United States
Environmental Protection
Agency
Oi'fice of A;r Quality
Pijnnmg an'J Standards
Research Triangle Pa-k NC 277 "i
EMB Heport 85-HV.S-3
November 1 985
Hazardous Waste TSDF
Waste Process Sampling
Volume !V:
Chemall, inc., Port Neches, Texas
Chemical Leaman Tank Lines, Inc., Port Arthur, Texas
Gulf Oil Products Ccmpany, Port Arthur, Texas
Lower Neches Valley Authority, Beaumont, Texas
Mobii Oil Corporation, Beaumont Texas
Neches Butane Products Company, Port Neches, Texas
Texaco, incorporated, Port Arthur, Texas
•>* -v ;v
^iV^^S^'vS "
:, ..;• ^''".' -?a»
-------
Prepared for
U.S. Environmental Protection Agency
Office of Air Quality Planning and Standards
Research Triangle Park, North Carolina 27711
HAZARDOUS WASTE TSDF
WASTE PROCESS SAMPLING
VOLUME IV.
Chemall, Inc., Port Neches, Texas
Chemical Leaman Tank Lines, Inc., Port Arthur, Texas
Gulf Oil Products Company, Port Arthur, Texas
Lower Neches Valley Authority, Beaumont, Texas
Mobil Oil Corporation, Beaumont, Texas
Neches Butane Products Company, Port Arthur, Texas
Texaco, Incorporated, Port Arthur, Texas
October 1985
Prepared by
GCA CORPORATION
GCA/TECHNOLOGY DIVISION
Bedford, Massachusetts 01730
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DISCLAIMER
This Final Report was furnished to the Environmental Protection Agency by
GCA Corporation in fulfillment of Contract No. 68-02-3851, Task No. 8. The
opinions, findings, and conclusions expressed are those of the authors and not
necessarily those of the Environmental Protection Agency. Mention of company
or product name is not to be considered as an endorsement by the Environmental
Protection Agency.
ii
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TABLE OF CONTENTS
Page
Introduction iv
Chemall, Incorporated Trip Report 1-1
Chemical Leaman Tank Lines Trip Report 2-1
Gulf Oil Products, Port Arthur Refinery Trip Report 3-1
Lower Neches Valley Authority Trip Report 4-1
Mobil Oil Refinery Trip Report 5-1
Neches, Butane Products Company Trip Report 6-1
Texaco, Incorporated Trip Report 7-1
Appendix A - Sample Identification Forms.... A-l
Appendix B - GCA Data Report Forms B-l
Appendix C - RCRA Part A Permit Profile Sheet C-l
Appendix D - Analytical Procedures.. D-l
Appendix E - Quality Assurance E-l
Appendix F - Confidential Addenda F-l
iii
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INTRODUCTION
Air emissions from hazardous waste treatment, storage and disposal
facilities (TSDFs) are currently being studied by the EPA Office of Air
Quality Planning and,Standards (OAQPS). The seven sites described herein
represent a portion of the testing program undertaken by OAQPS in an effort to
profile TSDFs and estimate emissions. The results of the testing will be used
as background information for possible standards for TSDF area source air
emissions.
The facilities were selected to increase the scope of TSDF operations
encompassed by previous case study and testing programs. An effort was made
to expand the data base in terms of treatment operations, waste types and
geography. Waste sampling was conducted at all the sites. In addition,
detailed information on all waste operations, emission controls and operating
practices was collected.
Three distinct types of waste sampling were conducted. Liquid samples
from waste treatment tanks and impoundments were obtained and analyzed for
volatile organic compounds (VOCs). Soil cores from land treatment areas were
taken and analyzed for VOCs, FCBs, pesticides and metals. In addition,
surface soil composites were collected and analyzed for PCBs, pesticides and
metals. These analyses provide characterization of the volatile and
particulate components of on site wastes.
The wastestream characterization, sample analysis and waste process
descriptions should supply the necessary inputs to emission estimation
techniques. Surface soil samples provide an indication of the hazardous
compounds associated with fugitive particulates. The results of these
analyses are presented for each site.
These seven Texas sites represent both waste generators with on site
treatment operations and commercial TSDFs. Three refinerys, two petrochemical
manufacturers, a truck cleaning facility and a commercial wastewater treatment
facility were visited. Sample analysis and process descriptions reflect
operations on the day of the visit. Included with each trip report is a
summary of the analytical sample results, the actual results from analyses and
the Part A Permit Profile sheet for the facility.
iv
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Section 1.
Chemail, Incorporated
Port Neches, TX
1-1
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TABLE OF CONTENTS
Section Page
I. Introduction 1-5
II. Waste Characterization 1-6
III. Facility Process Descriptions 1-6
Product Process Operations 1-6
Wastewater Treatment 1-9
IV. Sample Location Description 1-9
Sample Location Description 1-9
Quality Assurance 1-12
V. Sample Analysis 1-12
Analytical Summary 1-12
Quality Assurance 1-16
1-2
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LIST OF TABLES
Table Page
1 Wastewater Analysis Conducted on the Lower Surface
Impoundment at Chemall, Incorporated in Port Neches,
Texas 1-7
2 Liquid Sample Analysis of the Field Bias Blank for the
Chemall Corporation Facility in Port Neches, Texas 1-13
3 Liquid Sample Analysis from the Treatment Ponds at the
Chemall Corporation Facility in Port Neches, Texas 1-14
4 Surface Soil Analysis of Composite Soil Sample from the
Chemall Corporation Facility in Port Neches, Texas 1-15
5 Surrogate Recoveries - Volatile Organics, Chemall, Port
Neches, Texas • 1-17
1-3
-------
LIST OF FIGURES
Figure Page
1 Chemall wastewater process flow diagram chart (Port
Neches, TX) 1-10
2 Sampling points at Chemall, Port Neches, TX 1-11
1-4
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Site:
FCID:
Site Contact:
Field Trip Personnel:
Visit Time and Date:
Chemall, Incorporated
5500 Highway 366
Port Neches, Texas 77651
latitude 29° 57' 52" N
longitude 93° 55' 27" W
TXD089792543
Dr. Brian Davis, Plant Manager
(409) 727-1471
Dr. Brian Davis, Plant Manager, Chemall
Jim Durham, EPA
Penny Lassiter, EPA
Douglas Seely, GCA/Measurements
Scott Osbourn, GCA/Engineering
January 25, 1985
8:30 a.m.
I. INTRODUCTION
Chemall, Incorporated, is a manufacturer of assorted chemical compounds.
The facility is located within an urban industrial area of Port Neches and has
undergone several charges in ownership, as well as major product lines, over
the last 30 years. Present ownership and product emphasis have been in effect
for the last two to three years. Currently, Chemall produces four primary
products: sodium thiosulfate, sulfamic acid, cuprous chloride, and cuprous
iodide. Plant operations are continous. An organic product termed "Cosorb"
is produced in lesser amounts by batch and it is anticipated that a cobalt
salt will be manufactured sometime in the future. These products are shipped
out in bulk form (i.e., railcar or tank trucks), however, a manual drumming
line is in operation, whereby materials are transferred from railcar to drums
and trucked off site. Drums are placed beneath an overhead chute and filled
manually, no automatic equipment is employed due to the small quantities of
material drummed. These are primarily special orders of low vapor pressure
1-5
-------
material, such as paraffin waxes and soybean oils, and are not manufactured on
site. A negative pressure hood and associated ducting serves as a vapor
return line to the railcar being emptied. A sump is located beneath the
drumming area to handle spills.
A plant warehouse currently stores drummed material which has accumulated
over years of previous plant operation. The drummed material is primarily
off-spec cuprous chloride. Many drums are of unknown composition and are
currently being inventoried. The drums were stacked approximately four high.
Some of the drums were corroded; however, no gross leakage was observed.
From a waste management standpoint, the process operations of most
concern at Chemall are no longer active. These operations included the
manufacture of toxaphene, small amounts of agent orange and the recycling of
waste oil. Applications were filed at one time to manufacture agent orange;
however, due to decreased market demand agent orange was never processed at
the site. Discontinuation of these operations is not reflected in the
attached Part A (Appendix C). Chemall has not applied for a Part B permit.
II. WASTE CHARACTERIZATION
Stormwater runoff provides the primary wastewater charge to the two
surface impoundments on site. Various process sumps at the plant are also
directly piped or flow through open drainage ditches to this destination. The
wastewater within these sumps consists primarily of inorganics, such as
mineral acids. Data concerning the quantity and waste characterization of the
process wastewater were not available on a per process basis. A wastewater
analysis, conducted in November of 1984 by Texas Environment Services, is
attached as Table 1.
III. FACILITY PROCESS DESCRIPTIONS
Product Process Operations
(THIS SECTION HAS BEEN CLAIMED CONFIDENTIAL BY CHEMALL, INC. THIS
INFORMATION IS CONTAINED WITHIN APPENDIX F OF THIS VOLUME)
1-6
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Table 1. WASTEWATER ANALYSIS CONDUCTED ON THE LOWER SURFACE IMPOUNDMENT
AT CKEMALL, INCORPORATED'IN PORT HECHES, TEXAS.
SAMPLE SOURCE:Lower Pond
DATE COLLECTED:11/01/84
CLIENT: Chemall,Inc.
P.O. BOX 30?
Groves.TX 7761?
ATTN:Bob Phyllis
DATA NUMBER:110184-2
REPORT DATE:ll/0<5/84
P.O.NUMBER :None
REFERB-JCE :METHOD
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(THIS SECTION HAS BEEN CLAIMED CONFIDENTIAL BY CHEMALL, INC. THIS
INFORMATION IS CONTAINED WITHIN APPENDIX F OF THIS VOLUME)
1-8
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Wastewater Treatment
Process sumps and storm water runoff are discharged to two open drainage
ditches which run the length of the facility and provide charge to the lower
surface impoundment (Figure 1). This lower impoundment is approximately 130
feet long, 210 feet wide, 9 feet deep and has a capacity estimated at 1.2
million gallons. A flocculant is added and after adequate retention time,
wastewater is pumped to the upper surface impoundment. Retention time in the
lower impoundment varies and can range to as long as six months during the
summer season. The upper impoundment is smaller in volume (350,000 gallon
capacity) and measures 110 feet in length, 65 feet in width, with a depth of
approximately seven feet.
Chemail has an NPDES permit to discharge from this upper impoundment to
the Neches River. Discharge can range to as high as 350,000 gallons per day.
Sodium thiosulfate received at the ponds results in a high chemical oxygen
demand (COD) in the pond water discharge. A wastewater analysis was conducted
in November of 1984 and all measured chemical constituents tested at less than
0.01 mg/l(the limit of detection of the analysis method). Chemall regularly
tests for wastewater oil and grease content as required by permit conditions.
The permit imposes a limit of 15 ppm and test results are frequently in the
range of one to seven ppm.
IV. SAMPLING INFORMATION
Sample,.Location. Description
Two surface impoundments on site, termed the upper and lower ponds, were
sampled at the Chemall facility. Sampling points are illustrated in the
schematic in Figure 2.
Lower Impoundment
Wastewater from process sumps and stonnwater runoff, coveyed via open
channels, provides charge to the lower treatment pond. The surface area was
green in color with no visible oil sheen. Grassy vegetation was growing to
1-9
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PRODUCTION
UNITS
PRODUCTION
UNITS
DRUMMING
AREA
WAREHOUSE
XAPHEN
SUMP
(CAPPED)
UPPER
SURFACE
IMPOUNDMENT
LOWER
SURFACE
IMPOUNDMENT
RAILROAD
NOT TO SCALE
Figure 1. Chemall wastewater process flow diagram, Port Neches, Texas.
1-10
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UI-1
UPPER TREATMENT
IMPOUNDMENT
LOWER TREATMENT
IMPOUNDMENT
NOT TO SCALE
® SAMPLING POINT
Figure 2. Sampling points at Chemall, Port Neches, Texas.
1-11
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the water's edge. A sample was taken at the outfall (Figure 2, point LI-1)
and was clear in appearance. Water temperature at the time of sampling was
approximately 52°F.
Upper Impoundment
After adequate retention time in the lower pond or when the capacity of
the lower pond is exceeded, wastewater is pumped to the upper impoundment.
Water within the upper pond was very clear in appearance. In some areas, an
orange sediment was visible on the pond bottom. The sample taken was very
clear in appearance. Water temperature at the time of sampling was 52°F.
Quality, Assuranc_e
Sampling procedures were employed as described in the Quality Assurance
Project Plan dated 30 October 1984. Liquid samples were collected in
quintuplicate, as a standard procedure, with one of the five samples retained
^
by the facility as a split. The remaining quadruplicate liquid samples were
returned to the GCA Analytical Laboratory in Bedford, MA, where they were
received into the sample bank. Sample custody and handling procedures
included the use of sample tags, chain-of-custody sheets, refrigeration of
samples between sampling and analysis, and shipping of samples in coolers
sealed with custody seals. In addition, each sample was assigned a unique
sample code which linked it to the facility, the source, and the sample point.
V. SAMPLE ANALYSIS
Analytical Summary
Tables 2 through 4 provide the analytical summary reports for the samples
collected during the site visit (see Appendix A). These tables present the
major compounds quantified by GCA Corporation/Technology Division. The actual
data sheets for the samples are provided in Appendix B.
1-12
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TABLE 2. L1SUID SAMPLE ANALYSIS OF THE FIELD BIAS BLANK FOR
THE CHEHALL CORPORATION FACILTY IN PORT HECHES, TEXAS
a,b
Compounds Detected Concentration (ug/I)
Acetone 80
ssssssssassssssssg-rr—sssssasss3STiiTT=5SSga,-. L'Tis
Analysis of saiple 42441F3B by 6CA Corporation using 6C/HS.
b
ug/I = ppb assuiing a density of 1.
1-13
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TABLE 3. LIQUID SABPLE ANALYSIS FROil THE TREAMENT PONDS AT THE
CHBIAU. CORPORATION FACILITY IN PORT HECHES, TE1AS
c
Concentration (ug/1)
a b
Coapounds Detected Analysis 1 Analysis 2
Acetone 97 tt
Toluene 8 4
1,1,1-Trichloroethane & 9
Cblorofori 4
Hetnylene chloride 3
TOTAL HALOGEHATED OR6ANICS 13 9 '
TOTAL OXYGENATED OR6ANICS 97 U
TOTAL AROHATICS 8 4
TOTALJ«HC_ __ 118 __ 79
a
Analysis of saaple 42791 (upper pond) by 6CA Corporation using SC/HS.
b
Analysis of saiple 42787 Hotter pond) by 6CA Corporation using 8C/BS.
c
ug/1 = ppb assuaing a density of 1.
1-14
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TABLE t. SURFACE SOIL ANALYSIS OF COMPOSITE SOIL SAMPLES FROM
THE CHEMALL CORPORATION FACILITY IN PORT NECHES, TEXAS
a,b
Parameter Concentration tig/kg}
Chlordane <3.0
Heptachlor epoxide <7.0
Toxaphene 104
a 63
Analysis of saiple 42812 by 6CA Corporation using GC w/Ni ECO
b
ig/lcg = ppa assuiing a density of 1.
1-15
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A summary of analytical procedures is contained in Appendix D. Aqueous
samples were analyzed for volatile organics; the composite soil sample was
analyzed for pesticides and PCBs. Refer to these sections in Appendix D for
the pertinent information.
Quality^Assurance
Chain of custody and quality control protocols are contained in Appendix
£. Quality control procedures for volatile organics included the use of
surrogate spikes; these results are contained in Table 5. Quality control
information for pesticides and FCBs should also be referenced regarding the
samples taken at Chemail.
1-16
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TABLE 5. SURROGATE RECOVERIES - VOLATILE ORGANICS.
CHEMALL, PORT NECHES, TEXAS.
Sample
Identification
C-LP-1D
C-UP-1D
Method blank
Percent Recoveries
GCA
Control No.
42787
42791
3/18/85
Average Percent Recovery
Relative Standard Deviation %
D8-
toluene
103
101
99
101
2
Bromo-
fluorobenzene
108
112
118
113
5
D4 - 1,2-
djLchlproethane
70
89
85
81
10
1-17
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Section 2.
Chemical Leaman Tank Lines
Port Arthur, TX
2-1
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TABLE OF CONTENTS
Section
I. Introduction 2-5
II, Waste Characterization 2-7
III. Waste Treatment Processes 2-8
Wastewater Treatment System 2-8
Container Storage 2-8
IV. Sampling Information 2-10
Sample Location Description. 2-10
Quality Assurance 2-11
V. Sample Analysis 2-11
Analytical Summary 2-11
Quality Assurance 2-11
2-2
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LIST OF TABLES
Table
1 Dimensions of Wastewater Treatment Tanks at Chemical
Leaman Tank Lines in Port Arthur, Texas 2-9
2 Liquid Sample Analysis of the Mixing Tank at the Chemical
Leaman Tank Lines, Inc. Facility in Port Arthur, Texas.... 2-12
3 Liquid Sample Analysis from the Outflow Pipe at the Chemical
Leaman Tank Lines, Inc. Facility in Port Arthur, Texas.... 2-13
4 ICAP Analysis of Composite Soil Samples from the Chemical
Leaman Tank Lines, Inc. Facility in Port Arthur, Texas.... 2-14
5 Analysis of Composite Soil Samples from the Chemical Leaman,
Tank Lines, Inc. Facility in Port Arthur, Texas 2-15
6 Base/Neutral Extractables Analysis of Surface Soil Taken
from Composite Soil Samples at the Chemical Leaman Tank
Lines Facility in Port Arthur, Texas 2-16
7 Surrogate Recoveries - Volatile Organics. Chemical Leaman
Tank Lines, Port Arthur, Texas 2-17
8 Surrogate Recoveries - Extractable Organics. Chemical
Leaman Tank Lines, Port Arthur, Texas 2-18
2-3
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LIST OF FIGURES
Figure Page
1 Sampling locations at Chemical Leaman Tank Lines (Port
Arthur, Texas) 2-6
2-4
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Site:
FCID:
Site Contact:
Field Trip Personnels
Visit Time and Date:
Chemical Leaman Tank Lines, Incorporated
6201 Twin City Highway
Port Arthur, Texas 77627
Latitude:
Longitude:
TXD047468129
29° 56' 57"
93° 57' 18"
Mr. Harold Thompson, Facility Manager
(409) 727-2121
Harold Thompson, CTLT
Jim Durham, EPA
Penny Lassister, EPA
Rich Roat, GCA/Measurements
Tom Warn, GCA/Engineering
January 23, 1985
1:30 p.m.
I. INTRODUCTION
Chemical Leaman Tank Lines (CLTL), Incorporated, is a commercial tanker
reconditioning facility located in rural Port Arthur, Texas. The facility
operates four cleaning bays, all under the same roof. Each bay is large enough
to contain a tanker and has overhead doors at both ends. The floor is concrete
with several drains, but with no curbing or gutter. Mr. Harold Thompson, the
facility manager, stated that very little of the washing solutions ever escaped
from the bay area. A general facility plot plan is presented in Figure 1.
Several different cleaning methods are utilized at this facility. These
include steam cleaning, a pre-solvent rinse, a cold water flush, and a
concentrated caustic solution used in a closed-loop system. The facility also
uses a steam dryer to remove moisture from the inside of clean tankers.
All the cleaning operations, with the exception of the closed-loop system,
are initiated by inserting a high pressure hose inside the tanker through the
top porthole. The proper wash solution is then pumped through the hose into
the tanker and removed at the rear drain valve. This wash solution is then
directed to the wastewater treatment system via a floor drain.
2-5
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DRIVEWAY
SLOPED, PAVED AREA
TANKER
CLEANING
FACILITY
OUTFLOW
FENCELINE
TANKER
GRAVITATOR
GRAVEL AREA
AERATION
TANK
MIXING
TANK
SUMP
UNDERGROUND PIPE
NOTE'-NOT TO SCALE
Q SAMPLE POINTS
Figure 1. Sampling Locations at Chemical Leaman Tank Lines (Port Arthur, Texas).
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The closed-loop system is operated differently in that the concentrated
caustic solution in held in a 1200 gallon reservoir and returned after each
use. The reservoir is a rectangular, steel tank with a loosely fitting cover
and no conservation vents. It maintains the temperature of the caustic
solution at about 180°F.
The cleaning method selected depends entirely on the material last
contained by the tanker. Mr. Thompson explained that when a tanker comes in
he simply reviews the shipping papers to see what material it had been
hauling. This information is then compared to his operations manual to see if
and/or how his facility should clean it. The facility cleans on the average
of three tankers per day. Most of the tankers serviced are owned by CLTL.
II. WASTE CHARACTERIZATION
The primary waste material generated at this facility is the waste rinse
water. The volume of this material was estimated to be about
10-15,000 gallons per month. This volume represents about 5 percent of the
total design capacity for the wastewater treatment system. Specific waste
characterization of the rinse wastewater is not known, but a general
description of the waste materials handled at this facility is provided in
Appendix E.
A secondary waste type handled at this facility is comprised of the solid
residues remaining in an empty tanker prior to cleaning. This material varies
greatly in composition, but is generally not more than 25 gallons in volume.
Again, specific characterization is not available for this material.
A third waste type handled at this facility is the spent concentrated
caustic solution used in the closed-loop system. This material is removed
from service about every six months and replaced with fresh solution. The
spent solution is then hauled by tanker off site to a commercial treatment
facility. Specific waste characterization is not available for this waste
material.
2-7
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III. WASTE TREATMENT PROCESSES
Wastewater Treatment System
The wastewater treatment system consists of a mixing tank, an aeration
tank, a gravitator, and a discharge holding tanker. The mixing tank and
aeration tank are both open, above ground concrete tanks with a capacity of
30,000 gallons. The wastewater flow enters the mixing tank on a batch
operation basis and is evenly distributed through the use of a slow speed
mixer.
After thorough mixing, the wastewater is directed to the aeration tank.
The objective of the extended aeration phase of treatment is to reduce the
Chemical Oxygen Demand (COD) of the wastestream through biological digestion.
The system uses a fixed aerator to provide the oxygen and mixing required by
extended aeration. At current flow rates, the retention time of this tank is
about 30 days.
After aeration, the wastewater flows to an above ground, circular
gravitator and then to a tanker. The system effluent is stored in this tanker
until the tanker is full. At that time a contract laboratory, Texas
Environmental, Incorporated, is contacted to take and analyze samples of the
wastewater discharge. Upon receiving the results of this analysis, the City
of Port Arthur allows CLTL to discharge the effluent to the municipal sanitary
sewer system. The dimensions and descriptions of the tanks used during the
wastewater treatment process are presented in Table 1.
Container Storage
The small amounts of residue remaining in uncleaned tankers is removed and
containerized. This is accomplished by heating the trailer with steam and
flushing residues out the rear drain into a drum or bucket. Due to the
possibility of chemical reaction, the residue of two different tankers is
never placed in the same container. These containers are sealed and stored
under the 90 day rule on site until the quantity is sufficient to constitute a
shipment to an off site facility for treatment or disposal. Therefore, this
is not a RCRA covered container operation.
2-8
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TABLE 1. DIMENSIONS OF WASTEWATER TREATMENT TANKS AT CHEMICAL
LEAMAN TANK LINES IN PORT ARTHUR, TEXAS.
Mixing Tank;
description
dimension
capacity
mixer
open, above ground, rectangular
19 ft. x 19 ft. x lift.
30,000 gallons
fixed, 3 Hp
Aeration Tank;
description
dimension
capacity
aerator
Grayitator
description
diameter
depth
Discharge Holding^Tanker
capacity
open, above ground, rectangular
19 ft. x 19 ft. x 11 ft.
30,000 gallons
fixed, 7.5 Hp
cylindrical, cone-shaped bottom
5 ft. (approx.)
10 ft. (approx.)
5000 gallons
2-9
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IV. SAMPLING INFORMATION
Sample Location Description
Liquid samples were taken from two locations at CLTL, one at the effluent
of the tanker cleaning facility and one from the mixing tank. In addition, a
composite dust sample was obtained from the facility grounds (Figure 1).
Cleaning Facility Outflow
The effluent from tanker cleaning operations was sampled as it entered the
sump leading to the wastewater treatment system (DF-1A-E). The liquid was
quite agitated and warm (110°F) at this point. In Figure 1, this location is
denoted as sample point A.
Mixing Tank
The mixing tank was sampled at sample point B in Figure 1 (MX-1A-E). The
tank had a dark blue color and an organic wastewater smell. Sample
temperature was 48°F.
Composite Dust Sample
A dust sample was collected near the facility boundary (SL-1A-C) between
the path used by entering tankers and the fenceline (sample point C in Figure
1). Drainage at the facility is into this dirt area from the paved and
graveled surfaces around the cleaning building. Two samples were collected
with stainless steel scoops from the top centimeters of dirt and placed in
500 ml amber jars for later analysis of metals, heavy organics, pesticides,
and PCBs.
2-10
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Quality Assurance
Sampling procedures were employed as described in the Quality Assurance
Project plan dated 30 October 1984. Liquid samples were collected in
quintuplicate, as a standard procedure, with one of the five samples retained
by the facility as a split. The remaining quadruplicate liquid samples were
returned to the GCA Analytical laboratory in Bedford, HA, where they were
received into the sample bank.
Sample custody and handling procedures included the use of sample tags,
chain-of-custody sheets, refrigeration of samples between sampling and
analysis, and shipping of samples in coolers sealed with custody seals. In
addition, each sample was assigned a unique sample code which linked it to the
facility, the source, and the sample point.
V. SAMPLE ANALYSIS
Analytical Summary
Tables 2 through 6 provide the analytical summary reports for the samples
collected during the site visit (see Appendix A). These tables present the
major compounds quantified by GCA Corporation/Technology Division. The actual
data report sheets are provided in Appendix B.
Analytical procedures are outlined in Appendix D. Aqueous samples were
analyzed for volatile organics; soil samples were analyzed for extractable
organics, pesticides and PCBs, and trace metals. These sections in Appendix D
should be referenced for further information.
Quality Assurance
Chain of custody and quality control protocols for the relevant analyses
were followed as detailed in Appendix E. Organic analyses required the use of
surrogate spikes as part of the quality control procedures. Data for these
recoveries are presented in Table 7 for volatile organics and in Table 8
extractable organics.
2-11
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TABLE 2. LIQUID SAMPLE ANALYSIS OF THE MIXING TANK AT THE CHEMICAL
LEAHAN TANK LINES, INC. FACILITY IN PORT ARTHUR, TEXAS
a,b
Cotpounds Detected Concentration (ug/1)
Methylene chloride 13CO
Acetone 130
Chlorofon 36
Toluene 47
TOTAL HALOGENATED OR6ANICS 1336
TOTAL OXYGENATES OR6ANICS 130
TOTAL AROHATICS 67
TOTAL UNIDENTIFIED OR6AHICS 1191
TOTAL NMHC 2724
s
a
Analysis of saiple 42624 by 6CA Corporation using Finn MAT DMA.
b
ug/1 = ppb assuiiag a density of 1.
2-12
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TABLE 3. LIQUID SAMPLE ANALYSIS FRQN THE OUTFLOW PIPE AT THE CHEMICAL
LEAHAN TANK LINES, INC. FACILITY IN PORT ARTHUR, TEXAS
Cotpounds Detected Concentration (ug/1)
Chlorofors Ifc
Tetrachloroethylene 12
TOTAL HAL06ENATEO ORSANICS 28
TOTAL NMHC 28
a
Analysis of saiple 42628 by ECA Corporation using Finn HAT ONA.
b
ug/1 - ppb assuting a density of 1.
2-13
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TABLE 4. ICAP ANALSIS OF COMPOSITE SOIL SAHPLES FROM THE CHEHICAL
LEAHAX TANK LINES, INC. FACILITY IH PORT ARTHUR, TEXAS
ajb
Eleaent Concentration (ug/I)
Aluainua
Antiaony
Arsenic
Bariua
Beryl liua
Boron
Cadaiui
Calciua
Chroaiua
Cobalt
Copper
»
Iron
Lead
Hagnesim
Hanganese
Holybdenua
Nickel
Ssleniui
Silicon
Silver
Sodiua
Strontiui
Thailiui
Tin
Titaniui
Vanadiui
Zinc
c
1BOO
c
(3.0
<3.0
49,4
O.BSi
3,52
7,98
64300
12.5
1.87
16,2
3580
140
3000
107
<0.4
43,7
c
<4.0
294
<0.6
c
450
118
c
3
<0.8
54.9
4.9
57.1
a
Analysis of saaple 42815 by GCA Corporation using ICAP.
b
ug/g = licrograas per graa.
c
These values should be considered seal-quantitative due to severe
tatrix interferences encountered during the analysis.
2-14
-------
TABLE 5. ANfiLYSIS QF COMPOSITE SOIL SAMPLES FROM THE CHEMICAL
LEAMAN TANK LINES, INC. FACILITY IN PORT ARTHUR, TEXAS
Paraaeter
alpha-BHC
beta-BHC
delta-BHC
gaisaa-BHC
Toxaphsne
a,b
Concentration tag/kg)
<0,10
<0.50
<0.50
<0.10
30
a 63
Analysis of saaple 42315 by GCA Corporation using GC w/Ni ECD.
b
sg/kg = ppo assusing a density of 1.
2-15
-------
TABLE fe. BASE/NEUTRAL EXTRACTABLES ANALYSIS QF SURFACE SOIL TAKEN FRCK
COMPOSITE SOIL SAMPLES AT THE CHEJ1ICAL LEAHAN TANK LINES FACILITY
IN PORT ARTHUR, TEXAS
a
Paraaeter Concentration (eg/kg)
Bistf-etnylhexyUphthalate SB
a
Analysis o-f saaple 42815-BN by SCA Corporation using 6C/H5.
2-16
-------
TABLE 7. SURROGATE RECOVERIES - VOLATILE ORGANICS.
TANK LINES, PORT ARTHUR, TEXAS.
CHEMICAL LEAMAN
Percent Recoveries
Sample
Identification
LC-MX-1D
LC-OF-1D
Method blank
GCA
Control No.
42624
42628
3/6/85
Average Percent Recovery
Relative Standard Deviation (%)
D8
toluene
99
95
99
98
Bromo-
flyprobenzene
101
78
104
94
14
D4 - 1,2-
dichlorpethane
97
67
95
86
17
2-17
-------
TABLE 8. SURROGATE RECOVERIES - EXTRACTABLE ORGANICS.
CHEMICAL LEAMAN TANK LINES, PORT ARTHUR, TEXAS.
Sample GCA
Identification Control No.
LC-SL-1A 42815
Method blank QC986
Spiked Sample QC987
Duplicate Sample QC988
D5-
Nitro-
benzene
52
131
27
24
Percent Recoveries
2- D^- 2- 2,4,6-
Fluoro- ter- V$ - fluoro- tribromo-
biphenyl phenyl phenol phenol phenol
47 27 67 65 83
102 105 0.7 54 34
25 22 83 82 118
23 18 73 70 102
Average Percent Recovery
Relative Standard
Deviation(%)
59
50
49
37
43
41
56
37
68
12
84
36
2-18
-------
Section 3.
Gulf Oil Products, Port Arthur Refinery
Port Arthur, XX
3-1
-------
TABLE OF CONTENTS
Section Page
I. Introduction. 3-6
II. Waste Characterization 3-6
Wastewater Treatment 3-7
Landfill 3-7
III. Waste Treatment Processes 3-11
Wastewater Treatment Process 3-11
Landfill 3-18
IV. Sampling Information 3-19
Sampling Location Description 3-19
Quality Assurance. 3-21
V. Sample Analysis 3-22
Analytical Summary 3-22
Quality Assurance 3-22
3-2
-------
LIST OF TABLES
Table
1 Approximately Wastewater Discharges by Source during
Normal Operation at Gulf Oil Company in Port Arthur,
Texas 3-8
2 Class I Non-hazardous Waste Discharged to Number 7 Section
of Number 3 Reservoir at Gulf Oil Company in Port Arthur,
Texas, during 1984 3-8
3 Waste Materials Landfilled from January 10 through 24, 1984
at the Gulf Oil Company in Port Arthur, Texas 3-9
4 Waste Materials Landfilled at Gulf Oil Company in
Port Arthur, Texas during 1984 3-9
5 1984 off Site Disposal of Solid Wastes from Gulf Oil
Company in Port Arthur, Texas 3-10
6 Wastewater Treatment Tank/Basin Dimensions and
Description for Gulf Oil Company in Port Arthur, Texas.... 3-14
7 Liquid Sample Analysis of the Field Bias Blank for the
Gulf Oil Refinery in Port Arthur, Texas 3-23
8 Liquid Sample Analysis from the Final Clarifier at the
Gulf Oil Refinery in Port Arthur, Texas 3-24
9 Liquid Sample Analysis from the Inlet Surface of the DAF
Clarifier at the Gulf Oil Refinery in Port Arthur, Texas.. 3-25
10 Liquid Sample Analysis from the Oxidation Pond at
the Gulf Oil Refinery in Port Arthur,
Texas 3-26
11 Liquid Sample Analysis from Storm Basin No. 2 at the Gulf
Oil Refinery in Port Arthur, Texas 3-27
12 Liquid Sample Analysis of Influent of Section No. 7 at
the Gulf Oil Refinery in Port Arthur, Texas 3-28
13 ICAP Analysis for Metals in Soil Core Samples from the
Upper Landfill at the Gulf Oil Refinery in Port
Arthur, Texas 3-29
14 ICAP Analysis for Metals in Surface Soil Samples from the
landfill at the Gulf Oil Refinery in Port Arthur,
Texas 3-30
3-3
-------
List of Tables (continued)
Table
15 Base/Neutral Extractables Analysis of Soil Core Samples
from the Landfill at Gulf Oil Refinery in Port Arthur,
Texa ; 3-31
16 Acid Extractables Analysis of Soil Core Samples from
the Landfill at the Gulf Oil Refinery in Port Arthur,
Texas .... 3-32
17 Surrogate Recoveries - Volatile Organics. Gulf Oil
Company, Port Arthur, Texas.. 3-33
18 Surrogate Recoveries - Extractable Organics. Gulf Oil
Company, Port Arthur, Texas'.'. 3-34
3-4
-------
LIST OF FIGURES
Figure Page
1 Facility map of wastewater treatment system at Gulf Oil
in Port Arthur, Texas 3-12
2 Flow diagram of refinery wastewater treatment system at
Gulf Oil in Port Arthur, Texas '. 3-13
3 Liquid"sampling locations at Gulf Oil - U.S. Port
Arthur Refinery, Texas 3-20
3-5
-------
Site:
Gulf Oil Company
U.S. Port Arthur Refinery
West 7th Street
Port Arthur, Texas 77640
FCID:
Site Contact:
Latitude:
Longtitude:
TXD008090409
29° 51'
93° 58'
Mr. Don Williams, Environmental Engineeer
(409)985-1661
Field Visit Personnel: Don Williams, Gulf
Terry Harrison, EPA
Penny Lassiter, EPA
Rich Roat, GCA/Measurements
Tom Warn, GCA/Engineering
Time and Date:
January 24, 1985
12:30 PM
I. INTRODUCTION
Gulf Oil Company is a petroleum refinery located in rural Port Arthur,
Texas. The facility was originally built in 1901 and covers approximately
3000 acres. The major products from this facility include primary fuels,
ethylene, benzene, lubrication substances, charcoal lighter, and cumene.
Gulf Oil Company, Port Arthur, Texas became Chevron U.S.A. Inc., Port
Arthur, Texas on July 1, 1985. The use of the Gulf name in this report
reflects the facility operations at the time of the visit.
II. WASTE CHARACTERIZATION
The Gulf Oil refinery operates waste processing systems for process
wastewater and surface drainage. In addition, there is a Class II landfill
located on site. The waste materials and relative volumes handled by these
operations are described as follows.
3-6
-------
Wastewater Treatment
The wastewater generated at this facility is derived primarily from
manufacturing processes and stormwater runoff. Though it is monitored daily
for parameters such as BOD, COD, ammonia, phenol, and sulfide content,
information regarding the concentration of specific organic compounds was not
available. A generalized breakdown of the wastewater generated under normal
conditions is provided in Table 1. Additionally, a description of the
wastewater discharged to Section No. 7 of No. 3 Reservoir is presented in
Table 2.
The process wastewater high in ammonia and/or sulfide concentration and
the overflow from Section No. 7 of No. 3 Reservoir are processed through the
activated sludge wastewater treatment system. This relates to approximately
2.1 MGD of wastewater influent to the system. The remaining process
wastewater is directed through an oil/water separator tank and combines with
the activated sludge treatment system effluent in the transport canal. The
transport canal also receives any excess rainwater which overflows the storm
surge basin during storm events.
Landfill
The landfill at the Gulf Oil refinery is utilized to dispose miscellaneous
plant waste, provided it passes a leachate test and can be classified Class II
solid waste. No liquids are accepted. A description of the waste material
disposed at the landfill during the two weeks prior to the site visit is
presented in Table 3. Table 4 provides information on the waste material
landfilled on-site during 1984. The solid waste materials disposed off site
are described in Table 5.
3-7
-------
TABLE 1. APPROXIMATE WASTEWATER DISCHARGES BY SOURCE DURING NORMAL
OPERATION AT GULF OIL COMPANY IN PORT ARTHUR, TEXAS
Source
Process Wastewater
Rainwater Overflow
Cooling Tower Slowdown
Treating Water Losses
Average 1984 Throughput
Percent of Total
49%
377.
107.
47.
Volume (MGD)a
11.5
8.7
2.3
0.9
23.4
aVolumes are based on the average daily discharge during 1984.
^Refers to the rainwater overflowing surge basin during storm events.
TABLE 2. CLASS I NON-HAZARDOUS WASTE DISCHARGED TO NUMBER 7 SECTION
OF NUMBER 3 RESERVOIR AT GULF OIL COMPANY IN
PORT ARTHUR, TEXAS DURING 1984.
Texas Waste Code
104100
340150
EPA Waste
Code
Waate_De8criptiQn
NA Sour Water Stripper Bottoms
(This material is actually a
wastewater which is treated by
the NPDES permitted wastewater
treating system.)
NA Wastewater Treating Unit
Biosludge
Volume^(tons)
639,261
NA
3-8
-------
TABLE 3. WASTE MATERIALS LANDFILLED FROM JANUARY 10 THROUGH 24, 1984
AT THE GULF OIL REFINERY IN PORT ARTHUR, TEXAS.
_Waste_Descriptign_
FCC Charge Tank Bottoms
Elemental Sulfur
Pipe Conduct Sludge
FCC Catalyst Fines
Vo lume_ .(yds. £)_
156
45
69
69
TABLE 4. WASTE MATERIALS LANDFILLED AT GULF OIL REFINERY IN
PORT ARTHUR, TEXAS DURING 1984.
Texas Waste Code EPA Waste
205060
270770
270900
251640
NA
MA
NA
NA
Wagte_Description
Still Bottoms/Tank Bottoms
Misc. Plant Wastes
FCC Catalyst Fines
Dirt, oil, water, wax
Vo lume _._(t ons )
5435
9187
858
8603
3-9
-------
TABLE 5. 1984 OFF SITE DISPOSAL OF SOLID WASTES FROM GULF OIL COMPANY
IN PORT ARTHUR, TEXAS
Texas Waste Code
EPA Waste
Code
Waste Description
Volume (tons)
Class I Hazardous Waste
970210 D001
972280 U134
973130 D003
940110 D007
950050 K051
979310 P110
910120 D001, U159
950530 K049
979850 U019, U055, U056
979630 P024
900630 D002
950130 D009
984990 D001
910650 D001
979290 D002
959210 D001
913810 D001
950220 K052
Spent Catalyst
H.F. Acid Contaminated Mat.
Iron Sulfide
Chromate Bearing Sludge
API Separator Sludge
TEL Contaminated Material
Paint Solvents
Filter Cake Slurry
Dirt, Organic Contaminated
Analine Contaminated Material
Caustic Wastes
Mercury Sludges
Adhesive Waste
Paint Waste Liq.
Acid Contaminated Material
Tank Bottoms
Sealant
Tank Bottoms-TEL
669.5
207
22.4
235
585
11
0.3
481
37
10 LBD
209.6
0.12
0.5
9
5
531.4
1
14.4
179390
152180
179850
173880
179370
174200
179430
Class I Nonhazardous Wastes
NA Asbestos 229
NA Tank Bottoms 108
NA Dirt, Organic Chem.
Contaminated 53.7
NA PCB Capacitators 73 LBD
NA Asbestos Contaminated Material 135
NA Antimony Oxide Contaminated Mat. 0.3
NA PCB Contaminated Mat. 1 LBD
250060
270900
280620
280560
279760
279450
NA
NA
NA
NA
NA
NA
Class II Solid Wastes
Still Bottoms/Tank Bottoms
FCC Catalyst Fines
Oily Trash
Trash-Misc. Combustible
Plant Refuse, General, Misc.
Empty Containers
1203
1942
7511
1133
9569
3.4
3-10
-------
III. WASTE TREATMENT PROCESSES
Waatewater^Treatment^Prgcess
The wastewater treatment process at the Gulf Oil refinery is subdivided
into two operations, the dirty water treatment system and the surface drainage
treatment system, respectively (see Figure 1). A schematic flow diagram of
these two systems is illustrated in Figure 2.
The dirty water treatment system consists of four API separators, two
dissolved air floatation (DAF) units, two aeration basins, three final
clarifiers and Section 7 of No. 3 Reservoir. The surface drainage treatment
system employs Tank 1912, an oil/water separator, and a Stormwater Surge
Basin #2. The discharges from both systems are released to the transport
canal and finally to the oxidation pond. The dimensions and descriptions of
the tanks and basins utilized by both treatment systems are provided in
Table 6.
Dirty Water Treatment System
API^separator. The four API separators represent the initial phase of the
dirty water treatment system. These are rectangular tanks equipped with
floating roofs. Scrapers are pulled the length of the tanks, skimming off the
oil layer and returning it to the oil recovery unit.
The sludges and heavy ends contained in the incoming wastewater are
allowed to settle to the bottom. These bottom layers are then removed on an
as needed basis through the use of vacuum trucks. The waste material is then
shipped off site to a commercial disposal facility. The quantity of API
sludges transferred off site in 1984 amounted to 585 tons.
DAF_ units. The wastewater overflow from the API separators is pumped to
one of two DAF units on site. These units are utilized to increase phase
separation, skimming the top oil film and returning it to the oil recovery
unit. These open, circular, above ground tanks are equipped with skimmer arms
and a diffused air system which maintains a gentle rolling at the surface. A
3-11
-------
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FlRura 1. Facility map of wastowater treatment system at Gulf Oil in Port Arthur, Texas.
-------
CO
I
.SURFACE
DRAINAGE
EMERGENCY
OVERFLOW
PROCESS
WASTEWATER
COLLECTION
SYSTEM
POND 7
OIL/WATER
SEPARATION
TANK 1912
TRANSPORT
CANAL
API
SEPARATOR
PUMP
STATION
310
DAF
UNITS
ACTIVATED
SLUDGE
DIRTY WATER
TREATMENT UNIT
CLARIFIERS
OXIDATION
POND
OUTFALL
Figure 2. Flow diagram of refinery wastewater treatment system at Gulf Oil in Port Arthur, Texas.
-------
TABLE 6. WASTEWATER TREATMENT TANK/BASIN DIMENSIONS AND DESCRIPTION
FOR GULF OIL COMPANY IN PORT ARTHUR, TEXAS
Dirty Water Treatment System
API Separators
description
dimensions
DAF Units (2)
description
diameter
depth
capacity
Aeration Basins (2)
description
dimensions
aerators (24)
Clarifiers (3)
description
diameter
depth
capacity
Section ..No. 7
description
surface area
depth
Transport^ Canal
description
length
width
depth
Oxidation Pond
description
surface area
depth
capacity
rectangular tanks with floating roofs
20 ft. x 130 ft. x 9 ft.
circular, above-ground, open
60 ft.
11 ft.
30,000 gal.
earthen, retangular, turbulent
100 ft x 300 ft. x 10 ft.
Ashbrook-MSA; floating, 20 @ 60 Hp, 4 @ 50 Hp
circular, above-ground, open
80 ft.
6.5 ft.
220,000 gal.
earthen, rectangular
170 acres
12 ft. (est. 8 ft. of sludge)
open, mostly earthen
4000 ft. (approx.)
30 ft. (average)
6 ft. (estimated average)
earthen, L-shaped
646 acres
5 ft. (approx.)
1.08 billion gallons
(continued)
3-14
-------
TABLE 6. (continued)
Surface. Drainage^ Treatment System;
Tank, 1912
description circular, above-ground, floating roof
diameter 102 ft.
depth 40 ft.
flow capacity 18,000 GPM
Storm Surge
description earthen, rectangular, corregated steel sides
surface area 225,000 sq. ft.
depth 10 ft. (approx. average)
3-15
-------
circular baffle is used to prevent the separated oil film from overflowing
into the outer weir trough. The wastewater overflow from these units flows by
gravity to the aeration basins.
Aeration basins. There are two aeration basins utilized on site for
biological treatment of process wastewater, via activated sludge. The
influent to the aeration system enters the first basin, which in turn
overflows into the second basin. Both basins are earthen in structure and
equipped with a dozen floating aerators. The surface is highly turbulent and
the system appeared to be well mixed. The overflow from the second basin is
directed to one of three final clarifiers.
Clarifiers. There are three circular clarifiers located on site. These
tanks are open, above ground, and equipped with skimming arms which return any
floatables to the aeration basin. The primary purpose of the these units is
to settle out the activated sludge and discharge the liquid overflow into the
transport canal.
Depending on the needs of the biological system, a percentage of the
settled activated sludge is returned to the aeration basins. The remaining
sludge is disposed by pumping it to Section 7, Reservoir No. 3.
Section No. 7.,_ Reservoir^ Pond 7 serves two functions for the wastewater
treatment processes at Gulf. It is used primarily as a holding basin for
excess sour water (153 million gallons in 1984). This water is pumped back to
the aeration basins at whatever rate the biological system can treat. In
addition, Section 7 is used as a disposal unit for the excess biological
sludges.
At the time of the site visit, Section 7 was having a surface oil layer
removed by vacuum truck. Mr. Don Williams of Gulf Oil explained that the oil
layer was a result of treatment practices (i.e., used as a middle layer solids
separator) of many years ago. He further stated that Gulf has been involved
in cleaning off the oil layer for several months now. They anticipated
another two months until their clean-up efforts would be completed.
3-16
-------
In addition to the oil layer, Section 7 displayed a noticeable amount
(about 15 percent of the total surface area) of floating solids. There was
also a strong odor of hydrogen sulfide present near the basin.
Surface Drainage Treatment System
Tank_1912. This tank is a circular, above-ground oil/water separation
unit equipped with a floating roof. It is used to recover oil from surface
water drainage and some process wastewater (e.g., the condensate drained from
storage tanks). The tank has a capacity for treating 18,000 gpm, but the
average flow is maintained at closer to 6500 gpm. The oil layer separated
from the wastewater is pumped to the oil recovery unit. The treated
wastewater is discharged to the transport canal.
Mr. Williams stated that a second identical oil/water separation tank was
under construction and that it should be in operation in a couple of months.
At that time, Gulf plans to equip the tanks to accept flow from the storm
Surge Basin, No. #2. This capability currently does not exist.
Storm Surgei Basin No.. 2. This rectangular, earthen basin is utilized to
retain stormwater runoff from throughout the plant. The sides of the basin
have been reinforced with corregated steel piling. The basin is operated by
allowing the oily stormwater to collect and then skimming the oil layer off
with permanently mounted pumps. There is a weir on the north end which allows
overflow to enter the transport canal. A floating, vinyl baffle system is
used to prevent the oil layer from escaping into the transport canal.
At the time of the site visit, there was no appreciable flow into the
basin. The sides of the basin displayed oily residues on four to five feet of
freeboard. No overflow to the transport canal was observed.
Transport Canal
The transport canal represents about 4000 feet of open earthen channel.
It is highly variable in width, ranging from 10 to 300 feet across. It is
equipped with a pair of baffles which can be used to retain any oils that may
escape Storm Surge Basin No. 2 during intense storm events.
3-17
-------
At the end of the canal, pump station 310 directs the flow into an
above-ground 48 inch pipeline. This pipeline discharges as influent into the
oxidation pond.
Oxidation Fond
The oxidation pond is an earthen impoundment with a surface area of
646 acres. The average depth is estimated at five feet and the capacity at
over a billion gallons. It receives the wastewater discharges from both the
dirty water treatment system and the surface drainage treatment system. In
1984 this amounted to approximately 23.4 HGD.
The outfall consists of a concrete weir system and is located at the
opposite end of the basin from the influent pipe. The basin is equipped with
several mixers which are used for pH adjustment. These are located directly
before the outfall area. Mr. Williams explained that the purpose of pH
adjustment was to meet permit requirements which become difficult to obtain
due to the presence of algae during the summer months. The overflow from the
basin is released into the main outfall canal.
Landfill
Gulf Oil operates a Class II landfill on site at their Port Arthur, Texas,
refinery. The landfill has been in service since 1971 and is 26.6 acres in
size. The operation consists of using a large dragline to dig disposal
areas. A pile of spent clay from a lube filtration unit is located near the
disposal area and is used for mixing with the waste materials landfilled. The
materials are hauled to the site by dumptrucks at a rate of five to twenty
truck loads per day. The dragline loader then mixes the waste and clay as it
fills the disposal area. When the disposal area is full, the process begins
all over at a different disposal area at the landfill.
3-18
-------
IV. SAMPLING INFORMATION
Sampling_Lpcatign DescrlBtion
Liquid samples for five of the impoundments and open tanks within the
wastewater treatment system were sampled (Figure 3):
o the DAF unit,
o Pond 7 influent,
o the final clarifier effluent,
o separator #2, and
o the 646 acre oxidation basin.
In addition to the liquid samples, the landfill was also sampled. Sample
cores were taken from the landfill, and a soil composite was also obtained.
DAF Unit
Two locations in one of the DAF units were sampled (Figure 3a): one spot
at the influent (DAS-1A-E) and one at the effluent (DAE-1A-E). As these were
aerated units, there was unavoidably some formation of air bubbles in the vial
after sampling. The liquid in the DAF units was dark, covered with solids and
possessed a strong organic smell. Influent and effluent temperatures were
both 78°F.
Section 7 Influent, Reservoir No. 3
The influent to Section 7 was sampled through the sour water pipe that
leads to the impoundment (SO-1A-E). Despite repeated attempts, the sample
taken was aerated due to turbulence at the sampling valve. Sample temperature
was 84°F. Section 7 itself was darkly colored and had a strong organic
smell. It was impossible to reach the aqueous layer in the impoundment
directly due to the steep berm and heavy oil layer near the shoreline.
3-19
-------
•INFLUENT
-EFFLUENT
3o DAF UNITS
3c STORM BASIN
3b FINAL CLARIFIERS
INFLUENT
POND #7
EFFLUENT
3d OXIDATION BASIN
Figure
3. Liquid sampling locations at Gulf Oil - U.S. Port Arthur refinery, Texas.
-------
Final Clarifier
A sample (C1-1A-E) of the combined effluents from the final clarifiers
(Figure 3b) was obtained. The clarifiers had a clear, calm surface. Sample
temperature was 60°F.
Separator #2
Separator #2 (Figure 3c) was sampled at the influent (SB-1A-E). The
impoundment was clear and calm at the time of the visit. Sample temperature
was 51°F.
Oxidation Pond
This 646 acre impoundment (Figure 3d) was sampled at the influent
(OXI-1A-E) and the effluent (OXE-lA-E). The impoundment was calm with some
oil evident on the surface near the influent. An oil sheen was observed over
the entire surface. Influent temperature was 59°F, and effluent temperature
was 50°F.
Landfill
Soil cores were taken from the landfill (LO-1A-C) at the active face.
This surface was disturbed due to daily sludge disposal. Also collected was a
fugitive dust sample. Soil at the landfill's surface was gathered with a
stainless steel scoop and placed in a 500 ml jar. This soil sample was a
composite from several locations at the landfill. A split was given to Gulf
Oil. The sample was analyzed for metals, heavy organics, pesticides and PCBs.
Quality Assurance
Sampling procedures were employed as described in the Quality Assurance
Project Plan dated 30 October 1984. Liquid samples were collected in
quintuplicate, as a standard procedure, with one of the five samples retained
3-21
-------
by the facility as a split. Soil core samples were collected in triplicate.
The facility split for these samples was provided in a 500-ml amber glass
bottle due to the limited supply and expense of the custom-built soil core
samples. The remaining quadruplicate liquid samples and the duplicate soil
samples were returned to the GCA Analytical Laboratory in Bedford, MA where
they were received into the sample bank.
Sample custody and handling procedures included the use of sample tags,
chain-of-custody sheets, refrigeration of samples between sampling and
analysis, and shipping of samples in coolers sealed with custody seals. In
addition, each sample was assigned a unique sample code which linked it to the
facility, the source, and the sample point.
V. SAMPLE ANALYSIS
Analytical Summary
Tables 7 through 16 provide the analytical summary reports for the process
samples collected during the site visit (see Appendix A). These tables
present the major compounds quantified by GCA/Technology. The actual data
report sheets for each respective sample are provided in Appendix B.
The analytical procedures are discussed in Appendix D. Aqueous samples
were analyzed for volatile organics. Soil cores and surface soil samples were
analyzed for extractable organics and trace metals. These particular sections
in Appendix D should be referred to for information on these analyses.
(Quality. Assurance
Chain of custody procedures and quality control protocols are detailed in
Appendix E. The quality control sections pertinent to the analysis of samples
from Gulf Oil are those on volatile organics, extractable organics and trace
metals. For volatile organics, surrogate spikes were used as part of the
quality control protocol. These results are reported in Table 17. The
analysis for extractable organics also employed a similar procedure, and are
reported in Table 18.
3-22
-------
TABLE 7. LIQUID SAHPLE ANALYSIS OF THE FIELD BIAS BLANK
„ -_ FOR ™E JSiHLJE R.F1N!R! IN P.RI ARJE?' IE.?S_
-_„.
Coapounds Detected Concentration (ug/1)
Acetone 67
a
Analysis of saaple 42431FBB by GCA Corporation using BC/RS.
b
ug/1 = ppb assuiing a density of 1.
3-23
-------
TABLE 8. LIQUID SAMPLE ANALYSIS FROH THE FINAL CLARIFIES
AT THE GULF OIL REFINERY IN PORT ARTHUR, TEXAS
a,b
Coipounds Detected Concentration (ug/I)
Acetone 75
1,1,1-Trichloroethane 7
a
Analysis of saaple 42759 by 6CA Corporation using 6C/BS.
b
ug/1 - ppb assuring a density of 1.
3-24
-------
TABLE 9. LIQUID SAMPLE ANALYSIS FROM THE INLET SURFACE OF THE DAF
CLARIFIER AT THE GULF OIL REFINERY IN PORT ARTHUR, TEXAS
a,b
Coipounds Detected Concentration (ug/1)
Benzene 64000
Acetone 9500
Methyl ene chloride 4500
Chlorofora 2000
Toluene 1400
TOTAL HALQ6ENATED ORSANICS 6500
TOTAL OXYGENATED ORSANICS 9500
TOTAL ARQHATICS 78000
TOTAL NMHC 94000
a
Analysis of saaple 42766 by 6CA Corporation using 6C/HS.
b
ug/1 = ppb assuring a density of 1.
3-25
-------
TABLE 10. LIQUID SABPLE ANALYSIS FROH THE OXIDATION POND
AT THE GULF OIL REFINERY IN PORT ARTHUR, TEXAS
38aaa8aasaaaaaga3gaaaaasssagaaaag.aa3asaaggasaassgsaaaasasaaaagagBaasa3aaa3saaaaaa3a3ggsaaaaaaaaaaag
C
Concentration (ug/I)
a b
Cocpounds Detected Analysis 1 Analysis 2
Toluene 4900
Benzene 11200
Acetone 55 1700
ftethylene chloride 1700
Ethylbenzene 600
Styrene 500
Chloroform 4 4300
TOTAL HALOGENATED OR6ANICS 4 1700
TOTAL OXYGENATED ORSANICS 55 6000
TOTAL ARQRATICS 17200
TOTAL WIHC 59 24900
saaasg.ggagggaaagsaaaaasaasggggggsagggTaaagaassgasgsasaga'sagggTggaaaaggaa
a
Analysis of saiple 42771 by 6CA Corporation using 6C/HS. (Oxidation pond,effluent)
b
Analysis of saiple 42774 by 6CA Corporation using 6C/MS. (Oxidation pond,influent)
c
ug/1 = ppb assuming a density of 1.
3-26
-------
TABLE 11. LIQUID SAMPLE ANALYSIS FROM STORM BASIN NO. 2
AT THE GULF OIL REFINERY IN PORT ARTHUR, TEXAS
C
Concentration (ug/1)
a b
Coipounds Detected Analysis 1 Analysis 2 Average
Chlorofor* 113 85 99
Acetone 46 64 65
Brosodichloroiethane 17 14 15.5
TOTAL HALOGENATED OR6ANICS 130 99 114.5
TOTAL OXYGENATED OR6ANICS 66 44 45
TOTAL NHHC 196 163 179.5
SSSSSSS5SS5S5SSSSa5SS5S5SSSS5SSSSSSSSSSSSSSSSSSSSSSS5SBBS5BaSSSSSSSSSaSSSSSSS3SSS53555SSS5
a
Analysis of duplicate saiples for ID no. GO-SB-ID by 6CA Corporation using 6C/MS.
b
GCA control nos. are 42779 -KA) and 42779-2 (B), respectively.
c
ug/1 = ppb assuming a density of 1.
3-27
-------
TABLE 12. LIBUIO SAHPLE ANALYSIS OF INFLUENT OF POND 17
AT THE BULF OIL REFINERY IN PORT ARTHUR, TEXAS
a,b
Cospounds Detected Concentration (ug/1)
2-Butanone (HEX)
Benzene
Acetone
Toluene
Hethylene chloride
Total Xylenes (o,i,p)
TOTAL HALQ6ENATED QR6ANICS
TOTAL OJYEE.NATED QRGAN1CS
TOTAL AROHATICS
TOTAL MHHC
8800
7900
6500
4800
4000
900
4000
15300
13600
32900
a
Analysis of saiple 42782 by 6CA Corporation using 6C/HS.
b
ug/1 s ppb assuaing a density of 1.
3-28
-------
TABLE 13. ICAP ANALYSIS FOR METALS IN SDIL CORE SAMPLES FROM THE
UPPER LANDFILL AT THE GULF OIL REFINERY IS PORT ARTHUR, TEXAS
a~b
Eleaent Concentration (ug/q)
c
Al minus 41000
c
Antiagny 7.9
Arsenic 20
Bariui 75.1
Berylliua 8.52
Boron 11.8
Cadiiui 0.297
Calciui 13400
Chroniui 602
Cobalt 5.94
Copper 381
Iron 35800
Lead 290
Maqnesiui 6300
Manganese 197
Holybdenua <0.4
Nickel 63.8
c
Seleniua <4.0
Silicon 151
Silver <0.6
Sadiui 14000
Strontiua 66
Thalliui <3.0
Tin 27.5
Titaniut 176
Vanadiui 74
Zinc 401
a
Analysis of saaple 42BOS by 6CA Corporation using ICAP.
b
ug/g = licrograis per grai.
c
These values should be considered seal-quantitative due to severe
utrix interferences encountered during the analysis.
3-29
-------
TABLE 14. 1CAP ANALYSIS FOR METALS IN SURFACE SOIL SAMPLES FROM THE
LANDFILL AT THE SULF OIL REFINERY IN PORT ARTHUR, TEXAS
a,b
Elesent Concentration (ug/g)
c
Aluiinu 28000
c
Antiiony <3.0
Arsenic <3.0
Bariui 146
Berylliui 5.27
Boron 18.1
Cadiiui 1.49
Calciui 31800
Chroaiut 64.3
Cobalt 10
Copper 15.2
Iron 17300
Lead 190
Hagnesiui 28000
Manganese 591
Itolybdenui <0.4
Nickel 51.1
c
Seleniu* 24
Silicon 818
Silver <0.6
c
Sadim 630
Strontiui 53.3
c
Thalliui <3.0
Tin 14.7
Titaniui 250
Vanadiua 64
Zinc 78.2
a
Analysis of saiple 42813 by SCA Corporation using ICAP.
b
ug/g = licrograts per grat.
c
These values should be considered sesi-quantitative due to severe
•itrii interferences encountered during the analysis.
3-30
-------
TABLE 15. BASE/NEUTRAL EXTRACTABLES ANALYSIS OF SOIL CORE SAMPLES
„ _ _FRO« THE LANDFILL AT THE GULF OILjtEFINERY IN PORT ARTHUR, TEXAS
a
Paraseter Concentration lag/kg)
Nap thai ene 122
b c
2-flethyl napthalene 308
a
Analysis of saiple 42BOB BH by 6CA Corporation using 6C/HS.
b
Present but below detection Hiits of <350 iq/kq.
c
Units are ug/1.
3-31
-------
TABLE 16. ACID EXTRACTABLES ANALYSIS OF SOIL CORE SAMPLES FROK THE
LANDFILL AT THE GULF OIL REFINERY IH PORT ARTHUR, TEXAS
l
Pvaieter Concentration (ig/kg)
b
2,4-Diiethylphenol ?
sssssssssssssssssszsssssssssssassassssssassssssssssssssssssssssssssssssssssssrssa
a
Analysis of saiple 42808-A by BCA Corporation using 6C/HS.
b
Present but below detection liiits of <3S ig/kg.
3-32
-------
TABLE 17. SURROGATE RECOVERIES - VOLATILE ORGANICS.
GULF OIL, PORT ARTHUR, TEXAS.
Percent Recoveries
Sample
Identification
GO-CL-1D
GO-DAE-1C
GO-DAE-1D
GO-DAI-1C
GO-OXE-ID
GO-OXI-IC
GO-SB-ID
GO-SB-ID
GO-SO-1C
Method blank
Method blank
Method blank
GCA
Control NpA
42759
42762
42763
42766
42771
42774
42779A
42779B
42782
3/4/85
3/18/85
5/20/85
Average Percent Recovery
Relative Standard Deviation (%)
toluene
105
96
84
98
103
104
101
93
86
99
99
99
97
7
Bromo-
fluQrpbenzene
108
108
100
109
132
109
114
112
112
96
118
95
109
10
DA - 1.2-
dichlprpethane
128
71
107
95
103
87
69
64
113
128
85
105
96
22
3-33
-------
TABLE 18. SURROGATE RECOVERIES - VOLATILE ORGANIC.
GULF OIL COMPANY PORT ARTHUR, TEXAS
Sample
Identification
GO-CO-1A
Method blank
Spiked Sample
GCA
Control^Ng..
42808
QC986
QC987
Duplicate Sample QC988
Average Percent Recovery
Relative Standard
Deviation(%)
D5-
Nitro-
benzene
a
131
27
24
61
61
Percent Recoveries
2-
Fluoro-
btphenyl
a
102
25
23
D14-
ter-
phenyl
a
105
22
18
D5 -
phenol
20
0.7
83
73
2-
fluoro-
phenol
22
54
82
70
2,4,6-
tribromo
phenol
38
34
118
102
50
45
48
49
44
40
57
26
73
43
aCould not be calculated due to a large dilution factor for the sample.
3-34
-------
Section 4.
Lower Neches Valley Authority
Beaumont, TX
4-1
-------
TABLE OF CONTENTS
Section
AMMMMMMM*
I. Introduction ...*.* 4-5
II. Waste Characterization 4-6
III. Waste Treatment Process 4-6
Equalization Basin 4-6
Aeration Basin 4-10
Auxiliary Aeration Basin 4-10
Clarif iers 4-11
High Pressure Filter System. 4-11
IV. Sampling Information 4-12
Sample Location Description 4-12
Quality Assurance 4-14
V. Sample Analysis 4-14
Analytical Summary 4-14
Quality Assurance 4-22
4-2
-------
LIST OF TABLES
Table
1 Waste Volumes Contributed to LNVA by the Five User
Facilities, Beaumont, Texas 4-7
2 Basin/Tank Specifications for LNVA Facility in Beaumont,
Texas 4-9
3 Liquid Sample Analysis from the Equalization Tank Influent
at the Lower Neches Valley Authority Facility in
Beaumont, Texas 4-15
4 Liquid Sample Analysis from the Equalization Tank (Oil
Slick) at the Lower Neches Valley Authority Facility
in Beaumont, Texas 4-16
5 Liquid Sample Analysis from the Equalization Tank (Clear
Area) at the Lower Neches Valley Authority
Facility in Beaumont, Texas 4-17
6 Liquid Sample Analysis of Disposal Sludge at the Lower
Neches Valley Authority in Beaumont, Texas 4-18
7 Liquid Sample Analysis from Clarifier No. 2 at the Lower
Neches Valley Authority in Beaumont, Texas 4-19
8 Liquid Sample Analysis from the Organic - Aux Lagoon at the
Lower Neches Valley Authority in Beaumont, Texas • 4-20
9 Liquid Sample Analysis from the Aerator Outfall, Lower
Neches Valley Authority in Beaumont, Texas 4-21
10 Surrogate Recoveries - Volatile Organics. LNVA, Beaumont,
Texas 4-23
4-3
-------
LIST OF FIGURES
Figure Page
1 Treatment system schematic flow diagram, LNVA, Beaumont,
Texas 4-8
2 Sampling locations at LNVA treatment system, Beaumont,
Texas 4-13
4-4
-------
Site:
Site Contact:
Field Trip Personnel:
Visit Time and Date:
Lower Neches Valley Authority
North Regional Treatment System
7850 Eastex Freeway
Beaumont, Texas 77704
latitude 30° 04'N
longitude 94° 03'W
A.T. Hebert, Jr., Assistant General Manager
(409) 892-4011
A.T. Hebert, Jr., LNVA
Edmond A. Airhart, AOSI
Jim Durham, EPA
Penny Lassiter, EPA
Rich Roat, GCA/Measurements
Tom Warn, GCA/Engineering
January 23, 1985
8:30 a.m.
I.
INTRODUCTION
The Lower Neches Valley Authority (LNVA) North Regional Treatment System
represents a non-RCRA, privately owned, wastewater treatment facility located
on 19.1 acres in an highly industrialized section of Beaumont, Texas. The
facility began operations in 1976 and is operated under contract by Aware
Operating Services, Incorporated (AOSI).
Mr. Edmond Airhart, chief plant operator, conducted the tour of the
facility and provided information regarding the waste handling operations. He
stated that this facility provided secondary treatment to the process
wastewater from five industrial users. These users include: Mobil Oil
Corporation, Mobil Chemical Corporation, P.O. Glycol, Olin Corporation, and
Estech General Chemical Company. At the time of the visit, however, Estech
General Chemical Company was not in production and therefore was not
discharging wastewater to the LNVA facility.
4-5
-------
II. WASTE CHARACTERIZATION
The wastestream entering LNVA consists of the primary effluents (see
Table 1) from the five industrial users previsouly mentioned. Each of these
discharges is monitored by LNVA before they are combined to form the
vastewater influent that enters the treatment facility.
The monitoring consists of an on-line pH meter and temperature recorder,
a grab sample every four hours, and a 24 hour composite sample. These samples
are analyzed for COD, BOD, TSS, VSS, TKN, oil and grease, phosphorous, lead,
total chromium, phenols, ammonia, and sulfides. This information is then used
to adjust the flow rates of each user wastestream in order to maintain a
composite waste loading of approximately 23,000 Ibs BOD/day (or 70,000 Ibs
COD/day) on the treatment system. The normal throughput is about 16 MGD
(range of 14-20 MGD).
Mr. Airhart stated that records of the analytical results were available,
but noted that the analyses did not identify specific chemical constituents.
Priority pollutant analyses are performed biannually on the system effluent,
but to date no concentration has ever been identified above detection limits.
In general, no specific waste characterization is available for this facility.
III. WASTE TREATMENT PROCESS
The sole waste treatment process operated at this facility is an
activiated sludge wastewater treatment system. This system consists of an
equalization basin, two aeration basins, four clarifiers, and an auxiliary
high pressure filtration system. A schematic flow diagram of the treatment
system is represented by Figure 1. Additionally, Table 2 provides dimensions
and specifications for the surface impoundments and tanks used during the
treatment operations. The remainder of this section provides a detailed
description of the wastewater treatment process.
Equalization Basin
The equalization basin is an unlined, earthen basin that receives the
combined wastewater influent from a turbulent concrete trough at the midpoint
of the northern embankment. The wastewater is spread evenly throughout the
4-6
-------
TABLE 1. WASTE VOLUMES CONTRIBUTED TO LNVA BY THE FIVE USER FACILITIES,
BEAUMONT, TEXAS.
yger_Facility FCID MaJQrt,Prodyct . Wagte_yolume_.(GPM*J> Percent
Mobil Oil Corporation TXD990797714 primary fuels 8900 74.8
Mobil Chemical TXD000449694 ethylene 1490 12.5
Corporation
P.D. Glycol, glycol 275 2.3
Incorporated
Estech General nitrogen fertilizer 1110 9.3
.Chemical Company
Olin Corporation sulfuric acid 125 1.1
LNVA (design capacity) 11,900
*Values represent design flows. Actual waste volumes will vary with production levels.
-------
NOTE' NOT TO SCALE
O
Q] FIXED AERATOR
/\ FLOATING AERATOR
MAIN RECYCLE AUXILIARY RECYCLE
oo
EQUILIZATION BASIN
MAIN
AERATION BASIN
TO THICKENER
OFFSITE
Figure
1. Treatment system schematic flow diagram, LNVA, Beaumont, Texas.
-------
TABLE 2: BASIN/TANK SPECIFICATIONS FOR LNVA FACILITY IN BEAUMONT, TEXAS.
Equalization Basin
capacity
surface area
depth
mixers (5)
impeller
Aeration Basin
capacity
surface area
depth
aerators (9)
impeller
manufacturer
efficiency
power
transfer rate
Auxiliary Agration_Bagin
capacity
surface area
depth
aerators (6)
impeller
manufacturer
efficiency
power
transfer rate
Clarifiers (4)
capacity
depth
diameter
surface area
10.9 MG
121,000 sq. ft. (approx.)
12 feet (approx.)
30 Hp - low speed (68 RPM)
4 blades - 48" diameter
10.9 MG
121,000 sq. ft. (approx.)
12 feet (approx.)
100 Hp - 1800 RPM
4 blades - 102" diameter
Lightning (fixed)
94.1 percent
86.8 power rating
3.0 Ibs/Hp-hr (approx.)
5.76 MG
48,000 sq. ft. (approx.)
16 feet (approx.)
75 Hp - 1200 RPM
4 blades - 102" diameter
Aqua-jets (floating)
94.1 percent
65.1 power rating
3.0 Ibs/Hp-hr
0.81 MG
12 feet at sidewall (12.5 feet avg.)
105 feet
8,659 sq. ft.
4-9
-------
basin through the use of five low-speed mixers. Two overflow weirs are
located on the common wall between the equalization basin and the main
aeration basin. The flow proceeds by gravity through the basin until it
overflows across these weirs into the main aeration basin. During times of
high organic loading an auxiliary feed pump is used to supply wastewater to a
second (auxiliary) aeration basin. The average detention time within the
equalization basin is 16 hours.
During the site visit the basin appeared to be uniformly mixed, with only
slight agitation of the surface occuring at the inlet and immediately around
the mixers. With the wind blowing from the northeast corner of the basin, a
noticeable oil layer had accumulated in the southwest corner of the basin near
the west weir. An oil-type sheen was also observed on the surface throughout
the basin.
Aeration^Basin
The main aeration basin is an unlined, earthen basin that receives the
overflow from the equalization basin. It employs nine 100 horsepower, fixed
aerators to supply the oxygen and mixing necessary for efficient biological
wastewater treatment. The average detention time within the basin is 16
hours, with the mixed liquor suspended solids (MLSS) concentrations normally
maintained at 2300-2500 mg/1.
During the site visit the wastewater within the aeration basin appeared
brown in color with an oil-type sheen on the surface. The surface was highly
turbulent.
Auxiliary Aeration. Basin
The auxiliary aeration basin is an unlined, earthen basin with
approximately one-third the surface area of the main basin. It is used by
LNVA during periods of high flow. Six 75 horsepower, floating aerators are
used to provide adequate oxygen and mixing.
4-10
-------
At the time of the site visit the basin was not being used for biological
treatment. The only flow into the basin was the surface skimming from the
four final clarifiers. The surface was fairly quiescent with an oil/scum
layer accumulation in the southwest corner, due to the wind.
Normally, the overflow from this basin would combine with the other
aeration basin overflow and flow through the screw lift pump to the
clarifiers. During periods of inactivity, skimmings collect in the basin and
are periodically returned for further biological digestion.
Clarifiers
There are four final clarifiers used by this facility. They are
circular, above ground tanks with rotating skimmer arms to return floatables
to digestion. Their function is to allow solids to settle out, so they may be
transferred either back to the aeration basin or to a sludge thickener and
subsequent off site dewatering and disposal. The overflow is then discharged
to the Lower Neches River as effluent.
During the site visit, all four clarifiers were in use. The surface was
fairly quiescent with a slight oil-type sheen. The overflow appeared fairly
clear.
High Pressure Filter System
During periods of high flow, LNVA uses a high pressure filter loop to
ensure that their effluent does not exceed permit limits. The loop consists
of a percentage of'the effluent passing through a filter of anthracite coal
and sand. This is to remove the suspended material which has failed to settle
out during clarification. The filter effluent is returned to the remaining
plant effluent and discharged to the river.
This system is an optional part of the treatment process. It was not in
operation during the site visit.
4-11
-------
IV. SAMPLING INFORMATION
Sample_LQcatiQn Description
Liquid samples were collected from the following areas:
o the equalization basin,
o the aeration basin,
o the auxiliary aeration basin,
o the final clarifiers, and
o sludge from the final clarifiers.
Sampling points for these tanks and impoundments are indicated in Figure 2.
Equalization Basin
Three samples were taken at the equalization basin. One point (EQ-1A-E)
near the influent was sampled. This area was somewhat turbulent and it was
impossible to obtain a non-aerated sample. One clear area (EQ-1A-J), and one
point in the small oil slick covering one corner of the basin (EQ-1K-0), were
sampled. These are designated SI, S2 and S3 respectively in Figure 2. Sample
temperatures were 65°F (SI), 62°F (S2) and 60°F (S3).
Aeration Basin
The aeration tank was sampled at the outfall, in a relatively calm area
(AI-1A-E). The liquid had a brown color, and the surface was agitated due to
the aerators. Sample temperature was 58°F.
Auxiliary Aeration Basin
This impoundment acts as an overflow area for the plant, but had not been
active for some time. The surface was calm, had a black color and an organic
smell was noticed. One sample was taken (AV-1A-E); temperature was 52°F.
4-12
-------
NOTE'NOT TO SCALE
(?) SAMPLE LOCATION
PREVAILING
WIND
O MIXER
Q] FIXED AERATOR
/\ FLOATING AERATOR
MAIN RECYCLE AUXILIARY RECYCLE
\
EQUILIZATION BASIN /SLICK
MAIN
AERATION BASIN
TO THICKENER
OFFSITE
Figure 2. Sampling locations at LNVA treatment system, Beaumont, Texas.
-------
Final Clarifiers
One of the four clarifiers was sampled (CL-1A-E). In addition, a sample
of the waste bio-sludge (SL-1A-E) leaving the clarifiers was sampled from the
line leading to the sludge thickener at Mobil. This bio-sludge is
approximately 1 percent solids. Temperature at the clarifier was 54°F, while
the bio-sludge was 55°F.
Quality Assurance
Sampling procedures were employed as described in the Quality Assurance
Project Plan dated 30 October 1984. Liquid samples were collected in
quintuplicate, with one of the five samples retained by the facility as a
split. The remaining quadruplicate liqud samples were returned to the GCA
Analytical Laboratory in Bedford, MA where they were received into the sample
bank.
Sample custody and handling procedures included the use of sample tags,
chain-of-custody sheets, refrigeration of samples between sampling and
analysis, and shipping of samples in coolers sealed with custody seals. In
addition, each sample was assigned a unique sample code which linked it to the
facility, the source, and the sample point.
V. SAMPLE ANALYSIS
Analytical Summary
Tables 3 through 9 provide the analytical summary reports for the samples
collected during the site visit (see Appendix A). These tables present the
major compounds quantified by GCA Corporation/Technology Division. The actual
data report sheets for the samples are provided in Appendix B.
Analytic procedures were followed as outlined in Appendix C. Aqueous
samples were analyzed for volatile organics. The analytical procedures for
volatile organics listed in Appendix C are pertinent to the LNVA samples.
4-14
-------
TABLE 3. LIQUID SAMPLE ANALYSIS FROH THE EQUALIZATION TANK INFLUENT AT THE
LOWER NECHES VALLEY AUTHORITY FACILITY IN BEAUMONT, TEXAS
a,b
Coipounds Detected Concentration (ug/1)
Benzine 5900
Hethylene chloride 5550
Toluene 1950
Acetone 1700
2-Butanone (HEX) 1600
Total Xylenes lo,i,p) 350
Ethylbenzene 250
Chi or of on 200
TOTAL HAL06EHATED OR6ANICS 5750
TOTAL OXYBENATED ORBAHICS 3300
TOTAL AfiOflATICS 8450
TOTAL HKHC 17500
nxzaaaacaxgaaaaaasaaaraaaaaaaaaaaaaaiaaassaiaasaaaaaaaaasaaianaszaiaaaaacaazasasnaraaa
a 3
Analysis of saiple 42651 by EGA Corporation using BC/HS.
b
ug/1 * ppb assuiing a density of 1.
4-15
-------
TABLE 4. LIQUID SAMPLE ANALYSIS FROH THE EQUALIZATION TANK (OIL SLICK) AT THE
LOVER HECHES VALLEY AUTHORITY FACILITY IN BEAUHQNT, TEXAS
Compounds Detected Concentration (ug/1)
Benzene 7350
Toluene 3750
2-Butanone («£X) 2700
Acetone 1200
Hetbvlene chloride 1100
4-HethyI-2-pentanone (HIBX) 1000
Total lylenes lo,i,p) 600
Chlorofori 230
TOTAL HAL06ENATED ORGANICS 1330
TOTAL OXYGENATED ORSANICS 4900
TOTAL AROHATICS 11900
TOTAL UNIDENTIFIED ORSANICS 57630
TOTAL m£ 75780
a
Analysis of suple 42654 by SCA Corporation using 6C/BS.
b
ug/1 3 ppb issuiing a density of 1.
4-16
-------
TABLE 5. LIQUID SAMPLE ANALYSIS FROH THE EQUALIZATION TANK (CLEAR AREA) AT THE
LOSER HECHES VALLEY AUTHORITY FACILITY IN BEAUBQNT, TEIAS
Compounds Detected Concentration (ug/1)
Broiofori
Toluene
2-Butanone (HEX)
Hethylene chloride
Total lylenes (o,i,p)
Ethylbenzene
Oilorofori
TOTAL HALQGENATED OR6AHICS
TOTAL OXY6ENATED ORBANICS
TOTAL AROHATICS
TOTAL UNIDENTIFIED ORBANICS
TOTAL NHHC
7350
3050
2200
2100
450
330
250
9700
2200
3850
43990
79740
—.--.... ,_..„„—-—. ......... 1 , 1 y»,,, lff . . .. |._t-— ,— ...--,
a
Analysis at suple 42659 by BCA Corporation using 6C/HS.
b
ug/1 * ppb issuting a density of 1.
4-17
-------
TABLE 6. LIQUID SAKPLE ANALYSIS OF DISPOSAL SLUDGE AT THE
LOWES NECHES VALLEY AUTHORITY IN BEAUHONT, TEIAS
gaasaaaaaaaaaagasgaaaaaaaaaaaaasaasaaaaaaasaaaaasaasarsraaaaaaaaasaasaa
a,b
Cospounds Detected Concentration (uq/1)
Chlorofori 30
TOTAL HAL06ENATED OR8ANICS 30
TOTAL OR6ANICS 30
l
Analysis of saiple 42646 by GCA Corporation using Finn RAT OHA.
b
ug/1 = ppb assuiing a density of 1.
4-18
-------
TABLE 7. LIBUID SAMPLE ANALYSIS FROfl CLARIFIER NO. 2 AT THE
LQHER NECHES VALLEY AUTHORITY IN BEAUHONT, TEXAS
a,b
Coapounds Detected Concentration (ug/l>
Chlorofori 9
TOTAL HAL06ENATED ORGANICS ?
TOTAL ORSANICS 9
a
Analysis of saiple 42640 by 6CA Corporation using Finn RAT OKA.
b
ug/1 = ppb assuaing a density of 1.
4-19
-------
TABLE 8. LIQUID SAHPLE ANALYSIS FROM THE QR6ANIC-AUX LAGOON AT THE
LONER HECHES VALLEY AUTHORITY IK BEAUHONT, TEXAS
Coipounds Detected Concentration (ug/1)
Chlorofon 3.9
TOTAL HALOGENATED OR6ANICS 4
TOTAL ORBANICS 4
a
Analysis of saiple 42636 by GCA Corporation using Finn HAT OHA.
b
ug/l = ppb assuiing a density of 1.
4-20
-------
TABLE 9. LIBUID SAMPLE ANALYSIS FROH THE AERATOR OUTFALL
LOWES NECHES VALLEY AUTHORITY IN BEAUMONT, TEXAS
sssssssssssssssssssssssssssssssssssssssssssssssssssssssssssssssssssss
a,b
Coapounds Detected Concentration (ug/1)
Chlorofori 14
TOTAL HAL06ENATED ORBANICS 14
TOTAL UNIDENTIFIED ORGANICS 627
TOTAL OR6ANICS 641
Analysis of saiple 42632 by ECA Corporation using Finn HAT DMA.
b
ug/1 = ppb assuiing a density of 1.
4-21
-------
Quality Assurance
Chain of custody and quality control protocols appear in Appendix E.
Surrogate spikes were utilized in conjunction with LNVA samples for volatile
organics; these recoveries are reported in Table 10.
4-22
-------
TABLE 10. SURROGATE RECOVERIES - VOLATILE ORGANICS.
LNVA, BEAUMONT, TEXAS
Percent Recoveries
Sample
Identification
LNVA- AL- ID
LNVA- AU- ID
LNVA-CL-1D
LNVA-SL-LD
LNVA-EQ-1C
LNVA-EQ-1G
LNVA-EQ-1M
Method blank
Average Percent
GCA
Control No.
42632
42636
42640
42646
42651
40654
42659
3/7/85
3/8/85
3/4/85
Recovery
Relative Standard Deviation (7.)
D8
toluene
96
97
96
97
99
97
97
99
97
99
97
1
Bromo-
fluorobenzene
99
98
95
106
96
108
109
97
95
96
100
6
D4 - 1,2-
dichloroethane
92
74
76
91
74
103
90
89
76
128
89
17
4-23
-------
Section 5.
Mobil Oil Refinery
Beaumont, XX
5-1
-------
TABLE OF CONTENTS
Section Page
I. Introduction 5-6
II. Waste Characterization 5-7
Wastewater Treatment System 5-7
Land Treatment Operations. 5-7
III. Waste Treatment Processes 5-9
Wastewater Treatment 5-9
Land Treatment 5-13
Landfill 5-14
IV. Sample Site Descriptions 5-14
Wastewater Treatment 5-14
Land Treatment 5-18
Landfill. 5-20
Quality Assurance 5-20
V. Sample Analysis.. 5-21
Analytical Summary 5-21
Quality Assurance 5-21
5-2
-------
LIST OF TABLES
Page
Average Daily Process Waste Quantities at the Mobil
Beaumont Refinery, Texas 5-8
2 Physical Dimensions of Wastewater Treatment Process Tanks
and Basins at Mobil Beaumont Refinery, Texas 5-11
3 Liquid Sample Analysis of Field Bias Blanks for the Mobil
Oil Refinery in Beaumont, Texas 5-22
4 Liquid Sample Analysis from the API Separator at the Mobil
Oil Refinery in Beaumont, Texas 5-23
5 Liquid Sample Analysis from the API Separator at the Mobil
Oil Refinery in Beaumont, Texas 5-24
6 Liquid Sample Analysis from the Belt Press Feed at the
Mobile Oil Refinery in Beaumont, Texas 5-25
7 Liquid Sample Analysis from the DAF Effluent at the
Mobile Oil Refinery in Beaumont, Texas 5-26
8 Liquid Sample Analysis from the Primary Basin at the Mobil
Oil Refinery in Beaumont, Texas 5-27
9 Liquid Sample Analysis from the Secondary Basin at the Mobil
Oil Refinery in Beaumont, Texas 5-28
10 ICAP Analysis for Metals in Surface Soil of the Upper
Landfill at the Mobile Oil Refinery in Beaumont, Texas.... 5-29
11 ICAP Analysis for Metals in Soil Cores from the Landfarm/
Landfill at the Mobil Oil Refinery in Beaumont, Texas 5-30
12 ICAP Analysis for Metals in Soil Cores from the South Plant
Landfarm at the Mobile Oil Refinery in Beaumont, Texas.... 5-31
13 ICAP Analysis for Metals in Soil from the Upper Landfill
at the Mobile Oil Refinery in Beaumont, Texas 5-32
14 Analysis of Surface Soil from the Upper Landfill at the
Mobil Oil Refinery in Beaumont, Texas 5-33
15 Analysis of Base/Neutral Extractables from the Upper
Landfill at the Mobil Oil Refinery in Beaumont, Texas 5-34
5-3
-------
List of Tables (continued)
Table Page
16 Analysis of Solids, Oil and Grease, and Moisture Contents
of Soil from the Mobil Oil Refinery Landfill/Landfarm
and South Plant Landfill in Beaumont, Texas 5-35
17 Surrogate Recoveries - Volatile Organics. Mobil Oil,
Beaumont, Texas 5-36
18 Surrogate Recoveries - Extractable Organics. Mobil Oil,
Beaumont, Texas 5-37
5-4
-------
LIST OF FIGURES
Figure Page
1 Mobil Beaumont Refinery (Texas) wastewater treatment
system 5-10
2 Wastewater treatment sampling points at Mobil Beaumont
Refinery, Texas 5-16
3 Land treatment area and landfill sampling points at Mobil
Beaumont Refinery (Texas) 5-19
5-5
-------
Site:
FCID:
Site Contact:
Field Trip Personnel:
Visit Time and Date:
Mobil Oil Beaumont Refinery
P.O. Box 3311
Beaumont, Texas 77704
latitude 30° 04' 05" N
longitude 94° 03' 34" W
TXD990797714
Don R. Robinson, Manager, Conservation
(409) 839-3645
Don R. Robinson, Manager, Conservation, Mobil
Bob Crisman, Sampling Specialist, Mobil
Bill Stewart, Environment Engineer, Mobil
Jim Durham, USEPA
K.C. Hustvedt, USEPA
Terry Harrison, USEPA
Gene Riley, USEPA
Susan Thorneloe, USEPA
Penny Lassiter, USEPA
Scott Osbourn, GCA/Engineering
Tom Warn, GCA/Engineering
Douglas Seely, GCA/Measurements
Richard Roate, GCA/Measurements
January 24, 1985
8:30 a.m.
I. INTRODUCTION
The Mobil Beaumont Refinery is located in a highly industrialized section
along the Gulf Coast of Texas. Process operations were initiated at this site
in 1903. Mobil Chemical is located north of the Beaumont refinery.
(THE REMAINDER OF THIS SECTION HAS BEEN CLAIMED CONFIDENTIAL BY MOBIL OIL
CORPORATION. THIS INFORMATION IS CONTAINED WITHIN APPENDIX F OF THIS VOLUME.)
5-6
-------
II. WASTE CHARACTERIZATION
Mobil's Beaumont facility is equipped with a primary wastewater treatment
system, several land treatment areas, and a landfill operation. Secondary
wastewater treatment is performed at the adjacent Lower Neches Valley
Authority (LNVA) treatment facility. Table 1 lists average daily process
waste quantities generated at Mobil. A characterization of the wastes
received and treated within each of these treatment processes is detailed
below.
Wastewater Treatment System
The wastewater treatment system handles process wastewater, stormwater
runoff collected at the refinery, and cooling water blowdown. Wastewater
throughput averages from 6000 to 7000 gallons per minute. A wastewater
analysis of influent to the primary treatment system has been requested from
Mobil and is yet to be received.
Land Treatment Operations
The land treatment operations receive sludges produced within Mobil's
primary wastewater treatment system and LNVA's secondary wastewater treatment
system. The sources of the sludges are described in detail in the following
section on WASTE TREATMENT PROCESSES. Oily sludges from DAF float and API
separator bottoms are sent to a holding tank for thickening prior to discharge
to the belt press operation. The oily sludge typically consists of six to
ten percent solids, 23 percent oil content and 65 to 70 percent moisture.
After beltpressing, the oily sludge filter cake consists of approximately
eight to ten percent oil content and 60 percent moisture. Biological sludge
is piped from LNVA to one of two cone bottom holding tanks prior to discharge
to the belt press. The biosludge consists of approximately three percent
solids and the remainder moisture (oil content is negligible). After
beltpressing, the biocake is approximately 70 to 80 percent moisture content
5-7
-------
TABLE 1. AVERAGE DAILY PROCESS WASTE QUANTITIES AT THE
MOBIL BEAUMONT REFINERY, TEXAS.
EPA Type Quantity Method of
Waste of (Ibs/day) Disposal
Code Waste
(UNAVAILABLE)
5-8
-------
and the remainder solids. Dredgings from the primary basin are hydraulically
transferred to one of the two dredge spoil basins for dewatering and
subsequently to the North Plant land treatment area. Waste characterization
data were not available concerning this dredged material.
Subsequent to the visit, land treatment areas have been inactive. Primary
basin dredgings are currently being landfilled after dewatering.)
II. WASTE TREATMENT PROCESSES
Wastewater^Treatment
A flow diagram of the Mobil Refinery wastewater treatment system is
presented in Figure 1. Specifications of open tanks and basins in the system
are listed in Table 2. Mobil provides only primary wastewater treatment and
then discharges to the Lower Neches Valley Authority (LNVA) facility for
secondary treatment. The LNVA is a non-RCRA, commercial wastewater treatment
facility which provides secondary treatment to the process wastewater from
five industrial users, including Mobil Oil.
Wastewater throughput averages approximately 6000 to 7000 gallons per
minute and is received from refinery process unit and cooling tower blowdown.
Underground sewer systems at the Mobil refinery route wastewater flow to a
central area referred to as a diversion box. From this point, wastewater is
routed via screw lift conveyor to either the API separator for primary
treatment or to the primary basin when the capacity of the treatment system is
exceeded. During periods of excessive stormwater runoff, flow which would
exceed the capacity of the API separator is routed directly from the diversion
box to the primary basin. If the capacity of the primary basin is exceeded,
overflow is pumped to the secondary basin. When flow subsides, wastewater
within the primary basin is routed to the API separator and wastewater within
the secondary basin is sent directly to LNVA. Therefore, during periods of
wet weather, LNVA receives from Mobil not only the 6000 to 7000 gallons per
minute from the primary wastewater treatment system, but also an additional
2000 to 3000 gallons per minute from the secondary basin.
5-9
-------
(THIS INFORMATION HAS BEEN CLAIMED CONFIDENTIAL BY MOBIL OIL CORPORATION.
THIS INFORMATION IS CONTAINED WITHIN APPENDIX F OF THIS VOLUME.)
Figure 1. Mobil Beaumont Refinery (Texas) wastewater treatment system.
5-10
-------
TABLE 2. PHYSICAL DIMENSIONS OF WASTEWATER TREATMENT PROCESS
TANKS AND BASINS AT MOBIL BEAUMONT REFINERY, TEXAS.
Process Unit
Dimensions (feet)
Length Width Depth
Total Surface Area
API
Separator
each bay
(4
bays)
104
104
80
20
7
7
8320
2080
ft
ft
2
2
DAF unit (4 channels) 89
each channel 89
Primary basin NA
Secondary basin NA
Dredge spoil basin NA
Oily sludge holding tank3 NA
(open-top tank #432)
88
22
NA
NA
NA
65
8
8
4 (avg.)
4-10
4
14
7832 ft 2
1958 ft 2
16 acres
62 acres
12 acres
NA
NA - dimesions not available.
5-11
-------
The API separator consists of four bays. The forebay is covered.
Skimmers span the entire width of the separator and provide for continuous
scum and oil removal. These skimmers, spaced about 10 feet apart, move
concurrent to wastevater flow through the separator. Consequently, most of
the skimmed oil is in the vicinity of the separator outlet. Oil skimmed from
the API separator is sent to non-hazardous tankage for slop oil processing.
Oil recovered is recycled to process operations and wastewater is recycled to
the API separator.
Wastewater flows directly from the separator to a dissolved air floatation
(DAF) unit. Polymer is added here to facilitate the DAF process. The DAF
unit consists of four channels. Scum rakes are provided for continuous
float/scum removal. Wastewater discharged from the DAF unit is either sent
directly to the LNVA facility for additional treatment and discharge or
recycled to the DAF unit cooling towers, coker unit or filter belt press
wash. Approximately one-third of the DAF discharge, supersaturated with air,
is recycled to facilitate aeration and scum removal. The primary basin serves
as a holding basin for DAF effluent when flow is greater than LNVA treatment
availability.
The wastestream entering LNVA is monitored by LNVA before it is combined
with the primary effluent of other industrial users to form the influent that
enters the treatment facility. The monitoring consists of an on-line pH
meter, a grab sample every four hours and a 24 hour composite sample These
samples are analyzed for COD, phenols, ammonia, and sulfides.
The secondary basin has never been dredged. The primary is dredged
approximately every two years and the dredgings are hydraulically transferred
to the dredge spoil basin. Biological sludge is piped from LNVA to one of two
cone bottom holding tanks prior to discharge to the belt press operations.
There are three belt presses on site. The bio-sludge press operates nearly
every day and the oily presses run for approximately two weeks every month.
The belt presses had not run in 24 to 36 hours previous to the time of
inspection. One belt press is for biological sludge (non-hazardous) and 2 are
for processing oily sludge (hazardous).
5-12
-------
There are currently eleven holding tanks for oily sludges and slop oil
emulsions. These are designated as hazardous waste treatment tanks on RCRA
Part A. Three tanks are of the internal-floating type, seven are fixed-roof,
and one is an open-top tank (tank no. 432). Slop oil emulsions are received
in seven of these tanks and subjected to heat treatment. Open-top tank
no. 432 receives DAF float for thickening purposes prior to discharge to one
of the heat treatment tanks.
Land Treatment
Mobil is currently in the process of re-evaluating their land treatment
operations. It was anticipated at the time of the visit that the amount of
material to be land treated would be minimized and land treatment areas would
be phased out. A decision was made to begin phasing out the land treatment
operation because of permitting problems regarding Part B permit approval. It
is anticipated that the materials currently land treated can either be
directly landfilled on-site (slop oils) or sent to the Beaumont city dump
(belt press biosludge). Mobil anticipates that the belt press waste will have
a moisture content low enough to make direct landfilling feasible. If the
material previously land treated is not suitable for landfill, Mobil will
investigate sending the waste off-site or injecting it into the coker unit
operation (they have a patent on this process).
Currently, oily sludge and biosludge filter cake from the belt press
operations, in addition to some dredgings and sludge bottoms (not dewatered),
are simply spread over the land treatment area to facilitate drying. There is
very little biological activity. Material is turned over occasionally, but
not tilled into the soil. The soil is mostly clay. Dewatering is the
principal land treatment process. They are not trying to degrade and fix
their wastes, the wastes are simply spread, dried for approximately one month,
removed and landfilled. The thickness of the layer (primarily belt press
cake) is from one to six inches.The number of applications is a function of
weather and operation of the belt press.
The quantity of belt press cake (both biocake and oily sludge filter cake)
land treated averages four trucks per day at six to eight tons per truck.
This material contains approximately 70 to 80 percent moisture content. There
5-13
-------
are four land treatment areas at Mobil, designated the Landfill/Landfarm (8.7
acres), the North Plant Landfarm (30 acres), the South Plant Landfarm (4
acres) and the Wax Mold Landfarm (2 acres). The North Plant Landfarm is a
dredge spoil spreading area receiving waste from the dredge spoil basin.
Although Mobil refers to this area as land treatment, it actually more closely
resembled a surface impoundment. Oily sludge filter cake, from the belt press
operation, is land treated primarily at the South Plant Landfarm and the
Landfill/Landfarm. The Wax Mold Landfarm is now undergoing closure and Mobil
is currently developing a RCRA Part B permit application for this procedure.
(As previously mentioned, these land treatment areas became inactive
subsequent to this visit. Belt press cake has a sufficiently low moisture
content to allow direct landfilling.)
Landfill
Mobile has one Class I landfill on site and it is active. Landfilling
operations were initiated at Mobil in 1950 and now encompass an area of
approximately 49 acres. The landfills are not divided into cells but are
located above ground. Consequently, there is no leachate collection system.
Waste is dumped and soil is trucked in and mixed before the surface is
compacted by heavy equipment. Mobil does not spread a soil cover over the
waste on a daily basis.
Marshlands and refinery property border the landfill. Mobil landfills
spent catalyst material, trash, dredge spoils and land treated filtercake.
Materials which cannot be landfilled, such as leaded tank bottoms,
PCs-contaminated material and reactive wastes are drummed and sent off-site.
The drumming is performed right at the cleaning site; there is no central drum
storage area.
IV. SAMPLING SITE DESCRIPTIONS
Wastewater Treatment
Mobil employs a primary wastewater treatment system consisting of an API
separator and a dissolved air floatation (DAF) unit. Wastewater discharged
5-14
-------
from the DAF unit is piped to the Lower Heches Valley Authority (LNVA)
facility for secondary treatment. The Mobil facility also has a primary and
secondary basin to handle stormwater runoff and process wastewater when the
capacity of the primary treatment system is exceeded.
Liquid samples were collected from the following areas:
o the API separator inlet
o the API separator outlet
o the DAF unit
o the primary basin
o the secondary basin
o the belt press feed storage tank
Sampling points for these tanks and impoundments are indicated in Figure 2.
API Separator
Sampling was conducted at the API separator inlet and outlet (Figure 2,
points API-1 and API-2, respectively). Skimmers were operating at the
separator surface moving concurrent to the wastewater flow. Consequently,
there was a high surface oil content in the vicinity of the separator outlet.
Sampling was conducted from a walkway at a point approximately 20 feet from
the inlet. A sample was also taken at a point above the separator cascade
prior to discharge to the DAF unit. This location was chosen in order to
obtain a sample before the addition of polymer at the DAF unit inflow. There
was no heavy oil layer at this point due to the continuous skimming; however,
the water was brown in color with a visible oil sheen. The water temperature
at both sampling locations was approximately 85°F.
DAF Unit
Wastewater flows directly from the API separator to the DAF unit where a
polymer is added to facilitate oil and scum removal. Sampling was conducted
from a walkway at the DAF unit outlet upstream of the system cascade
5-15
-------
(THIS INFORMATION HAS BEEN CLAIMED CONFIDENTIAL BY MOBIL OIL CORPORATION.
THIS INFORMATION IS CONTAINED WITHIN APPENDIX F OF THIS VOLUME.)
Figure 2. Wastewater treatment sampling points at Mobil Beaumont Refinery,
Texas.
5-16
-------
(Figure 2, point DAF-1). The water was light brown in color and a slight oil
sheen was visible across the entire surface. The sample taken resembled
slightly dirty water. Water temperature in this vicinity was approximately
80°F.
Primary Basin
The primary basin receives stormwater runoff and process wastewater
directly from the sewer system when the capacity of the primary treatment
system is exceeded. There were various regions of light and heavy oil layers
covering approximately 75 percent of the basin surface. In the region of
heavy surface oil, booms were in place and a vacuum truck was operating.
Sampling was conducted from the pump house outfall (Figure 2, point PB-1) in
an area where the surface was relatively oil-free. The sample taken resembled
dirty water with some suspended solids and an oil sheen visible at the
meniscus. Water temperature at the point of sampling was approximately 64°F.
Secondary Basin
Wastewater within the. secondary basin was brown in color but much clearer
in appearance than the primary basin wastewater. There was no noticeable oil
sheen at the surface. Sampling was conducted from a gauging station at the
basin inlet where the water temperature was 58°F. The sample taken resembled
dirty water with a slight oil sheen at the meniscus.
Belt Press Feed Storage Tank
The belt press feed storage tank receives DAF float and slop oil
emulsions. The material is fed through a top splash discharge pipe at the
tank perimeter. The feed was very oily and foamy and the surface area was
almost completely covered by suspended solids. Sampling was conducted from a
walkway along the tank perimeter (Figure 2, point BPF-1) where the wastewater
temperature was approximately 64°F. The tank was estimated to be about 75
percent full or to a level about 10 feet from the top. The sample taken was
very oily and it was extremely difficult to hold a meniscus.
5-17
-------
Land_treatment
Mobil employs four land treatment areas: the South Plant, the North Plant,
the Wax Mold and the Landfill/Landfarm. Plant process wastes are first filter
pressed and then spread over the land treatment areas to evaporate residual
moisture. After adequate retention time, land treatment composites are
transferred to the landfill. Biosludge from the LNVA treatment facility is
processed by Mobil and disposed of at the landfill. Only at the landfill is
soil actually mixed with the waste. Sample cores were taken at the following
locations:
o the South Plant Landfarm
o the Landfill/Landfarm
o the Upper Landfill
Sampling locations are detailed in Figure 3.
South Plant Landfarm
It appeared as though waste had recently been applied to approximately 60
percent of this- four acre landtreatment area. The waste layer was not uniform
and varied from one to six inches. The remaining 40 percent of the area had
recently been scraped and the dried sludge removed to the landfill. Piles of
waste to be spread had been dumped along one entire edge of the landtreatment
area.
A sampling point was selected within the area of recent application
(Figure 3, point SL-1). The waste material was very moist, dark gray in color
and possessed a foamy or spongy consistency. Approximately a dozen attempts
were made to fill the soil core. Rather than go into the core, the sample
oozed away. At the time of sampling, ambient temperature was 58°F and the
waste temperature was approximately 54°F.
5-18
-------
(THIS INFORMATION HAS BEEN CLAIMED CONFIDENTIAL BY MOBIL OIL CORPORATION.
THIS INFORMATION IS CONTAINED WITHIN APPENDIX F OF THIS VOLUME.)
Figure 3. Land treatment Area and Landfill Sampling Points at Mobil
Beaumont Refinery (Texas).
5-19
-------
Landfill/Landfarm
This land treatment area had recently been scraped of the waste which had
been spread to dry. A long pile of belt press filter cake, approximately two
to three feet high, had been dumped but not yet spread. This pile had been
undisturbed for about one week and was beginning to dry out on top. The
surface was tan in color and darker brown to gray several inches beneath.
Sampling was conducted within this pile (Figure 3, point LL-1). The material
was moist and extremely spongy and several attempts were required to fill the
sample core. Temperature within this filter cake pile was meassured at 50°F.
Landfill
There is one landfill area at the Mobil facility, with an upper and lower
area. Both areas are still active, but only the upper portion of the landfill
was sampled. The landfill surface area consisted predominantly of dry,
crumbly sludge which had been transferred from one of the landtreatment areas
on-site. Soil is occasionally trucked in and mixed with this sludge layer.
Several inches below the surface, the mixture of waste material and soil
appeared to be moist and compacted. Sample cores were taken in an area of
recent activity at the landfill's west edge (Figure 3, point UL-1). It was
difficult to obtain a full sample core because of compaction. After several
attempts, the cores were still one-half to one inch below the top on both
samples. Soil temperature at the point of sampling was 56°F.
Surface dust samples were taken from six zones within the landfill area
(Figure 3, points UL-3). These samples were all combined in order that a
representative composite could be analyzed for fugitive dust potential. In
addition, a grab sample of spent catalyst was obtained from a catalyst pile at
the site (Figure 3, point UL-2).
Quality Assurance
Sampling procedures were employed as described in the Quality Assurance
Project Plan dated 30 October 1984. Liquid samples were collected in
septuplicate, as a standard procedure, with three of the seven samples
5-20
-------
retained by the facility as a split. Soil core samples were collected in
duplicate. The facility split for these samples was taken by Mobil
representatives with their own soil core sampling device. The remaining
quadruplicate liquid samples and the duplicate soil samples were returned to
the GCA Analytical Laboratory in Bedford, MA. where they were received into the
sample bank.
Sample custody and handling procedures included the use of sample tags,
chain-of-custody sheets, refrigeration of samples between sampling and
analysis, and shipping of samples in coolers sealed with custody seals. In
addition, each sample was assigned a unique sample code which linked it to the
facility, the source, and the sample point.
V. SAMPLE ANALYSIS
Tables 3 through 16 provide the analytical summary reports for the process
samples collected during the site visit (see Appendix A). These tables
present the major compounds quantified by GCA/Technology. The actual data
report sheets for each respective sample are provided in Appendix B.
The analytical procedures are discussed in Appendix D. Aqueous samples
were analyzed for volatile organics; soil samples were analyzed for
extractable organics, pesticides and PCBs, trace metals, percent solids, and
oil and grease.
Quality Assurance
Chain of custody and quality control protocols appear in Appendix E.
Surrogate spikes were utilized in conjunction with Mobil samples for volatile
organics and extractable organics; these recoveries are reported in Table 17
and Table 18, respectively.
5-21
-------
TABLE 3. LIQUID SAMPLE ANALYSIS OF FIELD BIAS BUNKS FQR
THE KOBIL OIL REFINERY IN BEAUMONT, TEIAS
a,b
Coipoonds Detected Concentration (oq/l)
Acetone 65
a
Analysis of satple 42435FBB by BCA Corporation using BC/HS.
ug/1 * ppb assiuing a density of 1.
5-22
-------
TABLE 4. LIQUID SAMPLE ANALYSIS FROH THE API SEPARATOR
AT THE H08IL OIL REFINERY IN BEAUHQNT, TEXAS
Coipaunds Detected
2-Butanane (HOC)
Total lylenes (o,i,p)
Acetone
Toluene
Benzene
Hethylene chloride
Chlorofon
TOTAL HALOGENATEB QR6ANICS
TOTAL OXY6ENATED QRSANICS
TOTAL AROHATICS
TOTAL UNIDENTIFIED OR6ANICS
TOTAL NBHC
Concentration
a
Analysis 1
25200
3800
3200
2400
1800
1600
1600
29400
8000
38000
— ^ . _ . . -—
c
(ug/l)
b
Analysis 2
27600
1800
61200
2800
600
3400
27600
3000
15382
49382
Average
26400
3800
3200
2100
31500
2200
600
2500
28000
5500
15332
43691
a
Analysis of sitple 42696 by 6CA Corporation on 04-NAR-85 using SC/KS.
b
Analysis of saiple 42696 by SCA Corporation on 21-HAR-8S using SC/ftS.
c
ug/l = ppb assuiing a density of 1.
5-23
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TABLE 5. LISUID SAMPLE ANALYSIS FROM THE API SEPARATOR
AT THE HOBIL OIL BEFINEJY IN BEAUilONT, TEXAS
a,b
Ccapounds Detected Concentration (tig/1)
2-Butanone (HEK)
Toluene
Benzene
Acetone
Methyl ene chloride
Total Xylenes lo,»,p)
Ethylbenzene
TOTAL HALOSENATED ORSANICS
TOTAL OXYGENATED ORGAN I CS
TOTAL A80HAT1CS
TOTAL HHHC
24400
4700
2800
1600
1400
1200
1100
1600
26000
9800
37400
a
Analysis si saipie 42700 by GCA Corporation using SC/HS.
b
ug/1 3 ppb jssuiing a density of 1.
5-24
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TABLE 6. LIQUID SAMPLE ANALYSIS FRQH THE BELT PRESS FED
AT THE MOBIL OIL REFINERY IN BEAUMONT, TEXAS
J,b
Coipounds Detected Concentration (ug/1)
Total Zylenes (o,»,p)
Ethylbenzene
Toluene
Benzene
Chlorofon
TOTAL HAL06EXATED ORGAN I CS
TOTAL AROHATICS
TOTAL UNIDENTIFIED ORBANICS
TOTAL OREANICS
260000
220000
96000
9500
c
890
890
585000
TBA
584390 + UNID'D
a
Analysis of suple 42705 by EGA Corporation using SC/KS.
b
ug/1 = ppb assuring a density of 1.
TBA = To be analyzed
5-25
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TABLE 7. LISU10 SAMPLE ANALYSIS FROM THE DAF EFFLUENT
AT THE MOBIL OIL REFINERY IN BEAUMONT, TEXAS
—==«==="="==—="=====::======—"=s
C
Concentration (ug/1)
a b
Coapounds Detected Analysis 1 . Analysis 2 Average
2-Butanone (HEX)
Toluene
Benzene
Acetone
He thy lens chloride
Etbylbenzene
TOTAL HALOSENATED OBBANICS
TOTAL WY6ENATED QRGANICS
TOTAL ARQMATICS
TOTAL NMKC
40800
3600
2BOO
2600
1200
800
1200
42000
7200
50400
40000
. 2400
1600
12800
1200
600
1200
52800
4600
58600
40400
3000
2200
7700
1200
700
1200
47400
5900
54500
a
Analysis of saaple 42708 by 6CA Corporation on 04-MAR-85 using BC7HS.
b
Analysis of saaple 42708 by SCA Corporation on 21-MAR-B5 using EC/MS.
c
ug/1 = ppb assming a density of 1.
5-26
-------
TABLE B. LIQUID SAMPLE ANALYSIS FROM THE PRIMARY BASIN
AT THE flOBIL OIL REFINERY IN 8EAUHOMT, TEXAS
a,b
Coapaunds Detected Concentration (ug/1)
Benzene 11050
Toluene 2400
Acetone 1400
Hethylene chloride 1050
Styrene . 1000
Total lylenes (o,i,p) 450
Ethylbenzene 400
Cblorofori 200
TOTAL HALOGENATED ORGANICS 1250
TOTAL QXY6ENATED OREANICS 1400
TOTAL ARQHATICS 15500
TOTAL OR6ANICS 18150
a
Analysis of sasple 42712 by SCA Corporation using 8C/HS.
b
ug/1 3 ppb assuaing a density of 1.
5-27
-------
TABLE ?. LIQUID SAWPLE ANALYSIS FROM THE SECONDARY BASIN
AT THE HOBIL OIL REFINERY IN BEAUHONT, TEXAS
Compounds Detected
Hethylene chloride
Benzene
2-3uUnone (HEKJ
Toluene
Acetone
Total lylenes Io,»,p)
Styrene
Etnylbenzene
TOTAL HALG5ENATED OR6ANICS
TOTAL OXYGENATED QRSANICS
TOTAL ARGSATICS
TOTAL NHKC
a,b
Concentration (iig/1)
6640
2240
940
900
860
400
260
100
6640
1800
3900
12340
a
Analysis of saaple 42716 by SCA Corporation using 6C/MS.
b
ug/1 = ppb assuming a density of 1.
5-28
-------
TABLE 10. ICAP ANALYSIS FOR METALS IN SURFACE SOIL OF THE UPPER
LANDFILL AT THE NOBIL OIL REFINERY IN BEAUMONT, TEXAS
Elesent
Concentration (ug/g)
a b
Analysis 1 Analysis 2
Aluainua
Antieony
Arsenic
Bariua
Beryl liui
Boron
Cadiiui
Calciui
Chroaiua
Cobalt
Copper
Iron
Lead
Hagnesiua
Manganese
Molybdenua
Nickel
Seleniua
Silicon
Silver
Sadiiui
Strontiua
Thalliua
Tin
Titaniua
Vanadiui
Zinc
a
150000
d
<3.0
<3.0
94.3
1.79
27.5
0.2
1130
57.3
5.68
64.8
3910
640
190
40.1
<0.4
130
d
21
784
<0.6
d
3000
107
d
10
55
471
310
119
d
17000
d
30
33
244
4.93
18.5
1.19
8970
1610
10.7
270
20000
2SOO
7300
324
11.5
40.1
d
26
1000
<0.6
d
1400
73.6
d
<3.0
35.5
49.2
93
1280
b
Analysis oi saaple 42718 by GCA Corporation using ICAP.
Analysis oi saaple 42719 by BCA Corporation using ICAP.
c
ug/g = aicrograas per graa.
d
These values should be considered seai-quantitative due to severe
aatrix interferences encountered during the analysis.
5-29
-------
TABLE 11. 1CAP ANALYSIS FOR HE7ALS IN SOIL CORES FRQfl THE LANDFARH/
LANDFILL AT THE MOBIL OIL REFINERY IN BEAUMONT, TEXAS
a,b
Eleaent Concentration (og/g)
Aluiinut
Antiwny
Arsenic
Bariiia
Beryl liui
Boron
Cad«iu»
Cakiui
Diro»iu»
Cobalt
Copper
Iron
Lead
Hagnestut
Manganese
Holybdentu
Nickel
Selenitu
Silicon
Silver
Sodiua
Strontiui
Thai lias
Tin
Titanius
Vanadiui
Zinc
c
13000
c
94
33
269
4.5
18.8
1.76
6510
5760
8.45
336
18400
1400
4600
296
(0.4
74.1
c
74
201
<0.6
c
4400
95.9
c
<3.0
23.4
47.7
240
2030
a
Analysis ai saaple 42720 by SCA Corporation using IMP.
b
ug/g = licrograis per qrai.
c
These values should be considered seal-quantitative due to severe
•atrix interferences encountered during the analysis.
5-30
-------
TABLE 12. ICAP ANALYSIS FOR METALS IN SOIL CORES FROK THE SOUTH PLANT
LANOFARM AT THE MOBIL OIL REFINERY IN BEAUHQNT, TEXAS
a,b
Elesent Concentration (aq/g)
Aluiinua
Antiaony
Arsenic
Bariua
Beryl liua
Boron
Cadiiui
Calciua
Chroaiua
Cobalt
Copper
Iron
Lead
Hagnesiua
Manganese
Holybdenua
Nickel
Seleniua
Silicon
Silver
Sodiui
Strontiua
Thalliu
Tin
Titaniua
Vanadiua
Zinc
c
14000
c
34
25
260
4.34
9.26
1.03
8660
2290
7.79
290
19100
2100
6900
339
14.7
46
C f
31
84.8
<0.6
c
1500
78.6
c
<3.0
22.8
24.2
88
1420
a
Analysis of saiple 42722 by GCA Corporation using ICAP.
b
ug/g - aicrograis per graa.
c
These values should be considered seal-quantitative due to severe
•atrix interferences encountered during the analysis.
5-31
-------
TABLE 13. IMP ANALYSIS FDR METALS IN SOIL CORES FROM THE UPPER
LANDFILL AT THE MOBIL OIL REFINERY IN BEAUMONT, TEWS
Eleaent Concentration (ug/g)
Aluainua
Antiaony
Arsenic
Bariua
Berylliui
Boron
Cadaiua
Calciua
Chroaiua
Cobalt
Copper
Iron
Lead
Kagnesiua
Manganese
Holybdenui
Nickel
Selsniut
Silicon
Silver
Sodiua
Strontiui
Th alii in
Tin
Titaniua
Vanadiua
Zinc
c
liOOO .
c
34
32
303
4.78
10.?
1.19
9550
2040
10.5
353
20800
2300
7900
336
30.7
40.8
c
27
122
<0.6
c
1200
80
C
<3.0
23.4
35.3
78
1810
•a
Analysis of saiple 42724 by SCA Corporation using ICAP.
b
ug/g - licrograas per gra«.
c
These values should be considered seal-quantitative due to severe
•itrii interferences encountered during the analysis.
5-32
-------
TABLE 14. ANALYSIS OF SURFACE SOIL FROil THE UPPER LANDFILL
AT THE «OBIL OIL REFINERY IN 3EAUKONT, TEXAS
a,b
Paraaetsr Concentration (ig/kg)
Chlordane
Toxaphene
PCB-1254
PCB-1240
PCB-1016
PCB-1221
PC8-1242
PCB-124B
PC3-1232
<13
<5.0
<5.0
<5.0
NO:
ND;
ND: c
NO:
ND:
••• SgSgSS— SS5 5a~"SSS5S5BS~~™*™™™~?T JT" '"T * "M^™""Sg**r~™ST "S •
i 43
Analysis of saiple 42719 by GCA Corporation using GC »/Ni ECO
b
•g/kg = ppa assuaing a density of 1.
Not detected at detection liiit of <15 ag/kg.
5-33
-------
TABLE 15. ANALYSIS OF BASE/NEUTRAL EHRACTABLES FROH THE UPPER
LANDFILL AT THE .10311 OIL REFINERY IN BEAUMONT, TEXAS
a
Paraieter Concentration (ig/kg)
b
Pyrene 380
a
Analysis of saaple 42719BH by GCA Corpooration using SC/MS, and EPA Method 625.
b
Present but below detection at detection liiit <350 ig/kg.
5-34
-------
TABLE li. ANALYSIS OF SOLIDS. OIL AND GREASE. AND HOISTURE
CONTENTS OF SOIL F&Ofl THE flOBIL OIL REFINERY
LANDFILL/LANDFARH AND SOUTH PLANT LANDFILL
IN BEAUMONT, TEIAS
a
Concentration (I!
b c d
Caaponent Analysis 1 Analysis 2
Solids (including 16.4
Oil and grease)
Moisture 83. &
45.9
54.1
Oil and Srease 19.5_ 13.0
a
Analyses perforsed bv SCA Corporation using CfiL 444, CHL 445,
and SH-846, aethod 9071 analysis procedures.
b
Solids and misture contents Here teasured in the saae
aliquot, and sua to 1001. Oil and grease contents Here
•easuret) froi an additional aliquot of the saae sasple.
c
Analysis of saaple 42720, froa Hobil Oil Refinery's
Landfill/Landfara.
d
Analysis of saaple 42722, froi Hobil Oil Refinery's South
Plant Landfara.
5-35
-------
TABLE 17. SURROGATE RECOVERIES - VOLATILE ORGANICS.
MOBIL OIL, BEAUMONT, TEXAS.
Sample
Identification
GCA
Control No.
M-API-1C 42696
M-API-2C 42700
M-DAF-1C 42708
M-PB-1C 42712
M-SB-1C 42716
Method blank 3/4/85
toluene
92
95
97
92
102
99
Percent Recoveries
Bromo- 04 - 1,2-
fluorobenzene dichloroethane
108
101
103
107
95
96
93
72
76
92
107
128
Average Percent Recovery 96
Relative Standard Deviation (%) 4
102
5
95
21
5-36
-------
TABLE 18. SURROGATE RECOVERIES - EXTRACTABLE ORGANICS.
MOBIL OIL, BEAUMONT, TEXAS.
Sample
Identification
M-UL-3A
Method blank
Spiked Sample
Duplicate Sample
Average Percent
GCA
Control No.
42719
QC986
QC987
QC988
Recovery
Relative Standard
Deviation(%)
D5-
Nitro-
benzene
a.
131
27
24
61
61
2-
Fluoro-
biphenyl
a
102
25
23
50
45
Percent
D14-
ter-
phenyl
a
105
22
18
48
49
Recoveries
D5 -
phenol
23
0.7
83
73
45
39
2-
fluoro-
phenpl
24
54
82
70
45
39
2,4,6-
tribromo-
phenol
47
34
118
102
75
41
aCould not be calculated due to a large dilution facter for the sample.
5-37
-------
Section 6.
Heches Butane Products Company
Port Neches, TX
6-1
-------
TABLE OF CONTENTS
Section Page
I. Introduction 6-5
II. Waste Characterization 6-7
Wastewater Treatment 6-7
Land Treatment 6-7
III. Waste Treatment Process 6-8
Wastewater Treatment Process 6-8
Land Treatment 6-12
IV. Sampling Information 6-13
Sample Location Description 6-13
Quality Assurance 6-17
V. Sample Analysis. 6-17
Analytical Summary 6-17
Quality Assurance 6-17
6-2
-------
LIST OF TABLES
Table
1 Waste Volumes Contributed to Neches Butane Products
Company Wastewater Treatment Process by Each User
Facility at Design Flow 6-6
2 Waste Loading Record for Landfarm Plot 3 6-7
3 Dimensions of Treatment Tanks and Basins Utilized at the
Neches Butane Products Company Wastewater Treatment
Facility 6-10
4 Liquid Sample Analysis of the Plant Effluent at the Neches
Butane Products Facility in Port Neches, Texas 6-18
5 Liquid Sample Analysis of the Clarifier Effluent at the
Neches Butane Products Facility in Port Neches, Texas 6-19
6 Liquid Sample Analysis from the Equalization Basin at the
Neches Butane Products Facility in Port Neches, Texas 6-20
7 Liquid Sample Analysis of the Polishing Pond Influent
at the Neches Butane Products Facility in Port
Neches, Texas 6-21
8 ICAP Analysis for Metals in Soil Core Samples from the
Landfarm at the Neches Butane Products Facility in
Port Neches, Texas 6-22
9 Soil Core Analysis from the Landfarm Area at the Neches
Butane Facility in Port Neches, Texas 6-23
10 Headspace Analysis of Soil Core Samples from the Landfarm
Area at the Neches Butane Facility in
Port Neches, Texas 6-24
11 Surrogate Recoveries - Volatile Organics. Neches Butane
Products, Port Neches, Texas 6-25
12 Surrogate Recoveries - Extractable Organics. Neches Butane
Products, Port Neches, Texas-Volatile Organics 6-26
6-3
-------
LIST OF FIGURES
Figure Page
1 Wastewater treatment processes at Neches Butane Products,
Port Neches, Texas «> 6-9
2 Liquid sampling locations, Neches Butane Products,
Port Neches, Texas 6-14
3 Land treatment sample point, Neches Butane Products,
Port Neches, Texas 6-15
6-4
-------
Site:
Site Contact:
Field Trip Personnel:
Time and Date:
Neches Butane Products Company
Highway 366 and Spur 136
Port Neches, Texas 77641
Mr. A.W. Catanach, Manager Environmental Control
(409) 724-4797
A.W. Catanach, Neches Butane Products Company
B.C. Davidson, Neches Butane Products Company
M.H. Clarke, Texaco Chemical Company
Terry Harrison, EPA
K.C. Hustvedt, EPA
Gene Riley, EPA
Susan Thomeloe, EPA
Rich Roat, GCA/Measurments
Tom Warn, GCA/Engineering
January 25, 1985
8:30 a.m.
I. INTRODUCTION
Neches Butane Products Company is a chemical manufacturing facility
located in a highly industrialized section of Port Neches, Texas. The
facility was originally built in 1943 by the United States government to
assist in meeting war-time demands for butadiene. In 1955, the facility was
sold into private ownership, changing hands several times over the next 26
years. Finally in 1981, Texaco, Incorporated purchased the facility and it
became a subsidiary of Texaco Butadiene Company.
The major products for Neches Butane Products Company remain butadiene
and MTB ether. Additionally, this facility is responsible for the operation
and maintenance of a non-RCRA wastewater treatment system serving five
industrial users. These users include: Neches Butane Products Company, Texaco
Chemical Company (TXD008076846), B.F. Goodrich, SYNPOL (TXD000789685), and
Shell Chemical Company.
6-5
-------
TABLE 1. WASTE VOLUMES CONTRIBUTED TO NECHES BUTANE PRODUCTS COMPANY
WASTEWATER TREATMENT PROCESS BY EACH USER FACILITY AT DESIGN FLOW.
User Facility
Neches Butane
Products Company
Texaco Chemical
Company
B.F. Goodrick
SYNPOL
Shell Chemical
Company
FCID
TXD008076846
TXD000789685
Majgr^Prgducts
butadiene/MTBE
Waste Volume
(GPM) Percent
2640
ethylene oxide/glycol 5060
triethanol amine
SBR
SBR
Isoprene
1650
1430
220
System Design Flow:
24
46
15
13
2
11,000
6-6
-------
II. WASTE CHARACTERIZATION
Wagtewater Treatment
The process wastewater and stonnwater runoff from the aforementioned user
facilities provide the influent wastestream for the wastewater treatment
plant. A breakdown of relative wastewater volumes for each user facility at
design flow is provided in Table 1.
Mr. Art Catanach explained that the wastewater treatment facility was
operated based on the Total Organic Carbon (TOC) content of the influent. For
this reason, on line TOC analyzers were used to monitor influent loadings.
Normally, the TOC loading is about 150-200 mg/1 on an average throughput of
10-11 MGD. Waste characterization for specific constituents was not available.
Land^Treatment
The waste material disposed of by land treatment consists solely of the
primary solids removed during the wastewater treatment process. At one time,
biosludges were also land treated. This practiced was halted, however, due to
significant odor problems. The bio-sludge is now hauled offsite to a
Browning-Ferris Industry landfill near Houston, Texas. Table 2 provides the
loading rate for the active land treatment tract, plot 3.
Table 2. Waste Loading Record For Landfarm Plot 3.
Loading Weight_Qf^dry_8Qlids_(lbs)
1st 709,197
2nd 1,183,160
3rd 262,914
Loading Duration
April 10 - May 10, 1979
Sept. 24 - Dec. 6, 1981
Oct. 1984 - (still active)
6-7
-------
III. WASTE TREATMENT PROCESSES
The waste treatment processes operated by Neches Butane Products Company
include an activated sludge wastewater treatment plant and a 55 acre
landtreatment area. The remainder of this section provides a detailed
description of the operation of these waste treatment processes.
Wastewater Treatment_PrQce88
The wastewater treatment process (see Figure 1) consists of four primary
clarifiers, an equalization basin, two aeration tanks, three final clarifiers,
and a ten acre (approx.) oxidation pond. In addition, several of the user
facilities have stormwater surge basins and emergency holding ponds for use
during process upsets. A listing of the dimensions of the tanks and basins
used during the treatment process is provided by Table 3.
The collection system used to transport the wastewater from the user
facilities to the treatment plant consists mostly of open ditches. These
ditches vary between three and six feet in width and can be either concrete or
earthen in structure. During storm events, stormwater runoff is combined with
process wastewater in these transport canals. If the hydraulic loading
exceeds the treatment plant capacity (i.e., 16 MGD), this combined influent
can be diverted to surge basins until the treatment process can adequately
handle the excess flow.
Primary Clarifiers
The primary clarifiers are open, circular, above-ground tanks with skimmer
arms. Three of the four tanks are used to remove solids from the combined
influent. These primary solids are then pumped through a six inch PVC line to
the land treatment area. The overflow from these clarifiers is directed to a
concrete trough. Here, it is neutralized before being discharged to the
equalization basin.
6-8
-------
VO
EQUALIZATION
BASIN
00
PRIMARY
CLARIFIERS
UJ
UJ
UJ
o:
FINAL
;CLARI-
(FIERS
AERATION
TANKS
. LAND TREATMENT AREA
NOTE'NOT TO SCALE
Figure 1. Wastewater treatment processes at Neches Butane Products, Port Neches, Texas.
-------
TABLE 3s DIMENSIONS OF TREATMENT TANKS AND BASINS UTILIZED AT THE NECHES
BUTANE PRODUCTS COMPANY WASTEWATER TREATMENT FACILITY
Primary, Cla f i f iers .• (3)
description
diameter
depth
Bio-sludge Thickener
description
diameter
depth
Equalization Basin
description
surface area
depth
Aeration Tanks (2)
description
size
capacity
aerators
impeller
Final Clarifiers (3)
description
diameter
depth
OxidatiQn_PQnd
description
surface area
depth
open, above ground, circular
(2) 80 ft., (1) 90 ft.
10 feet
open, above ground, circular
90 ft.
10 ft.
unlined, earthen basin
4 acres (est.)
4 ft. (est.)
open, ground level, square
250 ft. x 250 ft. x 15 ft. each
5.3 MG each
(6) 150 Hp (fixed) in each
cone-shaped, 9 ft. dia.
open, above ground, circular
97 ft.
12 ft.
unlined, earthen basin
10 acres (est.)
3-4 ft. (est.)
10 foot (design capacity)
6-10
-------
The remaining clarifier is utilized as a sludge thickener. Waste
bio-sludge is pumped to the tank where the solids are concentrated to about
three percent before being pumped to a filter press. The overflow is returned
to the equalization basin for further treatment.
Equalization Basin
The equalization basin is an unlined, earthen basin. Its trapezoidal
shape is designed to equalize the flow at both ends of basin. This allows for
better mixing, which in turn provides for a more consistent waste loading on
the biological system. The overflow from this basin is pumped to the aeration
tanks.
Aeration Tanks
The biological digestion of the wastewater is conducted in the treatment
system's two aeration tanks. These tanks have a capacity of 5.3 MG each and
have a sand-add mix base with a concrete pad directly under the aerators.
Twelve 150 horsepower, fixed aerators are use to supply a dissolved oxygen
level of about 2-3 mg/1. The overflow from these tanks is directed to the
final clarifiers.
During the visit, only one of the tanks was in operation with only five
of its six aerators in use. The waste material appeared brown in color with
no noticeable odor problem.
Final Clarifiers
There are three final clarifiers utilized to remove the bio-sludges from
the wastewater. These solids are either returned to the aeration system or
pumped to the bio-sludge thickener. The overflow from these tanks is directed
to the oxidation pond.
6-11
-------
Oxidation Fond
The oxidation pond represents the final stage of treatment before the
wastewater is discharged to the river. It is an unlined, earthen basin with
an average detention time of 30 hours. The water appeared clear and calm at
the time of the site visit.
Waste Bio-sludge Handling
As previously mentioned, the waste bio-sludge is pumped to a thickener.
After the solids are concentrated to approximately three percent, they are
pumped to a filter press. The filter press dries the bio-sludge and deposits
it in an open dumpster. When the dumpster is full, it is hauled offsite to
the Browning-Ferris Industry landfill near Houston, Texas.
Land Treatment
The land treatment area employed by Neches Butane Products Company is
comprised of 11 five acre tracts (see Figure 3). Each tract is separated by a
double levee system which allows an active plot to drain while another is
worked. Mr. Catanach explained that not all of the plots were currently
active, but that even the inactive plots are disked and then reseeded with
grasses at least once every year.
At the time of the site visit, plot 3 was the currently active tract.
Normal procedure begins by flooding the plot with the 7-15 percent solids from
the primary clarifiers, maintaining at least a two foot freeboard. A large
Kamatsu tractor is then used to spread the solids evenly across the tract.
The inner levee is then broken down so that the water layer is drained. This
drainage water is piped back to the wastewater treatment system.
Once the water layer has been drained, the remaining solids are tilled
into the soil to an average depth of six inches. The inner levee is then
repaired and the plot is ready for another application of sludge. The entire
process usually takes about a week to complete.
6-12
-------
The same plot remains active until a total loading of about one million
pounds of solids (dry weight) has been applied. Mr. Catanach stated that this
usually took 3-6 months. Once removed from active service the plot is tilled
and seeded with grasses.
The estimated active life remaining for the 55 acre land treatment area
was a minimum 15 years. Mr. Catanach stated that this estimate was based on
heavy metal concentrations accumulating in the soil. He further explained
that the two plots which are no longer used for land treatment are idle out of
courtesy to nearby homeowners and not because the soil has reached its
limiting capacity to receive further waste. Additionally, since they are no
longer landtreating bio-sludges, the reduction in waste volume allows for the
reduction in active land treatment area without diminishing the efficiency of
the treatment operations.
IV. SAMPLING INFORMATION
Sample Location Description
Liquid samples were taken from four areas:
o Texaco Chemical plant effluent (Neches Butane wastewater treatment
influent),
o the primary clarifiers,
o the equalization basin, and
o the oxidation pond.
Sampling points can be seen in Figure 2. In addition, one of the active
landfarm plots was sampled (Figure 3).
6-13
-------
TEXACO
EFFLUENT
FILTER SCREEN
WOODEN PLATFORM
NECHES
BUTANE
INFLUENT
2a Chemical Plant Efflutnl
INFLUENT
2c Equalisation Batln
cr>
I
2b ClarlJUfi
TO <
RIVER
2d Pollihlng Pond
\
INFLUENT
PIPE
NOTEiNOT TO SCALE
® SAMPLE LOCATIONS
Figure 2. Liquid sampling locations, Neches Butane Products, Port Heches, Texas,
-------
nESERVOIH ROAD
I
M
Ol
HWY. SPUR NO. 136
'\ C
LEGEND:
"I PLOT NUMDEM
X Sample I'olnl:
]'vjj;tife 3. Ldncltrcotineiik sninplc point, Nochcfi Ihit/ine I'rodnotn, I'or I: Nnclion, Tnxna.
-------
Chemical Plant Effluent
Wastewater from Texaco Chemical is collected by a concrete canal and
piped to the Neches Butane wastewater treatment system. The point at which
the wastewater ditch enters a pipe leading to the treatment system was sampled
(CE-1A-E, Figure 2a). The surface of the liquid was agitated and very foamy
at this point, and brown in color with a slight organic smell. Liquid
temperature was 78°F. Due to aeration of the wastewater, air bubbles
unavoidably formed in the sample vial.
Primary Clarifiers
The three primary clarifiers constitute the first treatment step at
Neches Butane. One sample near the effluent of one of these clarifiers was
taken (CL-1A-E, Figure 2b). The surface was calm, and the liquid clear and
74°F.
Equalization Basin
The equalization basin receives wastewater from the clarifiers. A sample
near the influent was taken (EQ-1A-E, Figure 2c). The surface was calm, and
the liquid dark in color and 72°F.
Oxidation Pond
The oxidation pond is the last step in the wastewater treatment system.
A point near the influent was selected for sampling (PP-1A-E, Figure 2d).
Sample temperature was 66°F. Water from this impoundment is released to the
river.
Landfarm Plot 3
A soil core (CO-lA-L) was taken from plot 3 (Figure 3). Sludge with 7-15
percent solids was spread in this location. The soil surface had been plowed,
was rough and very wet.
6-16
-------
Qua1ity_Assurance
Sampling procedures were employed as described in the Quality Assurance
Project Flan dated 30 October 1984. Liquid samples were collected in
quintuplicate, as a standard procedure, with one of the five samples retained
by the facility as a split. Soil core samples were collected in triplicate.
The facility split for these samples was provided in a 500-ml amber glass
bottle due to the limited supply and expense of the custom-built soil core
samplers. The remaining quadruplicate liquid samples and the duplicate soil
samples were returned to the GCA Analytical Laboratory in Bedford, MA where
they were received into the sample bank.
Sample custody and handling procedures included the use of sample tags,
chain-of-custody sheets, refrigeration of samples between sampling and
analysis, and shipping of samples in coolers sealed with custody seals. In
addition, each sample was assigned a unique sample code which linked it to the
facility, the source, and the sample point.
V. SAMPLE ANALYSIS.
Analytical^Summary
Tables 4 through 10 provide the analytical summary reports for the samples
collected during the site visit (see Appendix A). These tables present the
major compounds quantified by GCA Corporation/Technology Division. The actual
data report sheets for the samples are provided in Appendix B.
Analytic procedures were followed as outlined in Appendix D. Aqueous
samples were analyzed for volatile organics; soil samples were analyzed for
extractable organics, pesticides and PCBs, trace metals, percent solids, and
oil and grease.
Quality Assurance
Chain of custody and quality control protocols appear in Appendix E.
Surrogate spikes were utilized in conjunction with LNVA samples for volatile
organics and extractable organics; these recoveries are reported in Table 11
and Table 12, respectively.
6-17
-------
TABLE 4. LIfiUID SABPLE ANALYSIS OF THE PLANT EFFLUENT AT THE
NECHES BUTANE PRODUCTS FACILITY ID PORT NECHES, TEIAS
S3SSS3STS3SSZZSS3SS
c
Concentration (ug/1)
Coipounds Detected
Chlorofors
1,2-Dichloroethane
1,1.1-Trichlcroethane
Acetone
1,2-Dichloropropane
Methyl ene chloride
Broiodichloroiethane
Toluene
Chlorobenzene
Benzene
2-Hexanone
a
Analysis 1
244
190
154
92
20
17
14
b
Analysis 2
115
144
113
155
9
31
B
5
5
22
22
Average
179.5
167
134.5
123.5
14.5
24
11
5
5
22
22
TOTAL HAL06ENATED ORSAHICS 425 425
TOTAL OXYGENATED ORSANICS 177 177
TOTAL AROSATICS 27 27
TOTAL UNIDENTIFIED OREANICS 144 144
TOTAL WHC 775 775
a
Analysis of saiple 42795HS by SCA Corporation using 6C/HS.
b
Analysis of saiple 42795 by ECA Corporation using EC/MS.
c
ug/1 * ppb assuring a density of 1.
6-18
-------
TABLE 5. LIQUID SAHPLE ANALYSIS OF THE CLARIFIES EFFLUENT AT THE
HECHES BUTANE PRODUCTS FACILITY IN PORT HECHES, TEIAS
a,b
Coipounds Detected Concentration (ug/1)
Styrene
Etnyl benzene
Retnylene chloride
Toluene
Chi or of on
TOTAL HALQBENATEO OREANICS
TOTAL AROHATICS
TOTAL UNIDENTIFIED OREANICS
TOTAL NMHC
xsxxaaxsssrsssKsssssassxassxsassssxssi
12040
2240
300
180
140
640
H4BO
1138
1&2SB
8gsaaasss3«asaas'rsgassjsssJaa«s-^-JS3sa«aas
a
Analysis of saiple 4279B by GCA Corporation using GC/HS.
b
ug/1 = ppb assuiing a density of 1.
6-19
-------
TflBLE 6. LIQUID SAMPLE ANALYSIS FRQK THE EQUALIZATION BASIM AT THE
HECHES BUTANE PRODUCTS FACILITY IM PORT NECHES, TEXAS
a,b
Coapounds Detected Concentration (ug/1)
Slyrene
Etnyl benzene
Metnylene chloride
Chlorofori
Toluene
TOTAL HALC6ENATED OR6ANICS
TOTAL AROBATICS
TOTAL UNIDENTIFIED ORGAN I CS
TOTAL mm
7180
15iO
fciO
220
120
B90
8860
1572
11312
a
Analysis of saiple 42802 by ECA Corporation using 6C/HS.
b
ug/1 * ppb assuring a density of 1.
6-20
-------
TABU 7. LIQUID SAME ANALYSIS OF THE FOLIEH1NB POND INFLUENT AT THE
NECHES BUTANE PRODUCTS FACILITY IN PORT HECHES, TEIAS
gggCTg-gg» t--—f---^—m,i —•--•-•gi --— -m-!»-.'. ;••» .- -_ i - ___—»,
a,b
Coipounds Detected Concentration Iug/1)
Chlorofori 8
TOTAL HALOSEHATED ORGANICS 8
TOTAL UNIDENTIFIED OfiSANICS 314
TOTAL NHHC 322
a
Analysis of saiple 42B07 by 6CA Corporation using EC/US.
b
ug/1 * ppb assuring a density of 1.
6-21
-------
TABLE 8. ICAP ANALYSIS FOR METALS IN SOIL CORE SAMPLES FROH THE
LANDFARf! AT THE NECHES BUTANE PRODUCTS FACILITY I*
PORT NECHES, TEIAS
S3ssxsxsxtsassssaaTrfffsss9^T~T~s3ssasss3S3~±aua*frsrsaM£sssat-T~s
a,b
Elsient Concentration (ug/g)
Aluiinui
Antiiony
Arsenic
Bariui
Berylliui
Boron
Cadiiui
Calciui
Chroiiui
Cobalt
Copper
•
Iron
Lead
Hignesiui
Manganese
Rolybdenui
Nickel
Seleniui
Silicon
Silver
Sodiui
Strontiui
Thalliu
Tio
Titaniu
Vanadiui
Zinc
c
19000
C
3.9
6.?
178
3.83
2.45
<0.3
9270
229
4.12
120
13200
20
3500
171
<0.4
18.5
c
6.9
110
1.08
c
530
45
c
3
22.7
25.9
32
201
a
Analysis of saiple 42810 by SCA Corporation using ICAP.
ug/g * licrograis per grai.
c
These values should be considered seii-quantitative due to severe
latrix interferences encountered during the analysis.
6-22
-------
TABLE 9. SOIL CORE ANALYSIS FROH THE LANDFARH AREA AT THE
NECHES BUTANE FACILITY IN PORT NECHES, TEIAS
a,b
Paraaetsr Concentration (ig/kg)
Toxaphsne <3.0
a 43
Analysis of saaple 42BIO by ECA Corporation using GC N/Ni ECD
b
ig/lcg = ppa assusing a density of 1.
6-23
-------
TABLE 10. HEAD5PACE ANALYSIS OF SOIL CORE SAMPLES FRQN •
THE LANDFARH AREA AT THE NECHES BUTANE FACILITY
IN PORT NECHE3, TEXAS
.....
Paraaeter Concentration tug/kg 1
Hethytene Chloride 320
a
Analysis of saaple 42810 by GCA Corporation using EC/MS.
b
ug/g = ppb assuaing a density of 1.
6-24
-------
TABLE 11. SURROGATE RECOVERIES - VOLATILE ORGANICS
NECHES BUTANE PRODUCTS, PORT NECHES, TEXAS.
Sample
Identification
NB-CE-1D
NB-CL-1C
NB-EQ-1C
NB-PP-1D
Method blank
GCA
Control, No.
42795
42798
42802
42807
3/4/85
3/20/85
toluene
107
98
98
87
99
110
Percent Recoveries
Bromo-
fluorobenzene
107
106
106
120
96
114
D4 - 1,2-
dichlorpethane
86
81
114
89
128
44
Average Percent Recovery
Relative Standard Deviation (%)
101
10
108
8
90
29
6-25
-------
TABLE 12. SURROGATE RECOVERIES - EXTRACTABLE ORGANICS
NECHES .BUTANE PRODUCTS, PORT NECHES,
TEXAS - VOLATILE ORGANICS
Sample
Identification
NB-CO-1A
Method blank
Spiked Sample
Duplicate Sample
Average Percent
GCA
Control No.
42810
QC986
QC987
QC988
Recovery
Relative Standard
Deviation (7.)
D5-
Nitro-
benzene
11
,131
27
24
48
56
2-
Fluoro-
biphenyl
11
102
25
23
40
42
D14-
ter-
phenyl
9
105
22
18
39
45
Percent
D5 -
phgnol
19
0.7
83
73
44
40
Recoveries
2-
f luoro-
phenol
19
54
82
70
56
27
2,4,6-
tribrotao
phenol
36
34
118
102
73
44
aCould not be calculated due to a large dilution facter for the sample.
6-26
-------
Section 7.
Texaco Oil Refinery
Port Arthur, TX
7-1
-------
TABLE OF CONTENTS
Section Page
I. Introduction 7-6
II. Waste Characterization 7-7
Wastewater Treatment System 7-8
Land Treatment Operation 7-8
III. Waste Treatment Processes 7-8
Wastewater Treatment 7-8
Land Treatment 7-13
Landfill 7-14
IV. Sampling Site Descriptions... 7-14
Wastewater Treatment 7-14
Land Treatment 7-18
Quality Assurance 7-21
V. Sample Analysis 7-22
Analytical Summary 7-22
Quality Assurance 7-22
7-2
-------
LIST OF TABLES
Table
1 Average Daily Process Waste Quantities at Texaco Port
Arthur Refinery, Port Arthur, TX 7-7
2 Physical Dimensions of Vastewater Treatment Process Tanks
and Basin at Texaco Port Arthur Refinery, Port Arthur,
TX 7-10
3 Land Treatment Waste Application Log for Subplots 3A and
3B at Texaco Port Arthur Refinery in Texas During July
and August 1984 7-20
4 Liquid Sample Analysis from Equalization Basin No. 11 at
the Texaco Oil Refinery in Port Arthur, Texas 7-23
5 Liquid Sample Analysis from the West Ditch Separator at
the Texaco Oil Refinery in Port Arthur, Texas 7-24
6 Liquid Sample Analysis from the Inlet of the West Ditch
Separator at the Texaco Oil Refinery in Port Arthur,
Texas* , 7-25
7 Liquid Sample Analysis from the Inlet of the West Ditch
Separator at the Texaco Oil Refinery in Port Arthur,
Texas 7-26
8 Liquid Sample Analysis from the Drainage Ditch at the Texaco
Oil Refinery in Port Arthur, Texas 7-27
9 Liquid Sample Analysis from the 3VPS Separator at the Texaco
Oil Refinery in Port Arthur, Texas 7-28
10 Liquid Sample Analysis of Activated Sludge Waste from a
Closed Holding Tank at the Texaco Oil Refinery in
Port Arthur, Texas 7-29
11 Liquid Sample Analysis from Clarifier C at the Texaco
Oil Refinery in Port Arthur, Texas 7-30
12 ICAP Analysis for Metals in Sludge from Landfarm Area
No. 7 at the Texaco Oil Refinery in Port Arthur, Texas.... 7-31
13 ICAP Analysis for Metals in Soil Core from Landfarm Area
No. 3A at the Texaco Oil Refinery in Port Arthur, Texas... 7-32
7-3
-------
List of Tables (continued)
Table Page
14 ICAP Analysis for Metals in Soil Core from Landfarm Area
No. 3B at the Texaco Oil Refinery in Port Arthur, Texas... 7-33
15 Analysis of Solids, Oil and Grease, and Moisture Contents
of Soil from Landfarms No. 7, 3A, and 3B from the Texaco
Oil Refinery in Port Arthur, Texas 7-34
16 Surrogate Recoveries - Volatile Organics. Texaco, Port
Arthur, Texas 7-35
17 Surrogate Recoveries - Extractable Organics. Texaco,
Port Arthur, Texas 7-36
7-4
-------
LIST OF FIGURES
Figure
1 Texaco Port Arthur Refinery wastewater treatment
system 7-9
2 Wastewater treatment sampling points at Texaco
Port Arthur Refinery 7-15
3 Land treatment area sampling points at Texaco Port
Arthur Refinery 7-19
7-5
-------
Site:
FCID:
Site Contact:
Field Trip Personnels
Visit Time and Date:
I. INTRODUCTION
Texaco Incorporated Port Arthur Refinery
P.O. Box 712
Port Arthur, Texas 77640
latitude: 29° 53'14"N
longitude: 93° 58' 42"W
TXD008097529
Ronald L. Korbini
(409) 989-7171
Ronald L. Korbini, Supervisor, Conservation Division,
Texaco
Dennis L. Brown, Environmental Health & Safety,
Texaco
K.C. Hustvedt, EPA
Susan Thorneloe, EPA
Terry Harrison, EPA
Gene Riley, EPA
Scott Osbourn, GCA/Engineering
Douglas Seely, GCA/Measurements
January 23, 1985
8:30 a.m.
The Texaco Port Arthur Refinery is a sprawling facility located in an
urban industrial area along the Gulf Coast of Texas. Process operations were
initiated at this site in 1903. The refinery has a crude oil processing rated
capacity of approximately 200,000 barrels per day. At the time of inspection,
Texaco was operating at a rate of approximately 200,000 barrels per day.
Operations conducted at Texaco include atmospheric distillation, vacuum
distillation, fluid catalytic cracking, catalytic reforming, catalytic
hydrocracking and hydrotreating, and lube oil processing.* The plant operates
continuously. The approximate percentage product distribution is contained in
Appendix F. The Part B permit application is currently being assembled.
Mr. Korbini of Texaco indicated that a letter was sent to Susan Wyatt
(CPB/ESED) and to GCA Corporation stating their belief that contractors are
not designatable EPA employees under the Clean Air Act.
7-6
-------
II. WASTE CHARACTERIZATION
Texaco's Port Arthur facility is equipped with a wastewater treatment
system, a land treatment or landfarming operation and a landfill. Table 1
lists average daily process waste quantities generated at the facility (based
on 1983 data).^ A characterization of the wastes received and treated within
each of these treatment processes is detailed below.
TABLE 1. AVERAGE DAILY PROCESS WASTE QUANTITIES AT TEXACO
PORT ARTHUR REFINERY, PORT ARTHUR, TXA.
EPA
Waste
Code
K051
K050
K052
NA
NA
NA
NA
NA
NA
NA
NA
Type of Waste
API Separator Sludge
Heat exchanger bundle cleaning sludge
Leaded tank bottoms
Clay fines
Cooling tower sludge
Primary oil/solids/water^ separator
sludge (other than API)
Spent acid sludge
Spent catalysts (other than FCC)
Waste FCC catalyst
Tank bottoms (other than leaded)0
Waste activated sludge 1
Quantity
(lbs/day)B
5381
104
8559
3967
6532
800
3425
1107
1085
16,751
,711,066
Method of Disposal
Off site
Off site
Off site
Landfill
Off site
Land treatment
Off site
Off site
Landfill
Land treatment
Surface
impoundment
AReference 2
BBased on 1983 annual data, 400,000 bbl/day throughput. Since 9/84 throughput
has been 200,000 bbl/day.
GPrimary oil/solids/water separator sludge - comes from ditches within the
plant; 507. H20, 207. oil, 307. solids; pH = 6-8
^on-leaded tank bottoms - approx 99% FeO£ and 1% saturates (refined oils)
7-7
-------
Wastewater Treatment System
The wastewater treatment system handles refinery wastewater, rainwater
runoff collected at the refinery, and cooling water blowdown. The average
daily wastewater throughput is approximately 15 million gallons.
Land Treatment..Operation
The land treatment operation receives sludges produced within the
wastewater treatment system. The sources of the sludges are described in
detail in the following section on WASTE TREATMENT PROCESSES. Separator
sludges, as well as non-leaded tank bottoms, are presently not dewatered prior
to land treatment. These sludges typically consist of 15 to 30 percent oil
content by weight, 40 to -50 percent water and the remainder solids. Waste
biosludge from the biological treatment unit and the clarifiers is routed to
the waste biological sludge holding tanks. These tanks serve to concentrate
the biosludge charge to the dewatering belt filter. Oil content is <5 percent
by weight. The biosludge is dewatered to 18 percent solids by weight prior to
land treatment.
III. WASTE TREATMENT PROCESSES
Was t ewater_Treatment
A flow diagram of the Texaco Refinery wastewater treatment system is
presented in Figure 1. Specifications of open tanks and basins in the system
are listed in Table 2.
Open drainage ditches, located throughout the plant, route refinery
wastewater and stormwater runoff to one of four oil/water separators. Three
of these separators are referred to as earthen separators, but actually are
constructed of corrugated steel piling sidewalls. Wastewater charged to each
of these separators depends upon their particular location within the plant.
For example, the West ditch separator receives charge from the catalytic
reformers, the compressed gas plant, and hydrotreating and hydrocracking
operations. Wastewater received at the #2 Drainage Plant Separator originates
7-8
-------
WASTEWATER FROM
PROCESS PIPES
WASTEWATER
OIL RECYCLED TO CRUDE UNITS
CHEMICAL
TREATMENT
AREA
API BOTTOMS
TO
LANOTREATMENT
o
o
ac
o
o
Zj
BIO-SLUDGE
HOLDING TANKS
NOT TO SCALf
Figure 1. Texaco Port Arthur Refinery wastewater treatment system.
-------
TABLE 2. PHYSICAL DIMENSIONS OF WASTEWATER TREATMENT PROCESS TANKS
AND BASINS AT TEXACO PORT ARTHUR REFINERY, PORT ARTHUR, TX.
Oil/Water,Separators (3)
description
dimensions
ReservQir_No._ll
description
surface area:
north basin
south basin
depth
Aerated Lagoon
description
capacity
depth
aerator
Bigrslydge_Holding Tanks (2)
description
diameter
depth
Clarifiers (3)
description
diameter
depth
open, ground-level rectangular ditches
corrugated steel piling sides, earthen
bottoms
150 ft. x 100 ft. x 10 ft.
200 ft. x 100 ft. x 10 ft.
200 ft. x 100 ft. x 10 ft.
2 earthen, rectangular impoundments
24 acres
31 acres
7 ft. (average)
open, ground-level, rectangular
concrete banks and earthen bottom
12 MGD
28-1800 Hp totaKrange 20-100Hp)
open, above-ground, circular
30 ft. (approx.)
15 ft. (approx.)
open, above-ground, circular
100 ft. (approx.)
12 ft. (approx.)
7-10
-------
primarily within the catalytic cracking unit, the FCCU, and the sulfuric acid
alkylation unit. The North ditch separator receives water from crude and lube
oil areas. These separators also receive process wastewater upstream via
submerged fill feed lines. The skimmed oil layer flows by gravity to an
underground pumphouse sump for collection and eventual recycle to slop crude
processing (the bottom sediment and water plant). The fourth separator,
termed the vacuum pipe separator, is essentially a closed system receiving
wastewater from the crude units, desalting units, the vacuum pipe still, and
cooling water blowdown. Makeup water to this loop is provided by reservoir
no. 11 and the effluent is primarily discharged to reservoir no. 4. This is a
covered-top cascading separator.
Oil skimmed from all separators is routed to a holding area consisting of
four storage tanks at 80,000 barrels capacity each. Steam heat is applied to
these tanks allowing oil to rise to the top where it is skimmed and recovered
to the crude units. Water is drained off the bottom of these tanks and routed
to BS & W Plant where sulfuric acid is added to obtain a pH of approximately
two. The effluent from this unit is charged to a concrete-lined separator.
The skimmed oil is again sent to slop oil processing and the wastewater routed
to the West ditch separator.
Separator sludges, as well as non-leaded tank bottoms, are presently not
dewatered prior to land treatment. These sludges consist of 15 to 30 percent
oil content by weight, 40 to 50 percent water and the remainder solids.
Wastewater flows directly from the three oil/water separators to
equalization reservoir no. 11. Reservoir no. 11 is divided into two basins -
North and South. The North basin has an estimated surface area of 24 acres
and an average depth of seven feet. The South basin has approximately the
same average depth and a 31 acre surface area. The North and South basins
currently contain an estimated 27 and 35 million gallons of wastewater,
respectively. Oil recovered here can be directly pumped to slop oil
processing.
Reservoir no. 11 and the other storm water holding reservoirs (318 acres
of total reservoir area) were removed from RCRA authority when Texaco
7-11
-------
submitted a revised Part A in consideration of the dilution or mixture rule.
Collectively, these reservoirs provide charge to the digestion or biological
treatment area.
The biological treatment area is an open, aerated lagoon approximately 12
million gallons in capacity. This is a cement and soil-lined basin with a
hardened embankment at the perimeter. Typical flow through the lagoon
averages 8000 to 10,000 gallons per minute. The biotreatment area is equipped
with approximately 28 aerators, ranging in size from 20 to 100 horsepower.
Collectively, these aerators, manufactured by Aqua-Aerobic, can provide a
maximum of 1800 total horsepower. Texaco typically operates at a collective
average of 1000 to 1200 total horsepower. Biosludge from the clarifier
bottoms is pumped to storage, then belt filtered or recycled. Two open-top
storage tanks are provided for sludge storage. Each tank is approximately 15
feet high and 30 feet in diameter. These tanks serve to concentrate the
sludge charge to the dewatering belt filter. This sludge is dewatered to
approximately 18 percent solids by weight content prior to land treatment.
Biological sludge filter cakes resulting from belt press operations provide
the majority of land treated material. Wastewater from the belt press
operation is recycled to the biological treatment unit.
Aeration basin effluent is then charged to one of three clarifiers
operating in parallel, on site. These are circular, open-top clarifiers
equipped with rotating skimmer arms. Each clarifier is approximately 100 feet
in diameter and 12 feet deep. Sludge removed in the clarifiers comprises
microbes from the biotreatment tank. A portion of this sludge is recycled to
the biotreatment tank, and a portion is fed to one of the two waste biological
sludge storage tanks previously mentioned. Again, wastewater from the press
is piped back to the biological treatment unit.
Water from the clarifiers is piped to Alligator Bayou. Water flows to
Taylor's Bayou and then is discharged to Lake Sabine (NPDES #0005835). The
total organic carbon (TOC) concentration in water entering the biological
treatment unit is approximately 250 ppm and the TOC in the final discharge is
about 70 ppm. Based on the total volume of the biotreatment unit and
reservoir no. 11, total retention time in the entire wastewater treatment
system was estimated by Texaco at approximately five days.
7-12
-------
Land_Treatment
The land treatment operation, initiated in 1980, was previously a dredge
spoil area for dredgings from the process waste reservoir. Land treatment at
the Texaco refinery is divided into Class I and Class II waste treatment
areas. The Class I area consists of three plots of three acres each and one
plot of one acre (ten acres total area), designated as plot nos. 1, 2,
3a and 3b. The Class II land treatment area has a capacity of 44 acres;
however, only 30 acres are presently operational. For the past three years,
the land treatment areas have been actively used for nine to ten months each
year.
Tank bottoms are applied to the Class I land treatment area. These
wastes are not dewatered before spreading. Some tank bottoms low in flash are
considered to be the only hazardous material at the Class I area. Biological
sludge is also applied here to increase retention capacity of the soil;
however, this sludge is primarily disposed at the Class II land treatment
area. For almost all wastes, the typical range of characteristics is as
follows: oil content of 15 to 30 percent (20 percent average), water content
of 40 to 50 percent and the remainder composed of solids.
Waste is applied to each subplot approximately once a month, or less
frequently when oil levels are too high. Generally, an application rate of
less than 100 barrels per acre per month of oil content is the desired limit.
A maximum of two percent oil content in the soil is generally the guide for
respreading, although sometimes visual determinations are made according to
soil color or texture. There may also be other limitations in the waste, such
as salts or heavy metals that would limit the application rate, rather than
the amount of oil.
Sludges high in water content are brought to the site by vacuum truck,
while heavy solidified wastes are distributed over the land treatment area
from trucks and spread by a bulldozer. Wastes are not mixed into a composite
and applied, rather specific wastes are usually designated to be applied to
each site. Texaco tries to maintain an eight inch soil incorporation zone
and, in order to keep the soil aerobic, the frequency of tilling is usually
with each waste application. Often, tilling is limited by weather conditions
7-13
-------
such as heavy rainfall. The surface soil .texture is a sandy clay loam
underlaid with Beaumont clay.
Texaco has been trying to improve their land treatment techniques by
developing certain guidelines (i.e., check pH, cation exchange, need for
fertilization, etc.). Soil pH is maintained at about seven to increase waste
assimilation and precipitate out most of the heavy metals. Generally, heavy
metals are water insoluble at pH values above seven, below this level the
leachability of metals markedly increases. Soil pH strongly influences
microbial activity and should be maintained between seven and nine. Available
nitrogen and/or phosphate is added to achieve the maximum biodegradation
rate. These inorganics are supplied by agricultural fertilizers and are added
as needed.
Landfill
There is a small Class II landfill area on site used primarily for plant
trash. Waste not landfilled (i.e., sulfur, bagged asbestos, neutralized acid
sludges, and leaded tank bottoms) is handled by commercial waste disposal
firms, such as Rollins or Chemical Waste Management. There are no drumming
operations at the plant, although a general plant cleanup had recently been
completed, resulting in a small number of drums observed at the landfill
area. At the time of inspection, Rollins was repacking these drums and
preparing them for shipment off site.
IV. SAMPLING SITE DESCRIPTIONS
Wastewater Treatment
After a review of overall facility wastewater flow, it was decided to
conduct sampling at seven sites within the wastewater treatment system.
Sampling points at each of the treatment processes are illustrated in Figure 2.
7-14
-------
ROAD
r
K1
Ul
POINT
OPEN
DRAINAGE DITCH
~~|® POINT EB-i
EQUALIZATION BASIN NO. II
NOT TO SCALP
D SAMPLING POINT
TL
®POINT
WALKWAY
WALKWAY
INFLUENT
POINT AI-1
API SEPARATOR
CLARIFIER C
® POINT V-l
VACUUM PIPE
SEPARATOR
PUMP
POINT
SL-l
ACTIVATED
SLUDGE LINE
Figure 2. Wastewater treat.ent sampling points at Texaco Port Arthur Refinery.
-------
Open Drainage Ditch
Sampling was conducted at one of the many open drainage ditches which
carry plant wastewater and storm water runoff. This particular ditch provides
charge to the North ditch separator. The wastewater surface was very oily,
containing large orange solids. Water temperature at the time of sampling was
approximately 68° F. A significant petrochemical odor was very apparent. The
sample taken was milky in appearance with a scummy oil meniscus. Orange, oily
drops subsequently formed in the VGA vial (Figure 2, point DD-1.)
Oil/Water Separator
This earthen separator, termed the West ditch separator, receives charge
from the West side of the plant. This charge consists of wastewater from
catalytic reformers, the compressed gas plant, the hydrotreating and
hydrocracking operations. This is not a cascade-type separator, rather
wastewater passes beneath a baffle and the skimmed oil layer feeds by gravity
underground to a pumphouse sump. Sampling was conducted downstream of this
baffle (Figure 2, point A-l). The wastewater was green in color with some
suspended solids. A thin oily layer was observed over approximately 75
percent of the surface area downstream of the baffle. Water temperature at
the time of sampling was approximately 68° F.
Oil/Water Separator Inlet
Sampling was also conducted at the West ditch separator inlet. At the
point of sampling (Figure 2, point AI-1), influent was being received via a
submerged fill pipe. An extremely heavy oil scum entrained with air bubbles
covered the entire surface area at this location. Water temperature in this
vicinity was 70° F.
7-16
-------
Vacuum Pipe Separator
Wastewater charge is received from the crude units and the vacuum pipe
still (i.e., wastewater from desalting and cooling tower blowdown). This is a
covered-top, cascading-type separator. Sampling was conducted upstream of the
system cascade where the surface was green in color (Figure 2, point V-l). An
oily film covered approximately 50 percent of the surface area in this
vicinity. Water temperature was 76° F. The sample taken was milky in
appearance with a thin oily meniscus.
Equalization Basin
Sampling was conducted at the south end of equalization basin no. 11.
Wastewater charged to this basin is primarily from all Oil/Water Separators on
site. The basin contained green colored water with some suspended solids.
Possibly as much as one-third of the basin surface area was covered by a thin
oily layer. A heavy oil slick at the southwest corner of the basin was being
vacuumed and pumped directly to slop oil recovery. Sampling was conducted at
an outfall in the vicinity of a thin oily layer (Figure 2, point EB-1). Water
temperature at this site was approximately 48° F. Wind action was creating
small ripples, however, the basin surface was essentially smooth. The sample
taken had the appearance of dirty water topped with a thin oily skim.
Clarifier
Clarifier C consists of a cylindrical inner tank drained by an outer
ring. The water was green with some white suspended solids. Sampling was
conducted from the walkway at a point above the clarifier outlet (Figure 2,
point C-l). There were some isolated oily areas on the surface, however no
real oil film. Water temperature in this area was approximately 50° F. The
sample taken was light green with some suspended solids topped by an oily
sheen on the meniscus.
7-17
-------
Activated Sludge Line
Waste biological sludge pumped from the clarifiers is routed to one of
two open-top storage tanks. These tanks serve to concentrate the sludge
charge to the dewatering belt filter. A process valve associated with the
holding tanks was opened, enabling a sample to be collected from an open-ended
pipe (Figure 2, point SL-l). The sample was essentially a clear liquid with
brown suspended solids.
Land_Treatment
Soil cores were taken at two of the four subplots (3a and 3b) within the
Class I land treatment area and a grab sample was collected at the Class II
area. Sampling locations are detailed in Figure 3. Table 3 lists the types
and amounts of waste applied to subplots 3a and 3b during July and August 1984.
Roads within the land treatment areas consisted mainly of gravel
underlaid by old construction material. A five mile per hour speed limit was
posted and there seemed to be very little fugitive dust potential.
Class I Land Treatment Areas
The land treatment activity log was checked in order that sampling could
be conducted at the sites of most recent activity. In this manner, subplot 3a
was selected. A soil core was extracted and it was subsequently determined
that we had sampled at subplot 3b. Subplot 3b had not seen activity since
early August and was last tilled at about that time. It appeared as though
oily tank bottom material had been tilled into the soil. There were some
areas of standing water and the soil was fairly moist up to three inches below
the surface. Since we had not meant to sample at subplot 3b, only one core
was taken (Figure 3, point 3b-l).
A set of soil core samples was taken at a point within the northwestern
corner of subplot 3a (Figure 3, point 3a-l). It appeared as though the soil
contained a large percentage of oily sludge, possibly tank bottoms. The soil
surface was dry and became increasingly wet approximately two to three inches
7-18
-------
I
M
VO
CLASS 1 LANDTREATMENT AREA
CLASS Jl LANDTREATMENT AREA
NOT TO SCALE
©SAMPLING POINT
POINT 3A-1®
3a
117'
® POINT 7-1
Figure 3. Land treatment area sampling points at Texaco Port Arthur Refinery.
-------
TABLE 3. LAND TREATMENT WASTE APPLICATION LOG FOR SUBPLOTS
3A AND 3B AT TEXACO PORT ARTHUR REFINERY IN TEXAS
DURING JULY AND AUGUST 1984.A
Application
Date
7-6
7-9
7-9
7-10
7-10
7-11
7-13
7-31
7-31
7-31
7-13
8-6
8-7
8-8
8-13
8-16
Plot
3a
3a
3a
3a
3a
3a
3a
3a
3a
3a
3a
3b
3b
3a
3a
3b
% Oil
28
28
27
28
23
23
<5
15
15
15
15
30
30
25
26
23
% Water
40
40
18
20
12
12
<5
10
10
10
10
10
10
10
43
49
Description
Fuel Oil Tank Bottoms
Fuel Oil Tank Bottoms
Fuel Oil Residual and
Sand
Fuel Oil Tank Bottoms
Oily dirt
Oily dirt
Oily dirt
Oily dirt
Oily dirt
Oily dirt
Oily dirt
Tank filter bottoms
Solid oxides, tank
bottoms
Oily sand
Tank bottoms
Tank 12465
Amount
90bbl
SObbl
3yd3
SObbl
112yd3
42yd3
18yd3
14yd3
12yd3
14yd3
14yd3
3yd3
3yd3
3yd3
3yd3
3yd3
AMost recent data available at the time of inspection.
7-20
-------
below the surface. The soil appeared to be fairly compacted below the surface
and it is anticipated that there may not be much pore space with the soil
cores taken. At the time of sampling, ambient temperature was 50° F and the
soil temperature was approximately 48° F.
Class II Land Treatment Area
Land treatment area no. 7 did not appear to have been active for quite
some time. In fact, there were many grassy areas within this subplot. An
amber jar was used to obtain a grab sample at the far eastern edge of the
subplot (Figure 3, point 7-1). An isolated pile of ditch dredging sludge had
been dumped at this location. The material was greyish-black in color and
appeared to be high in moisture content. The material had not been tilled
into the soil and apparently was dumped and left to dry.
Quality Assurance
Sampling procedures were employed as described in the Quality Assurance
Project Plan dated 30 October 1984. Liquid samples were collected in
quintuplicate, as a standard procedure, with one of the five samples retained
by the facility as a split. Soil core samples were collected in triplicate,
except in the case of landfarm plot 3b, where only one core was taken (see
sample location description). The facility split for these samples was
provided in a 500-ml amber glass bottle due to the limited supply and expense
of the custom-built soil core samplers. The remaining quadruplicate liquid
samples and the duplicate soil samples were returned to the GCA Analytical
Laboratory in Bedford, MA where they were received into the sample bank.
Sample custody and handling procedures included the use of sample tags,
chain-of-custody sheets, refrigeration of samples between sampling and
analysis, and shipping of samples in coolers sealed with custody seals. In
addition, each sample was assigned a unique sample code which linked it to the
facility, the source, and the sample point.
7-21
-------
V. SAMPLE ANALYSIS
Analytical. Summary
Tables 4 through 15 provide the analytical summary reports for the
samples collected during the site visit (see Appendix A). These tables
present the major compounds quantified by GCA/Technology. The actual data
report sheets for the samples are provided in Appendix B.
Analytical procedures were followed as outlined in Appendix D. Aqueous
samples were analyzed for extractable organics, trace metals, oil and grease,
and percent solids. These sections of Appendix D should be referred to for
futher information.
Quality Assurance
Chain of custody and quality control protocols appear in Appendix E.
Surrogate spikes were utilized in conjunction with Texaco samples for volatile
organic and extractable organics; these recoveries are reported in Tables 16
and 17, respectively.
7-22
-------
TABLE 4. LIQUID SAMPLE ANALYSIS FROM EQUALIZATION BASIN NO. 11
AT THE TEXACQ OIL REFINERY IN PORT ARTHUR, TEXAS
a,b
Coapoands Detected Concentration (ug/1)
2-Sutanone (HEX)
Benzene
Toluene
Acetone
Hethylene chloride
Total Xylenes (o,a,p)
Ethylbenzene
Chlorofori
TOTAL HALGEENATED ORSANICS
TOTAL OXYGENATED ORSANICS
TOTAL AROHATICS
TOTAL UNIDENTIFIED ORSANICS
TOTAL NHHC
6700
5400
4250
1200
1100
900
550
250
1350
7900
11100
34502
54352
a
Analysis of saaple 42663 by SCA Corporation using GC/HS.
b
ug/1 = ppb assuming a density of 1.
7-23
-------
TABLE 5. LIQUID SAMPLE ANALYSIS FROM THE WEST DITCH API SEPARATOR
AT THE TEXACO OIL REFINERY IN PORT ARTHUR, TEXAS
Coapounds Detected
Benzene
Acetone
Chlorofon
Hethylene chloride
Toluene
TOTAL HALQSENATED OR6AHICS
TOTAL OJY6ENATED ORB ASICS
TOTAL AROHATIC3
TOTAL UNIDENTIFIED ORSANIC3
TOTAL NHHC
a,b
Concentration (ug/U
12000
12000
3000
3000
3000
6000
12000
15000
319493
332483
Analysis of saaple 42667 by ECA Corporation using SC/HS.
ug/1 - ppb assuiing a density of 1.
b
7-24
-------
TABLE i. LIQUID SAHPLE ANALYSIS PROS THE INLET OF THE HEST DITCH API
SEPARATO AT THE TEXACO OIL REFINERY IN PORTRTWIR, TEXAS
a
Compounds Detected
Ethylbenzene
Benzene
Total Xylenes
Toluene
TOTAL HALOGENATED QRGANICS
TOTAL AROHATICS
isssssssssss=s3s=ssssssssssrsassjsssssssssssssss
b,c
Concantration (ug/1)
B20000
740000
480000
240000
d
210000
d
140000
b
PE3 dispersion of an oily waste saaple
Analysis of saaple 42671 by ECA Corporation using 6C/HS.
c
ug/1 = ppb assuming a density of 1.
d
Analysis of saaple 42671 by SCA Corporation using SC/FIO.
7-25
-------
TABLE 7. LIQUID SAMPLE ANALYSIS FROM THE INLET OF THE SEST DITCH API
SEPARATOR AT THE TEXACO OIL REFINERY IN PORT ARTHUR, TEIAS
Coapounds Detected Concentration (ug/U
Benzene 123
Toluene 35
Acetone 12
TOTAL HALQ6EHATEB OR6ANICS &
TOTAL OXY6ENATED ORSANICS 12
TOTAL AROHATICS 163
TOTAL UNIDENTIFIED OREANICS 157
TOTAL NflHC 338
a
Analysis oi saiple 42672 by 6CA Corporation using 6C/MS.
b
ug/1 - ppb assuring a density of 1.
7-26
-------
TABLE 8. LIQUID SAMPLE ANALYSIS FROM THE DRAINAGE DITCH AT
THE TEIACO OIL REFINERY IN PORT ARTHUR, TEXAS
Coipounds Detected
Chlorofori
toluene
Acetone
Hethylene chloride
Concentration (ug/1)
a,b
700000
48000
30000
10000
TOTAL HALOGENATED OR6ANICS
TOTAL OXYGENATED QR6ANICS
TOTAL AROHATICS
TOTAL UNIDENTIFIED ORSANICS
TOTAL NHHC
710000
30000
48000
584378
1342378
Analysis of saaple 42683 by GCA Corporation using GC/HS.
b
ug/1 = ppb assuaing a density of 1.
7-27
-------
TA3LE 9. LISUID SAMPLE ANALYSIS FRGH THE 3VPS API SEPARATOR
AT THE TEXACO OIL REFINERY IN PORT ARTHUR.TEIAS
Coapounds Detected Concentration lug/1)
2-Butanone (HEKI 17700
Toluene 7600
Benzene 3400
Acetone 1600
Total lylenes (o.i,p) 900
Kethylene chloride 800
Ethyibenzene 400
TOTAL HAL06ENATED ORSAMICS BOO
TOTAL OXYGENATED QRSANICS 19300
TOTAL AROKATICS 12300
TOTAL UNIDENTIFIED ORSANIC3 10995
TOTAL »»HC 43395
a
Analysis of saaple 42687 by SCA Corporation using BC/WS.
ug/1 = ppb assuiing a density of 1.
7-28
-------
TABLE 10. LIQUID SAMPLE ANALYSIS OF ACTIVATED SLUDGE HASTE FROM A CLOSED
HOLDIN8 TANK AT THE TEIACO OIL REFINERY III PORT ARTHUR, TEIAS
a,b
Compounds Detected Concentration (ug/1)
Methylene chloride 380
Acetone 94
TOTAL UNIDENTIFIED ORSANICS 8801C
TOTAL NHHC 880!
a
Analysis of saiple 42675 by 6CA Corporation using Finn HAT OVA,
b
ug/I * ppb assming a density of 1.
c
Analysis of saaple 42675 by 6CA Corporation using SC/FID.
7-29
-------
TABLE 11. LIQUID SAMPLE ANALYSIS FROM CLARIFIES C AT THE
TEXACO OIL REFINEHY IN PORT ARTHUR, TEXAS
a,b
Coapounds Detected Concentration tog/1)
Chlorofori 5.7
a
Analysis of saaple 42680 by 6CA Corporation using Finn HAT DMA.
b
ug/1 * ppb assuaing a density of 1.
7--30
-------
TABLE 12. ICAP ANALYSIS FOR METALS IN SLUDGE FROM LANDFARH AREA NO. 7
AT THE TEXACO OIL REFINERY IN PORT ARTHUR, TEIAS
a,b
Elesent Concentration (ug/g)
Alusinua
Antiiony
Arsenic
Bariui
Beryl liua
Boron
Cadiiui
Calciui
Chroaiua
Cobalt
Capper
Iron
Lead
Hagnesiua
Manganese
Kolybdenut
Nickel
Seleniui
Silicon
Silver
Sod i in
Strontiua
Thalliua
Tin
Titaniua
Vanadiua
Zinc
c
6100
c
<3.0
26
183
6.19
3.4
1.38
97900
109
68.4
1950
31500
1300
9700
340
<0.4
213
c
17
100
0.739
c
310
129
c
<3.0
28
79.7
18
1030
1
Analysis of saaple 42689 by SCA Corporation using ICAP.
b
ug/g * aicrograas per graa.
c
These values should be considered seal-quantitative due to severe
aatrix interferences encountered during the analysis.
7-31
-------
TABLE 13. ICAP ANALYSIS FOR PETALS IN SOIL CORE FROM LANDFAHH AREA N0.3A
AT THE TEXACO OIL REFINERY IN PORT ARTHUR, TEIAS
J,b
Element Concentration (ug/g)
Aluiinni
Antisony
Arsenic
Barim
Beryl HUB
Boron
Cadaiut
Calciui
Chroaiua
Cobalt
Copper
Iron
Lead
flagnesiui
Manganese
Bolybdeniu
Nickel
Seleniai
Silicon
Silver
Sodiut
Strontiua
Thillim
Tin
Titaniui
Vanadiu
Zinc
c
11000
c
<3.0
28
92.9
7.09
8.S9
0.599
13000
171
13.3
454
33300
1200
3400
237
16.7
33.8
c
7
443
<0.6
c
630
108
c
<3.0
13.5
13.8
26
1360
a
Analysis of ssiple 42691 by BCA Corporation using ICAP.
b
ug/g = licrograas per grai.
c
These values should be considered seii-quantitative due to severe
•atrix interferences encountered during the analysis.
7-32
-------
TABLE 14. ICAP ANALYSIS FOR METALS IN SOIL CORE FRO* LANDFARH AREA NO. SB
ATJHE TE1ACO_OIL_REFINERY IN PORT ARTHUR, TEXAS
a,b
Eleaent Concentration (ug/g)
Aluainua
Antiiony
Arsenic
Bariua
Berylliua
Boron
Cadaiua
Calciua
Chroaiua
Cobalt
Copper
Iron
Lead
Magnesiua
Manganese
Holybdenua
Nickel
Seleniua
Silicon
Silver
Sod i us
Strontiui
Thalliiu
Tin
Titaniua
Vanadiua
Zinc
c
14000
c
<3.0
24
129
7.15
7.74
0.993
35SOO
324
21.3
912
33600
990
5000
335
30.9
74.8
c
15
271
<0.i
c
950
197
c
<3.0
15.3
53.5
38
2270
a
Analysis of sasple 42&92 by BCA Corporation using ICAP.
b
ug/g = licrograas per grai.
c
These values should be considered seal-quantitative due to severe
•atrix interferences encountered during the analysis.
7-33
-------
TABLE 15. ANALYSIS OF SOLIDS. OIL AND GRKSE. AND MOISTURE
CONTENTS OF SOIL FROM LANDFARMS NO. 7. 3A, AND 38
FROM THE TEXACO OIL REFINERY IN PORT ARTHUR, TEIAS
Coupon ent
Solids
Oil and Grease
Moisture
b
Analysis 1
64.3
4.1
31. &
a
Concentration (I)
c
Analysis 2
63.0
6.0
31.0
d
Analysis 3
64.5
6.9
28.6
a
Analyses perforaed by 6CA Corporation using CRL 444, CRL 44S, and
SH-B46, lethod 9071 analysis procedures.
b
Analysis of saiple 42689, fro§ Landfara No. 7.
c
Analysis of saaple 42691, frot Landfari No. 3a.
d
Analysis of saaple 42692, froi Landfara No. 3b.
7-34
-------
TABLE 16. SURROGATE RECOVERIES - VOLATILE ORGANICS.
TEXACO, PORT ARTHUR, TEXAS.
Percent Recoveries
Sample
Identification
GCA
Control No.
TX-11-1C 42663
TX-API-1C 42667
TX-API-2C 42671
TX-ASW-2C 42675
TX-CLC-1D 42680
TX-DD-1C 42683
TX-V-1C 42687
Method blank 3/4/85
Method blank 3/7/85
Method blank 5/13/85
toluene
99
94
88
96
96
98
99
99
99
96
Bromo-
flugrobenzene
132
104
75
100
107
112
103
96
97
99
D4 - 1,2-
dichlgrgethane
115
56
88
100
99
121
71
128
89
96
Average Percent Recovery
Relative Standard Deviation (%)
96
3
103
14
99
22
7-35
-------
TABLE 17. SURROGATE RECOVERIES - EXTRACTABLE ORGANICS
TEXACO, PORT ARTHUR, TEXAS.
Sample
Identification
TX-3A-1A
TX-313-1A
Method blank
Spiked sample
Duplicate Sample
GCA
Control No.
42691
A2692
QC986
QC987
QC988
D5-
Nitro-
benzene
a
a
131
27
24
2-
Fluoro-
biphenyl
a
a
102
25
23
Percent
DU-
ter-
phenyl
a
a
105
22
18
Recoveries
D5 -
phenol
23
21
0.7
83
73
2-
fluoro-
phenol
24
22
54
82
70
2,4,6-
tribromo-
phenpl
43
39
34
118
102
Average Percent Recovery
Relative Standard
Deviation (%)
61
61
50
45
48
49
40
36
50
27
67
40
acould not be calculated due to a large dilution factor.
7-36
-------
REFERENCES
1. Cantrell, Aileen. Annual Refining Survey* Oil and Gas Journal.
March 21, 1984. pp. 128-153
2. Letter and Attachments from R.L. Korbini, Texaco, Inc. to Ronald C. Sims,
Utah State University. November 16, 1984.
7-37
-------
APPENDIX A
SAMPLE IDENTIFICATION FORMS
A-l
-------
6AMRE INVCNIODY FOR CHEKAll CORPORATION IN PORI HECHES, TEIAS
SUE
Chmll Coiporition
Chdill Cofporillon
Chmll Coiporition
Chmll Corporation
Chmll Corporation
Chmll Cor peril Ion
Chmll Coiporition
Chdill Corporilion
Chmll Corporitioii
Chdill Coiporillon
Chdill Cor per it tot
INK « Not Anilyied
iiVilidil* ol IEA inilym
Id
iiEii!
II0089792S41
U008W2S4J
I10089WSIJ
1ID089I925U
TI008WJS4J
110089)92543
110089)92541
SAKPLE
SOURCE COMMENTS ID 1
louir trtititnt Pond
lOHtr Irntient Pond
loiitr trutient Pond
louir Irtititnt Pond
Uppir Pond
Uppir Pond
Uppir Pond
Uppir Pond
Coipotiti toll Siiplt
Flild (In (link
Flild (ill Hint
MP-II
C'lP-IO
C-UP-IA
C-UP-II
C-UP-IC
C-UP-ID
C-C5-IA
FCBO II 383-0
FBBOIISBI-P
SfiHflE LAB
mi CONIROL 1
Liquid
liquid
Liquid
liquid
Liquid
liquid
SurliCi toll
Liquid
Liquid
42?Bi
427B7
42768
42'89
427(0
4?/9t
42BI2
42441
OAtf SAHPLINO DA1E
SAMPLED CONIRACIOR RECEIVED
01/25/83
01/23/85
01/25/65
01/23/81
01/23/85
01/21/81
01/23/83
01/23/81
OI/23/B3
01/23/81
01/23/81
fiCA
CCA
GCA
BCA
GCA
1CA
GCA
GCA
GCA
GCA
GCA
01/24/63
01/24/85
01/24/83
01/24/85
01/21/81
01/24/83
01/24/83
01/24/83
01/24/81
01/21/81
01/24/63
DAIE ANAUSIS
ANALYIED CONTRACTOR
NA
03/02/85
02/05/B3
03/18/85
KA
01/62/8!
02/03/83
01/18/81
03/14/81
02/03/83
01/18/83
IEA
ICAii
fiCA*"
IEA
lEAu
6CAUI
CCA
fiCA
BCAill
GCA
DAIE
REPORTED
01/28/81
02/19/65
04/24/81
01/28/81
02/19/83
04/24/81
04/20/85
02/19/83
04/17/83
It currtntly btlnij iviluitid
f
-------
SAMPLE INVENTORY FDR CHEMICAL IEANAN IftKK LINES IN PORT MUWIR, 1EME
SUE
Chtiicil LiiMn link linn
Chtiicil Ltiiin Fink Unit
CheiUil Ltiun link Unit
Cheilcil Itiiin Tink linn
Chiiictl Lmin link linis
Chtiicil Lcmn link Unit
Cheiicil Ltiiin link Unit
Chdicil Limn Tinl linn
Cheiicil Ltiiin Tint Unet
Chtiicil Ltiun link Linet
Chtiicil Ltiiin Tint Linn
ChMici) LfJ/iJD Tint- Lines
Chtiicil liuin Tink Linct
FACILI1Y
101
H004746BI2*
110047466127
W047468IW
TID0474t8l2?
IJDOOUBI2?
UD0474iBI2f
1ID0474t8l2f
1ID047UBI2?
T»0474i8l2f
UD0474kBI29
UD0474t8l2f
HD047UBIJ9
TID04746BI2f
SBHPLE
SOURCE COHKEHTS ID 1
Hiilng Tink
III i Ing Unk
Nlilng link
Hliing Tink
DlltllDH Plpl
Out (1 OK Pipi
Outdo* Pipi
Out II on Pipi
Coipotitt Soil
Composite Soil
Coipoiitt Soil
Cotpgfitt Soil
Coipoilti Soil
Suplf
Siipli
Siipli
Suplt
Siipli
IC-NI-IA
LC-NI-IB
U-HI-1C
u-ni-iD
IC-OF-U
IC-OF-IB
LC-OF-IC
U-OF-ID
U-SL-IA
IC-SL-M
LC-SL-I*
LC-SL-IA
U-SL-IB
SBKPLE
TVFE
liquid
liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Surfict toll
Surlici loll
Surliti toll
Sur/itt loll
Surlic* toil
LAB
CONTROL 1
42421
42622
42621
42624
42425
42626
42627
42628
42815
42615
42BIS
42BI5
42816
DATE EAKPLIN6 DATE
SAHRED CONtRACTOR RECEIVED
01/23/83
01/23/85
01/21/83
01/23/83
01/23/83
01/23/83
01/23/83
01/23/85
OI/24/B3
01/24/83
01/24/83
01/24/83
01/24/83
GCA
BCA
CCA
BCA
BCA
BCA
ECA
BCA
BCA
BCA
BCA
BCA
BCA
01/24/83
OI/24/B3
01/24/83
01/24/83
01/24/83
01/24/83
01/24/83
01/24/83
01/26/83
OI/26/B3
01/26/83
01/26/83
01/26/83
DATE ANALYSIS DATE
mitm CONTRACTOR REPORTED
03/04/83
NA
01/28/83
03/06/BS
03/08/83
NA
OI/2B/B3
03/06/BS
03/22/83
04/06/83
04/06/B3
05/14/63
NA
IEAH 03/2B/63
IEA
BCAiii 02/01/83
ECA 03/28/65
IEAH 03/28/85
IEAH
GCAin 02/01/63
ECA 03/26/65
GCA 03/26/83
ECA 06/20/85
GCA 06/20/85
ECA 04/20/65
GCA
iNA > Not Anilyjed
itVilidity ol IEA inilyttt ii currently undir iviluition.
GC/FID screening jhoned no dittctibU coipoundi| thui, no furthtr 6C/NS teitlnj MI perforud.
U)
-------
SAHPU INVENIOR* FDR BULK OIL COMPANY III PORT AfilHUfl, IEIAS
SITE
Gulf Oil Refinery
Gulf Oil Refinery
Gulf Oil hrlinery
Gulf Oil Refinery
Gulf Oil Refinery
Gulf Oil Refinery
Gulf Oil Refinery
Gulf Oil Refinery
Gulf Oil Refinery
Gulf Oil Refinery
Gulf Oil Refinery
Gulf 01) Refinery
Gulf Oil Refinery
Gulf Oil Refinery
Gull Oil Refinery
Gulf Oil Refinery
Gulf Oil Refinery
Gulf Oil Refinery
Gulf Oil Refinery
Gulf Oil Refinery
Gulf Oi) Refinery
Gulf Oil Refinery
Gulf Oil Refinery
Gulf Oil Refinery
Gulf Oil Refinery
Gulf Oil Refinery
Gulf Oil Winery
Gulf Oil Refinery
Gulf Oil Refinery
Gulf Oil Refinery
Gulf Oil Refinery
Gulf Oil Refinery
to Gulf Oil Refinery
I Gulf Oil Refinery
*• Gulf Oil Refinery
Gulf Oi) Refinery
Gulf Gil Refinery
Gulf Oil Refinery
INS > Not Anil y ltd
MVilUity of IEA
titlnUul EC/FID
FACILITY
101
TI0008090409
IIDOOB090409
7JDOOB090409
710008090409
T1DOOB090409
11000B090409
TI000B090409
T1000B090409
T1000B090409
IID008070409
TI000B090409
T1DOOB090409
TIOOOB090409
1I000B090409
TID008090409
710008090409
T1DOOB090409
710008090409
TID00B090409
710008090409
7I0008090409
710008090409
110008090(09
TIOOOB090409
TIDOOB090409
TID008090409
TID008090409
T1D008090409
110008090409
IID00B090409
710008090409
T1D008090409
TID00B090409
I 10008090409
UOOOB090409
TIDOOB090409
110008090409
110008090409
SOURCE
Flnil CUrifler
Flnil Clarifier
Flnil CUrifler
Finil CUrifler
DAF CUrlflir
DAF CUrilier
DAF CUrifler
DAF CUrifler
DAF Clirifitr
DAF CUrifitr
DAF CUrifler
DAF CUrifler
Oiiditlon Pond
Oil lilt ion Pond
Oiiditlon Poni
Oiiditiofl Pond
Diidition Pond
Oiiditlon Pond
Oiiditlon Pond
Oiidition Pond
Stor* Biiln 12
Stor* Biiln 12
Stor* Biiln 12
Stor* Biiin 12
Stor* Biiln 12
Pond 17
Pond 17
Pond 17
Pond 17
Undflll
Liftdlill
Lindflll
Lindflll
lindfill
Lindflll
lindfill
Field Bin Blink
Field (In Hint
COMMENTS
Effluent
Effluent
Effluent
Effluent
Influent Suffice
Influent Surfut
Influent Surfici
Influent Eurfici
Effluent
iff uenl
Effluent
Effluent
Influent
Influent
Influent
Influent
Influent
Influent
Influent
Influent
SAHPLE
IDI
60-CL-IA
GO-Cl-IB
GO-CL-IC
GO-Cl-ID
60-DAE-IA
6D-DAE-1I
GO-DAE-IC
GO-DAE-ID
60-DAHA
GO-DAI-U
GD-DA1-1C
BO-DAHO
BO-OJE-IA
GO-OIE-IB
GO-D1E-IC
ED-OIE-ID
GO-OII-IA
GO-OII-II
BO-OU-IC
GO-OM-IO
GQ-SB-IA
GO-EB-IB
GO-SB-IC
GO-SB-ID
GO-EB-IB
GO-SO- 1 A
ED-SD-ll
GO-SO-IC
60-SO-ll
EO-CO-IA
60-CO-IA
GO-CO- IA
60-CO-IA
GO-CO-IB
GO-SL-IA
BO-SL-IB
F6BOII5B5-E
FBBOII5B5-F
SAMPLE LAB
TYPE CONTROL 1
liquid
Liquid
liquid
Liquid
liquid
liquid
LUuld
liquid
liquid
liquid
Liquid
Liquid
liquid
Liquid
liquid
liquid
liquid
liquid
liquid
liquid
Liquid
Liquid
liquid
liquid
Liquid
liquid
Liquid
Soil cori
Soil con
Soil core
Soil cori
Soil cor*
Surfici toil
Suffice toll
Liquid
Liquid
42751
42/57
42758
42759
42710
42711
42712
42713
42714
42715
42711
42717
42748
m
42771
42772
42773
42774
42775
42771
42777
42778
42779-A
42779-B
42780
427BI
427B2
427B3
42808
42808
42808
42BOB
42809
42BI3
42B14
42830
42B3I
DATE SAMPLING DATE
EANPLED CONTRACTOR RECEIVED
01/24/85
0/24/63
01/24/65
01/24/85
01/24/85
01/24/85
01/24/85
01/24/85
OI/24/B5
01/24/85
01/24/85
01/24/85
0I/24/B5
0/24/85
01/24/85
01/24/85
01/24/85
DI/24/BS
01/24/85
01/24/85
01/24/85
01/24/85
01/24/85
OI/24/B5
01/24/85
01/24/85
01/24/85
01/24/85
01/24/85
01/24/85
OI/24/B5
OI/24/B5
OI/24/B5
01/24/85
OI/24/B5
OI/24/B5
01/24/85
OI/24/B5
ECA
GCA
GCA
GCA
GCA
GCA
GCA
GCA
GCA
GCA
ECA
GCA
ECA
ECA
BCA
ECA
GCA
ECA
GCA
GCA
ECA
ECA
ECA
BCA
BCA
BCA
GCA
ECA
GCA
GCA
GCA
GCA
GCA
GCA
ECA
BCA
01/21/85
0I/21/B5
01/24/85
01/21/85
01/21/85
OI/21/B5
01/21/85
01/21/85
01/21/85
01/24/85
01/21/85
01/21/85
01/21/85
0/24/63
01/21/85
01/21/85
01/21/85
01/21/85
01/21/85
01/24/63
01/24/83
01/21/65
01/24/63
01/21/85
01/24/83
01/24/65
01/24/63
01/24/85
01/21/85
01/21/85
01/21/83
01/21/85
01/21/85
01/24/65
01/21/85
01/24/85
01/24/65
01/21/85
DATE ANALYSIS DATE
ANALt7ED CONTRACIDR REPORTED
03/03/35
NA
NA
03/IB/B5
03/04/B5
HA
02/OI/B5
05/20/B5
NA
03/03/35
03/04/85
NA
NA
mm
03/18/85
NA
03/04/85
03/04/B5
NA
NA
03/02/B5
02/04/85
03/IB/B5
03/18/85
03/03/35
NA
03/04/B5
NA
03/28/83
04/01/85
04/01/85
02/27/85
NA
03/28/85
NA
02/05/85
03/18/85
lEAn 05/26/65
IEA
IEA
GCA 04/24/85
lEAU 03/28/63
IEA
GCAiii 02/19/85
GCA 01/20/B5
IEA
IEAH 03/2B/B5
ECA 04/24/B5
GCA
IEA
lEAn 03/28/85
GCAHi 02/19/85
GCA 04/24/85
IEA
IEAH 03/28/85
GCA 04/24/85
GCA
IEA
lEAn 03/28/85
ECAlii 02/19/85
ECA 04/24/85
KA 04/24/85
lEAU 03/28/85
IEA
BCA 04/24/85
ECA
ECA 04/17/65
GCA 01/20/B5
GCA 01/20/85
ECA 03/04/83
RAD
GCA 04/17/63
GCA
GCAiii 02/19/85
ECA 04/17/85
inilytet it currently being eviluited
ureening (honed no detectiblt coipoundi|
thut, no further 6C/NS tettlng
mi perfoned
-------
SAMPLE 1NVENIORV FDR LOUER HECHES VALLEY MITHOR11Y IN BEBUXOH1,
SITE
loner Nechei
Lover Nechti
Loner Ncchu
loner Nechei
loner Nccliti
Loner Ntchti
Loner Ntchei
Loner Nechei
Loner Nichet
Loner Nechei
Loner Nechei
Loner Nechei
Loner Nechei
Loner Nechei
Loner Nechei
Loiter Nechei
Loner Hechei
Loner Nechei
Loner Nechei
Loner Nechtt
;> Loner Nechei
1 Loner Heches
"* Loner Nechei
Loner Nechei
Loner Nechti
Loner Neches
Loner Nechei
Loner Nechei
Villey Auth.
Villey Auth.
Villey Auth.
Villty Auth.
Villty Auth.
Villey Auth.
Villty Auth.
Villey Auth.
Villey Auth.
Villey Auth.
Villey Auth.
Villey Auth.
Villey Auth.
Villty Auth.
Villiy Auth.
Villey Auth.
Villey Auth.
Villey Auth.
Villey Auth.
Villey Auth.
Villey Auth.
Villey Auth.
Villey Auth.
Villty Auth.
Villey Auth.
Villey Auth.
Villey Auth.
Villey Auth.
SOURCE
Atritor Outlill
Aeritor Outlill
Aeritor Outlill
Aeritor Outlill
Orginlc Aui-Ligooi
Orginlc Aui-ligoon
Organic Aui-Ligoon
Orginlc Aut-Ligooi
CUrlfltr 2
CUrilltr 2
Clirllier 2
Clirilier 2
Dlipoul Bludgt
Diipotil Sludgt
Dlipoul Sludgt
Ditpoiil Sludge
Equiliiition link
Equilliition link
Equiliiition link
Equjliiition link
Equiliiition link
Equilliition link
Equiliiition link
Equiliiitloft Tank
Equilliitio* link
Equilliitloi Tink
Equiliution link
Equiliiition link
COMMENTS
Influent
Influent
Influent
Influent
Oil Slick
Oil Slick
Oil Slick
Oil Slick
Cleir Art!
Cleir Arti
Cleir Am
Cleir Am
SAMPLE
ID 1
LNVA-AL-1A
INVA-AL-II
LNVA-AL-IC
LNVA-AL-ID
LNVA-AIHA
LNVA- AD-IB
LNVA-AU-IC
INVA-AIMD
LNVA-CL-IA
INVA-Cl-IB
LNVA-CL-IC
LNVA-CL-ID
LNVA-SL-IA
LNVA-SL-II
LNVA-SL-IC
LNVA-SL-ID
LNVA-EO-IA
INVA-EB-II
LNVA-EO-IC
LNVA-ED-IO
LNVA-EB-IF
LNVA-EO-16
LNVA-EO-IH
LNVA-EO-U
LNVA-EO-IK
LNVA-EQ-IL
LNVA-EB-IH
LNVA-ED-IN
SAMPLE
TYPE
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
LAB
CONTROL 1
42427
42430
42431
42112
42433
42434
42433
42434
42437
42438
424M
42440
4244!
42444
4244S
42444
42441
42410
42451
42452
42453
42454
4245S
42454
42437
42438
4245?
42440
DATE BAHPL1N8 DATE
SAMPLED CONTRACTOR RECEIVED
OI/24/B5
01/24/83
01/24/85
01/24/83
01/24/85
01/24/83
01/24/83
01/24/83
01/24/83
01/24/83
01/24/83
01/24/85
01/24/83
01/24/85
01/24/85
01/24/85
01/24/85
01/24/85
01/24/85
01/24/85
01/24/83
01/24/85
01/24/85
01/24/85
OI/24/B3
01/24/85
01/24/85
01/24/85
6CA
ECA
ECA
ECA
ECA
BCA
ECA
ECA
BCA
ECA
BCA
ECA
BCA
ECA
BCA
BCA
BCA
ECA
ECA
ECA
BCA
ECA
ECA
BCA
ECA
BCA
ECA
ECA
01/24/83
01/24/83
01/24/85
01/24/83
01/24/83
01/24/85
01/24/85
01/24/85
01/24/83
01/24/85
01/24/83
01/24/83
01/24/83
01/24/85
01/24/85
01/24/95
Ot/24/85
01/24/83
OI/24/B5
01/24/85
01/24/65
01/24/85
01/24/85
01/24/85
01/24/85
01/24/83
01/24/85
01/24/85
DATE ANALYSIS DATE
ANALYIED CONTRACTOR REPORTED
01/04/83
HA
01/28/83
01/07/85
03/04/85
03/02/85
01/28/85
03/08/85
NA
03/03/35
OI/2B/B5
03/08/85
03/04/83
NA
01/28/85
03/04/85
03/02/83
NA
03/04/83
03/03/85
03/04/85
03/04/85
NA
03/04/85
03/03/85
NA
03/04/85
NA
lEAn 03/2B/B5
1EA
ECAiM 02/01/85
BCA 04/03/85
1EAM 03/28/85
lEAii 03/28/85
BCAiii 02/01/83
BCA 04/03/85
IEA
lEAii 03/28/85
fiCAin 02/01/83
BCA 04/03/83
lEAii 03/28/85
IEA
GCAni 02/01/85
BCA 04/03/83
IEA" 03/28/85
IEA
ECA 04/24/85
lEAii 03/28/85
1EAH 03/28/85
BCA 04/24/85
BCA
IEA" 03/28/85
IEA" 03/28/85
IEA
ECA 04/24/85
BCA
iNA * Not Analyzed
"Validity ol IEA intlyiei It currently btlng tviluittd
iiilnitiil EC/FID ureeninj ihoned no dttictibli cotpoundi) thut, no further EC/MS testing nil perlornd.
-------
SAHPLE INVtNIORV FOR NOIIL OIL CONTAIN IN ICAUNONI, IC1AS
SUE
Hobil Oil Refinery
Hobll Oil Refinery
Hobil Oil Refinery
Hobll Oil Refinery
Hobil Oil Refinery
Hobll Oil Refinery
Hobll Oil Refinery
Hobil Oil Refinery
Hobll Oil Refinery
Hobil Oil Refinery
Hobll Oil Refinery
Kobll Oil Refinery
Hobil Oil Refinery
Hobil Oil Refinery
Hobll Oil Refinery
Hobil Oil Refinery
Hdbil Oil Refinery
Hobil Oil Refinery
Hobil Oil Refinery
Hobil Oil Refinery
Hobll Oil Refinery
Hobil Oil Refinery
Hobil Oil Refinery
.p. Hobil Oil Refinery
1 Until Oil Refinery
°" Robil Oil Refinery
Hobll Oil Refinery
Hobi! Oil Refinery
Hobil Oil Refinery
Hobil Oil Refinery
Hobil Oil Reflury
Hobil Oil Refinery
Hobil Oil Refinery
Hobil Oil Refinery
Hobll Oil Refinery
Hobil Oil Refinery
Hobil Oil Refinery
Hobil Oil Refinery
Hobil Oil Refinery
Hobll Oil Refinery
Hobll Oil Refinery
Hobil Oil liiflnery
Hobil Oil Refinery
Hobil Oil Refinery
Hobil Oil Rtfinery
Habll Oil Refinery
Hobll Oil Refinery
Hobil Oil Refinery
FACIL11V
IDI
110990797714
110990797714
HD990717714
II09907177I4
uow7977n
1ID9907177I4
U09907977I4
1ID9907977H
1H9907977I4
U09107977I4
IID9907977I4
U09907977I4
IID9107177H
1ID9107177I4
UD9907977I4
IID9907177I4
IID9907977I4
IID99A7H7H
1109907*7714
IID9907177I4
110990797714
110990797714
110990797714
110990797714
1109*0717714
110990717.714
UD990717714
UD9107177I4
II09907977M
UD9907977M
1109)0717711
IID9907977I4
II09907977M
IID9907177I4
1109907*7711
W9907977I4
110990797714
IID9907977I4
1ID9907977I4
II09907977I4
110990797714
1109907*7714
1109907*7714
1IOW7977I4
IH9907977I4
1109907977)4
110990797714
111)990797714
SAME SAME LAI
SOURCE CONHEN1S ID 1 UPE COH1RW. 1
API Sepintor
API Sepiritor
API Sepiritar
API Sipirilor
API Septritor
API lepiritor
API Bepiutor
API Eepiritor
API Septritor
kit Priu feed
lilt Prut Fud
lilt Priu Fied
lilt Priu Feed
IAF EMIuent
DAF Effluent
DAF Effluent
DAF Effluent
DAF Effluent
Prlury l4iln
Prlury liiln
Prlury liiln
Pritiry Biiln
Secondary liiln
Eicondiry liiln
Sicandiry lain
Secondtry Buln
Upper lindflll
Upper Undlill
Upper Lindfill
Uppir Undflll
Upper Undllll
lindfill/ Undliri
Undfill/ UndUri
Undllll/ Undliri
Undllll/ Undfiri
Undflll/UndUrt
Undflll/ Undliri
Souln Plint Undfir*
South Flint Lindfirt
Soutk Plint UndUri
South Plint Undliri
South Plint Undfiri
South Plint lindfirn
Upper Undltll
Upper lindflll
Upper Undllll
Field 11 it Ilinli
Field liii Ilink
H-API-IA
H-API-II
H-API-IC
H-API-IC
H-dPI-ID
H-API-7*
K-API-21
R-BPI-JC
H-API-Jt
H-BPF-IA
N-IPf-ll
H-IPF-IC
H-IPF-ID
H-DAF-U
H-DAF-H •
H-DAf-lC
H-DAF-IC
N-OAF-II
H-PI-IA
H-PI-II
H-PI-IC
H-PI-II
H-SB-IA
H-SB-II
H-SB-IC
H-EB-IO
H-IH.-2A
H-UL-3A
H-UL-3A
N-UL-1A
H-W.-IA
H-U-ln
M-ll-U
H-IL-U
H-IL-U
H-ll-U
H-U-IB
JI-SL-U
H-6L-IA
H-SL-IA
ll-8t-U
H-SL-IA
H-SL-II
M-W.-IA
H-W.-M
H-UL-II
liquid
Liquid
liquid
Liquid
Liquid
Liquid
Liquid
Liquid
liquid
Liquid
liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
liquid
Liquid
liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Surfiti tell
Surlici loll
Surlice Soil
Surface Sell
Suffice Soil
Soil tori
Soil cori
loll tori
Soil con
Soli cori
loll ciri
Soil cart
Soil cori
Soil con
Soil con
Soil cori
Soil cori
Soil con
Soil cori
Soil con
FBBOII5B5-I Liquid
FBBOII5B3-J Liquid
42U4
42195
42494
4?m
42497
42491
42499
42700
42701
42702
42701
42704
42703
42704
42707
42708
42708
42701
42710
42711
42712
4271)
42714
427IS
42714
42717
42718
42719
42711
42711
4271*
42720
42720
42720
42720
42720
42721'
42722
42722
42722
42722
42722
42721
42724
42724
42723
42434
424)3
OA1E SAMPLING
SAHPLEI CONIRAUOR
OI/24/S3
01/24/83
01/24/13
01/24/83
01/24/83
01/24/13
01/24/13
01/24/13
01/24/13
01/24/83
01/24/83
01/24/83
01/24/83
01/24/83
01/24/83
01/24/83
01/24/83
01/24/83
01/24/83
01/24/85
01/24/83
01/24/85
01/24/83
01/24/15
01/24/83
01/24/85
01/24/85
01/24/85
01/24/85
01/24/85
01/24/15
01/24/15
01/24/15
01/24/15
01/24/85
01/24/15
01/24/85
01/24/85
01/24/85
01/24/83
01/24/85
01/24/85
01/24/85
01/24/89
01/24/85
01/24/85
01/24/85
01/24/85
6CA
SCA
BCA
6CA
GCA
SCA
OCA
OCA
ECA
SCA
CCA
GCA
ECA
ECA
GCA
ECA
ECA
ECA
ECA
ECA
ECA
GCA
ECA
GCA
GCA
GCA
ECA
ECA
GCA
ECA
GCA
ECA
GCA
GCA
GCA
BCA
ECA
ECA
GCA
ECA
GCA
GCA
GCA
GCA
GCA
GCA
GCA
GCA
OA1E
RECEIVE!
01/23/83
01/23/85
01/23/83
01/23/83
01/23/83
01/23/83
01/23/83
01/23/85
01/23/83
01/23/85
01/25/85
01/23/15
01/23/85
01/23/83
01/23/83
01/23/83
01/23/83
01/23/85
01/23/15
01/23/85
01/23/83
01/23/85
01/23/83
01/23/15
01/25/13
01/23/83
01/23/83
01/23/85
01/23/15
01/25/85
01/23/83
01/23/83
01/25/83
01/23/85
01/23/83
01/23/85
01/23/83
01/23/85
01/23/13
01/23/83
01/23/83
01/23/85
01/23/13
01/25/83
01/23/15
01/25/15
01/23/85
01/25/83
DAIE ANALYSIS
ANALtlEO CONIRAC10R
01/04/83
NA
03/04/85
01/21/85
NA
01/04/85
NA
03/04/85
NA
01/04/85
NA
NA
02/15/83
01/04/85
NA
01/04/I3
01/21/85
NA
01/01/15
NA
01/04/85
NA
01/04/85
NA
01/04/83
NA
01/11/83
01/19/85
09/14/85
04/04/83
04/04/85
01/20/85
01/20/15
01/20/15
04/17/85
02/20/85
NA
01/20/85
01/20/85
03/20/85
04/17/85
02/20/85
NA
03/22/85
02/20/85
NA
02/03/85
01/18/85
1EAH
IEA
GCA
SCA
CCA
IEAH
IEA
GCA
GCA
IEAU
IEA
GCA
GCA
IEAU
IEA
GCA
GCA
SCA
IEAU
1EA
GCA
GCA
IEAU
IEA
GCA
GCA
GCA
GCA
GCA
GCA
GCA
GCA
GCA
GCA
ECA
SCA
RAD
ECA
GCA
ECA
GCA
GCA
RAD
CCA
GCA
RAO
DAIE
REPOAIED
01/28/83
04/24/83
04/24/83
01/28/83
04/24/83
01/28/83
01/28/83
01/28/85
04/24/83
04/24/83
01/28/83
04/24/83
01/28/83
04/24/85
01/28/83
01/28/85
04/20/13
04/20/83
04/20/85
01/28/85
04/20/85
04/20/85
04/20/15
02/27/83
01/28/15
04/20/13
04/20/85
04/20/85
02/27/83
03/2B/B5
02/27/15
GCAiii 02/19/13
GCA
04/24/85
•NA > Wol Antlyied
•iV«\i4tly of Uft inilytes it currently being ivtlutted.
• iilnititl BC/flD icrceninq thawed no dtltctabl* compounds?,
thus, no further fiC/MS listing M«* perfumed.
-------
SAMPLE INVENTORY FOR NECIIES BUTANE IN PORT HECHES, UIAS
SHE
Mechtt flulini
Htchei Butjfit
HrchH Mint
llechu flulinf
Nrchts Bulint
Nichti BuUne
Nrchts Butiitt
Niches Butint
Ntchu Eliitlni
Nectut BuUni
Kichu Butini
Niches Butini
Nichts BuUni
Nfthts fmUni
Ntchis Butirii
Ntclirt Butini
Hichis Bulint
Nichii {ulint
Nichis Mint
Nithii lulmt
Nichti Butint
Ntchts B'jtint
Nichii BuUni
Nechtt (utini
Nichil tutini
SOURCE
Pint Elllutnt
Plat Elllu.nt
Flint Ellluiiit
Flint Elllurnt
CUtllltr
Clirllitr
Clirtlitr
Cliriliir
Equillutlon lulu
Equililitlmi lull
(quilidtioii tni»
Eouiliiilion till*
FolliMnt Pond
Pollthini Fond
PulUMnj Pond
Follihlng Fond
lindliri
lindlirt
lindliri
lindliil
lindliri
linitlirl
linMin
lindliri
lindltri
SAhPIE 8AHPIE
COHKCNTS ID 1 TVFE
Ellluint
Efllutnt
Effluent
Ellluint
Inlluinl
illuent
Inllutnt
tnlluint
NI-CE-I*
N6-CMI
NB-CE-IC
NB-CE-ID
NB-Cl-IA
NB-Cl-ll
NB-CL-IC
NB-Ct-ID
NB-EO-lR
NB-EO-IB
Nt-CO-IC
NB-EB-ID
NB-FF-U
NO-IP-li
N6-IP-lt
HB-FF-ID
NB-CO-IA
NB-CO-H
NB-CO-U
NI-CO-U
HB-CO-I*
NB-CO-IA
H6-CQ-U
NB-CO-IA
NB-CO-II
LlquU
liquid
Liquid
liquid
liquid
liquid
liquid
liquid
liquid
Liquid
liquid
liquid
liquid
ti'qulJ
Llauid
Soil cort
Boll tort
Soli cort
loll (on
Soil can
Soil cort
Soil cart
Soil con
Soil cort
IAD
CON1RH 1
nin
nm
urn
Kin
43/94
42m
4?m
42799
42600
42801
42807
42BOI
42B04
J2B01
42007
42810
42810
42810
42BIO
4JBIO
42BIO
42010
42810
42811
OA1E SWUNG DAIE
SAWIED COIUIIACIOIt RECEIVED
OI/J3/B5
OI/23/8S
01/23/85
OI/2S/B5
01/23/85
OI/25/B5
01/23/83
01/25/8}
01/25/65
01/25/85
01/25/85
01/25/81
01/25/BS
01/25/85
01/25/85
01/25/85
01/25/85
01/25/85
01/25/85
OI/2S/B5
01/25/85
OI/25/B5
01/23/85
OI/2S/B5
01/23/85
GCA
GCA
GCA
BCA
GCA
ECA
GCA
CCA
ECA
CCA
GCA
CCA
GCA
^
GCA
CCA
GCA
CCA
CCA
GCA
GCA
ECA
GCA
GCA
dim/85
01/24/85
01/24/85
OI/24/B5
OI/24/B5
01/24/85
01/24/83
01/21/83
01/24/83
OI/24/B5
01/21/83
01/24/85
01/26/83
^,m
01/24/83
01/24/85
OI/24/B5
01/21/85
01/24/85
01/21/83
01/21/83
01/21/63
01/21/83
01/21/83
DAIE ANALYSIS
ANAU1ED CONlfcACIDR
03/04/83
lift
02/03/83
OJ/20/B3
NA
01/02/85
03/04/85
NA
03/04/65
03/OJ/H
01/04/83
NA
03/02/83
NA
02/05/83
03/20/B5
03/20/BS
02/27/85
04/17/83
03/20/83
04/06/83
04/04/85
03/14/65
04/08/65
NA
lEfin
IEA
GCAin
GCA
IEA
IEAH
CCA
GCA
Itfin
IEAH
GCA
GCA
IEAH
cc!..,
GCA
CCA
GCA
GCA
GCA
GCA
GCA
GCA
CCA
RAD
DAIE
BEPORIEO
03/28/13
02/11/85
04/24/85
03/2B/B3
04/24/85
03/28/83
03/26/65
04/21/85
03/28/85
07/11/63
04/24/63
03/28/83
03/04/85
01/20/85
03/2B/B5
01/20/65
01/20/85
01/20/85
04/24/85
• Not Anilyiid
s» IEA jajlyiti It currtntlir t»ln« mluattd
EC/flD scriinin) should no dttictiblt
thai, no lurthir EC/MS tilting mi pirfornd.
-------
SAHPIE INVENIORY FOR TEIACO OIL REFINERY IH PORT ARTHUR, TEIAS
oo
SUE
Tiuco Oil Relinery
liuto Oil Rillntry
Tiuco Oil Reltnery
Iiiico Oil Relinery
Teuco Oil Rillntry
lento Oil Refinery
Tiuco Oil Refinery
Imco Oil Rtflnery
Tiuco Oil Refinery
Icuco Oil Rtfintry
liuco Oil Relinery
lento Oil Refinery
Imco Oil Rtfinery
Ituco Oil Rellniry
Imco Oil Refinery
lento Oil Refinery
lento Oil Refinery
Teuco Oil Relinery
lento Oil Refinery
Tiuco Oil Rilinery
Tiuco Oil Relinery
Teuco Oil Relinery
lento Oil Relinery
Ttuco Oil dell nery
lento Oil Relinery
Tiuco Oil Rilinery
Tiuco Oil Riliniry
Tiuco Oil Rifincry
Tiuco Oil fit finery
Tiuco Oil Riliniry
Tiuco Oil Relinery
Ttuco Oil Rilinery
Tiuco Oil Refinery
Tiuco Oil Relinery
lento Oil Riliniry
Tiuco Oil Riflfiiry
Tiucojil Reltnery
Teuco Oil Refinery
Ituco Oil Refiniry
Tiuco Oil Riliniry
leuco Oil Rilinery
Teuco Oil Refinery
Teuco Oil Rilinery
lemo Otl Rilinery
leuco Oil Relinery
leuco Oil Relinery
lento Oil Refinery
iNft * Mel Dnilyied
••Validity cf IEA analyst*
FACILITY
IDI
uoooflo?7S2?
IIDOOBOW2?
U000809752t
TID00809752?
U06(iflO?752?
HD008097S2?
I1000B09732?
MOOOBO?7S2?
TID0080?732»
TIOOOBOra?
IIOOOB09732?
IIDOOB097529
II0008097529
1ID008097529
IIOOOB097S29
11000609752?
11D008097529
MDOOB097529
I1DOOB097329
TID008097529
1II)00809752»
1ID008097529
llD00809752f
IID008097529
110008097529
110008097529
IIOOOB097529
11D008097529
1IOOOB097529
T1000B097529
11 0008097529
110008097529
11000B097529
1IOOOB097529
1UOOB097529
TIOftOB09752?
UOOOB097SM
I1000B097329
110006097329
TIOOOB097329
110008097329
110008097329
1ID008097529
110008097529
110008097529
1 10006097529
110008097529
tOURCC
EquilliatlM liil* III
Equaliiatlo* Bail* III
EqullUttlOft l
-------
APPENDIX B
GCA DATA REPORT FORMS
B-l
-------
Project 1-627-008
GCA Control No. 42787
DATA REPORT SHEET
Purgeables
Sample I.D. C-IP-1D
Analysis Date 03/18/85
Sample Matrix Wafer
Instrument HP5985 GC/MS
Sample Dilution None
I— « /\ • £3 •
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chloromethane .
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethy^lene
1 , 1-Dichloroethane
Trans-1 1 2-dichioroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodi chloromethane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
ND
66
ND
ND
ND
ND
ND
ND
9
ND
ND
ND
C* • /» • D •
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1^2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethylene
Dibromechlorome thane
Benzene
cis-1, 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methvl-2-pentanone (MIBK)
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
4
ND
ND
ND
ND = < 3 ug/1
ND* » < 5 ug/1
K = Quantitation below detection limit
ortho- 95-47-6, meta- 108-38-3, para- 106-42-3
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows
•^•F- ^mr mfmm
GCA
GCACOnPOR-r..'.-.i:
Technology Divisioi
3-2
-------
Project 3-627-008
GCA Control No. 42787
Sample I. p. C-I.P-11)
Sample Matrix Water
DATA REPORT SHEET
Additional Compounds
Instrument HP5985 GC/MS
Analysis Date 03/18/85
Sample Dilution N°ne
C.A.S.
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Ally! Alcohol
Bis (chloromethyl )ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorodif luorome thane
Diethyl ether
Ethvl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
i-» • A * o •
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrof uran
Trichlorof luorome thane
1,1,2-Trichloro-
lj 2 , 2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI =* Direct Injection
ug/1 = ppb (for density of water)
ND - < 3 ug/1
NA = Not analyzed by Purge and Trap
K = Quantitation below detection limit
B-3
•^•r- ^fr «^^*»
GCA
GCA CORPORA;.: i:
Technology Division
-------
Project 1-627-OQ8
GCA Control No. 42791
DATA REPORT SHEET
Purgeables
Sample I.D.
C-liP-in
Analysis Date 03/18/85
Sample Matrix Water
Instrument HP5985 GC/MS
Sample Dilution
None
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chloromethane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethy lene
Chloroform
2-Butanone (MEK)
1 , 1 f 1-Trichloroethane
Carbon tetrachloride
Bromodi chloromethane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
3
97
ND
ND
ND
ND
4
ND
6
ND
ND
ND
v^ •/»•&•
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethylene
Dibromechlorome thane
Benzene
cis-1 LS-Dichloropjropylene
2-ChloroethylvinyJ.ether
Bromoform
4-Methyl-2-pentanone (MIBK)
Tetrachloroethylene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
8
ND
ND
ND
PT = Purge and Trap
DI = Direct Injection
ND » < 3 ug/1
ND* - < 5 ug/1
K *» Quantitation below detection limit
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows: ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-4
•*ar ~*mr «w^
GCA
GCA CORPOR- :0i:
Technology Divisioi
-------
Project 1-627-008
GCA Control No. 42791
DATA REPORT SHEET
Additional Compounds
Sample T.n.
Sample Matrix Water
Instrument HP5985 GC/MS
Analysis Date
03/18/85
Sample Dilution None
L^ • /\ • o •
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethyl )ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Di chlorodif luoromethane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrof uran
Trichlorof luoromethane
1,1,2-Trichloro-
1,2, 2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND '
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI « Direct Injection
ug/1 = ppb (for density of water)
ND » < 3 ug/1
NA •» Not analyzed by Purge and Trap
K « Quantitation below detection limit
^Mf^- ^B^- «••••»
GCA
GCA CORPORA iiO;
Technology Division
B-5
-------
Project 1-627-OOS
CCA Control No.
42812
DATA REPORT SHEET
Pesticides/PCSs
Sample I.D.
C-CS-1A
Analysis UaLe 5-14-85
Sacple Matrix Bulk
Instrument
HP 5880A CC w/Ni63 ECD
Parameter
aldrin
o-BHC
e-BHC
6-BHC
Y-3HC
chlordane
4,4'-DDD
4, 4' -DDE
4, 4' -DDT
dieldrin
endcsulfan I
endosulfan II
endoaulfan aulfate
endrin
Ion Used To
Quantitate
Concentration
( mg/kg )
ND
ND
ND
ND
ND
<3.0
ND
ND
ND
ND
ND
ND
ND
ND
Remarks
endrin aldehyde
ND
heotachlor
heo each lor eo oxide
Coxae hene
PC3-1016
PCS-1221
PCS-1232
PC3-1242
PC3-1248
PC3-1254
PC3-1260
ND
<7.0
104
ND*
ND*
ND*
ND*
ND*
ND*
ND*
XD = <1.0 mg/kg
ND* = <7.0 mg/kg
B-6
GCA
Technology Division
-------
Project 1-627-008
GCA Control No. 42441
DATA REPORT SHEET
Purgeables
FBB
Sample J.D.
FI1H 011585-P
Analysis Date 3-18-85
Sample Matrix Water
Instrument IIP5985 GC/MS
Sample Dilution None
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Ch 1 or ome thane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-lf 2-dichloroethylene
Chloroform
2-Butanone (MEK)
lf li 1-Trichloroethane
Carbon tetrachloride
Bromodich lor ome thane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
ND
80
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
L • A • D •
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1 1 1 jj> , 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethvlene
Dibromechlorome thane
Benzene
cis-1, 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methyl-2-pentanone (MIBKL
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
ND
ND
ND
ND
PT = Purge and Trap
DI = Direct Injection
ND = < 3 ug/1
ND* = < 5 ug/1
K = Quantitation below detection limit
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows: ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-7
•^^r ~^mr mm*f^
GCA
GCACORPon-r,;:.i:
Technology Divisioi
-------
Project 1-627-008
Sample T.D.
FBD 011585-P
Sample Matrix Water
DATA REPORT SHEET
Additional Compounds
Instrument HP5985 GC/MS
GCA Control No. 42441
FDB
Analysis Date 03/18/85
Sample Dilution None
C.A.S.
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethyl )ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorodif luorome thane
Diethvl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luorome thane
1,1,2-Trichloro-
1 ,Jj 2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND - < 3 ug/1
NA » Not analyzed by Purge and Trap
K •» Quantitation below detection limit
B-8
GCA
.
Technology Division
-------
Project 1-627-008
GCA Control No. A2624
DATA REPORT SHEET
Purgeables
Sample I.D.
LC-Mlx-lD
Analysis Date 3/6/85
Sample Matrix
Water
Instrument Finn MAT OWA
Sample Dilution
1:5
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Ch lor ome thane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1 , 1 , 1-Trichloroethane
Carbon tetrachloride
Bromodichlorome thane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
1300
130
ND
ND
ND
ND
36
ND
ND
ND
ND
ND
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1 , Ij2j^2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethvlene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methyl-2-pentanone (MIBK)
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concer.tratio
(ug/1)
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
67
ND
ND
PT = Purge and Trap
DI = Direct Injection
ND = < 15 ug/1
ND* = <25 ug/1
K = Quantitation below detection limit
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows: ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-9
GCA
Technology Divisioi
-------
Project 1-627-008
GCA Control No. 4262/l
Sample I.D.
LC-Mlx-lD
Sample Matrix Water
DATA REPORT SHEET
Additional Compounds
Instrument Finn MAT OWA
Analysis Date
3/6/85
Sample Dilution
1:5
C.A.S.
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethyl )ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorodif luorome thane
Diethyl ether
Ethvl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luorome thane
1,1, 2-Trichloro-
1,2, 2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 - ppb (for density of water)
ND « < 15 ug/1
NA = Not analyzed by Purge and Trap
K = Quantitation below detection limit
B-10
GCA
GC
Technology Division
-------
Project 1-627-008
GCA Control No. 42628
DATA REPORT SHEET
Purgeables
Sample I.D.
LC-OF-1D
Analysis Date 3/6/85
Sample Matrix
Water
Instrument Finn MAT OWA
Sample Dilution_
1:5
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Ch lor ome thane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 / 1-Dichloroethylene
1 , 1-Dichioroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodichlorome thane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
ND
ND*
ND
ND
ND
ND
16
ND
ND
ND
ND
ND
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1 , 1 , 2_t 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethylene
Dibromechlorome thane
Benzene
cis-lL3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methvl-2-oentanone (MIBK)
Tetrachloroethylene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concer.tratio
(ug/1)
ND
ND
ND
ND
ND
ND
ND
ND*
. ND
ND*
12
ND
ND
ND
ND
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows
ND = < 15 ug/1
ND* = <25 ug/1
K = Quantitation below detection limit
ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-ll
GCA
Technology Divisioi
-------
Project 1-627-008
GCA Control No. 42628
Sample I.D.
LOOP-ID
Sample Matrix Water
DATA REPORT SHEET
Additional Compounds
Instrument Finn HAT OWA
Analysis Date
3/6/85
Sample Dilution
1:5
v* • f\ • £j •
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethvl )ether
Cyclohexane
Cyclohexanone
1, 2-Dibromoethane
Dicnlorodif luorome thane
Diethyl ether
Ethvl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luorome thane
1,1,2-Trichloro-
1 , 2 , 2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND •» < 15 ug/1
NA = Not analyzed by Purge and Trap
K = Quantitation below detection limit
B-12
••A
GCA
GCA
Technology Division
-------
Project 1-627-01:8 t:i:,\ Omrr-.l n.,. A 2 SI 5
HATA KKIMKI' I'.IIKKT
MI-mis-
Sample i.D. IIC:S.L-IA
Saraple Matrix R«''k Si-lids
Element.
1CAP An.nlvsis
Aluminum
Antiiaony
Arsenic
B.irium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cob.iU
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Selenium
Silicon
Silver
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
':7;;;rr
iaooa
<3.oa
<3.0
69. h
0.886
5.52
7.ya
64300
12.5
1.H7
lb.2
3^80
140
'J"00
107
<0.4
43.7
<4.03
. 294
<0.(S
/,503
113
•!.U;1
'0.8
5/«.9
4.9
57.1
These values should ho considered st:m[-(]ii;incLcntive due to severe matrix
incerferences frnvMiiUi'r
-------
Proj ec t 1-627-008
GCA Control No. 42815
DATA REPORT SHEET
Pesticides/PCSs
Sample I.D. LC-SL-1A
Analvsia Date 5-14-85
Sample Matrix Bulk
Instrument HP 5840A GC v/Ni63 ECD
Parameter
aldrin
Q.-BHC
E-BHC
5-BHC
Y-BHC
chlordane
4,4' -ODD
4, 4' -DDE
4,4'-DDT
dieidrin
endosulfan I
endosulfan II
endosulfan sulfate
endrin
endrin aldehyde
heotachlor
hectachlor eooxide
toxanhene
PC3-1016
PCB-1221
PCB-1232
PCB-1242
PCS -1248
PCB-1254
PC3-1260
Ion Used To
Quantitate
Concentration
( mg/kg )
ND
<0.10
<0,50
<0.50
<0.10
ND*
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
30
ND*
ND*;
ND*
ND*
ND*
ND*
ND*
Remarks
ND = <1.0 mg/kg
ND* = <5.0 mg/kg
B-14
GCA
Technology Division
-------
Project 1-627-008
GCA Control No. 42815-A
DATA REPORT SHEET
Acid Extracables
Sample I.D
LC-SL-1A
Analysis Date 4-6-85
Sanrole Matrix water
Parameter
Phenol
2-Chlorooheno 1
2-Nitrophenol.
2 ,4-Dimethy Iphenol
2.4-Dichlorophenol
4-Chloro-3-methylphenol
2,4, 6-Tr ichloropheno 1
2 , 4-Dini tropheno 1
2-Methy 1-4, 6-dini tropheno 1
4-Nitropheno 1
Pentachlorophenol
Instrument
CAS t
108-95-2
95-57-8
88-75-5
105-67-9
120-83-2
59-50-7
88-06-2
51-28-5
534-52-1
100-02-7
87-86-5
HP 5985A GC/MS
Concentration
(mg/kg)
ND
ND
ND
ND
ND
ND
ND
ND*
ND*
ND*
ND*
ND = < 10 mg/kg
ND* = < 50 mg/kg
B-15
•^^ ~^^ <^^^»
GCA
GCA CORPORATION
Technology Division
-------
Project 1-627-008
42815-BN
Sample I.D._
GCA Control No.
DATA REPORT SHEET
Base/Neutral Extractables
LC-SL-1A 1:2 dil Analysis Date *~6-85
Sample Matrix water
Instrument
HP 5985 GC/MS
CAS #
Parameter
Concentration
(mg/kg)
111-44-4
541-73-1
106-46-7
95-50-1
39638-32-9
621-64-7
67-72-1
98-95-3
78-59-1
119-91-1
120-83-1
91-20-3
87-68-3
91-58-7
131-11-3
208-96-8
606-20-2
83-32-9
121-14-2
84-66-2
86-73-7
7005-72-3
118T-74rl
85-01-8
120rl2T-7
84-74-2
129-00-0
95-68-7
91-94-1
56-55-3
218-01^9
117-81-7
117^84r-0
205-99-2/207-08-9
50^-32r-8
193-39-5
53-70-3
191-24-2
ND =< 2 mg/kg
Bis(2-Chloroethvl)ether
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
1,2-Dichlorobenzene
Bis(2-Chloroisopropyl)ether
N-nitrosodi-n-propvlamine
Hexachloroe thane
Nitrobenzene
Isoohorone
Bis (-2-Chloroethoxy )methane
1,2,4-Trichlorobenzene
Napthalene
Hexachlorobutadiene
2-Chloronaphthalene
Dimethvl phthalate
Acenaphthylene
2 , 6-Dini tro to luene
Acenaptherie
2 ,4-Dinitroto luene
Diethvl phthalate
Fluor ene
4-Chloroohenvl phenyl ether
Hexachlorobenzene
Phenanthrene
Anthracene
Di-n- Butyl phthalate
Pyrene
Butvl benzyl ohthalate
3,3'-Dichlorbenzidine
Benzo ( a ) anthracene
Chrysene
Bis (2-ethylhexyl)phtha late
Di-n-octyl phthalate
Benzo (b)fluoranthene/Benzo(k)fluoranthenea
Benzo(a)Pyrene
Indeno( 1 ,2 ,3-cd)pyrene
Dibenzo(a.h)anthracene
Benzo ( z .h . i)pery lene
ND* =< 4 mg/kg
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND . . .
ND
ND
ND*
ND
ND
58
ND
ND
ND
ND*
ND*
ND*
aUnder the conditions stipulated by EPA Method 625 this compound pair cannot
be chromatographically resolved. The concentration reported reflects the total
of both isomers.
B-16
~^^ '•^r ^^H»
GCA
GCA CORPORATION
Technology Division
-------
Project 1-627-008
GCA Control No. 42759
DATA REPORT SHEET
Purgeables
Sample I.D. flO-CL-ID
Analysis Date 03/18/85
Sample Matrix Water
Instrument HP5985 GC/MS
Sample Dilution None
Vrf • «\ » O •
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chloromethane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethy^lene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodi chloromethane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
ND
75
ND
ND
ND
ND
ND
ND
7
ND
ND
ND
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethvlene
Dibromechloromethane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methvl-2-pentanone (MIBK)
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
ND
ND
ND
ND
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows
ND = < 3 ug/1
ND* = < 5 ug/1
K = Quantitation below detection limit
ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-17
GCA
GCA CORPOR-:.:'•(:
Technology Divisioi
-------
Project 1-627-008
GCA Control No. 42759
DATA REPORT SHEET
Additional Compounds
Sample I.D. OO-CL-1D
Sample Matrix Water
Instrument HP5985 GC/MS
Analysis Pate 03/18/85
Sample Dilution None
C.A.S.
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis ( chloromethyl )ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorodif luorome thane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luorome thane
1,1,2-Trichloro-
1 12 1 2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND - < 3 ug/1
NA = Not analyzed by Purge and Trap
K = Quantitation below detection limit
B-18
GCA
GCACORPOR-'V.i:
Technology Division
-------
Project 3-627-008
GCA Control Mo. 42763
DATA REPORT SHEET
Purgeables
Sample I. D. CO-DAE-ID
Analysis Date
5/20/85
Sample Matrix Water
Instrument Finnigan MAT OWA
Sample Dilution 1:500
C . A : S .
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chlorome thane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethvlene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Dutanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Dromodi chlorome thane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethylene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethvlvinylether
Bromof orm
4-Methyl-2-pentanone (MIBK)
TetrachloroethyJLene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
ND
ND
ND
ND
PT = Purge and Trap
DI - Direct Injection
ND = <1500 ug/1
ND* = <2500 ug/1
K = Quantitation below detection limit
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows: ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-19
GCA
r,cv\ Connor?'
Technology Division
-------
Project 1-627-008
GCA Control No. 42763
DATA REPORT SHEET
Additional Compounds
Sample I.D.
GO-DAE-ID
Sample Matrix Water
Instrument Finnlgan MAT OWA
Analysis Date
5/20/85
Sample Dilution 1:500
C.A.S.
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Ally! Alcohol
Bis (chloromethyl )ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
bi chlorodif luoromethane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luoromethane
1,1,2-Trichloro-
1 , 2 , 2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 - ppb (for density of water)
ND = < 1500ug/l
NA <= Not analyzed by Purge and Trap
K = Quantitation below detection limit
B-20
GCA
Technology Division
-------
Project 1-627-008
GCA Control No.
42766
DATA REPORT SHEET
Purgeables
Sample I.D.
CO-DAT-1C
Analysis Date
03/04/85
Sample Matrix Water
Instrument HP5985 GC/MS
Sample Dilution 1;50°
L* • A • b •
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chlorome thane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichioroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodichloromethane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
4500
9500
ND
ND
ND
ND
2000
ND
ND
ND
ND
ND
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethvlene
Dibromechloromethane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromof orm
4-Methyl-2-pentanone (MIBK)
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
64000
ND
ND*
ND
ND*
ND
1400
ND
ND
ND
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows
ND = < I500ug/l
ND* = < 2500 ug/1
K = Quantitation below detection limit
ortho- 95-47-6, meta- 108-38-3, para- 106-42-3
B-21
GCA
GCA CORPOR--:•.•!!
Technology Divisioi
-------
Project 1-627-008
GCA Control No. 42766
DATA REPORT SHEET
Additional Compounds
Sample I.D.
GO-DAI-1C
Sample Matrix
Water
Instrument HP5985 GC/MS
Analysis Date
03/04/85
Sample Dilution
v*» • ** • O •
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bistchloromethvl )ether
Cyclohexane
Cyclohexanone
1 / 2-Dibromoethane
Dichlorodif luoromethane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
C* • /V • £> •
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luoromethane
1 , 1 / 2-Trichloro-
1 , 2 , 2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND - < 1500 ug/1
NA = Not analyzed by Purge and Trap
K = Quantitation below detection limit
B-22
GCA
GCA CORPORA Jr.".',
Technology Division
-------
Project 1-627-OQ8
GCA Control No.
42771
DATA REPORT SHEET
Purgeables
Sample I.D.
fiO-OXE-lD
Analysis Date 03/18/85
Sample Matrix Water
Instrument HP5985 GC/MS
Sample Dilution None
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3'
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Ch lor ome thane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1 f 1 , 1-Trichloroethane
Carbon tetrachloride
Bromodich lor ome thane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
ND
55
ND
ND
ND
ND
A
ND
ND
ND
ND
ND
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-l| 3-dichloropropylene
Trichloroethvlene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methyl-2-pentanone (MIBK)
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
ND
ND
ND
ND
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows
ND = < 3 ug/1
ND* = < 5 ug/1
K = Quantitation below detection limit
ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-23
-^^r- -^mr *BB^
GCA
GCA CORPGR--'' •-'••:
Technology Divisioi
-------
Project 1-627-006
GCA Control No.
42771
DATA REPORT SHEET
Additional Compounds
Sample I.p. no-QXE-in
Sample Matrix Water
Instrument HP5985 GC/MS
Analysis Date
03/18/85
Sample Dilution None
C.A.S.
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethvl )ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichiorodif luorome thane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
t-» • A • £i •
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luoromethane
1,1,2-Trichloro-
lL2J2-trif luoroethane
1 , 1 ,1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT - Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND = < 3 ug/1
NA = Not analyzed by Purge and Trap
K = Quantitation below detection limit
B-24
-^^r -^^f «™^~
GCA
GCA CORPORA:.;':i;
Technology Division
-------
Project 1-627-008
GCA Control No. 42774
DATA REPORT SHEET
Purgeables
Sample I.D. CO-OKI-1C
Analysis Date 03/04/85
Sample Matrix
Water
Instrument HP5985 GC/MS
Sample Dilution 1;10°
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chloromethane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodi chloromethane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
1700
1700
ND
ND
ND
ND
4300
ND
ND
ND
ND
ND
(•* • *» • *3 •
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
lj 1 i 2 , 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethvlene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropvlene
2-Chloroethylvinylether
Bromoform
4-Methvl-2-pentanone (MIBK)
Tetrachloroethylene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
11200
ND
ND*
ND
ND*
ND
4900
ND
600
500
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows
ND =» < 300 ug/1
ND* = < 500 ug/1
K = Quantitation below detection limit
ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-25
^^ -^BT- •^••B
GCA
GCA CORPGR-:> "i:
Technology Divisioi
-------
Project 1-627-008
GCA Control No. 42774
DATA REPORT SHEET
Additional Compounds
Sample I.D.
GQ-OX1-1C
Sample Matrix Water
Instrument HP5985 GC/MS
Analysis Date 03/04/85
Sample Dilution 1*100
C.A.S.
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethyl )ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorodif luorome thane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
v* • A • o •
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luorome thane
1,1,2-Trichloro-
1 i 2 t2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND « < 300 ug/1
NA *> Not analyzed by Purge and Trap
K *» Quantitation below detection limit
B-26
GCA
GCA CORPORA i i.
Technology Division
-------
Project 1-627-008
GCA Control No. 42779-KA)
DATA REPORT SHEET
Purgeables
Sample I.D. GO-SB-ID
Analysis Date 3-18-85
Sample Matrix
Water
Instrument HP5985 GC/MS
Sample Dilution None
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chi or ome thane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodichloromethane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
ND
66
ND
ND
ND
ND
113
ND
ND
ND
I/
ND
v>* • *» • o •
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
ij 1 , 2 , 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethvlene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methyl-2-pentanone (MIBK)
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
ND
ND
ND
ND
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows
ND = < 3 ug/1
ND* = < 5 ug/1
K = Quantitation below detection limit
ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-27
•*ur ^•r-^B""
GCA
GCA
Technology Divisioi
-------
Project 1-627-008
GCA Control No. 42779-l(A)
DATA REPORT SHEET
Additional Compounds
Sample I.D.
GO-SB-ID
Sample Matrix
Water
Instrument HP5985 GC/MS
Analysis Date
3-18-85
Sample Dilution NONE
v* • *» • O •
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bisichloromethyl lether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorodif luorome thane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
v* • *» » O •
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luorome thane
1,1,2-Trichloro-
1,2, 2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND • < 3 ug/1
NA = Not analyzed by Purge and Trap
K - Quantitation below detection limit
B-28
GCA
GCA CORPORA:-.'.(i
Technology Division
-------
Project 1-627-008
GCA Control No. 42779-2(B)
DATA REPORT SHEET
Purgeables
Sample I.D.
flO-SB-TD
Analysis Date 3-18-85
Sample Matrix_
Water
Instrument HP5985 GC/MS
Sample Dilution None
v^ • *» • O •
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Ch lor ome thane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodichlorome thane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
ND
64
ND
ND
ND
ND
85
ND
ND
ND
14
ND
L* • A • o •
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropvlene
Trichloroethvlene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromof orm
4-Methvl-2-pentanone (MIBK)
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
ND
ND
ND
ND
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows;
ND = < 3 ug/1
ND* = < 5 ug/1
K = Quantitation below detection limit
ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-29
•*M^ ^•T-.HMM
GCA
GCACORPCR-rCi:
Technology Divisioi
-------
Project 1-627-008
GCA Control No. 42779-2(B)
Sample I.D.
GO-SB-ID
Sample Matrix_
Water
DATA REPORT SHEET
Additional Compounds
Instrument HP5985 GC/MS
Analysis Date
3-18-85
Sample Dilution None
C.A.S.
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Ally! Alcohol
Bis (chloromethvl )ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorodif luoromethane
Diethyl ether
Ethvl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luoromethane
1,1, 2-Trichloro-
lj 2 1 2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND = < 3 ug/1
NA « Not analyzed by Purge and Trap
K = Quantitation below detection limit
B-30
GCA
GCACORPOFV'iiO:
Technology Division
-------
Project 1-627-008
GCA Control No.
A2782
DATA REPORT SHEET
Purgeables
Sample I.D.
GO-SO-1C
Analysis Date
03/04/85
Sample Matrix Water
Instrument HP5985 GC/MS '
Sample Dilution 1;100
V- • f\ • O •
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Ch lor ome thane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodichlorome thane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
4000
6500
ND
ND
ND.
ND
ND
8800
ND
ND
ND
900
*-* • A • JD •
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethvlene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methyl-2-pentanone (MIBK)
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
7900
ND
ND*
ND
ND*
ND
4800
ND
ND
ND
PT = Purge and Trap
DI = Direct Injection
ND = < 300 ug/1
ND* » < 500 ug/1
K = Quantitation below detection limit
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows: ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-31
•^^ -^mr ^m^~
GCA
GCA CORPGR~!>...i:
Technology Divisioi
-------
Project 1-627-006
GCA Control No.
42782
DATA REPORT SHEET
Additional Compounds
Sample I.D.
CO-SO-1C
Sample Matrix Water
Instrument HP5985 GC/MS
Analysis Date 03/04/85
Sample Dilution IrlOO
C.A.S.
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis(chloromethyl) ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorodif luoromethane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND •
ND
ND
ND
ND
ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luoromethane
1,1,2-Trichloro-
lj 2 L2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND » < 300 ug/1
NA = Not analyzed by Purge and Trap
K = Quantitation below detection limit
3-32
GCA
GCA CORPORA ; i•:.!•.
Technology Division
-------
Project 1-627-008
GCA Control Me.
42808
DATA REPORT SHEET
Headspace Analysis
Sample I.D.
GO-CO-1A
Analysis Date
2/27/85
Sample Matrix
Soil Core
Instrument HP5985 GC/MS
Sample Dilution
N.A.
C . A. S .
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chlorome thane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 t 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodi chloromethane
Total xylenes
Concentration
(ug/g)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1, 3-dichloropropylene
Trichloroethylene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methyl-2-pentanone (MIBK)
Tetrachloroethylene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratit
(ug/g )
ND
ND
ND
' ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND = < 5.0 ug/g
"9/g = PPt>
*C.A.S. Numbers for xylene isomers are as follows: ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-33
^^ -^^ ^•••B
GCA
,••'. COR'1 •"
Technology Division
-------
Project, 1-627-008
GCA Control No. 42808
Sample I.D. GO-CO-1A
Sample Matrix Soil Core
DATA REPORT SHEET
Headspace Analysis
Additional Compounds
Instrument HP5985 GC/MS
Analysis Date 2/27/85
Sample Dilution
N/A
C.A.S.
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Ally! Alcohol
Bis(chloromethvl) ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorodif luoromethane
Diethvl ethor
Ethvl acetate
Ethyl acrylate
Concentration
(ug/g )
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
C» • A • o *
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luoromethane
1,1, 2-Trichloro-
lj 2 , 2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/g)
ND
ND
ND
N
ND
ND
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
ND
< 5.0 ug/g
Ug/g a ppb
B-34
GCA
rS,t- CORPOF-'
Technology Division
-------
Project 1-617-008
GCA Control No.
42808-A
DATA REPORT SHEET
Acid Extracables
Sample I.D. GO-CO-1A (S-7) I;5 dil
4-6-85
Sample Matrix Water
Parameter
Phenol
2-Chloroohenol
2-Nitrophenol
2,4-Dinethylphenol
2 ,4-Dichlorophenol
4-Ch lor o-3 -methy Ipheno 1
2,4,6-Trichlorophenol
2 ,4-Dinitropheno 1
2-Me thy 1-4 , 6-dini tropheno 1
4-Nitropheno 1
Pentachloropheno 1
Instrument
CAS #
108-95-2
95-57-8
88-75-5
105-67-9
120-83-2
59-50-7
88-06-2
51-28-5
534-52-1
100-02-7
87-86-5
HP 5985A GC/MS
Concentration
nig/ kg
ND
ND
ND
9.0 k
ND
ND
ND
ND*
ND*
ND*
ND*
ND = < 7 mg/kg
ND* - < 35 tag/kg
k = present but below detection limit.
B-35
^^r -^^^ *^^^»
GCA
GCA CORPORATION
Technology Division
-------
Project 1-627-008
GCA Control No..
DATA REPORT SHEET
42808 BN
Base/Neutral Extractables
Sample I.D. GO-CO-1A (S-7) 1:250 dil Analysis Date_i±!I
Sample Matrix Water Instrument HP 5985 GC/MS
CAS #
111-44-4
541-73-1
106-46-7
95-50-1
39638-32-9
621-64-7
67-72-1
98-95-3
78-59-1
119-91-1
120-83-1
91-20-3
87-68-3
91-58-7
131-11-3
208-96-8
606-20-2
83-32-9
121-14-2
84-66-2
86-73-7
7005-72-3
118-74-1
85r-01-8
120-12-7
84-74-2
129-00-0
95-68-7
91-94rl
56-55-3
218-01-9
117-81-7
117^84^0
205-99-2/207-08-9
50^32-8
193-39-5
53-70-3
191-24-2
Parameter Concentration
nig/ kg
Bis(2-Chloroethvl) ether
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
1.2-Dichlorobenzene
Bis (2-Chloroisopropvl) ether
N-nitrosodi-n-proovlamine
Hexachloroethane
Nitrobenzene
Isophorone
Bis(-2-Chloroethoxv)methane
1 ,2,4-Trichlorobenzene
Naothalene
Hexachlorobutadiene
2-Ch loronaphtha lene
Dimethyl phthalate
Acenaphthylene
2 , 6-Dinitroto luene
Acenapthene
2,4-Dinitrotoluene
Diethvl phthalate
Fluorene
4-Chloroohenyl phenyl ether
Hexachlorobenzene
Phenanthrene
Anthracene
Di-n-Butyl phthalate
Pvrene
Butyl benzyl phthalate
3,3'-Dichlorbenzidine
BenzoC a) anthracene
Chrysene
Bis (2-ethylhexyl)phtha late
Di-n-octvl phthalate
Benzo(b)f luoranthene/Benzo(k)f luoranthenea
Benzo(a)Pyrene
Indeno ( 1 , 2 , 3-cd ) pyrene
Dibenzo(a,h)anthracene
Benzo(g,h,i)perylene
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
122
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND . . .
ND
ND
ND*
ND
ND
ND
ND
ND
ND
ND*
ND*
ND*
ND =<• 350 mg/kg ND* =< 700 mg/kg
aUnder the conditions stipulated by EPA Method 625 this compound pair cannot
be chromatographically resolved. The concentration reported reflects the total
of both isomers.
Additional 308 ug/1 2-methyl naphthalene
k = present but below detection limits
B-36
••^^ i^pr «••»
GCA
GCA CORPORATION
Technology Division
-------
Proj ec t 1-627-OOS
CCA Control
DATA HKl'ORT SHEET
42308
Sample I.D. CO-CO- LA (S-7)
Sample Matrix S
Report Date 0 '3/23/85
Element
Tlialliun
Concentration
ICAP Analysis
Aluminum
41000a
Antinonv '•-'
Arsenic
Barium
Be rv Ilium
Boron
20
75.1
8.52
H.8
Cadmium '
Calcium
Chromium
Cobalt
Coooer
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
S>ileniu:a
Silicon
Silver
13400
602
5.94
3SI
35300
290
ft WO
197 '
-0.4
63.3
<4.0a
151
<0.f>
Sodium 14000
Strontiun
66.0
Tin
27.5
Titanium
176
Vanadium
74
Zinc
40!
These values should b».v considered seml-qunntitativfi due to severe matrix
interferences tMicoir.icorc'd in rlu1 nnnlvsis.
B-37
GCA
> *'• •" !-(>HPC~/- ' iuf ;
Technology Division
-------
Pr o j e c c T-6!!7-OUg
Sample I.D. C^-^L-IA
CCA Control N". 42ST ^
DATA K«-:iH)KT SI1KKT
MI-I,I Is
K.-imri O.U-; (n/2H/3r)
Saraple Matrix r>>il !< jln! ids
Element
Concentration
< us/g )
ICAP Aiialyais
Alucinum
Ancimony
Arae-.uo
Barium
Berylliuia
Boron
Cadmiur.
Calcium
ChroraiuK!
Cobalt
28000*
5.27
1.49
3180f)
64.3
10.0"
Copper
15.2
Iron
17300
Lead
190
Magnesium
591
Mo Ivbdenum
<0.4
Nickal
51.1
Selenium
24'
Silicon
818
Silver
<0.6
Sml ium
Strontium
53.3
Thai I turn
Tin
14.7
Titanium
230
V.in.iu:;l'iiT«-tl :.'-iui - 'jiuint lent i v«: Jut.: I" :-i-'-v«:ry
if i-t «•»! i.i (in- ,i.:.-il vs I.s.
B-38
DIviMO/i
-------
Project 1-627-008
GCA Control No.
DATA REPORT SHEET
Purgeables
FBB
Sample I.D.
miSRS-F
Analysis Date 3-18-85
Sample Matrix Water
Instrument HP5985 GC/MS
Sample Dilution None
^* • /» • o •
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chloromethane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodichlorome thane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
ND
67
ND
ND
ND
ND
ND
ND
ND
ND
C> • /V • o •
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1 , 1 , 2j 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethylene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropvlene
2-Chloroethylvinylether
Bromoform
4-Methvl-2-pentanone (MIBK)
Tetrachloroethylene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
ND
ND
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows;
ND = < 3 ug/1
ND* - < 5 ug/1
K = Quantitation below detection limit
ortho- 95-47-6, meta- 108-38-3, para- 106-42-3
B-39
•nnr -^mr «••••
GCA
GCA CORPOR-r.."1.!:
Technology Diwisioi
-------
Project 1-627-OOe
DATA REPORT SHEET
Additional Compounds
Sample I.p. FBB OU585-F
Sample Matrix Water
Instrument HP5985 GC/MS
GCA Control No.
FBB
Analysis Date 3-18-85
Sample Dilution None
C.A.S.
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethyl )ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorodif luorome thane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrof uran
Trichlorof luorome thane
1,1, 2-Trichloro-
If_2_i2-trifluoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND - < 3 ug/1
NA = Not analyzed by Purge and Trap
K » Quantitation below detection limit
B-40
GCA
GCA CORPORA.. '
Technology Division
-------
Project 1-627-008
GCA Control No. 42632
DATA REPORT SHEET
Purgeables
Sample I.D.
LNVA-AL-1D
Analysis Date 3/7/85
Sample Matrix
Water
Instrument Finn MAT OWA
Sample Dilution_
None
O. A . S .
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Ch 1 or ome thane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , l-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1 t 1-Trichloroethane
Carbon tetrachloride
Bromodich lor ome thane
Total xylenes
Concentration
(ug/1)
ND*
ND
• ND*
ND
ND
ND*
ND
ND
ND
ND
14
ND
ND
ND
ND
ND
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1 , 1 , 2j 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethylene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methyl-2-pentanone (MIBK)
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concer.tratio
(ug/1)
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
ND
ND
ND
ND
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows
ND = < 3 ug/1
ND* » < 5 ug/1
K » Quantitation below detection limit
ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-41
GCA
Technology Divisioi
-------
Project 1-627-008
GCA Control No. *2632
DATA REPORT SHEET
Additional Compounds
Sample I.D.
LNVA-AL-ln
Sample Matrix Water
Instrument Finn MAT OWA
Analysis Date
3/7/85
Sample Dilution
None
Vx • f\ • O •
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethvl )ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichiorodif luorome thane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
v* • A • S •
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrof uran
Trichlorof luoromethane
1,1,2-Trichloro-
1,2, 2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND ='< 3 ug/1
NA = Not analyzed by Purge and Trap
K = Quantitation below detection limit
B-42
OCA
GCA
Technology Division
-------
Project 1-627-008
GCA Control No. 42636
Sample I.D.
Sample Matrix
LNVA-AV-1D
Water
DATA REPORT SHEET
Purgeables
Instrument Finn MAT OWA
Analysis Date 3/8/85
Sample Dilution
None
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chloromethane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
i, 1-Dichloroet hygiene
1 , I-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1 j 1 tl-Trichloroethane
Carbon tetrachloride
Bromodi chloromethane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
ND
ND
ND
ND
ND
ND
3.9
ND
ND
ND
ND
ND
{* • /» • ^ •
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethvlene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4~Methyl-2-pentanone (MIBK)
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concer.tratio
(ug/1)
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
ND
ND
ND
ND
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND = < 3ug/1
ND* = < 5 ug/1
K =» Quantitation below detection limit
*C.A.S. Numbers for xylene isomers are as follows: ortho- 95-47-6, meta- 108-38-3, para- 106-42-3
B-43
GCA
Technology Divisioi
-------
Project 1-627-008
GCA Control No.
42636
DATA REPORT SHEET
Additional Compounds
Sample I.D.
LNVA-AV-1D
Sample Matrix Water
Instrument Finn MAT OHA
Analysis Date
3/8/85
Sample Dilution
None
\f • t\ • ^ •
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethvl ) ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorodif luorome thane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
C* • t\ • o •
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrof uran
Trichlorof luorome thane
1 , 1 , 2-Trichloro-
Ii2f2-trif luoroe thane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND - < 3 ug/1
NA = Not analyzed by Purge and Trap
K = Quantitation below detection limit
B-44
GCA
GCA CQR?:>V '
Technology Division
-------
Project 1-627-008
GCA Control No. ^2640
DATA REPORT SHEET
Purgeables
Sample I.D.
LNVA-CL-1D
Analysis Date 3/8/85
Sample Matrix
Water
Instrument Finn MAT OWA
Sample Dilution
None
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chloromethane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodi chloromethane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
ND
ND*
ND
ND
ND
ND
9.0
ND
ND
ND
ND
ND
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
]j 1, 2 , 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1, 3-dichloropropylene
Trichloroethylene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methyl-2-pentanone (MIBK)
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concer.tratio
(ug/1)
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
ND
ND
ND
ND
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows:
ND = < 3 ug/1
ND* = < 5 ug/1
K = Quantitation below detection limit
ortho- 95-47-6, meta- 108-38-3, para- 106-42-3
B-45
GCA
Technology Divisioi
-------
Project 1-627-008
GCA Control No. 42640
DATA REPORT SHEET
Additional Compounds
Sample I.D.
LNVA-CL-1D
Sample Matrix Water
Instrument Finn MAT OWA
Analysis Date
3/8/85
Sample Dilution_
None
C.A.S.
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Ally! Alcohol
Bis(chloromethvl)ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorodif luorome thane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luorome thane
1,1,2-Trichloro-
1 , 2 i 2-trif luoroe thane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
«
ug/1 = ppb (for density of water)
ND = < 3 ug/1
NA = Not analyzed by Purge and Trap
K = Quantitation below detection limit
B-46
GCA
GCA CGRP:>~-' '
Technology Division
-------
Project 1-627-008
GCA Control No. 42646
DATA REPORT SHEET
Purgeables
Sample I.D.
I.NVA-SL-1D
Analysis Date_
3/6/85
Sample Matrix
Water
Instrument Finn MAT OWA
Sample Dilution
1:10
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chloromethane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodi ch 1 or ome thane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
ND
ND*
ND
ND
ND
ND
30
ND
ND
ND
ND
ND
V* • f\ • k> •
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethylene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromof orm
4-Methvl-2-pentanone (MIBK)
Tetrachloroethylene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concer.tratio
(ug/1)
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
ND
ND
ND
ND
PT = Purge and Trap
DI = Direct Injection.
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows:
ND = < 30 ug/1
ND* - < 50 ug/1
K - Quantitation below detection limit
ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-47
GCA
Technology Divisioi
-------
Project 1-627-008
GCA Control No.
DATA REPORT SHEET
Additional Compounds
Sample I.D.
LNVA-SL-ID
Sample Matrix Water
Instrument Finn MAT OWA
Analysis Date
Sample Dilution
42646
3/6/85
1:10
V— • *» • o •
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethyl )ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorodif luorome thane
Diethyl ether
Ethvl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
\* m A • o •
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propvl benzene
Tetrahydrofuran
Trichlorof luorome thane
1,1, 2-Trichloro-
1 , 2^2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND » < 30 ug/1
NA = Not analyzed by Purge and Trap
K = Quantitation below detection limit
B-48
GCA
C,CA CORP ::><-" •
Technology Division
-------
Project 1-627-008
GCA Control No. 42651
DATA REPORT SHEET
Purgeables
Sample I.D.
LNVA-EQ-1C
Analysis Date 03/04/85
Sample Matrix
Water
Instrument HP5985 GC/MS
Sample Dilution 1;50 PT
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chloromethane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethy lene
1 , 1-Dichloroethane
Trans-1 / 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1 f 1 , 1-Trichloroethane
Carbon tetrachloride
Bromodi chloromethane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
5550
1700
ND
ND
ND
ND
200
1600
ND
ND
ND
350
i«* • A • o •
Number
79-34-5
78-87-5
10061-2-6
79^01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethvlene
Dibromechloromethane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methyl-2-pentanone (MIBK)
Tetrachloroe thy lene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
sqnn
ND
ND*
ND
ND*
ND
iqsn
ND
250
ND
PT = Purge and Trap
DI = Direct Injection
ND - < 150 ug/1
ND* - <250 ug/1
K = Quantitation below detection limit
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows: ortho- 95-47-6, meta- 108-38-3, para- 106-42-3
B-49
GCA
GCA CORPOR-Ti.":i':
Technology Divisioi
-------
Project 1-627-008
GCA Control No. 42651
DATA REPORT SHEET
Additional Compounds
Sample i.p. LNVA-EQ-1C
Sample Matrix Water
Instrument HP5985 GC/MS
Analysis Date 03/04/85
Sample Dilution 1;50 PT
C.A.S.
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis ( chloromethvl )ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorodif luorome thane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luorome thane
1,1,2-Trichloro-
1,2, 2-trif luoroethane
1 , 1 , 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND - < 150 ug/1
NA «* Not analyzed by Purge and Trap
K = Quantitation below detection limit
B-50
GCA
OCA conpon-'.:.- '
Technology Division
-------
Project 1-627-008
GCA Control No. 42654
DATA REPORT SHEET
Purgeables
Sample T.D.
LNVA-EQ-1C
Analysis Date 03/04/85
Sample Matrix Water
Instrument HP5985 GC/MS
Sample Dilution 1:50 PT
{*> • /» • t> •
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chloromethane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethy lene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodi chloromethane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
1100
1200
ND
ND
ND
ND
250
2700
ND
ND
ND
800
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethvlene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methyl-2-pentanone (MIBK)
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
7350
ND
ND*
ND
1000
ND
3750
ND
ND
PT = Purge and Trap
DI = Direct Injection
ND = < 150ug/l
ND* = <500 ug/1
K = Quantitation below detection limit
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows: ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-51
•^^ •^•»- ^^^—
GCA
GCA
Technology Divisioi
-------
Project 1-627-008
GCA Control No. 42654
DATA REPORT SHEET
Additional Compounds
Sample i.p. LNVA-EQ-1G
Sample Matrix Water
Instrument HP5985 GC/MS
Analysis Date
03/04/85
Sample Dilution 1:50 FT
V* • *\ • O •
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethyl )ether
Cyclohexane
Cyclohexanone
1, 2-Dibromoethane
Dichlorodif luorome thane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrof uran
Trichlorof luorome thane
1,1,2-Trichloro-
lj 2 ^2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND « < 150 ug/1
NA = Not analyzed by Purge and Trap
K = Quantitation below detection limit
B-52
GCA
GCA CORPORA;, r.
Technology Division
-------
Project 1-627-008
GCA Control No.
42659
DATA REPORT SHEET
Purgeables
Sample I.D.
LNVA-EQ-1M
Analysis Date 03/04/85
Sample Matrix Water
Instrument HP5985 GC/MS
Sample Dilution 1;50 PT
\* • /» • o •
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Ch lor ome thane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , l-Dichloroeth^lene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1 f 1 , 1-Trichloroethane
Carbon tetrachloride
Bromodichlorome thane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
2100
ND
ND
ND
ND
ND
250
2200
ND
ND
ND
450
^— • A • o •
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethvlene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methvl-2-pentanone (MIBK)
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
ND
ND
ND*
7350
ND*
ND
3050
ND
350
ND
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows:
ND = < 150 ug/1
ND* - < 250ug/1
K = Quantitation below detection limit
ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-53
GCA
GCA
Technology Divisioi
-------
Project 1-627-008
GCA Control No. *2659
DATA REPORT SHEET
Additional Compounds
Sample I.D. LNVA-EQ-IM
Sample Matrix Water
Instrument HP5985 GC/MS
Analysis Date 03/04/85
Sample Dilution
1:50 PT
**~r • «* • & •
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethyl )ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorodif luoromethane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate'
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luoromethane
1,1,2-Trichloro-
1,2, 2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT - Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND = < 150 ug/1
NA = Not analyzed by Purge and Trap
K ~ Quantitation below detection limit
B-54
GCA
GCACORPOR-". '.
Technology Division
-------
Project 1-627-000
GCA Control No. 42696
DATA REPORT SHEET
Purgeables
Sample I.D.
M-API-1C
Analysis Date 03/04/85
Sample Matrix
Water
Instrument IIP5985 GC/MS
Sample Dilution 1;200.PT
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chloromethane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1, 1 Ll-Tri chloroethane
Carbon tetrachloride
Bromodi chloromethane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
1600
3200
ND
ND
ND
ND
ND
25200
ND
ND
ND
3800
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
I(lr2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropvlene
Trichloroethylene
Dibromechlorome thane
Benzene
cis-1, 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methyl-2-pentanone (MIBK)
Tetrachloroethylene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
1800
ND
ND*
ND
ND*
ND
2 f> 00
ND
ND
ND
PT = Purge and Trap
DI = Direct Injection
ND « < 600 ug/1
ND* » < 1000 ug/1
K = Quantitation below" detection limit
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows: ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-55
^•^ ^ffr •«•••
GCA
GCA
Technology Divisioi
-------
Project 1-627-008
GCA Control No. 42696
DATA REPORT SHEET
Additional Compounds
Sample I.D.
M-API-1C
Sample Matrix Water
Instrument HP5985 GC/MS
Analysis Date 03/04/85
Sample Dilution 1;200 FT
v* • A • o •
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethyl )ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorodif luorome thane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate1
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trich lor of luorome thane
1, 1,2-Trichloro-
lj 2 i2-trif luoroethane
1 , 1 , 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND » < 600 ug/1
NA = Not analyzed by Purge and Trap
K = Quantitation below detection limit
B-56
GCA
GCA CORKMV'!••.'.':
Technology Division
-------
Project 1-627-008
GCA Control No.
42696
DATA REPORT SHEET
Purgeables
Sample I.D.
M-API-1C
Analysis Date_
03/21/85
Sample Matrix Hater
Instrument IIP5985 GC/MS
Sample Dilution 1:200
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chloromethane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1 , 1 , 1-Trichloroethane
Carbon tetrachloride
Bromodi chloromethane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
2800
ND
ND
ND
ND
ND
600
27600
ND
ND
ND
ND
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 i 2-Dichloropropane
Trans-1 , 3-dichloropropvlene
Trichloroethvlene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methyl-2-pentanone (MIBK)
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
61200
ND
ND*
ND
ND*
ND
1800
ND
ND
ND
PT = Purge and Trap
DI = Direct Injection
ND = < 600 ug/1
ND* = <1000 ug/1
K = Quantitation below detection limit
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows: ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-57
^4^- ^M*- MHMft
GCA
GCA
Technology Divisioi
-------
Project 1-627-008
GCA Control No.
42696
DATA REPORT SHEET
Additional Compounds
Sample I.D.
H-API-1C
Sample Matrix Water
Instrument HP5985 GC/MS
Analysis Date 03/21/85
Sample Dilution 1;200
C.A.S.
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethvl ) ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorodif luorome thane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetralvydrof uran
Trichlorof luorome thane
1,1,2-Trichloro-
It2f 2-trif luoroe thane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
MA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND = <600 ug/l
NA = Not analyzed by Purge and Trap
K = Quantitation below detection limit
B-58
GCA
GCA CORPORA'.-'I-
Technology Division
-------
Project 1-627-008
GCA Control No. 42700
DATA REPORT SHEET
Purgeables
Sample I.D.
H-API-2C
Analysis Date 03/04/85
Sample Matrix Water
Instrument HP5985 GC/MS
Sample Dilution 1:100 FT
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Ch lor ome thane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1 , 1^ 1-Trichloroethane
Carbon tetrachloride
Bromodichloromethane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
1400
1600
ND
ND
ND
ND
ND
24400
ND
ND
ND
1200
V-* • /V • b •
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
li lj 2 , 2-Tetrachloroethane
1 i 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethvlene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methyl-2-pentanone (MIBK)
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
2800
ND
ND*
ND
ND*
ND
4700
ND
1100
ND
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows
ND = < 300 ug/1
ND* = < 500 ug/1
K = Quantitation below detection limit
ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-59
•*mr ^mr «M«I»
GCA
GCA conpon-'-r.,1!:
Technology Divisioi
-------
Project 1-627-008
GCA Control No.
42700
Sample I.D.
M-API-2C
Sample Matrix
Water
DATA REPORT SHEET
Additional Compounds
Instrument HP5985 GC/MS
Analysis Date
03/04/85
Sample Dilution 1'IOQ
C.A.S.
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Ally! Alcohol
Bis (chloromethvl lether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorodif iuoromethane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75^-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate-
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrof uran
Trichlorof Iuoromethane
1,1,2-Trichloro-
1,2, 2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND = < 300 ug/1
NA =» Not analyzed by Purge and Trap
K » Quantitation below detection limit
B-60
GCA
GCA CORPORA; i ::•!
Technology Division
-------
Project 1-627-008
GCA Control No. 42705
DATA REPORT SHEET
Purgeables
Sample I.D,
Sample Matrix_
PEG
Instrument HP5985 GC/MS
Analysis Date Q2/15/B5
Sample Dilution i;50Q PT
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chi or ome thane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Tri chloroethane
Carbon tetrachloride
Bromodich lor ome thane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
ND
ND
ND
ND
ND
ND
890 K
ND
ND
ND
ND
260,000
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1 , 1, 2j 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethvlene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methyl-2-pentanone (MIBKL
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
9500
ND
ND*
ND
ND*
ND
96,000
ND
220,000
ND
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND «* <1500 ug/1
ND* " OOOO ug/1
K = Quantitation below detection limit
*C.A.S. Numbers for xylene isomers are as follows: ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-61
-^^- ^v *mmim
GCA
Technology Divisioi
-------
Project 1-627-008
GCA Control No. 42705
DATA REPORT SHEET
Additional Compounds
Sample I.D.
M-BPF-1D
Sample Matrix PEG
Instrument IIP5985 GC/MS
Analysis Date 02/15/05
Sample Dilution 1;500 PT
Vrf • f\ • O «
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethyl )ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorodif luorome thane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propvl benzene
Tetrahydrofuran
Trichlorof luorome thane
1,1,2-Trichloro-
lj 2 , 2-trif luoroethane
1 , 1 , 1-Tr if luoroe thane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND » <1500 Ug/l
NA e Not analyzed by Purge and Trap
K = Quantitation below detection limit
B-62
~^r- -*^r m i
GCA
GCA CORPORA!OH
Technology Division
-------
Project^1-627-008
GCA Control No. 42708
DATA REPORT SHEET
Purgeables
Sample I.D.
M-DAF-1C
Analysis Date 03/04/85
Sample Matrix
Water
Instrument HP5985 GC/MS
Sample Dilution l£20p_PT
l*> ft /\ • O •
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chlorome thane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodi ch lor ome thane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
1200
2600
ND
ND
.1 ND
ND
ND
40800
ND
ND
ND
ND
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropvlene
Trichloroethvlene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichlorqpropylene
2-Chloroethylvinylether
Bromoform
4-Methyl-2-pentanone (MIBK)
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
«
Concentratio
(ug/1)
ND
ND
ND
ND
ND
2800
ND
ND*
ND
ND*
ND
3600
ND
800
ND
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows
ND = < 600 ug/1
ND* = < 1000 ug/1
K = Quantitation below detection limit
ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-63
-^^T ~^mr m^^mm
GCA
GCA coRPon-r.;:-r:
Technology Divisioi
-------
Project 1-627-OOa
GCA Control No. 42708
DATA REPORT SHEET
Additional Compounds
Sample I.D,
M-DAF-1C
Sample Matrix Hater
Instrument HP5985 GC/MS
Analysis Date
03/04/85
Sample Dilution *;200
C.A.S.
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethyl )ether
Cyclohexane
Cyclohexanone
1 / 2-Dibromoethane
Dichlorodif luorome thane
Diethyl ether
Ethvl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
. 76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luoromethane
1,1,2-Trichloro-
1 , 2 1 2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND = < 600 ug/1
NA = Not analyzed by Purge and Trap
K « Quantitation below detection limit
B-64
GCA
GCACOnPOFPiiOi;
Technology Division
-------
Project 1-627-008
GCA Control No.
42708
DATA REPORT SHEET
Purgeables
Sample I.D.
M-DAF-1C
Analysis Date 03/21/85
Sample Matrix Water
Instrument HP5985 GC/MS
Sample Dilution 1:200
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chloromethane
Dromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethylene
1 , 1-Dichioroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodi chloromethane
Total xylenes
Concentration
(ug/1)
ND*
NO'
ND*
ND
1200
12800
ND
ND
ND
ND
ND
40000
ND
ND
ND
ND
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1^1 t 2 t 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropvlene
Trichloroethylene
Dibromechlorome thane
Benzene
cis-1, 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methvl-2-pentanone (MIBK)
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
1600
ND
ND*
ND
ND*
ND
2400
ND
600
ND
PT = Purge and Trap
DI = Direct Injection
ND = < 600 ug/1
ND* = < 1000ug/l
K = Quantitation below detection limit
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows: ortho- 95-47-6, meta- 108-38-3, para- 106-42-3
B-65
•^IV ^**r «™—
GCA
GCA
Technology Divisioi
-------
Project 1-627-008
GCA Control No.
42708
DATA REPORT SHEET
Additional Compounds
Sample I.D.
M-DAF-1C
Sample Matrix
Water
Instrument HP5985 GC/MS
Analysis Date
03/21/85
Sample Dilution 1;20°
C.A.S.
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethyl ) ether
Cyclohexane
Cyclohexanone
1 , 2-bibromoethane
Dichlorodif luorome thane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
. ND
NA
{-* • A • o •
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luorome thane
1,1,2-Trichloro-
It2j2-trif luoroethane
1, 1/1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 » ppb (for density of water)
ND = < 600 ug/1
NA = Not analyzed by Purge and Trap
K = Quantitation below detection limit
B-66
•^HT- -^mr i " i •i" '
GCA
. .
Technology Division
-------
Project^1-627-000
GCA Control No.
42712
DATA REPORT SHEET
Purgeables
Sample I.D.
H-PB-1C
Analysis Date
03/04/85
Sample Matrix
Water
Instrument HP5985 GC/MS
Sample Dilution 1;50 FT
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chlorome thane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethy lene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodichlorome thane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
1050
1400
ND
ND
ND
ND
200
ND
ND
ND
ND
450
>-• • /\ • O •
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-lf 3-dichloropropylene
Trichloroethvlene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methyl-2-pentanone (MIBK)
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
11050
ND
ND*
ND
ND*
ND
2600
ND
400i
1000
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows
ND = < 150 ug/1
ND* = < 250 ug/1
K =* Quantitation below detection limit
ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-67
^w^ ^mr •••»•••
GCA
GCA c
Technology Divisioi
-------
Project 1-627-008
GCA Control No.
42712
DATA REPORT SHEET
Additional Compounds
Sample I.D.
M-PB-1C
Sample Matrix Water
instrument HP5985 GC/MS
Analysis Date 03/04/85
Sample Dilution *t50
C.A.S.
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethvl )ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorodif luorome thane
Diethyl ether
Ethvl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
< ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate1
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrof uran
Trichlorof luorome thane
1,1,2-Trichloro-
1,2, 2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT =
DI -
Purge and Trap
Direct Injection
ug/1 = ppb (for density of water)
ND « < 150 ug/1
NA =» Not analyzed by Purge and Trap
K « Quantitation below detection limit
B-68
GCA
GCACORPOR-Mi. '.'
Technology Division
-------
Project 1-627-008
GCA Control No. 42716
DATA REPORT SHEET
Purgeables
Sample I.D.
H-SB-1C
Analysis Date 03/04/85
Sample Matrix
Water
Instrument I1P5985 GC/MS
Sample Dilution 1;20 PT
*-» • f\ • «3 *
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chloromethane
Bromome thane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodi ch lor ome thane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
6640
860
ND
ND
ND
ND
ND
940
ND
ND
ND
400
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1 , 1^ 2 , 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropvlene
Trichloroethylene
Dibromechlorome thane
Benzene
cis-1 , 3-DichlorqpropyJ.ene
2-Chloroethylvinylether
Bromoform
4-Methyl-2-pentanone (MIBK)
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
2240
•ND
ND*
ND
ND*
ND
900
ND
100
260
PT = Purge and Trap
DI = Direct Injection
ND «= < 60 ug/1
ND* = < 100 ug/1
K = Quantisation below detection limit
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows: ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-69
-^•T- -^gr i i i IB
GCA
GCA conp>on-r.;.M:
Technology Divisioi
-------
Project 1-627-008
GCA Control No. 42716
DATA REPORT SHEET
Additional Compounds
Sample I.D.
M-SB-1C
Sample Matrix
Water
Instrument HP5985 GC/MS
Analysis Date
03/04/85
Sample Dilution ^20 PT
C.A.S.
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis(chloromethyl ) ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
DichiorodTf luorome thane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
< ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate-
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrof uran
Trichlorof luorome thane
1 , 1 , 2-Trichloro-
1 , 2 L2-trif luoroethane
1 / 1 , 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT » Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND « < 60 ug/1
NA = Not analyzed by Purge and Trap
K = Quantitation below detection limit
B-70
GCA
GCA
Technology Division
-------
Project
i;CA c,,,,^.,,. No.
DATA UKI'UKT SHKKT
M.-t ;ils
Sample I.D. M-I.'I.-^A
Import Hal.-;
Sample Matrix Bulk Solids
Element
ICA? Anal.vsis
Aluminum
Antiacny
Arsenic
Barium
Beryllium
Boron
Cuncencrat ion
f ' J JT / J* j
1 ^OM'lf^
<3.0a
•-3.0
94.3
1.79
27.5
Catlniura •()...
Calcium
Chromium
Cobalt
Corner
Iron
Lead
1130
57.3
5.68
n4.8
3910
6/.C!
Magnesium ' "
Mani!auti:!u
40.1
Molvbdeuitin
Nickel
Selenium
Silicon
130
21"
784
Silver -'0.6
Sod ium 3QCO
SLronLiuiu
Thallium
Tin
Ticaniun
Vanadium
Zinc
1U7
ioa
35.5)
471
310
119
Thsse vaiuejs sl'.uula ij'i crit'.«iJiircd s
-------
r • —
f Prcjac; 1~'J • '~^'-t> CCA Gmfr.il At,.
!>ATA KKI-JWT SHK.KT
Sample l.D. M-'-l- 1A UrjiofL 1).»Lt«
Sample Matrix Bulk SoTIds
I CAP Analvsis
Aluminum
Ancinanv
17000°
30a
Arsenic " "J'l
Bariun 24^
Beryllium
Boron
CaJaiura
Calziura
Ciironium
Cobalt
Conner
Iron
Lead
Magnesium
t.93
IS. 5
1.19
3970
1610
tO. 7
'.' 7(1
2000U
2snn
7'JUU
M.ineaiu::it» ^^
MoLvbde.itia
Nickel
S^lnniuw
Silicon
S i I vc r
Sod ium
II. 5
40.1
26-'
1000
-------
Project 1-627-QQ8
GCA Control No.
42719
DATA REPORT SHEET
Pesticides/PCBs
Sample I.D. M-UL-3A
Saaple Matrix Bulk
Analysis Dace 5-U-85
Instrument HP 5840A GC w/Ni6 ECD
Parameter
aldrin
o-BHC
E-3HC
e-BHC
Y-BKC
chlordane
4, A1 -ODD
4, A.1 -DDE
4, 4' -DDT
dieldrin
endosulfan I
endosulfan II
endosulfan aulfate
endrin
endria aldehyde
hentachlor
heotachlor eo oxide
tcxaohene
PC3-1016
PC3-1221
PC2-1232
PC3-1242
PC3-1248
PC3-125A
PC3-1260
Ion Used To
Quant itate
Concentration
( mg/kg )
ND
ND
ND
ND
ND
' <15
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
<5.0
ND*
ND*
ND*
ND*
ND*
<5.0
<5.0
Remarks
-
ND » <1-0 mg/kg
ND* = <15 mg/kg
B-73
GCA
.
Technology Division
-------
Project 1-627-008
GCA Control No. 42719A
DATA REPORT SHEET
Acid Extracables
Sample I.D. M-UL-3A
Analysis Date 4-6-85
Sample Matrix Water
Parameter
Phenol
2-Chlor onheno 1
2-Nitropheno 1
2 , 4-Dimethy Ipheno 1
2 ,4-Dichloropheno 1
4-Chloro-3-methy Ipheno 1
2,4, 6-Trichloropheno 1
2 ,4-Dinitropheno 1
2-Me thy 1-4 , 6-dini tr opheno 1
4-Nitropheno 1
Pentachloropheno 1
Instrument
CAS *
108-95-2
95-57-8
88-75-5
105-67-9
120-83-2
59-50-7
88-06-2
51-28-5
534-52-1
100-02-7
87-86-5
HP 5985A GC/MS
Concentration
nig/ kg
ND
ND
ND
ND
ND
ND
ND
ND*
ND*
ND*
ND*
ND =
-------
Project 1-627-008
GCA Control No. 42719BN
DATA REPORT SHEET
Base/Neutral Extractables
Sample I .P. M-UL-3A 1:250 dil Analysis Date,
Samole Matrix Water
CAS #
111-44-4
541-73-1
106-46-7
95-50-1
39638-32-9
621-64-7
67-72-1
98-95-3
78-59-1
119-91-1
120-83-1
91-20-3
87-68-3
91-58-7
131-11-3
208-96-8
606-20-2
83-32-9
121-14-2
84-66-2
86-73-7
7005-72-3
118-74-1
85r-01-8
120-12^7
84-74-2
129-00-0
95-68-7
91-94rl
56-55-3
218-01-9
117-81-7
117-84-0
205-99-2/207-08-9
50-32-8
193-39-5
53-70-3
191-24-2
Instrument HP
Parameter
Bis ( 2-Chloroethvl) ether
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
1 , 2-Dichlorobenzene
Bis(2-Chloroisopropyl)ether
N— nitrosodi— n— Drooylamine
Hexachloro ethane
Nitrobenzene
Isoohorone
Bis (-2-Chloroethoxv)methane
1 , 2 ,4-Trichlorobenzene
Naothalene
Hexachlorobutadiene
2-Chloronanhthalene
Dimethvl ohthalate
Acenaohthylene
2.6-Dinitrotoluene
Acanaothene
2 . 4-Dinitro to luene
Diethyl phthalate
Fluor ene
4-Chloroohenvl ohenvl ether
Hexachlorobenzene
Phenanthrene
Anthracene
Di-n-Butvl ohthalate
Pvrene
Butvl benzvl ahthalate
3,3'-Dichlorbenzidine
Benzo ( a) anthracene
Chrvsene
Bis (2-ethvlhexyl)T>htha late
Di-n-octvl ohthalate
5985 GC/MS
Concentration
ing/ kg
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
. ND
ND
ND
ND
ND
ND
ND
ND
ND
ND . .
380k
ND
ND*
ND
ND
ND
ND
Benzo(b)f luoranthene/Benzo(k)f luoranthene3 ND
Benzo(a)Pyrene
Indeno (1,2,3-cd) nyrene
Dibenzo ( a ,h) anthracene
Benzo(a,h,i)t>erylene
ND
ND*
ND*
ND*
ND =< 350 mg/kg ND* =< 700 mg/kg
aUnder the conditions stipulated by EPA Method 625 this compound pair cannot
be chromatographically resolved. The concentration reported reflects the total
of both isomers.
k present but below detection
B-75
GCA
GCA CORPORATION
Technology Division
-------
(JCA Concrol No.
DATA HKItiKT SHKKT
M':f..i! s
'If 20
Sample I.D. M-LI.-1A (S-4)
Sample Matrix SVL!
R-pocc Dace Q3/2S/85
Element
ICAP Analysis
Aluninum
Anciraonv
Arsenic
130003
94n
3']
Barium 2d9
Beryllium
Bo ron
4.50
IS. 8
Ccdmiura " I- /ft
Calcium kjiU
Chromiunt
Cob.ilC
Coooer
Iron
Lead
5760
fl.'i:'
336
13400
1400
11 '. fiu\
Miij'iiiiS nun •ii'i'ii
Manganese 296
Mo 1 v b cl e HUM ""0 . '\
Nickel
7i.l
Solenium 74
Silicon
•Silver
201
•-0./S
Sod ium 4400
Scrunciucn
Ttialliun
95.9
<3.0a
Tin 2>-^
'7 7
y .,_ - i : _ "*ifj
2 Luc
TlieiJC valuus shtml-l !n- con i; Itli; TIM! .si-jnl-qtuinclL,
ir.cerf'ir&nc^t; enryiinrL-n'o in ch«- .-m.-iJ VH Iw.
B-76
20 JO
ativ«.' d«:i% t,i» .severe macrix
^^!?ia Tfichnoinqy Division
-------
Project 1-627-008
GCA Control Me.
42720
DATA HEPORT SHEET
Sample I.D.
Sample Matrix
M-LL-1A
Soil Core
Headspace Analysis
Instrument HP5985 GC/MS
Analysis Date
2/20/85
Sample Dilution
C.A.S.
Number
74-87-3
74-83^9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chloromethane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
I Ll-Dichloroethvlene
1 tl-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Dutanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Dromodi ch lor ome thane
Total xylenes
Concentration
*C.A.S. Numbers for xylene isomers are as follows: ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-77
^^r ^t^ ™n«^
GCA
•VA coniv ••
Technology Divisioi
-------
Pro ject_
1-627-008
GCA Control No. 4272°
Sample I.D.
DATA REPORT SHEET
lleadapace Analysis
Additional Compounds
M-I.L-1A
Sample Matrix Soil Core
Instrument HP5985 GC/MS
Analysis Date 2/20/85
Sample Dilution
N/A
C.A.S.
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis ( chlorome thy 1 ) ether
Cyclohexane •
Cyclohexanone
1 , 2-Dibromoethane
Dichlorodif luorome thane
Diethyl ethor
Ethyl acetate
Ethyl acrylate
Concentration
(ug/8 )
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter-
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trich lor of luorome thane
1,1,2-Trichloro-
1,2, 2-trif luoroethane
1 , 1 , 1-Trif luoroethane
Concentration
(ug/ g)
ND
KD
ND
ND
ND
NU
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
ND o < S.Oug/g
"9/8
B-78
^*r ~^r " '
GCA
v./. coni'oc
Technology
-------
I—•»27-('i;K
Sample I.D. M-SL-IA (S-L)
OATA K!-:."Ui
2bO
Beryllium 4.34
Boron
9.26
Caiiuii.Kn * ' -IW
Calcium
Chromitua
Cobalt
Cooper
Iron
8660
22'JU
7.79
290
191UO
Lead 2100
Hucnesiiim
6900
110
Mann.ii'.sse -'-'•'
Molybdenum
Nickal
Selenium
SLLicun
U.7
46.0
3la
8A.S
Silver •:°-6
Sod ium
SLroncLum
Tliallium
Tin
Titanium
Vanadium
Zinc
a
These values siuji-.UI !>(.• ••mi:-:ii.k-ri.-d s«'tni -ti'i.-mr i t:if!v«» duf r<>
inter fv.-rc:it:i.::. i-tn-nMu:. ,-i i.-il ii: ! In- .-ui.il ys 1::.
B— 79 ^^'^i'^ik
r^r- A
( 7> ./ V
1500a
7S.6
•3.0J
22.3
24.2
fi3
1A20
:;c-vpro K.Tfri:-:
• ' . ' • H':': .l'-'-ili :fl
fociinoicgy Oivisicn
-------
Project 1-627-008
GCA Control Me.
42722
Sample I.D.
M-SL-1A
DATA REPORT SHEET
Headspace Analysis
2/20/85
Analysis Date
Sample Matrix
Soil Core
Instrument HP5985 GC/MS
Sample Dilution
N.A.
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chi or ome thane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethvlerfe
1 i 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodichlorome thane
Total xylenes
Concentration
(ug/g)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetra chloroe thane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethylene
Dibromech lor ome thane
Benzene
cis-1 , 3-Dichloropropvlene
2 -Chloroe thvlvinvle the r
Bromoform
4-Methyl-2-pentanone (MIBK)
Tetrachloroethylene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratic
(ug/g)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
< 5.0 ug/g
ug/g - ppb
*C.A.S. Numbers for xylene isomers are as follows: ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-80
GCA
••V:A conrv -
Technology Oivisioi
-------
Project 1-627-008
GCA Control No. 42722
DATA REPORT SHEET
lleadspace Analysis
Additional Compounds
Sample I.D.
M-SL-1A
Sample Matrix Soil Core
Instrument HP5985 GC/MS
Analysis Date 2/20/85
Sample Dilution
N/A
\-. • f\ 9 k3 •
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethvl )ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorod if luorome thane
Diethyl ethor
Ethyl acetate
Ethyl acrylate
Concentration
B-81
•^iV ~^BT m^^^~
GCA
'/./• conpor •
Technology Divisior
-------
Cf.'A Cotti.ru I MM.
llAf.A KKJUKT S1IKKT
M.-t :»!:;
Sample I.D. M-i:i.-lA -_(.£-
Sample Macri:; b'--il
I CAP Aaafvsls
AluBinun
Ancinonv
Arsenic
ifioeic3
3V'
32
Barium ™'3
Beryllium
Boron
Cadmium
C.ilcium
Chroaium
Cobalt
Coooer
Iron
La ad
4.78
10.')
1.19
•mo
2060
10.5
353
20,StK)
2300
H.l^iViS I urn /''Oil
•5O£
Mo Lvbdt;:tuiR
in. 7
NL-kel •/ilJ-:j
Selenium 27
Silicon ^22
Silver •'°-fl
Soti iurn
Scroncium
Thaliiun
Tin
Ticaniitm
Vjna-iium
1200a
SO.O
0.0"
23.4
35.3
78
zinc iaio
These values s>iu;u]J !)»• runs Idcrcd s«-'iri-qu;inc Lcac i vo due tn .scvcrti oacrl>:
incerfercncerf em-wmctTiMl in clu- an.ilysls.
B-82 Si? ^3?iA Technology Division
-------
Project 1-627-008
GCA Control Me.
42724
DATA KEPORT SHEET
Sample I.D.
M-UI.-1A
Sample Matrix
Soil Core
Iliindspace Analysis
Instrument HP5985 GC/MS
2/20/85
Analysis Date
Sample Dilution N.A.
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chlorome thane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodichlorome thane
Total xylenes
Concentration
(ug/g)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
- ND
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1 , 1 , 2 1 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1, 3 -dichloropropylene
Trichloroethylene
Dibromechlorome thane
Benzene
cis-1 f 3-Dichloropropylene
2-Chloroethvlvinylether
Bromoform
4-Methyl-2-pentanone (MIBK)
Tetrachloroethylene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratit
(ug/g )
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
< 5.0 ug/g
= ppb
*C.A.S. Numbers for xylene isomers are as follows: ortho- 95-47-6, meta- 108-38-3, para- 106-42-3
B-83
^mr ^i«r- ^»»
GCA
-A com\.-.
L Technology Divisioi
-------
Project 1-627-008
GCA Control No.
Sample I.D.
M-UI/-1A
Sample Matrix Soil Core
DATA REPORT SHEET
Headspace Analysis
Additional Compounds
Instrument HP5985 GC/MS
Analysis Date
2/20/85
Sample Dilution
N/A
C.A.S.
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethyl )ether
Cyclohexane
Cyclohexanone
1 , 2-Dibrombethane
Dichlorodif luorome thane
Diethyl ethor
Ethvl acetate
Ethyl acrylate
Concentration
(ug/g )
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luorome thane
1,1,2-Trichloro-
1 , 2 f 2-trif luoroethane
1 , 1, 1-Trif luoroethane
Concentration
(ug/g)
ND
ND
ND
N
ND
NP
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
ND = < 5.0 ug/g
"9/8 c ppb
B-84
GCA
'/./• CORPOF-'
Technology Divisior
-------
Project 1-627-OOB
»"" GCA Control No. 42435
DATA REPORT SHEET
Purgeables
FBB
Sample I.D. vnn nil585-.T
Analysis Date 3-18-85
Sample Matrix_
Water
Instrument HP5985 GC/MS
Sample Dilution
None
V* • t\ • t> •
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chi or ome thane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodichlorome thane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
ND
65
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethvlene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methyl-2-pentanone (MIBK)
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
ND
ND
ND*
HD
ND*
ND
ND
ND
ND
ND
PT = Purge and Trap
DI = Direct Injection
ND = < 3 ug/1
ND* = < 5 ug/1
K = Quantitation below detection limit
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows: ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-85
^S^- -*W cm I
GCA
GCA
Technology Dlvisioi
-------
Project 1-627-008
DATA REPORT SHEET
Additional Compounds
Sample I.D.
FBU 011585J
Sample Matrix Water
Instrument HP5985 GC/MS
GCA Control No. 42435
PUB
Analysis Date 3-18-85
Sample Dilution None
V-» • f\ • O •
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis(chloromethvl )ether
Cyclohexane
Cyclohexanone
1, 2-Dibromoethane
DJ chlorodif luoromethane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlor of luoromethane
1,1,2-Trichloro-
1,2, 2~trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND - < 3 ug/1
NA « Not analyzed by Purge and Trap
K = Quantitation below detection limit
B-86
GCA
GCA conron ••!.;'(
Technology Division
-------
Project 1-627-000
GCA Control No. 42795
DATA REPORT SHEET
Purgeables
Sample I.D. NR-CE-in
Analysis Date 03/20/85
Sample Matrix Water
Instrument IIP5985 GC/MS
Sample Dilution N°ne
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
PT a Purge
DI = Direct
Parameter
Chloromethane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodi ch lor ome thane
Total xylenes
2- Hexanone
and Trap
; Injection
Concentration
(ug/1)
ND*
ND
ND*
ND
31
155
ND
ND
ND
ND
115
ND
113
ND
8
ND
22
C A S
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1 , lj 2A2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethvlene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methyl-2-pentanone (MIBK)
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
1 ,2-Dlchloroethane
ND B < 3 ug/1
ND* <= < 5 ug/1
K = Quantitation below detec
Concentratio
(ug/1)
ND
9
ND
ND
ND
22
ND
ND*
ND
ND*
ND
5
5
ND
ND
144
tion limit
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows: ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-87
^•r^ ^V «•&•!••
GCA
GCA CORPGR--r. V
Technology Divisioi
-------
Project 1-627-008
GCA Control No. 42795
Sample I.D.
NH-CE-1U
Sample Matrix Water
DATA REPORT SHEET
Additional Compounds
Instrument HP5985 GC/MS
Analysis Date 03/20/85
Sample Dilution None
C.A.S.
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethvl Jether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Di chlorodif luoromethane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luoromethane
1,1,2-Trichloro-
1,2, 2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA r.
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 =» ppb (for density of water)
ND = < 3 ug/1
NA «» Not analyzed by Purge and Trap
K - Quantitation below detection limit
B-88
GCA
GCA
Technology Division
-------
Project 1-627-008
GCA Control No.
42798
DATA REPORT SHEET
Purgeables
Sample I.D.
N1J-CL-1C
Analysis Date 03/04/85
Sample Matrix Water
Instrument HP5985 GC/MS
Sample Dilution 1;20
v« • /» » & •
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
PT = Purge
DI = Direct
Parameter
Chloromethane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1 , 1 / 1-Trichloroethane
Carbon tetrachloride
Bromodi chloromethane
Total xylenes
and Trap
; Injection
Concentration
(ug/1)
ND*
ND
ND* ,
ND
500
ND
ND
ND
ND
ND
140
ND
ND
ND
ND
ND
t-t • /\ • O •
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-l| 3-dichloropropylene
Trichloroethylene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropylene
2-ChloroethylvinyJLether .
Bromoform
4-Methvl-2-pentanone (MIBK)
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
ND = < 60 ug/1
ND* » < 100 ug/1
K = Quantitation below detec
Concentratio
(ug/1)
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
18u
ND
2240
12060
tion limit
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows
ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-89
^M^- -^MC- •» '••
GCA
Technology Divisioi
-------
Project 1-627-008
GCA Control No.
42798
DATA REPORT SHEET
Additional Compounds
Sample I.D.
NB-CL-1C
Sample Matrix_
Water
Instrument HP5985 GC/MS
Analysis Date
03/0/1/85
Sample Dilution
v* » /\ * O •
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethvl )ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Di chlorodif luoromethane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luoromethane
1,1,2-Trichloro-
1 , 2 , 2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT *= Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND «= < 60 ug/1
NA = Not analyzed by Purge and Trap
K «= Quantitation below detection limit
B-90
<«av -^tf "ii
GCA
Technology Division
-------
Project 1-627-008
GCA Control No. 42802
DATA REPORT SHEET
Purgeables
Sample I.D.
NB-EQ-1C
Analysis Date 03/04/85
Sample Matrix
Water
Instrument HP5985 GC/MS
Sample Dilution_
1:20 PT
V-« • £\ * £> •
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chloromethane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodi chloromethane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
660
ND
ND
ND
ND
ND
220
ND
ND
ND
ND
ND
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 i 2-Dichloropropane
Trans-1 , 3-dichloropropvlene
Trichloroethvlene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methyl-2-pentanone (MIBK)
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
120
ND
1560
7180
PT = Purge and Trap
DI = Direct Injection
ND = < 60 ug/1
ND* » < 100 ug/1
K = Quantitation below detection limit
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows: ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-91
GCA
GCA CORPOn-TlGM
Technology Divisioi
-------
Project 1-627-008
GCA Control No.
42802
DATA REPORT SHEET
Additional Compounds
Sample i.D. ND-EQ-1C
Sample Matrix Water
Instrument HP5985 GC/MS
Analysis Date
03/04/85
Sample Dilution 1*20 FT
C.A.S.
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethyl)ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorodif luorome thane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
v* • *» • O •
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luorome thane
1,1,2-Trichloro-
1 , 2^2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND = < 60 ug/1
NA = Not analyzed by Purge and Trap
K •> Quantitation below detection limit
B-92
-^^- -^w HI i i
GCA
GCA CORPOH-MI; r
Technology Division
-------
Project 1-627-008
GCA Control No.
42807
DATA REPORT SHEET
Purgeables
Sample I.D.
NIJ-PP-1D
Analysis Pate 03/20/85
Sample Matrix Water
Instrument HP5985 GC/MS
Sample Dilution None
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chlorome thane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Tri chloroethane
Carbon tetrachloride
Br omodichl or ome thane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
ND
ND
ND
ND
ND
ND
8
ND
ND
ND
ND
ND
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethylene
Dibromechlorome thane
Benzene
cis-lL3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methyl-2-pentanone (MIBK)
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
ND
ND
ND
ND
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows:
ND = < 3 ug/1
ND* - < 5 ug/1
K = Quantitation below detection limit
ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-93
•^c^p- -^mr •*»*••
GCA
GCACORPOR-r-.V:
Technology Divisioi
-------
Project 1-627-OQ8
GCA Control No.
42807
DATA REPORT SHEET
Additional Compounds
Sample I.D.
NB-PP-1D
Sample Matrix Water
Instrument IIP5985 GC/MS
Analysis Date
03/20/85
Sample Dilution None
trf • A • o •
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis ( chloromethvl ) ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorod if luorome thane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrof uran .
Trichlorof luorome thane
1,1,2-Trichloro-
1,2, 2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI =» Direct Injection
ug/1 = ppb (for density of water)
ND • < 3 ug/1
NA «* Not analyzed by Purge and Trap
K = Quantitation below detection limit
B-94
^fff ~^mr «™i—»
GCA
GCA connoH••>;•: <:
Technology Division
-------
Pr oj ec t 1-627-008
GCA Control Ho. 42810
DATA REPORT SHEET
Pesticides/PCBs
Sample I.D. NB-CO-lA (S-5)
Sample Matrix Soil
Analysis Date 5-14-85
Instrument HP 5340A GC w/Ni63 ECD
Parameter
aldrin
c-BHC
E-BHC
-------
Project 1-627-008
GCA Control No.
42810-A
DATA REPORT SHEET
Acid Extracables
Sample I.D. NB-CO-lA C5-5) 1:5 dil
4-6-85
Sample Matrix Water
Parameter
Phenol
2-Chlorouhenol
2-Nitropheno 1
2 ,4-Dimethy Ipheno 1
2 ,4-Dichloropheno 1
4-Chloro-3-methy Ipheno 1
2,4,6-Trichlqrophenol
2,4-Dinitrophenol
2-Methyl-4,6-dinitrophenol
A-Nitrophenol
Pentachlorophenol
ND = < 1.5 mg/kg
ND* = < 7 mg/kg
Instrument HP
CAS *
108-95-2
95-57-8
88-75-5
105-67-9
120-83-2
59-50-7
88-06-2
51-28-5
534-52-1
100-02-7
87-86-5
.T
GCA
5985A GC/MS
Concentration
mg/kg
ND
ND
ND
ND
ND
ND
ND
ND*
ND*
ND*
ND*
GCA CORPORATION
Technology Division
-------
Project 1-627-008
GCA Control No.
42810 BN
DATA REPORT SHEET
Base/Neutral Extractables
Sample I.D. NB-CO-1A (5-5) I; 10 dil Analysis Date_i±!L
Sample Matrix Water Instrument HP 5985 GC/MS
CAS #
111-44-4
541-73-1
106-46-7
95-50-1
39638-32-9
621-64-7
67-72-1
98-95-3
78-59-1
119-91-1
120-83-1
91-20-3
87-68-3
91-58-7
131-11-3
208-96-8
606-20-2
83-32-9
121-14-2
84-66-2
86-73-7
7005-72-3
118-74-1
85-01-8
120-12r7
84-74-2
129-00-0
95-63-7
91r94rl
56-55-3
218-01r-9
117-81-7
117-84-0
205-99-2/207-08-9
50-32^8
193-39-5
53-70-3
191-24-2
Parameter Concentration
rag /kg
Bis (2-Chloroethvl) ether
1 ,3-Dichlorobenzene
1 ,4-Dzchlorobenzene
1 ,2-Dichlorobenzene
Bis (2-ChloroisoDrooyl) ether
N-nitrosodi-n-prooylamine
Hexachloroethane
Nitrobenzene
IsoTJhorone
Bis (-2-Chloroethoxv)methane
1 , 2 ,4-Trichlorobenzene
Nanthalene
Hexachlorobutadiene
2-Chloronanhthalene
Dimethvl phthalate
Acenanhthvlene
2 . 6-Dinitro to luene
Acenaothene
2,4-Dinitrotoluene
Diethvl uhthalate
Fluorene
4-ChloroD*nenvl ohenyl ether
Hexachlorobenzene
Phenanthrene
Anthracene
Di-n-3utvl ohthalate
Pyrene
Butvl benzyl ohthalate
3,3'-Dichlorbeazidine
Benzo ( a ) anthracene
Chrysene
Bis(2-ethylhexvl)ohthalate
Di-n-octyl ohthalate
Benzo (b)fluoranthene/Benzo(k)fluoranthenea
Benzo ( a ) P-nrene
Indeno( l,2,3-cd)ovrene
Difaenzo ( a . h) anthracene
Benzo ( e , h , i) nervlene
HD
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND .
ND
ND
ND*
ND
ND
ND
ND
ND
ND
ND*
ND*
ND*
ND =< 7 mg/kg ND* =< 15 mg/kg
aUnder the conditions stipulated by EPA Method 625 this compound pair cannot
be chromatographically resolved. The concentration reported reflects the total
of both isomers.
B-97
GCA
GCA COFFCRATiCN
Technology Division
-------
Project 1-627-008
GCA Control Me.
42810
DATA REPORT SHEET
Sample I.D.
NB-CO-1A
Hciadspace Analysis
Sample Matrix
Soil Core
Instrument HP5985 GC/MS
2/27/85
Analysis Date
Sample Dilution
N.A.
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chloromethane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodi chloromethane
Total xylenes
Concentration
(ug/g)
ND
ND
ND
ND
320
ND
ND
ND
ND
WD
ND
ND
ND
ND
ND
ND
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethylene
Dibromech lor ome thane
Benzene
cis-1, 3-Dichloropropylene
2-Chloroethvlvinvlether
Bromoform
4-Hethyl-2-pentanone (MIBK)
Tetrachloroethylene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratit
(ug/g)
ND
ND
ND
ND
ND
MD
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND = < 20ug/g
*C.A.S. Numbers for xylene isomers are as follows: ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-98
^••^ ^«B^F ^mmmm
GCA
.
Technology Divisioi
-------
Project
1-627-008
GCA Control No.
42810
Sample I.D.
NB-CO-1A
Sample Matrix
DATA REPORT
lleudspace Analysis
Add i t i ona1 Compounds
Analysis Date
Instrument HP5985 GC/MS
Sample Dilution
2/27/85
N/A
o .;-..£.
Number
75-05-3
107- lb -6
542-88-1
li 0-82-7
ica-94-i
1 '.-6-92 -4
~> ~ - ~> i - i
i - • 4 . D
61. -29-7
141-7&-6
140-88-5
Parameter
Acetonitri le
All_yl Alcohol
Bis Lchloromethyl lether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoe thane
Di ch] orod Lif iuororr.c thane
Diethyl tther
Ethyl «Tcetate
Ethyl acrylate
Concentration
( ug/g )
ND
ND
ND
ND
ND
HI)
C.A.S.
Number
98-C1-1
78-81-1
79-2 -9
r 67-5 -.1
79-4 -4
^71-3 -3
ND ! 103- 5-1
lib j 109- 9-9
ND 75-C --1
' "N'D ' "
76-12-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methy] acetate
Methyl alcohol
Methyl methacrylate
n-Dutyl alcohol
n-Propi'l benzene
Te t v a hyd r o f u r a n
Tr.i ohlorof luorome thane
1,1,2-Trichloro-
1,2, 2-tr.i.f 1 uoroethane
1 , 1 , 1-Trif luoroethane
Concentration
(ug/ g)
ND
CT
ND
K
!>'D
NT)
ND
ND
ND
ND
I ID
Concentrations based on a con.parison of the total ion -.roc. of the compound with that of the internal
standar f. .
ND = < 20 ucj/a
S = PPb
B-99
^Hf *«»^^ ••••••
GCA
(,( !• ViM! ' :
Technology Division
-------
Ci:A
ll.VIV. UK POUT KH.KHT
M.- till:;
rol Nn. 42H! 0
Sample I.D.
Sarsp 1 e Ma c r ix St-j I
Elets-jr.c
MK--Q-1A (S-51 . U.-p.nC D.it.- 03/2H/S5
l!iir»'i-ncr !;«-vcr«: m.icri.x
: I::.
B-100
A
Divisiofi
-------
Project 1-627-008
GCA Control No. 42663
DATA REPORT SHEET
Purgeables
Sample J.D.
TX-ll-C
Analysis Date 03/04/85
Sample Matrix_
Water
Instrument HP5985 GC/MS
Sample Dilution 1;5Q PT
C.A.S.
Number
'*J
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chloromethane
Bromomethane
Viny] Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Br omod i chl or ome thane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
1100
1200
ND
ND
ND
ND
250
6700
ND
ND
ND
900
C- • A • fc» •
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1 , 1 , 2j 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1/ 3-dichloropropylene
Trichloroethvlene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromof orm
4-Methyl-2-pentanone (MIBK)
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
5400
ND
ND*
ND
ND*
ND
4250
ND
550
ND
PT = Purge and Trap
DI » Direct Injection
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows:
ND » < 150 ug/1
ND* " < 500 ug/1
K *» Quantitation below detection limit
ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
^•^ ^^ ^^^^
GCA
GCA
Technology Divisioi
B-101
-------
Project 1-627-008
GCA Control No. 42663
Sample I.D.
TX-ll-C
Sample Matrix Water
DATA REPORT SHEET
Additional Compounds
Instrument HP5985 GC/MS
Analysis Date
03/04/85
Sample Dilution 1;50 PT
C.A.S.
Number
75-05-8
107-18-6
542-88-1.
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bi s (chloromethyl )ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorodif luorome thane
Diethyl ether
Ethvl acetate
Ethyl acrylate
Concentration
(ug/1)
ND.
NA
ND
ND
ND
ND
ND
ND
ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate-
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luorome thane
1 , 1 , 2-Trichloro-
l±2 , 2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND « < 150 ug/1
NA » Not analyzed by Purge and Trap
K « Quantitation below detection limit
^H^ -^y .••••
GCA
GCA CORPORA !iOi:
Technology Division
B-102
-------
Project 1-627-000
GCA Control No. 42667
DATA REPORT SHEET
Purgeables
Sample I.D.
TX-APT-1C
Analysis Date
03/04/85
Sample Matrix
Water
Instrument HP5985 GC/MS
Sample Dilution 1;1000 FT
v^ • /» • O •
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
PT = Purge
DI = Direct
Parameter
Chlorome thane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon dasulfide
1 , 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodichlorome thane
Total xylenes
and Q'rap
: Injection
Concentration
(ug/1)
ND*
ND
ND*
ND
3000
12000
ND
ND
ND
ND
3000
ND
ND
ND
ND
ND
• C* • /V • o •
Number
79-T34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethylene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methyl-2-pentanone (MIBK)
Tetrachloroethylene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
ND = < 3000 ug/1
ND* » < 5000 ug/1
K = Quantitation below detec
Concentratio
(ug/1)
ND
ND
ND
ND
ND
i2nnn
ND
ND*
ND
ND*
ND
•wnn
wn
ND
ND
:tion limit
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows: ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
^u*- ~*mr HI
GCA
GCA CORPOR-r,.>:
Technology Dlvisioi
B-103
-------
Project 1-627-OOe
GCA Control No. 42667
DATA REPORT SHEET
Additional Compounds
Sample J.D. TX-APT.-1C
Sample Matrix
Water
Instrument HP5985 GC/MS
Analysis Date
03/04/85
Sample Dilution 1:1000 PT
V- • *» • t) •
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethvl )ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Di chlorodif luoromethane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
v<* • *» • t> •
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luoromethane
1,1,2-Trichloro-
lj 2 r 2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND » <3000 ug/1
NA » Not analyzed by Purge and Trap
K ** Quantitation below detection limit
B-104
^U*r- -^vr «H^M
GCA
GCA CORPORA •:".»;
Technology Division
-------
Project 1-627-008
GCA Control No. 42671
Sample I.D. TX-API-2C
Sample Matrix
PEG
DATA REPORT SHEET
Additional Compounds
Instrument HP5985 GC/MS
Analysis Date 5/13/8b
Sample Dilution ItlO.OOO
\~t * t\ • fa •
Number
75-05-8
107-18-6
K A o o n _ i
->«l/: — ob — 1
110-82-7
108-94-1
106-93-1
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Ally! Alcohol
ui s \ cnioromet nv i / etner
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorodif luoromethane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
xi i^
ML)
ND
ND
ND
ND
ND
ND
NA
C.A.S.
Number
98-01-1
•78-83-1
n a_o O — Q
/ y — /u— y
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
• ..i* . .
Meciiyj. aceuaue
Methyl alcohol
Methyl methacrylate
n-Dutyl alcohol
n-Propyl benzene
Tetrahydrof uran
Trichlorof luoromethane
1,1,2-Trichloro-
1,2, 2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
NL)
NA
ND
MA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND « <50000ug/l
NA ** Not analyzed by Purge and Trap
K = Quantitation below detection limit
Also tentatively .Identified In this sample were Isomers of other alky.l
\
B-105
benzenes.
GCA
no A connon •••:•.'«•
Technology Division
-------
Vroject 3-627-000
GCA Control Mo. 42671
DATA REPORT SHEET
Purgeables
Sample I.p. TX-API-2C
Analysis Date 5/13/85
Sample Matrix PRG
Instrument HP5985 GC/MS
Sample Dilution i
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Ch lor ome thane
Bromome thane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Pichloroethylene
1 jJL-nichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodichlorome thane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
480,000
• C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethylene
Dibromechlor ome thane
Benzene
cis-1 , 3-Dichloropropvlene
2-Chloroethvlvinvlether
Bromof orm
4-Methyl-2^pentanone (MIBK)
Tetrachloroethylene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
HD
ND
ND
ND
740,000
ND
ND*
ND
ND*
ND
240,000
___. ND.
S2d7ooo
ND
PT = Purge and Trap
DI = Direct Injection
ND « < 50,000
ND* » < 100,000
K •» Quantitation below detection limit
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows: ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-106
GCA
Technology Division
-------
Project^ 1-627-000
GCA Control No. 42672
DATA REPORT SHEET
Purgeables
Sample T.D. TX-AVT-2D
Analysis Date
03/0/./85
Sample Matrix Water
Instrument IIP5985 GC/MS
Sample Dilution None
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
PT = Purge
DI = Direct
Parameter
Chloromethane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroeth^lene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodi chloromethane
Total xylenes
and Trap
. Injection
Concentration
(ug/1)
ND*
ND
ND*
ND
ND
12
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethylene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichlorqpropylene
2-Chloroethylvinylether
Bromoform
4-Methvl-2-pentanone (MIBK)
Tetrachloroethylene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
ND «=• < 3 ug/1
ND* = < 5 ug/1
K *» Quantitation below detec
Concentratio
(ug/1)
ND
ND
ND
ND
ND
128
ND
ND*
ND
ND*
ND
T5
ND
ND
ND
tion limit
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows: ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-107
GCA
GCA CORPOR- :•.':•(:
Technology Divlsioi
-------
Project 1-627-008
GCA Control No.
42672
Sample T.D.
TX-APT-2D
Sample Matrix
Water
DATA REPORT SHEET
Additional Compounds
Instrument HP5985 GC/MS
Analysis Date
03/04/85
Sample Dilution None
>•* • *» • wl •
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chioromethyl Jether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Di chlorodif luoromethane
Diethyl ether
Ethvl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
HD
ND
NA
(•* • *» * o •
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luoromethane
1,1, 2-Trichloro-
1,2, 2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND « < 3 ug/1
NA - Not analyzed by Purge and Trap
K = Quantitation below detection limit
B-108
•^•v •• »"
GCA
.
Technology Division
-------
Project 1-627-008
GCA Control No. 42675
DATA REPORT SHEET
Purgeables
Sample I.D.
TX-ASW-2C
Analysis Date
3/7/85
Sample Matrix
Water
Instrument Finn MAT OWA
Sample Dilution
1:5
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chloromethane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodi ch 1 or ome thane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
380
94
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethylene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methvl-2-pentanone (MIBK)
Tetrachloroethylene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concer.tratio
(ug/1)
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
ND
ND
ND
ND
PT = Purge and Trap
DI «= Direct Injection
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows
ND = < 15 ug/1
ND* « <25 ug/1
K *» Quantitation below detection limit
ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-109
•^•^ -^mr- mmimtm
GCA
Technology Divisloi
-------
Project 1-627-008
GCA Control No. 42675
Sample I.D.
TX-ASW-2C
Sample Matrix Water
DATA REPORT SHEET
Additional Compounds
Instrument Finn MAT OWA
Analysis Date
Sample Dilution
3/7/85
1:5
w • ** \ »3 •
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethvl )ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorodif luoromethane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
\* • A » o •
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propvl benzene
Tetrahydrofuran
Trichlorof luoromethane
1,1,2-Trichloro-
I,2t2-trifluoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND = < 15 ug/1
NA = Not analyzed by Purge and Trap
K " Quantitation below detection limit
B-110
GCA
GCA
Technology Division
-------
Project. 1-627-008
GCA Control No. 42680
DATA REPORT SHEET
Purgeables
Sample I.D.
JL'XrCLCrllL
Analysis Date
3/7/85
Sample Matrix
Water
Instrument Finn MAT OWA
Sample Dilution
None
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chloromethane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethylene
1 , 1-bichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodi chloromethane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
ND
ND*
ND
ND
ND
ND
5.7
ND
ND
ND
ND
ND
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropvlene
Trichloroethvlene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methvl-2-pentanone (MIBK)
Tetrachloroethylene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
ND
ND
ND
ND
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows
ND e < 3 ug/1
ND* «= < 5 ug/1
K =' Quantitation below detection limit
ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-lll
~*mr •***• *m*^
GCA
Technology Divisioi
-------
Project 1-627-008
GCA Control No.
42680
DATA REPORT SHEET
Additional Compounds
Sample I.D.
TX-CT,C-I n
Sample Matrix Water
Instrument Finn MAT OWA
Analysis Date
Sample Dilution
3/7/85
None
Vrf • f\ t o •
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethyl )ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Di chlorodif iuoromethane
Diethyl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
. 75-69-4
76-13-1
420-26-2
Parameter
Furfural
iJCsobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof Iuoromethane
1,1,2-Trichloro-
1 , 2 ,'2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
ND = < 3 ug/1
NA « Not analyzed by Purge and Trap
K = Quantitation below detection limit
B-112
GCA
GCA C
Technology Division
-------
Project 1-627-008
GCA Control No. 42683
DATA REPORT SHEET
Purgeables
Sample I. D. TX-DD-1C
Analysis Date 03/04/85
Sample Matrix Water
Instrument HP5985 GC/MS
Sample Dilution 1;2000 FT
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Ch lor ome thane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodi chloromethane
Total xylenes
Concentration
(ug/1)
ND*
ND
ND*
ND
10000
30000
ND
ND
ND
ND
700000
ND
ND
ND
ND
ND
L* « f\ • O •
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethvlene
Dibromechlorome thane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methvl-2-pentanone (MIBK)
Tetrachloroethvlene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratio
(ug/1)
ND
ND
ND
ND
ND
ND
ND
ND*
ND
ND*
ND
480^0
ND
ND
ND
PT = Purge and Trap
DI = Direct Injection
ug/1 = ppb (for density of water)
*C.A.S. Numbers for xylene isomers are as follows
ND = <6000 ug/1
ND* = <10000ug/l
K =» Quantitation below detection limit
ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
^v -*mr •••••
GCA
GCACORPOR-M.'.f!
Technology Dlvisioi
B-113
-------
Project 1-627-OOB
GCA Control No. 42683
Sample I .p. TX-nn-ic
Sample Matrix Water
DATA REPORT SHEET
Additional Compounds
Instrument HP5985 GC/MS
Analysis Date
03/04/85
Sample Dilution 1;2000 PT
C.A.S.
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethvl )ether
Cydohexane
Cyclohexanone
1 , 2-Dibromoethane
Di chlorodif luoromethane
Diethyl ether
Ethvl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luoromethane
1,1, 2-Trichloro-
1 ,2j 2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT «= Purge and Trap
DI =» Direct Injection
ug/1 « ppb (for density of water)
ND » < 6000 ug/1
NA = Not analyzed by Purge and Trap
K '•* Quantitation below detection limit
GCA
GCA CORPORA;id:
Technology Division
B-114
-------
Project 1-627-008
GCA Control No. 42687
DATA REPORT SHEET
Purgeables
Sample I.D.
TX-V-1C
Analysis Date_
03/04/85
Sample Matrix_
Water
Instrument HP5985 GC/MS
Sample Dilution 1.-100 PT
C.A.S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chloromethane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-DichloroethyJLene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1 , 1 , 1-Trichloroethane
Carbon tetrachloride
Bromodi chloromethane
Total xylenes
Concentration
:
Technology Divisioi
B-115
-------
Project 1-627-008
GCA Control No. 42687
Sample I.D.
TX-V-1C
Sample Matrix Water
DATA REPORT SHEET
Additional Compounds
Instrument HP5985 GC/MS
Analysis Date
03/0/./85
Sample Dilution ItlOO PT
C.A.S.
Number
75-05-8
107-18-6
542-88-1.
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
All^l Alcohol
Bis (chloromethyl )ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichiorodif luoromethane
Diethvl ether
Ethyl acetate
Ethyl acrylate
Concentration
(ug/1)
ND
NA
ND
ND
ND
ND
ND
ND
ND
NA
L* • A • £> •
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate-
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran
Trichlorof luoromethane
1,1, 2-Trichloro-
1,2, 2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/1)
ND
NA
ND
NA
ND
NA
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
PT = Purge and Trap
DI » Direct Injection
ug/1 = ppb (for. density of water)
ND •- < 300 ug/1
NA •» Not analyzed by Purge and Trap
K ** Quantitation below detection limit
^mr «• ^™»«-
GCA
GCACORPOfV'SO:
Technology Division
3-116
-------
Project
»;s:A O
N. .
f'.-f .ils
Saatple I.D. TX-HI.-1A
Sample Matrix S!iu!>;o
Element
I CAP Ar.alrviLs
Aluminum
Antiiaonv
Arsenic
Barium
Borvllii-.i.i
i
Boron
Cadrai-jr.
C.i Icium
Chroni'i-i
Cobal:
Cooeor
Iron
L-=ad
Magnus iu-a
M.-1-iean.-w
Mol'/bd.^KIT.
Nick,: I
Sol«nuin
Silicun
Silver
S.,,|£
Scroncium
T'.ialliuci
TLr.
TLcar.i-ii-.
Vur.adi-.ira
Zinc
Koporc 0;ic- 3/2S/S5
ConceiiC ration
6100a
<3.0a
26
181
6.!1)
3.4')
1.33
yjyoo
IC'J
6fi.'4
1950
31500
1300
9700
340
--Q./.
21 J
I7a
io«;
0.7"9
jt-.r'
12?
<3.0a
23.0
7«.7
13
IU30
T.'.ese vaiuea slio'ilil bi: c.i.-irjiiltirn1.! s.-nil-qiuinC teat Lve due t«j severs: nacrL:c
Incorfercnc-'s c-m
in rli.- ;m;i lysis.
B-H7
»'«7^ '"^ \ '••••' -''" ;M'.!:' :f!
idf »fc'-£ak Technciogy Division
C-f"- A
-------
Project _ 1-627-0;)^
Sampl.- I.D. TX-3A-IA
CO\ Control No. 42091
DATA Hi !'H!:T SI1KMT
H"t I I •:
K.",u.t-i. Hal-
Sample MaCrLx So 11
Elomenc
(\tncenc ration
1CAP Analysis
Aluminum
Antiraonv
ArsenLc
R^r Itim
Beryllium
Boron
Cadniirs
Calciun
Chroniitra
Cohalc
C«/po^r
Iron
Lead
M:ii:n«iS Lum
Mnnirani::;^
Molybdenum
Nickel
Selenium
S i I icon
Si lv«r
Sod iu:ft
SLroncuii!*
T!ia 1 1 iua
Tin
Ticsniu:.'.
Vanadiuc
^ LUC
1 IO(JOn
<3.Qn
28
y^.s
7.uy
y.y
0.39'^
1 3COO
171
13.3
43i
33300
1200
3AOO
237
16.7
33.3
7.0n
443
--0.6
6:^)a
10«
<3.0;1
13.5
13.3
26
I !'.()
c valuer sliculJ '>« runsldurud .s«s:ii -qii.-iut t cnc i vt- dm- Co sov^re rancrix
?rffrrv«(T-:: rru-i-urti iT'-;i in l?n- ;ii:.i !•..-: i.-:.
B-118
Ti-clinoloqy Divi.sicn
-------
Project 1-627-008.
GCA. Control No. 42691 A
DATA REPORT SHEET
Acid Extracables
Sample I.D. TX-3A-1A 1:5 dil
4-6-85
Sample Matrix Water
Parameter
Phenol
2-Chloroohenol
2-Nitrophenol
2 .4-Dimethvlphenol
2 ,4-Dichloropheno 1
4-Chloro-3-methylphenol
2,4, 6-Tr ichloropheno 1
2 ,4-Dinitropheno 1
2-Methyl-4,6-dinitrophenol
4-Nitrophenol
Pentachloropheno 1
Instrument
CAS #
108-95-2
95-57-8
88-75-5
105-67-9
120-83-2
59-50-7
88-06-2
51-28-5
534-52-1
100-02-7
87-86-5
HP 5985A GC/MS
Concentration
m?/k?
ND
ND
ND
ND
ND
ND
ND
ND*
ND*
ND*
ND*
ND = < 7 mg/kg
ND* » < 35 mg/kg
B-119
GCA
GCA CORPORATION
Technology Division
-------
Project 1-627-008
GCA Control Ho..
DATA REPORT SHEET
42691 BN
Base/Neutral Extractables
Sample I.P. TX-3A-1A 1:250 dil Analysis Date.
4-6-85
Sample Matrix Water
CAS #
111-44-4
541-73-1
106-46-7
95-50-1
39638-32-9
621-64-7
67-72-1
98-95-3
78-59-1
119-91-1
120-83-1
91-20-3
87-68-3
91-58-7
131-11-3
208-96-8
606-20-2
83-32-9
121-14-2
84-66-2
86-73-7
7005-72-3
1187-74-1
85r-01-8
120-12-7
84-74-2
129-00-0
95-68-7
91-94-1
56-55-3
218-01-9
117-81-7
117T-84r-0
205-99-2/207-08-9
50r-32r-8
193-39-5
53-70-3
191-24-2
Instrument HP 5985 GC/MS
Parameter Concentration
mg/kg
Bis (2-Chloroethyl) ether
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
1 ,2-Dichlorobenzene
Bis (2-Chloroisopropyl) ether
N-nitrosodi-n-propylamine
Hexachloroe thane
Nitrobenzene
Isophorone
Bis (-2-Chloroethoxy )methane
1 ,2,4-Trichlorobenzene
Napthalene
Hexachloro butadiene
2-Chloronaphthalene
Dimethyl phthalate
Acenaphthylene
2 , 6-Dinitro to luene
Acenaothene
2, 4-Dinitro toluene
Diethvl phthalate
Fluor ene
4-Chlorophenyl phenyl ether
Hexach lorofaenzene
Phenanthrene
Anthracene
Di-n-Butyl phthalate
Pyrene
Butyl benzyl phthalate
3,3'-Dichlorbenzidine
Benzo ( a )anthracene
Chrysene
Bis(2-ethylhexyl)ohthalate
Di-n-octvl phthalate
Benzo(b)f luoranthene/Benzo(k)f luoranthenea
Benzo(a)Pyrene
Indeno( 1.2,3-cd)pvrene
Dibenzo(a.h)anthracene
Benzo (e.h.i)perylene
ND
ND
• ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND . . .
ND
ND
ND*
ND
ND
ND
ND
ND
ND
ND*
ND*
ND*
ND =< 350 mg/kg ND* =< 700 mg/kg
aUnder the conditions stipulated by EPA Method 625 this compound pair cannot
be chromatographically resolved. The concentration reported reflects the total
of both isomers.
B-120
GCA
GCA CORPGRAJOl
Technology Division
-------
Project 1-627-008
GCA Control Me.
42691
Sample I.D.
TX-3A-1A
DATA REPORT SHEET
lleadspace Analysis
2/20/85
Analysis Date
Sample Matrix
Soil Core
Instrument HP5985 GC/MS
Sample Dilution N.A.
C. A. S.
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Ch lor ome thane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 , 1-Di chloroethvlene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1,1, 1-Trichloroethane
Carbon tetrachloride
Bromodich lor ome thane
Total xylenes
Concentration
(ug/g)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1 ,1 , 2, 2 -Tetra chloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Tri chloroethvlene
Dibromech lor ome thane
Benzene
cis-1 , 3-Dichloropropylene
2-Chloroethvlvinvlether
Bromoform
4-Methyl-2-pentanone (MIBK)
Tetrachloroethylene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratit
(ug/g!
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
< 5.0 ug/g
= ppt>
*C.A.S. Numbers for xylene isomers are as follows: ortho- 95-47-6, meta- 108-38-3, para- 106-42-3.
B-121
^•nr- -*w <••••»
GCA
•,--A conn. •••
Technology Oivisic.i
-------
Project 1-627-OQ8
GCA Control No. *2691
Sample I.D.
TX-3A-1A
Sample Matrix Soil Core
DATA REPORT SHEET
Headspace Analysis
Additional Compounds
Instrument HP5985 GC/MS
Analysis Date 2/20/85
Sample Dilution
N/A
V* • f\ • O •
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
140-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis (chloromethvl )ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorod if luorome thane
Diethvl ether
Ethvl acetate
Ethyl acrylate
Concentration
(ug/g )
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
C.A.S.
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
,.}«
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrofuran -
Trichlorof luorome thane
1 , 1 , 2-Trichloro-
1,2, 2-trif luoroethane
1,1, 1-Trif luoroethane
Concentration
(ug/g)
ND
ND
ND
N
ND
NP
ND
ND
ND
ND
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
ND - < 5.0 ug/g
ppb
GCA
GCA CORPOR-"
Technology Division
-------
Project l-f;J7-r/i).°. CCA Control NM. 42>;V2
(IATA K'-.!'CJKT SHKKT
N..M a Is
Sample I.D. TX-3H-IA (S-S) R,-p:>rc n.-iie 03/2.3/85
Sanple Matrix Soil
... i!tnu:i*nrr;ic ion
Element , / ,
( US/R )
ICAF Ana'lyais
Aluninua l^OO'""
Antimony
Arsenic • 24
Barium 12'.'
Beryllium 7.15
Boron
Cadaiun O.Ml
C.ilciuui
Cliroaium
Cobalt
Coooer
Iron
990
Macnesium
315
Man«ane:;e
Molvbdenum 30.9
Nickel 74.8
Selenium
Silicon 271
Silver r.n
Strontiurr. 197
Thallium v^-
Tin
15.3
Titanium 5]. 5
Vanadium 33
Zinc 2270
These values s};
-------
Project 1-627-008
DATA REPORT SHEET
GCA Control Me.
42692
Sample I.D.
TX-311-1A
Sample Matrix
Soil Core
Ueadspace Analysis
Instrument HP5985 GC/MS
Analysis Date
2/20/85
Sample Dilution
*- . A . S .
Number
74-87-3
74-83-9
75-01-4
75-00-3
75-09-2
67-64-1
75-15-0
75-35-4
75-34-3
156-60-5
67-66-3
78-93-3
71-55-6
56-23-5
75-27-4
*
Parameter
Chloromethane
Bromomethane
Vinyl Chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1 tl-Dichloroethylene
1 , 1-Dichloroethane
Trans-1 , 2-dichloroethylene
Chloroform
2-Butanone (MEK)
1 , 1 i 1-Trichloroethane
Carbon tetrachloride
Bromodi chloromethane
Total xylenes
Concentration
(ug/g)
ND
ND
ND
ND
34
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
C.A.S.
Number
79-34-5
78-87-5
10061-2-6
79-01-6
124-48-1
71-43-2
10061-01-5
110-75-8
75-25-2
108-10-1
127-18-4
108-88-3
108-90-7
100-41-4
100-42-5
Parameter
1,1,2, 2-Tetrachloroethane
1 , 2-Dichloropropane
Trans-1 , 3-dichloropropylene
Trichloroethylene
Di bromech lor ome thane
Benzene
cis-1, 3-Dichloropropylene
2-Chloroethylvinylether
Bromoform
4-Methyl-2-pentanone (MIBK)
Tetrachloroethylene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Concentratit
(ug/g !
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
< 5.0 ug/g
e PPb
*C.A.S. Numbers for xylene isomers are as follows: ortho- 95-47-6, meta- 108-38-3, para- 106-42-3
B-124
~^r ~V WMK
GCA
•:,•"* conn: •
Technology
-------
Pro ject_
1-627-008
GCA Control No. /l2692
DATA REPORT SHEET
Headspace Analysis
Additional Compounds
Sample I.D.
TX-3B-1A
Sample Matrix Soil
Instrument HP5985 GC/MS
Analysis Date
2/20/85
Sample Dilution
N/A
C.A.S.
Number
75-05-8
107-18-6
542-88-1
110-82-7
108-94-1
106-93-4
75-71-8
60-29-7
141-78-6
14C.-88-5
Parameter
Acetonitrile
Allyl Alcohol
Bis ( chloromettivl ) ether
Cyclohexane
Cyclohexanone
1 , 2-Dibromoethane
Dichlorodif luorome thane
Diethvl ethor
Ethyl acetate
Ethyl acrylate
Concentration
( ug/g )
ND
No
ND
ND
ND
ND
ND
ND
ND
ND
v* • *\ • o •
Number
98-01-1
78-83-1
79-20-9
67-56-1
79-41-4
71-36-3
103-65-1
109-99-9
75-69-4
76-13-1
420-26-2
Parameter
Furfural
Isobutyl alcohol
Methyl acetate
Methyl alcohol
Methyl methacrylate
n-Butyl alcohol
n-Propyl benzene
Tetrahydrof uran -
Trichlorof luorome thane
1,1,2-Trichloro-
1,2, 2-trif luoroethane
1,1,1-Trifluoroethane
Concentration
(ug/g)
ND
ND
ND
N
ND
NP
ND
ND
ND
ND.
ND
Concentrations based on a comparison of the total ion area of the compound with that of the internal
standard.
ND • < S.Oug/g
ug/8
•^h^ "^HT «••••>
GCA
B-125
GCA CORPOR-'' '
Technology Division
-------
Project 1-627-008
GCA Control No.
42692 A
DATA REPORT SHEET
Acid Extracables
Sample I.D. TX-3B-1A 1:5 dil
4-6-85
Sample Matrix Water
Parameter
Phenol
2-Chlorocheno 1
2-Nitrophenol
2 ,4-Dinethylphenol
2,4-Dichlorophenol
4-Chloro-3-methylphenol
2,4,6-Trichlqrophenol
2,4-Dinitrophenol
2-Methyl-4,6-dinitrophenol
4-Nitrophenol
Pentachloropheno 1
Instrument
CAS #
108-95-2
95-57-8
88-75-5
105-67-9
120-83-2
59-50-7
88-06-2
51-28-5
534-52-1
100-02-7
87-86-5
HP 5985A GC/MS
Concentration
mg/kg
ND
ND
ND
ND
ND
ND
ND
ND*
ND*
ND*
ND*
ND = < 7 mg/kg
ND* = < 35 mg/kg
B-126
GCA
GCA CORPORATION
Technology Division
-------
?roject_
1-627-008
GCA Control No. *2692 BN
DATA REPORT SHEET
Base/Neutral Extractables
Sample I.D. TX-3B-1A 1:250 dil Analysis Date 4-6-85
Sample Matrix Water
Instrument HP 5985 GC/MS
CAS #
111-44-4
541-73-1
106-46-7
95-50-1
39638-32-9
621-64-7
67-72-1
98-95-3
78-59-1
119-91-1
120-83-1
91-20-3
87-68-3
91-58-7
131-11-3
208-96-8
606-20-2
83-32-9
121-14-2
84-66-2
86-73-7
7005-72-3
118^74-1
85-01-8
120-12r-7
84-74-2
129-00-0
95-68-7
91-94-1
56-55-3
218-01-9
117-81-7
117-84-0
205-99-2/207-08-9
50-32r8
193-39-5
53-70-3
191-24-2
Parameter Concentration
Bis (2-Chloroethyl) ether
1 ,3— Dichlorobenzene
1 ,4-Dichlorobenzene
1 ,2— Dichlorobenzene
Bis (2-Chloroisopropyl) ether
N— nit ro sod i—n— prop vlamine
Hexachloroethane
Nitrobenzene
Isophorone
Bis (-2-Chloroethoxv)methane
1 ,2.4-Trichlorobenzene
Naothalene
Hexachlorobutadiene
2-Chloronaphthalene
Dimethvl phthalate
Acenaphthylene
2, 6-Dinitro toluene
Acenaothene
2,4-Dinitrotoluene
Diethvl phthalate
Fluorene
4-Chlorophenyl phenvl ether
Hexachlorobenzene
Phenanthr ene
Anthracene
Di-n-3utvl phthalate
Pvrene
Butvl benzvl phthalate
3 ,3'-Dichlorbenzidine
Benzo(a)anthracene
Chrvsene
Bis (2-ethvlhexvl)phtha late
Di-n-octyl phthalate
Benzo(b)f luoranthene/Benzo(k)f luoranthenea
Benzo (a) Pvrene
IndenoC 1.2 ,3-cd)pvrene
Dibenzo(a,h)anthracene
BenzoCs ,h, i)perylene
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND . .
ND
ND
ND*
ND
ND
ND
ND
ND
ND
ND*
ND*
ND*
ND =< 350 mg/kg ND* =<:700 mg/kg
aUnder the conditions stipulated by EPA Method 625 this compound pair cannot
be chromatographically resolved. The concentration reported reflects the total
of both isomers.
B-127
GCA
GCA CORPORATION
Technology Division
-------
APPENDIX C
RCRA PART A PERMIT PROFILE SHEET
C-l
-------
U.S. ENVIRONMENTAL PROTECTION AGENCY, OFFICE OF SOLID HASTE
HAZARDOUS HASTE FACILITY PROFILE
PREPARED BY DEVELOPMENT PLANNIN0 AND RESEARCH ASSOCIATES, IHC. (DPRAI
DATA SOURCEt HWDM3 VERSIOH VZ IAS OP 27DEC04)
FOR FACILITY I TXD009792543, CIIEMALL INC
DATEI 06FEDOS
PAGE I 1
FACILITYl TX0009792S43
FACILITY INFORMATION
EPA IDENTIFICATION NUMBER I TX0009792543
FACILITY NAME! CIIEHALL INC
HAILING AUORESSl PO BOX 307
GROVES
EPA REGIONl
FACILITY OHNERi
TX 77619
06
CIIEHALL INC
PO BOX 309
GROVES
713/7E7-1471
. TX 7761?
CONTACT PERSON/TITLE!
CONTACT TELEPHONE I
ACTUAL ADDRESSi .
OWEN BEN L PLANT MANAGER
713/727-1471
SSOO Sll 366
PORT HECHES
TX 77651
FACILITY IS A NON-MAJOR HANDLER NOTIFIED WIDER RCRA.
FACILITY IS PRIVATE.
TSOF OHHER IS ALSO THE OPERATOR.
EXISTING FACILITY.
NATURE OF BUSINESS DESCRIPTION IS PRESENT.
713/727-1471
FACILITY OPERATOR! CIIEHALL INC
PO BOX 309
COUNTY! t45
LATITUDE i
LONGITUDE!
TX nm
MAP IS ACCEPTABLE.
DHAHING IS ACCEPTABLE.
PHOTOGRAPHS ARC ACCEPTABLE.
JEFFERSON
29-57-52.0
93-55-Z7.0
INDIAN LAND! NO
EXISTENCE! 17FEB78
CLOSURE! UNKNOWN DATE
LAST HWDHS UPDATE! 19NOV04
NOTIFICATION ACTIVITIES! GENERATION, TREATMENT/STORAGE/DISPOSAL.
SIC COOES!
(01) 2669 INDUSTRIAL ORGANIC CHEMICALS,
(02) 2992 LUBRICATING OILS AND CREASES
110,000.00 GALLONS.
METRIC TONS HASTE PROCESSESS
36.29 000 SOI
10.14 080 SOI
605.04 000 SOI T02
740.26
DESIGN CAPACITIES!
101) SOI CONTAINER
WASTESi
PI23
K049 SLOP OIL FH OILY HATER SEHER P
0002 NON-LISTED CORROSIVE HASTRES
MM FACILITY TOTAL MM
HASTES HITHOUT AMOUNTS OR PROCESSES!
U224
PHASE II VERIFICATION SURVEY!
HASTE PROCESS SIZES!
STORAGE CONTAINERS! UNKNOHN GALLONS.
THIS FACILITY HAS A TSD OR GENERATOR IN 1901.
HAZARDOUS HASTE GENERATED IN 19011 £0.00 TOH3.
THIS SITE DID HOT RECEIVE HAZARDOUS HASTES GENERATED BY OTHER FIRMS.
(02) TOE SURFACE IMPOUNDMENT
1,000.00 BALLONS/OAY.
DM13 DATAt
SICSi 2992
CALAORIAN INTERNATIONAL CORP
IIHV 366
PORT HECHES TX 776S1
BUSINESS LINE! MFRS LUBRICATING
PRINCIPAL OFFICER! BEN OHEN
PHONEi 713/727-1471
STARTED!
NET WORTH!
SALES!
EMPLOYEES!
UNKNOHN
UNKHOHH
UNKHOHII
10
*» NOTE! END OF REPORT FOR FACILITY! TXD009792543, CIIEMALL INC nit
-------
U.S. ENVIRONMENTAL PROTECTION AGENCY. OFFICE OF SOLID WASTE
HAZARDOUS WASTE FACILITY PROFILE DATE: 16MARB5
PREPARED BY DEVELOPMENT PLANNING AND RESEARCH ASSOCIATES. INC. (DPRA) PAGE: 1
DATA SOURCE: HWDMS VERSION VI US OF .) FACILITY! TXD04746B129
PHASE II VERIFICATION SURVEY:
WASTE PROCESS SIZES:
SURFACE IMPOUNDMENTS: 756.00 SQUARE YARDS.
STORAGE CONTAINERS: 2.750.00 GALLONS.
STORAGE TANKS: 50.000.00 GALLONS.
TREATMENT TANKS: 1.200.00 GALLONS.
THIS FACILITY WAS A TSD OR GENERATOR IN 1961.
HAZARDOUS WASTE GENERATED IN 1981: UNKNOWN TONS.
THIS SITE DID NOT RECEIVE HAZARDOUS WASTES GENERATED BY OTHER FIRMS.
«» NOTE: END OF REPORT FOR FACILITY: TXD04746fil29» «*
n
u>
-------
U.S. ENVIRONMENTAL PROTECTION AGENCY* OFFICE OF SOLID WASTE
HAZARDOUS HASTE FACILITY PROFILE
PREPARED BY DEVELOPMENT PLANNING AND RESEARCH ASSOCIATES, INC. (DPRA)
DATA SOURCE: HWDMS VERSION VI (AS OF 27DEC84)
FOR FACILITY! TX0008090409, GULF OIL COMPANY US PORT ARTHUR REFINERY
DATE: 1BMAR05
PAGEt 1
FACILITY! TX0008090409
O
FACILITY INFORMATION
EPA IDENTIFICATION NUMBERI TXOOOB090409
FACILITY NAME: GULF OIL COMPANY US PORT ARTHUR REFINERY
MAILING ADDRESSt PO BOX 701
PORT ARTHUR TX 77640
EPA REGION:
FACILITY OWNER:
CONTACT PERSON/TITLE:
CONTACT TELEPHONE:
ACTUAL ADDRESS:
G J WILSON JR
713/983-3301
WEST 7TH STREET
PORT ARTHUR
06
GULF OIL COMPANY-US
PO BOX 701
PORT ARTHUR
713/963-3301
FACILITY OPERATOR: GULF OIL COMPANY-US
PO BOX 701
TX 77640
FACILITY IS A NON-MAJOR HANDLER NOTIFIED UNDER RCRA.
FACILITY IS PRIVATE.
TSDF OWNER IS ALSO THE OPERATOR.
EXISTING FACILITY.
NATURE OF BUSINESS DESCRIPTION IS PRESENT.
MAP IS ACCEPTABLE. DRAWING IS ACCEPTABLE. PHOTOGRAPHS ARE ACCEPTABLE.
713/983-3301
TX 77640
TX
COUNTY: 245 JEFFERSON
LATITUDE t 29-51-00.0
LONGITUDE: 93-58-00.0
EXISTENCE: 01JAN02
CLOSURE: UNKNOWN DATE
LAST HWDMS UPDATE: 290CTB4
INDIAN LAND: NO
NOTIFICATION ACTIVITIES: GENERATION. TRANSPORTATION, TREATMENT/STORAGE/DISPOSAL.
TRANSPORTATION MODEIS)( RAIL, HIGHWAY, MATER.
SIC CODES:
(01) 2911 PETROLEUM REFINING
DESIGN CAPACITIES:
(01) SOI CONTAINER
(03) S04 SURFACE IMPOUNDMENT
(05) T02 SURFACE IMPOUNDMENT
151,668.00 GALLONS.
40,000,000.00 GALLONS.
17,280,000.00 GALLONS/DAY.
(02) S02 TANK STORAGE
(04) T01 TANK TREATMENT
(06) T04 OTHER TREATMENT
1,800,000.00 GALLONS.
8,640,000.00 GALLONS/DAY.
504,000.00 GALLONS/DAY.
WASTES:
U239 XYLENE
UZ26 1,1,1-TRICHLOROMETHANE «
U223 TOLUENE DIISOCYANATE
U220 TOLUENE
U211 .TETRACHLOROMETHAHE OR CARBON T
U166 PHENOL OR CARBOLIC ACID,HYDROX
U161 METHYL ISOBUTYL KETORE
U159 METHYL ETHYL KETONE
U154 METHANOL OR METHYL ALCOHOL
U144 LEAD ACETATE
U134 HYDROFLUORIC ACID (C,T)
U125 FURFURAL (I)
U117 ETHYL ETHER (I,T)
U056 CYCLOHEXANE(I)
U055 CUIIENE
NOTE: ONLY THE FIFTEEN LARGEST
METRIC TONS WASTE PROCESSESS
27.22 SOI T01 T02
27.22 SOI T01 T02
46.27 SOI T01 T02
27.22 SOI T01 T02
2.72 SOI T01 T02
27.22 SOI T01 T02
2.72 SOI T01 T02
27.22 SOI T01 T02
27.22 SOI TOl T02
0.14 SOI TO! T02
27.22 SOI TOl T02
27.22 SOI TOl T02
2.72 SOI TOl T02
27.22 SOI TOl T02
27.22 SOI TOl T02
WASTES ARE LISTED HERE.
»» INFORMATION FOR GULF OIL COMPANY US PORT ARTHUR REFINERY CONTINUED ON NEXT PAGE.
-------
U.S. ENVIRONMENTAL PROTECTION AGENCY, OFFICE OF SOLID WASTE
HAZARDOUS HASTE FACILITY PROFILE
PREPARED BY DEVELOPMENT PLANNING AND RESEARCH ASSOCIATES, INC. (DPRA1
DATA SOURCE: HWOMS VERSION VI (AS OF 27DEC84)
WASTES:
MM FACILITY TOTAL *M
WASTES WITHOUT AMOUNTS OR PROCESSES:
DOOO
PHASE II VERIFICATION SURVEY:
WASTE PROCESS SIZES:
STORAGE CONTAINERS:
STORAGE TANKS:
HAZARDOUS WASTE GENERATED IN 1981:
DUNS DATA:
SICS: 2911
GULF OIL CORP
WEST AVE & 7TH
PORT ARTHUR TX 77640
DATE: 16MAR85
PAGE: Z
FACILITY: TXD008090409
METRIC TONS WASTE PROCESSESS (CONTINUED FROM PREVIOUS PAGE)
2,897,041.07
55.00 GALLONS.
0.00 GALLONS.
UNKNOWN TONS.
BUSINESS LINE:
PRINCIPAL OFFICER:
PHONE:
PETROLEUM REFINE
G J WILSON JR MGR
713/983-3301
STARTED:
NET WORTH:
SALES:
EMPLOYEES:
UNKNOWN
UNKNOWN
UNKNOWN
3,500
MM NOTE: END OF REPORT FOR FACILITY: TXD008090409, GULF OIL COMPANY US PORT ARTHUR REFINERY **
-------
U.S. ENVIRONMENTAL PROTECTION AGENCY, OFFICE OF SOLID HASTE
HAZARDOUS HASTE FACILITY PROFILE
PREPARED BY DEVELOPMENT PLANNING AND RESEARCH ASSOCIATES, INC. (DPRA)
DATA SOURCES HWDM3 VERSION VI (AS OF 27DEC84)
FOR FACILITY! TXD990797714, I10DIL OIL CORP
DATE I 1BI1ARQ5
PAGEl 1
FACILITY: TX0990797714
FACILITY INFORMATION
EPA IDENTIFICATION NUMBER: TXD990797714
FACILITY NAME: MOBIL OIL CORP
MAILING ADDRESS: PO BOX 3311
BEAUMONT
EPA REGION:
FACILITY OUNER:
TX 77704
CONTACT PERSON/TITLE:
CONTACT TELEPHONE:
ACTUAL ADDRESS:
R G SANDERS MANAGER-COM3ERVATI
713/839-3328
END OP BURT STREET
BEAUMONT TX 77704
FACILITY IS A MAJOR HANDLER NOTIFIED UNDER RCRA.
FACILITY IS PRIVATE.
TSDF OUNER IS ALSO THE OPERATOR.
EXISTING FACILITY.
NATURE OF BUSINESS DESCRIPTION IS PRESENT. .
MAP IS ACCEPTABLE. DRAWING IS ACCEPTABLE.
NOTIFICATION ACTIVITIES: TREATMENT/STDRAGE/DISPOSAL.
06
MOBIL OIL CORPORATION BEAUMNT REFINERY
PO DOX 3311
BEAUMONT YX 77704
713/033-9411
FACILITY OPERATOR: MOBIL OIL CORPORATION BEAUMNT REFINERY
PO BOX 3311
???mm???mmtmm TX
713/633-9411
COUNTY: 245 JEFFERSON
LATITUDE I 30-04-05.0
LONGITUDES 94-03-34.0
EXISTENCE: 01MAY03
CLOSURE: UNKNOWN DATE
LAST HHDMS UPDATE: 12JAN84
PHOTOGRAPHS ARE ACCEPTABLE.
INDIAN LANDS NO
SIC CODES:
(01) 2911 PETROLEUM REFINING
DESIGN CAPACITIES:
(01) 080 LANDFILL
(031. SOZ TANK STORAGE
(051 TO I TANK TREATMENT
(071 T04 OTHER TREATMENT
(02) 2669 INDUSTRIAL ORGANIC CHEMICALS,
1,140.00 ACRE-FEET.
5,124,000.00 GALLONS.
34,606,000.00 GALLONS/DAY.
146,000.00 GALLONS/DAY.
(02) 001 LAND APPLICATION
(04) S04 SURFACE IMPOUNDMENT
(06) T02 SURFACE IMPOUNDMENT
54.00 ACRES.
666)000.00 GALLONS.
4,320,000.00 GALLONS/DAY.
HASTES: METRIC TONS
U239 XYIE1IE 0.32
U220 TOLUENE 6.62
U10B PHENOL OR CARBOLIC ACIDtHYOROX 0.01
U161 METHYL ISOBUTYL KETORE 0.15
UI59 METHYL ETHYL KETONE 5.35
U12S FURFURAL (I) 0.04
UQ44 CHLOROFORM!I,T) 0.01
U043 CHLOROETHENE OR VINYL CHLORIDE 0.26
U002 ACETONE (I) 1.32
K051 API SLUDGE FM API OILY SEWER P 5,443.20
K048 DAF FM OILY WATER SEWER PETRO 69,359.20
FOOl SPENT HALO CHLORIDES « SLUDGE 290.30
D002 NON-LISTED CORROSIVE WASTRES 23,042.86
0001 NON-LISTED IGIUTADLE WASTES 244.94
MM FACILITY TOTAL MM 118,396.59
WASTES WITHOUT AMOUNTS OR PROCESSES:
DOOO 0003 K049-KOSO KOS2 U054
WASTE PROCESSESS
S04 T01
S04 T01
S04 T01
S04 TO I
304 T01
S04 T01
S04 T01
S04 T01
S04 T01
DBO S04 T02
081 S02 T01 T04
S04 T01
S02 T01
D80
MM INFORMATION FOR MODIL OIL CORP CONTINUED ON NEXT PAGE.
-------
U.S. ENVIRONMENTAL PROTECTION AGENCY, OFFICE OF SOLID HASTE
HAZARDOUS HASTE FACILITY PROFILE
PREPARED BY DEVELOPMENT PLANNING AND RESEARCH ASSOCIATES. INC. (DPRAI
DATA SOURCE: HHDMS VERSION VI (AS OF E7DEC64)
HASTES WITHOUT AMOUNTS OR PROCESSES! (CONTINUED FROM PREVIOUS PAGE)
PHASE II VERIFICATION SURVEY!
HASTE PROCESS SIZES:
HAZARDOUS HASTE GENERATED IN 1961: UNKNOWN TONS.
MM NOTE: END OF REPORT FOR FACILITY: TXD990797714. MOBIL OIL CORP MM
DATE: 16MAR65
PAGE: 2
FACILITY: TXD990797714
n
i
-------
U.S. ENVIRONMENTAL PROTECTION AGENCY, OFFICE OF SOLID WASTE
HAZARDOUS HASTE FACILITY PROFILE
PREPARED BY DEVELOPMENT PLAMI I IMG AMD RESEARCH ASSOCIATES, INC. (DPRA)
DATA SOURCE I HWDM3 VERSION VI CAS OF 27DECB4)
FOR FACILITY! TX00000975Z9, TEXACO INC
DATEt 16MAR85
PAGEl 1
FACILITYt TXD0060975Z9
FACILITY INFORMATION
EPA IDENTIFICATION HUHQERt TX0008097529
FACILITY NAME: TEXACO INC
MAILING ADDRESSi PO DOX 712
PORT ARTHUR
EPA REGION!
FACILITY OWNER i
TX 77610
06
TEXACO USA
PO DOX 712
PORT ARTHUR
713/962-5711
TX 77640
CONTACT PERSON/TITLE:
CONTACT TELEPHONE:
ACTUAL ADDRESS:
MOHR 0 A
713/982-5711
WEST END OF HOUSTON AVE
PORT ARTHUR
FACILITY OPERATORI TEXACO USA
PO BOX 712
TX 77640
713/982-5711
FACILITY IS A MAJOR HANDLER NOTIFIED UNDER RCRA.
FACILITY IS PRIVATE.
TSDF OUNER IS ALSO THE OPERATOR.
EXISTING FACILITY.
NATURE OF BUSINESS DESCRIPTION IS PRESENT.
COUNTY: 245 JEFFERSON
LATITUDE t 29-53-14.0
LONGITUDE: 93-58-42.0
EXISTENCES
CLOSURE:
LAST HWOMS UPDATE:
TX ?????
07APR02
UNKNOWN DATE
20MOV84
MAP IS ACCEPTABLE.
DRAWING IS ACCEPTABLE.
PHOTOGRAPHS ARE ACCEPTABLE.
INDIAN LANDt NO
n
00
NOTIFICATION ACTIVITIES: GENERATION, TRANSPORTATION* TREATMENT/STORAGE/DISPOSAL.
TRANSPORTATION MODEtS): HIGHWAY.
SIC CODES:
(Oil 2911 PETROLEUM REFINING
DESIGN CAPACITIES:
(01) D80 LANDFILL
(03) SOI CONTAINER
(051 TOl TANK TREATMENT
3.00 ACRE-FEET.
11,000.00 GALLONS.
4,440,000.00 GALLONS/DAY.
(02) Dfll LAND APPLICATION
(04) S02 TANK STORAGE
(06) T02 SURFACE IMPOUNDMENT
10.00 ACRES.
4,000,000.00 GALLONS.
24,200,000.00 GALLONS/DAY.
WASTES:
U2ZO TOLUENE
U056 CYCLOIIEXANE(I)
PI 10 TETRAETIIYL LEAD
KOSZ BOTTOMS (LEADED) FM PETRO REFI
KOS1 API SLUDGE FM API OILY SEMER P
K050 PETRO REFIN EXC BUNDLE CLEANIN
K049 SLOP OIL FM OILY MATER SEIIER P
F017 PAINT RESIDUES GENERATED FROM
F003 NON-HALOGENATED SOLV t SOLV RE
FOOZ HALO SOLV AND SOLV REC STILL B
0011 SILVER
0007 CHROMIUM
0004 ARSENIC
D002 NUN-LISTED CORROSIVE WASTRES
DOOO NON-LISTED TOXIC WASTES
NOTE: ONLY THE FIFTEEN LARGEST
METRIC TONS WASTE PROCESSESS
45.36 TOl
45.36 TOl
9.07 T02
13.61 000 D8I 302 T02
76,204.60 TOl
235.67 TOl T02
743.90 DOO D01 S02 T02
9.07 SOI
4.54 060 SOI
4.54 DOO T02
0.00 DSO D81 SOI T02
1,179.36 030
0.00 060 061 SOI T02
72,576.00 TOl TOZ
5,445,177.70 DOO SOI T02
WASTES ARE LISTED HERE.
INFORMATION FOR TEXACO INC CONTINUED ON NEXT PAGE.
-------
HASTES:
«•* FACILITY TOTAL
U.S. ENVIRONMENTAL PROTECTION AGENCY, OFFICE OF SOLID HASTE
HAZARDOUS HASTE FACILITY PROFILE
PREPARED BY DEVELOPMENT PLANNING AND RESEARCH ASSOCIATES, INC. (DPRA)
DATA SOURCE: HWDMS VERSION VI (AS OF 27DEC84)
METRIC TONS WASTE PROCESSESS (CONTINUED FROM PREVIOUS PAGE)
5,596,249.16
DATEt 18MAR85
PAGE l Z
FACILITY: TXD008097529
WASTES WITHOUT AMOUNTS OR PROCESSES:
D001 D003 D005-D006 DOOO-0010 F005 U013 U019
PHASE II VERIFICATION SURVEYi
WASTE-PROCESS SIZES:
LANDFILL:
LAND TREATMENT AREA:
SURFACE IMPOUNDMENTS!
STORAGE TANKS:
TREATMENT TANKS:
HAZARDOUS WASTE GENERATED IN 1981:
DUNS DATA:
SICS: 2911
TEXACO INC
EIID OF HOUSTON AVE
PORT ARTHUR TX 77640
32,502.00 TONS.
38.00 ACRES.
14,352.00 SQUARE YARDS.
0.00 GALLONS.
0.00 GALLONS.
UNKNOWN TONS.
BUSINESS LINE:
PRINCIPAL OFFICER:
PHONE:
REFINING
DONALD L CHASE MGR
713/982-5711
STARTED:
NET NORTH:
SALES:
EMPLOYEES:
UNKNOWN
UNKNOWN
UNKNOWN
2,000
** NOTE: END OF REPORT FOR FACILITY! TXD008097529, TEXACO INC
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APPENDIX D
ANALYTICAL PROCEDURES
D-l
-------
ANALYTICAL PROCEDURES
Introduction
Representative aliquots for the analytical procedures described in this
section were obtained following the coning and quartering technique described
in ASTM D346-35 (Reference 1). As there was some concern about moisture loss
in the samples during the coning and quartering procedure, the sample weights
were measured before and after this process for weight loss. These
calculations indicated the weight loss to be negligible and most likely due to
the loss of sample during the procedure.
Trace Metals
The samples submitted for the determination of trace metals were prepared
according to the procedures described in EPA Method 3050 (Reference 2).
Quantitation was performed by inductively coupled argon plasma emission
spectrometry (ICAP) utilizing a Jarrel Ash Model 855 Atom Comp. Instrumental
Analysis was conducted according to the procedures outlined in EPA Method 6010
(Reference 2) and Section 10 of EPA Method 200.7 (Reference 3). Due to the
complex nature of the sample matrices, many problems were encountered during
the analysis. The values for aluminum, antimony, selenium, sodium and
thallium should be considered semi-quantitative as a result of these severe
matrix interferences.
Percent Solids
Determination of percent solids in the project samples was conducted
according to the protocol outlined in CRL Method 444 (Reference 4).
Percent Moisture
Percent moisture determinations followed the procedures discussed in CRL
Method 445 (Reference 4).
D-2
-------
Oil and Grease
Determination of oil and grease content in the submitted samples was
performed according to the procedures discussed in EPA Method 9071
(Reference 2).
Extractable Organics
Samples submitted for extractable organics determination were prepared
according to the procedures described in EPA Methods 3530 and 3540
(Reference 2). Instrumental analysis was conducted according to the protocol
discussed in EPA Method 8270 (Reference 2) utilizing a Hewlett-Packard 5985
GC/MS.
Pesticides/PCBs
Samples submitted for pesticides/PCBs determination were prepared
according to the procedures outlined in EPA Method 3540 (Reference 2).
Instrumental analysis was conducted according to the protocol discussed in EPA
Method 8080 (Reference 2) utilizing a Hewlett-Packard 5880 gas chromatograph
(GC) equipped with a Ni^3 electron capture detector (ECD). Due to significant
ECD interferences the samples, were subjected to additional alumina
chromatography cleanup.
D-3
-------
REFERENCES
1. American Society for Testing and Materials, Philadelphia, Pennsylvania.
2. Test methods for Evaluating Solid Waste: Physical/Chemical Methods,
2nd Edition, SW846, USEPA, Washington, DC. July 1982.
3. Methods for Chemical Analysis of Water and Wastes, EPA-600/4-79-020,
USEPA: Environmental Monitoring and Support Laboratory, Cincinnati, OH.
March 1983.
4. Chemistry Laboratory Manual for Bottom Sediments and Elutriate Testing,
EPA-905/479-014, USEPA: Central Regional Laboratory, Chicago, IL.
March 1979.
D-4
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APPENDIX E
QUALITY ASSURANCE
E-l
-------
Quality Assurance
Chain of Custody
A set of samples was received by GCA/Technology Division on the date
indicated in Appendix A for analysis. The samples received were clearly
labelled and appropriately chilled. These samples were assigned GCA Control
Numbers (listed as Lab Control^ in Appendix A) and entered into the Master
Log. Chain of custody procedures were followed and samples were transferred
to the locked Sample Bank for refrigerated storage until the time of
analysis. Sample custody records were maintained throughout all laboratory
procedures. Duplicate aqueous samples went submitted to Industrial and
Environmental Analysis (IEA) of Gary, North Carolina. Duplicate soil core
samples were submitted to Radian Corporation of Austin, Texas.
Quality Control Procedures
I. VOLATILE ORGANICS
Quality control procedures for volatile organics determination included
the use of surrogate spikes. Each sample was spiked with a surrogate mixture
containing dg-toluene, bromofluorobenzene and d,^-!,2-dichloroethane. These
recoveries are presented in the text.
II. EXTRACTABLE ORGANICS
Quality control procedures included the analysis of a spiked sample, a
duplicate sample and the use of surrogate spikes. One of the project samples
was spiked with a mixture containing some of the compounds of interest; spike
recoveries are shown in Table E-l. A duplicate aliquot of one of the project
samples was prepared and analyzed. Only one compound was detected,
bis(2-ethylhexyl) phthalate, with reported values of 58 and 53 ug/1. Each
sample was spiked with a. surrogate mixture containing d5-nitrobenzene,
2-fluorobiphenol and 2,4,6-tribromophenol. Surrogate recoveries are shown in
the text. A large dilution factor for the samples accounts for the low
recoveries.
E-2
-------
III. PESTICIDES AND PCBs
Quality control protocol included the analysis of a spiked aliquot of one
of the project samples. However, the spike recoveries could not be calculated
because the large dilution factor raised the detection limits above the level
at which the sample was spiked.
IV. TRACE METALS
Quality control procedures for trace metals determination included the
analysis of a laboratory control sample and a duplicate sample analysis. The
laboratory control sample was prepared from an aliquot of NBS 1645 River
Sediment; these results are listed in Table E-2. Duplicate analysis was
performed on one of the project samples. Precision, calculated as percent
difference, ranged from 0 to 93 percent, with an average of 12 percent.
V. PERCENT SOLIDS
An aliquot of EPA Municipal Sludge (WP 976), with an expected value of
96 percent solids, was analyzed with project samples. The reported value in
the analysis was 96.7 percent solids.
VI. OIL AND GREASE
Quality control procedures included duplicate analysis of one of the
project samples. Precision, calculated as percent difference, was
25 percent. In addition, a duplicate aliquot of EPA Municipal Sludge
Reference Material was analyzed along with project samples. The expected
range for this material is between 26,100 and 90,300 mg/kg. The reported
values were 100,500 and 108,000 mg/kg. Although the reported values were out
of the expected range, the precision between the duplicates did show good
agreement.
E-3
-------
TABLE E-l. PERCENT RECOVERIES OF A SPIKE PROJECT SAMPLE FOR
EXTRACTABLE ORGANICS
Compound Percent Recovery
1,2,4-trichlorobenzene 95
acenaphthene 90
2,4-dinitrotoluene 85
di-n-butylphthalate 95
pyrene 45
n-nitroso-di-n-propylamine 9
1,4-dichlorobenzene 13
pentachlorophenol 88
phenol 60
2-chlorphenol 74
4-chloro-3-methylphenol 34
4-nitrophenol 98
E-4
-------
TABLE E-2. ANALYSIS OF NBS 1645 RIVER SEDIMENT FOR TRACE METALS
Element
Aluminum
Cadmium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Sodium
Thallium
Vanadium
Zinc
Concentration
Reported
0.42%
8.70
2.72%
14.8
104
7.19%
730
7000
575
51.1
970
3.0
12
1540
(ug/g)*
Expected
2.26%
10.2
2.96%
10.1
109
11.3%
714
7400
785
45.8
5400
1.44
23.5
1720
Percent
Recovery
19
85
92
147
94
64
102
95
73
112
18
208
51
90
*Except as noted.
E-5
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APPENDIX F
CONFIDENTIAL ADDENDA
F-l
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