&ER&
United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park NC 27711
EMB Report 79-OCM-15
April 1981
Air
Benzene
Organic Chemical
Manufacturing
Ethylbenzene/Styrene
Emission Test Report
El Paso Products
Company
Odessa, Texas
-------
SOURCE TEST AT EL PASO PRODUCTS
ETHYLBENZENE/STYRENE PLANT
ODESSA, TEXAS
Contract No. 68-02-2812
Work Assignment No. 52
Project No. 79-OCM-15
EPA Technical Manager: Winton Kelly
Prepared for:
Emission Measurement Branch
Emission Standards and Engineering Division
U. S. Environmental Protection Agency
Research Triangle Park, North Carolina 27711
Prepared by:
TRW
Environmental Engineering Division
P. 0. Box 13000
Research Triangle Park, North Carolina 27709
-------
TABLE OF CONTENTS
Section Page
1.0 INTRODUCTION 1-1
2.0 SUMMARY AND DISCUSSION OF RESULTS 2-1
3.0 LOCATION OF SAMPLING POINTS 3-1
4.0 SAMPLING AND ANALYSIS PROCEDURES 4-1
APPENDIX A - SAMPLE CALCULATIONS AND RESULTS A-l
APPENDIX B - FIELD ANALYTICAL WORKSHEETS B-l
APPENDIX C - FIELD DATA SHEETS C-l
APPENDIX D - TEST LOG D-l
APPENDIX E - FIELD AUDIT REPORT E-l
APPENDIX F - PROJECT PARTICIPANTS F-l
-------
1.0 INTRODUCTION
During the periods of September 24th through 28th and October 1st
through 5th personnel from TRW Environmental Engineering Division,
Energy and Environmental Analysis Incorporated (EEA) and the U.S.
Environmental Protection Agency's (EPA) Emission Measurement Branch
(EMB) conducted tests at El Paso Products' Ethylbenzene/Styrene plant
located in Odessa, Texas.
This facility was tested in order to obtain and analyze samples to
provide data in support of possible National Emissions Standards for
Hazardous Pollutants (Benzene) and New Source Performance Standards
(Organic Chemical Manufacturing Industry).
Two process heaters were tested at this facility; the steam super-
heater and the hot oil heater. Samples were collected to analyze the
fuel and exhaust gas from each device. The purpose of this testing was
to determine the destruction efficiency of benzene in these combustion
devices and to determine benzene concentration and total flow into the
atmosphere of this pollutant. All sampling and analysis was performed
at the El Paso Products plant by TRW personnel. Plant operating data
was obtained by personnel from EEA. The entire operation was monitored
by EPA EMB personnel.
-------
2.0 SUMMARY AND DISCUSSION RESULTS
The sampling and analysis data at El Paso Products were obtained
from two separate process locations. The first week was spent sampling
and analyzing the fuel and the outlet gases from the steam superheater.
The second week was spent collecting data from the fuel gas inlet and
the exhaust gases of the hot oil heater. The hot oil heater and the
steam superheater are diagrammed in Figure 2-1. Points one and two were
sampled simultaneously and points three, four and five were sampled
simultaneously in order to determine the benzene destruction efficiency
of the combustion processes. Figure 2-1 shows the sampling designations
next to the sampling point number. Samples were analyzed for:
a) C02, 02, N2, H2, CH4 by GC/TCD.
b) Benzene, toluene, xylene, ethyl benzene, styrene
by GC/FID.
c) Low molecular weight hydrocarbons as Cj-Cg
species by GC/FID.
d) Total hydrocarbons as benzene by FID.
e) Moisture content by EPA standard method.
®
Samples were collected in tedlar bags utilizing Teflon sampling
lines. The sampling apparatus was precleaned and pretested to eliminate
aromatic background concentrations. The samples were analyzed the day
of collection to minimize sample degradation.
The analysis of the fuel gases by GC/FID indicated that a saturation
effect of the detector occurred when more than 5 percent total hydro-
carbons were introduced. This affected the Cj-C6 system only and methane
was the component most affected. For that reason methane (Cj) was
determined by thermal conductivity. For the remainder of the components
-------
(2) ABO - X
Flue Gas
Hot
011
Heater
Fuel Mix
(1) ABI - X
(5) SHO - X
Flue Gas
Stean
Superheater
I
Ethylbenzene Unit Off - Gas
Natural Gas
Tuel
Mix
Drum
From Fuel Mix Drum
3-1 <»> FGI - X Fuel
Gas
(4) 061 - X Dehydrogenation Off - Gas
Figure 2-1. Sample point schematic.
2-2
-------
this saturation effect was remedied by diluting the fuel samples 100:1
with nitrogen before analysis. The dilutions were performed on a rotameter
dilution board and the results were checked by using 02, CH4, and H2 as
internal standards which were verified on the thermal conductivity
detector. Since the outlet samples were of lower concentrations, they
were injected directly in the GC/FID.
The previous discussion has encompassed the overall sampling project.
The following discussion will concern itself with the individual processes,
the steam superheater and the oil heater, respectively.
2.1 STEAM SUPERHEATER
Five one-hour integrated grab samples were taken simultaneously at
each of the two fuel inlets and at the flue gas outlet. Run one at the
superheater outlet (SHO-1) was invalid due to a leaking bag. Each bag
was analyzed for the constituents listed in Section 2.0 under (a)(b) and
(c).
Prior to sampling, the outlet of the superheater was traversed and
a sample extracted and pumped to the continuous FID to determine if
there were any irregularities in concentrations of total hydrocarbons
across the stack. The results exhibited very low hydrocarbon concen-
trations at all points of the stack. Noise levels of the monitor were
high due to the vibrations of the stack and minor deviations would have
been hard to detect. Major deviations (>10 percent) would have been
easily detected, however none were detected. The GC analysis summaries
are listed in Tables 2-1 through 2-3. Prior to each sampling run, a
velocity traverse and a moisture determination were conducted at the
outlet of the superheater. These results are listed in Table 2-4.
The superheater operating conditions were not always constant. The
inlet gas analysis shows that the benzene levels dropped as testing
progressed. This data is not in conflict with the plant process data.
The outlet showed <.5 ppm benzene on all tests which would give high
destruction efficiency results on all the tests. The benzene emission
data are summarized in Table 2-7.
2-3
-------
Table 2-1. SWtlARY GAS ANALYSIS - DEHYDROGENATED OFFGAS INLET
AT EL PASO PRODUCTS COHPANY, ODESSA, TEXAS
RUN NO.
DATE
TIME
Species
analysis
C-la
C-2 + C?
C-3
C-4
C-5
C-6
Benzene
Toluene
Ethylbenzene
Xylene
Styrene
TOTAL
HYDROCARBONS
by species
summation
OG1-1
ppmv as
compound
27,550
742
462
28
<0.1
<0.1
5,047
299
4,278
<0.1
<0.1
38,406
OGI-2
ppmv as
compound
25.390
5.659
321
18
<0. 1
-------
Table 2-2. SUMMARY GAS ANALYSIS - FUEL GAS INLET
AT EL PASO PRODUCTS COMPANY, ODESSA. TEXAS
RUN NO.
DATE
TIME
Species
analysis
C-la
C-2 * C2
C-3
C-4
C-5
C-6
Benzene
Toluene
Ethyl benzene
Xylene
Styrene
TOTAL
HYDROCARBONS
by species
summation
FGI-1
ppmv as
compound
923,500
2,419
353
8
<0.1
7
52
<0.1
597
<0.1
<0.1
926,936
FGI-2
ppmv as
compound
923,500
16,260
2,852
<0_ j
-------
Table 2-3. SUMMARY GAS ANALYSIS • SUPERHEATER OUTLET AT
EL PASO PRODUCTS COMPANY, ODESSA, TEXAS
RUN NO.
DATE
TIME
Species
analysis
C-la
C-2 * C2
C-3
C-4
C-5
C-6
Benzene0
Toluene
Ethyl benzene
Xylene
Styrene
TOTAL
HYDROCARBONS
by species
summation
SHO-1 SHO-2 SHO-3 SHO-4 SHO-5 AVERAGES
ppmv as ppnv as ppmv as ppmv as ppmv as
CMpound CMpound CMpound compound CMpound
b 2.64 5.7 <0.1 <0.1 <0.1
0.3 0.4 <0.1 <0.1 <0.1
-- <0. 1 {0.1 cO.l ^0.1 ^0.1
-- <0. 1 ^0.1 <0. 1 <0. 1 <0.1
0.2 <0.1 <0.1 <0.1 <0.1
0.3 0.4 <0.1 <0.1 <0.1
0.3 <0.1 4.9 6.2 3.9
<0.1 <0.1 <0.1 <0.1 <0.1
<0. 1 <0. 1 <0.1 <0.1 <0.1
-- <0. 1 <0.1 <0. 1 <0. 1 <0. 1
3.74 10.7 4.9 6.2 6.4
Inertsc
N.O, X by volume
N_, X by volume
0., X by volume
CO., X by volume
Hj, X by volume
CH^, X by volume
TOTAL (X)
6.28 6.45 5.42 5.60 5.94
82.34 77.81 86.50 76.30 80.74
3.15 4.61 6.60 7.60 5.49
10.69 9.12 9.10 7.70 9.15
NDe ND ND ND ND
ND ND ND ND ND
102.46 97.99 107.62 97.20 101.32
"Measured by a Shinadzu Mini-2 dual GC/FID using Porapak Q column.
Run voided due to leaky bag.
Steasured by a Shiudzu Mini-1 dual GC/FID using SP2100/0.1X Carbowax on 100/120 Supelcoport column.
Tteasured by a Carle 8700 GC/TCD using •olecular sieve and Chronosorb 102 columns.
eNot detected.
2-6
-------
ro
Table 2-4. SUMMARY MOISTURE AND VOLUMETRIC FLOWRATE - SUPERHEATER
OUTLET AT EL PASO PRODUCTS COMPANY, ODESSA, TEXAS
Run no.
SHO-1
SHO-2
SHO-3
SHO-4
SHO-5
Average
Date
9/27/79
9/28/79
9/29/79
10/02/79
10/03/79
—
Moisture
(% by volume)
15.1
16.9
17.9
13.5
14.1
15.5
Volume fraction dry gas
(M )
.849
.831
.821
.863
.859
.845
Volumetric
(acfm)
85,263
95,836
83,269
97,094
86,663
89,625
flowrate
(dscfm)
34,012
37,439
32,053
39,436
34,596
35,507
-------
Table 2-5.
SIDWARY GAS ANALYSIS OIL HEATER INLET AT EL PASO
PRODUCTS COMPANY, ODESSA, TEXAS
RUN NO.
DATE
TIME
Species
analysis
C-la
C-2 + C2
C-3
C-4
C-5
C-6
Benzene
Toluene
Ethylbenzene
Xylene
Styrene
TOTAL
HYDROCARBONS
by species
summation
ABI-2
ppmv as
compound
925,155
21.462
6,560
291
56
<0.1
57.4
23.5
<0.1
<0. l
<0. 1
955,605
ABI-3
ppmv as
compound
897,180
33,404
5,508
-------
Table 2-6. SUMMARY GAS ANALYSIS OH BURNER OUTLET AT
EL PASO PRODUCTS COMPANY, ODESSA, TEXAS
RUN NO.
DATE
TIME
Species
analysis
C-la
C-2 * C2
C-3
C-4
C-5
C-6
Benzene
Toluene
Ethyl benzene
Xylene
Styrene
TOTAL
HYDROCARBONS
by species
summation
ABO- 2 ABO- 3 ABO- 4 AVERAGE
ppmv as ppmv as ppmv as ppmv as
compound compound compound compound
<0.1 <0.1 <.01 <0.1
<0.1 <0.1 <0. 1 <0.1
<0.1 <0.1 <0.1 <0.1
<0.1 <0.1 <0.1 <0.1
<0.1 <0.1 <0.1 <0.1
1.3 <0.1 <0.1 0.43
<0.1 <0.1 <0.1 <0.1
<0.1 <0.1 <0.1 <0.1
<0.1 <0.1 <0.1 <0.1
<0.1 <0.1 <0.1 <0.1
1.3 <0.1 <0.1 0.43
Inerts0
H-0, X by volume
N2. X by volume
02, X by volume
C02> X by volume
H, , X by volume
CH4, X by volume
TOTAL (X)
5.53 6.45 6.34 6.07
75.81 76.94 73.97 75.57
4.61 3.63 3.98 3.92
9.89 10.37 9.50 9.92
NDd ND ND ND
ND ND ND ND
95.39 97.39 93.69 95.49
"Measured by a Shiwdzu Mini-2 dual GC/FID using Porapak Q column.
bMeasured by a ShiMdzu Mini-1 dual GC/FIO using SP2100/0.1X Carbowax
on 100/120 Supelcoport column.
Steasured by a Carle 8700 GC/TCD using Molecular Sieve and Chromosorb 102 columns.
dNot detected.
2-9
-------
No problems were encountered during the sampling using the modified
EPA 110 sampling procedure (see Section 4). No problems were encountered
in the analytical procedures. The procedures are also explained in
Section 4.
2.2 OIL HEATER
Three one-hour integrated bag samples were taken at the fuel inlet
and the outlet to the oil heater simultaneously. Each bag was analyzed
for (a), (b) and (c), listed in Section 2.0. During the test period a
final scrubber in the ethylbenzene unit was cleaned and this resulted in
a low benzene concentration in the fuel gas. The results are presented
in Table 2.5. Table 2.6 shows the results of the samples obtained at
the outlet of the oil heater. Dilution ratios were calculated using
stoichiometric combustion calculations. The resultant dilution ratios
were then applied to the benzene inlet and outlet concentrations to give
the boiler benzene reduction efficiency (see Table 2.7). Run AB-2
appears to have a poor efficiency; however, this is caused by the low
benzene concentration in the fuel. No sampling or analytical problems
were encountered. No velocity traverse or moisture data were obtained
at the outlet as the sampling point was inaccessable.
2-10
-------
Table 2-7. SUMMARY - BENZENE REMOVAL EFFICIENCY AT EL PASO PRODUCTS COMPANY,
ODESSA, TEXAS
Run no.
ABO-2
ABO-3
ABO-4
SHO-2
SHO-3
SHO-4
SHO-5
Benzene concentration
Stack outlet Fuel Inlet
(ppmv wet) (ppmv dry, (ppmv)
03% 02)
1.3 1.52 57.4
<0.1 <0.1 65.7
<0.1 <0.1 55.8
0.3 .33 I/O6
0.4 .49 I/O
<0.1 <0.1 I/O
<0.1 <0.1 I/D
Oxygen concentration
Stack
(% by volume wet)
4.16
3.63
3.98
3.15
4.61
6.6
7.6
(% by volume dry)
4.40
3.88
4.24
3.36
4.93
6.98
8.05
Moisture
stack3
(%>
5.53
6.45
6.24
6.28
6.45
5.42
5.60
Dilution
factor
10.01
9.48
10.37
I/O
I/O
I/D
I/D
Benzene removal Emission
efficiency rates
(%)
73.49
"100
"100
I/O
I/O
"100
"100
(Ib/hr)
I/O
I/O
I/O
.16
.17
<.052
<.045
(kg/hr)
I/O
I/D
I/O
.07
.08
<.02
<.02
ro
i
aAs analyzed 1n sample.
bI/D - Insufficient data.
-------
3.0 LOCATION OF SAMPLING POINTS
There were five sampling points in the two processes. The first
three were the two inlets to the superheater and the outlet from the
superheater. These are discussed in Section 3.1. The remaining two
were the inlet to and outlet from the oil burner heater, which are
discussed in Section 3.2.
3.1 SUPERHEATER SAMPLING POINTS
The sample locations for the Steam Superheater were shown in
Figures 3-1 and 3-2. At sample point 3 (FGI) fuel gas from the fuel
mixing drum was collected for analysis. At sample point 4 (OGI)
dehydrogenated off gas was collected. Both of these points were sampled
after a flow orifice which measured the amounts of fuel delivered to the
superheater burners. Sample point 5 (SHO) was located on the exhaust
stack of the superheater. There were two ports located 90° apart about
the centroid of the stack. Moisture measurements and velocity traverses
were conducted from both of these ports. The integrated bag sample was
extracted from one of these ports at a single point in the centroid of
the stack.
3.2 OIL BURNER SAMPLING POINTS
Sampling locations from the oil heater are shown in fig. 1A and
Figure 3.3. Sample point 1 (ABI) consisted of the fuel entering the
boiler from the fuel mix tank. Sample point 2 (ABO) was a stream taken
from the exhaust gases of the stack. The exhaust gases were inacces-
sible for flow measurement. The integrated bag sample was taken at the
outlet of a 1/4" stainless steel line which ran down the side of the
stack. This was provided by the plant and is their normal sampling
point for this location.
-------
Dampers
60'
Exhaust To Air
20
40'
40'
SHO
900 Ports
% Ring Platform
t
Burners
Figure 3-1. Sampling locations steam superheater - Unit 2.
3-2
-------
DEHYDROGENATED OFF-GAS
From
Dehydrogenated
Off
Gas
£
A
<
V Pipe
To Super
Platform
leater
FUEL GAS & OFF-GAS
>
From Fuel Gas
Orifice
A
>!«" Pipe
FGI
To Superheater 2'
Platform
Figure 3-2. Sampling locations off-gas and fuel gas inlets to superheater.
3-3
-------
txhaust To Air
OUTLET POIKT
ABO
30'
INLET TOTAL
GAS
Fuel Mix
Froe Fuel
Nix On*
V
=0
ABI
Oil Heater
Ground
Figure 3-3. Sampling locations oil heater - Unit 1.
3-4
-------
4.0 SAMPLING AND ANALYSIS PROCEDURES
4.1 SAMPLING
4.1.1 Volumetric Flow and Moisture Determination
The gas volumetric flow data was obtained from the superheater
outlet by EPA Reference Methods 1 and 2. Moisture content at stack
conditions was determined by EPA Reference Method 4.
4.1.2 Hydrocarbon Sampling System
A modified Method 110 was chosen for use in collecting a hydrocarbn
sample. The modification was the replacement of the vacuum pump with an
evacuated can. This system was chosen because of the explosion risk and
safety requirements of the plant.
The evacuated can method was used for obtaining a given quantity of
sample into a tedlar bag. This method uses the negative pressure from
an evacuated can connected to a sample bag can as the mechanism for
obtaining a controllable sample flow.
The procedure uses a diaphram pump to evacuate the can using a
self-sealing quick-disconnect valve. A vacuum guage is connected at the
other quick-disconnect valve and the can is evacuated to 29" Hg. The
vacuum is monitored for a leak. If the pressure loss does not exceed
more than 1" Hg in 30 minutes, the can is considered to be leak-free.
The equipment is then transported to the sampling site and assembled
according to the Figure 4.1.
The tedlar sample bag is placed in the sample can and connected
to the sample line that has been purging at the site. The sample flow
into the sample bag is obtained by opening the valve between the two
cans. The sample flow can be monitored with the flow meter. The
adjusting of the valve will give the appropriate sample flow desired.
-------
The sample flow will remain constant until the evacuated can
starts to reach a low pressure level. When the sample flow drops or the
appropriate test time is completed, the valve is shut between the cans
and the sample bag disconnected from the sample line. The bag is capped
off and removed from the sample can. The bag is appropriately labeled
and transported by the sampler to the lab for analysis.
4-2
-------
KEDLE VALVE
_LJ
FLOWMETER
QUICK DISCONNECT
n
1
1
1
1
1
1
1
1
SAMPLING -
BAG
1
1
1
1
1
1
1
1
*
EVACUATED
CAN
4-3
-------
APPENDIX A
SAMPLE CALCULATIONS AND RESULTS
-------
Table A.I. COMBUSTION CALCULATIONS
Calculation Basis: 100 Moles Fuel
Let: a = volume % N2 in fuel
b = volume % C02 in fuel
c = volume % 02 in fuel
d = volume % H2 in fuel
e = volume % CH4 in fuel
L = volume % non-CH4 species in fuel
k = number of % non-CH4 species in fuel
m = hydrogen atoms in non-methane HC species
n = carbon atoms in non-methane HC species
1. Oxygen required for combustion, moles
k m.
02 = Jjd + 2e + I L.(n. + -^- ) - c
2. Nitrogen with combustion air, moles
N2 = (79/21) 02
3. Carbon dioxide generated, moles
k
C02 = e + I (Lini)
4. Water generated, moles
k
H20 = d + 2e + I (L.m./2)
i=l n 1
5. At stoichiometric air rates*, moles
Oo* = 05
2 2
N2* = a + N2
C02* = b + C02
H20* = H20
A-l
-------
Table A.I. Continued.
6. Since excess air is added and water is condensed prior to analysis:
Let: x = excess moles 02 added
y = moles H20 condensed
% N2e = N2 in exhaust sample
% 02e = 02 in exhaust sample
% C02e = C02 in exhaust sample
7. Nitrogen balance:
* KI e - (N?* + 3.76 xXlOO)
2 N2* + C02* + H20* + x + 3.76x-y
8. Oxygen balance:
* n e _ x (100) _
* U2 N2* + C02* + H20* + x + 3.76x-y
9. Solving for x by eliminating y in the above equations:
N *
X =
N2e - 3.76
02e
10. Therefore y = N2* + C02* + H20* + 4.76x -
02e
11. At sample conditions, combustion products from 100 moles of fuel is
given by:
02S oxygen: x moles
N2S nitrogen: N2 + 1 + 3.76x moles
C02S carbon dioxide: C02 + b moles
H20S water vapor: H20 - y moles
TOTAL MOLES = SUM moles
12. Dilution ratio (DR) =
C - C —
13. Mass removal efficiency = in out 100
Cin
A-2
-------
Table A-2. MOISTURE CALCULATION3
Temperature, Moisture H20,
°F % by volume t saturation
70
75
80
85
90
95
100
105
110
115
2.47
2.92
3.45
4.06
4.72
5.53
6.45
7.50
8.66
10.0
aFrom psychometric charts. Calculated water vapor concentration
assumed to be saturated at analysis temperature.
A-3
-------
Table A.3. BENZENE REMOVAL EFFICIENCY
Benzene Concentration, ppmv @ 3% 02, dry
17.9
d w (I'M) 20.9 - 0.
where:
B. = Benzene concentration ppmv @ 3% 02, dry
B = Benzene, ppmv, wet
W
20.9 = Oxygen (% v/v) in ambient air
0 . = Oxygen, % v/v, dry
M = Moisture fraction, —
100
Equation A. 4
= CIN ' COUT
CIN
where:
MD = Benzene Mass Removal Efficiency (%)
b
CIN = Concentration Inlet
= Concentration Outlet
DR = Dilution Ratio
A-4
Equation A.3
-------
LOAD SHEET
STACK TEST - VOLUMETRIC FLOW RATE
Test f: sMo-f
Part 1
ftnter
1
JfMin)
I2(in2)
S(1n Hg)
|ft3)
K'{rti )
|0:>
o?
K-2
oV
gft2)g
R+460)
P(mg)
t(iss)
T0(f3)
IC'Hg)
jk+460)
jscfrr.)
(Initial
Value
0.0283
17.71
0.0474
1032
I.S
..w
-Lk.ll
a, f*<
^.o-
/o.o
^/o.^^
ioto
Part 2
^:>
•?f^.")S
y Only)
Location
04
05
05
07
09
10
11
12
13
14
15
16
17
18
19
00
01
02
03
04
05
06
Test £ S^o-T- Test =? Sfo-3
Enter
Tf(Min)
l(D!l)2(1n2)
PS(in Hq)
VM(ft3)
W,'(ml }
% CO?
% 0?
% \h
J435d/
lAs(ft2)
(Ts+460)
mf (me)
rat (me)
VMSTn(f3)
k ("Ho)
!i-w
(Ts+460)
Qs(scfn)
Value
;S
l.o
2.G.to
2,o«Y^
1^
/i? ?
3.2.
tl.3
63S-?7.3
V^-3*/
JOG"?
Part 2
•^^
?.C,-^
Location I
i
09
1C
11
12
13
14
15
16
17
18
19
00
01
02
03
04
05
05
Enter
Tf(Min)
Value
/S
(CN)2(1n2)! /. 6
PS(in Hq)
VM(ft3)
W(inl )
% CO?
% 0?
% N?
4350V
As(ft2)
(Ts+460)
mf (mq)
n>t (mq)
VMsrnff3)
PS ("Kn)
Kd
(Ts+460)
Qs(sc*m)
J?c,-flo
2.-Y^
10.0
/o.~)
3.-L
fl.3
iT:^/7^.7
Vff.3«./
/oi (,,S
Part 2
S3.S
xd.^
Locatior
09
10
11
12
13
U
15
16
17
16
19
00
01
02
03
04
05
05
I
I
A-5
-------
RESULTS
STACK TEST - VOLUMETRIC FLOW RATE
Test 0
Test #
Test
Value
Vm (SCF)
Vm (SCM
Vw qas (CF)
% Moisture
Hd
Wd
MM
Vs (fpm)
ACFM
Flow (SCFM)^A
Flow (SCMM)
55 I
% EA
Front nr/scf
Front nro/scm
Total gr/scf
Total jim/scm
Front gr/acf
Front -cm/ a cm
Total sr/acf
Total gm/acm
Front Ib/hr
Front kg/hr
Total Ib/hr
Total kn/hr
/,m
""" '
^
& 1
/:> , /
2l)3,"">k
ftSU,!.0!
\?Yi?/>.£
-3-^-
l^j-L
:
i
•
i
Value
Vm (SCF)
Vm (SCM) ' ' '
Vw gas (CF)
% Moisture
•Hd
Wd
m
fVs (fpm)
i
Flow (SCFM)
Flow (SC!',M)
% I
% EA
Front gr/scf
Front qrn/scm
Total gr/scf
. Total ^isi/scm
Front gr/acf
Front gm/acir,
Total gr/acf
i Total nra/acm
Front Ib/hr
Front kg/hr
Total Ib/hr
Total kg/hr
! £V
'-^
H,'?
~-
s-
„..
12")i,7
^^KBC>, ^
31^^. C#
H-IV
•
' Value
Vm (SCF)
.
Vm (SCIi)
Vw gas (CF)
S Moisture n ,^
Md
JWd
KW
Vs (fpn) i ^ .06^', 7-
ACFM , S' 37.G^7-
Flow (SCFH) ^1(3<3,-^
Flow (SCMM)
^ I
% EA n. IV
Front or/scf
Front gn/scm
Total gr/scf
Total ci.-,/scn
Front gr/ncf
Front gn/acm
Total gr/acf !
Total cm/ a cm
Front Ib/hr
Front kg/hr
Total Ib/hr
Total kg/hr i ;
A-6
-------
LOAD SHEET
STACK TEST - VOLUMETRIC FLOW RATE
Test
Part 1
— Enter
1
1
•
I
Pf(,Min)
t)2(in?)
-(in Hg)
K(ft3)
(mi)
1' CO?
c?
:w2
§50V
«(ft2)
Is+460)
(ntq)
•t (rag)
§STD(f3)
•S.C'Hg)
•
Ts-i-460)
f(scfn)
(Initial
Value
0.0283
17.71
0.0^74
1032
/£
/ o
2fe,9
/,qr/-
r.s.
/o,i
3.x
•fl.3
6<>Vi-J.£
^iV i(,«-
V0.3«-»
/P/.?
Part ?
^1
7Lf.,°l
y Only)
Location
04
05
06
07
09
10
11
12
13
14
15
16
17
18
19
00
01
02
03
04
05
06
Enter
Tf(Min)
(DH)2(1R2)
PS(in Hq)
VM(ft3)
Mm!)
*: CO?
% 0?
% N?
435C\/
As(ft2)
(Ts+450)
•nf (mg)
!t!t (nq)
VMSTD(f3)
P<; ("Ho)
Md
(Ts-KSO)
Os(scfn)
,
Test 5 S^'O
Value
/r
/ o
at. 9
7..V2.
i.e.
to. 7
I.-L
61 • Z
^SOTSA
Ho- "2^1
1010
Part 2
75
2fa,C|
•
-£
Location
09
10
11
12
13
14
15
16
17
18
19
00
01
02
03
C4
05
C5
.
Enter
Tf(Min)
(DK)2(1n2)
PS (in Hn)
VH(ft3)
VW(nl )
% CO?
% C?
% N?
435CV
As(ft2)
(Ts^SO)
mf (n-q)
mt (ma)
VMSTn(f3)
PS ("Hn)
Md
(Ts+460)
Os(scfn)
Te^t ? Sjio.
value
/3f
i.h I
26 A/
A
/\
/(?/?'
•B.v
/
ItoiSj
*/0-lW.
/
i>art 2
/*
-Q
Lotatio;
/ 09
10
11
12
13
14
15
16
17
\1S
^
00
01
02
03
04
C5
06
I
I
A-7
-------
RESULTS
STACK TEST - VOLUMETRIC FLOW RATE
Test*
Value
Vm (SCF)
Vm (SCM
Vw gas (CF)
% Moisture
Md
.MWd
MW
Vs (fpm)
ACFM
Flow (SCFM)
Flow (SCMM)
% I
% EA
Front gr/scf
Front gm/scm
Total gr/scf
Total gm/scm
Front gr/acf
Front gm/acm
Total gr/acf
Total gm/acm
Front Ib/hr
Front kg/hr
Total Ib/hr
Total kg/hr
: StyG r *7
/,?.6
•
2''/0>C,.9
9>->fc/, (,
v9u/3&,<
-
-•• .
.--
•
r •: ::' Test #
• "Value
Vm (SCF)
Vm (SCM)
Vw gas (CF)
% Moisture
Md
MWd
MW
Vs (fpm)
ACFM
Flow (SCFM)
Flow (SCMM)
% I
% EA
Front gr/scf
Front gm/scm
Total gr/scf
Total gm/scm
Front gr/acf
Front gm/acm
Total gr/acf
Total gm/acm
Front Ib/hr
Front kg/hr
Total Ib/hr
Total kg/hr
: 5*V0 r.h
v$W
.
2/^,3
;/. &&3. /
r«-/w. c
»-.... ::Test:$
Value
Vm (SCF)
Vm (SCM)
Vw gas (CF)
% Moisture
Md
MWd
MW
Vs (fpm)
ACFM
Flow (SCFM)
Flow (SCMM)
% I
% EA
Front gr/scf
Front gm/scm
Total gr/scf
Total gm/scm
Front gr/acf
Front gm/acm
Total gr/acf
Total gm/acm
Front Ib/hr
Front kg/hr
Total Ib/hr
Total kg/hr
..
•
. •*
A-8
-------
41
* NflNE Tlfif
o a.Ji
T r. v j •
• t* I T*L.
H-2 ^
Cl '• C-i>
Vi'pRT 09.29. CO. 3:.
£7
67
F;i.t
-C,
r:95 _ C,
.4.24— C4
1. 28 -
;TCP
4J
£).
{•
0
707.1!
io«c «k
0.351
3.7216 V
71 ~ r, *
. >N*>C-
rf^' • i-* I I
•Vl r-j-'.j
C1-C6 Calibration Example
r
"
i^jf.i —^
22»6 - C3
jos-; - c4
50V'o ~ Cc.
/>•>•? - c^
A-9
-------
» ^^~
Ethene
" U1
Ethane
STO*3-55
=;HPL «
FILE #
fcCF1! *
«ETHOD
ft
0
0
8
0
8
0
8
8
6
fi
r)
0
03
3
25
41
NflME
TlrtE
0.31
0.41
0.7
0.81
1.7
3.37
5.24
6.68
io!s5
It.21
11.2:6
ijic-S
CONC
0. 2626
25.5967
20.8169
2.0348
1.84*S
S.1529
0.147
8.4S06
3.2793
0.2213
0.2992
1.5895
w.3057
&.!•)$$
V
V
V
V
V
V
V
V
• V
fiREfi
• 65 r
6428" 1 ;
522? -'Co-- .-
5D3 ~C|
464 ^c2 '• •>
J8 L3 :
36
i2Cit Temperature
1P5.J Program
7&
55
75 , '"
76
C1-C6 ExampleRun
A-10
-------
001
C"o. <•<;
i'«. ri1'
4. »1
1 . y — Styrene
STOP
3. ££ - Ethyl benzene
1.03 - Benzene
SMPL * *0
FILE * 3
KEPT * 17
METHOD 4 i
*
0
0
e
0
0
0
e
HOME TIME
0.26
0.48
0.77 .
t.33
1.93
r *^O "
*>• */O
5.8
TOTflL
CONC fJK
49.0065
0.021 T
0.023
23. SI 52
1.4481
25.231
*J.0T«y2
0.395& V
100
RREft
25H1
10
11
122D3 -g
• •:•• 742 -P Cl
1292S — EB
50 •'
202 - Sty
51241
Example Aromatic Hydrocarbon Sample Run
A-ll
-------
1U6
>7fiRT 60.80.03.08.
• '
STOP
1.63- Benzene .•
SUP;. * eo .
••• » * •• A • ' T
' l «_£ * •}
F.£P1 i 6
r.£JHdt> 41
KftH£ TitiE
C 0.25
0 1.63
TOTAL
•
CONC MIC
0.9285
99.0714
99.9599
* *
•t
• f
'
fiRCfl • .
32S .
35092
. 35421 •
Benzene Calibration
A-12
-------
APPENDIX B
FIELD ANALYTICAL WORKSHEETS
-------
GC WORKSHEET
COLUMN;
7
RUN NUMBER:
'ISMt •
DATE; ?/?*/;>> 9
00001
COMPOUND
Cl
C2
C3
C4
C5
C.XJ
p
BENZENE
TOLUENE
XYLENE
ETHYL-
BENZENE
STYRENE
TOTAL
HYDRO-
CARBONS
(THC)
RETENTION TIME
IN &.
•
/. 7
3.C
ft.*
,/.?
NO'S
/•77
^rfr
3. 07
+ r*f
•
COUNTS
MIS'
?2#
K7
4X.£
o
tm
^
^
/
DILUTION FACTOR
(Diluted w/N2)
/OO///M
' /
*
\*o: )
\
•
CONCENTRATION AS
COMPOUND
Hl'o^
5V3*pP,v,
Jr3°o<»«n.
o ' /„„,«
22,
^
»*\
cl
00
I
ENVIRONMENTAL ENGINEERING DIVISION
-------
00002
O3
I
ro
rofftoji w
6C WORKSHEET /
• ' / •/ ^
COLUMN: Jr~/le*> ifa+jL. *J¥ RUN NUMBER: /W<7"N
CONCENTRATION AS
-BEN-ZCNe
110117 ' C6^
31 1
1*
—
—
J/2V,m
*»* <»^
2 6 fr ^ A-^.
0
ENVIRONMENTAL ENGINEERING DIVISION
-------
00003
GC WORKSHEET
COLUMN:
RUN NUMBER:
DATE:
?
COMPOUND
Cl
C2
C3
C4
C5
C6
BENZENE
TOLUENE
XYLENE
ETHYL-
BENZENE
STYRENE
TOTAL
HYDRO-
CARBONS
(THC)
RETENTION TIME
IN CM.
.4
.8
' i.S-i
i-I.Of
.X1
)>(,<
' -fiftf^SfiU
J\ >i/ViV VM
;.?*
COUNTS
MM
tf>$3
w/
i?<,
ti/7
b"l70
tHrui^i1!^
3XU
SI
/<
\!
/
->
5AN
y
I
o1*
/
f
ATTENUATION
IL '
\
•••
'
i/
X
\/
V
•
DILUTION FACTOR
(Diluted w/N2)
/6; Ai^^
• I
f
V
lo: 1
\ /
^^
•
•
CONCENTRATION AS
COMPOUND
//^7^
7 V ^ /ya^wx
• 3)&/ai*^>
6*lS A&r**.
/Z2~T>Pm
CONCENTRATION AS
— BCNrENL
C./VJPD (coit/t)
'(*q/
HH^
34
/5^-ac.
<&foaL-+*.
7/9 ./L^_
"775?
/ / 0 f-f*V*
/ '
ENVIRONMENTAL ENGINEERING DIVISION
-------
COLUMN;
00004
GC WORKSHEET
RUN' NUMBER:
- /
DATE:
9
•
f
•
5
•
COMPOUND
Cl
C2
C3
C4
C5
C6
BENZENE
TOLUENE
XYLENE
ETHYL-
BENZENE
STYRENE
TOTAL
HYDRO-
CARBONS
(THC)
RETENTION TIME
IN #4.
• 41
.£(
1.*3
J:ST
^5.7
ll.«!
\.c^
' ~
~
3-C*C*
^
COUNTS
!«•/*( 7
OS?*
J*^
to
0
MO
18«J
O
0
30,,'
o
SPAN
*
J
|63
V
ATTENUATION
16
J
r
?
s
/
DILUTION FACTOR
(Diluted w/N2)
|66 ! 1 ^1
•
1
f
•
CONCENTRATION AS
COMPOUND
irw ff~
2ST*rp-
^o rf~
* rf-
o
7-t rp^
•^ x-
-
.
iiSWn
_
CONCENTRATION AS
BENZENE
ss»~
o
o
«3/,-
&
TRW
ENVIRONMENTAL ENGINEERING DIVISION
-------
00005
COLUMN; AT-*****
GC WORKSHEET
RUN NUMBER; FouU
~
- 2-
DATE:
COMPOUND
Cl
C2
C3 •
C4
C5
C6
BENZENE
TOLUENE
JWLENE*
f
ETHYL- J
BENZENE
STYRENE
TOTAL
HYDRO-
CARBONS
(THC)
RETENTION TIME
IN CM.,
•Y*
• **"
z.tl
lfli/1
«y?H
o
/^3
6
3Vr
6
0
SPAN
/0
1
^
105
' '
<
ATTENUATION
1C
\
^
*
(
l^
.DILUTION FACTOR
(Diluted w/N2)
100 '. l\^°S
I
i
•
CONCENTRATION AS
COMPOUND
sym/Y fft~
W' ~—
me, fLfo^^.
o
<&f.-l1 PPm
—
10, &/?Pf*l
-
_
CONCENTRATION AS
BENZENE
/
4&J fffjH^
0
iff 7 .^._
/03^/«
0
c)
00
I
en
.oot.75"
TRW
ENVIRONMENTAL ENGINEERING DIVISION
-------
COLUMN;
GC WORKSHEET
00006
RUN NUMBER;
DATE:
COMPOUND
Cl
C2
C3
C4
C5
C6
BENZENE
TOLUENE
XYLENE
ETHYL-
BENZENE
STYRENE
TOTAL
HYDRO-
CARBONS
(THC)
RETENTION TIME
IN CM.
.
-------
00007
GC WORKSHEET
COLUMN
•••4
7' IIQQ At* L**. ^¥
RUN' NUMBER;
- /
DATE:
COMPOUND
C1
C2
C3
C4
C5
C6
BENZENE
TOLUENE
XYLENE
ETHYL-
BENZENE
STYRENE
TOTAL
HYDRO-
CARBONS
(THC)
RETENTION TIME
IN CM.
t
•
COUNTS
0
o
0
6
O
O
O
O
6
6
0
SPAN
to
i
.
ATTENUATION
\L
1
*
DILUTION FACTOR
(Diluted w/N2)
IN0»V*
•
>
p
•
CONCENTRATION AS
COMPOUND
CONCENTRATION AS
BENZENE
TRW
ENVIRONMENTAL ENGINEERING DIVISION
-------
COLUMN i AT- 1 'loo 6**.
. GC WORKSHEET
RU^NUMBER; fl,,r7.gr - 2
00008
DATE;
00
I
00
7
f
•
?
•
*
1
1*.
0
0
$
^
*
COMPOUND
C1
C2
C3
C4
C5
C6
BENZENE
TOLUENE
XYLENE
ETHYL-
BENZENE
STYRENE
TOTAL
HYDRO-
CARBONS
(THC)
RETENTION TIME
IN CM.
M\
.81
|.SV
XT' 3-0
r u-5
^ 11.^
|./M
/.S5
i^L S-15"
?.&
^3
•
COUNTS
/St
so
0
to
\X
i*»
io<4
i^r
o
o
o
SPAN
10
\
-
f
(0*
1
-!/
ATTENUATION
l(^
>
f
«-
-
\
\J
DILUTION FACTOR
(Diluted w/N2)
KDvcC
•
•
Jr
•
CONCENTRATION AS
COMPOUND
2.C^V/y»^
•3 ?p»^
c?
./ Pfl* —
• OC»tf/>«w
• L. PP*VS.
, S PPM'
• 3 PPr»>
CONCENTRATION AS
BENZENE
— **iS« (
-------
COLUMN :
00009
GC WORKSHEET
~^ 3
7
:i.
RUN NUMBER:
DATE:
*
i
0
1
1
COMPOUND
j*
Cl
C2
C3
C4
C5
C6
BENZENE
TOLUENE
XYLENE
ETHYL-
BENZENE
STYRENE
TOTAL
HYDRO-
CARBONS
(THC)
RETENTION TIME
IN CM.
.v/
>#3
M*
3.3J
—
•»
.?/
A61
^ B
-
^
» •
COUNTS
3*5"
V!
—
6
.^
^ .p
/3^
/73^
SPAN
7*
*
*
/o3
\
1
AHENUATION
/6
1
'
I
^
s
V
f
DILUTION FACTOR
(Diluted w/N2)
K0*,<
1
1
1
v/
•
CONCENTRATION AS
COMPOUND
s5~. 7^tvv
» y _4-«2x»w
/ '
O
^ 03 flx«9-«A^
— '
• *Y p r> M
^/,z>p^
CONCENTRATION AS
BENZENE
* y/o*a<*/\
,6~< 2-MLn*
CO
I
to
ENVIRONMENTAL ENGINEERING DIVISION
-------
00010
COLUMN®
GC WORKSHEET
RUN''NUMBER:
DATE:
COMPOUND
Cl
C2
C3
C4
C5 -
C6
BENZENE
TOLUENE
XYLENE
ETHYL-
BENZENE
STYRENE
TOTAL
HYDRO-
CARBONS
(THC)
RETENTION TIME
IN CM.
.n
3»wr
SPAN
/
6
•
COMPOUND.
A, .07~
>-
*• . ei e»
Jfi- ?• *OG>ft
A.* .oof*
A. s . • oe>S J
jf^ « .«r« /7
AS -oo7J
CONCENTRATION to
/5-./^^
/7 • £ w<»9 **»
/*-. d -—*
^ ^
^^ ^ *^^^
1
t
CD
I
ENVIRONMENTAL ENGINEERING DIVISION
-------
00011
GC WORKSHEET
COLUMN:AT-IZoo
•7
RUN NUMBER:
DATE:
COMPOUND
Cl
C2
C3
C4
C5
C6
BENZENE
TOLUENE
XYLENE
ETHYL-
BENZENE
STYRENE
TOTAL
HYDRO-
CARBONS
(THC)
RETENTION TIME
IN &£
.y/
•ri
i.r'
Li*
C.77
/f. &1
/.Oi
•
COUNTS
7W
l*t>°
uu.f
3o 5>"
V-737
W«/l
5!f3rt.f
SPAN
/o>
*
'
/o-s
ATTENUATION
,C*
J
^
DILUTION FACTOR
(Diluted w/N2)
6
•
»
i
O
CONPENTRATOM A5
C/f^F/SCTO^S
jt. .6i. ,5.1^
^e .010 f«|.Cr
t-...»t. If 4
IL--OOTO 15"- 2.
^ -s . •»>< /5"- 6
t * .*el£ /5"- 7
>ts .0030
CONCENTRATION AS
BENZENE
H
A>&V*.
7Ȥy
CNVIRONMEN7AL ENGINEERING DIVISION
-------
00012
GC WORKSHEET
4^» 3*1
RUN NUMBER:
DATE:
COMPOUND
Cl.
C2
C3
C4
C5
C6
BENZENE
TOLUENE
XYLENE
ETHYL-
BENZENE
STYRENE
TOTAL
HYDRO-
CARBONS
(THC)
RETENTION TIME
IN CM.
.4'
.*3
M3
4.11
7.05
ii. tj
.1
•
COUNTS
7ffl
ieri<^
21* \
3,^
5?»z.
79 11
fJT
•
SPAN
10
\
f
l/N3
\
^
AHENUATION
)L
\
y
1
1
DILUTION FACTOR
(Diluted w/N2)
+**
•
<*
r
•
CONCENTRATION AS
COMPOUND
Jtt r . O t<*
hw« .t^o^Cv
JL * .*o<.X
Jk. *. o&*/^
-fo^ .ooio
^L: tOOZ.O
J2 - .OOZ-
CONCENTRATION AS
BENZENE
IT. 1 ff.*
id.dpp.
|f./L
lS"'£ «|Ak.
IA-.1^^
£NVtRONM£N7AL ENGINEERING DIVISION
-------
00013
COLUMN:
GC WORKSHEET
RUN7NUMBER:
DATE:
COMPOUND
Cl
C2
C3
C4
V
C6
BENZENE
TOLUENE
XYLENE
ETHYL-
BENZENE
STYRENE
TOTAL
HYDRO-
CARBONS
(THC)
RETENTION TIME
IN CM.
.-//
•*7
2.**
4.31
7.1
II. 33
.1
t.7Z~
3./3.*/L>. W
J.'/
v.fd.
•
COUNTS
7*3
I
>
DILUTION FACTOR
(Diluted w/N2)
**«.<*
• •
: (
/
CONCENTRATION AS
COMPOUND
|(r .Ot€>«/€>
k» •oo^C
)( = .tfor.S
CONCENTRATION AS
BENZENE
15- 1 4»0MA
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FIELD ENGINEERING NOTEBOOK
NUMBER 13382
-------
DATE
VNV2-
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PROJECT.
JOB I
00030
48
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B-42
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0004-
DATE A?/A:/-7l PROJECT.
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00044
DATE
63
PROJECT
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DATE:
DATE:
SIGNED.
DATE
0
B-44
-------
00045
DATE /O/3/79 PROJECT &•' ' JOB NO..
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B-45
WITNESS. DATE: SIGNED.
WITNESS: DATE: DATE
-------
00046
DATE //I / 3/ 7 9 PROJECT
._ JOB NO.
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37/9
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B-46
-------
APPENDIX C
FIELD DATA SHEETS
-------
GAS SAMPLING FIELD DATA
00001
Material Sampled __
Date ff/3 7 H 9
Plant
/ p£
I
j
Bar. Pressure
Ambient Temp.
Run No. / -
,?*«->
Power Stat Setting_
Filter Used: Yes
Operator
M
"Hg.
Location
Consents
°F
No
r»>^
CLOCK TIME
METER (Ft)
FLOW METER
SETTING^CFH)
METER TEMPERATURE
IN
MA
ScF-H
Comments:
Impinger Bucket No..
Meter Box No.
C-l
-------
GAS SAMPLING FIELD DATA
00003
Material Sampled for^Tf^
Date
" ant
Bar. Pressure
Ambient Temp.
Power Stat Setting,
Filter Used: Yes
Operator
"Kg.
Location
Consents :
No X
- I
6 AS
CLOCK TIME
/*/.i-/9 -
- "•
METER (Ft?)
=*/^- ^
. .
METER TEMPERATURE
IN
4»
•
Comments:
Implnger Bucket N6._
Meter Box No.
C-2
-------
Material Sampled for
Date 9-17-7?
Plant £
Bar. Pressure
Ambient Temp.
NO.
Power Stat Setting_
Filter Used:
Operator /rt
Yes
GAS SAMPLING FIELD DATA
I
"Hg.
Location
Consents:
No
00003
CLOCK TIME
m-.'ot)
/
-------
Kateri*
Date
1 Sampled for
Plant'
Bar. Pressure
Ambient Temp.
Run Ho. QPX ~
Power Stat Setting
Filter Used: Yes
Operator
GAS SAMPLING FIELD DATA
^
-^ <\ Ci
/ fe
i
"Hg_.
Location
Consents
No
00004
^
CLOCK TIME
METER (Ft?)
FLOW METER
SETTING £FH)
METER TEMPERATURE
IN
1
3
crop
Comments:
Impinger Bucket No.
Meter Box No.
C-4
-------
Material Samled for
Date
PI an
Bar. Pressure
Ambient Temp,
Run No.
Power Stat Setting,
Filter Used: Yes _
Operator
6AS SAMPLING FIELD DATA
"Kg_.
_No A
Locat1on(
Consents:
00005
1
CLOCK TIME
»^:^/S'
/MvoO
• "
, • f
-
METER (Ft?)
*
.
• *
, FLOW METER
J SETT ING iCFH)
rO-O
- •
METER TEMPERATURE
IN
,t
Comments:
Implnger Bucket No.
Meter Box No.
C-5
-------
GAS SAMPLING FIELD DATA
00006
Material Sampled for fefOZ£A)£. ;ATH£
Date _
Plant
Bar. Pressure
Ambient Temp.
Run No.
Power Stat Sett1ng_
Filter Used: Yes m
Operator I
"Hg.
Location
Conments
No X
£T(W '
CLOCK TIME
•/»>o
iH-'.u-o
-
METER (Ft?)
•
* *
FLOW METER
' SETTING tCFH)
/ 3CFtf-
l tettf
1
METER TEMPERATURE
IN
-i
Comments:
Implnger Bucket No..
Meter Box No.
C-6
-------
GAS SAMPLING FIELD DATA
00007
Material
Date
-n-k:
Plant
Bar. Pressure
Ambient Temp.
Run No._OfirT-3_
Power Stat Setting
Filter Used: Yes
Operator
°F
No X
Location
Conments:
CLOCK TIME
./P2-2-
foz?.
10*JT-
/*S±-
METER (Ft?)
sT&cr
siot^
•
*
• *
..
FLOW METER
SETTINGJfCFH)
S
^Su
^ 1
«£af
METER TEMPERATURE
IN
9
Comments:
Implnger Bucket No.
Meter Box No.
C-7
-------
GAS SAMPLING FIELD DATA
00008
Material Sampled for
Date
Bar. Pressure
Ambient Temp.
Run No.
Location OteSSfr
Coc!»ients:
Power Stat Setting
Filter Used: Yes ,
Operator &£g I
it
/Vv>
CLOCK TIME
//9;'O£>
//^.'^^
.
METER (Ft?)
.STJteT""
572>P-
•
•
FLOW METER
SETTING (.CFH)
^5L^D
. ...
-
METER TEMPERATURE
IN
«
.
Comments:
Implnger Bucket No.
Meter Box No.
C-8
-------
\
GAS SAMPLING FIELD DATA
00010
Material Sampled for
Date
pX f
Plant
Bar. Pressure
"Hg.
Location
Consents
Ambient Temp. 3 ") ° °F
Run No. /
Power Stat Setting '
Filter Used: Yes No ' —
Operator VV\ ^
)|/f 1 ^KT.b.
CLOCK TIME
ISM |
IT5"6>
.. _
METER (Ft?)
—
•
* *
FLOW METER
SETTING (CFH)
VOftf
......
(.
AtJ
n*' i ° ^'srs\
METER TEMPERATURE
IN
• -
«
•
Comments:
Implnger Bucket No.
Meter Box No.
C-10
-------
00011
{0///-79
c-n
-------
00012
v/(
I**
C-12
-------
(
00013
-- 3
C-13
-------
|S"00
C-14
-------
00015
C-15
-------
00016
-------
OCrT
00017
- 5
-V. FT
C-17
-------
00018
j^
C-18
-------
00019
9
C-19
-------
00020
^^
10 10(2 \
S
OR i 0
C-20
-------
C-21
00021
10 (3
\
-------
APPENDIX D
TEST LOG
-------
Date
Time
Activity
Personnel
08/29/79
09/26/79
09/27/79
1403-1452
1405-1435
1419-1435
09/28/79
1340-1440
1346-1446
1345-1400
09/29/79
1022-1052
1020-1035
09/30/79 1541-1556
Presurvey conducted at test site.
Velocity traverse: Preliminary SHO.
Velocity traverse: SHO-1.
Moisture determination: SHO-1
Gas sample: OGI-1
Gas sample: SHO-1
Gas sample: FGI-1
Velocity traverse: SHO-2
Velocity traverse: SHO-3
Moisture determination: SHO-2
Gas sample: SHO-2
Gas sample: OFI-2
Gas sample: FGI-2
Moisture determination: SHO-3
Gas sample: OGI-3
Gas sample: FGI-3
Gas sample: ABO-1
Porpak Q analysis: FGI-3
Winton Kelly
David Mascone
Buddy Newman
Mack Webster
Webster/
Jongleux
Hartman/
Jongleux
Hartman/
Jongleux
Jongleux
Webster
Dorosz
Hartman/
Jongleux
Hartman/
Jongleux
Webster/
Hartman
Webster/
Hartman
Jongleux
Dorosz
Hartman
Jongleux
Dorosz
Hartman/
Dorosz
Haney
D-2
-------
Date
Time
Activity
Personnel
10/01/79 1017-1052
1017-1042
1500-1535
1500-1535
10/02/79
0910-0930
0910-0925
1405-1435
1407-1437
1400-1455
Gas sample: ABI-2
Gas sample: ABO-2
Gas sample: ABI-3
Gas sample: ABO-3
Porpak Q calibrated
Porpak Q analysis: ABO-3
Porpak Q analysis: ABO-2
Porpak Q analysis: ABI-2
Porpak Q analysis: ABI-3
Velocity traverse: SHO-4
Moisture determination: SHO-4
Benzene determination: SHO-3
Gas sample: ABI-4
Gas sample: ABO-4
Gas sample: SHO-4
Gas sample: OGI-4
Gas sample: SHO-4
Porpak Q calibrated
Porpak Q analysis: ABO-4
Porpak Q analysis: ABI-4
Porpak Q analysis: FGI-4
Porpak Q analysis: OGI-4
Porpak Q analysis: SHO-4
Dorosz
Dorosz
Dorosz
Jongleux
Haney
Haney
Haney
Haney
Haney
Webster
Hartman/
Dorosz
Dorosz/
Hartman
Dorosz
Jongleux
Dorosz
Jongleux
Dorosz
Haney
Haney
Haney
Haney
Haney
Haney
D-3
-------
Date Time Activity Personnel
10/03/79 Moisture determination: SHO-5 Hartman
0910-0945 Gas sample: FGI-5 Dorosz
0910-0945 Gas sample: OGI-5 Jongleux
0910-0935 Gas sample: SHO-5 Jongleux
Porpak Q calibrated Haney
Porpak Q analysis: OGI-5 Haney
Porpak Q analysis: FGI-5 Haney
Porpak Q analysis: SHO-5 Haney
D-4
-------
APPENDIX E
FIELD AUDIT REPORT
-------
PART A - To be
FIELD. AUDIT REPORT
out by organization supply unit cylinders (RTI)
1. Organization supplying" audit sample(s) and shipping address
Research Triangle -Institute, P.O. Box 12194 . -
Research Triangle' Party -NC 27709 ' ' . _ •
2. Audit supervisor, organization, and phone number (EMB Technical
Manager) ..'...
\C^ 'Winton Kelly. U.S. "Environmental Protection Agency
. ' ' ' 'MD- 13,' Research TriTngle Park; NC. 27711
3." Shipping instructions "-. Name, Address, Attention _
' To be picked-up'by TRW on' '9/19/79 '
4. Guaranteed arrival date for cylinders
5. Planned shipping date for cylinders __
9/19/79
Details on audit cylinders for last analysis
Low Cone.
a. Date jof. last analysis
b. Cylinder number
C. Grinder, pressure, PSI
£. Audit :9a5(es)/balarice, gas
er Audit sas(es) ppm
f. Cylinder construction
9A19/79
B-1017
High Cone.
9/19/79 9/19/79
B-455 -BAL 310
2000
1800
1700
Benzene in Benzene in Propane in
Nitrogen Nitrogen Nitrogen
8.2
Steel
74.5
Steel
10.6
Aluminum
E-2
-------
PART B - To be filled out by audit supervisor
1. Organic chemical manufacturing process £fkb 11 gkzpue /S^re* e
/
2. Location of audit
flftfc? pto»*tT$ co. _ . oc&SA TV.
3. Name of. individual audit and organization CAftoL
'TVcU/ • -
4. Audit results
a. Cylinder number
b. Cylinder pressure before
audit, psi
c. 'Cylinder pressure after
audit, psi
d. Audit date and measured
concentration, ppm
Date
Analysis #1
is it
is i 3
«„• - #TX concentration, ppm
"At&V Xfart A, 6d)
iyi,V.;'-.p4 .C •
Low Cone. High Cone.
. ^
-7.g
A9, 3
E-3
-------
f. Audit accuracy*
Analysis #1 - 3.7% -
Analysis £2 -3,0% -
; -Analysis #3 . "
*Percent accuracy .Measured" Cone - RTI tone. x
. Kii Lone.
"g. Problems detected (if
E-4
-------
APPENDIX F
PROJECT PARTICIPANTS
-------
PROJECT PARTICIPANTS
EPA
Winton Kelly, EMB
Andy Miles, EEA
Buddy Newman, EEA
EMB Technical Manager
NSS Contractor
NSS Contractor
TRW
Michael Hartman
Mack Webster
Robert Jongleux
Caroline Haney
Geraldine Dorosz
Team Leader
Sampler
Sampler
Analyst
Sampler
F-2
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