FINAL TEST REPORT
FOR
USEPA TEST PROGRAM
CONDUCTED AT
GENERAL SHALE BRICK PLANT
JOHNSON CITY, TENNESSEE
U. S. EPA CONTRACT NO. 68D20029
EMB WORK ASSIGNMENT NO. 18
December 1993
ETS, Inc.
1401 Municipal Road, Roanoke, Virginia 14012
-------
TABLE OF CONTENTS
PAGE
1.0 INTRODUCTION 1
1.1 SUMMARY 1
1.2 TEST PROGRAM PERSONNEL 5
2.0 PROCESS DESCRIPTION AND SAMPLING LOCATIONS 5
2.1 RAW MATERIAL CRUSHING, SCREENING AND
STORAGE OPERATION 5
2.2 MIXING AND EXTRUSION OPERATION 7
2.3 KILN OPERATION 8
2.4 POLLUTION CONTROL DESCRIPTION 10
3.0 SUMMARY AND DISCUSSION OF TEST RESULTS 11
3.1 OBJECTIVES AND TEST MATRIX 11
3.2 TEST MATRIX 11
3.3 FIELD TEST CHANGES, PROBLEMS, AND COMMENTS . . 13
3.3.1 KILN COMBUSTION EXHAUST STACK 13
3.3.3.1 CONTINUOUS EMISSIONS MONITORING 13
3.4 SUMMARY OF RESULTS 13
3.4.1 CRUSHING, SCREENING, AND STORAGE
OPERATIONS SAMPLING 13
3.4.1.1 AMBIENT SAMPLING 13
3.4.1.2 PARTICULATE AND PM10 EMISSIONS
AT THE BAGHOUSE OUTLET .... 14
3.4.1.3 PROCESS SAMPLING 16
3.4.2 KILN A DRYER STACK SAMPLING 16
3.4.2.1 TOTAL HYDROCARBONS, METHANE,
AND ETHANE EMISSIONS 16
3.4.3 KILN COMBUSTION EXHAUST STACK SAMPLING . 19
3.4.3.1 PM, PM10, AND CPM EMISSIONS . . 19
3.4.3.2 TRACE METALS EMISSIONS .... 20
3.4.3.3 NOX AND CO EMISSIONS 22
3.4.3.4 HYDROGEN FLUORIDE EMISSIONS . . 23
3.4.3.5 TOTAL HYDROCARBONS, METHANE,
AND ETHANE EMISSIONS 24
3.4.3.6 VOC EMISSIONS . 26
3.4.3.7 SVOC EMISSIONS 27
3.4.3.8 COAL AND SHALE TESTING .... 27
-------
TABLE OF CONTENTS fCont.l
4.0 SAMPLING AND ANALYTICAL PROCEDURES FOR
AMBIENT TESTING 29
4.1 AMBIENT PARTICIPATE MATTER
(PM AND PM10) - HI-VOL 29
4.2 SAMPLER SETUP AND CALIBRATION 29
4.3 SAMPLER OPERATION AND FILTER RECOVERY 29
5.0 SAMPLING AND ANALYTICAL PROCEDURES FOR
SOURCE TESTING 30
5.1.1 SAMPLING AND TRAVERSE POINT DETERMINATION
EPA METHOD 1 30
5.1.1.1 SAMPLING AND TRAVERSE POINTS FOR THE
BAGHOUSE OUTLET STACK 30
5.1.1.2 SAMPLING AND TRAVERSE POINTS FOR THE
KILN A DRYER STACK 30
5.1.1.3 SAMPLING AND TRAVERSE POINTS FOR THE
KILN COMBUSTION EXHAUST STACK ... 30
5.1.2 VOLUMETRIC MEASUREMENTS - EPA METHOD 2 ... 34
5.1.3 MOLECULAR WEIGHT DETERMINATION
EPA METHOD 3 AND 3A 34
5.1.4 FLUE GAS MOISTURE CONTENT - EPA METHOD 4 . . 34
5.1.5 PM AND PM10 SAMPLING - EPA METHOD 201A ... 35
5.1.5.1 SAMPLING TRAIN DESCRIPTION 35
5.1.5.2 PRE-TEST PREPARATION ........ 36
5.1.5.3 SAMPLING TRAIN OPERATION 36
5.1.5.4 SAMPLE TRAIN RECOVERY 37
5.1.5.5 PM10 ANALYSES 38
5.1.5.6 PM ANALYSES 38
5.1.6 PM, PMlor AND CPM SAMPLING
EPA METHOD 201A/202 39
5.1.6.1 SAMPLING TRAIN DESCRIPTION 39
5.1.6.2 PRE-TEST PREPARATION 39
5.1.6.3 SAMPLING TRAIN OPERATION 39
5.1.6.4 SAMPLE TRAIN RECOVERY 39
5.1.6.5 FIELD BLANKS 42
5.1.6.6 CPM ANALYSES - EPA METHOD 202 ... 42
5.1.6.7 PM10 ANALYSES - EPA METHOD 201A . . 42
5.1.7 MULTIPLE METALS WITH PM
EPA MULTI-METALS PROCEDURE 44
5.1.7.1 SAMPLING TRAIN DESCRIPTION 44
5.1.7.2 PRE-TEST PREPARATION . 45
5.1.7.3 SAMPLING TRAIN OPERATION 45
5.1.7.4 SAMPLE TRAIN RECOVERY 46
5.1.7.5 FIELD BLANKS 46
5.1.7.6 PM ANALYSES - EPA METHOD 5 46
5.1.7.7 MULTI METALS ANALYSES
EPA MULTI-METALS 48
ii
-------
TABLE OF CONTENTS fCont.l
5.1.8 HYDROGEN FLUORIDE (HF) - EPA METHOD 26 ... 50
5.1.8.1 SAMPLING TRAIN DESCRIPTIONS .... 50
5.1.8.2 SAMPLING TRAIN OPERATION 51
5.1.8.3 SAMPLE TRAIN RECOVERY 51
5.1.8.4 FIELD BLANKS 52
5.1.8.5 HYDROGEN FLUORIDE ANALYSIS 52
5.1.9 CONTINUOUS EMISSIONS MONITORING FOR
02/ C02, CO, NOX, AND THC -
INSTRUMENTAL METHODS 53
5.1.9.1 SAMPLING TRAIN DESCRIPTIONS .... 53
5.1.9.2 DATA ACQUISITION SYSTEM 55
5.1.9.3 CALIBRATION 55
5.1.10 VOLATILE ORGANICS SAMPLING 57
5.1.10.1 SAMPLING TRAIN DESCRIPTIONS .... 57
5.1.10.2 SAMPLING TRAIN OPERATION 57
5.1.10.3 SAMPLE TRAIN RECOVERY 58
5.1.10.4 FIELD BLANKS 59
5.1.10.5 VOLATILE ORGANICS ANALYSES
METHOD 0030 59
5.1.11 SEMIVOLATILE ORGANICS SAMPLING 57
5.1.11.1 SAMPLING TRAIN DESCRIPTIONS .... 60
5.1.11.2 SAMPLING TRAIN OPERATION 61
5.1.11.3 SAMPLE TRAIN RECOVERY 62
5.1.11.4 FIELD BLANKS 62
5.1.11.5 SEMIVOLATILE ORGANICS ANALYSES . . 62
6.0 FACILITY PROCESS DATA , 65
7.0 QA/QC ACTIVITIES 66
7.1 EQUIPMENT QC PROCEDURES 66
7.1.1 EQUIPMENT INSPECTION AND MAINTENANCE ... 66
7.1.2 EQUIPMENT CALIBRATION 66
7.1.2.1 PITOT TUBES 67
7.1.2.2 IMPINGER THERMOMETER 67
7.1.2.3 DRY GAS METER THERMOMETER ... 67
7.1.2.4 FLUE GAS TEMPERATURE SENSOR . . 67
7.1.2.5 DRY GAS METER AND ORIFICE ... 68
7.2 SAMPLING QC PROCEDURES 68
7.2.1 PRE-TEST QC CHECKS AND PROCEDURES ... 68
7.2.2 QC CHECKS AND PROCEDURES DURING TESTING 69
7.2.3 QC CHECKS AND PROCEDURES AFTER TESTING . 70
7.3 ANALYTICAL QA PROCEDURES 70
7.4 ANALYTICAL QC PROCEDURES 71
7.5 QA/QC CHECKS OF DATA REDUCTION 72
7.6 SAMPLE IDENTIFICATION AND CUSTODY 72
iii
-------
TABLE OF CONTENTS (Cont.\
LIST OF TABLES
TABLE 1.1-1 TARGETED METALS FOR JOHNSON CITY BRICK ... 3
TABLE 1.1-2 TARGETED VOLATILE COMPOUNDS 4
TABLE 1.1-3 TARGETED SEMIVOLATILE COMPOUNDS 4
TABLE 3.2-1 OVERVIEW OF TEST PROGRAM FOR
JOHNSON CITY BRICK 12
TABLE 4.4.1-1 SUMMARY OF AMBIENT HI-VOL SAMPLING FOR
TSP AND PM10 14
TABLE 3.4.1-2 SUMMARY OF BAGHOUSE PARTICULATE EMISSIONS 15
TABLE 3.4.1-3 SUMMARY OF RESULTS FOR SIEVE ANALYSIS
FROM PROCESS SAMPLES COLLECTED AT THE
CRUSHING AND SCREENING OPERATION 16
TABLE 3.4.2-1 SUMMARY OF KILN A DRYER EXHAUST TOTAL
HYDROCARBONS, METHANE, AND
ETHANE EMISSIONS 18
TABLE 3.4.3-1 SUMMARY OF THE KILN COMBUSTION EXHAUST PM,
PM10, AND CPM EMISSIONS 20
TABLE 3.4.3-2 SUMMARY OF THE KILN COMBUSTION EXHAUST
MULTIPLE METALS AND TOTAL PARTICULATE
EMISSIONS 21
TABLE 3.4.3-3 SUMMARY OF THE KILN COMBUSTION EXHAUST NOX
AND CO EMISSIONS 22
TABLE 3.4.3-4 DATA AND RESULTS FOR KILN COMBUSTION
EXHAUST HYDROGEN FLUORIDE TESTING .... 23
TABLE 3.4.3-5 SUMMARY OF THE KILN COMBUSTION EXHAUST THC
AND METHANE AND ETHANE EMISSIONS 25
TABLE 3.4.3-6 SUMMARY OF THE KILN COMBUSTION EXHAUST
STACK TARGETED VOC EMISSIONS 26
TABLE 3.4.3-7 SUMMARY OF THE KILN COMBUSTION EXHAUST
STACK TARGETED SVOC EMISSIONS 28
TABLE 7.4-1 SUMMARY OF RESULTS FOR TRACE METALS
ANALYSES ON EPA AUDIT SAMPLES 70
iv
-------
TABLE OF CONTENTS (Cont.1
LIST OF FIGURES
FIGURE 1.1-1 JOHNSON CITY BRICK FACILITY SITE PLAN ... 2
FIGURE 2.1-1 SCHEMATIC OF THE CRUSHING, SCREENING AND
STORAGE OPERATION 6
FIGURE 2.1-1 SCHEMATIC OF BAGHOUSE DUCTING AND SAMPLING
LOCATIONS FOR JOHNSON CITY BRICK PLANT . . 7
FIGURE 2.3-1 SCHEMATIC OF KILN A DRYER EXHAUST STACK
SAMPLING LOCATIONS 8
FIGURE 2.3-2 SCHEMATIC OF KILN A COMBUSTION ZONE
EXHAUST STACK SAMPLING LOCATIONS 9
FIGURE 5.1.1-1 BAGHOUSE DUCT SAMPLING AND TRAVERSE
POINT LOCATIONS 31
FIGURE 5.1.1-2 DRYER EXHAUST STACK SAMPLING AND TRAVERSE
POINT LOCATIONS 32
FIGURE 5.1.1-3 KILN A COMBUSTION ZONE EXHAUST STACK
SAMPLING AND TRAVERSE POINT LOCATIONS . . 33
FIGURE 5.1.3-1 EPA METHOD 3 SAMPLING TRAIN 35
FIGURE 5.1.5-1 EPA METHOD 201A/202 SAMPLING TRAIN ... 37
FIGURE 5.1.5-2 METHOD 201A RECOVERY PROCEDURE SOURCE:
40 CFR PART 51, APPENDIX M 38
FIGURE 5.1.6-1 METHOD 201A/202 RECOVERY PROCEDURE SOURCE:
40 CFR PART 51, APPENDIX M 41
FIGURE 5.1.6-2 METHOD 201A/202 ANALYSIS PROCEDURE SOURCE:
40 CFR PART 51, APPENDIX M 43
FIGURE 5.1.7-1 MULTIPLE METALS/TSP SAMPLING TRAIN ... 45
FIGURE 5.1.7-2 MULTIPLE METALS RECOVERY PROCEDURE SOURCE:
40 CFR PART 51, APPENDIX M ........ 47
FIGURE 5.1.7-3 MULTIPLE METALS ANALYSIS PROCEDURE SOURCE:
40 CFR PART 51, APPENDIX M 49
FIGURE 5.1.8-1 EPA METHOD 3 SAMPLING TRAIN 51
-------
TABLE OF CONTENTS (Cont.1
FIGURE 5.1.8-2 EPA METHOD 26 RECOVERY PROCEDURE SOURCE:
40 CFR PART 51, APPENDIX M 52
FIGURE 5.1.9-1 DRY EXTRACTIVE CONTINUOUS EMISSIONS
MONITORING SYSTEM FOR 02, C02, CO AND NOX 54
FIGURE 5.1.9-2 CONTINUOUS EMISSIONS MONITORING SYSTEM
FOR EPA METHOD 25A 55
FIGURE 5.1.10-1 VOLATILE ORGANIC SAMPLING TRAIN
(METHOD 0030) 58
FIGURE 5.1.10-2 METHOD 0030 RECOVERY PROCEDURE SOURCE:
EPA 600/8-84-007 59
FIGURE 5.1.10-3 METHOD 0030 ANALYSIS PROCEDURE SOURCE:
EPA 600/8-84-007 60
FIGURE 5.1.11-1 EPA METHOD 0010 SAMPLING TRAIN FOR
SEMIVOLATILE ORGANICS 61
FIGURE 5.1.11-2 METHOD 0010 RECOVERY PROCEDURE SOURCE:
EPA 600/8-84-007 63
FIGURE 5.1.11-3 METHOD 0010 ANALYSIS PROCEDURE SOURCE:
EPA 600/8-84-007 64
vi
-------
TABLE OF CONTENTS (Cont.l
LIST OF APPENDICES
APPENDIX A - TEST LOG
APPENDIX B.O •
APPENDIX
APPENDIX
APPENDIX
APPENDIX
APPENDIX
APPENDIX
APPENDIX
• CRUSHING, GRINDING, AND SCREENING OPERATION
APPENDICES
B.I - BAGHOUSE OUTLET; DATA AND RESULTS FOR EPA
METHOD 201A TESTING
B.2 - DATA AND RESULTS FROM PARTICULATE SAMPLING
FROM THE BAGHOUSE CATCH
B.3 - PROCESS SAMPLING: DATA AND RESULTS FOR
MOISTURE AND SIEVE ANALYSIS
B.4 - DATA AND RESULTS FOR HI-VOL AMBIENT SAMPLING
B.5 - BAGHOUSE OUTLET: RAW FIELD SAMPLING DATA FOR
EPA METHOD 201A TESTING
B.6 - RAW FIELD DATA FOR HI-VOL AMBIENT SAMPLING
B.7 - BAGHOUSE OUTLET: GRAVIMETRIC LABORATORY DATA
APPENDIX C.O - KILN A DRYER OUTLET STACK APPENDICES
APPENDIX C.I - DATA AND RESULTS FOR EPA METHOD 25A AND
MODIFIED METHOD 25A TESTING (THC, METHANE AND
ETHANE)
RAW FIELD SAMPLING DATA FOR EPA METHODS 2-4
DATA AND RESULTS FOR CONTINUOUS EMISSIONS
MONITORING (THC, METHANE AND ETHANE)
APPENDIX C.2
APPENDIX C.3
APPENDIX D.O - KILN COMBUSTION ZONE EXHAUST STACK APPENDICES
APPENDIX D.1.0
APPENDIX D.I.I
APPENDIX D.I.2
APPENDIX D.I.3
APPENDIX D.I.4
APPENDIX D.I.5
APPENDIX D.I.6
APPENDIX D.I.7
KILN COMBUSTION EXHAUST STACK DATA AND
RESULTS APPENDICES
DATA AND RESULTS FOR EPA METHOD 201A/202
TESTING
DATA AND RESULTS FOR EPA METHOD 29 TESTING
DATA AND RESULTS FOR EPA METHOD 26 TESTING
DATA AND RESULTS FOR EPA METHOD 25A AND
MODIFIED METHOD 25A TESTING (THC, METHANE
AND ETHANE)
DATA AND RESULTS FOR EPA METHOD 0030
TESTING
DATA AND RESULTS FOR EPA METHOD 0010
TESTING
DATA AND RESULTS FOR CONTINUOUS EMISSIONS
MONITORING (02,C02,CO, and NOx)
vii
-------
TABLE OF CONTENTS (Cont.l
APPENDIX D.2.0 - KILN COMBUSTION EXHAUST STACK
RAW FIELD DATA APPENDICES
APPENDIX D.2.1 - RAW FIELD SAMPLING DATA FOR EPA METHOD
201A/202 TESTING
APPENDIX D.2.2 - RAW FIELD SAMPLING DATA FOR
EPA METHOD 29 TESTING
APPENDIX D.2.3 - RAW FIELD SAMPLING DATA FOR
EPA METHOD 26 TESTING
APPENDIX D.2.4 - RAW FIELD SAMPLING DATA FOR
EPA METHOD 0030 TESTING
APPENDIX D.2.5 - RAW FIELD SAMPLING DATA FOR
EPA METHOD 0010 TESTING
APPENDIX D.3.0 - KILN COMBUSTION EXHAUST STACK LABORATORY
DATA APPENDICES
APPENDIX D.3.1 - GRAVIMETRIC LABORATORY DATA FOR THE KILN
COMBUSTION EXHAUST STACK
APPENDIX D.3.2 - EPA METHOD 29 MULTIPLE METALS LABORATORY
DATA
APPENDIX D.3.3 - EPA METHOD 26 FLUORIDE LABORATORY DATA
APPENDIX D.3.4 - EPA METHOD 0030 VOC LABORATORY DATA
APPENDIX D.3.5 - EPA METHOD 0010 SVOC LABORATORY DATA
APPENDIX E.O - COAL AND SHALE SAMPLING RESULTS
APPENDIX F.O - LABORATORY RESULTS FOR EPA TRACE METALS AUDIT
SAMPLES
APPENDIX G.O - EQUATIONS AND CALCULATIONS
APPENDIX G.I - CALCULATIONS FOR EPA METHODS 2-4
APPENDIX G.2 - CALCULATIONS FOR EPA METHOD 5 PARTICULATE,
METHOD 201A, AND METHOD 202
APPENDIX G.3 - CALCULATIONS FOR EPA METHOD 29 MULTIPLE
METALS
APPENDIX G.4 - GENERAL GASEOUS EMISSIONS CALCULATIONS
APPENDIX H.O - FIELD EQUIPMENT CALIBRATIONS
viii
-------
1.0 INTRODUCTION
1.1 SUMMARY
The U.S. Environmental Protection Agency (EPA), Office of
Air Quality Planning and Standards (OAQPS), Emission Inventory
Branch (EIB) is responsible for developing and maintaining air
pollution emission factors for industrial processes. EIB, in
collaboration with the Brick Institute of America, is currently
studying the brick manufacturing industry. The purpose of this
study is to develop emission factors for the coal-fired kiln
operations used by brick manufacturing facilities. The Emission
Measurement Branch (EMB) of OAQPS coordinated the emission
measurement activities at this plant. ETS Incorporated (ETS,
Inc.) conducted the ambient and source measurements. Midwest
Research Institute, Inc. (MRI) collected samples of the process
materials and obtained process data during testing.
EPA/EIB and the Brick Institute of America considered the
General Shale Brick Plant located in Johnson City, Tennessee to
be representative of this type of brick manufacturing operation.
Three areas of the manufacturing facility were tested; l) the raw
material crushing and screening operations; 2) the kiln dryer
zone; and 3) the kiln combustion zone. A facility site plan
showing the layout of the operation and the sampling locations is
presented in Figure 1.1-1.
The test program was conducted from July 27, 1993 through
July 31, 1993. Air sampling at the crushing and screening
operations for particulate matter (PM) and particulate matter
less than or equal to ten microns (PM10) was performed at the
baghouse outlet. In addition, background ambient air sampling
for PM and PM.0 was conducted around the crushing, screening and
storage building. The source and ambient testing were both
executed on July 27, 1993. Process materials from the grinding
and screening operations along with the baghouse catch were
sampled and analyzed for moisture content and particle size.
Source sampling at the kiln was performed on both the dryer
exhaust stack and the kiln combustion exhaust stack. The dryer
exhaust stack was sampled for methane, ethane and total
hydrocarbons on July 28, 1993. The kiln exhaust stack was
sampled for the following pollutants:
methane/ethane;
total hydrocarbons;
PM, PM.0, condensible particulate matter (CPM);
multiple metals;
hydrogen fluoride (HF);
nitrogen oxides (NOX);
carbon monoxide (CO)
volatile organic compounds (VOC);
semivolatile organic compounds (SVOC).
-------
1J.OOO GALLON
BKlCX OIL TANK
SOUTHERN HAILW
Figur* 1.1-1: Johnson City Brick Facility Site Plan
-------
The sampling was conducted from July 29 through July 31, 1993.
Table 1.1-1 identifies the metals targeted for measurement. The
VOC and SVOC compounds targeted for measurement in this test
program are presented in Tables 1.1-2 and 1.1-3, respectively.
TABLE 1.1-1: Targeted Metals for Johnson City Brick (Johnson
City, Tennessee)
METAL
antimony
arsenic
beryllium
cadmium
chromium
lead
manganese
mercury
nickel
phosphorus
selenium
-------
TABLE 1.1-2: Targeted Volatile Compounds
COMPOUND (VALIDATED1)
COMPOUND (NOT VALIDATED2)
chloromethane
bromomethane
methylene chloride
chloroform
trichlorofluoromethane*
carbon tetrachloride
trichloroethene*
benzene
tetrachloroethene
acetone
carbon disulfide
2-butanone
1,1,1-trichloroethane
vinyl acetate
2-hexanone*
toluene
ethylbenzene
styrene
o-xylene
m-/p-xylene
1 Validated Analytical Method
; Not a Validated Analytical Method
Not a listed HAP.
TABLE 1.1-3: Targeted Semivolatile Compounds
COMPOUND (VALIDATED1)
COMPOUND (NOT VALIDATED2)
phenol
naphthalene
2-methyIphenol
dimethylphthalate
dibenzofuran
di-n-butylphthalate*
bis(2-ethylhexy)phthalate
\ Validated Analytical Method
« Not a Validated Analytical Method
Not a listed HAP.
-------
1.2 TEST PROGRAM PERSONNEL
The key personnel who coordinated the test program and their
phone numbers are:
ETS, Inc., Project Manager, Ted Handel 703/265-0004
EIB Technical Coordinator, Ron Myers 919/541-5407
EMB Field Test Coordinator, John Brown 919/541-0200
General Shale Contact, Dave McNees 615/282-4661
MRI Process Monitor, Bryan Schrager 919/677-0249
2.0 PROCESS DESCRIPTION AND SAMPLING LOCATIONS
The Johnson City Brick Plant is located in Johnson City,
Tennessee and is also known as General Shale Plant Number 10.
The plant encompasses approximately 100 acres and is adjacent to
the General Shale mines No.l, No.12, and No.16. The Johnson City
plant has an annual manufacturing capacity of 60 million bricks
from its two tunnel-type kilns. The plant uses coal as a primary
fuel. Natural gas is used as a secondary fuel and is added to
the preheater section of the kiln in order to increase combustion
efficiency. Ten to twelve percent of the heat provided to the
kiln is from natural gas. Natural gas addition is also used
during a "flash" cycle which is employed to achieve a darker
brick surface. This "flashing" cycle occurs for approximately
one minute out of every three.
Emissions from the following operations were studied:
(1) raw material crushing and screening operations.
(2) brick drying process within the kiln.
(3) brick firing process within the kiln.
2.1 Raw Material Crushing, Screening and Storage Operation
A simplified process schematic for the raw material crushing
and screening operation is given in Figure 2.1-1.
The raw material (shale) is transported from the excavation
area by dump truck where it is loaded into the primary crusher.
The primary crusher consists of a single roll crusher where the
large pieces of shale are initially broken apart. From the
primary crusher, the crushed shale is transported via belt
conveyor to the 384 pan grinder. From the pan grinder, the
crushed shale is conveyed to a series of four 4' by 5' Leahy
vibrating screens. The oversize material may be sent either back
to the pan grinder or to a Pasco Claypactor. The Claypactor is a
type of hammer mill which is used for final size reduction of the
shale. The material exiting the Claypactor is conveyed back to
-------
the Leahy vibrating screens. The undersized material from the
screen is conveyed into the storage bins via a reciprocating belt
conveyor. This material is kept in the storage bins until it is
loaded into the brick making operations.
To Storage
Bins
Figure 2.1-1:
Schematic of the Crushing, Screening and Storage
Operation.
Background ambient measurements of PM and PM10 were
conducted outside the crushing and screening building. The
ambient sampling for PM and PM10 was performed using Hi-Vol
samplers to collect three sets of samples. The Hi-Vol sampling
location was approximately 100 feet north of the crusher building
overhead door as depicted in Figure 1.1-1
Particulate emissions from the size reduction and screening
operation were measured at the following locations: (1) the
baghouse outlet gas duct; (2) the baghouse particulate catch.
The PM and PM10 emissions of the crushing and screening
building were measured at the baghouse outlet gas duct. All
access doors except the shale loading door were closed during
sampling. The discharge at the bottom of the baghouse was tested
for total mass. Figure 2.1-2 presents a schematic of the
-------
baghouse duct sampling locations. In addition, process material
was sampled at the crushing and screening building for sieve and
moisture analyses.
Collected
Portlculote
Discharges
Figure 2.1-2:
Schematic of Baghouse Ducting and Sampling
Locations for Johnson City Brick Plant.
2.2 Mixing and Extrusion Operation
The sized shale granules are removed from the storage bins
and transported on the mill room feed belt conveyor to the
texture mixing area. The granules are off-loaded into two feed
hoppers that service twin lines of brick extruding equipment.
The extruding equipment for each line consists of a J.C. Steele
pug sealer and a J.C. Steele extruder. Water and sand are mixed
with the shale granules in the extruders to form a thick paste.
The paste is extruded in rectangular form and the bricks are then
cut to size. The unfired bricks are then conveyed to a setter or
are hand set on the kiln cars. After setting, the bricks are
transferred to the predryer.
-------
2.3 Kiln Operation
The Johnson City plant has two tunnel kilns labeled A and B.
Each kiln is separated into four sections:
(1) the predryer.
(2) the dryer.
(3) the combustion zone.
(4) the cooling zone.
Each kiln has two exhaust stacks. The dryer exhaust stack
is located at the start of the dryer zone. It draws heated air
from the cooling section located at the end of the tunnel kiln.
A schematic of the sampling locations utilized at the dryer
exhaust stack is presented in Figure 2.3-1.
—
82.
i
n=
25" '
HE
32.5"
1 '
I
t
36"
1
30"
^
—
^6" Ports
3" Port
S \
15"
1
Roof Line
Figure 2.3-1: Schematic of Kiln A Dryer Exhaust Stack Sampling
Locations.
-------
The combustion zone exhaust stack is located at the
beginning of the combustion zone and draws air through the
combustion zone. The stack is rectangular in shape and measured
24" x 25". Figure 2.3-2 displays a schematic of the sampling
locations for the kiln combustion zone exhaust stack.
51
6" Ports
t
28'
f
3" Port
23"
T
7"
Kiln A Roofline
44"
Figure 2.3-2: Schematic of Kiln A Combustion Zone Exhaust Stack
Sampling Locations.
-------
2.4 Pollution Control Description
The air pollution control equipment at the Johnson City
plant consists of a pulse-jet type baghouse that services the
crushing, screening and storage building. The baghouse is a
Wheelabrator-Frye Ultra-Jet Aire Filter No. 115/Model 108 that
has the following operating parameters:
•Gas Volume (acfm): 17,000
•Gas Temperature: Ambient
•Gas to Cloth Ratio: 8.02
•Flange to Flange Pressure Drop (W.G.): 7-inches
•Tubesheet Pressure Drop (W.G.): 6-inches
•Number of Cells: 5
•Number of Bags per Cell: 30
•Bag-Type: 16-oz. Polyester, Double-Density felt bags.
•Bag-Dimensions: 6-inches I.D. by 108-inches long.
•Cleaning Cycle: 75 seconds
10
-------
3.0 SUMMARY AND DISCUSSION OF TEST RESULTS
3.1 Objectives and Test Matrix
The purpose of the test program is to develop emission
factors for the brick manufacturing industry.
The specific objectives of the test program for the Johnson
City Brick Plant were:
(1) Measure the following emissions for the crushing,
grinding, and storage operation:
• Particulate Matter
PM10
(2) Measure the following emissions for the kiln at the
dryer exhaust stack:
• Total Hydrocarbons
• Methane
• Ethane
(3) Measure the following emissions for the kiln at the
brick-firing exhaust stack:
Particulate Matter
PM10
Condensible Particulate Matter
Multiple Metals
Hydrogen Fluoride
Carbon Monoxide
Nitrogen Oxides
Total Hydrocarbons
Methane
Ethane
Volatile Organics
Semivolatile Organics
3.2 Test Matrix
Table 3.2-1 presents an overview of the sampling and
analytical matrix for measuring emissions from the Johnson City
Brick Plant. A more detailed delineation of the source test
program is contained in the field test log in Appendix A of this
report.
11
-------
TABLE 3.2-1:
Overview of Test Program for Johnson City Brick
Plant.
LOCATION
Baghouse Outlet
Outside of Crushing
& Screening Bldg.
Storage Bldg.
Baghouse Catch
Kiln A Dryer Stack
Kiln A Dryer Stack
Kiln A Dryer Stack
Kiln Combustion
Exhaust
Kiln Combustion
Exhaust
Kiln Combustion
Exhaust
Kiln Combustion
Exhaust
Kiln Combustion
Exhaust
Kiln Combustion
Exhaust
Kiln Combustion
Exhaust
Kiln Combustion
Exhaust
Kiln Combustion
Exhaust
Kiln Coal and
Shale
SAMPLING
METHOD
EPA Method 201A
Ambient Hi-Vol
Grab
Grab
EPA Methods 1-4
EPA Method 25A
Modified Meth. 25A
Method 0010
Modified Meth. 25A
EPA Method 25A
EPA Method 26
Method 0030
EPA Method 29
EPA Method 7E
Modified Meth. 10
Methods 201A/202
Grab
TEST
PARAMETER(S)
PM/PM10
Background PM, PM10
Sieve, Moisture
PM
Velocity, Moisture,
Gas Flowrate
Total Hydrocarbons
Methane/Ethane
Semivolatiles
Methane/Ethane
Total Hydrocarbons
Hydrogen Fluoride
Volatile Organic
Compounds
Multiple Metals/PM
Nitrogen Oxides
Carbon Monoxide
PM/PM10 and
Condensible PM
Elements, Ash,
moisture
DATB(S)
TESTED
07/27/93
07/27/93
07/27/93
07/28/93
07/28/93
07/28/93
07/29-30/93
07/29-30/93
07/29-30/93
07/30-31/93
07/29-30/93
07/30-31/93
07/30-31/93
07/30-31/93
07/31/93
07/27/93
12
-------
3.3 Field Test Changes, Problems, and Comments
3.3.1 Kiln Combustion Exhaust Stack*
3.3.3.1 Continuous Emissions Monitoring; The
continuous emissions monitoring for total hydrocarbons revealed a
steady decline in THC concentrations from the first test run on
July 29, 1993. However, the concentration of ethane and methane
remained relatively consistent during this time period. The THC
concentration measurements were continued beyond the three valid
EPA Method 25A test runs to evaluate the trend in THC
concentrations. It should be noted that the THC concentrations
remained at a low level for the extended test period subsequent
to the Method 25A test runs. All Method 25A CEM data for the
kiln combustion exhaust is contained in Appendix D.I.4 of this
report.
The oxygen CEM during test run 3 of Method 201A/202 testing
at the Kiln Combustion Exhaust (KCE-M202A/202-R3) exceeded the
calibration drift limit of 3.0% as stated in 40 CFR 60 Appendix
A. System calibration drift was 11.68% at the zero span for this
run. However, the datum was adjusted to account for calibration
drift.
3.4 Summary of Results
3.4.1 Crushing, Screening, and Storage Operation Sampling
3.4.1.1 Ambient Sampling; Ambient particulate sampling was
conducted in order to determine background particulate
concentrations surrounding the crushing and screening building.
In order to determine particulate emission rates from the
grinding building, it is important to have a measure of the
particulate concentrations of the ambient air. Ambient PM and
PM10 measurements were made at the crushing, grinding, and
screening operation coinciding with source testing at the
baghouse outlet for particulates. Table 3.4.1-1 presents the
average PM and PM10 concentrations measured. The field and
laboratory data for the ambient monitoring is contained in
Appendix B.3.
13
-------
TABLE 3.4.1-1: Summary of Ambient Hi-Vol Sampling for TSP and
PM10 at the Johnson City Brick Plant.
TSP:
Date
Start Time
End Time
Average Flow - scfm
TSP Cone. - ug/m3
PM10s
Date
Start Time
End Time
Average Flow - scfm
PM10 Cone. - ug/m3
Percentaae PM10
Run 1
07/27/93
07:41
10:38
39.9
202.1
07/27/93
07:28
10:25
39.6
159.3
78.8
Run 2
07/27/93
10:45
14:06
40.1
161.8
07/27/93
10:37
13:55
39.4
106.4
65.8
Run 3
07/27/93
14:12
17:08
41.3
133.0
07/27/93
14:00
17:04
40.7
103.3
77.7
Average
165.6
123.0
74.1
3.4.1.2 Particulate and PMin Emissions at the Baohouse
Outlet; Sampling for total filterable particulate and 10 micron
or smaller particulate was conducted using EPA Method 201A. The
total particulate emissions, including TSP and PM10, averaged
0.00345 grains per dry standard cubic feet (gr/dscf) with a range
of 0.00164 to 0.00444 gr/dscf. The PM10 emissions averaged
0.00237 gr/dscf with a range of 0.00123 to 0.00352 gr/dscf. On
average, PM10 constituted 71% of the total particulate matter.
The PM10 percentage of total particulate for Run 3, 49.9%, is
anomalous compared to the first two runs. Table 3.4.1-2 presents
a summary of the Method 201A test program. Detailed data and
results for each Method 2OLA test run are contained in Appendix
B.I.
In addition to the PM measured during the Method 201A
testing at the baghouse outlet stack, the PM of the baghouse
catch was sampled. The results from this testing are contained
in Appendix B.2. The total particulate loading may be estimated
by combining the total PM from the Method 2OLA testing and the
particulate measured from the baghouse catch.
14
-------
TABLE 3.4.1-2: Summary of Baghouse Outlet Particulate Emissions
RUN I.D.
DATE
TIME STARTED
TIME ENDED
BO-M201A-R1
07/27/93
09:04
10:17
BO-M201A-R2
07/27/93
10:55
12:18
BO-M201A-R3
07/27/93
13:05
14:36
AVERAGE
SAMPLING PARAMETERS
Metered Volume - dcf 29.664
Corrected Volume - dscf 29.363
Total Test Time - min 66
% Isokinetics 103.9
D50 9.71
GAS PARAMETERS
Gas Temperature - oF 76.1
Oxygen - % 20.8
Carbon Dioxide - % 0.1
Moisture - % 1.76
37.423
35.918
81
108.6
9.63
81.0
20.8
0.1
2.91
42.414
40.152
90
99.3
9.54
86.8
20.8
0.1
3.51
36.039
34.758
78.0
101.6
9.62
81.4
20.8
0.1
2.6
GAS FLOWRATE
Velocity - ft/sec 51.28
Actual Volume - acfm 19401
Standard Volume - dscfm 18418
49.93
18887
17559
46.37
17540
16034
48.83
18471
17226
PM10 EMISSIONS
Concentration - gr/dscf
Mass Rate - Ib/hr
3.52E-03
0.556
1.36E-03
0.205
1.23E-03
0.168
2.37E-03
0.362
PM> IQu EMISSIONS
Concentration - gr/dscf
Mass Rate - Ib/hr
9.16E-04
0.145
2.76E-04
0.042
1.23E-03
0.169
1.07E-03
0.157
TOTAL PM
Concentration - gr/dscf 4.44E-03
Mass Rate - Ib/hr 0.700
1.64E-03
0.247
2.46E-03
0.338
3.45E-03
0.519
PERCENT AS PM10
79.4
83.1
49.9
70.8
15
-------
3.4.1.3 Process Sampling; Process samples of the shale and
clay were collected from the crushing and screening operations
and analyzed for sieve and moisture analyses. Table 3.4.1-3
contains a summary of the sieve analyses. Additional information
regarding the sieve and moisture analyses is contained in
Appendix B.3. The sieve analysis was consistent for two of the
three samples. The third sample sieve analysis revealed an
overall smaller mean particulate diameter. The two consistent
samples had an average of 60.1% particles less than 18 mesh or
1000 microns. The third sample contained 73.6% particles less
than 18 mesh. The third sample contained a larger percentage of
smaller particles down to 35 mesh or 500 microns. The two
consistent samples averaged 42.9% while the third sample
contained 54.4% particles less than 35 mesh. The composition of
particles less than 60 mesh is comparable for all three samples.
Moisture analyses for the three samples ranged from 8.11% to
10.81%.
TABLE 3.4.1-3: Summary of Results for Sieve Analysis from Process
Samples Collected at the Crushing and Screening
Operation.
MESH SIZE
18 Mesh Sample
20 Mesh Sample
25 Mesh Sample
30 Mesh Sample
35 Mesh Sample
60 Mesh Sample
80 Mesh Sample
100 Mesh Sample
200 Mesh Sample
SIZE
(Microns)
1000
850
710
600
500
250
180
150
75
RUN 1
Percent
Less Than
58.47
43.45
48.67
44.82
41.67
30.36
26.45
24.82
16.24
RUN 2
Percent
Less Than
61.82
56.80
51.94
47.91
44.07
32.05
27.77
26.20
18.42
RUN 3
Percent
Less Than
73.56
68.73
63.60
58.82
54.39
37.75
30.90
27.53
16.70
3.4.2 Kiln A Drver Stack Sampling
3.4.2.1 Total Hydrocarbons. Methane, and Ethane Emissions*
Total hydrocarbon (THC) emissions were monitored instrumentally
in accordance with procedures outlined in the Code of Federal
Regulations. Title 40. Part 60 f40 CFR 601. Appendix A. Method
25A. EPA Methods 2 through 4 were conducted simultaneously with
the Method 25A testing for flue gas flowrate determination.
Methane and ethane were measured instrumentally by modifying the
Method 25A sampling system. An activated charcoal filter was
utilized to remove all hydrocarbons except methane and ethane
from the gas sample prior to instrumental analysis. The methane
and ethane concentrations were measured immediately before the
16
-------
Method 25A test runs. Although the methane and ethane
concentrations were not measured simultaneously with the THC
concentrations, the two measurements are compared to determine
the concentration of total gaseous non-methane organics (TGNMO).
The three test runs measured consistent concentrations of THC and
methane and ethane, averaging 0.324 Ib/hr (as carbon) and 0.15
Ib/hr (as carbon), respectively. Using the THC and
methane/ethane emissions for each of the three test runs, the
average TGNMO mass emissions equal 0.173 Ib/hr (as carbon).
Table 3.4.2-1 presents a summary of the THC, Methane and Ethane
test results. Detailed data for the velocity and flowrate
measurements are contained in Appendix C.I. The continuous
emissions monitoring data for the Method 25A and Modified Method
25A testing are contained in Appendix C.3.
17
-------
TABLE 3.4.2-1: Summary of Kiln A Dryer Exhaust Total
Hydrocarbons, Methane, and Ethane Emissions
RUN I.D.
DATE
TIME STARTED
TIME ENDED
SAMPLING PARAMETERS
Metered Volume - dcf
Corrected Volume - dscf
Total Test Tine - min
GAS PARAMETERS
Gas Temperature - oF
Oxygen - %
Carbon Dioxide - %
Moisture - %
GAS FLOWRATE
Velocity - ft/sec
Actual Volume - acfm
Standard Volume - dscfm
KAD-M1-4-R1 KAD-M1-4-R2 KAD-M1-4-R3
07/28/93 07/28/93 07/28/93
11:05 12:40 14:15
12:05 13:40 15:15
AVERAGE
35.484
33.403
60
145.3
19.4
0.1
6.69
60.16
17720
14483
35.162
32.583
60
143.5
18.8
0.8
6.10
60.46
17806
14689
36.160
33.363
60
148.0
18.7
0.8
6.84
60.49
17817
14474
35.602
33.116
60
145.6
19.0
0.6
6.54
60.37
17781
14549
THC EMISSIONS
Cone. - pptnwv (as Propane) 3.72 3.58 3.82 3.71
Cone. - ppmdv (as Propane) 3.99 3.81 4.10 3.97
Cone. - ppmdv (as Carbon) 11.96 11.44 12.30 11.90
Mass Rate - Ib/hr (as Carbon) 0.324 0.314 0.333 0.324
METHANE AND ETHANE EMISSIONS*
Cone. - ppmwv (as Propane) 2.13 1.62 1.42 1.72
Cone. - ppmdv (as Propane) 2.28 1.73 1.52 1.84
Cone. - ppmdv (as Carbon) 6.85 5.18 4.57 5.53
Mass Rate - Ib/hr (as Carbon) 0.186 0.142 0.124 0.150
TGNMO EMISSIONS
Mass Rate - Ib/hr (as Carbon) 0.138
0.172
0.209
0.173
* Methane/Ethane emissions are based on a 14-minute test conducted
immediately prior to each THC test run.
18
-------
3.4.3 Kiln Combustion Exhaust Stack Sampling
3.4.3.1 PM. PM]n. and CPM Emissions: Particulate emissions
were measured at the kiln combustion exhaust stack using a
combined Method 201A/202 approach to determine total filterable
particulate, particulate less than 10 microns, and condensible
particulate matter. In addition, total particulate was measured
in combination with multiple metals using EPA Method 29.
The total particulate matter measured during Method 29
testing averaged 0.1253 gr/dscf at a mass emission rate of 4.67
Ib/hr. All three runs measured relatively consistent particulate
concentrations. Table 3.4.3-2 presents a summary of the Method
29 test program. More detailed data and results for each
individual test run is contained in Appendix D.I.2 of this
report.
The PM10 emissions measured during EPA Method 201A/202
testing averaged 0.085 gr/dscf at a mass emission rate of 3.14
Ib/hr. The combined PM10 and particulate matter greater than 10
/z measured during the testing averaged 4.27 Ib/hr. The
condensible particulate matter (CPM) was measured utilizing
Method 202. The CPM averaged 0.026 gr/dscf at a mass emission
rate of 0.96 Ib/hr. The CPM averaged 20.7% of total particulate
emissions for the kiln combustion exhaust stack. Table 3.4.3-1
contains a summary of the Method 201A/202 test program which is
presented in detail in Appendix D.I.I.
19
-------
TABLE 3.4.3-1: Summary of the Kiln Combustion Exhaust PM, PM10,
and CPM Emissions
RUN I.D.
DATE
TIME STARTED
TIME ENDED
KCB-M201A/202-R1 KCB-M201A/202-R2 KCB-M201A/202-R3
07/31/93 07/31/93 07/31/93
11:45 14:07 16:49
13:29 15:55 18:26
AVERAGE
SAMPLING PARAMETERS
Metered Volume - dcf
Corrected Volume - dscf
Total Test Time - min
% Isokinetics
D50
GAS PARAMETERS
Gas Temperature - oF
Oxygen - %
Carbon Dioxide - %
Moisture - %
GAS FLOWRATE
Velocity - ft/sec
Actual Volume - acfm
Standard Volume - dscfm
PM10 EMISSIONS
Concentration - gr/dscf
Mass Rate - Ib/hr
PM> 10 MICRON EMISSIONS
Concentration - gr/dscf
Mass Rate - Ib/hr
CPM EMISSIONS
Concentration - gr/dscf
Mass Rate - Ib/hr
TOTAL PM EMISSIONS
Concentration - gr/dscf
Mass Rate - Ib/hr
41.126
39.685
94
107.2
9.47
333.6
13.12
6.62
10.25
28.83
7208
4318
0.090
3.323
0.032
1.171
0.024
0.883
0.145
5.378
44.103
42.171
100
114.8
9.52
331.5
13.04
6.58
9.76
26.70
6675
4030
0.073
2.517
0.044
1.529
0.042
1.454
0.159
5.500
36.054
34.080
81.0
107.2
9.39
342.0
12.01
6.47
11.43
29.44
7359
4305
0.080
2.958
0.036
1.334
0.028
1.026
0.144
5.318
38.590
36.882
87.5
107.2
9.43
337.8
12.57
6.55
10.84
29.13
7284
4311
0.085
3.141
0.034
1.252
0.026
0.955
0.145
5.348
3.4.3.2 Trace Metals Emissions; Trace metal sampling was
performed together with total particulate sampling utilizing EPA
Method 29. Table 3.4.3-2 presents a summary of the trace metal
and total particulate test program. The trace metal emissions
were in agreement within a factor of 2 of the mean from run to
run. Samples were analyzed for antimony arsenic, beryllium
20
-------
cadmium, chromium, lead, manganese, mercury, nickel, phosphorus,
and selenium. Detectable quantities of all the metals were
detected in each of the sample runs. Detailed data and results
for each Method 29 test run is provided in Appendix D.I.2.
TABLE 3.4.3-2: Summary of the Kiln Combustion Exhaust Multiple
Metals and Total Particulate Emissions
RUN I.D. KCB-M29-R1
DATE
TIME STARTED
TIME ENDED
SAMPLING PARAMETERS
Metered Volume - dcf
Corrected Volume - dscf
Total Test Time - min
% I8okineti.es
GAS PARAMETERS
Gas Temperature - oF
Oxygen - %
Carbon Dioxide - %
Moisture - %
GAS FLOWRATE
Velocity - ft/sec
Actual Volume - acfm
Standard Volume - dscf
PARTICULATE EMISSIONS
Concentration - gr/dscf
Cone. - gr/dscf @ 7% O2
Mass Rate - Ib/hr
METALS EMISSIONS - lb/hr
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Lead
Manganese
Mercury
Nickel
Phosphorus
Selenium
07/30/92
12:28
14:44
73.243
70.904
120
107.7
334.0
13.16
6.53
10.60
28.83
7208
4294
0.1199
0.2153
4.41
1.06E-04
8.71E-04
9.94E-05
2.95E-05
4.97E-04
6.13E-04
3.27E-04
6.77E-04
1.07E-03
3.62E-03
2.98E-03
KCB-M29-R2
07/30/92
15:12
17:31
74.772
72.097
120
107.7
336.5
12.86
6.34
10.53
29.40
7349
4368
0.1229
0.2124
4.60
8.74E-05
9.01E-04
1.07E-04
2.37E-05
5.16E-04
6.27E-04
3.11E-04
6.03E-04
1.12E-03
3.61E-03
2.89E-03
KCE-M29-R3
07/31/92
09:05
11:24
72.554
71.292
120
105.9
336.0
13.10
6.62
10.46
29.49
7373
4392
0.1330
0.2370
5.01
9.67E-05
9.21E-04
1.09E-04
1.43E-05
5.69E-04
5.08E-04 '
3.10E-04
6.69E-04
1.30E-03
3.84E-03
3.41E-03
AVERAGE
73.523
71.431
120
107.1
335.5
13.04
6.49
10.53
29.24
7310
4351
0.1253
0.2216
4.67
9.65E-05
8.98E-04
1.05E-04
2.25E-05
5.27E-04
5.83E-04
3.16E-04
6.50E-04
1.16E-03
3.69E-03
3.09E-03
21
-------
3.4.3.3 NCL and CO Emissions; Nitrogen oxide and carbon
monoxide emissions were monitored instrumentally during the EPA
Method 29 multiple metals and total particulate testing.
Nitrogen oxide emissions were measured in conjunction with EPA
Method 7E. The NOX concentration averaged 154.03 ppmdv with a
mass emission rate of 4.80 Ib/hr. Carbon monoxide emissions were
measured utilizing a modified EPA Method 10 technique. The CO
concentration average 322.92 ppmdv with a mass emission rate of
6.13 Ib/hr. Table 3.4.3-3 presents a summary of the NOX and CO
emissions. Detailed continuous emissions monitoring data is
contained in Appendix D.1.7.
TABLE 3.4.3-3: Summary of the Kiln Combustion Exhaust NOX and CO
Emissions.
RUN I.D.
DATE
TIME STARTED
TIME ENDED
KCB-M7E/10B-R1 KCE-M7E/10B-R2 KCE-M7E/10B-R3
07/30/93 07/30/93 07/31/93
12:29 15:12 09:05
14:44 17:31 11:24
AVERAGE
GAS PARAMETERS*
Gas Temperature - OF
Oxygen - %
Carbon Dioxide - %
Moisture - %
334.0
13.16
6.53
10.60
336.5
12.86
6.34
10.53
336.0
13.10
6.62
10.46
335.5
13.04
6.50
10.53
GAS FLOWRATE*
Velocity - ft/sec 28.83
Actual Volume - acfm 7208
Standard Volume - dscfm 4294
29.40
7349
4368
29.49
7373
4392
29.24
7310
4351
CO EMISSIONS
Concentration - ppmdv
Mass Rate - Ib/hr
318.26
5.96
326.21
6.21
324.30
6.21
322.92
6.13
NOx EMISSIONS
Concentration - ppmdv 160.36
Mass Rate - Ib/hr (as NO2) 4.93
145.17
4.54
156.55
4.93
154.03
4.80
* Gas parameters and gas flowrate data were taken from EPA Method 29
testing which was conducted concurrently.
22
-------
3.4.3.4 Hydrogen Fluoride Emissions; Hydrogen fluoride
sampling was conducted using EPA Method 26. The concentration of
hydrogen fluoride averaged 110.1 ppmdv 6 7% 02 at a mass emission
rate of 0.85 Ib/hr. The hydrogen fluoride emissions were
consistent for two of the three test runs. The third run of the
Method 26 testing (KCE-M26-R3) measured a hydrogen fluoride
concentration greater than 2 times that of the next highest HF
measurement. Table 3.4.3-4 displays the results of the hydrogen
fluoride testing. Detailed hydrogen fluoride sampling data and
analytical results are contained in Appendices D.2.3 and D.3.3,
respectively.
TABLE 3.4.3-4: Data and Results for Kiln Combustion Exhaust
Hydrogen Fluoride Testing.
RUN NUMBER
DATE
START TIME
END TIME
KCB-M26-R1
07/30/93
12:28
14:44
KCE-M26-R2
07/30/93
15:12
17:31
KCB-M26-R3
07/31/93
09:05
11:24
AVERAGE
SAMPLING DATA
Initial Meter Volume - 1 934.790 1175.340 1420.070 1176.733
Final Meter Volume - 1 1175.070 1415.970 1664.410 1418.483
Net Meter Volume - 1 240.280 240.630 244.340 241.750
Average Meter Temp. - F 112.1 . 116.6 106.5 111.8
Barometric Pres. - in.Hg 29.97 29.97 30.00 29.98
Avg. Meter Pres. - in.W.C. 2.4 2.4 2.4 2.4
Meter Cal. Factor - Gamma 0.9985 0.9985 0.9985
Corr. Meter Volume - dscf 7.875 7.825 8.096 7.932
Oxygen - %dv* 13.16 12.86 13.10 13.04
GAS FLOWRATE DATA*
Velocity - ft/sec 28.83 29.40 29.49 29.24
Actual Volume - acfm 7208 7349 7373 7310
Standard Volume - dscfm 4294 4368 4392 4351
LABORATORY DATA
Fluoride Analysis
Total Liquid Volume - ml
Fluoride Cone. - mg/liter
73.0
74.0
68.0
106.0
80.0
259.0
73.7
146.3
HF EMISSIONS
Concentration - ppmdv
Cone. - ppmdv @ 7% O2
Mass Rate - Ib/hr
30.672
55.082
0.410
41.188
71.208
0.561
114.439
203.935
1.566
62.099
110.075
0.846
* Gas flowrate and oxygen content data were taken from EPA Method 29
testing which was conducted concurrently.
23
-------
3.4.3.5 Total Hydrocarbonsf Methane, and Ethane Emissions;
Total hydrocarbon (THC) emissions were monitored
instrumentally in accordance with procedures outlined in EPA
Method 25A. Methane and ethane were measured instrumentally by
modifying the Method 25A sampling system. An activated charcoal
filter was utilized to remove all hydrocarbons except methane and
ethane. The methane and ethane concentrations were measured
before and after each of the Method 25A test runs. Although the
methane and ethane concentrations were not measured
simultaneously with the THC concentrations, the two measurements
are compared to determine the concentration of total gaseous non-
methane organics (TGNMO). Table 3.4.3-5 presents the results of
the THC, methane and ethane emissions testing.
The THC emissions steadily declined during the Method 25A
testing. The first Method 25A test run (KCE-M25A-R1) measured an
average mass rate of 1.21 Ib/hr reported as carbon. The second
and third runs (KCE-M25A-R2 and KCE-M25A-R3) averaged 0.68 Ib/hr
and 0.36 Ib/hr (as carbon), respectively. However, the
concentration of ethane and methane remained relatively constant
during the testing, averaging a mass emission rate of 0.55 Ib/hr
(as carbon). The average TGNMO mass emission rate was 0.4 Ib/hr.
The THC concentration measurements were continued beyond the
three valid EPA Method 25A test runs to evaluate the trend in THC
concentrations. All continuous emissions monitoring data are
contained in Appendix D.I.4.
24
-------
TABLE 3.4.3-5: Summary of the Kiln Combustion Exhaust THC and
Methane and Ethane Emissions.
RUN I.D.
DATE
TIME STARTED
TIME ENDED
KCB-M25A-R1
07/29/93
08:48
10:48
KCB-M25A-R2
07/29/93
11:38
13:38
KCB-M25A-R3
07/29/93
14:26
15:26
AVERAGE
GAS PARAMETERS*
Gas Temperature - oF
Oxygen - %
Carbon Dioxide - %
Moisture - %
327.5
15.9
4.5
9.58
327.5
15.9
4.5
9.58
336.1
14.7
5.6
8.36
330.4
15.5
4.9
9.17
GAS FLOWRATE*
Velocity - ft/sec
Actual Volume - acfm
Standard Volume - dscfm
29.52
7381
4488
29.52
7381
4488
28.79
7198
4388
29.28
7198
4455
THC EMISSIONS
Cone. - ppmwv (as Propane) 43.50
Cone. - ppmdv (as Propane) 48.11
Cone. - ppmdv (as Carbon) 144.33
Mass Rate - Ib/hr (as Carbon) 1.21
24.45
27.04
81.12
0.68
13.27
14.48
43.44
0.36
27.07
29.88
89.63
0.75
METHANE/ETHANE EMISSIONS**
Cone. - ppmwv (as Propane) 20.98
Cone. - ppmdv (as Propane) 23.20
Cone. - ppmdv (as Carbon) 69.61
Mass Rate - Ib/hr (as Carbon) 0.584
18.11
20.03
60.09
0.504
20.39
22.25
66.75
0.548
19.83
21.83
65.48
0.545
TGNMO EMISSIONS
Mass Rate - Ib/hr (as Carbon) 0.626
0.176
0.401
* Gas parameters and gas flowrate data are taken from KCE-M0010-R1 for
M25A runs 1 and 2 and KCE-M0010-R2 for M25A run 3.
** Methane/Ethane emissions are calculated from the average of two 14-minute
tests; one conducted prior to and one conducted after each of the
individual M25A test runs.
25
-------
3.4.3.6 VOC Emissions: Volatile organic compounds (VOC)
emissions were sampled using Method 0030 targeting the compounds
identified in Table 1.1-2. In addition, the samples were
analyzed for the Method 8240, Table 2 list of volatile compounds.
Detectable quantities of bromomethane, methylene chloride,
trichlorofluoromethane, 1,1,1-trichloroethane, ethylbenzene, m-
/p-xylene, and o-xylene were found in one or more of the sample
runs. Table 3.4.3-6 contains a summary of the detailed
information contained in Appendix D.I.5.
TABLE 3.4.3-6: Summary of the Kiln Combustion Exhaust Stack
Targeted VOC Emissions.
RUN I.D.
DATE
START TIKE
END TIME
KCB-M0030-R1
07/29/93
09:23
12:50
KCE-M0030-R2
07/29/93
14:12
17:49
KCE-M0030-R3
07/29/93
08:15
11:33
AVERAGE1
POLLUTANT CONCENTRATION - Ib/hr
Chloromethane
Bromomethane
Trichlorofluoromethane
Carbon disulfide
Acetone
Methylene chloride
Chloroform
Vinyl acetate
2-Butanone
1,1, 1-Tr ichloroethane
Carbon tetrachloride
Benzene
Trichloroethene
Toluene
Tetrachloroethene
2-Hexanone
Ethylbenzene
m-/p-Xylene
o-Xylene
Styrene
* 6.85E-04
1.45E-04
4.54E-05
< 6.52E-07
* 6.09E-03
1.57E-05
< 6.52E-07
< 6.52E-07
* 1.89E-03
< 6.52E-07
< 6.52E-07
* 1.97E-03
< 6.52E-07
* 2.05E-03
< 6.52E-07
< 5.22E-06
1.77E-04
* 1.20E-03
4.11E-04
< 6.52E-07
< 6.29E-04
1.56E-04
* 2.29E-05
* 2.21E-05
* 2.58E-03
O.OOE+00
< 6.63E-07
< 6.63E-07
* 1.72E-03
< 6.63E-07
< 6.63E-07
* 1.87E-03
< 6.63E-07
* 1.55E-03
< 6.63E-07
< 5.52E-06
1.23E-04
7.94E-04
2.78E-04
< 6.63E-07
* 1.11E-03
1.69E-04
* 1.99E-04
* 2.25E-05
* 4.78E-03
O.OOE+00
< 6.60E-07
< 6.60E-07
* 1.34E-03
< 3.37E-04
< 6.60E-07
* 1.84E-03
< 6.60E-07
* 1.33E-03
< 6.60E-07
< 5.50E-06
1.17E-04
6.07E-04
2.37E-04
< 6.60E-07
< 8.09E-04
1.57E-04
* 8.90E-05
* 1.51E-05
* 4.49E-03
5.24E-06
< 6.58E-07
< 6.58E-07
* 1.65E-03
< 1.13E-04
< 6.58E-07
* 1.89E-03
< 6.58E-07
* 1.64E-03
< 6.58E-07
< 5.41E-06
1.39E-04
* 8.66E-04
3.09E-04
< 6.58E-07
1 The emission values for each run represent the average of two pairs of
VOST tube analyses. See Appendix D.I.5 for more detailed test results.
< Not detected.
* Detected but below the quantitation limit; quantity is estimated.
26
-------
3.4.3.7 SVOC Emissions: Semi-volatile compounds (SVOC)
were sampled utilizing Method 0010 targeting phenol, naphthalene,
2-methylphenol, dimethylphthalate, dibenzofuran, di-n-
butylphthalate, and bis(2-ethylhexyl)phthalate. In addition, the
samples were analyzed for the Method 8270, Table 2 list of semi-
volatile compounds. Detectable quantities of phenol,
naphthalene, di-n-butylphthalate, and bis(2-ethylhexyl)phthalate
were found in one or more of the sample runs. Table 3.4.3-7
presents a summary of the Method 0010 test program. Detailed
data and results for the SVOC testing are contained in Appendix
D.I.6.
3.4.3.8 Coal and Shale Testing: Three samples of coal used
to fire the kilns were collected and analyzed for moisture, ash
content, carbon, hydrogen, sulfur, nitrogen, oxygen, and heat
content (Btu/lb). In addition, shale samples were collected and
analyzed for moisture and sulfur content. The data and results
from the analyses are contained in Appendix E.O.
27
-------
TABLE 3.4.3-7: Summary of the Kiln Combustion Exhaust Stack
Targeted SVOC Emissions.
RUN I.D.
DATE
TIME STARTED
TIME ENDED
KCB-M0010-R1
7/29/93
08:43
13:11
KCB-M0010-R2
7/29/93
14:12
16:42
KCB-M0010-R3
7/30/93
08:15
11:49
AVERAGE
SAMPLING PARAMETERS
Metered Volume - dcf 150.256
Corrected Volume - dscf 142.521
Total Test Time - min 240
% Isokinetics 103.6
117.294
109.693
192
101.9
120.078
115.462
192
105.5
129.209
122.559
208
103.7
GAS PARAMETERS
Gas Temperature - oF
Oxygen - %
Carbon Dioxide - %
Moisture - %
327.5
15.9
4.5
9.58
336.1
14.7
5.6
8.36
332.8
10.1
9.6
7.99
332.1
13.6
6.6
8.64
GAS FLOWRATE
Velocity - ft/sec 29.52
Actual Volume - acfm 7381
Standard Volume - dscfm 4488
28.79
7198
4388
29.06
7264
4461
29.12
7281
4445
SEMIVOLATILE EMISSIONS (lb/hr)
VALIDATED COMPOUNDS
Phenol
Naphthalene
NOT VALIDATED COMPOUNDS
O.OOE+00
1.10E-04
2-Methylphenol < 1.30E-05 <
Dimethylphthalate < 4.46E-06 <
Dibenzofuran < 3.83E-06 *
Di-n-butylphthalate O.OOE+00
bis(2-EthyIhexyl)phthalate 0.OOE+00
3.15E-04
O.OOE+00
1.48E-05 <
5.56E-06 <
2.75E-06 <
O.OOE+00
1.88E-04
3.93E-04
2.71E-05
2.36E-04
4.56E-05
1.49E-05 < 1.42E-05
5.72E-06 < 5.25E-06
4.91E-06 * 2.75E-061
O.OOE+00 O.OOE+00
8.08E-04 3.32E-04
< Not detected
* Detected but below the quantitation limit; quantity is estimated
1 Average is composed of estimated values only; non-detected values
are not included in the calculation of the average.
28
-------
4.0 SAMPLING AND ANALYTICAL PROCEDURES FOR AMBIENT TESTING
4.1. Ambient Particulate Matter (PM and PMin^ - Hi-Vol:
Ambient sampling of PM was conducted in accordance with 40 CFR 50
Appendix B. This method provides a measurement of the mass
concentration of total suspended particulate matter in ambient
air. Ambient sampling of PM10 was conducted in accordance with
40 CFR 50 Appendix J. The Hi-Vol samplers were used to establish
background PM and PM10 concentrations at the site. The samplers
operate by drawing a measured quantity of air through a tared
filter.
4.2 Sampler Setup and Calibration; The ambient Hi-Vol PM
and Hi-Vol PM10 samplers were collected at the sampling site.
The samplers were secured to level platforms at least 2 meters
above the surrounding terrain. The platform at the grinding
building inlet location was constructed using industrial
scaffolding. The samplers were located on raised platforms with
extensions such that they were separated by a minimum of 2
meters. This assured separation minimized interference between
the samplers.
The Hi-Vol samplers were calibrated on site. The samplers
were calibrated by measuring the pressure drop across a certified
calibrated orifice plate attached to the sampler inlet. A flow
rate versus pressure drop calibration curve was generated for
each sampler.
4.3 Sampler Operation and Filter Recovery; A pre-tared,
numbered quartz filter was attached to the inlet screen of each
sampler. Using the generated calibration curves, each sampler
was adjusted to a predetermined flow rate. The samplers were
operated for three distinct tests, each lasting approximately 3
hours. The sample times and flow rates were recorded in order to
calculate the total air volume sampled.
At the completion of the each test, the filter was
recovered by carefully removing it from the inlet sampler screen
and folding it, exposed side in, and placing it in a labeled
envelope for later gravimetric analysis. Prior to weighing, the
filter was conditioned to a controlled temperature and humidity
for at least 24 hours. Filters were inspected for tears or
pinholes which, if present, will cause the filter to be voided.
Filters were weighed to the nearest 0.1 mg.
29
-------
5.0 SAMPLING AND ANALYTICAL PROCEDURES FOR SOURCE TESTING
5.1.1 Sampling and Traverse Point Determination - EPA
Method 1
EPA Method 1 procedures are used to determine suitability of test
locations and to calculate the sampling and traverse points for
each location. The results of EPA Method 1 analysis for each
sampling location are provided in the following sections.
5.1.1.1 Sampling and Traverse Points for the Baohouse
Outlet Stack; Figure 5.1.1-1 presents a schematic of the
sampling and traverse points used at the baghouse outlet stack
location. A total of 24 points (12 points for each of two ports)
were utilized for all pollutant and gas flowrate measurements.
5.1.1.2 Sampling and Traverse Points for the Kiln A Dryer
Stack; A total of 24 points (12 points for each of two ports)
were utilized for all gas flowrate measurements at the Kiln Dryer
Stack location. Figure 5.1.1-2 displays a schematic of the
traverse points used to measure flue gas velocity, temperature,
moisture.
5.1.1.3 Sampling and Traverse Points for the Kiln
Combustion Exhaust Stack; A total of 24 points (6 for each of 4
ports) were utilized for all pollutant and gas flowrate
measurements at the kiln combustion exhaust stack location.
Figure 5.1.1-3 presents a schematic of the sampling and traverse
point locations.
30
-------
34.0"
POINT
1
2
3
4
5
6
7
8
9
10
11
12
% ID
2.1
6.7
11.8
17.7
25.0
35.6
64.4
75.0
82.3
88.2
93.3
97.9
DISTANCE FROM
INSIDE OF PORT
(inches)
1.00*
2.28
4.01
6.02
8.50
12.10
21.90
25.50
27.98
29.99
31.72
33.00*
* Points moved 1-inch away from stack wall.
INSIDE STACK DIAMETER
DISTANCE UPSTREAM FROM
DISTURBANCE
DISTANCE DOWNSTREAM FROM
DISTURBANCE
34 in
92 in
22 in
2.83 ft
2.7 DIA
0.6 DIA
Figure 5.1.1-1:
Baghouse duct sampling and traverse point
locations.
31
-------
30.0
POINT
1
2
3
4
5
6
7
8
9
10
11
12
% ID
2.1
6.7
11.8
17.7
25.0
35.6
64.4
75.0
82.3
88.2
93.3
97.9
DISTANCE FROM
INSIDE OF PORT
(inches)
1.00*
2.01
3.54
5.22
7.50
10.68
19.32
22.50
24.69
26.46
27.99
29.00 *
* Points moved 1—inch away from stack wall.
INSIDE STACK DIAMETER
DISTANCE UPSTREAM FROM
DISTURBANCE
DISTANCE DOWNSTREAM FROM
DISTURBANCE
30 in
68.5 in
49.8 in
2.5 ft
2.3 DIA
1.7 DIA
Figure 5.1.1-2:
Dryer Exhaust Stack Sampling and Traverse
Point Locations.
32
-------
22.0"
;
J.O"
14.0"
i
10.0"
I
6.0"
2.0"
t
4
4
4
4
+
4
4
-f
-f
9.4"
4
4
5.6"
Duct Cross Section
Inside Stack Dimensions
-H
4-
4
4
24"
21.9"
25" x 24"
Figure 5.1.1-3:
Kiln A Combustion Zone Exhaust Stack Sampling
and Traverse Point Locations.
33
-------
5.1.2 Volumetric Measurements - EPA Method 2: EPA
Reference Method 2 was used to measure the gas velocity in order
to determine volumetric flow rates of the stack gases. Stainless
steel Type-S pitot tubes were used to measure the gas velocity
heads. The pitot tubes were calibrated against a NBS traceable
pitot tube in accordance with Method 2 procedures. Calibrated
Type-K thermocouples were used to determine stack gas
temperatures. Velocity and temperature measurements were made at
each of the traverse points determined by EPA Method 1.
5.1.3 Molecular Weight Determination - EPA Method 3 and 3A;
Gas compositional measurements (02 and C02) for determining the
average molecular weight of the stack gases were performed using
procedures of EPA Method 3 at the baghouse outlet and kiln A
dryer exhaust test locations. EPA Method 3 procedures were also
utilized at the kiln combustion exhaust stack during Method 0010
testing for SVOC. Multi-point, integrated sampling was used to
obtain a constant rate sample of flue gas concurrent with
pollutant testing. Sampling was of the same duration (except
purges following port changes) as the pollutant runs.
A stainless steel probe was affixed to the pollutant
sampling probe for this purpose. A peristaltic pump, delivering
500 to 750 Ml/min of flue gas, was used to fill a Tedlar bag.
Moisture was removed from the sample gas by means of an air-
cooled condenser located prior to the pump. Figure 5.1.3-1 shows
a schematic of the Method 3 sampling train.
EPA Method 3A procedures were followed for measuring flue
gas composition at the kiln combustion exhaust stack for all
testing except SVOC. Method 3A involves measuring gas
composition (02 and C02) instrumentally. Sampling was conducted
concurrent with pollutant testing with integrated gas samples as
part of the continuous emissions monitoring system.
5.1.4 Flue Gas Moisture Content - EPA Method 4; The flue
gas moisture content was measured in conjunction with each of the
pollutant tests according to the sampling and analytical
procedures outlined in EPA Method 4. The flue gas moisture for
each test was determined by gravimetric analyses of the water
collected in the impinger train. All impingers were contained in
an ice bath during the testing in order to assure complete
moisture condensation of the sampled flue gas. Any moisture
which was not condensed in the impingers was captured in the
silica gel contained in the final impinger.
34
-------
Flowmeter
Fine Adjust
Volve
Method 3 Probe
(1/4" SS Tubing)
Isokinetic Sompling Probe
Stack Wall
Air-Cooled
Water
Condenser
Teflon
Sample
Line
Rigid. Protective Container
Figure 5.1.3-1: EPA Method 3 Sampling Train
5.1.5 PM and PM10 Sampling - EPA Method 201A; EPA Method
201A was used for determination of PM and PM10 emissions from
the baghouse outlet and the kiln combustion zone exhaust. This
procedure utilized an in-stack PM10 sizing device and an in-stack
filter in conjunction with an EPA Method 17 train. Gravimetric
analyses were performed as described by EPA Method 5.
5.1.5.1 Sampling Train Descriptions; The Method 201A train
consisted of a cyclone followed by a 47 mm diameter glass fiber
(Gelman) filter. These in-stack components were attached to an
unheated stainless steel probe. The Method 201A sampling train
is shown in Figure 5.1.5-1. The stack gases were drawn through
the cyclone where a portion of the airborne particulate is
separated before it passes through a Gelman filter. The size
fraction of the particles that have a 50 percent probability of
exiting the cyclone to the Gelman filter are defined as the
cyclone cut size (D50) . The reguired particle size for a valid
test run ranges from 9 urn to 11 urn. After the sample gas passes
35
-------
through the Gelman filter, it then enters a stainless steel
conduit which leads into a glass impinger train consisting of
four impingers immersed in an ice bath. The first, second and
third impingers each contained 100 milliliters of water. The
fourth impinger was initially empty and the fifth impinger
contained approximately 200 grams of color-indicating silica gel.
5.1.5.2 Pre-Test Preparation; Before sampling/ a velocity
traverse of the stack was performed. This traverse/ along with
an analysis of the stack gas, was used to determine the nozzle
diameter (s) needed to maintain a flow rate through the cyclone to
achieve a cut size of lOjim. A nozzle was selected by comparing
the velocity heads from the velocity traverse with the Ap,^,, and
calculated for each nozzle.
5.1.5.3 Sampling Train Operation: Throughout the sampling
run the orifice pressure head was maintained at the pretest
calculated value. If the stack gas temperature varied by more
than 28°F from the pretest average temperature, then the orifice
pressure head was determined using the pretest average ± 28°F.
Sampling was started at the first traverse point. Sampling
time (or dwell time) at this point was determined by the pretest
calculations. After moving to the next traverse point, the dwell
time at this point was determined by the velocity head at this
point. This procedure was repeated for the remainder of the
traverse points.
36
-------
Gelmon
Cyclone Filter
__^ -L Stoinless Steel Conduit
Inclined Dry Cos
Monometer Meter
Vone
Pump
Silica Gel Blank
Figure 5.1.5-1:
EPA Method 201A/202 Sampling Train
5.1.5.4 Sample Train Recovery; During the run, if
necessary, and following the run, the filters were quantitatively
recovered into their original tared and labeled foil wrappers.
Following the run, the particulate matter was quantitatively
recovered using acetone on all of the surfaces of the sampling
train from the probe through the cyclone to the cyclone exit to
the front half of the in-stack filter holder, including the "turn
around" cup inside the cyclone and the interior surfaces of the
exit tube. The rinses were placed into labeled glass bottles.
The filters and rinses were transported to the ETS laboratory for
gravimetric analyses as described by EPA Method 5. The impinger
water and silica gel were recovered as per EPA Method 4
procedures. Figure 5.1.5-2 presents a schematic of the sampling
train recovery procedure.
37
-------
Filter
Corefully remove
and place in
petri dish
Brush loose
participate
onto filter
Seal petri dish
Container 1
Cyclone and
"Turnaround Cup"
Front-half of
Filter Holder
Cyclone
Housing
Impinger 5
Silica Gel
Rinse
with
acetone
Rinse
with
acetone
Rinse
with
acetone
Empty contents
into sample
container
Container 2
Container 3
(Discard)
Container 8
Figure 5.1.5-2.
Method 201A Recovery Procedure
Source: 40 CFR Part 51, Appendix M
5.1.5.5 PM10 Analyses: Analyses of the glass fiber filters
and cyclone acetone rinses from the Method 201A sampling trains
were performed gravimetrically in accordance with EPA Method 5
procedures. The total PM10 catch included the particulate
collected in the acetone rinses from all of the surfaces from the
cyclone exit to the front half of the in-stack filter holder,
including the "turn around" cup inside the cyclone and the
interior surfaces of the exit tube, as well as the particulate
collected by the glass fiber filter.
5.1.5.6 PM Analyses: The PM catch from the Method 201A
trains included the particulate recovered from the nozzle and the
cyclone, excluding the "turn around" cup and the interior surface
of the exit tube. Analyses of the acetone rinses for PM larger
than 10 micrometers from the Method 201A sampling trains were
performed gravimetrically in accordance with EPA Method 5
procedures.
38
-------
5.1.6 PM. PM10. and CPM Sampling - EPA Method 201A/202;
Sampling of total PM, PM.0, and CPM at the combustion zone
exhaust stack was conducted with a combined Method 201A/202
sampling train. The analyses of the samples included Method 201A
procedures for determining total PM and PM10 and Method 202
procedures for determining CPM.
5.1.6.1 Sampling Train Description; The Method 201A/202
train consists of a cyclone followed by a 47 mm diameter glass
fiber (Gelman) filter. These in-stack components are attached to
an heated stainless steel probe. For sampling at the combustion
zone exhaust, a teflon liner will be used with the sample probe.
The Method 201A/202 sampling train is the same as the Method 201A
train presented in Figure 5.1.5-1.
The stack gases are drawn through the cyclone, the Gelman
filter, the probe and into a five glass impinger train immersed
in an ice bath. The first, second, and third impingers each
contained 100 milliliters of deionized distilled water. The
fourth impinger was initially empty, and the fifth initially
contained approximately 200 grams of silica gel.
5.1.6.2 Pre-Test Preparation; Before sampling, a velocity
traverse of the stack was performed. This traverse, along with
an analysis of the stack gas, was used to determine the nozzle
diameter(s) needed to maintain a flow rate through the cyclone to
achieve a cut size of lOjxm. A nozzle was selected by comparing
the velocity heads from the velocity traverse with the Apmi and
^Pmax calculated for each nozzle. The details of the calculations
are provided in Appendix G.2. Two additional pretest
calculations were also needed. First, the orifice pressure head
needed to maintain the necessary cyclone flow rate was
calculated. Second, the dwell time for the first traverse point
was calculated from the pretest traverse.
5.1.6.3 Sampling Train Operation; Throughout the sampling
run the orifice pressure head was maintained at the pretest
calculated value. If the stack gas temperature varied by more
than 28°F from the pretest average temperature, then the orifice
pressure head was determined using the pretest average ± 28°F.
Sampling was started at the first traverse point. Sampling
time (or dwell time) at this point was determined by the pretest
calculations. After moving to the next traverse point, the dwell
time at this point was determined by the velocity head at this
point. This procedure was repeated for the remainder of the
traverse points.
5.1.6.4 Sample Recovery and Clean-up; At the conclusion of
the sampling run, the filters were quantitatively recovered into
petri dishes. Following the run, the particulate matter was
quantitatively recovered using acetone from all of the surfaces
39
-------
from the cyclone exit to the front half of the in-stack filter
holder, including the "turn around" cup inside the cyclone
and the interior surfaces of the exit tube. The rinses were
placed into labeled glass bottles. The filters and rinses were
transported to the ETS laboratory for gravimetric analyses as
described by EPA Method 5.
The back-half of the sampling train (impingers plus
connecting glassware) was recovered in accordance with EPA Method
202 procedures. The pH of the first impinger was measured
immediately after the test. If the pH was less than 4.5, then
the entire impinger train was purged for one hour using purified
air in accordance with Method 202 procedures. If the pH of the
first impinger exceeded 4.5, then the purge was omitted.
A schematic of the recovery of the combined 201A/202 train is
presented in Figure 5.1.6-1 . The analysis for the 201A and 202
sampling trains were slightly different.
40
-------
Filter
T
Cyclone and
"Turnaround Cup"
Front-half o(
Filter Holder
Carefully remove
and place in
petri dish
Brush loose
participate
onto filter
Cyclone
Housing
Rinse
with
acetone
Rinse
with
acetone
Rinse
with
acetone
Seal petri dish
Container 1
Container 2
Container 3
(Discard)
Bock-half of
Filter Holder and
Impingers 1-4
Rinse filter
housing twice
with distilled water
Impingers 1-4
Impinger 5
Silica Gel
Measure contents
of each impinger
Empty contents
into sample
container
Rinse twice
with distilled
water
Rinse
with
MeCI2
Empty contents
into sample
container
Container 4 and 5
Container 7
Container 8
Figure 5.1.6-1:
Method 201A/202 Recovery Procedure
Source: 40 CFR Part 51, Appendix M
41
-------
5.1.6.5 Field Blanks; One field blank was collected during
the test program for Method 201A/202 testing at the kiln
combustion stack. Each field blank consisted of a complete
sampling train set up on site and recovered during the recovery
of the normal stack test samples.
5.1.6.6 CPM Analyses - EPA Method 202; The determination
of the total condensible particulate matter (CPM) in the back-
half of the sampling train was determined in accordance with
Method 202 procedures. The total sulfate concentration of the
impinger contents was not analyzed because the pH of the solution
was greater than 4.5. The impinger contents and aqueous rinses
were combined with the methylene chloride rinses and extracted
twice with methylene chloride using a separatory funnel. The
samples were divided into organic (methylene chloride) and
inorganic (aqueous) fractions. The organic fraction was
evaporated at room temperature and pressure, and the resulting
residue gravimetrically analyzed to a constant weight. The
inorganic fraction was evaporated to dryness at 105°C.
The back-half condensible particulate catch equals the
organic residue plus the inorganic residue plus the combined
water removed by the acid-base reaction based on the impinger
analysis for sulfate.
The total particulate catch equals the front-half probe
rinse and filter plus the back-half condensibles. A schematic of
the analytical procedure is contained in Figure 5.1.6-2.
5.1.6.7 PM10 Analyses - EPA Method 201A; Analyses of the
glass fiber filters and cyclone acetone rinses from the PM10
sampling were performed gravimetrically in accordance with EPA
Method 5 procedures. The total PM10 catch included the
particulate collected in the acetone rinses from all of the
surfaces from the cyclone exit to the front half of the in-stack
filter holder, including the "turn around" cup inside the cyclone
and the interior surfaces of the exit tube, as well as the
particulate collected by the glass fiber filter. A schematic of
the analytical procedure is contained in Figure 4.1.8.6-1.
42
-------
Contoiner 1
Filter
Contoiner 2
-------
5.1.7 Multiple Metals with PM - EPA Multi-Metals Procedure:
Sampling for antimony, arsenic, beryllium, cadmium, total
chromium, lead, manganese, mercury, nickel, phosphorous, and
selenium was performed in accordance with EPA Method 5 in
conjunction with Section 3.1 of "Methods Manual for Compliance
with BIF Regulations (EPA/530-SW-91-010)". This method is
commonly referred to as the Multi-Metals procedure which is
proposed as EPA Method 29. In addition, the filter and probe
washes were analyzed for determining PM in accordance with EPA
Method 5.
5.1.7.1 Sampling Train Description; The testing was
conducted utilizing the multi-metals sampling train as
illustrated in Figure 5.1.7-1. A heated stainless steel probe
with a quartz liner was used to withdraw the gas sample. The
probe was equipped with an appropriately sized integrated quartz
nozzle fused directly to the liner for isokinetic gas withdrawal.
From the nozzle and probe, sample gas was pulled through a
heated glass filter holder which holds a Pallflex ultra-pure 2500
QUAT-UP quartz filter supported on a teflon frit. The filter was
maintained at a temperature sufficiently high to prevent the
condensation of water (248 ± 25°F). Sample gas subsequently
passed through an impinger train consisting of seven glass
impingers immersed in an ice bath. The first impinger was
initially empty. The second and third impingers each contained
100 milliliters of 5% nitric acid/10% hydrogen peroxide solution.
The fourth impinger was initially empty. The fifth and sixth
impingers each contained 100 milliliters of 4% potassium
permanganate/10% sulfuric acid solution. The seventh impinger
contained approximately 200 grams of silica gel. The amount of
moisture collected in the sampling train was quantified in order
to determine the stack gas moisture content in accordance with
EPA Method 4.
44
-------
STACK
Figure 5.1.7-1:
Multiple Metals/TSP Sampling Train
5.1.7.2 Sample Train Preparation; All glassware components
of the multiple metals sampling train were pre-cleaned before
use. The following cleaning procedure was used:
1) Wash with hot water and detergent.
2) Rinse with tap water three times.
3) Rinse with deionized, distilled water three times.
4) Soak in a 10% nitric acid solution for four hours.
5) Rinse three times with deionized water.
6) Rinse three times with acetone and allow to air dry.
All glassware openings were covered with Teflon tape until
sampling.to prevent contamination.
5.1.7.3 Sample Train Operation; Sampling was done in
accordance with EPA Method 5 procedures and specifications,
including leak checking, isokinetic sampling rate and stack
traversing.
45
-------
5.1.7.4 Sample Recovery and Clean-up; At the completion of
each test, the probe was removed from the train and the ends of
the probe and sample train capped. The probe was cleaned on the
test platform, while the remainder of the sample train was
transported to a clean-up site for recovery. The sample recovery
procedure is shown in Figure 5.1.7-2.
5.1.7.5 Field Blanks: One field blank was collected during
the test program for each location from which metals sampling was
conducted. Each field blank consisted of a complete sampling
train set up on site and recovered during the recovery of the
normal stack test samples. In addition, audit metals samples
were analyzed as a measure of QA/QC. Section 6.4 of this report
discusses the audit samples in detail.
5.1.7.6 PM Analyses - EPA Method 5; Particulate matter was
determined in accordance with EPA Method 5 procedures. The
filter was analyzed gravimetrically to a constant weight. The
front half rinse was evaporated and analyzed gravimetrically to a
46
-------
Probe ond Front— holf Impinger 1 and
Rlter of niter Holder Back-half of
T
Carefully remove
with teflon tweezers
and place in
petri dish
Rinse back-half
Impinger 7
Filter Holder Impinqers 2-3 Impinger 4 Impinqers 5-6 Silica Gel
1
of filter holder Measure Measure Measure
ond all connecting lines contents of contents of contents of
three times with each impinger impinger each impinger
0.1 N HNO,
Record the volume
of the condensate
copured in the
Brush loose Brush with nonmetallic brush
partic
onto
first impinger
Empty contents
into sample
container
Empty contents Empty contents
ulate ond rinse probe and front-half ' into s
filler of filter holder three Empty contents conl
times with acetone ml° sornPle
Seal petri dish
container
Rinse first impinger
three tir
ample into s
oiner cont
Empty contents
ample 1 into s
}iner Rinse each impinger cant
three times with
acidified KMnOj
n*
-------
constant weight. The total particulate catch equaled the sum of
the front half rinse and the filter.
5.1.7.7 Multi-Metals Analyses - EPA Multi-Metals; The
filter, front-half rinses, and contents of impingers 1 through 4
of the multi-metals sampling train were analyzed for antimony,
arsenic, beryllium, cadmium, total chromium, lead, manganese,
nickel, phosphorous, and selenium. The rinses and contents of
impingers 5 and 6 were analyzed for mercury.
Analyses of the filters and front-half acetone rinses were
conducted after completion of the Method 5 gravimetric analyses.
SW-846 Method (atomic absorption) was used to determine the
metals concentrations.
The sampling train components (including the digested
filter, probe washes, and impinger contents and rinses) were
prepared for analysis in accordance with the procedures given in
the EPA draft method. All digestions were performed using a 600-
watt microwave digester and Teflon pressure relief vessels.
After preparation, the samples were analyzed with a Perkin Elmer
Plasma 2000 inductively coupled plasma (ICP) atomic absorption
spectrometer for antimony, arsenic, beryllium, cadmium, total
chromium, lead, manganese, nickel, phosphorous, and selenium. A
Coleman 50A cold vapor atomic absorption spectrometer (CVAAS) was
used to analyze the samples for mercury.
Duplicate analyses were performed on all metals samples. In
addition, field blanks were analyzed. Spikes were added to the
samples to determine the metals recovery efficiencies. A
schematic of the analytical procedure is contained in Figure
5.1.7-3.
48
-------
Container 3 Container 2 Container 1 Container 4 Container 5A, 5B, & 5C Container 6
FH Nitric Rinse FH Acetone Rinse Filter Impingers 1 — 3 Impinqers 4 — 6 Silica Gel
Reduce to dryness t
in a tared beaker Desiccate to 1
constant weight
1 Aliquot token
for CVAAS
for Hg analysis
I Determine filter Fraction 28
| parliculate weight 1
Solubilize residue i
with cone. HNOj Digest with acid
and permanganate
1
1
f
Acidify
remaining
sample to PH 2
with cone. HNOj
Fraction 2A
\
Reduce volume
to near dryness
at 95°C for 2 hours and digest with
Divide into 0.5 g for "<* ^ CVAAS
i sections and digest
Acidify to PH 2 each section with
with cone. HNOT cone. HF and HNO-?
1
Reduce volume to
near dryness and
digest with HF
and cor
ic. HNO3
Filter and dilute
to known volume
Frnrtinn 1
Remove 50 to 100 ml ... ... .
aliquot for Hg Dla-est wllh °cld,a^c
" analysis by CVAAS " permanganate at 95
Fraction IB ° water bath for 2 nou
'"'" " I
41 I
V V •
Analyze by ICAP for Analyze for Analyze aliquot for
target metals metals by GFAAS1 Hg using CVAAS
Fraction 1A Fraction 1A
HNO-j and HoO?
Analyze
by ICAP for
15 target metals
I
\
Analyze by
GFAAS
for metals^
Individually, three
'C in separate digestions
rs and analyses:
digest with acid
and permanganate
at 95°C for 2 hours \
and analyze Wejgn ,o
F \' "^A ^R ^r nearest 0.5 g
'Analysis by AAS for metals found at less than 2 ug/ml in digestate solutions, if desired. Or analyze for each metal by AAS, if desired.
Figure 5.1.7-3:
Multiple Metals Analysis Procedure
Source: 40 CFR Part 266, Appendix IX, Section 3
49
-------
5.1.8 Hydrogen Fluoride fHF) - EPA Method 26; HF emissions
were measured in accordance with EPA Method 26. The procedure
involves absorbing the HF in dilute sulfuric acid and analyzing
the solution for total fluorides using an ion chromatography
technique.
5.1.8.1 Sampling Train Description; A schematic of the
Method 26 sampling train is shown in Figure 5.1.8-1. A heated
glass probe was used for sample withdrawal. The gas stream was
passed through a heated Teflon filter and five glass impingers.
The impingers were immersed in an ice bath. The first impinger
was initially left empty, a shortened tube is used to prevent
bubbling of the gas sample through the collected condensate. The
second and third impingers were each charged with 15 ml of 0.1
Normal sulfuric acid solution for HF absorption. The fourth
impinger was charged with 15 ml of 0.1 Normal sodium hydroxide to
absorb acid gases harmful to the dry gas meter. The fifth
impinger.was charged with silica gel to absorb any moisture
before the stream enters the dry gas meter.
50
-------
3-Woy
Gloss Stopcock
P*.'.*,*,*,*,*.*.*,*.*,*.", ...''. j
Vone
PumD
Figure 5.1.8-1:
EPA Method 26 Sampling Train
5.1.8.2 Sampling Train Operation: The gas stream was
sampled at a single point in the center of the stack for 120
minutes at a sampling rate of approximately 2 liters per minute.
All sampling procedures, such as leak checking and system
purging, were in accordance with EPA Method 26. The impingers
were maintained in an ice bath during the sampling period. The
sample train was initially leak checked from the probe and
subsequently checked at the three way stopcock for the subsequent
runs. The sample trains were leak checked to demonstrate a
leakage rate not in excess of 2% of the average sample.
5.1.8.3 Sample Recovery and Clean-up; A schematic of the
recovery of the Method 26 sampling train is contained in Figure
5.1.8-2.
51
-------
Impingers 1 — 3
Impinger 4
Impinger 5
Silica Gel
Measure impinger
contents
Empty, contents
into sample
container
Rinse three times with
distilled water
Measure impinger
contents
Rinse three times with
distilled water
Empty contents
into sample
container
Container 1
Container 2
(Discord)
Container 3
Figure 5.1.8-2:
EPA Method 26 Recovery Procedure
Source: 40 CFR Part 60, Appendix A
5.1.8.4 Field Blanks; One field blank was collected during
the HF test program at the kiln combustion exhaust stack. The
field blank consisted of a complete sampling train set up on site
and recovered during the recovery of the normal stack test
samples.
5.1.8.5 Hydrogen Fluoride Analyses; The contents of the
first three impingers of the Method 26 train were analyzed for
fluoride in accordance with EPA Method 26 procedures. The
contents of the fourth impinger (sodium hydroxide) was not
analyzed. Ion chromatography was employed in the analyses. A
schematic of the analytical procedure is contained in Figure
5.1.8-3. '
52
-------
5.1.9 Continuous Emissions Monitoring for (X. C02. CO. ^.
and THC - Instrumental Methods; Instrumental monitoring of the
stack gases were performed in accordance with the following
procedures:
GAS REFERENCE METHOD INSTRUMENT TYPE
02 Method 3A Teledyne Model 320A Chemical
Cell Portable 02 Analyzer
C02 Method 3A HORIBA Model PIR-2000 NDIR
C02 Analyzer
NOX Method 7E TECO Model 10AR Chemilu-
minesence NOX Analyzer
CO Modified M10 TECO Model 48 NDIR CO Analyzer
THC Method 25A J.U.M. Model VE-7 Heated
THC Analyzer (FID)
All of the analyzers except the hydrocarbon analyzer
measured gas concentrations on a dry volume basis. The
hydrocarbon analyzer measured the concentrations in parts per
million wet volume as propane (ppmwv as C3H8) .
5.1.9.1 Sampling System Description; An integrated, remote
instrumental system housing the pollutant gas analyzers as well
as the diluent gas (O? and CO2) monitors were used. The design
incorporated a dry extractive system. All of the instruments
were housed in a trailer located at ground level.
Figure 5.1.9-1 presents a schematic of the dry sampling
system. Each dry sampling system consisted of a heated stainless
steel probe located at the stack port location. A heated glass
fiber filter was attached to the probe for rough particulate
removal. A short section of heated Teflon sample line delivered
the sample to an ice-cooled condenser designed to remove the flue
gas moisture. An unheated Teflon sample line transported the dry
gas sample from the stack port location down to the instrumental
system. The sample gas exiting the Teflon sample line was pumped
to the O2, C02, CO, and NOX monitors.
The sampling system for the hydrocarbon analyzer
incorporated a heated stainless steel probe, a heated glass fiber
filter, and a heated Teflon sample line. The sample line was
heated along its entire length from the stack sampling location
to the analyzer. Methane and ethane determination was performed
by installing an activated charcoal filter in the sample line to
remove all hydrocarbons except methane and ethane. Figure 5.1.9-
2 presents a schematic of the wet sampling system used for THC
and methane and ethane monitoring.
53
-------
3-Woy
Valve
H«ot«d Stoinl.u stMl Prob*
Data Acquisition
7
y y y x^c^t
rY^)
Condeniate K s(
Flowmeter
Heated /
Teflon
Sample Line
Teflon
Diaphragm
Pump
Unheated Teflon
/ Sample Line
To Individual
Analyzer
Calibration Manifold
# # #
Calibration Ca*««
Figure 5.1.9-1: Dry Extractive Continuous Emissions Monitoring
System for 02, C02/ CO, and NOX.
54
-------
3-Woy
Volve
Heated Stainless Steel Probe
7
Flowmeter
x x x x.
X X X X X X X X X X X X X X
VOC (ppmwv)
Signal
To Datalogger
VOC Q
Analyzer ^^
Hydrogen Calibration
Fuel Gas
Heated
Teflon
Sample Line
Figure 5.1.9-2:
Continuous Emissions Monitoring System for
EPA Method 25A.
5.1.9.2 Data Acquisition System; The response outputs of
the monitors were recorded digitally by a Campbell Scientific
Model CR10WP multi-channel data acquisition system. The system
sampled at a rate of 60 Hz, and stored one-minute average values.
5.1.9.3 Calibration: At the beginning of every test day,
each monitor in the dry sampling system was zeroed, using Zero
Nitrogen, and spanned, using a certified calibration gas (EPA
Protocol 1 certified or ± 1% Traceable Standards) with a
concentration of 80-100% of the instrument span. Following local
calibration a mid range gas, 40-60% of the instrument span, was
introduced locally to each monitor to check for response
linearity.
55
-------
At the beginning of every test day in which THCs were to be
measured, each THC monitor was zeroed, using Zero Nitrogen, and
spanned, using a certified propane calibration gas (EPA Protocol
1 certified or ± 1% Traceable Standards) with a concentration of
80-90% of the instrument span. Following local calibration a mid
range gas (45-55% of the instrument span) and a low range gas
(25-35% of instrument span) was introduced locally to each
monitor to check for response linearity.
After locally calibrating all monitors, calibration gas was
introduced remotely through the probe in order to verify the
absence of sampling system bias. The bias error did not exceed
5% of the instrument span as required by EPA Reference Method 6C.
After each test run, Zero Nitrogen and a high range
calibration gas was introduced locally to each monitor to check
for calibration drift error. In accordance with Methods 6C and
25A, the instrument drift did not exceed 3% of the instrument
span except for the oxygen monitor on Method 201A/202 Run 3 at
the kiln combustion exhaust stack (KCE-M201A/202-R3). All gas
values were adjusted to compensate for system calibration drift.
At the end of every test day, calibration gas was again
introduced remotely through the probe in order to verify the
absence of sampling system bias.
56
-------
5.1.10 Volatile Orqanics Sampling; Sampling for volatile
organics was conducted in accordance with Method 0030 of SW-846.
5.1.10.1 Sampling Train Description; A schematic of the
volatile organic sampling Train (VOST) is shown in Figure 5.1.10-
1. The primary components of the VOST system were the probe,
condenser, condensate trap, a second condenser, and a backup
resin trap. The first cartridge was packed with approximately
1.6 grams of Tenax-GC resin. The second cartridge was packed
with Tenax-GC and petroleum-based charcoal (1 gram of
each, approximately 3:1 by volume), with the charcoal on the
outlet end of the cartridge. The first trap retained most of the
higher boiling analytes. Lower boiling analytes and the portion
of the higher boiling analytes that break through the first
cartridge were retained on the second trap. Analytes that
collect in the condensate trap were purged into the second trap
and condenser units. The metering system consisted of vacuum
gauges, a leak-free pump, a calibrated rotameter, and a dry gas
meter.
5.1.10.2 Sampling Train Operation; Sampling was done in
accordance with Method 0030 of SW-846 procedures, including leak
checking and sampling rate. The train was leak checked by
closing the valve at the inlet to the first condenser and pulling
a vacuum of 10 in. Hg above the normal operating pressure. The
traps and condensers were isolated from the pump and the leak
check noted. The leak rate was less than 0.1 in. Hg per minute.
After leak checking, sample collection was accomplished by
opening the valve at the inlet to the first condenser, turning on
the pump, and sampling at a constant rate for 20 minutes. At
this point, the train was leaked checked at the highest vacuum
achieved during the sampling run, and the first pair of sorbent
cartridges were replaced with a new pair of cartridges. This
procedure was repeated until a total of six pairs of sorbent
cartridges were used. Three of the six pairs involved sampling
at a rate of approzimately 1 liter per minute (1 Ippm), and the
remaining three pairs involved sampling at a rate of
approximately 2 1pm. The varied sampling rates were incorporated
to allow a greater flexibility in the analysis of the sorbent
cartridges. Each sampling run had a duration of 120 minutes.
57
-------
Heoted Quortz Probe
Clots Wool Plug
Thermometers
^ Orifice Q
Exhoust
Dry Gas
Meter
Teflon Lines
m-
/
Glass
Condensers
Coolant
Water — =1
In
Coolant
Water
Out
By-Pass
Valve
Condensote Silica
Trap Gel
Figure 5.1.10-1: Volatile Organic Sampling Train (Method 0030)
5.1.10.3 Sample Train Recovery and Clean-up; At the end of
each 20-minute sampling period, each pair of sorbent cartridges
was removed from the sampling train, the end caps were replaced
on the cartridges, and the cartridges were stored in a cooler
with "Blue Ice" until analysis. A schematic of the recovery is
shown in.Figure 5.1.10-2.
58
-------
Tenox Tube
Tenox\Chorcool Tube
Remove tube
from troin
Cop off ends
of tube
Insert into
protective sheath
Remove tube
from troin
Cop off ends
of tube
Insert into
protective sheath
Label and refrigerate Label and refrigerate
Figure 5.1.10-2:
Method 0030 Recovery Procedure
Source: EPA 600/8-84-007
5.1.10.4 Field Blanks; A single pair of sorbent cartridges
to the sampling location and the ends removed for a period of
time while the two pairs of sorbent cartridges on the VOST system
were exchanged. At the end of this period, the end caps were
replaced, and the cartridges were stored and analyzed with the
samples cartridges.
5.1.10.5 Volatile Organics Analyses - Method 0030; The
VOST sorbent cartridges were analyzed for volatile compounds
listed in Method 8240, Table 2. The analyses were performed
using thermal desorption and gas chromatography with mass
spectroscopy (GC/MS) in accordance with Method 0030 procedures.
A schematic of the analytical procedure is contained in Figure
5.1.10-3. Only two of the six pairs of cartridges were analyzed
for each sampling run for reporting purposes.
59
-------
Container 1
Tenox Tube
Container 2
Tenax/Charcoal Tube
Spike
Spike
Thermal desorption Thermal desorption
with nitrogen with nitrogen
Analysis by GC/MS
Analysis by GC/MS
Figure 5.1.10-3: Method 0030 Analysis Procedure
Source: EPA 600/8-84-007
5.1.11 Semivolatile Organics Sampling; Sampling for semi-
volatile organics was conducted in accordance with Method 0010 of
SW-846.
5.1.11.1 Sampling Train Description; Figure 5.1.11-1
illustrates the Method 0010 sampling train. The train employed a
single piece quartz nozzle and probe for sample withdrawal. The
nozzle opening was appropriately sized to maintain isokinetic
sampling. Particulate matter was removed from the gas stream by
means of a heated glass filter supported on a Teflon frit. The
filter temperature was maintained at 248 + 25°F. After
particulate removal, the gases passed into a water-cooled glass
condenser and entered an XAD resin sorbent trap. The sorbent
trap was packed with pre-cleaned, quality control checked
amberlite XAD-2 resin. Coolant water maintained at wet-ice
temperature was continuously recirculated into the assembly using
a submersible water pump. The condenser cooled the sample gases
and condensed part of the moisture. The cooled gases and
condensate flowed down through the XAD-2 resin which retained the
organics. After passing through the sorbent trap, the sample
gases passed through a chilled impinger train to remove the
remaining moisture. The impinger train consisted of five glass
impingers immersed in an ice bath. The first impinger was left
blank to facilitate collection of the condensate which passed
through the XAD-2 resin trap. The second and third impingers
each contained 100 milliliters of distilled water. The fourth
impinger was initially empty and the fifth impinger initially
60
-------
contained approximately 200 grams of silica gel. All components
from the nozzle to the fourth impinger were made of glass. All
connections from the probe to the exit stem of the fourth
impinger were sealed with Teflon 0-rings. Sealing grease was not
used on any connections before the fifth impinger.
STACK
Heoted Filter
Condenser
XAD Sorbent Trop
Pitot
Tubes Inclined
(Type-S) Monometer
/ n\ \
/ 100 ml > Silico
Condensote H20 Empty Cel
Trop
By-Poss
Volve
Thermometers
Orifice o p
Figure 5.1.11-1:
EPA Method 0010 Sampling Train for Semi-
volatile Organics
5.1.11.2 Sampling Train Operation: Sampling was performed
in general accordance with EPA Method 5 procedures and
specifications, including leak checking, isokinetic sampling
61
-------
rate, and stack traversing. A minimum sample volume of 106 dry
standard cubic feet was obtained for each run.
5.1.11.3 Sample Recovery and Clean-up: At the completion
of each test run, the probe was removed from the train, and the
ends of the sample train capped with hexane-rinsed aluminum foil.
The probe was immediately recovered at each sampling location,
while the remainder of the sampling train was transported to a
clean-up site for recovery. Sample recovery proceeded as
illustrated in Figure 5.1.11-2.
Immediately upon recovery, all samples including liquid
rinses, filters and sorbent traps were placed into insulated
coolers packed with ice, thus protecting the samples from light
and heat.
The samples remained inside the coolers during transport to
the analytical laboratory. While in the custody of ETS, the
temperatures inside the coolers were periodically measured to
insure that the samples did not exceed 32°F. All samples were
express mailed directly to the analytical lab for analysis.
While at the lab, the samples were kept in a refrigerated
compartment until analyzed.
5.1.11.4 Field Blanks: One field blank was collected
during the test program for the Method 0010 tests. The field
blank consisted of a complete sampling train set up on site and
recovered during the recovery of the normal stack test samples.
5.1.11.5 Semivolatile Oraanics Analyses: Analysis of the
Method 0010 sample train components was performed in accordance
with the procedures outlined in Method 0010 of SW-846. Analyses
were performed for the semivolatile compounds listed in Method
8270, Table 2. The analyses were performed with high resolution
gas chromatography/mass spectrometry (GC/MS). A schematic of the
analytical procedure is contained in Figure 5.1.11-3.
62
-------
Filter
Carefully remove
and place in
petri dish
Brush loose
participate
onto filter
Seat petri dish
Container 1
Probe &
Front-half Back-half
Condenser
Impinger 1
Impinger 2-4
Rinse three times
with acetone and
brush between rinsings
Record impinger volume
tmpinger 5
•Silica Gel
Rinse three times
with methylene chloride
Rinse thr
ee times
with t luene
Container 2A Container 3
Measure impinger volumes Empty contents
to determine moisture into sample
content container
Rinse t
with
ee times
Dluene
Sorbent
Cartridge
Cop off ends
of cartridge
Cover with hexane
rinsed aluminum foil
Container 4A Container 4B
Discord contents Container 5A and 5B
Label and refrigerate
Container 6
Figure 5.1.11-2:
Method 0010 Recovery Procedure
Source: EPA 600/8-84-007
63
-------
Container 1
Filter
Container 6
Sorbent Cartridge
Spike
Containers 2A, 3,
4A, and 4B
Train Rinses
and Condensate
Spike
Separatory funnel
extraction
Containers 5A and 5B
Silica Gel
Transfer to
glass thimble
Soxhlet extraction
16 hours with MeCI2
Extractions are combined
and analyzed by GC/MS
Weigh to
nearest 0.5 g
Figure 5.1.11-3:
Method 0010 Analysis Procedure
Source: EPA 600/8-84-007
64
-------
6.0 FACILITY PROCESS DATA
The facility process data reflects the specific operating
conditions of the facility during the testing. This section is
to contain this process data. However, this data was not
available as of the final draft of this report. It is to be
included at a later date by EPA/EIB personnel. Appendix I is to
contain all facility operating data.
65
-------
7.0 QA/QC ACTIVITIES
Specific quality control (QC) procedures were followed to
ensure the continuous production of useful and valid data
throughout the course of this test program. The QC checks and
procedures described in this section represent an integral part
of the overall sampling and analytical scheme. Strict adherence
to prescribed procedures is quite often the most applicable QC
check. A discussion of both the sampling and analytical QC
checks that were utilized during this program are presented
below.
7.1 Equipment QC Procedures
7.1.1 Equipment Inspection and Maintenance: Each item of
field test equipment was assigned a unique, permanent
identification number. An effective preventive maintenance
program was necessary to ensure data quality. Each item of
equipment returning from the field was inspected before it was
returned to storage. During the course of these inspections,
items were cleaned, repaired, reconditioned, and recalibrated
where necessary.
Each item of equipment transported to the field was
inspected again before being packed to detect equipment problems
which may originate during periods of storage. This minimizes
lost time on the job site due to equipment failure.
Equipment failure in the field is unavoidable despite the
most rigorous inspection and maintenance procedures. For this
reason, ETS routinely transported to the job site spare equipment
for all critical sampling train components.
7.1.2 Equipment Calibration; New items for which
calibration was required were calibrated before initial field
use. Equipment whose calibration status may change with use or
time was inspected in the field before testing began and again
upon return from each field use. When an item of equipment was
found to be out of calibration, it was repaired and recalibrated
or retired from service. All equipment was periodically
recalibrated in full, regardless of the outcome of these regular
inspections.
Calibrations are conducted in a manner, and at a frequency,
which meets or exceeds U.S. EPA specifications. ETS followed the
calibration procedures outlined in the EPA Methods, and those
recommended within the Quality Assurance Handbook for Air
Pollution Measurement Systems: Volume III (EPA-600/4-77-027b,
August, 1977). When these methods were inapplicable, ETS used
methods such as those prescribed by the American Society for
Testing and Materials (ASTM).
66
-------
Data obtained during calibrations were recorded on
standardized forms, which were checked for completeness and
accuracy by the quality assurance director or the quality
assurance manager. Data reduction and subsequent calculations
were performed using ETS's own computer facilities. Calculations
were checked at least twice for accuracy.
Emissions sampling equipment requiring calibration included pitot
tubes, pressure gauges, thermometers, dry gas meters, and
barometers. The following sections elaborate on the calibration
procedures followed by ETS for these items of equipment.
7.1.2.1 Pitot Tubes; All Type-S pitot tubes used by ETS,
whether separate or attached to a sampling probe, are constructed
in-house. Each new pitot was calibrated in accordance with the
geometric standards contained in EPA Method 2. A Type S pitot
tube, constructed and positioned according to these standards,
had a coefficient of 0.84 ± 0.02. This coefficient should not
change as long as the pitot tube was not damaged. The actual
coefficient of each pitot tube was determined using a wind tunnel
calibration against a standard NIST traceable pitot tube. These
calibrations were performed in accordance with EPA Method 2
procedures.
Each pitot tube was inspected visually upon return from the
field. If a cursory inspection indicated damage or raised doubt
that the pitot remained true to its original calibration, the
pitot tube was refurbished as needed and recalibrated.
7.1.2.2 Impinger Thermometer; Prior to the start of
testing, the thermometer used to monitor the temperature of the
gas leaving the last impinger was compared with a mercury-in-
glass thermometer which meets ASTM E-l No. 63F specifications.
The impinger thermometer was adjusted when necessary until it
agreed within 2°F of the reference thermometer. If the
thermometer was not adjustable, it was labeled with a correction
factor.
7.1.2.3 Dry Gas Meter Thermometer; The thermometer used to
measure the temperature of the metered gas sample was checked
prior to each field trip against an ASTM mercury-in-glass
thermometer. The dry gas meter thermometer was acceptable if the
values agree within ± 5.4°F. Thermometers not meeting this
requirement were adjusted or labeled with a correction factor.
7.1.2.4 Flue Gas Temperature Sensor; All thermocouples
employed for the measurement of flue gas temperatures were
calibrated upon receipt. Initial calibrations were performed at
three points (ice bath, boiling water, and furnace). An ASTM
mercury-in-glass thermometer was used as a reference. The
thermocouple was acceptable if the agreement is within 1.5
percent (absolute) at each of the three calibration points.
67
-------
On-site, prior to the start of testing, the reading from the
flue gas thermocouple-potentiometer combination was compared with
an ASTM mercury-in-glass reference thermometer. If the two agree
within ± 1.5 percent (absolute), the thermocouple and
potentiometer were considered to be in proper working order for
the test series. After each field use, the thermocouple-
potentiometer system was compared with an ASTM mercury-in-glass
reference thermometer at a temperature within ± 10 percent of the
average absolute flue gas temperature data. If the absolute
temperatures agree within +1.5 percent, the temperature data
were considered valid.
7.1.2.5 Dry Gas Meter and Orifice; Two procedures were
used to calibrate the dry gas meter and orifice simultaneously.
The full calibration was a complete laboratory procedure used to
obtain the calibration factor of the dry gas meter. Full
calibrations are performed over a wide range of orifice settings.
A simpler procedure, the post test calibration, was designed to
check whether the calibration factor had changed. Post test
calibrations were performed after each field test series at an
intermediate orifice setting (based on the test data) and at the
maximum vacuum reached during the test.
Each metering system received a full calibration at the time
of purchase and a post test calibration after each field use. If
the calibration factor Y deviated by less than five percent from
the initial value, the test data were acceptable. If Y deviated
by more than 5 percent, the meter was recalibrated and the meter
coefficient (initial or recalibrated) that yielded the lowest
sample volume for the test runs was used. EPA Method 5 requires
another full calibration anytime the post test calibration check
indicates that Y had changed by more than 5 percent. Standard
practice at ETS is to recalibrate the dry gas meter anytime Y was
found to be outside the range of 0.98 to
1.02.
An orifice calibration factor was calculated for each flow
setting during a full calibration. If the range of values did
not vary by more than 0.15 in. H20 over the range of 0.4 to 4.0
in. H20, the arithmetic average of the values obtained during the
calibration was used.
7.2 Sampling QC Procedures
7.2.1 Pre-Test PC Checks and Procedures; The following
pretest QC checks were conducted:
All sampling equipment was thoroughly checked to ensure
clean and operable components.
- Equipment was inspected for possible damage from
shipment.
68
-------
The oil manometer used to measure pressure across the
Type S pitot tube was leveled and zeroed.
The number and location of the sampling traverse points
were checked before taking measurements.
The temperature measurement system was visually checked
for damage and operability by measuring the ambient
temperature prior to each traverse.
All cleaned glassware and sample train components were
kept sealed until train assembly.
The sampling trains were assembled in an environment
free from uncontrolled dust.
Each sampling train was visually inspected for proper
assembly.
Pretest calculations determined the proper sampling
nozzle size.
7.2.2 QC Checks and Procedures During Testing: The
following checks and procedures will be conducted during testing:
Readings of temperature and differential pressure were
taken at each traverse point.
All sampling data and calculations were recorded on
Preformatted data sheets.
All calibration data forms were reviewed for
completeness and accuracy.
Any unusual occurrences were noted during each run on
the appropriate data form.
The project supervisor reviewed sampling data sheets
daily during testing.
The roll and pitch axis of the Type S pitot tube and
the sampling nozzle were properly maintained.
Leak check the train before and after any filter
change.
Conduct additional leak checks if the sampling time
exceeded 4 hours.
Maintained the probe, filter and impingers at the
proper temperature.
69
-------
Maintained ice in the ice bath at all times.
Make proper readings of the dry gas meter, delta P and
delta H, temperature, and pump vacuum during sampling
at each traverse point.
Maintained isokinetic sampling within the requirements
of each method.
7.2.3 QC Checks and Procedures After Testing:
Visually inspect the sampling nozzle.
Visually inspect the Type S pitot tube.
Leak check each leg of the Type S pitot tube.
Leak check the entire sampling train.
7.3 Analytical QA Procedures
All analytical QA procedures followed those given in each
test method. Each test method along with the prescribed
reference sections regarding auditing procedures are as follows:
Test Method
Method 29
Method 26
Method 18
Reference
Method 29, Section 7
proposed to be added to
Appendix A of 40 CFR 60
Method 26, Section 6.2
of 40 CFR 60
Method 18, Section 7.4.4.3
of 40 CFR 60
70
-------
Method 0030
Method 0030, Section 7.0
of SW - 846
Method 0010
Method 0010, Section 11.0
of SW - 846
EPA audit samples were submitted and analyzed for trace metals
following analytical procedures outlined in proposed EPA Method
29. A summary of the analytical results from the analyses of the
audit samples is contained in Table 6.4-1.
TABLE 7.3-1:
Summary of Results for Trace Metals Analyses on
EPA Audit Samples,
CONPQNKNT
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Lead
Manganese
Mercury
Nickel
Phosphorus
Selenium
Silver
Thallium
Zinc
Sb
As
Be
Cd
Cr
Cu
Pb
Mn
Hg
Ni
P
Se
Ag
Tl
Zn
SAMPLE H399 - High Level
Total ^/filter
7.28
12.8
34.4
40.8
40.0
43.1
184
37.6
< 2
180
64.8
3.45
7.63
2.85
110
SAMPLE L399 - Low Level
Total ///filter
1.04
9.00
2.42
5.43
7.24
7.24
21.8
5.97
< 2
14.5
48.7
1.15
4.57
2.32
54.6
7.4 Analytical QC Procedures
All analyses for this program were performed using accepted
laboratory procedures in accordance with the specified analytical
protocols. Adherence to prescribed QC procedures ensured data of
consistent and measurable quality. Analytical QC focused upon
the use of control standards to provide a measure of analytical
precision and accuracy. Also, specific acceptance criteria were
defined for various analytical operations including calibrations,
control standard analyses, drift checks, blanks, etc. The
following general QC procedures were incorporated into the
analytical effort:
The on-site project supervisor reviewed all analytical
data and QC data on a daily basis for completeness and
acceptability.
Analytical QC data was tabulated using the appropriate
charts and forms on a daily basis.
71
-------
Copies of the QC data tabulation were submitted to the
quality assurance manager following the completion of
the test program.
All hard copy raw data (i.e., strip charts, computer
printouts, etc.) were maintained in organized files.
7.5 QA/QC Checks of Data Reduction
Calculations that were to be used in the field were checked
by the QA officer prior to testing with predetermined data. The
QA officer performed random checks in the field to insure data
was being properly recorded. Upon completion of the testing,
data was then transferred from the data sheets to the computer.
This process was also reviewed and checked by the QA officer.
When multiple tests were performed in one location, data from
each test were compared.
7.6 Sample Identification and Custody
Each test run was assigned a unique run identification
(i.d.) which consisted of a 3 digit code for the location, the
test method and the specific test run. Labels were pre-printed
with the test method, the container number, a unique
client/sample i.d., a space to write in the run number described
above and the contents of the sample container. As each sample
was recovered, its sample label was attached and the sample
number and contents were recorded in the chain of custody section
of the run sheet. The run identification, the sample number and
contents were then recorded in a bound field sample log that was
maintained by the sample recovery person. A three way check was
then made by the recovery person to insure that the sample label
information, the log book information and the run sheet chain of
custody all corresponded correctly.
When the samples were returned for analysis, the team leader
again checked to see that the sample label information, the run
sheet chain of custody and the field log book information all
corresponded correctly. Any discrepancies were brought to the
attention of the project manager. If any condition existed that
may influence the integrity of the sample, it was noted and
brought to the attention of the project manager (i.e. broken
seals, leaking samples, improper storage temperature). All of
the chain of custody information was entered into a database. A
print out of the computerized field log was made and checked
against the chain of custody on the test run sheet. A copy of
the computerized chain of custody accompanied the samples to the
location where they were to be analyzed. Each sample label was
checked again against the computerized field log as it was sent
from sample management.
72
-------
-------
APPENDIX A
TEST LOG
-------
GENERAL SHALE BRICK PLANT
JOHNSON CITY, TENNESSEE
TEST LOG
LOCATION
Baghouse Outlet
Baghouse Outlet
Baghouse Outlet
Kiln A Dryer Stack
Kiln A Dryer Stack
Kiln A Dryer Stack
Kiln A Dryer Stack
Kiln A Dryer Stack
Kiln A Dryer Stack
Kiln A Dryer Stack
Kiln A Dryer Stack
Kiln A Dryer Stack
Kiln Combustion Exhaust
Kiln Combustion Exhaust
Kiln Combustion Exhaust
Kiln Combustion Exhaust
Kiln Combustion Exhaust
Kiln Combustion Exhaust
Kiln Combustion Exhaust
Kiln Combustion Exhaust
Kiln Combustion Exhaust
Kiln Combustion Exhaust
Kiln Combustion Exhaust
Kiln Combustion Exhaust
Kiln Combustion Exhaust
Kiln Combustion Exhaust
Kiln Combustion Exhaust
Kiln Combustion Exhaust
Kiln Combustion Exhaust
Kiln Combustion Exhaust
Kiln Combustion Exhaust
Kiln Combustion Exhaust
-------
B
-------
B.O
CRUSHING, GRINDING, AND SCREENING OPERATION APPENDICES
-------
APPENDIX B.I
BAGHOUSE OUTLET
DATA AND RESULTS FOR EPA METHOD 201A TESTING
-------
RUN NUMBER
BO-M201A-R1
DATE
START TIME
END TIME
STACK DIAM.
NOZZLE I.D.
METER BOX GAMMA
METER BOX dH@
BAROMETRIC
Cp
TEST DURATION
SAMPLING RESULTS
Metered Volume
Metered Volume
Volume @ Std.Cond.
Volume @ Std.Cond.
% Water
% Isokinetics
VOLUMETRIC RESULTS - USENG
Velocity
Actual Flow
Std. Flow
Dry Std. Flow
STATIC
fin. WO
-10.00
-10.00
07/27/93
09:04
10:17
34
0.164
1.00462
1.85206
30.09
0.84
66.0
METHOD 4 DATA
inches
inches
in.Hg
minutes
IMP.1
IMP.2
IMP.3
IMP.4
IMP.5
IMP.6
IMP.7
TOTAL
S.G.
INIT.
(ml)
100.0
100.0
0.0
200.0
200.0
FINAL
(ml)
104.0
100.0
0.0
204.0
207.2
NET
(ml)
4.0
0.0
0.0
0.0
0.0
0.0
0.0
4.0
7.2
METHOD 3 DATA
29.664
0.840
29.363
0.831
1.76
103.9
NG
51.28
19401
18747
18418
dcf
dcm
dscf
dscm
%
%
ft/sec
acfm
scfm
dscfm
%O2
%CO2
%CO
%N2
O2+CO2
VOLUMETRIC
Velocity
Actual Flow
Std. Flow
Dry Std. Flow
20.8
0.1
0.0
79.1
10.0
RESULTS
Md
Ms
Ps
Fo
%EA
-SI
15.63
32962
31852
31292
28.85
28.66
29.35
1.000
25243
m/sec
am3/hr
sm3/hr
dsm3/hr
METER METER TEMPERATURE
DP
(in.WC)
0.75
0.65
0.96
0.91
0.98
1.00
0.84
0.85
0.71
0.63
0.60
0.59
0.55
0.76
0.62
0.72
0.80
1.00
0.89
0.95
0.96
0.97
0.93
0.75
DWELL
TIME
2.62
2.44
2.96
2.89
2.99
3.03
2.77
2.79
2.55
2.40
2.34
2.32
2.24
2.64
2.38
2.57
2.71
3.03
2.85
2.95
2.96
2.98
2.92
2.62
DH VOLUME
(in.WC)
0.62
0.62
0.62
0.62
0.62
0.62
0.62
0.62
0.62
0.62
0.62
0.62
0.62
0.62
0.62
0.62
0.62
0.62
0.62
0.62
0.62
0.62
0.62
0.62
(dcf)
469.104
498.768
INLET
(DeaF)
67
72
72
74
75
77
77
79
80
81
81
82
87
83
83
84
84
85
85
85
85
86
87
87
OUTLET
(Dec
IE)
67
70
71
72
72
73
74
75
76
76
77
78
86
80
81
82
82
83
83
83
83
84
85
86
76 > -10.00
0.81
2.71
0.62
498.768
29.664
80
-------
EPA METHOD 201A ANALYSES
RUN I.D.
SUMMARY
COMPONENT
PM10:
Probe Wash <= 10 microns
Filter
TOTAL PM 10
PM(>10 Microns):
Probe Wash > 10 microns
TOTAL PM
ANALYTICAL DATA
METHOD 201A COMPONENTS:
Filter
Probe Wash Residue <= PM10
Acetone Blank Residue
Applicable Acetone Blank
Max. Allowable Blank
Probe Wash Residue > PM10
Acetone Blank Residue
Applicable Acetone Blank
Max. Allowable Blank
PARTICULATE EMISSIONS:
Actual Grain Loading (gr/dscf)
BO-M201A-R1
NET
(grams)
0.00260
0.00410
0.00670
0.00270
0.0094
TARE
(grams)
0.54180
66.35430
67.18690
64.90430
67.28290
PM10
0.00352
CORRECTED
FOR BLANK
(grams)
0.00260
0.00410
0.00670
0.00174
0.00844
FINAL
(grams)
0.54590
66.35690
67.18690
64.90700
67.28440
PM>10u
0.00092
NET
(grams)
0.00410
0.00260
0.00000
0.00000
0.00097
0.00270
0.00150
0.00146
0.00096
TOTAL PM
0.00444
VOLUME
(ml)
NA
124.0
125.0
124.0
NA
122.0
125.0
122
NA
Mass Rate (Ib/hr)
0.556
0.145
0.700
-------
D50 Calculations
RUN I.D. BO-M201A-R1
Stack Gas Viscosity (micropoise) 181.0818
Cyclone Flow Rate (dscf/min) 0.444895
Cyclone Flow Rate (acfm) 0.468831
D50 9.710571
dPmin and dPmax Calculations
Stack Gas Viscosity (micropoise) 181.7729
Cyclone Flow Rate (acfm) 0.451525
Dn vn vmin vmax dPmin dPmax
0.136 74.60326 62.87641 91.91469 1.203301 2.571394
0.15 61.32719 52.54302 76.21100 0.840289 1.767804
0.164 51.30361 44.79688 64.40361 0.610793 1.262464
0.18 42.58833 38.11672 54.18842 0.442211 0.893741
0.197 35.55520 32.77620 45.99485 0.326976 0.643898
0.215 29.85099 28.48740 39.39548 0.247004 0.472380
0.233 25.41697 25.18559 34.30391 0.193065 0.358167
0.264 19.79829 21.04721 27.91599 0.134830 0.237195
0.3 15.33180 17.79213 22.90333 0.096351 0.159660
0.342 11.79732 15.22575 18.98377 0.070560 0.109689
0.39 9.07207 13.23111 15.98466 0.053283 0.077769
-------
RUN NUMBER
BO-M201A-R2
DATE
START TIME
END TIME
STACK DIAM.
NOZZLE I.D.
METER BOX GAMMA
METER BOX dH@
BAROMETRIC
Cp
TEST DURATION
SAMPLING RESULTS
Metered Volume 37
Metered Volume 1
Volume @ Std.Cond. 3£
Volume @ Std.Cond. 1
% Water
% Isokinetics 1
VOLUMETRIC RESULTS • USENG
Velocity 4
Actual Flow H
Std. Flow H
Dry Std. Flow 1
METHOD 4 DATA
IMP.1
IMP.2
IMP.3
IMP.4
IMP.5
IMP.6
IMP.7
TOTAL
S.G.
METHOD 3 DATA
%O2 20.8
%CO2 0.1
%CO 0.0
%N2 79.1
O2+C02 20.9
NIT.
tea
100.0
100.0
0.0
200.0
200.0
FINAL
(ml)
118.0
100.0
0.0
218.0
204.9
NET
(ml)
18.0
0.0
0.0
0.0
0.0
0.0
0.0
18.0
4.8
Md
Ms
Ps
Fo
%EA
VOLUMETRIC RESULTS - SI
Velocity 15.22
Actual Flow 32090
Std. Flow 30727
Dry Std. Flow 29834
28.85
28.53
29.35
1.000
25243
m/sec
am3/hr
sm3/hr
dsm3/hr
POINT
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
AVG.
STACK
TEMP STATIC
(DeaF) fin .WO
75 > -10.00
74 > -10.00
80
81
81
82
83
83
83
83
83
83
82
81
80
82
84
84
83
83
83
84
83
84
82 > -10.00
METER METER TEMPERATURE
DP
fm.WC)
0.87
0.88
0.82
0.84
0.88
0.91
0.89
0.68
0.69
0.64
0.55
0.50
0.54
0.51
0.49
0.66
0.82
0.84
0.82
0.78
0.85
0.87
0.91
0.90
0.76
DWELL
TIME
3.63
2.96
3.52
3.56
3.64
3.71
3.66
3.20
3.23
3.11
2.88
2.75
2.85
2.77
2.72
3.16
3.52
3.56
3.52
3.43
3.58
3.63
3.71
3.69
3.33
DH VOLUME
fin.WC) (dcfl
0.63 499.080
0.63 536.503
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
536.503
0.63 37.423
INLET
(DeaF)
88
87
87
88
89
91
94
96
99
98
99
99
101
102
99
102
101
103
102
103
103
104
104
104
OUTLET
(DeaF)
90
90
90
90
91
91
93
93
95
93
94
95
98
97
95
98
98
99
98
98
99
100
100
101
96
-------
EPA METHOD 201A ANALYSES
RUN I.D. BO-M201A-R2
SUMMARY
COMPONENT
PM10:
Probe Wash <= 10 microns
Filter
TOTAL PM10
PM(>10 Microns):
NET
(grams)
0.00190
0.00127
0.00317
CORRECTED
FOR BLANK
(grams)
0.00190
0.00127
0.00317
TOTAL PM
ANALYTICAL DATA
METHOD 201A COMPONENTS:
Filter
Probe Wash Residue <= PM10
Acetone Blank Residue
Applicable Acetone Blank
Max. Allowable Blank
Probe Wash Residue > PM10
Acetone Blank Residue
Applicable Acetone Blank
Max. Allowable Blank
PARTICULATE EMISSIONS:
Actual Grain Loading (gr/dscf)
0.00477
TARE
(grams)
0.53753
67.19910
67.18690
66.23130
67.28290
PM10
0.00136
0.00381
FINAL
(grams)
0.53880
67.20100
. 67.18690
66.23290
67.28440
PM>10 u
0.00028
NET
(grams)
0.00127
0.00190
0.00000
0.00000
0.00086
0.00160
0.00150
0.00146
0.00096
TOTAL PM
0.00164
VOLUME
(ml)
NA
110.0
125.0
110.0
NA
122.0
125.0
122
NA
Mass Rate (Ib/hr)
0.205
0.042
0.247
-------
D50 Calculations
RUNI.D. BO-M201A-R2
Stack Gas Viscosity (micropoise) 181.6198
Cyclone Flow Rate (dscf/min) 0.443433
Cyclone Flow Rate (acfm) 0.477898
D50 9.629951
dPmin and dPmax Calculations
Stack Gas Viscosity (micropoise) 182.4166
Cyclone Flow Rate (acfm) 0.455138
Dn vn vmin vmax dPmin dPmax
0.136 75.20010 63.36569 92.63959 1.203866 2.573137
0.15 61.81782 52.94856 76.80934 0.840578 1.768878
0.164 51.71405 45.13949 64.90662 0.610918 1.263129
0.18 42.92904 38.40492 54.60880 0.442225 0.894118
0.197 35.83965 33.02083 46.34879 0.326923 0.644090
0.215 30.08980 28.69698 39.69581 0.246912 0.472453
0.233 25.62031 25.36821 34.56279 0.192952 0.358168
0.264 19.95668 21.19609 28.12280 0.134704 0.237130
0.3 15.45446 17.91466 23.06928 0.096225 0.159565
0.342 11.89170 15.32779 19.11790 0.070442 0.109585
0.39 9.14465 13.31754 16.09464 0.053176 0.077666
-------
RUN NUMBER
BO-M201A-R3
DATE
START TIME
END TIME
STACK DIAM.
NOZZLE I.D.
METER BOX GAMMA
METER BOX dH@
BAROMETRIC
Cp
TEST DURATION
SAMPLING RESULTS
Metered Volume
Metered Volume
Volume @ Std.Cond.
Volume @ Std.Cond.
% Water
% Isokinetics
VOLUMETRIC RESULTS - USENG
Velocity
Actual Flow
Std. Flow
Dry Std. Flow
POINT
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
AVG.
STACK
TEMP
fDeaF)
83
85
87
87
86
86
86
86
87
87
90
88
87
87
88
88
86
88
86
87
87
86
88
87
STATIC
fin. WO
-10.00
-10.00
07/27/93
13:05
14:36
34 inches
0.180 inches
1.00462
1.85206
30.09 in.Hg
0.84
90 minutes
METHOD 4 DATA
IMP.1
IMP.2
IMP.3
IMP.4
IMP.5
IMP.6
IMP.7
TOTAL
S.G.
INIT.
Ml
100.0
100.0
0.0
200.0
200.0
FINAL NET
(ml) (ml)
121.0 21.0
100.0 0.0
0.0 0.0
0.0
0.0
0.0
0.0
221.0 21.0
210.0 10.0
METHOD 3 DATA
42.414 dcf
1.201 dcm
40.152 dscf
1.137 dscm
3.51 %
99.3 %
%O2
%CO2
%CO
%N2
O2+CO2
20.8
0.1
0.0
79.1
20.9
NG VOLUMETRIC RESULTS
46.37 ft/sec
17540 acfm
16617 scfm
16034 dscfm
Velocity
Actual Flow
Std. Flow
Dry Std. Flow
Md 28.85
Ms 28.47
Ps 29.35
Fo 1.000
%EA 25243
•SI
14.13 m/sec
29801 am3/hr
28233 sm3/hr
27243 dsm3/hr
METER METER TEMPERATURE
DP DWELL
fin. WO TIME
0.73 4.08
0.74 4.10
0.62 3.75
0.73 4.08
0.76 . 4.15
0.74 4.10
0.65 3.84
0.57 3.60
0.50 3.37
0.46 3.23
0.48 3.30
0.46 3.23
0.50 3.37
0.53 3.47
0.55 3.53
0.55 3.53
0.67 3.90
0.77 4.18
0.76 4.15
0.65 3.84
0.75 4.13
0.76 4.15
0.76 4.15
0.72 4.04
DH
fm.WO
0.66
0.66
0.66
0.66
0.66
0.66
0.66
0.66
0.66
0.66
0.66
0.66
0.66
0.66
0.66
0.66
0.66
0.66
0.66
0.66
0.66
0.66
0.66
0.66
VOLUME
(deft
536.880
579.294
INLET
(DeaF)
104
103
101
103
103
106
105
107
106
108
106
108
104
105
105
108
106
106
105
106
107
108
108
110
OUTLET
(DeaF)
101
102
101
102
101
103
102
103
102
104
102
104
101
103
103
104
103
102
103
102
102
104
105
104
87 > -10.00
0.64
3.80
0.66
579.294
42.414
104
-------
EPA METHOD 201A ANALYSES
RUN I.D. BO-M201A-R3
SUMMARY
COMPONENT
PM10:
Probe Wash <= 10 microns
Filter
TOTALPM10
PM(>10 Microns):
NET
(grams)
0.00200
0.00119
0.00319
CORRECTED
FOR BLANK
(grams)
0.00200
0.00119
0.00319
Probe Wash > 1 0 microns
TOTAL PM
0.00390
0.00709
0.00320
0.00639
ANALYTICAL DATA
METHOD 201 A COMPONENTS:
Filter
Probe Wash Residue <= PM10
Acetone Blank Residue
Applicable Acetone Blank
Max. Allowable Blank
Probe Wash Residue > PM10
Acetone Blank Residue
Applicable Acetone Blank
Max. Allowable Blank
PARTICULATE EMISSIONS:
Actual Grain Loading (gr/dscf)
TARE
(grams)
0.53611
66.36540
67.18690
65.57020
67.28290
PM10
0.00123
FINAL
(grams)
0.53730
66.36740
67.18690
65.57410
67.28440
PM>10u
0.00123
NET
(grams)
0.00119
0.00200
0.00000
0.00000
0.00094
0.00390
0.00150
0.00107
0.00070
TOTAL PM
0.00246
VOLUME
(ml)
NA
120.0
120.0
120.0
NA
89.0
125.0
89
NA
Mass Rate (Ib/hr)
0.168
0.169
0.338
-------
D50 Calculations
RUNI.D. BO-M201A-R3
Stack Gas Viscosity (micropoise) 182.3753
Cyclone Flow Rate (dscf/min) 0.446134
Cyclone Flow Rate (acfm) 0.488233
D50 9.535618
dPmin and dPmax Calculations
Stack Gas Viscosity (micropoise) 183.2633
Cyclone Flow Rate (acfm) 0.45879
Dn vn vmin vmax dPmin dPmax
0.136 75.80348 63.86365 93.37496 1.209003 2.584524
0.15 62.31383 53.36212 77.41699 0.844085 1.776611
0.164 52.12899 45.48966 65.41811 0.613402 1.268574
0.18 43.27349 38.70033 55.03696 0.443965 0.897901
0.197 36.12722 33.27238 46.71001 0.328161 0.646755
0.215 30.33123 28.91329 40.00301 0.247808 0.474357
0.233 25.82588 25.55737 34.82826 0.193621 0.359570
0.264 20.11681 21.35130 28.33586 0.135135 0.238008
0.3 15.57846 18.04331 23.24122 0.096506 0.160117
0.342 11.98712 15.43571 19.25777 0.070627 0.109934
0.39 9.21802 13.40959 16.21014 0.053303 0.077892
-------
APPENDIX B.2
DATA AND RESULTS OF TOTAL PARTICULATE
SAMPLING FROM THE BAGHOUSE CATCH
-------
92-655 WA14; Johnson City Brick
Baghouse Dust Collection Summary
Run
Number
BO-M201A-R1
BO-M201A-R1
BO-M201A-R1
BO-M201A-R1
BO-M201A-R1
Average
BO-M201A-R2
BO-M201A-R2
BO-M201A-R2
BO-M201A-R2
BO-M201A-R2
Average
BO-M201A-R3
BO-M201A-R3
BO-M201A-R3
BO-M201A-R3
BO-M201A-R3
Average
Average not
Bag
Number
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
includin<
Date
07/27/93
07/27/93
07/27/93
07/27/93
07/27/93
07/27/93
07/27/93
07/27/93
07/27/93
07/27/93
07/27/93
07/27/93
07/27/93
07/27/93
07/27/93
j Bag Number
Start
Time
09:05:00
09:07:00
09:10:00
09:45:00
09:48:00
11:10:00
11:12:00
11:14:00
11:17:00
11:19:00
13:15:00
13:17:00
13:19:00
13:21:00
13:23:00
13
End
Time
09:06:00
09:08:00
09:11:00
09:45:30
09:49:00
11:10:30
11:12:30
11:14:30
11:17:30
11:19:30
13:15:30
13:17:30
13:19:30
13:21:30
13:23:30
Time
(sec)
60
60
60
30
60
30
30
30
30
30
30
30
30
30
30
Dust
(lb)
20.0
26.0
21.5
16.0
35.5
20.5
20.5
16.5
17.5
22.5
16.5
34.0
61.0
19.0
17.0
Mass Rate
(Ib/min)
20.0
26.0
21.5
32.0
35.5
27.0
41.0
41.0
33.0
35.0
45.0
39.0
33.0
68.0
122.0
38.0
34.0
59.0
43.3
-------
APPENDIX B.3
PROCESS SAMPLING
DATA AND RESULTS FOR MOISTURE AND SIEVE ANALYSIS
-------
DUST MOISTURE CONTENT
ETS CONTRACT:
SITE :
SAMPLE TYPE :
92-655 WA 14
JOHNSON CITY BRICK
SHALE AND CLAY FROM GRINDING ROOM EXIT
ETS ID CLIENT ID
6158D RUN 1
6159D
6160D
RUN 2
RUN 3
CRUCIBLE
INT.WT.
14.3588
14.1548
14.5292
13.6661
14.6246
15.3362
CRUCIBLE -fDUST
INT.WT.
22.0001
23.6043
23.9142
20.9466
22.5001
23.2467
CRUCIBLE+DUST
WT. AFTER DRYING
21.3828
22.8359
AVG.
23.1462
20.3592
AVG.
21.6511
22.3888
%
MOISTURE
8.08
8.13
8.11
8.18
8.07
8.13
10.78
10.85
AVG. 10.81
-------
SIEVE ANALYSIS RESULTS FOR EPA BRICK PLANT
ETS CONTRACT :
SAMPLE TYPE :
SAMPLE ID :
ETS ID :
92-655 WA 14
SHALE AND CLAY FROM GRINDING ROOM EXIT
RUN 1
6158D
AS-IS SAMPLE WT.(gms)
18 MESH SAMPLE
20 MESH SAMPLE
25 MESH SAMPLE
30 MESH SAMPLE
35 MESH SAMPLE
60 MESH SAMPLE
80 MESH SAMPLE
100 MESH SAMPLE
200 MESH SAMPLE
137.3048
SAMPLE
WT. (cms)
: 57.0190
: 6.8928
: 6.5617
: 5.2896
: 4.3285
: 15.5314
: 5.3679
: 2.2323
: 11.7782
PERCENT
LESS THAN
58.4727
53.4526
48.6737
44.8212
41.6688
30.3571
26.4477
24.8219
16.2437
SIZE
(microns)
1000
850
710
600
500
250
180
150
75
-------
SIEVE ANALYSIS RESULTS FOR EPA BRICK PLANT
ETS CONTRACT :
SAMPLE TYPE :
SAMPLE ID :
ETS ID :
92-655 WA 14
SHALE AND CLAY FROM GRINDING ROOM EXIT
RUN 2
6159D
AS-IS SAMPLE WT.(gms)
18 MESH SAMPLE
20 MESH SAMPLE
25 MESH SAMPLE
30 MESH SAMPLE
35 MESH SAMPLE
60 MESH SAMPLE
80 MESH SAMPLE
100 MESH SAMPLE
200 MESH SAMPLE
136.9568
SAMPLE
WT. ( cms]
: 52.2936
: 6.8745
: 6.6489
: 5.5286
: 5.2587
: 16.4524
: 5.8695
: 2.1479
: 10.6590
PERCENT
LESS THAN
61.8174
56.7980
51.9432
47.9065
44.0668
32.0540
27.7683
26.2000
18.4173
SIZE
(microns)
1000
850
710
600
500
250
180
150
75
-------
SIEVE ANALYSIS RESULTS FOR EPA BRICK PLANT
ETS CONTRACT :
SAMPLE TYPE :
SAMPLE ID :
ETS ID :
92-655 WA 14
SHALE AND CLAY FROM GRINDING ROOM EXIT
RUN 3
6160D
AS-IS SAMPLE WT.(gms) : 137.2600
18 MESH SAMPLE (gins) :
20 MESH SAMPLE (gms) :
25 MESH SAMPLE (gms) :
30 MESH SAMPLE (gms) :
35 MESH SAMPLE (gms) :
60 MESH SAMPLE (gms) :
80 MESH SAMPLE (gms) :
100 MESH SAMPLE (gms) :
200 MESH SAMPLE (gms) :
SAMPLE
WT . ( crms )
36.2624
6.6530
7.0444
6.5583
6.0927
22.8304
9.4026
4.6225
14.8698
PERCENT
LESS THAN
73.5812
68.7342
63.6021
58.8241
54.3853
37.7523
30.9021
27.5344
16.7011
SIZE
(microns)
1000
850
710
600
500
250
180
150
75
-------
APPENDIX B.4
DATA AND RESULTS FOR HI-VOL AMBIENT SAMPLING
-------
SUMMARY OF AMBIENT HI-VOL SAMPLING FOR TSP
GENERAL SHALE PLANT #10
RUN I.D.
DATE
START TIME
END TIME
TEST DURATION - Min.
SAMPLING DATA
Corr. Flow - scfm
GRAVIMETRIC DATA
Tare Filter Weight - gm
Final Filter Weight - gm
Net Filter Gain - gm
TSP EMISSIONS
Cone. - ug/m3
RUN1
07/27/93
07:41
10:38
177
39.9
3.5084
3.5488
0.0404
202.14
RUN 2
07/27/93
10:45
14:06
201
40.1
2.6503
2.6872
0.0369
161.77
RUN 3
07/27/93
14:12
17:08
175
41.3
2.6450
2.6722
0.0272
132.98
AVERAGE
165.6
-------
SUMMARY OF AMBIENT SAMPLING FOR PM 10
GENERAL SHALE PLANT #10
RUN I.D.
DATE
START TIME
END TIME
TEST DURATION - Min.
SAMPLING DATA
Corr. Flow - scfm
GRAVIMETRIC DATA
Tare Filter Weight - gm
Final Filter Weight - gm
Net Filter Gain - gm
TSP EMISSIONS
RUN1
07/27/93
07:28
10:25
177
39.6
3.4604
3.4920
0.0316
RUN 2
07/27/93
10:37
13:55
198
39.4
2.6593
2.6828
0.0235
RUNS
07/27/93
14:00
17:04
179
40.7
2.6377
2.6590
0.0213
AVERAGE
Cone. - ug/m3
159.31
106.44
103.31
123.0
-------
APPENIDIX B.5
BAGHOUSE OUTLET
RAW FIELD SAMPLING DATA FOR EPA METHOD 201A TESTING
-------
FACILITY.
.•lELD DATA SHEET FOR METHOD 201 A
PAGE 1
DATE
STAPTTIME
TEST LOCATION
RUN NUMBER
I I Sample j dock j j Stack
Time Time Static) Ternp.
Stack
dP
Ovell
Tirrw
Meter
IO.O
.63
V7/J
IS
9.0
,63
7V
10.'
.63
/.c)
,62
V7.TJ
77
3.S
.69
77
7V
77
3.7?
V77.
sr
,5
77
,7;
76
10
33,0
77
2.10
5
n
H*l.t
Q!
77
J.-f
62
32-0
31.0.
,5-J
9-7
66
3V.
.61
'•H
f J
U
3b,
7?
If*-5
6 /
;.a
7*-
,(>*
j.f
.9-0
60
Hi,
.O
•*
j.g
J
.63
60
j.t
5V.
.76
60
1.8
.97
61
79
•3
61
7.3
63-
79
, 75
9-7
?.$L
CHA! r-fef^TQfifl 3II8DRMATIQN
(Cuntoi net
Number
OdlTlIJIc
I.D.
/&!
Description
FiLTUL
SlUlA C^
LEAK CHECK
Vacuum
Rate .006
5"
IMPINGE? VOLUMES
Time
= 3.03
#1
£2
#3
(00
D
#5
u
Final
/on
0
METER BOX 1.0.
GAMMA
DELTA K
OPERATOR
BAR. PRESS.
FILTER I.D.
30. o<
-//?
-------
r .
ELD DATA SHEET FOR METHOD 201 A
PAGE 1
FACILITY.
DATE
START TIME
TEST LOCATION
RUN NUMBER _£.
Time Time Static
Stack
Temp.
Stack
dP
Tmw
Meter
dH
Meter Volume
cu.ft.
Meter Temp.
Inlet
Outlet
Imp.
Temp.
Meter
Vac.
A
0
16SS
75
,V7
fr
67 M
3,t
.ss
soo.t
90
3.
1
±
3-56
/3,7
7.1
n.3
3.7 /
,63
6 /
7 I3/.Q
.6J
V
.63
SiO.Z
i e
r//.?
T
JJ
/o
f
6).
JJ
-63
f
/J 36,'
.50
SU.o
-------
rlELD DATA SHEET FDR METHOD 20LA PAGE i
/I
FACILITY.
7alUccfl
C,'f\ ai'^k
•-TAPT TIMC / ? 0 5
Sample
Point Time
/ 0
3
)
^
;
j,
7
1r
T
10
1 /,
(4
'
;
?
y
j
f
7
}r
c,'
(0
if
fi
w.o
frl .f
m.-/o,o
>-/o.p
Stack
Ternp.
£3
fj"
^7
9-1
7
_so
.^/6
,vr
^6
.to
£7m -93
6tv\ .55
rrf
^6
?r
a-6
^7
^7
?6
^^
^7
60PMATION
^
Description
Gdn&n fiHrr
^ftylfi Afliilnj/it.
.5*5
.67
,77
,7^
.65
,7S
.7h
^?
.72
c>v«n
Tim*
H.vfr
*.!
3,7£
«,'o$
H.IS
LlJ
3.fr*Y
JiO
3,37
}<(J
).id
m
;.J7
3 V7
?>J
3-i?
?,90
t^,/e
V.Af
7^V
H.I 3
1-lS
Y./5
f.O«V
DAT
(0-. (?-V/^ RUN
Meter
dH
,6(>
/Of
107
106
lOf
,06
IQfr
\OH
/o?
/OS
) f}&
/(56
\06
10$
/06
to
7
10*
/09-
i
10
i*— ^S" T ^? iy
LEAK CHECK
Vacuun
Rute
15"
.60S.
[Outlet
/a/
tot
161
to*
101
/OJ
103.
102
/oj
i o V
toS
toi
10 1
/G)J
>o}
101
fOj
loj
103
to*
/02
104
/Of
IW
Imp.
Temp.
6/
sr
S7
fi~)
$6
<;£
(^
^6
•S 7
57
^r
€^
6(?
6^
6J
Meter
Vac.
J^/
7.J
JJ
J 5
7.J
3J
3-?
JJ
J.J
J-J
7J
JJ
7-?
^
V
jj
? ?
JJ
j;j
5-3
3>3
7J
J^
JJ
Ovell Time LJ no. -,
fnr Pftin* 1 = ^- ~<£
1
«i/-PT. V-77
{MibA'fJau/ofa MPINGffi YOLUMts
SiUc-A OJLSL^
Mr '• a
1 1 i
1
1
r i
#1
92
#3
#4
#5
Initial
'CO
/GO
1 0
H&OcL
u
Final
/ 2_ /
/t)0
O
- AJD.O/
METER BOX 1.0. #-<7
GAMMA l-iiO'iS^
DELTA H»»
OPERATOR
/.fj^fl^
C.f'ri'J'*
BAR. PRESS. 3C/-05
FILTER ID.
\G-12- /If
«./=•
-------
INTEGRATED BAG ANALYSIS DATA
Job Name
Contract
Method of Analysis
Lfh 6rtfk vh /y
72- b$s
0-, I(O7
Run Number
80-
<)-&.?
• 77
-------
APPENDIX B.6
RAW FIELD DATA FOR HI-VOL AMBIENT SAMPLING
-------
PH-10 AIR QUALITY SAMPLE RECORD
NETWORK:
SITE/10:
cn IT
'•* I
/ 0
SAMPLER HO:
FILTER NO:
STOP
TYPE
START Date/Ti«»» 27 2
Dickson Reading for thia Seaple:
START PLOW (cfm):
STOP PLOW (cf»):
AVQ'PLOW (effe): 3.
FlowB«t«r/Oririel« Operational Cteekt
DATS OP LAST CHECK: '
P • Core PLOW (acffe): _
DiekMO (efa)t ...
39.10
END tteifht (PM):
START Waifht (CM):
W-NET Waifht f^lt
TIMER STOP: -
TIMER START: ___^
T • RUH TDK (Min)j
Not*: PM10 NAAOJS - 24 BR Cone Standards
Primary: 150 pf/a3
Secondary: 150 u«/«3
CHAIN OP CUSTODY
NAME/DATE -
-------
K'Ji'H A
TSP / IF AIR QUALITY SAMPLE RECORD
NETWORK:
SITE/10:
SAMPLER NO: ''Pft ~
FILTBl NO: 25
TYPB
STOP Dftt«/TiM:
START DAM/TIM: 7/£7/*3
Oickton Raadinff for thla Saapla:
START FLOW (cf»): 3. V
STOP FLOW (efa):
AVO FLOW (cfa):
3 V
Flovwtar/Orifiea Operational Qxaek:
DAT! OF LAST CHM:
F • Corr FLOW (acffc):
Dickaca (cf»): —
om Waifht (»«a) t _
START Waifht (o»)<
w-Nir Waifbt (pa)s
TIMER STOP* ^.^^_.
TDODl STAKTs
T • ROITZNi (Hia)i
Nou: PN10 NAAQB • 2t Bt Coae
CHAIN OF CUSTODY
NAME/DATE
Sacoadaryt 190
-------
TSF / IP AIR QUALITY SAMPLE RECORD
\
NETWORK:
SITE/10:
' &
SAMPLER HO:
FILTER NO:
TYPI
STOP Oat«/TlM: 7/r?/O
START
-------
PH-10 AIR QUALITY SAMPLE RECORD
NETWORK: £~ T 5
SITE/ID:
SAMPLER NO: /4i~Vol TYPE
FILTER NO: ? J 22 8
STOP Data/Tiaa:
START Data/Ti»a:
Olckson Raading for this Saapla:
START PLOW (cf«): 3>3 (J«&
STOP PLOW (cf»): ^-"3
AVQ'PLOW (cfa): 3.3
FlowBatar/Orifieia' Oparational Chack:
DATE OP LAST CHECK:
P • Corr PLOW (scfa):
Diekaon (cfa):
END ttoifht
START Might (gM):
W-NET Waifht fM>lt
TIMER STOP: .'••'•
TIMER START:
0-DL.6U
T * RUN TIMB (Mln) :
I H "7
Note: PN10 NAAQS - 24 RR Cone Standards
Priaary: 150 Uf/a3
Sacondary: 150 uc/a3
CHAD! OP CUSTODY
NAME/DATS -
-------
TSP / IF AIR QUALITY SAMPLE RECORD
(2* 3,
NETWORK:
SITE/ID:
/
SAMPLER NO:
FILTER NO:
TYPE
25.:,:;.
Diekjon Raadlnf for thla S«apl«:
/O'^START FLOW (eft) ~ '" '^^
STOP PLOW (cf»):
AVO PLOW (cfl):
FloMtt«r/Orifie«
DATE OP LAST CBECIi
P • Corr PLOW (Mffc): _
Diekaon (cf*): .
ChMtk:
do w«i«he (PN)
a, fe g
START feifht (§M)I
W-NET w«i«hc dm) i
TIMER STOP: —.^__
TIMER START!
Itl?
CHAIN OP CUSTODY
NAME/DATE
QOU
CVlU
PM10
- 24
i 190 uc/a3
t 1*5 wc/«3
-------
i
TSP / I? AIR QUALITY SAMPLE RECORD
NETWORK: ^/ S
SITE/ID: <^7^
.5
/*4,
SAMPLER NO:
FILTER NO: .
r'-.j'-*.
TYPI
STOP D*tt/Tlat:/VlV*
^START Ottt/TlM: Vr?/
-------
APPENDIX B.7
BAGHOUSE OUTLET
GRAVIMETRIC LABORATORY DATA
-------
E T S , INC.
FIELD SAMPLE LOG
Contract No. 92-655WA
Job I.D.
Test Method 201A
Print Date 10/29/93 Time 16:57:42
Page 1
Sample
No.
00100
00100
00101
00102
00103
00104
00105
00106
00107
00108
00109
00110
00111
00112
00113
00114
00115
00116
00117
00118
00119
00120
00121
00122
00123
Container
No.
Fl
Fl
F2
F3
F4
F5
F6
Fl
F2
F3
F4
F5
F6
Fl
F2
F3
F4
F5
F6
Fl
F2
F3
F4
F5
F6
Other
I.D.
G92-117
G92-0117
G92-0118
G92-0119
G92-0120
Run
I.D.
BO -201-R1
BO -201-R1
BO -201-R1
BO -201-R1
BO -201-R1
BO -201-R1
BO -201-R1
BO -201-R2
BO -201-R2
BO -201-R2
BO -201-R2
BO -201-R2
BO -201-R2
BO -201-R3
BO -201-R3
BO -201-R3
BO -201-R3
BO -201-R3
BO -201-R3
BO -201-RO
BO -201-RO
BO -201-RO
BO -201-RO
BO -201-RO
BO -201-RO
Sample
Type
Gelman Filter
Gelman Filter
>PM10 Acetone Rinse
<=PM10 Acetone Rinse
Impinger Liquids
Imp. 4 Silica Gel
TEDLAR BAG
Gelman Filter
>PM10 Acetone Rinse
<=PM10 Acetone Rinse
Impinger Liquids
Imp. 4 Silica Gel
TEDLAR BAG
Gelman Filter
>PM10 Acetone Rinse
<=PM10 Acetone Rinse
Impinger Liquids
Imp. 4 Silica Gel
TEDLAR BAG
Gelman Filter
>PM10 Acetone Rinse
<=PM10 Acetone Rinse
Impinger Liquids
Imp. 4 Silica Gel
TEDLAR BAG
Volume, ml
no Rinses
125.00000
125.00000
Volume, ml
w/ Rinses
125.00000
125.00000
Analyst
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
pjb
PJb
PJb
PJb
PJb
PJb
pjb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
Date
08/02/93
08/02/93
08/02/93
OB/02/93
08/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
08/02/93
08/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
Comments
-------
ETS, Inc.
GRAVIMETRIC LABORATORY DATA
Tare Beaker Weights
Report Prepared on: 08/03/93
Page
Beaker
Number
07/07/93-001
07/07/93-002
07/07/93-003
07/07/93-004
07/07/93-005
07/07/93-006
07/07/93-007
07/07/93-008
07/07/93-009
07/07/93-010
07/07/93-011
07/07/93-012
Date Time
07/19/93 14:18
07/20/93 14:35
08/02/93 10:49
07/19/93 14:27
07/20/93 14:36
07/19/93 14:28
07/20/93 14:37
07/19/93 14:29
07/20/93 14:38
07/19/93 14:29
07/20/93 14:39
07/19/93 14:30
07/20/93 14:39
07/19/93 14:31
07/20/93 14:40
07/19/93 14:31
07/20/93 14:40
07/19/93 14:32
07/20/93 14:41
07/19/93 14:41
07/20/93 15:05
07/19/93 14:52
07/20/93 15:06
07/19/93 14:53
07/20/93 15:07
Weight (g)
67.84220
67.84220
67.84220
64.90430
64.90430
66.35420
66.35430
65.48210
65.48210
66.23110
66.23130
67.19940
67.19910
64.51520
64.51560
65.56970
65.57020
66.36560
66.36540
64.40950
64.40940
67.28260
67.28290
67.18740
67.18690
Analyst
TGW
TGW
TGW
TGW
TGW
TGW
TGW
TGW
TGW
TGW
TGW
TGW
TGW
TGW
TGW
TGW
TGW
TGW
TGW
TGW
TGW
TGW
TGW
TGW
TGW
Constant
Weight (g)
67.84220
64.90430
66.35430
65.48210
66.23130
67.19910
64.51560
65.57020
66.36540
64.40940
67.28290
67.18690
-------
ETS, Inc.
GRAVIMETRIC LABORATORY DATA
Tare Filter Weights
Filter Description: Gelmans
Report Prepared on: 08/03/93
Page
Filter
Number
G92-0117
G92-0118
692-0119
G92-0120
Date Time
02/26/92 07:07
03/06/92 16:11
02/26/92 07:07
03/06/92 16:09
02/26/92 07:08
03/06/92 16:07
02/26/92 07:09
03/06/92 16:06
Weight (g)
0.54169
0.54180
0.53751
0.53753
0.53611
0.53611
0.53236
0.53242
Analyst
NKL
nkl
NKL
nkl
NKL
nkl
NKL
nkl
Constant
Weight (g)
0.54180
0.53753
0.53611
0.53242
-------
ETS, Inc.
GRAVIMETRIC LABORATORY DATA
Final Beaker Weights
Job Number: 92-655WA
Report Prepared on: 11/01/93
Page
Beaker #
Filter #
Sample #
Run I.D.
Total Vol., ml
Aliquot Vol.
07/07/93-001
G92-117
G92-0117
92-655WA-00100
BO -201-R1
07/07/93-002
92-655WA-00101
BO -201-R1
122.00000
122.00000
07/07/93-003
92-655WA-00102
BO -201-R1
124.00000
124.00000
07/07/93-004
G92-0118
92-655WA-00106
BO -201-R2
07/07/93-005
92-655WA-00107
BO -201-R2
122.00000
122.00000
Constant
Tare
Weight (g)
Beaker
Filter
67.84220
0.54180
64.90430
0.00000
66.35430
0.00000
65.48210
0.53753
66.23130
0.00000
Final Weight Data
Date Time Weight (g) Analyst
07/28/93 12:30 68.37720 PJB
07/28/93 18:32 68.38500 pjb
07/29/93 07:55 68.38790 PJB
07/29/93 14:00 68.38810 PJB
07/28/93 12:34 64.90550 PJB
07/28/93 18:36 64.90740 PJB
07/29/93 07:55 64.90700 PJB
07/28/93 12:32 66.35980 PJB
07/28/93 18:33 66.35840 PJB
07/29/93 07:56 66.35730 PJB
07/29/93 14:02 66.35690 PJB
07/28/93 12:35 66.01500 PJB
07/28/93 18:36 66.02200 PJB
07/29/93 07:56 66.02070 PJB
07/29/93 14:03 66.02090 PJB
07/28/93 12:36 66.23240 PJB
07/28/93 18:40 66.23290 PJB
Constant
Final
Weight (g)
68.38810
64.90700
66.35690
66.02090
66.23290
-------
ETS, Inc.
GRAVIMETRIC LABORATORY DATA
Final Beaker Weights
Job Number: 92-655WA
Report Prepared on: 11/01/93
Page
Beaker #
Filter #
Sample #
Run I.D.
Total Vol., ml
Aliquot Vol.
07/07/93-006
92-655WA-00108
BO -201-R2
110.00000
110.00000
07/07/93-007
G92-0119
92-655WA-00112
BO -201-R3
07/07/93-008
92-655WA-00113
BO -201-R3
89.00000
89.00000
07/07/93-009
92-655WA-00114
BO -201-R3
120.00000
120.00000
07/07/93-010
G92-0120
92-655WA-00118
BO -201-RO
Constant
Tare
Weight (g)
Beaker
Filter
67.19910
0.00000
64.51560
0.53611
65.57020
0.00000
66.36540
0.00000
64.40940
0.53242
Final Weight Data
Date Time Weight (g) Analyst
07/28/93 12:32 67.20150 PJB
07/28/93 18:38 67.20100 PJB
07/28/93 12:32 65.05470 PJB
07/28/93 18:38 65.05230 PJB
07/29/93 07:56 65.05490 PJB
07/29/93 14:01 65.05200 PJB
07/30/93 07:10 65.05340 PJB
07/30/93 13:10 65.05290 PJB
07/28/93 12:34 65.57440 PJB
07/28/93 18:40 65.57410 PJB
07/28/93 12:34 66.36890 PJB
07/28/93 18:42 66.37510 pjb
07/29/93 07:57 66.36710 PJB
07/29/93 14:02 66.36740 PJB
07/28/93 12:33 64.93920 PJB
07/28/93 18:40 64.94070 PJB
07/29/93 07:58 64.94270 PJB
07/29/93 14:02 64.94290 PJB
Constant
Final
Weight (g)
67.20100
65.05290
65.57410
66.36740
64.94290
-------
ETS, Inc.
GRAVIMETRIC LABORATORY DATA
Final Beaker Weights
Job Number: 92-655WA
Report Prepared on: 11/01/93
Page
Beaker #
Filter #
Sample #
Run I.D.
Total Vol., ml
Aliquot Vol.
07/07/93-011
92-655WA-00119
BO -201-RO
125.00000
125.00000
07/07/93-012
92-655WA-00120
BO -201-RO
125.00000
125.00000
Constant
Tare
Weight (g)
Beaker
Filter
67.28290
0.00000
67.18690
0.00000
Final Weight Data
Date Time Weight (g) Analyst
07/28/93 12:28 67.28250 PJB
07/28/93 18:40 67.28400 PJB
07/29/93 07:59 67.28440 PJB
07/28/93 12:29 67.18640 PJB
07/28/93 18:39 67.18690 PJB
Constant
Final
Weight (g)
67.28440
67.18690
-------
ETS, Inc.
GRAVIMETRIC LABORATORY DATA
Silica Gel Weights
Report Prepared on: 08/03/93
Page
Sample
Number
92-655WA-00104
92-655WA-00110
92-655WA-00116
92-655WA-00121
Tare Weight (g)
200.0000
200.0000
200.0000
200.0000
Final Weight (g)
207.1500
204.8500
210.0100
200.1600
Description
teal
purple/teal
teal/amber
blue
-------
-------
c.o
KILN A DRYER OUTLET STACK APPENDICES
-------
APPENDIX C.I
DATA AND RESULTS FOR EPA METHOD 25A
AND MODIFIED METHOD 25A TESTING
(THC, METHANE AND ETHANE)
-------
Summary of Kiln A Dryer Exhaust Total Hydrocarbons, Methane, and
Ethane Emissions
RUN I.D.
DATE
TIME STARTED
TIME ENDED
SAMPLING PARAMETERS
Metered Volume - dcf
Corrected Volume - dscf
Total Test Time - min
GAS PARAMETERS
Gas Temperature - oF
Oxygen - %
Carbon Dioxide - %
Moisture - %
GAS FL'OWRATE
Velocity - ft/sec
Actual Volume - acfm
Standard Volume - dscfm
KAD-M1-4-R1 KAD-N1-4-R2 KAD-M1-4-R3
07/28/93 07/28/93 07/28/93
11:05 12:40 14:15
12:05 13:40 15:15
AVERAGE
35.484
33.403
60
145.3
19.4
0.1
6.69
60.16
17720
14483
35.162
32.583
60
143.5
18.8
0.8
6.10
60.46
17806
14689
36.160
33.363
60
148.0
18.7
0.8
6.84
60.49
17817
14474
35.602
33.116
60
145.6
19.0
0.6
6.54
60.37
17781
14549
THC EMISSIONS
Cone. - ppmwv (as Propane) 3.72 3.58 3.82 3.71
Cone. - ppmdv (as Propane) 3.99 3.81 4.10 3.97
Cone. - ppmdv (as Carbon) 11.96 11.44 12.30 11.90
Mass Rate - Ib/hr (as Carbon) 0.324 0.314 0.333 0.324
METHANE AND ETHANE EMISSIONS*
Cone. - ppmwv (as Propane) 2.13 1.62 1.42 1.72
Cone. - ppmdv (as Propane) 2.28 1.73 1.52 1.84
Cone. - ppmdv (as Carbon) 6.85 5.18 4.57 5.53
Mass Rate - Ib/hr (as Carbon) 0.186 0.142 0.124 0.150
TGNMO EMISSIONS
Mass Rate - Ib/hr (as Carbon) 0.138
0.172
0.209
0.173
Methane/Ethane emissions are based on a 14-minute test conducted
immediately prior to each THC test run.
-------
RUN NUMBER
KAD-M1-4-R1
DATE
START TIME
END TIME
STACK DIAM.
METER BOX GAMMA
METER BOX dH@
BAROMETRIC
Cp
TEST DURATION
METHOD 1-4 RESULTS
Metered Volume
Volume @ Std.Cond.
% Water
Velocity
Actual Flow
Std. Flow
Dry Std. Flow
STACK
TEMP STATIC
POINT fDeaF) (in. WO
1 111 0.47
2 110
3 115
4 119
5 148
6 154
7 156
8 156
9 156
10 157
11 158
12 158
13 137
14 138
15 139
16 139
17 148
18 151
19 153
20 155
21 155
22 157
23 158
24 159
25
AV6. 145 0.47
07/28/93
11:05
12:05
30
1.00624
1.72964
30.01
0.84
60
35.484
33.403
6.69
60.16
17720
15522
14483
DP
(in. WO
0.62
0.86
0.96
0.97
1.05
0.98
0.94
0.89
0.89
0.94
0.96
0.83
1.00
1.05
1.10
1.25
1.30
1.30
0.93
0.96
0.99
0.95
0.95
0.93
0.98
inches
in.Hg
minutes
dcf
dscf
%
ft/sec
acfm
scfm
dscfm
DH
(in. WO
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
METHOD 4
IMP.l
IMP. 2
IMP. 3
IMP. 4
IMP. 5
IMP. 6
IMP. 7
TOTAL
S.G.
METHOD 3
%02
%CO2
%CO
%N2
02+C02
METER
VOLUME
(dcf)
499.990
535.474
535.474
35.484
DATA
INIT.
(ml)
100.0
100.0
0.0
200.0
200.0
DATA
19.4
0.1
0.0
80.5
19.5
FINAL
(ml)
137.0
108.0
0.0
245.0
205.9
Md
Ms
Ps
Fo
%EA
NET
(ml)
37.0
8.0
0.0
0.0
0.0
0.0
0.0
45.0
5.9
28.80
28.07
30.04
12.500
1051
METER TEMPERATURE
INLET
(DeqF)
100
117
OUTLET
(DeaF)
100
112
107
-------
RUN NUMBER
KAD-M1-4-R2
DATE 07/28/93
START TIME 12:40
END TIME
STACK DIAM.
METER BOX GAMMA
METER BOX dH@
BAROMETRIC
Cp
TEST DURATION
METHOD 1-4 RESULTS
Metered Volume
Volume @ Std.Cond.
% Water
Velocity
Actual Flow
Std. Flow
Dry Std. Flow
STACK
TEMP STATIC
POINT (DeaF) (in.WC)
1 121 0.50
2 122
3 130
4 135
5 139
6 139
7 145
8 146
9 147
10 148
11 149
12 149
13 139
14 139
15 143
16 147
17 147
18 148
19 150
20 151
21 153
22 153
23 153
24 152
25
AVG. 144 0.50
13:40
30
1.00624
1.72964
30.01
0.84
60
35.162
32.583
6.10
60.46
17806
15643
14689
DP
(in. WO
0.64
0.91
0.96
0.97
1.05
1.05
0.88
0.86
0.83
0.91
0.89
0.94
1.00
1.10
1.15
1.35
1.15
1.10
0.94
0.98
1.05
1.10
1.10
1.10
1.00
inches
in.Hg
minutes
dcf
dscf
%
ft/sec
acfm
scfm
dscfm
DH
(in. WO
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
METHOD 4
IMP.l
IMP. 2
IMP. 3
IMP. 4
IMP. 5
IMP. 6
IMP. 7
TOTAL
S.G.
METHOD 3
%02
%CO2
%CO
%N2
02+C02
METER
VOLUME
(dcf)
535.603
570.765
570.765
35.162
DATA
INIT.
(mil
100.0
100.0
0.0
200.0
200.0
DATA
18.8
0.8
0.0
80.4
19.6
FINAL
(ml)
132.0
106.0
0.0
238.0
207.0
Md
Ms
Ps
Fo
%EA
NET
(ml)
32.0
6.0
0.0
0.0
0.0
0.0
0.0
38.0
7.0
28.88
28.21
30.05
2.692
773
METER TEMPERATURE
INLET
(DeoFl
114
120
OUTLET
(DeoF)
113
118
116
-------
RUN NUMBER
KAD-M1-4-R3
DATE
START TIME
END TIME
STACK DIAM.
METER BOX GAMMA
METER BOX dH@
BAROMETRIC
Cp
TEST DURATION
METHOD 1-4 RESULTS
Metered Volume
Volume @ Std.Cond.
% Water
Velocity
Actual Flow
Std. Flow
Dry Std. Flow
STACK
TEMP STATIC
POINT (DeaF) (in. WO
1 118 0.49
2 120
3 122
4 126
5 138
6 147
7 150
8 154
9 156
10 157
11 157
12 157
13 147
14 146
15 148
16 151
17 154
18 158
19 157
20 158
21 158
22 158
23 158
24 158
25
AVG. 148 0.49
07/28/93
14:15
15:15
30
1.00624
1.72964
30.01
0.84
60
36.160
33.363
6.84
60.49
17817
15536
14474
DP
(in.WC)
0.81
0.94
1.00
1.05
1.00
0.96
0.93
0.70
0.65
0.86
0.85
0.92
1.10
1.20
1.25
1.35
0.88
1.20
0.95
0.98
1.05
1.10
1.05
1.05
0.99
inches
in.Hg
minutes
dcf
dscf
%
ft/sec
acfm
scfm
dscfm
DH
(in.WC)
1.00
1.00
1.00
1.00
1.00
1.00-
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
METHOD 4
IMP.l
IMP. 2
IMP. 3
IMP. 4
IMP. 5
IMP. 6
IMP. 7
TOTAL
S.G.
METHOD 3
%02
%C02
%CO
%N2
O2+CO2
METER
VOLUME
(dcf)
570.927
607.087
607.087
36.160
DATA
INIT.
(ml)
100.0
100.0
0.0
200.0
200.0
DATA
18.7
0.8
0.0
80.5
19.5
FINAL
(ml)
18.0
222.0
0.0
240.0
212.0
Md
Ms
Ps
Fo
%EA
NET
(ml)
-82.0
122.0
0.0
0.0
0.0
0.0
0.0
40.0
12.0
28.87
28.13
30.05
2.857
730
METER TEMPERATURE
INLET
(DeqF)
118
121
OUTLET
(DeaF)
118
118
119
-------
APPENDIX C.2
RAW FIELD SAMPLING DATA FOR EPA METHODS 2-4
-------
METHOD 1-4 DATASHEET
muTOAPT MIIMPCO
lrl/« • I INrtO I I*WI IWWfX
end Time /-if .'
Sox Number.
/. 1 1
BAROMETRIC PRESSURE
AVERAGE DELTA M / >• O
':TAT!C PRESSURE 1*
•
IKiTSAL METER VOLUME .
FINAL METER VOLUME ^"7(0. 1
METER TEMPERATURE U'H/h 1
TRAVERSE DATA
JOB NAME
SAMPLING LOCATION
BOX
.S'A9
A* 7
/VJ
/^7
/v;
tit
1 SO
ISI
IS)
)S3
>£J
1S2
MPWGER YOL'.WES/HEIGHTS
11
#3
SG
Initial
ml
ml
Rrral
rr,l
l& 6 ml
Port
dP
Stack Temp.
Ow. F
i
I
i
I
i
1
1
i
-------
METHOD 1-4 DATA 5MEET
(V.r, Mi|f--.Kp^ 1 A-f} ~ MI-LJ - /
...•ji, UUIiivCi ^fl**1 ' '
'jl<
En
So
r- .
Ga
BA
AV
r!V
i.'.1!
Fif
ME
TP
>Ct
?
?
r'
*>
/
4
i ft Time //.-Q5"
d Ti me ,'P '- dT
/Number. 416
/, ?0?^y
mn« /.0063V
ROMETRIC PRE
[RAGE DELTA h
iT!C PRESSURE
T:AL METER vo
AL METER VOL
TER TEMPERA!
JAVERSt D
,
AMPLING LOCATIO
nxnPFPAinp C
f
<4 y^//h /(
\Fe^^0^
TATI- o
/Jf
Port
;
^
3
V
;
^
?
f
t
//
/^
dP
l>0
/.OS
I.I
l.JS
1.1
U
,13
.56
.ft
,K
.$$
fj
Stack Temp.
Deo.. F
131
i 5 C*
* »./ Q
w
/Jf
i vr
1st
J$!
1 S3
}S$
If?
is>r
l$1
%
s
s
M
£02
;m
, &.*
/} fi
*•*'/• V^A O
/
i
MPNGER YOUJMES/ WEIGHTS
Initial
#1 /^x? ml
*2 /c,0 ml
#3 D ml
SG ^OO^ $m
0
Port
Final
A? 7 m1
— S9— *
/af ml
Z) ml
o^Xf^9m
dP
&
Stack Temp.
•
1
.
"7
-------
METHOD M DATA SHEET
MIIMPCO
JOB NAME
7 iff ic
/ / • 1 3
SAMPLING LOCATION
A
end Time
Sox Number.
fcifc H,
BOXI
STACK SIZE
BAROMETRIC PRESSURE
AVERAGE DELTA M
':TAT!C PRESSURE
/.o
-f ,
i i it-it, i H.II.
C'O ^
^> \j . \
FINAL METER VOLUME
METER TEMPERATURE
TRAVERSE DATA
£o 7
/-,'n
-------
INTEGRATED BAG ANALYSIS DATA
Job Name
Contract
Method of Analysis
LPh Rrick V/h ^
<\1- &S5
0^ I(O7
Run Number
80-
cHP.f
0.
#0-
o.\
. 1
/6.-7
. 77
-------
APPENDIX C.3
DATA AND RESULTS FOR CONTINUOUS EMISSIONS MONITORING
(THC, METHANE AND ETHANE)
-------
EPA Brick WA 14
Dryer Stack
Total Hydrocarbons
DSO-M25A-R1
Starting
07-28-93
Time
11:07
11:08
11:09
11:10
11:11
11:12
11:13
11:14
11:15
11:16
11:17
11:18
11:19
11:20
11:21
11:22
11:23
11:24
11:25
11:26
11:27
11:28
11:29
11:30
11:31
11:32
11:33
11:34
11:35
11:36
11:37
11:38
11:39
11:40
11:41
11:42
11:43
11:44
11:45
THC
PPMWV
4.04
4.24
4.22
3.98
3.88
3.97
4.06
3.95
3.94
4.04
4.20
4.20
4.16
4.10
4.18
.4.14
3.87
3.71
3.78
3.87
3.94
3.92
3.92
3.92
3.98
3.92
3.92
3.97
4.15
4.22
4.14
4.30
4.27
4.25
4.18
4.15
4.16
4.31
4.41
-------
EPA Brick WA 14
Dryer Stack
Total Hydrocarbons
DSO-M25A-R1
Starting
07-28-93
Time
11:46
11:47
11:48
11:49
11:50
11:51
11:52
11:53
11:54
11:55
11:56
11:57
11:58
11:59
12:00
12:01
12:02
12:03
12:04
12:05
59 MinAvg
THC
PPMWV
4.29
4.28
4.24
4.30
4.28
4.56
4.39
4.49
4.39
4.16
3.97
3.91
4.00
3.96
3.86
3.81
3.95
4.02
4.00
4.05
4.09
Data Corrected for Calibrations
59 MinAvg 3.72
-------
Calibrations:
VOC 100 Span Value - 100
LOW Calibration Gas = 0.00 HIGH Calibration Gas = 24.58
Initial Cal. at: 1041
LOW Cal. Response = -0.01 HIGH Cal. Response = 24.83
Cal. Drift = -0.00 Cal. Drift = 0.00
Final Cal. at: 1215
LOW Cal. Response = 0.74 HIGH Cal. Response = 25.27
Cal. Drift = 0.01 Cal. Drift = 0.01
LOW System Drift = 0.01 HIGH System Drift = 0.00
-------
EPA Brick WA 14
Dryer Stack
Total Hydrocarbons
DSO-M25A-R2
Starting
07-28-93
Time
12:42
12:43
12:44
12:45
12:46
12:47
12:48
12:49
12:50
12:51
12:52
12:53
12:54
12:55
12:56
12:57
12:58
12:59
13:00
13:01
13:02
13:03
13:04
13:05
13:06
13:07
13:08
13:09
13:10
13:11
13:12
13:13
13:14
13:15
13:16
13:17
13:18
13:19
13:20
THC
PPMWV
3.93
4.11
4.10
4.08
4.05
4.15
4.26
4.20
4.22
4.18
4.22
4.20
4.17
4.17
4.17
4.31
4.24
4.07
3.86
3.90
4.03
4.03
4.00
4.07
4.17
4.10
4.08
4.07
4.21
4.26
4.23
4.21
4.27
4.49
4.58
4.52
4.51
4.61
4.66
-------
EPA Brick WA 14
Dryer Stack
Total Hydrocarbons
DSO-M25A-R2
Starting
07-28-93
Time
13:21
13:22
13:23
13:24
13:25
13:26
13:27
13:28
13:29
13:30
13:31
13:32
13:33
13:34
13:35
13:36
13:37
13:38
13:39
13:40
59 MinAvg
THC
PPMWV
4.66
4.54
4.40
4.50
4.45
4.41
4.45
4.74
4.81
4.64
4.47
4.34
4.13
4.25
4.13
4.11
4.20
4.31
4.27
4.26
4.27
Data Corrected for Calibrations
59 MinAvg 3.58
-------
Calibrations:
VOC 100
Span Value = 100
LOW Calibration Gas =
Initial Cal. at: 1215
LOW Cal. Response = 0.74
Cal. Drift = 0.01
Final Cal. at: 1350
LOW Cal. Response = 0.70
Cal. Drift = 0.01
LOW System Drift = -0.00
0.00 HIGH Calibration Gas = 24.58
HIGH Cal. Response = 25.27
Cal. Drift = 0.01
HIGH Cal. Response = 24.93
Cal. Drift = 0.00
HIGH System Drift = -0.00
-------
EPA Brick WA 14
Dryer Stack
Total Hydrocarbons
DSO-M25A-R3
Starting
07-28-93
Time
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
14:
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
THC
PPMWV
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
4.
18
30
33
24
26
37
50
48
39
33
45
50
55
41
57
83
68
59
48
26
11
07
26
18
35
34
35
34
62
63
55
39
40
53
51
45
48
53
61
-------
EPA Brick WA 14
Dryer Stack
Total Hydrocarbons
DSO-M25A-R3
Starting
07-28-93
Time
14:56
14:57
14:58
14:59
15:00
15:01
15:02
15:03
15:04
15:05
15:06
15:07
15:08
15:09
15:10
15:11
15:12
15:13
15:14
15:15
59 MinAvg
THC
PPMWV
4.53
4.53
4.54
4.65
4.60
4.61
4.61
4.49
4.62
4.58
4.60
4.65
4.67
4.57
4.35
4.57
4.57
4.62
4.38
4.29
4.47
Data Corrected for Calibrations
59 MinAvg 3.82
-------
Calibrations:
Span Value = 100
VOC 100
LOW Calibration Gas
Initial Cal. at: 1350
LOW Cal. Response = 0.70
Cal. Drift = 0.01
Final Cal. at: 1525
LOW Cal. Response = 0.71
Cal. Drift = 0.01
LOW System Drift = 0.00
0.00 HIGH Calibration Gas = 24.58
HIGH Cal. Response = 24.93
Cal. Drift = 0.00
HIGH Cal. Response = 24.91
Cal. Drift = 0.00
HIGH System Drift = -0.00
-------
EPA Brick WA 14
Dryer Stack
Methane/Ethane
RUN 1
Starting
07-28-93
Time
10:47
10:48
10:49
10:50
10:51
10:52
10:53
10:54
10:55
10:56
10:57
10:58
10:59
11:00
14 MinAvg
Meth/Eth
PPMWV
2.11
2.02
2.02
2.07
2.19
2.38
2.20
2.15
2.22
2.25
2.12
2.05
2.07
2.02
2.13
-------
EPA Brick WA 14
Dryer Stack
Methane/Ethane
RUN 2
Starting
07-28-93
Time
12:21
12:22
12:23
12:24
12:25
12:26
12:27
12:28
12:29
12:30
12:31
12:32
12:33
12:34
14 MinAvg
Meth/Eth
PPMWV
1.73
1.71
1.77
1.72
1.71
1.74
1.59
1.52
1.49
1.54
1.55
1.54
1.51
1.53
1.62
-------
EPA Brick WA 14
Dryer Stack
Methane/Ethane
RUN 3
Starting
07-28-93
Time
13:54
13:55
13:56
13:57
13:58
13:59
14:00
14:01
14:02
14:03
14:04
14:05
14:06
14:07
14 MinAvg
Meth/Eth
PPMWV
1.44
1.41
1.45
1.50
1.46
1.40
1.37
1.37
1.42
1.45
1.42
1.41
1.39
1.38
1.42
-------
-------
D.O
KILN COMBUSTION ZONE EXHAUST STACK APPENDICES
-------
APPENDIX D.1.0
KILN COMBUSTION EXHAUST STACK
DATA AND RESULTS APPENDICES
-------
APPENDIX D.I.I
DATA AND RESULTS FOR EPA METHOD 201A/202 TESTING
-------
Summary of the Kiln Combustion Exhaust PM,
PM10, and CPM Emissions
RUN I.D.
DATE
TIME STARTED
TIME ENDED
KCE-M201A/202-R1 KCE-M201A/202-R2 KCE-M201A/202-R3
07/31/93 07/31/93 07/31/93
11:45 14:07 16:49
13:29 15:55 18:26
AVERAGE
SAMPLING PARAMETERS
Metered Volume - dcf
Corrected Volume - dscf
Total Test Time - min
% Isokinetics
D50
GAS PARAMETERS
Gas Temperature - oF
Oxygen - %
Carbon Dioxide - %
Moisture - %
GAS FLOWRATE
Velocity - ft/sec
Actual Volume - acfm
Standard Volume - dscfm
PM10 EMISSIONS
Concentration - gr/dscf
Mass Rate - Ib/hr
PM> 10 MICRON EMISSIONS
Concentration - gr/dscf
Mass Rate - Ib/hr
CPM EMISSIONS
Concentration - gr/dscf
Mass Rate - Ib/hr
TOTAL PM EMISSIONS
Concentration - gr/dscf
Mass Rate - Ib/hr
41.126
39.685
94
107.2
9.47
333.6
13.12
6.62
10.25
28.83
7208
4318
0.090
3.323
0.032
1.171
0,024
0.883
0.145
5.378
44.103
42.171
100
114.8
9.52
331.5
13.04
6.58
9.76
26.70
6675
4030
0.073
2.517
0.044
1.529
0.042
1.454
0.159
5.500
36.054
34.080
81.0
107.2
9.39
342.0
12.01
6.47
11.43
29.44
7359
4305
0.080
2.958
0.036
1.334
0.028
1.026
0.144
5.318
38.590
36.882
87.5
107.2
9.43
337.8
12.57
6.55
10.84
29.13
7284
4311
0.085
3.141
0.034
1.252
0.026
0.955
0.145
5.348
-------
RUN NUMBER
KCE-M201A/202-R1
DATE
START TIME
END TIME
STACK LENGTH
STACK WIDTH
STACK EQUIV. DIAM.
NOZZLE I.D.
METER BOX GAMMA
METER BOX dH@
BAROMETRIC
Cp
TEST DURATION
SAMPLING RESULTS
Metered Volume
Metered Volume
Volume @ Std.Cond.
Volume @ Std.Cond.
% Water
% Isokinetics
07/31/93
11:45
13:29
25 inches
24 inches
24.49 inches
0.264 inches
1.00624
1.72964
30.00 in.Hg
0.84
94.0 minutes
41.126
1.165
39.685
1.124
10.25
107.2
dcf
dcm
dscf
dscm
METHOD 4
IMP.1
IMP.2
IMP.3
IMP.4
IMP.5
IMP.6
IMP.7
TOTAL
S.G.
METHOD 3
%02
%CO2
%CO
%N2
O2+CO2
DATA
INIT.
{mJl
100.0
100.0
100.0
0.0
300.0
200.0
DATA
13.12
6.62
0.0
80.3
10.0
FINAL
(ml)
174.0
110.0
100.0
0.0
384.0
212.3
Md
Ms
Ps
Fo
%EA
NET
(m!i
74.0
10.0
0.0
0.0
0.0
0.0
0.0
84.0
12.3
29.58
28.40
30.01
1.175
162.60
VOLUMETRIC RESULTS - USENG
Velocity 28.83
Actual Flow 7208
Std. Flow 4811
Dry Std. Flow 4318
ft/sec
acfm
scfm
dscfm
VOLUMETRIC RESULTS • SI
Velocity 8.79 m/sec
Actual Flow 12247 am3/hr
Std. Flow 8173 sm3/hr
Dry Std. Flow 7336 dsm3/hr
POINT
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
AVG.
STACK
TEMP
(DeaF)
298
319
344
349
346
331
310
327
337
329
312
342
318
311
341
340
347
348
340
341
341
345
344
346
334
METER METER TEMPERATURE
STATIC DP
(in.WC) (in.WCl
0.17 0.19
0.16 0.18
0.15 0.22
0.13 0.21
0.18
0.15
0.18
0.16
0.17
0.15
0.16
0.15
0.15
0.16
0.18
0.21
0.18
0.21
0.15
0.15
0.17
0.16
0.17
0.18
0.15 0.17
DWELL
TIME
4.05
3.94
4.35
4.25
3.94
3.59
3.94
3.71
3.83
3.59
3.71
3.59
3.59
3.71
3.94
4.25
3.94
4.25
3.59
3.59
3.83
3.71
3.83
3.94
3.86
DH VOLUME
(in. WO (dcfl
0.52 830.837
0.52 871 .963
0.52
0.52
0.52
0.52
0.52
0.52
0.52
0.52
0.52
0.52
0.52
0.52
0.52
0.52
0.52
0.52
0.52
0.52
0.52
0.52
0.52
0.52
871 .963
0.52 41.126
INLET
(DeoF)
93
88
86
90
90
94
96
91
87
91
89
94
96
97
94
91
98
100
101
102
99
97
98
97
OUTLET
(DegF)
92
80
87
88
87
89
92
85
87
89
87
91
93
92
90
90
94
96
98
98
96
94
94
94
93
-------
EPA METHOD 201A/202 ANALYSES
RUN I.D.
SUMMARY
COMPONENT
PM10:
Probe Wash <= 1 0 microns
Filter
TOTAL PM10
PM(> 10 Microns):
Probe Wash > 10 microns
TOTAL PM
CONDENSIBLE PM
Organic CPM
Inorganic CPM
TOTAL CPM
TOTAL PARTICULATE (TSP+CPM)
ANALYTICAL DATA
METHOD 201A COMPONENTS:
Filter
Probe Wash Residue <= PM10
Acetone Blank Residue
Applicable Acetone Blank
Max. Allowable Blank
Probe Wash Residue > PM10
Acetone Blank Residue
KCE-M201A/202-R1
NET
(grams)
0.01310
0.21782
0.23092
0.08150
0.31242
0.04600
0.04530
0.09130
0.40372
TARE
(grams)
0.41468
64.95180
67.69890
65.00620
64.00410
CORRECTED
FOR BLANK
(grams)
0.01310
0.21782
0.23092
0.08140
0.31232
NA
NA
0.06140
0.37372
FINAL
(grams)
0.63250
64.96490
67.69890
65.08770
64.00420
Applicable Acetone Blank
Max. Allowable Blank
METHOD 202 COMPONENTS:
Container #4
Organic Residue (uncorr.)
Inorganic Residue (uncorr.)
MeCI2 Blank
H2O Blank
TARE
(grams)
67.08520
197.53390
64.89250
64.59390
FINAL
(grams)
67.13120
197.57920
64.90660
64.60970
PARTICULATE EMISSIONS:
PM10
Actual Grain Loading (gr/dscf) 0.08978
Mass Rate (Ib/hr) 3.323
PM>10u
0.03165
1.171
NET
(grams)
0.21782
0.01310
0.00000
0.00000
0.00047
0.08150
0.00010
0.00010
0.00082
NET
(grams)
0.04600
0.04530
0.01410
0.01580
Total CPM
0.02387
VOLUME
(ml)
NA
60.0
120.0
60.0
NA
105.0
110.0
105
NA
VOLUME
(ml)
534
250
450
125
500
Total PM
0.145
0.883
5.378
-------
D50 Calculations
RUNI.D. KCE-M201A/202-R1
Stack Gas Viscosity (micropoise) 235.1002
Cyclone Flow Rate (dscf/min) 0.42218
Cyclone Flow Rate (acfm) 0.705133
D50 9.470939
dPmin and dPmax Calculations
Stack Gas Viscosity (micropoise) 240.5222
Cyclone Flow Rate (acfm) 0.668166
Dn vn vmin vmax dPmin dPmax
0.136 110.39773 92.55990 135.64784 1.784526 3.832683
0.15 90.75184 77.23037 112.37690 1.242377 2.630457
0.164 11.00000 17.08689 20.34882 0.060814 0.086249
0.18 63.02211 55.81326 79.72440 0.648861 1.323914
0.197 52.61451 47.87923 67.56796 0.477498 0.950952
0.215 44.17342 41.50585 57.77248 0.358836 0.695215
0.233 37.61197 36.59894 50.21214 0.279006 0.525163
0.264 29.29747 30.45106 40.72376 0.193144 0.345440
0.3 22.68796 25.62170 33.27779 0.136739 0.230667
0.342 17.45765 21.82369 27.45933 0.099205 0.157057
0.39 13.42483 18.88296 23.01457 0.074271 0.110327
-------
RUN NUMBER
KCE-M201A/202-R2
DATE
START TIME
END TIME
STACK LENGTH
STACK WIDTH
STACK EQUIV. DIAM.
NOZZLE I.D.
METER BOX GAMMA
METER BOX dH@
BAROMETRIC
Cp
TEST DURATION
SAMPLING RESULTS
Metered Volume
Metered Volume
Volume @ Std.Cond.
Volume @ Std.Cond.
% Water
% Isokinetics
07/31/93
14:07
15:55
25 inches
24 inches
24.49 inches
0.264 inches
1.00624
1.72964
30.00 in.Hg
0.84
100.0 minutes
44.103
1.249
42.171
1.194
9.76
114.8
VOLUMETRIC RESULTS - USENG
Velocity 26.70
Actual Flow 6675
Std. Flow 4466
Dry Std. Flow 4030
dcf
dcm
dscf
dscm
ft/sec
acfm
scfm
dscfm
METHOD 4 DATA
IMP.1
IMP.2
IMP.3
IMP.4
IMP.5
IMP.6
IMP.7
TOTAL
S.G.
METHOD 3 DATA
%02 13.04
%CO2 6.58
%CO 0.0
%N2 80.4
O2+CO2 19.6
NIT.
[mi}
100.0
100.0
100.0
0.0
300.0
200.0
FINAL
(ml)
178.0
110.0
100.0
0.0
388.0
208.8
NET
(ml)
78.0
10.0
0.0
0.0
0.0
0.0
0.0
88.0
8.8
Md
Ms
Ps
Fo
%EA
VOLUMETRIC RESULTS - SI
Velocity 8.14
Actual Flow 11341
Std. Flow 7588
Dry Std. Flow 6848
29.57
28.45
30.01
1.195
159.41
m/sec
amS/hr
sm3/hr
dsm3/hr
POINT
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
AVG.
STACK
TEMP STATIC
(DeaF) (in.WC)
318 0.16
322 0.14
335 0.14
322 0.17
320
338
335
340
331
317
334
340
329
335
314
337
333
334
340
329
336
334
342
342
332 0.15
METER METER TEMPERATURE
DP
(in.WC)
0.13
0.15
0.13
0.14
0.14
0.13
0.13
0.13
0.14
0.18
0.18
0.13
0.15
0.15
0.13
0.14
0.14
0.13
0.21
0.21
0.18
0.17
0.15
0.13
0.15
DWELL
TIME
3.93
4.21
3.93
4.07
4.07
3.93
3.93
> 3.93
4.07
4.62
4.62
3.93
4.21
4.21
3.93
4.07
4.07
3.93
4.99
4.99
4.62
4.49
4.21
3.93
4.20
DH VOLUME
(in.Wa (dcfi
0.53 872.362
0.53 916.465
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
916.465
0.53 44.103
INLET
(DeaF)
90
90
91
92
91
97
95
100
100
97
98
102
100
102
101
106
101
97
98
102
104
107
108
107
OUTLET
(DeaR
90
90
91
92
90
94
94
97
97
95
95
98
99
98
98
100
96
94
97
98
100
102
102
103
98
-------
EPA METHOD 201 A/202 ANALYSES
RUN I.D.
SUMMARY
COMPONENT
PM10:
Probe Wash <= 1 0 microns
Filter
TOTAL PM 10
PM(>10 Microns):
Probe Wash > 10 microns
TOTAL PM
CONDENSIBLE PM
Organic CPM
Inorganic CPM
TOTAL CPM
TOTAL PARTICULATE (TSP+CPM)
ANALYTICAL DATA
METHOD 201A COMPONENTS:
Filter
Probe Wash Residue <= PM10
Acetone Blank Residue
Applicable Acetone Blank
Max. Allowable Blank
Probe Wash Residue > PM10
Acetone Blank Residue
Applicable Acetone Blank
Max. Allowable Blank
METHOD 202 COMPONENTS:
Container #4
Organic Residue (uncorr.)
Inorganic Residue (uncorr.)
MeCI2 Blank
H2O Blank
PARTICULATE EMISSIONS:
Actual Grain Loading (gr/dscf)
KCE-M201A/202-R2
NET
(grams)
0.01110
0.18800
0.19910
0.12110
0.3202
0.01920
0.12570
0.14490
0.46510
TARE
(grams)
0.40990
67.64640
67.69890
68.14970
64.00410
TARE
(grams)
65.12590
196.20190
64.89250
64.59390
PM10
0.07285
CORRECTED
FOR BLANK
(grams)
0.01110
0.18800
0.19910
0.12100
0.32010
NA
NA
0.11500
0.43510
FINAL
(grams)
0.59790
67.65750
67.69890
68.27080
64.00420
FINAL
(grams)
65.14510
196.32760
64.90660
64.60970
PM>10u
0.04427
NET
(grams)
0.18800
0.01110
0.00000
0.00000
0.00055
0.12110
0.00010
0.00010
0.00086
NET
(grams)
0.01920
0.12570
0.01410
0.01580
Total CPM
0.04208
VOLUME
(ml)
NA
70.0
120.0
70.0
NA
110.0
110.0
110
NA
VOLUME
(ml)
538
250
450
125
500
Total PM
0.159
Mass Rate (Ib/hr)
2.517
1.529
1.454
5.500
-------
D50 Calculations
RUNI.D. KCE-M201A/202-R2
Stack Gas Viscosity (micropoise)
Cyclone Flow Rate (dscf/min)
Cyclone Flow Rate (acfm)
D50
dPmin and dPmax Calculations
Stack Gas Viscosity (micropoise)
Cyclone Flow Rate (acfm)
Dn vn vmin
0.136 110.14761 92.35538
0.15 90.54623 77.06099
0.164 75.74696 65.59021
0.18 62.87933 55.69315
0.197 52.49530 47.77745
0.215 44.07334 41.41881
0.233 37.52676 36.52325
0.264 29.23109 30.38958
0.3 22.63656 25.57132
0.342 17.41810 21.78193
0.39 13.39441 18.84776
vmax
135.34444
112.12656
94.66319
79.54874
67.42018
57.64721
50.10429
40.63780
33.20903
27.40397
22.96937
234.8959
0.421707
0.69869
9.518384
240.2805
0.666653
dPmin
1.784272
1.242241
0.899942
0.648844
0.477510
0.358866
0.279046
0.193191
0.136786
0.099250
0.074312
3
2
1
1
0
0
0
0
0
0
0
dPmax
.831929
.629988
.874558
.323742
.950860
.695174
.525154
.345460
.230701
.157095
.110366
-------
RUN NUMBER
KCE-M201A/202-R3
DATE
START TIME
END TIME
STACK LENGTH
STACK WIDTH
STACK EQUIV. DIAM.
NOZZLE I.D.
METER BOX GAMMA
METER BOX dH@
BAROMETRIC
Cp
TEST DURATION
SAMPLING RESULTS
Metered Volume
Metered Volume
Volume @ Std.Cond.
Volume @ Std.Cond.
% Water
% Isokinetics
07/31/93
16:49
18:26
25
24
24.49
0.264
1.00624
1.72964
30.00
0.84
81
36.054
1.021
34.080
0.965
11.43
107.2
inches
inches
inches
inches
in.Hg
minutes
dcf
dcm
dscf
dscm
%
%
VOLUMETRIC RESULTS - USENG
Velocity
Actual Flow
Std. Flow
Dry Std. Flow
STACK
TEMP STATIC
POINT (DegF) (in.WC)
1 339 0.16
2 342 0.14
3 345 0.15
4 344 0.15
5 344
6 340
7 329
8 341
9 343
10 345
11 347
12 345
13 337
14 344
15 344
16 347
17 340
18 343
19 335
20 339
21 342
22 344
23 344
24 344
25
AVG. 342 0.15
29.44
7359
4860
4305
ft/sec
acfm
scfm
dscfm
METHOD 4
IMP.1
IMP.2
IMP.3
IMP.4
IMP.5
IMP.6
IMP.7
TOTAL
S.G.
METHOD 3
%O2
%CO2
%CO
%N2
02+CO2
DATA
INIT.
(ml)
100.0
100.0
100.0
0.0
300.0
200.0
DATA
12.01
6.47
0.0
81.5
18.5
VOLUMETRIC RESULTS
Velocity
Actual Flow
Std. Flow
Dry Std. Flow
FINAL
{ml}
172.0
106.0
100.0
0.0
378.0
215.4
Md
Ms
Ps
Fo
%EA
-SI
8.97
12503
8257
7314
NET
(ml)
72.0
6.0
0.0
0.0
0.0
0.0
0.0
78.0
15.4
29.52
28.20
30.01
1.374
126.27
m/sec
am3/hr
sm3/hr
dsm3/hr
METER METER TEMPERATURE
DP
(in.WCl
0.19
0.21
0.22
0.21
0.18
0.16
0.15
0.16
0.18
0.19
0.16
0.15
0.15
0.16
0.16
0.18
0.21
0.18
0.16
0.18
0.19
0.20
0.18
0.16
0.18
DWELL
TIME
3.53
3.71
3.79
3.71
3.43
3.23
3.13
3.23
3.43
3.53
3.23
3.13
3.13
3.23
3.23
3.43
3.71
3.43
3.23
3.43
3.53
3.61
3.43
3.23
3.40
DH
(in.WCl
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
0.53
VOLUME
(dcfl
916.753
952.807
952.807
36.054
INLET
(DegF)
104
105
105
109
108
111
108
111
112
112
108
106
104
105
108
109
108
106
105
105
104
103
101
101
104
OUTLET
(DeaF)
100
101
101
102
102
104
106
105
106
106
103
101
100
102
103
104
102
103
104
98
97
97
96
95
-------
EPA METHOD 201 A/202 ANALYSES
RUN I.D.
SUMMARY
COMPONENT
PM10:
Probe Wash <= 1 0 microns
Filter
TOTAL PM10
PM(>10 Microns):
Probe Wash > 10 microns
TOTAL PM
CONDENSIBLE PM
Organic CPM
Inorganic CPM
TOTAL CPM
TOTAL PARTICULATE (TSP+CPM)
ANALYTICAL DATA
METHOD 201A COMPONENTS:
Filter
Probe Wash Residue <= PM10
Acetone Blank Residue
Applicable Acetone Blank
Max. Allowable Blank
Probe Wash Residue > PM10
Acetone Blank Residue
KCE-M201A/202-R3
NET
(grams)
0.01940
0.15769
0.17709
0.07990
0.25699
0.02680
0.06450
0.09130
0.34829
TARE
(grams)
0.39921
64.49090
67.69890
67.83080
64.00410
CORRECTED
FOR BLANK
(grams)
0.01940
0.15769
0.17709
0.07983
0.25692
NA
NA
0.06140
0.31832
FINAL
(grams)
0.55690
64.51030
67.69890
67.91070
64.00420
Applicable Acetone Blank
Max. Allowable Blank
METHOD 202 COMPONENTS:
Container #4
Organic Residue (uncorr.)
Inorganic Residue (uncorr.)
MeCI2 Blank
H2O Blank
TARE
(grams)
64.25800
196.65340
64.89250
64.59390
FINAL
(grams)
64.28480
196.71790
64.90660
64.60970
PARTICULATE EMISSIONS:
PM10
Actual Grain Loading (gr/dscf) 0.08018
Mass Rate (Ib/hr) 2.958
PM>10u
0.03614
1.334
NET
(grams)
0.15769
0.01940
0.00000
0.00000
0.00062
0.07990
0.00010
0.00007
0.00064
NET
(grams)
0.02680
0.06450
0.01410
0.01580
Total CPM
0.02780
VOLUME
(ml)
NA
79.0
120.0
79.0
NA
82.0
110.0
82
NA
VOLUME
(ml)
528
250
450
125
500
Total PM
0.144
1.026
5.318
-------
D50 Calculations
RUNI.D. KCE-M201A/202-R3
Stack Gas Viscosity (micropoise)
Cyclone Flow Rate (dscf/min)
Cyclone Flow Rate (acfm)
D50
dPmin and dPmax Calculations
Stack Gas Viscosity (micropoise)
Cyclone Flow Rate (acfm)
Dn vn vmin
0.136 111.36357 93.34840
0.15 91.54580 77.88304
0.164 76.58316 66.28370
0.18 63.57347 56.27545
0.197 53.07482 48.27059
0.215 44.55988 41.84022
0.233 37.94103 36.88940
0.264 29.55378 30.68659
0.3 22.88645 25.81434
0.342 17.61038 21.98300
0.39 13.54228 19.01697
vmax
136.81848
113.34249
95.68463
80.40151
68.13729
58.25477
50.6271 1
41 .05409
33.54166
27.67140
23.18738
235.8046
0.420737
0.719574
9.38981
241.3803
0.674012
dPmin
1.783642
1,241594
0.899306
0.648234
0.476935
0.358329
0.278546
0.192749
0.136400
0.098916
0.074025
dPmax
3.831629
2.629538
1.874037
1.323190
0.950306
0.694635
0.524639
0.344990
0.230284
0.156731
0.110052
-------
APPENDIX D.I.2
DATA AND RESULTS FOR EPA METHOD 29 TESTING
-------
RUN NUMBER
KCE-M29-R1
DATE
START TIME
END TIME
STACK DIAM.
NOZZLE I.D.
METER BOX GAMMA
METER BOX dH@
BAROMETRIC
Cp
TEST DURATION
SAMPLING RESULTS
Metered Volume
Metered Volume
Volume @ Std.Cond.
Volume @ Std.Cond.
% Water
% Isokinetics
VOLUMETRIC RESULTS -
Velocity
Actual Flow
Std. Flow
Dry Std. Flow
STACK
TEMP STATIC
POINT (DeaF) (in. WO
1 321 0.16
2 331 0.15
3 345 0.14
4 336 0.17
5 332
6 320
7 316
8 331
9 346
10 321
11 340
12 334
13 320
14 331
15 331
16 335
17 347
18 348
19 331
20 342
21 340
22 336
23 342
24 341
25
AVG. 334 0.16
07/30/92
12:28
14:44
25 x 24
0.3125
1.00624
1.72964
29.97
0.84
120
METHOD 4 DATA
inches
inches
in.Hg
minutes
IMP.l
IMP. 2
IMP. 3
IMP. 4
IMP. 5
IMP. 6
IMP. 7
TOTAL
S.G.
INIT.
(ml)
0.0
100.0
100.0
0.0
100.0
100.0
400.0
200.0
FINAL
(ml)
96.0
152.0
112.0
2.0
100.0
100.0
562.0
216.5
NET
(ml)
96.0
52.0
12.0
2.0
0.0
0.0
0.0
162.0
16.5
METHOD 3 DATA
73.243
2.074
70.904
2.008
10.60
107.7
USENO
28.83
7208
4803
4294
DP
( in . WC )
0.20
0.22
0.19
0.19
0.18
0.15
0.12
0.17
0.17
0.19
0.16
0.15
0.15
0.16
0.16
0.18
0.21
0.22
0.15
0.15
0.16
0.17
0.19
0.18
0.17
dcf
dcm
dscf
dscm
%
%
ft/sec
acfm
scfm
dscfm
DH
(in.WC)
1.30
1.55
1.20
1.20
1.10
0.96
0.96
1.10
1.10
1.20
1.00
0.96
0.96
1.00
1.00
1.15
1.40
1.55
0.96
0.96
1.00
1.10
1.20
1.15
1.13
%02
%C02
%CO
%N2
02+C02
VOLUMETRIC
Velocity
13.16
6.53
0.0
80.3
10.0
RESULTS
Actual Flow
Std. Flow
Dry Std.
METER
VOLUME
fdcf)
608.374
644.845
644.894
681.666
73.243
Flow
Md
Ms
Ps
Fo
%EA
- SI
8.79
12247
8160
7296
29.57
28.35
29.98
1.185
163.64
m/sec
am3/hr
sm3/hr
dsm3/hr
METER TEMPERATURE
INLET
(DeqF)
97
92
95
96
98
93
89
90
88
92
93
92
90
95
91
93
94
94
90
96
94
92
95
93
OUTLET
(DeaF)
90
89
90
90
91
89
89
89
86
88
87
85
90
90
88
89
88
89
88
93
90
90
91
89
91
-------
EPA METHOD 5 DATA
RUN NUMBER
KCE-M29-R1
COMPONENT
Probe Wash
Corr. for Blank
Filter
Back Half
TOTAL
ACETONE BLANK
Actual Residue
Actual Blank Corr.
Max. Allowable Res.
Volume
TARE
(grams)
FINAL
(grams)
NET VOLUME
(grams) (ml)
67.07370 67.08480
0.43440 0.97420
0.00000 0.00000
0.00000 grams
0.00000 grams
0.00104 grams
125.0 ml
0.01110 132.0
0.01110
0.53980
0.00000
0.55090
PARTICULATE EMISSIONS
Actual Grain Loading
Corrected to 7% O2
Corrected to 12% CO2
Corrected to 50% Excess Air
Mass Rate
0.11990 gr/dscf
0.21533 gr/dscf @ 7% O2
0.22035 gr/dscf @ 12% CO2
0.21075 gr/dscf <§ 50% EA
4.4132 Ib/hr
SAMPLING QA/QC
Isokinetics
Corrected Meter Volume
107.7 %
70.904 dscf
-------
SUMMARY OF METAL EMISSIONS
RUN NUMBER
SAMPLE VOLUME
TOTAL GAS FLOWRATE
CARBON DIOXIDE %
OXYGEN %
KCB-M29-R1
70.904 dscf
4294.030 dscfm
6.5
13.2
LABORATORY DATA
GAS EMISSIONS
SAMPLE CATCH - micrograms
COMPONENT
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Lead
Manganese
Mercury
Nickel
Phosphorus
Selenium
Sb
As
Be
Cd
Cr
Pb
Mn
Hg
Ni
P
Se
FRONT HALF:
SAMPLE
12.40
106.00
12.40
3.36
65.20
61.80
34.90
65.40
136.00
452.00
371.00
BLANK
0.00
0.00
0.00
0.09
4.20
1.06
1.41
0.00
2.72
0.00
0.00
BACK HALF:
SAMPLE BLANK TOTAL
0.78
2.77
0.00
0.46
2.05
15.80
7.88
19.10
1.27
0.00
0.77
0.00
0.00
0.00
0.05
1.00
0.00
0.59
0.00
1.00
0.00
0.00
13.18
108.77
12.40
3.68
62.05
76.54
40.78
84.50
133.55
452.00
371.77
CONCENTRATION
ACTUAL
uq/Nm3
7.04
58.14
6.63
1.97
33.17
40.91
21.80
45.17
71.38
241.60
198.71
@ 12% CO2
ug/Nm3
12.95
106.84
12.18
3.61
60.95
75.18
40.06
83.00
131.18
443.98
365.17
@7% 02
uq/Nm3
12.65
104.41
11.90
3.53
59.56
73.47
39.14
81.11
128.20
433.88
356.86
MASS
RATE
Ib/hr
1.06E-04
8.71E-04
9.94E-05
2.95E-05
4.97E-04
6.13E-04
3.27E-04
6.77E-04
1.07E-03
3.62E-03
2.98E-03
Front Half - Probe Wash and Filter
Back Half - Impinger Catches
Blank - Field Blank
-------
RUN NUMBER
KCE-M29-R2
DATE
START TIME
END TIME
STACK DIAM.
NOZZLE I.D.
METER BOX GAMMA
METER BOX dH@
BAROMETRIC
Cp
TEST DURATION
SAMPLING RESULTS
Metered Volume
Metered Volume
Volume @ Std.Cond.
Volume @ Std.Cond.
% Water
% Isokinetics
VOLUMETRIC RESULTS -
Velocity
Actual Flow
Std. Flow
Dry Std. Flow
STACK
TEMP STATIC
POINT (DeaF) (in.WC)
1 324 0.15
2 331 0.17
3 333 0.15
4 340 0.16
5 341
6 335
7 335
8 345
9 346
10 341
11 340
12 344
13 321
14 336
15 338
16 341
17 335
18 335
19 325
20 336
21 342
22 331
23 337
24 344
25
AVG. 337 0.16
07/30/92
15:12
17:31
25 X 24
0.3125
1.00624
1.72964
29.97
0.84
120
74.772
2.117
72.097
2.042
10.53
107.7
USENG
29.40
7349
4882
4368
inches
inches
in.Hg
minutes
dcf
dcm
dscf
dscm
%
%
ft/sec
acfm
scfm
dscfm
METHOD 4 DATA
INIT.
(mil
IMP.l 0.0
IMP. 2 100.0
IMP. 3 100.0
IMP. 4 0.0
IMP. 5 100.0
IMP. 6 100.0
IMP. 7
TOTAL 400 . 0
S.G. 200.0
METHOD 3 DATA
%02 12.86
%C02 6 . 34
%CO 0.0
%N2 80.8
O2+CO2 19.2
VOLUMETRIC RESULTS
Velocity
Actual Flow
Std. Flow
Dry Std. Flow
FINAL
(ml)
117.0
138.0
104.0
1.0
104.0
100.0
564.0
216.2
Md
Ms
Ps
Fo
%EA
- SI
8.96
12487
8295
7421
NET
(ml)
117.0
38.0
4.0
1.0
4.0
0.0
0.0
164.0
16.2
29.53
28.32
29.98
1.268
151.81
m/sec
am3/hr
sm3/hr
dsm3/hr
METER METER TEMPERATURE
DP
(in.WC}
0.15
0.16
0.18
0.18
0.20
0.19
0.16
0.16
0.18
0.20
0.18
0.17
0.15
0.16
0.18
0.19
0.19
0.17
0.16
0.22
0.21
0.22
0.18
0.16
0.18
DH
(in.WC)
0.96
1.00
1.15
1.15
1.30
1.20
1.00
1.00
1.15
1.30
1.15
1.10
0.96
1.00
1.15
1.20
1.20
1.10
1.00
1.55
1.40
1.55
1.15
1.00
1.16
VOLUME INLET
(dcf) (DeqF)
682.140 91
92
93
94
95
95
90
93
95
97
97
719.092 98
719.165 90
95
96
100
99
98
97
99
99
98
97
96
756.985
74.772
OUTLET
(DeqF)
90
90
90
91
91
91
89
89
90
92
93
94
89
91
91
92
91
91
90
91
92
91
90
94
93
-------
EPA METHOD 5 DATA
RUN NUMBER
KCE-M29-R2
COMPONENT
Probe Wash
Corr. for Blank
Filter
Back Half
TOTAL
ACETONE BLANK
Actual Residue
Actual Blank Corr.
Max. Allowable Res.
Volume
TARE
(grama)
FINAL
(grama)
67.94350 67.95340
0.44220 1.00630
0.00000 0.00000
0.00000 grams
0.00000 grama
0.00102 grams
125.0 ml
NET
(grams)
VOLUME
(ml)
0.00990 130.0
0.00990
0.56410
0.00000
0.57400
PARTICIPATE EMISSIONS
Actual Grain Loading
Corrected to 7% O2
Corrected to 12% CO2
Corrected to 50% Excess Air
Mass Rate
0.12286 gr/dscf
0.21242 gr/dscf @ 7% O2
0.23255 gr/dacf @ 12% CO2
0.20626 gr/dscf @ 50% EA
4.6001 Ib/hr
SAMPLING QA/QC
Isokinetica
Corrected Meter Volume
107.7 %
72.097 dscf
-------
SUMMARY OF METAL EMISSIONS
RUN NUMBER =
SAMPLE VOLUME =
TOTAL GAS FLOWRATE =
CARBON DIOXIDE % =
OXYGEN % =
KCE-M29-R2
72.097 dacf
4368.014 dscfm
6.3
12.9
LABORATORY DATA
GAS EMISSIONS
SAMPLE CATCH - micrograms
COMPONENT
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Lead
Manganese
Mercury
Nickel
Phosphorus
Selenium
Sb
As
Be
Cd
Cr
Pb
Mn
Hg
Ni
P
Se
FRONT HALF:
SAMPLE
10.90
110.00
13.30
2.73
67.40
56.30
39.00
72.00
142.00
451.00
361.00
BACK HALF:
BLANK
0.00
0.00
0.00
0.09
4.20
1.06
1.41
0.00
2.72
0.00
0.00
SAMPLE
0.00
2.45
0.00
0.37
2.16
23. OO
1.85
3.21
1.51
0.00
0.00
BLANK
0.00
0.00
0.00
0.05
1.00
0.00
0.59
0.00
1.00
0.00
0.00
TOTAL
10.90
112.45
13.30
2.96
64.36
78.24
38.85
75.21
139.79
451.00
361.00
CONCENTRATION
ACTUAL
uq/Nm3
5.73
59.11
6.99
1.56
33.83
41.13
20.42
39.53
73.48
237.07
189.76
@ 12% CO2
ug/Nm3
10.84
111.88
13.23
2.95
64.03
77.84
38.65
74.83
139.08
448.72
359.17
@7% 02
ug/Nm3
9.91
102.19
12.09
2.69
58.49
71.10
35.31
68.35
127.04
409.86
328.07
MASS
RATE
Ib/hr
8.74E-05
9.01E-04
1.07E-04
2.37E-05
5.16E-04
6.27E-04
3.11E-04
6.03E-04
1.12E-03
3.61E-03
2.89E-03
Front Half - Probe Wash and Filter
Back Half - Impinger Catches
Blank - Field Blank
-------
RUN NUMBER
KCE-M29-R3
DATE
START TIME
END TIME
STACK DIAM.
NOZZLE I.D.
METER BOX GAMMA
METER BOX dH@
BAROMETRIC
Cp
TEST DURATION
SAMPLING RESULTS
Metered Volume
Metered Volume
Volume @ Std.Cond.
Volume <§ Std.Cond.
% Water
% Isokinetics
07/31/92
09:05
11:24
24 X 25 inches
0.3125 inches
1.00624
1.72964
30.00 in.Hg
0.84
120 minutes
72.554 dcf
2.055 dcm
71.292 dscf
2.019 dscm
10.46 %
105.9 %
METHOD 4
IMP.l
IMP. 2
IMP. 3
IMP. 4
IMP. 5
IMP. 6
IMP. 7
TOTAL
S.6.
METHOD 3
%02
%CO2
%CO
%N2
O2+CO2
DATA
INIT.
(mil
0.0
100.0
100.0
0.0
100.0
100.0
400.0
200.0
DATA
13.10
6.62
0.0
80.3
19.7
FINAL
(ml)
102.0
147.0
106.0
1.0
105.0
101.0
562.0
214.9
Md
Ms
Ps
Fo
%EA
NET
(ml)
102.0
47.0
6.0
1.0
5.0
1.0
0.0
162.0
14.9
29.58
28.37
30.01
1.178
161.85
VOLUMETRIC RESULTS
Velocity
Actual Flow
USENO VOLUMETRIC RESULTS - SI
29.49 ft/sec Velocity 8.99 m/sec
7373 acfm Actual Flow 12527 am3/hr
Std.
Dry
POINT
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
AV6.
Flow
Std. Flow
STACK
TEMP STATIC
(DeaF) (in. WO
338 0.18
344 0.16
348 0.16
340 0.15
339
342
327
331
338
346
346
347
323
332
332
332
340
343
337
336
335
320
310
339
336 0.17
4905
4392
DP
(in. WO
0.21
0.22
0.24
0.24
0.20
0.20
0.15
0.15
0.16
0.16
0.15
0.15
0.15
0.16
0.18
0.18
0.22
0.24
0.16
0.16
0.18
0.18
0.16
0.16
0.18
scfm
dscfm
DH
(in. WO
1.30
1.35
1.50
1.50
1.25
1.25
0.93
0.93
0.97
0.97
0.93
0.93
0.93
0.97
1.10
1.10
1.35
1.50
0.97
0.97
1.10
1.10
0.97
0.97
1.12
Std. Flow
Dry Std.
METER
VOLUME
(dcf)
757.526
793.726
793.726
830.080
72.554
Flow
8334
7463 i
METER TEMPERATURE
INLET
(DeaFl
70
76
77
80
81
81
77
81
84
87
86
87
84
87
85
86
89
86
89
92
98
94
93
94
OUTLET
(DeaF)
70
74
74
75
76
76
76
79
81
81
81
82
83
83
82
82
83
82
87
89
94
93
88
89
83
-------
EPA METHOD 5 DATA
RUN NUMBER
KCE-M29-R3
COMPONENT
Probe Wash
Corr. for Blank
Filter
Back Half
TOTAL
ACETONE BLANK
Actual Residue
Actual Blank Corr.
Max. Allowable Res.
Volume
TARE
(grams)
FINAL
(grams)
64.32910 64.33800
0.44340 1.04900
0.00000 0.00000
0.00000 grams
0.00000 grams
0.00094 grams
125.0 ml
NET VOLUME
(grams) (ml)
0.00890 120.0
0.00890
0.60560
0.00000
0.61450
PARTICULATE EMISSIONS
Actual Grain Loading
Corrected to 7% O2
Corrected to 12% CO2
Corrected to 50% Excess Air
Mass Rate
0.13302 gr/dscf
0.23705 gr/dscf @ 7% O2
0.24112 gr/dscf @ 12% CO2
0.23221 gr/dscf @ 50% EA
5.0080 Ib/hr
SAMPLING OA/OC
Isokinetics
Corrected Meter Volume
105.9 %
71.292 dscf
-------
SUMMARY OF METAL EMISSIONS
RUN NUMBER
SAMPLE VOLUME
TOTAL GAS FLOWRATE
CARBON DIOXIDE %
OXYGEN %
KCE-M29-R3
71.292 dscf
4392.346 dscfm
6.6
13.1
LABORATORY DATA
GAS EMISSIONS
SAMPLE CATCH - micrograms
COMPONENT
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Lead
Manganese
Mercury
Nickel
Phosphorus
Selenium
Sb
As
Be
Cd
Cr
Pb
Mn
Hg
Ni
P
Se
FRONT HALF:
SAMPLE
11.30
111.00
13.40
1.80
73.10
60.60
36.70
80.10
162.00
471.00
417.00
BACK HALF:
BLANK SAMPLE BLANK
0.00
0.00
0.00
0.09
4.20
1.06
1.41
0.00
2.72
0.00
0.00
0.56
2.05
0.00
0.10
1.85
2.74
3.30
2.00
0.95
0.00
0.78
0.00
0.00
0.00
0.05
1.00
0.00
0.59
0.00
0.95
0.00
0.00
TOTAL
11.86
113.05
13.40
1.76
69.75
62.28
38.00
82.10
159.28
471.00
417.78
CONCENTRATION
ACTUAL
uq/Nm3
6.30
60.10
7.12
0.94
37.08
33.11
20.20
43.64
84.67
250.38
222.09
@ 12% CO2
uo/Nm3
11.43
108.94
12.91
1.70
67.21
60.01
36.62
79.11
153.49
453.87
402.58
@7% O2
ug/Nm3
11.24
107.10
12.69
1.67
66.08
59.00
36.00
77.78
150.89
446.19
395.78
MASS
RATE
Ib/hr
9.67E-05
9.21E-04
1.09E-04
1.43E-05
5.69E-04
5.08E-04
3.10E-04
6.69E-04
1.30E-03
3.84E-03
3.41E-03
Front Half - Probe Wash and Filter
Back Half - Impinger Catches
Blank - Field Blank
-------
APPENDIX D.I.3
DATA AND RESULTS FOR EPA METHOD 26 TESTING
-------
Data and Results for Kiln Combustion Exhaust
Hydrogen Fluoride Testing
RUN NUMBER
DATE
START TIME
END TIME
KCE-M26-R1
07/30/93
12:28
14:44
KCE-M26-R2
07/30/93
15:12
17:31
KCE-M26-R3
07/31/93
09:05
11:24
AVERAGE
SAMPLING DATA
Initial Meter Volume - 1 934.790 1175.340 1420.070 1176.733
Final Meter Volume - 1 1175.070 1415.970 1664.410 1418.483
Net Meter Volume - 1 240.280 240.630 244.340 241.750
Average Meter Temp. - F 112.1 116.6 106.5 111.8
Barometric Pres. - in.Hg 29.97 29.97 30.00 29.98
Avg. Meter Pres. - in.W.C. 2.4 2.4 2.4 2.4
Meter Cal. Factor - Gamma 0.9985 0.9985 0.9985
Corr. Meter Volume - dscf 7.875 7.825 8.096 7.932
Oxygen - %dv* 13.16 12.86 13.10 13.04
GAS FLOWRATE DATA*
Velocity - ft/sec 28.83 29.40 29.49
Actual Volume - acfm 7208 7349 7373
Standard Volume - dscfm 4294 4368 4392
29.24
7310
4351
LABORATORY DATA
Fluoride Analysis
Total Liquid Volume - ml
Floride Cone. - mg/liter
73.0
74.0
68.0
106.0
80.0
259.0
73.7
146.3
HF EMISSIONS
Concentration - ppmdv
Cone. - ppmdv @ 7% O2
Mass Rate - Ib/hr
30.672
55.082
0.410
41.188
71.208
0.561
114.439
203.935
1.566
62.099
110.075
0.846
* Gas flowrate and oxygen content data were taken from EPA Method 29
testing which was conducted concurrently.
-------
APPENDIX D.I.4
DATA AND RESULTS FOR EPA METHOD 25A
AND MODIFIED METHOD 25A TESTING
(THC, METHANE AND ETHANE)
-------
Summary of the Kiln Combustion Exhaust THC and Methane
and Ethane Emissions
RUN I.D.
DATE
TIME STARTED
TIME ENDED
KCE-M25A-R1
07/29/93
08:48
10:48
KCE-M25A-R2
07/29/93
11:38
13:38
KCB-M25A-R3
07/29/93
14:26
15:26
AVERAGE
GAS PARAMETERS*
Gas Temperature - oF
Oxygen - %
Carbon Dioxide - %
Moisture - %
327.5
15.9
4.5
9.58
327.5
15.9
4.5
9.58
336.1
14.7
5.6
8.36
330.4
15.5
4.9
9.17
GAS FLOWRATE*
Velocity - ft/sec
Actual Volume - acfm
Standard Volume - dscfm
29.52
7381
4488
29.52
7381
4488
28.79
7198
4388
29.28
7198
4455
THC EMISSIONS
Cone. - ppmwv (as Propane) 43.50
Cone. - ppmdv (as Propane) 48.11
Cone. - ppmdv (as Carbon) 144.33
Mass Rate - Ib/hr (as Carbon) 1.21
24.45
27.04
81.12
0.68
13.27
14.48
43.44
0.36
27.07
29.88
89.63
0.75
METHANE/ETHANE EMISSIONS**
Cone. - ppmwv (as Propane) 20.98
Cone. - ppmdv (as Propane) 23.20
Cone. - ppmdv (as Carbon) 69.61
Mass Rate - Ib/hr (as Carbon) 0.584
18.11
20.03
60.09
0.504
20.39
22.25
66.75
0.548
19.83
21.83
65.48
0.545
TGNMO EMISSIONS
Mass Rate - Ib/hr (as Carbon) 0.626
0.176
0.401
* Gas parameters and gas flowrate data are taken from KCE-M0010-R1 for
M25A runs 1 and 2 and KCE-M0010-R2 for M25A run 3.
** Methane/Ethane emissions are calculated from the average of two 14-minute
tests; one conducted prior to and one conducted after each of the
individual M25A test runs.
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R1
Starting
07-29-93
Time
08:50
08:51
08:52
08:53
08:54
08:55
08:56
08:57
08:58
08:59
09:00
09:01
09:02
09:03
09:04
09:05
09:06
09:07
09:08
09:09
09:10
09:11
09:12
09:13
09:14
09:15
09:16
09:17
09:18
09:19
09:20
09:21
09:22
09:23
09:24
09:25
09:26
09:27
09:28
THC
PPMWV
56.43
67.11
63.13
54.50
53.14
58.81
64.72
53.72
51.15
51.01
61.82
57.70
50.88
49.92
54.83
66.90
49.81
49.50
49.04
58.37
54.28
47.91
46.80
50.99
56.80
47.99
45.76
49.62
53.77
52.87
46.09
44.63
48.43
54.96
45.89
43.80
42.77
51.77
51.44
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R1
Starting
07-29-93
Time
09:29
09:30
09:31
09:32
09:33
09:34
09:35
09:36
09:37
09:38
09:39
09:40
09:41
09:42
09:43
09:44
09:45
09:46
09:47
09:48
09:49
09:50
09:51
09:52
09:53
09:54
09:55
09:56
09:57
09:58
09:59
10:00
10:01
10:02
10:03
10:04
10:05
10:06
10:07
THC
PPMWV
43.55
42.31
50.64
50.83
45.18
42.81
43.54
51.54
50.85
42.67
42.75
44.83
51.91
44.79
41.57
40.44
46.97
41.46
40.10
39.43
41.12
48.93
42.20
38.69
38.46
46.11
45.25
37.36
35.31
36.38
43.17
37.46
33.40
33.34
40.17
43.31
36.67
36.37
38.61
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R1
Starting
07-29-93
Time
10:08
10:09
10:10
10:11
10:12
10:13
10:14
10:15
10:16
10:17
10:18
10:19
10:20
10:21
10:22
10:23
10:24
10:25
10:26
10:27
10:28
10:29
10:30
10:31
10:32
10:33
10:34
10:35
10:36
10:37
10:38
10:39
10:40
10:41
10:42
10:43
10:44
10:45
10:46
THC
PPMWV
46.97
41.22
37.58
36.98
42.26
45.36
37.34
36.14
35.87
43.74
38.64
34.84
34.71
37.74
40.16
34.19
32.83
33.37
40.00
36.97
33.06
32.40
34.94
38.61
32.65
31.31
31.75
38.24
33.26
31.49
31.36
31.42
33.02
31.48
31.37
31.42
37.28
34.84
31.29
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R1
Starting
07-29-93
Time
10:47
10:48
119 MinAvg
THC
PPMWV
30.49
32.64
43.45
Data Corrected for Calibrations
119 MinAvg 43.50
-------
Calibrations:
VOC 100 Span Value = 100
LOW Calibration Gas = 0.00 HIGH Calibration Gas = 24.58
Initial Cal. at: 744
LOW Cal. Response = 0.11 HIGH Cal. Response = 24.15
Cal. Drift = 0.00 Cal. Drift - -0.00
Final Cal. at: 1111
LOW Cal. Response = 0.98 HIGH Cal. Response = 25.43
Cal. Drift = 0.01 Cal. Drift = 0.01
LOW System Drift = 0.01 HIGH System Drift = 0.01
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R2
Starting
07-29-93
Time
11:40
11:41
11:42
11:43
11:44
11:45
11:46
11:47
11:48
11:49
11:50
11:51
11:52
11:53
11:54
11:55
11:56
11:57
11:58
11:59
12:00
12:01
12:02
12:03
12:04
12 : 05
12:06
12:07
12:08
12:09
12:10
12:11
12:12
12:13
12:14
12:15
12:16
12:17
12:18
THC
PPMWV
28.01
27.98
29.23
31.73
29.05
29.33
30.52
34.38
37.55
31.83
30.71
30.26
35.73
31.98
27.85
27.07
28.41
31.25
26.66
25.09
24.94
29.46
28.56
25.59
26.97
29.34
32.78
28.50
26.43
25.41
30.82
30.15
25.55
25.08
27.76
33.36
27.28
25.72
25.58
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R2
Starting
07-29-93
Time
12:19
12:20
12:21
12:22
12:23
12:24
12:25
12:26
12:27
12:28
12:29
12:30
12:31
12:32
12:33
12:34
12:35
12:36
12:37
12:38
12:39
12:40
12:41
12:42
12:43
12:44
12:45
12:46
12:47
12:48
12:49
12:50
12:51
12:52
12:53
12:54
12:55
12:56
12:57
THC
PPMWV
31.89
30.78
25.54
24.98
27.34
32.12
26.59
24.78
24.75
31.08
30.35
25.68
25.16
26.19
30.84
25.93
24.04
23.74
27.81
27.24
23.49
22.69
23.37
27.23
23.24
21.73
21.62
24.31
24.82
21.78
20.86
21.19
23.74
21.25
19.44
18.86
21.99
22.56
20.06
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R2
Starting
07-29-93
Time
12:58
12:59
13:00
13:01
13:02
13:03
13:04
13:05
13:06
13:07
13:08
13:09
13:10
13:11
13:12
13:13
13:14
13:15
13:16
13:17
13:18
13:19
13:20
13:21
13:22
13:23
13:24
13:25
13:26
13:27
13:28
13:29
13:30
13:31
13:32
13:33
13:34
13:35
13:36
THC
PPMWV
20.21
20.69
24.00
21.84
20.01
20.23
22.33
22.65
20.10
20.35
21.40
25.27
23.44
20.78
20.43
22.34
23.31
21.12
21.07
21.62
23.93
23.20
21.26
20.84
22.26
23.88
20.69
19.70
20.13
22.86
20.99
19.60
20.07
22.49
23.17
20.12
19.50
19.28
23.09
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R2
Starting
07-29-93
Time
13:37
13:38
119 MinAvg
THC
PPMWV
21.66
19.74
25.10
Data Corrected for Calibrations
119 MinAvg 24.45
-------
Calibrations:
VOC 100 Span Value = 100
LOW Calibration Gas = 0.00 HIGH Calibration Gas = 24.58
Initial Cal. at: 1111
LOW Cal. Response = 0.98 HIGH Cal. Response = 25.43
Cal. Drift = 0.01 Cal. Drift = 0.01
Final Cal. at: 1349
LOW Cal. Response = 0.77 HIGH Cal. Response = 25.03
Cal. Drift = 0.01 Cal. Drift = 0.00
LOW System Drift = -0.00 HIGH System Drift = -0.00
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R3
Starting
07-29-93
Time
14:28
14:29
14:30
14:31
14:32
14:33
14:34
14:35
14:36
14:37
14:38
14:39
14:40
14:41
14:42
14:43
14:44
14:45
14:46
14:47
14:48
14:49
14:50
14:51
14:52
14:53
14:54
14:55
14:56
14:57
14:58
14:59
15:00
15:01
15:02
15:03
15:04
15:05
15:06
THC
PPMWV
15.63
15.37
14.88
13.38
13.86
14.51
14.77
14.24
13.32
13.40
13.47
13.17
12.92
13.26
13.31
13.42
13.28
12.92
12.90
13.20
13.52
13.82
13.19
13.06
13.13
12.95
12.29
12.98
13.54
13.65
13.79
13.54
13.89
13.91
14.15
13.71
13.42
14.17
14.35
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R3
Starting
07-29-93
Time
15:07
15:08
15:09
15:10
15:11
15:12
15:13
15:14
15:15
15:16
15:17
15:18
15:19
15:20
15:21
15:22
15:23
15:24
15:25
15:26
60 MinAvg
THC
PPMWV
14.29
14.50
14.27
14.61
14.38
13.82
13.21
13.79
13.82
12.75
12.91
12.94
13.53
13.24
12.34
13.11
13.34
13.48
12.65
12.81
13.59
Data Corrected for Calibrations
60 MinAvg 13.27
-------
Calibrations:
VOC 100 Span Value = 100
LOW Calibration Gas = 0.00 HIGH Calibration Gas = 24.58
Initial Cal. at: 1349
LOW Cal. Response = 0.77 HIGH Cal. Response = 25.03
Cal. Drift = 0.01 Cal. 'Drift = 0.00
Final Cal. at: 1723
LOW Cal. Response = 0.48 HIGH Cal. Response = 24.28
Cal. Drift = 0.00 Cal. Drift = -0.00
LOW System Drift = -0.00 HIGH System Drift = -0.01
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R4
Starting
07-29-93
Time
18:01
18:02
18:03
18:04
18:05
18:06
18:07
18:08
18:09
18:10
18:11
18:12
18:13
18:14
18:15
18:16
18:17
18:18
18:19
18:20
18:21
18:22
18:23
18:24
18:25
18:26
18:27
18:28
18:29
18:30
18:31
18:32
18:33
18:34
18:35
18:36
18:37
18:38
18:39
THC
PPMWV
24.19
22.40
12.60
22.88
-6999.00*
35.03
32.77
27.32
22.20
20.00
19.79
26.95
32.34
37.76
46.90
40.20
27.99
22.56
19.46
17.78
16.52
14.60
14.85
14.83
14.87
13.18
12.90
13.52
13.23
12.73
11.73
12.63
13.04
12.89
12.32
12.22
12.53
12.62
12.02
* Data marked with an * is not included in the average,
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R4
Starting
07-29-93
Time
18:40
18:41
18:42
18:43
18:44
18:45
18:46
18:47
18:48
18:49
18:50
18:51
18:52
18:53
18:54
18:55
18:56
18:57
18:58
18:59
19:00
19:01
19:02
19:03
19:04
19:05
19:06
19:07
19:08
19:09
19:10
19:11
19:12
19:13
19:14
19:15
19:16
19:17
19:18
THC
PPMWV
10.81
11.54
12.18
12.46
11.24
10.88
12.06
11.97
11.33
10.01
14.15
18.86
24.42
31.19
33.88
38.67
42.10
30.48
21.08
17.79
16.73
16.12
14.33
13.32
13.60
13.42
12.98
11.47
12.10
12.39
12.53
12.75
11.69
12.89
12.96
12.36
10.98
11.85
12.66
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R4
Starting
07-29-93
Time
19:19
19:20
19:21
19:22
19:23
19:24
19:25
19:26
19:27
19:28
19:29
19:30
19:31
19:32
19:33
19:34
19:35
19:36
19:37
19:38
19:39
19:40
19:41
19:42
19:43
19:44
19:45
19:46
19:47
19:48
19:49
19:50
19:51
19:52
19:53
19:54
19:55
19:56
19:57
THC
PPMWV
12.44
11.54
10.50
11.98
12.59
12.61
12.40
12.29
12.80
13.29
12.08
11.29
12.29
12.80
12.99
10.96
11.59
13.14
13.17
11.79
10.76
12.39
12.09
12.73
10.19
11.27
12.29
12.40
11.85
10.22
11.52
12.30
12.74
11.14
11.75
12.95
13.14
12.79
10.47
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R4
Starting
07-29-93
Time
19:58
19:59
20:00
20:01
20:02
20:03
20:04
20:05
20:06
20:07
20:08
20:09
20:10
20:11
20:12
20:13
20:14
20:15
20:16
20:17
20:18
20:19
20:20
20:21
20:22
20:23
20:24
20:25
20:26
20:27
20:28
20:29
20:30
20:31
20:32
20:33
20:34
20:35
20:36
THC
PPMWV
12.06
12.66
12.68
10.59
10.91
12.18
12.33
11.69
9.82
11.87
12.27
12.20
9.91
10.28
11.15
11.66
11.02
9.39
10.80
11.24
11.68
9.75
9.69
11.12
11.66
11.63
9.42
10.65
11.83
12.47
12.21
10.80
12.60
13.25
13.18
11.12
12.30
12.88
13.46
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R4
Starting
07-29-93
Time
20:37
20:38
20:39
20:40
20:41
20:42
20:43
20:44
20:45
20:46
20:47
20:48
20:49
20:50
20:51
20:52
20:53
20:54
20:55
20:56
20:57
20:58
20:59
21:00
21:01
21:02
21:03
21:04
21:05
21:06
21:07
21:08
21:09
21:10
21:11
21:12
21:13
21:14
21:15
THC
PPMWV
11.31
10.88
12.82
13.10
13.16
10.20
12.08
13.31
13.57
11.13
10.48
12.50
13.11
12.91
10.45
12.00
13.19
13.20
11.23
10.40
12.02
12.48
12.35
9.51
10.64
11.53
12.39
10.83
9.34
11.24
11.46
11.22
8.77
9.25
10.39
10.92
9.39
7.77
9.54
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R4
Starting
07-29-93
Time
21:16
21:17
21:18
21:19
21:20
21:21
21:22
21:23
21:24
21:25
21:26
21:27
21:28
21:29
21:30
21:31
21:32
21:33
21:34
21:35
21:36
21:37
21:38
21:39
21:40
21:41
21:42
21:43
21:44
21:45
21:46
21:47
21:48
21:49
21:50
21:51
21:52
21:53
21:54
THC
PPMWV
9.90
10.07
9.39
10.10
10.66
10.73
9.30
7.95
9.57
10.04
9.88
7.56
7.76
9.00
9.61
8.55
7.05
8.49
8.79
8.93
7.62
7.43
8.46
8.98
8.66
6.80
8.18
9.06
9.63
7.62
7.79
9.34
9.68
9.21
7.12
9.14
9.74
10.30
8.34
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R4
Starting
07-29-93
Time
21:55
21:56
21:57
21:58
21:59
22:00
22:01
22:02
22:03
22:04
22:05
22:06
22:07
22:08
22:09
22:10
22:11
22:12
22:13
22:14
22:15
22:16
22:17
22:18
22:19
22:20
22:21
22:22
22:23
22:24
22:25
22:26
22:27
22:28
22:29
22:30
270 MinAvg
THC
PPMWV
8.10
10.04
10.55
10.17
7.55
9.82
10.38
10.52
8.51
8.25
10.04
10.76
10.36
7.98
9.39
9.91
10.12
8.30
7.52
9.79
10.28
9.84
6.98
8.69
9.84
10.26
8.30
7.12
9.67
10.19
10.01
6.95
8.79
9.99
10.40
8.37
12.78
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R4
Starting
07-29-93
Time
THC
PPMWV
Data Corrected for Calibrations
270 MinAvg 12.70
-------
Calibrations:
VOC 100 Span Value = 100
LOW Calibration Gas = 0.00 HIGH Calibration Gas = 24.58
Initial Cal. at: 1723
LOW Cal. Response = 0.48 HIGH Cal. Response = 24.28
Cal. Drift = 0.00 Cal. Drift = -0.00
Final Cal. at: 2240
LOW Cal. Response = 0.16 HIGH Cal. Response = 24.62
Cal. Drift = 0.00 Cal. Drift = 0.00
LOW System Drift = -0.00 HIGH System Drift = 0.00
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R5
Starting
07-30-93
Time
09:39
09:40
09:41
09:42
09:43
09:44
09:45
09:46
09:47
09:48
09:49
09:50
09:51
09:52
09:53
09:54
09:55
09:56
09:57
09:58
09:59
10:00
10:01
10:02
10:03
10:04
10:05
10:06
10:07
10:08
10:09
10:10
10:11
10:12
10:13
10:14
10:15
10:16
10:17
THC
PPMWV
15.88
16.14
15.92
14.90
14.43
14.35
15.37
14.81
14.36
15.02
15.27
15.18
14.28
13.53
13.49
13.90
12.95
12.51
12.71
13.66
13.20
12.92
12.50
12.06
12.47
12.40
12.34
11.91
12.12
12.99
12.49
11.75
12.40
13.30
12.10
11.50
11.59
12.95
13.66
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R5
Starting
07-30-93
Time
10:18
10:19
10:20
10:21
10:22
10:23
10:24
10:25
10:26
10:27
10:28
10:29
10:30
10:31
10:32
10:33
10:34
10:35
10:36
ItT:37
10:38
10:39
10:40
10:41
10:42
10:43
10:44
10:45
10:46
10:47
10:48
10:49
10:50
10:51
10:52
10:53
10:54
10:55
10:56
THC
PPMWV
11.25
11.00
11.77
12.56
11.84
11.33
11.19
11.14
11.96
11.23
11.20
10.99
12.40
11.81
11.43
11.15
12.18
12.40
11.58
11.46
10.99
12.02
11.94
11.20
12.14
12.76
12.84
11.12
10.79
10.66
12.46
12.18
11.67
11.81
12.71
14.38
13.08
12.81
12.43
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R5
Starting
07-30-93
Time
10:57
10:58
10:59
11:00
11:01
11:02
11:03
11:04
11:05
11:06
11:07
11:08
11:09
11:10
11:11
11:12
11:13
11:14
11:15
11:16
11:17
11:18
11:19
11:20
11:21
11:22
11:23
11:24
11:25
11:26
11:27
11:28
11:29
11:30
11:31
11:32
11:33
11:34
11:35
THC
PPMWV
13.84
13.54
12.40
12.86
12.67
13.22
12.38
12.52
11.94
12.75
12.66
11.87
11.59
12.27
12.91
11.92
11.66
11.64
13.20
12.84
11.59
11.67
11.74
12.19
10.72
10.06
9.89
10.64
10.62
9.67
9.12
9.15
10.19
9.60
9.28
9.30
9.40
10.17
9.89
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R5
Starting
07-30-93
Time
11:36
11:37
11:38
11:39
11:40
11:41
11:42
11:43
11:44
11:45
11:46
11:47
11:48
11:49
11:50
11:51
11:52
11:53
11:54
11:55
11:56
11:57
11:58
11:59
12:00
12:01
12:02
12:03
12:04
12:05
12:06
12:07
12:08
12:09
12:10
12:11
12:12
12:13
12:14
THC
PPMWV
9.94
9.83
10.70
9.78
9.49
9.58
10.30
10.33
9.40
9.38
10.10
11.78
10.18
9.73
10.49
10.74
10.66
9.08
9.57
10.34
10.81
9.96
10.12
10.12
10.73
10.45
9.33
9.43
9.53
11.34
10.49
9.80
9.86
10.56
11.12
10.10
10.08
10.94
11.35
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R5
Starting
07-30-93
Time
12:15
12:16
12:17
12:18
12:19
12:20
12:21
12:22
12:23
12:24
12:25
12:26
12:27
12:28
12:29
12:30
12:31
12:32
12:33
12:34
12:35
12:36
12:37
12:38
12:39
12:40
12:41
12:42
12:43
12:44
12:45
12:46
12:47
12:48
12:49
12:50
12:51
12:52
12:53
THC
PPMWV
11.30
10.76
10.46
10.64
11.94
11.07
10.76
10.63
12.02
12.19
11.52
11.37
13.04
14.69
12.69
11.42
11.38
11.86
11.03
10.13
10.33
10.75
11.93
10.35
10.59
12.04
12.13
11.01
10.74
10.92
11.17
12.20
11.74
11.26
11.74
12.62
12.25
11.94
11.64
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R5
Starting
07-30-93
Time
12:54
12:55
12:56
12:57
12:58
12:59
13:00
13:01
13:02
13:03
13:04
13:05
13:06
13:07
13:08
13:09
13:10
13:11
13:12
13:13
13:14
13:15
13:16
13:17
13:18
13:19
13:20
13:21
13:22
13:23
13:24
13:25
13:26
13:27
13:28
13:29
13:30
13:31
13:32
THC
PPMWV .
12.13
11.84
11.07
11.09
10.46
10.55
10.42
10.41
10.55
11.10
10.81
10.19
9.77
9.72
9.89
10.03
10.39
10.01
9.71
9.44
9.78
9.92
9.71
9.77
10.33
10.11
9.76
9.85
9.08
9.69
9.53
9.46
9.55
9.58
9.20
8.97
8.79
9.16
9.10
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R5
Starting
07-30-93
Time
13:33
13:34
13:35
13:36
13:37
13:38
13:39
13:40
13:41
13:42
13:43
13:44
13:45
13:46
13:47
13:48
13:49
13:50
13:51
13:52
13:53
13:54
13:55
13:56
13:57
13:58
13:59
14:00
14:01
14:02
14:03
14:04
14:05
14:06
14:07
14:08
14:09
14:10
14:11
THC
PPMWV
8.73
8.90
8.78
8.75
8.88
9.23
9.17
8.65
8.82
8.95
9.14
9.15
9.06
9.54
9.92
9.30
9.49
8.99
8.77
9.16
9.04
9.59
9.16
9.03
9.09
9.48
9.67
8.97
9.15
9.49
8.73
8.48
7.95
8.02
8.80
8.69
8.34
8.27
8.18
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R5
Starting
07-30-93
Time
14:12
14:13
14:14
14:15
14:16
14:17
14:18
14:19
14:20
14:21
14:22
14:23
14:24
14:25
14:26
14:27
14:28
14:29
14:30
14:31
14:32
14:33
14:34
14:35
14:36
14:37
14:38
14:39
14:40
14:41
14:42
14:43
14:44
14:45
14:46
14:47
14:48
14:49
14:50
THC
PPMWV
9.40
9.24
9.46
9.30
9.14
8.58
9.02
8.59
8.57
9.02
9.23
9.40
8.68
8.79
9.09
8.87
8.53
10.95
10.09
9.18
8.51
8.56
8.68
8.88
8.89
8.69
8.73
9.35
8.87
8.54
8.35
8.57
8.94
8.87
8.71
8.45
9.10
8.88
8.44
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R5
Starting
07-30-93
Time
14:51
14:52
14:53
14:54
14:55
14:56
14:57
14:58
14:59
15:00
15:01
15:02
15:03
15:04
15:05
15:06
15:07
15:08
15:09
15:10
15:11
15:12
15:13
15:14
15:15
15:16
15:17
15:18
15:19
15:20
15:21
15:22
15:23
15:24
15:25
15:26
15:27
15:28
15:29
THC
PPMWV
8.84
8.93
9.16
8.76
8.33
8.00
8.07
8.18
7.95
7.74
7.62
8.79
8.60
8.50
8.28
8.87
9.24
8.91
8.40
8.40
8.35
8.13
8.22
8.18
8.83
8.49
8.03
8.65
8.59
9.38
9.06
8.31
8.08
8.34
8.41
8.65
8.60
9.57
8.94
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R5
Starting
07-30-93
Time
15:30
15:31
15:32
15:33
15:34
15:35
15:36
15:37
15:38
15:39
15:40
15:41
15:42
15:43
15:44
15:45
15:46
15:47
15:48
15:49
15:50
15:51
15:52
15:53
15:54
15:55
15:56
15:57
15:58
15:59
16:00
16:01
16:02
16:03
16:04
16:05
16:06
16:07
16:08
THC
PPMWV
8.44
8.64
8.27
8.61
9.06
9.16
9.03
8.86
9.33
8.46
8.53
8.61
8.87
8.77
8.10
8.17
8.44
8.81
8.42
8.46
7.68
7.76
8.60
8.36
8.12
8.17
9.31
8.66
7.88
8.09
9.56
9.08
8.87
8.79
8.60
8.64
8.34
7.97
7.68
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R5
Starting
07-30-93
Time
16:09
16:10
16:11
16:12
16:13
16:14
16:15
16:16
16:17
16:18
16:19
16:20
16:21
16:22
16:23
16:24
16:25
16:26
16:27
16:28
16:29
16:30
16:31
16:32
16:33
16:34
16:35
16:36
16:37
16:38
16:39
16:40
16:41
16:42
16:43
16:44
16:45
16:46
16:47
THC
PPMWV
7.91
8.25
8.00
8.06
8.07
8.78
8.35
7.91
8.05
8.53
9.43
8.45
8.25
8.31
8.77
8.30
8.44
8.09
8.33
9.21
8.44
7.72
8.30
8.80
8.48
7.51
7.50
7.50
8.71
7.35
7.79
7.28
7.84
7.97
7.49
7.72
7.63
8.57
7.75
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R5
Starting
07-30-93
Time
16:48
16:49
16:50
16:51
16:52
16:53
16:54
16:55
16:56
16:57
16:58
16:59
17:00
17:01
17 : 02
17:03
17:04
17:05
17:06
17:07
17:08
17:09
17:10
17:11
17:12
17:13
17:14
17:15
17:16
17:17
17:18
17:19
17:20
17:21
17:22
17:23
17:24
17:25
17:26
THC
PPMWV
7.79
7.83
7.91
8.72
7.79
7.46
7.20
8.21
8.04
8.14
7.83
8.63
8.41
7.83
7.94
9.07
9.50
8.53
8.37
7.81
8.22
8.59
7.81
7.54
7.16
7.93
7.46
7.22
7.63
8.15
7.99
7.22
7.08
6.91
7.59
7.54
7.61
7.14
7.79
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Total Hydrocarbons
KSO-M25A-R5
Starting
07-30-93
Time
17:27
17:28
17:29
17:30
17:31
17:32
17:33
17:34
17:35
17:36
17:37
17:38
17:39
17:40
17:41
17:42
17:43
17:44
17:45
17:46
17:47
17:48
17:49
491 MinAvg
THC
PPMWV
7.83
6.72
6.42
6.35
8.07
7.35
6.91
6.92
8.01
9.22
7.47
7.73
7.61
7.87
8.43
7.60
7.20
7.68
8.16
7.29
7.13
6.73
6.11
9.84
Data Corrected for Calibrations
491 MinAvg 9.61
-------
Calibrations:
VOC 100 Span Value = 100
LOW Calibration Gas = 0.00 HIGH Calibration Gas = 24.58
Initial Cal. at: 846
LOW Cal. Response = 0.04 HIGH Cal. Response = 24.82
Cal. Drift = 0.00 Cal. Drift - 0.00
Final Cal. at: 1751
LOW Cal. Response = 0.09 HIGH Cal. Response = 25.29
Cal. Drift = 0.00 Cal. Drift = 0.01
LOW System Drift = 0.00 HIGH System Drift = 0.00
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Methane/Ethane
RUN 1
Starting
07-29-93
Time
08:32
08:33
08:34
08:35
08:36
08:37
08:38
08:39
08:40
08:41
08:42
08:43
08:44
08:45
14 MinAvg
Meth/Eth
PPMWV
11.28
15.35
14.30
15.21
16.32
30.65
40.75
33.07
30.39
30.95
37.98
30.47
29.75
29.35
26.13
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Methane/Ethane
RUN 2
Starting
07-29-93
Time
11:19
11:20
11:21
11:22
11:23
11:24
11:25
11:26
11:27
11:28
11:29
11:30
11:31
11:32
11:33
14 MinAvg
Meth/Eth
PPMWV
10.70
12.53
13.50
12.87
14.36
14.46
16.37
15.34
14.94
15.50
16.65
17.14
15.88
15.75
15.63
15.83
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Methane/Ethane
RUN 3
Starting
07-29-93
Time
13:55
13:56
13:57
13:58
13:59
14:00
14:01
14:02
14:03
14:04
14:05
14:06
14:07
14 MinAvg
Meth/Eth
PPMWV
8.55
9.23
10.29
11.65
13.35
12.59
12.43
12.59
14.48
14.78
13.27
13.07
12.94
20.39
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Methane/Ethane
RUN 4
Starting
07-29-93
Time
17:46
17:47
17:48
17:49
17:50
17:51
17:52
17:53
17:54
17:55
17:56
17:57
17:58
17:59
14 MinAvg
Meth/Eth
PPMWV
9.93
9.54
9.57
9.68
9.38
8.57
8.82
8.78
-6999.00*
-6999.00*
-6999.00*
65.30
46.93
37.76
20.39
* Data marked with an * is not included in the average.
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Methane/Ethane
RUN 5
Starting
07-29-93
Time
22:46
22:47
22:48
22:49
22:50
22:51
22:52
22:53
22:54
22:55
22:56
22:57
22:58
22:59
14 MinAvg
Meth/Eth
PPMWV
5.53
5.31
5.57
5.18
5.69
6.00
6.36
5.99
5.75
6.48
7.07
7.25
6.78
7.05
6.14
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Methane/Ethane
RUN 6
Starting
07-30-93
Time
09:19
09:20
09:21
09:22
09:23
09:24
09:25
09:26
09:27
09:28
09:29
09:30
09:31
09:32
14 MinAvg
Meth/Eth
PPMWV
5.34
4.93
6.09
6.95
6.90
6.95
7.14
7.61
8.63
7.94
8.02
8.26
8.91
8.54
7.30
-------
EPA Brick WA 14
Kiln Combustion Exhaust
Methane/Ethane
RUN 7
Starting
07-30-93
Time
17:57
17:58
17:59
18:00
18:01
18:02
18:03
18:04
18:05
18:06
18:07
18:08
18:09
18:10
14 MinAvg
Meth/Eth
PPMWV
3.09
4.19
3.59
3.04
3.29
3.42
4.79
3.91
3.63
3.76
4.40
4.46
3.64
3.64
3.77
-------
EPA Brick WA 14
Bias Check Report
Starting
07-28-93
Time
12:11
12:12
12:13
12:14
12:15
THC
PPMWV
0.74B
14.63
25.41
25.45
25.27B
-------
EPA Brick WA 14
Bias Check Report
Starting
07-28-93
Time
13:47
13:48
13:49
13:50
THC
PPMWV
0.70B
17.45
25.10
24.93B
-------
EPA Brick WA 14
Bias Check Report
Starting
07-28-93
Time
15:24
15:25
15:26
THC
%
PPMWV
0.70B
13.06
24.90B
-------
EPA Brick WA 14
Calibration Report
Starting
07-28-93
Time
10:30
10:31
10:32
10:33
10:34
10:35
10:36
10:37
10:38
10:39
10:40
10:41
THC
PPMWV
-0.01C
-0.02
8.58
86. IOC
76.80
86.10
63.78
55.50C
55.47
35.45
24.85
24.83C
-------
EPA Brick WA 14
Calibration Report
Starting
07-29-93
Time
07:32
07:33
07:34
07:35
07:36
07:37
07:38
07:39
07:40
07:41
07:42
07:43
07:44
THC
PPMWV
0.01C
15.00
84.60
85.60
86.10
86.00C
86.00
79.90
54.61C
54.63
53.88
32.10
24.15C
-------
EPA Brick WA 14
Calibration Report
Starting
07-29-93
Time
16:11
16:12
16:13
16:14
16:15
16:16
16:17
16:18
16:19
16:20
16:21
16:22
16:23
16:24
16:25
16:26
16:27
16:28
THC
%
PPMWV
0.04C
-0.50
-0.08
0.48
19.42
68.74
86.10
86. IOC
70.10
55.80
55.80
55.81C
55.80
53.92
26.81
24.95
24.88
24.86C
-------
EPA Brick WA 14
Calibration Report
Starting
07-30-93
Time
08:37
08:38
08:39
08:40
08:41
08:42
08:43
08:44
08:45
08:46
THC
%
PPMWV
0.04C
-0.05
0.50
82.00
86.00C
74.40
38.47
55.92C
23.44
24.82C
-------
EPA Brick WA 14
Calibration Report
Starting
07-30-93
Time
08:37
08:38
08:39
08:40
08:41
08:42
08:43
08:44
08:45
08:46
02
%
DV
20.37
20.38
20.38
20.38
20.38
20.39
20.39
20.38
20.38
20.38
C02
%
DV
2.54
2.53
2.51
2.50
2.49
2.47
2.46
2.44
2.43
2.42
CO
PPMDV
1.31
1.50
1.39
1.58
1.45
1.43
1.41
1.40
1.29
1.26
NOX
PPMDV
-3.37
-3.36
-3.37
-3.35
-3.36
-3.36
-3.36
-3.36
-3.36
-3.36
-------
APPENDIX D.I.5
DATA AND RESULTS FOR EPA METHOD 0030 TESTING
-------
SUMMARY OF EPA M0030 TESTING
KILN COMBUSTION EXHAUST
RUN I.D.
DATE
START TIME
END TIME
KCE-M0030-R1
07/29/93
09:23
12:50
KCE-M0030-R2
07/29/93
14:12
17:49
KCE-M0030-R3
07/29/93
08:15
11:33
AVERAGE
POLLUTANT CONCENTRATION - Ib/hr
Chloromethane
Vinyl Chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1,1-Dichloroethene
Carbon disulfide
Acetone
Methylene chloride
trans-l,2-Dichloroethene
1,1-Dichloroethane
cis-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Vinyl acetate
2-Butanone
1,1,1-Trichloroethane
Carbon tetrachloride
Benzene
Trichloroethene
1,2-Dichloropropane
Bromodichloromethane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Dibromochloromethane
Bromoform
4-Methyl-2-pentanone
Toluene
Tetrachloroethene
2-Hexanone
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylene
Styrene
1,1,2,2-Tetrachloroethane
*
<
*
<
*
<
<
<
<
<
<
*
<
<
*
<
<
<
<
<
<
<
<
<
*
<
<
*
<
<
6.85E-04 <
1.30E-06 <
1.45E-04
6.65E-05
4.54E-05 *
6.11E-06 *
6.52E-07 *
6.09E-03 *
1.57E-05
6.52E-07 <
6.52E-07 <
6.52E-07 <
6.52E-07 <
6.52E-07 <
6.52E-07 <
1.89E-03 *
6.52E-07 <
6.52E-07 <
1.97E-03 *
6.52E-07 <
6.52E-07 <
6.52E-07 <
6.52E-07 <
6.52E-07 <
1.30E-06 <
6.52E-07 <
1.30E-06 <
2.61E-06 <
2.05E-03 *
6.52E-07 <
5.22E-06 <
1.60E-04
1.77E-04
1.20E-03
4.11E-04
6.52E-07 <
1.30E-06 <
6.29E-04 *
1.33E-06 <
1.56E-04
6.77E-05
2.29E-05 *
5.09E-06
2.21E-05 *
2.58E-03 *
0. OOE+00
6.63E-07 <
6.63E-07 <
6.63E-07 <
6.63E-07 <
6.63E-07 <
6.63E-07 <
1.72E-03 *
6.63E-07 <
6.63E-07 <
1.87E-03 *
6.63E-07 <
6.63E-07 <
6.63E-07 <
6.63E-07 <
6.63E-07 <
1.10E-06 <
6.63E-07 <
1.33E-06 <
3.09E-06 <
1.55E-03 *
6.63E-07 <
5.52E-06 <
1.60E-04
1.23E-04
7.94E-04
2.78E-04
6.63E-07 <
1.77E-06 <
1.11E-03
1.76E-06
1.69E-04
9.19E-05
1.99E-04
8.79E-05
2.25E-05
4.78E-03
0. OOE+00
6.60E-07
6.60E-07
6.60E-07
6.60E-07
6.60E-07
6.60E-07
1.34E-03
3.37E-04
6.60E-07
1.84E-03
6.60E-07
6.60E-07
6.60E-07
6.60E-07
6.60E-07
1.10E-06
6.60E-07
1.76E-06
3.08E-06
1.33E-03
6.60E-07
5.50E-06
9.41E-05
1.17E-04
6.07E-04
2.37E-04
6.60E-07
1.76E-06
< 8.09E-04
< 1.46E-06
1.57E-04
7.53E-05
* 8.90E-05
* 3.30E-05
< 1.51E-05
* 4.49E-03
5.24E-06
< 6.58E-07
< 6.58E-07
< 6.58E-07
< 6.58E-07
< 6.58E-07
< 6.58E-07
* 1.65E-03
< 1.13E-04
< 6.58E-07
* 1.89E-03
< 6.58E-07
< 6.58E-07
< 6.58E-07
< 6.58E-07
< 6.58E-07
< 1.17E-06
< 6.58E-07
< 1.46E-06
< 2.93E-06
* 1.64E-03
< 6.58E-07
< 5.41E-06
1.38E-04
1.39E-04
* 8.66E-04
3.09E-04
< 6.58E-07
< 1.61E-06
Notes:
The emission values for each run represent the average of two pairs of
VOST tube analyses.
< Not detected
* Detected but below the quantitation limit; quantity is estimated
-------
SUMMARY OF EPA MO030 TESTING
KILN COMBUSTION EXHAUST
RUN I.D.
DATE
KCE-M0030-R1A
07/29/93
KCE-M0030-R1B AVERAGE
07/29/93
POLLUTANT CONCENTRATION - Ib/hr
Chloromethane *
Vinyl Chloride <
Bromomethane
Chloroethane
Trichlorofluoromethane
1,1-Dichloroethene *
Carbon disulfide <
Acetone *
Methylene chloride
trans-l,2-Dichloroethene <
1,1-Dichloroethane <
cis-l,2-Dichloroethene <
Chloroform <
1,2-Dichloroethane <
Vinyl acetate <
2-Butanone *
1,1,l-Trichloroethane <
Carbon tetrachloride <
Benzene *
Trichloroethene <
1,2-Dichloropropane <
Bromodichloromethane <
cis-l,3-Dichloropropene <
trans-1,3-Dichloropropene <
1,1,2-Trichloroethane <
Dibromochloromethane <
Bromoform <
4-Methyl-2-pentanone <
Toluene *
Tetrachloroethene <
2-Hexanone <
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylene
Styrene <
1,1,2,2-Tetrachloroethane <
1,
7,
9.16E-04
1.72E-06
,40E-04
.14E-05
3.36E-05
6.03E-06
8.61E-07
1.03E-02
O.OOE+00
8.61E-07
8.61E-07
8.61E-07
8.61E-07
8.61E-07
8.61E-07
2.31E-03
8.61E-07
8.61E-07
2.32E-03
8.61E-07
8.61E-07
8.61E-07
8.61E-07
8.61E-07
1.72E-06
8.61E-07
1.72E-06
44E-06
00E-03
8.61E-07
6.89E-06
1.64E-04
.88E-04
,06E-03
.93E-04
8.61E-07
1.72E-06
3
2
1.
1.
3,
*
<
*
<
*
<
<
<
<
<
<
*
<
<
*
<
<
<
<
<
<
<
<
<
*
<
<
*
<
<
4.
8.
1.
6.
5.
6.
4.
1.
3.
4.
4.
4.
4.
4.
4.
1.
4.
4.
1.
4.
4.
4.
4.
4.
8.
4.
8.
1.
2.
4.
3.
1.
1.
1.
4.
4.
8.
55E-04
86E-07
51E-04
16E-05
71E-05
20E-06
43E-07
92E-03
15E-05
43E-07
43E-07
43E-07
43E-07
43E-07
43E-07
46E-03
43E-07
43E-07
63E-03
43E-07
43E-07
43E-07
43E-07
43E-07
86E-07
43E-07
86E-07
77E-06
10E-03
43E-07
54E-06
56E-04
67E-04
33E-03
29E-04
43E-07
86E-07
*6.85E-04
<1.30E-06
1.45E-04
6.65E-05
4.54E-05
*6.11E-06
<6.52E-07
*6.09E-03
1.57E-05
<6.52E-07
<6.52E-07
<6.52E-07
<6.52E-07
<6.52E-07
<6.52E-07
*1.89E-03
<6.52E-07
<6.52E-07
*1.97E-03
<6.52E-07
<6.52E-07
<6.52E-07
<6.52E-07
<6.52E-07
<1.30E-06
<6.52E-07
<1.30E-06
<2.61E-06
*2.05E-03
<6.52E-07
<5.22E-06
1.60E-04
1.77E-04
*1.20E-03
4.11E-04
<6.52E-07
<1.30E-06
< Not detected
* Detected but below the quantitation limit; quantity is
estimated
-------
PRELIMINARY
VOST SAMPLING DATA AND RESULTS
Run I . D .
KCE-M0030-R1A
KCE-M0030-R1B
KCE-M0030-R1C
KCE-M0030-R1D
KCE-M0030-R1E
KCE-M0030-R1P
KCE-M0030-R1
Date
07/29/93
07/29/93
07/29/93
07/29/93
07/29/93
07/29/93
Start
Time
09:23
09:58
10:28
11:27
12:00
12:30
End
Time
09:43
10:18
10:48
11:47
12:20
12:50
Meter
Temp.
(Fo)
96.0
105.0
111.0
110.0
112.5
113.5
Meter
Press.
fin. we)
1.0
2.1
1.0
2.1
1.0
2.1
Bar.
Press.
(in. Ha)
30.00
30.00
30.00
30.00
30.00
30.00
Initial
Meter
Volume
(liters)
263.320
284.610
325.690
363.430
404.440
426.740
Final
Meter
Volume
(liters)
283.790
324.920
345.690
403.970
424.440
466.760
Sample
Volume
(liters)
20.470
40.310
20.000
40.540
20.000
40.020
Corrected
Sample
Volume
(dscm)
0.0195
0.0379
0.0186
0.0378
0.0185
0.0371
-------
ANALYTICAL DATA AND RESULTS FOR ORGANIC SAMPLING
RUN I.D.
DATE
START TIME
END TIME
CORR. SAMPLE VOL.
VOLUMETRIC FLOWRATE
SAMPLE I.D.
KCE-M0030-R1A
07/29/93
09:23
09:43
0.020 dscm
4488 dscmf1
600/602
GAS EMISSIONS
POLLUTANT
(a)
SAMPLE
Uq
* 1.083 *
< 0.002 <
0.163 <
0.083 <
0.058 *
* 0.007 <
< 0.001 <
*11.932 <
0.070
< 0.001 <
< 0.001 <
< 0.001 <
< 0.001 <
< 0.001 <
< 0.001 <
* 2.688 <
< 0.001 <
< 0.001 <
* 2.693 <
< 0.001 <
< 0.001 <
< 0.001 <
< 0.001 <
< 0.001 <
< 0.002 <
< 0.001 <
< 0.002 <
< 0.004 <
* 2.333 *
< 0.001 <
< 0.008 <
0.190 <
0.218 <
1.236 <
0.457 <
< 0.001 <
< 0.002 <
(b)
BLANK
Uq
0.019 *
0.002 <
0.002
0.003
0.019
0.001 *
0.001 <
0.011 *
0.299
0.001 <
0.001 <
0.001 <
0.001 <
0.001 <
0.001 <
0.035 *
0.001 <
0.001 <
0.001 *
0.001 <
0.001 <
0.001 <
0.001 <
0.001 <
0.001 <
0.001 <
0.002 <
0.004 <
0.015 *
0.001 <
0.007 <
0.001
0.001
0.001
0.001
0.001 <
0.002 <
(a-b)
TOTAL**
uq
1.064 *
0.002 <
0.163
0.083
0.039
0.007 *
0.001 <
11.932 *
0.000
0.001 <
0.001 <
0.001 <
0.001 <
0.001 <
0.001 <
2.688 *
0.001 <
0.001 <
2.693 *
0.001 <
0.001 <
0.001 <
0.001 <
0.001 <
0.002 <
0.001 <
0.002 <
0.004 <
2.318 *
0.001 <
0.008 <
0.190
0.218
1.236
0.457
0.001 <
0.002 <
CONC.
ACTUAL
ug/Nm3
58.469 *
0.110 <
8.957
4.561
2.143
0.385 *
0.055 <
655.691 *
0.000
0.055 <
0.055 <
0.055 <
0.055 <
0.055 <
0.055 <
147.712 *
0.055 <
0.055 <
147.987 *
0.055 <
0.055 <
0.055 <
0.055 <
0.055 <
0.110 <
0.055 <
0.110 <
0.220 <
127.380 *
0.055 <
0.440 <
10.441
11.980
67.921
25.113
0.055 <
0.110 <
MASS
RATE
Ib/hr
9.16E-04
1.72E-06
1.40E-04
7.14E-05
3.36E-05
6.03E-06
8.61E-07
1.03E-02
O.OOE+00
8.61E-07
8.61E-07
8.61E-07
8.61E-07
8.61E-07
8.61E-07
2.31E-03
8.61E-07
8.61E-07
2.32E-03
8.61E-07
8.61E-07
8.61E-07
8.61E-07
8.61E-07
1.72E-06
8.61E-07
1.72E-06
3.44E-06
2.00E-03
8.61E-07
6.89E-06
1.64E-04
1.88E-04
1.06E-03
3.93E-04
8.61E-07
1.72E-06
Chloromethane
Vinyl Chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1,1-Dichloroethene
Carbon disulfide
Acetone
Methylene chloride
trans-1,2-Dichloroethene
1,1-Dichloroethane
cis-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Vinyl acetate
2-Butanone
1,1,1-Trichloroethane
Carbon tetrachloride
Benzene
Trichloroethene
1,2-Dichloropropane
Bromodichloromethane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Dibromochloromethane
Bromoform
4-Methyl-2-pentanone
Toluene
Tetrachloroethene
2-Hexanone
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylene
Styrene
1,1,2,2-Tetrachloroethane
< Not detected
* Detected but below the quantitation limit; quantity is estimated
**If Blank(ug) Not Detected, then TOTAL(ug) = SAMPLE(ug); if
BLANK(ug) > SAMPLE(ug), the TOTAL(ug) = 0.00
1 Flowrate is from KCE-M0010-R1.
-------
ANALYTICAL DATA AND RESULTS FOR ORGANIC SAMPLING
RUN I.D.
KCE-M0030-R1B
DATE
START TIME
END TIME
CORK. SAMPLE VOL.
VOLUMETRIC FLOWRATE
SAMPLE I.D.
07/29/93
09:58
10:18
0.038 dscm
4488 dscmf1
603/605
POLLUTANT
(a)
SAMPLE
GAS EMISSIONS
(b) (a-b) CONC.
BLANK TOTAL** ACTUAL
ua ug
*
<
*
<
*
<
<
<
<
<
<
*
<
<
*
<
<
<
<
«
<
<
<
<
*
<
<
*
<
><
1
0
0
0
0
0
0
4
0
0
0
0
0
0
0
3
0
0
3
0
0
0
0
0
0
0
0
0
4
0
0
0
0
2
0
0
0
.046 *
.002 <
.340 <
.139 <
.148 *
.014 <
.001 <
.329 <
.370
.001 <
.001 <
.001 <
.001 <
.001 <
.001 <
.292 <
.001 <
.001 <
.676 <
.001 <
.001 <
.001 <
.001 <
.001 <
.002 <
.001 <
.002 <
.004 <
.746 *
.001 <
.008 <
.353 <
.376 <
.999 <
.968 <
.001 <
.002 <
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
019 *
002 <
002
003
019
001 *
001 <
Oil *
299
001 <
001 <
001 <
001 <
001 <
001 <
035 *
001 <
001 <
001 *
001 <
001 <
001 <
001 <
001 <
001 <
001 <
002 <
004 <
015 *
001 <
007 <
001
001
001 *
001
001 <
002 <
u<
1
0
0
0
0
0
0
4
0
0
0
0
0
0
0
3
0
0
3
0
0
0
0
0
0
0
0
0
4
0
0
0
0
2
0
0
0
a uq/Ntn3
.027 *
.002 <
.340
.139
.129
.014 *
.001 <
.329 *
.071
.001 <
.001 <
.001 <
.001 <
.001 <
.001 <
.292 *
.001 <
.001 <
.676 *
.001 <
.001 <
.001 <
.001 <
.001 <
.002 <
.001 <
.002 <
.004 <
.731 *
.001 <
.008 <
.353
.376
.999 *
.968
.001 <
.002 <
29
0
9
3
3
0
0
122
2
0
0
0
0
0
0
93
0
0
103
0
0
0
0
0
0
0
0
0
133
0
0
9
10
84
27
0
0
.045
.057
.616
.931
.648
.396
.028
.429
.008
.028
.028
.028
.028
.028
.028
.102
.028
.028
.962
.028
.028
.028
.028
.028
.057
.028
.057
.113
.799
.028
.226
.983
.634
.815
.376
.028
.057
* 4
< 8
1
6
5
* 6
< 4
* 1
3
< 4
< 4
< 4
< 4
< 4
< 4
* 1
< 4
< 4
* 1
< 4
< 4
< 4
< 4
< 4
< 8
< 4
< 8
< 1
* 2
< 4
< 3
1
1
* 1
4
< 4
< 8
MASS
RATE
Ib/hr
.55E-04
.86E-07
.51E-04
.16E-05
.71E-05
.20E-06
.43E-07
.92E-03
.15E-05
.43E-07
.43E-07
.43E-07
.43E-07
.43E-07
.43E-07
.46E-03
.43E-07
.43E-07
.63E-03
.43E-07
.43E-07
.43E-07
.43E-07
.43E-07
.86E-07
.43E-07
.86E-07
.77E-06
.10E-03
.43E-07
.54E-06
.56E-04
.67E-04
.33E-03
.29E-04
.43E-07
.86E-07
Chloromethane
Vinyl Chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1,1-Dichloroethene
Carbon disulfide
Acetone
Methylene chloride
trans-1,2-Dichloroethene
1,1-Dichloroethane
cis-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Vinyl acetate
2-Butanone
1,1,1-Trichloroethane
Carbon tetrachloride
Benzene
Trichloroethene
1,2-Dichloropropane
Bromodichloromethane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene<
1,1,2-Trichloroethane
Dibromochloromethane
Bromoform
4-Methyl-2-pentanone
Toluene
Tetrachloroethene
2-Hexanone
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylene
Styrene
l,l,2,2-Tetrachloroethane< 0.002
< Not detected
* Detected but below the quantitation limit; quantity is estimated
**If Blank(ug) Not Detected, then TOTAL(ug) = SAMPLE(ug); if
BLANK(ug) > SAMPLE(ug), the TOTAL(ug) = 0.00
1 Flowrate is from KCE-M0010-R1.
-------
SUMMARY OF EPA M0030 TESTING
KILN COMBUSTION EXHAUST
RUN I.D.
DATE
KCE-M0030-R2E KCE-M0030-R2F
07/29/93 07/29/93
AVERAGE
POLLUTANT CONCENTRATION - lb/hr
Chloromethane * 4.80E-04
Vinyl Chloride < 8.88E-07
Bromomethane 1.70E-04
Chloroethane 5.68E-05
Trichlorofluoromethane * 0.OOE+00
1,1-Dichloroethene * 4.00E-06
Carbon disulfide * 1.95E-05
Acetone * 2.31E-03
Methylene chloride * 0.OOE+00
trans-l,2-Dichloroethene < 4.44E-07
1,1-Dichloroethane < 4.44E-07
cis-l,2-Dichloroethene < 4.44E-07
Chloroform < 4.44E-07
1,2-Dichloroethane < 4.44E-07
Vinyl acetate < 4.44E-07
2-Butanone * 1.92E-03
1,1,1-Trichloroethane < 4.44E-07
Carbon tetrachloride < 4.44E-07
Benzene * 1.39E-03
Trichloroethene < 4.44E-07
1,2-Dichloropropane < 4.44E-07
Bromodichloromethane < 4.44E-07
cis-l,3-Dichloropropene < 4.44E-07
trans-l,3-Dichloropropene < 4.44E-07
1,1,2-Trichloroethane < 4.44E-07
Dibromochloromethane < 4.44E-07
Bromoform < 8.88E-07
4-Methyl-2-pentanone < 1.78E-06
Toluene * 1.51E-03
Tetrachloroethene < 4.44E-07
2-Hexanone < 3.11E-06
Chlorobenzene 1.56E-04
Ethylbenzene 1.16E-04
m-/p-Xylene 8.52E-04
o-Xylene 2.77E-04
Styrene < 4.44E-07
1,1,2,2-Tetrachloroethane < 8.88E-07
< Not detected
* Detected but below the quantitation limit; quantity is
estimated
<
<
*
*
*
*
<
<
<
<
<
<
*
<
<
*
<
<
<
<
<
<
<
<
<
*
<
<
<
<
7.78E-04
1.76E-06
1.42E-04
7.85E-05
4.59E-05
6.17E-06
2.47E-05
2.86E-03
0. OOE+00
8.82E-07
8.82E-07
8.82E-07
8.82E-07
8.82E-07
8.82E-07
1.52E-03
8.82E-07
8.82E-07
2.36E-03
8.82E-07
8.82E-07
8.82E-07
8.82E-07
8.82E-07
1.76E-06
8.82E-07
1.76E-06
4.41E-06
1.58E-03
8.82E-07
7.94E-06
1.65E-04
1.30E-04
7.35E-04
2.79E-04
8.82E-07
2.65E-06
* 6.29E-04
< 1.33E-06
1.56E-04
6.77E-05
* 2.29E-05
* 5.09E-06
* 2.21E-05
* 2.58E-03
* 0. OOE+00
< 6.63E-07
< 6.63E-07
< 6.63E-07
< 6.63E-07
< 6.63E-07
< 6.63E-07
* 1.72E-03
< 6.63E-07
< 6.63E-07
* 1.87E-03
< 6.63E-07
< 6.63E-07
< 6.63E-07
< 6.63E-07
< 6.63E-07
< 1.10E-06
< 6.63E-07
< 1.33E-06
< 3.09E-06
* 1.55E-03
< 6.63E-07
< 5.52E-06
1.60E-04
1.23E-04
7.94E-04
2.78E-04
< 6.63E-07
< 1.77E-06
-------
PRELIMINARY
VOST SAMPLING DATA AND RESULTS
Run I.D.
KCE-M0030-R2A
KCE-M0030-R2B
KCE-M0030-R2G
KCE-M0030-R2D
KCE-M0030-R2E
KCE-M0030-R2F
KCE-M0030-R2
Date
07/29/93
07/29/93
07/29/93
07/29/93
07/29/93
07/29/93
Start
Time
14:12
14:49
17:29
15:48
16:34
17:01
End
Time
14:32
15:09
17:49
16:08
16:54
17:21
Meter
Temp.
(Fo)
113.5
114.0
116.0
118.0
116.0
115.0
Meter
Press.
(in. we)
1.0
2.1
2.1
1.0
2.1
1.0
Bar.
Press.
Un. Ha)
30.00
30.00
30.00
30.00
30.00
30.00
Initial
Meter
Volume
(liters)
528.960
549.680
677.640
593.800
614.230
655.980
Final
Meter
Volume
(liters)
548.960
589.850
717.900
613.930
654.320
676.180
Sample
Volume
(liters)
20.000
40.170
40.260
20.130
40.090
20.200
Corrected
Sample
Volume
(dscm)
0.0185
0.0372
0.0372
0.0185
0.0370
0.0186
-------
ANALYTICAL DATA AND RESULTS FOR ORGANIC SAMPLING
RUN I.D.
DATE
START TIME
END TIME
CORR. SAMPLE VOL.
VOLUMETRIC FLOWRATE
SAMPLE I.D.
KCE-M0030-R2E
POLLUTANT
07/29/93
16:34
16:54
0.037 dscm
4388 dscfm1
630/632
GAS EMISSIONS
(a) (b) (a-b) CONC.
SAMPLE BLANK TOTAL** ACTUAL
up ug
*
<
*
*
*
*
*
<
<
<
<
<
<
*
<
<
*
<
<
<
<
te <
<
<
<
<
*
<
<
<
ie <
1
0
0
0
0
0
0
5
0
0
0
0
0
0
0
4
0
0
3
0
0
0
0
0
0
0
0
0
3
0
0
0
0
1
0
0
0
.101 *
.002 <
.382 <
.128 <
.003 *
.009 <
.044 <
.197 <
.048
.001 <
.001 <
.001 <
.001 <
.001 <
.001 <
.329 <
.001 <
.001 <
.127 <
.001 <
.001 <
.001 <
.001 <
.001 <
.001 <
.001 <
.002 <
.004 <
.415 *
.001 <
.007 <
.351 <
.261 <
.920 <
.624 <
.001 <
.002 <
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
019 *
002 <
002
003
019
001
001
Oil
299
001 <
001 <
001 <
001 <
001 <
001 <
035 *
001 <
001 <
001 *
001 <
001 <
001 <
001 <
001 <
001 <
001 <
002 <
004 <
015 *
001 <
007 <
001
001
001
001
001 <
002 <
ug
1.
0.
0.
0.
0.
0.
0.
5.
0.
0.
0.
0.
0.
0.
0.
4.
0.
0.
3.
0.
0.
0.
0.
0.
0.
0.
0.
0.
3.
0.
0.
0.
0.
1.
0.
0.
0.
082 *
002 <
382
128
000 *
009 *
044 *
197 *
000 *
001 <
001 <
001 <
001 <
001 <
001 <
329 *
001 <
001 <
127 *
001 <
001 <
001 <
001 <
001 <
001 <
001 <
002 <
004 <
400 *
001 <
007 <
351
261
920
624
001 <
002 <
uo/Nm3
31
0
11
3
0
0
1
150
0
0
0
0
0
0
0
125
0
0
90
0
0
0
0
0
0
0
0
0
98
0
0
10
7
55
18
0
0
•
•
•
»
•
•
*
•
•
•
•
•
•
•
•
•
•
•
^
.
*
*
*
,
*
*
•
.
,
,
•
.
•
•
•
•
•
367
058
074
711
000
261
276
661
000
029
029
029
029
029
029
498
029
029
652
029
029
029
029
029
029
029
058
116
566
029
203
176
566
661
090
029
058
* 4
< 8
1
5
* 0
* 4
* 1
* 2
* 0
< 4
< 4
< 4
< 4
< 4
< 4
* 1
< 4
< 4
* 1
< 4
< 4
< 4
< 4
< 4
< 4
< 4
< 8
< 1
* 1
< 4
< 3
1
1
8
2
< 4
< 8
MASS
RATE
lb/hr
.80E-04
.88E-07
.70E-04
.68E-05
.OOE+00
.OOE-06
.95E-05
.31E-03
.OOE+00
.44E-07
.44E-07
.44E-07
.44E-07
.44E-07
.44E-07
.92E-03
.44E-07
.44E-07
.39E-03
.44E-07
.44E-07
.44E-07
.44E-07
.44E-07
.44E-07
.44E-07
.88E-07
.78E-06
.51E-03
.44E-07
.11E-06
. 56E-04
.16E-04
.52E-04
.77E-04
.44E-07
.88E-07
Chloromethane
Vinyl Chloride
Br omomet hane
Chloroethane
Trichlorofluoromethane
1,1-Dichloroethene
Carbon disulfide
Acetone
Methylene chloride
trans-1,2-Dichloroethene
1,1-Dichloroethane
cis-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Vinyl acetate
2-Butanone
1,1,1-Trichloroethane
Carbon tetrachloride
Benzene
Trichloroethene
1,2-Dichloropropane
Bromodichloromethane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Dibromochloromethane
Bromoform
4-Methyl-2-pentanone
Toluene
Tetrachloroethene
2-Hexanone
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylene
Styrene
1,1,2,2-Tetrachloroethane
< Not detected
* Detected but below the quantitation limit; quantity is estimated
**If Blank(ug) Not Detected, then TOTAL(ug) = SAMPLE(ug); if
BLANK(ug) > SAMPLE(ug), the TOTAL(ug) = 0.00
1 Volumetric flowrate is from KCE-M0010-R2.
-------
ANALYTICAL DATA AND RESULTS FOR ORGANIC SAMPLING
RUN I.D.
DATE
START TIME
END TIME
CORR. SAMPLE VOL.
VOLUMETRIC FLOWRATE
SAMPLE I.D.
POLLUTANT
Chloromethane
Vinyl Chloride
Bromomethane
Chloroethane
Trichlorof luoromethane
1, 1-Dichloroethene
Carbon disulfide
Acetone
Methylene chloride
trans-l,2-Dichloroethene
1, 1-Dichloroethane
cis-1, 2-Dichloroethene
Chloroform
1,2-Dichloroethane
Vinyl acetate
2-Butanone
1,1, 1-Trichloroethane
Carbon tetrachloride
Benzene
Trichloroethene
1 , 2-Dichloropropane
Bromodichloromethane
cis-1, 3-Dichloropropene
trans-1 , 3-Dichloropropene
1,1,2-Trichloroethane
D ibromoch loromet hane
Bromoform
4-Methyl-2-pentanone
Toluene
Tetrachloroethene
2-Hexanone
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylene
Styrene
1,1,2, 2-Tetrachloroethane
KCE-M0030-R2F
07/29/93
17:01
17:21
0.019 dscm
4388 dscfm1
633/635
(a) (b)
SAMPLE BLANK
<
<
ie
*
*
it
iene <
<
ie <
<
<
<
*
i <
<
*
<
<
<
sne <
•pene <
! <
<
<
<
*
<
<
<
.hane <
u
0.
0.
0.
0.
0.
0.
0.
3.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
2.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
p.
901
002
161
089
071
007
028
237
059
001
001
001
001
001
001
724
001
001
675
001
001
001
001
001
002
001
002
005
809
001
009
187
147
833
316
001
003
*
<
<
<
*
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
*
<
<
<
<
<
<
<
<
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ug
.019
.002
.002
.003
.019
.001
.001
.011
.299
.001
.001
.001
.001
.001
.001
.035
.001
.001
.001
.001
.001
.001
.001
.001
.001
.001
.002
.004
.015
.001
.007
.001
.001
.001
.001
.001
.002
GAS EMISSIONS
(a-b) CONC.
TOTAL** ACTUAL
uo ug/Nm3
<
<
*
*
*
*
<
<
<
<
<
<
*
<
<
*
<
<
<
<
<
<
<
<
<
*
<
<
<
<
0
0
0
0
0
0
0
3
0
0
0
0
0
0
0
1
0
0
2
0
0
0
0
0
0
0
0
0
1
0
0
0
0
0
0
0
0
.882 <
.002 <
.161
.089
.052 *
.007 *
.028 *
.237 *
.000
.001 <
.001 <
.001 <
.001 <
.001 <
.001 <
.724 *
.001 <
.001 <
.675 *
.001 <
.001 <
.001 <
.001 <
.001 <
.002 <
.001 <
.002 <
.005 <
.794 *
.001 <
.009 <
.187
.147
.833
.316
.001 <
.003 <
50
0
9
5
2
0
1
186
0
0
0
0
0
0
0
99
0
0
154
0
0
0
0
0
0
0
0
0
103
0
0
10
8
47
18
0
0
•
•
•
•
•
.
•
,
•
•
m
•
•
•
•
•
•
.
•
•
•
•
•
•
•
•
•
.
•
m
•
•
*
•
•
.
•
794
115
272
125
995
403
613
418
000
058
058
058
058
058
058
285
058
058
053
058
058
058
058
058
115
058
115
288
316
058
518
769
466
972
198
058
173
7.
4.
MASS
RATE
lb/hr
7.78E-04
1.76E-06
1.42E-04
.85E-05
•59E-05
6.17E-06
2.47E-05
2.86E-03
O.OOE+00
8.82E-07
8.82E-07
8.82E-07
8.82E-07
8.82E-07
8.82E-07
1.52E-03
8.82E-07
8.82E-07
2.36E-03
8.82E-07
8.82E-07
8.82E-07
8.82E-07
8.82E-07
1.76E-06
8.82E-07
1.76E-06
4.41E-06
1.58E-03
8.82E-07
7.94E-06
1.65E-04
1.30E-04
7.35E-04
2.79E-04
8.82E-07
2.65E-06
< Not detected
* Detected but below the quantitation limit; quantity is estimated
**If Blank(ug) Not Detected, then TOTAL(ug) = SAMPLE(ug); if
BLANK(ug) > SAMPLE(ug), the TOTAL(ug) = 0.00
Volumetric flowrate is from KCE-M0010-R2.
1
-------
SUMMARY OF EPA M0030 TESTING
KILN COMBUSTION EXHAUST
RUN I.D.
DATE
KCE-M0030-R3E
07/30/93
KCE-M0030-R3F AVERAGE
07/30/93
POLLUTANT CONCENTRATION - Ib/hr
Chloromethane
Vinyl Chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1,1-Dichloroethene
Carbon disulfide
Acetone
Methylene chloride
trans-1,2-Dichloroethene
1,1-Dichloroethane
cis-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Vinyl acetate
2-Butanone
1,1,1-Trichloroethane
Carbon tetrachloride
Benzene
Trichloroethene
1,2-Dichloropropane
Bromodichloromethane
cis-1,3-Dichloropropene
trans-l,3-Dichloropropene
1,1,2-Trichloroethane
Dibromochloromethane
Bromoform
4-Methy1-2-pentanone
Toluene
Tetrachloroethene
2-Hexanone
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylene
Styrene
1,1,2,2-Tetrachloroethane <
< Not detected
* Detected but below the quantitation limit; quantity is
estimated
*
<
*
*
*
<
<
<
<
<
<
*
<
*
<
<
<
<
<
<
<
<
<
*
<
<
<
<
1
2
1
9
2
1
2
3
0
8
8
8
8
8
8
1
3
8
2
8
8
8
8
8
1
8
2
4
1
8
7
9
1
5
2
8
2
.02E-03 *
.64E-06 <
.21E-04
.23E-05
.54E-04 *
.01E-04
.64E-05 *
.83E-03 *
.OOE+00
.79E-07 <
.79E-07 <
.79E-07 <
.79E-07 <
.79E-07 <
.79E-07 <
.50E-03 *
.89E-04 <
.79E-07 <
.37E-03 *
.79E-07 <
.79E-07 <
.79E-07 <
.79E-07 <
.79E-07 <
.76E-06 <
.79E-07 <
.64E-06 <
.39E-06 <
.32E-03 *
.79E-07 <
.91E-06 <
.67E-05
.20E-04
.87E-04
.42E-04
.79E-07 <
.64E-06 <
1
8
2
9
1
7
1
5
0
4
4
4
4
4
4
1
2
4
1
4
4
4
4
4
4
4
8
1
1
4
3
9
1
6
2
4
8
.21E-03
.84E-07
.16E-04
.14E-05
.44E-04
.47E-05
.86E-05
.73E-03
.OOE+00
.42E-07
.42E-07
.42E-07
.42E-07
.42E-07
.42E-07
.18E-03
.85E-04
.42E-07
.31E-03
.42E-07
.42E-07
.42E-07
.42E-07
.42E-07
.42E-07
.42E-07
.84E-07
.77E-06
.33E-03
.42E-07
.09E-06
.14E-05
.14E-04
.28E-04
.31E-04
.42E-07
.84E-07
*1
<1
1
9
*1
8
*2
*4
0
<6
<6
<6
<6
<6
<6
*1
<3
<6
*1
<6
<6
<6
<6
<6
<1
<6
<1
<3
*1
<6
<5
9
1
6
2
<6
<1
•
•
•
•
*
•
•
•
•
•
•
*
*
•
•
•
•
•
•
•
•
•
•
•
»
•
•
•
•
•
•
*
•
•
•
•
•
11E-03
76E-06
69E-04
19E-05
99E-04
79E-05
25E-05
78E-03
OOE+00
60E-07
60E-07
60E-07
60E-07
60E-07
60E-07
34E-03
37E-04
60E-07
84E-03
60'E-07
60E-07
60E-07
60E-07
60E-07
10E-06
60E-07
76E-06
08E-06
33E-03
60E-07
50E-06
41E-05
17E-04
07E-04
37E-04
60E-07
76E-06
-------
PRELIMINARY
VOST SAMPLING DATA AND RESULTS
Run I.D.
KCE-M0030-R3A
KCE-M0030-R3B
KCE-M0030-R3C
KCE-M0030-R3D
KCE-M0030-R3E
KCE-M0030-R3F
KCE-M0030-R3
Date
07/30/93
07/30/93
07/30/93
07/30/93
07/30/93
07/30/93
Start
Time
08:15
08:42
09:20
10:13
10:42
11:13
End
Time
08:35
09:02
09:40
10:33
11:02
11:33
Meter
Temp.
(Fo)
87.5
93.0
102.5
109.0
112.0
110.5
Meter
Press.
fin. vie)
1.0
2.1
1.0
2.1
1.0
2.1
Bar.
Press.
(in. Ha)
29.97
29.97
29.97
29.97
29.97
29.97
Initial
Meter
Volume
(liters)
732.050
752.840
794.420
828.790
869.200
890.020
Final
Meter
Volume
(liters)
752.520
793.050
815.050
868.830
889.720
930.630
Sample
Volume
(liters)
20.470
40.210
20.630
40.040
20.520
40.610
Corrected
Sample
Volume
(dscm)
0.0198
0.0386
0.0194
0.0374
0.0190
0.0378
-------
ANALYTICAL DATA AND RESULTS FOR ORGANIC SAMPLING
RUN I.D.
DATE
START TIME
END TIME
CORR. SAMPLE VOL.
VOLUMETRIC FLOWRATE
SAMPLE I.D.
KCE-M0030-R3E
07/30/93
10:42
11:02
0.019 dscm
4461 dscfm1
651/653
POLLUTANT
GAS EMISSIONS
(a)
SAMPLE
ug
* 1.175
< 0.003
0.138
0.105
0.308
0.115
* 0.030
* 4.361
0.065
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
* 1.703
0.442
< 0.001
* 2.696
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
< 0.002
< 0.001
< 0.003
< 0.005
* 1.522
< 0.001
< 0.009
0.110
0.137
0.668
0.275
< 0.001
< 0.003
(b)
BLANK
UP
* 0.019
< 0.002
< 0.002
< 0.003
* 0.019
< 0.001
< 0.001
< 0.011
0.299
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
< 0.035
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
< 0.002
< 0.004
* 0.015
< 0.001
< 0.007
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
< 0.002
(a-b)
TOTAL**
uq
* 1.156
< 0.003
0.138
0.105
* 0.289
0.115
* 0.030
* 4.361
0.000
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
* 1.703
0.442
< 0.001
* 2.696
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
< 0.002
< 0.001
< 0.003
< 0.005
* 1.507
< 0.001
< 0.009
0.110
0.137
0.668
0.275
< 0.001
< 0.003
CONC.
ACTUAL
ua/Nm3
* 65.259 *
< 0.169 <
7.790
5.927
* 16.315 *
6.492
* 1.694 *
*246.188 *
0.000
< 0.056 <
< 0.056 <
< 0.056 <
< 0.056 <
< 0.056 <
< 0.056 <
* 96.138 *
24.952
< 0.056 <
*152.195 *
< 0.056 <
< 0.056 <
< 0.056 <
< 0.056 <
< 0.056 <
< 0.113 <
< 0.056 <
< 0.169 <
< 0.282 <
* 85.074 *
< 0.056 <
< 0.508 <
6.210
7.734
37.710
15.524
< 0.056 <
< 0.169 <
MASS
RATE
Ib/hr
1.02E-03
2.64E-06
1.21E-04
9.23E-05
2.54E-04
1.01E-04
2.64E-05
3.83E-03
O.OOE+00
8.79E-07
8.79E-07
8.79E-07
8.79E-07
8.79E-07
8.79E-07
1.50E-03
3.89E-04
8.79E-07
2.37E-03
8.79E-07
8.79E-07
8.79E-07
8.79E-07
8.79E-07
1.76E-06
8.79E-07
2.64E-06
4.39E-06
1.32E-03
8.79E-07
7.91E-06
9.67E-05
1.20E-04
5.87E-04
2.42E-04
8.79E-07
2.64E-06
Chloromethane
Vinyl Chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1,1-Dichloroethene
Carbon disulfide
Acetone
Methylene chloride
trans-l,2-Dichloroethene
1,1-Dichloroethane
cis-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Vinyl acetate
2-Butanone
1,1,1-Trichloroethane
Carbon tetrachloride
Benzene
Trichloroethene
1,2-Dichloropropane
Bromodichloromethane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Dibromochloromethane
Br onto form
4-Methyl-2-pentanone
Toluene
Tetrachloroethene
2-Hexanone
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylene
Styrene
1,1,2,2-Tetrachloroethane
< Not detected
* Detected but below the quantitation limit; quantity is estimated
**If Blank(ug) Not Detected, then TOTAL(ug) = SAMPLE(ug); if
BLANK(ug) > SAMPLE(ug), the TOTAL(ug) = 0.00
1 Volumetric flowrate is from KCE-M0010-R3.
-------
ANALYTICAL DATA AND RESULTS FOR ORGANIC SAMPLING
RUN I.D.
DATE
START TIME
END TIME
CORR. SAMPLE VOL.
VOLUMETRIC FLOWRATE
SAMPLE I.D.
KCE-M0030-R3F
07/30/93
11:13
11:33
0.038 dscm
4461 dscfm1
654/656
POLLUTANT
(a)
SAMPLE
GAS EMISSIONS
(b) (a-b) CONC.
BLANK TOTAL** ACTUAL
UCf UO
*
<
*
2.
0.
0.
0.
0.
0.
0.
*12.
<
<
<
<
<
<
*
<
*
<
<
<
<
<
<
<
<
<
*
<
<
<
<
0.
0.
0.
0.
0.
0.
0.
2.
0.
0.
2.
0.
0.
0.
0.
0.
0.
0.
0.
0.
3.
0.
0.
0.
0.
1.
0.
0.
0.
755 *
002 <
490 <
207 <
344 *
169 <
042 <
964 <
199
001 <
001 <
001 <
001 <
001 <
001 <
681 <
646 <
001 <
955 <
001 <
001 <
001 <
001 <
001 <
001 <
001 <
002 <
004 <
024 *
001 <
007 <
207 <
257 <
421 <
524 <
001 <
002 <
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.019 *
.002 <
.002
.003
.019 *
.001
.001 *
.011 *
.299
.001 <
.001 <
.001 <
.001 <
.001 <
.001 <
.035 *
.001 <
.001 <
.001 *
.001 <
.001 <
.001 <
.001 <
.001 <
.001 <
.001 <
.002 <
.004 <
.015 *
.001 <
.007 <
.001
.001
.001
.001
.001 <
.002 <
UCL
2
0
0
0
0
0
0
12
0
0
0
0
0
0
0
2
0
0
2
0
0
0
0
0
0
0
0
0
3
0
0
0
0
1
0
0
0
.736 *
.002 <
.490
.207
.325 *
.169
.042 *
.964 *
.000
.001 <
.001 <
.001 <
.001 <
.001 <
.001 <
.681 *
.646 <
.001 <
.955 *
.001 <
.001 <
.001 <
.001 <
.001 <
.001 <
.001 <
.002 <
.004 <
.009 *
.001 <
.007 <
.207
.257
.421
.524
.001 <
.002 <
uo/Nm3
77
0
13
5
9
4
1
367
0
0
0
0
0
0
0
76
18
0
83
0
0
0
0
0
0
0
0
0
85
0
0
5
7
40
14
0
0
•
•
•
•
•
•
•
,
.
.
•
•
.
.
•
.
*
•
,
.
.
,
.
,
.
•
•
.
•
m
•
•
•
•
•
•
•
631 *
057 <
903
873
221 *
795
192 *
838 *
000
028 <
028 <
028 <
028 <
028 <
028 <
070 *
329 <
028 <
845 *
028 <
028 <
028 <
028 <
028 <
028 <
028 <
057 <
113 <
377 *
028 <
199 <
873
292
319
868
028 <
057 <
MASS
RATE
Ib/hr
1.
8.
2.
9.
1.
7.
1.
5.
0.
4.
4.
4.
4.
4.
4.
1.
2.
4.
1.
4.
4.
4.
4.
4.
4.
4.
8.
1.
1.
4.
3.
9.
1.
6.
2.
4.
8.
21E-03
84E-07
16E-04
14E-05
44E-04
47E-05
86E-05
73E-03
OOE+00
42E-07
42E-07
42E-07
42E-07
42E-07
42E-07
18E-03
85E-04
42E-07
31E-03
42E-07
42E-07
42E-07
42E-07
42E-07
42E-07
42E-07
84E-07
77E-06
33E-03
42E-07
09E-06
14E-05
14E-04
28E-04
31E-04
42E-07
84E-07
Chloromethane
Vinyl Chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1,1-Dichloroethene
Carbon disulfide
Acetone
Methylene chloride
trans-1,2-Dichloroethene
1,1-Dichloroethane
cis-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Vinyl acetate
2-Butanone
1,1,1-Trichloroethane
Carbon tetrachloride
Benzene
Trichloroethene
1,2-Dichloropropane
Bromodichloromethane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
Dibromochloromethane
Bromoform
4-Methy1-2-pentanone
Toluene
Tetrachloroethene
2-Hexanone
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylene
Styrene
1,1,2,2-Tetrachloroethane
< Not detected
* Detected but below the quantitation limit; quantity is estimated
**!£ Blank(ug) Not Detected, then TOTAL(ug) = SAMPLE(ug); if
BLANK(ug) > SAMPLE(ug), the TOTAL(ug) = 0.00
1 Volumetric flowrate is from KCE-M0010-R3.
-------
APPENDIX D.I.6
DATA AND RESULTS FOR EPA METHOD 0010 TESTING
-------
SUMMARY OF EMISSIONS FOR SEMI VOLATILE TESTING
KILN COMBUSTION EXHAUST
RUN I.D.
DATE
TINE STARTED
TIME ENDED
KX-N0010-R1
7/29/93
08:43
13:11
KCE-N0010-R2
7/29/93
14:12
17:42
KCE-N0010-R3
7/30/93
08:15
11:49
AVERAGE
SEN 1 VOL AT HE EMISSIONS (Ib/hr)
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,2-Dichlorobenzene
Benzyl alcohol
2,2'-oxybis(1-Chloropropane)
2-Methylphenol
3/4-Methylphenol
N-Nitroso-di-n-propylamine
HexachIoroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
bis(2-Chloroethoxy)methane
Benzoic acid
2,4-Dichlorophenol
1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexach I orobutadi ene
4-Chloro-3-methylphenol
2-Methylnaphthalene
HexachIorocycIopentadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethylphthalate
2,6-Dinitrotoluene
2,4-Dinitrotoluene
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
Diethylphthalate
4-Chlorophenyl-phenylether
Fluorene
4-Nitroaniline
4,6-Dinitro-2-methylphenol
N-Nitrosodiphenylamine
4-BromophenyI-phenyIether
Hexachlorobenzene
PentachIorophenoI
Phenanthrene
Anthracene
Di-n-butylphthalate
Fluoranthene
Pyrene
Butylbenzylphthalate
3,3'-Dichlorobenzidine
bis(2-Ethylhexyl)phthalate
Benzo(a)anthracene
Chrysene
Di-n-octylphthalate
Benzo(b)fIuoranthene
BenzodOf luoranthene
Benzo(a)pyrene
Indeno(1,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
< Not detected
* Detected but below the quantitat ion limit; quantity is estimated
** Average is composed of estimated values only, non-detected values
are not included in the calculation of the average.
O.OOE+00
1.24E-05 <
9.71E-06 <
9.12E-06 <
9.04E-06 *
9.S8E-06 <
1.96E-05 <
1.07E-05 <
1.30E-05 <
1.26E-05 <
1.97E-05 <
2.02E-05 <
1.00E-04 <
5.71E-04
1.63E-05 <
1.08E-05 <
9.42E-06 <
1.05E-03
1.21E-05 <
1.07E-05 <
1.10E-04
8.83E-06 <
1.85E-05 <
1.22E-05 <
9.46E-06 *
1.95E-05 <
1.63E-05
1.50E-05
5.71E-06
1.91E-05
4.46E-06 <
1.83E-05
1.08E-05
3.29E-06 <
1.41E-05 <
5.79E-06 <
2.82E-05 <
1.91E-05 <
3.83E-06 *
1.59E-05 *
1.03E-05 <
4.62E-06 <
1.02E-05 <
1.57E-05 <
5.96E-06 <
1.41E-05 <
1.08E-OS <
1.32E-05 <
2.33E-06 *
2.50E-06 <
O.OOE+00
1.67E-06 <
1.42E-06 <
1.66E-05 *
4.71E-06 <
O.OOE+00
1.71E-06 <
1.87E-06 <
1.79E-04
2.00E-06 <
2.00E-06 <
2.04E-06 <
1.79E-06 <
2.33E-06 <
2.12E-06 <
3.15E-04
1.40E-OS <
1.10E-05 <
1.03E-05 <
2.75E-05 *
1.08E-05 <
2.22E-05 <
1.22E-05 <
1.48E-05 <
1.43E-05 <
2.22E-OS <
2.28E-05 <
1.30E-05 <
6.93E-06
1.92E-05 <
1.27E-05 <
1.10E-05 <
1.25E-03
1.42E-05 <
1.26E-05 <
O.OOE+00
1.04E-05 <
2.17E-05 <
1.42E-05 <
8.26E-06 *
2.42E-05 <
2.03E-05 <
1.86E-05 <
7.14E-06 <
2.38E-05 <
S.S6E-06 <
2.28E-05 <
1.35E-05 <
4.13E-06 *
1.76E-05 <
7.25E-06 <
3.52E-05 <
2.38E-05 <
2.75E-06 <
5.82E-06 *
1.29E-05 <
5.77E-06 <
1.27E-05 <
2.32E-05 <
8.84E-06 <
2.09E-05 <
1.60E-05 <
1.97E-05 <
6.93E-06 <
3.70E-06 <
O.OOE+00
2.49E-06 <
1.96E-06 *
8.20E-06 *
6.46E-06 <
1.88E-04
2.38E-06 <
2.54E-06 <
8.88E-05
2.54E-06 <
2.54E-06 <
2.59E-06 <
2.28E-06 <
2.91E-06 <
2.70E-06 <
3.93E-04
1.42E-05 <
1. HE-OS <
1.04E-OS <
3.15E-05 *
1.09E-05 <
2.23E-05 <
1.23E-05 <
1.49E-05 <
1.44E-OS <
2.24E-05 <
2.30E-05 <
1.36E-05 <
7.26E-06
2.00E-05 <
1.33E-05 <
1.15E-05 <
2.56E-03
1.48E-05 <
1.31E-05 <
2.71E-05
1.08E-05 <
2.27E-05 <
1.49E-05 <
1.65E-05 *
2.50E-05 <
2.09E-05 <
1.92E-05 <
7.36E-06 <
2.45E-05 <
5.72E-06 <
2.35E-05 <
1.39E-05 <
1.43E-05 *
1.81E-05 <
7.46E-06 <
3.63E-05 <
2.45E-05 <
4.91E-06 *
5.21E-06 *
1.33E-05 <
5.93E-06 <
1.31E-05 <
2.48E-05 <
9.46E-06 <
2.23E-05 <
1.71E-05 <
2.10E-05 <
3.73E-06 *
3.99E-06 <
O.OOE+00
2.66E-06 <
1.99E-06 *
8.02E-06 *
6.59E-06 <
8.08E-04
2.40E-06 <
2.61E-06 <
5.21E-05
2.56E-06 <
2.56E-06 <
2.61E-06 <
2.30E-06 <
2.96E-06 <
2.71E-06 <
2.36E-04
1.35E-05
1.06E-05
9.94E-06
2.95E-05**
1.05E-05
2.14E-05
1.17E-05
1.42E-05
1 .38E-05
2.14E-05
2.20E-05
4.24E-05
.95E-04
.85E-05
.23E-05
.06E-05
.62E-03
.37E-05
1.22E-05
4.56E-05
1.00E-05
2.10E-05
1.38E-05
1.14E-05
2.29E-05
1.92E-05
1.76E-05
6.74E-06
2.25E-05
5.25E-06
2.15E-05
1.27E-05
1.43E-05"*
1.66E-05
6.83E-06
3.32E-05
2.25E-05
2.75E-06"
8.97E-06
1.22E-05
5.44E-06
1.20E-05
2.12E-05
8.08E-06
1.91E-05
1.46E-05
1.80E-05
6.93E-06**
3.40E-06
O.OOE+00
2.27E-06
1.99E-06**
8.11E-06**
5.92E-06
3.32E-04
2.16E-06
2.34E-06
1.07E-04
2.37E-06
2.37E-06
2.41E-06
2.12E-06
2.74E-06
2.51E-06
-------
RUN NUMBER
KCE-N0010-R1
DATE
START TIME
END TIME
STACK DIAM.
NOZZLE I.D.
METER BOX GAMMA
METER BOX dH3
BAROMETRIC
Cp
TEST DURATION
METHOD 1-4 RESULTS
Metered Volume
Volume a Std.Cond.
X Water
X Isokinetics
Velocity
Actual Flow
Std. Flow
Dry Std. Flow
STACK
TEMP STATIC
POINT (DeaF) (in.WC)
1 285 0.17
2 296 0.13
3 311 0.14
4 301 0.13
5 321
6 324
7 321
8 329
9 328
10 330
11 331
12 329
13 291
14 295
15 325
16 327
17 331
18 331
19 324
20 320
21 336
22 329
23 340
24 335
25 280
26 326
27 337
28 343
29 345
30 336
31 338
32 337
33 336
34 321
35 344
36 346
37 335
38 333
39 337
40 340
41 336
42 330
43 333
44 337
45 340
46 337
47 342
48 343
49
AVG. 328 0.14
7/29/93
08:43
13:11
25 X 24
0.3125
1.0046
1.8521
30.00
0.84
240
150.256
142.521
9.58
103.6
29.52
7381
4963
4488
DP
(in.WC)
0.19
0.19
0.17
0.18
0.22
0.24
0.20
0.20
0.16
0.15
0.15
0.17
0.15
0.15
0.17
0.16
0.19
0.18
0.21
0.21
0.18
0.16
0.16
0.17
0.15
0.19
0.17
0.15
0.22
0.20
0.19
0.19
0.22
0.22
0.23
0.23
0.16
0.16
0.15
0.16
0.19
0.20
0.20
0.19
0.17
0.17
0.19
0.17
0.18
inches
inches
in.Hg
minutes
dcf
dscf
X
X
ft/sec
acfra
scfm
dscfm
DH
(in.WC)
1.20
1.20
1.10
1.15
1.50
1.80
1.30
1.30
1.00
0.96
0.96
1.10
0.96
0.96
1.10
1.00
.20
.15
.40
.40
.15
.00
1.00
1.10
0.96
1.20
1.10
0.96
1.50
1.30
1.20
1.20
1.50
1.50
1.65
1.65
1.00
1.00
0.96
1.00
1.20
1.30
1.30
1.20
1.10
1.10
1.20
1.10
1.19
METHOD 4
IMP.1
IMP. 2
IMP.3
IMP.4
IMP.5
IMP. 6
IMP. 7
TOTAL
S.G.
METHOD 3
X02
XC02
XCO
XN2
02+C02
METER
VOLUME
(dcf)
606.361
643.596
643.596
679.763
680.150
720.161
720.161
757.004
150.256
DATA
INIT.
(ml)
0.0
100.0
100.0
0.0
200.0
200.0
DATA
15.9
4.5
0.0
79.6
20.4
FINAL
(ml)
295.0
98.0
101.0
2.0
496.0
224.7
Md
Ms
Ps
Fo
XEA
NET
(ml)
295.0
-2.0
1.0
2.0
0.0
0.0
0.0
296.0
24.7
29.36
28.27
30.01
1.104
311
METER TEMPERATURE
INLET
tDegF)
87
90
92
94
94
96
97
97
98
99
99
100
98
102
103
103
105
105
106
107
108
108
107
107
101
104
106
107
106
107
106
108
110
111
111
111
106
107
108
110
113
115
115
112
110
110
112
112
OUTLET
(DegF)
86
87
88
89
90
91
91
91
92
93
93
94
95
98
98
98
99
99
100
101
102
102
102
102
100
102
101
102
102
102
102
103
104
104
105
106
103
104
104
105
106
108
109
107
106
106
106
107
102
-------
LABORATORY DATA AND RESULTS Fu.
SENIVOLATILE COMPOUNDS
RUN NUMBER
SAMPLE VOLUME
TOTAL GAS FLOURATE
OXYGEN
KCE-N0010-R1
142.521 dscf
4488 dscfm
15.9 X
GAS EMISSIONS
(a)
SAMPLE
"9
< 2.23 *
< 2.98 <
< 2.33 <
< 2.19 <
< 2.17 <
< 2.30 <
< 4.70 <
< 2.58 <
< 3.13 <
< 3.03 <
< 4.72 <
< 4.84 <
< 24.11 <
137.13 <
< 3.92 <
< 2.60 <
< 2.26 <
277.50
< 2.91 <
< 2.58 <
76.77
< 2.12 <
< 4.45 <
< 2.92 <
* 2.27 <
< 4.68 <
< 3.91 <
< 3.59 <
< 1.37<
< 4.59 <
< 1.07<
< 4.39 <
< 2.60 <
< 0.79 <
< 3.39 <
< 1.39 <
< 6.78 <
< 4.59 <
< 0.92 <
* 6.21 *
< 2.48 <
< 1.11 <
< 2.45 <
< 3.76 <
< 1.43 <
< 3.38 <
< 2.59 <
< 3.18 <
< 0.56 <
< 0.60 <
93.91
< 0.40 <
< 0.34 <
< 3.99 <
< 1.13 <
23.13
< 0.41 <
< 0.45 <
42.99 <
< 0.48 <
< 0.48 <
< 0.49 <
< 0.43 <
< 0.56 <
< 0.51 <
(b)
BLANK
_ug_
6.46
2.69 <
2.11 <
1.97 <
1.96 <
2.08 <
4.25 <
2.33 <
2.83 <
2.73 <
4.26 <
4.37 <
2.66 <
1.42
3.91 <
2.60 <
2.25 <
25.16
2.91 <
2.57 <
50.42
2.12 <
4.44 <
2.92 <
1.45 *
5.01 <
4.18 <
3.84 <
1.47 <
4.91 <
1.14 <
4.70 <
2.78 <
0.85 <
3.63 <
1.49 <
7.27 <
4.91 <
0.99 <
2.40 *
2.66 <
1.19 <
2.63 <
5.20 <
1.98 <
4.68 <
3.58 <
4.40 <
0.78 <
0.83 <
222.49
0.56 <
0.48 <
0.86 <
1.58 <
103.97
0.58 <
0.63 <
0.44 <
0.62 <
0.62 <
0.63 <
0.56 <
0.72 <
0.66 <
(a-b)
TOTAL**
_ug_
0.00
2.98 <
2.33 <
2.19 <
2.17 <
2.30 <
4.70 <
2.58 <
3.13 <
3.03 <
4.72 <
4.84 <
24.11 <
137.13
3.92 <
2.60 <
2.26 <
252.34
2.91 <
2.58 <
26.35
2.12 <
4.45 <
2.92 <
2.27 *
4.68 <
3.91 <
3.59 <
1.37 <
4.59 <
1.07 <
4.39 <
2.60 <
0.79 <
3.39 <
1.39 <
6.78 <
4.59 <
0.92 <
3.81 *
2.48 <
1.11 <
2.45 <
3.76 <
1.43 <
3.38 <
2.59 <
3.18 <
0.56 <
0.60 <
0.00
0.40 <
0.34 <
3.99 <
1.13 <
0.00
0.41 <
0.45 <
42.99 <
0.48 <
0.48 <
0.49 <
0.43 <
0.56 <
0.51 <
CONCENTRATION
ACTUAL
U9/Nm3
0.000
0.792 <
0.620 <
0.582 <
0.577 <
0.612 <
1.250 <
0.686 <
0.832 <
0.806 <
1.255 <
1.287 <
6.411 <
36.465
1.042 <
0.691 <
0.601 <
67.101
0.774 <
0.686 <
7.007
0.564 <
1.183 <
0.776 <
0.604 *
1.244 <
1.040 <
0.955 <
0.364 <
1.221 <
0.285 <
1.167 <
0.691 <
0.210 <
0.901 <
0.370 <
1.803 <
1.221 <
0.245 <
1.013 *
0.659 <
0.295 <
0.651 <
1.000 <
0.380 <
0.899 <
0.689 <
0.846 <
0.149 <
0.160 <
0.000
0.106 <
0.090 <
1.061 <
0.300 <
0.000
0.109 <
0.120 <
11.432 <
0.128 <
0.128 <
0.130 <
0.114 <
0.149 <
0.136 <
a 7X 02
ug/Nm3
0.000
2.203 <:
1.722 <
1.619 <
1.604 <
1.700 <
3.474 <
1 .907 <
2.314 <
2.240 <
3.489 <
3.578 <
17.823 <
101.373
2.898 <
1.922 <
1.671 <
186.541
2.151 <
1 .907 <
19.479
1.567 <
3.290 <
2.159 <
1.678 *
3.460 <
2.890 <
2.654 <
1.013 <
3.393 <
0.791 <
3.245 <
1.922 <
0.584 <
2.506 <
1.028 <
5.012 <
3.393 <
0.680 <
2.817 *
1.833 <
0.821 <
1.811 <
2.780 <
1.057 <
2.499 <
1.915 <
2.351 <
0.414 <
0.444 <
0.000
0.296 <
0.251 <
2.950 <
0.835 <
0.000
0.303 <
0.333 <
31.780 <
0.355 <
0.355 <
0.362 <
0.318 <
0.414 <
0.377 <
MASS
RATE
Ib/hr
O.OOE+00
1.24E-05
9.71E-06
9.12E-06
9.04E-06
9.58E-06
1.96E-05
1.07E-05
1.30E-05
1.26E-05
1.97E-05
2.02E-05
1.00E-04
5.71E-04
1.63E-05
1.08E-05
9.42E-06
1.05E-03
1.21E-05
1.07E-05
1.10E-04
8.83E-06
1.85E-05
1.22E-05
9.46E-06
1.95E-05
1.63E-05
1.50E-05
5.71E-06
1.91E-05
4.46E-06
1.83E-05
1.08E-05
3.29E-06
1.41E-05
5.79E-06
2.82E-05
1.91E-05
3.83E-06
1.59E-05
1.03E-05
4.62E-06
1.02E-05
1.57E-05
5.96E-06
1.41E-05
1.08E-05
1.32E-05
2.33E-06
2.50E-06
O.OOE+00
1.67E-06
1.42E-06
1.66E-05
4.71E-06
O.OOE+00
1.71E-06
1.87E-06
1.79E-04
2.00E-06
2.00E-06
2.04E-06
1.79E-06
2.33E-06
2.12E-06
SEMIVOLATIIE COMPOUNDS
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlocobenzene
1,4-Dichlorobenzene
1,2-DichIorobenzene
Benzyl alcohol
2,2'-oxybis(1-Chloropropane)
2-Methylphenol
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
bis(2-Chloroethoxy)methane
Benzoic acid
2,4-Dichlorophenol
1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
HexachIorobutadi ene
4-Chloro-3-methylphenol
2-Methylnaphthalene
Hexachlorocyclopentadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethylphthalate
2,6-Dinitrotoluene
2,4-Dinitrotoluene
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
Diethylphthalate
4-Chlorophenyl-phenylether
Fluorene
4-Nitroaniline
4,6-Dinitro-2-methylphenol
N-Nitrosodiphenylamine
4-Bromophenyl-phenylether
HexachIorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butylphthalate
Fluoranthene
Pyrene
Butylbenzylphthalate
3,3'-Dichlorobenzidine
bis(2-Ethylhexyl)phthalate
Benzo(a)anthracene
Chrysene
Di-n-octylphthalate
Benzo(b)fIuoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(1,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
< Not detected
* Detected but below the quantitat ion limit; quantity is estimated
** If BLANK(ug) Not Detected, then TOTAL(ug) = SAMPLE (ug); if BLANK(ug) >
then TOTAL(ug) = 0.00
SAMPLE (ug).
-------
RUN NUMBER
KCE-N0010-R2
DATE
START TIME
END TIME
STACK DIAM.
NOZZLE I.D.
METER BOX GAMMA
METER BOX dH3
BAROMETRIC
Cp
TEST DURATION
METHOD 1-4 RESULTS
Metered Volume
Volume 3 Std.Cond.
X Water
X Isokinetics
Velocity
Actual Flow
Std. Flow
Dry Std. Flow
STACK
TEMP STATIC
POINT (DegF) (in.WC)
1 313 0.16
2 305 0.15
3 315 0.13
4 317 0.13
5 317
6 325
7 339
8 344
9 341
10 336
11 336
12 340
13 335
14 335
15 334
16 337
17 350
18 345
19 325
20 330
21 353
22 350
23 341
24 354
25 312
26 310
27 348
28 336
29 337
30 341
31 353
32 351
33 351
34 352
35 341
36 323
37 327
38 344
39 342
40 339
41 326
42 334
43 326
44 335
45 352
46 348
47 348
48 342
49
AVG. 336 0.14
7/29/93
14:12
17:42
25 X 24
0.3125
1.00462
1.85206
30.00
0.84
192
117.294
109.693
8.36
101.9
28.79
7198
4788
4388
DP
(in.WC)
0.15
0.15
0.17
0.18
0.17
0.19
0.16
0.16
0.18
0.17
0.18
0.18
0.16
0.16
0.18
0.19
0.16
0.15
0.18
0.19
0.21
0.21
0.22
0.21
0.15
0.17
0.19
0.21
0.18
0.18
0.19
0.18
0.15
0.15
0.15
0.15
0.17
0.18
0.18
0.19
0.16
0.16
0.16
0.17
0.16
0.16
0.17
0.15
0.17
inches
inches
in.Hg
minutes
dcf
dscf
X
X
ft/sec
acfm
scfm
dscfro
DH
(in.WC)
0.96
0.96
1.10
1.15
1.10
1.20
1.00
1.00
1.15
1.10
1.15
1.15
1.00
1.00
1.15
1.20
1.00
0.96
1.15
1.20
1.40
1.40
1.50
1.40
0.96
1.10
1.20
1.40
1.15
1.15
1.20
1.15
0.96
0.96
0.96
0.96
1.10
1.15
1.15
1.20
1.00
1.00
1.00
1.10
1.00
1.00
1.10
0.96
1.11
METHOD 4
INP.1
IMP. 2
IMP.3
IMP. 4
IMP. 5
IMP. 6
IMP. 7
TOTAL
S.G.
METHOD 3
X02
XC02
XCO
XN2
02+C02
METER
VOLUME
(dcf)
762.757
791.734
791.734
821 .923
822.787
851.759
851.759
880.915
117.294
DATA
INIT.
(ml)
0.0
100.0
100.0
0.0
200.0
200.0
DATA
14.7
5.6
0.0
79.7
20.3
FINAL
(ml)
196.0
100.0
95.0
1.0
392.0
220.4
Md
Ms
Ps
Fo
XEA
NET
(ml)
196.0
0.0
-5.0
1.0
0.0
0.0
0.0
192.0
20.4
29.49
28.53
30.01
1.103
232
METER TEMPERATURE
INLET
(DegF)
109
108
109
107
111
112
111
111
111
111
112
112
109
110
110
111
111
113
113
113
113
113
115
116
112
114
117
118
118
117
118
116
116
115
112
112
109
110
111
112
113
113
112
111
112
113
112
112
OUTLET
(DegF)
107
107
108
107
107
107
106
106
107
107
108
108
105
105
106
107
107
106
107
107
107
107
108
108
109
110
111
111
112
110
111
111
111
110
108
109
106
107
107
107
108
107
106
106
107
106
106
106
110
-------
LABORATORY DATA AND RESULTS Fu.
SEMIVOLATILE COMPOUNDS
KCE-N0010-R2
109.693 dscf
4388 dscfm
14.7 X
(a)
SAMPLE
Ufl
66.05 *
< 2.65 <
< 2.08 <
< 1.95 <
* 5.19 <
< 2.05 <
< 4.19 <
< 2.30 <
< 2.79 <
< 2.70 <
< 4.20 <
< 4.31 <
< 2.46 <
1.31 <
< 3.62 <
< 2.40 <
< 2.08 <
261.41
< 2.68 <
< 2.38 <
26.13
< 1.96 <
< 4.10 <
< 2.69 <
* 1.56 <
< 4.58 <
< 3.83 <
< 3.51 <
< 1.35 <
< 4.49 <
< 1.05 <
< 4.30 <
< 2.55 <
< 0.78 <
< 3.32 <
< 1.37<
< 6.65 <
< 4.49 <
* 0.52 <
* 3.50 *
< 2.43 <
< 1.09 <
« 2.40 <
< 4.39 <
< 1 .67 <
< 3.95 <
< 3.02 <
< 3.72 <
* 1.31 <
< 0.70 <
61.30
< 0.47 <
< 0.37 <
* 1.55 <
< 1.22 <
139.40
< 0.45 <
< 0.48 <
16.78 <
< 0.48 <
< 0.48 <
< 0.49 <
< 0.43 <
< 0.55 <
< 0.51 <
(b)
BLANK
_ua_
6.46
2.69 <
2.11 <
1.97 <
1.96 *
2.08 <
4.25 <
2.33 <
2.83 <
2.73 <
4.26 <
4.37 <
2.66 <
1.42
3.91 <
2.60 <
2.25 <
25.16
2.91 <
2.57 <
50.42
2.12 <
4.44 <
2.92 <
1.45 *
5.01 <
4.18 <
3.84 <
1.47 <
4.91 <
1.14 <
4.70 <
2.78 <
0.85 <
3.63 <
1.49 <
7.27 <
4.91 <
0.99 *
2.40 *
2.66 <
1.19 <
2.63 <
5.20 <
1.98 <
4.68 <
3.58 <
4.40 <
0.78 *
0.83 <
222.49
0.56 <
0.48 <
0.86 *
1.58 <
103.97
0.58 <
0.63 <
0.44
0.62 <
0.62 <
0.63 <
0.56 <
0.72 <
0.66 <
(a-b)
TOTAL**
"3
59.59
2.65 <
2.08 <
1.95 <
5.19 *
2.05 <
4.19 <
2.30 <
2.79 <
2.70 <
4.20 <
4.31 <
2.46 <
1.31
3.62 <
2.40 <
2.08 <
236.25
2.68 <
2.38 <
0.00
1.96 <
4.10 <
2.69 <
1.56 *
4.58 <
3.83 <
3.51 <
1.35 <
4.49 <
1.05 <
4.30 <
2.55 <
0.78 <
3.32 <
1.37 <
6.65 <
4.49 <
0.52 *
1.10 *
2.43 <
1.09 <
2.40 <
4.39 <
1.67 <
3.95 <
3.02 <
3.72 <
1.31 *
0.70 <
0.00
0.47 <
0.37 <
1.55 *
1.22 <
35.43
0.45 <
0.48 <
16.78
0.48 <
0.48 <
0.49 <
0.43 <
0.55 <
0.51 <
GAS EMISSIONS
CONCENTRATION
ACTUAL
ug/Nm3
20.588
0.916 <
0.719 <
0.674 <
1.793 *
0.708 <
1.448 <
0.795 <
0.964 <
0.933 <
1.451 <
1.489 <
0.850 <
0.453
1.251 <
0.829 <
0.719 <
81 .623
0.926 <
0.822 <
0.000
0.677 <
1.417 <
0.929 <
0.539 *
1.582 <
1.323 <
1.213 <
0.466 <
1.551 <
0.363 <
1.486 <
0.881 <
0.269 <
1.147 <
0.473 <
2.298 <
1.551 <
0.180 *
0.380 *
0.840 <
0.377 <
0.829 <
1.517 <
0.577 <
1.365 <
1.043 <
1.285 <
0.453 *
0.242 <
0.000
0.162 <
0.128 <
0.536 *
0.422 <
12.241
0.155 <
0.166 <
5.797
0.166 <
0.166 <
0.169 <
0.149 <
0.190 <
0.176 <
a A 02
u9/Nm3
46.157
2.053 <
1.611 <
1.510 <
4.020 *
1.588 <
3.245 <
1.782 <
2.161 <
2.091 <
3.253 <
3.338 <
1.905 <
1.015
2.804 <
1.859 <
1.611 <
182.994
2.076 <
1.843 <
0.000
1.518 <
3.176 <
2.084 <
1.208 *
3.548 <
2.967 <
2.719 <
1.046 <
3.478 <
0.813 <
3.331 <
1.975 <
0.604 <
2.572 <
1.061 <
5.151 <
3.478 <
0.403 *
0.852 *
1.882 <
0.844 <
1.859 <
3.400 <
1.294 <
3.060 <
2.339 <
2.881 <
1.015 *
0.542 <
0.000
0.364 <
0.287 <
1.201 *
0.945 <
27.443
0.349 <
0.372 <
12.997
0.372 <
0.372 <
0.380 <
0.333 <
0.426 <
0.395 <
MASS
RATE
Ib/hr
3.15E-04
1.40E-05
1.10E-05
1 .03E-05
2.75E-05
1.08E-05
2.22E-05
1.22E-05
1.48E-05
1.43E-05
2.22E-05
2.28E-05
1.30E-05
6.93E-06
1.92E-05
1.27E-05
1.10E-05
1.25E-03
1.42E-05
1.26E-05
O.OOE+00
1.04E-05
2.17E-05
1.42E-05
8.26E-06
2.42E-05
2.03E-05
1.86E-05
7.14E-06
2.38E-05
5.56E-06
2.28E-OS
1.35E-05
4.13E-06
1.76E-05
7.25E-06
3.52E-05
2.38E-05
2.75E-06
5.82E-06
1.29E-05
5.77E-06
1.27E-05
2.32E-05
8.B4E-06
2.09E-05
1.60E-05
1 .97E-05
6.93E-06
3.70E-06
O.OOE+00
2.49E-06
1.96E-06
8.20E-06
6.46E-06
1.88E-04
2.38E-06
2.54E-06
8.88E-05
2.54E-06
2.54E-06
2.59E-06
2.28E-06
2.91E-06
2.70E-06
RUN NUMBER
SAMPLE VOLUME
TOTAL GAS FLOURATE
OXYGEN
SEMIVOLATILE COMPOUNDS
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-0ichlorobenzene
1,4-DichIorobenzene
1,2-Dichlorobenzene
Benzyl alcohol
2,2'-oxybis(1-Chloropropane)
2-Methylphenol
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
bis(2-Chloroethoxy)methane
Benzoic acid
2,4-Dichlorophenol
1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methylphenol
2-Methylnaphthalene
Hexachlorocyclopentadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethylphthalate
2,6-Dinitrotoluene
2,4-Dinitrotoluene
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
Diethylphthalate
4-Chlorophenyl-phenylether
Fluorene
4-Nitroaniline
4,6-Din1tro-2-methylphenol
N-Nitrosodiphenylamine
4-Bromophenyl-phenylether
HexachIorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butylphthalate
Fluoranthene
Pyrene
Butylbenzylphthalate
3,3'-Dichlorobenzidine
bis(2-Ethylhexyl)phthalate
Benzo(a)anthracene
Chrysene
Di-n-octylphthalate
Benzo(b)fIuoranthene
BenzoOOf luoranthene
Benzo(a)pyrene
Indeno(1,2,3-cd)pyrene
DibenzCa,h)anthracene
Benzo(g,h, i )perylene
< Not detected
* Detected but below the quantitation limit; quantity is
** If BLANK(ug) Not Detected, then TOTAL(ug) - SAMPLE (ug);
then TOTAL(ug) = 0.00
estimated
if BLANK(ug) > SAMPLE (ug),
-------
RUN NUMBER
KCE-N0010-R3
DATE
START TIME
END TIME
STACK DIAM.
NOZZLE I.D.
METER BOX GAMMA
METER BOX dH3
BAROMETRIC
Cp
TEST DURATION
METHOD 1-4 RESULTS
Metered Volume
Volume a Std.Cond.
X Water
X Isokinetics
Velocity
Actual Flow
Std. Flow
Dry Std. Flow
STACK
TEMP STATIC
POINT (DegF) (in. WO
1 314 0.19
2 319 0.17
3 328 0.11
4 312 0.13
5 322
6 340
7 341
8 341
9 342
10 341
11 342
12 315
13 316
14 313
15 341
16 342
17 342
18 335
19 339
20 332
21 329
22 318
23 347
24 345
25 319
26 324
27 322
28 331
29 337
30 335
31 348
32 349
33 347
34 344
35 343
36 324
37 330
38 332
39 338
40 340
41 338
42 340
43 336
44 334
45 322
46 321
47 332
48 346
49
AVG. 333 0.15
7/30/93
08:15
11:49
25 X 24
0.3125
1.00462
1.85206
29.97
0.84
192
120.078
115.462
7.99
105.5
29.06
7264
4848
4461
DP
(in.WC)
0.23
0.24
0.22
0.23
0.24
0.24
0.22
0.19
0.21
0.19
0.18
0.18
0.15
0.15
0.18
0.18
0.17
0.17
0.18
0.18
0.17
0.17
0.15
0.15
0.15
0.15
0.16
0.15
0.17
0.17
0.18
0.19
0.15
0.15
0.20
0.20
0.15
0.16
0.15
0.15
0.18
0.19
0.20
0.19
0.18
0.18
0.17
0.17
0.18
inches
inches
in.Hg
minutes
dcf
dscf
X
X
ft/sec
acfm
scfm
dscfm
DH
(in.WC)
1.65
1.80
1.50
1.65
.80
.80
.50
.20
.40
.20
.15
.15
0.96
0.96
1.15
1.15
1.10
1.10
1.15
1.15
1.10
1.10
0.96
0.96
0.96
0.96
1.00
0.96
1.10
1.10
1.15
1.20
0.96
0.96
1.30
1.30
0.96
1.00
0.96
0.96
1.15
1.20
1.30
1.20
1.15
1.15
1.10
1.10
1.21
METHOD 4
IMP.1
IMP. 2
IMP. 3
IMP. 4
IMP. 5
IMP. 6
IMP. 7
TOTAL
S.G.
METHOD 3
X02
XC02
XCO
XN2
02+C02
METER
VOLUME
(dcf)
881 .470
914.642
914.642
943.461
943.668
972.65
972.65
1001.755
120.078
DATA
INIT.
(ml)
0.0
100.0
100.0
0.0
200.0
200.0
DATA
10.1
9.6
0.0
80.3
19.7
FINAL
(ml)
189.0
100.0
101.0
0.0
390.0
223.1
Md
Ms
Ps
Fo
XEA
NET
(ml)
189.0
0.0
1.0
0.0
0.0
0.0
0.0
190.0
23.1
29.94
28.99
29.98
1.125
91
METER TEMPERATURE
INLET
(DegF)
78
76
78
79
81
82
82
83
84
85
86
89
93
94
94
97
98
100
101
102
103
104
106
105
100
100
101
101
101
104
105
107
108
110
109
109
103
102
105
106
104
104
102
103
103
102
102
104
OUTLET
(DegF)
78
77
77
77
77
78
78
79
80
80
82
86
91
93
93
96
97
98
99
100
100
101
102
101
99
100
100
99
99
100
101
102
102
104
103
103
100
100
101
101
100
100
99
99
98
98
98
99
94
-------
LABORATORY DATA AND RESULTS
SEMIVOLATILE COMPOUNDS
RUN NUMBER
SAMPLE VOLUME
TOTAL GAS FLOURATE
OXYGEN
KCE-N0010-R3
115.462 dscf
4461 dscfm
10.1 X
GAS EMISSIONS
<
<
<
*
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
*
<
<
<
<
<
<
<
<
*
<
<
<
<
<
*
<
<
<
<
<
<
<
<
<
<
<
*
*
<
<
<
<
<
<
<
<
<
(a)
SAMPLE
»g
83.37 *
2.77 <
2.17 <
2.03 <
6.16 <
2.14 <
4.37 <
2.40 <
2.91 <
2.81 <
4.38 <
4.50 <
2.66 <
1.42 <
3.91 <
2.60 <
2.25 <
526.35
2.90 <
2.57 <
55.73
2.12 <
4.44 <
2.91 <
3.22 <
4.89 <
4.09 <
3.75 <
1.44 <
4.80 <
1.12 <
4.60 <
2.72 <
2.79 <
3.55 <
1.46 <
7.10 <
4.80 <
0.96 <
3.42 *
2.60 <
1.16 <
2.57 <
4.86 <
1.85 <
4.37 <
3.35 <
4.11 <
0.73 <
0.78 <
47.71
0.52 <
0.39 <
1.57 <
1.29 <
262.00
0.47 <
0.51 <
10.19 <
0.50 <
0.50 <
0.51 <
0.45 <
0.58 <
0.53 <
(b)
BLANK
_U9_
6.46
2.69 <
2.11 <
1.97 <
1.96 *
2.08 <
4.25 <
2.33 <
2.83 <
2.73 <
4.26 <
4.37 <
2.66 <
1.42
3.91 <
2.60 <
2.25 <
25.16
2.91 <
2.57 <
50.42
2.12 <
4.44 <
2.92 <
1.45 *
5.01 <
4.18 <
3.84 <
1.47 <
4.91 <
1.14 <
4.70 <
2.78 <
0.85 *
3.63 <
1.49 <
7.27 <
4.91 <
0.99 <
2.40 *
2.66 <
1.19 <
2.63 <
5.20 <
1.98 <
4.68 <
3.58 <
4.40 <
0.78 <
0.83 <
222.49
0.56 <
0.48 *
0.86 *
1.58 <
103.97
0.58 <
0.63 <
0.44
0.62 <
0.62 <
0.63 <
0.56 <
0.72 <
0.66 <
(a-b)
TOTAL**
ug
76.91
2.77 <
2.17 <
2.03 <
6.16 *
2.14 <
4.37 <
2.40 <
2.91 <
2.81 <
4.38 <
4.50 <
2.66 <
1.42
3.91 <
2.60 <
2.25 <
501.19
2.90 <
2.57 <
5.31
2.12 <
4.44 <
2.91 <
3.22 *
4.89 <
4.09 <
3.75 <
1.44 <
4.80 <
1.12 <
4.60 <
2.72 <
2.79 *
3.55 <
1.46 <
7.10 <
4.80 <
0.96 <
1.02 *
2.60 <
1.16 <
2.57 <
4.86 <
1.85 <
4.37 <
3.35 <
4.11 <
0.73 <
0.78 <
0.00
0.52 <
0.39 *
1.57 *
1.29 <
158.03
0.47 <
0.51 <
10.19
0.50 <
0.50 <
0.51 <
0.45 <
0.58 <
0.53 <
CONCENTRATION
ACTUAL
ug/Nm3
25.244
0.909 <
0.712 <
0.666 <
2.022 *
0.702 <
1.434 <
0.788 <
0.955 <
0.922 <
1.438 <
1.477 <
0.873 <
0.466
1.283 <
0.853 <
0.739 <
164.507
0.952 <
0.844 <
1.743
0.696 <
1.457 <
0.955 <
1.057 *
1.605 <
1.342 <
1.231 <
0.473 <
1.576 <
0.368 <
1.510 <
0.893 <
0.916 *
1.165 <
0.479 <
2.330 <
1.576 <
0.315 <
0.335 *
0.853 <
0.381 <
0.844 <
1.595 <
0.607 <
1.434 <
1.100 <
1.349 <
0.240 <
0.256 <
0.000
0.171 <
0.128 *
0.515 *
0.423 <
51.871
0.154 <
0.167 <
3.345
0.164 <
0.164 <
0.167 <
0.148 <
0.190 <
0.174 <
3 7X 02
ug/Nm3
32.490
1.170 <
0.917 <
0.858 <
2.602 *
0.904 <
1.846 <
1.014 <
.229 <
.187 <
.850 <
.901 <
.124 <
0.600
1.652 <
1.098 <
0.951 <
211.727
1.225 <
1.086 <
2.243
0.896 <
1.876 <
1.229 <
1.360 *
2.066 <
1.728 <
1.584 <
0.608 <
2.028 <
0.473 <
1.943 <
1.149 <
1.179 *
1.500 <
0.617 <
2.999 <
2.028 <
0.406 <
0.431 *
1.098 <
0.490 <
1.086 <
2.053 <
0.782 <
1.846 <
1.415 <
1.736 <
0.308 <
0.330 <
0.000
0.220 <
0.165 *
0.663 *
0.545 <
66.759
0.199 <
0.215 <
4.305
0.211 <
0.211 <
0.215 <
0.190 <
0.245 <
0.224 <
MASS
RATE
Ib/hr
3.93E-04
1.42E-05
1.11E-05
1.04E-05
3.15E-05
1.09E-05
2.23E-05
1.23E-05
1.49E-05
1.44E-05
2.24E-05
2.30E-05
1.36E-05
7.26E-06
2.00E-05
1.33E-05
1.15E-05
2.56E-03
1.48E-05
1.31E-05
2.71E-05
1.08E-05
2.27E-05
1.49E-05
1.65E-05
2.50E-05
2.09E-05
1.92E-05
7.36E-06
2.45E-05
5.72E-06
2.35E-05
1.39E-05
1.43E-05
1.81E-05
7.46E-06
3.63E-05
2.45E-05
4.91E-06
5.21E-06
1.33E-05
5.93E-06
1.31E-05
2.48E-05
9.46E-06
2.23E-05
1.71E-05
2.10E-05
3.73E-06
3.99E-06
O.OOE+00
2.66E-06
1.99E-06
8.02E-06
6.59E-06
8.08E-04
2.40E-06
2.61E-06
5.21E-05
2.56E-06
2.56E-06
2.61E-06
2.30E-06
2.96E-06
2.71E-06
SEMI VOLATILE COMPOUNDS
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1 ,4-Dichtorobenzene
1,2-Dichlorobenzene
Benzyl alcohol
2,2l-oxybis(1-Chloropropane)
2-Methylphenol
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexach I oroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
bis(2-Chloroethoxy)methane
Benzoic acid
2,4-Dichlorophenol
1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexach I orobutadi ene
4-Chloro-3-methylphenol
2-Methylnaphthalene
Hexach I orocyc I opentadi ene
2,4,6-Trichlorophenol
2,4.5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethylphthalate
2,6-Dinitrotoluene
2,4-Dinitrotoluene
Acenaphthylene
3-Nitroani line
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
Diethylphthalate
4-Chlorophenyl-phenylether
Fluorene
4-Nitroani line
4,6-Dinitro-2-methylphenol
N - N i t rosod i pheny I ami ne
4-Bromophenyl -phenylether
Hexach I orobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butylphthalate
Fluoranthene
Pyrene
Butylbenzylphthalate
3,3'-Dichlorobenzidine
bis(2-Ethylhexyl)phthalate
Benzo( a ) anth racene
Chrysene
Di-n-octylphthalate
Benzo(b)f luoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indenod ,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h, i )perylene
< Not detected
* Detected but below the quantftation limit; quantity is estimated
** If BLANK(ug) Not Detected, then TOTAL(ug) = SAMPLE (ug); if BLANK(ug)
then TOTAL(ug) = 0.00
> SAMPLE (ug),
-------
APPENDIX D.I.7
DATA AND RESULTS FOR CONTINUOUS EMISSIONS MONITORING
(O2,CO2,CO, and NOx)
-------
Starting
07-31-93
EPA Brick WA 14
Kiln Combustion Exhaust
02/C02/CO/NOX
KCE-M201/202-R1
Time
11:46
11:47
11:48
11:49
11:50
11:51
11:52
11:53
11:54
11:55
11:56
11:57
11:58
11:59
12:00
12:01
12:02
12:03
12:04
12:05
12:06
12:07
12:08
12:09
12:10
12:11
12:12
12:13
12:14
12:15
12:16
12:17
12:18
12:19
12:20
12:21
12:22
12:23
12:24
02
%
DV
12.83
12.36
13.23
13.60
13.53
12.37
11.93
12.09
12.31
13.25
13.13
12.88
12.44
12.72
12.10
11.80
12.96
13.05
13.39
12.53
12.78
12.85
14.01
12.68
12.46
13.00
13.26
13.19
12.09
12.18
12.56
13.12
12.88
12.05
13.58
13.62
13.61
12.36
13.03
C02
%
DV
6.63
7.06
6.26
5.93
6.05
7.02
7.44
7.33
7.12
6.25
6.28
6.58
7.05
6.82
7.29
7.53
6.46
6.47
6.15
6.81
6.67
6.64
5.59
6.75
6.94
6.50
6.30
6.38
7.25
7.27
6.94
6.45
6.57
7.30
5.97
5.95
5.97
7.00
6.46
CO
PPMDV
335.30
327.20
314.10
320.50
315.00
343.30
311.90
297.20
302.70
320.40
336.00
330.40
321.50
313.90
333.60
317.70
317.40
318.60
318.80
342.50
321.70
321.50
315.80
336.10
323.30
311.00
314.30
309.10
341.20
304.80
307.60
303.70
328.20
331.50
319.50
321.80
313.80
337.90
303.50
NOX
PPMDV
160.20
152.60
162.70
164.10
159.40
128.90
129.80
142.50
154.30
150.00
163.50
181.40
180.60
155.60
132.10
136.90
173.90
179.70
157.90
150.70
174.60
170.90
162.00
144.10
162.90
176.80
181.30
148.70
140.70
157.40
175.60
167.70
152.20
153.10
170.00
176.20
161.60
149.00
174.00
-------
Starting
07-31-93
EPA Brick WA 14
Kiln Combustion Exhaust
02/C02/CO/NOX
KCE-M201/202-R1
Time
12:25
12:26
12:27
12:28
12:29
12:30
12:31
12:32
12:33
12:34
12:35
12:36
12:37
12:38
12:39
12:40
12:41
12:42
12:43
12:44
12:45
12:46
12:47
12:48
12:49
12:50
12:51
12:52
12:53
12:54
12:55
12:56
12:57
12:58
12:59
13:00
13:01
13:02
13:03
02
%
DV
13.27
13.90
13.31
12.46
13.42
12.77
13.04
11.75
12.70
13.27
13.38
13.40
13.19
13.71
13.28
13.71
12.37
12.60
13.62
14.05
12.84
11.59
12.90
13.15
13.29
12.86
12.85
13.00
12.83
13.26
12.10
12.65
12.49
12.85
11.80
12.26
13.34
13.52
12.77
C02
%
DV
6.25
5.71
6.14
6.91
6.05
6.77
6.50
7.57
6.73
6.23
6.17
6.06
6.15
5.82
6.29
5.88
6.98
6.84
5.92
5.56
6.64
7.74
6.53
6.36
6.24
6.61
6.61
6.51
6.72
6.23
7.18
6.81
6.98
6.67
7.56
7.11
6.16
6.04
6.73
CO
PPMDV
307.70
301.20
332.30
326.50
316.00
313.40
307.30
327.90
301.70
313.50
310.10
329.00
342.50
316.50
310.80
301.90
327.60
294.50
299.00
303.80
314.00
309.20
296.10
300.20
301.20
302.10
308.70
301.40
289.60
306.70
321.00
284.90
286.30
281.10
303.70
297.80
298.20
301.00
307.50
NOX
PPMDV
178.90
167.50
147.50
157.90
172.80
175.50
146.30
128.30
154.40
177.10
168.10
149.60
165.50
181.20
189.20
168.40
156.70
172.10
177.60
172.20
144.20
137.40
168.80
184.90
170.20
157.60
173.70
175.40
154.00
140.20
140.20
155.90
151.10
133.80
118.70
138.80
155.30
152.50
122.40
-------
Starting
07-31-93
EPA Brick WA 14
Kiln Combustion Exhaust
02/C02/CO/NOX
KCE-M201/202-R1
Time
13:04
13:05
13:06
13:07
13:08
13:09
13:10
13:11
13:12
13:13
13:14
13:15
13:16
13:17
13:18
13:19
13:20
13:21
13:22
13:23
13:24
99 MinAvg
02
DV
11.68
12.84
13.30
13.54
12.81
12.09
12.63
13.57
13.96
12.08
12.59
12.84
13.52
12.36
11.77
12.40
12.69
13.15
12.30
12.31
12.42
12.85
C02
DV
7.65
6.60
6.20
6.06
6.62
7.32
6.85
6.00
5.53
7.22
6.83
6.63
6.02
6.98
7.54
7.03
6.78
6.31
6.95
7.08
7.00
6.61
CO
PPMDV
308.80
278.70
287.40
273.90
314.10
285.70
278.70
286.60
304.80
327.40
284.20
294.30
291.20
324.20
305.10
284.40
292.30
295.80
332.50
290.70
287.50
310.37
NOX
PPMDV
105.20
130.40
148.10
132.90
124.20
118.70
144.00
136.40
129.40
121.10
141.10
155.10
151.10
126.80
122.90
143.00
142.90
125.10
122.30
134.80
145.60
153.52
Data Corrected for Calibrations
99 MinAvg 13.12 6.62
320.06
159.72
-------
Calibrations:
02 25 Span Value = 25
LOW Calibration Gas = 0.00 HIGH Calibration Gas = 22.00
Initial Cal. at: 1133
LOW Cal. Response = 0.05
Cal. Drift = 0.00
Final Cal. at: 1640
LOW Cal. Response = 0.02
Cal. Drift = 0.00
LOW System Drift = -0.00
HIGH Cal. Response =
Cal. Drift =
HIGH Cal. Response -
Cal. Drift =
HIGH System Drift =
21.59
-0.02
21.45
-0.02
-0.01
C02 20 Span Value = 20
LOW Calibration Gas = 0.00 HIGH Calibration Gas =
Initial Cal. at: 1133
0.01
18.20
LOW Cal. Response =
Cal. Drift = 0.00
Final Cal. at: 1640
LOW Cal. Response = 0.01
Cal. Drift = 0.00
LOW System Drift = 0.00
HIGH Cal. Response = 18.23
Cal. Drift = 0.00
HIGH Cal. Response = 18.10
Cal. Drift = -0.00
HIGH System Drift = -0.01
CO 1000 Span Value = 1000
LOW Calibration Gas = 0.00 HIGH Calibration Gas = 929.00
Initial Cal. at: 1142
-0.38 HIGH Cal. Response = 906.00
-0.00 Cal. Drift = -0.02
LOW Cal. Response =
Cal. Drift =
Final Cal. at: 1640
LOW Cal. Response =
Cal. Drift =
LOW System Drift =
-0.17 HIGH Cal. Response = 896.78
-0.00 Cal. Drift = -0.03
0.00 HIGH System Drift = -0.01
NOx 250 Span Value = 250
LOW Calibration Gas = 0.00 HIGH Calibration Gas = 257.00
Initial Cal. at: 1137
-0.31 HIGH Cal. Response = 250.50
-0.00 Cal. Drift = -0.03
LOW Cal. Response =
Cal. Drift =
Final Cal. at: 1640
LOW Cal. Response =
Cal. Drift -
LOW System Drift =
0.92 HIGH Cal. Response = 243.17
0.00 Cal. Drift = -0.06
0.00 HIGH System Drift = -0.03
-------
EPA Brick WA 14
Kiln Combustion Exhaust
O2/C02/CO/NOX
KCE-M201/202-R2
Starting
07-31-93
Time
14:08
14:09
14:10
14:11
14:12
14:13
14:14
14:15
14:16
14:17
14:18
14:19
14:20
14:21
14:22
14:23
14:24
14:25
14:26
14:27
14:28
14:29
14:30
14:31
14:32
14:33
14:34
14:35
14:36
14:37
14:38
14:39
14:40
14:41
14:42
14:43
14:44
14:45
14:46
02
%
DV
12.56
13.53
12.74
11.93
12.26
12.93
13.67
12.29
12.83
13.74
13.54
12.86
11.62
12.42
13.08
13.02
11.70
12.83
12.92
12.97
12.07
11.99
13.47
13.64
13.01
11.46
12.13
12.91
13.47
12.77
11.94
13.01
13.34
13.00
11.55
12.23
12.72
13.54
13.04
C02
%
DV
6.86
5.98
6.59
7.35
7.10
6.52
5.75
6.98
6.56
5.70
5.91
6.47
7.62
6.96
6.35
6.41
7.52
6.54
6.49
6.51
7.23
7.30
5.96
5.83
6.44
7.75
7.20
6.51
6.02
6.56
7.36
6.44
6.14
6.47
7.68
7.14
6.70
5.97
6.28
CO
PPMDV
306,50
302.30
327.60
316.40
298.80
299.60
312.40
337.20
298.80
301.20
306.30
324.70
319.30
305.10
316.70
314.50
330.30
305.10
310.10
301.40
326.50
317.00
310.60
317.00
308.10
318.50
296.40
305.60
306.50
324.60
319.60
303.00
309.10
300.30
322.40
293.20
302.30
304.60
336.80
NOX
PPMDV
176.00
159.10
140.40
139.60
149.90
150.50
137.00
133.40
144.70
154.00
166.80
153.30
149.00
173.30
173.70
153.40
138.90
175.30
180.30
165.60
136.90
152.60
173.30
179.20
155.30
138.30
167.60
182.80
169.70
153.40
155.90
172.20
172.40
156.60
143.30
172.10
179.70
167.50
150.60
-------
Starting
07-31-93
EPA Brick WA 14
Kiln Combustion Exhaust
02/CO2/CO/NOX
KCE-M201/202-R2
Time
14:47
14:48
14:49
14:50
14:51
14:52
14:53
14:54
14:55
14:56
14:57
14:58
14:59
15:00
15:01
15:02
15:03
15:04
15:05
15:06
15:07
15:08
15:09
15:10
15:11
15:12
15:13
15:14
15:15
15:16
15:17
15:18
15:19
15:20
15:21
15:22
15:23
15:24
15:25
02
%
DV
11.95
12.37
12.77
12.79
12.34
13.38
12.75
13.08
12.03
12.39
12.48
14.11
13.93
12.42
13.82
13.13
13.13
12.40
13.02
13.84
13.02
13.38
12.16
12.99
13.22
13.56
12.35
12.61
13.15
13.56
13.44
12.81
12.95
13.11
13.44
12.74
13.00
13.33
12.71
C02
%
DV
7.39
7.04
6.70
6.64
6.92
6.03
6.71
6.43
7.29
6.91
6.89
5.42
5.55
6.87
5.65
6.33
6.39
6.93
6.35
5.63
6.43
6.08
7.08
6.42
6.22
5.97
6.97
6.70
6.21
5.87
5.94
6.38
6.37
6.24
5.97
6.49
6.28
6.00
6.66
CO
PPMDV
312.80
299.10
302.40
309.50
331.30
313.30
311.30
297.80
322.10
312.90
312.30
311.20
315.40
335.30
306.10
305.10
290.70
318.20
309.90
301.50
304.90
304.50
332.00
303.40
306.10
283.00
312.50
300.60
290.20
293.80
301.30
328.20
297.30
300.40
298.40
328.90
311.30
305.40
298.90
NOX
PPMDV
152.40
174.30
176.20
153.20
155.60
174.40
179.50
163.70
137.10
146.50
166.00
169.20
152.50
157.10
163.10
182.90
165.50
146.20
156.90
168.70
165.40
159.20
150.60
170.20
169.80
149.10
119.70
134.70
157.40
157.90
135.70
140.70
158.40
169.00
162.70
152.40
157.00
175.90
175.20
-------
Starting
07-31-93
EPA Brick WA 14
Kiln Combustion Exhaust
02/C02/CO/NOX
KCE-M201/202-R2
Time
15:26
15:27
15:28
15:29
15:30
15:31
15:32
15:33
15:34
15:35
15:36
15:37
15:38
15:39
15:40
15:41
15:42
15:43
15:44
15:45
15:46
15:47
15:48
15:49
15:50
15:51
15:52
15:53
15:54
15:55
108 MinAvg
02
DV
12.87
11.49
12.37
12.39
12.96
11.83
12.24
13.57
13.42
12.79
11.71
12.28
12.74
13.40
12.48
12.20
13.01
12.61
12.57
11.25
12.53
12.86
13.42
12.36
12.62
12.71
12.79
12.68
11.40
12.82
12.77
C02
DV
6.48
7.65
6.90
6.91
6.41
7.34
6.98
5.78
5.96
6.55
7.44
6.97
6.56
5.95
6.68
6.97
6.24
6.66
6.69
7.79
6.66
6.36
5.92
6.74
6.55
6.54
6.53
6.57
7.65
6.40
6.58
CO
PPMDV
301.50
317.20
293.70
299.90
295.40
323.20
314.70
316.10
317.10
311.90
321.80
287.40
300.70
302.50
332;40
324.70
321.90
322.00
320.50
336.10
307.50
320.00
314.30
339.80
325.70
319.90
310.60
319.90
330.90
315.40
311.49
NOX
PPMDV
150.60
135.00
165.40
169.80
164.80
133.70
151.70
166.00
176.20
147.50
140.90
171.40
184.20
167.30
155.70
163.60
174.60
165.10
142.80
130.90
170.30
177.30
161.40
145.60
160.70
174.60
167.40
143.40
138.50
171.30
158.92
-------
EPA Brick WA 14
Kiln Combustion Exhaust
02/C02/CO/NOX
KCE-M201/202-R2
Starting
07-31-93
Time
02 C02 CO
DV DV PPMDV
NOX
PPMDV
Data Corrected for Calibrations
108 MinAvg 13.04 6.58
321.21
165.35
-------
Calibrations:
O2 25 Span Value = 25
LOW Calibration Gas = 0.00 HIGH Calibration Gas = 22.00
Initial Cal. at: 1133
0.05
0.00
LOW Cal. Response =
Cal. Drift =
HIGH Cal. Response -
Cal. Drift =
Final Cal. at: 1640
LOW Cal. Response = 0.02
Cal. Drift = 0.00
21.59
-0.02
HIGH Cal. Response = 21.45
Cal. Drift = -0.02
LOW System Drift = -0.00 HIGH System Drift = -0.01
C02 20 Span Value = 20
LOW Calibration Gas = 0.00 HIGH Calibration Gas
Initial Cal. at: 1133
0.01
0.00
LOW Cal. Response =
Cal. Drift =
Final Cal. at: 1640
LOW Cal. Response =
Cal. Drift =
LOW System Drift =
HIGH Cal. Response =
Cal. Drift =
0.01 HIGH Cal. Response =
0.00 Cal. Drift =
0.00 HIGH System Drift =
18.20
18.23
0.00
18.10
-0.00
-0.01
-------
Calibrations:
CO 1000 Span Value = 1000
LOW Calibration Gas = 0.00 HIGH Calibration Gas
Initial Cal. at: 1142
929.00
LOW Cal. Response = -0.38
Cal. Drift = -0.00
Final Cal. at: 1640
LOW Cal. Response = -0.17
Cal. Drift = -0.00
LOW System Drift = 0.00
HIGH Cal. Response = 906.00
Cal. Drift = -0.02
HIGH Cal. Response = 896.78
Cal. Drift = -0.03
HIGH System Drift = -0.01
NOx 250 Span Value = 250
LOW Calibration Gas = 0.00 HIGH Calibration Gas = 257.00
Initial Cal. at: 1137
-0.31 HIGH Cal. Response = 250.50
-0.00 Cal. Drift = -0.03
LOW Cal. Response =
Cal. Drift =
Final Cal. at: 1640
LOW Cal. Response =
Cal. Drift =
LOW System Drift =
0.92 HIGH Cal. Response = 243.17
0.00 Cal. Drift = -0.06
0.00 HIGH System Drift = -0.03
-------
Starting
07-31-93
EPA Brick WA 14
Kiln Combustion Exhaust
02/C02/CO/NOX
KCE-M201/202-R3
Time
16:49
16:50
16:51
16:52
16:53
16:54
16:55
16:56
16:57
16:58
16:59
17:00
17:01
17:02
17:03
17:04
17:05
17:06
17:07
17:08
17:09
17:10
17:11
17:12
17:13
17:14
17:15
17:16
17:17
17:18
17:19
17:20
17:21
17:22
17:23
17:24
17:25
17:26
17:27
02
%
DV
13.10
12.48
13.23
12.75
12.22
11.87
12.87
13.52
12.43
12.96
12.64
13.27
12.19
12.13
13.62
13.17
12.72
11.52
12.49
13^55
13.66
12.41
12.29
12.95
13.16
12.53
11.72
12.51
13.00
13.51
11.69
12.33
12.51
13.30
12.90
12.85
12.86
12.57
13.17
C02
%
DV
6.24
6.86
6.18
6.47
7.02
7.40
6.51
5.83
6.79
6.39
6.73
6.16
7.03
7.11
5.78
6.26
6.64
7.64
6.81
5.83
5.79
6.81
6.97
6.41
6.24
6.78
7.42
6.73
6.34
5.90
7.47
6.93
6.80
6.11
6.40
6.33
6.46
6.78
6.21
CO
PPMDV
332.50
332.70
324.80
362.00
345.10
336.60
337.50
356.10
362.70
334.00
337.00
331.10
354.90
336.00
352.30
346.20
341.20
342.30
324.80
342.80
347.40
361.30
333.70
333.40
332.20
338.40
336.20
330.10
341.20
334.20
351.10
323.10
329.80
323.30
339.40
358.50
348.50
339.60
329.10
NOX
PPMDV
185.40
187.50
161.00
144.70
154.10
174.80
174.20
141.00
166.80
182.00
183.40
154.90
147.10
163.00
171.50
170.10
145.90
139.20
170.20
176.30
160.70
150.00
167.30
180.20
168.60
148.20
138.40
176.50
185.00
163.70
136.70
162.60
174.40
172.40
149.10
159.50
180.40
183.80
157.40
-------
Starting
07-31-93
EPA Brick WA 14
Kiln Combustion Exhaust
02/C02/CO/NOX
KCE-M201/202-R3
Time
17:28
17:29
17:30
17:31
17:32
17:33
17:34
17:35
17:36
17:37
17:38
17:39
17:40
17:41
17:42
17:43
17:44
17:45
17:46
17:47
17:48
17:49
17:50
17:51
17:52
17:53
17:54
17:55
17:56
17:57
17:58
17:59
18:00
18:01
18:02
18:03
18:04
18:05
18:06
02
%
DV
12.11
12.24
12.75
13.39
12.95
12.14
13.16
13.25
13.11
11.66
12.17
12.74
13.83
13.24
11.68
12.41
12.89
13.38
12.07
12.40
12.90
12.71
12.50
12.09
12.83
13.13
13.50
11.69
12.57
12.96
13.56
12.41
11.67
12.42
12.73
13.47
11.80
12.27
13.18
C02
%
DV
7.05
6.99
6.56
5.99
6.36
7.04
6.19
6.14
6.31
7.52
7.07
6.57
5.61
6.09
7.50
6.90
6.48
6.02
7.11
6.86
6.44
6.67
6.81
7.07
6.53
6.29
5.93
7.49
6.70
6.38
5.88
6.89
7.49
6.86
6.62
5.93
7.32
6.99
6.17
CO
PPMDV
359.70
328.60
332.80
327.80
346.20
344.30
335.60
336.40
332.20
354.80
322.60
330.20
334.90
354.70
343.30
321.70
328.00
330.00
358.10
323.30
330.70
325.00
346.50
356.20
344.30
326.50
339.70
361.20
331.30
339.80
335.00
347.60
340.30
331.20
336.00
334.40
366.00
327.70
342.00
NOX
PPMDV
146.20
162.50
179.30
171.60
153.70
159.90
180.10
182.30
158.70
132.30
164.10
178.90
168.40
150.60
152.30
179.50
181.10
165.00
159.00
171.20
187.30
174.60
149.90
162.20
176.60
168.50
155.50
135.00
166.80
180.50
171.00
145.80
143.50
178.70
169.70
153.30
141.00
162.90
178.20
-------
Starting
07-31-93
EPA Brick WA 14
Kiln Combustion Exhaust
02/C02/CO/NOX
KCE-M201/202-R3
Time
18:07
18:08
18:09
18:10
18:11
18:12
18:13
18:14
18:15
18:16
18:17
18:18
18:19
18:20
18:21
18:22
18:23
18:24
18:25
18:26
98 MinAvg
02
DV
14.19
12.48
12.05
12.82
14.18
13.91
11.79
12.89
13.83
13.54
12.03
0.10
0.04
2.42
20.63
21.24
21.67
16.47
0.12
2.78
12.45
C02
DV
5.30
6.83
7.15
6.49
5.30
5.56
7.39
6.42
5.60
5.93
5.78
0.02
0.02
0.02
3.89
11.65
17.83
10.44
0.03
0.03
6.40
CO
PPMDV
339.50
355.90
331.20
332.80
334.30
334.60
354.00
324.30
339.10
326.80
352.50
123.60
-0.03
-0.07
-0.18
0.53
-0.66
-1.07
0.49
0.84
309.37
NOX
PPMDV
163.00
139.30
131.50
172.20
169.10
151.60
145.40
164.30
175.60
175.30
158.30
0.04
-0.91
-1.05
-0.72
-0.91
-1.23
32.40
255.90
231.70
153.74
Data Corrected for Calibrations
98 MinAvg 12.01 6.47
307.62
153.33
-------
Calibrations:
O2 25 Span Value = 25
LOW Calibration Gas = 0.00 HIGH Calibration Gas = 22.00
Initial Cal. at: 1640
LOW Cal. Response = 0.02
Cal. Drift = 0.00
Final Cal. at: 1839
LOW Cal. Response = 2.94
Cal. Drift = 0.12
LOW System Drift = 0.12
HIGH Cal. Response =
Cal. Drift =
HIGH Cal. Response =
Cal. Drift =
HIGH System Drift =
21.45
-0.02
21.69
-0.01
0.01
CO2 20 Span Value = 20
LOW Calibration Gas = 0.00 HIGH Calibration Gas =
Initial Cal. at: 1640
0.01
0.00
18.20
LOW Cal. Response =
Cal. Drift =
Final Cal. at: 1839
LOW Cal. Response =
Cal. Drift =
LOW System Drift =
HIGH Cal. Response =
Cal. Drift =
18.10
-0.00
0.01 HIGH Cal. Response = 17.86
0.00 Cal. Drift = -0.02
0.00 HIGH System Drift = -0.01
CO 1000 Span Value = 1000
LOW Calibration Gas = 0.00 HIGH Calibration Gas = 929.00
Initial Cal. at: 1641
-0.20 HIGH Cal. Response = 939.00
-0.00 Cal. Drift = 0.01
LOW Cal. Response =
Cal. Drift =
Final Cal. at: 1839
LOW Cal. Response =
Cal. Drift =
LOW System Drift =
0.00 HIGH Cal. Response = 929.97
0.00 Cal. Drift = 0.00
0.00 HIGH System Drift = -0.01
NOx 250 Span Value = 250
LOW Calibration Gas = 0.00 HIGH Calibration Gas = 257.00
Initial Cal. at: 1641
LOW Cal. Response = -0.40
Cal. Drift = -0.00
Final Cal. at: 1839
LOW Cal. Response = -0.48
Cal. Drift = -0.00
LOW System Drift = -0.00
HIGH Cal. Response = 256.70
Cal. Drift = -0.00
HIGH Cal. Response = 259.26
Cal. Drift = 0.01
HIGH System Drift = 0.01
-------
Starting
07-30-93
EPA Brick WA 14
Kiln Combustion Exhaust
O2/C02/CO/NOX
KSO-M3A/10B/7E-R1
Time
12:29
12:30
12:31
12:32
12:33
12:34
12:35
12:36
12:37
12:38
12:39
12:40
12:41
12:42
12:43
12:44
12:45
12:46
12:47
12:48
12:49
12:50
12:51
12:52
12:53
12:54
12:55
12:56
12:57
12:58
12:59
13:00
13:01
13:02
13:03
13:04
13:05
13:06
13:07
02
%
DV
12.67
13.25
14.06
12.61
12.16
13.42
14.16
13.84
12.54
13.36
14.04
14.04
13.20
12.05
13.04
13.25
13.69
12.38
12.57
12.56
13.63
13.58
12.68
12.64
13.61
14.26
12.51
13.42
13.03
13.03
13.17
12.31
13.59
14.10
13.53
12.03
12.82
13.28
13.89
C02
%
DV
7.04
6.51
5.82
7.10
7.40
6.28
5.63
5.97
7.04
6.29
5.76
5.80
6.49
7.43
6.60
6.43
6.06
7.14
7.03
7.05
6.09
6.05
6.84
6.98
6.06
5.51
7.02
6.17
6.65
6.66
6.50
7.16
6.09
5.68
6.28
7.50
6.78
6.42
5.89
CO
PPMDV
323.90
324.40
320.40
341.00
327.60
315.50
325.60
322.90
343.00
313.60
308.20
296.20
325.50
328.80
314.50
320.20
316.70
343.50
311.60
307.90
303.90
331.60
341.20
310.70
305.30
311.10
339.70
311.60
312.80
298.40
314.10
326.00
312.40
321.80
307.50
317.50
305.70
310.50
317.20
NOX
PPMDV
172.10
176.70
164.00
130.20
139.80
163.60
168.00
154.40
145.60
160.80
170.30
165.90
149.20
153.30
173.30
179.80
159.90
146.70
161.90
174.80
173.10
143.80
164.40
179.70
173.50
156.40
151.90
168.60
186.20
172.70
151.60
163.70
179.40
176.30
152.30
133.80
164.40
181.00
165.90
-------
Starting
07-30-93
EPA Brick WA 14
Kiln Combustion Exhaust
02/C02/CO/NOX
KSO-M3A/10B/7E-R1
Time
13:08
13:09
13:10
13:11
13:12
13:13
13:14
13:15
13:16
13:17
13:18
13:19
13:20
13:21
13:22
13:23
13:24
13:25
13:26
13:27
13:28
13:29
13:30
13:31
13:32
13:33
13:34
13:35
13:36
13:37
13:38
13:39
13:40
13:41
13:42
13:43
13:44
13:45
13:46
02
%
DV
13.69
11.87
13.13
13.48
14.53
12.63
13.40
13.75
13.89
13.53
12.93
12.67
12.76
13.22
12.01
12.39
13.30
13.51
14.08
12.55
12.62
12.71
13.69
13.09
12.44
12.77
13.75
13.20
11.75
12.87
12.83
13.57
12.67
12.55
13.38
12.95
13.02
11.56
13.52
C02
%
DV
6.09
7.65
6.56
6.24
5.36
7.00
6.25
6.03
5.99
6.28
6.71
7.06
6.99
6.60
7.62
7.18
6.45
6.30
5.73
7.06
7.09
7.01
6.07
6.55
7.16
6.91
6.00
6.54
7.73
6.72
6.82
6.14
6.91
6.94
6.26
6.74
6.66
7.86
6.02
CO
PPMDV
328.70
320.60
302.90
322.90
314.70
329.60
312.00
319.10
311.00
321.80
331.90
311.20
310.30
298.70
321.60
313.60
319.90
317.30
317.20
334.80
302.00
300.90
302.90
328.70
316.50
298.10
309.50
319.90
330.70
314.70
315.20
309.10
335.80
319.10
314.90
310.30
311.50
327.00
314.30
NOX
PPMDV
145.80
139.80
161.00
174.10
155.70
147.90
169.10
185.20
183.40
150.80
157.50
174.50
177.80
150.50
129.00
158.50
184.10
177.10
153.70
162.10
177.40
167.30
153.70
149.00
170.30
170.00
170.60
141.70
134.90
170.60
176.90
152.40
140.00
146.70
169.20
164.90
143.30
125.30
154.50
-------
EPA Brick WA 14
Kiln Combustion Exhaust
O2/C02/CO/NOX
KSO-M3A/10B/7E-R1
Starting
07-30-93
Time
13:47
13:48
13:49
13:50
13:51
13:52
13:53
13:54
13:55
13:56
13:57
13:58
13:59
14:00
14:01
14:02
14:03
14:04
14:05
14:06
14:07
14:08
14:09
14:10
14:11
14:12
14:13
14:14
14:15
14:16
14:17
14:18
14:19
14:20
14:21
14:22
14:23
14:24
14:25
02
%
DV
13.36
13.41
12.14
11.97
12.74
14.23
13.70
12.10
12.29
12.99
14.75
13.34
12.07
12.99
13.62
13.75
12.22
13.03
13.30
13.48
12.31
11.69
12.37
12.62
13.31
12.88
12.49
12.92
13.50
13.06
11.74
12.52
12.77
14.09
12.64
12.59
12.60
13.61
13.72
C02
%
DV
6.27
6.29
7.41
7.48
6.81
5.44
5.98
7.35
7.23
6.61
4.96
6.25
7.41
6.59
5.99
5.93
7.22
6.52
6.32
6.20
7.24
7.68
7.13
6.93
6.28
6.54
7.03
6.67
6.14
6.48
7.64
6.98
6.75
5.53
6.90
6.93
6.94
5.99
5.84
CO
PPMDV
320.60
307.80
322.00
315.90
314.80
324.40
324.30
337.60
308.00
303.70
311.80
344.70
324.60
302.90
309.30
305.10
327.00
311.10
310.40
305.90
323.00
320.10
310.80
308.60
310.00
344.20
317.20
303.20
297.30
320.20
318.70
297.90
315.50
321.40
334.40
308.00
305.70
305.10
326.80
NOX
PPMDV
178.20
168.00
129.80
142.70
164.20
162.20
149.40
148.50
156.80
165.60
139.30
146.20
150.00
166.60
171.50
158.50
149.70
174.60
168.90
160.30
128.30
138.50
161.10
168.10
139.70
144.80
159.40
163.10
150.60
134.50
134.00
161.50
168.30
151.70
138.60
152.60
163.60
162.50
140.40
-------
Starting
07-30-93
EPA Brick WA 14
Kiln Combustion Exhaust
02/C02/CO/NOX
KSO-M3A/10B/7E-R1
Time
14:26
14:27
14:28
14:29
14:30
14:31
14:32
14:33
14:34
14:35
14:36
14:37
14:38
14:39
14:40
14:41
14:42
14:43
14:44
14:45
137 MinAvg
02
DV
12.47
12.39
12.82
13.97
12.63
13.10
12.97
12.84
13.55
12.88
12.82
12.80
13.30
13.10
13.50
13.36
13.40
13.26
12.72
13.86
13.06
C02
DV
6.92
7.10
6.68
5.65
6.79
6.34
6.57
6.71
6.00
6.53
6.71
6.78
6.29
6.30
5.99
6.21
6.19
6.29
6.62
5.69
6.56
CO
PPMDV
333.90
306.70
310.10
314.70
337.70
319.10
313.00
302.10
309.40
330.90
311.40
300.40
294.90
337.20
324.30
310.00
309.40
315.60
332.00
313.90
316.92
NOX
PPMDV
157.10
165.30
173.10
148.90
148.10
159.90
174.30
165.50
150.90
164.30
177.90
169.20
149.40
139.60
164.20
173.80
166.70
133.30
142.10
164.20
158.87
Data Corrected for Calibrations
137 MinAvg 13.16 6.53
318.26
160.36
-------
Calibrations:
02 25 Span Value = 25
LOW Calibration Gas = 0.00 HIGH Calibration Gas =
Initial Cal. at: 935
22.00
LOW Cal. Response = 0.03
Cal. Drift = 0.00
Final Cal. at: 1505
LOW Cal. Response = 0.04
Cal. Drift = 0.00
LOW System Drift = 0.00
HIGH Cal. Response = 22.00
Cal. Drift - 0.00
HIGH Cal. Response = 21.60
Cal. Drift = -0.02
HIGH System Drift = -0.02
C02 20 Span Value = 20
LOW Calibration Gas = 0.00 HIGH Calibration Gas
Initial Cal. at: 1002
18.20
LOW Cal. Response = -0.00
Cal. Drift = -0.00
Final Cal. at: 1505
LOW Cal. Response = 0.02
Cal. Drift = 0.00
LOW System Drift = 0.00
HIGH Cal. Response =
Cal. Drift =
HIGH Cal. Response =
Cal. Drift =
HIGH System Drift =
18.28
0.00
18.24
0.00
-0.00
CO 1000 Span Value - 1000
LOW Calibration Gas = 0.00 HIGH Calibration Gas = 929.00
Initial Cal. at: 1002
-0.03 HIGH Cal. Response = 929.00
-0.00 Cal. Drift = 0.00
LOW Cal. Response =
Cal. Drift =
Final Cal. at: 1505
LOW Cal. Response =
Cal. Drift =
LOW System Drift =
0.00 HIGH Cal. Response = 921.21
0.00 Cal. Drift = -0.01
0.00 HIGH System Drift = -0.01
NOx 250 Span Value = 250
LOW Calibration Gas = 0.00 HIGH Calibration Gas = 257.00
Initial Cal. at: 950
HIGH Cal. Response
LOW Cal. Response = 0.11
Cal. Drift = 0.00
Final Cal. at: 1505
LOW Cal. Response = -0.23
Cal. Drift = -0.00
LOW System Drift = -0.00
Cal. Drift =
257.70
0.00
HIGH Cal. Response = 251.61
Cal. Drift = -0.02
HIGH System Drift = -0.02
-------
Calibrations:
VOC 100 Span Value = 100
LOW Calibration Gas = 0.00 HIGH Calibration Gas = 24.58
Initial Cal. at: 846
LOW Cal. Response = 0.04 HIGH Cal. Response = 24.82
Cal. Drift - 0.00 Cal. Drift - 0.00
Final Cal. at: 1751
LOW Cal. Response = 0.09 HIGH Cal. Response = 25.29
Cal. Drift = 0.00 Cal. Drift = 0.01
LOW System Drift = 0.00 HIGH System Drift = 0.00
-------
Starting
07-30-93
EPA Brick WA 14
Kiln Combustion Exhaust
02/C02/CO/NOX
KSO-M3A/10B/7E-R2
Time
15:13
15:14
15:15
15:16
15:17
15:18
15:19
15:20
15:21
15:22
15:23
15:24
15:25
15:26
15:27
15:28
15:29
15:30
15:31
15:32
15:33
15:34
15:35
15:36
15:37
15:38
15:39
15:40
15:41
15:42
15:43
15:44
15:45
15:46
15:47
15:48
15:49
15:50
15:51
02
%
DV
13.04
13.64
12.52
11.77
12.79
12.77
13.57
11.82
12.23
12.57
13.50
13.03
12.56
12.59
12.85
13.37
12.36
12.77
13.12
13.45
13.14
12.57
13.45
13.03
13.58
12.16
12.06
12.55
13.87
13.07
11.69
12.45
12.66
13.32
12.38
12.03
12.57
13.66
13.44
CO2
%
DV
6.20
5.68
6.68
7.26
6.35
6.40
5.68
7.20
6.85
6.55
5.72
6.11
6.48
6.57
6.34
5.83
6.65
6.31
6.01
5.74
5.96
6.42
5.67
6.07
5.57
6.79
6.96
6.48
5.26
5.98
7.19
6.53
6.35
5.73
6.49
6.85
6.39
5.39
5.56
CO
PPMDV
319.80
306.00
323.80
316.70
308.90
317.30
310.30
334.80
313.10
307.10
310.40
327.50
337.50
311.30
306.70
308.80
338.60
315.20
325.60
320.10
332.10
338.30
319.80
317.90
309.60
328.10
310.70
306.90
321.70
329.10
326.30
298.70
305.60
302.00
332.90
320.70
308.40
311.70
321.60
NOx
PPMDV
172.50
159.50
131.60
134.70
150.40
166.60
141.00
124.90
154.00
165.00
160.80
135.70
150.80
161.60
165.00
147.40
143.60
158.30
169.30
159.20
142.90
144.40
163.00
175.40
154.00
139.90
154.50
162.20
151.40
134.70
123.30
149.20
154.00
145.30
131.90
137.80
152.90
146.40
135.90
-------
Starting
07-30-93
EPA Brick WA 14
Kiln Combustion Exhaust
02/C02/CO/NOX
KSO-M3A/10B/7E-R2
Time
15:52
15:53
15:54
15:55
15:56
15:57
15:58
15:59
16:00
16:01
16:02
16:03
16:04
16:05
16:06
16:07
16:08
16:09
16:10
16:11
16:12
16:13
16:14
16:15
16:16
16:17
16:18
16:19
16:20
16:21
16:22
16:23
16:24
16:25
16:26
16:27
16:28
16:29
16:30
02
%
DV
11.91
12.32
12.40
13.30
12.77
12.49
12.42
12.67
13.30
12.03
12.63
12.31
12.86
13.05
12.66
13.15
13.36
13.43
12.24
12.70
12.79
13.44
12.32
11.77
12.55
13.07
13.39
12.35
12.76
12.49
12.97
13.30
12.47
12.77
12.48
12.95
12.04
12.75
11.99
C02
%
DV
6.91
6.60
6.53
5.71
6.10
6.36
6.53
6.32
5.70
6.76
6.28
6.62
6.13
5.84
6.19
5.83
5.66
5.58
6.57
6.20
6.18
5.59
6.59
7.05
6.37
5.90
5.62
6.47
6.15
6.47
6.05
5.64
6.46
6.24
6.55
6.06
6.79
6.16
6.96
CO
PPMDV
333.90
308.60
307.30
307.90
326.50
333.40
313.80
317.30
312.60
335.80
316.70
312.20
308.20
327.20
339.40
315.10
315.40
312.00
333.40
317.50
312.20
311.10
325.70
332.60
313.60
322.60
323.90
343.10
331.60
320.40
310.10
326.60
341.70
309.00
304.80
311.50
352.60
325.40
327.30
NOX
PPMDV
129.40
149.10
157.60
149.60
129.30
146.60
157.90
154.40
135.40
131.40
156.80
157.80
146.70
129.50
150.90
162.80
160.90
142.50
135.90
157.70
153.00
147.10
120.50
120.60
143.20
150.50
135.10
127.00
146.20
156.50
143.70
130.00
138.10
161.10
158.50
139.10
128.60
135.00
149.40
-------
EPA Brick WA 14
Kiln Combustion Exhaust
02/C02/CO/NOX
KSO-M3A/10B/7E-R2
Starting
07-30-93
Time
16:31
16:32
16:33
16:34
16:35
16:36
16:37
16:38
16:39
16:40
16:41
16:42
16:43
16:44
16:45
16:46
16:47
16:48
16:49
16:50
16:51
16:52
16:53
16:54
16:55
16:56
16:57
16:58
16:59
17:00
17:01
17:02
17:03
17:04
17:05
17:06
17:07
17:08
17:09
02
%
DV
12.85
12.25
11.70
12.31
12.92
13.09
11.61
12.08
13.05
12.91
12.38
11.47
12.04
12.42
14.03
12.29
11.82
12.19
12.92
12.62
12.10
13.12
12.49
12.86
12.02
12.44
12.75
12.66
12.56
11.17
11.94
13.28
13.57
12.09
11.61
12.15
12.58
13.08
11.77
C02
%
DV
6.20
6.71
7.19
6.68
6.12
5.98
7.29
6.87
5.97
6.17
6.62
7.40
6.91
6.59
5.06
6.59
7.10
6.79
6.13
6.35
6.75
5.86
6.50
6.17
6.85
6.46
6.22
6.35
6.42
7.60
6.96
5.71
5.47
6.79
7.25
6.78
6.40
5.91
7.04
CO
PPMDV
317.10
333.10
327.40
314.70
317.50
324.20
341.70
320.90
323.20
321.60
331.90
338.40
312.50
316.20
324.40
360.20
331.30
321.10
314.60
324.90
343.50
325.90
323.80
320.00
344.70
341.20
329.90
324.60
326.20
346.30
316.50
328.20
332.50
358.30
336.50
325.50
329.10
332.20
356.50
NOX
PPMDV
151.30
124.40
129.30
153.40
159.80
139.60
117.50
138.00
150.50
143.60
122.40
119.20
131.90
146.70
126.60
125.10
139.20
151.00
141.40
123.60
126.40
144.50
154.70
139.90
119.50
144.30
153.50
149.70
124.40
114.90
147.30
151.30
142.80
124.80
131.00
158.20
154.30
134.30
128.50
-------
Starting
07-30-93
EPA Brick WA 14
Kiln Combustion Exhaust
O2/C02/CO/NOX
KSO-M3A/10B/7E-R2
Time
17:10
17:11
17:12
17:13
17:14
17:15
17:16
17:17
17:18
17:19
17:20
17:21
17:22
17:23
17:24
17:25
17:26
17:27
17:28
17:29
17:30
17:31
139 MinAvg
02
DV
12.83
12.30
12.85
11.76
11.58
12.50
13.71
13.22
11.69
11.98
12.93
12.89
12.28
12.02
12.88
13.41
13.30
11.40
12.16
11.94
12.78
12.57
12.62
C02
DV
6.10
6.66
6.17
7.12
7.25
6.41
5.30
5.74
7.08
6.94
6.03
6.11
6.59
6.88
6.09
5.66
5.59
7.35
6.72
6.96
6.26
6.26
6.36
CO
PPMDV
335.00
330.30
317.00
341.80
327.80
320.80
329.30
332.80
348.40
318.80
321.90
326.00
340.80
346.10
328.40
336.60
339.00
352.20
325.20
331.10
317.90
339.80
324.51
NOX
PPMDV
150.00
154.30
143.10
114.70
130.90
153.10
150.50
137.00
132.10
148.40
154.40
139.60
122.40
136.70
159.20
152.90
131.60
115.30
124.20
146.30
144.10
128.10
143.34
Data Corrected for Calibrations
139 MinAvg 12.86 6.34
326.21
145.17
-------
Calibrations:
02 25 Span Value = 25
LOW Calibration Gas = 0.00 HIGH Calibration Gas =
Initial Cal. at: 1505
22.00
LOW Cal. Response = 0.04
Cal. Drift = 0.00
Final Cal. at: 1751
LOW Cal. Response = 0.04
Cal. Drift = 0.00
LOW System Drift = -0.00
HIGH Cal. Response = 21.60
Cal. Drift = -0.02
HIGH Cal. Response = 21.56
Cal. Drift = -0.02
HIGH System Drift = -0.00
CO2 20 Span Value = 20
LOW Calibration Gas = 0.00 HIGH Calibration Gas =
Initial Cal. at: 1505
LOW Cal. Response = 0.02
0.00
18.20
Cal. Drift =
Final Cal. at: 1751
LOW Cal. Response = 0.01
Cal. Drift = 0.00
LOW System Drift = -0.00
HIGH Cal. Response =
Cal. Drift =
18.24
0.00
HIGH Cal. Response = 18.21
Cal. Drift = 0.00
HIGH System Drift = -0.00
CO 1000 Span Value = 1000
LOW Calibration Gas = 0.00 HIGH Calibration Gas = 929.00
Initial Cal. at: 1505
0.00 HIGH Cal. Response = 921.21
Cal. Drift = -0.01
LOW Cal. Response =
Cal. Drift = 0.00
Final Cal. at: 1751
LOW Cal. Response = 0.00
Cal. Drift = 0.00
LOW System Drift = 0.00
HIGH Cal. Response = 927.12
Cal. Drift = -0.00
HIGH System Drift
0.01
NOx 250 Span Value = 250
LOW Calibration Gas = 0.00 HIGH Calibration Gas = 257.00
Initial Cal. at: 1505
-0.23 HIGH Cal. Response = 251.61
LOW Cal. Response -
Cal. Drift = -0.00
Final Cal. at: 1751
LOW Cal. Response = 0.97
Cal. Drift = 0.00
LOW System Drift = 0.00
Cal. Drift = -0.02
HIGH Cal. Response = 255.32
Cal. Drift = -0.01
HIGH System Drift = 0.01
-------
Starting
07-31-93
EPA Brick WA 14
Kiln Combustion Exhaust
02/C02/CO/NOX
KSO-M3A/10B/7E-R3
Time
09:06
09:07
09:08
09:09
09:10
09:11
09:12
09:13
09:14
09:15
09:16
09:17
09:18
09:19
09:20
09:21
09:22
09:23
09:24
09:25
09:26
09:27
09:28
09:29
09:30
09:31
09:32
09:33
09:34
09:35
09:36
09:37
09:38
09:39
09:40
09:41
09:42
09:43
09:44
02
%
DV
12.73
13.57
12.69
12.27
12.57
12.99
13.52
11.55
12.15
12.54
13.65
12.68
12.34
13.08
13.10
12.94
12.44
12.98
13.04
13.51
12.89
12.07
12.52
13.07
12.91
11.82
13.06
13.70
13.69
13.12
12.47
13.74
13.64
14.32
13.14
12.37
12.66
12.80
12.37
CO2
%
DV
6.96
6.25
6.97
7.32
7.12
6.75
6.24
7.94
7.43
7.14
6.12
6.96
7.22
6.62
6.65
6.80
7.06
6.66
6.72
6.32
6.80
7.49
7.17
6.65
6.84
7.67
6.56
6.09
6.15
6.63
7.10
5.99
6.16
5.58
6.55
7.32
7.08
6.96
7.27
CO
PPMDV
329.90
322.70
350.10
329.80
310.70
311.60
323.10
345.70
310.00
320.40
317.40
353.80
330.20
327.30
317.10
317.10
345.60
325.20
318.50
311.40
346.20
333.70
305.50
317.00
324.80
343.50
321.70
325.00
316.00
342.10
333.40
328.40
329.90
325.80
356.60
306.40
296.50
293.70
324.10
NOX
PPMDV
175.60
164.00
145.80
154.10
169.70
164.00
149.00
133.40
160.70
163.50
152.80
132.90
140.00
170.40
172.30
141.00
140.30
163.50
173.20
162.70
148.60
146.70
166.20
152.90
140.40
128.00
158.60
168.00
168.00
146.10
152.90
172.70
183.80
153.30
140.40
132.20
145.70
132.50
121.40
-------
Starting
07-31-93
EPA Brick WA 14
Kiln Combustion Exhaust
02/C02/CO/NOX
KSO-M3A/10B/7E-R3
Time
09:45
09:46
09:47
09:48
09:49
09:50
09:51
09:52
09:53
09:54
09:55
09:56
09:57
09:58
09:59
10:00
10:01
10:02
10:03
10:04
10:05
10:06
10:07
10:08
10:09
10:10
10:11
10:12
10:13
10:14
10:15
10:16
10:17
10:18
10:19
10:20
10:21
10:22
10:23
02
%
DV
12.03
13.50
13.28
13.17
11.46
12.21
12.66
14.21
13.79
11.85
12.62
13.36
14.27
12.79
12.75
12.73
13.38
13.30
11.47
13.04
13.34
13.91
12.48
12.37
12.50
13.84
13.56
12.65
13.24
13.15
13.70
12.61
13.02
13.51
13.19
12.85
12.01
13.35
14.20
C02
%
DV
7.53
6.22
6.48
6.65
8.09
7.37
7.01
5.63
5.98
7.70
7.05
6.36
5.56
6.84
6.90
7.00
6.38
6.43
7.99
6.60
6.39
5.93
7.11
7.24
7.16
5.94
6.13
6.90
6.49
6.58
6.09
6.97
6.59
6.18
6.57
6.87
7.49
6.33
5.58
CO
PPMDV
313.50
312.50
316.20
304.20
335.00
297.70
308.00
311.80
337.00
338.10
300.90
314.20
314.70
355.80
309.70
300.30
298.10
329.00
331.10
314.90
323.30
316.90
345.50
315.70
305.70
321.70
331.90
344.50
310.70
316.80
305.90
337.90
318.50
322.80
311.90
315.00
329.70
310.30
309.20
NOX
PPMDV
118.60
147.70
146.50
126.50
104.10
133.10
152.50
151.10
134.80
133.20
154.00
167.60
146.40
140.70
155.30
163.90
155.10
139.70
126.80
163.00
173.10
159.90
140.40
160.20
165.20
162.70
145.50
153.40
177.50
187.80
167.80
148.00
164.70
178.90
179.40
145.50
144.40
170.70
173.00
-------
Starting
07-31-93
EPA Brick WA 14
Kiln Combustion Exhaust
02/C02/CO/NOX
KSO-M3A/10B/7E-R3
Time
10:24
10:25
10:26
10:27
10:28
10:29
10:30
10:31
10:32
10:33
10:34
10:35
10:36
10:37
10:38
10:39
10:40
10:41
10:42
10:43
10:44
10:45
10:46
10:47
10:48
10:49
10:50
10:51
10:52
10:53
10:54
10:55
10:56
10:57
10:58
10:59
11:00
11:01
11:02
02
%
DV
13.93
12.44
11.98
13.68
13.71
13.58
12.17
13.09
13.77
14.03
12.13
11.78
12.58
12.84
12.87
12.56
13.47
13.23
13.60
13.46
12.54
13.03
13.45
13.02
12.65
12.61
14.29
13.86
12.68
12.43
13.70
14.30
13.21
11.84
12.63
12.76
13.57
13.69
12.50
C02
%
DV
5.87
7.15
7.53
5.96
6.04
6.15
7.33
6.55
5.93
5.73
7.44
7.69
7.02
6.82
6.78
6.91
6.14
6.44
6.10
6.16
7.08
6.61
6.23
6.59
6.90
6.97
5.38
5.82
6.86
7.06
5.95
5.44
6.46
7.61
6.89
6.83
6.11
5.90
7.00
CO
PPMDV
301.10
326.70
307.20
308.30
307.60
314.00
339.10
306.90
313.50
316.70
330.80
315.30
307.50
307.20
312.80
344.40
321.50
325.30
314.60
332.40
308.90
305.10
311.80
313.10
305.10
297.00
313.20
312.00
332.20
327.00
314.80
316.00
308.00
325.80
291.70
301.40
300.20
329.00
327.80
NOx
PPMDV
161.30
142.40
143.90
170.90
172.80
156.10
145.40
175.40
176.20
165.10
130.00
134.70
156.50
162.80
142.10
146.70
170.50
178.70
167.40
151.30
149.50
159.10
164.00
143.30
140.00
152.10
144.40
157.10
149.10
159.10
171.30
164.20
142.90
124.50
149.30
173.50
157.40
140.60
144.80
-------
Starting
07-31-93
EPA Brick WA 14
Kiln Combustion Exhaust
02/C02/CO/NOX
KSO-M3A/10B/7E-R3
Time
11:03
11:04
11:05
11:06
11:07
11:08
11:09
11:10
11:11
11:12
11:13
11:14
11:15
11:16
11:17
11:18
11:19
11:20
11:21
11:22
11:23
11:24
139 MinAvg
02
DV
13.43
13.23
13.77
12.23
12.84
13.50
14.24
13.10
11.92
12.53
12.64
13.06
12.83
13.30
13.84
13.17
12.60
11.35
12.95
13.63
13.67
12.35
12.99
C02
DV
6.17
6.41
5.92
7.19
6.69
6.10
5.46
6.46
7.51
7.01
6.93
6.54
6.57
6.21
5.75
6.47
6.94
8.00
6.53
5.90
5.95
7.06
6.65
CO
PPMDV
303.40
311.40
310.40
337.70
312.30
317.50
321.50
332.50
327.60
298.80
309.20
302.50
342.10
323.50
327.90
308.70
319.30
318.10
304.90
321.50
320.20
341.90
319.64
NOX
PPMDV
169.40
174.00
157.70
142.80
171.10
172.80
165.80
148.10
140.60
160.80
170.80
148.20
147.40
166.50
167.20
164.10
131.10
121.20
154.90
171.90
161.60
148.60
154.24
Data Corrected for Calibrations
139 MinAvg 13.10 6.62
324.30
156.55
-------
Calibrations:
O2 25 Span Value = 25
LOW Calibration Gas = 0.00 HIGH Calibration Gas
Initial Cal. at: 749
22.00
LOW Cal. Response = 0.01
Cal. Drift = 0.00
Final Cal. at: 1133
LOW Cal. Response = 0.05
Cal. Drift = 0.00
LOW System Drift = 0.00
HIGH Cal. Response =
Cal. Drift =
HIGH Cal. Response =
Cal. Drift =
HIGH System Drift =
22.02
0.00
21.59
-0.02
-0.02
C02 20 Span Value = 20
LOW Calibration Gas = 0.00 HIGH Calibration Gas =
Initial Cal. at: 749
0.00
18.20
LOW Cal. Response =
Cal. Drift = 0.00
Final Cal. at: 1133
LOW Cal. Response = 0.01
Cal. Drift = 0.00
LOW System Drift = 0.00
HIGH Cal. Response = 18.36
Cal. Drift = 0.01
HIGH Cal. Response = 18.23
Cal. Drift = 0.00
HIGH System Drift = -0.01
CO 1000 Span Value = 1000
LOW Calibration Gas = 0.00 HIGH Calibration Gas = 929.00
Initial Cal. at: 801
0.02 HIGH Cal. Response = 926.00
Cal. Drift = -0.00
LOW Cal. Response =
Cal. Drift = 0.00
Final Cal. at: 1142
LOW Cal. Response = -0.38
Cal. Drift = -0.00
LOW System Drift = -0.00
HIGH Cal. Response = 906.00
Cal. Drift = -0.02
HIGH System Drift = -0.02
NOx 250 Span Value = 250
LOW Calibration Gas = 0.00 HIGH Calibration Gas = 257.00
Initial Cal. at: 756
-2.94 HIGH Cal. Response = 258.00
-0.01 Cal. Drift = 0.00
LOW Cal. Response =
Cal. Drift =
Final Cal. at: 1137
LOW Cal. Response =
Cal. Drift =
LOW System Drift =
-0.31 HIGH Cal. Response = 250.50
-0.00 Cal. Drift = -0.03
0.01 HIGH System Drift = -0.03
-------
APPENDIX D.2.0
KILN COMBUSTION EXHAUST STACK
RAW FIELD DATA APPENDICES
-------
APPENDIX D.2.1
RAW FIELD SAMPLING DATA FOR EPA METHOD 201A/202 TESTING
-------
. .ELD DATA SHEET FOR METHOD 201**
FiiCILITV.
£'/>
PAGE 1
DATE
START Tl ME JL
TEST LOCATION
RUN NUMBER
A
Sample' Clock
Time Time
30.)
Static
T./6
7*
5.
.£
,5
61« 7
73.3
764
Temp.
379
3? 7
357
.?*•/
Stack
dP
,/JT
./*
/5
/ n
,14
Tim*
V-0.5
19V
3-59
3-71
3-fff
3,41
Meter
dH
,5,?
.Set
0
,£?
Meter Volume
cu.ft.
m
-0
g.SX'7
8S7.S
K/-099
Meter Temp.
Inlet Outlet
f"?
1*
161
1
Imp.
Temp.
f")
V
CY
60
*'? .
Meter
Vac.
0
10
2.0
£.0
2,0
*0
^ ^}
^.^f
3.0
^L
-oosTiw JMWRMATION
(Container| Sample
Number
/
.D.
Description
:> i
LEAK CHECK
Vacuum
Rate
V*
.00 y
Dvell Tim* // „ .-
for P«>W 1 = '« (/^
IMMNGfcHYOLUMbS
#4
#5
Initial
too
final
/££ i
/DO
0
f-
METER BOX I.D.
GAMMA
DELTA H
OPERATOR
9AR. PRESS.
30-00
FILTER I.D.
-------
FACILITY.
START T! ME
MELD DATA SHEET FOR METHOD 201 A
TEST LOCATION
PAGE t
RUN NUMBER
I i Sample i nock i
! Poir.ti Time Time ^
Tetnp.
Stack
JP
Tim*
fleter
dH
Meter Volume
cu.ft.
Meter Temp. I !rr>p. j Meter '
Inlet I Outlet j Temp. I Vac.
D
0
M.
H-J1
3.V
V \li.o
321
.$2
n
Col
30
I I
33.0
1,07
tnt
t
6Q
30
6 \ Q.0.0
3-tt
.SJ
2-6
i 33,
r/3
-**
•<&
47
./V
IOQ
97
f./V
60 7.0
_
T VO.J
Lb I
JVO
Iff-/-
441
i sT3. o
SI -I
,13
101
,/V
106
f06\s
101
U
3.0
903 7
73-0 !
,/7
(02
A..O
iOk
,17
\01
1
,SJ
top-
6 . .3
.si
3.6
CHAI^flfQlgT!
^/6-V6^
'tfWio Mm.
wknjs
\ °2-t I !//tQ. /j
7 ^J
LEAK CHECK
Vacuum
Rate
5"
ifl/o
Dv«H Time
for Point 1 :
05
• -V
IMPINGEHYOL'JMbS
initial
nrrt
O
/Of)
'0
METER BOX 1.0.
GAMMA
DELTA H* /. 7Af
-------
FACILITY.
lo
"iOTTIMf If:
.ft
Meter Volume
cu.ft.
.KJ
.L
Meter Temp! imp. {Meter
Inlet (Outlet I Temo.lYec.
*
in
n
too
101
fif
tot
^ 5"?
\
133.3"
I3y.<730
,iT?
.ri
^L
^7.7
.7ft,
-A.
<-<
MS
/*
7-
/of
4-7
fa
Vacuum
Rate
LEAK CHECK
i>Dt,
WPINGKYOL'JMES
Tim*
inrtiaj
final
OO
METER BOX I.D.
CAttMA
tLTA
OPERATOR
,8AR. PRESS. ! SO 00
FILTER !.D.
\
i
-------
APPENDIX D.2.2
RAW FIELD SAMPLING DATA FOR EPA METHOD 29 TESTING
-------
m TV
FIELD UATA SHEET FOR ISOKINETIC SAMPLING
JU.iX TFST LOCATION
PAAC 1
LTARTTIME ft-'29
POLLUTANT M-/4.. dUAk
RUN I.D.
Point
Sample
Time
Clock
Time
Static
Stack
Temp.
Stack
dP
Meter
dH
Meter Volume
cu.ft.
Muter Temp
Inlet Outlet
Filter Imp.
Temp.
Temp.
Meter
Vec.
.J
f/
V
, 6"
fv
/J
/
20
n
y. /
'•
f?
• "
41 i
V
CHA!NQ/l2ig:Tr.iriY INFORMATION
(Container
I Numpgr
LEAK CHECK
Sample
I.D.
70
So
70^,
2&2.
30JL
Description
Vacuum
Pate
Ib i
.g/o .017
IMPING ER VOLUMES
#1
#2
#4
#5
#6
InitiaJ
/o o
0
/ 0 o
/o o
Final
100
/(DO
/NOZZLE SIZE
METER BOX I.D.
GAMMA
DELTA
BAR. PRESS.
FILTER I.D.
OPERATOR
1 . 7JK
7-
-------
FIELD DATA SHEET FOR ISOKINETIC SAMPLING
FACILITY _2jiLt&±
PAfiE 1
POLLirTANT M»l
RUN ID \<.L£~r J?4' -PJ
Point
Sample
Time
Clock
Time
Static
Stack
Temp.
Stack
dP
Meter
dH
Meter Volume
cu.fl.
Muter Temp
Inlet Outlet
Filter
Temp.
Imp.
Temp.
Meter
0
. IQo
LZ.
JSL
Jd2-
L
*d£.
Uf
JU.
. ^
/
>SJ_
i£^
JL
1.0
l.b
Ho
ff
/7
.10
1-3
701.
}
n
/^'/7I
81
It'-.
US'
6>t
l.o
I !*,'
a
3S1
ft/>
M
73/.1
ff
6
A-
l.p
fo
I 2
\* 1
I 3 I
719 . t)
f
_ i
6 \
ia.
1-0
Container
Number
POTION
LEAIf CHECK
Sample
I.D.
J
Description
-------
FATUITY
FIELD DATA SHEET FOR ISOKINETIC SAMPLING
W B^./-l TfST LOCATION to«Lnk*. /^L,.<\7
97
V-f
I 2
•$?
Sis -I
i « I
1__*^ 1
3J5
*i$
lt.O
9^
\SJ
330
.It
3/0
, f 6 .^ 7
13
i /
i it i
I I 33? .
CHAIN!
j Container
I Number
LEAK CHECK
Sample
I.D.
7/9
Description
-?£*-
713
z£t
Vacuum
Pate
tiJO.030
MPWGER VOLUMES
#2
#3
#4
#5
*6
IretiaJ
0
IOC'
/DO
Final
/£/
WZ2LE SIZE
METER BOX I.D.
GAMMA
DELTA H*
BAR. PRESS.
FILTER I.D.
OPERATOR
6
/"/>*//
-------
APPENDIX D.2.3
RAW FIELD SAMPLING DATA FOR EPA METHOD 26 TESTING
-------
Figure £.0- EPA Method 26 Sampling Do Sheet
Proect
Nominal Sampling Rate
Mater So;; !.D. _
Meter Box Gamma
//n CornfaLtsho/i-fxhaiXr Nominal Sampling dH-in.W.C.
; 7"-3t- *?3 Barometric Pressure-in. Hg
Operator 'D.
MX n\
tt'.SO
//
J\
'•*£'
JfcM
n:
-------
APPENDIX D.2.4
RAW FIELD SAMPLING DATA FOR EPA METHOD 0030 TESTING
-------
RUN NUMBER
Date 7
Test Location f( . / r\ Com lit ) Sfto/i £ lra LIST
Meter Box I.D.
Meter Box Calibration Factor D.
INITIAL LEAK CHECK'
Vacuum
leak Rate mm Ha/minute
SAMPLE COLLECTION
CARTRIDGE SET 1
CARTRIDGE SET 2
CARTRIDGE SET 3
Tenax I.D.
- Rl
Charcoal !.D.
- PtC
I
INITIAL
FINAL
INITIAL
FINAL
INITIAL ! FINAL
Time
Meter Volume
JL3.3J
. 99
Merer Temperature
/OJ.D'f
Meter Pressure j / f)
Lo
2.1
J.I
y.n
System Vac u urn
7.0
Condenser 1 Temp.
Condenser 2 Temp
bt'F
Probe Temperature
Leak Rate
\ d.oo
! o
CARTRIDGE SET 4
CARTRIDGE SET 5
CARTRIDyESE" 6
Tenax i.D.
- A/0050-/?/ D
Charcoal I.D.
INITIAL
FINAL
INITIAL
FINAL
INITIAL
FINAL
Time
Meter Volume
99
Meter Temperature j
Meter Pressure
I.O
/.&
rO.I
/
Sustem Vacuum
9.0
Condenser 1 Temp.
r/..-.-1 •-«•>.- '• T. ~,.
O^'IIUCMOCI t. ICIMJ.'.
Probe Temperature {
. OO
O.OD j
6.00 ! 0.&6
ET;.101490
-------
RUN NUMBER
Te?t Location A^. I n rio/n hos4to,-\
Meter Box I.D.
Meter Box Caiibration Factor /9.
INITIAL LEAK CHECK
Vacuum /£. D
teak Rate mm Hg/minute
SAMPLE COLLECTION
CARTRIDGESET1
CARTRIDGE SET
CARTRIDGE SET
Tenax I.D.
JCC€_ -
Charcoal I.D.
krc
INITIAL
FINAL
INITIAL
FINAL
FINAL I
Tim*
x
f.n
AO !
System Vacuum
o
9./9
V.O
Condenser 1 Temp.
uOHOCH?Cf" t. I CIMp. I
LS'F
Probe Temperature
/?
0-O&
0.00
ET':. 1024 90
-------
RUN H UMBER
Test Location T//V)
Meter Box I.D.
Meter Box Calibration Factor
INITIAL LEAK CHECK
Vacuum
leak Rate mm Ho/minute
SAMPLE COLLECTION
CARTRIDGE SET 1
CARTRIDGE SET 2
CARTRIDGE SET!
Tenax I.D.
Charcoal I.D.
Time
Meter Volume
Merer Temperature
Meter Pressure
System Vacuum
Condenser 1 Temp.
Condenser 2 Temp.
Probe Temperature
Leak Rate
\?Ct-Mff^O- &2<^
KCP, - tyCb3o - teC*
INITIAL
/9/a?^
<£?/^V
//5'°P
£./
?.o
(s^P
tJ^L**
£>.oo
FINAL
//7.'4"?
•7/9. 9A
m^f
tj. i
?,&
(„$•£
Ltfop
<=2#%°r
fi.Od
INITIAL
FINAL
INITIAL
FINAL
!
i
'
CARTRIDGE SET 4
CARTRIDGE SET 5
CARTRIDGE SET r.
Tenax i.D.
Charcoal I.D.
Time
Meter Volume
Meter Temperature
Meter Pressure
Sustem Vacuum
Condenser 1 Temp.
t'C'iiuCMv'?.!" i. 16 TTip.
Probe Temperature
1 **\ Pstf.
INITIAL
FINAL
INITIAL
FINAL
INITIAL
FINA.
1
i
l
i
j
i
-------
RUN NUMBER
Pate
Test Location kiln Av»>/?/JSfr
o>/)
Meter Box I.D.
Meter Box Calibration Factor f).
INITIAL LEAK CHECK:
Vacuum -/£> - O
leak Rate mm Hg/minute
SAMPLE COLLECTION
CARTRIDGE SET!
% f^Ll
£39
CARTRIDGE SET 2
J-//W
CA DTD I r>~r C-JT
nKI KiL/'jL it. i
Tenax I.D.
^., Charcoal !.D.
- RlA-
INITIAL
FINAL
INITIAL
FINAL
INITIAL ] FINAL
Time
Meter Volume
f^ /V5
.^?. ?
/ 0
Sustem Vacuum
0 /?
9.
Condenser 1 Temp
Condenser 2 Temp
£,?*£
Probe Temperature
l Leak Rate
Q Do
d.oo
O.Oo
/9
/?.
CARTRIDGE SET 4
CARTRIDGE SET 5
CARTRIDGE SET o
Tenax i.[.'.
Charcoal I.D.
INITIAL
FINAL
INITIAL
FINAL
INITIAL
FINA
Time
/0'T)cf''
///*£
llA'F
Meter Pressure 1
t.fj
/.o
. /
Sustem Vacuum
Condenser 1 Temp.
Condenser 2 Temp.
Probe Temperature
I I O
-------
APPENDIX D.2.5
RAW FIELD SAMPLING DATA FOR EPA METHOD 0010 TESTING
-------
".JARTTIME
FIELD DATA SHEET FOR ISGKINETIC SAMPLING
irer LOCATION f»^L^>^ £*L.\
/./r
Ltf.C,
n
3LL
Lll.1
'. e>
33 f
30
i
ft
if
to
336
1*
6,36.
6 6*
Jf
100
\/3
CtO
&.?
K/
1*
3SJ
ktr
/.r
\toJi
.n
16
D.I
f
13
in
-,.!
S?
V
to
ZJtf
6eCL_L\idCe_i^D
1L
m-
\/o i
\ IOC?
\ \.71L,
I to4
LTD .
tot
(10
Mb
t'lL l,
(03
n
\lcj
S3
CHAIN OF CUSTODY IN FORMATION
LEAK CHECK
jUoritainer Sample
Number I I.D.
Description
^OJ
SO 3
0 f( (ttA.
w
Vacuum
-Pate
WRINGER VOLUMES
#1
#2
*6
Initial
/DO
/O 0
final
J
NOZZLE SIZE
METER BOX I.D.
GAMI-W
DELTA H*
BAR. PRESS.
FILTER I.D
OPERATOR
-------
HELD DAI A
FQR ISQKINETIC SAMPLING
RUN 1.0.
l i
! Time'
Static | Temp
dP
Meter
dH
Meter Yolurr*
cu.ft.
Meter Temp.
inlet Outlet
Filter | Imp. -Merer]
Temp. Tem^.l\&;. i
C
4V
£ 7
no
.HZ
6fg.-/
2V7
ns
,15
/£>?
'o'J
.C 3
/'if)
.So
/a?
S6
\SJ
J37
1 10
.U
, r
//O
ISS
/ov
SS
no
. 7
ILO
.2)
ass
fO
( i / to
/-o
S7\//.fi'\
i 2
si> I//.Q i
1 I 1 fj
3VO
/-O
I
i//j i
i r
J/. 7
x^i
. Jo
A3
7-7V.
XT
/, J
/J
i , n
t-
> '7
A; jT^^-g
I U
I I
LEAK CHECK
Vacuum
Pste
^0"
.r?/^?
-
-------
PAT! MTV .
MARITIME
FIELD DATA SHEET FOR ISOKINETIC SAMPLING
,g^W DATE
POLLLTTANT
RUN I.D.
PA« i
- 9 2
Point
Sample
Ti me
Clock
Tim*
Static
Stack
Temp.
Stack
dP
Meter
dH
Meter Volume
cu.ft.
Muter Temp
Inlet Outlet
Filter
Temp.
Imp.
Temp.
Meter
Yec
l
3/3
t?
/07
r
11
-1
Jo 7
211
. n
. \
lit
Jo?
1
/T5~l 7
HI
LO
it
.\U
/Pis
31
32
nit
, in
IC7
7
,n
, \
to
Lit
y/i
7
Ci
33T
ho
V. z?
JO 5
33T
/ i
. 7
351
if I*
/Al
i 77
Jo 7
SV 7
1,3
! to I
3£? .Ji
-
JO 7
I 7
. e,
' $&
11 \ 1,5
i /r . /c ?
<;(* \ '7
7
CHAIN OF CUSTODY INFORMATION
LEAK CHECK
(Container (Sample
I Kumter I I.D.
/
-Sfil
Description
H
Vacuum
Rate
MPWGER VOLUMES
#1
#2
#3
*4
too
/oo
Final
/OO
NOZZLE SI2E
METER BOX I.D.
GAMMA
DELTA
BAR. PRESS.
FILTER I.D.
OPERATOR
-------
FIELD DA i A SHEET FDR ISQKINETIC SAMPLlNb
RUN I.D..
PACE 2
I i '^rop'e ' Clock
Poir.t| Time ! time
Static
Temp.
St.«clr.
Meter
-------
f ATI MTV
•-.TARTTIMF OtjfJ
FIELD DATA SHEET FOR ISQKINETIC SAMPLING
v 6',it TEST LOCATIM f ..>/>.
POimTAKT
0~)~]0'1J
RUN I D. lc&£ -^-OoiD-P 3
Point
Sample
Ti me
Clock
Tire
Static
Stack
Temp.
Stack
dP
Meter
too
/DO
0
AO&CL
' i
Final
/tf9
/GO
/ o 1
n
2,^3 ^/
NOZZLE SIZE
METER BOX I.D.
GAMMA
DELTA H*
BAR. PRESS.
FILTER 1
D
OPERATOR
sy^
#?
f.OO^te
/. ex-toe
^cr.
-------
HELD Dal A SHEt^T FQR ISQKINETIC CAMPLINb
RUN I.D./CC/C ~
;>mpl»
» I
roir.i Time Time
?•*:>:
Static | Temp.
UP
Me
-------
QRSAT FIELD DATA
JOB NAME
FUEL TVPE
JOB NUMBER
a£>H
TEST LOCATION
RUN NUMBER
.OPERATOR
Time of
Sample
Collection
TO
Time of
Analysis
TO
Average
C02
Reading
A
«.&
02
Reading
B
CO
Reading
w
Average
%Q2
B-A
\r.1
SCO
C-B
SN2
100-C
i
n
TEST LOCATION /c- /n f* I«AA«JJ"«. exHg.vs'}'
RUN NUMBER ;^c~ ^ LEAK TEST? _^ DATE 7A<> OPERATOR
Time of
Sample
Collection
TO
Time of
Analysis
TO
Average
C02
Reading
A
vT. (,1.
02
Reading
B
CO
Reading
Average
*02
B-A
ro
^co
C-B
^N2
100-C
TEST LOCATION
RUN NUMBER _
LEAK TEST?,
.DATE
.OPERATOR
Time of
Sample
Collection
TO
Time of
Analysis
TO
Average
C02
Readinq
A
02
Reading
B
CO
Reading
U
Average
S02
B-A
SCO
C-B
SN?
100-C
1
-------
ORSAT FIELD DATA
JOB NAME
FUEL TYPE
JOB NunBER
C g^ / >^v / "L» /• /V 67-
TEST LOCATION
RUN NUMBER
"'LEAK TEST?
DATE
OPERATOR
Time of |
Sample [Time of
Collection} Analysis
!
TO 1 TO
i
I
I
i
Average
C02
Reading
A
-------
APPENDIX D.3.0
KILN COMBUSTION EXHAUST STACK
LABORATORY DATA APPENDICES
-------
APPENDIX D.3.1
GRAVIMETRIC LABORATORY DATA FOR
THE KILN COMBUSTION EXHAUST STACK
-------
E T S , INC.
FIELD SAMPLE LOG
Contract No. 92-655WA
Job I.D.
Test Method 201A/202
Print Date OB/02/93 Time 11:54:50
Page 1
Sample
No.
00200
00201
00202
00203
00204
00205
00206
00207
00208
00209
00210
00211
00212
00213
00214
00215
00216
00217
00218
00219
00220
00221
00222
00223
Container
No.
Fl
F2
F3
F4
F5
F6
F7
Fl
F2
F3
F4
F5
F6
F7
Fl
F2
F3
F4
F5
F6
F7
Fl
F2
F3
Other
I.D.
92-0008
92-0009
92-0144
92-0145
Run
I.D.
KCE-1A2-R1
KCE-1A2-R1
KCE-1A2-R1
KCE-1A2-R1
KCE-1A2-R1
KCE-1A2-R1
KCE-1A2-R1
KCE-1A2-R2
KCE-1A2-R2
KCE-1A2-R2
KCE-1A2-R2
KCE-1A2-R2
KCE-1A2-R2
KCE-1A2-R2
KCE-1A2-R3
KCE-1A2-R3
KCE-1A2-R3
KCE-1A2-R3
KCE-1A2-R3
KCE-1A2-R3
KCE-1A2-R3
KCE-1A2-RO
KCE-1A2-RO
KCE-1A2-RO
Sample
Type
FIBERGLASS FILTER
>PM10 ACETONE RINSE
<=PM10 ACETONE RINSE
IMPINGER CONTENTS
IMP CONT EXTRA STORE
BACK HALF MeCL2
SILICA GEL
FIBERGLASS FILTER
>PM10 ACETONE RINSE
<=PM10 ACETONE RINSE
IMPINGER CONTENTS
IMP CONT EXTRA STORE
BACK HALF MeCL2
SILICA GEL
FIBERGLASS FILTER
>PM10 ACETONE RINSE
<=PM10 ACETONE RINSE
IMPINGER CONTENTS
IMP CONT EXTRA STORE
BACK HALF MeCL2
SILICA GEL
FIBERGLASS FILTER
>PM10 ACETONE RINSE
<=PM10 ACETONE RINSE
Volume , ml
no Rinses
Volume, ml
w/ Rinses
Analyst
PJb
PJb
PJb
PJb
PJb
pjb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
pjb
pjb
pjb
Date
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
08/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
Comments
blank
blank
blank
-------
E T S , INC.
FIELD SAMPLE LOG
Contract No. 92-655WA
Job I.D.
Test Method 201A/202
Print Date 08/02/93
Page 2
Sample
No.
00224
00225
00226
00227
Container
No.
F4
F5
F6
F7
Other
I.D.
Run
I.D.
KCE-1A2-RO
KCE-1A2-RO
KCE-1A2-RO
KCE-1A2-RO
Sample
Type
IMPINGER CONTENTS
IMP CONT EXTRA STORE
BACK HALF MeCL2
SILICA GEL
Volume, ml
no Rinses
Volume, ml
w/ Rinses
Analyst
pjb
pjb
pjb
pjb
Date
OB/02/93
08/02/93
08/02/93
08/02/93
Comments
blank
blank
blank
blank
-------
ETS, Inc.
GRAVIMETRIC LABORATORY DATA
Tare Filter Weights
Filter Description: Fiberglass
Report Prepared on: 10/29/93
Page
Filter
Number
92-0144
92-0145
Date
03/24/92
03/26/92
03/24/92
03/26/92
Time
13:57
13:17
13:58
13:40
Weight (g)
0.39924
0.39921
0.39887
0.39883
Analyst
TLP
TLP
TLP
TLP
Constant
Weight (g)
0.39921
0.39883
-------
ETS, Inc.
GRAVIMETRIC LABORATORY DATA
Tare Filter Weights
Filter Description: Fiberglass
Report Prepared on: 10/29/93
Page
Filter
Number
92-0008
92-0009
Date
03/16/92
03/18/92
03/16/92
03/18/92
Time
12:01
15.24
12:03
15:21
Weight (g)
0.41442
0.41468
0.40957
0.40990
Analyst
TLP
tip
TLP
TLP
Constant
Weight (g)
0.41468
0.40990
-------
ETS, Inc.
GRAVIMETRIC LABORATORY DATA
Tare Beaker Weights
Report Prepared on: 11/01/93
Page
Beaker
Number
07/07/93-013
07/07/93-014
07/07/93-015
07/07/93-016
07/07/93-017
07/07/93-018
07/07/93-019
07/07/93-020
07/07/93-021
07/07/93-022
07/07/93-023
07/07/93-024
07/07/93-025
07/07/93-026
Date Time
07/18/93 11:30
07/20/93 08:28
07/18/93 10:40
07/20/93 08:29
07/18/93 10:31
07/20/93 08:30
07/18/93 10:15
07/20/93 08:31
07/18/93 11:20
07/20/93 08:32
07/19/93 15:04
07/20/93 15:10
07/18/93 11:12
07/20/93 15:16
07/19/93 15:12
07/20/93 15:17
07/18/93 11:14
07/20/93 08:34
07/19/93 15:12
07/20/93 15:19
07/19/93 15:13
07/20/93 08:19
07/20/93 16:11
07/19/93 15:14
07/20/93 15:19
07/19/93 15:14
07/20/93 15:20
07/19/93 15:15
07/20/93 15:21
Weight (g)
67.28980
67.28950
65.00610
65.00620
64.95150
64.95180
66.14850
66.14820
68.14960
68.14970
67.64630
67.64640
64.61520
64.61510
67.83120
67.83080
64.49130
64.49090
66.86780
66.86770
64.00530
64.00440
64.00410
67.69920
67.69890
67.08480
67.08520
64.71440
64.71440
Analyst
PJB
PJB
PJB
PJB
pjb
pjb
pjb
pjb
pjb
Pjb
TGW
TGW
tgw
TGW
TGW
TGW
pjb
tgw
TGW
TGW
TGW
TGW
WLL
TGW
TGW
TGW
TGW
TGW
TGW
Constant
Weight (g)
67.28950
65.00620
64.95180
66.14820
68.14970
67.64640
64.61510
67.83080
64.49090
66.86770
64.00410
67.69890
67.08520
64.71440
-------
ETS, Inc.
GRAVIMETRIC LABORATORY DATA
Tare Beaker Weights
Report Prepared on: 11/01/93
Page
Beaker
Number
07/07/93-027
07/07/93-028
07/07/93-029
07/07/93-030
07/07/93-031
07/07/93-032
07/07/93-033
Date Time
07/19/93 15:15
07/20/93 15:21
07/19/93 15:25
07/20/93 15:33
07/19/93 15:25
07/20/93 15:34
07/19/93 15:29
07/20/93 15:35
07/19/93 15:30
07/20/93 15:35
07/19/93 15:30
07/20/93 15:36
07/19/93 15:30
07/20/93 15:36
Weight (g)
64.90910
64.90890
64.46020
64.45970
65.12580
65.12590
65.18230
65.18190
64.54770
64.54770
66.88850
66.88820
64.25760
64.25800
Analyst
TGW
TGW
TGW
TGW
TGW
TGW
TGW
TGW
TGW
TGW
TGW
TGW
TGW
TGW
Constant
Weight (g)
64.90890
64.45970
65.12590
65.18190
64.54770
66.88820
64.25800
-------
ETS, Inc.
GRAVIMETRIC LABORATORY DATA
Tare Beaker Heights
Report Prepared on: 10/29/93
Page
Beaker
Number
07/13/93-020
07/13/93-021
Date Time
07/14/93 09:45
07/14/93 15:55
07/14/93 09:45
07/14/93 15:55
Weight (g)
64.20170
64.20180
65.96910
65.98930
Analyst
PJB
PJB
PJB
PJB
Constant
Weight (g)
64.20180
65.98930
-------
ETS, inc.
GRAVIMETRIC LABORATORY DATA
Tare Beaker Weights
Report Prepared on: 10/29/93
Page
Beaker
Number
07/30/93-009
07/30/93-010
07/30/93-011
07/30/93-012
07/30/93-013
07/30/93-014
Date Time
07/30/93 16:03
08/02/93 10:21
07/30/93 16:04
08/02/93 10:22
07/30/93 16:04
08/02/93 10:22
07/30/93 16:04
08/02/93 10:23
07/30/93 16:04
08/02/93 10:23
07/30/93 16:05
08/02/93 10:24
Weight
-------
ETS, Inc.
GRAVIMETRIC LABORATORY DATA
Final Beaker Weights
Job Number: 92-655WA
Report Prepared on: 08/09/93
Page
Beaker I
Filter f
Sample f
Run I.D.
Total Vol., ml
Aliquot Vol.
07/07/93-013
92-0008
92-655WA-00200
KCE-1A2-R1
07/07/93-014
92-655WA-00201
KCE-1A2-R1
105.00000
105.00000
07/07/93-015
92-655WA-00202
KCE-1A2-R1
60.00000
60.00000
07/07/93-016
92-0009
92-655WA-00207
KCE-1A2-R2
07/07/93-017
92-655HA-00208
KCE-1A2-R2
110.00000
110.00000
Constant
Tare
Weight (g)
Beaker
Filter
67.28950
0.41468
65.00620
0.00000
64.95180
0.00000
66.14820
0.40990
68.14970
0.00000
Final Weight Data
Date Time Weight (g) Analyst
08/04/93 13:51 67.92230 TGW
08/05/93 08:09 67.92200 TGW
08/04/93 13:51 65.08810 TGW
08/05/93 08:10 65.08770 TGW
08/04/93 13:52 64.96490 TGW
08/05/93 08:11 64.96490 TGW
08/04/93 13:52 66.74610 TGW
08/05/93 08:11 66.74610 TGW
08/04/93 13:53 68.27060 TGW
08/05/93 08:12 68.27080 TGW
Constant
Final
Weight (g)
67.92200
65.08770
64.96490
66.74610
68.27080
-------
ETS, Inc.
GRAVIMETRIC LABORATORY DATA
Final Beaker Weights
Job Number: 92-655WA
Report Prepared on: 08/09/93
Page
Beaker f
Filter #
Sample f
Run I.D.
Total Vol., ml
Aliquot Vol.
07/07/93-018
92-655WA-00209
KCE-1A2-R2
70.00000
70.00000
07/07/93-019
92-0144
92-655WA-00214
KCE-1A2-R3
07/07/93-020
92-655WA-00215
KCE-1A2-R3
82.00000
82.00000
07/07/93-021
92-655HA-00216
KCE-1A2-R3
79.00000
79.00000
07/07/93-022
92-0145
92-655WA-00221
KCE-1A2-RO
Constant
Tare
Weight (g)
Beaker
Filter
67.64640
0.00000
64.61510
0.39921
67.83080
0.00000
64.49090
0.00000
66.86770
0.39883
Final Weight Data
Date Time Weight (g) Analyst
08/04/93 13:53 67.65730 TGW
08/05/93 08:12 67.65750 TGW
08/04/93 13:53 65.17020 TGW
08/05/93 08:13 65.17160 TGW
08/06/93 15:00 65.17200 TGW
08/04/93 13:54 67.91060 TGW
08/05/93 08:13 67.91070 TGW
08/04/93 13:54 64.51030 TGW
08/05/93 08:13 64.51030 TGW
08/04/93 13:55 67.26610 TGW
08/05/93 08:14 67.26570 TGW
Constant
Final
Weight (g)
67.65750
65.17200
67.91070
64.51030
67.26570
-------
ETS, Inc.
GRAVIMETRIC LABORATORY DATA
Final Beaker Weights
Job Number: 92-655WA
Report Prepared on: 08/09/93
Page
Beaker i
Filter #
Sample f
Run I.D.
Total Vol., ml
Aliquot Vol.
07/07/93-023
92-655WA-00222
KCE-1A2-RO
110.00000
110.00000
07/07/93-024
92-655WA-00223
KCE-1A2-RO
120.00000
120.00000
Constant
Tare
Weight (g)
Beaker
Filter
64.00410
0.00000
67.69890
0.00000
Final Weight Data
Date Time Weight (g) Analyst
08/04/93 13:55 64.00450 TGW
08/05/93 08:14 64.00420 TGW
08/04/93 13:55 67.69880 TGW
08/05/93 08:15 67.69850 TGW
Constant
Final
Weight (g)
64.00420
67.69850
-------
ETS, Inc.
GRAVIMETRIC LABORATORY DATA
Final Beaker Weights
Job Number: 92-655WA
Report Prepared on: 08/13/93
Page
Beaker 1
Filter *
Sample t
Run I.D.
Total Vol., ml
Aliquot Vol.
07/13/93-020
92-655WA-00203
KCE-1A2-R1
07/13/93-021
92-655WA-00204
KCE-1A2-R1
07/30/93-012
92-655WA-00204
KCE-1A2-R1
07/07/93-025
92-655WA-00205
KCE-1A2-R1
07/07/93-018
92-655WA-00209
KCE-1A2-R2
70.00000
70.00000
Constant
Tare
Weight (g)
Beaker
Filter
64.20180
0.00000
65.98930
0.00000
67.34280
0.00000
67.08520
0.00000
67.64640
0.00000
Final Weight Data
Date Time Weight (g) Analyst
08/12/93 11:23 64.21850 TGW
08/13/93 08:57 64.21900 TGW
08/12/93 11:23 66.00340 TGW
08/13/93 08:58 66.00320 TGW
08/12/93 11:27 67.35690 TGW
08/13/93 09:03 67.35700 TGW
08/12/93 11:23 67.13120 TGW
08/13/93 08:58 67.13120 TGW
08/04/93 13:53 67.65730 TGW
08/05/93 08:12 67.65750 TGW
Constant
Final
Weight (g)
64.21900
66.00320
67.35700
67.13120
67.65750
-------
ETS, Inc.
GRAVIMETRIC LABORATORY DATA
Final Beaker Weights
Job Number: 92-655WA
Report Prepared on: 08/13/93
Page
Beaker I
Filter *
Sample f
Run I.D.
Total Vol., ml
Aliquot Vol.
07/07/93-027
92-655WA-00210
KCE-1A2-R2
07/07/93-028
92-655WA-00211
RCE-1A2-R2
07/30/93-013
92-655WA-00211
KCE-1A2-R2
07/07/93-029
92-655WA-00212
KCE-1A2-R2
07/07/93-020
92-655WA-00215
KCE-1A2-R3
82.00000
82.00000
Constant
Tare
Weight (g)
Beaker
Filter
64.90890
0.00000
64.45970
0.00000
66.83330
0.00000
65.12590
0.00000
67.83080
0.00000
Final Weight Data
Date Time Weight (g) Analyst
08/12/93 11:24 64.95170 TGW
08/13/93 08:09 64.95320 TGW
08/13/93 14:35 64.95360 TGW
08/12/93 11:24 64.50310 TGW
08/13/93 08:09 64.50420 TGW
08/13/93 14:36 64.50420 TGW
08/12/93 11:28 66.87260 TGW
08/13/93 08:04 66.87000 TGW
08/13/93 14:38 66.86980 TGW
OB/12/93 11:25 65.14530 TGW
08/13/93 08:59 65.14510 TGW
08/04/93 13:54 67.91060 TGW
08/05/93 08:13 67.91070 TGW
Constant
Final
Weight (g)
64.95360
64.50420
66.86980
65.14510
67.91070
-------
ETS, Inc.
GRAVIMETRIC LABORATORY DATA
Final Beaker Weights
Job Number: 92-655WA
Report Prepared on: 08/13/93
Page
Beaker #
Filter I
Sample f
Run I.D.
Total Vol., ml
Aliquot Vol.
07/07/93-021
92-655WA-00216
KCE-1A2-R3
79.00000
79.00000
07/07/93-031
92-655WA-00217
KCE-1A2-R3
07/07/93-032
92-655WA-00218
KCE-1A2-R3
07/30/93-014
92-655WA-00218
KCE-1A2-R3
07/07/93-033
92-655WA-00219
KCE-1A2-R3
Constant
Tare
Weight (g)
Beaker
Filter
64.49090
0.00000
64.54770
0.00000
66.88820
0.00000
65.21750
0.00000
64.25800
0.00000
Final Weight Data
Date Time Weight (g) Analyst
08/04/93 13:54 64.51030 TGW
08/05/93 08:13 64.51030 TGW
08/12/93 11:25 64.56770 TGW
08/13/93 08:00 64.56860 TGW
08/13/93 14:37 64.56810 TGW
08/12/93 11:25 66.90770 TGW
08/13/93 09:01 66.90780 TGW
08/12/93 11:28 65.24170 TGW
08/13/93 08:04 65.24230 TGW
08/13/93 14:38 65.24200 TGW
08/12/93 11:26 64.28510 TGW
08/13/93 09:01 64.28480 TGW
Constant
Final
Weight (g)
64.51030
64.56810
66.90780
65.24200
64.28480
-------
ETS, Inc.
GRAVIMETRIC LABORATORY DATA
Final Beaker Heights
Job Number: 92-655WA
Report Prepared on: 08/13/93
Page
Beaker f
Filter #
Sample I
Run I.D.
Total Vol., ml
Aliquot Vol.
07/07/93-022
92-0145
92-655WA-00221
KCE-1A2-RO
07/07/93-023
92-655WA-00222
KCE-1A2-RO
110.00000
110.00000
07/07/93-024
92-655WA-00223
KCE-1A2-RO
120.00000
120.00000
07/30/93-009
92-655WA-00224
KCE-1A2-RO
07/30/93-010
92-655WA-00225
KCE-1A2-RO
Constant
Tare
Weight (g)
Beaker
Filter
66.86770
0.39883
64.00410
0.00000
67.69890
0.00000
64.59390
0.00000
64.89250
0.00000
Final Height Data
Date Time Height (g) Analyst
08/04/93 13:55 67.26610 TGW
08/05/93 08:14 67.26570 TGW
08/04/93 13:55 64.00450 TGW
08/05/93 08:14 64.00420 TGW
08/04/93 13:55 67.69880 TGW
08/05/93 08:15 67.69850 TGW
08/12/93 11:26 64.60980 TGW
08/13/93 09:02 64.60970 TGW
08/12/93 11:27 64.90620 TGW
08/13/93 09:02 64.90660 TGW
Constant
Final
Weight (g)
67.26570
64.00420
67.69850
64.60970
64.90660
-------
ETS, Inc.
GRAVIMETRIC LABORATORY DATA
Final Beaker Weights
Job Number: 92-655WA
Report Prepared on: 08/13/93
Page
Beaker f
Filter *
Sample f
Run I.D.
Total Vol., ml
Aliquot Vol.
07/30/93-011
92-655WA-00226
KCB-1A2-RO
Constant
Tare
Weight (g)
Beaker
Filter
66.31110
0.00000
Final Weight Data
Date Time Weight (g) Analyst
08/12/93 11:27 66.33990 TGW
08/13/93 09:03 66.34010 TGW
Constant
Final
Weight (g)
66.34010
-------
GTS, Inc.
GRAVIMETRIC LABORATORY DATA
Silica Gel Weights
Report Prepared on: 08/03/93
Page
Sample
Number
92-655WA-00206
92-655WA-00213
92-655WA-00220
92-655WA-00227
Tare Weight (g)
200.0000
200.0000
200.0000
200.0000
Final Weight (g)
212.2600
208.8400
215.3700
199.9800
Description
tan/light purple
light purple/pink
pink/ light purple
blue
-------
E T S , INC.
FIELD SAMPLE LOG
Contract No. 92-655WA
Job I.D.
Test Method M29
Print Date OB/02/93 Time 11:47:34
Page 1
Sample
No.
00700
00701
00702
00703
00704
00705
00706
00707
00708
00709
00710
00711
00712
00713
00714
00715
00716
00717
00718
00719
00720
00721
00722
00723
00724
00725
00726
Container
No.
Fl
F2
F3
F4A
F4B
F5A
FSB
F5C
F6
Fl
F2
F3
F4A
F4B
F5A
FSB
F5C
F6
Fl
F2
F3
F4A
F4B
F5A
FSB
F5C
F6
Other
I.D.
Q10/15/92-0037
Q10/15/92-0038
Q10/15/92-0039
Run
I.D.
KCE-M29-R1
KCE-M29-R1
KCE-M29-R1
KCE-M29-R1
KCE-M29-R1
KCE-M29-R1
KCE-M29-R1
KCE-M29-R1
KCE-M29-R1
KCE-M29-R2
KCE-M29-R2
KCE-M29-R2
KCE-M29-R2
KCE-M29-R2
KCE-M29-R2
KCE-M29-R2
KCE-M29-R2
KCE-M29-R2
KCE-M29-R3
KCE-M29-R3
KCE-M29-R3
KCE-M29-R3
KCE-M29-R3
KCE-M29-R3
KCE-M29-R3
KCE-M29-R3
KCE-M29-R3
Sample
Type
Quartz Filter
FH Acetone Rinse
FH Nitric Rinse
Imp. 1-3 + Rinses
Imp. 1-3 + Rinses
Imp. 4 + Rinses
IMP 5,6+RINSE (+H2O)
Water+HCl Rinse 5+6
Imp. 7 Silica Gel
Quartz Filter
FH Acetone Rinse
FH Nitric Rinse
Imp. 1-3 + Rinses
Imp. 1-3 + Rinses
Imp. 4 + Rinses
IMP 5,6+RINSE (+H20)
Water+HCl Rinse 5+6
Imp. 7 Silica Gel
Quartz Filter
FH Acetone Rinse
FH Nitric Rinse
Imp. 1-3 + Rinses
Imp. 1-3 + Rinses
Imp. 4 + Rinses
IMP 5,6+RINSE (+H2O)
Water+HCl Rinse 5+6
Imp. 7 Silica Gel
Volume, ml
no Rinses
Volume, ml
w/ Rinses
Analyst
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
pjb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
Date
08/02/93
08/02/93
08/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
Comments
-------
E T S , INC.
FIELD SAMPLE LOG
Contract No. 92-65SWA
Job I.D.
Test Method M29
Print Date OB/02/93
Page 2
Sample
No.
00727
00728
00729
00730
00731
00732
00733
00734
00735
Container
No.
Fl
F2
F3
F4A
F4B
F5A
FSB
F5C
F6
Other
I.D.
Q10/15/92-0040
Run
I.D.
KCE-M29-RO
KCE-M29-RO
KCE-M29-RO
KCE-M29-RO
KCE-M29-RO
KCE-M29-RO
KCE-M29-RO
KCE-M29-RO
KCE-M29-RO
Sample
Type
Quartz Filter
FH Acetone Rinse
FH Nitric Rinse
Imp. 1-3 + Rinses
Imp. 1-3 + Rinses
Imp. 4 + Rinses
IMP 5,6+RINSE (+H20)
Water+HCl Rinse 5+6
Imp. 7 Silica Gel
Volume, ml
no Rinses
Volume, ml
w/ Rinses
Analyst
PJb
PJb
PJb
PJb
PJb
pjb
PJb
PJb
PJb
Date
08/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
Comments
-------
ETS, Inc.
GRAVIMETRIC LABORATORY DATA
Tare Beaker Weights
Report Prepared on: 08/03/93
Page
Beaker
Number
04/08/93-001
04/08/93-002
04/08/93-003
04/08/93-004
04/08/93-005
04/08/93-006
04/08/93-007
04/08/93-008
Date
05/04/93
05/07/93
05/04/93
05/07/93
05/04/93
05/07/93
05/04/93
05/21/93
05/04/93
05/06/93
05/07/93
05/04/93
05/21/93
05/04/93
05/06/93
05/14/93
05/21/93
05/04/93
05/21/93
Time
15:30
11:20
15:29
09:50
15:32
09:51
15:33
14:14
15:27
14:21
10:00
15:31
14:16
15:25
10:05
15:20
14:16
15:24
14:18
Weight (g)
64.54570
64.54610
67.07360
67.07370
64.45080
64.45030
67.94340
67.94350
64.86260
64.86200
64.86250
64.32930
64.32910
64.69810
64.69910
64.69920
64.69950
64.64180
64.64150
Analyst
TLP
WLL
TLP
TLP
TLP
TLP
TLP
PJB
TLP
TLP
TLP
TLP
PJB
TLP
TLP
RKT
PJB
TLP
PJB
Constant
Weight (g)
64.54610
67.07370
64.45030
67.94350
64.86250
64.32910
64.69950
64.64150
-------
ETS, Inc.
GRAVIMETRIC LABORATORY DATA
Tare Filter Weights
Filter Description: Quartz
Report Prepared oni 08/03/93
Page
Filter
Number
Q10/15/92-0037
Q10/15/92-0038
Q10/15/92-0039
Q10/15/92-0040
Date Time
12/07/92 08:38
12/08/92 13:42
12/09/92 11:00
01/22/93 11:21
01/27/93 12:16
12/07/92 11:00
12/08/92 13:43
12/07/92 08:49
12/08/92 13:45
12/09/92 11:00
01/22/93 11:06
01/27/93 12:23
12/07/92 08:46
12/08/92 13:47
12/09/92 11:00
Weight (g)
0.45120
0.44580
0.44380
0.4349
0.43440
0.44170
0.44220
0.46820
0.45960
0.45330
0.4438
0.44340
0.44530
0.44810
0.44830
Analyst
TLP
TLP
TLP
PJB
PJB
TLP
TLP
TLP
TLP
TLP
PJB
PJB
TLP
TLP
TLP
Constant
Weight (g)
0.43440
0.44220
0.44340
0.44830
-------
ETS, Inc.
GRAVIMETRIC LABORATORY DATA
Final Beaker Weights
Job Number: 92-655WA
Report Prepared on: 08/03/93
Page
Beaker f
Filter 1
Sample f
Run I.D.
Total Vol., ml
Aliquot Vol.
04/08/93-001
Q10/15/92-0037
92-655WA-00700
KCE-M29-R1
04/08/93-002
92-655WA-00701
KCE-M29-R1
132.00000
132.00000
04/08/93-003
Q10/15/92-0038
92-655WA-00709
KCE-M29-R2
04/08/93-004
92-655WA-00710
KCE-M29-R2
130.00000
130.00000
04/08/93-005
Q10/15/92-0039
92-655WA-00718
KCE-M29-R3
Constant
Tare
Weight (g)
Beaker
Filter
64.54610
0.43440
67.07370
0.00000
64.45030
0.44220
67.94350
0.00000
64.86250
0.44340
Final Weight Data
Date Time Weight (g) Analyst
08/03/93 12:05 65.52060 PJB
08/03/93 18:20 65.52030 PJB
08/03/93 12:05 67.08510 PJB
08/03/93 18:20 67.08480 PJB
08/03/93 12:05 65.45640 PJB
08/03/93 18:20 65.45660 PJB
08/03/93 12:05 67.95310 PJB
08/03/93 18:21 67.95340 PJB
08/03/93 12:06 65.91100 PJB
08/03/93 18:21 65.91150 PJB
Constant
Final
Weight (g)
65.52030
67.08480
65.45660
67.95340
65.91150
-------
* ETS, Inc.
GRAVIMETRIC LABORATORY DATA
Final Beaker Weights
Job Number: 92-655WA
Report Prepared on: 08/03/93
Page
Beaker f
Filter f
Sample f
Run I.D.
Total Vol., ml
Aliquot Vol.
04/08/93-006
92-655WA-00719
KCE-M29-R3
120.00000
120.00000
04/08/93-007
Q10/15/92-0040
92-655WA-00727
KCE-M29-RO
04/08/93-008
92-655WA-00728
KCE-M29-RO
125.00000
125.00000
Constant
Tare
Weight
-------
ETS, Inc.
GRAVIMETRIC LABORATORY DATA
Silica Gel Weights
Report Prepared on: 08/03/93
Page
Sample
Number
92-655WA-00708
92-655WA-00717
92-655WA-00726
92-655WA-00735
Tare Weight (g)
200.0000
200.0000
200.0000
200.0000
Final Weight (g)
216.5300
216.2100
214.9200
200.0100
Description
teal/tan
orange/ It . purple
pink/teal
blue
-------
APPENDIX D.3.2
EPA METHOD 29 MULTIPLE METALS LABORATORY DATA
-------
ETS Analytical Services, Inc.
Proudly serving industry and government since 1973.
A subsidiary of ETS International, Inc.
A USEPA Contract Laboratory
RECEIVE) SEP S 1
ETS, Inc.
1401 Municipal Road N.W.
Roanoke, VA 24012
ATTN: Dr. Ted Handel
Re: Laboratory Analysis
Project #92-655 WA-14
REPORT DATE/NUMBER: September 21, 1993
SAMPLES COLLECTED BY:
ANALYSIS FOR: Metals by Inductively Coupled Plasma Emission (ICP), Graphite
Furnace Atomic Absorption (GFAAS), and Cold Vapor AAS
METHOD OF ANALYSIS: Methodology for the Determination of Trace Metal Emissions
in Exhaust Gasses From Stationary Combustion Processes, USEPA
INSTRUMENTAL: Bacharach CVAAS, 2000 ICP, PE Z5100 GFAAS
SAMPLE PREPARATION INFORMATION
INIT VOL
LAB ID
144268
144269
144270
144271
144272
144273
144274
144275
144276
144277
144278
144279
1442BO
144281
144282
144283
144284
RUN #
KCE-M29-R1
KCE-M29-R1
KCE-M29-R1
KCE-M29-R1
KCE-M29-R1
KCE-M29-R2
KCE-M29-R2
KCE-M29-R2
KCE-M29-R2
KCE-M29-R2
KEC-M29-R3
KEC-M29-R3
KCE-M29-R3
KCE-M29-R3
KCE-M29-R3
KCE-M29-RO
KCE-M29-RO
FRACTION
1A
2A
3A
3B
3C
1A
2A
3A
3B
3C
1A
2A
3A
3B
3C
1A
1A
&
&
&
6
&
&
&
&
IB
2B
IB
2B
IB
2B
IB
IB
(ml)
128
498
98
503
110
104
510
103
513
118
108
500
103
465
158
112
347
DIG VOL
ICP/AAS
128
398
110
104
410
118
108
400
158
112
247
FIN VOL
ICP/AAS
300
150
500
300
150
500
300
150
500
300
150
DIG VOL
CVAAS
1
10
10
10
10
1
10
10
10
10
1
10
10
10
10
10
10
REPORT CONTINUED ON NEXT PAGE
1401 Municipal Road, NW - Roanoke, Virginia 24012-1309 - Telephone: 703-265-0004 - FAX: 703-563-4866
^ft Printed on recycled paper @ Printed on recyclable paper
-------
ETS, Inc. / 192-655 WA-14
Report of September 21, 1993
Page No. 2
1
UYTV.I. J.WI1
INIT VOL
LAB ID
144285
144286
144287
1
Rim I FRACTION
KCE-M29-RO 3A
KCE-M29-RO 3B
KCE-M29-RO 3C
(ml)
98
478
120
DIG VOL FIN VOL DIG VOL
ICP/AAS ICP/AAS CVAAS
10
10
120 500 10
1
SAMPLE ANALYSIS DATA
Lab ID: 144268 Description: Fraction 1A & IB
Antimony
Train ID: KCE-M29-R1
12.40 yg, Total
U=>Comments: Solution Concentrations 41.20 ug/1
Arsenic 106.00 pg, Total
lt>Comments: Solution Concentrations 352.40 ug/1
Beryllium 12.40 \iq, Total
lt>Comments: Solution Concentration^ 41.40 ug/1
Cadmium 3.36 yg, Total
lt>Comments: Solution Concentrations 11.20 ug/1
Chromium 65.20 pg, Total
^Comments: Solution Concentrations 217.30 ug/1
Lead 61.80 pg, Total
lt>comments: solution Concentrations 205.90 ug/1
Manganese 34.90 pg, Total
^Comments: Solution Concentrations 116.40 ug/1
Mercury 65.40 pg, Total
lt>comments: Solution Concentrations 218.00 ug/1
Nickel 136.00 pg, Total
li>Comments: Solution Concentrations 452.40 ug/1
Phosphorus 452.00 fjg, Total
lt>Comments: Solution Concentration^ 1507.50 ug/1
Selenium 371.00 yg, Total
t>comments: Solution Concentration^ 1237.00 ug/1
Lab ID: 144269 Description: Fraction 2A & 2B
Antimony
Train ID: KCE-M29-R1
0.78 fjg, Total
L>Comments: Solution Concentration^ 4.16 ug/1
Arsenic 2.77 j;g, Total
t>Comments
Beryllium
Solution Concentration^ 14.76 ug/1
< 0.02 fjg, Total
l>comments: Solution Concentrations <0.10 ug/1
Cadmium 0.46 pg, Total
L>comments: Solution Concentrations 2.45 ug/1
Chromium 2.05 yg, Total
IL>comment8: solution Concentrations 10.94 ug/1
Lead -—• 15.80 \tq, Total
lt>connnents: Solution concentration^ 84.10 ug/1
REPORT CONTINUED ON NEXT PAGE
Printed on recycled paper ^ Printed on recyclable paper
-------
ETS, inc. / 192-655 WA-14
Report of September 21, 1993
Page No. 3
Lab ID: 144269 (continued)
Manganese
SAMPLE ANALYSIS DATA
7.88 yg, Total
t>Comments: Solution Concentrations 42.00 ug/1
Mercury 19.10 yg, Total
^Comments: solution Concentration^ 38.30 ug/1
Nickel 1.27 pg, Total
t>Commente: Solution Concentrations 6.75 ug/1
Phosphorus < 93.80 \iq, Total
t>comments: Solution Concentrations <500.00 ug/1
Selenium 0.77 pg, Total
IL>comments: Solution Concentrations 4.08 ug/1
Lab ID: 144270 Description: Fraction 3A
Mercury
Train ID: KCE-M29-R1
- < 0.20 jjg, Total
lt>Comments: Solution Concentration* <2.00 ug/1
Lab ID: 144271 Description: Fraction 3B
Mercury
Train ID: KCE-M29-R1
< 1.01 pg, Total
lt>connnents: Solution Concentrations <2.00 ug/1
Lab ID: 144272 Description: Fraction 3C
Mercury
Train ID: KCE-M29-R1
< 1.00 pg, Total
lt>Comments: Solution Concentrations <2.00 ug/1
Lab ID: 144273 Description: Fraction 1A & IB
Antimony
Train ID: KCE-M29-R2
10.90 pg, Total
^Comments: Solution Concentrations 36.40 ug/1
Arsenic 110.00 pg, Total
l>Conrunents: Solution Concentrations 365.10 ug/1
Beryllium 13.30 yg, Total
l!=>Comments: Solution Concentrations 44.20 ug/1
Cadmium 2.73 yg, Total
H=>commentB: solution Concentrations 9.10 ug/1
chromium 67.40 pg, Total
lL>comments: Solution Concentrations 224.80 ug/1
Lead 56.30 pg, Total
L>comments: Solution Concentrations 187.50 ug/1
Manganese 39.00 pg, Total
t>comments: Solution Concentration^ 130.10 ug/1
Mercury 72.00 pg, Total
^Comments: Solution Concentration^ 240.00 ug/1
Nickel 142.00 ^g, Total
B>>comments: Solution Concentrations 474.70 ug/1
Phosphorus 451.00 yg, Total
&>Comments: Solution Concentrations 1503.70 ug/1
REPORT CONTINUED ON NEXT PAGE
Printed on recycled paper ~f~L Printed on recyclable paper
-------
ETS, Inc. / #92-655 WA-14
Report of September 21, 1993
Page No. 4
Lab ID: 144273 (continued)
Selenium
SAMPLE ANALYSIS DATA
361.00 yg, Total
l>Comments: Solution Concentrations 1202.00 ug/1
Lab ID: 144274 Description: Fraction 2A & 2B
Antimony
Train ID: KCE-M29-R2
< 0.37 yg, Total
&>Comments: Solution Concentration^ <2.00 ug/1
Arsenic 2.45 jjg, Total
(^comments: Solution Concentrations 13.12 ug/1
Beryllium < 0.02 pg, Total
U>comments: Solution Concentrations <0.10 ug/1
Cadmium 0.37 pg, Total
^Comments: Solution Concentrations 1.96 ug/1
chromium 2.16 pg, Total
^Comments: Solution Concentrations 11.59 ug/1
Lead 23.00 pg, Total
^Comments: Solution Concentration^ 123.50 ug/1
Manganese 1.85 yg, Total
lt>Comments: Solution Concentrations 9.90 ug/1
Mercury 3.21 yg, Total
lt>comments: Solution Concentrations 6.30 ug/1
Nickel 1.51 fjg, Total
l!=>comments: solution Concentrations 8.08 ug/1
Phosphorus < 93.30 yg, Total
t>CommentB: Solution Concentrations <500.00 ug/1
Selenium : < 0.37 \iq, Total
li>Comments: Solution Concentrations <2.00 ug/1
Lab ID: 144275 Description: Fraction 3A
Mercury
Train ID: KCE-M29-R2
< 0.21 pg, Total
IL>comments: Solution Concentrations <2.00 ug/1
Lab ID: 144276 Description: Fraction 3B
Mercury
Train ID: KCE-M29-R2
< 1.03 pg, Total
!>Comments: Solution Concentrations <2.00 ug/1
Lab ID: 144277 Description: Fraction 3C
Mercury
Train ID: KCE-M29-R2
- < 1.00 ^g, Total
lt>comments: Solution Concentrations <2.00 ug/1
Lab ID: 144278 Description: Fraction 1A & IB Train ID: KEC-M29-R3
Antimony 11.30 pg, Total
&>comments: Solution Concentrations 37.60 ug/1
Arsenic 111.00 tig, Total
^Comments: Solution Concentrations 368.80 ug/1
REPORT CONTINUED ON NEXT PAGE
Printed on recycled paper -£i Printed on recyclable paper
-------
ETS, Inc. / #92-655 WA-14
Report of September 21, 1993
Page No. 5
Lab ID: 144278 (continued)
Beryllium
SAMPLE ANALYSIS DATA
13.40 pg, Total
^Comments: Solution Concentration** 44.80 ug/1
Cadmium 1.80 pg, Total
l>Comments: solution Concentration- 6.00 ug/1
Chromium 73.10 yg, Total
H>Comments: Solution Concentration^ 243.50 ug/1
Lead 60.60 yg, Total
H>>Comments: Solution Concentration^ 202.00 ug/1
Manganese 36.70 pg, Total
lt>Comments: solution Concentration^ 122.40 ug/1
Mercury 80.10 nq, Total
lt>Comments: solution Concentration^ 267.00 ug/1
Nickel 162.00 yg, Total
IL>Comments: Solution Concentration^ 538.40 ug/1
Phosphorus 471.00 pg, Total
lk>comments: solution Concentration^ 1571.60 ug/1
selenium 417.00 pg, Total
Uoconunents: solution Concentration^ 1390.00 ug/1
Lab ID: 144279 Description: Fraction 2A & 2B
Antimony
Train ID: KEC-M29-R3
0.56 pg, Total
IL>Comments: Solution Concentration= 2.99 ug/1
Arsenic - 2.05 pg, Total
^Comments: solution Concentration^ 10.92 ug/1
Beryllium - < 0.02 pg, Total
^Comments : solution Concentration^ <0.10 ug/1
Cadmium - 0.10 pg, Total
t>Comments : solution concentration^ 0.54 ug/1
Chromium - 1.85 \iq, Total
li>Comment8 : Solution Concentration= 9.88 ug/1
Lead - 2.74 pg, Total
^Comments: solution Concentration^ 14.60 ug/1
Manganese
3.30
Total
H>Comments : solution Concentration^ 17.60 ug/1
Mercury - 2.00 yg, Total
H>Comments : Solution Concentration^ 4.00 ug/1
Nickel - 0.95 yg, Total
&>Comments : solution Concentration^ 5.09 ug/1 •
Phosphorus - < 93.80 pg, Total
H>>Comments: Solution Concentration^ <500.00 ug/1
Selenium - 0.78 yg, Total
^Comments: solution Concentrations 4.14 ug/1
REPORT CONTINUED ON NEXT PAGE
Printed on recvcled oaoer •£: Printed on recyclable -M-aer
-------
ETS, Inc. / f92-655 WA-14
Report of September 21, 1993
Page No. 6
SAMPLE ANALYSIS DATA
Lab ID: 144280 Description: Fraction 3A Train ID: KCE-M29-R3
Mercury < 0.21 pg, Total
&>Comments: solution Concentrations <2.00 ug/1
Lab ID: 144281 Description: Fraction 3B Train ID: KCE-M29-R3
Mercury < 0.93 jjg, Total
i>Comments: Solution Concentration* <2.00 ug/1
Lab ID: 144282 Description: Fraction 3C Train ID: KCE-M29-R3
Mercury < 1.00 pg, Total
&>comments: Solution Concentrations <2.00 ug/1
Lab ID: 144283 Description: Fraction 1A & IB Train ID: KCE-M29-RO
Antimony < 0.60 yg, Total
!>Comments: Solution Concentrations <2.00 ug/1
Arsenic < 0.30 pg, Total
&>Comments: Solution Concentrations <1.00 ug/1
Beryllium < 0.03 yg, Total
^>Comments: Solution Concentrations <0.10 ug/1
Cadmium 0.09 yg, Total
&>Comments: Solution Concentrations 0.31 ug/1
Chromium 4.20 pg, Total
&>Comment8: Solution Concentrations 14.00 ug/1
Lead 1.06 pg, Total
l>Comments: Solution Concentrations 3.52 ug/1
Manganese 1.41 pg, Total
&>Comments: Solution Concentrations 4.70 ug/1
Mercury < 0.60 fig, Total
fc>Comments: Solution Concentrations <2.00 ug/1
Nickel 2.72 yg, Total
t>Comments: Solution Concentration^ 9.07 ug/1
Phosphorus < 150.00 pg, Total
l>Coiranent8: Solution Concentrations <500.00 ug/1
Selenium < 0.60 yg, Total
l>comments: Solution Concentrations <2.00 ug/1
Lab ID: 144284 Description: Fraction 1A & IB Train ID: KCE-M29-RO
Antimony < 0.42 yg, Total
L>comments: Solution Concentrations <2.00 ug/1
Arsenic < 0.21 yg, Total
!>>Comments: Solution Concentrations <1.00 ug/1
Beryllium < 0.02 pg, Total
L>Comments: Solution Concentrations <0.10 ug/1
Cadmium 0.05 pg, Total
L>Comments: Solution Concentrations 0.22 ug/1
Chromium 1.23 pg, Total
l>CommentB: Solution Concentrations 5.82 ug/1
REPORT CONTINUED ON NEXT PAGE
Printed on recycled paper "JZ Printed on recyclable paper
-------
ETS, Inc. / 192-655 WA-14
Report of September 21, 1993
Page No. 7
SAMPLE ANALYSIS DATA
I
Lab ID: 144284 (continued)
Lead < 0.21 yg, Total
^Comments: Solution Concentration^ <1.00 ug/1
Manganese 0.59 pg, Total
&>Comments: Solution Concentration** 2.80 ug/1
Mercury < 0.60 yg, Total
l!=>Comments: Solution Concentration^ <2.00 ug/1
Nickel 1.16 \tq, Total
^Comments: Solution Concentration^ 5.51 ug/1
Phosphorus < 105.00 pg, Total
li>Comments: Solution Concentration= <500.00 ug/1
Selenium < 0.42 ^g, Total
lk>Comments: Solution Concentration= <2.00 ug/1
Lab ID: 144285 Description: Fraction 3A Train ID: KCE-M29-RO
Mercury < 0.20 pg, Total
^comments: Solution Concentrations <2.00 ug/1
Lab ID: 144286 Description: Fraction 3B Train ID: KCE-M29-RO
Mercury < 0.96 pg, Total
U=>CommentB: Solution Concentration^ <2.00 ug/1
Lab ID: 144287 Description: Fraction 3C Train ID: KCE-M29-RO
Mercury < 1.00 pg, Total
l>Comments: Solution Concentration^ <2.00 ug/1
If we may be of further assistance, please contact us at any time.
sincerely,
ETS ANALYTICAL SERVICES
Susanne H. Deegan
AS Department Manager
-------
ElG
ETS, Inc. / 192-655 WA-14
Report of September 21, 1993
Page No. 8
QUALITY ASSURANCE SUMMARY
CALIBRATION
ANALYTE
Antimony (Sb)
Arsenic (As)
Beryllium (Be)
Cadmium (Cd)
Cadmium (Cd)
Cadmium (Cd)
chromium (Cr)
Chromium (Cr)
Lead (Pb)
Lead (Pb)
Manganese (Mn)
Mercury ( Hg )
Mercury (Hg)
Nickel (Ni)
Nickel (Ni)
Phosphorus (P)
Selenium (Se)
Selenium (Se)
Selenium (Se)
UNITS
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
TRUE
1024.0
50.90
478.00
493.00
493.00
100.90
480.00
480.00
4739.0
98.40
474.00
5.00
5.00
488.00
488.00
2500.0
50.70
50.70
50.70
FOUND
998.00
50.60
471.90
476.90
504.10
102.80
473.40
510.60
5058.4
101.80
450.10
5.30
5.00
505.60
499.60
2475.1
50.50
50.40
51.20
% REC
97.5
99.4
98.7
96.7
102.3
101.9
98.6
106.4
106.7
103.5
95.0
106.0
100.0
103.6
102.4
99.0
99.7
99.4
101.0
QAO
85% to 115% REC
85% to 115% REC
85% to 115% REC
85% to 115% REC
85% to 115% REC
85% to 115% REC
85% to 115% REC
85% to 115% REC
85% to 115% REC
85% to 115% REC
85% to 115% REC
85% to 115% REC
85% to 115% REC
85% to 115% REC
85% to 115% REC
85% to 115% REC
85% to 115% REC
85% to 115% REC
85% to 115% REC
DUPLICATES
LAB ID
144268
144268
144268
144268
144268
144268
144268
144268
144268
144268
144268
144269
ANALYTE
Antimony
Arsenic
Beryllium
Cadmium
chromium
Lead
Manganese
Mercury
Nickel
Phosphorui
Selenium
Antimony
SAMPLE
12.36
105.72
12.42
3.36
65.19
61.77
34.92
65.40
135.72
452.25
371.10
0.78
DUPLICATE
11.78
107.46
12.21
3.33
60.39
62.94
34.65
65.10
141.66
397.86
364.20
0.68
UNITS
fjg, Total
fjg, Total
pg, Total
pg, Total
pg, Total
pg, Total
yg, Total
jjg, Total
fjg, Total
pg, Total
pg, Total
pg, Total
RPD
4.8
1.6
1.7
0.9
7.6
1.9
0.8
0.5
4.3
12.8
1.9
13.3
QAO
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
Printed on recycled paper £i Printed on recyclable paper
-------
ETS, inc. / #92-655 HA-14
Report of September 21, 1993
Page No. 9
QUALITY ASSURANCE SUMMARY
——= Continued «===
DUPLICATES
LAB ID
144269
144269
144269
144269
144269
144269
144269
144269
144269
144269
144270
144271
144272
144273
144273
144273
144273
144274
144274
144274
144274
144274
144274
144274
144274
144274
144275
144276
144277
144278
144278
144278
144278
144279
144279
144279
144279
144279
144279
ANALYTE
Arsenic
Beryllium
Cadmium
Chromium
Lead
Manganese
Mercury
Nickel
Phosphorui
Selenium
Mercury
Mercury
Mercury
Antimony
Arsenic
Mercury
Selenium
Antimony
Arsenic
Beryllium
Cadmium
chromium
Lead
Mercury
Nickel
Selenium
Mercury
Mercury
Mercury
Antimony
Arsenic
Mercury
Selenium
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Lead
SAMPLE
2.77
<0.02
0.46
2.05
15.78
7.88
19.07
1.27
03.84
0.77
<0.20
<1.01
<1.00
10.92
109.53
72.00
360.60
<0.37
2.45
<0.02
0.37
2.16
23.04
3.21
1.51
<0.37
<0.21
<1.03
<1.00
11.28
110.64
80.10
417.00
0.56
2.05
<0.02
0.10
1.85
2.74
DUPLICATE
2.66
<0.02
0.46
2.27
18.77
8.54
19.17
1.44
03.84
<0.38
<0.20
<1.01
<1.00
10.88
110.64
72.60
347.10
0.39
2.41
<0.02
0.37
2.16
23.85
3.47
1.54
<0.37
<0.21
<1.03
<1.00
11.50
111.48
78.90
401.10
0.49
1.71
<0.02
0.10
1.88
2.72
UNITS
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg. Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
>ort continued on Next Page
RPD
4.2
NC
0.8
10.2
17.3
8.0
0.5
12.6
0.0
NC
NC
NC
NC
0.4
1.0
0.8
3.8
NC
1.6
NC
2.0
0.1
3.4
7.6
2.0
NC
NC
NC
NC
1.9
0.8
1.5
3.9
14.0
18.0
NC
1.9
1.4
0.8
O.AO
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
Printed on recvcled Ta-ser ^ Printed on recyclable wxr
-------
ETS, Inc. / 192-655 WA-14
Report of September 21, 1993
Page No. 10
QUALITY ASSURANCE SUMMARY
•== Continued «=™==
DUPLICATES
LAB ID
144279
144279
144279
144280
144281
144282
144283
144283
144283
144283
144283
144283
144283
144283
144284
144284
144284
144284
144284
144284
144284
144284
144284
144285
144286
144287
ANALYTE
Mercury
Nickel
Selenium
Mercury
Mercury
Mercury
Antimony
Arsenic
Beryllium
Cadmium
Lead
Mercury
Nickel
Selenium
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Lead
Mercury
Nickel
Selenium
Mercury
Mercury
Mercury
SAMPLE
2.00
0.95
0.78
<0.21
<0.93
<1.00
<0.60
<0.30
<0.03
0.09
1.06
<0.60
2.72
<0.60
<0.42
<0.21
<0.02
0.05
1.23
<0.21
<0.60
1.16
<0.42
<0.20
<0.96
<1.00
DUPLICATE
<1.00
0.80
<0.38
<0.21
<0.93
<1.00
<0.60
<0.30
<0.03
0.09
1.09
<0.60
2.65
<0.60
<0.42
<0.21
<0.02
0.03
1.27
<0.21
<0.60
1.14
<0.42
<0.20
<0.96
<1.00
UNITS
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
RPD
NC
17.8
NC
NC
NC
NC
NC
NC
NC
6.7
3.1
NC
2.8
NC
NC
NC
NC
37.8
3.9
NC
NC
1.6
NC
NC
NC
NC
QAO
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
<26 RPD or 2X IDL
SPIKES
LAB ID
144268
144268
144268
144268
144268
ANALYTE
Antimony
Arsenic
Beryllium
Cadmium
Chromium
SA RESULT
41.20
352.40
41.40
11.20
217.30
tenort Contii
SPK RESULT
141.65
677.00
93.30
550.10
413.90
med on Next I
SPK ADD | % REC | QAO
100
400
50
50
200
100.5
96.9
103.8
101.4
98.3
75%-125%
75%-125%
75%-125%
75%-125%
75%-125%
Printed on recycled paper yS Printed on recyclable paper
-------
ETS, Inc. / 192-655 WA-14
Report of September 21, 1993
Page No. 11
QUALITY ASSURANCE SUMMARY
===-== Continued —=•—•=
SPIKES
LAB ID
144268
144268
144268
144268
144268
144268
144269
144269
144269
144269
144269
144269
144269
144269
144269
144269
144269
144270
144271
144272
ANALYTE
Lead
Manganese
Mercury
Nickel
Phosphorus
Selenium
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Lead
Manganese
Mercury
Nickel
Phosphorus
Selenium
Mercury
Mercury
Mercury
SA RESULT
205.90
116.40
218.00
452.40
1507.50
1237.00
4.16
14.76
<0.10
2.45
10.94
84.10
42.00
38.30
6.75
<500.00
4.08
<2.00
<2.00
<2.00
SPK RESULT
759.30
657.70
309.00
1005.60
11570.80
2181.50
2.99
33.63
53.50
4.34
12.11
859.50
595.20
43.00
24.90
8792.10
4.71
9.90
10.50
9.70
SPK ADD
500
500
100
500
10000
1000
20
20
50
87
1
500
500
5
20
10000
10
10
10
10
% REC
110.7
108.3
91.0
110.6
100.6
94.5
-5.9
94.4
106.8
87.4
117.0
85.4
110.6
94.0
90.8
82.9
6.3
99.0
105.0
97.0
QAO
75%-125%
75%-125%
75%-125%
75%-125%
75%-125%
75%-125%
75%-125%
75%-125%
75%-125%
75%-125%
75%-125%
75%-125%
75%-125%
75%-125%
75%-125%
75%-125%
75%-125%
75%-125%
75%-125%
75%-125%
QAO: Quality Assurance Objective; RECt Recovery; RPD: Relative Percent Difference
NC: Not Calculatable; IDL: Instrument Detection Limit
-------
ETS, Inc. / #92-655 WA-14
Report of September 21, 1993
Page No. 12
DETECTION LIMITS SUMMARY
LAB ID
144268
144268
144268
144268
144268
144268
144268
144268
144268
144268
144268
144269
144269
144269
144269
144269
144269
144269
144269
144269
144269
144269
144270
144271
144272
144273
144273
144273
144273
144273
144273
144273
144273
144273
144273
144273
144274
144274
ANALYTE
Antimony
Arsenic
Beryllium
cadmium
Chromium
Lead
Manganese
Mercury
Nickel
Phosphorus
Selenium
Antimony
Arsenic
Beryllium
Cadmium
chromium
Lead
Manganese
Mercury
Nickel
Phosphorus
Selenium
Mercury
Mercury
Mercury
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Lead
Manganese
Mercury
Nickel
Phosphorus
Selenium
Antimony
Arsenic
DET LIMIT
0.60
0.30
0.30
1.50
0.60
0.30
0.60
6.00
4.80
150.00
0.60
0.38
0.19
0.02
0.02
0.38
0.19
0.38
1.00
0.38
93.84
0.38
0.20
1.01
1.00
0.60
0.30
0.30
1.50
0.60
0.30
0.60
6.00
4.80
150.00
0.60
0.37
0.19
UNITS
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
INSTRUMENT DL
2.00
1.00
1.00
5.00
2.00
1.00
2.00
20.00
16.00
500.00
2.00
2.00
1.00
0.10
0.10
2.00
1.00
2.00
2.00
2.00
500.00
2.00
2.00
2.00
2.00
2.00
1.00
1.00
5.00
2.00
1.00
2.00
20.00
16.00
500.00
2.00
2.00
1.00
UNITS
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
Printed on recycled paper -^£ Printed on recyclable paper
-------
Etfi
ETS, Inc. / §92-655 WA-14
Report of September 21, 1993
Page No. 13
DETECTION LIMITS SUMMARY
Continued
LAB ID
144274
144274
144274
144274
144274
144274
144274
144274
144274
144275
144276
144277
144278
144278
144278
144278
144278
144278
144278
144278
144278
144278
144278
144279
144279
144279
144279
144279
144279
144279
144279
144279
144279
144279
144280
144281
144282
144283
ANALYTE
Beryllium
Cadmium
Chromium
Lead
Manganese
Mercury
Nickel
Phosphorus
Selenium
Mercury
Mercury
Mercury
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Lead
Manganese
Mercury
Nickel
Phosphorus
Selenium
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Lead
Manganese
Mercury
Nickel
Phosphorus
Selenium
Mercury
Mercury
Mercury
Antimony
DET LIMIT
0.02
0.02
0.37
0.19
0.37
1.02
0.37
93.29
0.37
0.21
1.03
1.00
0.60
0.30
0.30
1.50
0.60
0.30
0.60
6.00
4.80
150.00
0.60
0.38
0.19
0.02
0.02
0.38
0.19
0.38
1.00
0.38
93.75
0.38
0.21
0.93
1.00
0.60
UNITS
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
INSTRUMENT DL
0.10
0.10
2.00
1.00
2.00
2.00
2.00
500.00
2.00
2.00
2.00
2.00
2.00
1.00
1.00
5.00
2.00
1.00
2.00
20.00
16.00
500.00
2.00
2.00
1.00
0.10
0.10
2.00
1.00
2.00.
2.00
2.00
500.00
2.00
2.00
2.00
2.00
2.00
UNITS
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
f -wrjer -ft Printed on recyclable oa-ser
-------
ETS, Inc. / 192-655 WA-14
Report of September 21, 1993
Page No. 14
DETECTION LIMITS SUMMARY
Continued
LAB ID
144283
144263
144283
144283
144283
144283
144283
144283
144283
144283
144284
144284
144284
144284
144284
144284
144284
144284
144284
144284
144284
144285
144286
144287
ANALYTE
Arsenic
Beryllium
Cadmium
Chromium
Lead
Manganese
Mercury
Nickel
Phosphorus
Selenium
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Lead
Manganese
Mercury
Nickel
Phosphorus
Selenium
Mercury
Mercury
Mercury
DET LIMIT
0.30
0.03
0.03
0.60
0.30
0.60
0.60
0.60
150.00
0.60
0.42
0.21
0.02
0.02
0.42
0.21
0.42
0.60
0.42
105.36
0.42
0.20
0.96
1.00
UNITS
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
\iq, Total
\iq, Total
pg, Total
pg, Total
jjg, Total
pg, Total
pg, Total
pg, Total
pg, Total
yq, Total
pg, Total
yg, Total
pg, Total
fjg, Total
pg, Total
pg, Total
pg, Total
pg, Total
pg, Total
INSTRUMENT DL
1.00
0.10
0.10
2.00
1.00
2.00
2.00
2.00
500.00
2.00
2.00
1.00
0.10
0.10
2.00
1.00
2.00
2.00
2.00
500.00
2.00
2.00
2.00
2.00
UNITS
pg/L
yg/L
yg/L
yg/L
yg/L
pg/L
M9/L
pg/L
^g/L
pg/L
pg/L
pg/L
pg/L
^g/L
/jg/L
pg/L
pg/L
j/g/L
pg/L
pg/L
pg/L
yg/L
pg/L
pg/L
Printed on recycled paper :££ Printed on recyclable paper
-------
APPENDIX D.3.3
EPA METHOD 26 FLUORIDE LABORATORY DATA
-------
E T S , INC.
FIELD SAMPLE LOG
Contract No. 92-655WA
Job I.D.
Test Method 26
Print Date 08/02/93 Time 11:38:40
Page 1
Sample
No.
00300
00301
00302
00303
00304
00305
00306
00307
00308
00309
00310
00311
00312
00313
00314
00315
00316
00317
00318
00319
Container
No.
F2
F3
F5
F6
F2A
F2
F3
F5
F6
F2A
F2
F3
F5
F6
F2A
F2
F3
F5
F6
F2A
Other
I.D.
Run
I.D.
KCE-M26-R1
KCE-M26-R1
KCE-M26-R1
KCE-M26-R1
KCE-M26-R1
KCE-M26-R2
KCE-M26-R2
KCE-M26-R2
KCE-M26-R2
KCE-M26-R2
KCE-M26-R3
KCE-M26-R3
KCE-M26-R3
KCE-M26-R3
KCE-M26-R3
KCE-M26-RO
KCE-M26-RO
KCE-M26-RO
KCE-M26-RO
KCE-M26-RO
Sample
Type
Imps. 1-3 / Rinses
Imp. 4+5 NaOH
Imp. 6 Silica Gel
TEDLAR BAG
EXTRA STORE IMP 1-3
Imps. 1-3 / Rinses
Imp. 4+5 NaOH
Imp. 6 Silica Gel
TEDLAR BAG
EXTRA STORE IMP 1-3
Imps. 1-3 / Rinses
Imp. 4+5 NaOH
Imp. 6 Silica Gel
TEDLAR BAG
EXTRA STORE IMP 1-3
Imps. 1-3 / Rinses
Imp. 4+5 NaOH
Imp. 6 Silica Gel
TEDLAR BAG
EXTRA STORE IMP 1-3
Volume, ml
no Rinses
Volume, ml
w/ Rinses
Analyst
pjb
PJb
PJb
PJb
pjb
pjb
pjb
PJb
PJb
PJb
PJb
PJb
PJb
pjb
PJb
PJb
PJb
PJb
PJb
PJb
Date
08/02/93
OB/02/93
08/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
08/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
Comments
-------
ETS Analytical Services, Inc.
Proudly serving industry and government since 1973.
A subsidiary of ETS International, Inc.
A USEPA Contract Laboratory
RECEIVED AUG 1 8 1993
ETS, Inc.
1401 Municipal Road N.W.
Roanoke, VA 24012
ATTN: Dr. Ted Handel
Re: Laboratory Analysis
ETSAS Client No. 6593
Project #92-655
REPORT DATE/NUMBER: August 13, 1993 / 216
ANALYSIS FOR: Fluoride
METHOD OF ANALYSIS: USEPA Method 26
SAKPLE ANALYSIS DATA
Matrix: AQUEOUS
Lab ID: 144180 Client ID: KC3-M26-R1
Other ID: 92-65SWA Collected by: CLIENT
Collection Date: 08/02/93 Time: Received at ETSAS: 08/04/93
ORGANIC ANALYTES:
Fluoride 74.0 mg/1
k>Analy8is Date: 9-AUG-1993 by: GAM Run ID: 10010070
&>Method: Ion Chromatography? Det Limit= 0.10 mg/1
8=>Coraments: Repl = 73.80 mg/1; Rep2 - 74.20 mg/1; RPD - 0.5
Lab ID: 144181 Client ID: KCE-M26-R2 Matrix: AQUEOUS
Other ID: 92-655WA Collected by: CLIENT
Collection Date: 08/02/93 Time: Received at ETSAS: 08/04/93
Fluoride 106 mg/1
b-Analysis Date: 9-AUG-1993 by: GAM Run ID: 10010070
^>Method: Ion Chromatography; Det Limit= 0.10 mg/1
k>Ccmments: Repl = 106.00 mg/1; Rep2 = 106.00 mg/1; RPD =0.0
Lab ID: 144182 Client ID: KCE-M26-R3 Matrix: AQUEOUS
Other ID: 92-655WA Collected by: CLIENT
Collection Date: 08/02/93 Time: Received at ETSAS: 08/04/93
Fluoride 259 mg/1
G»Analysis Date: 9-AUG-1993 by: GAM Run ID: 10010070
^•Method: Ion Chromatography; Det Limit= 0.10 mg/1
lb
-------
ETS, Inc.
Report of 08/18/93
Page No. 2
SAMPLE ANALYSIS DATA
I
Lab ID: 144183 (continued)
Fluoride < 0.10 mg/1
^Analysis Date: 9-AUG-1993 by: GAM Run ID: 10010070
k>Method: Ion Chromatography; Det Limit= 0.10 mg/1
8>>Comments: Repl = <0.10 mg/1; Rep2 = <0.10 mg/1; RPD =• 0.0
NOTE: Bottle volumes: 144180 KCE-M26-R1 73 mis
144181 KCE-M26-R2 68 mis
144182 KCE-M26-R3 80 mis
144183 KCE-M26-RQ 58 mis
Quality Assurance performed on the above data is presented on the following page(s)
If we may be of further assistance, please contact us at any time.
Sincerely/
ETS .ANALYTICAL dERVlfcES, / INC.
ft'
Chris Southworth, Project Manager
-------
ETS, Inc.
Report of 08/18/93
Page No. 3
QUALITY ASSURANCE SUMMARY
CALIBRATION VERIFICATION
ANALYTE
Fluoride
Fluoride
Fluoride
Fluoride
Fluoride
UNITS
mg/1
mg/1
mg/1
mg/1
mg/1
TRUE
1.90
1.90
2.05
2.05
2.05
FOUND
1.89
1.89
2.07
2.05
2.09
% REC | QAO
99.5
99.5
101.0
100.0
102.0
75-125%
75-125%
75-125%
75-125%
75-125%
RUN ID
10010070
10010070
10010070
10010070
10010070
BLANKS
ANALYTE
Fluoride
Fluoride
Fluoride
Fluoride
Fluoride
Fluoride
Fluoride
Fluoride
UNITS
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
FOUND
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
TYPE
ICB
CCB1
CCB2
CCB3
ICB
CCB1
CCB2
CCB3
QAO
<0.1 ug/1
<0.1 ug/1
<0.1 ug/1
<0.1 ug/1
<0.1 mg/1
<0.1 mg/1
<0.1 mg/1
<0.1 mg/1
RUN ID
10010070
10010070
10010070
10010070
10010070
10010070
10010070
10010070
SPIKES
LAB ID | ANALYTE
144180 | Fluoride
SAMPLE
73.8
SPK
116.0
ADDED | % REC | QAO
49.8 | 84.7 | 75-125%
RUN ID
10010070
QAO: Quality Assurance Objective; REC: Recovery; RPD: Relative Percent Difference
NC: Not Calculatable; DUP: Duplicate Analysis Result; SPK: Spiked Analysis Result.
For Duplicates <5X the Detection Limit (DL), ± DL shall apply for the QAO.
-------
APPENDIX D.3.4
EPA METHOD 0030 VOC LABORATORY DATA
-------
E T S , INC.
FIELD SAMPLE LOG
Contract No. 92-655WA
Job I.D.
Test Method VOST
Print Date 08/02/93 Time 16:22:35
Page 1
Sample
No.
00600
00601
00602
00603
00604
00605
00606
00607
00608
00609
00610
00611
00612
00613
00614
00615
00616
00617
00618
00619
00620
00621
00622
00623
00624
Container
No.
Fl
F3
F2
Fl
F3
F2
Fl
F3
F2
Fl
F3
F2
Fl
F3
F2
Fl
F3
F2
Fl
F3
F2
Fl
F3
F2
Fl
Other
I.D.
Run
I.D.
KCE-VST-R1
KCE-VST-R1
KCE-VST-R1
KCE-VST-R1
KCE-VST-R1
KCE-VST-R1
KCE-VST-R1
KCE-VST-R1
KCE-VST-R1
KCE-VST-R1
KCE-VST-R1
KCE-VST-R1
KCE-VST-R1
KCE-VST-R1
KCE-VST-R1
KCE-VST-R1
KCE-VST-R1
KCE-VST-R1
KCE-VST-R2
KCE-VST-R2
KCE-VST-R2
KCE-VST-R2
KCE-VST-R2
KCE-VST-R2
KCE-VST-R2
Sample
Type
VOST TUBE - CHARCOAL
TEDLAR BAG
VOST TUBE -TENAX
VOST TUBE - CHARCOAL
TEDLAR BAG
VOST TUBE -TENAX
VOST TUBE - CHARCOAL
TEDLAR BAG
VOST TUBE -TENAX
VOST TUBE - CHARCOAL
TEDLAR BAG
VOST TUBE -TENAX
VOST TUBE - CHARCOAL
TEDLAR BAG
VOST TUBE -TENAX
VOST TUBE - CHARCOAL
TEDLAR BAG
VOST TUBE -TENAX
VOST TUBE - CHARCOAL
TEDLAR BAG
VOST TUBE -TENAX
VOST TUBE - CHARCOAL
TEDLAR BAG
VOST TUBE -TENAX
VOST TUBE - CHARCOAL
Volume, ml
no Rinses
Volume, ml
w/ Rinses
Analyst
PJb
PJb
PJb
pjb
PJb
pjb
PJb
PJb
PJb
PJb
PJb
pjb
PJb
pjb
PJb
pjb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
Date
OB/02/93
08/02/93
08/02/93
08/02/93
08/02/93
08/02/93
08/02/93
08/02/93
08/02/93
08/02/93
08/02/93
08/02/93
08/02/93
08/02/93
08/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
Comments
analyze
analyze
-------
E T S , INC.
FIELD SAMPLE LOG
Contract No. 92-655WA
Job I.D.
Test Method VOST
Print Date 08/02/93
Page 2
Sample
No.
00625
00626
00627
00628
00629
00630
00631
00632
00633
00634
00635
00636
00637
00638
00639
00640
00641
00642
00643
00644
00645
00646
00647
00648
00649
Container
No.
F3
F2
Fl
F3
F2
Fl
F3
F2
Fl
F3
F2
Fl
F3
F2
Fl
F3
F2
Fl
F3
F2
Fl
F3
F2
Fl
F3
Other
I.D.
Run
I.D.
KCE-VST-R2
KCE-VST-R2
KCE-VST-R2
KCE-VST-R2
KCE-VST-R2
KCE-VST-R2
KCE-VST-R2
KCE-VST-R2
KCE-VST-R2
KCE-VST-R2
KCE-VST-R2
KCE-VST-R3
KCE-VST-R3
KCE-VST-R3
KCE-VST-R3
KCE-VST-R3
KCE-VST-R3
KCE-VST-R3
KCE-VST-R3
KCE-VST-R3
KCE-VST-R3
KCE-VST-R3
KCE-VST-R3
KCE-VST-R3
KCE-VST-R3
Sample
Type
TEDLAR BAG
VOST TUBE -TENAX
VOST TUBE - CHARCOAL
TEDLAR BAG
VOST TUBE -TENAX
VOST TUBE - CHARCOAL
TEDLAR BAG
VOST TUBE -TENAX
VOST TUBE - CHARCOAL
TEDLAR BAG
VOST TUBE -TENAX
VOST TUBE - CHARCOAL
TEDLAR BAG
VOST TUBE -TENAX
VOST TUBE - CHARCOAL
TEDLAR BAG
VOST TUBE -TENAX
VOST TUBE - CHARCOAL
TEDLAR BAG
VOST TUBE -TENAX
VOST TUBE - CHARCOAL
TEDLAR BAG
VOST TUBE -TENAX
VOST TUBE - CHARCOAL
TEDLAR BAG
Volume, ml
no Rinses
Volume, ml
w/ Rinses
Analyst
PJb
PJb
PJb
PJb
PJb
pjb
PJb
pjb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
pjb
PJb
PJb
PJb
PJb
PJb
PJb
Date
08/02/93
08/02/93
08/02/93
08/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
08/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
08/02/93
08/02/93
08/02/93
08/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
Comments
analyze
analyze
-------
E T S , INC.
FIELD SAMPLE LOG
Contract No. 92-655WA
Job I.D.
Test Method VOST
Print Date 08/02/93
Page 3
Sample
No.
00650
00651
00652
00653
00654
00655
00656
00657
00658
00659
Container
No.
F2
Fl
F3
F2
Fl
F3
F2
Fl
F3
F2
Other
I.D.
Run
I.D.
KCE-VST-R3
KCE-VST-R3
KCE-VST-R3
KCE-VST-R3
KCE-VST-R3
KCE-VST-R3
KCE-VST-R3
KCE-VST-RO
KCE-VST-RO
KCE-VST-RO
Sample
Type
VOST TUBE -TENAX
VOST TUBE - CHARCOAL
TEDLAR BAG
VOST TUBE -TENAX
VOST TUBE - CHARCOAL
TEDLAR BAG
VOST TUBE -TENAX
VOST TUBE - CHARCOAL
TEDLAR BAG
VOST TUBE -TENAX
Volume, ml
no Rinses
Volume, ml
w/ Rinses
Analyst
PJb
PJb
PJb
PJb
pjb
PJb
pjb
PJB
PJB
PJB
Date
08/02/93
08/02/93
OB/02/93
08/02/93
OB/02/93
08/02/93
OB/02/93
08/02/93
OB/02/93
OB/02/93
Comments
analyze
analyze
BLANK/ ANALYZE
BLANK/ ANALYZE
-------
CASE NARRATIVE
Triangle Laboratories of RTF, Inc.
801 Capitola Drive
Durham, NC 27713
Phone: (919) 544-5729
Fax: (919) 544-5491
DATE: August 19,1993
CLIENT P.O. NO:
TU PROJECT NO: 24685A&B
OBJECTIVE: Analysis of seven VOST tube pairs for the Method 8240 Table 2 volatile
compounds.
METHOD:
The samples were analyzed according to the guidelines of Methods 5040 and
8240. The internal standards bromochloromethane, 1,4-difluorobenzene, and chloro-
benzene-d5 and the surrogate standards l,2-dichloroethane-d4, benzene-d6, and to-
Iuene-d8 were added in the amount of 0.25 ug to the tubes immediately prior to analy-
sis by GC/MS.
The GC/MS analysis conditions are listed below:
Purge and trap: Tekmar LSC-2000
Purge: 17 min.
Desorb Temperature: 250 C
Desorb Time: 3 min.
GC CONDITIONS:
Column: 30 m x .53 mm x Q3u J&W DB624
Program: 0 C hold .5 min. to 45 C at
10 C/min, to 90 C 'at 6 C/min, hold
4 min to 200 at 27.5 C/min.
MS CONDITIONS:
Instrument VG TRIO-1
Lab Base data system
Scan: 35-350 amu at .60 s/scan
Source temperature: 180 C
Interface: Jet Separator, 200 C
REPORT:
summary reports the amounts of detected compounds for all samples.
tion limits are reported in parentheses for non-detected compounds.
-------
TRIANGLE LABORATO. IS OF RTF, INC Auo ;t 19,1993
CASE NARRATIVE 24685
The data are reported as quantitation reports, total ion chromatograms, interim
reports, and spectra of detected compounds. The quantitation report header gives the
sample and calibration file names as well as the client sample name, TLI sample
number, TO project number, and the dates of analysis and report. The raw areas and
retention times found on the quantitation report are from the interim report. The
response factors used for the VOST tubes are the average response factors from the
initial calibration. All initial and continuing calibration data are located in the back of
the data package. The ISID is the internal standard identifier. Those compounds
matched to chlorobenzene-d5, for example, are flagged with the ISID number 3. The
amounts for the target compounds and surrogate standards are reported in total micro-
grams (ug). Sample calculations are shown below. If the target compound is detected, a
code of 'D' is reported. If the target compound is detected but at a level below the
quantitation limit or above the calibration range, a code of 'E' or estimated is reported.
If the target compound is not detected, a code of 'ND' or not detected is reported.
Estimated detection limits which are reported for target compounds that are not detect-
ed are calculated using an area of 20 counts. Compounds flagged with the code T are
internal standards.
RESULTS
Four samples were analyzed on August 11,1993 and were calibrated against a
standard five p_oint initial calibration. These samples were 00657/00659 T/TC,
00654/00656 T/TC, 00630/00632 T/TC, and 00603/00605 T/TC. Three of these samples
were found to contain several target analytes exceeding the calibration limit of one
microgram. After discussion with the client, three additional samples were analyzed
against an initial calibration with an extended range for chloromethane, toluene, ben-
zene, acetone, 2-butanone, and m-/P-xylene. The upper limit for this calibration is 10 ug
for acetone and 2-butanone, 5 ug for chloromethane, toluene, benzene, and m-/p-xy-
lene, and 1 ug for all other compounds. The samples analyzed against this extended
ICAL were 00600/00602 T/TC, 00633/00635 T/TC, and 00651/00653 T/TC.
As requested all tube pairs were analyzed in tandem. All samples were analyzed
within the fourteen day sampling to analysis holding period.
The compounds chloromethane, acetone, 2-butanone, benzene, toluene, and m-
/p-xylene were all above the calibration range in samples 00603/00605 T/TC,
00630/00632 T/TC, and 00654/00655 T/TC These compounds are flagged with an T'
on the report and should be considered estimates. Benzene was found to have a satu-
rated spectrum in these three samples, and the quantitations for benzene should there-
fore be considered underestimates.
Although 00600/00602 T/TC was analyzed against the extended calibration,
acetone still exceeded the calibration limit in this sample.
All internal standard areas and surrogate standard percent recoveries were
within criteria for the matrix.
The laboratory blank VOSTBLK081193 T/TC analyzed along with the samples
was found to contain the target analytes methylene chloride and toluene at levels below
the quantitation limit The laboratory blank VOST081393 T/TC was found to contain
methylene chloride, chloroform, toluene, m-/p-xylene, o-xylene, and styrene at levels
below the quantitation limit. Although these compounds are so low as to be considered
estimates, none of these compounds should be considered native to the samples unless
they are detected at levels at least five times that found in the associated blank.
-------
TRIANGLE LABORATORIES OF RTF, INC
CASE NARRATIVE
August 19,1993
24685
The four ketone analytes reported for the VOST samples are acetone, 2-buvaiione,
4-methyl-2-pentanone, and 2-hexanone. While these compounds are Method 8240
Table 2 analytes, they are not addressed by Method 5040, and often experience erratic
recoveries from VOST. All ketone results for VOST matrices should therefore be con-
sidered semi-quantitative.
SAMPLE CALCULATIONS:
Response Factor (RF) =
(area analyte) x faint IS)
(area IS) x (amt analyte)
Amount in ug =
(area analyte in sample) x (amt IS)
(area IS) x (avg ical
Where:
ical = initial calibration
ccal = continuing calibration
IS = internal standard
amt IS = amount of internal standard = 0.25 ug
amt analyte ical = amount of analyte in the ical = .1 to 1.0 ug
For Triangle Laboratories of RTF, Inc.,
Report Preparation:
Quality Control:
Selena Armistead
Report Preparation Chemist
Amy Wa
Report Preparation Chemist
-------
Triangle Laboratories of RTP
Project Summary for Project 24685
Filename : FK744 FK747
Client H: 00657/0065 00603/0060$
Units : ug ug
Chloromethane
Vinyl Chloride
Bromomethane
Chloroelhane
Trichlorofluoromethane
1 , 1 -Dichloroethene
Carbon disulfide
Acetone
Methylene chloride
trans- 1 ,2-Dichloroethene
1,1- Dichloroethane
cis-l,2-Dichloroethene
Chloroform
1 ,2-Dichloroethane
Vinyl acetate
2-Butanone
1,1,1-Trichloroethane
Carbon tetrachloride
Benzene
Trichloroethene
1 ,2-Dichloropropane
Oromodichlorome thane
cis-13-Dichloropropene
trans- 1 ,3-Dichloropropene
1 ,1 ,2-Trichloroethane
Dibromochloromethane
Bromoform
0.019
(0.002)
(0.002)
(0.003)
0.019
(0.001)
(0.001)
(0.011)
0.299
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.035)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.002)
1.046
(0.002)
0.340
0.139
0.148
0.014
(0.001)
4329
0.370
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
3.292
(0.001)
(0.001)
3.676
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.002)
(0.001)
(0.002)
FK746
00630/0063}
"g
1.101
(0.002)
0382
0-128
0.003
0.009
0.044
5.197
0.048
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
4329
(0.001)
(0.001)
3.127
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.002)
PK745
00654 /0065C
°g
2.755
(0.002)
0.490
0.207
0.344
0.169
0.042
12.964
0.199
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
2.681
0.646
(0.001)
2.955
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.002)
PK763
00600/00602
"g
1.083
(0.002)
0.163
0.083
0.058
0.007
(0.001)
11.932
0.070 .
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
2.688
(0.001)
(0.001)
2.693
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.002)
(0.001)
(0.002)
FK764
00633/00633
0.901
(0.002)
0.161
0.089
0.071
0.007
0.028
3.237
0.059
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
1.724
(0.001)
(0.001)
2.675
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.002)
(0.001)
(0.002)
FK765
00651/00653
1.175
(0.003)
0.138
0.105
0308
0.115
0.030
4.361
0.065
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
1.703
0.442
(0.001)
2.696
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.002)
(0.001)
(0.003)
0-EsHmnted Detection Limit Page 1
ProJ_Sum v4.0
-------
Triangle Laboratories of RTF
Project Summary for Project 24685
5/J
Filename :
Client Id:
Units :
FK744
00657/0065
US
FK747
00603/00605
U8
FK746
00630/00633
U8
FK745
00654/00656
"8
FK763
00600/0060*
U8
FK764
00633/0063^
U8
FK765
00651/00653
U8
4-Methyl-2-pentanone
'Toluene
Tetrachloroethene
2-Hexanone
Clilorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylene
Styrene
1 ,1 ,2,2-Tetrachloroethane
(0.004)
0.015
(0.001)
(0.007)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.002)
(0.004)
4.746
(0.001)
(0.008)
0.353
0.376
2.999
0.968
(0.001)
(0.002)
(0.004)
3.415
(0.001)
(0.007)
0.351
0.261
1.920
0.624
(0.001)
(0.002)
(0.004)
3.024
(0.001)
(0.007)
0.207
0.257
1.421
0.524
(0.001)
(0.002)
(0.004)
2.333
.(0.001)
(0.008)
0.190
0.218
1.236
0.457
(0.001)
(0.002)
(0.005)
1.809
(0.001)
(0.009)
0.187
0.147
0.833
0.316
(0.001)
(0.003)'
(0.005)
1.522
(0.001)
(0.009)
0.110
0.137
0.668
0.275
(0.001)
(0.003)
0-EsUmnled Detection Umlt Page 2
Proj_Sum v4.0
-------
Triangle Laboratories of RTF
Project Summary for Project 24685
Filename :
Client Id:
Units :
Chloromethane
Vinyl Chloride
Bromomethane
Chloroelhane
Trichlorofluoromethane
1 ,1 -Dichloroethene
Carbon disulfide
Acetone
Methylene chloride
trans-1,2-Dichloroethene
1 , 1 -Dichloroethane
cis-l,2-Dich!oroethene
Chloroform
1 ,2-Dichloroethane
Vinyl acetate
2-Butanone
1,1,1-Trichloroethane
Carbon tetrachloride
Benzene
Trichloroethene
1 ,2-DichIoropropane
Bromodichloromethane
cis-l,3-Dichloropropene
lrans-l,3-Dichloropropene
1 , 1 ,2-Trichloroethane
Dibromochloromethane
Bromoform
FK743
VOSTBLK081/13
U8
(0.003)
(0.002)
(0.002)
(0.003)
(0.001)
(0.001)
(0.001)
(0.010)
0.011
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.035)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.002)
FK762
VOSTBLK0813^ *
ug <>fiv-'x,-e)y
(0.003)
(0.002)
(0.002)
(0.003)
(0.001)
(0.001)
(0.001)
(0.013)
0.015
(0.001)
(0.001)
(0.001)
0.008
(0.001)
(0.001)
(0.045)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.002)
(0.001)
(0.002)
0-Esllmnted DclecMon LlmlJ Pngc 3
ProJ_Sum v4.0
-------
Triangle Laboratories of RTF
Project Summary for Project 24685
Filename :
Client Id:
Units :
FK743 FK762
VOSTBLK081fl* VOSTBLK08131 ~*>
"g "g
4-Melhyl-2-pentanone
Toluene
Tetrachloroethene
2-Hexanone
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylene
Styrene
1,1,2,2-TetrachIoroethane
<0.004)
0.004
(0.001)
(0.007)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.002)
(0.005)
0.004
(0.001)
(0.009)
(0.001)
(0.001)
0.006
0.004
0.009
(0.003)
0-EsHmated Detection UmJt Page 4
-------
Triangle Laboratories of RTF, Inc.
801 Capitoia Dr.
Durham, NC 27713
(919) 544-5729
Quantitation Results Method 8240
Sample File: FK763
Response File: ICALF6PT
Date Analyzed: 08/13/93
Date Reported: 08/19/93
Project Number: 24685
Sample ID: OC 00602 T/TC KCE-VST-Rl
TLI ID: 68-178-1/2
Analyte
Area
RF
RTISID Amount
Code Quan
Limit
FLAG
BromochJoromcthane
Chloromethane
Vinyl Chloride
Bromomethane
ChJoroc thane
Trichlorofluoromethane
1,1-Dichloroethene
Carbon disulfide
' Acetone
Methyiene chloride
trans- 1 ,2-Dichloroethene
1,1-Dichloroethane .
cis- 1 2- Dichloroethene
Chloroform
1 ,2-Dichlorocthanc
1 ,4-Difluoro benzene
Vinyl acetate
2-Butanone
1 , 1 , 1-Trichloroethane
Carbon tetrachloride
Benzene
Trichloroethcnc
1 ,2-Dichloropropane
* *
Bromodichloromediane
cis-1 3-Didiloropropenc
trans- 1 3-Dichloropropcne
r *
1 , 1 ,2-Trichloroethane
Dibromochloromethane
Brornororm
Chlorobenzcnc-d
5
4-Methyl-2-pcntanone
Toluene
Tetnchloroethene
2-Hexanone
Chlorobcnzene
Ethylbenzene
m-/p-Xylcnc
2070
8212
0
1463
571
2196
116
0
18582
1032
0
0
0
0
0
11256
0
1210
0
0
178701
0
0
0
0
0
0
0
0
13444
0
118542
0
0
10582
6836
53830
0.915
1.025
1.087
0.828
4.564
2.000
7.386
0.188
1.789
2.138
3.654
2.145
4.743
2.457
0.396
0.010
0.889
0.882
1. 474
0.574
0.400
0.687
0.639
0.533
0.262
0.417
0.188
0.084
0.945
0.440
0.047
1.038
0.584
0.810
5.42
1.41
0.00
2.05
2.18
2.53
3.16
0.00
3.35
3.76
0.00
0.00
0.00
0.00
0.00
6.68
0.00
5.25
0.00
0.00
6.13
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
11.11
0.00
8.81
0.00
0.00
11.15
11.43
11.67
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
"3
3
1.083
0.002
0.163
0.083
0.058
0.007
0.001
11.932
0.070
0.001
0.001
0.001
0.001
0.001
0.001
2.688
0.001
0.001
2.693
0.001
0.001
0.001
0.001
0.001
0.002
0.001
0.002
0.004
2333
0.001
0.008
0.190
0.218
1.236
I
E
ND
D
D
D
E
ND
E
D
ND
ND
ND
ND
ND
I
ND
E
ND
ND
E
ND
ND
ND
ND
ND
ND
ND
ND
I
ND
E
ND
ND
D
D
D
0,05
0.05
' 0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05-
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.10
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv43
-------
__. f riangie Laboratories of RTP, Inc.
/' 801 Capitola Dr.
Durham, NC 27713
(919) 544-5729
Quantitation Results Method 8240
Sample File: FK763
Response File: ICALF6PT
Date Analyzed: 08/13/93
Date Reported:08/19/93
Project Number 24685
Sample ID: OC 00602 T/TC KCE-'/ST-Rl
TLI ID: 68-178-1/2
Analyte
o-Xylene
Styrene
1 , 1 ,2,2-Tetrachlorocthane
Area
16718
0
0
RF
0.680
1.063
0.157
RT ISID Amount
"i
12.40
0.00
0.00
3
3
3
0.457
0.001
0.002
Code
D
ND
ND
Quan FLAG
Limit
0.05
0.05
0.05
Surrogate Summary
Area
RF
RTISID Amount Code %REC
1,2-Dichlorocthanc-d
Benzene-d
6
Toluenc-d
5096 2292 6.09 1
20352 1.441 6.08 2
17559 1.206 8.71 3
0.268 D 107
0.314 D 126
0.271 D 108
Reviewed by.
Date
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
OrgrepvO
-------
Triangle Laboratories of RTP, Inc.
801 CapitolaDr.
Durham, NC 27713
(919) 544-5729
Quantitation Results Method 8240
Sample File: FK747
Response File: ICALF731
Date Analyzed: 08/11/93
Date Reported .-08/19/93
Project Number 24685
Sample ID: 00 '00605 T/TC
TU ID: 68-178-^/4
Analyte
Area
RF
RTISID
Amount
"g
Code Quan
Limit
FLAG
Bromochloromcthane
Chloromethane
Vinyl Chloride
Bromomcthane
Chloroe thane
Trichlorofluoromethane
1,1-Dichloroethene
Carbon disulfide
Acetone
Mediyiene chloride
trans-1 ,2-Dichloroethene
1,1-Dichloroethane
cis-1 ,2-Dichloroethene
Chloroform
1,2-Dichloroe thane
1,4-Difluoro benzene
Vmyl acetate
2-Butanone
1,1,1 -Trichlorocdune
Carbon tetrachloride
Benzene
Trichloroethene
1 ,2-Dichloropropane
Bromodichloromethane
cis-13-Dichloropropcnc
trans-13-Dichloropropene
1,1,2-Trichloroethanc
Dibromochloromethanc
Bromoform
Chlorobcnzenc-d
4-Methyl-2-pentanone
Toluene
Tetrachloroethene
2-Hexanone
Chlorobcnzcnc
Ethylbcnzcne
m-/p-Xylenc
2293
7665
0
3392
1055
6198
251
0
7983
6077
0
0
0
0
0
11513
0
1667
0
0
254434
0
0
0
0
0
0
0
0
13582
0
219679
0
0
19883
11921
129055
0.799
1.025
1.086
0.828
4.564
2.000
7.386
0201
1.789
2.138
3.654
2.145
4.743
2.457
0.396
0.011
0.889
0.882
1.503
0.574
0.400
0.687
0.639
0.533
0.262
0.417
0.188
0.084
0.852
0.439
0.047
1.038
0.584
0.792
5.43
1.40
0.00
2.04
2.17
2.53
3.17
0.00
3.48
3.77
0.00
0.00
0.00
0.00
0.00
6.69
0.00
5.32
0.00
0.00
6.14
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
11.12
0.00
8.83
0.00
0.00
11.16
11.44
11.69
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
1.046
0.002
0.340
0.139
0.148
0.014
0.001
4.329
0.370
0.001
0.001
0.001
0.001
0.001
0.001
3.292
0.001
0.001
3.676
0.001
0.001
0.001
0.001
0.001
0.002
0.001
0.002
0.004
4.746
0.001
0.008
0.353
0.376
2.999
I
E
ND
D
D
D
E
ND
E
D
ND
ND
ND
ND
ND
I
ND
E
ND
ND
E
ND
ND
ND
ND
ND
ND
ND
ND
I
ND
E
ND
ND
D
D
E
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.10
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv43
-------
/
ule Laboratories of RT?. inc.
801 CapitolaDr.
Durham, NC 27713
(919) 544-5729
Sample File: FK747
Response File: ICALF731
Dace Analyzed; 08/11/93
Date Reported : 08/19/93
Project Number 24685
Sample ID: 00'' "'00605 T/TC KCE-VST- ill
TLI ID: 68-17o-j/4
Quantitarion Results Method 8240
Analyte
o-Xylene
Scyrene
1 , 1 ,2,2-Tetrachloroethane
Area
35760
0
0
RF
0.680
1.063
0.157
RT ISID Amount
«g
12.41
0.00
0.00
3
3
3
0.968
0.001
0.002
Code
D
ND
ND
Quan FLAG
Limit
O.OS
0.0-5
0.05
Surrogate Summary
Area RF RTISID Amount
(ug)
Code %R£C
1 ,2-Dichloroethane-d
Benzene-d
Toluene-d
7334 2J92 6.11 1
23054 1.441 6.11 2
18255 1.206 8.72 3
0.349 D 140
0.347 D 139
0.279 D 112
Reviewed by.
SrV
Date.
ND -Not Detected; D- Detected; £- Estimated; I- Internal Standard
Orgrepv43
-------
ngle Laboratories of RTP, Inc.
801 Capitola Dr.
Durham, NC 27713
(919) 544-5729
Quan citation Results Method 8240
Sample File: FK746
Response File: ICALF731
Date Analyzed: 08/11/93
Date Reported: 08/19/93
Project Number: 24685
Sample ID: 00' 00632 T/TC KCE V.ST-R.2
TLI ID: 68-178-21/22
Analyte
Bromochloromethane
Chloromethane
Vinyl Chloride
Bromomethane
Chloroe thane
Trichlorofluoromethane
1 , 1 - Dichloroethene
Carbon disuifide
Acetone
Memylene chloride
trans- 1 2- Dichloroethene
1,1-Dichloroe thane
ds-12-Dichloroeihene
Chloroform
1 ,2-Dichloroethane
1 ,4-Difluorobenzenc
Vmyl acgrate
2-Butanone
1,1,1 -TrichJoroethanc
Carbon tetrachloride
Benzene
Trichloroethene
1 ,2-Dichloropropane
r r
Bromodichloromethane
cis-1 3-Dichloropropene
trans-1 3-Dichloropropene
1,12-Trichloroethane .
Dibromochloromethane
Bromoform
Chlorobenzene-d
5
4-Methyl-2-pentanone
Toluene
Tetrachloroethene
2-Hexanone
Chlorobenzene
Ethylbenzene
m-/p-Xylene
Area
2533
8915
0
4204
1071
137
186
3290
10585
865
0
0
0
0
0
13179
0
2510
0
0
247773
0
0
0
0
0
0
0
0
15493
0
180306
0
0
22596
9445
94254
RP
0.799
1.025
1.086
0.828
4.564
2.000
7.386
0201
1.789
2.138
3.654
2.145
4.743
2.457
0.396
0.011
0.889
0.882
1.503
0.574
0.400
0.687
0.639
0.533
0262
0.417
0.188
0.084
0.852
0.439
0.047
1.038
0.584
0.792
RT ISID Amount
"g
5.43
1.40
0.00
2.05
2.18
2.54
3.17
3.30
3.50
3.77
0.00
0.00
0.00
0.00
0.00
6.70
0.00
5-32
0.00
0.00
6.14
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
11.12
0.00
8.83
0.00
0.00
11.17
11.44
11.69
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
1.101
0.002
0.382
0.128
0.003
0.009
0.044
5.197
0.048
0.001
0.001
0.001
0.001
0.001
0.001
4329
0.001
0.001
3.127
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.002
0.004
3-415
0.001
0.007
0.351
0261
1.920
Code
I
E
ND
D
D
E
E
E
E
E
ND
ND
ND
ND
ND
I
ND
E
ND
ND
E
ND
ND
ND
ND
ND
ND
ND
ND
I
ND
E
ND
ND
D
D
D
Quan FLAG
Limit
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05 ^T
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.10
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv43
-------
.'riangie Laboratories of RTF, Inc.
Durham, iMC 27713
(919) 544-5729
Quantitation Results Method 8240
Sample File: FK746
Response File: ICALF731
Date Analyzed: 08/11/93
Date Reported: 08/19/93
Projea Number 2468 5
Sample ID: 00630/00632 T/TC KCE-VST-R2
11110:68-17, 22
Analyte
Area RF RTISID Amount Code Quan FLAG
ug Limit
o-Xylene
Styrene
1 , 1 ,22-Tctrachloroethanc
26288
0
0
0.680
1.063
0.157
12.41
0.00
0.00
3
3
3
0.624
0.001
0.002
D
ND
ND
0.05
0.05
0.05
Surrogate Summary
Area
RF
RTISID Amount Code %REC
1,2-Dichloroethane-d
Benzene-d
Toluene-d
6909 2292 6.12 1
23284 1.441 6.10 2
20417 1.206 8.73 3
0.297 D 119
0.307 D 123
0273 D 109
Reviewed by.
Date
9,11,13
ND-Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv43
-------
1 rianeie Laboratories or RTF, Inc.
801 CapitoUDr.
Durham. NC 27713
(919) 544-5729
Quantitation Results Method 8240
Sample File: FK764
Response File: ICALF6PT
Date Analyzed: 08/13/93
Date Reported: 08/19/93
Project Number 24685
Sample ID: 00^^/00635 7/TC KCE-VST-R2
TUID:68-1/. .3/24
An ah/re
Bromochloromethanc
ChJoromethane
Vmyl Chloride
Bromomcmanc
Qiloroc thane
Trichlorofluoromethane
1,1-Dichloroedaene
Carbon disulfidc
Acetone
Methylcne chloride
trans-1 ,2-Dichloroedicne
1,1-Dichloroethane
as- 1 ,2-Dichloroethene
Chloroform
1 ,2-Dichloroethane
1 ,4-Difluoroben2ene
Vinyl acctarc
2-Butanone
1,1,1-Trichloroethane
Carbon tetrachloride
Benzene
Trichlorocthcnc
1,2-Dichloropropane
Bromodichloromcthanc
cis-1 3-Dichloropropene
trans-13-Dicfaloropropene
1 ,1 ,2-Trichloroethane
Dibromochloromethane
Bromororm
Cnlorobenzenc-d
4-Methyl-2-pentanone
Toluene
Tetrachloroethene
2-Hcxanone
Chlorobenzene
Ethyibenzene
nWp-Xylenc
Area
1957
6451
0
1366
573
2532
114
1609
4763
825
0
0
0
0
0
10748
0
741
0
0
169550
0
0
0
0
0
0
0
0
11953
0
81719
0
0
9299
4111
32264
RF
0.915
1.025
1.087
0.828
4.564
2.000
7.386
0.188
1.789
2.138
3.654
2.145
4.743
2.457
0.396
0.010
0.889
0.882
1.474
0.574
0.400
0.687
0.639
0.533
0.262
0.417
0.188
0.084
0.945
0.440
0.047
1.038
0.584
0.810
RT ISID Amount
"g
5.41
1.40
0.00
2.03
2.17
2.52
3-16
3.29
3.45
3.76.
0.00
0.00
0.00
0.00
0.00
6.68
0.00
5.30
0.00
0.00
6.12
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
11.10
0.00
8.80
0.00
0.00
11.15
11.42
11.66
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
0.901
0.002
0.161
0.089
0.071
0.007
0.028
3.237
0.059
0.001
0.001
0.001
0.001
0.001
0.001
1.724
0.001
0.001
2.675
0.001
0.001
0.001
0.001
0.001
0.002
0.001
0.002
0.005
1.809
0.001
0.009
0.187
0.147
0.833
Code Quan FLAG
Limit
1
D
ND
D
D
D
E
E
E
D
ND
ND
ND
ND
ND
I
ND
E
ND
ND
E
ND
ND
ND
ND
ND
ND
ND
ND
I
ND
E
ND
ND
D
D
D
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.10
ND -Not Detected; D- Detected; E- Estimated; \- Internal Standard
Orgrepv43
-------
iViangie Laboratories of RTF, Inc.
, 801 CapitolaDr.
/ Durham, NC 27713
(919) 544-5729
Quantitation Results Method 8240
Sample File: FK764
lesponse File: ICALF6PT
Date Analyzed: 08/13/93
Date Reported: 08/19/93
Project Number 24685
Sample ID: 00633/00635 T/TC KCE-VST-R2
TLIID:68-m 24
Analyte
Area
RF
RT ISID Amount
Code
"g
o-Xylene
Scyrene
1,1 ,2,2-Tctrachloroethanc
10280
0
0
0.680
1.063
0.157
12.39
0.00
0.00
3
3
3
0.316
0.001
0.003
D
ND
ND
Quan FLAG
Limit
0.05
0.05
0.05
Surrogate Summary
Area RF RTISID Amount
(ug)
Code %R£C
1,2-Dichloroethane-d
Bcnzenc-d
Toluene-d
4957 2.292 6.09 1
19078 1.441 6.08 2
15475 1-206 8.70 3
0.276 D 110
0.308 D 123
0268 D 107
Reviewed by.
6ft-
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv43
-------
Triir.sie Laboratories of RTF, Inc.
801 Capicola Dr.
Durham, NC 27713
(919) 544-5729
Quantitation Results Method 8240
Sample File: FK765
Response File: ICALF6FT
Date Analyzed : 08/13/93
Date Reported: 08/19/93
Projca Number: 24685
Sample ID: 00651/00653 T/TC KCE-VST-R3
TU ID: 68-17' 736
Analyte
Area
RF
RTISID Amount
Code Quan
Limit
FLAG
Bromochloromethane
Chloromethanc
Vinyl Chloride
Bromomethane
Qiloroc thane
Trichlorofluoromethanc
1,1 -Dichloroethene
Carbon disulfide
Acetone
Methylene chloride
trans-1,2- Dichloroethene
1,1-Dichloroe thane
cis-1 ,2- Dichloroethene
Chloroform
1 v2-Dichloroc thane
1,4-Difluoro benzene
Vinyl acetate
2-Butanone
1,1,1-Trichloroethane •
Carbon tetrachloride
Benzene
Trichloroethene
1,2-Dichloropropane
Bromodichloromethanc
cis-13-Didiloropropene
trans-13-Dichloropropene
1,1,2-Trichloroethane
Dibromochloromethane
Bromotorrn
Chlorobenzene-d
4-Mediyl-2-pcntanonc
Toluene
Tetrachloroethcne
2-Hcxanonc
Chlorobenzenc
Ethylbenzene
m-/p-Xylcne
1937
8333
0
1159
675
10883
1778
1731
6352
906
0
0
0
0
0
10234
0
697
16072
0
162671
0
0
0
0
0
0
0
0
12029
0
69201
0
0
5485
3861
26026
0.915
1.025
1.087
0.828
4.564
2.000
7.386
0.188
1.789
2.138
3.654
2.145
4.743
2.457
0.396
0.010
0.889
0.882
1.474
0.574
0.400
0.687
0.639
0.533
0.262
0.417
0.188
0.084
0.945
0.440
0.047
1.038
0.584
0.810
5.41
1.41
0.00
2.04
2.17 1
153
3.16
3.50
3.76
0.00
0.00
0.00
0.00
0.00
6.68
0.00
5.30
5.68
0.00
6.12
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
11.09
0.00
8.80
0.00
0.00
11.14
11.42
11.65
329 1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
1.175
0.003
0.138
0.105
0.308
0.115
0.030
4.361
0.065
0.001
0.001
0.001
0.001
0.001
0.001
1.703
0.442
0.001
2.696
0.001
0.001
0.001
0.001
0.001
0.002
0.001
0.003
0.005
1.522
0.001
0.009
0.110
0.137
0.668
I
E
ND
D
D
D
D
E
E
D
ND
ND
ND
ND
ND
I
ND
E
D
ND
E
ND
ND
ND
ND
ND
ND
ND
ND
I
ND
E
ND
ND
D
D
D
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.0*
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.10
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv43
-------
f riangle Laboratories of RTF, Inc.
801 Capitola Dr.
Durham, NC 27713
(919) 544-5729
Quantitation Results Method 8240
Sample File: FK765
Response File: ICALF6PT
Date Analyzed: 08/13/93
Date Reported: 08/19/93
Project Number 24685
Sample ID: 00'" /00653 T/TC KCE-VST-R3
TLI ID: 68-17o.,j/36
Analytc
Area RF RTISID Amount Code Quan
ug Limit
FLAG
o-Xylene
Styrene
1,1 ,Z2-Tetrachloroe thane
8996 0.680 12.38 3
0 1.063 0.00 3
0 0.157 0.00 3
0.275 D 0.05
0.001 ND 0.05
0.003 ND 0.05
Surrogate Summary
Area RF RTISID Amount
(ug)
Code %REC
1,2-Dichloroethane-d
Benzene-d
6
Toluene-d
5251 2.292 6.09 1
18954 1.441 6.08 2
15388 1.206 8.70 3
0.296 D 118
0.321 D 128
0.265 D 106
Reviewed by.
Date
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv43
-------
Triangle Laboratories of RTF, Inc.
801 CapitoiaDr.
Durham, NC 27713
(919)544-5729
Quantitation Results Method 8240
Sample File: FK745
Response File: ICALF731
Date Analyzed : 08/11/93
Date Reported: 08/19/93
Project Number 24685
Sample ID: 00 '00656 T/TC KCE-VST-R3
TL! ID: 68-178-3//38
Analyte
Area
RF
RTISID Amount
Code Quan
Limit
FLAG
Bromochloromethane
Chloromethane
Vinyl Chloride
Bromomethane
CWoroe thane
Trichlorofluoromethane
1,1-Dichloroethenc
Carbon disulfide
Acetone
Methylene chloride
trans-1,2-Dichloroethene
1,1 -Dichloroethane
cis-1 ,2-Dichloroethcnc
Chloroform
1 ^-Dichloroethane
1,4-Difluoro benzene
Vinyl acetate
2-Butanone
1,1,1-Trichloroethane
Carbon tetnchloride
Benzene
Trichloroethene
1,2-Dichloropropane
Bromodichloromethane
cis-13-Dichloropropcne
trans-13-Dichloropropene
1,1,2-Trichloroctnane
Dibromochloromethane
Bromoform
Chlorobenzene-d
4-Mediyl-2-pentanone
Toluene
Tctrachloroethene
2-Hexanone
Chlorobcnzcnc
Ethyibenzene
m-/p-Xylene
2580
22723
0
5490
1765
16189
3483
3194
26897
3672
0
0
0
0
0
13187
0
1555
30284
0
234248
0
0
0
0
0
0
0
0
15722
0
162034
0
0
13531
9436
70768
0.799
1.025
1.086
0.828
4.564
2.000
7.386
0.201
1.789
2.138
3.654
2.145
4.743
2.457
0.396
0.011
0.889
0.882
1.503
0.574
0.400
0.687
0.639
0.533
0.262
0.417
0.188
0.084
0.852
0.439
0.047
1.038
0.584
0.792
5-43
1.41
0.00
2.04
2.18
2.53
3.17
3.30
3.44
3.77
0.00
0.00
0.00
0.00
0.00
6.70
0.00
5.29
5.70
0.00
6.14
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
11.12
0.00
8.83
0.00
0.00
11.17
11.44
11.69
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
I
2.755 E
0.002 ND
0.490 D
0.207 D
0.344 D
0.169 D
0.042 E
12.964 E
0.199 D
0.001 ND
0.001 ND
0.001 ND
0.001 ND
0.001 ND
I
0.001 ND
2.681 E
0.646 D
0.001 ND
2.955 E
0.001 ND
0.001 ND
0.001 ND
0.001 ND
0.001 ND
0.001 ND
0.001 ND
0.002 ND
I
0.004 ND
3.024 E
0.001 ND
0.007 ND
0.207 D
0.257 D
1.421 D
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.10
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv43
-------
/triangle Laboratories of RTF. Inc.
/ 801 CapitolaDr.
Durham. NC 27713
(919) 544-5729
Quantitation Results Method 8240
Sample File: FK745
Response File: ICALF731
Date Analyzed: 08/11/93
Date Reported: 08/19/93
Project Number: 24685
Sample ID: 006^/00656 T/TC KCE-VST-R3
TLI ID: 68-17. ./38
Analyte
Area RF RTISID Amount
"§
Code Quan
Limit
FLAG
o-Xylenc
Styrene
1,1 ^2-TctrachIoroemanc
22394 0.680 12.41 3
0 1.063 0.00 3
0 0.157 0.00 3
0.524 D 0.05
0.001 ND 0.05
0.002 ND 0.05
Surrogate Summary
Area
RF
RT BID
Amount
(ug)
Code %REC
1,2-Dichloroethane-d
Benzene-d
6
Toluene-d
6021 2.292 6.11 1
23069 1.441 6.09 2
21263 1.206 8.72 3
0.255 D 102
0.304 D 122
0.280 D 112
Reviewed by.
Date
ND-Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv43
-------
/angle Lafaoracories of RTF, Inc.
/Q\ Capicoia Dr.
/Durham. NC 27713
' (919)544-5729
Quantitation Results Method 8240
Sample File: FK743
Response File: ICALF731
Date Analyzed : 08/11/93
Date Reported: 08/18/93
Project Number 24685
Sample ID: VOSTBLK081193 T/TC
TLIID:VOS" K081193T/TC
Analyte
Area RF RTISID Amount
ug
"Code Quan
Limit
FLAG
o-Xylene
Styrene
1,1 ,Z2-Tetrachloroe thane
0 0.680 0.00 3
0 1.063 0.00 3
0 0.157 0.00 3
0.001 ND 0.05
0.001 ND 0.05
0.002 ND 0.05
Surrogate Summary
Area RF RTISID Amount
(ug)
Code %REC
1,2-Dichloroethane-d
Benzene-d
Toluenc-d
4649 2.292 6.09 1
20610 1.441 6.09 2
20295 1.206 8.71 3
0.210 D 84
0.274 D 110
0.292 D 117
Reviewed by.
Date
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv43
-------
-'^Triangle Laboratories of RTF, Inc.
801 Capicola Dr.
Durham, NC 27713
(919) 544-5729
Quantitation Results Method 8240
Sample File: FK743
Response File: ICALF731
Date Analyzed: 08/11/93
Date Reported: 08/18/93
Project Number 24685
Sample ID: VCr~UK081193 T/TC
TLJ ID: VOSTb^OSl 193T/TC
Analyte
Area RF RTISID Amount Code Quan
ug Limit
FLAG
Bromochloromethane
Chloromcthane
Vinyl Chloride
Bromomethane
Chloroe thane
Trichlorofluoromcthane
1,1-DichJoroethene
Carbon disulfide
Acetone
Mediylene chloride
trans-12- Dichloroethene
1,1 - Dichloroe thane
as-1,2-Dichloroethene
Chloroform
1 ,2-Dichloroe thane
1,4-Difludro benzene
Vinyl acetate
2-Butanone
1,1,1-Trichloroethane
Carbon tetrachloride
Benzene
Trichloroedrene
1,2-Dichloropropane
Bromodichloromethane
cis-13- Dichloro propene
trans-13-Dichloropropene
1,1 ,2-Trichloroethane
Dibromochloromethane
Bromoform
Chlorobenzene-d
4-Methyl-2-pentanone
Toluene
Tetrachloroethene
2-Hexanone
Chlorobcnzcnc
Ethylbenzene
ni-/p-Xylene
2410
0
0
0
0
0
0
0
0
182
0
0
0
0
0
13056
0
0
0
0
0
0
0
0
0
0
0
0
0
14395
0
204
0
0
0
0
0
5.42 1
0.799
1.025
1.086
0.828
4.564
2.000
7.386
0.201
1.789
2.138
3.654
2.145
4.743
2,457
0.396
0.011
0.889
0.882
1.503
0.574
0.400
0.687
0.639
0.533
0.262
0.417
0.188
0.084
0.852
0.439
0.047
1.038
0.584
0.792
0.00
0.00
0.00
0.00
0.00
6.69
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
11.11
0.00
8.81
0.00
0.00
0.00
0.00
0.00
0.00 1
0.00 1
0.00 1
0.00 1
0.00 1
0.00 1
0.00 1
0.00 1
3.76 1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
0.003
0.002
0.002
0.003
0.001
0.001
0.001
0.010
0.011
0.001
0.001
0.001
0.001
0.001
0.001
0.035
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.002
0.004
0.004
0.001
0.007
0.001
0.001
0.001
I
ND 0.05
ND 0.05
ND 0.05
ND 0.05
ND 0.05
ND 0.05
ND 0.05
ND 0.05
E 0.05
ND 0.05
ND 0.05
ND 0.05
ND 0.05
ND 0.05
I
ND 0.05
ND 0.05
ND 0.05
ND 0.05
ND 0.05
ND 0.05
ND 0.05
ND 0.05
ND 0.05
ND 0.05
ND 0.05
ND 0.05
ND 0.05
I
ND 0.05
E 0.05
ND 0.05
ND 0.05
ND 0.05
ND 0.05
ND 0.10
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv43
-------
--^Triangle Laboratories of RTP, Inc.
801 CapicolaDr.
Durham, NC 27713
(919) 544-5729
Quantitation Results Method 8240
Sample File: FK762
Response File: ICALF6PT
Date Analyzed: 08/13/93
Date Reported:08/18/93
Project Number 24685
Sample ID: VOSTBLK081393 T/TC
TLIID:VOS K081393T/TC
Analytc
Bromochloromethane
Chloromethanc
Vinyl Chloride
Bromomethane
Chloroe thane
Trichlorofluoromethane
1 , 1 -Dichloroethenc
Carbon disulfide
Acetone
Methyiene chloride
trans-1 ,2-Dichloroethene
1,1-Dichloroe thane
cis- 1 3.- Dichloroethene
Chloroform
1 ,2'Dichloroethane
1 ,4-Difluoro benzene
Vinyl acetate
2-Butanone
1 , 1 , 1-Trichloroethane
Carbon tetrachloride
Benzene
Trichloroethene
1 ,2-Dichioropropane
r r
Bromodichloromethane
cis-1 3-Dichloropropene
trans- 1 3-Dichloropropenc
1 , 1 ,2-TrichlQroethane
Dibromochloromethane
Bromoform
Chlorobenzene-d
5
4-M«hyl-2-pentanone
Toluene
Tetnchloroethene
2-Hexanonc
Chlorobenzene
Ethyibenzenc
nWp-Xylene
Area
2065
0
0
0
0
0
0
0
0
228
0
0
0
331
0
11175
0
0
0
0
0
0
0
0
0
0
0
0
0
11745
0
183
0
0
0
0
211
RF
0.915
1.025
1.087
0.828
4.564
2.000
7.386
0.188
1.789
2.138
3.654
2.145
4.743
2.457
0.396
0.010
0.889
0.882
1.474
0.574
0.400
0.687
0.639
0.533
0.262
0.417
0.188
0.084
0.945
0.440
0.047
1.038
0.584
0.810
RT ISID Amount
"g
5.40
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
3.75
0.00
0.00
0.00
5.55
0.00
6.67
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
11.08
0.00
8.79
0.00
0.00
0.00
0.00
11.64
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
0.003
0.002
0.002
0.003
0.001
0.001
0.001
0.013
0.015
0.001
0.001
0.001
0.008
0.001
0.001
0.045
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.002
0.001
0.002
0.005
0.004
0.001
0.009
0.001
0.001
0.006
Code Quan FLAG
Limit
I
ND
ND
ND
ND
ND
ND
ND
ND
E
ND
ND
ND
E
ND
I
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
I
ND
E
ND
ND
ND
ND
E
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.10
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv43
-------
/fiaimie Laboratories of RT?, Inc.
/801 CapitolaDr.
Durham, NC 27713
(919) 544-5729
Quantitation Results Method 8240
Sample fiie: FK762
Response File: ICALF6PT
Date Analyzed: 08/13/93
Date Reported: 08/18/93
Project Number 24685
Sample ID: VQST3LK081393 T/TC
TLI ID: VOST" '<081393T/TC
Analytc
Area RF RTISID" Amount
"§
Code Quan
Limit
FLAG
o-Xylene
Styrtnc
1,1 ,2,2-Tetrachloroethane
130 0.680 12.37 3
473 1.063 12.41 3
0 0.157 0.00 3
0.004 E 0.05
0.009 E 0.05
0.003 ND 0.05
Surrogate Summary
Area RF RTISID Amount
(ug)
Code %REC
1,2-Dichloroethane-d
Benzene-d
Tolucne-d
4121 2.292 6.07 1
16426 1.441 6.07 2
16561 1.206 8.69 3
0.218 D 87
0.255 D 102
0.292 D 117
Reviewed by.
Date
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv4J
-------
APPENDIX D.3.5
EPA METHOD 0010 SVOC LABOPJVTORY DATA
-------
E T S , IMC.
FIELD SAMPLE LOG
Contract No. 92-655WA
Job I.D.
Test Method SW-846 0010
Print Date 08/02/93 Time 10:26:25
Page 1
Sample
No.
00500
00501
00502
00503
00504
00505
00506
00507
00508
00509
00510
00511
00512
00513
00514
00515
00516
00517
00518
00519
00520
00521
00522
00523
Container
No.
Fl
F2
F3
F4
F5
F6
Fl
F2
F3
F4
F5
F6
Fl
F2
F3
F4
F5
F6
Fl
F2
F3
F4
F5
F6
Other
I.D.
Run
I.D.
KCE-010-Rl
KCE-010-R1
KCE-010-R1
KCE-010-R1
KCE-010-R1
KCE-010-R1
KCE-010-R2
KCE-010-R2
KCE-010-R2
KCE-010-R2
KCE-010-R2
KCE-010-R2
KCE-010-R3
KCE-010-R3
KCE-010-R3
KCE-010-R3
KCE-010-R3
KCE-010-R3
KCE-010-RO
KCE-010-RO
KCE-010-RO
KCE-010-RO
KCE-010-RO
KCE-010-RO
Sample
Type
FILTER
PROBE & FH RINSE
XAD TRAP
IMP 1 CONTENTS+RINSE
IMP 1 & BH RINSES
IMP 5 SILICA GEL
FILTER
PROBE & FH RINSE
XAD TRAP
IMP 1 CONTENTS+RINSE
IMP 1 & BH RINSES
IMP 5 SILICA GEL
FILTER
PROBE & FH RINSE
XAD TRAP
IMP 1 CONTENTS+RINSE
IMP 1 & BH RINSES
IMP 5 SILICA GEL
FILTER
PROBE & FH RINSE
XAD TRAP
IMP 1 CONTENTS+RINSE
IMP 1 & BH RINSES
IMP 5 SILICA GEL
Volume, ml
no Rinses
Volume, ml
w/ Rinses
Analyst
PJb
pjb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
PJb
pjb
PJb
PJb
Date
08/02/93
08/02/93
08/02/93
08/02/93
08/02/93
OB/02/93
08/02/93
08/02/93
08/02/93
08/02/93
08/02/93
08/02/93
08/02/93
08/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
OB/02/93
Comments
-------
ETS, Inc.
GRAVIMETRIC LABORATORY DATA
Silica Gel Weights
Report Prepared on: 08/03/93
Page
Sample
Number
92-655WA-00505
92-655WA-00511
92-655WA-00517
92-655WA-00524
Tare Weight (g)
200.0000
200.0000
200.0000
200.0000
Final Weight (g)
224.7300
220.4400
223.0800
200.0300
Description
light orange/teal
light orange/pink
light pink/purple
blue
-------
CASE NARRATIVE
Triangle Laboratories of RTF, Inc
801 Capitola Dr.
Durham, N.C 27713
PHONE: (919) 544-5729
FAX: (919) 544-5491
DATE: August 16,1993
CLIENT P.O. NO: 4371
TLI NO: 24684
OBJECTIVE: Analysis of four MM5 train samples for the Method 8270 Table 2 list of
semivolatile compounds.
METHOD
The MM5 train sample extractions and GC/MS analyses are based on the guide-
lines of Method 8270. The XAD traps were prespiked with 100 micrograms of ter-
phenyl-d^ prior to sampling. The XAD, filter, and rinse portions of the samples were
spiked with 100 ug of surrogate standards phenol-d-, 2,4,6-tribromophenol, and 1,4-
dibromobenzene-d4 before being Soxhlet extracted for 16 hours with methylene chlo-
ride. The impinger rinses were spiked with 100 ug of surrogate standard anthracene-
d10/ 1,3,5-trichlorobenzene-cL, nitrobenzene-dy and 2-fluorobiphenyl before being
extracted with methylene chloride using a separatory funnel. The extracts were com-
bined and brought to a volume of 1 milliliter.
The internal standards l,4-dichlorobenzene-d4, naphthalene-d8/ phenanthrene-
d1Q/ chrysene-d12, and perylene-d., were added to the extracts such that the final inter-
nal standard concentration was 40ug/mL immediately prior to analysis by GC/MS.
The GC/MS analysis conditions are listed below:
GC CONDITIONS:
Column: J&W DB5-625,30m x .32mm x lu film
Program: ' 35 C, ramp 12C/min to 285C, hold
for 2min, ramp at 8.5C/min to 315C
hold for 13 min.
Carrier Gas: Helium
MS CONDITIONS:
Instrument • HP MSD, Chemsystem and Target data systems
Scan: 35-550 amu at 1.67s/scan
Interface: Capillary, 250C
-------
Triangle Laboratories of RTF August 16,1993
Case Narrative 24684
REPORT
Enclosed with the case narrative are the client request for analysis sheet and
chain of custody, TLJ chain of custody sheets, wet laboratory extraction information
sheets, analyst worksheets, run logs and tracking forms. All initial and continuing
calibration data is located behind the samples in the back of the data package. Please
find at the rear of this case narrative a project summary. The project summary lists the
amounts of the analyte detected in the samples, and the estimated detection limit in
parentheses for the samples in which the analyte was not found.
The data are reported as quantisation reports, chromatogTams, interim reports,
and spectra of detected compounds. The quantitation report headers list the sample and
calibration file names. The client sample name, TLI identification number, dilution
factor, TLI project number, date of report, and analysis date are also listed in the quanti-
tation report header. The raw responses and retention time values found on the quanti-
tation report are from the interim report located behind the quantitation report. The
response factor (RF) is from the continuing calibration. The ISID is the internal standard
identifier. Those compounds matched to phenanthrene-d10 for example, are flagged
with ISID number 4. Compounds flagged with an T are internal standards. If the inter-
nal standard area is above or below quality control criteria a flag of "H" or "L" will
appear in the right hand margin next to the internal standard. The quantitations for the
target compounds and surrogate standards are reported in units of micrograms (ug).
Some example calculations are listed below in the Sample Calculations section of the
narrative. If the target compound is detected, a code of "D" is reported. If the target
compound is detected but the amount is below the quantitation limit or over the cali-
bration range, a code of "E'^or estimated is reported. If the target compound is not
detected, a code of "ND" is reported. The estimated detection limits reported for target
compounds that are not detected are calculated using an area of 100 counts.
Immediately following the sample report are two pages which comprise the total
ion chromatograms. Labeled internal and surrogate standards present in the sample
have their identifications and retention time printed above their peak on the chromato-
grams. On the interim report a ($) is indicative of a surrogate standard and a (*) repre-
sents an internal standard. The interim report from the instrument is followed by the
target spectra of the detected compounds. Four spectral plots are included for each
compound: a raw spectrum of the peak, a background subtracted version of the same
spectrum, a library spectrum of the compound, and a plot showing the percent dif-
ference between trie library spectrum and the background subtracted spectrum. Ex-
tracted ion current profiles are plotted on the right-hand side of the page showing the
quantitation mass and one or two other prominent ions known to be present in the
target compound as they appear in the sample peak.
RESULTS
Please note that the sample names which appear on the quantitation report, the
names used on the ETS field sample log, are not those used for the samples throughout
the extraction process nor analysis of the samples. The difference is due to the necessity
of keeping the parts of the train separate to allow for proper extraction of the samples/
The front and back half rinses for samples KCE-010-R1 and KCE-010-R2 became
aqueous during the extraction procedure and were therefore added and extracted with
the impinger water portion of the sample train.
-------
Triangle Laboratories of R iP August 16,1993
Case Narrative 24684
RESULTS
Per the client's request dilutions were performed on the samples in order for the
target analytes to be within the calibration range of the instrument. For all the samples
please fina both an undiluted analysis and a diluted analysis. All detected target ana-
lytes were within the calibration range in the diluted analyses of the samples, although
a few low level analytes wre lost in the dilution.
All internal standard areas and surrogate standard percent recoveries were
within Method 8270 criteria for the samples and method blank with the following
exceptions: surrogate standard 2,4,6-tribromophenol was extremely low in samples
KCE-010-R1 (undiluted), KCE-010-RO (1:2), KCE-010-R2 (1:2), KCE^010-R3 (1:4), SBLK
080593, and was not detected at all in sample KCE-010-R1 (1:4).
The method blank, SBLK 072393, was found to contain naphthalene at a level
below the quantitation limit and di-n-butylphthalate and bis(2-Ethylhexyl)phthalate
within the calibration range. Naphthalene is a common XAD contaminate and although
estimated should not be considered as native to the samples unless found at a level at
least five times that of the associated blank.
All holding times from sampling to extraction and extraction to analysis were
met.
SAMPLE CALCULATIONS:
Response Factor, RF:
RF= (Area X x Amount Int Stdl
(Area Int Std x Amount X)
Amount in samples:
Amount, ug = (Area X x Amt Int Std x DF) ,
(Area Int Std x RF X)
where:
X = Analyte
Int Std = internal standard
Amt Int Std = 'amount of internal standard = 40 ug
RF X = response factor of X from continuing calibration
DF = dilution factor
For Triangle Laboratories, Inc.,
Report Generation Quality Control
Amy Wall Nancy Bragg
Report Preparation Chemist Air Quality Senior Project Manager
-------
Triangle Laboratories of RTF
Project Summary for Project 24684
Filename : ZD926
Client Id: KCE-010-RO
Units : ug
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1 3-Dichlorobenzene
1,4-Dichlorobenzene
12-Dichiorobenzene
22'-oxybis(l-Chloropropane)
Benzyl alcohol
2-Methylphenol
3 /4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
bis(2-Chloroethoxy)methane
Benzoic acid
2,4-Dichlorophenol
1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methylphenol
2-Methylnaphtnalene
Hexachlorocydopentadiene
2,4,6-Trichlorophenol
2,45-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethylphthalate
2,6-Dinitrotoluene
2,4-Dinitrotoluene
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
6.46
(2.69)
(2.11)
(1-97)
(1.96)
(2.08)
(233)
(4.25)
(2.83)
(2.73)
(426)
(437)
(2.66)
(1.42)
*(3.91)
(2.60)
(2.25)
25.16
(2.91)
(257)
50.42
(2.12)
(4.44)
(2.92)
(1.45)
(5.01)
(4.18)
(3.84) .
(1.47)
(4.91)
(1.14)
(4-70)
(2.78)
(0.85)
(3.63)
(1.49)
(727)
(4.91)
(0.99)
ZD930 ZD929
KCE-010-RO KCE-010-R1
ug ug
(3.96)
(5.28)
(4.14)
(3.88)
(3.85)
(4.08)
(4.58)
(834)
(5.55)
(537)
(837)
(8.58)
(533)
(2-84)
(7.84)
(5.20)
(4.51)
17.90
(5.82)
(5.16)
50.57
' (424) v
(8.90)
(5.84)
(2.90)
(9.63)
(8.04)
(738)
(2.83)
(9.45)
(220)
(9.05)
(535)
(1.63)
(6.99)
(2.87)
(13.97)
(9.45)
(1.90)
(223)
(2.98)
(233)
(2.19)
(2.17)
(230)
(258)
(4-70)
(3.13)
(3.03)
(4.72)
(4.84)
24.11
137.13
(3.92)
(2.60)
(226)
635.11
(2.91)
(258)
76.77
(2.12)
(4.45)
(2.92)
5.14
(4.68)
(3.91)
(359)
(137)
(459)
(1.07)
(439)
(2.60)
(0.79)
(339)
(139)
(6.78)
(459)
(0.92)
ZD935
KCE-010-R1
ti.4)
(557)
(7-44)
(5.83)
(5.46)
(5.42)
(5.75)
(6.45)
(11.75)
(7.82)
(7.56)
(11.79)
(12.09)
(7.07)
70.49
(10.40)
(6.90)
(5.98)
277.50
(7.72)
(6.84)
4535
(5.62)
(11.80) '
(7-75)
227
(1330)
(11.11)
(1020)
(3-91)
(13.05)
(3.04)
(12.49)
(739)
(226)
(9-65)
(3.97)
(1930)
(13.05)
(2.62)
ZD928
KCE-010-R2
66.05
(2.65)
(2.08)
(1.95)
5.19
(2.05)
(2.30)
(4.19)
(2.79)
(2.70)
(4.20)
(431)
(2.46)
(131)
(3.62)
(2.40)
(2.08)
236.27
(2.68)
(238)
26.13
(1.96)
(4.10)
(2.69)
3.99
(458)
(3.83)
(3.51)
(135)
(4.49)
(1.05)
(430)
(255)
(0.78)
(332)
(137)
(6.65)
(4.49)
0.52
0-Estimated Detection Limit Page 1
Proj_Sum v4.0
-------
Triangle Laboratories of RTF
Project Summary for Project 24684
Filename : ZD926
Client Id: KCE-010-RO
Units : ug
Diethylphthalate
4-Chlorophenyl-phenylether
Fluorene
4-Nitroaniline
4,6-Dinitro-2-methylphenol
N-Nitrosodiphenylamine
4-Bromophenyl-phenylether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butylphthalate
Fluoranthene
Pyrene
Butylbenzylphthalate
33'-D»chlorobenzidine
bis(2-Ethylhexyl)phthalate
Benzo(a)anthracene
Ovrysene
Di-n-octylphthaJate
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(123-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
2.40
(2.66)
(1.19)
(2.63)
(5.20)
(1.98)
(4.68)
(3.58)
(4.40)
(0.78)
(0.83)
210.52
(056)
(0.48)
X(0.86)
(158)
103.97
(058)
(0.63)
(0.44)
(0.62)
(0.62)
(0.63)
(056)
(0.72)
(0.66)
ZD930 ZD929
KCE-010-RO KCE-010-R1
0:2.)
ug ug
(1.87)
(5.11)
(228)
(5.05)
(9.95)
(3.79)
(8.96)
(6.86)
(8.43)
(1.49)
(1.59)
222.49
(1.07)
(0.78)
(139)
(255)
100.91
(0.94)
(1.02)
(0.79)
(1-11) ,
(1.11) '
(1.13)
(1.00)
(129)
(1.18)
621
(2.48)
(1.11)
(2.45)
(3.76)
(1.43)
(338)
(259)
(3.18)
(0.56)
(0.60)
93.91
(0.40)
(0.34)
3.99
(1.13)
23.13
(0.41)
(0.45)
42.99
(0.48)
(0.48)
(0.49)
(0.43)
(056)
(051)
ZD935
KCE-010-R1
ug"^
(2.58)
(7.06)
(3.15)
(6.98)
(12.15)
(4.63)
(10.93)
(837)
(10.29) .
(1.82)
(1.95)
54.97
(131)
(0.94)
(1.68)
(3.09)
10.68
(1.13)
(1.23)
15.96
(125)
(1-25)
(127)
(1-13)
(1-45)
(133)
ZD928
KCE-010-R2
ug
3.50
(2.43)
(1.09)
(2.40)
(439)
(1.67)
(3.95)
(3.02)
(3.72)
131
(0.70)
61.30
(0.47)
(037)
1.55
(1.22)
260.19
(0.45)
(0.48)
16.78
(0.48)
(0.48)
(0.49)
(0.43)
(055)
(051)
0-Estimated Detection Limit Page 2
Proj_Sum v4.0
-------
Triangle Laboratories of RTF
Project Summary for Project 24684
Filename :
Client Id:
Units :
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1 3-Dichlorobenzene
1 ,4-Dichlorobenzene
1 2-Dichlorobenzene
22'-oxybis(l-Chloropropane)
Benzyl alcohol
2-Methylphenol
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
bis(2-Chloroethoxy)methane
Benzole acid
2,4-Dichlorophenol
12,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methylphenol
2-Methylnaphthalene
Hexachlorocyclopentadiene
2,4,6-Trichlorophenol '
2,45-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethylphthalate
2,6-Dinitrotoluene
2,4-Dinitrotoluene
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
ZD933
KCE-010-R2
(3.66)
(4.88)
(3.82)
(358)
(356)
(3.77)
(423)
(7.71)
(5.13)
(4.96)
(7.73)
(7.93)
(4.69)
(250)
>,(6.89)
(4.58)
(3.96)
261.41
(5.12)
(453)
12.74
(3.73)
(7.82)
(5.14)
1.56
(8.93)
(7.46)
(6.85)
(2.62)
(8.76)
(2.04)
(839)
(4.96)
(152)
(6.48)
(2.66)
(12.95)
(8.76)
(1.76)
ZD927
KCE-010-R3
US
8337
(2.77)
(2.17)
(2.03)
6.16
(2.14)
(2.40)
(437)
(2.91)
(2.81)
(4.38)
(450)
(2.66)
(1.42)
(3.91)
(2.60)
(2.25)
65734
(2.90)
(2.57)
55.73
(2.12)
(4.44)
(2.91)
3.87
(4-89)
(4.09)
(3.75)
(1.44)
(4.80)
(1.12)
(4.60)
(2.72)
2.79
(355)
(1-46)
(7.10)
(4.80)
(0.96)
ZD934
KCE:010-R3
ug U'4J
(7.23)
(9-64)
(756)
(7.08)
(7.03)
(7.46)
(836)
(1524)
(10.14)
(9.81)
. (1529)
(15.68)
(9.00)
(4.80)
(1323)
(8.78)
(7.60)
52635
(952)
(8.70)
51.49
: (7-15)
(15.01)
(955)
3.22
(1723)
(1439)
(1321)
(5.06)
(16.90)
(3.93)
(16.18)
(957)
(2.92)
(12.49)
(5-14)
(24.99)
(16.90)
(339)
ZD925
SBLK 08059
(2.17)
(2.90)
(227)
(2.13)
(2.11)
(224)
(251)
(458)
(3.05)
(2-95)
(459)
(4.71)
(2.78)
(1.48)
(4.09)
(2.71)
(235)
(3.78)
(3.03)
(2.69)
5.49
(221)
(4.64)
(3.04)
(151)
(5-12)
(428)
(3.93)
(150)
(5.02)
(1-17)
(451)
(2.85)
(057)
(3.71)
(153)
(7.43)
(5-02)
(1.01)
0-Estimated Detection Limit Page 3
Proj_Sum v4.0
-------
Triangle Laboratories of RTF
Project Summary for Project 24684
Filename: ZD933 ZD927 ZD934 ZD925
Client Id: KCE-010-R2 KCE-010-R3 KCE-010-R3 SBLK 08059
tV 2.) (I' 4 \
Units : ug ug ug ' J ug
Diethylphthalate (1.73) 3.42 (3.34) (0.99)
4-Chlorophenyl-phenylether (4.74) (2.60) (9.15) (2.72)
Fluorene (2.12) (1.16) (4.08) (1.21)
4-Nitroaniline (4.68) (257) (9.04) (2.69)
4,6-Dinitro-2-methyiphenol (8.75) (4.86) (16.88) (553)
N-Nitrosodiphenyiamine (333) (1.85) (6.43) (2.11)
4-Bromophenyl-phenylether (7.87) (437) (15.19) (4.97)
Hexachlorobenzene (6.03) (335) (11.63) (3.81)
Pentachlorophenol . (7.41) (4.11) (1430) (4.68)
Phenanthrene (131) (0.73) (253) (0-83)
Anthracene ' (1.40) (0.78) (2.70) (0.89)
Di-n-butylphthalate 32.02 47.71 47.77 6235
Fluoranthene (0.94) (052) (1.82) (059)
Pyrene (0.68) 039 (1.30) (051)
Butylbenzylphthalate V(122) 157 (234) (0.92)
33'-Dichlorobenzidine (224) (129) (429) (1.69)
bis(2-Ethylhexyl)phthalate 139.40 254.71 262.00 25.40
Benzo(a)anthracene (0.82) (0.47) (157) (0.62)
Chrysene (0.89) (051) (1.71) (0.67)
Di-n-octylphthalate (0.68) 10.19 (132) (051)
Benzo(b)fluoranthene (0.96) (050) . (1.86) (0.72)
Benzo(k)fluoranthene (0.96) (050) (1.85) (0.72)
Benzo(a)pyrene (0.98) (051) (1.89) (0.74)
Indeno(123-cd)pyrene (0.86) (0.45) (1.67) (0.65)
Dibenz(a,h)anthracene (1.11) (058) (2.16) (0.84)
Benzo(gAi)perylene (1.02) (053) (1.98) (0.77)
Q-Estimated Detection Limit Page 4 Proj_Sum v4.0
-------
ETS. INC.
Proudly serving indusijy and government since 1973. Providing: Toxic Emission Measurement & Control
A subsidiary of ETS International, Inc.
August 2, 1993
Mr. Bill Hurst
Triangle Laboratories of RTF, Inc.
801 Capitola Drive
Durham, NC 27713
Dear Mr. Hurst,
Accompanying this letter are two coolers and one box of Method 0010
and 0030 sampling train components for analysis, plus six (6) extra
unused XAD traps and seven (7) 0030 VOST tube sets for Triangle to
keep for ETS, Inc. for use at a later date.
Each Method 0010 sampling train consists of one (1) filter, one (1)
sorbent (XAD) trap, one (1) probe wash/rinse (aqueous sample) and
one (1) impinger catch/rinse (aqueous sample). Each 0030 sampling
train consists ofHsix (6) sets of Tenax and Charcoal Tubes; please
note only ONE set per train will be analyzed at this time, as noted
on the field log. t Please store the remainder of 0030 samples we
are returning - we will notify you of any further analysis if
necessary. The 0030 blank train consists of only one set of Tenax
and Charcoal tubes.
A field sample log is included which lists each method sample types
and identification numbers for each; please note highlighted
samples ONLY for analysis at this time. Please analyze Method 0010
according to Method 8270, Table 2, SW-846 Semi-volatiles and
analyze Method 0030 according to Method 8240, Table 2, SW-846
Volatiles.
Attached please find a copy of ETS, Inc. purchase order
information, analysis requirements for each method and a copy of
Triangle Labs price quote for analysis, as per Deborah Hage. A
turnaround time of 21 calendar days is appreciated. Please contact
Project Manager Ken Appel, Field Services Manager Andy Hetz, Terry
Williamson or me if you have any questions.
J. Broadwell
Sample Technician
ETS, Inc.
/PJB
Enclosure(s)
ETS, INC. - !40i Municipal ?,02d. NW - Roanoke, Virginia 24012-1309 - Telephone: 703-265-OOCK - FAX: 703-265-0131
"Poiiitiion Engineering National 5-STAR Environmental Award Winner"
-------
E T S , INC.
FIELD SAMPLE LOG
Contract NO. 92-655WA
Job I.D.
Test Method SW-846 O010
Print Date OB/02/93 Time 10:25i39
Page 1
Sample
No.
.)0500
00501
00502
00503
00504
00506
00507
00508
00509
00510
•OObix —
00512
00513
00514
00515
00516
UU3 J /
00518
00519
00520
00521
00522
AftV»-< —
Container
No.
%
Fl
F2
F3
F4
F5
Fl
F2
F3
F4
F5
Pto
Fl
F2
F3
F4
F5
1 O
Fl
F2
F3
F4
F5
Other
I.D.
Run
I.D.
KCE-010-R1
KCE-010-R1
KCE-010-R1
KCE-010-R1
KCE-010-R1
KCE-01O-R2
KCE-010-R2
KCE-010-R2
KCE-010-R2
KCE-010-R2
KGB— triU— Itr ~
KCE-010-R3
KCE-010-R3
KCE-010-R3
KCE-010-R3
KCE-010-R3
.._« n t f\ ••.->
KCE-I01O"lRj ••
KCE-010-RO
KCE-010-RO
KCE-010-RO
KCE-010-RO
KCE-010-RO
Wf»P_A*A_Rfl —
Sample
Type
FILTER
PROBE & FH RINSE
XAD TRAP
IMP 1 CONTENTS+RINSE
IMP 1 £ BH RINSES
FILTER
PROBE & FH RINSE
XAD TRAP
IMP 1 CONTENTS+RINSE
IMP 1 £ BH RINSES
irir J UiiilCn UcL
FILTER
PROBE G FH RINSE
XAD TRAP
IMP 1 CONTENTS+RINSE
IMP 1 & 3U"RINSES
_ —,-IT
IMP • J olLilCn OElj" ••
FILTER
PROBE & FH RINSE
XAD TRAP
IMP 1 COHTENTS+RINSE
IMP 1 & BH RINSES
^T-MP — «;— • « W.TPft-OPf.
Volume, ml
no Rinses
Volume, ml
w/ Rinses
Analyst
pjb
pjb
PJb
Pjb
Pjb
_ j L
Pl»
pjb
Pjb
Pjb
Pjb
Pjb
f J«J
Pjb
Pjb
Pjb
Pjb
pjb
J L
pjb
Pjb
pjb
Pjb
JElb
Pjb
r%4K
Date
08/02/93
08/02/93
08/02/93
08/02/93
08/02/93
rto /rto /D.3
08/02/93
08/02/93
08/02/93
Oa/02/93
08/02/93
DO/ o^/y j
08/02/93
08/02/93
08/02/93
08/02/93
08/02/93
98/G2-/93-
08/02/93
08/02/93
08/02/93
08/02/93
OB/02/93
nn/n9 /c>3
Comment a
AUG 0 4 1993
TRIANGLE" LABS |MC.
-------
?AGE 1 OF 2
: Custody Seal Present/Intact
! Chain of Custody Present
! Sannle Tags Present
I Sample Tag Numbers Listed
1 SHO Forms Absent
! Ice Chest
! Sample ID
I ' TLI Client
1 68-1I7-1A
i 68-177-18
! 68-177-1C
I 68-177-10
; 58-177-1E
! 5E-177-2A
! 68-177-28
I 68-177-2C
I 66-177-20
! 6E-177-2E
I 68-177-3A
I 66-177-38
i 68-177-3C
1 68-177-30
! 66-177-3E
! 66-177-4A
1 66-177-48
! Receiving
1 92-S55KA-00500--R1
1 92-555KA-00502:R1
1 92-555KA-00501=R1
1 92-655M-00504=Rl
! 92-855KA-00503:R1
I 92-655XA-00506:R2
; 92-555KA-00508=R2
I 92-655KA-00507:R2
1 92-£55XA-00510:R2
! 92-655KA-00509:R2
! 32-t55XAT00512:R3
I S2-655XA-005H:R3
! 92-555XA-bo513=R3
! 92-555KA-00516=R3
! 92-655k'A-00515=R3
I 92-S55KA-00518=RO
1 92-655XA-00520:RO
Remarks:
Ice
t
1
1
1
1
l
l
l
t
1
1
1
1
1
1
t
1
1
t
1
t
1
1
1
1
I
1
1
1
1
1
t
l
Temo 40.0 F
1
Hatrix ,'
FILTER
XAD
FH/RIHSE
BH/RINSE
IHPINGER
FILTER
XAD
FH/RINSE
BH/RINSE
IHPINGER
FILTER
XAD
FH/RIHSE
BH/RINSE
IHPINGER
FILTER
XAD
1
t
1
t
t
t
1
1
1
1
1
l
1
1
1
1
1
1
1
1
1
1
t
1
i
i
i
: TLI Project Number 1 24684
; Client:
ETS02 '
1 Date Received
! Carrier
Storage
Location
COOLERI2
COOLERJ2
COOLERJ2
COOLERS
COOLERI2
COOLERJ2
COOLERS
COOLERS
COOLERS
COOLER} 2
COOLERJ2
COOLERS
COOLERS
COOLERS
COOLERJ2
COOLERS
COOLERI2
! ETS INTERNATIONAL. INC.
I 08/04/93 !
8y^27/^X
and Number ; FEDX.S055023422
1 To Lab
1 Date/Initial
1
1
1
1
l
1
l
1
1
1
1
1
1
1
l
1
— ._ '
1
1
1
l
1
i
1
t
1
1
t
1
1
1
l
1
1
\
1
t
1
I
1
j ^—
1
I
1
1
1
t
I
1
I
1
1
^t
I
1
t
t
1
1
I
1
\
\
1
1
1
1
1
1
I
1
1
1
t
1
1
1 1
1 1
1 1
1 l
1
I
t
1
1
1
1
•*
! Book !
i
•*•* "f^"
66 ':
Y \ Page ',
; 177 ;
To Storage ; To Lab |
Date/Initial \ Date/Initial \
\ \
i i
1 i
1 i
i i
l . i
i i
i |
t i
t i
1 i
I |
1 i
1 I
1 i
i i
1 i
1 i
I i
i i
i i
I t
I i
I i
1 i
i i
i I
i i
i i
I i
1 <
1 I
i i
i
i
i
i
i
i
i
i
i
l
t
i
i
l
i
i
i
i
l
i
t
i
i
i
l
i
i
i
! Archive Rejisrks:
i
i
i
t
i
i
i
i
i
i
!
i
l
i
i
i
i
i
t
t
i
i
i
l
i
i
i
i
i
i
i
t
t
-TRIANGLE LABORATORIES OF RTF, IKC.-CKA1N OF CUSTODY-REVISED 03/12/93—
-------
PAGE 2 OF 2
4 4
Custody Seal Present/Intact
Chain of Custody Present
Sanole Tags Present
SanDle Tag Nunbers Listed
SKO Forns Absent
Ice Chest
Sanple ID
TLI Client
68-177-4C ! 92-655KA-005l"9:RO
68-177-40 I 92-655KA-00522:RO
66-177-4E ! 92-655KA-00521:RO
1
1
1
1
1
t
1
1
1
1
1
1
1
1 '
!
i
i
l
i
i
l
i
t
i
Receiving Re&arks:
Archive Recarks:
Ice Teno 40.0 F
t i
! Matrix |
! FH/RINSE I
! BH/RINSE I
! IHPIHGER . i
i i
i i
i i
i i
X i . i.
I 1
1 1 1
< T '
1 t
1 1
1 1
1 1
1 1
1 t
t 1
1 1
1 1
1 1
1 1
1 1
1 1
1 1
1 1
t . 1
, ' 1
1 1
d. — — J.
1 1
1 f
1 TLI Project Nunber | 24684
1 Client: ETS02
! Date Received
! ETS INTERNATIONAL, INC.
! 08/04/93
!__!_j2dRr
! Carrier and Nunber ! FEDX. 5055023422
Storage |
Location 1
COOLERI2 1
COOLERI2 !
COOLERJ2 1
1
1
1
1
I
1
t
1
i
1
1
t
1
I
t
t
1
1
I
1
1
1
I
I
I
1
1
1
To Lab !
Date/Initial \
\ \
\ \
\ \
\ l
1 l
1 i
t 1
1 1
1 t
1 i
t 1
1 \
\ \
1 l
1 1
1 |
1 l
1 l
t i
+ i
1 t
t |
+ i
1 l
1 i
1 ' 1
1 1
1 1
- 1 1
1 t
1 |
i i
1 1
1 |
i *
1 1
1 l
To Storage
Date/Initial
1
t .
1
t
l
I
I
I
l
t
t
1
1
I
1
i
I
1
i
1
1
I
t
1
1
1
l
1
1-
1
i
I
•J---
\
\
1
1
1
1
I
1
1
I
1
1
1
1
t
1
1
1
1
1
1
t
1
1
1
f
I
1
1
1
1
t
1
1
1
1
1
I Book
! 68
^~^ \ Page
To Lab
Date/Initial
1
I
1
I
I
I
I
1
I
1
l
i
1
1
1
1
I
I
I
i
I
1
I
1
1
I
1
t
l
I
1
I
l
i
t
I
t
i
i
t
4
i
i
i
i
4
i
t
4
i
i
i
4
i
4
i
i
4
i
i
i
i
i
i
4
l
t
4
i
i
i
4
t
i
4
i
i
4
i
i
i
i
4
i
t
T
1
1
1
1
I
1
I
l
1
TRIAKSLE LABORATORIES OF RTF, INC,-CHAIN OF CUSTODY-REVISED 03/12/33
-------
xacprep rev. 2/11/92
7^5 - 9
TRIANGLE LABORATORIES OF RTF, INC.
AIR QUALITY PREPARATION WORK ORDER FORM
PLEASE RETURN THIS FORM WITH THE SAMPLES AFTER THE SAMPLING SESSION
TLI- INFORMATION SECTION
Reference No:.
P.O. Number:
Customer ID:
Order.Taken BY:
Order 'Date: 7^
Due Date: f
/
<&.
Product Manager:
Type & No. of Traps:
XAD
.PUF
QA/QC
FILTER
Petri dishes seperate: yes / no
SAMPLE HISTORY
XAD Resin Batch No. :
from
Preparer
# of Blanks.
PUF > Sandwich with XAD resin: yes / no
> Screen Required: yes / no
> PUF'S Shipped in: Jars / Sleeves
Fortification: XAD: yes / no PUF: yes / no Joint Project: yes / no
T
Spiker/Observer: (D).
Spiking Date: (D)
Spiking Sin ID: (D).
Nominal con. : (D).
10}
(01 3S9-<
(0) _
Nature & Amount of Surrogates
37C14-2,3,7,8 -' TCDD
13012-2,3,4,7,8 - 'PeCDF
13012-1,2,3,4,7,8 - HxCDF
13012-1,2,3,4,7,8 - HxCDD
13012-1,2,3,4,7,8,9 - HpCDF
Terphenyl d
Fluorene d1
/6D
uc,
fig
ug/ml
ng
ng
.ng
-ng
.ng
_ng
_ng
HRPCB: 13C12-3,3;5,5 T-PCB ng
13C12-3;3;4,4;5 PePCB ng
13012-2,2;3,4,4;5 HxPCB ng
13012-2,2;3,3;5,5;6,6 O-PCB ng
Other:
Snecial Instructions:
Ship to the attention of:
Mailing Address: _
(street address) _
SHIPPING INFORMATION
/ ^ *~ ~s>
b by T / r*-> / 7.D
n
'(shipping date)
UFK
~
urr
:
-
Air Bill No.:
HE
hone No:
CLIENT INFORMATION SECTION
circle requested analysis
Selections circled by
Date:
MM5 Front & Back Halves (pooled)ryes / no PUF & Filter Pooled: yes' / no
M23 Toluene Analysis (separate): yes / no
PCDD / PCDF
Mono through Octachlorinated: yes / no
Tri through Octachlorinated: yes / no
Tetra through Octachlorinat=d: yes / no
Confirmation of 2,3,7,8-TCDF: yes / no
Toxicity Equivalency Factor: yes / no
ORGANICS
KSL:
PAH:
PAHH:
PCS:
PCBH:
yes / no
yes / no
yes / no
yes / no
yes / no
-------
ATr: 07/16/93
TRIANGLE LABORATORIES CF RT?, INC
SAMPLE ANALYSIS QUOTATION rORM
VALID THRU: 09/20/93 Phone: (919)544-5729
Tax: (919)544-5491
Ship Samples To:
801 Capitola Driv
Durham, NC 27713
Client Information
Client Code: ETS02
Client: ETS INTERNATIONAL, INC.
Contact: TERRY WILLIAMSON
Phone No: 703-265-0004
Fax No: 703-265-0131
NOTES:
1. Send this cfuote w/sanples.
2. Re-extractions or Dilutions due to matrix
problems will have additional billing,
Client vill be notified.
3. Payment Terms.- NET 30 Days
REFERENCE NO.: 0300000767
PRODUCT MANAGER: Hani Karam 919-544-6351
SALES REP: Deborah Hage 919-544-8355
TO BE CORRECTED
BY CUSTOMER
Billing Address.,
ATTN: ACCOUNTS PAYABLE
1401 MUNICIPAL ROAD ~
ROANOKE
VA 24012-1309
Shipping Address.
(No ?0 Sox)
1401 MUNICIPAL DRIVE
ROANOKE, VA 24012
.Purchase Order No,
Sample/Analysis Information
Start: Date: 08/01/S3
Freauencv:
Legislation
Turn-Around Time:ZTuays
Minimum Amount Needed:
Percent Moisture/Lipids: yes / no
TSCA
FIFRA
RCRA
NPDES
Other
PREPS
Qty Price
Unit Total
Grinding
Compositing
% Lipid
XAD Prep.
PUF Prep.
Filter Prep.
VOST Prep.
Other "
Pooled FH/3H: yes no
Tandem VOST: ves no
# Matrix
22 VOSTPREP
IS VOST
6 XAD PRZP
4 MM5
ANALYSIS • PRICE
Analysis/Method Unit
202101 45.00
CLEAN/PACK (NO SPIKE)
300101 232.50
8240 (TABLE 2)TC<-
E00061 110.00
CLEAN/PACK/SPIXZ (OTHERS)
C01061 __ 371.25
8270 (TABLE 2) I CL
Total
990.OOi
4417.50
660.00
1485.OOj
I
f
GRAND TOTAL
SPECIAL REQUIREMENTS: SPECIAL DEAL- THIS PROJECT ONLY!
7552.50
j Report Generation
Dry Weight: yes / no
Toxic Equivalency Factors: yes / no
No. Cooies:
Tvoe:
Au-thorized Signatures:
TLI Contact:
0 Customer:
Deboran Z. nage
-------
T-^ _r ^.-
t"*' *.
vi/t) I .
^
tu?1
0 -74
SDK
SDLVEKI: (Lj^OlUtlu ]CUlKfR/K[XAH:
CK:CL
SOIVEKI 101 KWIBER(S):
7-
JOINT DRCJ-1CT:
REEXTRACTION:
r.L/.-.SD:
r.s/r.so l
r.S/f.SD VOL:
SURR ID:
SURF, VOL:
FISH
OTHER
INUM
CLIENT ID I WT/VOL
FINAL
VOL SOLV
PK SPIKE
INT WTS
C ri 7 i/ r i o n T
»••• i K L | wH ^
I NT I WT I INT | WT I N'T
0 TLI SLir
SSLK
ICkvuJHtv1
tfi
Q jb "«"'•»-
: J?_. I SA-fe
U 0 S- 1 (. - R. 3
.- fc
_ ,' p
IL/U!
i (
1
•i <:
COMMENTS:
Chain of
• numoer OT samples
2. Relinauished by
number cf sampiss
3. Relinc-'ished by
. • • number of samples
date
pare
Received by
Received by
Received by
daze
cate
rev ? 12/C5/90
-------
OWL Sample Extraction and Cleanup Tracking Fora
rftfS Single Analysis
Project?
Hethod
Sample No.
£->^
Q;^
£-•*<•/
d* /3/ (j
'' 6 -^
— —
6—1
^..2-^:
5/-V-
^~%?to
£>-*^
*
:•.; • v
'
. ' '•.-. 'r -
"•". '
Step Description
Prep Glassvare
I/D front half 'and baci half rinses to i»l.^^
Place filler in thisble and enpty XAP into thinbit.
Add FK and SH rinses tc thiible
Spile appropriate surrogates.
Sriie apprcpriate QC spiiss.
Extract for !6 hours vith CE,C1. on sex.
I/D OOVD iipinger rinses if any. \f^)
Pour iapinger water is separatory funnel, aeasure and record pH and
vojuse. •
Add iipinfer ricses to the water.
Add aturosriate surroEites.
Adjust pE ;o '<2 and extract 3 x 50 si CE,C1,
Adjust pE >!] and extract 3 : 50 zl
Filter both sex and ispinser extracts throueb Kc.SO,.
£/D botL extracts to about 5 sis, corbisias upon i/Din?.
K, extract tc 1 Kl, vialire. and risse vith 2 x 0.5 iL CE,Cl,.
K, to 1 tl. ' • '
Seliaquish to GC/XS.
SOP #
DSP-12E-90
DSP-12f-90
DSP-12J-9C
OVL-!li-90
OVL-i 11-90
OVL-11!-:0
Oft-! 11 -SO
Owl-111-SO
Date
r/^;
/
/
i
- —
*/r/«3
i-
fty
gf*
I f
fy
7?>
\
/
Initials
(M*
/
4-
/
-~
^^
^
/
^yni / s~/e\
^
.
//*
/
B5"
\/
..:-.... /L-P'
. -TO
-------
\\
'L'( I. ah: Ii.vlriiclinn Observation Form Cor A (jncous ' Samples •• ; j..
-' ' •:'~"!l ..... "• ' '
M'jcci H ">Cf
/"
'
Observer 1 N-\clhod
Dale
/ ' .
1 1 .\\tlf.
:6>
3
lY
Volume Used
j^pTnti
JS»~L>
JJo-t*
' AOO^JL,
„
Inilial pll
?
<_,
\
1
g •
'
Volume of N;iOII
*2 W*1^)
// y^
3,
^
Adjnslcd pi 1
^ •'
IJL"
fi
\
v
r
Volume of II2SO.|
I^JL
^
^
-
-JT
Adjnslcd j>ll
< -*v
V
Claiily
,^^;
— -
Color
cs^
•
Odor
Jo
-•
—
J-^
Ub
-------
Organic \Vi:l L;ili: k.\l racMon Ul).serv;il ion l-oini tor I'Ui's, A A I.J I liips', lUivn
II \H
Observer
'-
Y
MP
c
-illci
Method
Pnle
of Sov.
X AH Color
l:jllcr Color
(Jlnsswool Color
Pllp Color
W
Odor
HP
XA
Noli-s:
-------
TLI
DATE
SPIKE
aborat
ories -
lOOug TERPHEttYL-dJL4
'iii,2i£. _____
PREPARES G.L.
Triangle Laboratories, Inc
TLI PROJECTS 24475
DATE 07/22/93
SPIKE lOOuq TERPHEN'YL -
SP i KER__LL^C ____
PREPARER Xf . L .
SWiPLE * 92- 655WA-
00520
ETS02-ETS IhfTER^TIONAL, INC.
92-655WA-00520=R0
— -L~7"~7 —
-------
7~ L.
GC/MS
C
Project #:
PUF Water Soil Other
8270 625 CLP
BE LIST:(Table 2) TCLP 625 CLP CAA/PAP-. PAH C8/CP Other
tame: ICAL
Time TLRTP ID
KM-/
'. / o i
I
I
)
v.
I
Sample ID JFile Name
Comments
DFTPP
SSTD°5°
Solvent Blks
SBLK
-------
TRIANGLE LABORATORIES OF RTP, INC. RUN LOG
MSU
^
COLUMN TYPE
\>6S'VA$~
COLUMNS
-5#0&I6>-A
ANALYST
/
ACQ METHOD
n
-------
--'"Triancle Laboratories or RTF, Inc.
80! Capitola Dr.
Durham, NC 27713
(919) 544-5729
Quantitation Results Method 8270-TB2
Sample File: ZD926
Response File: ZD923
Date .Analyzed: 08/09/93
Date Reported: 08/16/93
Project Number: 24684
Sample !D: KG'-OIO-RO
Sample ID:
TLIID:68-177-4(A-E)
Dilution Factor: LOO
AnaJyte
Area RF RTISID Amount Code Quan
ug Limit
FLAG
1,4-Dichlorobenzene-d
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
13-Dichlorobenzenc
1,4-Dichlorobenzene
1,2-Dichlorobenzene
2,2'-oxybis(l-Chloropropane)
Benzyl alcohol
2-Mediylphenol
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachlo roe thane
Naphthalene-d
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
bi$(2-Chlorocthoxy)mcthane
Benzoic acid
2,4-DichJorophenol
1 ,2,4-Trichlorobenzcne
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methyIphenol
2-Mediyinaphthalene
Acenaphthene-d
Hexachlorocydopentadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chioronaphdialene
2-Nitroanilinc
Dimethyiphthalatc
2,6-Dinitro toluene
2,4-Dinitrotoluene
Accnaphthylene
1583
320
0
0
0
0
0
0
0
0
0
0
0
4666
0
0
0
0
0
695
0
0
5722
0
0
0
0
2584
0
0
0
0
0
0
0
0
0
1.254
0.940
1.199
1.280
1.289
1.215
1.084
0.595
0.894
0.924
0.593
0.578
0.322
0.604
0.219
0.330
0.381
0.237
0.295
0.333
0.973
0.405
0.193
0.294
0.592
0.309
0.370
0.403
1.052
0.315
1.354
0.329
0.556
1.821
9.80
9.10
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
12.32
0.00
0.00
0.00
0.00
0.00
11.74
0.00
0.00
12.37
0.00
0.00
0.00
0.00
15.94
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
I
6.46 E
2.69 ND
111 ND
1.97 ND
1.96 ND
2.08 ND
2.33 ND
4.25 ND
2.83 ND
2.73 ND
4.26 ND
4.37 ND
I
166 ND
1.42 ND
3.91 ND
2.60 ND
125 ND
25.16 D
191 ND
157 ND
50.42 D
2.12 ND
4.44 ND
192 ND
1.45 ND
I
5.01 ND
4.18 ND
3.84 ND
1.47 ND
4.91 ND
1.14 ND
4.70 ND
2.78 ND
0.85 ND
10
10
10
W
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
ND-Not Detected; D- Detected; E- Estimated;!- Internal Standard
Orgrepv43
-------
/riangle Laboratories of RTF. Inc.
'801 Capitoia Dr.
Durham. NC 27713
(919) 544-5729
Quamitation Results Method 8270-TB2
Sample File: ZD926
Response File: ZD923
Date Analyzed : 08/09/93
Date Reported: 08716/93
Project Number 24684
Sample ID: KCF.-OlO-RO
Sample ID:
TLI ID: 68-177-4(A-E)
Dilution Factor: 1.00
Analyte
3-Nitroaniline
Acenaphthcne
2,4-Dinitrophcnol
4-Nitrophenol
Dibenzofuran
Diethylphthalate
4-Chlorophenyl-phcnyIether
Fluorene
4-Nitro aniline
Phenanchrene-d
10
4,6-Dinitro-2-methylphenol
/ i
N-Nitrosodi phenykmine
r /
4-Bromophcnyl-phenylether
r * i *
Hexachloro benzene
Pentachlorophenol .
Phenanthrene
Anthracene
Di-n-butylphthakte
Fluoranthene
Quysene-d
Pyrene
Butylbenzyiphthakte
33'-Dichlorobenzidine
bis(2-Ethylhexyl) phthalate
Benzo(a)anthracene
Chrysenc
Peryiene-d
Di-n-octylphthalate
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l ,2,3-cd)pyrcne
Diberu(a,h)anthracenc
Benzo(E.h,i)Dervlene
Area
0
0
0
0
0
246
0
0
0
5343
0
0
0
0
0
0
0
43726
0
6429
0
0
0
14588
0
0
7232
0
0
0
0
0
0
0
RF
0.426
1.036
0.213
0.315
1.570
1.594
0.582
1.304
0.589
0.144
0.378
0.160
0.209
0.170
0.959
0.899
1.555
1.339
1.296
0.723
0.394
0.873
1.074
0.990
1.262
0.893
0.895
0.877
0.992
0.770
0.838
RT BID
0.00
0.00
0.00
0.00
0.00
16.86
0.00
0.00
0.00
19.04
0.00
0.00
0.00
0.00
0.00
0.00
0.00
20J29
0.00
24.59
0.00
0.00
0.00
24.68
0.00
0.00
28.59
0.00
0.00
0.00
0.00
0.00
0.00
0.00
3
3
3
3
3
3
3
3
3
4
4
4
4
4
4
4
4
4
4
5
5
5
5
5
5
5
6
6
,6
6
6
6
6
6
Amount
"g
3-63
1.49
7.27
4.91
0.99
140
2.66
1.19
163
5.20
1.98
4.68
3.58
4.40
0.78
0.83
210.52
0.56
0.48
0.86
1.58
103.97
0.58
0.63
0.44
0.62
0.62
0.63
0.56
0.72
0.66
Code Quan FLAG
Limit
ND
ND
ND
ND
ND
E
ND
ND
ND
I
ND
ND
ND
ND
ND
ND
ND
E
ND
I
ND
ND
ND
D
ND
ND
I
ND
ND
ND
ND
ND
ND
ND
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv43
-------
/ianglc Laboratories of RTF, Inc.
Capitola Dr.
Durham, NC 27713
(919) 544-5729
Sample File: ZD926
Response File: ZD923
Date Analyzed : 08/09/93
Date Reported: 08/16/93
Project Number: 24684
Sample ID: KCC-010-RO
Sample ID:
TLIID:68-177-4(A-E)
Dilution Factor: 1.00
Surrogate Summary
Area RF RTISID Amount
(ug)
Code %R£C
Phenol-d}
Nitrobenzene-d
5
1 3.5-Trichlorobenzene-d
1 ,4-Dibromobenzcnc-d
2- Fluorobiphenyl
2,4,6-Tribromophenol
Anthracene-d
10
Pyrene-d
7 10
Terphcnyl-d
4353
3430
2908
2674
6365
1113
10806
16088
12915
1.202
0.368
0.354
0.824
1238
0.282
0.864
1.050
0.785
9.08
10.88
11.55
12.43
14.55
17.58
19.15
22.00
22.38
1
2
2
1
3
3
4
5
5
91.53
79.92
70.42
82.02
79.58
61.13
93.64
95.33
102.36
D
D
D
D
D
D
D
D
D
92
80
70
82
80
61
94
95
102
Reviewed by.
Date
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv43
-------
Triangle Laboratories of RTP, Inc.
801 Capitola Dr.
Durham, NC 27713
(919) 544-5729
Quantitation Results Method 8270-TB2
Sample File: ZD930
Response File: ZD923
Date Analyzed: 08/09/93
Date Reported: 08/16/93
Project Number 24684
Sample ID: K 'J10-RO
Sample ID:
TLIID:68-177-4(A-E)
Dilution Factor 100
Analyte
Area RF RTISID Amount
"g
Gxie Quan
Limit
FLAG
1,4-Dichlorobcnzenc-d
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobcnzene
12-Dichlorobenzcnc
22'-oxybis(l-Chloropropane)
Benzyl alcohol
2-Methyiphcnol
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Naphthalene-d
Nitrobenzene
Isophoronc
2-Nitrophenol
2,4-Dimethylphenol
bis(2-Chloroethoxy)methane
Benzoic acid
2,4-Dichlorophenol
1 2,4-Trichlorobcnzcne
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methylphenol
2-Mcthybaphthalene
Acenaphthcne-d
Hexachlorocydopentadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophcnol
2-Chloronaphthalene
2-Nitroaniline
Dtmcthylphthalatc
2,6-Dinitro toluene
2,4-Dinitro toluene
Acenaphthylcnc
1612
0
0
0
0
0
0
0
0
0
0
0
0
4658
0
0
0
0
0
247
0
0
2865
0
0
0
0
2688
0
0
0
0
0
0
0
0
0
1.254
0.940
1.199
1.280
1.289
1215
1.084
0.595
0.894
0.924
0.593
0.578
0.322
0.604
0.219
0.330
0.381
0237
0295
0.333
0.973
0.405
0.193
0294
0.592
0.309
0.370
0.403
1.052
0.315
1.354
0.329
0.556
1.821
9.81
0.00
0.00
0.00
0.00 1
0.00 1
0.00
0.00
0.00
0.00
0.00
0.00
0.00
12.33
0.00
0.00
0.00
0.00
0.00
11.73
0.00
0.00
12.37
0.00
0.00
0.00
0.00
15.95
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
I
3-96 ND
528 ND
4.14 ND
3.88 ND
3.85 ND
4.08 ND
4.58 ND
8.34 ND
5-55 ND
5-37 ND
8.37 ND
8.58 ND
I
5.33 ND
2.84 ND
7.84 ND
520 ND
4.51 ND
17.90 E
5.82 ND
5.16 ND
50.57 D
424 ND
8.90 ND
5.84 NO'
2.90 ND
I
9.63 ND
8.04 ND
7.38 ND
2.83 ND
9.45 ND
220 ND
9.05 ND
5-35 ND
1.63 ND
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
10
20
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv43
-------
Triangle Laboratories of RTP, Inc.
801 Capicola Dr.
Durham, NC 27713
(919) 544-5729
Quantitation Results Method 8270-TB2
Sample File: ZD930
Response File: ZD923
Date Analyzed : 08/09/93
Date Reported: 08/16/93
Project Number: 24684
Sample ID: K" 010-RO
Sample ID:
TLI ID: 68-177-4(A-E)
Dilution Factor: 2.00
Analyte
3-Nitroaniline
Acenaphthenc
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
Diethylphthakte
4-Chlorophenyl-phenyledier
Fluorene
4-Nitro aniline
Phcnanthrene-d
10
4,6-Dinitro-2-methylphenol
* 4 i
N-Nitrosodiphenylamine
r *
4-Bromophenyl-phenylether
Hexachlorobcnzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butylphthalate
Fluorantnenc
Chryscne-d
Pyrcne
Butylbenzylphthalate
/ / r
3,3'* Dichlorobenzidi ne
bi$(2-EthylhexyO phchalarc
Bcn2o(a)anthraoene
Chrysene
Perylene-d
Di-n-octylphthalate
Benzo(b)rluoranthenc
Benzo(k)fluoranthenc
Benzo(a)pyrene
^ * I /
Indcno(l ,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i) perylene
Area
0
0
0
0
0
0
0
0
0
5580
0
0
0
0
0
0
0
24134
0
7950
0
0
0
8754
0
0
8060
0
0
0
0
0
0
0
RF
0.426
1.036
0.213
0.315
1.570
1.594
0.582
1.304
0.589
0.144
0.378
0.160
0209
0.170
0.959
0.899
1.555
1.339
1.296
0.723
0.394
0.873
1.074
0.990
1.262
0.893
0.895
0.877
0.992
0.770
0.838
RT ISID Amount
ug
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
19.04
0.00
0.00
0.00
0.00
0.00
0.00
0.00
20.29
0.00
24.60
0.00
0.00
0.00
24.68
0.00
0.00
28.60
0.00
0.00
0.00
0.00
0.00
0.00
0.00
3
3
3
3
3
3
3
3
3
4
4
4
4
4
4
4
4
4
4
5
5
5
5
5
5
5
6
6
6
6
6
6
6
6
6.99
2.87
13.97
9.45
1.90
1.87
5.11
128
5.05
9.95
3.79
8.96
6.86
8.43
1.49
1.59
222.49
1.07
0.78
1.39
2.55
100.91
0.94
1.02
0.79
1.11
1.11
1.13
1.00
1.29
1.18
Code Quan FLAG
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
I
ND
ND
ND
ND
ND
ND
ND
D
ND
I
ND
ND
ND
D
ND
ND
I
ND
ND
ND
ND
ND
ND
ND
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
• 20
20
20
20
20
20
20
20
20
20
20
20
20
ND -Not Detected; D- Detected; E- Estimated; I- IntemahStandard
OrgrepvO
-------
Triangle Laboratories or RTF, Inc.
801 Capicoia Dr.
Durham, NC 27713
(919) 544-5729
Sample File: ZD930
Response File: ZD923
Date Analyzed : 08/09/93
Date Reported : 08/16/93
Projecr Number: 24684
Sample ID: K 010-RO
Sample ID:
TU ID: 68-!77-4(A-E)
Dilution Factor: 2.00
Surrogate Summary
Area RF RTISID Amount
(ug)
Code %REC
Phcnol-d
s
NJtrobcnzcne-d
5
1 ,3,5-Trichlorobenzene-d
3
1 ,4-Dibromobenzcne-d
4
2-Fluorobiphenyl
2,4,6-Tribromophcnol
Anthraocne-d
10
Pyrenc-d
7 10
Terphenyl-d
719
1648
1367
1287
3212
71
5588
9197
7373
1.202
0.368
0.354
0.824
1.238
0.282
0.864
1.050
0.785
9.09
10.87
11.55
12.43
14.56
17.61
19.16
22.00
22.38
1
2
2
1
3
3
4
5
5
29.69
76.91
66.33
77.48
77.22
7.49
92.72
88.15
94.51
D
D
D
D
D
D
D
D
D
30
77
66
77
77
7
93
88
95
Reviewed by.
Date
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv43
-------
i"riangle Laboratories or" RTP, Inc.
801 CapitolaDr.
Durham, NC 27713
(919) 544-5729
Quantitation Results Method 8270-TB2
Sample File: ZD929
Response File: ZD923
Date Analyzed: 08/09/93
Date Reported: 08/16/93
Project Number 24684
Sample ID: K" 010-Ri
Sample ID:
TLIID:68-177-1(A-E)
Dilution Factor: 1.00
Anaiyte
Area
Rf
RTISID Amount
Gxle Quan
Limit
FLAG
1,4-Dichlorobenzene-d
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichiorobenzene
1,2-Dichlorobenzene
2,2'-oxybis(l -Chloropropane)
Benzyl alcohol
2-Mediylphenol
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Naphthalene-d
Nitrobenzene
Isophoronc
2-Nitrophenol
2,4-Dimcthyiphenol
bis(2-Chloroethoxy)methane
Benzoic acid
2,4-Dichlorophenol.
1,2,4-Trichlorobcnzene
Naphthalene
4-Chloroanilinc
Hexachlorobutadiene
4-Chloro-3-mcthylphcnol
2-Mediylnaphthalene
Accnaphthcnc-d
Hexachlorocydopcntadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nicroanilinc
Dimethylphthalate
2,6-Dtnitro toluene
2,4-Dinitro toluene
Acenaphthylene
1429
0
0
0
0
0
0
0
0
0
0
0
0
4654
903
9638
0
0
0
17516
0
0
8692
0
0
0
354
2768
0
0
0
0
0
0
0
0
0
1.254
0.940
1.199
1.280
1.289
1.215
1.084
0.595
0.894
0.924
0.593
0.578
0.322
0.604
0.219
0.330
0.381
0.237
0295
0.333
0.973
0.405
0.193
0.294
0.592
0.309
0.370
0.403
1.052
0.315
1.354
0.329
0.556
1.821
9.81
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
12.33
10.99
11.43
0.00
0.00
0.00
12.03
0.00
0.00
12.37
0.00
0.00
0.00
13.79
15.94
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
I
2.23 ND
2.98 ND
2.33 ND
2.19 ND
2.17 ND
130 ND
158 ND
4.70 ND
3.13 ND
3.03 ND
4.72 ND
4.84 ND
I
24.11 D
137.13 D
3.92 ND
2.60 ND
126 ND
635.11 E
2.91 ND
158 ND
76.77 D
112 ND
4.45 ND
192 ND
5.14 E
I
4.68 ND
3.91 ND
3.59 ND
1.37 ND
4.59 ND
1.07 ND
4.39 ND
2.60 ND
0.79 ND
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv43
-------
Triangle Laboratories of RTP. Inc.
801 CapicolaDr.
Durham, NC 27713
(919) 544-5729
Quantitation Results Method 8270-TB2
Sample File: ZD929
Response File: ZD923
Date Analyzed: 08/09/93
Date Reported : 08/16/93
Project Number 24684
Sample ID: K 010-Rl
Sample ID:
TLIID:68-177-l(A-£)
Dilution Factor: 1.00
Analyte
Area
RF
RTISID Amount
Code Quan
Limit
FLAG
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
Diethylphthakte
4-Chlorophenyl-phenylether
Fluorene
4-Nitroaniline
Phenanthrene-d
10
4,6-Dinitro-2-methylphenol
N-Nitrosodiphcnylamine
4-Bromophcnyl-phcnylether
Hcxachloro benzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butyiphthakte
Fluoranthene
Qirysene-d
Pyrene
Butylbenzylphthalate
33'-Dichlorobenzidine
bis(2*£thylhexyi)phthakte
BenzD(a)anthracene
Chrysene
Perylene-d
Di-n-octylphthalate
&cnzo(b)fluoranthene
Benzo(k)fluoranthenc
Benzo(a)pyrene
IndenoO 2,3-cd)pyrcne
Dibenz(aji) anthracene
Benzo(g,h,i) perylene
0
0
0
0
0
684
0
0
0
7395
0
0
0
0
0
0
0
26998
0
9019
0
650
0
4553
0
0
9304
12619
0
0
0
0
0
0
0.426
1.036
0.213
0.315
1.570
1.594
0.582
1.304
0.589
0.144
0.378
0.160
0209
0.170
0.959
0.899
1.555
1.339
1296
0.723
0.394
0.873
1.074
0.990
1262
0.893
0.895
0.877
0.992
0.770
0.838
0.00
0.00
0.00
0.00
0.00
16.87
0.00
0.00
0.00
19.04
0.00
0.00
0.00
0.00
0.00
0.00
0.00
20.30
0.00
24.62
0.00
23.41
0.00
24.68
0.00
0.00
28.62
26.84
0.00
0.00
0.00
0.00
0.00
0.00
3
3
3
3
3
3
3
3
3
4
4
4
4
4
4
4
4
4
4
5
5
5
5
5
5
5
6
6
6
6
6
6
6
6
3.39 ND
1.39 ND
6.78 ND
4.59 ND
0.92 ND
6.21 E
148 ND
1.11 ND
2.45 ND
I
3-76 ND
1.43 ND
3.38 ND
159 ND
3.18 ND
0.56 ND
0.60 ND
93.91 D
0.40 ND
I
0.34 ND
3.99 E
1.13 ND
23.13 D
0.41 ND
0.45 ND
I
4199 D
0.48 ND
0.48 ND
0.49 ND
0.43 ND
0.56 ND
0.51 ND
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv43
-------
Triangle Laboratories of RTF, inc.
801 Capitola Dr.
Durham, NC 27713
(919) 544-5729
Sample File: ZD929
Response File: ZD923
Date Analyzed : 08/09/93
Date Reported : 08/16/93
Project Number 24684
Sample ID: K 010-Rl
Sample ID:
TL!ID:68-177-1(A-E)
Dilution Factor 1.00
Surrogate Summary
Area -RF RTISID Amount
(ug)
Code %REC
Phcnol-d
5
Nitrobenzene-d
5
1 3,5-TrichJorobenzene-d
1 ,4-Dibromobenzene-d
2-FluorobjphcnyI
2,4,6-Tribromophenol
Anthncene-d
10
Pyrene-d
Terphenyl-d
3363
3918
3234
3066
8356
26
14787
17350
17010
1.202
0.368
0.354
0.824
1.238
0.282
0.864
1.050
0.785
9.18
10.89
11.56
12.43
14.56
17.66
19.17
22.02
22.39
1
2
2
1
3 '
3
4
5
5
78.30
91.49
78.52
104.11
97.54
1.38
92.57
73-29
96.10
D
D
D
D
D
D
D
D
D
78
91
79
104
98
1
93
73
96
Reviewed by.
DUE P) I til
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
OrgrepvO
-------
Triangle Laboratories of RTP, Inc.
801 Capitola Dr.
Durham, NC 27713
(919) 544-5729
Quantitation Results Method 8270-TB2
Sample File: ZD935
Response File: ZD923
Date Analyzed : 08/09/93
Date Reported: 08/16/93
Project Number: 24684
Sample ID: Y 010-Rl
Sample ID:
TLIID:68-177-1(A-E)
Dilution Factor: 4.00
Analyte
Area
RF
RTISID Amount
Code Quan
Limit
FLAG
1,4-Dichlorobenzene-d
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-DichJorobenzene
1,4-Dichlorobenzene
12-Dichlorobenzcne
22'-oxybis(l -Chloropropanc)
Benzyl alcohol
2-Methylphenol
3/4-Methylphcnol
N-Nitroso-di-n-propylamine
Hexachloroethane
Naphthalene-d
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
bis(2-Chloroethoxy)mediane
Benzoic acid
2,4-Dichlorophcnol
1 2,4-Trichlorobenzene
Naphthalene
4-Chioroaniline
Hcxachlorobutadicne
4-Chloro-3-methylphenol
2-Memyinaphchalene
Acenaphthene-d
Hexachlorocydopentadienc
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroanilinc
Dimethylphthalate
2,6-Dinitro toluene
2,4-Dinitro toluene
Acenaphdiylene
2289
0
0
0
0
0
0
0
0
0
0
0
0
7025
0
1869
0
0
0
2887
0
0
1937
0
0
0
59
3892
0
0
0
0
0
0
0
0
0
1254
0.940
1.199
1.280
1.289
1.215
1.084
0.595
0.894
0.924
0.593
0.578
0322
0.604
0219
0.330
0.381
0.237
0295
0.333
0.973
0.405
0.193
0294
0.592
0.309
0.370
0.403
1.052
0.315
1.354
0.329
0.556
1.821
9.81
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
12.32
0.00
11.39
0.00
0.00
0.00
11.83
0.00
0.00
12.37
0.00
0.00
0.00
13-78
15.95
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
I
5.57 ND
7.44 ND
5-83 ND
5-46 ND
5.42 ND
5.75 ND
6.45 ND
11.75 ND
7.82 ND
7.56 ND
11.79 ND
12.09 ND
I
7.07 ND
70.49 D
10.40 ND
6.90 ND
5-98 ND
277.50 D
7.72 ND
6.84 ND
45.35 D
5.62 ND
11.80 ND
7.75 ND
227 E
I
13.30 ND
11.11 ND
10.20 ND
3.91 ND
13.05 ND
3.04 ND
12.49 ND
7.39 ND
226 ND
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv43
-------
Triangle Laboratories of RTF, Inc.
801 CapicolaDr.
Durham, NC 27713
(919) 544-5729
Quantitation Results Method 8270-TB2
Sample File: ZD935
Response File: ZD923
Date Analyzed: 08/09/93
Date Reported: 08/16/93
Project Number: 24684
Sample ID: KC ^10-Rl
Sample ID:
TU ID: 68-177-1 (A-E)
Dilution Factor: 4.00
Analyte
Area RF RTISID Amount Code Quan
ug Limit
FLAG
3-Nitroaniline
Acenaphchcne
2,4-Dinitrophenol
4-Nitrophenol
Dibcnzoruran
Diethylphthalate
4-Chlorophenyl-phenylether
Fluorcnc
4-Nitroaniline
Phenanthrene-d
10
4,6-Dinitro-2-methyIphenol
N-Nitrosodiphenylamine
4- B romo phenyl-phenylether
Hcxachloro benzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butylphthalate
Fluonnthene
Chrysene-
-------
iriangie Laboratories or RTF, inc.
801 Capicola Dr.
Durham, NC 27713
(919) 544-5729
Sample File: ZD935
Response File: ZD923
Dace Analyzed : 08/09/93
Date Reported: 08/16/93
Project Number: 24684
Sample ID: K' 010-R1
Sample ID:
TLIID:68-177-1(A-E)
Dilution Factor: 4.00
Surrogate Summary
Phenol-d
5
Micro be nzene-d
5
1 3.5-Tricb.lorobenzene-d
3
1 ,4-Dibromobenzene-d
4
2-Fluorobiphcnyl
2,4,6-Tribromophenol
Anthracene-d
10
Pyrene-d
Terphenyl-d
Area
65
853
670
602
1546
0
2716
3235
2981
RF
1.202
0.368
0.354
0.824
1.238
0.282
0.864
1.050
0.785
RT
9.15
10.87
11.56
12.43
14.55
0.00
19.15
22.00
22.38
BID
1
2
2
1
3
3
4
5
5
Amount
(ug)
3.83
52.80
43-14
51.12
51.33
NA
55.01
37.52
46.24
Code
D
D
D
D
D
ND
D
D
D
%R£C
4
53
43
51
51
NA
55
38
46
Reviewed by.
Date & I/JO
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv4J
-------
7 riangie Laboracories of RTF. Inc.
801 Capitola Dr.
Durham. NC 27713
(919) 544-5729
Quantitation Results Method 8270-TB2
Sample File: ZD928
Response File: ZD923
Date Analyzed: 08/09/93
Date Reported: 08/16/93
Project Number 24684
Sample ID: K 010-R2
Sample ID:
TLI ID: 68-177-2(A-£)
Dilution Factor 1.00
Analyte
Area
RF
RTISID Amount
Code Quart
Limit
FLAG
1,4-Dichlorobenzene-d
Phenol
bis(2-Chloro«hyl)ether
2-Chlorophenol
13-Dichlorobenzene
1,4-Dichlorobcnzcnc
1 ,2-Dichioro benzene
2^'-oxybis(l-Chloropropane)
Benzyl alcohol
2-Methylphenol
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Naphthalene-d
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimcthylphenol
bis(2-Chloroethoxy)methane
Benzoic acid
2,4-Dichlorophenol
1 ,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadienc
4-Chloro-3-methylphenol
2-Methylnaphthalene
Accnaphthene-d
Hexachlorocydopentadicne
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chbronaphthalene
2-Nitroaniline
Dimethylphthalate
2,6-Dinitro toluene
2,4-Dinitrotolucne
Acenaphthylene
1605
3323
0
0
0
268
0
0
0
0
0
0
0
5050
0
0
0
0
0
7070
0
0
3210
0
0
0
298
2825
0
0
0
0
0
0
0
0
0
1.254
0.940
1.199
1.280
1.289
1.215
1.084
0.595
0.894
0.924
0.593
0.578
0.322
0.604
0.219
0.330
0.381
0.237
0.295
0.333
0.973
0.405
0.193
0.294
0.592
0.309
0.370
0.403
1.052
0315
1.354
0.329
0.556
1.821
9.81 1
9.12 1
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1233
0.00
0.00
0.00
0.00
0.00
11.88
0.00
0.00
1236
0.00
0.00
0.00
13.78
15.95
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
9.84 1
0.00 1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
0.00. .3
I
66.05 D
2.65 ND
108 ND
1.95 ND
5.19 E
2.05 ND
2.30 ND
4.19 ND
2.79 ND
2.70 ND
4.20 ND
4.31 ND
I
2.46 ND
1.31 ND
3.62 ND
2.40 ND
108 ND
236.27 E
2.68 ND
2.38 ND
26.13 D
1.96 ND
4.10 ND
2.69 ND
3.99 E
I
4.58 ND
3.83 ND
3.51 ND
1.35 ND
4.49 ND
1.05 ND
4.30 ND
2.55 ND
0.78 ND
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
OrgrepvO
-------
i riangle Laboratories of RTF, Inc.
801 CapirolaDr.
Durham, NC 27713
(919) 544-5729
Quantitation Results Method 8270-TB2
Sample File: ZD928
Response File: ZD923
Date Analyzed: 08/09/93
Date Reported: 08/16/93
Project Number 24684
Sample ID: K MO-R2
Sample ID:
TLIID:68-177-2(A-E)
Dilution Factor 1.00
Analyte
3-Nitroaniline
Accnaphthene
2,4-Dinitrophenol .
4-Nitrophenol
r
Dibenzoruran
Diediyiphthalate
4-Chlorophenyl-phenylether
Fluorene
4-Nitroaniline
Phenanthrene-d
10
4,6-Dinitro-2-methylphcnol
N-Nitrosodiphcnylamine
4-Bromophenyl-phenylether
Hexachlorobenzene
Pentachiorophenol
Phenanthrene
Anthracene
Di-n-butyiphthalate
Fluoranthene
Chrysene-d
Pyrene
Bucylbenzyiphthakte
33'-Dichlorobcnzidine
bis(2-EthyIhexyOphthflJate
Bcn2o(a)anthracene
Chryscne
Perylene-d
Di-n-octylphthalate
Bcnzo(b)fluorandiene
Benzo(k)fluoranthcnc
Bcn2o(a)pyrene
Indeno(l >2,3-cd)pyrene
Dibenz(aji)anthracene
Benzo(g,h,i)perylene
Area
0
0
0
0
57
394
0
0
0
6329
0
0
0
0
0
198
0
15083
0
8333
0
233
0
47321
0
0
9376
4963
0
0
0
0
0
0
RF
0.426
1.036
0.213
0.315
1.570
1.594
0.582
1.304
0.589
0.144
0.378
0.160
0.209
0.170
0.959
0.899
1.555
1.339
1.296
0.723
0.394
0.873
1.074
0.990
1.262
0.893
0.895
0.877
0.992
0.770
0.838
RTISID
0.00
0.00
0.00
0.00
16.37
16.87
0.00
0.00
0.00
19.04
0.00
0.00
0.00
0.00
0.00
19.09
0.00
20.29
0.00
24.61
0.00
23.41
0.00
24.69
0.00
0.00
28.59
26.55
0.00
0.00
0.00
0.00
0.00
0.00
3
3
3
3
3
3
3
3
3
4
4
4
4
4
4
4
4
4
4
5
5
5
5
5
5
5
6
6
6
6
6
6
6
6
Amount
"g
3.32
1.37
6.65
4.49
0.52
3.50
2.43
1.09
2.40
4.39
1.67
3.95
3.02
3.72
1.31
0.70
61.30
0.47
0.37
1-55
1.22
260.19
0.45
0.48
16.78
0.48
0.48
0.49
0.43
0.55
0.51
Code Quan FLAG
Limit
ND
ND
ND
ND
£
E
ND
ND
ND
I
ND
ND
ND
ND
ND
E
ND
D
ND
I
ND
E
ND
E
ND
ND
I
D
ND
ND
ND
ND
ND
ND
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrep v4.3
-------
Triangle Laboratories of'RTP. inc.
801 Capitola Dr.
Durham, NC 27713
(919)544-5729
Sample File: ZD928
Response File: ZD923
Date Analyzed : 08/09/93
Date Reported: 08/16/93
Project Number: 24684
Sample ID: K( 10-R2
Sample ID:
TLIID:68-177-2(A-E)
Dilution Factor: 1.00
Surrogate Summary
Phenol-d
5
Nitrobcnzcnc-d
j
1 ,3.5-Trichlorobenzene-d
3
1 ,4-Dibromobenzcne-d
2-Fluorobiphenyi
2,4,6-Tribromophenol
Anthracene-d
to
Pyrene-d
7 10
Terphcnyl-d
Area
4292
3474
2758
2657
7171
2055
12700
15602
14080
RF
1.202
0.368
0.354
0.824
1.238
0.282
0.864
1.050
0.785
RT
9.10
10.88
11.55
12.43
14.55
17.59
19.16
22.01
22.39
ISID
1
2
2
1
3
3
4
5
5
Amount
(ug)
88.99
74.77
61.72
80.38
82.00
103.18
92.90
71.33
86.10
Code
D
D
D
D
D
D
D
D
D
%REC
89
75
62
80
82
103
93
71
86
Reviewed by.
ND -Not Detected; D- Detected; £• Estimated; I- Internal Standard
Orgrep v4.3
-------
Triangle Laboratories of RTP, Inc.
801 CapitolaDr.
Durham, NC 27713
(919) 544-5729
Quantitation Results Method 8270-TB2
Sample File: ZD933
Response File: ZD923
Date Analyzed: 08/09/93
Date Reported : 08/16/93
Project Number: 24684
Sample ID: Kf 10-R2
Sample ID:
TLI ID: 68-177-2(A-E)
Dilution Factor 2.00
Analyte
1 ,4-Dichlorobenzenc-d
4
Phenol
bis(2-ChloroethyI)ether
2-Chlorophenol
*
1 3-Dichlorobenzene
1 ,4-Dichlorobenzene
1 ,2-Dichlorobcnzenc
2,2'-oxybis(l -Chloropropane)
* * 44'
Benzyl alcohol
2-M«hylphenol
/ r
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hccachlorocthane
Naphthalene-d
Nitrobenzene
Isophorone
r
2-Nitrophenol
2,4-Dimethylphenol
bis(2-Chlorocthoxy)methane
Benzoic acid
2,4-Dichlorophenol
' r
1 ,2,4-Tridilorobenzene
Naphthalene
4-Chloroanilinc
Hexachlorobutadicne
4-Chloro-3-methylphenol
2-Methylnaphthalcnc
i r
Accnaphthene-d
Hexachlorocydopentadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalenc
2-Nitroanilinc
Dimethyiphthalate
2,6-Dinitro toluene
2,4-Dinitro toluene
Acenaphdiylene
Area
1744
0
0
0
0
0
0
0
0
0
0
0
0
5298
0
0
0
0
0
4103
0
0
821
0
0
0
61
2899
0
0
0
0
0
0
0
0
0
RF
1.254
0.940
1.199
1280
1.289
1.215
1.084
0.595
0.894
0.924
0.593
0.578
0.322
0.604
0.219
0.330
0.381
0.237
0295
0.333
0.973
0.405
0.193
0.294
0.592
0.309
0.370
0.403
1.052
0.315
1.354
0.329
0.556
1.821
RT BID
9-81
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
12.33
0.00
0.00
0.00
0.00
0.00
11.85
0.00
0.00
12.37
0.00
0.00
0.00
13.79
15.95
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1
1
1
1
1
1
1
1
1
1
1
1 .
1
2
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
Amount
"g
3.66
4.88
3.82
3.58
3.56
3-77
4.23
7.71
5.13
4.96
7.73
7.93
4.69
150
6.89
4.58
3.96
261.41
5.12
4.53
12.74
3.73
7.82
5.14
1.56
8.93
7.46
6.85
162
8.76
104
8.39
4.96
1-52
Code Quan FLAG
Limit
I
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
I
ND
ND
ND
ND
ND
D
ND
ND
E
ND
ND
ND
E
I
ND
ND
ND
ND
ND
ND
ND
ND
ND
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrep vO
-------
Triangle Laboratories of Rl P, Inc.
801 Capitoia Dr.
Durham, NC 27713
(919) 544-5729
Quantitation Results Method 8270-TB2
Sample File: ZD933
Response File: ZD923
Dace Analyzed : 08/09/93
Dace Reported:08/16/93
Project Number 24684
Sample ID: K MO-R2
Sample ID:
TLIID:68-177-2(A-E)
Dilution Factor: 2.00
Analyte
3-Nitroaniline
Acenaphthene
r
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
Diethyiphthalace
4-Chlorophenyl-phenylether
r ' r /
Fluorcnc
4-Nitroaniline
Phenanthrene-d
10
4,6-Dinitro-2-methylphenol
* r
N-Nitrosodiphenylamine
4-Bromophcnyl-phenylether
HexachJoro benzene
Pentachlorophenol
Phenanthienc
Anthracene
Di-n-butyiphtnalate
Fluoranthcne
Chrysene-d
Pyrene
Butylbenzyiphthalate
' ' r
3,3'-DichJorobenzidine
bis(2-Ethylhexyl)phthalate
Benzo(a)anthracene
Chrysene
Peiylcnc-d
Di-n-octyiphthalate
/ r
Benzo(b)fluoranthcnc
Bcnzo(k)fluoranthcne
Benzo(a)pyrcne
x * 1 *
Indeno(l v2,3-cd)pyrenc
Dibenz(a,h)anthracene
Benzo(g,h,i) perylcne
Area
0
0
0
0
0
0
0
0
0
6351
0
0
0
0
0
0
0
3953
0
9055
0
0
0
13774
0
0
9349
0
0
0
0
0
0
0
RF
0.426
1.036
0.213
0.315
1.570
1.594
0.582
1.304
0.589
0.144
0.378
0.160
0.209
0.170
0.959
0.899
1.555
1339
1.296
0.723
0.394
0.873
1.074
0.990
1.262
0.893
0.895
0.877
0.992
0.770
0.838
RT ISID
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
19.05
0.00
0.00
0.00
0.00
0.00
0.00
0.00
20.29
0.00
24.61
0.00
0.00
0.00
24.69
0.00
0.00
28.60
0.00
0.00
0.00
0.00
0.00
0.00
0.00
3
3
3
3
3
3
3
3
3
4
4
4
4
4
4
4
4
4
4
5
5
5
5
5
5
5
6
6
6
6
6
6
6
6
Amount
"g
6.48
166
12.95
8.76
1.76
1.73
4.74
112
4.68
8.75
3.33
7.87
6.03
7.41
1.31
1.40
3102
0.94
0.68
1.22
124
139.40
0.82
0.89
0.68
0.96
0.96
0.98
0.86
1.11
1.02
Code Quan FLAG
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
I
ND
ND
ND
N.D
ND
ND
ND
D
ND
I
ND
ND
ND
D
ND
ND
I
ND
ND
ND
ND
ND
ND
ND
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv4J
-------
Triangle Laboratories of RTP, Inc.
801 Capitola Dr.
Durham, NC 27713
(919)544-5729
Sample File: ZD933
Response File: ZD923
Date Analyzed: 08/09/93
Date Reported : 08/16/93
Project Number: 24684
Sample ID: KC 10-R2
Sample ID:
TLIID:68-!77-2(A-E)
Dilution Factor 2.00
Surrogate Summary
Phenol-d
5
Nitrobenzene-d
5
1 3,5-Trichlorobenzene-d
1 ,4-Dibromobenzene-d
4
2-Fluorobiphenyl
2,4,6-Tribromophenol
Anthracene-d
10
Pyrene-d
' to
Tcrphenyl-d
Area
139
808
678
659
1726
19
3044
3920
3676
RF
1.202
0.368
0.354
0.824
1.238
0.282
0.864
1.050
0.785
RT ISID Amount
(ug)
9.16
10.88
11.56
12.43
14.55
17.62
19.16
22.01
22.38
1
2
2
1
3
3
4
5
5
5.33
33.17
28.93
36.71
38.47
1.86
44.38
32.98
41.38
Code
D
D
D
D
D
D
D
D
D
%R£C
5
33
29
37
38
2
44
33
41
Reviewed by.
Date & I/IP I
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrep v43
-------
Triangle Laboratories of RTP, Inc.
801 CapicolaDr.
Durham. NC 27713
(919) 544-5729
Quantitation Results Method 8270-TB2
Sample File: ZD927
Response File: ZD923
Date Analyzed : 08/09/93
Date Reported: 08/16/93
Project Number: 24684
Sample ID: f 010-R3
Sample ID:
TLIID:68-177-3(A-E)
Dilution Factor 1.00
Analyte
Area RF RTISID Amount Code Quan FLAG
ug Limit
1 ,4-DidiIorobenzcne-d
4
Phenol
bts(2-ChloroethyI)ether
2-Qilorophenol
i
1 3-Dichlorobcnzene
1 ,4-DichIorobenzene
1 ,2-Dichlorobenzene
2,2'-oxybis(l-Chloropropane)
/ ^ r r 7
Benzyl alcohol
2-Methylphenol
/ r
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Naphchalene-d
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
' r
bis(2-Chloroethojcy)methanc
Benzoic acid
2,4-Dichlorophenol
r
1 ,2,4-Trichlorobenzene
Naphthalene
4-Chloroanilinc
Hcxachlorobutadiene
4-Chloro-3-methylphcnol
2-Methylnaphthalene
Accnaphthene-d
Hcxachlorocydopcntadiene
' r
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalcnc
2-Nitroanilinc
Dimethyiphthakte
2,6-Dinitro toluene
2,4-Dinitro toluene
Acenaphthylenc
1538
4021
0
0
0
305
0
0
0
0
0
0
0
4667
0
0
0
0
0
18180
0
0
6327
0
0
0
267
2644
0
0
0
0
0
0
0
0
335
1.254
0.940
1.199
1.280
1.289
1.215
1.084
0.595
0.894
0.924
0.593
0.578
0.322
0.604
0.219
0.330
0.381
0.237
0.295
0.333
0.973
0.405
0.193
0294
0.592
0.309
0.370
0.403
1.052
0.315
1.354
0.329
0.556
1.821
9.80
9.12
0.00
0.00
0.00
9.84
0.00
0.00
0.00
0.00
0.00
0.00
0.00
12.33
0.00
0.00
0.00
0.00
0.00
12.01
0.00
0.00
12.37
0.00
0.00
0.00
13.78
15.94
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
15-95
1
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
83.37
2.77
2.17
2.03
6.16
114
2.40
4.37
2.91
2.81
4.38
4.50
2,66
1.42
3.91
2.60
2.25
657.34
190
2.57
55.73
2.12
4.44
2.91
3.87
4.89
4.09
3.75
1.44
4.80
1.12
4.60
172
179
I
D
ND
ND
ND
E
ND
ND
ND
ND
ND
ND
ND
I
ND
ND
ND
ND
ND
E
ND
ND
D
ND
ND.
ND
E
I
ND
ND
ND
ND
ND
ND
ND
ND
E
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
ND -Not Detected; D- Detected; E- Estimated; 1- Internal Standard
Orgrep v43
-------
Triangle Laboratories of RTF, Inc.
801 CapitoiaDr.
Durham, NC 27713
(919) 544-5729
Quantitation Results Method 8270-TB2
Sample Fiie: ZD927
Response File: ZD923
Date Analyzed : 08/09/93
Date Reported: 08/16/93
Project Number: 24684
Sample ID: K HO-R3
Sample ID:
TLJID:68-177-3(A-E)
Dilution Factor: 1.00
Analytc
Area
RF
RTISID Amount
Code Quan
Limit
FLAG
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzoruran
Diethylphthalatc
4-Chlorophenyl-phenylcther
Fluorene
4-Nitroaniline
Phenanthrene-d
10
4,6-Dinitro-2-methylphenol
N-Nitrosodiphenylamine
4-Bromophenyl-phenylethcr
Hexachlorobenzene
Pentachlorophcnol
Phenanthrene
Anthracene
Di-n-butylphthalate
Fluoranthcnc
Chiysene-d
Pyrcnc
Butylbenzylphthalate
33'-Dichlorobcnzidinc
bis(2-Ethylh«yOphthalatc
Benzo(a)anthracene
Oirysene
Perylcnc-d
Di-n-octylphthalate
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l ,2,3-cd)pyrene
Dibcnz(a,h)andiraccne
Benzo(g,h,i)perylene
0
0
0
0
0
360
0
0
0
5718
0
0
0
0
0
0
0
10606
0
7851
99
222
0
43645
0
0
8959
2880
0
0
0
0
0
0
0.426
1.036
0-213
0.315
1.570
1.594
0.582
1.304
0.589
0.144
0.378
0.160
0.209
0.170
0.959
0.899
1.555
1.339
1296
0.723
0.394
0.873
1.074
0.990
0.893
0.895 ,
0.877
0.992
0.770
0.838
0.00
0.00
0.00
0.00
0.00
16.86
0.00
0.00
0.00
19.04
0.00
0.00
0.00
0.00
0.00
0.00
0.00
20.29
0.00
22.04
23.41
24.70
0.00
0.00
28.60
26.55
0.00
0.00
0.00
0.00
0.00
0.00
3
3
3
3
3
3
3
3
3
4
4
4
4
4
4
4
4
4
4
24.60 5
0.00 5
5
5
5
6
6
6
6
6
6
6
6
3.55 ND
1.46 ND
7.10 ND
4.80 ND
0.96 ND
3.42 E
160 ND
1.16 ND
157 ND
I
4.86 ND
1.85 ND
4.37 ND
3.35 ND
4.11 ND
0.73 ND
0.78 ND
47.71 D
0.52 ND
I
0.39 E
1.57 E
1.29 ND
254.71 E
0.47 ND
0.51 ND
I
10.19 D
0.50 ND
0.50 ND
0.51 ND
0.45 ND
0.58 ND
0.53 ND
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
19-
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv43
-------
Triangle Laboratories of RTP, Inc.
801 CapitolaDr.
Durham, NC 27713
(919) 544-5729
Sample File: ZD927
Response File: ZD923
Date Analyzed : 08/09/93
Date Reported: 08/16/93
Project Number 24684
Sample ID: K MO-R3
Sample ID:
TLI ID: 68-177-3(A-E)
Dilution Factor: 1.00
Surrogate Summary
Phenol-d
j
Nitrobenzene-d"
5
1 ,3.5-Trichlorobenzene-d
3
1 ,4-Dibromobenzcne-d
2-Fluorobiphenyl
2,4,6-Tribromophenol
Anthracene-d
10
Pyrene-d
Terphenyl-d
Area
4619
3706
3176
2851
7511
2007
12987
16575
14152
RF
1.202
0.368
0.354
0.824
1.238
0.282
0.864
1.050
0.785
RT
9.09
10.88
11.56
12.43
14.55
17.58
19.16
22.01
22.39
BID
1
2
2
1
3
3
4
5
5
Amount
(ug)
99.91
86.30
76.88
89.96
91.76
107.65
105.14
80.43
91.85
Code
D
D
D
D
D
D
D
D
D
%R£C
109
85
77
90
92
108
105
80
92
Reviewed by.
Due£itJ(f>
1
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv43
-------
Triangle Laboratories of RTF, Inc.
801 CapitolaDr.
Durham, NC 27713
(919) 544-5729
Quantitation Results Method 8270-TB2
Sample File: ZD934
Response File: ZD923
Date Analyzed: 08/09/93
Date Reported:08/16/93
Project Number: 24684
Sample ID: K HO-R3
Sample ID:
TLI ID: 68-177-3(A-£)
Dilution Factor: 4.00
Analyte
Area
RF
RTISID
Amount
"g
Code Quan
Limit
FLAG
1,4-Dichlorobenzene-d
Phenol
bis(2-Chloroethyl)ethcr
2-Chlorophenol
13-Dichlorobenzene
1,4-Dichlorobenzene
1,2-Dichlorobenzene
2,2'-oxybis(l-Chloropropane)
Benzyl alcohol
2-Methylphenol
3/4-Mcthylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Naphthaiene-d
Nitrobenzene
Isophorone
2-NitrophenoI
2,4-Dimethylphenol
bis(2-Chlo roethoxy)methane
Benzoic acid
2,4-Dichlorophenol
1 ,2,4-Trichlorobenzene
Naphthalene
4-Chloro aniline
Hexachlorobutadiene
4-Chloro-3-methylphenol
2-Mcthylnaphthalene
Accnaphthcne-d
Hexachlorocydopentadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroanilinc
Dimcthyiphthalate
2,6-Dinitro toluene
2,4-Dinitro toluene
Accnaphthylenc
1765
0
0
0
0
0
0
0
0
0
0
0
0
5523
0
0
0
0
0
4306
0
0
1729
0
, o
0
65
3005
0
0
0
0
0
0
0
0
0
1.254
0.940
1.199
1.280
1.289
1-215
1.084
0.595
0.894
0.924
0.593
0.578
0.322
0.604
0.219
0.330
0.381
0.237
0.295
0.333
0.973
0.405
0.193
0.294
0.592
0.309
0.370
0.403
1.052
0.315
1.354
0.329
0.556
1.821
9.81
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
12.32
0.00
0.00
0.00
0.00
0.00
11.86
0.00
0.00
12.37
0.00
0.00
0.00
13.78
15.94
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
I
7.23 ND
9.64 ND
7.56 ND
7.08 ND
7.03 ND
7.46 ND
8.36 ND
15.24 ND
10.14 ND
9.81 ND
15-29 ND
15.68 ND
I
9.00 ND
4.80 ND
13.23 ND
8.78 ND
7.60 ND
526.35 D
9.82 ND
8.70 ND
51.49 D
7.15 ND
15.01 ND
9.85 ND
3.22 E
I
17.23 ND
14.39 ND
13.21 ND
5.06 ND
16.90 ND
3.93 ND
16.18 ND
9-57 ND
192 ND
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv4.3
-------
Triangle Laboratories of RTP, Inc.
801 CapitolaDr.
Durham, NC 27713
(919) 544-5729
Quantitation Results Method 8270-TB2
Sample File: ZD934
Response File: ZD923
Date Analyzed: 08/09/93
Date Reported: 08/16/93
Project Number 24684
Sample ID: KC '0-R3
Sample ID:
TLIID:68-177-3(A-E)
Dilution Factor: 4.00
Analyte
Area
RP
RTISID Amount
Code Quan
Limit
FLAG
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
Diethylphthakte
4-Chlorophenyl-phenylether
Fluorene
4-Nitroaniline
Phenanthrene-d
10
4,6-Dinitro-2-methylphenoI
N-Nitrosodiphenylamine
4-Bromophenyl-phenylether
Hexachloro benzene
Pen tachlo ro phenol
Phenanthrene
Anthracene
Di-n-butylphthalate
Fluoranthene
Chrysene-d
Pyrene
Butylbenzylphthalate
3,3'-Dichlorobenzidine
bis(2-EthylhexyOphthalate
Benz»(a)anthracene
Chrysenc
Pcrylene-d
Di-n-octylphthakte
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(lJ2,3-cd)pyrene
Dibenz(a,h)anthracene
Bcnzo(g,h,i) perylene
0
0
0
0
0
0
0
0
0
6581
0
0
0
0
0
0
0
3055
0
9465
0
0
0
13531
0
0
9638
0
0
0
0
0
0
0
0.426
1.036
0.213
0.315
1.570
1.594
0.582
1.304
0.589
0.144
0.378
0.160
0.209
0.170
0.959
0.899
1.555
1-339
U96
0.723
0.394
0.873
1.074
0.990
1.262
0.893
0.895
0.877
0.992
0.770
0.838
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
19.04
0.00
0.00
0.00
0.00
0.00
0.00
0.00
20.29
0.00
24.60
0.00
0.00
0.00
0.00 3
3
3
4
4
4
4
4
4
4
4
4
4
5
5
5
5
24.68 5
0.00 5
0.00 5
28.60 6
0.00
0.00
0.00
0.00
0.00
0.00
0.00
6
6
6
6
6
6
6
12.49 ND
5-14 ND
24.99 ND
16.90 ND
3.39 ND
3.34 ND
9.15 ND
4.08 ND
9.04 ND
I
16.88 ND
6.43 ND
15.19 ND
11.63 ND
14.30 ND
2.53 ND
170 ND
47.77 D
1.82 ND
I
1.30 ND
134 ND
4.29 ND
262.00 D
1.57 ND
1.71 ND
I
1.32 ND
1.86 ND
1.85 ND
1.89 ND
1.67 ND
116 ND
1.98 ND
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv43
-------
Triangle Laboratories of RTF, Inc.
801 Capitola Dr.
Durham, NC 27713
(919) 544-5729
Sample File: ZD934
Response File: ZD923
Date Analyzed: 08/09/93
Date Reported: 08/16/93
Project Number: 24684
Sample ID: ?' 010-R3
Sample ID:
TLIID:68-177-3(A-E)
Dilution Factor: 4.00
Surrogate Summary
Area RF RTISID Amount
(ug)
Code %R£C
Phenol-d
Nitrobenzene-d
5
1 ,3,5-Trichlorobenzene-d
3
1 ,4-Dibromobenzene-d
2-Fluorobiphenyl
2,4,6-Tribromophenol
Anthracene-d
10
Pyrene-d
Tcrphenyi-d
126
991
845
768
1971
54
3442
4726
3974
1.202
0.368
0.354
0.824
1.238
0.282
0.864
1.050
0.785
9-12
10.88
11.56
12.43
14.56
17.60
19.15
22.00
22.38
1
2
2
1
3
3
4
5
5
9.50
78.07
69.21
84.53
84.79
10.31
96.85
76.09
85.57
D
D
D
D
D
D
D
D
D
10
78
69
85
85
10
97
76
86
Reviewed by.
Date
ft
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrep v43
-------
Triangle Laboratories of RTP, Inc. Sample File: ZD925 Sample ID: SE )80593
801 Capicola Dr. Response File: ZD923 Sample ID:
Durham, NC 2771 3 Date Analyzed : 08/09/93 TLI ID: N/A
(919)544-5729 Date Reported : 08/16/93 Dilution Factor 1.00
Project Number: 24684
Quantitation Results Method 8270-TB2
Analyte
1 ,4-Dichlorobcnzenc-d
Phenol
bis(2-Chloroethyl)ether
2-Chlorophcnol
1 3-Dichlorobenzene
1 ,4-Dichlorobenzene
1 ,2-Dichlorobenzene
2,2'-oxybis(l-Chloropropane)
Benzyl alcohol
2-Methyiphenol
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Naphthalene-d
Nitrobenzene
Isophoronc
2-Nitrophenol
2,4-Dlmethylphenol
bis(2-Chlorocthoxy)mcthane
Benzoic acid
2,4-Dichiorophenol
1 ,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadicne
4-Chloro-3-methylphenol
2-Methyinaphthalenc
Accnaphthene-d
Hexachlorocydopentadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroanilinc
Dimethyiphthalate
2,6-Dinitro toluene
2,4-Dinitro toluene
Acenaphthylcne
Area
1467
0
0
0
0
0
0
0
0
0
0
0
0
4468
0
0
0
0
0
0
0
0
596
0
0
0
0
2528
0
0
0
0
0
0
0
0
0
RF
1.254
0.940
1.199
1.280
1.289
1.215
1.084
0.595
0.894
0.924
0.593
0.578
0.322
0.604
0.219
0.330
0.381
0.237
0.295
0.333
0.973
0.405
0.193
0.294
0.592
0.309
0.370
0.403
1.052
0.315
1.354
0329
0.556
1.821
RT ISID Amount
"g
9.80
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
12.32
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
12.36
0.00
0.00
0.00
0.00
15.94
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
117
2.90
2.27
2.13
2.11
2.24
2.51
4.58
3.05
195
4.59
4.71
178
1.48
4.09
2.71
2.35
3.78
3.03
2.69
5.49
121
4.64
3-04
1.51
5.12
4.28
3.93
1.50
5.02
1.17
4.81
185
0.87
Code Quan FLAG
Limit
I
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
I
ND
ND
ND
ND
ND
ND
ND
ND
E
ND
ND
ND
ND
I
ND
ND
ND
ND
ND
ND
ND
ND
ND
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrep v4.3
-------
Triangle Laboratories of RTP, Inc. Sample File: ZD925 Sample ID: S\ 080593
801 CapitolaDr. Response File: ZD923 Sample ID:
Durham, NC 2771 3 Date Analyzed : 08/09/93 TLI ID: N/A
(919)544-5729 Date Reported : 08/1 6/93 Dilution Factor 1.00
Project Number 24684
Quantitation Results Method 8270-TB2
Analyte
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzoruran
Diethyiphthalate
4-Chlorophenyl-phenylether
Fluorene
4-Nitroaniline
Phcnanthrene-d
10
4,6-Dinitro-2-methylphenol
N-Nitrosodiphenylamine
4-Bromophcnyl-phenylether
Hexachloro benzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butyiphthaktc
Fluoranthene
Chrysene-d
Pyrene
Butylbenzylphthalate
33'-Dichlorobcnzidine
bis(2-EthyUicxyOphthakte
Bcnzo(a)anthracene
Chrysene
Poylene-d
Di-n-octylphthalate
Bcnzo(b)fluoranthcne
Benzo(k)fluoranthcne
Bcnzo(a)pyrenc
Indeno(l 2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i) perylenc
Area
0
0
0
0
0
0
0
0
0
5026
0
0
0
0
0
0
0
12184
0
6010
0
0
0
3331
0
0
6200
0
0
0
0
0
0
0
RF
0.426
1.036
0.213
0.315
1.570
1.594
0.582
1.304
0.589
0.144
0.378
0.160
0.209
0.170
0.959
0.899
1.555
1.339
1296
0.723
0.394
0.873
1.074
0.990
1262
0.893
0.895
0.877
0.992
0.770
0.838
RT ISID Amount
"g
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
19.04
0.00
0.00
0.00
0.00
0.00
0.00
0.00
2029
0.00
24.59
0.00
0.00
0.00
24.68
0.00
0.00
2S.59
0.00
0.00
0.00
0.00
0.00
0.00
0.00
3
3
3
3
3
3
3
3
3
4
4
4
4
4
4
4
4
4
4
5
5
5
5
5
5
5
6
6
6
6
6
6
6
6
3.71
1.53
7.43
5.02
1.01
0.99
2.72
1.21
2.69
5-53
111
4.97
3.81
4.68
0.83
0.89
62.35
0.59
0.51
0.92
1.69
25.40
0.62
0.67
0.51
0.72
0.72
0.74
0.65
0.84
0.77
Code Quan FLAG
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
I
ND
ND
ND
ND
ND
ND
ND
D
ND
I
ND
ND
ND .
D
ND
ND
I
ND
ND
ND
ND
ND
ND
ND
10
10
10 •
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv43
-------
Triangle Laboratories of RTP, Inc.
801 Capicola Dr.
Durham, NC 27713
(919) 344-5729
Sample File: ZD925
Response File: ZD923
Date Analyzed: 08/09/93
Dace Reported: 08/16/93
Project Number 24684
Sample ID: SF )80593
Sample ID:
TLI ID: N/A
Dilution Factor 1.00
Surrogate Summary
Area RF RTISID Amount
(ug)
Code %REC
Phenol-d
5
Nitrobenzene-d
5
1 ,3.5-Trichlorobenzenc-d
3
1 ,4-Dibromobenzene-d
2-Fluorobiphenyi
2,4,6-Tribromophenol
Anthracene-d
10
Pyrenc-d
Tcrphenyl-d
3474
2664
2020
2177
5305
222
10225
15519
12766
1.202
0.368
0.354
0.824
1.238
0.282
0.864
1.050
0.785
9.07
10.88
11.55
12.43
14.55
17.58
19.15
22.00
22.37
1
2
2
1
3
3
4
5
5
78.77
64.81
51.10
72.02
67.80
12.51
94.17
98.36
108.23
D
D
D
D
D
D
D
D
D
79
65
51
72
68
13
94
98
108
Reviewed by.
Date &\
ND -Not Detected; D- Detected; E- Estimated; I- Internal Standard
Orgrepv43
-------
-------
APPENDIX E
COAL AND SHALE SAMPLING RESULTS
-------
RUN I.D.
DATE
SUMMARY OF COAL SAMPLING
GENERAL SHALE PLANT #10
RUN 1 RUN 2 RUN 3
07/29/93 07/29/93 07/30/93
AVERAGE
SAMPLING DATA (AS RECEIVED)
%Moisture
%Carbon
%Hydrogen
%Nitrogen
%Sulfur
%Ash
%Oxygen(diff)
Btu/lb
1.44
79.83
5.48
1.96
0.90
3.38
7.01
14408
1.49
79.77
5.43
1.89
0.90
3.26
7.26
14690
1.46
79.84
5.45
1.95
0.90
3.20
7.20
14451
1.46
79.81
5.45
1.93
0.90
3.28
7.16
14516
SAMPLING DATA (DRY BASIS)
%Moisture
%Carbon
%Hydrogen
%Nitrogen
%Sulfur
%Ash
%Oxygen(diff)
Btu/lb
NA
81.00
5.56
1.99
0.91
3.43
7.11
14619
NA
80.98
5.51
1.92
0.91
3.31
7.37
14690
NA
81.02
5.53
1.98
0.91
3.25
7.31
14665
NA
81.00
5.53
1.96
0.91
3.33
7.26
14658
-------
SUMMARY OF SHALE SAMPLING
GENERAL SHALE PLANT #10
RUNI.D. RUN1 RUN 2 RUN 3 AVERAGE
DATE 07/27/93 07/29/93 07/30/93
SAMPLING DATA (AS RECEIVED)
%Moisture 1.47 1.16 1.56 1.40
%Sulfur < 0.01 < 0.01 < 0.01 < 0.01
SAMPLING DATA (DRY BASIS)
%Moisture NA NA NA NA
%Sulfur < 0.01 < 0.01 < 0.01 < 0.01
-------
1993
COMMERCIALTESTING & ENGINEERING CO.
GENERAL OFFICES: 1919 SOUTH HIGHLAND AVE., SUITE 210-B, LOMBARD, ILLINOIS 60148 • (708) 953-9300
SINCE 1908
Member of the SGS Group (Societe GeheVale de Surveillance)
August 6, 1993
ETS, INCORPORATED
1401 MUNICIPAL ROAD, NW
ROANOKE VA 24012
KENNETH APPELL
Kind of sample COAL
reported to us
Sample taken at —
Sample taken by
Date sampled July 29, 1993
Date received August 5, 1993
PLEASE ADDRESS ALL CORRESPONDENCE TO:
P.O. BOX 808, CHARLESTON, WV 25323
TELEPHONE: (304) 925-6631
FAX: (304) 925-8877
Sample identification by
SAMPLE I.D.: COAL SAMPLE
07/29/93
Analysis Report No.
61-28087
SHORT PROXIMATE - ULTIMATE ANALYSIS
% Moisture
% Carbon
% Hydrogen
% Nitrogen
% Sulfur
% Ash
% Oxygen(diff)
Btu/lb
As Received
1.44
79.83
5.48
1.96
0.90
3.38
7.01
100.00
14408
Dry Basis
xxxxx
81.00
5.56
1.99
0.91
3.43
7.11
100.00
14619
MAF 15138
Respectfully submitted,
COMMERCIAL TESTING & ENGINEERING CO.
Manager, Charleston Laboratory
OVER 40 BRANCH LABORATORIES STRATEGICALLY LOCATED IN PRINCIPAL COAL MINING AREAS, TIDEWATER AND GREAT LAKES PORTS, AND RIVER LOADING FACILITIES
F-465
Original Watermarked For Your Protection TERMS AND CONDITIONS ON REVERSE
-------
DECEIVED AUS - 9 1993
COMMERCIAL TESTING & ENGINEERING CO.
GENERAL OFFICES: 1919 SOUTH HIGHLAND AVE., SUITE 210-B, LOMBARD, ILLINOIS 60148 • (708) 953-9300
SINCE I9O8
Member of the SGS Group (Societe Geherale tie Surveillance)
August 6, 1993
ETS, INCORPORATED
1401 MUNICIPAL ROAD, NW
ROANOKE VA 24012
KENNETH APPELL
Kind of sample COAL
reported to us
Sample taken at —
Sample taken by
Date sampled July 29, 1993
Date received August 5, 1993
PLEASE ADDRESS ALL CORRESPONDENCE TO:
P.O. BOX 808, CHARLESTON, WV 25323
TELEPHONE: (304) 925-6631
FAX: (304) 925-8877
Sample identification by
SAMPLE I.D.: COAL SAMPLE
07/29/93
Analysis Report No.
61-28088
SHORT PROXIMATE - ULTIMATE ANALYSIS
% Moisture
% Carbon
% Hydrogen
% Nitrogen
% Sulfur
% Ash
% Oxygen(diff)
Btu/lb
As Received
1.49
79.77
5.43
1.89
0.90
3.26
7.26
100.00
14471
Dry Basis
xxxxx
80.98
5.51
1.92
0.91
3.31
7.37
100.00
14690 MAP 15193
Respectfully submitted,
COMMERCIAL TESTING & ENGINEERING CO.
Manager, Charleston Laboratory
OVER 40 BRANCH LABORATORIES STRATEGICALLY LOCATED IN PRINCIPAL COAL MINING AREAS, TIDEWATER AND GREAT LAKES PORTS, AND RIVER LOADING FACILITIES
F-465
Original Watermarked For Your Protection TERMS AND CONDITIONS ON REVERSE
-------
RECEIVED A06 - 9 1993
COMMERCIAL TESTING fie ENGINEERING CO.
GENERAL OFFICES: 1919 SOUTH HIGHLAND AVE., SUITE 210-B, LOMBARD, ILLINOIS 60148 • (708) 953-9300
SINCE 1908
Member of the SGS Group (Socie'te Generate de Surveillance)
August 6, 1993
ETS, INCORPORATED
1401 MUNICIPAL ROAD, NW
ROANOKE VA 24012
KENNETH APPELL
Kind of sample COAL
reported to us
Sample taken at . —
Sample taken by
Date sampled July 30, 1993
Date received August 5, 1993
PLEASE ADDRESS ALL CORRESPONDENCE TO:
P.O. BOX 808, CHARLESTON, WV 25323
TELEPHONE: (304) 925-6631
FAX: (304) 925-8877
Sample identification by
SAMPLE I.D.: COAL SAMPLE
07/30/93
Analysis Report No. 61-28089
SHORT PROXIMATE - ULTIMATE ANALYSIS
% Moisture
% Carbon
% Hydrogen
% Nitrogen
% Sulfur
% Ash
% Oxygen(diff)
Btu/lb
As Received
1.46
79.84
5.45
1.95
0.90
3.20
7.20
100.00
14451
Dry Basis
xxxxx
81.02
5.53
1.98
0.91
3.25
7.31
100.00
14665
MAF 15158
Respectfully submitted,
COMMERCIAL TESTING & ENGINEERING CO.
Manager, Charleston Laboratory
OVER 40 BRANCH LABORATORIES STRATEGICALLY LOCATED IN PRINCIPAL COAL MINING AREAS, TIDEWATER AND GREAT LAKES PORTS, AND RIVER LOADING FACILITIES
'-465
Original Watermarked For Your Protection
TERMS AND CONDITIONS ON REVERSE
-------
KtUhlVtU HUO - 3
COMMERCIAL TESTING & ENGINEERING CO.
GENERAL OFFICES: 1919 SOUTH HIGHLAND AVE., SUITE 210-B, LOMBARD, ILLINOIS 60148 • (708) 953-9300
Member Of the SGS Group (Socie'te Generate cte Surveillance)
August 6, 1993
ETS, INCORPORATED
1401 MUNICIPAL ROAD, NW
ROANOKE VA 24012
KENNETH APPELL
Kind of sample SHALE
reported to us
Sample taken at —
Sample taken by
Date sampled July 27, 1993
Date received August 5, 1993
PLEASE ADDRESS ALL CORRESPONDENCE TO:
P.O. BOX 808, CHARLESTON, WV 25323
TELEPHONE: (304) 925-6631
FAX: (304) 925-8877
Sample identification by
SAMPLE I.D.: SHALE SAMPLE RUN 1
07/27/93
Analysis report no.
61-28090
MOISTURE & SULFUR IN THE ANALYSIS SAMPLE
As Received Dry Basis
% Moisture 1.47 xxxxx
% Sulfur <.01 <.01
Respectfully submitted,
COMMERCIAL TESTING & ENGINEERING CO.
Manager, Charleston Laboratory
OVER 40 BRANCH LABORATORIES STRATEGICALLY LOCATED IN PRINCIPAL COAL MINING AREAS, TIDEWATER AND GREAT LAKES PORTS, AND RIVER LOADING FACILITIES
F-465
Original Watermarked For Your Protection TERMS AND CONDITIONS ON REVERSE
-------
KfcCEIVEO A08 - 9 1993
!COMMERCIAL TESTING & ENGINEERING CO.
3ENERAL OFFICES: 1919 SOUTH HIGHLAND AVE., SUITE 210-B, LOMBARD, ILLINOIS 60148 • (708) 953-9300
SINCC 1908
Member of the SGS Group (Societe Gehe'rale de Surveillance)
August 6, 1993
ETS, INCORPORATED
1401 MUNICIPAL ROAD, NW
ROANOKE VA 24012
KENNETH APPELL
Kind of sample SHALE
reported to us
Sample taken at
Sample taken by
Date sampled July 27, 1993
Date received August 5, 1993
PLEASE ADDRESS ALL CORRESPONDENCE TO:
P.O. BOX 808, CHARLESTON, WV 25323
TELEPHONE: (304) 925-6631
FAX: (304) 925-8877
Sample identification by
SAMPLE I.D.: SHALE SAMPLE RUN 2
07/27/93
Analysis report no. 61-28091
MOISTURE & SULFUR IN THE ANALYSIS SAMPLE
As Received Dry Basis
% Moisture 1.16 xxxxx
% Sulfur <.01 <.01
Respectfully submitted,
COMMERCIAL TESTING & ENGINEERING CO.
Manager, Charleston Laboratory
OVER 40 BRANCH LABORATORIES STRATEGICALLY LOCATED IN PRINCIPAL COAL MINING AREAS, TIDEWATER AND GREAT LAKES PORTS, AND RIVER LOADING FACILITIES
r-465
Driginal Watermarked For Your Protection TERMS AND CONDITIONS ON REVERSE
-------
COMMERCIALTESTING & ENGINEERING CO.
GENERAL OFFICES: 1919 SOUTH HIGHLAND AVE., SUITE 210-B, LOMBARD, ILLINOIS 60148 • (708) 953-9300
SINCE I9O8
Member of the SGS Group (Socie'te Gehe'rale
-------
-------
APPENDIX F.O
LABORATORY RESULTS FOR TRACE METALS AUDIT SAMPLES
-------
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
ATMOSPHERIC RESEARCH AND EXPOSURE ASSESSMENT LABORATORY
RESEARCH TRIANGLE PARK
NORTH CAROLINA 27711
Analysis for Multi-Metal Filters
Sample: Multi metals on glass fiber filters
Procedure: The filter samples should be analyzed according to
the proper EPA Reference methods.
Please note that following the complete digestion of the
filters, the digestion solution must be either
centrifuged or filtered to remove glass fibers.
Results: Report results in ug/filter.
-------
EPA AUDIT SAMPLE SUMMARY
Multi Metals Filters
High Level
RUN I.D. = H399
LABORATORY DATA
SAMPLE CATCH - micrograms/filter
COMPONENT
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Lead
Manganese
Mercury
Nickel
Phosphorus
Selenium
Silver
Thallium
Zinc
SAMPLE
Sb 7.28
As 12.8
Be
Cd
Cr
Cu
Pb
Mn
Hg <
Ni
P
Se
Ag
Tl
Zn
34.4
40.8
40.0
43.1
184
37.6
2
180
64.8
3.45
7.63
2.85
110
-------
EPA AUDIT SAMPLE SUMMARY
Multi Metals Filters
Low Level
RUN I.D. = L399
LABORATORY DATA
SAMPLE CATCH - micrograms/filter
COMPONENT
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Lead
Manganese
Mercury
Nickel
Phosphorus
Selenium
Silver
Thallium
Zinc
SAMPLE
Sb 1.04
As 9.00
Be
Cd
Cr
Cu
Pb
Mn
Hg <
Ni
P
Se
Ag
Tl
Zn
2.42
5.43
7.24
7.24
21.8
5.97
2
14.5
48.7
1.15
4.57
2.32
54.6
-------
RECEIVED SEP 2 4 1993
ETS
Proudly serving industry and government since 1973.
A subsidiary of ETS International, Inc.
A USEPA Contract Laboratory
ETS, Inc.
1401 Municipal Road N.W.
Roanoke, VA 24012
ATTN: Dr. Ted Handel
Re: Laboratory Analysis
ETSAS Client No. 6593
REPORT DATE/NUMBER: September 24, 1993 / 223
ANALYSIS FOR: Multi Metals on Glass Fiber Filters
METHOD OF ANALYSIS: USEPA Methods 200.7, 245.5, 270.2, 279.2
1
Lab ID: 144193
Other ID:
Collection Date:
Hi f-lrnl
"7iTir» — - ... —...-.. .
Client ID: H399 Matrix: FILTER
Collected by: CLIENT
/ / Time: Received at ETSAS: 08/04/93
, 7 *>fl 11 rr If \ 1 1-m-
. . . 15 fl iin/fi 1 tnr
_. _ -\A A nn /-Fi 1 -t-nr-
dO S ua/filtor
, An 0 ua/filtor
.. _, 43 i ua/filtor
1 84 na/f iltor
_ , 37 g ua/f liter
,_. ^ ? no /-f-i 1 i-nr*
IflO ua/f iltor
64 n ua/filtor
..... .. 3 45 ua/filtor
7 63 ua/filter
2 85 ua/filtor
_ 110 ua/f liter
Lab ID: 144194
Other ID:
Collection Date:
Antimony
Arsenic
Client ID: L399
Matrix: FILTER
/ /
Beryllium
Collected by: CLIENT
Time: Received at ETSAS: 08/04/93
: — 1.04 ug/filter
9.00 ug/filter
2.42 ug/filter
REPORT CONTINUED ON NEXT PAGE
1401 Municipal Road, NW - Roanoke, Virginia 24012-1309 - Telephone: 703-265-0004 - FAX: 703-563-4866
@ Printed on recycled paper ^ Printed on recyclable paper
-------
ETS, Inc.
Report of 09/24/93
Page No. 2
i- —^—— — ^— — — — ^— — OAFUTljCi AI1/U-IIOJ.O 1
Lab ID: 144194 (continued)
I
jt\±*\ 1
543 ua/filter
7 54 ua/filter
7-)A r\n/fl 1 *-a>-
21 n ua/filtor
597 ua/filter
«r 7 na/f -i 11-nr
/! R 7 nn/-F-il+-nr-
11 R no /-Fi 1 f-o-r
2 TO iirt /F-i 1 -f-^r-
i
If we may be of further assistance, please contact us at any time.
Sincerely,
ETS ANALYTICAL SERVICES^, INC.
usanne H. Deegan, Project/Manager
Printed on recycled paper -gj Printed on recyclable paper
-------
Elements
Be
cd
Cr
cu
P
pfa
Mn
As
Sb
Tl-
Multi Metals Filters
Low Level
Reported Values fttg)
. s
4.5-7
/.
/>/S"
Multi Metals Filters
High Level
Reported Values (;jg)
Ho
./
3.45
-------
G
-------
APPENDIX G.O
EQUATIONS AND CALCULATIONS
-------
APPENDIX G.I
CALCULATIONS FOR EPA METHODS 2-4
-------
EPA METHODS 2-4 CALCULATIONS
1. Metered Gas Sample Volume at Standard Conditions
AH 1
f- -h —
528
aa
Tm + 460
2 . Gas Volume of Water Vapor Collected in Impinger Liquid
- (v ~ V)x 0.047 07
3. Gas Volume of Water Vapor Collected in Silica Gel
' (W ~ *)x 0.047 15
4. Moisture Volume Fraction in Flue Gas
"of i ofvn "*• *wsg(std)
5. Moisture Volume Percentage in Flue Gas
6. Absolute Pressure of Flue Gas
P.
136
7. Nitrogen Content of Flue Gas
%W2 - 100 - (%CO2 + %O2 + %CC)
8. Dry Molecular Weight of Flue Gas
Md - 0.44x%CO2 + 0.32x%02 + 0.28x(%J^2 + %CO)
9. Wet Molecular Weight of Flue Gas
Ms - Mdx (1 - BW3) +
10. Fuel Factor Based on Flue Gas Composition
20,9 - %OL
F° ~ %ca
2
-------
EPA METHODS 2-4 CALCULATIONS - continued
11. Excess Air of Flue Gas
, -0.5%CO
%EA -- - - xlOO
- (%0-0.5%CO)
12. Average Gas Velocity, ft/sec
I
-85 . 49xCpx ( AP)
13. Area of Round Duct or Stack
. (round ducts)
s 4x144
14. Area of Rectangular Duct
L x W
AS 144
(rectangular ducts)
15. Actual Volumetric Flow Rate of Flue Gas
Q, - v0xA0x60
*=Bt 3 3
16. Flow Rate of Flue Gas at Standard Temperature and Pressure
PDx528
Qs -
(Ta + 460) X29.92
17. Dry Flow Rate of Flue Gas at Std. Temperature and Pressure
Qsd - QBx (1 - Bvs)
-------
NOMENCLATURE FOR EPA METHODS 2-4
AP
Fo
Y
L
MO
.
static
V,
V.
m
m(std)
Vs
Vwc(std)
^wsg(std)
w
wf
wi
%o2
%co2
%co
%N2
%EA
Stack area, ft2
Moisture volume fraction
Pitot tube coefficient («0.84)
Stack diameter, inches
Average meter orifice pressure, in.W.C.
Pitot tube differential pressure, in.W.C.
Combustion factor
Meter calibration factor, gamma
Length of rectangular stack or duct, inches
Dry molecular weight, Ib/lb-mole
Wet molecular weight, Ib/lb-mole
Barometric pressure, in.Hg
Absolute stack pressure, in.Hg
Average static pressure, in.W.C.
Actual gas flow rate, acfm
Standard gas flow rate, scfm
Dry standard gas flow rate, dscfm
Average meter temperature, °F
Average stack temperature, °F
Final impinger volume, ml
Initial impinger volume, ml
Uncorrected metered gas volume, dcf
Corrected gas volume, dscf
Average gas velocity, ft/sec
Gas volume of water caught in impingers, scf
Gas volume of water caught in silica gel, scf
Width of rectangular stack or duct, inches
Final silica gel mass, grams
Initial silica gel mass, grams
Dry volumetric concentration of 02, %dv
Dry volumetric concentration of C02, %dv
Dry volumetric concentration of CO, %dv
Dry volumetric concentration of N2, %dv
Percent excess air
-------
APPENDIX G.2
CALCULATIONS FOR EPA METHOD 5 PARTICULATE,
METHOD 201A, AND METHOD 202
-------
EPA METHOD 5 GRAVIMETRIC CALCULATIONS
1. PM Collected in Probe Wash -
- ( WpW> final ' ^pw> tare
2. Applicable Acetone Blank Correction - Bapw
Bapw = [(^ final
3. Maximum Allowable Acetone Blank - Bamax
Bamax = 0.7845 X 0.00001 X Vpv
4. Actual Probe Wash Blank Correction - B_w
Bpw = MINIMUM [Bapw, Bamax]
5. PM Collected on Filter - Mf
Mf= (^ final
6. Total PM Collected for Method 5 Calculations - M5
M5 = Mpw + Mf - Bpw
NOMENCLATURE
= Maximum allowable acetone blank correction,
t '
based on weight of acetone in probe wash,
grams
= Acetone blank correction based on residue of
blank, grams
B_w = Acetone blank correction actually used, grams
Me- = Total mass of particulate in train corrected for
acetone blank, grams
Mf = Mass gain of filter, grams
M_w = Probe wash residue, grams
vab = Liquid volume of acetone blank, ml
= Liquid volume of probe wash, ml
finai = Final weight of beaker containing acetone blank
residue, grams
(wat>)tare ~ Tare weight of beaker containing acetone blank
residue, grams
(wf) final = Final weight of filter, grams
(Wf)tare = Tare weight of filter, grams
(Wpw)finai = Final weight of beaker containing probe wash
residue, grams
(Wpw) tare = Tare weight of beaker containing probe wash
residue, grams
-------
PA.
-------
CALCULATIONS FOR EPA METHOD 201A
Determination of cyclone flow rate and orifice pressure head!
Molecular weight of stack gas, dry basis, Md:
+ 0.32(%O2) +0.2
where Md = Ib/lbmol.
Molecular weight of stack gas, wet basis, MH:
Mv-Md(l-Bwa)+18(Bws)
where BHS = moisture fraction of the stack gas;
Mw = Ib/lbmol.
Absolute stack pressure, PS:
+
13.6
where P^ = barometric pressure (HHg) ;
P = stack static pressure ("H20) ;
Pi = "Hg.
Viscosity of stack gas, MS:
H s-152.418+ 0. 2552 tfl+3. 2355xlO-5tJ +0.53147 (%O2) -74.143BB
where ts = average stack temperature (°F) ;
Hs = micropoise.
Cyclone flow rate, Qs:
[ (C0+460) I0'2949
Ps-0.002837M ' '
where Q = ft3/min.
-------
CALCULATIONS FOR EPA METHOD 201A (continued)
Orifice pressure head, AH, needed for cyclone flow rate:
AH-
CU1--ELJP,
ws' * s
. 083
rJbar
where tm = meter temperature (°F);
AH = "H20.
Equations for Nozzle Selection;
Nozzle velocity, vn:
3.056
where Dn = nozzle diameter (in.);
vn = ft/sec.
Minimum and maximum velocities, vmin and v|nax, in ft/sec:
Calculate R:
-0.2457
0.3072
0.2603^^
If R,,,^ is less than 0.5 or imaginary then:
Otherwise use:
-------
CALCULATIONS FOR EPA METHOD 201A (continued)
Calculate
vn
1.5
If R^ is greater than 1.5 then:
Otherwise use:
max~ ni"inax
Minimum and maximum velocity head values, Apm,.n and Apm
Apmi_ -1. 36 86x10"4 —^
-1. 36 86x10-4
where CD = pitot coefficient
A = "H°-
Dwell time;
Dwell time at first traverse point, t,:
where 6 = total run time (min);
N = total number of traverse points;
AP'I — velocity head at the first traverse point
(from a previous traverse) ("H20) ;
Ap'avg = tne square of the average square root of the
Ap's (from a previous traverse) ("H20);
t = min.
-------
CALCULATIONS FOR EPA METHOD 201A (continued^
Dwell time at subsequent traverse points, tn:
~n ,n-2.3....N
Apn = measured velocity head at point n ("H2O);
Ap., = measured velocity heat at point 1 ("H2O) ;
tn = min.
Determination of D;o;
Stack gas viscosity, nc c:
where C1 = 51.05 micropoise;
C2 = 0.207 micropoise/R;
C3 = 3.24xlO"5 micropoise/R2;
C4 = 53.147 micropoise/fraction O2;
C5 = 74.143 micropoise/fraction H2O;
Ts = average absolute stack gas temperature (R);
f02 = stack gas 02 volume fraction, dry basis;
Bws = stack gas moisture volume fraction;
/icyc = micropoise.
Total cyclone flow rate at standard conditions, Qs/ste|):
6
where Vm(std) = volume of gas measured by DGM corrected to
standard conditions (dscf);
6 = total sampling time (min);
PM10 flow rate, at actual cyclone conditions, Qs:
T,
s
V,
w(std)
-------
CALCULATIONS FOR EPA METHOD 201A (continued)
where K, = 17.64 R/"Hg;
V,
w(std)
= volume of water vapor in gas sample at
standard conditions (scf);
Qs = ft,/min.
Diameter of particles having a 50% probability of
penetration, D50:
"Pi
0.2091
10.7091
where B1 = 0.15625
D50 = Jim.
-------
METHOD 202 CALCULATIONS
1. Calculated correction factor
where ,
K = 0.0205 when correcting for NH4+ and H2O
= 0.1840 when correcting for NH4+ only
2. Weight of total corrected inorganic CPM (ing)
rr _
V vic
3. Corrected concentration of CPM (mg/dscm, mg/dscf)
= m0 + m± - mb
cpm v
vm(std)
4. CPM emission rate (kg/hr, Ib/hr)
ERcpm = K Ccptn
where K = 6.0E-5 (kg min)/(mg hr) for metric units
= 1.32E-4 (Ib min)/(mg hr) for English units
5. Calculation of sulfate ion concentration using NH3
titration
_ 48.03 Vt N
Cso*2 100
-------
METHOD 202 CALCULATIONS (Continued)
NOMENCLATURE
CCPM
CS04
mc
mCl
m°
N
Q
Vic
Vm(std)
concentration of CPM in flue gas (mg/dscm, mg/
dscf)
concentration of S04~2 in sample (mg/ml)
mass of NH4+ added to sample to form (NH4)2SO4
(mg)
correction factor for chloride
weight of CPM in MeCl2 and H20 blanks (mg)
weight of inorganic CPM (mg)
weight of organic CPM (mg)
weight of dried inorganic fraction (mg)
normality of NH4OH (mg/ml)
volumetric flow rate (dscmm, dscfm)
volume of sample taken for 1C analysis (ml)
volume of impinger contents sample (ml)
volume of gas sampled, corrected to standard
conditions (dscm, dscf)
volume of NH4OH titrant
-------
APPENDIX G.3
CALCULATIONS FOR EPA METHOD 29 MULTIPLE METALS
-------
METALS CALCULATIONS
LABORATORY CALCULATIONS;
1. Percent recovery - (%R)
a_ SpikeResult - SampleResult
«.K~ ——r: _ . ,—j
SpikeAdded
2. Total mass of each metal in the front half (except Hg)
M « C1 * P7 * I/
mfh '"ill rd vaol,l
where Mfh = total mass of each metal (except Hg)
collected in the front half of the
sampling train.
Cfl1 = concentration of metal in sample Fraction
1A as read from the standard curve
(ug/ml).
Fd = dilution factor (Fd = the inverse of the
fractional portion of the concentrated
sample in the solution actually used in
the instrument to produce the reading
cei>-
Vsoln , = total volume of digested sample solution
(Fraction 1), ml.
3. Total mass of each metal in the back half (except Hg)
AfLi. - C , * F * V
JbA ^a2 a a
where M^ = total mass of each metal (except Hg)
collected in the back half of the
sampling train (Fraction 2), ug.
Ca2 = Concentration of metal in sample
concentrated Fraction 2A, as read from
the standard curve (ug/ml).
Fa = aliquot factor, volume of Fraction 2
divided by volume of aliquot Fraction 2A.
Va = total volume of digested sample solution
(concentrated Fraction 2A), ml.
4. Total mass of mercury in front half
Qth
where Hgfh = total mass of mercury collected in the
front half of the sampling train
(Fraction 1), ug.
Qfh = quantity of mercury in analyzed sample,
ug
Vf1B = volume of fraction IB analyzed, ml.
V8oln 1 = total volume of digested sample solution
(Fraction 1), ml.
-------
5. Total mass of mercury in back half Fraction 2
. °»i* * v
V VBOl,2
where Hg^ = total mass of mercury collected in
Fraction 2, ug.
0^,2 = quantity of mercury in analyzed sample,
ug
Vf2B = volume of fraction 2B analyzed, ml.
Vsoin 2 = total volume of Fraction 2 , ml .
6. Back half mercury calculation for Fractions 3A, 3B, and 3C
f3(A,B,O
where Hg^^ B C) = total mass of mercury collected
separately in Fraction 3a,3b, or 3c, ug.
B o = quantity of mercury in separately
analyzed samples, ug.
o -. = volume of Fraction 3A.3B, or 3C analyzed,
Of Ly *
ml.
Vsoin 3
-------
3. Concentration corrected to 7% 02, Cj7 is:
. 9
where %O2 = oxygen content in stack gas, dry %
4. The mass flow rate of substance (i), G{ (Ib/hr), is:
J Vraatdxl06x453.593
where Wf = total sample weight of (i) (micrograms)
Vmstd = the volume of gas sampled at STP (dscf)
Qsd — stack gas flow rate (dscfm)
60 = min/hr
106 = micrograms per gram
453.593 = grams/lb
-------
APPENDIX G.4
GENERAL GASEOUS EMISSIONS CALCULATIONS
-------
INSTRUMENT ANALYZER CALCULATIONS
1. Analyzer Calibration Error is determined by:
Ec - ^S^X. x 100
2. System Bias is determined by:
B- - * c x 100
3. Calibration Drift is determined by:
D,. - ——- x 100
4. The Adjusted Data Value is determined by:
r - Cc-r) x ina
Sas Vl- co' x r _r
-------
Nomenclature;
Ac = the analyzer response for calibration gas standard
Bs = Sampling system bias, % analyzer span
C = the average gas concentration of the analyte
indicated by the gas analyzer
Cg = the actual gas cylinder concentration value
Cr»,Q = tne adjusted gas concentration of the analyte
guo
Cm = the average of initial and final system
calibration responses for the upscale calibration
gas
C^ = the actual concentration of the upscale
calibration gas used for system calibration
C0 = the average of initial and final system
calibration responses for the zero gas
Cs = the system response for calibration gas introduced
remotely at the sample probe (zero or upscale)
Dc = Calibration drift, % analyzer span
EC = Analyzer calibration error, % analyzer span
Fc = Final system calibration response value
Ic = Initial system calibration response value
Vs = Span value of analyzer
-------
GASEOUS EMISSIONS MONITORING CALCULATIONS
1. Conversion of wet basis to dry basis concentration (THC only)
c-
100
where Cd = Dry basis total hydrocarbon concentration, ppmdv
Cw = Wet basis total hydrocarbon concentration, ppmwv
%H20 = Moisture content of stack gas, %
2. Conversion of total hydrocarbon concentration as propane to
total hydrocarbon concentration as carbon:
where Cc = Hydrocarbon concentration as carbon, ppmdv
Cd = Hydrocarbon concentration as propane, ppmdv
K = Carbon equivalent correction factor (3 for
propane)
3. CONCENTRATION AT 7% O2
on Q-7 0
-(7.x ^U'a ' '"
i 1 20.9-%O2
where C7i = Concentration of gas i corrected to 7% 0,
%O2 = Actual gas concentration of 02, % dry volume
-------
GASEOUS EMISSIONS MONITORING CALCULATIONS (Continued)
4. Hourly emissions rate - M,.
M,--
106xO.84948x453.593
where
Ci
MWf
0.84948
453.593
10
6 _
NOX/ CO, or total hydrocarbons (as carbon)
Mass emissions rate of i, Ib/hr
Concentration of i in stack gas, ppmdv
Molecular weight of i
28.01 for CO
46.01 for N02
12.01 for Carbon
Average flue gas flow rate, dscfm
Minutes per hour
Molar volume of ideal gas, ft3/mole
grams per pound
parts per million
-------
H
-------
APPENDIX H.O
FIELD EQUIPMENT CALIBRATIONS
-------
E T S , INC.
METER CONSOLE CALIBRATION FORM
Contract No. 93-950
Job I.D.
Meter Box No.: 6
Delta Hi 1.7296
Gamma: 1.0062
Analyst: wch
Calibration Date: 07/23/93
Test Meter No. 9548
Barometric Pressure 28.81
Print Date 07/23/93
Run
1
2
3
4
5
6
Orf
Set
0.5
1.0
1.5
2.0
2.5
3.0
Initial
Test
319.854
330.445
341.135
352.442
362.856
373.198
Final
Test
330.303
340.935
352.261
362.664
373.009
388.188
Volume
Test
10.449
10.490
11.126
10.222
10.153
14.990
Init
Temp
75.0
76.0
76.0
76.0
76.0
76.0
Finl
Temp
75.0
75.0
76.0
76.0
75.0
76.0
Test
Temp
75.00
75.50
76.00
76.00
75.50
76.00
Initial
Box
430.851
441.475
452.211
463.561
474.011
484.366
Final
Box
441.334
451.991
463.368
473.817
484.182
499.359
Volume
Box
10.483
10.516
11.157
10.256
10.171
14.993
I-I
Temp
76.0
81.0
84.0
87.0
85.0
89.0
1-0
Temp
75.0
77.0
80.0
81.0
82.0
82.0
F-I
Temp
77.0
80.0
81.0
82.0
82.0
83.0
F-0
Temp
81.0
85.0
87.0
85.0
90. 0
92.0
Temp
77.25
80.75
83.00
83.75
84.75
86.50
Time
25.0
18.0
16.0
12.5
11.0
15.0
Delta H
1.67783
1.71804
1.80592
1.73870
1.69971
1.73762
*
Gamma
0.99967
1.00474
1.00639
1.00596
1.00904
1.01164
-------
E. T.S. INC.
METER CONSOLE CftLIBRflTION FORM
Meter Box No.
THERMOCOUPLE NUMBER
RUN NUMBER
1
£
*i
4
5
6
7
e
9
10
11
6 REFERENCE CflLIBRflTOR
1 Date
REFRENCE
TEMPERflTURE
1
33
10£
200
S97
THERMOCOUPLE
TEMPERflTURE
1
33
101
£01
£98
400
50£
704
800
900
704
800
900
HH71 CflK-K
ll-May-93
DIFFERENCE
%
0. 000
0.000
0.980
-0.500
-0. 337
0.000
0.000
-0. Ifefc
0.000
0.000
0.000
CftLIBRflTION PERFORMED BY R. RICHflRDS
-0.00£1 flVERflBE DIFF
Comments:
-------
E.T.S. INC.
METER CONSOLE CftLIBRflTION FORM
Meter Box No
THERMOCOUPLE NUMBER
RUN NUMBER
1
2
3
4
5
6
7
e
9
Id
11
6 REFERENCE CflLIBRflTOR
2 Date
REFRENCE
TEMPERflTURE
1
32
195
301
398
497
604
700
801
898
THERMOCOUPLE
TEMPERflTURE
1
32
101
196
302
397
495
605
700
800
896
HH71 CflK-K
ll-May-93
DIFFERENCE
%
0.000
0.000
0.980
-0.513
-0.332
0.251
0.402
-0.l&fc
0.000
0. 125
0.223
CflLIBRflTION PERFORMED BY.
R. RICHORDS
0.0683 flVERflBE DIFF
Comments:
-------
E.T.S. INC.
METER CONSOLE CflLIBRflTION FORM
Meter Box No
THERMOCOUPLE NUMBER
RUN NUMBER
1
2
3
4
5
6
7
e
9
10
11
6 REFERENCE CflLIBRflTOR
3 Date
REFRENCE
TEMPERflTURE
1
34
98
196
380
401
584
603
701
799
898
THERMOCOUPLE
TEMPERflTURE
1
34
97
19fc
302
401
502
603
701
798
897
HH71 CflK-K
ll-May-93
DIFFERENCE
%
0.000
0.000
1.020
0.000
-0.667
0.000
0.397
0.000
0.000
0.125
0.111
CflLIBRflTION PERFORMED BY.
R. RICHARDS
0.0897 flVERflGE DIFF
Consents:
-------
E.T.S. INC.
METER CONSOLE CALIBRATION FORM
Meter Box No
THERMOCOUPLE NUMBER
RUN NUMBER -
1
£
3
4
5
6
7
a
9
10
'••• 11
6 REFERENCE CALIBRATOR
4 Date
REFRENCE
TEMPERATURE
1
31
102
804
£99
399
503
597
696
801
898
THERMOCOUPLE
TEMPERflTURE
1
31
104
£0£
£96
399
501
597
701
800
896
HH71 CAK-K
ll-May-93
DIFFERENCE
%
0.000
0.000
-1.961
0.980
1.003
0.000
0.398
0.000
-0.430
0. 1£5
0.000
CflLIBRflTION PERFORMED BY R. RICHftRDS
0.0105 AVERflGE DIFF
Consents:
-------
E.T.S. INC.
METER CONSOLE CflLIBRflTION FORM
Meter Box No
THERMOCOUPLE NUMBER
RUN NUMBER
1
£
3
4
5
fc
7
8
9
10
11
REFERENCE CftLIBRflTOR
Date
REFRENCE
TEMPERflTURE
1
31
104
£0£
295
399
50£
596
781
800
899
THERMOCOUPLE
TEMPERflTURE
1
31
104
£02
£9fc
399
501
597
701
800
898
HH71 CflK-K
li-May-93
DIFFERENCE
*
0.000
0.000
0.000
0.000
-0.339
0.000
0.199
-0.1&8
0.000
0.000
0. Ill
CflLIBRflTION PERFORMED BY.
R. RICHflRDS
-0.0176 flVERflBE DIFF
Comments:
-------
E.T.S. INC.
METER CONSOLE CftLIBRflTION FORM
Meter Box No
THERMOCOUPLE NUMBER
RUN NUMBER
1
£
3
4
5
6
7
B
9
10
11
fe REFERENCE CflLIBRftTOR
6 Dat e
REFRENCE
TEMPERflTURE
1
3b
98
197
384
402
500
599
703
804
897
THERMOCOUPLE
TEMPERflTURE
1
3b
98
198
306
40£
500
&01
703
804
897
HH71 CflK-K
ll-May-93
DIFFERENCE
%
0.000
0.000
0.000
-0.508
-0.&58
0.000
0.000
-0.334
0.000
0. 000
0. 000
CflLIBRflTION PERFORMED BY.
R. RICHARDS
-0.13&3 flVERflBE DIFF
Comments:
-------
E.T.S. INC.
METER CONSOLE CALIBRATION FORM
Meter Box No.
6 REFERENCE CALIBRATOR
7 Date
RUN NUMBER
1
2
3
4
5
6
7
6
9
10
11
REFRENCE
TEMPERATURE
1
35
99
£05
299
396
504
597
697
800
898
THERMOCOUPLE
TEMPERATURE
1
35
99
£06
301
398
503
599
697
799
898
HH71 CflK-K
ll-May-93
DIFFERENCE
*
0.000
0.000
0.000
-0.488
-0.669
0.000
0. 198
-0.335
0.000
0. 125
0.000
CALIBRATION PERFORMED BY R. RICHARDS
-0.1062 AVERAGE DIFF
L-omment s:
-------
E T S , INC.
METER CONSOLE CALIBRATION FORM
Contract No. 93-948T
Job I.D.
Meter Box No.: 6
Delta H: 1.7168
Gamma: 0.9962
Analyst: wch
Calibration Date: 08/04/93
Test Meter No. 9548
Barometric Pressure 28.94
Print Date 08/04/93
Run
1
2
3
4
5
6
Orf
Set
0.5
1.0
1.5
2.0
2.5
3.0
Initial
Test
873.460.
884.041
894.092
905.876
918.690
929.387
Final
Test
883.845
893.920
905.653
918.522
929.164
939.912
Volume
Test
10.385
9.879
11.561
12.646
10.474
10.525
Init
Temp
72.0
73.0
72.0
72.0
73.0
73.0
Finl
Temp
73.0
73.0
73.0
73.0
73.0
72.0
Test
Temp
72.50
73.00
72.50
72.50
73.00
72.50
Initial
Box
960.694
971.467
981.724
993.722
1006.72
1017.54
Final
Box
971.271
981.530
993.478
1006.55
1017.32
1028.14
Volume
Box
10.577
10.063
11.754
12.823
10.593
10.597
I-I
Temp
74.0
79.0
82.0
80.0
85.0
87. 0
I-O
Temp
73.0
76.0
77.0
78.0
80.0
80.0
F-I
Temp
76.0
77.0
79.0
80.0
80.0
81.0
F-O
Temp
80.0
83.0
83.0
87.0
88.0
90.0
Temp
75.75
78.75
80.25
81.25
83.25
84.50
Time
25.0
17.0
16.5
15.5
11.5
10.5
Delta H
1.67987
1.71041
1.75660
1.72421
1.72634
1.70317
Gamma
0.98659
0.98979
0.99411_
0.99733
1.00142
1.00791
-------
E T S , INC.
METER CONSOLE CALIBRATION FORM
Contract No. 93-95O
Job I.D.
Meter Box No.t 9
Delta Hi 1.8521
Gamma: 1.0046
Analysti wch
Calibration Datei O7/22/93
Test Meter No. 9548
Barometric Pressure 28.88
Print Date O7/22/93
Kim
Orf
Set
0.5
1 .0
1.5
2.O
2.5
3.0
Initial
Test
241.670
253.772
264.306
275.682
289.196
304.831
Final
Test
253.505
264.128
275.454
288.965
304.657
317.368
Volume
Test
11.835
10.356
11.148
13.283
15.461
12.537
Init
Temp
73.0
73.0
73.0
73.0
72.0
72.0
Finl
Temp
73.0
72.0
73.0
71.0
72.0
72.0
Test
Temp
73.00
72.50
73.00
72.00
72.00
72.00
Initial
Box
392.579
404.753
415.356
426.805
440.415
456.115
Final
Box
404.490
415.175
426.598
440.186
455.920
468.648
Volume
Box
11.911
1O.422
11.242
13.381
15.505
12.533
I-I
Temp
72.0
75.0
78.0
79.0
79.0
79.0
1-0
Temp
72.0
78. 0
82.0
85.0
84.0
86. O
F-I
Temp
79.0
82.0
86.0
85.0
86.0
87.0
F-O
Temp
75.0
77.0
79.0
79.0
78.0
79.0
Temp
74.50
78.00
81.25
82. OO
81.75
82.75
Time
29.5
18.5
16.5
17. O
17.5
13.0
Delta H
1.81237
1.84620
1.89314
1.87768
1.83665
1.84632
Gamma
0.99515
1.O0138
1.00316
1.O0621
1.OO9O1
1.01280
-------
THERMOCOUPLE CALIBRATIO.'I DATA SHE--?
-,... Ol'lO^l rv_ounl.,,, +*/ &yl
Aroient Temp
Calibrator:
!
| Reference
i point
! No.4
i
i
1
I
i
i
i
i
i
i
1
i
i
i
i
j
;
i
erafjre: , , °" 3arcr.etr1e =ro??urp- "He
C \<1 £-e.ft'^10A Rafere
TO l« J J}
Source*
(specify)
Reference
tneraanezer
tecperaure,
°F
O
3^
1 00
30*
3oo
V^)0
5ao
600
-700
*00
900
Every 1CO°F for each reference point when
• Source: 1 Ice tath
2) Furnace
5 Percent difference < 1.55
Ref. temp. 3F - tneraocauple ter.p. °F
Ref. tesip. °F
ncs: Herc-jry-in-gla
Oth
Thermocouple
potenti ccs ter
tecperature.
"F
o
?0
17
$60
300
Wl. ^
Sot^k
6
-------
THERMOCOUPLE CALISRATIC.'J DATA SKEE>
*,,.. 05-30-iJ 7_Plinlp,n: $3 &*<=}
Ambient Ten;;
Calibrator:
Reference
point
Mo.a
_
lorat'jre: °" Sare-.etrlc =rp«sure: "Ha
C /tf/j^J'OA Rofere
Sourca*
(specify)
Reference
thenncaeter
terse ra tare,
°F
n
i?
100
2oo
300
LfOO
50Q
fao
loo
W
fyo
3
Every 100°F for each reference point when
• Source: 1) Ice bath
2) Furnace
b Percent difference i 1 .55
Ref. temp. "F - thermocouple teco. °F
Ref. teap. '?
r.cs: Mercury- in-g la
OUi
Thersocauple
potent: cr.e tar
tec^eratare,
•F
(9
3.o
tf
j?9 '
3*2
39f
V^f
*00
7^
^^
^^
Average
5 difference
SS!
*T'.tfHlH*i'£
Difference,15
-------
1
r
i TnERHCCCL'PLE CALIBRATIC.'l CATA SKEE^
I Aabient Ter;p
Calibratsr:
: Reference
i point
i
I
i
praters: ,..,,. "- Sarr— Ptr^c crp5sure! "He
/- r
U- f^fi'Uj:-, Rofprp
-/
Source*
(scecify)
1 i
1 i
t
i
j
i
1 1
i I
i i
!
i
:
.
Deference
tnerecaeter
tessera ture.
"F
0
1J
100
20!)
ncs: Merc^ry-in-gla
Oth
Thenrocouple
potenticr.etfir
ter.perature ,
°F
O
3^
^•^
/ ' '
3QO 7>3Q
LjOO
' 39?
£QO L/?y
• too
70o
$00
W
Every 100°F for each reference point when
• Source: 1) Ice tath
2) Furnace
•* Percent difference £.1.55
Ref. tenp. °F - thennocsuple terp. °F
Ref. tenp. 'F
600
-7 on
G'JO
^*\ . _
*^7 - /' ^_,'
Average
5 difference
««•
er-H H~7 (~~( AL'
Difference,5'
9
O
G.7.5
n /)
.5
0.
jj-
. 3
3
1
';
r\
.V£
using furnace up to EOO'F.
x ICO
1
ft
-------
i
1
1
J
i
i
!
-.5. ;:;c.
Tr:-RMCCC'J?L£ CALIBRATION DATA SKEE^
•\,r». Oj'-s' ' x TSorr-nrouole ,1o. : & U .?.''•' ^ -
/vr.bier.t Terr.;
Calibrate:-:
Reference
point
No.4
pra<-jre: '? 3arcr.etr1c =rP55urp: "HO
£ -r :'••-'..*?.. Rof^re
Source*
(specify)
Reference
y.enscaeter
rerrperat^re,
•F
0
32
idO
2oo
300
wo
£00
• 600
700
*00
fl *.r\
• J'J
a
Every 1CO°F for each reference point when
• Source: 1) Ice bath
2) Furnace
b Percent difference i 1.55
P.ef. tenp. "F - thermocouple tecp. °F
Ref. temp. 'F
nee: Kercury-in-gli
Ot*
Theraoccuple
potenti caeter
tesnperatare,
°F
0
10
w
}3&
3oo
>i 00
Hw
601
700
$00
300
Average
*» difference
«•
pr-}40/ -Se/-lc
Difference,1'
tr
m
\ 0
6.ar
^
w.
£
>-\
_/
•3 - -
• 3
- !i7
O
0
C?
.^?9
using furnace up to SCOT.
t. ICO
-------
7ri£RMCCOJ?l£ CALIBRATION DATA SHEET-
01 . 1 / -n ? *~- •/" /? ~ • $
-> •* • '• • Thf>rr.ncaunle No.: f~~ -^ f- ' '
Antner.t Tern;
Calibrate:-:
Reference
point
No.*
erat-jre: °? 3arcr.etr-tc oressupe: "HC
C ''ft':-:* Refere
Source*
(specify)
Reference
tnennciseter
terperauire,
•F
0
31
100
£03 •
300
L/ao
Soo
- SoO
•7GQ
too
^0
Every 1CO*F for each reference point when
• Source: 1) Ice bath
Z) Furnace
b Percent difference i 1.55
Ref. temp, "f - thermocouple tesp. 8F
Ref. temp. 3F
ncs: Mercury-in-gla
Oth
Thercccouple
potenticneter
teciperature,
°F
o
L 10
QZ
)H
loo
3W
Hw
£•33
700
£ OO
G.-)Q
Average
5 difference
«•
\
pr. rfA' ~- '-c»i •<:
Difference,''
9
•
0
h.oj
1
,5
.0
.75
,3
. 0
0
0
0
.0U
using furnace up to SOO'F.
x ICO
-------
!
-------
THERKCCCUPIE CALlBRATIC.'l CATA SHEE?
! late:
rn. - i
w' „, ' , (
Therr.occupie ,'io.:
nt 7e.~per2.-re:
. °F 3arcc.etric pressure:
Ssferenca: Merc-jry-in-glass:
Other:
Rafererca
point
,Vo.a
; •
i
i
Source*
(specify)
Reference
yienaseter
tes^Jeraciire,
•F
^
3^
)00
3QO
300
H60
500
£00
701
%60
[ *to\
Thenrocsuple
potenficcatar
lenperatare,
°F
0
•11
$3
£00
10?
w
HW
600
7<7>
too
401
Average
5 difference
Difference,13
;
o
3.^5
)
0
ft
^
,Q
^>
0
0
r-»
\.'
..mfi
i Every '."O'F for each referecce ?cint when using furnace up to 500°F.
« Source: 1) Ice tath
2) Furnace
b Fercer.t difference 5. 1.55
Ref. tenp. °F - theraocsuple *ecp. °F
F.ef. tesp. 5F
ICO
-------
E T S , INC.
METER CONSOLE CALIBRATION FORM
Contract No. 93-937T
Job I.D.
Meter Box No.t 9
Delta H: 1.9033
Gamma: 0.9964
Analyst: wch
Calibration Date: 08/06/93
Test Meter No. 9548
Barometric Pressure 28.76
Print Date 08/09/93
Run
1
2
3
4
5
6
Orf
Set
0.5
1.0
1.5
2.0
2.5
3.0
Initial
Test
11.449
21.782
32.343
51.249
62.285
76.422
Final
Test
21.460
32.203
50.977
62.159
76.256
86.871
Volume
Test
10.011
10.421
18.634
10.910
13.971
10.449
Init
Temp
73.0
72.0
72.0
71.0
72.0
72.0
Finl
Temp
72.0
72.0
71.0
72.0
74.0
72.0
Test
Temp
72.50
72.00
71.50
71.50
73.00
72.00
Initial
Box
77.965
88.380
99.061
118.227
129.399
143.751
Final
Box
88.056
98.923
117.948
129.272
143.584
154.351
Volume
Box
10.091
10.543
18.887
11.045
14.185
10.600
I-I
Temp
75.0
77.0
79.0
83.0
83.0
79.0
1-0
Temp
74.0
74.0
76.0
78.0
78.0
85.0
F-I
Temp
73.0
76.0
77.0
78.0
88.0
86.0
F-O
Temp
77.0
81.0
83.0
83.0
79.0
79.0
Temp
74.75
77.OO
78.75
80.50
82.00
82.25
Time
25.5
19.0
27.5
14.0
16.0
11.0
Delta H
1.89607
1.93111
1.88814
1.89722
1.89431
1.91272
Gamma
0.99499
0.99517
0.99624
0.99939
0.99518
0.99710
-------
APPENDIX I
FACILITY PROCESS DATA
-------
Date: April 7, 1994
Subject: Test Completion Notice: General Shale Plant No. 10
Johnson City, Tennessee
Review and Update of AP-42 Chapter 8, Mineral Products
EPA Contract 68-D2-0159, Work Assignment'I-01
MRI Project 4601-01
From: Brian Shrager
To: Ron Myers
TSD/EIB/EFMS (MD-14)
U. S. Environmental Protection Agency
Research Triangle Park, N.C. 27711
I. Background
Source testing was conducted at General Shale Products
Corporation (General Shale) Plant No. 10, Johnson City,
Tennessee, from July 26 through 31, 1993. The purpose of this
testing program was to obtain data to characterize emissions from
a typical coal-fired brick manufacturing plant. Specifically,
the primary objectives of the test were to quantify emissions of
particulate matter (PM), PM-10, metals, hydrogen fluoride, total
hydrocarbons, methane, ethane, volatile hazardous air pollutants
(HAP's), semivolatile HAP's, carbon monoxide (CO), sulfur dioxide
(S02) and nitrogen oxides (NOX) from the most significant sources
associated with brick manufacturing. Emission factors will be
calculated based on the emission data and the process rates
recorded during the testing program.
II. Emission Testing
Figure 1 provides a process flow diagram with the sampling
points identified. Production begins at the grinding room, which
is a large metal building that houses a primary crusher, a pan
grinder, five vibrating screens, a hammermill, and several
material transfer points and conveyors. The grinding room has
three bay doors, two exhaust fans (not operating during testing)
located near the top of the building walls, two exit doors, two
doors that lead to the raw material storage building and conveyor
system, and a large opening that allows trucks to access the
hopper that feeds the primary crusher. With the exception of the
truck access opening, all of the bay doors and other doors
remained shut during testing. Emissions from the crusher,
grinder, and screens are ducted to a fabric filtration system
that is also located in the grinding room. Dust collected in the
fabric filter is transferred to a conveyor that leads from the
primary crusher to the pan grinder. Emissions from the grinding
-------
SAMPLING POINTS
Al: Grinding room exhaust
A2: Fabric filter dust
B: Finished material storage piles
C: Dryer exhaust
D: Kiln exhaust
E: Coal storage piles
Emission*
I Al
KEY
MATERIAL FLOW
EMISSIONS
Figure 1. Location of Sampling Points for General Shale, Johnson City, Tennessee
-------
room consist of fugitive particulate matter (PM). Controlled
filterable PM and PM-10 emissions from the grinding room were
measured at the fabric filter exhaust stack (Sampling Point Al)
using Methods 5 and 201, respectively. During the stack tests,
timed samples of the fabric filter discharge (Sampling Point A2)
were collected in order to estimate uncontrolled PM emissions
from the grinding room operations.
During each grinding room test run, bulk material samples
were collected from the grinding room conveyor that conveys the
finished material to storage (Sampling Point B). The samples
will be analyzed for silt and moisture content.
The exhaust from the drying section of Kiln A (Sampling
Point C) was sampled for total hydrocarbons (Method 25A) and
methane and ethane (Method 18). The exhaust from the firing
section of Kiln A (Sampling Point D) was sampled for several
pollutants, including total hydrocarbons (Method 25A), methane
and ethane (Method 18), volatile HAP's (Method 0030--VOST), semi-
volatile HAP's (Method 0010--modified Method 5), hydrogen
fluoride (Method 26), total fluorides, metals and PM (Method 0012
modified for PM), PM-10 and condensible PM (Methods 201A and
202), particle sizing (Andersen impactor), CO (Method 10), C02
(Method 3A), S02 (Method 6C-- instrument analysis) and NOX
(Method 7E--instrument analysis). Three runs of each sampling
train were conducted on the kiln exhaust. Samples of pulverized
coal were collected daily for sulfur and ash content analyses
(Sampling Point E).
Throughout the one week testing period, an ambient air
sampler was used to sample background PM and PM-10. .The sampler
was placed at a site between the grinding room and the kiln,
adjacent to an unpaved road. Plant personnel provided sufficient
water on the road to limit dust emissions caused by vehicles
passing by the monitor.
III. Process Operations During Testing
The first set of tests was conducted at the grinding room,
which housed all of the screening and grinding operations. The
process rate was calculated using the number of truck loads
dumped into the primary crusher, the average size (in cubic
yards) of a truck load (historical), and the average weight of a
cubic yard of material. The process rate for the grinding room
during testing is shown in Table 1. The grinding room operations
were observed several times during testing. During each
observation, plant personnel indicated that the process was
operating normally.
The second set of tests was conducted at the exhaust stack
for the drying section of Kiln A. The process rates for these
runs were calculated from data that were supplied by the plant,
and are shown in Table 2. The kiln (drying section) typically
-------
TABLE 1. RAW MATERIAL PROCESSING RATES (GRINDING ROOM)
Test date
7-27-93
Time
Daily
Material processed
Mg/hr (tons/hr)
54.0 (59.5)
TABLE 2. BRICK PRODUCTION RATES (KILNS)
Test date
07-28-93
07-29-93
07-30-93
07-31-93
Kiln A production rate, Mg/hr (tons/hr)
6.24 (6.88)
6.07 (6.58)
6.24 (6.88)
6.07 (6.58)
TABLE 3. AVERAGE COAL AND GAS CONSUMPTION RATES
Test date
07-28-93
07-29-93
07-30-93
07-31-93
Kiln A coal consumption, Mg/hr (tons/hr)
0.28 (0.31)
0.29 (0.32)
0.28 (0.31)
0.29 (0.32)
Kiln A gas consumption, m3/hr (f^/hr)
44.74 (1,580)
44.74(1,580)
44.74 (1,580)
44.74(1,580)
TABLE 4. KILN FIRING ZONE TEMPERATURES-DAILY RANGES AND
AVERAGES
Test date
07-28-93
07-29-93
07-30-93
07-31-93
Kiln A firing zone temperature range,
°C(°F)
954-1027 (1750-1880)
963-1027 (1765-1880)
963-1027 (1765-1880)
963-1024 (1765-1875)
Kiln A firing zone average
temperature, °C (°F)
999 (1830)
999 (1830)
999 (1830)
999 (1830)
-------
operates 24 hours per day and no shutdowns or upsets were
reported during the testing.
The third set of tests was conducted at the Kiln A exhaust
stack. The process rates for these runs were calculated from
data that were supplied by the plant, and are shown in Table 2.
Average coal and supplemental natural gas firing rates (provided
by the plant) are shown in Table 3. Operating temperatures for
the kiln were also provided by the plant. Daily kiln (fire zone)
temperature ranges and averages are shown in Table 4. The kiln
typically operates 24 hours per day and no shutdowns or upsets
were reported during the testing.
IV. Conclusions
All processes that were tested operated normally during the
test runs. Therefore, the data obtained should be representative
of a typical coal-fired brick manufacturing plant.
A0108-1\CBI
------- |