United States
Environmental Protection
Agency
Office of Air Quality E^B Report 91 -WAF-01
Planning and Standards Volume I
Research Triangle Park NC 27711 April 1992
Air
Oriented Strand Board
Emission Test Report
Georgia Pacific
Skippers, Virginia
&EPA
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TEST REPORT
VOLUME I.
METHOD DEVELOPMENT AND TESTING FOR
ORIENTED STRAND BOARD PLANT EMISSIONS
GEORGIA-PACIFIC ORIENTED STRAND BOARD PLANT
SKIPPERS, VIRGINIA
EPA Project No. 91-WAF-01
EPA Contract No. 68-D9-0055
Work Assignment No. 1-85
Prepared for:
Dennis P. Holzschuh
Emission Measurement Branch
Technical Support Division
U.S. Environmental Protection Agency
Research Triangle Park, North Carolina 27711
Prepared by:
William K. Kirk
Roger T. Shigehara
Lisa Grosshandler
Research and Analysis Division
Entropy Environmentalists, Inc.
Post Office Box 12291
Research Triangle Park, North Carolina 27709
March 27, 1992
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DISCLAIMER
This report was prepared by Entropy Environmentalists, Inc.
under Contract No. 68-D1-0055, Task 1-85. This report has been
reviewed by the Emission Measurement Branch and Emission
Inventory Branch of the Technical Support Division, Office of Air
Quality Planning and Standards, U.S. Environmental Protection
Agency, by the National Council for Air and Stream Improvement,
and by Georgia-Pacific, and is approved for release. Approval
does not signify that the contents necessarily reflect the views
and policies of the U.S. Environmental Protection Agency, nor
does mention of trade names or commercial products constitute
endorsement or recommendation for use by EPA, Entropy, or
Georgia-Pacific.
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TABLE OF CONTENTS
1. 0 INTRODUCTION
1.1 Summary of Test Program 1
1.2 Key Personnel 2
2.0 PLANT AND SAMPLING LOCATION DESCRIPTIONS
2 . l Process Description and Operation ". 3
2 . 2 Wet Electrostatic Precipitator Description 3
2.3 Flue Gas Sampling Locations 3
2 .4 ESP Cleaning Cycle 8
3.0 SUMMARY OF TEST RESULTS AND DISCUSSION
3.1 Objectives and Test Matrix 9
3 . 2 Volumetric Flow Rates 9
3 . 3 Emissions and Process Data 12
3.4 Emission Factors 12
3 . 5 Relationship Between Methods 25 and 25A 16
3 . 6 ODEQ Method 7 versus M202 16
3.7 Semi-Volatile Data 16
4.0 SAMPLING AND ANALYTICAL PROCEDURES
4 .1 Test Methods 19
4.2 Particulate Matter/Condensible Particulate Matter...19
4.3 Modified Method 5 19
4 . 4 Other Test Methods 26
5 . 0 QA/QC ACTIVITIES 37
5.1 QC Procedures 37
5 . 2 Sample Volume and Percent Isokinetics 37
APPENDIX A.
APPENDIX B.
APPENDIX C.
APPENDIX D.
APPENDIX E.
Method M0011 Data Summary
Method 5/202 Data Summary
Modified Method 5 Data Summary
Method 25 Data Summary
CEMS Data Summary - 02, CO2, CO, NOX, and THC
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LIST OF TABLES
Page
3-1 Sampling Matrix 10
3-2 Volumetric Flow Rate Data H
3-3 Summary of ESP Emissions 13
3-4 Wet ESP Collection Efficiencies 14
3-5 Summary of Process and Control Equipment Operating 14
Conditions
3-6 Summary of Emission Factors Based on Dry Wood Flakes 15
3-7 Semi-Volatile Organic Compounds 17
3-8 Semi-Volatile Organic Compounds 18
4-1 Sampling and Analytical Methods for Georgia Pacific 20
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LIST OF FIGURES
2-1. Oriented Strand Board (OSB) process flow diagram 4
2-2. Lower and upper wet ESP sampling locations 5
2-3. ESP outlet sampling locations • 6
4-1. Method 202 sampling train with out-of-stack filter 21
4-2. Method 202 sampling train with Method 5 filter and
backup filter 22
4-3. Sample recovery scheme for particulate/condensibles
samples 23
4-4. Analytical scheme for particulate/condensibles
samples 24
4-5. Modified Method 5 sampling train 25
4-6. Modified Method 5 sample recovery scheme 27
4-7. Organic field blank analysis flow scheme 28
4-8. Integrated gas sampling train for Method 3 29
4-9. Formaldehyde (Method 0011) sampling train 30
4-10. Sample recovery scheme for Method 0011 samples 31
4-11. Method 0011A. Formaldehyde by high performance
liquid chromatography (HPLC) 32
4-12. Method 25 sampling train 34
4-13. Instrumental measurement system for outlet stack
location 35
4-14. Instrumental measurement system for inlet location 36
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1.0 INTRODUCTION
1.1 SUMMARY OF TEST PROGRAM
The U.S. Environmental Protection Agency (EPA), Office of
Air Quality Planning and Standards (OAQPS), Emission Inventory
Branch (EIB) is responsible for developing and maintaining air
pollution emission factors for industrial processes. EIB, in
collaboration with the National Council for Air and Stream
Improvement (NCASI), is presently studying the wood products
industry. The purpose of this study is to develop emission
factors for oriented strand board (OSB) production facilities.
The Emission Measurement Branch (EMB) of OAQPS coordinated the
emission measurement activities at this plant. Entropy
Environmentalists, Inc. (Entropy) and NCASI conducted the
emission measurements.
EPA/EIB, EPA/EMB, and NCASI considered the Georgia-Pacific
facility in Skippers, Virginia to be one of four facilities that
represent the diversity in wood species and dryer control
devices. This test, the first of the four, was conducted on
June 25-26, 1991. Simultaneous measurements were conducted at
the inlet and outlet of the wet electrostatic precipitator (ESP)
for the wood flake dryer exhaust. Pollutants measured were:
particulate matter (PM), condensible particulate matter (CPM),
carbon monoxide (CO) , nitrogen oxides (NOX) , hydrocarbons (THC),
formaldehyde, other aldehydes, and ketones, and semivolatile
organic compounds (SVOC).
Current data for wood flake dryer exhausts for particulate
and VOC emissions have been obtained using various test methods
and often lack sufficient documentation for developing emission
factors. Therefore, one objective of this test was to
standardize the test methods. This test also served as a
compliance test to the State of Virginia under consent order.
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1.2 KEY PERSONNEL
The key personnel who coordinated the test program and their
telephone numbers are:
• Mr. Dallas Safriet
Technical Coordinator, EIB 919/541-5371
• Mr. Dennis Holzschuh
Field Test Coordinator, EMB 919/541-5239
• Mr. Bill Kirk
Field Test Director, Entropy 919/781-3551
• Mr. Chuck Vaught
Process Engineer, MRI 919/677-0249
• Mr. Larson Harsey
Georgia-Pacific Representative 404/527-0220
• David Rovell-Rixx
NCASI Representative 904/377-4708
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2.0 PLANT AND SAMPLING LOCATION DESCRIPTIONS
2.1 PROCESS DESCRIPTION AND OPERATION
The basic processing steps for OSB production are:
• Logs are cut into shorter lengths, debarked, slashed into
blocks, and sliced into thin wood flakes.
• The wood flakes are dried, classified on a rotary screen,
blended and mixed with resin, oriented, and formed into a
mat.
• The formed mats are separated into desired lengths,
heated, and pressed to activate the resin and bond the
wood flakes into a solid sheet.
• Sheets are trimmed, edge treated, and packaged for
shipping.
The wood mix for the Georgia-Pacific plant at Skippers,
Virginia is about 40 percent pine and 60 percent soft hardwoods.
About 17-20 tons/hr of wet wood flakes are sent to each of four
dryers with an inlet temperature of about 1000-1200°F to maintain
an exit temperature of about 250°F. At this point in the
process, the moisture content of the wood flakes ranges from 3 to
6 percent, wet basis. Figure 2-1 presents a generalized OSB
process flow diagram; the figure does not reflect exactly all the
activities at the Skippers plant.
2.2 WET ELECTROSTATIC PRECIPITATOR DESCRIPTION
Particulate matter from the wood flake dryers are controlled
by cyclones and a wet ES? manufactured by United-McGill. An ESP
relies on three basic process steps for particulate removal:
(1) electrical charging of the particles, (2) particle collection
on the electrodes, and (3) removal of the collected particulate.
The United-McGill wet ESP has an intermittent travelling header
system equipped with multiple high-pressure spray nozzles to
remove the collected particulate. The Skippers plant also has a
prequencher to cool and condense the gas stream before it enters
the ESP. The prequencher cools the gas by spraying water into
the incoming gas stream. The cooling and condensation increases
the capture of the sticky resins released from the wood flake
drying process.
2.3 FLUE GAS SAMPLING LOCATIONS
Emission samples were collected at the wet ESP outlet stack
and two separate inlet locations. Figures 2-2 and 2-3 are
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Fuel Storage
Outlet Test Point
Stack
3685 3/92
Press and Shuttle
Fuel Storage rress ana snunie Fue| storage
Figure 2-1. Generalized Oriented Strand Board (OSB) process flow diagram.
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42" Diameter
Traverse Points
1 Axis
8 Points/Axis
8 Total Points
Section X - X
To
Prequencher
Lower wet ESP inlets
Traverse Points
2 Axes
16 Points/Axis A
32 Total Points
108" Diameter
Section K - K
OA
J
View A - A
Upper wet ESP inlet
To
Prequencher
Figure 2-2. Lower and upper wet ESP sampling locations.
3685 11/91
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TRAVERSE POINTS
2 AXES
16 POINTS/AXIS
32 TOTAL POINTS
SECTION X-X
SECTION Y-Y
SECTION Z-Z
4 :
70" 48,
Y
7 1/2"
-ffO"
X
Y
100'
3685 3/92
Figure 2-3. ESP outlet sampling locations.
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schematics of the sampling locations. The exhausts from four
dryers are combined upstream of the prequencher that leads to the
wet ESP-
2.3.1 Lower Wet ESP Inlet Sampling Location
The lower wet ESP inlet consists of four identical 42-inch
diameter horizontal ducts upstream of four fans and bypass
stacks. A manual damper is located approximately one duct
diameter upstream from the 4-inch sampling port, and a square
access door is located 32 inches (0.75 duct diameters) downstream
from the sampling port in each of the ducts. This access would
be considered a minor disturbance. The distance between the
damper and the fans is 178 inches (4.2 diameters). The plant
installed additional ports approximately two diameters downstream
from the original locations. Since the flow profiles at both
locations were similar and because of the cramped conditions at
the additional locations, the original locations were chosen for
the test.
Each of the four ducts had different flow profiles. The
manual dampers were set independently to balance the system for
production.
The sample traverse consisted of one axis only with
8 traverse points per duct (32 total) at 2 1/2 minutes per point,
for a total sampling time of 80 minutes. Method 5/202 for PM and
CPM and SW-846 Method 0011 for formaldehyde, aldehydes, and
ketones were performed at this location.
2.3.2 Upper Wet ESP Inlet Sampling Location
The upper wet ESP inlet sampling location, at which the four
dryer exhaust ducts are combined, is downstream of the lower
inlet location. This location in the 108-inch horizontal duct
has two 4-inch ports. One port is on the horizontal axis and the
other is on the vertical axis. The distance from the sampling
ports downstream to the 90-degree elbow leading to the
prequencher is less than a duct diameter. The horizontal
sampling port is located directly across from one of the four
(54-inch) ducts that tangentially tie into the 108-inch duct.
Methods 25 and 25A were performed at this location.
2.3.3 Wet ESP Stack Outlet Sampling Location
The outlet stack for the wet ESP had a total of eight
sampling ports located on three different planes in the 108-inch
diameter vertical duct. Figure 2-3 shows the stack sampling
locations. The ports are 0.78 duct diameter upstream from the
stack exit and 2.3 duct diameters downstream from a disturbance.
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2.4 ESP CLEANING CYCLE
The wet ESP goes through an automatically controlled
16-minute wash cycle to purge the collection plates of
accumulated particulate matter. Within each of the 80-minute
test runs, one of the four (20-minute) isokinetic sampling
traverses conducted at one of the lower four inlet ducts was
timed to take place during the wash cycle. Simultaneous
measurements were taken at the ESP outlet to include the effect
(if any) of the wash cycle on the outlet emissions.
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3.0 SUMMARY OF TEST RESULTS AND DISCUSSION
3.1 OBJECTIVES AND TEST MATRIX
The purpose of the test program was to develop emission
factors for OSB production facilities from the wood products
industry.
Table 3-1 presents the sampling and analytical matrix and
summarizes all the measurements being made at each test location.
The specific objectives were:
• Measure the emissions of PM, CPM, CO, NOX, THC,
formaldehyde, other aldehydes, and ketones at the
wood flake dryer wet ESP inlet and outlet
locations, and semi-volatile organics at the
outlet.
• Determine the relationship between Method 25 and
Method 25A for THC, and between Method 5/202 and
the Oregon Department of Environmental Quality
(ODEQ) Method 7 for particulates (PM and CPM).
• Assess the suitability of deriving a correction
factor for Method 25A.
• Obtain dryer production rates, feed inlet and
outlet moisture content, inlet and outlet dryer
temperatures, inlet and outlet ESP temperatures,
ESP field voltages and currents, and wash cycle
time, ESP water rate, and wood mix.
3.2 VOLUMETRIC FLOW RATES
To determine mass emission rates and wet ESP collection
efficiency, flow rate is an important component. During this
test program, three separate trains provided simultaneous
measurements of velocities, temperatures, and moisture contents.
M5/202 and M0011 were run simultaneously at the ESP inlet
(lower); M5/202, M0011, and MM5 were run simultaneously at the
ESP outlet and concurrently with M5/202 and M0011 at the ESP
inlet. Table 3-2 summarizes the flow rate data. Method 3 data
for O2 and CO2 are added to this table.
The following observations are made:
• The temperature measurements of the ESP inlet were within
±6°F and at the outlet, the temperatures were within ±2°F.
The ±6°F is a variation of less than ±1 percent in volume
measurements.
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TABLE 3-1. SAMPLING MATRIX - GEORGIA PACIFIC
ntfftt A* A
RUN NO,
DATE
1
6/25/91
2
6/25/91
3
6/26/91
SAMPLE
TYPE
PM/CPM
02/C02
F/A/K
svoc
TGNMO
THC
NOX
CO
PM/CPM
02/C02
F/A/K
SVOC
TGNMO
THC
NOX
CO
PM/CPM
02/C02
F/A/K
SVOC
TGNMO
THC
NOX
CO
TEST
METHOD
M5/202
M3
M0011
MM5
M25
M25A
M7E
M10
M5/202
M3
M0011
MM5
M25
M25A
M7E
M10
M5/202
M3
M0011
MM5
M25
M25A
M7E
M10
LOCATION/CLOCK TIME1
ESP INLET
(Lower)
1015-1340
1014-1340
1753-2007
1715-2015
0930-1141
0930-1141
ESP INLET
(Upper)
1014-1404
1019-1340
1014-1404
1014-1404
1014-1404
1754-2005
1754-2006
1754-2005
1754-2005
1754-2005
0930-1141
0930-1144
0930-1141
0930-1141
0930-1141
ESP OUTLET
1014-1342
1014-1404
1014-1342
1014-1342
1010-1340
1014-1404
1014-1404
1014-1404
1753-2005
1754-2005
1753-2005
1753-2005
1753-2005
1754-2005
1754-2005
1754-2005
0930-1141
0930-1141
0930-1143
0930-1143
0930-1144
0930-1141
0930-1141
0930-1141
1 All sampling times were 80 minutes in length.
Note: Mercury Labs analyzed M0011 samples for F/A/K.
Triangle Labs analyzed MM5 samples for semivolati1es
NCASI collected and analyzed the M25 samples.
Entropy collected and analyzed all other samples.
10
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TABLE 3-2. VOLUMETRIC FLOW RATE DATA - GEORGIA PACIFIC
RUN
NO.
1-1
1-2
1-3
Avg
S-l
S-2
S-3
Avg
FLOW RATE, dscmh
M5/202
189,250
193,739
192,821
192,270
182,515
191,038
199,861
191,138
MOO 11
203,546'
193,785
187,712
195,014"
200,225
191,916
194,423
195,521
MM5
182,094
186,164
183,328
183,862
Average
196,398
193,762
190,767
188,278
189,706
192,537
TEMPERATURE, °F
M5/202
198
188
200
195
143
144
145
144
MOO 11
203
200
208
204
144
146
148
146
MM5
144
147
147
146
MOISTURE, %H20
M5/202
22.0
23.0
23.6
22.9
22.4
21.8
22.4
22.2
MOO 11
22. Ob
22.1
21.3
21. 7b
21.4
22.3
22.8
22.2
HM5
22.0
23.2
23.8
23.0
ORSAT
02
17.1
18.3°
16.8
17.0
17.2
16.9
17.2
17.1
C02
3.6
2.6C
3.9
3.7
3.5
3.6
3.5
3.5
"This volumetric flow rate is based on 22% moisture. See notation (b). Originally, the value was 215,499 dscmh.
bActual value was 16.5% moisture. The value from M5/202 was substituted.
cThese values indicate that the sample bag might have had a leak. Therefore, they were excluded from the average.
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• Run 1-1, MOOll had a moisture content of 16.5 percent.
When this value was compared with the moisture contents of
M5/202, Runs 1-2 and 1-3 of MOOll, and the ESP outlet
moisture contents of the M5/202, MOOll, and MM5 trains,
16.5 percent was obviously an outlier. Therefore, 16.5
percent was replaced with the moisture content from the
M5/202 train, which was run simultaneously with the MOOll
train. When this was done, moisture contents at the inlet
were within ±1.2 percent of each other. • At the outlet of
the ESP, the moisture contents were within ±0.7 percent of
each other.
• The O2/CO2 data for Run 1-2 appear to be out of line when
compared to the rest of the data, especially the outlet.
The higher O2 and lower C02 values than the rest of the
data indicate probable leakage into the sample bag.
Therefore, these data should be discarded.
• All flow rates were within ±6.3 percent of the respective
averages. Considering that the flow rates at the inlet
were summations of the four individual ducts, the
agreement was well within the experimental error.
Based on these observations, the moisture content of
16.5 percent from MOOll Run 1-1 was discarded and replaced with
22.0 percent. The emission concentrations and flow rates were
recalculated and are presented in Table 3-2. These average flow
rates were considered to provide the best data, and therefore,
were used to calculate the mass emission rates.
3.3 EMISSIONS AND PROCESS DATA
Tables 3-3, 3-4, and 3-5 summarize the emissions, ESP
collection efficiencies, and process data, respectively. The
aldehyde/ketone data from MOOll are not included in the tables,
but are found in Appendix A. The data, however, should not be
used since subsequent tests at other plants indicated a problem
with collection efficiencies. If sampling problems are resolved
later, EPA plans to return to the plant to determine the
emissions of aldehydes and ketones.
3.4 EMISSION FACTORS
Table 3-6 presents the emission factors in terms of tons of
dry wood flakes processed by the dryer.
12
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TABLE 3-3. SUMMARY OF WET ESP EMISSIONS - GEORGIA PACIFIC
METHOD/
COMPONENT
M202: Filterable PM
Inorganic CPM
Organic CPM
Total
Filterable PM
Inorganic CPM
Organic CPM
Total
25A THC
THC
M25: TGNMO
Condensible Organics
NMO (Noncondenslbles)
TGMNO
M10 CO
M7E NOv
As- NO,
UNITS
mg/dscm
mg/dscm
mg/dscm
mg/dscm
Ib/hr'
Ib/hr
lb/hr
lb/hr
ppm C
mg/dscm
Ib/hr'
ppm C
ppm C
ppm C
mg/dscm
lb/hr8
ppm
lb/hra
ppm
lb/hra
WET ESP INLET
RUN 1 RUN 2 RUN 3 AVG
248 333 366 316
51 70 87 69
14 23 36 24
313 426 489 409
107 4 142.3 153.9 134.5
22.1 29.9 36.6 29.5
6.1 9.8 15.1 10.3
135.5 182.0 205.7 174.4
396 1013 445 618
198 506 222 309
85.7 216.2 93.5 131.8
343 1296 538 726
343 1296 538 726
0000
171 648 269 363
74.2 276.6 113.1 154.6
WET ESP OUTLET
RUN 1 RUN 2 RUN 3 AVG
20.2 36.6 30.0 28.9
13.2 20.1 20.0 17.8
10.2 16.1 12.4 12.9
43.6 72.8 62.4 59.6
8.4 15.3 12.7 12.1
5.5 8.4 8.5 7.5
4.2 6.7 5.3 5.4
18.1 30.4 26.5 25.0
346 836 403 528
173 418 201 264
71.8 174.7 85.5 110.6
373 1189 413 658
373 1189 413 658
0 000
186 594 206 329
77.4 248.5 87.6 137.8
95.6 139.8 199.4 145
46.2 68.1 98.6 70.9
32 20 21 24
25.4 16.0 17.0 19.5
Emission rates are based on average flow rates determined from the simultaneous runs.
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TABLE 3-4. WET ESP COLLECTION EFFICIENCIES
METHOD/COMPONENT
Method 5/202
Filterable PM
CPM
Inorganic
Organic
Total
Method 25 TGNMO
Method 25A THC
RUN NO. 1
92.2
65.5
75.2
30.2
86.7
-4.31
16.3
RUN NO. 2
89.2
61.9
71.9
31.5
83.3
10.2
19.2
RUN NO. 3
91.7
73.4
76.8
65.2
87.1
22.5
8.6
AVERAGE
91.0
67.7
74.7
47.7
85.7
10.9
16.1
1 Negative efficiencies result primarily from the almost equal inlet and
outlet concentrations and the precision of the test methods.
TABLE 3-5. SUMMARY OF PROCESS AND CONTROL EQUIPMENT
OPERATING CONDITIONS
PARAMETERS
Dryer Production Rate
Feed Moisture
Exit Moisture
Dryer Entrance Temp
Dryer Exit Temp
ESP Temp, Inlet
ESP Temp, Outlet
ESP Field 1 Voltage,
ESP Field 1 Amperage,
ESP Field 2 Voltage,
ESP Field 2 Amperage,
ESP Field 3 Voltage,
ESP Field 3 Amperage,
Wash Cycle Start,
Wash Cycle Stop,
Cycle Time
Average Wood Mix
Hardwood
South Pine
ESP Water
UNITS
Ton/hr*
%
%
•F
°F
°F
'F
Kv
mA
Kv
mA
Kv
mA
Time
Time
min
%
%
gpm
RUN 1
35.4
46.8
2.9
1084
248
214
143
26.2
42
38.5
221
41.0
316
1016
1033
17
58
42
362
RUN 2
38.8
47.7
3.7
1134
236
208
146
28.2
35
42.5
297
40.2
300
1755
1812
17
58
42
361
RUN 3
38.7
47.1
2.5
1137
246
220
146
27.7
30
42.0
274
42.1
316
1016
1033
17
58
42
361
AVG
37.6
47.2
3.0
1118
243
214
145
27.4
36
41.0
264
41.1
311
58
42
361
Based on dry tons/hr, 0% moisture content
14
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TABLE 3-6. SUMMARY OF EMISSION FACTORS BASED ON PRODUCTION OF DRY WOOD FLAKES
METHOD/
COMPONENT
M202
Filterable PM
CPM
Inorganic CPM
Organic CPM
Total
M25A THC
Method 25 TGNMO
CO
NOX as N02
UNITS
Ib/ton
Ib/ton
Ib/ton
Ib/ton
Ib/ton
Ib/ton
Ib/ton
Ib/ton
Ib/ton
WET ESP INLET
RUN 1 RUN 2 RUN 3 AVG
3.03 3.67 3.98 3.56
0.80 1.02 1.34 1.05
0.62 0.77 0.95 0.78
0.17 0.25 0.39 0.27
3.83 4.69 5.31 4.61
2.42 5.57 2.42 3.47
2.10 7.13 2.92 4.05
WET ESP OUTLET
RUN 1 RUN 2 RUN 3 AVG
0.24 0.39 0.33 0.32
0.27 0.39 0.36 0.34
0.15 0.22 0.22 0.20
0.12 0.17 0.14 0.14
0.51 0.78 0.68 0.66
2.03 4.50 2.21 2.91
2.19 6.40 2.26 3.62
1.31 1.75 2.55 1.87
0.72 0.41 0.44 0.52
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3.5 RELATIONSHIP BETWEEN METHODS 25 AND 25A
The data for the relationship between Methods 25 and 25A are
shown in Table 3-7.
The Method 25A concentrations are the averages over the entire
elapsed time of the test, while the Method 25 sample was stopped
and started to correspond with the particulate matter sample.
Therefore, the Method 25A concentrations were -recalculated to
correspond to the times that Method 25 was obtaining samples.
The data show some consistencybetween the two methods at both
the inlet and outlet of the ESP. Before any conclusions are
made, data from all other tests should be evaluated.
3.6 ODEQ METHOD 7 VERSUS M202
NCASI analyzed the back-up filter and verbally reported that
the back-up filters had no particulate mass weights. Therefore,
it was concluded that the two methods were equivalent.
3.7 SEMI-VOLATILE DATA
Table 3-8 presents the data for the semi-volatile organic
compounds. A table showing detection limits is included in
Appendix C. This test was conducted basically for screening
purposes. Further discussion of these data will be done under a
separate report.
16
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TABLE 3-7. METHOD 25 VERSUS METHOD 25A
RUN THC TGNMO RATIO
lb/hr Ib/hr TGNMO/THC
1-1 85.8 74.2 0.86
1-2 209.7 276.6 - 1.32
1-3 94.7 113.1 1.19
Avg 1.13
S-l 70.2 77.4 1.10
S-2 174.4 248.5 1.42
5-3 86.7 87.6 1.01
Avg 1.18
17
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TABLE 3-8. SEMIVOLATILE ORGANIC COMPOUNDS
NAME
Naphthalene
MM5-1 MM5-2
3 3
Diethylphthalate 14.1 4.5
Di-n-butylphthalate 6.6 7.5
Butylbenzylphthalate 4.8 4.8
bis(2-Ethylhexyl)phthalate 55 54
Di-n-octylphthalate 5.1 8.2
Total 85.6 79.0
Ib/hr 0.036 0.033
MM5-3 AVG.
3 3
524 175
6.1 8.2
5.7 6.6
20.2 9.9
58 56
41 18
655.0 273.7
0.278 0.115
18
-------
4.0 SAMPLING AND ANALYTICAL PROCEDURES
4.1 TEST METHODS
Table 4-1 summarizes the analytes and test methods used for
sampling and analysis. The schematics of all sampling trains,
flow diagrams of sample recovery and sample analysis, and
descriptions of any modifications to the test methods are also
included in this section.
4.2 PARTICULATE MATTER/CONDENSIBLE PARTICULATE MATTER
Method 5/202 was used at the inlet and outlet of the wet ESP
to measure PM/CPM. NCASI desired to compare Method 202 with ODEQ
Method 7, which is identical to Method 202 except for the
following:
• A second filter is placed just before the silica gel
impinger.
• Acetone rather than methylene chloride is used in the
final rinse of the impingers and connecting glassware.
• An optional out-of-stack filter is used before the
impingers.
Because of space limitations, NCASI decided to make this
comparison by inserting a second filter in the Method 202 train
in the same position as that in the ODEQ Method 7 and using the
out-of-stack filter. The back-up filter was transmitted to
NCASI, which analyzed the filter gravimetrically according to
ODEQ Method 7.
Figures 4-1 and 4-2 illustrate the modifications to the
Method 202 sampling train. Figures 4-3 and 4-4 illustrate the
sample recovery procedure and analysis schemes, respectively.
4.3 MODIFIED METHOD 5
The standard MM5 sampling train of SW-846 Method 0010 shown
in Figure 4-5 was used to collect the semivolatile organic
screening samples at the outlet location.
Standard MM5 pre-cleanup reguirements included several
unigue preparation steps to ensure the sampling train components
were not contaminated with organics that could have interfered
with the analysis. The glassware, glass fiber filters, and XAD
adsorbing resin were precleaned using strict protocols. For this
particular study, the impinger water fraction was analyzed for
oxygenated organics as well as the semivolatile organics.
Therefore, the acetone pre-rinse of the train was detected.
19
-------
TABLE 4-1. SAMPLING AND ANALYTICAL METHODS FOR GEORGIA-PACIFIC
Analyte
Sampling Method
Analytical Method
Participate
Matter (PM)
Condensible
Participate
Matter (CPM)
Carbon Monoxide
(CO)
Nitrogen
Oxides (NOJ
Oxygen (02),
Carbon Dioxide (C02)
Formaldehyde,
Aldehydes,
Ketones
VOC as propane
VOC as carbon
Organics Screening
EPA Method 202
w/ Method 5 filter
ODEQ Method 7
EPA Method 202
w/ Method 5 filter
ODEQ Method 7
EPA Method 10
EPA Method 7E
EPA Method 3
SW-846 Method 0011
EPA Method 25A
EPA Method 25
SW-846 Method 0010 (MM5)
EPA Method 5
(Gravimetric)
ODEQ Method 7
(Gravimetric)
EPA Method 202
(Extraction/
Gravimetric)
ODEQ Method 7
(Extraction/
Gravimetric)
EPA Method 10
(NDIR)
EPA Method 7E
(Chemiluminescence)
EPA Method 3 (Orsat)
SW-846 Method 0011
(HPLC)
EPA Method 25A (FID)
EPA Method 25
(Catalysis, GC/FID)
SW-846 Method 8270
(HPLC)
20
-------
EPA Method
5 Sampling
Components
Thermocouple check
TT Valve
Figure 4-1. Method 202 sampling train with out-of-stack filter.
3667 6/91
-------
EPA Method
5 Sampling
Components
Thermocouple Check
T Valve
3667 7/91
Figure 4-2 Method 202 sampling train with Method 5 filter and backup filter.
-------
Probe I iner
and Nozfte
Front Hal o)
Filler Housing
I Hl«i
Back H,irt
ol F irier
Housing
Rjns« with
acetone
Brush and
nns« with
acetone
Baish liner
and nnse with
acetone
ro
GO
I
AR
(2)
Ca/elulry
remove and
place in
pelrt dish
Brusn loose
paniculate
onto (iher
Seal petn dish
Rinse 2x
with 01 waler
Rlnse2x
wtth MeClj
IMP
(4)
1st. 2nd & 3rd
Impingers
(PI Waler)
fronl HaH ot
Backup Filler
Housing
Backup Filler
Last
Impmger
Measure
Impinger
contents
Empty
contents Into
sample
container
Carefully
remove and
place In
pelri dish
Weigh
silica gel
for moisture
Seal petri dish
Rinse ZK
with 01 Water
Rinse 2x
with Dl water
Rinse 2x
with MeClj
Rinse 2x
whh MeCU
MeCL
(5)
BU-F
(6)
SO
(3)
Sample container number.
Figure 4-3. Sample recovery scheme for particulate/condensibles sampl
es,
-------
CONTAINER 1
FILTER
CONTAINER 2
ACETONE RINSE
CONTAINER 4
IHPiNGERS
Desiccate and
weigh to
constant
Hei ght
Del ermi ne
total sample
vo1ume
Transfer contents
to tared
beaker
Desiccate and
we igh to
constant
weight
Determine
total sample
volume
CONTAINER 5
MECL,
Determine
total sample
vol une
CONTAINER 6
BACK-UP FILTER
Combine contents in
1000-ml separatory
funnel
Mix, a low to
separate, drain (save)
most of HeCl, phase
Into MeCI,
sample container
Add 75 ml of MeCI, to
separatory funnel and
repeat above
procedure
Repeat above
I
Place H,0 In a
pre-cleaned container
and evaporate to 50 ml
on a hot plate
or equivalent
Place in a tared beaker
and evaporate to dryness
in a 105"C oven
Desiccate and
weigh to
constant weight
Transfer MeCI,
contents to tared
beaker
Allow to
evaporate at room
tenperature
under a hood
Desiccate and
weigh to
constant weight
Desiccate and
weigh to
constant weight
Figure 4-4. Analytical scheme for particulate/condensibles samples,
-------
Condenser
Thermocouple
Thermocouple
100 ml (each) ol H 2O
Thermocouples
3667 6/91
Figure 4-5. Modified Method 5 sampling train.
-------
Figures 4-6 and 4-7 show the sample recovery and analysis
schemes.
4.4 OTHER TEST METHODS
Figures 4-8 through 4-14 show the sampling train schematic
and sample recovery and analysis schemes for the rest of the test
methods used in this test program.
26
-------
rx)
-J
Probe Liner
No* jle/FH a
Allac
1 250 ml
flask to liner
end
Rinse
3x with
acelone and
brush
until c
Rinse
3x or
lean
3i with
melhylene
chloride and
brush rl
neces
P
sary °
r\
(1)
Filter
Carek
lly
remove and
place
p«ln d
Brush
n
ish
loose
paniculate
onto filler
Seal c
H
eln dish
(2)
Sorbenl
Module
Back Hall
Components
Isl. 2nd, 3rd, S 4lh
Impingers/Componenls
5lh
Impinger
Secure XAD
module openings
Rinse 3x wilh
acelone
Measure impimger
contents
Place in cooler
lor storage
shipment
Weigh
silica gel
lor moisture
Rinse 3x wilh
melhylene
chloride d
Rinse 3x with
Dl water
Record weight
SM
(3)
BHH
(4)
IMPW
(5)
SG
(6)
FH = Fronl half includes connecting glassware Irom probe to filter housing and front hat! filler housing
'BUR = Back hall componenls - includes connecting glassware Irom Ironl liller housing through condenser coil,
front lilter support, back halt of front liller housing, condenser coil, impingers and connecting glassware
1st. 2nd, 3rd, and 4lh Impinger Componenls - Includes Impingers and connecting glassware
Molhylene chloride rinse will only be used il results Irom lirsl OSB lest Indicate that it is necessary.
3667 7/91
Figure 4-6. Modified Method 5 sample recovery scheme.
-------
Figure 4-7. Organic field blank analysis flow scheme.
ACETONE
FH RINSE
FILTER
KD TO
2 ml
ADD TO
SOX1
FRACTION
3
XAD
PRESPIKED
W/100 ug
TERPHENYL
-D14
AC/MeCl2
BH RINSE
FRACTION
D
ANALYZE FOR
SEMI-VOLATILE
ORGANICS
Method 8270
ANALYZE FOR
SEMI-VOLATILE
ORGANICS
Method 8270
ANALYZE FOR
SEMI-VOLATILE
ORGANICS
Method 8270
ANALYZE FOR
SEMI-VOLATILE
ORGANICS
Method 8270
ORGANICS £S SPIKE:
D5-=HENOL '00 ug
1 , 4-o:3ROMOBENZENE 100 ug
D5-NI7R03ENZENE 100 ug
2-FLUORO8IPHENYL 100 ug
', , 2 , 5-TRICHLOROBENZENE-D3 100 ug
2,- , 5-TRIBROMOPHENOL 100 ug
ANTHRACENE-D10 100 ug
PYRENE-D10 100 ug
TLI rev-hk-1 Jun 91
28
-------
RATE METER
AIR-COOLED
CONDENSER
M
FILTER
(GLASS WOOL)
VALVE
QUICK DISCONNECT
BAG
RIGID CONTAINER
Figure 4-8. Integrated gas sampling train for Method 3.
-------
U)
o
Thermocouple
Orifice
Manometer
Thermocouple
T
Modified Greenburg
Smith Impingers
Figure 4-9. Formaldehyde (Method 0011) sampling train.
-------
Probe Liner
and Nozzle
Measure
condensale
with mpinger
conlenls
Rinse with
MeCI j
Brush 3* wrth
Telton bnstl«
brush
Rinse wrth
MeCI 2 urttl no
bnger yeltow
Rinse brush
with MeCI 2
or Dl water
1st & 2nd
Impinge rs
(DNPH)
Meas
impin
conle
Rinse
wlh K
Brusr
Telkx
brush
Rinse
wlh K
(indu
brush
Rinse
Dl wa
(mdi>
bnjsh
ure
ger
nls
3.
wrth
i bnslle
li
^eCl2
ding
)
with
ter
ding
)
3rd Impinger
(Empty)
Measure
Impinger
contenls
Rinse 3*
with MeCI 2
Brush with
Tellon bnsllf
brush
Rinse 1x
with MeCI 2
(indudmg
brush)
Rinse wrth
Dl water
(indudmg
brush)
Last
Impinger
Weigh
silica gel
for moisture
IMP
SG
(2)
Figure 4-10. Sample recovery scheme for Method 0011 samples
-------
soli*
:t'trwiflffr«fl. if
* ' 2
torn**
: 000
'Iui4;
7.2.1
citenuo. il
7.2.2 C»«wifgo,o
10^01*. if
"•CtlMPf
1
1
for
of mM
of 100
MfMftt
7.1.4.1
buffv arx adjust
pN vitM WttiC
or
30
to turns;
to
e*n«Hi«A
7 J.AJ ftom^v
>QfH
7 J.4J Owio trw
«y*olo
w/omo
€>
7 15.i ice ::«':•» j
Suf'tr ;•• :;..jf
9f US .
J«fli
7.15.2 i
Mi'n «,m J.2C— •
7.15.J
i a
1 5
Fi gure 4-11
(conti nued )
Method 0011A. Formaldehyde by high performance liquid
chromatography (HPLC).
32
-------
J
7 S.l.l.l »r«0ort
7.5.1.1.2
7.5.1.2.1
tronaarat «n«
7.5.1.2J
esi
flg*r wiltt 1
or
7.1.1
"
conditions: omtr
ft9Tft0fT9 ffT
««fv m«* D«
uU4 if OC
UM
7.I.J If DMk
4> Un
nnf t.
7.1.4 H
7.7 i C
9«
l"*f
Dilution 'actor
1
Figure 4-11 (continued)
33
-------
REGULATING
VALVE
VACUUM PUMP
DUAL RANG
ROTAMETER
TEMPERATURE
CONTROLLER
THERMOCOUPLES
I
PURGE VALVE
THERMOCOUPLE
STACK
WALL
ROTAMETER
SAMPLE
VALVE
STAINLESS STEEL
FILTER HOLDER
HEATED BOX
STAINLESS
STEEL PROBE
MANOMETER
FLOW
CONTROL
VALVE
SAMPLE
TANK
VALVE
CONDENSATE
TRAP
SAMPLE
TANK
Figure 4-12. Method 25 sampling train.
34
-------
CALIBRATION
GAS VENT
U)
Ln
HEATED
SAMPLE
LINE
HEATED
LINE
CONDENSATF.
PUMPS
RATFISCH RS 55/FID
GAS ANALYZER
HEATED
TEFLON PUMP
CALIBRATION GAS LINE
SAMPLE
PUMP
SAMPLE GAS MANIFOLD
Lr Lr Lr
CALIBRATION GASES
Figure 4-13. Instrumental measurement system for outlet stack location.
-------
CALIBRATION
GAS VENT
CO
CTl
HEATED
SAMPLE
LINE
HEATED
FILTER
•HEATED
LINE
HEATED
TEFLON PUMP
RATFISCH RS 55/FID
GAS ANALYZER
GAS MANIFOLD
CALIBRATION GAS LINE
CALIBRATION GASES
Figure 4-14. Instrumental measurement system for inlet location
-------
5.0 QA/QC ACTIVITIES
5.1 QC PROCEDURES
One field spike was performed at the EFB outlet location as
a check of field handling and recovery procedures. The field
spike consisted of introducing 200 jil of the Field Spike Standard
into an impinger containing 200 ml of the DNPH solution and
following normal recovery procedures.
The Field Spike Standard was prepared in the field according
to the method. Exactly 0.5 ml of 37% by weight of formaldehyde
(401 mg/ml) was added to a 50-ml volumetric flask containing
approximately 40 ml of methanol and then volumed to 50 ml.
The method specifies a 500-^1 syringe to transfer both the
formaldehyde and the field spike solution. A 500-^1 syringe was
not available; therefore, a 100-jil syringe was used.
The results of the field spikes are shown below:
Train
Li-Train
S-Train
HCOH
Added Analyzed
0.80 mg 0.83 mg
0.80 mg 0.20 mg
No explanation or reasons could be found for the great
difference in the S-train spike.
5.2 SAMPLE VOLUMES AND PERCENT ISOKINETICS
All sampling rates were within ±10 percent of isokinetic,
The sample volume and percent isokinetics are shown below:
RUN
1-1
1-2
1-3
S-l
S-2
S-3
SAMPLE VOLUME
M5/202
61.0
45.1
44.1
49.0
49.8
54 . 4
M0011
49 . 8
47.7
46.2
47. 1
45.5
46.2
MM5
48.2
49 . 1
60.0
PERCENT ISOKINETIC
M5/202
97 .2
102.0
103.5
103. 1
100.2
99 . 0
M0011
100. 5
101.1
101.0
94 .8
95.5
95.7
MM5
91.3
95.9
96.3
37
-------
APPENDIX A. Method M0011 Data Summary
-------
FIELD DATA AND RESULTS TABULATION
(Revised Data for LI-1)
PLANT: Georgia-Pacific Corporation, Skippers, VA
SAMPLING LOCATION: Lower Prequench Inlet
Test Date
Run Start Time
Run Finish Time
Net Traversing Points
Theta Net Run Time, Minutes
Dia Nozzle Diameter, Inches
Cp Pitot Tube Coefficient
Y Dry Gas Meter Calibration Factor
Pbar Barometric Pressure, Inches Hg
Delta-H Avg. Pressure Differential of
Orifice Meter, Inches H2O
Vm Volume Of Metered Gas Sample, Dry ACF
tm Dry Gas Meter Temperature, Degrees F
Vmstd Volume Of Metered Gas Sample, Dry SCF*
Vic Total Liquid Collected In
Impingers & Silica Gel, grams
Vwstd Volume of Water Vapor, SCF*
%H2O Moisture Content, Percent by Volume
Mfd Dry Mole Fraction
%CO2 Carbon Dioxide, Percent By Volume, Dry
%O2 Oxygen, Percent By Volume, Dry
%CO+N2 CO + N2, Percent By Volume, Dry
Md Gas Molecular Weight, Lb/Lb-Mole, Dry
Ms Gas Molecular Weight, Lb/Lb-Mole, Wet
Pg Flue Gas Static Pressure, Inches H2O
Pa Absolute Flue Gas Pressure, Inches Hg
ts Flue Gas Temperature, Degrees F
Delta-p Average Velocity Head, Inches H2O
vs Flue Gas Velocity, Feet/Second
A Stack/Duct Area, Square Inches
Qsd Volumetric Air Flow Rate, Dry SCFM*
Qmsd Volumetric Air Flow Rate, Dry SCMH*
Qaw Volumetric Air Flow Rate, Wet ACFM
Qmaw Volumetric Air Flow Rate, Wet ACMH
%I Isokinetic Sampling Rate, Percent
ton/hr Average Process Feed Rate, ton/hr
* 68° F ( 20°C) — 29.92 Inches of Mercury (Hg)
A-l
LI-M0011-1 LI-M0011-2 LI-M0011-3
6/25/91
1014
1340
32
80.00 -
0.191
0.84
1.0050
29.90
1.49
51.947
95
49.796
NA
NA
22.0
0.780
r 3.6
17.1
79.3
29.26
26.78
-15.50
28.76
203
1.7005
86.88
5,542
119,789
203,546
200,618
340,890
100.5
35.4
6/25/91
1715
2015
32
80.00
0.191
0.84
1.0050
29.90
1.33
49.592
93
47.691
287.0
13.509
22.1
0.779
2.6
18.3
79.1
29.15
26.69
-15.00
28.80
200
1.5298
82.31
5,542
114,045
193,785
190,070
322,967
101.1
38.8
6/26/91
930
1141
32
80.00
0.191
0.84
1.0050
29.90
1.24
47.933
92
46.169
265.0
12.474
21.3
0.787
3.9
16.8
79.3
29.30
26.89
-16.00
28.72
208
1.4380
80.08
5,542
110,471
187,712
184,917
314,211
101.0
38.7
ENTROPY
-------
FIELD DATA AND RESULTS TABULATION
(Revised Data for LI-1)
PLANT: Georgia-Pacific Corporation, Skippers, VA
SAMPLING LOCATION: Lower Prequench Inlet
LI-M0011-1 LI-M0011-2 LI-M0011-3
fwt
mg
mg/DSCM
ppmvd
ppm@12%CO2
ppm@7%O2
Ib/hr
Ib/ton
fwt
mg
mg/DSCM
ppmvd
ppm@12%CO2
ppm@7%O2
Ib/hr
Ib/ton
fwt
mg
mg/DSCM
ppmvd
ppm@12%CO2
ppm@7%O2
Ib/hr
Ib/ton
Acetaldehvde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Acetone Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Acrolein Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
44.00
8.5
6.03
3.30
11.0
11.8
2.70
0.0764
58.00
2.3
1.63
0.68
2.25
2.43
0.732
0.0207
56.00
1.9
1.35
0.579
1.93
2.08
0.605
0.0171
44.00
28.0
20.7
11.3
52.3
58.8
8.86
0.228
58.00
11.4
8.44
3.50
16.2
18.2
3.61
0.0929
56.00
7.9
5.85
2.51
11.6
13.0
2.50
0.0644
44.00
11.9
9.10
4.98
15.3
16.6
3.77
0.0973
58.00
3.1
2.37
0.98
3.03
3.28
0.981
0.0254
56.00
2.7
2.07
0.887
2.73
2.96
0.855
0.0221
* 68" F ( 20*C) — 29.92 Inches of Mercury (Hg)
A-2
ENTROPY
-------
FIELD DATA AND RESULTS TABULATION
(Revised Data for LI-1)
PLANT: Georgia-Pacific Corporation, Skippers, VA
SAMPLING LOCATION: Lower Prequench Inlet
LI-M0011-1 LI-M0011-2 LI-M0011-3
fwt
mg
mg/DSCM
ppmvd
ppm@12%CO2
ppm@7%O2
Ib/hr
Ib/ton
fwt
mg
mg/DSCM
ppmvd
ppm@12%CO2
ppm@7%O2
Ib/hr
Ib/ton
fwt
mg
mg/DSCM
ppmvd
ppm@12%CO2
ppm@7%O2
Ib/hr
Ib/ton
Benzaldehyde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Butylaldehyde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Crotonaldehyde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7%"O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
106.00
< 0.1 <
< 0.0709 <
< 0.0161 <
< 0.0536 <
< 0.0578 <
< 0.0318 <
< 0.000899 <
72.00
0.37
0.262
0.0877
0.292
0.315
0.118
0.00333
70.00
0.66
0.468
0.161
0.536
0.577
0.210
0.00593
106.00
0.1 <
0.0740 <
0.0168 <
0.0776 <
0.0871 <
0.0316 <
0.000815 <
72.00
1.23
0.911
0.304
1.40
1.58
0.389
0.0100
70.00
2.58
1.91
0.656
3.03
3.40
0.816
0.0210
106.00
0.1
0.0765
0.0174
0.0534
0.0579
0.0317
0.000818
72.00
0.14
0.107
0.0358
0.110
0.119
0.0443
0.00114
70.00
0.42
0.321
0.110
0.340
0.368
0. 133
0.00343
* 68' F ( 20"C) — 29.92 Inches of Mercury (Hg)
A-3
ENTROPY
-------
FIELD DATA AND RESULTS TABULATION
(Revised Data for LI-1)
PLANT: Georgia-Pacific Corporation, Skippers, VA
SAMPLING LOCATION: Lower Prequench Inlet
LI-M0011-1 LI-M0011-2 LI-M0011-3
fwt
mg
mg/DSCM
ppmvd
ppm@12%C02
ppm@7%O2
Ib/hr
Ib/ton
fwt
mg
mg/DSCM
ppmvd
ppm@12%C02
ppm@7%O2
Ib/hr
Ib/ton
fwt
mg
mg/DSCM
ppmvd
ppm@12%CO2
ppm@7%O2
Ib/hr
Ib/ton
Dimethvlbenzaldehvde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Formaldehyde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Hexaldehyde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
134.00
0.65
0.461
0.0827
0.276
0.297
0.207
0.00584
30.00
27.4
19.4
15.6
51.9
55.9
8.72
0.246
100.00
< 0.1 <
< 0.0709 <
< 0.0171 <
< 0.0569 <
< 0.0612 <
< 0.0318 <
< 0.000899 <
134.00
0.04
0.0296
0.00532
0.0245
0.0276
0.0127
0.000326
30.00
78.0
57.8
46.3
214
240
24.7
0.636
100.00
0.1
0.0740
0.0178
0.0822
0.0924
0.0316
0.000815
134.00
< 0.1
< 0.0765
< 0.0137
< 0.0422
< 0.0458
< 0.0317
< 0.000818
30.00
41.2
31.5
25.3
77.7
84.2
13.0
0.337
100.00
< 0.1
< 0.0765
< 0.0184
< 0.0566
< 0.0613
< 0.0317
< 0.000818
68' F ( 20'C) — 29.92 Inches of Mercury (Hg)
A-4
ENTROPY
-------
FIELD DATA AND RESULTS TABULATION
(Revised Data for LI-1)
PLANT: Georgia-Pacific Corporation, Skippers, VA
SAMPLING LOCATION: Lower Prequench Inlet
LI-M0011-1 LI-M0011-2 LI-M0011-3
fwt
mg
mg/DSCM
ppmvd
ppm@12%CO2
ppm@7%O2
Ib/hr
Ib/ton
fwt
mg
mg/DSCM
ppmvd
ppm@12%C02
ppm@7%O2
Ib/hr
Ib/ton
fwt
mg
mg/DSCM
ppmvd
ppm@12%C02
ppm@7%O2
Ib/hr
Ib/ton
* 68* F (
Propionaldehyde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Tolualdehyde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams <
Concentration, mg/DSCM* <
Concentration, ppmvd <
Concentration, ppmvd at 12% CO2 <
Concentration, ppmvd at 7% O2 <
Emission Rate, Ib/hr <
Emission Rate, Ib/ton <
Valeraldehyde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams <
Concentration, mg/DSCM* <
Concentration, ppmvd <
Concentration, ppmvd at 12% CO2 <
Concentration, ppmvd at 7% O2 <
Emission Rate, Ib/hr <
Emission Rate, Ib/ton <
20*C) — 29.92 Inches of Mercury (Hg)
58.00
0.45
0.319
0.132
0.441
0.475
0.143
0.00405
120.00
0.1 <
0.0709 <
0.0142 <
0.0474 <
0.0510 <
0.0318 <
0.000899 <
86.00
0.1 <
0.0709 <
0.0198 <
0.0661 <
0.0712 <
0.0318 <
0.000899 <
58.00
1.7
1.26
0.522
2.41
2.71
0.538
0.0139
120.00
0.1 <
0.0740 <
0.0148 <
0.0685 <
0.0770 <
0.0316 <
0.000815 <
86.00
0.1 <
0.0740 <
0.0207 <
0.0956 <
0.1074 <
0.0316 <
0.000815 <
58.00
1.6
1.22
0.508
1.56
1.69
0.506
0.0131
120.00
0.1
0.0765
0.0153
0.0472
0.0511
0.0317
0.000818
86.00
0.1
0.0765
0.0214
0.0658
0.0713
0.0317
0.000818
A-5
ENTROPY
-------
FIELD DATA AND RESULTS TABULATION
PLANT: Georgia-Pacific Corporation, Skippers, VA
SAMPLING LOCATION: Lower Prequench Inlet
Test Date
Run Start Time
Run Finish Time
Net Traversing Points
Theta Net Run Time, Minutes
Dia Nozzle Diameter, Inches
Cp Pitot Tube Coefficient
Y Dry Gas Meter Calibration Factor
Pbar Barometric Pressure, Inches Hg
Delta-H Avg. Pressure Differential of
Orifice Meter, Inches H2O
Vm Volume Of Metered Gas Sample, Dry ACF
tm Dry Gas Meter Temperature, Degrees F
Vmstd Volume Of Metered Gas Sample, Dry SCF*
Vic Total Liquid Collected In
Impingers & Silica Gel, grams
Vwstd Volume of Water Vapor, SCF*
%H2O Moisture Content, Percent by Volume
Mfd Dry Mole Fraction
%CO2 Carbon Dioxide, Percent By Volume, Dry
%O2 Oxygen, Percent By Volume, Dry
%CO+N2 CO + N2, Percent By Volume, Dry
Md Gas Molecular Weight, Lb/Lb-Mole, Dry
Ms Gas Molecular Weight, Lb/Lb-Mole, Wet
Pg Flue Gas Static Pressure, Inches H2O
PB Absolute Flue Gas Pressure, Inches Hg
ts Flue Gas Temperature, Degrees F
Delta-p Average Velocity Head, Inches H2O
vs Flue Gas Velocity, Feet/Second
A Stack/Duct Area, Square Inches
Qsd Volumetric Air Flow Rate, Dry SCFM*
Qmsd Volumetric Air Flow Rate, Dry SCMH*
Qaw Volumetric Air Flow Rate, Wet ACFM
Qmaw Volumetric Air Flow Rate, Wet ACMH
%I Isokinetic Sampling Rate, Percent
ton/hr Average Process Feed Rate, ton/hr
* 68° F ( 20"C) — 29.92 Inches of Mercury (Hg)
A-6
LI-M0011-1
6/25/91
1014
1340
32
80.00
0.191
0.84
1.0050
29.90
1.49
51.947
95
49.796
208.5
9.814
16.5
0.835
3.6
17.1
79.3
29.26
27.41
-15.50
28.76
203
1.7005
85.89
5,542
126,824
215,499
198,323
336,991
94.9
35.4
LI-M0011-2
6/25/91
1715
2015
32
80.00
0.191
0.84
1.0050
29.90
1.33
49.592
93
47.691
287.0
13.509
22.1
0.779
2.6
18.3
79.1
29.15
26.69
-15.00
28.80
200
1.5298
82.31
5,542
114,045
193,785
190,070
322,967
101.1
38.8
LI-M0011-3
6/26/91
930
1141
32
80.00
0.191
0.84
1.0050
29.90
1.24
47.933
92
46.169
265.0
12.474
21.3
0.787
3.9
16.8
79.3
29.30
26.89
-16.00
28.72
208
1.4380
80.08
5,542
110,471
187,712
184,917
314,211
101.0
38.7
ENTROPY
-------
FIELD DATA AND RESULTS TABULATION
PLANT: Georgia-Pacific Corporation, Skippers, VA
SAMPLING LOCATION: Lower Prequench Inlet
LI-M0011-1 LI-M0011-2 LI-M0011-3
fwt
mg
mg/DSCM
ppmvd
ppm@12%C02
ppm@7%O2
Ib/hr
Ib/ton
fwt
mg
mg/DSCM
ppmvd
ppm@12%CO2
ppm@7%O2
Ib/hr
Ib/ton
fwt
mg
mg/DSCM
ppmvd
ppm@12%CO2
ppm@7%O2
Ib/hr
Ib/ton
Acetaldehyde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Acetone Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Acrolein Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
44.00
8.5
6.03"
3.30
11.0
11.8
2.86
0.0809
58.00
2.3
1.63
0.68
2.25
2.43
0.775
0.0219
56.00
1.9
1.35
0.579
1.93
2.08
0.640
0.0181
44.00
28.0
20.7
11.3
52.3
58.8
8.86
0.228
58.00
11.4
8.44
3.50
16.2
18.2
3.61
0.0929
56.00
7.9
5.85
2.51
11.6
13.0
2.50
0.0644
44.00
11.9
9.10
4.98
15.3
16.6
3.77
0.0973
58.00
3.1
2.37
0.98
3.03
3.28
0.981
0.0254
56.00
2.7
2.07
0.887
2.73
2.96
0.855
0.0221
68' F ( 20'C) — 29.92 Inches of Mercury (Hg)
A-7
ENTROPY
-------
FIELD DATA AND RESULTS TABULATION
PLANT: Georgia-Pacific Corporation, Skippers, VA
SAMPLING LOCATION: Lower Prequench Inlet
LI-M0011-1 LI-M0011-2 LI-M0011-3
fwt
mg
mg/DSCM
ppmvd
ppm@12%CO2
ppm@7%O2
Ib/hr
Ib/ton
fwt
mg
mg/DSCM
ppmvd
ppm@12%CO2
ppm@7%O2
Ib/hr
Ib/ton
fwt
mg
mg/DSCM
ppmvd
ppm@12%C02
ppm@7%O2
Ib/hr
Ib/ton
Benzaldehyde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Butylaldehyde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Crotonaldehyde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
106.00
< 0.1 <
< 0.0709 <
< 0.0161 <
< 0.0536 <
< 0.0578 <
< 0.0337 <
< 0.000952 <
72.00
0.37
0.262
0.0877
0.292
0.315
0.125
0.00352
70.00
0.66
0.468
0.161
0.536
0.577
0.222
0.00628
106.00
0.1 <
0.0740 <
0.0168 <
0.0776 <
0.0871 <
0.0316 <
0.000815 <
72.00
1.23
0.911
0.304
1.40
1.58
0.389
0.0100
70.00
2.58
1.91
0.656
3.03
3.40
0.816
0.0210
106.00
0.1
0.0765
0.0174
0.0534
0.0579
0.0317
0.000818
72.00
0.14
0.107
0.0358
0.110
0.119
0.0443
0.00114
70.00
0.42
0.321
0.110
0.340
0.368
0.133
0.00343
* 68' F ( 20'C) — 29.92 Inches of Mercury (Hg)
A-f
ENTROPY
-------
FIELD DATA AND RESULTS TABULATION
PLANT: Georgia-Pacific Corporation, Skippers, VA
SAMPLING LOCATION: Lower Prequench Inlet
LI-M0011-1 LI-M0011-2 LI-M0011-3
fwt
mg
mg/DSCM
ppmvd
ppm@12%C02
ppm@7%O2
Ib/hr
Ib/ton
fwt
mg
mg/DSCM
ppmvd
ppm@12%C02
ppm@7%O2
Ib/hr
Ib/ton
fwt
mg
mg/DSCM
ppmvd
ppm@12%C02
ppm@7%O2
Ib/hr
Ib/ton
Dimethvlbenzaldehvde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Formaldehyde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Hexaldehyde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
134.00
0.65
0.461
0.0827
0.276
0.297
0.219
0.00619
30.00
27.4
19.4
15.6
51.9
55.9
9.23
0.261
100.00
< 0.1 <
< 0.0709 <
< 0.0171 <
< 0.0569 <
< 0.0612 <
< 0.0337 <
< 0.000952 <
134.00
0.04 <
0.0296 <
0.00532 <
0.0245 <
0.0276 <
0.0127 <
0.000326 <
30.00
78.0
57.8
46.3
214
240
24.7
0.636
100.00
0.1 <
0.0740 <
0.0178 <
0.0822 <
0.0924 <
0.0316 <
0.000815 <
134.00
0.1
0.0765
0.0137
0.0422
0.0458
0.0317
0.000818
30.00
41.2
31.5
25.3
77.7
84.2
13.0
0.337
100.00
0.1
0.0765
0.0184
0.0566
0.0613
0.0317
0.000818
68' F ( 20'C) — 29.92 Inches of Mercury (Hg)
A-9
ENTROPY
-------
FIELD DATA AND RESULTS TABULATION
PLANT: Georgia-Pacific Corporation, Skippers, VA
SAMPLING LOCATION: Lower Prequench Inlet
LI-M0011-1 LI-M0011-2 LI-M0011-3
fwt
mg
mg/DSCM
ppravd
ppm@12%CO2
ppm@7%O2
Ib/hr
Ib/ton
fwt
mg
mg/DSCM
ppmvd
ppm@12%CO2
ppm@7%O2
Ib/hr
Ib/ton
fwt
mg
mg/DSCM
ppmvd
ppm@12%CO2
ppm@7%O2
Ib/hr
Ib/ton
* 68' F (
Propionaldehyde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Tolualdehyde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams <
Concentration, mg/DSCM* <
Concentration, ppmvd <
Concentration, ppmvd at 12% CO2 <
Concentration, ppmvd at 7% O2 <
Emission Rate, Ib/hr <
Emission Rate, Ib/ton <
Valeraldehyde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams <
Concentration, mg/DSCM* <
Concentration, ppmvd <
Concentration, ppmvd at 12% CO2 <
Concentration, ppravd at 7% O2 <
Emission Rate, Ib/hr <
Emission Rate, Ib/ton <
20"C) — 29.92 Inches of Mercury (Hg)
58.00
0.45
0.319
0.132
0.441
0.475
0.152
0.00428
120.00
0.1 <
0.0709 <
0.0142 <
0.0474 <
0.0510 <
0.0337 <
0.000952 <
86.00
0.1 <
0.0709 <
0.0198 <
0.0661 <
0.0712 <
0.0337 <
0.000952 <
58.00
1.7
1.26
0.522
2.41
2.71
0.538
0.0139
120.00
0.1 <
0.0740 <
0.0148 <
0.0685 <
0.0770 <
0.0316 <
0.000815 <
86.00
0.1 <
0.0740 <
0.0207 <
0.0956 <
0.1074 <
0.0316 <
0.000815 <
58.00
1.6
1.22
0.508
1.56
1.69
0.506
0.0131
120.00
0.1
0.0765
0.0153
0.0472
0.0511
0.0317
0.000818
86.00
0. 1
0.0765
0.0214
0.0658
0.0713
0.0317
0.000818
A-l 0
ENTROPY
-------
FIELD DATA AND RESULTS TABULATION
PLANT: Georgia-Pacific Corporation, Skippers, VA
SAMPLING LOCATION: Stack
Test Date
Run Start Time
Run Finish Time
Net Traversing Points
Theta Net Run Time, Minutes
Dia Nozzle Diameter, Inches
Cp Pitot Tube Coefficient
Y Dry Gas Meter Calibration Factor
Pbar Barometric Pressure, Inches Hg
Delta-H Avg. Pressure Differential of
Orifice Meter, Inches H2O
Vm Volume Of Metered Gas Sample, Dry ACF
tm Dry Gas Meter Temperature, Degrees F
Vmstd Volume Of Metered Gas Sample, Dry SCF*
Vic Total Liquid Collected In
Impingers & Silica Gel, grams
Vwstd Volume of Water Vapor, SCF*
%H2O Moisture Content, Percent by Volume
Mfd Dry Mole Fraction
%CO2 Carbon Dioxide, Percent By Volume, Dry
%O2 Oxygen, Percent By Volume, Dry
%CO+N2 CO -t- N2, Percent By Volume, Dry
Md Gas Molecular Weight, Lb/Lb-Mole, Dry
Ms Gas Molecular Weight, Lb/Lb-Mole, Wet
Pg Flue Gas Static Pressure, Inches H2O
Pa Absolute Flue Gas Pressure, Inches Hg
ts Flue Gas Temperature, Degrees F
Delta-p Average Velocity Head, Inches H2O
vs Flue Gas Velocity, Feet/Second
A Stack/Duct Area, Square Inches
Qsd Volumetric Air Flow Rate, Dry SCFM*
Qmsd Volumetric Air Flow Rate, Dry SCMH*
Qaw Volumetric Air Flow Rate, Wet ACFM
Qmaw Volumetric Air Flow Rate, Wet ACMH
%I Isokinetic Sampling Rate, Percent
ton/hr Process Feed Rate, ton/hr
* 68° F ( 20°C) — 29.92 Inches of Mercury (Hg)
A-1 1
S-M0011-1 i
6/25/91
1014
1342
32
80.00
0.248
0.84
1.0055
29.80
1.33
50.395
107
47.133
273.0
12.850
21.4
0.786
3.5
17.2
79.3
29.25
26.84
0.00
29.80
144
0.5228
45.12
9,161
117,835
200,225
172,237
292,665
94.8
35.4
S-M0011-2 i
6/25/91
1753
2005
32
80.00
0.248
0.84
1.0055
29.80
1.18
47.620
95
45.484
277.5
13.062
22.3
0.777
3.6
16.9
79.5
29.25
26.74
0.00
29.80
146
0.4912
43.89
9,161
112,945
191,916
167,529
284,665
95.5
38.8
S-M0011-3
6/26/91
930
1143
32
80.00
0.248
0.84
1.0055
29.80
1.25
49.150
104
46.204
290.5
13.674
22.8
0.772
3.5
17.2
79.3
29.25
26.68
0.00
29.80
148
0.5115
44.91
9,161
114,420
194,423
171,437
291,306
95.7
38.7
ENTROPY
-------
FIELD DATA AND RESULTS TABULATION
PLANT: Georgia-Pacific Corporation, Skippers, VA
SAMPLING LOCATION: Stack
S-M0011-1 S-M0011-2 S-M0011-3
fwt
mg
mg/DSCM
ppmvd
ppm@12%CO2
ppm@7%O2
Ib/hr
Ib/ton
fwt
mg
mg/DSCM
ppmvd
ppm@12%CO2
ppm@7%O2
Ib/hr
Ib/ton
fwt
mg
mg/DSCM
ppmvd
ppm@12%CO2
ppm@7%O2
Ib/hr
Ib/ton
Acetaldehvde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Acetone Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Acrolein Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
44.00
8.1
6.07
3.32
11.4
12.2
2.68
0.0757
58.00
2.8
2.10
0.870
2.98
3.21
0.926
0.0262
56.00
2.9
2.17
0.933
3.20
3.44
0.959
0.0271
44.00
12.2
9.47
5.18
17.3
17.7
4.01
0.103
58.00
4.4
3.42
1.42
4.72
4.84
1.45
0.0372
56.00
4.0
3.11
1.33
4.45
4.56
1.31
0.0339
44.00
10.7
8.18
4.47
15.3
16.5
3.51
0.0906
58.00
3.7
2.83
1.17
4.02
4.32
1.212
0.0313
56.00
4.0
3.06
1.31
4.50
4.84
1.31
0.0339
68" F ( 20"C) — 29.92 Inches of Mercury (Hg)
A-12
ENTROPY
-------
FIELD DATA AND RESULTS TABULATION
PLANT: Georgia-Pacific Corporation, Skippers, VA
SAMPLING LOCATION: Stack
S-M0011-1 S-M0011-2 S-M0011-3
fwt
rag
mg/DSCM
ppmvd
ppm@12%CO2
ppm@7%O2
Ib/hr
Ib/ton
fwt
mg
mg/DSCM
ppmvd
ppm@12%C02
ppm@7%O2
Ib/hr
Ib/ton
fwt
mg
mg/DSCH
ppmvd
ppm@12%C02
ppm@7%O2
Ib/hr
Ib/ton
Benzaldehvde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Butylaldehyde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Crotonaldehyde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
106.00
< 0.1
< 0.0749
< 0.0170
< 0.0583
< 0.0626
< 0.0331
< 0.000934
72.00
0.39
0.292
0.0976
0.335
0.360
0.129
0.00364
70.00
1.38
1.03
0.355
1.22
1.31
0.456
0.0129
106.00
< 0.1 <
< 0.0776 <
< 0.0176 <
< 0.0587 <
< 0.0602 <
< 0.0328 <
< 0.000847 <
72.00
1.83
1.42
0.475
1.58
1.62
0.601
0.0155
70.00
0.86
0.668
0.229
0.765
0.783
0.282
0.00728
106.00
0.1
0.0764
0.0173
0.0595
0.0639
0.0328
0.000846
72.00
0.46
0.352
0.117
0.403
0.433
0.151
0.00389
70.00
1.68
1.28
0.441
1.51
1.63
0.550
0.0142
68' F ( 20'C) -- 29.92 Inches of Mercury (Hg)
A-13
ENTROPY
-------
FIELD DATA AND RESULTS TABULATION
PLANT: Georgia-Pacific Corporation, Skippers, VA
SAMPLING LOCATION: Stack
S-M0011-1 S-M0011-2 S-M0011-3
fwt
mg
mg/DSCM
ppmvd
ppm@12%CO2
ppm@7%O2
Ib/hr
Ib/ton
fwt
mg
mg/DSCM
ppmvd
ppm@12%C02
ppm@7%O2
Ib/hr
Ib/ton
fwt
mg
mg/DSCM
ppmvd
ppm@12%CO2
ppm@7%O2
Ib/hr
Ib/ton
Dimethvlbenzaldehvde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Formaldehyde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Hexaldehyde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
134.00
< 0.1 <
< 0.0749 <
< 0.0134"<
< 0.0461 <
< 0.0496 <
< 0.0331 <
< 0.000934 <
30.00
32.3
24.2
19.4
66.5
71.5
10.7
0.302
100.00
< 0.1 <
< 0.0749 <
< 0.0180 <
< 0.0618 <
< 0.0664 <
< 0.0331 <
< 0.000934 <
134.00
0.1 <
0.0776 <
0.0139 <
0.0465 <
0.0476 <
0.0328 <
0.000847 <
30.00
41.4
32.1
25.8
85.9
88.0
13.6
0.350
100.00
0.1 <
0.0776 <
0.0187 <
0.0623 <
0.0638 <
0.0328 <
0.000847 <
134.00
0.1
0.0764
0.0137
0.0470
0.0505
0.0328
0.000846
30.00
19.7
15.1
12.1
41.4
44.5
6.45
0.167
100.00
0.1
0.0764
0.0184
0.0630
0.0677
0.0328
0.000846
68' F ( 20°C) — 29.92 Inches of Mercury (Hg)
A-1 4
ENTROPY
-------
FIELD DATA AND RESULTS TABULATION
PLANT: Georgia-Pacific Corporation, Skippers, VA
SAMPLING LOCATION: Stack
S-M0011-1 S-M0011-2 S-M0011-3
fwt
mg
mg/DSCM
ppmvd
ppm@12%CO2
ppm@7%O2
Ib/hr
Ib/ton
fwt
mg
mg/DSCM
ppmvd
ppm@12%CO2
ppm@7%O2
Ib/hr
Ib/ton
fwt
mg
mg/DSCM
ppmvd
ppm@12%C02
ppm@7%O2
Ib/hr
Ib/ton
Propionaldehvde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Tolualdehyde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppmvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Valeraldehyde Results
Formula Weight, Ib/lb-mole
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, ppmvd
Concentration, ppmvd at 12% CO2
Concentration, ppcnvd at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
58.00
1.1
0.824
0.342
1.17
1.26
0.364
0.0103
120.00
< 0.1 <
< 0.0749 <
< 0.0150 <
< 0.0515 <
< 0.0553 <
< 0.0331 <
< 0.000934 <
86.00
1.13
0.847
0.237
0.812
0.872
0.374
0.0106
58.00
0.78
0.606
0.251
0.837
0.858
0.256
0.00660
120.00
0.1 <
0.0776 <
0.0156 <
0.0519 <
0.0531 <
0.0328 <
0.000847 <
86.00
0.15
0.116
0.033
0.109
0. Ill
0.0493
0.00127
58.00
1.28
0.978
0.406
1.39
1.49
0.419
0.0108
120.00
0.1
0.0764
0.0153
0.0525
0.0564
0.0328
0.000846
86.00
1.26
0.963
0.269
0.924
0.992
0.413
0.0107
68' F ( 20'C) — 29.92 Inches of Mercury (Hg]
A-15
ENTROPY
-------
APPENDIX B. Method 5/202 Data Summary
-------
FIELD DATA AND RESULTS TABULATION
PLANT: Georgia-Pacific Corporation, Skippers, VA
SAMPLING LOCATION: Lower Prequench Inlet
Test Date
Run Start Time
Run Finish Time
Net Traversing Points
Theta Net Run Time, Minutes
Dia Nozzle Diameter, Inches
Cp Pitot Tube Coefficient
Y Dry Gas Meter Calibration Factor
Pbar Barometric Pressure, Inches Hg
Delta-H Avg. Pressure Differential of
Orifice Meter, Inches H2O
Vm Volume Of Metered Gas Sample, Dry ACF
tm Dry Gas Meter Temperature, Degrees F
Vmstd Volume Of Metered Gas Sample, Dry SCF*
Vic Total Liquid Collected In
Impingers & Silica Gel, grams
Vwstd Volume of Water Vapor, SCF*
%H2O Moisture Content, Percent by Volume
Mfd Dry Mole Fraction
%CO2 Carbon Dioxide, Percent By Volume, Dry
%O2 Oxygen, Percent By Volume, Dry
%CO+N2 CO + N2, Percent By Volume, Dry
Md Gas Molecular Weight, Lb/Lb-Mole, Dry
Ms Gas Molecular Weight, Lb/Lb-Mole, Wet
Pg Flue Gas Static Pressure, Inches H2O
Ps Absolute Flue Gas Pressure, Inches Hg
ta Flue Gas Temperature, Degrees F
Delta-p Average Velocity Head, Inches H2O
vs Flue Gas Velocity, Feet/Second
A Stack/Duct Area, Square Inches
Qsd Volumetric Air Flow Rate, Dry SCFM*
Qmsd Volumetric Air Flow Rate, Dry SCMH*
Qaw Volumetric Air Flow Rate, Wet ACFM*
Qmaw Volumetric Air Flow Rate, Wet ACMH*
%I Isokinetic Sampling Rate, Percent
ton/hr Process feed rate, ton/hr
* 68° F ( 20° C) — 29.92 Inches of Mercury (Hg)
ENTROPY
LI-M5/202-1
6/25/91
1015
1340
32
80.00
0.223
0.84
1.0026
29.90
2.12
63.918
97
61.024
365.5
17.204
22.0
0.780
3.6
17.1
79.3
29.26
26.78
-15.50
28.76
198
1.4588
80.17
5,542
111,376
189,250
185,123
314,561
97.2
35.4
LI-M5/202-2
6/25/91
1753
2007
32
80.00
0.185
0.84
1.0026
29.90
1.06
47.198
95
45.106
286.5
13.486
23.0
0.770
2.6
18.3
79,1
29.15
26.59
-15.50
28.76
188
1. 534
81.87
5,542
114,018
193,739
189,059
321,249
102.0
38.8
LI-M5/202-3
6/26/91
930
1141
32
80.00
0,182
0.84
1.0026
29.90
1.03
46.231
96
44.099
289.5
13.627
23.6
0.764
3.9
16.8
79.3
29.30
26.63
-15.50
28.76
200
1.5744
83.65
5,542
113,478
192,821
193,152
328,204
103.5
38.7
-------
FIELD DATA AND RESULTS TABULATION
PLANT: Georgia-Pacific Corporation, Skippers, VA
SAMPLING LOCATION: Lower Prequench Inlet
LI-M5/202-1 LI-M5/202-2 LI-M5/202-3
mg
mg/DSCM
gr/DSCF
gr@12%C02
gr@7%O2
Ib/hr
Ib/ton
mg
mg/DSCM
gr/DSCF
gr@12%CO2
gr@7%O2
Ib/hr
Ib/ton
mg
mg/DSCM
gr/DSCF
gr@12%CO2
gr@7%O2
Ib/hr
Ib/ton
mg
mg/DSCM
gr/DSCF
gr@12%CO2
gr@7%O2
Ib/hr
Ib/ton
Part icu late Results
Filterable
Catch Weight, milligrams
Concentration, mg/DSCM
Concentration, grains/DSCF*
Concentration, gr/DSCF at 12% CO2
Concentration, gr/DSCF at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Condensable - Organic
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, grains/DSCF*
Concentration, gr/DSCF at 12% CO2
Concentration, gr/DSCF at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Condensable - Inorganic
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, grains/DSCF*
Concentration, gr/DSCF at 12% CO2
Concentration, gr/DSCF at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Backup Filter
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, grains/DSCF*
Concentration, gr/DSCF at 12% CO2
Concentration, gr/DSCF at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
427". 8
248
0.108
0.361
0.388
103
2.92
23.7
14
0.00599
0.0200
0.0215
5.72
0.162
88.9
51
0.0225
0.0749
0.0807
21.5
0.606
0.0
0
0.0
0.0
0.0
0.0
0.0
425.8
333
0.146
0.672
0.755
142
3.67
29.4
23
0.0101
0.0464
0.0522
9.83
0.253
89.3
70
0.0306
0.1410
0.1584
29.9
0.770
0.0
0
0.0
0.0
0.0
0.0
0.0
457.0
366
0.160
0.492
0.533
156
4.02
44.5
36
0.0156
0.0479
0.0519
15.1
0.391
108.7
81
0 . 0380
0.1170
0.1268
37.0
0.956
0.0
0
o.o
0,0
0.0
o.o
o.o
68'
F ( 20" C) — 29.92 Inches of Mercury (Hg)
ENTROPY
B-2
-------
FIELD DATA AND RESULTS TABULATION
PLANT: Georgia-Pacific Corporation, Skippers, VA
SAMPLING LOCATION: Lower Preguench Inlet
LI-M5/202-1 LI-M5/202-2 LI-M5/202-3
Total Particulate
mg Catch Weight, milligrams
mg/DSCM Concentration, mg/DSCM*
gr/DSCF Concentration, grains/DSCF*
gr@12%CO2 Concentration, gr/DSCF at 12% CO2
gr@7%O2 Concentration, gr/DSCF at 7% O2
Ib/hr Emission Rate, Ib/hr
Ib/ton Emission Rate, Ib/ton
* 68° F ( 20° C) — 29.92 Inches of Mercury (Hg)
540.4
313
0.137
0.456
0.491
130
3.69
544.5
426
0.186
0.860
0.966
182
4.69
610.2
489
0.214
0.657
0.712
208
5.37
B-3
ENTROPY
-------
FIELD DATA AND RESULTS TABULATION
PLANT: Georgia-Pacific Corporation, Skippers, VA
SAMPLING LOCATION: Stack
S-M5/202-1 S-M5/202-2 S-M5/202-3
Theta
Dia
Cp
Y
Pbar
Delta-H
Vm
tm
Vmstd
Vic
Vwstd
%H2O
Mfd
%CO2
%02
%CO+N2
Md
Ms
Pg
Ps
ts
Delta-p
vs
A
Qsd
Qmsd
Qaw
Qmaw
Test Date
Run Start Time
Run Finish Time
Net Traversing Points
Net Run Time, Minutes
Nozzle Diameter, Inches
Pitot Tube Coefficient
Dry Gas Meter Calibration Factor
Barometric Pressure, Inches Hg
Avg. Pressure Differential of
Orifice Meter, Inches H2O
Volume Of Metered Gas Sample, Dry ACF
Dry Gas Meter Temperature, Degrees F
Volume Of Metered Gas Sample, Dry SCF*
Total Liquid Collected In
Impingers & Silica Gel, grams
Volume of Water Vapor, SCF*
Moisture Content, Percent by Volume
From Measured Water Catch
Saturation at Flue Gas Temperature
Dry Mole Fraction
Carbon Dioxide, Percent By Volume, Dry
Oxygen, Percent By Volume, Dry
CO + N2, Percent By Volume, Dry
Gas Molecular Weight, Lb/Lb-Mole, Dry
Gas Molecular Weight, Lb/Lb-Mole, Wet
Flue Gas Static Pressure, Inches H2O
Absolute Flue Gas Pressure, Inches Hg
Flue Gas Temperature, Degrees F
Average Velocity Head, Inches H2O
Flue Gas Velocity, Feet/Second
Stack/Duct Area, Square Inches
Volumetric Air Flow Rate, Dry SCFM*
Volumetric Air Flow Rate, Dry SCMH*
Volumetric Air Flow Rate, Wet ACFM
Volumetric Air Flow Rate, Wet ACMH
6/25/91
1014
1342
32
80.00
0.254
0.84
1.0114
29.80
1.26
50.537
90
49.024
283.5
13.344
21.4
22.4 **
0.776
3.5
17.2
79.3
29.25
26.73
-20.00
28.33
143
0.4655
43.72
9,161
107,413
182,515
166,881
283,565
6/25/91
1753
2005
32
80.00
0.254
0.84
1.0114
29.80
1.35
52.019
97
49.838
307.5
14.474
22.5
21.8 **
0.782
3.6
16.9
79.5
29.25
26.80
0.00
29.80
144
0.4799
43.26
9,161
112,428
191,038
165,143
280,610
6/26/91
930
1141
32
80.00
0.261
0.84
1.0114
29.80
1.63
56.247
92
54.415
347.0
16.333
23.1
22..**
0.776
3.5
17.2
79.3
29.25
26.73
0.00
29.80
145
0.5324
45.66
9,161
117,621
199,861
174,300
296,170
* 68° F ( 20° C) -- 29.92 Inches of Mercury (Hg)
** Actual %H2O used in Calculations
B-4
ENTROPY
-------
FIELD DATA AND RESULTS TABULATION
PLANT: Georgia-Pacific Corporation, Skippers, VA
SAMPLING LOCATION: Stack
%I
ton/hr
mg
mg/DSCM
gr/DSCF
gr@12%CO2
gr@7%02
Ib/hr
Ib/ton
mg
mg/DSCM
gr/DSCF
gr@12%CO2
gr@7%02
Ib/hr
Ib/ton
mg
mg/DSCM
gr/DSCF
gr@12%C02
gr@7%O2
Ib/hr
Ib/ton
mg
mg/DSCM
gr/DSCF
gr@12%C02
gr@7%02
Ib/hr
Ib/ton
Isokinetic Sampling Rate, Percent
Average Process Feed Rate, ton/hr
Particulate Results
Filterable
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, grains/DSCF*
Concentration, gr/DSCF at 12% CO2
Concentration, gr/DSCF at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Condensable - Organic
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, grains/DSCF*
Concentration, gr/DSCF at 12% CO2
Concentration, gr/DSCF at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Condensable - Inorganic
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, grains/DSCF*
Concentration, gr/DSCF at 12% CO2
Concentration, gr/DSCF at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
Backup Filter
Catch Weight, milligrams
Concentration, mg/DSCM*
Concentration, grains/DSCF*
Concentration, gr/DSCF at 12% CO2
Concentration, gr/DSCF at 7% O2
Emission Rate, Ib/hr
Emission Rate, Ib/ton
S-M5/202-1
103.1
35.4
28.1
20.2
0.00885
0.0303
0.0326
8.14
0.230
14.1
10.2
0.00444
0.0152
0.0164
4.09
0.115
18.3
13.2
0.00576
0.0198
0.0212
5.30
0.150
0.0
0.0
0.0
0.0
0.0
0.0
0.0
S-M5/202-2
100.2
38.8
51.7
36.6
0.0160
0.0534
0.0547
15.4
0.398
22.7
16.1
0.00703
0.0234
0.0240
6.77
0.175
28.3
20.1
0.00876
0.0292
0.0299
8.44
0.218
0.0
0.0
0.0
0.0
0.0
0.0
0.0
S-M5/202-3
99.0
38.7
46.3
30.0
0.0131
0.0450
0.0484
13.2
0.342
19.1
12.4
0.00542
0.0186
0.0200
5.46
0.141
30.8
20.0
0.00874
0.0299
0.0322
8.81
0.228
0.0
0.0
0.0
0.0
0.0
0.0
0.0
* 68° F ( 20° C) — 29.92 Inches of Mercury (Hg)
ENTROPY
B-5
-------
FIELD DATA AND RESULTS TABULATION
PLANT: Georgia-Pacific Corporation, Skippers, VA
SAMPLING LOCATION: Stack
S-M5/202-1 S-M5/202-2 S-M5/202-3
Total Particulate
mg Catch Weight, milligrams
mg/DSCM Concentration, mg/DSCM*
gr/DSCF Concentration, grains/DSCF*
gr@12%CO2 Concentration, gr/DSCF at 12% CO2
gr@7%O2 Concentration, gr/DSCF at 7% O2
Ib/hr Emission Rate, Ib/hr
Ib/ton Emission Rate, Ib/ton
* 68° F ( 20° C) — 29.92 Inches of Mercury (Hg)
60.5
43.6
0.0190
0.0653
0.0702
17.5
0.495
102.7
72.8
0.0318
0.1060
0.109
30.6
0.790
96.2
62.4
0.0273
0.0935
0.101
27.5
0.711
B-6
ENTROPY
-------
APPENDIX C. Modified Method 5 Data Summary
-------
FIELD DATA AND RESULTS TABULATION
PLANT: Georgia-Pacific Corporation, Skippers, VA
LOCATION: Stack
RUN #
S-MM5-1
S-HM5-2
S-MM5-3
DATE
6/25/91
6/25/91
6/26/91
OPERATOR
Clyde E. Nack
Clyde E. Nack
Clyde i. Nack
Run Start Time
Run Finish Time
Net Traversing Points
Theta Net Run Time, Minutes
Dia Nozzle Diameter, Inches
Cp Pitot Tube Coefficient
Y Dry Gas Meter Calibration Factor
Pbar Barometric Pressure, Inches Hg
Delta-H Avg. Pressure Differential of
Orifice Meter, Inches HUO
Vm Volume Of Metered Gas Sample, Dry ACF
tm Dry Gas Meter Temperature, Degrees F
Vmstd Volume Of Metered Gas Sample, Dry SCF*
Vic Total Volume of Liquid Collected
in Impingers & Silica Gel, m-l
Vwstd Volume of Water Vapor, SCF*
y.HjO Moisture Content Percent by Volume
From Measured Water Catch
Saturation at Flue Gas Temperature
Mfd Dry Mole Fraction
XCO, Carbon Dioxide, Percent By Volume, Dry
XO-, Oxygen, Percent By Volume, Dry
Md Gas Molecular Weight, Ib/lb-Mole, Dry
Ms Gas Molecular Weight, Ib/lb-Mole, Wet
Pg Flue Gas Static Pressure, Inches HjO
PS Absolute Flue Gas Pressure, Inches Hg
ts Flue Gas Temperature, Degrees F
Delta-p Average Velocity Head, Inches 820
vs Flue Gas Velocity, feet/Second
A Stack/Duct Area, Square Inches
Qsd Volunetric Air Flow Rate, Dry SCFM*
Qaw Volumetric Air Flow Rate, Wet ACFM
XI Isokinetic Sampling Rate, Percent
S-MM5-1
. 1014
1342
32
80.00
0.268
0.840
1.0004
29.80
1.45
49.889
87
48.179
293.5
13.815
22.3
22.0**
0.780
3.5
17.2
29.25
26.77
0.0
29.80
144
0.4382
41.37
9,161
107,165
157,930
91.3
S-MM5-2
1753
2005
32
80.00
0.261
0.840
0.9903
29.80
1.44
52.762
102
49.104
315.0
14.827
23.2**
23.7
0.768
3.6
16.9
29.25
26.64
0.0
29.80
147
0.4721
43.15
9,161
109,560
164,713
95.9
S-MM5-3
0930
1143
32
80.00
0.290
0.840
0.9903
29.80
2.13
63.613
96
59.951
413.5
19.463
24.5
23.8**
0.762
3.5
17.2
29.25
26.58
0.0
29.80
147
0.4636
42.82
9,161
107,891
163,449
96.3
68° F ( 20° C) -- 29.92 Inches of Mercury (Hg)
ACTUAL %H20 USED IN CALCULATIONS
C-l
ENTROPY
(Continued next page)
-------
TABLE _._ SUMMARY OF MODIFIED METHOD 5 SAMPLING AND ANALYSIS FOR SEMIVOLATILE ORGANIC COMPOUND
O
I
Target Analyles
Phenol
bis(2-Chloroethyl)e(her
2-Chlorophenol
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
Benzyl alcohol
1 ,2-Dichlorobenzene
2-Methylphenol
bis<2-Chloroisopropyl)e(her
4-Methylphenol
N-Nitroso-di-n-propylamlne
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
Benzole acid
bls(2-Chloroethoxy)methane
2,4-Dichlorophenol
1 ,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobuladiene
4-Chloro-3-methylphenol
2-Methylnaphthalene
Hexachlorocyclopentadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dlmethylphthalate
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
Total Analyle Mass, ug
Reagent
Run 1 Run 2 Run 3 Blanks
< 15 < 95 < 13 < 3.2
< 14 <89 < 12 <2.9
< 16 < 10 < 13 < 3.4
< 29 < 18 < 26 < 6.8
< 16 < 10 < 14 < 3.5
< 47 < 30 < 40 < 10
< 19 < 12 < 17 < 4.3
< 30 < 19 < 26 < 6.7
< 15 < 10 < 13 < 3.3
< 30 < 19 < 26 < 6.7
< 40 < 26 < 33 < 8.3
< 57 < 36 < 51 < 13
< 15 < 11 < 13 < 3.9
< 1 1 < 8.0 < 9.3 < 2.9
< 48 < 35 < 36 < 11
< 24 < 18 < 21 < 6.7
< 49 < 36 < 38 < 11
< 13 < 99 < 12 < 3.7
< 22 < 17 < 20 < 6.3
< 19 < 15 < 18 < 5.7
< 7.5 < 5.7 d 890 d 426
< 16 < 12 < 16 < 5.0
< 45 < 34 < 43 < 14
< 21 < 16 < 18 < 5.7
< 9.6 < 7.3 < 9.0 < 2.8
< 25 < 19 < 25 < 6.6
< 21 < 16 < 21 < 5.5
< 19 < 14 < 19 < 5.0
< 7.5 < 5.8 < 7.8 < 2.1
< 14 < 11 < 13 < 3.3
< 5.8 < 4.5 < 5.9 < 1.6
< 4.3 < 3.3 < 4.4 < 1.2
< 18 < 14 < 18 < 4.8
< 8.1 < 6.2 < 8.3 < 2.2
< 87 < 67 < 71 < 18
Analyle Concentration and Mass Emission Rate
MM-5 Run 1
(ug/M3) (Ibs/hr)
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
MM-5 Run 2
(ug/M3) (Ibs/hr)
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
MM-5 Run 3
(ug/M3) (Ibs/hr)
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
524 0.212
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
3-Run Average
(ug/M3) (Ibs/hr)
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
175 0.070
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
(continued)
-------
TABLE _._ (Continued)
n
i
OJ
Target Analyles
4-Nitrophenol
Dibenzoluran
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diethylphthalate
4-Chlorophenyl-phenylether
Fluorene
4-Nitroaniline
4,6-Dinitro-2-methylphenol
N-Nitrosodiphenylamlne(1)
4-Bromophenyl-phenylether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butylphthalate
Fluoranthene
Pyrene
Butylbenzylphthalate
3,3'-Dichlorobenzldine
Benzo(a)anthracene
Chrysene
bis(2-Ethylhexyl)phthalate
Di-n-octylphthalate
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
lndeno(1 ,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Tolal Analyle Mass, ug
Reagent
Run 1 Run 2 Run 3 Blanks
< 49 < 38 < 46 < 12
< 4 3 < 3 3 < 4 4 < 1.2
< 16 < 12 < 15 < 4.0
< 31 < 24 < 30 < 7.9
e 19 e 6 e 8 < 1.5
< 9 6 < 7 4 < 9.8 < 2.6
< 5 7 < 4 4 < 5.9 < 1.6
< 25 < 19 < 26 < 7.1
< 34 < 26 < 24 < 6.3
< 65 < 4.8 < 6.3 < 1.7
< 11 < 8 1 < 10 < 2.9
< 10 < 7.5 < 10 < 2.8
< 19 < 14 < 15 < 4.0
< 28 < 2.1 < 2.7 < 0.7
< 30 < 23 < 2.9 < 0.8
e 89 e 10 e 9.7 d 13
< 1 7 < 1.3 < 1.6 < 0.4
< 1 4 < 1.0 < 1.5 < 0.4
e66 e 6.6 d 34 < 0.6
< 30 < 2.2 < 2.9 < 0.7
< 1.2 < 0.9 < 1.2 < 0.3
< 1 4 < 1.0 < 1.4 < 0.3
d 76 d 76 d 79 d 15
e 6.9 e 11 d 56 < 0.3
< 1.0 < 0.7 < 1.1 < 0.3
< 1.1 < 0.8 < 1.2 < 0.3
< 1.0 < 0.7 < 1.0 < 0.2
< 1.2 < 0.8 < 1.2 < 0.3
< 1.1 < 0.8 < 1.2 < 0.3
< 1.0 < 0.7 < 1.1 < 0.3
Analyte Concentration and Mass Emission Rate
MM-5 Run 1
(ug/M3) (Ibs/hr)
ND ND
ND ND
ND ND
ND ND
14.1 0.006
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
6.6 0.003
ND ND
ND ND
4.8 0.002
ND ND
ND ND
ND ND
55 0.022
5.1 0.002
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
MM-5 Run 2
(ug/M3) (Ibs/hr)
ND ND
ND ND
ND ND
ND ND
4.5 0.002
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
7.5 0.003
ND ND
ND ND
4.8 0.002
ND ND
ND ND
ND ND
54 0.022
8.2 0.003
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
MM-5 Run 3
(ug/M3) (Ibs/hr)
ND ND
ND ND
ND ND
ND ND
6.1 0.0025
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
5.7 0.002
ND ND
ND ND
20.2 0.008
ND ND
ND ND
ND ND
58 0.023
41 0.017
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
3-Run Average
(ug/M3) (Ibs/hr)
ND ND
ND ND
ND ND
ND ND
8.2 0.003
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
6.6 0.003
ND ND
ND ND
9.9 0.004
ND ND
ND ND
ND ND
56 0.022
18 0.007
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
DATA QUALIFIER SYMBOLS
< - not detected at less than amount shown
ND- not detected and a value ot zero used In averaging with any reported values
d - detected above quantifiable limit
e - estimated value for compound that was detected, but below quantifiable limit
-------
APPENDIX D. Method 25 Data Summary
-------
2-5
TABLE 2-4
TOTAL GASEOUS NONMETHANE ORGANICS TESTS SUMMARY
Upper Prequench Inlet
Test Date
Run Start Time
Run Finish Time
Flue Gas Parameters
CO2 , Percent By Volume, Dry
O2, Percent By Volume, Dry
Air Flow Rate, Dry SCFM*
Total Gaseous Nonmethane Orqanics
Concentration, ppmvd
Emission Rate, Ib/hr
UI-M25-1
6/25/91
1019
1340
3.6
17.1
119,126
as C
343
76.4
UI-M25-2
6/25/91
1754
2006
2.6
18.3
114,014
1,296
276
UI-M25-3
6/26/91
930
1144
3.9
16.8
112,005
538
113
Average
3.4
17.4
115,048
726
155
* From the average of concurrent M0011 and M5/202 sampling performed at
the lower prequench inlet.
D-1
ENTROPY
-------
TABLE 2-8
TOTAL GASEOUS NONMETHANE ORGANICS TESTS SUMMARY
Stack
Test Date
Run Start Time
Run Finish Time
Flue Gas Parameters
CO2, Percent By Volume, Dry
O2, Percent By Volume, Dry
Air Flow Rate, Dry SCFM*
Total Gaseous Nonmethane Oraanics
Concentration, ppmvd
Emission Rate, Ib/hr
S-M25-1
6/25/91
1019
1340
3.5
17.2
117,605
as C
373
82.0
S-M25-2
6/25/91
1753
2005
3.6
16.9
112,518
1,189
250
S-M25-3
6/26/91
930
1144
3.5
17.2
115,868
413
89.5
Average
3.5
17.1
115,330
658
141
From the average of concurrent M0011 and M5/202 sampling.
D-2
ENTROPY
-------
SOUTHERN REGIONAL CENTER
P.O. Box 141020
Gainesville, FL 32614-1020
(904) 377-4708
FAX: (904) 371-6557
NATIONAL COUNCIL OF THE PAPER INDUSTRY FOR AIR AND STREAM IMPROVEMENT, INC.
69
CERTIFICATION SHEET
Having supervised the Method 25 test program described in
this report, I hereby certify the data, information and results
in this report to be accurate and true according to the methods
and procedures used.
jrf^ P- E. , Regional Manager
D-3
-------
SAMPLE OA/OC
(1) Carrier Gas and System Air Blank (<5 ppm required)
CO + CH4 + C02 + NMO = 0 ppm
(2) Catalyst Efficiency Check (±2%)
Methane standard 10150 ppm CH4
Methane standard after catalyst 10150.5 ppm C02
% difference =0.0%
(3) Analyzer Linearity Check
A full calibration was conducted on the analyzer before each
day of analysis.
(4) System Leak Check
4 mbar/10 min
D-4
-------
71
SAMPLE TANK LEAK CHECK
TANK NO.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
INITIAL VACUUM
(mbar)
1008.2
895.6
1001.8
1017.0
1017.1
966.2
1013.7
1015.8
1016.6
995.6
1012.7
1004.3
1014.8
1015.1
1015.4
1003.4
1011.1
1005.3
1006.2
1013.4
1009.4
1011.2
1011.6
1012.9
1010.2
1009.4
1011.9
1014.7
1014.6
1010.0
FINAL VACUUM
(mbar)
CHANGE
(mbar)
1006.7
894.0
1000.3
1015.5
1015.7
964.6
1012.2
1014.4
1015.1
994.0
1011.1
1002.8
1013.6
1013.5
1014.0
1001.9
1009.7
1003.7
1004.6
1011.9
1008.6
1010.3
1010.8
1012.2
1009.5
1008.4
1011.0
1013.9
1013.6
1009. 1
-1.5
-1.6
-1.5
-1.5
-1.4
-1.6
-1.5
-1.4
-1.5
-1.6
-1.6
-1.5
-1.2
-1.6
-1.4
-1.5
-1.4
-1.6
-1.6
-1.5
-0.8
-0.9
-0.8
-0.7
-0.7
-1.0
-0.9
-0.8
-1.0
-0.9
D-5
-------
EPA METHOD 25 VOC SYSTEM PERFORMANCE CHECK
7/8/91
SAMPLE VOC VOC SOLVENT SOLVENT PERCENT RSD
(ppm CH4) (mg C) (ul) (mgC) RECOVERY (<5%)
HEXANE
DECANE
1458
1453
1343
6529
6952
7188
1524
1544
1571
7715
8004
7859
5.74
5.64
5.31
26.39
27.51
26.56
6.05
6.38
6.20
30.98
31.77
31.41
10
10
10
50
50
50
10
10
10
50
50
50
5.5
5.5
5.5
27.6
27.6
27.6
6.2
6.2
6.2
30.8
30.8
30.8
AVERAGE
104.0%
102.1%
96.2%
95.6%
99.6%
96.2%
98.2%
103.5%
100.6%
100.6%
103.1%
102.0%
100.1%
4.1%
2.2%
2.6%
1.3%
D-6
-------
73
EPA METHOD 25 VOC DATA SHEET
GEORGIA PACIFIC CORP. OSB MILL SKIPPERS, VA
VENT RUN# TANK TRAP INITL TANK BARO FINAL TANK BARO
NO. NO. VAC TEMP PRES VAC TEMP PRES
(mbar) (deg F) (mm Hg) (mbar) (deg F) (mm Hg
INLET 1A S 14 1 1010 77 766 243 94 765
1A B 7 1016 72 761
2A S 18 17 1003 80 765 539 77 766
2A B 9B 1017 72 763
3A S 15 10 1010 75 766 401 86 765
3A B 11 1017 72 762
OUTLET
BLANK
VENT RUN#
INLET 1A
1A
2A
2A
3A
3A
OUTLET 1A
1A
2A
2A
3A
3A
1A
1A
2A
2A
3A
3A
S
B
S
B
S
B
S
B
S
B
S
B
S
B
S
B
S
B
B
TANK
NO.
14
7
18
9B
15
11
8
5
29
9
25
3B
8
5
29
9
25
3B
10
FLSH
PRES
(mbar)
903
797
784
822
776
789
773
797
765
802
747
805
22 1014
1017
19 1001
1019
14 1015
1018
1010
79
72
80
72
75
72
72
TANK BARO
TEMP PRES
(deg F) (mm Hg)
72
72
72
72
72
72
72
72
72
72
72
72
761
761
763
763
762
762
762
762
763
763
764
763
TANK
VOL.
(ml)
6148
4561
6149
4581
6145
6146
6148
4575
6700
4581
6790
4562
764
762
764
763
763
763
766
SAMPL
VOL.
(ml)
4456
2801
3587
5543
5519
5134
58 94 763
157 77 764
226 86 763
ANAL
VOL.
(ml)
11564
8105
10893
8286
10815
10895
10802
8146
11744
8196
11806
8176
BLANK
B 10
724
72
766 4588
7905
D-7
-------
74
EPA METHOD 25 VOC DATA
GEORGIA PACIFIC CORP. OSB MILL
SHEET
SKIPPERS, VA
VENT
INLET
OUTLET
RUN#
1A
1A
2A
2A
3A
3A
1A
1A
2A
2A
3A
3A
TANK TRAP INITL
NO. NO. VAC
TANK BARO FINAL TANK BARO
TEMP PRES VAC TEMP PRES
(mbar)(deg F)(mm Hg)(mbar)(deg F)(mm Hg)
S 14
B 7
S 18
B 9B
S 15
B 11
S
B
8
5
S 29
B 9
S 25
B 3B
17
10
22
19
14
1010
1016
1003
1017
1010
1017
1014
1017
1001
1019
1015
1018
77
72
80
72
75
72
79
72
80
72
75
72
766
761
765
763
766
762
764
762
764
763
763
763
243
539
401
58
157
226
94
77
86
94
77
86
765
766
765
763
764
763
BLANK
B 10
1010
72
766
D-i
-------
75
EPA METHOD 25 VOC DATA SHEET
GEORGIA PACIFIC CORP- OSB MILL SKIPPERS, VA
VENT RUN# ANALYSIS
CONCENTRATION (ppm C)
TOTAL
VOC VOC-BLANK
SAMPLE CONC.
VOC VOC
NM CO CH4 C02 TOTAL (mg C) (mg C) (mg/DSCM (ppm C)
INLET
1A
1A
5.5
O
2A 0 39.4 3.7
2A 5.2
3A 0 73.0 0
3A 4.3
OUTLET 1A O 52.0
1A 4.5
2A 0 66.0
2A 5.5
3A 0 92.8
3A 6.7
BLANK
14544
191
9871
442
12718
179
18402
258
16166
806
5.2 16555
261
,7
0
197
0
447
0
183
0
263
0
812
0
268
0.00
0.79
0.00
1.85
0.00
0.99
0.00
1.06
0.00
3.31
0.00
1.09
0.03
0.763
1.815
0.965
1.035
3.282
1.060
171
648
269
187
595
206
343
1296
538
373
1189
413
D-9
-------
APPENDIX E. CEMS Data Summary - 02, C02, CO, NOX, and THC
-------
PLANT: Georgia-Pacific; Skippers, Virginia
SAMPLING LOCATION: Stack
S-CEM-1 S-CEM-2 S-CEM-3
Test Date
Run Start Time
Run Finish Time
Theta Net Sample Time, Minutes
Mfd Dry Mole Fraction
%C02 Carbon Dioxide, Percent By Volume, Dry
%02 Oxygen, Percent By Volume, Dry
Qsd Volumetric Air Flow Rate, Dry SCFM *
ton/hr Process Feed Rate, ton/hr
Carbon Monoxide
Fwt Formula Weight, Lb/Lb-Mole
ppmvd Concentration, ppmvd
ppm@i2% Concentration, ppmvd @ 12% C
ppm@7% Concentration, ppmvd @ 7% 02
mg/DSCM Concentration, mg/DSCM
Ib/hr Emission Rate, Ib/hr
Ib/ton Emission Rate, Ib/ton
Nitrogen Oxides as NO2
Fwt Formula Weight, Lb/Lb-Mole
ppmvd Concentration, ppmvd
ppm@12% Concentration, ppmvd @ 12% C
6/25/91
1014
1404
230
0.78
3.5
17.2
117,605
35.4
28.01
95.6
328
352
111
49
1.385
46.01
32.0
110
6/25/91
1754
2005
131
0.78
3.6
16.9
112,518
38.8
28.01
139.8
466
477
163
69
1.768
46.01
20.0
66.7
6/26/91
930
1141
131
0.78
3.5
17.2
115,868
38.7
28.01
199
684
735
232
101
2.604
46.01
21.0
72.0
E-1
-------
ppm@7% Concentration, ppmvd @ 7% O2
mg/DSCM Concentration, mg/DSCM
Ib/hr Emission Rate, Ib/hr
Ib/ton Emission Rate, Ib/ton
Total Hydrocarbons, as Carbon
Fwt Formula Weight, Lb/Lb-Mole
ppmvw Concentration, ppmvw
ppmvd Concentration, ppmvd
ppm@12% Concentration, ppmvd @ 12% C
ppm@7
-------
PLANT: Georgia-Pacific; Skippers, Virginia
SAMPLING LOCATION: Upper Inlet
l-CEM-1 l-CEM-2 l-CEM-3
Test Date
Run Start Time
Run Finish Time
Theta Net Sample Time, Minutes
Mfd Dry Mole Fraction
%CO2 Carbon Dioxide, Percent By Volume, Dry
%O2 Oxygen, Percent By Volume, Dry
Qsd Volumetric Air Flow Rate, Dry SCFM *
ton/hr Process Feed Rate, ton/hr
Total Hydrocarbons, as Carbon
Fwt Formula Weight, Lb/Lb-Mole
ppmvw Concentration, ppmvw
ppmvd Concentration, ppmvd
ppm@l2°/o Concentration, ppmvd @ 12% C
ppm@7% Concentration, ppmvd @ 7% 02
mg/DSCM Concentration, mg/DSCM
Ib/hr Emission Rate. Ib/hr
Ib/ton Emission Rate, Ib/ton
* From the average of concurrent EPA M0011 and MM5 sampling.
6/25/91
1014
1404
230
0.78
3.5
17.2
117,605
35.4
12.01
309
396
1,358
1,460
198
87
2.467
6/25/91
1754
2005
131
0.78
3.6
16.9
112,518
38.8
12.01
790
1,013
3,376
3,458
506
213
5.493
6/26/91
930
1141
131
0.78
3.5
17.2
115,868
38.7
12.01
347
445
1,525
1,639
222
96
2.491
E-3
-------
Georgia-Pacific; Skippers, Virginia - RUN 1
Page 1
06-25-1991
Time
10:15
10:16
10:17
10:18
10:19
10:20
10:21
10:22
10:23
10:24
10:25
10:26
10:27
10:28
10:29
10:30
10:31
10:32
10:33
10:34
10.35
10.36
10:37
10.38
10.39
10 40
10 41
1042
10 43
10 44
10 45
10 46
10.47
10:48
10:49
10:50
10:51
10.52
10:53
10:54
10.55
Outlet
NOx
30.8
30.9
31.9
32.4
33.2
32.1
30.9
31
32.9
37.5
34.9
33.5
32.3
32
32
31.7
31.8
31.8
31.7
30.8
30.5
31.3
32.5
32
32.3
30 9
32 2
28 5
29 7
28 5
27 5
27.6
27.5
29.3
32.8
32.6
32.9
33.2
33.1
33.2
32
Outlet
ppmCO
70
66.2
68
68.2
72.1
77.7
79.9
86.7
92.7
95.9
105.1
105.8
110.6
110.9
119.7
111.4
107.6
123
141.5
143.3
135.3
124.8
130
139.7
134.8
121.1
111 7
894
82 8
74 1
65 7
584
53.5
120.8
160.8
170.9
159.5
154.9
147.9
150.6
140.6
Outlet
%O2
17.53
17.54
17.46
17.4
17.28
17.13
17.28
17.19
17.16
16.99
16.93
16.82
16.84
16.82
16.86
17.04
17.05
16.85
16.73
16.85
17.03
17.01
16.9
16.89
16.99
17 43
17 42
18 29
18 25
18.58
18 87
1902
18.89
16.91
16.53
16.7
16.71
16.78
16.79
16.77
17.01
Outlet
%CO2
3.17
3.16
3.22
3.28
3.4
3.53
3.39
3.45
3.52
3.68
3.71
3.81
3.77
3.82
3.76
3.6
3.6
3.79
3.89
3.79
3.6
3.68
3.76
3.75
3.68
3.17
3.05
2.37
2 37
2.07
1.84
1.72
2.01
3.81
4.08
3.91
3.94
3.87
3.87
3.86
3.64
Outlet
ppm THC
247.7
249.3
252.9
261.2
265.8
269
270.5
271.9
265.8
261.1
249.1
261.8
268.2
271.1
273.2
272.4
268.9
258.4
279.2
281.9
279.9
279.9
283.1
286.8
285.2
265.4
245.5
213.5
209.4
189.5
170.9
160.1
159.8
263.7
299.7
308.3
315.7
312.9
306.5
302.1
294.6
Inlet
ppm THC
295
299.2
304
315.9
320.6
329.3
331.6
334
332.1
326.9
332.8
332.8
339.5
340.9
342.7
340.5
331.2
342
354.3
355.9
349.8
344
333.8
344.3
345.5
360.4
345.1
301.6
242.4
220.5
203.1
207.9
247.2
333.5
350.9
359
368.6
368.4
362.1
365.5
357
E-4
-------
Georgia-Pacific; Skippers, Virginia - RUN 1
Page 2
10:56
10:57
10:58
10:59
11:00
11:01
11:02
11:03
11:04
11:05
11:06
11:07
11:08
11:09
11:10
11:11
11:12
11:13
11:14
11:15
11:16
11-17
11:18
11:19
11 20
1 1.21
11:22
11:23
11 24
1 1 25
11 26
11 27
11.28
11 29
11 30
1 1 31
11.32
11:33
11:34
11:35
11:36
11.37
11:38
11:39
1 1 :40
33.6
34.4
35.5
35.3
34.6
34.6
34.5
34
34.2
33.8
33.8
33.7
34.5
33.8
34.3
34.4
35.6
34.7
34.5
34.6
34.4
34.7
35.1
36.1
35.3
33.4
34.5
33.6
32.8
34 3
35.2
33.7
33 1
33 9
33.6
33.3
33.2
34.5
33.3
32.7
33.2
34.3
33.1
32.4
32.6
121.7
116.3
128.9
136.1
128.4
121.5
110.9
100.6
98.8
108.2
102.8
99.9
102.2
96.4
94.1
90.7
97.7
107.3
112.7
113.9
113.5
116
120.4
127.7
135.8
146.5
138.3
123
123.8
131
136.1
1424
128
125 1
128.6
129.8
128.4
133.4
137.8
128
126.4
133.1
130.9
117.6
115
17.12
16.94
16.59
16.51
16.75
16.83
16.79
16.94
16.94
16.88
16.93
16.95
16.91
17.02
17.01
17.03
16.75
16.73
16.76
16.78
16.78
16.79
16.74
16.7
16.49
16.64
16.75
16.86
16.84
16.61
16.43
16.58
16.84
16.76
16.78
16.93
16.92
16.67
16.69
16.93
16.86
16.79
16.98
17.07
17 12
3.56
3.75
4.06
4.04
3.87
3.81
3.84
3.69
3.71
3.76
3.7
3.7
3.72
3.62
3.63
3.65
3.9
3.89
3.86
3.85
3.86
3.86
3.91
3.95
4.13
3.92
3.91
3.81
3.86
4.08
4.22
4.08
3.88
3 97
3.96
3.83
3.88
4.1
4.05
3.86
3.95
3.99
3.83
3.74
3.72
287.3
286.6
297.3
304.3
303.3
296.1
284.2
292.8
296.9
295.5
304.4
308.2
308.4
305.7
304.8
299.2
302.6
301.4
297.9
293.1
291.4
293.9
298.9
306.5
311.5
308.5
289.5
297
308.2
318.5
324.8
325.5
315.6
315.2
319.5
325.4
330.1
342.6
350.3
347.6
348.7
345.9
329.6
325.5
323.4
353.4
353
364.2
367.9
367
359.9
358.4
367.4
375.6
373.2
373.3
376.3
371
364.7
364.1
349.9
345.6
342.4
327.5
329.8
323.5
311.4
323.7
337
335.1
333.5
332
327.8
334.5
340.7
343.6
343.8
333.4
333.3
333.3
344.2
348
361.6
373.8
364.1
361.9
364.6
364.2
351
343.6
E-5
-------
Georgia-Pacific; Skippers, Virginia - RUN 1
Page 3
11:41
11:42
11:43
11:44
11:45
11:46
11:47
11:48
11:49
11:50
11:51
11:52
11:53
11:54
11:55
11:56
11:57
11:58
11:59
12:00
12:01
12:02
12:03
12:04
12 05
12 06
12 07
1208
1209
12 10
1211
12 12
12 13
12 14
12 15
12 16
12.17
12:18
12:19
12:20
12.21
12 22
12.23
12.24
12.25
32.5
32.8
33.4
32
31.8
31.7
31.4
31.4
31.7
32.9
34
34.2
35.5
35
35.8
35.7
36.7
37.4
37.2
37.8
37.7
39.4
41.4
41.3
42.2
40.9
40.1
40.5
39
40 4
40 1
394
39 1
39 7
40 5
40
39
38.2
37.3
36.6
37.1
38.2
39.7
37.2
33.6
119.6
127.5
131.6
131.5
131.8
129.1
133.2
148.3
142.2
121.4
121.2
147.9
115.5
92.2
86.4
84.2
34.8
85.2
86
75.4
69.4
81.6
44.4
36.3
32.6
28.6
26.4
25.9
28.2
50.3
46
30 1
32.3
35 4
39.9
43.4
49.7
60
70.6
70.3
69.1
64.1
56.6
55.2
51.9
17.15
16.94
16.87
16.89
16.89
16.92
16.84
16.9
16.95
16.94
16.94
16.98
17 11
17.26
17.22
17.26
17.18
17.18
17.28
17.32
17.53
17.65
17.74
17.86
17.91
18.07
18.12
18.02
17.93
17.92
18.12
18 13
18.13
18.13
17.98
17 89
17.9
17.71
17.72
17.74
17.7
17.76
17.88
18.05
18.35
3.68
3.92
3.97
3.96
3.96
3.96
4.01
3.98
3.94
3.95
3.95
3.9
3.79
3.64
3.71
3.66
3.74
3.73
3.64
3.61
3.39
3.29
3.2
3.07
3.03
2.86
2.81
2.93
3.02
3.02
2.83
2.84
2.83
2.86
3.02
3.1
3.11
3.29
3.27
3.24
3.28
3.21
3.09
2.91
2.58
313.1
309.6
319.1
318.1
319.3
314
312.9
320.4
315.9
308.7
313
311.8
301.7
295.8
290.3
286.9
280.8
274.6
271.1
267.3
270.7
264.3
262
260.4
255.2
250.1
246.5
242.9
249.4
253.6
242.6
245.8
248.8
249.3
247.5
246.9
244.3
243.4
245.8
246.2
239
236.2
234.8
231.7
225.1
345.3
338.3
340.6
331.4
338.9
324.3
322.2
333.7
336.2
334.4
344.7
339.9
330.8
322.9
310.1
311.7
307.2
299.9
311.5
300.6
303.1
309.4
298.5
300.8
294.1
287.2
285.3
279.2
278.6
282.9
290.7
280.5
270.7
273
275.7
276.1
278.2
273.2
272.6
279
277.8
271.3
271.1
258.3
242.7
E-6
-------
Georgia-Pacific; Skippers, Virginia - RUN 1
Page 4
12:26
12:27
12:28
12:29
12:30
12:31
12:32
12:33
12:34
12:35
12:36
12:37
12:38
12:39
12:40
12:41
12:42
12:43
12:44
12:45
12:46
12:47
12:48
12:49
12:50
12:51
12:52
12:53
12:54
12.55
12.56
12 57
12.58
12 59
13:00
13.01
13:02
13:03
13:04
13:05
13:06
13:07
13:08
13:09
13:10
31.8
32.8
32.8
33.3
33.6
34.2
35
35.7
37.2
38.6
38.8
37.7
36.4
36.8
36.5
36.4
35.1
34.3
34.3
34.7
33.6
32.4
31.8
31.3
30.3
29.8
30.7
31.7
31
31.8
34.7
37.2
37.2
38
39.2
39.2
37.4
35.3
36.3
38
38.6
38.4
39.9
39.9
39.6
42.9
32.3
25.9
24.6
25.5
30.1
34.3
34.8
35.9
35.8
36.9
39.2
40.6
40.7
36.2
34.7
35.9
38.8
43
47.7
53
57.7
62.8
70.2
76.6
76.6
85.2
84.2
90.3
90.8
113.5
120
109.3
74.8
44
26.6
21.2
20.2
22.9
19
16.5
18
18
16.5
17.3
18.51
18.51
18.62
18.64
18.68
18.62
18.55
18.56
18.42
18.19
18
17.83
17.96
18.05
17.95
17.88
17.89
17.97
17.91
17.73
17.56
17.55
17.53
17.32
17.51
17.85
17.76
17.58
17.53
17.62
17.31
17.3
17.54
17.69
17.78
17.92
18.12
18.3
18.31
18.3
18.4
18.43
18.36
18.32
18.26
2.45
2.44
2.35
2.36
2.33
2.39
2.45
2.45
2.61
2.83
3.02
3.14
3.01
2.94
3.05
3.1
3.08
3.01
3.1
3.26
3.41
3.41
3.42
3.65
3.41
3.16
3.25
3.33
3.45
3.37
3.66
3.63
3.4
3.27
3.19
3.06
2.85
2.69
2.69
2.69
2.6
2.57
2.66
2.7
2.76
216
207.4
203.3
200.7
-196.1
196.4
198.6
202.4
204
206.6
210.9
214.6
214.7
211.8
227.9
233.6
235.3
233.1
232.8
238.2
244.1
250.6
253.3
261.5
258
246.4
247.6
244.1
236.3
247.5
259.3
261.6
260.7
253.5
249.9
246.6
242.5
238
237.8
235.3
232.4
231.6
228.7
221.6
217.7
222.4
219.5
211.4
212.5
218.1
221.8
223.1
231.1
243.8
248.6
256.6
262.8
269.9
274.6
277.8
277.2
275.2
266.6
265.2
269
273.6
282.9
286.1
292.3
296.6
290.7
279.5
281.3
280.8
282.8
283.1
292.3
287.5
282.7
287.6
273.8
268
262
265
267.6
263.2
263.2
262.6
259.2
260.9
E-7
-------
Georgia-Pacific; Skippers, Virginia - RUN 1
Pages
13:11
13:12
13:13
13:14
13:15
13:16
13:17
13:18
13:19
13:20
13:21
13:22
13:23
13:24
13:25
13:26
13:27
13:28
13:29
13.30
13:31
13:32
13:33
13:34
13.35
13 36
13 37
13:38
13 39
13 40
13 41
13 42
13 43
13 44
13 45
13 46
13.47
13:48
13:49
13.50
13.51
13.52
13:53
13.54
13:55
39
39
37.9
37.1
35.3
35.4
35.3
34
35.1
34.8
34.8
36.7
36.8
36.7
36.4
36.5
36.1
36.7
39.7
38.6
36.2
36.7
37.3
36.7
35.9
35 8
35.5
36.2
36.1
35 2
35
34 4
33 6
33 3
33.5
33 2
33.3
33.8
33.5
38.8
34.2
33.7
33.4
34.2
36.4
19.4
19.9
20.9
22.9
26.4
31.5
35.2
37.4
37.6
42.6
51.6
60.1
63
84.5
142.5
116.4
121.9
135.6
144.1
135.4
127
114.1
130.3
134.7
131.3
130.9
126.1
129.4
137.8
132.6
124.7
122 5
130 7
136
127
1148
112.4
122.1
122.5
125.8
122
121
103.9
93.5
90.9
18.26
18.25
18.3
18.32
18.44
18.47
18.31
18.49
18.44
18.4
18.37
18.17
18.12
18.08
17.84
17.6
17.52
17.51
16.91
16.85
17.19
17.15
16.93
16.99
17.08
17.11
17.24
17.14
17.14
17.28
17.34
17.29
17.24
17.26
17.36
17.53
17.41
17.27
17.31
17.23
17.18
17.24
17.38
17.46
17.3
2.75
2.77
2.71
2.7
2.54
2.57
2.7
2.51
2.59
2.61
2.66
2.87
2.89
2.94
3.19
3.43
3.46
3.52
4.05
4.05
3.74
3.84
3.99
3.94
3.87
3.83
3.73
3.83
3.81
3.69
3.65
3.69
3.74
3.7
3.62
3.46
3.61
3.73
3.7
3.75
3.8
3.73
3.62
3.55
3.7
214.1
212.2
209.4
208.7
205.5
205.6
207.6
209.3
214.3
220.8
227.2
233.9
239
237.3
240.4
248.3
257.5
261.4
276.3
284.9
283.8
286
292.6
303.8
309.4
309.5
310
308.8
306.5
302.2
293.1
290.1
288.9
286.5
285.9
285
288.3
288.8
288.4
287.2
289.5
294.1
288.4
287.9
298.3
246.2
235.9
229.1
226.9
217
208.7
211.5
212.5
217.2
223.9
228.3
240.4
250.6
254.4
258.1
263.9
279.2
284.6
294.9
312.1
314.3
311.8
321
323.7
340.5
343.1
342.2
334.9
336.6
336.5
327.6
312.7
313.4
311.5
309.3
314.9
314.3
314.8
502.6
316.2
319.4
325.5
323.2
321.9
330.8
-------
Georgia-Pacific; Skippers, Virginia - RUN 1 Page 6
13:56
13:57
13:58
13:59
14:00
14:01
14:02
14:03
14:04
37.2
35.8
33.9
31.6
31.8
33.4
31.6
31.2
32.5
90.8
89.8
86.4
88.6
96.3
105.5
104.9
107.5
102.4
17.18
17.12
17.11
17.18
17.02
17.07
17.05
17.24
17.16
3.81
3.85
3.85
3.81
3.94
3.89
3.9
3.74
3.88
310.7
314.6
314
319.1
333.5
328.9
323.6
322.3
319.9
345.8
351.3
381
368.9
373.5
389.6
400
399.9
397.7
Average 34.7 90.4 17.43 3.4 270.3 308.8
E-9
-------
Georgia-Pacific; Skippers, Virginia - RUN 2
Page 1
06-25-1991
Time
17:11
17:12
17:55
17:56
17:57
17:58
17:59
18:00
18:01
18:02
18:03
18:04
18:05
18:06
18:07
18:08
18:09
18:10
18:11
18:12
18:13
18.14
18 15
18 16
18.17
18 18
18 19
18 20
18 21
18 22
18 23
18 24
18 25
18.26
18:27
18.28
18:29
18:30
18 31
18:32
18:33
18.34
Outlet
NOx
14.5
14.3
18.2
16.8
17
17
16.5
16.5
16.4
16
18.7
18.1
19.3
21.3
19.6
18.9
19.2
19.4
18.7
26
21
20.3
19.9
22
22.5
21.7
20.5
204
19 5
19 5
19 6
19.7
19.3
19.2
19.9
20
19.5
19.6
19.3
20.5
21
20.5
Outlet
ppmCO
146.9
149.4
84.3
165.5
216.3
205.5
223.7
211.9
165.4
183.2
140.4
89.8
92.3
99.2
102.6
114.2
124.3
133.7
127.4
129.9
132.2
138.4
134.7
137.3
140.9
149.1
161.3
166.3
154 4
151.8
155
162.9
163
154.2
155.5
166.6
157.8
145.8
138.9
135.6
160.6
162.1
Outlet
%02
17.05
17.12
17.77
17.77
17.81
17.78
17.71
17.76
17.77
17.67
17.53
17.57
17.48
17.49
17.46
17.42
17.19
17.21
17.31
17.29
17.26
17.24
17.3
17.27
17.14
17.11
17.02
17.05
17.25
17.23
17.18
17.09
17.15
17.19
17
16.94
17.17
17.23
17.49
17.25
17.06
17.24
Outlet
%CO2
3.8
3.72
3.2
3.2
3.16
3.2
3.25
3.21
3.19
3.29
3.42
3.37
3.46
3.44
3.47
3.51
3.72
3.67
3.6
3.61
3.65
3.65
3.61
3.62
3.75
3.78
3.86
3.81
3.66
3.67
3.73
3.8
3.74
3.71
3.89
3.91
3.72
3.67
3.43
3.69
3.82
3.67
Outlet
ppm THC
517.2
508.1
539.6
589
582.5
574.5
584.9
585.8
581.6
597.2
588.8
586.9
613.3
545
575.8
591.8
605.3
608.2
629.5
554.1
609.5
624
612
620.6
645.8
645.7
649.5
651.2
652.4
673
674.3
713.6
722.6
725.9
741.2
736.3
727.9
711
738.3
738
727
722
Inlet
ppm THC
533.1
541.9
743.1
755
749.7
745.9
750.6
749.2
742.8
727.3
731
735.3
746.4
751.3
747.9
752
769.7
765.9
758.8
756.6
755.4
753.6
756.7
723.2
722.4
768.7
777.1
779.3
783.7
784.9
788
821.1
841.1
840.4
857
836.9
812.8
798.1
794.2
811.4
822.2
800
E- 1 0
-------
Georgia-Pacific; Skippers, Virginia - RUN 2
Page 2
18:35
18:36
18:37
18:38
18:39
18:40
18:41
18:42
18:43
18:44
18:45
18:46
18:47
18:48
18:49
18:50
18:51
18:52
18:53
18:54
18.55
18:56
18:57
18:58
18:59
1900
19:01
19.02
19:03
19 04
19 05
19 06
19 07
19 08
19 09
19.10
19.11
19:12
19:13
19:14
19.15
19:16
19:17
19:18
19:19
23
19.9
19.7
19.9
19.3
19.2
19.2
19.6
19.8
20.6
20.6
20.8
21.2
22.3
21.5
22
21.7
21.5
21.2
20.9
21
13.9
8.1
22.4
19 3
20
21.2
20.7
20.3
19 9
20.1
206
20.1
20 7
21 1
21.3
21.4
20.7
20.4
22.8
20.5
20.3
20.2
20
20.1
152.1
138.6
146.2
162.2
160.7
157.2
155.4
147
149.1
156.1
158.7
148
143.1
131.8
116.3
128.7
132.3
121.2
123
114.4
116.7
101.4
12.2
88.1
115.3
112.2
126.5
136.4
147
151.2
149 5
156 3
156
143 5
159
171 3
175.3
167.9
162.4
160.2
166.2
173.1
156.8
149
154.7
17.4
17.39
17.3
17.19
17.3
17.29
17.32
17.29
17.26
17.09
17.17
17.23
17.32
17.55
17.54
17.27
17.39
17.45
17.46
17.52
17.54
19.22
20.4
17.62
17.59
17.53
17.31
17.29
17.27
17 29
17 29
17 17
17.36
17 34
17 15
17.07
17.07
17.17
17.27
17.19
17.09
17 16
17.26
17.33
17.22
3.53
3.55
3.63
3.7
3.6
3.6
3.57
3.6
3.62
3.78
3.69
3.67
3.55
3.36
3.39
3.63
3.5
3.46
3.43
3.4
3.34
1.63
0.94
3.32
3.35
3.39
3.61
3.62
3.63
3.6
3.61
3 71
3.52
3.56
3.72
3.79
3.78
3.69
3.61
3.69
3.78
3.71
3.63
3.58
3.7
716.9
703.2
750.7
780.1
807.1
820.4
823.6
808.1
813.8
796.9
737.1
752.8
753.9
713.2
705.8
712.6
719.2
743.8
795.5
815.3
704.3
273.2
338.4
784.8
826.5
811.1
803.2
776.1
757.6
712.4
749.3
751.3
730
722.2
731
730.7
687.8
657.4
651.6
681.9
693.3
707.4
717.6
732.3
744.6
777.8
783.5
799.9
814.1
831
860.8
858.8
872.6
902.4
901.2
890.5
873.9
846.9
843
846.8
883.6
891.2
903.3
965.6
983.6
978.6
963
966.8
946.5
920.7
952.5
944.9
940.5
915.8
920.2
942.8
937.6
972.3
948.6
952.6
951.8
958.5
948.8
943.1
957.2
968.1
962
988.3
982.4
994.8
E-1 1
-------
Georgia-Pacific; Skippers, Virginia - RUN 2
Page 3
19:20
19:21
19:22
19:23
19:24
19:25
19:26
19:27
19:28
19:29
19:30
19:31
19:32
19:33
19:34
19:35
19:36
19:37
19:3?
19:39
19:40
19:41
19:42
19:43
19:44
19 45
1946
19:47
1948
19 49
19 50
19 51
19 52
19 53
19 54
19 55
19:56
19:57
19.58
19:59
20:00
20:01
20:02
20.03
20:04
20.7
20.4
20.9
20.8
20.9
21
20.9
21
21.6
21.3
21.4
20.7
21.2
21.7
22.6
22.6
22.3
23
22.5
22.3
24.3
23.4
22.8
22.6
22.7
24
24.6
24.9
24.8
24.2
25
25.1
24 3
25.1
24.7
25.1
25.5
25.7
24.4
24.1
24.5
23.8
23.5
23.5
24.3
171
167.2
156
149.5
145.7
145.3
138.9
139.2
155.3
163.1
151.8
144.4
133.4
128.7
133.2
142.5
133.6
135.1
132.2
119.9
123.1
122.3
122.7
118.5
111.5
109.4
105.4
105
104.1
104.4
103.1
105.7
101.4
97.9
100.6
107
101.4
106.1
102.7
99.4
95
97.4
98.2
97.7
100.3
17.05
17.17
17.15
17.21
17.26
17.3
17.32
17.3
17.07
17.13
17.18
17.33
17.41
17.33
17.2
17.16
17.28
17.12
17.34
17.41
17.41
17.34
17.4
17.41
17.5
1746
17.42
17.31
17.33
17 42
17.35
17.29
1746
17.45
17.38
17.32
17.42
17.33
17.36
17.46
1742
17.48
1748
17.54
17.38
3.83
3.73
3.76
3.69
3.66
3.6
3.59
3.61
3.8
3.73
3.69
3.55
3.48
3.56
3.69
3.71
3.62
3.74
3.52
3.5
3.48
3.55
3.49
3.49
3.42
3.45
3.5
3.6
3.58
3.5
3.59
3.62
3.48
3.5
3.57
3.61
3.54
3.62
3.59
3.5
3.54
3.49
3.49
3.45
3.6
749.7
772.5
759.5
711.4
-698.4
677.4
679.8
681.2
683.8
695.7
674.1
671.6
652.1
642.4
639.5
634.8
632
626.9
597.2
580.8
576.5
582.5
585.7
582.5
563
552.9
554.9
546.1
558.3
551.5
553.5
553.2
536.3
524.2
508.3
519.5
516.8
515.4
512.5
510.4
517.2
531.8
536.1
526.7
522.7
1009.7
1037
1024.8
973.2
924.9
872.2
857.4
846.2
842.1
827.9
807.4
794.7
785.2
761.3
729.9
717.5
720
724.1
705
676.9
659.7
664.9
661.2
658.2
645.1
635.9
628
613.6
628.2
621.3
611
600.3
589.2
574.7
575.5
582.5
568.1
574.3
567.8
561.9
562.9
570.2
568.5
566.4
570.1
E-12
-------
Georgia-Pacific; Skippers, Virginia - RUN 2 Page 4
20:05
20:06
20:07
24.5
23.2
23.4
108.4
113.7
110.5
17.3
17.39
17.43
3.65
3.57
3.54
539.2
536.5
520.5
580.7
571.7
565.5
Average 20.9 136.6 17.4 3.5 651.6 789.5
E-13
-------
Georgia-Pacific; Skippers, Virginia - RUN 3
Page 1
06-25-1991
Time
09:31
09:32
09:33
09:34
09:35
09:36
09:37
09:38
09:39
09.40
09:41
09:42
09:43
09:44
09:45
09:46
09:47
09:48
09:49
09:50
09:51
09:52
09 53
09:54
09.55
09:56
09 57
09 58
09 59
10 00
10 01
10 02
10 03
10:04
10:05
10:06
10:07
10:08
10:09
10:10
10:11
10:12
Outlet
NOx
23.6
24.6
25.4
26.8
27.9
27
26.9
28.6
27.6
26.9
27
26
26.6
26.4
26.1
25.8
25.1
24.8
25
22.6
22.2
22.4
22.4
22.5
27.4
25.1
24.1
24.2
23.8
23
22.7
22.6
22.1
23.1
23.9
23.1
23.1
23.2
23.9
23.2
22.4
21.8
Outlet
ppmCO
117.5
121.6
126
136.3
181.4
185.1
166.3
187.9
212.8
213.3
220.2
203.4
184.6
181.1
185.6
184.4
184.7
183.1
175.4
167.4
178.3
171.4
156.6
147.9
137.2
142.8
148.4
152.9
146.3
149.6
147 5
154.2
153.7
153.2
180.6
205.9
221.6
229.4
248
264.9
251.1
251.9
Outlet
%O2
17.28
17.22
17.25
16.97
16.73
17.03
17.01
16.69
16.8
16.84
16.88
17.06
17.1
17.05
16.98
16.91
16.99
17.14
17.18
17.12
17.01
17.05
17.14
17.12
16.59
16.92
16.96
16.93
16.98
17.06
17 11
17.09
17.23
17 14
16.91
16.93
16.91
16.93
16.73
16.82
16.88
16.99
Outlet
%CO2 |
0.02
6.1
4.74
3.9
4.06
3.8
3.84
4.11
4
3.98
3.94
3.78
3.76
3.82
3.87
3.95
3.85
3.73
3.69
3.75
3.83
3.79
3.71
3.72
3.59
3.89
3.86
3.88
3.84
3.76
3.72
3.74
3.61
3.72
3.91
3.88
3.9
3.88
4.07
3.97
3.94
3.83
Outlet
ppm THC |
382.9
389.5
382.5
395.7
400.4
392.5
394.3
400.5
387.5
383.6
367.3
361.6
354.5
359
357.4
361.2
359.2
354.2
353.3
341.8
337
329.3
322.9
317
312
324
323.3
324.7
325.3
327.7
317.6
313.4
313.5
323.5
323.4
320
324.2
325.8
326.6
317.2
312.3
308.9
Inlet
ppm THC
430.8
433.8
427.6
432
435.5
428.2
428.5
428.7
416.1
413.1
399.1
388.8
389.9
400.1
410.4
390.7
398.2
395.8
394.3
391.6
386
372.5
362.4
353.9
350
353.6
348.4
347.1
345
349
338.7
337.1
330.4
336.6
337.5
338.8
329.6
333.4
342.4
348.6
336.9
332.2
E-14
-------
Georgia-Pacific; Skippers, Virginia - RUN 3
Page 2
10:13
10:14
10:15
10:16
10:17
10:18
10:19
10:20
10:21
10:22
10:23
10:24
10:25
10:26
10:27
10:28
10:29
10:30
10:31
10:32
10:33
10.34
10:35
10:36
10.37
10.38
10:39
10.40
10 41
10 42
10 43
10 44
10 45
10 46
10 47
10 48
10.49
10:50
10:51
10:52
10:53
10:54
10.55
10:56
10:57
21.4
21.3
22.4
22.6
22.2
22.1
22.3
22.7
23
23.2
23.4
23.8
23.4
23.5
22.8
20.4
20
18.8
19
19.3
19.2
18.7
18.5
18.4
19 2
19 2
19.2
19.2
198
19 7
19 4
23 8
21 1
20 7
20 8
21
20.6
21.2
21.4
20.7
20.5
20 7
21.1
21.9
23.1
241.8
240.7
248.4
256.7
227.9
234.7
245.3
258.7
261.8
253.6
272.1
284
263.4
258.7
253.3
253.3
251.6
227.3
208.6
214.9
213.1
200.1
184.3
166.2
163.8
1724
178.2
171.7
161.2
171.5
171
173 1
184
202 6
213 1
2005
195.1
208.8
218.3
217.9
206.9
198.2
204.6
195.2
219.5
17.13
17.17
17.09
17.14
17.13
17.11
17.08
17
17.04
17.02
16.86
16.91
16.85
16.76
16.81
16.84
16.94
17.2
17.18
17.04
17.08
17 12
17.33
17.37
17.26
17.21
17.18
17.29
17.23
17.18
17 25
16 97
1712
1692
17.03
17.15
17.12
16.99
16.96
17.04
17.12
17.17
17.16
17.16
16.97
3.7
3.69
3.76
3.7
3.72
3.75
3.77
3.84
3.8
3.85
3.97
3.91
3.98
4.05
3.99
3.96
3.86
3.64
3.67
3.78
3.74
3.69
3.51
3.49
3.59
3.64
3.65
3.56
3.62
3.67
3.6
3 66
3.73
3 91
3.8
3.7
3.73
3.85
3.87
3.78
3.72
3.69
3.66
3.7
3.85
305.7
299.6
295.6
289.1
296.6
304.5
300
298.8
288.9
284.3
289.7
290.8
290
292.3
292.1
289.3
288.6
288.1
290.1
291.8
291.2
292.3
288.6
280.4
278.9
279.5
278.2
269.3
269.3
270.1
264.8
266.2
271.6
274
276.1
275.8
277.6
281
290.4
292.2
288.2
286.2
286.7
288.7
291.7
317.3
309.9
310.2
303.3
314.4
323.4
320.6
315.8
315.8
311.8
310.3
315.7
306.4
312.1
317
321.5
319
308.9
310.5
314.5
314.4
314.7
314.8
305.7
306
312.6
314.3
310.8
308
330.1
299.6
305.9
311.8
315.3
322
317.3
315.9
323.5
326.2
328.1
315.9
318
316.4
318.9
321.7
E-15
-------
Georgia-Pacific; Skippers, Virginia - RUN 3
Page 3
10:58
10:59
11:00
11:01
11:02
11:03
11:04
11:05
11:06
11:07
11:08
11:09
11:10
11:11
11:12
11:13
11:14
11:15
11:16
11:17
11:18
11:19
11:20
11:21
11:22
11:23
11:24
11:25
11:26
11.27
11.28
11 29
11 30
1 1 .31
11.32
11:33
11:34
11:35
11:36
11:37
11:38
11:39
11:40
11:41
11:42
23.4
23.7
24.1
22.7
23
22.1
21.6
22.5
22.8
23.4
22.3
21.2
21
21.3
23.2
21.4
21.1
22.9
23.1
23.1
22.8
22.4
21.6
21.6
22.1
21.9
21.9
21.9
224
22.2
22 7
21 5
22 4
22 1
22.6
22.6
22.1
21.9
22
21.1
20.9
21.5
20.3
20
20.4
230.1
226.6
212.5
207.1
214.1
219.6
190.7
182.4
179.2
176.8
176
166
164.4
168.9
159.8
160.7
146.7
162.6
189.6
190
194.4
186
172.3
168.6
185.7
207.9
207.4
208.9
219.9
227.4
239
226 5
228.8
234 8
261.8
271.1
274
236.3
217.8
183.2
126.9
136.5
113
104.4
104.7
16.94
17.06
17.03
17.12
16.98
17.11
17.23
17.12
17.12
17.02
17.15
17.24
17.26
17.22
17.34
17.37
17.43
17.08
17
17.01
17.01
17.09
17.3
17.2
17.06
17.05
17.14
17.2
17.1
17 16
1705
17 27
17 15
17 13
16 96
16.89
17.04
17.21
17.14
17.52
1744
1744
17.62
17.64
17.54
3.86
3.77
3.78
3.72
3.83
3.7
3.62
3.72
3.73
3.81
3.68
3.6
3.58
3.6
3.47
3.44
3.44
3.76
3.81
3.8
3.8
3.73
3.54
3.64
3.76
3.76
3.68
3.63
3.71
3.68
3.75
3.57
3.67
3.7
3.84
3.89
3.74
3.6
3.68
3.27
3.42
3.35
3.2
3.2
3.3
291.7
293.3
293.5
293.5
299.2
298.9
296.7
298.1
297.7
299.1
295.4
299
304.9
306.9
309.4
312.3
313.6
318.9
322
322.5
325
321.5
314.5
319.3
324.8
329.2
327
324.5
319.1
316.3
320.6
312.5
318.8
326.8
336.2
339
333.9
326.7
332.5
314.6
318.3
306.2
302.9
297.4
295
321.2
317.3
324.8
326.2
329
334.5
332.2
333.8
334.2
332.9
390.8
339.3
343.9
352.6
350.3
350.5
348.6
347.3
349.7
353.8
357.3
356.9
348.3
355.3
364.5
378.3
370
368.8
361.9
360.8
364.3
357.2
360.3
372.3
384.3
384.2
374.8
364.1
369.8
349.2
352.8
351.9
349.5
344.3
338.6
E- 1 6
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Georgia-Pacific; Skippers, Virginia - RUN 3 Page 4
11:43 20.8 102.6 17.55 3.28 291.4 341.1
11:44 21 103.3 17.63 3.19 288.7 334
Average 22.5 195.0 17.1 3.7 314.0 347.3
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