EMB Reoort No. 78rOCM-12A
                                  November 1980
                   R   POLLUT
              EMISSION   TEST
  CD
O
LH
SOCMI - Fugitive Emissions
     Ethylene Production
                     Union Carbide Corporation

                      Torrance, California
                        November 1980
          UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
                 Office of Air and Waste Management
               Office of Air Quality Planning and Standards
                   Emission Measurement Branch
                Research Triangle Park. North Carolina

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                                EMB Report No. 78-OCM-12A
  Emission Test Report
          SOCMI
   Fugitive Emissions
   Ethylene Production
Union Carbide Corporation
  Torrance, California
     November  1980

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I.  Introduction
    Under the Clean Air Act, as amended, the Environmental Protection
Agency is required to develop standards of performance for new stationary
sources.  These standards are based on the best systems of emission reduction
(considering costs) that have been demonstrated.  EPA is currently developing
a standard for fugitive emissions from synthetic organic chemical manufacturing
processes, and testing was performed at this facility to gather data for
this study.
     Testing was performed at Union Carbide Corporation's ethylene unit at
Torrance, California during October 13-19, 1978.  Emission Standards and Engineering
Division, EPA and Engineering Science, Inc., Arcadia, California, personnel
performed the testing.
     The purpose of the field study was to perform a complete individual equipment
survey with a portable VOC analyzer to measure the local VOC concentration
around the item's potential leak source, and based on that data, compute the
frequency of occurrence of leaks based on different concentration-limit criteria.
     A second purpose was to compare the effectiveness of an area monitoring system
in this unit for indicating the presence of leaks when an overall equipment survey
is used as a base for comparison.  Unit walkthrough surveys with a portable
analyzer were also conducted for comparison of leak detection effectiveness.
     Finally, vapor and liquid samples were collected from selected sources
for chromatographic analysis to compare vapor-liquid distributions of individual
organic compounds.

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II.   Summary of Results
      The results of individual component surveys are presented in Table II-l.
The frequency of occurrence of VOC readings in various ranges are presented
for each general equipment type and for all equipment screened.  The results
of the walkthrough surveys will be analyzed in a separate report.  Due to
the relatively high frequency of occurrence of VOC concentrations >10,000 ppmv
for all equipment types and the lack of elevated readings from the fixed point
monitoring, it appears that the fixed monitors in use are ineffective for
identifying these fugitive emission sources.  However, the monitors were designed
for personnel "exposure and detecting explosive mixture formations and not
for fugitive emissions'--control.
      In one area of the unit, a repeat screening of individual equipment
was conducted.  The separation area storage tanks were first tested on
October 16, and were retested three days later.  During the repeat test,
different instrument operators and data recorders performed portions of
testing.  Also the individual components were not uniquely identified.
Therefore the results presented in Table II-2 represent the combined varia-
                                                                ^
bilities resulting from method repeatibility (different instrument operators),
item identification (different data recorders) and variations  in  leak
magnitude.   As can be observed in Table II-2, the reproducibility was
good for concentration results less than 200 ppm and greater than 10,000 ppm.
For measurements between these two points, the data were more often different
than they were the same.
      The field data sheets are included in Appendix B.

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      The results of the chromatographic analysis of vapor and liquid
samples are given in detail in Appendix A.  This appendix incorporates
the report prepared by Engineering Science, Inc. for EPA describing the
methods used and complete results.  Sample identifications are given in
Table 11-3.  For the purposes of  this study, the compounds were identified
and grouped by elution times equivalent to normal paraffins.  It is expected
that the majority of the compounds "measured were actually unsaturated olefins.
III.  Process Description
      Union Carbide's Torrance chemical plant thermally cracks purified
refinery gas and distills the product to make ethylene and acetylene.  The
ethylene is then used to produce  polyethylene.  The plant was started up
in  1956 and has been in almost continuous operation since that time.  The
plant was  operating normally throughout the test period.
IV.   Sampling and Analytical Procedures
      The  instrument used to conduct surveys at this facility was a Century
Systems Corporation OVA-108 organic vapor analyzer.  The instrument was
calibrated daily at the test site.  Methane in air standards were used.
      Unit walkthrough surveys were performed by first identifying a proposed
path so that the unit perimeter would be traversed, and that all pumps and
control valves at ground level would be surveyed within a distance of 1 meter.
The instrument was then carried through the unit along this path with concen-
trations and location notations recorded on a strip chart recorder.
      Individual component surveys were performed by traversing at the surface
of the potential leak interface to determine local VOC concentrations.  The
highest observed concentration was recorded on a field data sheet.
      The procedures used to collect and analyze the vapor and liquid samples
are described in Appendix A.

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              Table II-l:  Summary - Number of Components Versus VOC
Concentration at 0 Centimeters from the Source; Union Carbide Corporation, Torrance, California
VOC Concentration
ppm as hexane
< 200
201-1000
1001-10000
> 10000
Total
Equipment Type
Pump
Seals
#
30
9
1
11
51
%
59
18
2
21

Control
Valves
#
85
13
5
25
128
%
66
10
4
20

Other
Vatves
#
1554
203
108
436
2301
%
67
9
5
19

Open Ended
Lines
#
287
40
16
•43
386
%
74
10
4
11


#





%






#





%





Compressor
Seals
#
3
10
4
25
42
%
7
24
10
59

Total
Equipment
#
1959
275
134
540
2908
%
67
9
5
19















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                    Table II-2:  Summary of Results
           Repeat Screening of Separation Area Storage Tanks
Test A:  10/16/78
Test B:  10/19/78
voc
Concentration
0-200
201-1000
1001-10000
> 10000
Measurements
with same result *
Number
77
6
11
65
%
85
24
44
93
Measurements
with different result
Number
14
19
14
5
%
15
76
56
7
  *Test A used as reference for determining VOC range.

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                   Table II-3:  Liquid and Vapor Sample
                      Identification and Descriptions
Sample Number
577 000 089

        090

        091

        092

        093

        094
        095

        096

        097

        098

        099

        100

        101

        102

        103

        104
        105
        106
        107
Collection Location
Separation Area, Pump
DH 38
Separation Area Tank
Farm
Separation Area Acetone
Storage Tank
Separation Area Crude Drip
Storage Tank
Separation Area 1#
Res. H.E. Liquid Trap
Separation Area Pump
#38
Separator Area Concentrates
column kettle
Separation Area Vent
column bottoms
Separation Area - Vent
column bottoms
Separation Area - Dripolene
still bottoms
Separation Area - C^
column bottoms
Separation Area - C3
column
Separation Area - Ethylene
product pump
Separation Area - 0# propane
subcooler on primary pump
Cooling Tower Water Inlet
Cooling Tower Water Outlet
Glycol/Water Cooler
Liquid Concentrates Vaporizer
Sample Type
Vapor leak from
pump seal
Ambient vapor
sample
Vapor - Leak from
valve
Vapor - Leak from
valve
Vapor - Leak from
valve
liquid from trap
Vapor - Leak from
pump seal
Vapor leak from
open-ended line
Vapor leak from
control valve
Liquid from.
control valve loop
Liquid
Liquid
Vapor leak from
gauge valve
Vapor leak from
valve
Vapor leak from
valve
Liquid
Liquid
Vapor
Vapor leak from
control valve

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                            Table II-3, Continued
Sample Number
         108
         109

         110

         111

         112
         113

         114

         115
         116
         117
Collection Location
Furnace Area Clarifier
Furnace Area Clarifier
feed liquid
Furnace Area Clarifier
overflow effluent
Separator Area Storage
water seal drum on N 2
dripolene storage
Separation Area C2H. Mix
storage tank
Wastewater Treatment Area

Wastewater Treatment Area
Wastewater Separator
Wastewater Separator
feed
Sample Type
Vapor over clarifier
Liquid

Liquid

Vapor over drum

Liquid in drum

Vapor ^ Leak from
drain valve
Vapor  - Leak from
covered manway
Carbon cannister vent
Liquid - water discharge
Liquid

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     APPENDIX  A
LABORATORY  REPORT

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            VOC EMISSIONS FROM A

      POLYETHYLENE MANUFACTURING PLANT
            Contract  68-02-2815
            Work Assignment  28
               Submitted to:

   U. S. Environmental Protection Agency
Office of Air Quality Planning and Standards
   Research Triangle Park, North Carolina
               Submitted by:

            Engineering-Science
            7903 Westpark Drive
              McLean, Virginia
                 April 1979

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                             DRAFT
                            TABLE .OF CONTENTS

                                                                   Page

SECTION I           INTRODUCTION                                     1-1

SECTION II          SUMMARY OF RESULTS                               II-l

SECTION III         ANALYTICAL PROCEDURES                            III-l
                       Field Testing                               III-l
                       Laboratory Analysis of Liquid
                         and Head Space Samples                    II1-2
APPENDIX A          RETENTION TIME DATA
APPENDIX B          STANDARDIZATION RESULTS
APPENDIX C          CALCULATIONS AND DATA WORKSHEETS

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                               DRAFT


                                  SECTION  I
                               INTRODUCTION

     The United States  Environmental  Protection Agency, Office of Air Quality
Planning and Standards  (OAQPS)  is  currently investigating the magnitude and
nature of fugitive volatile organic carbon (VOC) emissions from petrochemical
plants for the purpose  of recommending appropriate emission standards for that
industry.  Engineering-Science  was issued  Task Order Number 22 under Contract
Number 68-02-2815 to provide field testing capabilities for development of
fugitive emission data  from a petroleum refinery.
     The field test program was conducted  at the Union Carbide Corporation's
Torrance, California polyethylene  facility during the period from October 19,
1978.  The test program utilized two  portable total hydrocarbon analyzers
(Century Organic Vapor  Analyzer, OVA) and  a TRACOR Model 550 gas chromatograph
(gc) equipped with dual flame ionization detectors.  This report presents only
test results obtained with the  gc.
     The remainder of this report  is  divided into two sections as follows:
     Section II - Summary of Results
     Section III - Analytical Procedures
In addition, example calculations, and laboratory data are presented as
appendices.
                                  J-1

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                              DRAFT
                                  SECTION  II
                              SUMMARY OF RESULTS
     The results of the analyses  of  the syringe samples collected and ana-
lyzed during the field test  program  are presented in Tables II-l and II-2.
Table II-l presents the results in terms of specific concentrations in parts
per million by volume (ppmv).  The values presented in the table are in terms
of actual ppmv of each compound*   The  total ppmv for each sample is presented
in terms of methane.  Table  I1-2  presents the same results in terms of weight
percent distribution of the  various  hydrocarbon groups.  The total weight per-
cent of. reactive hydrocarbons  (all non-methane and non-ethane hydrocarbons)
is presented at the bottom of  Table  II-2.
     Table II-3 presents the results of the laboratory analyses of liquid
samples collected during the field test program.  The values presented in
Table II-3 are weight percent  of  each  hydrocarbon fraction.  Total hydro-
carbon concentrations in parts per million by weight and the percent total
reactive hydrocarbons (all non-methane and non-ethane hydrocarbons) are pre-
sented at the bottom of Table  II-3.  Table II-4 presents the results of
head space analyses of a few liquid  samples.  Reproducibility of the head
space sample analysis was extremely  poor and attempts to continue the
analyses were abandoned.

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                              DRAFT
                              IA3LE II-.
VDC ANALYTICAL SIWIARY


VOC Concentrations
UNION CARBIDE - TORRANCE, CA. - FIELD SAMPLES
                     089
  090     091
092
093
095
096
097
  PARAFIRS;,
             ppm HC
                                 .  2106
                5852
     23,364
         12
    11,202
                                                                    73
   C3
                                         60
                                22
                                                                         50,474
   C5
                         363
   C8
   C9
  AROMATICS
 •OLEFINS
                     18
                 238
    10,280
         26
            13,037
                                             95
                       2,566
               133
               116
                                                  1,558
* As  methane.

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                            DRAFT
                          ABT2 II-l (Cent.,.
VOC ANALYTICAL SUMMARY
VOC Concentrations
UNION  CARBIDE - TORRANCE, CA. - FIELD SAMPLES
* As methane.

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                             DRAFT
                                 II-I  tCont.)
VDC ANALYTICAL SUMMARY


VOC Concentrations
UNION CARBIDE - TORRANCE, CA. - FIELD  SAMPLES
                   114
115
  PARAFUiS,
            ppm EC
                                                                     s  t "/
                    20
 12
   C3
                    11
   C5
   C6
   C8
   Cg
  ^OLEEINS
   C5

   C6
                    19
 17

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VOC ANALYTICAL SUMMARY


Weight Percent
          DRAFT
           TABLE II-2

        UNION CARBIDE - TORRANCE, CA. -  FIELD SAMPLES
  SAMPLE NUMBERS
089
090
091
092
093
095
                                                                   096
                                                       097
  PARAFINS
                WEIGHT PERCENT
                                    100
                       88.3
                      38.6
                        2.4
                      82.5
                                                                   1.1
   C3
                                        5.5
                                       1.3
   C4
   C5
                               3.0
                                              90.6
   C6
   C8
   Cg
  AROMATICS
  OLEFINS
                    37.5
                        7.2
                      34.0
                       10.6
                                                                            9.3
                                             4.3
                               12.7
                              81.5
                               2.6
   C4
                               10.3
* As methane.

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                            DRAFT
VOC ANALYTICAL SUMMARY
Weight Percent
TA3LL 11-2

 UNION CARBIDE - TORRANCE, CA. - FIELD SAMPLES
*As methane.

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                             DBAFT.
VOC ANALYTICAL SUMMARY
Weight Percent
         UNION CARBIDE - TORRANCE,  CA. - FIELD SAMPLES
  SAMPLE NUMBERS
 114
 115
  PARAFINS
                WEIGHT PERCENT
                   5.3
        24.5
   C3
 1.6
 3.8
                   11.8
   C5
 6.7
   C8
   C9
  AROMATICS
  OLEFINS
   C2
10.2
 2.4
70.4
 1.3
   C6

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                         DRAFT
VOC ANALYTICAL SUMMARY  UNION CARBIDE - TQRRANCE LIQUID SAMPLES

-------
VOC ANALYTICAL SUMMARY    UNION CARBIDE - TORRANCE LIQUID SAMPLES
 SAMPEE NUMBERS
    110
    112
    116
  117
  PARAFTNS,-
                     WEIGHT PERCENT
                    0.028
           0.009
                   0.178
   C3
                            32.078
                  14.785
   C5
 63.614
  0.826
 15.169
8.344
   C6
           0.255
                    0.049
           0.041
          2.424
           1.028
   Cg
  6.858
  0.003
  1.360
0.546
                   19.973
           0.041  51.168
                  44.972
  AROMATICS^
  TOTAL ppm
   2800     8600     560
                     260
  TOTAL REACTIVE
99.972
99.991
100.000
                                             99.822
  HYDROCARBONS

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                               DRAFT,
                             . .- .  --  J. J-~ H '. '_ v. ,. C. . )

VOC ANALYTICAL SUMMARY    UNION CARBIDE - TORRANCE HEAD SPACE SAMPLES
                     098
           To]
           09«
       Bottom
          099
            104
           105
                                         ppm HC
                   0.019
         0.001
                1.035
                 1.290
                                   0.021
   C3
                0.010
                0.439
                 0.259
   C4
0.353
0.001
 0.105
 1.032
 2.321
   C5
0.039
6.809
14.413
 0.268
 3.244
                   0.106
         8.857
                1.311
                 0.904
                   1.980
         2.909
       0.379
                 1.092
   C8
7.688
0.312
 1.639
32.671
31.450
   C9
5.960
1.105
 0.045
        0.371
                  34.958
        0.906
       4.215
        61.283
       56.356
  AROHATICS
  OLEF1NS
                  16.208
        0.000
                0.487
                   0.068
   C4
        0.736
                           1.453
               78.909
                           0.047
  TOTAL ppm
  TOTAL  REACTIVE
  HYDROCARBONS
                 99.981
       99,999
      99.979
        98.965
       98.7J.O

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                                DRAFT
                                 SECTION III
                            ANALYTICAL PROCEDURES

FIELD TESTING
     ES employed a TRACOR Model 550 dual FID gas chromatograph for deter-
mination of the composition of grab samples provided by the EPA test  team*
Samples were collected in glass 100 cubic centimeter syringes.   The gc was
equipped with a gas sampling valve and 1 cc sample loops.   The valve  inlet
was sealed with a septum.  Samples were injected from the  glass syringes
through the septum and flushed through the gas sample loops.   A minimum of
20 cc of sample was used to flush the valve prior to each  sample injection.
After duplicate analysis of a single sample or standard, the gas sampling
valve was flushed for several minutes with zero grade air  (total hydro-
carbon less than 1'ppm) prior to injection of the next sample.   All samples
were analyzed on the same day as their collection.  Between the time  of
collection and sample analysis, samples were stored in an  opaque container
to protect against component degradation.
     The column used for the analysis on the first two days of  testing
(October 13 and 16) was a 6-foot by 1/8-inch (outside diameter) stainless
steel column packed with 5% SP 1200/1.75% Bentone 34 on 100/120 mesh  Supel-
coport.  Compounds of primary interest were olefins and aromatic hydrocar-
bons.  ES established retention times for approximately 15 compounds  inclu-
ding benzene, toluene, xylenes, straight chain paraffins through Cg and
straight chain olefins through Cg.  Satisfactory separation of  ethylene
from ethane was not attainable using the SP 1200/Bentone column.   A 9-foot
by 1/8-inch stainless steel 100/120 mesh Porapak Q column  was rush-ordered
and arrived at the job site on October 16.  This column was used from
October 17 through the end of the test program.  Column temperatures  were
varied throughout the test program in an attempt to optimize separation
but minimize analysis time.  GC operating conditions are presented in
Appendix A with associated retention times.
     Instrument calibration was performed using benzene and propane standards.
Relative response for other compounds was determined by a  single standard gas
                                  III-l

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                               DRAFT
injection since published response factors could not be reliably extended
over the range of gc conditions used unless electronic integration were
available, which it was not.  Both benzene and propane standards produced
fairly good linear response.  The results of the standard analyses are pre-
sented in Appendix B.
     Under most gc operating conditions a single standard was  run  for
paraffins and olefins and toluene.   This was necessary since no  electronic
or mechanical integrator was available and data analysis  was based on peak
height. The peak height was a function of retention time  as well as concen-
tration.
     Some of the syringe field samples collected during the test program
contained hydrocarbon concentrations in excess of the  instrument range.
These samples were diluted using 100 cc glass syringes with 3-way  stainless
steel stop-cocks.  This dilution method was checked using a 1023 propane
standard gas and performing a series of two 50% dilutions on that  gas.
This analysis was performed on October 18 under 160°C  isothermal condi-
tions.  The results are presented in Appendix B as the standard  analysis
for that date.  Propane concentrations prepared from the  1023  ppm  gas were
511.5 ppm and 255.7 ppm.

LABORATORY ANALYSIS OF LIQUID AND HEAD SPACE SAMPLES
     Process stream and wastewater samples were collected during the field
test program and returned to the ES McLean Laboratory  for analysis.  Anal-
ysis of these samples was performed using a Hewlett-Packard 5830A, dual FID
gc equipped with a microprocessor and electronic integrator.
     Liquid samples collected in the field were transported to the ES lab-
oratory in McLean, Virginia.  Samples were then refrigerated until analysis
was performed.  Due to instrument linearity checks, liquid sample  analyses
were not completed until March 1979.  Although samples were sealed, protec-
ted from light, and refrigerated during the four-month interim from the time
of collection, some sample degradation probably did occur.
     Prior to analysis, portions of the samples were gravity-filtered  through
Whatman Number 1 filter paper to remove particulate material.  One microliter
                                 III-2

-------
                               DRAFT
aliquot was injected into a 200°C injection  port.  The column used for liquid
analysis was 10-foot by 1/8-inch stainless steel packed with 20% SP2100/0.1%
Carbowax 1500 on 100/120 mesh Supelcoport.   The oven was maintained at 35°C
for 15 minutes then temperature programmed at a rate of 5°C per minute to a
maximum temperature of 165°C.  All liquid samples were run in duplicate.
One cc headspace injection was made from samples 098, 099, 104 and 105.
     Example calculations are presented in Appendix C.  Field and labora-
tory raw data is also presented in Appendix  C.
                                III-3

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    APPENDIX A
RETENTION TIME DATA

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October 13, 1978

Oven'Temperature 175 °C

Column:  5% SP 1200/1.75% Bentone 34, 6' x 1/8" SS, 100/120 mesh Supelco-
         port

Injection Port Temperature 130°C

Detector Temperature 200°C

Nitrogen Flow 30cc/min.

Hydrogen 35%

Air Flow 6.5 SCFH
Compound
Ethylene
Propylene
Propane
Benzene
Toluene
Xylene
Samples - 089,
(Minutes )
Retention Time
0.53
0.58
0.50
2.12
3.57
4.83
090
Mean Peak
Height per ppm (cm)
2.86

5.83
0.464
0.347
0.137

No. of
Standards N


5
7
2
2


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October 16, 1978




Column:  5% SP 1200/1.75% Bentone 34, 6' x 1/8", 100/120 mesh Supelcoport




Oven Temperature 160°C
Compound
Methane
Ethylene
Ethane
Propylene
Propane
Benzene
(Minutes)
Retention Time
0.35
0.53
0.60
1.01
1.10
2.09
Mean Peak
Height per ppm (cm)
2.35
3.44
3.00

2.26
2.08
No. of
Standards N
0
0
0

6
9
Samples - 091, 092

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October 17, 1978




Column:  9' x 1/8" Porapak Q, 100/120 mesh




Nitrogen Flow 50cc/min.




Oven Temperature  130°C
Compound
Methane
Ethylene
Ethane
Propylene
Propane
Butene
Butane
Pentene
Pentane
Hexene
Hexane
Benzene
Toluene
Xylene
Samples - 093,
(Minutes )
Retention Time
0.35
0.51
0.59
1.00
1.10
2.40
2.60
6.20
7.30
17.00
19.00
20.80
51.60
79.80
095
Mean Peak
Height per ppm (cm)
3.48
5.10

4.45
3.35

1.84

0.90


0.33
0.25
0.10

No. of
Standards N
1
1
1
1
9
1
1
1
1
1
1
3
1
1


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October 17, 1978




Column:  Porapak Q 9' x 1/8" SS 100/120 mesh




Oven:  100-200°C @ 7.5cc/min.




Nitrogen:  50cc/min.
Compound
Methane
Ethylene
Ethane
Propylene
Propane
Butene
Butane
Benzene
Toluene
Xylene
Sample - 096
(Minutes)
Retention Time
0.36
0.50
0.72
1.07
1.40
2.50
2.80
8.10
11.40
16.70

Mean Peak
Height per ppm (cm)
2.18

2.82
2.62
2.75


0.65



No. of
Standards N
1
1
1
1
8
1
1
1




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October 18, 1978




Column:  Porapak Q, 9f x 1/8" SS, 100/120 mesh




Oven Temperature:  160°C




Nitrogen:  50cc/min.
Compound
Methane
Ethylene
Ethane
Propylene
Propane
Butane
Pentane
Hexane
Benzene
Toluene
Xylene
(Minutes )
Retention Time
0.36
0.45
0.48
0.73
0.76
1.30
2.80
4.99
7.60
18.60
43.60
Mean Peak
Height per ppm (cm)
2.50
4.86
3.73
4.48
4.70
3.52
1.94
0.81
0.86
0.64
0.25
No. of
Standards N
1
1
1
9
1
1
1
1
3


Samples - 97, 101, 102, 103, 106, 107 and 108

-------
October 19, 1978




Column:  Porapak Q, 9' x i/8" SS, 100/120 mesh




Oven Temperature:  130°C




Nitrogen 50cc/min.
Compound
Methane
Ethylene
Ethane
Propylene
Propane
Butane
Pentane
Hexane
Benzene
Toluene
Xylene
(Minutes )
Retention Time
0.32
0.51
0.59
1.00
1.10
2.60
7.30
19.00
20.80
52.00
80.80
Mean Peak
Height per ppm (cm)
.826
1.600
2.410
2.690
2.820
1.150
0.980
0.430
0.220
0.160

No. of
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-------
       APPENDIX B






STANDARDIZATION RESULTS

-------
October 13 - Benzene Standards
Concentration( ppm)
1.1
1.1
554.0
554.0
554.0
882.0
882.0
882.0
Peak Height
4.8
4.8
2496.0
2608.0
2560.0
4160.0
4192.0
4256.0
Peak Height per ppm
4.36
4.36
4.51
4.71
4.62
4.72
4.75
4.83

-------
October 16 - Benzene Standards
Concetttration(ppm)
4.77
4.77
4.77
4.77
45.00
45.00
100.00
100.00
100.00
Peak Height
10.6
10.4
11.0
10.6
88.0
88.8
197.0
195.0
189.0
Peak Height per ppm
2.22
2.18
2.31
2.22
1.96
1.97
1.97
1.95
1.89

-------
October 17 - Benzene  Standards



13(X°C
Concentration(ppm)
4.77
45.00
100.00
October 17 - Propane Standards
100-200°C
Concentration( ppm)
1023.0
1023.0
1022.0
1022.0
511.0
511.0
15.7
15.7
Peak Height
1.6
14.4
34.4


Peak Height
5069.0
5171.0
4608.0
4710.0
2713.0
2637.0
67.2
67.5
Peak Height per ppm
0.34
0.32
0.34


Peak Height per ppm
4.96
5.05
4.51
4.61
5.31
5.16
4.28
4.30

-------
October 18 - Benzene Standards
Concentration(ppm)     	Peak Height	Peak Height per ppm
        1.1                        0.91                          0.83
       45.0                       38.25                          0.85
      100.0                       90.20                          0.90
October 18 - Propane Standards
Concentration(ppm)       	Peak Height	Peak Height per ppm
     1023.0                        4762                          4.65
     1023.0                        4787                          4.68
     1023.0                        4608                          4.50
      511.5                        2406                          4.70
      511.5                        2381                          4.65
      255.7                        1209                          4.73
      100.0                         448                          4.48

-------
October 19 - Propane Standards




130 °C
Concentration(ppm)
2559
2559
2559
1023
1023
24.2 Methane
1000.0 Ethylene
14.6 Ethane
1000.0 Propylene
15.0 Butane
Peak Height
..6451
6298
6502
2790
2713
20.0
1600.0
35.2
2688.0
17.2
Peak Height per ppm
2.52
2.46
2.54
2.73
2.65
0.826
1.600
2.410
2.690
1.150

-------
   APPENDIX C

   CALCULATIONS
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                     Appendix C - Test Log
10/13/78
10/16/78
10/17/78
10/18/78
10/19/78
1400-1438
1441-1454
1502-1522
1545-1603
0954-1007
1350-1520

0912-0945
0900-1125
1320-1720

1145

1440
Separation plant walkthrough
Storage Walkthrough
Compressor Bldg. Walkthrough
Furnace area Walkthrough
Polyethylene Walkthrough
Separation Area Storage - OVA
vapor and liquid samples?
Sep. Area Walkthrough
Separation Area OVA
Vapor sample and liquid samples
Compressor Bldg OVA
Cooling Tower OVA
Furnace Area OVA
Furnace Area OVA
Bepeat Separator Area Storage OVA
vapor and liquid samples
wastewater separator OVA

-------