United States Office of Air Quality
Environmental Protection Planning and Standards
Agency Research Triangle Park NC 27711
EMS Report 80-BYC-10
August 1981
Air
Benzene Fugitive Leaks
Coke Oven By-Product Plants
Emission Test Report
Republic Steel Corporation
Gadsden, Alabama
-------
DCN 81-222-018-01-18 EMK Report No. 80-BYC-10
EMISSION TEST REPORT
FUGITIVE EMISSIONS TESTING
AT THE
REPUBLIC STEEL
GADSDEN PLANT
Prepared by:
D.P. Wiesenborn, J.I. Steinmetz, and G.E. Harris
RADIAN CORPORATION
8501 Mo-Pac Boulevard
Austin, T&xas 78759
Prepared for:
Dan Bivins
U.S. Environmental Protection Agency
ESED/EMB (MD-13)
Research Triangle Park, North Carolina 27711
EPA Contract No. 68-02-3542
Work Assignment No. 1
ESED No. 74/4J
11 September 1981
-------
CONTENTS
Section Page
1 Introduction 1
2 Summary of Results 2
3 Process Description ... 6
4 Methodology 8
4.1 Screening Procedures 8
4.2 Sampling Procedures 9
4.3 Analytical Techniques 12
5 Quality Control/Quality Assurance 13
5.1 Quality Control for Screening Procedures 13
5.2 Quality Control for Analytical and sampling procedures. 15
5.2.1 Blind Standards 15
5.2.2 Accuracy Checks 16
Appendix A 21
Appendix B 35
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FIGURES
Number Page
3-1 Light oil recovery unit, Republic Steel 7
4-1 Sampling train for baggable source of hydrocarbon emissions . 10
5-1 Mass spectrum of pure benzene on SP-2100/bentone column 17
5-2 Mass spectrum of light oil product on SP-2100/bentone 18
5-3 Mass spectrum of light oil product on TCEP 19
ii
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TABLES
Number Page
2-1 OVA screening value distribution: Republic Steel,
Gadsden Plant 3
2-2 Summary of benzene and non-methane hydrocarbon leak rates
(Ib/hr) from sampled sources: Republic Steel Gadsden
Plant 4
2-3 Comparison of benzene content in emissions and in liquid
lines: Republic Steel Gadsden Plant 5
5-1 Calibration checking of OVA and TLV 14
5-2 Blind standards data listing 16
5-3 Accuracy checks data listing 20
iii
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SECTION 1
INTRODUCTION
This report presents the results of testing for fugitive VOC (Volatile
Organic Compounds) and benzene emissions at the Republic Steel plant in Gadsden,
Alabama. The testing was performed by Radian Corporation on December 8 through
December 12, 1980.
This work was funded and administered by the Emission Measurement Branch
of the U.S. Environmental Protection Agency under Contract No. 68-02-3542. The
results of this testing may be used in support of a National Emission Standard
for Hazardous Air Pollutants for benzene from coke oven by-products recovery
units in steel mills.
Potential sources of fugitive benzene emissions in the by-product unit
were screened with a portable hydrocarbon detector to estimate the frequency
of leak occurrence. Liquid and vapor benzene fugitive emission rates were
quantified by collecting and analyzing samples from leaking fittings. Also,
liquid samples were obtained from process lines to provide data on the
proportion of benzene in process lines relative to the proportion of benzene
in emissions from fittings in those lines.
The following sections present a summary of results, a description of the
process configuration, the testing -methodology, and QA/QC procedures. Example
calculations and a full listing of data and other supplemental information
are included in the appendices.
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SECTION 2
SUMMARY OF RESULTS
This section presents a summary of the fugitive emission data gathered
at the Republic Steel plant in Gadsden. All data are presented in the form
of original data sheets in Appendix B.
The plant screening results are presented in Table 2-1. This table
presents the distribution of OVA readings for each source type.
The results of the baggable sampling are presented in Table 2-2. The
mass emission rates are presented in pounds per day for each source in terms of
both benzene and nonmethane hydrocarbons. Mass emission rates are also pre-
sented in terms of vapor phase and liquid phase emission rate. Each source was
rescreened immediately before and after bagging. The average of these two
values is also presented in Table 2-2 for both the OVA and the TLV.
A comparison of the benzene concentration in vapor-phase and total emissions
with the benzene concentrations in the liquid lines is presented in Table
2-3. The benzene concentration in the vapor-phase leak and the total leak
(vapor plus liquid) is expressed as the ratio of the benzene emission rate
to the non-methane hydrocarbon emission rate, since bag samples are diluted
with air.
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TABLE 2-1. OVA SCREENING VALUE DISTRIBUTION: REPUBLIC STEEL GADSDEN PLANT
OVA
SCREENING
VALUE (ppmv)
0 to 199
200 to 9,000
>_ 10,000
Total Sources Screened
FLANGES
#a
47
0
0
47
%b
100.0
0.0
0.0
100.0
THREADED
FITTINGS
#
42
0
0
42
%
100.0
0.0
0.0
100.0
VALVES
//
44
4
5
53
%
83.0
7.5
9.4
100.0
PUMPS
SEALS
'#
0
0
4
4
%
0.0
0.0
100.0
100.0
EXHAUSTERS
#
4
2
0
6
%
66.
33.
0.
100.
7
3
0
0
a) # - number of sources in each category
b) % - percent of total sources screened
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TABLE 2-2. SUMMARY OF BENZENE AND NON-METHANE HYDROCARBON LEAK RATES (LB/HR)
FROM SAMPLED SOURCES: REPUBLIC STEEL GADSDEN PLANT
Block Valves
Control Valves
Pumps
Exhausters
Sampling
Date
12/10/80
12/11/80
12/12/80
12/10/80
12/10/80
12/11/80
12/12/80
Source
ID
23
121
122
123
124
125
129
73
32
21-SC
119-S
28-S
120-S
2
4
Mean OVA
Rescreenlng
Value3
0
10000
57501
1800
65001
55000
40000
1250
75000
75001
67500
100001
57000
2000
500
Mean TLV
Rescreenlng Benzene Leak Rates
Value Vapor
b
2590
8901
40
6301
800
4300
700
9351
9000
8700
10001
8401
2450
800
0.000260
0.044714
0.001576
0.131233
0.001347
0.006814
0.000941
0.435302
0.289490
0.446587
0.121617
0.626817
0.001901
0.000755
Li
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
2.
0.
0.
quid
299810
000000
040316
000000
000000
000000
000000
000000
000000
000000
212200
478370
538640
000000
000000
Total
0.000260
0.085030
0.001576
0.131233
0.001347
0.006814
0.000941
0.435302
0.289490
1.658787
0.599987
3.165457
0.001901
0.000755
Nonmethane-HC Leak
Vapor
0.000915
0.045277
0.002448
0.113854
0.001460
0.006442
0.001490
0.476986
0.370162
0.485804
0.130749
0.733095
0.011467
0.005489
Liquid
0.437040
0.000000
0.055379
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
1.582500
0.722610
3.314150
0.000000
0.000000
Rates
Total
.
0.000915
0.100656
0.002448
0.113854
0.001460
0.006442
0.001490
0.476986
0.370162
2.068304
0.853359
4.047245
0.011467
0.005489
a) Average of before and after sampling screening values (given in Appendix B-2).
b) This symbol indicates that no data was taken in that category.
c) S denotes a single seal pump.
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l/i
TABLE 2-3. COMPARISON OF BENZENE CONTENT IN EMISSIONS AND IN LIQUID LINES:
REPUBLIC STEEL GADSDEN PLANT
Line
BTX Light
Oil
BTX Light
Oil
Footnotes;
a)
b)
c)
d)
Temp Press Wt % Benzene
(°F) (psig) in Line
71 35 71.5
50 20 71.5
! /
Weight percent benzene in the vapor =| .. ' ~
\ /
Weight percent benzene in the total leak- 1 — — - — i-
S denotes a pump with a single seal «
HA denotes high ambient: ambient benzene content
Source Wt
ID in
21SC
28S
32
119S
120S
121
122
123
124
125
129
\
emissions of benzene 1
emissions of NMHC /
% Benzene3
Vapor Leak
79
93
92
93
87
29,HAd
99
64
115 e
92
106 e
100
b
Wt % Benzene
in Total Leak
79
70
92
80
78
29
85
64
115
92
106
' \
mass emissions of benzene|X 100
mass emissions of NMHC
at least 40 percent of
;
/
sample benzene
content
Analysis for benzene and NMHC were performed on different instruments; probably almost
all of the NMHC in this sample is benzene
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SECTION 3
PROCESS DESCRIPTION
The Republic Steel plant at Gadsden, Alabama operates with a wash oil
absorption system to recover light oil from the coke oven gas. The crude
light oil product is sent outside of the plant for refining.
During the testing period, the coke ovens were producing 1470 tons per
day of coke and 22.5 MMSCFD of coke oven gas. The light oil recovery unit
was recovering 5,630 gallons per day of crude BTX light oil.
A simplified flow diagram for the plant is shown in Figure 3-1. The
benzolized wash oil from the scrubber is stripped with steam to separate the
light oil from the wash oil. The light oil vapors then go to a rectifier.
The rectifier splits the light oil into two fractions, an overhead and a
bottoms fraction. The overhead fraction includes essentially all of the
benzene, and is referred to as BTX light oil. These BTX vapors are condensed
and the water taken out in the light oil separator.
Fugitive emissions testing was to be performed in all areas of the
plant with at least 4 weight percent or more benzene. This included the
stripper overhead, the BTX product, and the BTX storage and loading areas.
Also screened were the exhausters, which are upstream from light oil recovery
on the coke oven gas line, and are not shown in Figure 3-1. The benzolized
wash oil and the rectifier bottoms (secondary oil) contain less than 4 weight
percent benzene and were not screened.
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VAPOR LIGHT OIL
AND STEAM
BTX + STEAM
DEBENZOLIZED
WASH OIL
COKE
OVEN
GAS
Numbers following the letters VA and PU are source ID numbers
for valves and pumps, respectively, from which fugitive emissions
were detected.
Numbers in parentheses are the weight percent benzene in that
lime.
Figure 3-1. Light Oil Recovery Unit, Republic Steel.
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SECTION 4
METHODOLOGY
The fugitive emissions testing at the Republic Steel Gadsden plant
included both "screening" and "bagging" operations. Screening is a generic
term covering any quick portable method of detecting fugitive emissions. Bag-
ging refers to a quantitative emission measurement achieved by enclosing the
source in a Mylar® shroud and analyzing an equilibrium flow of air through
the enclosure.
4.1 SCREENING PROCEDURES
Screening was done according to the procedures specified in EPA's proposed
Method 21, a copy of which may be found in Appendix A-2. The instrument used
in performing this screening was the Century Systems Organic Vapor Analyzer
(OVA) Model 108. Method 21 requires the results of the screening to be
recorded Oas specified in the applicable regulation) only if the leak
definition Is met or exceeded. Since this effort was more oriented to standards
development than to regulatory monitoring, the exact screening value was record-
ed for all sources.
The screening methods were used to survey every accessible valve and pump,
and a portion of the flanges, on lines handling at least 4 weight percent
benzene. Only one-third of the flanges were screened because of their large
population. Exhausters were also screened, although they are not in the light
oil recovery section of the plant and the coke oven gas they handle contains
less than 4 weight percent benzene. Exhausters were included because they
can potentially have high emissions.
-------
The survey was conducted on a line-by-line basis with plant flow diagrams
to ensure that no sources were missed and to group sources subject to similar
process conditions. Plant personnel corroborated the identification of process
lines and supplied data that was not otherwise immediately available, such as
the composition and phase of the material in the line.
All leaking valves, pump seals, and exhauster seals were tagged with their
respective ID numbers and were subsequently bagged.
4.2 SAMPLING PROCEDURES
Bagging procedures were carried out according to methods developed in
previous petroleum refinery testing. Before and after a source was sampled, it
was again screened. This time, however, a J.W. Bacharach "TLV Sniffer" (TLV)
was used in addition to the OVA. The OVA uses a flame ionization detector and
has a quick response time that makes it ideal for the initial screening. The
TLV uses a catalytic oxidation detector and has a slower response than the
OVA.
The leaking area of the source was completely enclosed in a shroud of
Mylar® plastic to contain any emissions. Mylar® is well suited to this func-
tion, because it does not absorb significant amounts of hydrocarbons and has
a high melting point (250°C). The enclosures were kept as small as possible,
generally less than one cubic foot in volume except for enclosures of exhauster
seals. A small enclosure provided a more effective seal, minimized the time
required to make the enclosure and reach steady-state conditions, and minimized
the condensation of heavy hydrocarbons within the enclosure.
The enclosure was connected to the sampling train shown in Figure 4-1.
The sampling train included a cold trap, a dry gas meter, and a vacuum pump.
The vacuum pump induced a flow of air, plus any fugitive emissions contained
-------
MAGNEHELIC
x-
a
V
V
TEt
1
1
-~X
n\ ._
L'l 1
^J
r
IT
/
—
'
[— r—
If
dT
\
1 —
-^
!2
t
/-I -
f
LEAKING
THIS LINE SHOULD
BE AS SHORT
,A t! PD Q <5in 1 P
/ 1\ \3 \ \J O O 1 U l_ L
V,
\
-1
COLD TRAP
(ICE DATH)
TRAP
(
i
— il_|f7
i—w 1
a
DRY OAS
VALVE
METER
Hg MANOMETER
CONTROL
^ VALVE ^—v > — «-
i-^-^l 1 Fi~~~ ' O I
n^j1 >-<
P
[
FILTER VACUUM PUMP
^Q=®F=K SAMPLE DAQ
SMALL \\ /
DIAPHRAGM \
PUMP TWO WAY VALVE
Figure 4-1. Sampling train for baggable source of hydrocarbon emissions.
-------
within the enclosure, through the sampling train. A magnehelic connected to
the enclosure with a short piece of latex tubing was used to ensure that a
slight, but measurable, vacuum was maintained within the enclosure. A slight
vacuum prevented fugitive emissions from leaking out of the enclosure. To
obtain an adequate vacuum on the two leaking exhausters, it was necessary to
connect each enclosure to two sampling trains.
The cold trap was used to condense water and heavy organics that might
otherwise condense downstream in lines and equipment. This trap consisted
of a 500 ml flask in an ice bath. No condensate was observed at the Gadsden
plant; however, if an organic condensate were collected, it would be measured,
analyzed, and included in calculating the total leak rate.
Downstream from the cold trap, a dry gas meter measured the volume of
gas that passed through the sampling train. By measuring the volume of gas
during a known period of time, it was possible to calculate the dry gas
flow rate. The gas flow rate could be varied, and the maximum flow rate
achievable was about 2.5 cubic feet per minute. The temperature and pressure
of the gas were measured to allow a conversion to standard conditions.
When sufficient time had passed to allow the system to reach steady-state
(generally, 4 minutes were more than adequate for an enclosure of 1 cubic foot),
a Tedlar® sampling bag was filled from the discharge of the small Teflon®-lined
diaphragm pump. A second Tedlar® bag was filled with a sample of ambient air
near the enclosure. The two samples were then taken to the mobile lab on the
plant grounds for analysis.
Liquid leak rates were estimated by capturing the liquid in a watchglass
and measuring the volume collected over a known period of time. Samples of
each, liquid leak and of the- liquids from process lines were taken back to the
laboratory for benzene analysis. Sample bottles were filled to the brim to
minimize any vapor overhead space that would allow the benzene in the liquid
sample to become dispersed between 2 phases.
11
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4.3 ANALYTICAL TECHNIQUES
To quantify the VOC emissions from the bagged sources, the concentration
of total hydrocarbon and also that of benzene were determined using gas chroma-
tographic procedures. Primary analysis of fugitive volatile organic compounds
(VOC) was performed on a Byron 301C Total Hydrocarbon Analyzer (THC). The
THC has an upper detection limit of 20,000 ppmv. Dilutions of more concen-
trated samples were made with a 1.5 liter gas-tight syringe.
Methane calibrations were carried out daily on the THC with an 8000 ppmv
methane/air standard. Nonmethane hydrocarbon calibrations were also carried
out daily on the THC with a 713 ppmw NBS propane standard.
Analyses for benzene were performed on a Hewlett Packard 5730A Dual FID
Gas Chromatograph. Dual gas samples were introduced simultaneously onto sepa-
rate columns with a Valco 10 port Hastalloy C multiport valve installed immedi-
ately forward of the GC syringe injection ports. Peak integrations were com-
piled on two Hewlett Packard 3380A electronic integrators. Liquid samples
were analyzed by normal syringe injection techniques using benzene as an ex-
ternal standard.
The columns and conditions used for the benzene analyses are listed
below:
1/8" OD, 2 mm ID, 15 feet, 5% SP-2100/1.75% Benton 34
on 100/120 mesh Supelcoport.
1/8" OD, 2 mm ID, 15 feet, 10% TCEP on 100/120 mesh
Chromosorb P acid washed.
N2 carrier at 30 ml/min.
Isothermal at 110°C.
The instrument was calibrated daily with a 5571 ppmw benzene in air standard.
Single analyses were done simultaneously on the two different columns after
calibration.
12
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SECTION 5
QUALITY CONTROL/QUALITY ASSURANCE
5.1 QUALITY CONTROL FOR SCREENING PROCEDURES
Screening at the Gadsden plant was done with a single Century Systems
Organic Vapor Analyzer (OVA) Model 108 and one J.W. Bacharach Instrument
Company "TLV Sniffer." The corresponding instrument identification numbers
are given below:
Device Type Assigned ID Number
OVA 3
TLV 4
The OVA and TLV instruments were calibrated in the morning each day before
they were used. Standards of 90 ppmv and 1990 ppmv hexane in air were used to
obtain a two point calibration on the TLV; 7990 ppmv methane in air was used
to calibrate the OVA. Before a recalibration was made each day, the values
obtained from the instrument were recorded. This served two purposes:
• a check for instrument damage or malfunction, and
a rough- check of the stability of the daily calibration.
In addition to the high- (.and low for TLV) standard calibrations, a
dilution probe was occasionally attached to the instrument and another read-
ing was taken. The probe was s-et at 10:1 dilution of the high standard con-
centration. The calibration data is summarized in Table 5-1.
13
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TABLE 5-1. CALIBRATION CHECKING OF OVA AND TLV
Date
12/08/80
12/09/80
12/10/80
12/11/80
12/12/80
Footnotes:
a) OVA
b) OVA
c) TLV
d) TLV
e) The
OVA 3 t TLV 4 d
High Standard, ppmv Oil Probe, ppmv Low Standard.ppmv"" High Standard, ppmv"
3700
650e 3000
7500 1100 1800
\
>10,000 700 500 2000
>10,000 2000
calibration standard contained 7990 ppmv methane in air
reading with dilution probe should be 800 ppmv
low calibration standard contained 90 ppmv hexane in air
high calibration standard contained 1990 ppmv hexane in air
low valve was caused by an' instrument malfunction that "was -immediately corrected.
-------
The calibration checking results do indicate some significant drift. It
should be noted, however, that these readings are taken in the morning before
calibration and not at the close of the screening day. It is likely that most
of the calibration drift occurs due to the overnight shutdown and recharge
rather than during the days screening. The phenomenon of calibration drift
over a shutdown and re-start has been observed in other studies. The low OVA
calibration value observed on December 9 was caused by an instrument malfunc-
tion that was immediately repaired.
5.2 QUALITY CONTROL FOR ANALYTICAL AND SAMPLING PROCEDURES
Quality control procedures were implemented to insure accurate, consistent,
and unbiased analytical and sampling techniques during the project. The
procedures discussed in this section include:
• blind standards
• accuracy checks
5.2.1 BLIND STANDARDS
Standard materials were prepared and submitted to the analyst without
divulging the concentration of benzene or hexane present in order to evalute
the quality of data generated by the Byron 301C Total Hydrocarbon Analyzer
(THC) and the HP5703A Dual FID Gas Chromatograph. A 262.7 ppm hexane standard
and a 1075.9 ppm benzene standard were implemented to demonstrate the precision
and accuracy of the analysis of bag samples by the Byron THC and the HP Gas
Chromatograph, respectively. Table 5-2 lists the data from the blind standard
analyses. The difference between the prepared and measured concentration is
shown as the percent difference. The percent difference is calculated as follows;
% Diff=(Prepared-Measured Concentration)X 100/Prepared Concentration.
15
-------
TABLE 5-2. BLIND STANDARDS DATA LISTING
Prepared Measured Diff. Percent
Instr. Date Gas Type (ppmw) (ppmw) (ppmw) Diff
THC
HP
12/09/80
12/10/80
Hexane
Benzene
262.7
1075.9
247.9
1042.3
14.8
33.6
5.63
3.12
In addition to the blind standard materials analysis, a sample of light
oil product was analyzed by GC/MS to confirm that the amounts of benzene found
by GC were only benzene and were not any coeluting compounds. Analysis of this
sample and a sample of pure benzene, as depicted graphically in Figures 5-1
through 5-3, demonstrates.that there were no other compounds present with the
same retention time as benzene.
5.2.2 ACCURACY CHECKS
Accuracy checks were used to evaluate the overall accuracy of the sampling
and analysis techniques. It basically involves inducing a known flow rate of
a concentrated calibration gas into the sampling system and taking a bag sample
of the diluted calibration gas at the exit of the system. Analysis of the bag
sample by THC or GC provides data to calculate the measured leak rate. The
induced leak rate is calculated from the flow rate and concentration of the
induced standard gas.
Table 5-3 lists the data from two accuracy checks. The measured leak
rate, induced leak rate, and the percent recovery are shown. The percent
recovery is calculated as follows:
r, Measured Leak Rate - -._<,.
Percent Recovery = , —-—. B X 100%
J Induced Leak Rate
16
-------
FRII 17437 SPECTRUM 56 RETENTION TIME 3.3
U.K&ST 4« 78.0.100.9 77.0, 33.9 51.0, 31.8 53.0. 20.6
LAST 4! 77.0, 33.9 78.9,100.0 79.0, 6.8 80.1, .3
PAGE 1 V • 1.00
100
80
60
40
20
0
100
80
60
40.
20.
0.
i ,,,], aj-1
1
20 49 69 89 109 130 140 169
' 1S0 ' 208 ' 880 ' 340 ' 280 ' 288 ' 38(9 ' Q^'tJ
Figure 5-1. Mass Spectrum of Pure Benzene on
SP-2100/Bentone Column
17
-------
FRh 17445 SPECTRUM 81 RETENTION TIME 4.7
LARGST 4i 78.9,199.9 76.9. SS.6 58.9, 16.8 59.9, 14.5
LAST 41 76.9, 4.9 76.9, 3S.6 78.9,199.9 79.9, 6.7 '
PAGE 1 V • 1.90
L00
3d
60
40
0
199
80
69
40
20.
0
, , „ I , ,li
1
29 44 64 80 190 129 149 169
130 200 220 240 2fi0 280 309 33Q
Figure 5-2. Mass Spectrum of Light Oil Product
on SP-2100/Bentone
18
-------
UORK AREA SPHCTPUn FRN 17507
: 78.0,100.0 76.9, E8.9
4i 73.9, 7.a 78.9, 26.9
+• 120 -114 -1
PAC£ 1 Y - 1.00
54.0, 23.5 51.0, 31.2
73.0,10O.d 79.0, 7.2
38
60
4«
20
0
•p*" '" 1"
"40
T1" ""|"»
140
80
40
0
J I
Figure 5-3. Mass Spectrum of Light Oil Product
on TCEP
19
-------
TABLE 5-3. ACCURACY CHECKS DATA LISTING
Measured Induced
Standard Leak Rate Leak Rate Percent
Date Type (lbs/hr) (Ibs/hr) Recovery
12/09/80 Benzene 0.0008817 0.0007554 116.7
12/09/80 Hexane 0.0008251 0.0008232 100.2
20
-------
REPUBLIC STEEL
GADSDEN PLANT
APPENDIX A
CALCULATIONS AND METHODS
A-l Sample Emission Calculations
A-2 EPA Proposed Method 21
21
-------
REPUBLIC STEEL
GADSDEN PLANT
A-l Sample Emission Calculations
22
-------
APPENDIX A-l
EMISSION CALCULATIONS
The emission rates can be calculated from the physical measurements
recorded during the operation of the sampling train and with the anlyses
of the hydrocarbon content of the air passing through the sampling train.
The basic equation is:
ki DF(P-AP)M(C -C )
T 1 A / A 1 \
where L = Hydrocarbon vapor emission rate, Ib/hr
_6
k.! = 2.75x10 (°R-min-mole/SCF-in.Hg-hr-ppmw)
D = Dry gas meter correction factor (dimensionless)
F = Flow rate, cubic feet per minute
P = Ambient atmospheric pressure, in. Hg
AP = Pressure differential between ambient pressure
and pressure at dry gas meter, in. Hg
M = Average molecular weight of gas (essentially
air) passing through dry gas meter, Ib/lb.mole
Q
T = Total hydrocarbon concentration in air passing
through the dry gas meter, ppmw
Q
A = Total hydrocarbon concentration in air near the
sampled leak source, ppmw
T = Temperature of gas (air) stream at the dry gas
meter, °F.
The constant k^ is a product of several conversion -constants:
, (.520°R) x (.60 min/hr).
—
(379 ^f ) x (29.92 in. Hg) x (lQ6ppmw)
mole
23
-------
ki = 2.75 x 10~ (°R-min-mole/SCF-in.Hg-hr-ppmw)
As an example calculation, assume a total hydrocarbon concentration of 19,000
ppmw was measured in the gas stream from a tent around a leaking source in an
ethylene unit. The hydrocarbon would be assumed to be hexane (MW-86). The
following values were recorded during the sampling:
F = 1.5 CFM
P = 29.9 in. Hg
AP = 2.0 in. Hg (at the dry gas meter)
T = 19,000 ppmw
A = 20 ppmw
T = 75°F
and D = 0.95
10s
Then M = 19.000 + 10b - 19,000 = 29'37
86 29
The vapor emission rate L is then calculated from Equation (A-l)
(2.75 x 10~6)(0.95)(1.5)(29.9 - 2.0)(29.37X19,000 - 20)
460 + 75
L = 0.114 Ib/hr.
The vapor emission rate of benzene is estimated from the hydrocarbon
emission rate and the concentration data for benzene and non-methane hydro-
carbons. The equation used is:
(CB " CAB) (A-2)
where B = Benzene vapor emission rate, Ib/hr
Cij = Benzene concentration in air passing through
B
the dry gas meter, ppmw
C. = Benzene concentration in air near the sampled
leak source, ppmw.
24
-------
For example, using the previous example with the data:
C = 15,500 ppmw
AB
the benzene vapor emission rate is calculated:
B = 0.114 (15,500 - 10)
(19,000 - 20)
B = 0.093 Ib/hr.
The emission rates for liquid leaks are calculated by the equation:
TLLR =7.93 -^— (A-3)
t
where TLLR = Total liquid leak rate, Ib/hr
7.93 = Conversion factor from g/.sec to Ib/hr
V = Volume of liquid collected, cc
t = Time of collection, sec
P = Density of sample, g/cc.
For example, 4.0 cc of liquid from a leaking source were captured in 60
seconds, and the liquid was found to have a density of 0.75 g/cc, then:
TLLR = (7.93)(0.75)(4.0)/(60)
TLLR = 0.40 Ib/hr.
The liquid benzene leak rate is:
BLLR = TLLR [Benz.J (A-4)
100
where BLLR = Benzene liquid leak rate
[BenzJ= Benzene concentration in liquid, weight percent
For example, if the liquid leak described above was found to have 79 wt per-
cent benzene then:
BLLR = (0.40)(79)/(100)
BLLR = 0.31 Ib/hr.
25
-------
REPUBLIC STEEL
GADSDEN PLANT
A-2 EPA Proposed Method 21
26
-------
PROPOSED METHOD.21. DETERMINATION.OF.VOLATILE ORGANIC COMPOUND LEAKS
1. Applicability and Principle
1.1 Applicability. This method applies to the determination of
volatile organic compound (VOC) leaks from organic process equipment.
These sources include, but are not limited to, valves, flanges and other
connections, pumps and compressors, pressure relief devices, process
drains, open-ended valves, pump and compressor seal system degassing
vents, accumulator vessel vents, and access door seals.
1.2 Principle. A portable instrument is used to detect VOC leaks
from individual sources. The instrument detector is not specified, but
it must meet the specifications and performance criteria contained in
paragraph 2.1.
2. Apparatus
2.1 Monitoring Instrument. The monitoring instrument shall be as
follows:
2.1.1 Specifications.
a. The VOC instrument detector shall respond to the organic
compounds being processed. Detectors which may meet this requirement
include, but are not limited to, catalytic oxidation, flame ionization,
infrared absorption, and photoionization.
27
-------
b. The instrument shall be intrinsically safe for operation in
explosive atmospheres as defined by the applicable U.S.A. Standards
(e.g., National Electrical Code by the National Fire Prevention Association),
c. The instrument shall be able to measure the leak definition
concentration specified in the regulation.
d. The instrument shall be equipped with a pump so that a
continuous sample is provided to the detector. The nominal sample flow
rate shall be 1-3 liters per minute.
e. The scale of the instrument meter shall be readable to
±5 percent of the specified leak definition concentration.
2.1.2 Performance Criteria. The instrument must meet the
following performance criteria. The definitions and evaluation
procedures for each parameter are given in Section 4.
2.1.2.1 The instrument response time must be 30 seconds or less.
The response time must be determined for the instrument system
configuration to be used during testing, including dilution equipment.
The use of a system with a shorter response time than that specified
will reduce the time required for field component surveys.
2.1.2.2 Calibration Precision: The calibration precision must be
less than or equal to 10 percent of the calibration gas value.
2.1.2.3 Quality Assurance. The instrument shall be subjected to
response time and calibration precision tests prior to being placed in
service. The calibration precision test shall be repeated every
6 months thereafter. If any modification or replacement of the
28
-------
instrument detector is required, the instrument shall be retested and a
new 6 month quality assurance test schedule will apply. The response
time test shall be repeated if any modifications to the sample pumping
system or flow configuration is made that would change the response
time.
2.3 Calibration Gases. The monitoring instrument is calibrated in
terms of parts per million by volume (ppmv) of the compound specified in
the applicable regulation. The calibration gases required for
monitoring and instrument performance evaluation are a zero gas (air,
3 ppmv VOC) and a calibration gas in air mixture approximately equal to
the leak definition specified in the regulation. If cylinder
calibration gas mixtures are used, they must be analyzed and certified
by the manufacturer to be within ±2 percent accuracy. Calibration gases
may be prepared by the user according to any accepted gaseous standards
preparation procedure that will yield a mixture accurate to within
±2 percent. Alternative calibration gas species may be used .in place of
the calibration compound if a relative response factor for each
instrument is determined so that calibrations with the alternative
species may be expressed as calibration compound equivalents on the
meter readout.
3. Procedures
3.1 Calibration. Assemble and start up the VOC analyzer and
recorder according to the manufacturer's instructions. After the
appropriate warmup period and zero or internal calibration procedure,
introduce the calibration gas into the instrument sample probe. Adjust
the instrument meter readout to correspond to the calibration gas value.
29
-------
If a dilution apparatus is used, calibration must include the instrument
and dilution apparatus assembly. The nominal dilution factor may be
used to establish a scale factor for converting to an undiluted basis.
For example, if a nominal 10:1 dilution apparatus is used, the meter
reading for a 10,000 ppm calibration would be set at 1,000. During
'field surveys, the scale factor of 10 would be used to convert
measurements to an undiluted basis.
3.2 Individual Source Surveys.
3.2.1 Case I - Leak Definition Based on Concentration Value.
Place the probe inlet at the surface of the component interface where
leakage could occur. Move the probe along the interface periphery while
observing the instrument readout. If an increased meter reading is
observed, slowly probe the interface where leakage is indicated until
the maximum meter reading is obtained. Leave the probe inlet at this
maximum reading location for approximately two times the instrument
response time. If the maximum observed meter reading is greater than
the leak definition in the applicable regulation, record and report the
results as specified in the regulation reporting requirements. Examples
of the application of this general technique to specific equipment types
are:
a. Valves—The most common source of leaks from valves is at the
seal between the stem and housing. Place the probe at the interface
where the stem exits the packing gland and sample the stem
circumference. Also, place the probe at the interface of the packing
gland take-up flange seat and sample the periphery. In addition, survey
30
-------
valve housings of multipart assembly at the surface of all interfaces
where leaks can occur.
b. Flanges and Other Connections—For welded flanges, place the
probe at the outer edge of the flange-gasket interface and sample around
the "circumference of the flange. Sample other types of nonpermanent
joints (such as threaded connections) with a similar traverse.
c. Pumps and Compressors—Conduct a circumferential traverse at
the outer surface of the pump or compressor shaft and seal interface.
If the source is a rotating shaft, position the probe inlet within one
centimeter of the shaft-seal interface for the survey. If the housing
configuration prevents a complete traverse of the shaft periphery,
sample all accessible portions. Sample all other joints on the pump or
compressor housing where leakage can occur.
d. Pressure Relief Devices—The configuration of most pressure
relief devices prevents sampling at the sealing seat interface. For
those devices equipped with an enclosed extension, or horn, place the
probe inlet at approximately the center of the exhaust area to the
atmosphere for sampling.
e. Process Drains—For open drains, place the probe inlet at
approximately the center of the area open to the atmosphere for
sampling. For covered drains, place the probe at the surface of the
cover interface and conduct a peripheral traverse.
f. Open-Ended Lines or Valves—Place the probe inlet at
approximately the center of the opening to the atmosphere for sampling.
31
-------
g. Seal System Degassing Vents and Accumulator Vents—Place the
probe inlet at approximately the center of the opening to the atmosphere
for sampling.
h. Access Door Seals—Place the probe inlet at the surface of the
door seal interface and conduct a peripheral traverse.
3.2.2 Case II-Leak Definition Based on "No Detectable Emission".
a. Determine the local background concentration around the source
by moving the probe inlet randomly upwind and downwind at distance of
one to two meters from the source. If an interference exists with this
determination due to a nearby emission or leak, the local background
concentration may be determined at distances closer to the source, but
in no case shall the distance be less than 25 centimeters. Note the
background concentration and then move the probe inlet to the surface of
the source and conduct a survey as described in 3.2.1. If a concentration
increase greater than 2 percent of the concentration-based leak definition
is obtained, record and report the results as specified by the regulation.
b. For those cases where the regulation requires a specific device
installation, or that specified vents be ducted or piped to a control
device, the existence of these conditions shall be visually confirmed.
When the regulation also requires that no detectable emissions exist,
visual observations and sampling surveys are required. Examples of this
technique are:
i. Pump or Compressor Seals—If applicable, determine the type
of shaft seal. Perform a survey of the local area ambient VOC
32
-------
concentration and determine if detectable emissions exist as described
in 3.2.2.a.
ii. Seal system degassing vents, accumulator vessel vents,
pressure relief devices—If applicable,, observe whether or not the
applicable ducting or piping exists. Also, determine if any sources
exist in the ducting or piping where emissions could occur prior to the
control device. If the required ducting or piping exists and there are
no sources of where the emissions could be vented to the atmosphere
prior to the control device, then it is presumed that no detectable
emissions are present.
4. Instrument Performance Evaluation Procedures
4.1 Definitions.
4.1.1 Calibration Precision. The difference between the average
VOC concentration indicated by the meter readout for consecutive
repetitions and the known concentration of a test gas mixture.
4.1.2 Response Time. The time interval from a step change in VOC
concentration at the input of the sampling system to the time at which
90 percent of the corresponding final value is reached as displayed on
the instrument readout meter.
4.2 Evaluation Procedures. At the beginning of the instrument
performance evaluation test, assemble and start up the instrument
according to the manufacturer's instructions for recommended warmup
period and preliminary adjustments. If a dilution apparatus is used
during field surveys, the evaluation procedure must be performed on the
instrument-dilution system combination.
33
-------
4.2.1 Calibration Precision Test. Make a total of nine
measurements by alternately using zero gas and the specified calibration
gas. Record the meter readings (example data sheet shwon in Figure 21-
1).
•4.2.2 Response Time Test Procedure. Introduce zero gas into the
instrument sample probe. When the meter reading has stabilized, switch
quickly to the specified calibration gas. Measure the time from
concentration switching to 95 percent of final stable reading. Perform
this test sequence three times and record the results (example data
sheet given in Figure 21-2).
4.3 Calculations. All results are expressed as mean values,
calculated by:
*'
Where:
x. = Value of the measurements.
2 = Sum of the individual values.
— = Mean value.
A
n = Number of data points.
34
-------
REPBULIC STEEL
GADSDEN PLANT
APPENDIX B
ORIGINAL DATA SHEETS
B-l Screening Data
B-2 Screening Sheets for Sample Data
B-3 Sample Data
B-4 Analysis Data
B-5 OVA and TLV Calibration Data
B-6 Dry Gas Meter Calibration Data
B-7 Accuracy Check Data
35
-------
REPUBLIC STEEL
GADSDEN PLANT
B-l Screening Data
36
-------
TABLE B-l.l. SOURCE TYPE IDENTIFICATION CODES
Source Type
Flange
Process Drain
Open-End Line
Agitator Seal
Relief Valve
Screwed Fitting
Valves
Block valve - gate type
Block valve - globe type
Block valve - plug type
Block valve - ball type
Block valve - butterfly type
Block valve - other types
Control valve - gate type
Control valve - globe type
Control valve - plug type
Control valve - ball type
Control valve - butterfly type
Control valve - other types
On-Line Pump Seals*
Single, mechanical, emission point at seal
Single, mechanical, emission point at vent
Single, mechanical, other emission point
Double, mechanical, emission point at seal
Double, mechanical, emission point at vent
Double, mechanical, other emission point
Source Type
Code
1
2
3
4
5
6
10
11
12
13
14
15
20
21
22
23
24
25
30
31
32
33
34
35
Continued .
37
-------
TABLE B-l.l. CONTINUED
Source Type
Source Type
Code
Single, packed, emission point at seal
Single, packed, emission point at vent
Single, packed, other emission point
Sealless pumps
Off-Line Pump Seals
Single, mechanical, emission point at seal
Single, mechanical, emission point at vent
Single, mechanical, other emission point
Double, mechanical, emission point at seal
Double, mechanical, emission point at vent
Double, mechanical, other emission point
Single, packed, emission point at seal
Single, packed, emission point at vent
Single, packed, other emission point
Sealless pumps
On-Line Compressor Seals
Single, mechanical, emission point at seal
Single, mechanical, emission point at vent
Single, mechanical, other emission point
Double, mechanical, emission point at seal
Double, mechanical, emission point at vent
Double, mechanical, other emission point
Single, packed, emission point at seal
Single, packed, emission point at vent
Single, packed, other emission point
Sealless compressors
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
Continued
38
-------
TABLE B-l.l. CONTINUED
- ™ Source Type
Source Type _ , JY
3* Code
Off-Line Compressor Seals
Single, mechanical, emission point at seal 60
Single, mechanical, emission point at vent 61
Single, mechanical, other emission point 62
Double, mechanical, emission point at seal 63
Double, mechanical, emission point at vent 64
Double, mechanical, other emission point 65
Single, packed, emission point at seal 66
Single, packed, emission point at vent 67
Single, packed, other emission point 68
Sealless compressors 69
Exhausters
Suction side 70
High pressure side 71
* 0 = outboard seal; I = inboard seal
39
-------
TABLE B-1.2. STREAM IDENTIFICATION CODES
Code Description of Stream (Columns 25-27)
1 Coke oven gas
2 BTX fraction of light oil; Unit 3 refers to this as
Secondary Oil - a convention different from that used at
Unit 2 where secondary oil is the non-BTX fraction of the
light oil
3 Steam and vaporized light oil
4 Light oil - mostly BTX with some 2° oil
5 Light oil (BTX and 2° oil)
Service
1 Gas
2 Light liquid
3 Heavy liquid
Elevation
1 Sources at ground level
2 Sources at one level above ground level
3 Sources at two levels above ground level
40
-------
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COMMENTS:
-------
SCREENING DATA SHEET
reenin
Team
urc
ID
13
Pro
Un
Primary
Material
25
28
Secondary
Material
32
ratu
p
Ul
Ul
Line
essure
psig
WJ
•J
bie
Air
era
°F
o\l
tMl
J5JQ
J
50
IV \9
o
Jii
0
0
c?
IvU
\o
0
00
1L
0
0
0
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0
'1
ii
>/
JI
J^
0
ill
I I I
A
1
1 1
Ait<
-------
REPUBLIC STEEL
GADSDEN PLANT
B-2 Screening Sheets for Sample Data
49
-------
Card 1 (IF
SCREENING SHEET
FOR SAMPLE DATA
1. Radian Valve/Pump ID # I 0|7.| E|"A| 0 |o | Q| 2J 2. Unit/Process^?^
3. Plant Name
Mo. Day Yr.
4. Date
1 \-2\l\Z
11
6. Before Tenting
Screening Time
(Military Time)
5. Screener's ID
17
7. Before Tenting OVA I 1 I l^l
Screening Value
TLV Screening Value
1
\
\1
\o
],-\
|O
3 1
8. Screener's ID
38
9. After Sampling / \4\3\O
Screening Time ^1
(Military Time)
10. After Sampling OVA
Screening Value
\3o\v\o
TLV Screening
Value
1000
J^iublo
Comment 1
59
Comment 2
6 1
50
-------
RADIAN
Card 1 Is I d
SCREENING SHEET
FOR SAMPLE DATA
1. Radian Valve/Pump ID #
2. Unit/Process
3. Plant Name I\P
-------
RADIAN
Card 1
SCREENING SHEET
FOR SAMPLE DATA
1. Radian Valve/Pump ID #
2. Unit/Process
3. Plant Name
Mo. Day Yr.
4. Date
\
t |0
11
6. Before Tenting
Screening Time
(Military Time)
5. Screener's ID It) IP
1 7
7 - Before Tenting OVA
Screening Value
j | 51 Clo lob
2«*
TLV Screening Value
3 1
00
8. Screener's ID
38
9. After Sampling
Screening Time
(Military Time)
10. After Sampling OVA
„Screening Value
TLV Screening
Value
52
Comment 1
59
Comment 2
b 1
52
-------
RADIAN
Card 1
LS_
1
SCREENING SHEET
FOR SAMPLE DATA
1. Radian Valve/Pump ID #
2. Unit/Process
3. Plant Name H0JuuJj£
Mo. Day Yr.
4. Date I/ \2\l \O
1 1
6.
Before Tenting / 1.51 / |£)
Screening Time 2 o
(Military Time)
5. Screener's ID
17
7. Before Tenting OVA
Screening Value 2l*
\r \'•' I ' . TLV Screening Value
3 1
8. Screener's. ID
38
9. After Sampling
Screening Time
(Military Time)
10. After Sampling OVA
Screening Value
TLV Screening
Value
52
Comment 1
59
Comment 2
6 1
53
-------
RADIAN
Card 1 Is.
SCREENING SHEET
FOR SAMPLE DATA
1. Radian Valve/Pump ID #
2. Unit/Process
- fo l '
3. Plant Name
Mo. Day Yr
4. Date
/£
I \t\S\o
11
6. Before Tenting
Screening Time
(Military Time)
5. Screener's ID
7. Before Tenting OVA
Screening Value 21*
\ i
Y)
\o
\o \*
TLV Screening Value
I \i\G\C\C\:
3 1
8. Screener's ID
38
9. After Sampling
Screening Time
(Military Time)
10. After Sampling 0V
Screening Value
'LV Screening
Value
( I /lololoh
52
Comment 1
Comment 2
59
6 1
-------
RADIAN
Card 1 LS_
\
1. Radian Valve/Pump ID
SCREENING SHEET
FOR SAMPLE DATA
2. Unit/Process
P>P
3. Plant Name
Mo. Day Yr.
4. Date
12
1 1
6. Before Tenting / ]/ \Q\S
Screening Time 20
(Military Time)
5. Screener's ID
17
7. Before Tenting OVA
Screening Value
2l*
TLV Screening Value
o |o ]o
3 1
8. Screener's ID \D\P\W
38
9. After Sampling [ / [/ \4\S\
Screening Time ^i
(Military Time)
10. After Sampling OVA
Screening Value TsT
7|5|^k)|Q
TLV Screening
Value
Comment 1 I
59
Comment 2
6 1
55
-------
RADIAN
Card 1 Is I C
SCREENING SHEET
FOR SAMPLE DATA
1. Radian Valve/Pump ID #
V\2 \P \L> \&\ I |3|o
2. Unit/Process
g.p.
3. Plant Name
5fe/,
Mo. Day Yr.
4. Date
\0
5. Screener's ID
1 7
6. Before Tenting __/J / | (|Q
Screening Time 2 o
(Military Time)
7. Before Tenting OVA
Screening Value 2l*
I I7lo
o|c
,|o
TLV Screening Value
/ 01
3 1
!. Screener's ID I I |
38
9. After Sampling
Screening Time
(Military Time)
10. After Sampling OVA
Screening Value
NTLV Screening
'Value
52
Comment 1 I
59
Comment 2
6 1
56
-------
RADIAN
Card 1 IS
SCREENING SHEET
FOR SAMPLE DATA
1. Radian Valve/Pump ID #
2. Unit /Process ('/dh> &P
3. Plant Name /7/^j.uitu.
Mo. Day Yr.
Date
1 12
l\l
Bp
11
6.
Before Tenting
Screening Time
(Military Time)
5. Screener's ID
1 7
7. Before Tenting OVA
Screening Value
*L\H\0\0\0
TLV Screening Value
\ \l \o\e\
c-\ i
3 1
8. Screener's ID L
38
After Sampling
Screening-Time
(Military Time)
10. After Sampling OVA
Screening Value
\3\0\o\o\e
TLV Screening
Value
52
Comment 1
59
Comment 2
6 1
57
-------
RADIAN
Card 1 Is I d
i
Radian Valve/Pump ID #
Plant Name / e.*f,i j)£r_
SCREENING SHEET
FOR SAMPLE DATA
2. Unit/Process
Mo. Day Yr.
4. Date
11
6. Before Tenting
Screening Time
(Military Time)
1 . Before Tenting OVA
Screening Value
2I+
8. Screener's ID I— I I
38
9. After Sampling
Screening Time
(Military Time)
5. Screener's ID \&\PvO
1 7
I f
TLV Screening Value
3 1
10. After Sampling OVA
Screening Value
TLV Screening
Value
52
Comment 1
59
Comment 2
6 1
58
-------
RADIAN
Card 1 IsTcl
i
1. Radian Valve/Pump ID #
SCREENING SHEET
FOR SAMPLE DATA
0\2.\\AA\c\t
> 131*2.
2. Unit/Process \y R'F
3. Plant Name
Mo. Day Yr.
4. Date
\
&:. Before Tenting
Screening Time 2o
(Military Time)
5. Screener's ID
|W
17
7. Before Tenting OVA
\7\n\o\o\n
Screening Value 2"*
TLV Screening Value
3 1
8. Screener's ID
38
9. After Sampling \ |4 |4|o[
Screening Time ^ j
(Military Time)
10. After Sampling OVA
Screening Value
Iflbloloh
TLV Screening
Value
\ Is lo lo I V
52
Comment 1
59
Comment 2
6 1
59
-------
RADIAN
Card 1
SCREENING SHEET
FOR SAMPLE DATA
1. Radian Valve/Pump ID #
Q|2.|V|A|o|o|7]3
2. Unit/Process
n
3. Plant Name l(jL0<.JJLe.
Mo. Day Yr.
4. Date U I 2| 1 |2|8|O
11
6. Before Tenting / jfT| 2| £>
Screening Time 20
(Military Time)
5. Screener's ID
17
7. Before Tenting OVA
Screening Value
. Screener's ID
21
TLV Screening Value
I 1 1^1olo
3 1
-^LJs&Jt )tJ££LfC,UVW. C0 fW\. SVt^AA*] <~W XLC/^^'i^-Wj*. riff
38
9. After Sampling
Screening Time
(Military Time)
10. After Sampling OVA
Screening Value "Vs*"
ISIolo
TLV Screening
Value
52
Comment 1
59
Comment 2
e i
60
-------
RADIAN
Card 1 Is I C
SCREENING SHEET
FOR SAMPLE DATA
1. Radian Valve/Pump ID #
-------
RADIAN
Card 1
SCREENING SHEET
FOR SAMPLE DATA
1. Radian Valve/Pump ID #
2. Unit/Process
3. Plant Name
/
Mo . Day
4. Date / I-2- / |ff
±
6. Before Tenting
Yr.
&\C 5. Screener's ID Q> r\tJ
1 7
/I3WIS
Screening Time 20
(Military Time)
7. Before Tenting OVA
\/\0\<-->\
-------
RADIAN
Card 1
SCREENING SHEET
FOR SAMPLE DATA
1. Radian Valve/Pump ID #
"' [£ I \J \A \ O \ f [2. \ 2J
2. Unit/Process
3. Plant Name
Mo. Day Yr.
4. Date I/ 1.3 I / I
11
6. Before Tenting \tf\g ]p>
Screening Time 2 o
(Military Time)
5. Screener's ID
17
7. Before Tenting OVA
Screening Value 21*
TLV Screening Value
3 1
8. Screener's ID
38
9. After Sampling
Screening Time
(Military Time)
10. After Sampling OVA
Screening Value
1 1
\-S\o\o b
TLV Screening
Value
f
|-7k?bb
52
Comment 1 I
59
Comment 2
6 1
63
-------
RADIAN
Card 1 OF
SCREENING SHEET
FOR SAMPLE DATA
1. Radian Valve/Pump ID #
2. Unit/Process
3. Plant Name
Mo. Day Yr.
4. Date
/ 12 /I/
11
Before Tenting
Screening Time
(Military Time)
5. Screener's ID Ifl P
1 7
Before Tenting OVA
Screening Value
TLV Screening Value
3 1
8. Screener's ID
38
9. After Sampling
Screening Time
(Military Time)
10. After Sampling OVA
Screening Value
1 1
1 1 Ifl
TLV
Value
Screening (III \B\C
52
Comment 1 I
59
Comment 2
6 1
64
-------
RADIAN
Card 1 Is I cl
i
1. Radian Valve/Pump ID #
SCREENING SHEET
FOR SAMPLE DATA
0 \2 \ V\A \ 0\ I \3-\tl
2. Unit/Process
3. Plant Name
Mo. Day Yr.
4. Date
TTaol
11
Before Tenting
Screening Time 20
(Military Time)
5. Screener's ID \D \P \i\,
1 7
7. Before_ Tenting OVA
I \0\0\0\0\t
Screening Value 2l*
TLV Screening Value
1 V
°\
o
£j
I
3 1
8. Screener's ID
38
9. After Sampling [ / \@ \\
Screening Time
(Military Time)
10. After Sampling OVA
Screening Value
o|o
TLV Screening
Value
52
Comment 1
59
Comment 2
s i
65
-------
Card 1 Is I cl
i
1. Radian Valve/Pump ID #
SCREENING SHEET
FOR SAMPLE DATA
0\2.\V\A \0\t
2. Unit/Process
3. Plant Name
Mo. Day Yr.
4. Date
t\2
11
6. Before Tenting /
Screening Time 2o
(Military Time)
5. Screener's ID
1 7
7. Before Tenting OVA
Screening Value
TLV Screening Value
3 1
Kdolo
c-1
8. Screener's ID
38
9. After Sampling /
Screening Time
(Military Time)
10. After Sampling OVA
Screening Value
\f
1 -~
ID
0
°\
G
TLV Screening
Value
f I I H -K
I I I i \u\o
52
Comment 1
59
Comment 2
61
66
-------
RADIAN
Card 1
SCREENING SHEET
FOR SAMPLE DATA
1. Radian Valve/Pump ID #
\3.\\/\A\O\t \2\
2. Unit/Process
3. Plant Name
Mo. Day Yr.
4. Date
11
6. Before Tenting
Screening Time
(Military Time)
5. Screener's ID
1 7
7. Before Tenting OVA
Screening Value 2l*
c^loio
TLV Screening Value
3 1
8. Screener's ID
38
9. After Sampling | /
Screening Time
(Military Time)
10. After Sampling OVA
Screening Value
TLV Screening
Value
52
Comment 1
59
Comment 2
6 1
67
-------
REPUBLIC STEEL
GADSDEN PLANT
B-3 Sample Data
68
-------
Card 1 II \S\
i
SAMPLE DATA SHEET
1. Radian Valve/Pump ID# |O|2.|£|%| O|Q|O|2.| 2. Unit/Process
3
3. Plant Name
Mo. Day
4. Date
6. Time
11
\* \0\0\
20
(Military Time)
25
10. Meter #1 I l^m.
11. Time #1
I I |Q
37
14. Temp #1 °F
"t5
16. Bar. Press., in. Hg.
3|o| .
51
18. DGM
Factor
20. Vol. Org.
Condensate ml
61
66
21. Coll. time, minutes
5. Sampler's Initials
17
7- Cart ID# I 1 I 8. N.B.# 9. Page #
12. Meter #2
.IQISI
13. Time #2 I I I
if i
15. Temp #2 °F
1*8
17. AP, in. Hg.
•I.ISI5
56
11 . lOlllSI 19. Meter #
I I J 15 I 22. Specific Gravity I I
71.
of Organic
Condensate
75
23. Comment
78
69
-------
Card 1
SAMPLE DATA SHEET
1. Radian Valve/Pump ID# |o| 2.| E.|:*| o |o | o|-z.| 2. Unit/Process
3
cote
3. Plant Name
Mo. Day Yr.
4. Date
6. Time
11
10.
20
(Military Time)
5. Sampler's Initials
17
7. Cart ID# l2j 8. N.B.i
9. Page
10. Meter #1 IH3I51 .1111
25
11. Time #1 I I 1°
14. Temp #1 °F I 1 ~l\o
12. Meter #2
J5|. |S1Z
13. Time #2 I I I
15. Temp #2 °F I I "71
16. Bar. Press., in. Hg.
5 1
18. DGM Correction]
Factor
20. Vol. Org. I—
Condensate ml 66
17- AP- in. Hg.
1 Ul. U
56
19. Meter #
~7/
21. Coll. time, minutes
22. Specific Gravity | |
of Organic 7S
Condensate
23. Comment
73
70
-------
Card I
SAMPLE DATA SHEET
1. Radian Valve/Pump ID# |O|2.l£r|X| o|o|O|^| 2. Unit/Process Qo)c£
3
3. Plant Name
4. Date
6. Time
Mo. Day Yr.
I i [7.1 1 |-2,| 6|Q
11
rrrn
20
(Military Time)
5. Sampler's Initials 1-PlWl
17
7. Cart ID# LU 8. N.B.i
9. Page #
. Meter #1 I I 1 Ife If H
10
11. Time #1
25
37
14. Temp #1 °F I HIP I
r
16. Bar. Press., in. Hg.
3M.
18. DGM Correction
Factor
20. Vol. Org.
Condensate ml
66
12. Meter #2 I bl
-------
coopommoM
Card 1 II Isl
i
SAMPLE DATA SHEET
1. Radian Valve/Pump ID# I o|z|&|y. | o\o |o.| 4 | 2. Unit/Process c. o
3
3. Plant Name
4.
6.
Mo. Day Yr.
Date I M3.ll I^J&IQ
11
Time I I I I I
9 n
(Military Time)
5. Sampler's Initials
17
7. Cart ID# I"21 8. N.B.i
9. Page #
10. Meter #1 I l^ni-l'
25
11. Time #1
37
14. Temp #1 °F
12. Meter #2 \_\ti\\° I .
5 1
18. DGM Correction -H". I <•> I 51
Factor ^, ^
20. Vol. Org. I—I—I—I—L
Condensate ml 66
17- AP, in. Hg.
19. Meter #
1 131.
IV
56
21. Coll. time, minutes I I I i |5
22. Specific Gravity
of Organic 7S
Condensate
23. Comment
78
7
72
-------
RADIAN
Card 1 ll Isl
SAMPLE DATA SHEET
1. Radian Valve/Pump ID# WZ, \-Pti I 1 \ 0\ Z-l ) \ 2. Unit/Process
3. Plant Name
Mo. Day Yr.
4. Date
6. Time
/IZJ /\0
11
(Military Time)
5. Sampler's Initials ]F&-\
I 7
1. Cart ID# [I] 8. N.B.# 9. Page #
10. Meter #1
11. Time #1
25
3 7
14. Temp #1 °F | [
1*5
12. Meter
13. Time #2
15. Temp #2 °F
16. Bar. Press., in. Hg.
3p|. \Z\
5 I
17. AP, in. Hg.
18. DGM Correction, _/J_i
19. Meter #
Factor
61
20. Vol. Org.
Condensate ml
I I I
66
21. Coll. time, minutes.
22. Specific Gravity I 1 1
of Organic
Condensate
75
23. Comment
78
73
-------
RADIAN
Card 1
SAMPLE DATA SHEET
1. Radian Valve/Pump ID# I 0\ Z| P\M\<%\tf\2\£ I 2. Unit/Process
3
3. Plant Name
Mo. Day Yr.
4. Date
6. Time
/rz-
/i/
(Military Time)
5. Sampler's Initials
1 7
7. Cart ID#
8. N.B.#
9. Page #
10. Meter #1
25
12. Meter #2
3
11. Time #1
13. Time #2
14. Temp #1 °F \
16. Bar. Press., in. Hg.
3ioi ,
5 1
6 1
18. DGM Correction,
Factor
20. Vol. Org.
Condensate ml 66
15. Temp #2 °F
1*8
17. AP', in. Hg.
19. Meter #
56
21. Coll. time, minutes
22. Specific Gravity I L
of Organic
Condensate
75
23. Comment
78
74
-------
RADIAN
UMIT
Card 1
SAMPLE DATA SHEET
1. Radian Valve/Pump ID#
3. Plant Name
\4\/ \/ ff \ 2. Unit/Process
3 '
Mo. Day Yr.
4. Date
6. Time
11
/!/ if Ifll"
20
(Militax-y Time)
10. Meter #1
11. Time #1
14. Tenro
25
16. Bar. Press., in.
5 1
18. DGM Correction.
Factor
20. Vol. Org.
Condensate ml
6 1
66
21. Coll. time, minutes
71
5. Sampler's Initials
7. Cart ID#
8. N.B.#
31
12. Meter #2 Iffl/ l7lx
13. Time #2
15. Temp #2 °F
14131
9. Page #
17. AP, in. Hg.
I/I,
56
19. Meter #
22. Specific Gravity
of Organic
Condensate
75
23 . Comment
78
-------
RADIAN
Card 1
SAMPLE DATA SHEET
. Radian Valve/Pump ID# ft" 1^1 F\U f0l /I A°\ 2. Unit/Process
3. Plant Name
Mo. Day Yr.
4. Date
>; Time
TJO
11
5. Sampler's Initials
7. Cart ID# [7
17
8. N.B.#
(Military Time)
10. Meter #1
11. Time #1
25
12. Meter #2 lf[? J^l - I/
14. Temp #1 °F I
16. Bar. Press., in. Hg. 13l £J •
5 1
18. DGM CorrectionJZ_L_L^i2E
TT^i^*- «-«. 6 1
13. Time #2
15. Temp #2 °F
17. AP, in. Hg
19. Meter #
9. Page #
I/L,
56
Factor
20. Vol. Org.
Condensate ml 6S
21. Coll. time, minutes
22. Specific Gravity
of Organic
Condensate
75
23. Comment
78
76
-------
RADIAN
Card 1 Ills
SAMPLE DATA SHEET
1. Radian Valve/Pump ID# \O\Z\ \/\/h£\ti l5 |£l 2. Unit/Process
3. Plant Name
Mo. Day Yr.
4. Date
6. Time
11
(Military Time)
5. Sampler's Initials
7. Cart ID# \J_
1 7
8. N.B.#
10. Meter //I
11. Time
25
37
14. Temp #1 °F
1*5
12. Meter #2
13. Time #2
15. Temp #2 °F
1*8
9. Page #
16. Bar. Press., in. He. l5l^l . I 2\O\ 17. AP, in. Hg.
6 1
18. DGM Correction,
Factor
20. Vol. Org.
Condensate ml
21. Coll. time, minutes
19. Meter #
22. Specific Gravity I I I
of Organic 7S
Condensate
23. Comment I
78
77
-------
Card 1 1
SAMPLE DATA SHEET
1. Radian Valve/Pump ID# \0 &-\}/ ffil U\^\1\2>\ 2. Unit/Process
3. Plant Name
Mo. Day Yr.
4. Date
6. Time
/ i
(Military Time)
5. Sampler's Initials
1 7
7. Cart ID#
8. N.B.#
9. Page #
10. Meter #1
25
12. Meter #2
11. Time #1
13. Time #2
14. Temp #1 °F I 17l P|
15. Temp #2 °F
16. Bar. Press., in. Hg.
5 1
18. DGM Correction]/L
Factor
6 1
20. Vol. Org.
Condensate ml ss
17. AP; in. Hg.
I/
56
19. Meter #
21. Coll. time, minutes I I u.
22. Specific Gravity I ! I
of Organic 7S
Condensate
23. Comment
78
78
-------
RADIAN
Card 1 Ills
SAMPLE DATA SHEET
1. Radian Valve/Pump ID# \O\'Z\]/\ft\ £)!/ |Z| /i 2. Unit/Process
3
3. Plant Name
Mo. Day Yr.
4. Date
6. Time
\ I
5. Sampler's Initials
7. Cart ID# \±\ 8. N.B.#
1 7
(Military Time)
10. Meter #1 2|7|7l.
11. Time #1
12. Meter #2 \2\Z\3- |JT7
13. Time #2
14. Temp #1 °F I ffl 7
15. -Temp #2 °F
16. Bar. Press., in. Hg.
If
5 1
17. AF, in. Hg.
9. Page #
IZI
56
6 1
18. DGM
Factor
20. Vol. Org.
Condensate ml
21. Coll. time, minutes
19. Meter #
i i 14
71
22. Specific Gravity I L
of Organic 75
Condensate
23. Comment
78
-------
RADIAN
Card 1
SAMPLE DATA SHEET
1. Radian Valve/Pump ID# \&\2-\{/\A&\ J \Z\Z» 2. Unit/Process
3. Plant Name
Mo. Day
4. Date
6. Time
Zl Xl/ I
1 1
I
20
(Military Time)
10. Meter #1
11. Time #1
25
14. Temp #1 °F | I
1*5
16. Bar. Press., in. Hg. I 3\O I .
5 1
18. DGM Correction! /I - lOl e?\ &
Factor °^
20. Vol. Org.
Condensate ml
66
21. Coll. time, minutes
23. Comment
78
5. Sampler's Initials
1 7
7: Cart ID#
12. Meter #2
13. Time #2
8. N.B.#
If l
^^™^™^
15. Temp #2 °F 1
1*8
17. AP, in. Hg.
19. Meter #
9. Page #
22. Specific Gravity
of Organic
Condensate
7S
80
-------
RADIAN
Card 1 Ills
SAMPLE DATA SHEET
1. Radian Valve/Pump ID# \O\Z-\ i/Vfl£M A?J&\ 2. Unit/Process
3. Plant Name
Mo. Day Yr.
4. Date
6. Time
I/
5. Sampler's Initials
1 7
(Military Time)
10. Meter #1
11. Time #1
14. Temp #1 °F
25
12. Meter #2
13. Time #2
15. Temp #2 °F
\3\7
5 1
16. Bar. Press., in. He. \2>\O\ • \ I!% I 17. AP, in. Hg.
19. Meter #
56
18. DGM -Correction]/
Factor 61
20. Vol. Org.
Condensate ml
21. Coll. time, minutes
22. Specific Gravity I 1
of Organic 75
Condensate
23. Comment
7. Cart ID# 0 8- N.B.# 9. Page #
78
81
-------
RADIAN
Card 1
SAMPLE DATA SHEET
1. Radian Valve/Pump ID# U7l 21 *!$ \U\ / 1 2)^ 2. Unit/Process
3
3. Plant Name
Mo. Day Yr.
4. Date
6. Time
B53
(Military Time)
5. Sampler's Initials
1 7
7. Cart ID# [7] 8. N.B.# 9. Page #
ztr
10
. Meter //I M
-------
RADIAN
Card 1
SAMPLE DATA SHEET
1. Radian Valve/Pump ID# \0\Z-\V\ft\O\
3
3. Plant Name
2. Unit/Process
Mo. Dav Yr.
4. Date
6. Time
11
5. Sampler's Initials
1 7
(Milita2ry Time)
10. Meter #.
11. Time #1
14. Temp. #1 °F
ZT5
, I <3O\
7. Cart ID//
12. Meter #2
13. Time #2
15. Temp #2 °F
8. N.B.#
9. Page #
16. Bar. Press., in. He. I"3|Q| . I / I JT 17. AP, in. Hg.
JZjLJL^l2lS] 19- Meter #
56
18. DGM Correction,
Factor
20. Vol. Org.
Condensate ml
6 1
66
21. Coll. time, minutes
22. Specific Gravity
of Organic
Condensate
75
23. Comment
78
83
-------
Card 1
SAMPLE DATA SHEET
1. Radian Valve/Pump ID# \&\2rf\A\&\ /\ttf \ 2. Unit/Process
3. Plant Name
Mo. Day Yr.
4. Date
6. Time
(Military Time)
5. Sampler's Initials
1 7
7. Cart ID# FT] 8. N.B.# 9. 'Page #
10. Meter #1
12. Meter /r'2
11. Time #1
3 7
13. Time #2
14. Temp #1 °F
16. Bar. Press., in. He. P PI- I/ iff
15. Temp #2 "F
"*8
5 1
17. AP, in. Hg.
LZl
56
18. DGM Correction!/ I ~ \O\(?\ 8\ 19. Meter #
Factor
20. Vol. Org.
Condensate ml
I I
66
21. Coll. time, minutes I I I
22. Specific Gravity
of Organic 7S
Condensate
23. Comment
78
84
332-
-------
REPUBLIC STEEL
GADSDEN PLANT
B-4 Analysis Data
85
-------
TABLE B-4.1 COMPONENT CODES FOR ANALYSIS DATA SHEETS
Code Component
001 Methane
012 Benzene
888 OVA reading for sample bag
997 Hexane
998 Non-methane HC
999,777 OVA reading for ambient air bag
86
-------
1. Radian Valve/Pump ID# 0
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
6*
0| O|O |Z
2. Unit/Process
3. Plant Name Y^JT) llVlliV- S-Wj
Mo. Day Yr.
4. Date
\|3L
11
6. Time (Military) \ 161010
20
5. Analyst's Initials Q|
7. N.B. #
17
8. Page
9. Instrument HP 5150
Z
24
AMBIENT AIR
Component Code
ppmj
BAG SAMPLE
Component Code
ppmw/3-
Card 2 2 i A Duplicate columns 3 through 10 from Card 1
Remarks:
87
-------
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
1. Radian Valve/Pump ID#
o
oo
2. Unit/Process
3. Plant Name
4. Date
Mo. Day Yr.
3L
|0
11
6. Time (Military)
9. Instrument HP
Slo
5. Analyst's Initials
7. N.B. #
17
8. Page
20
24
AMBIENT AIR
Component Code
ppmw
BAG SAMPLE
Component Code
Card 2 2 I A Duplicate columns 3 through 10 from Card 1
ppmw
37
55
73
ppmw
23
1 1
1 1
41
59
Remarks:
88
-------
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
1. Radian Valve/Pump ID#
3. Plant Name
H< C] \0 \C\
2. Unit/Process
4. Date
Mo. Day Yr.
11
6. Time (Military) _\
9. Instrument
17
8. Page
5. Analyst's Initials CL|Q | (p
7. N.B. #
24
AMBIENT AIR
Component Code
ppmr
BAG SAMPLE
Component Code
1.
t
'l^flX
25
2.
43
3.
61
Card 2
Component
4.
2|A
Dv
1
Code
11
5.
29
6.
1
47
117
<
rani.
tj
28
46
|
1
64
iplicate columns 3
ppmw
r~
1
14
|
32
1
>5^ -
through 10 i
Com]
1
C{ ft fg
34
S*>^
'
52
.xTv
i
cy
70
from Card 1
jonent Code
1
20
^1^1^
38
56
==s-
37
I/
55
73
23
41
™»—
by
£
^
\-S
1
I
5
) ll
• 1 i
|
ppmw
1
|
A
P
ft
j
•H-
^
6
h=>-
OP
L/*\l /\-
U 1 '-*i
•
Remarks:
89
-------
1. Radian Valve/Pump ID#
3. Plant Name
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
£ X
o\"2. \*-\-tc\ o| o |o \1
2. Unit/Process
4. Date
Mo. Day Yr.
i T.
11
5. Analyst's Initials C|J | &•
17
6. Time (Military)
9. Instrument
\\$
o N.B.
8. Page
20
3olC TH
24
AMBIENT AIR
Component Code
ppmw
BAG SAMPLE
Component Code
1.
2.
3.
Card
Compc
4.
5.
6.
ih
l»
25
I
43
|
61
2
ment
2 | A
Dt
1
Code
1
11
1
29
i|n
~7
B|-J| .
4
28
1 I
46
1 I
64
iplicate columns 3
ppmw
1 1
14
I 1
32
|
1 !
through 10 i
Com]
°l
^
•a
34
52
1
70
from Card 1
jonent Code
20
38
6
e
8
1 J 5|5 1. 1
37
1 I 1
55
1 1 1
73
ppmw
1 1 1
23
1 1 1
41
1 1 1-7 le lo
47
Remarks:
50
56
59
90
-------
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
1. Radian Valve/Pump ID#
| 6 \Q |Q |^ J 2. Unit/Process
3. Plant Name "VJSLpU In I iV^ S-UjLJ
Mo. Day Yr.
4. Date
V
XiO
11
6. Time (Military) 1 | (p| \ |Q
5. Analyst's Initials Cj3l£
7. N.B. *
9. Instrument
M
20
24
AMBIENT AIR
Component Code
ppmw
BAG SAMPLE
Component Code
PPmw
Remarks:
91
-------
ANALYSIS DATA SHEET
(AMBIENT AND SAG)
1. Radian Valve/Pump ID#
3. Plant Name
02.
oo P
2. Unit/Process
4. Date
Mo. Day Yr.
11
1 -3.
6. Time (Military) 1 | to \ I |o
17
8. Page
5. Analyst's Initials C| J[6-
7. N.B. #
9. Instrument
20
3
-------
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
1. Radian Valve/Pump ID* Q|j2l'g-U.I OlAiriT?
2. Unit/Process
Cob
3. Plant Name \<£r?VK.V3\ \ C
4. Date
Mo. Day Yr.
2_10&iQ
11
5. Analyst's Initials CiTTl G
6. Time (Military)
7. N.B.
20
17
8. Page
9. Instrument
VlP ^T\ ^0 O
24
AMBIENT AIR
Component Code
ppmv
BAG SAMPLE
Component Code
ppmw
U.i9i?i5l '&
50
59
Remarks:
93
-------
1. Radian Valve/Pump ID#
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
| V-4-A-
2. Unit/Process
» !<•*•
3. Plant Name
4. Date
Mo. Day Y'r.
i
8
11
6. Time (Military)
9. Instrument HP
20
24
5. Analyst's Initials C I 3* I
7. N.B.
AMBIENT AIR
Component Code
ppmw
28
46
BAG SAMPLE
Component Code
64
Card 2 2 | A Duplicate columns 3 through 10 from Card 1
1
ppmw
14
32
50--
ppmw
t\t I
37
55
73
ppmw
23
41
59
Remarks:
94
-------
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
? UL
1. Radian Valve/Pump IDf |0 \0*\ VfArf^lO Qj I | 2:.' Unit/Process Qj toL-. "P \
3. Plant Name
A
Mo. Day Yr.
4. Date \ I £. \ \ 6 ?)|0
11
6. Time (Military) | ]_iolO[O
20
rrj
9. Instrument Dv^fiTX OU\ C_ *
0
5. Analyst's Initials C | ^f 1 6
17
7- N.B. # 8. Page #
"rtC i
TT
AMBIENT AIR
Component Code
ppmw
BAG SAMPLE
Component Code
1.
O
l6]!^
25 '
2.
1
43
3.
1
61
Card 2
Component
4.
5.
6.
i/fn
28
46
. |0|5
1 1 ft
o\
i^iS
34
1 1
1 1
52
1
64
2 ! A j Duplicate columns 3
1
Code
1
11
|
29
Hll
1
ppmw
14
32
1
1 1
70
through 10 from Card 1
Component Code
1 1
20
1
1 1
' — JO
\
°\
\C)\0
Ci
1^/1^1^155 10
37
I 1 1 1 1
55
Mill
73
ppnw
1 1 1 1 1
23
Mil!
41
CQ
47
Remarks:
95
-------
1. Radian Valve/Pump ID#
3. Plant Name
Mo. Dav Yr.
4. Date
11
i & no
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
P U.S
"H«gH£r |Q
2. Unit/Process
S-\--ee, \
6. Time (Military)
9. Instrument
5. Analyst's Initials
7. N.B. #
AMBIENT AIR
Component Code
ppmw
IkHi ,
|5|3
28
46
BAG SAMPLE
Component Code
64
Card 2 [_2 | A j Duplicate columns 3 through 10 from Card 1
1
ppmw
14
6.
32
50
59
Remarks:
96
-------
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
1
1. Radian Valve/Pump ID#
3. Plant Name
4. Date
3
V C_
2. Unit/Process
(V,W P\
Mo. Day Y'r.
Vi\
11
6. Time (Military)
9. Instrument
5. Analyst's Initials Cl3"lG
7. N.B. #
AMBIENT AIR
Component Code
ppraw
BAG SAMPLE
Component Code
47
Remarks:
Q\/-f\~
— nx \A.
0
97
-------
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
? u. S
1. Radian Valve/Pump ID#
3. Plant Name
2. Unit/Process
GJ kx_
4. Date
Mo. Day Yr.
11
6. Time (Military) j
H£
9. Instrument
5. Analyst's Initials
7. N.B. t
24
AMBIENT AIR
Component Code
1.
2.
3.
ppmw
BAG SAMPLE
Component Code
273.1
28
46
64
Card 2 [_2 j A j Duplicate columns 3 through 10 from Card 1
1
ppmw
14
32
6.
50
I
37
55
73
ppmw
23
41
59
135M
t3^53
Remarks:
rxvt/
-------
=#-2.
1. Radian Valve/Pump ID# 0
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
P UL S
) I ) l°f I 2. Unit/Process
3. Plant Name
3**
UL i
4. Date
Mo . Day Yr .
ia
11
6. Time (Military) 1 I'SU 1 I"7?
5. Analyst's Initials
7. N.B. #
9. Instrument
!) U mYA ?)0\ C
•
24
AMBIENT AIR
Component Code
ppmr
1.
2.
3.
'Mi*
2L5
1 !
43
1 1
i i m^n*
28
1 1 1 1 1
46
1 1 1 1 1
BAG SAMPLE
Component Code
ppmw
61
64
Card 2 I 2 I AJ Duplicate columns 3 through 10 from Card 1
1
Component Code
4.
5.
6.
Remarks:
ppmw
14
32
50
37
55
73
ppmw
23
41
59
99
-------
1. Radian Valve/Pump
3. Plant Name
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
? u. 5
l 19
2. Unit/Process
SWJ
Mo. Day 'Yr.
4. Date I I <-A I
11
6. Time (Military
ElD
9. InstrumenfTTftL-
1^ ^0 5. Analyst's Initials C_\ \
) i \-3\ \\C
17
SG
7- N.B. # 8. Page #
20
5130 &c ra
24
AMBIENT AIR
Component Code
1.
2.
3.
BAG SAMPLE
Component Code
46
64
Card 2 j 2 : A Duplicate columns 3 through 10 from Card 1
14
32
50
ppmw
37
55
73
ppmw
23
41
59
6 6
Remarks:
100
-------
ANALYSIS DATA SHEET
1. Radian Va
3. Plant Nam
M
4. Date \
11
(AMBIENT AND BAG)
1| A
1 ? u. 5
Ive/Pump ID* 0 Q.| V-fsUJ-Q-l 1 |^|0 2. Unit/ProcessC ^ kjzJll CU"\T
3
elv2_Du_b ^c_ IbAccJ
\
o. Day Yr.
1^- III ^5|(3 5. Analyst's Initials Cl 3l
-------
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
UL S
1. Radian Valve/Pump ID//
Ql^4v*U+& 1 PJ^I 2. Unit/Process C,7, VOL "P \ CU
3. Plant Name
T^IDU.\0 \ \
C
Mo. Day Tr.
4. Date
'\ ^ \ | I
11
6. Time (Military) \
9. Instrument
HV 5150GC
24
5. Analyst's Initials
7- N.B.
AMBIENT AIR
Component Code
1.
ppmw
, \°i\3
">£
28
46
BAG SAMPLE
Component Code
64
Card 2 |_2 | A Duplicate columns 3 through 10 from Card 1
1
ppmv
14
6.
32
50
37
55
73
23
41
59
ppmw
7
Remarks:
102
-------
1 I A
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
1. Radian Valve/Pump ID* O \^\ V | A
2. Unit/Process
Cok. PI
3. Plant Name
'VxQjQU-bUc
Mo. Day Yr.
4. Date
ha
.\
iorsio
11
6. Time (Military) ( |S| j
9. Instrument
5. Analyst's Initials
7. N.B. #
AMBIENT AIR
Component Code
pprow
BAG SAMPLE
Component Code
1.
(A
i°
fa
25
2.
\ \
43
3.
\ \
61
Card 2
Component
4.
5.
6.
2 i A
1
Code
\ \
11
i 1
29
inn
Di
1 1 i ~~)l c^ f^
I | 1 of-\ ^> \ O
28
1 1 1
46
1 1 1 1
64
iplicate columns 3
ppmw
1 1 1
14
1 1 1
32
1 1 \lr2lOlG
Z5o,o
through 10 i
Comi
^ | 4 1 ^
34
1 1 J
52
1 1
70
:rom_ Card 1
?onent Code
- 1 1
20
1 1
38
^iVl^
iOi ^ikm o
37
1 1 1 1
55
1 1 1 1
73'
ppmw
1 1 1 1
23
1 1 1 1
41
\ lOlOlOiO 1
47
Remarks:
50
56
59
103
-------
1. Radian Valve/Pump ID#
3. Plant
. Date
C
. D
Mo. Day Yr.
( |0
11
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
6. Time (Military)
9. Instrumen
trJT
z_
24
2. Unit/Process
( ^ K 0 T \ "> f\ T~
^—^ [v*~ I I '"MX \
5. Analyst's Initials
7. N.B. #
AMBIENT AIR
Component Code
ppmw
28
46
BAG SAMPLE
Component Code
64
Card 2 2 j A | Duplicate columns 3 through 10 from Card 1
1
ppmw
14
6.
32
50
Remarks:
104
-------
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
1. Radian Valve/Pump IDf |(TQ|v U lAl API I 31 2. Unit/Process Co k?
3. Plant Name
> 1 V? 1 V C
4. Date
Mo. Day Yr.
5. Analyst's Initials C_| ^3]
17
6. Time (Military) (
20
7. N.B. #
8. Page
9. Instrument
U
jacn
24
AMBIENT AIR
Component Code
ppmv
BAG SAMPLE
Component Code
Card 2 2 A Duplicate columns 3 through 10 from Card 1
5.
6.
L2I4I3I
ppmw
47
Remarks:
105
-------
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
1. Radian Valve/Pump ID#
3. Plant Name
I A | QQf7|3> 2. Unit/Process,
4. Date
Mo. Day Yr.
11
210
6. Time (Military) _]
9. Instrument
20
5. Analyst's Initials
7. N.B. #
17
8. Page
AC
24
AMBIENT AIR
Component Code
ppmv
BAG SAMPLE
Component Code
Duplicate columns 3 through 10 from Card 1
37
55
73
ppmw
23
41
50
56
59
Remarks:
106
-------
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
1
1. Radian Valve/Pump ID#
3. Plant Name
V
I A |C) It E2JTI 2. Unit/ProcessCo k_£_ T I O-'vOt
KJlfiUlhU
3
C
Mo. Day Yr.
4. Date
10- III
11
5. Analyst's Initials C| 'S
6. Time (Military) \
7. N.B.
20
9 . Ins trument U.<7m
1.
iyc
0
•JT
AMBIENT AIR
Component Code
pprnw
BAG SAMPLE
Component Code
Duplicate columns 3 through 10 from Card 1
1 1 15-1 f
?IO
37
55
73
ppmw
23
41
59
QlQ
Remarks:
107
-------
1. Radian Valve/Pump ID#
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
|Q| ll^l 1 I 2. Unit/Process Q I
-------
1. Radian Valve/Pump ID#
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
2. Unit/Process
3. Plant Name
r.
Mo . Day Yr .
4. Date \l,3 \ 1
11
6. Time (Military)
9. Instrument Jy\\f
0
V 5s! 0
1 IUI
310
5. Analyst's Initials CL|C
17
[^
7. N.B. # 8. Page #
™ 30 1 (L TWCTil
24
AMBIENT AIR
Component Code
ppmw
BAG SAMPLE
Component Code
37
55
73
23
41
ppmw
I 171
OlOlO
59
Remarks:
109
-------
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
1. Radian Valve/Pump ID#
3. Plant Name 4\(LpL)lipU
v lA |Q|
2. Unit/Process
3
(L-
4. Date
Mo. Day Tr.
11
6. Time (Military)
9. Instrument
\~\ 9
5. Analyst's Initials
7. N.B.
AMBIENT AIR
Component Code
ppmw
BAG SAMPLE
Component Code
ppmw
1.
2.
3.
Card
Compc
4.
5.
6.
All I^L
25
1 1
43
1 1
61
2
snent
2 |A
1
Code
1 1
11
1 1
29
1 1
Dt
i i^i^n
28
i i i
46
i i i
64
iplicate columns 3
ppmw
_J
i i i
14
32
i i i
! 1 1 I !
through 10 i
Coraf
o\ ta
34
1 1
52
| |
70
:rom Card 1
jonent Code
1 1
20
1 1
38
1 1
I KolSiO (a
37
L L L 1
55
1 1 1
73
ppmw
1 1 1
23
1 1 I 1
41
1 II"
47
50
56
59
Remarks:
110
-------
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
1
1. Radian Valve/Pump ID#
\Q\
2. Unit/Process
G
3. Plant Name*
Mo. Dav Yr.
4. Date
\
\\
11
6. Time (Military) [ | O\ \
20
V
9. Instrumentpu (71
5. Analyst's Initials
7. N.B. #
TMT (T)
24
AMBIENT AIR
Component Code
ppmu
BAG SAMPLE
Component Code
Duplicate columns 3 through 10 from Card 1
KL5'IO
. |5
37
55
73
ppmw
23
41
50
56
59
Remarks:
111
-------
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
1. Radian Valve/Pump ID#
I o^l 3 2. Unit/Process,
3. Plant Name
r\?jT7U\Q\i,
Mo
. D
4. Date
11
ay Y'r.
50
6. Time (Military)
9. Instrument
UP
5. Analyst's Initials
7. N.B. #
24
AMBIENT AIR
Component Code
ppmw
BAG SAMPLE
Component Code
ppmw
. it
23
2.0=1. "2.
I3J,
37
46
55
6.
64
Duplicate columns 3 through 10 from Card 1
ppmw Component Code
i i i i T~
14
I I I I ~
32
i i i i T"
50
73
ppmw
23
41
59
Remarks:
112
-------
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
1. Radian Valve/Pump ID* \C\ \ &H V I A \G I I Q>4
2. Unit/Process
3. Plant Name |y 0 QU bl iV S4&0
Mo. Day Yr;
4. Date
ll^-lll %£>
11
6. Time (Military) | |^-|<5|6
5. Analyst's Initials Osbl^
17
7. N.B. # 8. Page #
20
9. InstrumentT)^ COYl oOl A- iW~\ I |
6 24
AMBIENT AIR
Component Code
BAG SAMPLE
Component Code
1.
2.
3.
Card
Compc
4.
5.
6.
^ih i^
25
1 1
43
1 1
61
2
ment
2 j A
1
Code
1 1
11
1 1
29
If
Ml
Di
|
28
1 \|\
1 1 1 1
1
46
1 1 1 1
64
iplicate columns 3
ppmv
1
1 1 1
14
1 1 1 1
32
|
1 I^IOIO
V\4
through 10 i
Comj
°[tf 1?
34 '
1 1
52
1 1
70
from Card 1
jonent Code
1 1
20
1 1
38
^fSi?
ii m i lOio
37
1 1 1 1
55
1 1
73
ppmw
1 1
23
1 1 1
41
i4l5lOiOiO
47
59
Remarks:
/\
113
-------
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
1
1. Radian Valve/Pump ID#
3. Plant Name
2. Unit/Process
\
Mo . Day Yr .
4. Date \ I
-------
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
1. Radian Valve/Pump ID//
2. Unit/Process63
•^
3. Plant Name ^NJLpU,b U C, S \££ (
4. Date
Mo. Day Yr.
III
11
5. Analyst's Initials
20
6. Time (Military) \ \ Lp\Q\0
a
7- N.B.
17
8. Page #_
9. Instrument
C3
24
AMBIENT AIR
Component Code
pprow
BAG SAMPLE
Component Code
37
55
73
ppnw
23
41
50
56
59
Remarks:
115
-------
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
1. Radian Valve/Pump ID# Q|^| V | A \Q\ I Pel 31 2. Unit/Process
3. Plant Name
Mo. Day Yr.
4. Date
11
6. Time (Military)
9.
5. Analyst's Initials
7. N.B. #
17
8. Page
AMBIENT AIR
Component Code
ppmw
BAG SAMPLE
Component Code
Duplicate columns 3 through 10 from Card 1
37
55
73
56
23
41
59
ppmw
4-14,1
Remarks:
116
-------
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
1. Radian Valve/Pump ID#
3. Plant Name1v(LOU t
v I A |Q| /
2. Unit/Proces
Ca\
-------
ANALYSIS DATA SHEET
(AMBIENT ANT) BAG)
1. Radian Valve/Pump ID#
3. Plant
4. Date
^|^IV|A|Q|) .\Z\°\
/\
2. Unit/Process
Mo . Day Yr .
11
6. Time (Military) \ [[
5. Analyst's Initials
7- N.B. #
9. Ins trumentJA£_5750
24
AMBIENT AIR
Component Code
BAG SAMPLE
Component Code
Card 2 2 | A Duplicate columns 3 through 10 from Card 1
37
55
73
23
41
50
56
59
n
1
1 1 1
Remarks:
118
-------
,
/
CO
a // j f j / / • «.
A
74,5
.2 , -7
V*T
-------
7.
/-LL\
(
' 3
o
3
U>
23
. x
f -..
//v r. s^^^y -^> ^^e — a 7z
//f ( /.2^J? /AJ ^-7^* } ^> T^
-------
REPUBLIC STEEL
GADSDEN PLANT
B-5 OVA and TLV Calibration Data
121
-------
l/MIT
CALIBRATION CHECKING FORM
NJ
1
.u
a
0
/|3
, ,.a
ip.
'I2-
1 |i
1 |3k
l|2
) |2
1
|
1
id
^t
QL %
C' | C'
? | 0
t |O
1 I1
'l'
I |Z
1 p
1
1
1
Instrument
k
%
'a,
^
>
A
'3
4
>
Screening
Team
f)
C,
0
,
"X
\
0|1
o
o
0
o
I
/
I
1
Low standard
ppm calibration
nv
1 1
1 1
1 1
1 1 1
1 1
1 1
1 1 1 1 1
1 1 1 1 1
1 1
1 1
1 1
1 1
1 1
1 1
5\v |0
1 1
1 1
1 1
1 1
1 1
High standard
ppm calibration
1 1-iU-U-^
1 1 Ik 15 |o
i ni5ioio
1 1 l|8|0|0
\\\o\p
oil
\ \^\°\o\p
\\-\u\o
\ 1 2 | o
III.
1 1 1
1 1 1
0| 1
ojo
I
|
1
Dilution Probe
Calibration
?n
1 1 1 1 1
1 1 -I" M^'lO
1 1 1 1 1 1 &|o
1 1 1 1 1
i i nioio
i i i i i
i i i i i
i i i i i
i i i i i
i -i i i i
i i i i i
2.
Z
7
7.
Comment B :
-------
REPUBLIC STEEL
GADSDEN PLANT
B-6 Dry Gas Meter Calibration Data
123
-------
RADIAN
Card 1
SAMPLE DATA SHEET
1. Radian Valve/Pump ID# \ \ 1 1 I I I i 2. Unit/Process
3. Plant Name
Mo. Day Yr.
4. Date
6. Time
20
(Military Time)
10. Meter #1 l7fST7l- l^-l Q
^5
5. Sampler's Initials
1 7
7. Cart ID#
8. N.B.#
12. Meter #2 I 7\ «£|5l 1^1 / I
31
9. Page #
11. Time #1
37
13. Time #2
14. Temp #1 °F
"15
15. Temp #2 °F I \C\3\
16. Bar. Press., in. Hg.
5 1
17. AP, in. Hg.
56
-I2-
18. DGM Correction,
Factor
20. Vol. Org.
Condensate ml 6S
19. Meter #
'/
21. Coll. time, minutes
22. Specific Gravity
of Organic
Condensate
75
23. Comment
78
124
-------
Card 1
s]
SAMPLE DATA SHEET
1. Radian Valve/Pump ID# I I I I I I I I 2. Unit/Process
3
3. Plant Name
Mo. Day Yr.
4. Date
6 . Time
I \Z\t\LW0\
5. Sampler's Initials
1 7
(Military Time)
10. Meter #1
25
11. Time #1 I I
37
14. Temp #1 °F
7. Cart ID#
12. Meter #2
13. Time #2
15. Temp #2 °F
8. N.B.#
9. Page #
51
16. Bar. Press., in. He. \3O\' \2\(\ 17. AP, in. Hg.
19. Meter #
1 I£L
|Z
56
18. DGM Correction,
i,u9iSi£
Factor
20. Vol. Org.
Condensate ml
61
66
21. Coll. time, minutes
22. Specific Gravity
of Organic
Condensate
75
23. Comment
78
125
-------
REPUBLIC STEEL
GADSDEN PLANT
B-7 Accuracy Check Data
126
-------
RADIAN
Card 1
SAMPLE DATA SHEET
1.
1 O Z A C o a a \
Radian Valve/Pump ID# \A\C\f l£ 101? iff & JC2.
Unit/Process
3. Plant Name
Mo. Day Yr.
4. Date
6. Time
11
5. Sampler's Initials I ffiL*^
20
(Military Time)
7- Cart ID# \T\ 8. N.B.# 9. Page #
2V
10. Meter #1
11. Time #1
25
12. Meter #2 \S\Q\Z\. \7 \f\
37
'f
14. Temp #1 °F
16. Bar. Press., in. Hg.
• I l\8
5 I
/\ •
6 1
18. DGM Correction.
Factor
20. Vol. Org.
Condensate ml
21. Coll. time, minutes
13. Time #2
15. Temp #2 °F I
i
17. AP, in. Hg.
19. Meter #
28.5s
I/I
56
22. Specific Gravity
of Organic
Condensate
75
23. Comment
78
/I
4.
"
127
-------
Card 1
SAMPLE DATA SHEET
1 C "2- A C o o o Z
1. Radian Valve/Pump ID#
j/ 2. Unit/Process
3. Plant Name
Mo. Day Yr.
4. Date
6 . Time
11
5. Sampler's Initials jx* l^J
1 7
20
(Military Time)
7. Cart ID# \T 8. N.B.# 9. Page #
Tnrf '^^^'^^
10. Meter #1
11. Time #1
14. Temp #1 °F
25
12. Meter #2
13. Time #2
15. Temp #2
1+8
16. Bar. Press., in. Hg.
18. DGM Correction.
Factor
20. Vol. Org.
Condensate ml 6 6
. 21. Coll. time, minutes'
23. Comment
17- AP, in. Hg.
19. Meter #
56
I I I I 22. Specific Gravity L I I
of Organic
Condensate
75
78
,
1,05
1,05
128
f/
-------
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
A o o o c
1. Radian Valve/Pump ID#
3. Plant Name
4. Date
6. Time (Military)
r ,\s ~P\ 'i
2. Unit/Process ^ O &c
17
8. Page #
AMBIENT AIR
Component Code
ppmv
BAG SAMPLE
Component Code
ppmw
37
55
73
23
41
59
ppmj
Remarks:
129
- 3. $17
//< 7Z %
-------
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
O -2. A e, oo 02.
X-S .•—•l A I
1. Radian Valve/Pump ID#
3. Plant Na
4. Date
6. Time (Military)
9. Instrument
2. Unit/Process C_jb K 1 T I^
5. Analyst's Initials Qo I 6?!
AMBIENT AIR
Component Code
ppmv
BAG SAMPLE
Component Code
2 | A | Duplicate columns 3 through 10 from Card 1
130
56
37
73
23
41
59
ppmw
- *5
ppmw
Remarks:
-------
ANALYSIS DATA SHEET
(AMBIENT ASP BAG)
1
1. Radian Valve/Pump ID#
fiU KID
4. Date ._ .
. 2. /O
6. Time (Military)
9. Instrument
2. Unit/Process
T lOLK\JC~
5. Analyst's Initials Q3~| O
17
7. N.B.
8. Page #_
AMBIENT AIR
Component Code
BAG SAMPLE
Component Code
1. l^^p^^"
1 1
1
25 28
2. I
| |
1
43 46
3. 1
61
1 1
!
64
Card 2 1 2 j A Duplicate columns 3
1
Component Code
4. |
ppmv
1 1
1
11 14
5. 1
29 32
6. |
1 1
1 1
i
I
47 50
through 10 i
Corai
131
6ll 12.
34
| |
52
I i
70
:rom Card 1
jonent Code
1 1
20
1 1
38
1 1
56
/\O\4*\2-\ - \3?
37
1
1 I
55
|.
73
|
LJ
1
pptnw
|
23
1 1
41
1
|
|
59
Remarks: &<£_. jyy* — *.•> r- a /v,^^
X
-------
#•2,
1. Radian Valve/Pump ID#
3. Plant
ANALYSIS DATA SHEET
(AMBIENT AND BAG)
BLlHD S
V | A
2. Unit/Process
Mo. Day
4. Date
\\~2~
11
oi
------- |