United States Environmental Protection Agency Office of Air Quality Planning and Standards Research Triangle Park NC 27711 EMB Report 80-BOF-7 September 1980 Air Steel Processing Fugitive Emissions Emission Test Report Republic Steel Company South Chicago, Illinois ------- FUGITIVE EMISSION EVALUATION REPORT BASIC OXYGEN FURNACE REPUBLIC STEEL COMPANY South Chicago, Illinois Prepared for the U.S. Environmental Protection Agency Emission Measurement Branch Research Triangle Park, North Carolina 27711 Prepared by Clayton Environmental Consultants, Inc 25711 Southfield Road Southfield, Michigan 48075 EMB REPORT NO. 80-BOF-7 Work Assignment 32 Contract No. 68-02-2817 ------- TABLE OF CONTENTS Page List of Tables i List of Figures ii 1.0 Introduction 1 2.0 Discussion of Results 3 3.0 Observation Locations and Emission Points 22 4.0 Observation Procedures 28 APPENDICES A. Project Participants B. Field Data Sheets B-l. Basic Oxygen Furnace (Method 22) B-2. Roof Monitor Readings B-2.1. Method 22 B-2.2. Method 9 B-3. Velocity Traverse Data C. Calibration Data D. Method 9 E. Method 22 F. Visible Emission Certifications of Observers ------- LIST OF TABLES Table Page 2.1 Summary of Fugitive Emissions - 4 Vessel Operations 2.2 Roof Monitor Emissions - Method 9 5 (24 consecutive readings) 2.3 Roof Monitor Emissions - Method 9 11 (6-minute averages) 2.4 Roof Monitor Emissions - Method 22 17 2.5 Methods 9 and 22 Averages 20 2.6 Stack Gas Parameters - Secondary 21 Inlet, No. 2 Furnace ------- LIST OF FIGURES Figure Page 3.1 Basic oxygen furnace observation 24 locations 3.2 Roof monitor observation locations 25 3.3 Sampling location and stack cross- 27 section 11 ------- 1.0 INTRODUCTION The Clean Air Act mandates that Standards of Performance be established for new stationary air pollution sources. Establishment of these standards requires that an emission data base be developed for each source category. This data base is used as a guide for the establishment of Performance Standards which will minimize air quality degradation and yet not be impossible to attain. The U.S. Environmental Protection Agency (EPA) retained Clayton Environmental Consultants, Inc., to evaluate both visible and fugitive emissions emanating from the basic oxygen furnace (Q-BOP) operations at Republic Steel in East Chicago, Illinois. Observations included fugitive emissions from the vessel operations (scrap charge, hot metal charge, oxygen blow, turndown, reblows, tapping, and deslagging), and both fugitive and opacity determinations of the roof monitor. In addition, nine velocity traverse runs were conducted on the inlet to the secondary control system. The field study was completed during the week of June 2, 1980. The results of this study will be used as part of the field sampling data for supporting New Source Performance Standards for fugitive process emissions in the iron and steel industry. This study was commissioned ------- as Project No. 80-BOF-7, Contract No. 68-02-2817, Work Assignment 32. Project participants are listed in Appendix A. - 2 - ------- 2.0 DISCUSSION OF RESULTS BASIC OXYGEN FURNACE Table 2.1 presents the results of the fugitive emission readings taken during the various vessel operations. Each run constitutes one heat. Ten entire heats were observed. Emission frequencies from the scrap charge were consistently 0-percent on both the charge and tap sides. Emissions during the hot metal charge ranged from 26 to 100-percent on the charging side and were 0-percent on the tap side. Emissions during the oxygen blow cycle ranged from 0 to 13-percent on the charge side and from 0 to 67-percent on the tap side. During turndown, fugitive emissions ranged from 0 to 64-percent on the charge side and were consistently 0-percent on the tap side. Tapping emissions ranged from 0 to 51-percent on the charge side and from 87 to 100-percent on the tap side. Deslagging resulted in fugitive emissions ranging from 31 to 94-percent on the charge side and from 0 to 49-percent on the tap side of the furnace. ROOF MONITOR Method 9 Visible emission data were reduced using two methods. In Table 2.2, percent opacities were averaged for 24 consec- utive readings, excluding any interferences. This method - 3 - ------- TABLE 2.1 SUMMARY OF FUGITIVE EMISSIONS - VESSEL OPERATIONS'1 1980 n,a -f~0 LJQ. L-ti Time Run No. 6/2 1228 1 6/2 1335 2 6/2 1605 3 6/3 1142 4 6/3 1333 5 Cycle5- SC HMC 02 TD TAP DS SC HMC 02 TD 02 TD TAP DS SC HMC 02 TD TAP DS SC HMC 02 TD 02 TD INT TAP INT DS SC HMC 02 TD TD TAP DS Frequency, Percent Charge Side Obs. 1 0 87 0 3 0 31 0 84 0 33 0 3 0 80 0 96 0 16 17 43 0 30 5 27 4 42 5 33 0 72 0 39 < 1 Obs. 2 0 93 0 5 0 39 0 74 0 42 0 0 0 39 _ 91 0 15 20 35 0 28 0 64 0 37 23 42 0 60 0 56 < 1 J 47 J 24 51 68 23 91 Tap Side Obs. 3 0 0 61 0 88 8 0 0 67 0 — 0 97 0 0 0 64 0 93 49 0 0 <1 0 0 - 99 0 0 __ 0 24 0 0 96 0 Obs. 4 0 0 58 0 87 0 0 0 65 0 0 0 98 0 0 0 59 0 90 0 0 0 <1 0 0 0 0 100C 6 0 _ 0 24 0 10QC 17 All observations are of Furnace 2, except Runs 9 and 10, which are of Furnace 1. SC = scrap charge INT = Interim HMC = hot metal charge TAP = tapping 02 = oxygen blow DS = deslagging TD = turndown 1980 Date Time Run No. 6/3 1603 6 6/3 1700 7 6/4 1142 8d 6/4 1616 9 6/4 1809 10 Cycle SC HMC 02 TD TAP DS SC HMC TD TAP DS SC HMC TD 02 TD TAP DS SC HMC 02 TD 02 TD TAP DS SC HMC 02 TD TAP INT DS Frequency, Charge Side Obs. 1 0 26 1 53 8 89 0 44 8 0 73 0 77 25 0 44 0 33 0 68 0 20 0 34 0 71 0 91 0 5 0 0 63 Obs. 2 0 38 1 35 48 91 0 41 3 0 84 0 83 29 0 39 0 35 0 100C 0 30 13 38 0 94 0 100C 0 2 0 0 61 Percent Tap Side Obs. 3 0 0 55 0 96 0 0 0 0 100 0 0 0 0 0 0 96 0 0 0 10 0 0 0 99 0 0 0 7 0 94 18 0 Obs. 4 0 0 57 0 100C 0 0 0 0 100C 30 0 0 0 0 0 97 0 0 0 5 0 0 0 95 0 0 0 8 0 93 61 0 Observers: Dusanka Lazarevic Donna Opthoff Justine Schroeder Timothy Palmer c Indicates emission frequencies greater than 100-percent. Intricacies in observin procedures could be responsible for this discrepancy. Charging doors jammed and were manually closed prior to the oxygen blow. - 4 - ------- TABLE 2.2. ROOF MONITOR EMISSIONS - METHOD 9 (24 consecutive readings) Date 1980 Time 1215-1223 1223-1231 1231-1244 1245-1250 1251-1256 1257-1302 1303-1308 1309-1314 1325-1330 1331-1401 1402-1407 1408-1415 1415-1422 1422-1428 1428-1434 1434-1440 1440-1446 1446-1503 6-2 1503-1509 1509-1515 1515-1521 1521-1527 1527-1533 1533-1539 1539-1545 1545-1551 1551-1557 1557-1613 1613-1619 1619-1625 1625-1631 1631-1637 1637-1643 1643-1649 1649-1655 1655-1701 1701-1707 Observer Low 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 High 0 40 40 20 20 5 10 20 0 0 0 0 10 5 0 0 10 10 0 20 0 0 0 0 0 0 30 40 0 5 0 0 0 0 15 5 0 1 Avg. 0 23.3 4.2 0.8 2.1 0.2 0.8 1.2 0 0 0 0 1.7 0.2 0 0 0.8 2.1 0 1.7 0 0 0 0 0 0 3.8 4.8 0 0.4 0 0 0 0 1.5 0.4 0 Date 1980 Tlme 1215-1247 1247-1253 1253-1259 1259-1305 1305-1311 1311-1327 1327-1333 1333-1404 1404-1410 1410-1416 1416-1422 1422-1428 1428-1434 1434-1440 1440-1446 1446-1502 1502-1508 1508-1514 6_2 1514-1520 1520-1526 1526-1532 1532-1538 1538-1544 1544-1550 1550-1556 1556-1612 1612-1618 1618-1624 1624-1630 1630-1636 1636-1642 1642-1648 1648-1654 1654-1700 1700-1706 Observer Low High 2 Avg. Interference 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5 5 0 0 10 5 0 15 5 5 0 0 0 0 5 10 40 0 0 0 0 0 5 5 0 0 0 0 0 0 0 0 0 0 2.3 0.4 0 0 1.0 0.2 0 2.9 0.4 0.4 0 0 0 0 0.4 0.6 3.8 0 0 0 0 0 1.0 0.2 0 - 5 - ------- TABLE 2.2. ROOF MONITOR EMISSIONS - METHOD 9 (Continued) (24 consecutive readings) Date 1980 TlmS 1115-1120 1121-1126 1127-1132 1133-1138 1139-1144 1145-1150 1151-1156 1157-1202 1203-1208 1209-1214 1225-1230 1231-1236 1237-1242 1243-1256 1256-1306 1306-1312 1312-1318 1318-1337 1337-1343 1343-1351 1351-1359 1359-1405 1405-1411 6-3 1411-1417 1418-1423 1424-1429 1430-1535 1536-1541 1542-1547 1548-1553 1554-1559 1600-1605 1606-1611 1612-1617 1618-1623 1624-1629 1630-1645 1646-1653 1654-1659 1700-1705 1706-1711 1712-1717 1718-1724 1724-1730 1730-1736 1736-1742 Observer Low 0 0 0 0 0 0 0 0 0 0 5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5 10 10 5 0 0 0 0 High 0 10 10 0 5 10 0 0 40 5 20 35 50 35 20 5 60 60 20 0 50 55 5 5 35 20 5 0 0 0 20 0 0 30 5 0 20 0 35 40 40 50 10 20 10 0 1 Avg. 0 1.2 1.9 0 0.4 1.7 0 0 20.2 1.0 13.3 7.3 8.8 5.8 2.3 0.6 27.9 19.2 2.7 0 7.5 10.6 0.4 0.2 14.6 7.1 1.0 0 0 0 4.8 0 0 4.2 0.2 0 3.5 0 12.9 19.0 17.9 20.0 6.0 6.9 3.5 0 Date 1980 TimS 1115-1120 1121-1126 1127-1132 1133-1138 1139-1144 1145-1150 1151-1156 1157-1202 1203-1208 1209-1214 1225-1230 1231-1236 1237-1242 1243-1254 1254-1302 1302-1309 1309-1315 1315-1323 1324-1339 1340-1345 1346-1353 1355-1401 1401-1407 6-3 1407-1413 1413-1419 1419-1425 1425-1431 1431-1537 1537-1544 1545-1550 1551-1556 1557-1602 1603-1608 1609-1614 1615-1620 1621-1626 1627-1632 1633-1648 1649-1654 1655-1700 1701-1706 1707-1712 1713-1718 1719-1724 1725-1731 1732-1737 1738-1743 Observer Low 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5 5 10 5 0 0 0 High 0 0 0 5 10 5 0 10 35 5 20 30 50 5 45 0 70 55 65 0 55 15 60 5 0 35 45 0 0 5 0 0 10 30 5 35 20 75 40 30 35 40 20 60 10 40 15 2 Avg. 0 0 0 0.4 0.8 0.2 0 0.6 6.7 0.6 7.7 2.3 9.0 0.6 6.5 0 11.7 13.3 15.8 0 5.6 1.5 7.7 1.2 0 17.7 5.8 0 0 1.0 0 0 1.0 4.8 0.4 4.0 1.9 26.0 8.8 2.7 13.3 10.4 12.7 20.2 4.4 12.7 7.5 ------- TABLE 2.2. ROOF MONITOR EMISSIONS - METHOD 9 (Continued) (24 consecutive readings) Date 1980 Time 1100-1105 1106-1112 1112-1118 1118-1124 1125-1130 1131-1136 1137-1142 1143-1148 1149-1154 1155-1210 1211-1218 1218-1224 1224-1230 1230-1236 1236-1242 1242-1248 1248-1254 1254-1300 1300-1306 1306-1322 1322-1328 1328-1334 1334-1340 1340-1346 6-4 1346-1352 1352-1358 1358-1404 1404-1410 1410-1416 1416-1432 1432-1438 1438-1444 1444-1450 1615-1620 1621-1626 1627-1632 1633-1638 1639-1644 1645-1650 1651-1707 1708-1713 1714-1719 1720-1725 1726-1731 1732-1737 1738-1743 1744-1749 1750-1755 1756-1801 Observer Low 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 High 0 0 0 0 0 0 10 5 0 0 0 0 0 0 0 0 0 0 5 5 20 5 0 0 0 0 0 5 5 0 0 0 0 10 0 0 35 5 0 30 10 10 10 5 10 5 0 15 10 1 Avg. 0 0 0 0 0 0 1.0 1.7 0 0 0 0 0 0 0 0 0 0 0.6 0.6 6.2 0.2 0 0 0 0 0 0.2 0.4 0 0 0 0 2.9 0 0 7.7 0.4 0 10.6 2.9 3.5 1.9 4.4 2.1 0.4 0 2.9 1.9 Date 1980 Time 1100-1105 1106-1111 1112-1117 1118-1124 1124-1130 1130-1136 1136-1142 1142-1148 1148-1154 1154-1210 1210-1217 1217-1223 1223-1229 1230-1235 1236-1241 1242-1247 1248-1253 1254-1259 1300-1305 1306-1321 1322-1327 1328-1333 1334-1339 1340-1345 6-4 1346-1351 1352-1357 1358-1403 1404-1409 1410-1415 1416-1431 1432-1437 1438-1443 1444-1449 1450-1624 1625-1630 1631-1636 1637-1642 1643-1648 1649-1654 1655-1711 1712-1717 1718-1723 1724-1729 1730-1735 1736-1741 1742-1747 1748-1753 1754-1759 1800-1805 Observer Low 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 High 0 0 0 0 0 0 5 5 0 0 0 0 0 0 0 0 0 0 15 0 20 0 0 0 0 0 0 0 0 0 0 0 0 15 0 30 30 0 0 25 0 0 10 5 10 5 0 25 10 2 Avg. 0 0 0 0 0 0 0.4 1.2 0 0 0 0 0 0 0 0 0 0 0.8 0 5.0 0 0 0 0 0 0 0 0 0 0 0 0 1.2 0 4.6 3.3 0 0 5.8 0 0 2.3 2.3 1.5 1.5 0 2.9 1.7 - 7 - ------- TABLE 2.2. ROOF MONITOR EMISSIONS - METHOD 9 (Continued) (24 consecutive readings) Date 1980 TlmS 1100-1106 1106-1112 1112-1118 1118-1124 1124-1130 1131-1136 1137-1142 1143-1148 1149-1157 1157-1213 1213-1219 1219-1225 1225-1231 1231-1237 1237-1243 1243-1249 1249-1316 1316-1322 1322-1328 1328-1334 1334-1340 1340-1346 6-5 1346-1352 1352-1358 1358-1404 1404-1410 1410-1416 1416-1422 1422-1428 1428-1443 1443-1449 1449-1455 1455-1501 1501-1507 1507-1513 1513-1519 1519-1525 1525-1531 1531-1537 1537-1553 1553-1559 1559-1605 1605-1611 1611-1617 1617-1623 1623-1629 1629-1635 Observer Low 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 High 0 0 0 0 0 10 0 5 0 0 0 0 30 90 0 0 0 100 60 15 65 0 20 30 20 0 0 0 0 0 0 0 0 0 0 20 85 0 10 40 5 10 10 40 0 60 50 1 Avg. 0 0 0 0 0 0.6 0 0.4 0 0 0 0 3.8 13.8 0 0 0 38.3 10.8 1.5 9.2 0 0.8 7.3 5.2 0 0 0 0 0 0 0 0 0 0 1.7 22.9 0 0.4 5.0 0.6 1.0 2.1 3.8 0 20.8 17.1 Date 1980 TimS 1100-1107 1107-1113 1113-1119 1119-1125 1125-1131 1131-1137 1137-1143 1143-1149 1149-1156 1157-1212 1213-1218 1219-1224 1225-1231 1231-1237 1237-1243 1243-1249 1249-1308 1309-1324 1325-1330 1331-1336 1337-1342 1343-1348 6-5 1349-1354 1355-1400 1401-1406 1407-1412 1413-1418 1419-1434 1435-1440 1441-1446 1447-1452 1453-1458 1459-1504 1505-1510 1511-1516 1517-1522 1523-1528 1529-1549 1550-1555 1556-1601 1602-1607 1608-1613 1614-1619 1620-1625 1626-1631 1632-1637 1638-1643 Observer 2 Low 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 High 0 0 0 0 0 15 0 10 0 0 5 0 0 90 0 5 20 90 15 65 0 0 30 20 20 0 0 0 0 0 0 0 0 0 0 65 75 0 5 20 0 10 35 0 65 10 0 Avg, 0 0 0 0 0 1.2 0 1.0 0 0 0.4 0 0 11.9 0 0.4 3.5 22.9 1.9 9.6 0 0 7.3 2.1 1.9 0 0 0 0 0 0 0 0 0 0 7.1 10.8 0 0.6 2.3 0 1.7 2.5 0 30.6 2.5 0 ------- TABLE 2.2. ROOF MONITOR EMISSIONS - METHOD 9 (Continued) (24 consecutive readings) Date 1980 6-5 6-6 Time 1635-1641 1641-1647 1647-1703 1703-1711 1711-1717 1717-1723 1723-1729 1729-1735 1735-1741 1741-1749 1749-1755 1100-1110 1111-1116 1117-1122 1123-1128 1129-1134 1135-1140 1141-1147 1147-1153 1153-1159 1159-1215 1215-1221 1221-1227 1227-1233 1233-1239 1239-1245 1245-1251 1251-1257 1257-1303 1303-1309 1309-1325 1325-1331 1331-1337 1337-1343 1343-1350 1351-1356 1357-1402 1403-1408 1409-1414 1415-1430 1431-1436 1437-1442 1443-1448 1449-1454 1455-1500 1501-1506 1507-1512 1513-1518 1519-1524 Observer Low 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 High 0 10 15 60 70 40 0 50 0 5 0 10 30 20 25 20 0 5 5 25 30 5 0 10 0 0 25 15 0 20 15 10 5 20 20 75 60 0 20 0 40 5 10 10 5 10 10 0 5 1 Avg. 0 0.4 3.8 25.2 17.3 4.4 0 12.1 0 0.4 0 2.7 7.7 5.8 2.5 3.1 0 0.6 0.6 4.4 5.8 0.2 0 1.2 0 0 6.5 2.7 0 5.6 4.6 3.8 0.6 6.0 2.3 6.7 7.1 0 3.8 0 10.6 0.6 1.5 1.0 0.6 1.9 0.6 0 1.2 - 9 - Date 1980 6-5 6-6 Time 1644-1659 1700-1705 1706-1711 1712-1717 1718-1723 1724-1729 1730-1735 1736-1741 1742-1747 1748-1753 1100-1105 1106-1111 1112-1117 1118-1123 1124-1129 1130-1135 1136-1141 1142-1147 1148-1153 1154-1159 1210-1215 1216-1221 1222-1227 1228-1233 1234-1239 1240-1245 1246-1251 1252-1257 1258-1303 1304-1309 1320-1325 1326-1331 1332-1337 1338-1343 1344-1349 1350-1355 1356-1401 1402-1407 1408-1413 1414-1419 1430-1435 1436-1441 1442-1447 1448-1453 1454-1459 1500-1505 1506-1511 1512-1517 1518-1523 1524-1529 Observer Low 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 High 0 65 30 60 20 0 45 10 10 0 0 15 5 15 30 0 0 5 15 45 25 10 5 0 0 0 20 20 0 20 15 15 5 30 45 20 75 0 20 0 20 50 5 10 0 15 15 5 0 60 2 Avg. 0 14.2 13.1 21.0 1.5 0 6.7 1.5 1.0 0 0 4.0 2.1 1.0 5.2 0 0 0.4 3.5 3.3 5.2 1.2 0.4 0 0 0 5.2 2.7 0 4.4 6.5 4.0 1.5 4.4 8.3 2.7 12.7 0 2.5 0 2.3 11.2 0.4 1.0 0 1.2 1.9 0.2 0 16.2 ------- does not permit direct comparison of simultaneous observa tions. Table 2.3 presents the percent opacities in 6-minute averages, which includes all interferences. Method 22 Results of the Method 22 roof monitor readings are presented in Table 2.4. Any corresponding interference times noted on the Method 9 data sheets were subtracted from each observer's accumulated observation time. The emission frequency ranges for Observer 1 are as follows: 0 to 19.9-percent on June 2; 3.5 to 100.0-percent on June 3; 0 to 68.4-percent on June 4; 0 to 51.4-percent on June 5; and, 4.1 to 43.0-percent on June 6. Emission frequencies for Observer 2 ranged from 1.3 to 28.8-percent on June 2; 4.7 to 97.5-percent on June 3; 0 to 64.4-percent on June 4; 0 to 37.1-percent on June 5; and, 13.1 to 67.5- percent on June 6. Overall and unobscured averages for both Methods 9 and 22 are presented in Table 2.5. VELOCITY TRAVERSE A total of nine velocity traverses were performed at the inlet to the secondary collector on the Q-BOP. Three runs were conducted under each of three fan operating conditions - auto, medium, and high. Results are presented in Table 2.6. Flowrates averaged 95,600, 87,400, and 184,000 standard cubic feet per minute under the three conditions, respectively. - 10 - ------- TABLE 2-3. ROOF MONITOR EMISSIONS - METHOD 9 (6-minute averages) 6-2 Date 1980 Time Observer 1 No. of Inter- ferences Low High Avg. Date 1980 Time Observer 2 No. of Inter- ferences Low High Avg. 1215-1220 1221-1226 1227-1232 1233-1238 1239-1244 1245-1250 1251-1256 1257-1302 1303-1308 1309-1314 1325-1330 1400-1405 1406-1411 1412-1417 1418-1423 1424-1429 1430-1435 1436-1441 1442-1447 1500-1505 1506-1511 1512-1517 1518-1523 1524-1529 1530-1535 1536-1541 1542-1547 1548-1553 1554-1559 1610-1615 1616-1621 1622-1627 1628-1633 1634-1639 1640-1645 1646-1651 1652-1657 1658-1703 1704-1709 11 2 10 22 3 0 0 0 0 0 0 0 2 3 4 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 30 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 40 40 30 0 20 20 5 10 20 0 0 0 10 5 0 0 0 10 0 20 5 0 0 0 0 0 0 30 40 0 5 0 0 0 0 15 5 0 0 11.4 25.0 30.0 0 0.8 2.1 0.2 0.8 1.2 0 0 0 1.5 0.4 0 0 0 2.9 0 1.2 0.4 0 0 0 0 0 0 3.8 4.8 0 0.4 0 0 0 0 1.7 0.2 0 1215-1220 1221-1226 1227-1232 1233-1238 1239-1244 1245-1250 1251-1256 1257-1302 1303-1308 1309-1314 1325-1330 1400-1405 1406-1411 1412-1417 1418-1423 1424-1429 1430-1435 1436-1441 1442-1447 1500-1505 6-2 1506-1511 1512-1517 1518-1523 1524-1529 1530-1535 1536-1541 1542-1547 1548-1553 1554-1559 1610-1615 1616-1621 1622-1627 1628-1633 1634-1639 1640-1645 1646-1651 1652-1657 1658-1703 1704-1709 24 24 24 24 24 10 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 - - 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 - - 0 0 0 0 0 0 0 0 5 5 5 0 0 10 0 15 5 5 0 0 0 0 0 5 40 0 0 0 0 0 0 5 0 0 - - 0 0 0 0 0 0 0 0 1.0 1.2 0.4 0 0 1.2 0 2.5 0.8 0.4 0 0 0 0 0 0.4 4.4 0 0 0 0 0 0 1.2 0 0 - 11 - ------- TABLE 2.3. ROOF MONITOR EMISSIONS - METHOD 9 (Continued) (6-minute averages) 6-3 Date 1980 Time Observer 1 No. of Inter- ferences Low High Avg. Date 1980 Time Observer 2 No. of Inter- ferences Low High Avg. 1115-1120 1121-1126 1127-1132 1133-1138 1139-1144 1145-1150 1151-1156 1157-1202 1203-1208 1209-1214 1225-1230 1231-1236 1237-1242 1243-1248 1249-1254 1255-1300 1301-1306 1307-1312 1313-1318 1319-1324 1335-1340 1341-1346 1351-1356 1357-1402 1403-1408 1409-1414 1415-1420 1421-1426 1427-1432 1535-1540 1541-1546 1547-1552 1553-1558 1559-1604 1605-1610 1611-1616 1617-1622 1623-1628 1629-1634 1645-1650 1651-1656 1657-1702 1703-1708 1709-1714 1715-1720 1721-1726 1727-1732 1733-1738 1739-1744 0 0 0 0 0 0 0 0 0 0 0 0 0 18 12 10 6 0 1 12 0 0 8 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 4 4 0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5 0 0 0 0 0 0 0 0 0 0 0 0 0 5 10 5 0 0 0 0 0 0 10 10 0 5 10 0 0 40 5 20 35 50 5 5 35 10 5 60 20 60 5 50 55 10 5 20 35 20 0 0 0 20 20 0 30 5 0 20 10 35 40 30 40 50 10 20 10 0 0 1.2 1.9 0 0.4 1.7 0 0 20.2 1.0 13.3 7.3 8.8 0.8 2.5 10.4 0.8 0.6 29.6 4.2 19.2 0.2 11.2 9.8 0.8 0.7 2.9 16.2 3.3 0 0 0 2.9 1.9 0 4.2 0.2 0 2.3 1.5 9.0 17.5 14.0 16.5 19.3 4.4 6.9 1.9 0 1115-1120 1121-1126 1127-1132 1133-1138 1139-1144 1145-1150 1151-1156 1157-1202 1203-1208 1209-1214 1225-1230 1231-1236 1237-1242 1243-1248 1249-1254 1255-1300 1301-1306 1307-1312 1313-1318 1319-1324 1335-1340 1341-1346 1351-1356 6-3 1357-1402 1403-1408 1409-1414 1415-1420 1421-1426 1427-1432 1535-1540 1541-1546 1547-1552 1553-1558 1559-1604 1605-1610 1611-1616 1617-1622 1623-1628 1629-1634 1645-1650 1651-1656 1657-1702 1703-1708 1709-1714 1715-1720 1721-1726 1727-1732 1733-1738 1739-1744 0 0 0 0 0 0 0 0 0 0 0 0 0 18 3 8 5 0 0 10 0 0 6 0 0 0 0 0 0 0 6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5 0 0 0 0 0 0 0 0 5 0 0 0 0 0 0 0 0 0 0 0 1Q 0 0 5 5 10 5 0 0 0 0 0 0 5 10 5 0 10 35 5 20 30 50 5 5 45 0 0 70 10 65 0 55 60 5 5 30 45 0 0 0 5 0 0 30 5 5 35 0 75 5 35 40 15 35 60 10 40 15 0 0 0 0.4 0.8 0.2 0 0.6 6.7 0.6 7.7 2.3 9.0 0.8 0.5 9.7 0 0 24.0' 1.8 15.8 0 8.1 8.8 0.2 1.0 2.9 20.6 0 0 0 1.0 0 0 5.4 0.4 0.4 5.8 0 34.0 0.8 9.6 11.0 9.4 14.0 17.3 4.2 13.1 6.0 - 12 - ------- TABLE 2.3. ROOF MONITOR EMISSIONS - METHOD 9 (Continued) (6-minute averages) 6-4 Date 1980 Time Observer 1 No. of Inter- ferences Low High Avg. Date 1980 Time Observer 2 No. of Inter- ferences Low High Avg. 1100-1105 1106-1111 1112-1117 1118-1123 1124-1129 1130-1135 1136-1141 1142-1147 1148-1153 1154-1159 1210-1215 1216-1221 1222-1227 1228-1233 1234-1239 1240-1245 1246-1251 1252-1257 1258-1303 1304-1309 1320-1325 1326-1331 1332-1337 1338-1343 1344-1349 1350-1355 1356-1401 1402-1407 1408-1413 1414-1419 1430-1435 1436-1441 1442-1447 1615-1620 1621-1626 1627-1632 1633-1638 1639-1644 1645-1650 1705-1710 1711-1716 1717-1722 1723-1728 1729-1734 1735-1740 1741-1746 1747-1752 1753-1758 1759-1804 0 2 0 2 0 0 0 0 0 0 1 4 0 0 0 0 0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 10 0 0 0 0 0 0 0 0 0 0 5 5 20 5 0 0 0 0 0 0 5 5 0 0 0 10 0 0 35 5 0 20 5 10 5 5 10 0 10 15 25 0 0 0 0 0 0 0 2.7 0 0 0 0 0 0 0 0 0 0 0.6 0.2 4.4 2.5 0 0 0 6-4 0 0 0 0.4 0.2 0 0 0 2.9 0 0 7.7 0.4 0 7.5 1.7 2.9 2.7 2.5 2.5 0 0.4 2.5 3.8 1100-1105 1106-1111 1112-1117 1118-1123 1124-1129 1130-1135 1136-1141 1142-1147 1148-1153 1154-1159 1210-1215 1216-1221 1222-1227 1228-1233 1234-1239 1240-1245 1246-1251 1252-1257 1258-1303 1304-1309 1320-1325 1326-1331 1332-1337 1338-1343 1344-1349 1350-1355 1356-1401 1402-1407 1408-1413 1414-1419 1430-1435 1436-1441 1442-1447 1620-1625 1626-1631 1632-1637 1638-1643 1644-1649 1650-1655 1710-1715 1716-1721 1722-1727 1728-1733 1734-1739 1740-1745 1746-1751 1752-1757 1758-1803 1804-1809 0 0 0 2 0 0 0 0 0 0 1 2 3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5 0 0 0 0 0 0 0 0 0 0 15 0 20 5 0 0 0 0 0 0 0 0 0 0 0 15 0 30 30 0 25 15 0 10 5 5 10 0 5 25 10 0 0 0 0 0 0 0 1.7 0 0 0 0 0 0 0 0 0 0 0.8 0 3.5 1.5 0 0 0 0 0 0 0 0 0 0 0 1.2 0 5.0 2.9 0 2.3 2.1 0 2.3 0.6 1.9 2.7 0 0.2 3.1 1.7 - 13 - ------- TABLE 2.3. ROOF MONITOR EMISSIONS - METHOD 9 (Continued) (6-minute averages) 6-5 Date 1980 Time Observer 1 No. of Inter- ferences Low High Avg. Date 1980 Time Observer 2 No. of Inter- ferences Low High Avg. 1100-1105 1106-1111 1112-1117 1118-1123 1124-1129 1130-1135 1136-1141 1142-1147 1148-1153 1154-1159 1210-1215 1216-1221 1222-1227 1228-1233 1234-1239 1240-1245 1246-1251 1316-1321 1322-1327 1328-1333 1334-1339 1340-1345 1346-1351 1352-1357 1358-1403 1404-1409 1410-1415 1416-1421 1422-1427 1440-1445 1446-1451 1452-1457 1458-1503 1504-1509 1510-1515 1516-1521 1522-1527 1528-1533 1534-1539 1550-1555 1556-1601 1602-1607 1608-1613 1614-1619 1620-1625 1626-1631 3 0 0 0 1 0 0 0 5 5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 10 0 0 5 0 0 0 0 30 90 0 0 80 100 15 65 0 0 30 20 0 0 0 0 0 0 0 0 0 0 20 85 0 40 5 10 0 10 40 0 60 0 0 0 0 0 0.6 0 0 0.5 0 0 0 0 5.8 11.7 0 0 30.0 19.2 1.5 9.2 0 0 7.7 5.6 0 6-5 0 0 0 0 0 0 0 0 0 3.5 21.0 0 4.8 1.2 1.0 0 2.9 2.9 0 34.6 1100-1105 1106-1111 1112-1117 1118-1123 1124-1129 1130-1135 1136-1141 1142-1147 1148-1153 1154-1159 1210-1215 1216-1221 1222-1227 1228-1233 1234-1239 1240-1245 1246-1251 1252-1257 1258-1303 1304-1309 1320-1325 1326-1331 1332-1337 1338-1343 1344-1349 1350-1355 1356-1401 1402-1407 1408-1413 1414-1419 1430-1435 1436-1441 1442-1447 1448-1453 1454-1459 1500-1505 1506-1511 1512-1517 1518-1523 1524-1529 1545-1549 1550-1556 1557-1602 1603-1608 1609-1614 1615-1620 7 0 0 0 0 0 0 0 0 5 0 0 0 2 0 0 0 22 24 8 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 - 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 15 0 10 0 0 0 5 0 90 0 0 5 0 - 20 90 15 65 0 0 30 20 0 0 0 0 0 0 0 0 0 0 0 75 20 0 5 20 0 10 35 0 0 0 0 0 1.2 0 1.0' 0 0 0 0.4 0 13. C 0 0 0 0 - 7.8 21.2 1.9 9.6 0 0 8.8 2.5 0 0 0 0 0 0 0 0 0 0 0 16.0 1.9 0 0.6 2.3 0 1.7 2.5 - 14 - ------- TABLE 2.3. ROOF MONITOR EMISSIONS - METHOD 9 (Continued) (6-minute averages) Date 1980 Time Observer 1 No. of Inter- ferences Low High Avg. Date 1980 Time Observer 2 No. of Inter- ferences Low High Avg. 6-5 1632-1637 1638-1643 1644-1649 1700-1705 1706-1711 1712-1717 1718-1723 1724-1729 1730-1735 1736-1741 1742-1747 1748-1753 1754-1759 6-6 1100-1105 1106-1111 1112-1117 1118-1123 1124-1129 1130-1135 1136-1141 1142-1147 1148-1153 1154-1159 1210-1215 1216-1221 1222-1227 1228-1233 1234-1239 1240-1245 1246-1251 1252-1257 1258-1303 1304-1309 1320-1325 1326-1331 1332-1337 1338-1343 1344-1349 1350-1355 1356-1401 1402-1407 1408-1413 0 0 0 0 7 0 0 0 0 0 9 0 0 16 4 0 0 0 0 0 3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5 0 0 0 0 0 0 0 0 0 5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 20 0 15 60 45 70 5 0 50 0 5 0 10 0 10 30 20 25 10 0 5 5 25 30 5 0 10 0 0 25 15 0 20 15 10 5 20 15 15 75 0 20 3.3 6-5 0 3.8 14.2 16.5 21.0 0.4 0 12.1 0 0.7 0 1.0 0 6-6 5.2 6.0 5.8 4.2 1.5 0 0.7 0.6 4.4 5.8 0.2 0 1.2 0 0 6.5 2.7 0 5.6 4.6 3.8 0.6 6.9 1.8 1.9 11.9 0 3.8 1621-1626 1627-1632 1633-1638 1639-1644 1655-1700 1701-1706 1707-1712 1713-1718 1719-1724 1725-1730 1731-1736 1737-1742 1743-1748 1749-1754 1100-1105 1106-1111 1112-1117 1118-1123 1124-1129 1130-1135 1136-1141 1142-1147 1148-1153 1154-1159 1210-1215 1216-1221 1222-1227 1228-1233 1234-1239 1240-1245 1246-1251 1252-1257 1258-1303 1304-1309 1320-1325 1326-1331 1332-1337 1338-1343 1344-1349 1350-1355 1356-1401 1402-1407 1408-1413 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 25 65 10 0 0 65 30 60 0 0 45 0 10 0 0 15 5 15 30 0 0 5 15 45 25 10 5 0 0 0 20 20 0 20 15 15 5 30 45 20 75 0 20 3.1 29.2 0.8 0 0 19.2 8.1 22.5 0 0 8.1 0 1.0 0 0 4.0 2.1 1.0 5.2 0 0 0.4 3.5 3.3 5.2 1.2 0.4 0 0 0 5.2 2.7 0 4.4 6.5 4.0 1.5 4.4 8.3 2.7 12.7 0 2.5 - 15 - ------- TABLE 2.3. ROOF MONITOR EMISSIONS - METHOD 9 (Continued) (6-minute averages) Date 1980 Time Observer 1 No. of Inter- ferences Low High Avg. 6-6 1414- 1430- 1436- 1442- 1448- 1454- 1500- 1506- 1512- 1518- 1524- 1419 1435 1441 1447 1453 1459 •1505 •1511 •1517 1523 •1529 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 40 5 5 10 5 10 10 0 5 60 0 9.8 1.5 0.8 1.7 0.6 1.9 0.6 0 0.8 22.5 6-6 Date 1980 Time Observer 2 No. of Inter- ferences Low High Avg. 1414- 1430- 1436- 1442- 1448- 1454- 1500- 1506- 1512- 1518- 1524- •1419 •1435 1441 1447 1453 •1459 1505 1511 1517 1523 1529 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 20 45 5 10 0 15 15 5 0 60 0 2.3 11.2 0.4 1.0 0 1.2 1.9 0.2 0 16.2 - 16 - ------- TABLE 2.4. ROOF MONITOR EMISSIONS - METHOD 22 Date 1980 Time Accumulated Observation Time (sec) Accumulated Emission Time (sec) Observer 1 Observer 2 Emission Frequency Percent Observer 1 Observer 2 6/2 1215-1244 1255-1324 1256-1355 1400-1429 1440-1514 1525-1554 1605-1634 1645-1714 6/3 1115-1144 1155-1224 1235-1304 1315-1344 1355-1424 1435-1504 1540-1609 1620-1649 1700-1729 1740-1809 6/4 1100-1129 1140-1209 1220-1249 1300-1329 1080 1800 1800 1650 1800 1800 1800 1800 1800 1800 1125 1605 1725 1800 1710 1800 1740 1800 1740 1800 1755 1770 35 0 186 358 51 260 59 171 709 695 653 575 434 60 388 1,740 847 0 364 a 362 311 241 462 411 24 314 246 92 479 778 634 585 441 80 396 1696 723 0 274 6 404 3.3 0 11.3 19.9 2.8 14.4 3.3 9.5 39.4 61.8 40.7 33.3 24.1 3.5 24.1 100.0 47.1 0 20.2 a 20.5 28.8 13.4 28.0 22.8 1.3 17.4 13.7 5.1 26.6 69.2 39.5 33.9 24.5 4.7 24.5 97.5 40.2 0 15.2 0.3 22.8 lStopwatch malfunctioned. - 17 - ------- TABLE 2.4. ROOF MONITOR EMISSIONS - METHOD 22 (CONTINUED) Date 1980 Time Accumulated Observation Time Accumulated Emission Time (sec) Observer 1 Observer 2 Emission Frequency Percent Observer 1 Observer 2 6/4 1340-1409 1420-1449 1620-1649 1700-1729 1740-1809 6/5 1100-1129 1140-1209 1220-1249 1315-1344 1355-1424 1435-1504 1515-1544 1555-1624 1635-1704 1715-1744 1715-1734 1745-1814 1750-1814 6/6 1100-1129 1140-1209 1220-1249 1300-1329 1800 1800 1800 1800 1800 1695 1650 1770 1800 1800 1800 1800 1800 1800 1725 1200 1740 1500 1500 1755 1800 1800 0 0 573 1, 231 576 0 59 221 925 333 55 497 480 154 532 80 519 255 74 525 0 0 670 1160 490 0 62 150 668 253 0 466 465 292 427 254 712 446 235 1215 0 0 31.8 68.4 32.0 0 3.6 12.5 51.4 18.5 3.1 27.6 26.7 8.6 30.9 5.3b 34.6 14.5 4.1 29.2 0 0 37.2 64.4 27.2 0 3.8 8.5 37.1 14.1 0 25.9 25.8 16.2 35. 6a 14.6 47.5 25.4 13.1 67.5 Based on a 20-minute observation period. Based on a 25-minute observation period. - 18 - ------- TABLE 2.4. ROOF MONITOR EMISSIONS - METHOD 22 (CONTINUED) Date 1980 Time Accumulated Observation Time (sec) Accumulated Emission Time (sec) Observer 1 Observer 2 Emission Frequency Percent Observer 1 Observer 2 6/6 1340-1409 1420-1449 1500-1529 1540-1609 1620-1649 1725 1800 1800 1800 1800 742 582 614 207 352 910 632 672 1038 578 43.0 32.3 34.1 11.5 19.5 52.8 35.1 37.3 57.7 32.1 - 19 - ------- TABLE 2.5. METHODS 9 AND 22 AVERAGES EPA Method Overall Unobscured1 24 Consecutive Readings 9 2.9 2.8 2.8 22 24.5 23.1 N/A Excludes any 6-minute or 30-minute or full set data with periods of obscured view. - 20 - ------- TABLE 2.6. STACK GAS PARAMETERS - SECONDARY INLET, NO. 2 FURNACE Date Fan 1980 Condition 6-3 Auto Average fi -3 Med (Blow) Average 6-3 High Average Test Number 1 2 3 1 2 3 1 2 3 Flowrate scfm 98,900 93,700 94,100 95,600 89,100 86,900 86,200 87,400 184,000 185,000 183,000 184,000 Stack Temp F 75 75 75 75 75 75 75 75 75 75 75 75 - 21 - ------- 3.0 OBSERVATION LOCATIONS AND EMISSION POINTS BASIC OXYGEN FURNACE (Q-BOP) Both Furnace Nos. 1 and 2 were observed during the study. The tap side of Furnace No. 2 was observed from one of two positions depending on the wind direction: Locations A and B, each about 20-feet southwest and southeast of the furnace, respectively. Heating of the teeming ladle with a gas flame made Location A very hot, especially when the flames shot 3 to 6-feet above the operations floor with the wind blowing toward Location A. The observers would then move to Location B.. For Furnace No. 1, the tap side location was approximately 20-feet southwest of the furnace (Location C). The charge side observation location alternated between Points D and E. Point D, used for observing Furnace No.2, was about 75-feet northwest of the furnace. Point E was about 40-feet northwest of Furnace No. 1. The observation points on the tap side were the best available. The tap side of the furnace was very dangerous, especially during tapping when hot metal would fly across the aisle. Due to a cramped working area on this side, observers could not locate themselves any further away from the furnace. The observation locations on the charge side permitted optimum viewing of the furnaces and were relatively safe - 22 - ------- from the slag pots and scrap ladles moving overhead. Figure 3.1 presents a plan view of the Q-BOP shop and respective observation locations. ROOF MONITOR The three location sites used during the study afforded the best view of the roof monitor and were the only ones available. These observation locations are presented in Figure 3.2. Observations for both Methods 9 and 22 began each morning from a parking lot approximately 350-feet due east of the roof monitor. The sun was behind the observer's back until about 1400 at which time the observers had to move to a second parking lot location southeast of the roof monitor. The sun angle at this point was between 85° and 95°. A strong southerly wind on June 5, 1980 made observa- tions from either of the previously mentioned locations impossible. Therefore, observers repositioned themselves in an old slag field approximately 300-feet northeast of the roof monitor. With clear sky conditions, the sun would have interfered with the readings. However, it was a cloudy, overcast day and direct sunlight was blocked. VELOCITY TRAVERSE The secondary scrubber inlet was a 96-inch I.D. duct located approximately 50-feet above ground level. The duct was accessed through a 3-inch sampling port - 23 - ------- Tap side Charge side Pulpit Figure 3.1. Basic oxygen furnace observation locations. ------- •N K 1 n_ /mi i 1 1 in mi ii ii mi Him mi i ii 1 1 ii in mi minium ii minium IHI/ i /. A pm Guard house Infirmary Garage Admin. building ' am Slag field location Figure 3.2. Roof monitor observation locations, ------- which was less than one duct diameter downstream and less than one duct diameter upstream from any flow distur- bances. Velocity pressures were measured at 24 traverse points. The temperature was assumed to be ambient. Traverse points 1 through 8 had no velocity pressures due to the poor sampling location (inadequate port to disturbance distances). Figure 3.3 presents a plan view of the sampling location and a stack cross-section. Velocity traverses could not be conducted during a heat cycle because of the unsafe sampling location. The overhead crane barely cleared the ductwork above the furnace and no one was allowed in that area during the oxygen blow. Therefore, only the fan was run to simulate actual operating conditions in the stack. Stack temperatures under this condition were ambient but could vary greatly (increase) during a heat cycle. This should be taken into consideration when reviewing flowrate data. Three traverses were made under each of three fan operating conditions: auto, medium, and high. - 26 - ------- Duct junction Bend Sampling port Flow from - Q-BOP Q-BOP enclosure Elevation view 96-in. I.D. Figure 3.3. Sampling location and stack cross-section. - 27 - Point 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 Distance (Inches) 1.1 3.1 5.3 7.6 10.1 12.7 15.5 18.6 22.1 26.1 31.0 38.2 57.8 65.0 69.9 73.9 77.4 80.5 83.3 85.9 88.4 90.7 92.9 94.9 ------- 4.0 OBSERVATION PROCEDURES Visible emission observations were performed in accordance with EPA Method 22, Visible Determinations of Fugitive Emissions from Material Processing Sources, and EPA Method 9, Visual Determination of the Opacity of Emissions from Stationary Sources. BASIC OXYGEN FURNACE The entire heat of the furnace was observed. A single heat, which was also considered one test run, included the scrap charge, hot metal charge, oxygen blow, turndown, any additional blows and turndowns, tapping, and deslagging. Two persons observed the charge side and two observed the tap side, simultaneously, all four using Method 22. Radio communications provided coordina- tion between the observers during each test. The designated start and stop times for the above sequences were keyed to the following activities: Scrap charge (charging doors open)- from start of ladle tilt to its return to an upright position. Hot metal charge (charging doors open)- two hot metal ladles were used to charge the furnace. The onset of the nitrogen purge prior to the hot metal addition signified the start of the hot metal charge and ended when the charge doors closed. - 28 - ------- Oxygen Blow (charging doors closed) - flames would appear along the top of the furnace at the onset and completion of the oxygen blow. These flames were used as the start and finishing points of the blow. Turndown (charging doors closed)- as the furnace tilts forward a bright glow appears at the upper edge of the charging doors signifying the start of turndown. (The bright glow turned into flames as the furnace tilted to a 45° position). Turndown is completed when the glow disappears from the upper edge of doors as the furnace returns to its upright position. Tapping (charging doors closed) - as the furnace tilts backwards, (toward tapping side), the bright glow of the metal can be seen at the lower edge of the door indicating the start of tapping. Completion is when the glow disappears as the furnace tilts upright. Deslagging (charging doors closed) - as the furnace tilts forward a bright glow at the edge of the charging doors signified the start of deslagging. Deslagging is completed when the glow disappears from the upper edge of the doors as the furnace returns to its upright position. - 29 - ------- The heats were generally back to back extending the observa- tion period to two or more hours. This was in violation of Method 22 which requires that the observer take a 5 to 10-minute break for every 15 to 20-minutes of observations. Since emissions were noted during the oxygen blow in the first three tests, the entire heat had to be observed, from the scrap charge to the end of deslagging. So as not to violate Method 22, alternate heats were read. A total of 10 heats were observed. Roof Monitor Four observers were situated outside the BOF shop to observe the fugitive emissions from the roof monitor. Two persons used Method 22, taking a 10-minute break in between each 30-minute observation. The other two persons read Method 9 for 1-hour intervals with 10- minute breaks. All four observations began simultaneously, with the exception of the Method 9 readings obtained on June 5, 1980. A discrepancy in observation times between the Method 9 readers was noted after observers relocated due to a wind change (about 1300). Thereafter, the 1-hour intervals were not simultaneous for the remainder of that day. Velocity Traverse Exhaust gas sampling was conducted in accordance with procedures outlined in the U.S. Environmental - 30 - ------- Protection Agency's "Standards of Performance for New Stationary Sources"(Federal Register 40CFR60, December 23, 1971, as amended through August 18, 1977), Methods 1 and 2. The duct was divided into equal areas and exhaust gas velocities and temperatures were measured at each midpoint. Velocity pressures were obtained using an S-type Pitot tube and inclined 0 to 10-inch water gauge manometer. Temperatures were measured with an iron-constantan (I/O thermocouple attached to the Pitot tube and to a calibrated pyrometer. - 31 - ------- |