.16
0.00144
0.00144
2200.7
AVERAGE




















36.252
3274.
5634.
105.4
0.67
0.67
0.0
0.81
0.81
12.09
12.09
0.47
0.47
0.16
0.16
0.00144
0.00144
2200.7
READY

-------
                    TABLE 6
PLANT:  RESERVE MINING CO., SILVER BAY,- MINN,
LOCATION:  HOOD VENT STACK,. PELLETIZER NO.  5,
OPERATOR:  ENV I ORNMENTAL PROTECTION AGENCY
                                             TOTAL ASBESTOS  EMISSIONS
      PART I CD LATE  SUMMARY  IN - METRIC  UNITS
   DESCRIPTION

 DATE OF RUN

 STACK AREA
 NET TIME OF RUN
 BAROMETRIC PRESSURE
 AVG ORIFICE PRES DR
 VOL DRY GAS-METER C
 AVG GAS METER TEMP
 VOL DRY GAS-STD COND
 TOTAL H2.0 COLLECTED
 VOL H20 VAPOR-STD C
 PERCENT MOISTURE BY
 MOLE FRACTION DRY G
 PERCENT C02 BY VOL,
 PERCENT 02 BY VOL,
 PERCENT CO BY VOL,
 PERCENT N2 BY VOL,
 MOLECULAR WT-DRY ST
 MOLECULAR VJT-STK GA
 AVG STACK TEMPERATURE
 NET SAMPLING POINTS-
 STACK PRESSURE, ABS
 AVG STACK GAS VELOC
 STK FLOWRATE, DRY,S
 ACTUAL STACK FLOWRATE
 PERCENT ISOKINETIC
 PART ICULATE WT-PAR
 PARTICULATE WT-TOTAL
 PERC IMPINGER CATCH
       LOAD-PTL,STD
       LOAD-TTL,STD
       LOAD-PTL,STD
       LOAD-TTL,STD
       LOAD-PTL,STK
       LOAD-TTL,STK
      C EM IS-PARTIAL
      C EMIS-TOTAL
      EMIS/WT PRD FD
      EMIS/WT PRD FD
PART
PART
PART
PART
PART
PART
PART
PART
PART
PART
UNITS

M2
MIN
MM.HG
OP MM.H20
OND DM3
DEG.C
D DNM3
ML
OND NM3
VOL
AS
DRY
DRY
DRY
DRY
K GAS
,S
RE DEG.C

OLUTE MM.HG
ITY M/S
TD CN DNM3/M
TE AM3/M

IAL MG
,L MG
1
CN MG/NM3
CN MG/NM3
CN @ 12% C02
CN @ 12% C02
CN MG/AM3
CN MG/AM3
KG/HR
KG/HR
I PTL KG/MTON
I TTL KG/MTON
10
09-13-73
2.572
36'. 0
745.24
30.480
0.65
25.6
0.63
31.2
0.04
6.2
0.938
0.0
21.0
0.0
79.0
28.84
28.17
120.0
1
742.70
25.542
2705.
3942.
99.7
0.24
0.24
0.0
0.37
0.37
AVERAGE





















25.542
2705.
3942.
99.7
0.24
0.24
0.0
0.37
0.37
******************
******************
0.26
0.26
0.06
0.06
0.00049
0.00049
0.26
0.26
0.06
0.06
0.00049
0.00049
                                  1 O

-------
PLANT:   RESERVE MINING COMPANY; SILVER BAY,
LOCATION:   FINE CRUSHER STACK 110, AMPHIDOI.F.
OPERATOR:   ENVIRONMENTAL PROTECTION AGENCY
                                           MINNESOTA
                                           ASBESTOS EMISSIONS
      PART ICULATE  SUMMARY  IN  METRIC  UNITS
  DESCRIPTION     .     .  UNITS

DATE OF RUN               	

STACK AREA                   M2
NET TIME OF RUN            MIN
BAROMETRIC PRESSURE       MM.HG
AVG ORIFICE PRES DROP    MM.H20
VOL DRY GAS-METER COND  -  -  DM3
AVG GAS METER TEMP        DEG.C
VOL DRY GAS-STD COND	-	DMM3
TOTAL H20 COLLECTED          ML
VOL H20 VAPOR-STD COND      NM3
PERCENT MOISTURE BY VOL
MOLE FRACTION DRY GAS		
PERCENT C02 BY VOL, DRY
PERCENT 02 BY VOL, DRY     	
PERCENT CO BY VOL, DRY
PERCENT N2 BY VOL, DRY
MOLECULAR WT-DRY STK GAS
MOLECULAR WT-STK GAS
AVG STACK TEMPERATURE     DEG.C
NET SAMPLING POINTS
STACK PRESSURE, ABSOLUTE  MM.HG
AVG STACK GAS VELOCITY      M/S
STK FLOWRATE, DRY,STD CN DNM3/M
ACTUAL STACK FLOWRATE     AM3/M
PERCENT I SDK I NET 1C
PARTICULATE WT-PARTIAL       MG
PART ICULATE WT-TOTAL         MG
PERC IMPINGER CATCH   	
PART.  LOAD-PTL,STD CN    MG/NM3
PART.  LOAD-TTL,STD CN    MG/NM3
PART.  LOAD-PTL,STD CN @ 12% C02
PART.  LOAD-TTL,STD CN @ 12% C02
PART.  LOAD-PTL,STK CN    MG/AM3
PART.  LOAD-TTL,STK CN    MG/AM3
PART 1C EM IS-PARTIAL       KG/HR
PART 1C EMIS-TOTAL         KG/HR
PART EMIS/WT PRO FD PTL KG/MTON
PART EMIS/WT PRO FD TTL KG/MTON
PERCENT EXCESS AIR
3 AVERAG.E. ' . ' ~ " ;
9-11-73 	 ~ -;• 	
0.369
120.0
739.14
44.704
	 2.65 —
29.2
2.52
19.2
" 	 0.03 -
1.0
	 0.990 	
0.0
	 -21.0
0.0
"79.0
28.84
28.73
15.9
	 1
739.14
21.706 •••"•
471.
481. 	 '
98.1
- 1.65
1.65
- o.i
0.65
0.65
************
************
0.64
0.64
0.02
0.02
0.00005 0
0.00005 0
	 — 	 — --' 	 	 	 •--•
	 	 	 	 '" •-. 	 -

•• 	 	 — • — .. - -. •- 	
.
21.706 - 	 • 	 ! '
471.
'481. ~ • 	 "• 	 v •
98.1
1.65 "•" 	 	 -;••'••
1.65
— • o.i 	 .---.-
0.65 . '•• i ••-:••;<-".• • ••"•••--.
"0.65 . — - , 	 - ...,
****** . -.-••;-
****** ---• - 	 - _ . ... ..
0.64 ••'-.
0.64 	 	 " ". ----••
0.02
0. 02 " .
.00005 K"---. ':
.00005 ~ -•.--,-- -;-.-. • ..;.
                                    ******************
                                      13

-------
                    TABLE 8
PLANT:  RESERVE MINING CO., SILVER BAY, MINN.
LOCATION:  WASTE GAS STACK, PELLET I ZER NO. 5,
OPERATOR:  ENVIORNMENTAL PROTECTION AGENCY
                                                      AMPHIBOLE EMISSIONS
               PART ICULATE  SUMMARY  IN  METRIC  UNITS
READY
           DESCRIPTION    •   .     UNITS

         DATE OF RUN

         STACK AREA                   M2
         NET TIME OF RUN            MIN
         BAROMETRIC PRESSURE       MM.HG
         AVG ORIFICE PRES DROP    MM.H20
         VOL DRY GAS-METER COND      DM3
         AVG GAS METER TEMP        DEG.C
         VOL DRY GAS-STD COND       DNM3
         TOTAL H20 COLLECTED          ML
         VOL H20 VAPOR-STD COND      NM3
         PERCENT MOISTURE BY VOL
         MOLE FRACTION DRY GAS
         PERCENT C02 BY VOL, DRY
         PERCENT 02 BY VOL, DRY
         PERCENT CO BY VOL, DRY
         PERCENT N2 BY VOL, DRY
         MOLECULAR WT-DRY STK GAS
         MOLECULAR WT-STK GAS
         AVG STACK TEMPERATURE     DEG.C
         NET SAMPLING POINTS
         STACK PRESSURE, ABSOLUTE  MM.HG
         AVG STACK GAS VELOCITY      M/S
         STK FLOWRATE, DRY,STD CN DNM3/M
         ACTUAL STACK FLOWRATE     AM3/M
         PERCENT ISOKINETIC
         PARTICULATE WT-PARTIAL       MG
         PARTICULATE WT-TOTAL         MG
         PERC IMPINGER CATCH
         PART. LOAD-PTL,STD CN    MG/NM3
         PART. LOAD-TTL,STD CN    MG/NM3
         PART. LOAD-PTL,STD CN @ 12% C02
         PART. LOAD-TTL,STD CN @ 12% C02
         PART. LOAD-PTL,STK CN    MG/AM3
         PART. LOAD-TTL,STK CN    MG/AM3
         PART 1C EM IS-PARTIAL       KG/HR
         PART 1C EMIS-TOTAL         KG/HR
         PART EMIS/WT PRO FD PTL KG/MTON
         PART EMIS/WT PRO FD TTL KG/MTON
         PERCENT EXCESS AIR
6
09-12-73
2.590
37.0
743.71
46.990
0.85
22.9
0.83
53.8
0.07
8.0
. 0.920
0.8
20.0
0.0
79.2
28.93
A A ^ f
L 0 . U 3
180.U
1
740.16
36.252
3274.
5634.
105.4
0.64
0.64
0.0
0.78
0.78
11.67
11.67
0.45
0.45
0.15
0.15
0.00139
0.00139
2200.7
AVERAGE





















36.252
3274.
5634.
105.4
0.64
0.64
0,0
0.78
0.78
11.67
11.67
0.45
0.45
0.15
0.15
0.00139
0.00139
2200.7

-------
                     TABLE 9
PLANT:  RESERVE MINING CO., SILVER BAY, MINN
LOCATION:   HOOD VENT STACK, PELLET I ZER NO. 5,
OPERATOR:   ENVI ORNMENTAL PROTECTION AGENCY
                                                     AMPHIBOLE  EMISSIONS
               PART ICULATE  SUMMARY   IN  METRIC  UNITS
           DESCRIPTION

         DATE OF RUN

         STACK AREA
         NET TIME OF RUN
         BAROMETRIC PRESSURE
         AVG ORIFICE PRES D
         VOL DRY GAS-METER
         AVG GAS METER TEMP
         VOL DRY GAS-STD COND
         TOTAL H20 COLLECTED
         VOL H20 VAPOR-STD C
         PERCENT MOISTURE BY
         MOLE FRACTION DRY G
         PERCENT C02 BY VOL,
         PERCENT 02 BY VOL,
         PERCENT CO BY VOL,
         PERCENT N2 BY VOL,
         MOLECULAR WT-DRY ST
         MOLECULAR WT-STK G
         AVG STACK TEMPERATURE
         NET SAMPLING POINTS
         STACK PRESSURE, ABS
         AVG STACK GAS VELOC
         STK FLOWRATE, DRY,S
         ACTUAL STACK FLOWRATE
         PERCENT ISOK1NETIC
         PART ICULATE WT-PAR
         PART ICULATE WT-TOTAL
         PERC IMPINGER CATCH
         PART.  LOAD-PTL,STD
         PART.  LOAD-TTL,STD
         PART.  LOAD-PTL,STD
         PART.  LOAD-TTL,STD
         PART.  LOAD-PTL,STK
         PART.  LOAD-TTL,STK
         PART 1C EM IS-PARTIAL
         PART 1C EMIS-TOTAL
         PART EMIS/WT PRO FD
         PART EMIS/WT PRO FD
         PERCENT EXCESS-AIR





OP
OND

D

OND
VOL
AS
DRY
DRY
DRY
DRY
K GAS
RE

OLUTE
ITY
TD CN
TE

IAL
L

CN
CN
CN @
CN @
CN
CN


PTL
TTL
UN 1 TS

M2
MIN
MM . HG
MM.H20
DM3
DEG.C
DNM3
ML
NM3







D EG « C

MM . HG
M/S
DNM3/M
AM3/M

MG
MG

MG/NM3
MG/NM3
12% C02
m cor
MG/AM3
MG/AM3
KG/HR
KG/HR
KG/MTON
KG/MTOM
.10
09-13-73
2.572
36.0
745.24
30.480
0.65
25.6
0.63
31.2
0.04
6.2
0.938
0.0
21.0
0.0
79.0
_^ v .2^.84
12olo
1
'• 742.70
25.542
2705.
3942.
99.7
0.24
0.24
0.0
0.37
P. 37
***********
AVERAGE




















25.542
2705.
3942.
99.7
0.24
0.24
0.0
0.37
0.37
*******
, . : .;*,****.** ***********
0.26
0.26
0.06
0.06
0.00049
0.00049
0.26
0.26
0006
0.06
0.00049
0.00049
                                    ******************
READY
                                             1

-------
                     -r n. n !  r 1 r>
                     ! .M.L'!_C. i U
PLANT:   RESERVE MINING; SILVER BAY, MINNESOTA
LOCATION:   FINE CRUSHER STACKI10, TOTAL PARTICIPATE
OPERATOR:   ENVIRONMENTAL PROTECTION AGENCY
                                                    EM
                   ss
                                                         ONS
      PART ICULATE SUMMARY   IN  ENGLISH  UNITS
  DESCRIPTION

DATE OF RUN

STACK AREA
NET TIME OF RUN
BAROMETRIC PRESSURE
AVG ORIFICE PRES DROP
VOL DRY GAS-METER COND
AVG GAS METER TEMP
VOL DRY GAS-STD COND
TOTAL H20 COLLECTED
VOL M20 VAPOR-STD COND
PERCENT MOISTURE BY VOL
MOLE FRACTION DRY GAS
PERCENT C02 3Y VOL, DRY
PERCENT 02 BY VOL, DRY
PERCENT CO BY VOL, DRY
PERCENT N2 BY VOL, DRY
MOLECULAR NT-DRY STK GAS
MOLECULAR WT-STK GAS
AVG STACK TEMPERATURE
NET SAMPLING POINTS
STACK PRESSURE, ABSOLUTE
AVG STACK GAS VELOCITY
STK FLOV.'RATE, DRY,STD CN
ACTUAL STACK FLOWRATE
PERCENT ISOKINETIC
PART ICULATE WT-PARTIAL
PART ICULATE WT-TOTAL
PERC IMPINGER CATCH
      LOAD-PTL,STD CN
      LOAD-TTL,STD CN
      LOAD-PTL,STD CN @
      LOAD-TTL,STD CN @
      LOAD-PTL/STK CN
      LOAD-TTL,STK CN
                          UNITS'
                            FT2
                            MIN
                           IN.HG
                          IN.H20
                            DCF
                          D EG. F
                           DSCF
                             ML
                            SCF
PART,
PART,
PART,
PART,
PART,
PART,
PART 1C
       EM IS-PARTIAL
PART 1C EMIS-TOTAL
PART EMIS/WT PRD FD
PART EMIS/V/T PRD FD
PERCENT EXCESS AIR
                    PTL
                    TTL
                           DEG.F

                          ' IN.HG
                             FPS
                           DSCFM
                            ACFM

                              MG
                              MG

                         GR/DSCF
                         GR/DSCF
                         125 C02
                         12% C02
                          GR/ACF
                          GR/ACF
                           LB/HR
                           LB/HR
                          LB/TON
                          LB/TON
3
9-11-73
3.976
120.0
29.10
1.760
93.70
84.6
89.06
19.2
0.91
1.0
0.990
0.0
21.0
0.0
79.0
28.84
28.73
60.7
1
29.10
71.214
16644.
16989.
98.1
26.70
28.48
6.3
0.00462
0.00493
********
AVERAGE





















71.214
16644.
16989.
98.1
26.70
28.48
6.3
0.00462
0.00493
**********
******************
0.00452
0.00482
0.66
0.70
0.00146
0. 00452
0.00482
0.66
0.70
0.00145
 0.00156   0.00156
*•* ****************

-------
PLANT:
I nr* A T i nn .
L. W V>/~\ I  I VJ I* •
OPERATOR:
       RESERVE
          I.I AC Tr
                 TABLE 11
               MINING CO
                 SILVER BAY, MINN.
            ACK, PELLET IZER NO. 5,
ENVIORNMENTAL PROTECTION AGENCY
                                             TOTAL  PARTICIPATE
      PART ICULATE SUMMARY   IN  ENGLISH  UNITS
  DESCRIPTION            UNITS

DATE OF RUN

STACK AREA                 FT2
NET TIME OF RUN            MIN
BAROMETRIC PRESSURE      IN.HG
AVG ORIFICE PRES DROP    IN.H20
VOL DRY GAS-METER COND     DCF
AVG GAS METER TEMP       DEG.F
VOL DRY GAS-STD COND      DSCF
TOTAL H20 COLLECTED         ML
VOL H20 VAPOR-STD COND     SCF
PERCENT MOISTURE BY VOL
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL, DRY
PERCENT 02 BY VOL, DRY
PERCENT CO BY VOL, DRY
PERCENT N2 BY VOL, DRY .
MOLECULAR WT-DRY STK GAS
MOLECULAR WT-STK GAS
AVG STACK TEMPERATURE    • DEG.F
NET SAMPLING POINTS
STACK PRESSURE, ABSOLUTE  IN.HG
AVG STACK GAS VELOCITY      FPS
STK FLOWRATE, DRY,STD CN  DSCFM
ACTUAL STACK FLOWRATE      ACFM
PERCENT ISOKINETIC
PART ICULATE WT-PARTIAL       MG
PART ICULATE WT-TOTAL         MG
PERC IMPINGER C#TCH
PART. LOAD-PTL/STD CN   GR/DSCF
PART. LOAD-TTL,STD CN   GR/DSCF
PART. LOAD-PTL,STD CN @ 12% C02
PART. LOAD-TTL,STD CN @ 12% C02
PART. LOAD-PTL,STK CN    GR/ACF
PART. LOAD-TTL,STK CN    GR/ACF
PARTIC EMIS-PARTIAL       LB/HR
PART 1C EMIS-TOTAL         LB/HR
PART EMIS/WT PRO FD PTL  LB/TON
     EMIS/WT PRO FD TTL  LB/TON
PART
PERCENT
         EXCESS
               AIR
6
09-12-73
27.882
37. 0
29.28
1.850
29.90
73.2
29.21
53.3
2.55
8.0
0.920
0.8
20.0
0.0
79.2
••> o 01
£. 0 • Cl J
28.05
356.8
1
29.1U
118.936
115621.
198972.
105.4
294.30
294.30
0.0
0.15514
0.15514
2.32712
2J32712
0.09010
0.09010
153.75
153.75
1. 27068
1.27068
2200.7
AVERAGE





















118.936
115621.
198972.
105.4
294.30
294.30
0.0
0.15514
0.15514
2.32712
2.32712
0.09010
0.09010
153.75
153.75
1.27068
1.27068
2200.7

-------
                  TABLE 12
PLANT:  RESERVE MINING CO., SILVER BAY, MINN.
LOCATION:   HOOD VENT STACK, PELLETIZER MO. 5, TOTAL PARTICULATE EMISSIONS
OPERATOR:   ENV!ORNMENTAL PROTECTION AGENCY
       PARTICULATE SUMMARY  IN  ENGLISH  UNITS
   DESCRIPTION

 DATE OF RUN

 STACK AREA
 NET TIME OF RUN
 BAROMETRIC PRESSURE
 AVG ORIFICE PRES DR
 VOL DRY GAS-METER C
 AVG GAS METER TEMP
 VOL DRY GAS-STD COND
 TOTAL H20 COLLECTED
 VOL H20 VAPOR-STD C
 PERCENT MOISTURE BY
 MOLE FRACTION DRY G
 PERCENT C02 BY VOL,
 PERCENT 02 BY VOL,
 PERCENT CO BY VOL,
 PERCENT N2 BY VOL,
 MOLECULAR WT-DRY ST
 MOLECULAR WT-STK GA
 AVG STACK TEMPERATURE
 NET SAMPLING POINTS
 STACK PRESSURE, ABS
 AVG STACK GAS VELOC
 STK FLOWRATE, DRY,S
 ACTUAL STACK FLOWRATE
 PERCENT ISOKINETIC
 PARTICULATE WT-PAR
 PARTICULATE WT-TOTAL
 PERC IMPINGER CATCH
 PART. LOAD-PTL,STD
 PART. LOAD-TTL,STD
 PART,, LOAD-PTL,STD
 PART., LOAD-TTL,STD
 PART., LOAD-PTL,STK
 PART,, LOAD-TTL,STK
 PART 1C EM IS-PARTIAL
 PART 1C EMIS-TOTAL
 PART EMIS/WT PRO FD
 PART EMIS/WT PRD FD
 PERCENT EXCESS AIR





OP
OND

D

OND
VOL
AS
DRY
DRY
DRY
DRY
K GAS
S
RE

OLUTE
ITY
TD CN
TE

IAL
L

CN
CN
CN @
CN @
CN
CN


> PTL
' TTL
UNITS •

FT2
MIN
1 M . HG
IN.H20
DCF
DEG.F
DSCF
ML
SCF








DEG.F

IN.HG
FPS
DSCFM
ACFM

MG
MG

GR/DSCF
GR/DSCF
12% C02
12% C02
GR/ACF
GR/ACF
LB/HR
LB/HR
LB/TON
LB/TON
10 -
09-13-73
27.688
36.0
29.34
1.200
23.10
78.1
22.37
31.2
1.48
6.2
0.938
0.0
21.0
0.0
79.0
28.84
28.17
248.0
1
29.24
83.800
95509.
139214.
99.7
81.10
81.10
0.0
0.05582
0.05582
**** * ****4
AVERAGE





















83.800
95509.
139214.
99.7
81.10
81.10
0.0
0.05582
0.05582
*********
******************
0.03828
0.03828
45.70
45.70
0.33357
0.33357
0.03828
0.03828
45.70
45.70
0.33357
0.33357
******************
                               IH

-------
PLANT:   RESERVE  MINING COMPANY; SILVER BAY,  MINNESOTA
: .-..- .".*.- :/•*.?.!_   r: : MC  rr>\ ;c i!rt?  *:T n. r.<-; i 1 r\   ~<"AT A ;  AC a CCTOC CM i CC
L. vv w M i I w 1-4 •   t  i 111_  \s , \^* *^ * » t»  v • .,»-.. i i. v ,  :**:.—. i- r-.	.-..• i *..-•-• t-r • • • • •_•
OPERATOR:   ENVIROMMENiAL  PROTECTION  AGENCY

                        TABLE 13


        PART ICULATE  SUMMARY   IN  ENGLISH  UNITS
   DESCRIPTION

 DAT.E  OF RUN
UNITS
           9-11-73
AVERAGE
STACK AREA FT2
NET TIME OF RUN MIN
BAROMETRIC PRESSURE IN.HG
AVG ORIFICE PRES DROP IN.H20
VOL DRY GAS-METER COND DCF
AVG GAS METER TEMP DEG.F
VOL DRY GAS-STD COND DSCF
TOTAL H20 COLLECTED ML
VOL H20 VAPOR-STD COND SCF
PERCENT MOISTURE BY VOL
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL, DRY
PERCENT 02 BY VOL, DRY
PERCENT CO BY VOL, DRY
PERCENT N2 BY VOL, DRY
MOLECULAR WT-DRY STK GAS
MOLECULAR WT-STK GAS
AVG STACK TEMPERATURE DEG.F
NET SAMPLING POINTS
STACK PRESSURE/ ABSOLUTE IN.HG
AVG STACK GAS VELOCITY FPS
STK. FLOWRATE, DRY/STD CN DSCFM
ACTUAL STACK FLOWRATE ACFM
PERCENT ISOKINETIC
PART ICU LATE WT- PARTIAL MG
PART ICU LATE WT-TOTAL MG
PERC IMPINGER CATCH
PART. LOAD-PTL/STD CN GR/DSCF
PART. LOAD-TTL,STD CN GR/DSCF
PART. LOAD-PTL,STD CN @ 12% C02
PART. LOAD-TTL/STD CN @ 12% C02
PART. LOAD-PTL/STK CN GR/ACF
PART. LOAD-TTL,STK CN GR/ACF
PART 1C EMIS-PARTIAL LB/HR
PART 1C EMIS-TOTAL LB/HR
PART EMIS/WT PRO FD PTL LB/TON
PART EMIS/WT PRO FD TTL LB/TON
PERCENT EXCESS AIR
3.976
120.0
29.10 '
1.760
93.70
84.6
89.06
19.2
0.91
1.0
0.990
0.0
21.0
0..0
79.0
28.84
28.73
60.7
1
29.10
71.214
16644.
16989.
98.1
1.65
1.65
0.1
0.00029 0
0.00029 0




















71.214
16644.
16989.
98.1
1.65
1.65
0.1
.00029
.00029
******************
******************
0.00028 0
0.00028 0
0.04
0.04
0.00009 0
0.00009 0
************
.00028
.00028
0.04
0.04
.00009
.00009
******

-------
                    TABLE. 14
PLANT:   RESERVE MINING CO., SILVER BAY, MINN.
LOCATION:  WASTE GAS STACK, PELLETiZER NO.  5,  TOTAL  ASBESTOS  EMISSIONS
OPERATOR:  ENVIORNMENTAL PROTECTION AGENCY
       PARTICIPATE SUMMARY   IN  ENGLISH  UNITS
  DESCRIPTION

DATE OF RUN

STACK AREA
NET TIME OF RUN
BAROMETRIC PRESSURE
AVG ORIFICE PRES DROP
VOL DRY GAS-METER COND
AVG GAS METER TEMP
VOL DRY GAS-STD COND
TOTAL H20 COLLECTED
VOL H20 VAPOR-STD COND
.PERCENT MOISTURE BY VOL
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL, DRY
PERCENT 02 BY VOL, DRY
PERCENT CO BY VOL, DRY
PERCENT N2 BY VOL, DRY
MOLECULAR WT-DRY STK GAS
MOLECULAR WT-STK-GAS
AVG STACK TEMPERATURE
NET SAMPLING POINTS
STACK PRESSURE, ABSOLUTE
AVG STACK GAS VELOCITY
STK FLOWRATE, DRY,STD CN
ACTUAL STACK FLOWRATE
PERCENT ISOKINETIC
PART ICULATE WT-PARTIAL
PARTICIPATE WT-TOTAL
PERC IMPINGER CATCH.
PART.  LOAD-PTL,STD CN
PART.  LOAD-TTL,STD CN
PART.  LOAD-PTL,STD CN @
PART.  LOAD-TTL,STD CN @
PART.  LOAD-PTL,STK CN
PART.  LOAD-TTL,STK CN
PART 1C EM IS-PARTIAL
                          UNITS
                            FT2
                            MIN
                          .1 N. HG
                         IN.H20
                            DCF
                          DEG.F
                           DSCF
                             ML
                            SCF
 PART 1C EMIS-TOTAL
 PART EMIS/WT PRD'FD
 PART EMIS/WT PRO FD
 PERCENT EXCESS AIR
                     PTL
                     TTL
  DEG.F

  I N. HG
    FPS
  DSCFM
   ACFM

     MG
     MG

GR/USCF
G"R/D,S£.F
1 0 ft •;• f>-f- -t •
X £ 'j  Vj* vr* /j
12%  C02
 GR/ACF
 GR/ACF
  LB/HR
  LB/HR
 IB/TON
 LB/TON
6
09-12-73
27.882
37.0
29.28
1.850
29.90
73.2
29.21
53.8
2.55
8.0
0.920
0.8
20.0
• 0.0
£73., '2
28.93
28.05
* 356.8.
1
29.U
118.936
115621.
198972.
105.U
0.67
0.67
0.0
0.00035
0.0-0035
0.00528
0.00528
0.00020
0.00020
0.35
0.35
0.00288
0.00288
2200.7
AVERAGE





















118.936
115621.
198972.
105.1*
0.67
0.67
0.0
0.00035
0.00035
0.00528
0.00528
0.00020
0.00020
0.35
0.35
0.00288
0.00288
2200.7
                                 20

-------
                    TABLE 15
PLANTS  RESERVE MINING CO., SILvtR BAY, MINN.
LOCATION:  HOOD VENT STACK', PELLETIZER NO. 5, TOTAL ASBESTOS EMISSIONS
OPERATOR:  ENVIORNMENTAL PROTECTION AGENCY
       PARTICULATE SUMMARY  IN ' ENGLISH  UNITS
   DESCRIPTION

 DATE OF RUN

 STACK AREA
 NET TIME OF RUN
 BAROMETRIC PRESSURE
 AVG ORIFICE PRES DR
 VOL DRY GAS-METER C
 AVG GAS METER TEMP.
 VOL DRY GAS-STD COND
 TOTAL H20 COLLECTED
 VOL H20 VAPOR-STD C
 PERCENT MOISTURE BY
 MOLE FRACTION DRY G
 PERCENT C02 BY VOL,
 PERCENT 02 BY VOL,
 PERCENT CO BY VOL,
 PERCENT N2 BY VOL,
 MOLECULAR WT-DRY ST
 MOLECULAR WT-STK GA
 AVG STACK TEMPERATURE
 NET SAMPLING POINTS
 STACK PRESSURE, ABS
 AVG STACK GAS VELOC
 STK FLOWRATE, DRY,S
 ACTUAL STACK FLOWRATE
 PERCENT ISOKINETIC
 PARTICULATE WT-PAR
 PARTICULATE WT-TOTAL
 PERC IMPINGER CATCH
 PART. LOAD-PTL,STD
 PART. LOAD-TTL,STD
 PART. LOAD-PTL,STD
 PART. LOAD-TTL,STD
 PART. LOAD-PTL,STK
 PART. LOAD-TTL,STK
 PART 1C EM IS-PARTIAL
 PART 1C EMIS-TOTAL
 PART EMIS/WT PRO FD
 PART EMIS/WT PRD FD
 PERCENT EXCESS AIR





OP
OND

D

OND
VOL
AS
DRY
DRY
DRY
DRY
K GAS
S
RE

OLUTE
ITY
TD CN
TE

IAL
L

CN
CN
CN @
CN @
CN
CN


PTL
TTL
UNITS .

FT2
MIN
IN.HG
IN.H20
DCF
DEG.F
DSCF
ML
SCF








DEG.F

IN.HG
FPS
DSCFM
ACFM

MG
MG

GR/DSCF
GR/DSCF
12? C02
12% C02
GR/ACF
GR/ACF
LB/HR
LB/HR
LB/TON
LB/TON
10
09-13-73
27.688
36.0
29.31*
1.200
23.10
78.1
22.37.
31.2
1 . I* 8
6.2
0.938
0.0
21.0
0.0
79.0
28. 8U
28.17
21*8.0
1
29.21*
83.800
95509.
139211*.
99.7
0.2U
0.21*
0.0
0.00016
0.00016
AVERAGE





















83.800
95509.
1392U.
99.7
0.21*
0.2t*
0.0
0.00016
0.00016
******************
******************
0.00011
0.00011
0.13
0.13
0.00098
0.00098
0.00011
0.00011
0.13
0.13
0.00098
0.00098
******************
                                 21

-------
PLANT:  .RESERVE MINING COMPANY; SILVER BAY, MINNESOTA
LOCATION:  FINE CRUSHER STACK 110, AMPHIBOLE ASBESTOS EMISSIONS
OPERATOR;  ENVIRONMENTAL PROTECTION AGENCY
       PART ICULATE SUMMARY  IN  ENGLISH  UNITS
   DESCRIPTION

 DATE OF RUN

 STACK AREA
 NET TIME OF RUN
 BAROMETRIC PRESSURE
 AVG ORIFICE PRES DROP
 VOL DRY GAS-METER COND
 AVG GAS METER TEMP
 VOL DRY GAS-STD COND
 TOTAL H20 COLLECTED
 VOL H20 VAPOR-STD COND
 PERCENT MOISTURE BY VOL
 MOLE FRACTION DRY GAS
 PERCENT C02 BY VOL, DRY
 PERCENT 02 BY VOL, DRY
 PERCENT CO BY VOL, DRY
 PERCENT N2 BY VOL, DRY
 MOLECULAR WT-DRY STK GAS
 MOLECULAR WT-STK GAS
 AVG STACK TEMPERATURE
 NET SAMPLING POINTS
 STACK PRESSURE, ABSOLUTE
 AVG STACK GAS VELOCITY
 STK FLOWRATE, DRY,STD CN
 ACTUAL STACK FLOWRATE
 PERCENT ISOKINETIC
 •PART I CU LATE WT-PARTIAL
 PART ICULATE WT-TOTAL
 PERC IMPINGER CATCH
 PART.  LOAD-PTL,STD CN
 PART.  LOAD-TTL/STD CN
 PART.  LOAD-PTL,STD CN @
 PART.  LOAD-TTL,STD CN @
 PART.  LOAD-PTL,STK CN
 PART.  LOAD-TTL,STK CN
 PART 1C EMIS-PARTIAL
 PART 1C EMIS-TOTAL
 PART EMIS/WT PRO FD PTL
 PART 'EMIS/WT PRO FD. TTL
 PERCENT EXCESS AIR
UN 1 TS

FT2
MIN '
IN.HG
IN.H20
DCF
DEG.F
DSCF
ML ._..
SCF






.

DEG.F

: IN.HG
FPS
i DSCFM
ACFM

MG
MG

GR/DSCF
GR/DSCF
12% C02
12% C02
GR/ACF
GR/ACF
LB/HR
LB/HR
LB/TON
LB/.TON
3.
9-11-73
3.976
120.0
29.10
1.760
93.70
	 8U.6
89.06
19.2
0.91
"" 1.0
0.990
0.0
21.0
0.0
79.0
" 28.8U
28.73
60.7
1
29.10
71. 2U
1.66UI4.
16989.
98.1
1.65
1.65
0.1
0.00029
0.00029
*********
*********
0.00028
0.00028
O.OU
0.01*
0.00009
0.00009
AVERAGE. .

• .
... ...... . . .. . . - . ....
•


._. .. . _. . . -.-













	
71.2lk
166^4. ' .
16989.
98.1
1.65
1.65 	
0.1
0.00029
0.00029
*********
*********
0.00028
0.00028
o.ou 	
0.01*
0.00009 	 —
0.00009
******************
                                      00
                                      LA i-

-------

PLANT:   RESERVE MINING CO.,  SILVER BAY,  MINN.
LOCATION:   WASTE GAS STACK,  PELLETIZER NO. 5, AMPHIBOLE EMISSIONS
OPERATOR:
           ENVIORNMENTAL PROTECTION AGENCY
       PART ICULATE SUMMARY  IN  ENGLISH  UNITS
   DESCRIPTION    •    .

 DATE OF RUN

 STACK AREA
 NET TIME OF RUN
 BAROMETRIC PRESSURE
 AVG ORIFICE PRES DROP   !
 VOL DRY GAS-METER COND
 AVG GAS METER TEMP
 VOL DRY GAS-STD COND
 TOTAL H20 COLLECTED
 VOL H20 VAPOR-STD COND
 PERCENT MOISTURE BY VOL
 MOLE FRACTION DRY GAS
 PERCENT C02 BY VOL, DRY
 PERCENT 02 BY VOL,  DRY
 PERCENT CO BY VOL,  DRY
 PERCENT N2 BY VOL,  DRY
 MOLECULAR WT-DRY STK GAS
 MOLECULAR WT-STK GAS
 AVG STACK TEMPERATURE
 NET SAMPLING POINTS
 STACK PRESSURE, ABSOLUTE
 AVG STACK GAS VELOCITY
 STK FLOWRATE, DRY,STD CN
 ACTUAL STACK FLOWRATE
 PERCENT ISOKINETIC
 PARTICULATE WT-PARTIAL
 PART ICULATE WT-TOTAL
 PERC IMPINGER CATCH
 PART.  LOAD-PTL,STD CN
 PART.  LOAD-TTL,STD CN
 PART.  LOAD-PTL,STD CN @
 PART.  LOAD-TTL,STD CN @
 PART.  LOAD-PTL,STK CN
 PART.  LOAD-TTL,STK CN
 PART 1C EM IS-PARTIAL
                          UNITS
                            FT2
                            MIN
                          I N. HG
                          N.H20
                            DCF
                          DEG.F
                           DSCF
                             ML
                            SCF
 PARISC EM!S-TOTAL
 PART EMIS/WT PRO FD PTL
 PART EMIS/WT PRO FD TTL
 PERCENT EXCESS AIR
  DEG.F

  I N. HG
    FPS
  DSCFM
   ACFM

     MG
     MG

GR/DSCF
GR/DSCF
12% C02
12% C02
 GR/ACF
 GR/ACF
  LB/HR
  L5/HP.
 LB/TON
 LB/TON
6
09-12-73
27.882
37.0
29.28
1.850
29.90
73.2
29.21
53.8
2.55
8.0
0.920
0.8
20.0
0.0
79.2
28.93
28.05
356.8
1
29.14
118.936
115621.
198972.
105.4
0.64
0.64
0.0
0.00034
0.00034
0.00510
0.00510
0.00020
0.00020
0.34
0.34
0.00278
0.00278
2200.7
AVERAGE





















118.936
115621.
193972.
105.4
0.64
0.64
0.0
0.00034
0.00034
0.00510
0.00510
0.00020
0.00020
0.34
n . 311
0.00278
0.00278
2200.7
                             23

-------
                   TABLE 18
PLANT:   RESERVE MINING CO., SILVER BAY, MINN.
LOCATION;   HOOD VENT STACK,PELLETiZER NO. 5, AMPHIBOLE
OPERATOR:   ENVIORNMENTAL PROTECTION AGENCY
                                                EMISSIONS
PART ICULATE SUMMARY  IN  ENGLISH  UNITS
   DESCRIPTION            UNITS

 DATE OF RUN

 STACK AREA                 FT2
 NET TIME OF RUN            MIN
 BAROMETRIC PRESSURE      IN.HG
 AVG ORIFICE PRES DROP   IN.H20
 VOL DRY GAS-METER COND     DCF
 AVG GAS METER TEMP       DEG.F
 VOL DRY GAS-STD COND      DSCF
 TOTAL H20 COLLECTED         ML
 VOL H20 VAPOR-STD COND  .   SCF
 PERCENT MOISTURE BY VOL
 MOLE FRACTION DRY GAS
 PERCENT C02 BY VOL, DRY
 PERCENT 02 BY VOL, DRY
 PERCENT CO BY VOL, DRY
 PERCENT N2 BY VOL, DRY   •«• ;-• •: "
 MOLECULAR WT-DRY STK GAS
 MOLECULAR WT-STK-GAS
 AVG STACK TEMPERATURE
 NET SAMPLING POINTS
 STACK PRESSURE, ABS
 AVG STACK GAS VELOCITY
 STK FLOWRATE, DRY,STD
 ACTUAL STACK FLOWRATE
 PERCENT ISOKINETIC
 PARTICULATE WT-PARTIAL
 PARTICULATE WT-TOTAL
 PERC IMPINGER CATCH
 PART. LOAD-PTL,STD C
 PART. LOAD-TTL,STD C
 PART. LOAD-PTL,STD C
 PART. LOAD-TTL,STD C
 PART. LOAD-PTL,STK C
 PART. LOAD-TTL,STK C
 PART 1C EM IS-PARTIAL
 PART 1C EMIS-TOTAL
 PART EMIS/WT PRO -FD
 PART EMIS/WT PRO FD
 PERCENT EXCESS AIR
                                 10

                             09-13-73

                               27.688
                                 36.0
                                29.34
                                1.200
                                23.10
                                 78.1
                                22.37
                                 31.2
                                 1.48
                                  6.2
                                0.938
                                  0.0
                                 21.0
                                  0.0
AVERAGE

IE DEG.F

ILUTE IN.HG
TY FPS
'D CN DSCFM
'E ACFM

AL MG
MG

:N GR/DSCF
!N GR/DSCF -
:N @ 12% C02
IN @ 12% C02
IN GR/ACF
IN 'GR/ACF
LB/HR
LB/HR
PTL IB/TON
TTL LB/TON
28.17
248.0
1
29.24
83.800
95509.
139214.
99.7
0.24
0.24
0.0
0.00016
--XL-OOP 16




83.800
95509.
139214.
99.7
0.24
0.24
0.0
0.00016
0.00016
******************
******************
0.00011
0.00011
0.13
0.13
0.00098
0.00098
0.00011
0.00011
0.13
0.13
0.00098
0.00098
                             ******************
                            24

-------
       SUMMARY AND DISCUSSION OF PROCESS SAMPLE ANALYSIS

     Process samples were obtained at two locations on the same
days that the stacks at these respective facilities were tested.

     Samples of the output from this crusher group were collected at
the discharge of the conveyor in the concentrator building on September  11,
1973.  It was not possible to sample the output from an individual
crusher set.  Samples were taken using the established plant sampling
technique.  A sampling pan, about 1 1/2" wide x 12" long, x 12" deep,
was inserted in the belt discharge stream at the middle and both sides.
Duplicate samples were taken, one for EPA and one retained by the company.
Samples were taken every hour on the hour from 8:00 a.m. to 3:00 p.m.

     Samples of the green.p.el.lets were taken on September 12, 1974, from
                        *-':\.. '•  '• 2:'*.*'"."":'™ - .'Jr. . .•:
the three conveyor belts wbJch, discharge .to the conveyor which feeds this
pelletizer.  Samples were taken every hour on the hour from 10:00 a.m. to
5:00 p.m. inclusive.  Duplicate samples were taken for EPA and the company.

     A report of the analysis of these samples has been prepared separately
and is entitled "Sample Process Material at Taconite Plant" final report
Task 22, Contract No. 68-02-0230, by R. J. Kuryvial and C. W. Metton,
February 1974.  This report is%v#s8&Me"Tfrom the Office of Technical
Analysis, EPA.
                                  or:

-------
                              PROCESS DESCRIPTION

     A  schematic  flow diagram of the process  is attached  (Figure  III-l).
The ore is received  in  railroad cars from  the mine where  it has been
crushed to minus  4-inch size.  The ore  is  crushed to minus 3/4-inch
size by cone  type  crushers.  It is then ground wet in  rod mills and
ball mills and separated  by magnetic separators into concentrate  and
tailings.  The tailings ar,e pumped into Lake  Superior.  The concentrate
is mixed with a small amount of bentonite  clay and introduced  into large
rotating drums which roll  it into balls of about 1/2"  diameter.   The
balls are fed into a traveling grate pelletizing machine where they are
first dried,  then  heated  to over 2200°F, passed through an oxidizing
-section, then a cooling section.  This  transforms them into hard  pellets,
ideally suited for blast  f ;Y^££,;£eec!,
     The raw  ore  is  about 24 ;percent iron  and the'concentrate  if  65 percent
iron.   The asbestos  type  mineral in the ore is said to be amosite and  said
to range from 20  to  30  percent in content.
     Detailed descriptions of the operations  and controls are  given in
the following sections.
a.  Car Dumping and  Fine  Crushing
     The ore  is received  frora .the.uiifie..in  railroad ore cars.   It  has been
crushed at the mine  to minus 4-inch size.  A  rotary car dumper lifts two
cars at a time and dumps  their contents into  two receiving pits.  Water
sprays  are actuated when  cars are being dumped to suppress dust emissions.
The pits are  each  ventilated by a fan of 50,000 cfm capacity which is  vented
to a multiple cyclone collector (multiclone).

-------
     From the dump pits the-ore is fed to a belt conveyor, and  transported
to storage bins in the fine crusher building.   From the storage bins,  a
system of belt conveyors delivers the ore to ten sets  of crushers  in
parallel.  Each set.consists  of two cone type-crushers, in series,'with a
vibrating screen between the  crushers.  The ore is crushed to minus  3/4-inch
size.
     The conveyor belt transfer points are controlled  by ten multiclones,
each with its own stack.  Each of the ten sets of crushers,  with its
screens, is controlled by a Type W Rotoclone.
     The crushers discharge to two belt conveyors which deliver the
crushed ore to two transfer bins in the concentrator building.   These  bins
transfer the ore to two conveyors which discharge to 22 storage bins,  each
of which feeds a rod mill.   The transfer points in this system  are vented
by 24 multiclones, each with  its own stack.  Water is  added  at  the rod mills
and all the subsequent grinding, magnetic separation and regrinding  is done
in slurry form.
b.  The Palletizing Furnaces
     There are eight furnaces which bake the moist iron oxide balls  from
the balling drums, turning  them into hard FepCU (hematite) pellets,  suitable
for blast furnace feed.  Furnaces 1 - 6 operate at about 135 wet tons/hr.
Furnaces 11 and 12 are larger and operate at about 290 wet tons/hr.  The
amount of bentonite additive  in the moist balls is very small,  only  in the
range of 18 - 27 Ibs/hr.
     The moist load disappears into the totally enclosed furnace where it
first contacts about 90,000 scfm of hot combustion gases recirculated
                                           27

-------
from the ignition section.  This gas passes upward through the ball  bed and
exits from the "hood stack"'at about 225°F.  The balls are thus gently
dried, then they move into an ignition section.  Here, several oil burners
force combustion gases downward through the bed and maintain a temperature
of about 2350°F on top of the bed.  The hot air from this operation plus
part of the drying hot air is discharged at about 400 - 500°F through the
waste gas stack and amounts to about 110,000'scfm.  A following section is
called the "induration section," where no oil is burned, but where an
exothermic reaction with oxygen of the air occurs and heats all the bed to
                                           1*  .
a yellow heat.  This is due to oxidation of ferrous iron at the bed tempera-
ture.
          4 (Fe 0. Fe203) + 02 -*•  6 Fe2 03
             magnetite            hematite
Other forms of ferrous iron are also oxidized.  Air passes downward through
the bed.  The exhaust from these sections is reused  in the drying and
ignition sections.
     The final operation is cooling of the pellet bed.  Air goes downward
and is partly reused for drying and partly discharged from the second
stage cooling stack at about 20,000 scfm.
     The plant produces ten million tons/yr of pellets.  The gas emission
from all eight pelleting furnaces is 1,900,000 scfm.  There are no
emission controls.  There are six stacks per furnace on the roof of the
pelletizing furnace building.  They are, in order:  hood exhaust; waste
gas; recuperation (capped); 1st stage cooler; 2nd stage cooler; pellet
dump end.
                                       9 P

-------
                          PROCESS OPERATION DURING TEST

a.  Fine Crusher Test.  9-11-73
     The ten sets of crushers are-divided into two groups.   Each group
discharges to a belt conveyor which delivers the crushed ore to the
concentrator building.  Each crusher set consists of the following items
in series:  a vibrating screen, a primary cone crusher, a vibrating
screen, a secondary cone crusher.  Each of these four devices is enclosed
and all vented to a Type W Rotoclone, size 30.
     The crusher set tested was no. 104.  The dust collector .was no.  110.
The feed rate to the crusher was measured and recorded on a circular
chart.  The readings fluctuated considerably.  An eye-ball  average was
made of the chart traces for the following periods, in tons per hour:
          11:00 - 11:00 :  550              3:00 - 4:00 : 500
          11:00 - 12:00 :  500              4:00 - 5:00 : 450
           1:00 -  2:00 :  600              5:00 - 6:00 : 450
           2:00 -  3:00 :  550
     Opacity readings of the collector stack were read at various times.
Readings were made with the sun at my back.  Readings were recorded at
the following times:
          10:00 : 15%                      4:00 : 10%
          10:30 : 15%                      4:30 : 10%
           1:30 : 10%                      5:00 : 10%
           2:30 : 10%                      5:30 : 10%
           3:30 : 10%
      When  the  plume was observed  looking  towards  the sun,  the opacity
appeared  to  be  very much greater.

-------
b.  Pelletizing Furnace Stack Test.  9-12-73


     The flue gas (waste gas) stack was sampled on September  12,  1973.


The unit tested was pelletizer no. 5.  This unit and two others had  been


modified by the addition of ,a. roll screen to remove fines from the green


pellet feed in an effort to reduce emissions.


     The pelletizer operator recorded the average feed  rate each  hour.


The following readings, in tons per hour, were taken from his log sheet:


           9:00 - 10:00 : 137           2:00 - 3:00 : 115


          10:00 - 11:00 : 137           3:00 - 4:00 : 121


          11:00 - 12:00 : 135           4:00 - 5:00 : 121


          12:00 -  1:00 : 132           5:00 - 6:00 : 131

           1:00 -  2:00 : 120           6:00 - 7:00 : 136


     Opacity readings were taken at various times from  the roof,  with  the.
                          ."if '       *      •   -. --  X*/ -.."

sun to the observer's back.  It was noted that the position of the sun


made little difference in thc.^:7;r.^;-.#te?-a<:-7.:-:«ts4l:;-the plume.  The weather  was


clear and cool with a breeze estimated as 15 MPH.  The  following  opacities

were recorded:


          10:30 : 15%                   5:10 : 5%


          11:15 : 15%                   6:15 : 5%


          11:30 : 10%'                   6:30 : 5%


           3:15 : 10%               	7:00 : 5%


           3:45 : 10%
                                           30

-------
c.  Dryer (hood) Stack Test.-  9-13-73
     The pellet feed rates in tons  per hour from  the  operator's  log  sheet
were as follows:
          6:00 - 7:00 :  134      .   11:00 - 12:00  :  13.3  •  ...   '.
          7:00 - 8:00 :  136        .  12:00 -  1:00  :  137
          8:00 -.9:00 :  132           1:00 -  2:00  :  138
          9:00 -10:00 :  136           2:00 -  3:00  :  137
         10:00 -11:00 :  134
     Visible emissions from the stack were very light.  The weather  was
clear and cool with a brisk wind.   The following  opacity  readings were
recorded:
         10:00 a.m.
         10:15
         10:30
         10:40
         10:50
         11:00
         11:15
         12:10 p.m.
         12:30
         12:40
     Visible emissions from the stacks of the other pelletizers  were
casually observed, but not recorded.   Nearly all  the  other pelletizers
had emissions of greater opacity than the one being tested.   Several
had emissions which were in the range of 15-30% opacity most  of  the  time,
with occasional periods  of much higher rates — up  to 100%  opacity for a
few minutes, several times' a day.
                                        31
5%
0
5%
5%
0
0
5%
5%
5%
5%
12:50 p.m.
2:00
2:15
2:30
2:45
2:50
2:53
2:55
3:00

: 5%
: 5%
: 0
: 0
: 0
:10%
:15%
: 0
: 0

-------
d.   Concentrator Stack Test.   9-13-/3
     Collector system no.  118 in the East Concentrator Building was
tested in the late afternoon  of September 13, 1973.   No ore samples
were collected, and no material flow rates were available.   However,
the average discharge rate of each bin is about 160 tons/hr.  based on
an average of 85,000 tons/day of ore received at the plant.
     No visible emissions  were observed from the stack being tested,
nor from any of the other  21  stacks in, the two concentrator buildings.
The ore appeared to be damp and no visible dust was  observed when the
tripper was filling a bin.

-------
                  LOCATION OF SAMPLING POINTS

1.   Fine Crusher No.  10
     Sampling was conducted downstream of the Rotoclone serving
the number 104 fine crusher set, on s-tack No. 110..  . The ports-were  . .  .  .
located 127" (4.7 diameters) downstream of the nearest disturbance' and
24" (0.89 diameters)  upstream of the exit to the atmosphere.   The 27"
diameter crossection  was divided into 16 equal  areas and sampling
was to be conducted at the centroid of each area.   However,  since the
outmost points on each diameter were less than 1 inch from the stack wall,
sampling was not conducted at point 1 and 8 on each diameter.   Method 1
(Federal Register, Vol. 36, No. 247, December 23,  1971) requires  36
sampling points for a location such as was available here; however, only
a 12-point traverse was used.  Because of the relatively small stack
diameter, the reduction of traverse points should  not effect the  represen-
tativeness of the sample.

2.   Haste Gas Stream, Pelletizer No. 5
     Sampling was conducted on the uncontrolled waste gas stream  at a
location approximately 75' (~12 diameters) downstream of the nearest
disturbance and 50' (~8 diameters) upstream of the  exit to the atmosphere.
The 71 1/2-inch diameter stack was divided into 12  equal areas and
sampling was conducted at the centroid of each equal area.

3.   Hood Vent Exhaust, Pelletizer No. 5
     Sampling was conducted on the uncontrolled stack serving  the hood
vent stream at a location approximately 48' (8.1 diameters)  downstream  of
the nearest disturbance and 40' (6.8 diameters) upstream of  the exit to
                                      33

-------
the atmosphere.  The 71 1/4" diameter cross-section was divided into
12 equal areas and sampling was conducted .at the centroid of each equal
area.

4.  Concentrator Location-..     •• •   •  .    -..'.•'    .-.••••••
     Sampling was conducted on the control system No. 118 serving the
No. 11 and 12 bins and their'conveying systems.  The sampling ports were
located 32' (9.8 diameters) downstream of the nearest disturbance and
26' (7.8 diameters) upstream of the exit to the atmosphere.  The 39 3/4"
diameter cross-section was divided into 12 equal areas and sampling
was conducted at the centroid of each'equal area.
                                         Vi
                                         U '•ji

-------
              SAMPLING AND ANALYTICAL PROCEDURES

     The procedures used to collect the samples were essentially
identical to those outlined in Method 5 (Federal Register,  December
23, 1971) with the .following exceptions:   .       ...    ....
     1.  A Mi Hi pore type AA membrance filter was substituted for the
MSA 1196 BH glass fiber filter.
     2.  Filter and probe heating was not maintained at 225°F since
maximum temperature allowable for the membrane filter is ~200°F.
This temperature was maintained  at 150-180°F, which  was above the
dew point of all 'streams sampled.
     3.  No acetone washings were used in the train  cleanup.   The probe
was washed with water only and was kept separate from the impinger
contents and wash.
At the fine crusher location* sampling was conducted for five minutes
at each of 12 traverse points for a total test time  of 60 minutes.  At
the waste gas and- hood vent locations, sampling was  conducted for three
minutes at each of 12 traverse points for a total run time  of 36 minutes
for each test.  At the concentrator location, sampling was  conducted for
ten minutes at each of 12 traverse points for a total test  time of
120 minutes.

     Prior to each run, the sampling train was leak-checked and any
leakage was corrected prior to the start of testing.  After sampling the
train was sealed and moved to the cleanup area intact.  There it was
disassembled and the filter was  placed in a glassene envelop and sealed.
                                        35

-------
     The probe and front half of the filter holder were washed
with distilled, deionized water and placed in a glass shipping bottle.
The back half of the filter and the remainder of the impinger train
were rinsed with water and added to the impinger contents  in a separate
shipping bottle.  These containers were sealed and packed  for shipment.

     Upon return to the EPA laboratories in Durham, the filters were
weighed and the samples were separated for shipment to .several laboratories
for analysis.  Runs 3, 6, and 10 were sent to Battelle Columbus for
asbestos identification and analysis by electron microscope.  The complete
analysis procedure is given in Appendix C in Battelle's laboratory report,

-------
                    APPENDIX A



COMPLETE CALCULATION RESULTS AND SAMPLE CALCULATIONS

-------
                         . TABLE A-l '

PLANT:  RESERVE MINING FINE CRUSHER STACK DO.10
LOCATION:  SILVER RAY MINN.

OPERATOR:  EPA
                   SUMMARY  IN  ENGLISH  UNITS
   DESCRIPTION            UNITS

 DATE OF RUM

 STACK AREA                 FT2
 NET TIME OF RUN            MIN
 BAROMETRIC PRESSURE      IN.HG
 AVG ORIFICE PRES DROP   IM.H20
 VOL DRY GAS-METER COND     DCF
 AVG GAS METER TEMP       DEG.F
 VOL DRY.GAS-STD COND      DSCF
 TOTAL H20 COLLECTED         ML
 VOL H20 VAPOR-STD COND     SCF
 PERCENT MOISTURE BY VOL"  "
 MOLE FRACTION DRY GAS .
 PERCENT C02 BY'VOL, DRY
 PERCENT 02 BY VOL, DRY
 -PERCENT CO BY VOL, DRY
 PERCENT M2 BY VOL, DRY
 .MOLECULAR VJT-DRY STK GAS
 MOLECULAR V/T-STK GAS
 AVG STACK TEMPERATURE     DEG.F
 MET .SAMPLING POINTS
 STACK PRESSURE,  ABSOLUTE  IN.HG
 AVG STACK GAS VELOCITY      FPS
 STK FLOWRATE, DRY,STD CN  DSCFM.
 ACTUAL STACK FLOWRATE      ACFM
 PERCENT ISOKINETIC
1
9-11-73
3.976
60.0
29.08
1.800
1*6.70
76.2
1*5.06
13.1
0.62
l.U
0.386
0.0
21.0
0.0
79.0
28. 81*
28.69
67.6
29.08
72.M7
1663U.
17276.
,99. l*
2
9-11-73
3.976
120.0
29.08
1.790
94.90
79.1
91.07
21.3
1.01
1.1
0.989
0.0
21.0
0.0
79.0
28. 8U
28.72
62.0
29.08
71.90U
16738.
17153.
99.8
3
9-11-73
3.976
120.0
29.10
1.760
93.70
8U. 6
89.06
19.2
0.91
1.0
0.990
0.0
21.0
0.0
79.0
28.81*
28.73
60.7
29.10
71.211*
16GUI*.
1G989.
98.1

-------
                          TABLE A-2

PLANT:  RESERVE MINING FINE CRUSHER STACK NO.10
LOCATION:  SILVER BAY MINN.   '   '  .
OPERATOR:  EPA
                    SUMMARY   IN  METRIC  UNITS
 •  DESCRIPTION            UNITS         1

 DATE OF RUN                        9-11-73

 STACK.AREA                   M2       0.369
 NET TIME OF RUN            MIN     .    60.0
 BAROMETRIC PRESSURE       MM.HG      738.63
 AVG ORIFICE PRES PROP    MM.H20      U5.720
 VOL DRY GAS-METER COND      DM3        1.32
 AVG GAS METER TEMP        DEG.C        21*. 6
 VOL DRY GAS-STD COND       DNM3        1.28
 TOTAL H20 COLLECTED          ML        13.1
 VOL H20 VAPOR-STD COND      NM3        0.02
 PERCENT MOISTURE BY VOL    .    .         1.1*
 MOLE FRACTION DRY GAS                 0.986
 PERCENT C02 BY VOL, DRY                 0.0
 PERCENT 02 BY VOL, DRY                 21.0
 PERCENT CO BY VOL/ DRY                  0.0
 PERCENT N2 BY VOL, DRY                 79.0
 MOLECULAR WT-DRY STK GAS              28.81*
 MOLECULAR VIT-STK GAS                  28.69
 AVG STACK TEMPERATURE     DEG.C        19.8
 MET SAMPLING POINTS
 STACK PRESSURE, ABSOLUTE  MM.HG      738.63
 AVG STACK GAS VELOCITY      M/S      22.073
 STK FLOWRATE, DRY,STD CN DNM3/M        1*71.
 ACTUAL STACK FLOV/RATE     AM3/M        1*89.
 PERCENT ISOKINETIC                     99.U
2
9-11-73
0.369
120.0
738.63
1*5.1*66
2.69
26.2
2.58
21.3
0.03
1.1
0.989
0.0
21.0
0.0
79.0
28.8U
28.72
16.7
738.63
21.916
1*71*.
486.
99.8
3
9-11-73
0.369
120.0
739. Ik
1*1*. 701*
2.65
29.2
2.52
19.2
0.03
1.0
0.990
0.0
21.0
0.0
79.0
28.8U
28.73
15.9
739.11*
21.706
1*71.
1*81.
98.1
AVERAGE
 21.898
  ' 1*72.
   1*85.
   99.1

-------
                              •  TABLE A-3

PLANT:  RESERVE MINING WASTE GAS STACK NO.29  (SHORT  RUN  DUE TO MOISTURE  PROBLEM
LOCATION:  SILVER BAY MINN.
OPERATOR:  EPA
                   SUMMARY   IN  ENGLISH  UNITS
   DESCRIPTION            UNITS         U      AVERAGE

 DATE OF RUN         .               9-12-73

 STACK AREA                 FT2       27.882      --.  --
 NET TIME OF RUN            MIN         20.0
 BAROMETRIC PRESSURE      IN.HG        29.28
 AVG ORIFICE; PRES DROP   IN.H20        1.780     -.   —
 VOL DRY GAS-METER COND•    DCF        16.70
 AVG GAS METER TEMP       DEG.F         66.7
 VOL DRY GAS-STD COND      DSCF '       16.51
 TOTAL H20 COLLECTED         ML         30.9
 VOL H20 VAPOR-STD COND   '  SCF         1.U6
 PERCENT MOISTURE BY VOL                 8.1
 MOLE FRACTION DRY GAS                 0.919
 PERCENT C02 BY VOL, DRY                 0.8
 PERCENT 02 BY VOL, DRY                 20.0      ;  •
 PERCENT CO BY VOL, DRY                  0.0
 PERCENT H2 BY VOL, DRY                 79.2   '
 MOLECULAR V.'T-DRY STK GAS              28.93
 MOLECULAR WT-STK GAS  .  -    <          28.0^
 AVG STACK TEMPERATURE     DEG.F       323.0
 MET SAMPLING POINTS
 STACK PRESSURE, ABSOLUTE  IN.HG  -     29:llr
 AVG STACK GAS VELOCITY      FPS     112.761   112.761
 STK FLOK'RATE, DRY,STD CN  DSCFM     111*201+.   11U20U.
 ACTUAL STACK FLOWRATE      ACFM     18861*1.   18861*1.
 PERCENT ISOKINETIC              -      111.6      111,6

-------
                                TABLE A-4

PLANT:  RESERVE MINING HASTE GAS  STACK  NO.29  (SHORT  RUN DUE TO MOISTURE PROBLEM
LOCATION:  SILVER RAY MINN.
OPERATOR:  EPA                                       •            •       .  .
                    SUMMARY   IN  METRIC   UNITS
   DESCRIPTION

 DATE OF RUN

 STACK AREA
 NET TIME OF RUN
 BAROMETRIC PRESSURE
 AVG ORIFICE PRES DROP
 VOL DRY GAS-METER COND
 AVG GAS METER TEMP
 VOL DRY GAS-STD COND.
 TOTAL H20 COLLECTED
 VOL H20 VAPOR-STD COND
 PERCENT MOISTURE BY  VOL
 MOLE FRACTION DRY GAS
 PERCENT C02 BY VOL,  DRY
 PERCENT 02 BY VOL, DRY
 PERCENT CO CY VOL, .DRY
 PERCENT N2 BY VOL,- DRY
 MOLECULAR VJT-DRY STK GAS
 MOLECULAR VHT-STK GAS
 AVG STACK TEMPERATURE
 PET SAMPLING POINTS
 STACK PRESSURE, ABSOLUTE
 AVG STACK GAS VELOCITY
 STK FLOV/RATE, DRY,STD CN
 "CTI'AL STACK FLOV.'PATE
 DERCENT ISOKINETIC
UNITS
AVERAGE
          9-12-73
M2
M 1 N
MM.HG
M.M.H20 .
DM3
DEG.C
DNM3
ML
NM3








DEG.C
MM.HG
M/S
DMM3/M
AM3/M

2.590
20.0
7U3.71
- U5.212
O.U7
19.3
O.U7
30.9
0.0l»
8.1
0.919
0.'8
20.0
0.0
79.2
28.93
28. OU
161.7'
7U0.16
5U.370
32314.
53U2.
lll.G



















3U.370
3234.
53U2.
111.6

-------
                           TABLE A-5

PLAN":   RESERVE f'.INING V?ASTE GAS STACK NO. 29
LOCATION:
OPERATOR;
SILVER
EPA
                  BAY,  MINN.
                   SUMMARY  IN  ENGLISH  UNITS
   DESCRIPTION            UNITS

 DATE OF RUN

 STACK AREA                 FT2
 NET TIME OF RUN            MIN
 BAROMETRIC PRESSURE      IN.HG
 AVG ORIFICE PRES DROP   IN.H20
 VOL DRY GAS-METER COND     DCF
 AVG GAS METER TEMP       DEG.F
 VOL PRY GAS-STD COND      DSCF
 TOTAL H20 COLLECTED         ML
 VOL H20 VAPOR-STD COND     SCF
 PERCENT MOISTURE BY VOL
 MOLE FRACTION DRY GAS
 PERCENT C02 BY VOL, DRY
 PERCENT 02 BY VOL, DRY
 PERCENT CO BY VOL, DRY
 PERCENT N2 BY VOL, DRY
.MOLECULAR V.'T-DRY STK GAS
 MOLECULAR V/T-STK GAS
 AVG STACK TEMPERATURE     DEG.F
 NET SAMPLING POINTS
 STACK PRESSURE, ABSOLUTE  IN.HG
 AVG STACK GAS VELOCITY      FPS
 STK FLOV/RATE, DRY,STD CN  DSCFM
 ACTUAL STACK .FLOWRATE      ACFM
 PERCENT ISOKINETIC
5
9-12-73
27.882
36.0
29.28
1.950
29.00
76.1
28.19
54.6
2.59
8.1*
0.916
0.8
20.0
0.0
79.2
28.93
28.01..
358.6
29.14
118.007
113992.
197417.
106.0
6
9-12-73
< 27.882
37.0
29.28
1.850
29.90
73.2
29.21
53.8
2.55
s;o
0.920
0.8
20.0
0.0
79.2
28.'93
28.05
356.8
29. Ik
118.936
115621.
198972.
105.4
                                                         AVERAGE
                                             9-12-73

                                               27.882
                                                  36.0
                                                29.28
                                                2.070
                                                30.20
                                                  84.7
                                                28.90
                                                  63.4
                                                  3.01
                                                   9.4
                                                0.906
                                                   0.8
                                                  20.0
                                                   0.0
                                                  79.2
                                                28.93
                                                27.90
                                                335.1

                                                29.14
                                               120.024
                                               118051.
                                               200792.
                                                104.9
                                                                    118.989
                                                                    115888.
                                                                    199060.
                                                                      105.5

-------
                          TABLE A-6

PLANT:  RESERVE M I'M I NG 'WASTE GA-S STACK MO.29
LOCATION:  SILVER BAY, MINN.
OPERATOR:  EPA
                    SUMMARY   IN  METRIC  UNITS
  ' DESCRIPTION            UNITS

 DATE OF RUN

 STACK AREA      -             M2
 NET TIME OF RUM            MIN
 BAROMETRIC PRESSURE.       MM.HG
 AVG ORIFICE PRES DROP    MM.H20
 VOL DRY GAS-METER COMD      DM3
 AVG GAS METER TEMP        DEG.C
 VOL DRY GAS-STD COMD       DNM3
 TOTAL H20 COLLECTED          ML
 VOL H20 VAPOR-STD COND      NM3
 PERCENT MOISTURE BY VOL
 MOLE FRACTION DRY GAS
 PERCENT C02 BY VOL, DRY
 PERCENT 02 BY VOL, DRY
 PERCENT CO BY VOL, DRY
 .PERCENT H2 RY VOL, DRY
 MOLECULAR WT-DRY STK GAS
 .MOLECULAR WT-STK GAS
 AVG STACK TEMPERATURE     DEG.C
 MET SAMPLING POINTS
 STACK PRESSURE, ABSOLUTE  MM.HG
 AVG STACK GAS VELOCITY      M/S
 STK FLOWRATE, DRY,STD CN DNM3/M
 ACTUAL STACK FLOV-'RATE     AM3/M
 PERCENT ISOKINETIC
9-12-73   9-12-73
   2.590
    36.0
  743.71
  49.5"30
    0.82
    2k. 5
    0.80
    54.6
    0.07
     8.4
   0.916
     0.8
  '  20.0
     0.0
    79.2
   28.93
   28.01
   181.U


  71*0.16
  35.968
   3228.
   5590.
   106.0
 2.590
  37.0
7143.71
46.990
  0.85
  22.9
  0.83
  53.8
  0.07
   8.0
 0.920
   0.8
  20.0
   0.0
  79.2
 28.93
 28.05
 180.4


71*0.16
36.252
 3274.
 5634.
 105.4
7
9-12-73
2.590
36.0
7U3.71
52.578
0.86
29.5
0.82
63.4
0.09
9.4
0.906
0.8
20.0
0.0
79.2
28.93
27.90
168.4
740.16
36.583
3343.
5686.
104.9
AVERAGE














-


-


36.26
3282
5637
105.

-------
                              TABLE A-7                 '   "

PLANT:  RESERVE MINING PELLETIZER HOOD  EXHAUST  STACK NO.32
LOCATION:  SILVER BAY, -MINN.    -. .       •   *.•    "-v
OPERATOR:  EPA           .            . '   .  .       .
                   SUMMARY   IN   ENGLISH   UNITS
  DESCRIPTION            UNITS

DATE OF RUN

STACK AREA                 FT2
NET TIME OF RUN            MIN
BAROMETRIC PRESSURE      IN.HG
AVG ORIFICE PRES DROP    IN.H20
VOL DRY GAS-METER COND     DCF
AVG GAS METER TEMP       DEG.F
VOL DRY GAS-STD COND      DSCF
TOTAL H20 COLLECTED.        ML
VOL !!20 VAPOR-STD COND     SCF
PERCENT MOISTURE BY VOL
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL, DRY
        02 BY VOL, DRY
        CO BY VOL, DRY
        N2 BY VOL, DRY
          WT-DRY STK GAS
          WT-STK GAS
                                                             10.
                                     9-13-73    9-13-73    9-13-73
                              AVERAGE
 PERCENT
 PERCENT
 PERCENT
 MOLECULAR
 MOLECULAR
 AVG STACK TEMPERATURE     DEG.F
 NET SAMPLING POINTS
 STACK PRESSURE, ABSOLUTE  IN.HG
 AVG STACK GAS VELOCITY      FPS
 STK FLOWRATE, DRY,STD CN  DSCFM
 ACTUAL STACK FLOWRATE      ACFM
 PERCENT ISOKINETIC
 27.688
   36.0
  29.37
  1.250
  23.70
   81.5
  22.81*
   31.2
   1.1*8
    6.1
  0.939
    0.0
   21.0
    0.0
   79.0
  28.81*
  28.18
  237.0

  29.27
 81*.750
 9831*1.
H0792.
   98.9
 27.688
   36.0
  29.31*
  1.260
  23.70
   76.1*
  23.03
   30.9
   1.1*6
    6.0
  0.9UO
    0.0
   21.0
    0.0
   79.0
  28. 8k
  28.19
  239.6

  29.21*
 85.789
 99183.
11*2518.
   98.9
 27.688
   36.0
  29. 31*
  1.200
  23.10
   78.1
  22.37
   31.2
   1.1*8;
    6.2
  0.938
    0.0
   21.0
    0.0
   79.0
  28. 81*
  28.17
  21*8.0

  29.21*
 83.800
 95509.
13921£*.
   99.7
                                                                    81*.780
                                                                    97677.
                                                                   1U0841.
                                                                      99.1

-------
                           TABLE A-8

PLANT:  RESERVE MIMING PELLETIZER HOOD EXHAUST STACK NO.32
LOCATION:  SILVER BAY, MINN.
OPERATOR:  EPA         .   .
                    SUMMARY  IN  METRIC  UNITS
   DESCRIPTION

 DATE OF RUN

 STACK AREA
 NET TIME OF RUN
 BAROMETRIC PRESSURE
 AVG ORIFICE PRES DROP
 VOL DRY GAS-METER COND
 AVG GAS METER TEMP
 VOL DRY GAS-STD COND
 TOTAL H20 COLLECTED
 VOL H20 VAPOR-STD COND
. PERCE?VJT MOISTURE BY VOL
 MOLE FRACTION DRY GAS
 PERCENT C02 BY VOL, DRY
 PERCENT 02 DY VOL, DRY
 PERCENT CO BY VOL, DRY
 PERCENT N2 BY VOL, DRY
 MOLECULAR WT-DRY STK GAS
 MOLECULAR V.T-STK GAS
 AVG STACK TEMPERATURE
 MET SAMPLING POINTS
 STACK PRESSURE, ABSOLUTE
 AVG STACK CAS VELOCITY
 STK FLOWRATE, DP.Y,STD CN
 ACTUAL STACK FLOWRATE
 PERCENT ISOKIMETIC
UNITS
    M2
  MIN
 MM.HG
MM.H20
   DM3
 DEG.C
  DNM3
    ML
   NM3
 DEG.C

 MM.HG
   M/S
DNM3/M
 AM3/M
8
9-13-73
2.572
36. 0
7U6.nO
31.750
0.67
27.5
0.65
31.2
O.Oi*
6,1
0.939
0.0
21.0
0.0
79.0
28.81*
28.18
113.9
7U3. UP
25.832
2785.
3987.
98.9
9
9-13-73
2.572
36.0
7U5.21*
32.004
0.67
21*. 7
0.65
:30.9
O.Oi*
6S0
0.940
0.0
21.0
0.0
79.0
28.81*
28.19
115.3
7U2.70
26.11*9
2809.
U036.
. . 98.9 ,.
10
9-13-73
2.572
36.0
71*5.21*
30.1*80
0.65
25.6
0.63
31.2
o.ot*
6,2
0.938
0.0
21.0
0.0
79.0
28.81*
28.17
120.0
71*2.70
25.51*2
2705.
39U2.
	 99.7
AVERAGE
 25.81*1
  2766.
  3988.
   99.1

-------
                          TABLE A-9

PLANT:  RESERVE MINING CONVEYOR STACK NO.20
LOCATION:  SILVER BAY, MINN.
OPERATOR:  EPA
                   SUMMARY  IN  ENGLISH  UNITS
   DESCRIPTION            UNITS       .  11     AVERAGE

 DATE OF RUN                        9-13-73

 STACK AREA          .       FT2        8.618
 MET TIME OF RUN            MIN        120.0
 BAROMETRIC PRESSURE      IN.HG        29.25
 AVG ORIFICE PRES DROP   IM.H20        2.600
 VOL DRY GAS-METER COND     DCF       112.40
 AVG GAS METER TEMP       DEG.F         63.5
 VOL DRY GAS-STD COND      DSCF       111.95
 TOTAL H20 COLLECTED         ML         12.0
 VOL H20 VAPOR-STD COND     SCF         6.57     . ••
 PERCENT MOISTURE BY VOL       .          0.5     .
 MOLE FRACTION DRY GAS                 0.995
 PERCENT CO2 BY VOL, DRY                 OtO
 PERCENT 02 BY VOL, DRY                 21.0
 PERCENT CO BY VOL, DRY                  0.0   .
 PERCENT M2 BY VOL, DRY                 79.0
 MOLECULAR WT-DRY STK GAS              28.84
 MOLECULAR WT-STK GAS                .28.79
 AVG STACK TEMPERATURE     DEG.F        74.7    	
 NET SAMPLING POINTS                              . .
 STACK PRESSURE, ABSOLUTE  IN.HG       29.21
 AVG STACK GAS VELOCITY      FPS      52.119     52.119
 STK FLOWRATE,, DRY,STD CN  DSCFM      25940.     25940.
 ACTUAL STACK FLOV/RATE      ACFM      26949.     26949.
 PERCENT ISOKINETIC   .       .          102.9      102.9

-------
                          TABLE A-'lp'        '

PLANT::  RESERVE MINING CONVEYOR STACK MO. 20
LOCATION:   SILVER BAY, MINN.
OPERATOR:   EPA
                    SUMMARY  IN  METRIC  UNITS
   DESCRIPTION

 DATE OF RUN

 STACK AREA
 MET TIME OF RUN
 BAROMETRIC PRESSURE
 AVG ORIFICE PRES DROP
 VOL DRY GAS-METFR COND
 AVG GAS METER TEMP
 VOL'DRY GAS-STD COND
 TOTAL H20 COLLECTED
 VOL H20 VAPOR-STD COND
 PERCENT MOISTURE BY VOL
 MOLE FRACTION DRY GAS
 PERCENT C02 BY VOL, DRY
 PERCENT 02 BY VOL, DRY
 PERCENT CO BY VOL, DRY
 PERCENT N2 BY VOL, DRY
 MOLECULAR NT-DRY STK GAS
 MOLECULAR VIT-STK GAS
 AVG STACK TEMPERATURE
 NET SAMPLING POINTS
 STACK PRESSURE, ABSOLUTE
 AVG STACK GAS VELOCITY
 STK FLOWRATE, DRY,STD CM
 ACTUAL STACK FLOWRATE
 PERCENT ISOKINETIC
UNITS
AVERAGE
          9-13-73
. M2
MIN
MM.HG
MM. H 2.0
DM3
DEG.C
DNM3
ML
NM3








DEG.C
MM.HG
M/S
DNM3/M
AM3/M

0.801
120.0
7U2.95
c e ./»«,.«
D O *•>•&<*. jj -•'•
3=18
17:, 5
3.17
12.0
0.02
0.5
0.995
0.0
21.0
0.0
79.0
28. 81*
28.79
23.7
7U1.93
15.886
735.
763.
102.9



















15.886
735.
763.
102.9

-------
               APPBID1X A.  SAMPLE CALCULATIOIIS





Nomenclature



P.       Barometric Pressure, niin. Hg.



P       Average Orifice Pressure Drop, mm. H?0



T       Average.Dry Gas Meter Temperature, °C



V       Volume of Dry Gas Sampled at Meter Conditions, Am




 m .^   Volume of Dry Gas Sampled at Standard Conditions   , Nm



V       Total hUO Collected in  Impingers and Silica Gel, ml




 v; ,  ,   Volume of Water Vapor Collected at Standard Conditions^  , Nm



%M      Percent Moisture in Stack -Gas, by Volume



M,      Hole Fraction Dry Stack Gas



%C^2    Percent C0? by volume, dry



%0p     Percent 0? by volume, dry



%CQ     Percent CO by volume, dry



%Mp     Percent N? by volume, dry



MW,     Molecular Weight of Dry Stack Gas, gm/gm-mole



MW      Molecular Weight of Wet Stack Gas, gm/gm-mole



C     '  Pitot Tube Coefficient



P     •  Stack Gas Pressure, mm. Hg., absolute



T       Stack Gas Temperature,  °C
 D


T       Average Stack Gas Temperature, °C



AP      Velocity head, mm. I-LO
  ^                         C.


V.      Average Stack Gas Velocity, Stack Conditions, Ain/s


                     r>

A      -Stack Area, in'


                                                   (1}        3
Q.      Stack Gas Flov; Rate at  Standard Conditions    , dry Nm /min

-------
Q       Stack Gas Flov/ Rate at Stack Conditions, Anf/nnn
 a
T.      Net Time of Test, min.
  L
D       Sampling Nozzle Diameter, rnm.
 ti
%l      Percent Isokinetic
inf      Particulate Collected i'n Probe, cyclone and-filter', mg:
in,.      Total Particulate Collected, mg.
  u
I.      Percent of Particulate Caught in Impingers
C r     Particulate Concentrations at Standard Conditions^  , dry,
 sf                                                    3
        based on probe, cyclone and filter catch, mg/Nm
C .      Particulate Concentration at Standard Conditions^  , dry,
                                   3         •          •  •
        based on total catch, mg/Nm
C f     Particulate Concentration at Stack Conditions, based on
                                              3
        probe, cyclone and filter catch, mg/Am
C       Particulate Concentration at Stack Conditions, based on total
 at                 j
        catch, nig/Am
Ef      Particulate Emission Rate, based on probe, cyclone and filter
        catch, kg/hr
E.       Particulate Emission Rate, based on total participate catch, kg/hr
P       Unit Process Rate,  Crusher feed rate or Green pellet feed rate,	
      .    Mton/hr.	
PEf     Particulate Emission Rate on a Process Basis, probe,-cyclone
      •  and filter catch, kg/_Mtqn	
PE.     Particulate Emission Rate on a Process Basis, total catch
        kg/ Mton	
%EA     Percent Excess Air in Stack Gas

-------
                          Kun Nu. d
1.   Volume of Dry Gas Sampled at Standard Conditions^ '
    Vm tH  *  !'3875 ^n^ (Pb + Vl^l  = 0.3875 x  2.65 x(739.1*
      std       • — |T  - 2-^y           ^         (  29.2  1-2731
           = 2. 52 Mm3





2.   Volume of' Water Vapor at Standard Conditions^ '






        Vw     =  0.0012 x V   =  0.0012 x    19.2  =       0.03 Nm3
          gas                w




3.   Percent. Moisture in Stack Gas by Volume




    on.     100 X V

                          =  100 x  0-03      _        1(J

                                 ~           ~        l
-------
7.  Stack Gar, Velocity at Stack Conditions1^
                     y
                     A
                        x 106.35
8.  Stack Gas Volumetric Flow Rate at Standard Conditions^  ,  dry

    n   -  ?V?q* v. x Ac x M, x Pc      23.25 x 21.7 _ x  0.369 x  .99x739.14
                                       '  ~        --
              471   Nin3/min
9.  Stack Gas Volumetric Flow Rate at Stack Conditions

           2.58 x Qs(Ts + 273)    •  2.58 x  471    (  15.9   + 273)
    ya        PS x Md                 739.14  x .99


                481 Am3/min
10.  Percent Isokinetic .

            54,120 x (T  + 273) x V
                x T  x P  x
         =  54,120 x ( 15.9+ 273) x 2.52 __
            'zrrr  x 120. x 739. 14x .99  x        2  =    98.1
11.  Particulate Concentration at Standard Conditions^  , dry,

     based on probe, cyclone and filter -catch


                   !t_  =    26.7' __  =   10.57  mg/Nm3
                              "
                V -    ..     2.52
                 mstd
-------
12.  Particulate Concentration at Standard Conditions^  , dry,
     based on total catch

        Cst  =   mt    =  .	28.48	  = .     11.27 mg/Nm3
                 mstd'    '  '        '   :
13.   Participate Concentration at Stack Conditions, based on probe,
     cyclone, and filter catch
             0.3875 x Csf x Ps x Md
     W        (Ts + 273)                    '   (  15.9  + 273)

               10.35  mg/Ani3

14.   Particulate Concentration at Stack-Conditions, based on total catch
             0.3875 x Csf x Ps x Hd     -0.3875x11-27  x 739.14  x   -99
                 11.04  nig/Am"

15.   Particulate Emission Rate, based on probe, cyclone, and fil.ter catch

     Ef  = 1,000,000 x C f x Qs  =  1,000,000 x 10.57 x 471   ---   0.30  kg/hr

16.   Particulate Emission Rate, based on total catch

     Et  = 1,000,000 x C t x Qs  =  1,000,000 x H-27 x 471   =  0.32  kg/hr

17.   Particulate Emission Rate on a Process Basis, probe, cyclone,
     and filter catch

     PEv  -  _Ef  =	OJK)	=  O.OOQ73 kg/Mton crusher feed •
             "pu   409.5 Mton/hr
-------
18.  Participate Emission Rate on a Process Basis, total  catch


     PE       Et  =   0.032	  =  0.00073 kg/Mton crusher feed
      .*    .  R~  .   ~T69T5.
               U      •:.•••••;       ....'•.    . •    • .   .

19.  Asbestos  emissions calculated  in the same manner as Items 11-18.
(1)  Standard Conditions:  21.1°C, 760 mm.  Hg.
(2)
/~AP>f (Tr  + 273)    is determined by averaging the square root
         s
                          of the product of the velocity head (AP )
                          and the absolute stack temperature
                          (T  + 273) at each sampling point.
                            o
-------
APPENDIX B



Field Data
-------
                       TRAVERSE POINT LOCATION FOR CIRCULAR DUCTS
               p
                 f r f >'-- f
,y,-;,
                    /"/ J1
 PLANT	
 DATE	
 SAMPLING LOCATION       -'-•'   ••
 INSIDE OF FAR WALL TO
   OUTSIDE OF NIPPLE, (DISTANCE A) _
 INSIDE OF NEAR WALL TO
   OUTSIDE OF NIPPLE, (DISTANCE B) _
'STACK I.D., (DISTANCE A - DISTANCE B).
 NEAREST UPSTREAM DISTURBANCE	
 NEAREST DOWNSTREAM DISTURBANCE.
 CALCULATOR	'   •.-.•;.
                                     26
                                        •">  •"*
                                                                                t
                                                                                f  ~N.      J
                                                                                           A
                                                                     SCHEMATIC OF SAMPLING LOCATION
TRAVERSE
POINT
NUMBER
1
7.
^
^
f
d
r,
' P
















FRACTION
OF STACK 1.0.
.6-33

,/Qv
.323
,(,77
t vS 0 v'
<.> cp<-
,4tr
















STACK I.D.
27"
J 7"






















PRODUCT OF
COLUMNS 2 AND 3
(TO NEAREST 1/8 INCH)
, *9f dM.
z,$3
i' ^-y
^, 72-
/§>, ay
2/. 76
23/9
2<^" / ctc&&-


-




4-
•
^"



\
i " i - ii-

o

=^-
~^




rr
j.

•^
^""
i
*.
i

V
j
'. t
V
\~~ \~
\ \
DISTANCE B
r
3"
3"
3"
J"
3"
3"
J"





^
x^









TRAVERSE POINT LOCATION
FROM OUTSIDE OF NIPPLE
(SUM OF COLUMNS 4 & 5)
—
•57fr3 5 ^
-------
                        NOMOGRAPH DATA
 PLANT.



 DATE_
 SAMPLING LOCATION
 '
*v.
,• .•>
CALIBRATED PRESSURE DIFFERENTIAL ACROSS .
ORIFICE, in. H20
AVERAGE METER TEMPERATURE (AMBIENT + 20 °F),°F
PERCENT MOISTURE IN GAS STREAM BY VOLUME
BAROMETRIC PRESSURE AT METER, in. Hg
STATIC PRESSURE IN STACK, in. Hg
(Pm±0.073 i STACK GAUGE PRESSURE in in. H20)
RATIO OF STATIC PRESSURE TO METER PRESSURE
AVERAGE STACK TEMPERATURE, °F
AVERAGE VELOCITY HEAD, in. H20
MAXIMUM VELOCITY HEAD, in. H20
C FACTOR
CALCULATED NOZZLE DIAMETER, in.
ACTUAL NOZZLE DIAMETER, in.
REFERENCE Ap, in. H20
AH@
Tmavg.
Bwo
pm
ps
Ps/Pm
savg.
APavg.
APmax.
/. 72
'6f
*>
>•«.
; ^/.^/
3$or
/
6$
/.^
1.*
0.
-------
                                                           FIELD DATA
t/
/
PLANT K.ts-frt,-e /*///,•/, ,
DATF f-XX-^J- /
PROBE LENGTH AND TYPE •^•/r 1 /* .- / /r»^y


Urpoz<- \ut-T-- SAMPLING LOCATION .'~/,fS /V/.- "',s - S/s . fs

TRAVERSE
POINT
NUMBER
_?
3

.~
f.
7

/.'J
,' /

/ ,V
/'/
./J'










SAMPLE TYP
RUN NUMBEF
OPERATOR
AMBIENT TE
BAROMETRIC
STATIC PRE
FILTERNUM
\. CLOCK TIME
TIME.min ^\
	 	 /£££_
^iJ2-
JT ./.r- '£•
_5 ' £f —
r //? "•—
r- 2a
-j • / O
y . /f> ' ''
—~~~. 	 ^S&JJL
£" j£ *Z-
f . /t> ^
•'-'- . -** ~J
3 ' /& '
. 5- /.-> y^-
jT ,'J a-~
f <£_£-










F /.-••••-.',• ^>
i

(5PERATURE ."-"-"•'
PRFSSIIRF t Q3


NOZZLE I.D
ASSUMED MC
SAMPLE BOJ
METER BOX
METER AH^
C FACTOR
rt. /
S 7. x
ISTURF., ". 2
(NUMBER /
NUMBER /
*f j' '--^.
f? 7*??
PROBE HEATER SETTING
HEATER BOX SETTING

SCHEMATIC OF TRAVERSE P
READ AND RECORD ALL DATA EVERY
GAS METER READING
^ .*/.5
f-SS-/
6- ? ('&>$
& S'J, 7
£ $ •>./, J
+
6 *f- 5"
££t.%
,?£$',<»
t & ,f , f
/<7J'2-
x; 7#-.<5










VELOCITY
HEAD
(ips), in. H20
/3
/.j
/.'/
/.7
/.3-.r
Af

>*- 2
/ 2.
^ 
6?
70
?£>
/fl

~~-








REFERENCE
ES
xi-o
/^T£>
An

DRY GAS METER
TEMPERATURE
INLET
(Tmin),°F
(-£
7^
X"rf>
7f
y?
%&>

75
J>L
f>3
*

-'" . ij
••?,(J • '







OUTLET
<:-2
72.
7-z
72
72.
72.

73 •
7-?

7Y
7S
75-

/ .
:ll-^'~







PUMP
VACUUM,
in.Hg
jT
5~
•2 z.
7
7
7

£>
^
*/\
7

p










'SAMPLE BOX
TEMPERATURE.
°F
/J^P
/*•/
• /s-/
/.rs
S %*-
/7/

y^5'
• /^7
/•/•/
/•*"/
A?/
/^/
*
.









IMPINGER
TEMPERATURE,-
°F
L ^7
_-2.
!'
-------
                                    ANALYTICAL DATA
PLANT.

DATE_
                <- v
          -//-  7 3
SAMPLING .LOCATION

SAMPLE TYPE

RUN NUMBER
SAMPLE BOX NUMBER .

CLEAN-UP MAN_/L
FRONT HALF
         WASH OF NOZZLE, PROBE, CYCLONE (BYPASS),
    FLASK, FRONT HALF OF FILTER HOLDER

  FILTER NUMBER  / c1 8 v c> 
-------
                                                                        FIELD DATA
PLANT
DATE
                                     TI_'<"
                                   °'
PROBE LENGTH AND TYPE.
NOZZLE I.D	Q.
SAMPLING LOCATION yy/v •<•
SAMPLE TYPE       /'•'•-,••'*'
RUN NUMBER	- /^~
Is*-
/a .2^
"^-r-^ — -^r*-
/O *'-*•
ja - 7--
' j/> ?t£
r'0 2~-
> o. T^-
,0 3&










GAS METER READING
(Vm), It3
,<7^-/ '
f ?*'.*/
6 ?2 , 7
7 
"/I "!. 0
7 2 5'. J
,!-
73^. 2
71Q. 7
-;<^, 7
7S'/.3
7f~3,3
77J,0>
— " "
Tt*al ?K9








VELOCITY
HEAD
(Aps), in. H20
/. J
/.3f
/.1f
J.l
/z
J.I

/.2
).!
o.$S
1.0
Z./5-
2.t










ORIFICE PRESSURE
DIFFERENTIAL
(AH), in. H20)
DESIRED
Lf
/,SL
/.&l
2Ji
2.0
/.9

J.f
/.,?r
J.o
3.1*
!.
&/
•&l
(fi^

&l
£1 .
/^ 2-
^/
^7
^ 5-










DRY GAS METER
TEMPERATURE
INLET
(Tmjn),"F
-------
                                   ANALYTICAL DATA
PLANT
HATF
               .< -e r
COMMENTS:
SAMPLING LOCATION.

SAMPLE TYPE _££<

RUN NUMBER	2_
                        T£
SAMPLE BOX NUMBER.

CLEAN-UP MAN.
FRONT HALF
  ASEHJNBWASH OF NOZZLE, PROBE, CYCLONE (BYPASS),
    FLASK, FRONT HALF OF FILTER HOLDER

  FILTER NUMBER   /on 0 O 0 V  	
CONTAINER S-7?'Oov- Jbfa
                                              CONTAINER   -?•
                                                                       LABORATORY RESULTS

                                                                                      mg
                                              FRONT HALF SUBTOTAL
                                                                                     .mg
BACK HALF

  IMPINGER CONTENTS AND WATER WASH OF
    IMPINGERS, CONNECTORS, AND BACK
    HALF OF FILTER HOLDER
MOISTURE
  IMPINGERS
                                              CONTAINER
                                              BACK HALF SUBTOTAL
                                                                                     _mg

                                                                                     .mg

                                                                                     .mg

                                                                                     .mg
                                              TOTAL WEIGHT
                                                                                      mg
FINAI Vni IIMF A C Y
'INITI/U vm IIMF X a a
NETVflLUMF X
SILICA GEL
FINAL WFI^HT V $ %. ?
INITIA' WFIP,HT H 7-J"t\
NFT WEIGHT / .? - 3s
EPA (Dur) 231
4/72
ml
ml.
ml
g 6 E
g 6 E
£ E E;

                                                          TOTAL MOISTURE
-------

FIELD DATA

PLANT /(evtr-c- S//S/(ft*. *
DATE f-//-7J? '
PROBE LENGTH AND TYF
•* •" NOZZLE I.D. £
SAMPLING LOCATION fins (''>'" f !<•'*' $U(L'thf J&V )
SAMPLE TYPF i'" >-/•<•« i** f-
RUN NUMBER 3 • • :

OPERATOR
f 5-r li,t 1 ZL )S - b Fffli'c
'
• AMBIENT TEMPERATURE -7ff

TRAVERSE
POINT
NUMBER
2
3

f
6>
7

ID
//
• n
/3
/>/.
/£










• BAROMETRIC
STATIC PRE
FILTER NUM
^"V CLOCK TIME
- ->-___J_Jt**
/£ 3 '-^
/^> /l£
//5 '/ '•£-
/o ^-i1-^-
to . 4'^.
/a '*"""" ,fs£!

/O $°-

M 5 "^

//) . 5'i2-
/$ 5Z2-


'







PRESSURE 17.10
SURF (P )
RFR(<:) /OOQO 0 5-
SCHEf
READ AND REC
GAS METER READING
(\). It3
775-2 '
7£0> *
•7#7. &

Ro?.(.•/. 3
Q **'sy t £
gyz.*
&±"i.i
%&&.<~f _
^^~~
93. 7








VELOCITY
HEAD
(Aps), in. H20
1.3S
y.3**
./#••>.
IISTIJRF,?; 2.
< NUMBER 3
NUMBER /
A 7Z
0.9?
' PROBE HEATER SETTING
HEATER BOX SETTING
REFERENCE
ATIC OF TRAVERSE POINT LAYOUT
ORD ALL DATA FVFRY /O MINUTES
ORIFICE PRESSURE
DIFFERENTIAL
(AH), in. H20)
DESIRED
J.?
/.$
/ 52
2JT,
2.0%


/.'/
/,/i
O. 72'
2 i ' r A
2j?
1. 35"










ACTUAL
y 5-
j 5-
/.5S-
y.l
2.1


A'/
/-/
o.9 f
1,1

2,3*~










STACK
TEMPERATURE
(TS).°F
&^
Kg
/f>0
£/
&/
r*

J~7

^ i_
^3
^/
63










/fa
/J"iD
An /.t-S'

DRY GAS METER
TEMPERATURE
INLET
(Tmin),°F
£?
90

£>/
9f
?f

f/
8^
Z2>
$i
z%
V*










OUTLET
^-2-
91
7?
g£-
fy /
Q Cr»
p&

85
77
7&
73

•?7










PUMP
VACUUM.
in. H|
7^
r

n
ir


7

51
/O
//
//t



•






SAMPLE BOX
TEMPERATURE,
°F
ysy
/fi>S~
767
/ yy
;S3
jj-g.

-JL3
/ ty^
/ 7 £f
/ £~ &
/5'2.
/SS











IMPINGER
TEMPERATURE.
°F
£3
£2
^S'
£7

6>y

ss-
3
• £i

61
60










COMMENTS: . '
EPA (Our) 235 ' .
4 '72
%
nl
til
13*
-------
                                    ANALYTICAL DATA
PLANT_4

DATE.
               d /-  Y
         ?-//-
SAMPLING LOCATION	£_

SAMPLE TYPE	~l_

RUN NUMBER	-3
SAMPLE BOX NUMBER	

CLEAN-UP MAN..//   T2^.
           <7

FRONT HALF
  4eS=0NE-WASH OF NOZZLE, PROBE, CYCLONE (BYPASS),
    FLASK, FRONT HALF OF FILTER HOLDER

  FILTER NUMBER  / a * t, a c <:T  	
COMMENTS:
                           LABORATORY RESULTS
CONTAINER S-73-QQ*
CONTAINER
                                          mg
                                                FRONT HALF SUBTOTAL
BACK HALF

  IMPINGER CONTENTS AND WATER WASH OF
    IMPINGERS, CONNECTORS, AND BACK
    HALF OF FILTER HOLDER

A-eEfONE-WftSH-efHrflPINGERSr-eONNEGTORS,
CONTAINER
  •EXTRACTION-

CONTAINER
                                               BACK HALF SUBTOTAL
                                                                                         .mg

                                                                                         .mg

                                                                                         .mg

                                                                                         .mg
        WEIGHT
                                                                                          mg
MOISTURE

  IMPINGERS
   FINAL VOLUME JLj_£_ ml
  . fN.ITIAL VOLUME XoO   ml
   NET VOLUME   	SL-.m\

  SILICA GEL
   FINAL WEIGHT    y ft-1 g
   INITIAL WEIGHT _ZZ£LcL g
   NET WEIGHT   	/ '!-'< g

  EPA (Dur) 231
     4/72
g
g
g,
                                                           TOTAL MOISTURE    / 9' -
-------
                                          DRY MOLECULAR WEIGHT DETERMINATION
 PLANT.
 DATE_
             J..P f
                           t ft
COMMENTS:
SAMPLING TIME (24-hr CLOCKS
SAMPLING LOCATION

                                    /

                                         f
                                 S*-rtrl!t#y-
SAMPLE TYPE (BAG, INTEGRATED, CONTINUOUS).
ANALYTICAL METHOD	
AMBIENT TEMPERATURE_
OPERATOR
                               tint &<.
^\^^ RUN
GAS ^^^
C02
02(NET IS ACTUAL 02
READING MINUS ACTUAL
C02 READING)
CO (NET IS ACTUAL CO
READING MINUS ACTUAL
02 READING)
N£ (NET IS 100 MINUS
ACTUAL CO READING)
1
ACTUAL
READING

NET
£>
21. V
0.0
79.0
2
ACTUAL
READING
&.&
^^.£>
21,0
13.0
NET
0
I/. 6
0.0
74.0
3-
ACTUAL
READING




NET




AVERAGE
NET
VOLUME

1



MULTIPLIER
44/100

1
• 32/100
L. J '
a/100
28/100 .
MOLECULAR WEIGHT OF
STACK GAS (DRY BASIS)
Md, Ib/lb-mole




TOTAL
EPA (Our) 230
   4/72
-------
                                                                               l*M^           .3 t» ., „. «
                   TRAVERSE POINT LOCATION FOR CIRCULAR DUCTS
PLANT.
DATE _
                    ;/A.-.
SAMPLING LOCATION	^r$









TRAVERSE POINT LOCATiCl-:
FROM OUTSIDE OF NIPPLE
(SUM OF COLUMNS 4 ft ^
£./
-------
                            PREI IMJNARY VELOCITY TRAVERSE
PI ANT
DATE
                                  -f>_

 LOCATION	
 STACK I.D._.
 BAROMETRIC PRESSURE, in. Hg_
 STACK GAUGE PRESSURE, in. H20.
. OPERATORS       X £-/.,./
                          *  ftifp-t!
                             29.
                                                          SCHEMATIC OF TRAVERSE POINT LAYOUT
TRAVERSE
POINT
NUMBER
/
z
3
¥•
r
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AVERAGE
VELOCITY
HEAD
(Aps), in.H20
3.0.
3J
2.*
2.1
±,1
3,0














• •



2.?
STACK
TEMPERATURE
(Ts), °F
3#5~
3










AVERAGE
VELOCITY
HEAD
(Aps), in.H20












0













STACK
TEMPERATURE
(Ts), °F


















^X







EPA (Dur) 233
   4/72
-------
                        NOMOGRAPH DATA
 PLANT.

 DATE_
 '    f
LLU
 SAMPLING LOCATION
                k
CALIBRATED PRESSURE DIFFERENTIAL ACROSS
ORIFICE, in. H20
AVERAGE METER TEMPERATURE (AMBIENT + 20 °F),°F
PERCENT MOISTURE IN GAS STREAM BY VOLUME
BAROMETRIC PRESSURE AT METER, in. Hg
STATIC PRESSURE IN STACK, in. Hg
(Pm±0.073 x STACK GAUGE PRESSURE in in. H20)
RATIO OF STATIC PRESSURE TO METER PRESSURE
AVERAGE STACK TEMPERATURE, °F
AVERAGE VELOCITY HEAD, in. H20
MAXIMUM VELOCITY HEAD, in. H20
C FACTOR
CALCULATED NOZZLE DIAMETER, in.
ACTUAL NOZZLE DIAMETER, in.
REFERENCE Ap, in. H20
AH@
'Tmavg.
Bwo
pm
PS
Ps/Pm
savg.
*Pavg.
APmax.
/.7L
70
7
19.28*
29JS
$.99
307
2.?
3.1
O'J
o,n
0./9Z
l.tr
EPA (Dur) 234
   4/72
-------
                                                                           FIELD DATA
                                        ' -f'f •
Co
PLANT	£
DATE	
SAMPLING LOCATION.
SAMPLE TYPE	/
RUN NUMBER	,
OPERATOR	t-
               9-/Z-.73
                                                                                                      PROBE LENGTH AND TYPF
                                                  .
                                                 /
AMBIENT TEMPERATURE .
BAROMETRIC PRESSURE    . 2 *?, Zfr
STATIC PRESSURE, (P;)  .    7-t, fJ
FILTER NUMBER (s)     /OOOf)O£,
                                    */**,;
NOZZLE I.D	
ASSUMED MOISTURE, %.
SAMPLE BOX NUMBER.
METER BOX NUMBER _
METER iHg	
C FACTOR	
                                                                                                                         O-
                                                                                                                         S'72.
                                                                                                      PROBE HEATER SETTING.
                                                                                                      HEATER BOX SETTING	
                                                                                                      REFERENCE 4p	
                                                                                                  2.5-
                                                                   SCHEMATIC OF TRAVERSE POINT LAYOUT
                                                            READ AND RECORD ALL DATA EVERY.
                                                                       MINUTES
TRAVERSE
POINT
NUMBER
/
2
3
V
S~
£

7
S
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5 /o*7
~~r~~~ — - — u.^
3 //^
C/,














GAS METER READING
(Vm), ft3
%t>7./
ft trs}sv S37O,














VELOCITY
HEAD
(Aps), in. H20
3.o
s.
66

&7















PUMP
VACUUM,
in. Hg
/^
/^
9
9
/z
^

10















SAMPLE BOX
TEMPERATURE.
°F
'*9
/5-S-
/sp
/&/
Jtf
/$~r

/•*7















IMPINGER
TEMPERATURE,
°F
S~t>
fY
s-y
ss>
ft
J#

4,0















     COMMENTS:

     EPA (Out) 235
-------
                                    ANALYTICAL DATA
PLANT  R G S €

DATE    9  ~ / 2.
                 -  73
SAMPLING LOCATION  iAifi57£   €. fr<*

SAMPLE TYPE

RUN NUMBER
SAMPLE BOX NUMBER

CLEAN-UP MAN	(L
                                               COMMENTS:
FRONT HALF
              OF NOZZLE, PROBE, CYCLONE (BYPASS),
    FLASK, FRONT HALF OF FILTER HOLDER

  FILTER NUMBER
                                                                         LABORATORY RESULTS
                                               CONTAINER 5-?3-i
                                                                                        mg
                                               CONTAINER
                                               FRONT HALF SUBTOTAL
                                                                                       .mg
BACK HALF

  IMPINGER CONTENTS AND WATER WASH OF
    IMPINGERS, CONNECTORS, AND BACK
    HALF OF FILTER HOLDER
                 ^
                                               CONTAINER 5 -73 -to V
                                               CONTAINER
                                               BACK HALF SUBTOTAL
                                                                                       .mg

                                                                                       .mg

                                                                                       .mg

                                                                                       .mg
                                                TOTAL WEIGHT
                                                                                       _mg
MOISTURE

  IMPINGERS
   FINAL VOLUME
   INITIAL VOLUME
   NET VOLUME
                  3  fc
                  O O
                        ml
                        ml
                        ml
  SILICA GEL
   FINAL WEIGHT   V 7 9.?g
   INITIAL WEIGHT  H 7 S~.0l
   NET WEIGHT       V  7 g

  EPA (Dur) 231
     4/72
                                               g
                                               g
                                               g:
                                                          TOTAL MOISTURE
                                                                                       ;   A
-------
FIELD DATA

PLANT /••.r"P}r-r S'S.->* --,-'«• £-:,
DATE -7 /;? ' x*;.' >"'
SAMPLING LOCATION' W-'W -• / /- S? 6 r S-ff,r

TRAVERSE
POINT
NUMBER
7
,f
9
/#
//
/2.

/
1

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6,










SAMPLE TYP
RUN NUMBEF
OPERATOR
AMBIENT TE
BAROMETRIC
STATIC PRE
FILTER NUM
\. CLOCK TIME
~ ~~ 	 2^.
? f ¥
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? ' 2^-
3 2^
3 2**-
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MPERATURE ^' &~f
: PRESSURE :-r,'.~?f
;<;IIRF (P ) •= -*>. /•.*'
RFR(c) / OG0Q& 7
PROBE LENGTH AND TYPE 7 > ^
(
NOZZLE I.D.
(^> y^ J

ASSUMED MOISTIIRF, ". 7
SAMPLE BOX NUMBER -5
METER BOX NUMBER /


METER AH{
C FACTOR
/ •/ ?
a.?
PROBE HEATER SETTING
HEATER BOX SETTING

SCHEMATIC OF TRAVERSE P(
READ AND RECORD ALL DATA EVERY
GAS METER READING
(V ) (t3
1 m'1
^7///
f <*










ACTUAL
1,0

Li
2.5-

2.dy

1.1
2' I
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2.25"
7.0










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STACK
TEMPERATURE
(TS),°F
3^7
3W
3S-&
?£l
Ui
J5&

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15Z
36 /

J?£5
3S?










REFERENCE
ES
yy^ ~f~-f-^ L ^ ^ ,*,
"/•?&'
Ap x . -3

DRY GAS METER
TEMPERATURE
INLET
(Tm in).0!7
7'/
ry
r£>
77
79
7?

8TI
£0
76
7&
79
7f










OUTLET
7£,

7?
7Y
7S-
73

7&
76
7?

7&>
7/










PUMP
VACUUM.
in. Hg
<£
7
7~z.
^y
/Y

/77

J7&
/7
-------
                                    ANALYTICAL DATA
PLANT    g s -g /-   e
DATE
                -  73
SAMPLING LOCATION
SAMPLE TYPE  PAfeTU»iA-r£

RUN NUMBER       ^	
SAMPLE BOX NUMBER

CLEAN-UP MAN   ^
                  7*" r.J
                                               COMMENTS:
FRONT HALF
         WASH OF NOZZLE, PROBE, CYCLONE (BYPASS),
    FLASK, FRONT HALF OF FILTER HOLDER

  FILTER NUMBER  /OOP OG 1 _
                                                                          LABORATORY RESULTS

                                               CONTAINERS-9-3 
-------
                                                                      FIELD DATA
PLANT fr'.s >t "-T At rut" «., i
DATE 7-/Z
SAMPLING LOCATION _/'.<~Jr;s,,S.
AMBIENT TEMPERATURE •/
BARnMFTRin PRFSSIIRF
STATir PRFWIIRF (P )
FIITFRNI!MRFR(0 5 /<
-r ?
r/V /T
''/^ A /^, -

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7^"
25?. 2 .*
? ••>. / v
•?.tra#.v
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£*
                                                                                                PROBE LENGTH AND TYPE
                                                                                                NOZZLE I.D
                                                                                                ASSUMED MOISTURE,'..
                                                                                                SAMPLE BOX NUMBER _
                                                                                                METER BOX NUMBER _
                                                                                                METER AHg	
                                                                                                CFACTOR	
                                                                                                                                 ss
                          -Z-
                          JL
                       A 72
                                                                                                PROBE HEATER SETTING
                                                                                                HEATER BOX SETTING
                                                                                                REFERENCE ip
                                                              SCHEMATIC OF TRAVERSE POINT LAYOUT
                                                       READ AND RECORD ALL DATA EVERY.
MINUTES
TRAVERSE
POINT
NUMBER
/
2
3
*/
5"
£

7
,e
•9
/o
//
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^^\^ CLOCK TIME
S3LING XcS^K)
TIME, mm x^
— — -— — ^sj£p
«'-+
3 4'-^
1. 4'-*-
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1 y^-
•( ¥ss
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9/9.6
92Z.3
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IMPINGER
TEMPERATURE,
"F
51
£/
^J
£3
&y
zy

s?
*9
£0
sr
6
-------
                                    ANALYTICAL DATA
PLANT  /? e C €• tr \f g

DATE      *3 ~ / 2.  - 7 .
SAMPLING LOCATION  IQA6TE

SAMPLE TYPE _

RUN NUMBER_
SAMPLE BOX NUMBER.

CLEAN-UP i
                                               COMMENTS:
FRONT HALF
                                                                          LABORATORY RESULTS
  A6EPOME WASH OF NOZZLE, PROBE, CYCLONE (BYPASS),    CONTAINER 3-',
    FLASK, FRONT HALF OF FILTER HOLDER

  FILTER NUMBER   / O & O O 6 ^	      CONTAINER
                                                                                         mg
                                                         S-TJ-ooV-5-/?
                                                                                        .mg
                                                            SUBTOTAL
                                                                                        .mg
BACK HALF

  IMPINGER CONTENTS AND WATER WASH OF
    IMPINGERS, CONNECTORS, AND BACK
    HALF OF FILTER HOLDER
    •AND-BAeK-ttAtF-OFTILTEirHOL-DER-
                                               ET-HER=eHtOR0FQRIVU
                                               BACK HALF SUBTOTAL
                                         .mg

                                         .mg

                                         .mg

                                         .mg
                                                       WEIGHT
                                                                                         mg
MOISTURE

  IMPINGERS
   FINAL VOLUME  2
                        ml
   INITIAL VOLUME 2 o O   ml.
   NET VOLUME      "V &>   ml

  SILICA GEL
   FINAL WEIGHT
   INITIAL WEIGHT  Y 7.H Qg
   NET WEIGHT   _ ~L-Z g

  EPA (Dur) 231
     4/72
                                   • E
                                   .g
                                   -g
g
g
g:
TOTAL MOISTURE
-------
FIELD DATA
~?^r^
•Co t
TRAVERSE
POINT •
NUMBER
-r
F
c


72

'/
.-•
r
//
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^










- PLANT P-flf — -*- //;>:<"*, L f
O^' DATE -'-.'.'•• .' :-
- SAMPLING L
•^ ^ SAMPLE TYP
),£> RUNNUfflBEF
OPERATOR .
AMBIENT TE
• " BAROMETRIC
. . " ' STATIC PRE.
FILTER NUM
•
>v CLOCK TIME
	 	 -~— £J^£
J &*•*-
3 • & * —
o - b'-^
J <£ ^~
? & 't-2-
3 £> W~
•" --S -.<& — '
^ /,-•-
^ ' ^- ^—

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5 • 7^
J 7 ^""










JCATION ' -; ' ' ' "' ' • • ' " •''•''•'• r '''•
F ;-:':- -'-.-,. :,,-.,
i 7

ilPERATURE '/ ?
PRESSURE 2 '"-*-' T-
SIIRF (P ) -i •?./•'/
RFR(.) /,fff>r-fjo^
PROBE LENGTH AND TYPE . : ." f.C JV/i
NOZZLE I.D.
f. t'?l

ASSUMED MniSTURF,"; . - T
SA.MPLE BOX NUMBER '3 ' . '

." .. SCHEMATIC OF TRAVERSE P
READ AND RECORD ALL DATA EVERY
GAS METER READING
(Vm), It3
9J-3. y
^55. "L.
rf£ 7. J
9*?. I
96 1,7 '**'
?£'/•?
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973, y

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HEAD
(APS), in. H20
/y
/,£
/- 7
3.Z
1.7
V.o

3.2
3,f>
2.3
2.S"
3,3
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ORIFICE PRESSURE
DIFFERENTIAL
(AH), in. H20)
DESIRED
/ Of
y/2
/.!(.
7.7

?.?

:?.«/
2- Z
/./'
y. 










PUMP
VACUUM,
in. Hj
^
7
7

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'/&

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/Z

/0\-
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TEMPERATURE,
°F
.//jT
77 7

7^2.
/?"•/
JZS"

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/77
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IMPINGER
TEMPERATURE..
"F
^> J^"
6't
s^Z
72-
77


6 7
&5~
•£•'/ •
67
!-•?
7^










COMMENTS:
EPA (Dur) 235 ^ . ^ "~~
4 72 '
/=r
'
y-??
yjf
yj2
/3f
-------
                                    ANALYTICAL DATA
PLANT ye.s
DATF   9 -  / 2  - 73
                                               COMMENTS:
SAMPLING LOCATION  /.Jflfrs

SAMPLE TYPE  • • pfl g Til m ftr e

RUN NUMBER	2
SAMPLE BOX NUMBER

CLEAN-UP MAN	d
FRONTHALF
                                                                         LABORATORY RESULTS
              OF NOZZLE, PROBE, CYCLONE (BYPASS),
    FLASK, FRONT HALF OF FILTER HOLDER

  FILTER NUMBER /oo&oo °i   _ ___
                                               CONTAINER .>~
                                                                                        mg
                                               CONTAINER 5-7J-OOV - 5"2 O
                                               FRONT HALF SUBTOTAL
                                                                                       .mg
BACK HALF

  IMPINGER CONTENTS AND WATER WASH OF
    IMPINGERS, CONNECTORS, AND BACK
    HALF OF FILTER HOLDER

AeETONE-WASH-QHMPINGERSreONNEeTORS,
                                               BACK HALF SUBTOTAL
                                                                                       .mg

                                                                                       .mg

                                                                                       _mg

                                                                                       _mg
                                               TOTAL WEIGHT
                                                                                        mg
MOISTURE

  IMPINGERS
   FINAL VOLUME   ^? 5~
  . INITIAL VOLUME  3L O o
   NET VOLUME    •  f
                        ml
                        ml
                        ml
SILICA GEL
 FINAL WEIGHT   /**  f g
 INITIAL WEIGHT  Y7.T-P g
 NET WEIGHT   	7-Y E

EPA (Our) 231
   4/72
                                               g
                                               g
                                               g;
                                                          TOTAL MOISTURE
                                                                                         .
                                                                                      ' f' '•  ••••
-------
                                    DRY MOLECULAR WEIGHT DETERMINATION
PLANT /f-rrms-C /sTintx-? S ~ COMM
DATE ?-/2-
SAMPLING TIME (24-hr CLOCK)
SAMPLING LOCATION M/<* J
SAMPLE TYPE (BAG, INTEGRATED,
ANALYTICAL METHOD
AMBIENT TEMPERATURE
OPERATOR 2*
- — 4 '
..-, •x^r' // '&
/& • — -~ // — <^*t tf
«^^ /^^j- Zftck.
CONTINUOUS) 8*4
£?>' r/r, (/
jTT"
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""^-^ RUN
GAS ^\^
C02
02(NET IS ACTUAL 02
READING MINUS ACTUAL
C02 READING)
CO(NET IS ACTUAL CO
READING MINUS ACTUAL
02 READING)
N2 (NET IS 100 MINUS
ACTUAL CO READING)
1
ACTUAL
READING
&,?
^^.^
ZO-P
19.1.
NET
^f
10.0
0.0
m
2
ACTUAL
READING
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2£>. f
7&TL
NET
a.?
20.0
0,0
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3
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NET




AVERAGE
NET
VOLUME





MULTIPLIER
44/100
32/100
T~H
28/ioo
28/ioo
TOTAL
MOLECULAR WEIGHT OF
STACK GAS (DRY BASIS)
Md, Ib/lb-mole
0.3f
&.io
G.0f>
2Z.'*
L?3*
EPA (Dur) 230
  4/72
-------
                    TRAVERSE POINT LOCATION FOR CIRCULAR DUCTS '  .'.
PLANT  ''-.I'. .^
DATE .. _____ ___?.-/£.:..?
SAMPLING . LOCATION . __ ^^^-
INSIDE OF FAR WALL TO     -r
  OUTSIDE OF NIPPLE, (DISTANCE A^
INSIDE OF NEAR WALL TO  '   '•
' • OUTSIDE OF NIPPLE, (DISTANCE. B)
STACK I.D., '(DISTANCE A - DISTANCE B)
NEAREST UPSTREAM DISTURBANCE _
NEAREST DOWNSTREAM DISTURBANCE.
CALCULATOR ____ £" .jjut/z.-

                                       ^
                                 ?7-V
                                       ft
.i
                                                                 .SCHEMATIC.OF SAMPLING LOCATION
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POINT
NUMBER'-
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TRAVERSE POINT LQCATIO:.
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'(SUM OF COLUMNS 4 £ 5}
..;: £i/t/
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3~*. ¥
£4.o
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4/72

-------
r^ r^ r* 1 i s r t >M Q~ c^ * • i • f *
tiV C!_ !!'/'! !!'.:.'•! !\Y V' r !
                                                       i •*" ^ f *T~ *^ P * f "~ V"~ ** r
                                                       ! ! V  ! F? w \.' !- R\
PLANT.	i
DATE	
LOCATION	
STAC K I. D	Z/y  1
BAROMETRIC PRESSURE, in. H«_.
STACK GAUGE PRESSURE, in. H20.
                                        .x
                                                                 SCHEMATIC OF TRAVERSE POINT LAYOUT
TRAVERSE
POINT
NUMBER •
." '/
2
•?
• ¥ '
Js
£ .
7
P
9
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AVERAGE
VELOCITY
HEAD •
(Aps), in. H?0
1 ./.3'
' ' J,f •
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.;,£
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. J.S
•J.f-
1,.O -
/•«&
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• STACK'
•TEMPERATURE
(Ts), °F. - .
2-If--
ZL£
• ?? ?••
22? -
••' 33-&
^LlP •
2}7
^' 2 i i
Z3& - '
• 231
2S2
?*
-------
                        NOMOGRAPH DATA
PLANT.

DATE_
SAMPLING LOCATION
                    Minute   fa
                                  aeJ ZifLaftrf £}#£&
CALIBRATED PRESSURE DIFFERENTIAL ACROSS
ORIFICE, in. H20 . • ...
.AVERAGE METER TEMPERATURE (A!YIBIENT + 20°F),°F
PERCENT MOISTURE IN GAS STREAM BY VOLUME
BAROMETRIC PRESSURE AT METER, in. Hg
STATIC PRESSURE IN STACK,' in. Hg
(Pm±0.073 x STACK GAUGE PRESSURE in in. H20)
RATIO OF STATIC PRESSURE TO METER PRESSURE '
. AVERAGE STACK TEMPERATURE, °F ',
AVERAGE VELOCITY HEAD, in. H20
MAXIMUM VELOCITY HEAD-, in, H20 ' '•
C.FACTOR . .. . •
• CALCULATED NOZZLE DIAMETER, in. - -
ACTUAL NOZZLE DIAMETER, in.
REFERENCE Ap, in. H20 , •.
. AH@
Tmavg.
Bwd
• pn,
- Ps
. Ps/Pm .
savg.
APavg.
APmax.
7.72
$*
/2
29.37.
•' 21.27
/ -
22f
/•7
'2fo
-O.$f.
&,/
-------
FIELD DATA

»
.PLANT Rrjri^^f M//t,tt.~ Ccr -•
DATE ?-S3~73 •' '•••'•
' • SAMPLING L
SAMPLE TYP
RUN NUMBEF
. OPERATOR .
aCATION /^//ff-'f-r,- Mt>a rj £
f /Zr, -•/;,.,/«{-.* '.^

X J'- /t,f/T. 4?c& /0?/e<-c
-..'•• ' - PROBE LENGTH AND TYPE 9-f^ SS.3J& •' '.-•''
- j f ( fa -/ •
• AMBIENT TEMPERATURE. -6'O .. ' ' . •' -


TRAVERSE
POINT
NUMBER
7
ff
Q
/&
//
/2

/
• z
' - 3
y
. y
f
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• BAROMETRIC
STATIC PRE
:' . * FILTER NUM
^K CLOCK TIME
SAMPLING^ CLOCK)
TIME.niin x^
— -. 	 Jo^/_
•2 - /^

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'.PRESSURE 2 f. ?7~
KIIRF (P ) ' 2?. i 7
RFR («) / , / % £
ISTIIRF •; /?- ' .'•••'
(NUMBER' 3 •
NUMBER /
/. 7-2
. . Q. g-$~ • -.
-- • -• . . . PROBE HEATER SETTING
'.- HEATER BOX SETTING
//fl-t.S
/•7t>
' ' *
' ' REFERENCE An 2'V •
"SCHEMATIC OF TRAVERSE POINT LAYOUT
READ.AND'RECORD ALL DATA EVERY__^I__ MINUTES
• GAS METER READING
(V 1 ft^
\ m'1 " .
• fs^r. /
^fO.'L.
' J 92.-J, .
•' • qqt/, 1
., 
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*,
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/<7
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• J.3
•
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/,£
/•?
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. ORIFICE PRESSURE
DIFFERENTIAL .
(iH), in. H20)
flESIRED
D/. "•
.= /• ^
: ).„
ACTUAL
A3
/-V
/ if
•i^ji- ]'/.2S-
$f*jt" '• / 35"
%(,•#£, \ /,ff
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//

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. DRY GAS METER-
TEMPERATURE .
INLET
(Tmin),°F
.?/ '
^•7
^7
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#*
$y

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OUTLET
Xt
pi
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: -.rz.
•''•fZ'
.'
^ ;
/?
&









• SAMPLE BOX-.
TEMPERATURE,
°F
JV
'/?2
. /^

/<6o .
/&(
" /73 •









: • . • .-
IMPINGER
TEMPERATURE,
"F
• vr
4*9
SO
6 &
Co
o

&o
£>o
• 60

60
60










COMMENTS: . • -%. £~-cJj>*ef #& ' f/ttlis -...'•
EPA (Our) 235 - ' ' . ' . • ; .'.''.•
472 ' '. ' .
^:
//5-
j
-------
                                   .ANALYTICAL DATA
PLANT
nATF
          e 5 -e  h y g
SAMPLING LOCATION.

SAMPLE TYPE   'p^£T>cu

RUN NIIIHIRFR      ft
SAMPLE BOX NUMBER.

CLEAN-UP
            /
FRONT HALF
         WASH OF NOZZLE, PROBE, CYCLONE (BYPASS),
    FLASK, FRONT HALF OF FILTER HOLDER
  FILTER NUMBER
                                               COMMENTS:
CONTAINER
                                                                         LABORATORY RESULTS

                                                                                        mg
                                               CONTAINER S '73' 6 o
                                        .mg
                                               FRONT HALF SUBTOTAL
BACK HALF

  IMPINGER CONTENTS AND WATER WASH OF
    IMPINGERS, CONNECTORS, AND BACK
    HALF OF FILTER HOLDER
MOISTURE

  IMPINGERS
   FINAL VOLUME
  • INITIAL VOLUME 3-0 Q   ml
   NET VOLUME      *f  ml

  SILICA GEL
   FINAL WEIGHT  JLULLJ-g
   INITIAL WEIGHT _4L2_£L? g
   NET WEIGHT       S> - Z g

  EPA (Dur) 231
     4/72
                                               CONTAINER
                                               CONTAINER.
                                               BACK HALF SUBTOTAL
                                                                                        .mg

                                                                                        .mg

                                                                                        .mg
                                                TOTAL
                                                                                         mg
                                               g
                                               g
                                               g;
                                                                                 (\
            TOTAL MOISTURE
                             3 /.
-------
                                                                        FIELD DATA
PLANT   F.'.fo-~-r
DATE	£:
                                         - XJ?

                      SAMPLING LOCATION   /x//>;6 j--P.-
                      SAMPLE TYPE     Ps,rlic,, lfftx
                      RUN NUMBER	   f
                      OPERATOR      £.fr/,.'f.     /?'
PROBE LENGTH AND TYPE.
NQ7ZLF I.D.     '      /.
                                                                                                                           9 P1~~
                      AMBIENT TEMPERATURE
                      BAROMETRIC PRESSURE
                      STATIC PRESSURE, (P )
                      FILTER NUMBER (s)
                                                                             ASSUMED MOISTURE/,
                                                                             SAMPLE BOX NUMBER.
                                                                             METER BOX NUMBER _
                                                                             METER AHg	
                                                                             CFACTOR	
                      3 
1 . I 2 "—
3 J*fJL
3 . 72^-
-.> /; ""-^





.



-
GAS METER READING
(Vm), tf
/jr^y _,
/^/
• y^.2
' /^ z .
'!3
/;•- V
S.lf
/./.r

A3
/-•/
/^•i"
/'/
/«j
;.°









•
ACTUAL
/.J
/J
/,J
A2
J.l?
;./*

/.r
'•?-
i,*?
AV
./. 3
AO










STACK
TEMPERATURE
(TS).°F
I*//
2W
1*3
' I 3S"
2^*-
I'/J

j?VZ.
13V
7?5"
,? ^ J
2'//
y?.*/










DRYGAS METER
TEMPERATURE
INLET
(Tmin),"F
?o
7'/..
T/
7&
7£
f-t.

7&
7C*
?^
ty
f-7.
77










OUTLET
(Tmout).°F
?o
'71
73
73
7Y
•»/

7S-
76>
?y
73
7 v'
7S~










PUMP
VACUUM,
in. Kg
7
•7
' 7
7
7
7

•7
7
7
7
.•-»
/
fy










SAMPLE BOX
TEMPERATURE,
°F '
/^5-
xV*'
^!?£3
/77.
77^3
J6ff

/ ~- ' '
//*'
>/?
/^i
//^
///
///.
/j
/oJ--*
/03
COMMENTS:
EPA (Our) 235
   4/72
-------
                                     ANALYTICAL DATA
PLANT.
                                                COMMENTS:
DATE__
SAMPLING LOCATION  HcnO   l< &t->r  .57VHK
SAMPLE; TYPE
RUN NUMBER
SAMPLE-: BOX NUMBER
CLEAN-UP
                   3L-
                   7  TJ^A..
FRONT HALF
          WASH OF NOZZLE, PROBE, CYCLONE (BYPASS),
    FLASK, FRONT HALF OF FILTER HOLDER

  FILTER NUMBER  /a o aa I O   _
CONTAINER ^ 7.3
                                                CONTAINER 5' 73' 0
                                                                           LABORATORY RESULTS

                                                                                          mg
                                                             SUBTOTAL
BACK HALF

  IMPINGER CONTENTS AND WATER WASH OF
    IMPINGERS, CONNECTORS, AND BACK
    HALF OF FILTER HOLDER
ACETONE WASH OF
    AND-BAGK-HAbF OF FILTER HOLDER
                                                CONTAINER.
                                                BACK HALF SUBTOTAL
                                          _mg

                                          .mg

                                          .mg

                                          .mg
                                                                                          mg
MOISTURE

  IMPINGERS
   FINAL VOLUME   * 2 5"
                        .ml
   INITIAL VOLUME %O P   ml
   NET VOLUME     . 3 ST  m|

  SILICA GEL
   FINAL WEIGHT   9 * & .7 g
   INITIAL WEIGHT  *f 7 T. 9 g
   NET WEIGHT   	5~- 7 g

  EPA (Dur) 231
     4/72
                                   .g
                                   • g
                                   -g
g
g
g;
TOTAL MOISTURE
- ?
-------
FIELD DATA
'r'-c-h
•PLANT fiff.cru •*. Mnnilti C»
DATE  - J/ood £Tie'J
&
tf
£
\
'O- #'°
>j 2/'&
#'.'0.0
TRAVERSE
POINT
NUMBER •
7
z
9
y,/,-/?, .x^4> fell"}'.

AMBIENT TEMPERATURE ' -65'- -" . .-"'• '."..-.'
' . . , BAROMETRIC
' • ; STATIC PRE
FILTER NUM
f
^^- CLOCK TIME
SAMPLING ^VC'LQCK)
TIME.njin -v^
—-r- -_____5J£X
3 • i — -


? .?J2-
•2 7 ¥&

.7'. 2 '-:i"
°1~~~': 	 	 ^£
? 2^-
J • . " J "-^
j •. • J^3
? 3«J^
*^ • "^
J« y 5^
• J — '






••



PRESSURE ?-?,.?/
SURF, (Ps) • ^ <*,?*/
RFR(«)- /#k&&tt1.
•••'•'. :' SCHEff
. • . ' ' READ AND REC
GAS METER READING-
j*.1"/
J^.5"
^
i-7
J. -3"
AJT
y /y -




_
A




PROBE LEN
NOZZLE 1.0
ASSUMED MC
SAMPLE BO
METER BOX
METER AH^
C FACTOR
GTH AND TYf
E ^ // ^-T JV£
x^ /t" -2 • .'
ISTURE/i '• - <£ ->•'•''"
(NUMBER ' '3 - ' • . '-- -•
NUMBER" 7 '"-.'•

/j. '
sir-
i/
., ,
/ ? i>~-
/i-T
A.?
/./S

//





»




"' : STACK .' . '
TEMPERATURE
-^JY
Z3Y •
>J7
- .''.i'^
y ss-
231

jy/^,._
j/^(X,
2*7
*! tf 7
' j* c* *j
• ' i /J










S/cv^? ' ' '
• . -/j-o
An . • • 2 • y" . • '
* " '
• ' • ' ' - .* '•(
. DRY GAS METER
• TEMPERATURE -
• INLET
(Tmjn).°F
g.0
po
7f
7^
n


%/
?•?
•??
#0
S'Z
fz

*








OUTLET-
n) out
y ^
7^
%;

%.¥
*fy
**
5jT
77
7"»
y *y?
/jr^1 •
X-i'-T
> 3T
• y^~y

'•/^•y
/j-f
'.iff
/&f
/<£.?
1 /^7









1
• v
IMPINGER
TEMPERATURE",
&3 1
t^C,
£ f
^7
fc? •
• ' 6& ' •

'&¥
• . 69 •
77

7J>ut,*.jL • " (yj'Ji'S rfs»/> '• (LAtckf.? 0 K' .
EPA(Dur}235 ' 	 ". •"- .•'•''..' ...-;' / . ' . . '• •
4 72 • • . ' ' ' '
'?/
j'f. .
//$•
"Y
-------
                                     ANALYTICAL DATA
PLANT

nATF
           -/•?- 7 J
SAMPLING LOCATION.

SAMPLE. TYPE   PflK

RUN NUMBER	IO.
SAMPLE BOX NUMBER

CLEAN-UP MAN.
FRONT HALF
          WASH OF NOZZLE, PROBE, CYCLONE (BYPASS),
    FLASK, FRONT HALF OF FILTER HOLDER
  FILTER NUMBER  /aO
                                                COIVI1VIENTS:
                                                                           LABORATORY RESULTS
CONTAINER 5-73 OQV


CONTAINER 5
                                                                                           mg
                                               .JEROaiT- HALF SUBTOTAL
                                                                                          .mg
BACK HALF

  IMPINGER CONTENTS AND WATER WASH OF
    IIKIPINGERS, CONNECTORS, AND BACK
    HALF OF FILTER HOLDER
    •ANB-BAGK-HAfcf-6F-fHLTER HOLDER
MOISTURE

  IMPINGERS
   FINAL VOLUME   1 * *
   INITIAL VOLUME _2L2je_
   NET VOLUME   	2 (,
  SILICA GEL
   FINAL WEIGHT  7
   INITIAL WEIGHT
   NET WEIGHT         -**-
  EPA (Our) 231
     4/72
HTIirD f*U|. ODDCIADM
1 1 ML.K-U1LUI
-------
                                          DRY MOLECULAR WEIGHT DETERMINATION
 PLANT.
 DATE_
ns?.
    /• r is f-
                        sty/, tf .•<•"?
COMMENTS:
                 ~/3 ' 7?
SAMPLING TIME (24-hr CLOCK).
SAMPLING LOCATION    /fr,
                                   — / 7 - •*
                                       ...       	f
                                   tfea et  £~*•-/,<•,*<;?
SAMPLE TYPE (BAG, INTEGRATED, CONTINUOUS).
ANALYTICAL METHOD     '	
AMBIENT TEMPERATURE	6 3
OPERATOR	#*
                              / i
^-^^ RUN
GAS ^^\
C02
Q£ (NET IS ACTUAL 02
READING MINUS ACTUAL
C02 READING) '
CO(NET IS ACTUAL CO
READING MINUS ACTUAL
02 READING)
N2 (NET IS 100 MINUS
ACTUAL CO READING)
1
ACTUAL
READING
a*
2l,o
11,0
79,°
NET
0.0
Zi.o
2.0
79
2
ACTUAL
READING
A*
11. 0
2/,0
?<}.&
NET
^. 0
2>,v
0-0
77
3 .
ACTUAL
READING




NET




AVERAGE
NET
VOLUME





MULTIPLIER
44/100

1
32/100
1 ~t
1 	 . 	 1
28/ioo
28/ioo.
MOLECULAR WEIGHT OF
STACK GAS (DRY BASIS)
Md, Ib/lb-mole
^
<^,3
0
22.2-
TOTAL ,^r
EPA (Dur) 230
   4/72
-------
                                                                                              i
                      TRAVERSE POINT LOCATION FOR CIRCULAR DUCTS
 PLANT.
 DATE .
SAMPLING LOCATION	(/("
INSIDE OF FAR WALL TO
  OUTSIDE OF NIPPLE, (DISTANCE A) _
INSIDE OF NEAR WALL TO  '
  OUTSIDE OF NIPPLE, (DISTANCE B) _
STACK I.D., (DISTANCE A - DISTANCE B).
NEAREST UPSTREAM DISTURBANCE	
NEAREST DOWNSTREAM DISTURBANCE,.
CALCULATOR	<~  -//iLc^L,
                                     ?
                                    J
                                        -ft
                                                                   .SCHEMATIC OF SAMPLING LOCATION
TRAVERSE
POINT
NUMBER

/
2
3
4'
s~
&
7
f
4
•s'0
//
/£












FRACTION
OF STACK I.D.

*/.•/
;'•/,*/
If.*
7J,J'
£-r?
fc:&












•





STACK .D.

j?4





-.



























PRODUCT OF
COLUMNS I AND 3
fro NEAREST 1/3 INCH)

/-^
S*z
//* -

' jy0
.




.










'A




^'

»
f T
^ 	 -j« _j







j
1
i
1








j0^ '
\





i i 4 	 ,
DISTANCE B

JT±
9~v
;Sir
j/4

y/%








^p
X









TRAVERSE POINT LOCATiC1
FROM OUTSIDE OF NIPPLE
(SUM OF COLUMNS ', & 5)

























PA (Dur) 232
   V/2
-------

PRELIMINARY VELOCITY TRAVERSE
PATF ?-/* • 7?
LOCATION Csntvs^o- >*f. /(',•. '': /£/-•//' i
STA^K in ~'f ••-'' "
BAROMETRIC PRES
STACK GAUGE PRE!
51IRF, in. Hp ' V'. 2 T
5
//
• /i












AVfJiAGE
VELOCITY
HEAD
(Aps),in.H20
0.?7
£,*/
tfS-f-
$. P 7
,-:?.-cf
^17^
A 7?
£.?#
&.41
f f / / *
0,??
#'.£$'













STACK
TEMPERATURE
(Ts), °F
• ^y.
• ^_r
^7
^7
< ?'•
\l& /
C/? //o
^7
£7"
67
£ 7
68-













:PA (Our) 233
' 4/72
                            SCHBrtATIC OF TRAVERSE POINT LAYOUT
                          .TRAVERSE•
                            POINT
                            NUMBER
                            AVERAGE
VELOCITY
  HEAD
(Aps), in.H20
  STACK
TEMPERATURE
   (Ts), °F
                                                  ^^
-------
                        NOMOGRAPH DATA
 PLANT

 DATE
 SAMPLING LOCATION
tc

Mt//
CALIBRATED PRESSURE DIFFERENTIAL ACROSS
ORIFICE, in. H20
AVERAGE METER TEMPERATURE (AMBIENT + 20 °F),°F
PERCENT MOISTURE IN GAS STREAM BY VOLUME
BAROMETRIC PRESSURE AT METER, in. Kg
STATIC PRESSURE.IN STACK, in. Hg
(Pm±0.073 x STACK GAUGE PRESSURE in in. H20)
RATIO OF STATIC PRESSURE TO METER PRESSURE
AVERAGE STACK TEMPERATURE, °F
AVERAGE VELOCITY HEAD, in. H20
MAXIMUM VELOCITY HEAD, in. H20
C FACTOR
CALCULATED NOZZLE DIAMETER, in.
ACTUAL NOZZLE DIAMETER, in.
REFERENCE Ap, in. H20
•AH@
Ttnavg.
Bwo
pm
ps
Ps/Pm
savg;
Apavg.
APmax.
/,72
?
-------
                                                                        :IELD DATA
                      PLANT.
                      DATE_
                              KJ- f..-

                                                                         PROBE LENGTH AND TYPE.
                                                                         NOZZLE I.D	&•
                      SAMPLING LOCATION
                      SAMPLE TYPE
                      RUN NUMBER
                      OPERATOR    /. y
                          15*1,  Pr /,,
AMBIENT TEMPERATURE .
BAROMETRIC PRESSURE .
STATIC PRESSURE, (Ps)_
FILTER NUMBER (s)	
                                      ,;
                                                                             ASSUMED MOISTURE,'',.
                                                                             SAMPLE BOX NUMBER.
                                                                             METER BOX NUMBER _
                                                                             METER AHg	
                                                                             C FACTOR
/.71.
                                                                                                                       /.a
                                              ?-?,.?/
                                                                        PROBE HEATER SETTING.
                                                                        HEATER BOX SETTING	
                                                                        REFERENCE Ap	
                                                                SCHEMATIC OF TRAVERSE POINT LAYOUT
                               READ AND RECORD ALL DATA FVFRY
                                                                                              MINUTES
TRAVERSE
POINT
NUMBER
7

7
#
"7
/ 0
//
1 1-

/
2
t>
tJ
_T
' /<








\v CLOCK" TIME
^=\£S?i
• TIME, mm \_
" 	 ~~ 	 -^--CLJ
. • r  ^ - -
	 	 _/£->"
/• '. s °°
6 k> • —
/ / °
JO ' o ~
/o. to'hfL
10 (?3^
10 ff '.'"
/ c? ' o -53-
"" — • ~, ^_., iJ. ^i ^'.
so . i °-.
/^ 7 -
/<9- 7 2^r
AO 7--
--'':•'
\r> ";!^;-








GAS METER READING
(Vm), 1?
i 1 •">
1
V1

7?. 5
,5>7.-c_
f (P' 7
/'!
. bS

-?!>
.

y.S
2. 7
3-.?
1 .?
2., '?
^?.»

2. , -vr
-?.
2.7
1 7
1,'f
1

61
61
leZ^.
(,^
•* , -• t^~-->
^








PUMP
VACUUM,
in. Hg
_

//
//
/2-
/Z-
/^
?

/^
/2
i rt
1 /<_r
I Z-
lit
C\








SAMPLE BOX
TEMPERATURE,
°F
_—

/JO
/J7
/ ^7
/o-j
/ oo
/ 00

;/s
/if
MS*
i • "TJ
i ! 7--'
I O'~i








IMPINGER
TEMPERATURE,
"F
. —

jT-i"
->",?•
J>"7
5-
F^P>








pjrajlf
Is.**;-'
*/=
??
?'?
95~
°i3
1Z.
^0
?£.
•^

-------
                                   ANALYTICAL DATA
PLANT /f -e S e /• IA -e
SAMPLING LOCATION
SAMPLE: TYPE _
RUN NUMBER	
SAMPLE BOX NUMBER.

CLEAN-UP MAN.
FRONT HALF
                                              COMMENTS:
                          &~ i?e0e,a /3   	
CONTAINER .6-
                                                                       LABORATORY RESULTS

                                                                S3I  _ mg
                                              CONTAINER S-73-Oal-
                                                                                     .mg
                                             :FROU HALF SUBTOTAL
BACK HALF

  IMPINGER CONTENTS AND WATER WASH OF
    IMPINGERS, CONNECTORS, AND BACK
    HALF OF FILTER HOLDER
MOISTURE
                                             -EfHER^HtOROFORM
                                              BACK HALF SUBTOTAL
                                              TOTAL WEIGHT
IMPINGERS
FINAL VOLUME
INITIAL VOLUME
NET VOLUME -
SILICA GEL
FINAL WEIGHT
INITIAL WEIGHT
NET WEIGHT
EPA (Dur) 231
4/72
/ ? 6
2« v
_ a
ty/.
? ? c. <
/a.

• ml
ml
ml ••-••••
^E E «
^ g g E
g E ' E!

                                                         TOTAL MOISTURE
                                        .mg

                                        .mg



                                        .mg
                                                                                      mg
-------
                                          DRY MOLECULAR WEIGHT DETERMINATION
 PLANT.
 DATE_
                                            COMMENTS:
- 72
 SAMPLING TIME (24-hr CLOCK).
 SAMPLING LOCATION	
                                                                          **
 SAMPLE TYPE (BAG, INTEGRATED, CONTINUOUS).
 ANALYTICAL METHOD	
 AMBIENT TEMPERATURE	
 OPERATOR	'
\^ RUN
GAS ^^^^
C02
02 (NET IS ACTUAL 02
READING MINUS ACTUAL
C02 READING)
CO(NET IS ACTUAL CO
READING MINUS ACTUAL
02 READING)
N£ (NET IS 100 MINUS
ACTUAL CO READING)
1
ACTUAL
READING




NET




2
ACTUAL
READING




« 3
NET ;p AQTUAL' .
•:lj RgDING




;. f



NET




AVERAGE
NET
VOLUME




•
MULTIPLIER
44/100

1
32/100
C"ll •
28/ioo
• 28/ioo
MOLECULAR WEIGHT OF
STACK GAS (DRY BASIS)
Md, Ib/lb-mole


-

TOTAL
EPA (Dur) 230
   4/72
-------
   APPENDIX C



Laboratory Report
-------
               UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
                 NATIONAL ENVIRONMENTAL RESEARCH CENTER
               RESEARCH TRIANGLE PARK, NORTH CAROLINA 27711

SUBJECT:  Process Emission Samples From Duluth         DATE: March  14,  1974


FROM:    F. P. Scaringelli -^
        Chief, ESAS       *

TO-.    .  R. L.- Ajax     •               ...      .,.-..
        Chief, EMB

        THROUGH:   0/D,  QAEML


             As per your memorandum of February 5, 1974, we  are
        transmitting for your use the following items:

             a)  A xerox copy of the data sheets showing the ac-
                 cumulative particulate matter and the weights of
                 the filter from which these values were computed.
                 These  are  pages copied from laboratory notes of
                 Gary McAlister, Chemist.

             b)  Documentation of Chain of Custody - Sampling
                 handling log; Source Sample request and report;
                 letter of  transmittal of samples to Battelle
                 with certified mail receipt superimposed; and
                 the cover  letter from the Battelle Analytical
                 report.

             All  other  information that you require, has been re-
        quested from Battelle.  They will be transmitted to  you  as
        soon as received.
        cc:  Dr. Shearer
             D. Goodwin
             Ur. Thompson
             R. H. Jungers

        Enclosures
EPA Form 1320-6 (Rev. 6-72)
-------
o^-\,  ci'n/
/•io. :  l&
                                                    $ft.i-:'*}iL $.

 _ . ..••(. v.^-S'i.t--   ;  /(. ^-J. /-
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                                        J  -  .. <-/<,j<::
                                                 . fil
-------
        u*. A.    r.^,'n
             »~A      i	--—J—I .. .
 y.•;•••• -.",rT-7


    -  3..

'  .  ..-...^,..
            53
        .43^0
-  ->/
                                              - $6
                                              -57
            '/-
-/ 5"
                                                      y  i
 - / 7
   -
                                              _zfI/_
                                                "Z
                                             jL£lr_
                                              - 5-5-
                                             - .-r'6
       	_42_oJ_

                                                        4 Jv
-------
                        Reserve Mining Test :?74-HAS-l

                           Sample Identification*
Fine Crusher Stack
Probe
Filter
Impinger
Waste Gas Stack
Probe
Filter
Impinger
Hood Vent Stack
Probe
' Filter
Impinger
Concentrator Stack .
Probe
Filter
Impinger
Run 1
501
502
503
Run 4
510
511
512
Run 8
.522
523
524
Run 11
531
532
533
Run 2
. 506
505
504
-Run "5
513
514
515
Run 9
525.
526
527


Run 3
507
508
509
Run 6
516
517
518
Run 10
528
529
530


Run 4
—
Run 7
519
520
521




The numbers shown are the final three digits in an 8-number code:
S-73-004-xxx (for example the probe wash for run #1, fine crusher
is identified:   S-73-004-501).
-------
3i .' iS ' J.I : 35 : Ji
 SAMPLING DATE
               YR| MO  I DAY
                                                        1 50
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                                                                                                                      19 I .70 ! 71 I 72 '  73 I 7« | 75 | 7li j 77 '  T. \ ?» • 80 '
                                                           SOURCE SAMPLE REQUEST & REPORT
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[FIRST IOENT.
I NO. USED   s  71 00^1  s
         [LAST IDENT.
          NO. USED    5  73   004
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                                                                                         REPORT 01'  ANALYSIS
                                                                                           TRACE ELEMENTS
                                                                                         pprn - (or si .id samples
                                                                                       • ug/ml -  for I quid samples
                                                                                                                                                            Waik (xt  lor specific onclysis
                                                                                                                                                            Mark (x)  in block to left of Ident.  No. wfien
                                                                                                                                                            reauesting ell analysis  or, thai line
1C

















•;:••! No. 1
1
• f















.H?l
1 |

-»M
J L
1 1

! 1

J L
1 !

1 1

I i

1 I

Be
I |

J L
J L
1 1

1 I

J L
1 I

1 1
\
1 1

1 1

Cd
! i


J.L
1 1

1 1

J L
1 I

1 1
.
1 1
.


As
I |


J L
1 1

1 1

J L
1 1

1 I

1 1

1 1

V
1 I

— . —
J-L
1 1

l-l

J L
] 1
'
1 1
.
1 I

•i 1

Mn
I I

J L
J L
1 1

1 1

J L
1 I

1 i

i 1



Ni
1 1

J L
J L
1 I

1 I

J L
1 1

1 1

1 1

1 1

Sb
1 I

J L
J L
1 1

1 1


i I

1 1

1 1

i 1

Cr
1 I

J L
J L
1 1

1 1

J L
1 1

1 1

1 1

1 1

Zn
! 1

J L
J L
1 1

1 1

J L
! 1

1 1

1 1

1 1

Cu
1 I

J L
J L
1 1

1 I

J L
1 1-

1 !

1 1

1 1

Pb
I 1

J L
J L
1 1

l-l

J L
1 1

1 1

1 1

1 1

Se
I I

J L.
J L
! I

1 1

J L
1 1

1 1

1 1

1 !

B
1 I

J L
J L
1 I

1 I

J L


1 1

1 1

1 I

F •
1 |

_j L
J L
1 I

i |

-J L
! 1

! 1 .

l I-

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Li
I |

J L
J L
I I

1 I

J L
1 1

•1 1

1 1

1 I

Ag
1 I

_) L
J L
I I

1 |

J L
! 1

1 1

1 1

I I

Sn
1 1

J L
J L
1 1

1 1

J L
1 1

i 1

1 1

1 1

Fe
1 |

J L
J L
1 I

1 I

J L
J L

1 1

1 1

J L

Sr
I |

J L
J L
1 I

1 I

J L
1 1

1 1

1 1

1 1

Ma
1 |

J L
J L
1 1

1 1

J L
1 1

i 1

1 !

1 1

K
1 I

J L
J L
1 1

1 1

J L
1 !

1 1

1 1

1 1

Co
I |

J L
J L
1 1

1 1

-1 L
l l

1 l

1 I

1 |

Si
I I

J L
J.L
1 1

1 1

J L
! 1

1 I

1 1

1 1

Mg
I |

J L
J U
1 1

1 l

J L
1 1

1 1

1 1

1 1

Ba
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J L
J L
I I

I 1

J L
1 1

1 1

1 1

1 1


1 1

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J L
1 I

1 1

J L
J U

1 !

1 1

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I 1

J L
J L
1 1

1 1

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1 1 •

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1 1


1 1

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J L
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1 1

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     ysis l.'eih.ox  !-'iiAA. 2-SSMS,-3-OES. •'••AA. 5-ASV,  6-XRF, end 7-oiher
                                                                                                                                  Comments:
! 0:-tri Analysis  - Use  Table  B to  fill analysis requested  (above each column)
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Cc-rnmenis:
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                                                                               It  57   5B  59
                                                                                            60  61   62  63
               III     I
• .SAV.PLiN?, DATE j ^' (1   \  lf\

               lYR'i MO ' DAY*1
                                     FIRST IDENT.
                                      *  USED
                                                             SOURCE SAMPLE REQUEST & REPORT
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                                                                                     LAST IDENI
                                                                                     NO. USED.
         II-DUSTRY
                                 (USE TABLE A)

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                                                      _DATE ANALYSIS REQUESTED	
                                                                                                                  DATE OF REQUEST	
                                                                                                                                    (TO BE  FILLED !.': RY ^f-Aii
-------
                                                                                        REPORT  dF ANALYSIS
                                                                                         TRACfi ELEMENTS
                                                                                        ppm •  for .solid samples
                                                                                       ug/rril • for liquid  samples
Murk ixi  lor r.jc-citic cr.ci'jSi:
Work ixi  in block tc  lei! of idei;. Nj. when
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ideal No.




















Hg
J L
J L
J L
J L
J L
J L
J L
J L
J L
TL
Be
LJ L
U L
J L
J L
J L
J L
J L
r-J h
Q-TJ
J
L
Cd
U L
U L
U L
U L
U L
U L
J L
U L
J L
TTL
As
J L
U L
U U
V
J L
J L
U L
U LU L
U L
U L
U L
J L
U LJ L
j Epm
U L
J L
J L
Mn
J L
U L
U L
U L
U L
J L
J L
J L
J L
J L
Ni
J L
J L
J L
J L
J L
J L
J L
J L
J"L
Tn
Sb
J L
J L
U. L
U L
U L
-1- L
U L
U
J
L
L'
J L
Cr
J L
J L
J L
Zn
J L
J L
rJ L
J LU L
U L
-1 L
J L
n/ L-
J L
J L
J L
J L
J L
J L
J L
J L
Cu
J L
J L|
Pb
J L
J L
J LU L
J L
U L
J L
J L
J i_
J L
J L
J L
J L
J L
J L
Se'
J L
J L
J L
J L
J L
J L
J L
J LjJ L
J L
J L
J L
U L
B
U L
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J L
;:rt
J L
J L
U LJ L
U LJ L
J L
—
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J s.-.
H -H h
J JJ,h
iMilysis Method: 1-NA.A. 2-SSMS. 3-OtS. 4-AA, S-ASV, 6-XRF, end 7-other •
i • •'
Oiper Anc!y:;is • U:e Table B to fill- onciysis requested (above eoch column)
idem No.
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U L
:m
J L
J L
J L
J L
J. L
J L
J L
J L
Ag
J L
U L
J L
J L
J L
U L
U L
J L
J L
J L
Sn
J L
U L
U L
U L
U L
U L
U L
U L
U L
U L
Fe
U L
U L
U L
U L
U L
U L
U L
U L
J L
J L
Sr
J L
J L
U L
No
U L
U L
U L
J UJ L
J L
J L
J L
J L
J L
J L
r
U L
J L
K
U L
J L
J L
J L
J L
J L
J L
U 1 	 1 L
J L
J L
J L
J L
Co
U L
U L
U L
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1

U L
U L
Si
J L
U L
Mg
J L
BG . V;f
J
J LJ
U LU L
1 1

U L,
J L
J LU L
J L
U L
U L
' Comments:


*
J
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Ccr.meo'.s:
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SOURCE SAMPLE REQUEST & REPORT . •
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REQUESTED

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ANALYSIS REQUESTED • GENERAL COMMENTS
(APPROX CONCENTRATIONS • POSSIBLE INTERFERENCES
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-mm s,<.[>i>
-------
 REPORT  )F ANALYSIS
   TRACE  ELEMENTS
 ppm  • for  solid samples
ug/ml - !or liquid samples
Mar1' ixi fo: sij-ici'i: c'.:.'vs:s
'.'.iff. ui n  biotr. ;o !•:•!; c!  !•-•::•:. .'.
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-idem No.








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Hg
hJ L
J L
J L
rJLi






U L_
J L
J L
J L
J L
J L
dfj'jlysis Me:had:

Be
J L
r-l L
J L
J L

J L
J L
J L
J L
F^
Cd
J L
J L
J L
J L
J L
J L
J L
J L
J L
As •
J L
r-l L
J L
' V"
J L
J L
J L
J LLJ L
ircr
J L
J L
J L
J L
J L
J L
J L
J
JLJUJ
L
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J L
J L
J L
J L
r1 L
J L
J L
J L
ITC
Mi
J L
J L
J L
J L
J L
J L
J L
J L
:m
J L
So
J L
J L
J L
J. L
J L
J L
J L
J
3'
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L
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Cr
J L
J L
J L
J L
J L
J L
J L
J L
J i_
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Zn
J L
J L
J L
J L
J L
J L
J L
J L
J L
J L
Cu
J L
J L
J L
J L
J L
J'L
J L
J L
J
U
L
L
Pb
J L
J L
J L
J L
J L
J L
J L
J L
Se
J L
J L
J L
J L
J L.
J L
J L
J L
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J L
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8
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J L
J L
J L
J L
J. L
J L
J. L
J L
J L
J L
J L
J L
J L
J L
J L
J L
J L
J L
J L
J L
Sn .
J L
J L
J L
J L
J L
J L
J L
J L
j L
J L
Fe
J L
J L
J L
J L
J L
J L
J L
J L
J U
J L
Sr
J L
J L
J L
J L
J L
J L
J L
J L
J L
J L
No
J L
J L
J L
J L
J L
j L
J L
J L
J L
J L
K
Co
J i J
J L
J L
J .L
H L
J L
J L
J L
J L
J L
L
Si
1 1

J L
J L
J L
J L
JL^JL
J L
J L
J L
J L
J L
J L
J L
J L
J U J L
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Mg
J L
J L
J L
J L
J L
J L
J L
J L
J L
J L_
3c
J L
J L
J L
J L
J L
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J i? ^ '-H H-' H
1-fiAA, 2-SSMS, 3-OLS, 4-AA, 5-ASV, 6-XRF, ond 7-other • Comments: . _ -
t
Otter- Analysis • Use Table B to fill ana ysis requested lobove each column) V.crV ui lor specific cr-c'-ysis re:-j?s-ed
Iden; fio.
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Con-,me-;s: . .
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SOURCE SAMPLE REQUEST & REPORT • ' 1-
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ANALYSIS REQUESTED - GENERAL COMMENTS ' .• r
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59

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                             (IF APPLICABLE)
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EPA(DUP.C!5
                                          .DATE ANALYSIS REQUESTED	
                                       DATE OF REQUEST.
                                                                                                                         (TO BE FILLED IN BY SSFABi
-------
                                                                                           REPORT  OF ANALYSIS
                                                                                             TRACK  ELEMENTS
                                                                                           ppm -  lei  silid scrnplos
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J L
J L
J L
J L
J L
_j L
J L
J L
J L
Sr
J L
J L
J L
J L
J L
rJ L
J L
J L
J L
J L
No
J L
J L
J L
J L
J L
J L
J L
J L
J L
K
J L
J L
J L
J L
J L
J L
Co Si Mg Bo j ;',;:V. '
J 1 	 II 	 1 UJ UJ LU LU LU L
J LU L_U UJ LU LU L-LTUJ U
1 !^ 1^ ] ! 1
JLJJLULJJLULULULUU
ii i i l
J UJ 1 	 11 	 1 UJ 1 	 1 UJ LJJ U
r \ - i i i
J UJ 1 	 1 1 	 1 1 	 1 LJJ LU LU Lj
J UJ LU UJ LU UJ LiJ LU L_
J I_U LLJ LJ LJJ LU LLJ i 	 ! LU U
J L
J l_J
J LJJ L
1
J
i i r T r .

LJJ UJ 1 	 l U_i U
l ^ .!..!_
J UJ 1 	 I UJ -1 	 i i 	 1 LU UJ U
! i i 1
U LU UJ -'UJ 1 	 1 LU LU LJJ U
1 i i : i
Comments: •'"'
". ' •
C.-'.r.f.t Ancr/:iS • Use Table B
10 fill analysis requested (otovq each column)
U'?nt iio.
! U
i : —
1
j



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• '• H • ••
i D
i- • u
u
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j

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g u
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i
-------
" 1 ! ! I -1 I ! i 1 I" ! ! 1 ! ! ! 1 ' 1 1 ! M | ! I ! 1
~;= • • , SOURCE SAMPLE REQUEST & REPORT • |-
-;; . : . (MUST BE FILLED OIT-FOR EACH TEST' RUN)
•'•* ' -SAMPLING DATE 7^! fl ! ;3 ' TFST NO 'jy tfA£~t
i* JYR; ««o i DAY FIRST IOENT. LAST IDENT.
~7; • . ' L'" ' NO. USED 5- 7. 3 "CO V - ,5-2.2 • NO. USED S~93 c6r->lO
j 1 \ *
™ ' 0^-71 ^/vxp^ y\C fy1" £ t-*^ t'-V-k % H"^A^^/t\ { ^* ^1^*1'^? 5 I
I « v. /
- -j • !

- - •
i

' 1

	 	 ;

'- 1
'
Ui
UNIT PROCESS OPERATIC
AIR POLLUTION CONTRC
FUEL USE
. -;:.i INLET .y o
GAS VOLUME SAMPLi
(METES VOL IN FT3
. SAMPLE
WT VOL
. (SOLID) • ; ' LIQUID)
MG ' ML
• 1 '









"Tj j COMMENTS:
N l4trr,(I l/e^vr r
;
j
11 k.V^-r\ P . U
r
;—
D

JTLET _ 0 .
rn c* 3 • / • _
j
ANALYSIS REQUESTED • GENERAL COMMENTS j
(APPROX CONCENTRATIONS - POSSIBLE INTERFERENCES j-
ETC) (INDICATE SPECIFIC ANALYSIS ON BACKSIDE) ' 1
r
/
Wv?*> i (\*;kc'')i->-.
', .. . 7
L^v I/ (I <. REQUEST ^/ / ^ J_

i (IF APPLICABLE.)
;"' DATE OF REQilFST DATF ANAI YSIS
!":
RFOIIFSTFn ' OATF OF RFOllFST ' ll
'-1 EPAfDURi^S ' " ' " (TO BE FILLED IN BY SSFAB) j =
-r— , " • J—
-------
                                                                                           REPORT OF ANALYSIS
                                                                                             TRACE ELEMENTS
                                                                                           ppm • lo: soiid samples
                                                                                          ug/rnl •  k" liquid samples
                                                                                                                                                              Mo I'd ui  'or specific. "Tis'.ysis
                                                                                                                                                              f.'crk HI  in block :o i*!i '' !;•?"'.  No. v.ren
                                                                                                                                                              reaueslmg oil  analysis on ;-.:! i;.ne
lient No. Hg
r

•







U L
J L
Be
U L
U L
J LU U
i i
J L
J L
J L
J L
Cd
J L
J L
J L
u i_unj
J L
J L
J L
J L
J LU L
1
. JJ LU LU L
• U LU I
r
HL

J L
1 |
TU
As •
J L
J L
J L
J L
J L
J L
J L
J L
TIL
J~C
V
J L
J L
J L
J L
J L
J L
J U
J L
J L
-J L_
Mn
J L
J L
J L
J L
J L
J L
J' L
im
J L
J L
Mi
J L
J L
J L
J L
J L
J L
J L
J"L
J L
So
J L
J L
J L
J L
J L
J L
J L
J L
ITL
J L
Cr
J L
J L

J L
J L
J L
J L
J L
J~C
J L
Zn
J L
J L
J L
J L
J L
J L
J L
J L
J L
J L
Cu
J L
J L
J L
J L
J L
J L
Pb
J L
J L
J L
J L
J1 L
J L
J 1 	 1 L
1
J L
J L
J U
J L
J L
J L
Se
J L
J L
J" L
J L
J L
J L
J L
J L
J L

B
J L
ITT::
J L.
1 I

J.L
J L
J L.

j i

J L
F
I |

_J L
..J L
1 |

J L
J L\
J L
J L
1 I

J L
Li
J L
J L
J L
J L
J L
J L
J L
J L
J L
J L
.Ag
J L
J L
Sn
J L
J.. L
UELJ L
1 1 1 1 1
J L
J L
J L
J L
J L
J L
J L
J L
J L
J L
J L
J L
Fe
J L
J L
J L
J L
J L

J L
J L
J L
J L
Sr
J L
J L
J L
J L
J L
J L
J L
J L
J L
J L
No
J L
J L
J L
J L
J L
J L
j i_
J L
J L
J L
K
J L
J L
Co
J L
J L
J 1 	 1 L
J L
J L
r1 L
J L
Si
J L
J L
Mg
J L
J L
ULJL
Be
J L

j | 	 | L
i

J
J LU LU LJ
I t 1
J LU LU LU
i 1 >
J LU LU LU L
J LU L
J L
J L
J L
J L
J LU LLJ L
J L
J L
JIUUL
J LJJ L
J L
J L
J L
J -L
J L
J L
U LU LU
! i
J 1 | i LJ
J UJ LJ
1 !
J 1 	 i LU L
i -i
J L
J LLJ L
J
IT
J LJ LJ LU LJ
J LU L
J 1 	 1 L



1

',:.".,-

LJ L,.
-Hh





J L

LUT:



LU L
LUL
LJJ L_j
J L
A.KOiysis f.'et^cd: l-'iAA, 2-SSMS. 3-OF.S, 4-AA, 5-ASV, 6-XRF, and 7-other • ' Comments:
J Lj
(
•
j C'ner Anc;/:.is -  Use Toble B ;o  fill cwiysis  requested (above each column)
                                                                                                                                                                       Mark (xj  !cr specific crc:;,sis .-eciesie.; j

)











'-:

Ident No.
• .











n:ys;
rteA

J

U
J
J
U
j
j
LJ .

J
J



J

J
J -
_J
J
U
J .
,J

J
J



J

J
i
J
iJ
J
J
U

u
J



J

_J
J
LJ
J
J
J
J

J
J



J

J
_J
_J
LJ
LJ
J
J

J
J



J

J
J
g
J
j
j
j

j
j



j

j
j
j
j
j
u
j

j
j •



j

j
J
_i
j
j
j
j-

j
u



J

J
u
J
J
J
J
1 I

J
J


I
J

u
_i
U '
u
u
i
— I


D
j


Ccrr.rnsr;;:
-------
                                        44 I 41 | 16 ! 47 | 43
                                                       49 505I |  12. 53
                                                                      UJ-LLLJ   I   I   LU-4- _L
                                                                      156 I •>: i 58 I S3. | 60  61 | 62 | 63 | 64 I 65  66 | 67 | 68 | 63 | 7
                                                            SOURCE SAMPLE REQUEST & REPORT
                                                            (MUST BE FILLED OUT FOR EACH TEST RUN)
SAMPLING DATE |;/-|J_qJ )3_|.
             jYR ; MO  I DAY
[FIRST '.DENT.
I NO.
            It.'OUSTRY.
                                  (USE TABLE A)
                       i\          I A.  x
            COMPANY	\^:.fr^r   IA
            ADDRESS
          .  f.F.THOD
  S i
. X
 i
                                                                    ~1      H.AST IDENT.
                                                                   _J      |f!0. USED   3-f?3-gf'1'
                                                                                                                               TEST N0___

                                                                                                                                RUN NO——^	'
                                                                  UNIT PROCESS OPERATION	

                                                                   AIR POLLUTION CONTROI	

                                                                             FUEL USED	
                                                                        O INLET TO OUTLET
                                                                     GAS VOLUME SAMPLED	
                                                                     (METER VOL IN
                                                                                                   •13.-7
DESCRIPTION OF
IOENT «() 1 ' SAMPLE OR SAMPLE
. ' | • FRACTION
! . ,
$2*'t \ prH'e L.«J.4f»- co'.^,k
.... ^2h \ j^;-\nr,- ( \OC.i: f>(C\\
^2? j U-^'^Pr' £ C-.v-T-V.V-k -4-LAj.-L-Jov-,.-,,':jj*



I



     CO Vi ML NTS:	
   SAMPLING
   CONTRACTOR	\

DATE OF REQUEST	
                                                         -PROJECT OFFICER
                               (IF APPLICABLE)
                                                                CER	Lf\ .sOWvy.  YO t'l
                                                                              REQUEST
                                                                             .REVIEWED
                                                    .DATE ANALYSIS REQUESTED	
                                                                                                       DATE OF REQUEST,
                                                                                                                             (TO BE FILLED IN BY SSFAS)
-------
                                                                                         REPORT  OF A'MUSIS
                                                                                          TRACf: ELEMENTS
                                                                                         ppm •  !o( solid soinples
                                                                                       ug/ml • dr liquid somples
Mu.'k (xi !cr  sciCi'ic Ci'.si.S'.s
Vcr1'. IXi in il'iOCk  to 12K C!  iCC"-.  '.'C.
requesting  oil cnclysis on that I me
Ideni No. Kg Be Cd As V







t
J L.J 1 	 i UJ UJ L.
J UU 1 	 1 LJJ -1 	 1 L
J 1 	 1 1 	 1 1 	 I L 	 1 L
J UJ LJJ UJ UJ L
J UJ UJ UJ i 	 1 U
l i i
U LJJ UJ 1 	 i UJ L
i ' i
• U i | J LU 1 1 [ T
^ i i H"1 ' — '
U LJJ LJJ LJJ LJJ
i 1 l
L
r
Mn
J L
Ni
1 1

U C
J L
J L
J L
J L
J L
J U
HL
LJ LJJ (UJ 1 	 i .1 	 1 UJ U
J L
J L
J L
un
J L
J L
J L
J L
^
Sh
J L
U L
J L
J L
J L
J L
J
U
J
u
L
H
Cr
J L
J L
J L
J L
J L
J L
J U
J U
J. L

Zn
J '
U L
J L
J L
J L
J L
J L
J L
J U
J L
Cu
i t
U L
J L
J L
J L
J L
J L
J L
J L
TH
Pb
Se
J LJ L
J L
J L
J L
J L
r1 L
J U
J L
J U
J L
J L
J L
J L
J L.
J L,
J L
J L
J L
J.L
8 IF
jr.:
J L
J L.
J L.
J L.
J L.
J L.
J
1

J L
J L.
1 1

J L
..1 L
::m
..! L
J L
..1 L
i |

! 1

.J L
Li
I |

J L.
J L.
J L,
J L
J L.
J L.
J L
J L
J L
Ag
J L
J L
J L
J L
J L
J L
J L
J L
J L
J L
Sn
J L
U L
J L
J L
J L
J L
J L
J L
J L
J L
Fe
J L
U L
J L
U L
J L_
U 'L
J L
1 |

J L
Sr
J L
J L
J L
J L
J U
J L
J L^


U
J U
No
J L
U L
J L
J L
J L
J L
J L
J L
J L
F^KM1-
K Ca Si f.'.g Oc ",;.::"
1 I 1 1 1 1 1 1 i 1 I
! i '
J UJ LJJ 1 	 II 	 1
J LJ LJ LJ 1 	 i
l
J LJ LJ LJJ LU
11 ! i |
1
II III

1 Mil!:
f t
LJJ U
LJJ U
i
LJJ U
i i
" 	 i LJ
ULJLLlLJI 	 1LJLJUJ ..M|
j j | |
J LJJ_ UJ LJ LJ LJJ L_J UJ 1 	 1 U
J 1 	 ! L .j ) I 	 1 1 . 1 1 1 | 	 1 LJ JJ L, '
J L

LJ LJ 1 	 1 UJ LJ LJ
J LjJ LU 1 	 1 1 	 ! LJ 1 	 i LU
J J
I. l-j
1 ! 1 •]
1 i
J 1 l | 	 | 1 | i 1 i LjJ LJ LLJ LJ U
A;;c!ysis f.'5tr.od:.l-flAA. 2-SSMS. 3-OES..«-AA, L-ASV, 6-XRF. and 7-other • Comments:
i
.Direr Anc-ijsis • Use Table B to fill analysis requested (above each column) . I.'crk ui lor specific c^-lysis recjjes-vJ j
Ident No. ' " 1







i.
i
t •

• ' J
u .
g
P '
g
U
u •
g
g
• . g
Ar.O!>SJ
.vettoa
-

i
_j
j
.j
_j
_j •
_j
_j
_j



J •
J
J
J
J
J
g
j
j
LJ



-J
J -
J
_J
g
g
j
j
j
g



— '
g
j
j
g

g
j
g
g



U
g
j .
j
j
j
j
j
j
j



J
J
J
_J
_|
_l
J
J
J
J



_1
J
J
J
J
J
J

U
g
u
j

i i
_J
_J
g.
g u
j
j
g : LJ
J U
J
g


J
j
g •
u u



•
Comments:
-------
'MM
'SAMPLING DATE
INDUSTf
CQMPAr
ADORES
SAMPLI
METHOC
IDENT NO
•52 *' '
'f-f'tji
~~--> -,






; 1 |
^•<\ hv
YR'j' MO j DAY
}Y

;G £rpA£
)
M M i

j FIRST IDENT.
j NO. USED i

(USE. TABLE A)
&- /Vjr™
^l (ujfl;^

i i

5-03-00



^iw
. LJ_._L 1 _L1 I _J l-t-L.--!-. 	 J— U- 	 Ul- ' 1 L L'l

'4



L
SOURCE SAMPLE REQUEST & REPORT ' ^['
(MUST BE FILLED OUT (OR EACH TEST RUN) ' ' "i"
TFST HO 7^ /^^ /_. I'!
ILAST IDENT. • . ' :!.
fzt INO.USED S-K-cotf - *36 . RIIH Nn /^ • -f




, . DESCRIPTION OF
SAMPLE OR .SAMPLE
FRACTION
'rV.ii.£_ ' v.o.c
^-vVr_W_l©


,^ve,^
dW i,o,iax

-fr^W^e; \J-vJO_*,



rt (^bc
v_

,
|



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i
COMMENTS:








*
UNIT PROCESS. OPERATIC
AIR POLLUTION CONTRC
FUEL USE
C INLET fX.0
GAS VOLUME SAMPL
(METIER VOL IN FT^
SAM
WT.
(SOLID)
MG










P.E
VOL
~ (LIQUID)
ML
•









n / ' j 4- • ' 4
N /Ni'm« U3^vX [.!
IV* c' jj_j_
ii A^I(° [it.
D r.f
JTLET ^^ ^ ' T'i"
-n 2 .-5 • 3 • • L ,_
) j|_
ANALYSIS REQUESTED - GENERAL COMMENTS 17 1
(APPROX CONCENTRATIONS • POSSIBLE INTERFERLNCES r-f
ETC) (INDICATE SPECIFIC ANALYSIS ON BACKSIDE) • '\
* )

IflA.^^ />^?if'/."!fr>«: ' ! •» 1
/ V/- ^- ^ J ,r |
^i

o I
** 1
iM

tlj
i •• i
17
] j i
"=1
3 !
•sl
i ! -1-
SAMPLING
CONTRACTO
DATE OF REQUi
R
1ST


*
'•Ml*
(IF APPLICABLE)


HATF

PROJECT
UNALYSiS
OFFICER 	 L
REQUESTED
/wi^ kin, ;PEsn RV Ma/n/75 II


;
DATE OF REOUFST ' ^J
(TO BE FILLED IN BY SSFABi = j
n
-------
                                                                                         REPORT OF ANALYSIS
                                                                                           TRAC€  ILEMENT3
                                                                                         ppm •  kir  -.olid samples
                                                                                        ug/ml • for liquid samples
Merit o.i lor sccci'ic  or.jj'ysis-          '   '
\:,'A (ti in biocX  to  !*!; c! i;o".t. 'ij.  v.i.er.
requesting  all cr.oiysis on tnct  line
Ident Mo.









.
Hg
j L

' J L




J L
J L
J Li
Be
J L
.
Cd
J L
J LJ L
J L
J L
J U
U LU L
U L
H L


J-L
J !_
j 1
J L

J L
J L
J L
J LJ
J L
As
J L
J L
J L
V
_
J
J
L
Mn
J L
LU L
rujnTi
J LU L
J L
1 |

J LJ L
UTL
:rc
J L
TH
J L


i
J L
ITQ
JL

A:;ciyj:s f.'s'.r.os: 1-riAA, 2-SSMS. 3-Of.S
J L
J L
J L
J L
J L
J L
ITL
Ni
J L
J L
J L
J L
J L
J I.,
J L
J L
J L
J L
Sb
J L
J L
J L
J L
J L
J L
J 1^
-I LJ
J L
Cr
J L
J L
J L
J L
J L
J L
J L
J L
J L
J L
Zn
J L
-1 L,
J L
J L
J L
J L
Cu
J L
J L
J L
J L
J L
Pb
J L
J L
J L
J L
J L
Li LU L
J LU L
J L
J U
J L
J L
J L
J L
J L
J L
J L
J L
Se
J L
J L
J L
J L
J L
J L
J L
J L
J L
J L
	 , — . —
J U
J
UH
J L
J L
J L
_l i_
J. L
J u
J L
'•
J L
TL"
J L
J L
J L
311
Li
J L
J L
J L
J L
J L
J L
J LJJ L
an
J U
[j L
•
J L
J L
J L
Ag
J L
J L
J L
J L
J L
J L
J L
J L
J L
J L
Sn
J L
Fe
J L
Sr
J L
J UJ LJJ L
J UJ L
J L
U L
J L
J L
J L
J L
J L
J L
J L
J L
J L
J L
J L
J L
J LU L
J L
J L
J L
J L
J L
J L
No
J L
J L
J L
J L
J L
J L
J L
J L
J L
K
J L
J L
J L
J L
J L
Ca
1 1

Si
1 1

J LJ L
J LU L
nn
J L
J L
J-L
Mg
J L
J L
J L
J L
J L.
J LU LU LU L
J LU LU L
JLJJLJL
J LJJ LLJ LJ
J LU L
JLJL
J L
Be
J L


ULJL
J LU LJJ L
J UJ LJJ L
J UJ L
j i 11

1 1


! i

J LU L
J LU L
1 i

J L

M

J L

J L
1 !

J L
J L
^ L
J.L
_i i_
Hu
1 1


J L
1 I;::'
J L
zrcj-Li "— i
J L.J U
J 1 J LI

J L

1
J U
1
J LJ L
J LU L_|
JUJL
J LU U
J LH ^r* h
, 4- A A, 5-ASV, 5-XRf, and 7-oliier . ;-' Comments: -

: • . - ' - • . i
Q;r-er Analysis • Use Tcble B lo (HI analysis requested (above each column) •'•' - ' . Work (xi for specific onsiysis rs>"uei;?a
Iden! No.


1
I


•






'

J
	 1
J -• •
J
u

_J .
_J .
J
^J •
u
U - LJ
• u '•


j
A.-CiyS! .
"5th3d
J
u
_J


J
J
J
J



J
J
^J
J
u
J
J
J
J
J



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Comments:
-------
[
-LLL.I  J_LL!   !   !  !
 ____ _ _____ ___
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                                                                 67 | 6« I 69 | 70 \ 71 | 72 | 7> |"><
                                                     SOURCE SAMPLE REQUEST & REPORT
                                                     (MUST BE FILLED OUT I:OR EACH TEST RUN)
              •"!
  SAMPLING DATE  j £,'• <\
              j YR i V.O j DAY'
FIRST IDEMT.
NO. USED
                                                 00 if -
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                                                                     !NO.USED  s-93
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                                                                                          RUN NO	//
                                                                                             ///]$  /
       INDUSTRY.


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       ADDRESS .



       METHOD
                             (USE TABLE A)
                                    \
                              UNIT PROCESS OPERATION.^,
                                                               AIR POLLUTION CONTROL
                                                                                         n/  \t>   Q:T/ M'

                                                                         FUEL USED.
                       FP fl  S  ( M> \ I .>rf      W I
                                                   7
                                   GIMLET  -}C OUTLET
                                GAS VOLUME SAMPLED	// ^ ' '
                                 (,VE;TZR VOL IN
IDE.'iT NO
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DESCRIPTION OF
• SAMPLE OR SAMPLE
FRACTION
prcbv \xA~e * \.^c\^
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                                                                                                                                         h
    SAMPLING
    CONTRACTOR-
                 -PROJECT OFFICER-
                        .  (IF APPLICABLE)
                                                                                                      REQUEST
                                                                                                      -REVIEWED
                                                                                                                                         rr
DATE OF REQUEST.
                                             .DATE ANALYSIS REQUESTED	.	
                                                                DATE OF REQUEST..
                                                                                                                (TO EE FILLED IN BY SSFABi
-------
                                                                                             REPORT  IIP ANALYSE
                                                                                           •    TRACii  -XEMEIiTS
                                                                                             pprn - lor ;olid samples
                                                                                            ug/m1 • lor liquid  samples
                         Mcf'i< (>i !ot sr,eci!>c C-M-I/S'*
                         t.'.ci'K (xi in  blow io lii'i of  !•:•:":. '>o. -'..-en
                         requesting cil  Gr.G!',sis or, thai  lire
cnt Mo.








!
i
Kg
hj "-i
J L
P L-
J L
Be
J L
Cd
J L
TC
AS
J L
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J L
1TUUL
J~LU L+J UJ L
J LU L
J r.j j L
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J L
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U L
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J L
J L
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J L
J L
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Mn
J L
J L
J L
J L
J L
J L
J L
J L
J L
Ni
LJ L
J L
J L
J L
J L
J L
r
J L
J L
Sb
J L
J~C
J1 L
J L
J L
3 E
J L
JT-
Cr
J L
J L
r1 L
J L
J L
J L
J U
U L
J U
In
J L
J L
J L
J L
J L
J L
J L
J L
J L
Cu
J L
J L
r-1' L-
J L
J U
J L
J L
J L
J L
J L
Pb
J L
J L
J L
J L
J L
J L
J U
J L
J L
J L
Se'
J L
J L
J U
J L
J L
J L
J L
J L
J L
J L
B
J L
J L.
J L
J L
J L
J L
J L
J ;_
J 1~
. r'
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J L
J L
J L
J L
J L
.J L
J L.
lire
J L
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J L
J L
J L
J L
J L
J L
J L
J L
J L
Ag
J L
J L
J L
J L
J L
r-l L
LJ L
J L
J L
J L
Sn
J L
U L
Fe
J L
J L
J UJ L
J L
J L
J L
J L
J L
J L
J L
J L
J L
_j L
J L
J L
J LJJ L
Sr
J L
J L
r1 L
|J L
J L
J L
J L
J L
J L
J L
No
J L
J L
J L
J L
J L
J L
J L
J L
J L
J L
K
J L
J L
J L
J L
J L
J U
J L
J L
J..L
4L
Co
J L
J U
Si
J L
Mg
J L
J LLJ L,
J LU L
1 |

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1 1

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J L
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J UJ LU L
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Analysis Method:  1-NAA, 2-SSt.'S, 3-Of.S, 4-AA,  5-ASV, 6-XRF, and  7-other
Comments;.':'•
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                 C. liTl .
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                                                                      Sincerey  ycstsrs,
                                                                                                                  it
                                                                                                    ^  ^
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-------
January 4, 1974
Dr. Richard J. Thompson
Chief, Analytical Laboratory Branch
Quality Assurance and Environmental.                       .  .
   Monitoring Laboratory
U.S. Environmental Protection Agency
Research Triangle Park, North Carolina 27711
                                                          *
Dear Dr. Thompson:                           • •    .

Analyses for ashestos content of Samples 507, 503, 509,  516,  517,  528 sr.d 529
                                    ,          -           j     u.    uo
October 29, 1973.  The analytical procedure and  analytical results  are
presented in Appendix A.            •       .          '  •   •

If you have any questions please call  me at Extension 3397 or Carl  Melton
at Extension 2781.

Very truly yours,                   .                       :
R. E. Heffelfinger
Associate Manager
Analytical Chemistry Section

REH:uha

Enc.

-------
                                 APPENDIX A ;









                            ANALYTICAL PROCEDURE









                               Liquid Samples






          An aliquot from-each of the liquid samples numbered 597, 509, 516




and 528 was filtered on a tared membrane filter and the  collected parti-




culate matter was dried and weighed at 50% RH and 72C.  Carbon was vapor




deposited over the surface of the filter, the filter was dissolved away in




acetone and the carbon film was placed in the 'transmission electron microscope




where fiber counts and measurements of fiber lengths and widths were"made




at 12COG x magnificat:ion over kncwa areas as defined by 200 mesh, openings in




an electron microscope support grid1.  Also in the electron microscope identi-




fication of asbestos species was established by selected area electron diffractiur




and fiber morphology.  Only those particles having an aspect ratio of 3:1 or




greater were defined as -fibers.




          The volume of each fiber was computed by multiplying the width




squared times the length.  The mass of asbestos species was obtained by




multiplying its total volume in the sample times the density of'the asbestos




species (density.of araphibole =3.4 and that, of chrycotile = 2.56).  Then




the weight percent of asbestos present in the sample was calculated by dividing




the mass of the asbestos by the weight of the dried particulatc.




          Fiber length distribution is presented in graphical form which




expresses cumulative percent by number  vis. the average fiber lengths




assigned to si::e classes.  The point at whir1-, c'ae curve intersects 507. on

-------
                                             T
on the graph indicator the mean particle length with respect to fiber popu-




lation in the sample.






                               Filter Samples






          Filter samples 503, 517 and 529 had been weighed by EPA and the




weight was given on the sample envelope; consequently, no weighings of the




collected particulate were made in this laboratory.  Rather, to obtain an aliquo!




of the sample for analysis, asmeasuxedirxadial section was taken from each filter




sample.  The aliquot was low-temperature asked and redeposited on a 25 mm




membrane filter where it was coated with vapor deposited carbon.  As in the case




of the'water samples, the filter was dissolved away and the carbon film bearing




the particulate was examined in the transmission electron microscope.  Asbestos




species were then identified, and.length- and width measurements were made for




the purpose of expressing resx^V^^^yS'^iiai-^inglA'distribution and mass of




asbestos present in each sample.   '    .       .           '






                               Results of Analyses
          Analytical results are presented in Table I and Figures 1 through




8.  Table I lists samples and mass of asbestos in each sample.   The figures




are plots of cumulative percent by number, vs. fiber length in Jim.

-------
. TABLE I.  ASBESTOS MASS DATA
Weight of Dry Mass of Asbestos, ug "/, Asbestos in Ssr.ole
Sample Description Sample Particulate Chrysotile Amphibole • Chrysotiie Amptnuole
S-73-004-507
(Run No. 1-C)
, f
S-73-004-508
(1000005A, Run 3)
S-73-004-509 ' ,
(Bubbler No. I, Test F6-3)
S-73-004-509
(Bubbler Ko. 2, Run No. 1-C)
S-73-004-516 .'-
(Probe Wash P-3)
S -73-004-517 -.':. .
(1000003A, Run 6) .-
S-73-004-528 •
(Probe Wash P-7) .
S-73-004-529
/•innnni9A Pi,n in}
0.0117 g ' 0 775. 0 6.6 7.
" • " *
0.0150 g -0 875. 0- 5.8 7.
0.00122 .g . . ',.'• 0.17 ' 0.4 . . 0.013 .0.033. .
0.000562 g \5 • .. 0.14 1.5 0.025 0.27
0.2690 g ' 2.3 470, 0.0009 ' 0.2"
1
0.0253 g * 0 175. 0 ' 0.7 '
0.0704 g 0 212. 0 0.33
0.0107 g' 0 71. 0 ; 0.7

-------
 09.0'.' [""JT'

       ijii
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    98





    95




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 QJ



53   e°
    70
4J
C

o   co
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PH   50

    0.4  0.& 0.0   0.0   I             334

                                Particle  Length, Micrometers
                                                              6   7  0 
-------
  09.'.
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                                         )  t
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            0.5   0.4  0.
                        5  0.6   0.0  I             2        3     «    &   6  7 0  9 10


                               Particle Length, Micrometers
                 FIGURE 2.   'Sample S-73-004-508, 1000005A,  Run  3

                              Asbestos  Type:   Amphibole
-------
                                     I   ! !
                                                               1—r
                                                                                UJ-L
      11 Jl
                                                 t-;  M i
 99.9
             ,„..
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                 0.4  0.5  O.G   0.0   I             254


                              Particle Length,  Micrometers
                                                                     6  7 0  9 10
                FIGURE 3a.   Sample S-73-004-509,  Bubbler No.  1, Test FC-3

                              Asbextos Type:   Amphibole
-------
 09.99
  99.9
                                              Mil!
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 JO.OI
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                              i  !
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                              11
     O.E     O.J   0.4  O.'j 0.&   0.0  I            E       3    4

                            Particle Length,  Micrometers
                                                         c  7  o  
-------
                                                 "T
09.09
 99/J
                                   .! J..JJ.
                                                  MM'
                                                                              -IJJ.
                                                                                    I  !
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                                                                           ;..—'....zn. .i-.l T".._r.
            l-!ii

                                       T
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                             HI;
                                                                            -l-i-H
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           0.5   0.4  0.1) 0.6
                             O.U   I            2       5     4   rj  0  7  0  9 10
                             Particle  Length, Micrometers
                FIGURE 4a." Sample S-73-004-509,  Bubbler No. 2,  Run No.  1-C
                           •  'Asbestos Type:  Amphibole
-------
 ".n r.r.
 / V •!' */
  09.0
       •JU
                                                       ......... 1
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                                            MM
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                                                  T1:'
 •  99
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   80
   70
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 O.OI
      111
                              TIT
-rr r
0.2     0.}   0.4  0.5 0.6   0.0   I            'i.       i    4

                         Particle  Length, Micrometers
                                                                 6   7  0  9 10
               FIGURE  5a.   Sample  S-73-004-516, Probe Wash P-3

                            Asbestos Type :  Amphibole
-------
ii9.D9r.
 JO.OI
                          0.0   I           23
                           Particle Length, Micrometers

               FIGURE 5b.  Sample S-73-004-516,  Probe Wash P-3
                           Asbestos Type:  Chrysotile
                                                                               20
-------
09.90
  99.9
      ~t^*y* +rrtf^rt,
      I i j i  ; I:,
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     o.e     o.s   0.4  o.o O.G    o.o  i             2       3     i    o   6  i o 9 10
                              Particle  Length, Micrometers

                 FIGURE 6.   S-73-004-517, 1000008A,  Run 6
                              Asbestos  Type:  Amphibole.
-------
                           ^liiiigzpifjqziif
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     0.2     0.3   0.4 0.0  O.G  0.0   I           2      3    4   &   C  '/ 0 » 10

                           Particle  Length, Micrometers


                FIGURE 7.  S-73-004-528,  Probe Wash.P-7

                           Asbestos  Type:  Amphibolc
                                                                                 20
-------
09.09
 99.9
      Tli
      -jli
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                                               •i i! i!

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 80


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                                                                                   :|:-?i.:_:
                                        ;   mi
                                                                            -rr
          O.i   0.4  0.5 0.6   0.0   I            234
                            Particle Length, Micrometers

               FIGURE 8.  S-73-004-529,  1000012A, Run  10
                           Asbestos Type:  Aniphibole
                                                                   6   7  0 9 10
-------
                                                          C'olunibii-. (.'Inn •' 1J01
                                                          Tek'pnoTio •''H- J'>'MT>1
March 13, 1974                                            T,-U.X.M-:,IV:
Dr. Frank P. Scaringelli
Environmental Sample Analysis Section
Analytical Chemistry Branch
Environmental Protection Agency
Research Triangle Park, North Carolina 27711

Dear Dr. Scaringelli:

This letter is in response to your request for clarification of data reported
in the letter report to Dr. Thompson dated January 4, 1974.  The report
concerns samples 507, 508, 509, 516, 5175 528, and 529, which are described
in Dr. Thompson's letter dated October 29, 1973.  It is my understanding
that you want to know (1) the original .volume of each liquid sample received
(2) the calculations .employed to obtain reported values including aliquots
taker.,, etc. and  (3) an explanation of the cumulative size-frequency curves
shown in Figures i chrougn 8.      .

The original volume of each liquid sample was measured and recorded and are
given in Table 1;  Subsequently, all samples as received were placed on
rollers for one hour to disperse the particulate uniformly before removing
an aliquot.  Then an aliquot was removed, diluted with water, and 0.1%
aerosol OT was added to promote the dispersion of particulate.  The diluted
aliquots in plastic bottles were rolled for three hours, and several aliquots
from each sample were deposited on 25 mm Millipore HAWP (0.45 y, pore size)
filters to be able to select a suitable concentration of particulate for
counting and measuring asbestos fibers in the electron microscope.  The
filters bearing the deposited particulate were coated with a carbon film
by vapor deposition, a piece was cut from each carbon-coated filter, and  the
filter was dissolved away to leave the particulate supported by the carbon
film which was then placed in the transmission electron microscope where
measurements and counts of amphibole and chrysotile asbestos fibers were
made at 12000X ove.r areas delineated by 200-mesh electron microscope
suppor t grid openings.

The ratio of the area of the filter over which particulate was deposited  to
the area of the grid openings over which the measurements of fiber lengths
and widths were made is the factor used to compute the total population and
mass of asbestos in the aliquot deposited on the 25 mm filter.  In each
case the diameter of the deposit on the filter was 17.6 millimeters  (8.8  mm
or 8800 u radius) and the area of one grid 'opening was 90 x 90 u = 8100 ^m
-------
Dr. Frank P. Scaringelli              2                   March  13,  1974


Therefore, the calculation of the  factor became

                  TT  (8800 u)2	
                    8100 u2 x no. of grid openings;
                 •  •. •       •-..-.     •. •   •   4    .  .•     '    ...-.••..•
for one grid opening the factor is 3.0 x 10  which we have named grid area
factor/filter.  Further calculations to obtain the concentration of fibers
in the original sample from the aliquots taken in  the case of the liquid
samples are exemplified by the following case  (Sample 507);

          Step 1 -  30 ml were removed from original sample and
                 •   diluted to 200 ml

          Step 2 -  A 5 ml aliquot x^as removed  from the 200 ml diluted
                    sample then diluted further with filtereddeionized
                   water and the entire quantity of particulate
                    contained in this 5 ml aliquot was deposited on the
                    25 mm filter to create the dispersion from which
                    fiber counts were made.

That volume of the  original sample deposited over the effective filtering
area was therefore: . 5 ml/filter/200 ml x 15 ml = 0.375 ml/filter.
Consequently, -..'her.  SO air.phibolc fibers were found over the area of 2 grid
openings the calculation of tne numoer of "tibev ?>-per miiiiiiter or original
sample is                          .

                       3 x 10  grid area factor/filter     80 fibers
                              0.375 ml/filter           X  3 grid areas

     = 2.13 x 10  fibers/ml.  Since the original volume of the sample was
measured to be 108 ml, the number of fibers in the total sample is 108 ml
sample x 2.13 x 106 fibers/ml = 2.31 x 108 fibers/sample.

Length and width measurements to 0.1 y, were made on individual fibers and the
volume of each fiber was computed by multiplying the length times the width
squared.  The volumes of all fibers measured within a sample were totaled,
multiplied by the density  (3.4 for amphiboles and 2.56 for chrysotile) to
obtain the mass.  Then the value obtained for r.he mass of fibers measured
was multiplied by the aliquot factors to get the total mass of asbestos per
ml of sample, and. in turn multiplied by the original sample volume to get
the mass of asbestos in the sample.  One cubic micron multiplied times the
density yields results in picograms.which was more conveniently converted to
micrograms for reporting.  On this basis the 80 fibers measured in Sample 507
were computed to have a mass of 269 p.g..  Therefore the total mass of
-------
 Dr.  Frank P.  Scaringelli       '       3            '       March 13, 1974

                                                    4
   i- • v  i   j   _L   i no  i   c _L. • •     i         3 x 10  erid area factor
 •amphibole In  the 108 ml of this sample were  .	—°-r-.	  x
                               .     v              3 grid area

 108  ml/sample   nrr.        -, -,,   •, rt8 „  /    ,    -,-,f    ,    .
 -    —r-1	 x  269 p.g. = 7.76 x 10  P g/sample = 776 ug/sample.
 Since it was  found impractical to weigh accurately the small quantities of
 particulate filtered for electron microscopy, larger aliquots (approximately .
 1/4 of the total sample volume) was deposited on tared filters and weighed.
 Then the particulate loading for each sample was calculated in ug/ml.  This .
 figure was used to compute percent asbestos in the dry particulate.

 In the case of the filter samples submitted by EPA, the weights of collected
 particulate were obtained by EPA and were recorde'd on the sample envelopes.
 On the assumption that a radial section cut from the filter would provide
 a representative aliquot, a 45  radial section was cut from each filter.
 Because the filters contained nylon webbing support which is resistant to
 low-temperature ashing it was necessary to separate the deposit from the
 nylon webbing.  This was done by placing the 45  filter section in a test
 tube where it was washed with acetone to dissolve the filter substrate and
 also to wash  the overlying deposited particulate from the nylon support.  The
 acetone was allowed to evaporate in a laminar flow clean hood and the test
 tubes containing the dried residue were placed in the low-temperature asher
 for 72 hours.  Then the resulting ash residue was suspended, in 500 ml of filtered
 deionized water to which 0.17, Aerosol OT was added to promote the dispersion
  /?.•  1 „ «- .^ *. ~ A. I.  r. *.	 1    *. — — 11 J f-~~. / t -  _ _ .1 • 1 -   ,*..'.  V •
 or paTtiCMlcttc C.G tr.c ccir-pic "rcic r^-1-.^o *.v± -<• liuuiTa WHJ..LC UWULCIXIICU i.u a
 1000 ml Nalgene plastic bottle.  Afterwards aliquots were taken from the
 500 ml suspension and filtered to deposit several different densities of
 particulate over. 25 irsn HAUP Millipore filters in order to be able to select
 an appropriate concentration for counting and measuring in the electron
 microscope.  The fiber counts and measurements were made in the same manner
 as for the liquid samples; the calculation based on the ratio of effective
 filter area to area of the 200-mesh grid openings over which measurements
 were made is  the same.  Since 45  or 1/8 of the .filter was taken and the
 particulate dispersed in 500 ml of water from which aliquots were taken,
 this aliquot  factor is

                        500 ml	    -                .          .            .
                        volume filtered

 The data required to make the discussed calculations are presented in Table
 1.

 The size-frequency curves shown in Figure 1 through 7 in the January 4, 1974
 report: were generated by assigning length measurements to size classes,
 calculating the percentage of the total number of fibers represented by each
.size class and plotting the average length within a size class versus
 the cumulative percent by number to 'obtain a 'length distribution.

 Included in this report are clearer Xerox copies of the plots than were
.supplied in the January 4, 1974 report.
-------
Dr. Frank P. Scaringelli              4           •        March 13,  1974
If you have need for further data please contact me at Extension 2781 or
R. E. lleffelfinger at Extension 3397.

Very truly yours ,
Carl W. Melton
Staff Chemist
Analytical and Physical Chemistry Section
   : aha

Enc.
-------
                                                                         TABLE I.  DATA A)ID CALCULATED RESULTS
S«-ple No.
S73-W-507
S73-OOi-503
S73-0'>;-503
(iiibbltr No. I)
S73-'W-509
(r..jVjUr No. 2)
S7J-004-S16
S73-CO'.-517
S73-00;-52e*
S73-C04-523'
573-00^-529
Ai Received
Sample Vol.
{nl)
108 nl '
-
179 ot

148

224
- .
241
«l, .
-
AHnuots
Orlgln.il
Sjrcplc Vol. Taken
(or Filter Section)
IS 'ml
45° Section
25 ml

25 nl

25 nl
45 Section
25 ml
10 ml
45° Section
Diluted
to
200 nl
1000 ml
100 nl

200 ml

600 nl
1000 nl
600 ml
400 ml
1000 ml
Filtered
Volume
5 ml
20 ml
70 nl

14S ml

2 nl
20 ml
2 ml '
4 ml
20 nl
Weight Of
1'articulate.
in Orig. Sump; 11
100 ug/ml
0.0150 g/ftlt.r
6.86 eg/ml

3.8 kg/ml

1202 Hg/ml .
0.0253 g/fllttr
292 ug/ml
292 ug/ml
0.0107 g/fllUr
Fibers Measured
Ch Am
0

0

15

17

14

0

0

0

0

80/3 Grid
Openings
101/2 Grid
Opcnlnp.3
51/6 Grid
Openings
57/5 Grid
Openings *
28/8 Grid
Openings
57/4 Grid
Openings
14/6 Grid
Openings
11/8 Grid
Openings
18/7 Grid
Openings
Miss of Measured Fltier*
Ch' An Pg
0

0

0.33 Pg

0.31 Pg

0.23 Pg

0

0

0

0

269 Pg

146 Pg

7.2 Pg

33.9 Pg

47.1 Pg

58.2 Pg

14.0 Pg

26.1 Pg

41.6 Pg

No. of FlherWS.T.ple
Ch Aa
0

0

7.7 x 10J

7.8 x 10S

1.4 x 108

0

0

0

0

2.3 x 108

6.1 x '10*

2.6 x 106

2.6 x 106
_ — -
2.8 x 108

1.71 x 108

2.0 x 108

1.0 x 108

3.1 x 10*

f.v «/S,v.-le
Ch
0.*

0

0.17 I..

0.14 p.-

2.3 us

0

0

0

0

A3
775 ug •

875 wg

O.J ug

l.S ug

471 Mg

ITS ug

201 ug

234 ug

71 ug

*   D-.pltcotc deterolnatlons. •
Ch- C-.rysotllo
-------
APPENDIX D



 Test Log
-------
                                                   SAMPLING TASK  LOG
Plant    A •/.•,-<'
Plant Location
Date -Hi i/7S
. Comments
$J'^r t' — , "i ••/ ;.:i,tf •/',£,•?,<"#•
•j ' • l; 1 .' •'• i " - • - /
/Jj--".[-i! y- ••'•'.:•.'.•••,'•• •?,/• '-•.•.(_ rM//.j/'c.iJ
? J •
" r /! . ^' ' ^
J,,/i /,, ,;.,...,.. ".,,. .^ /...:,(<,/.,„. .. ./,
. • -
,./:/>,v,// ,^,^.4;,;.
^ < /. / ' " •




*












Run

1
7'
£
;?_
"*.'
^
3
















Recorded
Sampling location
(Port)

/,--vu 2-7
" >l ' 1 (.', -^ //'—/* ^
•/" y f /
,_,,,;- 5 >o--/<
-.•':.'/ ^7-C-
/>'i-f >
',;.''/,./ 7
'















by LO ,
Pollutant
r-/- (/>.-"
-
..
,.
i.
..
•.
•/
















l6-:"'Pi. '"
Vi
Clock
Beqan
f '-
ic°-'r
I a2-7
/-'
n ° V
j
-------
Plant
Date
                                                   SAMPLING  TASK LOG
                Plant Location
                Recorded by
        Q -Q     rj
        />•<"/• '  -L
\5
 tft
                   'Comments
       Sampling location
Run        (Port)
           Clock Time   Elapsed      Sample
Pollutant Began  Ended Time (min)     Nos.
i 1 /• / ,' ' •' f' '/
,*;«.:t >f.'.i ,-;.>.-/ y. A-/,.-.-/5 /v' '
y v • /' • <
O /A ;>'. .' '• , -.' :,','.-•
(J ' \'
A ::-r.&'v/ J ">; r /' •.•'•- -,/>-• .- V ,v . x ^ . v «. ";",( •
, ' . ' ' ',' • ' ' ' ;
^ //-,../ ' ?hc-£ O.tf.
•&,-/•< -:^.,,Jl:. ,/./,'/-/, A A'.
' ' U
/nu/^^./ ^A.-V.-^ '/.S'V.'.-d
A ' A ,- ' '/: •
(_/>TVI r K/ /"/ v ••"> :•-• •• '-t. .' i- ^
no. / 1 v. • >!/ y / •, .,, v---
,; '< ,.'{ .•• • - v7
..'.• v>. .. \ t- r. . ; , K •













V
V

5
5
6
. C
£
6
"/'
7













^ /-6
' ^- 7 - / ?-

,-••'• /-£
/ / •
^j /-6
^.•f' '/-/?
'
o/-/'2.
,.-/-- /-c-
'/,/l 7_/?













t7;/v •.
-?YlAiA

'in^-'
i '
„
,.,
..
••
;.
; t











'.a •"'•'
/.i? A:'
/^'
//-D/

^ "r
3®
J/a
'/•3--'
j/^
i/ "
V-*
4 ^







A7^-
. /:, :->
/^^
II-

-. ^S
ii
^
.:/ '£/•
-'/ ^
J./-&
6^
oy
7 "







i








/ 7
3

!?
>$
• 1?
12-
—
7
ft
IP











.
'
*/ -lib -'/-Si 2.


V^/.>-f;-/5

'/5/6--X5'/
-------
SAMPLING TASK LOG
Plant Kv;r--.'< •')]'.' •,;;•/•('
Date oA-:-'/ j.-'"' ,?/ /AvX ••'.•/'
,>''-/ .^ '/•'' • r /r /-• 'V i;/i"/
(" r ' ^ •' y '
-" V / •, ' ,.')•••• .'
<-
' , . ' •* — f ;
l'.- r;. '.'
iU ,.,.„',.:
.;'••. .v. •'.> ->•.•:•. i'., V •


>)!*.fj< /.- r.-rfV '.^--. ••'"'.'i''. >
•t'C^ /.yv • /) /••' . \>£'-i •;''<• i
i^..&. ' ', : '>..-.'.. J-'
j
t'.\vv.-.j /v-/ . 7'/l:i^.
by /, j, /K/^.y ' ' - •
Clock Tine Elapsed Sample
Pollutant Began Ended Time (min) Nos. .



7/^,00
r
,..
ii
«,
/•
,:
i 1

II
1.
, •









1 !^
u
/t •'-
/^ •"'
/./ -'
//'•*
/;--
It'8
n'11
'/ ~^.
\ 0
3 ~~~~
^
5- #
5 -:'
^^
^ •"







}7
/£? -

//C'
II-
/! -'
// :- '
/,-' •' '
/25'
0'°
:?•-•
o
5 //9
/.- %J
(o **
: j~ "
7 ^'










/(;?
/
-------
                         .APPENDIX E

                     Project Participants


Winton E. Kelly --Environmental Protection Agency, .QAQPS., ESEDj EMB,
                  Project Officer

Edward Vincent -.Environmental Protection Agency, OAQPS, ESED, ISB
                 Project Engineer

Earl Schulz - Battelle-Columbus, Test Team Leader

Bob Poling - Battelle-Columbus, Sampling Technician

Ben Furnace - Battelle-Columbus, Sampling Technician

John Faught - Battelle-Columbus, Sample Cleanup Technician
-------