United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park NC 27711
EMB REPORT 81 -CBS-1
November & December 1981
Air
Coke Battery Stack
Sulfate  Emissions

Emission Test Report
Republic Steel -
Cleveland Works
Cleveland, Ohio
                     VOLUME I


                  TEXT AND APPENDIX A

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               SUMMARY TEST REPORT
     Method Development and Testing for the
           Coke Battery Stack Industry
         Republic Steel-Cleveland Works

                   Volume I
             Text and Appendix A
                     by

          PEDCo Environmental,  Inc.
             11499 Chester Road
           Cincinnati,  Ohio  45246
           Contract No. 68-02-3546
           Work Assignment No. 10
               ESED No. 74/4i
                Task Manager

                 Frank Clay
     Emission Measurement Branch, MD-13
 Emission Standards and Engineering Division
    U.S. ENVIRONMENTAL PROTECTION AGENCY
RESEARCH TRIANGLE PARK, NORTH CAROLINA  27711
                December 1981

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                            CONTENTS
Figures                                                      iv
Tables                                                       vi
QA Element Finder                                            xi

1.   Introduction     '                                      1-1

2.   Summary of Results                                     2-1

     2.1  Particulate sampling protocol                     2-1
     2.2  Summary of particulate and related analyses
            results                                         2-9
     2.3  Comparison of particulate results at selected
            temperature                                     2-41
     2.4  Particulate sulfate                               2-53
     2.5  Discussion of particulate results                 2-56
     2.6  Discussion of back-half results                   2-63
     2.7  Reduced sulfur analysis by Method 15              2-64
     2.8  Gas stream flow rate and composition              2-71
     2.9  Visible emissions                                 2-79
     2.10 Process data                                      2-83

3.   Process Description                                    3-1

4.   Sampling and Analytical Procedures                     4-1

     4.1  Sampling locations                                4-1
     4.2  Gas stream flow rate, temperature, and
            composition                                     4-4
     4.3  Particulate, sulfur dioxide, and sulfuric
            acid mist emission tests                        4-4
     4.4  Reduced-sulfur emission tests                     4-15

5.   Quality Assurance                                      5-1
                               11

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                      CONTENTS (continued)
Appendices

  A  Computer Printouts and Example Calculations            A-l
  B  Field Data                                             B-l
  C  Laboratory Results                                     C-l
  D  Sampling and Analytical Procedures                     D-l
  E  Calibration Procedures and Results                     E-l
  F  Quality Assurance                                      F-l
  G  Project Participants and Project Log                   G-l
  H  Results of a Study to Evaluate Effects of Heating
       on Filter Tare Weights                               H-l
  I  Midwest Research Institute Process Summary             1-1
                               111

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                             FIGURES

Number                                                      Page

 2-1      Particulate Concentration vs. Average Actual
            Filter Temperature During NCOG Underfiring      2-26

 2-2      Particulate Concentration vs. Average Actual
            Probe Temperature During DCOG Underfiring       2-27

 2-3      Summary of Best-Fit Lines from Particulate
            Concentration vs. Average Actual Filter
            Temperature for NCOG and DCOG Underfiring       2-28

 2-4      Average Percent Weight Loss from Sampling
            Train 5, 121°C (250°F) Front-Half Tempera-
            ture, Due to Heat Conditioning Prior to
            Weighing (NCOG Underfiring)                     2-45

 2-5      Average Percent Weight Loss from Sampling
            Train 5, 121°C (250°F) Front-Half Tempera-
            ture, Due to Heat Conditioning Prior to
            Weighing (DCOG Underfiring)                     2-46

 2-6      Comparison of Average Particulate Concentration
            Determined from Sampling at the Specified
            Temperature and from Sampling at 121°C  (250°F)
            and Analyzing After Sequentially Heating at
            Specified Temperature for NCOG Underfiring
            Conditions                                      2-57

 2-7      Comparison of Average Particulate Concentration
            Determined from Sampling at the Specified
            Temperature and from Sampling at 121°C  (250°F)
            and Analyzing After Sequentially Heating at
            Specified Temperatures for DCOG Underfiring
            Conditions                                      2-58

 2-8      Comparison of Average Particulate Concentration
            from Actual Sampling Temperature, Sequential
            Heating, and IPA Extraction for NCOG Under-
            firing Conditions                               2-60
                               IV

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                       FIGURES (continued)

Number                                                      Page


 2-9      Comparison of Average Particulate Concentration
            from Actual Sampling Temperature, Sequential
            Heating, and IPA Extraction for DCOG Under-
            firing Conditions                               2-61

 2-10     H0S Response Curve with Increasing Concentra-
           tion                                            2-69

 3-1      Process Flow Diagram, Republic Steel-Cleveland
            Works                                           3-2

 4-1      Coke Battery No. 1 Flue Gas Exit Stack            4-2

 4-2      Coke Battery No. 1 Exit Stack Sampling Site
            and Traverse Point Locations                    4~3
                               v

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                             TABLES

Number                                                      Page

 2-1      Summary of Sample Trains Temperature and Con-
            figuration During NCOG Underfiring Testing      2-2

 2-2      Summary of Sample Trains Temperature and Con-
            figuration During DCOG Underfiring Testing      2-4

 2-3      Comparison of Sample Train 5 Component Tem-
            peratures During Standard Method 5 Sample
            Collection                                      2-7

 2-4      Summary of Results for NCOG Test Series  (mg)      2-10

 2-5      Summary of Results for DCOG Test Series  (mg)      2-11

 2-6      NCOG Underfiring Condition, Run No. 1 Test
            Results  (10/27/81)                              2-12

 2-7      NCOG Underfiring Condition, Run No. 2 Test
            Results  (10/27/81)                              2-13

 2-8      NCOG Underfiring Condition, Run No. 3 Test
            Results  (10/28/81)                              2-14

 2-9      NCOG Underfiring Condition, Run No. 4 Test
            Results  (10/28/81)                              2-15

 2-10     NCOG Underfiring Condition, Run No. 5 Test
            Results  (10/29/81)                              2-16

 2-11     NCOG Underfiring Condition, Run No. 6 Test
            Results  (10/29/81)                              2-17

 2-12     NCOG Underfiring Condition, Run No. 7 Test
            Results  (10/30/81)                              2-18

 2-13     NCOG Underfiring Condition, Run No. 8 Test
            Results  (10/30/81)                              2-18
                               VI

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                       TABLES  (continued)

Number                                                      Page

 2-14     DCOG Underfiring Condition, Run No. Dl Test
            Results  (12/8/81)                               2-19

 2-15     DCOG Underfiring Condition, Run No. D2 Test
            Results  (12/10/81)                              2-20

 2-16     DCOG Underfiring Condition, Run No. D3 Test
            Results  (12/11/81)                              2-21

 2-17     DCOG Underfiring Condition, Run No. D4 Test
            Results  (12/12/81)                              2-22

 2-18     DCOG Underfiring Condition, Run No. D5 Test
            Results  (12/12/81)                              2-23

 2-19     DCOG Underfiring Condition, Run No. D6 Test
            Results  (12/13/81)                              2-24

 2-20     MCOG Underfiring Condition, Trains 1 and 2 of
            Quad Train [121°C  (250°F) Front Half]           2-29

 2-21     NCOG Underfiring Condition, Trains 3 and 4 of
            Quad Train [121°C  (250°F) and 204°C  (400°F)
            Front Half]                                     2-30

 2-22     NCOG Underfiring Condition, Train 5  [121°C
            (250°F) Front Half]                             2-31

 2-23     NCOG Underfiring Condition, Train 6  [316°C
            (600°F) Front Half]                             2-34

 2-24     DCOG Underfiring Condition, Trains 1 and 2 of
            Quad Train [121°C  (250°F) Front Half]           2-35

 2-25     DCOG Underfiring Condition, Trains 3 and 4 of
            Quad Train [177°C  (350°F) and 204°C  (400°F)
            Front Half]                                     2-36

 2-26     DCOG Underfiring Condition, Train 5  (121°C
            (250°F) Front Half]                             2-37

 2-27     DCOG Underfiring Condition, Train 6  [316°C
            (600°F) Front Half]                             2-40

 2-28     Results of Sequential Heating of Selected NCOG
            Underfiring Test Series  Samples                 2-42
                                vn

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                       TABLES (continued)

Number                                                      Page

 2-29     Results of Sequential Heating of Selected DCOG
            Underfiring Test Series Samples                 2-43

 2-30     Results of Sequential Heating of Selected NCOG
            Underfiring Test Series Run 8.5, Front Half     2-44

 2-31     Comparison of Particulate Concentrations Deter-
            mined from Sampling at Two Different Tempera-
            tures Under NCOG Underfiring Conditions:  177°C
            (350°F) vs. 121°C (250°F) but Analyzing After
            Treatment at 177°C (350°F)                      2-47

 2-32     Comparison of Particulate Concentrations Deter-
            mined from Sampling at Two Different Tempera-
            tures Under NCOG Underfiring Conditions:  204°C
            (400°F) vs. 121°C (250°F) but Analyzing After
            Treatment at 204°C (400°F)                      2-48

 2-33     Comparison of Particulate Concentrations Deter-
            mined from Sampling at Two Different Tempera-
            tures Under NCOG Underfiring Conditions:  316°C
            (600°F) vs. 121°C (250°F) but Analyzing After
            Treatment at 315°C (600°F)                      2-49

 2-34     Comparison of Particulate Concentrations Deter-
            mined from Sampling at Two Different Tempera-
            tures Under DCOG Underfiring Conditions:  177°C
            (350°F) vs. 121°C (250°F) but Analyzing After
            Treatment at 177°C (350°F)                      2-50

 2-35     Comparison of Particulate Concentrations Deter-
            mined from Sampling at Two Different Tempera-
            tures Under DCOG Underfiring Conditions:  204°C
            (400°F) vs. 121°C (250°F) but Analyzing After
            Treatment at 204°C (350°F)                      2-51

 2-36     Comparison of Particulate Concentration Deter-
            mined from Sampling at Two Different Tempera-
            tures Under DCOG Underfiring Conditions:  316°C
            (600°F) vs. 121°C (250°F) but Analyzing After
            Treatment at 316°C (600°F)                      2-52

 2-37     Summary of Particulate and Acid Sulfate Results
            for the NCOG Underfiring Test Series            2-54

 2-38     Summary of Particulate and Acid Sulfate Results
            for the DCOG Underfiring Test Series            2-55
                                Vlll

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                       TABLES (continued)

Number                                                      Page

 2-39     Summary of Results Obtained Through Method 15
            Analysis of SRU Inlet COG                       2-65

 2-40     Summary of Results Obtained Through Method 15
            Analysis of SRU Outlet COG During DCOG
            Underfiring                                     2-66

 2-41     Summary of Results Obtained Through Method 15
            Analysis of No. 1 Coke Battery Exit Stack Gas   2-67

 2-42     Summary of Flue Gas Conditions During NCOG
            Underfiring Testing                             2-72

 2-43     Summary of Flue Gas Conditions During DCOG
            Underfiring Testing                             2-75

 2-44     Summary of Flue Gas Flow Rate and Temperature
            as Measured by a Full Velocity Traverse         2-77

 2-45     Summary of Visible Emissions Data No. 1 Coke
            Battery Exit Stack,  NCOG Underfiring Test
            Series                                          2-80

 2-46     NCOG Test Series Process Data                     2-84

 2-47     DCOG Test Series Process Data                     2-85

 2-48     Sulfur Content of Coal and Coke During NCOG
            Tests (Percent)                                 2-86

 2-49     Sulfur Content of Coal and Coke During DCOG
            Tests (Percent)                                 2-86

 4-1      NCOG Underfiring Test Series, October 26-30,
            1981, Revised Sampling Schedule                 4-5

 4-2      DCOG Underfiring Test Series, December 7-13,
            1981, Revised Sampling Schedule                 4-6

 4-3      NCOG and DCOG Underfiring Test Series Analyti-
            cal Schedule                                    4-7

 5-1      Field Equipment Calibration, Quad Train No. 1
            (NCOG)                                          5~2

 5-2      Field Equipment Calibration, Quad Train  No. 2
            (NCOG)                                          5-3
                                IX

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                       TABLES (continued)

Number                                                      Page

 5-3      Field Equipment Calibration, Quad Train No. 3
             (NCOG)                                          5-4

 5-4      Field Equipment Calibration, Quad Train No. 4
             (NCOG)                                          5-5

 5-5      Field Equipment Calibration, Quad Train No. 5
             (NCOG)                                          5-6

 5-6      Field Equipment Calibration, Quad Train No. 6
             (NCOG)                                          5-7

 5-7      Field Equipment Calibration, Quad Train No. 1
             (DCOG)                                          5-8

 5-8      Field Equipment Calibration, Quad Train No. 2
             (DCOG)                                          5-9

 5-9      Field Equipment Calibration, Quad Train No. 3
             (DCOG)                                          5-10

 5-10     Field Equipment Calibration, Quad Train No. 4
             (DCOG)                                          5-11

 5-11     Field Equipment Calibration, Quad Train No. 5
             (DCOG)                                          5-12

 5-12     Field Equipment Calibration, Quad Train No. 6
             (DCOG)                                          5-13

 5-13     Field and Reagent Blank Analysis, NCOG Test
            Series                                          5-14

 5-14     Field and Reagent Blank Analysis, DCOG Test
            Series                                          5-15

 5-15     Summary of Results Obtained Through Method 15
            Analysis of Audit Gases                         5-17
                               x

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                        QA ELEMENT FINDER
     Item

Project Description

Project Organization and
  Responsibility

QA Objectives

Sampling Procedures

Sample Custody

Calibration Procedures

Analytical. Procedures

Data Validation, Reduction,
  and Reporting

Internal QA Checks

Performance Systems Audits

Preventive Maintenance Schedule

Corrective Action

Quality Assurance Reports to
  Management
     Page

     1-1


Appendix G

Appendix F, 5-1

Appendix D, 4-1

Appendix B and C

Appendix E

Appendix D, 4-1


Appendix F

Appendix F

Appendix F

Appendix F

Appendix F


Appendix F
                               XI

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                            SECTION 1



                          INTRODUCTION






     During the weeks of October 26, 1981, and December 7, 1981,



PEDCo Environmental personnel conducted emission sampling pro-



grams at Republic Steel Corporation's Cleveland, Ohio, facility.



     The primary objective of the field tests was to obtain data



on battery stack particulate emissions using several modifica-



tions of EPA Method 5.  The modifications included front half



sampling train temperatures of 177°C (350°F), 204°C (400°F), and



316°C (600°F), post-test heating of samples and wet chemistry



analysis for sulfates.  The data will be used, with other infor-



mation, to formulate a test method to measure total non-sulfate



particulate matter emissions from batteries underfiring non-



desulfurized coke oven gas (NCOG) and desulfurized coke oven gas



(DCOG); and, to determine the effect of underfiring NCOG and DCOG



on particulate emissions.  The secondary objective of the field



tests was to measure the concentrations and types of reduced



sulfur compounds in the fuel gas before and after the Sulfiban



desulfurizer.  Data on reduced sulfur compounds will be used,



along with other information, to determine the impact of desul-



furizers on sulfur compound emissions from coke ovens.
                              1-1

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     The purpose of this test report is to describe the measure-

ment mode, document the results obtained, and discuss the pos-

sible relationships between the data and process or sampling

conditions.

     Republic's Cleveland plant was selected as the test site for

the following reasons:

     1.   A pad up rebuilt of the battery was completed in 1977.

     2.   The plant uses no add-on pollution control devices at
          the coke battery exhaust.

     3.   Earlier test data indicate that it is representative of
          a well controlled facility.

     4.   The two test series could be conducted close enough in
          time so as to reduce the effects of changes in condi-
          tion of the battery on emissions.

     Comprehensive testing was conducted at two sources:

     0    The Coke Battery No. 1 exhaust

     0    The Sulfiban sulfur removal unit (SRU)

     At the final exit stack serving Coke Battery No. 1, particu-

late, sulfur dioxide, and sulfuric acid mist concentrations were

measured by EPA Methods 5 and 8* modified into a quad sampling

train arrangement and two single sampling trains.  A test run

consisted of the operation of the quad train and two single

sampling trains.  Sampling and analytical parameters were varied

between runs.  Flue gas flow rates, temperature, moisture con-

tent, and composition [oxygen (CO and carbon dioxide (CO-)] were

measured in conjunction with the particulate test runs.
*
 40 CFR 60,, Appendix A, Reference Methods 1 through 5 and 8,
 July 1, 1981.


                              1-2

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     Flue gas samples were collected at the inlet and outlet
(during DCOG testing only) of the Sulfiban desulfurization unit
for determination of hydrogen sulfide (H_S), carbonyl sulfide
(COS),  carbon disulfide (CS2), and SO- concentrations.  Gas
chromatographic  (GC) separation and flame photometric detection
(FPD) by EPA Method 15* were used.
     Visible emissions were observed at Coke Battery No. 1 exit
stack during particulate tests according to EPA Method 9.**
     Midwest Research Institute (MRI) monitored process opera-
tions during both test series.  Mr. Yogesh Doshi monitored the
NCOG test series, and Mr.  Barry Gold monitored the DCOG test
series.  Mr. Frank Clay, EPA Task Manager, observed the NCOG test
series, and Mr. Terry Harrison of EPA who represented Mr. Clay,
observed the DCOG test series.
  40 CFR 60, Appendix A, Reference Method 15, July 1, 1981.
  40 CFR 60, Appendix A, Reference Method 9, July 1, 1981.
                               1-3

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                            SECTION 2



                       SUMMARY OF RESULTS






     This section presents the results from the normal coke oven



gas (NCOG) and desulfurized coke oven gas (DCOG) test series.



The NCOG test series was conducted during the week of October 26,



1981,  and the DCOG test series during the week of December 7,



1981.   The delay between the two test series was necessary to



allow the sulfur recovery unit (SRU) to stabilize after start-up.






2.1  PARTICULATE SAMPLING PROTOCOL



     Tables 2-1 and 2-2 summarize sampling trains, configura-



tions, metered volumes, and component temperatures for the NCOG



and DCOG underfiring test series, respectively.  Sampling Trains



1 through 4 comprised the quad train.  Sampling Train 5 was the



standard Method 5 train, and Sampling Train 6 was equipped for



316°C (600°F) probe and filter heat.  Back-half train configura-



tions and filter/probe temperatures varied between sample runs.



The sample identifications listed in Tables 2-1 and 2-2 gives the



sample train number (1 through 6), back-half configuration



(Method 8 or Method 5), and front-half probe/filter temperature




(°F).



     Probe and filter temperatures were measured by thermocouples



that contacted a well that had been blown into the glass probe






                                2-1

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                          TABLE 2-1 .   SUMMARY OF SAMPLE  TRAINS TEMPERATURE AND CONFIGURATION

                                            DURING NCOG  UNDERFIRING TESTING


Run


1
i




o
c.










4
*T


(contini

Sampl e
identification
1-M8-250
2-M8-250
3-M8-350
4-M8-350
5-M5-250
6-M8-600
1-M8-250
2-M8-250
3-M8-400
4-M8-400
5-M5-250
6-M8-600
1-M8-250
2-M8-250
3-M8-350
4-M8-350
5-M5-250
6-M8-600
1-M8-250
2-M8-250
3-M8-400
4-M8-400
5-M5-250
6-M8-600
jed)

Date
(1981)
10/27





10/27





10/28





10/28






Metered9
vol ume
Nntf
1.76
1.67
1.68
1.64
1.44
1.42
1.59
1.50
1.46
1.44
1.50
1.65
1.75
1.66
1.63
1.58
1.72
1.84
0.99
0.88
0.93
0.85
2.18
1.11

dscf
62.21
58.98
59.28
57.95
50.97
49.99
56.00
52.91
51.50
50.79
52.92
58.42
61.88
58.55
57.66
55.81
60.90
64.99
34.78
30.89
32.97
30.05
76.86
39.14

Stack
temperature
°C
280
281
280
281
288
288
279
284
279
283
259
259
279
282
280
282
270
270
275
277
274
276
270
270

°F
537
538
536
538
550
550
535
543
534
542
499
499
535
540
536
540
518
518
527
531
525
529
518
518

Average probe
temperature
°C
126
126
211
239
123
334
124
122
203
210
114
332
125
129
186
191
109
334
127
125
248
138
112
336

°F
258
259
411
462
253
634
255
252
398
410
238
630
258
263
366
376
229
633
261
257
479
280
233
638

Average filter
temperature
°C
122
125
170
169
128
320
119
128
198
207
125
316
113
127
178
169
109
293
123
130
177
169
130
328

°F
252
257
338
336
263
608
247
263
389
404
257
600
236
260
353
336
229
560
254
266
350
337
266
622

to
I
to

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   TABLE 2-1  (continued)
Run
5
6
7
8
Samp! e
identification
1-M8-250
2-M5-250
3-M8-350
4-M5-350
5-M5-250
6-M8-600
1-M8-250
2-M5-250
3-M8-400
4-M5-400
5-M5-250
6-M8-600
1-M8-250
2-M5-250
3-M8-350
4-M5-350
5-M5-400
6-M8-600
1-M8-350
2-M5-350
3-M8-400
4-M5-400
5-M8-250
6-M8-600
Date
(1981)
10/29
10/29
10/30
10/30
Metered
vol ume
Nm3
1.64
1.50
1.53
1.43
1.61
1.54
1.64
1.54
1.52
1.29
1.65
1.58
1.73
1.66
1.48
1.57
1.66
1.60
1.58
1.54
1.70
1.60
1.42
1.18
dscf
58.03
52.83
53.84
50.61
56.68
54.48
57.98
54.33
53.74
45.69
58.23
55.90
60.90
58.55
52.35
55.56
58.63
56.60
55.91
54.36
59.96
56.55
50.29
41.72
Stack
temperature
°C
274
276
276
275
271
271
274
277
277
278
271
271
277
280
277
280
271
271
285
283
285
286
271
271
°F
524
529
529
527
520
520
526
530
530
532
520
520
530
537
530"
536
520
520
545
542
545
547
520
520
Average probe
temperature
°C
124
127
184
178
129
325
127
121
203
196
118
328
122
130
131
169
208
329
182
184
208
214
128
326
°F
255
260
363
353
265
617
261
250
398
385
245
622
251
266
269
336
407
624
360
364
407
417
263
619
Average filter
temperature
°C
124
123
176
186
116
324
119
126
193
208
119
302
122
126
181
178
196
308
167
169
198
201
131
313
°F
255
254
349
366
240
616
246
258
379
407
246
576
252
258
358
353
385
587
332
336
388
393
268
596
to
I
CO
                                                  *
    Metered volume in dry normal cubic meters (dNm ) and dry standard cubic feet  (dscf)

    tions = 20°C and 760 mmHg (68°F and 29.92 in.Hg) and zero percent moisture.
Standard condi-

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                    TABLE 2-2.   SUMMARY  OF  SAMPLE TRAINS TEMPERATURE AND CONFIGURATION
                                      DURING  DCOG UNDERFIRING TESTING
Run
Dl
D2
D3
D4

Sampl e
identification
1-M8-250
2-M8-250
3-M8-350
4-M8-350h
5-M5-2500
6-M8-600
1-M8-250
2-M8-250
3-M8-350
4-M8-350
5-M5-250
6-M8-600
1-M8-250
2-M8-250
3-M8-400
4-M8-400
5-M5-250
6-M8-600
1-M8-250
2-M8-250
3-M8-400.
4-M8-400P
5-M5-250
6-M8-600

Date
(1981)
12/8
12/10
12/11
12/12

Metered3
vol ume
Nm3
1.25
1.23
1.16
1.12
0.96
1.40
1.78
1.71
1.79
1.84
1.68
1.48
1.62
1.40
1.44
1.79
1.72
1 1.69
1.69
1.49
1.75
1.67

dscf
44.11
39.67
40.99
39.61
34.02
49.40
62.68
60.47
63.26
64.79
59.35
52.29
57.25
49.32
51.01
63.10
60.82
59.82
59.79
52.50
61.80
58.85

Stack
temperature
°C
242
242
242
243
252
253
252
252
252
252
252
252
252
252
249
252
252
254
254
256
254
254

°F
468
468
468
470
485
487
486
486
486
486
486
486
486
486
480
486
486
490
490
492
490
490

Average probe
temperature
°C
129
124
178
175
265
238
237
186
173
129
320
127
125
214
218
124
325
113
123
207
134
302

°F
264
255
352
348
508
460
458
366
343
263
608
261
258
417
425
255
616
236
253
404
273
576

Average filter
temperature
°C
119
133
190
167
268
118
109
184
197
126
298
120
132
211
204
123
280
148
126
209
128
325

°F
246
272
374
333
515
244
229
363
387
258
569
248
270
411
400
254
536
299
259
409
263
617

(continued)

-------
     TABLE 2-2 (continued)
Run
D5
D6
Sam pi e
identification
1-M8-250
2-M5-250
3-M8-350
4-M5-350
5-M5-250
6-M8-600
1-M8-250
2-M5-250
3-M8-400
4-M5-400
5-M5-250
6-M8-600
Date
(1981)
12/12
12/13
Metered
vol ume
Nm3
1.74
1.74
1.56
1.60
1.69
1.62
1.56
1.56
1.45
1.49
1.83
1.45
scf
61.31
61.44
55.07
56.59
59.67
57.09
54.92
54.96
51.23
52.62
64.63
51.10
Stack
temperature
°C
244
244
244
244
244
244
235
236
235
232
235
235
°F
471
471
471
471
471
471
455
457
455
449
455
455
Average probe
temperature
°C
120
123
177
178
132
327
121
127
211
204
125
324
°F
248
254
350
352
269
621
251
261
412
399
258
616
Average filter
temperature
°C
123
127
181
177
122
316
132
120
204
219
131
319
°F
253
261
357
351
251
600
270
248
399
427
267
607
to
I
1/1
      Metered volume in dry normal cubic meters (dNm ) and dry standard cubic feet (dscf)
      tions = 20°C and 760 mmHg (68°F and 29.92 in.Hg) and zero percent moisture.

     DTest voided because of excessive post-test leak rate.
Standard condi-

-------
and the back-half of the glass filter holder.  During a typical



EPA Method 5 test*, the filter box temperature is the only param-



eter monitored to control front-half heat.  Table 2-3 summarizes



the sampling train component temperatures that were recorded



during all tests for Sampling Train 5.  In this case, the stack



temperature was high 232° to 288°C (450° to 550°F), and the



sample gas stream temperature was reduced to the desired filter-



ing temperature.  The filter box temperature and the actual



filter temperature compared closely.



     Sampling was conducted isokinetically by regulating the



sample flow rate relative to the flue gas flow rate as measured



by the pitot tube attached to the probe assembly.  Except for



Train 6 during NCOG underfiring, sampling trains were operated at



100 ^flO percent isokinetic.  An oversized quartz glass nozzle and



a higher than expected grain loading prevented proper isokinetics



from being maintained throughout the entire scheduled sample run



on Train 6.  During NCOG underfiring, Train 6 sampling rate



averaged 47 percent isokinetic.  The oversized nozzle problem was



rectified for the DCOG underfiring test series.



     Whatman Reeve Angel 934 AH glass fiber filters were used in



all sampling trains except Train 6, in which a quartz glass



filter was used.  Filters were chosen for their proven tare



weight stability when subjected to the heat treatments in the



analytical procedures.  Appendix H details a study conducted by



PEDCo to assess the effect of heat treatment on various filter
 40 CFR 60, Appendix A, Reference Method 5, July 1, 1981.




                               2-6

-------
      TABLE 2-3.  COMPARISON OF SAMPLE TRAIN 5 COMPONENT TEMPERATURES
                DURING STANDARD METHOD 5 SAMPLE COLLECTION
Test No.
1.5
2.5
3.5
4.5
5.5
6.5
8.5
D2.5
D3.5
D4.5
D5.5
D6.5
Average temperature, °C (°F)
Probe
123 (253)
114 (238)
109 (229)
112 (233)
129 (265)
118 (245)
128 (263)
129 (263)
124 (255)
134 (273)
132 (269)
125 (258)
Filter
128 (263)
125 (257)
109 (229)
130 (266)
116 (240)
119 (246)
131 (268)
126 (258)
123 (254)
128 (263)
122 (251)
131 (267)
Box
124 (256)
97 (207)
128 (263)
132 (270)
136 (277)
132 (270)
130 (267)
132 (270)
129 (264)
133 (271)
129 (264)
135 (275)
Stack
288 (550)
259 (499)
270 (518)
270 (518)
271 (520)
271 (520)
271 (520)
252 (486)
252 (486)
254 (490)
244 (471)
235 (455)
aTrain 7.5 operated at a higher temperature.  Train D1.5 was a voided run.

Note:   Probe, filter,  and stack temperature measured  by thermocouple
       indicator.   Box temperature measured by dial thermometer.
                                    2-7

-------
tare weights.  The Whatman Reeve Angel 934 AH proved to be one of



the most stable.  As a matter of routine, all filters used in



this test program were heated at 316°C (600°F) prior to initial



tare weighing.
                               2-8

-------
2.2  SUMMARY OF PARTICULATE AND RELATED ANALYSES RESULTS



     Tables 2-4 and 2-5 present the results obtained through



analysis of samples collected during the NCOG and DCOG test



series.  All results are reported as milligrams (ing) .   The ana-



lytical scheme used is presented in Section 4 and is discussed in



detail in Appendix D.  Appendix C presents actual laboratory



data.



     In addition to the particulate analysis, acetone rinse



residues and filters were analyzed for isopropanol soluble sul-



fate (acid sulfate) and water soluble sulfate (inorganic sul-



fate).   Selected filters also were analyzed for total organic



carbon (TOO.   Because the quantity of TOC proved to be negligi-



ble, the data were not included on the summary tables (refer to



Section 2.5.1 of this report for more information).



     Back half solutions were analyzed for sulfuric acid mist and



sulfur dioxide by EPA Method 8 or inorganic and organic content



by ether/chloroform extraction and total organic carbon ampule



techniques depending on the back-half configuration.



     Tables 2-6 through 2-13 present the analytical results for



each sampling train within a test run for NCOG underfiring, and



Tables 2-14 through 2-19 for DCOG underfiring.  Analytical



results are reported in mg, milligrams per cubic meter  (mg/m ),



and grains per dry standard cubic foot (gr/dscf).  These tables



also present details on desired front-half temperature, on



average filter temperature, and on whether sequential heating of



the front-half samples was performed prior to sulfate analysis.
                               2-9

-------
                                TABLE 2-4.   SUMMARY OF RESULTS FOR  NCOG TEST SERIES (mg)
Run
No.
1.1
.2
.3
.4
.5
.6
2.1
2.2
2.3
2.4
2.5
2.6
3.1
3.2
3.3
3.4
3.5
3.6
4.1
4.2
4.3
4.4
4.5
4.6
5.1
5.2
5.3
5.4
5.5
5.6
6.1
6.2
6.3
6.4
6.5
6.6
7.1
7.2
7.3
7.4
7.5
7.6
8.1
8.2
8.3
8.4
8.5*
8.6
Filterable participates under various conditions (front-half results)
Ambient
temperature
Rinse
101.6
93.9
4 1.5
27.1
82.3
12.1
79.3
81.1
33.4
49.0
62.8
23.3
104.5
62.6
66.6
20.4
74.5
18.9
64.3
55.7
30.0
48.7
59.8
16.3
82.0
101.4
31.4
15.4
117.8
10.2
102.9
100.2
18.9
12.6
108.1
19.9
123.4
117.3
48.2
42.4
24.4
14.4
19.9
32.2
18.6
13.5
85.4
11.0
Filter
125.3
98.9
31.4
23.5
53.0
14.9
103.8
68.1
12.9
12.3
28.1
16.2
97.5
94.3
20.7
19.9
96.7
17.1
75.6
57.5
31.1
29.7
114.7
53.4
56.6
84.2
19.1
16.7
103.2
14.7
81.2
50.6
15.4
14.3
87.6
11.0
72.4
69.8
16.6
20.2
15.8
9.9
45.4
43.8
47.5
47.0
98.5
34.1
2-h at 350° F
Rinse
32.2
26.1
18.4
14.9
10.6
34.8
18.6
27.6
28.6


Filter
23.0
21.4
15.6
19.3
18.4
102.5
18.2
22.8
13.7


4-h at 350°F
Rinse
21.6
15.5
8.6
29.8
24.7
25.9


Filter
20.1
15.2
18.2
99.0
19.5
11.7


2-h at 400°F
Rinse
17.8
9.1
14.4
8.4
12.7
22.4
17.9
10.8
21.9


Filter
19.5
15.7
14.8
17.8
29.0
90.0
18.3
13.4
11.3


4-h at 400°F
Rinse
15.6
13.3
7.8
16.8
14.7
'19.8


Filter
18.9
14.4
17.4
87.9
17.6
10.5


2-h at 600°F
Rinse
12.5
10.3
5.6
14.0
10.9
16.5


Filter
18.0
12.2
16.4
85.0
16.8
9.3


IPA rinse
(H2S04)
Rinse
38.2
7.4
9.8
2.1
0.0
0.0
35.1
0.0
12.2
14.4
0.0
2.6
40.5
0.0
24.1
3.7
0.0
4.2
23.0
0.4
6.4
10.0
0.0
0.0
65.5
3.0
9.5
0.0
0.0
0.0
47.6
0.0
2.8
0.0
0.0
0.0


Filter
43.3
0.0
0 0
z'.l
0.0
0.0
26.5
0.0
0.0
0.0
0.0
0.0
29.9
0.0
1.2
0.0
0.0
0.0
24.5
0.0
0.0
2.6
0.0
0.0
20.1
0.0
0.0
0.0
0.0
0.0
23.4
0.0
0.0
0.0
0.0
0.0


H?0 rinse
Rinse
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0


Filter
0
0
n
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0 .
0


Back-half results
S02
1960
1850
1S7Q
1810
1120
1370
1720
1700
1610
1940
1790
1540
1680
1620
1720
1300
1170
1250
1160
1550
2070
1970
2050
2000
1900
2010


H2S04
8.89
9.43
65.4
56.0
606
741
16.0
53.0
19.6
15.7
8.3
8.6
67.2
89.2
164
11.5
11.9
29.8
10.4
73.7
34.4
81.5
129
24.0
97.6
115


Ether chloroform
Inorganic
28.2
68.2
99.1
65.7
19.0
101.2
20.9
109.7
118.3
20.0


Organic
2.6
4.8
3.2
3.1
4.2
3.2
6.3
4.0
5.9
6.4


TOC
23.4
44.3
77.3
14.3
58.1
49. Z
11.8
42.3
15.4
15.2


rO.

M
O
        Special sequential analysis performed.

-------
                                       TABLE 2-5.   SUMMARY OF  RESULTS  FOR DCOG TEST  SERIES  (mg)
Run
No.
01.1
01.2
01.3
01.4,
01. 5a
01.6
02.1
02.2
02.3
02.4
02.5
02.6
03.1
03.2
03.3
03. 4
03.5
03.6
04. 1
04.2
04.3
04.4*
04.5
04.6
05.1
05.2
05.3
05.4
05. 5
05.6
06.1
06.2
06.3
06.4
06.5
06.6
Filterable participates under various conditions (front-half results)
Ambient
temperature
Rinse
18.0
22.2
17.2
23.6
15.2
242. 8b
25.1
21.0
25.9
24.4
14.7
26.8
19.4
18.3
27.4
18.9
16.7
18.3
36.9
16.4
19.6
12.2
17.8
14.8
11.0
15.1
9.5
7.9
7.2
14.2
10.8
8.0
12.6
6.8
Filter
14.6
15.2
16.8
19.7
12.1
7.2
13.2
13.8
11.3
16.7
15.6
11.8
15.1
12.6
11.3
16.1
8.8
10.2
8.3
8.4
11.6
5.3
5.5
5.2
5.3
4.0
6.4
5.0
5.0
6.9
4.8
4.0
7.3
2.4
2-h at 350=F
Rinse
8.4
7.5
12.5
11.0
7.3
13.4
5.6
2.6
8.4
Filter
13.4
14.5
12.1
12.4
14.9
8.3
3.1
4.3
5.2
q-n ai JDUT
Rinse
7.9
9.3
6.0
13.1
2.5
7.8
Filter
13.2
9.9
13.9
7.1
2.8
5.0
-n a i HW r
Rinse
5.4
8.9
6.3
5.3
8.1
7.6
2.5
1.7
6.5
Filter
11.4
9.9
11.8
10.4
5.4
7.5
2.0
3.7
5.0
H-II OL HUU r
Rinse
5.4
8.0
5.3
7.6
2.5
6.5
Filter
11.0
9.7
10.4
7.3
2.0
4.8
2-h st SCC°F
Rinse
3.8
6.2
4.2
6.0
1.4
1.0
Filter
10.8
8.9
9.2
6.3
1.0
3.4
IPA rinse
(H?SOi)
Rinse
0.0
1.0
0.0
0.0
0.0
1.0
1.3
0.6
0.4
0.0
0.0
0.3
0.1
0.0
1.9
0.0
0.0
0.0
0.0
0.7
0.0
0.0
3.4
0.6
2.2
0.6
0.0
0.3
0.0
0.0
1.0
0.0
0.0
0.2
Filter
0.0
1.0
0.0
0.0
0.0
0.0
1.3
0.0
0.0
0.0
<0.3
0.0
1.7
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.2
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
HZ0 rinse
Rinse
0.0
2.1
2.5
0.0
1.6
0.9
2.0
3.5
4.8
0.0
0.0
6.0
0.0
4.1
0.8
0.9
2.2
0.0
0.9
3.2
0.0
0.0
3.7
1.7
1.6
3.8
0.0
1.4
0.0
0.0
0.0
0.0
0.0
0.0
Filter
<0.3
Void
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
<0.3
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Back-half results
S02
69.7
116.1
117.0
115.8
97.9
120.8
159.4
155.0
131.8
152.8
90.1
152.8
130.8
143.4
169.1
135.6
130.5
118.3
90.1
131.8
123.6
129.0
118.3
113.3
110.1
H2S04
115
3.5
9.3
9.2
6.3
13.7
14.4
8.7
54.8
10.7
84.0
7.0
12.0
8.2
12.8
42.3
15.9
6.7
74.7
8.8
7.8
8.2
13.2
r
7.5
11.4
rthar- rtilnmfnm
Inorganic
_
152.6
28.9
84.5
74.5
158.1
15.6
55.2
144.2
10.0
Organic
_
0.8
2.0
2.9
0.7
4.0
1.4
2.4
2.8
2.4
TOC
—
8.6
3.4
8.5
202
572
3.6
403
77
8.0
to
I
         Test run voided.

         bContam1nated with oil.

-------
     TABLE  2-6.   NCOG UNDERFIRING CONDITION,  RUN NO. 1
                   TEST RESULTS (10/27/81)


Desired front-half tem-
perature. °C (CF)
Actual average filter
temperature, °C (°F)
Sequential heating,
°C (°F)
Front-half catch
Particulate (ambient)
mg ,
mq/m
gr/dscf
Acid soluble sulfate
as [H2S04]
mg ,
mg/m
gr/dscf
as [H2S04(H20)2]
mg ,
mg/m
gr/dscf
Back-half catch
Su'lfuric acid mist
mg ,
mg/m
gr/dscf
ppm
Sulfur dioxide
mg 3
mg/m
gr/dscf
ppm
Inorganic condensibles
mg 3
mg/m
gr/dscf
Organic condensibles
mg 3
mg/m
gr/dscf
Total organic carbon
mg 3
mg/m
gr/dscf

1.1
121
(250)
122
(252)


226.9
128.9
0.056
81.5
46.3
0.020
111.4
63.3
0.028

8.9
5.0
0.002
1
1960
1114
0.486
419




1.2
121
(250
125
(257)
177
(350)

192.8
115.4
0.050
7.4
4.4
0.002
10.1
6.1
0.003

9.4
5.6
0.002
1
1850
1108
0.484
416



Test
1.3
177
(350)
170
(338)


72.9
43.4
0.019
9.8
5.8
0.002
13.4
8.0
0.003

65.4
38.9
0.017
10
1870
1113
0.487
418



No.
1.4
177
(350)
169
(336)


50.6
30.8
0.013
4.7
2.9
0.001
6.4
3.9
0.002

56.0
34.1
0.015
8
1810
1104
0.482
415




1.5
121
(250)
128
(263)
316
(600)

135.3
94.0
0.041
0.0
0.0
0.000
0.0
0.0
0.000



28.2
19.6
0.008
2.6
1.8
0.001
23.4
16.2
0.007

1.6
316
(600)
320
(608)


27.0
19.0
0.008
0.0
0.0
0.000
0.0
0.0
0.000

606a
426.8
0.187
105
1120
789
0.346
296



'Hydrogen peroxide contaminated.
                              2-12

-------
      TABLE  2-7.   NCOG UNDERFIRING CONDITION, RUN NO. 2
                    TEST RESULTS  (10/27/81)

Desired front-half tem-
perature, °C (°F)
Actual average filter
temperature, °C (°F)
Sequential heating,
°C (°F)
Front-half catch
Particulate (ambient)
mg 3
mg/m
gr/dscf
Acid soluble sulfate
as [H2S04]
M9 3
mg/m
gr/dscf
as [H2S04 (H20)2]
ir.g 3
irg/m
gr/dscf
Back-half catch
Sulfuric acid mist
mg 3
nig/m
gr/dscf
ppm
Sulfur dioxide
mg 3
mg/m
cir/dscf
ppm
Inorganic condensibles
nig .
ng/m
gr/dscf
Organic condensibles
mg 3
rng/m
ijr/dscf
Totil organic carbon
mg 3
mg/m
ijr/dscf
Test No.
2.1
121
(250)
119
(247)

183.1
115.2
0.050
61.6
38.7
0.017
84.2
53.0
0.023
741a
466
0.204
114
1370
862
0.377
324



2.2
121
(250)
128
(263)
204
(400)
149.2
99.5
0.044
0.0
0.0
0.000
0.0
0.0
0.000
16.0
10.7
0.005
3
1720
1147
0.502
431



2.3
204
(400)
198
(389)

46.3
31.7
0.014
12.2
8.3
0.004
16.7
11.4
0.005
53.0
36.3
0.016
9
1700
1164
0.509
438



2.4
204
(400)
207
(404)

61.3
42.6
0.019
14.4
10.0
0.004
19.7
13.7
0.006
19.6
13.6
0.006
3
1610
1118
0.489
420



2.5
121
(250)
125
(257)
316
(600)
90.9
60.6
0.026
0.0
0.0
0.000
0.0
0.0
0.000


68.2
45.5
0.020
4.8
3.2
0.001
44.3
29.5
0.013
2.6
316
(600)
316
(600)

39.5
23.9
0.010
2.6
1.6
0.001
3.5
2.1
0.001
157
95.7
0.041
23
1940
1176
0.512
442



aHydnogen peroxide contaminated.
                              2-13

-------
TABLE 2-8.   NCOG UNDERFIRING  CONDITION, RUN NO. 3
             TEST RESULTS (10/28/81)

Desired front-half tem-
perature, "C (CF)
Actual average filter
temperature. "C (°F)
Sequential heating,
°C (°F)
Front-half catch
Paniculate (ambient)
mg ,
mg/m
gr/dscf
Acid soluble sulfate
as [H.SO.]
ng 3
rng/m
gr/dscf
as [H2S04(H20)2]
ing ,
mg/m
gr/dscf
Back-half catch
Sulfuric acid mist
mg -
mg/m
gr/dscf
ppm
Sulfur dioxide
mg -
mg/m
gr/dscf
ppm
Inorganic condensibles
mg ,
mg/m
gr/dscf
Organic condensibles
mg ,
mg/irr
gr/dscf
Total organic carbon
mg ,
mg/m
gr/dscf
Test No.
3.1
121
(250)
113
(236)

202.0
115.4
0.050
70.4
40.2
0.017
96.2
55.0
0.024
8.3
4.7
0.002
1
1790
1023
0.446
384



3.2
121
(250)
127
(260)
177
(350)
156.9
94.5
0.041
0.0
0.0
0.000
0.0
0.0
0.000
8.6
5.2
0.002
1
1540
928
0.406
349



3.3
177
(350)
178
(353)

87.3
53.6
0.023
25.3
15.5
0.007
34.6
21.2
0.009
67.2
41.2
0.018
10
1680
1031
0.450
387



3.4
177
(350)
169
(336)

40.3
25.5
0.011
3.7
2.3
0.001
5.0
3.2
0.001
89.2
56.4
0.025
14
1620
1025
0.448
385



3.5
121
(250)
109
(229)
316
(600)
171.2
99.5
0.043
0.0
0.0
0.000
0.0
0.0
0.000


99.1
57.6
0.025
3.2
1.9
0.001
77.3
44.9
0.020
3.6
316
(600)
293
(560)

36.0
19.6
0.008
4.2
2.3
0.001
5.7
3.1
0.001
164
89.1
0.039
22.
1720
935
0.408
351



                     2-14

-------
TABLE 2-9.  NCOG UNDERFIRING  CONDITION, RUN NO. 4
             TEST RESULTS (10/28/81)

Desired front-half tem-
perature, "C (BF)
Actual average filter
temperature, 6C (°F)
Sequential heating,
°c I;°F)
Front-half catch
Particulate (ambient)
mg 3
mg/m
gr/dscf
Acid soluble sulfate
as [H2S04]
mg 3
mg/m
gr/dscf
as [H2S04(H20)2]
mg »
mg/m
gr/dscf
Back-half catch
Sulfurlc acid mist
mg ,
mg/m
gr/dscf
ppm
Sulfur dioxide
mg ,
mg/m
gr/dscf
ppm
Inorganic condensibles
mg ,
mg/nr
gr/dscf
Organic condensibles
mg 3
mg/m
gr/dscf
Total organic carbon
mg ,
mg/m
gr/dscf
Test No.
4.1
121
(250)
123
(254)

139.9
141.3
0.062
47.5
47.9
0.021
64.9
65.6
0.029
11.5
11.6
0.005
3
1300
1313
0.577
494



4.2
121
(250)
130
(266)
204
(400)
113.2
128.6
0.056
0.4
0.4
0.0002
0.5
0.6
0.0002
11.9
13.5
0.006
3
1170
1329
0.584
500



4.3
204
(400)
177
(350)

61.1
65.7
0.028
6.4
6.9
0.003
8.7
9.4
0.004
29.8
32.0
0.014
8
1250
1344
0.585
505



4.4
204
(400)
169
(337)

78.4
92.2
0.040
12.6
14.8
0.006
17.2
20.3
0.009
10.4
12.2
0.005
3
1160
1365
0.596
513



4.5
121
(250)
130
(266)
316
(600)
174.5
80.0
0.035
0.0
0.0
0.000
0.0
0.0
0.000


65.7
30.1
0.013
3.1
1.4
0.0001
14.3
6.6
0.003
4.6
316
(600)
328
(622)

69.7
62.8
0.027
0.0
0.0
0.000
0.0
0.0
0.000
73.7
66.4
0.029
16
1550
1396
0.611
525



                      2-15

-------
TABLE 2-10.   NCOG UNDERFIRING CONDITION, RUN NO. 5
             TEST RESULTS (10/29/81)

Desired front-half tem-
peniture, °C (°F)
Actual average filter
temperature, °C (°F)
Sequential heating,
°C C'F)
Front- ha If catch
Partlculate (ambient)
ing 3
mg/m
!)r/dscf
Add soluble sulfate
as [H2S04]
In9 3
mg/m
gr/dscf
as [H2S04(H20)2]
mg ,
mg/m
gr/dscf
Back-half catch
Sulfurlc acid mist
img ,
mg/m
gr/dscf
ppm
Sulfur dioxide
mg -
mg/m
gr/dscf
ppm
Inorganic condensibles
mg ,
mg/m
gr/dscf
Organic condensibles
mg 3
mg/m
gr/dscf
Total organic carbon
mg ,
mg/m
gr/dscf
Test No.
5.1
121
(250)
124
(255)

138.6
84.5
0.037
85.6
52.2
0.023
117.0
71.3
0.031
34.4
21.0
0.009
5
2070
1262
0.550
474



5.2
121
(250)
123
(254)
177
(350)
185.6
123.7
0.054
3.0
2.0
0. 0008
4.1
2.7
0.001


19.0
12.7
0.006
4.2
2.8
0.001
58.1
38.7
0.017
5.3
177
(350)
176
(345)

50.5
33.0
0.014
9.5
6.2
0.003
13.0
8.5
0.004
81.5
53.3
0.023
13
1970
1288
0.564
484



5.4
177
(350)
186
(366)

32.1
22.4
0.010
0.0
0.0
0.000
0.0
0.0
0.000


101.2
70.8
0.031
3.2
2.2
0.001
49.2
34.4
0.015
5.5
121
(250)
116
(240)
316
(600)
221.0
137.3
0.060
0.0
0.0
0.000
0.0
0.0
0.000


20.9
13.0
0.006
6.3
3.9
0.002
11.8
7.3
0.003
5.6
316
(600)
324
(616)

24.9
16.2
0.007
0.0
0.0
0.000
0.0
0.0
0.000
129
83.8
0.036
20
2050
1331
0.581
500



                   2-16

-------
        TABLE 2-11.  NCOG  UNDERFIRING CONDITION,  RUN NO. 6
                     TEST  RESULTS (10/29/81)

Desired front-half tem-
perature, "C (°F)
Actual average filter
temperature, °C (°F)
Sequential heating.
Front-half catch
Paniculate (ambient)
mg ,
mg/m
gr/dscf
Acid soluble sulfate
as [H?SOJ
"9 3
mg/m
gr/dscf
as [H.S04(H20)2]
""9 3
mg/m
gr/dscf
Back-half catch
Sulfurlc add mist
mg ,
mg/m
gr/dscf
l>pm
Sulfur dioxide
rug ,
rng/m
gr/dscf
ppm
Inorganic condenslbles
mg ,
mg/m
gr/dscf
Organic condenslbles
mg .
mg/m
gr/dscf
Total organic carbon
mg _
mg/m
gr/dscf
Test No.
6.1
121
(250)
119
(246)

184.1
112.2
0.049
71.0
43.3
0.019
97.0
59.2
0.026
24.0
14.6
0.006
4
2000
1219
0.532
458



6.2
121
(250)
126
(258)
204
(400)
150.8
97.9
0.043
0.0
0.0
0.000
0.0
0.0
0.000


109.7
71.2
0.031
4.0
2.6
0.001
42.3
27.5
0.012
6.3
204
(400)
193
(379)

34.3
22.6
0.010
2.8
1.8
0. 0008
3.8
2.5
0.001
97.6
64.2
0.028
16
1900
1250
0.546
470



6.4
204
(400)
208
(407)

26.9
20.8
0.009
0.0
0.0
0.000
0.0
0.0
0.000


118.3
91.7
0.040
5.9
4.6
0.002
154a
119.4
0.052
6.5
121
(250)
119
(246)
316
(600)
195.7
118.6
0.052
0.0
0.0
0.000
0.0
0.0
0.000


20.0
12.1
0.005
6.4
3.9
0.002
15.2
9.2
0.004
6.6
316
(600)
302
(5760

30.9
19.6
0.008
0.0
0.0
0.000
0.0
0.0
0.000
115
72.8
0.032
18
2010
1272
0.555
478



'Contaminated with Isopropanol.
                             2-17

-------
TABLE 2-12. NCOG UNDERFIRING CONDITION, RUN NO.  7 TEST RESULTS (10/30/81)

Desired front-half tem-
perature, °C (°F)
Actual average filter
temperature, °C (°F)
Front-half catch
Particulate (ambient)
mg 3
mg/m
gr/dscf
Test No.
7.1
121
(250)
122
(252)
195.8
113.2
0.050
• 7.2
121
(250)
126
(258)
187.1
112.7
0.049
7.3
177
(350)
181
(358)
64.8
43.8
0.019
7.4
177
(350)
178
(353)
62.6
39.9
0.017
7.5
204
(400)
196
(385)
40.2
24.2
0.010
7.6
316
(600)
308
(587)
24.3
15.2
0.007
TABLE 2-13.  NCOG UNDERFIRING CONDITION,  RUN NO.  8 TEST RESULTS (10/30/81)
                                                  Test No.

Desired front-half tem-
perature, °C (°F)
Actual average filter,
perature, °C (°F)
Front-half catch
Particulate (ambient)
mg 3
mg/m
gr/dscf
8.1
177
(350)
167
(332)
65.3
41.3
0.018
8.2
177
(350)
169
(336)
76.0
49.4
0.022
8.3
204
(400)
198
(388)
66.1
38.9
0.017
8.4
204
(400)
201
(393)
60.5
37.8
0.016
8.5
121
(250)
131
(268)
183.9
129.5
0.056
8.6
316
(600)
313
(596)
45.1
38.2
0.017
                                  2-18

-------
  TABLE 2-14.   DCOG UNDERFIRING CONDITION, RUN NO. Dl  TEST RESULTS (12/8/81)

Desired front- half tem-
perature, °C (°F)
Actual average filter
temperature, °C (°F)
Sequential heating,
°C (°F)
Front-half catch
Particulate (ambient)
mg 3
mg/m
gr/dscf
Acid soluble sulfate
as [H2S04(H20)2]
mg 3
mg/m
gr/dscf
Water soluble sulfate
as [S04=]
mg 3
mg/m
gr/dscf
Back-half catch
Sulfuric acid mist
mg 3
mg/m
gr/dscf
ppm
Sulfur dioxide
mg 3
mg/m
gr/dscf
ppm
Test No.
Dl.l
121
(250)
119
(246)
316
(600)
32.6
26.1
0.011
0.0
0.0
0.000
<0.3
<0.2
<0.0001
11 5a
92.0
0.040
22
69.7
55.8
0.024
21
D1.2
121
(250)
133
(272)
177
(350)
37.4
33.4
0.014
2.7
2.4
0.001
2.1
1.9
0.001
3.5
3.1
0.001
1
116.1
103.7
0.045
39
D1.3
177
(350)
190
(374)

34.0
29.3
0.013
0.0
0.0
0.000
2.5
2.1
0.001
9.3
8.0
0.004
2
117.0
100.9
0.044
38
D1.4
177
(350)
167
(333)

43.3
38.7
0.017
0.0
0.0
0.000
0.0
0.0
0.000
9.2
8.2
0.004
2
115.8
103.4
0.045
39
D1.5
Void







D1.6
316
(600)
268
(515)

27.3
28.4
0.012
0.0
0.0
0.000
1.6
1.7
0.001
6.3
6.6
0.003
2
97.9
102.0
0.044
38
Hydrogen  peroxide  contaminated.
                                     2-19

-------
TABLE  2-15.   DCOG UNDERFIRING CONDITION, RUN  NO.  D2 TEST RESULTS  (12/10/81)

Desired front-half tem-
perature. °C (°F)
Actual average filter
temperature, °C (°F)
Sequential heating,
8C (°F)
Front-half catch
Partlculate (ambient)
mg ,
mg/m
gr/dscf
Acid soluble sulfate
as [H2S04(H20)2]
mg 3
mg/m
gr/dscf
Water soluble sulfate
as [S04«]
mg 3
mg/m
gr/dscf
Back-half catch
Sulfuric acid mist
mg .
mg/m
gr/dscf
ppm
Sulfur dioxide
mg ,
mg/m
gr/dscf
ppm
Inorganic condensibles
mg -
mg/m
gr/dscf
Organic condensibles
mg -
mg/m
gr/dscf
Total organic carbon
mg ,
mg/m
gr/dscf
Test No.
D2.1
121
(250)
118
(244)

249.9*
178.5
0.078
1.4
1.0
0.0004
0.9
0.6
0.0003
13.7
9.8
0.004
2
120.8
86.3
0.038
32



D2.2
121
(250)
109
(229)
177
(350)
38.3
21.5
0.009
3.5
2.0
0.001
2.0
1.1
0.001
14.4
8.1
0.004
2
159.4
89.6
0.039
34



D2.3
177
(350)
184
(363)

34.8
20.4
0.009
0.8
0.5
0.0001
3.5
2.0
0.001
8.7
5.1
0.002
1
155.0
90.6
0.040
34



02. 4
177
(350)
197
(387)

37.2
20.8
0.009
0.5
0.3
0.0001
4.8
2.7
0.002
54. 8b
30.6
0.013
8
131.8
73.6
0.032
28



02. 5
121
(250)
126
(258)
316
(600)
41.1
22.3
0.010
0.0
0.0
0.000
0.0
0.0
0.000


152.6
82.9
0.036
0.8
0.43
0.0002
8.6
4.7
0.002
D2.6
316
(600)
298
(569)

30.3
18.0
0.008
<0.4
<0.2
<0.0001
<0.3
<0.2
<0.0001
10.7
6.4
0.003
2
152.8
91.0
0.040
34



         Acetone rinse contaminated with oil.
         Hydrogen peroxide contaminated.
                                        2-20

-------
   TABLE 2-16.   DCOG UNDERFIRING  CONDITION, RUN NO.  D3
                 TEST RESULTS  (12/11/81)

Desired front-half tem-
perature, °C (°F)
Actual average filter
temperature, °C (°F)
Sequential heating,
°C (»F)
Front-half catch
Particulate (ambient)
mg 3
mg/m
gr/dscf
Acid soluble sulfate
as [H2S04(H20)2]
mg 3
mg/m
gr/dscf
Water soluble sulfate
as IS04=]
' m9 3
mg/m
gr/dscf
Back-half catch
Sulfuric acid mist
mg 3
mg/m
gr/dscf
Ppm
Sulfur dioxide
mg ,
mg/m
gr/dscf
ppm
Inorganic condensibles
mg 3
mg/m
gr/dscf
Organic condensibles
mg -
mg/m
gr/dscf
Total organic carbon
mg ,
mg/m
gr/dscf
Test No.
D3.1
121
(250)
120
(248)

38.6
26.1
0.011
0.4
0.3
0.0001
6.0
4.0
0.002
84. Oa
56.8
0.025
14
90.1
60.9
0.026
23



03. 2
121
(250)
132
(270)
204
(400)
34.5
21.3
0.009
2.5
1.5
0.001
0.0
0.0
0.000
7.0
4.3
0.002
1
152.8
94.3
0.041
35



03. 3
204
(400)'
211
(411)

30.9
22.1
0.010
0.0
0.0
0.000
4.1
2.9
0.002
12.0
8.6
0.004
2
130.8
93.4
0.041
35



D3.4
204
(400)
204
(400)

38.7
26.9
0.012
2.6
1.8
0.001
0.8
0.5
0.0003
8.2
5.7
0.002
1
143.4
99.6
0.043
37



03. 5
121
(250)
123
(254)
316
(600)
35.0
19.6
0.008
0.0
0.0
0.000
0.9
0.5
0.0002


28.9
16.1
0.007
2.0
1.1
0.0005
3.4
1.9
0.0008
D3.6
316
(600)
280
(536)

25.5
14.8
0.006
0.0
0.0
0.000
2.2
1.3
0.001
12.8
7.4
0.003
2
169.1
98.3
0.043
37



Hydrogen peroxide contaminated.
                          2-21

-------
TABLE 2-17.   DCOG UNDERFIRING  CONDITION, RUN  NO.  D4 TEST RESULTS  (12/12/81)

Desired front-half tem-
perature, "C (°F)
Actual average filter
temperature, °C (°F)
Sequential heating,
°C (°F)
Front-half catch
Particulate (ambient)
mg ,
mg/m
gr/dscf
Acid soluble sulfate
as [H2S04(H20)2]
mg 3
mg/m
gr/dscf
Mater soluble sulfate
as [S04°]
mg ,
mg/m
gr/dscf
Back-half catch
Sulfuric add mist
mg ,
mg/m
gr/dscf
PPm
Sulfur dioxide
mg 3
mg/m
gr/dscf
ppm
Inorganic condensibles
mg -
mg/m
gr/dscf
Organic condensibles
mg ,
mg/m
gr/dscf
Total organic carbon
mg ,
mg/m
gr/dscf
Test No.
04. 1
121
(250)
148
(299)

28.5
16.9
0.007
0.0
0.0
0.000
0.0
0.0
0.000
42.3s
25.0
0.011
6
135.6
80.2
0.035
30



04. 2
121
(250)
126
(259)
204
(400)
45.2
26.7
0.012
0.0
0.0
0.000
0.9
0.5
0.0002
15.9
9.4
0.004
2
130.5
77.2
0.034
29



04.3
204
(400)
209
(409)

24.8
16.6
0.007
0.9
0.6
0.0003
3.2
2.1
0.001
6.7
4.5
0.002
1
118.3
79.4
0.035
30



04. 4
Void










04. 5
121
(250)
128
(263)
316
(600)
31.2
17.8
0.008
0.0
0.0
0.000
0.0
0.0
0.000


84.5
48.3
0.021
2.9
1.6
0.0007
8.5
4.8
0.002
04. 6
316
(600)
325
(617)

17.5
10.5
0.004
0.0
0.0
0.000
0.0
0.0
0.000
74. 7a
44.7
0.020
11
90.1
54.0
0.024
20



       'Hydrogen peroxide contaminated.
                                       2-22

-------
TABLE 2-18.    DCOG UNDERFIRING CONDITION,  RUN NO. D5 TEST  RESULTS (12/12/81)

Desired front-half tem-
perature, °C (°F)
Actual average filter
temperature, °C (°F)
Sequential heating,
°C (°F)
Front-half catch
Particulate (ambient)
mg .
mg/m
gr/dscf
Acid soluble sulfate
as [H2S04 (H20)2]
mg -
mg/m
gr/dscf
Water soluble sulfate
as [S04=]
mg ,
mg/m
gr/dscf
Back-half catch
Sulfuric acid mist
mg ,
mg/m
gr/dscf
ppm
Sulfur dioxide
mg ,
mg/m
gr/dscf
ppm
Inorganic condensibles
1119 , 3
mg/m
gr/dscf
Organic condensibles
mg, 3
mg/m
gr/dscf
Total organic carbon
mg -
mg/m
gr/dscf
Test No.
D5.1
121
(250)
123
(253)

23.3
13.4
0.006
4.6
2.6
0.001
3.7
2.1
0.001
8.8
5.0
0.002
1
131.8
75.7
0.033
28



D5.2
121
(250)
127
(261)
177
(350)
20.0
11.5
0.005
1.1
0.6
0.0003
1.7
1.0
0.001


74.5
42.8
0.019
0.70
0.40
0.0002
202a
116
0.050
D5.3
177
(350)
181
(357)

16.3
10.4
0.004
3.0
1.9
0.001
1.6
1.0
0.0004
7.8
5.0
0.002
1
123.6
79.2
0.035
30



D5.4
177
(350)
177
(351)

19.1
11.9
0.005
0.8
0.5
0.0002
3.8
2.4
0.001


158.1
98.8
0.043
4.0
2.5
0.001
572a
357
0.156
D5.5
121
(250)
122
(251)
316
(600)
15.9
9.4
0.004
0.0
0.0
0.000
0.0
0.0
0.000


15.6
9.2
0.004
1.4
0.83
0.0004
3.6
2.1
0.0009
05. 6
316
(600)
316
(600)

12.9
3.0
0.003
0.4
0.2
0.0001
1.4
0.9
0.0003
8.2
5.1
0.002
1
129.0
79.6
0.035
30



         Contaminated with isopropanol.
                                       2-23

-------
TABLE 2-19.   DCOG UNDERFIRING CONDITION, RUN NO.  D6  TEST RESULTS (12/13/81)

Desired front-half tem-
perature, °C (°F)
Actual average filter
temperature, °C (°F)
Sequential heating,
°C (°F)
Front-half catch
Particulate (ambient)
mg ,
mg/m
gr/dscf
Add soluble sulfate
as [H2S04(H20)2]
mg 3
mg/m
gr/dscf
Water soluble sulfate
as [S04=]
mg ,
mg/m
gr/dscf
Back-half catch
Sulfurlc acid mist
mg .
mg/m
gr/dscf
ppm
Sulfur dioxide
mg ,
mg/m
gr/dscf
ppm
Inorganic condensibles
mg 3
mg/m
gr/dscf
Organic condensibles
mg 3
mg/m
gr/dscf
Total organic carbon
mg 3
mg/m
gr/dscf
Test No.
06. 1
121
(250)
132
(270)

12.2
7.8
0.003
0.0
0.0
0.000
0.0
0.0
0.000
13.2
8.5
0.004
2
118.3
75.8
0.033
28



06.2
121
(250)
120
(248)
204
(400)
21.1
13.5
0.006
0.0
0.0
0.000
0.0
0.0
0.000


55.2
35.4
0.015
2.4
1.5
0.0007
403a
258
0.113
D6.3
204
(400)
204
(399)

15.6
10.8
0.005
1.4
1.0
0.0004
0.0
0.0
0.000
7.5
5.2
0.002
1
113.3
78.1
0.034
29



06. 4
204
(400)
219
(427)

12.0
8.0
0.004
0.0
0.0
0.000
0.0
0.0
0.000


144.2
96.8
0.042
2.8
1.9
0.0008
77a
51.7
0.022
D6.5
121
(250)
131
(267)
316
(600)
19.9
10.9
0.005
0.0
0.0
0.000
0.0
0.0
0.000


10.0
5.5
0.002
2.4
1.3
0.0006
8.0
4.4
0.002
06. 6
316
(600)
319
(607)

9.2
6.3
0.003
0.3
0.2
0.0001
0.0
0.0
0.000
11.4
7.9
0,003
2
110.1
75.9
0.033
28



       Contaminated with isopropanol.
                                      2-24

-------
No water soluble sulfates were found on NCOG filters and acetone



rinse residues.  Figures 2-1 and 2-2 present graphs plotting



particulate concentration versus average filter temperature for



NCOG and DCOG underfiring, respectively.  A line of best fit was



determined for each data set by a least-squares linear regression



calculation.  Performance of this calculation, showed that the



NCOG data more accurately depicted a bimodal line of best fit.



Figure 2-3 presents the NCOG and DCOG best fit lines for partic-



ulate concentration versus average filter temperature.



     Analytical results obtained from Sampling Trains 1 and 2



[121°C (250°F) front-half temperature], Sampling Trains 3 and 4



[177°C (350°F) or 204°C (400°F) front-half temperature], Sampling



Train 5 [121°C (250°F) front-half temperature], and Sampling



Train 6 [316°C (600°F) front-half temperature] are presented in



Tables 2-20, 2-21, 2-22, and 2-23 for the NCOG underfiring test



series and Tables 2-24, 2-25, 2-26, and 2-27 for the DCOG under-



firing test series, respectively.



     Visible emissions observations and process data collected



during particulate testing are presented in Sections 2.5 and 2-10



of this report.
                              2-25

-------
    160
    140
    120
f>  100



z
o

h-

-------
     40
<_)
§
     30
I

RUN  1
RUN  2
RUN  3
RUN  4
RUN  5
RUN  6
                                                            LINE OF BEST FIT

                                                            V INT • 23.8
                                                            SLOPE - -0.031
                                                            CORR. COEF. - -0.254
cc.
a.
a.
     20
     10
                                            O    a
                       O

                        O
                           100                   200

                            AVERAGE ACTUAL FILTER TEMPERATURE, *C
                    300
         Figure  2-2.  Particulate concentration  vs. average actual
                filter temperature during DCOG underfiring.
                                       2-27

-------
 S
 o
 LJ
    160
    140
    120
    100
     no
     60
oc
KC
o.
     40
     20
                     NCOG, B
                    NCOG, A
                      DCOG
                                               1
                          100                  200


                           AVERAGE ACTUAL FILTER  TEMPERATURE, °C
300
Figure 2-3.   Summary  of best-fit lines from particulate concentration
vs. average actual filter temperature for NCOG and  DCOG underfiring.
                                    2-28

-------
                           TABLE 2-20.  NCOG UNDERFIRING CONDITION, TRAINS  1  AND  2  OF  QUAD TRAIN
                                                 [121°C  (250°F)  FRONT  HALF]
NJ
VO

Date (1981)
Actual average filter
temperature. °C (°F)
Sequential heating (2 hours),
°C (°r)
Front-half catch
Participate (ambient)
mq ,
mg/m
qr/dscf
» loss
Acid soluble sulfate
as [H;S04]
mq ,
mg/m
gr/dscf
as [H2S04(HZ0)2]
mg ,
mg/m
gr/dscf
Back-half catch
Sulfurlc add mist
mg 3
mg/mj
gr/dscf
Sulfur dioxide
mq
mg/m
ar/dscf
Ppm
Inorganic condenslbles
mg -
mq/mj
gr/dscf
Organic condenslbles
mg -
mg/m
gr/dscf
Total organic carbon
mg ..
mq/mj
gr/dscf

1.1
10/27
122
(252)

226.9
128.9
0.056
81.5
46.3
0.020
111.4
63.3
0.028
8.9
5.0
0.002
1960
1114
0.486
419
-
-
-
1.2
10/27
125
(257)
Amb.
192.8
115.4
0.050
-
-
177
(350)
55.2
33.0
0.014
72
7.4
4.4
0.002
10.1
6.1
0.003
9.4
5.6
0.002
1850
1108
0.4B4
416
-
-
-
3.1
10/28
113
(236)

202.0
115.4
0.050
70.4
40.2
0.017
96.2
55.0
0.024
3.3
4.7
0.002
1790
1023
0.446
384
-
-
-
Test No.
3.2
10/28
127
(260)
Amb.
156.9
94.5
0.041
-
-
177
(350)
34.2
20.6
0.009
78
0.0
0.0
0.000
0.0
0.0
0.000
8.6
5.2
0.002
1540
928
0.406
349
-
-
-
5.1
10/29
124
(255)

138.6
84.5
0.037
85.6
52.2
0.023
117.0
71.3
0.031
34.4
21.0
D.009
2070
1262
0.550
474
-
-
-
5.2
10/29
123
(254)
Amb.
185.6
123.7
0.054
-
-
177
(350)
36.8
24.5
0.011
80
3.0
2.0
0.0008
4.1
2.7
0.004
-
-
19.0
12.7
0.006
4.2
2.8
0.001
58.1
38.7
0.017
2.1
10/27
119
(247)

183.1
115.2
0.050
61.6
38.7
0.017
84.2
53.0
0.023
741a
466
0.204
1370
862
0.377
324
-
-
-
2.2
10/27
128
(263)
Amb.
149.2
99.5
0.044
-
-
204
(400)
24.8
16.5
0.007
84
0.0
0.0
0.000
0.0
0.0
0.000
16.0
10.7
0.005
1720
1147
0.502
431
-
-
-
4.1
10/28
123
(254)

139.9
141.3
0.062
47.5
47.9
0.021
64.9
65.6
0.029
11.5
11.6
0.005
1300
1313
0.577
494
-
-
-
4.2
10/28
130
(266)
Amb.
113.2
128.6
0.056
-
-
204
(400)
41.7
47.4
0.021
62
0.4
0.4
0.0002
0.5
0.6
0.0002
11.9
13.5
0.006
1170
1329
0.58)
500
-
-
-
6.1
10/29
119
(246)

184.1
112.2
0.049
71.0
43.3
0.019
97.0
59.6
0.026
24.0
14.6
0.006
2000
1219
0.532
458
-
-
-
6.2
10/29
126
(258)
Amb.
150.8
97.9
0.043
-
-
204
(400)
24.2
15.7
0.007
84
0.0
0.0
0.000
0.0
0.0
0.000
-
-
109.7
71.2
0.031
4.0
2.6
0.001
42.3
27.5
0.012

-------
   TABLE 2-21.  NCOG  UNDERFIRING CONDITION,  TRAINS 3 AND 4 OF QUAD TRAIN
                [1*1°C (250°F) AND 204°C  (400°F)  FRONT HALF]

Test No.
Date (1981)
Actual average filter
temperature, °C (°F)
Front-half catch
Particulate (ambient)
mg 3
mg/m
gr/dscf
Acid soluble sulfate
as [H2S04]
mg -
mg/m
gr/dscf
as [H2SO,j(H20)2]
mq -
mg/m
gr/dscf
Back-half catch
Sulfuric acid mist
mo ,
mg/m
gr/dscf
Sulfur dioxide
mg ,
mg/mj
gr/dscf
ppm
Inorganic condensibles
mg »
mg/m
gr/dscf
Organic condensibles
mg 3
mg/m
gr/dscf
Total organic carbon
mg carbon
mg/m3
gr/dscf

1.3
10/27
170
(338)

72.9
43.4
0.019
9.8
5.8
0.002
13.4
8.0
0.003
65.4
38.9
0.017
1870
1113
0.487
418
-
-
-

1.4
10/27
169
(336)

50.6
30.8
0.013
4.7
2.9
0.001
6.4
3.9
0.002
56.0
34.1
0.015
1810
1104
0.482
415
-
-
-
we
3.3
10/28
178
(353)

87.3
53.6
0.023
25.3
15.5
0.007
34.6
21.2
0.009
67.2
41.2
0.018
1680
1031
0.450
387
-
-
-
(350°F)
3.4
10/28
169
(336)

40.3
25.5
0.011
3.7
2.3
0.001
5.0
1.2
0.001
89.2
56.4
0.025
1620
1025
0.448
385
-
-
-

5.3
10/29
176
(349)

50.5
33.0
0.014
9.5
6.2
0.003
13.0
8.5
0.004
81.5
53.3
0.023
1970
1288
0.564
484
-
-
-

5.4
10/29
186
(366)

32.1
22.4
0.010
0.0
0.0
0.000
0.0
0.0
0.000
-
-
101.2
70.8
0.031
3.2
2.2
0.001
49.2
34.4
0.015

2.3
10/27
198
(389)

46.3
31.7
0.014
12.2
3.3
0.004
16.7
11.4
0.005
53.0
36.3
0.016
1700
1164
0.509
438
-
-
-

2.4
10/27
207
(404)

61.3
42.6
0.019
14.4
10.0
0.004
19.7
13.7
0.006
19.6
13.6
0.006
1610
1118
0.489
420
-
-
-
204 «C
4.3
10/28
177
(350)

61.1
65.7
0.028
6.4
6.9
0.003
8.7
9.4
0.004
29.8
32.0
0.014
1250
1344
0.585
505

-
-
(400-F)
4.4
10/28
169
(337)

78. 4
92.2
0.040
12.6
14.8
0.006
17.2
20.3
0.009
10.4
12.2
0.005
1160
1365
0.596
513
-
-
-

6.3
10/29
193
(379)

34.3
22.6
0.010
2.8 .
1.8
0.0008
3.8
2.5
o!ooi
97.6
64.2
0.028
1900
1250
0.546
470
-
-
-

6.4
10/29
208
(407)

26.9
20.8
0.009
0.0
0.0
0.000
0.0
0.0
0.000
-

118.3
91.7
0.040
5.9
4.6
0.002
154a
119.4
0.052
Isopropanol contaminated.
                                    2-30

-------
                                TABLE 2-22.  NCOG  UNDERFIRING  CONDITION,  TRAIN  5
                                             [121°C (250°F)  FRONT HALF]
to
I
U)

Actual average filter
temperature, °C (°F)
Front-half catch
Filter half designa-
tion
Sequential heating,
°C (°F)
Heating time, h
Particulate (ambient)
mg 3
mg/m
gr/dscf h
J difference
Acid sul fates
Total organic carbon
Back-half catch
Inorganic condenslbles
mg -
mg/m
gr/dscf
Organic condenslbles
mg -
mg/m
gr/dscf
Total organic carbon
mg carbon
mq/m3
gr/dscf
Test No. 1.5 (10/27/81)
128 (263)
A
177 177 204
Antb. (350) (350) (400)
242
135.3 47.5 41.7 37.3
94.0 33.0 29.0 25.9
0.041 0.014 0.013 0.011
66 68 73

204
(400)
4
34.5
24.0
0.010
76

316
(600)
2
30.5
21.2
0.009
78
NOC

B




NO
28.2
19.6
0.008
2.6
1.8
0.001
23.4
16.2
0.007
Test Ho. 2.5 (10/27/81)
125 (257)
A
177 177 204 204
An*. (350) (350) (400) (400)
2424
90.9 34.0 30.7 29.2 27.7
60.6 22.7 20.5 19.5 18.5
0.026 0.010 0.009 0.008 0.008
62 62 69 69

316
(600)
2
22.5
15.0
0.006
77
ND

B




NO
68.2
45.5
0.020
4.8
3.2
0.001
44.3
29.5
0.013

-------
          TABLE 2-22 (continued)

Actual average filter
temperature, "C (°F)
Front-half catch
Filter half designa-
tion
Sequential heating,
°C (°F)
Heating time, h
Participate (ambient)
mg ,
mg/m
gr/dscf
% differenceb
Add sulfates
Total organic carbon
Back-half catch
Inorganic condenslbles
mg -
mg/m
flr/dscf
Organic condenslbles
mfl 3
mg/m
gr/dscf
Total organic carbon
mg carbon
mg/m3
gr/dscf

Test No. 3.5 (10/28/81)
109 (229)
A
177 177 204
Amb. (350) (350) (400)
242
171.2 29.0 26.8 26.2
99.5 16.9 15.6 15.2
0.043 0.007 0.007 0.007
84 84 84

204
(400)
4
25.2
14.6
0.006
86

316
(600)
2
22.0
12.8
0.006
86
NO

B




ND
99.1
57.6
0.025
3.2
1.9
0.001
77.3
44.9
0.020

Test No. 4.5 (10/28/81)
130 (266)
A
177 177 204 204 316
Amb. (350) (350) (400) (400) (600)
24242
174.5 137.3 128.8 112.4 104.7 99.0
80.0 63.0 59.1 51.6 48.0 45.4
0.035 0.028 0.026 0.022 0.021 0.020
20 26 37 40 43
ND

B




ND
65.7
30.1
0.0!3
3.1
1.4
0.001
14.3
6.6
0.003

to
 I
u>

-------
                 TABLE  2-22  (continued)
to
 I
w
u>

Actual average filter
temperature, °C (°F)
Front-half catch
Filter half designa-
tion
Sequential heating,
°C (°F)
Heating time, h
Partlculate (ambient)
mg 3
mg/m
gr/dscf .
% difference"
Acid sul fates
Total organic carbon
Back-half catch
Inorganic condenslbles
mV
gr/dscf
Organic condenslbles
mg 3
mg/m
gr/dscf
Total organic carbon
mg carbon
mg/nK
gr/dscf
Test Mo. 5.5 (10/29/81)
116 (240)
A
177 177 204 204 316
Amb. (350) (350) (400) (400) (600)
24242
221.0 50.4 44.2 36.2 32.3 27.7
137.3 31.3 27.4 22.5 20.1 17.2
0.060 0.014 0.012 0.010 0.009 0.008
77 80 83 85 87
NO

B




NO
20.9
13.0
0.006
6.3
3.9
0.002
11.8
7.3
0.003
Test No. 6.5 (10/29/81)
119 (246)
A
177 177 204 204 316
Amb. (350) (350) (400) (400) (600)
24242
195.7 42.3 37.6 33.2 30.3 25.8
118.6 25.6 22.8 20.1 18.4 15.6
0.052 0.011 0.010 0.009 0.008 0.007
79 81 83 85 86
NO

B




NO
20.0
12.1
0.005
6.4
3.9
0.002
15.2
9.2
0.004
                  "All weights corrected to entire filter catch.

                   Calculated from concentration.

                  CND - Not detectable, sample response egualed blank response.

-------
             TABLE 2-23.   NCOG UNDERFIRING CONDITION,  TRAIN  6
                        [316°C (600°F)  FRONT HALF]

Date (1981)
Actual average filter
temperature, °C (°F)
Front-half catch
Particulate (ambient)
mg 3
mg/m
gr/dscf
Acid soluble sulfate
as [H2S04]
mg 3
mg/m
gr/dscf
as [H2S04(H20)2]
mg 3
mg/m
gr/dscf
Back-half catch
Sulfuric acid mist
mg 3
mg/m
gr/dscf
Sulfur dioxide
mg 3
mg/m
gr/dscf
Ppm
Test No.
1.6
10/27
320
(608)


27.0
19.0
0.008


0.0
0.0
0.000

0.0
0.0
0.000


606a
426.8
0.187

1120
789
0.346
296
2.6
10/27
316
(600)


39.5
23.9
0.010


2.6
1.6
0.001

3.5
2.1
0.001


157
95.7
0.041

1940
1176
0.512
442
3.6
10/28
293
(560)


36.0
19.6
0.008


4.2
2.3
0.001

5.7
3.1
0.001


164
89.1
0.039

1720
935
0.408
351
4.6
10/28
328
(622)


69.7
62.8
0.027


0.0
0.0
0.000

0.0
0.0
0.000


73.7
66.4
0.029

1550
1396
0.611
525
5.6
10/29
324
(616)


24.9
16.2
0.007


0.0
0.0
0.000

0.0
0.0
0.000


129
83.8
0.036

2050
1331
0.581
500
6.6
10/29
302
(576)


30.9
19.6
0.008


0.0
0.0
0.000

0.0
0.0
0.000


115
72.8
0.032

2010
1272
0.555
478
Hydrogen peroxide contaminated.
                                   2-34

-------
                            TABLE  2-24.   DCOG  UNDERFIRING CONDITION,  TRAINS 1  AND  2  OF QUAD TRAIN
                                                     [121°C  (250°F) FRONT HALF]

Date (1981)
Actual average filter
temperature. °C (°F)
Sequential heating (2 hours),
°C (°F)
Front-half catch
Partlculate (ambient)
mg ,
mg/m
gr/dscf
X loss
Acid soluble sulfate
as [H2S04(HZ0)2]
mg ,
mg/m
gr/dscf
Hater soluble sulfate
as [S04=]
mg
mg/m3
gr/dscf
Back-half catch
SulfuHc add mist
mg ,
mg/mj
gr/dscf
Sulfur dioxide
mg ,
mg/m
gr/dstf
ppm
Inorganic condensibles
mg -
mg/m
gr/dscf
Organic condensibles
mg 3
mg/m
gr/dscf
Total organic carbon
mg carbon
mg/nr
gr/dscf
Test Ho.
01.1
12/8
119
(246)
316
(600)
32.6
26.1
0.011
0.0
0.0
0.000
<0.3
0.2
-0.004
115b
92
0.040
69.7
55.8
0.024
21
-
-
-
01. 2
12/8
133
(272)
Anb.
37.4
33.4
0.014
-
-
177
(350)
22.0
19.6
0.008
41
2.7
2.4
0.001
2.1
1.9
0.001
3.5
3.1
0.001
116.1
103.7
0.045
39
-
-
-
D2.1
12/10
118
(244)

249.9
178.5
0.078
1.4
1.0
0.0004
0.9
0.6
0.0003
13.7
9.8
0.004
120.8
86.3
0.038
32
-
-
-
D2.2
12/10
109
(229)
Arab.
38.3
21.5
0.009
-
-
177
(350)
24.6
13.8
0.006
36
3.5
2.0
0.001
2.0
1.1
0.001
14.4
8.1
0.004
159.4
89.6
0.039
34
-
-
-
05.1
12/12
123
(253)

23.3
13.4
0.006
4.6
2.6
0.001
3.7
2.1
0.001
8.8
5.0
0.002
31.8
75.7
D.033
28
-
-
-
05. 2
12/12
127
(261)
An*.
20.0
11.5
0.005
-
-
177
(350)
8.7
5.0
0.002
56
1.1
0.6
0.0003
1.7
1.0
0.001
-
-
74.5
42.8
0.019
0.70
0.40
0.0002
202C
116
0.050
03.1 '
12/11
120
(248)

38.6
26.1
0.011
0.4
0.3
0.000
6.0
4.0
0.002
84. Ob
56.8
0.025
90.1
60.9
0.026
23
-
-
-
03. 2
12/11
132
(270)
Amb.
34.5
21.3
0.009

-
204
(400)
18.1
11.2
0.005
47
2.5
1.5
0.001
0.0
0.0
O.OOC
7.0
4.3
0.002
152.8
94.3
0.041
35
-
-
-
04.1
12/12
148
(299)

28.5
16.9
0.007
0.0
0.0
0.000
0.0
0.0
0.000
42.3b
25.0
0.011
35.6
80.2
D.035
30
-
-
-
04.2
12/12
126
(259)
Amb.
45.2
26.7
0.012
-
-
204
(400)
13.5
8.0
0.003
70
0.0
0.0
0.001
0.9
0.5
0.0002
15.9
9.4
0.004
130.5
77.2
0.034
30
-
-
-
06.1
12/13
132
;270)

12.2
7.8
0.003
0.0
0.0
0.000
0.0
0.0
0.000
13.2
8.5
0.004
118.3
75.8
1.033
28
-
-
-
06. 2
12/13
120
(248)
Ainb.
21.1
13.5
0.006
-
-
204
(400)
5.4
3.5
0.001
74
0.0
0.0
0.000
0.0
0.0
0.000
-
-
55.2
35.4
0.015
2.4
1.5
0.0007
403C
258
0.113
NJ
 I
Ul
cn
           aAcetone rinse contaminated with oil.

           Hydrogen peroxide contaminated.
           clsopropanol contaminated.

-------
                    TABLE 2-25.
DCOG  UNDERFIRING CONDITION, TRAINS 3 AND  4 OF QUAD TRAIN

    [177°C (350°F) AND  204°C (400°F) FRONT HALF]

Test No.
Date (1981)
Actual average filter
temperature. °C (°F)
Front-half catch
Participate (ambient)
mg 3
mg/m
gr/dscf
Add soluble sulfate
as [H2S04(HzO)2]
mg ,
mg/m
gr/dscf
Hater soluble sulfate
as [S04=]
mg 3
mg/m
gr/dscf
Back-half catch
Sulfurlc add mist
mg ,
mg/m
gr/dscf
Sulfur dioxide
mg ,
mg/m
gr/dscf
ppm
Inorganic condensibles
mg ,
mg/m
gr/dscf
Organic condensibles
mg 3
mg/m
gr/dscf
Total organic carbon
mg carbon
mg/m3
gr/dscf
177°C (350"F)
01.3
12/8
190 (374)
34.0
29.3
0.013
0.0
0.0
0.000
2.5
2.1
0.001
9.3
8.0
0.004
117.0
100.9
0.044
38
-
-
-
01.4
12/8
167 (333)
43.3
38.7
0.017
0.0
0.0
0.000
0.0
0.0
0.000
9.2
8.2
0.004
115.8
113.4
0.045
39
-
-
-
02. 3
12/10
184 (363)
34.8
20.4
0.009
0.8
0.5
0.0001
3.5
2.0
0.001
8.7
5.1
0.002
155.0
90.6
0.040
34
-
-
-
02.4
12/10
197 (387)
37.2
20.8
0.009
0.5
0.3
0.0001
4.8
2.7
0.002
54. 8a
30.6
0.013
131.8
73.6
0.032
28
-
-
-
05.3
12/12
181 (357)
16.3
10.4
0.004
3.0
1.9
0.001
1.6
1.0
0.0004
7.8
5.0
0.002
123.6
79.2
0.035
30
-
- •
-
05.4
12/12
177 (351)
19.1
11.9
0.005
0.8
0.5
0.0002
3.8
2.4
0.001
-
-
158.1
98.8
0.043
4.0
2.5
0.001
572b
357
0.156
204'C (400"F)
03.3
12/11
211 (411)
30.9
22.1
0.010
0.0
0.0
0.000
4.1
2.9
0.002
12.0
8.6
0.004
130.8
93.4
0.041
35
-
-
-
03.4
12/11
204 (400)
38.7
26.9
0.012
2.6
1.8
0.001
0.8
0.5
0.0003
8.2
5.7
0.002
143.4
99.6
0.043
37
-
-
-
04.3
12/12
209 (409)
24.8
16.6
0.007
0.9
0.6
0.0003
3.2
2.1
0.001
6.7
4.5
0.002
118.3
79.4
0.035
30
-
-
-
04.4
Void
run









06.3
12/13
204 (399)
15.6
10.8
0.005
1.4
1.0
0.0004
0.0
0.0
0.000
7.5
5.2
0.002
113.3
78.1
0.034
29
-
-
-
D6.4
12/13
219 (427)
12.0
8.0
0.004
0.0
0.0
0.000
0.0
0.0
0.000
-
-
144.2
96.8
0.042
2.8
1.9
0.0008
77b
51.7
0.022
to
I
         'Hydrogen peroxide contaminated.

          Isopropanol contaminated.

-------
                                TABLE 2-26.   DCOG  UNDERFIRING  CONDITION,  TRAIN
                                             [121°C (250°F)  FRONT HALF]

Actual average filter
temperature, "C (°F)
Front-half catch
Filter half designa-
tion
Sequential heating,
•C (°F)
Heating time, h
Partlculate (ambient)
mg 3
mg/m
gr/dscf h
* difference"
Add sul fates
as [H2S04(H20)2]
mq ,
mg/m
gr/dscf
Water soluble sulfate
as [S04=]
mg -
mg/m
gr/dscf
Total organic carbon
Back-half catch
Inorganic condenslbles
mg 3
mg/m
gr/dscf
Organic condenslbles
mg ,
mg/m
gr/dscf
Total organic carbon
mg carbon
mg/m3
gr/dscf

Test No. 01. 1 (12/8/81)
119 (246)
A
177 177 204 204 316
Afflb. (350) (350) (400) (400) (600)
24242
32.6 21.8 21.1 16.8 16.4 14.6
26.1 17.4 16.9 13.4 13.1 11.7
0.011 0.008 0.007 0.006 0.006 0.005
33 35 49 50 55
0.0
0.0
0.000
<0.3
<0.2
<0.0001

B





NOC
N/Ad
N/A
N/A

Test No. 02.5 (12/10/81)
126 (258)
A
177 177 204 204 316
Amb. (350) (350) (400) (400) (600)
24242
41.1 23.4 19.2 18.8 17.7 15.1
22.3 12.7 10.4 10.2 9.6 8.2
0.010 0.005 0.004 0.004 0.004 0.003
43 53 54 57 63
0.0
0.0
0.000
0.0
0.0
0.000

B





NO
152.6
82.9
0.036
0.8
0.4
0.0002
8.6
4.7
0.002

to
 I
OJ

-------
         TABLE 2-26 (continued)

Actual average filter
temperature, °C (°F)
Front-half catch
Filter half designa-
tion
Sequential heating,
°C (°F)
Heating time, h
Participate (ambient)
ng .
mg/m
gr/dscf h
I difference
Acid sui fates
as [H2SOA(H20)2]
mg 3
mg/m
gr/dscf
Water soluble sui fate
»s tSQ4=]
mq ,
mg/m'
gr/dscf
Total organic carbon
Back-half catch
Inorganic condenslbles
mg ,
mg/m
gr/dscf
Organic condenslbles
mg j
mg/m
gr/dscf
Total organic carbon
mg carbon
mg/m'
gr/dscf
Test No.
D3.5 (12/11/81)
123 (254)
A
177 177
Amb. (350) (350)
2 4
35.0 22.2 19.9
19.6 12.4 11.1
0.008 0.005 0.005
37 43
0.
0.
0.
204 204 316
(400) (400) (600)
242
15.7 15.7 13.4
8.8 8.8 7.5
0.004 0.004 0.003
55 55 62
0
0
000
0.9
0.5
0.0002

B





ND
28.9
16.1
0.007
2.0
1.1
0.0005
3.4
1.9
0.0008
Vest No.
D4.5 (12/12/81)
128 (263)
A
177 177
Amb. (350) (350)
2 4
31.2 21.7 20.2
17.8 12.4 11.5
0.008 0.005 0.005
34 35
0.
0.
0.
0.
0.
0.
204 204 316
(400) (400) (600)
242
15.1 14.9 12.3
8.6 8.5 7.0
0.004 0.004 0.005
52 52 61
0
0
000
0
0
000

84
48
0.
B





HD
.5
.3
021
2.9
1.6
0.0007
8.5
4.8
0.002
 I
to
00

-------
          TABLE  2-26  (continued)

Actual average filter
temperature, °C (°F)
Front-half catch
Filter half designa-
tion
Sequential heating.
°C (°F)
Heating time, h
Paniculate (ambient)
m", 3
mg/m
gr/dscf .
% difference0
Acid sul fates
as [H2S04(H20)2]
mg 3
mg/m
gr/dscf
Hater soluble sulfate
as [S04~]
mg ,
mg/m
gr/dscf
Total organic carbon
Back-half catch
Inorganic condensibles
mg ,
mg/m
gr/dscf
Organic condensibles
mg ,
mg/m
gr/dscf
Total organic carbon
mg carbon
mq/m3
gr/dscf
Test No
05. 5 (12/12/81)
122 (251)
A
177 177
Amb. (350) (350)
2 4
1S.9 6.9 5.3
9.4 4.1 3.1
0.004 0.002 0.001
56 67
0.
0.
0.
0.
0.
0.
204 204 316
(400) (400) (600)
242
4.5 4.5 2.4
2.7 2.7 1.4
0.001 0.001 0.001
71 71 85
0
0
000
0
0
0002

B





NO
15.6
9.2
0.004
1.
0.
0.
3.
2.
0.
4
8
0004
6
0009
Test No.
06.5 (12/13/81)
131 (267)
A
177 177
Amb. (350) (350)
2 4
19.9 13.6 12.8
10.9 7.4 7.0
0.005 0.003 0.003
32 26
204 204 316
(400) (400) (600)
242
11.5 11.3 4.4
6.3 6.2 2.4
0.003 0.003 0.001
42 43 78
0.0
0.0
0.000
0.
0.
0.
0
0
000

B





NO
. 10.0
5.5
0.002
2.4
1.3
0.0006
8.0
4.4
0.002
to
 I
co
vo
          aA11 weights corrected to entire filter catch.

           Calculated from concentration.

           NO = Not detectable, sample response similar to blank response.

          dN/A = Not analyzed.

-------
                              TABLE  2-27.  DCOG UNDERFIRING CONDITION, TRAIN 6
                                          [316°C (600°F) FRONT HALF]

Date (1981)
Actual average filter
temperature, °C (°F)
Front-half catch
Particulate (ambient)
mg ,
mg/tn
gr/dscf
Acid soluble sulfate
as [H2S04(H20)2]
mg ,
mg/'m
gr/dscf
Water soluble sulfate
as [S0
-------
2.3  COMPARISON OF PARTICULATE RESULTS AT SELECTED TEMPERATURES



     Selected particulate samples collected at a probe and filter



temperature of approximately 121°C  (250°F) were sequentially



heated to determine weight loss at  177°C  (350°F), 204°C  (400°F),



and 316°C (600°F).  Tables 2-28 and 2-29 present the results from



the sequential heating of the NCOG and DCOG samples, respec-



tively.  This data showed that more than half of the weight loss



occurred when the sample was initially heated to 177°C  (350°F).



Therefore, a sample was sequentially heated in 14°C  (25°F) incre-



ments to determine at what temperature the highest weight loss



occurred.  This data is presented in Table 2-30.  Figures 2-4 and



2-5 present this data graphically.



     Tables 2-31 through 2-33 present data comparing particulate



concentrations determined from sampling at two different tempera-



tures  [177°C (350°F) versus 121°C (250°F), but analyzing after



heat treatment at 177°C (350°F); 204°C (400°F) versus 121°C



(250°F), but analyzed after heat treatment at 204°C  (400°F); and



316°C  (600°F) versus 121°C (250°F) but analyzing after treatment



at 316°C  (600°F)] for NCOG underfiring.  Tables 2-34 through 2-36



present these data for DCOG underfiring.
                               2-41

-------
TABLE  2-28.  RESULTS OF  SEQUENTIAL  HEATING  OF SELECTED NCOG
               UNDERFIRING TEST SERIES SAMPLES
Sequential
heating
Temperature,
°C («F)
Time,
h
Participate weight
Front-half Hnse
mg
% weight
loss
Filter
mg
X weight
loss
Total
mg
I weight
loss
                         Sampling Train 1.5
Ambient
177 (350)
177 (350)
204 (400)
204 (400)
316 (600)
_
2
4
2
4
2
82.3
26.1
21.6
17.8
15.6
12.5
.
68
74
78
81
85
53.0
21.4
20.1
19.5
18.9
18.0
_
60
62
63
64
66
135.3
47.5
41.7
37.3
34.5
30.5
^
65
69
72
74
77
                         Sampling Train 2.5
Ambient
177 (350)
177 (350)
204 (400)
204 (400)
316 (600)
•
2
4
2
4
2
62.8
18.4
15.5
14.4
13.3
10.3
.
71
75
77
79
83
28.1
15.6
15.2
14.8
14.4
12.2
_
44
46
47
49
56
90.9
34.0
30.7
29.2
27.7
22.5
»
63
66
68
69
75
                         Sampling Train 3.5
Ambient
177 (350)
177 (350)
204 (400)
204 (400)
316 (600)
_
2
4
2
4
2
74.5
10.6
8.6
8.4
7.8
5.6
_
86
88
89
89
92
96.7
18.4
18.2
17.8
17.4
16.4
_
81
81
82
82
83
171.2
29.0
26.8
26.2
25.2
22.0
•
83
84
85
85
87
                         Sampling Train 4.5
Ambient
177 (350)
177 (350)
204 (400)
204 (400)
316 (600)
_
2
4
2
4
2
59.8
34.8
29.8
22.4
16.8
14.0
.
42
50
62
72
77
114.7
102.5
99.0
90.0
87.9
85.0
.
11
14
21
23
26
174.5
137.3
128.8
112.4
104.7
99.0
w
21
26
35
40
43
                          Sampling Train 5.5
Ambient
177 (350
177 (350
204 (400
204 (400
316 600





.
2
4
2
4
2
117.0
27.6
24.7
17.9
17.4
10.9
_
76
79
85
87
91
103.2
22.8
19.5
18.3
17.6
16.8
.
78
81
82
83
84
221.0
50.4
44.2
36.2
32.3
27.7
^
77
80
84
85
87
                          Sampling Train 6.5
Ambient
177 (350)
177 (350)
204 (400)
204 (400)
316 (600)
—
2
4
2
4
2
108.1
28.6
25.9
21.9
19.8
16.5
.
73
76
80
82
85
87.6
13.7
11.7
11.3
10.5
9.3
.
84
87
87
88
89
195.7
42.3
37.6
33.2
30.3
25.8
_
78
81
83
84
87
                               2-42

-------
TABLE  2-29.   RESULTS OF SEQUENTIAL HEATING OF SELECTED DCOG
                UNDERFIRING TEST  SERIES SAMPLES
Sequential
heating
Temperature,
•C (°F)
Time,
h
Participate weight
Front-hal? Hnse
mg
% weight
loss
Filter
mg
* weight
loss
Total
mg
% weight
loss
                         Sampling Train D1.5
Ambient
177
177
204
350)
350)
400)
204 (400)
316 (600)
—
2
4
2
4
2
18.0
B.4
7.9
5.4
5.4
3.8
m
53
56
70
70
79
14.6
13.4
13.2
11.4
11.0
10.8
m
8
9
22
25
26
32.6
21.8
21.1
16.8
16.4
14.6
—
33
35
48
50
55
                         Sampling Train 02.5
Ambient
177 (350)
177 (350)
204 (400)
204 (400)
316 (600)
.
2
4
2
4
2
24.4
11.0
9.3
8.9
8.0
6.2
.
55
62
63
67
74
16.7
12.4
9.9
9.9
9.7
6.9
.
26
41
41
42
47
41.1
23.4
19.2
18.8
17.7
15.1
.
43
53
54
57
63
                         Sampling Train D3.5
Ambient
177 (350)
177 (350)
204 (400)
204 (400)
316 (600)
.
2
4
2
4
2
18.9
7.3
6.0
5.3
5.3
4.2
_
61
68
72
72
78
16.1
14.9
13.9
10.4
10.4
9.2
_
7
14
35
35
43
35.0
22.2
19.9
15.7
15.7
13.4
—
36
43
55
55
62
                         Sampling Train 04.5
Ambient
177 (350)
177 (350)
204 (400)
204 (400)
316 (600)
_
2
4
2
4
2
19.6
13.4
13.1
7.6
7.6
6.0
_
32
33
61
61
69
11.6
8.3
7.1
7.5
7.3
6.3
_
28
39
35
37
46
31.2
21.7
20.2
15.1
14.9
12.3
.
30
35
52
52
60
                          Sampling Train 05.5
Ambient
177
177
204
204
350)
350)
400)
400)
316 (600)
_
2
4
2
4
2
9.5
2.6
2.5
2.5
2.5
1.4
_
72
74
74
74
85
6.4
4.3
2.8
2.0
2.0
1.0
_
33
56
69
69
84
15.9
6.9
5,3
4.5
4.5
2.4
_
57
67
72
72
85
                         Sampling Train 06.5
Ambient
177 (350)
177 (350)
204 (400)
204 (400)
316 (600)
_
2
4
2
4
2
12.6
8.4
7.8
6.5
6.5
1.0
.
33
38
48
48
92
7.3
5.2
5.0
5.0
4.8
3.4
.
29
31
31
34
53
19.9
13.6
12.8
11.5
11.3
4.4
.
32
36
42
43
78
                               2-43

-------
                                        TABLE 2-30.  RESULTS OF SEQUENTIAL HEATING OF
                                 SELECTED NCOG UNDERFIRING TEST SERIES RUN 8.5, FRONT HALF
Sequential
heating
Temperature,
°C (°F)
Ambient
135 (275)
149 (300)
163 (325)
177 (350)
204 (400)
316 (600)
Time,
h
-
2
4
2
4
2
4
2
4
2
4
2
Particulate weight
Front-half rinse
mg
85.4
32.3
23.9
22.1
20.1
18.7
17.6
15.7
15.3
11.3
10.0
6.4
% weight
loss
-
62
72
74
76
78
79
82
82
87
88
92
Filter
mg
98.5
43.2
42.8
42.4
42.3
42.3
42.3
42.2
42.1
41.6
40.9
39.2
% weight
loss
-
56
56
57
57
57
57
57
57
58
58
60
Total
mg
183.9
75.5
66.7
64.5
62.4
61.0
59.9
57.9
57.4
52.9
50.9
45.6
% weight
loss
-
59
64
65
66
67
67
68
69
71
72
75
Source concentration
mg/m
129.5
53.2
47.0
45.4
43.9
43.0
42.2
40.8
40.4
37.2
35.8
32.1
gr/dscf
0.056
0.023
0.021
0.020
0.019
0.019
0.018
0.018
0.017
0.016
0.016
0.014
NJ
I

-------
            100
                                                 I   I    I   I      I
I
•fc.
Ul
         I/O
UJ
on
             90
             80
         £   70
             60
                                                                                       RINSE
                                                I    I   I    I
                0
                                       135149163177   204
315
                                          HEAT CONDITIONING TEMPERATURE,  °C
                            Figure  2-4.  Average  percent  weight  loss  from  Sampling  Train  5,
                            121°C (250°F)  front-half  temperature, due to heat  conditioning
                                         prior  to weighing  (MCOG underfiring).

-------
100
 90
 80
 70
 60
 50
 40
 30
 20
 10
                                    O
                                     I
                                          I
                                                           RINSE
                                    177   204

                       HEAT CONDITIONING TEMPERATURE, *C
315
Figure 2-5.   Average percent weight  loss from Sampling  Train 5,
121°C (250°F)  front-half temperature,  due to heat conditioning
              prior to weighing  (DCOG underfiring).

                                 2-46

-------
"TABLE 2-31.  COMPARISON OF PARTICIPATE  CONCENTRATIONS  DETERMINED
FROM SAMPLING AT TWO DIFFERENT TEMPERATURES  UNDER  NCOG UNDERFIRING
   CONDITIONS:   177°C (350°F)  VS.  121°C (250°F) BUT ANALYZING
                AFTER TREATMENT AT 177°C (350°F)
Test No.
1.2
1.3
1.4
1.5
2.5
3.2
3.3
3.4
3.5
4.3
4.4
4.5
5.2
5.3
5.4
5.5
6.5
Date
(1981)
10/27
10/27
10/27
10/27
10/27
10/28
10/28
10/28
10/28
10/28
10/28
10/28
10/29
10/29
10/29
10/29
10/29
Actual filter
temperature,
°C (°F)
125 (257)
170 (338)
169 (336)
128 (263)
125 (257)
127 (260)
178 (353)
169 (336)
109 (229)
177 (350)
169 (337)
130 (266)
123 (254)
176 (349)
186 (366)
116 (240)
119 (246)
Sequential
heating
temperature,
°C (°F)
177 (350)
No
No
177 (350)
177 (350)
177 (350)
177 (350)
177 (350)
No
No
177 (350)
177 (350)
No
No
177 (350)
177 (350)
177 (350)
No
No
177 (350)
177 (350)
177 (350)
177 (350)
Heating
time, h
2
-
-
2
4
2
4
2
-
-
2
4
-
-
2
4
2
-
-
2
4
2
4
Front-half catch
particulate
mg
55.2
72.9
50.6
47.5
41.7
34.0
30.7
34.2
87.3
40.3
29.0
26.8
61.1
78.4
137.3
128.8
36.8
50.5
32.1
50.4
44.2
42.3
37.6
mg/m3
33.0
43.4
30.8
33.0
29.0
22.7
20.5
20.6
53.6
25.5
16.9
15.6
65.7
92.2
63.0
59.1
24.5
33.0
22.4
31.3
27.4
25.6
22.8
gr/dscf
0.014
0.019
0.013
0.014
0.013
0.010
0.009
0.009
0.023
0.011
0.007
0.007
0.028
0.040
0.028
0.026
0.011
0.014
0.010
0.014
0.012
0.011
0.010
                               2-47

-------
TABLE .2-32.   COMPARISON OF PARTICULATE CONCENTRATIONS  DETERMINED
FROM SAMPLING AT TWO DIFFERENT TEMPERATURES UNDER NCOG UNDERFIRING
   CONDITIONS:  204°C (400°F)  VS.  121 °C (250°F)  BUT ANALYZING
                AFTER TREATMENT AT 204°C (400°F)
Test No.
1.5
2.2
2.3
2.4
2.5
3.5
4.2
4.5
5.5
6.2
6.3
6.4
6.5
Date
(1981)
10/27
10/27
10/27
10/27
10/27
10/28
10/28
10/28
10/29
10/29
10/29
10/29
10/29
Actual filter
temperature,
°C (°F)
128 (263)
128 (263)
198 (389)
207 (404)
125 (257)
109 (229)
130 (266)
130 (266)
116 (240)
126 (258)
193 (379)
208 (407)
119 (246)
Sequential
heating
temperature,
°C (°F)
204 (400)
204 (400)
204 (400)
No
No
204 (400)
204 (400)
204 (400)
204 (400)
204 (400)
204 (400)
204 (400)
204 (400)
204 (400)
204 (400)
No
No
204 (400)
204 (400)
Heating
time, h
2
4
2
-
-
2
4
2
4
2
2
4
2
4
2
-
-
2
4
Front-half catch
particulate
mg
37.3
34.5
24.8
46.3
61.3
29.2
27.7
26.2
25.2
41.7
112.4
104.7
36.2
32.3
24.2
34.3
26.9
33.2
30.3
mg/m3
25.9
24.0
16.5
31.7
42.6
19.5
18.5
15.2
14.6
47.4
51.6
48.0
22.5
20.1
15.7
22.6
20.8
20.1
18.4
gr/dscf
0.011
0.010
0.007
0.014
0.019
0.008
0.008
0.007
0.006
0.021
0.022
0.021
0.010
0.009
0.007
0.010
0.009
0.009
0.008
                                2-48

-------
TABLE 2-33.  COMPARISON OF PARTICULATE CONCENTRATIONS DETERMINED
FROM SAMPLING AT TWO DIFFERENT TEMPERATURES UNDER NCOG UNDERFIRING
   CONDITIONS:  316°C (600°F)  VS.  121°C (250°F)  BUT ANALYZING
                AFTER TREATMENT AT 315°C (600°F)
Test No.
1.5
1.6
2.5
2.6
3.5
3.6
4.5
4.6
5.5
5.6
6.5
6.6
Date
(1981)
10/27
10/27
10/27
10/27
10/28
10/28
10/28
10/28
10/29
10/29
10/29
10/29
Actual filter
temperature,
°C (°F)
128 (263)
320 (608)
125 (257)
316 (600)
109 (229)
293 (560)
130 (260)
328 (622)
116 (240)
324 (616)
119 (246)
302 (576)
Sequential
heating
temperature,
°C (°F)
316 (600)
No
316 (600)
No
316 (600)
No
316 (600)
No
316 (600)
No
316 (600)
No
Heating
time, h
2
-
2
-
2
-
2
-
2
-
2
-
Front-half catch
particulate
mg
30.5
27.0
22.5
39.5
22.0
36.0
99.0
69.7
27.7
24.9
25.8
30.9
mg/m3
21.2
19.0
15.0
23.9
12.8
19.6
45.4
62.8
17.2
16.2
15.6
19.6
gr/dscf
0.009
0.008
0.006
0.010
0.006
0.008
0.020
0.027
0.008
0.007
0.007
0.008
                                2-49

-------
TABLE 2-34. ,'  COMPARISON OF PARTICULATE CONCENTRATIONS  DETERMINED
FROM SAMPLING AT TWO DIFFERENT TEMPERATURES  UNDER  DCOG UNDERFIRING
   CONDITIONS:  177°C (350°F)  VS.  121°C (250°F)  BUT  ANALYZING
                AFTER TREATMENT AT 177°C (350°F)
Test No.
Dl.l
D1.2
D1.3
D1.4
D2.2
D2.3
D2.4
D2.5
D3.5
D4.5
D5.2
D5.3
D5.4
D5.5
D6.5
Date
(1981)
12/8
12/8
12/8
12/8
12/10
12/10
12/10
12/10
12/11
12/12
12/12
12/12
12/12
12/12
12/13
Actual filter
temperature,
°C (°F)
119 (246)
133 (272)
190 (374)
167 (333)
109 (229)
184 (363)
197 (387)
126 (258)
123 (254)
128 (263)
127 (261)
181 (357)
177 (351)
122 (251)
131 (267)
Sequential
heating
temperature,
°C (°F)
177 (350)
177 (350)
-
-
177 (350)
-
-
177 (350)
177 (350)
177 (350)
177 (350)
-
-
177 (350)
177 (350)
Heating
time, h
2
4
2
-
-
2
-
-
2
4
2
4
2
4
2
-
-
2
4
2
4
Front-half catch
participate
mg
21 ;8
21.1
22.0
34.0
43.3
24.6
34.8
37.2
23.4
19.2
22.2
19.9
21.7
20.2
8.7
16.3
19.1
6.9
5.3
13.6
12.8
mg/mj
17.4
16.9
19.6
29.3
38.7
13.8
20.4
20.8
12.7
10.4
12.4
11.1
12.4
11.5
5.0
10.4
11.9
4.1
3.1
7.4
7.0
gr/dscf
0.008
0.007
0.008
0.013
0.017
0.006
0.009
0.009
0.005
0.004
0.005
0.005
0.005
0.005
0.002
0.004
0.005
0.002
0.001
0.003
0.003
                              2-50

-------
TABLE 2-35.  COMPARISON OF PARTICULATE  CONCENTRATIONS  DETERMINED
FROM SAMPLING AT TWO DIFFERENT TEMPERATURES  UNDER  DCOG UNDERFIRING
   CONDITIONS:   204°C (400°F)  VS.  121°C (250°F)  BUT  ANALYZING
                AFTER TREATMENT AT 204°C (400°F)
Test No.
Dl.l
D2.5
D3.2
D3.3
D3.4
D3.5
D4.2
D4.3
D4.5
D5.5
D6.2
D6.3
D6.4
D6.5
Date
(1981)
12/8
12/10
12/11
12/11
12/11
12/11
12/12
12/12
12/12
12/12
12/13
12/13
12/13
12/13
Actual filter
temperature,
°C (°F)
119 (246)
126 (258)
132 (270)
211 (411)
204 (400)
123 (254)
126 (259)
209 (409)
128 (263)
122 (251)
120 (248)
204 (399)
219 (427)
131 (267)
Sequential
heating
temperature,
°C (°F)
204 (400)
204 (400)
204 (400)
-
-
204 (400)
204 (400)
-
204 (400)
204 (400)
204 (400)
-
-
204 (400)
Heating
time, h
2
4
2
4
2
-
-
2
4
2
-
2
4
2
4
2
-
-
2
4
Front-half catch
particulate
mg
16.8
16.4
18.8
17.7
18.1
30.9
38.7
15.7
15.7
13.5
24.8
15.1
14.9
4.5
4.5
5.4
15.6
12.0
11.5
11.3
mg/mj
13.4
13.1
10.2
9.6
11.2
22.1
26.9
8.8
8.8
8.0
16.6
8.6
8.5
2.7
2.7
3.5
10.8
8.0
6.3
6.2
gr/dscf
0.006
0.006
0.004
0.004
0.005
0.010
0.012
0.004
0.004
0.003
0.007
0.004
0.004
0.001
0.001
0.001
0.005
0.004
0.003
0.003
                              2-51

-------
     TABLE  2-36.   COMPARISON  OF PARTICULATE  CONCENTRATIONS  DETERMINED
     FROM SAMPLING AT TWO  DIFFERENT  TEMPERATURES  UNDER  DCOG UNDERFIRING
        CONDITIONS:   316°C (600°F) VS.  121 °C (250°F)  BUT ANALYZING
                     AFTER TREATMENT AT 316°C (600°F)
Test No.
Dl.la
D1.6
D2.5
D2.6
D3.5
D3.6
D4.5
D4.6
D5.5
D5.6
D6.5
D6.6
Date
(1981)
12/8
12/8
12/10
12/10
12/11
12/11
12/12
12/12
12/12
12/12
12/13
12/13
Actual filter
temperature,
°C (°F)
119 (246)
268 (515)
126 (258)
298 (569)
123 (254)
280 (536)
128 (263)
325 (617)
122 (251)
316 (600)
131 (267)
319 (607)
Sequential
heating
temperature,
°C (°F)
316 (600)
-
316 (600)
-
316 (600)
-
316 (600)
-
316 (600)
-
316 (600)
-
Heating
time, h
2
-
2
-
2
-
2
-
2
-
2
-
Front-half catch
particulate
mg
14.6
27.3
15.1
30.3
13.4
25.5
12.3
17.5
2.4
12.9
4.4
9.2
mg/m-*
11.7
28.4
8.2
18.0
7.5
14.8
7.0
10.5
1.4
8.0
2.4
6.3
gr/dscf
0.005
0.012
0.003
0.008
0.003
0.006
0.003
0.004
0.001
0.003
0.001
0.003
aD1.5 was void run sequential  heating  procedure  done  on  Dl.l.
                                    2-52

-------
2.4  PARTICULATE SULFATE



     Acetone rinse residues and filters were analyzed for isopro-



panol (IPA) soluble sulfate (acid sulfate) and water soluble



sulfate (inorganic sulfate).   Tables 2-37 and 2-38 summarize the



acid sulfate concentrations determined for the NCOG and DCOG test



series.   The IPA extractable acid sulfate concentration is pre-



sented as H-SO. in mg/m .   Assuming that the acid sulfate is



hydrated H_SO., the resulting concentration is presented as



H-SO.(H-O)_ in mg/m .   Nonsulfate particulate concentration is



determined by subtracting the H-SO.(H-O)2 concentration from the



total particulate concentration.



     No water soluble sulfates were found on particulate col-



lected during NCOG underfiring.  A few outliers were attributed



to incomplete IPA extraction.  Water soluble sulfate data for the



NCOG test series is presented in Appendix C.  The water soluble



sulfate found on particulate collected during the DCOG tests are



presented in Table 2-38 as S0,= in mg/m .
                              2-53

-------
      TABLE 2-37.   SUMMARY  OF PARTICULATE  AND ACID SULFATE  RESULTS FOR THE  NCOG  UNDERFIRING TEST SERIES


Test
No.
.1
.2

.3
.4
.5

1.6
2.1
2.2

2.3
2.4
2.5

2.6
3.1
3.2

3.3
3.4
3.5

3.6
4.1
4.2

4.3
4.4
4.5

4.6
5.1
5.2

5.3
5.4
5.5

5.6
6.1
6.2

6.3
6.4
6.5

6.6
Average
filter
temperature.
°C («F)
122 (252)
125 (257)

170 (338)
169 (336)
128 (263)

320 (608)
119 (247)
128 (263)

198 (389)
207 (404)
125 (257)

316 (600)
113 (236)
127 (260)

178 (353)
169 (336)
109 (229)

293 (560)
123 (254)
130 (266)

177 (350)
169 (337)
130 (266)

328 (622)
124 (255)
123 (254)

176 (349)
186 (366)
116 (240)

324 (616)
119 (246)
126 (258)

193 (379)
208 (407)
119 (246)

302 (576)

Conditioning
temperature.
"C (°F)
Ambient
Ambient
177 (350)
Ambient
Ambient
Ambient
316 (600)
Ambient
Ambient
Ambient
204 (400)
Ambient
Ambient
Ambient
316 (600)
Ambient
Ambient
Ambient
177 (350)
Ambient
Ambient
Ambient
316 (600)
Ambient
Ambient
Ambient
204 (400)
Ambient
Ambient
Ambient
316 (600)
Ambient
Ambient
Ambient
177 (350)
Ambient
Ambient
Ambient
316 (600)
Ambient
Ambient
Ambient
204 (400)
Ambient
Ambient
Ambient
316 (600)
Ambient
Concentration, nra/m


Rinse
57.7
56.2
19.3
24.7
16.5
57.2
8.7
8.5
49.9
54.1
6.0
22.9
34.0
41.9
6.9
14.1
59.7
37.7
9.0
40.8
12.9
43.3
3.3
10.3
64.9
63.3
14.5
32.2
57.9
27.4
6.4
14.7
50.0
67.6
12.4
20.5
10.8
73.2
6.8
6.6
62.7
65.1
7.0
12.4
9.8
65.5
10.0
12.6
Participate
Filter
71.2
59.2
13.8
18.7
14.3
36.8
12.5
10.5
65.3
45.4
10.5
8.8
8.6
18.7
8.1
9.8
55.7
56.8
11.6
12.8
12.6
56.2
9.5
9.3
76.4
65.3
32.9
33.5
34.9
52.6
39.0
48.1
34.5
56.1
12.1
12.5
11.6
64.1
10.4
9.6
49.5
32.8
8.7
10.2
11.0
53.1
5.6
7.0
Total
128.9
115.4
33.1
43.4
30.8
94.0
21.2
19.0
115.2
99.5
16.5
31.7
42.6
60.6
15.0
23.9
115.4
94.5
20.6
53.6
25.5
99.5
12.8
19.6
141.3
128.6
47.4
65.7
92.2
80.0
45.4
62.8
84.5
123.7
24.5
33.0
22.4
137.3
17.2
16.2
112.2
97.9
15.7
22.6
20.8
118.6
15.6
19.6
Acid su

Rinse
21.7
.
4.4
5.8
1.3
.
0.0
0.0
22.1
.
0.0
8.3
10.0
.
0.0
1.6
23.1
.
0.0
14.8
2.3
.
0.0
2.3
23.2
.
0.4
6.9
11.8
.
0.0
0.0
39.9
.
2.0
6.2
0.0
.
0.0
0.0
29.0
.
0.0
1.8
0.0
.
0.0
0.0
H?SOd
Filter
24.6
-
0.0
0.0
1.6
-
0.0
0.0
16.6
-
0.0
0.0
0.0
-
0.0
0.0
17.1
.
0.0
0.7
0.0
.
0.0
0.0
24.7
.
0.0
0.0
3.0
-
0.0
0.0
12.3
-
0.0
0.0
0.0
.
0.0
0.0
14.3
.
0.0
0.0
0.0
_
0.0
0.0
Total
46.3
-
4.4
5.8
2.9
-
0.0
0.0
38.7
.
0.0
8.3
10.0
-
0.0
1.6
40.2
.
0.0
15.5
2.3
.
0.0
2.3
47.9
.
0.4
6.9
14.8
-
0.0
0.0
52.2
-
2.0
6.2
0.0
-
0.0
0.0
43.3
.
0.0
1.8
0.0
.
0.0
0.0
fate
H?SOa(H70
Rinse
29.7
.
6.1
8.0
1.7
-
0.0
0.0
30.2
-
0.0
11.4
13.7
-
0.0
2.1
31.6
-
0.0
20.2
3.2
.
0.0
3.1
31.8
.
0.6
9.4
16.1
-
0.0
0.0
54.6°
-
2.7
8.5
0.0
.
0.0
0.0
39.7
.
0.0
2.5
0.0
.
0.0
0.0
Filter
33.6
-
0.0
0.0
2.2
.
0.0
0.0
22.8
-
0.0
0.0
0.0
.
0.0
0.0
23.4
.
0.0
1.0
0.0
-
0.0
0.0
33.8
_
0.0
0.0
4.2
-
0.0
0.0
16.7
-
0.0
0.0
0.0
-
0.0
0.0
19.5
.
0.0
0.0
0.0
-
0.0
0.0
?
Total
63.3
-
6.1
8.0
3.9
.
0.0
0.0
53.0
.
0.0
11.4
13.7
.
0.0
2.1
55.0
-
0.0
21.2
3.2
.
0.0
3.1
65.6
.
0.6
9.4
20.3
-
0.0
0.0
71.3
-
2.7
8.5
0.0
-
0.0
0.0
59.2
.
0.0
2.5
0.0
.
0.0
0.0
Honsulfate
paniculate
Rinse
28.0
.
13.2
16.7
14.8
.
8.7
8.5
19.7
.
6.0
11.5
20.3
.
6.9
12.0
28.1
.
9.0
20.6
9.7
.
3.3
7.2
33.1
.
13.9
22.8
41.8
.
6.4
14.7
-4.6
-
9.7
12.0
10.8
-
6.8
6.6
23.0
.
7.0
9.9
9.8
.
10.0
12.6
Filter
37.6
-
13.8
18.7
12.1
.
12.5
10.5
12.3
.
10.5
8.8
8.6
.
8.1
9.8
32.3
.
11.6
11.8
12.6
.
9.5
9.3
42.6
.
32.9
33.5
30.7
.
39.0
48.1
17.8
-
12.1
12.5
11.6
-
10.4
9.6
30.0
.
8.7
10.2
11.0
.
5.6
7.0
Total
65.6
.
27.0
35.4
26.9
.
21.2
19.0
32.0
.
16.5
20.3
28.9
.
1S.O
21.8
60.3
.
20.6
32.4
22.3
.
12.8
16.5
75.7
.
46.8
56.3
72.5
.
45.4
62.8
13.2
-
21.8
24.5
22.4
-
17.2
16.2
53.0
.
15.7
20.1
20.8
.
15.6
19.6

HfSOj
Back-half
5.0
S.6
.
38.9
34.1
.
NAah
426.8b
466a
10.7
_
36.3
13.6
.
M
95.2
4.7
5.2
.
41.2
56.4
NA
.
89.1
11.6
13.5
.
32.0
12.2
-
NA
66.4
21.0
NA
-
53.3
NA
.
NA
83.8
14.6
NA
.
64.2
.
.
.
72.8
Total
51.3

.
44.7
37.0

.
-

.
.
47.7
23.6
.
.
96.8
44.9
.
.
56.7
58.7
.
.
91.4
59.5

-
38.9
27.0
-
-
66.4
73.0
-
-
59.5
-
-
-
83.8
57.9
-
.
66.0
-
-
-
72.8
Ul
          *N/A . Not analyzed.
           Contaminated with hydrogen peroxide.
          cMost likely hydrated with less than two H20 per H?S04 molecule.

-------
       TABLE 2-38.  SUMMARY OF PARTICULATE AND ACID  SULFATE  RESULTS FOR THE DCOG  UNDERFIRING TEST SERIES
Test
No.
01. 1
01.2
01. 3
01. 4
01.6
02. 1
02.2
02.3
02.4
02.5
02.6
03. 1
03. 2
03.3
03.4
03.5
03.6
04.1
04.2
04.3
04.5
04.6
05.1
05.2
05.3
05.4
05.6
06.1
06.2
06.3
06.4
06.5
06.6
Average
filter
temperature,
°C (°F)
119 (246)
133 (272)
190 (374)
167 (333)
268 (515)
118 (244)
109 (229)
184 (363)
197 (387)
126 (258)
298 (569)
120 (248)
132 (270)
211 (411)
204 (400)
123 (254)
280 (536)
148 (299)
126 (259)
209 (409)
128 (263)
325 (617)
123 (253)
127 (261)
181 (357)
177 (351)
316 (600)
132 (270)
120 (248)
204 (399)
219 (427)
131 (267)
219 (607)
Conditioning
temperature.
•C (°F)
Ambient
316 (600)
Ambient
177 (350)
Ambient
Ambient
Ambient
Ambient
Ambient
177 (350)
Ambient
Ambient
Ambient
316 (600)
Ambient
Ambient
Ambient
204 (400)
Ambient
Ambient
Ambient
316 (600)
Ambient
Ambient
Ambient
204 (400)
Ambient
Ambient
316 (600)
Ambient
Ambient
Ambient
177 (350)
Ambient
Ambient
316 (600)
Ambient
Ambient
Ambient
204 (400)
Ambient
Ambient
Ambient
316 (600)
Ambient
Concentration, ma/m
Participate
Rinse
14.4
3.0
19.8
6.7
14.8
21.1
15.8
73.4b
14.1
7.0
12.3
14.5
13.3
3.4
8.7
18.1
12.0
3.9
13.1
19.0
10.5
2.3
9.7
10.8
21.8
4.8
11.0
11.2
3.4
7.3
10.2
8.5
3.2
7.0
9.4
0.8
4.9
4.6
9.1
1.1
7.4
5.3
6.9
0.5
4.7
Filter
11.7
8.7
13.8
12.9
14.5
17.6
12.6
5.1
7.4
6.8
8.1
6.3
9.0
4.8
9.3
8.0
9.3
7.3
9.0
7.9
9.1
5.2
5.1
6.1
4.9
3.2
5.6
6.6
3.6
3.2
3.2
3.0
1.8
3.4
2.5
0.6
3.1
3.2
4,4
2.4
3.4
2.7
4.0
1.9
1.6
Total
26.1
11.7
33.4
19.6
29.3
38.7
28.4
178.5b
21.5
13.8
20.4
20.8
22.3
8.2
18.0
26.1
21.3
11.2
22.1
26.9
19.6
7.5
14.8
16.9
26.7
8.0
16.6
17.8
7.0
10.5
13.4
11.5
5.0
10.4
11.9
1.4
8.0
7.8
13.5
3.5
10.8
8.0
10.9
2.4
6.3

H7SO*
Rinse
0.0
1.2
0.0
0.0
0.0
1.0
1.0
0.5
0.3
0.0
0.0
0.3
0.1
0.0
1.8
0.0
0.0
0.0
0.0
0.6
0.0
0.0
2.6
0.4
1.9
0.5
0.0
0.2
0.0
0.0
1.0
0.0
0.0
0.2
Fl
0
1
0
0
0
0
1
0
0
0
<0
0.
1
0
0
0
0
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
Su
H?0
ter
0
2
0
0
0
0
0
0
0
0
3
0
4
0
0
0
0
0
0
0
0
0
0
2
0
0
0
0
0
0
0
0
0
0
2
Total
0.0
2.4
0.0
0.0
0.0
1.0
2.0
0.5
0.3
0.0
<0.3
0.3
1.5
0.0
1.8
0.0
0.0
0.0
0.0
0.6
0.0
0.0
2.6
0.6
1.9
0.5
0.0
0.2
0.0
0.0
1.0
0.0
0.0
0.2
fate
sor
Rinse
0.0
1.9
2.1
0.0
1.7
0.6
1.1
2.0
2.7
0.0
:0.0
4.0
0.0
2.9
0.5
0.5
1.3
0.0
0.5
2.1
0.0
0.0
2.1
1.0
1.0
2.4
3.0
0.9
0.0
0.0
0.0
0.0
0.0
0.0
Filter
<0.2
Void
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
<0.2
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Total
<0.2
1.9
2.1
0.0
1.7
0.6
1.1
2.0
2.7
0.0
<0.2
4.0
0.0
2.9
0.5
0.5
1.3
0.0
0.5
2.1
0.0
0.0
2.1
1.0
1.0
2.4
0.0
0.9
0.0
0.0
0.0
0.0
0.0
0.0
Total
<0.2
4.3
2.1
0.0
1.7
1.6
3.1
2.5
3.0
0.0
<0.5
4.3
1.5
2.9
2.3
0.5
1.3
0.0
0.5
2.7
0.0
0.0
4.7
1.6
2.9
2.9
0.0
1.1
0.0
0.0
1.0
0.0
0.0
0.2
Nonsulfate
Dartlcula e
Rinse
3.0
3.6
12.7
21.1
15.8
171.8
4.9
9.8
11.5
3.4
8.7
17.8
3.8
13.1
16.7
2.3
9.7
10.8
4.3
8.3
3.4
7.3
5.5
1.8
4.1
6.5
0.8
3.8
4.6
1.1
6.4
5.3
0.5
4.5
Filter
8.5
11.7
14.5
17.6
10.9
5.1
5.8
8.1
6.3
4.8
8.8
4.0
5.9
6.1
7.9
4.7
3.8
6.1
3.2
5.6
3.6
3.2
3.2
1.6
3.4
2.5
0.6
3.1
3.2
2.4
3.4
2.7
1.9
1.6
Total
11.5
15.3
27.2
38.7
26.7
176.9b
10.7
17.9
17.8
8.2
17.5
21.8
9.7
U.2
24.6
7.0
13.5
16.9
7.5
13.9
7.0
10.5
8.7
3.4
7.5
10.0
1.4
7.9
7.8
3.5
9.8
8.0
2.4
6.1
H7SOi
Front-
half
0.0
1.7
0.0
0.0
0.0
0.7
1.5
0.3
0.2
0.0
<0.2
0.2
1.1
0.0
1.3
0.0
0.0
0.0
0.0
0.5
0.0
0.0
1.9
0.5
1.4
0.4
0.0
0.2
0.0
0.0
0.7
0.0
0.0
7.9
TatfT
half
92.0a
3.1
8.0
8.2
6.6
9.8
8.1
&
NAC
6.4
56.8*
4.3
8.6
5.7
NA
7.4
25.0'
9.4
4.5
NAe.
74.7*
5.0
NA
5.0
NA
NA
5.1
8.5
NA
5.2
NA
NA
7.9
Total
92.0*
4.1
8.0
8.2
6.6
10.5
9.«
3os:2*
6.6
57.01
5.4
8.6
7.0
7.4
25.0*
9.4
5.0
;i.7«
6.9
6.4
5.3
8.5
5.9
8.0
Ul
         Hydrogen peroxide contaminated.
         Contaminated with oil.
         CNA « Not analyzed.

-------
2.5  DISCUSSION OF PARTICULATE RESULTS



     As shown in Figures 2-1 and 2-2 under similar front-half



temperatures and COG underfiring conditions particulate concen-



trations were consistent between runs.  During the NCOG test



series the particulate concentration decreased as the front-half



temperature increased.  This decrease was not as marked during



the DCOG test series.  Overall, the particulate concentration was



lower during DCOG underfiring than during NCOG underfiring, as



shown in Figure 2-3.



     Heat treatment of a particulate catch prior to gravimetric



analysis caused a loss of from 21 to 87 percent, depending on



heating temperature and time, sampling temperature, and type of



COG underfired.  As shown in Tables 2-28 through 2-30, more than



half of the total loss caused by a sequential heating takes place



at the first heating.



     The results presented in Tables 2-31 through 2-36 are graph-



ically depicted in Figures 2-6 and 2-7.  The data shows a con-



sistent difference between samples collected at a specified



temperature and samples collected at a lower temperature and



heated to the specified temperature prior to analysis.  The



sequentially heated results are always lower than the actual



filter temperature results.



     As shown in Tables 2-37 and 2-38 acid sulfate is a major



constituents of the particulate caught on a 121°C  (250°F) heated
                              2-56

-------
g

I
z
UJ
<_>
z
o
      50
      40
      30
   0

   §
      10
                                 O PART1CULATE FILTER TEMPERATURE

                                 • PARTICULATE FROM SEQUENTIAL HEATING

                                   (RUN 4 EXCLUDED)
                 177        204

                           AVERAGE FILTER TEMPERATURE, °C
                                                               316
Figure  2-6.   Comparison of  average participate concentration  determined
 from sampling at the specified temperature  and from sampling at 121°C
      (250°F)  and analyzing after sequentially heating at  specified
               temperatures  for NCOG underfiring conditions.
                                     2-57

-------
E

E
    o:
    o
    LJ
    O
    «r
    oc
        50
        40
        30
        20
        10
                                       O  PARTICULATE FILTER TEMPERATURE

                                       •  PARTICULATE FROM SEQUENTIAL HEATING
                   177       204

                           AVERAGE FILTER TEMPERATURE, °C
                                                               316
Figure  2-7.    Comparison of  average participate  concentration  determined
 from sampling at the specified  temperature and  from sampling  at 121°C
      (250°F)  and analyzing  after sequentially heating at specified
               temperatures for DCOG underfiring  conditions.
                                    2-58

-------
probe and filter collected during NCOG underfiring.  Sulfate had



a much smaller impact on particulate caught during DCOG under-



firing.  No water soluble sulfate was found on particulate col-



lected during NCOG underfiring.  A few outliers were attributed



to incomplete isopropanol extraction.



     Average particulate concentration versus average filter



temperature determined from actual sampling temperature, actual



sampling temperature with IPA extraction, and sampling at 171°C



(250°F) with sequential heating prior to analysis are depicted



graphically in Figures 2-8 and 2-9 for NCOG and DCOG underfiring,



respectively.  The data indicate actual sampling temperature will



yield a consistently higher concentration than from actual sam-



pling temperature with IPA extraction which will yield a con-



sistently higher concentration than from sequential heating prior



to analysis.  The data points averaged at the 177°C  (250°F)



filter heat were highly variable whereas the 204°C  (400°F) and



316°C  (600°F) filter heats yielded more consistent results.



2.5.1  Total Organic Carbon (Filterable) Results



     The TOC content of Sampling Train 5 [121°C (250°F) probe/fil-



ter heat] filters was determined by an oxidation/reduction tech-



nique.  The TOC content was negligible at all three purge tempera-



tures  [177°C (350°F), 232°C (450°F), and 316°C (600°F)] when



compared with the blank filter TOC content.  Air and nitrogen



purge blanks for the TOC recovery system averaged 0.9 mg TOC.



Filter blanks averaged 1.5 mg TOC/filter.  Sample filters aver-



aged between 1.0 and 2.0 mg TOC/filter.  A system recovery





                               2-59

-------
l_>
z
o
<
o.

UJ
ts
   50
   40
   30
   20
   10
                               ONONSULFATE PARTICIPATE AFTER IPA EXTRACTION

                               APARTICULATE SAMPLED AT 250 THEN HEATED

                               O PARTICIPATE FROM ACTUAL SAMPLING TEMPERATURE
               177        204


                         AVERAGE FILTER TEMPERATURE, *C
316
  Figure 2-8.   Comparison  of average participate concentration from

 actual  sampling  temperature, sequential heating, and IPA extraction

                    for NCOG underfiring conditions.
                                    2-60

-------
u
§
a:
a.
LU
o
s
     50
     40
     30
     20
     10
                                ONONSULFATE PARTICIPATE AFTER IPA EXTRACTION

                                A PARTICULATE SAMPLED AT 250 THEN HEATED

                                DPARTICULATE FROM ACTUAL SAMPLING TEMPERATURE
                177       204

                          AVERAGE FILTER TEMPERATURE, °C
316
 Figure 2-9.   Comparison of  average participate  concentration from
 actual sampling temperature,  sequential  heating,  and IPA  extraction
                   for DCOG underfiring  conditions.
                                     2-61

-------
efficiency of 99 percent was determined by treating a decane-



spiked filter (10 mg by gravimetric analysis) with the oxida-



tion/reduction technique.  Actual laboratory data is presented in



Appendix C.
                              2-6:

-------
2.6  DISCUSSION OF BACK-HALF RESULTS
     Sample trains consisted of either a Method 5 back-half for
condensible organics and inorganics determination or a Method 8
back-half for sulfuric acid mist and sulfur dioxide determina-
tion.
2.6.1  Sulfuric Acid Mist
     The amount of sulfuric acid measured in the back half of the
sample train during NCOG underfiring is related to the front half
filter/probe temperature.  The hotter the filter and probe, the
greater the amount of sulfuric acid mist collected in the back
half.  As the results in Tables 2-37 and 2-38 show, the total
sulfuric acid measured by different sampling trains seem to
correlate well.  This correlation was not as apparent during DCOG
underfiring where the amount of sulfur in the flue gas was
greatly reduced.
2.6.2  Sulfur Dioxide
     The measured SO2 concentration, which stayed relatively
constant throughout each test series, averaged 439 ppm during
NCOG underfiring and 33 ppm during DCOG underfiring.  Sulfur
dioxide concentration data were presented in Tables 2-6 through
2-27 for each individual run.
2.6.3  Condensible Organics and Inorganics
     The measured condensible organic concentration was constant
throughout both test series.  The ampule technique proved to be
much more sensitive than the ether/chloroform extraction.  High
biases  (attributed to isopropanol contamination) were observed by
the ampule technique but not by the ether/chloroform extraction.
                              2-63

-------
2.7  REDUCED SULFUR ANALYSIS BY METHOD 15



     Table 2-39 presents the results obtained through Method 15



analysis of SRU inlet COG during the NCOG and DCOG underfiring



test series.  Hydrogen sulfide (H-S) concentrations averaged 1915



ppm v/v during the NCOG test series, whereas carbonyl sulfide



(COS) averaged <17 ppm, and carbon disulfide (CS2) averaged 34



ppm for an average total reduced sulfur (TRS) concentration of



1961 ppm.  Hydrogen sulfide concentrations averaged 5086 ppm



during the DCOG test series, whereas COS averaged <7 ppm and CS2



averaged 80 ppm, for an average TRS concentration of 5112 ppm.



No changes in process operation or conditions (refer to Section



2.10) were recorded between the two test series to corroborate



the large difference in average TRS concentration.



     Table 2-40 presents the results obtained through Method 15



analysis of SRU outlet COG during the DCOG underfiring test



series.  The SRU was bypassed during NCOG underfiring; therefore,



no outlet data were collected.  Hydrogen sulfide concentrations



averaged 7 ppm at the SRU outlet during DCOG underfiring, whereas



COS averaged 19 ppm and CS~ averaged 20 ppm, for an average TRS



of 46 ppm.  Sulfur dioxide concentrations at the inlet and outlet



of the SRU averaged <3 ppm during both test series.



     Table 2-41 summarizes the results obtained through Method 15



analysis of No. 1 coke battery exit stack gas.   Hydrogen sulfide



concentrations averaged <3 ppm during NCOG underfiring; whereas



COS averaged <3 ppm CS_ averaged <2 ppm, for an average TRS of <8



ppm.  Hydrogen sulfide, carbonyl sulfide, and carbon disulfide






                              2-64

-------
    TABLE  2-39.  SUMMARY OF RESULTS OBTAINED THROUGH METHOD 15
                     ANALYSIS OF SRU INLET COG
Bag sample
collection
Date
(1981)
Time
Corresponding
participate
Run No.
Analysis
Date
(1981)
Time
Concentration, ppm
H2S
COS
CS2a
SO 2
TRS
                        NCOG TEST SERIES
10/27
10/27
10/28
10/28
10/29
10/29
10/30
10/30
0930
1430
0930
1605
0930
1400
1000
1500
1
2
3
4
5
6
7
8
10/27
10/28
10/27
10/28
10/30
10/28
10/28
10/28
10/29
10/29
10/30
10/30
1000
1354
1535
1442
1550
1036
1420
1642
1118
1454
1042
1606
Average
2000
2100
3800
1440
1800
1770
2200
1700
1500
1320
1590
1770
1915
130
<3
<3
<3
<3
<3
<3
<3
<3
<3
<3
<3
<17
44
48
31
34
39
40
40
39
32
<2
31
33
34
<3
<3
<3
<3
<3
<3
<3
<3
<3
<3
<3
<3
3
2174
2148
3831
1474
1839
1810
2240
1739
1532
1320
1621
1803
1961
                        DCOG TEST SERIES
12/8
12/9
12/10
12/10
12/11
12/11
12/11
1230
1150
1130
1455
0740
1215
1005
Dl
-
-
D2
-
D3
D4
12/8
12/10
12/10
12/10
12/11
12/11
12/12
1718
1318
1336
1712
1600
1624
1224
Average
2300
6600
8700
5700
4300
5600
2400
5086
<5
21
<5
<5
<5
<5
<5
<7
62
54
58
190
72
68
60
80
<6
<6
<6
<6
<6
<6
<6
<6
2362
6675
8758
5890
4372
5268
2460
5112
reported as S02 (twice C$2  value detected).
                                  2-65

-------
         TABLE  2-40.   SUMMARY OF RESULTS OBTAINED THROUGH METHOD 15
             ANALYSIS OF  SRU OUTLET COG DURING DCOG UNDERFIRING
Bag sample
collection
Date
(1981)
12/8
12/9
12/10
12/10
12/11
12/11
12/12
12/12
Time
1230
1150
1130
1455
0740
1215
0755
1005
Corresponding
participate
Run No.
Dl
-
-
D2
-
D3
-
D4
Analysis
Date
(1981)
12/8
12/9
12/10
12/10
12/10
12/11
12/11
12/12
12/11
12/11
12/12
Time
1412
1400.
1248°
1212
1624
1318
1436
1142
1412
1018
1054
Average
Concentration, ppm
H2S
112
6
<2
4
6
9
9
6
14
2
4
7
COS
25
21
18
20
20
18
18
20
19
19
19
19
cs2a
24
20
14
18
20
22
22
17
20
21
20
20
SO 2
<3
<3
<3
<3
<3
<3
<3
<3
<3
<3
<3
<3
TRS
61
47
32
42
46
46
49
43
53
42
43
46
JCS2  reported  as  S02  (twice CS2 value detected)
DNot  used  in average.
                                     2-66

-------
        TABLE 2-41.   SUMMARY OF RESULTS  OBTAINED  THROUGH  METHOD  15
               ANALYSIS OF NO.  1  COKE  BATTERY  EXIT  STACK  GAS
Bag sample
collection
Date
(1981)
Time
Corresponding
participate
Run No.
Analysis
Date
(1981)
Time
Concentration, ppm
H2S
COS
re a
CS2
SO 2
TRS
                             NCOG TEST SERIES
10/27
10/27
10/28
10/28
10/29
10/29
10/30
10/30
0930
1430
0930
1605
0930
1400
1000
1500
1
2
3
4
5
6
7
8
10/27
10/27
10/30
10/28
10/28
10/29
10/29
10/30
10/30
1200
1606
1436
1112
1706
1218
1600
1124
1736
Average
<3
<3
<3
<3
<3
<3
<3
<3
<3
<3
<3
<3
<3
<3
<3
<3
<3
<3
<3
<3
4
5
<2
<2
<2
<2
<2
<2
<2
<2
180
280
64
280
360
260
190
300
210
236
4
5
<8
<8
<8
<8
<8
<8
<8
<8
                             DCOG TEST  SERIES
12/8
12/10
12/11
12/12
1230
1330
1400
1030
Dl
D2
D3
D4
12/8
12/10
12/11
12/11
12/12
1500
1430
1536
1500
1106
Average
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<3
<2
<2
<2
7
18
3
<3
<3
9
<6
<6
<6
<6
<6
<6
CS2 reported as S02 (twice CS2 value detected).
                                    2-67

-------
concentrations all averaged <2 ppm during DCOG underfiring, for



an average TRS concentration of <6 ppm.



     According to Method 15 analysis, sulfur dioxide concentra-



tions averaged 236 ppm during NCOG underfiring and 9 ppm during



DCOG underfiring; however, Method 8 analysis showed an average



sulfur dioxide concentration of 439 ppm during NCOG underfiring



and 33 ppm during DCOG underfiring.



     Harmon Engineering and Testing provided analytical services



for determination of reduced-sulfur constituents of selected flue



gas samples by EPA Method 15.*  The major modification made to



Method 15 was the analysis of gas bag samples instead of the



usual gas samples continuously extracted via heat-traced Teflon



tubing.  The highly explosive nature of COG and the great distance



between the three sample sites necessitated this modification.



Method 15 uses gas chromatographic separation and flame photo-



metric detection to determine the reduced-sulfur constituents and



sulfur dioxide concentrations.



     The FPD used has a linear response range up to 70 ppm.



Self-absorption of the sulfur molecular light occurs at higher



concentrations and reduces the slope of the line.  Figure 2-10



presents a typical H.S calibration curve as the concentration



increases.  Having a dynamic dilution system prior to the sample



loop is the preferred method for staying in the FPD linear range.



Because the COG bag sample could not be diluted prior to analy-



sis, the sample loop size was reduced.  Reduction in sample size
*40 CFR 60, Appendix A, Reference Method 15, July 1980.




                               2-68

-------
  20,000


  10,000 -


   7,000 -


   5,000 -



   3,000 -


   2,000 -


o
1^

x  1,000
»/l

=i    700

-------
also lowers FPD sensitivity and accuracy.  Analysis of the COG



inlet sample required a factor of 22 reduction in sample loop



size over calibration loop size.  Because response was still



above the FPD linear response range, self-absorption of the



sulfur molecular light is the most likely reason for the high TRS



values resulting from the use of Method 15 at the SRU inlet.  As



self-absorption occurs and the slope of the response versus



concentration curve decreases, a relatively small increase in



response is interpreted as a large increase in concentration.



True calibration in this region of the curve is not possible.



The data show an increase in the COS concentration through the



SRU during DCOG underfiring.  This is most probably due to the



small sample loop used for inlet analysis, which was 22 times



smaller than the outlet (calibration) loop.
                               2-70

-------
2.8  GAS STREAM FLOW RATE AND COMPOSITION



     Tables 2-42 and 2-43 summarize the flue gas conditions data



collected at the No. 1 coke battery exit stack during the NCOG



and DCOG underfiring test series.  Actual volumetric flow rates



are expressed in cubic meters per hour (m /h) and actual cubic



feet per hour (acfh) at stack conditions.  Flow rates corrected



to standard conditions [20°C and 760 mmHg (68°F and 29.92 in.Hg)



and zero percent moisture] are expressed as dry normal cubic



meters per hour (dNm /h)  and dry standard cubic feet per hour



(dscfh).



     Prior to the first test run of each series a full velocity



traverse was performed.  Table 2-44 details the data collected



from these full velocity traverses.  Before the NCOG test series,



the volumetric flow rate averaged 45,845 dNm /h (1,619,014



dscfh), and the stack temperature averaged 240°C (464°F).  Prior



to the DCOG test series,  the volumetric flow rate was measured at



44,134 dNm /h (1,558,567 dscfh), and the stack temperature was



228°C  (443°F).



     The particulate sampling train nozzles were placed in the



stack at an accessible point of average velocity, as determined



by the preliminary velocity traverse.  This position was main-



tained throughout the test period.  Velocity head and stack



temperature were recorded every 10 minutes.  Sample trains were



operated simultaneously,  with few exceptions, within each run.



Tables 2-42 and 2-43 also contain all sample train start and stop



times.
                              2-71

-------
                 TABLE 2-42.   SUMMARY OF FLUE  GAS  CONDITIONS DURING NCOG UNDERFIRING TESTING
Run No.
1-1
1-2
1-3
1-4
1-5
1-6
Date
(1981)
10/27
Sampling
period
0910-1110
0914-1114
0910-1110
0914-1114
0947-1057
0958-1102
Average (Q)
(6)
2-1
2-2
2-3
2-4
2-5
2-6
10/27
1355-1555
1358-1558
1355-1555
1358-1558
1424-1624
1419-1549
Average (Q)
(6)
3-1
3-2
3-3
3-4
3-5
3-6
10/28
0955-1155
0958-1158
0955-1155
0958-1158
0947-1147
0950-1150
Average (Q)
(6)
Flue gas flow rate
, Actual3
mj/h
106,960
106,651
107,648
106,381
94,721
92,677
106,910
102,506
94,325
94,566
94,240
94,471
98,622
98,086
94,400
95,718
102,955
102,650
103,600
102,839
113,803
115,055
103,011
106,817
acfh
3,777,241
3,766,316
3,801,518
3,756,791
3,345,007
3,272,822
3,775,466
3,619,949
3,331,033
3,339,559
3,328,042
3,336,176
3,482,787
3,463,857
3,333,702
3,380,242
3,635,799
3,625,039
3,658,571
3,631,694
4,018,903
4,063,123
3,637,776
3,772,188
, Standard
dNmJ/h
48,666
48,106
47,148
48,616
42,057
46,661
48,134
46,876
42,173
42,266
42,288
42,449
46,059
47,253
42,294
43,748
47,583
47,844
46,258
47,406
53,499
50,694
47,273
48,881
dscfh
1,718,626
1,698,840
1,665,014
1,716,865
1,485,228
1,647,806
,699,836
,655,397
,489,327
,492,594
,493,373
,499,060
,626,567
,668,717
,493,589
,544,940
,680,373
,689,592
,633,571
,674,132
,889,290
,790,217
,669,417
,726,196
Moisture,
V
ft
12.3
12.9
15.6
11.8
13.5
1.7C
13.2
13.2
13.7
13.1
13.5
12.6
13.5
10.8
13.2
12.9
12.2
11.0
15.1
12.0
12.3
17.8
12.6
13.4
Temperature
°C
280
281
280
281
288
288
281
283
279
284
279
283
259
259
281
274
279
282
280
282
270
270
281
277
°F
537
538
536
538
550
550
537
542
535
543
534
542
499
499
539
525
535
540
536
540
518
518
538
531
Carbon
dioxide, %
4.2
4.2
4.2
4.2
4.2
4.2
4.2
4.2
4.2
.2
.2
.2
.2
.2
4.2
4.2
2.3
2.3
2.3
2.3
2.3
2.3
2.3
2.3
Oxygen,
V

-------
          TABLE 2-42 (continued)
Run No.
4-1
4-2
4-3
4-4
4-5
4-6
Date
(1981)
10/28
Sampling
period
1540-1716
1543-1718
1540-1715
1543-1715
1423-1706
1427-1716
Average (Q)
(6)
5-1
5-2
5-3
5-4
5-5
5-6
10/29
0940-1137
0943-1133
0940-1135
0943-1135
0943-1137
0942-1137
Average (Q)
(6)
6-1
6-2
6-3
6-4
6-5
6-6
10/29
1350-1550
1353-1553
1350-1550
1354-1554
1353-1553
1352-1552
Average (Q)
(6)



Flue gas flow rate
, Actual3
nT/h
99,070
99,108
98,964
100,893
113,770
113,495
99,509
104,217
99,656
104,659
100,065
99,119
109,724
109,572
100,875
103,799
94,435
94.734
94,514
95,053
109,673
109,786
94,684
99,699

acfh
3,498,604
3,499,941
3,494,845
3,562,981
4,017,725
4,008,004
3,514,093
3,680,350
3,519,316
3,695,966
3,533,728
3,500,352
3,874,861
3,869,468
3,562,340
3,665,615
3,334,937
3,345,471
3,337,721
3,356,748
3,873,037
3,877,050
3,343,719
3,520,827

, Standard
dNmJ/h
45,089
45,340
45,107
44,301
52,065
52,670
44,959
47,429
46,117
48,088
45,624
45,544
50,546
50,881
46,358
47,800
43,298
43,042
43,511
42,503
50,314
50,346
43,089
45,502

dscfh
,592,304
,601,155
,592,934
,564,464
,838,631
,860,026
,587,714
,674,919
,628,613
,698,186
,611,199
,608,375
,785,009
,796,847
,636,593
,688,038
1,529,041
1,520,006
1,536,556
1,500,961
1,776,813
1,777,953
1,521,641
1,606,888

Moisture,
14.4
13.6
14.4
14.3
14.7
13.5
14.2
14.2
13.3
13.5
14.2
13.7
14.1
13.4
13.7
13.7
14.0
14.4
13.3
15.6
14.7
14.5
14.3
14.4

Temperature
°C
275
277
274
276
270
270
276
274
274
276
276
275
271
271
275
274
274
277
277
278
271
271
277
275

°F
527
531
525
529
518
518
528
525
524
529
529
527
520
520
527
525
526
530
530
532
520
520
530
526

Carbon
dioxide, %
4.
4.
4.
4.
4.
4.
4.
4.
4.3
4.3
4.3
4.3
4.3
4.3
.3
.3
.5
.5
.5
.5
.5
.5
4.5
4.5

Oxygen,
%
11.0
11.0
11.0
11.0
11.0
11.0
11.0
11.0
11.3
11.3
11.3
11.3
11.3
11.3
11.3
11.3
10.5
10.5
10.5
10.5
10.5
10.5
10.5
10.5

-J
UJ
        (continued)

-------
           TABLE 2-42  (continued)
Run No.
7-1
7-2
7-3
7-4
7-5
7-6
Date
(1981)
10/30
Sampling
period
0930-1130
0933-1133
0930-1130
0933-1133
0935-1135
0934-1134
Average (Q)
(6)
8-1
8-2
8-3
8-4
8-5
8-6
10/30
1438-1638
1441-1641
1438-1638
1441-1641
1439-1623
1438-1608
Average (Q)
(6)
Flue gas flow rate
, Actual3
mj/h
100,034
100,343
103,699
100,267
109,520
109,489
101,086
103,892
101,278
101,279
100,996
101,273
109,733
109,966
101,206
104,088
acfh
3,532,635
3,543,545
3,662,069
3,540,882
3,867,652
3,866,549
3,569,783
3,668,889
3,576,587
3,576,610
3,566,612
3,576,390
3,875,168
3.883,405
3,574,050
3,675,795
, Standard
dNmJ/h
46,329
46,251
44,544
46,386
51,078
51,147
45,878
47,623
45,435
45,173
46,068
45,672
50,667
50,152
45,587
47,195
dscfh
,636,079
,633,313
,573,041
,638,107
,803,803
,806,240
,620,135
,515,097
,604,520
,595,254
,626,862
,612,867
,789,295
,771,103
,609,876
,666,650
Moisture,
%
12.9
12.8
13.4
12.5
13.2
13.0
12.9
13.0
14.4
15.2
12.9
13.7
14.1
15.1
14.1
14.2
Temperature
°C
277
280
277
280
271
271
279
276
285
283
285
286
271
271
285
280
°F
530
537
530
536
520
520
533
529
545
542
545
547
520
520
545
537
Carbon
dioxide, %
4.0
.0
.0
.0
.0
.0
.0
.0
4.3
4.3
4.3
4.3
4.3
4.3
4.3
4.3
Oxygen,
%
11.0
11.0
11.0
11.0
11.0
11.0
11.0
11.0
9.3
9.3
9.3
9.3
9.3
9.3
9.3
9.3
to
•o
          aVolumetric flow rate  in actual cubic meters per hour (m /h)  and actual cubic feet per hour (acfh)  at  stack  conditions.
           Volumetric flow rate  in dry normal cubic meters per hour (dNm/h) and dry standard cubic feet per  hour  (dscfh):  Standard
           conditions =  20°C  and 760 mm Hg (68°F and'29.92 in. Hg) and  zero percent moisture.
          C0utlier - not used in calculations.
           Average (Q) Is average quad train tests.
           Average (6) is average of all six tests.

-------
                 TABLE  2-43.  SUMMARY OF  FLUE  GAS  CONDITIONS  DURING DCOG UNDERFIRING TESTING
Run No.
01-1
01 -2
01-3
01 -4_
01 -5C
01-6
Date
(1981)
12/8
Sampling
period
1205-1335
1208-1338
1205-1335
1208-1338
1209-1339
Average (Q)
(5)
02-1
02-2
D2-3
02-4
D2-5
02-6
12/10
1341-1511
1308-1508
1310-1510
1312-1512
1310-1510
1311-1511
Average (Q)
(6)
03-1
03-2
03-3
03-4
D3-5
D3-6
12/11
1131-1540
1134-1540
1134-1542
1139-1548
1145-1544
1137-1546
Average (Q)
(6)



Flue gas flow rate
, Actual3
mj/h
90,548
90,863
91,316
91,309
80,795
91,009
88,966
102,820
103,171
103,773
103,721
98,778
98,700
103,371
101,827
84,440
84,484
86,574
86,156
94,944
95,278
85,414
88,646

acfh
3,197,639
3,208,783
3,224,786
3,224,520
2,853,244
3,213,932
3,141,794
3,631,049
3,643,425
3,664,702
3,662,869
3,488,292
3,485,548
3,650,511
3,595,981
2,981,939
2,983,501
3,057,331
3,042,559
3,352,885
3,364,702
3,016,332
3,130,486

n Standard
dNmJ/h
45,170
44,444
44,715
44,920
39,471
44,812
43,744
49,481
49,815
49,927
50,043
47,600
47,775
49,817
49,107
41,798
41,491
41,852
42,185
47,202
46,443
41,832
43,495

dscfh
1,595,142
1,569,507
1,579,103
1,586,320
1,393,914
,582,518
,544,797
,747,391
,759,182
,763,133
,767,255
,680,969
,687,140
,759,240
,734,178
,476,086
,465,237
,477,970
,489,756
,666,931
,640,093
,477,262
,536,012

Moisture,
%
9.9
11.7
11.6
11.0
10.2
11.1
10.9
12.2
12.0
12.3
12.1
12.2
11.8
12.2
12.1
9.9
10.6
12.0
11.5
9.5
11.3
11.0
10.8

Temperature
°C
242
242
242
243
252
242
244
253
252
252
252
252
252
252
252
252
252
252
249
252
252
251
252

°F
468
468
468
470
485
469
472
487
486
486
486
486
486
486
486
486
486
486
480
486
486
486
486

Carbon
dioxide, %
4.5
4.5
4.5
4.5
4.5
.5
.5
.3
.3
.3
.3
4.3
4.3
4.3
4.3
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0

Oxygen,
%
9.4
9.4
9.4
9.4
9.4
9.4
9.4
12.3
12.3
12.3
12.3
12.3
12.3
12.3
12.3
12.0
12.0
12.0
12.0
12.0
12.0
12.0
12.0

1/1
      (continued)

-------
TABLE  2-43 (continued)
Run No.
D4-1
D4-2
04-3.
D4-4C
D4-5
D4-6
Date
(1981)
12/12
Sampling
period
0940-1140
0943-1143
0940-1140
0940-1140
0942-1142
Average (Q)
(5)
D5-1
D5-2
05-3
05-4
05-5
05-6
12/12
1404-1604
1407-1607
1358-1558
1400-1600
1358-1558
1359-1559
Average (Q)
(6)
06-1
06-2
06-3
06-4
06-5
06-6
12/13
0945-1145
0947-1147
0945-1145
0947-1147
0945-1145
0946-1146
Average (Q)
(6)
Flue gas flow rate
, Actual3
mj/h
91,867
91,898
92,085
94,584
94,488
91,950
92,984
93,540
93,658
94,219
94,313
90,983
90,680
93,932
92,899
86,817
87,102
86,868
86,712
88,151
88,127
86,875
87,296
acfh
3,244.223
3,245,338
3,251,926
3,340,189
3,336,804
3,247,162
3,283,696
3,303,306
3,307,488
3,327,285
3,330,605
3,213,030
3,202,302
3,317,171
3,280,669
3,065,894
3,075,958
3,067,686
3,062,194
3,112,999
3,112,161
3,067,933
3,082,815
, Standard
dNmJ/h
44,981
44,895
44,617
45,882
46,101
44,831
45,295
46,412
46,137
46,292
46,074
44,907
45,615
46,229
45,906
43,962
43,438
43,837
43,681
44,327
44,383
43,730
43,938
dscfh
1,588,494
1,585,451
1,575,619
1,620,295
1,628,021
1,583,188
1,599,576
1,639,024
1,629,300
1,634,772
1,627,070
1,585,882
1,610,872
1,632,542
1,621,153
1,552,508
1,534,002
1,548,066
1,542,579
1,565,391
1,567,349
1,544,289
1,551,649
Moisture,
%
11.0
11.2
11.8
11.9
11.4
11.3
11.5
11.8
12.5
12.7
13.2
12.3
10.6
12.6
12.2
11.6
12.8
11.9
12.6
12.2
12.1
12.2
12.2
Temperature
°C
254
254
256
254
254
255
254
244
244
244
244
244
244
244
244
235
236
235
232
235
235
235
235
°F
490
490
492
490
490
491
490
471
471
471
471
471
471
471
471
455
457
455
449
455
455
454
454
Carbon
dioxide, %
3.7
3.7
3.7
3.7
3.7
3.7
3.7
3.7
3.7
3.7
3.7
3.7
3.7
3.7
3.7
5.1
5.
5.
5.
5.
5.
5.
5.
Oxygen,
%
11.
11.
11.
11.
11.
11.
11.
11.8
11.8
11.8
11.8
11.8
11.8
11.8
11.8
11.0
11.0
11.0
11.0
11.0
11.0
11.0
11.0
aVolumetr1c flow rate In actual  cubic meters per hour (m /h) and actual  cubic  feet per hour  (acfh) at stack conditions.

''Volumetric flow rate In dry normal cubic meters per hour (dfhn3/h) and dry  standard cubic feet oer hour (dscfhl:
 Standard conditions = 20°C and  760 mm  Hg  (68°F and 29.92 in. Hg) and zero  percent moisture.

cTest voided due to excessive post-test leak rate.

 Average (Q) is average quad train tests.
 Average (5) or (6) is average of all five or six tests.

-------
         TABLE 2-44.  SUMMARY OF FLUE GAS FLOW RATE AND TEMPERATURE
                   AS MEASURED BY A FULL VELOCITY TRAVERSE
Run No.
Date
(1981)
Flue gas flow rate
Actual3
m3/h acfh
Standard13
dNm^/h
dscfh


Temperature
°C
°F
                       NCOG underfiring test series
Pre. 1
Pre. 2
V.T.
10/22
10/22
10/27
Average
93,236
89,465
95,169
92,623
3,292,608
3,159,420
3,360,858
3,270,962
47,368
44,999
45,169
45,845
1,672,794
1,589,130
1,595,118
1,619,014
228
233
259
240
442
451
499
464
                        DCOG underfiring test series
Pre.
12/7
86,169
3,043,045
44,134
1,558,567
228
443
aVolumetric flow rate in actual cubic meters per hour (m /h) and actual cubic
 feet per hour (acfh) at stack conditions.

 Volumetric flow rate in dry normal  cubic meters per hour (dNm /h) and dry
 standard cubic feet per hour (dscfh):  Standard conditions = 20°C and 760
 mmHg (68°F and 29.92 in.Hg) and zero percent moisture.
                                    2-77

-------
     During the NCOG underfiring test series, the volumetric flow



rate averaged 46,882 dNm /h (1,634,766 dscfh), temperature aver-



aged 277°C (531°F),  and moisture content averaged 13.6 percent.



Oxygen and carbon dioxide contents averaged 10.6 and 4.0 percent,



respectively.



     During the DCOG underfiring test series, the volumetric flow



rate averaged 45,247 dNm /h (1,597,894 dscfh), temperature aver-



aged 247°C (476°F),  and the moisture content averaged 11.6 per-



cent.  Oxygen and carbon dioxide contents averaged 11.3 and 4.2



percent, respectively.
                              2-78

-------
2.9  VISIBLE EMISSIONS



     Table 2-45 summarizes visible emissions data collected



during the NCOG underfiring test series.  Data were not collected



during Runs 1, 2, and 3.  During Run 4, opacities ranged from 0



to 45 percent and averaged 15 percent.  These opacities were



markedly higher than those during Runs 5 through 8, which ranged



from 0 to 40 percent and averaged 3 percent.  Frank Clay of the



EPA made the visible emissions observations.



     Extreme adverse weather conditions prevented the observation



of visible emissions during the DCOG underfiring test series.



Cloud cover was 100 percent during the entire test series, and



snow fell during most of the test series.
                               2-79

-------
     TABLE 2-45.  SUMMARY OF VISIBLE EMISSIONS DATA NUMBER 1  COKE BATTERY EXIT STACK,  NCOG UNDERFIRING TEST SERIES
Particulate
Run No. .
1
2
3
4









5









6






Date
(1981)
10/27
10/27
10/28
10/28









10/29









10/29






Particulate
test time
0910-1114
1355-1624
0955-1158
1423-1716









0940-1137









1350-1554






Corresponding
VE run No.
N/Aa
N/A
N/A
VE-1









VE-2









VE-4






VE set
No.



VE-1-1
VE-1-2
VE-1 -3
VE-1 -4
VE-1-5
VE-1 -6
VE-1 -7
VE-1 -8
VE-1 -9
VE-1-10
VE-2-1
VE-2-2
VE-2-3
VE-2-4
VE-2-5
VE-2-6
VE-2-7
VE-2-8
VE-2-9
VE-2-10
VE-4-1
VE-4-2
VE-4-3
VE-4-4
VE-4-5
VE-4-6
VE-4-7
VE observation
time



1455-1500
1501-1506
1507-1512
1513-1518
1519-1525
1526-1531
1532-1537
1538-1543
1544_1549
1550-1551°
1035-1040
1041-1046
1047-1052
1053-1058
1059-1104
1105-1110
1111-1116
1117-1122
1123-1128
1129-1134
1431-1436
1437-1442
1443-1448
1449-1454
1455-1500
1501-1506
1507-1512
Average
% opacity



30
11
7
10
17
10
16
17
18
10
6
3
3
2
2
0
0
0
0
0
1
0
0
0
2
0
0

Range



20-45
0-35
0-15
0-25
10-25
5-20
0-25
10-20
10-20
5-15
5-10
0-5
0-5
0-5
0-5
0
0
0
0
0-5
0-5
0
0
0-5
0-5
0
0
00
o
     (continued)

-------
    TABLE 2-45 (continued)
Participate
Run No.
6
(cont'd)









7





8









Date
(1981)
10/29










10/30





10/30









Particulate
test time
1350-1554










0930-1135





1438-1641









Corresponding
VE run No.
VE-4


VE-5







VE-6





VE-7









VE set
No.
VE-4-8
VE-4-9
VE-4-10
VE-5-1
VE-5-2
VE-5-3
VE-5-4
VE-5-5
VE-5-6
VE-5-7
VE-5-8
VE-6-1
VE-6-2
VE-6-3
VE-6-4
VE-6-5
VE-6-6
VE-7-1
VE-7-2
VE-7-3
VE-7-4
VE-7-5
VE-7-6
VE-7-7
VE-7-8
VE-7-9
VE-7-10
VE observation
time
1513-1518
1519-1524
1525-1530
1536-1541
1542-1547
1548-1553
1554-1559
1600-1605
1606-1611
1612-1617.
1618-1620^
1003-1008,
1011-1012°
1018-1023
1024-1029
1030-1035.
1036-1040
1443-1448
1449_1454
1455-1500
1501-1506
1507-1512
1513-1518
1519-1524
1525-1530
1531-1536f
1540-1544
Average
% opacity
0
0
3
8
<6
<18
9
<2
0
0
0
0
0
0
<5
<2
0
<6
<3
<2
<6
8
<6
<5
<5
<7
<5

Range
0
0-5
0-10
5-10
<5-20
0-40
0-20
0-5
0
0
0
0
0
0-5
<5-5
0-<5
0
0-15
0-5
0-5
0-15
5-10
0-10
0-10
<5-10
0-15
0-10
I
00
    (continued)

-------
       TABLE 2-45 (continued)
Particulate
Run. No.
8
(cont'd)








Date
(1981)
10/30









Particulate
test time
1438-1641









Corresponding
VE run No.
VE-8









VE set
No.
VE-8-1
VE-8-2
VE-8- 3
VE-8-4
VE-8- 5
VE-8-6
VE-8-7
VE-8-8
VE-8-9
VE-8-10
VE observation
time
1551-1556
1557-1602
1603-1608
1609-1614
1615-1620
1621-1626
1627-1632
1633-1638
1639-1644
1645-1650
Average
% opacity
11
<3
0
0
0
0
2
8
<5
<5
Range
<5-20
0-5
0
0
0
0
0-15
5-10
0-10
0-5
Ni
I
00
to
aN/A = Not analyzed.
 Two-minute set.
cThree-minute set.
 Two-minute set.
eThree-minute set.
 Five-minute set.

-------
2.10  PROCESS DATA



     During each test, the process operation was monitored by an



MRI representative.  Tables 2-46 and 2-47 summarize the process



data collected during the NCOG and DCOG test series, respec-



tively.  The following parameters were monitored:  average COG to



battery average coal in battery, number of pushes and charges,



number of ovens empty, and exhaust main pressure (push and coke



side).



     Average COG to Battery No. 1 during the NCOG underfiring



testing was 4,820 m3/h (170,190 ft3/h).  The coal in the battery



averaged 640.4 Mg  (706.1 tons).  There were an average of 6



pushes, 7 charges, and 4 empty ovens during a test run.  Exhaust



main pressure averaged 78 mmH-O (3.1 in.H-O) on the push side,



and 81 mmH-O (3.2 in.H^O) on the coke side.



     Average COG to Battery No. 1 during the DCOG underfiring



testing was 4,339 m3/h (153,210 ft3/h).  The coal in the battery



averaged 596.4 Mg  (567.7 tons).  There were an average of 6



pushes, 5 charges, and 3 empty ovens during a test run.  Exhaust



main pressure averaged 57 mmH-O (2.2 in.H2O) on the push side,



and 60 mmH-O (2.4 in.H20) on the coke side.



     Tables 2-48 and 2-49 summarize the sulfur content of the



coal and coke during the NCOG and DCOG test series.  During the



NCOG test series, the coal and the coke contained an average of



0.82 and 0.70 percent sulfur, respectively.  During the DCOG test



series, the coal averaged 0.80 percent sulfur, and the coke



averaged 0.72 percent sulfur.
                              2-83

-------
                                             TABLE  2-46.   NCOG TEST  SERIES  PROCESS  DATA0
to
 I
00
Run No.
1
2
3
4
5
6
7
8
Date
(1981)
10/27
10/27
10/28
10/28
10/29
10/29
10/30
10/30
Time
0910-1114
1355-1624
0947-1158
1423-1718
0940-1137
1350-1554
0930-1135
1438-1641
Average
Average COG
to battery"
m3/h
4874
4754
4117
5012
4990
5213
4528
5068
4820
ftj/h
1/2,120
167,880
145,390
176,990
176,220
184,070
159,880
178,940
170,190
Average coal
in battery
Mg
604.6
622.7
635.1
655.2
650.3
650.4
648.1
657.2
640.4
tons
666.6
686.6
700.2
722.4
717.0
717.1
714.6
724.6
706.1
No. of
pushes
12
4
6
9
7
5
3
4
6
No. of
charges
12
3
5
11
6
7
6
4
7
No. of
ovens empty
6
6
3
3
3
3
3
3
4
Exhaust main pressure
Push side
mmH^O
78
74
76
78
79
79
80
79
78
in.H20
3.1
2.9
3.0
3.1
3.1
3.1
3.1
3.1
3.1
Coke side
nmH20
80
82
83
81
81
80
80
80
81
in.HzO
3.1
3.2
3.2
3.2
3.2
3.1
3.1
3.1
3.2
             aThe following information was provided by Republic Steel Corporation:   1)  Average amount of coal  charged per coke
              oven:  -15.3 tons/coking cycle.  2)  Average amount of coke produced  per coke oven:  -10.2 tons/coking cycle.
              3)  Coking temperature:  -2300°F.  (This  is the temperature recorded  in the flues.  The temperature of the coke would
              be approximately  150°F lower.)  4)  Average coking time:  -20.5 hours.

             bAt 40°C (140°F).

-------
                                             TABLE 2-47.   DCOG TEST  SERIES  PROCESS  DATAC
Run No.
D-1
D-2
D-3
0-4
D-5
0-6
Date
(1981)
12/8
12/10
12/11
12/12
12/12
12/13
Time
1150-1352
1305-1512
1134-1142
1350-1548
0940-1145
1355-1607
0945-1147
Average
Average COG
to batteryb
m^/h
4591
4521
4234
4130
4348
4209
4339
ftj/h
162,100
159,640
149,520
145,850
153,530
148,620
153,210
Average coal
in battery
Mg
598.6
598.6
585.9
598.6
598.6
598.6
596.4
tons
660.0
660.0
646.0
660.0
660.0
660.0
657.7
No. of
pushes
11
7
4
4
3
5
6
No. of
charges
10
8
4
3
2
5
5
No. of
ovens empty
3
3
3
3
3
3
3
Exhaust main pressure
Push side
rnrnHpO
64
62
55
55
55
52
57
in.HpO
2.5
2.4
2.2
2.2
2.2
2.0
2.2
Coke side
nfnH20
62
65
55
60
60
60
60
in.H20
2.4
2.6
2.2
2.2
2.4
2.4
2.4
00
Ul
            The following information was provided by Republic Steel  Corporation:  1)  Average amount  of coal charged per coke oven:
            -14 tons/coking cycle  during November/December.   2)   Average amount of coke produced per coke oven:  -10 tons/cokinq
            cycle during November/December.  3) Coke temperature:   ~2175°F to 2250°F.  (This is the  temperature recorded in the
            flues.  The temperature  of the coke would be approximately  150°F lower.)  4)  Average coking time:  -24 hours.  5)  Btu
            content of DCOG:  540  Btu/scf.

           bAt 40°C (104°F).

-------
      TABLE  2-48.   SULFUR CONTENT OF COAL AND COKE  DURING
                      NCOG TESTS (PERCENT)
Date analyzed3
10/25/81
10/26/81
10/27/81
10/28/81
10/29/81
10/30/81
Average
Coal
0.75
0.77
0.98
0.80
0.78
0.85
0.82
Coke
0.70
0.72
0.75
0.65
0.70
0.65
0.70
      TABLE 2-49.   SULFUR CONTENT OF COAL  AND COKE  DURING
                        DCOG TESTS (PERCENT)
Date analyzed3
12/07/81
12/08/81
12/09/81
12/10/81
12/11/81
12/12/81
12/13/81
Average
Coal
0.78
0.78
0.83
0.80
0.78
0.87
0.80
0.80
Coke
0.78
0.75
0.73
0.68
0.68
0.70
0.70
0.72
Sulfur content of coal  is usually analyzed 1  to  2  days  before  the
coal  is charged to the  ovens.   Sulfur content of coke is  usually
analyzed the same day the coke is pushed from the  ovens.
                               2-86

-------
     The MRI process description and data as received by PEDCo



are included in Appendix I.
                               2-87

-------
                            SECTION 3



                       PROCESS DESCRIPTION






     The Republic Steel facility in Cleveland currently operates



three Koppers gun-flue coke oven batteries.  The testing was



conducted on the flue gas from the No. 1 coke oven battery, which



consists of 51 ovens.  Coke was first pushed from this battery in



January 1977.  Initial startup of the Sulfiban desulfurization



system was in March/April 1981.  Coke is produced continuously



24-hours per day.  This facility uses byproduct coke ovens to



produce furnace coke from coal; the coke is used in blast furnaces



for the reduction of iron ore to metallic iron.  Figure 3-1 is a



simplified process flow diagram.



     The gas collecting system has two offtakes, one located at



each end of the oven.  The volatile products liberated during the



coking process pass through the battery's dual collection main



and are processed by the byproduct recovery system, which con-



sists of a primary cooler, exhauster, detarrer, ammonia absorber,



final cooler, a benzol scrubber, Sulfiban desulfurization system,



pressure regulator, and booster.  After leaving the byproduct



recovery system, the normal or desulfurized coke oven gas  (NCOG



or DCOG) is used to heat the ovens in the battery.



     About 40 percent of the COG  (DCOG or NCOG) generated by the



battery during the coking process is underfired to the battery





                               3-1

-------
COAL
 AIR	*
                   COKE
                     /1
COKING CHAMBER
               COKE BATTERY
 HEATING FLUE
                     1(1
                     Y
                  OUTLET
                   STACK
                              CHEMICALS
1

COAL-CHEMICAL
RECOVERY
                                  i'2
DESULFURIZATION
                           SULFUR RECOVERY
                          OTHER
                         PROCESSES
  OTHER
PROCESSES
          SAMPLING  POINT

      -*•  SOLIDS  FLOW

      •-*  AIR/GAS FLOW
                                SULFUR
                      Figure 3-1.  Process flow diagram,
                      Republic Steel-Cleveland Works.
                                   3-2

-------
along with combustion air.  The products of combustion from



underfiring with coke oven gas leave the battery via the waste



gas stack.  There are no add-on pollution control devices serving



the battery stack.  Naturally induced stack draft, which is



regulated by dampers at the end of each flue gas canal, draws air



required for combustion through an airbox at the bottom of the



regenerator chambers.



     Approximately 15 tons of coal (0.75 to 1.0 percent sulfur)



is charged through three openings in the top of each oven.  A



leveling bar on the pusher machine is used to level the coal



before the coking operation begins.  The coke ovens are under-



fired with coke oven gas  (NCOG or DCOG), and the firing takes



place from either the coke side or the push side.  More gas is



fired on the coke side of the oven since it is approximately 3



inches wider and, hence, contains more coke to heat up than the



pusher side of the oven.  Heat for the coking operation is pro-



vided by a regenerative combustion system located below the



ovens.  Since the combustion flue gas contains a significant



amount of process heat, two regenerators (one for combustion air



and one for combustion waste gas) are located below each oven.



Flow between the two regenerators alternates at about 30 minute



intervals as the firing of the coke ovens is reversed every 30



minutes to keep the ovens operating within the safe temperature



range of the silica refractories.



     When the coking operation is complete [skin temperature of



the coke has reached 1038° to 1093°C  (1900° to 2000°F)], the coke
                               3-3

-------
guide and quench car are moved into place, and the oven doors are



removed.  The pusher then pushes the coke out of the oven through



the coke guide and into the quench car.  The coke is then trans-



ported to the quench tower, where it is cooled by water sprays.



From there, it is removed to the wharf, where it is further



cooled before being conveyed to storage.



     The operation of each oven is cyclic, but the battery con-



tains a sufficiently large number of ovens to maintain an essen-



tially continuous yield of byproducts.  Although the time between



charging and discharge is approximately equal for all ovens,



charging times are staggered so that the flow of evolved gases



from the ovens is constant.  This helps to maintain a balance of



pressure in the flues, collecting main, and battery stack.
                             3-4

-------
                            SECTION 4


               SAMPLING AND ANALYTICAL PROCEDURES



     Samples collected at the exit stack were analyzed for par-


ticulate, sulfur dioxide, sulfuric acid mist, and other related


pollutants.  In addition, grab samples collected at the inlet and


outlet (during DCOG underfiring)  of the SRU and the exit stack


were analyzed for total reduced sulfurs (TRS).   This section


briefly describes the sampling and analytical procedures used in


this test; detailed descriptions of these procedures are pre-


sented in Appendix D.



4.1  SAMPLING LOCATIONS


     Sampling ports were located at the 15.2-m  (50-ft) level of


the 68.6-m (225-ft) outlet stack.  This site is 6 stack diameters


from the nearest downstream flow disturbance and 21 stack diam-


eters from the nearest upstream flow disturbance in the 2.5-m


(8.1-ft)  diameter stack  (see Figure 4-1).  Figure 4-2 shows the


sampling site configuration and traverse point locations.  Twenty-


four points were used for velocity traverse.  Particulate sam-


pling was conducted at a point of average velocity for the entire


2-hour test period.


     Gaseous grab samples were collected at the inlet and outlet


of the SRU via positive pressure taps located in the connecting


ductwork.
                               4-1

-------
                2.5 m (S.I  ft)  l.D.
1
68.6 m
(~225 ft)


i

i
15.2
(50
i
r
(,,

m
ft)
/
/









^
«

^




1
FLOW
r
:ID


1
\ GROUND LEVEL


Figure 4-1.   Coke Battery No.  1  flue gas exit stack.
                      . 4-2

-------
                          6-in.  PORT
                         (TRAINS 1-4)
       4-in. PORT
     (TRAINS 5 AND
6)
4-1n. PORT
              VELOCITY TRAVERSE POINT LOCATIONS
POINT NO.
1
2
3
4
5
6
7
8
9
10
11
12
LOCATION, in.
2
6 1/2
11 1/2
17 1/4
24 3/8
34 3/4
62 3/4
73 1/8
80 3/4
86
91
95 1/2
Figure 4-2.   Coke Battery No.  1  exit  stack  sampling  site and
                  traverse point locations.
                             4-3

-------
4.2  GAS STREAM FLOW RATE, TEMPERATURE, AND COMPOSITION


     Gas stream flow rate and temperature before each test series


and in conjunction with each particulate run were measured ac-


cording to the procedures described in EPA Method 2.*  Velocities


were measured with an S-type pitot tube and a 0 to 0.25-inch,


inclined, draft gauge manometer.  Temperatures were measured with


a calibrated thermocouple and digital potentiometer.  During each


particulate test an integrated bag sample was collected, the


oxygen and carbon dioxide content was determined by Orsat analy-


sis.  Method 3* sampling and analytical procedures were used in


all cases.



4.3  PARTICULATE, SULFUR DIOXIDE, AND SULFURIC ACID MIST EMISSION
     TESTS


     Samples were collected from a single point in the exit stack


by use of a quad train Method 5 sampling system, a standard EPA


Method 5 train, and a particulate sampling train equipped for


315°C (600°F) filter box and probe heat.  Sampling was conducted


isokinetically by regulating the sampling rate relative to the


flue gas velocity.  Tables 4-1 through 4-3 detail the sampling


and analytical schedules used during the NCOG and DCOG test


series.   Particulate filters were glass fiber,** sample train


back halves consisted of four impingers in a Method 5 water


configuration or five impingers in a Method 8 isopropanol,
 *40 CFR 60, Appendix A, Reference Methods 2 and 3, July 1980.
**
  Whatman Reeve Angel 934 AH.
                                4-4

-------
 TABLE 4-1.   NCOG UNDERFIRING TEST SERIES, OCTOBER 26-30, 1981,
                     REVISED SAMPLING SCHEDULE
Run
No.
1





2





3
4
5





6





7





8





Sample
train No.
1.1
1.2
1.3
1.4
1.5
1.6
2.1
2.2
2.3
2.4
2.5
2.6
3.1-3.6
4.1-4.6
5.1
5.2
5.3
5.4
5.5
5.6
6.1
6.2
6.3
6.4
6.5
6.6
7.1
7.2
7.3
7.4
7.5
7.6
8.1
8.2
8.3
8.4
8.5
8.6
Probe, filter temperature,
°C
121
121
177
177
121
316
121
121
204
204
121
316
Same as
Same as
121
121
177
177
121
316
121
121
204
204
121
316
121
121
177
177
204
316
177
177
204
204
121
316
°F
250
250
350
350
250
600
250
250
400
400
250
600
Run 1
Run 2
250
250
350
350
250
600
250
250
400
400
250
600
250
250
350
350
400
600
350
350
400
400
250
600
Back-half
configuration
Method 8
Method 8
Method 8
Method 8
Method 5
Method 8
Method 8
Method 8
Method 8
Method 8
Method 5
Method 8
Same as Run 1
Same as Run 2
Method 8
Method 5
Method 8
Method 5
Method 5
Method 8
Method 8
Method 5
Method 8
Method 5
Method 5
Method 8
Method 8
Method 5
Method 8
Method 5
Method 5
Method 8
Method 8
Method 5
Method 8
Method 5
Method 8
Method 8
Note:   All  filters were Whatman  Reeve  Angel  934 AH.   Sampling  trains
       1  through 4 operated  simultaneously  in  quad  system.   During
       every run, gas  samples  were collected at the  COG  inlet  to  the
       battery and at  the outlet stack for  TRS and  S0 analysis.
                              4-5

-------
 TABLE 4-2.   DCOG UNDERFIRING TEST  SERIES,  DECEMBER  6-13,  1981,
                     REVISED SAMPLING  SCHEDULE
Run
No.
Dl





D2
D3





D4
D5





D6





Sample
train No.
1.1
1.2
1.3
1.4
1.5
1.6
2.1-2.6
3.1
3.2
3.3
3.4
3.5
3.6
4.1-4.6
5.1
5.2
5.3
5.4
5.5
5.6
6.1
6.2
6.3
6.4
6.5
6.6
Probe, filter temperature,
°C
121
121
177
177
121
316
Same as
121
121
204
204
121
316
°F
250
250
350
350
250
600
*un Dl
250
250
400
400
250
600
Same as Run D3
121
121
177
177
121
316
121
121
204
204
121
316
250
250
350
350
250
600
250
250
400
400
250
600
Back-half
configuration
Method 8
Method 8
Method 8
Method 8
Method 5
Method 8
Same as Run Dl
Method 8
Method 8
Method 8
Method 8
Method 5
Method 8
Same as Run D3
Method 8
Method 5
Method 8
Method 5
Method 5
Method 8
Method 8
Method 5
Method 8
Method 5
Method 5
Method 8
Note:  All  filters were Whatman Reeve Angel  934 AH.   Sample trains
       1 through 6 operated simultaneously.   Gas samples were
       collected during every run at the inlet and outlet of the
       desulfurization unit and"at the outlet stack for TRS and SC2
       analysis.
                               4-6

-------
      TABLE 4-3.   NCOG AND DCOG UNDERFIRING TEST  SERIES ANALYTICAL SCHEDULE
Run
1,3,
01,02

























Sampl Ing
train
Method 5 with
Method 8 back
half

Method 5 with
Method 8 back
half


Method 5 with
Method 8 back
half

Method 5 with
Method 8 back
half

Method 5 with
H20 in the
impingers







Filter
1.0. No.
1.1
3.1
Dl.l
02. 1
1.2
3.2
01.2
02.2

1.3
3.3
01.3
02. 3
1.4
3.4
01.4
02.4
1.5
3.5
01.2
02.5






Probe and filter
temperature,
°C
121



121




177



177



121









°F
250



250




350



350



250









Laboratory protocol
Front half8
1. Desiccate and weigh
2. IPA-rlnse and titrate
3. H20-r1nse and titrate

1. Desiccate and weigh
2. Heat 2 h at 177°C (350°F)
3. Reweigh
4. IPA-rinse and titrate
5. H20-rinse and titrate
1. Desiccate and weigh
2. IPA-rinse and titrate
3. H,0-rinse and titrate
c
1. Desiccate and weigh
2. IPA-rinse and titrate
3. H-0-rlnse and titrate
2
1. Desiccate and weigh
2. Divide filter, desic-
cate and weigh
3. a. Heat 2 h at 177°C (350°F),
heat 4 h at 177°C (350°F),
heat 2 h at 204°C (400°F),
heat 4 h at 204°C (400°F),
heat 2 h at 316°C (600°F),
IPA-rinse and titrate,
H20-rinse and titrate
Back half
Standard Method 8



Standard Method 8




Standard Method 8



Standard Method 8



1. TOCb r
2. E-C ext.








(continued)

-------
            TABLE 4-3 (continued)
i
00
Run







2,4.
D3.D4














Sampl Ing
train



CCS filter
holder with
Method 8
back half
Method 5 with
Method 8 back
half

Method 5 with
Method 8 back
half


Method 5 with
Method 8 back
half

Method 5 with
Method 8 back
half
Filter
1.0. No.



1.6
3.6
01. 6
02.6
2.1
4.1
03. 1
04. 1
2.2
4.2
03.2
04.2

2.3
4.3
03. 3
04.3
2.4
4.4
03.4
Probe and filter
temperature,
°C



316



121



121




204



204


°F



600



250



250




400



400


Laboratory protocol
Front half3
b. 121°C (250°F) ~ TOC
temperature profile
- 316°C (600°F)
1. Desiccate and weigh
2. IPA-rinse and titrate
3. H,0-r1nse and titrate
t
1. Desiccate and weigh
2. IPA-rinse and titrate
3. H,0-rinse and titrate
2
1. Desiccate and weigh
2. Heat 2 h at 204°C (400°F)
3. Reweigh
4. IPA-rinse and titrate
5. H-O-rinse and titrate
1. Desiccate and weigh
2. IPA-rinse and titrate
3. H00-rinse and titrate
L.
1. Desiccate and weigh
2. IPA-rinse and titrate
3. H-O-rinse and titrate
Back-half



Standard Method 8



Standard Method 8



Standard Method 8




Standard Method 8



Standard Method 8


             (continued)

-------
TABLE 4-3 (continued)
Run

















5.D5










Sampl 1ng
train
Method 5 with
H20 In the
Implngers










CCS filter
holder with
Method 8 back
half
Method 5 with
Method 8 back
half
Method 5 with
H20 In the
Implngers


Method 5 with
Method 8 back
half
Filter
I.D. No.
2.5
4.5
03. 5
04. 5









2.6
4.6
03. 6
04. 6
5.1
05. 1

5.2
05. 2



5.3
05.3

Probe and filter
temperature,
°c
121












316



121


121




177


°F
250












600



250


250




350


Laboratory protocol
Front half3
1. Desiccate and weigh
2. Divide filter, desic-
cate and weigh
3. a. Heat 2 h at 177°C (350°F),
heat 4 h at 177°C (350°F),
heat 2 h at 204°C (400°F),
heat 4 h at 204°C (400°F),
heat 2 h at 316°C (600°F),
IPA-rlnse and titrate,
H20-rinse and titrate
b. 121°C (250°F) - TOC
temperature profile
- 316°C (600°F)
1. Desiccate and weigh
2. IPA-rinse and titrate
3. H,0-rinse and titrate
c.
1. Desiccate and weigh
2. IPA-rinse and titrate
3. H-O-rinse and titrate
1. Desiccate and weigh
2. Heat 2 h at 177°C (350°F)
3. Reweigh
4. IPA-rinse and titrate
5. H-0-rlnse and titrate
1. Desiccate and weigh
2. IPA-rinse and titrate
3. H-0-rinse and titrate
Back half
1. TOCb r
2. E-C ext.c











Standard Method 8



Standard Method 8


1. TOCb c
2. E-C ext.



Standard Method 8


  (continued)

-------
 TABLE 4-3  (continued)
Run




















6,06







Sampling
train
Method 5 with
H20 In the
Implngers
Method 5 with
H20 In the
Implngers










CCS filter
holder with
Method 8
back half
Method 5 with
Method 8 back
half
Method 5 with
HzO 1n the
Implngers


Filter
I.D. No.
5.4
05.4

5.5
05. 5











5.6
D5.6


6.1
06. 1

6.2
06.2



Probe and filter
temperature,
°C
177


121












316



121


121




°F
350


250












600



250


250




Laboratory protocol
Front half3
1. Desiccate and weigh
2. IPA-rinse and titrate
3. H20-rinse and titrate
1. Desiccate and weigh
2. Divide filter, desic-
cate and weigh
3. a. Heat 2 h at 177°C (350°F),
heat 4 h at 177°C (350°F),
heat 2 h at 204°C (400°F),
heat 4 h at 204°C (400°F),
heat 2 h at 316°C (600°F),
IPA-rinse and titrate,
HzO-rinse and titrate
b. 121 °C (250°F) - TOC
temperature profile
- 316°C (600°F)
1. Desiccate and weigh
2. IPA-rinse and titrate
3. H,0-rinse and titrate
f.
1. Desiccate and weigh
2. IPA-rinse and titrate
3. H20-rinse and titrate
1. Desiccate and weigh
2. Heat 2 h at 204°C (400°F)
3. Reweigh
4. IPA-rinse and titrate
5. H.O-rlnse and titrate
Back half
1. TOCb p
2. E-C ext.

1 . TOCb
2. E-C ext.











Standard Method 8



Standard Method 8


1. TOCb r
2. E-C ext.



(continued)

-------
 TABLE 4-3  (continued)
Run























7


Sampling
train
Method 5 with
Method 8 back
half
Method 5 with
H20 In the
impingers
Method 5 with
H20 in the
Impingers










CCS filter
holder with
Method 8
back half
Method 5 with
Method 8 back
half
Filter
I.D. No.
6.3
06.3

6.4
06. 4

6.5
06.5











6.6
06. 6


7.1


Probe and filter
temperature,
°C
204


204


121












316



121


°F
400


400


250












600



250


Laboratory protocol
Front halfa
1. Desiccate and weigh
2. IPA-rlnse and titrate
3. H~0-rinse and titrate
1. Desiccate and weigh
2. IPA-rinse and titrate
3. H20-r1nse and titrate
1. Desiccate and weigh
2. Divide filter, desic-
cate and weigh
3. a. Heat 2 h at 177°C (350°F),
heat 4 h at 177°C (350°F),
heat 2 h at 204 °C (400°F),
heat 4 h at 204°C (400°F),
heat 2 h at 316°C (600°F),
IPA-rinse and titrate,
H20-rinse and titrate
b. 121°C (250°F) *• TOC
temperature profile
+ 316°C (600°F)
1. Desiccate and weigh
2. IPA-rinse and titrate
3. H_0-r1nse and titrate
£
1. Desiccate and weigh
2. Hold

Back half
Standard Method 8


1. TOCb r
2. E-C ext.

1. TOCb r
2. E-C ext.c











Standard Method 8



Hold


(continued)

-------
                TABLE 4-3 (continued)
 I
M
to
                (continued)
Run





8


Sampling
train
Method 5 with
H20 in the
impingers
Method 5 with
Method 8 back
half
Method 5 with
HzO in the
impingers
Method 5 with
H20 in the
impingers
CCS filter
holder with
Method 8
back half
Method 5 with
Method 8 back
half
Method 5 with
H20 1n the
impingers
Method 5 with
Method 8 back
half
Filter
I.D. No.
7.2
7.3
7.4
7.5
7.6
8.1
8.2
8.3
Probe and filter
temperature,
°C
121
177
177
204
316
177
177
204
°F
250
350
350
400
600
350
350
400
Laboratory protocol
Front half3
1. Desiccate and weigh
2. Hold
1. Desiccate and weigh
2. Hold
1. Desiccate and weigh
2. Hold
1. Desiccate and weigh
2. Hold
1. Desiccate and weigh
2. Hold
1. Desiccate and weigh
2. Hold
1. Desiccate and weigh
2. Hold
1. Desiccate and weigh
2. Hold
Back half
Hold
Hold
Hold
Hold
Hold
Hold
Hold
Hold

-------
                 TABLE  4-3  (continued)
*»
 i
M
10
Run





















Sampling
train
Method 5 with
H20 1n the
Implngers
Method 5 with
Method 8 back
half











CCS filter
holder with
Method 8
back half
Filter
1.0. No.
8.4


8.5













8.6



Probe and filter
temperature,
°C
204


121













316



°F
400


250













600



Laboratory protocol
Front half3
1. Desiccate and weigh
2. Hold

1. Desiccate and weigh
2. Heat 2 h at 135°C (275°F),
heat 4 h at 135°C (275°F),
heat 2 h at 149°C (300°F),
heat 4 h at 149°C (300°F),
heat 2 h at 163°C (325°F),
heat 4 h at 163°C (325°F),
heat 2 h at 177°C (350°F),
heat 4 h at 177°C (350°F),
heat 2 h at 204°C (400°F),
heat 4 h at 204°C (400°F),
heat 2 h at 316°C (600°F),
IPA-rlnse and titrate.
HpO-Mnse and titrate
1. Desiccate and weigh
2. Hold


Back half
Hold


Hold













Hold



                aFront  half filter catches were saved after their analysis.

                 Total  organic carbon.
                 Ether-chloroform extraction.

-------
hydrogen peroxide configuration.  Stack, probe, filter, and



impinger gas temperatures were monitored for each train during



sampling.



     After sampling was completed, filters were removed and



placed in a petri dish.  The nozzle, probe, and filter holder



portions of the sample train were then acetone-rinsed.  The



acetone rinse and particulate caught on the filter media were



dried at room temperature, desiccated to a constant weight, and



weighed on an analytical balance.  Total filterable particulate



matter was determined by adding these two values.  Selected



filters were heated at indicated temperatures for 2 to 4 hours,



desiccated to a constant weight, and weighed on an analytical



balance.  After the indicated heat treatment, the filterable



particulate matter content was determined by adding these two



values.



     Acid sulfate and water-soluble sulfates were determined by



washing the particulate catch samples sequentially with IPA and



distilled water, and titrating the eluates with barium perchlo-



rate.



     Total organic carbon was determined from selected filters by



heating to the indicated temperature in the presence of a leak-



free nitrogen purge.  After the purge gas had been diluted and



oxidized, it was collected in a stainless steel tank.  An aliquot



was injected into a gas chromatograph with oxidation-reduction



capabilities.



     Sulfuric acid mist and sulfur dioxide concentrations were



determined from the sampling trains with Methods 8 back halves.



                                4-14

-------
The first and second impingers contained the acid mist sample,


and the third and fourth impingers contained the SO- sample.  In


each case, the concentrations were determined by titrating with


barium perchlorate.


     The Method 5 impinger contents for selected samples were


treated by an ether-chloroform extraction technique to determine


organic and inorganic condensibles.  The respective extracts were


placed in tared beakers and evaporated to dryness.  The organic


fraction was dried at ambient temperature, and the inorganic


fraction, at 105°C (221°F).  The beakers were then desiccated to


a constant weight and weighed to the nearest 0.1 mg.  Condensible


total organic carbon also was determined, by subjecting an ali-


quot of Method 5 back-half water to the ampule technqiue of


organic oxidation.  This method involves heating the aliquot in a


carbon-free atmosphere in the presence of a catalyst and quanti-


tatively determining carbon dioxide.



4.4  REDUCED-SULFUR EMISSION TESTS


     Gas samples were analyzed for reduced-sulfur compounds  (H-S,


COS, and CS2) and SO- by gas chromatographic (GC) separation and

                                                        j^
flame photometric detection  (FPD).  Fifteen-liter Tedlar  bags


were filled with COG via positive-pressure taps located in the


ductwork at the inlet and outlet of the SRU or filled with exit


stack gas by a leak-free Teflon diaphragm pump.  Only Teflon


tubing and connections were used during sample collection.  Inlet


and outlet SRU samples were collected simultaneously.
                               4-15

-------
     A sample aliquot was taken for analysis by a sample loop and



multiport valve system.  Aliquot size was determined by the



sample loop size.  For separation of the reduced-sulfur and



sulfur dioxide components, the sample aliquot was passed through



various chromatographic columns.  Flow through the sample loop



and columns was controlled by electronic integration.  After



separation, the relative quantity of each component was measured



as the electrical potential (yV-s)  produced from the flame photo-



metric detector and measured by the integrator.  Component cali-



bration curves of response versus concentration were made daily



by permeation devices and dynamic dilution.  The FPD response was



determined to be linear from 0 to 70 ppm.  Samples with component



concentrations greater than 70 ppm were analyzed in the FPD



linear range by reducing the sample loop size.  Audit and stan-



dard gases were diluted dynamically before they entered the



sample loop.  Harmon Engineering and Testing of Auburn, Alabama,



provided an onsite GC-FPD analysis.



     Appendix D presents a complete description of the sampling



and analytical procedures used.  Appendix A presents calcula-



tions, including gas velocity data.  Appendices B and C present



field and laboratory data sheets, and Appendix E describes the



equipment calibration procedures and results.
                               4-16

-------
                            SECTION 5

                        QUALITY ASSURANCE


     Because the end product of testing is the production of

representative emission results, quality assurance is one of the

primary facets of stack sampling.  Quality assurance guidelines

outline what is pertinent to the production of acceptable data

and emission data are considered reliable only if the proper

quality assurance measures are taken.  The steps outlined herein

are intended to ensure the production of quality data through our

testing and analysis procedures.

     Quality control procedures for the standard reference

methods were used throughout this test series.  These included,

but were not limited to, the following:

     0    Calibration of field sampling equipment.  Tables 5-1
          through 5-12 summarize calibration of equipment used in
          this test series.  Calibration guidelines are described
          in more detail in Appendix E.

     0    Train configuration and calculation checks.

     0    Onsite quality assurance checks such as leak checks of
          the sampling train, the pitot tube, and the Orsat line.

     0    Use of designated analytical equipment and sampling
          reagents.

     0    Lab analysis procedures.  Tables 5-13 and 5-14 show the
          results of quality assurance tests for accuracy of the
          analysis of field samples.
                                5-1

-------
                                TABLE 5-1.  FIELD EQUIPMENT CALIBRATION, QUAD  TRAIN  NO.  1  (NCOG)
Equipment
Meter box


Pi tot tube

Digital
indicator
Thermocouples
and stack
thermometers

Orsat analyzer

Impinger
thermometer
Trip balance
Barometer

Dry gas
thermometer
Probe nozzle

I.D.
No.
FB-2


1001

125

174


C02
231 02
CO


194
271

Inlet
Outlet
1
2-1
Calibrated
against
Wet test meter


Standard pi tot
tube
Millivolt signals

ASTM-2F or 3F



Standard gas

ASTM-2F or 3F

Type S weights
NBS traceable
barometer
ASTM-2F Of 3F

Caliper

Allowable
deviation
Y +0.02 Y
AH G» +0.15
(Y +0.05 Y post-test)
Cp +0.01

0.52

1.5S
(+2r, saturated)


+0.5X

+2°F

+0.5 g
+0.10 in. Hg.
(0.20 post test)
+5°F

Dn +0.004 in.

Actual
deviation
-3.0%


OK

+0.3%

0.4%


+0.2%
+0.1%
-0.4%
OK

+0.1 g
+0.02
in.
-2°F
-1°F
0.001 in.
0.002 in.
Within
allowable
limits
/


/

/

/





/

'
/

/
/
/
^
Comments






















in

-------
                                  TABLE 5-2.  FIELD EQUIPMENT CALIBRATION, QUAD  TRAIN  NO.  2  (NCOG)
Equipment
Meter box


Pi tot tube

Digital
indicator
Thermocouples
and stack
thermometers

Orsat analyzer
Impinger
thermometer
Trip balance
Barometer

Dry gas
thermometer
Probe nozzle

I.D.
No.
FB-10


1001

125

174


C00
w •
231 D£


194
271

Inlet
Outlet
2
2-2
Calibrated
against
Wet test meter


Standard pi tot
tube
Millivolt signals

ASTM-2F or 3F



Standard gas
ASTM-2F or 3F

Type S weights
NBS traceable
barometer
ASTM-2F Of 3F

Cali per

Allowable
deviation
Y +0.02 Y
AH P +0.15
(Y +0.05 Y post-test)
Cp +0.01

0.5%

1.5%
(+2% saturated)


+0.5%
+2°F

+0.5 g
+0.10 in. Hg.
(0.20 post test)
+5°F

Dn +0.004 in.

Actual
deviation
-3.1%


OK

+0.3%

0.4%


+0.2%
+0.15
-0.4%
OK

+0.1 g
+0.02 in.

-2°F
-1°F
0.001 in
0.002 in
Within
allowable
limits
/


/

/

/

•
*
/
/

'
/

/.

/
^
Comments





















Ul
I
U)

-------
                                  TABLE 5-3.  FIELD EQUIPMENT CALIBRATION,  QUAD TRAIN NO.  3 (NCOG)
Equipment
Meter box
Pi tot tube
Digital
indicator
Thermocouples
and stack
thermometers
Orsat analyzer
Impinger
thermometer
Trip balance
Barometer
Dry gas
thermometer
Probe nozzle
I.D.
No.
FB-1
1001
124
174
CO?
231 o?
CO
194
271
Inlet
Outlet
3
3-3
Calibrated
against
Wet test meter
Standard pi tot
tube
Millivolt signals
ASTM-2F or 3F
Standard gas
ASTM-2F or 3F
Type S weights
NBS traceable
barometer
ASTM-2F Of 3F
Cali per
Allowable
deviation
Y +0.02 Y
AH (a +0.15
(Y +0.05 Y post-test)
Cp +0.01
0.5%
1 5%
(+2% saturated)
+0.5%
+2°F
+0.5 g
+0.10 in. Hg.
(0.20 post test)
+5°F
Dn +0.004 in.
Actual
deviation
-2.2%
OK
-0.4%
0.4%
+0.2%
+0.1%
-0.4%
OK
+0.1 g
+0.02 in.
0°F
0.001 in.
0.000 in.
Within
allowable
limits
'
'
/
/
/
'
J
^
Comments








Ul
I
*>.

-------
                                 TABLE  5-4.   FIELD EQUIPMENT CALIBRATION, QUAD TRAIN NO. 4 (NCOG)
Equipment
Meter box


Pi tot tube

Digital
indicator
Thermocouples
and stack
thermometers

Orsat analyzer

Impinger
thermometer
Trip balance
Barometer

Dry gas
thermometer
Probe nozzle

I.D.
No.
FB-5


1001

124

174


C09
231 0~
CO


194
271

Inlet
Outl et
4
3-4
Calibrated
against
Wet test meter


Standard pi tot
tube
Millivolt signals

ASTM-2F or 3F



Standard gas

ASTM-2F or 3F

Type S weights
NBS traceable
barometer
ASTM-2F or 3F

Caliper

Allowable
deviation
Y +0.02 Y
AH 0 +0.15
(Y +0.05 Y post-test)
Cp +0.01

0.5%

1.5%
(^2% saturated)


+0.5%

+2°F

+0.5 g
+0.10 in. Hg.
(0.20 post test)
+5°F

Dn +0.004 in.

Actual
deviation
-3.6%


OK

-0.4%

0.4%


+0.2%
+0.1%
-0.4%
OK

+0.1 g
+0.02 in.

0°F
-1°F
0.000 in.
0.003 in.
Within
allowable
limits
/


/

/

/


/
J
*
/

'
/

/
^


Comments






















01
I
Ul

-------
TABLE 5-5.  FIELD EQUIPMENT CALIBRATION, TRAIN NO. 5 (NCOG)
Equipment
Meter box


Pi tot tube

Digital
indicator
Thermocouples
and stack
thermometers

Orsat analyzer

Impinger
thermometer
Trip balance
Barometer

Dry gas
thermometer
Probe nozzle

I.D.
No.
FB-4


186

207

203


C02
231 Op
CO


194
271

Inlet
Outlet
6-105
6-114
8-103
Calibrated
against
Wet test meter


Standard pi tot
tube
Millivolt signals

ASTM-2F or 3F



Standard gas

ASTM-2F or 3F

Type S weights
NBS traceable
barometer
ASTM-2F Of 3F

Caliper

Allowable
deviation
Y +0.02 Y
AH (a +0.15
(Y +0.05 Y post-test)
Cp +0.01

0.5%

1.5S
(+2% saturated)


+0.5%

+2°F

+0.5 g
+0.10 in. Hg.
(0.20 post test)
+5°F

Dn +0.004 in.

Actual
deviation
-0.6%


0.00

-0.4%

0.3%


+0.2%
+0.1%
-0.4%
OK

+0.1 g
+0.02 in.

-3°F
+1 °F
Q.'QOQ in.'
n nfll -in
\J f \J\S t Ilia
Within
allowable
limits
/


/

/

/





/

/
/

/
*
/
y
Comments























-------
                             TABLE  5-6.   FIELD EQUIPMENT CALIBRATION, TRAIN NO.  6 (NCOG)
Equipment
Meter box


Pi tot tube

Digital
indicator
Thermocouples
and stack
thermometers

Orsat analyzer
Impinger
thermometer
Trip balance
Barometer


Dry gas
thermometer

Probe nozzle
I.D.
No.
FB-8


186

207

203


C02
231 02
CO


194
271

Inlet
Outlet

A
B
Calibrated
against
Wet test meter


Standard pi tot
tube
Millivolt signals

ASTM-2F or 3F



Standard gas
ASTM-2F or 3F

Type S weights
NBS traceable
barometer

ASTM-2F Of 3F


Cali per
Allowable
deviation
Y +0.02 Y
AH (3 +0.15
(Y +0.05 Y post-test)
Cp +0.01

0.5%

1.5%
(+2% saturated)


+0.5%
+2°F

+0.5 g
+0.10 in. Hg.
(0.20 post test)

+5°F


On +0.004 in.
Actual
deviation
-0.4%


0.00

-0.4%

0.3%

t f\ OO/
+0.2%
+01%
1 \J • 1/0
-0.4%
OK

+0.1 g
+0.02 in,

+2°F
-3°F

0.001 in.
0.001 in.
Within
allowable
limits
/


/

/

/

,
/
'
/

/
/

/
/

/
/
Comments






















en

-------
                              TABLE 5-7.   FIELD EQUIPMENT CALIBRATION, QUAD  TRAIN  NO.  1  (DC06)
Equipment
Meter box
Pi tot tube
Digital
Indicator
Thermocouples
and stack
thermometers
Orsat analyzer
Impinger
thermometer
Trip balance
Barometer
Dry gas
thermometer
Probe nozzle
I.D.
No.
FB-2
1001
125
133
C09
230 0~
or
1
196
225
Inlet
Outlet
1-1
2-1
Calibrated
against
Wet test meter
Standard pi tot
tube
Millivolt signals
ASTM-2F or 3F
Standard gas
ASTM-2F or 3F
Type S weights
NBS traceable
barometer
ASTM-2F Of 3F
Cali per
Allowable
deviation
Y +0.02 Y
AH 0 +0.15
(Y +0.05 Y post- test)
Cp +0.01
0.5%
1.5%
(+2% saturated)
+0.5%
+2°F
+0.5 g
+0.10 in. Hg.
(0.20 post test)
+5°F
Dn +0.004 in.
Actual
deviation
-2.7%
OK
+0.3%
-0.5%
+0.4%
-0.3%
-0.5%
-4°F
+0.3 g
+0.01 in.
+4°F
+2°F
0.001 in.
0.001 in.
Within
allowable
limits
/
'
'
J
/
'
/
'
Comments



Correction factor used




in
I
oo

-------
                              TABLE 5-8.  FIELD EQUIPMENT CALIBRATION, QUAD  TRAIN  NO.  2 (DC06)
Equipment
Meter box


PUot tube

Digital
indicator
Thermocouples
and stack
thermometers

Orsat analyzer

Impinger
thermometer
Trip balance
Barometer

Dry gas
thermometer

Probe nozzle
I.D.
No.
FB-5


1001

125

133


C02
230 09
CO^
2

196
225

Inlet
Outlet
1-2
2-2
Calibrated
against
Wet test meter


Standard pi tot
tube
Millivolt signals

ASTM-2F or 3F



Standard gas

ASTM-2F or 3F

Type S weights
NBS traceable
barometer
ASTM-2F Of 3F

Cali per
Allowable
deviation
Y +0.02 Y
AH 9 +0.15
(Y +0.05 Y post-test)
Cp +0.01

0.5%

1.5%
(+2% saturated)


+0.5%

+2°F

+J).5 g
+0.10 in. Hrj.
(0.20 post test)
+5°F

Dn +0.004 in.
Actual
deviation
-2.3%


OK

+0.3%

-0.5%


+0.4%
-0.3%
-0.5%
-4°F

+ 0.3 q
+0.01 in.

+4°F
+2°F
0.001 in.
0.000 in.
Within
allowable
limits
/


/

/

/



/
/


/
/

/
/
/
/
Comments













Correction factor used







en
I
vo

-------
                             TABLE  5-9.   FIELD EQUfPMENT CALIBRATION,  QUAD TRAIN NO.  3 (DCOG)
Equipment
Meter box


PHot tube

Digital
indicator
Thermocouples
and stack
thermometers

Orsat analyzer

Impinger
thermometer
Trip balance
Barometer


Dry gas
thermometer

Probe nozzle
I.D.
No.
FB-8


1001

124

133


C0?
230 0,
or
3
196
225

Inlet
Outlet

1-3
2-3
Calibrated
against
Wet test meter


Standard pi tot
tube
Millivolt signals

ASTM-2F or 3F



Standard gas

ASTM-2F or 3F
Type S weights
NBS traceable
barometer

ASTM-2F Of 3F


Caliper
Allowable
deviation
Y +0.02 Y
AH P +0.15
(Y +0.05 Y post-test)
Cp +0.01

0.5%

i.sr,
(+2% saturated)


+0.5%

+2°F
+.0.5 g
+0.10 in. Hg.
(0.20 post test)

+5°F


Dn +0.004 in.
Actual
deviation
-0.6*


OK

-0.5%

-0.5%


+0.4%
-0.3%
-0.5%
-2°F
+0.3 g
+0.01 in.

-3°F
-2°F

0.000 in.
0.001 in.
Within
allowable
limits
/


/

/

/


/
/

/
/
/

/
•

/
/
Comments






















Ul

-------
                                 TABLE 5-10.   FIELD EQUIPMENT CALIBRATION, QUAD TRAIN NO. 4 (DCOG)
Equipment
Meter box


Pi tot tube

Digital
indicator
Thermocouples
and stack
thermometers

Orsat analyzer

Impinger
thermometer
Trip balance
Barometer


Dry gas
thermometer

Probe nozzle
I.D.
No.
FB-4


1001

124

133


C09
230 0^
CO
4

196
225

Inlet
Outlet

1-4
2-4
Calibrated
against
Wet test meter


Standard pi tot
tube
Millivolt signals

ASTM-2F or 3F



Standard gas

ASTM-2F or 3F

Type S weights
NBS traceable
barometer

ASTM-2F of 3F


Caliper
Allowable
deviation
Y +0.02 Y
AH (? +0.15
(Y +0.05 Y post-test)
Cp +0.01

0.5%

1.5%
(+2% saturated)


+0.5%

+2°F

+0.5 g
+0.10 in. Hg.
(0.20 post test)

+5°F


Dn +0.004 in.
Actual
deviation
+0.9%


OK

-0.5%

-0.5%


+0.4%
-0.3%
-0.5%
0°F

+0.3 g
+0.01 in.

0°F
0°F

3.001 in.
0.001 in.
Within
allowable
limits
/


/

/

/


/
/
/
/

/
/

/
/

/
/
Comments

I





















en
l

-------
                                 TABLE  5-11.   FIELD  EQUIPMENT CALIBRATION, TRAIN NO. 5 (DCOG)
Equipment
Meter box


Pi tot tube

Digital
indicator
Thermocouples
and stack
thermometers

Orsat analyzer

Impinger
thermometer
Trip balance
Barometer

Dry gas
thermometer
Probe nozzle
I.D.
No.
FB-1


034

221

133


C09
230 Oo
CO
5

196
225

Inlet
Outlet
352-104
7-101
Calibrated
against
Wet test meter


Standard pi tot
tube
Millivolt signals

ASTM-2F or 3F



Standard gas

ASTM-2F or 3F

Type S weights
NBS traceable
barometer
ASTM-2F Of 3F

Caliper
Allowable
deviation
Y +0.02 Y
AH (3 +0.15
(Y +0.05 Y post-test)
Cp +0.01

0.5%

1.5%
(+2% saturated)


+0.5%

+2°F

+0.5 g
+0.10 in. Hg.
(0.20 post test)
+5°F

Dn +0.004 in.
Actual
deviation
-3.7%


0.00

+0.4%

-0.5%


+0.4%
-0.3%
Oc o/
. 5%
OK

+0.3 g
+0.01 in.

-2°F
-5°F
0.002 in.
0.002 in.
Within
allowable
limits
/


/

/

/



J
*
/

'
/



^
Comments





















Ui

H
ro

-------
                               TABLE 5-12.   FIELD EQUIPMENT CALIBRATION, TRAIN NO. 6 (DCOG)
Equipment
Meter box


Pi tot tube

Digital
indicator
Thermocouples
and stack
thermometers

Orsat analyzer

Impinger
thermometer
Trip balance
Barometer

Dry gas
thermometer

Probe nozzle
I.D.
No.
FB-6


034

221

133


CO-
230 0~
or
6

196
225

Inlet
Outlet
6-108
6-105
Calibrated
against
Wet test meter


Standard pi tot
tube
Millivolt signals

ASTM-2F or 3F



Standard gas

ASTM-2F or 3F

Type S weights
NBS traceable
barometer
ASTM-2F Of 3F


Caliper
Allowable
deviation
Y +0.02 Y
AH (3 +0.15
(Y +0.05 Y post- test)
Cp +0.01

0.5%

1.5?,
(+2% saturated)


+0.5%

+2°F

+0.5 g
+0.10 in. Hg.
(0.20 post test)
+5°F


Dn +0.004 in.
Actual
deviation
-1.6%


0.00

+0.4%

-0.5%


+0.4%
-0.3%
-0.5%
OK
\Jt\
+0.3 g
+0.01 in.

-4°F
-4°F
0.001 in.
0.000 in.
Within
allowable
limits
/


/

/

/


/
/
/
^

/
/

/
^
/
/
Comments










•











U>

-------
TABLE 5-13.   FILTER AND REAGENT  BLANK ANALYSIS, NCOG TEST SERIES
Sample type and
analytical procedure
Acetone
Gravimetric
IPA extraction
H20 extraction
Filter
Gravimetric



IPA extraction
H20 extraction
Total organic carbon
(oxidation tech-
nique)
Method 5 back half
Ether/chloriform
Inorganic
Organic
Total organic carbon
(ampute tech-
nique)
Method 8 IPA solution
H2S04 titration


Method 8 H20^ solution
S02 titration
Lab No. (sample
volume, ml)
CB 954 (219)
CB 955 (348)
CB 954
CB 954

CB 894
CB 895
CB 900
CB 901
CB 901
CB 901
CB 900

CC 026 (196)
CC 027 (384)
CC 026 (150)
CC 027 (150)
CC 026 (60)
CC 027 (60)

CB 982
CB 983
CB 984
CB 985
CC 013-15
Blank weight,
mg
0.4
0.7
<0.3
<0.21

0.3
0.8
0.3
0.7
<0.3
<0.42
1.28

4.0
3.8
1.6
1.3
0.5
0.05

0.25
0.22
0.20
<0.15
<1
Comments










0.01 used in
calculations





                             5-14

-------
TABLE 5-14.   FILTER AND  REAGENT BLANK ANALYSIS, DCOG TEST SERIES
Sample type and
analytical procedure
Acetone
Gravimetric

IPA extraction
HpO extraction
Filter
Gravimetric



IPA extraction
H20 extraction
Total organic carbon
(oxidation tech-
nique)
Method 5 back half
Ether/chloriform
Inorganic



Organic



Total organic carbon
(ampute technique)
Method 8 IPA solution
H2S04 titration
Method 8 H202 solution
S02 titration
Lab No. (sample
volume, ml)

CC 769 (270)
CC 770 (275)
CC 769
CC 769

CC 666
CC 672
CC 671
CC 673
CC 669
CC 669
CC 666
CC 666



CC 771 (225)

CC 772 (205)

CC 771 (150)

CC 772 (150)

CC 771 (60)
CC 772 (60

773-6
CC 778-9

Blank weight,
mg

-0.9
1.1
<0.05
<0.24

0.2
0.1
0.3
0.2
<0.3
<0.24
1.58
1.65



-0.9

-0.5

4.7

-0.3

0.3
0.7

<0.11
0.0


Comments

0.0 used in cal-
culation














0.0 used in cal-
culations
0.0 used in cal-
culations
0.01 used in cal-
. culations
0.0 used in cal-
culations






                             5-15

-------
     0    Internal and external audits to ensure accuracy in
          sampling and and analysis.  Onsite audit data sheets
          are included in Appendix B, Section 1.1 and 2.1.

     Audit solutions prepared by EPA were used to check the

analytical procedures and reagents prior to onsite S02 sample

analysis.  The results of the onsite analytical audit are pre-

sented below:

                    Audit solution       Measured
  Audit sample      concentration,    concentration,     Percent
    lot No.            mg/dNm	       mg/dNm	   difference

  3291 (NCOG)            22.89             22.75         -0.6
  3575 (NCOG)            17.16             16.98         -1.0
  8026 (DCOG)           381.3             383.3          +0.5
  6220 (DCOG)          1334.6            1321.2          -1.0

     Table 5-15 details the results obtained by Method 15 analy-

sis of EPA-prepared reduced-sulfur gases.

     Sampling equipment, reagents, and analytical procedures for

this test series follow and meet all necessary guidelines set

forth for accurate test results.  Calibrations of particulate

sampling equipment are all within limits described for Method 5

in the Federal Register.*  Sample analysis and reagent quality

also meet with Federal regulations described in Method 5 of the

Federal Register.*
 40 CFR 60, Appendix A, Reference Method 5, July 1, 1980.
                                 5-16

-------
          TABLE 5-15.  SUMMARY OF  RESULTS OBTAINED THROUGH METHOD 15
                         ANALYSIS OF AUDIT GASES3
Cylinder
I.D.
RTI-b-704
428 ppm H2S
RTI-705
649 ppm H0S
L.
RTI-1584
100 ppm COS


Date
1/26/82

12/8/81
12/9/81

12/9/81
12/9/81

12/12/81
Time
1400

1754
1730

1648
1757

1530
TRS concentra-
tion, ppm
449

797
540

94
103

96
Comments
Dynamic dilution

Bag sample
Dynamic dilution
35.1 to 1
Bag sample
Dynamic dilution
3.18 to 1
Bag sample
 All  acceptable  COS  results  required a correction factor of 1.257 because of
 an  incorrect  permeation  rate.

3RTI  =  Research  Triangle  Institute.
                                    5-17

-------
                APPENDIX A




COMPUTER PRINTOUTS AND EXAMPLE CALCULATIONS
                     A-l

-------
                         CONCENTRATION CALCULATIONS
CS (Part), mg/m3 = MN/V     (m3)
                       mstd

CS (Part), gr/dscf = 0.001  x MN x 15.43/Vm    (ft3)
                                         mstd

CS (S09 or H,SOA), mg/m3 =  SN/Vm    (m3)
      i     *•  *               mstd

CS (S02 or H2S04), ppm = CS (S02 or H2S04),  mg/m3  x  24.06/MW


CS (SO, or H9SOJ, gr/dscf  = 0.001  x SN x 15.43/V      (ft3)
      *     ^  4                                mstd
where

     CS (Part) = concentration of participate  at  stated  parameters

      CS (SOp) = concentration of sulfur dioxide  at  stated  parameters

            MN = particulate catch at  stated parameter  (mg)

         V     = volume method at 68°F and  29.92  in.Hg,  (m3 or  ft3)
          mstd

            SN = sulfur dioxide catch  (mg)  or  sulfuric acid catch  (mg)

            MW = molecular weight of S09 =  64  g/g mole,  H9SO,, = 98,
                 H2S04-2H20 = 134      L                 *•  *
                                    A-2

-------
1.0  NCOG Underfiring Test Series
          October 1981
              A-3

-------
                  STACK VELOCITY DATA
      PLANT
      DATE
      SAMPLING LOCATION
      RUN NUMBER

      CLOCK TIME
      OPERATOR
      AMBIENT TEMP. (OEG.F)
      BAR.PRESS.(IN HG)
      STATIC PRESS.(IN H20)
      MOLECULAR HEIGHT
      STACK INSIDE OIM(IN)
      PITOT TUBE COEFF.
      MOISTURE CONTENT(X)
TRAVERSE
 POINT
  NO.
POSITION
 INCHES
REPUBLIC STEEL CLEVELAND
io/22/ei
COKE BATTERY STACK-NO.1
 PRE-1

 954
CB-DO
 54.
 29.60
 -1.20
 29.00
 97.500
  .80
 12.00

        VELOCITY
          HEAO
        (IN H20)
 STACK
 TEMP
(OEG.F)
    01
    02
    03
    OQ
    05
    Ob
    07
    08
    09
    10
    11
    12
    .0
    .0
    .0
    .0
    .0
    .0
    .0
    .0
    .0
    .0
    .0
    .0
         .020
         .050
         .045
         .060
         .000
         .OBO
         .070
         .060
         .050
         .070
         .060
         .050
  128.
  305.
  430.
  510.
  480.
  406.
  487.
  492.
  497.
  496.
  497.
  497.
  AVERAGE
                   .058
                                 442.

-------
         PLANT
         DATE
         SAMPLING LOCATION
         RUN NUMHER

  STACK AREA, SO. FT.
  STACK ABS. PRES.. IN HG.
  STACK CAS TEMPERATURCt OEG.F
  3URUVEL HO X STACK TEMP ABS)
REPUBLIC STEEL CLEVELAND
10/28/81
CUKE BATTERY STACK-NO.1
 PRE-1

        51.809
        29.51
        • 02.
         7.2
  STACK GAS VELOCITY, ACT. FPS          17.6
  STACK GAS VOLUME  (MET), ACT. CFM.  50876.8
  STACK GAS VOLUME  (ORY), ACT. CFM.  aB291.5
  STACK GAS VOLUME  3 29.92 IN. HG  AND  68  DG.
                (DRY)                 27879.9
                (WET)                 31681.H
              F !
 \
t_n

-------
                                              SAMPLE CALCULATIONS
SYMBOLS!
          AREA      CROSS-SECTIONAL STACK AREA,  SO FT
          BPRES     BAROMETRIC PRESSURE,  IN HG
          OELP      DELTA P
          OIA       DIAMETER OF CIRCULAR  STACK,  IN
          DIM1      LENGTH OF RECTANGULAR STACK, IN
          DIM2      WIDTH OF RECTANGULAR  STACK,  IN
          MOIST     MOISTURE CONTENT
          M*»        MOLECULAR WEIGHT
          NP        NUMBER OF TRAVERSE POINTS
          BM        MOLE FRACTION WATER VAPOR
PTC       PITOT TUBE COEFFICENT
SPUES     STATIC PRESSURE, IN H20
STEMP     STACK TEMPERATURE, OEG F
STPRES    STACK PRESSURE, IN HG
STVEL     STACK VELOCITY, AFPM
TEI*P      TEMPERATURE, DEC F
VH        VELOCITY HEAD, IN H?O
SVOLFLH   STANDARD VOLUMETRIC FLOM  (WET),  ACFM
VOLFLW    VOLUMETRIC FLOW (WET), ACFM
SVOLFLO   STANDARD VOLUMETRIC FLOW  (DRY),  DSCFM
FORMULAS AND SAMPLE CALCULATIONS:


                    SUMI30RTIVH * TEMP))            86.2

          DEL?  =  —	-—	—  =	  =     7.2
                          NP                       12


          STPRES  =  BPKES + (SPRES/13.6)  =  29.60 * ( -1.20/13.6)  =    29.5 IN HG


                     SUM (STEMP]           5305.
          StEMP  =  —	  r • —	—  a   442.  DEC F

                       NP                 12


                                   3.1016 * (DIA/2)**2        3.1416 * ( 97.500/2)**2
          AREA(CIRCULAR STACK)   =  —	  =  	—  «   51.849 SO FT
                                           104                       144


                     85.49 * PTC • DELP       85.49 *  .84 •    7.2
          STVEL  «  "	———-——   =	......  z   17.6 AFPM
                     SORT(MH • STPRF31         SORT(  29.00 •  29.5 )


          VOLFLW  a  60. » STVEL * AREA  =  60. *  17.6 *   51.849  =   54876.8 ACFM


          SVOLFLM  *  VOLFLM * STPRES  * ( 460. + 68. )       54876.8 *  29.5 * ( 460. * 68. )
                      ................................  s   ........—...................	..  s     31681.8 ACFM

                          29.92 * ( STEMP » 460. )               29.92 * (  442.1 » 460. )


          3VOLFLD = SVOLFLW * (1 - BH)  f    31681.8 * (1 -     .12) s    27879.9 DSCFM

-------
                       STACK VELOCITY DATA
 I
-J
           PLANT
           DATE
           SAMPLING LOCATION
           RUN NUMBER
REPUBLIC STEEL CLEVELAND
10/22/81
COKE BATTERY STACK-NO.1
 PRE-2
CLOCK TIME 95Q
OPERATOR CB-00
AMBIENT TEMP. (DEG.F) 54.
BAR. PRESS. (IN H9) 29.60
STATIC PRESS. (IN H20) -1.20
MOLECULAR WEIGHT 29.00
STACK INSIDE DIM(IN) 97.500
PITOT TUBE COEFF. .84
MOISTURE CONTENTU) 12.00
TRAVERSE POSITION
POINT INCHES
NO. 	 	
01 .0
_. 02 ..-. ^0
03 .0
04 .0
05 .0
06 .0
07 .0
08 .0
09 .0
10 .0
11 .0
12 .0









VELOCITY
HEAD
(IN H20)
.045
.050
.060
.060
.060
.060
.060
.055
.050
.050
.040
.040









STACK
TEMP
(DEG.F)
345.
392.
415.
430.
452.
473.
480.
483.
484.
486.
487.
487.
       AVERAGE
         .052
451,

-------
           PLANT
           0»TC
           SAMPLING LOCATION
           RUN NUMBER

    STACK  AREA, SO. FT.
    STACK  ABS. PRES.,  IN H6.
    STACK  GAS TEMPERATURE,  DEG.F
    SQRMVEL HD X  STACK  TEMP ABS)
REPUBLIC STEEL CLEVELAND
10/22/81
COKE BATTERY STACK-NO.1
 PRE-2

        51.8«9
        a*.si
        051.
         6.9
    STACK  6AS  VELOCITY,  ACT.  FPS          16.9
    STACK  GAS  VOLUME  (NET),  ACT.  CFM.  52657.0
    STACK  GAS  VOLUME  (DRY),  ACT.  CFM.  46336.2
    STACK  GAS  VOLUME  3 29.92  IN.  HG  AND 66  DG.  F
                 (DRY)                 26485.5
                 (WET)                 30097.2
 I
oo

-------
                                                         SAMPLE CALCULATIONS
            SYMBOLS:
                      AREA      CROSS-SECTIONAL  STACK  AREA, SO FT
                      BPRES     BAROMETRIC PRESSURE,  IN  HG
                      OELP      DELTA P
                      DIA       DIAMETER OF CIRCULAR  STACK, IN
                      OIMJ      LENGTH OF RECTANGULAR  STACK,  IN
                      DIM2      WIDTH OF RECTANGULAR  STACK, IN
                      MOIST     MOISTURE CONTENT
                      MM        MOLECULAR WEIGHT
                      NP        NUMBER OF TRAVERSE POINTS
                      BN        MOLE FRACTION  MATER VAPOR
                                                                       PTC       PITOT  TUBE COEFF1CENT
                                                                       SPRES     STATIC PRESSURE,  IN H20
                                                                       STEMP     STACK  TEMPERATURE,  DEC F
                                                                       STPRES    STACK  PRESSURE, IN  HG
                                                                       STVEL     STACK  VELOCITY, AFPM
                                                                       TEMP      TEMPERATURE,  DEC  F
                                                                       VH        VELOCITY  HEAD,  IN M20
                                                                       SVOLFLM   STANDARD  VOLUMETRIC FLOW (WET), ACFM
                                                                       VOLFLW    VOLUMETRIC FLO* (WET), ACFM
                                                                       SVOLFLD   STANDARD  VOLUMETRIC FLOW (DRY), DSCFM
 I
vo
 FORMULAS AND SAMPLE  CALCULATIONS:


                     SUM(SORT(VM *  TEMP)!            82.7
           6ELP  «  ————————  e  ..........  .     6.9
                           NP                        12


           STPRES  s   BPRES *  (SPRES/13.6)  «  29.60 » (  -1.20/13.6)  *    29.5 IN HG


                      SUMISTEMP)           5414.
"~~        SfEMP  s  ————  •  .—.——   s   451.  DEC  F
                        NP                  12


                                    3.1416 * (DlA/2)**2        3.1416 * (  97.500/2)0*2
           AREA(CIRCULAR STACK)  a   ...———	  = 	.	  a   51.849 SO FT
                                            144                       144


                      65.49 •  PTC * DELP       05.49 •  .84 *     6.9
           STVEL  «  ..—.—.——   •  —	...............  s    16.9 AFPM
                      SORT [MW  * STPRES)         SORT {  29.00 »   29.5 )


           VOLFLW  s   60- • STVEL * AREA  e  60.  •  16.9  •   51.849   «  52657.0 ACFM


           SVOLFLW  c VOLFLW  * STPRES • ( 460. * 68.  )       52657.0 * 29.5  • (  460. * 68.  )
                      .........	...............	..  *   ........	................	..   *     30097.2 ACFM

                           29.92 •  ( STEMP * 460. )              29.92 *  (  451.2 « 460. )


           SVOLFLO  e  SVOLFLW • (I - BW)  s    30097.2 »  (1  -    .12)  «   26485.5 OSCFM

-------
                        STACK  VELOCITY  DATA
            PLANT
            DATE
            SAMPLING LOCATION
            RUN NUMBER

            CLOCK TIME
            OPERATOR
            AMBIENT TEMP.  (DEG.F)
            BAR.PRESS.(IN  HC)
            STATIC PRESS.(IN H20)
            MOLECULAR HEIGHT
            STACK INSIDE DIM(IN)
            PITOT TUBE COEFF.
            MOISTURE CONTENT(X)
      TRAVERSE
       POINT
        NO.
              POSITION
               INCHES
      REPUBLIC STEEL CLEVELAND
      10/27/61
      COKE STACK
        V.T.

      1300
      DO/HP
       62.
       29.39
       •1.20
       29.00
       97.500
        .63
       12.00

              VELOCITY
                HEAD
              (IN H20)
                       STACK
                       TEMP
                      (DEG.F)
>
I
01
02
03
04
05
06
07
06
09
10
11
12
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.042
.050
.005
.060
.055
.056
.065
.065
.064
.062
• 060
.055
445.
464.
476.
494.
515.
515.
512.
511.
510.
509.
507.
507.
        AVERAQT
                                 ,057

-------
          PLANT
          DATE
          SAMPLING LOCATION
          RUN NUMBER

   STACK AREA, SO. FT.
   STACK ABS. PRE3.. IN HC.
   STACK GAS TEMPERATURE* DEG.F
   SQRT(VEL HD X STACK TEMP  ABS)
REPUBLIC STEEL CLEVELAND
10/27/81
COKE STACK
  V.T.

        SI.649
        29.30
        499.
         T.4
   STACK GAS VELOCITY, ACT. FPS          1S.O
   STACK GAS VOLUME  (MET), ACT. CFM. 56014.3
   STACK GAS VOLUME  (DRY), ACT. CFM. 49292.5
   STACK GAS VOLUME  9 29.92 IN. M6 AND 68 06. F
                 (DRY)                26585.3
                 (MET)                30210.6
>
 I

-------
                                               SAMPLE  CALCULATIONS
 STMBOLSl
           AREA       CROSS-SECTIONAL  STACK  AREA,  SO FT
           BPRES      BAROMETRIC  PRESSURE*  IN  H6
           OELP       DELTA  P
           OIA        DIAMETER  OF CIRCULAR  STACK*  IN
           DIM1       LENGTM OF RECTANGULAR  STACK,  IN
           DIM2       MIDTH  OF  RECTANGULAR  STACK,  IN
           MOIST      MOISTURE  CONTENT
           MM        MOLECULAR HEIGHT
           NP        NUMBER OF TRAVERSE  POINTS
           BH        MOLE FRACTION  MATER VAPOR
PTC       PITOT TUBE COEFFICENT
SPRE8     STATIC PRESSURE, IN H20
STEMP     STACK TEMPERATURE, DEC F
STPRES    STACK PRESSURE, IN MG
8TVEL     STACK VELOCITY, AFPM
TEMP      TEMPERATURE, DEG F
VH        VELOCITY HEAD,  IN H20
SVOLFLN   STANDARD VOLUMETRIC FLON  (MET),  ACFM
VOLFLM    VOLUMETRIC FLON (MET)* ACFM
SVOLFLO   STANDARD VOLUMETRIC FLOM  (DRY)*  OSCFM
 FORMULAS  AND  SAMPLE  CALCULATIONS!

                     SUM (SORT(VH  •  TEMP))            88.8
 	      Ofil»   «  ——————   m   ..........   •      T.4
                           NP                        12

           STPRES-  »   BPRES +  (SPRES/13.6)   »   29.39 *  ( -1.20/13.6)   •     29.3  IN HG

                      SUM (STEMP)          5985.
	      STEMP  «  —..——.—  *   ———   •   «99.  DEG F
                       NP                  12

                                   3.141ft  * (DIA/2)**2        3.1416  *  (  97.300/2)**2
           AREA(CIRCULAR STACK)   •  ————————   •   —————  «   91.849 SQ FT
 _                                          144                       140

                      85.49 *  PTC * OELP        85.49 *   .83 •     7.4
           STVEL  «  ————   c .........—...——  •   is.Q  AFPM
                      SORT (MM  * STPRES)         SORTt 29.00 *   29.3 )

           VOLFLM  *   60. • STVEL * AREA  • 60.  *  18.0 •  51.849  «    56014.3  ACFM

           SVOLFLM  « VOLFLM  * STPRES •  (  460. * 68. )        56014.3  *  29*3 *  (  460. * 68. )
                      ................................ •  ..................................  •     30210.6 ACFM
                           29.92  •  (  STEMP  » 460.  )               29.92  •  (  498.8 * 460. )

           SVOLFLO  •  SVOLFLM * (1. - 8M) •    30210.6  • (1 -     .12) *     26585.3  OSCFM

-------
                                                               FIELD  OAT*
 I
M
u>
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION NO. 1 COKE BATTERY STACK
SAMPLE TYPE PART/H2S04/S02
OPERATOR BRUFFEY
AMBIENT TEMP. (DEG.F) 62.
BAR. PRESS. (IN. HG) 29.39
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530115
STACK INSIDE DIM. (IN) 97.50 .00
P1TOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM 3 5.0 IN.HG
METER CALIB. FACTOR 1.003
READ » RECORD DATA EVERY 10.0 MINUTES
TRAVERSE
POINT
NO.

INI? "












SAMPLE
TIME
(MIN.)

0~~
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
CLOCK
TIME
(24-HR
f i n^ tf i
CLUCK!
~ 910
920
930
9ao
950
1000
1010
1020
1030
1040
1050
1100
iiio
GAS METER
READING
(CU.FT.)

6 5 6. "4 7 2
661.630
666.670
6M.720
677.260
682.630
687.920
693.050
698.130
703.250
708.370
713.970
720.086
VELOCITY
HEAD
(IN.H20)

. 	 ..
.060
.060
.060
.070
.070
.060
.060
.060
.060
.060
.070
.090
ORIFICE
PRESSUHE
DIFFERENTIAL
(IN.
DESIKED

.76
.72
.72
.87
.87
.72
.72
.72
.72
.72
.87
1.11
H20)
ACTUAL

.76
.72
.72
.87
.87
.72
.72
.72
.72
.72
.87
1.11
STACK
TEfP
(DEG.F)


519.
538.
545.
545.
555.
550.
520.
535.
510.
544.
556.
520.
DATE 10/27/81
RUN NUMBER 1-1
PROBE LENGTH ft TYPE 5* HEATEU GLASS
NUZZLE 1 t I.D. .398
ASSUMED MOISTURE 12.0
SAMPLE BOX NUMBER U
KtTER BOX NUMBER FU2
KttEH Ht»0 OIFF. 1.76
C FACTOR .86
PROBE HEATER SETTING 250.
HEATER BOX SETTING 250.
REFERENCE PRESS. DIFF. .15
OHY GAS MEIER
TEMP
(DEG.F)
ULEI OUTLET

67. 67.
66. 68.
72. 68.
75. 68.
76. 7U.
77. 71.
78. 72.
78. 72.
78. 7cf.
79. 73.
79. 73.
79. 73.
PUMP
VACUUM
(IN.HG)


2.0
2.U
3.0
3.0
2.0
3.0
3.5
3.6
3.6
3.6
3.6
3.6
SAMPLE
BOX TEMP
(OEG.F)


270.
256.
212.
256.
255.
248.
249.
251.
252.
250.
244.
250.
IMPINGEK
TEMP
(DEG.F)


54.
55.
53.
52.
54.
54.
55.
52.
53.
52.
53.
52.
      TOTALS
      AVERAGE
120.0
63.614
                                          .79
                                .79    537.
76.
                                                                          71,
                3.0   252.
53.

-------
           PARTICIPATE FIELD DATA ft RESULTS TABULATION




PLANT- NAME AND ADDRESS               TEST TEAM LEADER




REPUBLIC STEEL CLEVELAND              BRUFFEY
TEST
1-1
NO. 1 COKE BATTERY STACK


TEST DATE
TB
TF
TT
NP
V
ON
___CP
PM
> VM
1
TM
VMSTD
VLC
VHC
BNO
FMD
PC02
P02
PCO
PN2
MD
MMS
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS 	
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
	 PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRV GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRV GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H20 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF MATER VAPOR
AT STANDARD CONDITIONS*
~ PERCENT MOISTURE BV VOLUME
MOLE FRACTION DRV GAS
PERCENT C02 BY VOL., DRY
PERCENT 02 Bv VOL., DRV
PERCENT CO BV VOL., DRV
PERCENT N2 BV VOL., DRY
MOLECULAR MT-ORY STACK GAS
MOLECULAR KT-3TACK GAS
ENGLISH UNITS
10/27/81
1110
120.0
12
1.003
.398 IN
	 .84
.79 IN-H20
63.614 CU-FT
73.0 F
62.205 SCF
fST.S
8.731 SCF
12.31
.677
4.20
1C. 50
.00
85.30
29.0«
27.73
METRIC UNITS
10/27/81
910
1110
120.0
12
1.003
10.1
.84
20.2
1.601
22.6
1.761
185.5
.247
12.31
.877
4.20
10.50
.00
85.30
29.09
27.73



CM

CM-H20
CU-M
C
SCI"

sec









-------
     PB        BAROMETRIC PRESSURE
     PSI     'STATIC PRES OF STACK GAS
     PS        STACK PRES, ABS.
     TS        AVERAGE STACK TEMP
     VS     "~" AV6 STACK GAS VELOCITY
     AS        STACK AREA
     OSSTO     STACK FLOW RATE* DRY*
     OS        ACTUAL STACK FLOW RATE
     ISO       PERCENT ISOKINETIC
     MN        FILTERABLE PART
                 MG. EPA 5
     CS        FILTERABLE PART
     PMR       FILTERABLE PART
                 EMISSION RATE
        •  68 DEC F,  29.92 IN.HG.
     29.39  IN-HG
     •1.20  IN-H20
     29.30  IN-HG
    537.    F
     20.2   FPS
   7466.   SQ-IN
171B626.    SCFH
3777201.    ACFH
    108.b
       .0

       .0000 GR/OSCF*
       .000   LB/HR
   716.51   KM-HG
   -30.as   cf-nao
   7aa,26   CK-HG
   280.     c
     6.2   fPS
     a.817  SO-M
 08666.     SCMH
106960.     »CHH
   108.6
      .0

      .000  CG/OSO
       .00   KG/HK
 I
M
Ul

-------
              EXAMPLE PARTICIPATE CALCULATIONS TEST NO.   1-1

                   NO. 1 COKE BATTERY STACK



        VOLUME OF DRV GAS SAMPLED AT STANDARD CONDITIONS

        VMSTD '• (17.647 • VM * Y * IPB * PM / 1S.6J) / (TM •» 460.)

                  17.607 *    63.614 * 1.003 * ( 24.39 »  .793 / 13.6)
        VMSTD » —————— — ......_.— ....................... -     t>^.^o'3  uscf
                                 (  73. * 460.)



        VOLUME OF HATER VAPOR AT STANDARD CONDITIONS

        VHC • .04707 * VLC

        VHC i .04707 *  i86. *   8.73 SCF



        PERCENT MOISTURE IN STACK GAS

        BHO «~ (100. * VHC) / (VMStb * VHC)

                  100. *   6. 73
 I       BNO * - ------- — • ---- — ------- s 12.31 PERCENT
                    62.205 *   8.73
(Ti
        MOLE FRACTION OF DRY STACK GAS

        FMD e (100. - BMO) / 100.

                  100. -  12.3
        FMD * -— --- — — — --- — s   .877
                       100.
        AVERAGE MOLECULAR HEIGHT OF DRY STACK GAS

        MO « (PC02 * .44) » (P02 * .32) * (PN2 * PCO) * .28

        MD * ( 4.20*44/100) » (10.5*32/100) * ((85.3+ .0) * 28/100 =   29. 09



        MOLECULAR HEIGHT OF STACK GAS

        MHS 8 MD * (1. • (BHO/100)) * 18. * (BNO/100)

        MWS *  29.09* (1. -(12.31/100)) «• 10. * (12.31/100) a   27.73

-------
STACK 6*3 VELOCITY AT STACK CONDITIONS

DELP « SUM. OF THE SORTtVH *  ITS * 160.))

VS s 85.49 * CP • DELP / ISQRT(MMS * PS) • PNTS)

VS * 85.49 *  .84 *   96.387  /  (SORH 27.73 * 29.30)  *  12. =   20.21 FPS




STACK GAS VOLUMETRIC FLOM AT  STACK CONDITIONS

OS = VS * AS • 3600/144

OS * ~ 30.24 •  7466. 3600/144  *    3777241. ACFH




STACK CAS VOLUMETRIC FLOM AT  STANDARD CONDITIONS

OSSTtT* if.647 • OS • PSr
-------
Run No.  1.1
     Sample volume = 1.76  m3.  62.21  scf
Example calculations
     CS (Part) =227.1/1.76 = 129.0 rna/m3
     CS (Part) = 0.001  x 227.1x 15.43/62.21 = 0.56   qr/dscf
     CS (S02)   =1960 /I.76 =1113,6mQ/m3
               =1113.6x 24.06/64 =  419ppm
               = 0.001  x  1960x 15.43/£2L^L_ =  0.486 gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


226.9






81.5
111.4
1960

8.9



3 Concentration,
mg/m


128.9






46.3
63.3
1113.6

5.0



gr/dscf


0.056






0.020
0.028
0.486

0.002



ppm











419

1



                                     A-18

-------
                                                               FIELD  DATA
vo
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION NO.l CUKE BATTERY STACK
SAMPLE TYPE PART/M2S04/SU2
OPERATOR BRUFFEY
AMBIENT fEMP. (DEC. F) 62.
BAR. PRESS. UN. H6) 29.39
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530019
STACK INSIDE DIM. (IN) 97. 50 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .001 CFH 9 6.0 IN.HG
METER CALIB. FACTOR I. 091
READ » RECORD DATA EVERY 10.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY ORIFICE PRESSURE STACK
POINT TIME TIME READING HEAD DIFFERENTIAL TEMP
NO. (MIN.) (24-HR (CU.FT.) (IN.H20) (IN.H20) (DEG.F)

INlf ~ 0""
10.0
20.0
30.0
40.0
50.0
60.0
70.0
ao.o
90.0
100.0
110.0
120.0
1*1. Vl*n /
	 91a —
924
934
944
954
1004
~ 1014
1024
1034
1044
1054
1104
1114
DESIRED
902.817
907.590
912.260
917.320
922. 400
927.530
932.230
936.910
941.610
946.760
951.470
956.660
961.326
._ — ...
.060
.060
.070
.070
.070
".060
.060
.060
.070
.060
.070
.060
.._ .
.76
.72
.87
.87
.87
.72
.72
.72
.87
.72
.87
.72
ACTUAL

.76
.72
.87
.87
.87
.72
.72
.72
.87
.72
.87
.72
DATE 10/27/01
HUN NUMBER 1-2
PHOBE LENGTH ft TYPE 5' HEATED GLASS
NUZZLE 2 : I.D. .397
ASSUMED MOISTURE 12.0
SAMPLE BOX NUMBEH 0
PETER BOX NUMBER FBI
METER MEAD DIFF. i.ao
C FACTOH .86
PROBE HEATER SETTING 250.
HEAIER BOX SETTING 250.
REFERENCE PRESS. DIFF. .15
DHY GAS METER PUMP SAMPLE IMPINGEH
TEMP VACUUM BOX TEMP TEMP
(DEG.F) (IN.HG) (OEG.F) (DEG.F)
INLET OUTLET

527.
541.
542.
549.
561.
515.
523.
538.
533.
550.
562.
520.

72.
71.
76.
80.
81.
83.
83.
84.
84.
8«.
84.
83.
-
73.
73.
74.
75.
75.
76.
76.
77.
78.
78.
79.
78.

.5
.5
.5
.0
.0
.0
.0
.0
.0
.0
4.0
4.0
*
283.
245.
263.
253.
255.
260.
251.
255.
253.
258.
258.
254.

49.
50.
49.
50.
51.
52.
54.
53.
52.
51.
50.
50.
      TOTALS
      AVERAGE
120.0
58.511
                                         .79
                               .79   538,
80.
76.
3.9   257.
51.

-------
           PARTICULATE FIELD DATA & RESULTS TABULATION



PLANT* NAME AND ADDRESS               TEST TEAM LEADER




REPUBLIC STEEL CLEVELAND              BHUFFEY
TEST
1-2
NO.I COKE BATTERY STACK


TEST DATE
TB
TF
TT
NP
Y
DN
CP
PM
>
1
M VM
O
TM
VM3TD
VLC
VMC
BMO
FMD
PC02
P02
PCO
PN2
MD
MHS
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H20 COLLECTED IN
IMPINGERS AND SILICA GELjML.
VOLUME OF MATER VAPOR
AT STANDARD CONDITIONS*
PERCENT ~MOI3tUR£ BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL., DRY
PERCENT 02 BY VOL.* DRY
PERCENT CO BY VOL., DRY
PERCENT N2 BY VOL., DRY
MOLECULAR NT-DRY STACK GAS
MOLECULAR WT-STACK GAS
ENGLISH UNITS
10/27/81
914
1114
120.0
12
1.044
.397 IN
•ea
.79 IN-H20
58.511 CU-FT
78.2 F
58.981 SCF
iS5~.7
8.741 SCF
12.91
.871
4.20
10.50
.00
85.30
29.09
27.66
METRIC UNITS
10/27/81
914
Ilia
120.0
12
1.044
10.1
.84
20.0
1.657
25.7
1.670
185. 1
.248
12.91
.871
4.20
10.50
.00
85.30
29.09
27.66



KM

MM-H20
CU-M
C
SCM

SCM









-------
     PB        BAROMETRIC PRESSURE

     P3I       STATIC PRES OF STACK GAS

     PS        STACK PRES, ABS.

     TS        AVERAGE STACK TEMP

     VS        AVG STACK GAS VELOCITY

     AS        STACK AREA

     OSSTO     STACK FLOH RATEt DRY*

     OS        ACTUAL STACK FLOH RATE

     ISO       PERCENT ISOKINETIC

     MN        FILTERABLE PART
                 MG. EPA 5

     CS        FILTERABLE PART

     PMR       FILTERABLE PART
                 EMISSION RATE

        *   66  DEC F,  29.92 IN.HG.
 29.39  IN-HG

 M.20  IN-H20

 29.30  IN-HG

538.    F

        FP3

       SO-1N

        SCFH

        ACFH
     20.2

   7466.

1698840.

3766316.

    104.7

       .0
   .0000 GR/D3CF*

   .000   LB/HR
   746.51  MM-HG

   -30.48  KM-H80

   744.26  CM-HG

   281.    C

     6.2   PPS

     4.817 30-M

 48106.    SOH

106651.    AC»>H

   104.7

      .0



      .000 PG/DSCP

       .00  KG/HH
 I
NJ

-------
               EXAMPLE  PARTICIPATE CALCULATIONS TEST NO.   1-2


                    NO.l  COKE BATTERY STACK






        VOLUME  OF  DRY  GAS  SAMPLED AT STANDARD CONDITIONS


        VMSTO  « (17.647  •  VM *  Y  * (PB * PM / 13.6)) / (TM » 460.)


                   17.647 •   50.511 * 1.044 • ( 29.39 *  .766 / 13.6)

        VMSTO  » ——————— — — — — ——— — — — — —	-. =     58.981 OSCF

                                  (  78. * 460.)






        VOLUME  OF  MATER  VAPOR AT  STANDARD CONDITIONS


        VtlC *  .04707 * VLC


        VHC V .04707 •   186. »    8.74 3CF






        PERCENT MOISTURE IN  STACK GAS


        BHO"*  (100. •  VMC) / (VMSTD * VWC)


                   100. •  0.74

>       BKO »  —	•	—	— » 12.91 PERCENT

 I                   SB.981 *   8.74
N3
to          ....             ...      ..      	



        MOLE FRACTION OF DRY STACK GAS


        FMD *  (100. - BHO) / 100.
                   100.  -   13.9
        FMD « —————  »   .871

                        100.
        AVERAGE M6LECULAW~N'ClftHT~3F" DRV  STACK


        MD a  (PC02  *  .44)  *  (P02  *  .32)  »  (PN2 * PCO)  * .28


        MD *  ( 4.20*44/100)  «  (10.5*32/100)  *  ((85.3*  .0)  * 28/100 z   29.09





        MOLECULAR HEIGHT OF  STACK GAS


        MhS > MD *  (1. • (BHO/100))  * 18.  *  (BWO/100)


        MMS *  29.09*  (1.  -(12.91/100))  *  18.  » (12.91/100) s   27.66

-------
        STACK  GAS VELOCITY AT STACK CONDITIONS

        OELP * SUM.  OF THE SQRTCVH * (TS * 460.))

        VS » 83.49 * CP * OELP /  (SORT(MWS •  PS)  • PNTS)

        VS * 85.49 *  .84 *   95.993 /  (SORT( 27.66 *  39.30)   *  12.  =   20.18 FPS



        STACK  6AS VOLUMETRIC  FLOM AT STACK CONDITIONS

        OS s VS • AS • 3600/144

        OS «   20.18 *  7466. 3600/144  •   3766316.  ACFH



        STACK  GAS VOLUMETRIC  FLOM AT STANDARD CONDITIONS

        OSSTD  « 17.647 «i  d$ * PS  5 (1.  - (BHO/KTOj)  /  (TS *  460.)

                  17.647  *    3766316.  *  29.30  *  (1.  • (12.91/100))
        OSSTD  « .-...—.-..-..—..-...—. — — .-.-—.—	...... =     1698640.  SCFH
                           (  538. * 460.)



        PERCENT ISOKINETIC
>
 I       ISO a  (305.SB«(TS*460.))«((0.002669»VLC)*(V**Y*(PB*(PM/13.6))/(TM*«I60.)))/(TT«VS*PS«DN«DN)
N>
W              (30S.58«(  538.«460.))*((0.ti02669i~~186.)+(   58.511*1.044«C  29.39»(    .786/13.6))/(   78.«460.)))
        ISO »  —	•	—	———	.............	.	.	.	...	.	* 104.71 PERCENT
                                           120.  *      20.18  •   29.30  •   .397  *   .397



        PARftCULATE  LOADtNfi ••'EPA METHOD  5 (AT  STANDARD  CONDITIONS)

        CS  » 0.001 * MN  *  15.43 / VMSTD

        CS  * 0.001 *      .0  *  15.43 /     58.981 c     .000  GR/OSCF



        PARTICULATE  LBS/HR •• EPA METHOD 5

        PMR  *  CS  • OSSTD  / (15.43 •  453.6)

        PMR  s      .000 *    1698840.  /  (15.43 •  153.6)  «       .00

-------
3
Run No.  1.2
     Sample  volume = 1.67  m r 58.98  scf
Example calculations
     CS (Part)  =192.8 / 1.67= 115.4 m/m-
     CS (Part)  = 0.001 x 192.8X  15.43/58.98 =  0.050 qr/dscf
     CS (S02)   =1850  / 1.67=n07.8mq/m3
               =1107.8X  24.06/64  = 416DDm
               = 0.001 x1850  x  15.43/58.98  = 0.484 gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Sulfur dioxide
Sul f uric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg

192.8
55.2





7.4
10.1
1850

9.4



, Concentration,
mg/m

115.4
33.0





4.4
6.1
1107.8

5.6



gr/dscf

0.050
0.014





0.002
0.003
0.484

0.002



ppm









416

1



  A-24

-------
                                                               FIELD  DATA
 I
NJ
tn
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION COKE OVEN OUTLET
SAMPLE TTPE I-3-M8-350
OPERATOR CLARKE
AMBIENT TEMP.(OEG.F) 72.
BAR. PRESS. (IN. HG) 29.39
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530092
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .61
THERM. NO.
LEAKAGE .000 CFM 8 3.5 IN.HG
METER CALI8. FACTOR .992
READ » RECORD DATA EVERT 10.0
TRAVERSE
POINT
NO.

INIT












OTALS
SAMPLE
TIME
(MIN.)

0
10.0
20.0
30.0
ao.o
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
120.0
CLOCK
TIME
(20-HR
r i nrv 1
ULUIR J
910 ~
920
930
940
950
1000
1010
1020
1030
1040
1050
1100
1110

GAS METER
READING
(CU.FT.)

410.667
416.000
421.475
425.775
430.695
435.595
440.777
445.910
450.024
455.667
460.660
466.500
471.932
61.065
MINUTES
VELOCITY
HEAD
(IN.H20)

	
.060
.060
.060
.070
.070
'.060
.060
.060
.060
.060
.070
.090


ORIFICE

PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.78
.78
.78
.87
.87
.78
.78
.78
.78
.78
.87
i.io

H2U)
ACTUAL

.76
.78
.78
.87
.87
.76
.78
.78
.78
.78
.87
1.10


STACK
TEfP
(DEG.F)


519.
536.
545.
545.
555.
550.
520.
535.
510.
544.
558.
516.

DATE 10/27/81
HUN NUMBER 1-3
PKOBE LENGTH « TYPE 5FT GLASS HEAltO
NUZZLE 3 > l.D. .394
ASSUMED MU1S1UHE 12.0
SAMPLE BUX NUMBER
PETER BOX NUMBER FBI
*ETEH MEAD D1FF. 1.87
C FACTOH .88
PROBE HEATER SETTING 35U.
HEATER BOX SETTING 350.
REFEHENCE PRESS. DIFF. .15

OHY GAS METER
TEMP
(DEG.F)
ULET OUTLET

68. 63.
70. 63.
73. 64.
76. 61.
78. 66.
80. 66.
80. 66.
80. 67.
80. 68.
80. 66.
80. 68.
78. 60.


PUMP
VACUUM
(IN.HG)


2.0
2.0
2.0
2.0
2.0
2.0
2.V
2.0
2.0
2.0
3.0
3.5


SAMPLE
BOX TEMP
(DEG.F)


306.
337.
3«6.
3«7.
344.
341.
337.
345.
3«5.
336.
337.
335.


IMPINGEH
TEMH
(DEG.F)


52.
40.
40.
40.
42.
42.
42.
44.
4b.
46.
46.
4«.

      AVERAGE
.83
.83   536.
77.
65.
2.2
338.
                 44.

-------
           PARTICIPATE FIELD DATA ft RESULTS TABULATION




PLANT- NAME AND ADDRESS               TEST TEAM LEADER




REPUBLIC STEEL CLEVELAND              CLARKE
TEST
1-3
COKE OVEN OUTLET
ENGLISH UNITS
TEST DATE
TB
TF
TT
NP
Y
ON
CP
PM
1 VM
(Ti
TM
VMSTD
VLC
VWC
BHO
FMO
PC02
P02
PCO
PN2
MD
MHS
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRV GAS SAMPLED
AT STANDARD CONDITIONS*
fdtAL H2o couecTE6 IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF MATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL.* DRY
PERCENT 02 8Y VOL.i DRY
PERCENT CO BY VOL.* DRY
PERCENT N2 BY VOL., DRY
MOLECULAR MT-OftV STACK GAS
MOLECULAR MT-STACK GAS
10/27/81
910
1110
120
12




61
71
59
m
10
15

4
10

85
29
27
.0

.99Z
.394 IN
.84
.83 IN-H20
.065 CU-FT
.1 F
.280 SCF
i3
.981 SCF
.63
.844
.20
.50
.00
.30
.09
.36
METRIC UNITS
10/27/81
910
1110
120
12

10

21
1
21
1
233

15

4
10

85
29
27
.0

.992
.0
.84
.1
.729
.7
.679
.3
.311
.63
.844
.20
.50
.00
.30
.09
.36



KM

(HM-H20
CU-M
C
SCM

SCM









-------
     PB        BAROMETRIC PRESSURE

     P8I       STATIC PRES OF STACK  GAS

     PS        STACK PRES, ABS.

     TS        AVERAGE STACK TEMP

     VS        AVG STACK GAS VELOCITY

     AS        STACK AREA

     OSSTO     STACK FLOW RATE* DRY*

     OS        ACTUAL STACK FLON RATE

     ISO       PERCENT I30KINETIC

     MN        FILTERABLE PART
                 MG. EPA 5     	

     CS        FILTERABLE PART

     PMR       FILTERABLE PART
                 EMISSION RATE

        •  68 DEC F,  29.~9ir~iN~.~Hl;.
     29.39  1N-HG

     -1.20  IN-H20

     29.30  IN-HG

    536.    F

     20.0   FPS

   7066.   SQ-IN

1665014.    SCFH

3801518.    ACFH

    109.0

       .0


       .0000 GR/DSCF*

       .000   LB/HH
   706.51  *M-HG

   -30.48  *

   740.26  MM-HG

   260.    C

     6.2   WPS

     0.817 30-M

 07106.    SCMH

107648.    »OH

   109.0

      .0


      .000 PG/DSCP

       .00  KG/HM
 I
NJ

-------
              EXAMPLE PARTICIPATE CALCULATIONS TEST NO.    1-3

                   COKE OVEN OUTLET



        VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

        VMSTD » (17.647 * VM * Y • (PB * PM / 13.6)) /  (TM * 460.)

                  17.647 *    61.065 *  .992 * ( 39.39  «•   .829  /  13.6)
        VMSTO « —————— — . — — - — — — — . — — — — -.-...-.  s      59.380  OSCF
                                 I ' 71. * 460.)



        VOLUME OF MATER VAPOR AT STANDARD CONDITIONS

        VMC » .04707 * VLC

        VWC « .04707 *  235. « ~Td.98 SCF



        PERCENT MOISTURE IN STACK GAS

        BWO « (100. * VNC) / (VMSTD # VHC)

                  100. *  10.90
^       BNO * — ------- — --- — — — - = 15.63 PERCENT
I                   59.3BO *  10.98
NJ
00                      ..........                ------  ......

        MOLE FRACTION OF DRY STACK GAS

        FMD s (100. - BNO) / 100.
                     .~i  15.6
        FMD « — - ---- — --- — — — «   .844
                       100.
        AVERAGE MOLECULAR HEIGHT OF Gftv STACK GAS

        MD a (PC02 * .44) * (POZ * .33) * (PN3 + PCO) * .38

        MD s ( 4.ZO*44/100) * (10.5*32/100) * ((85.3* .0) * 38/100 =   39.09



        MOLECULAR WEIGHT OF STACK GAS

        MMS s MD * (1. - (BNO/IOO)) * 18. * (BNO/100)

        MNS *  39.09* (i. -(15.63/100)) 4 18. * (15.63/100) *   27.36

-------
       STACK GAS VELOCITY AT STACK CONDITIONS

       OELP « SUM. OF THE SORTIVH *  US *  460.))

       V3 » 85.49 • CP • DELP /  (SQRT(MWS  * PS) • PNTS)

       VS a 85.49 *  .84 *   96.360  /  (SORT( 37.36  * 39.30)   *   13.  =    20.37 FPS




       STACK GAS VOLUMETRIC FLON AT  STACK  CONDITIONS

       OS ' VS * AS * 3600/144

       OS *   80.37 *  7466. 3600/144  a    3801518. ACFH




       STACK GAS VOLUMETRIC FLON AT  STANDARD CONDITIONS

       03STD « 17.647 • OS • PS • (17- IBNO/lOO))  / (TS » 460.)

                 17.647 *    3801518.  «  29.30 • (1. - (15.63/100))
       03STD • ————————— ——————— — — — =     166S01U. SCFH
                          ( 536. * 460.)




       PERCENT ISOKINETIC

>      ISO « (305.58*(TS+460.))»((0.002669*VLC)'»(VM*Y*(PB*(PM/13.6))/(TM*
-------
Run No. 1.3
     Sample volume  =  1.68m3f 59.28 scf
Example calculations
     CS (Part)  =  72.9/1.68 = 43.4  mq/m3
     CS (Part)  =  0.001  x_73	x  15.43/59.28  =  0.019  qr/dscf
     CS (S02)   = 1870 / 1.68 = 1113.bo/m3
               =1113.1 x 24.06/_64_ = 418 ppm
               =  0.001  x1870 x  15.43^9.28   =  0.487gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


72.9






9.8
13.4
1870

65.4



3 Concentration,
mg/m


43.4






5.8
8.0
1113.1

38.9



gr/dscf


0.019






0.002
0.003
0.487

0.017



ppm










4.18

10



                                     A-30

-------
                                                                FIELD  DATA
 I
u>
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION COKE OVEN OUTLET
SAMPLE TYPE 1-4-M8-350
OPERATOR CLARKE
AMBIENT TEMP. (DEG.F) 72.
BAR. PRESS. (IN.HG) 29.39
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530072
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM 9 5.0 IN.HG
METER CALIB. FACTOR 1.010
READ I RECORD DATA EVERY 10.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY ORIFICE PRESSURE
POINT TIME
NO. (MIN.)

INlf 0"
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
TIME"
(20-HR

- §U-
924
934
944
954
1004
ioi4 —
1024
1034
1044
1054
1104
1114"
READING
(CU.FT.)

838.960
843.665
848.801
853.800
858.673
863.750
868.473
873.392
878.250
883.476
888.380
893.725
898.155
HEAD
(IN.H20)

	
.060
.060
.070
.070
.070
.060
.060
.060
.070
.060
.070
.060
DIFFERENTIAL
(IN.
DESIRED

.78
.78
.87
.87
.87
.r*
.78
.78
.87
.78
.87
.78
H20)
ACTUAL

.78
.78
.87
.87
.87
.78
.78
.78
.87
.78
.87
.T8
STACK
TEMP
(DEG.F)


527.
541.
532.
509.
561.
516.
523.
538.
533.
550.
562.
521.
DATE 10/27/81
KUN NUMBER i-o
PROBE LENGTH » TYPt 6FT GLASS HEATED
NOZZLE 0 < 1.0. .397
ASSUMED MOISTURE 12.0
SAMPLE BOX NUMBEH
METEN BOX NUMBtR FB5
METEN HEAD DIFF. 1.86
C FACTOR .88
PROBE HEATER SETTING 350.
HEATER BOX SETTING 35u.
REFERENCE PRESS. DIFF. .15
OHY GAS METER PUMP SAMPLE IMPINGEH
TEMP VACUUM
(DEG
INLET

71.
71.
70.
76.
80.
81.
82.
82.
82.
83.
82.
80.
.F) (IN.HG)
OUTLET

72. 1.0
71.
72.
72.
72.
73.
70.
75.
7b.
77.
76.
75.
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
BOX TEMP
(OEG.F)


277.
338.
339.
342.
348.
344.
342.
345.
339.
339.
332.
341.
TEMP
(DEG.F)


52.
52.
50.
50.
56.
50.
50.
56.
56.
5B.
58.
60.
       TOTALS
       AVERAGE
120.0
59.195
                                         .82
                               .82
538.
79.
74.
1.0
336.
55,

-------
           PARTICIPATE FIELD DATA & RESULTS TABULATION

PLANT» NAME AND ADDRESS               TEST TEAM LEADER

REPUBLIC STEEL CLEVELAND              CLARKE
TEST
        1-4
COKE OVEN OUTLET


TEST DATE
TB
TF
TT
NP
Y
ON
CP
PM
> VM
OJ
TM
VMSTD
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
ENGLISH UNITS
10/27/81
914
1114
120.0
12
1.010
.397 IN
•««
.82 IN-H20
59.195 CU-FT
76.2 F
37.947 SCF
METRIC UNITS
10/27/81
914
Ilia
120.0
12
1.010
10.1
.84
20.8
1.676
24.6
1.641



VM

VM-H20
CU-M
C
SCM
          AT STANDARD CONDITIONS*

VLC       TOTAL H20 COLLECTED IN
          IMPINGERS AND SILICA GEL,ML.

VMC       VOLUME OF HATER VAPOR
          AT STANDARD CONDITIONS*

BNO       PERCENT MOISTURE BY VOLUME

FMD       MOLE FRACTION DRY GAS

PC02      PERCENT C02 BY VOL., DRY

P02       PERCENT 02 BY " VffLVi DRY

PCO       PERCENT CO BY VOL., DRV

PN2       PERCENT N2 BY VOL., DRV

MD        MOLECULAR XT-DRY STACK GAS

MMS       MOLECULAR HT-STACK GAS
                          165.0
                            7.767 SCF
165.0
   .22U SCP
11.82
.882
4.20
10.50
.00
as. 30
29.09
27.78
11.82
.882
4.20
10.50
.00
85.30
29.09
27.78

-------
PB
PSI
PS
T8
VS
AS
OSSTD
OS
ISO
MN
CS
PMR
BAROMETRIC PRESSURE
STATIC PRES OF STACK GAS
STACK PRES, ABS.
AVERAGE STACK TEMP
AVG STACK GAS VELOCITY
STACK AREA
STACK FLOM RATE, DRY*
ACTUAL STACK FLOW RATE
PERCENT ISOKIMETIC
FILTERABLE PART
MG. EPA 5
FILTERABLE PART
FILTERABLE PART
29
.....
29
538
"26
7466
1716865
3756751
101



.39
.20
.30
•
.1
IN-HG
IN-H20
IN-HG
f
FPS
SO-IN
•
•
.8
.0
.0000
.000
SCFH
ACFH


GR/OSCF*
L8/HR
746
-30
744
281
6
4
48616
106381
101



.51
.48
.26
•
.1
.817
•
•
.8
.0
.000
.00
MM-HG
*M-H20
PM-HG
C
SQ-M
SCUM
• C*H


^G/USC*
KG/HH
                 EMISSION RATE

        •  68 DIG Fr  29.92  IN.H6.
U)
OJ

-------
               EXAMPLE PARTICIPATE CALCULATIONS TEST NO.   1-1


                    COKE OVEN OUTLET




         VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS


         VMSTD * (17.647 * VM * Y • (P8 * PM / 13. fc)) / ITM * 460.)


                   17.647 •    59.195 * 1.010 * ( 39.39 *  .818 / 13.6)
         VMSTO « ————— ———— — ............. ---- ........ -      57.«»                    57.947 *   7.77
 I
U)              •    -    ------      - .........         — -
*>

         MOLE FRACTION OF DRY STACK GAS


         FHD * (100.  - BMO) / 100.


                   loo. •  ii.e
                             —— •   .882
                        100.
         AVERAGE  MOLECULAR NEt§Hf OF DRY STACK GAS

         MD s (PCOa * .44) «• (P02 * .32) * (PN2 » PCO) * .28

         MD z (  4.20*44/100) * (10. 5*32/100)  » ((65.3* .0) * 28/100 =   29.09




         MOLECULAR WEIGHT OF STACK GAS

         MMS • MD * (1.  • (BMO/100)) » 18. *  (BMO/100)

         MWS s  29.09* (i. -(11.82/100)) » 18. * (11.82/100) *   27.78

-------
          STACK  GAS VELOCITY  AT  STACK  CONDITIONS

          DELP * SUM.  OF  THE  SORTIVH • (TS  *  460.))

          VS  = 8S.49 * CP * OELP /  (30RT(MKS  •  PS)  *  PNTS)

          VS  = 85.49 *  .84 *    95.959 /  CSOHTC 37.78 •  29.30)   *   12.  =    £0.13  FPS



          STACK  GAS VOLUMETRIC FLON AT STACK  CONDITIONS

          OS  * VS * AS *  3600/144

          OS  *    20.13 *   t466.  3600/144  •    3756791. ACFH



          STACK  GAS VOLUMETRIC FLON AT STANDARD CONDITIONS

          QSSTD  « 17.64?  * 0$ •  ?3  • (1.  -  (BMO/100))  /  (TS  +  460.)

                    17.647 •     3756791.  *  29.30 *  (1.  -  (11.62/100))
          OSSTD  » —..————............. —...........	...	. -     1716665. SCFH
                             ( 538. »  460.)



          PERCENT ISOKINETIC

>         ISO *  (305.58*(TS*460.))*((0.002669*VLC)*(VM*Y*(PB»(PM/13.6))/(TM*460.)))/(TT*V9*P8*DN*DN)
 I
J£                (305.58*( 538.*460.))*((0.0026698"  165.)»(    54.195*1.010*( 29.39+(    .818/13.6))/(  76.«460.)))
          ISO •  ——————————--—•——— — --- — ------——---------—- — --- — — -------- — - — s  101.80  PERCENT
                                             120. *      20.13  •   29.30 *   .397 •  .397



          PARTICULAR  LOADING -- EPA METHOD 5 (AT STANDARD CONDITIONS)

          CS e 0.001 •  MN  • 15.43 / VMSTO

          CS * 0.001 *      .0 *  15.43 /    57.947 •     .000  GR/DSCF



          PARTICULATE  LBS/HR ••  EPA METHOD 5

          PMR *  CS  * OSSTD / (15.43 •  053.6)

          PMR «      .000  •   1716865.  /  (15.43 * 453.6) «       .00

-------
Run No.1.4
     Sample volume =1.64 nT%  57.95 scf
Example calculations
     CS (Part)  = 50.6/1.64 = 30.8  mq/m3
     CS (Part)  = 0.001  x50.7  x  15.43/57.95 = 0.013  qr/dscf
     CS (S02)   = 1810/1.64 =1103.7ma/m3
               =1103.7X 24.06/64  =415 ppm
               = 0.001  x 1810  x  15.43/57.95  = 0.482 gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Sulfur dioxide
Sul f uric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg

50.6





4.7
6.4
1810

56.0



2 Concentration,
mg/m

30.8





2.9
3.9
1103.7

34.1



gr/dscf

0.013





0.001
0.002
0.482

0.015



ppm








415

8



                                      A-36

-------
                                                        FIELD  DATA
PLANT REPUBLIC STEEL
SAMPLING LOCATION COKE OVEN STACK
SAMPLE TYPE METHOD 5-250
OPERATOR 00
AMBIENT TEMP. (DEC. F) 62.
BAR. PRESS. (IN.HG) 29.39
STATIC PRESS. (IN. H20) .00
FILTER NUMBER(S) 3530066
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .64
THERM. NO.
LEAKAGE


METER CALIB. FACTOR
READ • RECORD DATA
TRAVERSE SAMPLE
POINT TIME
NO. (MIN.)

INIT 0 ~
10.0
20.0
30.0
40.0
50.0
60.0
70.0
70.4
CLOCK
TIME
(24-HR
PI t\f tf i
CLUCK)
947
957
1007
1017
1027
1037
1047
1057
1057

.000
1.033
EVERT 10.0
GAS METER
READING
(CU.FT.)

593.361
600.570
607.750
614.950
622.140
629.310
636.500
643.640
644.151

CFM 8 6.

MINUTES
VELOCITY
HEAD
(IN.H20)


.050
.050
.050
.050
.050
.050
.050
.050
CLEVELAND

0 IN.HG


ORIFICE




PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.81
.81
.81
.81
.81
.81
.81
1.81
H20)
ACTUAL

.81
.81
.81
.81
.81
.81
.81
.81




STACK
TEMP
(OEG.F)


550.
550.
550.
550.
550.
550.
550.
550.
DATE 10/27/81
HUN NUMBER 1-5
PROBE LENGTH A TYPE 6* GLASS
NOZZLE 6-103S I.D. .520
ASSUMED MOISTUHE 11.0
SAMPLE BOX NUMBER
KETEH BOX NUMBER FB4
METEH HEAD OIFF. 1.68
C FACTOR .92
PRUBE HEATER SETTING 250.
HEATER eux
REFERENCE


DRY GAS METER
TEMP
(DEG.F)
INLtT OUTLET
-•
77. 77.
74. 75.
76. 74.
78. 73.
80. 74.
80. 74.
80. 74.
80. 74.
SETTING
250.

PRESS. DIFF. .05


PUMP
VACUUM
(IN.HG)


4.7
5.1
5.2
5.3
5.3
5.3
5.5
5.5


SAMPLE
BOX TEMP
(DEG.F)


230.
288.
29U.
291.
262.
240.
253.
253.


IMPINGEH
TEMP
(DEG.F)


38.
40.
«0.
50.
50.
54.
52.
52.
TOTALS
AVERAGE
70.4
50.790
                                       1.61
                              1.81
550.
78.
74,
5.2
263,
47,

-------
           PARTICIPATE FIELD DATA ft RESULTS TABULATION
PLANT- NAME AND ADDRESS               TEST TEAM LEADER
REPUBLIC STEEL CLEVELAND              DO
TEST
1-5
                COKE OVEN STACK
TEST DATE







>
1
U)
00

TB
TF
TT
NP
V
ON
CP
PM
VM
TM
VMSTD
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
ENGLISH UNITS
10/27/61
947
1057
70
8
1


1
SO
76
50
.4

.033
.520 IN
.84
.81 IN-H20
.790 CU-FT
.3 F
.973 SCF
METRIC UNITS
10/27/81
947
1057
70.
8
1.
13.
•
4b.
1.
24.
1.
4

033
2
84
0
438
6
443



KM

MM-H20
CU-M
C
SCM
          AT STANDARD CONDITIONS*
VLC       TOTAL H20 COLLECTED IN
          IMPINGERS AND SILICA GELrML,
VNC       VOLUME OF MATER VAPOR
          AT STANDARD CONDITIONS*
BMO       PERCENT MOISTURE BV VOCUME
FMD       MOLE FRACTION DRY GAS
PC02      PERCENT C02 BV VOL.r DRV
P02       PERCENT 02 BY"VOL., DRY
PCO       PERCENT CO BV VOL., DRY
PN2       PERCENT N2 BY VOL., DRY
MD        MOLECULAR MT-ORY STACK GAS
MHS       MOLECULAR MT-STACK GAS
                                          169.5
                                            7.978 SCF
                                                       169.5
                                                          .226 Sen
13.53
.865
4.20
10.50
.00
85.30
29.09
27.59
13.53
.865
4.20
10.50
.00
85.30
29.09
27.59

-------
      PB        BAROMETRIC PRESSURE

      PSI       STATIC PRES OF STACK GAS

      PS        STACK PRES, ABS.

      TS        AVERAGE STACK TEMP

      VS        AVG STACK GAS VELOCITY

      AS        STACK AREA

      OSSTD   .  STACK FLOW RATE* DRY*

      OS        ACTUAL STACK FLO* RATE

      ISO       PERCENT ISOKINETIC

      MN        FILTERABLE PART
                  MG. EPA 3  	

      CS        FILTERABLE PART

      PMR       FILTERABLE PART
                  EMISSION RATE

         •  68~DCG F, ~Z~
     29.39  IN-HG

       .00  IN-H20

     Z9.39  IN-HG

    550.    F

     17.9   FPS

   7066.   SO-IN

1485328.    3CFH

3345007.    ACFH

    102.8

       .0


       .0000 GR/DSCF*

       .000   LB/HR
  746.51  *M-HG

     .00  PM-H20

  746.51  PM-HG

  288.    C

    5.5   KPS

    4.817 SO-M

12057.    SON

94721.    *CKH

  102.8

     .0
     .000

      .00  KG/MR
 I
OJ
VD

-------
      EXAMPLE PARTICIPATE CALCULATIONS TEST NO.    1-5

           COKE OVEN STACK



VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

VMSTO « (17.647 • VM * Y * (PB » PM / 13.6)) /  (TM * 460.)

          17.647 •    50.790 * 1.033 * ( 39.39  * 1.810 /  13.6)
VMSTD * —————	—	•	—	•	a      50.973  DSCF
                         (  76. * 460.)




VOLUME OF MATER VAPOR AT STANDARD CONDITIONS

VNC « .04707 * VLC

VNC « .04707 *  170. « "~7.98 SCF



PERCENT MOISTURE IN STACK GAS

BHO » (100. * VMCJ / (VMStD * VHCT

          100. *   7.98
BHO « —————	......... s 13.53 PERCENT
            50.973 *   7.98



MOLE FRACTION OF DRY STACK GAS

FMD * (100. - BNO) / 100.

          loo. -  rs.s
FMD * —————......... •   .865
               100.




AVERAGE MOLECULAR HEIGHT OF DRY STACK CAS

MD « (PC02 * .44) * (POZ * .33) * (PNZ • PCO) • .28

MD * ( 4.20*44/100) * (10.5*32/100) » ((85.3* .0)  * 28/100 =   29.09




MOLECULAR HEIGHT OF STACK GAS

MNS a MD * (1. - (BNO/100)) » 18. • (BNO/100)

MH3 *  29.09* (1. •(13.53/100)) * 18. * (13.53/100) «   27.59

-------
STACK G»3 VELOCITY AT STACK CONDITIONS

DELP « SUM. OF THE 30RTIVH *  ITS » 460.))

VS * BS.49 • CP * OELP / (SQRT(MHS • PS) * PNTS)

VS 3 65.49 *  .84 •   56.651  /  (SQRM 27.59 * 29.39)  *   8. =    17.92 FPS




STACK GAS VOLUMETRIC FLOH AT  STACK CONDITIONS

QS * VS • AS * 3600/144

OS 3   17.92 *  7466. 3600/144  x    3345001. ACFH




STACK CAS VOLUMETRIC FLON AT  STANDARD CONDITIONS

OSSTO » 17.647 • 03 •P8"^(T7i (BNO/100)) / (TS * 460.)

          17.647 •    3345007.  •  29.39 • (1. - (13.53/100))
03STD » ———————————————— — — — a     1485226. SCFH
                   ( 550. * 460.)




PERCENT ISOKINETIC

ISO « (30S.5B«(TS*460.))*((0.002669«VLC)«(VM<»Y*(PBMPM/13.6))/(TM+460.)))/(TT«VS*P3*DN*Df»)

       (305.58M: 5$6.*460.))M(0.602669«  170.)*(   50.790*1.033*( 29.39«(   1.810/13.6))/(   7b.*060.)))
ISO * ——————................................................_.._....._......_.................. i  102.84  PkHCEMT
                                    70. *     17.92 *   29.39 •   .520 *  .520




PARTICIPATE LOADING -• EPA METHOD 5 (AT ^TANDARO CONOltlONS)

CS e 0.001 * MN • 15.43 / VMSTD

CS * 0.001 •      .0 • 15.43 /    50.973 =     .000 GR/DSCF




PARTICULATE LBS/HR — EPA METHOD 5

PMR * CS * OSSTD / (15.43 * 453.6)

PMR •     .000 *   ~I485228. /  (15.43 • 453.6) »      .00

-------
Run No.  1.5
     Sample  volume = 1.44 tn3t 50.97 scf
Example  calculations
     CS  (Part)  =135.3/1.44 =  94.0 mq/m3
     CS  (Part)  =  0.001  x135.3x 15.43/50.97=   0.041 qr/dscf
     CS  (S02)   =	/	=	mg/m3
               =	 x 24.06/	=	ppm
               =  0.001  x	x 15.43/	. =	gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Sulfur dioxide
Sul f uric acid mist
As H2S04
As H2S04-2H20
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


135.3
47.5
41.7
37.3
34.5
30.5

0.0
0.0




28.2
2.6
23.4
3 Concentration,
mg/m


94.0
33.0
29.0
25.9
24.0
21.2

0.0
0.0




19.6
1.8
16.2
gr/dscf


0.041
0.014
0.013
0.011
0.010
0.009

0.0
0.0




0.008
0.001
0.007
ppm


















                                        A-42

-------
                                                               FIELD  OAT*
 I
£>.
U)
PLANT REPUBLIC STEEL
SAMPLING LOCATION COKE UVEN STACK
SAMPLE TYPE METHOD 8-600
OPERATOR DO
AMBIENT TEMP. (DEC. F) 62.
BAR. PRESS. (IN.HG) 29.39
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530210
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM 8 21.
METER CALIB. FACTOR .982
READ ft RECORD DATA EVERY 10.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY
POINT
NO.

INIT







TIME
(MIN.)

6
10.0
20.0
30.0
40.0
50.0
60.0
64.5
TIME
(24-HR
f i nf M \
LLUCKJ
958"
1008
1018
1028
1038
1048
1058
1102
READING
(CU.FT.)

88.938
98.960
107.100
115.080
122.680
130.090
137.250
140.342
HEAD
(IN.H20)

._. .._ ..
.050
.050
.050
.050
.050
.050
.050
CLEVELAND
0 IN.HG
ORIFICE PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.66
.66
.66
.66
.66
.66
.66
H20)
ACTUAL
-
3.66
2.20
2.20
2.00
1.87
1.80
1.60
STACK
TEMP
(OEG.F)


550.
550.
550.
550.
550.
550.
550.
DATE 10/27/81
NUN NUMBER t-6
PROBE LENGTH S TYPE 4* QUARTZ
NUZZLE t I.U. .620
ASSUMED MOISTURE 11.0
SAMPLE BOX NUMBER
METER BOX NUMBER FB8
METER HEAD DIM . 1.91
c FACTOR .94
PROBE HEATER SETTING 600.
HEATER BOX SETTING 600.
REFERENCE PRESS. DIFF. .02
DRY GAS METER PUMP SAMPLE IMPINGER
TEMP
(DEG
IM.E!

64.
68.
70.
71.
71.
71.
70.'
.F)
OUTLET

63.
63.
63.
64.
65.
65.
65.
VACUUM
(IN.HG)


9.6
13.9
17.7
19.4
19.7
19.8
20.2
BOX TEMP
(DEG.F)


624.
653.
612.
667.
639.
528.
535.
TEMP
(DEG.F)


38.
40.
40.
50.
50.
54.
52.
      TOTALS
      AVERAGE
64.5
51.404
                                        3.66
                              2.19   550.
69.
64.
17.2   608.
46.

-------
           PARTICIPATE FIELD DATA ft RESULTS TABULATION
PLANT- NAME AND ADDRESS               TEST TEAM LEADER
REPUBLIC STEEL CLEVELAND              00
TEST
1-6
                COKE OVEN STACK


TEST DATE
TB
TF
TT
NP
Y
ON
CP
PM .
> VM
"^ TM
VMSTD
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRV GAS SAMPLED
ENGLISH UNITS
10/27/81
958
1102
64.5
7
.982
.620 IN
_.••«
2.19 IN-H20
51.404 CU-FT
66.6 F
49.985 SCF
METRIC UNITS
10/27/81
958
1102
64.5
7
.982
15.7
.84
55.6
1.456
19.2
1.415



MM

KM-H20
CU-M
C
SCM
          AT STANDARD CONDITIONS*

VLC       TOTAL H20 COLLECTED IN
          IMPINGERS AND SILICA GEL,ML.

VMC       VOLUME OF MATER VAPOR
          AT STANDARD CONDITIONS*

BMO       PERCENT MOISTURE BY VOLUME

FMD       MOLE FRACTION DRY GAS

PC02      PERCENT C02 BY VOL., DRY

P02       PERCENT 02 BY VOl... DRY

PCO       PERCENT CO BY VOL., DRY

PN2       PERCENT N2 BY VOL., DRY

MD        MOLECULAR MT-DRt STACK GAS

MMS       MOLECULAR XT-STACK GAS
                                           1 779
                                             .843 SCF
                                                        17.9
                                                          .024 SCW
"1.66
.983
4.20
10.50
.00
85.30
29.04
28.91
1.66
.983
4.20
10.50
.00
85.30
29.09
28.91

-------
PB        BAROMETRIC PRESSURE

PSI       STATIC PRES OF STACK GAS

PS        STACK PRES* ABS.

TS        AVERAGE STACK TEMP

VS        AVG STACK GAS VELOCITY

AS        STACK AREA

OSSTD     STACK FLOW RATE* DRY*

OS        ACTUAL STACK FLOW RATE

ISO       PERCENT ISOKINETIC

MN        FILTERABLE PART
            MG. EPA 5

CS        FILTERABLE PART

PMR       FILTERABLE PART
            EMISSION RATE

   *  68 DEC F,  29.92 iN.HG.
     29.39  IN-HG

     -1.20  IN-H20

     29.30  IN-HG

    550.    F

     17.5   FPS

   7466.   SQ-IN

1647806.    SCFH
3272822.

     69.8

       .0
ACFH
       .0000 GR/OSCF*

       .000   LB/HR
  746.51  PP-HG

  •30.48  PK-H20

  744.26  CM-HG

  288.    C

    5.5   CPS

    4.817 SO-M

46661.    SOH

92677.    *CHH

   69.8

     .0
                .000

                 .00  KG/Hrt

-------
              EXAMPLE PARTICIPATE CALCULATIONS TEST NO.   1-6

                   COKE OVEN STACK



        VOLUME OF DRV GAS SAMPLED AT STANDARD CONDITIONS

        VMSTD • (IT.647 • VM • Y • (PB «• PM / 13.6)) / (TM * 460.)

                  17.647 *    51.404 •  .982 « ( 29.39 » 3.190 / 13.6)
        VMSTO « .———.————.—— ——— — ——	...... x      49.9A5  D3CF
                                 (  67. + 460.)



        VOLUME OF HATER VAPOR AT STANDARD CONDITIONS

        VHC * .04707 • VLC

        VHC a .04707 *   18. a.B4~SCF



        PERCENT MOISTURE IN STACK GAS

        BHO « (100. • VMC) / (VMStb * VHC)

                  100. *    .84
>       BMO a ———————	a  1.66 PERCENT
 I                   49.985 *    .84
»^

-------
       STACK GAS VELOCITY AT STACK CONDITIONS

       DELP « SUM. OF THE SORTIVH • (TS » 460.))

       VS s 85.49 • CP • DELP / (3QRT(MH3 • PS) • PNTS)

       VS * BS.49 •  .84 *   49.744 / (SORT( 28.91 * 29.30)  *   7. a   17.53 FPS



       STACK GAS VOLUMETRIC FLO* AT STACK CONDITIONS

       OS B VS * AS • 3600/144

       OS *   17.53 «  7466. $600/144 •    3272622. ACFH



       STACK GAS VOLUMETRIC FLON AT STANDARD CONDITIONS

       OSSTD » 17.647 • OS • "PS~« U. • (BNO/100)) / (TS * 460.)

                 17.647 •    3272822. *  29.30 •(!.-( 1.66/100))
       OSSTD « ———— ——————	..... :    1*47606. SCFH
                          ( 550. * 460.)



       PERCENT ISOKINETIC
>
 1      ISO • (305.58*(TS+460.))*U0.002669*VLC)+(VM*Y*(PB*(PM/13.6))/(TM«460.)))/(TT*VS*PS*DN*DN)
£*

~J       *     (30S.5fl«( 550.»«60.))««0.00266*«"  !«.)»(   5I.404« ,982*( 29.39*(   2.190/13.6))/(  67.^460.)))
       130 « .-——————————.. — — .-..—-- — — -....-...--. — .---.—.. — ...... — . s  69.78 PERCENT
                                           65. *     17.53 *   29.30 •  .620 *  .620



       PARTICIPATE LOADING -^EPA METHOD 5 (AT-STANDARD CONDITIONS)

       C3 • O.OOt * MN • 15.43 / VMSTD

       CS * 0.001 •      .0 *  15.43 /    49.985 =     .000 GR/OSCF



       PARTICIPATE LBS/HR — EPA METHOD 5

       PMR « C3 * OSSTD / (15.43 * 453.6)

       PMR «     .000 *    16«r806. / (15.43 • 453.6) «      .00

-------
Run No.  1.6



     Sample  volume = 1.42 m.49.99  scf



Example  calculations



     CS  (Part)  =  27.0/ 1.42= 19.0  mq/m3



     CS  (Part)  =  0.001 x27.0 x 15.43/49.99 «  0.008  qr/dscf



     CS  (S02)   =  1120/1.42=788.7nig/m3



               =  788.7x  24.06/54  = 296 DPm



               =  0.001 x1120 x 15.43/12^2-. = 0.346  gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sulfates
As H2S04
As H2S04-2H20
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


27.0






0.0
0.0
1120

606



3 Concentration,
mg/m


19.0






0.0
0.0
788.7

426.8



gr/dscf


0.008






0.0
0.0
0.346 ,

0.187



Ppm











296

105



Hydrogen peroxide contaminated.
                                     A-48

-------
                                                        FIELD  DATA
        PLANT
        SAMPLING LOCATION

        SAMPLE TTPE
        OPERATOR
        AMBIENT TEMP.(DEC.F)
        BAR.PRESS.(IN.HG)
        STATIC PRESS. UN.H20)
        FILTER NUMBER(S)
        STACK INSIDE DIM.(IN)
        PITOT TUBE COEFF.
        THERM. NO.
                     REPUBLIC STEEL CLEVELAND
                     NO.l COKE BATTERY STACK

                     PART/H2304/S02
                     BRUFFEY
                      64.
                     29.30
                     -1.20
                     3530080
                       97.50    .00
                       .64
                                               DATE
                                               RUN NUMBER

                                               PROBE LENGTH » TYPE
                                               NUZZLE  2-1 t I.D.
                                               ASSUMED MOISTURE
                                               SAMPLE BOX NUMBER
                                               METER BOX NUMBER
                                               METER MEAD OIFF.
                                               c FACTOR
                                               PROBE HEATER SETTING
                                               HEATER BOX SETTING
                          10/27/01
                             2-1

                          5* HEATED GLASS
                           .397
                          12.0

                          FB2
                          1.76
                           .66
                          250.
                          250.
LEAKAGE
METER CALIB. FACTOR
.001
1.003
READ » RECORD DATA EVERY 10.0
TRAVERSE
POINT
NO.

INIT












SAMPLE
TIME
(MIN.)


0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
SO.O
90.0
100.0
110.0
120.0
CLOCK
TIME
(24-HR
ft nnt i
vUULK J

i|55
1405
1415
1425
1435
1445
1455 "
1505
1515
1525
1535
1545
~ 15S5
GAS METER
READING
(CU.FT.)

720.259
725.000
729.740
734.500
739.240
744.010
740.790
753.600
756.360
763.120
767.690
772.690
777.466
CFM a 5.
MINUTES
VELOCITY
HEAD
(IN.H20)

	 — -
.050
.050
.050
.050
.050
.050
.050
.050
.050
.050
.050
.050
0 IN.HG

ORIFICE
REFERENCE PRESS. DIFF. .15

PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.62
.62
.62
.62
.62
.62
.62
.62
.62
.62
.62
.62
H20)
ACTUAL

.62
.62
.62
.62
.62
.62
.62
.62
.62
.62
.62
.62

STACK
TEMP
(DEG.F)


525.
519.
530.
537.
535.
553.
565.
511.
522.
534.
534.
553.

DRY GAS PETER
TEMP
(OEG.F)
INLET OUTLET

67. 68.
66. 68.
70. 68.
73. 66.
74. 69.
75. 69.
75. 69.
75. 69.
75. 69.
75. 70.
75. 70.
73. 68.

PUMP
VACUUM
(IN.HG)


1.5
2.0
2.0
2.0
2.0
2.5
.0
.0
.0
.0
.0
.0

SAMPLE
BOX TEMP
(OEG.F)


250.
251.
2«9.
245.
250.
253.
249.
249.
242.
242.
237.
242.

IMPINGEH
TEMP
(OEG.F)


55.
54.
53.
53.
53.
52.
50.
51.
50.
51.
52.
50.
TOTALS
AVERAGE
120.0
57.227
                                         .62
                               .62   535.
73.
69,
2.5   247.
52.

-------
           PARTICIPATE FIELD DATA & RESULTS TABULATION

PLANT- NAME AND ADDRESS               TEST TEAM LEADER

REPUBLIC STEEL CLEVELAND              BRUFFEY
TEST
2-1
NO.l COKE BATTERY STACK

ENGLISH UNITS
TEST DATE 10/27/81
TB
TF
TT
NP
Y
ON
cp
PM
1 VM
cn
0
TM
VMSTD
TIME-START 1335
TIME-FINISH 1555
NET TIME OF TEST* MIN. 120.0
NET SAMPLING POINTS 12
METER CALIBRATION FACTOR 1.003
SAMPLING NOZZLE DIAMETER .397 IN
PITOT TUBE COEFFICIENT •««
AVERAGE ORIFICE PRESSURE .62 IN-H20
DROP
VOLUME OF DRV GAS SAMPLED 57.227 CU-FT
AT METER CONDITIONS
AVERAGE GAS METER TEMP 70.8 F
VOLUME OF DRY GAS SAMPLED 55.996 SCF
METRIC UNITS
10/27/81
1355
1555
120.0
12
1.003
10.1
.84
15.7
1.620
21.6
1.586



CM

CM-H2U
CU-M
C
SCf
          AT STANDARD CONDITIONS*

VLC    '"'TOtA'L HZ« COLLECTED IN
          IMPIN6ERS AND SILICA GEL,ML,

VMC       VOLUME OF HATER VAPOR
          AT STANDARD CONDITIONS*

BN6       PERCENT MOISTURE BY VOLUME

FMD       MOLE FRACTION DRY GAS

PC02      PERCENT C02 BY VOL.* DRY

P02       PERCENT 62 SY~ VOL.." fcRY

PCO       PERCENT CO BY VOL.* DRY

PN2       PERCENT N2 BY VOL., DRY

MD        MOLECULAR NT-DRY STACK GAS

MH3       MOLECULAR NT-STACK GAS
                                  TB9.I
                                    8.901 SCF
                                               189.1
                                                  .252 SCM
"13.72
.863
a. 20
"10.50
.00
85.30
29.09
27.57
13.72
.863
4.20
10.50
.00
85.30
29.09
27.57

-------
     PB        BAROMETRIC PRESSURE

     PSI        STATIC PRES OF STACK GAS

     PS        STACK  PRES, ABS.

     TS        AVERAGE STACK TEMP

     VS        AVG STACK GAS VELOCITY

     AS        STACK  AREA

     OSSTO     STACK  FLOW RATE, DRY*

     OS        ACTUAL STACK FLON RATE

     ISO        PERCENT ISOKINETIC

     MN        FILTERABLE PART
                 MG.  EPA 5     _ _

     CS        FILTERABLE PART

     PMR        FILTERABLE PART
                 EMISSION RATE

       *   68  OE6 F,   29.92 IN.HG.
     29.90  IN-HG

     •1.20  IN-H20

     29.21  IN-HG

    535.    F

     17.8   FPS

   7466.   SO-IN

1489327.    SCFH
3331033.

    113.4

       .0
ACFH
       .0000 GR/D3CF*

       .000   LB/HR
  740.22  CH-HG

  -30.40  PM-H20

  741.98  KH-MG

  279.    C

    5.4   HPS

    4.817 SO-M

42173.    SOH

94325.    ACI-H

  113.4

     .0


     .000 KG/OSC"

      .00  KG/HH
 I
Ul

-------
             EXAMPLE PARTICULATE CALCULATIONS TEST NO.   2-1

                  NO.l COKE BATTERY STACK



       VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

       VMSTO • (17.647 * VM * Y * (PB » PM / 13.6)) / (TM » 460.)

                 17.647 •    57.227 * 1.003 * ( 29.30 *  .620 / 13.6)
       VMSTD a	..———.	.	...	3     55.996 OSCF
                                (  71. * 460.)




       VOLUME OF NATER VAPOR AT STANDARD CONDITIONS

       VHC a .04707 * VLC

       VHC * .04707 *  189. a   8.90 SCF




       PERCENT MOISTURE IN STACK GAS

       BMO a" (iOO. * VHC) / (VMSTO * VHC)

                 100. *   B.90
IP      BMO * —	—	——	 = 13.72 PERCENT
I                   55.996 «•   8.90



       MOLE FRACTION OF DRV STACK GAS

       FMO * (100. - BHO) / 100.

                 100. -  13.7
       FMD a —	——	........ i   .863
                      100.



       AVERAGE MOLECULAR HEIGHT OF DRY STACK GC1

       MD  a (PC02 • .44) * (P02 * .32) * (PN2 * PCO) * .28

       MD  a ( 4.20*44/100) * (10.5*32/100)  * ((85.3* .0) * 28/100 =   29.09




       MOLECULAR HEIGHT OF STACK GAS

       MMS a MD • (1. • (BHO/100)) * 18. *  (BHO/100)

       MHS =  39.09* (1. -(13.72/100)) * 18. *  (13.72/100) s   27.57

-------
       STACK SAS VELOCITY AT STACK CONDITIONS


       DELP « SUM. OF THE SQRT(VM * (TS » 460.))


       VS • 65.49 * CP • DELP / (SORT(MMS • PS) • PNTS)


       VS o 85.49 *  .84 •   84.631 / tSORTC 37.57 • 29.31)  •  12. x   17.85 FP3




       STACK 6AS VOLUMETRIC FLOM AT STACK CONDITIONS


       OS s VS • AS * 3600/144


       OS *   17.85 *  7466. 3600/144 •    3331033. ACFH




       STACK GAS VOLUMETRIC FLOM AT STANDARD CONDITIONS


       QSSTD • 17.647 •OS • PS •"UT- (BHO/100)) / (TS » 460.)


                 17.647  *    3331033. *  29.21  * (1. • (13.72/100))
       OSSTD « ---------———- ——.——--——--— — - — -	. z    1489327. SCFH
                          ( 535. * 460.)




       PERCENT ISOKINETIC
>

(Jn      ISO * (305.5B«(TS+460.))*((0.002669*VLC)+(VM«Y«(PB+(PM/13.6))/(TM+460.)))/(TT*V3»PS*DN*DM


              (30S.S8*(  535.4460.))*((0.002669*  1B9.)*(   57.227*1.003*t  29.30«(    .620/13.6))/(  71.+460.)))
       ISO • —	———————————————	—	•	t 113.40 PkRCENT
                                          120.  •     17.85 •   29.21 *   .397  *   .397




       PARfiCULAfE LOADING --"EPA METHOD  5 (AT"STANDARD CONDITIONS)


       C3 • 0.001  * MN * IS.43 / VMSTD


       CS * 0.001  *      .0 •  15.43 /    55.996 »     .000 GR/DSCF




       PARTICULATE LBS/HR — EPA METHOD 5


       PMR « CS *  OSSTD  / (15.43 • 453.6)


       PMR •     .000 *     1489327.7 (15.43 *  «53.6)  I      .00

-------
Run No.  ?.l
     Sample volume =1.59  m3.56.QQ scf
Example calculations
     CS (Part)  =183.1/1.59 =  115.1 mq/m3
     CS (Part)  =  0.001  x!83.1  x  15.43/56.00  = 0.050  qr/dscf
     CS (S02)   =1370  /I.59 =  861.ana/m3
               =861.6 x 24.06/64 = 3?4 ppm
               =  0.001  x  1370  x  15.43/56.00  =0.377  gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Sulfur dioxide
Sul f uric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


183.1






61.6
84.2
1370

741 a



3 Concentration,
mg/m


115.2






38.7
53.0
861.6

466.0



gr/dscf


0.050






0.017
0.023
0.377

0.204



ppm










324

114



Hydrogen peroxide contaminate.
                                       A-54

-------
                                                                FIELD  DAT*
 I
Uv
Ul
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION NO.l COKE BATTERY OUTLET
SAMPLE TYPE PART/H2S04/S02
OPERATOR BRUFFEV
AMBIENT TEMP. (DEC. F) 69.
BAR. PRESS. (IN. HG) 29.30
STATIC PRESS, (IN. H20) •1.20
FILTER NUMBER(S) 35300013
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .B<»
THERM. NO.
LEAKAGE .000 CFM 9 S.O IN.HG
METER CALIB. FACTOR 1.044
READ I RECORD DATA EVERT 10.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY ORIFICE PRESSURE
POINT
NO.

INlf












TIME
(MIN.)

0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
SO.O
90.0
100.0
110.0
120.0
TIME
(24-HR
ft f\f*tt \
CLUCK J
1558
1408
1418
1428
1438
1448
1458
1508
1518
1528
1538
1548
1558
READING
(CU.FT.)

961.498
965.910
970.265
974.650
979.000
983.345
987.710
992.070
996.400
.720
5.090
9.420
13.753
HEAD
(IN.H20)

	 .
.050
.050
.050
.050
.050
".050
.050
.050
.050
.050
.050
~ .050
DIFFERENTIAL
(IN.
DESIRED

.62
.62
.62
.62
.62
.62
.62
.62
.62
.62
.62
.62
H20)
ACTUAL

.62
.62
.62
.62
.62
.62
.62
.62
.62
.62
.62
.62
STACK
TECP
(DtG.F)


573.
524.
532.
540.
543.
555.
568.
513.
S26.
536.
541.
559.
DATE 10/27/81
HUN NUMBER 2*2
PROBE LENGTH ft TYPE 4* HEATED GLASS
NOZZLE 2-2 : l.U. .397
ASSUMED MOISTURE 12.0
SAKPLE BOX NUPBEH
MtTER BOX NUHBER F10
ftTER HEAD OIFF. 1.80
C FACTOR .06
PROBE HEATER SETTING 25U.
HEATER BOX SETTING 250.
REFERENCE PRESS. DIFF. .15
DHY GAS METER PUKP SAMPLE IMPINGER
TEMP
(DEG
INLET

71.
71.
73.
76.
77.
78.
78.
77.
78.
78.
77.
74.
.F)
OUTLET

72.
71.
72.
72.
72.
73.
73.
73.
72.
73.
72.
71.
VACUUM
(IN.HG)


.0
.0
.0
.5
.0
.0
2.0
2.0
2.4
2.5
2.5
2.6
BOX TEMP
(OEG.F)


268.
262.
262.
254.
264.
265.
267.
265.
262.
263.
256.
263.
TEMP
(OEG.F)


48.
47.
49.
51.
50.
50.
50.
50.
53.
54.
56.
52.
       TOTALS
       AVERAGE
120.0
52.255
                                         .62
                               .62   543.
76.
72.
1.7   263.
51.

-------
                 PARTICIPATE FIELD DATA ft RESULTS TABULATION

      PLANT- NAME AND ADDRESS               TEST TEAM LEADER

      REPUBLIC STEEL CLEVELAND              BRUFFEY
      TEST
        2-2
NO.l COKE BATTERY OUTLET
 I
Ul
ENGLISH UNITS
TEST
TB
TF
TT
NP
Y
DN
CP
PM
DATE
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS 	
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
10/27/61
1356
1556
120
12
1



.0

.044
.397 IN
.••*
.62 IN-H20
METRIC UNITS
10/27/81
1358
1558
120
12
1
10

15
.0

.044
.1
.84
.7



CM

CM-
          DROP

VM        VOLUME OF DRY GAS SAMPLED
          AT METER CONDITIONS

TM        AVERAGE GAS METER TEMP

VMSTO     VOLUME OF DRY GAS SAMPLED
          AT STANDARD CONDITIONS*

VLC       TOTAL H20 COLLECTED IN
          IMPINGERS AND SILICA GEL,ML,

VNC       VOLUME OF MATER VAPOR
          AT STANDARD CONDITIONS*

BMO       PERCENt MOISTURE BY VOLUME

FMD       MOLE FRACTION DRY GAS

PC02      PERCENT C02 BY VOL., DRY

P02       PERCENt 02 BY VOL;, D«t

PCO       PERCENT CO BY VOL., DRY

PN2       PERCENT N2 BY VOL., DRY

MD        MOLECULAR MT-DffY STACK GAS

MMS       MOLECULAR MT-STACK GAS
                           52.255 CU-FT


                           73.9   F

                           52.914 SCF


                          169.2


                            7.964 SCF
  1.480 CU-M


 23.3   C

  1.498 SC^


169.2


   .226 SO
13.06
.669
4.20
10.50
.00
65.30
29.09
27.64
13.08
.869
4.20
10.50
.00
85.30
29.09
27.64

-------
PB
PSI
PS
TS
VS
AS
OSSTO
OS
ISO
MN
CS
PMR
*
1
en
BAROMETRIC PRESSURE
STATIC PRES OF STACK GAS
STACK PRES, ABS.
AVERAGE STACK TEMP
AVG STACK GAS VELOCITY
STACK AREA
STACK FLOM RATE* DRY*
ACTUAL STACK FLOW RATE
PERCENT ISOKINETIC
FILTERABLE PART
MG. EPA 5 	
FILTERABLE PART
FILTERABLE PART
EMISSION RATE
6* DEC F, 29.92 IN.H6.
. . . - . _ 	 „ ._ _
29.30 IN-HG
"1.20 IN-H20
29.21 IN-HG
543. F
~17.9 FPS
7466. SO-IN
1492594. SCFH
3339539. ACFH
106.9
.0
.0000 GR/DSCF*
.000 LB/HR

	 .
700.22 *M-HG
-30.08 HH-H20
741.96 CM-HG
284. C
5.5 VPS
4.817 SO-M
42266. 3CMH
94566. »CVH
106.9
.0
.000 HG/OSC
.00 KG/HH



-------
              EXAMPLE PARTICIPATE CALCULATIONS TEST NO.   2-2

                   NO.l COKE BATTERY OUTLET



        VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

        VMSTD « (17.607 « VM • Y • (PB « PM / 13~i6)) /  (TM  * 060.)

                  17.647 •    52.255 * 1.004 • ( 29.30  «•  .620  /  13.6)
        VMSTO * ——————— — — ——— ———- — ----  r      52.9la DSCF
                                 (  74. «• 460.)



        VOLUME OF HATER VAPOR AT STANDARD CONDITIONS

        VWC * .04707 • VLC

        VHC » .04707 *  169. *   7.96 SCF



        PERCENT MOISTURE IN STACK GAS

        BNO « (100.  • VKC) / (VMSTD * VWC)

                  100. *   7.96
        BMO • ——	———— s 13.08 PERCENT
jp                   58.914 *   7.96
I            ...         ....     ..           ....      ...
Ul
oo
        MOLE FRACTION OF DRY STACK GAS

        FMD « (100.  • BNO) / 100.

                  100. -  13.i
        FMD » ————————— *   .869
                       100.



        AVERAGE MOLECULAR HEIGHT OF DRY STACK GAS

        MO * (PC02 • .44) * (P02 * .32) » (PN2 «• PCO) * .28

        MD = ( 4.20*44/100) » (10.5*32/100) * ((85.3* .0) * 28/100 =   29.09
        MOLECULAR WEIGHT OF STACK GAS

        MNS  « MD * (1.  - (BMO/100)) * 18. * (BNO/100)

        MNS  *  29.09* (1. -(13.08/100)) » 18. * (13.08/100) »   27.64

-------
       STACK  GAS  VELOCITY  AT  STACK  CONDITIONS



       OELP • SUM.  OF  THE  SORMVH * (TS »  460.))



       VS  * 85.19 • CP • DELP /  (SORT(MNS  *  PS)  *  PNTS)


       VS  > 85.49 *  .84 •   84.956 /  (SQRT( 37.64 •  29.21)   *  12.  -   17.89  FPS






       STACK  GAS  VOLUMETRIC FLOW  AT STACK  CONDITIONS



       OS  » VS *  AS *  3600/144



       OS  *    17.89 •   7466.  3600/144  *    3339959. ACFH






       STACK  GAS  VOLUMETRIC FLOW  AT STANDARD CONDITIONS



       OSSTD  * 17.647  * OS •  PT~* (1.  - (BMO/100)) /  (TS  *  460.)



                 17.647 *     3339559.  * 29.21  *  (1.  -  (13.08/100))

       OSSTD  * —	———	——	——	=    1«9259

Ui             (305.5SM 543.+460.))*((0.002669»~ 169.)V(   52.255*1.044*(  29.30+(    .620/13.6))/(   70.+060.)))

VD      iso •  ——————................................................—...............—.....	....... s 106.92 PEHCEM

                                          120.  •      17.89 •    29.21  *   .397 *   .397






       PARTICULATE  LOADING -- EPA METHOD s  (AT  STANDARD CONDITIONS)



       CS  * 0.001 •  MN • 15.43 /  VMSTD



       CS  • 0.001 *      .0 * 15.43 /    52.914 a     .000 GR/DSCF






       PARTICULATE  LBS/HR  —  EPA  METHOD 5



       PMR s  CS * QSSTD /  (15.43  *  453.6)



       PMR *      .000  *   1492594.  /  (15.43 *  453.6) =       .00

-------
Run No.  2.2
                           o
     Sample  volume =  1.50 m . 52.9  scf


Example  calculations

     CS  (Part)  =149.2/1.50  =  99.5 mq/m3


     CS  (Part)  =  0.001  x 149.2x 15.43/52.91  = 0.044   qr/dscf

     CS  (S02)   =  1720/  1.50=n46.7mo/m3

               =1146.7 x 24.06/64  = 431 ppm


               =  0.001  x!720 x 15.43/52^9J_ = n.sm  gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


149.2


24.8



n.o
0.0
1720

16.0



, Concentration,
mg/m


99.5


16.5



0.0
0.0
1146.7

10.7



gr/dscf


0.044


0.007



0.0
0.0
0.502

0.005



ppm











431

3



                                      A-60

-------
                                                        FIELD  DATA
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION COKE OVEN OUTLET
SAMPLE TYPE 2-3-M8-400
OPERATOR CLARKE
AMBIENT TEMP. (DEG.F) 69.
BAR. PRESS. (IN.HG) 29.30
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530057
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM 9 2.0 IN.HG
METER CALIB. FACTOR .992
READ ft RECORD DATA EVERY 10.0 MINUTES
TRAVERSE
POINT
NO.


INIT












SAMPLE
TIME
(MIN.)


0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
CLOCK
TIME
(24-HR
f*l f\f* V 1
UL.UCR J

1355
1405
1415
1425
1435
1445
1455
1505
1515
1525
1535
1545
1555
GAS METER
READING
(CU.FT.)
VELOCITY
HEAD
(IN.H20)
ORIFICE PRESSURE
DIFFERENT
(IN.H20)
1AL

STACK
TEMP
(DEG.F)
DESIRED ACTUAL
472.072
476.400
480.900
485.375
489.689
494.120
498.525
502.915
507.405
511.695
516.198
520.470
524.984
	
.050
.050
.050
.050
.050
,050
.050
.050
.050
.050
.050
.050

.60
.60
.60
.60
.60
.60
.60
.60
.60
.60
.60
.60

.60
.60
.60
.60
.60
.60
.60
.60
.60
.60
.60
.60

525.
519.
530.
537.
535.
543.
565.
511.
522.
534.
534.
553.
DATE 10/27/81
RUN NUMBER 2-3
PROBE LENGTH ft TYPE 5 FT GLASS HEATED
N02ZLE 2-3: I.D. .398
ASSUMED MOISTUHE 12.0
SAMPLE BUX NUMBER
PETER BUX NUMBtH FBI
KETEH HEAD 01FF. 1.87
C FACTON .88
PROBE HEATER SETTING 400.
HEATER BOX SETTING 400.
HEFERENCE PRESS. DIFF. .15
DKY GAS METER
TEMP
(DEG.F)
INLET OUTLET

64. 60.
66. 60.
JO. 60.
72. 61.
74. 62.
76. 64.
76. 62.
76. 64.
76. 62.
76. 63.
76. 65.
78. 64.
PUMP
VACUUM
(IN.HG)


2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
SAMPLE
BOX TEMP
(DEG.F)


300.
365.
389.
365.
406.
383.
416.
393.
404.
409.
426.
414.
IMPINGEK
TEMP
(DEG.F)


52.
42.
52.
52.
54.
54.
56.
56.
52.
52.
58.
58.
TOTALS
AVERAGE
120.0
52.912
                                         ,60
                               .60   534.
73.
62.
2.0   369.
53.

-------
           PARTICIPATE FIELD DATA S RESULTS TABULATION
PLANT* NAME AND ADDRESS  ~             TEST TEAM LEADER
REPUBLIC STEEL CLEVELAND              CLARKE
TEST
        2-3
COKE OVEN OUTLET
ENGLISH UNITS
TEST
TB
TF
TT
NP
Y
ON
CP
PM
DATE
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS 	
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
10/27/61
1355
1555
120
12




.0

.992
.398 IN
.64
.60 IN-H2U
METRIC UNITS
10/27/61
1355
1555
120.
12
*
10.
•
15.
0

992
1
84
2



»«

PM-
          DROP
VM        VOLUME OF DRY GAS SAMPLED
          AT METER CONDITIONS
TM        AVERAGE GAS METER TEMP
VMSTD     VOLUME OF DRY GAS SAMPLED
          AT STANDARD CONDITIONS*
VLC       TOTAL H20 COLLECTED IN
          IMPIN6ERS AND SILICA GEL,ML,
VMC       VOLUME OF MATER VAPOR
          AT STANDARD CONDITIONS*
6*0       PERCENT MOISTURE BY VOLUME
FMD       MOLE FRACTION DRV GAS
PC02      PERCENT C02 BY VOL., DRY
P02       PERCENT 02 BriniL.T DRY
PCO       PERCENT CO BY VOL., DRV
PN2       PERCENT N2 BY VOL., DRY
MO        MOLECULAR MT-DRV STACK GAS
MNS       MOLECULAR MT-STACK GAS
                                           52.912 CU-FT
                                                 1.496 CU-M
67.
51.
175.
6.
13.
•
4.
10.
•
65.
29.
27.
6 F
499 SCF
q
021 SCF
40
665
20
50
00
30
09
60
19.
1.
170.
•
13.
•
4.
to.
•
85.
29.
27.
9
458
4
227
48
865
20
50
00
30
09
60
C
SCP

SC*









-------
     PB         BAROMETRIC  PRESSURE
     P8I        STATIC  PRES OF  STACK  GAS
     PS         STACK PRES,  ABS.
     TS         AVERAGE STACK TEMP
     VS         AVG  STACK GAS VELOCITY
     AS         STACK AREA
     QSSTD      STACK FLOW  RATE.  DRY*
     OS         ACTUAL  STACK FLO* RATE
     ISO        PERCENT ISOKINETIC
     MN         FILTERABLE  PART
                 M6. EPA 5
     CS         FILTERABLE  PART
     PMR        FILTERABLE  PART
                 EMISSION  RATE
        •  68 DEC F,   29.92 IN.H6.
     39.30  IN-HG
     -i.20  IN-H20
     29.21  IN-HG
    534.    F
    ~if.e   FPS
   7466.   SO-IN
1493373.    SCFH
3338048.
    103.5
       .0
ACFH
       .0000 GR/DSCF*
       .000   LB/HH
  744.22  MM-HG
  -30.48  *M-H20
  741.98  KH-Mli
  279.    C
    5.4   KPS
    4.817 30-M
42288.    3CCH
94240.
  103.5
     .0

     .000
      .00  KG/HR
 I
CTl
U)

-------
      EXAMPLE PARTICIPATE CALCULATIONS TEST NO.   2-3

           COKE OVEN OUTLET



VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

VMSTD « (17.647 * VM * Y * (PB » PM / IS. 6)) /  (TM » 460.)

          17.64? •    52.912 *  .992 • ( 39.30  »  .600  /  13.6)
VMSTD « — --- ——————. ----- ....... ------------------  a      51.
-------
       STACK GAS VELOCITY AT  STACK CONDITIONS

       DELP » SUM.  OF THE SQRT(VH * (TS * 460.))

       VS * 85.49 * CP *  OELP /  (SORTCMHS * PS)  * PNTS)

       VS * 85.49 *  .84  *   84.596 /  (SORT( 27.60 •  29.21)   •  12.  r   17.83 FP3




       STACK GAS VOLUMETRIC FLOW  AT STACK CONDITIONS

       03 « VS • A3 * 3600/144

       OS *   17.83 •  f466.  3600/144  »    3328042.  ACFH




       STACK GAS VOLUMETRIC FLON  AT STANDARD CONDITIONS

       OSSTD * 17.647 • 03 *  P3 * (1.  - (BNO/100)) /  (TS »  460.)

                 17.647 *    3328042.  *  29.21  *  (1.  -  (13.48/100))
       OSSTO * ....—............................................ s    1493373.  SCFH
                          ( 534.  * 460.)
      PERCENT  ISOKINETIC

>     ISO  •  (305.58*(TS+460.))*U0.002669*VLC)«(VM*V*(PB+(PM/13.6))/(TM«460.)))/(TT«V9*PS«DN*DN)
I
           '"  (30S.M«( 534.*«60.))«C(0.002669
-------
Run No. 2.3
     Sample volume  =_l.A£m  ,__51_5Q_scf
Example  calculations
     CS  (Part)  =46.3 /1.46=  31.7  mq/m3
     CS  (Part)  =  0.001 x46.3  x 15.43/51.50=0.014   qr/dscf
     CS  (S02)   = 1700/1.46=n64.3ng/m3
               = 1164.3x 24.06/64  =438 ppm
               =  0.001 x1700  x 15.43J51.50   = 0.50  gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


46.3






12.2
16.7
1700

53.0



3 Concentration,
mg/m


31.7






8.3
11.4
1164.7

36.3



gr/dscf


0.014






0.004
0.005
0.509

0.016



ppm











438

9



                                      A-66

-------
                                                        FIELD  DAT*
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION COKE OVEN OUTLET
SAMPLE TYPE 2-4-M8-400
OPERATOR CLARKE
AMBIENT TEMP. (DEC. F) . 69.
BAR. PRESS. UN. HS) 29.30
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530062
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM 8 2.0 IN.HG
METER CALIB. FACTOR 1.016
READ * RECORD DATA EVERT 10.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY ORIFICE PRESSURE
POINT TIME
NO. (MIN.)

INIT 0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
TIME
(24-HR
ft np v i
(*LUt n i
ms
1408
1418
1428
1438
1448
1458
1508
1518
1528
1538
1548
'1558 ~
READING
(CU.FT.)

898.35)
902.665
906.900
911.186
915.762
919.670
924.085
928.200
932.712
936.920
940.920
945.776
949.848
HEAD
(IN.H20)

• • - - -
.050
.050
.050
.050
.050
.050
.050
.050
.050
.050
.050
.050
DIFFERENTIAL
(IN.
DESIRED

.60
.60
.60
.60
.60
.60
.60
.60
.60
.60
.60
.60
H20)
ACTUAL

.60
.60
.60
.60
.60
.60
.60
.60
.60
.60
.60
.60
STACK
TEMP
(DEG.F)


573.
524.
530.
539.
543.
555.
566.
514.
525.
536.
541.
559.
DATE 10/27/81
NUN NUMBER i-n
PRUBE LENGTH « TYPE 6 FT GLASS HEATED
NU22LE 2-4t I.D. .397
ASSUMED MOISTURE 12.0
SAMPLE BOX NUMBER F
METER BOX NUMBER FBS
METEH HEAD DIFK i.t»6
C FACTOR .68
PROBE HEATER SETTING 400.
HEATER BOX SETTING 400.
tfEFEKENCE PRESS. DIFF. .75
DKY GAS METER PUMP SAMPLE IMPINGER
TEMP VACUUM
(DEG
I&LET

68.
69.
72.
74.
76.
78.
78.
78.
78.
78.
78.
62.
.F) (IN.HG)
OUTLET

69.
69.
70.
70.
70.
72.
72.
72.
72.
72.
72.
74.
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
BOX TEMP
(DEG.F)


405.
369.
386.
430.
373.
394.
392.
394.
422.
413.
450.
418.
TEMP
(OEG.F)


42.
38.
40.
42.
46.
48.
46.
44.
42.
44.
46.
48.
TOTALS
AVERAGE
120.0
51.495
                                         .60
                               .60   542.
76.
71.
1.0   404.
44.

-------
           PARTICULATE FIELD DATA ft RESULTS TABULATION

PLANT* NAME AND ADDRESS               TEST TEAM LEADER

REPUBLIC STEEL CLEVELAND              CLARKE
TEST
2-4
COKE OVEN OUTLET


TEST DATE
TB
TF
TT
NP
Y
ON
CP
PM
I VM
CO
TM
VMSTD
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS 	
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRV GAS SAMPLED
ENGLISH UNITS
10/27/81
1358
1558
120.0
12
1.016
.397 IN
. ..••«
.60 IN-H20
51.495 CU-FT
T3.5 F
50.787 SCF
METRIC UNITS
10/27/81
1358
1558
120.0
12
1.016
10.1
.84
15.2
1.458
23.0
1.438



KM

CM-H20
CU-M
C
SCK
          AT STANDARD CONDITIONS*

VLC       TOTAL H20 COLLECTED IN
          IMPINGERS AND SILICA GELrML.

VNC       VOLUME OF MATER VAPOR
          AT STANDARD CONDITIONS*

8Mb    ~ PERCENT MOISTURE BT VOLUME

FMD       MOLE FRACTION DRY GAS

PC02      PERCENT C02 BT VOL.r DRY

P02       PERCENT 02 6T VOL.; DRY

PCO       PERCENT CO BY VOL.* DRY

PN2       PERCENT N2 BY VOL.r DRV

MO        MOLECULAR NT-DRY STACK GAS

MMS       MOLECULAR XT-STACK GAS
                                  156.1
                                    7.348 SCF
                                               156. 1
                                                  .208 SC»
12.64
.874
4.20
10.50
.00
05.30
29.09
27.69
12.64
.874
4.20
10.50
.00
85.30
29.09
27.69

-------
PB        BAROMETRIC PRESSURE

PSI       STATIC PRES OF STACK GAS

PS        STACK PRES, ABS.

TS        AVERAGE STACK TEMP

VS        AV6 STACK GAS VELOCITY

AS        STACK AREA

QSSTO     STACK FLO* RATE* DRY*

OS        ACTUAL STACK FLOM RATE

ISO       PERCENT ISOKINETIC

MN        FILTERABLE PART
            MG. EPA 5

CS        FILTERABLE PART

PMR       FILTERABLE PART
            EMISSION RATE

   *  6* DEC Ft  29.92tN.H6.
     29.30  IN-HG

     •1.20  IN-H20

     29.21  IN-HG

    542.    F

     if.9   FPS
   7466.

1499060.

3336176.

    102.2

       .0
SO-IN

 SCFH

 ACFH
       .0000 GR/DSCF*

       .000   LB/HH
  Taa.22  KM-HG

  -30.48  HM-H20

  741.98  MM-HG

  283.    C

    5.4   HP8

    4.817 SO-M

42449.    SCHH

94471.    ACMH

  1U2.2

     .0


     .000 HG/OSCP

      .00  KG/HR

-------
      EXAMPLE PARTICIPATE CALCULATIONS TEST NO.   2-4

           COKE OVEN OUTLET



VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

VMSTD * (17.647 • VM • T • (PB » PM / 13.6)) /  (TM » 460.)

          17.647 •    51.495 * 1.016 • ( 29.30  *  .600 /  13.6)
VMSTO * — — — — — -------- ..... --- . --- . --------------------  -      50.787  USCF
                         I  73. * 460.)



VOLUME OF MATER VAPOR AT STANDARD CONDITIONS

VMC m .04707 • VLC

VHC • .04707 *  156. »  ~7.3S SCF



PERCENT MOISTURE IN STACK GAS

BMO a (100. * VMC) / (VMSTO * VHC)

          100. •   7.35
            ——————— z 12.64 PERCENT
            50.787 *   7.35
MOLE FRACTION OF DRY STACK GAS

FMD « (100. - BMO) / 100.

          loo. -  it.*
FMD m —————— x   .874
               100.
AVERAGE MOLECULAR WEIGHT OF DRY STACK GAS

MD • (PC02 • .44) «• (P02 • .32) * (PN2 * PCO) * .28

MO = ( 4.20*44/100) * (10.5*32/100) » ((85.3* .0) • 28/100 =   29.09



MOLECULAR HEIGHT OF STACK GAS

MHS s MD * (1. - (BMO/100)) » 18. • (BHO/100)

MMS «  29.09* (1. -(12.64/100)) * IB. * 112.64/100) r   27.69

-------
        STACK CAS VELOCITY AT STACK CONDITIONS

        DELP « SUM.  OF THE SORTtVH * (TS * 460.))

        VS a 85.49 * CP •  DELP / ISQRTtMMS *  PS)  * PNTS)

        VS = 65.49 *  .84  *   84.945 /  (SORT( 27.69 * 29.21)   *   12.  a   17.87  FP3



        STACK CAS VOLUMETRIC  FLOM AT STACK CONDITIONS

        OS > VS * A3 * 3600/144

        OS a   17.87 «  7466. 3600/104  m   3336176.  ACFH




        STACK CAS VOLUMETRIC  FLON AT STANDARD CONDITIONS

        OSSTD « 17.647 • OS • PS • U.  - (BMO/lOO))  / (TS *  460.)

                  17.647 *    3336176.  *  29.21  *  (1. -  (12.64/100))
        OSSTD a ————————.—-————- — - —	...  3    1499060.  SCFH
                           (  542. * 460.)



        PERCENT ISOKINETIC

>       ISO • (305.58*(TS»460.))«((0.002669«VLC)*lVM*r*(PB*(PM/13.6))/(TM*460.)))/(TT«VS*PS«DN*DN)

^              (305.58«( 542.*460.))*((0.002669i-  I56.)+(   51.495*1.016*(  29.30*1   .600/13.6))/(   73.4460.)))
        ISO » —————	........	.................	.	..	..	.	.  .  102.18 PEHCENT
                                           120.  •      17.87  *   29.21  *   .397 *   .397




        PARTICIPATE  LOADING "EPA METHOD  5 (AT  STANDARD  CONDITIONS)

        CS a 0.001 • MN •  15.43 / VMSTD

        CS • 0.001 *      .0  * 15.43 /     50.787 *     .000  GR/OSCF




        PARTICULATE  LBS/HR — EPA METHOD 5

        PMR • CS  * OSSTD / (15.43 * 453.6)

        PMR •     .000 *   1499060.  /  (15.43 *  453.6) =       .00

-------
Run No.  2.4
     Sample volume =  1.44m3r 50.79scf
Example  calculations
     CS  (Part) =61.3  /1.44 =42.6   mq/m3
     CS  (Part) = 0.001 x 61.3 x 15.43/50.79 = 0.019   qr/dscf
     CS  (S02)  = 1610/1.44=1118.Qng/m3
              J118.0 x 24.06/64  =420 ppm
              = 0.001 x!610  x 15.43/50.79 = 0.489 gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Sulfur dioxide
Sulfuric acid mist
As H2$04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


61.3






14.4
19.7
1610

19.6



o Concentration,
mg/m


42.6






10.0
13.7
1118.0

13.6



gr/dscf


0.019






0.004
0.006
0.489

0.006



ppm











420

3



                                     A-72

-------
                                                              FIELD  DAT*
 I
^1
OJ
PLANT REPUBLIC STEEL
SAMPLING LOCATION COKE OVEN STACK
SAMPLE TYPE METHOD 5-250
OPERATOR 00
AMBIENT TEMP.(DEG.F) 63.
BAR. PRESS. (IN. H6> 29.03
STATIC PRESS. (IN. H20) -1.20
FILTER NUHBER(S) 3530000
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .012 CFM 9 7.
METER CALIB. FACTOR 1.033
READ S RECORD DATA EVERY 10.0 MINUTES
TRAVERSE
POINT
NO.

INIT












SAMPLE CLOCK
TIME
(MIN.

0
10.0
20.0
30.0
40.0
50.0
'60.0
70.0
ao.o
90.0
100.0
110.0
120.0
TIME
) (24-HR
ft nr» M i
CLUCK 1
1424
1434
1444
1454
1504
1514
~ 1524
1534
1544
1554
1604
1614
1624
GAS METER
READING
(CU.FT.)

645.051
649.460
653.770
658.110
662.460
666.820
671.190
675.560
679.940
684.320
686.710
693.140
697.556
VELOCITY
HEAD
(IN.H20)

	 	
.057
.057
.057
.057
.057
.057
.057
.057
.057
.057
.057
,05f
CLEVELAND
0 IN.HG
ORIFICE
PRESSURE
DIFFERENTIAL
(IN.
DESIREU

.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
H20)
ACTUAL

.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
.63
STACK
TEfP
(OEG.F)


499.
499.
099.
099.
099.
099.
099.
099.
099.
099.
099.
099.
DATE 10/27/81
HUN NUMBER 2-5
HHOBE LENGTH 8 TYPE 6* GLASS
NOZZLE 6-1101 I.U. .377
ASSUMED MOISTURE 11.0
SAMPLE BOX NUMBER
METER BOX NUMBEH FBO
METER HEAD 01FF. 1.88
C FACTOR .92
PROBE HEATER SETTING 250.
HEATER BOX SETTING 250.
HEFENENCE PRESS. DIFF. .17
DRY GAS METER
TEMP
(OEG.F)
INLET OUTLET

67. 66.
68. 66.
1i. 67.
70. 68.
77. 69.
76. 70.
79. 71.
00. 72.
SO. 73.
»0. 73.
80. 73.
79. 73.
PUPP
VACUUM
(IN.HG)


3.7
.7
.0
.1
.2
.4
.5
.8
5.0
5.0
5.7
5.7
SAMPLE
BOX TEMP
(OEG.F)


234.
271.
271.
238.
252.
262.
208.
271.
205.
252.
275.
261.
IPPINGER
TEMP
(DEG.F )


so.
50.
50.
08.
06.
48.
08.
50.
50.
50.
50.
48.
      TOTALS
      AVERAGE
120.0
52.507
                                         .63
                               .63   099.
76.
70,
0.6   257.
49.

-------
           PARTICIPATE FIELD DATA S RESULTS TABULATION




PLANT- NAME AND ADDRESS               TEST TEA* LEADER




REPUBLIC STEEL CLEVELAND              DO
TEST
2-5
COKE OVEN STACK


TEST DATE
TB
TF
TT
NP
Y
DN
CP
PM
> VM
1
•* TM
VMSTD
VLC
VMC
BNO
FMD
PC02
P02
PCO
PN2
MO
MHS
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRV GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H20 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF NATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL., DRY
PERCENT 02 8V VOL., DRV
PERCENT CO BY VOL., DRV
PERCENT N2 BY VOL., DRY
MOLECULAR HT-ORY STACK GAS
MOLECULAR MT-STACK GAS
ENGLISH UNITS
10/27/81
1424
1624
120.0
12
1.033
.377 IN
.84
.63 IN-H20
52.507 CU-FT
T3.1 F
52.922 SCF
ns.s
8.261 SCF
13.50
.865
4.20
10.50
.00
85.30
29.09
27.59
METRIC UNITS
10/27/81
1424
1624
120.0
12
1.033
9.6
.84
16.0
1.487
22.8
1.499
175.5
.234
13.50
.865
4.20
10.50
.00
85.30
29.09
27.59



MM

MM-H20
CU-M
C
SCM

SCM









-------
     PB        BAROMETRIC PRESSURE

     PSI       STATIC PRES OF STACK GAS

     PS        STACK PRESf ABS.

     TS        AVERAGE STACK TEMP

     VS        AV6 STACK GAS VELOCITY

     AS        STACK AREA

     OSSTO     STACK FLOW RATE* DRY*

     OS        ACTUAL STACK FLOH RATE

     ISO       PERCENT ISOKINETIC

     MN        FILTERABLE PART
                 M6. EPA 5

     CS        FILTERABLE PART

     PMR       FILTERABLE PART
                 EMISSION RATE

        *  68 OEG F,  39.93 IN.HG.
     29.43  IN-HG

     -1.20  IN-H20

     29.34  IN-HG

    499.    F

     18.7   FPS

   7066.   SO-IN

1636567.    SCFH
3482787.

    108. 8

       .0
ACFH
       .0000 GR/OSCF*

       .000   LB/HR
  707.52  MM-HG

  -30.48  KM-H20

  745.28  PM-HG

  259.    C

    5.7   *P3

    4.817 3Q-M

46059.    3CfH

98622.    ACMH

  108.8

     .0
                .000

                 .00  KG/HR
 I
•~J
Ul

-------
              EXAMPLE PARTICIPATE CALCULATIONS  TEST  NO.    2-5

                   COKE OVEN STACK



        VOLUME OP DRY GAS SAMPLED AT STANDARD CONDITIONS

        VMSTO »  (17.64f • VM * Y *  (PB V PM  / U.6))  /  (TM «• 460.)

                  17,647 *    52.507 • 1.033 *  ( 29.43  *   .630  /  13.6)
        VMSTD «  ————————.———.——. — ... — .. — ..  3      58.S22 OSCF
                                 I  73. * 460.)



        VOLUME OF MATER VAPOR AT STANDARD CONDITIONS

        VNC » .04707 * VLC

        VMC « ,04707 *  If 6. •   8.26 SCF



        PERCENT  MOISTURE IN STACK GAS

        BHO « (iOO. • VMC) 7 (VMSTO * VWC)

                  100. *   6.26
        BHO « — — --- — — ----- — ---- — a 13.50 PERCENT
>                   52.922 *   a. 26
 I
~j                   ......
CTi

        MOLE FRACTION OF DRV STACK GAS

        FMD * (100. • BMO) / 100.

                  100. -  Il.f
        FMD * —.———.——— --- r   .865
                       100.
        AVERAGE MOLECULAR HEIGHT OF DRY STACK GAS

        MD * (PC02 * .44) * (P02 * .32) »  (PN2 * PCO) *  .28

        MD a ( 4.20*44/100) + (10.5*32/100) * ((85.3* .0) * 28/100  «    29.09



        MOLECULAR MEIGHT OF STACK GAS

        MM 3 a MD * (1. - (8MO/100)) *  18.  * (BHO/100)

        MMS *  29.09* (1. -(13.50/100)) »  18. *  (13.50/100) »   27.59

-------
       STACK 6A3 VELOCITY AT STACK CONDITIONS

       DELP « SUM. OF THE SQRT(VH * (TS * 460.))

       VS * 85.49 • CP • OELP / (SORT(MMS • PS) * PNTS)

       V3 = 8S.49 •  .84 *   88.721 / (3URT( 27.59 • 29.34)  *  12. s   16.66 FPS



       STACK CAS VOLUMETRIC FLO* AT STACK CONDITIONS

       OS « VS * AS * 3600/144

       OS *   18.66 •  7466. 3600/144 •    3482787. ACFH



       STACK GAS VOLUMETRIC FLON AT STANDARD CONDITIONS

       QSSTO * 17.647 * OS • PS * (1. - (BMO/100)) / (TS » 460.)

                 17.647 *    3482787. *  29.34 * (1. - (13.50/100))
       OSSTD * — -—-.—————..— — — ——.. —.- e    1626567. SCFH
                          ( 499. «• 460.)



       PERCENT ISOKINETK

>      ISO * (305.58*(TS+460.))M(0.002669*VLC)«(VH*V*(PB*(PM/13.6))/(TM+460.)))/(TT*V3*PS*ON*DN)
I
-J             (305.58M 499.*460.))*((0.002669*  176.)*{   $2.507*1.033*(  29.03*1    .630/13.6))/(  73.+460.)))
       ISO « —————————	—	.....	.	..	> 108.62 PEHCEM
                                          120. *     18.66 *   29.34 •  .377 *  .377



       PARTICIPATE LOADING"-- EPA METHOD 5 (AT STANDARD CONOltlONS)

       CS « 0.001 • MN • 15.43 / VMSTD

       CS s 0.001 *      .0 « 15.43 /    52.922 =     .000 GR/DSCF



       PARTICULATE LBS/HR -- EPA METHOD 5

       PMR « CS * OSSTD / (15.43 * 453.6)

       PMR «     .000 *    1626567. / (15.43 * *53.6) *      .00

-------
Run No.  2.5
     Sample volume  =  1.50 m  .  52.92 scf
Example  calculations
     CS  (Part)  =90.9/1.5 =  60.6  mq/m3
     CS  (Part)  =  0.001  x90-9  x 15.43/52.92 = 0.026  qr/dscf
                                     3
     CS (S02)   =	/	=	mg/nr
               =	 x  24.06/	=	ppm
               =  0.001 x	x 15.437	
gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Sulfur dioxide
Sul f uric acid mist
As H2$04
As H2S04-2H20
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


90.9
34.0
30.7
29.2
27.7
22.5

0.0
0.0




68.2
4.8
44.3
3 Concentration,
mg/m


60.6
22.7
20.5
19.5
18.5
15.0

0.0
0.0




45.5
3.2
29.5
gr/dscf


0.026
0.010
0.009
0.008
0.008
0.006

0.000
0.000




0.020
0.001
0.013
ppm


















                                       A-78

-------
                                                               FIELD  DATA
 i
-o
vo
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION COKE OVEN STACK
SAMPLE TYPE METHOD 6-600
OPERATOR 00
AMBIENT TEMP. (DEG.F) 63.
BAR. PRESS. (IN.HG) 29.43
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530212
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .64
THERM. NO.
LEAKAGE .000 CFM 8 21.7 IN.HG
METER CALIB. FACTOR .962
READ • RECORD DATA EVERY 10.0 MINUTES
TRAVERSE
POINT
NO.

INlt









SAMPLE
TIME
(MIN.)

0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
60.0
90.0
CLOCK
TIME
(24-HR

1419
1429
1439
1449
1459
1509
1519
1529
1539
1549
GAS METER
READING
(CU.FT.)

141.627
149.070
156.460
163.870
170.840
177.430
163.760
169.600
195.720
201.620
VELOCITY
HEAD
(IN.H20)

	
.057
.057
.057
.057
.057
.057
.057
.057
.057
ORIFICE
PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.66
.66
.68
.68
.68
.66
.68
.68
.68
H20)
ACTUAL

.90
.90
.90
.60
.49
.36
.28
.15
.13
STACK
TEMP
(OEG.F)


499.
499.
499.
499.
499.
499.
499.
499.
499.
DATE 10/27/61
HUN NUMBER 2-6
PROBE LENGTH S TYPE 4' QUARTZ
NOZZLE ! 1.0. .590
ASSUMED MOISTURE 11.0
SAMPLE BUX NUMBER
METER BOX NUMBER FB8
ME1EH MEAD OIFF. 1.91
C FACTOH .94
PROBE HEATER SETTING 600.
HEATER BUX SETTING t>oo.
DEFERENCE PRESS. OIFF. .03
DRY GAS METER
TEMP
(DEG.F)
INLET OUTLET

63. 62.
66. 62.
70. 62.
72. 63.
71. 63.
70. 64.
69. 64.
66. 63.
68. 63.
PUMP
VACUUM
(IN.HG)


7.2
6.6
12.6
19.8
20.5
20.6
21.0
21.4
21.4
SAMPLE
BOX TEMP
(OEG.F)


617.
564.
596.
619.
567.
576.
566.
616.
635.
IMPINGER
TEMP
(DEG.F)


42.
44.
50.
60.
58.
56.
56.
54.
50.
      TOTALS

      AVERAGE
90.0
59.993
                                       3.66
                              1.55
499.
69.
63.
17.1
600,
52.

-------
           PARTICUIATE FIELD DATA ft RESULTS TABULATION

PLANT- NAME AND ADDRESS               TEST TEAM LEADER

REPUBLIC STEEL CLEVELAND              DO
TEST
2-6
COKE OVEN STACK


TEST DATE
TB
TF
TT
NP
Y
ON
CP
PM
1 VM
00
o
TM
VMSTD
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRV GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRV GAS SAMPLED
ENGLISH UNITS
10/27/81
1509
90.0
9
.982
.590 IN
	 .80
1.55 IN-H20
59.993 CU-FT
65.7 F
58.020 SCF
METRIC UNITS
10/27/81
1019
1509
90.0
9
.982
15.0
.80
39.3
1.699
18.7
1.650



I'M

MM-H20
CU-M
C
SCK
          AT STANDARD CONDITIONS*

VLC       TOTAL H20 COLLECTED IN
          IMPINGERS AND SILICA GEL,ML,

VNC       VOLUME OF MATER VAPOR
          AT STANDARD CONDITIONS*

BMO       PERCENT MOISTURE BY VOLUME

FMO       MOLE FRACTION DRY GAS

PC02      PERCENT C02 BY VOL., DRV

P02       PERCENT 02 B? VOL., DRY

PCO       PERCENT CO BY VOL., DRV

PN2       PERCENT N2 BY VOL., DRV

MD        MOLECULAR NT-DRY STACK GA9

MWS       MOLECULAR MT-STACK GAS
                                    7.056 SCF
                                                       109.9
                                                  .200 SO
10.78
.892
0.20
10.50
.00
85.30
29.04
27.90
10.78
.892
0.20
10.50
.00
85.30
29.09
27.90

-------
     PB        BAROMETRIC PRESSURE

     PSI       STATIC PRES OF STACK 6AS

     PS        STACK PRES, ABS.

     TS        AVERA6E STACK TEMP

     VS        AV6 STACK GAS VELOCITY

     AS        STACK AREA

     OSSTD     STACK FLON RATE, DRY*

     os        ACTUAL STACK FLON RATE

     ISO       PERCENT ISOKINETIC

     MN        FILTERABLE PART
                 M6. EPA 5

     CS        FILTERABLE PART

     PMR       FILTERABLE PART
                 EMISSION RATE

        *  68 DEC F,  29.92 iN.HG.
     29.43  IN-HG

     •1.20  IN-H20

     29.34  IN-HG

    499.    F

     18.6   FPS

   7466.   SO-IN

1666717.    SCFH

5463857.    ACFH

     63.7

       .0


       .0000 GR/DSCF*

       .000   LB/HR
  747.52  fM-HG

  •30.46  CM-H20

  745.28  CM-HG

  259.    C

    5.7   *P3

    4.617 SO-M

47253.    SC»»H

96066.    ACHH

   63.7

     .0


     .000 PG/DSCP

      .00  KG/HR
 I
00

-------
              EXAMPLE PARTICIPATE CALCULATIONS TEST NO.   2-6

                   COKE OVEN STACK



        VOLUME OF DRY 6A9 SAMPLED AT STANDARD CONDITIONS

        VMSTD * (17.647 * VM * T * (PB » PM / 13.6)) / (TM * 460.)

                  17.647 *    59.993 •  .982 * ( 29.43 * 1.548 / 13.6)
        VMSTD « ——————-———.—...........—........... 3     56.424  OSCF
                                 I  66. «• 460.)



        VOLUME Of MATER VAPOR AT STANDARD CONDITIONS

        VMC « .04707 • VLC

        VHC • .04707 *  ISO. »   7.06 SCF



        PERCENT MOISTURE IN STACK GAS

        BMO » (100. • VMC) '/ (VMSTD » VMC)

                  100. *   7.06
        BMO « ——	———	...... 3 10.78 PERCENT
;>                   58.424 *   7.06
I
oo                         ""	               " ' "
NJ
        MOLE FRACTION OF DRY STACK GAS

        FMD « (100. - BMO) / 100.

                  100. -  10.8
        FMD » ——.———.—— s   .892
                       100.



        AVERAGE MOLECULAR HEIGHT OF DRV STACK GAS

        MD « (PC02 * .44) » (P02 * .32) » (PN2 • PCO) * .28

        MD * ( 4.20*44/100) * (10.5*32/100)  * ((85.3* .0) * 28/100 s   29.09



        MOLECULAR MEIGHT OF STACK GAS

        MMS * MO * (1. - (BMO/100)) » 18. *  (BMO/100)

        MMS a  29.09* (1. -(10.76/100)) * 18. * (10.78/100) s   27.90

-------
        STACK GAS VELOCITY AT STACK CONDITIONS

        OELP « SUM. OF THE SORHVH * (TS * 060.))

        VS * 65. 49 • CP * OELP / (SORTCMNS * PS) * PNTS)

        VS > 95.49 •  .84 *   66.541 / (SORT( 27.90 * 29.34)  •
                                                          9. a   16.56 FPS
STACK 6AS VOLUMETRIC FLO* AT STACK CONDITIONS

OS * VS * AS * 3600/144

OS •   IB. 56 *  7466. 3600/144 «    346S657. ACFH
STACK GAS VOLUMETRIC FLON AT STANDARD CONDITIONS

OSSTD * 17.647 * OS • PS * (1. • (BMO/100)) / (TS + 460.)

          17.647 •    3463657. •  29.34 *  (1. - (10.76/100))
           —————————— — ............. ---- ......
                   ( 499. » 460.)
        OSSTO »
                                                                 1666717. SCFH
S
PERCENT ISOKINETIC

ISO • (305.58*(TS*460.) )«((0.002669*VLC)»(VM*Y*(PB*(PH/13.6) ) / 
-------
Run No.   2.6
     Sample volume = I-65  m , 58.42 scf
Example calculations
     CS (Part)  =39.5/1.65 = 23.9  mo/m3
     CS (Part)  =  0.001  x 39-5 x  15.437 58.42=  0.010 qr/dscf
     CS (S02)   =  1940/1.65 =1175.8mo/m3
               =1175.8X 24.06/64  = 442 pDtT1
               =  0.001  xJiiLx  15.43/58.42  = 0.512 gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H£S04
As H2S04-2H20
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


39.5






2.6
3.5
1940

157



3 Concentration,
mg/m


23.9






1.6
2.1
1175.8

95.7



gr/dscf


0.010






0.001
0.001
0.512

0.041



ppm











442

23



                                      A-84

-------
                                                                 FIELD  DATA
 I
00
Ul
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION N01 COKE BATTERY OUTLET
SAMPLE TYPE PART/302/H2SU4
OPERATOR BRUFFEY
AMBIENT TEMP. (DEG.F) 58.
BAR. PRESS. (IN. HG) 29.78
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3930093
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM 3 3.0 IN.HG
METER CALIB. FACTOR 1.003
READ ft RECORD DATA
TRAVERSE
POINT
NO.

INIT












SAMPLE
TIME
(MIN.)

9
10.0
20.0
30.0
• 0.0
50.0
60.0
70.0
ao.o
90.0
100.0
110.0
120.0
CLOCK
TIME
(24-HR
f i ncK i
vLUtK;
955
1005
1015
1025
1035
1045
1055
1105
1115
1125
1135
lias
1155
EVERT 10. 0
GAS METER
READING
(CU.FT.)

777.764
783.020
788.000
793.070
798.540
803.570
808.620
813.670
818.720
823.350
828.440
833.520
838.555
MINUTES
VELOCITY
HEAD
(IN.H20)

	
.065
.060
.060
.070
.060
.060
.060
.060
.050
.060
.060
.060

ORIFICE

PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.80
.73
.73
.87
.73
.73
.73
.73
.61
.73
.73
.73
H20)
ACTUAL

.80
.73
.73
.87
.73
.73
.73
.73
.61
.73
.73
.73

STACK
TEMP
(DEG.F)


546.
515.
525.
536.
531.
550.
558.
517.
528.
539.
529.
545.
DATE 10/28/81
RUN NUMBER 3-1
PROBE LENGTH ft TYPE 5* HEATED GLASS
M022LE t I.U. .398
ASSUMED MUISTUHE 12.0
SAMPLE BOX NUMBER U
METEN BOX NUMBtk FB2
HETEH HEAD OIFF. 1.76
C FACTOR .86
PROBE HEATER SETTING 250.
HEATER BOX SETTING 250.
HEFERENCE PRESS. DIFF. .15

DRY GAS METER
TEMP
(DEG.F)
INLET OUTLET

54. 55.
56. 55.
58. 56.
61. 55.
62. 56.
62. 56.
63. 56.
64. 57.
6«. 57.
64. 57.
64. 57.
64. 57.

PUMP
VACUUM
(IN.HG)


2.0
2.0
2.5
2.0
2.5
2.5
2.5
2.5
3.0
3.0
3.0
3.0

SAMPLE
BOX TEMP
(DEG.F)


160.
228.
251.
239.
248.
248.
247.
245.
242.
245.
241.
234.

IMPINGEH
TEMP
(OEG.F)


44.
44.
43.
4a.
43.
44.
4«.
46.
44.
42.
44.
43.
        TOTALS
        AVERAGE
120.0
60.791
                                          .74
                                ,74   535.
61.
56.
2.5   236.
44.

-------
           PARTICULATE FIELD DATA » RESULTS TABULATION

PLANT- NAME AND ADDRESS               TEST TEAM LEADER

REPUBLIC STEEL CLEVELAND              BRUFFEY
TEST
3-1
NOI COKE BATTERY OUTLET
ENGLISH UNITS
TEST DATE
TB
TF
TT
NP
Y
ON
_CP
PM
1 VM
00
en
TM
VMSTD
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS 	
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRV GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRV GAS SAMPLED
10/28/81
953
1155
120.
12
1.
.
__._•
•
60.
58.
61.
0

003
398 IN
64
74 IN-H20
791 CU-FT
8 F
683 SCF
METRIC UNITS
10/26/81
955
1155
120
12
1
10

16
1
la
1
.0

.003
.1
.64
.T
.721
.9
.752



I'M

MM-H20
CU-M
C
SCM
          AT STANDARD CONDITIONS*

VLC       TOTAL H2«i COLLECTED IN
          IMPINGERS AND SILICA GEL,ML,

VNC       VOLUME OF MATER VAPOR
          AT STANDARD CONDITIONS*

0MO       PERCENT MOIfTURE BY VOLUME

FMO       MOLE FRACTION DRY GAS

PC02      PERCENT C02 BY VOL.* DRY

P02       PERCENT 02 BY VOL., DRV

PCO       PERCENT CO BY VOL., DRV

PN2       PERCENT N2 BY VOL.* DRY

MD        MOLECULAR HT-DPY STACK GA3

MMS       MOLECULAR MT-STACK GAS
                                    8.633 SCF
                                                       163.4
                                                  .244 SCN
12.24
.878
2.30
10.90
.00
86.80
28.60
27.48
12.24
.876
2.30
10.90
.00
66.80
26.80
27.48

-------
     PB        BAROMETRIC PRESSURE

     P9I       STATIC PRES OF STACK GAS

     PS        STACK PRES, AB9.

     TS        AVERAGE STACK TEMP

     VS        AV6 STACK GAS VELOCITY

     AS        STACK AREA

     OSSTO     STACK FLOW RATE, DRY*

     OS        ACTUAL STACK FLO* RATE

     ISO       PERCENT ISOKINETIC

     MN        FILTERABLE PART
                 M6. EPA 5

     CS        FILTERABLE PART

     PMR       FILTERABLE PART
                 EMISSION RATE

        •  68 OEG F,  29.92 IN.HG.
     29.78  IN-MG

     •1.20  IN-M20

     29.69  IN-HG

    535.    F

     19.5   FPS

   7466.   SO-IN

1680373.    SCFH
3635799.

    110.5

       .0
ACFH
       .0000 GR/OSCF*

       .000   LB/HR
   756.ai  MM-HG

   -30.a8  KM-H2U

   750.17  MM-HG

   279.    C

     5.9   KPS

     1.817 30-M

 47583.    SCI»H

102955.    »CKM

   110.5

      .0


      .000 KG/DSC^

       .UU  KG/HH
 I
00

-------
              EXAMPLE PARTICIPATE  CALCULATIONS TEST NO.    3-1

                   N01 COKE BATTERY  OUTLET




        VOLUME OF  DRY GAS  SAMPLED  AT STANDARD CONDITIONS

        VMSTO  « (17.647 •  VM •  Y  • (PB * PM / 13.6)) / (TM + 460.)

                  17.647 *   60.791 * 1.003 * (  29.78 «•  .736 / 13.6)
        VMSTD  • ——...	.	..	 =     61.883 OSCF
                                 I  59. * 460.)




        VOLUME OF  MATER VAPOR AT  STANDARD CONDITIONS

        VNC  »  .04707  * VLC

        VMC  »  .04707  *  103. s    6.63 SCF




        PERCENT MOISTURE IN STACK  GAS

        BWO  i'tiOO. • VWC) 7~(VMSTD  * Vt«C)

                  too. •   a.63
        BNO  *  —.——	.	.......... *  12.24  PERCENT
>                  61.883 *   8.63

oo                          -                    —
CO

        MOLE FRACTION OF DRY STACK GAS

        FMD  »  (100. - BHO) / 100.

                  100. -  12.2
        FMD  «  ——————......... c   .878
                       100.




        AVERAGE MOLECULAR  HEIGHT  OF  DRY STACK GAS

        MD * (PC02 •  .44)  4 (P02  * .32) » (PN2 •  PCO)  *  .28

        MD a (  2.30*44/100) * (10.9*32/100) + ((86.8*  .0)  « 28/100  =   28.80




        MOLECULAR  HEIGHT OF STACK  GAS

        MNS  >  MD * (1. - (BMO/IOO))  * 18. * (BMO/100)

        MNS  «   28.80* (1.  •(12.24/100)) * IB. * (12.24/100) *    27.48

-------
        STACK GAS VELOCITY AT STACK CONDITIONS

        DELP • SUM. OF THE 3QRT(VH • ITS » 460.))

        VS « 85.49 • CP • DELP / (SORT(MHS • PS) * PNTS)

        VS > 85.49 •  .84 •   92.979 / (SQRT( 27.48 • 29.69)  •  12. =   19.«8 FP3




        STACK GAS VOLUMETRIC FLOM AT STACK CONDITIONS

        OS > VS • AS • 3600/144

        OS *   19.48 •  7466. 3600/144 •    3635799. ACFH




        STACK GAS VOLUMETRIC FLOW AT STANDARD CONDITIONS

        OSSTD * 17.647 • OS • PS • (1. - tBMO/100)) / (TS * 460.)

                  17.647 •    3635799. *  29.69 • (1. - (12.24/100))
        OSSTD » ———————————————............. =    1680373. SCFH
                           ( 535. » 460.)




>       PERCENT ISOKINETIC
 I
^       ISO * (305.5B*(TS»460.))*((0.002669*VLC)*(VM*Y*(PB*(PM/13.6))/(TM*460.)))/(TT*VS*P3*ON*DN)

               (30S.58*( 53S.+460.))*((0.002669*  183.)*(   60.791*1.003*(  29.78+(    .738/13.6))/(  59.+060.)))
        ISO » .-—-.—......... .........	......	....	..	...	.	...	.	B 110.51 PERCENT
                                           120. *     19.48 *   29.69 *  .398 *  .398




        PARTiCULATE LOADING •• EPA METHOD 5 (AT'STANDARD CONDITIONS)

        CS • 0.001 * MN * 15.43 / VM3TD

        CS * 0.001 *      .0 • 15.43 /    61.883 >     .000 GR/OSCF




        PARTICULATE LBS/HR — EPA METHOD 5

        PAR B CS * OSSTD / (15.43 • 453.6)

        PMR *     .000 •   T6ad373. I (15.43 *"«53.6) *      .00

-------
Run No.  3.1
     Sample volume  =  1.75m3f61.88  scf
Example  calculations
     CS  (Part)  =202.0/1.75 = 115.4  mq/m;
     CS (Part)  =  0.001 x202-0 x 15.43^-88  = 0.050 qr/dscf
     CS (S02)   = 1790 / 1.75 = 1022.4a/m3
               =2022.8* 24.06/64  = 384ppm
               =  0.001 x1790 x 15.43/Jit88_
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Sulfur dioxide
Sul f uric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


202.0






70.4
96.2
1790

8.3



3 Concentration,
mg/m


115.4






40.2
55.0
1022.8

4.7



gr/dscf


0.050






0.017
0.024
0.446

0.002



ppm











384

1



                                     A-90

-------
                                                                FIELD  DATA
 I
VD
PLANT REPUBLIC STEEL CLEVELAND, OH
SAMPLING LOCATION NO.l COKE BATTERY
SAMPLE TYPE PART/S02/H2S04
OPERATOR BRUFFEY
AMBIENT TEMP. (DEC. F) 58.
BAR. PRESS. (IN. H6) 29.78
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530087
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .64
THERM. NO.
LEAKAGE .015 CFM 9 4.0 IN.HG
METER CALIB. FACTOR 1.044
READ t RECORD DATA EVERY 10.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY ORIFICE PRESSURE
POINT
NO.

INlt












TIME
(MIN.)

0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
60.0
90.0
100.0
110.0
120.0
TIME
(24-HR
PI flf* tf \
ILUCK J
956 ~
1008
1016
1028
1038
1046
1056
1106
1116
1126
1138
1148
1156
READING
(CU.FT.)

15.19*
20.070
24.910
29.510
34.130
36.750
43.360
47.960
52.600
56.870
61.510
66.180
70.795
HEAD
(IN.H2U)



.065
.065
.060
.060
.060
.060
.060
.060
.050
.060
.060
~ .060
DIFFERENTIAL
(IN.
DES1RCU

.80
.80
.73
.73
.73
.73
.73
.73
.61
.73
.73
.73
H20)
ACTUAL

.60
.80
.73
.73
.73
.73
.73
.73
.61
.73
.73
.73
STACK
TEPP
(DEG.F)


567.
519.
S31.
539.
536.
552.
564.
520.
529.
542.
533.
552.
DATE 10/28/81
HUN NUMBER 3-2
PROBE LENGTH & TYPE a* HEATED GLASS
KUZZLE : l.D. .397
ASSUMED MOISTURE 12.0
SAMPLE BOX NUMBER 0
PETER BOX NUMBER FIO
PETER HEAD DIFF. 1.80
C FACTOR .06
PROBE HEATER SETTING 250.
HEATER BOX SETTING 250.
REFERENCE PRESS. DIFF. .15
DKY GAS METER PUPP SAPPLE IPPINGER
TEMP
(DEG
INLET

57.
58.
61.
63.
6
-------
           PARTICIPATE FIELD DATA ft RESULTS TABULATION

PLANT- NAME AND ADDRESS               TEST TEAM LEADER

REPUBLIC STEEL CLEVELAND* OH          BRUFFEY
TEST
3-2
NO.l COKE BATTERY
ENGLISH UNITS
TEST DATE
TB
TF
TT
NP
V
ON
CP
PM
1 VM
VD
TM
VMSTD
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRV GAS SAMPLED
10/28/81
958
1158
120.
12
1.
.
.
•
55.
62.
58.
0

044
397 IN
84
73 IN-H20
603 CU-FT
0 F
547 SCF
METRIC UNITS
10/28/81
958
1158
120
12
1
10

18
1
16
1
.0

.044
.1
.84
.6
.574
.7
.658



MM

PM-H2U
CU-M
C
SCM
          AT STANDARD CONDITIONS*

VLC       TOTAL H20 COLLECTED IN
          IMPINGERS AND SILICA GEL.ML,

VNC       VOLUME OF MATER VAPOR
          AT STANDARD CONDITIONS*

§Nd       PERCENT MOISTURE BY VOLUME

FMO       MOLE FRACTION DRY GAS

PC02      PERCENT C02 BY VOL.» DRV

P02       PERCENT 02 BY VOX., DRV

PCO       PERCENT CO BY VOL.* DRY

PN2       PERCENT N2 BY VOL.* DRY

Mb        MOLECULAR NT-DRY STACK GAS

MNS       MOLECULAR NT-STACK GAS
                                  ff4.0
                                    7.249 SCF
                                               154.0
                                                  .205 SC*
11.02
.890
2.30
10.90
.00
86.80
28.80
27.61
11.02
.890
2.30
10.90
-.00
86.80
28.80
27.61

-------
PB        BAROMETRIC PRESSURE

PSI       STATIC PRES OF STACK GAS

PS        STACK PRES, ABS.

TS        AVERAGE STACK TEMP

VS        AV6 STACK GAS VELOCITY

AS        STACK AREA

033TO     STACK FLOW RATE* DRY*

OS        ACTUAL STACK FLON RATE

ISO       PERCENT ISOKINETIC

MN        FILTERABLE PART
            M6. EPA 5

CS        FILTERABLE PART

PMR       FILTERABLE PART
            EMISSION RATE

   *  68 OES F,  29.92 IN.H6.
     29.78  IN-HG

     -1.20  IN-H20

     29.69  IN-HG

    540.    F

     19.4   FPS

   7466.   30-IN

1689593.    SCFH

3635039.    ACFH

    104.9

       .0


       .0000 GR/DSCF*

       .000   LB/HR
   756.41   KM-HG

   -30.48   KM-M20

   754.17   CM-MG

   eez.    c

     5.9   KP8

     4.817 SO-M

 47844.    SCMH

102650.    *CMH

   104.5

      .0


      .000 CG/OSCK

       .00  KG/HH

-------
              EXAMPLE PARTICIPATE CALCULATIONS TEST NO.   3-?

                   NO.l COKE BATTERY



        VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

        VMSTO * (17.647 • VM * Y • (PB * PM / 13.6)) / (TM * 460.)

                  17.647 *    55.603 * 1.044 * ( 29.78 *  .732 / 13.6)
        VMSTO «	........	.	 =     58.517  DSCF
                                 (  62. * 460.)



        VOLUME OF MATER VAPOR AT STANDARD CONDITIONS

        VNC » .04707 • VLC

        VWC • .04707 •'  154. «   7.25~SCF



        PERCENT MOISTURE IN STACK GAS

        BMO • (100. • VNC)*/ (VMSTD * VWC)

IP                 100. •   7.25
 I       BHO * ——	.—	 > 11.02 PERCENT
vo                   58.547 »   7.25
>e»



        MOLE FRACTION OF DRY STACK GAS

        FMD « (100. - BNO) / 100.
                  100. •  11.0
        FMD « —.-————.—— s   .890
                       100.
        AVERAGE MOLECULAR WEIGHT OF DRY STACK GAS

        MD » (PC02 * .44) » (P02 * .32) t (PN2 » PCO) * .28

        MO > (  2.30*44/100) «• (10.9*32/100)  » ((86.8* .0) * 28/100 s   28.80



        MOLECULAR HEIGHT OF STACK GAS

        MHS * MO • (1.  • (BNO/100)) * 18. *  (BNO/100)

        MMS =  28.80* (1. -(11.02/100)) * 18. • (11.02/100) s   27.61

-------
       STACK  GAS  VELOCITY  AT  STACK  CONDITIONS

       OtLP « SUM.  OF  THE  SORUVH •  ITS  *  460.))

       VS  * 85.49 *  CP * OELP /  (SORT(MMS  *  PS)  *  PNTS)

       VS  * 05.49 *   .84 *    92.927  /  (30RT( 27.61  *  29.69)   *   12.  =    19.42  FPS



       STACK  GAS  VOLUMETRIC FLON AT  STACK  CONDITIONS

       OS  * VS *  AS  *  3600/144

       OS  »    19.42  *   7466.  3600/144  *    3625039. ACFH




       STACK  GAS  VOLUMETRIC FLON AT  STANDARD CONDITIONS

       OSSTD  « 17.647  • OS *  PS * (17  -  (B»»0/10~0))  /  (TS  * 460.)

                  17.647 *     3625039.  *  29.69 * (1.  •  (11.02/100))
       OSSTD  » —————————— —......................... T     1689592. SCFH
                           ( 540. *  460.)
       PERCENT  ISOKINETIC

 I      ISO •  (30S.5B*(TS«460.))*((0.002669*VLC)«(VM*V*(PB*(PM/13.6))/(TM«460.)))/(TT*VS*PS*ON*ON)
VD

01              (305.58M 540;+460.))*((0.0026697 154.)*(   55.603*1.OOd* ( 29.78*(     .732/13.6))/(   62.+460.)))
       ISO «  —.———.——	..........	..	.....	.	.	.	*  104.51  PEKCtM
                                           120.  •      19.42 •   29.69  •   .397  *   .397




       PAftTtCULATE LOADING — EPA METHOD 5 (AT  STANDARD CONDITIONS)

       CS * 0.001 • MN • 15.43 / VMSTO

       CS * 0.001 *      .0 • 15.43 /    58.547 *      .000 GR/OSCF




       PARTICULATE LBS/HR — EPA METHOD 5

       PMR *  CS • OSSTD / (15.43 * 453.6)

       PMR «     .000 •    1689592. V (15.43 •  453.6)  •       .00

-------
Run No.  3.2
                          o
     Sample  volume =  1.66m .58.55  scf

Example  calculations

     CS  (Part) =156.9/1.66= 94.5  mq/m3

     CS  (Part) = 0.001 x!56.9x 15.43/58.55=  0.041  qr/dscf

     CS  (S02)  =1540/1.66=927.7 ma/m3

              = 927.7 x 24.06/_64_ = 349 ppm

              = 0.001 x1540  x 15.43/58.55  = 0.406 gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2$04
As H2S04.2H20
Sulfur dioxide
Sul f uric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


156.9
34.2





0.0
0.0
1540

8.6



2 Concentration,
mg/m


94.5
20.6





0.0
0.0
927.7

5.2



gr/dscf


0.041
0.009





0.000
0.000
0.406

0.002



ppm











349

1



                                      A-96

-------
                                                               FIELD   OAT»
 I
V£>
-J
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION COKE OVEN OUTLET
SAMPLE TTPE 3-3-M8-350
OPERATOR CLARKE
AMBIENT TEMP. (DEG.F) 58.
BAR. PRESS. (IN. H6) 29.78
STATIC PRESS. UN. HZO) -1.20
FILTER NUMBER(S) 3530080
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM 9 2.0 IN.HG
METER CALIB. FACTOR .992
READ ft RECORD DATA EVERT 10.0
TRAVERSE
POINT
NO.

INIT












SAMPLE
TIME
(MIN.)

0
10.0
20.0
30.0
00.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
CLOCK
TIME
(24-HR
ft nf v I
CLUCKJ
955
1005
1015
1025
1035
1045
1055
1105
1115
1125
1135
1145
ilSS
GAS METER
READING
(CU.FT.)

525.179
530.233
535.270
539.087
544.864
549.778
554.615
559.325
564.660
568.622
573.180
578.160
583.158
MINUTES
VELOCITY
HEAD
(IN.H20)


.065
.060
.060
.070
.060
.060
.060
.060
.050
.060
.060
.060

ORIFICE

PRESSURE
DIFFERENTIAL
(IN.
DESlKfcU

.79
.74
.74
.87
.74
.74
.74
.74
.60
.74
.74
.74
H20)
ACTUAL

.79
.74
.74
.87
.74
.74
.74
.74
.60
.74
.74
.74

STACK
TEKP
(DEG.F)


546.
514.
525.
537.
550.
548.
558.
517.
528.
537.
527.
545.
DATE 10/28/81
RUN NUMBER 3-3
PROBE LENGTH ft TYPE 4* GLASS HEATED
NUZZLE : I.U. .394
ASSUMED KOISTUWE 12.0
SAMPLE BOX NUPBER
PETEH BOX NUMBER FBI
MEIER HEAD OIFF. i.e7
C FACTOR .88
HHOBE HEATER SETTING 350.
HEATER BUX SETTING 350.
HEFEHENCt PBfcSS. DIFF. .15

DKY GAS METER
TtMP
(DEG.F)
INLtT UUTLtT

60. 55.
62. 5b.
66. 56.
69. 50.
71. 58.
72. 58.
74. 60.
76. 60.
77. 62.
76. 62.
76. 63.
76. 62.

PU»»P
VACUUM
(IN.HG)


2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0

SAMPLE
BOX TEMP
(DEG.F)


394.
378.
335.
327.
300.
352.
354.
354.
350.
349.
352.
346.

IMPINGER
TEMP
(DEG.F)


48.
46.
48.
48.
50.
52.
52.
50.
52.
54.
55.
50.
      TOTALS
      AVERAGE
120.0
57.979
                                          .74
                                ,74   536.
71.
59.
2.0   353.
                                                                                                    50.

-------
                  PARTICULATE  FIELD  DATA  S  RESULTS  TABULATION
       PLANT*  NAME AND  ADDRESS               TEST TEAM  LEADER
       REPUBLIC  STEEL CLEVELAND               CLARKE
       TEST
        3-3
COKE OVEN OUTLET
      TEST DATE
 I
VD
00
TB        TIME-START
TF        TIME-FINISH
TT        NET TIME OF TESTt MIN.
NP        NET SAMPLING POINTS
T         METER CALIBRATION FACTOR
ON        SAMPLING NOZZLE DIAMETER
CP        PITOT TUBE COEFFICIENT
PM        AVERAGE ORIFICE PRESSURE
          DROP
VM        VOLUME OF DRT GAS SAMPLED
          AT METER CONDITIONS
TM        AVERAGE GAS METER TEMP
VMSTO     VOLUME OF DRY GAS SAMPLED
          AT STANDARD CONDITIONS*
VLC       TOTAL HZO COLLECTED IN
          IMPINGERS AND SILICA GEL. ML.
VNC       VOLUME OF HATER VAPOR
          AT STANDARD CONDITIONS*
•MO       PERCENT MOISTURE BY VOLUME
FMD       MOLE FRACTION DRY GAS
PC02      PERCENT C02 BY VOL.* DRY
P02       PERCENT 02 BY VOL., DRY
PCO       PERCENT CO BY VOL.. DRY
PN2       PERCENT N2 BY VOL.r DRY
MO        MOLECULAR MT-DRY STACK GAS
MMS       MOLECULAR MT-STACK GAS
ENGLISH UNITS
10/28/81
1155
120.0
12
.992
,39a IN
.84
.74 IN-H20
57.979 CU-FT
65.2 F
57.660 SCF
218.3
10.275 SCF
"15.13
.649
2.30
10.90
.00
86.60
28.60
27.17
METRIC UNITS
10/20/61
955
1155
120.0
12
.992
10.0
.84
18.9
1.642
18.4
1.633
216.3
.291
15.13
.809
2.30
10.90
.00
86.80
26.80
27.17




MM

MM-H20
CU-M
C
SCM

SCM









-------
      PB        BAROMETRIC PRESSURE

      PSI        STATIC PRES OF STACK GAS

      PS        STACK PRES, ABS.

      TS        AVERAGE STACK TEMP

      VS        AVG STACK  GAS VELOCITY

      AS        STACK AREA

      QSSTO      STACK FLOH RATE* DRY*

      OS        ACTUAL STACK FLOM RATE

      ISO        PERCENT ISOKINETIC

      MN        FILTERABLE PART
                  MG. EPA  5

      CS        FILTERABLE PART

      PMR        FILTERABLE PART
                  EMISSION RATE

        *   68  DEG Ff  29.92 IN.HG.
     29.76  IN-HG

     •1.20  IN-H20

     29.69  IN-HG

    536.    F

     19.6   FPS

   7066.   30-IN

1633571.    SCFH

3656571.    ACFH

    106.1

       .0



       .0000 GR/OSCF*

       .000   LB/HR
      .01  KM-HG

   -30.46  MM-H20

   750.17  fM-HG

   280.    C

     6.0   PPS

     0.817 SO-M

 06258.    SOH

103600.    »CMH

   108.1

      .0



      .000 PG/DSCK

       .00  KG/HH
 I
VD
VD

-------
                EXAMPLE PARTICIPATE CALCULATIONS TEST NO.   3-3

                     COKE OVEN OUTLET



          VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

          VMSTD • (17.647 • VM • Y • tPB » PM / 11.6)) /  (TM 4 460.)

                    17.647 *    57.979 *  .992 * ( 29.78  *  .743 /  13.6)
          VMSTO * ———————————— --- ...... — ..... — -      57.660  DSCF
                                   (  65. * 460.)



          VOLUME OF MATER VAPOR AT STANDARD CONDITIONS

          VHC « .04707 * VLC

          VHC « .04707 •  218. «  10728 StF
          PERCENT MOISTURE IN STACK GAS

          BHO • (100. • VMCJ f (VMSTD *

>                   100. •  10.28
1          BHO * —————— z 15.13 PERCENT
                      57.660 *  10.28
          MOLE FRACTION OF DRY STACK GAS

          FMD • (100. - BHO) / 100.

                    100. -  15.1
          FMD • —————— s   .849
                         100.
          AVERAGE MOLECULAR HEIGHT OP DRY STACK GAS

          MO s (PC02 • .44) * (P02 * .32) * (PN2 * PCO) * .28

          MD * ( 2.30*44/100) * (10.9*32/100) » ((86.8* .0) * 28/100 =   28.80



          MOLECULAR HEIGHT OF STACK GAS

          MHS s MD * (1. - (BHO/100)) * 18. * (BHO/100)

          MHS *  28.80* (1. •(15.13/100)) + 18. • (15.13/100) *   27.17

-------
      STACK GAS VELOCITY AT STACK CONDITIONS

      OELP « SUM. OF THE SQRTtVH *  (TS * 460.))

      VS • 05.49 • CP * OELP /  (SORT(MRS * PS) * PNTS)

      VS * 65.49 *  .84 *   93.030  /  (SORT( 27.17 • 29.69)   *   12.  =    19.60 FPS



      STACK GAS VOLUMETRIC FLOW AT  STACK CONDITIONS

      OS * VS * AS • 3600/144

      OS *   19.60 •  7466. 3600/144  *    3658571. ACFH



      STACK GAS VOLUMETRIC FLON AT  STANDARD CONDITIONS

      OSSTD » 17.647 * OS • PS • (1.  • (BMO/100)) / (TS * 460.)

                17.647 *    3658571.  *  29.69 • (1. - (15.13/100))
      OSSTD » ———————————————— — — — =     1633571. SCFH
                         ( 536. » 460.)



>    PERCENT I30KINETIC
 I
|-J    ISO » (305.58*(TS»460.))«((0.002669«VLC)*(VMoY*(PBt(PH/13.6))/(TM*460.)))/(TT*VS*PS«DN*DN)
o                            ...

1-1           (305.58V( 556.*460.))«(tO.002669*  Zi8.)*(   57.97<*« .992*t 29.78*1    .743/13.6))/(  6S.*460.)))
      ISO « ———————————————--—-—..——— — -—— — --—— — — - ———-«---•-•• *  108.09  PERCENT
                                         120. *     19.60 •   29.69 *   .394 *  .394



      PARTICIPATE LOADING -- EPA METHOD 5 (At STANDARD CONDITIONS)

      CS * 0.001 * MN • 15.43 / VMSTD

      CS * 0.001 *      .0 * 15.43  /    57.660 *     .000 GR/DSCF



      PARTICIPATE LBS/HR — EPA METHOD 5

      PMR a CS * OSSTO / (15.43 • 453.6)

      PMR «     .000 •    16J3571.  /  (15.43 * 453.6) =       .00

-------
Run No. 3.3
                          o
     Sample  volume = 1.63 m . 57.66  scf
Example  calculations
     CS  (Part)  =87.3 /1.63=  53.6  ma/m3
     CS  (Part)  =  0.001 x87.3  x 15.43/ 57.66=  0.023 qr/dscf
     CS  (S02)   =1680/1.63=1030.6mg/m3
               =1030.6X  24.06/64  = 387 ppm
               =  0.001 x1680  x 15.43/57.66  = 0.450  gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
87.3
25.3
34.6
1680
67.2



2 Concentration,
mg/m
53.6
15.5
21.2
1030.7
41.2



gr/dscf
0.023
0.007
0.009
0.450
0.018



ppm


387
10



                                      A-102

-------
                                                              FIELD  DAT*
O
U)
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION COKE OVEN OUTLET
SAMPLE TYPE 3-4-M8-350
OPERATOR CLARKE
AMBIENT TEMP.(OEG.F) 58.
BAR. PRESS. (IN. HG) 29.78
STATIC PRESS. UN. H20) -1.20
FILTER NUMBER(S) 3530046
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM a 2.0 IN.HG
METER CALIB. FACTOR 1.010
READ * RECORD DATA EVERY 10.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY ORIFICE PRESSUHE
POINT
NO.

INIT












TIME
(MIN.)

0
10.0
20.0
30.0
40.0
SO.O
60.0
70.0
80.0
90.0
100.0
110.0
120.0
TIME
(24-HR

9S8
1008
1018
1028
1038
1048
1058
1108
1118
1128
1138
1148
1158
READING
(CU.FT.)

950.042
954.880
959.555
964.200
968.911
973.615
978.290
982.900
987.697
992.074
996.815
1.270
6.194
HEAD
(IN.H20)


.065
.065
.060
.060
.060
~ .060
.060
.060
.050
.060
.060
.060
DIFFERENTIAL
(IN.
DESIRED

.79
.79
.74
.74
.74
.74
.74
.74
.60
.74
.74
.74
H20)
ACTUAL

.79
.79
.74
.74
.74
.74
.74
.74
.60
.74
.74
.74
STACK
TEMP
(DEG.F)


567.
519.
531.
539.
537.
552.
564.
520.
526.
540.
532.
552.
DATE 10/28/81
HUN NUMBER 3-4
PROBE LENGTH ft TYPE 5 FT GLASS HEA1EO
NOZZLE I 1.0. .397
ASSUMED MOISTURE 12.0
SAMPLE BOX NUMBER
KETEH BOX NUMBER FB5
METER HEAD OIFF. 1.86
c FACTOR .88
PHOBE HEATER SETTING 350.
HEATER BUX SETTING 350.
REFERENCE PRESS. OIFF. .15
DRY GAS METER PUMP SAMPLE IMPINGER
TEMP VACUUM
(OEG
INLET

66.
67.
72.
73.
77.
80.
82.
04.
85.
66.
65.
86.
.F) (IN.Hb)
OUTLET

64.
64.
66.
67.
69.
72.
73.
74.
76.
77.
78.
78.
.0
.0
.0
.0
.U
.0
.0
.0
.0
.0
.0
.0
BOX TEMP
(DEG.F)


284.
322.
328.
314.
337.
349.
353.
341.
348.
356.
344.
354.
TEMP
(DEG.F)


40.
38.
40.
40.
40.
40.
42.
42.
46.
44.
44.
46.
     TOTALS
     AVERAGE
120.0
56.152
                                         .74
                                .74   540,
79,
72,
1.0
336.
42.

-------
           PARTICIPATE FIELD DATA A RESULTS TABULATION
PLANT- NAME AND ADDRESS               TEST TEAM LEADEN
REPUBLIC STEEL CLEVELAND              CLARKE
TEST
3-4
COKE OVEN OUTLET


TEST DATE
TB
TF
TT
NP
Y
ON
CP
PM
> VM
I—1
0 TM
VMSTO
VLC
VNC
BNO
FMD
PC02
P02
PCO
PN2
MO
MNS
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL M20 COLLECfEO IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF MATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL., DRY
PERCENT 02 BY VOL.^ DRY
PERCENT CO BY VOL.* DRY
PERCENT N2 BY VOL.* DRY
MOLECULAR NT-DRY STACK GAS
MOLECULAR MT-STACK GAS
ENGLISH UNITS
10/28/81
938
1158
120.0
12
1.010
.397 IN
._. •8fl
,74 IN-H20
56.152 CU-FT
75.0 F
55.806 SCF
ifri.9
7.621 SCF
12.01
.880
2.30
10.90
.00
86.80
28.80
27.51
METRIC UNITS
10/28/81
9b8
Ilb8
120.0
12
1.010
10.1
.ea
18.7
1.590
23.9
1.580
161.9
.216
12.01
.880
2.30
10.90
.00
86.80
28.80
27.51



KM

MM-H2U
CU-M
C
SCH

SCf









-------
    PB        BAROMETRIC PRESSURE


    PSI       STATIC PRES OF STACK CAS


    PS        STACK PRES, ABS.


    TS        AVERAGE STACK TEMP


    VS        AV6 STACK 6AS VELOCITY


    AS        STACK AREA


    OSSTO     STACK FLOW RATE* DRY*


    OS        ACTUAL STACK FLOM RATE


    ISO       PERCENT ISOKINETIC


    MN        FILTERABLE PART
                M6. EPA 5


    CS        FILTERABLE PART


    PMR       FILTERABLE PART
                EMISSION RATE


       *  68 DEG F,  29.92 iN.HG.
     29.76  IN-MG


     -1.20  IM-H20


     29.69  IN-HG


    540.    F


     19.5   FPS


   7466.   30-IN


1674132.    SCFH


3631694.    ACFH


    100.5


       .0




       .0000 GR/OSCF*


       .000   LB/HR
   756.ai  *M-HG


   -30.46  HH-H20


   754.17  »H-HG


   282.    C


     5.9   »P3


     4.617 SO-M


 47406.    SCf'H


102639.    ACCH


   100.5


      .0




      .000 KG/DSC*'


       .00  KG/HK
 I
\->
o

-------
>
 I..
             EXAMPLE  PARTICIPATE  CALCULATIONS TEST NO.   3-4

                  COKE  OVEN  OUTLET



       VOLUME OF  DRV  GAS  SAMPLED  AT  STANDARD CONDITIONS

       VMSTD  • (17.647  •  VM  •  T • IPB * PM  / 13.6)) / (TM + 460.)

                 17.647 *   56.152  • 1.010 * ( 29.78 »  .737 / 13.6)
       VMSTD  « ————————— --- ....... ------------------ -     55.B06 OSCF
                               (  75. * 460.)



       VOLUME OF  WATER  VAPOR AT STANDARD CONDITIONS

       VMC •  .04707 • VLC

       VHC •  ".04707 *   i62.  «   7.62 SCF



       PERCENT MOISTURE IN STACK  GAS

       BHO «  (100. «~  VWCi /"(VMSTO «~V»»C)      ~~~
                 100. *   7.62
      BMO * ———————  *  12.01  PERCENT
                  55.806 *   7.62
o
^     MOLE FRACTION OF DRT STACK GAS

      FMD »  (100. - BHO) / 100.

                 100. -   12.0
      FMD «  ————— *    .esc
                     100.
      AVERAGE MOLECULAR WEIGHT  OF  DRY  STACK  6(51

      MD *  (PC02 *  .44) +  (P02  • .32)  +  (PN2 * PCO)  *  .28

      MD *  ( 2.30*44/100)  •  (10.9*32/100)  *  ((86.6*  .0)  • 28/100 =   28.60



      MOLECULAR HEIGHT OF  STACK GAS

      MMS » MD * (1. - (BNO/100))  *  18.  *  (BNO/100)

      MMS »  28.80*  (1. -(12.01/100))  »  18.  * (12.01/100) s   27.51

-------
       STACK GAS VELOCITY AT STACK CONDITIONS

       DELP » SUM. OF THE SQRT(VH * (TS * 460.if

       VS « 65.49 • CP • OELP / (SORT(MMS • PS)  * PNTS)

       VS • 85.49 *  .84 *   92.915 / (SORT( 27.51 * 29.69)   •  12. =   19.46 FPS



       STACK 6A8 VOLUMETRIC FLO* AT STACK CONDITIONS

       OS • VS * AS * 3600/144

       OS *   19.46 *  7466. 3600/144 •    3631694. ACFH



       STACK GAS VOLUMETRIC FLOM AT STANDARD CONDITIONS

       OSSTD « 17.64? • OS • PS * (1. • (BMO/106)) / (TS * 460.)

                 17.647 •    3631694. *  29.69 * (1. • (12.01/100))
       OSSTO • ——«	.....	....	...	r    167«13*.  SCFM
                          ( 540. * 460.)



       PERCENT ISOKINETIC

.       ISO * (305.58*(TS*460.))*((0.002669*VLC)*(VM*T*(PB*(PM/13.6))/(TM»460.)))/ I TT*V3*PS*DN*DN)
I>
M             (305.58*( 540.M60.))*((0.002669*   162.)*(   56.152*1.010*(  29.78»(    .737/13.6))/(   75.4460.)))
O      ISO » ———-—..-.—.——.—...——.—.———............................................... c 100.54 PERCENT
"^                                         120. •     19.46 *   29.69 •   .397  *   .397



       PARTtCULATE LOADING"-- EPA METHOD  5 UT'STANOARD  CONDITIONS)

       CS « 0.001 * MN • 15.43 / VMSTD

       CS • 0.001 *      .0 * 15.43 /    55.806  *     .000 GR/DSCF



       PARTICULATE LBS/HR — EPA METHOD 5

       PMR B CS * OSSTD / (15.43 « 453.6)

       PMR *     .000 •    1674132. / (15.43 * 453.6)  =       .00

-------
Run No.   3.4
                          o
     Sample  volume =  1.58m t 55.81  scf
Example  calculations
     CS  (Part) =40.3  /1.58= 25.5  mq/m3
     CS  (Part) = 0.001 x40.3  x 15.43/65.81  =0.011   qr/dscf
     CS  (S02)  =1620/1.58= 1025ma/m3
              = 1025  x 24.06/64  =385 ppm
              = 0.001 x1620  x 15.43/55.81  =0.448  gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Sulfur dioxide
Sulfuric acid mist
As H2$04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg

40.3






3,7
5.0
1620

89.2



3 Concentration,
mg/m

25.5






2.3
3.2
1025.3

56.4



gr/dscf

0.011






0.001
0.001
0.448

0.025



ppm










385

14



                                       A-108

-------
                                                              FIELD   DATA
 I
M
O
PLANT REPUBLIC STEEL
SAMPLING LOCATION COKE STACK
SAMPLE TYPE METHOD 5-250
OPERATOR 00/MP
AMBIENT TEMP.(DEG.F) 55.
BAR. PRESS. (IN. H6) 29.78
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530058
STACK INSIDE DIM. (IN) 47.50 .00
PITOT TUBE COEFF. .ea
THERM. NO.
LEAKAGE .012 CFM 9 9.
METER CALIB. FACTOR 1.033
READ * RECORD DATA EVERT 10.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY
POINT TIME
NO. (MIN.


INIT 0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.6
TOTALS 120.0
TIME
) (24-HR
<*• nr*H i
LLUCKI

947
957
1007
1017
1027
1037
~1047
1057
1107
1117
1127
1137
~ U4f

READING
(CU.FT.)


719.921
724.750
729.570
734.430
739.300
744.250
749.140
754.100
759.070
764.050
769.030
774.000
7?9.017
59.096
HEAD
(IN.H20)



.075
.075
.075
.075
.075
~,075
.075
.075
.075
.075
.075
~.0?S

CLEVELAND
3 IN.HG
ORIFICE
PRESSURE
DIFFERENTIAL
(IN.
DESIRED


.77
.77
.77
.77
.77
~ .77
.77
.77
.77
.77
.77
.77

H20)
ACTUAL

.77
.77
.77
.77
.77
.77
.77
.77
.77
.77
.77
.77

STACK
TEKP
(OEG.F)


518.
518.
518.
518.
518.
518.
518.
518.
518.
518.
518.
518.

DATE 10/28/81
HUN NUMBER 3-5
PROBE LENGTH S TYPE 6* GLASS
NUZZLE 6-1051 I.D. .374
ASSUMED MOISTURE 11.0
SAMPLE BOX NUMBER
PETER BOX NUMBER FB4
PETER HMD D1FF. 1.88
C FACTOR .92
PROBE HEATER SETTING 250.
HEATER BOX SETTING 250.
REFERENCE PRESS. DIFF. .is
DRY GAS METER PUMP SAMPLE IMPINGER
TEMP
(DEG
INLET

60.
61.
61.
69.
M.
73.
75.
76.
75.
75.
75.
75.

.F)
OUTLET

59.
59.
60.
62.
63.
65.
67.
68.
66.
69.
69.
69.

VACUUM
(IN.HG)


7.4
7.7
7.9
8.1
8.2
.5
.7
.8
.8
.8
.8
.9

BOX TEMP
(OEG.F)


226.
230.
234.
241.
227.
228.
225.
226.
228.
225.
230.
227.

TEMP
(DEG.F)


36.
36.
38.
36.
38.
38.
40.
40.
00.
38.
40.
40.

     AVERAGE
.77
.77   518.
71.
65.
6.4   229.
39,

-------
 I-
\->

o
                 PARTICIPATE FIELD DATA  ft  RESULTS  TABULATION


      PLANT- NAME AND ADDRESS                TEST fEAM  LEADER


      REPUBLIC STEEL CLEVELAND               DO/HP
      TEST
3-5
COKE STACK


TEST DATE
TB
TF
TT
NP
Y
ON
CP
PM
VM
TM
VMSTO
VLC
VHC
BNO
FMD
PC02
P02
PCO
PN2
MD
MNS
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H26 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF MATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL.. DRY
PERCENT 02 BY VOL. V OR V
PERCENT CO BY VOL.* DRY
PERCENT N2 BY VOL.* DRY
MOLECULAR MT-ORY STACK GAS
MOLECULAR NT-STACK GAS
ENGLISH UNITS
10/28/81
947
1147
120.0
12
1.033
.374 IN
.64
.77 IN-H20
59.096 CU-FT
67.8 f
60.900 SCF
189.7
8.506 SCF
T2.25
.877
2.30
HJi90
.00
86.80
28.60
27.48
METRIC UNITS
10/28/81
947
1147
1?0.0
12
1.033
9.5
.64
19.6
1.673
19.9
1.724
180.7
.241
12.25
.877
2.30
10.90
.00
86.80
28.80
27.48



CM
KM-H20
CU-M
C
sew

SCK









-------
    PB        BAROMETRIC PRESSURE

    PSI       STATIC PRES OF STACK GAS

    PS        STACK PRES, ABS.

    T8        AVERAGE STACK TEMP

    VS        AVG STACK GAS VELOCITY

    AS        STACK AREA

    OSSTD     STACK FLON RATE, DRY*

    OS        ACTUAL STACK FLON RATE

    ISO       PERCENT ISOKINETIC

    MN        FILTERABLE PART
                M6. EPA 5 _		

    CS        FILTERABLE PART

    PMR       FILTERABLE PART
                EMISSION RATE

       •  68 OE6i'F»  29,92 IN.H6.
 29.78  IN-HG

 -1.20  IN-M20

 29.69  IN-HG

518.    F

 21.5   FPS

       30-IN

        SCFH

        ACFH
   7466.

1889290.

4018903.

    109.5

       .0
       .0000 GR/OSCF*

       .000   LB/HH
   756.ai  MH-MG

   -30.48  MM-H20

   750.17  KM-HG

   270.    C

     6.6   I" PS

     4.817 30-M

 53499.    3CWH

113803.    *C*M

   109.5

      .0


      .000 NG/DSO

       .00  KG/HR
>
 I

-------
      EXAMPLE PARTICIPATE CALCULATIONS TEST NO.    3-5

           COKE STACK



VOLUME OF DRY 6A3 SAMPLED AT STANDARD CONDITIONS

VMSTO* (17.647 • VW •" Y •  IPB * PM / 13~.6>)  /  (TM  » 060.)

          17.647 •    59.096 * 1.033 • ( 29.78  *   .770  /  13.6)
VMSTD * ——————— — —.....................  =      60.900 D3CF
                         (  60. » 460.)



VOLUME OF WATER VAPOR AT STANDARD CONDITIONS

VMC » .04707 * VLC

VNC « .04707 •  181. »  ~ 8.51 SCF



PERCENT MOISTURE IN STACK GAS

BNO » (100. • VHCl / (VMSTD * VHC)

          100. *   a.si
BNO « —————————— * 12.25 PERCENT
            60.900 *   8.51
    ,.      .     	....      .          	.„


MOLE FRACTION OF DRY STACK GAS

FMD » (100. - BMO) / 100.

          100. -  12.I
FMD * —————	c   .877
               100.



AVERAGE MOLECULAR WEIGHT OF DRY STACK Stf

MD * (PC02 * .44)  * (P02 *  .32) + (PN2 * PCD) * .28

MD * ( 2.30*44/100) • (10.9*32/100) * ((86.8* .0)  * 28/100  *   28.80



MOLECULAR HEIGHT OF STACK GAS

MNS * MD • (1. • (BMO/100)) + 18. * (BHO/100)

MHS a  28.80* (1.  -(12.25/100)) * 18. * (12.25/100) «   27.48

-------
      STACK GAS VELOCITY AT STACK CONDITIONS

      DELP « SUM. OF THE SQRTIVM •  ITS * 460.))

      VS a 65.49 • CP • OELP / (SORT(MHS • PS) * PNTS)

      VS s 85.49 *  .84 •  102.770  /  (SORTl 27.48 » 29.69)  *   12. =   21.53 FPS



      STACK GAS VOLUMETRIC FLO" AT  STACK CONDITIONS

      OS z VS * AS * 3600/144

      OS 3   21.53 •  7466. 3600/144  a    4018903. ACFH



      STACK GAS VOLUMETRIC FLON AT  STANDARD CONDITIONS

      OSSTO • IT.647 • OS • PS * (1.  - (BMO/lOO)) / (TS * 460.)

                17.647 *    4018903.  •  29.69 * (1. - (12.25/100))
      OSSTD « ————————..———.— ——	 =    1689290. SCFH
                         ( 518. * 460.)



      PERCENT ISOKINETIC

>     ISO a (305.58*(TS»460.))*((0.002669*VLCmVM*Y*(PB«(PM/13.6))/{TM»460.)))/(TT*VS*PS*DN*DN)
 I
I-1            (30b.58*( SlB.+460.))*((6.002669* ~ iel.)*(   59.096*1.033*( 29.78*1    .770/13.6))/(  68.+460.)))
f"J     ISO «	——————	—	..	....	.	— •  109.54  PERCENT
                                         120. •     21.53 *   29.69 *  .374 *  .374



      PARTICIPATE LOADING— EPA METHOD 5 (AT STANDARD CONDITIONS)

      CS a 0.001 * MN * 15.43 / VMSTD

      C3 a 0.001 •      .0 * 15.43 /    60.900 a     .000 GR/DSCF



      PARTICULATE LBS/HR — EPA METHOD 5

      PMR a CS * OSSTD / (15.43 * 453.6)

      PMR «     .000 *   "1889290. /  (15.43 * 455.6) s      .00

-------
Run No.  3-5
     Sample volume  =  1.72 m3. 60.90 Scf
Example  calculations
     CS  (Part)  =171.2/1.72=  99.5  mq/m3
     CS  (Part)  =  0.001  x171.2 x 15.43/60.90=0.043   qr/dscf
     CS  (S02)   =	/	=	mg/m3
               =	 x 24.06/	=	ppm
               =  0.001  x	x 15.43/	=	gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Sulfur dioxide

Sulfuric acid mist
As H2S04
As H2S04-2H20
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


171.2
29.0
26.8
26.2
25.2
22.0

0.0
0.0





99.1
3.2
77.3
- Concentration,
mg/m


99.5
16.9
15.6
15.2
14.6
12.8

0.0
0.0





57.6
1.9
44.9
gr/dscf


0.043
0.007
0.007
0.007
0.006
0.006

0.0
0.0

1



0.025
0.001
0.020
ppm



















                                       A-114

-------
                                                             FIELD  DATA
Cn
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION COKE STACK
SAMPLE TYPE METHOD 8-600
OPERATOR DO/HP
AMBIENT TEMP.(DEG.F) 55.
BAR. PRESS. (IN. HG) 39.78
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530025
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM 9 12.0 IN.HG
METER CALIB. FACTOR .962
READ > RECORD DATA EVERY 10.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY ORIFICE PRESSURE STACK
POINT TIME TIME READING HEAD DIFFERENTIAL T£f»P
NO. (MIN.) (24-HR (CU.FT.) (IN.H20) (IN.H2U) (DEG.F)

INif 0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
SO.O
90.0
100.0
110. 0
120.0
vuuvn f
950
1000
1010
1020
1030
1040
1050
1100
1110
1120
1130
1140
1150
DESIRED ACTUAL
203.451
208.690
214.260
219.700
225.150
230.620
236.040
241.550
247.000
252.490
257.960
263.460
266.908

.075
.075
.075
.075
.075
.075
.075
.075
.075
.075
.075
.075

4.72
4.72
4.72
4.72
.72
.72
.72
.72
.72
.72
.72
.72
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00

518.
518.
516.
516.
516.
518.
518.
518.
518.
518.
516.
516.
DATE 10/26/81
HUN NUMBER 3-6
PHOBE LENGTH S TYRE 4* OUAHTZ
NUZZLE : I.U. .590
ASSUMED MOISTURE 11.0
SAMPLE BOX NUMBER
PETER BOX NUMBER FB8
PETER HtAD OIFF. 1.91
C FACTOk .94
PROBE HEATEH SETTING 600.
HEATER BOX SETTING 600.
REFERENCE PRESS. OIFF. .03
DHY GAS METER PUPP SAMPLE IMPINbEK
TEMP VACUUM BOX TEMP TEMP
(DEG.F) (IN.HG) IDEG.F) (OEG.F)
INLET OUTLET

54.
56.
60.
64.
66.
68.
69.
69.
69.
69.
70.
70.

52.
52.
53.
54.
55.
57.
56.
59.
59.
6U.
61.
61.

4.0
4.0
4.2
4.2
4.3
6.2
6.6
9.3
9.3
9.4
9.6
11.2

577.
556.
553.
526.
580.
538.
565.
574.
576.
565.
566.
537.

34.
3«.
36.
40.
38.
34.
38.
40.
40.
40.
42.
42.
    TOTALS
    AVERAGE
120.0
65.457
                                        4.72
1.00
                                     518.
65,
57.
7.0
560.
38.

-------
           PARTICIPATE FIELD DATA ft RESULTS TABULATION

PLANT- NAME AND ADDRESS               TEST TEAM LEADER

REPUBLIC STEEL CLEVELAND              DO/MP
TEST
3-6
COKE STACK

TEST 0
TB
TF
TT
NP
V
ON
CP
PM

ATE
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
ENGLISH UNITS METRIC UNITS
10/28/81 10/28/61
950 950
1150 1150
120.0 120.0
12 12
.982 .982
.590 IN 15.0 **
•8fl •»
-------
     PB        BAROMETRIC PRESSURE



     P9I       STATIC PRES OF STACK GAS



     PS        STACK PRES, ABS.




     T3        AVERAGE STACK TEMP



     VS        AVG STACK GAS VELOCITY




     AS        STACK AREA




     OSSTD     STACK FLOW RATE, DRY*




     OS        ACTUAL STACK FLOW RATE




     ISO       PERCENT ISOKINETIC



     MN        FILTERABLE PART

                 MG. EPA 5




     CS        FILTERABLE PART



     PMR       FILTERABLE PART

                 EMISSION RATE



        •   68  OE6 F,  29.92 iN.HG.
     29.78  1N-HG




     -1.20  IN-M20



     29.69  IN-HG



    518.    F



     21.8   FPS




   7466.   SQ-IN



1790817.    SCFH
4063123.




     49.6



       .0
ACFH
       .0000 GR/OSCF*




       .000   LB/HR
   756.41  VM-HG




   -30.18  *M-M2U




   754.17  KM-HG




   270.    C




     6.6   VPS




     4.817 SO-M




 50694.    SCKH




115055.    ACMH




    49.6




      .0






      .000 PG/DSCf




       .00  KG/HH
>
I

-------
           EXAMPLE PARTICULATE CALCULATIONS TEST NO.   3-6

                COKE STACK



     VOLUME OF ORT GAS SAMPLED AT STANDARD CONDITIONS

     VMSTO • (17.647 • VM * V * (PB * PM / 13.6)) / (TM * 460.)

               17.647 *    65.457 •  .902 • ( 29.78 » 1.000 / 13.6)
     VMSTD • ———————————............—........... -     64.S92  OSCF
                              (  61. » 460.)



     VOLUME OF HATER VAPOR AT STANDARD CONDITIONS

     VNC » .04707 • VLC

     VNC * .04707 *  29$. *  14.04 SCF




     PERCENT MOISTURE IN STACK GAS

     BHO * (100. * VMC) / (VMSTD * VHC)     ~'~
>          ...

 '              100. *  14.04
\L   BMO « —.——.....—......... a 17.76 PERCENT
00               64.992 *  14.04
     MOLE FRACTION OF DRY STACK GAS

     FMD « (100. - 8NO)  / 100.

               100. -~ 17.8
     FMD « ————.———. *   .822
                    100.




     AVERAGE MOLECULAR WEIGHT of DRY STACK GAS

     MO * (PC02 • .44) * (P02 • .32) * (PN2 * PCO) • .28

     MO * ( 2.30*44/100) * (10.9*32/100) * 1(86.8* .0) * 28/100 =   28.80




     MOLECULAR HEIGHT OF STACK GAS

     MNS * MO » (1. - (BNO/100)) * 18. * (BWO/100)

     MNS *  28.80* (1. -(17.76/100)) + 16. • (17.76/100) *   26.89

-------
      STACK GAS VELOCITY AT STACK CONDITIONS

      DELP » SUM. OF THE SORTCVH * ITS * 060.))

      VS * 85.09 • CP • OELP / (SORT(MRS • PS) * PNTS)

      VS * 85.49 •  .84 •  102.770 / (SORT( 26.89 • 29.69)  *  12. =   21.77 FPS



      STACK GAS VOLUMETRIC FLO* AT STACK CONDITIONS

      OS * VS • AS * 3600/144

      OS •   21.77 *  7466. 3600/144 •    4063123. ACFH



      STACK GAS VOLUMETRIC FLON AT STANDARD CONDITIONS

      QSSTD • 17.607 • OS • PS * (1. • (BMO/10~6)) / (TS » 460.)

                17.647 *    4063123. *  29.69 • (1. - (17.76/100))
      OSSTO « —	——~	——	—	s    1790217. SCFH
                         ( 518. » 060.)



      PERCENT ISOKINETIC

jL     ISO « (305.58MTS»460.))«((0.002669«VLC)*(VM«Y*(PB*(PM/13.6))/(TM««60.)))/(TT*VS«PS«DN«DN)
M
^            (305.58*( S18.+460.))*((0.002669*  Z98.)«(   65.057* .982*( 29.78»(   1.000/13.6))/(  61,»060.)))
      ISO • —.—.—————————————.—— — — —————— ———— — — — — — 8  49.58 PERCENT
                                         120. •     21.77 •   29.69 *  .590 *  .590



      PARTICULATE LOADING — EPA METHOD 5 (AT STANDARD CONDITIONS)

      CS * 0.001 * MN * 15.43 / VMSTD

      CS > 0.001 *      .0 • 15.43 /    64.992 «     .000 GR/OSCF



      PARTICULATE LBS/HR — EPA METHOD 5

      PMR « CS • QSSTD / (15.43 • 453.6)

      PMR 8     .000 *    1790217. / (15.43 * 453.6)  *      .00

-------
Run No. 3.6
                          Q
     Sample  volume =1.84  m r 64.99 scf


Example  calculations

     CS  (Part) =36.0/1.84=19.6   mq/m3


     CS  (Part) = 0.001 x36.0  x 15.43/64.99= 0.008  qr/dscf

     CS  (S02)  =1720/1.84=935   mg/m3

              = 935   x 24.06/64  =351 ppm


              = 0.001 x!720  x 15.43/64.99  =0.408  gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


36.0






4.2
5.7
1720

164



., Concentration,
mg/m


19.6






2.3
3.1
935

89.1



gr/dscf


0.008






0.001
0.001
0.408

0.039



ppm











351

22



                                    A-120

-------
                                                             FIELD  DATA
>
I-1
PLANT
SAMPLING LOCATION
SAMPLE TYPE
OPERATOR
REPUBLIC STEEL CLEVELAND
NO.l COKE BATTERY OUTLET
PART/H2S04/S02
BHUFFEY
AMBIENT TEMP.(OEG.F) 56.
BAR. PRESS. (IN. H6) 39.81
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530039
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .64
THERM. NO.
LEAKAGE .Ota CFM 9 17.
METER CALIB. FACTOR 1.003
READ « RECORD DATA EVERT 10.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY
POINT
NO.

INlf







TIME
(MIN.)

0
10.0
20.0
30.0
40.0
50.0
60.0
62.0
TIME
(24-HR
* f*l Of* tf %
CLUCKJ
1540
1550
1600
1610
1620
1630
1704
1716
READING
ICU.FT.)

638.776
643.860
646.930
654.010
659.090
664.160
669.540
673.150
HEAD
(IN.H20)


.060
.060
.060
.060
.060
.070
.030
0 IN.HG
ORIFICE
PRESSURE
DIFFERENTIAL
(IN.
UESIREU

.73
.73
.73
.73
.73
.87
.37
H20)
ACTUAL

.73
.73
.73
.73
.73
.87
.37
STACK
TEPP
(DtG.F)


543.
556.
515.
519.
529.
514.
511.
DATE 10/28/81
NUN NUMBER 4-1
PROBE LENGTH S TYPE 5* HEATED GLASS
MUZZLE : I.D. .397
ASSUMED MOISTUKE 12.0
SAKPLE BOX NUMBER 01
PETER BOX NUMBER FB2
PETER MEAD UIFF. 1.76
C FACTOR .86
PROBE HEATER SETTING 250.
HEATER BUX SETTING 250.
REFERENCE PRESS. DIFF. .15
DRY GAS METER PUMP SAMPLE IPPINGEK
TEMP
(DEC
If^LEf

60.
62.
65.
66.
66.
b6.
64.
.F)
OUTLET

60.
6V.
61.
60.
60.
61.
60.
VACUUM
(IN.HG)


2.0
2.0
2.0
4.0
3.0
3.0
8.0
BOX TEMP
(DEG.F)


255.
264.
252.
261.
241.
255.
246.
TEMP
(DEG.F)


47.
48.
4«.
42.
46.
47.
0.
    TOTALS
    AVERAGE
62.0
34.374
                                         ,70
                                .70    527,
64.
60.
3.4   254.
39.

-------
                PARTICIPATE FIELD DATA a RESULTS TABULATION
     PLANT" NAME AND ADDRESS               TEST TEAM LEADER
     REPUBLIC STEEL CLEVELAND              BRUFFEY
     TEST
        4-1
NO.I COKE BATTERY OUTLET
to
ENGLISH UNITS
TEST
TB
TF
TT
NP
V
ON
CP
PM
DATE
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
10/28/61
1540
1716
62
7
1



.0

.003
.397 IN
.84
.70 IN-H20
METRIC UNITS
10/28/81
1540
1716
62
7
1
10

17
.0

.003
.1
.84
.7



KM

MM-
          DROP
VM        VOLUME OF DRY GAS SAMPLED
          AT METER CONDITIONS
TM        AVERAGE GAS METER TEMP
VMSTD     VOLUME OF DRV GAS SAMPLED
          AT STANDARD CONDITIONS*
VLC       TOTAL H26 COLLECTED IN
          IMPINGERS AND SILICA GEL,ML.
VNC       VOLUME OF HATER VAPOR
          AT STANDARD CONDITIONS*
BHO       PERCENT MOISTURE BY VOLUME
FMD       MOLE FRACTION DRY GAS
PC02      PERCENT C02 BY VOL.* DRV
P02       PERCENT 02 BY VOL., DRY
PCO       PERCENT CO BY VOL., DRV
PN2       PERCENT N2 BY VOL., DRY
MD        MOLECULAR HT-DHY STACK GAS
MHS       MOLECULAR MT-STACK GAS
                                                34.374 CU-FT
                                                  .973 CU-M
62.4 F
34.761 SCF
IM.I
5.641 SCF
14.38
.656
4.10
11.00
.00
84.90
29.10
27.50
16

124

14

4
11

84
29
27
.9 C
.985 SCM
.1
.165 SCC
.38
.856
.10
.00
.00
.90
.10
.50

-------
     PB        BAROMETRIC PRESSURE

     PSI       STATIC PRES OF STACK GAS

     PS        STACK  PRES, ABS.

     TS        AVERA6E STACK TEMP

     V3        AV6 STACK GAS VELOCITY

     AS        STACK  AREA

     OSSTO     STACK  FLON RATEr  ORT*

     OS        ACTUAL STACK  FLON RATE

     ISO       PERCENT ISOKINETIC

     MN        FILTERABLE PART
                 M6.  EPA 5

     CS        FILTERABLE PART

     PMR       FILTERABLE PART
                 EMISSION RATE

        *   68  DEC F,   29.92  IN.HG.
     89.81  1N-HG

     -1.80  IN-HZO

     29.72  IN-HG

    527.    F

     18.7   FPS

   7466.   SO-IN

1592300.    SCFH
3098600.

    127.5

       .0
ACFM
       .0000 GR/D8CF*

       .000   LB/HR
  757.17  *M-HG

  -30.08  VM-M20

  750.93  *M-HG

  275.    C

    5.7   KP3

    0.817 SO-M

05089.    SCKH

99070.    ACMH

  187.5

     .0


     .000 PG/OSCI"

      .00  KG/HR
to
u>

-------
           EXAMPLE PARTICULATE CALCULATIONS TEST NO.   4-1

                NO.l COKE BATTERY OUTLET



     VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

     VMSTD * (17.647 * VM * Y * (PB * PM / 13.6)) /  (TM * 460.)

               17.647 •    34.374 • 1.003 * ( 29.81  «•  .699 /  13.6)
     VMSTD » —————— — —————	............	i      31.781  DSCF
                              (  62. * 460.)



     VOLUME OF MATER VAPOR AT STANDARD CONDITIONS

     VMC • .04707 * VLC

     VMC • .04707 •  124. a   5.84 SCF



     PERCENT MOISTURE IN STACK GAS

     BMO » (100. * VMC) / (VMSTD + VMC)

               100. *   5.84
>    BMO «	—.——	....... s 14.38 PERCENT
^                34.781 «•   5.84



     MOLE FRACTION OF DRY STACK GAS

     FMD • (100. • BMO) / 100.

               100. -  14.4
     FMD « —————— s   .856
                    100.



     AVERAGE MOLECULAR HEIGHT OF DRY STACK GAS

     MD * (PC02 * .44) * (P02 * .32) * (PN2 * PCO) • .28

     MO » ( 4.10*44/100) * (11.0*32/100) * ((84.9* .0) * 20/100 =   29.10



     MOLECULAR HEIGHT OF STACK GAS

     MMS s MD * (1. - (8MO/100)) * 18. * (BMO/100)

     MMS »  29.10* (1. -(14.38/100)) + 18. * (14.38/100) «   27.50

-------
     STACK  GAS  VELOCITY  AT  STACK  CONDITIONS

     OELP * SUM.  OF  THE  SORT(VH • (TS  *  460.))

     VS = 85.49 * CP • OELP /  (SORT(M*S  •  PS)  *  PNTS)

     VS = 85.09 *  .84 •    52.236 /  (SORT( 27.50 *  29.72)   *    7.  =    18.74  FPS



     STACK  GAS  VOLUMETRIC FLO* AT STACK  CONDITIONS

     OS « VS *  AS *  3600/144

     OS *    18.74 *   7466.  3600/144  •    3498604. ACFH



     STACK  GAS  VOLUMETRIC FLOM AT STANDARD CONDITIONS

     OSSTD  • 17.647  * OS *  PS * (1.  -  (BNO/IOO))  /  (tS  » 460.)

               17.647 •     3498604.  *  29.72 *  (1.  »  (14.38/100))
     OSSTD  • ————————. ——————- — — ----	 x     1592304. SCFH
                        I 527. *  460.)



>    PERCENT ISOKINETIC

£    ISO »  (305.58*(TS»460.))»((0.002669«VLC)*(VM«YMPB+(PM/13.6))/(TM*460.)))/(TT*VS«P9*DN*DN)
Ui
            (305.58M 527.+460.))*((0.002669*   124.)»(   34.374*1.003*(  29.81*1    .699/13.6))/{   62.*460.)))
     130 a  —	...........	..	......	.....	...	.....	.	s  127.bl  PERCENT
                                        62. *      18.74 *   29.72 •   .397 *   .397




     PARTICIPATE  LOADING— EPA METHOD 5 (AT STANDARD CONDITIONS)

     CS * 0.001 * MN * 15.43 / VMSTD

     CS = 0.001 *      .0 * 15.43 /    34.781 «     .000 GR/D3CF




     PARTICULATE  LBS/HR —  EPA METHOD  5

     PMR •  CS * OSSTD /  (15.43 *  453.6)

     PMR •      .000  *    1592304.  /  (15.43 * 453.6) s       .00

-------
Run No.  4.1
     Sample volume =  0.99 m3f34.78  scf
Example  calculations
     CS  (Part)  =139.9/0.99 =  141.3 mg/m3
     CS  (Part)  =  0.001  x!39.9 x 15.43/34.78 =0.062   qr/dscf
     CS  (S02)   =1300  70.99 =1313.1ma/m3
               =1313.Ix 24.06/64  =493 ppm
               =  0.001  x1300  x 15.43/34.78  = 0.577 gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
139.9
47.5
64.9
1300
11.5



- Concentration,
mg/m
141.3
47.9
65.6
1313.1
11.6



gr/dscf
0.062
0.021
0.029
0.577
0.005



ppm


494
3



                                    A-126

-------
                                                            FIELD   DATA
M
ro
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION NO.l COKE BATTERY OUTLET
SAMPLE TYPE PART/H2304/S02
OPERATOR BRUFFEY
AMBIENT TEMP. (DEG.F) 56.
BAR. PRESS. (IN. HG) 29.81
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530081
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM 9 6.0 IN.HG
METER CALIB. FACTOR 1.04a
READ § RECORD DATA EVERY 10.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY ORIFICE PRESSURE
POINT
NO.

INIT







TIME
(MIN.)

0
10.0
20.0
30.0
40.0
50.0
5S.O
58.0
TIME
(24-HR
i*i nrif %
CLUCK/
1543
1553
1603
1613
1623
1633
1710
1718
READING
ICU.FT.)

71.235
75.900
80.590
85.260
89.970
94.585
99.580
100.865
HEAD
(IN.H20)

	
.060
.060
.060
.060
.060
.070
.030
DIFFERENTIAL
(IN.
DESIRED

.73
.73
.73
.73
.73
.87
.37
H20)
ACTUAL

.73
.73
.73
.73
.73
.87
.37
STACK
TEMP
(DEG.F)


547.
563.
MS.
520.
530.
523.
516.
DATE 10/28/81
RUN NUMBER 4-2
PHOBE LENGTH « TYPE 4' HEATED GLASS
NOZZLE : 1.0. .397
ASSUMED MOISTURE 12.0
SAMPLE BUX NUMBER Q
PETER BOX NUMBbH F10
METEH HIAD DIFF. i.ao
C FACTOR .86
PROBE HEATER SETTING 250.
HEATER BUX SETTING 250.
REFERENCE PRESS. DIFF. .15
ONY GAS METER PUMP SAMPLE IMPINGER
TEMP
(DEG
IKLET

66.
67.
70.
71.
71.
72.
be.
.F)
OUTLET

66.
66.
66.
66.
66.
66.
67.
VACUUM
(IN.Hb)


2.0
3.0
3.0
3.0
3.0
3.0
1.0
BOX TEMP
(DEG.F)


270.
298.
256.
266.
252.
253.
264.
TEMP
(OEG.F)


50.
51.
50.
50.
49.
50.
47.
    TOTALS
    AVERAGE
58.0
29.630
                                         ,70
                               .70
531,
69.
66.
2.6   266.
50.

-------
                 PARTICIPATE  FIELD  DATA  ft  RESULTS TABULATION

      PLANT*  NAME AND  ADDRESS               TEST  TEAM  LEADER

      REPUBLIC  STEEL CLEVELAND               BRUFFEY
      TEST
        4-2
NO.l COKE BATTERY OUTLET
00
ENGLISH UNITS
TEST
TB
TF
TT
NP
Y
DN
CP
PM
DATE
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
10/28/81
1 54 j
me
58
7
1

_.

.0

.004
.397 IN
.64
.70 IN-H20
METRIC UNITS
10/26/81
1543
1718
56
7
1
10

17
.0

.044
.1
.84
.7



CM

MM-1
          DROP

VM        VOLUME OF DRY GAS SAMPLED
          AT METER CONDITIONS

TM        AVERAGE GAS METER TEMP

VMSTO     VOLUME OF DRY GAS SAMPLED
          AT STANDARD CONDITIONS*

VLC       TOTAL H2CCOLLECTED IN
          IMPINGERS AND SILICA GEL,ML,

VNC       VOLUME OF MATER VAPOR
          AT STANDARD CONDITIONS*

BNO       PERCENT MOISTURE BY VOLUME

FMO       MOLE FRACTION DRY GAS

PC02      PERCENT COS BY VOL., DRY

P02       PERCENT 02 BY VOL.* DRV

PCO       PERCENT CO BY VOL., DRV

PN2       PERCENT N2 BY VOL., DRY

MD        MOLECULAR MT-DRY STACK GAS

MHS       MOLECULAR NT-STACK GAS
                           29.630 CU-FT


                           67.7   F

                           30.690 SCF


                          103.3


                            4.662 SCF
   .839 CU-M


 19.6   C

   .875 SCC


103.3


   .136
13.60
.664
4.10
11.00
.00
84.90
29.10
27.59
13.60
.664
4.10
11.00
.00
84.90
29.10
27.59

-------
    PB        BAROMETRIC PRESSURE

    PSI        STATIC PRES OF STACK GAS

    PS        STACK PRES, ABS.

    TS        AVERAGE STACK TEMP

    VS        AV6 STACK 6AS VELOCITY

    AS        STACK AREA

    OSSTD      STACK FLOW RATE* DRY*

    OS        ACTUAL STACK FLON RATE

    ISO        PERCENT ISOKINETIC

    MN        FILTERABLE PART
                MG. EPA 5

    CS        FILTERABLE PART

    PMR        FILTERABLE PART
                EMISSION RATE

      •   6*  DEC F,  29.92 IN.H6.
     39.81  IN-HG

     •1.20  IN-H20

     29.72  IN-HG

    531.    F

     te.e   FPS

   7466.   30-IN

1601155.    SCFH
3499941.

    120.4

       .0
     ACFH
.0000 GR/DSCF*

.000   LB/HR
  757.17  PM-HG


  -30.46  PM-H20


  754.93  t'M-HG


  277.    C


    5.7   KPS

    4.817 30-M


45340.    SCt'H


99108.    »CKH


  120.4


     .0
                            .000


                             .00  KG/HR
H
N>
VO

-------
            EXAMPLE PARTICIPATE CALCULATIONS TEST NO.   4-2
                 NO.l COKE BATTERY OUTLET

      VOLUME OF DRV GAS SAMPLED AT STANDARD CONDITIONS
      VMSTD « (17.607 « VM • T * (PB * PM / 13.6)) / (TM * 460.)
                17.647 •    39.630 * 1.044 * ( 39.81 *  .699 / 13.6)
      VMSTO « ——————————--- ———-- — - -------- --- r     30.690 OSCF
                               (  68. * 460.)


      VOLUME OF HATER VAPOR AT STANDARD CONDITIONS
      VMC  « .04707 * VLC
      VHC  * .04707 •  103. a  ~4.86~SCF


      PERCENT MOISTURE IN STACK GAS
      BNO  • (100.  • VHC) /~ (VMSTD * VHC)
^               100. *   4.86
I     BHO  » - ----- — — — ---- ..... ... e  13.60 PERCENT
M                 30.890 *   4.86
O
      MOLE  FRACTION OF DRY  STACK GAS
      FMD • (100.  > BHO)  /  100.
                100. -  13.6
      FMD a —.-.———— --- .. •   .864
                     100.
      AVERAGE  MOLECULAR HEIGHT  OF  DRV STACK GAS
      MD  «  (PC02 •  .44) *  (P02  •  .32) * CPN2 » PCD) * .28
      MO  «  ( 4.10*44/100)  *  (11.0*32/100)  * ((80.9* .0)  * 28/100 =   29.10

      MOLECULAR  HEIGHT  OF  STACK GAS
      MRS * MD * (1.  >  (BRO/100))  + 18. *  (RHO/100)
      MHS * 29.10*  (1. .(13.60/100)) * 18. * (13.60/100) *   27.59

-------
STACK GAS VELOCITY AT STACK CONDITIONS

DELP « SUM. OF THE SORTIVH * (TS » 460.))

VS « BS.49 « CP • OELP /  (SORT(MNS • PS) • PNT3)

VS » 85.49 *  .84 *   53.338 / (SORT( 27.59 * 29.72)  *   7. =   16.75 FP3



STACK GAS VOLUMETRIC FLO* AT STACK CONDITIONS

OS « VS * AS * 3600/144

OS *   18.75 •  7466. 3600/144 •    3099941. ACFH



STACK 9AS VOLUMETRIC FLOM AT STANDARD CONDITIONS

OSSTO « 17.647 • OS • ?3~* U. - (BNO/100)) / (TS * 460.)

          17.647 •    3499941. •  29.72 • (1. • (13.60/100))
OSSTO * ——————	..	 =    1601155. SCFH
                   ( 531. * 460.)
PERCENT ISOKINETIC

ISO * (305.58*(T3+460.))«((0.002669*VLC)«(VM*V*(PB+(PM/13.6))/(TM+     .000 GR/D3CF



PARTICULATE LBS/HR — EPA METHOD 5

PMR * CS * OSSTD / (15.43 * 453.6)

PMR *     .000 •    1601155. / (IS.43 * 453.6) >      .00

-------
Run No.  4.2
     Sample .volume = n.flR m f  3n.RQ scf
Example calculations
     CS (Part) =113.2/0.88 = 128.6 mg/m3
     CS (Part) = 0.001  x113.2  x 15.43/30.89 =  0.056  qr/dscf
     CS (S02)  =1170 /0.88 =1329.5mg/m3
               =1329.5X 24.06/64   =500  ppm
               = 0.001  x 1170  x 15.43/30.89
= 0.584 gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sulfates
As H£S04
As H2S04-2H20
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
113.2
41.7
0.4
0.5
1170
11.9



3 Concentration,
mg/m
128.6
47.4
0.4
0.6
1329.5
13.5



gr/dscf
0.056
0.021
0.0002
0.0002
0.584 |
0.006



ppm


500
3



                                     A-132

-------
                                                            FIELD   DATA
u>
U)
PLANT REPUBLIC STEEL
CLEVELAND

SAMPLING LOCATION COKE OVEN OUTLET
SAMPLE TYPE 4-3-M8-400
OPERATOR CLARKE
AMBIENT TEMP. (DEG.F) 56.
BAR. PRESS. (IN.HG) 29.81
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530024
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM 9 5.
METER CALIB. FACTOR .992
READ * RECORD DATA EVERY 10.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY
POINT TIME ~ TIME READING HEAD
NO. (MIN.) (24-HR (CU.FT.) (IN.H20)
f 1 rt f* H 1
CLUCK 1
INIT 0 1540 583.448
10.0 1550 588.298 .060
20.0 1600 593.200 .060
30.0 1610 597.855 .060
40.0 1620 602.700 .060
50.0 1630 607.666 .060
55.0 1640 613.075 .070
60.0 1715 616.530 .030









0 IN.HG


ORIFICE PRESSURE
DIFFERENTIAL
(IN.H20)
DESIRED ACTUAL

.74 .74
.74 .74
.74 .74
.74 .74
.74 .74
.82 .82
.37 .37












STACK
TECP
(DEG.F)


542.
558.
514.
519.
529.
499.
512.
DATE 10/28/81
NUN NUMBER 4-3
PROBE LENGTH 8 TYPE 4 FT GLASS HEATED
NUZZLE : I.D. .398
ASSUMED MOISTURE 12.0
SAMPLE BOX NUKbER
PETER BOX NUMBER FBI
PETEH HEAD DIFF. 1.87
C FACTOR .88
PROBE HEATER SETTING 400.
HEATER BOX SETTING 400.
REFERENCE PRESS. DIFF. 1.50


DKV GAS METER PUMP SAKPLE IMPINGEK
TEMP VACUUM BOX TEMP TEMP
(DEG.F) (IN.HG) (DEG.F) (DEG.F)
INLET OUTLET

61. 58. 2.0 285. 54.
64. 56. 2.0 340. 52.
6«. 56. 2.0 365. 52.
72. 60. 2.0 371. 52.
74. 60. 2.0 366. 52.
76. 62. 3.0 355. 54.
70. 62. 2.0 371. 52.
   TOTALS
   AVERAGE
60.0
33.082
                                         .70
                                .70   525.
69.
60.
2.1
350,
53.

-------
           PARTICIPATE FIELD DATA A RESULTS TABULATION

PLANT- NAME AND ADDRESS               TEST TEAM LEADER

REPUBLIC STEEL CLEVELAND              CLARKE
TEST
           a-3
COKE OVEN OUTLET

TEST
TB
TF
TT
NP
Y
DN
CP
PM

DATE
TIME-STARt
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
ENGLISH UNITS
10/28/81
1540
1715
60.0
7
.992
.398 IN
.84
.70 IN-H20
METRIC UNITS
10/26/81
1540
1715
60. 0
7
.992
10.1
.84
17.7



KM

KM-
             DROP

tL VM         VOLUME  OF DRY  GAS  SAMPLED
U)           AT METER CONDITIONS

   TM         AVERAGE GAS METER  TEMP

   VMSTD      VOLUME  OF DRY  GAS  SAMPLED
             AT STANDARD CONDITIONS*

   VLC        TOTAL H20 COLLECTED  IN
             IMPINGERS AND  SILICA GEL,ML.

   VMC        VOLUME  OF HATER VAPOR
             AT STANDARD CONDITIONS*

   BNO        PERCENT MOISTURE BY  VOLUME

   FMD        MOLE FRACTION  DRV  GAS

   PC02       PERCENT C02 BY VOL., DRV

   P02        PERCENT 02 BV  VOL.,  DRV

   PCO        PERCENT CO BY  VOL.,  DRV

   PN2        PERCENT N2 BY  VOL.,  DRY

   MD         MOLECULAR NT-DRV STACK GAS

   MNS        MOLECULAR HT-STACK GAS
                                           33.062 CU-FT
                                                  .937 CU-M
64.5 F
32.972 SCF
118.1
5.559 SCF
14.43
.856
4.10
11.00
.00
84.90
29 . 1 0
27.50
18

118

14

4
11

84
29
27
.1 C
.934 SCK
.1
.157 SCM
.43
.856
.10
.00
.00
.90
.10
.50

-------
PB        BAROMETRIC PRESSURE

PSI       STATIC PRES OF STACK GAS

PS        STACK PRES, ABS.

TS        AVERAGE STACK TEMP

VS        AV6 STACK GAS VELOCITY

AS        STACK AREA

QSSTD     STACK FLON RATE, DRY*

OS        ACTUAL STACK FLON RATE

ISO       PERCENT ISOKINETIC

MN        FILTERABLE PART
            M6. EPA 5

CS        FILTERABLE PART

PMR       FILTERABLE PART
            EMISSION RATE

   •  66 DEC F,  29.92 iN.HG.
                                               29.61  1N-HG

                                               •1.20  IN-H20

                                               29.72  IN-HG

                                              525.    F

                                               18.7   FPS

                                             7466.   SO-IN

                                          1593930.    SCFH
3094845.

    124.2

       .0
                                                      ACFH
                                                 .0000 GR/DSCF*

                                                 .000   LB/HN
  757.17  f*-Ht

  -30.08  *M-H20

  750.93  HH-HG

  87«.    C

    5.7   KPS

    a.617 SQ-M

05107.    SCMH

98960.    ACMH

  120.2

     .0



     .000 MG/DSCI"

      .00  KG/HH
Ul
U1

-------
            EXAMPLE  PARTICIPATE  CALCULATIONS  TEST  NO.    4-3

                COKE  OVEN  OUTLET



     VOLUME OF DRY  GAS  SAMPLED  AT  STANDARD CONDITIONS

     VMSTD  •  (17.64?  •  VM  *  T *  (PB I  *  PM  / 13.6))  /  (TM * 460.)

               17.647 •   33.002  *   .992 *  (  29.81  *  .699 /  13.6)
     VMSTO  •  —————— --------- . -------------------------- =     32.97«! OSCF
                              I  65.  » 460.)



     VOLUME OF HATER  VAPOR AT STANDARD CONDITIONS

     VMC •  .04707 * VLC

     VHC *  .04707 •   li*.  » " S.S6 SCF
     PERCENT MOISTURE  IN  STACK GAS

     BHO •  (100. • VHC) /  (VMSTD »  VHC)

                100.  *   5.56
>    BHO s  — --- ..................  x  14.43  PERCENT
I                32.972 *   5.56
U)
cr>
     MOLE FRACTION OF DRY STACK GAS

     FMD «  (100. • BHO) / 100.

                100. -   14.4
     FMD •  —————— 8    .856
                    100.
     AVERAGE MOLECULAR HEIGHT OF DRV  STACK  GAS

     MO *  (PC02 •  .44) *  (P02 • .32)  *  (PN2 * PCO)  *  .28

     MO >  ( 4.10*44/100)  •  (11.0*32/100)  *  ((64.9*  .0)  *  28/100  =   29.10



     MOLECULAR HEIGHT OF  STACK GAS

     MRS « MD * (1. • (BHO/100)) +  18.  *  (BMO/100)

     MNS «  29.10*  (i. -(14.45/100))  *  18.  *  (14.43/100)  *    27.50

-------
      STACK 6AS VELOCITY AT STACK CONDITIONS

      DELP • SUM. OF THE SORUVH * (TS * 460.))

      VS * 85.49 * CP * DELP / (SORT(MRS * PS) • PNTS)

      VS > 65.49 *  .84 *   52,170 / (SORT( 27.50 * 29.72)  *   7. =   16.72 FPS




      STACK 6A9 VOLUMETRIC FLOW AT STACK CONDITIONS

      OS * VS • A3 * 3600/144

      OS >   18.72 *  7466. 3600/144 *    3494845. ACFH




      STACK GAS VOLUMETRIC FLOH AT STANDARD CONDITIONS

      03STD » 17.647 * OS * PS * (1. » (BHO/100)) / (TS » 460.)

                17.647 •    3494845. *  29.72 • (1. - (14.43/100))
      OSSTO » ——————--- ——.——............	.—.. -    1592934. SCFH
                         ( 525. * 460.)




      PERCENT ISOKINETIC

>     ISO • (305.58MT3«460.))*((0.002669*VLC)«(VM*V*(PB«(PM/13.6))/(TM+460.)))/(TT*VS«PS*ON*DN)

to            (305.58*( 525.+460.))*((0.002669*  118.)»(   33.002* ,992*(  29.81*(    .699/13.6))/(  65.+460.)))
-J     ISO » —————————————————	...... —....................................... B 124.23 PEHCf.M
                                          60. •     18.72 •   29.72 *  .398 *  .398




      PARTICIPATE LOADING — EPA METHOD 5 (AT STANDARD CONDITIONS)

      CS * 0.001  • MN • 15.43 / VMSTO

      CS * 0.001  *      .0 • 15.43 /    32.972 s     .000 GR/DSCF




      PARTICULATE LBS/HR — EPA METHOD 5

      PMR a CS *  OSSTD / (15.43 * 453.6)

      PMR «     .000 *    15*2934. / (15.43 * 453.6) «      .00

-------
Run No.  4.3
     Sample volume =0.93  m3.32.97 scf
Example  calculations
     CS  (Part) =61.1 /1.93= 65.7 ma/m3
     CS  (Part) = 0.001 x61.1  x  15.43/32.97=0.028   qr/dscf
     CS  (S02)  =1250/0.93=1344 ma/m3
              = 1344  x 24.06/64 = 505 ppm
              = 0.001 x 1250 x  IS.43/22*32- = JL585 gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg

61.1






6.4
8.7
1250

29.8



2 Concentration,
mg/m

65.7






6.9
9.4
1344

32.0



gr/dscf

0.028






0.003
0.004
0.585

0.014



ppm









505

8



                                  A-138

-------
                                                              FIELD  DATA
OJ
vo
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION COKE OVEN OUTLET
SAMPLE TYPE 4-4-M8-400
OPERATOR CLARKE
AMBIENT TEMP. (OEG.F) 56.
BAR. PRESS. (IN. HG) 26.01
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530069
STACK INSIDE DIM. (IN) 97. SO .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM 9 5.0 IN.MG
METER CALIB. FACTOR 1.016
READ ft RECORD DATA EVERT 10.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY ORIFICE PRESSURE
POINT
NO.

INlf







TIME
(MIN.)

0
10.0
20.0
30.0
40.0
50.0
55.0
60.0
TIME
(24-HR
f»i nf tf )
ILUEK/
1543
1553
1603
1613
1623
1633
1708
1715
READING
(CU.FT.)

6.355
11.050
15.885
20.586
25.371
29.486
34.987
37.334
HEAD
(IN.H20)

—
.060
.060
.060
.060
.060
.070
.030
DIFFERENTIAL
(IN.
DESIRED

.74
.74
.74
.74
.74
.82
.37
H20)
ACTUAL

.74
.74
.74
.74
.74
.02
.37
STACK
TEKP
(DEG.F)


547.
556.
515.
521.
532.
519.
515.
DATE 10/28/81
NUN NUMBER 4-4
PHOBE LENGTH ft TYPE 5 FT GLASS HEAlEU
NOZZLE : 1.0. .397
ASSUMED MOISTURE 12.0
SAKPLE BOX NUMBER
PETER BUX NUMBER FB5
HE1ER HEAD DIFF. 1.86
C FACTOR .88
HHOBE HEATER SETTING 400.
HEATER BOX SETTING 400.
REFERENCE PRESS. DIFF. 1.50
OHY GAS METER PUMP SAMPLE IMPINGEH
TEMP
(DEG
INLET

69.
70.
74.
78.
HI.
82.
77.
.F)
OUTLET

70.
70.
70.
70.
72.
72.
74.
VACUUM
(IN.HG)


.0
.0
.0
.0
.0
.0
.0
BOX TEMP
(OEG.F)


275.
355.
342.
312.
325.
363.
386.
TEMP
(DEG.F)


46.
42.
4U.
40.
47.
44.
58.
     TOTALS
     AVERAGE
60.0
30.979
                                         ,70
                                ,70    529.
76.
71,
1.0
337.
45.

-------
               PARTICIPATE FIELD DATA « RESULTS TABULATION

    PLANT- NAME AND ADDRESS               TEST TEAM LEADER

    REPUBLIC STEEL CLEVELAND              CLARKE
    TEST
        4-4
COKE OVEN OUTLET
I


O

TEST
TB
TF
TT
NP
Y
DN
CP

DATE
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
ENGLISH UNITS
10/28/61
1543
1715
60.0
7
1.016
.397 IN
.84
METRIC UNITS
10/28/61
1543
1715
60.0
7
1.016
10.1
.84



KM

PM        AVERAGE ORIFICE PRESSURE
          DROP

VM        VOLUME OF DRY GAS SAMPLED
          AT METER CONDITIONS

TM        AVERAGE GAS METER TEMP

VMSTO     VOLUME OF DRY GAS SAMPLED
          AT STANDARD CONDITIONS*

VLC       TOTAL HZO COLLECTED IN
          IMPINGERS AND SILICA GEL,ML.

VNC       VOLUME OF MATER VAPOR
          AT STANDARD CONDITIONS*

BNO       PERCENT MOISTURE BY VOLUME

FMD       MOLE FRACTION DRY GAS

PC02      PERCENT C02 BY VOL., DRV

POZ       PERCENT 02 BY VOL., DRV

PCO       PERCENT CO BY VOL., DRV

PN2       PERCENT N2 BY VOL., DRV

MO        MOLECULAR MT-ORY STACK GAS

MM3       MOLECULAR NT-STACK GAS
                                                 .70  IN-H20


                                               30.979 CU-FT
                                                17.7   CM-H20
                                                  .877 CU-M
73.
30.
166.
5.
If.
•
4.
11.
•
84.
'29.
27.
5 F
048 SCF
5
013 SCF
30
657
10
00
00
90
10
51
23.
•
106.
•
14.
•
4.
11.
•
84.
29.
27.
1 C
851 SCC
s
142 SCH
30
857
10
00
00
90
10
51

-------
PB        BAROMETRIC PRESSURE

PSI       STATIC PRES OF STACK 6*3

PS        STACK PRESr ABS.

TS        AVERAGE STACK TEMP

VS        AV6 STACK GAS VELOCITY

AS        STACK AREA

Q3STD     STACK FLOM RATE, DRY*

OS        ACTUAL STACK FLON RATE

ISO       PERCENT ISOKINETIC

MN        FILTERABLE PART
            M6. EPA 5

CS        FILTERABLE PART

PMR       FILTERABLE PART
            EMISSION RATE

   *  68 DE6 F,  24.92 IN.HG.
 28.81  IN-HG

 •1.20  IN-H20

 28.72  IN-HG

529.    F

 19.1   FPS

       SO-IN

        SCFM

        ACFH
   7466.

1564464.

3562981.

    115.9

       .0
   731.77  fM-HG

   -30. 4«  C

   789.53  PM-HG

   276.    C

     5.8   KPS

     4.817 SO-M

 44301.    SCMH

100893.    *CCM

   115.9

      .0
   .0000 GR/OSCF*

   .000   LB/HK
      .000

       .00  KG/HK

-------
             EXAMPLE PARTICIPATE  CALCULATIONS  TEST  NO.    0-«

                  COKE OVEN OUTLET



       VOLUME OF DRY GAS SAMPLED  AT STANDARD CONDITIONS

       VM3TO • (17.647 • VM * T •  (PB  * PM  / IS.6))  /  (TM *  460.)

                 17.647 *    30.979 *  1.016 *  ( 28.61  »   .699  /  13.6)
       VMSTO * ——————..........................	.	. -     30.018 OSCF
                                I  74. » 460.)



       VOLUME OF MATER VAPOR AT STANDARD CONDITIONS

       VMC • .04707 • VLC

       VMC • .04707 *  107. «   5.01 SCF



       PERCENT MOISTURE IN STACK GAS

       BMO «i~(id6. • ^fMC) / (VMSTD * VMC)

                 100. •   5.01
       BMO • —————————— = 14.30 PERCENT
jp                  30.046 *   5.01
H           ....    -
a*.
10      MOLE FRACTION OF CRT STACK GAS

       FMD « (100. - BMO) / 100.

                 100. - ~14.3
       FMD • ———	— s   .857
                      100.
       AVERAGE MOLECULAR WEIGHT OF DRY STACK GAS

       MO * (PC03 * .44) * (POZ * .32) *  (PN3 » PCO)  *  .28

       MD • ( 4.10*44/100) * (11.0*32/100) * ((80.9*  .0)  *  28/100  r    29.10



       MOLECULAR HEIGHT OF STACK GAS

       MMS • MD * (1. - (BMO/100)) »  16.  * (BMO/100)

       MMS *  Z9.10* (1. -(14.30/100)) *  16. •  (14.30/100)  a    27.51

-------
STACK GAS VELOCITY AT STACK CONDITIONS

OECP « SUM. OF THE SQRT(VH *  (T3 + 460.))

VS * 65. 49 • CP * DELP /  (SURT(MNS * PS) * PNTS)

VS » 85.49 •  .84 *   52.303  /  ISQRU 27.51 • 28.72)  *   7. r    19.09 FPS



STACK GAS VOLUMETRIC FLO* AT  STACK CONDITIONS

OS * VS * AS * 3600/144

OS *   19.09 •  ?466. 3600/144  3    3562981. ACFH



STACK GAS VOLUMETRIC FLOM AT  STANDARD CONDITIONS

OSSTO • 17.647 • OS * PS * (1.  - (BMO/iffO)') / (TS » 460.)

          17.647 •    3562981.  •  28.72 * (1. - (14.30/100))
OSSTO * —————— —————— — — --- - r     1564464. SCFH
                   ( 529. «• 460.)



PERCENT ISOKINETIC

ISO • (305.S8«(TS*460.))«((0.002669«VLC)»(VH*V«(PB»(PW/13.6) ) / (TM«460.) ) ) / (TT*VS*PS*DN*DN)
       (305. 5S*t S29. +460. ))*((0. 002669*  107.)+(   30.979*1 .Ol6*( 28.81M    .699/13.6) )/(  74.«460.)))
ISO » — - --- — --- — — — — — --- — — — — ----------------------------- — ------- — ------- . --- 3  115.86  PEHCENT
                                    60. •     19.09 •   2B.72 •  .397 •  .3V7



PARtfCULATE LOADTNe— EPA METHOD 5 «T STANDARD CONDITIONS)

CS • 0.001 • MN * 15.43 / VMSTD

CS » 0.001 *      .0 • 15.43 /    30.048 a     .000 GR/DSCF



PART1CULATE LBS/HR " EPA METHOD 5

PMR • CS * QSSTD / (15.43 * 453.6)

PMR «     .000 *    1564464. / (15.43 • 453.6) =      .00

-------
Run No.  4.4
                          3
     Sample  volume =0.85  m t 30.OR  scf
Example  calculations
     CS  (Part) =78.4/0.85 = 92.2   ma/m3
     CS  (Part) = 0.001 x78.4  x 15.43/30.05 -  0.040  qr/dscf
                                     3
     CS (S02)  =1160/0.85 = 1364  mg/nT
              = 1364 x 24.06^4   = 513ppm
              = 0.001 xl160  x 15.43/_2O5_
0.596 gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


78.4






12.6
17.2
1160

10.4



3 Concentration,
mg/m


92.2






14.8
20.3
1365

12.2



gr/dscf


0.040






0.006
0.009
0.596

0.005



PPm










513

3



                                    A-144

-------
                                                             FIELD  DATA
M
*»
Ul
PLANT REPUBLIC STEEL
SAMPLING LOCATION COKE STACK
SAMPLE TYPE METHOD 5-230
OPERATOR DO/MP
AMBIENT TEMP.(DEG.F) 58.
BAR. PRESS. (IN.HG) 29.81
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530026
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM 8 11.
METER CALI8. FACTOR 1.033
READ ft RECORD DATA
TRAVERSE SAMPLE
POINT TIME
NO. (MIN.)

INtT t '-
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
130.0
140.0
150.0
CLOCK
TIME
(24-HR

1423
1433
1443
1453
1503
1513
1523
1533
1543
1553
1603
1613
1623
1633
1643
1706
EVERY iO.O
GAS METER
READING
(CU.FT.)

77*. 364
764.300
769.220
794.140
799.100
604.000
606.930
613.660
618.830
823.770
628.690
633.660
636.580
643.550
646.497
653.407
MINUTES
VELOCITY
HEAD
(IN.H20)


.073
.075
.075
.075
.075
.075
.075
.075
.075
.075
.075
.075
.075
.075
.075
CLEVELAND
5 IN.HG

ORIFICE

PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.81
.81
.61
.61
.61
.61
.81
.81
.61
.61
.61
.61
.61
.61
.81
H20)
ACTUAL

.at
.81
.61
.61
.61
.61
.61
.61
.81
.81
.81
.81
.81
.81
.61

STACK
TEPP
(DEG.F)


916.
516.
518.
516.
516.
516.
516.
516.
516.
516.
518.
516.
516.
516.
516.
DATE 10/28/81
RUN NUMBER 0-5
PROBE LENGTH ft TYPE 6* GLASS
NOZZLE 1 I.D. .377
ASSUMED MOISTURE 11.0
SAMPLE BOX NUMBER
METER BOX NUMBER FB4
PETER HEAD DIFF. 1.68
C FACTOR .92
PROBE HEATER SETTING 250.
HEATER BOX SETTING 250.
REFERENCE PRESS. DIFF. .17

DRV GAS METER
TEMP
(OEG.P)
INLET OUTLET

64. 62.
65. 62.
66. 62.
67. 62.
68. 62.
68. 62.
67. 62.
67. 62.
67. 62.
67. 62.
66. 62.
68. 62.
67. 62.
66. 62.
67. 64.

PUMP
VACUUM
(IN.HG)


a.
9.
10.
10.
10.
10.
11.2
10.6
10.7
10.5
11.0
10.6
10.7
10.6
10.4

SAMPLE
BOX TEMP
(OEG.F)


237.
255.
274.
266.
244.
262.
27.5.
275.
272.
274.
270.
27.3.
27.5.
273.
254.

IMPINGER
TEMP
(OEG.F)


47.
47.
18.
46.
44.
SO.
47.
46.
45.
46.
46.
•6.
46.
46.
46.
     TOTALS
     AVERAGE
150.0
74.041
                                         .61
                               .81   318.
67.
62.
10.6   265.

-------
           PARTICIPATE FIELD DATA B RESULTS TABULATION

PLANT- NAME AND ADDRESS               TEST TEAM LEADER

REPUBLIC STEEL CLEVELAND              00/MP
TEST
••5
COKE STACK
TEST DATE
                                 ENGLISH UNITS

                                    10/28/61
                                              METRIC UNITS

                                                 10/26/61
TB
TF
TT
NP
¥
DN
CP
PM
TIME-START
TIME-FINISH
NET TIME OF TEST* MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
	 PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
1423
1706
150
15
1



          DROP

VM        VOLUME OF DRY GAS SAMPLED
       	AT METER CONDITIONS

TM        AVERAGE GAS METER TEMP

VMSTD     VOLUME OF DRY GAS SAMPLED
          AT STANDARD CONDITIONS*

VLC       TOTAL H20 COLLECTED IN
          IMPINGERS AND SILICA GEL*ML.

VNC       VOLUME OF NATER VAPOR
          AT STANDARD CONDITIONS*

BMO       PERCENT MOISTURE BY VOLUME

FMD       MOLE FRACTION DRY GAS

PC02      PERCENT C02 BY VOL.r DRV

P02       PERCENT 02 BY VOL.* DRV

PCO       PERCENT CO BY VOL.* DRY

PN2       PERCENT N2 BY VOL.* DRY

MD        MOLECULAR NT-DRY STACK GAS

MMS       MOLECULAR NT-STACK GAS
                                    1.033

                                     .377 IN

                                     .84

                                     .61  IN-H20


                                   74.041 CU-FT


                                   64.5   F

                                   76.660 SCF


                                  280.7


                                   13.213 SCF
                                              1706

                                               150.0

                                                15

                                                 1.033

                                                 9.6   MM

                                                  .64

                                                20.6   MM-H20


                                                 2.097 CU-M


                                                16.1   C

                                                 2.176 SCM


                                               280.7


                                                  .374 SCM
14.67
.653
4.10
11.00
.00
84.90
29.10
27.47
14.67
.853
4.10
11.00
.00
84.90
29.10
27.47

-------
PB        BAROMETRIC PRESSURE
PSi       STATIC PRES OF STACK GAS
PS        STACK PRES, ABS.
TS        AVERAGE STACK TEMP
VS        AVG STACK GAS VELOCITY
AS        STACK AREA
OSSTD     STACK FLOW RATE* DRY*
03        ACTUAL STACK FLOW RATE
ISO       PERCENT ISOKINCTIC
MN        FILTERABLE PART
            M6. EPA 5
CS        FILTERABLE PART
PMR       FILTERABLE PART
            EMISSION RATE
     29.81  IN-HG
     •1.20  1N-H20
     29.72  IN-HG
    518.    F
     21.5   FPS
   7466.   30-IN
1838631.    SCFH
401772S.    ACFN
    111.8
       .0

       .0000 GR/OSCF*
       .000   LB/HR
                                                            757.17  MM-MG
                                                            •30.48  MM-H20
                                                            754.93  MM-HG
                                                            270.    C
                                                              6.6   «PS
                                                              4.817 SO-M
                                                          52065.    3C»H
                                                         113770.    »CHH
                                                            111.8
                                                               .0

                                                               .000 PG/OSC*
                                                                .00  KG/HR
*  66 DEC F,
                       IN.H6.

-------
           EXAMPLE PARTICULATE CALCULATIONS  TEST  NO.    4*5

                COKE STACK




     VOLUME OF DRV GAS SAMPLED AT  STANDARD CONDITIONS

     VMSTD •  (17.647 • VM *  V •  (PB  •  PM  / 13.6))  /  (TM *  460.)

               17.647 •    74.041  *  1.033 •  (  29.81  *   .810 / 13.6)
     VMSTD »  ••-—-..—.—.——............................... •     76.860 DSCF
                              (  65. * 460.)




     VOLUME OF NATER VAPOR AT STANDARD CONDITIONS

     VHC « .04707 * VLC

     VHC « .04707 *  281. »  13.21 SCF




     PERCENT  MOISTURE IN STACK GAS

   "~ Stid • UOlT. • VHC) / (VM3TO * VHC)

               100. *  13.21
>    BHO « .————.———.— ;« 14.67  PERCENT
 I                76.860 *  13.21
M

00

     MOLE FRACTION OF DRY STACK GAS

     FMD • (100. • BNO) / 100.

               100. -  14.7
     FMD « -————.-—..— •    .853
                    100.




     AVERAGE  MOLECULAR HEIGHT OF DRY STACK GAS

     MO « (PC02 * .44) » (P02 *  .32) » (PN2  •  PCO) • .28

     MD • ( 4.10*44/100) * (11.0*32/100)  * ((84.9* .0)  * 28/100  »   29.10




     MOLECULAR HEIGHT OF STACK GAS

     MHS * MD * (1. • (BMO/100)) » 18. *  (BHO/100)

     MHS «  29.10* (1. -(14.67/100)) » 18. *  (14.67/100) •    27.47

-------
      STACK GAS VELOCITY AT STACK CONDITIONS

      DELP • SUM. Or THE SQRTtVH * (TS » 460.))

      VS « 65.49 • CP • OELP / (SORT(MW3 • PS) • PNTS)

      VS « 85.49 *  .84 *  128.467 / (SORT( 27.47 • 29.72)  •  15. •   21.52 FPS



      STACK 6A8 VOLUMETRIC FLO* AT STACK CONDITIONS

      OS » VS * AS • 3600/144

      OS «   21.5* •  7466. 3600/144 »    4017725. ACFH



      STACK CAS VOLUMETRIC FLO* AT STANDARD CONDITIONS

      093TO « 17.647 • OS * PS • (1. - (8MO/100)) / (TS * 460.)

                17.647 *    4017725. •  29.72 • (1. • (14.67/100))
      OSSTD • ..————————.—————................ •    1838631. 3CFH
                         ( 518. * 460.)



I     PERCENT ISOKINETIC
M
£     ISO • (305.58*(TS*460.))*((0.002669«VLC)»(VN*Y»(PB*(PM/13.6))/(TM*460.)))/(TT»VS*P8*DN«DN)

             (305.50*( 518.»460.))«C(0.002669*  281.)*(   74.041*1.033*1 29.81«(    .810/13.6))/(  65.4460.)))
      130 • [[[ • 1U.85 PERCENT
                                         ISO. •     21.52 •   29.72 •  .377 •  .377



      PANICULATE LOADING — EPA METHOD 5 (AT STANDARD CONDITIONS)

      CS * 0.001 • MN • 15.43 / VMSTD

      CS » 0.001 •      .0 • 15.43 /    76.860 •     .000 6R/D8CF



      PARTICULATE LBS/HR — EPA METHOD 5


-------
Run No.  4.5
                           Q
     Sample volume =  2.18 m .  76.86 scf
Example  calculations
     CS  (Part)  =174.5/2.18 = 80.0  mq/m3
     CS  (Part)  =  0.001  x  174.5X  15.43/76.86
     CS  (S02)   =	/	=	mg/m3
               =	 x 24.06/	=	ppm
               =  0.001  x	x  15.43/	
0.035  gr/dscf
       gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Sulfur dioxide
Sulfuric acid mist
As H2S04
As H2S04-2H20
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


174.5
137.3
128.8
112.4
104.7
99.0

0.0
0.0




65.7
3.1
14.3
o Concentration,
mg/m


80.0
63.0
59.1
51.6
48.0
45.4

0.0
0.0




30.1
1.4
6.6 j
gr/dscf


0.035
0.028
0.026
0.022
0.021
0.020

0.0
0.0




0.013
0.001
0.003
ppm


















                                  A-150

-------
                                                        FIELD  DATA
        PLANT
        SAMPLING LOCATION

        SAMPLE TYPE
        OPERATOR
        AMBIENT TEMP.(OEG.F)
        BAR.PRESS.(IN.HG)
        STATIC PRESS.(IN.M20)
        FILTER NUMBER(S)
        STACK INSIDE DIM.(IN)
        PITOT TUBE COEFF.
        THERM. NO.
        LEAKAGE
        METER CALIB. FACTOR
        READ • RECORD DATA EVERT
                     REPUBLIC STEEL CLEVELAND
                     COKE STACK

                     METHOD 8-600
                     DO/MP
                      58.
                     29.01
                     •1.20
                     3530226/3530206
                       97.50    .00
                       .84

                      .000 CFM 3 20.0 IN.HG
                      .982
                     10.0 MINUTES
                                               DATE                     10/28/81
                                               RUN NUMBER                  0-6

                                               PROBE LENGTH ft TYPE      a* UUAHTZ
                                               NUZZLE      : I.D.        .620
                                               ASSUMED MOISTURE         11.0
                                               SAPPLE BOX NUMBER
                                               PETER BOX NUMBER         FBB
                                               PETER MEAD OIFF.         1.91
                                               C FACTOR                  .91
                                               PROBE HEATER SETTING     600.
                                               HEATER BOX SETTING       600.
                                               REFERENCE PRESS. OIFF.    .02





>
M
(Jl
I-1







TRAVERSE SAMPLE
POINT TIME
NO. (MIN.)

INlf" 0
10.0
20.0
30.0
40.0
50.0
60.0
ro.o
60. 0
90.0
100.0
110.0
CLOCK
TIME~
(24-HR
n ftp if i
vLUlfK 9
T«2?
1437
1447
1457
1507
1517
1527
1537
1547
1557
1714
1716
GAS METER
READING
(CU.FT.)

269.548
274.840
278.700
282.500
286.360
290.190
294.0)0
297.530
300.570
303.500
308.180
309.023
VELOCITY
HEAD
(IN.H2U)

.....
.075
.075
.075
.075
.075
~ .075
.075
.075
.075
.075
.075
ORIFICE
PRESSURE
DIFFERENTIAL
(IN.
DESIRED

5.73
5.73
5.73
5.73
5.73
5.73
5.73
5.73
5.73
5.73
5.73
H20)
ACTUAL

1.00
.50
.50
.50
.50
.50
.40
.30
.30
.75
.75
STACK
TEMP
(OEG.F)


518.
518.
518.
518.
518.
518.
518.
518.
518.
518.
518.
DRY GAS METER
TEMP
(DEG.F)
INLET OUTLET

58. 56.
60. 56.
63. 57.
64. 57.
65. 58.
66. 58.
67. 59.
68. 60.
69. 61.
66. 63.
66. 61.
PUMP
VACUUM
(IN.HG)


5.5
10.6
13.3
16.2
18.2
19.5
21.5
21.3
23.3
3.7
3.8
SAPPLE
BOX TEMP
(DEG.F)


586.
596.
606.
630.
642.
620.
620.
627.
631.
621.
663.
IPPINGEH
TEMP
(DEG.F)


38.
36.
38.
38.
40.
42.
44.
49.
43.
46.
38.
TOTALS
AVERAGE
110.0
39.475
                                        5.73
                               .55   518.
65.
59.
14.3
622.
41,

-------
                 PARTICULAR FIELD DATA  ft RESULTS TABULATION

      PLANT- NAME AND ADDRESS               TEST  TEAM LEADER

      REPUBLIC  STEEL  CLEVELAND              DO/MP
      TEST
        4-6
COKE STACK
Ln
NJ
ENGLISH UNITS
TEST
TB
TF
TT
NP
Y
ON
CP
PM
DATE
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
10/28/61
14*7
1716
110
11




.0

.962
.620 IN
.64
.55 IN-H20
METRIC UNITS
10/28/61
1427
1716
110
11

15

13
.0

.982
.7
.84
.9



KM

KM-
          DROP

VM        VOLUME OF DRV GAS SAMPLED
          AT METER CONDITIONS

TM        AVERAGE GAS METER TEMP

VMSTD     VOLUME OF DRY GAS SAMPLED
          AT STANDARD CONDITIONS*

VLC    "" TOTAL' HZO"COLLECTED IN
          IMPINGERS AND SILICA GEL,ML,

VNC       VOLUME OF MATER VAPOR
          AT STANDARD CONDITIONS*

BMO       PERCENT MOISTURE BY VOLUME

FMD       MOLE FRACTION DRV GAS

PC02      PERCENT C02 BY VOL.* DRY

P02       PERCENT 02 BY VOliY D*Y

PCO       PERCENT CO BV VOL.» DRV

PN2       PERCENT N2 BV VOL., DRY

MO      'MOLECULAR IT-DRY STACK GAS

MHS       MOLECULAR NT-STACK GAS
                           39.475 CU-FT


                           61.7   F

                           39.139 SCF


                          Il9.4


                            6.091 SCF
  1.116 CU-M


 16.5   C

  1.106 SCM


129.4


   .172 SCM
13.47
.665
4.10
n.oo
.00
B4.90
"Z^.iO
27.60
13.47
.865
4.10
11.00
.00
64.90
29.10
27.60

-------
     PB         BAROMETRIC  PRESSURE

     PSI        STATIC  PRES OF  STACK  GAS

     PS         STACK PRES, ABS.

     TS         AVERAGE STACK  TEMP

     V8         AVG  STACK GAS  VELOCITY

     AS         STACK AREA

     OSSTD      STACK FLOW  RATE,  DRY*

     US         ACTUAL  STACK FLO* RATE

     ISO        PERCENT ISOKINETIC

     MN         FILTERABLE  PART
                M6. EPA 3

     CS         FILTERABLE  PART

     PMR        FILTERABLE  PART
                EMISSION  RATE

       *  6* OE6 F,   29.92 IN.M6.
     29.61  IN-HG

     -1.20  IN-H2U

     29.72  IN-HG

    516.    F

     ^1.5   FPS

   7466.   SO-IN

1660026.    SCFH

4006004.    ACFH

     26.4

       .0



       .0000 GR/DSCF*

       .000   LB/HH
   757.17  >«M-HG

   -30. «8  PK-H20

   754.9J  VM-HG


   270.    C

     6.5   *PS

     4.617 SU-M

 52670.    3CI"H

113495.    ACHH

    26.4

      .0
      .000

       .00  KG/HH
Ul
CO

-------
Ul
*»
      EXAMPLE PARTICULATE CALCULATIONS TEST NO.   4-6

           COKE STACK



VOLUME OF DRY 6AS SAMPLED AT STANDARD CONDITIONS

VMSTD « (17.647 * VM * Y •  (PB * PM / 13.6)) /  (TM  + 460.)

          17.647 *    39.475 •  .962 • ( 29.81  *  .545  /  13.6)
VMSTD « "—	—....—.	..............	«      39.139 DSCF
                         (  62. » 460.)



VOLUME OF HATER VAPOR A'T STANDARD CONDITIONS

VMC • .04707 • VLC

VWC i .04707 *  129. «   6.09 SCF



PERCENT MOISTURE IN STACK CAS

BMO « (100. •VWC)/ (VMSTD * VMC)

          100. *   6.09
BMO » —•	——	......... m 13.47 PERCENT
            39.139 *   6.09



MOLE FRACTION OF DRY STACK GAS

FMD • (100. • BMO) / 100.

          100. -  13.5
FMD • ————— ———— z   .865
               100.



AVERAGE MOLECULAR HEIGHT OF DRY STACK GAS

MO = (PC02 * .44) * (P02 * .32) * (PN2 * PCU) * .28

MD * ( 4.10*44/100) * (11.0*32/100) » ((84.9* .0) * 28/100 =   29.10



MOLECULAR HEIGHT OF STACK GAS

MMS « MO * (1. - (BMO/10U)) » 18. * (BMO/100)

MHS «  29.10* (1. -(13.47/100)) » 18. * 113.47/100) s   27.60

-------
    STACK GAS VELOCITY AT STACK CONDITIONS

    OELP « SUM. OF THE SQRT(VH * ITS » 460.))

    VS « 65.49 * CP * DELP / (SORT(MHS • PS) * PNTS)

    V3 « 85.49 *  .84 •   94.209 / (SORT( 27.60 • 29.72)   •  11.  =   21.17 FPS



    STACK GAS VOLUMETRIC FLO* AT STACK CONDITIONS

    OS s VS * AS * 3600/144

    OS •   Z1.47 *  7466. 3600/144 •    4008004. ACFH



    STACK 6AS VOLUMETRIC FLOM AT STANDARD CONDITIONS

    QSSTD « 17.607 * OS * PS * U. - (BltO/lOO)) / (TS * 460.)

              17.647 *    4008004. *  29.72 * (1. - (13.47/100))
    OSSTO « —————— — — ..——.———..—.	. =    1060026.  SCFH
                       I 518. * 460.)



*f  PERCENT ISOKINETIC
M
£  ISO • (305.58«(T3*460.))*l(0.002669«VLC)«(VM«YMPB+(PM/13.6))/(TM +       .00

-------
Run No.  4.6
     Sample volume =1.11 m  ,39.14  scf
Example  calculations
     CS  (Part)  =  69.7/1.11 = 62.8  mq/m3
     CS  (Part)  =  0.001  x 69.7  x 15.43/39.14 =  0.027 qr/dscf
     CS  (S02)   =  1550/1.11 = 1396 mg/m3
               =  1396  x 24.06/_6J_=_5Z5ppm
               =  0.001  x 1550  x 15.43/3HU4_ = n.fill  gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


69.7






0.0
0.0
1550

73.7



, Concentration,
mg/m


62.8






0.0
0.0
1396

66.4



gr/dscf


0.027






0.0
0.0
0.611

0.029



ppm











525

16.3



                                   A-156

-------
                                                        FIELD  DAT*
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING-LOCATION N01 COKE BATTERY OUTLE1
SAMPLE TYPE PART/S02/H2S04
OPERATOR BRUFFEY
AMBIENT TEMP. (OEG.F) 52.
BAR. PRESS. (IN.HG) 29.66
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530071
STACK INSIDE DIM. (IN) 97.50 .00
P1TOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM 3 6.0 IN.HG
METER CALIB. FACTOR 1.003
READ ft RECORD DATA EVERY 10.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY ORIFICE PRESSURE
POINT
NO.

INlt












TIME
(MIN.)

6
10.0
20.0
30.0
40.0
50.0
60.0
70.0
60.0
90.0
100.0
110.0
114.9
TIME
(24-HR

940
950
1000
1010
1020
1030
1040
1050
1100
1110
1120
1130
1137
READING
(CU.FT.)

873.366
676.400
883.410
866.430
893.040
896.110
903.100
907.750
912.410
916.700
923.380
926.100
930.347
HEAD
(IN.H20)


.060
.060
.060
.050
.060
.060
.050
.050
.100
.050
.050
.050
DIFFERENTIAL
(IN.
UESIRfcU

.73
.73
.73
.62
.73
.73
.62
.62
1.22
.62
.62
.62
H20)
ACTUAL

.73
.73
.73
.62
.73
.73
.62
.62
1.22
.62
.62
.62
STACK
TEMP
(DEG.F)


530.
543.
556.
518.
529.
495.
531.
545.
501.
519.
530.
495.
DATE 10/29/81
RUN NUMBER 5-1
PROBE LENGTH ft TYPE 5* HEATEU GLASS
NOZZLE : I.U. .390
ASSUMED MOISTURE 12.0
SAMPLE BOX NUMBER 0
MtTER BOX NUMBER FB2
KETER HEAD OIFF. 1.76
C FACTOR .86
PROBE HfcATER SETTING 250.
HEATER BOX SETTING 250.
REFERENCE PRESS. DIFF. .15
UkY GAS METER PUMP SAMPLE IMPINGER
TEMP
(DEC
INLET

52.
54.
56.
62.
63.
64.
66.
67.
68.
69.
69.
70.
.F)
OUTLET

52.
52.
52.
53.
54.
56.
56.
58.
59.
60.
61.
62.
VACUUM
(IN.HG)


2.0
3.0
3.0
2.5
2.5
2.5
2.0
2.5
2.5
3.5
4.0
3.0
BOX TEMP
(DEG.F)


227.
263.
259.
258.
264.
260.
254.
251.
255.
260.
252.
255.
TEMP
(OEG.F)


41.
40.
41 .
42.
41.
42.
46.
48.
49.
52.
57.
56.
TOTALS
AVERAGE
114.9
56.961
                                         .72
                               .72   524.
64.
56.
2.8   255.
                         46.

-------
               PARTICIPATE FIELD DATA ft RESULTS TABULATION
    PLANT- NAME AND ADDRESS               TEST  TEAM LEADER
    REPUBLIC STEEL CLEVELAND              BRUFFET
    TEST
3-1
N01 COKE BATTERY OUTLET
ENGLISH UNITS
TEST
TB
TF
TT
NP
Y
DN
CP
PM
DATE
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
10/29/81
940
1137
110
12
1



.9

.003
.398 IN
.84
.72 IN-H20
METRIC UNITS
10/29/81
940
1137
114
12
1
10

18
.9

.003
.1
.84
.2



KM

KM-
•f             DROP
Ln   VM         VOLUME  OF  DRV  GAS  SAMPLED
0°             AT  METER CONDITIONS
    TM         AVERAGE GAS  METER  TEMP
    VMSTD      VOLUME  OF  DRY  GAS  SAMPLED
              AT  STANDARD  CONDITIONS*
    VLC        TOTAL H2o  COLLECTED  IN
              IMPINGERS  AND  SILICA  GEL,ML.
    VNC        VOLUME  OF  MATER  VAPOR
              AT  STANDARD  CONDITIONS*
    8*0        PERCENT MOISTURE BY  VOLUME
    FMO        MOLE FRACTION  DRY  GAS
    PC02       PERCENT C02  BY VOL.*  DRY
    P02        PERCENT 02 BY  VOL.,  DRV
    PCO        PERCENT CO BY  VOL.,  DRV
    PN2        PERCENT N2 BY  VOL.,  DRV
    MD         MOLECULAR  MT-ORY STACK GAS
    MWS        MOLECULAR  MT-STACK GAS
                                   56.981 CU-FT

                                   59.9   F
                                   58.031 SCF

                                     .1

                                    8.901 SCF
                                                 1.614 CU-M

                                                15.5   C
                                                 1.643 SCK

                                               189.1

                                                  .252
13.30
.867
4.30
11.30
.00
84.40
29.14
27.66
13.30
.867
4.30
11.30
.00
84.40
29.14
27.66

-------
     PB        BAROMETRIC PRESSURE

     PSI       STATIC PRE3 OF STACK GAS

     PS        STACK PRES, ABS.

     TS        AVERAGE STACK TEMP

     VS        AV6 STACK GAS VELOCITY

     AS        STACK AREA

     03STD     STACK FLOW RATE* DRY*

     OS        ACTUAL STACK FLOW RATE

     ISO       PERCENT ISOKINETIC

     MN        FILTERABLE PART
                 MG. EPA 5

     CS        FILTERABLE PART

     PMR       FILTERABLE PART
                 EMISSION RATE

        *  68 DEC F,  29.92 IN.HG.
29.86
-1.20
29.77
S24.
18.9
7466.
1628613.
3519316.
111.7
.0
IN-HG
IN-H20
IN-HG
F
FPS
SQ-IN
SCFH
ACFH


.0000 GR/DSCF*
.000
LB/HR
758.44
-30. 4B
756.20
274.
5.7
4.817
46117.
99656.
111.7
.0
.000
.00
CM-HG
*M-H20
»N-HG
C
*P3
30-M
SCMH
»C*H


VG/DSCI
KG/HH
Ul
VO

-------
           EXAMPLE PARTICULATE  CALCULATIONS  TEST  NO.    5-1

                N01 COKE BATTERY  OUTLET



     VOLUME OF DRY GAS SAMPLED  AT  STANDARD CONDITIONS

     VMSTD «  (17.647 * VM *  Y *  (PB  * PM  / 1J.6))  /  (TM «•  460.)

               17.647 •    56.981  «  1.003 *  (  29.86  *   .716  /  13.6)
     VMSTD *  ————————*-— — — - — - — ---- —	.....  -      58.031 OSCF
                              (   60. + 460.)



     VOLUME OF MATER VAPOR AT STANDARD CONDITIONS

     VMC » .04707 * VLC

     VWC * .04707 •  18$. »   8;«*0 SCF



     PERCENT  MOISTURE IN STACK  GAS

     BMO « (100. * VMC) / (VMSTD  * VWCJ

               100. •   8.90
     BMO = ————————— > 13.30  PERCENT
>                SB.031 *    B.90


O
     MOLE FRACTION OF DRY STACK GAS

     FMD * (100. • BMO) / 100.

               10
-------
      STACK GAS VELOCITY AT STACK CONDITIONS

      DELP • SUM.  OF THE SQRT(VH * (TS » 460.))

      VS 3 SS.49 • CP • DELP / (SQRT(MMS * PS)  * PNTS)

      VS • 05.49 *  .84 •   90.411 / (SORT( 87.66 • 29.77)   *  12. =   18.65 FPS



      STACK GAS VOLUMETRIC FLON AT STACK CONDITIONS

      OS > VS * AS • 3600/144

      OS «   18.85 •  7466. 3600/144 •    3519316. ACFH



      STACK GAS VOLUMETRIC FLON AT STANDARD CONDITIONS

      03STD « 17.647 • OS • PS • (1. - (BMO/166)) / (TS * 460.)

                17.647 •    3519316. *  29.77 * (1. • (13.30/100))
      QSSTD = ——--————-—— — — --——— ———	 s    1628613.  SCFH
                         ( 524. «• 460.)



      PERCENT ISOKINETIC
>
jL     ISO • (305.5S*(TS«460.))*((0.002669*VLC)«(VM*Y*(PB«(PM/13.6))/(TM4460.)))/(TT*VS*PS*DN*DN)
CTl                                            _
H            (305.S0*( 524.*460.))*((0.002669*   109.)+(   56.981*t.003*(  29.06*(    .716/13.6))/(   60.4460.)))
      ISO * ......	.........	...	........	.......	.......	s 111.67 PERCENT
                                         115. *     18.85 •   29.77 *   .390  *   .340



      PARTICULATE  LOADING — EPA METHOD 5 (AT STANDARD  CONDITIONS)

      CS * 0.001 * MN * 15.43 / VMSTO

      CS * 0.001 *      .0 * 15.43 /    58.031  *     .000 GR/DSCF



      PARTICULATE  LBS/MR — EPA METHOD 5

      PMR « CS  • OSSTO / (15.43 * 453.6)

      PMR •     .000 *    1620613. / (15.43 • 453.6) =       .00

-------
Run No.  5.1
     Sample  volume =1.64 m3. 58.03  scf
Example  calculations
     CS  (Part) =138.6/1.64 = 84.5  mq/m3
     CS  (Part) = 0.001 x138.6x 15.43/  58.03=  0.037  qr/dscf
                                    3
     CS (S02)  =2070/1.64=  1262mg/nT
              = 1262 x 24.06/64  = 474 ppm
              = 0.001 x2070  x 15.43/58.03
0.550 gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


138.6






85.6
117.0
2070

34.4



3 Concentration,
mg/m


84.5






52.2
71.3
1262

21.0



gr/dscf


0.037






0.023
0.031
0.550

0.009



ppm











474

5



                                     A-162

-------
                                                             FIELD  DATA
CTl
U)
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION NO.l COKE BATTERY OUTLET
SAMPLE TYPE PANT
OPERATOR BRUFFEY
AMBIENT TEMP. (DEC. F) 52.
BAR. PRESS. (IN. HG) 29.86
STATIC PRESS. (IN. HZO) -1.20
FILTER NUMBER(S) 3530113
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .011 CFM 3 23.0 IN.HG
METER CALIB. FACTOR 1.004
READ & RECORD DATA EVERT 10.0 MINUTES
TRAVERSE
POINT
NO.

1NIT











SAMPLE
TIME
(MIN.)

0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
CLOCK
TIME
(24-HR
pi nr v i
ILUtn J
943
953
1003
1013
1023
1033
1043
1053
1103
1113
1123
1133
GAS METER
READING
(CU.FT.)

101.037
105.700
110.380
115.030
119.330
123.990
128.300
132.610
136.900
142.830
147.070
151.348
VELOCITY
HEAD
(IN.H20)

	
.060
.060
.060
.050
.060
.050
.050
.050
.200
.050
.050
ORIFICE
PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.73
.73
.73
.62
.73
.62
.62
.62
1.22
.62
.62
H20)
ACTUAL

.73
.73
.73
.62
.73
.62
.62
.62
1.22
.62
.62
STACK
TEfP
IDEG.F)


536.
548.
507.
520.
533.
521.
536.
549.
510.
522.
536.
DATE 10/29/81
HUN NUMBER 5-2
PHUBE LENGTH S TYPE 4* HEATED GLASS
NOZZLE : I.I). .397
ASSUMED MOISTURE 12.0
SAMPLE BUX NUKBER 0
CETEH BOX NUMBtH F10
HETER HEAD D1FF. 1.80
C FACTOR .86
PROBE HEATER SETTING 250.
HEATER BOX SETTING 250.
REFERENCE PRESS. OIFF. .15
DRY GAS METER
TEMP
(OkG.F)
INLET OUTLET

58. 58.
60. 58.
b2. 58.
66. 60.
67. 61.
69. 61.
70. 63.
71. 64.
72. 65.
75. 66.
75. 67.
PUHP
VACUUM
(IN.HG)


2.0
2.5
2.0
2.5
3.0
3.0
2.5
3.0
3.0
4.0
8.0
SAMPLE
BOX TEMP
(UEG.F)


261.
270.
253.
253.
252.
251.
246.
251.
250.
256.
249.
IMPINGEW
TEMP
(DEG.F)


40.
40.
4U.
42.
43.
42.
47.
49.
51.
50.
55.
    TOTALS
    AVERAGE
110.0
50.311
                                          .71
                                .71
529.
68,
62.
3.2   254.
45,

-------
           PARTICIPATE FIELD DATA & RESULTS TABULATION
PLANT- NAME AND ADDRESS               TEST TEAM LEADER
REPUBLIC STEEL CLEVELAND              BRUFFEY
TEST
        5-2
NO.l COKE BATTERY OUTLET
ENGLISH UNITS
TEST
TB
TF
TT
NP
Y
DN
CP
PM
DATE
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
10/29/81
443
1133
110
11
1

_

.0

.044
.397 IN
.64
.71 IN-H20
METRIC UNITS
10/29/61
943
1133
110
11
1
10

16
.0

.044
.1
.84
.1



KM

PM-I
          DROP

VM        VOLUME OF DRV GAS SAMPLED
          AT METER CONDITIONS

TM        AVERAGE GAS METER TEMP

VMSTD     VOLUME OF DRV GAS SAMPLED
          AT STANDARD CONDITIONS*

VLC    '"  TOTAL HiO COLLECTED IN
          IMPINGERS AND SILICA GEL,ML,

VHC       VOLUME OF MATER VAPOR
          AT STANDARD CONDITIONS*

8WO     ~  PERCENT MOISTURE BY VOLUME

FMD       MOLE FRACTION DRV GAS

PC02      PERCENT C02 BY VOL., DRY

P02       PERCENT 02 BY VOL., DRY

PCO       PERCENT CO BY VOL., DRY

PN2       PERCENT N2 BY VOL., DRY

MO        MOLECULAR MT-ORY STACK GAS

MMS       MOLECULAR XT-STACK GAS
                                           50.311 CU-FT


                                           64.6   F

                                           52.630 SCF
                                            6.256 SCF
                                                 1.425 CU-M


                                                16.2   C

                                                 1.496 SCM


                                               175.4


                                                  .234 SCM
13.52
.665
4.30
11.30
.00
84.40
29.14
27.63
13.52
.665
4.30
11.30
.00
84.40
29.14
27.63

-------
PB        BAROMETRIC PRESSURE

PS1       STATIC PRES OF STACK GAS

PS        STACK PRES* AB3.

TS        AVERAGE STACK TEMP

VS        AVG STACK GAS VELOCITY

A8        STACK AREA

OSSTD     STACK FLOW RATE. DRY*

OS        ACTUAL STACK FLO* RATE

ISO       PERCENT ISOKINETIC

MM        FILTERABLE PART
            MG. EPA 5

CS        FILTERABLE PART

PMR       FILTERABLE PART
            EMISSION RATE

   *  68 DEC F,  29.92 iN.HG.
     29.86  IN-HG

     •1.20  IN-H20

     29.77  IN-HG

    529.    F

     19.8   FPS

   7466.   SO-IN

1698186.    SCFH

3695966.    ACFH

    102.4

       .0


       .0000 GR/DSCF*

       .000   LR/HR
   758.44  PM-HG

   -iO.46  P

   756.20  fM-HG

   276.    C

     6.0   fPS

     4.617 3U-M

 4A088.    SCCH

104659.    *CKH

   102.4

      .0


      .000 PG/DSC*

       .00  KG/Hk

-------
              EXAMPLE PARTICIPATE CALCULATIONS TEST NO.   5-2

                   NO.l COKE BATTERY OUTLET



        VOLUME OF DRY GAS SAMPLED AT STANDAHD CONDITIONS

        VMSTD » (17.647 • VM * Y • (PB + PM / 13i6)) / (TM «• 060.)

                  17.647 •    SO.311 « 1.044 * ( 29.86 *  .715 / 13.6)
        VMSTO • ——————........................	..	.	. -     52.830  OSCF
                                 (  65. * 060.)




        VOLUME OF MATER VAPOR AT STANDARD CONDITIONS

        VNC  » .04707  * VLC

        VNC  « .04.707  *  17S. *   8.26 SCF




        PERCENT MOISTURE IN STACK GAS

     ""  BNO  » (100.  * VHC)~7 (VMSTD * VNC)

                  100. •   8.26
jjy       BNO  « ——————	....... r  13.52 PERCENT
 I                   52.830 *   8.26
I-"


        MOLE FRACTION OF DRY STACK GAS

        FMD  * (100.  - BMO) / 100.

                  100. -  13.5
        FMD  a ——————— •   .865
                       100.



        AVERAGE MOLECULAR HEIGHT OF DRV STACK GAS

        MD « (PC02 •  .44) *  (P02 • .32) * (PN2 * PCO) * .28

        MD « ( 4.30«44/100)  * (11.3*32/100) * ((84.4* .0) * 28/100 =   29.14




        MOLECULAR HEIGHT OF  STACK GAS

        MNS  3 MD * (1. - (BHO/100)) » 18. « (BNO/100)

        MNS  •  29.140 (l. .(13.52/100)) * 18. *  (13.52/100) »   27.63

-------
    STACK 6AS VELOCITY AT STACK CONDITIONS

    DELP • SUM. OF THE SORTIVH • ITS » 060.))

    VS » 65.09 * CP * OELP / (SORT(MHS * PS) * PNTS)

    VS « 65.49 *  .84 «   66.999 / (SORT( 37.63 « 29.77)  *  11. =   19.60 FP3



    STACK GAS VOLUMETRIC FLO* AT STACK CONDITIONS

    OS * VS • AS • 3600/144

    OS •   19.60 *  7466. 3600/144 a    3695966. ACFH



    STACK 6AS VOLUMETRIC FLOW AT STANDARD CONDITIONS

    OSSTD » 17.647 • OS • PS • (1. - (6*0/100)) / (TS * 460.)

              17.647 •    3695966. •  29.77 • (1. - (13.52/100))
    OSSTD • ————— — — — ——————	 r    1690186. SCFH
                       I 529. «• 460.)



    PERCENT ISOKINETIC
>
jL   ISO « (305.58«(TS*460.))M(0.002669«VLC)*(VM«Y»(PB*(PW/13.6))/(TM*460.)))MTT«VS*P9«DN*DN)

-J          (305.58M 529.»460.))*t(0.002669*  175.)»(   50.311*1.044*( 29.86+(    .715/13.6))/(  65.4460.)))
    ISO * ..—————.	..........	..	.	..	.	.... *  102.36 PtRCEM
                                       110. *     19.80 •   29.77 *  .397 •  .397



    PARTtCULATE LOAOlNfc — EPA METHOD 5 (Af STANDARD CONDITIONS)

    CS > 0.001 * MN • 15.43 / VMSTO

    CS > 0.001 *      .0 * 15.43 /    52.630 e     .000 GR/DSCF



    PARTICIPATE LBS/HR — EPA METHOD 5

    PMR • CS • QSSTD / (15.43 * 453.6)

    PMR c     .006 *    1696186. / (15.43 * 453.6) «      .00

-------
Run No.   5.2
     Sample volume = 1.50  m .  52.83  scf
Example calculations
     CS (Part) = 185.6/ 1.50= 123.7 mq/m3
     CS (Part) = 0.001  x 185.6 x 15.43/52.83  =  0.054  qr/dscf
                                      3
     CS (S02)  =	/	=	mg/m
               =	 x 24.OS/	=	ppm
               = 0.001 x	x 15.43/	
gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sulfates
As H2S04
As H2S04.2H20
Sulfur dioxide

Sulfuric acid mist
As H2S04
As H2S04-2H20
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


185.6
36.8





3.0
4.1





19.0
4.2
58.1
2 Concentration,
mg/m


123.7
24.5





2.0
2.7





12.7
2.8
38.7
gr/dscf


0.054
0.011





0.0008
0.001

1



0.006
0.001
0.017
Ppm



















                                     A-168

-------
                                                             FIELD  DATA
M
CT>
VO
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION COKE OVEN OUTLET
SAMPLE TYPE S-3-MB-350
OPERATOR CLARKE
AMBIENT TEMP.(DEG.F) 52.
BAR. PRESS. (IN. HG) 29.06
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530073
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .04
THERM. NO.
LEAKAGE .000
METER CALIB. FACTOR .992
READ » RECORD DATA EVERY 10.0
TRAVERSE SAMPLE CLOCK GAS METER
POINT
NO.

IN if"'












TIME
(MIN.)

6
10.0
20.0
30.0
40.0
50.0
60.0
70.0
60.0
90.0
100.0
110.0
115.0
TIME
(24-HR
f i fif* tf t
LLUCK J
940
950
1000
1010
1020
1030
1040" "
1050
1100
1110
1120
1130
it35
READING
ICU.FT.)

616.015
621.635
626.300
631.020
635.502
639.909
644.604
649.300
653.003
659.305
663.440
666.370
670.591
CFM 8 3.
MINUTES
VELOCITY
HEAD
(IN.H20)



.060
.060
.060
.050
.060
.060
.050
.050
.100
.050
.050
.050
0 IN.HG
ORIFICE
PRESSUKE
DIFFERENTIAL
(IN.
DESIRED

.73
.T3
.73
.62
.73
.73
.62
.62
1.20
.62
.62
.62
H20)
ACTUAL

.73
.73
.73
.62
.73
.73
.62
.62
1.20
.62
.62
.62
STACK
TEI*P
(DEG.F)
DATE 10/29/01
HUN NUMBER b-3
PROBE LENGTH ft TYPE 5 FT GLASS HEATED
NUZZLE t I.D. .394
ASSUMED MOISTUHE 12.0
SAMPLE BOX NUMBER
PETER BOX NUMBER FBI
KETER HEAD DIFF. 1.87
C FACTOH .80
PROBE HEATER SETTING 350.
HEATER BOX SETTING 350.
REFERENCE PRESS. OIFF. 1.50
OHY GAS METEH PUMP SAMPLE IMPINGEH
TEMP
IOEG.F)


VACUUM
(IN.HG)
BOX TEMP
(OEG.F)
TEMP
(OEG.F)
INLET OUTLET

530.
543.
556.
510.
530.
540.
531.
546.
505.
519.
530.
495.

55.
50.
60.
65.
67.
60.
70.
73.
76.
80.
00.
80.

SO.
51.
51.
52.
54.
54.
56.
60.
61.
64.
64.
64.

2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.5
2.0
2.0
2.0

301.
362.
352.
342.
356.
358.
350.
359.
359.
354.
340.
351.

50.
44.
««.
48.
50.
56.
58.
52.
5o.
52.
56.
54.
    TOTALS
    AVERAGE
115.0
53.776
                                          .71
                                ,71
529.
69.
57,
2.0   349.
51,

-------
           PARTICIPATE FIELD DATA A RESULTS TABULATION




PLANT- NAME AND ADDRESS               TEST TEAM LEADER




REPUBLIC STEEL CLEVELAND              CLARKE
TEST
5-3
COKE OVEN OUTLET


TEST DATE
TB
TF
TT
NP
V
ON
CP
PM
1 VM
O
TM
VMSTO
VLC
VNC
BHO
FMO
PC02
P02
PCO
PN2
MO
MNS
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H20 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF NATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRV GAS
PERCENT C02 BY VOL., DRY
PERCENT 02 BY VOL., DRY
PERCENT CO BY VOL., DRY
PERCENT N2 BY VOL.* DRV
MOLECULAR NT-DRY STACK GAS
MOLECULAR NT-STACK GAS
ENGLISH UNITS
10/29/81
940
1135
115.0
12
.992
.394 IN
.84
.71 IN-H20
53.776 CU-FT
63.0 F
53.638 SCF
8.915 SCF
r«Y2i
.858
4.30
11.30
.00
84.40
-29. 10
27.56
METRIC UNITS
10/29/81
940
1135
115.0
12
.992
10.0
.84
18.1
1.523
17.2
1.525
189.4
.252
14.21
.858
4.30
11.30
.00
84.40
29.14
27.56



PM

MM-H2U
CU-M
c
SCM
SCM









-------
PB        BAROMETRIC PRESSURE

P8I       STATIC PRES OF STACK GAS

PS        STACK PRES, ABS.

TS        AVERAGE STACK TEMP

VS        AVG STACK GAS VELOCITY

A8        STACK AREA

Q33TD     STACK FLON RATE, DRY*

OS        ACTUAL STACK FLON RATE

ISO       PERCENT ISOKINETIC

MN        FILTERABLE PART
            MG. EPA 5  ________

CS        FILTERABLE PART

PMR       FILTERABLE PART
            EMISSION RATE
     29.86  IN-HG

     -t.20  IN-H20

     Z9.77  IN-HG

    529.    F

     16.9   FPS

   7066.   30-IN

1611199.    SCFH

3533728.    ACFH

    106.8

       .0


       .0000 GR/OSCF*

       .000   LB/HH
   758.Ofl  CM-HG

   •30.08  PM-H2U

   756.20  PM-HG

   276.    C

     5.8   >»PS

     a.817 SO-M

 05620.    3CHH

100065.    ACMH

   106.6

      .0


      .000 fG/DSC"

       .00  KG/HR
   •  68 DEC F,  89.92! iN.MG.

-------
             EXAMPLE PARTICULATE CALCULATIONS TEST NO.   5-3

                  COKE OVEN OUTLET




       VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

       VM8TO • (IT.647 • VM * Y * (PB * PM / 1J.6)J / ITM * 460.)

                 17*647 •    53.776 *  .992 * ( 29.86 *  .714 / 13.6)
       VMSTD « ——————.—————•———— ———-- =     53.838 DSCF
                                I  63. * 460.)



       VOLUME OF MATER VAPOR AT STANDARD CONDITIONS

       VNC  * .04707 * VLC

       VNC  • .04701 •  f89. » "8.92 SCF




       PERCENT MOISTURE IN STACK GAS

       8NO  » (100.  • VNC) T (VMStO * VNC)

                 100. *   8.92
>      BHO  » ......	—	......... > 14.2i PERCENT
 I                  53.838 «•   8.92
(-•

NJ

       MOLE FRACTION OF DRY STACK GAS

       FMD  * (100.  - BMO) / 100.

                 100."-~"H,Z   "
       FMD  • ——	............... •   .858
                      100.




       AVERAGE MOLECULARHEIGHT OF D«Y STACK GAS

       MO » (PC02 * .44) • (P02 • .32) » IPN2 4 PCO) * .28

       MD * ( 4.30*44/100) 4 (11.3*32/100) * ((84.0* .0) * 28/100 *   29.14




       MOLECULAR WEIGHT OF STACK GAS

       MNS  • MD * (1. - (BNO/100)) 4 18. * (BNO/100)

    ~  MNS  «  29.14* (1. -(14.21/100)) « 18. *  (14.21/100) a   27.56

-------
STACK GAS VELOCITY AT STACK CONDITIONS

DELP • SUM. OF THE 80RTCVH *  US » 460.))

VS * 85.49 * CP * OELP /  (SORMMHS * PS) * PNTS)

VS * 85.09 *  .84 •   90.615  /  (SORT( 27.56 * 29.77)  *   12. s    18.93 FPS



STACK GAS VOLUMETRIC FLO* AT  STACK CONDITIONS

OS * VS • AS • 3600/144

OS •   18.93 •  7466. 3600/144  «    3533728. ACFH



STACK GAS VOLUMETRIC FLOW AT  STANDARD CONDITIONS

OSSTO • 17.647 * 03I • PS • (iT- (B«0/106j) / (TS «• 460.)

          17.647 •    3533728.  •  29.77 • (1. - (14.21/100))
OSSTO » ——————•	——	.......	r     1611199. SCFH
                   ( 529. + 460.)
PERCENT ISOKINETIC

ISO « (305.58MTS*460.))*((0.002669*VLC)+(V**Y*(PB+(PM/13.6))/(TM4460.)))/(TT*VS*PS*ON*ON)
       (305.58*( 529V«46d.))*((0.002669l  l89.)*l   53.776* ,992«( 29.86»(    .7K/13.6) ) /(  63.«460.)))
ISO • .——.———— ........ ---- ........ --- ........ ------------ . ------ . ---- .... -------- .. -------- ... z  106.77 PEHCEN1
                                   115. *     18.93 *   29.77 •  .391 *  .394



PARTICIPATE LOADING •• EPA METHOD 5 (At "STANDARD CBNDfTiONSl

CS « 0.001 * MN • 15.43 / VMSTO

CS « 0.001 *      .0 * 15.43 /    53.838 *     .000 GH/OSCF



PARTICULATE LBS/HR — EPA METHOD 5

PMR « CS * OSSTD / (15.43 * 453.6)

PMR «     .600 •    mtl99. / U5.43 
-------
Run No.  5.3
     Sample volume =1.53 m3r53.84  scf
Example calculations
     CS (Part) =50.5 /I.53 = 33.0   ma/
m
     CS (Part) = 0.001  x 50.5  x 15.43/53.84  = 0.014  qr/dscf
     CS (S02)  = 1970/1.53  = 1287  mg/m3
               = 1287  x 24.06/64   = 484pom
               = 0.001  x 1970  x 15.437 53.84 = O.B64 gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04..2H20
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


50.5






9.5
13.0
1970

81.5



- Concentration,
mg/m


33.0






6.2
8.5
1288

53.3



gr/dscf


0.014






0.003
0.004
0.564

0.023



ppm











484

13



                                  A-174

-------
                                                            FIELD  DATA
U1
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION COKE OVEN OUTLET
SAMPLE TYPE 5-4-MS-350
OPERATOR CLARKE
AMBIENT fEMP.TOE6.FJ 52.
BAR. PRESS. (IN. HG) 29.86
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER (3) 3530107
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM 9 3.0 IN.HG
METER CALIB. FACTOR 1.016
READ * RECORD DATA EVERT 10.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY ORIFICE PRESSURE
POINT
NO.

INlf












TIME
(MIN.)

0 "
10.0
20.0
30.0
ao.o
SO.O
60.0
70.0
80.0
90.0
100.0
110.0
112.0
TIME
(24-HR
n uric i
UUUln t
943
953
1003
1013
1023
1033
1043
1053
1103
1113
1123
1133
1135 ~
READING
(CU.FT.)

38.568
43.355
47.374
52.310
56.333
60.739
64.726
69.205
73.425
79.230
83.320
87.690
86.721
HEAD
(IN.H20)

	
.060
.060
.060
.050
.060
.050
.050
.050
.100
.050
.050
.050
DIFFERENTIAL
(IN.
DESIRED

.73
.73
.73
.62
.73
.62
.62
.62
1.20
.62
.62
.62
H20)
ACTUAL

.73
.73
.73
.62
.73
.62
.62
.62
1.20
.62
.62
.62
STACK
TEKP
(DEG.F)


536.
546.
507.
520.
531.
510.
535.
548.
510.
522.
536.
515.
DATE 10/27/81
RUN NUMBER 5-4
PROBE LENGTH ft TYPE 6 FT GLASS HEATED
NOZZLE < I.D. .396
ASSUMED MOISTURE 12.0
SAMPLE BOX NUMBER 1
PETER BOX NUKBfcR FB5
PETER HEAD DIFF. 1.86
c FACTOR .88
PROBE HEATER SETTING 350.
HEATER BOX SETTING 350.
HEFERENCE PRESS. DIFF. 1.50
DRY GAS METER PUMP SAMPLE IMPINGE"
TEMP VACUUM
(DEG
INLET

60.
61.
64.
68.
70.
74.
78.
80.
84.
87.
80.
69.
.F) (IN.HG)
OUTLET

60.
60.
60.
61.
63.
65.
68.
72.
75.
77.
80.
60.
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
BOX TEMP
(DEG.F)


300.
395.
377.
370.
363.
364.
364.
373.
371.
376.
367.
369.
TEMP
(OEG.F)


38.
38.
40.
40.
42.
46.
48.
46.
48.
50.
50.
46.
    TOTALS
    AVERAGE
112.0
50.153
                                         .70
                               .70   527.
75.
66.
1.0   366.
45.

-------
           PARTICIPATE FIELD DATA ft RESULTS TABULATION




PLANT- NAME AND ADDRESS               TEST TEAM LEADER




REPUBLIC STEEL CLEVELAND              CLARKE
TEST
COKE OVEN OUTLET

TEST DATE
TB
TF
TT
NP
V
ON
CP
PM
VM
TM
VMSTD
VLC
VHC
BMO
FMD
PC02
P02
PCO
PN2
MD
MNS

TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
P1TOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H20 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF HATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL., DRY
PERCENT 62 BY 'VOL., BUY
PERCENT CO BY VOL., DRV
PERCENT N2 BY VOL., DRV
MOLECULAft NT-DRY STACK GAS
MOLECULAR NT-STACK GAS
ENGLISH UNITS
10/27/81
943
1135
112.0
12
1.016
.396 IN
.84
.70 IN-H20
50.153 CU-FT
71.5 F
50.606 SCF
171.0
8.049 SCF
13.72
.863
4.30
11.30
.00
84.40
29.14
27.61
METRIC UNITS
10/27/81
943
1135
112.0
12
1.016
10.1
.84
17.9
1.420
21.9
1.433
171.0
.228
13.72
.863
4.30
11.30
.00
84.40
29.14
27.61



MM

*M-H
CU-M
c
SCM

SCH









-------
PB        BAROMETRIC PRESSURE

PSI       STATIC PRES OF STACK CAS

PS        STACK PRES, ABS.

TS        AVERAGE STACK TEMP

VS        AVG STACK GAS VELOCITY

AS        STACK AREA

Q3STO     STACK FLOW RATE* DRY*

QS        ACTUAL STACK FLOW RATE

ISO       PERCENT I30KINETIC

MN        FILTERABLE PART
            MG. EPA 5

CS        FILTERABLE PART

PMR       FILTERABLE PART
            EMISSION RATE

   *  68 PEG F>  24.92 IN.MG.
     29.6b  IN-HG

     -1.20  IN-H2U

     29.77  IN-HG

    527.    F

     18.8   FPS

   7466.   SQ-IN

160837%.    SCFH
3500352.

    102.2

       .0
ACFH
       .0000 GR/DSCF*

       .000   LB/HR
  758. <4«  CM-HG

  -so. ae  M

  756.20  >>M-HG

  275.    C

    5.T   >»PS

    4.817 30-M

assao.    SCHH

99119.    ACKIH

  102.2

     .0
                .000

                 .00  KG/HH

-------
              EXAMPLE  PARTICULATE  CALCULATIONS  TEST  NO.    5-4

                   COKE  OVEN  OUTLET



        VOLUME OF  DRY  GAS  SAMPLED  AT  STANDARD CONDITIONS

        VMSTD  « (17.647  *  VM  •  T * (PB  »  PM  / 13.6))  /  (TM > 460.)

                  17.647 *    50.153  *  1.016 «  (  24.86  *   .705  /  13.6)
        VMSTD  » ————————-—-——-—......	— =     50.606 DSCF
                                I  72. * 460.)



        VOLUME OF  HATER  VAPOR AT STANDARD CONDITIONS

        VKC «  .0*707 * VLC

        VKC «  .04707 *   171.  a   «U05~3CF



        PERCENT MOISTURE IN STACK  GAS

        B*0 «  (100. •"~VMC) /  TVMSTD * VNC)

>                 too. *   a.os
I       BMO »  ————	...........  * 13.72  PERCENT
^                  50.606 *   8.05
oo    .


        MOLE FRACTION  OF DRY  STACK GAS

        FMD *  (100. -  BNO) /  100.

           ~      100. -13.7
        FMO •  .-.———————— 9    .863
                      100.



        AVERAGE MOLECULAR WEI6HT OF DRY StACK GAS

        MD * (PC02  * .44) • (P02 * .32) * (PN2  «•  PCO) *  .28

        MO * (  4.30*44/100) * (11.3*32/100)  * ((84.0+ .0)  * 28/100  =   29.14



        MOLECULAR  HEIGHT OF STACK  GAS

        MNS s  MD *  (1. - (BHO/100)) *  IB. *  (BMO/100)

        MMS «   29.14*  (1. -(13.72/100)) * 18. *  (13.72/100) *   27.61

-------
      STACK  GAS VELOCITY AT STACK CONDITIONS

      OELP • SUM.  OF THE SQRftVH • ITS » 460.))

      VS • BS.49 • CP * OELP /  (SORT(MHS * PS)  * PNTS)

      VS * 65.49 *  .84 *   89.647 /  (SORT! 27.bl • 29.77)   *  12.  =   10.75 FPS



      STACK  GAS VOLUMETRIC  FLON AT STACK CONDITIONS

      OS • VS • AS * 3600/144

      OS *   18.75 *  7466. 3600/144  s    3506352.  ACFH



      STACK  GAS VOLUMETRIC  FLON AT STANDARD CONDITIONS

      03STO  » 17.647 • OS * ~PS  • U.  - (BNO/100)) / (TS * 460.)

                17.647 •    3500352.  •  29.77  •  11. • (13.72/100))
      QSSTO  * -—.———— ———— —........	.	...  =    Ib0837b.  SCFH
                         (  527. «• 460.)



>    PERCENT ISOKINETIC

!~J    ISO *  (305.58*(TS*460.))«((0.002669*VLC)*(VM*Y*(PB*(PM/13.6))/(TM+460.)))/(TT«V3«P3«»DN*ON)
vo
             (305.58»( 527.*460.))*((0.002669*   171.J*(   50.153*1.016*(  29.86*(    .705/13.6))/(   72.+460.)))
      ISO •  ———•———.——.——..................................	............................. s 102.19 PEHCEN1
                                         112.  *      18.75 *    29.77 •   .396  *  .396



      PARflCULATE  LOA6INB -S EPA METHOD  5 (AT  STANDARD  CONDITIONS)

      CS * 0.001  • MN • 15.43 / VMSTD

      CS * 0.001  *      .0  • 15.43 /     50.606  s     .000 GR/DSCF




      PARTICIPATE  LBS/HR " EPA METHOD 5

      PMR *  CS  *  OSSTD / (15.43 * 453.6)

      PMR »      .000 •   1608375.  /  (15.43 •  453.6) a       .00

-------
Run No. 5.4
     Sample volume = 1.43 m r  50.61  scf
Example calculations
     CS (Part) = 32.I/  1.43= 22.4  tna/m3
     CS (Part) = 0.001  x 32.1  x 15.43/50.61
     CS (S02)  =	/	=	mg/m3
               =	 x 24.06/	=	ppm
               = 0.001  x	x 15.437	
0.010 gr/dscf
      gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Sulfur dioxide
Sulfuric acid mist
As H2S04
As H2S04-2H20
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


32.1






0.0
0.0




101.2
3.2
49.2
2 Concentration,
mg/m


22.4






0.0
0.0




70.8
2.2
34.4
gr/dscf


0.010






0.0
0.0




0.031
0.001
0.015
ppm


















                                   A-180

-------
                                                              FIELD   OAT*
00
PLANT REPUBLIC STEEL
SAMPLING LOCATION COKE STACK
SAMPLE TYPE METHOD 5-350
OPERATOR DO/MP
AMBIENT TEMP. (DEC. F) 52.
BAR. PRESS. UN. HG) 29.86
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530100
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .004 CFM 9 14.
METER CALIB. FACTOR 1.033
READ * RECORD DATA EVERY 10.0 MINUTES.
TRAVERSE
POINT
NO.

INI?












SAMPLE
TIME
(MIN.)

o
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
M3.7
CLOCK
TIME
(24-HR
PI nf*K i
ILUvn J
945 ~
953
1003
1013
1023
1033
1043
1053
1103
1113
1123
1133
1137
GAS METER
READING
(CU.FT.)

854.767
859.460
864.150
868.850
873.590
878.350
883.170
888.030
692.910
897.820
902.740
907.630
909.368
VELOCITY
HEAD
(IN.H20)

	 -
.070
.070
.070
.070
.070
.070
.070
.070
.070
.070
.070
"" .070
CLEVELAND
0 IN.HG
ORIFICE PRESSURE
DIFFERENTIAL
(IN.H20)
DESIRED ACTUAL

.72 .72
.72 .72
.72 .72
.72 .72
.72 .72
.72 .72
.72 .72
.72 .72
.72 .72
.72 .72
.72 .72
.72 .72
DATE 10/29/81
HUN NUMBER 5-5
PROBE LENGTH * TYPE 6* GLASS
NUZZLE I 1.0. .374
ASSUMED MOISTURE 11.0
SAMPLE BOX NUMBER
KETEH BOX NUMBER FB4
fETEH MEAD DIFF. 1.88
C FACTOR .92
PROBE HEATER SETTING 250.
HEATER BUX SETTING 250.
REFERENCE PRESS. I) IFF. .18
STACK
TE*P
(DEG.F)


520.
520.
520.
520.
520.
S20.
520.
520.
520.
520.
520.
520.
DRY GAS METER
TEMP
(DEG.F)
INLET OUTLET

55. 54.
57. 55.
60. 56.
64. 56.
67. 60.
69. 62.
71. 64.
72. 66.
74. 68.
75. 69.
75. 70.
75. 71.
PUMP
VACUUM
(IN.HG)


0.7
8.7
8.8
.0
.0
.2
.6
.8
.9
10.1
10.7
12.2
SAMPLE
BOX TEMP
(OEG.F)


225.
244.
252.
246.
236.
243.
242.
236.
234.
240.
235.
841.
IMPINGER
TEMP
(DEG.F)


40.
40.
40.
41.
42.
44.
43.
44.
42.
42.
42.
44.
      TOTALS
      AVERAGE
113.7
54.601
                                          .72
                                .72   520,
68.
63.
9.6   240.
42.

-------
           PARTICIPATE FIELD DATA A RESULTS TABULATION




PLANT* NAME AND ADDRESS               TESf TEAM LEADER



REPUBLIC STEEL CLEVELAND              00/MP
TEST
5-5
COKE STACK


TEST DATE
TB
TF
TT
NP
Y
ON
CP
PM
1
M VM
00
N>
TM
VMSTD
VLC
VHC
BHO
FMD
PC02
P02
PCO
PN2
MO
MMS
TIME-STARf
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRV GAS SAMPLED
AT METER CONDITIONS
AVERAGE CAS METER TEMP
VOLUME OF DRY GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H20 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF MATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL.* DRY
PERCENT 02 BY VOL., DRY
PERCENT CO BY VOL., DRY
PERCENT N2 BY VOL., DRY
MOLECULAR MT-ORY STACK GAS
MOLECULAR NT-STACK GAS
ENGLISH UNITS
10/29/61
943
1137
113.7
12
1.033
.374 IN
.84
.72 IN-H20
54.601 CU-FT
65.3 F
56.660 SCF
197.2
9.282 SCF
14.07
.659
4.30
11.30
.00
84.40
" 29.14
27.57
METRIC UNITS
10/29/61
943
1137
113. 7
12
1.033
9.S
.84
18.3
1.546
18.5
1.605
197.2
.263
14.07
.659
4.30
11.30
.00
84.40
29.14
27.57



I'M

MM-H20
CU-M
C
SCM

SCM









-------
    PB         BAROMETRIC  PRESSURE

    P3I        STATIC  PRES OF  STACK  GAS

    PS         STACK PRES,  A83.

    TS         AVERAGE STACK TEHP

    VS         AVG  STACK GAS VELOCITY

    AS         STACK AREA

    QSSTO      STACK FLON  RATE,  ORT*

    OS         ACTUAL  STACK FLON RATE

    ISO        PERCENT ISOKINETIC

    MN         FILTERABLE  PART
               MG. EPA 5

    CS         FILTERABLE  PART

    PMR        FILTERABLE  PART
               EMISSION  RATE

      *  68 DEC F,   39.93 IN.HG.
     29.86  1M-HG

     •1.30  1N-H30

     29.77  IN-HG

    520.    f

     20.8   FPS

   7466.   30-IN

1785009.    SCFH

3674661.    ACFH

    113.9

       .0


       .0000 GR/OSCF*

       .000   LB/HR
   758.44  CM-HG

   -30.48  H

   756.30  PM-HG

   3M.    C

     6.3   CPS

     a.817 SO-M

 50546.    SO'H

109734.    ACK-H

   113.9

      .0


      .000 PG/DSCP

       .00  KG/HR
00
U)

-------
          EXAMPLE PARTICULATE CALCULATIONS TEST  NO.    5-5

               COKE STACK



    VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

    VMSTD * (It.647 • VM * Y *  (PB * PM / 13.6))  /  (TM + 460.)

              17.647 *    54.601 • 1.033 * ( 29.86  »   .720  /  13.6)
    VMSTD « ———————— — —	  s      56.680 OSCF
                             (  65. » 460.)



    VOLUME OF MATER VAPOR AT STANDARD CONDITIONS

    VMC • .04707 • VLC

    VMC • .04707 *  197. •   9.28 SCF



    PERCENT MOISTURE IN STACK GAS

    BMO » (100. * VMC) / (VMSTD «• VMC)

              100. •   9.28
    BNO « ——	—	......... z 14.07 PERCENT
•f               56.680 *   9.28
t-1
CO

    MOLE FRACTION OF DRV STACK GAS

    FMD « (100. • BMO) / 100.

              100. -  14.i~
    FMD * —	————— x   .859
                   100.
    AVERAGE MOLECULAR HEIGHT OP DRY STACK GAS

    MD * (PC02 * .44) * (P02 * .32) »  (PN2 * PCO)  *  .28

    MO * ( 4.30*44/100) • (11.3*32/100) + ((84.4»  .0)  *  28/100  z    29.14



    MOLECULAR NEIGHT OF STACK GAS

    MMS * MO • (1. • (8*0/100)) *• 18.  * (BNO/100)

    MMS •  29.14* (1. -(14.07/100)) +  18. * (14.07/100)  *   27.57

-------
    STACK GAS VELOCITY AT STACK CONDITIONS

    DELP « SUM. OF THE SQRUVH • (TS * 060.))

    VS > 85.49 • CP * OELP / (SORT(MNS * PS) * PNTS)

    VS > 65.49 *  .84 •   99.390 / (SQRT( 27.57 * 29.77)  *  12. =   20.76 FPS



    STACK GAS VOLUMETRIC FLOW AT STACK CONDITIONS

    OS * VS • AS * 3600/144

    OS *   20.76 *  7466. 3600/144 a    3874861. ACFH



    STACK GAS VOLUMETRIC FLON AT STANDARD CONDITIONS

    OSSTO * 17.647 * OS • PS •"(1. - (BNO/iOO)) / (TS * 460.)

              17.647 •    3874861. •  29.77 • (1. • (14.07/100))
    OSSTD «	———	— —	—	s    1765009. SCFH
                       ( 520. * 460.)



>   PERCENT ISOKINETIC

£   ISO • (305.58*(TS«460.))*((0.002669*VLC)+(VM«Y«(PB+(PM/13.6))/(TM»460.)))/ITT«V3«PS«ON«DN)

           (305.58M «0.+460.))*((b.002669*  197.>+(   54.601*1.033*( 29.66«(    .720/13.6))/(  65.+460.)))
    ISO « ———————————————	—	......	—.	.	..	.. • U3.89 PERCENT
                                       114. *     20.76 *   29.77 *  .374 •  .J74



    PARTICIPATE LOADING —"EPA METHOD 5 (AT STANDARD CONDITIONS)

    CS » 0.001 * MN * 15.43 / VMSTD

    CS * 0.001 *      .0 » 15.43 /    56.680 *     .000 GR/DSCF



    PARTICULATE LBS/HR — EPA METHOD 5

    PMR s CS • OSSTO / (15.43 * 453.6)

    PMR *     .000 *    FfaSObT. / (15.43 • 453.6) s      .00

-------
Run No. 5.5
     Sample volume =1.61  m .56.68  scf
Example calculations
     CS (Part) =221.0; 1>61. 137.3 mq/m3
     CS (Part) = 0.001 x_22J_._Ox 15.43/ 56.68= 0.060  qr/dscf
     CS (S02)  =	/	=	mg/m3
               =	 x 24.06/	=	pptn
               = 0.001 x    .  x 15.43/	=	gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Sulfur dioxide
Sulfuric acid mist
As H2S04
As H2S04-2H20
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


221.0
50.4
44.2
36.2
32.3
27.7

0.0
0.0




20.9
6.3
11.8
3 Concentration,
mg/m


137.3
31.3
27.4
22.5
20.1
17.2

0.0
0.0




13.0
3.9
7.3
gr/dscf


0.060
0.014
0.012
0.010
0.009
0.008

0.0
0.0




0.006
0.002
0.003
ppm


















                                    A-186

-------
                                                            FIELD  DATA
            PLANT
            SAMPLING LOCATION

            SAMPLE TYPE
            OPERATOR
            AMBIENT TEMP.(DE6.F)
            BAR.PRESS.(IN.HG)
            STATIC PRESS.(IN.H20)
            FILTER NUMBER(S)
            STACK INSIDE  DIM.(IN)
            PITOT TUBE COEFF.
            THERM. NO.
            LEAKAGE
            METER CALIB.  FACTOR
                     REPUBLIC STEEL CLEVELAND
                     CUKE STACK


                     METHOD 8-600
                     DO/MP
                      52.
                     29.86
                     •1.20
                     3530224

                       97.50    .00
                       .84


                      .000 CFM 9 11.0 IN.HG
                      .982
                                               DATE                      10/29/81
                                               RUN NUMBER                  5-6

                                               PROBE LENGTH s TYPE       4* QUARTZ
                                               NUZZLE      t I.D.         .590
                                               ASSUMED MOISTURE          11.0
                                               SAMPLE BOX NUMBER
                                               PETER BOX NUMBER          FBB
                                               PETER HEAD DIFF.          1.91
                                               C FACTOR                   .94
                                               PROBE HEATER SETTING      250.
                                               HEATER BOX SETTING        250.
                                               HEFERENCE PRESS. DIFF.     .03
            READ » RECORD DATA EVERY 10.0 MINUTES
H1
CO
TRAVERSE SAMPLE CLOCK
POINT TIME TIME
NO. (MIN.) (24-HR
' r*i nf *

INIT d
10.0
20.0
30.0
40.0
50.0
60.0 ~
70.0
80.0
90.0
100.0
110. 0
114.8
bk vvn
942"
952
1002
1012
1022
1032
1042
1052
1102
1112
1122
1132
1137
GAS METER
READING
(CU.FT.)
|
1
309.372
314.030
318.710
323.430
328.160
332.940
337.690
342.440
347.200
351.950
356.770
361.630
"'" 363.907
VELOCITY ORIFICE PRESSURE STACK
MEAD DIFFERENTIAL TEPP
(IN.H20) (IN.H20) (OEG.F)
DESIRED

.070
.070
.070
.070
.070
.070
.070
.070
.070
.070
.070
.070
.44
.44
.44
.44
.44
.44
.44
.44
.44
.44
.44
.44
ACTUAL

.75
.75
.75
.75
.75
.75
.75
.75
.75
.75
.75
.75
DHY GAS METER PUMP SAMPLE
TEMP VACUUM BOX TEMP
(OEG.F) (IN.HG) (OEG.F)
IMPINGER
TEMP
(OEG.F)
I1LET OUTLET

520.
520.
520.
520.
520.
520.
520.
520.
520.
520.
520.
520.

49.
52.
57.
60.
63.
65.
66.
67.
68.
69.
70.
71.

47.
48.
50.
51.
53.
55.
56.
57.
58.
59.
61.
63.

3.3
4.7
5.2
5.4
5.7
6.0
7.5
8.3
9.3
9.6
9.8
10.0

629.
604.
598.
610.
617.
620.
618.
618.
620.
620.
619.
623.

38.
36.
3b.
40.
44.
52.
50.
SO.
48.
44.
44.
48.
    TOTALS
    AVERAGE
114.6
54.535
                                        4.44
                               .75   520.
63.
55.
7.1   616.
44.

-------
           PARTICIPATE FIELD DATA a RESULTS TABULATION



PLANT* NAME AND ADDRESS               TEST TEAM LEADER



REPUBLIC STEEL CLEVELAND              DO/HP
TEST
5-6
COKE STACK

TEST DATE
Tb
TF
TT
NP
T
DN
CP
PM
>
1
I-1 VM
00
00
TM
VMSTD
VLC
VHC
BMO
FMD
PC02
P02
PCO
PN2
MO
MMS


TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OP DRV GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRV GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H20 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF HATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL.* DRY
PERCENT 02 8Y~ VOi;, DRY
PERCENT CO BY VOL.* DRV
PERCENT N2 BY VOL., DRY
MOLECULAR HT-ORY STACK GAS
MOLECULAR NT-STACK GAS
ENGLISH UNITS
10/29/61
942
1137
110.8
12
.982
.590 IN
. .._••«....
.75 IN-H20
54.535 CU-FT
59.0 F
54.477 SCF
178.8
8.416 SCF
13.38
.866
4.30
11.30
.00
84.40
29.14
27.65
METRIC UNITS
10/29/81
942
1137
114.8
12
.982
15.0 KM
.84
19.1 HM-H2U
1.544 CU-M
15.0 C
1.543 SCf
178.8
.238 SCH
13.38
.866
4.30
11.30
.00
84.40
29.14
27.65

-------
    PB        BAROMETRIC PRESSURE

    PSI        STATIC PRES OF STACK GAS

    PS        STACK PRES, AB3.

    TS        AVERAGE STACK TEMP

    VS        AV6 STACK GAS VELOCITY

    AS        STACK AREA

    OSSTD     STACK FLO* RATE* DRY*

    OS        ACTUAL STACK FLOW RATE

    ISO        PERCENT ISOKINETIC

    MN        FILTERABLE PART
                MG. EPA 5

    CS        FILTERABLE PART

    PMR        FILTERABLE PART
                EMISSION RATE

      *   68 PEG Fr  29~.92 iN.HG.
     29.66  IN-HG

     -1.20  IN-H20

     29.77  IN-HG

    520.    f

     20.7   FPS

   7466.   30-1N

1796847.    3CFH
3869468.

     43.3

       .0
ACFH
       .0000 GR/03CF*

       .000   LB/HR
   758.44  *M-HG

   -30.48  PH-H20

   756.20  *M-HG

   271.    C

     6.3   KPS

     4.817 SO-M

 50881.    SCt'H

109572.    ACKH

    43.3

      .0


      .000 f'G/DSCM

       .00  KG/HH
00
VO

-------
            EXAMPLE PARTICIPATE CALCULATIONS TEST NU.   5-6

                 COKE STACK



      VOLUME OF DRV 6AS SAMPLED AT STANDARD CONDITIONS

      VMSTD » (17.647 * VM • Y » (PB « PM / 13.6)) /  CTM + 460.)

                17.647 •    54.535 *  .982 * ( 29.86  *  .750 /  13.6)
      VMSTD * ———————.................—............	=      54.477  OSCF
                               I  59. * 460.)



      VOLUME OF HATER VAPOR AT STANDARD CONDITIONS

      VMC » .04707 • VLC

      VHC * .04707 •  "179. *   8.42 SCF



      PERCENT MOISTURE IN STACK GAS

      BMO • (100. • VHC) / (VMSTD * VHC)

                100. *   8.42
      BHO * ——————........... 3 13.38 PERCENT
>                 54.477 *   8.42
 I
M
MD
O
      MOLE FRACTION OF DRY STACK GAS

      FMO • (100. - BNO) / 100.

                ioo. -is.*
      FMD * --.——..————.- c   .866
                     100.
      AVERAGE MOLECULAR WEIGHT OF DRV STACK GAS

      MD * IPC02 • .44) «• (P02 * .32) * (PN2 * PCO) • .28

      MD « ( 4.30*44/100) » (11.3*32/100) + t(84.0» .0) * 28/100 =   29.14



      MOLECULAR HEIGHT OF STACK GAS

      MHS • MD * (1. • IBHO/100)) * 18. * (BHO/100)

      MHS a  29.14* (i. -(13.38/100)) 4 18. * (13.38/100) =   27.65

-------
     STACK GAS VELOCITY AT STACK CONDITIONS


     OELP • SUM. OF THE SQRT(VH • CT3 t 060.))


     VS * 65.49 • CP * OELP / (SQRT(MMS * PS) * PNTS)


     VS * 65.49 •  .84 •   99.390 / (SQRM 37.65 * 39.77)  *  12. :   20.73 FPS






     STACK GAS VOLUMETRIC FLO* AT STACK CONDITIONS


     OS * VS • AS • 3600/144


     OS *   20.73 *  f466. 3600/144 B    3669466. ACFM






     STACK GAS VOLUMETRIC FLOM AT STANDARD CONDITIONS


     OSSTD • 17.647 • 03 * PS * (1. - (BMO/100))  /     PERCENT ISOKINETIC


£    ISO • (305.S6*(TS*460.))*U0.002669«VLC)«(VM*Y*(PB+(PM/13.6))/(TM+Q60.)))/(TT*V3*PS*DN*ON)
M

            (305.58«( 520.*460.))«((0.002669*  179.)*(   54.535* .9S2*(  29.66*(    .750/13.6))/(  59.4460.)))

     ISO * ————————————.———.———— — — -—— — ---————.- — . — — ..—-. 9  43.28 PEHCENT

                                        115. •     20.73 •   29.77 *  .590  •  .590






     PARTICIPATE LOADING — CPA METHOD  5 (AT STANDARD CONDITIONS)


     CS * 0.001  * MN • 15.43 / VMSTD


     CS • 0.001  *      .0 * 15.43 /    54.477 a     .000 GR/DSCF






     PARTICIPATE LBS/HR — EPA METHOD 5


     PMR * CS •  OSSTO / 115.43 • 453.6)


     PMR «     .000 •    1T96647. / (15.43 • 453.6) *      .00

-------
Run No.  5.6
     Sample volume =1.54 m3r54.48  scf
Example calculations
     CS (Part) =24.9 /I.54 = 16.2   mq/m3
     CS (Part) = 0.001  x 24.9 x 15.437 54.48=  0.007  qr/dscf
     CS (S02)  = 2050/1.54 = 1331  mg/m3
               = 1331  x 24.06/64   = 500ppm
               = 0.001  x 2050 x 15.43/54.48   = 0.581  gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Sulfur dioxide
Sul f uric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


24.9






0.0
0.0
2050

129



, Concentration,
mg/m


16.2






0.0
0.0
1331

83.8



gr/dscf


0.007






0.0
0.0
0.581

0.036



ppm











500

20



                                    A-192

-------
                                                        FIELD  DATA
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION NO.l COKE BATTERY OUTLET
SAMPLE TYPE PAHT/H2S04/S02
OPERATOR BRUFFEY
AMBIENT TEMP. (DEC. F) 75.
BAR. PRESS. (IN.HG) 29.88
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530064
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM 9 5.0 IN.HG
METER CALIB. FACTOR 1.003
READ ft RECORD DATA EVERY 10.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY ORIFICE PRESSURE
POINT
NO.

INIT


i
j
>
)






TIME
(MIN.)

o
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80*0
90.0
100.0
110.0
120.0
TIME
(24-HR

1350
1400
1410
1420
1430
1440
1450
1500
1510
1520
1530
1540
1550
READING
(CU.FT.)

930.535
935.270
940.000
944.750
949.450
954.200
958.990
963.750
968.900
973.670
978.430
983.190
988.325
HEAD
(IN.H20)


.050
.050
.050
.050
.050
.050
.050
.060
.050
.050
.050
.060
DIFFERENTIAL
(IN.
DESIRED

.62
.62
.62
.62
.62
.62
.62
.73
.62
.62
.62
.73
H20)
ACTUAL

.62
.62
.62
.62
.62
.62
.62
.73
.62
.62
.62
.73
STACK
TEPP
(OEG.F)


520.
502.
523.
536.
496.
537.
551.
504.
523.
535.
546.
535.
DATE 10/29/81
RUN NUMBER b-i
PHUBE LENGTH ft TYPE 5* HEATED GLASS
NOZZLE : I.U. .397
ASSUMED MOISTURE 12.0
SAMPLE BOX NUMBER Q
PETER BOX NUMBER FB2
PETEH HEAD OIFF. 1.76
C FACTOR .86
PROBE HtATER SETTING 250.
HEATER BOX SETTING 250.
REFERENCE PRESS. OIFF. .15
DHY GAS METER PUMP SAMPLE IMPINGE*
TEMP
(DEG
INLET

65.
65.
67.
70.
71.
71.
71.
72.
73.
73.
73.
73.
.F)
OUTLET

64.
64.
64.
64.
65.
65.
65.
66.
67.
67.
68.
68.
VACUUM
(IN.HG)


1.5
2.0
2.0
2.5
3.0
3.0
2.5
2.5
2.5
2.5
2.0
3.0
BOX TEMP
(OEG.F)


222.
245.
249.
248.
243.
246.
250.
251.
249.
249.
248.
249.
TEMP
(DEG.F)


49.
52.
53.
54.
52.
SI.
54.
55.
56.
57.
56.
57.
TOTALS
AVERAGE
120.0
57.790
                                         .64
                               .64   526.
                                                                 70.
66.
2.4   246.
54.

-------
           PARTICIPATE FIELD DATA & RESULTS TABULATION




PLANT- NAME AND ADDRESS               TEST TEAM LEADER




REPUBLIC STEEL CLEVELAND              BRUFFEY
TEST
6-1
NO.I COKE BATTERY OUTLET
ENGLISH UNITS
TEST DATE
TB
TF
TT
NP
Y
ON
CP
PM
jL VH

-------
      PB         BAROMETRIC  PRESSURE

      PSI        STATIC  PRES OF  STACK  GAS

      PS         STACK PRES,  ABS.

      TS         AVERAGE STACK TEMP

      VS         AVG  STACK GAS VELOCITY

      AS         STACK AREA

      OSSTD      STACK FLOW  RATE. DRY*

      OS         ACTUAL  STACK FLON RATE

      ISO        PERCENT I90KINETIC

      MN         FILTERABLE  PART
                 MG. EPA 5

      CS         FILTERABLE  PART

      PMR        FILTERABLE  PART
                 EMISSION  RATE

        «  66 DEC F,   29.92 IN.HG.
     39.88  1N-HG
 29.79  IN-HG

526.    F

 17.9   FPS

       3Q-IN

        SCFH

        ACFH
   7466.

1529041.

333*937.

    114.4

       .0
       .0000 GR/DSCF*

       .000   LB/HN
  7b8.95  fM-HG

  -30. «8  CM-H20

  756.71  PM-HG

  274.    C

    5. a   *P3

    a. 817 3Q-M

13298.    SCFH
                     no. a

                        .0
                        .000 MG/03O

                         .00  KG/HR
(Ji

-------
vo
CTi
      EXAMPLE PARTICIPATE CALCULATIONS TEST NO.   6-1

           NO.l COKE BATTERY OUTLET



VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

VMSTD * (17.647 • VM * V * (PB * PM / 15.6)) /  (TM «• 460.)

          17.647 •    57.790 • 1.003 * ( 29.88  *  .638 /  13.6)
VMSTD « —————————— — —	...... :      57.V81  OSCF
                         (  68. » 460.)



VOLUME OF HATER VAPOR AT STANDARD CONDITIONS

VNC * .04707 * VLC

VNC » .04707 •  261. »   9.47 SCF



PERCENT MOISTURE IN STACK GAS

BNO • (100. * VNC) / (VM3TD * VNC)

          100. *   9.47
BNO * —	————— a 14.04 PERCENT
            57.981 »   9.47



MOLE FRACTION OF DRV STACK GAS

FMO « (100. - BNO) / 100.

          100. ^ "14.0
FMD * ————————— •   .860
               100.



AVERAGE MOLECULAR NEieHT OF DRV STACK «s

MD * (PC02 * .44) * (P02 * .32) * (PN2 * PCO) * .28

MO » ( 4.50*44/100) * (10.5*32/100) * ((85.0* .0) * 28/100 =   29.14



MOLECULAR HEIGHT OF STACK GAS

MNS • MD * (1. - (BNO/100)} * 16. * (BNO/100)

MNS *  29.14* (1. -(14.04/100)) * 18. * (14.04/100) *   27.58

-------
     STACK CAS VELOCITY AT  STACK  CONDITIONS

     DELP * SUM. OF THE SQRTIVH *  (TS  *  460.))

     VS » 85.49 * CP • OELP /  (SORT(MHS  *  PS) *  PNTS)

     VS * 65.49 *  .84 •    85.575  /  (SORT( 37.58 *  29.79)   *   12.  =    17.67  FPS



     STACK 6AS VOLUMETRIC FLOH AT  STACK  CONDITIONS

     OS * VS * AS * 3600/144

     OS *   17.87 *  7466.  3600/144  >    3334937. ACFH



     STACK GAS VOLUMETRIC FLON AT  STANDARD CONDITIONS

     OSSTO * 17.647 * OS •  PS • (1.  -  IBMO/100))  /  (TS « 460.)

               17.647 *     3334937.  *  29.79 * (1.  - (14.04/100))
     OSSTO a ————————...............	.....	. =     1529041. SCFH
                        ( 526. * 460.)



     PERCENT ISOKINETIC
>
 I    ISO • (305.58MTS*460.))*l(0.002669*VLC)*(VM*Y*(PB*(PM/13.6))/(TM*460.)))/(TT*VS*PS*DN*ON)
,_,

12           (305.5BM 526.+460.))* ((0.002669"?  2ul.)+(   57.790* 1.003* ( 29.88M    .638/13.6))/(  6B.+460.)))
     ISO * ————.............	......	..	.	.	.....	  H«.37  PEHCEM
                                         120. *      17.87 *   29.79 *   .397 *  .397




     PARfiCULATE LOADING — EPA METHOD 5 (Af STANDARD CONDITIONS)

     CS * 0.001 • MN • 15.43 / VMSTD

     CS * 0.001 *      .0 * 15.43  /    57.981 •     .000 GR/DSCF



     PARTICULATE LBS/HR — EPA METHOD 5

     PMR « CS * OSSTD / (IS.43 • 453.6)

     PMR «     .000 *    1529041.  /  (15.43 * 453.6) =       .00

-------
Run No.  6.1
     Sample  volume =1.64 m3r57.98   scf
Example calculations
     CS (Part)  =184.1 / 1.64* 112.2  mq/m3
     CS (Part)  = 0.001  x 184  x 15.43/57.98 = 0.049  qr/dscf
     CS (S02)   = 2000/ 1.64=1219.5ma/m3
               =1219.5X 24.06/64  = 458ppm
               = 0.001  x 2000  x 15.437 57.98 = 0.532 gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
184.1
71.0
97.0
2000
24.0



3 Concentration,
mg/m
112.2
43.3
59.2
1219.5
14.6



gr/dscf
0.049
0.019
0.026
0.532
0.006



ppm


458
4



                                    A-198

-------
                                                        FIELD  DATA
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION NO.l COKE BATTERY OUTLET
SAMPLE TYPE PART
OPERATOR BRUFFEY
AMBIENT TEMP. (DEG.F) 75.
BAR. PRESS. (IN.HG) 29.88
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBERO) 3530098
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .001 CFM 9 6.0 IN.HG
METER CALIB. FACTOR 1.044
READ ft RECORD DATA EVERY 10.0 MINUTES
TRAVERSE
POINT
NO.
SAMPLE
tIME
(MIN.)
CLOCK
TIME
(24-HR
r*i nf* \
GAS METER
READING
(CU.FT.)
VELOCITY
HEAD
(IN.H2U)
ORIFICE PRESSURE
DIFFERENT
(IN.H20)
IAL

STACK
TEKP
(DEG.F)
OESIKEU ACTUAL
INlf












0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
135)
1403
1413
1423
1433
1443
1453
1503
1513
1523
1533
1543
1553
151.645
156.000
160.350
164.700
169.050
173.420
177.780
182.130
186.860
191.240
195.590
199.910
204.632
. 	
.050
.050
.050
.050
.050
.050
.050
.060
.050
.050
.050
•"" .060

.62
.62
.62
.62
.62
.62
.62
.73
.62
.62
.62
.73

.62
.62
.62
.62
.62
.62
.62
.73
.62
.62
.62
.73

520.
515.
528.
541.
525.
543.
555.
515.
524.
538.
522.
538.
DATE 10/29/81
RUN NUMBER t>-2
PHUBE LENGTH 8 TYPE 4' HEATED GLASS
NOZZLE < l.D. .397
ASSUMED MOISTURE 12.0
SAMPLE BOX NUPHEM 0
PETER BOX NUMBER F10
PETEH HEAD D1FF. 1.80
C FACTOR .86
PROBE HEATER SETTING 250.
HEATER BOX SETTING 250.
REFERENCE PRESS. D1FF. .15
DRY GAS METER
TEMP
(DEG.F)
INLET UUTLET

76. 76.
76. 75.
78. ' 76.
80. 76.
81. 77.
81. 76.
81. 76.
81. 76.
81. 76.
81. 76.
79. 76.
79. 75.
PUMP
VACUUM
(IN.HG)


1.0
1.0
2.0
2.5
3.0
3.0
3.5
3.5
3.0
3.0
3.0
4.0
SAMPLE
BOX TEMP
(DEG.F)


248.
266.
264.
264.
265.
255.
257.
254.
258.
256.
251.
255.
IMPINGER
TEMP
(DEG.F)


50.
50.
52.
53.
51.
53.
55.
57.
59.
61.
61.
62.
TOTALS
AVERAGE
120.0
52.987
                                         .64
                               .64
530.
80.
76.
2.7   258.
56.

-------
              PARTICIPATE FIELD DATA & RESULTS TABULATION

   PLANT- NAME AND ADDRESS               TEST TEAM LEADER

   REPUBLIC STEEL CLEVELAND              BRUFFEY
   TEST
6-2
NO.l COKE BATTERY OUTLET

TEST
TB
TF
TT
NP
Y
DN
CP

DATE
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
ENGLISH UNITS
10/29/81
1353
1553
120.0
12
1.044
.397 IN
.84
METRIC UNITS
10/29/81
1353
1553
120.0
12
1.044
10.1
.84



KM

   PM


^  VM
O
p
   TM
   VMSTD


   VLC


   VNC


   BNO

   FMO

   PC02

   P02

   PCO

   PN2

   MD

   MMS
  AVERAGE ORIFICE PRESSURE
  DROP

  VOLUME OF DRY GAS SAMPLED
  AT METER CONDITIONS

  AVERAGE CAS METER TEMP

  VOLUME OF DRY GAS SAMPLED
  AT STANDARD CONDITIONS*

  TOTAL H20 COLLECTED IN
  IMPINGENS AND SILICA GEL,ML.

  VOLUME OF MATER VAPOR
  AT STANDARD CONDITIONS*

  PERCENT MOISTURE BY VOLUME

  MOLE FRACTION DRY GAS

  PERCENT C02 BY VOL.* DRY

  PERCENT 02 BY VOLiT DRY

  PERCENT CO BY VOL., DRY

  PERCENT N2 BY VOL., DRV

  MOLECULAR HT-ORY STACK GAS

  MOLECULAR NT-STACK GAS
                             .64  IN-H20


                           52.987 CU-FT


                           77.7   F

                           54.332 SCF


                          194.4


                            9.150 SCF
 16.2   PM-H20


  1.500 CU-M


 25.4   C

  1.539 SCM


194.4


   .259
14.41
.856
4.50
10.50
.00
85.00
29.14
27.53
14.41
.656
4.50
10.50
.00
85.00
29.14
27.53

-------
      PB         BAROMETRIC  PRESSURE

      PSI        STATIC  PRES OF  STACK  GAS

      P9         STACK  PRES* AB3.

      TS         AVERAGE STACK TEMP

      V3         AV6  STACK GAS VELOCITY

      AS         STACK  AREA

      OSSTD      STACK  FLO*  RATE,  DRV*

      OS         ACTUAL  STACK FLOM RATE

      ISO        PERCENT ISOKINETIC

      MN         FILTERABLE  PART
                  MG.  EPA 5

      CS         FILTERABLE  PART

      PMR        FILTERABLE  PART
                  EMISSION  RATE

        *  66  DEC F,   29.92 IN.H6.
     29.68  IN-HG

    "-1.20  IN-H20

     29.79  IN-HG

    530.    F

     17.9   FPS

   7«b6.   SQ-IN

1520006.    SCFH

3345471.    ACFH

    107.B

       .0


       .0000 GR/OSCF*

       .000   LB/HR
  758.95  *M-HG

  -30.48  PM-H20

  756.71  *M-HG

  277.    C

    5.5   KPS

    1.817 SQ-M

430fl2.    SCt'H

94734.    ACHH

  107.8

     .0


     .000 ("G/OSCC

      .00  KG/HW
N)
O

-------
               EXAMPLE PARTICIPATE CALCULATIONS TEST NO.   6-2

                    NO.l COKE BATTERY OUTLET



         VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

         VMSTD • (17.647 » VM * Y • CPB * PM / 13.6)) / (TM * 460.)

                   17.647 •    52.967 * 1.044 * ( 29.88 »  .636 / 13.6)
         VMSTD » ——	—	—	......	     51.332  D3CF
                                  (  78. * 460.)



         VOLUME OF MATER VAPOR AT STANDARD CONDITIONS

         VMC « .04707 • VLC

         VMC « .04707 *  194. *   9.15 3CF



         PERCENT MOISTURE IN STACK GAS

         BMO « (100. • VMC) /~(VMSTD * V«C)    ~

•y                  100. •   9.15
I        BNO * ————.—	—. * 14.41 PERCENT
NJ                    54.332 *   9.15
Q
fO            	     -  -	       -          	


         MOLE FRACTION OF DRY STACK GAS

         FMD * (100. - BMO) / 100.

                   100. -  1«.4
         FMD « ———————— *   .856
                        100.



         AVERAGE MOLECULAR WEIGHT OF DRY STACK GAS

         MD  « (PC02 • .44) « (P02 • .32) * (PN2 * PCO) • .28

         MD  * ( 4.50*44/100) * (10.5*32/100) * ((85.0* .0) « 28/100 =   29.14



         MOLECULAR HEIGHT OF STACK GAS

         MMS s MD * (1. • (BMO/100)) + 18. * (BNO/100)

         MMS a  29.14* (1. -(14.41/100)) «• 18. •" (14.41/100) s   27.53

-------
STACK GAS VELOCITY AT STACK CONDITIONS

OELP « SUM. OF THE SQRMVH * (TS » 460.))

V3 * 85.49 * CP • OELP / (SORT(MH3 * PS) * PNTS)

VS * 85.49 •  .84 •   85.781 / (SQRT( 27.53 • 29.79)  *  12. =   17.92 FPS



STACK 6AS VOLUMETRIC FLO* AT STACK CONDITIONS

OS * VS * AS • 3600/144

OS •   17.92 •  7466. 3600/144 a    3345471. ACFH



STACK GAS VOLUMETRIC FLON AT STANDARD CONDITIONS

QSSTO « 17.647 • OS • PS • (i. • (BNO/tVOD / (TS * 460.)

          17.647 •    3345471. •  29.79 • (1. • (14.41/100))
OSSTO « —	——	....	.	=    1520006. SCFH
                   ( 530. » 460.)



PERCENT ISOKINETIC

ISO * (305.58«(TS+460.))«((0.002669«VLC)»(VM*Y*(PB+(PM/13.6))/(TM+460.m/(TT«V3«PS*DN*DN)

       (30S.SB*( 3SO.*460.))*((O.OOZ66W  194.)+(   52.987*1.044*( 29.88+(    .638/13.6))/(  78.+460.)))
ISO « —	.——.—.—	...........	...	...	. i 107.81 PERCENT
                                   120. •     17.92 *   29.79 •  .397 *  .397



PARTlCULATE LOADING — EPA METHOD 5 (AT~8TANOARD CONDITIONS)

CS * 0.001 * MN * 15.43 / VMSTD

CS * 0.001 *      .0 • 15.43 /    54.332 *     .000 GR/DSCF



PARTlCULATE LBS/HR -- EPA METHOD 5

PMR • CS • OSSTD / (15.43 « 453.6)

PMR *     .000 *    1520006. / (15.43 * 453.6) =      .00

-------
Run No.  6.2
     Sample volume  =  1.54m  r 54.33 scf
Example  calculations
     CS  (Part)  =150.8.71.54 =97.9  mq/m3
     CS  (Part)  «  0.001 xl50.8 x 15.43/54.33=0.04.3   qr/dscf
                                     3
     CS (S02)   =	/	=	mg/m
               =	 x 24.06/	=	ppm
               =  0.001 x	x 15.43/	
gr/dscf
Parameter
Particulate following
conditioning at:
Ambient .
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Sulfur dioxide
Sulfuric acid mist
As H2S04
As H2S04-2H20
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


150.8


24.2



0.0
0.0




109.7
4.0
42.3
3 Concentration,
mg/m


97.9


15.7



0.0
0.0




71.2
2.6
27.5
gr/dscf


0.043


0.007



0.0
0.0




0.031
0.001
0.012
ppm


















                                    A-204

-------
                                                              FIELD  OAT*
N)
O
Ul
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION COKE OVEN OUTLET
SAMPLE TYPE 6-3-M8-400
OPERATOR CLARKE
AMBIENT TEMP. (DEC. F) 75.
BAR. PRESS. (IN.HG) 29.88
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 353101
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .001 CFM 8 3.0 IN.HG
METER CALIB. FACTOR .992
READ K RECORD DATA
TRAVERSE
POINT
NO.

INIT












SAMPLE
TIME
(MIN.)

0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
CLOCK
TIME
(24-HR

1350
1400
1410
1420
1430
1440
1400
1500
1510
1520
1530
1540
1550
EVERY 10.0
GAS METER
READING
(CU.FT.)

671.163
675.675
680.055
684.701
689.000
694.040
698.525
703.200
707.689
712.000
716.520
720.798
725.992
MINUTES
VELOCITY
HEAD
(IN.H20)

	
.050
.050
.050
.050
.050
.050
.050
.060
.050
.050
.050
.060

ORIFICE

PRESSURE

STACK
DIFFERENTIAL TEMP
(IN.
DESIRED

.62
.62
.62
.62
.62
.62
.62
.72
.62
.62
.62
.72
H20)
ACTUAL

.62
.62
.62
.62
.62
.62
.62
.72
.62
.62
.62
.72
(DEG.F)


520.
502.
523.
537.
547.
537.
553.
553.
523.
535.
499.
530.
DATE 10/29/81
HUN NUMBER 6-3
PROBE LENGTH ft TYPE 5* GLASS HEATED
NOZZLE : I.D. .398
ASSUMED MOISTURE 12.0
SAMPLE BOX NUMBER
KETER BOX NUKBER FBI
KETER HEAD OIFF. 1.87
C FACTOR .88
PROBE HEATER SETTING 400.
HEATER BOX SETTING 400.
REFERENCE PRESS. DIFF. 1.50

DHY GAS METER
TEMP
(DEG.F)
INLET OUTLET

74. 70.
74. 69.
70. 68.
80. 67.
00. 69.
81. 69.
81. 69.
82. 70.
82. 70.
82. 70.
82. 71.
81. 70.

PUMP
VACUUM
(IN.HG)


2.0
2.0
2.U
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0

SAMPLE
BOX TEMP
(DEG.F)


310.
356.
397.
422.
370.
363.
368.
386.
386.
379.
388.
407.

IMPINGER
TEMP
(DEG.F)


54.
50.
56.
58.
56.
60.
60.
58.
56.
50.
50.
57.
     TOTALS
     AVERAGE
120.0
54.829
                                          .64
                                .64   530.
80.
69,
2.0   379.
56,

-------
                 PARTICIPATE FIELD DATA ft RESULTS TABULATION
      PLANT- NAME  AND  ADDRESS               TEST TEAM LEADER
      REPUBLIC STEEL CLEVELAND              CLARKE
      TEST
        6-3
COKE OVEN OUTLET
 I
to
o
cr>
      TEST DATE
TB        TIME-START
TF        TIME-FINISH
TT        NET TIME OF TEST, MIN.
NP        NET SAMPLING POINTS
Y         METER CALIBRATION FACTOR
ON        SAMPLING NOZZLE DIAMETER
CP        PITOT TUBE COEFFICIENT
PM        AVERAGE ORIFICE PRESSURE
          DROP
VM        VOLUME OF DRY GAS SAMPLED
          AT METER CONDITIONS
TM        AVERAGE GAS METER TEMP
VMSTD     VOLUME OF DRY GAS SAMPLED
          AT STANDARD CONDITIONS*
VLC       TOTAL K20 COLLfCTED IN
          IMPINGERS AND SILICA GEL,ML,
VMC       VOLUME OF HATER VAPOR
          AT STANDARD CONDITIONS*
BKO       PERCENT MOISTURE BY VOLUME
FMD       MOLE FRACTION DRV GAS
PC02      PERCENT C02 BY VOL., DRY
P02       PERCENT 02 BY VOL., DRY
PCO       PERCENT CO BY VOL., DRY
PN2       PERCENT N2 BY VOL., DRY
MD        MOLECULAR MT-DRY STACK GAS
MNS       MOLECULAR MT-STACK GAS
                                         ENGLISH UNITS
                                            10/29/81
                         1550
                          120.0
                           12
                             .992
                             .396 IN

                         __ «8a
                             .64  IN-H20

                           54.629 CU-FT

                           74.5   F
                           53.737 SCF

                         T75. 4

                            8.256 SCF
METRIC UNITS
   10/29/61
1350
1550
 120.0
  12
    .992
  10.1   PM
    .84
  16.2   MM-H20

   1.553 CU-M

  23.6   C
   1.522 SCP

 175.4

    .234 SCP
T1VW
.667
4.50
10.50
.00
65.00
29.14
27.66
13.32
.867
4.50
10.50
.00
85.00
29.14
27.66

-------
     PB         BAROMETRIC  PRESSURE


     PSI        STATIC  PRES OF  STACK  GAS


     PS         STACK PRES, ABS.


     TS         AVERAGE STACK TEMP


     vs         AVG  STACK" GAS VELOCITY


     AS         STACK AREA


     OSSTD      STACK FLON  RATE,  DRY*


     OS         ACTUAL  STACK FLON RATE


     ISO        PERCENT ISOKINETIC


     MN         FILTERABLE  PART

                M6. EPA 5


     CS         FILTERABLE  PART


     PMR        FILTERABLE  PART

                EMISSION  RATE


       *  68 DE6 F,   29.92 IN.H6.
     29.ee  IN-HG


     -1.20  IN-H20


     29.79  IN-HG


    530.    F


     17.9   FPS


   7«66.   SO-IN


1536556.    SCFH
3337721.


    104.9


       .0
ACFH
       .0000 GR/OSCF*


       .000   LB/HR
  750.95  »»M-HG


  -30.06  HP-H20


  756.71  *M-HG


  377.    C


    5.5   Kpg


    0.017 3Q-M


43511.    SCHH


94514.    ACMH


  104.9


     .0




     .000 t'G/OSCK


      .00  KG/HR
I
fO
o

-------
              EXAMPLE PARTICIPATE CALCULATIONS TEST NO.   6-3

                   COKE  OVEN OUTLET



        VOLUME OF  ORT GAS  SAMPLED AT  STANDARD CONDITIONS

        VMSTD  a (17.64?  •  VM •  Y  * (PB + PM / if.6))  / (TM * 460.)

                  17.647 *    54.629  •  .992 * ( 29.86 *  .637 / 13.6)
        VMSTO  » ——	———	—•	•	=     53.737 OSCF
                                 t  75. * 460.)



        VOLUME OF  HATER  VAPOR AT  STANDARD CONDITIONS

        VHC  a  .04707 • VLC

        V*C  a  .04707 •  175. i8.26 3CF



        PERCENT MOISTURE IN  STACK GAS

        BMO  *  (100.  * VMC) / (VMSTO » VHC)

.                  100. •  8.26
•f       BHO  »  ——	—• — r  13.32 PERCENT
ro                   53.737 »   8.26
o
oo                                             • —

        MOLE FRACTION OF DRY STACK GAS

        FMD  »  (100.  - BMO) / 100.

                  100. -  13.1
        FMD  •  ———————— a   ,867
                      100.



        AVERAGE MOLECULAR  HEIGHT  OF DRV STACK 6T3

        MD * (PC02 • .44)  *  (P02  * .32) + (PN2 4 PCO)  * .28

        MO « ( 4.50*44/100)  •» (10.5*32/100) » ((85.0+  .0)  * 28/100 =   29.14



        MOLECULAR  HEIGHT OF  STACK GAS

        MRS  a  MD * (1. • (BHO/100)) » 18. • (BHO/100)

        MRS  *   29.14* (1.  -(13.32/100)) t 18. * (13.32/100) =   27.66

-------
       STACK GAS VELOCITY AT STACK CONDITIONS

       OELP « SUM. OF THE SORT(VH * (TS * 460.))

       VS « B5.49 • CP • OELP / (SQRT(M«S * PS) • PNT3)

       VS « 85.49 *  .04 •   95.778 / (SORT( 27.66 * 29.79)  •  12. =   17.68 FPS



       STACK GAS VOLUMETRIC FLOW AT STACK CONDITIONS

       OS > VS * AS * 3600/144

       OS «   17.88 •  7466. 3600/144 *    3337721. ACFH



       STACK GAS VOLUMETRIC FLON AT STANDARD CONDITIONS

       OSSTO « 17.647 • OS * PS • (1. - (BMO/100J) / (TS « 460.)

                 17.647 *    3337721. *  29.79 • (1. - (13.32/100))
       OSSTO « ———————— —	 s    153b55b. SCFH
                          ( 530. » 460.)
",      PERCENT ISOKINETIC
K>
O      ISO » (305.58*(TS*460.))*((0.002669*VLC)*(VM*Y*(PB*(PM/13.6))/(TM*460.)))/(TT*VS*PS*DN*ON)
VD

              (305.58*( 530.V460.))*((6.002669*  175.)»{   54.829* ,992*( 24.8B«(    .637/13.6))/(  75.+460.)))
       ISO » -i——.———————.......................—............. —.............................. * 104.95 PERCEM
                                          120. *     17.88 •   29.79 *  .398 *  .398



       PARTICIPATE LOADING — EPA METHOD 5 (AT STANDARD CONDITIONS)

       CS a 0.001 * MN • 15.43 / VM3TD

       CS * 0.001 *      .0 • 15.43 /    53.737 *     .000 GR/DSCF



       PARTICIPATE LBS/HR — EPA METHOD 5

       PMR * CS * OSSTO / (15.43 * 453.6)

       PMR •     .000 •    15)6556. / (15.43 i~453.6) =      .00

-------
Run No.  6.3
                           3
     Sample volume = 1 .52 m r  53.74 scf
Example calculations
     CS (Part) = 34.3/1.52 = 22.6   mq/m3
     CS (Part) = 0.001  x 34-3  x 15.437  53.74=  0.010  qr/dscf
     CS (S02)  =1900 /1.52 . 1250mg/m3
               J250
                 0.001  x 190°  x 15.43/53.74  = 0.546 gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


34.3






2.8
3.8
1900

97.6



o Concentration,
mg/m


22.6






1.8
2.5
1250

64.2



gr/dscf


0.010






0.0008
0.001
0.546

0.028



ppm











470

16



                                   A-210

-------
                                                        FIELD  DATA
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION COKE OVEN OUTLET
SAMPLE TYPE 6-4-M5-400
OPERATOR CLARKE
AMBIENT TEMP. (DEG.F) 75.
BAR. PRESS. (IN.HG) 29.00
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530003
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .04
THERM. NO.
LEAKAGE .120 CFM 3 c.O IN.HG
METER CALI8. FACTOR 1.016
READ * RECORD DATA EVERY 10.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY ORIFICE PRESSURE
POINT TIME
NO. (MIN.)

INlt 0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
00.0
90.0
100.0
110.0
120.0"
TIME
(24-HR

1354
1404
1414
1424
1434
1444
1454
1504
1514
1524
1534
1544
1554
READING
(CU.FT.)

00.937
93.212
97.425
101.926
106.210
110.736
115.426
119.660
124.111
120.140
132.670
137.220
142.007
HEAD
(IN.H20)

	 	 •
.050
.050
.050
.050
.050
.050
.050
.060
.050
.050
.050
.060
DIFFERENTIAL
(IN.
DESIRED

.62
.62
.62
.62
.62
.62
.62
.72
.62
.62
.62
.72
H20)
ACTUAL

.62
.62
.62
.62
.62
.62
.62
.72
.62
.62
.62
.72
STACK
TEMP
(DEG.F)


550.
515.
526.
541.
519.
537.
556.
514.
524.
535.
523.
539.
DATE 10/29/81
RUN NUMBER 6-4
PROBE LENGTH « TYPE 6 FT GLASS HEATtD
NOZZLE 1 1.0. .397
ASSUMED MOISTURE 12.0
SAMPLE BOX NUMBER
METER BOX NUMBER FB5
METER HEAD DIFF. 1.86
C FACTOR .88
PROBE HEATER SETTING 400.
HEATER BOX SETTING 400.
REFERENCE PRESS. DIFF. 1.50
DRY GAS METER PUMP SAMPLE IMPINGEH
TEMP VACUUM
(DEG
INLET

04.
05.
08.
90.
92.
94.
94.
94.
94.
93.
92.
92.
.F) (IN.HG)
OUTLET

02.
02.
63.
65.
06.
66.
00.
60.
88.
88.
67.
87.
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
BOX TEMP
(DEG.F)


370.
401.
434.
442.
395.
403.
406.
411.
399.
390.
407.
421.
TEMP
(OEG.M


46.
44.
42.
40.
52.
50.
40.
46.
44.
42.
44.
42.
TOTALS
AVERAGE
120.0
46.702
                                         .64
                               .64   532.
91,
66.
1.0   407.
46.

-------
           PARTICIPATE FIELD DATA a RESULTS TABULATION
PLANT- NAME AND ADDRESS               TEST TEAM LEADER
REPUBLIC STEEL CLEVELAND              CLARKE
TEST
6-4
COKE OVEN OUTLET


TEST DATE
TB
TF
TT
NP
Y
DN
CP
PM
1
10 VM
NJ
TM
VMSTD
VLC
VNC
BMO
FMD
PC02
P02
PCO
PN2
MO
MMS
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H20 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF NATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL., DRY
PERCENT 02 BY VOL., DRY
PERCENT CO BY VOL., DRV
PERCENT N2 BY VOL., DRY
MOLECULAR MT-ORY STACK GAS
MOLECULAR MT-STACK GAS
ENGLISH UNITS
10/29/61
1354
1554
120.0
»z
1.016
.397 IN
	 .64
.64 IN-H20
46.702 CU-FT
88.5 F
45.666 SCF
179.5
8.449 SCF
"15.61
.644
4.50
"iO.50
.00
85.00
-?9.14
27.40
METRIC UNITS
10/29/81
1354
1554
120.0
12
1.016
10.1
.64
16.2
1.322
31.4
1.294
179.5
.239
15.61
.844
4.50
10. SO
.00
85.00
29.14
27.40



KM

PM-H20
CU-M
c
sen-

SCM









-------
    PB         BAROMETRIC PRESSURE

    PSI        STATIC  PRE3 OF STACK GAS

    PS         STACK PRES, ABS.

    TS         AVERAGE STACK  TEMP

    VS         AVG  STACK  GAS  VELOCITY

    AS         STACK AREA

    OSSTD      STACK FLON RATEr  DRY*

    US         ACTUAL  STACK FLON RATE

    ISO        PERCENT ISOKINETIC

    MN         FILTERABLE PART
                M6. EPA  5

    CS         FILTERABLE PART

    PMR        FILTERABLE PART
                EMISSION RATE

      *  66  DEC F,   29.92 1N.H6.
     29.68  IN-HG

     -1.20  IN-H20

     29.79  IN-HG

    532.    F

     18.0   FPS

   7466.   SO-IN

1500961.    3CFH
758.95  *M-HG

-30.ae  MM-H20

756.71  HM-MG

        C

  5.5   t'PS

  0.817 SO-M
3356748
91



ACFH
.8
.0
.0000 GR/DSCF*
.000 LB/HR
95053.
91.8
.0
.000
.00
ACHH


CG/OSCK
KG/HH
NJ
M
U>

-------
            EXAMPLE PARTICULATE CALCULATIONS TEST NO.   6-4

                 COKE OVEN OUTLET




      VOLUME OF DRV 6AS SAMPLED AT STANDARD CONDITIONS

      VMSTO « (17.647 • VM • Y * (PB * PM / 13.6)) / (TM «• 460.)

                17.647 •    46.702 • 1.016 * ( 29.68 *  .637 / 13.6)
      VMSTD * ——————...................	.............— -      45.686  DSCF
                               (  89. » 460.)




      VOLUME OF HATER VAPOR AT STANDARD CONDITIONS

      VMC * .04707 * VLC

      VHC « .04707 •  160. »   8.45 SCF




      PERCENT MOISTURE IN STACK GAS

      BHO « (100.  • VHC) / (VMSTD * VHC)

                100. •   8.45
      BHO » ———.—..	...... c 15.61 PERCENT
                  45.686 »   8.45
*»                    """                       —. ...


      MOLE FRACTION OF DRV STACK GAS

      FMO • (100.  - BHO)  / 100.

                100. -"15.6
      FMO * —————— 9   .844
                     100.



      AVERAGE MOLECULAR HEIGHT OF DRY STACK CAS

      MD * (PC02 • .44)  * (P02 * .32) * (PN2 * PCO) * .28

      MD a ( 4.50*44/100) » (10.5*32/100)  + ((85.0* .0) * 28/100 >   29.14




      MOLECULAR HEIGHT OF STACK  GAS

      MHS • MD • (1. - (BHO/100)) «• 18. *  (BHO/100)

      MHS •  29.14* (1.  -(IS.61/100)) + 16. « (15.61/100) s   27.40

-------
STACK GAS VELOCITY AT STACK CONDITIONS

DELP * SUM. OF THE SORT(VH *  (TS * 460.))

VS * 85.49 * CP * DELP / (SORT(MWS • PS) • PNTS)

VS * 85.49 •  .84 *   85.862  /  (SORT( 27.40 * 29.79)  *  12. =   17.96 FP3



STACK 6AS VOLUMETRIC FLOH AT  STACK CONDITIONS

OS « VS • AS * 3600/144

OS »   17.98 • " f466. 3600/144 a    3356708. ACFH



STACK 6AS VOLUMETRIC FLON AT  STANDARD CONDITIONS

OSSTO « 17.647 i'OS * PS • (t. • (BNO/tfO)) / (TS * 460.)

          17.647 •    3356748. •  29.79 * (1. - (15.61/100))
OSSTD s ———-—.———.———.—-———— — — s    1500961. SCFH
                   f 532. » 460.)



PERCENT ISOKINETIC

ISO « (305.58«(TS*460.))«((0.002669«VLC)*(VM«T*(PB»(PM/13.6))/(TM*460.)))/(TT«>VS«PS*DN*ON)

       (305.58«( 552.»460.))«((0.002669*  180.)»(   46.70Z*!.016*( 29.8B*(    .637/13.6))/(  89.•460.)))
ISO » ——————	—	.....	......	....	.......	......	*  91.80  PEHCENT
                                   120. •     17.98 •   29.79 *  .397 •  .397



PARTICIPATE LOADING — EPA METHOD 5 (AT STANDARD CONDITIONS)

CS * 0.001 • MN * 15.43 / VMSTD

CS « 0.001 *      .0 * 15.43  /    45.686 «     .000 6R/DSCF



PARTICULATE LBS/HR — EPA METHOD 5

PMR « CS * OSSTD / (15.43 * 453.6)

PMR »     .000 *    1500961.  / (IS.43 * 453.6) =      .00

-------
Run No.   6.4
     Sample volume =1.29 m3.45.69  scf
Example calculations
     CS (Part)  = 26.9/1.29 = 20.8   ma/m3
     CS (Part)  = 0.001  x26.9  x 15.43/45.69 = O.Q09  qr/dscf
     CS (S02)   =	/	=	mg/m3
               =	 x 24.06/	=	ppm
               = 0.001  x	x 15.43/	=	gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Sulfur dioxide
Sul f uric acid mist
As H2S04
As H2S04-2H20
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


26.9






0.0
0.0




118.3
5.9
154.0
3 Concentration,
mg/m


20.8






0.0
0.0




91.7
4.6
119.4
gr/dscf


0.009






0.0
0.0




0.040
0.002
0.052
ppm


















                                   A-216

-------
                                                             FIELD   DATA
             PLANT
             SAMPLING  LOCATION

             SAMPLE  TYPE
             OPERATOR
             AMBIENT TEMP.(DEG.F)
             BAR.PRESS.(IN.H6)
             STATIC  PRESS.(IN.H20)
             FILTER  NUMBER(S)
             STACK INSIDE DIM.(IN)
             PITOT TUBE COEFF.
             THERM.  NO.
             LEAKAGE
             METER CALIB. FACTOR
                     REPUBLIC STEEL CLEVELAND
                     COKE STACK

                     METHOD 5-250
                     DO-MP
                      61.
                     29.88
                       .00
                       97.50
                       .80
             .00
                      .016 CFM 8 10.0 IN.HG
                     1.033
 DATE                     10/29/81
 RUN NUMBER                  6-5

 PROBE LENGTH ft TYPE      6* GLASS
 NUZZLE      > l.D.        .374
 ASSUMED MOISTURE         11.0
 SAMPLE BOX NUPBER
 HETER BOX NUMBER         FB4
 PETER HEAD DIFF.         i.ae
 C FACTOR                  .92
 PROBE HEATER SETTING     250.
 HEATER BOX SETTING       250.
 REFERENCE PRESS. DIFF.    .18
            READ  ft  RECORD  DATA EVERY  10.0 MINUTES
>
TRAVERSE SAMPLE CLOCK
POINT TIME TIME
NO. (MIN.) (24-HR
1*1 nrw %

INtt ~ 0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100. 0
110.0
120.0
tub VV" /
1353"
1403
1413
1423
1433
1443
1453
1503
1513
1523
1533
1543
i553
GAS METER
READING
(CU.FT.)
VELOCITY ORIFICE PRESSURE
HEAD DIFFERENTIAL
(IN.H20) (IN.H20)
DESIRED
909.697
914.440
919.130
923.810
928.440
933.160
937.860
942.550
947.240
951.910
956.610
961.300
965.996
	 	
.070
.070
.070
.070
.070
" .070
.070
.070
.070
.070
.070
" .070

.72
.72
.72
.72
.72
.72
.72
.72
.72
.72
.72
.72
ACTUAL

.72
.72
.72
.72
.72
.72
.72
.72
.72
.72
.72
.72
STACK
TEPP
(DEG.F)
ONY GAS METER PUMP SAMPLE
TEMP VACUUM BOX TEMP
(OEG.F) (IN.HG) (DEG.F)
1MPINGEH
TEMP
(OEG.F)
INLET OUTLET

520.
520.
520.
520.
520.
520.
520.
520.
520.
520.
520.
520.

64.
65.
67.
69.
70.
71.
72.
72.
72.
72.
72.
72.

64.
64.
63.
64.
65.
65.
66.
66.
66.
67.
67.
67.

8.4
8.7
8.7
8.7
8.6
8.7
8.7
8.7
8.7
8.7
8.7
8.8

225.
253.
249.
247.
240.
245.
248.
251.
251.
251.
247.
246.

45.
44.
4
-------
                 PARTICIPATE  FIELD  DATA  ft  RESULTS  TABULATION

      PLANT-  NAME AND  ADDRESS               TEST TEAM  LEADER

      REPUBLIC  STEEL CLEVELAND               DO-MP
      TEST
        6-5
COKE STACK
 I

00
ENGLISH UNITS
TEST
TB
TF
TT
NP
V
DN
CP
DATE
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
10/29/81
1553
1553
120
12
1


.0

.033
.374 IN
.84
METRIC UNITS
10/29/81
1353
1553
120
12
1
9

.0

.033
.5
.84



CM

PM        AVERAGE ORIFICE PRESSURE
          DROP

VM        VOLUME OF DRY GAS SAMPLED
          AT METER CONDITIONS

TM        AVERAGE GAS METER TEMP

VMSTD     VOLUME OF DRY GAS SAMPLED
          AT STANDARD CONDITIONS*

VLC       TOTAL H20 COLLECTED IN
          IMPINGERS AND SILICA GEL,ML,

VHC       VOLUME OF NATER VAPOR
          AT STANDARD CONDITIONS*

BMO       PERCENT MOISTURE BY VOLUME

FMO       MOLE FRACTION DRY GAS

PC02      PERCENT C02 BY VOL., DRY

P02       PERCENT 02 BY VOL., DRY

PCO       PERCENT CO BY VOL., DRY

PN2       PERCENT N2 BY VOL., DRY

MD        MOLECULAR MT-OftV STACK GAS

MMS       MOLECULAR NT-STACK GAS
                             .72  IN-H20


                           56.299 CU-FT


                           67.6   F

                           58.228 SCF


                          213.8


                           10.064 SCF
 18.3   CM-H20


  1.594 CU-M


 19.8   C

  1.649 SCC


213.8


   .285 SCC
14.74
.853
4.50
10.50
.00
85.00
29.14
27.50
14

4
10

85
29
27
.74
.853
.50
.50
.00
.00
.14
.50

-------
       PB        BAROMETRIC PRESSURE

       PSI       STATIC PRES OF STACK GAS

       PS        STACK PRES, ABS.

       TS        AVERAGE STACK TEMP

       VS        AV6 STACK GAS VELOCITY

       AS        STACK AREA

       OSSTD     STACK FLOW RATE, DRY*

       OS        ACTUAL STACK FLON RATE

       ISO       PERCENT ISOKINETIC

       MN        FILTERABLE PART
                   MG. EPA 5

       CS        FILTERABLE PART

       PMR       FILTERABLE PART
                   EMISSION RATE

          *  68 DEC F,  29.92 IN.H6.
     29.68  IN-HG

       .00  IN-H20

     29.88  IN-HG

    520.    F

     20.7   FPS

   7466.   SO-IN

1776813.    SCFH
3873037.

    111.4

       .0
ACFH
       .0000 GR/OSCF*

       .000   LB/HH
   758.95  CM-HG

      .00  MM-H20

   758.95  KM-HG

   271.    C

     6.3   CP3

     4.817 SQ-M

 50314.    SCHH

109673.    ACI'H

   111.4

      .0


      .000 PG/OSCP

       .00  KG/HR
to

-------
              EXAMPLE PARTICIPATE CALCULATIONS TEST NO.   6-5

                   COKE STACK




        VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

        VMSTD • (17.647 * VM * Y * (PB » PM / 15.6)) / (TM * 460.)

                  17.647 •    56.299 • 1.033 * ( 29.88 »  .720 / 13.6)
        VMSTO « ..————.................................—..... =     58.228 DSCF
                                 (  66. » 460.)




        VOLUME OF MATER VAPOR AT STANDARD CONDITIONS

        VMC * .04707 * VLC

        VMC « .04707 •  214. I  T6.06 SCF




        PERCENT MOISTURE IN STACK GAS

        BMO « (166.  * VMC) / (VMSTD «• VMC)   "™~

>                 100. *  10.06
I       BMO a .———.—	.......... s 14.74 PERCENT
^                   58.228 *  10.06
N)
O       ......       .    	         .      	


        MOLE FRACTION OF DRV STACK GAS

        FMO • (100.  - BMO) / 100.

                  100. •  14.7
        FMD « ————.——.—. *   .853
                       100.




        AVERAGE MOLECULAR HEIGHT or DRY STACK ns

        MD  « (PC02 * .44)  + (P02 « .32) * (PN2 * PCO)  * .28

        MO  • ( 4.50*44/100) «• (10.5*32/100) * ((85.0*  .0)  • 28/100 =   29.14




        MOLECULAR HEIGHT OF STACK GAS

        MMS • MD • (1. • (BMO/IOO)) + 18. • (BNO/100)

        MMS «  29.14* (1.  -(14.74/100)) » 18. *"T14.74/100) «   27.50

-------
>
STACK 6*3 VELOCITY AT STACK CONDITIONS

OELP * SUM. OF THE SQRT(VH * (TS * 460.))

VS * 65.49 * CP • OELP / (SORT(MW3 * PS) • PNTS)

VS » 85.49 •  .84 •   99.390 / (30RT( 37.50 • 29.88)  *  12. =   20.75 FPS



STACK GAS VOLUMETRIC FLOW AT STACK CONDITIONS

03 » VS * AS * 3600/144

OS «   20.75 *  7466. 3600/144 «    3873037. ACFH



STACK CAS VOLUMETRIC FLON AT STANDARD CONDITIONS

QSSTD • 17.647 * OS • PS * (1. • (BNO/100)) / (TS » 460.)

          17.647 *    3873037. •  29.88 * (1. - (14.74/100))
03STD • ———————————————— ---- — *    1776813. SCFH
                   ( 520. «• 460.)
    __.    .    .  „_


PERCENT ISOKINETIC

130 • (305.58«(T3*460.))«((0.002669«VLC)+(VM«Y*(PB«(PM/13.6))/(TM+460.)))/(TT«V3*P3«DN«ON)

       (30S.§8*( 520. +460.))*((d. 002669*  214. )»(   56. 299*1. 033«( 29. 88«(    .720/13.6) )/(  68.4460.)))
ISO « — — ..... ...... ..... --- ........... --- ...... ------------ .... . ------- . --- ...... --- ... ---------- . a 111.37 PERCENT
                                   120. •     20.75 *   29.88 *  .374 *  .374



PARTICULATE LOADING— EPA METHOD 5 (AT "STANDARD CONDITIONS)

CS * 0.001 * MN * 15.43 / VMSTD

C3 » 0.001 *      .0 * 15.43 /    58.228 «     .000 GR/OSCF



PARTICULATE LBS/HR — EPA METHOD 5

PMR * CS • OS3TD / (15.43 • 453.6)

PMR «     .000 •    1776813. / (15.43 • 953.6) r      .00

-------
Run No.  6.5
                           o
     Sample volume = 1.65 m ,58.23  scf

Example  calculations

     CS  (Part)  =195.7/1.65 =  118.6 mq/m3

     CS  (Part)  = 0.001  x!95.7  x  15.43/58.23 = 0.052  qr/dscf

     CS  (S02)   =	/	=	mg/m3

               =	 x 24.06/	=	ppm

               = 0.001  x	x  15.43/	=	gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Sulfur dioxide
Sul f uric acid mist
As H2$04
As H2S04-2H20
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


195.7
42.3
37.6
33.2
30.3
25.8

0.0
0.0




20.0
6.4
15.2
2 Concentration,
mg/m


118.6
25.6
22.8
20.1
18.4
15.6

0.0
0.0




12.1
3.9
9.2
gr/dscf


0.052
0.011
0.010
0.009
0.008
0.007

0.0
0.0




0.005
0.002
0.004
ppm















1


                                  A-222

-------
                                                        FIELD  DATA
PLANT . REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION COKE STACK
SAMPLE TYPE METHOD 8-600
OPERATOR DO/MP
AMBIENT TEMP. (DEC. FJ 61.
BAR. PRESS. CIN.H6) 29. S8
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER (3) 3530209
STACK INSIDE DIN. (IN) 97.50 .00,
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFN 8 7.0 IN
METER CALIB. FACTOR .982
READ ft RECORD DATA EVERT 10. 0 MINUTES










,HG


TRAVERSE SAMPLE CLOCK CAS METER VELOCITY ORIFICE PRESSURE
POINT TIME TIME READING HEAD DIFFERENTIAL
NO. (MIN.) (24-HR (CU.FT.) (IN.H20) (IN.H20)













STACK
TEMP
(OEG.F)
DESIRED ACTUAL

INIT 0 1392 364. 163
10.0 1402 368.920 .070
> 20.0 1412 373.660 .070
' 30.0 1422 378.370 .070
isj 40.0 1432 383.050 .070
U> SO.O 1442 387.780 .070
60.0 1452 392.500 .070
70.0 1502 397.230 .070
BO.O 1512 401.960 .070
90.0 1522 406.690 .070
100.0 1532 411.420 .070
110.0 1542 416.150 .070
120.0 1552 420.865 .070

.32 .75
.32 .75
.32 .75
.32 .75
.32 .75
.32 .75
.32 .75
.32 .75
.32 .75
.32 .75
.32 .75
.32 .75

920.
520.
520.
520.
520.
•520.
520.
520.
920.
520.
520.
920.
DATE 10/29/81
RUN NUMBER 6-6
PROBE LENGTH ft TYPE 4* QUARTZ
NOZZLE I I.D. .620
ASSUMED MOISTURE 11.0
SAMPLE BOX NUMBER
METER BOX NUMBER FBS
METER MEAD OIFF. 1.91
c FACTOR .92
PROBE HEATER SETTING 250.
HEATER BOX SETTING 250.
REFERENCE PRESS. DIFF. .02


DRV GAS METER PUMP SAMPLE IMPINGER
TEMP VACUUM BOX TEMP TEMP
(DE6.F) (IN.HG) (DEG.F) (DE6.F)
INLET OUTLET

61. 60. .6 SB6. 38.
62. 60. .7 582. 36.
65. 60. 7 509. 36.
68. 61. 9 542. 40.
70. 62. 0 545. 38.
72. 63. 3 583. 38.
72. 63. 4 584. 40.
73. 64. 7 594. 40.
73. 65. 8 587. 38.
73. 65. 9 601. 38.
73. 65. 1 599. 38.
73. 65. 5 600. 40.
TOTALS
AVERAGE
120.0
56.702
                                        9.32
                               .75   520.
70.
63.
4.5   576,
38.

-------
           PARTICULATE FIELD DATA ft RESULTS TABULATION



PLANT* NAME AND ADDRESS               TEST TEAM LEADER



REPUBLIC STEEL CLEVELAND              DO/HP
TEST
6-6
COKE STACK

TEST DATE
TB
TF
TT
NP
Y
DN
CP 	
PM
1
N> VM
NJ
TM
VMSTO
VLC
VMC
UNO
FMD
PC02
P02
PCO
PN2
" MO
MMS


TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRV GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL M20 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF NATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE 8V VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL., DRY
PERCENT 02 BY VOL.* ORV
PERCENT CO BY VOL.* DRV
PERCENT N2 BY VOL., DRV
MOLECULAR NT-DRY STACK GAS
MOLECULAR NT-STACK GAS
ENGLISH UNITS
10/29/81
1352
1552
120.0
12
.982
.620 IN
.84
.75 IN-H20
56.702 CU-FT
66.2 F
55.903 9CF
101.7
9.494 SCF
_li.S2
.855
4.50
10.50
.00
85.00
29.14
27.52
METRIC UNITS
10/29/81
1352
1552
120.0
12
.982
15.7 MM
.64
19.1 IMM-H20
1.606 CU-M
19.0 C
1.583 SCH
201.7
.269 SCN
14.52
.855
4.50
10.50
.00
85.00
29.14
27.52

-------
     PB        BAROMETRIC PRESSURE


     PSI       STATIC PRES Of STACK GAS


     PS        STACK PRES, ABS.


     TS        AVERAGE STACK TEMP


     VS        AV6 STACK GAS VELOCITY


     AS        STACK AREA


     QSSTD     STACK FLOW RATE* DRV*


     OS        ACTUAL STACK FLO* RATE


     ISO       PERCENT ISOKINETIC


     MN        FILTERABLE PART
                 MG. EPA 5


     C3        FILTERABLE PART


     PMR       FILTERABLE PART

                 EMISSION RATE


        *  68 010?;  89.94 IN.MG.
     29.OS  IN-HG


     •1.20  IN-M20


     29.74  IN-MG


    920.    F


     20.8   FPS


   7466.   SO-IN


17779S5.    SCFH


3877090.    ACFH


     38.9


       .0



       .0000 GR/OSCF*


       .000   L8SHR
   758.99  MM-HG


   •30.08  MM-H80


   75*.71  MM-HG


   271.    C


     6.3   MP8


     4.817 80-M


 S0346.    8CMH


109786.    ACMH


    38.9


      .0



      .000 M6/DSCH


       .00  KS/HR
ro
to
ui

-------
            EXAMPLE  PARTICIPATE  CALCULATIONS  TEST  NO.    6-6

                 COKE  STACK



      VOLUME OF DRY  GAS SAMPLED  AT  STANDARD CONDITIONS

      VMSTD •  (17.647  * VM *  Y *  (Pft  4 PM  / IS. 6))  /  (TM »  460.)

                17.647 *    56.702  *   .982 •  ( 29.88  «  .750  /  13.6)
      VMSTD •  — — — -— ........................ ........ ........ .     53.903 OSCF
                               (  66.  *  460.)



      VOLUME OF MATER  VAPOR AT STANDARD  CONDITIONS

      VMC • .04707 • VLC

      VMC • .04707 *  202. «   9.49 SCr




      PERCENT  MOISTURE IN STACK CAS

      0MO i (100. •  VKC7 / (VHSTO » VHC)

^              100. •   9.49
•f    BWO » ——.—.—.- ............. :» 14.51 PERCENT
to                55.903 *   9.49
•-OV-
      MOLE FRACTION OF DRY STACK GAS

      FMO • (100. - BMO) / 100.

      -         loft. •  14.S
      FMD • — — — — ............. •    .855
                     100.
      AVERAGE MOLECULAR "EIGHT OF DRV STACK GAS

      MO • (PC02 * .44) »  (P02 * .32) *  (PN2 • PCO)  «  .28

      MO a ( 4.50*44/100)  *  (10.5*32/100) * ((85.0*  .0)  *  28/100  •    29.14




      MOLECULAR HEIGHT OF  STACK GAS

      MHS a MO • (1. • (BNO/100)) *  18.  • (BNO/100)

      MNS a  89.14* (1. -(14.52/100)) *  18. • (14.52/100)  a    27.52

-------
      STACK GAS VELOCITY AT STACK CONDITIONS

      DELP • SUM. OF THE 90RTCVM • (TS » 460.))

      VS • 65.49 • CP • OELP / (SQRT(MMS • PS) • PUTS)

      VS « B5.49 *  .04 •   99.390 / (80RT( 27.92 • 29.79)  •  12. •   20.77 PPS



      STACK GAS VOLUMETRIC FLO* AT STACK CONDITIONS

      03 • VS • AS • 3600/144

      OS •   20.77 •  7466. 3600/144 •    3877090. ACFM




      STACK CAS VOLUMETRIC FLOH AT STANDARD CONDITIONS

      OSStO • if.647 • OS • PS~* Tl. • (MO/100)) / (T8 * 460.)

                17.647 •    3877050. *  29.79 • (1, - (14.92/100))
      OSSTO • ——————.................................... •    17779S3. SCFM
                         ( 920. » 460.)




      PERCENT I80KINETIC
>
 I     ISO » (309.58*(TS»460.))*((0.002669*VLC)»(VM*Y*(PB*(PM/13.6))/(TM*460,)))/(TT*VS«PS*DN*ON)
to
^            (36S.5M( S20.+460.))»((0.002669*  202.)+(   56.702* .*82*( 29.88«(    .750/13.6))/(  66.«460.)))
      ISO » .——..—.————.—[[[ .  38.88 PERCENT
                                         120. •     20.77 •   29.79 *  .620 •  .620




      PARTlCULAte LOADING —EPA METHOD 9 (AT STANDARD CONDITIONS)

      CS » 0.001 * MN • 19.43 / VMSTD

      CS * 0.001 *      .0 • 19.43 /    99.903 •     .000 6R/D8CF




      PARTICULATE LBS/HR — EPA METHOD 9


-------
Run No.  6.6
     Sample  volume =1.58  m3T 55.90  scf
Example  calculations
     CS  (Part) =30.9 /.58  =19.6   ma/m3
     CS  (Part) = 0.001 x30.9  x 15.43/55.90=  0.008  gr/dscf
                                     3
CS (S02)   =2010/1.58=1272  ma/m
          = 1272 x 24.06/G4  =478 ppm
          =  0.001 x2010  x 1 5. 43/.55JiP
                                                   gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Sulfur dioxide
Sul f uric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


30.9






0.0
0.0
2010

115



3 Concentration,
mg/m


19.6






0.0
0.0
1272

72.8



gr/dscf


0.008






0.0
0.0
0.555

0.032



ppm











478

18



                                   A-228

-------
                                                        FIELD  DAT*
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION NO.l COKE BATTERY OUTLET
SAMPLE TYPE PART/H2S04/S02
OPERATOR BRUFFEY
AMBIENT TEMP. (DEC. F) 54.
BAR. PRESS. (IN. HO) 29.92
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530043
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM 8 5.0 IN.MG
METER CALIB. FACTOR 1.003
READ » RECORD DATA EVERY 10. 0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY ORIFICE PRESSURE
POINT TIME
NO. (MIN.

INIT 0
10.0
20.0
> 30.0
to 40.0
to 50.0
vo 60.0
70.0
80.0
90.0
100.0
110.0
	 120.0
TIME
) (24-HR

930
940
950
1000
1010
1020
1030
1040
1050
1100
1110
1120
" 1130
READING
(CU.FT.)

988.550
993.730
998.590
3.600
9.050
13.680
18.350
23.840
28.590
33.300
39.130
43.820
48.499
HEAD
(IN.H20)


.060
.060
.060
.070
.050
.050
.070
.050
.050
.080
.050
".050
DIFFERENTIAL
(IN.
DESIRED

.73
.73
.73
.87
.62
.62
.87
.62
.62
1.00
.62
.62
H20)
ACTUAL

.73
.73
.73
.87
.62
.62
.87
.62
.62
1.00
.62
.62
STACK
TEMP
(OEG.F)

t
316.
536.
550.
503.
514.
540.
523.
565.
562.
505.
516.
527.
DATE 10/30/81
RUN NUMBER 7-1
PROBE LENGTH • TYPE 6* HEATED GLASS
NOZZLE 1 I.D. .398
ASSUMED MOISTURE 12.0
SAMPLE BOX NUMBER o
METER BOX NUMBER FB2
METER HEAD OIFF. i.76
C FACTOR .86
PROBE HEATER SETTING 250.
MEATER BOX SETTING 250.
REFERENCE PRESS. DIFF. .is
DRY GAS METER PUMP SAMPLE IMPINGER
TEMP
(DEG.F)
INLET

55.
56.
60.
63.
66.
67.
69.
70.
70.
70.
71.
71.
OUTLET

.54.
54.
54.
55.
57.
•58.
60.
61.
62.
63.
63.
64.
VACUUM
(IN.HG)


1.5
1.5
1.5
2.0
2.5
2.5
2.5
2.5
2.5
3.0
3.5
3.5
BOX TEMP
(DEG.F)


240.
247.
292.
254.
258.
257.
254.
256.
249.
244.
252.
255.
TEMP
(DEG.F)


46.
44.
46.
46.
47.
49.
56.
59.
60.
57.
•35.
93.
TOTALS
AVERAGE
120.0
59.949
                                         .72
                               .72   530.
66.
59.
2.4   292.
52.

-------
           PARTICIPATE FIELD DATA a RESULTS TABULATION
PLANT- NAME AND ADDRESS               TEST TEAM LEADER
REPUBLIC STEEL CLEVELAND              BRUFFEY
TEST
7-1
NO.I COKE BATTERY OUTLET

TEST DATE
TB
TF
TT
NP
Y
DN
CP
PM
E V"
OJ — 	 _..
0
TM
VMSTD
vie
•VHC
Slid
FMD
PC02
P02
PCO
PN2
MO
MM 3


TIME-START
TIME-FINISH
NET TIME OF TEST* MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAB SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL M20 COLLECTED IN
IMPINGERS AND SILICA GEL*ML.
VOLUME OF NATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRV GAS
PERCENT C02 BY VOL.* DRV
PERCENT 62 BY VOL.* DRY
PERCENT CO BY VOL.* DRV
PERCENT N2 BY VOL.* DRY
MOLECULAR NT-DRY STACK GAS
MOLECULAR NT-STACK GAS
ENGLISH UNITS
10/30/81
930
1130
120.0
12
1.003
.398 IN
.84
.72 IN-H20
59.949 CU-FT
62.2 F
60.903 SCF
1*2.1
4.042 SCF
12.43
.871
4.00
11.00
, .00
85.00
29.08
27.65
METRIC UNITS
10/30/81
430
1130
120.0
12
1.003
10.1 MM
.84
18.3 MM-H20
1.648 CU-M
16.8 C
1.725 SCM
142.1
.256 SCM
12.43
.871
4.00
11.00
.00
85.00
24.08
27.65

-------
   PB        BAROMETRIC PRESSURE

   PSI       STATIC PRE8 OF STACK 6AS

   PS        STACK PRES, ABS.

   TS        AVERAGE STACK TEMP

   VS        AVG STACK QAS VELOCITY

   AS        STACK AREA

   QSSTD     STACK FLOW RATE* DRT«

   OS        ACTUAL STACK FLO* RATE

   ISO       PERCENT ISOKINETIC

   MN        FILTERABLE PART
               M6. EPA 5

   CS        FILTERABLE PART

   PMR       FILTERABLE PART
               EMISSION RATE

      •  68 DEC FV  29.91 IN.HG.
     29.92  IN-MG

     -1.20  IK-M20

     29.03  IN-HG

    530.    F

     1ft.9   FPS

   7466.   SO-IN

1636079.    SCFM
3SS26SS.

    111.7

       .0
ACFH
       .0000 GR/DSCF*

       .000   LB/MR
   759.97  MM-H6

   •30.4ft  MM*N20

   757.73  MM-HG

   277.    C

     5.ft   HPS

     •.617 SO*M

 46329.    SCMH

100034.    ACMH

   111.7

      .0


      .000 N6/OSCK

       .00  KG/HR
to
U)

-------
            EXAMPLE PARTICULAR CALCULATIONS TEST NO.   7-1


                 NO.l COKE BATTERY OUTLET




      VOLUME OF OUT 6AS SAMPLED AT STANDARD CONDITIONS

      VMSTO • (17.647 *~ VM * Y * (PB * PM / 13.6)) / (TM » 460.)


                17.647 •    39.949 * 1.003 • ( 29.92 «•  .721 / IS. 6)
      VMSTD • ——————————————————— •     60.903 03CF
                               (  62. » 460.)




      VOLUME OF HATER VAPOR AT STANDARD CONDITIONS


      VMC • .04707 • VLC


      VNC • .04707 •  192. •   9.04
      PERCENT MOISTURE IN STACK 6AS


      BNO » (iOOi~* VHC) / (VMSTO * VWC)

                100. *   9.04
      BMO • .——.———.——— « 12.93 PERCENT
^                 60.903 *   9.04
 I
to
CO

M     MOLE FRACTION OF DRY STACK CAS


      FMO » (100. » BNO) / 100.


                100. -  12.9
      FMD • •...—•....••-•••.»•«•. •   .$71
                     100.
      AVERAGE MOLtCULA* HEIGHT OF DRY STACK CAS


      MO • (PC02 * .44) * (P08 • .32) * (PN2 * PCO) * .26


      MO • ( 4.00*44/100) » (11.0*32/100) * ((6S.O* .0) • 28/100 •   29. OS




      MOLECULAR NEI6MT OF STACK GAS


      MHS » MD • (1. • (BNO/100)) » IS. * (BNO/100)


      MHS »  29.06* (i. -(12.93/100)) » 18. * (12.93/100) •   27.65

-------
    STACK GAS VELOCITY AT STACK CONDITIONS

    OELP « SUM. Of THE SQRT(VH * (TS + 4*0.))

    VS • 85.49 • CP • DELP / (SQRT(MMS * PS)  • PNTS)

    VS • 8b.«9 *  .84 •   90.827 / (SQRT( 27.65 • 29.83)  •  12. •   18.93 FPS



    STACK CAS VOLUMETRIC FLOM AT STACK CONDITIONS

    OS * VS • AS * 3*00/144

    OS «   18.93 •  7466. 3600/144 •    3531(35.  ACFH



    STACK 6AS VOLUMETRIC FLON AT STANDARD CONDITIONS

    OSSTD « 17.647 * Q3 • M • (1. - (BNO/100H  / (T8 * 460.)

              17.647 •    3532635. *  29.83 • (1. • (12.93/100))
    OSSTD » — ———-.———— .............. .... ...........*    1636079.  3CFH
                       ( 530. » 460.)
>   PERCENT  ISOK1NETIC
I
    ISO  •  (305.58«(TS*460.))*((0.002669*VLC)«(VM«Y*(PB«(f>M/13.6))/(TM«460.)))/(TT*V8*P
-------
Run No.  7-1
     Sample volume =
Example calculations
                       ,  60.90 scf
CS (Part) =195. 8/ 1.73L  113.2mq/m3
CS (Part) = 0.001 x195-8 x  15.43/60.90=  0.050 qr/dscf
CS (S02)  = _ / _ = _ mg/m3
          = _ x 24. 06/ _ = _ ppm
          = 0.001 x _ x  15.43/ _ = _ gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Sulfur dioxide
Sulfuric acid mist
As H2S04
As H2S04-2H20
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
195.8












3 Concentration,
mg/m
113.2












gr/dscf
0.050












ppm













                                A-234

-------
                                                             FIELD  DATA
ro
10
uv
PLANT REPUBLIC 8TEEL CLEVELAND
SAMPLING LOCATION NO.l COKE BATTERY OUTLET
SAMPLE TYPE PART
OPERATOR BRUFFEY
~ AMBIENT TEMP. (OEG.F) 54.
BAR. PRESS. (IN. HG) 29.93
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530066
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM 8 6.0 IN.H6
METER CALIB. FACTOR 1.044
READ ft RECORD DATA EVERY 10. 0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY ORIFICE PRESSURE
POINT
NO.

INlf












TIME
(MIN.)

a
10.0
20.0
30.0
40.0
SO.O
60.0
70.0
80.0
90.0
100.0
110.0
120.0
TIME
(24-HR

933
943
953
1003
1013
1023
1033
1043
1053
1103
1113
1123
1133
READING
(CU.FT.)

204.803
209.480
214.180
216.880
223.930
228.290
232.670
237.720
242.080
246.450
251.890
256.250
260.606
HEAD
(IN.H20)


.060
.060
.060
.070
.050
.050
.070
.050
.050
.080
.050
.050
DIFFERENTIAL
(IN.
DESIRED

.73
.73
.73
.87
.62
.62
.87
.62
.62
1.00
.62
.62
H20)
ACTUAL

.73
.73
.73
.87
.62
.62
.87
.62
.62
1.00
.62
.62
STACK
TEMP
(OEG.F)


328.
541.
557.
504.
528.
349.
547.
565.
563.
507.
518.
333.
DATE 10/30/81
RUN NUMBER 7-2
PROBE LENGTH ft TYPE 5* HEATED GLASS
NOZZLE t I.D. .377
ASSUMED MOISTURE 12.0
8AMPLE BOX NUMBER 0
METER BOX NUMBER FIO
METER HEAD DIFF. 1.80
C FACTOR .86
PROBE HEATER SETTING 850.
HEATER BOX SETTING 250.
REFERENCE PRESS. DIFF. .15
DRY GAS METER PUMP SAMPLE IMPINGER
TEMP
(OEG.F)
INLET

58.
60.
64.
67.
70.
71.
72.
73.
74.
74.
75.
76.
OUTLET

58.
58.
60.
61.
61.
63.
64.
66.
66.
67.
68.
69.
VACUUM
(IN.HG)


1.
1.
2.
2.
2.
2.
3.0
2.5
3.0
3.0
3.0
3.0
BOX TEMP
(DE6.F)


259.
266.
264.
262.
264.
259.
258.
258.
253.
246.
253.
258.
TEMP
(OEG.F)


•2.
44.
46.
43.
47.
•49.
54.
39.
62.
56.
35.
32.
     TOTALS
     AVERAGE
120.0
55.803
                                         .72
                               .78   537.
70.
63.
2.5   258.
31.

-------
           PARTICIPATE FIELD DATA I RESULTS TABULATION
                       i
PLANT* NAME AND ADDRESS .              TEST TEAM LEADER
REPUBLIC STEEL CLEVELAND ,              BRUFFEY
TEST
T-Z
NO.l COKE BATTERY OUTLET








>
NJ
to
cn .



TEST DATE
TB
TF
TT
NP
Y
ON
CP
PM
VM
TM
VMSTO


flME-lfART
TIME-FINISH
NET TIME OF TEST, MlN.
NET SAMPLIN9 POINTS 	
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRV 6AS SAMPLED
AT METER CONDITIONS
AVERA6E GAS METER TEMP
VOLUME OF DRV 6AS SAMPLED
ENGLISH UNITS
10/30/61
«1
1133
120.0
12
1.044
.377 IN
.._.. •**
.72 IN-H20
55.803 CU-FT
66.5 F
98. 552 SCF
METRIC UNITS
10/30/81
933
1133
120.0
12
1.044
9.6 KM
.84
18.3 MM-H20
1.580 CU-M
19.1 C
1.658 SCM
          AT STANDARD CONDITIONS*
VLC       TOTAL M20 COLLECTED IN
          IMPINBERS AND SILICA GELtML.
VNC       VOLUME OF WATER VAPOR
          AT STANDARD CONDITIONS*
BMO       PERCENT MOISTURE BY VOLUME
FMO       MOLE FRACTION DRV 6AS
PC02      PERCENT C02 BV VOL.* DRV
pol       PERCENT 02 BY VOL.* 0*v
PCO       PERCENT CO BV VOL.. DRV
PN3       PERCENT N2 BV VOL., ORV
MO        MOLECULAR NT-DRY STACK GAS
MKS       MOLECULAR NT-STACK GAS
                                  HI. a
                                    8.557 SCF
                                               101.8
                                                  .242 SCM
12.75
.872
4.00
11.00
.00
85.00
29.08
27.67
12.75
.872
4.00
11.00
.00
85.00
29.08
27.67

-------
    PB         BAROMETRIC PRESSURE

    P3I        STATIC PRES OP STACK 6AS

    PS         STACK PRES, ABS.

    TS         AVEMA6E STACK TEMP

    VS         AV6 STACK  6A9 VELOCITY

    AS         STACK AREA

    QSSTD      STACK FLON RATE*  DRV*

    03         ACTUAL STACK FLON RATE

    ISO        PERCENT ISOKINETIC

    MN         FILTERABLE PART
                M6. EPA  3

    CS         FILTERABLE PART

    PMR        FILTERABLE PART
                EMISSION RATE

      •   68  DES F,  29.W IN.H6.
29
-1
29
537
19
7466
•
•
.
•
•
•
93
20
64

0
IN-HG
IN-H20
IN-HG
F
PPS
80-IN
1633313.
3543545
•

SCFH
ACFH
119.9
760
•30
757
280
5
4
46251
100343
119
.0


•
•
0000
000
GR/DSCF*
LB/HR


.22
.46
.98
•
.•
.817
•
•
.9
.0
.000
.00
•MM-H6

-------
           EXAMPLE PARTICULATE CALCULATIONS TEST NO.   7-2

                NO.l COKE BATTERY OUTLET



     VOLUME Of DRY GAS SAMPLED AT STANDARD CONDITIONS

     VM3T6 • (i?.*«7 • VM • Y * IPB * PM / IS.*)) /  (TM * 460.)

               17.647 •    95.803 • 1.044 * ( 29.'3 *  .721 /  IS.6)
     VMSTD • ——i—........................................... m      56.552 03CF
                              (  66. » 460.)
     VOLUME OP WATER VAPOR AT STANDARD CONDITIONS

     VNC « .04707 * VLC

     VWt « .OiTOT •  182. 6 " 875S SCF      	



     PERCENT MOISTURE IN STACK CAS

     BNO I'liOO.* V1CT / IVHSTO » VUC)

               100. •   S.56
 >   BMO » ——.................... • 12.T5 PERCENT
 I                50.552 *   8.56
 to
..^j	    ._... „     _   .		_.   ,          ..  		
 03

     MOLE TRACTION OF DRY STACK CAS

     FMO • tlOO. • BNO) / 100.
                    .•«—..-..... •   .872
                    100.
    TkVERACE MOLfCUiAR iCICHT OF DRY STACK 6X8

     MD * (PC02 • .44) » (P02 « .32) » (PN2 * PCO) • .28

     MD * ( 4.00*44/100) * (11.0*32/100) * U85.0+ .0) * 28/100 •   29.08



     MOLECULAR NEI6HT OP STACK CAS

     MMS * MD * (1. - (BNO/100)) » 18. * (BNO/100)

     MMS •  24.08* (I. -(12.75/100)) * 18. * (12.75/100) •   27.67

-------
     STACK 6A8 VELOCITT AT STACK CONDITIONS

     OELP • SUM. -OF THE SORT(VH •  (TS • 460.))

     VS • 85.49 • CP • OELP / (SORT(MKS * PS) • PNTS)

     V3 • 6S. 49 •  .64 *   91.155  /  (SORT( 27.67 • 29.84)  •  12. «    18.90 FPS



     STACK 6AS VOLUMETRIC PLON AT  STACK CONDITIONS

     03 * VS • AS * 3600/144

     OS •   18.98 *  7466. 3600/144  •    354354S. ACPH



     STACK 6AS VOLUMETRIC FLOW AT  STANDARD CONDITIONS

     OSST6 * 17.647 * OS • P8~i 11.  • (BMD/10V)) X CTS * 460.)

               17.647 •    3543545.  •  29.84 * (1. - (12.75/100))
     OSSTD • — .... ..................................... .........     1633313. SCFH
                        ( 537. * 460.)



     PERCENT ISOKINETIC

>    ISO • (305.58*(TS«460.))M(0.002669«VLC)*(VM*V*(PB«fPM/13.6))/(TM*460.)))/(TT«V8*P8*DN*DN)
I
          ~ '(305. S8«(S37«-»460.))*( (0.002669*  182. )•(   55. 803*1. 0«4«( 29w93*(    .721/13. 6))/(  66. •469.)))
     ISO • ........ •—.—...————.—••——.———— .—..————.——— —....i-.———i. • 119.90 PERCENT
                                        120. •     18.98 •   29.84 *  .377 •  ,377
     PARTfCULAfE LOADINO « «PA METHOD 5 (AT 1TANOARD CONDITIONS)

     CS « 0.001 • MN * 15.43 / VMSTD

     CS » 0.001 •      .0 • 15.43 /    58.552 »     .000 0R/D8CF



     PARTICULATE LB8/HR — EPA METHOD 5

     PMR • CS * OSSTD / (15.43 • 453.6)

     PMR •     .000 *    1633313. / (15.43 * 453.6) •      .00

-------
Run No.   7.?
     Sample volume  =1.66 m  .58.55  scf
Example  calculations
     CS  (Part)  =187.1/1.66 = 112.7 mo/m3
     CS  (Part)  =  0.001  xjj^jx 15.437 58.55.
     CS  (S02)   =	/	=	mg/m3
               =	 x 24.06/	=	ppm
               =  0.001  x	x 15.43/	
0.099 gr/dscf
      gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2$04
As H2S04.2H20
Sulfur dioxide
Sulfuric acid mist
As H2$04
As H2S04-2H20
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
187.1






3 Concentration,
mg/m
112.7






gr/dscf
0.049

1




ppm







                                    A-240

-------
                                                        FIELD  DATA
        PLANT
        SAMPLING LOCATION
                     REPUBLIC STEEL CLEVELAND
                     COKE OVEN OUTLET
        SAMPLE TYPE              7-3-M8-S90
        OPERATOR                 CLARKE
        AMBIENT TEMP.(DEG.F)      52.
        BAR.PRESS.(IN.HG)        27.92
        STATIC PRESS.(IN.H20)    -1.20
        FILTER NUMBER(S)         3S30079
        STACK INSIDE DIM.(IN)      97,50
        PITOT TUBE COEFF.          .94
        THERM. NO.
        LEAKA6E                   .000 CFM 9
        METER CALIB. FACTOR       .992
        READ i RECORD DATA EVERY 10.0 MINUTES
TRAVERSE
POINT
NO.
SAMPLE
TIME
(MIN.)
CLOCK
TIME ~
(24-HR
CLOCK)
GAS METER
~ READING
(CU.FT.)
VELOCITY
HEAD
(IN.H20)
                                 00
                                  3.0 IN.HG
                                                 ORIFICE PRESSURE  STACK
                                                   DIFFERENTIAL     TEMP
                                                    (IN.H20)      (DE6.F)
                                                DATE
                                                RUN NUMBER

                                                PROBE LENGTH • TYPE
                                                NOZZLE      I I.D.
                                                ASSUMED MOISTURE
                                                SAMPLE BOX NUMBER
                                                'METER BOX NUMBER
                                                METER HEAD OIFF.
                                                C FACTOR
                                                PROBE HEATER SETTING
                                                HEATER BOX SETTING
                                                REFERENCE PRESS. OIFF.
                                         10/30/81
                                            7-3

                                         SFT GLASS HEATED
                                          .394
                                         12.0

                                         FBI
                                         1.27
                                          .SB
                                         350.
                                         S50.
                                         1.50
                                                               DRV GAS METER  PUMP
                                                                   TEMP      VACUUM
                                                                  (DEG.F)    (IN.HG)
                                                                    SAMPLE
                                                                   BOX TEMP
                                                                   (DEG.F)
                                             IMPIN6ER
                                               TEMP
                                             (DEG.F)
                                                 DESIRED   ACTUAL
                                                               INLET  OUTLET
   INIT
0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0
110. 0
120.0
930
940
950
1000
1010
1020
1030
1040
1050
1100
1110
1120
~1130
TOTALS
AVERAGE
120.0
726.791
731.350
736.370
741.183
746.020
750.170
757.675
760.025
764.303
768.910
774.160
778.537
702.703

 55.912
                                           .060
                                           .060
                                           .060
                                           .070
                                           .050
                                           .050
                                           .070
                                           .050
                                           .050
                                           .080
                                           .050
                                           .050
                                         .72
                                         .72
                                         .72
                                         .87
                                         .62
                                         .62
                                         .67
                                         .62
                                         .62
                                         .99
                                         .62
                                         .62
                                         .72
.72
.72
.72
.87
.62
.62
.87
.62
.62
.99
.62
.62
916.
536.
550.
503.
507.
540.
536.
969.
562.
505.
916.
928.
                                .72   930.
56.
98.
63.
66.
69.
70.
72.
73.
74.
74.
74.
77.
               69.
-92.
92.
52.
52.
•56.
.56.
.58.
-99.
60.
62.
.63.
•64.
                 =97.
.0
.0
.0
.0
.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
339.
386.
326.
346.
403.
396.
376.
382.
319.
331.
339.
357.
                2.0   398.
 44.
 44.
 46.
 46.
 50.
:54.
 54.
 52.
 92.
 90.
 90.
'92.
                         90.

-------
               PARTICIPATE  FIELD  DATA  • RESULTS  TABULATION

    PLANT-  NAME AND  ADDRESS      ,         TEST TEAM  LEADER

    REPUBLIC  STEEL CLEVELAND               CLARKE
    TEST
7-3
                COKE OVEN OUTLET
to

TEST
TB
TF
TT
W-.
Y
ON
CP
PM

DATE
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
	 NET SAMPLING POINTS 	
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
	 PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
ENGLISH UNITS
10/30/81
*30
1130
120.0
12
.992
•394 IN
••«
.72 IN-H20
METRIC UNITS
10/30/81
930
1130
120.0
12
.992
10.0 MM
.84
18.2 IMM-H20
          DROP

VM        VOLUME OF DRY GAS SAMPLED
       	AT METER CONDITIONS

TM        AVERAGE GAS METER TEMP

VMSTD     VOLUME OF DRV GAS SAMPLED
          AT STANDARD CONDITIONS*

VLC     ~ T3TAL H»0 COLLECTED IN
          IMPIN6ER8 AND SILICA 6El,ML.

VMC       VOLUME OF HATER VAPOR
          AT STANDARD CONDITIONS*

BMO       PERCENT MOISTURE BY VOLUME

FMO       MOLE FRACTION DRY GAS

PC02      PERCENT C02 BY VOL., DRV

P02       PERCENT 02 BY VOL., DRY

PCO       PERCENT CO BY VOL., DRV

PN2       PERCENT N2 BY VOL.* DRV

MD        MOLECULAR NT-DAV STACK CAS

MMS       MOLECULAR NT-STACK GAS
                                               55.912  CU-FT
                                                         1.583 CU-M
63.0 F
52,351 SCF
ITfit
8.091 SCF
11.139
.866
4.00
11.00
.00
85.00
29.08
27.60
17.2
l.«»2
171.9
.229
13.39
.866
4.00
11.00
.00
85.00
29.08
27.60
C
SCM

SCM









-------
    PB        BAROMETRIC PRESSURE


    PSI       STATIC PRES OP  STACK  6*3


    PS        STACK PRES, ABS.


    TS        AVERAGE STACK TEMP


    VS        AV6 STACK CAS VELOCITY


    AS        STACK AREA


    OSSTD     STACK PLON RATE, DRY*


    OS        ttTUAL STACK fLO* RAT8


    ISO       PERCENT I80KINETIC


    MN        PILTERABLE PART
           	M6. EPA 5     	


    CS        PILTERABLE PART


    PMR       PILTERABLE PART
                EMISSION RATE
~i"~irBM'Ff'
                           IN.W6.
I
to
*>
u>
27
M
17
530
t«
7466
1573041
366206*
101



.92 IN-M6
.20 IN-M20
«83 IN-M6
P
.6 PP8
. 88-1N
. SCPH
. ACPH
.9
.0
.0000 OR/OSCP*
.000 L8/HR
709.17
-30.48
706.93
277.
6.0
4.817
44544.
103699.
101.9
.0
.000
.00
MM-HG
MM-H20
MM-HG
C
MRS
80-M
SCMH
ACMH


M6/D3C*
K6/HR

-------
           EXAMPLE  PARTICULATE CALCULATIONS TEST NO.   7-3

                COKE OVEN OUTLET



     VOLUME OF  DRY  GAS  SAMPLED AT  STANDARD CONDITIONS

     VMSTD  • (17.64? •  VM *  Y  * (PB •» PM / 13.6)) / (TM * 460.)

               IT.MT •   55.912  *  .991 • ( 27.92 *  ,716 / 13.6)
     VMSTO  « ...—-.—.......................................... •     52.351 03CF
                              ( 63.  * «60.)



     VOLUME OF  NATER VAPOR AT  STANDARD CONDITIONS

     VMC  «  .04707 • VLC

     VKC  •".WOT *  1TZ. •    8.0» ICF



     PERCENT MOISTURE IN  STACK BAS

     BMO  iTIOO. *  VWCJ / IVMSTD » VNC)

&              100. *  8.09
I    BNO  •  ...——»—..———...... *  tl.3*» PERCENT
M               3Z.351 *   B.09
(t^
^ ._	  _		  .	.                 	


     MOLE FRACTION  OF DRV STACK 6AS

     FMD  •  (100. *  BNO) / 100.

               100. «  1S.4
     FMD  •  ....................... •    .86*
                    100.



   ~~AVERA3£ MOLCeuLAir  REI6HT  OF DRY  STACK CAB

     MO • (PC02 • .44)  •  (P02  • .32)  * (PN2 • PCO) * .2$

     MD • ( 4.00*44/100)  • (11.0*32/100)  * ((tS.O* .0)  • 28/100 •   29.08
    MOLECULAR  NEI6HT  OF  STACK  GAS

    MMS  • MO • (1.  •  (8*0/100))  *  18.  •  (BNO/100)

    MNS  »   29.08*  (1. -(13.39/100))  4  18.  * (13.39/100) •   27.60

-------
     STACK  CAS  VELOCITY  AT  STACK  CONDITIONS

     DELP • SUM.  Of  THE  SORT(VH * (TS  »  460.)I

     VS  • 85.49 • CP • DELP /  (SORT(MMS  •  PS) •  PNTS)

     VS  • 09.49 •  .64 *   90.860 /  (SORT( 27.60 •  27.83)   •   12.  •    19.62 FPS



     STACK  «A8  VOLUMETRIC FLOW AT STACK  CONDITIONS

     OS  » VS *  AS *  3600/144

     OS  •    19.62 •   7466.  3600/144  *    3662069. ACM



     STACK  6AS  VOLUMETRIC FLON AT STANDARD CONDITIONS

     03STO  • 17.647  * 08 •  PS * (I.  -  (BMO/100))  /  (TS  * 460.)

               17.647 •     3662069.  *  27.83 • (I.  -  (13.39/100))
     QS3TO  • •-———i—•———-i—..—........—......... •     1373041. SCFH
                        ( S30. *  460.)
I   PERCENT  ISOKINETIC
NJ

£   ISO «  (305.58«(T8«460.))*((0.002669*VLC>«(VM*Y«(PB«(PM/13.6))/(TM«460.)))/(TT«VS*PS*DN*DN)

            (305.S8*( 530.+460.))*((0.002669*   172.)+(   55.912* ,»92»( 27.92+(    .718/13.6))/(  63.+460.)))
    ISO •  —.—.——.—..—....———.—.———.—..«—......................................... «  101.91  PERCENT
                                        120. •     19.62 •   27.83 •  .394 •  .394



    PAffTICUlATC LOADING — EPA METHOD 5  (*T 1TANOARD CONDITIONS)

    CS • 0.001 • MN * 15.43 / VMSTO

    CS « 0.001 *      .0 * 15.43 /    52.351 •      .000 6R/DSCF



    PARTICULATE LBS/HR •• EPA METHOD 5

    PMR •  CS • OSSTD / (15.43 • 453.6)

    PMR •     .000 •    1373041. / (15.43 « 453.6)  »      .00

-------
Run No.  7.3
     Sample volume =1.48 m3r  52.35scf
Example calculations
     CS (Part)  =64.8  71.48 =  43.fi  mo/m3
     CS (Part)  «  0.001  X64.8   x 15.437 52.35=  Q.niQ qr/dscf
                                     3
     CS (S02)   =	/	=	mg/m
               =	 x  24.06/	=	ppm
               =  0.001 x	x 15.43/	
gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2SOA
As H2S04.2H20
Sulfur dioxide
Sulfuric acid mist
As H2S04
As H2S04-2H20
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
64.8






- Concentration,
mg/m
43.8






gr/dscf
0.019






ppm







                                  A-2 46.

-------
                                                            FIELD  DAT*
I
NJ
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION COKE OVEN OUTLET
SAMPLE TYPE 7-4-MS-S50
OPERATOR CLARKE
AMBIENT TEMP. (DEB. F) 52.
BAR. PRESS. (IN. HG) 29.92
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 5530053
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .B4
THERM. NO.
LEAKAGE .015 CFM a 3.0 IN.HG
METER CALIB. FACTOR 1.016
READ » RECORD DATA EVERT 10.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY ORIFICE PRESSURE
POINT
NO.

INIT












TIME
(MIN.)

0
10.0
20.0
30.0
40.0
50.0
60.0
ro.o
60.0
90.0
100.0
110.0
120.0
TIME
(24-HR
f*i nf*v i
CLUCK 1
933
943
953
1003
1013
1023
1033
1043
1053
1103
1113
1123
1133
READING
(CU.FT.)

142.828
147.074
151.900
156.405
161. SOI
165*595
170.186
175.043
177.365
1*3.575
18B.728
193.253
197.533
HEAD
(IN.H20)

. —
.060
.060
.060
.070
.050
.050
.070
.050
.050
.080
.050
-— .050
DIFFERENTIAL
(IN.
DESIRED

.T2
.72
.72
.87
.62
.62
.87
.62
.62
.99
.62
.62
H20)
ACTUAL

.72
.72
.72
.87
.62
.62
.87
.62
.62
.99
.62
.62
STACK
TEMP
(DEG.F)


928.
541.
557.
504.
528.
544.
547.
564.
564.
507.
518.
531.
DATE 10/30/81
RUN NUMBER 7-4
PROBE LENGTH t TYPE 6 FT GLASS HEATED
NOZZLE 1 1.0. .397
ASSUMED MOISTURE 12.0
SAMPLE BOX NUMBER
PETER BOX NUMBER FB5
METER HEAD DIFF. 1.86
C FACTOR .88
PROBE HEATER SETTING 350.
HEATER BOX SETTING 350.
REFERENCE PRESS. DIFF. 1.50
DRV GAS METER PUMP SAMPLE IMPINGER
TEMP VACUUM
(DEC
INLET

60.
61.
65.
67.
71.
72.
76.
78.
78.
78.
80.
81.
.F) (IN.HG)
OUTLET

60.
60.
60.
61.
62.
65.
68.
70.
70.
71.
72.
73.
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
BOX TEMP
(DEG.F)


348.
390.
332.
346.
369.
350.
342.
340.
349.
350.
366.
354.
TEMP
(DEG.F)


36.
34.
32.
36.
40.
44.
43.
44.
46.
42.
•4.
46.
    TOTALS
    AVERAGE
120.0
54.705
                                         .72
                               .72   536.
72.
66.
1.0   353.
41.

-------
           PARTICIPATE FIELD DATA ft RESULTS TABULATION



PLANT* NAME AND ADDRESS               TEST TEAM LEADER



REPUBLIC STEEL CLEVELAND              CLARKE
TEST
7-4
COKE OVEN OUTLET
ENGLISH UNITS
TEST DATE
TB
TF
TT
NP
Y
ON
	 CP
PM
1
*? VM
.00 	
TM
VMSTD
VLC
V"C
BMO
FMO
PC02
P02
PCO
PN2
MD
MNS
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
	 PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRV GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL M«« COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF MATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL., DRY
PERCENT 02 BY VOL., DRY
PERCENT CO BY VOL., DRV
PERCENT N2 BY VOL., DRY
MOLECULAR NT-DRY STACK GAS
MOLECULAR XT-STACK GAS
10/30/81
933
1133
120
12
1


54
69
55
161
7
12

4
11

85
29
27
.0

.016
.397 IN
.84
.72 IN-H20
.705 CU-FT
.1 F
.560 SCF
.1
.912 SCF
,«T
.875
.00
.00
.00
.00
.08
.70
METRIC UNITS
10/30/81
933
1133
120
12
1
10

1
20
1
168

12

4
11

85
29
27
.0

.016
.1
.84
.549
.6
.573
.1
.224
.47
.875
.00
.00
.00
.00
.08
.70



MM

iMM-H20
CU-M
C
3CM

SCM









-------
     PB        BAROMETRIC PRESSURE
     PSI        STATIC PRES OP STACK GAS
     PS        STACK PRES, ABS.
     TS        AVERAGE STACK TEMP
     VS        AVG STACK GAS VELOCITY
     AS        STACK AREA
     OSSTD      STACK FLOM RATE,  DRT*
     os        ACTUAL STACK FLOM RATE
     ISO        PERCENT ISOKINETIC
     MN        FILTERABLE PART
                 M6. EPA 5
     CS        FILTERABLE PART
     PMR        FILTERABLE PART
                 EMISSION RATE
       •   66 DEC F,  29.92 IN.HG.
     29.92  IN-H6
     -1.20  IN-H20
     29.03  IN-MO
    536.    F
     I9.o   rps
   7466.   80-IN
1638107.    SCFH
3340*82.    ACFH
    102.3
       .0

       .0000 GR/DSCF*
       .000   LB/HR
   T59.97  MM-HG
   -30.48  MM-H20
   757.73  »M-H6
   280.    C
     5. 8   VP9
     4.817 80-M
 46386.    SCHH
100267.    ACMH
   102.3
      .0
      .000
       .00  KG/HR
M
^
VO

-------
Cn
o
      EXAMPLE PARTICIPATE CALCULATIONS TEST NO.   7-4

           COKE OVEN OUTLET



VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

VMSTO i (17.647 * VM * Y • (PB * PM / IS.6)) / (TM * 460.)

          17.647 *    S4.703 * 1.016 • ( 29.92 *  .716 /  13.6)
VMSTD » ————.———.———————.———— «      55.560  03CF
                         (  69. * 460.)



VOLUME OF WATER VAPOR AT STANDARD CONDITIONS

VNC • .04707 • VLC

VWC « .04707 *  166. »   7.91 SCF



PERCENT MOISTURE IN STACK GAS

BWO « (100. * VHCJ / (VMSTO » VHC)

          100. *   7.91
BWO * ———.—————— t 12.47 PERCENT
            55.560 *   7.91



MOLE FRACTION OF CRT STACK GAS

FMO « (100. • BNO) / 100.

          100. •  i*.5
FMO « ——•-•••••-—••••••« *   .875
               100.



AVERAGE MOLECULAR WEIGHT OF DRV STACK GAS

MO a (PC02 * .44) * (P02 « .32) » (PN2 «• PCO) • .26

MO s ( 4.00*44/100) * (1I.OOZ/100) • ((85.0* .0) • 28/100 *   29.08



MOLECULAR HEIGHT OF STACK GAS

MHS a MD * (1. - (BNO/100)) * 18. * (BNO/100)

MWS s  29.08* (1. -(12.47/100)) * 18. * (12.47/100) •   27.70

-------
      STACK GAS VELOCITY AT STACK CONDITIONS

      OELP > SUM. OF THE 8QRT(VH • (T3 » 460.))

      VS * 65.49 • CP • OELP / (SQRT(MN3 • PS) * PNTS)

      VS 9 65.49 *  .64 •   91.123 / (SORT( 27.70 * 29.63)  *  12. •   16.97 FPS



      STACK GAS VOLUMETRIC FLO* AT STACK CONDITIONS

      OS « VS • AS • 3600/144

      OS «   18.97 •  7466. 3600X144 •    3540602. ACPN



      STACK CAS VOLUMETRIC FLON AT STANDARD CONDITIONS

      QSSTD « 17.647 • OS • PS • (1. - (BNO/IOO)) / CT8 * 460.)

                17.647 •    3540662. *  29.65 • (1. - (12.47/100))
      OSSTO • ————.——————.————.—.——	*    1636107. SCFH
                         ( 536. * 460.)



      PERCENT ISOKINETIC

•f     ISO • (305.58*(TS+460.))*((0.002669*VLC)*(VM*r*(PB+(PM/13.6))/(TM«460.)))/(TT*VS*P8*ON*DN)

tn            (30S.56*( 536.«460.))M (0.0026*9*  160.)*(   54.705*1.016*(  29.92«(    .710/13.6))/(  69.4460.)))
*-•     ISO • -—————..—[[[ . |02.29 PERCENT
                                         120. •     16.97 •   29.83 •  .397 •  .397



      PARTICULATE LOADING — EPA METHOD  5 CAT STANDARD CONDITIONS)

      CS * 0.001 * MN » 15.43 / VMSTO

      CS » 0.001 *      .0 • 15.43 /    55.560 »     .000 6R/DSCF



      PARTICULATE L0S/HR — EPA METHOD 5


-------
Run No.  7-4
                           *\
     Sample volume =1-57 ^.55.56 scf

Example calculations

     CS (Part)  =62.6 /  1.57S  39.9  mq/m3

     CS (Part)  = 0.001  x 62-6 x 15.43755.56=  0.017 qr/dscf

     CS (S02)   =	/	=	mg/m3

               =	 x 24.06/	=	ppm

               = 0.001  x	x 15.43/	=	gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2$04
As H2S04-2H20
Sulfur dioxide
Sulfuric acid mist
As H2$04
As H2S04-2H20
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
62.6






, Concentration,
mg/m
39.9






gr/dscf
0.017






ppm







                                      A-252

-------
                                                           FIELD   DATA
to
Ui
U)
PLANT REPUBLIC STEEL
SAMPLING LOCATION COKE STACK
SAMPLE TYPE METHOD 9-400
OPERATOR 00/MP
AMBIENT TEMP. (DEG.F) 50.
BAR. PRESS. (IN. HG) 29.92
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530035
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .64
THERM. NO.
LEAKAGE .018 CFM 8 12.
METER CALIB. FACTOR 1.033
READ ft RECORD DATA
TRAVERSE
POINT
NO.

IN It"












SAMPLE
TIME
(MIN.)

0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
CLOCK
TIME
(24-HR

935
945
955
1005
1015
1025
1035
1045
1055
1105
1115
1125
1135
EVERY 10.0
GAS METER
READING
(CU.FT.)

•66.353
971.030
975.660
960.370
985.090
989.790
994.490
999.250
3.950
6.670
13.430
18.170
22.690
MINUTES
VELOCITY
HEAD
(IN.H20)


.070
.070
.070
.070
.070
.070
.070
.070
.070
.070
.070
.070
CLEVELAND
0 IN.HG

ORIFICE

PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.72
.72
.72
.72
.72
.72
.72
.72
.72
.72
.72
.72
H20)
ACTUAL

.72
.72
.72
.72
.72
.72
.72
.72
.72
.72
.72
.72

STACK
TEMP
(DEG.F)


520.
520.
520.
520.
520.
520.
520.
520.
520.
520.
520.
520.
DATE 10/30/81
RUN NUMBER 7-5
PROBE LENGTH ft TYPE 6* GLASS
NOZZLE t 1.0. .374
ASSUMED MOISTURE 11.0
SAMPLE BOX NUMBER
METER BOX NUMBER FB4
METER HEAD OIFF. t.aa
C FACTOR .92
PROBE HEATER SETTING 250.
HEATER BOX SETTING 250.
REFERENCE PRESS. DIFF. .18

DRY GAS METER
TEMP
(DEG.F)
INLET OUTLET

S3. 
-------
           PARTICIPATE FIELD DATA • RESULTS TABULATION
PLANT- NAME AND ADDRESS               TEST TEAM LEADER
REPUBLIC STEEL CLEVELAND              DO/MP
TEST
7-5
COKE STACK


TEST DATE
TB
TF
TT
NP
Y
DN
CP
PM
1 VM
NJ
(J\ ...
TM
VMSTD
VLC
VNC
BNO
FMD
PC02
P02
PCO
PN2
MO
MNS
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRV GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF ORT CAS SAMPLED
AT STANDARD CONDITIONS*
~" TOTAL H20 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF NATER VAPOR
AT STANDARD CONDITIONS*
" PERCENT MOISTURE SY VOLUME
MOLE FRACTION ORT GAS
PERCENT C02 BT VOL., DRY
PERCENT 02 BY VOL., DRV
PERCENT CO BT VOL., ORT
PERCENT N2 BY VOL., DRV
MOLECULAR NT-DRV STACK GAS
MOLECULAR MT-STACK GAS
ENGLISH UNITS
10/30/81
"Ml
1135
120.0
12
1.033
.374 IN
.84
.72 IN-H20
56.537 CU-FT
66.9 F
56.631 SCF
"IB9.1
6.901 SCF
	 13.16
.868
4.00
11.00
.00
65.00
29.08
27.62
METRIC UNITS
10/30/81
935
1135
120.0
12
1.033
9.5
.84
16.3
1.601
19.4
1.660
189.1
.252
13.18
.868
4.00
11.00
.00
85.00
29.08
27.62



•MM

• H.N.
CU-M
C
SCM

SCM









-------
      PB        BAROMETRIC PRESSURE


      PSI        STATIC PRES OF STACK CAS


      PS        STACK  PRES, ABS.


      TS        AVERAGE STACK  TEMP


      VS        AV6 STACK  GAS  VELOCITY


      AS        STACK  AREA


      OSSTD      STACK  FLOW RATE,  CRT*


      OS        ACTUAL STACK FLON RATE


      ISO        PERCENT ISOKINETIC


      MN        FILTERABLE PART
                  MG.  EPA  S


      CS        FILTERABLE PART


      PMR        FILTERABLE PART
                  EMISSION RATE


        *   68~ DEC F,   2*.92 tN.MC.
     29.92  IN-H6


     •1.20  1N-M20


     29.83  IN-HG


    S20.    F


     20.7   FPS


   7466.   80*IN


1803803.    SCFH


3867852.    ACFH


    110.5


       .0



       .0000 GR/DSCF*


       .000   LB/HR
   759.97  -KM-HG


   •30.48  KM-H20


   757.73  MM-MG


   271.    C


     4.3   fPS


     4.817 30-M


 51078.    SCHH


109520.    ACMH


   110.5


      .0



      .000 .CG/03CH


       .00  KG/MR
NJ
cn

-------
           EXAMPLE PARTICIPATE CALCULATIONS TEST NO.   7*5
                COKE STACK

     VOLUME Of OUT 6AS SAMPLED AT STANDARD CONDITIONS
     VMSTO • (17.647 * VM • Y • (PS * PM / 13.6)) / (TM » 460.)
               17.6*7 •    56.537 * 1.033 » ( 29.92 *  .710 / 13.6)
     VMSTO • ————————.............................. .     58.631 D8CF
                              (  67. • 4*0.)

     VOLUME OF MATER VAPOR AT STANDARD CONDITIONS
     VMC • .04707 • VLC
     VKC • .04707 •  189. •   8.90 SCF

     PERCENT MOISTURE IN STACK 6AS
     BHO * (100. * VMC) / (VMSTO * VHC)    ~
               100. *   8.90
     BHO • —....................... * 13.18 PERCENT
jP                S8.631 *   8.90
 I         	
K>
cn
**    MOLE FRACTION OF DRV STACK CAS
     FMO » (100. • BMO) / 100.
               IVO.-i~lI.ft                ~
     FMO « ——————.——. *   .868
                    100.
     AVERAGE MOLECULAR MEIOHT OF DRV STACK
     MO » (PC02 * .44) * (P02 * .32) » (PN2 » PCO) • .26
     MO « ( 4.00*44/100) * (11.0*32/100)  * ((65.0* .0) • 26/100 «   29.08

     MOLECULAR NEIGMT OF STACK CAS
     MH3 • MD • (1.  • (BNO/100)) * 16. *  (BNO/100)
     MMS «  29.06* (1. -(13.16/100)) * 18. • (13.16/100) «   27.62

-------
     STACK GAS VELOCITY AT STACK CONDITIONS

     DELP • SUN. OF THE SORTCVH * (TS » 466*))

     VS » 85.49 • CP • OELP / (SORT(MWS • P8) * PUTS)

     VS * 85.49 •  .84 •   99.390 / (90RT( 17.62 * 29.83)  •  12. •   20.72 FP3



     STACK CAS VOLUMETRIC PLOW AT STACK CONDITIONS

     03 • VS • AS • 3600/144

     QS •   20.72 •  7466. 3600/144 »    3867652. ACFM




     STACK CAS VOLUMETRIC FLON AT STANDARD CONDITIONS

     OSSTD » 17.647 • OS * PS * (1. • (BNO/iOO)) / (TS * 460.1

               17.647 •    3867652. •  29.63 • (1. • (11.18/100))
     OSSTD » ——————.................................... •    1803803. 3CFH
                        ( 520. * 460.)




 I    PERCENT ISOKINETIC
to
^   ISO • (305.58MTS»460.))M(0.002669*VLC)*(VM«y*(PBt(PM/13.6))/(TM«460.)))/(TT*VS*P8*ON«ON)

            (305.58M 520.»460.))«((0.002669*  189.)*(   56,537*1.033*( 29.92«(    .720/13.6))/(  67.*460.)))
     ISO « .————[[[i. . U0.46 PERCENT
                                        120. •     20.72 •   29.83 •  .374 •  .374




     PARTICULAR LOAOINC — EPA METHOD 5 CAT STANDARD CONDITIONS)

     CS * 0.001 • MN * 15.43 / VMSTO

     CS * 0.001 •      .0 • 15.43 /    58.631 •     .000 CR/OSCF




     PARTICULATE LBS/HR — EPA METHOD 5


-------
Run No.  7.5
                           o
     Sample volume =1.66  m T 58.63  scf
Example calculations
     CS (Part) = 40.2/  1.66=  24.2 mq/m3
     CS (Part) = 0.001  x 40.2 x  15.43/58.63 =  0.010 qr/dscf
                                     3
     CS (S02)   =	/	=	mg/m
               =_	 x 24.06/	=	ppm
               = 0.001 x	x  15.43/	
gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Sulfur dioxide
Sulfuric acid mist
As H2S04
As H2S04-2H20
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
40.2






3 Concentration,
mg/m
24.2






gr/dscf
0.010






ppm







                                    A-258

-------
                                                           FIELD  DATA
to
PLANT REPUBLIC STEEL CLEVELAND
9AMPLIN6 LOCATION COKE STACK
SAMPLE TYPE METHOD 6*600
OPERATOR DO/MP
AMBIENT TEMP. (DEC. FJ so.
BAR. PRESS. (IN. HG) 29.92
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530215
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .64
THERM. NO.
LEAKAGE .000 CFM 8 6.0 IN.H6
METER CALIB. FACTOR .982
READ t RECORD DAT* EVERY 10.0 MINUTES
TRAVERSE SAMPLE CLOCK CAS METER VELOCITY ORIFICE PRESSURE
POINT TIME TIME READING HEAD DIFFERENTIAL
NO. (MIN.) (24-HR (CU.FT.) (IN.H20) (IN.H20)

INIT 0
10.0
20.0
30.0
40.0
50.0
60. 0
70.0
ao.o
90.0
100.0
110.0
120.0
l»fc.VVn/
934
944
954
1004
1014
1024
1034
1044
1054
1104
1114
1124
1134

421.124
425.840
430.460
435.190
439.950
444.670
449.400
454.130
458.620
463.510
468.200
472.970
477.636
DESIRED

.070
.070
.070
.070
.070
.070
.070
.070
.070
.070
.070
.070
.42
.42
.42
.42
.42
.42
.42
.42
.42
.42
.42
.42
ACTUAL

.75
.75
.75
.75
.75
.75
.75
.75
.75
.75
.75
.75
STACK
TEMP
(DEG.F)
DATE 10/30/61
RUN NUMBER 7-6
PROBE LENGTH ft TYPE 4* QUARTZ
NOZZLE I I.D. .590
ASSUMED MOISTURE 11.0
SAMPLE BOX NUMBER
METER BOX NUMBER FB8
METER HEAD OIFF. 1.91
C FACTOR .94
PROBE HEATER SETTING 250.
HEATER SOX SETTING 250.
REFERENCE PRESS. OIFF. .03
DRY GAS METER PUMP SAMPLE IMPINGES
TEMP VACUUM BOX TEMP TEMP
(DEG.F) (IN.HG) (OEG.F) (DEG.F)
INLET OUTLET

520.
520.
520.
520.
520.
520.
520.
520.
520.
520.
520.
520.

47.
52.
57.
62.
65.
68.
69.
70.
70.
72.
73.
74.

46.
47.
49.
51.
•S3.
56.
58.
60.
61.
63.
63.
65.

3.1
3.2
3.7
4.0
4.2
4.2
4.3
5.2
6.3
7.3
7.7
7.9

615.
601.
593.
586.
565.
577.
574.
569.
571.
567.
590.
594.

38.
40.
40.
46.
52.
44.
44.
40.
40.
44.
44.
46.
   TOTALS
   AVERAGE
120.0
56.714
                                        4.42
                               .75   520.
65.
56.
5.1   587.
43.

-------
           PARTICULATE FIELD DATA ft RESULTS TABULATION



PLANT- NAME AND ADDRESS               TEST TEAM LEADER



REPUBLIC STEEL CLEVELAND              DO/HP
TEST
7-*
COKE STACK
ENGLISH UNITS
TEST DATE
TB
TF
TT
NP
Y
ON
CP
PM
>
£ VM
o
TM
VMSTD
VLC
VNC
BMO
FMD
PC02
P02
PCO
PN2
MD
MMS
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL M20 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF MATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL., DRV
PERCENT 02 BY VOL., DRY
PERCENT CO BY VOL., DRY
PERCENT N2 BY VOL., DRV
MOLECULAR NT-DRY STACK GAS
MOLECULAR NT-STACK GAS
10/30/81
43*
1134
120
12



56
60
56
110
B
13

4
11

85
29
27
.0

.982
.590 IN
.84
.75 IN-H20
.714 CU-FT
.5 F
.604 SCF
,3
.487 SCF
.04
.870
.00
.00
.00
.00
.08
.64
METRIC UNITS
10/30/81
934
1134
120.
12
•
15.
•
19.
1.
IS.
1.
180.
•
13.
•
4.
11.
•
85.
29.
27.
0

982
0
84
1
606
8
603
3
240
04
870
00
00
00
00
08
64



.MM

MM-M20
CU-M
C
3CM

3CM









-------
   PB        BAROMETRIC PRESSURE

   PSI       STATIC PRES Of STACK 0*3

   PS        STACK PRES, ABS.

   TS        AVERAGE STACK TEMP

   VS        AV6 STACK 6*3 VELOCITY

   AS        STACK AREA

   OSSTD     STACK FLON RATE* DRY*

   OS        ACTUAL STACK FLOW RATE

   ISO       PERCENT ISOKINETIC

   MN        FILTERABLE PART
               M6. EPA 5

   CS        FILTERABLE PART

   PMR       FILTERABLE PART
               EMISSION RATE

      •  fcT DEO f,  29.92 IK.MC.
     29.92  IN-H6

     •1.20  1N-M20

     89.83  IN-H6

    920.    F

     20.7   FPS

   ?«66.   SO-IN

1806240.    SCFM

            ACFH

     42.8

       .0


       .0000 8R/D3CF*

       .000   LB/HR
   739.97  MM-HG

   •30.08  'MM-M20

   T5T.73  'MM-H6

   271.    C

     6.3   I«PS

     4.817 SO-M

 S1147.    SCMH

109489.    ACMH

    42.8

      .0
      .000

       .00  KG/MR
ro.

-------
           EXAMPLE PARTICULATE CALCULATIONS TEST  NO.    7-6

                COKE  STACK



     VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

     VMSTO •  (17.647  • VM • Y •  (PB * PM / IS.6)) / (TM * 460.)

               17.647 •    56.714 •  .982 • ( 29.92 *   .750 /  13.6)
     VM3TD »  •—....—.——.....................................  •      56.604 DSCF
                              (  60. * 460.)



     VOLUME OF NATER  VAPOR AT STANDARD CONDITIONS

     VNC * .04707 • VLC

     VMC « .04707 •   180. •   8.49 SCP



     PERCENT  MOISTURE IN STACK GAS

     BWO » UOO. * VWCJ / (VMSTO » VWC)

               100. •   8.49
     BMO a ....................——.. • 13.04 PERCENT
                 56.604 *   8.49

to

N   MOLE FRACTION OF DRY STACK GAS

     FMD » (100. - 8HO) / 100.

               100. -  13.6
     FMD a ....................... •   .870
                    100.



~     AVERAGE  MOLECULAR WEIGHT OF DRY STACK BAB

     MO * (PC02 * .44) » (P02 • .32) * (PN2 * PCO) • .28

     MO * ( 4.00*44/100) * (11.0*32/100) » ((85.0* .0)  * 28/100 «   29.08



     MOLECULAR WEIGHT OF STACK GAS

     MWS * MD • (1. - (BNO/100)) « IB. • (BNO/100)

     MWS a  29.06* (1. -(13.04/1001) •» 18. • (13.04/100) a   27.64

-------
STACK GAS VELOCITY AT STACK CONDITIONS

DELP e SUM. OF THE SORT(VH • (TS •* 1*0.))

V3 « 85.49 • CP • DELP I (SORT(NWS • PS) • PNTS)

VS a 85.49 •  .84 •   99.390 / (80RT( 27*64 • 29.83)  *  12. »   20.71 FPS




STACK CAS VOLUMETRIC FLOW AT STACK CONDITIONS

OS a VS • AS • 3600/144

OS «   26.71 *  7466. 3600/144 *    38665M. ACFH




STACK 6AS VOLUMETRIC FLOW AT STANDARD CONDITIONS

OSSTD a 17.647 * OS • PS • (1. • (BNO/100)) / (TS « 460.)

          17.647 •    3866549. •  29.83 • (1. - (13.04/100))
OSSTD a -------——————.——.—.———.—-— •    1806240. SCFH
                   ( 520. * 460.)




PERCENT ISOKINETIC

ISO « (305.58«(TS»«60.))«((0.002669«VLC)*(VM*T»(PB*(PM/13.6))/(TM»«60.))}/(TT«V3«PS«DN«ON)

       (305.38M S20.«460.))*((0.002669*  180.)*(   S6.714* .982*( 29.92«(    ,750/13.6))/(  60.«460.)))
ISO « ....—.—..—————.——.—..——..........—..—...................................—.. «  42.79 PERCENT
                                   120. •     20.71 •   29.83 •  .590 •  ,590




PARTlCULATE LOA01NO " EPA METHOD 5 (AT STANDARD CONDITIONS)

CS * 0.001 • MN • 15.43 / VMSTD

CS a 0.001 *      .0 • 15.43 /    56.604 a     .000 6R/DSCF




PARTlCULATE LBS/HR — EPA METHOD 5

PMR a CS * OSSTD / (15.43 • 453.6)

PMR a     .000 *    1806240. / (15.43 • 493.6) a      .00

-------
Run No.  7.6
     Sample volume  =  1.60 m  t 56.60 scf
Example  calculations
     CS  (Part)  =24.3/1.60=15.2  mq/m3
     CS  (Part)  =  0.001 x24-3 x 15.43/ 56.60= 0.007  qr/dscf
                                     .3
     CS (S02)   =	/	=	mg/nT
               =	 x 24.06/	=	ppm
               =  0.001 x	x 15.43/	
gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Sulfur dioxide
Sul f uric acid mist
As H2S04
As H2S04-2H20
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
24.3






3 Concentration,
mg/m
15.2






gr/dscf
0.007






ppm







                                    A-264

-------
                                                               FIELD  DATA
                PLANT
                SAMPLING LOCATION

                SAMPLE  TYPE
                OPERATOR
                AMBIENT TEMP.(DEC.F)
                BAR.PRESS.(IN.H6)
                STATIC  PRESS.(IN.H20)
                FILTER  NUMBER(S)
                STACK INSIDE  DIM.(IN)
                PITOT TUBE COEFF.
                THERM.  NO.
                LEAKAGE
                METER CALIB.  FACTOR
                     REPUBLIC STEEL CLEVELAND
                     COKE OVEN OUTLET

                     6-3-M8-350
                     CLARKE
                      65.
                     29.93
                     -1.20
                     3530061
                       97.90    .00
                       .84
                      .000 CFM
                      .992
                3.0 IN.HG
               READ  & RECORD DATA EVERT  10.0 MINUTES
                         DATE
                         RUN NUMBER

                         PROBE LENGTH I TYPE
                         NOZZLE      I I.D.
                         ASSUMED MOISTURE
                         SAMPLE BOX NUMBER
                         METER BOX NUMBER
                         METER MEAD DIFF.
                         c FACTOR
                         PROBE HEATER SETTING
                         HEATER BOX SETTING
                         REFERENCE PRESS. DIFF.
                                         to/so/ai
                                            8-1

                                         « FT GLASS HEATED
                                          .378
                                         12. 0

                                         FBI
                                         1.87
                                          .88
                                         350.
                                         350.
                                         1.50
TRAVERSE
POINT
NO.

SAMPLE
TIME
(MIN.)

CLOCK
TIME
(24-HR
CLUCK J
GAS METER
READING
(CU.FT.)

VELOCITY
HEAD
(IN.H20)

ORIFICE PRESSURE
DIFFERENTIAL
(IN.H20)
DESIRED ACTUAL
STACK
TEMP
(OEG.F)

DRY GAS METER
TEMP
(DEG.F)
INLET OUTLET
PUMP
VACUUM
(IN.HG)

SAMPLE
BOX TEMP
(OEG.F)

IMPINGER
TEMP
(DEG.F)

           INIT
CTi
U1
0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
1438
1448
1458
1508
1518
1528
1538
1548
1608
1618
1628
1638,
1648a
       TOTALS
       AVERAGE
120.0
783.033
787.530
792*020
796.760
801.150
805.468
810.000
814.800
819.987
824.901
829.699
834.999
840.297

 57.264
                               .090
                               .050
                               .060
                               .050
                               .050
                               .050
                               .060
                               .070
                               .060
                               .060
                               .070
                               .070
.62
.62
.73
.62
.62
.62
.73
.87
.T3
.73
.87
.62
.62
.73
.62
.62
.62
.73
.87
.73
.73
.87
.87
540.
558.
570.
519.
530.
537.
542.
559.
575.
526.
536.
546.
                                                  .72    545.
75,
76.
80,
82.
83.
64.
86.
86.
86.
86.
86.
86.
                                               83.
70.
69.
70.
71.
72.
72.
73.
74.
74.
74.
74.
74.
                                78.
2.0
2.0
2.0
3.0
2.0
2.0
2.0
2.0
2.0
3.0
3.0
3.0
319.
347.
320.
332.
289.
298.
314.
342.
351.
351.
365.
359.
                               2.3    332.
56.
56.
56.
58.
60.
58.
58.
58.
98.
58.
57.
58.
                                          58.
        Vinal  time should be 1638.

-------
           PARTICIPATE FIELD DATA • RESULTS TABULATION



PLANT- NAME AND ADDRESS               TEST TEAM LEADER



REPUBLIC STEEL CLEVELAND              CLARKE
TEST
e-i
COKE OVEN OUTLET

TEST
TB
TF
TT
NP
V
ON
CP
PM
1
to VM
O^
O^ •
TM
VMSTD
VLC
VNC
BNO
FMD
PC02
P02
PCO
PN2
MO
MMS

DATE
TIME-START
TIME-FINISH
NET TIME OF TEST, MtN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL M20 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF NATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL., DRV
PERCENT 02 BY VOL.* DRY
PERCENT CO BY VOL., DRV
PERCENT N2 BY VOL., DRV
MOLECULAR NT-DRY STACK GAS
MOLECULAR NT-STACK GAS
ENGLISH UNITS
10/30/81
1438
1648
110,0
12
.992
.378 IN
.84
.72 IN-M20
97.264 CU-FT
77.6 F
55.906 SCF
W.8
9.405 SCF
14.40
.656
4.30
9,30
.00
86.40
29.06
27.47
METRIC UNITS
10/30/81
1438
1648
120.0
12
.992
9.6 'MM
.84
18.3 MM-H20
1.622 CU-M
25.3 C
1.583 SCM
199.8
.266 SCM
14.40
.836
4.30
9.30
.00
86.40
29.06
27.47

-------
     PB        BAROMETRIC PRESSURE
     PSI       STATIC PRES OF STACK CAS
     PS        STACK PRES, ABS.
     T3        AVERA6E STACK TEMP
     VS        AV6 STACK 6AS VELOCITY
     AS        STACK AREA
     QSSTD     STACK FLOW RATE* DRY*
     OS        ACTUAL STACK FLOW RATE
     ISO       PERCENT ISOKINETIC
     MN        FILTERABLE PART
             	MG. EPA 5
     CS        FILTERABLE PART
     PMR       FILTERABLE PART
                 EMISSION RATE
        *  66 DEO F,  29.92 1N.H6.
     29.93  IN-H6
     -1.20  IN-MZO
     89.64  IN-H6
    S«5.    F
     19.Z   FPS
   7466.   SQ-IN
U04S20.    8CFH
            ACFN
    IIS.9
       .0

       .0009 6R/OSCF*
       .000   LB/HR
        2  MM-H6
   •30.48  HM-M20
   737.98  MM«H6
   285.    C
     5.8   MPS
     4.817 SO-M
 45435.    SCMH
101278.    ACMH
   115.9
      .0

      .000 ne/oso
       .00  K6/HR
>
to

-------
            EXAMPLE PARTICIPATE CALCULATIONS TEST NO.   8-1

                 COKE OVEN OUTLET



      VOLUME OF DRV CAS SAMPLED AT STANDARD CONDITIONS

      VMSTD « (17.647 • VM • T • (Pfl * PM / IS. 6)) / (TM * 460.)

                17.647 •    57.264 •  .992 * ( 29.93 *  .719 / 13.6)
      VMSTD « —————.— ———...— ........... ............. •     55.906 OSCF
                               (  78. * 460.)



      VOLUME Of HATER VAPOR AT STANDARD CONDITIONS

      VMC  • .04707  • VLC

      VNC  « .0*707  •  200. m   9.40
      PERCENT MOISTURE IN STACK CAS

      BHO * (100.  *  VNC)  / (VMSTD * VHC)

te               100. *   9.40
7     BHO « ———.—....— ........ •  14.40 PERCENT
NJ                 55.906  •   9.40
oo
      MOLE FRACTION OP DRV  STACK  6AS

      FMD  « (100.  . BNO)  /  100.

          -     100. -  I*.i
      FMD  » —.«-.-.••——-—•• •   .896
                     100.
      *VER*6E  MOLECULAR  NEIGHT  OF  DRV STACK 6AS

      MO  *  (PCOZ *  .44)  •  (P02  *  .32) » (PN2 » PCO)  * .20

      MD  *  ( 4.30*44/100)  *  ( 9.3*32/100)  * ((86.4*  .0)  * 28/100 *   29.06



      MOLECULAR  NEI6HT OF  STACK CAS

      MHS » MD • (1.  • (BMO/100))  * 18. •  (BNO/100)

      MMS i 29.06*  (1.  -(14.40/100)) * 18. * (14.40/100) •   27.47

-------
      STACK  GAS  VELOCITY  AT  STACK  CONDITIONS

      DELP • SUM.  Of  THE  8QRT(VH • (TS  *  460.))

      VS  « 85.49 • CP • OELP /  (SORT(MNS  *  F8)  •  PNTS)

      V3  » 85.49 *  .84 •   91.672 /  (SQRT( (7.4? •  29.84)   •   12.  •   19.16 FPS



      STACK  6AS  VOLUMETRIC PLOW AT STACK  CONDITIONS

      03  > VS •  AS •  3600/144

      OS  *    19.16 •   TI66.  3600/144  •    357(567. ACPM



      STACK  GAS  VOLUMETRIC FLOW AT STANDARD CONDITIONS

      OSSTD  • 17.647  • OS •  PS  * Cl.  -  (BNO/100)) /  (T8 »  «60.)

                17.647 *     3576587.  •  29.04 •  (1.  •  (14.40/100))
      OSSTD  • .—.—...————....—...........———— •    1604520.  3CFH
                         ( 545. »  460.)



      PERCENT ISOKINETIC

"T     ISO »  (305.3«<>(TS«460.))*((0.00*669*VLC)*(VM*Y*(PB*(PM/13.6))/(TM«460.)))/(TT«VS*M*DN*DN)
to
2         "   (30*.«Mr*««.»*60.))«((0.002i4>«i  200. )*(  57.264* .992«(  29.93*(     .719/13.6))/(   7B.*fl60.)))
      ISO »  —.—...——.—.——..—......—.......—................................................. • 115.92 PERCENT
                                         120. •      19.16 *    29.84 •   .378  *   .378



      PARTiCULAtt  LOADING — EPA METHOD 5 IAT STANDARD  CONDITIONS)

      CS  « 0.001 • MN * 15.43 / VMSTD

      CS  » 0.001 *     .0 * 15.43 /    55.906 *     .000 GR/DSCF



      PARTICIPATE  LBS/HR  •"  EPA METHOD 5

      PMR *  CS * OSSTD /  (15.43 •  453.*)

      PMR r      .000  •   1604520.  /  (15.43 * 453.6) *       .00

-------
Run No. 8.1

                           3
     Sample volume = 1.58 m T  55.91  scf


Example calculations


     CS (Part) = 65.3/1.58 = 41.^ mq/m


     CS (Part) = 0.001  X65.3  x 15.43/  55.91=

                                      3
                                          n.Dia qr/dscf
CS (S02)
          =	 x 24.06/	=	ppm

          = 0.001 x	x 15.43/	
                                                     gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Sulfur dioxide
Sul f uric acid mist
As H2S04
As H2S04-2H20
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
65.3






3 Concentration,
mg/m
41.3






gr/dscf
0.018






ppm







                               A-270

-------
                                                        FIELD  DATA
        PLANT
        SAMPLING LOCATION
                     REPUBLIC STEEL CLEVELAND
                     COKE OVEN OUTLET
                                               DATE
                                                   NUMBER
                          10/30/81
                             e-2
SAMPLE TYPE 8-2-M5-350
OPERATOR CLARKE
AMBIENT TEMP.(OEG.F) 65.
BAR. PRESS. (IN.HG) 29.93
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530034
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM 9 3.
METER CALIB. FACTOR 1.016
READ & RECORD DATA EVERT 10.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY
POINT TIME
NO. (MIN.)

INIT 0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
TIME
(24-HR

1441
1451
1501
1511
1521
1331
1541
Ib51
1601
1611
1621
1631
1641
READING
(CU.FT.)

197.754
202.330
206.710
211.485
215.873
220.536
224.460
229. 31b
234.210
238.500
243.000
248.026
253.000
HEAD
(IN.H20)

—
.050
.050
.060
.050
.050
— .050
.060
.070
.060
.060
.070
.070
0 IN.HG
ORIFICE
PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.62
.62
.73
.62
.62
.62
.73
.87
.73
.73
.87
.87
H20)
ACTUAL

.62
.62
.73
.62
.62
.62
.73
.87
.73
.73
.87
.87
STACK
TEMP
(DEG.F)


540.
559.
570.
521.
529.
540.
546.
563.
518.
529.
540.
547.
PROBE LENGTH ft TYPE 5 FT GLASS HEA
NOZZLE : 1.0. .397
ASSUMED MOISTURt 12.0
SAMPLE BOX NUMBER
METER BOX NUMBER FB5
METER HEAD OIFF. 1.86
C FACTOR .88
PROBE HEATER SETTING 350.
HEATER BOX SETTING 350.
REFERENCE PRESS. DIFF. 1.50
DRY GAS METER PUMP SAMPLE IMPINGER
TEMP VACUUM
(DEG
INLET

85.
85.
87.
A9.
90.
91.
90.
90.
91.
90.
90.
90.
.F) (IN.HG)
OUTLET

84.
84.
84.
84.
84.
80.
84.
83.
83.
83.
83.
83.
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
BOX TEMP
(DEG.F)


338.
364.
343.
338.
315.
319.
305.
319.
329.
346.
361.
352.
TEMP
(DEG.F)


50.
48.
46.
46.
46.
44.
46.
44.
46.
40.
44.
45.
TOTALS
AVERAGE
120.0
55.246
                                         .72
                               .72   542.
89.
84.
1.0
336.
46,

-------
ro
               PARTICULATE FIELD DATA ft RESULTS TABULATION



    PLANT- NAME AND ADDRESS               TEST TEAM LEADER




    REPUBLIC STEEL CLEVELAND              CLARKE
    TEST
e-2
COKE OVEN OUTLET
ENGLISH UNITS
TEST DATE
TB
TF
TT
NP
Y
ON
CP
PM
VM
TM
VMSTD
VLC
VNC
BNO
FMD
PC02
POZ
PCO
PN2
MO
MNS
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRV GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H20 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF HATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRV GAS
PERCENT C02 BY VOL.r DRV
PERCENT 02 BY VOL., DRY
PERCENT CO BY VOL., DRV
PERCENT N2 BV VOL., DRY
MOLECULAR NT-DRY STACK GAS
MOLECULAR XT-STACK GAS
10/30/81
1441
1641
120
12
1



55
06
54
206
9
15
. *
4
9

86
29
27
.0

.016
.397 IN
.84
.72 IN-H20
.246 CU-FT
.3 F
.364 SCF
.2
.706 SCF
.15
.849
.30
.30
.00
.40
.06
.38
METRIC UNITS
10/30/81
1441
1641
120.
12
1.
10.
"
18.
1.
30.
1.
206.
•
15.
.
4.
9.
.
86.
29.
27.
0

016
1
8Q
3
564
2
539
2
275
15
849
30
30
00
40
06
38



KM

PM-H20
CU-M
C
SCM

SCM









-------
   PB         BAROMETRIC  PRESSURE


   PSI        STATIC  PRES OF  STACK  GAS


   PS         STACK PRES,  ABS.


   TS         AVERAGE STACK TEMP


   VS         AVG  STACK GAS VELOCITY


   AS         STACK AREA


   08STD      STACK PLOW  RATE*  DRY*


   OS         ACTUAL  STACK FLOH RATE


   ISO        PERCENT ISOKINETIC


   MN         FILTERABLE  PART
               MG. EPA 5


   CS         FILTERABLE  PART


   PMR        FILTERABLE  PART
               EMISSION  RATE


     *  68 DEC F,   29.92 1N.H6.
     29.93  IN-HG

     -1.20  IN-H20

     29.64  IN-HG


    542.    F

     19.2   FPS

   7466.   SO-IN

15*5254.    SCFH


3576610.    ACFH

    102.8

       .0



       .0000 GR/OSCF*

       .000   LB/HR
   760.22  KM-HG


   -30.08  CM-M20


   T57.98  KM-HR


   283.    C


     5.8   VPS


     4.817 SO-M


 45175.    SO'H


101279.    AC^H


   102.8


      .0



      .000 PG/DSCP

       .00  KG/HR
to
~4
U)

-------
             EXAMPLE PARTICIPATE CALCULATIONS TEST  NO.    e-a
                  COKE OVEN OUTLET

       VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS
       VMSTO *  (17.647 * VH * T * (PB * PM / Hi6))  /  (TM * 460.)
                 17.647 •    55.346 • 1.016 * ( 24.93  +   .719  /  13.6)
       VMSTD *  — — — — - ------ — — . ---- ..... --------------------  -      54.364 DSCF
                                (  86. *  460.)

       VOLUME OF MATER VAPOR AT STANDARD  CONDITIONS
       VMC * .04707 • VLC
       VRC *~.04707 *  206; a   ^.7
       PERCENT MOISTURE IN STACK GAS
      ~ BWO *"UOO. » VHCr /  tVWSTO * VWC)
                 100. *   9.71
       BHO «————"--—— ---- . ft  15.15 PERCENT
                   S4.364 +   9.71
>
 1     ..........     "   -....-....  .  .          ..... ,_
to
4*      MOLE FRACTION OF DRV  STACK GAS
       FMO =  (100. - BHO) /  100.
                 100. *  15.1
       FMD «  .-.——..-— ......... -   .849
                      100.
       AVERAGE MOLECULAR WEIGHT OF ORT STACK GAS —
       MO = (PC02 * .44) *  (P02 * .32) *  (PN2 » PCO)  •  .28
       MO * ( 4.30*44/100)  *  ( 9.3*32/100) * ((86.4*  .0)  *  26/100  *    29.06

       MOLECULAR HEIGHT OF  STACK GAS
       MHS a MD • (i. - (BMO/ioo)) *  is.  * (BNO/IOO)
       MHS a  29.06* (1. *(15.15/100)) »  18. • "(15.15/100)  •    27.38

-------
        STACK  GAS  VELOCITY  AT  STACK  CONDITIONS

        DELP « SUM.  OF  THE  SORT(VH * (TS  *  060.))

        VS  = 95.49 • CP  • OELP /  (SORT(MNS  *  PS) •  PNTS)

        VS  s 85.49 •  .80 •    91.534 /  (30RT( 27.38 *  39.80)   *   12.  «    19.16  FPS




        STACK  6AS  VOLUMETRIC FLO* AT STACK  CONDITIONS

        OS  s VS  •  AS *  3600/144

        OS  =    19.16 *   7466.  3600/144  *    357««10. ACFH




        STACK  GAS  VOLUMETRIC FLOW AT STANDARD CONDITIONS

        OSSTD *  17.647 • OS •  PS • (!;-»  (BNO/tOO))  /  (TS * 460.)

                  17.647 »     3576610.  *  29.84 • (I.  -  (15.15/100))
        OSSTD  *  ——	———	.....................	..	. x    1595254. SCFH
                           ( 542. «•  460.)




>       PERCENT  ISOKINETIC

^       ISO «  (305.58*(TS»460.))«((0.002669»VLC)«(VM»r«(PB«(PM/13.6))/(TM«460.)))/(TT«VS<»P3«DN*DN)
cn
               (305.58*( 542.*460.))M(0.002669"  206.)»(   55.246*1.016*( 29.93»(    .719/13.6))/(   86.*460.)))
        130 »  ..........................	..............	.	............................	.	.... •  102.78  PERCENT
                                           1?0. •      19.16 •   29.84 «   .397 •   .397




        PARTICIPATE LOADING »* EPA METHOD 5 (AT STANDARD CONDITIONS)

        CS  c 0.001 • MN  • 15.43 / VMSTO

        CS  = 0.001 •      .0 • 15.43 /    54.364 «     .000 GR/DSCF




        PARTICULAR LBS/HR —  EPA METHOD  5

        PMR «  CS * OSSTD /  (15.43 *  453.6)

        PMR •      .000 *    1595254.  /  (15.43 • 453.6) *       .00

-------
Run No.  8.2
     Sample volume =1.54 m t 54.36 scf
Example  calculations
     CS  (Part)  =76.0/1.54  g  49.4  mq/m3
     CS  (Part)  =  0.001  x  76.0 x 15.43/54.36 = 0.022   qr/dscf
                                     3
     CS (S02)   =	/	=	mg/m
               =	 x  24.06/	=	ppm
               =  0.001 x	x 15.43/	
gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Sulfur dioxide
Sulfuric acid mist
As H2S04
As H2S04-2H20
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
76.0






3 Concentration,
mg/m
49.4






gr/dscf
0.022






ppm







                                      A-276

-------
                                                             FIELD  DATA
 N>
~
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION NO.t COKE BATTERY OUTLET
SAMPLE TYPE PART/H2304/302
OPERATOR BRUFFEY
AMBIENT TEMP, (DEC. F) 78.
BAR. PRESS. (IN. H6) 29.93
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530120
STACK INSIDE DIM. (IN) 47.50 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM a 9.0 IN.H6
METER CALIB. FACTOR 1.003
READ t RECORD DATA EVERY 10.0 MINUTES
TRAVERSE SAMPLE CLOCK CAS METER VELOCITY ORIFICE PRESSURE
POINT
NO.

iNlf"












TIME
(MIN.)

0
10.0
20.0
30.0
00. 0
50.0
60.0
70,0
80.0
90.0
100.0
110.0
120.0
TIME
(24-HR
f*l flfftf %
CLUCK/
1418
1448
1458
1508
1518
1528
1538
1548
1558
1608
1618
1628
1638
READING
(CU.FT.)

48.689
S3. 490
58.200
63.360
68.090
72.820
77.640
82.800
88.390
93.580
98.750
104.320
109.886
HEAD
(IN.H20)

—
.050
.050
.060
.050
.050
.050
.060
.070
.060
.060
.070
.070
DIFFERENTIAL
(IN.
DESIRED

.62
.62
.T3
.«2
.62
.62
.73
,87
.73
.73
.87
.S7
H20)
ACTUAL

.62
.62
,T3
.62
.62
.62
.73
,•7
.73
,73
.87
,«7
STACK
TEMP
(DE6.F)


540.
558.
570.
519.
530.
537.
543.
559.
575.
527.
538.
545.
DATE 10/30/81
RUN NUMBER 8-3
PROBE LENGTH • TYPE 5* HEATED GLASS
NOZZLE I 1.0. .397
ASSUMED MOISTURE 12.0
SAMPLE BOX NUMBER 0
METER BOX NUMBER FB2
METER HEAD DIFF. 1.76
C FACTOR .86
PROBE HEATER SETTING 350.
HEATER BOX SETTING 350.
REFERENCE PRESS. DIFF. .15
DRY GAS 'METER PUMP SAMPLE IMPINGER
TEMP
(DE6
INLET

76.
77.
81.
83.
85.
86.
87.
88.
89.
88.
87.
87.
.F)
OUTLET

74.
75.
76.
77.
78.
79.
80.
80.
81.
82.
82.
81.
VACUUM
(IN.HG)


2.0
2.0
2.0
2.5
2.5
3.0
3.0
3.0
4.5
4.5
4.5
4.0
BOX TEMP
(DE6.F)


354.
376.
388.
387.
367.
368,
387,
400.
406.
404.
408.
409,
TEMP
(DE6.F)


49.
52,
55.
56.
57.
59.
61.
60.
66.
69.
67.
65.
     TOTALS

     AVERAGE
120.0
61.197
                                         .72
                               .72   545.
SS.
79.
3.1   388.
60,

-------
           PARTICULATE FIELD DATA S RESULTS TABULATION

PLANT* NAME AND ADDRESS               TCST TEAM LEADER

REPUBLIC STEEL CLEVELAND              BRUFFEY
TEST
8-3
NO.l COKE BATTERY OUTLET

TEST DATE
TB
TF
TT
NP
V
ON
CP
PM
¥ VM
to
" TM
VMSTD


TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRV GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
ENGLISH UNITS
10/30/81
1436
1638
120.0
12
1.003
.397 IN
.84
.72 IN-H20
61.197 CU-FT
81.6 F
59.962 SCF
METRIC UNITS
10/30/61
1438
1638
120.0
12
1.003
10.1 MM
.64
18.3 ,MM-H20
1.733 CU-M
27.6 C
1.696 SCM
          AT STANDARD CONDITIONS*

VLC      "TOTAL H20 COLLECTED IN
          IMPINGERS AND SILICA 6EL»ML.

VNC       VOLUME OF HATER VAPOR
          AT STANDARD CONDITIONS*

6*6       PERCENT MOISTURE 6V VOLUME

FMD       MOLE FRACTION DRY GAS

PC02      PERCENT C02 BY VOL.* DRV

P02       PERCENT 02 BY VOL.* DRV

PCO       PERCENT CO BV VOL., DRV

PN2       PERCENT N2 BV VOL., DRV

MO        MOLECULAR MT-DRV STACK GAS

MNS       MOLECULAR MT-STACK GAS
                                  (89.4
                                    6.915 SCF
                                               169.4
                                                  .252 SCM
12.94
.871
4.30
9,30
.00
66.40
29.06
27.63
12.94
.871
4.30
9.30
.00
86.40
29.06
27,63

-------
PB

PSI

PS

TS

VS

AS

QSSTD

OS

ISO

MN


CS

PMR
               BAROMETRIC PRESSURE

               STATIC PRES Of STACK CAS

               STACK PRESt ABS.

               AVERAGE STACK TEMP

               AVC STACK GAS VELOCITY

               STACK AREA

               STACK FLOW RATE* DRY*

               ACTUAL STACK F LOW RATE

               PERCENT ISOKINETIC

               FILTERABLE PART
                 MG. EPA 5

               FILTERABLE PART
               FILTERABLE PART
                 EMISSION RATE
 29.93  IN-H6

 •1.20  IN-MZO

 29.60  IN-HG

8*5.    F

        FPS

       30-IN

        SCFH

        ACFH
     19.1

   7466.

1626862.

3566*12.

    111.2

       .0
   .0000 6R/08CF*

   .000
   760.22  MM-HG

   -30.08  MM*H20

   757.98  MM-HC

   285.    C

     5.8   VPS

     •.617 80-M

 46068.    SCMH

100996.    ACMH

   111.2

      .0


      .000 MG/OSCK

       .00  KG/HR
   *  68 DEC f,
                            1N.H6.
NJ

-------
            EXAMPLE PARTICULATE CALCULATIONS TEST NO.   6-3

                 NO.l COKE BATTERY OUTLET



      VOLUME OP DRY CAS SAMPLED AT STANDARD CONDITIONS

      VM3TD • (17.647 * VM « V * (PB • PM / 13.6)) / (TM * 460.)

                17.647 *    61.197 * 1.003 * ( 29.93 *  .719 / 13.6)
      VMSTD • —.-.——————.-•—— ......... .............. *     59.962 D3CF
                               (  62. » 460.)



      VOLUME OF MATER VAPOR AT STANDARD CONDITIONS

      VNC • .04707 • VLC

      VHC » .WTOT •  189. •   8.92 SCF



      PERCENT MOISTURE IN STACK GAS

      BHO » (100. * VNC) 1 (VMSTD * VMC)

                100. •   a. 92
                                 ..... • 12. 94 PERCENT
jp                 59.962 *   8.92

fo
00

°     MOLE FRACTION OF DRY STACK GAS

      FMO » (100. > BNO) / 100.

                100. -  12.9
      FMO « — — ................. •   .871
                     100.
      AVERAGE MOLECULAR MEI6HT OF DRY STACK BIB

      MD * (PC02 • .44) « (P02 • .32) * (PN2 * PCO) • .28

      MO * ( 4.30*44/100) » ( 9.3*32/100) * ((86.4+ .0) * 28/100 *   29.06



      MOLECULAR NEI6MT OF STACK GAS

      MMS * MD • (1. • (8X0/100)) + 18. • (BNO/100)

      MWS «  29.06* (1. -(12.94/100)) • 18. * (12.94/100) *   27.63

-------
    STACK 6A3 VELOCITY AT STACK CONDITIONS

    DELP » SUM. OF THE SQRT(VH *  (TS » 460.))

    VS * 65.49 • CP • OELP /  (SORT(M*S • PS) • PNTS)

    VS ' BS. 49 *  .84 *   91.684  /  (30RT( 27.63 * 29.84)  •   12. «    19.11 FP3



    STACK GAS VOLUMETRIC PLOD AT  STACK CONDITIONS

    QS a VS * AS • 3600/144

    OS «   1*. ii •  7466. 3600/144  •    356*612. ACFH



    STACK CAS VOLUMETRIC FLO* AT  STANDARD CONDITIONS

    OSSTD i 17.647 * 69 * PS • (1.  - (BNO/100)) / (T8 * 460.)

              17.647 *    3566612.  •  29.84 • (1. •  (12.94/100))
    OSSTD « —————.———— ........... .......... --- ... «     1626862. SCFH
                       ( 545. » 460.)



>   PERCENT ISOKINETIC

    ISO « (305.58*(TS«460.))*((0.002669*VLC)*(VM*Y*(P8«(PM/13.6))/(TM«460.)))/(TT*V8*PS*DN«DN)
           (3D5.58«( 5«5.M60.))*((0. 002669*  189. )*l   61. 197*1. 003«( 29.93*(    . 719/13. 6))/(  82.*460.)))
    ISO •--.---..-------.--------.-.------.——————————————•————————— *  111. 16  PERCENT
                                       120. *     19.11 *   29.84 •  ,397 •  .397



    PARTlCULlTE LOADING — EPA METHOD 5 1*T"1T*NDAHO CONDITIONS)

    C3 » 0.001 • MN * 15.43 / VMSTD

    CS * 0.001 •      .0 * 15.43 /    59.962 «     .000 6R/DSCF
    PARTICULATE LBS/HR « EPA METHOD 5

    PMR « CS • OSSTD / (15.43 • 453.6)

    PMR •     .000 *    1626862. / (15.43 • 453.6) •      .00

-------
Run No.  8.3
     Sample volume = 1.70 m .  59.96 scf
Example calculations
     CS (Part) = 66.17 1.70= 38.9   mq/m3
     CS (Part) = 0.001 x 66.1  x 15.43/59.96  =  0.017 qr/dscf
                                     .3
     CS (S02)   =	/	=	mg/nT
               -	 x 24.06/	=	ppm
               = 0.001 x	x 15.43/	
gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Sulfur dioxide
Sulfuric acid mist
As H2$04
As H2$04-2H20
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
66.1






3 Concentration,
mg/m
38.9






gr/dscf
0.017






ppm







                                    A-282

-------
                                                        FIELD  DATA
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION NO.l COKE BATTERY OUTLET
SAMPLE TYPE PART
OPERATOR BRUFFKY
AMBIENT TEMP. (DEC. r) 76.
BAR. PRESS. (IN. H6) 29.93
STATIC PRE3S.UN.HZO) -1.20
FILTER NUMBER(S) 3530117
STACK INSIDE DIM. (IN) 97. SO .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .890 CFM 8 3.0 IN.H6
METER CALIB. FACTOR 1.044
READ « RECORD DATA EVERY 10.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY ORIFICE PRESSURE
POINT ~ TIME
NO. (MIN.)

fji|T 	 0
a* 10-°
7 20.0
M 30.0
a* 40.0
w 50.0
60.0
70.0
SO.O
90.0
100.0
110.0
120.0
TIME"
(24-HR
n nnr i
vLUln J
1M1
1451
1501
1510
1520
1531
1541
1551
1601
1611
1621
1631
1641
READING
(CU.FT.)

260.098
265.580
269. 9ZO
274.780
279.070
283.450
287.830
292.580
297.760
302.530
307.200
312.460
317.529
HEAD
(IN.H20)

- ..
.050
.050
.060
.050
.050
.050
.060
.070
.060
.060
.070
	 .070
DIFFERENTIAL
(IN.
DESIRED

.62
.62
.73
.62
.62
.62
.73
.87
.73
.73
.87
.87
H20)
ACTUAL

.62
.62
.73
.62
.62
.62
.73
.87
.73
.73
.87
.87
STACK
TEPP
(DEG.F)


540.
558.
564.
525.
530.
540.
547.
564.
580.
529.
544.
547.
DATE 10/30/81
RUN NUMBER 8-4
PROBE LENGTH S TYPE 4' HEATED GLASS
NOZZLE 1 I.D. .397
ASSUMED MOISTURE 12.0
SAMPLE BOX NUMBER 0
METER BOX NUMBER FIO
METER HEAD OIFF. i.so
C FACTOR .86
PROBE HEATER SETTING 350.
HEATER BOX SETTING 350.
REFERENCE PRESS. OIFF. .15
DRY GAS METER PUMP SAMPLE IMPIN6ER
TEMP
(DEG
INLET

90.
91.
94.
96.
97.
97.
97.
78.
97.
97.
97.
96.
.F)
OUTLET

90.
91.
92.
92.
93.
93.
93.
94.
93.
93.
93.
92.
VACUUM
(IN.HG)


1.0
1.5
2.0
2.0
2.0
3.0
4.0
4.5
4.0
4.5
5.0
5.0
BOX TEMP
(DEG.F)


392.
398.
406.
348.
359.
377.
403.
413.
404.
406.
405.
407.
TEMP
(DEG.F)


92.
S3.
55.
57.
56.
99.
60.
64.
66.
68.
66.
64.
TOTALS
AVERAGE
120.0
56.631
                                         .72
                               .72   S47.
94.
92.
3.2   393.
60.

-------
               PARTICULATE FIELD DATA ft RESULTS TABULATION
    PLANT- NAME AND ADDRESS               TEST TEAM LEADER
    REPUBLIC STEEL CLEVELAND              BRUFFEY
    TEST
        0-4
NO.l COKE BATTERT OUTLET
KJ
00

TEST
TB
TF
TT
NP
T
ON
CP

DATE
TIME-START
TIME-FINISH
NET TIME OF TEST* MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
ENGLISH UNITS
10/30/81 '
1441
1641
120.0
12
1.044
.397 IN
.84
METRIC UNITS
10/30/81
1441
1641
120.0
12
1.044
10.1 MM
.84
PM        AVERAGE ORIFICE PRESSURE
          DROP
VM        VOLUME OF DRV GAS SAMPLED
          AT METER CONDITIONS
TM        AVERAGE GAS METER TEMP
VMSTD     VOLUME OF DRY GAS SAMPLED
          AT STANDARD CONDITIONS*
VLC       TOTAL M20 COLLECTED IN
          IMPINGERS AND SILICA CEL.ML.
VNC       VOLUME OF WATER VAPOR
          AT STANDARD CONDITIONS*
BNO       PERCENT MOISTURE BY VOLUME
FMO       MOLE FRACTION DRY GAS
PC02      PERCENT C02 BY VOL.* DRV
P02       PERCENT 02 BY VOL.* DRV
PCO       PERCENT CO BY VOL.* DRV
PN2       PERCENT N2 BY VOL.* DRY
MO        MOLECULAR WT-ORV STACK GAS
MMS       MOLECULAR HT-STACK GAS
                                                 .72  IN-H20
                           56.631 CU-FT
                                                18.3   IMM-H20
1.604 CU-M
93.2 F
56.551 SCF
^1.3
9.004 SCF
13.74
.863
4.30
9.30
.00
86.40
29.06
27.54
34.
1.
191.
•
13.
•
4.
9.
•
86.
29.
27.
0 C
601 SCM
3
255 SCM
74
863
30
30
00
40
06
54

-------
fO
CO
en
      PB        BAROMETRIC PRESSURE

      PSI       STATIC PRES OF STACK GAS

      PS        STACK PRES, ABS.

      TS        AVERAGE STACK TEMP

      VS        AVG STACK GAS VELOCITY

      AS        STACK AREA

      OSSTO     STACK FLOW RATE* DRY*

      OS        ACTUAL STACK FLOW RATE

      ISO       PERCENT ISOKINETIC

      UN        FILTERABLE PART
                  MS. EPA 5

      CS        FILTERABLE PART

      PMR       FILTERABLE PART
                  EMISSION RATE

         •  48 DEC F,  29.92 IN.M8.
     29.93  IN-H6

     •1.20  IN-H20

     29.B4  IN-M6

    547.    F

     19.2   FPS

   7466.   SO-IN

1*12867.    SCFH

3S76390.    ACFH

    109.8

       .0


       .0000 GR/DSCF*

       .000   LB/MR
   760.22  MM-HG

   •30.48  HM-H20

   757.98  MM-HG

   266.    C

     5.8   MPS

     4.817 30-M

 45672.    3CHH

101273.    ACMH

   105.8

      .0


      .000 M6/DSCK

       .00  KG/HR

-------
            EXAMPLE PARTICIPATE CALCULATIONS TEST NO.   8-0
                 NO.l COKE BATTERY OUTLET

      VOLUME OP DRY GAS SAMPLED AT STANDARD CONDITIONS
      VMSTO • (17.647 * VM • Y • (P8 * PM / 13.6)) / (TM » 460.)
                17.647 •    56.631 * U044 * ( 29.93 *  .719 / 13.6)
      VMSTO « .—————.-——.—.—.—.—-.——	... •      86.551  OSCP
                               (  93. * 460.)

      VOLUME OP WATER VAPOR AT STANDARD CONDITIONS
      VNC « .04707 • VLC
      VMC • .04707 •  191. •   9.00 SCF

      PERCENT MOISTURE IN STACK GAS
      BMO « (iOO, * VHC) / CVMSTD » VWC)
^               100. •   9.00
7     BMO « —.......—..————.. • 13.74 PERCENT
M                 56.551 *   9.00
GO

-------
       STACK  GAS  VELOCITY  AT  STACK  CONDITIONS

       OELP « SUM.  OF  THE  8QRT(VH • (TS  *  460.))

       VS  « 85.49 • CP • OELP /  (SQRT(MKS  •  PS)  *  PNTS)

       VS  * 85.49 *  .84 •    91.790 /  (SORT( 27.54 *  29.84)   •   12.  •    19.16  FPS




       STACK  6AS  VOLUMETRIC FLO* AT STACK  CONDITIONS

       03  « VS •  A$ •  3690/144

       08  a    19.16 •   7466.  3600/144  »    3576390. ACFH




       STACK  CAS  VOLUMETRIC FLON AT STANDARD CONDITIONS

       OSSTO  * 17.647  • OS *  P8 • (1.  -  (BMO/100))  /  (T8  «• 460.)

                 17.647 •     3576390.  *  29.84 • (1.  - (13.74/100))
       OSSTO  • i.i—........................................	.. *     1612867. 3CFH
                          ( 547. »  460.)




•p      PERCENT ISOKINETIC

NJ      ISO *  (30S,5eMTS»460.))«((0.002669«VLC) + (VM*Y«(PB»(PM/13.6))/(TM*«60.)))/(TT«VSOPS<»DN«ON)
oo                             •  •

^             (305.58«( 547.*460.))*((0.002t»f*  191.)*(   56.631*1.040*( 29.93«(    .719/13.6))/(   93.*«60.)))
       ISO «  ....—[[[ «  105.75 PERCENT
                                          120. *      19.16 •   29.84 •   .347 *  .397




       PARTICULATE LOADING — EPA METHOD 5 (AT STANDARD CONDITIONS)

       C8 « 0.001 • MN  • 15.43 / VMSTD

       CS • 0.001 •      .0 * 15.43 /    56.551 •     .000 6R/OSCF




       PARTICULATE LBS/HR — EPA METHOD 5


-------
Run No.  8.4
     Sample volume =  1.60 m3t  56.55 scf
Example  calculations
     CS  (Part)  = 60.5/ 1.60=  37.8 mo/m3
     CS  (Part)  = 0.001 x60.5  x 15.43/56.55 =   0.016qr/dscf
     CS  (S02)   =	/	=	mg/m3
               =	 x  24.06/	=	ppm
               = 0.001 x	x 15.43/	=	gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Sulfur dioxide
Sulfuric acid mist
As H2S04
As H2S04-2H20
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
60.5






3 Concentration,
mg/m
37.8






gr/dscf
0.016

i




ppm







                                    A-288

-------
                                                        FIELD  DATA
        PLANT
        SAMPLING LOCATION

        SAMPLE TYPE
        OPERATOR
        AMBIENT TEMP.(DEC.F)
        BAR.PRESS.(IN.H6)
        STATIC PRESS.(IN.H20)
        FILTER NUMBER(S)
        STACK INSIDE DIM.(IN)
        PITOT TUBE COEFF.
        THERM. NO.
        LEAKAGE
        METER CALIB. FACTOR
                     REPUBLIC STEEL CLEVELAND
                     COKE STACK

                     METHOD 3-250
                     00/MP
                      67.
  -1.20
  3530008
    97.50
    .84
                                .00
                      .020 CFM 8 19.5 IN.HG
                     1.033
 DATE                     10/30/81
 RUN NUMBER                  8-5

 PROBE LENGTH t TYPE      6* GLASS
 NOZZLE      I 1.0.        .374
 ASSUMED MOISTURE         11.0
 SAMPLE BOX NUMBER
 'METER BOX NUMBER         PB4
 METER HEAD OIFF.         1.88
 C FACTOR                  .92
 PROBE HEATER SETTING     290.
 HEATER BOX SETTING       290.
 REFERENCE PRESS. OIFF.    .18
        READ t RECORD DATA EVERT 10.0 MINUTES
1
>
NJ
00
vo - •-
TRAVERSE SAMPLE
POINT TIME
NO. (MIN.)
INIf 0
10.0
20.0
30.0
«0.0
90.0
60.0
70.0
80.0
90.0
100.0
104.2
CLOCK
TIME
(24-HR
CLOCK)
1439
1449
1459
1509
1519
1529
1539
1549
1999
1609
1619
1623
GAS METER
READING
(CU.FT.)
VELOCITY ORIFICE PRESSURE
HEAD DIFFERENTIAL
(IN.H20) (IN.H20)
DESIRED
23.414
28.190
32.880
37.600
42.320
47.040
91.740
56.440
61.150
65.860
70.590
72*492
.070
.070
.070
.070
.070
.070
.070
.070
.070
.070
.070
.72
.72
.72
.72
.72
.72
.72
.72
.72
.72
.72
ACTUAL
.72
.72
.72
.72
.72
.72
.72
.72
.72
.72
.72
STACK
TEMP
(DEG.F)
DRV GAS METER PUMP SAMPLE
TEMP VACUUM BOX TEMP
(DEG.F) (IN.HG) (DEG.F)
IMPIN6ER
TEMP
(OE6.F)
INLET OUTLET
920.
920.
520.
520.
920.
920.
920.
920.
920.
920.
520.
70.
72.
73.
75.
76.
76.
77.
77.
78.
78.
78.
70.
70.
70.
71.
71.
71.
71.
72.
73.
73.
73.
10.9
10.5
10.4
10.4
10.4
10.4
10.7
10.9
11.7
13.1
15.5
259.
2TO.
273.
270.
267.
268.
268.
266.
268.
270.
264.
•9.
«7.
•7.
48.
92.
92.
57.
93.
52.
52.
93.
TOTALS
AVERAGE
104.2
49.078
                                         .72
                               .72   920.
79.
71.
11.4   268.
91.

-------
              PARTICIPATE FIELD DATA * RESULTS TABULATION
   PLANT- NAME AND ADDRESS               TEST TEAM LEADER
   REPUBLIC STEEL CLEVELAND              DO/MP
   TEST
        8-5
COKE STACK
   TEST DATE
                                         ENGLISH UNITS
                                            10/30/81
I
to
TB        TIME-START
TF        TIME-FINISH
TT        NET TIME OF TEST, MIN,
NP        NET SAMPLING POINTS
Y         METER CALIBRATION FACTOR
ON        SAMPLING NOZZLE DIAMETER
CP        PITOT TUBE COEFFICIENT
PM        AVERAGE ORIFICE PRESSURE
          DROP
VM        VOLUME OF DRY GAS SAMPLED
          AT METER CONDITIONS
TM        AVERAGE GAS METER TEMP
VMSTD     VOLUME OF DRY CAS SAMPLED
          AT STANDARD CONDITIONS*
VLC       TOTAL 1420 COLLECTED IN
          IMPIN6ERS AND SILICA GEL,ML.
VNC       VOLUME OF HATER VAPOR
          AT STANDARD CONDITIONS*
BNO       PERCENT MOISTURE BY VOLUME
FMO       MOLE FRACTION DRY GAS
PC02      PERCENT C02 BY VOL., DRY
P02       PERCENT 02 BY VOL., DRY
PCO       PERCENT CO BY VOL., DRY
PN2       PERCENT N2 BY VOL., DRY
MO        MOLECULAR MT-ORV STACK GAS
MMS       MOLECULAR NT-STACK GAS
                         1623
                          104.2
                           11
                            1.033
                             .374 IN
                             .84
                             .72  IN-H20

                           49.078 CU-FT
METRIC UNITS
   10/30/81
1439
1623
 104.2
  11
   1.033
   9.5   MM
    .84
  18.3   NM-M20

   1.390 CU-M
73
SO
175
B
14

4
' 9

86
29
27
*
•
•
•
•
•
9
•
•
•
•
•
4 F
289 SCF
0
237 SCF
07
859
30
30
00
40
06
50
23.
1.
175.
•
14.
•
4.
9.
•
86.
29.
27.
0
424
0
233
07
859
30
30
00
40
06
50
C
SCM

SCM









-------
PB
PSI
PS
TS
VS
«s
OSSTD
03
ISO
MN
cs
PMR
•"
to
VD
BAROMETRIC PRESSURE
STATIC PRES OF STACK CAS
STACK PRES, AB8.
AVERA6E STACK TEMP
AV6 STACK GAS VELOCITY
STACK AREA
STACK FLON RATE, DRY*
ACTUAL STACK FLON RATE
PERCENT ISOKINETIC
FILTERABLE PART
M6. EPA S
FILTERABLE PART
FILTERABLE PART
EMISSION RATE
68 DIG F, 29.92 tN.Ht.

29.93 IN-H6
•1.20 IN-H20
29.84 IN-H6
S20. F
20.8 FPS
7466. SO-IN
1789295. SCFH
38751*8. ACFH
110.0
.0
.0000 GR/DSCF*
.000 L6/HR


   760. ZZ  'MM-H6




   •30.48  MM-H20



   757.98  'HM-HG



   271.    C




     6.3   NPS



     4.817 SQ-M



 50667.    3CHH




109733.    ACMH



   110.0



      .0






      .000 M6/D3CK



       .00  KG/MR

-------
           EXAMPLE  PARTICIPATE  CALCULATIONS  TEST  NO.    6-5

                     STACK
    VOLUME OF DDT CAS  SAMPLED  AT  STANDARD  CONDITIONS

    VMSffi" •  (17.447 i  VM  i  Y * (PS  »  PM  /  11.6))  /  (TM  *  460.)

              17.647 *   49.078  •  J.033 • (  29.43  *   .720  /  13.6)
    VMSTD »  — .— — i~ ......................................... •     90.289 D3CF
                             ( 73. * 460.)
    VOLUME OF HATER VAPOR  AT  STANDARD  CONDITIONS

    VHC • .04707 • VLC

    VHC •".04707 •  175. • ' T.'MTtF ~



    PERCENT MOISTURE  IN STACK CAS

  ~ BNO••r-(ioo. • VNCJ / (VMSTO  *  VNO

              100. *   6.24
S,   BHO • ——.———.—.—..... * 14.07  PERCENT
I               50.289 *   8.24
to
vo             	

    MOLE FRACTION OF  DRY STACK CAS

    FMO • (100. • BNO) / 100.

        	100. -  14.1                - —
    FMO « ——.......——......  •    .859
                   100.



    AVERCil MO\ECULAIT WEI6NT  OF  DRY STACK CIS

    MO * (PC02 • .44) * (P02  • .32) *  (PN2 *  PCO)  « .26

    MO * (4.30*44/100) *  ( 9.3*32/100) *  ((86.0*  .0)  *  26/100  •    29.06



    MOLECULAR WEIGHT  OF STACK 6AS

    MHS * MO * (1. -  (BNO/100))  +  16.  * (BNO/100)

    MHS »  29.04* (1. -(14.07/100)1 »  18. •  (14.07/100)  *    27.50

-------
    STACK GAS VELOCITY AT STACK CONDITIONS

    OELP • SUM. OF THE SORTtVM * (TS * 460.))

    VS « 85.49 • CP • OELP / (SORT(MMS * PS) * PNTS)

    VS • 85.49 *  .84 *   91.108 / (SQRT( 27.50 • 29.84)  •  11. a   20.76 FPS




    STACK GAS VOLUMETRIC FLON AT STACK CONDITIONS

    OS • VS • AS • 3600/144

    OS *~  20.76 •  7466. 3600/144 *    3875168. ACFH




    STACK GAS VOLUMETRIC FLON AT STANDARD CONDITIONS

    OSSTO i 17.6*7 • 68 • « * (17 i (BHO/IW) / (TS * 460.)

              17.647 «    3875168. *  29,84 • (1. • (14.07/100))
    OSSTO » ——.—————.—.——.-..———————«    1789295. SCFH
                       ( 520. » 460.)




    PERCENT ISOKINCTIC

 <•>  ISO » (305.58*(TS*460.))M(0.002669«VLC)«(VM«Yo(PB*(PM/l3.6))/(TM*46«.)))/(TT«VS«»PS»ON«DN)

*D 	
           (SOS.58*( 520.**60.))•((«.00266t*  175.)*(   49.078«1.033*( 29.93»(    .720/13.6))/C  73.4460.)))
    ISO • ———————.————————[[[ • 110.00 PERCENT
                                       104. *     20.76 *   29.84 «  .374 •  .374



    PARTICIPATE LOADTN6 -- EPA METHOD 5 (AT »T*NOARD CONDITIONS)

    CS = 0.001 • MN • 15.43 / VMSTD

    CS * 0.001 •      .0 * 15.43 /    50.289 «     .000 GR/DSCF



    PARTICIPATE LBS/HR — EPA METHOD 5

    PMR » CS • OSSTO / (15*43 * 453.6)


-------
Run No.  8.5
     Sample volume = 1.42 m3.50.29  scf
Example calculations
     CS (Part)  =183.6/1.42 =129.3 mq/m3
     CS (Part)  = 0.001  x183.6 x  15.43/50.29 =
                                      3
     CS (S02)   =	/	=	mg/m
               =	 x 24.06/	=	ppm
               = 0.001  x	x  15.43/.
               gr/dscf
               gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 275°F
4-h at 275°F
2-h at 300°F
4-h at 300°F
2-h at 325°F
4-h at 325°F
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Sulfur dioxide
Sulfuric acid mist
As H2$04
As H2S04-2H20
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


183.9
75.5
66.7
64.5
62.4
61.0
59.9
57.9
57.4
52.9
50.9
45.6







2 Concentration,
mg/m


129.5
53.2
47.0
45.4
43.9
43.0
42.2
40.8
40.4
37.2
35.8
32.1







gr/dscf


0.056
0.023
0.021
0.020
0.019
0.019
0.018
0.018
0.017
0.016
0.016
0.014







ppm





















A-294

-------
                                                              FIELD  DATA
              PLANT
              SAMPLING LOCATION

              SAMPLE TYPE
              OPERATOR
              AMBIENT TEMP.(016.F)
              BAR.PRESS.(IN.H6)
              STATIC PRESS.(IN.H20)
              FILTER NUMBER(S)
              STACK INSIDE DIM.(IN)
              PITOT TUBE COEFF.
              THERM. NO.
              LEAKAGE
              METER CALIB. FACTOR
                    REPUBLIC STEEL CLEVELAND
                    COKE STACK

                    METHOD 8-600
                    DO/MP
                     47.
                    29.93
                    -1.20
                    3530214
                      97.90    .00
                      .84

                     ..000 CFN 8 22.0 IN.H6
                     .982
                                               DATE                      10/30/81
                                               RUN NUMBER                  8-6

                                               PROBE LENGTH • TYPE       4* QUARTZ
                                               NOZZLE      I 1.0.         .620
                                               ASSUMED MOISTURE          11.0
                                               SAMPLE BOI NUMBER
                                               METER BOX NUMBER          FB8
                                               METER HEAD DIFF.          1.91
                                               C FACTOR                   .94
                                               PROBE 'HEATER SETTING      290.
                                               HEATER BOX SETTING        290.
                                               REFERENCE PRESS. DIFF.     .02
              READ • RECORD DATA EVERY I0.i0 MINUTES
 I
to
10
TRAVERSE
POINT
NO.

INIT









SAMPLE CLOCK
TIME TIME
(MIN.) (24-HR
^1 t\t*tt
(•LUC*
0 	 1*J«
10.0 1448
20.0 1498
30.
40.
50.
60.
to.
80.
1508
1518
1528
1938
1948
1998
90.0 1608
CAS METER
READING
(CU.FT.)
i
i
478.098
482.690
487.420
492.180
496.930
901.640
906.460
911.190
919.910
920.698
VELOCITY ORIFICE
PRESSURE
HEAD DIFFERENTIAL
(IN.H20) (IN.
DESIRED
. .._. ._
.070
.070
.070
.070
.070
.070
.070
.070
.070
.44
.44
.44
.44
.44
.44
.44
.44
.44
H20)
ACTUAL

.79
.79
.79
.79
.79
.79
.79
.75
.75
STACK
TEMP
(OE6.F)


520.
520.
520.
520.
520.
520.
520.
520.
520.
DRV CAB METER
TEMP
(DEG.P)
INLET OUTLET

67. 67.
69. 67.
72. 67.
73. 68.
75. 69.
75. 69.
75. 69.
74. 69.
75. 70.
PUMP
VACUUM
(IN.HG)


4.8
8.3
11.3
13.6
15.2
16.9
16.7
17.7
21.7
SAMPLE
BOX TEMP
(DEG.F)


984.
993.
601.
592.
601.
603.
599.
999.
600.
IMPINGER
TEMP
(DEG.F)


90.
46.
44.
48.
48.
90.
94.
94.
56.
      TOTALS
      AVERAGE
90.0
42.600
                                       5.44
                               .75   520,
73.
68,
14.0   596.
;50.

-------
              PARTICULATE FIELD DATA t RESULTS TABULATION

   PLANT* NAME AND ADDRESS               TEST TEAM LEADER

   REPUBLIC STEEL CLEVELAND              00/MP
   TEST
8-6
                COKE STACK

TEST
TB
TF
TT
NP
Y
DN
CP
PM

DATE
f IME-ST ARf
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
ENGLISH UNITS
10/30/81
i«3e
1608
90.0
9
.982
.620 IN
.84
.75 IN-H20
METRIC UNITS
10/30/81
1438
1608
90.0
9
.982
15.7 MM
.84
19.1 MM-l
cn
          DROP

VM        VOLUME OF DRY CAS SAMPLED
        	AT METER CONDITIONS

TM        AVERAGE GAS METER TEMP

VMSTD     VOLUME OF DRY CAS SAMPLED
          AT STANDARD CONDITIONS*

VLC       TOTAL M» "COLLECTED IN
          IMPINCERS AND SILICA CELrNL.

VMC       VOLUME OF HATER VAPOR
          AT STANDARD CONDITIONS*

Blfb       PERCENT MOISTURE 8V VOLUME

FMD       MOLE FRACTION DRY CAS

PC02      PERCENT C02 BY VOL., DRY

P62       PCRCENT dZ BY VOL., 0«r

PCO       PERCENT CO BY VOL., DRY

PN2       PERCENT N2 BY VOL., DRY

MO        MOLECULAR IT-DRY STACK CAS

MMS       MOLECULAR NT-STACK CAS
                                              42.600 CU-FT
                                                         1.206 CU-M
T0.6 F
41.722 SCF
isa.o
7.437 SCF
"15.11
.849
4.30
9.30
.00
86.40
29.06
27.39
21
1
158

15

4
9

86
29
27
.4 C
.181 8C*
.0
.211 SCX
.13
.849
.30
.30
.00
.40
.06
.39

-------
   PB        BAROMETRIC PRESSURE

   PS!       STATIC PRES Of STACK CAS

   PS        STACK PRES* ABS.

   TS        AVERAGE STACK TEMP

   VS        AVC STACK *A3 VELOCITY

   AS        STACK AREA

   OSSTD     STACK PLOW RATE. DRT*

   OS        ACTUAL ITAC* FLOW RATE

   ISO       PERCENT ISOKINETIC

   MN        FILTERABLE PART
           	  MS. EPA 5     	

   CS        FILTERABLE PART

   PMR       FILTERABLE PART
               EMISSION RATE

      •  6ft C16 F,  2«.?MN.HG.
29.
-i<
29.
520.
20.
7466.
1771103.
3883105.
38.
•
.
.
93
20
84

*
IN-HG
IN-H20
IN-HG
F
FP8
SO-IN


B
0
0000
000
SCFH
ACFM


CR/D8CF*
LB/HR
760
-30
757
271
6
4
50152
109966
38



.22
.48
.98
•
.3
.817
•
•
.•
.0
.000
.00
MM-HG
•MM-H20
MM-HG
C
MP8
80-M
SCMH
ACMM


MG/D8CM
KG/MR
NJ

-------
          EXAMPLE PARTICIPATE CALCULATIONS  TEST  NO.    6-6

               COKE STACK



    VOLUME OF DRY 6AS SAMPLED AT  STANDARD CONDITIONS

    VMSTO «  (17.647 * VM •  T •  (P8  *  PM  / IS.*))  /  (TM * 460.)

              17.647 •    42.600  •   *982 •  (  29.93  *   .750 /  IS.6)
    VMSTD •  •——.—........................................... a     41.722 DSCF
                             (  71. » 460.)



    VOLUME OP NATER VAPOR AT STANDARD CONDITIONS

    VMC » .04707 • VLC

    VNC * V01T07 •  158. »  ~7ilt ICF



    PERCENT  MOISTURE IN STACK 6A8

    BMOi~TiW. • VNC) / (VMSTO * VHC)

              100. ft   7.44
>   BNO « ———.—.——.——.—  • 15.IS  PERCENT
^               41.722*    7.44
vo   _
CO   "  ""	--.—.._..
    MOLE FRACTION OF DRV STACK 6AS

    FMD •  C100. - BNO) / 100.
    FMO « ..........—.———  •    .84*
                   100.
                      NE10HT OF ORV  STACK SXB

    MO •  (PC02 • .44) •  (P02 • .12)  *  (PN2 * PCO)  •  .28

    MD «  ( 4.30*44/100)  *  ( 9.S*S2/100) » ((8*. 4*  .0)  *  28/100  •   29.06



    MOLECULAR NEI6MT OF  STACK GAS

    MNS * MO • (1. - (BNO/100)) *  18.  • (BNO/ 100)

    MMS «  29.06* (1. -(19.13/100))  •  IS. •  CIS. IS/100)  •    27.39

-------
STACK GAS VELOCITY AT STACK CONDITIONS

DELP • SUM. OF THE SQRTtVH * (TS * 460,))

V8 * 85.49 • CP • OELP / (SORT(MM8 • PS) • PNTS)

VS » 85.49 •  .84 •   74.543 / (SORT( 27.39 • 29.84)  •   9. «   20.81 FPS




STACK 6AS VOLUMETRIC FLOW AT STACK CONDITIONS

OS * VS * AS • 3600/144

OS >   20.81 •  7466. 3*00/144 .•    3UI405. ACrM




STACK CAS VOLUMETRIC PLON AT STANDARD CONDITIONS

QSSTO • 17.647 * OS • «HT(IV- (BW07W)J / (TS « 460.)

          17.647 *    38*3409. •  29.64 • (1. • (15.13/100))
OSSTD « ———————.———..................... •    1771103. 3CFH
                   ( 520. * 460.)




PERCENT ISOKINETIC

ISO » (305.58*(TS*460.))*((0.002669*VLC) + (VM*Y*(MMPM/13.6))/(TMM6

       (305.5«*( 520.4460.))•((0.002669*  156.J*(   42.600* .982*( 29.93*(    .79f/13.6))/(  71.4460.)))
ISO « —«—...—.........—.-[[[ n  36.04 PERCENT
                                    90. •     20.81 *   29.84 •  .620 *  .620




PARTICULAR LOADING -- IM METHOD S TAT1TAKOARO CONDITIONS)                    	

CS » 0.001 * MN * 15.43 / VMSTO

C3 * 0.001 *      .0 * 15.43 /    41.722 «     .000 GR/DSCF




PARTICULATE LBS/HR — EPA METHOD 5


-------
Run No.  8.6
     Sample volume =_LJJLm ,_lLZ!scf
Example  calculations
     CS  (Part) =45.1/1 ia e -?a 7 ma/m
     CS  (Part) = 0.001 x45.1  x 15.43/41.72= 0.017 qr/dscf
                                    3
     CS  (S02)  =	/	=	mg/m
              =	 x 24.06/	=	ppm
              = 0.001 x	x 15.43/	
gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Sulfur dioxide
Sulfuric acid mist
As H2S04
As H2S04-2H20
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
45.1






3 Concentration,
mg/m
38.2






gr/dscf
0.017






ppm







                                   A-300

-------
2.0  DCOG Underfiring Test Series
         December 1981
              A-301

-------
                                                             FIELD   0»T*
o
to
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION NO.l COKE BATTERY OUTLET
SAMPLE TYPE PART/H2S04/S02
OPERATOR BRUFFEY
AMBIENT TEMP.(OEG.F) 3b.
BAR. PRESS. (IN. HG) 29.21
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530310
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .00
THERM. NO.
LEAKAGE .000 CFM 3 6.0 IN.HG
METER CALIB. FACTOR 1.003
READ » RECORD DATA EVERY 10.0 MINUTES
TRAVERSE
POINT
NO.

INIT









SAMPLE
TIME
(MIN.)

0
10.0
20.0
30.0
40.0
50.0
60. 0
70.0
80. 0
90.0
CLOCK
TIME
(24-HR
fi ftp K %
LLUtK J
1205
1215
1225
1235
1245
1255
1305
1315
1325
1335
GAS METER
READING
ICU.FT.)

259.553
263.720
260.400
273.200
277.960
202.600
207.420
292.730
296.060
301.507
VELOCITY
HEAD
(IN.H20)


.050
.050
.050
.050
.050
.050
.050
.050
.050
ORIFICE
PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.67
.67
.67
.67
.67
.67
.67
.67
.67
H20)
ACTUAL

.67
.67
.67
.67
.67
.67
.67
.67
.67
STACK
TEMP
(DEG.F)


452.
463.
472.
467.
400.
492.
450.
459.
469.
DATE 12/00/81
RUN NUMBER 01-1
PROBE LENGTH * TYPE 4' HEATED GLASS
NOZZLE : I.D. .401
ASSUMED MOISTURE 14.0
SAMPLE BOX NUMBER 0
PETER BOX NUMBER FB2
METER HEAD OIFF. 1.00
C FACTOR .02
PROBE HEATER SETTING 250.
HEATER BUX SETTING 250.
REFENENCE PRESS. OIFF. .00
DRY GAS METER
TEMP
(DEG.F)
INLET OUTLET

32. 32.
32. 33.
33. 32.
35. 32.
35. 32.
35. 33.
36. 33.
36. 33.
36. 33.
PUMP
VACUUM
(IN.HG)


4.0
4.0
4.0
4.0
5.0
6.0
5.5
6.0
6.0
SAMPLE
BOX TEMP
(DEG.F)


239.
255.
245.
240.
251.
243.
244.
241.
246.
IMPINGER
TEMP
(DEG.F)


34.
36.
36.
37.
36.
37.
39.
40.
40.
     TOTALS
     AVERAGE
90.0
42.034
                                         .67
                               .67   460.
34.
33.
4.9   246.
37,

-------
           PARTICIPATE FIELD DATA t RESULTS TABULATION




PLANT- NAME AND ADDRESS               TEST TEAM LEADER




REPUBLIC STEEL CLEVELAND              BRUFFEY
TEST   Dl-l
NO.l COKE BATTERY OUTLET
ENGLISH UNITS
TEST DATE
TB
TF
TT
NP
Y
ON
CP
> PM
1
u>
o
U> VM
TM
VMSTD
VLC
VWC
BMO
FMD
PC02
P02
PCO
PN2
MO
MH3
TIME-START
TIME-FINISH
NET TIME OF TEST* MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRV GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H20 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF MATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL.* DRY
PERCENT 02 BY VOL.* DRY
PERCENT CO BY VOL., DRY
PERCENT N2 BY VOL., DRY
MOLECULAR MT-DRY STACK GAS
MOLECULAR MT-STACK GAS
12/08/81
1205
1335
90.
9
1.
.
.
42.
33.
44.
103.
4.
9.
.
4.
9.
.
86.
29.
26.
0

003
401 IN
64
67 IN-H20
034 CU-FT
5 F
111 SCF
2
656 SCF
92
901
50
40
00
10
10
00
METRIC UNITS
12/06/61
1205
1335
90.0
9
1.003
10.2
.64
17.0
1.190
.6
1.249
103.2
.136
9.92
.901
4.50
9.40
.00
66.10
29.10
26.00



PM

PM-H20
CU-M
C
SCf

SCM









-------
PB




PSI



PS



TS




V3




AS



OSSTD



OS




ISO




MN






cs



PMR
    BAROMETRIC PRESSURE



    STATIC PRES OF STACK GAS




    STACK PRES, ABS.



    AVERAGE STACK TEMP




    AV6 STACK GAS VELOCITY




    STACK AREA




    STACK FLO* RATE, DRY*




    ACTUAL STACK FLON RATE



    PERCENT ISOKINETIC






      MG. EPA 5










      EMISSION RATE



68 OEG f,  29.92 IN.H6.
     29.21  IN-HG




     -1.20  IN-H20




     29.12  IN-HG




    068.    F




     17.1   FPS




   74bb.   SO-IN




1595142.    SCFH




3197639.    ACFH




    109.0




       .0000






       .00000 GR/DSCF*




       .00000 LB/HR
  7ai.93  CM-MG




  -30.48  PM-H20




  739.b9  MM-HG




  242.    C




    5.2   CPS




    4.817 SO-M




45170.    SCKH




90548.    ACHM




  109.0




     .0000






     .0000 MG/OSCM




     .000 KG/MR

-------
              EXAMPLE PARTICIPATE CALCULATIONS  TEST  NU.   01-1

                   NO.l COKE BATTERY OUTLET



        VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

        VMSTO • (17.647 • VM * Y •  (P8 * PM  / 13.6))  /  (TM  * 460.)

                  17.647 *    42.034 • 1.003 *  (  29.21  »  .670  /  13.6)
        VMSTO « ——	  =      44.111  DSCF
                                 (  34. *  460.)



        VOLUME OF HATER VAPOR AT STANDARD  CONDITIONS

        VMC * .04707 * VLC

        VNC * .04707 *  103. s   4.66 SCF



        PERCENT MOISTURE IN STACK KAS

        BNO » (100. * VNC) / fVMSTD » VHC)

^                100. *   4.B6
f,      BNO 3 ——	—	—- i   9.92  PERCENT
W                  44.111 »   4.86
O
Ln

        MOLE FRACTION OF DRY STACK GAS

        FMD « (100. - BNO) / 100.

                  100. •   9.9
        FMO * ————	——	3    .901
                       100.



        AVERAGE MOLECULAR WEIGHT OF DRY STACK GAS

        MD a (PC02 * .44)  * (P02 * .32) *  (PN2 *  PCO) * .28

        MO * ( 4.50*44/100) » ( 9.4*32/100)  » ((86.1* .0) * 26/100 =   29.10



        MOLECULAR HEIGHT OF STACK GAS

        MNS a MO • (1. • (BNO/100))  * 16. *  (BNO/100)

        MNS *  29.10* (1.  -( 9.92/100)) *  18. * ( 9.92/100)  3   28.00

-------
        STACK 6*3 VELOCITY AT STACK CONDITIONS

        DELP * SUM. OF THE SORUVH * (TS •» 460.))

        VS • 65.49 • CP • OELP / (SORTlMKS * PS) * PNTS)

        VS * 85.49 *  .64 *   61.304 / (SORT( 86.00 * 29.12)   *   9.  =   17.13 FP3



        STACK 8AS VOLUMETRIC FLO* AT STACK CONDITIONS

        OS » VS * AS • 3600/144

        OS a   17.13 *  7466. 3600/144 •    3197639. ACFH



        STACK GAS VOLUMETRIC FLON AT STANDARD CONDITIONS

        OSSTO « 17.647 • OS » PS • (1. • (BNO/100)) / (TS + 460.)

                  17.647 »    3197639. *  29.12 *(!.-( 9.92/100))
        OSSTD « —	•	 =    1595142. SCFH
                           t 468. * 460.)



.        PERCENT I30KINETIC

U)       ISO B (305.56«(TS*460.))*((0.002669*VLC)«(VM*Y*(PB*(PM/13.6))/(TM*460.)))/(TT*VS*PS*DN*ON)
O
^              (305.58*( 468.+460.))*((0.002669*  103.)*(   42.034*1.003*( 29.21*(    .670/13.6))/(  34.4460.)))
        ISO * —	.............	.	...	.	....	.	a 109.00 PERCENT
                                            90. *      17.13 •   29.12 *  .401 *  .401



        PARTICULATE LOADING — EPA METHOD  5 (AT STANDARD  CONDITIONS)

        CS • 0.001 * MN * 15.43 / VMSTO

        CS « 0.001 *       .0000 * 15.43 /    44.111 =       .00000 GR/DSCF



        PARTICULATE LBS/HR — EPA METHOD 5

        PMR « CS * OSSTD / (15.43 • 453.6)

        PMR B       .00000 *    1595142. / (15.43  * 453.6)  =       .00000

-------
Run No.  D1.1
     Sample volume = 1 .25 m r  44.11  scf
Example calculations
     CS (Part) = 32.6/1.25 = 26.1   ma/m3
     CS (Part) = 0.001  x 32.6  x 15.43/44.11  = 0.011   qr/dscf
                                      3
CS (S02)  = 69.7/1.25 = 55.8  mg/m
          = 55.8 x 24.06/64   =21  ppm
          = 0.001  x 69.7 x 1
                                                     gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Water soluble sul fates
As S04=
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


32.6
21.8
21.1
16.8
16.4
14.6

0.0
0.0

<0.3
69.7

115*
N/A
N/A
N/A
3 Concentration,
mg/m


26.1
17.4
16.9
13.4
13.1
11.7

0.0
0.0

<0.2
55.8

92.0



gr/dscf


0.011
0.008
0.007
0.006
0.006
0.005

0.0
0.0

0.000
0.024

0.040



ppm













21

22



*Field analysis, isopropanol contaminated.
                                   A-307

-------
                                                           FIELD   DATA
            PLANT
            SAMPLING  LOCATION

            SAMPLE  TYPE
            OPERATOR
            AMBIENT TEMP.(OEG.F)
            BAR.PRESS.(IN.HG)
            STATIC  PRESS.(IN.H20)
            FILTER  NUMBER(S)
            STACK INSIDE  DIM.(IN)
            PITOT TUBE COtFF.
            THERM.  NO.
            LEAKAGE
            METER CALIB.  FACTOR
                    REPUBLIC STEEL CLEVELAND
                    NO.I COKE BATTERY OUTLET

                    PART/H2S04/S02
                    BRUFFEY
                     36.
                    29.21
                    -1.20
                    3530320
                      97.50    .00
                      .84
                     .000 CFM 9
                    1.016
                5.0 IN.HG
            READ  *  RECORD  DATA  EVERY  10.0  MINUTES
TRAVERSE
POINT
NO.
SAMPLE
TIME
(MIN.)
CLOCK
TIME
(24-HR
CLOCK)
GAS METER
READING
(CU.FT.)
VELOCITY
HEAD
(IN.H20)
                                                    ORIFICE PRESSURE   STACK
                                                      DIFFERENTIAL      TEPP
                                                        (IN.HZO)       (DEG.F)
                         DATE
                         RUN NUMBER

                         PROBE LENGTH S TYPE
                         NOZZLE      : 1.0.
                         ASSUMED MOISTURE
                         SAMPLE BOX NUMBER
                         PETER BOX NUMBER
                         KETEH HEAD OIFF.
                         c FACTOR
                         PROBE HEATER SETTING
                         HEATER BOX SETTING
                         REFERENCE PRESS. DIFF,
                                          12/08/01
                                            Dl-i

                                          5*  HEATED  GLASS
                                           .401
                                          14.0
                                           0
                                          FB5
                                          1.86
                                           .64
                                          350.
                                          850.
                                           .00
                                                    DESIRED   ACTUAL
                                                              DRY GAS METER
                                                                  TEMP
                                                                 (DEG.F)

                                                              INLET  OUTLET
                                     PUHP    SAMPLE
                                    VACUUM  BOX  TEMP
                                    (IN.HG) (OEG.F)
                                                                              IMPINGER
                                                                                TEMP
                                                                              (OEG.F)
       INIT
o
00
0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
ao.o
90.0
1206
1216
1226
1238
1248
1258
1308
1318
1326
1338
    TOTALS
    AVERAGE
90.0
349.502
353.780
357.960
362.170
366.360
370.540
374.760
378.910
383.140
387.318

 37.616
                              .050
                              .050
                              .050
                              .050
                              .050
                              .050
                              .050
                              .050
                              .050
.59
.59
.59
.59
.59
.59
.59
.59
.59
                                        .59
.59
.59
.59
.59
.59
.59
.59
.59
.59
                                .59
435,
465.
473.
471,
464.
495,
453.
462,
474.
               466.
37.
36.
39.
40.
41.
43.
43.
43.
43.
               41.
38.
30.
39.
39.
39.
40.
40.
4V.
40.
39.
        2.0
        2.0
        2.0
        2.0
        3.0
        2.0
        2.5
        2.0
        2.0
269.
270.
273.
272.
270.
273.
275.
270.
279.
                         2.2   272.
33.
34.
36.
37.
36.
37.
35.
34.
30.
                                 35.

-------
           PARTICULATE FIELD DATA « RESULTS TABULATION



PLANT- NAME AND ADDRESS               TEST TEAM LEADER




REPUBLIC STEEL CLEVELAND              BRUFFtY
TEST   DI-Z
NO.l COKF. BATTERY OUTLET

TEST DATE
TB
TF
TT
NP
Y
ON
CP
PM
1
0 VM
VD
TM
VMSTD
VLC
VMC
BNO
FMD
PC02
P02
PCO
PN2
MD
HWS


TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H20 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF MATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL., DRY
PERCENT 02 BY VOL., DRY
PERCENT CO BY VOL., DRY
PERCENT N2 BY VOL., DRY
MOLECULAR NT-ORY STACK GAS
MOLECULAR MT-STACK GAS
ENGLISH UNITS
12/08/61
1206
1338
90.0
9
1.016
.401 IH
.64
.59 IN-H20
37.616 CU-FT
40.0 F
39.669 SCF
111.4
5.244 SCF
11.66
.663
4.50
9.40
.00
86.10
29.10
27.80
METRIC UNITS
12/08/61
1206
1338
90.0
9
1.016
10.2 VM
.84
15.0 PM-H20
1.071 CU-M
4.4 C
1.123 SCC
111.4
.146 SCM
11.66
.683
4.bO
9.40
.00
66.10
29.10
27.80

-------
    PB

    PSI

    PS

    TS

    VS

    AS

    OSSTO

    OS

    ISO

    MN



    cs

    PMR
BAROMETRIC PRESSURE

STATIC PRES OF STACK GAS

STACK PRES* ABS.

AVERAGE STACK TEMP

AVG STACK GAS VELOCITY

STACK AREA

STACK FLOW RATE» OR**

ACTUAL STACK FLOW RATE

PERCENT ISOKINEUC


  MG. EPA 5
     29.21  IN-HG

     •1.20  IN-H20

     29.12  IN-HG

    468.    F

     IT.2   FPS

   7466.   SO-IN

1569507.    SCFH

3206763.    ACFH

     99.6

       .0000


       .00000 GR/DSCF*

       .00000 LB/HR
  741.93  HM-HG

  •30.46  KM-H20

  739.69  PM-HG


  242.    C

    5.2   fPS

    4.617 SO-M

44444.    SCMH

90863.    ACPH

   99.6

     .0000



     .0000 MG/OSCM

     .000 KG/HR
                EMISSION RATE

       *  68 DEG F,  29.98 IN.HG.
U)
M
O

-------
      EXAMPLE  PARTICULATE  CALCULATIONS  TEST  NO.   Dl-2

           NO.I COKE  BATTERY  OUTLET



VOLUME OF ORT  GAS SAMPLED  AT  STANDARD CONDITIONS

VMSTO •  (17.647 • VM  *  Y •  (PB  +  PM  / 13.6))  /  (TM  »  460.)

          17.647 •    37.816  •  1.016 *  (  39.21  «•  .590  /  13.6)
VMSTD *  —	  =     39.669 DSCF
                         (  40. •» 460.)



VOLUME OF HATER VAPOR AT STANDARD CONDITIONS

VMC « .04707 • VLC

VNC » .04707 *  111.  =   9.24 SCF



PERCENT  MOISTURE IN STACK GAS

BMO * (100. *  VNC) /  (VMSTD * VHC)

          100. •   5,24
BNO » —	•	—....  r M.68  PERCENT
            39.669 »    5.24



MOLE FRACTION OF DRY STACK GAS

FMD « (100. - BNO) /  100.

          100. -  11.7
FMD « —	————	— »    .883
               100.



AVERAGE MOLECULAR HEIGHT OF DRY STACK GAS

MD * (PC02 * .44) * (P02 * .32) *  (PN2 *  PCO) • .28

MO = ( 4.50*44/100) «• ( 9.4*32/100)  * ((86.1* .0) * 28/100 *    29.10



MOLECULAR HEIGHT OF STACK GAS

MHS * MD • (1. - (BHO/100)) » 18. *  (BNO/100)

MHS *  29.10* (1. -(11.68/100)) * 18. * (11.68/100)  s   27.80

-------
STACK GAS VELOCITY AT STACK CONDITIONS

DELP • SUM. OF THE SORHVH * (TS » 060.))

VS a 85.49 • CP • DELP / (SORT(MWS • PS) * PNTS)

VS « 85.09 •  .80 •   61.303 / (SORT( 27.80 * 29.12)  *   9. =   17.19 FPS



STACK GAS VOLUMETRIC FLOM AT STACK CONDITIONS

OS « V3 • AS • 3600/100

OS *   17.19 •  7466. 3600/140 «    3208783. ACFH



STACK GAS VOLUMETRIC FLON AT STANDARD CONDITIONS

OSSTD * 17.647 * OS * PS * (I. • (BHO/100)) / (TS * 460.)

          17.647 *    3208783. *  29.12 * (1. • (11.68/100))
OSSTD * — — — ---- - --------------------- - ----------------- =    1569507. SCFH
                   ( 468. » 460.)



PERCENT ISOKINETIC

ISO * (305.58*(TS+460.))*((0.002669*VLC)*(VM*Y*(PB»(PM/13.6))/(TM»460.)))/(TT*VS*PS*ON*DN)
       (305.58*( 468. *460.))*((0. 002669*  lll.)+(   37.816*1 .016* ( 29.21M    .590/13.6) )/(  O0.«460.)))
ISO » — — — ---- « — - ------- — --- ....... ---- .. ------- . ---------- - ------ ....... ----- ..... ------ . ----- -  99.62  PERCENT
                                    90. *     17.19 *   29.12 *  .401 •  .001



PARTICIPATE LOADING — EPA METHOD 5 (AT STANDARD CONDITIONS)

CS « 0.001 • MN * 15.43 / VMSTD

C3 * 0.001 *       .0000 * 15.43 /    39.669 =       .00000 GR/DSCF



PARTICULATE LBS/HR — EPA METHOD 5

PMR a CS • OSSTD / (15.43 • 453.6)

PMR •       .00000 *    1569507. / (15.43 * 453.6) =      .00000

-------
Run No.  PL2
     Sample volume = 1.12 m  r 39.67
Example  calculations
     CS  (Part)  =  37.4/1.12 = 33.4  mq/m3
     CS  (Part)  =  0.001  x 37.4 x 15.437 39.67=  Q.Q14  qr/dscf
     CS  (S02)   =116.1/1.12 = 103.7ma/m3
               =  103.7X 24.06/64  = 39 ppm
               =  0.001  x 116.1X 15.43/39.67  == 0.045 gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Water soluble sul fates
As S04=
Sulfur dioxide
Sul f uric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


37.4
22.0





2.0
2.7

2.1
116.1

3.5
N/A
N/A
N/A
3 Concentration,
mg/m


33.4
19.6





1.8
2.4

1.9
103.7

3.1



gr/dscf


0.014
0.008





0.001
0.001

0.001
0.045

0.001



ppm












39

1



                                     A-313

-------
                                                            FIELD  DAT*
 I
U)
PLANT REPUBLIC STEEL
SAMPLING LOCATION STACK OUTLET
SAMPLE TYPE PART/H2304/S02
OPERATOR DAN FITZGERALD
AMBIENT TEMP. (DEC. F) 36.
BAR. PRESS. (IN. HG) 29.21
STATIC PRESS. ( IN. H20) -1.20
FILTER NUMBER(S) 3530349
STACK INSIDE DIM. (IN) 97.75 .00
PITOT TUBE COEFF. .84
THERM. NO. 133
LEAKAGE .012 CFM 9 5.
METER CALIB. FACTOR 1.031
READ ft RECORD DATA EVERY 10.0 MINUTES
TRAVERSE
POINT
NO.

INtT









SAMPLE
TIME
(MIN.)

0
10.0
20.0
30.0
40.0
SO.O
60.0
70.0
60. 0
90.0
CLOCK
TIME
(Z4-HR
^i nr v \
CLUCK!
1205
1215
1225
1235
1245
1255
1305
1315
1325
1335
GAS METER
READING
(CU.FT.)

US. 363
169.785
174.100
176.120
182.375
186.670
190.950
195.325
199.630
203.870
VELOCITY
HEAD
(IN.H20)


.050
.050
.050
.050
.050
.050
.050
.050
.050
CLEVELAND OHIO
0 IN.HG
ORIFICE
PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.66
.66
.65
.66
.6«
.64
.66
.66
.65
H20)
ACTUAL

.66
.66
.65
.66
.64
.64
.66
.66
.65
STACK
TEMP
(DEG.F)


452.
463.
472.
467.
488.
492.
450.
459.
470.
DATE 12/08/81
RUN NUMBER 01-3
PROBE LENGTH S TYPE 4 FOOT GLASS
NOZZLE 1-3 t I.D. .402
ASSUMED MOISTURE 13.7
SAMPLE BOX NUMBER
METER BOX NUMBER FBI
METER HEAD DIFF. i.ee
PROBE HEATER SETTING 350.
HEATER BOX SETTING 350.
K FACTOR 12094.5
DRY GAS METER
TEMP
(OEG.F)
INLET OUTLET

37. 37.
38. 37.
41. 38.
43. 38.
45. 38.
46. 39.
47. 40.
47. 40.
47. 40.
PUMP
VACUUM
(IN.HG)


1.0
1.0
1.0
2.0
3.0
3.5
3.5
4.0
4.5
SAMPLE
BOX TEMP
(DEG.F)


381.
373.
378.
375.
373.
369.
370.
372.
372.
IMPINGER
TEMP
(OEG.F)


38.
39.
43.
44.
46.
47.
50.
52.
54.
    TOTALS
    AVERAGE
90.0
38.507
                                        .65
                               .65   468.
43.
39,
2.6   374.
46.

-------
           PARTICIPATE FIELD DATA ft RESULTS TABULATION




PLANT* NAME AND ADDRESS               TEST TEAM LEADER




REPUBLIC STEEL CLEVELAND OHIO         DAN FITZGERALD
TEST   Dl-3
STACK OUTLET


TEST DATE
TB
TF
TT
NP
Y
ON
CP
PM
1 VM
u>
I-1
en
TM
VMSTD
VLC
VMC
BMO
FMD
PCOZ
POZ
PCO
PNZ
MD
HW3
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL HZO COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF WATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL., DRY
PERCENT 02 BY VOL., DRY
PERCENT CO BY VOL., DRY
PERCENT N2 BY VOL., DRY
MOLECULAR NT-DRY STACK GAS
MOLECULAR NT-STACK GAS
ENGLISH UNITS
12/08/81
1205
1335
90.0
9
1.033
.402 IN
.84
.65 IN-H20
38.507 CU-FT
41.0 F
40.994 SCF
113.9
5.361 SCF
11.57
.884
4.50
9.40 .
.00
86.10
29.10
27.81
METRIC UNITS
12/08/81
1205
1335
90.0
9
1.033
10.2
.84
16.6
1.090
5.0
1.161
113.9
.152
11.57
.884
4.50
9.40
.00
86.10
29.10
27.81



I'M

PM-H20
CU-M
C
SCM

SCM









-------
     PB

     PSI

     PS

     TS
     VS
     »3
     OS3TD

     OS

     ISO
     MN

     CS
     PMR
    BAROMETRIC PRESSURE
    STATIC PRES OF STACK GAS

    STACK PRES, ABS.
    AVERAGE STACK TEMP

    AVG STACK CAS VELOCITY
    STACK AREA
    STACK FLO* RATE, DRY*

    ACTUAL STACK FLON RATE

    PERCENT ISOKINETIC

      MG. EPA 5



      EMISSION RATE
66 DEC f,  29.42 IN.HG.
     29.21  IM-HG

     -1.20  IN-H20

     29.12  IN-HG

    468.    F

     17.2   FPS

   7505.   SO-IN

1579103.    SCFH

3224786.    ACFH

    102.3

       .0000

       .00000 GR/OSCF*

       .00000 L8/HR
  741.93  HM-HG

  •30.48  WN-H20

  739.69  *M-HG

  242.    C

    5.2   WPS

    4.842 30-M

44715.    SC*H

91316.    ACHH

  102.3

     .0000

     .0000 MG/DSCM

     .000 KG/HR
>
co

-------
             EXAMPLE  PARTICIPATE  CALCULATIONS  TEST  NO.   01-3

                   STACK  OUTLET



       VOLUME OF  DRY  6*3 SAMPLED  AT  STANDARD CONDITIONS

       VMSTO »  (17.647 • VM  • Y *  (PB  *  PM  / 13.6))  /  (TM »  460.)

                  17,647  •    38.507  *  1.033 *  (  29.31 *   .653  /  13.6)
       VMSTD »  ——————.—.———— — — — — —  =      40.994 DSCF
                                (  41. *  460.)



       VOLUME OF  HATER VAPOR AT STANDARD  CONDITIONS

       VMC * .04707 • VLC

       VNC « .04707 *  114.  a   9.36 SCF



       PERCENT  MOISTURE  IN STACK  GAS

       BMO a (100. •  VHC) /  (VMSTD • VNC)

>                 100. •   5.36
'      BNO * ————	...—.. s 11.57  PERCENT
i_.                  40.994 »   5.36
       MOLE FRACTION OF DRY STACK GAS

       FMD • (100. • BMO) / 100.

                 100. •  11.6
       FMD a —•	——	....... *    .864
                      100.
       AVERAGE MOLECULAR HEIGHT OF DRY STACK GAS

       MD a (PC02 * .44) *  (P02 • .32) *  (PN2 * PCO) •  .28

       MD • ( 4.50*44/100)  » ( 9.4*32/100) * ((86.1* .0) * 26/100 =   29.10



       MOLECULAR HEIGHT OF  STACK GAS

       MH9 a MD * (1. • (BNO/100)) + 18.  * (BMO/100)

       MNS •  29.10* (1. -(11.57/100)) *  18. •  (11.57/100) a   27.81

-------
     STACK GAS VELOCITY AT STACK CONDITIONS

     OELP « SUM. OF THE SQRUVH * (TS * 060.))

     VS * 85.49 * CP • DELP / (SORT (MWS * PS)  * PNTS)

     VS * SS.49 *  .84 •   61.308 / (3QRT( 37.81 * 29.13)   *   9.  =   17.19 FPS



     STACK 6A3 VOLUMETRIC FLOW AT STACK CONDITIONS

     OS * VS * AS • 3600/144

     OS *   17.19 t  7505. 3600/144 *    3224786. ACFH



     STACK GAS VOLUMETRIC FLON AT STANDARD CONDITIONS

     8SSTD » 17.647 * OS * PS * (1. - (BwO/100)) / (TS * 460.)

               17.647 *    3224786. *  29.12 * (1. - (11.57/100))
     OSSTO « —	———	•	=    1579103. SCFH
                        ( 468. * 460.)



>    PERCENT ISOKINETIC

£    ISO * (305.58*(TS+460.))*((0.002669*VLC)»(VM*Y*(PB«(PM/13.6))/(TM+460.)))/ITT*VS*PS*DN*ON)
00
            (305.58*( 468.+460.))*((0.002669*   114.)*(   38.507*1.033*1 29.21+1    .653/13.6))/(  41.«460.)))
     ISO * ——————	.	—	......	................	.	—	s 102.34 PERCENT
                                         90. *     17.19 *   29.12 *  .402 *  .402



     PARTICULATE LOADING — EPA METHOD 5 (AT STANDARD CONDITIONS)

     CS * 0.001 * MN * 15.43 / VMSTO

     CS s 0.001 *       .0000 * 15.43 /    40.994 s       .00000 GR/OSCF



     PARTICULATE LBS/HR ~ EPA METHOD 5

     PMR * CS * OSSTD / (15.43 * 453.6)

     PMR s       .00000 *    1579103. / (15.43 * 453.6)  s       .00000

-------
Run No. PI.3
                          3
     Sample volume = 1.16  m T 40.99 scf
Example  calculations
     CS  (Part) =34.0/1.16 = 29.3  mq/m3
     CS  (Part) = 0.001 x34.0  x 15.43^0.99 = 0.013  qr/dscf
     CS  (S02)  =117.0/1.16  =100.9ma/m3
              = 100.9x 24.0664   =38 ppm
              = 0.001 xlU.Ox 15.43/_4_OJ2_=0_J}4J_ gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Water soluble sul fates
As S0d=
Sulfur dioxide
Sulfuric acid mist
As H2$04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
34.0
0.0
0.0
2.5
117.0
9.3
N/A
N/A
N/A
3 Concentration,
mg/m
29.3
0.0
0.0
2.1
100.9
8.0



gr/dscf
0.013
0.000
0.000
0.001
0.044
0.004



ppm



38
2



                                     A-319

-------
                                                           FIELD  DATA
U)
PLANT REPUBLIC STEEL
SAMPLING LOCATION STACK OUTLET «1
SAMPLE TYPE PART/H2S04/S02
OPERATOR DAN FITZGERALD
AMBIENT TEMP. (DEC. F) 36.
BAR. PRESS. UN. KG) 2V. 21
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530363
STACK INSIDE DIM. (IN) 97.75 .00
PITOT TUBE COEFF. .04
THERM. NO. 133
LEAKAGE .001 CFM 9 5.
METER CALIB. FACTOR .902
READ ft RECORD DATA EVERY 10.0 MINUTES
TRAVERSE
POINT
NO.

INIT









SAMPLE
TIME
(MIN.)

0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
ao.o
90.0
CLOCK
TIME
(20-HR
f* i nf k i
CLUCK]
1208
1210
1220
1230
1240
1250
1300
1310
1320
1330
GAS METER
READING
(CU.FT.)

597.103
601.255
605.610
610.030
614.360
616.650
622.940
627.325
631.705
636.074
VELOCITY
HEAD
(IN.H20)


.050
.050
.050
.050
.050
.050
.050
.050
.050
CLEVELAND OHIO
8ATTEHY
0 IN.HG
ORIFICE
PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.66
.66
.65
.66
.64
.63
.66
.66
.65
H20)
ACTUAL

.66
.66
.65
.66
.64
.63
.66
.66
.65
STACK
TEMP
(DEG.F)


055.
465.
473.
471.
404.
495.
453.
462.
474.
DATE 12/00/01
NUN NUMBER 01-4
PROBE LENGTH « TYPE 5 FOOT GLASS
N02ZLE 1*4 : I.I). .401
ASSUMED MOISTURE 13.7
SAMPLE BUX NUMBER
PETER BUX NUMBER FBS
HETER HEAD OIFF. 1.91
PROBE HEATER SETTING 350.
HEATER BOX SETTING 350.
K FACTOR 12094.5
DRY GAS METER
TEMP
(DEG.F)
INLET OUTLET

36. 34.
30. 32.
40. 35.
42. 36.
44. 36.
44. 36.
45. 37.
45. 37.
45. 37.
PUMP
VACUUM
(IN.HG)


1.5
1.5
1.5
1.5
2.5
3.0
3.5
3.5
3.5
SAMPLE
BOX TEMP
(DEG.F)


304.
332.
341.
339.
330.
330.
335.
334.
343.
IMPINGER
TEMP
(DEG.F)


40.
42.
40.
40.
42.
43.
44.
46.
47.
   TOTALS
   AVERAGE
90.0
30.971
                                         .65
                               .65   470,
42.
36.
2.4   333.
43.

-------
           PARTICIPATE FIELD DATA ft RESULTS TABULATION




PLANT- NAME AND ADDRESS               TEST TEAM LEADER




REPUBLIC STEEL CLEVELAND OHIO         DAN FITZGERALD
TEST   01-0
STACK OUTLET »1 BATTERY

TEST DATE
TB
TF
TT
NP
T
ON
CP
PM
fr
1
U) VM
KJ
M
TM
VMSTO
VLC
VNC
BNO
FMO
PC02
P02
PCO
PN2
MO
MHS


TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H20 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF MATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRV GAS
PERCENT C02 BY VOL., DRY
PERCENT 02 BY VOL., DRV
PERCENT CO BY VOL., DRY
PERCENT N2 BY VOL., DRY
MOLECULAR MT-DRV STACK GAS
MOLECULAR XT-STACK GAS
ENGLISH UNITS
12/08/61
1208
1336
90.0
9
.982
.401 IN
.84
.65 IN-H20
38.971 CU-FT
38.8 F
39.611 SCF
103.5
4.872 SCF
10.95
.890
4.50
9.40
.00
86.10
29.10
27.88
METRIC UNITS
12/08/81
1208
1338
90.0
9
.982
10.2 MM
.84
16.6 PM-H20
1.104 CU-M
3.8 C
1.122 SCM
103.5
.138 SO
10.95
.890
4.50
9.40
.00
86.10
29.10
27.88

-------
      PB

      Pdl

      PS

      TS

      VS

      AS

      QSSTD

      OS

      ISO

      MN



      CS

      PMR
    BAROMETRIC PRESSURE

    STATIC PRES OF STACK GAS

    STACK PRESf ABS.

    AVERAGE STACK TEMP

    AVG STACK GAS VELOCITY

    STACK AREA

    STACK PLON RATE* DRY*

    ACTUAL STACK FLO* RATE

    PERCENT ISOKINETIC



      M6. EPA 5





      EMISSION RATE

68 OEG F,  39.92 IN.HG.
     29.81  IN-HG

     •1.20  IN-H20

     29.12  IN-HG

    470.    F

     17.2   FPS

   7505.   SQ-IN

1586320.    SCFH

3224520.    ACFH

     98.9

       .0000



       .00000 GR/DSCF*

       .00000 LB/HR
  741.93  CM-HG


  -30.48  PM-H20


  739.69  MM-MG


  243.    C


    5.2   VPS

    4.842 3Q-M


44920.    SCKH


91309.    ACMH

   98.9


     .0000



     .0000 MG/DSCM


     .000 KG/HR
U)
to
N)

-------
      EXAMPLE PARTICIPATE CALCULATIONS  TEST  NO.   Dl-4

           STACK OUTLET HI BATTERY



VOLUME OF DRV GAS SAMPLED AT  STANDARD CONDITIONS

VM9TD • (17.647 • VM • Y * (PB * PM / 13.6))  /  (TM  » 460.)

          17.647 •    38.971  •  .982 *  (  29.21  *  .652  /  13.6)
VMSTO « —————............	.......................—  5      39.611  DSCF
                         (  39. * 460.)



VOLUME OF HATER VAPOR AT STANDARD CONDITIONS

VNC « .04707 * VLC

VNC • .04707 «  104. =   4.87 SCF



PERCENT MOISTURE IN STACK GAS

BNO » (tOO. * VNC) / (VMSTD * VNC)

          100. *   4.87
BNO » ———	—	— r 10.95  PERCENT
            39.611 »   4.87



MOLE FRACTION OF DRY STACK GAS

FMD « (100. - BNO) / 100.

          100. •  11.0
FMD • —————	B   .890
               100.



AVERAGE MOLECULAR HEIGHT OF DRY STACK GAS

MD * (PC02 * .44)  * (P02 • .32) * (PN2 *  PCO) * .28

MO « ( 4.50*44/100) * ( 9.4*32/100)  * ((86.1* .0) * 28/100 =   29.10



MOLECULAR NEIGHT OF STACK GAS

MNS • MD * (1. - (8*0/100))  * 18. *  (8*0/100)

MNS «  29.10* (1.  -(10.95/100)) * 18. * (10.95/100)  •   27.88

-------
      STACK  GAS  VELOCITY  AT  STACK  CONDITIONS

      DELP * SUM.  OF  THE  SQRHVH *  (TS  *  060.))

      VS  * BS.49 * CP * DELP /  (SORT(MWS  *  PS) •  PNTS)

      VS  » 65.49 * .84 *    61.378  /  (SORTl 27.88 *  29.12)   *    9.  c    17.19  FPS



      STACK  GAS  VOLUMETRIC FLO* AT  STACK  CONDITIONS

      OS  * VS *  AS *  3600/144

      OS  •    17.19 •   7SOS.  3600/144  a    3224520. ACFH



      STACK  GAS  VOLUMETRIC FLOH AT  STANDARD CONDITIONS

      098TD  * 17.647  * OS *  PS  * (1.  -  (BNO/100))  /  (TS  *  460.)

                17.647 •     3224520.  *  29.12  *  (1.  -  (10.95/100))
      OSSTO  » ————	——	=    1586320.  SCFH
                         ( 470. *  460.)



•f     PERCENT ISOKINETIC
U)
N)     ISO *  (305.58*ITS*460.))*((0.002669*VLC)*(VM*Y*(PB*(PM/13.6))/(TM*460.)))/(TT*VS*PS*DN*DN)
it»
             (305.58*( 470.+460.))*((0.002669*   104.)*(    38.971*  .982*(  29.21*(     .652/13.6))/(  39.«460.)))
      ISO »  —————	.......	.	.......	.	................	..... s  98.93 PERCENT
                                         90.  *      17.19  *    29.12 *   .401 * .401



      PARTICULATE  LOADING — EPA METHOD 5 (AT  STANDARD CONDITIONS)

      CS  « 0.001 • MN • 15.43 / VMSTD

      CS  * 0.001 *       .0000  * 15.43  /    39.611 c       .00000  GR/DSCF



      PARTICULATE  LBS/HR —  EPA METHOD  5

      PMR »  CS • OSSTD /  (15.43 •  453.6)

      PMR *        .00000 *    1586320.  /  (15.43  *  453.6) =       .00000

-------
Run No.  D1.4
                           o
     Sample volume =  1.12m ,39.61  scf
Example  calculations
     CS  (Part)  =  43.3/1.12 =  38.7  mq/m3
     CS  (Part)  =  0.001  x  43.3 x 15.43/39.61 = 0.017  qr/dscf
     CS  (S02)   =115.8/1.12 = 103.4ma/m3
               =103.4 x 24.06/64  = 39 pom
               =  0.001  x115.8 x 15.43/39.61  = 0.045 gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Water soluble sul fates
As S04-
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


43.3





•
0.0
0.0

0.0
115.8

9.2
N/A
N/A
N/A
3 Concentration,
mg/m


38.7






0.0
0.0

0.0
103.4

8.2



gr/dscf


0.017






0.000
0.000

0.000
0.045

0.004



ppm












39

2



                                    A-325

-------
                                                               FIELD   DAT*
               PLANT
               SAMPLING  LOCATION

               SAMPLE  TYPE
               OPERATOR
               AMBIENT TEMP.(DEG.F)
               BAR.PRESS.(IN.HG)
               STATIC  PRESS.(IN.H20)
               FILTER  NUMBER(S)
               STACK INSIDE  DIM.(IN)
               PITOT TUBE COEFF.
               THERM.  NO.
               LEAKAGE
               METER CALIB.  FACTOR
                     REPUBLIC STEEL CLEVELAND
                     COKE STACK

                     MB-600
                     OU
                      37.
                     29.21
                     -1.20
                     3530220
                       97.50    .00
                       .83
                      .012 CFM a
                      .967
                          8.0 IN.HG
               READ  I  RECORD  DATA  EVERY  10.0  MINUTES
         TRAVERSE
          POINT
           NO.
SAMPLE  CLOCK
 TIME    TIME
(MIN.) (24-HR
        CLOCK)
        GAS METER
         READING
         ICU.FT.)
         VELOCITY
           HEAD
         (IN.H20)
      ORIFICE PRESSURE  STACK
        DIFFERENTIAL     TEMP
         (IN.H20)      (DEG.F)
                                                DATE                      12/08/81
                                                RUN NUMBER                  01-6

                                                PROBk LENGTH  ft  TYPE       6*  GLASS
                                                NOZZLE       :  I.U.         .379
                                                ASSUMED MOISTURE          13.7
                                                SAMPLE BOX NUMBER
                                                METE* BOX NUMBER          FB6
                                                METER HEAD OIFF.          1.51
                                                C FACTOR                   .71
                                                PROBE HEATER  SETTING      6UU.
                                                HEATER BOX SETTING        600.
                                                REFERENCE PRESS. DIFF.     .22
                      DRY GAS METER  PUMP
                          TEMP      VACUUM
                         (DtG.F)    (IN.HG)
                                    SAMPLE
                                   BOX TEMP
                                   (DEG.F)
                               IMPINGER
                                 TEMP
                               (DEG.F)
                                                        DESIRED    ACTUAL
                                                               INLET  OUTLET
          INIT
UJ
fO
       TOTALS
       AVERAGE
  0
 10.0
 20.0
 30.0
 40.0
 SO.O
 60.0
 70.0
 80.0
 90.0

 90.0
1209
1219
1229
1239
1249
1259
1309
1319
1329
1339
646.852
650.750
654.450
658.220
661.860
665.690
669.490
673.300
677.120
680.811

 33.959
.040
.040
.040
.040
.040
.040
.040
.040
.040
.35
.35
.35
.35
.35
.35
.35
.35
.35
                                         .35
.35   485.
.35   485.
.35   485.
.35   405.
.35   485.
.35   485.
.35   485.
.35   485.
.35   485.
                                          .35   485.
34,
35,
36,
39.
40.
41.
41.
42.
42.
                                               39,
37,
37,
37.
37.
37,
37,
37.
37,
37,
                                          37,
3.2
3.0
3.0
3.2
4.0
6.0
6.5
6.8
7.1
569.
573.
510.
447.
489.
486.
514.
516.
529.
                                        4.8   515.
34.
34.
33.
33.
33.
34.
33.
34.
34.
                                                34.

-------
           PARTICIPATE FIELD DATA t RESULTS TABULATION
PLANT- NAME AND ADDRESS               TEST TEAM LEADER
REPUBLIC STEEL CLEVELAND              00
TEST   01-6
COKE STACK


TEST DATE
TB
TF
TT
NP
Y
ON
CP
PM
1
OJ VM
N)
-J
TM
VMSTD
VLC
VMC
BNO
FMD
PC02
P02
PCO
PN2
MD
MNS
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H20 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF NATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL., DRY
PERCENT 02 BY VOL., DRY
PERCENT CO BY VOL., DRY
PERCENT N2 BY VOL., DRY
MOLECULAR NT-DRY STACK GAS
MOLECULAR NT-STACK GAS
ENGLISH UNITS
12/08/81
1209
1339
90.0
9
.967
.379 IN
.63
.35 IN-H20
33.959 CU-FT
37.9 F
34.024 SCF
81.8
3.850 SCF
10.17
.898
4.50
9.40
.00
86.10
29.10
27.97
METRIC UNITS
12/08/81
1209
1339
90.0
9
.967
9.6
.83
8.9
.962
3.3
.963
81.8
.109
10.17
.896
4.50
9.40
.00
86.10
29.10
27.97



MM

MM-H20
CU-M
C
SO

SCM









-------
      PB




      PSI




      PS



      TS



      V3




      AS



      OSSTD




      OS




      ISO



      HN






      cs



      PMR
BAROMETRIC PRESSURE



STATIC PRES OF STACK GAS




STACK PRES, A8S.



AVERAGE STACK TEMP




AV6 STACK GAS VELOCITY




STACK AREA



STACK FLO* RATE* DRY*




ACTUAL STACK FLON RATE




PERCENT ISOKINETIC






  MG. EPA 5
     29.21  IN-HG




     -1.20  IN-H20




     29.12  IN-Ht




    485.    F




     15.3   FPS




   7466.   30-IN




1393914.    SCFH




2653244.    ACFH




    107.7




       .0000






       .00000 GR/OSCF*




       .00000 LB/HK
                  EMISSION  RATE



         *   68  DEC f,   29.93  IN.HG.
  741.93  KM-HG




  -30.48  CM-H20




  739.69  CM-HG




  252.    C




    4.7   MPS




    4.817 SO-M




39471.    SCMH




80795.    ACHH




  107.7




     .0000






     .0000 MG/OSCM




     .000 KG/HR
00

-------
to
vo
      EXAMPLE PARTICULATE CALCULATIONS  TEST  NO.   Dl-6

           COKE STACK




VOLUME OF DRV GAS SAMPLED AT STANDARD CONDITIONS

VMSTD *  (17.647 • VM • V •  (PB * PM  / 13.6))  /  (TM  + 460.)

          17.647 •    33.959 *  .967 *  (  29.21 *  .350  /  13.6)
VMSTD *  ———— — —	.........................	.......  c      34.024  DSCF
                         (  38. *  460.)



VOLUME OF HATER VAPOR AT STANDARD  CONDITIONS

VNC • .04707 • VLC

VNC « .04707 *   82. >   3.65 SCF




PERCENT  MOISTURE IN STACK GAS

BNO » (100. • VMC) / (VMSTD * VNC)

          100. •   3.85
BNO * ———.	..	..	— r 10.17  PERCENT
            34.024 *   3.85




MOLE FRACTION UF DRV STACK GAS

FMD « (100. - BNO) / 100.

          100. •  10.2
FMD « ———-.—	....... m    .698
               100.



AVERAGE MOLECULAR HEIGHT OF DRV STACK GAS

MD « (PC02 • .44) * (P02 * .32) *  (PN2 »  PCO) * .28

MD e C 4.50*44/100) «• ( 9.4*32/100) » ((86.1* .0) * 28/100 =   29.10




MOLECULAR HEIGHT OF STACK GAS

MNS * MD • (1. • (BHO/100))  * 18. * (BNO/100)

MNS »  29.10* (1. -(10.17/100)) * IB. * (10.17/100)  «   27.97

-------
STACK GAS VELOCITY AT STACK CONDITIONS

OELP * SUM. OF THE SORTtVH * (TS * 460.))

VS * 85.49 * CP * OELP / (SORT(MNS * PS) * PNTS)

V3 » 85.49 *  .83 *   55.334 / (SORT( 27.97 * 29.12)  *   9. r   15.29 FPS



STACK GAS VOLUMETRIC FLO* AT STACK CONDITIONS

OS « VS * A3 * 3600/144

OS »   15.29 *  7466. 3600/144 »    2853244. ACFH



STACK GAS VOLUMETRIC FLOW AT STANDARD CONDITIONS

OSSTO • 17.647 * OS * PS * (t. - (BWO/100)) / (TS « 460.)

          17.647 •    2853244. *  29.12 * (1. • (10.17/100))
OSSTO » ——————	...	...	..	s    1393914. SCFH
                   I 485. * 460.)



PERCENT ISOKINETIC

ISO « (305.58*(T8*460.))*((0.002669*VLC)*(VM*Y*(PBMPM/13.6))/(TM.i460.)))/(TT*VS*PS*DN*DN)

       (305.58*( 485.»460.})*((0.002669*   82.)*(   33.959* .967*( 29.21M    .350/13.6))/(  38.«460.)H
ISO »	.-.—.—......	.	.......	.	.	...	s  107.70  PERCENT
                                    90. *     15.29 *   29.12 *  .379 *  .379



PARTICULATE LOADING — EPA METHOD 5 (AT STANDARD CONDITIONS)

CS • 0.001 • MN * 15.43 / VMSTO

CS * 0.001 *       .0000 * 15.43 /    34.024 a       .00000 GR/DSCF



PARTICULATE LBS/HR -- EPA METHOD 5

PMR » CS * QSSTD / (15.43 * 453.6)

PMR *       .00000 *    1393914. / (15.43 * 453.6) «      .00000

-------
Run No. PI.6
     Sample volume  =0.96 m3.34.02  scf
Example  calculations
     CS  (Part)  =27.3  /0.96 =  28.4  mq/m3
     CS  (Part)  =  0.001 x 27.3 x 15.43/34.02 = 0.012  qr/dscf
     CS  (S02)   =  97.9/0.96 =102.0 mq/m3
               =102.0 x  24.06/64  = 38 ppm
               =  0.001 x 97.9 x 15.43/34.02  = Q.Q44 gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Water soluble sul fates
As S04=
Sulfur dioxide
Sul f uric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


27.3






0.0
0.0

1.6
97.9

6.3
N/A
N/A
N/A
- Concentration,
mg/m


28.4






0.0
0.0

1.7
102.0

6.6



gr/dscf


0.012






0.0
0.0

0.001
0.044

0.003



ppm













38

2



                                   A-331

-------
                                                               FIELD  I)»T»
to
u>
tO
PLANT REPUBLIC STEEL
SAMPLING LOCATION OUTLET STACK
SAMPLE TYPE PART/H2S04/S02
OPERATOR BRUFFEY
AMBIENT TEMP. (DEG.F) 28.
BAR. PRESS. (IN.HG) 29.51
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530310
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM a 6.
METER CALIB. FACTOR 1.003
READ ft RECORD DATA EVERY 10.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY
POINT
NO.

1NIT









TIME
(MIN.)

0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
TIME
(24-HR
ft flf* H \
ILUIK J
1341
1351
1401
1411
1421
1431
1441
1451
1501
1511
READING
(CU.FT.)

312.901
317.610
323.165
328.267
333.390
338.747
343.910
349.160
354.465
359.464
HEAD
(IN.H20)


.060
.065
.064
.066
.066
.060
.064
.064
.060
CLEVELAND
0 IN.HG
ORIFICE PRESSURE
STACK
DIFFERENTIAL TEPP
(IN.
DESIRED

.79
.86
.64
.87
.90
.79
.84
.84
.79
H2U)
ACTUAL

.79
.86
.84
.87
.90
.79
.84
.84
.79
(DEG.F)


500.
491.
505.
465.
476.
491.
473.
488.
496.
DATE 12/10/81
RUN NUMBER 02-1
PROBE LENGTH R TYPE 5' HEATfcl) GLASS
NOZZLE : I.D. .404
ASSUMED MOISTURE 14.0
SAMPLE BOX NUMBER 0
PETErt BOX NUMBER FB2
PETER HEAD DIFF. i.76
C FACTOR .62
PROBE HEATER SETTING 250.
HEATER BOX SETTING 250.
REFERENCE PRESS. OIFF. .14
DRY GAS METER PUMP SAMPLE IMPINGER
TEMP
(DEG
INLET

35.
35.
36.
37.
37.
37.
39.
38.
36.
.F)
OUTLET

32.
30.
30.
30.
30.
30.
30.
30.
30.
VACUUM
(IN.HG)


3.0
3.0
3.0
3.5
5.0
5.5
5.8
6.0
6.0
BOX TEMP
(DEG.F)


180.
236.
245.
234.
253.
254.
260.
262.
273.
TEMP
(DEG.F)


34.
36.
40.
37.
36.
38.
42.
42.
42,
      TOTALS
      AVERAGE
90.0
46.583
                                         .84
                                .64    487.
37,
30.
4.5   244.
39.

-------
           PARTICIPATE FIELD DATA ft RESULTS TABULATION

PLANT- NAME AND ADDRESS               TEST TEAM LEADER

REPUBLIC STEEL CLEVELAND              BHUFFEY
TEST   08-1
OUTLET STACK
ENGLISH UNITS
TEST DATE
TB
TF
TT
NP
Y
ON
CP
> PM
U)
LO
to VM
TM
VM3TD
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
12/10/81
1341
1511
90
9
1


46
33
49
.0

.003
.404 IN
.84
.84 IN-H20
.583 CU-FT
.6 F
.401 SCF
METRIC UNITS
12/10/81
1341
1511
90
9
1
10

21
1

1
.0

.003
.3
.84
.2
.319
.9
.399



MM

MM-H20
CU-M
C
SCM
          AT STANDARD CONDITIONS*

VLC       TOTAL H20 COLLECTED IN
          IMPINGERS AND SILICA GEL,ML.

VMC       VOLUME OF MATER VAPOR
          AT STANDARD CONDITIONS*

BMO       PERCENT MOISTURE BY VOLUME

FMD       MOLE FRACTION DRY GAS

PC02      PERCENT C02 BY VOL., DRV

P02       PERCENT 02 BY VOL., DRY

PCO       PERCENT CO BY VOL., DRY

PN2       PERCENT N2 BY VOL., DRY

MD        MOLECULAR HT-ORY STACK GAS

MhS       MOLECULAR NT-STACK GAS
                          145.9
                            6.868 SCF
145.9
   .194 SCC
12.20
.878
4.30
12.30
.00
83.40
29.18
27.82
12.20
.878
4.30
12.30
.00
83.40
29.18
27.82

-------
    PB

    PSI

    PS

    TS

    VS

    AS

    QS9TD

    OS

    ISO

    MN


    CS

    PMR
BAROMETRIC PRESSURE

STATIC PRE9 OF STACK GAS

STACK PRES, ABS.

AVERAGE STACK TEMP

AV6 STACK GAS VELOCITY

STACK AREA

STACK FLO* RATE, DRY*

ACTUAL STACK FLOW RATE

PERCENT ISOKINETIC


  MG. EPA 5
 29.51  1N-MG

 •1.20  1N-M20

 29.02  IN-HG

087.    F

        FPS

       SO-IN

        SCFH

        ACFH
     19.5

   7466.

1707391.

3631009.

    109.6

       .0000
                                   .00000 GR/OSCF*

                                   .00000 LB/HR
   709.55  MM-HG

   •30.08  KM-H20

   707.31  KM-HG

   253.     C

     5.9   UPS

     0.817 SO-M

 09081.     SCMH

102820.     ACMH

   109.8

      .0000


      .0000 MG/DSCM

      .000 KG/HR
                EMISSION  RATE

       *   68  DEC f,   29.92  IN.HG.
U)
UJ

-------
             EXAMPLE  PARTICIPATE  CALCULATIONS  TEST  NO.   02-1

                  OUTLET  STACK



       VOLUME OF DRY  GAS  SAMPLED  AT  STANDARD CONDITIONS

       VMSTO «  (17.647 •  VM  * V •  (PB  •»  PM  / 13.6))  /  (TM +  460.)

                 17.647 *    46.563  *  1.003 •  (  29.51 *   .636  /  13.6)
       VMSTD »  ————	•	=     19.401  DSCF
                                (  34. + 460.)



       VOLUME OF MATER VAPOR AT STANDARD CONDITIONS

       VNC * .04707 * VLC

       VMC • .04707 *  146.  =   6.67 SCF



       PERCENT  MOISTURE IN STACK  GAS

       BNO » (100. •  VMC) /  (VMSTO + VNC)

                 100. *   6.67
       BNO « ..———.-..............  3 12.20  PERCENT
>                  49.401 *   6.67

UJ-
U)
en
       MOLE FRACTION OF DRY  STACK GAS

       FMO » (100. • BHO) /  100.

                 100. -  12.2
       FMD • ————	—— •    .878
                      100.
       AVERAGE MOLECULAR HEIGHT OF DRY STACK GAS

       MD » (PC02 * .44) * (P02 * .32) *  (PN2 « PCO) •  .26

       MO * ( 4.30*44/100) » (12.3*32/100) » ((83.0+ .0) • 26/100 x   29.18



       MOLECULAR HEIGHT OF STACK GAS

       MfcS a MD • (1. • (BHO/100)) + 18.  * (BMO/100)

       MN9 »  29.16* (1. -(12.20/100)) 4  16. * (12.20/100) *   27.62

-------
     STACK GAS VELOCITY AT STACK CONDITIONS

     DELP « SUM. OF THE SORT(VH * (TS •» 460.))

     V3 a 85.49 * CP * OELP / (SQRT(MNS * PS) * PNTS)

     VS = 85.49 •  .84 •   69.746 / (SORT( 27.82 • 29.42)   •   9. =   19.45 FPS



     STACK GAS VOLUMETRIC FLOW AT STACK CONDITIONS

     OS a VS * AS • 3600/144

     OS *   19.45 •  7466. 3600/144 *    3631049. ACFH



     STACK GAS VOLUMETRIC FLON AT STANDARD CONDITIONS

     OSSTO * 17.647 * OS * PS * (1. » (BMO/100)) / (TS * 460.)

               17.647 *    3631049. *  29.42 * (1. • (12.20/100))
     OSSTO « —	•	—	•	s    1747391. SCFH
                        ( 487. + 460.)



>
 I    PERCENT ISOKINETIC
OJ
J£   ISO • (305.58*(T3+460.))*((0.002669*VLC)*(VM*T*(PB«(PM/13.6))/(TM*460.)))/(TT*VS*PS*DN*DN)

            (305.58*( 487.«460.))*((0.002669*  146. )*(   46.583*1.003* ( 29.51*(    .836/13.6))/(  34.«460.)))
     ISO » —————	——	—	......	.	.	...	...	....	.	.. s  109.78 PERCENT
                                         90. *     19.45 *   29.42 «  .404 *  .404



     PARTICULATE LOADING — EPA METHOD  5 (AT STANDARD CONDITIONS)

     CS » 0.001 • MN * 15.43 / VMSTO

     CS * 0.001 *       .0000 * 15.43 /    49.401 >       .00000 GR/DSCF



     PARTICULATE LBS/HR — EPA METHOD 5

     PMR • CS * OSSTD / 115.43 « 453.6)

     PMR *       .00000 *    1747391. / (15.43 * 453.6) •       .00000

-------
Run No.  D2.1
     Sample volume = 1.40 m3. 49.40 scf
Example  calculations
     CS  (Part)  =249.9/ 1.40=178.5 mq/m3
     CS  (Part)  =  0.001 X249.9X 15.43/49.40=  0.078 qr/dscf
     CS  (S02)   =  120.&/ 1.40=86.3 mq/m3
               =  86.3 x  24.067 64 =32 ppm
               =  0.001 x 120.8X 15.43/49.4  =  0.038gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Water soluble sul fates
As S04=
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
249. 9a
1.0
1.4
0.9
120.8
13.7
N/A
N/A
N/A
, Concentration,
mg/m
178.5
0.7
1.0
0.6
86.3
9.8



gr/dscf
0.078
0.0003
0.0004
0.0003
0.038
0.004



ppm



32
2



 Acetone rinse contaminated with  oil

-------
                                                             FIELD  DATA
CO
OJ
CO
PLANT REPUBLIC STEEL CLEVELAND
SAMPLING LOCATION OUTLET STACK
SAMPLE TYPE PART/H2S04/S02
OPERATOR 8RUFFEY
AMBIENT TEMP. (DEG.F) 28.
BAR. PRESS. (IN. MS) 29.51
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBEH(S) 3530050
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .000 CFM 9 5.0 IN.HG
METER CALIB. FACTOR 1.004
READ ft RECORD DATA EVERY 10.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY ORIFICE PRESSURE STACK
POINT TIME TIME READING MEAD DIFFERENTIAL TEMP
NO. (MIN.J (24-HR ICU.FT.) (IN.H20) (IN.H20) (DEG.F)

INIT 0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
\>uu\«™ /
1308
1318
1328
1338
1348
1358
1408
1418
1428
1438
1448
1458
1508
DESIRED
423.038
427.790
433.075
438.330
443.500
448.300
452.740
457.880
463.160
468.020
473.010
478.050
482.903

.060
.067
.068
.061
.065
.064
.066
.068
.060
.064
.064
.061

.73
.88
.90
.74
.70
.80
.85
.89
.73
.80
.80
.74
ACTUAL

.73
.88
.90
.74
.70
.80
.85
.09
.73
.80
.80
.74
DATE 12/10/81
RUN NUMBER 02-2
PROBE LENGTH ft TYPE 4' HEATED GLASS
NOZZLE : 1.0. .4UO
ASSUMED MOISTURE 14.0
SAMPLE BOX NUMBER 0
METER BOX NUMBER FBI
METER HEAD DIFF. 1.71
C FACTOR .84
PRUBE HEATER SETTING 250.
HEATER BOX SETTING 250.
REFERENCE PRESS. DIFF. .14
DRY GAS METER PUMP SAMPLE IMPINGER
TEMP VACUUM BOX TEMP TEMP
(DEG.F) (IN.HG) (OEG.F) (DEG.F)
INLET OUTLET

500.
481.
489.
478.
491.
505.
465.
476.
491.
173.
488.
496.

39.
03.
46.
46.
46.
46.
46.
46.
46.
47.
46.
46.

35.
36.
36.
36.
35.
35.
35.
36.
36.
36.
35.
35.

1.5
2.0
2.0
2.U
2.0
3.0
3.0
3.5
4.0
4.0
4.5
4.5

223.
200.
210.
199.
220.
232.
218.
230.
240.
246.
252.
265.

35.
36.
38.
39.
37.
40.
34.
35.
36.
40.
40.
40.
    TOTALS
    AVERAGE
120.0
59.865
                                          .80
                                .80    486.
45,
36.
3.0   229.
38.

-------
           PARTICIPATE FIELD DATA a RESULTS TABULATION



PLANT- NAME AND ADDRESS               TEST TEAM LEADER



REPUBLIC STEEL CLEVELAND              BHUFFEY
TEST   DZ-Z
OUTLET STACK

TEST DATE
TB
TF
TT
NP
Y
ON
CP
PM
W V"
^P
TM
VMSTD
VLC
VNC
BNO
FMD
PC02
POZ
PCO
PNZ
MD
MNS


TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRV GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL HZO COLLECTED IN
IMPIN6ERS AND SILICA GEL, ML.
VOLUME OF HATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL., DRY
PERCENT 02 BY VOL., DRY
PERCENT CO BY VOL., DRY
PERCENT NZ BY VOL., DRY
MOLECULAR HT-ORY STACK GAS
MOLECULAR MT-STACK GAS
ENGLISH UNITS
12/10/61
1308
1508
120.0
12
1.004
.400 IN
.84
.80 IN-HZO
59.865 CU-FT
40.4 F
62.678 SCF
181.9
8.562 SCF
12.02
.880
4.30
12.30
.00
83.40
29.18
27.84
METRIC UNITS
12/10/81
1308
1508
120.0
12
1.004
10.2 MM
.84
20.2 PM-HZO
1.695 CU-M
4.7 C
1.775 SCM
181.9
.242 SCC
12.02
.880
4.30
12.30
.00
83.40
29.18
27.84

-------
     PB




     PSI




     PS



     TS




     VS




     AS



     033TO




     OS




     ISO



     UN






     cs



     PMR
 BAROMETRIC PRESSURE



 STATIC PRES OF STACK GAS



 STACK PRES, ABS.




 AVERAGE STACK TEMP



 AVG STACK GAS VELOCITY




 STACK AREA




 STACK FLOW RATE* DRY*



 ACTUAL STACK FLOW RATE




 PERCENT ISOKINETIC






   M6. EPA 5










   EMISSION RATE




DEG f,  29.92 IN.HG.
     29. 51  IN-HG




     -1.20  IN-H20




     29.42  IN-HG




    466.    F




     19.5   FPS




   74bb.   SO-IN




1759182.    SCFH




3643425.    ACFH




    105.9




       .0000






       .00000 GR/DSCF*




       .00000 LB/HR
   749.55  f»M-HG




   -30.48  *M-H20




   747.31  MM-MG




   252.    C




     5.9   HPS




     4.817 30-M




 49815.    SCMH




103171.    ACMM




   105.9




      .0000






      .0000 MG/OSCM




      .000 KG/HR
U>

-------
             EXAMPLE  PARTICULATE CALCULATIONS TEST NO.  02-2

                  OUTLET STACK



       VOLUME OF  DRY  GAS SAMPLED AT STANDARD CONDITIONS

       VMSTO  * (17.647  • VM * Y • (PB * PM / 13.6)) / (TM * 460.)

                 17.647 •    59.865 * 1.004 * (  29.51 *  .797 / 13.6)
       VMSTO  » ————— ——————— —	.	=     62.678 OSCF
                                (  40. » 460.)



       VOLUME OF  NATER  VAPOR AT STANDARD CONDITIONS

       VNC  *  .04707 • VLC

       VNC  *  .04707 •   182. *   8.56 SCF



       PERCENT MOISTURE IN  STACK GAS

       BNO  »  (100. •  VNC) / (VMSTD  » VNC)

^.                100. •  8.56
7      BNO  «  —	———	...... c  12.02  PERCENT
U)                 62.678 »   8.56



       MOLE FRACTION  OF DRY STACK GAS

       FMO  *  (100. >  BNO) / 100.

                 100. .  12.0
       FMO  •  ————— ——— «   .880
                     100.



       AVERAGE MOLECULAR NEIGHT OF  DRY STACK GAS

       MD * (PC02 * .44)  »  (P02 * .32) * (PN2 *  PCO)  * .28

       MO * (  4.30*44/100)  «• (12.3*32/100)  » ((83.4+  .0)  * 28/100 =    29.18



       MOLECULAR  NEIGHT OF  STACK GAS

       MNS  *  MO *  (1. > (BNO/100))  * 18. *  (BNO/100)

       MNS  *   29.18*  (1.  •(12.02/100)) * 18. *  (12.02/100) *   27.84

-------
      STACK GAS VELOCITY AT STACK CONDITIONS


      OELP * SUM. OF THE SORT(VH *  (TS » 460.))


      VS « 85.49 * CP • OELP /  (SQRT(MNS • PS) * PNTS)


      VS « 85.49 *  .64 •   93.346  /  (SORM 87.84 * 39.42)  *   12. »    19.52 FPS





      STACK GAS VOLUMETRIC FLON AT  STACK CONDITIONS


      OS * VS * AS * 3600/144


      OS «   19.52 «  1466. 3600/144  s    3643425. ACFH





      STACK GAS VOLUMETRIC FLON AT  STANDARD CONDITIONS


      OSSTO « 17.647 * OS * P3 • (1.  • (BNO/100)) / (TS * 460.)


               17.647 *    3645425.  *  29.42 • (1. • (12.02/100))

      OSSTO *	——	•	—	»     1759182. 3CFH

                        ( 486. » 460.)




>
 I     PERCENT I30KINETIC
u>

£     ISO • (305.58*(T3+460.))«((0.002669«VLC)+(VM*Y*(P8+(PM/13.6))/(TM»460.)))/(TT«VS*PS«DN*DN)


            (305.58M 486.+460.))*((0.002669*  182.)+(   59.865*1.004*( 29.51+(    .797/13.6))/(   40.+460.)))
      j30 . .....	..	....	...	.	.	...	.	s  105.85 PERCENT

                                        120. *     19.52 *   29.42 *   .400 *  .400





      PARTICIPATE LOADING — EPA METHOD 5 (AT STANDARD CONDITIONS)


      CS » 0.001 • MN • 15.43 / VMSTO


      CS « 0.001 *       .0000 * 15.43 /    62.678 s       .00000 GR/DSCF





      PARTICULATE LBS/HR — EPA METHOD 5


      PMR • CS * OSSTD / (15.43 * 453.6)


      PMR *       .00000 *    1759182. / (15.43 * 453.6) *      .00000

-------
Run No. D2.2
                          3
     Sample volume  =  1.78m r 62.68 scf
Example  calculations
     CS  (Part)  =38.3/1.78 =21.5  mg/m3
     CS  (Part)  =  0.001 x38.3  x 15.43/62.68  =0.009   qr/dscf
     CS  (S02)   = 159.4*1.78= 89.6 ma/m3
               = 89.6 x 24.067 64 =34  pom
               =  0.001 x159.4x 15.43/_6Z^8_ = 0.039  gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Water soluble sul fates
As S04=
Sulfur dioxide
Sul f uric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
38.3
24.6
2.6
3.5
2.0
159.4
14.4*
N/A
N/A
N/A
3 Concentration,
mg/m
21.5
13.8
1.5
2.0
1.1
89.6
8.1



gr/dscf
0.009
0.006
0.001
0.001
0.001
0.039
0.004



ppm



34
2



*Field analysis.
                                  A-343

-------
                                                          FIELD  DATA
          PLANT
          SAMPLING LOCATION

          SAMPLE TYPE
          OPERATOR
          AMBIENT TEMP.(OEG.F)
          BAR.PRESS.(IN.HG)
          STATIC PRESS.(IN.H20)
          FILTER NUMBER(S)
          STACK INSIDE  DIM.(IN)
          PITOT TUBE COEFF.
          THERM. NO.
          LEAKAGE
          METER CALIB.  FACTOR
                     REPUBLIC STEEL CLEVELAND OHIO
                     STACK OUTLET *t BATTERY

                     PART/H2S04/S02
                     DAN FITZGERALD
                      20.
                     29. 51
                     -1.20
                     3530341
                       97.75    .00
                       .81
                     133
                      .000 CFM a  6.5 IN.HG
                      .982
                                                          DATE
                                                          NUN NUMBER

                                                          PMOBE LENGTH ft  TYPE
                                                          NUZZLE      :  1.0.
                                                          ASSUMED MOISTURE
                                                          SAMPLE BOX NUMBER
                                                          PETER BOX NUMBER
                                                          METER HEAD OIFF.

                                                          PROBE HEATER SETTING
                                                          HEATER BOX SETTING

                                                          K FACTOR
                                                                            12/iu/ai
                                                                              02-3

                                                                            4  FOOT GLASS
                                                                             .404
                                                                            13.7

                                                                            FB6
                                                                            1.91

                                                                            350.
                                                                            350.

                                                                          12337.4
          READ ft RECORD DATA EVERY 10.0 MINUTES
    TRAVERSE
     POINT
      NO.
SAMPLE  CLOCK
 TIME    TIME
(MIN.) (20-HR
        CLOCK)
GAS METER  VELOCITY  ORIFICE PRESSURE  STACK
 READING     HEAD      DIFFERENTIAL     TEPP
 (CU.FT.)  (IN.H20)     (IN.H20)      (DEG.F)

                     DESIRED   ACTUAL
                                DRY GAS METER  PUMP    SAMPLE
                                    TEMP      VACUUM  BOX TEMP
                                   (DEG.F)    (IN.HG) (UEG.F)
                                                                                        IMPINGER
                                                                                          TEMP
                                                                                        (DEG.F)
                                                                              INLET   OUTLET
     1NIT
co
  TOTALS
  AVERAGE
  0
 10.0
 20.0
 30.0
 40.0
 50.0
 60.0
 70.0
 80.0
 90.0
100.0
110.0
120.0

120.0
1310
1320
1330
1340
1350
1400
1410
1420
1430
1440
1450
1500
1510
  695.528
  700.300
  705.335
  710.200
  714.650
  720.000
  725.200
  729.600
  734.600
  740.100
  744.200
  749.600
  754.460

   58.932
.060
,067
.068
.061
.065
.064
.066
.068
,060
.064
.063
.062
.77
.88
.88
.60
.84
.85
.84
.89
.79
.84
.82
.80
                                         .83
.77
.88
.88
.80
.84
.85
.84
.89
.79
.84
.82
.80
                                          .83
500.
481.
489.
478.
491.
465.
505.
476.
491.
474.
488.
496.
                                        486.
36.
41.
44.
45.
45.
45.
45.
45.
45.
45.
45.
45.
                                  44.
35,
35.
35.
35.
35.
35.
35.
35.
35.
35,
35.
35.
                                35.
2.5
.0
.0
.0
.0
.0
.0
.0
.0
.0
.5
.5
360.
363.
361.
366.
370.
373.
361.
334.
377.
367.
363.
365.
                               4.8   363.
37.
39.
40.
40.
37.
40.
40.
54.
60.
55.
55.
55.
                                           46.

-------
           PARTICULATE FIELD DATA ft RESULTS TABULATION




PLANT* NAME AND ADDRESS               TEST TEAM LEADER




REPUBLIC STEEL CLEVELAND OHIO         DAN FITZGERALD
TEST   D2-3
STACK OUTLET HI BATTERY


TEST DATE
TB
TF
TT
NP
Y
ON
CP
PM
1
to VM
(ji ...
TM
VMSTD
VLC
VMC
BMO
FMO
PC02
P02
PCO
PN2
MD
MMS
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRV GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H20 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF NATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL., DRY
PERCENT 02 BY VOL., DRY
PERCENT CO BY VOL., DRY
PERCENT N2 BY VOL., DRY
MOLECULAR MT-ORY STACK GAS
MOLECULAR XT-STACK GAS
ENGLISH UNITS
12/10/61
1310
1510
120.0
12
.962
.404 IN
.84
.83 IN-H20
58.932 CU-FT
39.4 F
60.470 SCF
180.6
8.501 SCF
12.33
.677
4.30
12.30
.00
83.40
29.18
27.80
METRIC UNITS
12/10/61
1310
1510
120.0
12
.982
10.3
.84
21.2
1.669
4.1
1.712
180.6
.241
12.33
.877
4.30
12.30
.00
83.40
29.18
27.60



MM

PM-H20
CU-M
c
SCK

SCK









-------
     PB




     PSI




     PS




     TS




     VS




     AS




     OSSTD




     OS




     ISO




     MN






     CS




     PMR
BAROMETRIC PRESSURE



STATIC PRES Of STACK GAS




STACK PRES, ABS.




AVERAGE STACK TEMP




AVG STACK GAS VELOCITY




STACK AREA



STACK FLOM RATE, DRY*



ACTUAL STACK FLO* RATE




PERCENT ISOKINETIC






  MG. EPA 5
     84.51  IM-HG




     -1.20  IN-H20




     29.42  IN-HG



    466.    F




     19.5   FPS



   T505.   SO-IN




1763133.    SCFH



3664702.    ACFH



    100.4




       .0000






       .00000 GR/DSCF*



       .00000 LB/HR
                 EMISSION RATE



        *  66 DEC F,  29.92 IN.HG.
   749.55  KM-HG




   •30.48  PM-H20




   747.31  KM-HG




   252.    C




     6.0   I* PS




     4.842 SQ-M




 49927.    SCKH




103773.    ACPH




   100.4




      .0000






      .0000 MG/DSCM




      .000 KG/HR
U)

-------
      EXAMPLE PARTICIPATE CALCULATIONS  TEST  NO.   02-3

           STACK OUTLET *1 BATTERY




VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

VM9TD «  (17.647 * VM * Y * (PB  * PM  / 13.6))  /  (TM  «• 460.)

          17.647 •    56.932 *  .962 •  (  29.51  +  .633  /  13.6)
VMSTD » .......-....— — — .-——-	—............	.  i      60.470  OSCF
                         I  39. * ObO.)




VOLUME OF HATER VAPOR AT STANDARD CONDITIONS

VHC « .04707 • VLC

VHC • .04707 *  161. =   6.50 SCF




PERCENT MOISTURE IN STACK GAS

BWO • (100. * VMC) / (VMSTD * VHC)

          100. *   8.50
SMO « ——.	... * 12.33  PERCENT
            60.470 *   6.50




MOLE FRACTION OF DRY STACK GAS

FMD * (100. > BNO) I 100.

          100. *  12.3
FMD s ——	.....	..... *   .877
               100.




AVERAGE MOLECULAR WEIGHT OF DRV STACK GAS

MD • (PC02 * .44) * (P02 * .32) » (PN2 * PCD) • .26

MD * ( 4.30*44/100) «• (12.3*32/100) * ((83.4* .0) * 26/100 =   29.18




MOLECULAR HEIGHT OF STACK GAS

MHS s MD * (1. > (BHO/100)) » 18. *  (BHO/100)

MN3 *  29.18* (1. '(12.33/100)) » 18. * (12.33/100) s   27.60

-------
       STACK GAS VELOCITY AT STACK CONDITIONS

       DELP * SUM. OF THE SQRMVH * (TS + 460.))

       VS • 85.49 * CP • DELP / (SORT(MnS *  PS)  *  PNTS)

       VS « 85.49 •  .84 •   93.354 /  (SORT ( 27.80 *  29.43)   *   \Z.  =   19.53 FPS




       STACK GAS VOLUMETRIC  FLOW AT STACK CONDITIONS

       OS * VS • AS • 3600/144

       OS »   14.53 *  7505. 3600/144  a    3664702. ACFH




       STACK GAS VOLUMETRIC  FLON AT STANDARD CONDITIONS

       OSSTO « 17.647 • OS • PS * (1.  - (BWO/100)) /  (TS *  460.)

                 17.647 •    3664702.  *  29.42 *  (1.  - (12.33/100))
       OS8TD •	•	——	=    1763133.  SCFH
                          (  486. * 460.)



>
^      PERCENT ISOKINETIC

GO      ISO * (305.58*(TS»460.))*((0.002669*VLC)*(VM*Y*(PB»(PH/13.6))/(TM»460.)))/(TT*VS*PS*DN*ON)

              (305.58*( 486.+460.))*((0.002669*   181.)*(   58.932*  .982*(  29.51t(    .833/13.6))/(  39.+460.)))
       ISO * ———————-——.—- ————-—-- — -- ——..................................—....... s 100.40 PERCENT
                                          120. *      19.53  *    29.42 *   .404 •  .404




       PARTICULATE LOADING — EPA METHOD  5 (AT STANDARD  CONDITIONS)

       CS * 0.001 * MN * 15.43 / VMSTD

       CS » 0.001 *       .0000 * 15.43 /    60.470 =       .00000  GR/DSCF




       PARTICULATE LBS/HR -- EPA METHOD 5

       PMR « CS * QSSTD / (15.43 * 453.6)

       PMR s       .00000 *     1763133. / (15.43  * 453.6) =      .00000

-------
Run No.02.3
                           o
     Sample volume = 1.71  m .60.47  scf

Example calculations

     CS (Part)  =34.8 /I.71  .  20.4  mq/m3


     CS (Part)  = 0.001  x  34.8 x  15.43/60.47  =  0.009  qr/dscf

     CS (S02)   =155.0/1.71  =  90.6 ma/m3

               = 90.6 x 24.06/64  = 34 ppm

               = 0.001  xl55.0 x  15.43/60.47  = Q.Q4Q gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sulfates
As H2S04
As H2S04.2H20
Water soluble sulfates
As S04=
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
34.8
0.6
0.8
3.5
155.0
8.7
N/A
N/A
N/A
3 Concentration,
mg/m
20.4
0.3
0.5
2.0
90.6
5.1



gr/dscf
0.009
0.0001
0.0001
0.001
0.040
0.002



ppm



34
1



                                   A-349

-------
                                                              FIELD  DATA
I
CO
Ul
o
PLANT REPUBLIC STEEL
SAMPLING LOCATION STACK OUTLET #1
SAMPLE TYPE PART/HeSD4/SU2
OPERATOR DAN FITZGERALD
AMBIENT TEMP.(OEG.F) 20.
BAR. PRESS. (IN.HG) 29.51
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530311
STACK INSIDE DIM. (IN) 97.75 .00
PITOT TUBE COEFF. .84
THERM. NO. 133
LEAKAGE .000 CFM a 6.
METER CALIB. FACTOR 1.033
READ & RECORD DATA
TRAVERSE
POINT
NO.

INIT












SAMPLE
TIME
(MIN.)

0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
CLOCK
TIME
(24-HR

1312
1322
1332
1342
1352
1402
1412
1422
1432
1442
1452
1502
1512
EVERY 10.0
GAS METkR
READING
(CU.FT.)

253.209
257.945
262.940
268.415
273.160
277.600
282.600
287.500
293.800
297.800
302.900
307.600
312.205
MINUTES
VELOCITY
HEAD
(IN.H20)


.060
.067
.068
.061
.065
.064
.066
.068
.060
.064
.063
.062
CLEVELAND OHIO
BATTERY
0 IN.HG

ORIFICE

PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.77
.88
.88
.80
.84
.85
.84
.89
.79
.84
.82
.80
H20)
ACTUAL

.77
.88
.88
.80
.84
.85
.84
.89
.79
.84
.82
.80

STACK
TEPP
(DEG.F)


500.
481.
489.
478.
491.
465.
505.
476.
491.
474.
488.
496.
DATE 12/10/A1
HUN NUMBER 02-4
PROBE LENGTH 8 TYPE 4 FOOT GLASS
NOZZLE : I.D. .404
ASSUMED MOISTURE 13.7
SAMPLE BOX NUMBER
PETEK BOX NUMBER FB4
PETEN HEAD DIFF. 1.88
PROBE HEATER SETTING 350.
HEATER BUX SETTING 350.
K FACTOR 12337.4

DRY GAS METER
TEMP
(OEG.F)
INLET OUTLET

40. 40.
42. 40.
45. 38.
46. 39.
47. 39.
48. 39.
48. 39.
48. 39.
48. 39.
48. 39.
48. 39.
48. 39.

PUMP
VACUUM
(IN.HG)


2.5
3.0
3.0
3.0
4.5
4.5
4.5
5.0
5.0
5.0
5.0
5.5

SAMPLE
BOX TEMP
(DEG.F)


400.
405.
389.
395.
387.
388.
373.
373.
396.
381.
370.
385.

IMPINGER
TEMP
(DEG.F)


42.
40.
39.
40.
41.
40.
56.
54.
64.
60.
60.
60.
     TOTALS
     AVERAGE
120.0
58.996
                                          .83
                                .83    486.
46.
39.
4.2   387.
50.

-------
           PARTICIPATE FIELD DATA ft RESULTS TABULATION
PLANT- NAME AND ADDRESS               TEST TEAM LEADER
REPUBLIC STEEL CLEVELAND OHIO         DAN FITZGERALD
TEST   D2-4
STACK OUTLET HI BATTERY


TEST DATE
TB
TF
TT
NP
Y
DN
CP
PM
U) UM
Ul
TM
VMSTO
VLC
VNC
BNO
FMD
PC02
P02
PCO
PN2
MO
MNS
TIME-START
TIME-FINISM
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H20 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF NATER VAPUR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL., DRY
PERCENT 02 BY VOL., DRY
PERCENT CO BY VOL., DRY
PERCENT N2 BY VOL., DRY
MOLECULAR NT-DRY STACK GAS
MOLECULAR NT-STACK GAS
ENGLISH UNITS
12/10/81
1312
1512
120.0
12
1.033
.404 IN
.84
.83 IN-H20
58.996 CU-FT
42.7 F
63.263 SCF
184.6
8.689 SCF
12.08
.879
4.30
12.30
.00
83.40
29.18
27.83
METRIC UNITS
12/10/81
1312
1512
120.0
12
1.033
10.3
.84
at. a
1.671
5.9
1.791
184.6
.246
12.08
.879
4.30
12.30
.00
83.40
29.18
27.83



I'M

MM-H20
CU-M
C
SCK

3CM









-------
     PB

     P3I

     PS

     T3


     VS

     AS

     Q33TO


     OS

     ISO

     MN



     cs

     PMR
BAROMETRIC PRESSURE

STATIC PRES OF STACK GAS

3TACK PRES, ABS.

AVERAGE STACK TEMP

AVG STACK GAS VELOCITY

STACK AREA

STACK FLOW RATE, DRY*

ACTUAL STACK FLOW RATE

PERCENT 1SOK1NETIC



  MG. EPA 5
                 EMISSION RATE

        *  6B DEG F,  29.« IN.HG.
     29.51  1N-HG


     •1.20  1N-H20


     29.43  IN-HG


    086.    r


     19.5   FPS


   7505.   30-IN


1767255.    SCFH


3662869.    ACFH


    104.B


       .0000



       .00000 GR/OSCF*


       .00000 LB/HR
   7Q9.55  HM-HG


   -30.06  MM-M20


   747.31  KM-HG


   252.    C


     6.0   fPS


     0.812 30-M


 50003.    SCMH


103721.    ACMM


   104.B


      .0000



      .0000 MG/D3CM


      .000 KG/HR
co
01

-------
               EXAMPLE PARTICIPATE CALCULATIONS TEST NO.  02-4

                    STACK OUTLET «1 BATTERY



         VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

         VMSTD * (17.647 • VM • 1 • (P8 * PM / 13. 6)) /  (TM + 460.)

                   17.647 •    58.996 * 1.033 • ( 29.51  +  .833 / 13.6)
         VMSTD • — — — --- - --------------- - ------------------------ =     63.263 OSCF
                                  (  43. * 460.)



         VOLUME OF MATER VAPOR AT STANDARD CONDITIONS

         VMC e .04707 * VLC

         VNC « .04707 •  185. *   8.69 SCF



         PERCENT MOISTURE IN STACK GAS

         BMO « (100. • VMC) / (VMSTO * VWC)

                   100. *   8.69
         BMO « — — — --- ..... ---------- - s 12.08 PERCENT
jp                    63.263 *   8.69
 I
l_r.-
Ul
W        MOLE FRACTION OF DRY STACK GAS

         FMD * (100. - BMO) / 100.

                   100. -  12.1
         FMD * ————————— *   .879
                        100.
         AVERAGE MOLECULAR MEIGHT OF DRY STACK GAS

         MD  • (PC02 * .44) * (P02 * .32) * (PN2 » PCO) * .28

         MD  = (  4.30*44/100) » (12.3*32/100)  * ((83. 4* .0) * 26/100 =   29.18



         MOLECULAR  MEIGHT OF STACK GAS

         MHS a MO * (1.  - (BNO/100)) * 18. *  (BNU/100)

         MMS *  29.18*  (1. -(12.08/100)) * 18. * (12.08/100) s   27.63

-------
       STACK GAS VELOCITY AT STACK CONDITIONS

       DELP * SUM. OF THE SURHVH * (TS «• 460.))

       VS « 85.49 * CP • DELP / (SORT(MWS * PS) * PNTS)

       VS « 85.49 *  .84 *   93.354 / (SORT( 27.83 * 29.42)  *  12. =   19.52 FPS




       STACK GAS VOLUMETRIC FLON AT STACK CONDITIONS

       US * VS * AS • 3600/144

       QS »   19.52 *  7505. 3600/144 a    3662869. ACFH




       STACK GAS VOLUMETRIC FLON AT STANDARD CONDITIONS

       QSSTD * 17.647 * OS * PS * (1. • (BMO/100)) / (TS » 460.)

                 17.647 *    3662869. *  29.42 *  (1. • (12.08/100))
       OSSTO « —	———	a    1767255. SCFH
                          ( 486. * 460.)




,p     PERCENT ISOKINETIC

U>     ISO » (305.5B*(TS+460.))*((».002669«VLC)»(VM*Y*(PB»(PM/13.6))/(TM*460.)))/(TT*V8«PS*DN*DN)
(Ji
^            (305.5B*( 486.*460.))*((0.002669*  185.)*(   58.996*1.033*( 29.51*(    .833/13.6))/(  43.«460.)))
       ISO « ————————————————[[[ 3  104.79  PERCENT
                                          120. *     19.52 •   29.42 *  .404 *  .4V4




       PARTICIPATE LOADING — EPA METHOD 5 (AT STANDARD CONDITIONS)

       CS • 0.001 * MN • 15.43 / VM3TD

       CS « 0.001 *       .0000 * 15.43 /    63.263 >       .00000 GR/DSCF




       PARTICULATE LBS/HR — EPA METHOD 5

       PMH * CS * QSSTD / (15.43 * 453.6)


-------
Run No.  D2.4
     Sample volume = 1.79  m T 63.26  scf
Example calculations
     CS (Part)  =37.2/1.79  = 20.8  mg/m3
     CS (Part)  = 0.001  x 37.2 x  15.43/63.26 = 0.009  qr/dscf
     CS (S02)   =131.8/1.79  =73.6 mg/m3
               = 73.6 x 24.06/64  = 28 pom
               = 0.001  x 131.8x  15.43/62x2fi_BOa2. gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sulfates
As H2S04
As H2S04-2H20
Water soluble sulfates
As S04=
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
37.2
0.4
0.5
4.8
131.8
54.8
N/A
N/A
N/A
3 Concentration,
mg/m
20.8
0.2
0.3
2.7
73.6
30.6



gr/dscf
0.009
0.0001
0.0001
0.001
0.032
0.013



ppm



28
8



                                    A-355

-------
                                                              FltlO  DATA
U)
01
PLANT REPUBLIC STEEL
SAMPLING LOCATION COKE STACK
SAMPLE TYPE M5-250
OPERATOR DU
AMBIENT TEMP. (DEG.F) 28.
BAR. PRESS. (IN. HG) 29.51
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBERtS) 3530003
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .83
THERM. NO.
LEAKAGE .000 CFM 0 3.
METER CAL1B. FACTOR .992
READ ft RECORD DATA
TRAVERSE
POINT
NO.

INIT












SAMPLE
TIME
(MIN.)

0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
CLOCK
TIME
(24-HR
PI nr * \
IIUCK I
1310
1320
1330
1340
1350
1400
1410
1420
1430
1440
1450
IbUO
1510
EVERY 10.0
GAS METER
READING
(CU.FT.)

925.417
931.070
936.220
941.400
946.600
951.860
957.100
962.320
967.550
972.810
978.100
983.320
988.572
MINUTES
VELOCITY
HEAD
(IN.H20)


.060
.060
.060
.060
.060
.060
.060
.060
.060
.060
.060
.060
CLEVELAND
0 IN.HG

ORIFICE

PRESSURE

STACK
DIFFERENTIAL TE^P
(IN.
DESIRED

.89
.89
.89
.89
.89
.09
.89
.89
.89
.89
.89
.89
H20)
ACTUAL

.89
.89
.89
.89
.89
.89
.89
.89
.89
.89
.89
.89
(OEG.F)


501.
481.
489.
478.
491.
505.
465.
477.
491.
474.
488.
496.
OATE 12/10/81
RUN NUMBER D2-5
PROBE LENGTH S TYPE 6* GLASS
N02ZLE : 1.0. .431
ASSUMED MOISTURE 13.7
SAMPLE BUX NUMBER
ME1EH BOX NUMBER FBI
METER HEAD DIFF. i.«7
C FACTOR .71
PROBE HEATER SETTING 250.
HEATER BUX SETTING 250.
REFERENCE PRESS. DIFF. .12

DRY GAS METER
TEMP
(DEG.F)
INLET OUTLET

43. 36.
43. 35.
46. 36.
49. 36.
52. 37.
54. 3».
55. 39.
55. 39.
55. 39.
55. 40.
55. 40.
55. 40.

PUMP
VACUUM
(1N.H8)


2.0
2.0
2.0
2.1
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2

SAMPLE
BOX TEMP
(DEG.F)


268.
253.
193.
258.
318.
268.
268.
247.
291.
249.
218.
270.

IMPINGER
TEMP
(DEG.F)


3«.
34.
33.
35.
35.
35.
34.
34.
38.
38.
37.
37.
     TOTALS
     AVERAGE
120.0
63.155
                                          .89
                                .89    486.
51.
38.
2.1
                                                                                         258.
35.

-------
           PARTICIPATE  FIELD  DATA  a  RESULTS  TABULATION

PLANT- NAME AND  ADDRESS               TEST  TEAM LEADER

REPUBLIC STEEL CLEVELAND               DU
TEST   D2-5
COKE STACK


TEST DATE
TB
TF
TT
NP
Y
DN
CP
PM
1 VM
OJ
cn
~J TM
VMSTD
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
ENGLISH UNITS
12/10/81
1310
1510
120. 0
12
.992
.431 IN
.63
.69 IN-H20
63.155 CU-FT
44.7 F
64.791 SCF
METRIC UNITS
12/10/81
1310
1510
120.0
12
.992
10.9
.83
22.6
1.788
7.0
1.835



CM

KM-M20
CU-M
C
SCK
          AT STANDARD CONDITIONS*

VLC       TOTAL H20 COLLECTED IN
          IMPINGERS AND SILICA GEL,ML,

VMC       VOLUME OF WATER VAPOR
          AT STANDARD CONDITIONS*

BWO       PERCENT MOISTURE BY VOLUME

FMO       MOLE FRACTION DRY GAS

PC02      PERCENT C02 BY VOL.* DRY

P02       PERCENT 02 BY VOL.. DRV

PCO       PERCENT CO BY VOL., DRY

PN2       PERCENT N2 BY VOL.. DHY

MD        MOLECULAR hT-ORY STACK GAS

MMS       MOLECULAR WT-STACK GAS
                          190.7
                            8.976 SCF
190.7
   .251 SCI*
12.17
.878
4.30
12.30
.00
63.40
29.18
27.82
12.17
.878
4.30
12.30
.00
83.40
29.18
27.82

-------
     Pb

     PSI

     PS

     TS

     vs

     AS

     OSSTO

     OS

     ISO

     MN


     cs

     PHR
BAROMETRIC PKESSUHE

STATIC PRES OF STACK GAS

STACK PRESr ABS.

AVERAGE STACK TEMP

AV6 STACK 6AS VELOCITY

STACK AREA

STACK FLO* HATE* DHt*

ACTUAL STACK FLOW RATE

PERCENT ISOKINETIC



  MG. EPA 5
     29.51  IN-HG

     •1.20  IN-H20

     29.02  IN-HG

    066.    F

     18.7   FPS

   7066.   SO-1N

1680969.    SCFH
3488292.


     98.6

       .0000
ACFH
                                   .00000 GR/DSCF*

                                   .00000 LB/HR
  709.55  CM-HG

  •50.08  I»l»i-H20

  707.31  KM-HG

  252.    C

    5.7   CPS

    0.817 SO-M

07bOO.    SCCH

98778.    ACI»H

   98.6

     .0000


     .0000 MG/DSCH

     .000 KG/Hfi
                 EMISSION RATE

        *  68 DEG Ft  29.92 IN.HG.
U)
Ul
00

-------
              EXAMPLE PARTICULATE CALCULATIONS TEST NU.  02-5

                   COKE STACK



        VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

        VMSTD = (17.607 • VM * Y * (PB » PM / 13.6)) /  (TM » 060.)

                  17.647 •    63.155 •  .99? * ( 39.51  »  .890 /  13.6)
        VMSTD = ——.——. — — — — — — — ———.. — .. — . —  s      60.791  DSCF
                                 I  05. * 060.)



        VOLUME OF HATER VAPOR AT STANDARD CONDITIONS

        VHC  = .00707  * VLC

        VHC  = .00707  •  191. s   8.98 SCF



        PERCENT  MOISTURE IN  STACK GAS

        BNO  = (100. * VHC) / (VMSTD » VHC)

•p                 100. «   8.98
I       8HO  = --— — — — --- - ------- --- =  12.17 PERCENT
U)                  60.791 »   8.V8
ID
       MOLE FRACTION  OF  DRY  STACK  GAS

       FMD =  (100.  -  8*0)  /  100.

                  100.  -   12.3
       FMD =  — — — — — ---- — ---- =   .878
                       100.
       AVERAGE MOLECULAR  HEIGHT  OF  DRV  STACK GAS

       HD =  (PC02  *  .00)  *  (P02  *  .32)  *  (PN2 * PCO) • .28

       MD =  ( 0.30*00/100)  «•  (12.3*32/100)  » ((83. 0* .0)  * 28/100 =   29.18



       MOLECULAR HEIGHT OF  STACK  GAS

       MHS = MD *  (1. - (BWU/10U))  +  18.  *  (8X0/100)

       MWS =  29.18*  (1.  -(12.17/100))  *  18. * (12.17/100) =   27.82

-------
   STACK GAS VELOCITY AT STACK CONDITIONS




   DELP = SUM. OF THt SURT(VH • ITS + 060.))




   VS = 85.49 * CP * DELP / (SOHT(MNS * PS) • PNTS)



   VS = 85.49 •  .83 •   90.421 / ISQHT( 27.88 * 29.42)  •  lef. =    IB.69 FPS








   STACK GAS VOLUMETRIC FLO* AT STACK CONDITIONS



   OS = VS * AS * 3600/144



   OS =   10.69 *  7466. 3600/144 =    348B292. ACFH








   STACK GAS VOLUMETRIC FLON AT STANDARD CONDITIONS



   OSSTD = 17.647 * OS * PS * (1. - (BNU/100)) / (TS * 460.)



             17.647 *    3488292. *  29.42 *  (1. - (12.17/100))

   OSSTD = -—------—	......	....	=     1600969. SCFH

                      ( 486. + 460.)






>

I  PERCENT ISOKINETIC
Lo


O  130 = (305.58*(TS+46U.))«((0.002669*VLC)»(VM*Y*(PB»(PM/13.6))/(TM»460.)))/(TT*V3*PS*DN*ON)



          1305.58*( 486.+460.))*((0.002669*   191.)*(   63.155* ,992*( 29.51+1    .890/13.6))/(   45.«460.)))

   130 a ——.	—-—	— —	.................	....................................	...... •  98.63 PERCENT


                                      120. *     18.69 *   29.42 *   .431 *  .431








   PARTICIPATE LOADING — EPA METHOD 5 (AT STANDARD CONDITIONS)



   CS = 0.001 • MN * 15.43 / VMSTD



   CS = 0.001 *       .0000 * 15.43 /    64.791 =       .00000 GR/OSCF








   PAHTICULATE LBS/HR -- tPA METHOD 5



   PMR = CS * OSSTO / (15.43 • 453.6)



   PMR =       .00000 *    1680969. / (15.43  * 453.6) =      .00000

-------
Run No. D2-5
     Sample  volume =1.84 m3t64.79  scf
Example  calculations
     CS  (Part) =41.1 /1.84=  22.3  rnq/m3
     CS  (Part) = 0.001 x  41.1 x 15.43^4.79  =0.010  qr/dscf
     CS (S02)  =	/.
mg/nf
              =	 x 24.OS/	=	ppm
              = 0.001 x	x 15.43/	
                  gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Water soluble sul fates
As S04=
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg

41.1
23.4
19.2
18.8
17.7
15.1

0.0
0.0

0.0
N/A

N/A
152.6
0.8
8.6
3 Concentration,
mg/m

22.3
12.7
10.4
10.2
9.6
8.2

0.0
0.0

0.0



82.9
0.43
4.7
gr/dscf

0.010
0.005
0.004
0.004
0.004
0.003 .

0.000
0.000

0.000



0.036
0.0002
0.002
ppm

















                                    A-361

-------
                                                               FIELD   DATA
              PLANT
              SAMPLING LOCATION

              SAMPLE  TYPE
              OPERATOR
              AMBIENT TEMP.(OEG.F)
              BAR.PRESS.(IN.HG)
              STATIC  PRESS.(IN.H20)
              FILTER  NUMBEH(S)
              STACK INSIDE  DIM.(IN)
              PITOT TUBE COEFF.
              THERM.  NO.
              LEAKAGE
              METER CALIB.  FACTOR
                     REPUBLIC STEEL CLEVELAND
                     COKE STACK

                     M8-660
                     00
                      28.
                     39.51
                     -1.20
                     3530202
                       97. 50    .00
                       .83
                           CFM a 10.0 IN.HG
                                                DATE                      12/10/81
                                                RUN NUPBER                 02-6

                                                PROBE  LENGTH ft TYPE      5" GLASS
                                                NOZZLE      :  I.D.        .378
                                                ASSUMED  MOISTURE         13.7
                                                SAMPLE BOX NUMBER
                                                ff.1f.tt  BOX  NUMBER         FBb
                                                fETEH  hEAO DIFF.         1.51
                                                C  FACTOR                  .90
                                                PROBE  HEATER SETTING     600.
                                                HEATER BOX SETTING       600.
                                                REFERENCE  PRESS. DIFF.    .17
                      .967
              READ ft RECORD DATA EVERY  10.0 MINUTES
 I
U)
LUI. n t
1311
1321
1331
13
-------
           PARTICULATE FIELD DATA R RESULTS  TABULATION




PLANT- NAME AND ADDRESS                TEST TEAM LEADER




REPUBLIC STEEL CLEVELAND               DO
TEST   D2-6
COKE STACK
ENGLISH UNITS
TEST DATE
TB
TF
TT
NP
Y
ON
CP
PM
W VM
OJ
TM
VMSTD
VLC
VMC
BHO
FMD
PC02
P02
PCO
PN2
MD
MHS
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H20 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF HATER VAPUH
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 HY VOL., DRY
PERCENT 02 BY VOL., DRY
PERCENT CO BY VOL., DRY
PERCENT N2 BY VOL., DRY
MOLECULAR HT-ORY STACK GAS
MOLECULAR KT-STACK GAS
12/10/81
1311
1511
120.
12
.
.
.
•
58.
35.
59.
168.
7.
11.
.
4.
12.
.
83.
29.
27.
0

967
378 IN
83
63 IN-H20
333 CU-FT
8 F
317 SCF
3
922 SCF
78
882
30
30
00
no
18
86
METRIC UNITS
12/10/81
1311
1511
120.0
12
.967
9.6
.83
16.0
1.6b2
2.1
1.681
168.3
.224
11.78
.882
a. 30
12.30
.00
83. 00
29.18
27.86



PP

MM-H20
CU-M
C
SO

SCf









-------
   PB
   PS1
   PS
   TS
   VS
   AS
   QSSTD
   OS
   ISO
   MN

   cs
   PMR
BAROMETRIC PRESSURE
STATIC PRES OF STACK GAS
STACK PRES, ABS.
AVERAGE STACK TEMP
AVG STACK GAS VELOCITY
STACK AREA
STACK FLO* RATE, DRY*
ACTUAL STACK F|_0» HATE
PERCENT ISOKINETIC

  MG. EPA 5
>
cr\
               EMISSION RATE
      *  68 DEC F,  89.1)2 IN.HG.
     29.51  IN-HG
     -1.20  IN-H2U
     29.12  IN-HG
    4Bb.    F
     18.7   FPS
   7466.   SQ-IN
1687140.    SCFH
3185548.    ACFH
    117.0
       .0000

       .00000 GR/DSCF*
       .00000 LB/HR
  749.55  fM-HG
  -30.48  KH-H20
  747.31  PM-HG
  252.    C
    5.7   KPS
    4.017 SQ-M

47775.    SC^H
98700.    ACKH
  117.0
     .0000

     .0000 MG/DSCM
     .000 KG/HR

-------
              EXAMPLE PAHTICULATE CALCULATIONS  TEST  NO.   D2-6

                   COKE STACK



        VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

        VMSTD a (17.647 * VM * y * (PB * PM / 13.6)) /  (TM » 460.)

                  17.647 •    56.333 *  .967 *  ( 29.51  *  .630  /  13.6)
        VMSTD » ————...- —.... — .———.-..................-  =      59.307  DSCF
                                 (  36. + 460.)



        VOLUME OF MATER VAPOR AT STANDARD CONDITIONS

        VMC = .04707 * VLC

        VMC = .04707 *  168. r   7.92 SCF



        PERCENT MOISTURE IN STACK GAS

        BMO * (100. * VMC) / (VMSTD + VMC)

to                 100. •   7.92
I       BMO = — — ——	..._.— r 11.78 PERCENT
LO                   59.347 +   7.92

Ul


        MOLE FRACTION OF DRY STACK GAS

        FMD = (100. - BMO) / 100.

                  100. -  11.8
        FMD = —————	——--- s   .882
                       100.



        AVERAGE MOLECULAR MEIGHT OF DRY STACK GAS

        MD * (PC02 * .44) * (P02 * .32) » (PN2 * PCO) • .28

        MO s ( 4.30*44/100) » (12.3*32/100)  » ((83.a* .0) * 28/100 *   29.18



        MOLECULAR MEIGHT OF STACK GAS

        MMS s MD * (1. - (BMO/100))  «• 18.  *  (8*0/100)

        MMS =  29.16* (t. -(11.76/100)) *  18. * (11.76/100)  =   27.86

-------
        STACK  GAS  VELOCITY  AT  STACK  CONDITIONS

        DELP = SUM.  OF  THE  SClrtMVH  * ITS * . +  4bO.)


>
U)       PERCENT  ISOKINETIC
CT>
171       ISO =  (305.58*(TS*4bO.))* ( (0.002669*VLC) + (VM*Y*(PB*(PM/13.6))/(TM»460.)))/(TT*VS«PS*DN*ON)

               (305.58M 486.»460.))*((0.002669*   168.)+(   58.333* ,967*( 29.51»(    .630/13.6))/(   36.»460.)))
        ISO s  ................	.	.......	..	............	..................................... » 117.03 PERCENT
                                           120. *      18.67 *    29.42 *   .378 *  .378



        PARTICULATE  LOADING  — EPA METHOD  5 (AT STANDARD  CONDITIONS)

        CS  = 0.001  * MN * lb.43 / VMSTD

        CS  = 0.001  *       .0000  * 15.43 /    59.347 =        .00000 GR/DSCF



        PARTICULATE  LBS/HR  —  EPA METHOD 5

        PMR s  CS *  OSSTD /  (15.43 »  «53.6)

        PM« s        .00000  *    1687140. / (15.43  * 453.6)  s       .00000

-------
Run No.  D2.6
     Sample  volume =1.68  m r 59.35 scf
Example  calculations
     CS  (Part) =30.3/1.68 = 18.0  mg/m3
     CS  (Part) = 0.001  x30.3  x  15.43/59.35= 0.008 qr/dscf
     CS  (S02)  = 152.8/1.68 = 91.0 ma/m3
              = 91.0  x 24.06^4  =  34ppm
              = 0.001  x!52.8x  15.43£a*35__ = JLlMDgr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Water soluble sul fates
As S04=
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
30.3
<0.3
<0.4
<0.3
152.8
10.7



o Concentration,
mg/m
18.0
<0.2
<0.3
<0.2
91.0
6.4



gr/dscf
0.008
0.0001
0.0001
0.0001
0.040
0.003



ppm



34
2



                                   A-367

-------
                                                                FIELD  DATA
UJ
c^
00
PLANT REPUBLIC STEEL
SAMPLING LOCATION OUTLET STACK
SAMPLE TYPE PART/H2S04/S02
OPERATOR CB
AMBIENT TEMP.(OEG.F) 26.
BAR. PRESS. (IN. HG) 29.55
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530025
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .63
THERM. NO.
LEAKAGE .002 CFM S H.
METER CALIB. FACTOR 1.003
READ * RECORD DATA
TRAVERSE
POINT
NO.

1N1T













SAMPLE
TIME
(MIN.)

0
4.0
10.0
20.0
30.0
40.0
50.0
60.0
fo. o
80.0
90.0
100.0
110.0
120.0
CLOCK
TIME
(24-HR
r i rif* M \
ULUIK 9
1131
1141
1350
1400
1410
1420
1430
1440
1450
1500
1510
1520
1530
1540
EVERY 10.0
GAS METER
READING
(CU.FT.)

361.265
362.966
366.660
371.160
375.330
379.750
383.570
387.200
391.130
395.030
398.880
402.560
407.170
411.081
MINUTES
VELOCITY
HEAD
(IN.H20)


.055
.046
.049
.046
.050
.038
.035
.042
.000
.040
.043
.044
.045
CLEVELAND
0 IN.HG

ORIFICE

PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.72
.62
.64
.62
.65
.50
.46
.54
.52
.52
.56
.57
.58
H20)
ACTUAL

.72
.62
.64
.62
.65
.50
.46
.54
.52
.52
.56
.57
.5S

STACK
TECP
(DEG.F)


475.
496.
506.
470.
460.
485.
482.
500.
466.
480.
4B5.
505.
485.
DATE 12/11/81
NUN NUMBER 03-1
PWOBE LENGTH A TYPE 5* HEATEO GLASS
NOZZLE : 1.0. .401
ASSUMED KOISTUHE 14.0
SAMPLE BOX NUVBER 0
fETEH BOX NUMBER FB2
METE* HEAD DIFF. 1.76
C FACTUK .82
HRUet hfcATEk SETTING 250.
HEATER BOX SETTING 250.
KEFEHENCE PHESS. DIFF. .14

DRY GAS PblER
TECP
(DEG.F)
INLET OUTLET

35. 33.
35. 32.
35. 32.
36. 32.
40. 32.
44. 34.
46. 36.
48. 36.
48. 36.
48. 37.
48. 3B.
48. 38.
48. 30.

PUMP
VACUUM
(IN.Hb)


2.0
2.0
2.0
3.0
2.0
2.0
2.0
2.0
2.U
3.0
3.u
3.0
3.0

SAMPLE
BOX TEfP
(UEG.F)


275.
247.
269.
246.
24^.
252.
240.
250.
247.
250.
239.
230.
230.

IKP1NGEK
TEMP
(OEG.F)


0.
35.
37.
42.
46.
44.
51.
50.
4".
50.
52.
54.
54.
      TOTALS
      AVERAGE
120.0
49.816
                                          .58
                                .58
486.
43.
35.
                                                                                   2.4
                                                                      248,
                                           43.

-------
           PAHTICULATE MELO 1>ATA * RESULTS  TABULATION
PLANT* NAME ANU AOORkSS                ttST TEAM LEAUtH
REPUBLIC STtEL CLEVELAND               CB
TtST
       1)5-1
                 OUTLM  STACK
TtST DATE
TB        TIME-START
TF        TIME-FINISH ...
TT        NET TIME OF TEST, MIN.
NP        NET SAMPLING POINTS
Y         METER CALIBRATION FACTOR
ON        SAMPLING NOZZLE DIAMETER
CP        PITOT TUBE COEFFICIENT
PM        AVERAGE ORIFICE PRESSURE
          DROP
VM        VOLUME OF DRV GAS SAMPLED
          AT METER CONDITIONS
TM        AVERAGE GAS METER TEMH
VMSTO     VOLUME OF DRY GAS SAMPLED
          AT STANDARD CONDITIONS*
VLC       TOTAL M20 COLLECTED IN
          IMPINGERS AND SILICA GEL,ML.
VNC       VOLUME OF HATER VAPOR
          AT STANDARD CONDITIONS*
BNO       PERCENT MOISTURE BY VOLUME
FMD       MULE FRACTION DRY GAS
PC02      PERCENT C02 BY VOL., DRY
P02       PERCENT 02 BY VOL., DRY
PCO       PERCENT CO BY VOL., DRV
PN2       PERCENT N2 BY VOL., DRY
MO        MOLECULAR HT-DRY STACK GAS
MNS       MOLECULAR NT-STACK GAS
                                         ENULISM UNITS
                                         1131
                                                              Ht IK 1C UNI TS
                                                              1131
120.0
13
1.003
.401 IN
.83
.58 IN-H20
49.816 CU-FT
39.0 F
52.294 SCF
122.4
5.761 SCF
9.92
.901
4.00
12.00
.00
84.00
29.12
2B.02
180.0
13
1.003
10.2
.83
14.7
1.411
3.9
1.461
122.4
.163
9.92
.901
4.00
12.00
.00
84.00
29.12
28.02



MM

MM-H20
CU-M
c
sec

SCt"









-------
     PB


     P3I


     PS


     TS


     VS


     AS


     QSSTD


     OS


     ISO


     MN



     cs


     PMR
BAROMETRIC PRESSURE


STATIC PRES OF STACK GAS


STACK PRES, ABS.


AVERAGE STACK TEMP


AV6 STACK GAS VELOCITY


STACK AREA


STACK FLO* RATE, DRY*


ACTUAL STACK FLOW RATE


PERCENT ISOKINETIC



  MG. EPA 5
                 EMISSION RATE


        *  68 DEC f,  29.92 IN.HG.
     29.55  IN-HG


     -1.20  IN-H20


     29.46  IN-HG


    086.    F


     16.0   FPS


   7466.   SO-IN


1476086.    SCFH


2981939.    ACFH


    104.7


       .0000



       .00000 GR/DSCF*


       .00000 LB/HR
  750.57  KM-HG


  -30.48  KM-H20


  748.33  fM-HG


  252.    C


    4.9   UPS


    4.817 SO-M


41798.


84440.


  104.7


     .0000



     .0000 MG/OSCM


     .000 KG/HR
UJ
•J
O

-------
               EXAMPLE PARTICULATE CALCULATIONS TEST NO.  D3-1

                    OUTLET STACK



         VOLUME OF D»Y GAS SAMPLED AT STANDARD CONDITIONS

         VM8TD * (17.647 • VM • Y * (PB * PM / 13.6)) / (TM + 460.)

                   17.647 *    49.816 • 1.003 * ( 29.55 «•  .577 / 13.6)
         VMSTD » — — ----- — *— — . ------------- ....... ---------- a     52.294 03CF
                                  t  J9. » a*o.)



         VOLUME OP MATER VAPOR AT STANDARD CONDITIONS

         VMC  « .04707  * VLC

         VMC  » .04707  *  122. «   5.76 3CF



         PERCENT MOISTURE IN  STACK GAS

         BNO  « (100. * VMC)  / (VMSTD + VMC)

"f                  100. •   5.76
U)        BMO  = ————————— s   9.92 PERCENT
                    52.294 *   5.76
        MOLE FRACTION  OF  DRY  STACK  GAS

        FMD =  (100.  -  BMO)  /  100.

                   100.  -    9.9
        FMD =  — — ————— — —  =   .901
                        100.
         AVERAGE  MOLECULAR  WEIGHT  OF  DRY  STACK  GAS

         MD s  (PC02  •  .44)  *  (P02  *  .32)  *  (PN2 * PCO)  * .28

         MO •  ( 4.00*44/100)  *  (12.0*32/100)  +  ((61.0+  .0)  * 26/100 =   29.12



         MOLECULAR MEIGHT OF  STACK GAS

         MHS = MD «  (1. - (BHO/100))  *  18.  *  (BhO/100)

         MMS s  29.12*  (1.  •( 9.92/100))  »  18.  * ( 9.92/100) =   28.02

-------
STACK GAS VELOCITY AT STACK CONDITIONS

OELP * SUM. OF THE SORT(VH * (TS * 160.))

VS • 85.49 • CP * DELP / (SORMMKS * PS) * PNTS)

VS * 85.49 *  .83 *   84.090 / (SORT( 38.08 • 89.06)  *  13. =    15.98 FPS



STACK GAS VOLUMETRIC FLON AT STACK CONDITIONS

OS « VS * A3 * 3600/144

OS *   15.98 *  7466. 3600/144 =    2981939. ACFH



STACK GAS VOLUMETRIC FLOH AT STANDARD CONDITIONS

OSSTD • 17.647 • 03 * PS • (1. • (6*0/100)) / (TS * 460.)

          17.647 *    2981939. *  29.46 »(!.-( 9.92/100))
OSSTD = ----———.-.— — - — --—	..........	.. =     1476086. SCFH
                   ( 486. * 460.)




PERCENT ISOKINETIC

ISO = (305.58*(T3*460.))*((0.002669*VLC)*(V»'*Y*(PB*{PM/13.6))/(TM«.460.)))/(TT*V3*PS*DN*ON)

       (305.5B*( 486.+460.))*((0.002669*  122.)+(   49.816*1.003*( 29.55#(    .577/13.6))/(   39.4060.)))
ISO »	= 104.73 PERCENT
                                   120. *     15.98 *   29.46 *   .401 *  .401




PARTICIPATE LOADING — EPA METHOD 5 (AT STANDARD CONDITIONS)

CS * 0.001 * MN * 15.43 / VMSTD

CS * 0.001 *       .0000 * 15.43 /    52.294 =       .00000 6R/OSCF




PARTICULATE LBS/HR — EPA METHOD 5

PMR r CS * OSSTD / (15.43 * 453.6)

PMR c       .00000 *    1476086. / (15.43 • 453.6) =      .00000

-------
Run No.  D3.1
     Sample volume - 1.48 m3r  52.29  scf
Example calculations
     CS (Part)  = 38.6/1.48 = 26.1  mq/m3
     CS (Part)  = 0.001  x 33.6  x 15.43/52.29  = 0.011  qr/dscf
     CS (S02)   = 90.I/  1.48= 60.9  ma/m3
               = 60.9 x 24.06/64  =  23  ppm
               = 0.001  x 90.1  x 15.43/52.29  = 0.026 gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Water soluble sul fates
As S04=
Sulfur dioxide
Sul f uric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
38.6
0.3
0.4
6.0
90.1
84.0



3 Concentration,
mg/m
26.1
0.2
0.3
4.0
60.9
56.8



gr/dscf
0.011
0.0001
0.0001
0.002
0.026
0.025



ppm



23
14



                                   A-373

-------
                                                        FIELD  OAT*
        PLANT
        SAMPLING LOCATION

        SAMPLE TYPE
        OPERATOR
        AMBIENT TEMP.(DEG.F)
        BAR.PRESS.(IN.HG)
        STATIC PRESS.(IN.H20)
        FILTER NUMBER(S)
        STACK INSIDE DIM.(IN)
        PITOT TUBE COEFF.
        THERM. NO.
        LEAKAGE
        METER CALIB. FACTOR
                     REPUBLIC STEEL CLEVELAND
                     OUTLET STACK

                     PART/H2S04/SU2
                     BHUFFEY
                      28.
                     29.55
                     -1.20
                     3530309
                       97.50    .00
                       .83
                      .003 CFM 9
                     1.024
                5.0 IN.HG
        READ & RECORD DATA EVERY 10.0 MINUTES
  TRAVERSE
   POINT
    NO.
SAMPLE  CLOCK
 TIME    TIME
(MIN.) (24-HR
        CLOCK)
                GAS METER
                 READING
                 (CU.FT.)
         VELOCITY
           HEAD
         (IN.H2U)
ORIFICE PRESSURE  STACK
  DIFFERENTIAL     TEMP
   (IN.H20)      (DEG.F)
                             DATE                      12/01/81
                             RUN NUMBER                  D3-2

                             PROBE LENGTH ft TYPE       4* GLASS
                             NOZZLE      t I.D.         .401
                             ASSUMED MOISTURE          14.0
                             SAMPLE BOX NUMBER          g
                             PETER BOX NUMBER          FB7
                             METER HEAD OIFF.           .71
                             C FACTOR                   .84
                             PROBE HEATER SETTING      250.
                             HEATER BOX SETTING        250.
                             REFERENCE PRESS. OIFF.     .14
       DRY GAS METER  PUMP     SAMPLE
           TEMP      VACUUM  BOX  TEMP
          (DEG.F)    (IN.HG) (DEG.F)
                               IMPINGER
                                 TEMP
                               (DEG.F)
                                                 DESIRED   ACTUAL
                                                               INLET  OUTLET
   1NIT
>

-J
0
r.o
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
40.0
100.0
110.0
120.0
1134
1141
1350
1400
1410
1420
1430
1440
1450
1500
1510
1520
1530
1540
TOTALS
AVERAGE
120.0
483.135
486.635
489.200
493.770
496.350
502.950
507.640
511.800
515.680
519.900
524.000
528.470
532.990
537.320

 54.185
                                           .055
                                           .048
                                           .048
                                           .048
                                           .050
                                           .038
                                           .035
                                           .042
                                           .040
                                           ,040
                                           .043
                                           .044
                                           ,045
                                         .72
                                         .62
                                         .62
                                         .62
                                         .65
                                         .50
                                         .46
                                         .54
                                         .52
                                         .52
                                         .56
                                         .57
                                         .58
                                         .58
             .72
             .62
             .62
             .62
             .65
             .50
             .46
             .54
             .52
             .52
             .56
             .57
             .58
475.
498.
508.
470.
480.
485.
482.
500.
505.
466.
480.
485.
485.
                                .58   486.
40.
40,
44,
48.
50.
52.
55.
56.
56.
56.
56.
56,
56.
                            51,
                                                                         36.
                                                                         36.
                                                                         36.
                                                                         36.
                                                                         38.
                                                                         40.
                                                                         42.
                                                                         42.
                                                                         44.
                                                                         45.
                                                                         45.
                                                                         45.
                                                                         46.
                 41.
2.0
2.5
2.5
2.5
3.0
3.0
3.0
3.0
3.5
4.0
4.2
4.2
4.2
310
295
300
272
276
260
265
262
253
258
250
245
245
                3.2   270.
 0.
39.
44.
44.
47.
47.
55.
53.
55.
55.
55.
54.
54.
                                                                                                  46.

-------
           PARTICIPATE FIELD DATA ft RESULTS TABULATION




PLANT* NAME AND ADDRESS               TEST TEAM LEADER




REPUBLIC STEEL CLEVELAND              BRUFFEY
TEST   D3-2
OUTLET STACK

TEST DATE
TB
TF
TT
NP
Y
DN
CP
PM
1
OJ VM
TM
VMSTO
VLC
VNC
BHO
FMD
PC02
P03
PCQ
PN2
MD
MMS

TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRV GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H20 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF NATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRV GAS
PERCENT C02 BY VOL., DRV
PERCENT 02 BY VOL., DRY
PERCENT CO BY VOL., DRY
PERCENT N2 BY VOL., DRY
MOLECULAR WT-ORV STACK GAS
MOLECULAR NT-STACK GAS
ENGLISH UNITS
12/01/81
1134
1540
120.0
13
1.024
.401 IN
.83
.58 IN-H20
54.185 CU-FT
46.2 F
57.246 SCF
144.7
6.811 SCF
10.63
.894
4.00
12.00 .
.00
84.00
29.12
27.94
METRIC UNITS
12/01
1134
1540
120.0
13
1.024
10.2
.83
14.6
1.534
7.9
1.621
144.7
.193
10.63
.894
4.00
12.00
.00
84.00
29.12
27.94
/81



I'M

PM-H20
CU-M
C
sec

SCP









-------
    PB




    PSI




    PS




    TS




    VS




    AS




    OSSTO




    OS




    ISO




    MN






    CS




    PMR
BAROMETRIC PRESSURE




STATIC PRES OF STACK G»S




STACK PRES, ABS.




AVERAGE STACK TEMP




AV6 STACK GAS VELOCITY




STACK AREA




STACK FLO* RATE* DRY*




ACTUAL STACK FLON RATE




PERCENT ISOKINETIC






  MG. EPA S
     29.55  IN-HG




     -1.20  1N-H20




     29.06  IN-MG




    086.    F




     16.0   FPS




   7066.   SO-IN




1065237.    SCFH




29B3501.    ACFH




    115.5




       .0000






       .00000 GR/DSCF*




       .00000 LB/HR
  750.57  KM-HG




  •30.08  MM-H20




  708.33  CM-HG




  252.    C




    0.9   KPS




    0.817 SQ-M




01091.




81080.




  115.5




     .0000






     .0000 MG/DSCM




     .000 KG/HR
                EMISSION RATE



       *  68 OEG F,  29.92 IN.H6.
CJ

-------
      EXAMPLE PARTICIPATE CALCULATIONS  TEST  NO.   D3-2

           OUTLET STACK



VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

VMSTD *  (17.607 • VM * Y *  (PB  »  PM  / 13.6))  /  (TM  * 060.)

          17.607 •    50.185 •  1.020 *  (  29.55  *  .575  /  13.6)
VMSTD s  ......................	.........	...........	  -      57.206  DSCF
                         (  06. + 060.)



VOLUME OF MATER VAPOR AT STANDARD CONDITIONS

VMC = .00707 * VLC

VMC * .00707 *  145. =   6.81 9CF



PERCENT  MOISTURE IN STACK GAS

BMO « (100. * VMC) / (VMSTD * VMC)

          100. *   6.81
BMO « —	— = 10.63  PERCENT
            57.246 +   6.81



MOLE FRACTION OF DRY STACK GAS

FMO = (100. - BMO) / 100.

          100. >  10.6
FMD * ———————— s   .890
               100.



AVERAGE MOLECULAR WEIGHT OF DRV STACK GAS

MD s (PC02 * .44) » (P02 * .32) * (PN2 *  PCO) * .28

MD a ( 4.00*44/100) * (12.0*32/100) » ((80.0* .0) * 28/100 s   29.12



MOLECULAR WEIGHT OF STACK GAS

MMS « MD * (1. - (BHO/100))  * 18. * (BftO/100)

MMS =  29.12* 11. -(10.63/100)) » 18. * (10.63/100)  *   27.90

-------
      STACK GAS VELOCITY »T STACK CONDITIONS

      DELP = SUM. OF THE SQRT(VH *  (TS «• 460.))

      VS « 85.49 * CP * DELP /  (SORT(MWS * PS) * PNTS)

      VS * 85.49 *  .83 *   84.016  /  (SQRT( 27.94 * 29.46)  *  13. =    15.98  FPS




      STACK 6AS VOLUMETRIC FLON AT  STACK CONDITIONS

      OS » VS « AS • 3600/144

      OS =   15.98 *  7466. 3600/144  »    2983501. ACFH




      STACK CAS VOLUMETRIC FLON AT  STANDARD CONDITIONS

      OSSTD * 17.647 * OS * PS  * (I.  - (8WO/100)) / (TS * 460.)

                17.647 *    2983501.  *  29.46 • (1. - (10.63/100))
      OSSTD s .........................—........................ s     1465237. SCFH
                         ( 486. «• 460.)




>     PERCENT ISOKINETIC

^     ISO * (305.58*(TS+460.))*((0.002669*VLC)+(VM*Y*(PB+(PI*/13.6))/(TM4460.)))/(TT*VS*PS*DN*DN)
00
             (305.5BM 486.»460.))*((0.002669*  145.)*(   54.185*1.024* ( 29.55*(    .575/13.6))/(   46.+ 460.)))
      ISO *	.	.	—	 = 115.49 PERCENT
                                         120. *     15.98 *   29.46 *   .401 *  .401




      PARTICIPATE LOADING — EPA METHOD 5 (AT STANDARD CONDITIONS)

      CS * 0.001 * MN * 15.43 / VMSTO

      CS « 0.001 *       .0000  * 15.43 /    57.246 =       .00000 GR/OSCF




      PARTICULATE LBS/HR — EPA METHOD 5

      PMR = CS * OSSTD / (15.43 * 453.6)

      PMR z       .00000 *    1465237. / (15.43 * 453.6) s      .00000

-------
Run No. D3.2
     Sample  volume =1.62  m , 57.25  scf
Example  calculations
     CS  (Part) =34.5/1.62 = 21.3   mq/m3
     CS  (Part) = 0.001 x34.5  x 15.43,57.25 =  0.009  qr/dscf
     CS  (S02)  =152.Ei/1.62=  94.3ma/m3
              = 94.3 x 24.06/64  =35  ppm
              = 0.001 x!52.8x 15.43/57.25 =  Q.Q41 gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Water soluble sul fates
As S04=
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
34.5
18.1
1.8
2.5
0.0
152.8
7.0



o Concentration,
mg/m
21.3
11.2
1.1
1.5
0.0
94.3
4.3



gr/dscf
0.009
0.005
0.0005
0.001
0.000
0.041
0.002



ppm



35
1



                                     A-379

-------
                                                           FIELD  DATA
UJ
00
o
PLANT REPUBLIC STEEL
SAMPLING LOCATION STACK OUTLET *1
SAMPLE TYPE PART/H2S04/S02
OPERATOR DAN FTIZGERALl)
AMBIENT TEMP. (DEG.F) 26.
BAR. PRESS. (IN.HG) 29.55
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530345
STACK INSIDE DIM. (IN) 97.75 .00
PITOT TUBE COEFF. .84
THERM. NO. 133
LEAKAGE .004 CFM 3 10.
METER CALIB. FACTOR .962
HEAD & RECORD DATA EVERY 10.0 MINUTES
TRAVERSE
POINT
NO.

INIT












SAMPLE
TIME
(MIN.)

0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
CLOCK
TIME
(24-HR
pi nr v ^
LLUCn )
1134
1353
1403
1413
1423
1433
1446
1453
1503
1513
1523
1533
1542
GAS METER
READING
(CU.FT.)

754.742
759.100
763.255
767.550
771.675
775.930
779.750
783.375
787.225
791.165
794.960
798.960
803.032
VELOCITY
HEAD
(IN.H20)


.055
.046
.054
.048
.050
.038
.035
.042
.040
.040
.043
.044
CLEVELAND OHIO
BATTERY
0 IN.HG
ORIFICE
PRESSURE
DIFFERENTIAL
(IN.
OFSIREO

.68
.58
.65
.60
.62
.47
.03
.51
.48
.50
.53
.54
H20)
ACTUAL

.68
.58
.65
.60
.62
.47
.43
.51
.48
.50
.53
.54
STACK
TEMP
(DEG.F)
DATE 12/11/81
RUM NUMBER 03-3
PHOBE LENGTH ft TYPE 4 FOOT GLASS
NOZZLE : I.D. .402
ASSUMED MOISTURE 13.7
SAMPLE BOX NUMBER
MFTER BOX NUMBER FB8
METER HEAD OIFF. 1.91
PROBE HEATER SETTING 400.
HEATER BOX SETTING 400.
K FACTOR 11628.0
DRY GAS METER
TEMP
(DEG.F


PUMP
VACUUM
(IN.HG)
SAMPLE
BOX TEMP
(DEG.F)
IMPINGEH
TEMP
(DEG.F)
INLFT OUTLET

175.
496.
506.
470.
480.
485.
4«2.
500.
505.
466.
480.
485.

39.
35.
38.
42.
45.
47.
48.
50.
51.
52.
53.
54.

38.
33.
33.
34.
35.
36.
38.
40.
41.
42.
43.
44.

9.0
8.0
9.0
4.0
10.0
8. 5
7.5
7.5
7.5
7.5
8.0
6.0

369.
442.
406.
411.
411.
414.
430.
409.
398.
410.
407.
399.

40.
44.
48.
47.
50.
52.
55.
55.
59.
57.
60.
60.
  TOTALS
  AVERAGE
120.0
46.290
                                         .55
                               .55
486,
46,
38,
8.3   411.
52.

-------
                PARTICIPATE FIELD DATA « RESULTS TABULATION

     PLANT- NAME AND ADDRESS               TEST TEAM LEADER

     REPUBLIC STEEL CLEVELAND OHIO         DAN FTIZGERALO
     TEST   03-3
                STACK OUTLET  01 BATTERY
U)
DO
TEST DATE

TB        TIME-START
TF        TIME-FINISH

TT        NET TIME OF TEST, M1N.

NP        NET SAMPLING POINTS

Y         METER CALIBRATION FACTOR

ON        SAMPLING NOZZLE DIAMETER

CP        PITOT TUBE COEFFICIENT

PM        AVERAGE ORIFICE PRESSURE
          DROP

VM        VOLUME OF DRV GAS SAMPLED
          AT METER CONDITIONS

TM        AVERAGE GAS METER TEMP

VMSTD     VOLUME OF DRV GAS SAMPLED
          AT STANDARD CONDITIONS*

VLC       TOTAL HZO COLLECTED IN
          IMPINGERS AND SILICA GEL,»L.

VNC       VOLUME OF HATER VAPOR
          AT STANDARD CONDITIONS*

BHO       PERCENT MOISTURE BY VOLUME

FMD       MOLE FRACTION DRV GAS

PC02      PERCENT C02 BY VOL., DRY

P02       PERCENT 02 BY VOL.* DRV

PCO       PERCENT CO BY VOL., DRY

PN2       PERCENT N2 BY VOL., DRY

MD        MOLECULAR MT-DRY STACK GAS

MNS       MOLECULAR NT-STACK GAS
ENGLISH UNITS
12/11/81
1130
1542
120.0
12
.982
.002 IN
.84
.55 IN-H20
48.290 CU-FT
42.1 F
49.315 SCF
143.2
6.740 SCF
12.02
.880
4.00
12.00
.00
84.00
29.12
2T.78
METRIC UNITS
12/11/81
1134
1542
120.0
12
.982
10.2
.84
13.9
1.367
5.6
1.396
143.2
.191
12.02
.880
4.00
12.00
.00
84.00
29.12
27.78




KM

CM-H20
CU-M
C
SCf

sec









-------
    PB

    PSI

    PS

    TS

    VS

    AS

    OSSTO

    OS

    ISO

    HN


    cs

    PMR
    BAROMETRIC PRESSURE

    STATIC PRES OF STACK GAS

    STACK PRES, A8S.

    AVERAGE STACK TEMP

    AVG STACK GAS VELOCITY

    STACK AREA

    STACK FLOW RATE, DRY*

    ACTUAL STACK FLOM RATE

    PERCENT ISOKINETIC


      MG. EPA 5





      EMISSION RATE

68 DEC F,  29.92 IN.HG.
     89.55  IN-HG

     •1.20  IN-H20

     29.46  IN-HG

    486.    F

     16.3   FPS

   7505.   30-IN

1077970.    SCFH

3057331.    ACFH

     96.7

       .0000



       .00000 GR/OSCF*

       .00000 LB/HR
  750.57  KM-HG

  •30.40  HM-H20

  748.33  *M-MG

  252.    C

    5.0   fPS

    4.842 SQ-M

11852.    SCHH

86574.    *CfH

   98.7


     .0000



     .0000 MG/OSCM

     .000 KG/MR
U)
00
to

-------
"~co
 U)
              EXAMPLE PARTICIPATE CALCULATIONS TEST NO.  03-3


                   STACK OUTLET »l BATTERY





        VOLUME OF ORT GAS SAMPLED AT STANDARD CONDITIONS


        VMSTO « (17.647 • VM • Y • (PB * PM / 13.6)) / (TM * 460.)


                  17.647 •    48.290 •  .982 * ( 29.55 *  .549 /  13.6)
        VMSTD f - ---------------------------------------------------- =     49.315  DSCF
                                 (  42. + 460.)





        VOLUME OF MATER VAPOR AT STANDARD CONDITIONS


        VNC * .04707 • VLC


        VMC s .04707 *  143. =   6.74 SCF





        PERCENT MOISTURE IN STACK GAS


        BMO « (100. « VMC) / (VMSTD » VHC)


                  100. *   6.74
                    • ---------------- — * 12.02 PERCENT
                    49.315 *   6.74
        MOLE FRACTION OF DRY STACK GAS


        FMD « (100. • BMO) / 100.


                  100. -  13. 0
        FMD * .—.——————— z   .880
                       100.
        AVERAGE MOLECULAR HEIGHT OF DRY STACK GAS

        MO « (PC02 * .44) * (POZ * .32) * (PN2 * PCO) * .28

        MD = (  4.00*44/100) » (12.0*32/100)  * ((BO.O+ .0) * 28/100 =   29.12




        MOLECULAR HEIGHT OF STACK GAS

        MHS > MO * (1.  - (BHO/100)) + 18. *  (BHO/100)

        M*S *  29.12*  (I. •(12.02/100)) » 18. *  (12.02/100) a   27.78

-------
    STACK GAS VELOCITY AT STACK CONDITIONS

    OELP » SUM. OF THE SORT(VH *  (TS » 060.))

    VS * 85.39 * CP * DELP /  (SORT(Ml»S * PS) * PNTS)

    VS « 85.49 •  .84 *   77.908  /  (SORT( 27.78 * 29.46)  •  12. =    16.30 FPS




    STACK GAS VOLUMETRIC FLOM AT  STACK CONDITIONS

    OS a vs * AS * 3600/100

    OS *   16.30 *  7505. 3600/100  «    3057331. ACFH




    STACK GAS VOLUMETRIC FLOH AT  STANDARD CONDITIONS

    OSSTD « 17.647 * OS * PS * fl.  - (BNO/100)) / (TS * 460.)

              17.647 *    3057331.  •  29.46 *  (1. • (12.02/100))
    OSSTO a	=     1077970. SCFH
                       ( 486. «• 460.)




>  PERCENT ISOKINETIC
 I
jj£  ISO * (305.5B*(T3*460.))*((0.002669*VLC)*(VM*Y*(PB»(PM/13.6))/(TM»460.)))/(TT*VS«P3*DN*OM
*>
           (305.5B*( 486.+460,))*((0.002669*   143.)*(   48.290* ,982«( 29.55»(    .549/13.6))/(   42.4460.)))
    130 * ......-.....-..................................._................................................ z  98.65 PERCENT
                                       120. *     16.30 *   29.06 •   .402 •  .402




    PARTICIPATE LOADING -- EPA METHOD 5 (AT STANDARD CONDITIONS)

    CS » 0.001 * MN * 15.43 / VMSTO

    CS = 0.001 *       .0000 * 15.43 /    49.315 =       .00000 GH/OSCF




    PARTICULATE LBS/HR -- EPA METHOD 5

    PMR s CS * OSSTD / (15.43 * 453.6)

    PMR s       .00000 •    1477970. / (15.43  * 453.6) *      .00000

-------
Run No. D3.3
     Sample volume =  1.40m3T  49.32scf
Example  calculations
     CS  (Part)  =30.9/1.40 = 22.1   mq/m3
     CS  (Part)  =  0.001 x30.9 x 15.43/19.32  = 0.010  qr/dscf
     CS  (S02)   = 130.8/1.40 =  93.4ma/m3
               =  93.4 x 24.06/64  = 35 pom
               =  0.001 x130.8x 15.4349.32   = Q.Q41 gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Water soluble sul fates
As S04=
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
30.9
0.0
0.0
4.1
130.8
12.0



3 Concentration,
mg/m
22.1
0.0
0.0
2.9
93.4
8.6



gr/dscf
0.010
0.000
0.000
0.001
0.041
0.004



ppm



35
2



                                     A-385

-------
                                                               FIELD   DATA
GJ
00
PLANT REPUBLIC STEtL
SAMPLING LOCATION STACK OUTLET «1
SAMPLE TYPE PART/H2S04/S02
OPERATOR DAN FTIZGERALO
AMBIENT TEMP.(OEG.F) 28.
BAR. PRESS. (IN. HG) 29.55
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530513
STACK INSIDE DIM. (IN) 97.75 .00
PITOT TUBE COEFF. ,8a
THERM. NO. 133
LEAKAGE .014 CFM 3 5.
METER CALIB. FACTOR 1.033
READ * RECORD DATA
TRAVERSE
POINT
NO.

INIT












SAMPLE
TIME
(MIN.)

0
10.0
20.0
30.0
00.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
CLOCK
TIME
(24-HR
PI nr it i
LLULK )
1139
1358
1408
1418
1428
1438
144(1
1458
1508
1518
1528
1538
1548
EVERY 10.0
GAS METER
READING
(CU.FT.)

312.428
316.815
320.830
325.155
329.265
333.490
337.130
340.640
344.525
348.100
351.965
356.310
360.313
MINUTES
VELOCITY
HEAD
(IN.H20)


.055
.048
.054
.048
.050
.038
.035
.042
.000
.040
.043
.044
CLEVELAND OHIO
BATTERY
0 IN.HG

ORIFICE

PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.68
.58
.65
.60
.62
.47
.43
.51
.48
.50
.53
.54
H20)
ACTUAL

.68
.58
.65
.60
.62
.47
.43
.51
.48
.50
.53
.54

STACK
TEMP
(DEG.F)


475.
498.
508.
470.
400.
485.
482.
500.
505.
466.
480.
485.
DATE 12/11/81
RUN NUMBER D3-4
PROBE LENGTH ft TYPE 5 FOOT GLASS
NOZZLE : I.U. .401
ASSUMED MOISTURE 13.2
SAMPLE BOX NUMBER
METER BOX NUMBER FB4
METER HEAD OIFF. i.ss
PROBE HEATER SETTING 400.
HEATER BOX SETTING 400.
K FACTOR 11628.0

DRY GAS METER PUMP
TEMP VACUUM
(DEG.F) (IN.HG)
INLET OUTLET

43. 42.
39. 33.
42. 38.
47. 39.
49. 40.
51. 42.
53. 43.
53. 44.
54. 45.
55. 47.
57. 48.
59. 50.
.0
.0
.5
.0
.0
.0
.0
.5
.0
.5
.5
.5

SAMPLE
BOX TEMP
(OEG.F)


404.
440.
400.
404.
392.
409.
422.
415.
395.
395.
360.
364.

IMPINGER
TEMP
(DEG.F)


42.
46.
50.
50.
53.
56.
60.
59.
60.
59.
61.
59.
       TOTALS
       AVERAGE
120.0
47.885
                                         .55
                               .55
480,
50.
43.
3.6   400.
55.

-------
           PARTICIPATE FIELD DATA s RESULTS TABULATION
PLANT- NAME AND ADDRESS               TEST TEAM LEADER
REPUBLIC STEEL CLEVELAND OHIO         OAN FTIZGERALO
TEST   D3-4
STACK OUTLET »1 BATTERY


TEST DATE
TB
TF
TT
NP
Y
ON
CP
PM
OJ VM
CXI
TM
VMSTD
VLC
VNC
BHO
FMO
PC02
P02
PCO
PN2
MD
MMS
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H20 COLLECTED IN
IMPINGERS AND SILICA GEL,HL.
VOLUME OF MATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL., DRY
PERCENT 02 BY VOL., DRY
PERCENT CO BY VOL., DRY
PERCENT N2 BY VOL., DRY
MOLECULAR MT-DRY STACK GAS
MOLECULAR HT-STACK GAS
ENGLISH UNITS
12/11/81
1139
1548
120.0
12
1.033
.001 IN
.64
.55 IN-H20
47.885 CU-FT
46.4 F
51.009 SCF
141.1
6.642 SCF
11.52
.885
4.00
12.00
.00
84.00
29.12
27. BO
METRIC UNITS
12/11/81
1139
1548
120.0
12
1.033
10.2
.84
13.9
1.356
8.0
1.004
141.1
.188
11.52
.885
4.00
12.00
.00
84.00
29.12
27.84



MM

MM-H20
CU-M
C
SCM

SCM









-------
     PB

     PSI

     PS

     TS

     VS

     AS

     OSSTD

     OS

     ISO

     MN


     cs

     PMR
BAROMETRIC PRESSURE

STATIC PRES OF STACK GAS

STACK PRES, ABS.

AVERAGE STACK TEMP

AV6 STACK GAS VELOCITY

STACK AREA

STACK FLOW RATE, DRV*

ACTUAL STACK FLO* RATE

PERCENT ISOKINETIC



  MG. EPA 5
     29.55  IN-HG

     •1.20  IN-H20

     ?9.06  IN-HG

    «BO.    F

     lb.2   FPS

   7505.   SO-IN

1«89756.    SCFH

3002559.    ACFH

    101.7

       .0000



       .00000 GR/DSCF*

       .00000 LB/HR
  750.57  PM-HG

  •30.ae  VM-H20

  708.33  HM-MG

          C

    a.9   fPS

    a.602 SO-M

          SCMH

B6156.    »CMH

  101.7

     .0000



     .0000 MG/DSCM

     .000 KG/HR
                EMISSION RATE

       •  68 DE6 F,  29.92  IN.HG.
OJ
00
00

-------
            EXAMPLE  PARTICIPATE  CALCULATIONS TEST NO.  03-0

                 STACK  OUTLET  «l BATTERY



     VOLUME  OF  DRY  GAS SAMPLED  AT  STANDARD CONDITIONS

     VMSTD  a (17.647 • VM •  Y • (PB * PM / 13.6)) / (TM •» 860.)

                17.647  *    47.885  • 1.033 • ( 29.55 *  ,50<> / 13.6)
     VMSTD  a —— — ——	—-..	 — - —	 =     51.009 OSCF
                               C 46. + 460.)



     VOLUME  OF  MATER VAPOR AT STANDARD CONDITIONS

     VMC 3  .04707 * VLC

     VNC *  .04707 *  141. a    6.64 3CF



     PERCENT  MOISTURE  IN  STACK  GAS

     BMO •  (100. *  VMC) / (VMSTO * VMC)

                100. *   6.64
     BMO *	= 11.5? PERCENT
>                51.009 +  6.64

CO
00
ID
     MOLE FRACTION OF  DRY STACK GAS

     FMO =  (100. - BMO) / 100.

                100. -   11.5
     FMO a —	——	.	— a   .885
                    100.
     AVERAGE MOLECULAR MEIGHT  OF  DRY  STACK  GAS

     MD a  (PC02 •  .44) *  (P02  *  .32)  «•  (PN2 * PCO)  •  .28

     MO =  ( 4.00*44/100)  *  (12.0*32/100)  *  ((84.0*  .0)  *  28/100 =   29.12



     MOLECULAR HEIGHT OF  STACK GAS

     MMS a MD * (1. • (BHO/100))  »  18.  *  (BWO/100)

     MMS =  29.12*  (1. -(11.52/100))  *  18.  *  (11.52/100)  =   27.84

-------
      STACK  GAS VELOCITY AT STACK CONDITIONS

      DELP * SUM.  OF THE SQRT(VH • (TS *  460.))

      VS = BS.49 * CP *  DELP / (SURT(MHS  *  PS)  *  PNT3)

      VS = 85.49 *  .84  *   77.610 / (SQRT( 87.80 *  89.46)   *   18.  =   16.22 FPS



      STACK  GAS VOLUMETRIC  FLOW AT STACK  CONDITIONS

      OS * VS • AS * 3600/144

      OS a   16.22 *  7505. 3600/144 «    3042559.  ACFH



      STACK  GAS VOLUMETRIC  FLOW AT STANDARD CONDITIONS

      OSSTD  * 17.64? * OS * PS * (1. - (BWO/100))  /  (TS  *  460.)

                17.647 *    3042559. * 29.46  *  (1.  -  (11.52/100))
      OSSTD  * —	=    1489756.  SCFH
                         (  4«0. *• 460.)



      PERCENT I30KINETIC
>
jjj     ISO ~  (305.5e*(TS*460.))*((0.002669*VLC)»(VK*Y*(PB'»(P*/13.6))/(TM»460.)))/(TT*VS*PS*DN*DN)
VD
O            (305.58*( 480.4460.))*((0.002669*   141.)*(    47.885*1.033* (  29.59*(    .549/13.6))/(  «6.«460.)))
      ISO »	.....	.	. * 101.74 PERCENT
                                         120.  *      16.22  *    29.46 *   .401  *  .401



      PARTICIPATE  LOADING — EPA METHOD 5 (AT  STANDARD CONDITIONS)

      CS = 0.001  • MN *  15.43 / VMSTO

      CS * 0.001  *       .0000 * 15.43 /     51.009  =        .00000  GR/DSCF



      PARTICIPATE  LBS/HR -- EPA METHOD 5

      PMR »  CS  *  OSSTD / (15.43 * 453.6)

      PMR a        .00000 *     1489756. /  (15.43  *  453.6) c       .00000

-------
Run No. D3.4
     Sample volume =  1.44m3T 51.01 scf
Example  calculations
     CS  (Part) =38.7/1.44=26.9   mg/m3
     CS  (Part) = 0.001 x38.7  x 15.43/51.01 =  0.012  qr/dscf
     CS  (S02)  =143.4/1.44 =99.6  ma/m3
              = 99.6  x 24.06/64  =37 ppm
              = 0.001 x143.4 x 15.43/51.01  =  0.043 gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Water soluble sul fates
As S04=
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
38.7
1.9
2.6
0.8
143.4
8.2



3 Concentration,
mg/m
26.9
1.3
1.8
0.5
99.6
5.7



gr/dscf
0.012
0.001
0.001
0.0002
0.043
0.002



ppm



37
1



                                   A-391

-------
                                                            FIELD   DATA
>
U)
PLANT REPUBLIC SUEL
SAMPLING LOCATION CUKE STACK
SAMPLE TYPE M5-250
OPERATOR 00
AMBIENT TEMP. (OEG.F) 28.
BAR. PRESS. (IN. HG) 29.55
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 5530110
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .83
THERM. NO.
LEAKAGE .000 CFM a) 3.
METER CALIB. FACTOR .99?
READ • RECORD DATA
TRAVERSE
POINT
NO.

INIT












SAMPLE
TIME
(MIN.)

0
10.0
20.0
30.0
00.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
CLOCK
TIME
(24-HR
n nr* i
tL.Ul.~J
1145
1354
1404
1414
1424
1434
1444
1454
1504
1514
1524
1534
1544
EVERY 10.0
GAS METER
READING
(CU.FT.)

988.766
993. B70
998.960
4.060
9.180
14.330
19.490
24.680
29.880
35.090
40.300
45.510
50.756
MINUTES
VELOCITY
HEAD
(IN.H2U)


.056
.056
.056
.056
.056
.056
.056
.056
.056
.056
.056
.056
CLEVELAND
0 IN.HG

ORIFICE

PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.86
.86
.86
.86
.86
.86
.86
.86
.86
.86
.86
.86
H20)
ACTUAL

.86
.86
.86
.86
.86
.86
.86
.86
.86
.86
.86
.86

STACK
TEMP
(OEG.F)


«75.
498.
508.
470.
480.
485.
482.
500.
505.
466.
480.
485.
DATE 12/11/81
RUN NUKBER 03-5
PROBE LENGTH ft TYPE 5* GLASS
NOZZLE : I.U. .434
ASSUMED MOISTURE 13.7
SAMPLE BOX NUMBER
METEH BOX NUMBER FBI
PETER HEAD OIFF. 1.87
C FACTOR .71
PROBE HEATER SETTING 250.
HEATER BOX SETTING 250.
REFERENCE PRESS. DIFF. .12

DRY GAS METER
TEMP
(DEG.F)
INLET OUTLET

«3. 37.
42. 36.
45. 36.
51. 37.
56. 39.
60. 42.
61. 43.
62. 45.
64. 47.
65. 47.
65. 48.
64. 48.

PUMP
VACUUM
(IN.HG)


.5
.5
.5
.0
.0
.0
.0
.0
.0
.0
.0
.5

SAMPLE
BOX TEMP
(DEG.F)


228.
297.
243.
279.
236.
254.
282.
232.
280.
231.
219.
268.

IMPINGEK
TEMP
(OEG.F)


38.
38.
38.
39.
40.
40.
38.
38.
42.
44.
45.
46.
   TOTALS
   AVERAGE
120.0
61.990
                                         .86
                               .86
486.
                                              57.
42.
.9   254.
41.

-------
           PARTICIPATE FIELD DATA & RESULTS TABULATION
PLANT- NAME AND ADDRESS               TEST TEAM LEADER
REPUBLIC STEEL CLEVELAND              00
TEST   D3-5
COKE STACK

TEST DATE
TB
If
TT
NP
Y
DN
CP
PM
I VM
OJ
vo
W TM
VMSTD
VLC
VWC
8*0
FMO
PC02
P02
PCO
PN2
MO
HNS

TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRV GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H20 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF HATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL., DRY
PERCENT 02 BY VOL., DRY
PERCENT CO BY VOL., DRY
PERCENT N2 BY VOL., DRY
MOLECULAR NT-DRY STACK GAS
MOLECULAR KT-STACK GAS
ENGLISH UNITS
12/11/81
lias
isofl
120.0
12
.992
.030 IN
.83
.86 IN-H20
61.990 CU-FT
49.3 F
63.099 SCF
101.1
6.602 SCF
9.52
.905
0.00
12.00
.00
80.00
29.12
2«.06
METRIC UNITS
12/11
1105
1500
120.0
12
.992
11.0
.83
21.8
1.755
9.6
1.787
101.1
.186
9.52
.905
4.00
12.00
.00
84.00
29.12
28.06
/81



I'M

KM-H20
CU-M
C
sec

SCM









-------
     PB

     PSI

     PS

     TS

     VS

     AS

     (JSSTD

     OS

     ISO

     MN


     CS

     PMR
BAROMETRIC PRESSURE

STATIC PRES OF STACK GAS

STACK PRES, ABS.

AVERAGE STACK TEMP

AVG STACK GAS VELOCITY

STACK AREA

STACK FLOW RATE. DRY*

ACTUAL STACK FLO* RATE

PERCENT ISOKINETIC


  M6. EPA 5
                 EMISSION RATE

        *   68  OE6 F,   29.92  IN.HG.
     29.55  IN-HG

     •I.SO  IN-H20

     29.06  IN-HG

    OH6.    F

     10.0   FPS

   7066.   Sn-IN

1666931.    SCFH

3352B85.    ACFH

     95.5

       .0000


       .00000 GR/OSCF*

       .00000 LB/HR
  750.57  MM-HG

  -30.48  CM-H20

  708.33  *M-HG

  252.    C

    5.5   *P3

    4.817 SQ-M

17202.    3Cm

90944.    »CCH

   95.5

     .0000


     .0000 MG/DSCM

     .000 KG/MR
>
co

-------
      EXAMPLE PARTICIPATE  CALCULATIONS  TEST  NO.   D3-5

           COKE  STACK




VOLUME OF DRY GAS SAMPLED  AT  STANDARD CONDITIONS

VMSTD e  (17.647  * VM •  Y *  (PB  »  PM  / 13.6))  /  (TM * 460.)

          17.647 •    61.990  •   .993 •  (  39.55  »   .860  /  13.6)
VMSTO s  ———————.	..........	.......	.	.	     63.099 DSCF
                         (  49.  +  460.)




VOLUME OF HATER  VAPOR AT STANDARD  CONDITIONS

VHC s .04707 * VLC

VHC 3 .04707 *   141. 3   6.64 SCF




PERCENT  MOISTURE IN STACK GAS

BHO 3 (100. • VHC) / (VMSTO * VHC)

          100. •   6.64
BHO 3 —	......  -   9.52  PERCENT
            63.099 +   6.64




MOLE FRACTION OF DRY STACK GAS

FMD 3 (100. - BHO) / 100.

          100. -   9.5
FMD 3 —	.......	.	=    .905
               100.




AVERAGE MOLECULAR HEIGHT OF DRY STACK GAS

MD 3 (PC02 * .44) » (P02 * .33) *  (PN3 «•  PCO) • .28

MD 3 ( 4.00*44/100) » (13.0*32/100)  + ((84.0* .0)  * 36/100 s    39.12




MOLECULAR HEIGHT OF STACK GAS

MHS 3 MO * (1. - (BHO/100)) * 18. *  (BWO/lOO)

MHS 3  39.12* (1. -( 9.52/100)) *  18. * ( 9.52/100) s   38.06

-------
     STACK GAS VELOCITY AT STACK CONDITIONS

     DELP = SUM. OF THE SORTtVH • (TS » 060.))

     VS * 85.49 * CP • OELP / (SORMMKS * PS) * PNTS)

     VS = 85.19 *  .83 *   87.347 / (SOHT( 88.06 « 29.46)  *  12. =   17.96 FP3



     STACK GAS VOLUMETRIC FLO* AT STACK CONDITIONS

     OS = VS • AS • 3600/144

     03 *   17.96 •  7466. 3600/144 *    3352885. ACFH



     STACK GAS VOLUMETRIC FLON AT STANDARD CONDITIONS

     OSSTO = 17.647 • OS » PS • (1. - (BWO/100)) / (TS * 460.)

               17.647 «    3352885. *  29.46 •(!.-( 9.52/100))
     OSSTO * —..————— — - —..	.	..	a    1666931. SCFH
                        ( 486. » 460.)




     PERCENT ISOKINETIC

t>
 I    ISO * (305.58*(TS*460.))*((0.002669*VLC)*(VM*Y*(PB'MPM/13.6})/(TM»460.)))/(TT*VS*P3*DN*DN)
U)
J£           (305.58*1 486.+460.))*((0.002669*  141.)*(   61.990* .992*( 29.55+t    .860/1J.6))/(   O9.«460.)))
     ISO s	•	—	—	=  95.53 PERCENT
                                        1?0. *     17.96 •   29.46 *  .434 *   .034




     PARTICULATE LOADING — EPA METHOD 5 (AT STANDARD CONDITIONS)

     CS = 0.001 * MN * 15.43 / VMSTD

     CS * 0.001 *       .0000 * 15.43 /    63.099 =       .00000 GR/DSCF




     PARTICULATE LB3/HR — EPA METHOD 5

     PMR = CS * 03STD / (15.43 * 453.6)

     PMR s       .00000 *    1666931. / (15.43 * 453.6) =      .00000

-------
Run No.  D3.5
     Sample volume = 1.79  m3.  63.10  scf
Example calculations
     CS (Part)  = 35.0/1.79 =19.6  mq/m3
     CS (Part)  = 0.001  x 35.0  x  15.43/63.10 =0.008  qr/dscf
     CS (S02).  =	/	=	mg/m3
               =	 x 24.06/	=	ppm
               = 0.001  x,
.x  15.43/.
gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Water soluble sul fates
As S04=
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


35.0
22.2
19.9
15.7
15.7
13.4

0.0
0.0

0.9



28.9
2.0
3.4
3 Concentration,
mg/m


19.6
12.4
11.1
8.8
8.8
7.5

0.0
0.0

0.5



16.1
1.1
1.9
gr/dscf


0.008
0.005
0.005
0.004
0.004
0.003

0.000
0.000

0.0002



0.007
0.0005
0.0008
ppm



















                                    A-397

-------
                                                          FIELD  DATA
          PLANT
          SAMPLING LOCATION

          SAMPLE TYPE
          OPERATOR
          AMBIENT TEMP.(DEG.F)
          BAR.PRESS.(IN.HG)
          STATIC PRESS.(IN.H20)
          FILTER NUMBERO)
          STACK INSIDE DIM.(IN)
          PITOT TUBE COEFF.
          THERM. NO.
          LEAKAGE
          METER CALI8. FACTOR
                     REPUBLIC STEEL
                     COKE STACK

                     M8-600
                     00
                      28.
                     29.55
                     -1.20
                     3530218
                       97.50    .00
                       .63
                             CLEVELAND
                      .016 CFM 9
                      .967
                          10.5 IN.HG
          READ & RECORD DATA EVERY  10.0 MINUTES
    TRAVERSE
     POINT
      NO.
SAMPLE
 TIME
(MIN.)
 CLOCK
  TIME
(24-HR
 CLOCK)
GAS METER
 READING
 (CU.FT.)
VELOCITY
  HEAD
(IN.H20)
ORIFICE PRESSURE  STACK
  DIFFERENTIAL     TEPP
   (IN.H20)      (OEG.F)
                                                  DATE                      12/11/81
                                                  RUN NUPBER                  03-6

                                                  PROBE LENGTH ft  TYPE       4*  GLASS
                                                  NOZZLE       :  I.D.         .379
                                                  ASSUMED MOISTURE          13.7
                                                  SAPPLE BOX NUPBER
                                                  PETER BOX NUPBEN          FB6
                                                  PETER HEAD OIFF.          1.51
                                                  C FACTUR                   .90
                                                  PROBE HEATER SETTING      250.
                                                  HEATER BOX SETTING        250.
                                                  REFERENCE PRESS. DIFF.     .16
       DRY GAS METER  PUMP     SAPPLE
           TEMP      VACUUM   BOX  TEMP
          (DEG.F)    (IN.HG)  (DEG.F)
                               IPPINGEH
                                 TEMP
                               (OEG.F)
                                                   DESIRED   ACTUAL
                                                               INLET  OUTLET
     1N1T
co
vo
oo
  TOTALS
  AVERAGE
  0
 10.0
 20.0
 30.0
 40.0
 50.0
 60.0
 70.0
 80.0
 90.0
100.0
110.0
120.0

120.0
 1137
 1356
 1406
 1416
 1426
 1436
 1446
 1456
 1506
 1516
 1526
 1536
 1546
  741.956
  746.950
  751.960
  756.990
  762.060
  767.060
  772.060
  777.130
  782.200
  787.270
  792.340
  797.420
  802.493

   60.537
.056
.056
.056
.056
.056
.056
.056
.056
.056
.056
.056
.056
              .63
              .63
              .63
              .63
              .63
              ,63
              .63
              ,63
              .63
              .63
              .63
              .63
                                         .63
             .63
             .63
             .63
             .63
             .63
             .63
             .63
             .63
             .63
             .63
             .63
             .63
«75.
498.
508.
470.
480.
485.
482.
500.
505.
466.
480.
485.
                                           .63   486.
35.
34.
37.
43.
48.
51.
52.
52.
53.
53.
53.
52.
                                                 47,
35.
35.
35.
35.
36.
38.
39.
40.
42.
42.
42.
42.
                                    38.
3.3
3.4
3.6
3.7
3.7
4.0
4.8
6.2
7.4
8.0
8.7
9.2
517
555
546
536
534
547
538
538
538
538
522
524
                                                                                 5.5   536.
42.
41.
40.
40.
40.
40.
42.
42.
44.
44.
46.
46.
                                                                        42.

-------
           PARTICULATE FIELD DATA « RESULTS TABULATION




PLANT- NAME AND ADDRESS               TEST TEAM LEADER




REPUBLIC STEEL CLEVELAND              00
TEST   D3-6
COKE STACK


TEST DATE
TB
TF
TT
NP
Y
DN
CP
> PM
^° VM
vo
TM
VMSTD
VLC
VNC
BViO
FMD
PC02
P02
PCO
PN2
MO
MNS
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZ7LE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRV GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H20 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF HATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL., DRY
PERCENT 02 BY VOL., DRY
PERCENT CO BY VOL., DRY
PERCENT N2 BY VOL., DRY
MOLECULAR NT-DRY STACK GAS
MOLECULAR MT-STACK GAS
ENGLISH UNITS
12/11/81
1137
1506
120.0
12
.967
.379 IN
.83
.63 IN-H20
60.537 CU-FT
02.7 F
60.820 SCF
160.5
7.703 SCF
11.29
.887
0.00
12.00
.00
HO. 00
29.12
27.86
METRIC UNITS
12/11/81
1137
1546
120.0
12
.967
9.6
.83
16.0
1.710
5.9
1.722
164.5
.219
11.29
.887
4.00
12.00
.00
84.00
29.12
27.86



fM

KM-H20
CU-M
C
SCM

SCM









-------
     PB

     PSI

     PS

     T3

     VS

     AS

     OSSTD

     OS

     ISO

     MN


     cs

     PMR
BAROMETRIC PRESSURE

STATIC PRES OF STACK GAS

STACK PRES, ABS.

AVERAGE STACK TEHP

AVG STACK GAS VELOCITY

STACK AREA

STACK FLOW RATE, DRY*

ACTUAL STACK FLOW RATE

PERCENT ISOKINETIC


  MG. EPA 5
     39.55  IN-HG

     -1.20  IN-H20

     29.46  IN-HG

    486.    F

     18.0   FPS

   7466.   Sn-IN

1640093.    SCFH

3364702.    ACFH

    122.7

       .0000


       .00000 GR/OSCF*

       .00000 LB/HR
  750.57  *M-HG

  •30.48  PM-H20

  748.33  fM-HG

  252.    C

    5.5   WPS

    4.817 SO-M

46443.    SCKH

95278.    ACMH

  122.7

     .0000


     .0000 MG/OSCH

     .000 KG/HR
                EMISSION RATE

       *  68 DEG F,  29.92 IN.HG.
O
O

-------
             EXAMPLE PARTICIPATE CALCULATIONS  TEST  NO.   os-6

                  COKE STACK



       VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

       VMSTD * (17.647 * VM * Y *  (P8 «• PM  / 13.6))  /  (TM  * 460.)

                 17.647 •    60.537 *   .967 •  (  39.55  *   .630  /  13.6)
       VM3TD = ——	—	.	=      60.824 DSCF
                                I  43.  «•  4bO.)



       VOLUME OF HATER VAPOR AT STANDARD  CONDITIONS

       VMC * .04707 * VLC

       VKC f .04707 «  165. =   7.74 SCF



       PERCENT MOISTURE IN STACK GAS

       BMO * (100. * VMC) / (VMSTD * VMC)

>                100. •   7.74
'      BMO « ——————	......—. = 11.29  PERCENT
O                  60.824 »   7.74
       MOLE FRACTION OF DRY STACK GAS

       FMD = (100. - BHO) / 100.

                 100. •  11.3
       FHD s —.——.—............ 3   .887
                      100.
       AVERAGE MOLECULAR WEIGHT OF DRV STACK GAS

       MO = (PC02 • .44) + (P02 * .32) * (PN2 «• PCO) • .28

       MD = ( 4.00*44/100) » (12.0*32/100)  + ((80.0* .0) * 28/100 =   29.12




       MOLECULAR HEIGHT OF STACK GAS

       MHS = MD • (1. - (BVO/100)) + 18. *  (BWQ/100)

       MMS e  29.12* (1. -(11.29/100)) * IB. * (11.29/100) «   27.86

-------
     STACK  GAS VELOCITY  AT  STACK  CONDITIONS

     DELP  * SUM.  OF  THE  SHRT(VH  * (TS  »  060.))

     VS  s  85.
^    PERCENT I30KINETIC
o
M    ISO *  (305.58*(TS+060.))*((».002669*VLC)+(VMoYo(PB»(PM/13.6))/(TM4060.)))/(TT*VS*PS*DN*ON)

            (305.58M 086.+060.))*((0.002669*  165.)+(    60.537*  .967*(  29.55*(    .630/13.6))/(  O3.»060.)))
     ISO «	.	—	 s 122.73 PERCENT
                                        120.  *      18.03  *   29.06 •   .379  *  .379



     PARTICIPATE  LOADING —  EPA METHOD 5 (AT  STANDARD CONDITIONS)

     CS  < 0.001  * MN * 15.03 / VMSTD

     CS  = 0.001  *       .0000  *  15.03  /    60.820 =       .00000  GR/DSCF



     PAHTICULATE  LBS/HR  —  EPA METHOD  5

     PMR =  CS  * OSSTD /  (15.03 *  053.6)

     PMR =        .00000  *    1600093.  /  (15.03 * 053.6)  s       .00000

-------
Run No. D3.6
     Sample volume =1.72  m3. 60.82 scf
Example calculations
     CS (Part) =25.5/1.72=0.006 mg/m3
     CS (Part) = 0.001  x25.5 x 15.43/60.82=0.006  qr/dscf
     CS (S02)  =169.VI.72=  98.3ma/m3
              = 98.3  x 24.06^4  =37  ppm
              = 0.001  x 169.1 x 15.43/_&L£2_ = QJM3_ gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sulfates
As H2S04
As H2S04-2H20
Water soluble sulfates
As S04=
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
25.5
0.0
0.0
2.2
169.1
12.8



o Concentration,
mg/m
14.8
0.0
0.0
1.3
98.3
7.4



gr/dscf
0.006
0.000
0.000
0.0005
0.043
0.003



ppm



37
2



                                    A-403

-------
                                                        FIELD  DATA
PLANT REPUBLIC STEEL
SAMPLING LOCATION STACK OOTLET 01
SAMPLE TYPE PAHT/H2S04/S02
OPERATOR ARMSTRONG
AMBIENT TEMP.(OEG.FJ 35.
BAH. PRESS. (IN. H6) 39.72
STATIC PRESS. (IN. H2U) -1.20
FILTER NUMBERtS) 3530325
STACK INSIDE DIM. (IN) 97.75 .00
PITOT TUBE COEFF. .80
THERM. NO. 133
LEAKAGE .000 CFM 9 7.
METER CALIB. FACTOR 1.003
READ » RECORD DATA
TRAVERSE
POINT
NO.

1NIT












SAMPLE
TIME
(MIN.)

V
10.0
20.0
30.0
00.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
CLOCK
TIME
(24-HH
PI up w i
ILUIK 1
940
950
1000
1010
1020
1030
1040
1050
1100
1110
1120
1130
1140
EVERY 10.0
GAS METER
READING
(CU.FT.)

411.613
416.200
420.910
425.660
430.260
435.130
439.830
444.630
449.380
454.000
458.800
463.800
468.564
MINUTES
VELOCITY
HEAD
(IN.H20)


.047
.U50
.048
.050
.053
.049
.052
.048
.050
.051
.056
.050
CLEVELAND OHIO
BATTERY
0 IN.HG

ORIFICE

PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.62
.66
.64
.66
.70
.65
.68
.64
.66
.67
.74
.66
H20)
ACTUAL

.62
.66
.64
.66
.70
.65
.68
.64
.66
.67
.74
.66

STACK
TEfP
(DEG.F)


487.
495.
507.
474.
485.
498.
483.
499.
510.
474.
482.
490.
DATE 12/12/81
HUN NUMBER ua-i
PROBE LENGTH t TYPE 5 FOOT GLASS
NOZZLE : I.D. .404
ASSUMED MOISTURE 13.7
SAMPLE BOX NUMBER
KE1ER box NUMBErt FB2
METER HEAD D1FF. 1.7b
C FACTOh .80
PROBE HEATER SETTING 250.
HEATER BUX SETTING 250.
REFERENCE PRESS. OIFF. .14

DRY GAS METER
TEMP
(DEG.F)
INLET OUTLET

38. 37.
40. 37.
42. 37.
44. 38.
45. 38.
46. 38.
46. 38.
46. 38.
47. 40.
48. 40.
48. 40.
48. 4U.

PUfP
VACUUM
(IN.HG)


2.5
3.0
3.0
3.5
5.0
5.0
5.0
5.0
5.5
6.0
6.5
7.0

SAMPLE
BOX TEMP
(OEG.F)


292.
304.
320.
304.
315.
302.
319.
315.
301.
285.
266.
266.

IMPIN6ER
TEMP
(DEG.F)


37.
37.
44.
45.
«7.
«6.
50.
50.
53.
52.
53.
55.
TOTALS
AVERAGE
120.0
56.951
                                         .67
                               .67
490.
45.
38.
4.8   299,
47.

-------
           PARTICULATE FIELD DATA « RESULTS  TABULATION




PLANT- NAME AND ADDRESS                TEST  TEAM  LtADEH




REPUBLIC STEEL CLEVELAND OHIO          ARMSTRONG
TEST   D4-1
STACK OUTLET ft| BATTERY


TEST DATE
TB
TF
TT
NP
Y
ON
CP
I PM
O
V VM
TM
VMSTD
VLC
VWC
BNO
FMD
PC02
P02
PCO
PN2
MD
MftS
TIME-START
TIME-FINISH
NET TIMt OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H20 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF HATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL., DRY
PERCENT 02 BY VOL., DRY
PERCENT CO BY VOL., DRY
PERCENT N2 bY VOL., DRY
MOLECULAR |»T-OKY STACK GAS
MOLECULAR WT-STACK GAS
ENGLISH UNITS
12/12/81
940
1140
120.0
12
1.003
.404 IN
.84
.67 IN-H20
56.951 CU-FT
41.6 F
59.821 SCF
157.3
7.404 SCF
11.01
,B<)0
3.70
11.10
.00
85.20
29.04
27.62
METRIC UNITS
12/12/81
940
1140
120.0
12
1.003
10.3
.84
16.9
1.613
5.3
1.694
157.3
.210
11.01
.890
3.70
11.10
.00
85.20
29.04
27.82



KM

fM-H20
CU-M
C
SCK

SCM









-------
      PB


      PSI


      PS


      TS


      VS


      AS


      QSSTO


      OS


      ISO


      MN



      CS


      PMR
BAROMETRIC PRESSURE


STATIC PRES OF STACK GAS


STACK PRES, A6S.


AVERAGE STACK TEMP


AV6 STACK GAS VELOCITY


STACK AREA


STACK FLOW RATE* DRY*


ACTUAL STACK FLOW RATE


PERCENT ISOKINETIC



  MG. EPA 5
 I
£>
O
                 EMISSION RATE


        *  68 DEG F,  29.92  IN.HG.
     29.72  IN-HG


     -1.20  IN-H20


     29.63  IN-HG


    490.    F


     17.3   FPS


   7505.   SO-IN


1586494.    SCFH


3244223.    ACFH


    1 10.2


       .0000



       .00000 GR/DSCF*


       .00000 LB/HR
  754.89  KM-HG


  -30.48  KM-H20


  752.65  CM-HG


  255.    C


    5.3   CPS


    4.842 SO-M


44981.    SCKH


91867.    ACCH


  110.2


     .0000



     .0000 HG/OSCM


     .000 KG/HR

-------
             EXAMPLE PART1CULATE CALCULATIONS TEST NO.  DO-1

                  STACK OUTLET «1 BATTERY



       VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

       VMSTD  « (17.607  * VM •  Y * (PB * PM / 13.6)) / (TM * 060.)

                 17.607 *    56.951 • 1.003 * ( ?9.72 *  .665 / 13.6)
       VMSTD  s -	 -     59.821 DSCF
                                I  02. * 160.)



       VOLUME OF NATER  VAPOR AT STANDARD CONDITIONS

       V*C  =  .00707  * VLC

       VKC  =  .04707  •  157. =    7.aO SCF



       PERCENT MOISTURE IN  STACK GAS

       BNO  =  (100. * VHC) / (VMSTD » VHC)

&                100. *   7.00
^      BWO  =  --—	—	— —	 = 11.01 PERCENT
O                 59.821 +   7.00
~J


       MOLE FRACTION OF DRY STACK  GAS

       FMD  =  (100. - BWOJ  / 100.

                 100. -  11.0
       FMO  =  —	——	....... 3   .890
                     100.



       AVERAGE MOLECULAR WEIGHT  OF DRY STACK  GAS

       MD = (PC02 *  .00)  »  (P02  *  .32)  * (PN2 » PCO)  • .28

       MO = (  3.70*40/100)  »  (11.1*32/100)  »  ((85.2*  .0)  *  28/100 =   29.00



       MOLECULAR HEIGHT  OF  STACK  GAS

       MWS  s  MD * (1. - (MHO/100))  » 18. *  (HhO/100)

       MWS  =   29.00*  (1.  -U1.U1/1UU) )  + 18.  *  (11.01/100)  =   27.82

-------
      STACK GAS VELOCITY AT STACK CONDITIONS

      DELP = SUM. OF THE SORKVH * US + 160.))

      VS s 85. 49 * CP * DELP / (SQKT(MwS * PS) * PNTS)

      VS = 85.1V *  .84 •   82.965 / (SQRT( 27.83 * 29.63)  •  12. =   17.29 FPS



      STACK GAS VOLUMETRIC FLOW AT STACK CONDITIONS

      US = VS * AS * 3bUU/laa

      OS =   17.29 *  7505. 3600/144 s    3244223. ACFH



      STACK GAS VOLUMETRIC FLOW AT STANDARD CONDITIONS

      QSSTO s 17.647 * OS * PS * (1. - (BMO/100)) / (TS * 460.)

                17.647 «    3244223. *  29.63 • (1. - (11.01/100))
      QSSTD =	——	—	........—.......— z    1588494. SCFH
                         ( 490. * 460.)


>
^     PERCENT ISOKINETIC
o
00     ISO = - (305.58*(TS+460.))«((0.002669«VLC)+(Vf*Y*(PB+(PM/13.6))/(TM«'460.))}/(TT*VS«PS*UN*DN)

             (305.58M 490.+ 460.))*((0.002669.  157.)»(   56.951 * 1.003* ( 29.72+(    .665/13.6))/(   42.+460.)))
      ISO z -.	—	* U0.2« PERCENT
                                         120. *     17.29 •   29.63 *  .404 *  .404



      PARTICIPATE LOADING — EPA METHOD  5 (AT STANDARD CONDITIONS)

      CS = 0.001 • MN * 15.43 / VM3TD

      CS = 0.001 *       .1)000 * 15.43 /    59.821 s       .00000 GR/DSCF



      PARTICIPATE LBS/HR — EPA METHOD 5

      PMR = CS * OSSTO / (15.43 * 453.6)

      PMR =       .00000 *    1588490. / (15.43 * 453.6) =      .00000

-------
Run No. D4.1

                          3
     Sample volume =1.69 m. 59.8?  scf


Example  calculations


     CS  (Part) =28.5/1.69=16.9   mg/m3


     CS  (Part) = 0.001 x28.5 x 15.43/59.82 =  0.007 qr/dscf


     CS  (S02)  =135.6/1.69 = 80.2  mg/m3


              = 80.2 x 24.06/61_=_3Jl_ppm


              = 0.001 x135.6x 15.43/5aJJ2_sO25_ gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Water soluble sul fates
As SO/f
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
28.5
0.0
0.0
0.0
135.6
42.3



3 Concentration,
mg/m
16.9
0.0
0.0
0.0
80.2
25.0



gr/dscf
0.007
0.000
0.000
0.000
0.035
0.011



ppm



30
6



                                   A-409

-------
                                                             FIELD  DATA
 I

M
o
PLANT REPUBLIC STEEL
SAMPLING LOCATION STACK OUTLET «1
SAMPLE TYPE PART/H2SU4/S02
OPERATOR ARMSTRONG
AMBIENT TEMP. (DEC. F) 35.
BAR. PRESS. (IN. HG) 21. 12
STATIC PRESS. (IN. H20) -1.80
FILTER NUMBEH(S) 3530338
STACK INSIDE DIM. (IN) 97. 75 .00
PITOT TUBE COEFF. .84
THERM. NO. 133
LEAKAGE .000 CFM 31 5.
METER CALIB. FACTOR 1.004
READ ft RECORD DATA
TRAVERSE
POINT
NO.

INIT












SAMPLE
TIME
(MIN.)

0
10.0
20.0
30.0
40.0
50.0
60. 0
70.0
80.0
90.0
100.0
110.0
120.0
CLOCK
TIME
(24-HR
r* i n f* v i
LLULK J
943
953
1003
1013
1023
1033
1043
1053
103
113
123
133
143
EVERY 10.0
GAS METtR
READING
(CU.FT.)

537.680
542.190
546.960
551.670
556.500
561.450
566.240
571.140
575.920
580.730
5H5.000
590.670
595.468
MINUTES
VELOCITY
HEAD
(IN.H20)


.047
.050
.048
.050
.053
.049
.052
.048
.050
.051
.056
.050
CLEVELAND OHIU
BATTEHY
0 IN.HG

ORIFICE

PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.60
.68
.66
.68
.72
.67
.70
.66
.68
.t>9
.76
.68
H20)
ACTUAL

.60
.68
.66
.60
.72
.67
.70
.66
.68
.69
.76
.68

STACK
TEMP
(DEG.F)


487.
495.
507.
474.
485.
496.
483.
499.
510.
474.
482.
490.
DATE 12/12/81
HUN NUMBER D4-2
PROBE LENGTH ft TYPE 4 FOUI GLASS
NOZZLE : I.D. .400
ASSUMED MOISTUHE 13.7
SAMPLE BOX NUMBER
VETE« BOX NUMBER FB/
KETER HEAD OIFF. 1.71
C FACTOR .78
PROBE HEATER SETTING 250.
HEATER BUX SETTING 250.
REFERENCE PRESS. DIFF. .15

DRY GAS METER
TEMP
(DEG.F)
IKLET OUTLET

44. 40.
50. 40.
52. 41.
54. 42.
56. 43.
56. 43.
58. 44.
58. 45.
58. 46.
60. 48.
60. 48.
61. 48.

PUPP
VACUUM
(IN.HG)


2.0
2.2
3.0
3.2
3.5
3.8
3.8
4.0
4.0
4.2
4.0
5.0

SAMPLE
BOX TEMP
(UEG.F)


302.
265.
255.
245.
253.
249.
272.
260.
260.
255.
246.
246.

IPPINGER
TEMP
(OEG.F)


39.
39.
47.
47.
48.
50.
48.
51.
50.
49.
54.
52.
    TOTALS
    AVERAGE
120.0
•>7.788
                                          .68
                                .68
490.
                                                                   56.
44,
                                                                3.6   259.
                          48.

-------
                        FIELD  DATA  s  RESULTS  TABULATION
PLANT- NAME  AND  ADDRESS               TEST TEAM  LEADEN
REPUBLIC  STEEL CLEVELAND  OHIO         ARMSTRONG
TEST   D4-2
STACK OUTLET »1 BATTERY
ENGLISH UNITS
TEST DATE
TB
TF
TT
NP
Y
ON
CP
PM
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
12/12/81
943
1143
120.
12
1.
.
.
.
0

004
400 IN
84
68 IN-H20
METRIC UNITS
12/12/Bl
903
1 143
120.
12
1.
10.
•
17.
0

004
2
84
3



ft.

HM-I
VM

TM
VMSTD

VLC

VHC

BWO
FMD
PC02
P02
PCO
PN2
MO
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H20 COLLECTED IN
IMPINGERS AND SILICA GEL,ML,
VOLUME OF HATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL., DRY
PERCENT 02 BY VOL., DRY
PERCENT CO BY VOL., DRY
PERCENT N2 BY VOL., DHY
MOLECULAR HT-ORY STACK GAS
MOLECULAR hl-STACK GAS
                           57.788 CU-FT
                                                 1.636 CU-M
49.
59.
160.
7.
11.
•
3.
11.
•
85.
29.
27.
8 F
790 SCF
7
564 SCF
23
888
70
10
00
20
04
fiO
9
1
160

11

3
11

85
29
27
.<> C
.693 SCC
.7
.214 SCI"
.23
.888
.70
.10
.00
.20
.04
.80

-------
    PB
    PSI
    PS
    TS
    VS
    AS
    USSTO
    OS
    ISO
    MN

    cs
    PMR
BAROMETRIC PRESSURE
STATIC PRES OF STACK GAS
STACK PRES, ABS.
AVERAGE STACK TEMP
AVG STACK GAS VELOCITY
STACK AREA
STACK FLOW RATE» DRY*
ACTUAL STACK FLOW KATE
PERCENT ISOKINETIC

  MG. EPA 5
     29.73  IN-MG
     -1.20  IN-H20
     29.63  IN-HG
    090.    F
     17.3   FPS
   7505.   SQ-IN
1585051.    SCFH
3205338.    ACFH
    112.6
       .0000

       .00000  GR/OSCF*
       .00000  L8/HH
  754.B9  KM-HG
  -30.48  KM-H20
  752.65  VM-HG
  255.    C
    5.3   KPS
    4.842 SU-M
44895.    SCPM
91898.    ACNH
  112.6
     .0000

     .0000 MG/OSCM
     .000 KG/HH
                EMISSION RATE
       *  66 DEG f,  29.92  IN.HG.
K)

-------
       EXAMPLE  PARTICULATE  CALCULATIONS TEST NO.  oa-2

            STACK  OUTLET  01  BATTERY



VOLUME OF DRY  GAS SAMPLED  AT  STANDARD CONDITIONS

VMSTD  =  (17.6A7 • VM  » Y *  (PH  »  PM / 13.6))  / (TM •» flbO.)

          17.617  •    57.788  *  1.U01 * I  29.72 »  .682 / 13.6)
VMSTD  =  — — — «——— ————— — — — — - — — — -. =     59.790 DSCF
                          I  50.  * 
-------
       STACK  GAS  VELOCITY  AT  STACK  CONDITIONS

       DELP  = SUM.  OF  THE  SQRHVH  * ITS  «  «60.))

       VS  =  85.49 *  CP • DELP /  ISUKT(MWS  •  PS)  * PNTS)

       VS  =  85.49 *   .84 *    02.958 /  (SQRT( 27.BO * 29.63)   *  12. =   17.30 FPS




       STACK  GAS  VOLUMETRIC FLO*  AT STACK  CONDITIONS

       OS  =  VS *  AS  *  3600/144

       CIS  =    17.30  »   7505.  3600/144  =     3245338. ACFH




       STACK  GAS  VOLUMETRIC FLOn  AT STANDARD CONDITIONS

       QSSTU  = 17.647  * OS *  PS  *  (1.  -  (BviU/100)) / (TS * 460.)

                 17.647 *     3245338.  *  29.t,3 *  (1. - (11.23/100))
       OSSTO  s .-	 — --	— .	.	...	.	=    1585451. SCFH
                          ( 490.  *  460.)




       PERCENT ISOKINETIC

^      ISO =  (305.58«(TS»460.))«((0.002669«VLC)+(VM*Y«(PB*(P*/13.6))/(TM+460.)))/(TT«VS*PS«DN*DN)
I-1
**             (305.58*1 490.*4bO.))*((0.002669.   161.)*(   57.788*1.004* (  29.72*(    .682/13.6))/ (  50.*460.)))
       ISO =	= 112.61 PERCENT
                                          120.  •      17.30 •   29.63 •  .400 •  .400




       PARTICULATE LOADING " EPA METHOD 5 (AT  STANDARD  CONDITIONS)

       CS  =  U.001  *  MN * 15.43 /  VMSTD

       CS  =  0.001  •        .0000  •  15.43  /     59.790 =        .00000 GR/DSCF




       PARTICULAR LBS/HR --  EPA METHOD  5

       PMR s  CS •  OSSTD /  (15.43 *  453.6)

       PMK =       .00000 *    1585451.  /  (15.43  • 453.6)  =       .00000

-------
Run No.  D4.2
     Sample volume = 1.69  m T59.79   scf
Example calculations
     CS (Part)  = 45.2/  1.69= 26.7   mg/m3
     CS (Part)  = 0.001  x 45.2 x 15.43/59.79  = 0.012  qr/dscf
     CS (S02)   =130.5/1.69 =77.2 mg/m3
               =77.2  x 24.06/64 = 29 ppm
               = 0.001  x130.5 x 15.43/59.79  =	 gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Water soluble sul fates
As S04=
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
45.2
13.5
0.0
0.0
0.9
130.5
15.9



2 Concentration,
mg/m
26.7
8.0
0.0
0.0
0.5
77.2
9.4



gr/dscf
0.012
0.003
0.000
0.000
0.0002
0.034
0.004



ppm



29
2



                                    A-415

-------
                                                        FIELD  0»T»
PLANT REPUBLIC STEtL
SAMPLING LOCATION STACK OUTLET »1
SAMPLE TYPE PART/H2S04/S02
OPERATOR DAN FITZGtRALO
AMBIENT TEMP. (DEG.F) 35.
BAR. PRESS. (IN.HG) 29.72
STATIC PRESS. (IN. M20) -1.20
FILTER NUMBERU) 3530087
STACK INSIDE DIM. (IN) 97.75 .00
PITOT TUBE COEFF. .84
THERM. NO. 133
LEAKAGE .007 CFM S 6.
METER CALIB. FACTOR .982
READ & RECORD DATA
TRAVERSE
POINT
NO.

INIT












SAMPLE
TIME
(MIN.)

0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
CLOCK
TIME
(24-HR

940
950
1000
1010
1020
1030
1040
1050
1100
1110
1120
1130
1140
EVERY 10. 0
GAS METER
READING
(CU.FT.)

804.107
808.315
812.330
816.380
820.675
825.190
829.340
833.740
837.945
842.280
846.560
851.145
855.456
MINUTES
VELOCITY
HEAD
(IN.H20)


.047
.050
.048
.050
.053
.049
.052
.048
.050
.051
.056
.050
CLEVELAND OHIO
BATTERY
0 IN.HG

ORIFICE

PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.59
.62
.59
.63
.66
.61
.65
.59
.61
.64
.70
.62
H20)
ACTUAL

.59
.62
.59
.63
.66
.61
.65
.59
.61
.64
.70
.62

STACK
TEMP
(DEG.F)


487.
495.
507.
474.
485.
496.
4B3.
499.
510.
494.
482.
490.
DATE 12/12/81
RUN NUMBER 1)4-3
PROBE LENGTH « TYPE 4 FOUT GLASS
NOZZLE : I.D. .404
ASSUMED MOISTURE 13.7
SAMPLE BOX NUMBER
METER BOX NUMBER FB8
MF.TER HEAD OIFF. 1.91
PROBE HEATER SETTING 400.
HEATER BOX SETTING 400.
K FACTOR 11856.2

DRY GAS

METER
TEMP
(DEC
INLET

38.
43.
46.
47.
48.
49.
50.
50.
50.
52.
54.
56.
.F)
OUTLET

37.
37.
38.
38.
39.
40.
40.
41.
42.
43.
44.
46.

PUMP
VACUUM
(IN.HG)


2.5
3.0
4.0
4.5
5.0
5.0
5.0
5.0
5.0
5.5
5.5
5.0

SAMPLE
BOX TEMP
(DFG.F)


410.
406.
405.
405.
402.
408.
416.
411.
415.
412.
413.
410.

IMPINGER
TEMP
(DEG.F)


42.
43.
43.
44.
44.
47.
50.
51.
52.
52.
53.
53.
TOTALS
AVERAGE
120.0
51.349
                                         .63
.63
                                     492.
49.
40.
                                                                                  4.6
                                     409,
                                                                                48.

-------
            PARTICIPATE  FIELD  DATA  «  RESULTS  TABULATION
PLANT-  NAME  AND  ADDRESS                TEST  TEAM  LEADER
REPUBLIC  STEEL CLEVELAND OHIO         DAN FITZGERALD
 TEST   D4-3
STACK OUTLET #1 BATTERY

ENGLISH UNITS
TEST DATE 12/12/61
TB
TF
TT
NP
Y
ON
CP
TIME-START 940
TIME-FINISH 1140
NET TIME OF TEST, MIN. 120.0
NET SAMPLING POINTS 12
METER CALIBRATION FACTOR .982
SAMPLING NOZZLE DIAMETER .404 IN
PITOT TUBE COEFFICIENT .64
METRIC UNITS
12/12/81
940
1140
120.0
12
.902
10.3 KM
.64
PM        AVERAGE ORIFICE PRESSURE
          DROP
VM        VOLUME OF DRY GAS SAMPLED
          AT METER CONDITIONS
TM        AVERAGE GAS METER TEMP
VMSTD     VOLUME OF DRY GAS SAMPLED
          AT STANDARD CONDITIONS*
VLC       TOTAL H20 COLLECTED IN
          IMPINGERS ANQ SILICA GEL,ML.
VNC       VOLUME OF HATER VAPOR
          AT STANDARD CONDITIONS*
BNO       PERCENT MOISTURE BY VOLUME
FMD       MOLE FRACTION DRY GAS
PC02      PERCENT C02 BY VOL., DRY
P02       PERCENT 02 BY VOL., DRY
PCO       PERCENT CO BY VOL., DRY
PN2       PERCENT N2 BY VOL., DRY
MD        MOLECULAR HT-ORY STACK GAS
MHS       MOLECULAR WT-STACK GAS
                             .63  IN-H20

                           51.349 CU-FT

                           44.5   f
                           52.502 SCF

                          149.3

                            7.028 SCF

                           11.81
                             .H82
                            3.70
                           11.10
                             .00
                           85.20
                           29.04
                           27.73
 15.9   KM-H20

  1.454 CU-M

  6.9   C
  1.487 SCM

149.3

   .199

 11.81
   .882
  3.70
 11.10
   .00
 65.20
 29.04
 27.73

-------
   PB

   PS1

   P3

   TS

   VS

   AS

   QSSTD

   OS

   ISO

   MN



   cs

   PMR
BAROMETRIC PRESSURE


STATIC PRES OF STACK GAS


STACK PRES. ABS.

AVERAGE STACK TEMP


AVG STACK GAS VELOCITY


STACK AREA


STACK FLO* RATEr DRY*


ACTUAL STACK FLOW RATE


PERCENT ISOKINETIC



  M6. EPA 5
               EMISSION RATE

      *  68 DEC F,  29.9? IN.HG.
     89.78  IN-MG


     -1.20  IN-H20


     89.63  IN-HG

    098.    F


     17.3   FPS


   7505.   SO-IN

1575619.    SCFH


3851926.    ACFH


     97.5


       .0000



       .00000 GR/DSCF*


       .00000 LB/HR
  750.89  ffc-HG

  -30.08  VM-H80

  758.65  *M-HG

  855.    C

    5.3   *PS

    q.eoa SQ-M

04617.    SCCH

98085.    ACVH

   97.5

     .0000



     .0000 MG/OSCM

     .000 KG/HR
 I
^
M
00

-------
           EXAMPLE PARTICULATE CALCULATIONS TEST NO.  na-3

                STACK OUTLET 01 BATTERY



     VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

     VMSTO * (17.647 • VM * Y * (PB » PM / 13.6)) / (TM * 460.)

               17.647 *    SI.349 *  .982 * ( 29.72 »  .626 / 13.6)
     VMSTD » ————— — —	...............	...	... =     52.502 DSCF
                              I  45. * 460.)



     VOLUME OF MATER VAPOR AT STANDARD CONDITIONS

     VNC  * .04707  • VLC

     VNC  * .04707  •  149. =   7.03 SCF



     PERCENT MOISTURE IN STACK GAS

     BNO  3 (100.  * VHC) / (VMSTD » VWC)

               100. •   7.03
>    BNO  «	•	= 11.81  PERCENT
^                52.502 *   7.03
M
U3

     MOLE FRACTION OF DRY STACK GAS

     FMD  = (100.  - BNO) / 100.

               100. -  11.8
     FMD  « ———————— *   .882
                    100.



     AVERAGE MOLECULAR HEIGHT OF DRY STACK  GAS

     MD » (PC02 •  .44)  *  (P02 * .32) * (PN2 »  PCO)  * .28

     MO = (  3.70*44/100)  * (11.1*32/100)  *  ((85.2*  .0)  *  28/100  =   29.04



     MOLECULAR NEIGHT OF  STACK GAS

     MNS  = MO * (1. - (BNO/100))  + 18. *  (BWU/100)

     MHS  *  29.04* (1.  -(11.81/100)) * 18.  *  (11.81/100)  *   27.73

-------
     STACK GAS VELOCITY AT STACK CONDITIONS


     OELP » SUM. OF  THE 3QRHVH *  (T3 » 460.))


     VS * 85.49 • CP * OELP /  (SOHT(MNS * PS) • PNTS)


     VS = 85.49 *  .84 *   83.031  /  (SQRT( 27.73  • 89.63)  *   12. =    17.33  FPS




     STACK GAS VOLUMETRIC FLOW AT  STACK CONDITIONS


     OS s VS * AS *  3600/140


     OS *   17.33 *  7505. 3600/144  :    3251926. ACFH




     STACK GAS VOLUMETRIC FLON AT  STANDARD CONDITIONS


     OSSTD * 17.647  * OS * PS  * (1.  - (BWO/100))  / (TS  * 460.)


               17.647 *    3251926.  *  29.63 *  (1. -  (11.81/100))
     OSSTD = ——— ——	-- ———— —	.	.	...... =     1575619. SCFH
                        ( 492. » 460.)




>   PERCENT ISOKINETIC

4^
to   ISO = (305.58*(TS+4t>0.))*((0.002669*VLC)+(VM*Y*(PB»(PM/13.6)) /(TM«460.)))/(TT*V3*PS*DN*DN)
o

            (305.58*( 492.+460.))*((0.002669*   149.)+(   51.349* .982M  29.72+(    .626/13.6))/(   45.+460.)))
     ISO 3	.	—	 s  97.54 PERCENT
                                        120. *     17.33 *   29.63  *   .404  *   .404




     PARTICULATE LOADING — EPA METHOD 5 (AT STANDARD CONDITIONS)


     CS s 0.001 * MN * 15.43 / VMSTO


     CS a 0.001 *       .0000  • 15.43 /    52.502 =       .00000 GR/DSCF




     PARTICULATE LBS/HR — EPA METHOD 5


     PMR * CS * OSSTO / 115.43 * 453.6)


     PMR =       .00000 *    1575619. / (15.43  *  453.6) =       .00000

-------
Run No.04.3
     Sample volume =  1.49 m3T52.50  scf
Example calculations
     CS (Part)  =24.8  /I.49 =  16.6  mg/m3
     CS (Part)  =  0.001  x 24.8 x 15.43/52.50 = 0.007  qr/dscf
     CS (S02)   =118.3/1.49 =  79.4 mq/m3
               =  79.4 x 24.06/64  = 30 ppm
               =  0.001  x118.3 x 15.43/52.50  = Q.Q35 gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Water soluble sul fates
As S04=
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
24.8
0.7
0.9
3.2
118.3
6.7



3 Concentration,
mg/m
16.6
0.5
0.6
2.1
79.4
4.5



gr/dscf
0.007
0.0002
0.0003
0.0001
0.035
0.002



ppm



30
1



                                   A-421

-------
                                                             FIELD   DATA
            PLANT
            SAMPLING LOCATION

            SAMPLE  TYPE
            OPERATOR
            AMBIENT TEMP.(DEG.F)
            BAR.PRESS.(IN.HG)
            STATIC  PRESS.(IN.H20)
            FILTER  NUMBER(S)
            STACK INSIDE  DIM.(IN)
            PITOT TUBE COEFF.
            THERM.  NO.
            LEAKAGE
            METER CALIB.  FACTOR
                     REPUBLIC STEEL CLEVELAND
                     COKE STACK

                     M5-250
                     DO
                      35.
                     29.72
                     -1.20
                     3530320
                       97.50    .00
                       .63
                      .000 CFM a
                      .992
                          3.0 IN.HG
            READ » RECORD DATA EVERY  10.0 MINUTES
TRAVERSE
POINT
NO.
SAMPLE
TIME
(MIN.)
CLOCK
TIME
(24-HR
CLOCK)
GAS METER
READING
(CU.FT.)
VELOCITY
HEAD
(IN.H2U)
                                                     ORIFICE  PRESSURE   STACK
                                                        DIFFERENTIAL      TEMP
                                                         (IN.H20)       (DEG.F)
                                                DATE                      12/12/B1
                                                RUN NUMBER                  01-5

                                                PROBE LENGTH  ft  TYPE       5'  GLASS
                                                N02ZLE       :  I.D.         .431
                                                ASSUMED MOISTURE          13.7
                                                SAMPLE BOX NUMBER
                                                METER BOX NUMBER          FBI
                                                METER HEAD OIFF.          1.87
                                                C FACTOR                   .71
                                                PROBE HEATER  SETTING      250.
                                                HEATER BOX SETTING        250.
                                                REFERENCE PRESS. DIFF.     .13
                                                     DESIRED
                                               ACTUAL
                                                       DRY GAS METER
                                                           TEMP
                                                           (DEG.F)

                                                       II^LET  OUTLET
                                                                              PUMP
                                                                             VACUUM
                                                                             (IN.HG)
                                                                     SAMPLE
                                                                    BOX  TEMP
                                                                    (OEG.F)
                                                                 IMPINGER
                                                                   TEMP
                                                                 (DEG.F)
       INIT
£>
Ni
    TOTALS
    AVERAGE
  0
 10.0
 20.0
 30.0
 40.0
 50.0
 60.0
 70.0
 80.0
 90.0
100.0
110.0
120.0

120.0
 940
 950
1000
1010
1020
1030
1040
1050
1100
1110
1120
1130
1140
 72.306
 77.320
 82.320
 87.250
 92.220
 97.240
102.260
107.290
112.340
117.400
122.400
127.520
132.653

 60.347
.055
.055
.055
.055
.055
.055
.055
.055
.055
.055
.055
.055
.81
.81
.81
.81
.»!
.81
.81
.81
.81
.81
.81
.81
                                         .81
.81
.81
.81
.81
.81
.81
.81
.81
.81
.81
.81
.81
                                          .81
487.
495,
507.
474,
485.
496,
483,
499.
510,
474,
482,
490,
                                      490,
40.
43.
49.
54.
57.
59.
61.
62.
63.
63.
64.
65.
                                  57.
35.
35.
36.
38.
40.
41.
43.
44.
45.
46.
47.
47.
                                                                         41,
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.1
2.1
2.1
2.2
2.2
                                        2.1
256.
283.
249.
265.
280.
246.
237.
286.
249.
233.
298.
269.
                                     263.
40.
42.
42.
44.
44.
46.
46.
46.
48.
48.
48.
48.
                                                                                           45.

-------
                 PARTICULATE FIELD DATA  ft RESULTS  TABULATION

      PLANT- NAME AND ADDRESS                TEST TEAM LEADER

      REPUBLIC STEEL CLEVELAND               DO
      TEST   04-5
                COKE  STACK
NJ
U)
 TEST DATE

 TB        TIME-START
 TF        TIME-FINISH

 TT        NET TIME OF TEST, MIN.

 NP        NET SAMPLING POINTS

 Y         METER CALIBRATION FACTOR

 DN        SAMPLING NOZZLE DIAMETER

 CP        PITOT TUBE COEFFICIENT

 PM        AVERAGE ORIFICE PRESSURE
          DROP

 VM        VOLUME OF DRY GAS SAMPLED
          AT METER CONDITIONS

 TM        AVERAGE GAS METER TEMP

 VMSTD     VOLUME OF DRY GAS SAMPLED
          AT STANDARD CONDITIONS*

 VLC       TOTAL MZO COLLECTED IN
          IMPINGERS AND SILICA GEL,ML.

 VNC       VOLUME OF MATER VAPOR
          AT STANDARD CONDITIONS*

 BWO       PERCENT MOISTURE BY VOLUME

 FMD       MOLE FRACTION DRY GAS

 PC03      PERCENT CO? BY VOL., DRY

P03       PERCENT 03 BY VOL., DRY

 PCO       PERCENT CO BY VOL., DRY

PN2       PERCENT Ni BY VOL., DRY

MD        MOLECULAR HT-ORY STACK GAS

MWS       MOLECULAR XT-STACK GAS
ENGLISH UNITS
12/12/81
940
1140
120.0
12
.992
.431 IH
.83
.81 IN-H20
bO.347 CU-FT
49.0 F
61.B02 SCF
176.6
fl.313 SCF
11.86
.881
3.70
11.10
.00
85.20
89.04
37.73
METRIC UNITS
12/12/81
940
1140
120.0
12
.992
10.9
.83
20.6
1.709
9.5
1.750
176.6
.235
11.86
.881
3.70
11.10
.00
85.20
29.04
27.73




KM

PM-H20
CU-M
c
sec

SCM









-------
    PB


    PSI

    PS

    TS


    VS

    A3

    QSSTO


    OS

    ISO

    MN



    cs

    PMR
BAROMETRIC PRESSURE


STATIC PRES OF STACK GAS


STACK PRES, A8S.


AVERAGE STACK TEMP


AVG STACK GAS VELOCITY


STACK AREA


STACK FLON RATE, DRY*


ACTUAL STACK FLO" RATE


PERCENT ISOKINETIC



  MG. EPA 5
     29.72  IN-HG


     -1.20  IN-M20


     29.63  IN-HG


    090.    F

     17.9   FPS


   7466.   SO-IN

1620395.    SCFM


3300189.    ACFH


     97.6


       .0000



       .00000  GR/DSCF*


       .00000  LB/HR
  754.89  PM-HG


  -30.48  VM-H20


  752.h5  HM-HG


  255.    C


    5.5   *PS


    4.817 SO-H


45882.    SCKH


94564.    ACNH


   97.6


     .0000



     .0000 MG/DSCM


     .000 KG/HR
               EMISSION RATE

      *  68 DEC F,  29.42  IN.HG.
**
to

-------
             EXAMPLE PARTICULATE CALCULATIONS  TEST  NO.   D4-5

                  COKE STACK



       VOLUME OF DRY 6AS SAMPLED AT STANDARD CONDITIONS

       VM3TD » (17.647 * VM • Y •  (PB * PM  / 13.6))  /  (TM  «• 460.)

                 17.647 *    60.347 *  .993 *  (  39.78  »  .810  /  13.6)
       VMSTO B ——— — ——	. —....	...	. —...	*      61.803  DSCF
                                I  49. * 460.)



       VOLUME OF MATER VAPOR AT STANDARD CONDITIONS

       VMC a .04707 • VLC

       VMC * .04707 *  177. =   8.31 SCF



       PERCENT MOISTURE IN STACK GAS

       BMO a (100.  • VMC) / (VMSTD » VMC)

!f                100. •   8.31
^      BMO =	= 11.86  PERCENT
K>                  61.802 *   8.31
cn


       MOLE FRACTION OF DRY STACK  GAS

       FMD = (100.  > BMO) / 100.

                 100. -  11.9
       FMD s ————————— s   .881
                      100.



       AVERAGE MOLECULAR WEIGHT OF DRY STACK GAS

       MO a (PC03 * .44)  * (P03 *  .33)  * (PN3 * PCO) • .38

       MO = ( 3.70*44/100)  + (11.1*33/100)  * ((85.?+ .0)  * 38/100 =   39.04



       MOLECULAR  HEIGHT OF STACK GAS

       MNS ' MD * (1. - (BMU/100))  + 18. •  (BWO/100)

       MM3 =  39.04* (1.  .(11.86/100))  + 18. *  (11.86/100)  *   37.73

-------
    STACK GAS VELOCITY AT STACK CONDITIONS

    DELP = SUM. OF THE SORHVH * (T3 * 460.))

    VS = 85.49 • CP * DELP / (SO«T(MNS * PS) * PNTS)

    VS = 85.49 *  .83 *   86.747 / ISORT( 27.73 * 39.63)  •  12. =   17.90 FPS




    STACK GAS VOLUMETRIC FLON AT STACK CONDITIONS

    03 = VS * AS * 3600/144

    OS *   17.90 *  7466. 3600/144 *    3340189. ACFH




    STACK GAS VOLUMETRIC FLON AT STANDARD CONDITIONS

    OSSTD « 17.647 * OS • PS • (1. - (BWO/100)) / (TS * 460.)

              17.647 *    3340189. •  29.63 *  (1. - (11.86/100))
    OSSTD =	 =    1620295. SCFH
                       ( 490. * 460.)




jp   PERCENT ISOKINETIC
I
*•   ISO s (305.5B*(TS*460.))*((0.002669*VLC)*(VM*Y*(PB'»(PM/13.6))/(TM*460.)))/(TT*VS*PS*DN*DN)
NJ

^          (305.5B*( 090.+460.))*((0.002669*   177.)*(   60.347* .992*1 29.72*(    .810/13.6))/C   49.»460.)))
    ISO a .....-..........-.._-...............................—...........................................  =   97.60 PERCENT
                                       120. *     17.90 •   29.63 •  .431 *  .431




    PARTICULATE LOADING -- EPA METHOD 5 (AT STANDARD CONDITIONS)

    CS e 0.001 * MN • 15.43 / VMSTD

    C3 z 0.001 *       .0000 * 15.43 /    61.802 =       .00000 GR/DSCF




    PARTICULATE L8S/HR — EPA METHOD 5

    PMR c CS * OSSTD / (15.43 • 453.6)

    PMR c       .00000 *    1620295. / (15.43  * 453.6) =      .00000

-------
Run No. D4.5
                          •3
     Sample  volume =  1.75m T 61.80  scf
Example calculations
     CS (Part)  =31.2/1.75=17.8   mq/m3
     CS (Part)  =  0.001 x31.2  x 15.43/61-8   =  0.008 qr/dscf
                                     3
     CS (S02)   =	/	=	mg/nT
               =	 x 24.06/	=	ppm
               =  0.001 x	x 15.43/	
gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F

Acid sul fates
As H2S04
As H2S04-2H20
Water soluble sul fates
As S04=
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


31.2
21.7
20.2
15.1
14.9
12.3


0.0
0.0

0.0



84.5
2.9
8.5
o Concentration,
mg/m


17.8
12.4
11.5
8.6
8.5
7.0


0.0
0.0

0.0



48.3
1.6
4.8
gr/dscf


0.008
0.005
0.005
0.004
0.004
0.003
V

0.000
0.000

0.000



0.021
0.0007
0.002
ppm



















                                  A-427

-------
                                                                FIEtD  DATA
to
CO
PLANT REPUBLIC STEEL
SAMPLING LOCATION COKt STACK
SAMPLE TYPE M8-bOO
OPERATOR 00
AMBIENT TEMP.(OEG.F) 35.
bAR. PRESS. (IN. HG) 29.72
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530226
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .63
THERM. NO.
LEAKAGE .000 CFM a 12.
METER CALIB. FACTOR .967
READ ft RECORD DATA
TRAVERSE
POINT
NO.

INIT












SAMPLE
TIME
(WIN.)

0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
60.0
90.0
100.0
110.0
120.0
CLOCK
TIME
(24-HR
n or tt \
I-UUIK I
942
952
1002
1012
1022
1032
1042
1052
1102
1112
1122
1132
1142
EVERY 10.0
GAS METER
READING
ICU.FT.)

621.607
626.570
631.360
636.160
841.040
845.910
850.750
855.560
860.440
865.290
670.160
875.100
680.060
MINUTES
VELOCITY
HEAD
(IN.H20)


.055
.055
.055
.055
.055
.055
.055
.055
.055
.055
.055
.055
CLEVELAND OHIO
5 IN.HG

ORIFICE

PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.58
.58
.56
.58
.58
.58
.56
.58
.56
.58
.58
.58
H20)
ACTUAL

.58
.58
.56
.58
.58
.58
.58
.58
.56
.58
.58
.58

STACK
TEMP
(DEG.F)


487.
495.
507.
474.
485.
496.
463.
499.
510.
474.
482.
490.
DATE 12/12/81
RUN NUMBER D4-b
PROBE LENGTH * TYPE 4* GLASS
NOZZLE : I.U. .378
ASSUMED MOlSTUhfc 13.7
SAMPLE BOX NUMBER
METER BOX NUMBER FBb
METEN HEAD DIFF. 1.51
C FACTOR .90
PROBt HEATER SETTING bOO.
HEATER BUX SETTING bOO.
REFERENCE PRESS. OIFF. .16

DRY GAS

METER
TEMP
(DEG
INLET

35.
37.
40.
44.
47.
48.
50.
50.
50.
50.
51.
51.
.F)
OUTLET

38.
36.
38.
38.
39.
39.
40.
40.
40.
42.
42.
43.

PUMP
VACUUM
(IN.H6)


4.0
5.6
7.3
7.8
7.9
6.2
9.3
10.2
10.9
11.3
11.6
11.6

SAMPLE
BOX TEMP
(DEG.F)


543.
585.
599.
646.
633.
620,
625.
634.
636.
637.
628.
617.

IMPINGER
TEMP
(DEG.F)


37.
38.
36.
36.
40.
40.
42.
42.
44.
44.
46.
48.
       TOTALS
       AVERAGE
120.0
58.273
                                          .56
                                .58
490.
46.
40.
8.6   617.
41,

-------
            PARTICULATE  FIELD  DATA  & RtSIILTS TABULATION
PLANT*  NAME AND  ADDRESS               TEST TEAM LEADER
REPUBLIC  STEEL CLEVELAND  OHIO         DO
TEST   D4-6
COKE STACK
 TEST DATE
TB
TF
TT
NP
Y
DN
CP
PM
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
942
1142
120
12




          DROP

VM        VOLUME OF DRY GAS SAMPLED
          AT METER CONDITIONS

TM        AVERAGE GAS METER TEMP

VMSTD     VOLUME OF DRY GAS SAMPLED
          AT STANDARD CONDITIONS*

VLC       TOTAL H20 COLLECTED  IN
          IMPINGERS AND SILICA GEL.ML.

Vt«C       VOLUME OF WATER VAPOR
          AT STANDARD CONDITIONS*

BHO       PERCENT MOISTURE BY VOLUME

FMD       MOLE FRACTION DRY GAS

PC02      PERCENT C02 BY VOL.. DRY

P02       PERCENT 02 BY VOL.. DRY

PCO       PERCENT CO BY VOL.. DRY

PN2       PERCENT N2 MY VOL.. DRY

Ml)        MOLECULAR HT-DRY STACK GAS

MWS       MOLECULAR WT-STACK GAS
ENGLISH UNITS
12/12/61
942
1142
120.0
12
.967
.378 IN
.63
.58 IN-H20
58.273 CU-FT
42.9 F
58.849 SCF
160.0
7.531 SCF
11.35
.687
3.70
11.10
.00
65.20
29.04
27.78
METRIC UNITS
12/12/81
1142
120.0
12
.967
9.6
.83
14.7
1.650
6.1
1.666
160.0
.213
11.35
.887
3.70
11.10
.00
85.20
29.04
27.78




CM

CM-H
CU-M
C
sec

sec









-------
    PB


    PSI


    PS


    TS


    VS


    A3

    OSSTD


    OS


    ISO

    MN



    cs

    PMR
BAROMETRIC PRESSURE


STATIC PRES OF STACK GAS


STACK PRES, ABS.


AVERAGE STACK TEMP


AVG STACK GAS VELOCITY


STACK AREA


STACK FLOW RATE, DRY*


ACTUAL STACK FLON RATE


PERCENT ISOKINEUC



  MG. EPA 5
     29.72  IN-HG


     -1.20  IN-H20


     29.63  IN-HG


    q.    ACFH


    120.3


       .0000



       .00000 GR/OSCF*


       .00000 L8/MR
  750.89  f'M-HG


  •30.18  H


  752.65  HM-HG


  255.    C


    5.a   fPS


    a.817 SO-M


46101.    3CKH


9
-------
           EXAMPLE PAHTICULATE CALCULATIONS  TEST  NO.   Do-6

                COKE STACK



     VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

     VMSTO * (17.647 • VM * Y *  (PB * PM / 13.6))  /  ITM  «• 060.)

               17.607 *    58.273 *  .967 •  (  29.7?  *   .580  /  13.6)
     VMSTO = --—-- — - --------- — ------ - ----- ......... — ........  =      38.809 OSCF
                              (  03. » 060.)



     VOLUME OF HATER VAPOR AT STANDARD CONDITIONS

     VMC = .00707 * VLC

     VMC = .00707 *  160. =   7.53 SCF



     PERCENT MOISTURE IN STACK GAS

     BMO = 1100. * VHC) / (VMSTD + VMC)

               100. *   7.53
>    BMO a ............ ---- — — ...... = 11.35  PERCENT
i,                58.849 *   7.53
U)
I-1

     MOLE FRACTION OF DRY STACK GAS

     FMD = (100. - BMO) / 100.

               100. >  11.3
                    ..... ......... r   ,»B7
                    100.
     AVERAGE MOLECULAR MEIGHT OF DRY STACK GAS

     MD = (PC02 * .00) + (P02 * .32) * (PN2 » PCO) * .28

     MD = (  3.70*00/100) *• (11.1*32/100) * ((85. 2*-. 0) * 28/100 =   29.00


     MOLECULAR MEIGHT OF STACK GAS

     MMS = MD • (1.  - (BWO/100)) * 18. * (BWO/IOO)

     MMS *  29.00* (1. -(11.35/100)) * 18. * (11.35/100) =   27.78

-------
N)
STACK 6*3 VELOCITY AT STACK CONDITIONS

OELP a SUM. OF THE SQRMVH *  (TS » 060.))

VS = 85.19 • CP * OELP / (SQRT(MHS * PS) * PNTS)

VS = 85.49 *  .85 *   86.747  /  (S(jHT( 27.78 • £9.63)  *   12.  =    17.88  FPS



STACK GAS VOLUMETRIC FLOH AT  STACK CONDITIONS

OS = VS * AS * 3600/144

OS =   17.88 *  7466. 3600/144  =    3336804. ACFH



STACK GAS VOLUMETRIC FLOW AT  STANDARD CONDITIONS

OSSTO « 17.647 • OS * PS • (1.  • (BNO/100)) / (TS » 460.)

          17.647 •    3336804.  *  29.63 * (I. - (11.35/100))
OSSTO = ------------------------------ — — ----------------- =     1628021. SCFH
                   ( 490. * 460.)



PERCENT ISOKINETIC

ISO = (305.58*(TS+460.))*((0.002669*VLC)+(V»«*Y«(PB«(PM/13.6))/(TM»460.)))/(TT*VS*PS*DN*DN)

       (305.58*t 490. «460.))*((0. 002669*  160. )*(   58.273* .967*1  29.72M     .580/1 3.6) )/(  43. +460.)))
ISO x ----------------------------------------- — ------------------------ — --- - ----------------------- « 120.26 PERCENT
                                   120. *     17.88 *   29.63 *   .378 *   .378



PARTICULATE LOADING — EPA METHOD 5 (AT STANDARD CONDITIONS)

CS = 0.001 * MN * 15.43 / VMSTD

CS = 0.001 *       .0000 * 15.43 /    58.849 =       .00000 GR/DSCF



PARTICULATE LBS/HR — EPA METHOD 5

PMR s CS * OSSTD / (15.43 • 453.6)

PMR =       .00000 *    1628021. / (15.43 * 453.6) *       .00000

-------
Run No.  D4.6
                           3
     Sample volume = 1.67  m ,  58.85  scf
Example calculations
     CS (Part)  =17.5 /I.67 = 10.5  ma/m3
     CS (Part)  = 0.001  x 17.5  x 15.43/58.85  = 0.004   qr/dscf
     CS (S02)   = 90.1/1.67 = 54.0  ma/m3
               = 54.0 x 24.06/64   =  20 ppm
               = 0.001  x 90.1  x 15.43/58.58  = D.n?4  gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sulfates
As H2S04
As H2S04.2H20
Water soluble sulfates
As S04=
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles

TOC (Condensible)
Catch weight,
mg


17.5






0.0
0.0

0.0
90.1

74.7




2 Concentration,
mg/m


10.5






0.0
0.0

0.0
54.0

44.7


\

gr/dscf


0.004






0.000
0.000

0.000
0.024

0.020




ppm













20

11




                                     A-433

-------
                                                            FIELD  D»TA
            PLANT
            SAMPLING LOCATION
            SAMPLE TYPE
            OPERATOR
            AMBIENT TEMP.(DEC.F)
            BAR.PRESS.(IN.H6)
            STATIC PRESS.(IN.H80)
            FILTER NUMBER(S)
            STACK INSIDE DIM.(IN)
            PITOT TUBE COEFF.
            THERM. NO.
            LEAKAGE
            METER CALIB. FACTOR
                     REPUBLIC STEEL CLEVELAND OHIO
                     STACK OUTLET «1 BATTERY

                     PART/H8S04/S08

                      36.
                     89.78
                     -1.20
                     3530185
                       97.75    .00
                       .ea
                     133
                      .016 CFM a  5.5 IN.HG
                     1.003
            READ » RECORD DATA EVERY 10.0 MINUTES
                                                          DATE
                                                          RUN NUMBER

                                                          PROBE LENGTH ft  TYPE
                                                          NOZZLE       : I.U.
                                                          ASSUMED MOISTURE
                                                          SAMPLE BOX NUMBER
                                                          METER BOX NUMBER
                                                          METER HEAD DIFF.

                                                          PROBE HEATER SETTING
                                                          HEATER BOX SETTING
                                                                            05-1

                                                                          5 FOOT  GLASS
                                                                           .401
                                                                          13.7

                                                                          FB8
                                                                          1.76

                                                                          850.
                                                                          850.
TRAVERSE
POINT
NO.

SAMPLE
TIME
(MIN.)

CLOCK
TIME
(84-HR
n fir* i

GAS METER
READING
(CU.FT.)

VELOCITY
HEAD
(IN.H80)

ORIFICE PRESSURE
DIFFERENTIAL
(IN.H80)
DESIRED ACTUAL
STACK
TEMP
(DEG.F)

DRY GAS METER
TEMP
(DEG.F)
IKLET OUTLET
PUMP
VACUUM
(IN.HG)

SAMPLE
BOX TEMP
(DEG.F)

IMPINGEH
TEMP
(DEG.F)

       INIT
.to.
CO
    TOTALS
    AVERAGE
  o
 10.0
 80.0
 30.0
 40.0
 50.0
 60.0
 70.0
 80.0
 90.0
100.0
110.0
180.0

180.0
1404
1414
1484
1434
1444
1454
1504
1514
1584
1534
1544
1554
1604
469.955
474.660
479.410
484.430
489.310
49q,080
498.750
503.500
508.450
513.390
518.450
583.300
588.833

 58.878
.050
.058
.057
.055
.050
,050
.050
.055
.055
.055
.055
.055
.66
.68
.75
.78
.66
.66
.66
.78
.78
.78
.78
.78
                                         .70
.66
.68
.75
.78
.66
.66
.66
.78
.78
.78
.78
.78
500.
458.
465.
476.
458.
477.
490.
458.
465.
476.
458.
477.
                                          .70   471.
38.
40.
41.
44.
44.
43.
46.
46.
46.
46.
46.
46.
                                               44.
38.
40.
40.
40.
40.
40.
40.
40.
40.
40.
40.
40.
                                          40.
8.0
8.0
8.5
3.0
3.8
3.9
4.8
4.4
4.4
4.5
4.8
5.0
851,
846,
875.
859,
847,
858,
848.
860.
844.
854,
858.
845,
                                        3.7   853.
56.
56.
45.
45.
47.
49.
50.
56.
56.
57.
68.
57.
                                                 53.

-------
                PAHTICULATE  FIELD  DMA  s  RESULTS  TABULATION

          >  NAME AND  ADDRESS               TEST TEAM  LEADER

     REPUBLIC  STEEL CLEVELAND  OHIO
     TEST    05-1
                STACK OUTLET «1 BATTERY
U)
 TEST DATE

 TB         TIME-START
 TF         TIME-FINISH

 TT         NET TIME OF TEST, M1N.

 NP         NET SAMPLING POINTS

 Y          METER CALIBRATION FACTOR

 ON         SAMPLING NOZZLE DIAMETER

 CP         PITOT TUBE COEFFICIENT

 PM         AVERAGE ORIFICE PRESSURE
           DROP

 VM         VOLUME OF DRY GAS SAMPLED
           AT METER CONDITIONS

 TM         AVERAGE GAS METER TEMP

 VMSTD      VOLUME OF DRY GAS SAMPLED
           AT STANDARD CONDITIONS*

 VLC        TOTAL HZO COLLECTED IN
           IMPINGERS AND SILICA GELpML.

 VWC        VOLUME OF MATER VAPOR
           AT STANDARD CONDITIONS*

 BWO        PERCENT MOISTURE BY VOLUME

 FMO        MOLE FRACTION DRY GAS

 PC02       PERCENT COa BY VOL.. DRY

P02        PERCENT 02 BY VOL.,  DRY

PCO        PERCENT CO BY VOL.,  DRY

PN2        PERCENT N2 BY VOL..  DRY

MO         MOLECULAR NT-DRY STACK GAS

MNS        MOLECULAR MT-STACK GAS
ENGLISH UNITS
12/12/81
1000
1600
120.0
12
1.003
.001 IN
.80
.70 IN-H20
SB. 278 CU-FT
01.9 F
61.308 SCF
170.9
8.233 SCF
11.80
.882
3.70
11.80
.00
80.50
29.06
27.75
METRIC UNITS
12/12/81
1000
1600
120.0
12
1.003
10.2
.80
17.8
1.650
5.5
1.736
170.9
.233
11.80
.882
3.70
11.80
.00
80.50
29.06
27.75




MM

MM-H20
CU-M
C
SCI*

SCM









-------
    PB

    PSI

    P3

    TS

    VS

    AS

    OSSTD

    OS

    ISO

    MN


    cs

    PMR
BAROMETRIC PRESSURE

STATIC PRES OF STACK GAS

STACK PRES, ASS.

AVERAGE STACK TEMP

AVG STACK GAS VELOCITY

STACK AREA

STACK FLO* RATE» DRY*

ACTUAL STACK FLOW RATE

PERCENT ISOKINETIC


  MG. EPA 5
                EMISSION RATE

       •  68 DEG F,   29.92 IN.HG.
     £9.78  IM-HG

     -1.20  IN-H20

     29.69  IN-HG

    «71.    F

     17.6   FPS

   7505.   SO-IN

1639020.    SCFM

3303306.    ACFH

    111.1

       .0000


       .00000 GR/DSCF*

       .00000 LB/HR
  756.11  PM-HG

  -30.48  ^

  750.17  »»-HG

  200.    C

    5.a   VPS

    4.802 SO-M

4b012.    SC»*H

93500.    »CHH

  111.1

     .0000


     .0000 MG/DSCM

     .000 KG/HR
*»
U)

-------
          EXAMPLE PARTICULATE  CALCULATIONS TFST  NO.   D5-1

               STACK OUTLET  *1  BATTEkY



    VOLUME OF DRV GAS SAMPLED  AT  STANDARD  CONDITIONS

    VMSTD =  (IT. 647 * VM  * Y •  (PB  *  PM  /  13.6))  /  (TM * 460.)

              17.647 •    56.278  *  1.003 * (  29.78  *  .699 / 13.6)
    VMSTD =  —————— — — -- — -- --- ---. --- - — . ---- . ------- =     61.308 DSCF
                             (  ag. + 060.)



    VOLUME OF HATER VAPOR AT STANDARD CONDITIONS

    VHC a .04707 • VLC

    VHC » .04707 *  175.  a   8.23 SCF



    PERCENT  MOISTURE IN STACK GAS

    BHO • (100. * VNC) /  (VMSTD * VMC)

              100. *   8.23
•y  BHO a — — — — - — — — —  s 11.84  PERCENT
 I               61.308 «•   B.23
U)
-J
    MOLE FRACTION OF DRT STACK GAS

    FMO > (100. - BWO) / 100.

              100. -  11.8
    FMD a — ... ---- - -------- =   .882
                   100.
    AVERAGE MOLECULAR HEIGHT OF DRY STACK GAS

    MD a (PC02 • ,4fl) * (P02 * .32) * (PN2 * PCD) •  .28

    MD * ( 3.70*44/100) » (11.8*32/100) + ((84.5* .0) * 28/100  =   29.06



    MOLECULAR HEIGHT OF STACK GAS

    MHS = MU * (1. • (BMO/100)) * 18. * (BWO/100)

    MMS =  29.06* (1. -(11.84/100)) » 18. * (11.8Q/100) s   27.75

-------
       STACK GAS VELOCITY  AT  STACK  CONDITIONS

       OELP * SUM.  OF THE  SORUVH * ITS *  160.))

       VS a 85.09 • CP * DELP /  ISQRT(MWS  •  PS)  *  PNTS)

       VS » 85.49 *  .84 *   84.461 /  (SORT( 27.75 *  39.69)   •   18.  =   17.61 FPS



       STACK GAS VOLUMETRIC FLO*  AT STACK  CONDITIONS

       OS = VS * AS * 3600/144

       OS =   17.61 *  7505.  3600/144  =    3303306.  ACFH



       STACK GAS VOLUMETRIC FLON  AT STANDARD CONDITIONS

       OSSTD « 17.647 • OS •  PS • (1.  - (BwO/100)) /  (TS * 460.)

                 17.647 *     3303306.  * 29.69  *  (1.  - (11.84/100))
       OSSTD = — ——————	 — — -—.............	  =    1639084. SCFH
                          ( 471.  «•  460.)


>
I      PERCENT ISOKINETIC
>t*
ro      ISO = (305.58*(T3+460.))*((0.002669*VLC)*(VM*Y*(PB«(PM/13.6))/(TM*460.)))/(TT*VS*PS«DN*ON)

              (305.58*( 471.»460.))*((0.002669*   175.)*(   58.278*1.003*(  29.78*(    .699/13.6))/(  48.»460.)))
       130 s	.	= 111.14 PERCENT
                                          120.  *      17.61 *   29.69 *   .401  *  .401



       PARTICIPATE  LOADING — EPA METHOD 5 (AT  STANDARD  CONDITIONS)

       CS * 0.001  * MN * 15.43 /  VMSTD

       CS = 0.001  *       .0000 * 15.43 /     61.300 =        .00000  GR/DSCF



       PARTICULATE  L8S/HR  —  EPA  METHOD 5

       PMR = CS *  OSSTD /  (15.43  *  453.6)

       PHR B       .00000  *    1639024. /  (15.43  * 453.6)  =       .00000

-------
Run No.  D5.1
     Sample volume = 1.74  m ,  61.31  scf
Example calculations
     CS (Part) = 23.3/1.74 = 13.4   mq/m3
     CS (Part) = 0.001  x 23.3  x 15.43/61.31  =  0.006  qr/dscf
     CS (S02)  =131.8/1.74 = 75.7  ma/m3
               = 75.7 x 24.067 64  = 28  ppm
               = 0.001  X131.8  x 15.43/61.31   = 0.033  gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Water soluble sul fates
As S04=
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
23.3
3.4
4.6
3.7
131.8
8.8



- Concentration,
mg/m
13.4
1.9
2.6
2.1
75.7
5.0



gr/dscf
0.006
0.001
0.001
0.001
0.033
0.002



ppm



28
1



                                  A-439

-------
                                                              FIELD   0»T*
             PLANT
             SAMPLING LOCATION

             SAMPLE  TYPE
             OPERATOR
             AMBIENT TEMP.(OEG.F)
             BAR.PRESS.(IN.HG)
             STATIC  PRESS.(IN.H20)
             FILTER  NUMBER(S)
             STACK INSIDE  DIM.(IN)
             PITOT TUBE COEFF.
             THERM.  NO.
             LEAKAGE
             METER CALIB.  FACTOR
                     REPUBLIC STEEL CLEVELAND OHIO
                     STACK OUTLET «1 BATTERY

                     PART

                      36.
                     39.78
                     •1.20
                       97.75
                       .84
                     133
                      .000 CFM a
                     1.004
                        .00
                          4.0 IN.HG
             READ & RECORD  DATA EVERY  10.0 MINUTES
TRAVERSE
POINT
NO.
SAMPLE
TIME
(MIN.)
CLOCK
TIME
(24-HR
CLOCK)
GAS METER
READING
(CU.FT.)
VELOCITY
HEAD
(IN.H20)
                                                       ORIFICE  PRESSURE   STACK
                                                         DIFFERENTIAL      TE"P
                                                          (IN.H20)       (DEG.F)

                                                       DESIRED    ACTUAL
                                                DATE
                                                RUN NUPBER

                                                PHOBE LENGTH  *  TYPE
                                                NOZZLE       :  1.0.
                                                ASSUMED MOISTURE
                                                SAKPLE BOX  NUMBER
                                                PETER BOX NUMBER
                                                *ETER HF»0  DIFF.

                                                PROBE HEATER  SETTING
                                                HEATER BOX  SETTING
                                                             12/12/81
                                                              05-2

                                                             4 FUOT  GLASS
                                                             .401
                                                             13.7

                                                             FB7
                                                             1.71

                                                             250.
                                                             250.
                                                               DRY GAS METER  PUMP     SAMPLE    IMPINGER
                                                                   TEMP      VACUUM   BOX  TEMP    TEMP
                                                                  (DEG.F)    (IN.HG)  (DEG.F)    (DEG.F)

                                                               INLET  OUTLET
         INIT
>t^
£>
o
     TOTALS
     AVERAGE
  o
 10.0
 20.0
 30.0
 40.0
 50.0
 60.0
 70.0
 80.0
 90.0
100.0
110.0
120.0

120.0
1407
1417
1427
1437
1447
1457
1507
1517
1527
1537
1547
1557
1607
595.690
600.660
605.520
610.640
615.630
620.450
625.280
630.080
635.100
640.150
645.170
650.210
655.250

 59.360
.050
.052
.057
.055
.050
.050
.050
.055
.055
.055
.055
.055
.68
.70
.77
.74
.68
.68
.68
.74
.74
.74
.74
.74
                                         .72
.68
.70
.77
.74
.68
.68
.68
.74
.74
.74
.74
.74
                                          .72
500,
458.
465,
476.
452.
477,
490,
458.
465.
476.
458.
477,
                                      471,
46.
47,
50,
53,
56,
57,
58,
60,
60,
60,
60,
60.
                                  56.
44.
44.
44.
44.
45.
45.
46.
46.
47.
48.
48.
48.
                                46.
1.0
1.5
1.5
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
260.
252.
288.
269.
246.
260.
248.
270.
250.
260.
270.
261.
                               1.8   261.
46.
46.
47.
47.
49.
51.
47.
55.
53.
59.
59.
40.
                                           50.

-------
           PARTICIPATE FIELD DATA * RESULTS  TABULATION
PLANT- NAME AND ADDRESS                TEST TEAM LEADER
REPUBLIC STEEL CLEVELAND OHIO
TEST   D5-2
STACK OUTLET «1  BATTERY

TEST
TB
TF
TT
NP
Y
ON
CP
PM

DATE
TIME-START
TIME-FINISH
NET TIME OF TEST, MlN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
ENGLISH UNITS
12/12/81
1407
1607
120.0
12
1.004
.401 IN
.P4
.72 IN-H20
METRIC UNITS
12/12/81
1407
1607
120.0
12
1.004
10.2 MM
.84
18.3 PM-I
          DROP
VM        VOLUME OF DRY GAS SAMPLED
          AT METER CONDITIONS
TM        AVERAGE GAS METER TEMP
VMSTD     VOLUME OF DRY GAS SAMPLED
          AT STANDARD CONDITIONS*
VLC       TOTAL H20 COLLECTED IN
          IMPINGERS AND SILICA GEL,ML.
VMC       VOLUME OF MATER VAPOR
          AT STANDARD CONDITIONS*
BKO       PERCENT MOISTURE BY VOLUME
FMO       MOLE FRACTION DRY GAS
PC02      PERCENT C02 BY VOL., DRV
P02       PERCENT 02 BY VOL.. DRY
PCO       PERCENT CO BY VOL., DRY
PN2       PERCENT N2 BY VOL., DRY
MD        MOLECULAR WT-ORY STACK GAS
MWS       MOLECULAR HT-STACK GAS
                           59.360 CU-FT

                           50.7    F
                           61.441 SCF

                          186.0

                            8.755 SCF
  1.681 CU-M

 10.4   C
  1.740 SCM

186.0

   .248 SCK
12.47
.875
3.70
11.80
.00
84. bO
29.06
27.68
12.47
.875
3.70
11.80
.00
84.50
29.06
27.68

-------
PB




PSI




PS




TS




VS




AS




OSSTO




OS




ISO




MN






CS




PMR
BAROMETRIC PRESSURE




STATIC PRES OF STACK GAS




STACK PRES, ABS.




AVERAGE STACK TEMP




AVG STACK GAS VELOCITY




STACK AREA




STACK FLOW RATEr DRY*




ACTUAL STACK FLOW RATE




PERCENT ISOKINETIC






  MG. EPA 5
     29.78  IN-HG




     -1.20  IN-H20




     29.69  IN-HG



    a?t.    F




     17.6   FP3




   7505.   SO-IN



1629300.    SCFH



3307486.    ACFH



    112.0




       .0000






       .00000 GR/OSCF*




       .00000 LB/HR
  756.41  MM-HG




  -30.48  MM-H20




  750.17  VM-HG




  2«4.    C




    5.4   CPS




    4.842 SO-M




16137.    SCMH




93658.    »CVH




  112.0




     .0000






     .0000 MG/OSCM




     .000 KG/HR
            EMISSION RATE



   *  68 OEG F,  29.92 IN.HG.

-------
              EXAMPLE PARTICULATE CALCULATIONS TEST NO.  D5-2

                   STACK OUTLET «1 BATTERY



        VOLUME OF DRV GAS SAMPLED AT STANDARD CONDITIONS

        VM3TD * (17.607 * VM • Y * (PB * PM / 13.6)) /  (TM •» 060.)

                  17.607 *    59.360 • 1.000 * ( 29.78  +  .719 /  13.6)
        VMSTO s ...........	........	.	.	.....	.  s      61.001  DSCF
                                 (  51. * 060.)



        VOLUME OF MATER VAPOR AT STANDARD CONDITIONS

        VHC s .00707 * VLC

        VMC * .00707 *  186. 3   8.76 SCF



        PERCENT MOISTURE IN STACK GAS

        BNO s (100.  • VhC) / (VMSTO «• VHC)

•f                 100. •   8.76
**       BMO =	s 12.07 PERCENT
*>                   61.001 *   8.76
OJ


        MOLE FRACTION OF DRY STACK GAS

        FMD » (100.  - BMU) / 100.

                  100. -  12.5
        FMD s ———————— a   .875
                       100.



        AVERAGE MOLECULAR HEIGHT OF DRY STACK  GAS

        MO  s (PC02 • .00)  * (PU2 * .32) * (PN2 * PCO)  * .28

        MD  3 ( 3.70*00/100) » (11.8*32/100)  *  ((80.5*  .0) • 28/100 =   29.06



        MOLECULAR HEIGHT OF STACK GAS

        MMS s MD * (1. - (BHO/10U))  + 18. *  (RWO/100)

        MHS *  29.06* (1.  -(12.07/100)) + 18.  * (12.07/100)  =   27.68

-------
STACK GAS VELOCITY AT STACK CONDITIONS

DELP s SUM. OF THE SQRT(VH * (TS « 460.))

VS > 85.49 * CP * DELP / (SQRT(MMS * PS) * PNTS)

VS = 85.49 *  .84 •   84.461 / (SORT( 27.68 * 29.69)  *  12. =   17.63 FPS



STACK GAS VOLUMETRIC FLON AT STACK CONDITIONS

OS = VS * AS * 3600/144

OS >   17.63 *  7505. 3600/144 x    3307488. ACFH



STACK GAS VOLUMETRIC FLON AT STANDARD CONDITIONS

OSSTD a 17.647 * OS * PS * (1. - (BNO/100)) / (TS » 460.)

          17.647 *    3307488. •  29.69 • (1. - (12.47/100))
OSSTD « ——————-- ——— — .---- —............	. s    1629300. SCFH
                   ( 471. * 460.)



PERCENT ISOKINETIC

ISO * (305.58*(TS*46U.))*((0.002669*VLC)*(VM*Y*(PB»(PM/13.6))/(TM*460.)))/(TT*VS*PS*DN«DN)

       (305.58*( 471.+460.))*((0.002669*  186.)*(   59.360*1.000*( 29.78*1    .719/13.6))/(  5t.*460.)))
ISO 9	—	.	—.	.....	—	.........	........	s  112.05  PERCENT
                                   120. *     17.63 *   29.69 *  .401 *  .401



PARTICULATE LOADING — EPA METHOD 5 (AT STANDARD CONDITIONS)

CS * 0.001 * MN * 15.43 / VMSTD

CS « 0.001 *       .0000 * 15.43 /    61.441 =       .00000 GR/DSCF



PARTICULATE LBS/HR « EPA METHOD 5

PMR s CS * OSSTD / (15.43 * 453.6)

PMR a       .00000 *    1629300. / (15.43 * 453.6) *      .00000

-------
Run No.  D5.2
     Sample volume = 1.74  m3.61.44   scf
Example  calculations
     CS  (Part)  = 20.0/1.74  =  11.5  mg/m3
     CS  (Part)  = 0.001  x 20.0  x 15.43/61.44  = 0.005   qr/dscf
     CS (S02)  =	/.
    . mg/m*
                      x 24.06/_
         .ppm
               = 0.001  x
.x 15.43/.
gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Water soluble sul fates
As S04=
Sulfur dioxide
Sul f uric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
20.0
8.7
0.8
1.1
1.7


74.5
0.7
202
2 Concentration,
mg/m
11.5
5.0
0.5
0.6
1.0


42.8
0.40
116
gr/dscf
0.005
0.002
0.0002
0.0003
0.0004


0.019
0.0002
0.05
ppm







I PA contaminated
                                     A-445

-------
                                                           FIELD  DATA
           PLANT
           SAMPLING LOCATION

           SAMPLE TYPE
           OPERATOR
           AMBIENT TEMP.(DEG.F)
           BAR.PRESS.(IN.HG)
           STATIC PRESS.(IN.H20)
           FILTER NUMBEft(S)
           STACK INSIDE DIM.(IN)
           PITOT TUBE  COEFF.
           THERM. NO.
           LEAKAGE
           METER CALIB. FACTOR
                     REPUBLIC STEtL CLEVELAND OHIO
                     STACK OUTLET «1 BATTERY

                     PARTICULATE/SU2
                     DAN FITZGERALD
                      36.
                     29.78
                     -1.20
                     3530323
                       97.75    .00
                       .84
                     133
                      .014 CFM 9 11.0 IN.HG
                      .982
           READ S RECORD DAT*  EVERY 10.0 MINUTES
                                                          DATE
                                                          RUN NUMBER

                                                          PROBE LENGTH  ft  TYPE
                                                          NOZZLE       :  I.D.
                                                          ASSUMED MOISTURE
                                                          SAMPLE BOX NUMBER
                                                          PETER BOX NUMBER
                                                          *ETE« HEAD OIFF.

                                                          PROBE HEATER  SETTING
                                                          HEATER BOX SETTING

                                                          K FACTOR
                                                                          12/12/81
                                                                            05-3

                                                                          4 FOOT GLASS
                                                                           .402
                                                                          13.7

                                                                          F8B
                                                                          1.91

                                                                          350.
                                                                          350.

                                                                        11856.2
TRAVERSE
POINT
NO.

SAMPLE
TIME
(MIN.)

CLOCK
TIME
(24-HR
ri nric i

GAS METER
READING
(CU.FT.)

VELOCITY
HEAD
(IN.H20)

ORIFICE PRESSURE
DIFFERENTIAL
(IN.H2U)
DESIRED ACTUAL
STACK
TE"P
(DEG.F)

DRY GAS METER
TEMP
(DEG.F)
IKLET OUTLET
PUMP
VACUUM
(IN.HG)

SAMPLE
BOX TEMP
(OEG.F)

IMPINGEH
TEMP
(DEG.F)

      INIT
CTi
   TOTALS
   AVERAGE
  o
 10.0
 20.0
 30.0
 40.0
 50.0
 60.0
 70.0
 80.0
 90.0
100.0
110.0
120.0

120.0
1358
1408
1418
1428
1438
1448
1458
1508
1518
1528
1538
1548
1558
8S6.004
860.320
864.760
869.320
673.935
878.410
883.170
887.660
892.255
896.900
901.340
905.770
910.397

 54.393
.050
.055
.055
.055
.050
.057
.055
.055
.055
.050
.052
.057
.62
.71
.70
.70
.65
.72
.69
.71
.70
.64
.64
.72
                                 .68
.62
.71
.70
.70
.65
.72
.69
.71
.70
.64
.64
.72
500.
458.
465.
476.
452.
477.
490.
458.
465.
476.
458.
477.
                                                  .68   471.
46,
44,
50.
52.
54,
55.
56,
57,
58.
58,
5«J.
58.
                                                         54.
44.
45,
45.
43.
46.
47.
48.
48,
50.
50.
51.
52.
                                                       47.
8.0
9.0
10.5
11.0
10.0
10.5
10.0
10.0
10.0
9.0
9.0
9.5
370
358
355
364
359
355
358
345
355
354
355
353
                                                  9.7
                                     357.
43.
44.
43.
49.
50.
5«.
59.
59.
60.
59.
56.
52.
                                           52.

-------
           PARTICULATE FIELD DATA ft RESULTS TABULATION




PLANT- NAME AND ADDRESS               TEST TEAK LEADER




REPUBLIC STEEL CLEVELAND OHIO         DAN FITZGERALD
TEST   05-3
STACK OUTLET *1 BATTERY

TEST DATE
TB
TF
TT
NP
Y
ON
CP
PM
1
£ VM
-J
TM
VMSTD
VLC
VMC
BHO
FMD
PC02
P02
PCO
PN2
MD
MWS


TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H20 COLLECTED TN
IMPINGERS AND SILICA GEL. ML.
VOLUME OF HATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL.. DRY
PERCENT 02 BY VOL., DRY
PERCENT CO BY VOL.. DRY
PERCENT N2 BY VOL., DRY
MOLECULAR HT-DRY STACK GAS
MOLECULAR HT-STACK GAS
ENGLISH UNITS
12/12/81
135B
1558
120.0
12
.982
.402 IN
.84
.68 IN-H20
54.393 CU-FT
50.6 F
55.066 SCF
170.2
8.011 SCF
12.70
.873
3.70
11.80
.00
84.50
29.06
27.66
METRIC UNITS
12/12/81
1358
155B
120.0
12
.982
10.2 MM
.84
17.4 MM-H20
1.540 CU-M
10.3 C
1.559 SCM
170.2
.227 SCM
12.70
.873
3.70
11.80
.00
B4.50
29.06
27.66

-------
     PB




     PSI




     PS



     TS




     VS




     AS



     OSSTO



     OS




     ISO



     MN






     cs



     PMR
BAROMETRIC PRESSURE




STATIC PRES OF STACK GAS




STACK PRES, ABS.




AVERAGE STACK TEMP




AVG STACK GAS VELOCITY




STACK AREA




STACK FLON RATE, DRV*




ACTUAL STACK FLOW RATE




PERCENT ISOKINETIC






  MG. EPA 5
     29.78  IN-HG




     -1.20  IN-H20




     29.69  IN-HG




    471.    F




     17.7   FPS




   7505.   30-IN




1630772.    SCFH




3327285.    ACFH




     99.6




       .0000






       .00000 GR/DSCF*




       .00000 L8/HR
  7S6.ai  kM-HG




  -30.4B  CM-H20




  754.17  *M-HG




  204.    C




    5.a   MPS



    4.042 30-H




46292.    SCfH



94219.    ACfH



   99.6




     .0000






     .0000 MG/DSCM




     .000 KG/MR
                 EMISSION RATE



        *  66 OEG f,  29.92 IN.HG.
00

-------
             EXAMPLE  PARTICIPATE CALCULATIONS TEST NO.  05-3

                  STACK  OUTLET  »1 BATTERY



       VOLUME OF  DRY  GAS SAMPLED AT STANDARD CONDITIONS

       VM3TO  « (17.647 * VM *  Y * (PB + PM / 13.6)) / (TM » 460.)

                 17.647  •    50.393 •  .482 * ( 29.78 »  .683 / 13.6)
       VMSTD  * ---- • ------------------------------------------------ =     55.066 DSCF
                                (  51. * 060.)



       VOLUME OF  MATER VAPOR AT STANDARD CONDITIONS

       VHC  *  .04707 • VLC

       VMC  *  .04707 *  170. s    8.01  SCF



       PERCENT  MOISTURE  IN  STACK GAS

       BHO  »  (100. *  VMC) / (VMSTD +  VHC)

                 100. *   8.01
 >     BHO  a  —..——..———— — — s  12.70 PERCENT
 I                 55.066 «•  8.01
 *»
-*.- ........
 VO

       MOLE FRACTION  OF  DRY STACK GAS

       FMD  «  (100. -  BHO) / 100.

                 100. -   12.7
                     — — ------ —  a    .873
                     100.
      AVERAGE MOLECULAR HEIGHT  OF  DRY  STACK  GAS

      MD •  (PC02 • .44) 4  (PQ2  * .32)  »  (PN2 4 PCO)  *  .28

      MD 3  ( 3.70*44/100)  *  (11.8*32/100)  *  ((83.5*  .0)  •  28/100 =   29.06



      MOLECULAR HEIGHT OF  STACK GAS

      MHS s MD * (1. - (BNO/100))  +  18.  *  (BWO/10U)

      MHS >  29.06* (1. -(12.70/100))  +  18.  *  (12.70/100)  *    27.66

-------
      STACK GAS VELOCITY AT STACK CONDITIONS

      DELP * SUM.  OF THE SORT(VH * (TS * 460.))

      VS 3 65.49 * CP *  OELP /  (SQRT(MhS *  PS)  *  PNTS)

      VS = 85.09 *  .84  »    84.927 /  (SORM  27.66 *  59.69)   *   12.  =    17.73 FPS




      STACK GAS VOLUMETRIC  FLOW  AT STACK CONDITIONS

      OS x VS • AS • 3600/144

      OS *   IT.73 *  7505. 3600/144  s    3327285.  ACFH




      STACK GAS VOLUMETRIC  FLON  AT STANDARD  CONDITIONS

      QSSTO * 17.647 • OS  • PS  • (1.  - (BWO/100)) /  (TS  *  460.)

                17.647 *    3327285.  *  29.69  *  (1.  •  (12.70/100))
      OSSTO * ——————— -—..............................  s    1634772. SCFH
                         (  471.  » 460.)



>
I     PERCENT ISOKINETIC
*»

S     ISO * (305.58*(TS«460.))*((0.002669*VLC)+(VM*Y*(PB*(PM/13.6))/(TM+460.)))/(TT*VS*PS*DN*DN)

             (305.58M 471.«460.))*((0.002669*   170.)*(    54.393*  ,982*(  29.78»(    .683/13.6))/(  51.»460.)))
      ISO x ..—..........................—[[[ 3  99.59 PERCENT
                                         120.  *      17.73  *    29.69 *   .402 •  .402




      PARTICIPATE  LOADING  — EPA METHOD  5 (AT  STANDARD CONDITIONS)

      CS * 0.001 * MN *  15.43 /  VMSTO

      CS s 0.001 *       .0000  * 15.43 /    55.066  =        .00000  GR/OSCF




      PARTICULATE  LBS/HR — EPA  METHOD 5

      PMR s CS  * 03STD / (15.43  * 453.6)


-------
Run No.  D5.3
                          3
     Sample  volume = 1.56m T 55.07  scf
Example  calculations
     CS  (Part) =16.3/1.56 = 10.4  ma/m3
     CS  (Part) = 0.001  x 16.3x  15.43/55.07=  0.004 qr/dscf
     CS  (S02)  =323.1 /1.56=  79.2ma/m3
              = 79.2  x  24.06/64 =30  ppm
              = 0.001  x123.6x  15.43££JE_eQJ135_ gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Water soluble sul fates
As S0a=
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
16.3
2.2
3.0
1.6
123.6
7.8



3 Concentration,
mg/m
10.4
1.4
1.9
1.0
79.2
5.0



gr/dscf
0.004
0.001
0.001
0.0004
0.035
0.002



ppm



30
1



                                   A-451

-------
                                                           FIELD  DAT*
UV
to
PLANT REPUBLIC STEEL
SAMPLING LOCATION STACK OUTLET 01
SAMPLE TYPE PART
OPERATOR UAN FTIZGERALD
AMBIENT TEMP. (OEG.F) 36.
BAR. PRESS. (IN. HG) 29.78
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530335
STACK INSIDE DIM. (IN) 97.75 .00
PITOT TUBE COEFF. .84
THERM. NO. 133
LEAKAGE .019 CFM a 3.
METER CALIB. FACTOR 1.033
READ ft RECORD DATA
TRAVERSE
POINT
NO.

INIT












SAMPLE
TIME
(MIN.)

0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
BO.O
90.0
100.0
110.0
120.0
CLOCK
TIME
(24-HR
PI nrit i
I* UUL.TV f
1400
1410
1420
1430
1440
1050
1500
1510
1520
1530
1540
1550
1600
EVERY 10.0
GAS METER
READING
(CU.FT.)

412.927
417.135
421.690
426.235
430.800
435.175
439.825
444.395
449.040
453.645
458.030
462.430
467.086
MINUTES
VELOCITY
HEAD
(IN.H20)


.050
.055
.055
.055
.050
.057
.055
.055
.055
.050
.052
.057
CLEVELAND OHIO
BATTERY
0 IN.HG

ORIFICE

PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.62
.71
.70
.TO
.65
.72
.69
.71
.70
.64
.64
.72
H20)
ACTUAL

.62
.71
.70
.70
.65
.72
.69
.71
.70
.64
.64
.72

STACK
TEMP
(OEG.F)


500.
458.
465.
476.
452.
477.
490.
458.
465.
476.
458.
477.
DATE 12/12/81
RUN NUMBER ns-4
PROBE LENGTH ft TYPE 5 FOOT GLASS
NOZZLE : I.U. .401
ASSUMED MOISTURE 13.7
SAMPLE BOX NUMBER
KETEH BOX NUMBER FBO
METER HEAD OIFF. i.ee
PROBE HEATER SETTING 350.
HEATER BOX SETTING 350.
K FACTOR 11856.2

DRY GAS METER
TEMP
(OEG.F)
INLET OUTLET

51. 51.
52. 52.
57. 52.
61. 54.
64. 55.
66. 47.
66. 58.
68. 60.
70. 60.
70. 62.
70. 62.
69. 62.

PUMP
VACUUM
(IN.HG)


2.0
2.5
2.5
2.5
2.0
2.5
2.5
2.5
2.5
2.0
2.0
2.5

SAMPLE
BOX TEMP
(OEG.F)


352.
362.
347.
344.
367.
345.
348.
344.
350.
352.
350.
352.

IMPIN6ER
TEMP
(DEG.F)


42.
43.
45.
48.
52.
54.
58.
59.
59.
62.
57.
49.
   TOTALS
   AVERAGE
120.0
54.159
                                         .68
                               .68   471.
64.
57.
                                                                                 2.3   351.
52.

-------
               PARTICIPATE FIELD DATA * RESULTS TABULATION

    PLANT- NAME AND ADDRESS               TEST TEAM LEADER

    REPUBLIC STEEL CLEVELAND OHIO         DAN FTIZGERALD
    TtST   D5-4
                STACK OUTLET 01 BATTERY
ENGLISH UNITS
TEST
TB
TF
TT
NP
Y
ON
CP
PM
DATE
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
12/12/81
1400
1600
120
12
1



.0

.033
.401 IN
.84
.68 IN-H20
METRIC UNITS
12/12/61
1400
1600
120
12
1
10

17
.0

.033
.2
.84
.4



PM

PM-I
I/I—
OJ
          DROP

VM        VOLUME OF DRY GAS SAMPLED
          AT METER CONDITIONS

TM        AVERAGE GAS METER TEMP

VMSTD     VOLUME OF DRY GAS SAMPLED
          AT STANDARD CONDITIONS*

VLC       TOTAL H20 COLLECTED IN
          IMPINGERS AND SILICA GEL,ML.

VHC       VOLUME OF HATER VAPOR
          AT STANDARD CONDITIONS*

BNO       PERCENT MOISTURE BY VOLUME

FMD       MOLE FRACTION DRY GAS

PC02      PERCENT C02 BY VOL., DRY

PD2       PERCENT 02 BY VOL., DRY

PCO       PERCENT CO BY VOL., DRY

PN2       PERCENT N2 BY VOL., DRY

MO        MOLECULAR NT-DRY STACK GAS

MHS       MOLECULAR HT-STACK GAS
 54.159 CU-FT


 60.5   F

 56.586 SCF


182.8


  8.604 SCF
  1.534 CU-M


 15.8   C

  1.602 SCM


182.8


   .244 SCM
13.20
.868
3.70
11.80
.00
84.50
29.06
27.60
13.20
.868
3.70
11.80
.00
84.50
29.06
27.60

-------
      PB
      PS


      TS


      VS


      AS


      OSSTO


      OS


      ISO


      MN




      cs


      PMR
BAROMETRIC PRESSURE


STATIC PRES OF STACK GAS


STACK PRES, ABS.


AVERAGE STACK TEMP


AVG STACK GAS VELOCITY


STACK AREA


STACK FLOW RATE* DRY*


ACTUAL STACK FLOW RATE


PERCENT ISOKINETIC




  MG. EPA 5
     29.78  IN-HG


     -1.20  IN-H20


     29.69  IN-HG


    071.    F


     17.6   FPS


   7505.   SQ-IN


1627070.    SCFH


3330605.    ACFH


    103.3


       .0000




       .00000 GR/DSCF*


       .00000 LB/HR
  756.41  *M-HG


  •30.48  *M-H20


  754.17  *M-HG


  244.    C


    5.4   VPS


    4.842 SO-M


46074.    3CHH



94313.    ACMH


  103.3


     .0000




     .0000 MG/D3CM


     .000 KG/MR
                  EMISSION RATE


         *  68 OEG F,  29.93 IN.HG.
*"
en

-------
              EXAMPLE  PARTICULATE  CALCULATIONS TEST  NO.   D5-4

                   STACK  OUTLET  *1  BATTERY



       VOLUME OF DRY  GAS  SAMPLED  AT  STANDARD  CONDITIONS

       VMSTD  «  117.647 *  VM  • Y *  (PB  *  PM  /  13.6))  /  (TM * 460.)
                  17.647  •    54.154  •  1.033  *  (  29. 7B  *   .683 /  13.6)
       VMSTD * — -------------------------------------------------- a     56.586 DSCF
                                 I  60.  »  460.)
       VOLUME OF WATER VAPOR  AT  STANDARD  CONDITIONS

       VMC *  .04707  * VLC

       VHC •  .04707  *  183. =    8.60  SCF



       PERCENT MOISTURE  IN STACK GAS

       8*0 *  (100. * VMC) / (VMSTD +  VHC)

>                100. *   8.60
 I      BNO *  ------------------------- - =  13.20  PERCENT
^                  56.586 4   8.60
Ul


       MOLE FRACTION OF  DRY STACK GAS

       FMD *  (100. - BMO) / 100.

                 100. -  13.2
       FMD « ——————————  s    .868
                      100.



       AVERAGE MOLECULAR HEIGHT OF DRY STACK GAS

       MO « (PC02 * .44)  * (PQ2 • .32) *  (PN2 * PCO) • .28

       MO = ( 3.70*44/100) » (11.8*32/100) * ((84.5* .0) • 28/100 =   29.06



       MOLECULAR HEIGHT OF STACK GAS

       MMS * MD * (1. -  (BMO/100))  «•  18. * (RwO/100)

       MMS »  29.06* (1.  -(13.20/100)) + 18. * (13.20/100) s   27.60

-------
     STACK  GAS  VELOCITY  AT  STACK  CONDITIONS

     OELP = SUM.  Of  THE  SORUVH  *  (TS  +  460.))

     VS  « 85.49 * CP • OELP /  (SQRT(M*S  *  PS)  *  PNTS)

     VS  = 85.49 *  .84 «   84.927  /  (SGRT( 27.60 *  29.69)   *   12.  s   17.75 FPS



     STACK  GAS  VOLUMETRIC FLOW AT  STACK  CONDITIONS

     03  3 VS *  AS *  3600/144

     OS  =    17.75 *   7505.  3600/144  s     3330605.  ACFH



     STACK  GAS  VOLUMETRIC FLOW AT  STANDARD CONDITIONS

     OSSTD  = 17.647  * OS *  PS  *  (1.  -  (BWO/100)) /  (TS  *  460.)

               17.647 *     3330605.  *  29.69  *  (1.  -  (13.20/100))
     OSSTD  e ...................—.—..	...—.	..	.  =    1627070. SCFH
                        ( 471. *  460.)



>    PERCENT ISOKINETIC

£;    ISO =  (305.5B*(TS»460.))*((0.002669*VLC)+(VM*Y*(PB*(PM/13.6))/(TM*460.)))/(TT*VS*PS*DN*ON)
a\
            (305.58*( 471.«460.))*( (0.002669*  183.)»(    54.159*1.033*(  29.78+(    .683/13.6))/(  60.«460.)))
     ISO «			.	.......	a 103.34 PERCENT
                                        120.  *      17.75  *    29.69 *   .401  *  .401



     PARTICIPATE  LOADING -- EPA  METHOD 5 (AT  STANDARD CONDITIONS)

     CS  3 0.001  * MN * 15.43 / VMSTD

     CS  s 0.001  *       .0000  *  15.43  /    56.586  =        .00000  GR/OSCF



     PARTICULATE  LB3/HR  —  EPA METHOD  5

     PMR s  CS *  OSSTD /  (15.43 *  «53.6)

     PMR *        .00000  *    1627070.  /  (15.43 * 453.6) =      .00000

-------
Run No. D5.4
                          3
     Sample volume  =  1.60m  T 56.59  scf
Example  calculations
     CS  (Part)  =19.1  /1.60=  11.9  mq/m3
     CS  (Part)  =  0.001  x19.1  x 15.43/56.59 = 0.005  gr/dscf
     CS  (S02)   =	/	=	mg/m3
               =	 x 24.06/	=	ppm
               =  0.001  x	x 15.43/	=	gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Water soluble sul fates
As S04=
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
19.1
0.6
0.8
3.8


158.1
4.0
572
o Concentration,
mg/m
11.9
0.4
0.5
2.4


98.8
2.5
357
gr/dscf
0.005
0.0002
0.0002
0.001


0.043
0.001
0.156
ppm







IPA contaminated
                                    A-457

-------
                                                               FIELD  DATA
*>
U1
00
PLANT REPUBLIC STEEL
SAMPLING LOCATION CUKE STACK
SAMPLE TYPE M5-250
OPERATOR DU
AMBIENT TEMP. (DEG.F) 40.
BAR. PRESS. (IN. HG) 29.78
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER I b)
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .83
THERM. NO.
LEAKAGE .000 CFM 9 2.
METER CALI8. FACTOR .992
READ ft RECORD DATA
TRAVERSE
POINT
NO.

IN1T












SAMPLE
TIME
(MIN.)

0
10.0
20.0
30. V
40.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
CLOCK
TIME
(20-HR
f i fir* K i
l»LU(* K t
1358
1408
1418
1428
1438
1448
1458
1508
1518
1528
153B
1548
1558
EVERY 10.0
GAS METER
READING
(CU.FT.)

133.219
138.090
142.910
147.760
152.610
157.480
162.360
167.270
172.140
177.040
182.000
186.900
191.818
MINUTES
VELOCITY
HEAD
(IN.H20)


.052
.052
.052
.052
.052
.052
.052
.052
.052
.052
.052
.052
CLEVELAND
5 IN.HG

ORIFICE

PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
H20)
ACTUAL

.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76
.76

STACK
TEMP
(DEG.F)


500.
458.
465.
476.
452.
477.
490.
458.
465.
476.
458.
477.
DATE 12/12/41
RUN NUKBER 05-5
PROBE LENGTH ft TYPE 5' GLASS
N02/LE : I.D. .434
ASSUMED MOISTURE 13.7
SAMPLE BOX NUMBER
METER BOX NUMBER FBI
METER HEAD OIFF. 1.87
C FACTOR .71
PROBE HEATER SETTING 250.
HEATER BOX SETTING 250.
REFERENCE PRESS. DIFF. .13

DhY GAS fETER
TEMP
(DEG.F)
ULET OUTLET

45. 42.
48. 42.
53. 42.
57. 43.
60. 44.
61. 46.
63. 46.
65. 48.
65. 49.
66. 50.
67. SO.
.67. 51.

PUMP
VACUUM
(IN.HG)


.5
.5
.5
.5
.5
.5
.5
.5
1.0
1.0
1.0
1.0

SAMPLE
BOX TEMP
(OEG.F)


237.
21«.
282.
252.
275.
230.
271.
218.
252.
268.
220.
283.

IMPINGER
TEMP
(DEG.F)


44.
44.
46.
46.
47.
48.
48.
48.
48.
50.
50.
51.
      TOTALS
      AVERAGE
120.0
58.599
                                          .76
                                .76
471.
60,
46.
.7   251.
48,

-------
                PARTICIPATE  FIELD DATA  & RESULTS TABULATION
     PLANT- NAME AND  ADDRESS               TEST  TEAM LEADER
     REPUBLIC  STEEL CLEVELAND              DO
     TEST    D5-5
                COKE STACK
Ul

TEST
TB
TF
TT
NP
Y
ON
CP
PM

DATE
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
ENGLISH UNITS
12/12/81
1358
1558
120.0
12
.992
.434 IN
.63
.76 1N-H20
METRIC UMTS
12/12/81
1358
1558
120.0
12
.992
11.0
.83
19.3



KM

PM-I
          DROP
VM        VOLUME OF DRY GAS SAMPLED
          AT METER CONDITIONS
TM        AVERAGE GAS METER TEMP
VMSTD     VOLUME OF DRY GAS SAMPLED
          AT STANDARD CONDITIONS*
VLC       TOTAL H20 COLLECTED IN
          IMPINGEUS AND SILICA GEL."L.
VHC       VOLUME OF HATER VAPOR
          AT STANDARD CONDITIONS*
BHO       PERCENT MOISTURE BY VOLUME
FMO       MOLE FRACTION DRY GAS
PC02      PERCENT C02 BY VOL.. DRY
P02       PERCENT 02 BY VOL., DRY
PCO       PERCENT CO BY VOL., DRY
PN2       PERCENT N2 BY VOL., DRY
MD        MOLECULAR HT-ORY STACK GAS
MHS       MOLECULAR HT-STACK GAS
 58.599 CU-FT

 52.9   F
 59.671 SCF

177.8

  8.369 SCF
  1.659 CU-M

 11.6   C
  1.690 SCP

177.8

   .237 SCM
12.30
.877
3.70
11.80
.00
84.50
29.06
27.70
12.30
.877
3.70
11.80
.00
84.50
29.06
27.70

-------
    PB

    PSI

    PS

    TS

    VS

    AS

    QSSTD

    OS

    ISO

    MN



    CS

    PMR
BAROMETRIC PRESSURE

STATIC PRES OF STACK GAS

STACK PRES. A3S.

AVERAGE STACK TEMP

AVG STACK GAS VELOCITY

STACK AREA

STACK FLOW RATE* DRY*

ACTUAL STACK FLOW RATE

PERCENT ISOKINETIC



  MG. EPA 5
                EMISSION RATE

       *  68 DEC F,  29.92 IN.HG.
     39.78  IN-HG

     -1.20  1M-H20

     29.69  IN-MG

    471.    F

     17.2   FPS

   7466.   SO-IN

1585882.    SCFH

3213030.    ACFH

     95.0

       .0000



       .00000 GR/DSCF*

       .00000 LB/HR
  756.41  fM-HG

  -30.48  MM-H20

  754.17  MM-HG

  240.    C

    5.2   fPS

    4.817 SO-M

44907.    SCMH

90983.    ACMH

   95.0

     .0000



     .0000 MG/OSCM

     .000 KG/HR
it^
CT>
O

-------
       EXAMPLE  PARTICULATE  CALCULATIONS TfcST  NO.  D5-5

            COKE  STACK




VOLUME OF DRY  GAS  SAMPLED  AT  STANDARD  CONDITIONS

VMSTO  »  (17.607  *  VM •  Y *  (PB  *  PM  /  13.6))  / (TM * 060.)

          17.607 •    58.599  *   .992 * (  29.78 *  .760 / 13.6)
VMSTD  *  ————————.. —	.......	..—...	... -     59.671 OSCF
                         (  53. «• 060.)




VOLUME OF HATER  VAPOR AT STANDARD CONDITIONS

VHC =  .00707 • VLC

VHC *  .00707 *   178. =   B.37 SCF




PERCENT  MOISTURE IN STACK GAS

BHO s  (100. • VHC) / (VMSTD * VHC)

          100. *   8.37
BHO = —	•	* 12.30  PERCENT
            59.671 *    8.37




MOLE FRACTION OF DRY STACK GAS

FMD =  (100. > BHO) / 100.

          100. -   12.3
FMD * —————......... -   .877
               100.




AVERAGE MOLECULAR HEIGHT OF DRY STACK  GAS

MD * (PC02 * .00) * (P02 * .32) *  (PN2 «• PCCI)  *  .28

MO = ( 3.70*00/100) * (11.8*32/100)  *  ((80.5*  .0)  *  28/100  =    29.06




MOLECULAR HEIGHT OF STACK GAS

MHS = MD *  (1. - (BHO/100)) * 18.  *  (BWO/100)

MHS =  29.06* (1. -(12.30/100)) *  18.  * (12.30/100)  =    27.70

-------
     STACK GAS VELOCITY AT STACK CONDITIONS

     DELP s SUM. OF THE SORT(VH * (TS + 460.))

     VS » 85.19 * CP • DELP / (SQRT(MhS * PS) * PNTS)

     VS = 85.09 *  .83 *   83.192 /  (SOWT( 27.70 • 29.69)  *  12. =   17.21 FPS



     STACK GAS VOLUMETRIC FLOH AT STACK CONDITIONS

     OS = VS * AS • 3600/104

     OS s   17.21 *  7066. 3600/100  z    3213030. ACFH



     STACK GAS VOLUMETRIC FLO* AT STANDARD CONDITIONS

     OSSTO z 17.607 * OS * PS * Cl.  - (BwO/100)) / (TS * 060.)

               17.647 *    3213030.  *  29.69 • (1. - (12.30/100))
     OSSTO a	=    1585882. SCFH
                        ( 071. «• 460.)



jp    PERCENT ISOKINETIC

•**•    ISO = (305.58*(TS*060.))*((0.002fc69*VLC)*(VI"'*Y*(PB*(PM/13.6) )/(TM4060.)))/(TT*VS«PS*DN*ON)
o\

M           (305.58*C 071.+060.))*((0.002669*  178.)*(   58.599* ,992*( 29.78M    .760/13.6))/(  53.»060.)))
     ISO s	.	—	=   94.96 PERCENT
                                        120. *     17.21 *   29.69 *  .030 *  .030



     PARTICIPATE LOADING -- EPA METHOD  5 (AT STANDARD CONDITIONS)

     CS * 0.001  * MN • 15.03 / VMSTD

     CS - 0.001  *       .0000 * 15.03 /    59.671 =       .00000 GR/DSCF



     PARTICULATE LBS/HR -- EPA METHOD 5

     PMR = CS  *  OSSTD / (15.03 * 053.6)

     PMR »       .00000 *    1585882. / (15.03 * 053.6)  =      .00000

-------
Run No.  D5.5

                           3
     Sample volume =1.69  m . 59.67  scf


Example  calculations


     CS  (Part)  =15.9/1.69=  9.4  ma/rn3


     CS  (Part)  = 0.001  x 15.9x  15.43/59.67=   0.004qr/dscf
     CS (S02)   =	/.
    .mg/nT
                      x 24.06/_
         .ppm
               = 0.001  x.
.x  15.43/.
gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Water soluble sul fates
As S04I
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


15.9
6.9
5.3
4.5
4.5
2.4

0.0
0.0

0.0



15.6
1.4
3.6
, Concentration,
mg/m


9.4
4.1
3.1
2.7
2.7
1.4

0.0
0.0

0.0



9.2
0.83
2.1
gr/dscf


0.004
0.002
0.001
0.001
0.001
0.001

0.000
0.000

0.000



0.004
0.0004
0.0009
ppm



















                                    A-463

-------
                                                        FIELD  DAT*
        PLANT
        SAMPLING LOCATION

        SAMPLE TYPE
        OPERATOR
        AMBIENT TEMP.(DEC.F)
        BAR.PRESS. UN.MG)
        STATIC PRESS.(IN.H20)
        FILTER NUMBER(S)
        STACK INSIDE DIM.(IN)
        PITOT TUBE COEFF.
        THERM. NO.
        LEAKAGE
        METER CALIB. FACTOR
                     REPUBLIC STEfcL CLEVELAND
                     COKE STACK


                     M8-600

                     DO
                      40.
                     39.78
                     -1.20
                       97.50
                       .83
             ,00
                      .008 CFM 9 I 1.5 IN.HG
                      .967
          DATE                      12/12/81
          HUN NUMBER                 05-6


          PROBE LENGTH ft TYPE       a* GLASS
          NUZZLE      : I.D.         .379
          ASSUMED MOISTURE          13.7
          SAMPLE BOX NUMBER
          PETER BOX NUMBER          FBb
          METER HEAD OIFF.          1.51
          C FACTOR                   .90
          PROBE HEATER SETTING      600.
          HEATER BOX SETTING        600.
          REFERENCE PRESS. DIFF.     .lb
        READ ft RECORD DATA EVERY 10.0 MINUTES
TRAVERSE SAMPLE
POINT TIME
NO. (MIN.)

INIT 0
10.0
> 20.0
^ 30.0
 40.0
*» 50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
CLOCK
TIME
(24-HR
n nrv i
UI.UI* A J
1359
1409
1419
1429
1439
1449
1459
1509
1519
1529
1539
1549
1559
GAS METER VELOCITY ORIFICE PRESSURE STACK
READING HEAD DIFFERENTIAL TE*P
(CU.FT.) (IN.H20) (IN.H20) (DEG.F)
DESIRED
881.913
886.620
891.270
895.980
900.700
905.420
910.120
914.850
919.580
924.320
929.120
933.880
938.607

.052
.052
.052
.052
.052
.052
.052
.052
.052
.052
.052
.052

.55
.55
.55
.55
.55
.55
.55
.55
.55
.55
.55
.55
ACTUAL

.55
.55
.55
.55
.55
.55
.55
.55
.55
.55
.55
.55
DRY GAS METER PUMP SAMPLE
TEMP VACUUM BOX TEMP
(DEG.F) (IN.HG) (DEG.F)
IMPJNGER
TEMP
(OEG.F)
INLET OUTLET

500.
458.
465.
476.
452.
477.
490.
458.
465.
476.
458.
477.

39.
40.
44.
47.
49.
50.
51.
52.
52.
52.
52.
53.

41.
41.
41.
41.
42.
42.
42.
43.
43.
44.
44.
44.

4.3
4.8
7.2
7 .*>
7.5
8.8
10.0
10.3
10.8
11.2
11.0
11.2

555.
598.
620.
620.
623.
608.
607.
605.
600.
594.
587.
586.

42.
42.
44.
46.
4b.
47.
47.
48.
48.
49.
49.
49.
TOTALS
AVERAGE
120.0
56.694
                                         .55
                               .55
471,
48,
42.
                                                                                 6.7
                                                                    600.
46.

-------
               PARTICULATE FIELD 0»T» ft RESULTS TABULATION
    PLANT- NAME AND ADDRESS               TEST TEAM LEADER
    REPUBLIC STEEL CLEVELAND              DO
    TEST   05-6
                COKE STACK
Xn
ENGLISH UNITS METRIC UNITS
TEST
TB
TF
TT
NP
V
DN
CP
PM
DATE
TIME-START
TIME-FINISH
NET TIME OF TEST, MlN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
12/12/81 12/12/81
1359 1359
1559 1559
120.0 120.0
12 12
.967 .967
.379 IN 9.6
.A3 .83
.55 IN-H20 14.0



PM

KM-I
          DROP
VM        VOLUME OF DRV GAS SAMPLED
          AT METER CONDITIONS
TM        AVERAGE GAS METER TEMP
VMSTD     VOLUME OF DRY GAS SAMPLED
          AT STANDARD CONDITIONS*
VLC       TOTAL H20 COLLECTED IN
          IMPINGERS AND SILICA GEL,ML.
VWC       VOLUME OF MATER VAPOR
          AT STANDARD CONDITIONS*
8MO       PERCENT MOISTURE BY VOLUME
FMD       MOLE FRACTION DRV GAS
PC02      PERCENT C02 BY VOL.* DRY
P02       PERCENT 02 BY VOL., DRY
PCO       PERCENT CO BY VOL., ORY
PN2       PERCENT N2 BY VOL., DRY
MO        MOLECULAR HT-DRY STACK GAS
MMS       MOLECULAR MT-STACK GAS
 56.694 CU-FT

 45.4   F
 57.087 SCF

144.1

  6.783 SCF

 10.62
   .894
  3.70
 11 .80
   .00
 84.50
 29.06
 27.89
  1.605 CU-M

  7.4   C
  1.617 SCP

144.1

   .192 SCf

 10.62
   .894
  3.70
 11.80
   .00
 84.50
 29.06
 27.B9

-------
PB




PSI




PS




T3




VS




AS




OSSTO




OS




ISO




MN






CS




PMR
BAROMETRIC PRESSURE




STATIC PRES Of STACK GAS




STACK PRFSr ABS.




AVERAGE STACK TEMP




AVG STACK GAS VELOCITY




STACK AREA




STACK FLOW RATEf DRY*




ACTUAL STACK FLO* RATE




PERCENT ISOKINETIC






  MG. EPA 5
     29.78  IN-HG




     -1.50  IN-H20




     a9.69  IN-HG




    171.    F




     17.?   FPS




   7066.   SQ-IN




161087?.    SCFH




3202302.    ACFH




    117.3




       .0000






       .00000 GR/DSCF*




       .00000 LB/HR
  756. 
-------
            EXAMPLE PARTICULATE CALCULATIONS ttST NO.  D5-6

                 COKE STACK



      VOLUME OF  DRY GAS SAMPLED AT STANDARD CONDITIONS

      VMSTD  * (17.647 • VM • Y * (PB » PM / 13.6)) / (TM + 460.)

                17.647 *    56.694 •  .967 * ( 29.78 «•  .550 / 13.6)
      VMSTD  » ——--—	 —	 —	=     57.087 DSCF
                               t  45. » 460.)



      VOLUME OF  MATER VAPOR AT STANDARD CONDITIONS

      VNC  a  .04707  •  VIC

      VNC  a  .04707  *   144. =   6.78 SCF



      PERCENT MOISTURE IN STACK GAS

      BMO  a  (100. • VNC) / (VMSTD * VWC)

                100.  *   6.78
•.,,     BMO  a  —	———— — —	... = 10.62 PERCENT
 I                57.087 *  6,78
4*.
cn
«j

      MOLE FRACTION OF DRY STACK GAS

      FMD  a  (100. - BMO)  / 100.

                100.  •  10.6
      FMD  s  ——.............	... s   .894
                     100.



      AVERAGE  MOLECULAR  WEIGHT OF DRY STACK  GAS

      MD a (PC02 •  .44)  *  (P02 * .38)  *  (PN2 *  PCO)  * .28

      MD * (  3.70*44/100)  +  (11.8*32/100)  *  1(84.5*  .0)  *  28/100  =   29.06



      MOLECULAR  HEIGHT  OF  STACK GAS

      MhS  a  MD *  (1.  - (BMO/10U))  » 18.  *  (BMO/1UO)

      MWS  a   29.06*  (1.  -(10.62/100))  »  18.  *  (10.62/100)  a   27.89

-------
     STACK GAS VELOCITY AT STACK CONDITIONS

     DELP = SUM. OF THE SQRHVH * ITS * 060.))

     VS * 85.49 * CP » DELP / (SQRUMHS * PS) • PNTS)

     VS = 8S.49 *  .83 *   03.498 / (SQRT( 27.fl9 * 29.69)  *  12. :    17.16 FPS



     STACK GAS VOLUMETRIC FLOW AT STACK CONDITIONS

     US * VS • A3 * 3600/144

     OS =   IT.16 *  7466. 3600/144 =    3202302. ACFH



     STACK GAS VOLUMETRIC FLOH AT STANDARD CONDITIONS

     OSSTD = 17.647 * OS * PS * (1. - (BMO/100)) / (TS * 460.)

               17.647 •    3202302. *  29.69 • (1. - (10.62/100))
     OSSTD = ——	——	.....— ......	. — .	=     1610872. SCFH
                        ( 471. » 460.)



     PERCENT I30KINETIC
>
 |    ISO * (305.5B«(T3«460.))<»((0.002669*VLC)»(VM*Y«(PB+(PM/13.6))/(TM*460.)))/(TT«VS»PS«DN«DN)
.U
J?           (305.5SM 471.+460.))*((0.002669*  144.)+(   56.694* ,967«( 29.78«(    .550/13.6))/(   05.+460.)))
     ISO =	—	"	•	= 117.28 PERCENT
                                        120. *     17.16 •   29.69 •   .379 *  .379'



     PARTICULATE LOADING — EPA METHOD 5 (AT STANDARD CONDITIONS)

     CS = 0.001 • MN * 15.43 / VMSTD

     CS = 0.001 •       .0000 * 15.43 /    57.087 =       .00000 GR/DSCF



     PAHTICULATE LBS/HR — EPA METHOD 5

     PMR = CS * QSSTO / (15.43 * 453.6)

     PHR «       .00000 *    1610872. / (15.43 * 453.6) =      .00000

-------
Run No. D5.6
     Sample  volume =1.62 m3r 57.09  scf
Example calculations
     CS (Part) =12.9/1.62=8.0    mq/m3
     CS (Part) = 0.001 x  12.9X 15.43/57.09 = 0.003  qr/dscf
                                     3
     CS (S02)  =129.0/1.62=  79.6mq/nr
              = 79.6 x 24.06/64   =30  ppm
              = 0.001 x!29.0x 15.43/57.09
0.035 gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sulfates
As H2S04
As H2S04.2H20
Water soluble sulfates
As S04S
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
12.9
0.3
0.4
1.4
129.0
8.2



3 Concentration,
mg/m
8.0
0.2
0.2
0.9
79.6
5.1



gr/dscf
0.0003
0.0001
0.0001
0.0003
0.035
0.002



ppm



30
1



                                     A-469

-------
                                                        FIELD  DATA
        PLANT
        SAMPLING LOCATION
        SAMPLE TYPE
        OPERATOR
        AMBIENT TEMP.(DEC.F)
        BAR.PRESS.(IN.HG)
        STATIC PRESS.(IN.H20)
        FILTER NUMBER(S)
        STACK INSIDE DIM.(IN)
        PITOT TUBE COEFF.
        THERM. NO.
        LEAKAGE
        METER CALIB. FACTOR
                     REPUBLIC STEtL CLEVELAND
                     COKE OUTLET

                     PART/H2S04/S02
                     ARMSTRONG
                      38.
                     29.79
                     -1.20
                       97.75
                       .84

                      .000 CFM a
                     1.003
                        .00
                          6.0 IN.HG
        READ ft RECORD DATA EVERY 10.0 MINUTES
                                                 DATE
                                                 RUN NUMBER
                                                 PROBE  LENGTH  &  TYPE
                                                 NOZZLE       :  I.U.
                                                 ASSUMED  MOISTURE
                                                 SAMPLE BOX  NUMBER
                                                 METER  BOX NUMBER
                                                 METER  HEAD  OIFF.
                                                 C  FACTOR
                                                 PROBE  HEATER  SETTING
                                                 HEATER BOX  SETTING
                                                 REFERENCE PRESS. DIFF.
                                                                                    12/13/81
                                                                                      Ub-1

                                                                                    5 FT GLASS
                                                                      13.7
                                                                       0
                                                                      FB2
                                                                      1.76
                                                                       .78
                                                                      250.
                                                                      250.
                                                                       .15
TRAVERSE
POINT
NO.

SAMPLE
TIME
(MIN.)

CLOCK
TIME
(24-HR
LLUUK >
GAS METER
READING
(CU.FT.)

VELOCITY
HEAD
(IN.H20)

ORIFICE PRESSURE
DIFFERENTIAL
(IN.H20)
DESIRED ACTUAL
STACK
TEMP
(DEG.F)

DRY GAS METER
TEMP
(DEG.F)
INLET OUTLET
PUMP
VACUUM
(IN.HG)

SAMPLE
BOX TEMP
(DEG.F)

IMPINGER
TEMP
(DEG.F)

   INIT
TOTALS
AVERAGE
  0
 10.0
 20.0
 30.0
 40.0
 50.0
 60.0
 70.0
 80.0
 90.0
100.0
110.0
120.0

120.0
 945
 955
1005
1015
1025
1035
1045
1055
1105
1115
1125
1135
1145
531,
535,
539,
544,
548.
552.
557.
561.
565.
570,
574.
578,
583.
010
645
880
220
405
640
145
000
770
135
400
920
020
.050
.046
.048
.045
.046
.050
.047
.045
.047
.045
.050
.045
           52.010
.62
.56
.59
.55
.56
.62
.58
.55
.58
.55
.62
.55
.58
                                                              .62
                                                              .56
                                                              .59
                                                              .55
                                                              .56
                                                              .62
                                                              .58
                                                              .55
                                                              .58
                                                              .55
                                                              .62
                                                              .55
                                                  .58
               ass.
               463,
               465.
               443.
               456.
               463.
               447.
               460.
               460.
               440.
               448.
               461.
                                                455.
35.
38.
41.
44.
44.
44,
45.
45,
46.
46.
46,
06.
                                               43.
35.
35.
35.
35.
36.
36.
37.
38.
37.
38.
40.
40.
        37.
1.5
2.5
2.5
3.0
4.2
4.8
5.1
5.1
5.0
5.0
5.5
5.5
259.
262.
290.
261.
284.
280.
265.
271.
263.
265.
236.
302.
                                                            4.1    270.
41,
39.
40.
40.
40.
45.
47,
45.
45.
46.
52.
54.
                                                         45.

-------
           PARTICIPATE FIELD DATA ft RESULTS TABULATION




PLANT- NAME AND ADDRESS               TEST TEAM LEADER




REPUBLIC STEEL CLEVELAND              ARMSTRONG
TEST   D6-1
COKE OUTLET


TEST DATE
TB
TF
TT
NP
V
DN
CP
PM
i. VM
-J
TM
VMSTD
VLC
VHC
BNO
FMO
PC02
P02
PCO
PN2
MO
MHS
TIME-START
TIME-FINISH
NET TIME OF TEST. MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H20 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF HATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL., DRY
PERCENT 02 BY VOL., DRY
PERCENT CO BY VOL., DRY
PERCENT N2 BY VOL., DRY
MOLECULAR NT-DRY STACK GAS
MOLECULAR WT-STACK GAS
ENGLISH UNITS
12/13/81
945
1105
120.0
12
1.003
.404 IN
.64
.58 IN-H20
52.010 CU-FT
40.1 F
50.917 SCF
153.0
7.202 SCF
11.59
.884
5.10
11.00
.00
83.90
29.26
27.95
METRIC UNITS
12/13/81
945
1145
120.0
12
1.003
10.3
.84
14.7
1.473
4.5
1.555
153.0
.204
11.59
.884
5.10
11.00
.00
83.90
29.26
27.95



KM

PM-H20
CU-M
C
SCM

SCM









-------
PH




PSI



PS



TS




VS




AS



OSSTO




OS




ISO



MN






cs



PMR
BAROMETRIC PRESSURE




STATIC PRES OF STACK GAS




STACK PRES. ABS.




AVERAGE STACK TEMP




AVG STACK GAS VELOCITY




STACK AREA




STACK FLOW RATE* DRY*




ACTUAL STACK FLOW RATE




PERCENT ISOKINETIC






  MG. EPA 5
     29.79  IN-HG




     -1.20  IN-H2U




     39.70  IN-HG




    455.    F




     16.3   FPS




   7505.   SO-IN




1552508.    SCFH




3065694.    ACFH




    103.5




       .0000






       .00000 GR/DSCF*




       .00000 LB/HR
  756.67  *M-HG




  -30.48  PM-H20




  754.42  CM-HG




  235.    C




    5.0   *P3




    4.642 SO-M




43962.    SCMH




66617.    ACPH




  103.5




     .0000






     .0000 MG/DSCM




     .000 KG/HR
            EMISSION RATE



   *  68 DEC f,  29.92 IN.HG.

-------
          EXAMPLE  PARTICULATE  CALCULATIONS  TEST  NO.   06-1

               COKE  OUTLET




    VOLUME OF DRY  GAS  SAMPLED  AT  STANDARD CONDITIONS

    VHSTD =  (17.647  •  VM  *  Y *  (PB  t  PM  / 13.6))  / (TH * 460.)

              17.6*7 •    52.010  •  1.003 •  (  29.79 «•  .577  / 13.6)
    VMSTO =  —. ——.........	...	.....	._	.	=     50.917 OSCF
                             (  40. + 460.)




    VOLUME OF MATER  VAPOR AT STANDARD CONDITIONS

    VMC = .04707 * VLC

    VMC * .04707 *  153.  =   7.20 SCF




    PERCENT  MOISTURE IN STACK GAS

    BMO • (100. *  VMC) /  (VMSTD * VMC)

>             100. •   7.20
I   BMO * ——-——-——	.......  = 11.59  PERCENT
^               54.917 *    7.20
oo


    MOLE FRACTION  OF DRY STACK GAS

    FMO s (100. >  BMO) /  100.

              100. >   11.6
    FMO = -.————	........ ,   .884
                   100.
    AVERAGE MOLECULAR HEIGHT OF DRY STACK GAS

    MO r (PC02 * .44) * (P02 * .32) *  (PN2 * PCO)  *  .28

    MD = ( 5.10*44/100) * (11.0*32/100) » ((83.9*  .0)  * 28/100  a   29.26




    MOLECULAR HEIGHT OF STACK GAS

    MMS = MD • (1. - (BWO/100)) » 18.  * (BWO/100)

    MhS =  29.26* (1. -(11.59/100)) +18. *  (11.59/100) z   27.95

-------
STACK GAS VELOCITY AT STACK CONDITIONS

DELP = SUM. OF THE SORUVH * US » 460.))

VS » 85.49 • CP * OELP / (SQRMMWS * PS) * PNTS)

VS » 85.49 *  .84 •   78.681 / (SORT! 27.95 • 29.70)  *  12. =    16.34  FPS



STACK GAS VOLUMETRIC FLO" AT STACK CONDITIONS

OS = VS * A3 * 3600/144

OS e   10.34 *  7505. 3600/144 =    3065894. ACFH



STACK GAS VOLUMETRIC FLO* AT STANDARD CONDITIONS

OSSTD a IT.647 * (IS • PS * (1. - (BWO/100)) / (TS « 460.)

          17.647 •    3065894. •  29.70 •  (1. • (11.59/100))
OSSTD *	 =     1552508. SCFH
                   ( 455. » 460.)



PERCENT ISOKINETIC

ISO = (305.58*(TS*460.))*({0.002669«VLC)+(VM«YMPB*(PM/13.6))/(TM*460.)))/(TT«VS«PS«DN*ON)

       (305.58»( 455.«460.))*((0.002669*   153.)*(   52.010*1.003*( 29.79*(    .577/13.6))/1   4U. + 460.)))
ISO s	.	s 103.55 PERCENT
                                   120. *     16.34 *   29.70 *   .404 •  .404



PARTICIPATE LOADING — EPA METHOD 5 (AT STANDARD CONDITIONS)

CS s 0.001 * MN * 15.43 / VMSTO

CS s 0.001 •       .0000 * 15.43 /    54.917 =       .00000 GR/DSCF



PARTICIPATE LBS/HR -- EPA METHOD 5

PMR = CS * OSSTD / (15.43 * 453.6)

PUR *       .00000 *    1552508. / (15.43  * 453.6) =      .00000

-------
Run No. D6.1
                          *3
     Sample volume =JL_56_m T 54.92  scf

Example  calculations

     CS  (Part)  =12.2 /1.56=  7.8   mq/m3

     CS  (Part)  =  0.001 x12.2  x 15.43/54.92= 0.003  qr/dscf

     CS  (S02)   =118.3/1.56=  75.8mg/m3

               = 75.8  x 24.06/64  = 28 ppm

               =  0.001 x118.3 x 15.4364.92   = 0.033 gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Water soluble sul fates
As S04=
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
12.2
0.0
0.0
0.0
118.3
13.2



2 Concentration,
mg/m
7.8
0.0
0.0
0.0
75.8
8.5



gr/dscf
0.003
0.000
0.000
0.000
0.033
0.004



ppm



28
2



                                   A-47.5

-------
                                                           FIELD  OAT*
 I


CTt
PLANT REPUBLIC STEEL
SAMPLING LOCATION COKE OUTLET
SAMPLE TYPE PART
OPERATOR ARMSTRONG
AMBIENT TEMP. (DEG.F) 32.
BAR. PRESS. (IN. HG) 29.79
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBEM(S)
STACK INSIDE DIM. (IN) 97.75 .00
PITOT TUBE COEFF. .84
THERM. NO.
LEAKAGE .002 CFM 3 4.
METER CALIB. FACTOR 1.004
READ ft RECORD DATA EVERY 10.0 MINUTES
TRAVERSE SAMPLE CLOCK GAS METER VELOCITY
POINT
NO.

INIT












TIME
(MIN.)

0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
TIME
(24-HR
pi r\ p w \
LLUUK I
947
957
1007
1017
1027
1037
1047
1057
1107
1117
1127
1137
1147
READING
(CU.FT.)

655.605
660.100
664.425
668.850
673.140
677.450
681.980
686.350
690.700
695.000
699.430
704.020
708.370
HEAD
(IN.H20)


.050
.006
.008
.005
.046
.050
.047
.045
.047
.045
.050
.045
CLEVELAND
0 IN.HG
ORIFICE PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.62
.56
.59
.55
.56
.62
.58
.55
.58
.55
.62
.55
H20)
ACTUAL

.62
.56
.59
.55
.56
.62
.58
.55
.58
.55
.62
.55
STACK
TEMP
(DEG.F)


455.
463.
465.
403.
456.
463.
447.
460.
460.
060.
008.
461.
DATE 12/13/81
RUN NUMBER 06-2
PROBE LENGTH ft TYPE o FT GLASS
NOZZLE : I.U. .400
ASSUMED MOISTURE 13.7
SAMPLE BOX NUMBER 0
METER BOX NUMBER FB7
METER HEAD OIFF. I.TI
C FACTOR .76
PROBE HEATER SETTING 250.
HEATER BOX SETTING 250.
REFERENCE PRESS. D1FF. .15
DRY GAS METER PUMP SAMPLE IMP1NGER
TEMP VACUUM
(DEC
INLET

40.
42.
47.
51.
53.
55.
56.
57.
58.
58.
58.
58.
.F) (IN.HG)
OUTLET

38.
38.
38.
40.
40.
42.
43.
44.
44.
46.
46.
47.
.2
.5
.5
.5
.5
.5
.5
.5
.5
.5
.5
.5
BOX TEMP
(DEG.F)


270.
267.
260.
240.
258.
244.
232.
246.
245.
224.
22fc.
260.
TEMP
(DEG.F)


41.
37.
40.
41.
42.
43.
43.
44.
50.
51.
49.
55.
   TOTALS
   AVERAGE
120.0
52.765
                                         .58
                               .58
457.
53.
42.
1.5   248.
45.

-------
           PARTICULATE FIELD DATA ft RESULTS TABULATION
PLANT- NAME AND ADDRESS               TEST TEAM LEADER
REPUBLIC STEEL CLEVELAND              ARMSTRONG
TEST   06-2
                COKE OUTLET
ENGLISH UNITS
TEST
TB
TF
TT
NP
Y
ON
CP
PM
DATE
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
12/13/81
947
1147
120
12
1



.0

.004
.400 IN
.84
.58 IN-H20
METRIC UNITS
12/13/B1
947
1147
120
12
1
10

14
.0

.004
.2
.84
.7



VM

PM-I
          DROP
VM        VOLUME OF DRY GAS SAMPLED
          AT METER CONDITIONS
TM        AVERAGE GAS METER TEMP
VMSTD     VOLUME OF DRY GAS SAMPLED
          AT STANDARD CONDITIONS*
VLC       TOTAL H20 COLLECTED IN
          IMPINGERS AND SILICA GEL,ML,
VMC       VOLUME OF WATER VAPOR
          AT STANDARD CONDITIONS*
BHO       PERCENT MOISTURE BY VOLUME
FMD       MOLE FRACTION DRY GAS
PC02      PERCENT C02 BY VOL., DRY
P02       PERCENT 02 BY VOL., DRY
PCO       PERCENT CO BY VOL., DRY
PN2       PERCENT N2 BY VOL., DRY
MO        MOLECULAR HT-DRY STACK GAS
MhS       MOLECULAR NT-STACK GAS
                                           52.765 CU-FT
1.494 CU-M
47.5 F
54.959 SCF
171.0
8.049 SCF
12.77
.H72
5.10
11.00
.00
83.90
29.26
27.82
8
1
171

12

5
11

83
29
27
.6 C
.556 SCM
.0
.228 SCM
.77
.872
.10
.00
.00
.90
.26
.82

-------
   PB




   PSI




   PS




   T8




   VS




   AS




   OS3TO




   OS




   ISO




   MN






   CS




   PMR
BAROMETRIC PRESSURE




STATIC PRES OF STACK GAS




STACK PRES, ABS.




AVERAGE STACK TEMP




AVG STACK GAS VELOCITY




STACK AREA




STACK FLON RATE* DRV*




ACTUAL STACK FLON RATE




PERCENT ISOKINETIC






  MG. EPA 5
     29.7<»  IN-HG




     -1.20  IN-H20




     29.70  IN-HG




    457.    F




     16.a   FPS




   7505.   SO-IN




1534002.    SCFH




3075956.    ACFH




    107.0




       .0000






       .00000 GR/DSCF*




       .00000 LB/HR
               EMISSION  RATE



      *   68  DEC F,   29.92  IN.H6.
  756.67  KM-HG




  -30.48  PM-H20




  754.03  f»M-MG




  236.    C




    5.0   fPS




    4.842 SO-M




43438.    SCHH




87102.    ACMH




  107.0




     .0000






     .0000 MG/OSCM




     .000 KG/HR
00

-------
      EXAMPLE  PART1CULATE  CALCULATIONS  TEST  NO.   D6-2

           COKE  OUTLET



VOLUME OF DRY  GAS SAMPLED  AT  STANDARD CONDITIONS

VMSTD s  (17.647  * VM *  Y •  (PB  *  PM  / 13.6))  /  (TM  »  060.)

          17.607 *    52.765  *  1.000 *  (  29.79 «•   .577  /  13.6)
VMSTD =  ——— — ——	——.................	...	...  =     54.959 DSCF
                         (  07. » 060.)



VOLUME OF MATER  VAPOR AT STANDARD CONDITIONS

VMC « .00707 • VLC

VMC * .00707 *   171. s   8.05 SCF



PERCENT  MOISTURE IN STACK  GAS

BMO 8 (100. «  VMC) / (VMSTD * VMC)

          100. *   8.05
BMO »	= 12.77  PERCENT
            50.959 «•   8.05



MOLE FRACTION OF DRY STACK GAS

FMD = (100. - BMO) / 100.

          100. -  12.8
FMD s	s    .872
               100.



AVERAGE MOLECULAR HEIGHT OF DRY STACK GAS

MD s (PC02 • .00) * (P02 * .32) *  (PN2 *  PCO) * .28

MD * ( 5.10*00/100) * (11.0*32/100) * ((83.9* .0) • 28/100 =    29.26



MOLECULAR HEIGHT OF STACK GAS

MMS ' MD * (1. - (BMO/100)) «• IB. * (8*0/100)

MMS *  29.26*  (1. -(12.77/100)) +  18. * (12.77/100) s   27.82

-------
    STACK  GAS  VELOCITY  AT  STACK  CONDITIONS

    DELP = SUM.  OF  THE  SORT(VH *  (TS  +  460.))

    VS  s 85.49 •  CP * DEUP /  ISQRT(MWS  »  PS)  •  PNTS)

    V3  = 85.49 *   .84 •    78.751  /  (SGRTl 27.fl? *  89.70)   •   12.  =    16.40  FPS




    STACK  GAS  VOLUMETRIC FLO* AT  STACK  CONDITIONS

    OS  * VS  *  AS  *  3600/144

    OS  *    16.40  •   7505.  3600/144  =    3075958.  ACFH




    STACK  GAS  VOLUMETRIC FLON AT  STANDARD CONDITIONS

    OSSTD  =  17.647  * OS *  PS  * (1.  •  (BNO/100))  /  (TS  *  460.)

              17.647 •     3075958.  •  89.70  «  (I.  -  (12.77/100))
    OSSTO  f	  s    1534002.  SCFH
                       ( 457. *  460.)




>   PERCENT  ISOKINETIC
 I
TO   ISO *  (305.58*(T3*460.))*((0.002669*VLC)*(VM*Y*(PB*(PM/13.6))/(TM+460.)))/ITT*VS*PS*DN*ON)
O
           (305.5BM 457.4460.))*((0.002669*   171.)*(    58.765*1.004*(  89.79*(    .577/13.6))/(  47.»460.)))
    ISO =  —————————.-.. —...................—.....	................................ c 106.99 PERCENT
                                       120.  *      16.40  *    29.70 *   .400  *  .400




    PARTICULATE LOADING — EPA METHOD 5 (AT  STANDARD CONDITIONS)

    CS  s 0.001  *  MN * 15.43 / VMSTD

    CS  r 0.001  *        .0000  * 15.43  /    54.959  =        .00000  GR/DSCF




    PARTICULATE LBS/HR  —  EPA METHOD  5

    PMR >  CS *  OSSTD /  (15.43 •  453.6)

    PMR s       .00000  *    1534002.  /  (15.43  *  453.6) =       .00000

-------
Run No.  D6.2
     Sample volume  = 1.56 m  f 54.96 scf
Example  calculations
     CS  (Part)  =21.1/1.56=  13.5 mg/m3
     CS  (Part)  =  0.001 x 21.1 x 15.43/54.96  =  0.006  qr/dscf
     CS  (S02)   =	/	=	mg/m3
               =	 x 24.06/	=	ppm
               =  0.001 x	x 15.43/	=	
gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Water soluble sul fates
As S04=
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
21.1
5.4
0.0
0.0
0.0


55.2
2.4
403
~ Concentration,
mg/m
13.5
3.5
0.0
0.0
0.0


35.4
1.5
258
gr/dscf
0.006
0.001
0.000
0.000
0.000


0.015
0.0007
0.113
Ppm







IPA contaminated
                                A-481

-------
                                                           FIELD  DATA
00
PLANT REPUBLIC STEEL
SAMPLING LOCATION STACK OUTLET 01
SAMPLE TYPE PART/H2S04/S02
OPERATOR HAN FITZGERALD
AMBIENT TEMP. (DEC. F) 32.
BAR. PRESS. (IN.HG) 29.79
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530059
STACK INSIDE DIM. (IN) 97.75 .00
PITOT TUBE COEFF. .60
THERM. NO. 133
LEAKAGE .002 CFM a) 5.
METER CALIB. FACTOR .982
READ ft RECORD DATA
TRAVERSE
POINT
NO.

IN1T












SAMPLE
TIME
(MIN.)

0
10.0
20.0
30.0
00.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
CLOCK
TIME
(24-HR

945
955
1005
1015
1025
1035
1045
1055
1105
1115
1125
1135
1145
EVERY 10.0
GAS METER
READING
(CU.FT.)

911.166
915.480
919.560
923.675
927.765
931.700
936.000
900.205
900.290
908.480
952.700
957.105
961.260
MINUTES
VELOCITY
HEAD
(IN.H20)


.050
.046
.048
.005
.006
.050
.047
.045
.007
.045
.050
.005
CLEVELAND OHIO
BATTERY
0 IN.HG

ORIFICE

PRESSURE

STACK
DIFFERENTIAL TE"P
(IN.
DESIRED

.60
.58
.60
.58
.58
.63
.60
.57
.59
.58
.60
.57
H20)
ACTUAL

.60
.58
.60
.58
.58
.63
.60
.57
.59
.58
.60
.57
(DEG.F)
DATE 12/13/81
RUN NUMBER 06-3
PROBE LENGTH ft TTf-E a FOOT GLASS
NOZZLE : l.D. .400
ASSUMED MOISTURE 13.2
SACPLE BOX NUMBER
PETER BOX NUMBER FB8
METFR HEAD OIFF. 1.91
PROBE HEATER SETTING 400.
HEATER BOX SETTING 400.
K FACTOR 11628.3

DRY GAS
TEMP
(DEG.

METER

F)

PUMP
VACUUM
(IN.HG)

SAMPLE
BOX TEMP
(DEG.F)

IMPINGER
TEMP
(DEG.F)
INLET OUTLET

455.
063.
065.
443.
455.
463.
047.
060.
060.
000.
446.
461 .

34.
36.
43.
48.
50.
52.
54.
54.
55.
55.
56.
56.

32.
33.
35.
37.
40.
42.
04.
45.
06.
07.
48.
48.

2.5
2.5
2.5
2.5
3.0
4.5
4.5
4.5
5.0
5.0
5.0
5.0

407.
401.
401.
399.
404.
407.
406.
402.
397.
391.
387.
387.

40.
44.
42.
42.
43.
41.
49.
49.
57.
60.
60.
55.
   TOTALS
   AVERAGE
120.0
50.092
                                         .60
                               .60
055.
50.
                                                                          01,
3.9   399.
                                                                                09.

-------
           PARTICIPATE FIELD DATA ft RESULTS TABULATION

PLANT- NAME AND ADDRESS               TEST TEAM LEADER

REPUBLIC STEEL CLEVELAND OHIO         DAN FITZGERALD
TEST   D6-3
STACK OUTLET «1 BATTERY


TEST DATE
TB
TF
TT
NP
Y
DM
CP
PM
1
00 VM
OJ
TM
VMSTO
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
ENGLISH UNITS
12/13/81
945
1 145
120.0
12
.982
.404 IN
.84
.60 IN-H20
50.092 CU-FT
45.5 F
51.232 SCF
METRIC UNITS
12/13/81
945
1145
120.0
12
.982
10.3
.84
15.2
1.418
7.5
1.451



»»

PM-H20
CU-M
C
SO
          AT STANDARD CONDITIONS*

VLC       TOTAL H20 COLLECTED IN
          IMPINGERS AND SILICA GEL,ML.

VMC       VOLUME OF HATER VAPUR
          AT STANDARD CONDITIONS*

BHO       PERCENT MOISTURE BY VOLUME

FMD       MOLE FRACTION DRY GAS

PC02      PERCENT C02 BY VOL., DRY

P02       PERCENT 02 BY VOL., DRY

PCO       PERCENT CO BY VOL., DRV

PN2       PERCENT N2 BY VOL., DRY

MD        MOLECULAR HT-OKY STACK GAS

MHS       MOLECULAR XT-STACK GAS
                                          147.1
                                            6.924 SCF
                                               147.1
                                                  .196 SCC
11.91
.681
5.10
11.00
.00
83.90
29.26
?7.92
11.91
.881
5.10
11.00
.00
83.90
29.26
27.92

-------
    PB

    PS1

    PS

    TS

    VS

    AS

    OSSTO

    OS

    ISO

    MN



    cs

    PMR
BAROMETRIC PRESSURE


STATIC PRES OF STACK GAS


STACK PRES, ABS.


AVERAGE STACK TEMP


AVG STACK GAS VELOCITY


STACK AREA


STACK FLOW RATE, DRY*


ACTUAL STACK FLOW RATE


PERCENT ISOKINETIC



  MG. EPA 5
     29.79  IN-HG


     -1.20  IN-H20


     ?9.70  IN-HG

    455.    F


     16.4   FPS


   7505.   SO-IN

1546066.    SCFH


3067686.    ACFH


     96.9


       .0000



       .00000 GR/OSCF*


       .00000 LB/HR
  756.67  HK-HG


  -30.ae  KM-H20


  754.42  t>M-HG


  235.    C


    5.0   *PS


    4.842 SO-M

43837.    SCKH


BbB68.    ACHH

   96.9


     .0000



     .0000 MG/DSCM


     .000 KG/HR
                EMISSION  RATE

       *   68  OEG F,   29.92  IN.HG.
•^
00

-------
           EXAMPLE PARTICULATE CALCULATIONS TtST NU.  D6-3

                STACK OUTLET «\ BATTERY



     VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

     VMSTD = (17.647 * VM • Y * (PB » PM / 13.6)) /  (TM » 460.)

               17.647 •    50.092 •  .982 * ( 29.79  *  .597 /  13.6)
     VMSTD =	- —	—	—	 — ...... -      51.232  OSCF
                              (  
-------
      STACK GAS VELOCITY AT STACK CONDITIONS

      DELP * SUM. OF THE SQRMVH *  ITS » 460.))

      VS a 85.49 * CP * OELP /  tSQRT(M*S • PS) * PNTS)

      VS * 85.19 *  .84 *   78.678  /  (SORT( 87.92 • 29.70)  •   12. =    16.35 FPS




      STACK GAS VOLUMETRIC FLOW AT  STACK CONDITIONS

      03 s VS * AS • 3600/144

      OS s   16.35 •  7505. 3600/144  =    3067686. ACFH




      STACK GAS VOLUMETRIC FLON AT  STANDARD CONDITIONS

      QSSTD = 17.647 * OS * PS * (1.  • (8WO/100)) / (TS * 060.)

               17.647 *    3067686.  *  29.70 • (1. - (11.91/100))
      OSSTD s ——— — ———-.	...	.....	..... —....— r     1548066. SCFH
                        ( 455. » 460.)




>     PERCENT ISOKINETIC

OT     ISO * (305.58*(TS*460.))*((0.002669*VLC)+(VM*V*(PB»(P*/13.6))/(TM*460.)))/(TT*VS*PS*DN*DN)

            (305.58*( 455.+460.))*((0.002669*  147.)*(   50.092* .982*1 29.79*(    .597/13.6))/(   46.«460.)))
      130 c ............—	..—......................—.....—.	.......................................  x   96.88 PERCENT
                                        120. •     16.35 *   29.70 *   .404 •  .404




      PARTICIPATE LOADING — EPA METHOD s (AT STANDARD CONDITIONS)

      CS * 0.001 * MN « 15.43 / VMSTO

      CS * 0.001 *       .0000 * 15.43 /    51.232 =       .00000 GU/DSCF




      PARTICULATE LBS/HR — EPA METHOD 5

      PMR s CS * OSSTD / (15.43 * 453.6)

      PMR «       .00000 *    1548066. / (15.43 * 453.6) =      .00000

-------
Run No.  D6.3
     Sample volume =  1.45 m  .  51 .?3 scf
Example calculations
     CS (Part)  =  15.6/1.45 = 10.8  mg/m3
     CS (Part)  =  0.001  x 15.6  x  15.43/51.23 = O.QQ5  qr/dscf
     CS (S02)   =113.3/  1.45= 7ft. 1 ma/m3
               =  78.1 x 24.06/M_=_22_Ppm
               =  0.001  xl!3.3  x  15.43/51.23  = 0.034 gr/dscf
. Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Water soluble sul fates
As S04=
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
15.6
1.0
1.4
0.0
113.3
7.5



2 Concentration,
mg/m
10.8
0.7
1.0
0.0
78.1
5.2



gr/dscf
0.005
0.0003
0.0004
0.000
0.034
0.002



ppm



29
1



                                     A-487

-------
                                                            FIELD   DATA
CD
CO
PLANT REPUBLIC STEEL
SAMPLING LOCATION STACK OUTLET U\
SAMPLE TYPE PARTICULAR
OPERATOR DAN FITZGEHALD
AMBIENT TEMP. (DEC. F) 13.
BAR. PRESS. (IN. HG) 29.79
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S) 3530411
STACK INSIDE DIM. (IN) 47.75 .00
PITOT TUBE COEFF. .84
THERM. NO. 133
LEAKAGE .002 CFM a) 3.
METER CALIB. FACTOR 1.033
READ ft RECORD DATA EVERY 10.0 MINUTES
TRAVERSE
POINT
NO.

INIT












SAMPLE
TIME
(MIN.)

0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
eo.o
90.0
100.0
110.0
120.0
CLOCK
TIME
(24-HR
r* i nr* tt )
\f L.UL> n /
947
957
1007
1017
1027
1037
1047
1057
1107
1117
1127
1137
1147
GAS METER
READING
(CU.FT.)
VELOCITY
HEAD
(IN.H20)
CLEVELAND OHIO
BATTEHY
0 IN.HG
ORIFICE PRESSURE
DIFFERENT
(IN.H20)
IAL

STACK
TEMP
(DEG.F)
DESIRED ACTUAL
467.502
471.750
475.770
479.860
483.890
487.955
492.270
496.395
500.485
504.635
508.755
513.195
517.299

.050
.046
.048
,0«5
.046
.050
.047
.045
.047
.045
.050
.045

.64
.58
.60
.58
.58
.63
.60
.57
.59
.58
.64
.57

.64
.58
.60
.58
.58
.63
.60
.57
.59
.5*
.64
.57

455.
463.
465.
443.
455.
463.
447.
460.
460.
440.
448.
389.
DATE 12/13/81
RUN NUMBER D6-4
PROBE LENGTH ft TYPE 5 FOOT GLASS
NOZZLE : 1.0. .404
ASSUMED MOISTURE 13.7
SAMPLE BOX NUMBER
METER BOX NUMBER FB4
METER HEAD OIFF. 1.88
PROBE HEATER SETTING 400.
HEATER BOX SETTING 400.
K FACTOR 11628.3
DHY GAS METER
TEMP
(OEG.F)
INLET OUTLET

38. 38.
43. 40.
49. 42.
55. 45.
59. 48.
62. 52.
64. 54.
65. 55.
66. 57.
67. 58.
68. 60.
68. 60.
PUMP
VACUUM
(IN.HG)


2.0
1.5
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.5
2.0
SAMPLE
BOX TEMP
(DEG.F)


403.
444.
443.
440.
426.
433.
429.
438.
431.
425.
422.
387.
IMPINGER
TEMP
(DEG.F)


42.
48.
42.
45.
41.
46.
48.
52.
52.
55.
57.
55.
   TOTALS
   AVERAGE
120.0
49.797
                                          .60
                               .60
449.
59.
51,
2.0
427.
49.

-------
           PARTICIPATE FIELD DATA ft RESULTS TABULATION




PLANT* NAME AND ADDRESS               TEST TEAM LEADER




REPUBLIC STEEL CLEVELAND OHIO         DAN FITZGERALD
TEST   D6-0
STACK OUTLET »\ BATTfcRY

TEST DATE
TB
TF
TT
NP
Y
ON
CP
PM
>
*» VM
00
VO
TM
VMSTD
VLC
VMC
BHO
FMD
PC02
P02
PCO
pNe
MD
MWS


TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H20 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF HATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL., DRY
PERCENT 02 BY VOL., DRY
PERCENT CO BY VOL., DRY
PERCENT N2 BY VOL., DRY
MOLECULAR NT-DRY STACK GAS
MOLECULAR XT-STACK GAS
ENGLISH UNITS
12/13/81
907
1107
120.0
12
1.033
.000 IN
.64
.60 IN-H20
09. 797 CU-FT
50.7 F
52. M7 SCF
161.7
7.611 SCF
12.60
.670
5.10
11.00
.00
83.90
29.26
27.83
METRIC UNITS
12/13/81
907
1107
120.0
12
1.033
10.3 CM
.80
15.2 *M-H20
1.010 CU-M
12.6 C
1.090 SCW
161.7
.216 SCM
12.60
.870
5.10
11.00
.00
83.90
29.26
27.83

-------
    PB


    PSI


    PS


    TS


    VS


    AS


    QSSTO


    OS


    ISO


    MN



    cs


    PMR
BAROMETRIC PRESSURE


STATIC PRES OF STACK bAS


STACK PRES. ABS.


AVERAGE STACK TEMP


AVG STACK GAS VELOCITY


STACK AREA


STACK FLO* RATE> DRY*


ACTUAL STACK FLOW RATE


PERCENT ISOKINET1C



  MG. EPA 5
                EMISSION RATE


       *   68 DEC F,   29.92 IN.HG.
     29.79  1N-HG


     -1.20  IN-H20


     39.70  IN-HG


    449.    F


     16.3   FPS


   7505.   SQ-IN


15A2579.    SCFH


3062194.    ACFH


     99.9


       .0000



       .00000 GR/DSCF*


       .00000 LB/HR
  7b6.67  fH-HG


  -30.«8  VV-H20


  75a.42  KM»HG


  232.    C


    5.0   PPS


    4.642 SO-M


43b81.    SCMH


8h712.    *CVH


   99.9


     .0000



     .0000 MG/OSCM


     .000 KG/HR
*>
y?
o

-------
      EXAMPLE PARTICULATE  CALCULATIONS  TEST  NO.   D6-4

           STACK OUTLET  01 BATTERY




VOLUME OF DRY GAS SAMPLED  AT  STANDARD CONDITIONS

VMSTO s  (17.647 * VM  * Y « (PB  *  PM  / 13.6))  /  (TM  »  460.)

          17.647 *    49.797  *  1.033 *  (  29.79  *   .597  /  13.6)
VMSTO s	......	.	s      52.617  DSCF
                         (  55. » 460.)




VOLUME OF HATER VAPOR AT STANDARD CONDITIONS

VMC s .04707 * VLC

VMC 3 .04707 *  162. z   7.61 SCF




PERCENT  MOISTURE IN STACK GAS

BNO s (100. * VMC) /  (VMSTO * VNC)

          100. *   7.61
BMO z ~—......................  - 12.64  PERCENT
            52.617 +   7.61




MOLE FRACTION OF DRV STACK GAS

FMO 3 (100. > BMO) / 100.

          100. .  12.6
FMD 3 ....................... 3   .874
               100.




AVERAGE MOLECULAR MEIGHT OF DRY STACK GAS

MD 3 (PC02 * .44)  * (P02 * .32) «• (PN2 * PCO) • .28

MD 3 ( 5.10*44/100) + (11.0*32/100)  » ((83.9+ .0) * 28/100 z   29.26




MOLECULAR HEIGHT OF STACK GAS

MHS 3 MD * (1. - (BHO/100)) + 18. • (BfO/lUO)

MMS 3  29.26* (1.  -(12.64/100)) «• 18. * (12.64/100) 3   27.83

-------
       STACK GAS VELOCITY AT STACK CONDITIONS


       DELP = SUM. OF THE St)RT(VH * (TS + 060.))


       VS s 85.09 • CP • OELP / (SORT(M*S * PS) * PNTS)


       VS a 85.09 •  .80 •   78.021 / (StJRH 37.83 * 89.70)  *  12. =    16.32 FPS




       STACK GAS VOLUMETRIC FLOH AT STACK CONDITIONS


       OS * VS * AS • 3600/140


       OS *   16.32 •  7505. 3600/100 c    3062190. ACFH




       STACK GAS VOLUMETRIC FLOW AT STANDARD CONDITIONS


       OSSTO * IT.607 * OS • PS * (1. - (BWO/100)) / (TS * 060.)


                 17.607 *    3062190. *  29.70 *  (1. - (12.60/100))
       OSSTD =	2     1502579. SCFH
                          ( 009. » 060.)




p      PERCENT ISOKINETIC


*»      ISO s (305.58*(TS*060.))*((0.002669*VLC)+(VM*Y*(PB*(PM/13.6))/(TM+060.)))/(TT*VS«PS*DN*DN)
VO

^             (305.58*( 009.+060.))*((0.002669*   162.)+(   09.797*1.033*( 29.79»(     .597/13.6))/(   55.+060.)))
       ISO * ..............	.	...... —...............	......................	.............. s  99.85 PERCENT

                                          120. *     16.32 *   29.70 *   .000 *   .000




       PARTICIPATE LOADING — EPA METHOD 5 (AT STANDARD CONDITIONS)


       CS * 0.001 • MN * 15.03 / VMSTD


       CS z 0.001 *       .0000 * 15.03 /    52.617 =       .00000 GR/DSCF




       PARTICULATE LBS/HR -- EPA METHOD 5


       PMR s CS • OSSTD / (15.03 * 053.6)


       PMH s       .00000 *    1502579. / (15.03  * 053.6) =      .00000

-------
Run No. D6-4
     Sample volume =1.49  m352.62   scf
Example  calculations
     CS  (Part) =12.0/1.49= 8.0   mq/m3
     CS  (Part) = 0.001 x^-0  x 15.43/52.62=  0.004 qr/dscf
     CS  (S02)  =	/	=	mg/m3
              =	 x 24.06/	=	ppm
              = 0.001 x
.x  15.43/.
gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04-2H20
Water soluble sul fates
As S0a=
Sulfur dioxide
Sul f uric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
12.0
0.0
0.0
0.0


144.2
2.8
77
2 Concentration,
mg/m
8.0
0.0
0.0
0.0


96.8
1.9
51.7
gr/dscf
0.004
0.000
0.000
0.000


0.042
0.0008
0.022a
ppm








I PA contaminated.
                                     A-493

-------
                                                        FIELD  DATA
PLANT REPUBLIC STEEL
SAMPLING LOCATION COKE STACK
SAMPLE TYPE M5-250
OPERATOR 00
AMBIENT TEMP.(OEG.F) 32.
BAR. PRESS. (IN. HG) 29.79
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S)
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE CUEFF. .83
THERM. NO.
LEAKAGE .000 CFM a) 3.
METER CALIB. FACTOR .992
READ K RECORD DATA
TRAVERSE
POINT
NO.

INIT












SAMPLE
TIME
(MIN.)

0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
CLOCK
TIME
(24-HR
ft nt* w \
LLULK 1
945
955
1005
1015
1025
1035
1045
1055
1105
1115
1125
1135
1145
EVERY 10.0
GAS METER
READING
(CU.FT.)

191.991
197.190
202.330
207.560
212.780
218.010
223.260
228. 510
233.810
239.120
24a.430
249.750
255.077
MINUTES
VELOCITY
HEAD
(IN.H20)


.050
.050
.050
.050
.050
.050
.050
.050
.050
.050
.050
.050
CLEVELAND
0 IN.HG

ORIFICE

PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.89
.89
.89
.89
.89
.89
.89
.89
.89
.89
.89
.89
H20)
ACTUAL

.89
.89
.89
.89
.89
.89
.89
.89
.89
.89
.89
.89

STACK
TEMP
(DEG.F)


455.
463.
465.
443.
455.
463.
447.
460.
460.
440.
448.
461.
DATE 12/13/81
HUN NUMBER D6-5
PBUBfc LENGTH S TYPE 6* GLASS
NUZZLE : I.U. .431
ASSUMED MOISTURE 11.0
SAMPLE BOX NUMBER
METER BOX NUMBER FBI
METER HEAD DIFF. 1.37
C FACTOR .86
PROBE HEATER SETTING 250.
HEATER BOX SETTING 250.
REFERENCE PRESS. DIFF. .10

DRY GAS METER
TEMP
(DEG.F)
ULET OUTLET

37. 33.
41. 33.
49. 35.
55. 37.
59. 40.
62. 43.
63. 45.
65. 46.
65. 48.
66. 48.
67. 49.
67. 50.

PUMP
VACUUM
(IN.HG)


2.1
2.1
2.2
2.2
2.2
2.2
2.2
2.3
2.2
2.2
2.2
2.2

SAMPLE
BOX TEMP
(DEG.F)


271.
251.
289.
275.
267.
273.
258.
267.
266.
265.
264.
263.

IMPINGER
TEMP
(OEG.F)


42.
42.
43.
44.
44.
44.
46.
47.
48.
48.
48.
50.
TOTALS
AVERAGE
120.0
63.086
                                         .89
                               .89   455,
58.
                                                                         42.
2.2
267.
46.

-------
           PARTICIPATE FIELD DATA A RESULTS TABULATION
PLANT- NAME AND ADDRESS               TEST TEAM LEADER
REPUBLIC STEEL CLEVELAND              no
TEST   06-5
COKE STACK


TEST DATE
TB
TF
TT
NP
Y
ON
CP
PM
> VM
>t»
VD
01 TM
VMSTD
VLC
VHC
BMO
FMO
PC02
poa
PCO
PN2
HO
MW3
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H20 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF HATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRY GAS
PERCENT C02 BY VOL., DRY
PERCENT 02 BY VOL., DRY
PERCENT CO BY VOL., DRY
PERCENT N2 BY VOL., DRY
MOLECULAR HT-ORY STACK GAS
MOLECULAR WT-STACK GAS
ENGLISH UNITS
12/13/Bi
905
lias
120.0
IS
.992
.031 IN
.83
.89 IN-H20
63.086 CU-FT
50.1 F
64.634 SCF
191.1
8.995 SCF
12.22
.878
5.10
11.00
.00
83.90
29.26
27.88
METRIC UNITS
12/13/81
945
1145
120.0
12
.992
10.9
.83
22.6
1 .786
10.1
1.830
191.1
.255
12.22
.878
5.10
11.00
.00
83.90
29.26
27.88



*M

KM-H20
CU-M
C
sec

sen









-------
    PB
    P3I
    PS
    TS
    VS
    AS
    OSSTO
    OS
    ISO
    HN

    CS
    PMR
BAROMETRIC PRESSURE
STATIC PRES OF STACK GAS
STACK PRES, ABS.
AVERAGE STACK TEMP
AV6 STACK GAS VELOCITY
STACK AREA
STACK FLO* RATE, ORT*
ACTUAL STACK FLOW RATE
PERCENT ISOKINEUC

  MG. EPA 5
     29.79  IN-HG
     -1.20  IN-H20
     29.70  IN-HG
    «55.    F
     16.7   FPS
   7066.   SO-IN
1565391.    SCFH
3112999.    ACFH
    105.7
       .0000

       .00000 GR/DSCF*
       .00000 LB/HR
  756.67  VM-HG
  -30.18  VM-H20
  754.«2  *M-MG
  235.    C
    5.1   *PS
    a.817 SO-M

VD

-------
           EXAMPLE PARTICULATE CALCULATIONS TEST NO.  06-5

                COKE STACK




     VOLUME OF  DRY GAS SAMPLED AT STANDARD CONDITIONS

     VMSTD  * (17.647 • VM * Y * (PB + PM / 13.6)) / (TM » 460.)

               17.647 *    63.066 •  .992 • ( 29.79 »  .890 / 13.6)
     VMSTD  = ———-.———..................	...	... —.	     64.634 DSCF
                              I  50. * 460.)




     VOLUME OF  MATER VAPOR AT STANDARD CONDITIONS

     VNC  s  .04707  • VLC

     VNC  «  .04707  *  191. z   9.00 SCF




     PERCENT MOISTURE IN STACK GAS

   ~  BHO  8  (100. * VNC)  / (VMSTD  » VNC)

               100. *   9.00
>    BMO  s	s  12.22 PERCENT
J.,               64.634  »   9.00
VD
~J

     MOLE FRACTION OF DRY STACK GAS

     FMD  •  (100. - BMO)  / 100.

               100. •  12.2
     FMD  »  •••—................. z   .678
                    100.




     AVERAGE MOLECULAR HEIGHT OF  DRY STACK GAS

     MD e (PC02  •  .44)  *  (P02 • .32)  •» (PN2 » PCO)  * .28

     MD z (  5.10*44/100)  * (11.0*32/100)  + KB3.9+  .0)  •  28/100 =   29.26




     MOLECULAR WEIGHT OF  STACK GAS

     MMS  z  MD *  (1. • (BMO/100))  * 18. *  (BftO/100)

     MMS  =   29.26* (1.  -(12.22/100))  * 18. *  (12.22/100)  =   27.88

-------
     STACK  GAS VELOCITY AT  STACK  CONDITIONS

     DELP * SUM.  OF THE SORT(VH * (TS *  460.))

     VS » 85.49 * CP *  OELP /  (SQRT(MHS  *  PS)  * PNTS)

     VS = 65.49 *  .63  *   61.166 /  (SORT(  27.88 •  29.70)   *   12.  =   16.68 FPS



     STACK  GAS VOLUMETRIC FLO*  AT STACK  CONDITIONS

     OS : VS * AS * 3600/144

     OS a   16.66 *  7466.  3600/144  a    3112999.  ACFH



     STACK  GAS VOLUMETRIC FLON  AT STANDARD  CONDITIONS

     OSSTD  * 17.647 * OS *  PS  * (I.  - (BWU/100)) /  (TS  *  460.)

               17.647 •    3112999.  * 29.70  *  (1.  -  (12.22/100))
     OSSTD  = ———————............	...—..... —........  =    1565391. SCFH
                        ( 455.  +•  460.)



>    PERCENT ISOKINETIC
I
^    ISO «  (305.58*(TS»460.))*((0.002669*VLC)«(VM*Y*(PB«(PM/13.6))/(TM*460.)))/(TT*VS*PS*UN*DN)
CO
            (305.58*( 455.+460.))*((0.002669*   191.)»{    63.066*  .992M  29.79*(    .890/13.6))/(  50.«060.)))
     ISO a	.	.	.	—	= 105.66 PERCENT
                                        120.  *      16.68  *    29.70 *   .431  *  .431



     PARTICULATE  LOADING — EPA METHOD 5 (AT  STANDARD CONDITIONS)

     CS a 0.001  * MN •  15.43 /  VMSTO

     CS s 0.001  *       .0000  * 15.43 /     64.634  =        .00000  GR/DSCF



     PARTICULATE  LBS/HR --  EPA  METHOD 5

     PMR s  CS *  OSSTO / (15.43  *  453.6)

 "   PMR =        .00000 *    1565391. /  (15.43  • 453.6) s       .00000

-------
Run No. D6.5
     Sample volume  =1.83 m  T 64.63 scf
Example calculations
     CS (Part)  =19.9/1.83 = 10.9  mq/m3
     CS (Part)  =  0.001  x!9.9 x  15.43/64.63 = 0.005   qr/dscf
     CS (S02)   =	/.
    . mg/nT
                      x  24.06/_
         .ppm
               =  0.001  x
.x 15.43/.
gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Water soluble sul fates
As S04=
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg


19.9
13.6
12.8
11.5
11.3
4.4

0.0
0.0

0.0



10.0
2.4
8.0
3 Concentration,
mg/m


10.9
7.4
7.0
6.3
6.2
2.4

0.0
0.0

0.0



5.5
1.3
4.4
gr/dscf


0.005
0.003
0.003
0.003
0.003
0.001

0.000
0.000

0.000



0.002
0.0006
0.002
ppm



















                                    A-499

-------
                                                             FIELD   DATA
O
O
PLANT REPUBLIC STEtL
SAMPLING LOCATION CUKE STACK
SAMPLE TYPE M8-600
OPERATOR DO
AMBIENT TEMP. (DEG.F) 32.
BAR. PRESS. (IN.HG) 29.79
STATIC PRESS. (IN. H20) -1.20
FILTER NUMBER(S)
STACK INSIDE DIM. (IN) 97.50 .00
PITOT TUBE COEFF. .83
THERM. NO.
LEAKAGE .000 CFM * 7.
METER CALIB. FACTOR .967
READ & RECORD DATA
TRAVERSE
POINT
NO.

INIT












SAMPLE
TIME
(MIN.)

0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
CLOCK
TIME
(24-HR

946
956
1006
1016
1026
1036
1046
1056
1106
1116
1126
1136
1146
EVERY 10.0
GAS METER
READING
(CU.FT.)

938.892
943.070
947.250
951.440
955.650
959. BIO
964.000
968.220
972.420
976.620
980.820
985.060
989.293
MINUTES
VELOCITY
HEAD
(IN.H20)


.050
.050
.050
.050
.050
.050
.050
.050
.050
.050
.050
.050
CLEVELAND
0 IN.HG

ORIFICE

PRESSURE
DIFFERENTIAL
(IN.
DESIRED

.43
.43
.43
.43
.43
.43
.43
.43
.43
.43
.43
.43
H20)
ACTUAL

.43
.43
.43
.03
.03
.43
.43
.43
.43
.43
.43
.43

STACK
TEMP
(DEG.F)


455.
463.
465.
443.
455.
063.
447.
460.
460.
440.
048.
461.
DATE 12/13/81
RUN NUMBER 06-6
PROBE LENGTH ft TYPE 4* GLASS
NOZZLE : I.D. .378
ASSUMED MOISTURE 11.0
SAMPLE BOX NUMBER
METER BOX NUMBER FB6
METER HEAD OIFF. 1.51
C FACTOR .70
PRUBE HEATER SETTING 600.
HEATER BOX SETTING 600.
REFERENCE PRESS. OIFF. .21

DRY GAS METER
TEMP
(DEG.F)
INLET OUTLET

33. 35.
35. 35.
40. 35.
44. 36.
47. 37.
48. 38.
49. 39.
50. 00.
50. 00.
51. 01.
51. 01.
51. 41.

PUMP
VACUUM
(IN.HG)


3.5
3.8
3.9
3.8
4.0
4.9
5.4
5.6
5.7
5.8
6.5
6.8

SAMPLE
BOX TEMP
(OEG.F)


568.
598.
622.
612.
610.
611.
613.
615.
613.
613.
606.
605.

IMPINGER
TEMP
(DEG.F)


40.
40.
41.
41.
42.
42.
43.
44.
46.
Oh.
08.
51.
    TOTALS
    AVERAGE
120.0
50.001
                                         .43
                               .43   455.
46.
38.
5.0   607.
44.

-------
           PARTICULATE FIELD DATA ft RESULTS TABULATION
PLANT- NAME AND ADDRESS               TEST TEAM LEADER
REPUBLIC STEEL CLEVELAND              DO
TEST   D6-6
COKE STACK


TEST DATE
TB
TF
TT
NP
Y
ON
CP
PM
1
Ln
0 VM
TM
VMSTO
Vlt
VNC
BNO
FMD
PC02
P02
PCO
PN2
MD
MMS
TIME-START
TIME-FINISH
NET TIME OF TEST, MIN.
NET SAMPLING POINTS
METER CALIBRATION FACTOR
SAMPLING NOZZLE DIAMETER
PITOT TUBE COEFFICIENT
AVERAGE ORIFICE PRESSURE
DROP
VOLUME OF DRY GAS SAMPLED
AT METER CONDITIONS
AVERAGE GAS METER TEMP
VOLUME OF DRY GAS SAMPLED
AT STANDARD CONDITIONS*
TOTAL H20 COLLECTED IN
IMPINGERS AND SILICA GEL, ML.
VOLUME OF NATER VAPOR
AT STANDARD CONDITIONS*
PERCENT MOISTURE BY VOLUME
MOLE FRACTION DRV GAS
PERCENT C02 BY VOL., DRY
PERCENT 02 BY VOL., DRY
PERCENT CO BY VOL., DRY
PERCENT N2 BY VOL., DRY
MOLECULAR NT-DRY STACK GAS
MOLECULAR NT-STACK GAS
ENGLISH UNITS
12/13/81
946
1146
120.0
12
.967
.378 IN
.83
.43 IN-H20
50.401 CU-FT
42.0 F
51.098 SCF
149.2
7.023 SCF
12.08
.879
5.10
11.00
.00
83.90
29.26
27.90
METRIC UNITS
12/13/81
94b
1146
120.0
12
.967
9.6
.83
10.9
1.427
5.5
1.447
149.2
.199
12.08
.879
5.10
11.00
.00
83.90
29.26
27.90



KM

MM-H20
CU-M
C
SCf

SCP









-------
PB




PSI




PS



TS



V3




AS



QSSTD




OS




ISO



MN






cs



PMR
BAROMETRIC PRESSURE




STATIC PRES OF STACK GAS



STACK PRESr A8S.



AVERAGE STACK TEMP




AVG STACK GAS VELOCITY




STACK AREA



STACK FLO* RATE* DRY*



ACTUAL STACK FLOW RATE




PERCENT ISOKINETIC






  MG. EPA 5
            EMISSION RATE



   *  68 DEG F,  29.93 IN.HG.
     29.79  IN-HG




     -1.20  IN-H20




     29.70  IN-HG




    455.    F




     16.7   FPS




   7466.   SO-IN




1567349.    SCFH




3112161.    ACFH




    108.5




       .0000       r






       .00000 GR/DSCF*




       .00000 LB/HR
  756.67  KM-HG




  -30.48  KM-H20




  754.42  PM-HG




  235.    C




    5.1   fPS




    4.817 SQ-M




44383.    SCVH




88127.    ACMH




  108.5




     .0000






     .0000 MG/DSCM




     .000 KG/HR

-------
            EXAMPLE PARTICULATE CALCULATIONS  TEST  NO.   06-6

                 COKE STACK



      VOLUME OF DRY GAS SAMPLED AT STANDARD CONDITIONS

      VMSTO * (17.647 • VM • Y *  (PB * PM  / 13.6))  /  (TM  * 460.)

                17.647 •    50.401 •  .967 *  (  29.79  »  .430  /  13.6)
      VMSTD « ————— — — .-——..............—...	=      51.098  DSCF
                               (  42. * 460.)



      VOLUME OF WATER VAPOR AT STANDARD CONDITIONS

      VXC = .04707 * VLC

      VMC » .04707 *  149. =   7.02 SCF



      PERCENT MOISTURE IN STACK GAS

      8x0 » (100. • VWC) / (VMSTD * VNC)

                100. *   7.02
 >    BNO e -—————- — — - — -. = 12.08  PERCENT
 I                 51.098 «•   7.02
 Ui
. o  	
 co

      MOLE FRACTION OF DRY STACK GAS

      FMD s (100. - BMO) / 100.

  	           100. -  12.1
      FMD » ———————— :   .879
                     100.



      AVERAGE MOLECULAR HEIGHT OF DRY STACK GAS

      MD x (PC02 * .44)  * (P02 • .32) * (PN2 •»  PCO) • .28

      MO * ( 5.10*44/100) •» (11.0*32/100) » ((83.9+ .0) * 28/100 =   29.26




      MOLECULAR HEIGHT OF STACK GAS

      MMS z MD * (1. - (BHO/100))  » 18. • (B*0/10U)

	   MHS =  29.26* (1.  -(12.08/100)) » 18. * (12.08/100)  *   27.90

-------
     STACK  GAS  VELOCITY  AT  STACK  CONDITIONS

     OELP = SUM.  OF  THE  SORT(VH *  (TS  *  360.))

     VS  a 85.09 •  CP * OELP /  (SU»T(MHS  *  PS)  • PNTS)

     VS  s 85.49 *  .83 *    B1.166  /  (SO»T( 27.90  •  29.70)   »   12.  -    16.67  FPS



     STACK  GAS  VOLUMETRIC FLOW AT  STACK  CONDITIONS

     OS  = VS  *  AS  *  3600/100

     OS  =    16.67  *   7466.  3600/144  =    3112161. ACFH



     STACK  GAS  VOLUMETRIC FLON AT  STANDARD CONDITIONS

     OSSTO  =  17.647  * OS *  PS * (1.  -  (BHO/100))  /  (TS  + 460.)

               17.647 *     3112161.  •  29.70  *  (1.  -  (12.08/100))
     OSSTD  =  —	  =    1567349.  SCFH
                        ( 455. »  460.)



     PERCENT  ISOKINETIC

^    ISO =  (305.58*(TS*460.))*((0.002669*VLC)*(VM*Y«(PB*(PM/13.6))/(TM«460.)))/(TT«VS*PS*DN«ON)
O
*•           (305.5B*( 455.4460.))*((0.002669*   149.)+(   50.401*  .967*(  29.79+(    .430/13.6))/(   42.4460.)))
     ISO =  ———....................	..............—.....	....................................... = 108.46 PERCENT
                                        120.  *      16.67 *   29.70  *   .378 •   .378



     PARTICIPATE LOADING -- EPA METHOD 5 (AT  STANDARD CONDITIONS)

     CS  = 0.001 *  MN • 15.43 / VMSTD

     CS  > 0.001 *        .0000 * 15.43  /    51.098 =        .00000  GR/DSCF



     PARTICULATE LBS/HR  --  EPA METHOD  5

     PMR =  CS • OSSTD /  (15.43 *  453.6)

     PMR s        .00000  *    1567349.  /  (15.43  *  453.6) «       .00000

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Run No. D6.6
     Sample volume  =  1.45 m3.51.10  scf
Example  calculations
     CS  (Part)  =  9.2  /1.45=  6.3   mq/m3
     CS  (Part)  =  0.001  x  9.2  x 15.43/51.10=  0.003 qr/dscf
     CS  (S02)   =110.1/1.45=  75.9 mq/m3
               = 75.9  x 24.0(5/64  = 28 ppm
               =  0.001  x  IIO.Ix 15.43/51.0   = 0.033 gr/dscf
Parameter
Particulate following
conditioning at:
Ambient
2-h at 350°F
4-h at 350°F
2-h at 400°F
4-h at 400°F
2-h at 600°F
Acid sul fates
As H2S04
As H2S04.2H20
Water soluble sul fates
As S04=
Sulfur dioxide
Sulfuric acid mist
As H2S04
Inorganic condensibles
Organic condensibles
TOC (Condensible)
Catch weight,
mg
9.2
0.2
0.3
0.0
110.1
11.4



o Concentration,
mg/m
6.3
0.1
0.2
0.0
75.9
7.9



gr/dscf
0.003
0.0001
0.0001
0.000
0.033
0.003



ppm



28
2



                               , A-505

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