Um;.-,-: Stales
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research "mangle Park NC 27711
EMB Report 85-HWS-3
October 1985
Air
Hazardous Waste TSDF
Waste Process Sampling
Volume II:
Amoco Petroleum Additives Company, Wood River, IL
Reilly Tar and Chemical Corporation, Granite City, IL
Shell Oil Company, Wood River, IL
Texaco, Incorporated, Salem, IL
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Prepared for
U.S. ENVIRONMENTAL PROTECTION AGENCY
Office of Air Quality Planning and Standards
Research Triangle Park, North Carolina 27711
HAZARDOUS WASTE TSDF
WASTE PROCESS SAMPLING
VOLUME II.
Amoco Petroleum Additives Company, Wood River, IL
Reilly Tar and Chemical Corporation, Granite City, IL
Shell Oil Company, Wood River, IL
Texaco, Incorporated, Salem, IL
October 1985
Prepared by
GCA CORPORATION
GCA/TECHNOLOGY DIVISION
Bedford, Massachusetts 01730
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DISCLAIMER
This Final Report was furnished to the Environmental Protection Agency by
GCA Corporation in fulfillment of Contract Nos. 68-01-6871, Task No. 37 and
68-02-3851, Task No. 8. The opinions, findings, and conclusions expressed are
those of the authors and not necessarily those of the Environmental Protection
Agency. Mention of company or product name is not to be considered as an
endorsement by the Environmental Protection Agency.
ii
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TABLE OF CONTENTS
Page
Introduction iv
Amoco Petroleum Additives Company Trip Report 1-1
Reilly Tar and Chemical Corporation Trip Report 2-1
Shell Oil Company Trip Report 3-1
Texaco, Incorporated Trip Report 4-1
Appendix A - Sample Identification Forms A-l
Appendix B - GCA Data Report Forms B-l
Appendix C - Radian Corporation Data Report Forms C-l
Appendix D - Analytical Procedures D-l
Appendix E - RCRA Part A Permit Profile Sheet E-l
iii
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INTRODUCTION
Air emissions from hazardous waste treatment, storage and disposal
facilities (TSDFs) are currently being studied by the EPA Office of Air
Quality Planning and Standards (OAQPS). The four sites described herein
represent a portion of the testing program undertaken by OAQPS in an effort to
profile TSDFs and estimate emissions. The results of the testing will be used
as background information for possible standards for TSDF area source air
emissions.
Process sampling of wastestreams at the four sites was conducted. In
additions detailed information on all waste operations, emission controls and
operating practices was collected. The facilities were selected to increase
the scope of TSDF operations encompassed by previous case study and testing
programs. An effort was made to expand the data base in terms of treatment
operations, waste types and geography.
The wastestream characterization, sample analysis and waste process
descriptions should supply the necessary inputs to emission estimation
techniques. Liquid samples from waste treatment tanks and impoundments were
obtained from each site. Sludge samples from impoundments were taken where
applicable. The results of these analyses are presented for each site.
These four Illinois sites, visited in November 1984, represent waste
generators with on site treatment operations. All four are involved in the
petroleum products industry and include a production field, an oil refinery, a
tar refinery and a petroleum additives manufacturer. Sample analysis and
process descriptions reflect operations on the day of the visit. Included
with each trip report is a summary of the analytical sample results, the
actual analytical results and the Part A Permit Profile sheet for the facility.
iv
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Section 1.
Amoco Petroleum Additives Company
Wood River, IL
1-1
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TABLE OF CONTENTS
Section
I. Introduction 1-5
II. Wastestream Characterization Information 1-7
III. Facility Process Description 1-7
IV. Sampling Information. 1-9
Sample Location Description 1-9
Quality Assurance 1-11
V. Sample Analysis 1-12
Analytical Summary , 1-12
Quality Assurance 1-12
1-2
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LIST OF TABLES
Table Page
1 Model Input Data for Air Emission Release Rate Determination at
Amoco Petroleum Additives, Wood River, IL 1-10
2 Liquid Sample Analysis from the Sludge Lagoon at Amoco Chemical
Corporation in Wood River, IL 1-13
3 Liquid Sample Analysis from the Sludge Lagoon/Oil Layer at
Amoco Chemical Corporation in Wood River, IL. 1-14
4 Liquid Sample Analysis from the Sludge Lagoon Water at Amoco
Chemical Corporation in Wood River, IL 1-15
5 Liquid Sample Analysis from the Spray Pond at Amoco Chemical
Corporation in Wood River, IL 1-16
6 Liquid Sample Analysis from the Spray Pond at Amoco Chemical
Corporation in Wood River, IL 1-17
7 Solid Sample Analysis from the Sludge Lagoon at Amoco Chemical
Corporation in Wood River, IL 1-18
8 Cross Referenced List of Submitted Samples Collected at Amoco
in Wood River, IL 1-19
9 Quality Control Data for Analysis Conducted on the Samples
Collected at Amoco in Wood River, IL: Surrogate Recoveries -
Volatile Organics 1-21
10 Quality Control Data: Duplicate Aliquots of Sample ACC-OMS-1C
(GCA 41757) Spiked with Volatile Organics,
Amoco, Wood River, IL 1-23
11 Quality Control Data Matrix Spike Recoveries for Sample
ACC-SL-1C (GCA #41761), Amoco, Wood River, IL 1-24
1-3
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TABLE OF FIGURES
Figure Page
1 Facility layout, Amoco Petroleum Additives,
Wood River, IL 1-6
2 Disposal pond clean up process, and location and size of sludge,
clear water and oil slicks, Amoco, Wood River, IL. 1-3
1-4
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Site: Amoco Petroleum Additives Company
Old St. Louis Road
Wood River, IL 62095
FCID: ILD006272629
Site Contact: Richard A. Sumner, Environmental Engineer
(618) 251-2228
Field Trip Personnel: Andrew Baldwin, GCA/Engineering
James Thomas, GCA/Measurements
Richard Roat, GCA/Measurements
Chuck Vaught, GCA/Engineering
Richard Sumner, Amoco
Visit Time and Date: 9:00 a.m., 11/15/84
I. INTRODUCTION
The Amoco Petroleum Additives Company in Wood River, Illinois has been a
manufacturer of petroleum additives since 1983. The company was involved in
oil refining from 1907 to 1981, but decreased demand has ceased these
operations. Presently, Amoco employs over 285 workers and production includes
additives for lube oils, such as viscosity improvers and friction modifiers.
Amoco sells roughly 3 million gallons monthly to automotive oil companies.
Past refinery operations were performed at the main plant with treatment
of wastewater via mixing, aeration, and settling of sludges in a series of
treatment ponds. Treated liquid wastewater was discharged directly into the
Mississippi River. Cooling water was cooled in a 35-acre cooling pond via an
active sprayer system.
Presently the treatment of petroleum additive wastewater includes removal
of waste solids and biosolids via aeration and clarification in an enclosed
treatment facility. Effluent is discharged to the Mississippi River. The
facility layout is shown in Figure 1.
The size of the main plant is 586 acres; the old treatment ponds occupy
an additional 120 acres. Other oil refineries are located within a 1-mile
radius of the site. A residential area is situated to the east.
Climatological conditions the day of the visit were sunny skies, air
temperature of 50°F, and southwesterly winds at about 20 to 25 mph.
1-5
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RESIDENTIAL AREAS
PRODUCT STORAGE TANKS
OLD REFINERY
COMPANY BUILDINGS
PUMP HOUSf
35-ACRE
COOLING POND
SYSTEM
MISSISSIPPI
RIVER
Figure 1. Facility layout, Amoco Petroleum Additives, Wood River, Illinois.
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II. WASTESTREAM CHARACTERIZATION INFORMATION
Hazardous wastes generated by the facility primarily include oil sludge
and solids from heat exchanger leaks and tank bottoms. These were stored in
pond Nos. 1 and 2 and are now removed in the treatment process. Solid sludges
removed by DAF or API separator units during treatment of petroleum additive
production wastewater are dried and landfilled. Biosolids removed during
secondary clarification are recycled back to the treatment process. Effluent
has always been discharged into the Mississippi River. A more detailed waste
characterization was not available.
III. FACILITY PROCESS DESCRIPTION
The wastewater treatment system in use when Amoco was an active oil
refinery was a series of polishing surface impoundments until 1977 as shown in
Figure 2. Pond No. 2 served as a mixing lagoon; pond No. 1 served as a
storage lagoon for oil sludges and solids; and other lagoons were active
aeration and sludge settling basins.
A separate treatment facility began operation in 1977, and Amoco has
begun cleanup of the treatment ponds. An estimated 45 million gallons of
solids and sludges will be dried, chemically fixated, and stored in Pond No.
5. Dewatering was expected to be complete by the end of winter, including
transport of wastewater from Pond Nos. 2 and 4 to Pond No. 3, via subsurface
pipes and drainage into a surge basin enroute to the treatment facility. At
the time of the site visit the sludge storage lagoon (Pond No. 1) had an area
of standing water. Waste oil from past refinery operations still floats on
the surface of most ponds as well.
Treatment facility operations at Amoco include oil/water separation
followed by aeration via DAF (dissolved air flotation) unit processing.
Solids are bubbled to the surface, skimmed, belt-pressed, and sent to landfill
areas.
1-7
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EFFLUENT TO MISSISSIPPI RIVER
SURGE
BASIN
f
WASTEWATER -* PROCESS
TREATMENT WASTEWATER
WHEN ALL PONDS ARE DRY,
SLUDGE WILL BE EXCAVATED
AND LANDFILLED IN POND 5-
DOTTED ARROWS INDICATE
SUBSURFACE FLOW THROUGH
PIPES.
SAMPLING LOCATION
Figure 2. Disposal pond clean up process, and location and size of sludge,
clear water and oil slicks, Amoco, Wood River, Illinois.
1-8
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Wastewater is further biotreated in tanks using four 150 horsepower aerators.
A secondary clarification step removes biosolids which are recycled back to
the treatment tank. Effluent is eventually discharged into the Mississippi
River. Currently, water from the former treatment ponds is also being treated
in this system.
Since oil refinery operations have ceased, there is little need for
operation of the sprayer cooling system. Basically, the 35-acre pond serves
as a reservoir for cooling water pumped-in below the surface via a small, open
tank. From a waste standpoint, the pond is basically inactive. On the
average, its depth is 8 feet, and well water is pumped in when evaporative
losses become significant. A small oil slick has formed within the past
6 months, although the total surface oil content has drastically decreased
since refinery operations have ceased. However, sulfide sludges are still
present on the pond bottom.
Table 1 contains information necessary for estimating air emission
release rates of volatile organics from the cooling pond, sludge lagoon, and
old mixing lagoon at Amoco.
IV. SAMPLING INFORMATION
Sample Location Description
Three sources sampled (Figure 2) at the time of visit included:
o 35 acre cooling pond,
o sludge lagoon (Pond 1), and
o the old mixing pond (Pond 2).
Two quadruplicate liquid samples were obtained from the cooling pond.
One liquid sample (ACC-SP-l) was obtained at the inlet (16°C), the other
(ACC-SP-2) was taken at the outlet (13°C). These samples appeared slightly
cloudy.
1-9
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TABLE 1. MODEL INPUT DATA FOR AIR EMISSION RELEASE RATE DETERMINATION
AT AMOCO PETROLEUM ADDITIVES, WOOD RIVER, ILLINOIS.
Cooling Pond
Impoundment type:
Operation:
Typical throughput:
Handling/transfer:
Activity:
Surface area:
Average depth:
Typical retention times
Sludge Lagoon (Pond 1)
Impoundment types
Operation:
Activity:
Dimensions:
Surface area:
Average depth:
Old Mixing Pond (Pond 2)
Impoundment type:
Operation:
Handling/transfer:
Activity:
Dimensions:
Surface area:
Average depth:
Nonaerated
Continuous flow
10,000 gpm
Subsurface pumping
Storage
35 acres (1,524,600 ft2)
8 ft
150 hrs
Nonaerated
No flow in or out-drying
Disposal (inactive)
250 ft by 400 ft by 0-1 ft deep
100,000 ft2
1 ft where liquid present
Nonaerated
Continuous outflow, no input other than
storm runoff
Subsurface flow to pond 3
Disposal (inactive)
450 ft by 500 ft by 6-8 ft deep
225,000 ft2
7 ft
1-10
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One duplicate soil core sample (ACC-SL-C) was taken from the solid
material in the sludge lagoon (Pond 1) and a quadruplicate liquid sample
(ACC-OM-1) was taken from the liquid phase in the sludge lagoon (17°C).
Another quadruplicate liquid sample (ACC-OMS-1), temperature 15°C, was taken
from the oil slick in the old mixing pond (Pond 2). No splits were requested
by Amoco.
Quality Assurance
Sampling procedures were employed as described in the Quality Assurance
Project Plan dated 30 October 1984. Liquid samples were collected in
quadruplicate. Soil core samples were collected in duplicate. The
quadruplicate liquid samples and the duplicate soil samples were returned to
the GCA Analytical Laboratory in Bedford, MA where they were received into the
sample bank.
Sample custody and handling procedures included the use of sample tags,
chain-of-custody sheets, refrigeration of samples between sampling and
analysis, and shipping of samples in coolers sealed with custody seals. In
addition, each sample was assigned a unique sample code which linked it to the
facility, the source, and the sample point.
Some of the sample matrices and locations made it difficult if not
impossible to collect the liquid samples without air bubbles forming in the
40 ml VOA vial. In every case repeated attempts were made to obtain the
highest quality samples.
The samples from this facility which contained air bubbles include:
Sample Number Air Bubble Size
ACC-OMS-1A Small
ACC-OMS-1B Small
ACC-OMS-1D Small
1-11
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V. SAMPLE ANALYSIS
Analytical Summary
Tables 2 through 7 provide the analytical summary reports for all of the
process samples collected during the site visit (see Appendix A.). These
tables present the major compounds quantified by either GC/MS (GCA
Corporation/Technology Division) or a multiple detection system (Radian
Corporation). The actual data report sheets for each respective sample are
provided in Appendix B and Appendix C.
Analytical procedures are detailed in Appendix D. Aqueous po; amd soil
samples were analyzed as indicated.
Quality Assurance
Chain of Custody
A set of samples was received by GCA/Technology Division on November 19,
1984 for volatile organic analysis (VGA). Routine inspection upon receipt
revealed the samples to be clearly labeled and appropriately chilled. Air
bubbles were observed in some samples; these are noted in Table 8 under
remarks. Upon receipt the submitted samples were entered in the Master Log
Book and assigned GCA Control Numbers as listed in Table 8. Chain of custody
procedures were adhered to and the samples were transferred to the locked
Sample Bank for refrigerated storage until the time of analysis. Sample
custody records were maintained throughout all laboratory procedures.
Duplicate samples were submitted to Radian Corporation of Austin, Texas under
chain of custody for volatile organic analysis (VGA).
Quality Control
Quality control protocol for the determination of volatile organics
included the use of surrogate spikes, and matrix spikes. Each sample was
spiked with a surrogate mixture containing d4~l,2-dichloroethane, dg-toluene,
and 4-bromofluorobenzene; these recoveries are presented in Table 9.
1-12
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TABLE 2. LIQUID SAMPLE ANALYSIS FROM THE SLUDGE LA5QQM AT
AMOCO CHEMICAL CORPORATION IN HOGB RIVER, ILLINOIS.
a,b
Major Caapcunds Concentration (ag/1)
Cnlorofors 0.03
TOTAL HALOBENATED HC • 0.03
TOTAL UNIDENTIFIED HC 11
TOTAL HOM-KETKAHE HC - 11
l
Analysis of saaple 41754 by 6CA Corporation/Technology Division using 6C/HS.
b
•g/I = ppa asstiiing a density of 1.
1-13
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TABLE 3. LI3UID SAMPLE ANALYSIS FROH THE SLUDcE LAGOON/OIL LAYER
AT AttOCO CHEMICAL CORPORATION IN iiOGD RIVER, ILLINOIS.
a,b
Major Coapounds Concentration (tg/l)
Methyl ens chlorids 27
TOTAL HALOGE.NATED HC 27
TOTAL 'JNISaTIFIES HC 266
TOTAL NON-BETHANE HC 294
a
Analysis of satple 41757 by GCA Corporation/Technology Division using SC/HS.
b
•g/I = pps assuiing a density of 1.
1-14
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TABLE 4. LIQUID SAMPLE ANALYSIS FROrt THE SLUD6E LABDDN KATES AT
A.10CO CHEJIICAL CORPORATION IN JiQQO RIVER, ILLINOIS.
Hijor Compounds Concentration (ag/li
Acetone 0.2
Methyl ene chloride 0.2
TOTAL HALCGEHATE3 HC 0.2
TOTAL OHBEJiATE!) HC 0.2
TOTAL UNIDENTIFIED HC 3.0
TOTAL WHHCTHANE HC 3.4
a
Analysis of sasple 41761 by BCA Corporation/Technology Division using SC/HS.
b
•q/1 - ppi assuiing a density of I.
1-15
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TABLE 5. LIQUID SASPLE ANALYSIS FROM THE SPRAY POND AT
AHQCQ CHEMICAL CORPORATION IN WJQD RIVES, ILLINOIS.
Major Compounds
Concentration lag/li
Analysis i
Analysis 2
1-Propanoi
2,3-Diiethylbutane
2,4-Disetnylpentane
3-ltetnylpentane
Acetone
8-?insR9
Benzene
Chlcrctors
Cydohexane
Insan
Iscsiitane
Isehexane
hsthylcyclonexane
Rethylene chloride
H-3utane
M-Octsne
Nechexane
TOTAL PARAFFINS
TOTAL OLEFINS
TOTAL ARGJ1ATIC HC
TOTAL HALOSENATED HC
TOTAL OXYSESATEJ" HC
0.004
0.01
0.02
O.S03
0.2
0.03
0.7 1.8
0.06 O.Oi
0.31
0.003
0.01
C.01
o.Oi
O.M 0.1
0.02
0.003
0.002
1.1
0.03
0.7 1.8
0.06 0.1
0.004
TOTAL SGN-aETHAKE HC
0.7
3.0
b
d
Analysis si saspls 4!7i6 by 6CA Corporation/Techncloay Division using SC/HS.
Analysis ai saaple 41764 by Radian Corporation using SC/HD.
sg/1 = ppa assuaing a density or 1.
Csncsntratisn of Qxygsnated HC not used in Total NHHi. caic-jlaticr..
1-16
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TABLE fa. LIQUID SAMPLE ANALYSIS FSQii THE SPRAY PQNQ AT
AMOCO CKH1ICAL CORPORATION IN UOOD RIVES, ILLINOIS.
Hajor Coapoiinds
Acetone
Methylsne chloride
N-Hexane
T-2-Hixsne
TOTAL PARAFFINS
TOTAL OLEFINS
TOTAL HALQ6ENATED HC
TOTAL OXYGENATED HC
TOTAL UNIDENTIFIED HC
TOTAL NON-METHANE HC
Concentration (
i
Analysis 1
0.4
0.6
0.6
0.4
1.2
2.2
c
»g/l)
b
Analysis 2
0.05
0.01
0.1
0.05
0.1
0.05
0.3
Analysis of saspie 41769 by 6CA Corporation/Technology Division using 6C/H5.
Analysis at saepls 41767 by Radian Corporation using SC/'HD.
•g/1 = ppa assuEing a density of 1.
1-17
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TABLE 7. SOLID SAHPLE ANALYSIS FROrt THE SLUDGE LAGOON AT
AHQCC CKBtlCAL CORPORATION IH WOOD RIVER, ILLINOIS.
Hajor Coipounds
N-Undecane
M-Hexane
N-Ncnane
M-Decane
B-Pinene
Liaonene
N-3utylbenzene
P-Disthylbenzene
Isoiieptane
(Hieptane
S-Hethyihssiane
N-Octane
H-Propylfaenzene
H-Ethyltolusne
Isofaittyibenzene
Indan
Indene
Chiorosethane
Methylene cnlcride
Benzaldehyde
TOTAL PARAFFISS
TOTAL K^INS
TOTAL AROMATIC HC
TOTAL HALOEENATEil HC
TOTAL OXYGENATED HC
TOTAL IWIDEHTIFIED HC
TOTAL NQN-KETHAHE HC
c
Concentration (ug/g)
a b
Analysis 1 Analysis 2
100
13
20
45
14
21
32
13
S
5
7
• b
9
6
5
7
7
5
11 &
9
670
140
150
11 14
10
3
d
11 990
b
Analysis of saiole 41314 headspace by 3CA Corporation/Technology Division using 6C/.1S.
Analysis of sassle 41315 soil by Radian Corporation using a 6C/HD.
ug/g = ppi assusing a density oi 1.
Concentration of Oxygenated HC not used in Total KHHC calculation.
1-18
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TABLE 8. CROSS REFERENCED LIST OF SUBMITTED SAMPLES
COLLECTED AT AMOCO IN WOOD RIVER, ILLINOIS
Sample
Identification
ACC-OM-1A
ACC-OM-1B
ACC-OM-1C
ACC-OM-1D
ACC-OMS-1A
ACC-OMS-1B
ACC-OMS-1C
ACC-OMS-1D
ACC-SL-1A
ACC-SL-1B
ACC-SL-1C
ACC-SL-1D
ACC-SP-1A
ACC-SP-1B
ACC-SP-1C
ACC-SP-1D
GCA
Control No. Remarks
41751*
41752*
41753
41754
41755* SAB
41756 SAB
41757
41758* SAB
41759
41760*
41761
41762*
41763
41764*
41765*
41766
(continued)
1-19
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TABLE 8 (continued)
Sample GCA
Identification Control No. Remarks
ACC-SP-2A 41767*
ACC-SP-2B 41768
AGG-SP-2C 41769
ACC-SP-2D 41770*
ACC-SL-C1 41814
ACC-SL-C2 41815*
SAB = Small air bubble
* Submitted to Radian Corporation, Austin, Texas.
1-20
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TABLE 9. QUALITY CONTROL DATA FOR ANALYSIS CONDUCTED ON THE
SAMPLES COLLECTED AT AMOCO IN WOOD RIVER, ILLINOIS:
SURROGATE RECOVERIES - VOLATILE ORGANICS
Sample GCA
Identification Control No.
ACC-OM-1D
ACC-OMS-1D
ACC-SL-1C
ACC-SP-1D
ACC-SP-2C
Method Blank
Method Blank
Method Blank
Method Blank
41754
41757 MS
41757 MSD
41757
41761 MS
41761 MSD
41766
41769
01/09/85
01/10/85
01/11/85
01/15/85
Average Percent Recovery
Relative Standard
Deviation(%)
D8-
Toluene
93
88
105
87
98
94
90
97
88
87
83
83
91
6.6
Bromo f luorobenzene
125
74
82
80
82
74
90
71
114
62
90
80
85
18
D4-1.2-
D ich lor oe thane
86
94
108
87
62
95
102
94
91
105
59
124
92
18
1-21
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Duplicate aliquots of Samples ACC-OMS-1C (GCA 41757) and ACC-SL-1C (GCA 41761)
were spiked with a volatile organic mixture; results are shown in Tables 10
and 11.
At this time there are no appropriate quality control procedures
available for this type of soil core analysis.
1-22
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TABLE 10. QUALITY CONTROL DATA: DUPLICATE ALIQUOTS OF SAMPLE
ACC-OMS-1C (GCA 41757) SPIKED WITH VOLATILE ORGANICS,
AMOCO, WOOD RIVER, ILLINOIS.
Parameter
Concentration (ug)
Expected Aliquot A Aliquot B
Percent Average
Recovery Percent
Difference Recovery
1,1-Dichloroethene
Chlorobenzene
Toluene
Benzene
50
50
50
50
60
43
48
30
66
39
42
50
10
10
13
50
126
82
90
80
1-23
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TABLE 11. QUALITY CONTROL DATA MATRIX SPIKE RECOVERIES FOR
SAMPLE ACC-SL-1C (GCA #41761), AMOCO,
WOOD RIVER, ILLINOIS.
Parameter
Reported
Expected Concentration (ug)
(ug) Spike A Spike B
Relative Average
Percent Percent
Difference Recovery
1,1-Dichloroethene 50
Trichloroethene 50
Chlorobenzene 50
Toluene 50
Benzene 50
70
54
55
56
30
60
42
46
46
28
15
25
18
20
7
130
96
101
102
58
1-24
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Section 2.
Reilly Tar and Chemical Corporation
Granite City, IL
2-1
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TABLE OF CONTENTS
Section Page
I. Introduction 2-5
II. Wastestream Characterization Information 2-6
III. Facility Process Descriptions 2-6
Lagoon Cleanup Operations 2-6
Process Wastewater Treatment 2-9
IV. Sampling Information 2-9
Sample Location Description. 2-9
Quality Assurance 2-10
V. Sample Analysis 2-10
Analytical Summary 2-10
Quality Assurance 2-14
2-2
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LIST OF TABLES
Table Page
1 Description of the Impoundments at Reilly Tar and Chemical,
Granite City, XL 2-7
2 Liquid Sample Analysis from the Leaching Field at Reilly
Tar and Chemical in Granite City, IL 2-11
3 Liquid Sample Analysis from the Lagoon/Aerated Area at Reilly
Tar and Chemical in Granite City, IL 2-12
4 Liquid Sample Analysis from the Lagoon/Calm Area at Reilly
Tar and Chemical in Granite City, IL 2-13
5 Cross Referenced List of Submitted Samples Collected At
Reilly Tar and Chemical, Granite City, IL 2-15
6 Quality Control Data for Analyses Conducted on the Samples
Collected at Reilly Tar and Chemical, Granite City, IL.
Surrogate Recoveries - Volatile Organics 2-16
2-3
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LIST OF FIGURES
Figure Page
1 Facility layout for Reilly Tar and Chemical Corporation,
Granite City, IL 2-8
2-4
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Site: Reilly Tar and Chemical Corporation
Edwardville and 19th Sts.
Granite City, IL 62040
Mail Address: P.O. Box 370
FCID: ILD006278360
Site Contacts: William Justin, Director of Environmental Control
(317) 638-7531
Larry Purtle, Plant Manager
(618) 452-3141
William Roder, Research Chemist
(317) 247-8141
Field Trip Personnel: Andrew Baldwin, GCA/Engineering
James Thomas, GCA/Measurements
Richard Roat, GCA/Measurements
Chuck Vaught, GCA/Engineering
Larry Purtle, Reilly Tar
William Justin, Reilly Tar
William Roder, Reilly Tar
Visit Time and Date: 9:00 a.m., 11/16/84
I. INTRODUCTION
Reilly Tar and Chemical Corporation is headquartered in Indianapolis,
Indiana; the subject of this trip report is the Granite City, Illinois,
facility, which is a tar refinery. Reilly Tar buys coal tar from the steel
coking industry. Creosote oil, one of Reilly Tar's final products, is a
byproduct of coal tar distillation. The remaining residue is tar pitch that
is sold to the aluminum industry for anode binders, as well as to other
industries as roofing tar and roofing pitch. There are about 40 fixed roof
product storage tanks on site, but no drum storage.
Reilly Tar is in the process of cleaning up an old settling lagoon, as
mandated by new state regulations. This operation should be completed within
2 years. Reilly Tar also operates an above ground biotreatment system for
process wastewater. All treated wastewater is routed to a discharge field,
where it either evaporates or infiltrates.
Climatological conditions at the time of visit were sunny and clear
skies, an ambient air temperature of 34°F, and westerly winds at 10 to
15 mph. No odors were noticeable.
2-5
-------
II. WASTESTREAM CHARACTERIZATION INFORMATION
Waste handled by Reilly Tar and Chemical is the "wet cut" from coal tar
distillation. This is, for the most part, phenolic waste at a concentration
of about 1000 ppm« Other materials in the wastestream are polyaromatic
hydrocarbons such as naphthalene, pyrene, and phenanthrene, as well as trace
amounts of benzenes, toluenes, and xylenes. A more detailed wastestream
characterization was not available from the facility. The facility's Part A
Profile is attached (Appendix E); also in this Appendix is a copy of the most
recent update to their Part A Permit Application.
III. FACILITY PROCESS DESCRIPTIONS
Information necessary for estimating air emission release rates of
volatile organics from the lagoon and discharge field are summarized in
Table 1.. Process operations and locations are shown in Figure 1.
Because the only material entering the lagoon is storm water runoff, no
retention time or throughput was given. According to company officials, the
lagoon probably will be cleaned out within 2 years. The discharge field will
probably be inactive by 19S5.
Lagoon, Cleanup^Operations
As mentioned earlier, Reilly Tar is in the process of cleaning up an old
settling lagoon. The first part of the operation (currently in progress) is
in-situ biodegradation of hazardous materials present in the sludge at the
bottom of the lagoon; this is expected to decrease sludge removal costs
later. The system was set up by Polybac Corporation, and was designed to
destroy naphthalene, phenanthrene, pyrene, and other two-, three-, and
four-ring hydrocarbons found in the sludge. According to Reilly Tar
engineers, the process appears to be working. Occasionally, when the lagoon
becomes too full due to accumulation of storm water runoff, water is pumped
from the lagoon to one of the biotreatment tanks, where it is treated and
released to the discharge field.
2-6
-------
TABLE 1. DESCRIPTION OF THE IMPOUNDMENTS AT REILLY TAR AND CHEMICAL,
GRANITE CITY, ILLINOIS.
Aerate
-------
NJ
oo
-It—K K M K H H K K H » H * H * * * * * * K » M—-* * H M K K 1
1
1
I
EQUALIZATION '
»• * U I* I L - ji^-*^ •vnr*ir*tr'Ltv \ ^^ \ '
COOLING TOWER OVERFLOW
S10RM WAFER
STOKAGE
PROCESS
WASTEWATER
PROCESS
UNITS OFFICES
ABOVE-GROUND
TREATMENT
I 1 TANKS
-*—X—It-
KEY
OCCASIONAL PUMPING
AERATOR LOCATION
FENCE
SAMPLING LOCATION
DISCHARGE FIELD ,
Figure 1. Facility layout for Reilly Tar and Chemical Corporation,
Granite City, Illinois.
-------
Process Wastewater_Treatment
Most BTXs (benzenes, toluenes, and xylenes) present in the coal tar are
stripped out at the steel coking facility before the tar reaches Reilly.
Wastewater from processes at Reilly Tar is, thus, mostly the "wet cut" from
coal tar distillation (coal tar is 2 to 10 percent water when it arrives).
Wastewater contains approximately 1000 ppm phenolic waste, as well as some
polyaromatic hydrocarbons, and trace BTXs.
The wastestream is routed through a storage tank, and then to an
equalization tank. En route, the wastestream may be diluted with storm water
and cooling tower overflow stored in a nearby tank. After equalization, most
organics present in the wastewater are biodegraded in 250,000 gallon above
ground biotreatment tanks. The treated wastewater is then released to a
discharge field at a rate of about 20,000 gallons per day. Reilly Tar
personnel stated that a sewer hookup to the Granite City sewer system will be
installed before the end of the year to accept the treated wastewater.
IV. SAMPLING INFORMATION
Sample Location Description
Samples were taken at two locations (Figure 1):
o the aerated lagoon, and
o the discharge field.
Two quadruplicate liquid samples were taken from the aerated lagoon. The
first set of samples (RTC-L-1) was taken near one of the aerators; the surface
of the lagoon was foamed due to aerator action. The second set of liquid
samples (RTC-L-2) was taken in a calmer section of the lagoon, near the lagoon
discharge. All samples were at 10°C when taken.
A final quadruplicate liquid sample (RTC-F-1) was taken from the
discharge field. Only the area directly next to the influent line was
sufficiently deep to obtain a liquid sample. No soil core samples were
obtained. No liquid samples were requested by Reilly Tar and Chemical.
2-9
-------
Quality Assurance
Sampling procedures were employed as described in the Quality Assurance
Project Plan dated 30 October 1984. Liquid samples were collected in
quadruplicate. The quadruplicate liquid samples were returned to the GCA
Analytical Laboratory in Bedford, MA, where they were received into the sample
bank. The facility did not request splits, so none were taken.
Sample custody and handling procedures included the use of sample tags,
chain-of-custody sheets, refrigeration of samples between sampling and
analysis, and shipping of samples in coolers sealed with custody seals. In
addition, each sample was assigned a unique sample code which linked it to the
facility, the source, and the sample point.
Some of the sample matrices and locations made it difficult if not
impossible to collect the liquid samples without air bubbles forming in the 40
ml VOA vial. In every case repeated attempts were made to obtain the highest
quality samples.
V. SAMPLE ANALYSIS
Analytical Summary
Tables 2 through 4 provide the analytical summary reports for all of the
process samples collected during the site visit (see Appendix A). These
tables present the major compounds quantified by either GC/MS (GCA Corporation
/Technology Division) or a multiple detector system (Radian Corporation). The
actual data report sheets for each respective sample are provided in
Appendix B and Appendix C.
Appendix D outlines the analytical procedures employed. Only aqueous
samples were obtained at Reilly Tar.
2-10
-------
TABLE 2. LIQUID SAMPLE ANALYSIS FROM THE LEACHIN3 FIELD AT
REILLY TAR AND CHEHICAL IN GRANITE CITY, ILLINOIS
c
Concentration (as/I!
a b
Ssjar CsiBcanas Analysis 1 Analysis 2
Acetone 0.2
Careen tetrsehisride 0.03
fisthylens chiorise 0.2 0.05
TQTfil fcHLOSENATi:- HC 0.07
TOTAL UNIDENTIFIED HC 6.0
TOTAL MON-ftETHASE HC 6.0 0.07
Anaiysii at 5£.uBi3 -1772 iy 5CA Carcoratian/TgcnnaiDsy Division isino SC/fls.
b
Analysis sf saapis 41773 ay Radian Corporation using SC/HB.
c
ag/'i = 3Bi assuaing a sarsity 3t 1.
2-11
-------
TABLE 3. LIQUID SAMPLE ANALYSIS PROS THE LABOGN/AERATtB AREA AT
REILLY TAfl AND CKEKICAL IN 5RANITE CITY, ILLINOIS
jasaaaaasaaasasaaaasgagaaaasasaagaaA-jjssaasasj-JMaTaassaaraasasaaasaa
c
Concentration (sa/1!
Hajar Caapcunss
1.2,4.-7ri3etf:yi!3enzsris
Acstsns
Cartsn tstracnicnae
Hetiwlene chiarida
N-'jRiecana
TOTAL PARAFFINS
TOTAL A50MTIC HC
TOTAL HALaSESATES HC
TGTAL OXYGENATED HC
TOTAL UNIDENTIFIED KC
T3TAL NON-NtTHANE HC
a
Analysis I
0.2
0.2
—--—------
0.2
0.2
2.0
2.0
b
Analysis 2
0.02
0.03
0.03
0.04
' oTbl
0.02
0.05
0.04
0.2
T -J - ;t:="i"=~~=r=r-;
a
Analysis of sasscls 41777 by ECA Ccrporatian/Technciagy Division using SC/flS.
b
Analysis or ssapla 41775 by Saflian Corporation using BC/JiO.
c
iq/i = ppa assuing a density of I.
2-12
-------
TABLE 4. LI3UID SAMPLE ANALYSIS FF.QH THE LAGQOK/CALH AREA AT
REILLY TAR AND CHEMICAL IN GRANITE CITY, ILLINOIS
fiajsr Ccapounds
2,5-Diaethyihsxar.e
2-.1atnyl-2-3uteRe
Acstane
Kethyiene chioriss
TOTAL PARAFFINS -
TOTAL OLEFIHS
TOTAL HALSGENATED HC
TOTAL QXYEEHATED HC
TOTAL NGN-HSThftNE HC
========== =====r======:=s:r
Concentrition
a
Analysis 1
0.03
0.02
««»«»____..
0.02
0.03
0.05
c
(ag/1)
b
Analysis 2
O.G02
0.02
0.1
o"7i -
•0,02
0.1
0.2
a
Analysis ar saapis 417B2 by 3CA Ccrsoraticn/Technology Division using SC/3S.
b
Analysis or saaple 41779 by Radian Corporation using 3C/HC.
c
ag/1 - psa assuiaing a dansity of 1.
2-13
-------
Quality Assurange
Chain of Custody
A set of samples was received by GCA/Technology Division on November 19,
1984, for volatile organic analysis (VOA). Routine inspection upon receipt
revealed the samples to be clearly labeled and appropriately chilled. Air
bubbles were observed in some samples; these are noted in Table 5 under
remarks. Upon receipt the submitted samples were entered in the Master Log
Book and assigned GCA Control Numbers as listed in Table 5. Chain of custody
procedures were followed and the samples were transferred to the locked Sample
Bank for refrigerated storage until the time of analysis. Sample custody
records were maintained throughout all laboratory procedures. Duplicate
samples were submitted to Radian Corporation of- Austin, Texas, under chain of
custody for volatile organic analysis (VOA).
Quality Control
Quality control protocol for the volatile organics analysis included the
use of surrogate spikes. Each sample was spiked with a surrogate mixture
containing dg-toluene, bromofluorobenzene and d^.-!,2-dichloroethane.
Surrogate recoveries are listed in Table 6.
2-14
-------
TABLE 5. CROSS REFERENCED LIST OF SUBMITTED SAMPLES COLLECTED AT
REILLY TAR AND CHEMICAL, GRANITE CITY, ILLINOIS.
Sample GCA
Ident i ficat ion Control Remarks
RTC-F-1A 41171 LAB
RTC-F-1B 41772 LAB
RTC-F-1C 41773* LAB
RTC-F-1D 41774* LAB
RTC-L-1A 41775* LAB
RTC-L-1B 41776 SAB
RTC-L-1C 41777 SAB
RTC-L-1D 41778* LAB
RTC-L-2A 41779*
RTC-L-2B 41780*
RTC-L-2C 41781
RTC-L-2D 41782
SAB = Small air bubble
LAB = Large air bubble
*Submitted to Radian Corporation, Austin Texas.
2-15
-------
TABLE 6. QUALITY CONTROL DATA FOR ANALYSES CONDUCTED ON THE SAMPLES COLLECTED
AT REILLY TAR AND CHEMICAL, GRANITE CITY, ILLINOIS. SURROGATE
RECOVERIES - VOLATILE ORGANICS
Sample
Identification
RTC-F-1B
RTC-L-1C
RTC-L-2D
Method Blank
Method Blank
Average Percent
GCA
Control No.
41772
41777
41782
01/09/85
01/10/85
Recovery
Relative Standard Deviation (%)
D8
Toluene
106
82
85
88
87
90
9
Bromo f luorobenzene
94
78
74
114
62
84
20
D4-l,2-
Dichloroe thane
99
72
99
91
105
93
13
2-16
-------
Section 3.
Shell Oil Company
Wood River, IL
3-1
-------
TABLE OF CONTENTS
Section Page
I. Introduction 3-5
II. Wastestream Characterization Information 3-5
III. Facility Process Description....... 3-7
IV. Sampling Information 3-7
Sample Location Description 3-7
Quality Assurance 3-10
V. Sample Analysis 3-11
Analytical Summary...... 3-11
Quality Assurance 3-11
3-2
-------
LIST OF TABLES
Table Page
1 Model Input Data for Air Emission Release Rate Determinations
at Shell Oil, Wood River, IL 3-9
2 Liquid Sample Analysis from the Biotreatment Pond #2 at Shell Oil
Company in Wood River, IL 3-12
3 Liquid Sample Analysis from the Surface Impoundment Influent at
Shell Oil Company in Wood River, IL 3-13
4 Liquid Sample Analysis from the Surface Impoundment at Shell
Oil Company in Wood River, IL 3-14
5 Liquid Sample Analysis from the Surface Impoundment/Oily Surface
at Shell Oil Company in Wood River, IL 3-15
6 Cross Referenced List of Submitted Samples Collected at Shell Oil,
Wood River, IL 3-16
7 Quality Control Date for Analyses Conducted on the Samples Collected
at Shell Oil in Wood River, IL: Surrogate Recoveries -
Volatile Organics 3-17
3-3
-------
LIST OF FIGURES
Figure Page
1 Facility layout for Shell Oil, Wood River, IL 3-6
2 Wastewater treatment process flow for Shell Oil,
Wood River, IL 3-8
3-4
-------
Facility: Shell Oil Company
Wood River Manufacturing Complex
P.O. Box 262
Wood River, Illinois 62095
FCID: ILD080012305
Site Contacts: Joseph N. Brewster, Process Engineer, Manager
Gina Pruitt, Process Engineer
(618) 254-7371
Field Trip Personnel: Andrew Baldwin, GCA/Engineering
James Thomas, GCA/Measurements
Richard Roat, GCA/Measurements
Charles Vaught, GCA/Engineering
Joseph Brewster, Shell
Gina Pruitt, Shell
Visit Time and Date: 1:00 p.m., November 15, 1984
I. INTRODUCTION
Shell Oil Company, located in Wood River, Illinois, is the largest oil
refinery in the state. Products manufactured by the company include
lubricants and asphalts, as well as gasoline and turbine fuel. Most crude
oils arrive by pipeline and are refined via distillation, cracking, and
separation processes. Shell Oil has been in operation since 1917, and employs
about 1750 workers. The general facility layout is shown in Figure 1.
Storage of refinery products is one of the primary operations at Shell.
Emissions have been estimated in the most recent State Implementation Plan
(SIP) at 20,000 kilograms per day of nonmethane volatile organics. This
estimate includes emissions from fugitive sources.
Climatic conditions the day of the visit were sunny skies, an ambient air
temperature of 45°F, and northwesterly winds of 25 to 30 mph.
II. WASTESTREAM CHARACTERIZATION INFORMATION
Process wastewater (5,000 gpm) is treated to remove waste oil sludges and
solids. The water softening process removes approximately 40,000 pounds per
day of calcium carbonate. Water softening is used to treat raw well water for
use in the refinery.
3-5
-------
V
Oi
MISSISSIPPI
RIVER
I
AMOCO
PETROLEUM
ADDITIVES
COMPANY
WEST PROPERTY
RESIDENTIAL
AREA
NORTH
PROPERTY
PRODUCT
TANK STORAGE
15 ACRE SOLID WASTE
DISPOSAL BASIN
Ml I I I I I I I I I I I I I I 'I I I
WASTEWATER
TREATMENT AREA
I I I I I +-J-
SEPARATOR
REFINERY OPERATIONS
MAIN PROPERTY
. PRODUCT
TANK STORAGE
SOUTHWEST
PROPERTY
RESIDENTIAL
AREA
SCALE: 1" - 2,000'
Figure 1. Facility layout for Shell Oil, Wood River, Illinois.
-------
Solids and semi-solid wastes are stored in a 15-acre solid waste disposal
basin. These wastes include dissolved air floatation (DAF) float, slop oil
emulsion solids, and API separator sludge. Waste quantities are provided in
the Part A Profile in Appendix E.
III. FACILITY PROCESS DESCRIPTIONS
The wastewater treatment system at Shell, shown in Figure 2, is typical
of those found at many refinery operations. First, oils and water are
separated via API separator. The liquid is then combined with sanitary sewage
wastewater and lime solids from process cooling water and boiler water
softening. Further removal of floats and solids is accomplished in the
dissolved air floatation unit. The liquid is then allowed to equalize in
pond 1, bio-treated in a trickling filter, and is bio-treated in pond 2.
Bio-solids are removed in DAF 2 and returned to pond 2. The fate of the final
effluent is the Mississippi River.
Waste solids and sludges from API and DAF separations are allowed to
settle in a 15-acre disposal basin. The major waste types in the basin are
listed in the Wastestream Characterization Information section. An oil slick,
covering about 10 percent of the surface area of the basin, is periodically
drawn off by vacuum trucks and recycled to the refinery. Solid calcium
carbonate deposits, extracted during water softening, occupy about 5 percent
of the water surface. The rest of the surface area is open water. Water
removed from the basin is routed back to the first API separator.
Specific information necessary for estimating air emission release rates
from the waste disposal basin and bio-treatment pond 2 are given in Table 1.
IV. SAMPLING INFORMATION
Sample Location ..Description
Two impoundments were sampled (Figure 2):
o biotreatment pond 2, and
o the solid waste basin
3-7
-------
LJ
00
REFINERY
PROCESS
UNITS
PROCESS
WASTEWATER
OIL LAYER
WITHDRAWN BY
VACUUM TRUCKS
POND NO,I
(EQUALIZATION)
OILY
WATER
API
SEPARATOR
IS - ACRE SOLID
WASTE DISPOSAL BASIN
DAF NO.)
TRICKLING
FILTER
SAMPLING LOCATION
FLOAT
AND
SOLIDS
API
SEPARATOR
API
SEPARATOR
API SOLIDS
SEWAGE
LIME
SOLIDS
WASTE BIO-SOLIDS
BIO-SOLIDS RECYCLE
POND NO.2
(BIOTREATMENT)
& AM
DAF NO.2
(CLARIFIER)
SANITARY
SEWER
COOLING AND
BOILER WATER
LIME SOFTENING
POLISHING
LAGOONS
f.OOOgpm
EFFLUENT TO
MISSISSIPPI RIVER
Figure 2. Wastewater treatment process flow for Shell Oil, Wood River, Illinois,
-------
TABLE 1. MODEL INPUT DATA FOR AIR EMISSION RELEASE RATE DETERMINATIONS
AT SHELL OIL, WOOD RIVER, ILLINOIS.
_Spli
-------
One set of quintuplicate liquid samples (SOC-AP-1) was taken from
bio-treatment pond 2, an aerated surface impoundment where wastewater is
biologically treated following equalization and filtering. No characteristic
odors were noticeable. Sample temperature was 28°C.
Three sets of quintuplicate liquid samples were taken from the solid
waste basin. One sample set (SOC-SI-1) was taken at the influent (35°C),
another (SOC-SI-2) from a calm section of the basin (14°C), and the final
sample set (SOC-SI-3) from an oily area (14°C). A strong odor was noticeable
in the vicinity of the basin. Splits were provided for Shell for all samples
taken.
Quality^Assurance
Sampling procedures were employed as described in the Quality Assurance
Project plan dated 30 October 1984. Liquid samples were collected in
quintuplicate, as a standard procedure, with one of the five samples retained
by the facility as a split. The remaining quadruplicate liquid samples were
returned to the GCA Analytical Laboratory in Bedford, MA, where they were
received into the sample bank.
Sample custody and handling procedures included the use of sample tags,
chain-of-custody sheets, refrigeration of samples between sampling and
analysis, and shipping of samples in coolers sealed with custody seals. In
addition, each sample was assigned a unique sample code which linked it to the
facility, the source, and the sample point.
Some of the sample matrices and locations made it difficult if not
impossible to collect the liquid samples without air bubbles forming in the
40 ml VOA vial. In every case repeated attempts were made to obtain the
highest quality samples.
3-10
-------
V. SAMPLE ANALYSIS
Analytical, Summary
Tables 2 through 5 provide the analytical summary reports for all of the
process samples collected during the site visit (see Appendix A). These
tables present the major compounds quantified by either GC/MS (GCA
Corporation/Technology Division) or a multiple detection system (Radian
Corporation). The actual data report sheets for each respective sample are
provided in Appendix B and Appendix C.
Aqueous and oil samples obtained at Shell were analyzed as indicated in
Appendix D.
Quality.. Assurance
Chain of Custody
A set of samples was received by GCA/Technology Division on November 19,
1984, for volatile organic analysis (VGA). Routine inspection upon receipt
revealed the samples to be clearly labeled and appropriately chilled. Air
bubbles were observed in some samples; these are noted in Table 6 under
remarks. Upon receipt the submitted samples were entered in the Master Log
Book and assigned GCA Control Numbers as listed in Table 6. Chain of custody
procedures were followed and the samples were transferred to the locked Sample
Bank for refrigerated storage until the time of analysis. Sample custody
records were maintained throughout all laboratory procedures. Duplicate
samples were submitted to Radian Corporation of Austin, Texas, under chain of
custody for volatile organic analysis (VGA).
Quality Control
Quality control protocol for volatile organics determination included the
use of surrogate spikes. Each sample was spiked wih a surrogate mixture
containing dg-toluene, d^-l-Z-dichloroethane, and bromofluorobenzene; these
results are shown in Table 7.
3-11
-------
TABLE 2. LIQUID SAMPLE ANALYSIS FROrt THE BIOTREATHEST PGHO 12
AT SHELL OIL COnPANY IN HOOD RIVER, ILLINOIS
Kajor Cccpcunds
1,2-Dichloropropane
2,2,5-Trisethylhexane
2,4,4-Trise-2-pentene
2,5-Bisethylhexane
Acetcne
B-Pinene
Butanone
Butyr aldehyde
Isoautvlbanzsne
Isebutyraliishyce
iscoentine
itethylsne chloride
N-Hexane
8-Pantane
N-l'ndecane
Toluene
TOTAL PARAFFINS
TOTAL OLEFlfiS
TOTAL ARDJ1ATIC HC
TOTAL HALQ6ENATED HC
TOTAL OXYGENATED HC
TOTAL UHIDENTIFIH HC
TOTAL NON-ffiTHAKE HC
c
Concentration lig/1)
a b
Analysis 1 Analysis 2
0.01
0.03
0.02
0.03
0.4 1.3
0.02
0.1
0.1
0.1
0.02
1.6
0.4 C.J
0.4-
0.1
0.01
0.5
2.6
0.05
0.6
0.3
1.5 •
2.6
d
2.6 3.5
.,.,_.. ..— — — -_.-_..,._--,--.-.———————
0
Analysis oi saaple 41786 by SCA Corporation/Technology Division using SC/ilS.
Analysis of saiple 41734 by Radian Corporation using BC/ND.
iq/i = pps assuiin; a density of 1
Concsntration of Qxyqenatad HC not used in Total NHHC calculation.
3-12
-------
TABLE 3. LIQUID SAMPLE ANALYSIS FROH THE SURFACE IMPOUNDMENT
INFLUENT AT SHELL OIL COMPANY IN HOOD RIVER, ILLINOIS
Concentration iog/U
Major Coapcunds
1.1,1-Trichloroetriane
2,2,5-Triaethylhexane
2,4-Diaethylpentane
S-Hethylpentane
Acetone
Benzene
Cyclohexane
Ethane
Ethylbenzene
Isebutyraldehyde
Ischeptane
Iscpentane
Hethylcyclohexane
Methyl cyclopentane
Ksthyiene chloride
N-Decane
N-Hexane
Nechexane
Toluene
Total Xylenes
TOTAL PARAFFINS
TOTAL AROMATIC HC
TOTAL HALOEENATE3 HC
TOTAL OXYGENATED HC
TOTAL UNIDENTIFIED HC
TOTAL NQN-KETHANE HC
Analysis t
fa
Analysis 2
1.6
2.5
0.9
6.3
2.4
11
0.9
1.6
29
42
0.1
0.1
0.1
0.3
5.5
1.7
0.1
0.06
0.2
0.6
0.1
2.5
0.1
1.5
0.5
0.1
1.5
0.2
2.1
0.9
12
5
I
6
d
19
b
d
Analysis of sa,iple 41789 by 6CA Corporation/Technology Division using GC/MS.
Analysis of sasple 417B9 by Raaian Corporation using GC/MO.
sg/1 = pp» assuming a density of 1.
Ccncentraticn of Oxygenated HC not used in Total NtthC calculation.
3-13
-------
TABLE 4. LIQUID SA8PLE ANALYSIS FRQH THE SURFACE 1SPOUKDBEN7
AT SHELL OIL COMPANY IN WOOD RIVER. ILLINOIS
c
Concentration lag/1)
a
Major Cojpounds Analysis I
1-Butanol
1-Decene
1-Prapanol
1-Undecene
2,2,4-Triaethylpsntane
2,2,5-Triiethylhexane
2,3,5-Triiethylpentane
2,3-Oiiethylpentane
2,4-Oiiethylqentane
2,5-Diaethylhexane
3-Hethyl heptane
3-flethylpentane
Acetone . l.S
Benzene 4.3
Cyclohexane
Cyclepentsne
DifcroBocnierosetbane
Isoheptane
Bethyl cyclohexane
Wethylene chloride 0.9
H-Decane
N-Sonane
N-Octane
N-Undecane
T-4-Bethyl -2-pentene
Toluene l.S
Total lylenss 1.0
TOTAL PARAFFIHS
TOTAL QLEFINS
TOTAL ARQHATIC HC
TOTAL HALGSENATEiJ HC 6.8
TOTAL OXYGENATED HC
TOTAL UNIDENTIFIED HC 40
TOTAL !WN-«ETHANE HC 67
Analysis 2a
0.4
0.5
0.2
0.1
O.S
0.1
0.1
0.9
0.3
10
0.2
0.3
0.6
O.OS
0.1
0.3
0.1
0.1
0.6
34
0.7
1.4
O.S
0.4
d
58
b
1 2b
1.2
7.2
0.6
0.1
0.05
0.03
0.1
0.1
0.1
0.2
0.3
11
0.2
0.2
0.1
0.9
0.4
0.8
30
1.0
1.1
0.6
8.4
d
47
Analysis of sawie 41794 by SCA Corporation/Technology Division using 6C/3S.
Analysis cf sa*ole 41792 !2 analyses) by Radian Corporation using 5C/hD.
sg/1 = ppa assuiinq a density of 1.
Concentration ot Oxygenated HC not used in Total fWHC calculation.
3-14
-------
TABLE 5. LIQUID SAMPLE ANALYSIS FRQH THE SURFACE INPOUSDhENT/OILlf
SURFACE AREA AT SHELL OIL COMPANY IN HQOQ RIVER, ILLINOIS
a,b
Major Cospounds Concentration leg/U
. 7
Ethylbenzene IB
Hethylene chloride 16
Toluene 47
Total xylenes 77
TOTAL AROMATIC HC 150
TOTAL HALDBENATED HC 16
TOTAL ^IDENTIFIED HC 3fcOO
TOTAL NON-METHANE HC 3700
a
Analysis of saaole 41796 by SCA Corporation/Technology Division using SC/MS.
b
•g/1 - ppi assusing a density of I.
3-15
-------
TABLE 6. CROSS REFERENCED LIST OF SUBMITTED SAMPLES COLLECTED
AT SHELL OIL, WOOD RIVER, ILLINOIS.
Sample
Identification
SOC-AP-1A
SOC-AP-1B
SOC-AP-1C
SOC-AP-1D
SOOSI-1A
SOC-SI-1B
SOC-SI-1C
SOC-SI-1D
SOC-SI-2A
SOC-SI-2B
SOC-SI-2C
SOC-SI-2D
SOC-SI-3A
SOC-SI-3C
SOC-SI-3C
SOC-SI-3D
GCA
Control
41783
41784*
41785*
41786
41787
41788
41789*
41790*
41791
41792*
41793*
41794
41795
41796
41797*
41798*
Remarks
SAB
LAB
LAB
SAB
SAB
LAB
LAB
LAB
SAB
SAB
SAB
SAB
SAB -Small air bubble
LAB = Large air bubble
*Submitted to Radian Corporation, Austin, Texas.
3-16
-------
TABLE 7. QUALITY CONTROL DATA FOR ANALYSES CONDUCTED ON THE
SAMPLES COLLECTED AT SHELL OIL IN WOOD RIVER, ILLINOIS:
SURROGATE RECOVERIES - VOLATILE ORGANICS
Sample
Identification
GCA D8-
Control No. Toluene
Bromofluorobenzene
D4-l,2-
Dichloroethane
SOC-AP-1D 41786
SOC-SI-1B 41788
SOC-SI-2D 41794
SOC-SI-3B 41796
Method Blank 01/09/85
Method Blank 01/10/85
Method Blank 01/15/85
Laboratory Control Sample
93
96
95
104
88
87
83
79
81
117
117
133
114
62
80
77
81
89
96
123
91
105
124
106
Average Percent Recovery 90
Relative Standard Deviation (7.) 8
98
26
102
16
3-17
-------
Section 4.
Texaco, Incorporated
Salem, IL
4-1
-------
TABLE OF CONTENTS
Section Page
I. Introduction 4-5
II. Was test ream Characterization Data 4-6
III. Facility Process Descriptions 4-6
IV. Sampling Information... 4-8
Sample Location Description 4-8
Quality Assurance. 4-8
V. Sample Analysis 4-11
Analytical Summary. 4-11
Quality Assurance 4-14
4-2
-------
LIST OF TABLES
Table Page
1 Model Input Data for Air Emission Release Rate Determinations,
Texaco, Salem, IL 4-9
2 Liquid Sample Analysis form the Bubble Pit at Texaco Inc. in
Salem, IL 4-12
3 Liquid Sample Analysis from the Settling Basin at Texaco Inc.
in Salem, IL 4-13
4 Cross References List of Submitted Samples Collected at Texaco
in Salem, IL 4-15
5 Quality Control Data for Analyses Conducted on the Samples
Collected at Texaco in Salem, IL. Surrogate Recoveries -
Volatile Organics 4-17
4-3
-------
LIST OF FIGURES
Figures Page
1 Flow plan water flooding extraction operation at Texaco,
Salem, IL 4-7
2 Sampling points at Texaco, Salem, IL 4-10
4-4
-------
Site: Texaco, Inc.
Route 2
Salem, Illinois 62881
Site Contact: Gailon Gibb, Assistant Superintendent
Chris Culver, Engineer
(618) 548-1803
Field Trip Personnel: Andrew Baldwin, GCA/Engineering
James Thomas, CCA/Measurements
Richard Roat, CCA/Measurements
Chuck Vaught, GCA/Engineering
Gailon Gibb, Texaco
Chris Culver, Texaco
John Hamby, Texaco
Visit Time and Date: 10:00 a.m., 11/14/84
I. INTRODUCTION
The Texaco facility in Salem, Illinois, is an oil production field.
Secondary oil extraction processes are currently in operation. These involve
"flooding" the oil field with water via injection wells, withdrawing the
oil/water mixture, and separating the oil from the water. Currently,
approximately 244,000 barrels (bbl) of oil/water mixture are withdrawn from
360 wells each day, of which 4,000 bbl are oil.
A problem unique to this field is the formation of barium sulfate due to
the presence of barium and sulfate in two of the geologic formations which are
flooded. When water from these two formations is mixed, barium sulfate is
generated, forming a thick, rock-like layer on pipes and in lagoons. For this
reason, a large settling pond was constructed to allow settling of barium
sulfate.
A wastewater treatment plant removes solids and minerals prior to
reinjection to prevent clogging of the formations. Two hundred forty-five
water injection wells are currently in operation.
The size of the field is approximately 8,800 acres, about 2.5 miles wide
and 6.5 miles long. Residences are interspersed throughout the field.
Climatological conditions on the day of the visit were hazy skies, air
temperature about 45°F, and southerly winds about 10 mph.
4-5
-------
II. WASTESTREAM CHARACTERIZATION DATA
No listed hazardous waste is generated by this facility. No effluent is
produced because all treated process water is reinjected into the oil field
wells. Waste that is removed in the settling pond includes excess crude oil
and barium sulfate. Approximately 10.08 million gallons of waste are handled
each day in this system. No specific waste characterization was available.
III. FACILITY PROCESS DESCRIPTIONS
The basic process flow is shown in Figure 1. The oil/water mixture is
withdrawn from 360 wells throughout the field. From there it is pumped to one
of two oil/water separation systems designated as the north and south
batteries. Each battery has six 400-bbl free water knockout (FWKO) tanks, two
400-bbl "gun barrels," and two 400-bbl stock tanks.
In the FWKO tanks, oil and water are separated by gravity, after which the
oil layer is drawn off. This oil is pumped to the gun barrels, where
additional oil/water separation takes place. The oil then goes to the two
stock (storage) tanks, which are connected to a "sales line" that eventually
reaches a refinery.
Prior to installation of the two 400-bbl stock tanks, a single 3,000-bbl
tank was used. Because this tank had a longer residence time, tank botttom
solids had to be removed periodically and disposed in a nearby earthen pit.
Illinois State regulations recently required the closing and filling of such
pits, hence Texaco switched to smaller stock tanks. The pit was still open at
the time of visit to allow material in it to dry, but company officials noted
that it has been inactive for at least a year.
The water from the FWKO tanks is pumped to a bubbling chamber, to drive
off hydrogen sulfide gas. From there the water is pumped to the barium
sulfate/oil skim pond, allowing for the removal of oil (not a substantial
quantity) as well as the settling of barium sulfate. Following the skim pond,
water is pumped to a cement lined pond where fresh groundwater is added to
supplement evaporative losses. The water is then flocculated and filtered as
4-6
-------
PRODUCING
WELLS
(CURRENTLY
360 IN
OPERATION)
WATER
•vl
(CURRENTLY
2^0.000 bbl/day)
OIL
(CURRENTLY
*lOOO bbl/day)
BARIUM SULFATE/
OIL SKIM POND
GUN BARREL
TANKS
FRESHWATER
(FROM RANNEY
COLLECTOR)
CEMENT POND
(STORAGE AND
FRESHWATER
MIX-IN)
STOCK TANKS
SALES LINE
DISTRIBUTION
HIGH PRESSURE
INJECTION WELL
SYSTEM
(245 WELLS)
WASTEWATER
TREATMENT
(FLOCCULATION AND
FILTRATION)
Figure 1.
Flow plan—water flooding extraction
operation at Texaco, Salem, Illinois.
SLUDGE TO
LANDFILL
-------
a final treatment step to remove iron, barium sulfate, and other inorganic
solids. Filtered backwash is pumped back to the barium sulfate settling
pond. Final effluent is then injected back into the same formations from
which it came, closing the cycle.
Operating parameters for the bubbling pit and for the settling pond are
provided in Table 1. The bubbling pit is actually a tank, while the settling
pond in an impoundment.
IV. SAMPLING INFORMATION
Sample Location Description
The bubbling pit is the first process step where volatiles are exposed to
the atmosphere. One quadruplicate liquid sample (TI-BP-1) was obtained near
the effluent discharge of the bubbling pit (Figure 2). Due to the highly
aerated condition of the pit, samples contained some air bubbles. Sample
temperature was 32°C.
Another quadruplicate liquid sample (TI-SB-1) was taken from the settling
pond (Figure 2). Sampling was performed from the catwalk of the oil skimmer,
where the sample was taken from an oil slick on the pond surface. Sample
temperature was 28°C.
Qua 1 i ty_As surance
Sampling procedures were employed as directed in the Quality Assurance
Project Plan dated 30 October 1984. Liquid samples were collected in
quadruplicate. The facility did not request a split. The quadruplicate
liquid samples were returned to the GCA Analytical Laboratory in Bedford, MA
where they were received into the sample bank.
Sample custody and handling procedures included the use of sample tags,
chain-of-custody sheets, refrigeration of samples between sampling and
analysis, and shipping of samples in coolers sealed with custody seals. In
addition, each sample was assigned a unique sample code which linked it to the
facility, the source, and the sample point.
4-8
-------
TABLE 1. MODEL INPUT DATA FOR AIR EMISSION RELEASE RATE DETERMINATIONS,
TEXACO, SALEM, ILLINOIS.
Bubbling Pit
Type:
Aeration type:
Operation:
Typical throughput:
Typical retention time:3
Dimensions:
Operational surface area:
Operational depth:
Number of blowers:
Blower output:
Diffusion system:
Settling Pond
Type:
Operation:
Typical throughput:
Typical retention time:3
Dimensions:
Operational surface area:
Average operational depth:
Approximate area of oil slick:
Aerated tank
Diffused air
Continuous flow
10,080,000 gpd (240,000 bbl/day)
Approximately 15 minutes
20 ft by 40 ft by 20 ft deep
800 ft2
18.5 ft
3 (two operational at a time)
4,600 standard ft3/min (two blowers)
Piping from blowers (uniform diffusion)
Nonaerated impoundment
Continuous flow
10,080,000 gpd (240,000 bbl/day)
13 hrs
1,200 ft by 300 ft by 0-8 ft deep
360,000 ft2
2 ft
1,000 ft2
Based on reported throughput and tank dimensions.
4-9
-------
H
O
BUBBLE
PIT
LIME SOLUTION
SAND SOLUTION
®BP-1
V
R
o
A
D
p
SB-1®
ii
k^_
'
/
'
^
;
/
£
OIL
SKIMMER
/ CAT
' WALK
DISCHARGE
PIPES SETTLING BASIN {SKIM POND)
NOTE:NOT TO SCALE
® SAMPLE POINT
Figure 2. Sampling points at Texaco, Salem, Illinois.
-------
Some of the sample matrices and locations made it difficult if not
impossible to collect the liquid samples without air bubbles forming in the
40 ml VGA vial. In every case repeated attempts were made to obtain the
highest quality samples.
V. SAMPLE ANALYSIS
Analytical Summary
Tables 2 and 3 provide the analytical summary reports for all of the
process samples collected during the site visit (see Appendix A). These
tables present the major compounds quantified by either GO/MS (GCA
Corporation/Technology Division) or a multiple detection system (Radian
Corporation). The actual data report sheets for each respective sample are
provided in Appendix 8 and Appendix C.
Analytical procedures are outlined in Appendix D. Aqueous and oil samples
were obtained at Texaco.
4-11
-------
TABLE 2. LISUIG SASPLE A5SLYSI5 FfiW THE BUBBLE PIT AT
TE2ACD INCORPORATED 18 SALES, ILLINOIS
s= :===== — xsxsssssssesssssasssss=5=-~s=ss-—-assssss=sssss=~—
Concantraticn
a
Major Ceapsunds Analysis 1
1-Butanal
l-2scsne
i-Propansl
2.3-Disethylcap.tane
3-fcatnylhaxana
3-Kethylssntans
Acetone 0.4
Ssr.zans 1.0
Cycicaentane
UaJrosech! srasstnsne
Ethylbenzena
Ischestane
Ssrhylcyclchsxane
Satlivlane chlsrine 0.4
M-ricnane
JKJctana
M-Prcuyibsnisr.s
Prsayrse
Styrsre
T-*-SBinyl -2-psntins
Talasne 0.8
Total Ivlsnss 0.2
s-iylens/a-iyiens
TOTAL PflRAFFUIS
TOTAL OL-FL1S
TOTAL AROi-fiTIC HC 2.0
TOTAL HALSSSHATED HC
TGTSL OIYGSiATB HC
TOTAL IWI5ESTIFIE3 HC 2.9
T2TAL 3CS-STHANE HC 4.9
c
lsg/1)
b
Analysis 2
0.9
0.1
0.4
0.7
0.7
1.1
0.8
12.0
O.I
2.1
1.0
0.4
7.0
2.0
0.2
0.3
0.7
0.4
0.3
0.5
45
0.9
4.o
0.1
1.3
19.6
a
70
b
Analysis of isapie 41SCO by 3CA Carpcritian/Tacnnolagy Bivision using SC/BS.
Analysis sf ssaala 41201 by Sasian Corsoration using SC/ftO.
og/'l = pss aisuaing a deasity OT 1.
Csr-cMtraiisn ot Oxyganatac HC ns: usad ir. Total NhHC calculation.
4-12
-------
TABLE 3. LIQUID SAMPLE ANALYSIS FRGN THE SETTLINS BASIN
AT TEXACO INCORPORATED IN SALEM, ILLINOIS
a,b
Rajor Ccapounds Concentration (sg/1)
Benzene 6.
Ethylbenzene 25
Rethylene chloride 41
Toluene 19
Total xylsnes SB
TDTAL AROMATIC HC 110
TOTAL HAL06ENATED HC 41
TOTAL IMIOENTIFIEO HC 2600
TOTAL JESJ-HETKASE HC 2700
a
Analysis of saapls 41604 by SCA Corporation/Technolcqy Division using SC/KS.
b
eg/1 = ppa assuming a density of 1.
4-13
-------
Quality Assurance
Chain of Custody
A set of samples was received by GCA/Technology Division on November 19,
1984 for volatile organic analysis (VGA). Routine inspection upon receipt
revealed the samples to be clearly labeled and appropriately chilled. Air
bubbles were observed in some samples; these are noted in Table 4 under
remarks. Upon receipt the submitted samples were entered in the Master Log
Book and assigned GCA Control Numbers as listed in Table 4. Chain of custody
procedures were followed and the samples were transferred to the locked Sample
Bank for refrigerated storage until the time of analysis. Sample custody
records were maintained throughout all laboratory procedures. Duplicate
samples were submitted to Radian Corporation of Austin, Texas under chain of
custody for volatile organic analysis (VGA).
4-14
-------
TABLE 4. CROSS REFERENCED LIST OF SUBMITTED SAMPLES COLLECTED AT
TEXACO IN SALEM, ILLINOIS.
Sample
Identification
TI-BP-1A
TI-BP-AB
TI-BP-1C
TI-BP-1D
TI-SB-1A
TI-SB-1B
TI-SB-1C
TI-SB-1D
GCA
Control
41799
41800
41801*
41802*
41803*
41804
41805*
41806
Remarks
SAB
LAB
LAB
LAB
SAB
SAB
SAB
SAB
SAB = Small air bubble
LAB = Large air bubble
*Submitted to Radian Corporation, Austin, Texas.
4-15
-------
Quality Control
Quality control procedures for the determination of volatile organics
included the use of surrogate spikes. Each sample was spiked with a surrogate
mixture containing ds-toluene, bromofluorobenzene, and d4-l,2-dichloroethane.
Surrogate recoveries are presented in Table 5.
4-16
-------
TABLE 5. QUALITY CONTROL DATA FOR ANALYSES CONDUCTED ON THE SAMPLES
COLLECTED AT TEXACO IN SALEM, ILLINOIS. SURROGATE RECOVERIES
- VOLATILE ORGANICS
Sample
Identification
TI-BP-1B
TI-SB-1D
Method Blank
Method Blank
GCA
Control No.
41800
41806
01/09/85
01/15/85
Laboratory Control Sample
D8-
To luene
83
99
88
83
79
Bromof luorobenzene
110
74
114
80
77
D4-l,2-
Dichloroe thane
96
120
91
124
106
Average Percent Recovery 86
Relative Standard Deviation (%) 7.7
91
19
107
14
4-17
-------
APPENDIX A
SAMPLE IDENTIFICATION FORMS
A-l
-------
SAMPLE INVENTORY FOR MIOCO CHEMICAL CORPORATION III HOOD RIVER, ILLINOIS.
1DI
ILOC04272629
UD004272429
1LD004272429
ILD004272429
1LC004272429
1LB004272429
ILIIO(I4272429
1LCQ04272429
ILD004272429
1LD004272429
1LC004272429
1LM04272429
1LD004272429
1LD006272429
ILD004272429
ILD004272429
ILD004272429
11D004272429
1LD004272429
ILD004272429
ILD004272429
1LD004272429
SITE
Aioco Chiiicil Corp.
Aioco Chiiicil Corp,
Aioco Chiiicil Corp.
Aioco Chiiicil Corp.
Aioco Chiiicil Corp,
AJOCO Cheiicil Corp.
Aioco Cheiicil Corp.
Aioco Chiiicil Corp.
Aioco Chiiicil Corp.
Aioco Chiiicil Corp.
Aioco Chiiicil Corp.
Aioco Chiiicil Corp,
Aioco Chiiicil Corp.
Aioco Chiiicil Corp.
Aioco Cheiicil Corp,
Aioco Chiiicil Corp.
Aioco Chiiicil Corp,
Aioco Chiiicil Corp,
Aioco Cheiicil Corp,
Aioco Chiiicil Corp.
Aioco Chiiicil Corp.
Aioco Cheiicil Corp.
SOURCE
Sludgi Ligoon
Sludgi Ligoon
Sludgi Ligoon
Sludgi ligoon
Sludgi Ligoon
Sludgi tigoon
Sludgi Ligoon
Sludgt Ligoon
Sludgi Ligoon
Eludgi Ligoon
Sludgi Ligoon
Sludgi Ligoon
Spriy Pond
Spriy Pond
Spriy Pond
Spriy Pond
Epny Pond
Spriy Pond
Spriy Pond
Spriy Pond
Sludgi Ligoon
Sludgi Ligoon
COHHCNTS
Clur Liquid Phut
Clur Liquid Phut
Clur Liquid Phiu
Clur Liquid Phm
Oil Slick
Oil Slick
Oil Slick
Oil Slick
SAMPLE
IDI
ACC-OM-IA
ACC-ON-IB
ACC-OIMC
ACC-OIH0
ACC-OhS-IA
ACC-OHS-IB
ACC-ONS-IC
ACC-ONS-ID
ACC-SL-IA
ACC-SL-IB
ACC-SL-1C
ACC-9L-1D
ACC-SP-IA
ACC-SP-IB
ACC-SP-IC
ACC-SP-ID
ACC-SP-2A
ACC-EP-2B
ACC-SP-2C
ACC-9P-2B
ACC-SL-CI
ACC-SL-M
SAMPLE LAB
TYPE CONTROL 1
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Soil Con
Boil Cori
41731
41732
41733
41734
41733
41734
41737
4I7SB
41739
41740
41711
41742
41763
41744
41743
41744
41747
41748
41749
41770
41814
41813
DATE SAHPLIKB DATE DATE ANALYSIS DATE
SAHPLED CONTRACTOR RECEIVED ANALYZED CONTRACTOR REPORTED
11/I3/B4
11/13/84
11/13/84
11/13/84
11/13/84
11/13/84
11/13/84
11/13/84
11/13/84
11/13/84
11/13/84
1I/13/B4
11/13/84
11/15/84
11/13/84
11/13/84
11/13/84
11/13/84
11/13/84
11/13/84
11/13/84
11/13/84
BCA
BCA
BCA
BCA
BCA
ECA
BCA
BCA
BCA
BCA
BCA
6CA
BCA
BCA
ECU
BCA
BCA
ECA
BCA
BCA
BCA
BCA
11/19/84 NA
11/19/64 NA
11/19/84 12/05/84
11/19/84 01/11/83
11/19/84 NA
11/19/84 12/04/84
11/19/84 01/13/83
11/27/84 NA
11/19/84 12/05/84
1 1/27/84 NA
11/19/84 01/10/83
11/27/94 NA
11/19/84 I2/03/B4
11/27/84 OI/22/B3
11/27/84 NA
11/19/84 OI/09/B3
11/27/84 01/22/81
11/19/84 I2/03/B4
11/19/84 01/10/85
11/27/84 NA
11/19/84 02/2I/B3
11/27/84 01/01/83
RAD
RAD
BCA
GCA
RAO
BCA
BCA
RAD
BCA
RAD
BCA
RAD
ECA
RAD
RAD
BCA
RAD
ECA
BCA
RAD
BCA
RAO
OI/09/B3
02/12/83
DT
02/I2/B3
01/01/81
4I/2B/8S
01/09/83
02/28/83
OI/2B/B3
02/2B/B3
OI/C9/B3
OI/2B/B3
03/2B/B3
02/03/83
NA > not inilynd
-------
uo
SAHPLE INVENTORY FDR REILLY TAR t CHEMICAL IN 6RANITE CITY, ILLINOIS.
FACILITY
IDI
ILM04278340
RDOC427B340
1111004278340
lU0042763iO
1LD004278340
iwtotnmo
ILD004278340
1LD00427BM
11DOC627BIW
1LDC01279340
HD004278340
ILD0042763fcO
SI
Reilly Tir
Reilly Tir
Reilly Tir
Reilly Tar
Reilly Tir
Rfilly Tir
Reilly Tir
Reilly Tir
Reilly Tir
Reilly Tir
Reilly Tir
Rtllly Tir
FE
Chuicil
Chtiicil
ChttlcJl
ChHlcil
Chuicil
Chiilcil
Chuicil
Cheiicil
Cheiicil
Chtiicil
Cheiicil
Chuicil
SOURCE
Liiching Fiild
Ltiching FiiU
Ltiching Field
LiicMng Fitld
Ligoon
Ligoon
Ligoon
Ligoon
Ligoan
ligoon
Ligoon
Ligoon
COHNENTS
Fony, Aeritid Am
Foiiy, Aerited Am
Fony, Aerittd Am
Fony, Aeritid Arei
Cili Arei
Cili Am
CiU Arei
Cili Arei
SAMPLE
IB 1
RTC-F-IA
RTC-F-IB
RTC-F-IC
RTC-F-U
RTC-L-IA
RTC-L-IB
RTC-L-IC
RTC-L-IB
RTC-L-2A
RTC-L-2B
RTC-L-2C
RTC-L-2D
SAMPLE
TYPE
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
LAB
CONTROL 1
41771
41772
4I77I
41774
41775
41774
41777
4I77B
41779
41760
41761
41762
DATE
SAMPLED C
I1/14/B4
11/14/84
11/14/84
11/14/84
11/14/84
11/14/84
11/14/84
11/14/84
11/14/84
11/14/84
11/14/84
11/14/84
SAKPLINB
ONTRACTO
BCA
ECA
BCA
ECA
BCA
6CA
ECA
BCA
BCA
ECA
BCA
BCA
DATE
) RECEIVED
II/H/B4
11/11/84
11/27/64
11/27/64
11/27/64
11/19/64
11/19/84
11/27/84
II/27/B4
11/27/64
11/19/64
11/19/84
DATE
ANALY2ED C
12/04/84
01/10/63
01/22/6S
NA
OI/22/B5
12/04/64
01/10/85
NA
01/22/85
NA
12/04/84
01/09/65
INALYSU
1NTRACTO
ECA
ECA
RAD
RAD
RAD
6CA
BCA
RAD
RAD
RAD
ECA
ECA
DATE
R REPORTED
OI/09/6S
OI/2B/85
02/28/85
02/26/65
OI/09/B5
OI/2B/65
02/26/65
01/09/65
01/23/65
M • not inilyzed
-------
r
SAMPLE INVENTOR* FOR SHELL OIL COMPANY IX HMD RIVER, ILLINOIS.
FACILITY
101
ILD00427B340
KD006278310
1LD00427B140
ILDOOi27BUA
UD004276I40
1LD00427B340
110004276340
H500427E510
1LC004278360
Ilt00427SJ«
ILD30627B340
1LD00427B340
111)006278:40
ILD00427B340
ILC004278360
1LD004276340
SITE
Ehill Oil Coipiny
Shill Oil Coipiny
Shill Oil Coipiny
Shill Oil Coipiny
Shill Oil Coipiny
Shill Oil Coipiny
Shill Oil Coipiny
Shill Oil Coipiny
Shill Oil Coipiny
Skill Oil Coipiny
Shill Oil Coipiny
Still I Oil Coipiny
Shill Oil Coipiny
Shill Oil Coipiny
Shill Oil Conpiny
Shill Oil Coipiny
SOURCE
Biotriitunt Pond 12
Biotriitunt Pond 12
Biotriitunt Pond 12
liotriitunt Pond 12
Surdci lipoundunt
Surdci lipoundunt
Surdci lipoundunt
Surdci Iipoundunt
Surdci lipoundunt
Surdtf Upoundunt
Eurdci lipoundunt
Surdci lipoundunt
Surdci lipoundunt
Surdci lipoundunt
Surdci lipoundunt
Surdci lipoundunt
COMMENTS
Influent
Influent
Inlluint
IMlutot
Oil Slick
Oil Slick
Oil Slick
Oil Slick
SAMPLE
ID 1
SOC-AP-IA
EDC-AP-1B
BOC-AP-IC
SDC-AP-ID
SOC-EI-1A
SOC-S1-U
SOC-61-IC
SDC-SI-ID
BOC-SI-2A
SOC-S1-28
SOC-SI-2C
SOC-S1-2B
SOC-SI-3A
SOC-S1-3B
SOC-6I-3C
SOC-SI-30
SAMPLE
TYPE
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
LAB
CONTROL 1
41763
41784
41763
41784
4I7B7
4I7B8
4I7B9
41790
41791
41792
41793
41794
41795
4179ft
41797
41798
DATE
SAMPLED C
11/15/64
11/15/84
11/13/84
11/13/84
11/13/84
II/I3/B4
11/13/84
11/13/84
11/15/84
11/13/84
11/15/84
11/13/84
11/15/64
II/IS/B4
11/13/64
11/13/84
SAHPLIN6
ONTRACTOR
ECA
ECA
BCA
BCA
ECA
BCA
GCA
ECA
ECA
BCA
BCA
BCA
ECA
BCA
BCA
BCA
DATE
1 RECEIVED
I1/I9/B4
11/27/64
11/27/84
11/19/64
11/19/64
1I/I9/B4
11/27/64
11/27/64
11/19/84
11/27/84
11/27/84
11/19/84
11/19/64
11/19/84
11/27/64
11/27/64
DATE «
ANALY2ED U
12/06/64
01/22/83
NA
01/10/83
12/07/84
01/09/6S
01/22/85
NA
12/07/64
01/29/65
NA
01/09/85
NA
01/15/83
NA
NA
DIALYSIS
INTRACTD
ECA
RAD
RAD
BCA
BCA
ECA
RA1
RAD
ECA
RAD
RAD
ECA
ECA
ECA
RAD
RAD
DATE
R REPORTED
01/09/63
03/15/85
OI/2B/B3
01/09/85
05/28/85
01/15/65
01/09/B3
01/13/65
01/28/85
02/12/85
NA > not inilynd
-------
SAMPLE INVENTORY FOR TEIACO, INCORPORATED IN SOLED, ILLINOIS.
U1
Teuco
Teuco
Teuco
Teuco
Teuco
Teuco
Teiito
Tiiico
SITE
Incorporited
Incorporited
Incorporited
Incorporited
Incorporited
Incorporited
Incorporited
Incorporited
SOURCE
Bubble Pit
Bubble Pit
Bubbli Pit
Bubble Pit
Settling Bitin
Settling Bitin
Settling Bitin
Settling luin
BAHPLE
COKHENTS ID 1
TI-BP-IA
TI-BP-1D
TI-BP-1C
TI-BP-IO
TI-SB-1A
Tl-SB-IB
TI-SB-IC
Tl-SB-ID
BAHPLE
TVPE
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
LAB
CONTROL 1
4IW
41BOO
41801
4IB02
41B03
4IB04
4IB05
41B04
DATE
SAMPLED C
11/14/84
11/14/84
11/14/64
II/14/B4
11/14/84
11/14/64
11/14/84
11/14/64
5AHPLINB
ONTRAC16I
BCA
ECA
BCA
ECA
ECA
ECA
BCA
BCA
DATE
» RECEIVED
11/19/64
11/19/64
11/27/B4
11/27/64
11/27/64
II/I9/B4
11/27/64
11/19/84
DATE 1
ANALYZED Cl
12/07/64
01/09/85
01/29/B3
NA
NA
NA
NA
01/13/65
INALVSIS
1NTRACTO
BCA
BCA
RAD
RAD
RAO
SCA
RAD
ECA
DATE
IR REPORTED
01/09/65
01/26/65
03/15/65
02/12/8!
NA • not inilyied
-------
APPENDIX B
GCA DATA REPORT FORMS
B-l
-------
Project
1-623-027
CCA Control No.
41754
DATA REPORT SHEETS
Purgeables
Sample I.D.
Sample Matrix Water
Instrument
Analysis Date ..1/11/85 ______
5985^00 /MS, Sample Dilution _1;5,PT
Parameter
Chlororaethane
Bromome thane
Vinyl chloride
Chloroethane
Methylene chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethene
1 . 1-Dichloroethane
Trans-l,2-dichloroethene
Chloroform
2-Butanone
1,1, 1-Trichlorot thane _
Carbon tetrachloride
Bromodichloronethane
Total xvlenes
Concentration
(ug/1)
NT)*
NO
NO*
ND
NO**
ND**
ND
ND
ND
ND-.''
34K
ND
ND
ND
ND
ND
Parameter
1,1^2,2-Tytrachlcroethane
1 ,2-Di.chloroprooare
Trans- 1 ,3-DichloroDropen§
T rich loroet hens
Dibrotnochlprome thane
Benzene
cis-l,3-Dichlorccrooene
2-Chloroethvl vinvl ether
Broiaoform
4-Methvl-2-oentat;oTie
Tetrachloroethene
Toluene
Chlorobenzene
Ethylbenzcne
Styrene
Concentration
(ug/1)
ND
ND
ND
ND
ND
ND
ND
ND*
1 ND
f -ND*
ND
ND
ND
ND
ND
PT s Purge and Trap
DI = Direct Injection
ND
ND*
< 50 ug/1
< 100 ug/1
= blank contamination was observed for this compound
ug/1 = ppb (for density of water » 1)
K = Quantitation below detection limit
B-2
©DA
GCA
..-
Technology Division
-------
Project
1-628-037
GCA Control No.
DATA REPORT SHEET
Qualitative Compounds*
Sample I.D. ACC-OM-3D
Analysis Date
1/11/85
Sample Matrix _Water ^^ Instrument HP 5985 GC/HS Sample Dilution 1:5 ?T
Parameter
Allyl Alcohol
Bis(chloromethvl)ether
Cvclohexane_ T _ r ~ .
Cvclohexanone
1,2-Dibromoethane
Dichlo rod ifluorome thane
Diethyl_etherTT,_ .._.
Ethyl acetate
Ethvl acrvlate
Concentration
(Mg/D
NA
NU
ND
ND
ND
ND
ND
ND
JNA
Parameter
Furfural _^_ ^ n._<_^ ^
IsobutYl alcohol .
Methyl acetate
Methyl alcohol
Methyl rcethacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luoromethane
1,,1,2-Trichloro-
1,,2,,2-tfrifluoroethane
Trifluoroethane
Concentration
(ug/D
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
^Concentration based on a comparison of the total ion area of the compound with
that of the internal standard.
NA « Not analyzed by purge and trap
PT * Purge and Trap
DI * Direct Injection
ND
< 50 ug/1
ug/1 = ppb (for density of water = 1)
B-3
GCA COPPOflAPCN
'.^ Technology Division
GCA
-------
Project
1-628-037
GCA Control No. 41757
DATA REPORT SHEETS
Purgeables
Sample I.D. _ ACC-J3MS-1J^
Analysis Date _l/15/85_
Sample Matrix Oil (PEG)lnstrument HP 5985 CC/MS Sample Dilution 1:500 FT
Parameter
Chlorome thane
Bromomethane
Vinyl chloride
Chloroethane
Methylene chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethene
1 , 1-Dichloroethane
Trans-1 ,2-dichloroethene
Chloroform
2-Butanone
1 . 1 , 1-Trichloroethane
Carbon tetrachloride
Bromodichloromethane
Total xvlenes
Concentration
(yg/1)
ND*
ND
ND*
ND
27400*
ND
ND
ND
ND
ND-'
ND
ND
ND
ND
ND
ND
Parameter
1 , 1 ,2 ,2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-l^S-Dichloropropene
Trichloroethene
Dibromochlorome thane
Benzene
c is-1 , 3-Dichloropropene
2-Chloroethvl vinvl ether
Bronioform
4-Methvl-2-pent2none
Tetrachloroethtjne
Toluene
Chlorobenzene
Ethvlbenzene
Stvrene
Concentration
(ug/1)
ND
ND
ND
ND
ND
ND
ND
ND*
ND
1 ND*
ND
ND
ND
ND
ND
PT = Purge and Trap
DI = Direct Injection
ND = < 5000 jig/1
ND* - < 10000 ug/1
ug/1 = ppb (for density of water = 1)
K = Quantitation below detection limit
* = corrected for blank value
B-4
~^^r -^^ •^••v
GCA
GCA cCRPORAncr:
Technology Division
-------
Project
1-628-037
GCA Control No. 41757
DATA REPORT SHEET
Qualitative Compounds*
Sample I.D. . ACC-QMS-1 C
Analysis Date.-^.1/1.5/_85.
Sample Matrix Oil (PEG) Instrument HP 5985 GC/MS Sample Dilution 1:50.0 FT
Parameter
Allvl Alcohol
BisCchloromethyDether
Cvclohexane
(^yclohexanone
1,2-Dibromoethane
Dichiorodifluorome thane
Diethvl ether
Ethyl acetate
Ethyl acrylate
Concentration
(yg/l)
NA
ND
ND
NA
ND
ND
ND
ND
NA
-f '
Parameter
Furfural
Isobutyl alcohol
Concentration
(ug/D
ND
NA
Methyl acetate 1 ra
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
NA
ND
NA
ND
ND
Trichlorof luoromethane ' ND
1.1.2-Trichloro-
1,,2,,2-trif luoroethane
Trifluoroethane
ND
ND
^Concentration based on a comparison of the total ion area of the compound with
that of the internal standard.
NA = Not analyzed by purge and trap ; see FID results
PT - Purge and Trap
DI = Direct Injection
ND
< 5000 ug/1
ug/1 = ppb (for density of water = 1)
B-5
GCA
GCA
Technology Division
-------
Project
1-628-037
Sample I.D.
GCA Control No. 41757
(Matrix Spike)"
DATA REPORT SHEETS
Purgeables
Analysis Date _J./15/85;
Sample Matrix ,011 (PEG) Instrument HP 5985 GC/MS Sample Dilution 1:500 PT
Parameter
Chloromethane
Bromome thane
Vinyl chloride
Chloroethane
Methylene chloride
Acetone
Carbon disulfide
1,1-Dichloroethene
1 , 1-Dichloroethane
Trans-1 ,2-dichloroethene
Chloroform
2-Butanone
1,1, 1-Trichloroethane
Carbon ^tetrachloride
Bromodichloromethane
Total xylenes
Concentration
(ug/1)
NO*
ND
ND*
ND
41550*
6635*
ND
ND
ND
ND-'
ND
ND
ND
ND
ND
ND
Parameter
1,1,2, 2-Tetrachloroethane
1 ,2-Dichloropropane
Trans-1 ,3-Dichloropropene
Trichloroethene
Dibromochloromethane
Benzene
cis—1 ,3-Dichloropropene
2-Chloroethyl vinvl ether
Bromoform
4-Methvl-2-pentanone
Tetrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentration
(ug/1)
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
ND
ND
ND
ND
PT « Purge and Trap
DI = Direct Injection
ND = < 5000 ug/1
ND* = < 10000 ug/1
uy/1 = ppb (for density of water = 1)
K = Quantitation below detection limit
* = corrected for blank value
B-6
GCA
GCA CQRFORAriOM
Technology Division
-------
Project
1-628-037
GCA Control No._*!7_5MMS)_
DATA REPORT SHEET
Qualitative Compounds*
Sample I.D. ^ACC-OMS-lC
Analysis Date 1/15/85
Sample Matrix Oil (PEG) Instrument HP $985 GC/KS Sample Dilution 1:50° PT
Parameter
Allvl^Alcohol
Bis(chlQromethyl}ether
Cyclohexane
$vc lohexanone
1,2-Dibromoethane
Dichlorodif luoromethane
Diethvl ether
Ethyl acetate^_
EthvLacrYlate
Concentration
(Ug/1)
NA
ND
ND
NA
ND
ND
ND
ND
NA
Parameter
Furfural
Isobutvl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichl
-------
Project
1-628-037
GCA Control No. ,_4T757
DATA REPORT SHKKTS
Purgeables
(Matrix Spike
Duplicate)
Analysis Date __1/_15/_S5_
Sample I.D. __ACCd2i!S=.LC
Sample Matrix Oil fprm Instrument HP 5985 GC/MS. Sample Dilution 1:500 PT
Paraneter
Chlororaethane
Bronome thane
Vinyl chloride
Chloroethane
Methylene chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethene
1 , 1-Dichloroethane
Trans-li2-dichloroethene
Chloroform
2-Butanone
1.1, 1-Trichloroethane
Carbon tetrachlcride
Broraod ich loromethane
Tocal xvlenes
Concentration
(ug/1)
'ND*
ND
ND*
ND
37050*
ND
ND
ND
ND
ND-'
ND
ND
ND
ND
ND
ND
Parameter
1 , 1 , 2 , 2-To t rach lo ro
-------
Project
1-623-037
GCA Control No. 41757 (MSP)
DATA REPORT SHEET
Qualitative Compounds*
Sample I.D. __ACC-QMS-1C
Analysis Date 1/15/85
Sample Matrix __Qil. (PEG) Instrument _HP..$985 GC/MS Sample Dilution _1;50° PT
Parameter
Allvl Alcohol_
p is (chlorotngthyl) ether
Cvclohexane
Cvclohexanone
1,2-Dib^omoethane .
pichlorod if luorome thane
Diethvl ether
Ethyl acetaeerntm_^
Ethyl acrylaee_ _
Concentration
(ug/1)
NA
ND
ND
NA
ND
ND
ND
ND
NA
•
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrvlate
n-Butyl alcohol
n— PTOPV! benzene
Tetrahydrofuran
Trich loro f luorqmechane
1.1.2-Trichloro-
1.2, 2-t;r if lueroethane
^Tri^luoroethane
Concentration
(pg/1)
ND
i^A
ND
NA
ND
NA
ND
ND
ND
ND
ND
^Concentration based on a comparison of the total ion area of the compound with
that of the internal standard.
NA * Not analyzed by purge and trap; see FID results
PT « Purge and Trap
DI * Direct Injection
ND = < 5000 ug/1
ug/1 = ppb (for density of water = 1)
B-9
GCA
GCA CORPORATION
Technology Division
-------
Project 1-628-037
GCA Control No. 41761
DATA REPORT SHEET: TSOF
Volatile Organic Compounds
Sample Identification ACC-SL-IC
Analysis Date 1/10/85
Instrument and Sample Volume*
HP 5935 GC/MS 1:5 FT
Sample Matrix Water
Finnigan OWA GC/MS_
PE 3920 GC/FID
HP 5890 GC/FID
Compound
Acetone
Acetonitrile
Allvl Alcohol
Aniline
Benzene
Bis (chloromethyl) ether
Bromodichlorome thane
Bromoform
Bromome thane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethvl viuyl ether
Chloroform
Chloromethane
C is-1 ,3-Dichloropropene
Cyclohexane
Cyclehexanone
Dibromochlorome thane
1 ,2-Dibromoethane
Dich lorod if luorozne thane
1 . 1-Dichoroethane
1 ,2-Dichloroethylenf!
1 , 1-Dichloroethylerrc
ij2-Dichioroorocj:n2
Diethvl ether
Ethyl acetate
Ethvl acrvlate
Ethylene
Concentration
(mg/1)
0.17
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Compound
Ethytene chloride
Ethvlene dibromide
Ethylene dichloride
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methvl chloride
Methyl ethyl ketone
Methyl isobutvl ketone
Methyl methacrvlate
Methylene chloride
n-Butvl alcohol
n-Propyl benzene
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethvlene
Tetrahydrofuran
Toluene
Trans l,3-Dichlorcr>rooene
1,1. 1-Trichlorcethar.e
Trichloroethvlsna
Trichlorof lt:oro^r»rh-in .-
1,1,2-Trichlorc-
-l,2.2-Trifluoronethar.ci
Trif luoroechane
Vinyl chloride
Xylenes
Concentration
(rag/1)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND*
ND
0.19
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
I MD
ND
ND
ND~
MD '
1
*PT = Purge and Trap
DI = Direct Injection
HS = Headspace
ND = < 0.05 rag/1
ND* = < 0.10 tag/1
B-10
GCA TECHNOLOGY DIVISION
-------
Pro ject_
1-628-037
CCA Control .No. 41761 (tnauri:-: spike)
DATA REPORT SH'.CLT: TSDF
Volatile Organic Compounds
Sample Identification ACC-SL-IA
Analysis Date 1/10/85
Sample Matrix Wat_er
Instrument and Sample Volume*
UP 5985 GC/MS 1:5 FT
Finnigan OWA GC/MS.
PE 3920 GC/FTD
HP 5890 GC/FiD
Compound
Acetone
Acotonitrile
Allvl Alcohol
Aniline
Benzene
Bis(chloromethyl)ether
Bromodichlorome thane
Bromoform
Brombme thane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethyl vinvl ether
Chloroform
Chlorome thane
C is-1 ,3-Dichloropropcne
Cvclohexane
Cvclohexanone
Dibroraochloromethane
1 ,2-Dibromoethane
Dichlorodif luo rome t hane
1 , 1-Dichoroethane
1 ,2-Dichloroethylcne
1 , 1-Dichloroethvlene
1 ,2-Dichloroprooane
Diethvl ether
Ethvi acetate
Ethyl acrvlate
Ethvlene
Concentration
(mg/1)
0.17
NU
NO
Nn
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Compound
Ethylene chloride
Ethylene dibroraide
Ethvlene dichloride
Furfural
Isobutyl alcohol
Methvl acetate
Methyl alcohol
Methvl chloride
Methyl ethyl ketone
Methvl isobutvl ketone
Methyl methacrylate
Methvlene chloride
it-Butyl alcohol
n-Propyl benzene
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethvlenu
Tet rahvdrof uran
To luene
Trans 1,3-Dichloropropene
I , I , l-Trichlorc-thane
Trichloroethvlene
Trichlorof luorom" thane
1,1,2-Trichloro-
-!,2,2-TrifluorcTetban2
Trif luoroethans
Vinvl chloride
Xvlenes
1
1
Concentration
(mg/1)
MD
ND
ND
ND
ND
ND
ND
ND
ND
ND*
ND
0.43
L ND
ND
ND
ND
ND
ND
ND
ND
1 ND
ND
t ND
ND
ND
ND*
NI)
*FT = Purge and Trap
DI = Direct Injection
HS = Keadspace
ND = < 0.05 rajj/l
ND* = <- 0.10 ms/1
B-ll
GCA TECHNOLOGY DIVISION 3OA
-------
Project.
1-628-037
GCa Control No,
_417fil (matrix spike-
duplicate)
DATA REPORT SHEET: TSDF
Volatile Organic Compounds
Sample Identification ACC-SL-1A
Analysis Date 1/10/85
Instrument and Sample Volume*
HP 5985 GC/MS 1:5 FT
Sample Matrix Water
Finnigan OWA GC/MS__
PE 3920 GC/FID
H? 5890 GC/FID
Compound
Acetone
Acetonitrile
Allvl Alcohol
Aniline
Benzene
Bis(chloromethyl)ethor
Bromodichlorome thane
Bromoform
Bromotnethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethvl vinvl ether
Chloroform
Chlorome thane
C is-1,3— DichlorooroDene
Cvclohexane
Cyclohexanone
Dibromochlorome thane
1 . 2-Dibromoethane
Dichlo rod if luorone thane
1 . 1-Dichoroethane
1 ,2-Dichloroethvlene
1 , 1-Dichloroethvlene
1 , 2-Dichlorooropane
Diethvl ether
Ethyl acetate
Ethvl acrvlate
Ethylene _
Concentration
(mg/1)
0.45
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Compound
Ethylene chloride
Ethylene dibromide
Ethylene dichloride
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl chloride
Methyl ethyl ketone
Methyl isobutvl ketone
Methyl tnethacrvlate
Methylcne chloride
n- Butyl alcohol
n-Proovl benzene
Styrcnti
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
Tet rally drofuran
To luene
Trans 1,3-Dichloroprooene
1.1. 1-Trichloroethane
Trichioroethvlene
Trichlorof luorome Chans
1,1,2-Trichioro-
-1,2, 2-Tr if luoromethane
Tr if luoroe thane
Vinvl chloride
Xylenes
Concentration
(mg/D
ND
ND
ND
ND
ND
ND
ND
ND
NE
ND*
ND
0.75
ND
ND
ND
ND
ND
ND
ND
ND
?ID
ND
xn
?ID
ND
OT*
::D
*PT = Purge and Trap
DI = Direct Injection
HS = lieadspace
ND = < 0.05 mg/1
ND* = < 0.10 mfi/1
B-12
OCA TECHNOLOGY DIVi:..QN
-------
Project_
1-62S-Q37
Control No.
DATA RKPOUT SilKKT: TiiDF
Volatile Organic Compounds
Sample Identification
Analysis Date
ACC-SP-1D
1/9/85
Instrument and Saaple Volune*
HP 5985 GC/MS 1:5'PT
Sanple Matrix Water
Finnigan OWA GC/MS_
PE 3920 GC/FID ~
HP 5890 GC/FID
Compound
Acetone
Acetonitrile
Allvl Alcohol
Aniline
Benzene
Bis(chloromethvl)ether
Bromodichloromethanp
Bromoform
Bromome thane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethyl vinyl ether
Chloroform
Chloroine thane
C is-l,3-Dichlorooropene
Cvclohexane
Cyclohexanone
Dibromochlorome thane
1 . 2-Dibrorcoethane-
D ichlorod if luoroase thane
1 , 1-Dichoroethane
1 ,2-Dichloroethylene
1 , 1-Dichloroethylene
1 ,2-Dichloropropune
Diethvl ether
Ethyl acetate
Ethyl acrvlate
Ethylene
Concentration
(rag/1)
0.15
ND
ND
ND
0.68
ND
ND
ND
ND
ND
ND
ND
ND
ND*
0.06
ND*
ND
ND
ND
ND
ND
ND
NU
ND
ND
ND
ND
ND
| ND
| ND
Compound
Ethvlene chloride
Ethylene dibromide
Ethylene dichloride
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl chloride
Methyl ethvl ketone
Methyl isobutvl ketone
Methyl methacrylate
Methylene chloride
n-Butvl alcohol
n-Propyl benzene
Stvrene
1, 1,2,2-Tatrachloroethane
Tetrachloroethylene
Tetrahvdrofuran
Toluene
Trans 1,3-Dichloronropene
1,1, 1-Trichloroethane
Triehloroethvlen^
Trichlorof luorome thane
1, 1,2-Trichloro-
-1.2,.2-Trif luoroir.athane
Tr if luoroe thane
Vinyl chloride
Xylenes
Concentration
(ms/l)
ND
ND
NU
ND
ND
ND
KD
ND
MD
ND*
ND
0.09
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Kb
ND
ND
ND-
ND
*PT = Purge and Trap
DI = Direct Injection
HS - Headspace
ND = < 0.05 mg/1
ND* = < 0.10 mg/1
B-13
OCA TECHNOLOGY DIVISION
-------
Project 1-628-G37
GCA Control. No. 41769
DATA REPORT SHKET: TSDF
Volatile Organic Compounds
Samp le Ident if icat ion_
Analysis Date
Instrument and Samnle Volume*
HP 5985 GC/MS 1:5 P'f
1/10/85
Sample Matrix Water
Finnigan OWA GC/MS
PE 3920 GC/FID "
HP 5890 GC/FID
Compound
Acetone
Acetonitrile
Allvl Alcohol
Aniline
Benzene
Bis (chloromethyl)ether
Bromodichloromethane
Bromoform
Bromome thane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethyl vinvl ether
Chloroform
Chlorome thane
C is-l,3-Dichloropropene
Cvclohexane
Cyclohexanone
Dibromochloromethane
1 , 2-Dibromoethane
Dichlorodif luoromechane
1 , 1-Dichoroethane
1 , 2-Dichloroethvlene
1 , 1-Dichloroethylene
1 , 2-Dichloropropane
Diethyl ether
Ethyl acetate
Ethyl acrvlate
Ethvlene
Concentration
(mg/l)
0.44
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND*
NU
ND*
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Compound
Ethylene chloride
Ethvlene dibromide
Ethvlene dichlorids
Furfural
Isobutyl alcohol
Methvl acetate
Methvl alcohol
Methvl chloride
Methyl ethvl ketone
Methyl isobutyl k^'tone
Methvl methacrylate
Methylene chloride
n-Butvl alcohol
n-Propyl benzene
Stvrene
1,1,2.2-Tetrachloroethane
Tetrschloroethvlene
Tetrahvdrofuran
To luene
Trans 1,3-Dichloroorooene
1,1. 1-Trichlorcethane
Trichloroethvlene
Trichlorof luorometrhnne
[,1,1,2-Trichloro-
-1,2, 2-Tr if Luoromethane
Trif luoroethane
Vinyl chloride
^Xylenes
-
Concentration
(mg/l)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND*
ND
0.61
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND*
ND
*PT = Purge and Trap
DI = Direct Injection
HS = Headspace
ND = < 0.05 mg/L
N'D* = < 0.10 mg/l
B-14
:CA TECHi iOLCGY DIVISION
-------
Project 1-628-niI
GCA Control Me.
41814
DATA REPORT SHEET
Haadspace Analysis
Sample I.D.
ACC-SL-C1
Analysis Date 2/21/85
Sample Matrix
Soil Core
Instrument HP5985 GC/MS
Sample Dilution
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chloromethane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 L2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodi Chloromethane
Total xylenes
Concentration
(ug/g)
ND •
ND
ND-
ND
11
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethvlene
Dibromech lor ome thane
Benzene
cis-1 , 3-DichloroproDVlene
2-Chloroethylvinylether
Bromof orm
4-Methyl-2-pjentanone (MIBK)
Tetrachloroethylene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratic
(ug/g!
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Ln
= PPm
*C.A.S. Numbers for xylene isomers are as follows;
ND « < 5.0 ug/g
K «* Quantitation below detection limit
ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
GCA
Technology Divisioi
-------
Project 1-628-037
GCA Control No.
Sample I.D.
ACC-SL-C1
Sample Matrix So11 Core
DATA REPORT SHEET
Headspace Analysis
Additional Compounds
Instrument HP5985 GC/MS
Analysis Date
2/21/85
Sample Dilution
N.A.
C.A.S.
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethvl )ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorodif luorome thane
Diethyl ethor
Ethvl acetate
Ethyl acrylate
Concentration
(ug/g )
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
L* t A • fa •
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luorome thane
1,1,2-Trichloro-
1,2, 2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/g)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
w
I
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
ug/g =
ND = < 5.0 ug/g
K = Quantitation below detection limit
O0A
GCA
.
Technology Division
-------
Pro ject_
1-628-037
CCA Conrrol No. 41772
DATA REPORT SHEET; TSDF
Volatile Organic Compound:;
Sample Identification RTC-F-1B
Analysis Date I/10/85
Sanple Matrix Water
Instrument and Sanple Volume*
IIP 5935 C.C/MS U1JTL
Finnigan OVA GC/MS
PE 3920 GC/FID
HP 5890 GC/FID
Compound
Acetone
Acetonitrile
Allvl Alcohol
Aniline
Benzene
Bis(chlororaethyl)eth'-.r
Brotnodichloromethane
Bromofonn
-Bromome thane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethvl vinvl ether
Chloroform
Chlororaethane
C is-1 ,3— Dichloropropene
Cvclohexane
Cvclohexanone
Dibromochloroiae thane
1 , 2-Dibroicoethane
Dichlorod if luorome thane
1 , 1-Dichoroethane
1 ,2-Dichloroeth"l3ne
1 , 1-Dichloroethvlene
1 ,2-Dichlorooroocna
Diethvl ether
Ethvl acetate
Ethvl acrvlate
Ethvleno
Concentration
( mg/1)
0 I1}
Nn
ND
NT)
NH
ND
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
ND
ND
ND
ND
NU
ND
ND
ND
ND
ND
ND
ND
ND
Compound
Ethvlene chloride
Ethvlene dibromide
Ethvlene dichloride
Furfural
Isobutyl alcohol
Methyl acetate
Methvl alcohol
Mathvl chloride
Methyl ethvl ketone
Methvl isobutvl ketone
Methyl methacrvlate
Methylene chloride
n-3utyl alcohol
n-Propyl benzene
Styrene
1,1,2.2-Tetrachloroethane
Tetrachloroethvlene
Tetrahydrofuran
To luene
Trans 1,3-Dichloroprooene
1,1. l-Trichlorceth.ciie
Trichloroethvlenc
Trichlorof luorowethaue
1,1,2-Trichloro-
-1 ,2 ,2-Trif luororaethane
Tr if luorce thane
Vinyl chlorida
Xvlenes
Concentration
(mR/1)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND*
ND
0.20
ND
ND
ND
ND
ND
ND
ND
! ND
XD'
ND
ND
ND
ND
ND*
ND
*PT = Purge and Trap
DI = Direct Injection
HS = Hsadspace
ND = < 0.05 mg/1
ND* = < 0.10 mg/1
TECHNOLOGY DIVISION
B-17
-------
Project
L-623-037
CCA Control
41772
DATA REPORT SHEETS
Purgeablcs
Sacple I.D. HElEll!
Anal%-sis Date
1/10/35
oacple Matrix Water Instrument HP 5985 GC/HS Sample Dilution 1:5 ?T
Parameter
Chloroaethane
Bcorooee thane
Vinvl chloride
Chloroethane
Methvlene chloride
Acetone
Carbon distilfide
1 , 1-DichlorcPthene
1,1-Dichlcroethar.e
Trans-1 ,2-dichloroethene
Chloroform
2-Butar.one
1,1, 1-Trichloroethane
Carbon tetrachloride
BroraodichloroTsethane
Total xylenss
Concentration
(WS/D
N!)*
NO
NO*
ND
ND**
ND**
ND
ND
ND
ND •''
ND
KD
ND
N'D
XD
ND
Parameter
l,l,2,2-Tetrachloro§thane
1 ,2-Dichloropropane
Trans-1 ,3-Dichlorooro^ene
Trichloroethene
Dibromochloronethane
Benzene
cis-1 ,3-Dichloroorooene
2-Chloroath"l vinyl ether
Brotnoform
! 4-Methyl-2-T3entanone
[Tetrachloroethene
iToluene
Chlorobenzer.e
Ethylbenzene
Stvrene
Concentration
(,g/U
ND
iN'D
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
ND
ND
ND
ND
PI = Purge and Trap
DI * Direct Injection
ND = < 50 ug/1
ND* = <100 us/1
ug/1 = ppb (for density of water = 1)
K - Quantitation belov detection limit
ND** = Elaak contaninaticn observed for this sample.
B-18
•i^Ji^ Technology Division
GCA
-------
1-62S-C37
GCA Coatrol No. 41772
DATA KSPURT SilEET
Qualitative Compounds*
Scnple I.D. _ RTC-F-13
Analysis Date
1/10/85
Saaole Matrix
Instrument
Sample Dilution 1 :5 PT
Parameter
Allvl Alcohol
Bis (chlororaethvl) ether
Cvclohsxar.e _
C'-"c lohexanone
Concentration
(yg/1)
NA
KD
ND
ND
1,2-Dibrocioetbane ! ND
pichlorodif luoroTWthsne
Diathvl ether
Ethvl acetate
Erhvl acrvlate
ND
ND
MD
NA
I
1 _
1
Parameter
Furfural
Isobutyl alcohol
Msthv! acetate
Methyl alcohol
Methvl methacrvlate
n-Butvi alcohol
n-Propyl benzene
T^t.r3hvdTof'jran
Trichlozof luorongthanf
1-1.2-Trichloro-
1,2,2-trif luoroethan*
Trif luoroethfine
Concentration
(yg/1)
ND
NA
ND
NA
ND
NA
MD
SD
N:D
ND
ND
^Concentration based on a comparison of the total ion area of the compound with
that of the internal standard.
NA
Not analyzed by purge and trap
PT - Purge and Trap
DI = Direct Injection
ND = < 50 ug/1
ug/1 = ppb (for density of water = 1)
B-19
Technology Civision
-------
Project ' 1-628-037
CCA Control No.
DATA REPORT SHEET: T3DF
Volatile Organic Compounds
Sample Identification,
Analysis Date
Instrument and Snrapla Volume*
HP 5985 GC/MSj_-5F[
RTC-L-1C
1/1Q/85
Sample Matrix Water
Finnigan OWA GC/MS_
PE 3920 GC/FID ~
HP 5890 CC/FID
Compound
Acetone
Acetonitrile
Allvl Alcohol
Aniline
Benzene
Bis (chloromethvl) ether
Bromodichlorome thane
Bromoform
Bromome thane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethvl vinyl ether
Chloroform
Chloromethane
C is-l,3-Dichloropropene
Cvclohexane
Cvclohexanone
Dibromochlorome thane
1,2-Dibromoethane
Dichlorodif luoroinethane
I . l-Dichoroethane
1 ,2-Dichloroethylene
1 , 1-Dichloroethvlene
1 . 2-DichloroproDiine
Diethvl ether
Ethyl acetate
Ethyl acrvlate
Ethvlene
Concentration
(mg/1)
0.16
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Compound
Ethvlene chloride
Ethylene dibromide
Ethvlene dichloride
Furfural
Isobutyl alcohol
Methyl acetate
Methvl alcohol
Methyl chloride
Methyl ethyl ketone
Methvl isobutvl ketone
Methyl methacrylate
Methylene chloride
n— Butyl alcohol
n-Propyl benzene
Styrene
1 , 1 ,2 ,2-Tetrachloroethane
Tetrachloroethvlene
Tetrnhvdrofuran
Toluene
Trans l,3-Dichloroorot3er.e
1 . 1 . 1-Trichlorcethane
Trichloroethvlene
Trichlorof luorociethane
1,1,2-Trichloro-
-1 .2 ,2-Trif luororKjthane
Tr if luo roe thane
Vinvl chloride
Xylencs
Concentration
(mg/1)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND*
ND
0.16
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND*
::D
*PT = Purge and Trap
DI = Direct Injection
HS = Keadspace
ND = < 0.05 mg/1
ND* = < 0.10 mg/1
B-20
CA TECHNOLOGY DIVISION
-------
Project
.1-623-037
Control No.
41777
DATA REPORT SiiKtTS
Purgeables
Sanple I.D. RTC-L-IC
Sample Matrix Water
Analysis Date
Parameter
Chlorotne thane
BromoTne thane
Vinvl chloride _
Chlorcethane
Mgthvlere chloride
Acetone
Carbon disulfide
1 , 1-Oichloroethene
1 , 1-Dichloroethane
Trans-l ,2-dichlorcethenp
Chloroform
2-Butanone
1.1. 1-Trichloroethane
Carbon tetrachlcrids
Brnraodichloromethane
Total xvlenes
Concentration
(ug/1)
ND*
ND
ND*
ND
ND**
ND**
ND
N'T)
ND
ND '
ND
ND
ND
ND
ND
ND
Parameter
1A 1,,2,,2-Tetrachloroethane
1 ,2-Dichloropropane
Trans- 1 , 3-D ichloroprooene
Trichioroethene
Dibronochlorone thane
Benzene
c is- 1 , 3-D ichloropropene
2-Chlorosthyl vinyl eChar
[.Bromoform
1 4-Methvl-2-oentanone
lT«> t rach loroe thene
[TqluRne
IChlotobenzene
Ethvlbenzene
Stvrene
Concentration
(-g/D
ND
85
ND
ND
ND
ND .
ND
ND*
ND
ND*
ND
ND
ND
ND
ND
PT - Purge and Trap
DI = Direct Injection
ND « < 50 ug/1
ND* - <1QQ ug/1
ug/i - ppb (for density of water = 1)
K - Quantitation b^lov detection linit
ND** = Blank contamination observed for this compound.
B-21
GCA
.
Technology Division
-------
Project
1-628-027
GCA Control No. 41777
Sanple I.D.
RTC-L-1C
DATA REPORT SHEET
Qualitative Compounds*
.. _ Analysis Date
1/10/35
Sr.=ple Matrix Water Instrument H? 5985 GC/MS Sample Dilution 1:5 PT
Parameter
Allvl Alcohol
B is (chloromethvl) ether
Cvclohexane
Cvc lohexanone
1 j, 2-D Ibroiaoet hane
D ichlc rod if luoroma thane
Diethvl ether
Euhvl acetate
Concentration
(ug/1)
NA
ND
ND
NO
ND
ND
ND
Parameter
Furfural
Isobutyl alcohol _
Methyl acetate
Methyl alcohol
Methvl raethacrvlate_ _
Concentration
(wg/l)
ND
NA
ND
NA
ND
n- Butyl alcohol i NA
n-Pronyl benzene
Nn L Tetrahvdroftjrsn
ND
ND
Schvl_acrvlate
NA
_TrichlQTQfluoronethane_
ND
!
1,1,2-Trichloro-
lA2J,2-trifluorQ9thane
Trifluotoethane
ND
ND
^Concentration based on a comparison of the total ion area of the compound with
that of the internal standard.
KA * Not analyzed by purge and trap
PT » Purge and Trap
DI = Direct Injection
SID - < 50 ug/1
ug/1 = ppb (for density of water = 1)
B-22
GCA
HCA CORPORATION
Technology Division
-------
Project,
1-628-037
GCA Control i'io.
4173:
DATA REPORT SHEET: TSDF
Volatile Organic Compounds
Sample Identification_RTC-L-2D
Analysis Date 1/9?S5
Instrument and Sample Volume*
HP 5985 GC/MS Nn 'IN uf Ion: F
Sample Matrix \Jater_
Finnigan OWA GC/MS_
PE 3920 GC/FID
HP 5890 CC/FID
Compound
Acetone
Acetonitrile
Allvl Alcohol
Aniline
Benzene
Bis(chloromethyl)ethf;r
Bromodichloromethane
Bromoform
Bromome thane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethyl viuvl ether
Chloroform
Chloromethane
C is-l,3-Dichloropropene
Cvclohexane
Cvc lohexanone
Dibromochloromethane
1 ,2-Dibroraoethane
Dichlorod if luorome thane
1 , 1-Dichoroethane
1 .2-Dichloroethvlene
1 , 1-Dichloroethvlene
1 .2-Dichioroorops.ne
Diethvl ether
Ethvl acetate
Ethvl acrvlate
Ethylene
Concentration
(mg/1)
0.025
MD
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Compound
Ethylene chloride
Ethylene dibromide
Ethylene dichloride
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl chloride
Methyl ethyl ketone
Methyl isobutvl ketone
Methyl methacrylate
Methylene chloride
n-Butyl alcohol
n-Propyl benzene
Styreno
1, 1,2,2-Tetrachloroethane
Tetrachloroethvlene
Tetrahydrofuran
Toluene
Concentration
(tns/1)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND*
KD
0.016
ND
ND
ND
ND
ND
ND
ND
Trans 1,3-Dichlorcurooene! ND
1, 1,1-Trichloroethane ' > ND
Trichloroethvlene
Trichlorof luoroine thane
1,1,2-Trichloro-
-1.2,2-Trif luororea thane
Trifluoroe thane
Vinvl chloride
Xylenes
MD
ND
ND
ND
ND*
ND
*PT = Purge and Trap
DI = Direct Injection
HS = Headspace
ND = < 10 ug/1
ND* = < 20 ug/1
B-23
GCA TECHNOLOGY DIVISION O'3A
-------
Pro icct.
1-623-027
Control No. 41752
DATA RF.P03T SIIKK7C
Purgoables
Sample I.D.
Sscple Matrix Water
Analysis Date ___l/9/8A
Instrument HP 5985 GC/HS Sample Dilution No dilution: PT
Parameter
Chlorine tfcane
Bromcnsethnne
Vinvl chloride
Chlqroethane
Methvlene chloride
Acetone
Carbon disulfide
1, 1-DichLoroethene
1 , i-Dichloroethar.e
Trans-1 ,2-dichloroethsne
Chlorofcra
2-But.ir.or.e
1,1, 1-Trichloroethane
Carbon tetrachloride
Broracdichloromethanc
Total xvler.es
Concentration
(ug/1)
Nn*
NO
NO*
ND
ND**
NO*-
ND
ND
ND
ND •'
! ND
ND
ND
ND
ND
ND
Faraneter
1 , 1^2 ,2-Tetrachloroe5hnne
1 .2-Dichloroprcoane
Trans-1 ,3-Dichloroorooene
Trichlotoethene
Dibromochloronethane
B^n^ene
r. is- 1 . 3-D ich lorop ropene
i 2-Chloroethvl vinyl ether
Bronipform
1 4-MethYl-2-pen.tanone
iTetrachloroe there
Toluene
Chlorobenzene
Ethvlbenzene
Stvrene . _ _
1
Concentration
(ug/1)
ND
ND
ND
ND
NB
ND
ND
ND*
ND
ND*
ND
ND
ND
ND
ND
PT = Purge and Trap
DI = Direct Injection
ND - < 10 ug/1
ND* = < 20 ug/1
ug/1 = ppfa (for density of water = 1)
K 3 Quantitation below detection limit
= Blank contamination observed for this compound.
B-24
.
T-ichnology Civision
-------
Proiect
1-628-037
CtV Control No.
-1732
DATA REPORT SHEET
Qualitative Compounds*
Sa-ple I.D. _ RTC-L-2D
Analysis Date ..__ j-/9/85.
Matrix
Instrument HP, 5985 GC/M3 Sample Dilution No dilution; PT
Parameter
Allvl Alcohol
3i£(chioro:netnYl)eth«;T
Cyclohex-ine_
C'-c lohgxanqne
1.2-Dibrccocthane
Concentration
d.g/1)
NA
ND
ND
N'J
ND
Parameter
Furfural
Isobutyl alcohol
. Het;hvl_acet3te
. Hethvl alcohol
Methyl methacrYlate
Concentration
(yg/1)
ND
NA
ND
NA
ND
N'f)
alcohol
NA
Diethvl ether 1 ND
Ethyl ncstate Ni>
E:hyl acrvlate _ NA ••
1 r.— Protivl b«>nz<>r.e
L Tetrih^drofuran
1 Trichlorofluoronethane .
....'.. 1 1,1.2-Trichloro-
1 1^2,,2-tTif luoroethar.e
_ . i
1 Trif luQToetnsne
ND
ND
ND
ND
ND
*Concentration based on a cocparison of the total ion area of the compound with
that of the internal standard.
NA « Not analyzed by purge and trap
PT * Purge and Trap
DI s Direct Injection
ED = < 10 ug/1
U2/1 = ppb (for density of vater = 1)
B-25
GC-'- CGFPORATICM
Technology Division
-------
1-625-037
GCA Control No.
417S6
DATA REPORT SHEETS
Purgeabl.es
Sample I.D. ___
Sample Matrix Water
Analysis Date ^1/10/35
Instruaent HP 5985 GC/KS Sample Dilution 1:5 PT
Parameter
Chloromethane
Bro:r.onethane
Vinyl chlorida
Chloroethane
Methylene chloride
Acetone
Carbon disulfide
1 , l-Dichloroethene
I, 1-Dichloroethane
Trans-1 ,2-dichloroethene
Chloroform
2- Brit anon e
1,1. 1-Trichlorcethane
Cirbon tetrachloride
Brcnodichlorcme thane
Toc.il xvienes
Concentration
(yg/1)
NO*
NL>
ND*
ND
ND**
ND**
NU
ND
ND -.
ND
ND
ND
ND
ND
ND
ND
Parameter
1 , I ,2 ,2-Tetrachloroethan?
1^2-Dichloropropane
Tranr.-l^G-Dichloroprooene
Tcichlgroethgne
Dibronochlorome thane
Benzono
cis-1 .3-Dichloronrcoer.e
> 2-Chloroethvl vinyl ether
tBrcraofonn
r4-HethYl-2-pon'tanone
Ta t rach loroe thene
i Toluene
tChlorobenzene
Ethvlbenrene
rStvrene^ .- _ T--,._ '
Concentration
(yg/1)
ND
N6
ND
ND
ND
ND
ND
ND*
ND
ND*
i ND
ND
ND
ND
ND
PT » Purge and Trap
DI = Direct Injection
•ND - < 50 ug/1
ND* = < IQQ ug/1
1 » ppb (for density of water = 1)
Quantitation below detection limit
contamination observed for this compound.
B-26
GCA
CCA coF-
Technology Division
-------
Project
1-628-037
CCA Control Ko.
41736
DATA REPORT SHEET
Qualitative Compounds*
Sample I.D. _ SOC-AP-lD
Analysis Date
1/10/85
Sample Matrix Water Instrument HP 5935 GC/MS Saaple Dilution 1:5 PT
Parameter
Allvl Alcohol
Bistchlorocethyllether .
Cvclohexane
Cvc lohexanone
1 , 2-Dibroaoethane
D ichlorgd if luorome thane
Diethyl ecb.er
Eth*/l acetate
Ethyl acrylate _
Concentration
(us/D
NA
ND
Parameter
Furfural
Isobutvl alcohol
ND 1 Methvl acetate
ND
ND
ND
ND
N'D
NA .
Methyl alcohol
Methvl methacrylate
n-Butvl alcohol
n-Prooyl bensene
Te t rah vdro f uran
Trichlorof luoromethane
. 1,1,2-Trichloro-
lJ,2J,2-tTifluoroethane
Trtf luoroethane . . . .
Concentration
(wg/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
^Concentration based en a comparison of the total ion area of the compound with
that of the internal standard.
NA - Not analyzed by purge and trap
PT * Purge and Trap
DI = Direct Injection
ND
< 50 ug/1
ug/1 = ppb (for density cf water - 1)
B-27
GCA
GCA CCFPQfV-TlCN
Technology Division
-------
Project,
1-628-037
CCA Control Mo. 417S6
DATA REPORT SHEET: YSDF
Volatile Organic Compounds
Instrument and Sample Volume*
HP 5985 GC/M3 1:5 FT
Sample Identification.
Analysis Date
SOC-AP-1D
1/10/85
Sample Matrix Water
Finnigan OWA GC/MS_
PE 3920 GC/FID "
HP 5890 GC/FID
Compound
Acetone
Acetonitrile
Allvl Alcohol
Aniline
Benzene
Bis(chloromethvl)ethf;r
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethyl vinvl ether
Chloroform
Chloromethane
C is-l,3-Dichloropropene
Cvclohexane
Cvclohexanone
Dibromochloromethane
1,2-Dibromoethane
Dichlorodif luorome thane
1 . 1-Dichoroethane
1,2-Dichloroethylene
1 . 1-Dichloroethvlene
1 ,2-Dichloropropans
Diethyl ether
Ethyl acetate
Ethyl acrvlate
Ethylene
Concentration
(mg/1)
0.41
ND
ND
ND •
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Compound
Ethylene chloride
Ethylene dibromide
Ethylene dichloride
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl chloride
Methyl ethyl ketone
Methyl isobutyl k«tone
Methyl tnethacrylate
Methylene chloride
n-Butyl alcohol
n-Propyl benzene
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethvlene
Tetrahvdrofuran
To luene
Trans 1.3-Dichloropropene
1.1, 1-Trichlorcethana
Trichloroethylene
Trichlorof luo rone thane
1,1,2-Trichloro-
-1 ,2 ,2-Trif luorotnethane
Tr if luoroe thane
Vinvl chloride
Xylenes
Concentration
(mg/1)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND*
ND
0.35
ND
ND
ND
ND
ND
ND
ND
ND
N'D
ND
ND
ND
ND
ND*
ND
*PT = Purge and Trap
DI = Direct Injection
HS = Headspace
NU = < 0.05 mg/1
ND* = < 0.10 mg/1
B-28
OCA TECHNOLOGY DIVISION
-------
Project 1-62B-037
GCA Control No. 41788
DATA REPORT SHEET
Purgeables
Sample I.D. SOC-SI-1B
Analysis Date 1/9/85
Sample Matrix Aqueous
Instrument HP5985 GC/MS
Sample Dilution 1;5°
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chloromethane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodi ch lor ome thane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
850
1600
ND
ND
ND
ND
ND
ND
ND
ND
ND
2400
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichlor,opropane
Trans-1 , 3-dichloropropylene
Trichloroethylene
Dibroirochlorome thane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methvl-2-pentanone (MIBK)
Tetrachloroethylene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
' ND
ND
ND
ND
2500
ND
ND*
ND
ND*
ND
6300
ND
ND
ND
PT = Purge and Trap
DI = Direct Injection
ug/1 - ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows;
ND = < 500 ug/1
ND* » < 1000 pg/1
K = Quantitation below detection limit
ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
-*^*r -*+l*r tut mm
GCA
GCA
Technology Divisioi
-------
Project 1-628-037
GCA Control No. 41788
Sample I.p. SOC-SI-1B
Sample Matrix Aqueous
DATA REPORT SHEET
Additional Compounds
Instrument HP5985 GC/MS
Analysis Date 1/9/85
Sample Dilution 1;50
V* • f\ • ^ •
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethyl ) ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Di ch lor odif luorome thane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luorome thane
1,1, 2-Trichloro-
• 1^2j2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
MA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND - < 500 ug/1
NA = Not analyzed by Purge and Trap
K = Quantitation below detection limit
GCA
GCA CORPOR-'-' ."J: :
Technology Division
-------
1-G2S-037
CCA Control No.
41794
DATA REPORT SHEETS
Purgeables
Saaple I.C. JOC-Jil-JJD Analysis Date
Saaple Matrix Water Instrument .H? 5985 .GC/MS. Saaple Dilution _1;50_PT_
Parameter
Chloroaiethane
Procomethnne
V;r.yl chloride
Chloroethane
Methvlene chloride
Acetone j
Carbon disulfide
1 , 1-Cichlorosthene
1 , 1-Dichloroethane
Trans- 1^2-dichloroether.p
Chloroform . .
2-3utanone
1,1, 1-Trichloroethane
Carbon tetrachlcride
BrcTucdichiorcme thane
Total xvlenes
Concentration
(ug/1)
NO*
NO
NO*
NO
NO**
ND**
MD
MD
ND
ND •'
ND
ND
I ND
ND
ND
970
Parameter
1 ,1 ,2 ,2-Tetrachlotoethar.e
1 ,2-Dichlorooropane
Trans-1 ,3-DichloroprQuene
Trichloroethene
Dibromochlororoethan^
Benzene
c is-l^S-Dichlgroproegne
2-Chloro
-------
Project
1-628-037
CCA Control No.
4179.!
DATA REPORT SHEET
Qualitative Compounds*
Analysis Date
I.D. SOC-ST-2D
Saxple Matrix Water Instrument HP 5985 GC/MS Sample Dilution 1:5° PT
Parameter
Allvl Alcohol
E is (chlorocethvl) ether
Cvclob^xane
Cyclohexanone
1 . 2-Dibronoethane
Dichlcrodif luorocethar.e
Die-hvl ether
Ethyl acetate
Ethvl acrvlate
Concentration
(ug/1)
NA
ND
NO
ND
ND
ND
N'D
Mi)
Ni ''
Parameter
Furfural
Isobutvl alcohol
Mejhvl acetate
Methyl alcohol
Methyl raethacrylate
n-Bntyl alcohol
L nrPrapyl^b^nzene
Tctrahydrofuran
Trichlorof luorome thane
1,,1,2-Trichloro-
1 ^2^1-trif luoroethnne
Tr if luo roe thane
Concentration
(yg/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
^Concentration based on a comparison of the total ion area of the compound with
that of the internal standard.
NA « Not analyzed by purge and trap
PT » Purge and Trap
DI = Direct Injection
SID - < 500 ug/1
ug/1 - ppb (for density of water = 1)
B-32
GCA
CCA CCRFCnATlCN
Technology Division
-------
Project.
1-628-037
CCA
41794
DATA REPORT SHliliT: T15UK
Volatile Organic Compounds
Sample Identification
Analysis Date
SOC-SI-2D
1/9/85
Instrument and Sample Volume*
HP 5935 GC/MS 1:5Q PT
Sample Matrix Water
Finnigan OWA GC/MS_
PE 3920 GC/FID ~
HP 5890 GC/FID
Compound
Acetone
Acetonitrile
Allvl Alcohol
Aniline
Benzene
Bis(chloromethyl)eth^r
Bromodichloromethane
Bromoform
Bromome thane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethyl vinvl ether
Chloroform
Chloromethane
C is-1 ,3-Dichloropro^enn
Cvclohexane
Cvclohexanone
Dibromochlorome thane
1 ,2-Dibromo ethane
Dichlorodif luorome thane
1 , i-Dichoroethane
1,2-Dichloroethylene
1 , 1-Dichloroethvlene
1,2-Dichloropropane
Diethyl ether
Ethvl acetate
Ethvl acrvlate
Ethylene
Concentration
(mg/1)
1.77
ND
ND
ND
4.33
ND
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Compound
Ethylene chloride
Ethylene dibromide
Ethylene dichloride
Furfural
Isobutyl alcohol
Methvl acetate
Methvl alcohol
Methvl chloride
Methyl ethyl ketona
Methvl isobutyl ketona
Methyl methscrvlate
Methvlene chloride
n-Butvl alcohol
n-Propyl benzene
Styrene
1,1,2.2-Tetrachloroethane
Tetrachloroethylem:
Te t rahyd ro f uran
Toluene
Trans 1,3-DichloroDrooene
1,1. l-Trichlorcathane
Trichloroethvlene
Trichlorof luorotns thane
1,1,2-Trichloro-
-1,2,2-Trif luoroaethane
Trif luo roe thane
Vinvl chloride
Xylenes
Concentration
(mg/1)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND*
ND
0.90
ND
ND
ND
NU
ND
ND
1.47
ND
ND
ND
ND
ND
L ND
ND*
0.97
*PT = Purge and Trap
DI = Direct Injection
HS = Headspace
ND = < 0.50 mg/1
ND* = <• 1.00 mg/1
B-33
GCA TECHNOLOGY DIVISION
-------
Project
1-623-037
CCA Control No. 41796
Sample I.D. .SOC^SI;
DATA KLIOKT SHKETSJ
Purgaables
Analysis Date .i^
Sample Matrix Oil (PEC)Instrument HP 5985 GC/MS Sample Dilution 1:500 PT
Parameter
Chloromethane
Bromcrae thane
Vinyl chloride
Chloroethane
Methvlene chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethene
1, 1-Dichloroethane
Irans-l_12-dichloroethene
Chloroform
2-Butanone
1 , 1 » 1-Trichloroethane
Carbon tetrachloride
Bromodichlorome thane
Total xylenes
Concentration
(vg/1)
ND*
ND
ND*
ND
16300*
*m
ND
ND
ND
ND''
ND
ND
N»
ND
ND
77400
Paraneter
lJlA2,2-T«trachIorcethane
1 . 2-D ich loropropaue
Trans- 1 , 3-Dich loroorotJene
Trichloroethens
Dibromochlorome thane
Ben^enn
cis-1.3-Dichlorocrcpene
2-Chloroethvl vinyl ether
Bromoform
4-Methvl-2-oentanone
Tetrachloroethene
Toluene
Chlorobenzene
Ethylb^nzene
Stvrene
Concantration
(i-g/1)
ND
NT)
ND
ND
ND
7000
ND
ND*
ND
ND*
ND
47300
ND
18000
ND
PT = Purge and Trap
DI = Direct Injection
ND = < 5000 ug/1
ND* = <10000 wg/1
ug/1 = ppb (for density ot water - 1)
K = Ouantitation below detection limit
* = corrected for blank value
B-34
GG
•£& Technology Division
-------
Project
1-628-037
GCA Control No. 41796
DATA REPORT SHEET
Qualitative Compounds*
Sample I.D. JLQCr.SI-3B
Analysis Date 1/15/85
Sample Matrix .Oil (PEG)Instrument ,HP 5985 GC/MS Sample Dilution 1 : 500 PT
Parameter
Allvl^Alcohol^
Bis(chloromethvl)ether
Cyclohexane
Cvdohexanone
1.,2-Dibromo ethane
Dichlorodif luoromethane
Diethyl_ether_
£5hyl_acetate_ _
Ethyl acrylate
Concentration
(ug/1)
ND
ND
ND
NA
ND
ND
ND
ND
NA
Parameter
Furfural
IsobutvJ alcohol „ n „
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Prop'/l benzene.
Tetrahydrofuran
Trichlorof luoromethane
1^1,,2-Tricbloro-
U2,2-trif lugroethane
Trifluoroethane . „ _
Concentration
(ug/D
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
^Concentration based on a comparison of the total ion area of the compound with
that of the internal standard.
NA " Not analyzed.by purge and trap
PT « Purge and Trap
DI » Direct Injection
ND = <5000 ug/1
ug/1 a ppb (for density of water = 1)
B-35
•^^ -^^ *^^*m
GCA
GCA CORPORATION
Technology Division
-------
Project 1-62S-037
GCA Control, Ho. 41SOQ
DATA REPORT SHEET: TSDF
Volatile Organic Compounds
Instrument and Sample Volume*
HP 5985 GC/HS 1:20 PT
Sample Identification
Analysis Date
TI-RP-1B
1/9/85
Sample Matrix
Water
Finnigan OWA GC/MS_
PE 3920 GC/FID
HP 5890 GC/FID
Compound
Acetone
Acetonitrile
Allvl Alcohol
Aniline
Benzene
Bis(chloromethvl)eth*:r
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroeth'vl vinvl ether
Chloroform
Chloromethane
C is-l,3-Dichloropropene
Cvclohexane
Cvclohexanone
Dibroraochloromethane
1,2-Dibromoethane
D ich lorod if luorome thane
1 , 1-Dichoroethane
1,2-Dichloroethvlene
1 , 1-Dichloroethvlene
1,2-Dichloroprooane
Diethvl ether
Echvl acetate
Ethyl acrvlate
Ethvlene
Concentration
(mg/1)
0.63
ND
ND
ND
1.04
ND
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
ND
ND
ND
•ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Compound
Ethvlene chloride
Ethylene dibromide
Ethvlene dichloride
Furfural
Isobutvl alcohol
Methvl acetate
Methvl alcohol
Methvl chloride
Methvl ethyl ketone
Methvl isobutvl ketone
Methvl methacrvlate
Methylene chloride
n-Butvl alcohol
n-Propyi benzene
Styrene
1 , 1 ,2 ,2-Tetrachloroethane
Tetrachloroethvlene
Tetrahvdrofuraa
Toluene
Trans 1.3-Dichlorcprooene
1 ; 1 , 7-Trichloroethane
Trichlcroethvlene
Triclilorof luornmethane
1,1,2-Trichloro-
- 1 , 2 , 2-T-if luoromethane
Tr if iuoroe thane
Vinvl chloride
Xylenes
Concentration
(mg/1)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND*
ND
0.42
ND
ND
ND
ND
ND
ND
0.75
ND
:ID
ND
ND
ND
ND
ND*
0.17
*PT = Pur^e nnti Trap
DI = Direct Injection
HS = Headspace
ND = < 0.20 mg/1
ND* = < 0.40 ng/1
B-36
GCA TECHNOLOGY DIVISION 3-9A
-------
Project
L-628-037
GCA Control No. 41806
DATA REPORT SIIKETS
Purgeables
Sample I.D.
Analysis Date .
Sample Matrix _.Qil fp_rg) Instrument HP,5985 ,GC/HS Sanple Dilution 1:500 PT_
Parameter
Chlorome thane
Bromome thane
Vinyl chloride
Chloroethane
Methvlene chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethene
1 , 1-Dichloroethane
Trans-1 ,2-dichloroethene
Chloroform^
2-Butanone
1,1, 1-Trichloroethane
Carbon tetrachioride
Bromodichlorome thane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
40900*
ND
ND
ND
ND
ND.'
ND
ND
ND
ND
ND
58000
Parameter
1,1,2,2-Tetrachloroethane
1 »2-Dich]oropropane
Trans— 1 ,3— Dichloropropene
Trichloroethene
Dibromochlorome thane
Benzene
cis-liS-Dichloropropene
2-Chloroethvl vinyl ether
Bromoform
4-Methyl-2-pentanone
Tetrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Stvrene
Concentration
(•jg/1)
ND
N&
ND
N7D
ND
6800
ND
ND*
ND
ND*
ND
19000
ND
25000
ND
PT « Purge and Trap
DI » Direct Injection
ND = < 5000 ug/1
ND* = < 10,000^/1
ug/1 = ppfa (for density of water = 1)
K = Quantitation below detection limit
* = corrected for blank value
B-37
GCA
GCA CORPORA ncr.1
Technology Division
-------
Project
1-628-037
GCA Control No.
DATA REPORT SHEET
Qualitative Compounds'*
Sample I.D. TI-SB-ID
Analysis Date 1/15/85
Sample Matrix Oil (PEG! Instrument HP 5985 GC/MS Sample Dilution 1:500 PT
Parameter
Allvl Alcohol
Bis(chloromethyl)ether
Cyclohexane
Cvclohexanone
lJ2-Dibromo§thane
Dichlorodifluoromethane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
NA
ND
ND
NA
ND
ND
ND
ND
NA
"..
Parameter
Furfural
Isobutyl alcphol
Methyl acetate ..
Methyl alcohol
Methyl raethacrylate
n-Butyl alcohol
n-Propyl benzene
^Tetrahydrofuran
Trichlorof luoromethane .
l.l.2-Tr:j.ch}Qro-
l , 2 ,2-trif luoroethane
Trifluoroethane
Concentration
(ug/D
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
^Concentration based on a comparison of the total ion area of the compound with
that of the internal standard. *
NA = Not analyzed by purge and trap
PT = Purge and Trap
DI = Direct Injection
ND = < 5000 ug/1
ug/1 = ppb (for density of water = 1)
B-38
GCA
GCA CORPORATION
Technology Division
-------
APPENDIX C
RADIAN CORPORATION
DATA REPORT FORMS
C-l
-------
in NO: M7M
SAMI'U CONTROL HO: 4210-7
LinillC
OATC
DATE ANALYZED:
fll/22/85
COMPOUND
CONCENTRATION
COMPOUND
CONCENTRATION
ING-C/KL» IKS/LI*
PARAFFINS
r.-3 vac
ISOflUTANE
I!-OUTAN£
M E 0 H E X A N f
?i3-niMETHYLClUTAHC
1S3HEXANE
J-MCTMYLPENTANE
?,4-OIHiTHYLPEHTANE
rYfL3»CKANC
irTHYLCYCLOIIEXANE
N-OC1 AtJE
C6 MKAMC
C7 .UK AM.
C7 »LKAIir
C? AI.KAMT
CT *LKA»/E
C8 ALKANT
I C1 AlKANf
ro CT ALKANE
CIO* ALKANE
C10« »l.K»HE
cio* ALKAIIE
C|0» ALKA'IE
C10« ALKANE
OLEMHS
M-r It.'ENE
O1AL AR3HHICS
nr-mwE
inn AN
TOTAL tULOSfNATfn I'C
TRicHLonorLORonriiurir
HLTHYLENt CHLORIDE
rt'LDROFORH
776.0
II.)
12.0
Ifk
• u
&.:.
4.1
2.4
13.8
9.3
5.7
?.S
6.0
5.0
7.4
13.0
2.5
3.3
4.3
a. A
6.9
2.5
3.0
3.0
*.R
23.5
1630.0
3.0
12.3
13.9
VtRIAPLC RCCOVfY TMROUSH ORYINS .SYSTEM - CONCENTRATIONS
(C) CONCENTRATIONS UERE CALCULATED
USING VALUES OF
6 FOR THE
TOTAL OXYGENATED HC(B)
ItPROriliOL 2.5 0.004
UNIDENTIFIED VOCICI
UNIDENTIFIED VOC 7.4 0.009
UNIDENTIFIED VOC . 9.7 0.012
UNIDENTIFIED VOC 9.2 O.P11
UNIDENTIFIED VOC 6.2 0.007
PARAFFINS 91H.6 1.077
OLEFIHS 33.5 0.027
TOTAL AftGMATlCS 1633.0 1.771
TOTAL HALOGCNATEO HC 13.0 0.09?
TOTAL OXYGENATED HC 2.5 O.OOMBI
UNIDENTIFIED VOC 32.5 0.039
-------
firm in NO: 4i76i
SAMPLE CONTROL NO:
SAMPLE TYPE: LIQUID
DATE SAMPLED:
DATE ANALYZED:
Ol/22/Bb
COMPOUND
CONCENTRATION
CNG-C/HL) IHG/LX
COMPOUND
CONCENTRATION
(NG-C/ML) IMG/LI*
PARAFFINS
C-3 VOC
II-HCXANC
Cf, ALKAVE
ci ALKANE
C10» ALKANE
CIO* ALKANE
OLTFIMS
T-?-HEXENE
TOTAL HALOGENATED HC
TRICHLOROFLOROM^THAHE
METHYLCHE CHLORIDE
IFIED VOC(C>
IINIOENTIFIED VOC
IIHIDENTiriED VOC
PARAFFINS
OLEFIHS
T1TAL MALOGENATED MC
UNIOENT IF ICO VOC
TOTAL NMMC
20.8
4.9
7.6
2.4
3.4
2.0
121.0
20.3
6.7
0.024
0.006
0.009
0.002
0.004
0.002
0.142
0.23HA)
0.047
4.7
9.5
40.7
121.0
6.7
14.2
0.006
0.011
0.048
0.142
0.047
0.017IC)
162.6
0.254
n
i
U)
CA) ARTIFACT COMPOUND - CONCENTRATION NOT USED IN TOTAL NMMC CALCULATIONS.
VAR|A(UF RECOVERY THROUGM ORYPtr. SYSTEM - COSCE fITRA T IONS NOT USED IN TOTAL NMMC CALCULATIONS.
CC» COI4CENTRAT IONS WERE CALCULATED USING VALUES OF 6 FOR THE CAR113N NUMOFR AMI) H6 F "l» THE MOLECULAR WEIGHT.
UNITS ARE EUUIVALfHT TO PPM ASSUMING A DENSITY OF I.
-------
F irin in NO: n«i5
sAtc'ir CONTROL NO: 42in-29
SVILT TYPE: SOLID
DATE SAMPLED:
DATE ANALYZED:
I1/15/B1
01/03/05
m
I)
a
COMPOUND
CONCFUTRAT ION
UIO-C/G) |UG/C)i
COMPOUND
CONCENTRATION
(NG-t/0) IUS/G)«
PARAFFINS
f' £ Q"£ \ A*| £
CYCLOPCUHNE
2«3-f)!.'ir. THYLflllTA'lf
1 SOHFX Aflf
3-M* Tt1YLr'ENT AUF
N-HEXAHE
"F THYLCYCLOPENTANF
CYCLOIKXANE
JSOHEPTMif
3 -ME THYLHE XA'lf
II-HEPT ANE
HFTMYLrYCLOHFXAf.T
?. t'i-O 1 MF. TH YLI'F. X J'lf
2i3»4-TRJMriMYLnEllTAME
3-METHYLHrpTANC
2i2**-V* IMEIMYLI'EXANE
o (1-OCTANE
1 M-N3NANE
*" N-DECA»jF
•l-ijrjOEC* Mr
C7 ALKAME
C? ALKANF.
C7 ALKA'IE
C7 ALKA*'E
Cfl ALKA'.'E
CP ALKANE
CO ALKAME
C» ALKAMF.
Cfl ALKAME
ce ALKAvf
C9 ALKANF
C9 ALKAVF
CQ ALKANE
r.<) ALKAIIC
C9 ALKANE
C" AlKA'lE
C9 ALKAV'E
cio* ALKANE
(A) ART|C»CT COMPOUND
111) VAIIIAOLf HtCOVWY
< C ) C O'lCFNl" AT ITMS WE"
H5.1
26 J.O
2A6.0
79J.9
1273.0
11000. (I
PP30.0
796.0
1320.0
1129.0
4210.0
251C.O
1R70.0
1160.0
5550.0
1310.0
4990.0
17000.0
376P9.0
87* 00.0
513. 0
457.0
995.0
1 67P.Q
456.0
370.9
377.0
PB6 .n
674. P
4020.0
7 7 A A
* 1 1 » 'J
432."
191.3
1550.?
3290.0
4^40.0
!,1f,0.0
2490. 0
?.->ao.n
0.2
0.3
0.3
0.9
1.5
13.2
2.1
0.9
5.2
3.7
5.1
2.9
2.2
1.1
6.6
1.8
5.9
20.2
44.6
101.7
a. 6
0.5
1 .2
2.0
0.5
0.4
0.4
1 .1
0.8
4.B
Oq
• 7
0.5
0.2
l.P
3.9
P. 2
6.5
3.0
3.9
• COMCf NTfvATION NOT IISF" IN TOTAL NHHC
THROUGH OHYING SVSTC" - C3HCtHIP A T IONS
E CALCULATED USIN3 VALUER OF
f. FOR Tilt
PARAFFINS (CONT*0)
C*0« ALKANE
cio* ALKANE
Cl?» ALKANE
CIO* ALKANE
CIO* ALKANE
CIO* ALKANE
CIO* ALKANE
CIO* ALKANE
CIO* ALKANE
CIO* ALKANE
CIO* ALKANE
CIO* ALKANE
CIO* ALKANE
CIO* ALKANE
C»0* ALKANE
CIO* ALKANE
Clfl* AtKANE
CIO* ALKANE
CIO* ALKA«JE
CIO* ALKANE
CIO* ALKANE
CIO* ALKANE
CtO* ALKANE
CIO* ALKANE
CIO* ALKANE
CIO* ALKANE
CIO* ALKANE
CtO* ALKANE
OLEFINS
2i1i1-TRJHE-1-PENTENE
I-HCTHYLCYCLOHEXENE
1-OCTEHF
C-2-OCTENE
A-piunriE
P-.P1HEHE
LIHONENE
C" ALKFME
CALCULATIONS.
NOT USED ttt TOTAL HMHC CALCULATIONS.
CAROON NUHMLIt AND H6 F QR THE HOLECUI.AP UFITMT.
9930.0
20600.0
13300.0
9110.0
10300.0
9270.0
22700.0
36100.0
9960.0
12800.0
1690.0
3340C.O
7050.0
11400.0
2273.0
10500.0
12100.0
226CO.O
13300. P
11800.0
4900.0
5200.0
14ROO.O
54AO.O
74SO.O
14100.0
13000.0
1960.0
959.0
1350.0
1450.0
461.0
2020.0
12400.0
Ifl20d.fl
3300.9
11.8
24.4
5.8
1.2
2.2
1.0
6.9
3.2
1.6
5.2
5.6
36.0
fi.4
1 3.5
2.7
1 ?.5
14.3
26. E
15. fl
14.0
5.6
£.2
17.6
6.5
9.1
16.7
15.4
2.3
1 .1
1.5
1.7
0.5
3.3
14.1
2(1.7
3.9
AT FOlllVAfMT TO PPM A'SIIMIHG A (UN-MTV "F 1.
-------
r i r L n in no: 11 B 15
SA^IUr. CONTPOL HO: 1210-29
SAPIM.F TTPE: SOLIC
DATE SAHPLED:
DATE ANALYZED:
11/15/81
01 /03/P.5
COMPOUND
cq AIKEHE
C9 ALKf'JE
cio« AI.KHJE
cio* AL>T"E
CIO* ALKENE
CIO* ALKENF
CIO* ALKFNE
CIO* ALTNE
TOTAL AROMATIC"!
REII?ENF
TOLUENE
I SOPROPYLHLN?rNr
n
Ul
I «3ib-TR
ISO«UIYLOENZEIIE
P-ISOPROPYLIOI.U'~r'E
I NO* 'I
inortiE
II-BUTYLSFNZEWE
P-OIEIHYLPEMZEUE
CIO* AROHAIJC
CIO* APOHAT1C
CIO* AROMATIC
T1TAL MALOrirfJ»Trn HC
CHLOPOHf TH«nr
MEIHYLEK'E CHLORITE
1 <1 ,1-TRKHLOFOETHA'ir
UriIOENTIFlEO HAI 03CNATED
CONCENTRATION
(NT.-C/G) (UG/G>»
HC
5920.0
7110.0
13700.0
11303.0
13100.0
5070.0
1 •'000.0
5?10.0
1980.0
1360.0
J320.0
12AO.O
"\MO.O
510Q.O
I2noo.o
1630.0
3R30.0
592 l.d
6739.0
2«600.0
11ROO.O
11000.0
11800. 0
l?000.0
1250. 0
269.0
flit .0
215.0
143.0
6.9
8.3
16.0
16.7
15.3
5.9
19.9
6.5
2.1
1 .5
3.7
1 .8
".2
6.1
11.2
5.2
1.3
6.5
7.2
32.0
13.2
12.3
16.6
13.1
5.3
0.7
5.1
1 .1
O.S
COMPOUND
TOTAL OXYUNATEt) HC CONCFHTRA!MMS WERE CALCULATED USING VALUES Of 6 FOR THE CARB3U NUMnER AND H6 FOR THE MOLECULAR UEIfiHT.
« UNITS ART roi/IV«lE*JT TT PP" AS^UMIK", A DENSITY OF I.
-------
rinn in no: «ii7J
SAMPLE CONTROL NO: 4219-M
SAMPLE ivpt: Linuin
PAIE SAMPLED:
DATE ANALYZED:
oi/22/»i
COMPOUND
nut M»L?'»tN»irn HC
1EIMYUNC CHLORint
CARIIOM TflRACHLOP IDE
CONCIN1RAIION
ING-C/HI.) IM1/L)'
3H.2 0.439IAI
6.4 0.045
2.0 0.026
COMPOUND
CQNCCNTRM ION
INO-C/PLI IHS/ll*
T3TAL
I3TAL
MC
a.*
0.071
0.071
n
|At ARTIFACT COHPOIlNn - CONCENTRATION NOT USED IN TOTAL NHIT CALCULATIOMS.
Ill) VADIAniE RECOVERY TI'ROIISH ORYINS SYSTEM - CONCENTRATIONS NQt USED IN TOTAL NHHC CAl CUL ATIONS.
10 COUCENTPATIONS JERE CALCULATED USIN5 VALUES OF t FOR THE CARB3N NUMBER AND 86 MR THE MOLECULAR
• UNITS ARE EQUIVALENT TO PPH ASSUMING A DENSITY OF I.
-------
FIELD I" N": 41775 0»TE SAMPLED: II/I6/P4
SAMI'LE CON1ROL NOt 4213-13 DATE ANALYZED: 31/22/BO
SAMPLE TYPE: nouin
_—
CONCENTRATION CONCCNTRAT ) ON
C3HPOUHP • N'S-C/l'l) (HG/L)' CQHPOU'IO (N5-C/ML) IK3/LI*
ca
PARAFFINS
•|-U!JDCC»NC 31.1 0.040
tOlU AROHAIIC*
Ii?i4-TH|HfTHYLnCN7rNC 14.6 0.016
T1TM. UALnSCNAiro MC
in iriiLOnorLOBOHflHANr 16.0 0.205(A»
MftllYLClIC CHLORIDC 4.0 0.028
CARBON Tin ACMLGP IPE 2.0 0.026
IINIDCMI IF ICO VOCIC)
IMHOEUTI PI ED V3C 3.5 0.004
n UNinCN'IFICD VOC 32.9 0.039
I
*-l ntmrFIN'. 34.1 0.040
ITUL AROHATICS 14.6 0.01A
T3I4L MALOSCNAICn DC 6.0 0.054
IFIED VOC 36.4 0.043IC)
TOTAL NMHC
91.1
0.1S4
ARTIFACT COMPOlllin - COMC EN1 o AT I ON NOT USED IN TOTAL NMHC CALCULATIONS.
ll!» VARIAIILC RffOVERY T»'ROU5M DRYING SYSTEM - CONCENTRATIONS HOT USED I •• TOTAL MHMC CALCULATIONS.
1C) CONCCNIRATIONS WERE CALCULATED USINS VALUES OF 6 FOR THE CARBON NUMBER AMD Ob FOR THE HOLECtlLAR UFIGHT.
• UNITS ART rOUIVALFMT TO PPH ASSUMING A DENSITY OF 1 .
-------
FIELD ID in: MT79 DATE SAMPLED: I I/If/M
SAMPLE CONIROL NO: «2IO-15 DATE ANALYZED! 01/22/H5
SAMPLE TYPE.* LIOIMO N
CONCCNTRATIOri CONCCNIPAT I ON
COMPOUND INP-C/PLI IMS/LI* COHPOUHD (H5-C/ML) IHG/LJ*
il .
ea
2.1 0.002 JP
C6 ALKAHT 2.2 0.003 Ma
C7 ALKANE 69.3 O.J83
rn ALKANE 1.2 o.ooi
ILTF INS
•>-«rTIIYL-2-BUTrNE 17.8 0.017
MAL HAL13ENATED HC
TRICHLOROFLOROHCTHANC 9.8 O.I1KAJ
M:IMYLENE CHLORIDE 11.6 o.os6
vocio
vac 1.7 0.002
n
CO
PARAFFINS
OLEFIHS
T5TAL HALOSENATEO HC
UrjIDENl IF1ED VOC
TOTAL NMMT
17.R
13. b
1.7
107.9
O.OP9
0.017
0.096
0.302ICI
0.205
«» APT |r ACT COMPOUND - COMCCNTP AT I ON NAT ((SCO IN TOTAL NHHC CALCULATIONS.
CPI VARIADLf RLCOVERV IMRnilCM DRYISH SYSTEM - CONCENTRATIONS NOT USED IK TOTAL NHHC CALCULATIONS.
(Cl COIICENTRAUONS WERE CALCULAIEO USINS VALUES OF £ FOR THE CARBON NUMBER AND fib FOR THE MOLECULAR
UNITS ARE EQUIVALENT TO PPH ASSUHIN3 A DENSITY OF 1.
-------
10 NO: «iTfi
•SAHPLE CONTROL NQ: 4210-17
s*HPtr TYPE: tiouir
PATE SAMPLED: ii/is/e4
DATE ANALYZED: 02/22/85
COMPOUND
PARAFFINS
N-PF.NT ANC
N-HE«ANC
2,-S-OINETHYLHEXAHE
>t2i«-Tn IHETHYLHEXANE
CI ALKANE
C" ALKAIJf
ci ALKANE
C9 ALKAI/E
D0« ALKANE
3LCFINS
^;;;NERIMC"~PC"Tr"F
T1TAL AR3HAT1CS
9 TOLUFNf.
T3TAL HALOSCMATEO HC
TRlCHLOROFLOROHETHANr
HfTMYLENE CHLORIDE
TOTAL OXYGENATED HC»f)
ACFTOur
ISOnuTYRALDL'HYDr.
ilUTAriONT
OLCF INS
TTTAL AROKATICS
T.1TAL HALO^CNATEO MC
(At ARTIFACT COMPOUND - COKCTNTPAT
(Rl VAStACLT RtCOVcPY THROUGH D»YI
«C> CONrFNT'ATIONS VERC CALCULATED
CONCENTtATION CONCENTRATION
• NG-C/ML1 (Hli/LI* CONPUUNO (NC-C/HLI (HG/LI*
134A.O
121.0
357.0
27.4
20.5
11.4
10.2
171 .n
23.0
33.6
20.2
19.7
454.0
71. H
67.2
37. R
4.5
B35.0
16.7
52.5
44. A
2124. I
39.0
525. f
42.3
TOTAL OXYGENATED HC 948.5 l.SlSIb)
1.612 TOTAL NHHC 2732.1 3.458
0.146
0.427
0.033
O.C27
0.013
0.012
0.203
0.027-
0.011
0.040
0.024
0.022
0.49B
O.OPO
0.267
0.314
1.346
0.024
O.U79
O.OA7
2.S52
O.d46
C.578
0.2H2 |
ION NOT USTO IN TOTAL NHHC CALCULATIONS.
'IG SYSTE1 - CONCENTRATIONS IIDT USED }f TOTAL NHHC CALCULATIONS.
USINS VALUfS 'JF 6. FOR THE CARRTN NUHOfR AND R6 FOR THE MOLECULAR UEK.HT.
2
• UNITS ARE EOUIVALE'lT TO PPM ASSUMI»|j A CENf-ITY PF 1.
-------
0
FJfLO 10 NO: 4J7P9
CON1NOL NC: 42IO-1<»
TYPE: LIOUIC
DATE SAMPLED:
DATE ANALYZED:
11/15/84
01/22/RS
OHPOUNO
CONCENTRATION
IN>>-C/ML) IHG/L><
COMPOUND
CONCENTRATION
ING-C/HL) IHG/L)'
P.R*rFIN,
TTMANE
1 SOPfNT A>.f
UEJHLXA'il.
IS1HMANC
•"j-HfvUIL
HrTHYLCYCL3PfNTAK'E
2|4-D1HLTMYLPENTANE
CYCLOHEXAME
"-•1ETHYLHCXANE
'(-HCPTAHf
*UHYLCYCLOHEXANE
S-MfTHYLITPTANE
2»2t'»-TniMETHYLHEXANr
•1-OCTAHE
M-UQ'JANr.
'(-DECAHE
•I-UNOECAME
C6 ALKANf
C7 ALKAUr
C" ALKAMf
C<> ALKANt
C1* ALKAME
CIO* ALKANE
CIO* ALKAME
CIO* ALKAIir
Cll* ALKANE
CIC. ALK»-:r
Clfl* ALKAMf
CIO» ALKAME
TOTAL AROMATICS
ut'i?riif
I ILUCNC
rTHYLllt»l?E».C
(A) IRflFACT COMPOUND - COKCTNTRAT I Oh
mt vANiAnir nf.ctvr.fi THHOUGH DFYIMT
ICI CT ffHIlM JO'IS V'iRT CALCULA1EO US
41.1
2100.0
1B4 . 0
41.0
252 . C
1270. C
1270.6
70.1
45. B
24.7
38.6
70. P
26.9
40.4
33.7
27.4
56.3
26.5
3407.5
251.5
*66.1
43.4
61 .9
127.3
77.3
40.5
212.7
36.2
62.4
•56.9
1575.7
I'll A. 3
200. h
833. ft
.
0.060
2.527
0.220
0.049
0\i.*
• J U C
1.520
1.4R6
O.OH4
0.054
On • t
• U 3 1
0.025
0.046
O.OR3
0.032
0.054
0.040
0.033
O.U67
0.031
4.0*0
0.300
0.435
0.052
O.C74
.151
.092
.b4f>
.252
.043
.698
.367
1.709
2.103
0.722
0.9?2
NOT USED I 'I TOTAL NMI'C
SVSTC" - C3NCENTKATIONS
INI VALUES OF * FOR THE
TOTAL HALOGCNATEO HC
HETHYLENE CHLORIDE 68.3
1«1«1-TPICHLOROETHANE 19.2
TOTAL OXYGENATED HCI8»
ACETONE 3410.0
ISODUTYRALOEHYDt 396.0
UNIDENTIFIED vocio
UNIOCNTIFItO VOC 381. R
UNIDENTIFIED VOC 157.0
PARAFFINS 10429.0
TOTAL AROHATICS 4527.9
TOTAL HAL06ENATED HC XT. A
TOTAL OXYGENATED HC 3806.0
UNIDENTIFIED VOC 1138.8
TOTAL NMHC 161A3.2
.
•
CALCULATIONS.
NOT USED IN TOTAL NHHC CALCULATIONS.
C>RBON NUMBER AND «6 FOP THE MOLECULAR UEIGHT.
0.4B3
0.107
5.503
0.595
0.456
0.904
12.453
4.956
0.590
6.098(0)
1 .360ICI
19.360
z
• UNITS ARE EQUIVALENT TO PPM AS'-UHlN'. A DENSITY OF 1.
-------
FIELD 10 N"! 41TS2
SAMPLE CPNI19L fit: 421
SAMPLE TYPF: LIOUIO
c IMPOUND
PA,*FC,,,<
c-2 vnc
CVCLOPF'ITANC
J-MfTHYLPENTANC
CYCLOHCXAHE
ISOMEPUNE
rO-QIPrTMYLPENYANF
MCTHYLCYCLOHEvA^f
\.t{ THYLHEPIANE
?.2,?-TP|ir.THYLHf-»ANt
N-1CTAN1:
•J-fJ1i'll4t
M-OECANf.
H-UNDECU'E
C6 ALKA'lE
C6 ALKA'lf
C6 ALKA'JE
Cl ALKANE
C7 ALKA«E
1 C7 ALKAIIf
M C7 ALKA'Jf
C* ALKA'IT
CA ALKA'lE
C« *LKAUE
Cft ALKAMf
C" AlKA'lE
C-» ALKAHf
C *J A I, K A'*f
CO ALKA'IC
C9 ALKANL
CO ^ A L K A *J f
C-» »LKA'-r
CO 4LKA-IE
C'» ALKANT
C"> ALKAML
ci ALKANC
C9 ALKA'T
C1* ALKAHf
0-21-A
CONCfN]RATION
IN'i-C/MI.) • (HG/LI*
59.6 0.070
•540.6 9.978
53.2 • 0.064
245.9 0.2M
212.3 0.2!>3
425.1 0.507
M8.0 0.606
101.1 0.120
. 40.7 0.054
57.4 0.06A
3495.0 2.964
87.0 0.103
89.3 0.106
30.5 0.037
92.3 0.111
52. 5 0.063
984.3 1.174
1122.2 1.339
429.7 0.513
02.1 0.098
168. f 0.201
54.4 0.065
60. » 0.072
52.9 0.063
1195.0 1.420
202.4 0.240
* q Q 7 ni&QA
^»*«' U • n 7 1
814.? 0.967
1246.5 I. 491
237.7 0.282
237.7 0.2*2
f 4 n A n a A A
f ^ •! • ^ u • r p u
734.1 0.873
509.6 0.712
475.4 O.StS
73C.*> 0.660
7*1 n AQfiA
lit 1 » J Ut^Ull
49fl.l 0.592
2*>4.(, 0.349
II) APTKAC1 COKPOUND > CP» CLNTP AT 1 Cl. NOT USfH IN TOTAL 'HMMC
(III VAPIAOLC RtrOVfaV IHROUOH OfiYlwc SYSIEM - f JNCt •JfO A T IONS
1C) CO'JCf NTS AT IONS «C«E CALr.ULATEO
US INC VALUES 3F 6 FOP THL
DATE SAMPLED:
DATE ANALYZED:
11/15/84
01/29/05
CONCCNTRATION
COMPOUND
PARAFFINS ICONT'O)
CIO* ALKANC
CIO* ALKANC
CIO* ALKANC
CIO* ALKANC
CIO* ALKANC
CIO* ALKANC
CIO* ALKANC
CIO* ALKANC
CIO* ALKANC
CIO* ALKANC
CIO* ALKANC
CIO* ALKANC
CIO* ALKANC
CIO* ALKANC
CIO* ALKANC
CIO* ALKANC
CIO* ALKANC
CIO* ALKANC
CIO* ALKANC
CIO* ALKANC
CIO* ALKANE
CIO* ALKANC
CIO* ALKANC
CIO* ALKANE •
OLEFINS
1-DCCCNC
ItUNDCCFNC
TOTAL AROMATICS
OENZEWE
TOLUENE
TOTAL HALOCCNATCO HC
HCTHYLEN^ CHLORIOC.
OIBRQHQCHLOROHCTHANC
CALCULATIONS.
NOT US£0 IN T)TAL NHHC CALCULATIONS.
CAPBON NUHPEH AND fb FOR THE MOLECULAR WEIGHT.
INO-C/HL)
853.9
115.7
249.6
212.4
220.8
135.9
558.9
25.6
94.0
34.2
93.7
53.4
38.4
95.3
32.6
32.2
77.7
120.8
161.9
42.2
43.8
201.9
70.4
59.2
413.0
• 192.8
7(17.6
52'. 3
6.9
9.9
IHO/D*
1.015
0.137
0.296
0.252
0.262
0.161
0.663
0.030
0.064
0.041
G.099
0.063
0.046
0.113
O.P39
0.038
0.092
0.143
0.192
O.C50
0.052
0.239
0.063
0.070
0.4C3
0.225
O.F54
0.578
O.P4C
0.172
n
&
0
5
z
UNITS ARE EQUIVALENT TO PPM ASSUMING A PfMSlTY OF 1.
-------
riCLU 10 H*: 41792
CONIROL no: 42io-2i-A
TYPE; i inuii;
OATC
OATL
SAMPLED:
M/I3//I4
01/Z9/85
13TAL HAI. li
UNIOCNi
UK MCIH IK ico HAir>3F.«j*Tii>
HC «CO«I'0»
HC
o
I
in i uc HI I HID voc ic t
voc
rtro voc
; ir.o voc
I'MHE'lTIf IFO VOC
into voc
voc
uNinKNiirirn voc
'IF)£0 VOC
vac
iif.'loruTirifO VOC
voc
iuro voc
iro vor
OLEM»'S
111*1
UI*t H»fi3tN»TCn HC
T"f»L OKYTNAirO HC
n'iinr»'T tr no voc
19.S
04.2
IMS/LI*
COMPOUND
CnMCENTRATlON
INO-C/ML) IHS/L1*
0.032
P. 264
0.3S7
.me. 2
212ft. f.
5987.4
M 06 . .Y
5IB..1
58.1
154.1
1.7
1266.2
201.4
464.3
I?J7.0
S06.1
J«PS6.ft
f.05.B
1314.1
1JO.S
231.1
1737».2
4.«iil
. 2*540
7.146
!.*AO
0.300
O.Uf.9
0.1 114
O.OU9
1.515
0.336
O.S'S
1.47A
0.366
34.161
0.70ft
1.432
0.514
O.J!U(D>
20.7S7ID
4"306.4
'*i Aiiif»cr cjMPounp - courttdPAiioi.1 NCI uscn IN IOTAL NHHC CALCOLAIIONS.
("i vAciAnir Hrrovfy T>
-------
FICLO in N.I: 41712
SAMPLE CONTROL NT! 421Q-21-B
SAMPLE TYPE: tiouic
DATE SAHPLCD:
OATC ANALYZED!
it/is/64
01/29/65
COMOOIIND
CONCENTRATION
(NG-C/HLt* IMG/LI*
COMPOUND
CONCENTRATION
ING-C/HL) (HC/L)>
PARAFMNS
c-2 vac
CYCLOnFNTANE
?.4-OIH£THYLPENT«NE
?. ,3-niTTHYLPENTANt
2t2.«-l»|H£!HYLr'CNtANE
NfTMYLCYCLOHEXA'lF
2.5-OMETHYLHEXANr
7i3,4-TRIHETHYLPENTAHE
J-MCTHYLHEPTA'lE
2i2t5-T'MHETHYLHE*AME
'1-QECANr
«J-UNDEC»NE
Ch ALKANf
C6 ALKANE
C& iLKANf
CT ALKANE
CT HKANC
CT »LKANE
r.r ALKA'ir
CT ALKA'JE
CT ALKA'IT
CT ALKA»,r
CT ALKANf.
r.« iLKAur
Cl> ALKAMf
CC Al.KA»IC
fn Ai^k*ir
C " AUK A JL
C* ALXAMT
C« »LK*«Jf
C» ALKANt
C« ALKA'IC
l*tt AlVAtJf"
1. fl • U R A * i
C« ALKAMf
C1 >LKAUt
CM ALKA'lf
C" UKANC
C9 ALK A'|T
C9 ALKA'ir
C1* AlKAHf
186.9
9602.0
83.9
126.9
T?,9
173.1
93.9
28.4
1TC..T
36.9
42.2
T90.4
. 55. 4
83.0
S6.3
131.2
186.3
513.4
1068.0
158.2
21T.7
77.0
125.9
111.)
323.5
196.9
• 9 X T
23 . f
21.1
20.8
121.1
47. ^
9 A 7
* n • r
196.6
3545.0
710.0
205.1
9 \1 *\
f 3 t • 3
3T.7
216. H
0.219
11.218
0.100
0.151
0.087
0.202
0.064
0.034
0.210
0.049
0.050
0.889
0.066
0.099
0.06T
0.157
0.222
0.612
1.2T4
0.1P9
0.260
0.093
0.1 Ml
0.132
0.365
0.234
'A A 9 ll
0 • U f O
0.026
0.025
0.144
O.J56
0/11*
• IIJ *
0.234
4.211
0.249
0.244
09 A 9
• c r c
0.945
0.25B
(A) ARTITAC1 COMPOUND - CO'lCf KTh A 11 ON NOT US(D IN TOTAL NMHC
IB) VARIAULf RtCnvrPY THROUGH PRYING SYSTEM - CONCENTRATIONS
CC» CO'ICCNTRAT IONS WERl
CALCIILAUn USING VALUES OF
6 FOR THE
PARAFFINS (CONT'OI
CIO* ALKANE
CIO* ALKANE
CIO* ALKANE
CIO* ALKANE
CIO* ALKANE
CIO* ALKANE
CIO* ALKANE •
CIO* ALKANE
CIO* ALKANE
CIO* AtKANL
CIO* ALKANE
CIO* ALKANE
CIO* ALKANE
CIO* ALKANE
CIO* ALKANE
CIO* ALKANE
CIO* ALKANE
CIO* ALKANE
CIO* ALKANC
CIO* ALKANE
CIO* ALKANE
CIO* ALKANE
CIO* ALKANE
CIO* ALKANE
OLEF1NS
T-.4-HETMYL-2-PENTENE
. 1-UNOECENC
TOTAL AROHATICS
BENZENE
TOLUENE
TOTAL HALOGENATtO HC
01BROHOCHLOROHETHANE
UNIDENTIFIED HALOSENATED HC
CALCULATIONS.
NOT USED IN TOTAL NHHC CALCULATIONS.
CARBON NUMBER AND P6 FOR THE MOLECULAR WEIGHT.
23.7
*4.3
32.6
259.3
61.0
29.9
59.1
195.6
210.4
54.6
117.7
197.5
69.9
63.8
63.9
198.7
262.0
63.3
252.6
2274.0
26*. 8
389.4
179.4
386.6
355.3
S4| .9
2fB.1
761.0
12.3
73.9
0.028
0.100
O.P39
0.307
O.OT2
0.035
O.OTO
0.2J2
0.249
0.065
0.134
0.187
0.063
0.076
0.099
0.236
0.311
0.075
0.300
2.699
0.319
0.462
0.213
0.461
0.416
0.633
0.313
O.B34
0.714
0.232
UNITS ARE EQUIVALENT TO PPM A
-------
rtcio 10 NO: 1179;
5AMPLE CONMOL NC! 42I1-2I-B
SAMPLE TVPEt LIQUID
OATC SAHPLEO:
DATE ANALYSED!
I1/I5/B4
01/29/85
8
o
I
COMPOUND
HALPOFNATfn HC (COUT'DI
UNIDENTIFIED HALORtNATEO HC
TOTAL OXYGENATED HCIBI
I-PROPAHOL
I -UUTAN3L
VOC«CI
IINIDIMTI TIED VOC
IINIilfNT If UD VOC
IINIOCMI IF1EO VOC
UNIDCNTin CO VOC
UNIDENTIFIED VOC
UNIOCflTIFICO VOC
iiNior^TiriEO vnc
UNI DLST iriCO VOC
UNinCNTIFIED VOC
UMinCNTlHEO VOC
IINintNTlFlEO VOC
UNtOfNIIFICO VOC
UMIOtNl 1FIEO VOC
IIN|i)rNUf IEO VOC
UNIOINTIFIED VOC
OLEFI»'S
TOTAL A«nM«HCS
TOTAL HAL^GENATEO HC
T.1TAL 3»YtCN»Un HC
ico voc
CUHCtNJRATION
OIR-C/MLI (HG/L1*
34.1
COMPOUND
CONCENTRATION
(N6-C/HLI (HC/LI<
0.110
4324.0
767.7
29. B
31.7
49.9
3005.0
2165.0
1I1S.O
2193.0
578.3
3H1.9
954.1
508.0
20. a
237.8
311.)
182.0
503. b
2S32B.6
817,2
1C49.5
121.3
3121. 5
12238.4
7.219
1.185
0.041
0.038
0.060
3.589
2.566
1.332
2.619
0.691
0.456
1.140
0.601
0.029
0.2R4
0.372
0.218
0.601
29.102
1.049
1.147
0.5*6
e.44SIBI
14.618(0
T1TAL
39635.0 47.272
IAI ARTIFACT COMPOUND - CONCfNT»AT I ON NUT USED IN TOTAL NHHC CALCULATIONS.
(Ill VAIHABLT RtCOVfBY IHRPUSh ORYlNC SYSTE^ - CO'ICCNTH AT IONS NOT USfO IN TOTAL NHHC CALCULATIONS.
in co:irr.NTRATions UERC CAICULAIEO USINU VALUED or t- ron THL CARIIJN NUHPER ANO «t FOA THE HOLECULAD WEIGHT,
• UNITS ARE EQUIVALENT I1) PPM ASSI't-INf. A PENS IT Y OF I.
-------
n
i
FIELD in NO: 41*01
SAMPLE CONTROL *ic: *2io-25
SAMPLE TYPCt LIOU1P
DATC. SAMPLED:
DATE ANALYZED:
tl/H/8*
01/29/85
COMPOUND
COhCLHJRATIO'l
CNf-C/HLI ING/LI*
COMPOUND
CONCENTRATION
(NG-C/Mll IHG/LI*
PARAFFINS
C-J VOC
CYCLOPENTANE
^-HfTMYLPFNTAME
il-HEYANE
2l4-DlltrYHVL'tENTANE
1 ^ftWTP T A UF
l*>ur*L> ' • I4b
9f J-OIMCTMYfCNf ANE
^--KTHYLMEXiNE
"ETNYLCYrLOHr.XANE
J-METHYIHTPTANE
?|2»«-TR|METHYLHEXANC
U-OCTANE
N_ u n u ft ur
— N j N * " r.
iJ-UNDCCAUF
CT ALKANE
CT ALKA'ir
fT ALKA'Jf
c» ALKANr
C« ALKAMF
C* ALKANF
C* ALKANC
P • A 1 K A IT
l> n *L^*I
CA ALKt*fl
_*• A
.9^0
.05R
.547
.925
.967
A 3 T
• * • *
.404
.353
748.7 O.AB9
287.4 0.341
105. k 0.125
47.7 0.057
240. fi 0.261,
234. q 0.276
(A) ARTIFACT C3CPOIIIIO - CONCT.NTRA1 1 0>. NOT IISfD IN TOTAL NHHC
ID) VARIABLE "£COVtPY THHOUSH ORYINC SYSTEl - C3NCLKTR AT IONS
(Cl CONfEHTRATlON^ UERE CAlfULMEtj
USIN5 VALUES OF 6 FOR THE
PARAFFINS ICONT'OI
CIO* ALKANE
CIO* ALKANE
C14« ALKANE
OLCFINS
PROPYNE
Tt4-«ETHYL-2-PENTENE
1-.OECENE
1-UNOECENC
TOTAL AROMATICS
BENZENE
TOLUENE
ETHYLBENZENE
P-XVLENr/H-XVLENE
STYRENE
NtPROPYLBENZENC
TOTAL HALOGCNATEO HC
01 BROHOCHLOROME THANE
TOTAL OXYGENATED HCIBI
1-PROPANOL
1-BUTANOL
UNIDENTIFIED VOCICI
UNIDENTIFIED VOC
UNIDENTIFIED VOC
UNIDENTIFIED VOC
UNIDENTIFIED VOC
UNIDENTIFIED V?C
UNIDENTIFIED VOC
UNIDENTIFIED VOC
UNIDENTIFIED VOC
CALCULATIONS.
NOT USED IN TOTAL NHHC CALCULATIONS.
CARBON NUMBER AND fl6 FOR THE MOLECULAR WEIGHT.
104.9
195.7
94.2
295.7
355.3
120. S
82.4
697.9
317.4
1878.5
436.7
672.8
195.3
7.2
238.3
60R.6
390.4
TO.O
3860.0
1725.0
2419.0
1117.0
792.2
520.2
0.124
0.230
0.116
• .269
0.416
0.141
0.096
0.757
0.348
2.078
0.483
0.730
0.217
0.125
0.398
0.940
0.466
0.084
4.611
2.060
2.PR9
1.334
0.946
0.621
12
'I
2
• UNITS AHF EQUIVALENT TO PPM ASSUMIN3 A DENSITY OF 1.
-------
FIELD ID NO: u*oi
SAwptt CONTROL Not 4210-25
SAMPLE TYPC: LinillO
DATE SAMPLED:
DATC ANALYZED!
U/14/B4
Ol'29/aS
C9MOOUNO
CONCENTRATION
(Ut-C/MLI
-------
APPENDIX D
ANALYTICAL PROCEDURES
D-l
-------
ANALYTICAL PROCEDURES
GCA CORPORATION ANALYTICAL PROCEDURE
GC/FID Screening of Aqueous Samples
All of the aqueous samples were screened on an HP 5890 GC/FID to determine
the appropriate dilution factor for subsequent GC/MS analysis. One ul sample
aliquots were injected directly into the GC/FID using the conditions described
in the QA Project Plan with the temperature program proceeding to 230°C and
the Helium flow rate at about 30 ml/oxin. The thirty-seven organic compounds
which were screened by GC/FID are shown in Table D-l. The detection limits
for these compounds ranged from 1 mg/1 to 200 mg/1 owing to the variable
response of the flame ionization detector to these compounds.
Due to the large number of organic compounds screened by GC/FID, sample
analyses were conducted over several days. Subsets of the total number of
compounds were quantified on each day. Analyses were conducted on January 24
and 28, 1985 and February 1, 4, 13, 14, and 15, 1985.
GS/MS,Analvsi3
Following the GC/FID screening, aqueous samples were analyzed using the
purge and trap method (5030 of SW-846) for introducing the sample, or an
appropriately diluted sample, into the GC/MS.
Oil samples were dispersed in polyethylene glycol as described in
Section 7.0 of the QA Project Plan. The dispersed samples were then analyzed
by purge and trap GC/MS.
A 1000 ul headspace sample was withdrawn through the septum of each soil
core and then injected directly into the GC/MS.
All compounds were identified by GC/MS using the conditions described in
the QA Project Plan. GC/MS tuning and calibration checks were performed as
described in the QA Project Plan. Qualitative identification of priority
pollutants was performed using the retention time and spectral matches to
D-2
-------
standards. Quantitative analysis was performed using an internal standard
method of quantitation and a three point calibration curve as described in the
QA Project Plan. These values are reported on the Data Report Sheets
entitled: Purgeables. Additional compounds were identified employing a
forward search of the NBS mass spectral library. Component concentrations for
additional compounds were calculated relative to the closest eluting internal
standard. These values, entered on Data Report Sheets entitled: Qualitative
Compounds, represent approximations due to inherent variabilities in component
response factors in the absence of reference materials.
All data reported are blank corrected using the protocols described in the
QA Project Plan. Detection limits are indicated on each Data Report Sheet.
The GC/FID data for the samples reflect the ability to screen for alcohols
and ethyl aerylate. These compounds are not amenable to purge and trap GC/MS
analysis. Ethylene, aniline and acetonitrile were not included on the list of
targeted compounds.
An estimation of the concentration levels of unidentified volatile organic
constituents was made for each sample. This value was attained by comparison
of the total ion response for the entire sample GC/MS run to the response of
one internal standard. The achieved concentration was then corrected for
blank levels, levels of surrogate and internal standards added to the sample
prior to analysis, and levels of components found in the samples. Results of
this estimation are presented in the attached data summary tables.
In spite of the clean-up procedures applied prior to the use of PEG, some
low level contamination of acetone and methylene chloride were noted. Sample
results were not corrected for this contamination in order to allow the user
to evaluate the blank data.
RADIAN CORPORATION ANALYTICAL PROCEDURE
Radian Corporation employs a gas chromatography/multiple detection (GC/MD)
method which uses three detection systems operated simultaneously. These are
as follows: a flame ionization detector (FID) to detect and quantitate
hydrocarbons, a photoionization detector (PID) to generate toluene -
normalized response factors, and a Hall electrolytic conductivity detector
(HECD) in the halogen mode to provide quantitation and identification of
halogenated compounds. Detailed descriptions of the analytical procedures
required by this method are provided in Radian Corporation's September 23,
1984 document entitled "Protocols For Sampling And Analysis Of Surface
Impoundments And Landtreatment/Disposal Sites For VOCs."
D-3
-------
TABLE D-l. ORGANIC COMPOUNDS SCREENED BY GC/FID ON SAMPLES COLLECTED
Compound
1. Methanol*
2. Methylene chloride
3. Acetone
4. Trichlorofluoromethane
5. 1, 1-Dichloroe thane
6. Allyl alcohol*
7. 1, 1-Dichloroe thane
8. Trans-l,2-dichloroethene
9. Ethyl ether*
10. Chloroform *
11. 2-Butanone
12. 1,2-Dichloroethane
13. Isobutanol*
14. 1,1,1-Trichloroethane
15. Carbon tetrachloride
16. Dichlorobromomethane •
17. 1-Butanol*
18. 1,2-dichloropropane
19. Cis-l,3-dichloropropene
20. Trichloroethene
21. Benzene
Relative Retention
Time to Benzene
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
079
317
342
426
466
512
551
592
612
637
678
684
764
767
790
838
859
922
942
974
00
(continued)
D-4
-------
"TABLE D-l. (continued)
Relative Retention
Compound Time to Benzene
22. Trans-l,3-dichloropropene 1.03
23. 1,1,2-Trichloroethane 1.03
24. Dibromochloromethane 1.03
25. Hexane* 1.10
26. Ethyl aerylate* 1.14
27. Bromoform 1.21
28. 2-Hexanone 1.24
29. 4-Methyl-2-pentanone 1.34
30. 1,1,2,2-Tetrachloroethane 1.37
31. Toluene 1.45
32. Chlorobenzene 1.53
33. Ethylbenzene 1.66
34. Styrene* 1.86
35. m-Xylene 1.88
36. o-Xylene 1.92
37. p-Xylene 1.99
GC Conditions: • HP 5890 ft. x 1/8 inch OD column packed with 1% SP-1000
on 60/80 Mesh Carbopack B; Temperature Program: 60°C for 2
minutes, 60°C to 230°C at 10°C/min., then 230°C for 11
minutes; carrier gas: 36 ml Helium/minute; injector
temperature = 230°C.
*Area counts determined for a single concentration standard only. All other
compounds were determined over a dilution series.
D-5
-------
APPENDIX E
RCRA PART A PERMIT PROFILE SHEET
E-l
-------
U.S. ENVIRONMENTAL PROTECTION AGEHCY, OFFICE OF SOLID HASTE
HAZARDOUS HASTE FACILITY PROFILE
PREPARED BY DEVELOPMENT PLAWING AND RESEARCH ASSOCIATES, INC. (DPRAI
DATA SOURCE! HHDM3 VERSION VI (AS OF 27DEC04)
FOR FACILITY! ILD006272629, AMOCO OIL CO MAIN OFF I HATER TREATMENT
DATE! 06FEB85
PAGE! 1
FACILITY! IL0006272629
FACILITY INFORMATION
EPA IDENTIFICATION NUMBER! XLD006272629
FACILITY NAME* AMOCO OIL CO MAIN OFF ft MATER TREATMENT
MAILING ADDRESS! P 0 BOX 102
MOOD RIVER
EPA REGION!
FACILITY OWNER»
CONTACT PERSON/TITLE!
CONTACT TELEPHONE!
ACTUAL ADDRESS!
SUMMER RICHARD A
616/251-2228
OLD ST LOUIS RD
MOOD RIVER
IL 62095
IL 62095
OS
AMOCO OIL COMPANY
200 EAST RANDOLPH DRIVE
CHICAGO
312/856-5111
W
NJ
FACILITY IS A MAJOR HANDLER NOTIFIED UNDER RCRA.
FACILITY IS PRIVATE.
TSOF OWNER IS ALSO THE OPERATOR.
EXISTING FACILITY.
NATURE OF BUSINESS DESCRIPTION IS PRESENT.
MAP IS NOT ACCEPTABLE. DRAWING IS ACCEPTABLE.
FACILITY OPERATOR! AMOCO OIL COMPANY
200 EAST RANDOLPH DRIVE
?i??????mw?mwwt
312/856-5111
IL 60601
IL
COUNTY! 119 MADISON
LATITUDE i 38-51-05.0
LONGITUDE! 80-05-36.0
PHOTOGRAPHS ARE NOT ACCEPTABLE. INDIAN LANDi NO
EXISTENCE! 07JAN08
CLOSURE! UNKNOHN DATE
LAST HHDMS UPDATE! 07DEC84
NOTIFICATION ACTIVITIES! GENERATION. TREATMENT/STORAGE/DISPOSAL.
SIC CODES!
(01) 2911 PETROLEUM REFINING
DESIGN CAPACITIES!
(01) SOI CONTAINER
(03) T04 OTHER TREATMENT
HASTES!
U122 FORMALDEHYDE
K048 OAF FM OILY HATER SEWER PETRO
D001 NON-LISTED IGNITABLE HASTES
MM FACILITY TOTAL MM
(021 2869 INDUSTRIAL ORGANIC CHEMICALS.
6,000.00 GALLONS.
2,400.00 GALLONS/DAY.
(021 S02 TANK STORAGE
53.000.00 GALLONS.
METRIC TONS MASTE PROCESSESS
3.628.80
49,896.00 SOI S02
1,840.71 S04
55,365.51
HASTES WITHOUT AMOUNTS OR PROCESSES!
DOOO 0002 F001 F003-F005 F012 K049 K051-K052 P022 P053 P110 U002 U012-U013 UOI9 U044 U052 U054 U133
U135 U140 U151 UI54 U188 U210 U220 U226 U239
FINANCIAL DATA*
CURRENT CLOSURE COST ESTIMATE!
CURRENT POST-CLOSURE COST ESTIMATE!
PHASE II VERIFICATION SURVEY!
HASTE PROCESS SIZESi
HAZARDOUS HASTE GENERATED IN 19811
18,400. POSTED ON 22FEB84I PRIOR CLOSURE COST ESTIMATE!
*102,200. POSTED ON 22FEB84I PRIOR POST-CLOSURE COST ESTIMATEl
UNKNOHN TONS.
DUNS DATA!
KM INFORMATION FOR AMOCO OIL CO MAIN OFF ft MATER TREATMENT CONTINUED ON NEXT PAGE. MM
-------
U.S. ENVIRONMENTAL PROTECTION AGENCY. OFFICE OF SOLID HASTE
HAZARDOUS WASTE FACILITY PROFILE DATEt 06FEB85
PREPARED BY DEVELOPMENT PLANNING AND RESEARCH ASSOCIATES. INC. (OPRA) PAGE! 2
DATA SOURCE! HWDMS VERSION VI (AS OF E7DEC84) FACILITY: 110006272629
DUNS DATA: (CONTINUED FROM PREVIOUS PAGE)
SICS: 2911 STARTED: UNKNOWN
AMOCO OIL COMPANY INC THE BUSINESS LINE! PETROLEUM PRODUC NET WORTH! UNKNOWN
400 S MAIN PRINCIPAL OFFICER! F K WEBB SALES! UNKNOWN
WOOD RIVER IL 62095 PHONEi 618/254-7351 EMPLOYEES! 640
M« NOTE: END OF REPORT FOR FACILITY! UD006272629, AMOCO OIL CO MAIN OFF « MATER TREATMENT «*
M
OJ
-------
U.S. ENVIRONMENTAL PROTECTION ACENCYt OFFICE OF SOLID HASTE
HAZARDOUS WASTE FACILITY PROFILE
PREPARED BY DEVELOPMENT PLANNING AND RESEARCH ASSOCIATES! INC. (DPRA)
DATA SOURCE( HWDM3 VERSION VI IAS OF 27DEC84)
FOR FACILITY: ILD006278360, REILLY TAR ft CHEMICAL CORP
DATEl 06FEB85
PAGE! 1
FACILITY: ILD006270360
FACILITY INFORMATION
EPA IDENTIFICATION NUMBER j 110006270360
FACILITY NAME I REILLY TAR A CHEMICAL CORP
HAILING ADDRESSi P 0 BOX 370
GRANITE CITY
EPA REGION:
FACILITY OWNERt
CONTACT PERSON/TITLE:
CONTACT TELEPHONE:
ACTUAL ADDRESS:
PIRTLE LARRY L PLANT MGR
19TH I EDMARDSVILLE RD
GRANITE CITY
IL 62040
IL 62040
05
REILLY TAR I CHEMICAL CORPORATION
151 NORTH DELAWARE STREET
INDIANAPOLIS
317/638-7531
IN 46204
PI
FACILITY IS A MAJOR HANDLER NOTIFIED WIDER RCRA.
FACILITY IS PRIVATE.
TSDF OWNER IS ALSO THE OPERATOR.
EXISTING FACILITY.
NATURE OF BUSINESS DESCRIPTION IS PRESENT.
MAP IS ACCEPTABLE. DRAWING IS ACCEPTABLE.
FACILITY OPERATOR: REILLY TAR ft CHEMICAL CORPORATION
151 NORTH DELAWARE STREET
mm????7i?m?t?mm IN 7777?
317/638-7531
COUNTY: 119 MADISON
LATITUDE : 38-41-20.0
LONGITUDE: 80-08-20.0
EXISTENCE: 09SEP76
CLOSURE: UNKNOWN DATE
LAST HWDMS UPDATE: 26NOV84
PHOTOGRAPHS ARE ACCEPTABLE.
INDIAN LAND: NO
NOTIFICATION ACTIVITIES: GENERATION. TREATMENT/STORAGE/DISPOSAL.
SIC CODES:
(OH 2865 CYCLIC CRUDES AND INTERMEDIATE
DESIGN CAPACITIES:
(Oil SOI CONTAINER
(03) S03 WASTE PILE
(05) T02 SURFACE IMPOUNDMENT
110.00 GALLONS.
1*106.00 CUBIC YARDS.
30.000.00 GALLONS/DAY.
(021 S02 TANK STORAGE
(04) T01 TANK TREATMENT
(06) T03 INCINERATOR
71,000.00 GALLONS.
30.000.00 GALLONS/DAY.
0.32 METRIC TONS/HOUR.
HASTES:
U239 XYLENE
U226 1.1.1-TRICHLOROMETHANE »
U220 TOLUENE
U188 PHENOL OR CARBOLIC ACID.HYDROX
U151 MERCURY
U112 ETHYL ACETATE (I)
U051 CRESOTE
U002 ACETONE (I)
POOS 4-AHINOPYRIDINE OR AVITROL.PHI
K035 TREAT SLUDGES FM PROO CREOSOTE
«» FACILITY TOTAL **
WASTES WITHOUT AMOUNTS OR PROCESSES:
0001 U013
FINANCIAL DATA:
CURRENT CLOSURE COST ESTIMATE:
CURRENT POST-CLOSURE COST ESTIMATE:
METRIC TONS WASTE PROCESSESS
0.02 T03
0,02 T03
0.00 SOI
0.00 T03
0.00 SOI
0.01 T03
453.60 T03
0.00 T03
0.00 T03
1.36 S02
455.02
t2.14I.000. POSTED ON 22FEB84I PRIOR CLOSURE COST ESTIMATE: *1,600,000.
tieO.OOO. POSTED ON 22FEB84I PRIOR POST-CLOSURE COST ESTIMATE: 1180,000.
** INFORMATION FOR REILLY TAR ft CHEMICAL CORP CONTINUED ON NEXT PAGE. «M
-------
U.S. ENVIRONMENTAL PROTECTION AGENCY, OFFICE OF SOLID WASTE
HAZARDOUS HASTE FACILITY PROFILE
PREPARED BY DEVELOPMENT PLANNING AND RESEARCH ASSOCIATES, INC. (DPPA)
DATA SOURCE! HUDMS VERSION VI (AS OF 270ECB4)
DATEI 06FEB85
PAGEI 2
FACILITY! ILD006278360
FINANCIAL DATAl (CONTINUED FROM PREVIOUS PAGE)
ASSURANCE INSTRUMENT LETTER OF EFFECTIVE ON UNKNOWN DATE. EXPIRES ON 16JAN84.
THE INSTRUMENT NUMBER IS UNKNOWN AND THE INSTRUMENT COVERS ONE FACILITY.
LIABILITY INSTRUMENT FINANCIAL EFFECTIVE ON UNKNOMN DATE, EXPIRES ON 30MAR84.
THE INSTRUMENT NUMBER IS UNKNOWN AND THE INSTRUMENT COVERS ONE FACILITY.
PHASE II VERIFICATION SURVEY!
HASTE PROCESS SIZES!
SURFACE IMPOUNDMENTS! 30,000.00 SQUARE YARDS.
HASTE PILES: UNKNOWN CUBIC YARDS.
STORAGE CONTAINERS! 175.00 GALLONS.
THIS FACILITY MAS A TSD OR GENERATOR IN 1981.
HAZARDOUS HASTE GENERATED IN 1981: 8.00 TONS.
THIS SITE DID NOT RECEIVE HAZARDOUS HASTES GENERATED BY OTHER FIRMS.
DUNS DATA:
SICS: 2665
REILLY TAR t CHEMICAL CORP
19TH I EDUARDSVILLE RD
GRANITE CITY IL 62040
BUSINESS LINE: COAL TAR REFINER
PRINCIPAL OFFICER: KENNETH J MORRISON
PHONE: 618/452-3141
STATUS ON THIS INSTRUMENT IS ACTIVE.
STATUS ON THIS INSTRUMENT IS ACTIVE.
STARTED:
NET WORTH:
SALES:
EMPLOYEES:
UNKNOWN
UNKNOWN
UNKNOWN
70
«» NOTE: END OF REPORT FOR FACILITY: 110006278360, REILLY TAR t CHEMICAL CORP MM
PI
-------
U.S. ENVIRONMENTAL PROTECTION AGENCY* OFFICE til >ciUo
HAZARDOUS HASTE FACILITY PROFILE
PREPARED BY DEVELOPMENT PLANNING AMI) RESEARCH ASSOCIATES, IN* (DPRA)
DATA SOURCE I HHDMS VERSION VI lAS ul- 2/UtLfi^l
FOR FACILITY: ILD080012305, SHELL OIL CO MOOD RIVER REFINERY
DATES 06FEB85
PAGE! 1
FACILITY: ILD080012305
FACILITY INFORMATION
EPA IDENTIFICATION
FACILITY NAME:
MAILING ADDRESS:
NUMBER I XLD080012305
SHELL OIL CO MOOD
PO BOX 262
MOOD RIVER
RIVER REFINERY
IL 62095
EPA REGION:
FACILITY OWNER:
OS
SHELL OIL CO
PO BOX 262
MOOD RIVER
616/254-7371
XL 62095
CONTACT PERSON/TITLE:
CONTACT TELEPHONE:
ACTUAL ADDRESS:
MALLS CG MGR ENV CONSERV
618/254-7371
SA MA ft RTC 111
ROXANA
FACILITY OPERATOR:
IL 62084
SHELL OIL CO
PO BOX 262
m?mmmtw»?wm
618/254-7371
IL TWt
W
FACILITY IS A MAJOR HANDLER NOTIFIED UNDER RCRA.
FACILITY IS PRIVATE.
TSDF OWNER IS ALSO THE OPERATOR.
EXISTING FACILITY.
NATURE OF BUSINESS DESCRIPTION IS PRESENT.
MAP IS ACCEPTABLE. ORAUING IS ACCEPTABLE. PHOTOGRAPHS ARE NOT ACCEPTABLE. INDIAN LAND: NO
COUNTY: 119 MADISON
LATITUDE : 38-50-42.0
LONGITUDE: 90-02-59.0
EXISTENCE: 01JAN18
CLOSURE: UNKNOWN DATE
LAST HMDMS UPDATE: 07DEC84
NOTIFICATION ACTIVITIES: GENERATION. TRANSPORTATION. TREATMENT/STORAGE/DISPOSAL.
TRANSPORTATION MODE(S): HIGHWAY.
SIC COOES:
(01) 2869 INDUSTRIAL ORGANIC CHEMICALS,
DESIGN CAPACITIES:
(01) 003 SURFACE IMPOUNDMENT
(03) S02 TANK STORAGE
102) 2911 PETROLEUM REFINING
(02) SOI CONTAINER
40,000,000.00 GALLONS.
600,000.00 GALLONS.
5,000.00 GALLONS.
WASTES:
U16B PHENOL OR CARBOLIC ACID.HYDROX
U019 BENZENE
K052 BOTTOMS (LEADED) FM PETRO REFI
K051 API SLUDGE FM API OILY SEWER P
K050 PETRO REFIN EXC BUNDLE CLEANIN
K049 SLOP OIL FM OILY MATER SEHER P
K048 OAF FM OILY MATER SEWER PETRO
F003 NON-HALOGENATED SOLV i SOLV RE
F001 SPENT HALO CHLORIDES I SLUDGE
D003 NON-LISTED REACTIVE WASTES
D002 NON-LISTED CORROSIVE MASTRES
MM FACILITY TOTAL MM
HASTES WITHOUT AMOUNTS OR PROCESSES:
DOOO-D001 P110 U013
FINANCIAL DATA:
CURRENT CLOSURE COST ESTIMATE:
CURRENT POST-CLOSURE COST ESTIMATE:
METRIC TONS HASTE PROCESSESS
4.54 SOI
0.91 301
4.54 SOI
9,072.00 D83
4.54 SOI
2,721.60 D83
1,814.40 DB3
0.91 SOI
0.91 SOI
825.55 SOI 304
6,350.40 802
20,800.28
*415,000. POSTED ON 22FEB84I PRIOR CLOSURE COST ESTIMATE:
16,300. POSTED ON 22FEBQ4I PRIOR POST-CLOSURE COST ESTIMATE:
1415,000.
«6,300.
INFORMATION FOR SHELL OIL CO HOOD RIVER REFINERY CONTINUED ON NEXT PAGE. MM
-------
U.S. ENVIRONMENTAL PROTECTION AGENCYi OFFICE OF SOLID WASTE
HAZARDOUS HASTE FACILITY PROFILE
PREPARED BY DEVELOPMENT PLANNING AND RESEARCH ASSOCIATES, INC. (DPRA)
DATA SOURCE! HWDM3 VERSION VI (AS OF 27DEC84)
DATE: 06FEB65
PAGE: 2
FACILITY! ILD080012305
FINANCIAL DATA! (CONTINUED FROM PREVIOUS PAGE)
ASSURANCE INSTRUMENT FINANCIAL EFFECTIVE ON UNKNOWN DATE, EXPIRES ON 31HAR84. STATUS ON THIS INSTRUMENT IS ACTIVE.
THE INSTRUMENT NUMBER IS UNKNOUN AND THE INSTRUMENT COVERS ONE FACILITY.
LIABILITY INSTRUMENT FINANCIAL EFFECTIVE ON UNKNOUN DATE, EXPIRES ON 31MAR84. STATUS ON THIS INSTRUMENT IS ACTIVE.
THE INSTRUMENT NUMBER IS UNKNOUN AND THE INSTRUMENT COVERS ONE FACILITY.
PHASE II VERIFICATION SURVEY!
HASTE PROCESS SIZES:
HAZARDOUS HASTE GENERATED IN 1981I
DUNS DATA:
SICS: 2911
SHELL OIL COMPANY
JCT HMY 111 t 143
ROXANA IL 62084
UNKNOUN TONS.
BUSINESS LINE!
PRINCIPAL OFFICER!
PHONE:
REFINERY
A R MILLIAMS
618/254-7371
STARTED!
NET WORTH:
SALES:
EMPLOYEES:
UNKNOUN
UNKNOUN
UNKNOUN
1,700
«» NOTE: END OF REPORT FOR FACILITY! ILD080012305, SHELL OIL CO MOOD RIVER REFINERY «»
M
I
-------
FORM
3
RCRA
EPA
U.S. ENVIRONMENTAL. PROTECTION ACCNCY •
HAZARDOUS WASTE PERMIT APPLICATION
Consolidated Permit! Program
(Thit information it required under Srelion 3003 of RCRA.)
EPA I.D.
F I
FOR OFFICIAL USE ONLY
APPLICATION
>PPROVCO
3£S€g3$@f&&€S£3£IS^^
OATCRCCCIVEO
fyr. mo., f day)
COMMENTS
II. FIRST OR REVISED APPLICATION
Place in "X" in the appropriate box in A or 8 below (mark one box only) to indicate whether this is the first application you are submitting for your facility o
revised application. If this is your first application and you already know your facility's EPA I.O. Number, or if this is a revised application, enter your facility's
EPA 1.0. Number in Item I above.
A. FIRST APPLICATION (place on "X" btlou and provide tht appropriate date)
[531. EXISTING FACILITY (Stt instructions for definition of "ffitting" faeiUty.
11 . Complete item below.)
18
FOR EXISTING FACILITIES. PROVIDE THE DATE (yr.. mo.. A day)
OPERATION BEGAN OR THE DATE CONSTRUCTION COMMENCED
fuse the boitt to tht left)
]2.NEW FACILITY (Complete Htm below.)
FOR NEW FACILITIt
PROVIDE THE DATE
(yr.. mo., A day) OPEH
TION BEGAN OR IS
EXPECTED TO BEGI
B. REVISED APPLICATION (place on A below and complete Item I above)
r"5«- FACILITY HAS INTERIM STATUS
FACILITY MAS A RCRA PERMIT
III. PROCESSES - CODES AND DESIGN CAPACITIES ^Ig^^^^^^^»^CJ
A, PROCESS CODE — Enter the code from the list of process codes below that best describes each process to be used at the facility. Ten lines are provided for
entering codes. If more lines are needed, enter the cotie(s) in the space provided. If a process will be used that is not included in the list of codes below, the:
describe the process (including la design capacity) in the space provided on the form (Item III-CI.
B. PROCESS DESIGN CAPACITY — For each code entered in column A enter the capacity of the process.
t. AMOUNT — Enter the amount.
2. UNIT OF MEASURE — For each amount entered in column Bill, enter the code from the list of unit measure codes below that describes the unit of
measure used. Only the units of measure that are listed below should be used.
PROCESS
PRO- APPROPRIATE UNITS OF
CESS MEASURE FOR PROCESS
CODE DESIGN CAPACITY
PRO-
CESS
PROCESS
APPROPRIATE UNITS OF
MEASURE FOR PROCESS
CAPACITY
Storage:
CONTAINER (barrel, drum, etc.)
TANK
WASTE PILE
SURFACE IMPOUNDMENT
SOI GALLONS OR LITERS
502 GALLONS OR LITERS
SO3 CUBIC YARDS OR
CUBIC METERS
S04 GALLONS OR LITERS
Treatment:
TANK
SURFACE IMPOUNDMENT
INCINERATOR
TO I GALLONS PER DAY OR
LITERS PER DAY
T02 GALLONS PER DAY OR
LITERS PER DAY
T03 TONS PER HOUR OR
METRIC TONS PER HOUR:
GALLONS PER HOUR OR
LITERS PER HOUR
LANDFILL D»0 ACRE-FEET (the volume that OTHER (Ute for physical, chemical. T04 GALLONS PER DAY OR
would cover one acre to a thermal or biolofical treatment LITERS PER DAY
depth of one foot) OR processes not occurrinf in tanks.
HECTARE-METER surface impoundments or inciner-
LAND APPLICATION D*1 ACRES OR HECTARES atorx. Describe the practise* in
OCEAN DISPOSAL O«2 GALLONS PER DAY OR the space provided: Item ai-C.)
LITERS PER DAY
SURFACE IMPOUNDMENT Dt3 GALLONS OR LITERS
UNIT OF UNIT OF UNIT
MEASURE MEASURE MEASl
UNIT OF MEASURE CODE UNIT OF MEASURE CODE UNIT OF MEASURE COD
GALLONS G
LITERS
CUBIC 1
CUBIC K
GALLOI
EXAMPLE
other can 1
IET
IS 1
:FC
10lC
t (
c]
}R COMPLETING ITEM III (tho
400 gallons. The facility also ha
• T*A
DUP
t 1 > • tilt-
LINE
NUMOER
X-1
X-2
1
-
3
4
1
A. PRO-
CESS
CODE
(from list
above)
n - i»
s
T
5
S
T
0
0
C
0
0
2
3
1
3
2
B. PROCESS DESIGN
LITERS PER DAY
TONS PER HOUR
METRIC TONS PE
GALLONS PER HC
LITERS PER MOU
wn in line numbers X- 1 and X
s an incinerator that can burn
c \ N
1 \
• ~ \
. . . . V ACRE-FEET . t
R H
JUF
B
OUR
»
2 below): A facility has two storage tanks, one tank can hold 200 gallons and t
up to 20 gallons per hour.
\\x\\\\\\\\\\\\\\\\\\
CAPACITY
t. AMOUNT
(specify;
f* *
600
20
660
500
40,000
i» - i*
2. UNIT
OF MEA-
SURE
(enter
code)
G
E
G
Y
U
T«
FOR
OFFICIAL
USE
ONLY
f» - »i
t»
jt
LINE
NUMBER
5
6
7
8
9
10
A. PRO-
CESS
CODE
(from list
above;
t» - «•
• •
i»
B. PROCESS DESIGN CAPACITY
t. AMOUNT
!• - Z»
«» - !»
2. UNIT
OF MEA-
SURE
(enter
code)
>•
rt
FO
OFFK
US
ON
H •
?•
EPA Form 2510-3 16-80)
PAGE 1 OF 5
« ...e n —.
E-8
CONTINUE ON RHVc
1 _TO_O/.
-------
111. PROCESSES (continued)
C. SPACE FOR ADDITIONAL PROCESS CODES OR FOR DESCRIBING OTHCR PROCESSES (code "T04"). FOR EACH PROCESS ENTERED HERE
JNOUUDE DESIGN CAPACITY.
IV. DESCRIPTION OF HAZARDOUS WASTES >S*^
* -~*-~~ -.•^« ^ » .*« . j»****• ^* VW • •«-» M « ^h* ^^.^Tl^V^^^*--'-^^*v*'gi.'.^^-"g^:r"j*> <~ ^ry^^—c-•St1-*,*f>J5'=^'«":"^—i"t**r"^'r*'VJtTi~~<^"'^i*fc'T'''a'^"^'•a^r-^?>^^M-~'~*'•* =—^^1—^^^-
A. EPA HAZARDOUS WASTE NUMBER —.Enter the four-aigrt numoer trom 40 CFfiTSubpart^0 tor each listed hazardous waste you will1 handle. If you
handle hazardous wastes which are not listed in 40 CFR. Subpart D. enter the four—digit numberW from 40 CFR. Subpart C that describes the characteris-
* tics and/or the toxic contaminants "of those hazardous wastes.
B. ESTIMATED ANNUAL QUANTITY — For each listed waste entered in column A estimate the quantity of that waste that will be handled on an annual
basis. For each characteristic or toxic contaminant entered in column A estimate the total annual quantity of all the non—listed wastefo/ that will be handled
which possess that characteristic or contaminant.
C. UNIT OF MEASURE — For each quantity entered in column B enter the unit of measure code. Units of measure which must be used and the appropriate
codes are:
ENGLISH UNIT OF MEASURE
METRIC UN IT QFJAEASUHE^
CODE.
POUNDS.
TONS. . .
.f
.T
KILOGRAMS..
METRIC TONS.
,K
. M
If facility records use any other unit of measure for quantity, the units of measure must be converted into one of the required units of measure talcing into
account the appropriate density or specific gravity of the waste.
D. PROCESSES
1. PROCESS COOES:
For listed hazardous wast*: For each listed hazardous waste entered in column A select the coded) from the list of process codes contained in Item III
to indicate how the waste will be stored, treated, and/or disposed of at the facility.
For non—fisted hazardous wastes: For each characteristic or toxic contaminant entered in column A, select the codefil from the list of process codes
contained in Item III to indicate all the processes that will be used to store, treat, and/or dispose of all the non—listed hazardous wastes that poses
that characteristic or toxic contaminant.
Nota: Four spaces are provided for entering process codes. If more are needed: (1) Enter the first three as described above; (2) Enter "OCX)" in the
extreme right box of Item IV-Q(I); and (3) Enter in the space provided on page 4, the line number and the additional codefrj.
2. PROCESS DESCRIPTION: If a code is not listed for a process that will be used, describe the process in the space provided on the form.
NOTE: HAZARDOUS WASTES DESCRIBED BY MORE THAN ONE EPA HAZARDOUS WASTE NUMBER - Hazardous wastes that can be described by
more than one EPA Hazardous Waste Number shall be described on the form as follows:
1. Select one of the EPA Hazardous Waste Numbers and enter it in column A. On the same line complete columns B.C. and O by estimating the total annual
quantity of the waste and describing all the processes to be used to treat, store, and/or dispose of the waste.
2. In column A of the next line enter the other EPA Hazardous Waste Number that can be used to describe the waste. In column D(2) on that line enter
"included with above" and make no other entries on that line.
3. Repeat step 2 for each other EPA Hazardous Waste Number that can be used to describe the hazardous waste.
EXAMPLE FOR COMPLETING ITEM IV (shown in line numben X-1. X-2, X-3. and X-4 below} - A facility will treat and dispose of an estimated 900 pounds
per year of chrome shavings from leather tanning and finishing operation. In addition, the facility will treat and dispose of three non—listed wastes. Two wastes
are corrosive only and there will be an estimated 200 pounds per year of each waste. The other waste is corrosive and ignitable and there will be an estimated
100 pounds per year of that waste. Treatment will be in an incinerator and disposal will be in a landfill.
u
So
_1Z
X-1
%
J .
X-3
X-4
A. EPA
HAZARD.
WASTENO
(enter code)
K
D
D
D
0
0
0
0
5
0
0
0
4
2
1
2
B. ESTIMATED ANNUAL,
QUANTITY OF WASTE
900
400
100
C. UNIT
OF MEA-
SURE
(enter
code)
P
P
P
D. PROCESSES
t. PROCESS COOES
(enter)
1 J~
T 0 3
\ \
T 0 3
i J
T 0 3
\ i
i i
D 8 0
i i
D 8 0
D 8 0
i i
i i
i i
i *
i i
i i
i i
i i
i i
Z. PROCESS DESCRIPTION
(If a code it not entered in DID)
included with above
EPA Form 3510-3 16-80)
PAGE 2 OF 5
A—7 Revi
11-28-84
E-9
CONTINUE ON PAG
-------
Continued front page 2.
NOTE: Photocopy this p»or before completing if you have more than 26 wastts to list
Form Approved OMB No. 1S8-S80OO4
EPA 1.0. NUMBER fcnlcr from paftf 1)
•
w
•
1
L
D
0
0
62783
6
0
s - *•
T/A
f •
C
1
1*
\ \ \
*
W
row orriciAi. use ONUY \ \ \ \ \ \ \
DUP
U£ * \ \ \ \ \ \ »•
_J-2 DUP \\\\\\\
— DESCRIPTION OF HAZARDOUS WASTES (continued) "^^5 ?£* ^^^Jfc2^£3^^>:^
u
Ed
1
2
3
4
5
6
7
8
9
10
1
1
1
fe
13
14
15
16
17
18
19
20
21
22
23
25
26
A. EPA
HAZARD.
WASTE NO
(enter code)
L
K
M
0
0
5
3
1
5
>• i
B. ESTIMATED ANNUAL
QUANTITY OF WASTE
500
6,600
-
*
•
C. UNIT
OrMEA-
SURE
f enter
code)
JX
T
P
D. PROCESSES
1. PROCESS COOKS
(tnlrrl
l I
S 0 3
S
0 1
»
i i
i <
i i
i i
i i
i
i
i
i
i i
i
l
i
i
i i
i
l
i
i
i i
i i
i >
i i
i i
i i
i i
• i
i i
i i
i i
i i
i i
i i
i <
i i
i i
i i
i i
i i
i i
i i
i —i
i f
• i
• t
• i
i i
< i
i i
i i
i i
i i
i i
i i
i i
i i
i i
i i
" - >•
i *
I »
1 l
1 1
t 1
1 1
t 1
1 1
t 1
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Z. PROCESS DESCRIPTION
(If a code U not entered in D(l))
Off Site Disposal
Off Site Disposal
EPA Form 2570-3 (5-801
A-8 Revised 11-28-84
PAGE 3 OF 5
E-10
CONTINUE ON REVEF
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Continued from the Iront.
IV. DESCRIPTION OF HAZARDOUS WASTES (contir.uedl ^^^$$ J^^^lf^
• — — i - - - - —^- ._ _ ™" ™ ^* •••«** »*»»ji|^^«»»**»»*to/ i^r ^~¥i ^^^v * — -•• ^**^~ •*^«, • v\ t\"^y •• " % j
E. USE'THIS SPACE TO LIST ADDITIONAL PROCESS COOES FROM ITEM D(l J ON PACE 3.
EPA I.O. NO. (eater from page 1)
V. FACILITY DRAWING
All ex'cting facilities must indude in the space provided on pace 5 a scale drawing of the facility (see instructions for more detail!.
VI. PHOTOGRAPHS JS^J^gl^^?^^^^^
AH existing facilities must indude photographs (aerial or ground— level) that dearly delineate all existing structures; existing storage.
treatment and disposal areas; and sites of future storage, treatment or disposal areas (see instructions for more detail}.
_ _
FACILITY GEOGRAPHIC LOCATION ^:«^Sg^g^^45J:5?r^^^^
LATITUDE fdttrtr*. minute*. £ ttcondt)
LONGITUDE tdtgrret. minutet. ti seconds)
3 8
4 1
020
090
0 8
020
VIII. FACILITY
^3^^
If the facility owner a also th« facility operator as lined in Section VIII on Form 1. "General Information", place an ~X~ in the box to the left and
ikip to Section IX below.
B. If the facility owner is not the facility operator as lined in Section VIII on Form 1. complete the following items:
1. NAME OF FACILITY'S LEGAL. OWNER
2. PHONE NO. (ana code & nt
E!
S. STREET OR P.O. BOX
4. CITY OR TOWN
S.ST.
C. ZIP COOE
F!
C 1
Gl
IX. OWNER CERTIFICAT10N ^IV^S^^^^^^^Sg^^-r^^r^^^^^^gr^H^
/ certify under penalty of law that I have personally examined and am familiar with the information submitted in this and all attached
documents, and that based on my inquiry of those individuals immediately responsible for obtaining the information, I believe that the
submitted information is true, accurate, and complete, I am aware that there are significant penalties for submitting false information,
including the possibility of fine and imprisonment.
A. NAME (print or type)
C. F. Lesher
Executive Vice President
B. SW-HATUR
C, DATE SICNEO
X. OPERATOR CERTIFICATION
tify under penalty offaw that I have personally examined and am familiar with the information submitted in this and all attached
•I uments. and that bzssd on my inquiry of those Individuals immediately responsible for obtaining the information, I believe that the
submitted information is true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fine and imprisonment.
A. NAME (print or type]
8. SIGNATURE
C. DATE SICNEO
CONTINUE ON P;
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