United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park NC 27711
EMB Report 80-MET-9
May 1980
Air
Metallic  Minerals

Emission Test Report
Reynolds Metals
Company
Corpus Christi, Texas

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               SOURCE EMISSIONS TEST  REPORT
                 Reynolds Metals Company
                      Sherwin Plant
                  Corpus Christ!, Texas
                     Sources Tested:

          •    Ship Unloading Process

          •    Fine Ore Storage Area


August 1980



                                            a.  "R
                                 David A. Ralston
                                 Assistant Project Scientist
                                 Barry I^  JacksTo
                                 ProjectMan
                                 Air Testing
                RFW Report No. 0300-81-16
                 Contract No. 68-02-2816
                 Work  Assignment  No.  14
                       Prepared by

                   Roy F. Weston, Inc.
                 Designers - Consultants
                       Weston  Way
               West  Chester, Pennsylvania
                     (215)    692-3030

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                        TABLE OF CONTENTS


Section                                                   Page

           SUMMARY                                        1

           INTRODUCTION                                   3

           PROCESS DESCRIPTION                            5

           DESCRIPTION OF TEST LOCATIONS                  8

               Ship Unloading Scrubber Inlet Duct         8
               Ship Unloading Scrubber Discharge Duct     8
               No. 1 and No.  2 Fine Ore Storage Bins
               Exhaust Stack                               8
               No. 2 Fine Ore Storage Bin Baghouse
               Exhaust Duct                               8

           DESCRIPTION OF SAMPLING TRAINS                 13

               Particulate Sampling Trains                13
               Particle Size  Distribution Sampling
               Apparatus                                  13

           TEST PROCEDURES                                16

               Preliminary Tests                          16
               Formal Tests                               16
                   Ship Unloading Scrubber Inlet Duct     16
                   Ship Unloading Scrubber Discharge
                   Duct                                   17
                   No. 2 Fine Ore Storage Bin Baghouse
                   Exhaust Duct                           17
                   No. 1 and  No. 2 Fine Ore Storage Bins
                   Exhaust Stack                          18
                   Ship Unloading Platform                18
                   Ship Unloading Conveyor Belt           18
                   Tailings Pond No. 2 Bed                18

           ANALYTICAL PROCEDURES                          19

               Particulate Sample Recovery                19
               Particulate Analyses                       19
               Particle Size  Sample Recovery and
               Analyses                                   20

           TEST RESULTS AND DISCUSSION                    21

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                        TABLE OF CONTENTS
                           (continued)
Section                                                   Page
APPENDIX A - RAW TEST DATA                                A-l

APPENDIX B - LABORATORY REPORTS                           B-l

APPENDIX C - SAMPLE CALCULATIONS                          C-l

APPENDIX D - EQUIPMENT CALIBRATION RECORDS                D-l

APPENDIX E - PROJECT PARTICIPANTS                         E-l
                               111

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                         LIST OF TABLES
Table No.                     Title                        Page

     1       Ship Unloading Area Scrubber
             Summary of Test Data                         22

     2       Ship Unloading Area Scrubber
             Summary of Particulate Test Results
             (English Units)                               23

     3       Ship Unloading Area Scrubber
             Summary of Particulate Test Results
             (Metric Units)                                24

     4       No.  2 Fine Ore Storage Bin Baghouse
             Exhaust Duct
             Summary of Test Data                         25

     5       No.  1 and No.  2 Fine Ore  Storage  Bins
             Exhaust Stack
             Summary of Test Data                         26

     6       No.  2 Fine Ore Storage Bin Baghouse
             Exhaust Duct
             Summary of Particulate Test Results
             (English Units)                               27

     7       No.  2 Fine Ore Storage Bin Baghouse
             Exhaust Duct
             Summary of Particulate Test Results
             (Metric Units)                                28

     8       No.  1 and No.  2 Fine Ore  Storage  Bins
             Exhaust Stack
             Summary of Particulate Test Results
             (English Units)                               29

     9       No.  1 and No.  2 Fine Ore  Storage  Bins
             Exhaust Stack
             Summary of Particulate Test Results
             (Metric Units)                                30

    10       Ship Unloading  Scrubber Outlet
             Particle Size  Distribution                   31
                               IV

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                         LIST OF TABLES
                           (continued)
Table No.                    Title                        Page

   11        No.  1 and No.  2 Fine Ore Storage Bins
             Exhaust Stack Run No. 1
             Particle Size Distribution                   33

   12 .       No.  1 and No.  2 Fine Ore Storage Bins
             Exhaust Stack Run No. 2
             Particle Size Distribution                   35

   13        Ship Unloading Outlet
             Summary of Visible Emissions                 37

   14        Fine Ore Bin
             Summary of Visible Emissions                 38

   15        Fine Ore Bin Exhaust Stack
             Summary of Visible Emissions                 39

   16        Ship Unloading Platform
             Summary of Visible Emissions                 41

   17        Ship Unloading Conveyor
             Summary of Visible Emissions                 42

   18        Tailing Pond No. 2 Bed
             Summary of Visible Emissions                 43

   19        Mean Fugitive Emission Values
             (% frequency of emission)                     44

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                         LIST OF FIGURES
Figure No.                   Title                        Page

    1        Ship Unloading Scrubber Inlet Duct
             Port and Sampling Point Locations             9

    2        Ship Unloading Scrubber Discharge Duct
             Port and Sampling Point Locations            10

    3        No.  1 and No.  2 Fine Ore Storage Bins
             Exhaust Stack
             Port and Sampling Point Locations            11

    4        No.  2 Fine Ore Storage Bin Baghouse
             Exhaust Duct
             Port and Sampling Point Locations            12

    5        Particulate Sampling Train - EPA Method 5    14

    6        Particle Size  Distribution Sampling
             Apparatus - Andersen 2000, Inc.               15

    7        Ship Unloading Scrubber Outlet
             Run  No. 1
             Particle Size  Distribution Results           32

    8        No.  1 and No.  2 Fine Ore Bins Exhaust
             Stack Run No.  1
             Particle Size  Distribution Results           34

    9        No.  1 and No.  2 Fine Ore Bins Exhaust
             Stack Run No.  2
             Particle Size  Distribution Results           36
                               VI

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                             SUMMARY
The Emission Measurement Branch of the U. S. Environmental Pro-
tection Agency, contracted Roy F. Weston, Inc. (Weston) to con-
duct a source testing and analysis program at Reynolds Metals
Company's Sherwin Plant in Corpus Christi, Texas.

The objectives of the program were to collect representative
samples and make supplementary measurements necessary to deter-
mine the quantity of particulate emissions released to the envi-
ronment from each process discharge stream.  Source emission
samples were procured by Weston test personnel during the period
23 to 26 June 1980, and analyzed gravimetrically at Weston1s
West Chester, Pennsylvania laboratories.

The test points sampled during the survey and the numbers and
types of tests conducted at each source are listed below.

                               Number of Test Repetitions by Type
Source Description

Ship Unloading Scrubber
Inlet Duct

Ship Unloading Scrubber
Discharge Duct

No. 2 Fine Ore Storage Bin
Baghouse Exhaust Duct

No. 1 and No. 2 Fine Ore
Storage Bins Exhaust Stack

Ship Unloading
Conveyor Belt

Ship Unloading Platform

Tailings Pond No. 2 Bed
Particu-
late1
Parti-
cle

Size2
   3


   3
Visi-
ble
Emis-

sions"
           1


           3


           3


           1


           1

           1
Fugi-
tive
Emis-
     t
sions
                              1

                              1
 "Standards of Performance for New Stationary Sources," Code of
 Federal Regulations, Title 40, Part 60,  Appendix A,  18 August 1977.
2
 Operating Manual for Andersen 2000, Inc., "Mark III  Particle Sizing
 Stack Samplers," Andersen 2000, Inc.,  P.O.  Box 20769, Atlanta, GA.

3Federal Register, Vol. 39, No. 219, 12 November 1974.

4Draft Method, Revised 28 July 1978.
                                  -1-

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The particulate matter concentration and mass rate results are
summarized below for each test point:
                  Ship Unloading Scrubber Inlet Duct
Test              Particulate Concentration
Number     Date   	grains/DSCF	

  1       6-24-80           1.14
Particulate Mass Rate
	pounds/hour	

         806.
                Ship Unloading Scrubber Discharge Duct
Test              Particulate Concentration
Number     Date   	grains/DSCF	

  1       6-24-80           0.017
Particulate Mass Rate
	pounds/hour	

          12.6
         No. 1 and No. 2 Fine Ore Storage Bins Exhaust Stack
Test
Number
1
2
3
Avg.
Particulate Concentration
Date grains/DSCF
6-25-80
6-25-80
6-25-80

0.003
0.003
0.004
0.003
Particulate Mass Rate
pounds/hour
0.388
0.392
0.482
0.421
           No.  2 Fine Ore Storage Bin Baghouse Exhaust Duct
Test              Particulate Concentration
Number     Date   	grains/DSCF	

  1       6-25-80           0.004

  2       6-25-80           0.002

  3       6-25-80           0.002

 Avg.                       0.003
Particulate Mass Rate
	pounds/hour	

          0.218

          0.135

          0.113

          0.155
                                 -2-

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                           INTRODUCTION


The Emission Measurement Branch of the U. S. Environmental Pro-
tection Agency/ contracted Roy F. Weston, Inc. to conduct a
source testing and analysis program at the Reynolds Metals
Company's Sherwin Plant in Corpus Christi, Texas.  The objec-
tives of the testing program were to measure the quantity of
particulate emissions released to the environment from each pro-
cess discharge stream and to determine collector performance.

The locations tested, plus the number and types of tests per-
formed at each site, are as follows:

    1.  Ship Unloading Scrubber Inlet Duct

        a. One particulate test by EPA Method 5.

    2.  Ship Unloading Scrubber Discharge Duct

        a. One particulate test by EPA Method 5.

        b. One particle size distribution test by
           cascade impaction (Andersen).

        c. One opacity test by EPA Method 9 simul-
           taneous with the particulate test.

    3.  No. 1 and No. 2 Fine Ore Storage Bins Exhaust Stack

        a. Three particulate tests by EPA Method 5.

        b. Two particle size distribution tests by
           cascade impaction (Andersen).

        c. Three opacity tests by EPA Method 9 simul-
           taneous with the three particulate tests.

    4.  No. 2 Fine Ore Storage Bin Baghouse Exhaust Duct

        a. Three particulate tests by EPA Method 5.

        b. Three opacity tests by EPA Method 9 simul-
           taneous with the three particulate tests.

        c. Three fugitive emission tests by EPA Method 22.

    5.  Ship Unloading Conveyor Belt

        a. One opacity test by EPA method 9.
        b. One fugitive emission test by EPA Method 22.


                               -3-

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    6.  Ship Unloading Platform

        a. One opacity test by EPA Method 9.
        b. One fugitive emission test by EPA Method 22.

    7.  Tailings Pond No. 2 Bed

        a. One opacity test by EPA Method 9.
        b. One fugitive emission test by EPA Method 22.

All testing was conducted during the period 23 to 26 June 1980
by Weston Air Measurement Services personnel.
                               -4-

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                       PROCESS DESCRIPTION
The Sherwin facility is located approximately 15 miles north of
Corpus Christi on the Gulf Coast of Texas.  This facility proc-
esses bauxite imported from Caribbean and South American coun-
tries.  Bauxite is transported to the facility in ships carrying
from 15,000 to 50,000 tons.

Bauxite is unloaded from the ships by one of two mechanisms.
Most ships are designated as "self-unloading."  As such, they
have a self-contained extendable boom conveyor that interfaces
with a dockside conveyor belt via an accordian chute.  Smaller
ships require the services of a dockside extendable boom convey-
or that is inserted into the side of the ship.  Only a self-
unloading ship was tested during the test sequence reported
here.

From the dock, bauxite is conveyed to a covered "live" ore stor-
age area.  Bauxite is then reclaimed from the storage area and
conveyed to one of four storage bins.  Each storage bin feeds a
rod mill, although not all rod mills are operated simultane-
ously.  Product from the rod mill is processed through a modi-
fied Bayer refining system.  All processes from the rod mill up
to, but not including, the final calcination of alumina are wet
processes and do not emit particulate matter.  After calcination
of alumina the product is transferred by railcar to the dock
area where the alumina is dumped from the bottom of railcar hop-
pers onto a tunnel conveyor.  From the railcar dump alumina can
be conveyed either directly to a ship-loading tower or to one of
three temporary storage bins.  From the ship-loading tower alu-
mina is dumped through an accordian chute into the hold of a
ship or barge for shipment to reduction plants in various parts
of the country.

SHIP UNLOADING

Emission Control

From the standpoint of particulate-emission control, the ship
unloading facility is simply a conveyor transfer point with a
fairly long free-fall zone (20 to 30 feet between conveyor belts
via an accordian chute).

Both the extendable boom conveyor from the ship and the dockside
conveyor are enclosed.  Emission control is primarily affected
by ducting air from the base of the accordian chute and from
                               -5-

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the impact zone on the dockside conveyor belt.  Approximately
20rOOO cubic feet per minute (cfm)  are ducted to a dry cyclone
and then to a venturi scrubber.  An additional 70,000 cfm are
ducted directly from the transfer point to the venturi scrubber.
Design pressure drop across the scrubber is 15 inches (water);
the system manometer was not functioning during the test.

Ship Unloading Test Points

The following points were tested at the ship unloading facility.
At the combined inlet duct for the venturi scrubber Method 5
(one test) measurements were taken.  At the outlet of the
venturi scrubber Method 5 (one test), Method 9 (one test), and
particle size distribution measurements were taken.  Visible
emission measurements were also made at points which were
indicative of the capture efficiency of the emission control
system.  Accordingly, Method 9 and draft Method 22 readings
were taken at the interface of the accordian chute and the top
of the dockside conveyor shed, and at an open doorway in the
dockside conveyor shed.  This doorway was located approximately
10 feet from the duct pickup points at the impact zone on the
dock conveyor belt.  Visible emissions measurements at this
point measured the amount of emissions which escaped through
the doorway into the open environment.

Test Conditions

During the test period ore was unloaded at a rate of 1,500 to
1,700 tons per hour (normal rate).   Actual measurements were not
possible due to a malfunction of the strip chart recording the
unloading rate.  Plant personnel verified that the unloading
operation proceeded normally.

ORE STORAGE BIN

Emission Control

Particulate emissions from ore bins No. 1 and No. 2 (preceding
the rod mills)  are ducted separately to individual baghouses.
Both baghouse outlets are combined in a common stack.   Typically
only one bin is filled at a time, although both baghouses run
continuously.  The baghouses are located directly over the fine
ore bins; therefore, no measurements could be taken of the inlet
loadings to these baghouses.  Each baghouse is designed for a
flow rate of 7,000 cfm and an air-to-cloth ratio of 8  to 1.
                               -6-

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Test Points

Method 5 readings were taken at the outlet of the baghouse on
the No. 2 ore bin.  Method 5f Method 9, and particle size dis-
tribution tests were taken at the combined outlet of the No. 1
and No. 2 baghouses.  In addition, Method 9 and Method 22
readings were taken in the area of the baghouses at the top of
the ore bins.

Test Conditions

Because ore bin No. 2 was filled with a type of ore that is less
dusty than the normal mill feed, it was decided to test during
the filling of ore bin No. 1 only.  Tests were conducted during
a continuous draw and fill of ore bin No. 1 in order to maximize
emissions during the test period.  Fill rate varied between 425
and 475 tons per hour, which is the normal range.
                               -7-

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                  DESCRIPTION OF TEST LOCATIONS
SHIP UNLOADING SCRUBBER INLET DUCT

Two 3-inch I.D. test ports, 90° apart, were placed on a
straight section of the 54-inch I.D. metal duct at a location
approximately 72 inches downstream and 14 inches upstream from
the nearest flow disturbances.  EPA Method 1 criteria for this
test location required a minimum of 48 traverse points (24 per
port).  See Figure 1 for port and sampling point locations.

SHIP UNLOADING SCRUBBER DISCHARGE DUCT

Two 3-inch I.D. test ports, 90° apart, were placed on a
straight section of the 72-inch I.D. metal duct at a location
approximately 132 inches downstream and 42 inches upstream from
the nearest flow disturbances.  Forty-eight sampling points (24
per port)  were required for testing.  See Figure 2 for port and
sampling point locations.

NO. 1 AND NO. 2 FINE ORE STORAGE BINS EXHAUST STACK

Two 3-inch I.D. test ports, 90° apart, were placed on a
straight section of the 29-1/2-inch I.D. metal stack at a loca-
tion approximately 30 feet downstream and 60 inches upstream
from the nearest flow disturbances.  Test site geometry required
a minimum of 12 traverse points (6 per port axis).  Figure 3
illustrates port and sampling point locations.

NO. 2 FINE ORE STORAGE BIN BAGHOUSE EXHAUST DUCT

Two 3-inch I.D. test ports, 90° apart, were located on a
straight section of the 18-inch. I.D. metal duct at a location
approximately 12 inches downstream and 48 inches upstream from
the nearest flow disturbances.  EPA Method 1 protocol required a
minimum of 32 traverse points (16 per port).  Figure 4 illus-
trates port and sampling point locations.
                               -8-

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Traverse
Point
Number
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
Distance From
Inside Near Wall
Inches
5/8
1 3/4
3
4 1/4
55/8
71/8
83/4
101/2
123/8
143/4
171/2
21 1/2
32 1/2
36 1/2
393/8
41 5/8
43 1/2
45 1/4
467/8
483/8
493/4
51
521/4
533/8
                                                  Flow
                             O
                                             CM
JT
X  *
   JL
                                    \
                          Scrubber
                                           Test Point Elevation
Duct Cross-Sectional Plan
   FIGURE 1  SHIP UNLOADING SCRUBBER INLET DUCT

             PORT AND SAMPLING POINT LOCATIONS
                        -9-

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                                            Scrubber1
Test Point Elevation
Traverse
Point
Location
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
Distance From
Inside Near Wall
Inches
3/4
2 1/4
4
53/4
7 1/2
91/2
11 5/8
14
161/2
195/8
231/4
285/8
433/8
483/4
523/8
551/2
58
603/8
62 1/2
641/2
66 1/4
68
693/4
71 1/4
 Duct Cross-Sectional Plan
  FIGURE 2  SHIP UNLOADING SCRUBBER DISCHARGE DUCT
           PORT AND SAMPLING POINT LOCATIONS
                           -10-

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              T
               5'

              -•  c
                   X
               30'
  o
   Y
  t
                      Row
                                Test Point Elevation
    29 1/2" I.D.
From No. 1

Fine Ore Bin

 Baghouse
                                   From No. 2

                                  Fine Ore Bin

                                   Baghouse
Traverse
Point
Location
1
2
3
4
5
6
Distance From-
Inside Near Wall
Inches ;:.
1 1/4
4 1/4
83/4
203/4
25 1/4
28 1/4
 Duct Cross-Sectional Plan
FIGURE 3  NO. 1 AND NO. 2 FINE ORE STORAGE BINS EXHAUST

          STACK - PORT AND SAMPLING POINT LOCATIONS
                           -11-

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                      Row
     Floor Level
                          12"
                                       Baghouse
      Test Point Elevation
  Duct Cross-Sectional Plan
Traverse
Point
Location
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
Distance From
Inside Near Wall
Inches .
1/2
7/8
1 1/2
21/4
3
4
5 1/8
63/4
11 1/4
127/8
14
15
153/4
161/2
17 1/8
171/2.
FIGURE 4  NO. 2 FINE ORE STORAGE BIN BAGHOUSE EXHAUST
          DUCT - PORT AND SAMPLING POINT LOCATIONS
                          -12-

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                '  DESCRIPTION  OF  SAMPLING  TRAINS
PARTICULATE SAMPLING TRAINS

The test train utilized for particulate sampling of all test
locations was the standard EPA Method 5 train (see Figure 5).

A stainless steel nozzle was attached to a heated (— 250°F)
borosilicate probe which was connected directly to a borosili-
cate filter holder containing a 9-cm Reeve Angel 900 AF glass
fiber filter.  The filter holder was maintained at approximately
250°F in a heated chamber, and was connected by vacuum tubing
to the first of four Greenburg-Smith impingers which were
included in the train to condense the moisture in the gas
stream.  Each of the first two impingers contained 100 ml of
distilled water, the third was dry, and the final impinger
contained 200 grams of dry preweighed silica gel.  The first,
third, and fourth impingers were modified Greenburg-Smith types;
the second was a standard Greenburg-Smith impinger.  All
impingers were maintained in a crushed ice bath.  A Nutech con-
trol console with vacuum pump, dry gas meter, a calibrated ori-
fice, and inclined manometers completed the sampling train.

Flue gas temperature was measured by means of a calibrated Type
K thermocouple which was connected to a direct readout pyrom-
eter. The thermocouple sensor was positioned adjacent to the
sampling nozzle.

Gas velocity was measured using a calibrated S-type pitot tube
provided with extensions and fastened alongside the sampling
probe.  Gas stream composition (carbon dioxide, oxygen, and car-
bon monoxide content)  was determined utilizing an Orsat appara-
tus.

PARTICLE SIZE DISTRIBUTION SAMPLING APPARATUS

A stainless steel nozzle was connected directly to an 8-stage
Andersen cascade impaction device which separated the particles
according to their effective aerodynamic particle diameters.  A
solid glass fiber filter was used to capture any particles that
passed through the impactor substrates to permit the measurement
of total particulate.   The filter holder was maintained at stack
temperature, and was connected by vacuum tubing to the first of
four Greenburg-Smith impingers which were included in the train
to condense the moisture in the gas stream.   All impingers were
maintained in a crushed ice bath.  An RAC control console with
vacuum pump, dry gas meter, a calibrated orifice, and inclined
manometers completed the sampling train.  See Figure 6 for a
schematic of the particle sizing apparatus.


                               -13-

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         .TEMPERATURE
            SENSOR
                                                                  THERMOMETER
                                                                   CHECK VALVE

                                                                    VACUUM  LINE

                                                                       'ACUUM GUAGE
                                                                                    THERMOMETERS
                                        HEATED AREA
                                              FILTER HOLDER
NOZZLE/HEATED -
   PROBE
 REVERSE TYPE
  PITOT TUBE
             PITOT MANOMETER
                                                                                        ORIFICE
                                                                                        AND
                                                                                        MANOMETER
                                 IMPINGERS
                                                            ICE BATH
               FIGURE 5  PARTICULATE SAMPLING TRAIN-EPA METHOD 5

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                                                                                        Thermometer
       Nozzle
 I
M
Ul
Reverse-Type
 Pilot Tube
                Pilot Manomeler

                    Orifice
                                                hermometers
                                                            Bypass Valve   lingers
        \
       Ice Balh


Vacuum Gauge
                                                                       Air Tighl Pump
                                                                                                     Check Valve
                                                                                                           Vacuum
                                                                                                             Line
                                  FIGURE 6  PARTICLE SIZE DISTRIBUTION SAMPLING
                                             APPARATUS - ANDERSEN 2000, INC.

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                         TEST PROCEDURES
PRELIMINARY TESTS

Preliminary test data were obtained at each sampling location.
Stack geometry measurements were recorded and sampling point
distances calculated.  A preliminary velocity traverse was per-
formed at each test location utilizing a calibrated S-type
pitot tube and a Dwyer inclined manometer to determine velocity
profiles.  A check for the presence or absence of cyclonic flow
was conducted at each test location prior to formal testing.
Stack gas temperatures were observed with a direct readout
pyrometer equipped with a chromel-alumel thermocouple.

Preliminary test data were used for nozzle sizing and nomagraph
set-up for isokinetic sampling procedures.

Calibration of the probe nozzles, pitot tubes, metering systems,
probe heaters, temperature gauges, and barometer were performed
as specified in Section 5 of EPA Method 5 test procedures (see
Appendix D for calibration data).

FORMAL TESTS

Ship Unloading Scrubber Inlet Duct

A single test was conducted at the Ship Unloading Scrubber Inlet
Duct to measure the concentration and mass rate of particulate
matter emissions.  Forty-eight traverse points (24 per axis)
were sampled for two minutes each, resulting in a total test
time of 96 minutes.

During particulate sampling, gas stream velocities were measured
by inserting a calibrated S-type pitot tube into the stream
adjacent to the sampling nozzle.   The velocity pressure
differential was observed immediately after positioning the noz-
zle at each point, and sampling rates were adjusted to maintain
isokinetic sampling.   Stack gas temperatures were also monitored
at each point with the pyrometer and thermocouple.  Additional
temperature measurements were made at the final impinger,  and at
the inlet and outlet of the dry gas meter.

Test data were recorded at each traverse point during all test
periods.   Leak checks were performed according to EPA Method 5
instructions prior to and after each run and/or component
change.   Table 1 presents a summary of test data and test result
summarization appears in Tables 2 and 3.
                              -16-

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Ship Unloading Scrubber Discharge Duct

One Method 5 test was conducted at the Ship Unloading Scrubber
Discharge Duct simultaneous with the inlet testing.  Forty-eight
points were traversed (24 per axis)  for two minutes each,
yielding a test period of 96 minutes.   Procedures for isokinetic
sampling were identical to those described in the Ship Unloading
Scrubber Inlet Duct section.

See Tables 1, 2, and 3 for test data and test result summaries,
respectively.

One sampling point located at a site of average velocity was
selected from particulate traverse data for one particle size
distribution test.  During this test the gas stream was sampled
isokinetically at that point for 95 minutes, which permitted
collection of sufficient sample for analysis without overloading
the filter substrates.  See Table 10 for data and results, and
Figure 7 for the distribution plot.

Visual determinations of plume opacity were performed by a cer-
tified observer according to Method 9 procedures.  A summary of
results is presented in Table 13.

No. 2 Fine Ore Storage Bin Baghouse Exhaust Duct

Three Method 5 tests were performed on the No. 2 Fine Ore
Storage Bin Baghouse Exhaust Duct.  A total of 32 points were
sampled (16 per port) for three minutes each, yielding a test
period of 96 minutes.

Isokinetic sampling procedures were identical to those previous-
ly described.  Table 4 shows test data summarization and Tables
6 and 7 present test results.

Visual determinations of plume opacity were performed in accord-
ance with EPA Method 9 procedures.  Table 14 presents a summary
of results.

Fugitive emissions determinations were also conducted at this
location according to EPA Method 22 procedures.  A summary of
results is presented in Table 19.
                              -17-

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No. 1 and No. 2 Fine Ore Storage Bins Exhaust Stack

Three Method 5 tests were performed on the No. 1 and No. 2 Fine
Ore Storage Bins Exhaust Stack.  Twelve points were traversed
(six per axis)  for eight minutes each, resulting in a test
period of 96 minutes.  Samples were collected concurrently with
those at No. 2 Fine Ore Storage Bin Baghouse Exhaust Duct.

Isokinetic sampling procedures were identical to those previous-
ly described.  Table 5 shows test data summarization and Tables
8 and 9 present test results.

Two particle size distribution tests were conducted at a point
of average velocity.  The first particle size distribution test
was 90 minutes in length and the second test was 180 minutes in
duration.  Sample volume, temperature, and pressure data were
recorded at five-minute intervals.  See Tables 11 and 12 for
test data and test result summaries, and Figures 8 and 9 for
distribution plots.

Visual determinations of plume opacity were performed by a cer-
tified observer according to Method 9 procedures.  Result sum-
maries are presented in Table 15.

Ship Unloading Platform
Ship Unloading ConveyoF Belt
Tailings Pond No. 2 Bed

Plume opacities were recorded at these locations in accordance
with EPA Method 9 procedures.  See Tables 16, 17 and 18 respec-
tively for a summary of results.

Fugitive emission frequencies were also recorded at these loca-
tions according to EPA Method 22 procedures.  Table 19 presents
a summary of these results.
                              -18-

-------
                      ANALYTICAL PROCEDURES


PARTICIPATE SAMPLE RECOVERY

At the conclusion of each test, the sampling trains were disman-
tled, openings sealed, and the components transported to the
field laboratory.  Sample integrity was assured by maintaining
chain-of-custody records, which will be supplied on request.

A consistent procedure was employed for sample recovery.

    1.  The glass fiber filter(s) was removed from its
        holder with tweezers and placed in its original
        container (petri dish), along with any loose
        particulate and filter fragments  (sample type 1).

    2.  The probe and nozzle were separated, and the
        internal particulate rinsed with acetone into
        a borosilicate container while brushing a mini-
        mum of three times until no visible particles
        remained.  Particulate adhering to the brush
        was rinsed with acetone into the same contain-
        er.  The front half of the filter holder was
        rinsed with acetone while brushing a minimum
        of three times.  The rinses were combined (sam-
        ple type 2)  and the container sealed with a
        Teflon-lined closure.

    3.  The total liquid in impingers 1, 2, and 3 was
        measured, the value recorded, and the liquid
        discarded.

    4.  The silica gel was removed from the last
        impinger and immediately weighed.

    5.  An acetone sample was  retained for blank
        analysis.

PARTICIPATE ANALYSIS

The filters (sample type 1)  and any loose fragments were oven
dried at 105QC for two to three hours, cooled in a desiccator,
and weighed to the nearest 0.1 milligram to constant weight.

The acetone wash samples (sample type 2)  were evaporated at
ambient temperature in tared beakers, and desiccated at ambient
temperature and pressure to a constant weight.  All sample resi-
due weights were adjusted by the acetone blank value.

                               -19-

-------
The weight of the material collected on the glass fiber
filter(s) plus the weight of the residue of the acetone nozzle/
probe/front-half filter holder washes represents the total EPA
Method 5 catch.  Complete laboratory results are presented in
Appendix B of this report.

PARTICLE SIZE SAMPLE RECOVERY AND ANALYSES

The cascade impactor substrates and any loose fragments were
carefully removed from their support plates with tweezers and
placed in individual containers (petri dishes)  for shipment to
Weston's laboratory.

Each cascade impactor filter was fired at 525°C and pre-
weighed to the nearest 0.1 milligram to constant weight at
Weston's laboratory prior to on-site application.  Subsequent to
emissions exposure, the cascade impactor substrates, back-up
filters, and any loose fragments were oven dried at 105°C for
two to three hours, cooled in a desiccator, and weighed to the
nearest 0.1 milligram to constant weight.
                              -20-

-------
                   TEST RESULTS AND DISCUSSION
Particulate test data and test result summaries are presented
in Tables 1 through 9 of this section.   Tables 10 through 12
contain data and results of the particle size distribution
tests; Figures 7 through 9 show the distribution plots.   Tables
13 through 18 present plume opacity determination results and
Table 19 shows fugitive emission test results summaries.

The quantity of particulate matter measured during the one test
at the Ship Unloading Scrubber Inlet Duct was 1.14 grains/DSCF
and 806 pounds/hour.  The particulate matter discharged to the
atmosphere from the Ship Unloading Scrubber Discharge Duct was
0.017 grains/DSCF and 12.6 pounds/hour.   The Ship Unloading
Scrubber particulate removal efficiency was 98.4 percent.

The particulate matter discharged from the No. 2 Fine Ore
Storage Bin Baghouse Exhaust Duct was <0.004 grains/DSCF and
 < 0.218 pounds/hour.  The particulate matter discharged from
the No. 1 and No. 2 Fine Ore Storage Bins Exhaust Stack was
 < 0.004 grains/DSCF and <0.482 pounds/hour.

It should be noted that only one test set was run at the Ship
Unloading Scrubber.  Weston test personnel were directed by the
EPA Administrator not to conduct further testing at this site
due to high plume opacities recorded at the Scrubber Discharge
Stack by the Weston certified observer.

As per instructions by Mr.  Dennis P. Holzschuh, EPA Task
Manager, certain samples obtained by Weston test personnel were
released to York Research Corporation for trace metals
analysis.  See Appendix B for the trace metals analysis results.
                              -21-

-------
                                         Table 1

                               Ship Unloading Area Scrubber
                                   Summary of Test Data
                          Reynolds Metals Company, Sherwin Plant
                                  Corpus Christi, Texas
Test Data
    Test Run Number
    Test Location
    Test Date
    Test Period

Sampling Data

    Sampling Duration, minutes
    Nozzle Diameter, inches
    Barometric Pressure, inches mercury
    Average Orifice Pressure Differential,  inches water
    Average Dry Gas Temperature at Meter,  °F
    Total Water Collected by Train, ml
    Standard Volume of Water Vapor Collected,  cubic feet
    Dry Gas Meter Calibration Factor,  dimensionless
    Sample Volume at Meter Conditions, cubic feet
    Sample Volume at Standard Conditions,  cubic feet1

Gas Stream Composition

    COj, percent by volume
    02, percent by volume
    CO, percent by volume
    N2, percent by volume
    Moisture in Gas Stream, percent by volume
    Mole Fraction of Dry Gas
    Molecular Weight of Dry Gas
    Molecular Weight of Wet Gas

Gas Stream Velocity and Volumetric Flow

    Static Pressure, inches water
    Absolute Pressure, inches mercury
    Average Temperature, °F
    Pitot Tube Calibration Coefficient, dimensionless
    Total Number of Traverse Points
    Velocity at Actual Conditions, feet/second
    Stack/Duct Cross-Sectional Area, square feet
    Volumetric Flow, wet actual cubic feet/minute
    Volumetric Flow, dry standard cubic feet/minute

Percent Isokinetic
Unit/Process Operations Data
   1
 Inlet
 6-24-80
0807-1000
 96.0
  0.135
 29.94
  0.88
 87
 41.6
    96
    00
 52.3
 50.7
  0.9
 20.0
  0.0
 79.1
  3.7
  0.963
 28.95
 28.5
                                                               102.3
    1
 Outlet
 6-24-80
0800-0952
   96.0
    0.188
   29.94
    1.42
   95
   43.
    2.
    1.
03
00
   58.5
   55.9
    0.9
   20.0
    0.0
   79.1
    3.5
    0.965
   28.95
   28.6
-6.1
29.49
85.
0.84
48.0
94.2
15.9
89,800.
82,600.
-15.0
28.84
77.
0.84
48.0
54.4
28.3
92,300.
84,400.
                                                                              101.2
!standard Conditions = 68°F (20°C)  and 29.92 inches (760 mm)  mercury,  dry basis.
                                           -22-

-------
                                                Table  2

                                      Ship Unloading Area Scrubber
                                  Summary of Particulate Test Results
                                 Reynolds Metals Company, Sherwin Plant
                                         Corpus Christi, Texas
                                             (English Units)
       Test Data
u>
i
    Test Number
    Test Location
    Test Date
    Test Time

Gas Flow

    Standard Cubic Feet/Minute, dry
    Actual Cubic Feet/Minute, wet

Particulates

    Front-Half Wash Residue Catch Fraction, g
    Filter Catch Fraction, g

        Total Particulates, g

Particulate Emissions^-

    Grains/Dry Standard Cubic Foot2
    Pounds/Hour
    Scrubber Particulate Removal, percent
                                                                         1
                                                                       Inlet
                                                                       6-24-80
                                                                      0807-1000
                                                                    82,600.
                                                                    89,800.
                                                                         2.2573
                                                                         1.4825

                                                                         3.7398
                                                                         1.14
                                                                       806.
   Discharge
   6-24-80
  0800-0952
84,400.
92,300
     0.0186
     0.0443

     0.0629
     0.017
    12.6
                                                                               98.4
       ^Based on Total Particulates captured by train.

       2Standard Conditions = 68°F and 29.92 inches Hg.

-------
                                                Table  3

                                      Ship Unloading Area Scrubber
                                   Summary  of  Particulate Test  Results
                                 Reynolds Metals Company, Sherwin Plant
                                         Corpus Christi, Texas
                                              (Metric Units)
       Test Data
i
NJ
    Test Number
    Test Location
    Test Date
    Test Time

Gas Flow

    Standard Cubic Meters/Minute, dry
    Actual Cubic Meters/Minute, wet

Particulates

    Front-Half Wash Residue Catch Fraction,g
    Filter Catch Fraction, g

        Total Particulates, g

Particulate Emissions^

    Grams/Dry Standard Cubic Meter2
    Kilograms/Hour
    Scrubber Particulate Removal, percent
                                                                         1
                                                                       Inlet
                                                                       6-24-80
                                                                      0807-1000
                                                                     2,340.
                                                                     2,540.
                                                                         2.2573
                                                                         1.4825

                                                                         3.7398
                                                                         2.61
                                                                       365.6
  Discharge
  6-24-80
 0800-0952
2,390.
2,610.
    0.0186
    0.0443

    0.0629
    0.039
    5.7
                                                                               98.4
       ^Based on Total Particulates captured by train.

       2Standard Conditions = 68°F and 29.92 inches Hg.

-------
                                                                Table 4

                                            No.  2 Fine Ore Storage Bin Baghouse Exhaust Duct
                                                          Summary  of Test Data
                                                 Reynolds Metals Company, Sherwin Plant
                                                          Corpus Christi,  Texas
Test Data
    Test Run Number
    Test Location
    Test Date
    Test Period
Sampling Data

    Sampling Duration, minutes
    Nozzle Diameter, inches
    Barometric Pressure, inches mercury
    Average Orifice Pressure Differential, inches water
    Average Dry Gas Temperature at Meter, °P
    Total Water Collected by Train, ml
    Standard Volume of Water Vapor Collected, cubic feet
    Dry Gas Meter Calibration Factor, dimensionless
    Sample Volume at Meter Conditions, cubic feet
    Sample Volume at Standard Conditions, cubic feet1

Gas Stream Composition

    CO2, percent by volume
    02, percent by volume
    CO, percent by volume
    N2» percent by volume
    Moisture in Gas Stream, percent by volume
    Mole Fraction of Dry Gas
    Molecular Weight of Dry Gas
    Molecular Weight of Wet Gas

Gas Stream Velocity and Volumetric Flow

    Static Pressure, inches water
    Absolute Pressure, inches mercury
    Average Temperature, °F
    Pitot Tube Calibration Coefficient, dimensionless
    Total Number of Traverse Points
    Velocity at Actual Conditions, feet/second
    Stack/Duct Cross-Sectional Area, square feet
    Volumetric Flow, wet actual cubic feet/minute
    Volumetric Flow, dry standard cubic feet/minute

Percent Isokinetic
Discharge Duct
     6-25-80
    0915-1100
      96.0
       0.180
      30.00
       1.83
     110.
      34.6
       1.63
       1.00
      69.4
      64.9
       0.9
      20.0
       0.0
      79.1
       2.5
       0.975
      28.95
      28.7
      -7.1
      29.48
      88.
       0.84
      32.0
      67.9
       1.77
   7,200.
   6,670.
Discharge Duct
     6-25-80
    1215-1415
      96.0
       0.180
      29.99
       2.59
     108.
      38.8
       1.83
       1.00
      84.2
      79.0
       0.9
      20.0
       0.0
      79.1
       2.3
       0.977
      28.95
      28.7
      -7.1
      29.47
      88.
       0.84
      32.0
      79.6
       1.77
   8,440.
   7,820.
Discharge Duct
     6-25-80
    1450-1650
      96.0
       0.180
      29.96
       2.50
                                                                                                                        Average
     112.
      38.
       1
       1
      83
 80
,00
.5
                                              77.7
       0.9
      20.0
       0.0
      79.1
       2.3
       0.977
      28.95
      28.7
      -7.1
      29.44
      88.
       0.84
      32.0
      79.2
       1.77
   8,400.
   7,780.
 96.0
  0.180
 29.98
  2.31
110.
 37.2
  1.75
  1.00
 79.0
 73.9
                 0.9
                20.0
                 0.0
                79.1
                 2.4
                 0.976
                28.95
                28.7
                -7.1
                29.46
                88.
                 0.84
                32.0
                75.6
                 1.77
             8,010.
             7,420.
Unit/Process Operations Data
                                                                101.3
                                                                                    105.2
                                                                                                        104.0
                                                                                                                           103.5
*Standard Conditions = 68°F (20°C) and 29.92 inches (760 mm) mercury, dry basis.

-------
                                                                 Table 5

                                           No. 1 and No. 2 Fine Ore Storage Bins Exhaust Stack
                                                           Summary  of  Test Data
                                                  Reynolds  Metals Company, Sherwin  Plant
                                                          Corpus Christi, Texas
Test Data
    Test Run Number
    Test Location
    Test Date
    Test Period
Sampling Data

    Sampling Duration, minutes
    Nozzle Diameter, inches
    Barometric Pressure, inches mercury
    Average Orifice Pressure Differential, inches water
    Average Dry Gas Temperature at Meter, °F
    Total Water Collected by Train, ml
    Standard Volume of Water Vapor Collected, cubic feet
    Dry Gas Meter Calibration Factor, dimensionless
    Sample Volume at Meter Conditions, cubic feet
    Sample Volume at Standard Conditions, cubic feetl

Gas Stream Composition

    C02, percent by volume
    02, percent by volume
    CO, percent by volume
    N2, percent by volume
    Moisture in Gas Stream, percent by volume
    Mole Fraction of Dry Gas
    Molecular Weight of Dry Gas
    Molecular Weight of Wet Gas

Gas Stream Velocity and Volumetric Flow

    Static Pressure, inches water
    Absolute Pressure, inches mercury
    Average Temperature, °F
    Pitot Tube Calibration Coefficient, dimensionless
    Total Number of Traverse Points
    Velocity at Actual Conditions, feet/second
    Stack/Duct Cross-Sectional Area, square feet
    Volumetric Flow, wet actual cubic feet/minute
    Volumetric Flow, dry standard cubic feet/minute

Percent Isokinetic
Discharge Stack
     6-25-80
    0915-1050
      96.0
       0.188
      30.00
       1.25
      95.
      35.6
       1.68
       1.00
      59.6
      57.1
       0.9
      20.0
       0.0
      79.1
       2.9
       0.971
      28.95
      28.6
       0.40
      30.03
      91.
       0.84
      12.0
      53.8
       4.75
  15,300.
  14,300.
Discharge Stack
     6-25-80
    1208-1340
      96.0
       0.188
      29.99
       1.32
      96.
      42.4
         00
         00
      62.9
      60.1
       0.9
      20.0
       0.0
      79.1
       3.2
       0.968
      28.95
      28.6
     0.40
    30.02
    93.
     0.84
    12.0
    54.9
     4.75
15,600.
14,500.
Discharge Stack
     6-25-80
    1442-1620
      96.0
       0.188
      29.96
       1.33
                                                                                                                        Average
      89.
      49.
       2.
       1.
      61.
                           34
                           00
                           0
                                              59.0
       0.9
      20.0
       0.0
      79.1
       3.8
       0.962
      28.95
      28.5
                           0.40
                          29.99
                          94.
                           0.84
                          12.0
                          53.7
                           4.75
                      15,300.
                      14,000.
96.0
 0.188
29.98
 1.30
93.
42.6
 2.01
 1.00
61.2
58.7
                                            0.9
                                           20.0
                                            0.0
                                           79.1
                                            3.3
                                            0.967
                                           28.95
                                           28.6
                          0.40
                         30.01
                         93.
                          0.84
                         12.0
                         54.1
                          4.75
                     15,400.
                     14,300.
Unit/Process Operations Data
                                                                102.3
                                                                                    106.4
                                                                                                        107.7
                                                                                                                            105.5
^Standard Conditions = 68°F (20°C)  and 29.92 inches (760 mm)  mercury, dry basis.

-------
                                                                Table 6

                                            No.  2  Pine  Ore  Storage  Bin  Baghouse  Exhaust  Duct
                                                  Summary of Particulate Test Results
                                                Reynolds Metals  Company,  Sherwin  Plant
                                                         Corpus Christi, Texas
                                                            (English Units)
Test Data
    Test Number
    Test Location
    Test Date
    Test Time
Gas Flow

    Standard Cubic Feet/Minute, dry
    Actual Cubic Feet/Minute, wet

Part iculates

    Front-Half Wash Residue Catch Fraction,g
    Filter Catch Fraction,g

        Total Particulates, g

Particulate Emissions1

    Grains/Dry Standard Cubic Foot^
    Pounds/Hour
Discharge Duct
     6-25-80
    0915-1100
   6,670.
   7,200.
Discharge Duct
     6-25-80
    1215-1415
   7,820.
   8,440
Discharge Duct
     6-25-80
    1450-1650
   7,780.
   8,400.
                                                                                                                         Average
7,420.
8,010.
       0.0013
       0.0147

       0.0160
       0.004
       0.218
       0.0020
       0.0083

       0.0103
       0.002
       0.135
       0.0013
       0.0072

       0.0085
       0.002
       0.113
    0.0015
    0.0101

    0.0116
    0.003
    0.155
Ifiased on Total Particulates captured by train.

2Standard Conditions = 68°F and 29.92 inches Hg.

-------
                                                                Table 7

                                            No.  2  Fine  Ore  Storage  Bin  Baghouse  Exhaust  Duct
                                                  Summary of Particulate Test Results
                                                Reynolds Metals  Company,  Sherwin  Plant
                                                         Corpus Christi, Texas
                                                             (Metric  Units)
Test Data
    Test Number
    Test Location
    Test Date
    Test Time
Gas Plow

    Standard Cubic Meters/Minute, dry
    Actual Cubic Meters/Minute, wet

Particulates

    Front-Half Wash Residue Catch Fraction,g
    Filter Catch Fraction, g

        Total Particulates, g

Particulate Emissions^

    Grams/Dry Standard Cubic Meter^
    Kilograms/Hour
Discharge Duct
     6-25-80
    0915-1100
     188.9
     203.9
       0.0013
       0.0147

       0.0160
       0.009
       0.099
Discharge Duct
     6-25-80
    1215-1415
     221.4
     239.0
       0.0020
       0.0083

       0.0103
       0.005
       0.061
Discharge Duct
     6-25-80
    1450-1650
     220.3
     237.9
       0.0013
       0.0072

       0.0085
       0,005
       0.051
                                                                                                                         Average
210.2
226.9
  0.0015
  0.0101

  0.0116
  0,006
  0.070
iBased on Total Particulates captured by train.

2Standard Conditions = 68°F and 29.92 inches Hg.

-------
                                                                Table 8

                                          No. 1 and No. 2 Fine Ore Storage Bins Exhaust stack
                                                  Summary of Particulate Test Results
                                                 Reynolds  Metals  Company,  Sherwin  Plant
                                                         Corpus Christi, Texas
                                                            (English Units)
Test Data
    Test Number
    Test Location

    Test Date
    Test Time
Gas Flow

    Standard Cubic Feet/Minute, dry
    Actual Cubic Feet/Minute, wet

Particulates

    Front-Half Wash Residue Catch Fraction, g
    Filter Catch Fraction, g

        Total Particulates, g

Particulate Emissions^

    Grains/Dry Standard Cubic Foot2
    Pounds/Hour
 Fine Ore Bin
Discharge Stack
    6-25-80
   0915-1050
 14,300.
 15,300.
 Fine Ore Bin
Discharge Stack
    6-25-80
   1208-1340
 14,500.
 15,600.
Fine Ore Bin
 Discharge Stack
     6-25-80
    1442-1620
  14,000.
  15,300.
                                                                                                                         Average
14,300.
15,400.
      0.0055
      0.0062

      0.0117
      0.388
      0.0076
      0.0047

      0.0123
                          0.392
       0.0077
       0.0076

       0.0153
                                              0.482
     0.0069
     0.0062

     0.0131
                                                                                                                               0.421
^Based on Total Particulates captured by train.

2Standard Conditions = 68°F and 29.92 inches Hg.

-------
                                                                Table 9

                                          No. 1 and No. 2 Fine Ore Storage Bins Exhaust Stack
                                                  Summary of Particulate Test Results
                                                 Reynolds  Metals  Company,  Sherwin  Plant
                                                         Corpus Christi, Texas
                                                             (Metric  Units)
Test Data
    Test Number
    Test Location

    Test Date
    Test Time
Gas Flow

    Dry Standard Cubic Meters/Minute
    Wet Actual Cubic Meters/Minute

Particulates

    Front-Half Wash Residue Catch Fraction, g
    Filter Catch Fraction, g

        Total Particulates, g

Particulate Emissions1

    Grams/Dry Standard Cubic Meter2
    Kilograms/Hour
 Fine Ore Bin
Discharge Stack
    6-25-80
   0915-1050
    404.9
    433.3
      0.0055
      0.0062

      0.0117
      0.007
      0.176
 Fine Ore Bin
Discharge Stack
    6-25-80
   1208-1340
    410.6
    441.7
      0.0076
      0.0047

      0.0123
      0.007
      0.178
Fine Ore Bin
 Discharge Stack
     6-25-80
    1442-1620
     396.4
     433.3
       0.0077
       0.0076

       0.0153
       0.009
       0.219
                                                                                                                         Average
404.0
436.1
  0.0069
  0.0062

  0.0131
  0.008
  0.191
Iflased on Total Particulates captured by train.

2Standard Conditions = 68°F and 29.92 inches Hg.

-------
                              Table  10

                     PARTICLE SIZE DISTRIBUTION
Date:   6-24-80                           P.    (in. Hg.)   29.94
                                           bar
Location:   Reynolds  Metals  Company        Stack Temp ( F)  76
Sampling Location: Shtp  Unloading Scb.Outls.amP1e Time (Min.) 95.0
Traverse Point No. Sampled: X-15         Sample Volume  (cf) 59.3

Run No.  1                                  Molsture <* ^20)    3'5
                                          Meter Temp ( F)  1QO
                                          Flow Setting, ^H   1.2
                                              (in. H20)
                                          Nozzle Diameter (in.) 0.188
Sample Flow Rate  (at  stack conditions);0.6l cfm
              Net Wt.          %          Cumulative            EAD
                (mg)                            %             (Microns)
  1             18.9          32.7            100.0             12.5

  2             0.5           0.8             67.3              7.8
  3             0.9           1.6             66.5              5.2
  4             1.8           3.1             64.9              3.6

  5             4.5           7.8             61.8              2.7
  6             15.4          26.6             54.0              1.2
  7             8.7          15.1             27.4              0.71
  8             4.8           8.3             12.3              0.48
Backup
 Filter         2.3           4.0
TOTAL          57.8

                                 -31-

-------
                                                             Figure  7
        I/I

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        u
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o


oc


o


I


o
an
UJ
<
tu
>
       o
       LU
10.0
 9.0
 8.0

 7.0

 6.0

 5.0


 k.O


 3.0




 2.0
 1.0
 0.9
 0.8

 0.7

 0.6

 0.5

 0.4


 0.3
              0.2
              0.1
                                                 Ship  Unloading Scrubber Outlet

                                              Run No.  1  Particle Size  Distribution
                                                     z
                 0.01   0.05 O.I 0.2 0.5  I
                                  10     20  30  40 50   80  70  BO    90


                                       CUMULATIVE PERCENTAGE


                                   By Weight  Less Than Diameter
                                                                                   95
                                                                                 98  99
9.1 99.9
99.99

-------
                              Table  11


                     PARTICLE SIZE DISTRIBUTION
Date:   6-25-80                           Pbar (in.  Hg.)  30.00

Location: Reynolds Metals  Company          Stack Temp ( F) 9°

Sampling Location: No. t  & No. 2 Fine Ore. Sample Time (Min.)90.0
                   Bins Exhaust Stack                    .  . c-. c
Traverse Point  No. Sampled:   X-3          Sample Volume (cf) ;>/•:>

Run No. 1                                  Moisture (% H20) 2-°

                                          Meter Temp (°F)
                                          Flow Setting, O H1-35
                                              (in.  H20)

                                          Nozzle Diameter (in.)o.l85
Sample Flow Rate  (at  stack  conditions):0.63 cfm
              Net Wt.         %           Cumulative            EAD
                (mg)                            %              (Microns)
  1              2.A          17.8            100              12.2

  2              1.0           7.A             82.2             7.6

  3              1.1           8.2             7^.8             5.2

  *              0.8           5.9             66.6             3.6

  5              1.5          11.1             60.7             2.A

  6              1.6          11.9             A9.6             1.2

  7              1.3           9.6             37.7             0.71

  8              1.5          11.1             28.1             O.A7
Backup
 Filter          2-3          17.0             17.0
TOTAL
                13.5
                                 -33-

-------
                                              Figure 8
                            No.  1  and No.  2 Fine Ore Bins  Exhaust Stack
                               Run No.  1  Particle Size  Distribution
EFFECTIVE AERODYNAMIC PARTICLE DIAMETER, microns
O O OOOOOOO— 10 VA> .p- Ui ON >J OOVOC
— N» U) .p- Ul ON vj OOVOO O O O OOOOOC
































































































































































/














i
/
/












t
I
I
1












/
1
















1















1
•f














, 1
/
1











1
1
•j
/


























































































































0.01   0.05 O.I 0.2 0.5  1
10    20   30  40  50  60  70  80

     CUMULATIVE PERCENTAGE
 By Weight Less Than Diameter
                                                            90
95

-------
                             Table  12

                     PARTICLE SIZE  DISTRIBUTION
Date:   6-25-80                           p     (in.  Hg.) 29-99
Location:  Reynolds Metals                Stack Temp ( F)  90
Sampling Location: No.  1 & No.  2 Fine Ore  Sample Time (Min.)l80
                   Bins Exhaust Stack     „    ,     ,    /,»..,..-.
Traverse Point No.  Sampled:  X-3          Sample Volume (cf) 113.152
n   „   0                                 Moisture (% H,0)   2.0
Run No. 2                                              2
                                          Meter Temp (°F) 95
                                          Flow Setting, AH   1.35
                                              (in.  H20)
                                          Nozzle Diameter  (in.)°-l85
Sample Flow Rate  (at stack conditions):0.62  cfm
Plate
No.
1
2
3
*
5
6
7
8
Net Wt.
(mg)
12.2
1.5
1.3
0.5
1.2
0.8
.1.1
1.0
*
55.5
6.8
5.9
2.3
5.5
3.6
5.0
4.5
                                         Cumulative             EAD
                                              %              (Microns)
                                             100                12.2
                                             Mt.5               7.6
                                             37,7               5.2
                                             31.8               3.6
                                             29.5               2.4
                                             24.0               1.2
                                             20.4               0.71
                                             15.A               0.47
Backup          2.1*         10.9               10.9
 Filter
TOTAL          22.0
                                 -35-

-------
                                                                 Figure 9
i
u>
        V)

        O

        U

        1
        UJ

        O
O

£


O
O
oc
LLI
<

UJ
10.0
 9.0
 8.0
 7.0
 6.0

 5.0

 k.O


 3.0



 2.0
 1.0
 0.9
 0.8
 0.7
 0.6

 0.5

 0.4

 0.3
              0.2
              0.1
                                              No. 1 and No.  2 Fine Ore Bins  Exhaust Stack
                                                  Run No.  2  Particle Size Distribution
                 0.01  0.05 O.I 0.2  0.5 I
                                  10     20  30  40 50   60  70  BO

                                       CUMULATIVE PERCENTAGE
                                                                              90
                                                                            95
                                                                              99
99.99

-------
Date:
     2k June 1980
         Table 13
 SUMMARY  OF VISIBLE  EMISSIONS

	   Type  of  Plant:
     oT Discharge:
          Stack
       of Point of Discharge:      5  Feet
Wind Direction:        Out of Southwest
|plor of Plume:
fcserver No.:
           Rust
Distance from Observer to Discharge Point:
 irection of Observer from Discharge Point:
 bight of Observation Point; 	
 escriptfon of 'Background:	
Bauxite Processing
               Location of  Discharge:.Ship Unloading Outlet
               Description  of  Sky;    Clear blue sky	
               Wind Velocity:  	
               Detached Plume:
                                                      10-30 mph
                                 Duration of Observation:
                                   40 Feet
                                   Southeast
                                      heet
                                   Blue sky and hill
                                             97 minutes
SUMMARY OF-AVERAGE OPACITY
Set
Number
1
2
3
k
s
6
7
/
8
9
10
11
12
13
1 ^
14
i ~
15
» J>
16
17
18
19
20
Time Opacity
Start
0808
0814
0820
0826
0832
0838
0844
0850
0856
0902
0908
0914
0920
0926
0932
0938




End
081 4
.0820
0826
0832
0838
0844
0850
0856
0902
0908
0914
0920
0926
0932
0938
0945




Sum
420
465
485
455
470
455
440
450
440
430
455
445
460
465
460
555




Average
17.5
19.4
20.2
18.9
19.6
18.9
18.3
18.7
18.3
17-9
18.9
. 18.5
19.1
19.4
19.1
19.8




Set
Number
21
22
23
24
25
26
27
28
29
30
^ **
31
^ *
32
33
34
J •
35
«/ «*
36
37
38
39
40
T
Start




















me
End




















Opa
Sum




















pity
Average




















Sketch Showing How.Opacity Varied with Time:
 Opacity
20

15

10

 5
                                                                                     4-
                                       1/2 hr-   Time,  Hours  ]  nr-
                                                                       1  1/2 hr.
                                              -37-

-------
                                         Table  14
                                SUMMARY OF VISIBLE EMISSIONS
Date:    	
Type oT~Di sch'arge: Baghouse
25 June 1980
Height of Point of Discharge:  6  feet
Wind Direction:    None	
Color of Plume:    Rust
Observer No.:
Distance from Observer to Discharge Point:
Direction of Observer from Discharge Point:
Height of Observation Point:
Description of Background:
Type of Plant:   Bauxite Processing
                                  Location of Discharge: Fine Ore Bin
                                  Description of Sky:  Inside BuiIding
                                  Wind Velocity: 	None	
                                  Detached Plume:        	
                                  Duration of Observation:
                                     80  feet
                          3 runs @ 1  hour each
                   Gray Machinery

Set
Number
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
SUMMARY OF AVERAGE OPACITY
Time
Start
0925
0931
0937
0943
0949
0955
1001
1007
1013
1019
1215
1221
1227
1233
1239
121*5
1251
1257
1303
1309
End
0930
0936
0942
0948
0954
1000
1006
1012
1018
1024
1220
1226
1232
1238
1244
1250
1256
1302
1308
1314
Opacity
Sum
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Average
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Set
Number
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
T
Start
1505
1511
1517
1523
1529
1535
1541
1547
1553
1559










me
End
1510
1516
1522
1528
1534
1540
1546
1552
1558
1604











Opac
Sum
0
0
0
0
0
0
0
0
0
0










;ity
Average
0
0
0
0
0
0
0
0
0
0










Sketch Showing How Opacity Varied with Time:
 Opaci ty
  (*)
                                    1 hour
                                     Time, Hours  2 hours
                                       3  hours
                                              -38-

-------
                                        Table 15
                                SUMMARY OF VISIBLE EMISSIONS
        25  June  1980
Date:
Type of Discharge:   Stack
                                             Type of Plant:   Bauxite Processing
                                B'
Height of Point of Discharge:      125 feet
Wind Direction:    Out of  South	
Color of Plume:    None	
Observer No. :	
Distance from Observer to Discharge Point:
Direction of Observer from Discharge Point:
Height of Observation Point: 	'
Description of Background:  	
                                             Location of Discharge:  p;np
                                             Description of Sky:    Clear Blue Sk
                                             Wind Velocity: 10-30 mph
                                             Detached Plume:
                                             Duration of Observation:
                                              350 feet	
                           4.8 hours
                                              East
                                              100 feet
                                              Stacks, PTpes, Sky

Set
Number
1
2
3
4
5
s
6
7
8
9
10
11
12
13
1 *
14
15
16
17
18
19
20
SUMMARY OF AVERAGE OPACITY
Time
Start
0926
0932
0938
0949
0956
1002
1008
1014
1020
1026
1032
1038
1044
1050
1056
1102
1209
1215
1221
1227
End
0931
0937
0943
0955
1001
1007
1013
1019
1025
1031
1037
1043
1049
1055
1101
1107
1214
1220
1226
1232
Opacity
Sum
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Average
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Set
Number
21
22
23
24
25
*• «•' •
26
27
28
29
30
31
j '
32.
33
34
35
36
37
38
39
40
T
Start
1233
1239
1245
1251
1257
1303
1309
1315
1321
1327
1333
1339
1442
1448
1454
1500
1506
1512
1518
1524
me
End
1238
1244
1250
1256
1302
1308
1314
1320
1326
1332
1338
1344
1447
1453
1459
1505
1511
1517
1523
1529

Opa<
Sum
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
;ity
Average
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Sketch Showing How Opacity Varied with Time:

             8   	

             6   	

             4   	

             2	
Opaci ty
                                hbur
2 hoursj hours
  Time, Hours
                                                                                  4 hiurs
                                              -39-

-------
                                     Table  15  (continued)
                                SUMMARY OF VISIBLE EMISSIONS
             25 June  1980
Date: _^_	
Type of Discharge:    Stack	
Height of Point of Discharge:  125 feet
Wind Direction: 	Out of  South	
Color of Plume: 	None	
Observer No. :	_
Distance from Observer to Discharge Point:
Direction of Observer from Discharge Point:
Height of Observation Point:  	'
Description of Background:  	
Type of Plant:    Bauxite Processing
                                              Location of Discharge: Fine Ore Bin Exhaust Stack
                                              Description of Sky: Clear Blue Sky	
                                              Wind Velocity:   10-30 mph	
                                              Detached Plume:
                                              Duration of Observation:
                                             350 feet  	
                                             East
                                             100 feet
                                             Stacks, Pipes, Sky

Set
Number
1
2
3
k
5
6
7
8
9.
10
11
12
13
14
15
16
17
18
19
20
SUMMARY OF AVERAGE OPACITY
Time
Start
1530
1536
1542
1548
155k
1600
1606
1612












End
1535
1541
1547
1553
1559
1605
1611
1617












Opaci ty
Sum
0
0
0
0
0
0
0
0












Average
0
0
0
0
0
0
0
0












Set
Number
21
22
23
21*
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
T
Start




















me
End





















Opa<
Sum




















pity
Average




















Sketch Showing How Opacity Varied with Time:
 Opaci ty
                              5 hours
                                                 Time, Hours
                                              -40-

-------
                  2k  June  1980
         Table 16
SU:;.",ARY OF VISIBLE  EMISSIC'.'S

              Type  of  Plant:
Type ot Dischorgc:   Conveyor
Height of Point of  Discharge:
Ir/ind Direction:   Northwest
Color of Plume,:   Rust
Observer No.:
Roof Level
Distance from Observer  to  Discharge  Point:
Direction of Observer from Discharge Point:
Height of Observation Point: 	
Description of Background:  	
                   Bauxite Processing
Location of  Pischarge:Ship  Unloading Platform
Description  of Sky:    Clear blue  sky
Wind Veloci ty:
Detached Plume:
                                     18 mph
              Duration  of Observation:
               \5  feet
                           101 minutes
               Southeast
               Koor^eve I
               Discharge Pipe

Set
Number
1
2
3
4
5
6
7
8
9
10
11
12
13
14
\s
16
17
18
19
20
SUMMARY OF AVERAGE OPACITY
Time
Start
0800
0806
0812
0818
0824
0830
0836
0842
0848
0854
0900
0906
0912
0918
0924
0930
0936



End
0806
0812
0818
0824
0830
0836
0842
0848
0854
0900
0906
0912
0918
0924
0930
0936
0941



Opacity
Sum
85
120
120
155
165
215
165
195
40
135
260
5
0
0
0
0
0



Average
3-5
5.0
5.0
6.4
6.9
9-0
6.9
8.1
1.7
5.6
1.0.8
0.2
0
0
0
0
0



Set
Number
21
22
23
24
25
26
27
28 -
29
30
31
32
33
34
35
36
37
38
39
40
T
Start




















me
End




















Opa
Sum




















pity
Average



















i
Sketch Showing How Opacity Varied with Time:
                                     1/2 hour    Time, Hours   1 hour
                                                   1-1/2 hour
                                               -41-

-------
           2k June 1980
                       Conveyor
Date:     	
Type of Discharge:
Height of Point of Discharge:     4 Feet
Wind Direction: 	Northwest	
Color of Plume:
Observer No.:
         Table 17
 SUMMARY OF VISIBLE  EMISSIONS

	   Type  of  Plant:
                       Rust
Distance from Observer to Discharge Point:
Direction of Observer from Discharge Point:
Height of Observation Point; 	
Description of 'Background: 	
Bauxite Processing
              Location of  Discharge; .  Ship Unloading  Conveyor
              Description  of  Sky;     NA	
              Wind Velocity:  	
              Detached Plume:
                                                                   5  mi/hr.
              Duration of  Observation:
                3-4 Feet
                                                                           104 minutes
                                                o feet north or doorway
                                                ground level
                                                doorway

Set
Number
1
2
3
k
5
6
7
/
8
9
10
11
12
13
1 J
11*
15
' S
16
l \J
17
18
19
20
SUMMARY OFAVERAGE OPACITY
Time Opacity
Start
0806
0812
0818
0824
0830
0836
0842
0848
0854
0900
0906
0912
0918
0924
0930
0936
0942



End
0812
.0818
0824
0830
0836
0842
0848
0854
0900
0906
0912
0918
0924
0930
0936
0942
0950



Sum
60
90
45
85
55
55
80
70
60
45
65
40
70
45
50
45
90



Average
2.5
3-7
1.9
3-5
2.3
2.3
3-3
2.9
2.5
1-9
2.7
1.7
2.9
1.9
2.1
1.9
3-7



Set
Number
21
22
23
2k
25
26
27
28
29
30
31
32
33
34
35
36
J**
37
38
39
40
T
Start




















me
End




















Opa
Sum




















pity
Average




















Sketch Showing How Opacity Varied with Time:
                                          1/2  hr- Time, Hours    '  nr-
                                                                                     1  1/2  hr.
                                              -42-

-------
                                         Table 18
                                SU.'-'.MARY OF VISIBLE  EMISSIONS
        25  June  1980
Date:    ^	
Type of Discharge:   Tailing  Pond
   Type of Plant:   Bauxite Processing
Height of Point of Discharge:    1 foot
Wind Direction:      Southwest	
Color of Plume:      Rust	
Observer No.:
   Location of Discharge: Tailing Pond.  Bed
   Description of Sky:    Clear B.lue Sky
   Wind Velocity: 	
   Detached Plume:
20 mph
   Duration of Observation:  1  hour
Distance from Observer to Discharge Point: 2 ft. overlooking area of dry claylike bauxite
Direction of Observer from Discharge Point:Northeast corner looking south of Bed #2	
Height of Observation Point: 	   Ground Level	
Description of Background: 	
Dry c1 ay 1 ike bauxite

Set
Number
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
SUMMARY OF AVERAGE OPACITY
Time
Start
1435
1441
1447
1453
1459
1505
1511
1517
1523
1529










End
1440
1446
1452
1458
1504
1510
1516
1522
1528
1534










Opacity
Sum
0
0
0
0
0
0
0
0
0
0










Average
0
0
0
0
0
0
0
0
0
0










Set
Number
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
T
Start




















me
End




















Opaci ty
Sum




















Average




















Sketch Showing How Opacity Varied with Time:
 Opaci ty
  (*)
                                      1 hour
      Time, Hours
                                               -43-

-------
                        Table 19
 Mean Fugitive Emission Values (% frequency of emission)
Test
Test 1
Test 2
Test 3
Site Mean
Test
Test 1


Test
Test 1
Test
Test 1
                      FINE ORE BIN
                   TAILINGS POND NO.  2
SHIP UNLOADING CONVEYOR
                 SHIP UNLOADING PLATFORM
                              Test Mean
                                < 1.0
                                < 1.0
                                < 1.0
                                < 1.0
                              Test Mean
                                  0.0
                              Test Mean
                                 69.2
                              Test Mean
                                 60.7
                          -44-

-------