&EHV
          United States
          Environmental Protectioi,
          Agency
          Office of Air Quality
          Planning and Standards
          Research Triangle Park NC 27711
EMB Report 78-OCM-5
February 1979
          Air
Synthetic Organic
Chemical Manufacturing
Industry

Emission Test Report
Breathing Loss Emissions
from Fixed-Roof
Petrochemical Storage
Tanks

-------
          SYNTHETIC ORGANIC
   CHEMICAL MANUFACTURING INDUSTRY

        EMISSION TEST REPORT
    BREATHING LOSS EMISSIONS FROM
FIXED-ROOF PETROCHEMICAL STORAGE TANKS
      CONTRACT NO.  68-02-2815
       WORK ASSIGNMENT NO.  6
            Submitted To

    ENVIRONMENTAL PROTECTION AGENCY
  EMISSION MEASUREMENT BRANCH, ESED
  MAIL DROP 13, RESEARCH TRIANGLE PARK
         NORTH CAROLINA  27711
             MARCH 1978
            Submitted By

         ENGINEERING-SCIENCE
     150 North Santa Anita Avenue
      Arcadia, California  91006

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                           TABLE OF CONTENTS
SECTION I

SECTION II

SECTION III

SECTION IV
INTRODUCTION

SUMMARY OF RESULTS

SAMPLING AND MEASUREMENTS

DATA REDUCTION AND CALCULATIONS
  1-1

 II--1

III-l

 IV-1
APPENDIX A


APPENDIX B

APPENDIX C

APPENDIX D

APPENDIX E


APPENDIX F

APPENDIX G
AMERICAN PETROLEUM INSTITUTE BREATHING
   LOSS CALCULATIONS

FIELD DATA SHEETS

DATA REDUCTION WORK SHEETS

O.V.A. CALIBRATION CURVE CHARTS

FORMALDEHYDE GAS CHROMATOGRAPH
   CHART REDUCTION

EQUIPMENT USED FOR TESTING

COMPARISON OF BREATHING IN AND
   BREATHING OUT DATA
Table

II-l

II-2
          LIST OF TABLES

              Title

Tank Characteristics

Emission Measurements of Breathing Losses
   From Storage Tanks
 Page

 II-4

 II-5
III-l
Emergency Pressure and Vacuum Values
III-2

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                                SECTION I
                              INTRODUCTION
       A study of breathing loss emissions from fixed-roof petrochemical
storage tanks was requested by the Emission Measurement Branch of the
Environmental Protection Agency, Research Triangle Park,  North Carolina,
under Work Assignment No. 6 of Contract No. 68-02-2815.  The purpose
of the project was to develop data for new source performance standards
for fixed-roof storage tanks containing low vapor pressure petrochemicals.
       The study consisted of continuous monitoring of organic vapor
emission concentrations and rates from each of six fixed-roof storage
tanks and correlation of this data with significant chemical and environ-
mental parameters.  The storage tanks chosen to be tested contained
isopropanol, ethanol, acetic acid, formalin, cyclohexane, and ethyl
benzene.  The first three tanks were located at Union Carbide in Texas
City, Texas and the others were located at Celanese in Bishop, Texas,
Exxon at Bay Town, Texas, and Cosmar at Carville, Louisiana, respectively.
       Sampling and analysis was performed at these locations between the
dates of April 10, 1978 and May 18, 1978. by personnel of Engineering-
Science.
                                    1-1

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                                 SECTION II
                             SUMMARY OF RESULTS

      Table II-l details tank characteristics for each of the chemicals
tested.  Source parameters and breathing loss parameters for each chemical
(on a daily basis) are shown in Table II-2.
      The breathing loss parameters in Table II-2 include daily thru-put
                                                            o
on a SCF (standard cubic foot) basis, concentration in Ib/ft  (pounds per
cubic foot), tank emissions in Ib/day (pounds per day), maximum hourly
emissions in Ib/hr (pounds per hour) and the specific emissions calculated
as Ib/day/ft  (pounds per day per cubic foot).
      Condensation formation in test instrumentation became a problem during
the course of the tests.  As a result, some data were lost.  Whenever data
are unavailable,  it is so indicated in the tables and the field data sheets
in Appendix 3 by a footnote.
      The first tests (for anhydrous isopropanol emissions) were at Union
Carbide's facility at Texas City, Texas.  The tests on April 11 and 12, 1978
were disregarded due to organic vapor analyzer (OVA) failure (condensate
formation).  Testing continued on April 13 and 14 with successful results.
Some OVA data were lost during the early morning hours of April 13 due to
condensate formation.  (Refer to Appendix B for a detailed tabulation of
field data.)  However, sufficient data were available to determine tank
emissions.
      Ethanol (190 proof) emissions were tested at Union Carbide's Texas
City facility from April 18 through April 20, 1978.  Testing proceeded smoothly
with only a minimum of OVA data being lost due to condensate formation.
      The next chemical sampled at the Union Carbide facility on April 20
and 21 was glacial acetic acid.  Condensate formation briefly occurred on
an intermittent basis in the Roots meter and the OVA.  The condensate
formation problems did not result in data being lost or voided.  The emission
of glacial acetic acid on April 21 varied from that on April 20 because both
the daily ambient temperature change and total daily solar insolation were
greater on April  21.
                                    II-l

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      Emissions vary with tank parameters,  ambient temperature and solar
insolation.  The solar insolation for April 20 (a partially cloudy day) was
470 cal/cm^/day (calorie per square centimeter per day) while the solar
                                                           2
insolation for April 21 (a clear, sunny day) was 650 cal/cm /day 	 a
difference of approximately 38 percent.
      The Celanese plant at Bishop, Texas was the site of the formaldehyde
tests.  The period of testing was from April 26 through April 28, 1978.
Formaldehyde caused considerable condensation in the Roots meter.  Conse-
quently, the Roots meter was vented free to the atmosphere.  Some flow data
were still lost due to condensation, and true vapor pressure for these days
was not included in Table II-2.
      The heated formaldehyde tank at Celanese had a constant emission rate
which was totaled for a twenty-four hour period to determine daily standard
cubic feet and pounds per day of organic emission.  Water vapor was not
included as part of these organic emissions.
      Ethyl benzene was tested at the Cosmar facility in Baton Rouge,
Louisiana on May 9 and 10, 1978.  Ethyl benzene is shown to be oversaturated
                                                                    2
in Table II-2.  (Theoretical saturation is approximately 0.004 Ib/ft  based
on the measured bulk liquid temperature.)  The reason may be because the
temperature of the liquid in the tank was more stratified than in the other
tanks.  The concentration calculations were re-checked and appear correct.
Note that the average liquid temperature changes from 82°F to 80°F for the
two days (Table II-2).
      The Roots meter ran backwards during the ethyl benzene test.  Refer
to the worksheets in Appendix C.  A Roots meter can measure flow in 'either
direction.  Error will not result from running the unit backwards.
      The Exxon plant at Bay Town, Texas was the last facility tested during
the sequence of tests.  Cyclohexane emissions were sampled on May 16 through
18, 1978.  An electrical outage on May 16 caused a lack of OVA and tempera-
ture readings until 1200.  The Roots meter ran backwards during the
cyclohexane sampling (refer to the worksheets in Appendix C).  Testing was
curtailed on May 16 and 18 in mid-afternoon at the request of plant personnel.
The reason given was down-time required for tank maintenance.
                                   II-2

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      Breaching loss calculations based on American Petroleum Institute
procedures are in Appendix A.  The field data sheets are detailed in
Appendix B, and data reduction worksheets are included in Appendix C.
Plots of ambient vapor temperature, concentration and outflow versus
hours are also included in Appendix C.  Appendix D consists of OVA calibra-
tion curve charts for each chemical tested, and Appendix E details informa-
tion pertaining to formaldehyde gas chromatograph chart reduction.  Appendix
F details equipment used for testing.  Appendix G is a comparison of breathing
data for the tanks.  Storage tanks typically breathe out during heating
cycles (expansion) and breathe in during cooling cycles (contraction).
                                    II-3

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TABLE II-l

1978
4/13
4/14
4/18
4/19
4/20
4/20
4/21
4/26
4/27
4/28
5/9
5/10
5/16
5/17
5/18
Chemical
Isopropanol, 99%
Isopropanol , 99%
Ethanol, 190°
Ethanol, 190°
Ethanol, 190°
Acetic Acid,
Glacial
Acetic Acid,
Glacial
Formaldehyde
Formaldehyde
Formaldehyde
Ethyl Benzene
Ethyl Benzene
Cyclohexane
Cyclohexane
Cyclohexane
Company
Union Carbide
Union Carbide
Union Carbide
Union Carbide
Union Carbide
Union Carbide
Union Carbide
Celanese
Celanese
Celanese
Cosmar
Cosmar
Exxon
Exxon
Exxon
TANK

CHARACTERISTICS








Tank Parameters
Tank
No.
3710
3710
17
17
17
4
4
1745
1745
1745
302B
302B
65
65
65
Capacity
(bbls)
19,
19,
24,
24,
24,
80,
80,
12,
12,
12,
30,
30,
30,
30,
30,
000
000
500
500
500
000
000
300
300
300
000
000
000
000
000
Capacity Diam.
(gal x 103) (ft)
800
800
1,030
1,030
1.030
3,360
3,360
520 '
520
520
840
840
1,260
1,260
1,260
54
54
70
70
70
120
120
47
47
47
95
95
73
73
73
Height
(ft)
41
41
40
40
40
41
41
40
40
40
24
24
40
40
40
Liquid
Level
(ft)
15.5
15.5
30.7
30.7
30.7
18
18
15
15
15
15
15
24
24
24
Color
white
white
white
white
white
gray
gray
gray
Gray
Gray
white
white
white
white
white
Insula
tion
No
No
No
No
No
No
No
Yes
Yes
Yes
No
No
No
No
No

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                                                                     TABLE II-2
EMISSION MEASUREMENTS

1978
4/13
4/14
4/18
4/19
H 4/20
01
4/20
4/21
4/26
4/27
4/28
5/9
5/10
5/16
5/17
5/18

Chemical
Isopropanol,
99°
Isopropanol ,
99.
Ethanol,
190"
Ethanol ,
190"
Ethanol ,
190°
Acetic Acid,
Glacial
Acetic Acid,
Glacial
Formaldehyde
Formaldehyde
Formaldehyde
Ethyl Benzene
Ethyl Benzene
Cyclohexane
Cyclohexane
Cyclohexane

Company
Union
Carbide
Union
Carbide
Union
Carbide
Union
Carbide
Union
Carbide
Union
Carbide
Union
Carbide
Celanese
Celanese
Celanese
Cos mar
Cosmar
Exxon
Exxon
Exxon

Vapor
Tank Volume
No. (ft3)
3710 62,200
3710 62,200
17 43.500
17 43,500
17 43.500
4 297,800
4 297,800
1745 48,300
1745 48.300
1745 48.300
302B 70,200
302D 70,200
65 75,300
65 75,300
65 75,300


OF BREATHING LOSSES FROM STORAGE TANKS



Source Parameters
Avg.
Mol. Liquid
Wt. Temp.
(g/m) (°F)
60.10 70
60.10 70
46.02 71
46.02 71
46.02 71
1
60.05 70
00.05 70
30.03 150
30.03 150
30.03 147
106.11 82b>
106.11 80b>
34.16 79
84.16 79
84.16 79
True
Vapor
Pressure
(psia)
0.683
0.683
0.895
0.895
0.895
0.230
0.230
a)
a)
a)
0.200
0.200
1.97
1.97
1.97
Avg.
Avg. Ambient
Vapor Temp.
Temp. Change
<°F) <°F)
71.2 15
73.6 13
87.4 16
87.1 20
77.7 15
76.8 11
85.7 17
161.7 18
158.9 7
156.0 11
84.4 17
81.1 22
87.0 15
81.4 10
83.0 12
Baro-
metric
Pressure
(In Hg)
30.3
30.3
30.1
30.2
30.3
30.3
30.2
30.3
30.2
30.1
30.2
30.3
30.1
30.1
30.1
Total
Solar
Insolation
(cal/cm2/day)
6.7 x 102
6.2 x 102
4.6 x 102
6.3 x 102
4.7 x 102
4.7 x 102
6.5 x 102



Breathing Loss
Parameters
Daily
Thru- Concen.
Put (Ib/ft3)
(SCF) x 10-3)
3.824 3.9
4.248 4.1
1.313 4.6
790 4.3
1,435 4.0
9,508 2.5
18,934 2.4
6.4 x 102 25,000 1.0
6.7 x 102 24,000 1.0
5.0 x 102 22.000 1.0
5.8 x 102
6.9 x 102
4.7 x 102
6.8 x 102
a)
2,526 4.4
3.740 4.0
2,965 6.8
3,094 5.6
2.980 4.8
Max.
Dally Hourly
Emissions Emissions
(Ibs/day) (SCF/hr)
15.0 915
17.0 1.199
6.0 603
3.4 358
S.7 282
24.0 3,410
45.0 4,558
25.0 a)
24.0 a)
22.0 a)
11.0 734
15.0 845
20.0 1,175
17.0 686
14.0 839
Specific
Flow Rate
(Ib/day/ft3
x lO-3)
3.92
4.00
4.57
4.30
3.97
2.52
2.38
1.00
1.00
1.00
4.35
4.01
6.75
5.49
4.70
a)  Data unavailable.
b)  Measured temperature may not reflect  actual  temperature conditions in bulk liquid
    (large temperature changes In bulk could have  resulted from radiation).

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                               SECTION III
                        SAMPLING AND MEASUREMENTS

     The testing procedures used in this study were designed to measure
both the amount and concentration of the emissions from fixed-roof
storage tanks.  Also taken into consideration was the fact that the
equipment used had to be easily moved between and universally applicable
to different types of fixed-roof storage tanks.
     Two twelve-foot vans served both as a mobile testing laboratory and
a means of transporting the metering system.  Once located at the testing
site, the metering system was placed on the tank roof.  The temperature
and sampling lines were connected from the metering system to the analyzers
located inside the van.  Sampling lines were kept as short as possible and
heated to prevent condensation.
     Tank and test equipment schematics for each test are shown in
Appendix B.  Refer to Appendix F for a listing of major components of
the testing system and a schematic diagram.

FLOW MEASUREMENT
     Vapors expelled from the tank were passed through positive displace-
ment meters of either the bellows or rotary-type, depending on flow rate.
The bellows meter, manufactured by Singer, was used to monitor flows
below 300 CFH and the rotary meter, manufactured by Roots, was used during
peak flow periods when the differential pressure drop across the bellows
meter approached the tank relief valve settings.
     Both meters were mounted so that they could be manually switched for
positive and negative flow through a one-way pressure/vacuum relief valve
which was weighted, when applicable, to simulate the action of a conserva-
tion vent set at 0.86 inch water.  In all cases, a separate emergency
pressure/vacuum relief valve set at the tank manufacturer's specifications
was used in case of equipment failure.  The emergency pressure/vacuum
valve settings are listed in Table III-l.
     The meters were held by fittings of 4-inch I.D. polyvinyl chloride
and the system was connected using 4-inch I.D. flexible plastic hose.

                                 III-l

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TABLE III-l
EMERGENCY PRESSURE AND

Date
4/13/78
4/14/78
4/18/78
4/19/78
4/20/78
4/20/78
4/21/78
4/26/78
4/27/78
4/28/78
5/9/78
5/10/78
5/16/78
5/17/78
5/18/78

Chemical
Isopropanol,
99%
Isopropanol,
99%
Ethanol,
190°
Ethanol,
190°
Ethanol,
190°
Acetic Acid,
Glacial
Acetic Acid,
Glacial
Formaldehyde
Formaldehyde
Formaldehyde
Ethyl Benzene
Ethyl Benzene
Cyclohexane
Cyclohexane
Cyclohexane
-
Company
Union Carbide
Union Carbide
Union Carbide
Union Carbide
Union Carbide .
Union Carbide
Union Carbide
Celanese
Celanese
Celanese
Cosmar
Cosmar
Exxon
Exxon
Exxon
VACUUM VALUES

Tank No.
3710
3710
17
17
17
4
4
1745
1745
1745
302B
302B
65
65
65

Maximum
Pressure
0.5
0.5
1.0' .
1.0
1.0
1.5
1.5
1.5
1.5
1.5
0.5
0.5
0.25
0.25
0.25

Maximum
Vacuum
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.25
0.25
0.25
  III-2

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 The  entire  system was  mounted  onto  the  tank roof  using  the  sample hatch
 flange.
      The  entire metering  system  as  well as  other  openings in  the  storage
 tank were sealed  with  the use  of silicone gasket  material.  These seals
 were checked  under  positive  pressure  to ensure  that  all  emission  passed
 through the meters.  Both meters were calibrated  by  the  manufacturer.
ORGANIC VAPOR CONCENTRATION MEASUREMENT
     A sample stream of the tank vapors was drawn continuously through a
1/4-inch I.D.  heated teflon line to the van for analysis.  The sample was
mixed with a known volume of hydrocarbon-free air through a heated dilution
system and was then fed to a Century Organic Vapor Analyzer (OVA)  equipped
with a flame ionization detector to obtain concentration measurements.
     The OVA was calibrated and periodically checked between sample runs
with both 5000 ppm propane and standard concentrations of the organic vapors
being studied.  Electronic calibrations were also run and the OVA voltage
output was double checked using a volt meter.
     Laboratory calibration curves can be found following this section.
     Since formalin is a mixture of formaldehyde, water and methanol, it
does not respond well to a flame  ionization  detector;  therefore, a Carle
gas chromatograph equipped with a thermal conductivity detector and a
Porapack  T column was used for organic vapor measurements at Celanese.
The oven and injector were maintained at a temperature of 140°C,
and  the helium carrier liow was  set at  25 cc/min.  Undiluted emission
vapor was drawn through the heated sample line directly into the injector
port and was analysed on an hourly basis.  Standard gases of propane,
formaldehyde, methanol, and water were  used to span the gas chromatograph
periodically.  The OVA was used  to detect trace levels in addition to the
Carle gas chromatograph.
TEMPERATURE
      An Omega ten channel temperature system was  used to monitor  ambient,
 liquid, vapor, meter, dilution box and  sample line temperatures.  Tempera-
 ture  probes were  fitted in the tank and throughout the metering system  to
 allow the various temperatures to be  read.  Specifications on the Omega
 unit  are  included in Appendix  F.
                                 III-3

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SAFETY CONSIDERATIONS
     Due to the explosive and hazardous nature of the hydrocarbon vapors
which were metered and sampled during the investigation, the mobile labora-
tory was equipped with nitrogen purged fiberglass boxes in which all
electrical connections were made.
                                  III-4

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                                SECTION IV
                     DATA REDUCTION AND CALCULATIONS
     Calculations were performed according to the equations listed in
Table IV-1.
     Propane (C3) was used as a primary standard, in addition to the chemical
being tested, to double check the calibration of the organic vapor analyzer's
electronics.  Standard temperature and pressure was taken to be 68°F and
29.92 inches of mercury, respectively.
     The data reduction '.ables summarize all the calculations for each
individual reading.  Total pounds of organic emissions per day were cal-
culated by averaging all reasonable organic concentrations in pounds per
cubic foot and multiplying by the total standard cubic feet of vapor lost
during the day.

                               TABLE IV-1
(ft3)(Baro."Hg)(528°R)
  (29.92"Hg)(°F +460)

 (ppm)(MW g/m)
(1 x 106)(385.6)
Field Response Factor
                          EXAMPLE CALCULATIONS
standard cubic feet
tf/ft3 at 68°F and 29.92"Hg
  % Chart for X ppm C3
% Chart for X ppm Sample
Dilution Factor
% Chart Undiluted 5000 ppm GI to ppm C3
 % Chart Diluted 5000 ppm C3 to ppm C3
  ppm (mole  Wt)  x (2.81  x 10~9)  =  #/ft3
 L_                                    —i
                                  IV-1

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             APPENDIX A
AMERICAN PETROLEUM INSTITUTE BREATHING
          LOSS CALCULATIONS

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        AMERICAN PETROLEUM INSTITUTE BREATHING LOSS CALCULATIONS

     Calculations were performed in accordance wich API Bulletin 2523,
Petrochemical Evaporation Loss From Storage Tanks, November 1969, for
each test date.   Where vapor pressure data were missing from this bulletin
the vapor pressures were calculated using data from the Handbook of Chemistry
and Physics, 57th Edition, 1977.  Appendix Table A-l lists all the factors
for the API calculations and Appendix Table A-2  lists the measured breath-
ing losses and the calculated breathing losses for comparison.
     The API calculation procedures were developed primarily from tests
conducted on tanks containing gasoline.  A few tests were made on storage
tanks containing crude oil.  No test results were available for pure product
storage.

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                                              APPENDIX TABLE A-l
                                     API BREATHING LOSS  FORMULAE FACTORS
 Date
4/13/78
4/14/78
4/18/78
4/19/78
4/20/78
4/20/78
4/21/78
5/9/78
5/10/78
5/16/78
5/17/78
5/18/78
emical
ropanol ,
ropanol
97 '
nol, 1909
nol , 190°
nol, 190°
ic Acid
ic Acid,
1 o,. i a1
1 Benzene
Vapor
Pressure
(PS1A)
0.683
0.683
0.895
0.895
0.895
0.230*
0.230*
0.200*
1 Benzene j 0.200*
ohexane 1.97
ohexane • 1.97
ohexane : 1.97
Tank
Diameter
(ft)
54
54
70
70
70
120
120
60
60
73
73
73
Average
Outage
(ft)
23
28
12
12
12
28
28
25
25
19
19
19
;
Daily Ambient
Temp . Change
15
13
16
20
14
11
17
17
22
15
10
12

Paint
Factor
1
1
1.15
1.15
1.15
1.33
1.33
1
1
1
1
1

Small Dia.
Adj . Factor
1
1
1
1
1
1
1
1
1
1
1
1

M/W Factor
11.934
11.934
12.917
12.917
12.917
6.86*
6.86*
14.68*
14.68*'
11.004
11.004
11.004

        Not listed in API 2523

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           APPENDIX TABLE A-2
MEASURED VERSUS APT CALCULATED EMISSIONS
Date Chemical
Measured Breathing
Losses (
Ibs/day bbls/year tons/year
Calculated Breathing
Losses
Ibs/day bbls/year tons/year
4/13/78

4/14/78
4/18/78
ft/19/18
4/20/78
4/20/78

ft/21/78

5/9/78
5/10/78
5/16/78
5/17/78
5/18/78
Isopropanol ,
99%
Isopropanol
99%
Ethanol, 190°
Ethanol, 190°
Ethanol, 190°
Acetic Acid,
Glacial
Acetic Acid,
Glacial
Ethyl Benzene
Ethyl Benzene
Cyclohexane
Cyclohexane
Cyclohexane
15.0

17.0
6.0
3.4
5.7
24.0

45.0

11.0
15.0
20.0
17.0
14.0
20.0

22.0
7.9
4.5
7.5
24.0

45.0

15.0
19.0
27.0
23.0
19.0
2.75

3.02
1.1
0.6
1.1
4.4

8.3

2.3
2.9
3.7
3.1
2.6
44.0

46.0
74.0
82.4
70.0
74.6

92.7

28.4
34.7
127.0
104.0
123.0
59.0

59.0
98.0
109.0
92.0
74.6

92.7

38.7
43.9
172.0
141.0
167.0
8.1

8.1
16.5a>
I8.4a)
15.6a)
13.7

17.1

5.9
6.7
23.5
19.3
22.8

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    APPENDIX B
FIELD DATA SHEETS

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                         EPA FIXED-ROOF  STORAGE TANK STUDY
PLANT NAME
LOCATION
                    Union Carbide
                        TEST DATES
                                4/13-14/78
Texas City, Texas
                 TEST OPERATORS  A. L. Wilson,
CHEMICAL  Anhydrous Isopropanol
TANK I.D. 	3710	
DIAMETER (ft)	54   	
HEIGHT (ft)	
                             J. Mitchell. M. Escovicz
                        NORMAL RELIEF  SETTINGS
                          PRESSURE   0      OF VACUUM
41
CAPACITY (bbla)      19,000
COLOR 	White
                 MAXIMUM ALLOWED  RELIEF SETTINGS
                   PRESSURE   0-5    OF VACUUM   0-5
INSULATION:  TOP
No.
SIDE   NO
TANK GAUGE HEIGHT  (ft)   I5 • 5
STORAGE TEMPERATURE  (°F)  - Ambient
ROOF SLOPE 	
       10°
                                                                SAFETY  RELIEF
                                                                   VALVE
                                                                THIEF PORT
COMMENTS:   Tests  on  4/11-12/78 were disregarded because of organic  vapor
            analyzer  failure.

-------
EPA FIXED-ROOF STORAGE TANK STUDY
FIELD DATA SHEET
Chemical Anhydrous Isopropanol
Weather Conditions: AM Clear-Sunny
Location Texas City, Texas
O.V.A. 1400
Date 4/13/78
PM Clear-Sunny
Relative Humidity: AM 83%
PM 47%
O.V.A. Calibration:
Propane C3
5000 ppm
5000 ppm
1 Meter
Time Singer
0600 541
0630 541
0645 ; 541
0700 541
0715 541
0730 541
0800 541
0830 541
0845 541
0900 541
0930 541
1000 541
1030 541
1100 541
1130 541
1200 541
1230 541
1300 541
1330 633
1400 633
1430 ; 633
1500 ! 675
% Chart
AM 90 PM 90
Diluted AM 63 PM 63

ACF | Temperature °F
Roots Meter Liquid
6166 | 70°F
6220
6255
6357
6497 60
6697 61
7187 62
7599 65
7875 ! 67
8062 67
8432 ; 71
8882 76
9110 ; 79
9373 81 ;
Vapor Ambient




57
58
59
60
61
61
i 63
64
64
65
9574 82 '66
9938 86 68
10050 87 : 68
10084 85 68
10084 88 I 68
10266 88 : ! 69
10441 88 ; 70
;10441 90 70
Chemical
ppm
ppm

Dilution




55
56
58
60 -
61
61
64
67
69
70
; 129
207
: 171
166
155
117
98
! 87
% Chart
AM
Diluted AM
Pressure
Tank H20 Baro.
Inches Inche
-
_ i
+
+
+
0.0
+0.1
i +0.1
1 +0.1
+0.1
+0.2
+0.0
+0.4
0.0
+0.1 30.31
+0.1
+0.1
+0.0
+0.0
-0.0
+0.0
; -0.0
84 PM 85
55 PM 56


O.V.A. Reading
Hg! ' Rate
s 7, Chart: Air
1


i


i '
i
! 91
91 !
' 92
; 95
i
: 84 • 75
; 84 75

I
! 83 75
| 82 75
i 83 75
84 75
85 75
! 87 75
• Sample



i
i
j
1

I



: 28
28


28
28
28
23
28
28

-------
                             EPA FIXED-ROOF STORAGE TANK STUDY
                                     FIELD DATA SHEET
Chemical   Anhydrous Isopropanol (Cont'd.)
Location   Texas City,  Texas
O.V.A.  	
Date       4/13/78
O.V.A. Calibration:
                                     Weather Conditions:  AM  Clear-Sunny
1400
                     PM  Clear-Sunny
Relative Humidity:   AM  83%	
                                                          PM  47%
Propane Ci
5000
5000
ppm
ppm Diluted
7, Chart
AM
AM

90
63

PM
PM

90
63

Chemical
ppm
ppm Diluted
% Chart
AM
AM

84
55

PM
PM

85
56

     ' Meter ACF
                   Temperature
           Pressure
O.V.A. Reading
1
Time .Singer

.530 j 695
.600 695
.630 ! 697
!











Roots

10441
10441
10441












Meter

84
82
•80












Liquid

70°F














Vapor
1 •




i
j

!

1
!
i
i
!

Ambient

71
71
72





i





Tank H20
Dilution; Inches
1
82 i +0.0
79 ! -0.0
78 • -0.1



•







Baro. Hg
Inches

30.31









1



! Rate
% Chart ;Air| Sample
!
I
87 |75 28
i
1
88 75 28












-------
                             EPA FIXED-ROOF STORAGE TANK STUDY
Chemical   Anhydrous Isopropanol
Location   Texas City,  Texas
O.V.A.     1400	
Date       4/14/78	
O.V.A. Calibration:
Propane Cj ____^_^
5000 ppm   	
5000 ppm    Diluted
 Chart
AM   90
AM
63
PM
PM
                                     FIELD DATA SHEET
          90
63
                         Weather Conditions:  AM  Clear-Sunny
                                              PM  Clee
                         Relative Humidity:   AM  67%
                                         PM  Clear-Sunny
       Chemical
            ppm
                      ppm  Diluted
                                              PM  38%
 Chart
AM  84
AM
55
        PM  84
PM  56

Time
0615
0630
0645
0700
0730
0800
0830
0900
0930
1000
1030
1100
1130
1200
1230
1300
1330
1400
1430
1500
Meter
Singer
874
874
933
933
933
. 933
, 933
; 933
933
. 933
933
: 933
933
933
933
933
933
933
933
! 933
ACF
Roots
13078
13078
13078
13310
13708
14202
14841
15340
15750
Temperature °F
t
Meter
57
64
63
65
71
73
76
79
16153 82
16367 79
16558 83
16758 . 82
16930 87
17129 87
Liquid ! Vapor Ambient
f '
70°F ! 60
i
i
1 "
{ 64
| 64
\
66
: 67
: 68
: 70
70
71
: 70
72
!
71
17220 87 73
17266 83 72
: 17266 83 72
17266 82 : 73
1
17275 82
1 72

Dilution
56
56
71
69
72
72
75
77
79
80
81
82
83
83
84
83
82
82
: 81
Pressure O.V.A.
Tank H20
' Inches
-0.2
+0.6
-l-O.O
+0.0
+0.0
+0.0
3aro. Hg
Inches % Chart
i
1
83
83
j 84
' 84
1 84
+0.0 83
+0.0 : 85
+0.0 85
+0.0 30.33 85
+0.0 85
+0.0 84
+0.0 84
+0.0 85
+0.0 84
-0.1
-0.1
+0.3 84
1 +0.1 , i 84
Reading
Rate
Air
75
75
75
75
75
75
75
75
75
75
75
75
75
75


75
75
Sample
28
28
28
28
°8
28
28
r\ n
.•- O
23
,".8
23
28
23
23


28
; 28

-------
Chemical
Location
O.V.A.
Date
Anhydrous
Texas City
1400
4/14/78
O.V.A. Calibration:
Propane Ci
5000 ppm
5000 ppm

Diluted
EPA
Isopropanol
, Texas


7, Chart
AM 90
AM 63
FIXED-ROOF
FIELD
(Cont'd.)




PM 90
PM 63
STORAGE TANK STUDY
DATA SHEET
Weather Conditions
Relative Humidity:
Chemical %
ppm
ppm Diluted
: AM
PM
AM
PM
Chart
AM 84
AM 55
Clear-Sunny
Clear-Sunny
67%
38%

PM 84
PM 56
Meter

Time Singer
1530 933
1600 933
1715 933
i





ACF

Roots
17293
17293
16750








Meter
81
79
71






1

Liquid
70°








'empera

Vapor
'








iture °F

Ambient
73
73
71






Pressure O.V.A. Reading
Tank H?0 Baro. Hg j Rate
Dilution Inches Inches % Chart Air Sample
81 +0.1 84 75 28
80 -0.2 84 75 28
76 ; -0.1 30.34 75 28







-------
                           EPA FIXED-ROOF STORAGE TANK  STUDY
PLANT NAME

LOCATION __

CHEMICAL 	

TANK I.D.  	17_

DIAMETER  (ft).

HEIGHT  (ft)	
Union Carbide
Texas City,  Texas
Ethanol . 190C
  70
  40
CAPACITY  (bbls)   24500

COLOR 	  White
INSULATION:   TOP   No
               SIDE  No
STORAGE  TEMPERATURE  (°F)_

ROOF SLOPE      10°	
               Ambient
TEST  DATES
TEST  OPERATORS
4/18-21/78
J. Mitchell
                    J.  Wilson
NORMAL RELIEF SETTINGS

  PRESSURE   0      OF VACUUM    0
MAXIMUM ALLOWED  RELIEF SETTINGS

  PRESSURE   1.0    OF VACUUM   0.5
TANK  GAUGE HEIGHT  (ft)   30.69
         PRESSURE/
            VACUUM
            VALVE
          TANK
          BREATHER
          VALVE
          (CLOSED OFF))
          AIR/VAPOR   ROQTS METER


                   TURBINE METER
                                                      SAFETY RELIEF
                                                          VALVE
                                                      'THIEF PORT
                            FIXED ROOF TANK
                                                    VAPOR TEMP.
                                                                   LIQUID TEMP.
                                           SAMPLING
                                              PORT
                                           ACCESS
                                             PORT
                                                          TANK
                                                          BREATHING
                                                          VALVES

                                                           THIEF
                                                           PORT
                                                                         GAGE
                                                                         PORT
COMMENTS:

-------
Chemical
Location
OJ7.A.
DATE
O.7.A. CaJ
Propane C.
5000 ppm
5000 ppm
Ethanol, 1
Texas City
1400
. 4/18/78
Libration:
1 5

Diluted
90"
, Texas


'. Chart
AM 90 PM 90 '
AM 63 PM 63
EPA FIXED-ROOF STORAGE TANK STUDY
        FIELD DATA SHEET
                        Weather Conditions: AM  Cloudy-Rain
                        Relative Humidity:
  PM  Partly Cloudy-Sun
  AM  93%
  PM  74%
                  Chemical
Chart
                       ppm  Diluted
Time
06QO
0630
0700
0730
0800
0830
0900
0930
1000
1030
1100
1130
11200
J1230
[1300
J1330
JL400
1430
'1500
1330
•1600
1630
1700
Meter ACF
Singer
933
933
933
933
933
933
933
933
933
933
933
933
933
933
933
933
933
933
933
933
933
933
933
Roots
12583
12583
12583
12583
12596
12824
12969
13277
13577
1370l"
13791
13908
13908
13908
13908
13908
13908
13908
13908
13908
13908
13924
13968
Temperature °F
Meter
68
69

70
71
72
74
78
78
81
84
87
86
85
85
85
85
83
81
80
78
78
78
Liquid
69
69
70
70
70
70
70
70
70
71
70
70
70
70
70
71
71
71
71
71
71
71
72
Vapor
69
69
71
70
71
73
74
78
79
80
92
97
97
99
102
104
104
103
100
98
96
94
90
Ambient
69
69
70
71
71
72
73
77
76
78
82
83
81
83
85
85
83
82
81
81
80
78
78
Dilution
93
91
118
127
164
172
159
164
167
168
173
172
173
172
166
171
173
173
170
174
172
174
173
Pressure
Tank H20
Inches
-0.1
0.0
0.0
+0.2
+0.7
+0.1
+0.3
+0.7
+0.4
' +0.2
+0.4
+0.6
+0.2
+0.5
+0.3
+0.2
-0.1
-0.3
-0.4
-0.4
-0.5
-0.9
-0.8
Baro. Hg
Inches
30.10
30.09
30 . 10'
30.11
30.11
30.10
30.10
30.13
30.13
30.13
30.12
30.12
30.12
30.10
30.06
30.05
30.05
30.05
30.05
30.00
30.00
30.00
30.00
O.V.A. Reading
7. Chart


85
86
87
87
82
87 .
89
84
86
88
83
82
83
85
85
74
68
64
56
51
Air


75
75
75
75
75
75
75
75
75
75
75
75
75
75
75
75
75
75
75
75
Rate
Sample


28
28
28
28
28
28
28
28
28
28
28
28
28
28
28
28
28
23
28
28

-------
Chemical .
Location
O.V.A.
DATE
O.V.A. CaJ
Propane C.
5000 ppm
5000 ppm
Ethanol, 19C
Texas City,
1400
4/19/78
Libration:
7.
AM
Diluted AM
>°
Texas


Chart
90
63




PM 90 •
PM 63
EPA FIXED-ROOF STORAGE TANK STUDY
        FIELD DATA SHEET
                        Weather Conditions: AM Partly Cloudy
                                            PM Sun
                        Relative Humidity:  AM  91%
                                            PM  27%
                  Chemical
                       ppm
                       ppm


Diluted
Z
AM
AM
Chart
71
50
PM
PM
71
50
Time
0630
0700
0730
0800
0830
0900
0930
1000
1030
1100
1130
1200
(1230
.1300
11330
1410
!l440
1510
1530
1600
'1630
1645
Meter ACF
Singer
933
933
933'
933
933
933
933
933 .
935
938
1026
1091
1167
1220
1245
1275
1312
1311
1311
1313
1384
1427
Roots
15008
15008
15008
15116
15365
15391
15391
15391
15391
15391
15391
15391
15391
15391
15427
15427
15427
15427
15427
15427
15427
15427
Temperature °F
Meter
64
64
65
71
72
74
74
75
76
79
88
89
91
92
98
84
83
82
83
81
84
81
Liquid
71
71
71
71
71
71
71
71
71
71
71
71
71
72
72
72
72 .
72
72
72
72
72
Vapor
67
67
69
72
77
78
82
84
86
89
92
94
96
97
98
98
98
96
97
95
93
91
Ambient
63
64
68
70
69
70
71
72
75
76
76
79
78
81
82
83
82
81
81
80
79
79
Dilution
168
169
172
172
172
168
167
170
165
166
166
166
167
167
170
169
168
172
167
165
167
164
Pressure
Tank H20
Inches
-0.5
0.0
0.5
0.8
0.6
0.6
0.4
0.4
0.4
0.5
0.2
0.1
0.1
0.1
0.1
0.2
-0.2
-0.2
-0.3
-0.3
-0.4
-0.2
Baro. Hg
Inches
30.16
30.16
30.16
30.16
30.19
30.20
30.20
30.21
30.22
30.22
30.22
30.22
30.20
30.20
30.20
30.19
30.16
30.16
30.16
30.15
30.15
30.15
O.V.A. Reading
% Chart



82
83
36
85
84
• 85
86
86
87
87
88
86
89
91
79
89
90
50
53
Air



75
75
75
75
75
75
75
75
75
75
75
75
75
75
75
75
75
75
75
^ace
Sample



28
28
28
28
28
28
28"
28
28
28
28
28
23
28
28
28
28
28
28

-------
Chemical _
Location
O.V.A.
DATE
O.V.A. CaJ
Propane C,
5000 ppm
5000 ppm
Ethanol.
190
a

Texas City, Texas
1400
4/20/78
Libration:
>

Diluted


%
AM
AM


Chart
90
63


PM 90 '
PM 63
EPA FIXED-ROOF STORAGE TANK STUDY
        FIELD DATA SHEET
                        Weather Conditions: AM  Sun-Wind
                                            PM  Sun-Wind
                        Relative Humidity:  AM  50%
                                            PM  44%
                  Chemical
                       ppm  Diluted
Time
0630
0700
0730
0800
0830
0900
0930
1000
1030
1100
1130
1200
J1230
1300
1330
!l400
1430
1500
1530
1600
i
Meter ACF
Singer
2865
2871
3005 .
3116
3253
3395
3512
3612
3718
3745
3928
3957
3961
3992
4043
4070
4154
4267
4297
4422

Roots





















Temperature °F
Meter
56
58
63
63
66
71
70
69
72
70
76
66 '
67
68
81
76
78
86
77
72

Liquid
71
71
71
11
70
70
70
70
70
70
70
70
70
70
70
70
70
71
71
71

Vapor
63
64
66
63
69
73
74
76
77
78
82
83
81
79
82
84
87
89
91
87

Ambient
57
59
62
61
64
68
69
68 ,
71
71
67
64
67
65
65
69
69
68
71
71

Dilution
171
164
166
165
167
168
166
166
170
166
166
168
167
166
166
164
162
166
163
163

Pressure
Tank H20
Inches
0.0
0.4
0.6
0.1
0.4
0.9
0.6
0.1
0.4
0.3
0.5
-0.2
-0.3
. -0.5
0.9
0.4
0.0
0.5
0.0
-1.0

Baro. Hg
Inches
30.21
30.21
30.21
30.21
30.22
30.24
30.25
30.25
30.29
30.30
30.29
30.28
30.26
30.25
30.25
30.25
30 . 24
30.24
30.24
30.24

O.V.A. Reading
% Chart

73
78
80
81
81
83
83
83
81
85
85
82
75
36
85
85
35
89
83

Air

75
75
75
75
75
75
75
75
75
75
75
75
75
75
75
75
75
75
75

Elate
Sample

28
28
28
28
28
28
28
28
28
28
28
28
28
28
28
23
28
28
28


-------
                          EPA FIXED-ROOF STORAGE  TANK STUDY
PLANT NAME 	

LOCATION 	

CHEMICAL 	

TANK I.D. 	

DIAMETER (ft),

HEIGHT (ft)	
Union Carbide
TEST DATES
4/20-21/78
Texas City, Texas
TEST OPERATORS
M. Escovitz
Glacial Acetic  Acid
                    S.  Lambert
120
40' 11-3/4'
CAPACITY  (bbls)  80,000

COLOR 	
Gray
INSULATION:  TOP
           SIDE  NO
NORMAL RELIEF  SETTINGS

  PRESSURE   0      OF VACUUM   0

MAXIMUM ALLOWED  RELIEF SETTINGS

  PRESSURE   1.5    OF VACUUM   0.5


TANK GAUGE HEIGHT (ft)  17'  9-3/8"
STORAGE TEMPERATURE (°F)_

ROOF SLOPE 	
           Ambient
           10C
                      TANK BREATHER
                      VALVE (CLOSED OFF)
                                                               SAFETY RELIEF
                                                                  VALVE
                                                              BREATHER VALVE
                                                                     PORT
COMMENTS:  Condensation of Acetic Acid into  the  metering system
           caused  a  delay in testing.

-------
EPA FIXED-ROOF STORAGE TANK STUDY
        FIELD DATA SHEET
Chemical
Location
O.V.A.
DATE
O.V.A. Cal:
Propane C,
5000 ppm
5000 ppm
Glaci
Texas
1410
al Acetic Acid
City, Texas

Weather
Relative
Conditions
Humidity:
4/20/78
Lbration:

Diluted
Z Chart
AM 90 PM 89 '
AM 73 PM 72
Chemical
ppm
Z
AM
ppm Diluted AM
: AM Sun-Clouds-1
PM
AM
PM
Chart
54
45

53%


PM
PM




54-
45
Time
0615
0630
0700
0730
0800
0830
0900
0930
1000
1030
1100
1130
1200
1230
1300
1315
1330
1400
1430
1500
1530
1600
^640
i
Meter ACF
Singer























Roots
1120
1120
1120
1140
2870
4489
5780
6640
6970



8300
10107
10105
9919
9922
9923
9980
10435
11150
11596
11598

Temperature °F
Meter
56
56
57
60
63
65
68
68
69
69
69
73
75
75
71
71
71
76
79
80
83
76


Liquid
69
69
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70
70

Vapor
61
61
63
68
68
69
71
73
76
77
78
80
82
81
79
81
81
31
84
87
88
91
87

Ambient
56
56
57
58
58
58
61
62
61
61
63
63
64
63
64
64
64
66
66
67
67
64


Dilution
213
218
215
215
218
220
219
220
218
215
220
220
220
215
180
200
219
219
214
208
209
207


Pressure
Tank H20
Inches
-0.2
0.0
+0.3
+0.4
+0.4
+0.4
+0.3
+0.2
+0.3
+0.3
+0.4
+0.4
+0.5
0.0
-0.6
+0.1
+0.4
+0.5
+0.6
+0.7
+0.7
+0.5
-0.6

Baro. Kg
Inches
30.21
30.21
30.21
30.22
30.24
30.25
30.25
30.29
30.30
30.29
30.28
30.26
30.25
30.25
30.24
30.24
30.24
30.24
30.24
30.24
30.24
30.24
30.24

O.V.A. Reading
% Chart



83
82
82
83
88
88
88
88
88
89
38





88
38


Air



75
75
75
75
75
75
75
75
75
75
75





75
75


Elate
Sample



74
74 .
74
74
74
74
74
74
74
74
74





74
74



-------
Chemical w.aciaj. Acecic acia
Location
O.V.A.
DATE
O.V.A. CaJ
Propane C.
5000 ppm
5000 ppm
Texas City,
1410
4/21/78
Libration:
Z '
AM
Diluted AM
Texas


Chart
90
73



PM 89 '
PM 72
EPA FIXED-ROOF STORAGE TANK STUDY

        FIELD DATA SHEET

                        Weather Conditions:  AM  Clear-Sun
                                            PM  Clear-Sun
                        Relative Humidity:  AM  56%
                                            PM  49%
                  Chemical
                       ppm


Diluted
• z
AM
AM
Chart
54
45
PM
PM
54
44
Tine
0615
. 0630
0700
0730
0800
0830
0900
0930
1000
1030
1100
1130
1200
1230
1300
1311
1330
1420
1430
1500
1530
Meter ACT
Singer





















Roots
712
712
712
2710
4454
6650
9043
11110
13580
15226
17050
18520
19280
19708
19708
19482
19482
19482
19276
18912
18058
Temperature °7
Meter
50
53
55
65
72
79
84
88
91
92
94
93
92
89
34

81
80
79
77
73
Liquid
68
69
69
70
69
70
70
70
70
70
70
70
70
70
70

70
70
70
70
70
Vapor
59
61
63
66
71
77
84
88
93
94
96
97
97
98
97

96
95
96
94
91
Ambient
53
55
57
60
62
.65
66
67
68
68
69
70
70
70
71

70
70
70
69
68
Dilution
219
208
211
218
214
213
218
216
212
216
215
216
212
211
213

210
216
218
212
209
Pressure
Tank. H2°
Inches
-0.1
+0.3
+0.4
+0.4
+0.5
+0.5
+0.6
+0.6
+0.5
+0.4
+0.3
+0.1
0.0
-0.1
-0.4

-0.3
-0.2
-0.2
-0.2
-0.7
Baro. Hg
Inches





30.15
30.15


30.15
30.17
30.16
30.16
30.16
30.16

30.12

30.08


O.V.A. Reading
% Chart



86
87
38
38
88
' 87
87
87
38
87
87







Air



75
75
77
75
70
75
74
73
72
75
75







Rate
Sample



74
74
74
74
74
74
73
74
74
74
74








-------
                          EPA FIXED-ROOF  STORAGE TANK STUDY
PLANT NAME 	
LOCATION 	
CHEMICAL 	
TANK I.D. 	
DIAMETER (ft)_
HEIGHT (ft)	
Celanese
Bishop. Texas
Formaldehyde
1745
47
40
CAPACITY  (bbls)   12300
COLOR 	Gray
INSULATION:  TOP 	2"
          SIDE   2"
STORAGE TEMPERATURE (°F)  147
ROOF SLOPE 	
        20'
TEST DATES
4/26-28/78
TEST OPERATORS
                                                Mitchell,
   S. Lambert.  H.  Derlada
NORMAL RELIEF SETTINGS
  PRESSURE    0     OF VACUUM   0
MAXIMUM ALLOWED RELIEF SETTINGS
  PRESSURE   1.5    OF VACUUM  0.5
TANK GAUGE  HEIGHT (ft)  15
                                                 VAPOR OUT
                                           AIR INli
                                             -ROOTS METER
         TANK
         BREATHER
         VALVE
         (CLOSED OFF>
                                        TANK
                                        BREATHER
                                        VENT
                                                                     SAMPLING
                                                                     LOCATION
                                                                      GAGE
                                                                      PORT
 COMMENTS:  Because of  large  amounts of condensation the roots meter  was
            mounted to  vent  free to the atmosphere.

-------
Chemical  Formaldehyde
Location  Bishop, Texas
O.V.A.
Dace
1410
4/26/78
O.V.A. Calibration:
Propane C3 	
5000 ppm   	
5000 ppm    Diluted
                             EPA FIXED-ROOF STORAGE TANK STUDY
                                     FIELD DATA SHEET
          _%  Chart
             AM  90
             AM
                                      Weather Conditions:
               Relative Humidity:
PM  90
PM
Chemical
     ppm
     ppm  Diluted
                        AM
                        PM
                        AM
                        PM
 Chart
AM	
AM
                                         Clouds
                                                                Sunny
        38%
PM
PM
      Meter ACF
                    Temperature °F
                          Pressure
                             O.V.A. Reading

Time Singer Roots Meter ^Liquid
630 6100 ! :
1700 ; 5999 80 j 144
)730 5406 I 122 145
800 4760 ! 124 i 147
i
830 4284 126 j 148
900 3606 \ 127 i 148
930 2870 !
000 2148 ; 133 ' 149
t
030 1492 i 135 ! 150
100 850 ; 137 , 150
130 ' 95 139 151
200 J9451 : 137 152
230 8743 137 151
300 '8192 133 153
330 '7729 121 153
400 7389 127 150
430 7374 134 151
500 6730 137 152
530 6080 137 150
600 5364
630 ' 4863 135 151

Vapor

161
161
161
161
162

162

162
162
162
162
162
162
162
162
162
162
162

162

Ambient

58
60
63
64
65

70

71
72
74
76
76
76
74
75
75
75
74

75

Dilution

55
56
62
144
195

214

211
210
198
207
216
207
212
207
216
208
213

214
Tank H20
Inches

0.05
0.05
o'.os
0.05
0.05

0.05

0.02
0.0
0.0
0.0
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
Baro . Hg
Inches

30.26
30.27

30.28
30.29

30.29

30.29
30.26
30.25
30.23
30.23
30.22
30.21
30.21
30.21



30.21

7, Chart









58
52

53

54
58

58

62

55
Rate
Air ^Sample

|
1





i
0 100
0 i 100
1
0 ' 100

0 100
0 100

0 100

0 100

0 100

-------
                       EPA FIXED-ROOF STORAGE TANK STUDY
Chemical
Location
O.V.A.
Date
Formaldehyde (Cont'd.)
Bishop, Texas
1410
4/26/78
O.V.A. Calibration:
Propane C^ % Chart
5000 ppm
5000 ppm
AM 90 PM
Diluted AM PM

FIELD DATA SHEET
Weather Conditions: AM
PM
Relative Humidity: AM
PM
Chemical % Chart
90 ppm AM
ppm Diluted AM

Clouds
Sunny
38%


PM
?M

Meter ACF
Temperature °F
Pressure
O.V.A. Reading
;
Time
1700
1730
1800
2000
2030
2100
2130

Singer








Roots
4353
3924
3495
3401
2946
2477
2019

Meter
133
133
130
117
126
127
128

Liquid
152
151
151
148
149
! 148
146

Vapor
162
162
162
161
161
161
161

Ambient
74
72
71
66
65
64
64

Dilution
211
208
205
207
200
207
208
Tank H20
Inches
0.1
0.1
0.1
0.05
0.1
0.1

3aro. Hg
Inches "i
30.20
30.18
30.18
30.22
30.21
30.21
30.21

', Chart
51
58
58
56

53
54
Rate
Air Sample
0 100
0 100
0 100
0 100

0 100
0 100

-------
EPA FIXED-ROOF STORAGE TANK STUDY
        FIELD DATA SHEET
Chemical
Location
O.V.A.
DATE
O.V.A. Cald
Propane C-
5000 ppra
5000 ppm
Formaldehyde
Bishop,
1410
4/27/78
Lbracion:
Z
AM
Diluted AM
Texas


Chart
90 PM 90
PM
Weather
Relative
Chemical
ppm
Conditions
Humidity :
Z
AM
: AM
PM
AM
PM
Chart
ppm Diluted AM
Cloudy
Sunny
81%
41%

PM
PM
Time
0800
0830
{ 0900
1 0930
. 1000

' 1030
1100
1130
1200
! 1230
1300
1330
1400
1430
1500
Meter ACF
Singer
















Roots
991894
991348
990812
990255
989727

989078
988562
988009
987434
986883
986344
985801
985310
984754
984244
Temperature °F
Meter
114
127
128
127
124

128
132
131
131
132
127
128
126
129
129
Liquid
144
145
147
146
146

146
148
148
149
149
148
148
148
147
148
Vapor
158
159
159
159
159

159
159
159
159
159
159
159
159
159
159
Ambient
67
59
70
71
73

73
75
77
77
78
77
79
78
78
78
Dilution
67
128
183
210
218

215
215
207
205
215'
214
205
211
209
216
Pressure
Tank H20
Inches
0.0
0.1
0.1
0.1
0.1

0.1
0.1
0.1
0.1
0.1
0.1
0.12
- 0.1
0.1
0.1
Baro . Hg
Inches

30.24
30.24'
30.24
30.24

30.24
30.24
30.24
30.24
30.22
30.22
30.19
30.17
30.17
30.15
O.V.A. Reading
% Chart

53
57
53


54
55
52 .

53

54
51

54
Air

0
0
0


0
0
*ate
Sample

100
. 100
100


100
100
0 100

0

0
0

0
100

100
100

100

-------
EPA FIXED-ROOF STORAGE TANK STUDY
        FIELD DATA SHEET
Chemical
Location
O.V.A.
DATE
O.V.A. Calibration:
Propane C,
5000 ppm
5000 ppm Diluted
Formaldehyde
Bishop. Texas
1410
4/28/78
7. Chart
AM 90 PM 90
AM PM
Weather
Relative
Chemical
ppm
Conditions
Humidity:
?
AM
: AM
PM
AM
PM
Chart
ppm Diluted AM
Cloudy
Sun
64%
53%

PM
PM
Time
0815
0830
0900
0930
1000
1030
1100
1130
1200
1230
1300
1330
1400
1430
1500
Meter ACF
Singer















Roots
984050
983794
983320
982745
982175
981639
981134
980612
980067
979570
979120
978685
978265


Temperature °F
Meter
97
119
122
126
127
127
126
128
128
125
124
128
128
123
124
Liquid
140
143
143
145
144
145
145
145
145
143
144
145
144
144
144
Vapor
156
156
156
156
156
156
156
156
156
156
156
156
156
156
156
Ambient
73
75
• 75
77
78
79
79
81
81
81
81
81
81
80
80
Dilucion
79
142
200
213
207
206
215
209
202
211
202
207
200
199
208
Pressure
Tank r^O
Inches
+0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1


Baro. Hg
Inches
30.11

30.12

30.08

30.08

30.06

30.04
30.04
30.01
30.00

O.V.A. Reading
% Chart


53
55
54

56
54

56

56

56

Air


0
0
0

0
Rate
Sample


100
100
100

100
0 ! 100
j
0
100

0

0

100

100


-------
                          EPA FIXED-ROOF  STORAGE  TANK STUDY
 PLANT NAME
 LOCATION _
 CHEMICAL _
 TANK I.D. _
                 Cosmar
Baton Rouge, Louisiana
EEhvl  Benzene
302B
 DIAMETER (ft)	95
 HEIGHT (ft)
24
 CAPACITY (bbls)  30.000
 COLOR	
White
 INSULATION:  TOP
           SIDE   No
 STORAGE TEMPERATURE (°F)   Ambient
 ROOF SLOPE 	10"
                            TEST DATES
TEST OPERATORS
                  5/9-10/78
J. Mitchell
                  M. Escovicz
NORMAL RELIEF SETTINGS
  PRESSURE   0.5   OF VACUUM 0.5
MAXIMUM ALLOWED RELIEF  SETTINGS
  PRESSURE   0-5    OF VACUUM 0.5
TANK GAUGE HEIGHT  (ft)   14' 10-1/2"
        TANK
        BREATHER
        VALVE
        (CLOSED
COW-IENTS: Cosmar officials were  forced  Co work the tank on 5/11/78
          thus cutting  the test  short one day.

-------
ZPA FIXED-ROOF STORAGE TANK STUDY
        FIELD DATA SHEET •
Chemical
Location
O.V.A.
DATE
O.V.A. Cald
Propane C-
5000 ppm
5000 ppm
Ethyl Benzene
Baton Rouge
1410
5/9/78
Lbration:
Z
AM
Diluted AM
, Louisiana


Chart
90 PM 90
65 PM
Weather
Relative
Chemical
ppm
Conditions
Humidity:
Z
AM
: AM
PM _
AM
PM
Chart
74
ppm Diluted AM
Cloudy-Rai
Cloudy
80%
62%

PM
PM
Time

0700
0730
0800
0830
0900
0930
1000
1030
1100
1130
1200
1230
1300
1330
1400
1430
1500
1530

Meter ACF
Singer




















Roots
a)
6379
6420
6468
6494
6472
6256
6082
6065
5826
5369
5071
4839
4559
4326
4222
4092
4012
4012
a) Ro
Temperature aF
Meter


72
73
73
74
78
80
82
84
87
90
92 '
94
95
95
96
96
96
ots me
Liquid


80
80
81
81
82
82
82
81
82
82
82
82
83
83
82
82
82
:er ran
Vapor


76
76
77
77
78
80
81
79
84
87
88
90
91
92
93
93
93
backw;
Ambient


71
72
72
73
75
79
79
87
88"
87
82
83
84
83
85
84
84
irds dur
Dilution


176
173
178
166
165
199
195
173
193
196
195
190
193
193
191
191
191
.ng this
Pressure
Tank H2°
Inches


-0.1
0.0
-0.1
0.0
0.0
0.0
-K3.1
+0.1
+0.1
+0.1
+0.1
+0.1
. +0.1
+0.1
+0.1
0.0
0.0
sequence <
Baro. Hg
Inches


30.19





30.19


30.19







>f tests.
O.V.A. Reading
% Chart


78
78
84
83
83
87
89
87
89
90
91
92
92
93
93
92


Air





75
75
75
ilate
Sample





28
28
28
75 I 28
75 ! 28
75
28
75 28
75
75
75
75
75
75


28
28
28
28
28
28



-------
EPA FIXED-ROOF STORAGE TANK STUDY
        FIELD DATA SHEET
Chemical
Location
O.7.A.
DATE
O.V.A. Calibration:
Propane C-,
5000 ppm
5000 ppm Diluted
Ethvl Benzene
Baton Rouge, Louisiana
1410
5/10/78
Z Chart
AM 90 PM 89
AM 64 PM 62
Weather

Relative
Chemical
ppm
Conditions
Humidity:
?
AM
: AM
PM
AM
PM
Chart
74
ppm Diluted AM
Sun
Sun
60%


PM
PM
Time
0700
0730
0800
0830
0900
0930
1000
1030
1100
1130
1200
1230
1300
1330
1400
1430
1500
1530

Meter ACF
Singer



















Roots
8813
8642
8449
8156
7604
7543
7229
6901
6601
6422
6273
5867
5501
5374
5172
5016
5017
5093

Temperature °F
Meter
65
65
70
73
76
79
81
83
85
87
90
91
92
94
95
96



Liquid
78
78
79
80
80
80
80
80
80
80
80
81
81
81
81
81



Vapor
67
67

72
74
76
78
80
82
84
87
88
89
90
91
91



Ambient
61
61
67
73
76
78
79
81
80
80
31
81
82
83
83
83



Dilution
128
130
187
195
192
196
196
192
192
192
193
193
198
197
199
196



Pressure
Tank t^O
Inches
+0,0
+0.1
+0.1
+0.1
+0.1
+0.1
+0.1
+0.1
+0.1
+0.1
+0.1
+0.1
+0.1
+0.1
0.0
0.0



Baro. Hg
Inches

30.34
*











30.34




O.V.A. Reading
% Chart

81
81
82
83
83
84
84 .
85
86
88
88
89
90
90
90



Air

75
75
75
75
75
75
75
75
75
75
75
75
75
75
75



Rate
Sample

28
28
28
28
28
28
28
28
28
28
28
28
28
28
28




-------
                         EPA FIXED-ROOF  STORAGE TANK STUDY
                   Cvclohexane
PLANT NAME 	Exxon
LOCATION 	
CHEMICAL 	
TANK I.D. 	65_
DIAMETER (ft)	73_
HEIGHT (ft)	40
                                             TEST DATES
               5/16-17-18/78
                   Bay Town, Texas
TEST OPERATORS   J. Mitchell	
                 M. Eacovitz
NORMAL RELIEF SETTINGS-
1  PRESSURE   0.5   OF  VACUUM . 0. 25
CAPACITY (bbls)    30.000
COLOR
MAXIMUM ALLOWED RELIEF  SETTINGS
  PRESSURE   0.25   OF VACUUM 0.25
INSULATION:  TOP   No
                            SIDE  No
TANK GAUGE HEIGHT  (ft)  24' 3-1/2"
STORAGE TEMPERATURE  ("F)  Ambient
ROOF SLOPE    '  10°	
       NOTE:  TANK BREATHER
             VALVE - CLOSED OFF
COMMENTS: Electrical  outage  on 5/16/78 caused lack of OVA and  temperature
          readings until  1200.

-------
EPA FIXED-ROOF STORAGE TANK STUDY
        FIELD DATA SHEET
Chemical
location
J.V.A.
)ATE
O.V.A. Cald
?ropane C-
5000 ppm
iOOO ppm
Cyclohexane
Weather
Conditions
Bav Town, Texas
• 1410
5/16/78
Lbration:

Diluted


Z Chart
AM 90 PM 90
AM 37 PM 34
Relative
Chemical
ppm
Humidity:
Z
AM
: AM
PM
AM
PM
Chart
82
ppm Diluted AM
Cloudy
Sun
56%
60%

PM
PM
'ime
0700
0730
0800
0830
0900
0930
1000
1030
1100

1130
1200
1230
1300
1330
1400

Meter ACF
Singer

















Roots
8706
8682
8598
7873
7407
7322
7006
6713
6462

6120
5853
5752
5712
5699
5696
i
Temperature °F
Meter













91
92
91

Liquid













79
79
79

Vapor













88
87
86

Ambient









.



89
89
82

Dilution













196 •
198
198

Pressure
Tank H20
Inches












+0.1
+0.1



Baro. Hg
Inches








30.12



83
82
83
82

O.V.A. Reading
% Chart












33
82
83
82

Air






late
Sample









i


75
75
75
75



75
75
75
75


-------
EPA FIXED-ROOF STORAGE TANK STUDY

        FIELD DATA SHEET
Chemical Cyclohexane
location •
J.7.A.
)ATE
O.V.A. Cal:
'ropane C-
5000 ppm
iOOO ppm
' Bav
1410
5/17/78
Lbration:
Z
AM
Diluted AM
Town, Texas
-

Chart
90 PM
35 PM



89
34
                        Weather Conditions: AM Cloudy
                        Relative Humidity:
PM Sun

AM 91%
PM
                  'Chemical
                       ppm
                       ppm  Diluted
    PM

.'ime
0700
0730
0800
0830
0900
0930
1000
1030
1100
1130
1200
1230
1300
1330
1400
1430
1500
Meter
Singer

















ACF
Roots
4575
4386
4129
3726
3429
3149
2869
2768
2667
2557
2192
1877
1614
1557
1436
1412
1406

Meter

76
79
81
83
85
85
84
85
84
85
86
87
89
90
90

1
Liquid

77
78
78
79
79
79
79
79
79
79
79
79
•79
79
79

'erapera
Vapor

75
76
78
79
81
81
80
80
80
83
84
85
86
85
88

iture °F
Ambient

74
76
78
78
80
81
79
79
• 79
82
82
84
84
84
83


Dilution

133
152
152
148
153
155
152
152
153
152
153
151 .
• 154
153
154

Pres
Tank H2°
Inches
-0.1
+0.1
+0.1
+.0.1
+0.1
+0.1
+0.1
+0.1
0.0
+0.1
+0.1
. +0.1
+0.1
+0.1
+0.1
+0.1

sure
Baro. Hg
Inches




30.10












O.V.J!
% Chart

79
79
80
80
80
79
70
• 70
79
79
80
80
80
81
79

i. R<
Air

75
75
75
75
75
75
75
75
75
75
75
75
75
75
75

fading
late
Sample

75
75
75
75
75
75
75
75
75
75
75 '
75
75
75
75


-------
EPA FIXED-ROOF STORAGE TANK STUDY
        FIELD DATA SHEET
Chemical
Location
O.V.A.
OATE
O.V.A. CalJ
Propane C~
5000 ppm
5000 ppm
Cyclohexane
Bay Town
1410
5/18/78
Lbration:
Z
AM
Diluted AM
, Texas
•

Chart
90 PM 89
36 PM
Weather
Relative
Chemical
PPm „..,. 	
Conditions
Humidity:
%
AM
: AM
PM .
AM
PM
Chart
82
ppm Diluted AM
Sun-C
louds
Sun-Clouds
91%
fl%

PM
PM


82

Time
0730
' 0800
0830
0900
0930
1000
' 1030
: 1100
' 1130
1200
t
1230
1300
1330
Meter ACF
Singer













Roots
546
189
999912
999604
999412
99911:

999824*

9997481
999732:
999729*
999229:
Temperature °F
Meter
78
80
82
84
36
88
91
92
94
95
96
95
94
Liquid
77
78
78
79
79
79
79
79
79
79
79
79
79
Vapor
76
77
78
78
80
83
85 '
86
87
87
87
88
87
Ambient
75
76
77
78
79
82
84
84
85
87
87
86
36
Dilution
142
145
148
153
149
149
150
152
155
154
.154
153
154 '
Pressure
Tank H2°
Inches
0.0
+0.2
+0.2
+0.2
+0.2
+0.2
+0.2
+0.2
+0.2
+0.2
+0.2
' +0.2
+0.1
Baro. Hg
Inches


30.10










O.V.A. Reading
% Chart
79
78
77
77
78
78
78
78
' 79
79
78
77
76
Air
75
75
75
75
75
75
75
75
late
Sample
75
75
75
75
75
75
75
75
75 [ 75
75 75
75
75
75
75
75
75

-------
  APPENDIX C

DATA REDUCTION
  WORK SHEETS

-------
                                              WORKSHEET
CHEMICAL   Isopropanol (Anhydrous)
LOCATION   Union Carbide	
O.V.A. //   1400	
DATE       4/13/78
FIZLD RESPONSE FACTOR  1.07
DILUTION FACTOR 	
M.W. - 60.10 g/m
7.81
Time
0600
0630
0700
0730
0800
0830
0900
0930
1000
1030
1100
1130
1200
1230
1300
1330
1400
1430
1500
1530
1600
1630

TOTAL
A ACT
-54
-35
102
140
200
490
412
276
187
370
450
228
263
201
364
112
34
-92
0
-2
0

Meter Temp °R
520
520
521
522
525
527
527
531
536
539
541
542
546
547
545
548
548
548
550
544
542

3829
Baro. Hg
Indies
30.28
30.28
30.28
30.28
30.28
30.28
30.29
30.29
30.30
30.30
30.31
30.31
30.31
30.31
30.31
30.31
30.31
30.31
30.31
30.31
30.31
30.31


dSCT
-55
-36
105
143
204
497
418
278
186
370
445
225
258
196
357
109
33
-90
0
-2
0

3824
% Chart
< 	






84
84



83
82
83
84
84
85




ppm as C^








3100
3100



2900
2700
2900
3100
3100
3400



Diluted •
ppm
- a)
a)
a)
a)
a)
a)
a)
a)
3300
3300



3100
2900
3100
3300
3300
3600'




Undiluted
ppm








26000
26000



24000
23000
24000
26000
26000
28000



25000
Lbs/Ft3







4.0 x 10-3
4.0 x 10-3



3.7 x 10-3
3.6 x 10-3
3.7 x ID"3
I
i
4.0 x 10-3
4.0 x 10-3
4.4 x 10-3



15 ibs/day
  a)   Data lost due to condensate formation.

-------
                                             WORKSHEET
CHEMICAL    Isopropanol  (Anhydrous)
LOCATION    Union Carbide	
0.7.A. #    1400	
DATE 	4/14/78	
FIELD RESPONSE FACTOR
DILUTION FACTOR 	
M.W. = 60.10 g/m
1.07
7.81
Time
0630
0700
0730
0800
0830
0900
0930
1000
1030
1100
1130
1200
1230
1300
1330
1400
1430
1500
1530
1600
1630
1700
TOTAL
A ACT
0
0
688
494
639
499
410
403
214
191
200
172
199
91
46
0
0
9
18
0
-543

4273
Meter Temp °R
524
523
525
531
533
536
539
542
539
553
552
557'
557
557
553
553
552
552
551
549
541


Baro . Hg
Inches
30.33
30.33
30.33
30.33
30.33
30.33
30.33
30.33
30.33
30.33
30.33
30.33
30.33
30.33
30.33
30 ..33
30.33
30.33
30.33
30.33
30.33


ASCT
0
0
701
498
642
498
407
398
212
185
194
165
191
87
44
0
0
9
17
0
-537

4248
Z Chart
83
83
84
84
84
83
85
85
85
85
84
84 .
85
84

-------
                                              WORKSHEET
 CHEMICAL
 LOCATION
 O.V.A.  #
.DATS
Ethanol. 190C
Union Carbide
1400
FIELD RESPONSE FACTOR
DILUTION FACTOR 	
M.W.- 46.02 g/m
1.26
8.06
4/18/78
Time
0630
0700
0730
0800
0830
0900
0930
1000
1030
1100
1130
1200
1230
1300
1330
1400
1430
1500
1530
1600
1630
1700


TOTAL
A ACT
0
0
0
13
228
145
308
300
124
90
117
0
0
0
0 .
0
0
0
0
0
-16
-44


1325
Meter Temp "ft
528
529
529
530
531
532
534
538
538
541
544
547
546
545
545
545
545
543
541
540
538
538



Baro. Hg
Inches
30.09
30.10
30.11
30.11
30.10
30.10
30.13
30.13
30.13
30.12
30.12
30.10
30.10
30.06
30.05
30.05
30.05
30.05
30.05
30.00
30.00
30.00



A scr
0
0
0
13
228
145
307
296
122
88
114
o
0
0
0
0
0
0
0
0
-16
-43


1313
Z Chart
-
85
86
87
87
82
87
89
84
86
88
<












ppm as C«

3400
3600
4000
4000
2700
4000
4600
3200
3600
4300

.










Diluted •
ppm

4300
4500
5000
5000
3400
5000
5800
4000
4500
5400
a) -
a)
a)
a)
a)
a)
a)
a)
a)-
a)
a)



Undiluted
ppm

35000
36000
40000
40000
27000
40000
47000
32000
36000
44000











38000
Los /Ft 3

4.2 x 10-3
4.3 x 10-3
4.8 x 10-3
4.8 x 10-3
3.2 x 10-3
4.8 x 10-3
5.6 x 10-3
3.8 x 10-3
4.3 x ID'3
5.2 x 10-3

1








i
6.0 lbs/da;.
   a)   Data  lost because of  condensate  formation

-------
CHEMICAL
LOCATION
O.V.A. #
DATE 	
Ethanol, 190°
Union Carbide
1400
FIELD RESPONSE FACTOR
DILUTION FACTOR 	
M.tf.   46.02 g/m
1.26
8.06
4/19/78
Tine
0630
0700
0730
0800
0830
0900
0930
1000
1030
1100
1130
1200
1230
1300
1330
1400
1430
1500
1530
1600
1630
1700


TOTAL
A ACT
0
0
0
108
250
25
0
0
3
2
88
65
77
52
61
30
37
2
0
2
-71
-43


802
Meter Temp °R.
524
524
525
531
532
534
534
535
536
539
548
549-
551
552
550
544
543
542
543
541
544
• 541



Baro. Hg
Inches
30.16
30.16
30.16
30.16
30.19
30.20
30.20
30.21
30.22
30.22
30.22
30.22
30.20
30.20
30.20
30.19
30.16
30.16
30.16
30.16
30.15
30.15



A SCT
0
0
0
108
250
26
0
0
3
2
86
63
74
50
59
29
36
2
0
2
-69
-42


790
Z Chart



82
83
86
85
84
85
86
86
87
87
87
86
89
t 	







ppm as Co



2700
2900
3600
3400
3200
3400
3600
3600
4000
4000
4000
3600
4600








Diluted
ppm



3400
3600
4500
i300
4000
4300
4500
4500
5000
5000
5000
4500
5800
3\
a;
a)
a)
a)'
a)
a)



Undiluted
ppm



27000
29000
36000
35000
32000
35000
36000
36000
40000
40000
40000
36000
47000







Lba/Ft3



3.2 -x 10-3
3.5 x ID"3
4.3 x 10-3
4.2 x 10-3
3.8 x 10~3
4.2 x 10-3
4.3 x 10-3
4.3 x ID"3
4.8 x 10-3
4.8 x ID'3
4.8 x ID'3
4.3 x 10~3
5.6 x ID'3




1

36000 3.4 lbs/da?/
 a)  Data lost because of condensate formation

-------
                                             TORKSHEET
CHEMICAL
LOCATION
0.7.A. #
DATE
Echanol, 190°
Union Carbide
1400
4/20/78
 FIELD  RESPONSE FACTOR
 DILUTION  FACTOR 	
M.W.
                 1.26
,46.02 g/m
                 8.06
Time
0630
0700
0730
0800
0830
0900
0930
1000
1030
1100
1130
1200
1230
1300
1330
1400
1430
1500
1530
1600


TOTAL
A ACF
0
6
134
111
137
142
117
100
106
27
183
29
4
31
51
27
84
113
30
-125


Meter Temp *R
516
518
523
523
526
531
530
529
532
530
536
526
527
528
541
536
538
546
537
532


1432 j
Baro. Hg
Inches
30.21
30.21
30.21
30.21
30.22
30.24
30.25
30.25
30.29
30.30
30.29
30.28
30.26
30.25
30.25
30.25
30.24
30.24
30.24
30.24



& SC7
0
6
136
113
139
143
118
101
106
27
182
29
4
31
50
27
83
110
30
-125


1435
7. Chart

78
79
80
81
81
83
83
83
81
85
85
82
75
36
85
85
88
89
83

ppni as C^

2000
2200
2400
2500
2500
2900
2900
2900
2500
3400
3400
2700
1600
3600
3400
3400
4300
4600
2900

Diluted
ppm

2500
2800
3000
. 3200
3200
3600
3600
3600.
3200
4300
4300
3400
2000
4500
4300
4300
5400
5800
3600

1 ;
Undiluted
ppm

20000
22000
24000
26000
26000
29000
29000
29000
26000
35000
35000
27000
16000
36000
35000
35000
44000
47000
29000

Lbs/Fc3

2.4 x ID'3
2.6 x 10-3
2.9 x 10-3
3.1 x ID'3
3.1 x 10-3
3.5 x 10-3
3.5 x 10-3
3.5 x 10-3
3.1 x 10-3
4.2 x 10-3
4.2 x 10-3
3.2 x 10-3
1.9 x 10-3
4.3 x 10-3
4.2 x 10-3
4.2 x 10-3
5.2 x 10-3
5.6 x 10-3
3.5 x 10-3

1
l
7.3000 5.7 Ibs/da-i
i 1

-------
                                            ffOHKSHEZT
CHEMICAL Acetic Acid, Glacial
LOCATION
0.7. A. #
DATE
Union Carbide
1410
4/20/78
                                                      FIELD RESPONSE FACTOR
                                                      DILUTION FACTOR 	
                                                      M.W.    60.05 g/m
1.111
3.33
Time
0630
0700
0730
0800
0830
0900
0930
1000
1030
1100
1130
1200
1230
1300
1330
1400
1430
1500
1530
1600
1630
j

1
TOTAL
A ACT
0
0
+ 20
+1730
+1619
1291
860
330



1730
-1407
- 2
186
4
57
455
715
446
2



9445
Meter Temp °R
516
517
520
523
525
528
528
529
529
529
533
535-
535
531
531
531
536
539
540
543
536




Baro. Eg
Inches
30.21
30.21
30.21
30.22
30.24
30.25
30.25
30.29
30.30
30.29
30.28
30.26
30.25
30.25
30.24
30.24
30.24
30.24
30.24
30.24
30.24




dSCF
0
0
20
1764
1646
1305
869
333



1727
-1404
187
4
57
450
706
438
2



9508
% Chare


83
82
82
83
88
88.
88
38
88
38




38
88





ppm as C,


3100
2900
2900
3100
4300
4300
4300
4300
4300
4300





4300
4300





Diluted •
ppm


3400
3200
3200
3400
4800
4800
4800
4800
4800
4800
- a) -
a)
a)
a)
a)
a)
4800
4806.





Undiluted
ppm


11000
11000
11000
11000
16000
16000
16000
16000
16000
16000





16000
16000



Lbs/7t3


1.7 x HP3
1.7 x 10~3
1.7 x 10-3
1.7 x 10-3
2.5 x 10-3
2.5 x ID'3
2.5 x 10-3
2.5 x 10-3
2.5 x 10-3
2.5 x 10-3




2.5 x ID'3
2.5 x 10~3


I
1
16,000 j24 Ibs/dayi
a)  Data lost because of condensate formation

-------
                                             W3RKSHEET
CHEMICAL     Acetic Acid  (Glacial)
LOCATION     Union Carbide	
O.V.A. 9     1410	
DATE 	4/21/78	
FIELD RESPONSE FACTOR
DILUTION FACTOR 	
 M.W.     60.05 g/m
1.111
3.33
Time
0630
0700
0730
0800
0830
0900
0930
1000-
1030
1100
1130
1200
1230
1300
1330
1400
1430
1500
1530
1600

TOTAL
& ACT
0
0
1998
1744
2196
2393
2067
2470
1646
1824
1470
760
428
0
226
0
-206
-364
-854


19222
Meter Temp °R
510
513
515
525
532
539
544
548
551
552
554
553
552
549
544
541
540
537



Baro. Hg
Inches
30.15
30.15
30.15
30.15
30.15
30.15
30.15
30.15
30.15
30.17
30.16
30.16
30.16
30.16
30.15
30.13
30.12
30.12
30.12



dSCF
0
0
2064
17627
2196.
2362
2022
2398
1589
1759
1412
731
413
0
221
0
-202
-358
-845


18934
7. Chart


86
87
88
88
88
87
87
87
38
87
88
88
<






ppm as C.,


3800
4100
4300
4300
4300
4100
4100
4100
4300
4100
4300
4300





Diluted •
ppm


4200
4600
4800
4800
4800
4600
4600
4600
4800
4600
4800
4800
i — al -
»/
a)
a)
a)
a)


j
1
Undiluted
ppm


14000
15000
16000
16000
16000
15000
15000
15000
16000
15000
16000
16000






Lbs/Fc3


2.2 x 10-3
2.3 x 10-3
2.5 x UP3
2.5 x 10-3
2.5 x 10-3
2.3 x 10-3
2.3 x 10-3
2.3 x ID'3
2.5 x 10"3
2.3 x ID"3
2.5 x 10-3
2.5 x 10-3





I
15,000 45 Ibs/day;
 a)   Data lost because of condensate formation

-------
                                           WORKSHEET
CHEMICAL Formaldehyde
LOCATION Bishop, Texas
0.7. A.
DATE
Time
0630
0700
0730
0800
0830
0900
0930
1000
1030
1100
1130
1200
1230
1300
1330
1400
1430
1500
1530
1600
1630
1700
1730
1800
2000
2030
TOTAL
# 1410
4/26/78

A ACT

101
593
646
476
678
736
722
656
642
755
453
708
551
463
340
15
644
650
716
501
510
429
429
455
Meter Temp °R

540
582
584
586
587
587 .
593
595
597'
599
597'
597
593
581
587
594
597
597
597
595
593
593
590
577

Baro. Eg
Inches

30.26
30.27
30.27
30.28
30.29
30.29
30.29
30.29
30.26
30.25
30.23
30.23
30.22
30.21
30.21
30.21
30.21
30.21
30.21
30.21
30.20
30.18
30.18
30.22
30.21

ASC?

99
544
590
434
617
670
650
589
574
673
405
633
496
425
309
13
575
580
639
449
458
385
387
420


% Chart








58
52

53

54
58

58

62

55
51
58
58
56

FIELD RESPONSE FACTOR N.A.
DILUTION FACTOR
M.W.
N.A.

ppm as C,
\
\
\
\
\
\













/
/
/
/
/
/
Diluted
ppm






,
\
\
\
\
\
^
/
/
/
/
/
/







N.A.

Undiluted
ppm






/
/
/
/
/
/
/
\
\
\
\
\
\
\




(cont'd.!
Lbsm3
/
/
/
/
/
/














\
\
\
\
\
\
t
a) Gas chromatograph samples were used  to calculate  emissions.

-------
                                              TOTJKSHEST
CHEMICAL    Formaldehyde
LOCATION    Bishop, Texas
O.V.A. #
DAIE
    1410
                                          FIELD RESPONSE FACTOR  N.A.
                                          DILUTION FACTOR 	
                                          M.W.      N.A.
                                                                       N.A.
    4/26/78
 Time
 ACF
Meter Temp °R
Bare. Hj
 laches
ASCF
      a)
% Chart
ppm as G.J
DUuted
  ppm
Undiluted
   ppm
Lbs/Ft3
 2100
 2130
469
458
   587
   588
 30.21
 30.21
 426
 415
  53
  54
                                                            /
                                                         i
[TOTAL
 a)  Gas Chromatograph samples were used to calculate emissions.

-------
                                              WORKSHEET
CHEMICAL
LOCATION
0.7.A. #
DATE 	
      Formaldehyde
      Bishop,  Texas
      1410
      4/27/78
                                          FIELD RESPONSE FACTOR __.S.A.
                                          DILDTION FACTOR  .
                                                    N.A.
                                                 M.W.
                                                   N.A.
 Time
A ACF
Meter Temp "R
Baro. Hg
 Inches
ASC?
Char
ppm as G.J
 0800
 0830
 0900
 0930
 1000
 1030
 1100
 1130
 1200
 1230
 1300
 1330
 1400
 1430
 1500-
 546
 536
 557
 528
 649
 516
 553
 575
 551
 539
 543
 491
 556
 510
   574
   587
   588
   587
   584
   588
   592
   591
   591
   592
   587
   588-
   586
   589
   589
 30.24
 30.24
 30.24
 30.24
 30.24
 30.24
 30.24
 30.24
 30.22
 30.22
 30.19
 30.17
 30.17
 30.15
 496
 486
 506
 482
 589
 465
 499
 519
 496
 490
 492
 446
 503
 460
53
57
53

54
55
52

53

54
51

54
TOTAL
  a)  Gas Chromatograph samples were used to calculate emissions.

-------
                                              70RKSHEET
CHEMICAL
LOCATION
0.7.A. //
DATE
     Formaldehyde
     Bishop.  Texas
     1410
     4/28/78
                                          FIELD RESPONSE FACTOR
                                          DILUTION FACTOR 	
                                          M.W.       N.A.	
                                                   N.A.
                                                                        N.A.
 Time
 ACT
Meter Temp "R
Baro. Eg
 Inches
ASCT
     a)
Z Chart
                                                           as
Diluted
  ppm
Undiluted
   ppm
Lbs/Fc3
 0830
 0900
 0930
 1000
 1030
 1100
 1130
 1200
 1230
 1300
 1330
 1400
474
575
570
536
505
522
545
497
450
435
420
   579
   582
   586
   587
   587
   586
   588
   588
   585
   584
   588
   588"
 30.11
 30.11
 30.12
 30.12
 30.08
 30.08
 30.08
 30.08
 30.06
 30.06
 30.04
 30.04
 433
 522
 516
 485.
 457
 471
 492
 451
 409
 392
 379
  53
  55
  54

  56
  54

  56

  56
TOTAL
  a)  Gas chromatograph samples were used to calculate emissions.

-------
                                WORKSHEET
CHEMICAL   Ethyl Benzene
FIELD RESPONSE FACTOR   0.625
LOCATION Cosmar

O.V.A. // 1410
DILUTION
FACTOR
6.17
M.W. 106.11 g/m
DATE 5/9/78

Time
0700
0730
0800
0830
0900
0930
1000
1030
1100
1130
1200
1230
1300
.1330
1400
1430
1500
1530




Total

A ACF Meter Temp °R
'
0 532
: 41 "532
i 48 533
1 26 533
* 22 534
216 • 538
174 540
i 17 542
i 239 544
i 457 547
' 298 550
; 232 552
: 280 554
233 555
: 104 555
130 456
80 556
0 556




' 2597

Baro. Hg
Inches ,
1
30.19
30.19
30. L9
| 30.19
j 30.19
; 30.19
1 30.19
! 30.19
'• 30.19
30.19
: 30.19
; 30.19
30.19
30.19
30.19
30.19
30.19
30.19






A SCF
t

% Chart
0
41 | 78
48 78
26 84
22 j 83
214
172
17
234
445
289
224
269
83
87
89
87
89
90
91
92

ppm as Cj

2000
2000
3200
2900
2900
4000
4600
4000
4600
5000
5200
5400
224 92 i 5400
100
124
77
93
5600
93 5600
92 5400
0
i
i
i \ !
! i •
2526

Diluted |
ppm

1250 ;
1250 i
2000 !
[
1800
| 1800
2500
2900
2500
2900
3100
3200
3400
3400
3500
1 3500
3400




i
i


Undiluted i
ppm i Lbs/Ft^

7700 2.2 x 10-3
i
7700 ' 2.2 x 10-3
12000 . 3.3 x 10-3
11000 3.0 x 10-3
11000 3.0 x 10-3
15000 j 4.1 x ID"3
18000 ! 5.0 x 10-3
15000 •: 4.1 x 10-3
18000 5.0 x 10-'*
19000 i 5.2 x ID'3
20000 ; 5.5 x 10-3
21000 : 5.8 x 10-3
21000 : 5.8 x 10-3
22000 6.0 x 10-3
22000 6.0 x 10-3
21000 ' 5.3 x 10-3
i
i
i
i
i
: 16000 11 Ibs/day

-------
                                             WORKSHEET
             CHEMICAL   Ethyl Benzene




             LOCATION   Cosmar
                                              FIELD  RESPONSE  FACTOR




                                              DILUTION  FACTOR
                                                                       0.625
                                        6.17
             O.V.A.  *   1410




             DATE
                                              M.W.   106.16 g/m
              5/10/78
Time

0700
0730
0800
0830
0900
0930
1000
1030
1100
1130
1200
1230
1300
1330
1400
1430
1500
1530


A ACF

0
171
193
293
552
61
314
328
300
1 179
i
j 149
406
| 366
I
| 127
1
202
156
- 1
! - 76


Meter Temp °R !

525 !
'525
530
533
536
539
541
543
545
547
550
551
552
554
555
556
: 556
556


Baro. Hg
Inches

30.34
30.34
30.34
30.34
30.34
30.34
30.34
30.34
30.34
30.34
30.34
30.34
30.34
30.34
30.34
30.34
30.34
30.34


A SCF

0
174
195
294
551
60
311
323
295
175
145
394
355
123
195
150
- 1
- 73


% Chart ppm as 03 i
!
1

81 2500 :
81 ; 2500
.82 ; 2700 j
83 : 2900 \
83 ; 2900 '
84 ; 3200 ;
84 '' 3200 j
85 3400
86 3600
88 4200
88 4200
89 4800
90 5000
90 5000
90 5000




Diluted
ppm


1600
1600
1700
1800
1800
2000
2000
2100
2200
2600
2600
3000
3100
3100
3100




Undiluted
ppm


9900
9900
10000
11000
11000
12000
12000
13000
14000
'• 16000
16000
18000
19000
19000
19000




Lbs/Ft3


2.7 x 10-3
2.7 x 10-3
2.8 x 10-3
3.0 x 10-3
3.0 x 10-3
3.3 x 10-3
3.3 x 10-3
3.6 x 10-3
3.8 x 10-3
4.4 x 10-3
4.4 x 10-3
5.0 x 10-3
5.2 x 10-3
5.2 x 10-3
5.2 x 10-3




Total
3797
3740
                                                                             15000
                                                                             15  Ibs/dav

-------
                                           WORKSHEET
           Exxon
CHEMICAL
LOCATION 	
O.V.A. # _    1410
DATE
           Cyclohexane
           5/16/78
FIELD RESPONSE FACTOR
DILUTION FACTOR 	
M.W.    84.16 g/m
                                                                               0.835
12.5
Time
0700
0730
0800
0830
0900
0930
1000
1030
1100
1130
1200
1230
'1300
1330
1400
1430



[TOTAL
A ACT
0
24
34
725
466
85
316
293
251
342
267
101
40
13
3




3010
Mecar Temp "R
539*
539
539
539
539
539
539
539
539
539
551'
552
551
551

* average temp
5/17/78



Baro. Hg
Inches
30.12
30.12
30.12
30.12
30.12
30.12
30.12
30.12
30.12
30.12
30.12
30.12
30.12
30.12
30.12





dSCT
0
24
83
715
460
84
312
289
248
337
263
97
38
12
3




2965
% Chart










83
82
83
82






ppm as C^










3100
2900
3100
2900




Dilutad •
ppm
	 -.\
a)
a)
a)
a)
a)
a)
a)
a)
a)
2600
2400
2600
2400




1


Undiluted
ppm










32000
30000
32000
30000





Lbs/Ft3










7.0 x ID'3
6.5 x ID'3
7.0 x ID'3
6.5 x 10-3




i
31000 20 Ibs /day ;
a)  Data lost because of condensate formation.

-------
                                             WORKSHEET
CHEMICAL
LOCATION
0.7.A. #
DATE
Cyclohexane
Exxon
1410
FIELD RESPONSE FACTOR
DILUTION FACTOR 	
M.W.    84.16 g/m
 0.835
12.5
5/17/78
Time
0700
0730
0800
0830
0900
0930
1000
1030
1100
1130
1200
1230
1300
1330
1400
1430
1500


i
A ACT
0
189
257
403
297
280
280
101
101
110
365
315
263
57
121
24
6




[TOTAL
3169
Meter Temp °rl
536
536
539
541
543
545
545
544
545
544
545
546
547
549
550
550
550




Baro. Hg
Inches
30.10
30.10
30.10
30.10
30.10
30.10
30.10
30.10
30 . 10
30.10
30.10
30.10
30,10
30.10
30.10
30.10
30.10




!
ASCT
0
187
253
396
290
273
273
99
98
107
356
306
255
55
117
23
6




3094
7, Chart

79
79
80
80
. 80
79


79
79
80
80
30
81
79






ppm as €3

2300
2300
2500
2500
2500
2300


2300
2300 '
2500
2500
2500
2700
2300





Diluted •
ppm

a;
1900
1900
2100
2100
2100
1900
a)
a)
1900
1900
2100
2100
2100
2200
1900
a)




|
(
Undiluted
ppm

24000
24000
26000
26000
26000
24000


24000
24000
26000
26000
26000
28000
24000



Lbs/Ft3
N.
5.2 x ID'3
5.2 x ID'3
5.7 x 10-3
5.7 x 10-3
5.7 x 10-3
5.2 x 10-3


5.2 x 10-3
5.2 x ID"3
5.7 x 10~3
5.7 x 10-3
5.7 x 10-3
6.1 x 10-3
5.2 x 10-3




t
25000
17 lbs/day>
  a)  Data lost because of condensate formation.

-------
                                              WORKSHEET
CHEMICAL
LOCATION
0.7.A. #
DATE
Cyclohexane
Exxon
FIELD RESPONSE FACTOR   0.835
DILUTION FACTOR        12.5
1410
                                           M.W.
         84.16 g/m
5/18/78
Time
0730
0800
0830
0900
0930
1000
1030
1100
1130
1200
1230
1300
1330
1400

TOTAL
A ACT
0
357
103
309
192
295
435
436
281
382
156
28
7


3081
Meter Temp *R
538
540
542
544
546
548
551
552
• 554
555
556
555"
554



Baro. Hg
Inches
30.10
30.10
30.10
30.10
30.10
30.10
30.10
30.10
30.10
30.10
30.10
30.10
30.10


A SCP
0
351
101
302
187
286
419
420
365
366
149
27
7


2980
% Chart
79
78
77
77
78
78
78
78
79
79
78
77
76



ppm as C^
2300
2200
2000
2000
2200
2200
2200
2200
2300
2300
2200
2000
1900


Diluted.
ppm
1900
1800
1700
1700
1800
1800
1800
1800
1900
1900
1800
1700
1600


t
Undiluted
ppm
24000
22000
21000
21000
22000
22000
22000
22000
24000
24000
22000
21000
20000


Lbs/Ft3
5.2 x 10-3
4.8 x ID'3
4.6 x ID'3
4.6 x 10-3
4.8 x 10-3
4.8 x 10-3
4.8 x 10-3
4.8 x 10-3
5.2 x 10"3
5.2 x 10-3
4.8 x ID'3
4.6 x 10-3
4.4 x ID"3


21000 14 Ibs/dav
1 " ;

-------
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                      J      I	     I
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|i 80
a   A«
r- » * ;•
                                        I  	I      I	I
                                                                         I      I
                                              II00    (1i)4    |VX)

-------
 3 I0°


 S  »
 Q
             PLANT NAME
             CHEMICAL^ lies)]*
                  •


             COLOR
             LIQUID HEIGHT



             OUTAGE    1
TVP |,3>> .:
TANK HT. 4Ci
CAPACITY 3O,ftf)0
psia
ft.
bbls
DATE ^1 1 0 /?• C^
                                                       (   "
06OO   O7OO   0900   0900    tOtfO    1100   HOC?
V
                    J
                   otao
                          0340
                                              (I J-'
>
5
do
                                              llu
-------
           APPENDIX D
O.V.A. CALIBRATION CURVE CHARTS

-------
10,000
8.000
6,000
4.000
^ 2.000
a.
CL
CD
1 —
ji i.ooo
u 800
o
" 600
«t
0
Sf 400
200
too
OVA 1400 C3 CALIBRATION CURVE








































































































/
'










j
~if
/
/
/
/












/














/
/
/














/













'
0 10 20 30 40 50 fin 70 80 90 100
RESPONSE (% OF CHART)
tn

-------
10.000
B.OOO
6.000
4.000
E
£ 2.000
z:
0
i —
••x:
oc
S |.°o°
C_3
o 800
z 600
•*s
o_
O
cc
Q_
400
200
100
OVA 1410 C3 CALIBRATION CURVE







































































































/
/
'











j
y^
y
f












/
/














/
/
'














/













•
9 10 20 30 40 50 60 70 80 90 100
RESPONSE (% OF CHART)
-n
c?
c=
ao
m
t^a

-------
£D
CXI
O
PROPANE CONCENTRATION (ppm)
— K5 *k O5 tt O
— ro *k O) OD O O OOOO
o o oooo o oooo
OVA 1410 C3 CALIBRATION CURVE















































































/
/
/
/
r










/
/
/
/



















































































3 10 20 30 40 50 60 70 80 90 100
RESPONSE (% OF CHART)
-n
tn
c:
•so
m
CJ

-------
                                                              FIGURE  111-4
7.000
6,000
5.000
4.000
3.000

2.000
 ,000
  800
  600
  500
  400
  300

  200
  100
  80
  60
  50
  40
  30
       SOPROPANOL  Q.V.A.  1400 CALIBRATION CURVE
                20
 40          60
RESPONSE (% OF CHART)
                                                  80
                                                            100
                                                      ENGINEERING-SCIENCE

-------
                                                                    FIGURE  Ml-5
    7.000
    8,000
    S.OOO
    4,000
    3.000

    2.000
S  1,000
N^
ae    800
^3
3    800
H-
LLJ
H    400
u
_«


S    20°
      100
      30
      60

      40
             ETHANOL O.V.A..  1400 CALIBRATION CURVE
                    20
              z
 40          80
RESPONSE (%  OF CHART)
80
100
                                                            ENGINEERING-SCIENCE

-------
                                                                  FIGURE  111-6
   7,000
   6.000
   S.OOO
   4.000

   3.000

   2.000
S 1,000
g  800

g  600
h—
ae
UJ
CJ
g  400

ej

—  200
     100
     80
     60

     40
     30
           ACETIC ACID Q.V.A.  1410 CALIBRATION CURVE
                   20
   40          60
RESPONSE (* OF CHART)
80
                                                                100
                                                          ENGINEERING-SCIENCE

-------
                                                                FIGURE  111-7
        ETHYL BENZENE  O.V.A.  1410  CALIBRATION CURVE
   7,000
   6,000
   3,000
   4,000
   3.000

   2,000
e'
   1,000
    800
    600

    400
    200
    100
     80
     60

     40
     20
                   20
  40          60
RESPONSE (% OF CHART)
                                                    80
100
                                                         ENGINEERING-SCIENCE

-------
          APPENDIX E

FORMALDEHYDE GAS CHROMATOGRAPH
       CHART REDUCTION

-------
APPENDIX TABLE E-l
FORMALDEHYDE GAS CHROMATOGRAPH
CHART REDUCTION
THERMAL


Formaldehyde
Attn Area ppm i
4 16
4 16.
4 16
1
5000
5 5000
5000





i
i
CONDUCTIVITY

Water
Attn Area
4 7.0
4 7.5
4 7.5
CALIBRATION

:|
ppm |
5000
5000 :
5000


Methanol
Attn Area
4 14
4 14
4 13.5


ppm
5000
5000
5000






APPENDIX TABLE E-2
FORMALDEHYDE GAS
CHROMATOGRAPH
CHART REDUCTION




1 Formaldehyde
Date Time
4/26/78 1300
1345
1445
1500
1600
1730
Attn Area
i
i 4 42.0
! 4 42.0
4 41.0
4 42.0
; 4 41.0
4 42.0
1800 4 41.5
i
2000 : 4 A 3.0
2030
2045
4/27/78 1230
1300
1330
1400
1430
1500
1530
•' 4 42.0
' 4 42.0
4 45.0
. 4 48.0
4 49.0
1 4 44 . 0
' 4 43.0
4 48.0
4 45.0
ppm
13000
13000
13000
13000
13000
13000
13000
13000
13000
13000
14000
14000
14000
14000


Water
Attn Area
4
4
4
4
4
4
4
4
4
4
4
4
i
4
i
4
13000 4
14000 4
14000 4
103
103
100
96
105
92
90
77
95
95
112
107
105
108
110
103
108


:i
ppm :
i
70000
70000 :
68000 ,
66000 ;
72000
63000
62000 :
53000 ;
65000 i
65000
77000
73000
72000
74000

Methanol
Attn Area
1
1
1
^
1
1
1
1
l'
1
1
1
1
75000 . 1
70000 1
74000 1
5.0
5.0
4.5
4.5
6.0
6.0
4.5
3.5
4.0
4.5
6.0
5.0
4.5
5.0
6.0
4.0
5.0


ppm
450
450
410
410
540
540
410
320
360
410
540
450
410
450
540
360
450

-------
        APPENDIX F
EQUIPMENT USED FOR TESTING

-------
                                    APPENDIX TABLE F-l
                                EQUIPMENT USED FOR TESTING
Description
Pump
Pump
Dilution System
Recorder
Magnahelic
Digital Temperature
Indicator
Manufacturer Model
Cast Mfg. Corp. DOA-104-AA
Thomas Industries, Inc. 107C Series
(Built by ES) 	
Linear Instruments N/A
Corp.
Dwyer Instruments Cat.tf 2310
Omega Engineering 175
Comments
Used to pull sample from
source. One pump was also
required to pull dilution
system air.
	
No integrator.
0-5" H20
Ten channel digital read-
out.
Positive Displacement
Gas Meter (Roots)
Dresser Industries, Inc. Ilml25
               125 PSIG - 11,000 CFll Max
               310 M3/H - 860 KPA
               Four inch flanges, 10-1/2"
               between flanges.
Turbine Gas Meter
(Singer)
American Meter Div.
AL-425
425 CFH <§ 1/2" Diff.
900 CFH @ 2" Diff.
M.A.O.P-10 PSI

-------
                           BASIC  TEST  EQUIPMENT CONFIGURATION
                                                            SAMPLE RETURN  LINE
SAMPLING MANIFOLD
 BLIND FLANGE
                                                                MAGNAHELIX
                                                                PRESSURE  GAGE
                                                                            STRIP
                                                                            CHART -,
                                                                         RECORDER /
HEATED LINE
   REOSTAT~7
               FIXED ROOF TANK
              EXPLOSION PROOF PUMP
                                                                                     HYDROGEN
                                                                       ORGANIC VAPOR ANALYZER
                                                          DILUTION SYSTEM

-------

-------
                              WARRANTY

    OMEGA warrants this unit to be free of defects in materials and work-
    manship and to give satisfactory service for a period of 1  year. If the
    unit should malfunction,  it must be returned to the factory for evalu-
    ation. Our  Customer  Service  Department  will issue  an  Authorized
    Return  Number immediately upon phone  or written request. Upon
    examination by OMEGA, if the unit is  found to be defective, it will be
    repaired or replaced at no charge. However,  this WARRANTY  is VOID
    if  the unit shows evidence of having been opened or tampered with,
    shows evidence of being damaged as a result  of excessive  current,
    heat/moisture, vibration or misuse. OMEGA assumes no consequential
    warranties or obligations beyond repair or replacement of the above unit.

                   OMEGA  ENGINEERING INC.
(IMMMMMM^
                    OMEGA ENGINEERING, INC.
          P.O. BOX 4047, STAMFORD. CONNECTICUT 06907
                        PHONE (203) 359-1660
                             TELEX 996404

    The maienai in ihis manual is COPYRIGHTED and is presented here wiih ihe
    authors permission. No material in this book may be reproduced witnoui written
    permission.
SECTION l
   l.l
    i 2
    .2.1
    .2.2
    .2.3
    .2.4
    .2.5
    .2.6
    .2.7
    .2.8
SECTION 3

   3.1
   3.2
   3.2.1
   3.2.2
   3.2.3
   3.3
   3.3.1
   3.3.2
   3.4
   3.5
SECTION 5

   5.1

   5.2
        MODEL 175

    DIGITAL PYROMETER

      OWNERS MANUAL


    TABLE OF CONTESTS

CERTIFICATION ANU  IIAKKA.MV

INITIAL CHECKOUT PROCEDURE

     DESCRIPTION

       General
       Specifications
        Input
        Accuracy
        Conversion
        Display
        Digital  Signals
        Power
        Central
        Ranges

     RECEIVING AND INSTALLATION

       Unpacking  and Inspection
       Mechanical Installation

     OPERATING INSTRUCTIONS

       fin Assignments
       Powe r
        Input Voltage
        Input Fu&e
        Output Voltage
       Signal  Input
        Signal
        Ground Precautions
       Digital Signal Outputs
       Digital Signal Inputs

     ADJUSTMENT AND CALIBRATION

     Outline and Mounting

     OPTIONS

       Analog  Output (Option 05)

       Digital Controller (Option 06)
    Primed in U.S.A.
                                            ©OMEGA ENGINEERING. INC.

-------
CERTIFICATION
                                                                                                                          INITIAL CHECKOUT PROCEDURE
OMtCA  e.SuINCEKlNC.  IXC.,  certifies  chat this  instrument  was throughly in-
spected  and  tested at  the  factory  prior to shipment  and  found  to luet all
requlreoents defined by the contract under which they arc furnished.



Warranty and Assistance


OM£CA warrants  this  unit  to be tree of  defects in  Materials  and workmanship
and to <;ive  satisfactory service  for a  period or  1  year.  If  the unit should
calfunction,  it East be returned to the factory  for  evaluation.  Our Customer
Service  Department  will issue  an  Authorized  Return Number  immediately  upon
phone or written request.   Upon examination  by GlIECA.  if  the unit is found to
be defective,  it  will  be repaired or  replaced at no  charge.   However,  this
UAKKAim  is  VOIu  if the  unit  shows evidence of  having  been  tampered with.
shows evidence of  bein^ damaged us a  result of excessive current,  heat mois-
ture,  vibration or cisuse.    U!t£CA  assumes  no consequential  warranties  or
Obligations  beyond repair or replacement of the  above unit.


In all orders  for  service,  please  include a description of the failure and a
diagram ot  the  test  conditions that  will allow  the  factory  to reproduce the
failure syaptoms.
                                                                                                       See Section 2.1 for Unpacking and Inspection  Instructions.
                            CAUTION

        Meters art Internally connected for either 115V
        or 230V AC power, or 5V DC power.   Check label
        on meter for proper supply voltage.
REQUIRED EQUIPMENT

   1.   115V or 230V 50-60 Hz power  source  (4.3 watts), or
        5V DC at 750.T.A.
   2.   Three wire AC power cord, or a  two  wire DC power cord.

   3.   Flat blade screwdriver  (1/4" blade).

   4.   Piece of copper buss wire.

   5.   100 Ohm resistor.

TEST EQUIPMENT

   1.   Connect AC power as follows:

        a.   AC power HI (Blk)  to TB1-1.

        b.   AC power LO (Uht)  to TB1-2.

        c.   AC power CND  (Crn)  to TBl-3.

   2.   Connect DC power as follows:

        a.   +5V DC to TB1-2.

        b.   5V DC Return  to TBl-3.

   3.   For Thertoocouple Meters  connect a piece of copper wire
        between TBl-5 and TB1-6.

   4.   Apply power and examine  the  display.    The readout should
        show the approximate ambient temperature in °C or °F as
        applicable.

   5.   For RTD meters connect  a 100 Ohm  resistor between TBl-5
        and TB1-6.  Then connect a piece of copper wire between
        TBl-4.and TBl-5.

   6.   Apply power and examine  the  display.   The readout should
        show approximately zero.
                                     -2-
                                                                                                                                      -3-

-------
                     o
                     B
                     e
            8  it I
-4-
                                                                                           SECTIOH 1

                                                                                          DESCRIPTION
1.1       General

          Dual  slope  Integration with automatic zero correction
          Is  universally  accepted as the most accurate method
          of  analog to  digital conversion.   In the Model  175
          this  technique  is  further enhanced by the untillzation
          of  low noise  Input components to maintain noise levels
          below the resolution or the thermometer.  Accuracy
          near  the reference temperature of  each range Is not
          degraded by normal mode noise because the 175 perfoncs
          true  bipolar  signal Integration around zero.  Many
          competitive meters rectify the signal before intergra-
          tlon  which  erroneously adds the absolute value of
          the normal  oode noise to the signal reading.  The 175
          average value circuit provides full normal mode and
          superior AC line transient noise rejection at all
          signal levels.

          An  Inherent feature of dual slope  integration is the
          automatic rejection of AC Una noise on the signal
          If  the signal integration period Is equal to a multiple
          of  the AC line  period.  In the Halt with prcclsly
          equal periods the AC line noise rejection is Infinite.
          The Model 175  uses an accurate and stable oscillator
          which limits  the instability of the signal measuring
          interval to within i;!X and provides 30 dB of normal
          mode  rejection.  An'input filter provides an additional
          30  dB of normal mode rejection.  Overall, normal oode
          rejection is  the sua of these two  numbers of 60 dB.

          Noble metal and some base metal thermocouples are
          described by  the expression eof - AT + BT? in which
          cicf is the  output voltage, T is the temperature stim-
          ulus,  and A and B are constants.   Over the full range
          a thermocouple  output can be divided into two or three
          intervals that  are each described by an &nf expression
          with  different  values for the constants.   It should be
          noted that  the  two terms of the emf expression are the
          first  terms of  the series expansion of Ln(l-X).   By
          utilizing Ln(l-X) functions to fit the thermocouple
          characteristic  in the two or three Intervals, the
          resulting conformity error is less than the thermo-
          couple limits of error.  OMEGA'S  POUYLGC llnctrizer
          (patent applied for) is equal in perforoance to 16 to
          20  segment  digital or diode function generator llnear-
          Izer but without the drift and complexity problems of
          Cha diode function generator.
                                                                                              -5-

-------
1.1       (Continued)

          A platinum RTD la described by the  expression
          RT - Ro(l + CT -  DT2)  In which RT Is  the resistance
          at a given tcnperature,  RO is  the resistance at 0 °C,
          T Is the temperature stimulus, and  C  and D  are con-
          stants.   By subtracting  the Rp term (offset) from the
          R-r expression one is left with two  terms that are the
          first two terms of the scries  expansion of  Ln(l + X).
          By utilizing one  of at the moat two Ln(l +  X) functions
          to describe the Pt RTD over Its entire range the result-
          ing conforaity error is  less than 0.2%.  OMEGA'S
          POLYLOG  llneatizer (patent applied  for) in  this case
          is equal In performance  to a 64 segment digital llnear-
          Izer.
                               -6-
                                                                                                1.2
        Specification*
1.2.1     Input

            Configuration 	 Single-Ended


            Polarity 	 Bipolar with Polarity
                                      Indicator
            Zero 	Automatic with negligible
                                      long term drift.   Thermal
                                      emf's from Input  terminals,
                                      signal conditioning and
                                      basic meter Is less than
                                      0.15uV/°C.
                                                                                                            Full Scale Voltage 	20mV to 200mV


                                                                                                            Overvoltage Protection .. 130V RMS for TC or 6Vp
                                                                                                                                      for RTD without damage


                                                                                                            Impedance 	 100 Megohm


                                                                                                            Bias Current 	 1 Nanoamp
                                                                                                            Sensor Break Detection .. 60 Nanoamps current source
                                                                                                                                      with positive Overload
                                                                                                                                      Indication
                                                                                                            Lead Resistance 	 250 Ohms max for rated TC
                                                                                                                                      accuracy.
                                                                                                                                      Add 0.005% R per Oho of
                                                                                                                                      RTD conductor resistance
                                                                                                                                      to overall RTD accuracy.
                                                                                                            NMR @ SO/60 Hz 	 60dB  .
                                                                                                            CMR with 250 Ohm
                                                                                                             Imbalance 	 120dB AC power to Signal
                                                                                                                                      low.  120dB (opt) Digital
                                                                                                                                      Cnd to Signal low.
                                                                                                            CMV (DC to 60 Hz) 	 500 volts peak.
                                                                                                                              -7-

-------
1.2.2     Signal Conditioning

            Reference Junction
From 10-40 C ambient.
             for base
metals and 0,05 deg/de
                                        0.03  dcg/dee  for base
                                        metals  and 0,05 deg/deg
                                        for noble metals with I
                                        dej>  resolution.  Sensor
                                        offset  adjusted to zero
                                        from front  panel.

                                        Fron 10-40  C ambient, 0.02
                                        deg/deg for platinum with
                                        1.0  deg resolution.  Sensor
                                        offset  adjusted to zero
                                        from front  panel.
1.2.3     Conversion

            Technique

              TC 	  Dual  Slope, Average value

              RTD 	  Dual  Slope ratlometrlc,
                                        average value

            Signal Integration 	  100 milliseconds

            Reading Rate 	  Int.  3/4see, Ext. 0 to
                                        3-4/sec.

            Linearization 	  POLYLOG (patent applied
                                        for)
1.2.4     Display

            Type 	  13mm,  7  segment LCD

            Symbols 	  0.0.0  to -1.9.9.9

            Decimal Points  	  Any of Three

            Overload 	  3  Least  Significant Digits
                                        Flash.
                                                          1.2.5    Digital Signal*
           Logical '0'  	  0 to .6V        (Input)
                                       0 to .4V        (Output)

           Logical '!'  	  2.0 to 5.5V     (Input)
                                       2.4 to 5.5V     (Output)

           1 Unit Load  	  Logical '0' 1.6mA
                                       Logical '!' .04mA

           Hold	  '0' - Hold data
                                       Input load - 1 Unit load

           Data Ready	  '0* - Valid data
                                       Output drive - 3 Unit loads

           BCD Parallel Data 	  '!' -True
                                       Output drive - 3 Unit loads

           + Polarity	  '!' -Positive
                                       Output drive - 1 Unit load

           Overload	  'I1 - Overload - 3 Unit loads


1.2.6    Power

           Input Voltage	  115V  +101  50/60 Hi
                                       230V  T10Z  50/60 Hz  Option 01
                                       100V  +10Z  50/60 Hz  Option 02
                                       5VDC  J5Z    7SOxA     Option 03

           Input Power	  4.5 watts  at nominal Input

           Output Voltage 	  +5V @ 100mA without options
                                                                                                                              -9-

-------
1.2.7       General

              Operating Temperature	0°C to 40°C

              Storage Temperature 	  -40°C to 70°C

              Humidity	  Up to 95* at   40°C

              Weight 	  540g or 1.2 Ib.

              Case Material 	  ABS KJB

              Case Size

                Bezel (U x H x T)	  (96 x 40 x 6)am on
                                         (3.78 x 1.89 x 0.24)  In.

                Depth Behind Bezel
                Ulth Connector	  135.4mm or 5.33 In.

                Panel Coutout (W x U)...  (92 x 45)mm or
                                         (3.62 x 1.77)  In.

              Corjiectors 	  Barrier Strip,  Signal
                                         and Power.   36 Pin
                                         connector*  BCD output
                                         36 Pin connector,  options
                                         (Viking VK 180/12.
                                         SAE DAC 180/1-2,
                                         Winchester HSD 18SO)
                             -10-
                                                                                                   1.2.8     Ranges
TEMPERATURE SENSOR HANGES 4 ACCURACY 41 23'C
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»**
                                                                                                           Conformity errors are with respect to thermocouple reference
                                                                                                           tables based on the IPTS-68 and DIN 43760, September 1968.
                                                                                                           for platlnun RTD.

                                                                                                           Overall error Includes all error sources (basic meter,
                                                                                                           signal conditioner, llnearizer conformity, etc.) @ 25°C.

                                                                                                           Long Tera Stability 	 0.15Z error/yr
                                                                                                                               -11-

-------
                            SECTION 2

                   RECEIVING AND INSTALLATION
2.1       Unpacking and Inspection

          Your Model 175  was fully Inspected and tested.  Chen
          carefully packed before shipment.   Unpack Che meter
          carefully and Inspect It for obvious  shipping damage.
2.2
          Mecha
                         illation
          The Outline and Mounting drawing on  the  last  page
          Illustrates the mounting method for  your digital
          pyroneter.   The unit Is Inseted from the front of
          the panel and held In place  by  two slide retainers.
          The panel thickness may be between . 75tnm (.030") and
          6.35mm (.25").
                            -12-
                            SECTION 3

                     OPERATING INSTRUCTIONS
3.1


3.1.1
                                                                                                              Fin Assignment!
          Connector TB1
                                         POWER
                           AC OPERATION         5 DC OPERATION

                           AC Power HI           N/C

                           AC Power LO           +5 Volts

                           AC Power CUD         5V Return
                                                                                                                                           FUNCTION
                                                                                                                TBl-PIN         TC OPERATION         RTD

                                                                                                                   4            AC Guard Shield     	
                                                                                                                   5            TC (-)  Input        	

                                                                                                                   6            TC (+)  Input
                                                                                                                J5
                                                                                                                TB1
                                                                                                                Jl
                                                                                                                                                       OPTION  BOARD
                                                                                                                                                       HAIN  BOARD
                                                                                                                           REAR VIEW OF UNIT

                                                                                                                               Figure  2
                                                                                                                                 -13-

-------
3.1.2
          Connector Jl
J1-P1N
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
13
FUNCTION
No Connection
Spare
No Connection
Blank
COMP
SIC
Clock
80 Bit
40 Bit
20 Bit
10 Bit
IK Bit
Spare
Spare
+5V
Signal Gnd
Signal In
OL
Connector Type Viking

X— Key
	 1 	
	 | 	 	
Jl-PIN
A
B
C
D
E
F
H
J
K
L
M
N
t
R
S
T
U
V
FUNCTION
Spare
No Connection
Spare
1 Bit
2 Bit
4 Bit
8 Bit
100 Bit
200 Bit
400 B1C
800 Bit
1- Polarity
Data Ready
Hold
Ext OL (In)
Digital Cnd
Conv
RF.F
Viking VK18D/12
SAE SAC18D/12
Winchester HSD18SO

	
18
__
                            Figure 3

                Connector  Pin Orientation ns Viewed
                From the Rear of  the Meter.
                             -14-
                                                                                                   3.2       Power
                                                                                                   1.2.1     Input Voltage

                                                                                                             The standard meter operates  from 115V +1
                                                                                                             60 He.  1C consumes about 4.1 watts.   A three wire
                                                                                                             connection should be used to connect  power to the meter.
                                                                                                             Tvo conductors provide pover and the  third provides a.
                                                                                                             ground for noise rejection.

                                                                                                             Option 01 Is 230V +107., 50 He operation.   To change the
                                                                                                             meter In the flold7 from 115 to 230V  operation,  use the
                                                                                                             following procedure.  See Figure 3

                                                                                                                (1)  Remove power lines from meter and remove the
                                                                                                                     meter form the case.

                                                                                                                (2)  Remove the two jumpers on the transformer Ul
                                                                                                                     and U2.

                                                                                                                (3)  Add jumper W3 on the printed  circuit board.
                                                                                                                     The meter Is now wired for 230V.

                                                                                                             To change the meter from 230V to 115V operation, reverse
                                                                                                             the above steps.


                                                                                                   3.2.2     Input Fuse

                                                                                                             The power Input Co the Model '75 Is protected by a
                                                                                                             carbon composition resistor fuse.  If the meter  c*oea
                                                                                                             not light and It is suspected that the fuse has  been
                                                                                                             blown, check the continuity of the primary circuit.
                                                                                                             The resistance from power HI to power Lo  will be
                                                                                                             approximately 180 ohms for 115V meter and 700 ohms
                                                                                                             for the 230V meter.  If the fuse Is blown. It Is
                                                                                                             Imperative that It Is replaced by an  Identical pare,
                                                                                                             failure Co do so will void the warranty.   The fuse
                                                                                                             Is an Allen-Bradley 1/8U  10 ohm, +10% carbon
                                                                                                             composition resistor OMEGA pare nuxber  8111109.


                                                                                                   3.2.3     Output Voltage

                                                                                                             The +5V output la a regulated supply  'with the voltage
                                                                                                             range 4.5V Co 5.1V.  A maximum current of 100mA  Is
                                                                                                             available for external use.
                                                                                                                                -15-

-------
3.3       Signal Input


3.3.1     Signal

          For beat results  a shielded thermocouple should be used
          for the Input signal,  with the  shield  terminated to
          Signal Ground at  the connector  TBl-4.

          Signal Ground end Digital  Ground  are Internally connected
          and should not be connected externally.


3.3.2     Ground Precautions

          All Digital Signals used should be  returned to Digital
          Ground Pin T.

          Analog Ground Pin 16 or  TBl-4 may be used for a shielded
          thenrocouplc or RTD cable  IF SHIELD IS NOT RETURNED TO
          DIGITAL GROUND AT AMY  PODJT.
                              -16-
3.4       Digital Signal Outputs


3.4.1     BCD Parallel

          All BCD outputs are TTL and DTL compatible.

               Logical '!'      2.4 to S.1V.  source 0.12mA
               Logical '0*      0 to 0.4V,  sink 4.8mA

          The data outputs  are parallel  BCD.   The  outputs are
          stable and valid  while Data Ready  (pin P)  Is  low.
3.4.2
          + Polarity

               Logical  '!'

               Logical  '0'
2.4 to S.lV. source 0.08mA

0 to 0.4V. sink 1.6mA
          The -I- Polarity output  Is  a  logical  '!'
          Indicates a  positive reading.
                                                 when  the  meter
                                                                                                   3.4.3
                                                                                                            Data Ready
                                                                                                                 Logical '!'
                                                                                                                 Logical '0'
                              2.4  to  S.lV,  source  0.12mA

                              0  to 0.4V,  sink 4.8mA
                                                                                                            Data Ready will go to a logical '0* at the end of a
                                                                                                            conversion cycle and to a logical '!' at the beginning
                                                                                                            of a conversion cycle.
                                                                                                  3.4.4
                                                                                                            Overload
                                                                                                                 Logical '!'

                                                                                                                 Logical '0'
                              2.4 to S.lV, source 0.12mA

                              0 to 0.4V, sink 4.8mA
                                                                                                            Overload will go to a logical '!' If the display Is
                                                                                                            equal to or greater than the Internal overload set
                                                                                                            point or when Pin S Ext. OL In Is forced low by
                                                                                                            external command.  It Is stable while Data Ready Is
                                                                                                            low.  The Overload bit will reset during each
                                                                                                            conversion cycle.
                                                                                                                                -17-

-------
3.4.5
3.A.6
3.4.7
3.4.8
Conv.

     Logical '!'     2.4 Co 5.IV.  source 0.32mA

     Logical '0'     0 to 0.4V.  sink 6.4mA

Conv. will go to a logical 'O1  at  the beginning of a
conversion cycle and to a logical  'I1 at the end of
a conversion cycle.


Clock

     Logical '!'     2.4 to 5.1V.  source 0.12mA

     Logical '0'     0 to 0.4V.  sink 4.8mA

Clock Is factory set at 20KJIz +17..   It la available
during the conversion cycle ana1 If gated off with (SIC)
signal tlrae it can be used as a serial BCD output.
          SIC

               Logical '!'     2.4 to 5.1V source 0.12oA

               Logical '0'     0 to 0.4,  sink  4.8mA

          SIC will go to a logical '!'  at the  beginning of
          signal integrated and will go to logical '0* at the
          end of signal Integrate.
               Logical '!'      2.4 to 5.1V,  source  0.12mA

               Logical 'O1      0 to 0.4V,  sink  4.8mA

          REF will go to a logical '!'  at  the beginning  of
          reference Integrate and will go  to logical  '0' at
          the end of reference integrate.
                              -18-
                                                                                                 3.5


                                                                                                 3.5.1
                                                                                                 Digital Signal  Inputs
Hold
     Logical '!'     2.0V, source 0.16mA

     Logical '0*     0.8V, sink 3.2mA

When a logical '0' Is applied to the Hold input, the
meter will finish the conversion cycle ic is on and
will hold that reading.   If it Is applied before the
beginning of a conversion, the meter will no t start
that conversion.  Upon a logical '!' at the Hold
Input, a new conversion will begin within 360msec.
                                                                                                 3.5.2
                                                                                                                      2.7V,  source  .040mA

                                                                                                                      0.4V,  sink  1.2mA

                                                                                                 When  a external control  signal is  wired to  Pin S and
                                                                                                 goes  to a  logical  '0', the  three least  significant
                                                                                                 digits will  flash.
                                                                                       3.5.3
                                                                                                                Logical  'I1

                                                                                                                Logical  '0*
                                                                                                                      2.4V,  source  0.12mA

                                                                                                                      0.4V,  sink  3.6mA
                                                                                                When  a  logical  '0'  is applied  to  the  Blank  input,  the
                                                                                                three least significant digits will go blank.
                                                                                       3.5.4
                                                                                                 Comp.
                                                                                                       Logical  'I1

                                                                                                       Logical  '0'
                          1.5V,  source 0.0mA

                          0.8V,  sink 4.8mA
                                                                                                 3.5.5     Decimal Points

                                                                                                          Any of three decljnal points can be lighted by connect-
                                                                                                          ing the appropriate jumper with a bridge of solder as
                                                                                                          shown in Figure 4.
                                                                                                                               -19-

-------
                                                                                           SECTION 4

                                                                                  ADJUSTMENT AND CALIBRATION
IP,
                                                               4.1       The Model 175 was calibrated aC the factory with a
                                                                         precision source.  Frequent calibration Is not
                                                                         necessary due to the stability and Internal accuracy
                                                                         of the meter.  All adjustments are sealed except the
                                                                         zero adjustment which Is accessible with the lens
                                                                         reravcd.

                                                                         If calibration Is required, return to the factory for
                                                                         calibration."  Be sure to pack In a shipping container
                                                                         of sufficient size to allow ample packing material
                                                                         around unit  to prevent damage in shipping.


                                                               4.2       Calibration  Verification for Thermocouples.

                                                                         The following procedure should be used to verify the
                                                                         calibration  of thermocouple type meters.

                                                                           1.  Connect test cables as shown in Figure S.

                                                                           2.  Apply  power and allow meter to waro up for ten
                                                                               minutes.

                                                                           3.  Apply  zero volts from calibrated voltage source
                                                                               and verify readout of 000°C or 032°F.  Adjust
                                                                               zero pot If required (See Figure 4 for location).

                                                                           4.  Verify that the 175  is calibrated to the inter-
                                                                               national practical Temperature Scale, IPTS-63,
                                                                               as published In NBS Monograph 125 Issued March
                                                                               1974 or ASTM E230-72 or ASA C96.2-1973.


                                                               4.3       Calibration  Verification for RTD's

                                                                         The following procedure should be used to verify the
                                                                         calibration  of RTO type meters.

                                                                           1.  Connect test cables as shown In Figure 6.

                                                                           2.  Apply  power and allow oeter to warm up for ten
                                                                               minutes.
-20-
                                                                                             -21-

-------
4.3
          (Continued)
                 Apply appropriate resistance from the cal-
                 ibrated resistance source from DIN 43760,
                 September 1968.  This calibration, with an
                 a - .00385, Is for specially processed
                 platinum with Improved stability In indust-
                 rial environments.
                 NOTE:  Reference Paragraphs 4.2 and 4.3 see
                        Temperature Range and Accuracy Chart
                        1.2.3.
                              -22-
                                                                                                                                             MAIN BOARD
                                                                                                                                             THERMOCOUPLE
                                                                                                                                             WIRES
                                                                                            TWIST TOGETHER
                                                                                            AND SOLDER HERE
                                                                                                                       ICE  BATH

                                                                                                                     Figure  5
                                                                                                                        -23-

-------
                 REAR VIEW  OF UNIT
                                                                                                                OUTLINE  AND  MOUNTING
J5
TBl
Jl
1

18
1 1
A 1234
© |®|®l<2)|®
i
i-

A

5
®




6 V
©1 ©





18
-1

V

~v

f
                                                 MAIN BOARD
                                                     NOTE: ALL
                                                ^^  THREE WIRES
                                                     MUST BE THE
                                                     SAME LENGTH
                                                     AND CAGE.
                                                                                                                                                       PEAR Vltw
                                                                                                                                               (BEZEL NOT S«0»N fM CLAR.tr)
                                                                                                                                       CLAMP RiKos ooiArco i SLICE fiifAihtRS
                                                                                                                                       RtxovtO A3 SHOWN I OK INSTALLATION
                                                                                                            NOTC&: DIMENSIONS IN MILLIMETERS!.2suM
                                                                                                                  AND IN (INCHES);.oi in

                                                                                                                      DIN CASE
            3 WIRE RTD CALIBRATION
                    Figure  6
                         -24-
                                                                                                                         -25-

-------
5.1
5. I .1
       Analog Output  (Option 05)
        This option  18 contained  on a  second printed  circuit
       board  parallel  to  the main  board.    (See  Fig.  2,  Pg.
       13).   A  precal ibrated  linerizcd  analog   output  of  _^2
       volts maximum capable  of  driving a  1  MA  load  ia
       available for conventional  analog recording  and
       controlling  instruments.

       The  following connections  are required between  connec-
       tions Jl  and  J 5 :
a. Jl-C
b. Jl-2
c. J I-T
d. JI-15
e. Jl-U
f. Jl-v
o J5-U
o J5-17
o J5-16
o J5-U
o J5-10
o J5-P
g. Jl-N to J5-S
The analog output is ava
J5-V (Lo).
AC
AC
Digital Ground
»5 Vole s
CONV.
Ref.
• Pol.
liable between J5-18 (Hi) and

       NOTE:   If  connection Jl-N to  JS-S  is removed,  and  J5-S
       Is juDpered  to  J 5-U ,  an absolute  value  function  is
      •obtained  froo the 05 option.
                              -26-
                                                                                5.1.2  Field Calibration Procedure*:
MODEL 175

1.  Perform  needed cabling  between Jl lower connector  (meter)
    and J 5 (Option Board).

    Install  a  jumper  between  TBI -4  and  TBI -5  (Fig.  1).
    Connect  a  millivolt  source  to TBI -5  and  TBI -6 , and  oet
    for OHV.
                                                                                 2.
                                                                                 3.
     Apply  AC power  liatd on meter  label.   (115 VAC  or  230
    VAC).   The  analog  output  should  be  zero  and a  cero
    reading should be  displayed  with polarity  sign  toggling.
    Adjust  819  on option  board  for zero  voltage between J5
    pin  18  and  J 5  pin V if  necessary.   (Drawing  Mo.  06526).

     To  calibrate  positive  polarity,  open  the  thermocouple
    input  and  the  meter  will  display  its  positive  overload
    set  point.  (This  set  point  it inter nally  programmed  and
    will  vary  with  range and  type  of  meter.).   Adjust  R 5
    until the analog  output  in millivolts corresponds to  the
    flashing  displayed  reading.   (Drawing  Ho.  06526).

4.  To  calibrate  the  negative polarity  of the  analog  output
    option, disconnect power and remove the wire  attached to
    J5  pin  S . Short  pin S to pin  16 on J5.   Apply  power  and
    adjust  K6 until  the analog  output  in millivolts c or r e s~-
    ponds  to  the  flashing  displayed  reading.    Ignore  dis-
    played  polarity  on meter.   (Drawing No.  06526).

5.  Disconnect power.

6.  Remove  ground  jumper from J5  pin 5  to pin  16 and  re con-
7.  Reassemble meter  and  con
    couple  at   ice  point,  ad ju at   C  meters  for  a  toggling
    polarity  sign.    For   F meters  adjust  for  a  reading  of
    Ol .5°F  (example  31  toggling  32).   Zero  Pot • R  46  Shown
    o n Pg. 20  f igu re  4.
                                                                                                             nect thermocouple.   With thermo-
                                                                                                ice  point,  ad ju at   C
                                                                                                             -27-

-------
5.2  DIGITAL CONTROLLER  (Option 06)
     SPECIFICATIONS
     Power Required:   5V @ 6OHA f ron baaic  me te r.
     Accuracy  of  Switching  Point;   Same as  basic
     Outputs :
      tin. t»&  .„-....   	  _           eter,
 FORM C  relay  contact  rated  @ 2  AMPS 28 VDC
   or 1  AMP  @  115  VAC
ALARM -  1 TTL  load.
j^POLARlTV -  1  TTL  load.
OL/Teut  - 5  TTL  loads
Hi ALARM -  2 TTL loads
Lo ALARM -  2 TTL loads
RESET -  2 TTL  loads

O Volts 0  60  MA
12 BCD  BITS  *  1  TTL  load
POLARITY -  2 TTL loads
EXTERNAL RELAY CONTROL - 1 TTL load
EXTERNAL RESET - 2 TTL loads
ALARM  ZONE  - 2 TTL loads
LATCH  -  2 TTL  loads
COMP -  1 TTL load
 II.   Description,
      The  06  option is  a  two  state digital controller  or
      alarm which  accepts  up to 4  digits of BCD with  polarity.
      Its  outputs are  a Form  C relay,  a  TTL  output,  and  a
      front  panel  L.E.D.  which  flashca  when the  meter  is
      reading  in  the alarm zone.   (The  alarm  zone can  be
      above  or  below any  selected point.)  The  controller
      outputs  go  true  whenever the  meter   reading  is  in  the

                                       For  alarm  applications,
      the outputs  may  be set to latch  true  whenever  the router

      though  the  meter  reading  has returned  to  the  operating
      zone.   It raa y  be reset either externally  or  by pressing
      the front panel  button.
                                                  is true.
                                                            The
      The  TTL  alarm output is III when  the  al
      Form C  relay contacts  can  be  true  when  the  alarm is
      true or  can  be  externally controlled.   The  front panel
      L. H. D  flashes when  the alarm  is  true.   It  can be mad*;
      to  go  on continuously  or  inhibited  altogether.  Press-
      ing  the   front  panel button  causes  the  switching point
      to  be  displayed  on the  meter,  and  resets  the  alarm if
      latching  operation  is  being  used.   It  also  inhi-
      bits  the  alarm  output  for  about  1 second after  the
       button has been released.
                               -26-
     (Jl is the bottom  connector on the Model  175 or 2)0; J5
     is the  upper connector  on the aeter,  used  to  make all
     connections  to  the  05/06  option.)   See  Pg.  13,  Pig.
     2.
                                                                                      WARJ* INC ;   Disconnect  A.C.  powg r from meter  before doj n g
                                                                                                   any w i_r_i njj I
A. The
for
,_
2.
3.
4.
5.
6.
7.
1 o I 1 ow i ng
proper ope
(•5V)*
(CUD)'
(REF)*
(CONV)*
(SIC)
(OL)
(COMP)
connectio
ration of
J5-U
J5-I6
J5-P
J5-IO
J5-I2
J5-R
J5-I3
ns
an







mu ac be peraa
06 option:
JI-15
Jl-T.
Jl-V
JI-U
Jl-6
JI-S
JI-*
nently wired







* Required either  OS  or  06  or Both.

     B.   The  following connections vary  according  to your
         application:

         I.   Switching  Point:   Those  3CD  Bits  which are Hi
              (Positive  true logic)  for  the  desired switching
              point must  be wired  to  any  of  the  following
              Pins  on  J5:   1.  A. 2.  B, 3, C.  4,  D,  5, E, 6 or
              7.

              A.  Wire length  mu st be kept  under 6  inches  for
                 proper meter operation.   (See  D  below).

              B.    For example;   A  switching  point  of 673
                 requires  connecting  the 800,  40,  20,  10,  2
                 and I  Bits.   All other  BCD Bits  on  J5
                 should  be  left open, or connected to J 5  Pin
                 U through  a  single 1 OK  resistor.

              C.    For applications  where  the   operator must
                 change  the switching poing.  an external  BCD
                 thumbwheel switch  can  be  connected between
                 the  BCD outputs  and  the  controller  inputs.

              D.  If  wire lengths greater than  6 inches  total
                 are  needed,  a 100 Ohms,  1/8  Watt  resistor
                 may  be used  at  Jl  in   series  with each  BCD
                 Bit.
                                                                                                               -29-

-------
                                                                                5.2
                                                                                         cont inued
C.   TABLE - FIN ASSIGNMENTS  FOR 0} AND 06 OPTIONS  -  CONNECTOR Ji
     Fu nc t ion
BCD
BCD
BCD
BCD
BCD
    I npu t
    Input
    Input
    I npu t
    Input
-Pol Output
Pol Bit In
Relay Common

Re lay N.C.

Latch

Alarm to ne

Alarm Output

Re f 1nput* *

OT/ Test

•Pol In

Ext Relay Control

• 5 Bolts Power  In**
Pin

A
B
C
D
I
r
H
j

K

L

H

N

P
     Analog Output  (L0>*   V
     •05 Only
     ••05  and  06
                                        Fu nc t ion
                                        BCD
                                        BCD
                                        BCD
                                        BCD
                                        BCD
                                        BCD
                                             npu
                                             npu
                                        npu
                                        npu
                                        npu
                                        Hi  Pulie

                                        Relay N.O.
                                  Conv**

                                  LowPulae

                                  Signal

                                  Comp.

                                  ACV  for 0)*

                                  Re set

                                  Power CNO**

                                  ACV  For 05*
Pin

 I
 2
 3
 4
 5
 6
 7
 a

 9

10

11

12

13
                                                            13

                                                            16

                                                            17
                                        Analog  Output  (HI)* 18
IV  Polarity:
    A.   For  a  poaitive polarity  switching point  connect  J5
        pin S and J5 pin H to Jl pin N.

    B.   For  a  negative polarity  switching point,  jumper  J5
        pin H to J5  pin f.   Also connect J5  pin  S to Jl pin
        N.

    C.   For  a  switching point which ignores  polarity (abso-
        lute value)  connect  J5  pin  H to J5 pin U.   (If your
        meter has  an 05 option also; connecting  J5  pin H  to
        Jl pin  N will allow  the  05 to  function  with normal
        polarity,   while  the 06  functions  with absolute
        value. )

V   Alarm Zone:
    A.   For  a  HI  alarm zone:   (The  alarm  is  true  for all
        meter readings  equal  to or greater than  the  switch-
        ing point.)  Connect  J5 pin N  (ALARM  ZONE) to J5 pin
        B (111).

    B.   For  a  LO  alarm tone:   (The  alarm  is  true  for alt
        meter  readings  less than the  switching  point.)
        Connect  J5  pin H  (alarm zone) to J5  pin 11  (LO).

VI  Latch:

    A.  LATCHING OPERATION:
        If it is  desirable  for an alarm condition to remain
        true after  the meter  reading  has  returned  from the
        alarm zone  to  the  operating zone;   connect  J5 pin L
        (Latch) to J5  pin IS  (Reset).   This provides a reset
        Croa the  front panel button. Thia reset  lasts about
        1  second  after the  button  is  released.    The neter
        nay  be   reset externally  by   connecting  J 5  pin  L
        momentarily  to ground  (I  TTL   load)  (A 27K  pull  up
        to «5V  is necessary  and  is  provided  internally at  J5
        pin 15).

    B.  CONTROLLER OPERATION:
        If it  is  desirable  that  the  alarm reset  as  soon  as
        the meter reading returns from  the  alarm  zone to the
        operating  zone;   Bake  the  connection  specified
        be 1 ow:

        I.   If  the  alara  zone  is  HI;  connect  J5  pin  L
            (Latch)  to J5 pin  I I  (Lo).

        2.   If  the  alarm  zone  is  LO;  connect  J S  pin  L
            (Latch)  to J5 pin  8 (Hi).
                                -30-
                                                                                                           -31-

-------
 5.2
          c on C i Hue d
•VI I  OUTPUTS:

     A.   L.E.D.
         i s
on che front  panel  will flash when Che  a 1 am
                    are  required.   If  ic  ii
         desirable that che front panel  L.E.D.  not  flash  when
         che  alarm is true, cue Che wire  from  J 5  pin  12  to Jl
         pin  6.   This  will cause the  L.E.D.  simply  Co go on
         in  an alarm true state.  The  L.E.D. nay  be inhibited
         entirely  by  connecting J 5  pin  12  Co  J 5  pin  16
         (Jl   pin  6  must  be   left  open if  this  ia done).

     B.   The  alarm output ( J 5 pin N) can  source  1.5 TTL  loads
         or  sink 9.9 TTL  loads.  It  is  HI  when  Che  alarm is
         true.  (If  additional  source capability  is  desired.
         a  3,3 K pull up can be  added to  J 5  pin  15.  This  will
         allow  the   alarm output to  source  or sink  9  TTL
         loads . )

     C.   The  relay (Form C contacts) ia  driven  through J 5 pin
         T  (C'  1  TTL load):    Co  use  the  relay  as an a I area
         indicator or  to  controller;   connect J5 pin T  to J 5
         pin  N.

         1.   J5 pin  J is connected to  J 5  pin 9  when che  alarm
             is true (J5 pin T  HI ).

         2.   J5 pin  J is connected to  J5  pin K  when the  alarm
             is false.

         3.   The relay  contacts are  rated at  2  amps,  28  volts
             D.C.  or I  amp, at  115 volts A.C.

         4 .   Care  must  be  taken when using  the  relay  co  avoid
             coupling  noise  into  the  meter or  06 option.
                              -32-
                                                                                 5.2
                                                                                          cone inued
VIII Testing and Operation,

     After  the  06  Option has been wired  per  Section II; and
     the 05 Option, if any,  has  also been wired, apply power
     to  the  meter.  An  input  in the norms 1  operating range
     should  be  applied   to  the meter.   The  meter  reading
     should be normal.

     Press  che  fronc  panel button.   The switching  point
     should be displayed. Release  the  button.   After at least
     1   second,  apply  aa input  in  the  alarm  zone  (avoid
     overloading the'meter)*   The  outputs  should  go  true.
     causing a contact closure of  the  relay.   Continuity will
     exist between J5-J and  J5-9.  When  che mecer is returned
     Co  the  operacing  range the  outputs  should  return to a
     false condition causing the  relay to change scace giving
     continuicy between J5-J and J5-K.   If  che unit  ia wired

     nonencarily Co resec the relay.

     The  mecer  is   now  ready  for  use  in your  application.
     When the meter  reading is  in  che operacing  range,  the
     meter reads normally and  the outputs are  false.   When
     meter,  readings  enter  che  alarm zone;  the  front  panel
     L.E.D.  begins  flashing  (unless  inhibited) and the alarm
     goes true.   Pressing the fronc  panel  butcon recalls the
     switching  point,  which  is displayed,  and  also resec i the
     alara if latching operation is  being  used.   The alarnis
                                                                                                                           sd.
                                                                     NOTE:   Fals
                                                                      overload,  ic  is recommended  Chat  you avoid overloading
                                                                      you r  rae ce r.
                                                                                                              -33-

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         APPENDIX G
COMPARISON OF BREATHING IN
  AND BREATHING OUT DATA

-------
APPENDIX TABLE G-l
COMPARISON OF BREATHING IN AND BREATHING OUT DATA

Chemical Date
Isopropanol From
To
From
To
From
To
Ethanol From
To
From
To
From
To
From
To
From
To
Acetic Acid From
To
From
To

4/13/78
4/13/78
4/13/78
4/14/78
4/14/78
4/14/78
4/18/78
4/18/78
4/18/78
4/19/78
4/19/78
4/19/78
4/19/78
4/20/78
4/20/78
4/20/78
4/20/78
4/20/78
4/20/78
4/20/78
A ACF
Time In Out
0800
1430 3,436
1430
0645 2,937
0645
1600 4,215
0600
1400 1,325
1400
0630 1,100
0630
1440 1,217
1440
0630 1,553
0630
1530 1,432
0700
1200 7,580
1200
1315 1,219

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                            APPENDIX TABLE G-l  (Continued)
COMPARISON OF BREATHING IN AND BREATHING OUT DATA

Chemical
Acetic Acid
(Cont'd) From
To
From
To
From
To
From
To
Ethyl Benzene From
To
From
To
From
To
Cyclohexane From
To
From
To
From
To
Date
4/20/78
4/20/78
4/20/78
4/21/78
4/21/78
4/21/78
4/21/78
4/21/78
5/9/78
5/9/78
5/9/78
5/10/78
5/10/78
5/10/78
5/17/78
5/17/78
5/17/78
5/18/78
5/18/78
5/18/78
Time
1315
1600
1600
0615
0615
1200
1200
1530
0900
1500
1500
0700
0700
1430
0700
1500
1500
0730
0730
1330
A ACF
In Out
1,677
10,884
18,568
1,222
2,460
4,801
3,797
3,169
860
8,253
1)   It should be noted that a greater A ACF out  occurred in the formaldehyde
    and cyclohexane tanks because these are heated,  compared to the other tanks
    which were at ambient temperature.

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APPENDIX TABLE G-l (Continued)
COMPARISON OF BREATHING IN AND
BREATHING OUT DATA

Chemical
Formaldehyde From
To
From
To
From
To
From
To
From
To
Date
4/26/78
4/26/78
4/26/78
4/27/78
4/27/78
4/27/78
4/27/78
4/28/78
4/28/78
4/28/78
Time
0630
2130
2130
0800
0800
1500
1500
0815
0815
1400
A ACF
In Out
4,081
125
2,350
194
4,215

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