United States
Environmental Protection
Agency
                       Office of Radiation Programs
                       Las Vegas Facility
                       PO Box 15027
                       Las Vegas NV 89114
                       ORP LV-78-5
                       June 1978
Radiation
v>EPA
Study of Engineering and
Water Management Practices
that will Minimize the
Infiltration of Precipitation
into Trenches Containing
Radioactive Waste

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                              EPA REVIEW NOTICE
     This report has been reviewed by the EPA and approved for publication.
Approval does not signify that the contents necessarily reflect the vtews and
policies of the EPA, nor does mention of trade names, or commercial products
constitute endorsement or recommendation for use.

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                                   PREFACE


     The Office of Radiation Programs of the U.S.  Environmental  Protection
Agency carries out a national program designed to evaluate population exposure
to ionizing and non-ionizing radiation, and promote the development of controls
necessary to protect the public health and safety.

     This report was prepared to summarize current engineering and water
management practices that could minimize water infiltration from precipitation
into trenches containing buried radioactive waste.

     Problems have occurred at existing commercial radioactive burial sites
located in humid zones due to the formation of leachates containing radioactive
nuclides from the waste materials.  The leachates in turn provide a source,
and in some cases, a driving mechanism for the migration of radioactive
materials from the trenches into the burial site environs.

     The present study examines methods by which burial site containment could
be improved through the application of improved trench cover designs to exist-
ing and future burial sites.  The work is based primarily upon a review of
existing engineering practices as reported in the literature.  The study has
reviewed a number of materials and methods that could be considered for
application at radioactive waste burial sites.

     Readers of this report are encouraged to inform the Office of Radiation
Programs - Las Vegas Facility of any omissions or errors.  Comments or re-
quests for further information are also invited.
                                                           r
                                                             .(
                                                              >~c?
                                        Donald W. Hendricks
                                        Director, Office of
                                      Radiation Programs, LVF

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                Final  Report


  STUDY OF ENGINEERING AND WATER MANAGEMENT
PRACTICES THAT WILL MINIMIZE THE INFILTRATION
  OF PRECIPITATION INTO TRENCHES CONTAINING
             RADIOACTIVE WASTE

          CONTRACT NO. 68-03-2452
                Prepared for:

        Office of Radiation Programs
    U.S.  Environmental  Protection Agency
   National  Environmental  Research Center
               P. 0.  Box 15027
          Las Vegas,  Nevada  89114
                     By:

                SCS Engineers
        4014 Long Beach Boulevard
       Long Beach, California 90807
             September 17, 1977

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                          CONTENTS
                                                           Page
List of Tables                                              iv
ListofFigures                                              v
Acknowledgements                                            vi
1.   Summary and Recommendations                              1
       Summary                                               1
       Recommendations                                       7
          Remedial Steps                                     8
          New or Improved Practices                          8
          Post-Closure Practices                             9
2.   Introduction                                            10
       Background                                           10
       The Problem                                          10
       Waste Types & Characteristics                        11
       Disposal Practices                                   15
       Project Objectives                                   19
       Method of Approach                                   20
3.   Water Balance Considerations at Land Burial Sites       21
       Introduction                                         21
       Water Balance Factors                                21
          Surface Water Inputs                              24
          Groundwater and Waste Moisture Content            24
       Site Factors and Water Balance                       25
          Soil Characteristics                              25
          Topography                                        25
          Hydrology                                         27
          Vegetation                                        27
          Climatology                                       27
       Water Balance                                        27

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CONTENTS (continued)
                                                            Page
4.   Trench Caps and Covers                                   33
       Introduction                                          33
       Routine Trench Covering                               33
       Trench Caps                                           33
          Concrete                                           36
             Application                                     36
             Disadvantages                                   42
             Advantages                                      42
          Asphaltics                                          43
             Application                                     43
             Disadvantages                                   44
             Advantages                                      44
          Soil Cement                                        45
          Synthetic Polymer Membranes                        46
             Types                                           46
             Applications                                    48
          Clay                                               49
             Applications                                    50
             Advantages and Disadvantages                    51
          SoilSealants                                      51
             Applications                                    51
             Disadvantages                                   51
             Advantages                                      51
       Trench Cap Covers                                     52
5.  Alternative Trench and Site Construction Methods         55
        Introduction                                          55
       Trench Construction                                   58
       Trench Siting                                         58
        Diversion  Trenches                                    60
       Trench Liners                                         63
          Advantages and  Disadvantages                       63
       Grout Curtains                                        63
        In-SituEncapsulation                                 66
          Advantages and  Disadvantages                       67
                                i i

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6.   Burial Trench Maintenance and Monitoring                68
       Introduction                                         68
       Surface Maintenance                                  69
       Vegetation and Landscaping                           71
       Monitoring                                           73
          Trench Monitoring Systems                         73
          Monitoring Frequency                              76
Bibliography                                                77
Glossary                                                    85

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                               TABLES
Number                                                       Page
  1      Summary of Concepts for Control  of Water
          Infiltration into Radwaste Disposal  Trenches         2
  2      Projected Average Annual  Low-Level Radwaste
          Generation Volumes                                  15
  3      Total  Volumes and Quantities of Low-Level
          Radioactive Wastes Buried at Commercial
          Sites Through 1975                                  16
  4      Generalized Water Balance Equation at  a
          Waste Disposal  Site                                 23
  5      Water  Transmission under  Saturation                   26
  6      Runoff and Infiltration for a 2.5 cm Rainfall          28
  7      Approximate Seasonal Consumption of Water
          by Example Types of Vegetation                      29
  8      Summary of Example Water  Balance Calculations
          for  Three Areas                                     31
  9      Summary of Trench Caps and Covers                     37
 10      Costs  of Synthetic Polymer Membrane Liners            47
 11      Summary of Trench and Site Construction
          Alternatives                                        56

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                               FIGURES

Number                                                      Page

  1      ERDA Radwaste Disposal Sites                         13

  2      Commercial Radwaste Disposal Sites                   14

  3      Radwaste Disposal Practices                          17

  4      A Typical Waste Disposal Trench and
        Water Balance Pathways                               22

  5      Typical  Trench Completion                            35

  6      Concrete Capping Concepts                            41

  7      Depth of Frost Penetration                           53

  8      Conceptual Completed Low-Level Radwaste
        Disposal Trench                                      54

  9      Horizontal Flow of Water into a Backfilled
        Trench from Topsoil Located Uphill from
        the Trench                                           59

 10      Burial Trench Arrangement to Impede
        Horizontal Water Infiltration through
        the Topsoil                                          61

 11      Radwaste Disposal Trench with Diversion
        Trenches                                             62

 12      Radwaste Disposal Trench with Chemical
        Grout Curtain                                        65

 13      Grass-Covered Radwaste Disposal Site                 72

 14      Cross Section of Moisture Monitoring Cells
        for a Burial Trench                                  75

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                      ACKNOWLEDGEMENTS
     This manual  and supporting literature and case study
reports are the result of cooperation between EPA, industry,
university, and SCS personnel.   The guidance and assistance
of Mr.  Michael  O'Connell, Project Officer, Office of Radiation
Programs, U.S.  EPA, Las Vegas,  Nevada, is gratefully acknow-
ledged.  Keros  Cartwright,  Ph.D., hydrogeologist, provided
consulting assistance to the project team.

     SCS project participants were David E.  Ross, Project
Director, Messrs.  Rodney Marsh  and Thomas Wright, Project
Engineers, and  Dallas Weaver, Ph.D., Technical Advisor.   Mr.
Robert  P. Stearns  served as Reviewing Principal.

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                       CHAPTER 1
              SUMMARY AND RECOMMENDATIONS
SUMMARY
     Low-level  radioactive solid wastes (radwastes)  are gen-
erated by virtually every facet of the nuclear industry and
are conventionally buried in shallow trenches at several  land
disposal  sites.  Burial  practices are straightforward,
involving placement of wastes into the trench, backfilling
with soil, some compacting, and mounding of the surface soil
to minimize ponding.

     Disposal  of low-level radwastes by these procedures  has
generally been effective.  Escape from disposal sites of  low-
level radioactive material that could cause environmental
damage is rare.  However, the few problems that have developed at
several  disposal sites have spawned investigations into methods
for improving  the safety of low-level radwaste disposal practices
For example, water has infiltrated through soil covers  and trench
walls and filled trenches at several sites, and trenches  have
overflowed and leaked into underlying bedrock formations  thus
contaminating  local ground and surface water with measurable
radioactive material.  So far, levels of contamination  from such
incidents have not exceeded safe limits, but suggest potentially
more significant emissions.

     Conventional low-level radwaste disposal practices can be
improved.  In  some instances, improper sites have been  selected,
and operations have been inadequate.  Disposal trenches are
not always water secure, and infiltration and leakage have
occurred.  However, problem situations may be avoided in  the
future and are largely correctable at existing sites.

     The purpose of this project is to identify methods by which
infiltration of water into disposal trenches can be controlled
or eliminated.  Table 1  summarizes a variety of practices and
concepts based on experience and research into the prevention of
water movement at sanitary landfills and other waste disposal
facilities on land, reservoirs, canals, dams, and other situa-
tions where water infiltration control is necessary:
     •  Barriers to minimize or eliminate infiltration  of
        precipitation into radwaste disposal trenches;

     •  Methods to stabilize the surface at disposal sites; and

     •  Procedures to minimize perpetual site care requirements.

                               1

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               TABLE 1.   SUMMARY OF CONCEPTS FOR CONTROL OF WATER INFILTRATION INTO
                                     RADWASTE DISPOSAL TRENCHES
   Concept Description
            Approximate
Expected    Cost/Trench
Longevity3  Installed"
              Reference
                No.
                     Comments
Trench and Site Construction
      Alternatives

Situate disposal site on a
        slope

Situate disposal site on
    level ground

Construct system of berms/
drainage ditches on the
        site
Construct trenches with
   level bottoms

Construct trenches with
   sloped bottoms

Line trench bottom with
permeable soil or other
     material

Construct narrow gravel -
filled diversion trenches
around the entire site
and/or individual
disposal trenches
  NAV
  NA
    NA
    NA
Indefinite  $10/1inear
with        meter of berm
regular     or ditch
maintenance
  NA
  NA
  NA
    NA
    NA
$500-1,000
Indefinite  $100/1inear
with regu-  meter of
lar main-   diversion
tenance     trench
42      Applicable for new trenches only
42      Applicable for new trenches only
                         Should be implemented in all cases
42      Applicable for new trenches only
42      Applicable for new trenches only
42      Applicable for new trenches only
                 36      Applicable for new trenches or  as  a
                         remedial measure

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TABLE 1 (Continued)
Concept Description
Trench and Site Construction
Alternatives
Trench liners







Grout curtains around
entire site and/or
trench periphery








Injection of a slurry
of impermeable material
into each trench to
fill void spaces


Approximate
Expected Cost/Trench Reference
Longevity3 Installed" No. Comments


Varies $40,000 to 28» 39, Applicable for new trenches only.
with mater- 275,000, 75
ial and depending
exposure on liner
conditions; material
at least
5 to 40
years
Variable; Up to 2, 7, 8 Applicable for new trenches or as
grout $70,000 a remedial measure.
curtains depending
for dams on the
and grout
buildings material
have expec- used
ted lives
of at least
10 to 50
years
5 to 50 $140,000 -- Applicable for new trenches or as a
years, to 700,000 remedial measure.
depending depending on
on the the material
filler
material

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TABLE 1 (Continued)
Concept Description
Trench Caps and Covers
Concrete caps (in general)
-thin layer cap (10 cm)
-thick concrete mound
cap (100 cm)
-concrete encapsulation
and cover
Asphaltics
-normal asphalt
concrete (10 cm)
-hydraulic asphalt
-soil asphalt
-catalytically blown
bituminous seal
Soil cement
Expected
Longevity3
at least
40 years

at least
15 years

at least
25 years
Approximate
Cost/Trench Reference
Installed0 No. Comments
see below 36, 52, Applicable for new trenches or as
80, 28 a remedial measure
$ 16,000
$140,000
$500,000
see below 28, 37, Applicable for new trenches or as
39, 55 a remedial measure
$3,600-5,400
$5,400-7,600
$2,300 .
$2,700-3,600°
see below 5, 39, Applicable for new trenches or as
74 a remedial measure.
    -15 to 20 cm layer
     with a bituminous seal
     coal

    -carbonate bonding (15 cm)
$2,300
$2,400

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TABLE 1 (Continued)
Concept Description
Trench Caps and Covers
Synthetic polymer membranes
-butyl rubber

-polyethylene


-polyvinyl chloride


-ethyl ene-propyl ene
diene

-chlorinated
polyethylene

-hypalon

Clay




Expected
Longevity


at least
20 years
at least
5-10
years
at least
5-10
years
at least
5-10
years
at least
5-10
years
at least
10 years
1 ,000 +
years in
absence of
mechanical
damage
Approximate
Cost/Trench
Install edb


$5,000a
$8,000°
$1 ,800-;
$3,500°

$2,300-,
$4,500°

$5,000-,
$7,500°

$4,300->
$6,500°

$4,300-,
$6,500°
$1 ,300
(37)-
$10,000
(35)

Reference
No . Comments

Applicable for new trenches or as
a remedial measure.
JZ?

28, 39,
40

28, 39


28


28


28

1,3, Applicable for new trenches or as a
5, 36, remedial measure.
39, 69,
82


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      TABLE 1 (Continued)
           Concept Description
Expected
Longevity
Approximate
Cost/Trench
Installed
Reference
   No.
Comments
     Trench Caps and Covers
       Soil sealants
at least
5 years
$1,000
and up,
depending
on the
sealant
material
33, 35,      Applicable for new trenches or
86, 87       as a remedial measure.
o>
      a   Expected longevity is the estimated time for the conceptual method to remain intact with
          minimum maintenance.  A minimum of 40 years is considered essential.

      b   Costs approximate for a "typical" trench 100 m long by 15 m wide by 6 m deep.  Costs
          include materials and installation.  The costs do not include normal trench excavation
          and filling or maintenance.  Maintenance costs can vary widely depending on what type
          of trench cap cover is used  (soil, gravel, grass).

      c   NA - not applicable.

      d   Includes a 15 to 30 cm soil cover.

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In general, these concepts have not been applied at radwaste
disposal sites, although they have been proven elsewhere.

     Surface infiltration can be controlled with a multilayer
cover:

     1.  A compacted soil cover over the wastes, mounded;

     2.  An impervious cap of clay, concrete, asphalt,  plastic,
         or similar material ;

     3.  A protecting layer of soil; and

     4.  A 1ayer of gravel .

     Covers of this type would protect the wastes from  surface
infiltration and are themselves protected from exposure to
environmental  extremes and root damage from vegetative  growth.

     Infiltration of precipitation through the surface  soil
between trenches and thence horizontally into the trenches can
be minimized through the use  of berms and drainage ditches to
divert surface runoff; construction of impermeable curtains
or other barriers could be used to inhibit horizontal  water
flow.
     A  series of moisture cells placed in the trench bottom and
below  the soil cover can detect the presence of water in the
trenches.  Any water that has entered a disposal trench can be
accumulated in a sump and removed by pumping via an access pipe
before  it saturates deposited wastes or flows offsite.   If
water  is allowed to remain in contact with the wastes for
more than a few days, it can become contaminated and thus re-
quire  further treatment.  Frequent monitoring and pumping can
avoid  water contamination problems.  Pumping will be necessary
until  any danger of radioactive contamination has passed.

     A properly located, designed, and operated low-level
radwaste disposal site can be essentially water secure  for several
decades, if not centuries.  Such security will require  more
effort'and care than has been committed toward low-level rad-
waste disposal management in the past,and it will not be free.
But,considering the potential damage from inadequate practices,
control of water infiltration is neither infeasible nor pro-
hibitively expensive.

RECOMMENDATIONS

     The following recommendations apply to low-level radwaste
disposal in general.  A specific recommendation may not be
applicable at all sites, but universal application is not the
intent, nor is it expected that any one site would benefit from

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implementation of all  of the recommendations.   Finally,  it
should be noted that these recommendations  are not intended
to be requirements.

     The recommendations are divided into three groups  --
remedial steps that  could be taken at existing sites  and ongoing
burial operations, new or improved practices  that could  be
implemented during the design and operation of future sites,
and post-closure practices.

Remedial Steps

     •  Where not already available, access wells should be
        placed at the  low end of each trench  and any  standing
        water removed.

     t  Trench covers  should be leveled,  the  cover soil  recom-
        pacted, a new  soil mound placed,  and  an impermeable
        cap and cover  added.

     t  Moisture probes should be placed  in each trench  and
        monitored regularly.

     •  A series of  berms and drainage ditches should be con-
        structed and regularly maintained to  handle surface
        runoff and prevent site flooding.

     •  At sites where trenches are leaking or leaking  is  sus-
        pected, or that are underlain by  fractured bedrock,
        grouting should be considered as  a  means to prevent
        offsite movement of radioactive material.

     •  Consideration  should be given to  injection of an imper-
        meable material into trenches where water contact  or
        waste settlement has been or is now a problem.

New or Improved Practices

     t  Greater emphasis should be given  to the site  selection
        aspects of disposal  activities.  Over a span  of  several
        hundred years, leaks are possible at  virtually  any
        site; thus burial activities should be situated
        to minimize the impacts of'such leaks on the
        local and areal environment.  The newer low-level  rad-
        waste burial sites, which were selected after
        relatively extensive site surveys and hydrogeological
        investigations, are generally more  secure than  the  older
        sites.
                              8

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     •  Radwastes  should never be placed in a trench contain-
        ing standing water nor should they be dumped during
        a rainstorm.  The trench should be drained ahead of
        time or a  separate wet-weather trench with covers for
        contingency use provided.

     •  Temporary  berms should be constructed around each open
        trench to  prevent entrance of surface runoff.

     t  Wastes should be compacted as much as possible and,
        to minimize settlement as the organic waste fraction
        decomposes, void spaces filled with granular or other
        sui table material .

     •  Covers should be placed as noted in Remedial Steps,
        above.

     •  Moisture cells should be placed both immediately under
        the mounded cover and in the trench bottom.  Any
        water detected in the trenches should be removed
        immediately.  Immediate removal may avoid further
        treatment  and disposal problems for the infiltrate.

Post-Closure Practices

     •  Vegetative growth over closed trenches should  be
        carefully  controlled or eliminated to prevent  dis-
        ruption of the cover's integrity by root propagation.

     t  Ground and surface water should be monitored regularly;
        soil and vegetation samples from the area should be
        analyzed for possible contaminants.

     •  Site inspections should be conducted regularly,
        especially following any major climatic or geological
        event.

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                          CHAPTER 2

                        INTRODUCTION
BACKGROUND
     In the early days of the Manhattan Project, little thought
was given to radioactive waste disposal;  it was secondary to
the main task at hand.  Solid wastes were usually buried in
the most accessible and convenient vacant place without much
thought for long-term consequences.  Initially, this presented
no problem because of the small waste quantities involved and
the isolated nature of the research facilities.  However, with
the passing of time, nuclear research and production expanded
and wastes accumulated.  The commercialization of nuclear power
and isotope technology led to commercial  waste generation and
the establishment of two types of waste burial facilities -
federal (Atomic Energy Commission (AEC) or Energy, Research and
Development Administration (ERDA)) for wastes generated by
government research and production, and commercial, for wastes
generated by industrial and private use of radioisotopes.  The
commercial sites were limited to low-level (<1 microcurie (uCi)/
ft3 or gal.) radwastes.  The federal government segregated high-
and low-level wastes; most of their attention focused on the
disposal problems of the more dangerous high-level wastes.  Low-
level  waste land burial was not considered particularly
hazardous.

THE PROBLEM

     In November 1973, a group of researchers for the State of
Kentucky identified radioactive tritium (hydrogen -3), cobalt
-60, strontium -89 and -90, cesium -134 and -137, and plutonium
-238 and -239 in the soils and surface waters below the Maxey
Flats low-level radwaste burial site.  A December 1974 report
concluded that the disposal site was responsible for the unusual
offsite radioactivity (46).  At the West Valley, New York low-
level  radwaste burial site, water has been seeping out of two
trenches and running off of the site into some nearby streams.
The runoff contains elevated tritium levels (Richard Cunningham,
57).  The levels of radioactivity in a Clinch River, Tennessee,
tributary creek periodically exceed the maximum permissible EPA
limits  (See  10 CFR 20 and 40 CFR 158 for drinking water regu-
lations).  The radioactive materials are leaching out of
several Holifield National Laboratory, Oak Ridge radioactive
                               10

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waste burial trenches which are flooded by a rising water table
several  months each year (46).

     These and similar problems at the other low-level  radwaste
burial, sites are among the formidable obstacles facing
continued nuclear reactor development.  Safe waste burial
a necessity.  If the leaching of wastes cannot be prevented,
then an  alternate disposal method must be developed; if there
are none, waste generation, and consequently, nuclear techno-
logy development must cease.

     The problems are not insurmountable, however.  Radwaste
burial is similar in principle to many hazardous waste  control
situations.  The disposal technique must be such as to  prevent
any possibility of the hazardous material coming in contact
with any part of the environment which could affect man.  Tradi-
tionally, burial, or more generally land disposal, has  been
considered the best method for achieving this end.  But, as the
recent experiences at Maxey Flats, West Valley, and Holifield
indicate, environmental contamination is still a possibility.

     A basic problem with land burial is water:  rainwater,
surface  runoff, groundwater.   Water, leaking into or percolat-
ing through a burial site, can dissolve certain constituents
of the waste.  As the water percolates out of the site, it
carries  some of these constituents with it.  If the contaminated
water flows into a groundwater aquifer or surface water, it
will contaminate parts of the environment directly affecting  man

     When water attacks radwastes, the resulting leachate can
contain  not only dissolved organics and heavy metals, but also
radioactive material.  This radioactive leachate, because of
its potential carcinogenic and mutagenic properties, is much
more insidious in its effects than other hazardous leachates.
Although such radioactive leachates are in one sense less
hazardous than other toxic leachates because the radioactivity
will eventually decay, the immediate health effects can be much
more devastating.  It should be noted at this point that none
of the radioactively contaminated leachates thus far identified
has had  serious environmental or public health effects; the
leachates have been  low level discharges further diluted in the
environment (Richard Cunningham, 57).  The potential for serious
damage in the future is nonetheless real.

WASTE TYPES AND CHARACTERISTICS

     Every operation involved with radioactive material produces
wastes which either  are, or may be, contaminated with radio-
active isotopes.  To date, nuclear weapons manufacturing has
accounted for 83 percent of the radwastes generated; this is
expected to decrease to 6 percent by the year 2000 (if nuclear
                               11

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power plant construction continues at the predicted rate)
(Gerald H.  Daly,  57).   Most of the remainder of radwastes  is
from power  plants and  associated fuel reprocessing.  A small
fraction of the radwastes comes from hospitals, schools,  and
industries  using  radioisotopes.  The AEC and ERDA have classi-
fied these  wastes as "high-level" and "other" or "low-level."
This report is limited to a discussion of low-level radwastes,
defined as  having a radioactivity of less than or equal  to
lyCi/gal (3.785 liters)  or cubic ft (0.028 cubic meters).

     Physically,  low-level radwastes may range from paper  and
rubber gloves to  a contaminated 25-ton semitrailer (44).
Commercial  burial sites  were originally licensed for low-level
radwastes from hospitals, research facilities, and industry
(68).  However, the burial sites have been used increasingly
for the disposal  of contaminated wastes from the nuclear  power
industry.  The radwastes buried at ERDA sites are wastes
from nuclear weapons manufacturing.

     Weapons-related low-level radwastes, to date, have  totaled
about 1.2 million cu m (43 million cu ft) (Gerald H. Daly,
57).  These wastes are buried in five principal ERDA sites
(Oak Ridge, Tennessee; Los Alamos, New Mexico; Richland,
Washington; Savannah River, South Carolina;  and the Idaho
National Engineering Laboratory (INEL); and  six minor ERDA
sites (Sandia, New Mexico; Amarillo, Texas;  Fernald, Ohio;
Paducah, Kentucky; Portsmouth, Ohio; and the Nevada Test  Site)
(Figure 1).  One  million cu m (36 million cu ft) containing
1.8X10? Ci  have been buried at the five principal sites,
including 740 kg  (1,632  Ib) of plutonium at  INEL and 212  kg
(467 Ib) of plutonium at Richland  (46).  The low-
level radwastes from weapons manufacturing are currently
being generated at a rate of about 37,000 cu m (1.3 million
cu ft) per  year,  a rate  not expected to change significantly
before the  end of the  century (46).

     There  are six commercial burial sites operated by three
private companies - Nuclear Engineering Company (Hanford,
Washington; Beatty, Nevada; Sheffield, Illinois; and Maxey
Flats, Kentucky), Chem Nuclear Systems, Inc. (Barnwell,  South
Carolina),  and Nuclear Fuel Services (West Valley, New York),
(Figure 2).  To date,  258,000 cu m (9.1 million cu ft),  or
about 17 percent  of the  total low-level radioactive wastes
generated,  have been buried at these sites (Gerald H. Daly,
57).  With  the projected increase in nuclear power production,
the commercial sites are expected to contain 94 percent  of the
low-level radwastes by the year 2000 (Gerald H. Daly, 57).
Table 2 presents  the projected average annual volume of  low-
level radwastes through  the year 2000.
                              12

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 1  OAK  RIDGE, TN
 2  LOS  ALAMOS, NM
 3  IDAHO NATIONAL
    ENGINEERING LABS
 4  RICHLAND.WA
 5  SAVANNAH RIVER, SC
 6  SANDIA, NM
 7  AMARILLO, TX
 8  NEVADA TEST SITE
 9  FERNALD, OH
10  PADUCAH, KY
11  PORTSMOUTH, OH
                    Figure 1.   ERDA  radwaste disposal  sites

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1 MOREHEAD,  KY
  (MAXEY FLATS)
2 HANFORD, WA
3 BARNWELL,  SC
4 SHEFFIELD, IL
5 BEATTY, NV
6 WEST VALLEY, NY
                Figure 2.   Commercial  radwaste  disposal  sites

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     TABLE "2.   PROJECTED AVERAGE ANNUAL LOW-LEVEL
            RADWASTE GENERATION VOLUMES (68)
                     (103 cu m/yr)
Type
Fuel cycl
Non-fuel

1976-1980
e waste 57
cycle waste 45
Total 102
1981-1990
300
110
410
1991-2000
1 ,926
311
2,237
     Table 3 presents the total volumes and quantities of
each type of waste buried at the six commercial  sites through
1975.

DISPOSAL PRACTICES

     Essentially all  low-level  radwastes generated in the
United States are buried in trenches.  Typical trench dimen-
sions are about 90 m (300 ft) long by 12 m (40 ft) wide by
6 m  (20 ft) deep, with 6 m (20 ft) between trenches (66).  In
practice, however, trench sizes vary somewhat:  the trenches
at Maxey Flats are 110 m (360 ft) by 21 m (69 ft) by 6 m
(20  ft), while those at West Valley are 180 m (590 ft) long by
6 m  (20 ft) deep (4).  Each trench bottom is designed to be
sloped at about 1 degree from end to end (10).  A stone-filled
sump at the low end of the trench permits collection and
removal of any water that accumulates during filling and after
the  trench is completed.

     The trenches are filled from the high end.   The wastes may
either be dumped randomly or stacked neatly, depending on
their nature and a given site's operational procedures (Figure
3).  Wastes generally arrive at the site in cardboard or
wooden boxes, 55-gal  drums, bulk (for equipment, demolition
wastes, reactor shielding, etc.), or containerized liquid form.
Much of the liquid radwaste is solidified with newspaper and
concrete before disposal.  Increasingly, paper trash and
other loose or boxed  wastes are solidified or encapsulated
in concrete.   One unofficial  estimate is that up to 90
percent of all low-level radwastes being buried  at present are
solidi fied.

     The trenches are backfilled as needed to keep radiation
levels  below federal  government-set limits (100  mRem/hr around
open trenches) (10).   A minimum of approximately one meter of
                              15

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                 TABLE  3 .   TOTAL VOLUMES AND QUANTITIES OF LOW-LEVEL RADIOACTIVE
WASTES BURIED AT COMMERCIAL SITES THROUGH  1975a (Nuclear  Regulatory  Commission,  57)

Beatty,
Site
Nevada
Maxey Flats, Kentucky
Hanford,
Washington
Sheffield, Illinois
West Val
Barnwell
Total
ley, New York0
, South Carolina

Volume
(1000 Cu m)
52
126
12
55
68
60
373
By-product
Material
(1000 Ci)
128
1,912
440
40
538
253
3,311
Source
Material
(1000 Ib)
110
343
17
180
605
283
1,538
SNM
(1000 g)
178
375
33
72
55
343
1,056
Plutonium
(1000 g)
14b
69
13
13
4
0
113







 Numbers rounded to nearest thousand

 Does  not include 1974

GClosed March 1975; does not include 1975

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         K  if
Figure 3.   Radwaste  disposal  practices
                    ! 1

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soil is required to prevent alpha and beta radiation leaks
from the trenches.   The radwastes themselves generally are not
compacted.   Thus, as much as 30 percent of the trench volume
is void space (85).

     As will be noted shortly, lack of compaction can lead to
problems, which are largely avoidable, since the wastes are
compactible and could be reduced in volume by factors of 2 to
10 (4, 12).  As each trench is filled, the surface soil
cover is compacted  and shaped to form an "umbrella" to seal
out groundwater and divert surface water (10).  A standpipe
is left in the sump to facilitate removal of any water which
might collect in the trench bottom.

     Meyer  (60)  has described  what he calls  a typical  trench
life cycle:

     1.   The trench is  excavated from soils  with relatively
         low permeability.

     2.   The trench is  filled  with high porosity, permeable,
         compressible wastes which contain organics and a
         wide range of  chemical  forms.

     3.   The wastes are covered  with an earthen cap, which
         is often more  permeable than the original  pre-
         trench soil  and rock, in effect  creating  an
         infiltration gallery.

     4.   Some of the precipitation which falls on the
         cap infiltrates into  the trench and soaks
         the wastes.

     5.   Leaching of the wastes  begins, aided by the
         presence of organic matter, bacterial action, for-
         mation of  organic  and inorganic acids, and chelat-
         ing agents.

     6.   Trench leachate begins  to (a) migrate downward and
         laterally, because of the hydraulic head imposed
         by the leachate in the  trench and/or (b) to over-
         flow at the land surface in springs and seeps at
         some low point between  the cap and  the undisturbed
         soi 1 .

     7.   As the wastes  are  soaked and leached, they compact,
         undermine  the  cap, cause surface cracking, increase
         infiltration into  the trench, and thereby  increase
         leachate generation.
                               18

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     Furthermore, at the time the six low-level  radwaste
burial  sites were selected, systematic site selection criteria
had not been established.  The geological, geochemical, hydro-
logical, soil, climatological, and other criteria necessary to
ensure  that a given site would retain its radioactivity had not
been clearly formulated.  Tentative site selection criteria
are now being developed, and it is becoming evident that many
of the  sites currently in use are not suitable as radwaste
burial  sites (George D. DeBuchananne, 57).

     With the increase in solidified wastes and  the decrease
in loose, compressible, biodegradable organics,  much of this
settlement/trench cover collapse problem has been overcome.
There may still  be a problem of settlement in the loose backfill
between and around the solidified wastes.

     Among the other potential problems that can be encountered
at radwaste burial sites are gas generation and  nearby new
trench  construction.  Any organic, biodegradable materials
will generate methane and C0£ upon biodegradation.  Unless the
gas is  allowed to escape through the cover cap or vents,
pressure buildup can rupture a cap.  Furthermore, the methane
can present an explosion hazard if allowed to accumulate
in enclosed spaces.  Gas hazards are also minimized by increas-
ing waste solidification, but older burial trenches may still
present problems.

     The construction of new burial trenches can also pose a
threat  to completed trenches because of nearby heavy equip-
ment traffic.  Unless care and planning are devoted to new
trench  construction, it is possible for heavy equipment to
inadvertently drive over completed trenches and  damage covers.
Also, construction of new trenches adjacent to previously
filled  ones may affect the integrity of trench side walls,
depending on soil conditions and separation distance.

PROJECT OBJECTIVES

     Radioactive contaminants are reportedly leaving the
burial  trenches at several disposal sites.  It is generally
conceded that these contaminants are being (or at least may
be) leached out of the buried wastes by infiltrating surface
water from rainfall and runoff.  The principal objective of
this report is to investigate methods for selectively improving
current and future land disposal operations for  low-level
radioactive wastes by:

     1.  Minimizing infiltration of incident rain water
         and surface runoff;

     2.  Maximizing surface stabilization to prevent
         rupture of the trench cap; and
                              19

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     3.   Minimizing perpetual  care  requirements.

Secondary objectives include an investigation  of  methods  to
evaluate the water budget at low-level  radwaste disposal  sites
and an evaluation of the economics  for  implementing  improved
infiltration control practices.

METHOD OF APPROACH

     The core of this report was based  on an extensive search
of the literature.  Because of the  nature of the  problem,
not only literature on radioactive  waste disposal,  but also
literature on solid and hazardous waste disposal,  sanitary
landfills, soil  hydrology, channel  and  reservoir  construction,
seepage and mine drainage control was  reviewed.  The  bibli-
ography at the end of this report is by no means  exhaustive,
but it does present an excellent cross  section of  the
pertinent literature available on these subjects.

     Interviews  with acknowledged experts in related  fields
were used to verify and update information from the  literature
These individuals brought to the preparation of this  report
expertise in radioactive waste disposal, soil  hydrology
dynamics, and water infiltration prevention.  Experience  in
solid waste and  hazardous waste disposal was used  to  relate
and evaluate all of the concepts and suggestions  from these
sources.
                              20

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                           CHAPTER 3

                WATER BALANCE CONSIDERATIONS AT
                       LAND BURIAL SITES
INTRODUCTION

     The various physical, chemical, and biological  processes
that occur within a land disposal  trench produce compounds
that are susceptible to solution or suspension in water perco-
lating through the disposed wastes.  This percolating water
containing contaminants derived from the solid waste is
leachate.  The volume of leachate  produced at any particular
site is dependent on many factors  but generally is determined
by surface water infiltration and/or interception of ground-
water.  The relationship between precipitation/groundwater
and leachate generation is not necessarily linear, nor does
the presence of precipitation/groundwater necessarily result
in leachate.  Leachate generation  is more directly related to
the quantity of water which actually reaches  the buried waste.
The quantity of water, in turn, depends not only on  precipita-
tion but also on such factors as the surface  and subsurface
conditions and climatological characteristics in the area.
Water balance concepts have been developed to assess the
potential leachate problem for a given area, in light of the
variety of factors influencing leachate production.   The
usefulness of water bal'ance in regard to radwaste disposal
sites is twofold:  (1) water balance evaluations can be used
to help evaluate a candidate site's suitability in terms of
leachate generation potential; and (2) water  balance assess-
ments can help establish the extent of any infiltration
problem which might exist at a site in use and thus  help
determine what type(s) of controls, if any, are necessary.

WATER BALANCE FACTORS

     Water balance is based principally upon  the relationships
among precipitation, evapotranspiration, surface runoff, and
soil moisture storage.  Also, regional  geological factors,
such as the site's location with respect to recharge and dis-
charge areas, must be known to properly assess a site's water
balance.  Figure 4 shows a schematic of a typical waste
disposal trench and the various water pathways available.
Table 4 presents the equations relating the various  water
balance terms.
                              21

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                                     PRECIPITATION
EVAPOTRANSPIRATION
                                                    EVAPOTRANSPIRATION
                                              SURFACE
                                              RUN-OFF
                                                         COMPACTED
                                                        SOIL COVER
                                                        LOW-LEVEL
                                                       RADIOACTIVE
                                                         WASTES
                                      LEACHATE
                POSSIBLE
               GROUNDWATER—\
                CONTOURS    )
              Figure  4.   A typical waste disposal  trench
                          and  water balance pathways.
                                    22

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         TABLE 4.  GENERALIZED WATER BALANCE EQUATION
                 AT A WASTE DISPOSAL SITE (46)
where
and :
where
wl
w
w
w
I
R
E
W
 SR
          W
           GW
                         W
                          IR
R
SR
GW
'IR
              Input water from precipitation
              Input water from surrounding surface runoff
              Input water from groundwater
              Input water from irrigation
              Percolation
              Surface runoff
              Evapotranspiration
                                       W
          Ss = Change in moisture storage in soil
           R = Change in moisture storage in solid waste
          LG = Leachate flow to groundwater
          LS = Leachate flow to surface waters
          Wn = Water contributed by waste decomposition
                               23

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Surface Hater Inputs

     The principal  water source at most burial  sites  is  pre-
cipitation (WR).   Irrigation water (WIR)  can also be  a signifi-
cant source,  if the closed trenches have  a vegetative cover
which must be maintained by artificial  means.   In fact,  irri-
gation has been implicated as a primary leachate source  in
semi-arid areas,  where rainfall is insufficient to produce
much leachate (22).  Vegetation will  be discussed later.   At
this point it should be noted that leachate from radwaste
disposal sites is a sufficiently serious  problem to prohibit
irrigation, if such added water appears likely  to increase the
leachate production potential.   The only  other  likely water
source is site flooding (W$R).   Given proper site selection,
flooding is a remote possibility; it  is mentioned only because
it happened at the INEL disposal site (Carl Kuhlman,  57).

     Water applied to the surface of  a  burial  site has four
possible destinies:  evapotranspiration (E), runoff (R),
percolation (I),  and retention  (Ss).   Evapotranspiration  is
the combination of evaporation  from the soil and transpira-
tion by the vegetative cover.  Transpiration is usually  the
greater of the two (22).  Surface runoff  is that fraction of
the added water which is lost to overland flow  before it  has
a chance to infiltrate.  Retention is the fraction of the
water that is retained by the soil.  The  total  amount of  water
that can be stored by a given soil is referred  to as  its  field
capacity and  consists of two components - hygroscopic water
(zero soil moisture to the wilting point) and  available  water
(the wilting  point to field capacity).   Percolation water is
that fraction of the soil moisture which  exceeds the  field
capacity; it  is this fraction which is  responsible for saturat-
ing wastes in trenches and causing leaching.

Groundwater and Waste Moisture  Content

     Most water balance discussions dismiss groundwater  (WQ^)
and the initial moisture content of the wastes  (Wo) as negligible
relative to precipitation.  There are exceptions, however.
The groundwater table at the Holifield  low-level radwaste
disposal site rises periodically and  floods several disposal
trenches for  a few months; radioactive  material leaches  out of
the wastes during these periods and contaminates the  nearby
Clinch River.  To date, this is the only  reported incident of
leachate directly related to groundwater  infiltration.

     Much of  the low-level radwaste is  metal,  plastic, concrete,
or other material with virtually no free  moisture.  Most  liquid
wastes are encapsulated; some wet wastes, such  as filter  sludges,
are sealed in steel drums before disposal.  Disposal  trenches
full of these drums could be a  major  leachate  source  if  the
drums rupture due to corrosion.  Several  ERDA  low-level  radwaste
                              24

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disposal sites are presently exhuming drums to encapsulate the
wastes  (80).

SITE  FACTORS AND WATER BALANCE

      Precipitation, groundwater, irrigation, soil moisture,
evapotranspiration, runoff, retention, and percolation constitute
a site's water budget.  In addition, there are a number of
variables which can affect a site's water budget and thus
influence the quantity of leachate produced.  These variables
include site characteristics (soil types, topography, hydrology,
ecology, meteorology), waste characteristics, waste disposal
practices, and trench and site construction and management.

      Site characteristics are perhaps the most important
variables.  It is conceivable that site characteristics could
be such that no leachate would ever be produced, regardless of
how poorly controlled the other variables might be (as in
certain arid regions where annual rainfall seldom exceeds a
few millimeters).  It is sometimes possible to adjust these other
variables to overcome otherwise prohibitive site characteristics,
but ultimately, the natural site characteristics will determine,
to a  large degree, how much leachate a disposal trench can
produce.

Soil  Characteristics

     The three soil characteristics  which most strongly
influence the water budget are (1)  water  intake (infiltration),
(2)  hydraulic conductivity,  and  (3)  evaporation.   Water  intake
is influenced by the  amount of water applied and surface con-
dition.  Hydraulic conductivity  (under saturated conditions)
is influenced by particle  size,  compaction,  aggregation,
organic matter content,  fracturing,  etc.   Evaporation is
influenced by water availability,  temperature,  wind speed,
and  surface conditions.   Soils with  small  particles (clays,
silts) have a low hydraulic conductivity;  large particle soils
(sands) have a high hydraulic  conductivity and  poor water
retention properties.   This relationship  is  shown quantitatively
in Table 5.

Topography

     Topography most  strongly  affects  runoff both onto  and off
of a  disposal  site.  A site situated on a hillside  would  lose
more  incident precipitation to runoff  than would a  valley
site,  which might actually gain  water  from upstream runoff.
For  sites on a slope,  steeper  slopes have greater runoffs.
As runoff increases,  the amount  of water  available  for  in-
filtration decreases.   The potential  for  local  soils  replaced
as trench cover to erode and  form  gullies  is also influenced
by topography at the  site.   Such  erosion  may disrupt  the
                              25

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          TABLE 5.    WATER TRANSMISSION UNDER SATURATION (82)
           Soil  description
 Hydraulic3
conductivity
   cm/sec
                                                     Hourly transmitted
                                                           volume
                                                           m3/ha
Well -graded gravels or gravel-
  sands, no fines
   > 10
                                        ~
                                                       > 3.6 x 10
Poorly-graded gravels or gravel-
  sands, little or no fines
   > 10
                                                       > 3.6 x 10
Silty gravels, gravel -sand-silt
  mixtures
   ~       .
10~J to 10"°
                                                             .             .
                                                     3.6 x NT to 3.6 x 10"'
Clayey gravels, gravel -sand-
  clay mixtures
Well -graded sands or gravelly
  sands, little or no fines
   fi       „
10"° to 10~°
   > 10
                                         3
                                        "
                                                              , .            ,
                                                     3.6 x 10"' to 3.6 x 10
                                                       > 3.6 x 10
Poorly-graded sands or gravelly
  sands, little or no fines

Silty sands, sand-silt mixtures

Clayey sands, sand-clay
  mixtures
        ,
   > 10

10"3 to 10"5
10"° to 10
                                            a
                                           ~°
                                                       > 3.6 x 10

                                                     3.6 x 102 to 3.6 x 10"1
                                                     3.6 x  10"' to 3.6 x 10
Inorganic silts, very fine
  sands, rock flour, silty or
  clayey fine sands, clayey
  silts with slight plasticity

Inorganic silts and organic
  silts of low plasticity

Inorganic silts, micaceous or
  diatomaceous fine sandy or
  silty soils, elastic silts

Inorganic clays of high
  plasticity

Inorganic clays of medium to
  high plasticity, organic silts

Inorganic clays of low to medium
  plasticity, gravelly clays,
  silty clays-, sandy clays *
  lean clays
                                            K
                                           "°
10   to 10
   ,       fi
10   to 10"°
   ,       fi
10   to 10
   AS
10"° to 10
   fi       o
10~° to 10"°
   AS
10"° to 10"°
                                                      3.6 x  10  to 3.6 x 10
                                                              ,             -,
                                                      3.6  x  10* to 3.6 x 10"'
                                                              ,              ,
                                                      3.6  x  10   to  3.6 x  10"
                                                      3.6  x  10"   to  3.6 x 10
                                                               -t             7
                                                      3.6 x  10"' to 3.6 x 10"J
                                                      3.6  x  10"'  to  3.6 x IP
aAssumes that soils are saturated  and  uniform,
 and that sufficient water is  available
                                   26

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integrity of trenchcaps.   Table 6 gives typical  runoff and
infiltration characteristics for different topographical
conditions.

Hydrology

     Hydrology is the study of water in natural  systems.   Such
study includes consideration of groundwater location,  quantity,
and movement and the hydraulic characteristics of the  soil
and the disposal strata.   Characterization of the hydrological
regimen for site selection will preclude groundwater interr
ception of the disposal  trenches throughout seasonal variations
or intense periods of precipitation.  USGS recommended site
selection criteria include stipulations that piezometric  levels
be several meters below the burial  site (68).  The site's
hydrological system, especially the groundwater, will  play  a
major role in determining the pathways available to any
leachates emanating from  the fill.

Vegetation

      Vegetative  cover at  a  disposal  site  can  influence runoff,
infiltration,  and  evapotranspiration.   Table  6  demonstrates
how  vegetation  decreases  runoff  under  all  soil  and  slope
conditions.   Vegetation  also  increases  infiltration by provid-
ing  channels  for water flow into the  soil.   However,  vegeta-
tion  does consume  large  quantities  of  soil  moisture   (Table
7),  and  this,  in turn, increases evapotranspiration.   Vegeta-
tion  can  also  prevent site  erosion,  but long-rooted flora may
intercept the  trenches and  carry radioactive  material  to the
surface  (51).

C1imatology

      Climatology includes  precipitation  and  those  weather
factors  which  affect evapotranspiration or  infiltration.  Pre-
cipitation  is  the  major  water  source  at virtually  all  disposal
sites.   The quantities and  seasonality of the precipitation
strongly  influence leachate generation:   125  cm of rainfall
annually  is  more likely  to  lead  to  leaching  than  is 10 cm
annually; 100  cm yearly  falling  in  one month  will  have a diffe-
rent  impact than 8 cm monthly  for  12  months.  The  relative
humidity  of the air above  the  site  will  affect  evaporation
rates; dry  air  favors  increased  evaporation.  Freezing tempera-
tures prevent  infiltration  during  the  winter, but  may disrupt
natural  or  artificial  infiltration  barriers.

WATER BALANCE

      Several  mathematical  models have  been  prepared incorporat-
ing  water components and  site  characteristics (22,  79, 82).
These models  can be used  to predict the percolation of water
                               27

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                                       TABLE   6 .   RUNOFF AND  INFILTRATION  FOR
                                               A 2.5  cm  RAINFALL  (82)
ro
00

Surface
Condition
Cover Crop
(Pasture or
meadow)
Flat
Rolling
Hilly
Cultivated
(no vegeta-
tion, not
compacted)
Flat
Rolling
Hilly
Rational Runoff
Slope Coefficient.
% Sandy
loam

0- 5 0.05-0.
5-10 0.10-0.
10-30 0.15-0.

0- 5 0.30
5-10 0.40
10-30 0.52
Clay or Clay
silt loam

10 0.30 0.40
16 0.36 0.55
22 0.42 0.66

0.50 0.60
0.60 0.70
0.72 0.82
Sandy
loam

25.7
41
56.3

76.7
102.5
132.5
Runoff (m3/ha)
Clay or Clay
silt loam

77.1 102.5
91.1 141.0
107.2 155.1

127.8 59.2
153.2 179.5
184.2 209.6
Infi
Sandy
loam

230.3
215.3
199.3

179.5
153.2
123.1
Itration (m
Clay or
silt loam

179.5
163.6
148.5

127.8
102.5
71.7
/ha)a
Clay

153.2
114.7
102.5

102.5
76.7
46.1

       Hydraulic movement directed downward

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TABLE 7.  APPROXIMATE SEASONAL CONSUMPTION OF WATER
        BY EXAMPLE TYPES OF VEGETATION (82)
                                             mm

     Coniferous trees                      102-229

     Deciduous trees                       177-254

     Potatoes                              177-280

     Rye                                   >457

     Wheat                                 509-560

     Grapes                                >_152

     Corn                                  509-1910

     Oats                                  711-1020

     Meadow grass                          560-1525

     Lucern grass                          660-1400
                           29

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into disposal trenches.  Fenn, e_t aj_.  (22) actually calculated
water balances on a monthly basis for case study (nonradio-
active) municipal refuse disposal sites in Cincinnati, Orlando,
and Los Angeles.  The calculations included actual  and
potential evapotranspiration,  precipitation, surface turn-off,
as well as infiltration, soil  moisture storage, and changes in
soil moisture storage.  Historical climatological  data was
used as a basis on which to calculate expected leachate
generation rates.  Table 8 summarizes the results  of these
calculations.  Similar calculations could be employed to
determine the potential for leachate production at any site.

     Radwaste characteristics, burial  practices, and site
management method influence percolation and leachate genera-
tion.  Dry or anhydrous wastes will take longer to begin
leaching than saturated wastes.  Wastes sealed in  steel drums
or concrete will not leach until the casings begin to corrode
and/or disintegrate.  Radwaste characteristics will have
little direct impact on percolation if the wastes  are loosely
packed in the trenches.  However, decomposition of organic
wastes can produce gas that may, in turn, affect the trench
soil or membrane cover.

     Current radwaste burial practices were discussed in
Chapter 2.  Many of the more serious radionuclide  migration
problems could possibly have been prevented with better place-
ment practices.  As the photographs in Figure 1 indicate, under
past practices wastes remained in water-filled trenches for
some time.  Although now largely controlled, this  is still a
potential problem area and could be overcome by more efficient
trench pumping operations and/or diversion of off-site runoff.
At the very least, if there is a possibility that  a trench
may accumulate standing water, any exposed wastes  could be
covered to inhibit radwaste-water contact.

     Another problem is the lack of waste compaction.  As
noted, filled trenches may be  as much as 30 percent void space
(68).  This allows water to collect in a trench to such an
extent that the wastes are often sitting in water.   Tech-
nologies currently exist which could reduce the volume of
radwastes by a factor of about 2.5, minimizing the problem
(64).  Compaction would help inhibit the settlement and
cover-undermining disc'ussed in Chapter 1.  Trench  life and
disposal site life could be extended by compacting the low-
level radwastes.

     Compaction is not without problems.  Aside from the
added costs, there is increased risk of exposure to site
personnel engaged in the disposal and compaction operations
because of closer and longer contact with unshielded radwastes
in open trenches.  Shielding and shorter working periods could
                               30

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                           TABLE  8.  SUMMARY OF EXAMPLE WATER BALANCE CALCULATIONS
                                           FOR THREE AREAS9  (22)


Mean
annual
precipi-
tation
Location (mm)


Mean
annual
runoff
(mm)



Mean annual
infiltration
(mm)


Annual mean
actual evapo-
transpi ration
(mm)



Mean annual
percolation
(mm)

Time
of first
appearance
of leachate
(yrs)
Average
annual
leachate
quantity
expected
(liters?
Cincinnati, Ohio
1,025
154
872
658
213
11
40
Orlando, Florida     1,342
            100
          1,243
              1,172
               70
             15
            30
Los Angeles,
  California
  378
 44
334
334
   Not specifically related  to  existing radwaste burial  sites.
                                               5    2
   Landfill  areas  assumed:   Cincinnati  -  2 xlO c m
                            Orlando     -  4 x 101 m2
                            Los Angeles -  5 x 10  m2

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probably overcome this objection.   Another  possible  solution
to both the hazards and the compaction problem is  encapsulation
of the radwastes before disposal.   Although beyond the  scope
of this study, encapsulation does  appear to avoid  many  of the
problems which plague current disposal operations.

     When filled, each trench is  designed to be covered with
an umbrella shaped cap to encourage runoff  of the  trench
surface.  There are some advantages to placing disposal sites
on slopes to discourage surface ponding and encourage  runoff;
this requires some sort of upslope ditch or berm to  prevent
the upslope runoff from draining  into the disposal site.

     Ultimately, the entire problem revolves around  surface
infiltration control.  If no water percolates into the
trenches, no hazardous leachate will  percolate out.   While
easy to state in concept, such control is not so easy  to
accomplish in the field.  A variety of barriers is available
to prevent infiltration, but none  is  universally applicable,
and all have serious flaws under  some conditions.   There have
been few, if any, long-term (i.e.,  hundreds of years)  studies
done on these barriers, so their  lifetimes  are largely
conjectural.  However, proper coordination  of barrier(s) and
site conditions does hold promise  as  a leachate control method.
The different types of barriers available and their
advantages and disadvantages are  discussed  in the  following
chapters.
                               32

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                          CHAPTER 4

                    TRENCH CAPS AND COVERS

INTRODUCTION

     Meyer (60), in his description of a typical  low-level  rad-
waste disposal trench "life cycle" (discussed in  Chapter 1),
attributes the presence of water in trenches to rainwater infil-
tration through the trench cap.  While this may not always  be
true, infiltration through the cap must be considered a serious
potential  pathway:  a highly permeable cap will pass water
readily.  Consequently, it would be beneficial  to consider
concepts by which the trench caps may be made impermeable to
infiltrating rain water.

     Before discussing the concepts in depth, it  should be  noted
that the integrity of many types of caps is dependent on the
material in the trench.  Meyer (60) describes virtual cap
collapse due to settlement in the trench; this  would occur  with
consolidation and decomposition of uncompacted  paper and
other organic,  biodegradable wastes.  Much  of  the  radioactive
waste in  place  at  Maxey Flats,  for example,  is paper (60).
Researchers  (4,  68)  have  indicated that  compaction  of  low-
level radwastes  in the  trenches  is, at  best, poor  and  in some
cases may  be  absent  altogether.   Under  such  conditions  settle-
ment is virtually  inevitable,  and  the probability  of trench
cover collapse  increases  greatly.  When  the  cover  collapses,
any water  infiltration  control methods  previously  implemented
become  superfluous.

     Essentially, there are two ways to  avoid this  problem:
1) construct a  trench cap of inherent structural  integrity, or
2) bury only wel1-compacted or nonsettl eabl e wastes.  The first
method calls for  a rigid  trench cap, such as a roof, steel
sheet, or reinforced concrete.  However, this approach has
several disadvantages:

     •  The prohibitive costs of materials  and construction,

     t  The questionable  ability of such covers to  last
        several decades because of corrosion or structural
        failure,  and

     •  The possibly difficult access to the wastes in the
        event removal should become necessary.
                               33

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 Advantages  include:

      •  Greatly decreased  susceptibility  to  damage  from
         vegetation,  erosion,  or  nearby  waste-handling
         activities;  and

      •  Positive monitoring  control.

      The second option  involves  the  nature  of  the wastes  them-
 selves.   Much low-level  radwaste (e.g., demolition  rubble,
 concrete-encapsulated  and/or  metallic  wastes)  has the  necessary
 structural  stability to  support  a  trench  cap,  especially  in  the
 absence  of  appreciable  corrosion or  water damage  from  infiltra-
 tion.   Biodegradable organic  wastes  (paper,  boxes,  carcasses,
 protective  clothing, etc.) would require  some  sort  of  baling or
 dense compaction before  disposal to  inhibit  settling.   Even
 with the best compaction methods currently  available,  some
 settlement  is-likely,  but  uncompacted  radwastes  could  settle by
 as much  as  20 to 30  percent,  assuming  all void space  is
 eventually  filled by settlement.

ROUTINE TRENCH COVERING

      As  part of all  trench completion  procedures, approximately
 the top  one meter of trench  space  would be  filled with excavated
 soil,  compacted, mounded,  and sloped  (Figure 5).  It  is doubt-
 ful that mechanical  compaction will  return  the excavated  soil
 to its original, undisturbed  density,  but compaction  will  help
 minimize infiltration.   Mounding and  sloping is  necessary  to
 facilitate  runoff from  the trench  covers; the  optimum  slope
 is about 5  percent.   A  lesser slope  could soon settle  and  create
 depressions for ponding  of water,  while a greater slope may  be
 subject  to  erosion by  surface runoff.

TRENCH CAPS

     Frequently the soil  of the trench cover is more permeable
than the undisturbed  soil between the trenches, even after
compaction.   Under certain circumstances,  soil  can  be  com-
pacted to a  lower permeability than the undisturbed  soil,
especially for porous soils.   For most soils, however,  the
trench cover soil is  invariably more  permeable.  Consequently,
a further barrier may be necessary to completely inhibit
surface water infiltration.  This barrier, or cap,  should  be
placed over  the soil  cover.  There are a variety of  materials
available which can provide a  relatively impermeable trench  cap,
but not all  are equally suited for low-level  radwaste  disposal
trenches.  The materials  discussed  here are  concrete,  asphalt,
soil cement, synthetic  polymer membranes,  clay, and  various
combinations of these materials with  each  other and  the soil.
                                34

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             COMPACTED SOIL
             FROM THE TRENCH
             EXCAVATION
Figure  5.   Typical  trench completion
                      35

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Table 9 lists these materials with a summary of their
characteristics.   It should be noted that these cap concepts
are largely untested in regard to radwaste disposal.   Some of
the concepts are almost hypothetical,  in that no large-scale
testing has been performed with any waste.  They are  pre-
sented because they are potentially valid concepts, not because
they are proven solutions.

     In evaluating and comparing the various trench cap concepts
several generalizations and assumptions are made.   It is
unlikely that any burial  system can be kept intact and water-
tight for thousands of years, time enough for total decay of
some low-level radwaste.    However, perpetual maintenance may
be unnecessary.  If a burial  trench can be kept tight for at
least 40 to 50 years, most short-lived isotopes will  have
decayed, and infiltration will result  only in the  slow release
of any radioactive isotopes remaining.  Consequently, many
experts consider that a burial trench  concept life of 40 to 50
years is sufficient.

     Concept costs given  are  for materials and installation
costs above regular trench construction costs.  They  do not
include backfilling, compacting, or maintenance.  Maintenance
costs can add significantly to the overall costs of some con-
cepts, but these costs can be controlled through the  proper
selection of final cover  materials.

Concrete

     The usefulness .of concrete as a water barrier is well
documented.  Concrete structures are expected to be watertight
and, on the whole, they have  performed well.  Countless dams,
canals, and water tanks are constructed of concrete.   Properly
designed and bui 11concrete canal linings have been known to
last 40 years or longer (52).  A concrete cap is probably the
strongest structurally of the cap types under consideration
here.

Application--

     In practice, a concrete  cap could be applied  several ways
(Figure 6); the simplest  is to lay a concrete cap  several
inches deep over the compacted soil mound.  Given  the expense
of installing concrete (about $9/yd2 for a 4-in layer, adjusted
to January 1977 (28)), this is the least expensive application,
as it uses the least amount of concrete, but it is also the most
susceptible to damage from either waste or soil settling or
freeze/thaw.  Frost heave or  freeze/thaw damage possibly could
be averted by covering the cap with a  layer of soil or gravel,
while damage due to settlement of buried wastes could be
                                36

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                             TABLE  9.   SUMMARY OF TRENCH CAPS AND COVERS'
Trench Cap
Description
Concrete (in general)

Advantages
Longevity.
Structural strength.

Di
Expense
to crac
sadvantages
Susceptible
king due to
Expected
Longevity
40+ years
Approximate
Cost/Trench,
Installed13

Reference
No.
52
36, 8D
- 10 cm (4-in)  layer
  100 cm (40-in)
  layer extending
  below the top of
  the trench

  Concrete encapsu-
  lation/trench
  •filling/cover
                       Proven  success  as  a
                       water barrier and
                       radwaste  container.
Cost, as compared
to other concrete
caps.

Less susceptible to
cracking than the
thin concrete layer.
Least damageable of
the concrete caps.
                      settling or frost heave
                      of buried waste and/or
                      soil cap in certain en-
                      vironments; chemical
                      attack in acid, alka-
                      line, and high-sulfate
                      soils; erosion due to
                      freeze/thaw cycles.
                      Difficulty of access
                      in the event that relo-
                      cation of wastes be-
                      comes necessary.
Most expensive con-
crete cap.
Wastes are least
accessible
                                     $16,200
                                    $140,000
$500,000
                28

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       TABLE 9   (continued)
Trench Cap
Description
Advantages
Disadvantages
Expected
Longevity
Approximate
Cost/Trench,
Installed^
Reference
No.
       Asphaltics (in
       general)
Ease of placement.
Cost.
Proven worth as rad-
waste encapsulation
material.
Versatility.
CJ
00
       - Normal  asphalt
         concrete,  4-in
         layer

       - Hydraulic  asphalt
         concrete,  4-in
         layer

       - Soil  asphalt
Decreased perme-
ability over normal
asphalt concrete.

Cost.
Flexibility.
         Catalytically
         blown bituminous
         seal  (0.5-1  cm)
Flexibility.
Susceptible to chem-
ical degradation.
Photosensitive.
Susceptible to
cracking due to
settling or frost
heave.
Difficulty of access
in the event that
removal of the
wastes becomes
necessary.
15+ years
More difficult to
apply than normal
asphalt concrete.

Increased perme-
ability.
Questionable quality
control in installa-
tion.
Temperature sensitive.

Questionable homogen-
eity of cap.
Become brittle at low
temperatures.
Little structural
strength.
28, 37, 55
                                                            $3,600-
                                                             5,400
              $5,400-
               7,600
              $2,250
                                                      39
    39
    39
              $2,700-
               3,600b
    39

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       TABLE  9  (continued)
OJ
IO
Trench Cap
Description Advantages
Soil Cement Costs.
Disadvantages
Variable permeabili-
Expected
Longevity
25+ years
Approximate
Cost/Trench,
Installed b

Reference
No-
74
15-20 cm (6-8 in)
layer with a
bituminous seal
coat

Carbonate bonding
(15 cm (6-in)
layer)
         Synthetic polymer
         membranes
         - Butyl rubber

         - Polyethylene
         - Polyvinyl
           chloride
                              Proven worth as a
                              water barrier.
                              More flexible than
                              concrete.
                              Works better in
                              heavy clay soils
                              than normal  soil
                              cement.
                     Very permeable.

                     Cost
                     Strength,  chemical
                     resistance.
                     Impermeability.
                                            ties.
                                            Susceptible to chem-
                                            ical  attack and
                                            freeze/thaw erosion.
                                            Reduced longevity
                                            compared to concrete.
Cost.

Poor quality.
Poor weatherability.
Poor puncture resist-
ance.
Stability.
Temperature sensi-
tive.
20+ years

10+ years



10+ years
                                                                                          $2,250
                                     $2,400
$5,000-
 7,700C
$1,800-
 3.400C
$2,300-
 4,500C
                                                     39
    39

28, 39, 40



28, 39

-------
       TABLE 9   (continued)
-P.
o

Trench Cap
Description
- Ethyl ene-propy-
lene diene

- Chlorinated
polyethylene

- Hypalon



Clay




Advantages
Resistant to weather-
ing and temperature
deterioration.

- - see ethyl ene propyl

Resistant to chemical
attack, puncture,
temperature deteri-
oration.
Proven success as a
water barrier.
High impermeability.

Expected
Disadvantages Longevity
Poor chemical resist-
ance.


ene diene - -

Cost.
Low Tensile Strength.


Susceptibility to 1,000+
mechanical damage years
(animals, plant
Approximate
Cost/Trench,
Installed b
$4,900-
7,600C


$4,300-
6,300C

$4,300-
6,300C

$1,300
$10,000+


Reference
No.
28



28


28


39
36
1, 36
       Soil  sealants
                              Self-sealing  proper-
                              ties.
                              Flexible.
Relatively low
cost.  Ease of
application.
roots).
Susceptibility to
chemical deteriora-
tion.
Must be kept wet.

Lack of control  over
polymerization or
sealing process.
Subject to chemical
and biological attack.
unknown     $l,100+c    33,  35,
                        86,  87
       a  All  trench caps  can  be used  either as  remedial  measures  on  old  trenches  or  on new trenches.

       b  Costs  approximate  for  a trench 100 m long by 15 m wide  by 6 m deep.   Includes only the materials
          and  installation of  the cap  itself.

       c  Includes  a 15  to 30  cm soil  cover.

-------
  COMPACTED
    SOIL
  RADIOACTIVE /,
THIN CAP OVER
COMPACTED SOIL
   COVERING
 CONCRETE CAP, NO
MOUNDED SOIL COVER
                               /^RADIOACTIVE
                               r*
CONCRETE USED TO FILL
VOID SPACE AND CAP THE
  TRENCH (NO SOIL)
                  Figure  6.   Concrete capping concepts.

-------
controlled by efficient waste and cover compaction (although
some repair to the concrete cap may be necessary if
settlement is severe).

     The second type of concrete cap would be much less
susceptible to mechanical damage due to frost heave or settling,
although the exposed concrete surface is susceptible to chipping
and flaking from freeze/thaw cycles.  Because the quantity of
concrete is increased, the overall cost for capping the trench
is increased likewise (Table 9).

     The third type of cap is actually a combination of void-
filler and cap.  The concrete is poured on top of the wastes,
filling voids and essentially encapsulating the wastes.  The
trench is filled with concrete, and the surface mounded.
Structually, only freeze/thaw, which can be largely overcome
by covering the concrete with soil or gravel, presents any
problems to this cap (see Chapter 6).  This concept does have
the disadvantage of requiring a complete, filled trench for
a homogenous concrete cover; filling the trench in sections
creates joints which are more prone to failure than a contiguous
cover.  Leaving the trench open until completely filled may
violate radwaste disposal safety regulations (100 m Rem/hr
(10)).  This concept is also the most expensive by a wide
margi n (Table 9).

Di sadvantages--

     Concrete is easily the most expensive of the capping
materials under discussion (28).  It is completely inflexible
and will tend to crack under certain kinds of environmental
stress.  Low temperatures can freeze interstitial water in
the concrete, expanding and cracking it.  Concrete is
susceptible to chemical attack under both acid or alkaline
conditions, while concrete exposed to soils containing
sulfates will gradually dissolve (36).

     In one sense, the permanence of concrete may become a
problem.  If, in the future, it becomes necessary to remove
any transuranic radwastes and recover or relocate them, a
concrete cap would be a liability; removal would be costly
and time consuming.

Advantages--

     On the positive side, concrete has a long record of
successful  application as a watertight barrier with a long
lifetime.   A variety of concrete casks.and boxes has been and
is being used at several  low-level radwaste disposal  sites
(Los Alamos, Oak Ridge, Hanford, Savannah River) to store
Plutonium and other transuranic wastes (80).   These casks
and boxes  are usually buried in burial trenches, and, to date,
                               42

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they have held up well  with no leakage or mechanical  failure
reported.  At slightly  higher cost,  concrete can  be im-
pregnated with one of several polymers and made even  more
impermeable.   A properly designed and constructed concrete
trench cap, protected from the environment, should, with
minimum maintenance, be able to provide an effective  barrier
to water infiltration for at least several decades, based
on the apparent success of concrete  dams, for example.

Asphaltics

     Asphaltics  include a variety of  natural or  refined  liquid,
semi-sol id,or solid  hydrocarbon mixtures.  Asphaltic linings
are used regularly  in canals and reservoirs, and asphaltic
patches  are used  to  repair cracks in  concrete or other  linings.
There are  several types of asphaltic  materials which could be
used as  a  trench  cap - asphalt concrete,  hydraulic asphalt
concrete,  soil asphalt, and  catalytically  blown  bituminous seals.

Applicat ions--

     Normally, asphalt concrete  is applied as a  heated  mixture
of asphalt, aggregate, and filler; hydraulic asphalt concrete
differs  in the asphalt content and aggregate gradation.   Both
are mixed  and laid  using  the same equipment and  techniques,
although the  hydraulic asphalt concrete  is somewhat more  diffi-
cult to  handle (39).  The major  differences in the two  types
of asphalt concrete  are permeability  and  expense.  Hydraulic
asphalt  concrete, at $3.00 to  $4.20/yd2,  4 in thick, installed,
runs about 30 percent higher than normal  asphalt concrete (39).
The added  expense buys a  decreased permeability  -  from  1.2 x
10~8 cm/sec for  normal asphalt concrete  to 3.3 x 10~9 cm/sec
for hydraulic asphalt concrete (37).


      Soil  asphalt is a mixed-in-place surfacing  made by mixing
 a liquid asphalt into the soil.   Compared to other asphaltic
 caps, it is relatively inexpensive  - $1.25/yd2 installed (39).
 The permeability of a soil asphalt  can be controlled by the
 amount and type of asphalt used.  One study used a soil asphalt
 of an initial permeability of 1.7 x   10-3 cm/sec, which decreased
 to 2.8 x 10~8 cm/sec after one year   in the field (37).

      Catalytically blown bituminous   seals are produced by air-
 blowing hot asphalt in the presence  of a catalyst.  One to  one
 and one-half gal/yd2 are required to form a film 3/16  to 5/16
 in thick (39).   This type of membrane is supposedly  impervious
 to water,  but it is prone to mechanical  damage.   A soil cover
 is usually necessary,  bringing the  total cost to $1.50 to
 $2.00/yd2  installed.
                                43

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     The use of asphaltics as water barriers is  well  es-
tablished.   The main canal of the Boise Project, Idaho,  has  a
14-yr-old asphalt concrete surface which has shown no cracks
or signs of failures (55).  Experience with asphaltics as
sanitary landfill liners is not very extensive.   One  of  the
first such  liners was constructed in 1971  at Montgomery
County, Pennsylvania.  This liner was a 3-in tar cement  with
a 1/8-in hot tar sealer coat covered with  crushed rock and
incinerator ash (28).  Similar systems have been constructed
elsewhere,  but their relatively short time in place does
not allow a full evaluation of their success or  failure  as
long-term sanitary landfill liners.

Disadvantages--

     Organic acids attack asphaltics to a  limited extent,  and
oily materials can cause failures.  Neither of these  should
present a problem at radwaste burial sites.  Asphaltics  are
generally photosensitive and will decay in direct sunlight
(39).  Due  to settlement or freezing, asphalt concretes  are
susceptible to cracking.  Soil asphalts and bituminous seals
are more flexible, but can become embrittled at  extremely
low temperatures (-350Q).  Bituminous seals lack sufficient
structural  integrity to withstand much surface traffic,
animal  or plant damage, or tearing due to  settlement.  Soil
asphalts may be the best compromise as trench caps in terms  of
flexibility and strength, but they also are the  most  permeable
of the  asphaltics (37).

Advantages--

     Asphaltics are relatively inexpensive and,  while placement
requires a  certain expertise, this expertise is  readily  avail-
able nationwide.  A structurally sound asphaltic membrane  is
almost  impermeable to water.  Its sensitivities  and weaknesses
can be  overcome through the proper use of  cover  materials  over
the membrane.  Bituminous seals or soil asphalt  could even
be used to  seal each section of trench as  it is  filled.   This,
in conjunction with an overall trench cap, could ensure  that
a cap failure would at least be localized  in only one section
of a given  trench.  At best, the double seal could eliminate
leachate due to surface damage, or retard  it until the cap
could be repai red.

     It should be noted that several nations, including  the
United  States and U.S.S.R., are seriously  considering using
asphalt or  bitumen as an encapsulating material  for high-
level radwastes.  Preliminary tests have been favorable,  thus
establishing its potential applicability to low-level radwaste
si tes .
                              44

-------
     The asphaltics also have the same disadvantage as  concrete
in that their permanency precludes easy removal  of the  wastes,
should this ever become necessary.  Otherwise,  asphaltics  could
be a good trench cap material for preventing water infiltration
into the trenches.

Soil Cement

     Soil cement is a mixture of soil  and Portland cement,
compacted at optimum moisture content  and cured  to hydrate the
cement.  It is generally used for strength or seepage control,
where the expense or longevity of concrete is unnecessary.
The installed cost  of a 6 to 8-in soil cement layer with a bitumv
nous seal coat is $1.25/yd2 (39) as compared to  $7.90/yd2  for
a 4-in concrete layer (5).   However, the reduced cost reflects
a somewhat reduced  quality.  Soil cements are seldom used
where the 50+ year  longevity of concrete is required.  Further-
more, depending on  the quantity of cement and the soil  type,
soil cements vary widely in permeability.  Reported permeability
coefficients range  from a high of 10 cm/sec (39) to 10~6 cm/sec
(74) to 1.5 x TO'8  cm/sec (37).

     Soil cements are susceptible to attack by  acids.  They are
readily degraded by environmental factors such  as wet-dry
or freeze-thaw cycles (39).  Soil cements are more flexible than
concrete and thus could withstand some differential settling  and
frost heave to a greater degree, although they  too will crack
under sufficient stress.

     Soil cements have a long history  of successful applications
as low-cost liners  for reservoirs, canals, ponds, sewage lagoons,
and dam facings.  Rogers (74) lists a  variety of actual applica-
tions of soil cement, including site descriptions and general
specifications.  The longest lifetime  he reports is 23  years  for
a soil cement-lined reservoir in Port  Isabel, Texas.  At the
end of that period, the lining, with minimum maintenance needs,
was still performing satisfactorily.

     A variation on traditional soil cement is  carbonate bonding
(5), which incorporates lime hydrate instead of Portland cement;
it requires carbon  dioxide gas to set  up properly, and  it  is
cost competitive with normal soil cement  ($1.30/yd2 for a  6-in
layer  installed  (5), and $1.25/yd2  for a  6-in layer installed
(39)).  Its permeability to water  is comparable to that of
concrete, and  it resembles normal soil cement in other respects.
It might find  its  greatest application in heavy clay soils
where  the carbonate bonds form best and  where good soil cements
are most difficult  to attain.  Carbonate  bonding has not yet
been evaluated  in  full-scale applications.
                              45

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Synthetic Polymer Membranes

     Flexible polymeric membranes are assuming increased im-
portance as liner materials because of their low permeability
to water.  The polymeric materials used in the manufacture of
these liners includes synthetic plastics and rubbers.  The
membrane sheeting is usually available in rolls about 2 meters
wide and 60 meters long.  Several sheets can be factory seamed
by the fabricator to form larger panels.  The sheets can be
heat sealed, cemented, or solvent welded in the field.  Often
two sheets are plied together to increase strength and reduce
the effects of pinholes and other defects.  Sometimes a nylon
or polyester scrim fabric reinforcement is sandwiched between
the plies to give added strength to the liner.

     The use of plastics and synthetic rubbers as  watertight
liners  is a relatively recent innovation.   In fact,  most of
the synthetic polymers under consideration today did not even
exist commercially 25 years ago.  Their use as sanitary land-
fill  or reservoir liners is even more recent.  Consequently, it
is difficult to estimate, longevities  for many of the membrane
types simply because there has not been sufficient time to
test them.

Types--

     There are at least seven types of synthetic polymer
membranes currently used or under consideration for  landfill
liners  - butyl rubber, Hypalon, chlorinated polyethylene (CPE),
polyethylene (PE), polyvinyl chloride (PVC), Neoprene, and
ethylene-propylene diene monomer (EPDM).  These membranes vary
widely  in characteristics and costs.   Table 10 lists the costs
for each commonly used synthetic membrane.

     Butyl  rubber is one of the older synthetic polymers.  As
such, it has demonstrated longevities in excess of 20 years
(38, 39).  It is one of the least permeable membrane materials,
but is  also one of the more expensive.  Butyl rubber has ex-
cellent resistance to permeation of water and swelling in water.
Butyl liners age well although  they are susceptible  to cracking
in the presence of ozone.   They are difficult to splice in the
field.

     Polyethylene is the least expensive membrane  material.  It
is probably the least durable as well.  Membranes  of this
material  are often full  of pinholes and blisters which can go
undetected (39).   Polyethylene weathers poorly and has poor
puncture resistance (28).   Despite these drawbacks,  there are
examples of effective PE liners with  lifetimes exceeding 10 years
(40).  These liners are usually multi-ply and are  often reinforced
                              46

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     TABLE  10.   COSTS  OF  SYNTHETIC  POLYMER  MEMBRANE  LINERS
Li ner
Butyl rubber
Hypalon
Neoprene
Chlorinated polyethylene
Polyethyl ene
Ethylene-propyl ene diene
monomer
Polyvinyl chloride

2a
Installed Cost/yd^
$2.70-3.80
2.30-3.00
4.40-5.40
2.30-3.00
0.90-1.40
2.60-3.70
1 .20-2.00

Reference
No.
28
28
39
28
39
28
28, 40

aSoil  cover over membrane not included,  cost  of  which  could
 range from $0.10 to $0.50/yd /ft  of  depth.
                              47

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     Polyvinyl  chloride is one of the more common synthetic
liners.   It is  strong, puncture and chemical  resistant,  and
very impermeable.   Its stability is variable,  however,
depending on the particular plasticizer used.   As a  result,
PVC may  be subject to deterioration from wind, sunlight  or
heat (39).  Some plasticizers are biodegradable or water
soluble.   PVC tends to stiffen and become brittle at sub-
freezing  temperatures (28).  It is probably the most popular
1i ner material.

     Ethylene-propylene diene monomer is very  resistant  to
weathering or temperature deterioration.  It  is heat resistant
and retains its flexibility at low temperatures, but it  has
poor chemical resistance.

     Chlorinated polyethylene is a relatively  recent develop-
ment.  It makes durable linings for wastewater, or chemical
storage  pits, ponds,  or reservoirs.  It withstands ozone,
weathering, ultraviolet light, and microbial  attack.

     Hypalon is a  high cost membrane material.  It is highly
chemical  resistant with good puncture and temperature
resistance.  It has a low tensile strength, however, which
makes it  somewhat  susceptible to breakage due  to settling  or
frost heave in  the underlying soil or wastes.   It is the
second most popular liner material.

     Most of these membranes have been used as liners in
sanitary  landfills, reservoirs, sewage lagoons, or similar
applications.  Some,  such as PVC, PE, and butyl rubber  have
demonstrated longevities of at least 10 to 20  years  (39, 40).
For further information on the properties of  these membranes,
with examples of their applications, see Geswein (28),  Haxo
(37, 38,  39), Mickey  (40), Goldstein (30), C.luff (11),  or  . .
Moeller  and Ryffel (62).

Applications--

     As  trench  caps,  the membrane liner would  be laid on over
the mounded soil cover.  In general, the membranes come  in
rolls and may need to be seamed to provide a  continuous
surface.   Large panels are available for some  types  of
membranes.  Seaming can be a construction problem for some
polymer .types and  generally is the weak link  in the  liner.
One-yr leachate tests on PVC, CPE, and Hypalon have  shown  that
the seams may fail even when the membranes remain intact
(37).  Under mechanical stress, the seams often given way
first.                               .

     As  trench  caps,  the membranes would generally be exposed
only to  infiltrating  rain water which is relatively  weak
                              48

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chemically.  As a result, membranes susceptible to chemical
attack might still  be suitable as trench caps.   The major
threats to synthetic membranes as caps are microbial  attack,
sunlight, burrowing animals, plant roots, or weathering.

     The membrane could be covered with a layer of soil  to
prevent mechanical  damage or deterioration from sunlight.
The proper synthetic polymer membrane correctly emplaced  can
provide an impermeable trench cap of at least 30 yr duration,
with the added advantage of providing a good cap while being
easily removable in the event that the trench contents need
to be removed.  Reclosing the trench would require a  new
membrane, but this  is much less expensive or troublesome  than
replacing a concrete or asphalt trench cap.
     Clay is a natural, polymeric hydrous alumino-silicate
mineral.  Structurally it is formed of layers of connected
tetrahedral  or octahedral molecular units.   Because of the
charge distribution of these units, the surfaces of the
sheets are populated by cations, usually sodium  or calcium.
The addition of water causes the cations to hydrate, generating
electrical charges that repel  the sheets.  Physically, the
clay particles "swell.."  A layer of the "swollen" particles
is virtually impermeable to water because of the negligible
pore space between particles.

     This sealing property makes clay an ideal  liner for water-
containing structures - reservoirs, ponds,  canals, etc.  Clay
layers have also been used, with varying success, to line
sani tary landfi11s.

     Clays are available from  several sources.   Often, natural
clay deposits in the vicinity  of disposal sites  are used.
These clays are generally combinations of illite, kaolinite,
attapulgite, and montmori11onite in varying quantities (1).
Most native clays contain substantial nonclay portions con-
sisting of sand and silt, which diminishes  the  value of the
clay as a sealant.  The alternative is to buy proprietary clay
mixtures (e.g., bentonite, Volclay) which adds  to the expense
of the clay, but ensures chemical and physical  quality.
Most successful clay liners have relied on  commercial  clays.

     The chemical nature of the clay can strongly affect its
permeability.  Sodium bentonite (standard Wyoming bentonite),
for instance, is several times more "swellable"  than calcium
bentonite; that is, calcium bentonite swells to  a much lesser
degree.  Consequently, sodium  bentonite is  generally less
permeable.  It is also less stable.  If sodium  bentonite comes
in contact with water containing divalent cations (e.g.,
                              49

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calcium, magnesium),  the sodium will  be replaced  by the
divalent cations.   This, in turn,  affects  the structural
integrity of the clay and shortens its usable lifetime
dramatically.   Calcium bentonites  are generally  unaffected  by
this type of situation and are chemically  more stable.

Applications--

     As a trench cap, a clay layer would be placed  over the
mounded soil cover and covered with another layer of excavated
soil.  The soil  layer must be thick enough to prevent the
clay from drying out; when the clay dries  out, it cracks.
Swelling will  close the cracks when the clay is  wet again,
but sand or soil particles will undoubtedly have  gotten into
the cracks, making the closure incomplete.  After several such
wet and dry cycles, the incompletely closed cracks  could  go
through the clay and  breach the layer.  The thickness of  the
soil cover required to prevent such drying out will vary,
depending on local climatic conditions.  Hawkins  and Horton
(36) found that a  1-ft soil layer  was insufficient  to protect
a clay layer during a 3-mo drought, whereas 2 ft  of soil  pro-
tected the clay and prevented cracking.

     Often, especially in sanitary landfill applications, clay
is used in conjunction with another liner, such  as  plastic
membranes.  While  more costly than either  liner  type separately,
the combination is stable, very impermeable, and  not subject
to many of the disadvantages which hamper  the use of clay alone.

Advantages and Disadvantages--

     Clay liners are  extremely susceptible to biological
damage.  Insects and  animals can burrow through  them with
little difficulty.  Plant roots can be especially damaging.
Use of pesticides  or  plastic membranes along with the clay
can prevent much of this type of damage.

     Clay liners are  generally flexible and can  tolerate  some
deformity due to differential settling.  The clay must be
protected from freezing temperatures, as the expansion of
the water of hydration can crack the liner and threaten its
integrity.  A soil or gravel cover of sufficient  thickness
can prevent this.

     Cost estimates for bentonite  clay vary.  Haxo  (39) gives
an installed cost  for a 9-lb mixture of soil and  bentonite  of
$0.72/yd2.  Hawkins and Horton (39) state  that the  installed
cost of a bentonite cover in 1967  was about equal to that of
concrete.  Since clay has not increased in cost  at  the same
rate as Portland cement, concrete  covers would be slightly
more costly than clay in 1977.  In either  case,  it  has been
                               50

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estimated that,  in the absence of mechanical  damage,  a  clay
liner has an expected longevity of thousands  of  years (36).

Soil  Sealants

Appli cations--

     Soil sealants are chemicals, usually polymers  of some
sort, which can  be admixed with the soil  or clay of a trench
cover to form a  relatively impermeable layer.  They work by
polymerizing or  swelling between the soil particles and
forming a sheet  effect around the particles,  sealing  the
surface of the trench cover.   They are applied as liquids to
the trench cover and generally penetrate several millimeters
or centimeters into the soil.  They are polymerized either
through drying or with steam heat.  These sealers are fairly
new and relatively untested in full-scale applications.

     There are a wide variety of soil sealers:  calcium
1ignosulfonate,  alumino-si 1icate gels, elastomeric polymers,
latex, asphalt emulsions, and styrenes.  Gulf South Research
Institute  (33) has done considerable research with these
materials  and reported that bentonite alone worked better than
any of them.

Di sadvantages--

     The major problem with the  sealers  is lack of control over
the polymerization or sealing process.   Consequently, incomplete
seals are  rather common.  Soil sealants  are of marginal
stability, subject,  in many cases, to both chemical and biologi-
cal attack.   These defects have  led  Uniroyal, for  instance,  to
conclude that latex will not work as a soil sealant  (87).

      In  general,  soil  sealants  have  found  their greatest  appli-
 cability  in  the  stabilization  of mine  tailings  piles  (35, 86).
 Sealants  provide  structural  stability  even when they do  not
 form  impermeable  surface  layers.

 Advantages--

      The  greatest  advantage  of  soil  sealants  is  their  cost.
 Many  soil  sealants  can  be  formulated  from  waste polymers  and
 consequently, are  quite  inexpensive.   Havens  and Dean  (35)
 estimate  that either  DCA-70,  an  elastomeric  polymer, or  Norlig A
 a calcium  1ignosulfonate,  would  cost  less  than  $0.10/yd2
 installed.   In  conjunction with  a  better cap, such as  bentonite
 or synthetic  membranes,  they  would  be  a  good  backup  system.   It
 might  be  possible  to  mix  some  of these  sealants in with  the fill
 and  cover  soils  in  the  trenches  before  capping  to  provide an
 additional  safety  factor  against water  infiltration,  in  the
 event  that the  basic  material  cap  does  fail.
                               51

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TRENCH CAP COVERS

     None of the trench cap concepts mentioned so far is
completely resistant to environmental stresses:  concrete
will flake under freeze-thaw or crack due to frost heave;
asphalt will crack from frost heave or degrade in sunlight;
soil cements will degrade like concrete; many synthetic mem-
branes will degrade in sunlight or suffer mechanical  damage.
Consequently, some sort of cover is required to protect the
trench cap.  This cover will prevent mechanical damage,
protect the cap from sunlight, freeze/thaw and frost heave,
and keep clays damp.


     The two principal  cover materials are gravel  and soil.
Excavated trench soil  material  could be used for  the  soil  cover;
gravel would usually need to be purchased and brought in from
off site.  The placement of gravel  directly on top of some
trench caps (e.g., synthetic polymer membranes) may damage the
cap material.   For those caps most susceptible to mechanical
damage, a thin layer of soil can be laid down first and covered
with gravel .

     The depth of the  cover is largely dependent  on the local
climate.  Since one of the purposes of the cover  is to protect
the cap from frost heave, it must be deep enough  to thwart frost
penetration to the cap.  Figure 7 shows the average frost
penetrations in the United States.   For some caps, such as clay,
the cover must also be deep enough to prevent drying.  A depth
of 2 ft was previously cited as being sufficient  to prevent clay
drying and cracking under severe conditions.  In  this context,
a soil cover would probably work better than gravel.   A gravel
cover would allow freer air circulation at the cap surface
with  probable drying.  Of course,  vegetative damage  to  a  clay
cap would  be more  likely with a  soil  cover  than with gravel.
A  layered  cover,  half  soil  and  half gravel, might  be the  best
compromise  for  a  clay  cap cover.

      Soil  covers  are susceptible to erosion or mechanical
damage.   Normally, a vegetative  cover  could be used  to  prevent
such  damage, but  there may  be the  threat  of root damage
to  the  cap.   It would  be possible  to  use  some  of the soil
sealants mentioned earlier  to stabilize  the soil surface,
prevent  erosion,  and inhibit vegetation  growth.  Herbicide
application to  the surface may  be  necessary, where excessive
weed  growth is  expected.

      In  general,  for most cap materials,  the multi-layer  cover
concept  appears best.  The  soil  cover  protects the cap, and  the
gravel  protects the soil cover.  An average trench would  then
resemble  Figure 8:  waste material, soil  fill  and  mounded
cover,  trench cap, cover soil,  and gravel  top  cover.   Use  of
this  type  of system can  reduce  maintenance  costs dramatically.

                               52

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on
Co
                                                                                             Depth of
                                                                                          Frost Penetration
               Contours represent averoge depth of frost
               penetration in inches where data permit
               generalization. Elsewhere, depths at
               individual stations are shown.
               (Based on 40 years of record)
               Source:  U.S. Dept of Agriculture
            Source:   The  Clow  Corporation.    Pipe  Economy,  1975.
                                        Figure  7.    Depth  of  frost penetration.

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  COMPACTED SOIL (0.3 TO 0.6 M)
   GRAVEL
 (15 TO 40
     CM)
     TRENCH CAP
(MEMBRANE, CLAY* ETC.)
                                  COMPACTED
                                   SOIL
                                  BACKFILL
                                                       WASTE MATERIAL

Figure  8.   Conceptual completed low-level radwaste disposal trench,
                                      54

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                         CHAPTER  5
      ALTERNATIVE  TRENCH  AND  SITE CONSTRUCTION  METHODS
INTRODUCTION

     Two concepts  will  be  discussed  in  this  chapter:

      1.   Methods  that  can be implemented  prior  to  the  deposit
          of radioactive wastes  in  a disposal  trench,  i.e.,
          during the initial  trench  excavation and  generally
          applicable only  at  future  or  partially completed
          di sposal  si tes.

      2.   Methods  or procedures  that can  be  implemented  during
          or after disposal  operations  (other  than  trench
          covers,  which are  discussed in  Chapter 4)  and as
          remedial  measures  at existing sites  where  trenches
          are completed.

     The trench and site construction concepts discussed in
this chapter are not intended to be  considered as infiltration
controls independent of the  trench  covers  discussed  in  Chapter
4; rather, the concepts should be viewed  as  complementary.
Optimally constructed  disposal trenches depending on particular
infiltration control needs at a  given site would probably
include features presented in both  chapters.  Whereas  the  con-
cepts developed in Chapter 4  are concerned primarily with
infiltration through the cover,  this chapter addresses  such
problems as surface runoff  control  and curtailment  of  hori-
zontal groundwater percol ation in saturated  soils.

     Table 11  presents  a summary of the concepts addressed  in
this chapter.  Some of these  concepts are  theoretical,  and
thus largely untested,  but potentially  usable; others  have  been
used, but not at low level  radwaste  disposal  sites.   In  most
cases, the estimated longevities are conjectural, since the
methods have not been evaluated  over the  time  spans  considered
applicable for radwaste decay and/or degradation.  Even those
concepts of proven utility in management  of other types of
wastes have not been evaluated in the radwaste disposal
environment, although such methods  are  valid concepts  for
potential radwaste disposal  applications.   However,  direct
application of methods  developed for other wastes to radwaste
disposal conditions may not be possible without modifications or
adjustments in design,  construction technique, and/or  monitoring
procedures .

                               55

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                       TABLE  11.   SUMMARY OF TRENCH AND SITE CONSTRUCTION ALTERNATIVES
en
Concept
Description Comments
Expected
Longevity
Approxi-
mate
Cost/
Trench,
Instal-
led3
Refer-
ence
No.
Situate disposal
site on a slope
or hillside

Situate disposal
site on flat
ground

Construct system of
berms/drainage
ditches on the site
        Construct trenches
        with level bottoms

        Construct trenches
        with sloped bottoms

        Line trench bottom
        with permeable soil
        or other material
                                  Applicable for new sites only
                                  Applicable for new sites only
                                  Applicable as a remedial measure and at
                                  new site construction
                          Applicable for  new trenches  only
                          Applicable for new trenches  only
                          Applicable  for new trenches  only
    NA
    NA
Indefinite with  $10/linear
regular mainte-   meter of
nance             berm or
                  ditch

    NA
    NA
    NA
$500-1,000
             42
             42
42


42


42
          Costs are for a  "typical"  100 m by  15  m  x  6 m  trench

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       TABLE 11.  (continued)
Ul
--J

Concept
Description
Construct narrow gravel-
filled diversion trenches
around entire site and/or
individual disposal
trenches


Comments
Applicable at new sites or as
a remedial measure





Expected Longivity
Indefinite with
regular maintenance



Approxi-
mate
Cost/
Trench, Refer-
Instal- ence
led3 No.
$100/1 inear 36
meter of
diversion
trench

       Trench liners
       Grout curtains around
       sites and/or trench
       periphery
       In-situ encapsulation-
       injection of a slurry
       of impermeable material
       into each trench to fill
       void spaces
Applicable for new trenches
only
Applicable primarily as a
remedial measure, but can be
used at new sites
Applicable primarily as a
remedial measure in closed
trenches
Varies with
material and expo-
sure conditions;
at least 5 to 40
years
$40,000 to   28, 39,
$275,000.     75
depending on
linear
material
Variable, depend-
ing on the filler
material; 10 to
50 years
Up to
$70,000,
depending on
grout mate-
rial used

$140,000
to $700,000,
depending on
material
                                  2, 8, 75
        Costs  are for a  "typical"  100  m by 15 m x  6 m trench

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TRENCH CONSTRUCTION

     The typical  trench configuration described in Chapter 2
shows each trench with a sloped (3 to 5 percent)  bottom.   This
method of construction allows any water entering  the trench
during fill  operations (e.g., direct rainfall  and undiverted
runoff) to drain  to one end of the trench where it can be
conveniently pumped out.  However, a sloped bottom may actually
contribute to the presence of water in the trench, as noted by
Horton (42).  In  his study of soil moisture flow  in relation to
radwaste disposal, he suggests that radwaste disposal trenches
be constructed with level trench bottoms.  However, flat bottoms
do not prevent rain water or runoff from entering trenches
during fill  operations, and removal of any water  is difficult,
if it is in  a relatively shallow layer.  If a  trench can be
filled in such a  manner as to avoid standing water during the
operation (e.g.,  by location of sites in arid  climates; rapid
excavation and filling of trenches during dry  spells; dewater-
ing at the site during excavation; a system of berms and
temporary tarps to cover open trenches), then  the level bottom
probably is  less  likely to allow horizontal water movement into
the trench.   Trenches with level bottoms may cost more to
monitor and  remove water from, than trenches with sloped bottoms,

     The potential for horizontal percolation  of  water in the
unsaturated  zone   contacting radwaste through  sloped bottoms
can be mitigated  somewhat by providing a 30- to 60-cm thick
gravel floor in the trench before placement of wastes, prevent-
ing contact  between the wastes and any standing water.  Frequent
monitoring would  be necessary to ensure that the  depth of the
standing water did not rise above the depth of the gravel layer.

TRENCH SITING

     Trench  siting, whether on flat ground or  slopes, can
significantly affect the potential for infiltration of surface
runoff into  disposal trenches.  If a trench is located on an
incline, horizontal water percolation in the unsaturated zone
into the trench is possible, because the original ground surface
slopes toward and intersects the trench.  Water infiltrating
in homogenous soils through the zone of aeration  will naturally
tend to move toward the area of lower potential,  in this case
the trench,  depending upon the nature of the backfill (Figure 9)
One way to avoid  this is to place trenches only on a relatively
flat ground.  However, surface drainage at flat sites is often
poor, allowing rainfall or spilled water to pond  between the
mounded trench covers.  In such cases, a series of drainage
ditches would be  necessary to maintain water-free surfaces
between the  trenches.  Normally, however, percolating waters
will flow in a vertical pathway until reaching the ground-
water table.
                               58

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PRECIPITATION
PRECIPITATION
                       IMPERMEABLE CAP
                        BACKFILLED
                          TRENCH
   PATHWAYS OF
PERCOLATING WATER
   Figure 9.   Possible horizontal flow of water into a
              backfi11ed trench.
                           59

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     Placement of trenches on grades should not be ruled out.
Figure 10 depicts a slope site, with the topsoil  removed,
protected by a series of berms and an upslope diversion ditch.
The natural  slope allows precipitation runoff with little
danger of ponding, while the ditch and berms divert most
surface water away from the trenches.  This configuration will
inhibit both horizontal movement in the saturated zone and
surface runoff into the trenches.

DIVERSION TRENCHES

     Deep narrow trenches filled with a permeable medium (e.g.,
gravel) are  sometimes used to prevent or control  horizontal
groundwater  movement and divert water away from the individual
disposal trenches or even the entire site.  Groundwater
encountering one of these diversion trenches will follow the
diversion trench around the disposal trench or site if there
is a sufficient gradient within the trench.  This system, which
has been successfully applied to groundwater control at sanitary
landfills, has been proposed by other researchers for use at
radwaste disposal sites (36).

     The narrow trenches provide a high permeability path for
the water to flow around the site.  This type of approach is
analogous to electronic shielding problems where a circuit
is isolated  from outside voltage gradients by putting the
circuit in question inside a conducting box.  There is no need
to dewater the trench as long as the hydraulic potential is
less than in the surrounding soil.  If groundwater periodically
rises into the wastes, then falls again, the diversion trench
system will  not prevent contamination from this pumping action.

     In practice, the trenches should be about 50 cm wide,
deeper than  the level of the disposal trench bottom, and
usually filled with gravel or other permeable material to
within one meter of the surface and then backfilled with the
excavated soil.  Such diversion trenches down to the aquifer
will prevent the water table, in areas of high water table,
from rising  into the disposal trenches from beneath.

     In arid regions, it might be possible to limit construction
of diversion trenches to the periphery of the site, rather than
around each  trench, while for sites in wetter regions or in
high water table areas, diversion trenches throughout the site,
or possibly  around each trench (Figure 11) would provide better
protection.   Economics might be a factor for this concept;
construction of diversion trenches will cost about $100/1inear
meter.
                              60

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        DIVERSION
          DITCH
                       BERM
                                                              BERM
                                               TRENCH 2
Source:   40
Figure 10.  Burial  trench arrangement  to  impede  horizontal water infiltra-
                         tion through  the topsoil
                                     61

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                           TRENCH PLAN
                                                                LINED  TRENCHES
                                                                   TYPICAL
no
                                0. 0%
                      2'-0 TYP
                        LONGITUDINAL  SECTION
              NOTE:  ALL ELEVATIONS ARE ASSUMED
 ^x o
o    "o

 0.0%
                                                                        CROSS SECTION
                                                        GRAVEL TRENCH
                                                            (TYP)
                                                                                           GRAVEL
                                                                                           TRENCH
                                                                                           (TYP)
                     Figure 11 .  Radwaste  disposal trench  with diversion  trenches.

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TRENCH LINERS

     Nearly all  of the materials previously discussed  as  being
applicable for trench caps could also be used as  trench  liners;
most information referenced in the discussion of  trench  cap
materials concerns use of these materials as liners  for  sanitary
landfills, ponds, reservoirs,  and canals.  Most of the informa-
tion on material properties, costs, advantages, and  disadvan-
tages presented  in Chapter 4 are, therefore, largely applicable
here as well.  In general, since materials used as liners  are
generally buried, damages from frost heave, freeze/thaw,
settling and sunlight are less a problem for liners  than  for
caps.  However,  chemical  damage (due to soil alkalinity,
acidity, sulfates, and leachate) may be more severe.

Advantages and Disadvantages

     Aside from  the behavior of individual liners, the concept
of trench lining has numerous  advantages and disadvantages.  A
good liner can prevent groundwater infiltration into the
trenches through both the bottom and the sides.  If  water
infiltrates into the trench through the surface,  any leachate
formed will be retained for extended periods and  should  not
enter the environment, as long as the liner remains  intact.

     However, the ability to hold water can also  be  viewed as  a
major disadvantage of trench liners.  Lined trenches are
essentially bathtubs; they trap and hold any water that  may
have entered the wastes,  leaving it in contact with  the  wastes
for an indefinite time.  Under such conditions, more highly
concentrated leachates than might otherwise be encountered can
be produced.  As a result, lined trenches may require more
rigorous monitoring and more frequent remedial pumping than
unlined trenches.  This,  in turn, could create a  radioactive
liquid waste disposal problem.  In general, most  experts  have
been unenthusiastic about the applicability of the trench  liner
concept to low-level radwaste disposal situations.

GROUT CURTAINS

     Grouting is the process of injecting appropriate material
into soils and rocks thus  reducing the strata's permeability
and/or increasing its strength.  As a water sealant,  grouting
has a history of successful application  in mines  and tunnels,
and under dams (7, 8).  Grouting materials include cement,
clays, asphalts, bitumens, silicates, 1ignochromes,  1ignosulfates
epoxy resins, acrylamide, polyester resins, polyphenolics,
resorcinolformaldehyde, and other chemical polymers  (6,  7).
                              63

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     At a low-level  radwaste disposal  site,  grout curtains
could be placed around a burial  trench (Figure 12)  at any
time during the life of a trench site  in such a way as to
prevent the horizontal movement  of subsurface water,  either
into or out of the trench.   Grout curtains would work better
as a remedial  measure as new trench construction could damage
adjacent grout curtains around existing trenches.

     The longevity of grout curtains can be  expected  to vary
with the materials used; in general, they are expected to
last the life  of the dam (7).   References 7  and 8 contain
lists of many  sites  where old  grout curtains are still intact.

     The soil  or rock beneath  a  trench could conceivably be
grouted as well, but such practice could lead to the  formation
of a "bathtub," as discussed above.  In areas of fractured
bedrock grout  could  be used to seal some of the fissures, thus
providing a more secure and better delineated foundation for
a disposal site.  Grout injections could also be used to seal
leaks in the other liner systems.

     The variety of grout materials and injection techniques
available allows' considerable versatility in how and where grouts
can be used.  In general, grouting is  easiest in loose, dry
soils, since wet soils can inhibit and slow grout gelling,
sometimes to the extent that the grout material can dissolve
or be washed away before it has  a chance to set.  Fine grain
soils require  low viscosity grouting materials to ensure
proper spreading.  Despite these and similar problems, enough
different materials  are available to provide sufficient sealing
in almost every soil environment to be expected at a  disposal
si te.

     Recently, Applied Nucleonics Company, Inc., Los  Angeles,
studied radwaste relocation at Hanford, Washington; the
feasibility of grouting around radwaste trenches was  investi-
gated^).  Although  final results of this study are not yet
available, indications are that  grouting does have potential
for controlling water infiltration at this site.

     Grouting  has several  disadvantages.   Considerable research
is required to determine precise site soil conditions and to
select suitable grout material.   Skilled personnel  are needed
to properly place the grout, and it is difficult to assess
whether the grout curtain is working unless it fails.  Costs
are generally  in the range of $400/m3  installed, or up to
$70,000 per typical  trench for a complete curtain (around all
four sides) .

     For more  complete information, Reference 2 contains an
extensive bibliography on all  aspects  of grouting.
                              64

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CTl
cn
          ~^
                           TRENCH  PLAN
                               0.0  %
2'  TYP
    LONGITUDINAL SECTION
                                                    /«
                                                          CHEMICAL
                                                           GROUT

                                                         LINED CHANNEL
                                                           (TYPICAL )
                                                                         '-
                                                       o.o
                                                                ^
                                                                     CROSS SECTION
              NOTE:  ALL ELEVATIONS ARE ASSUMED
                  Figure 12.   Radwaste disposal trench with  chemical  grout curtain.

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IN-SITU ENCAPSULATION

      Because of the loose packing of radwastes  in  many  burial
trenches, there may be up to 2,000 m3 of void  space per  typical
trench of 7,000 m3 total  volume.   If water does  enter a  trench,
the amount of waste surface area  available for contact suggests
that highly concentrated  leachates could be generated.  Thus,
it would be advantageous  to prevent or minimize  infiltration
into the wastes (and thereby reduce potential  leachate
production) by filling (encapsulating) the void  space with  a
relatively impermeable material.   Water contact  with the wastes
would be reduced and, as  an added benefit, settlement of the
waste as it decomposes could be decreased significantly,
especially if the void filler material had some  structural
strength.

     The same basic methodology would be used  for encapsulation
as in grouting.  In general the nature of the  wastes in  the
trenches is such that less care is needed in selecting a
suitable void fill material, and, in fact, it  might be possible
to use certain wastes, such as fly ash or spent  drilling muds.
Fly ash will set up like  concrete and provide  a  nearly imper-
meable fill material, and, being a waste product of combustion
the major costs would be  in transport to the disposal site and
application.  Materials costs would be very low or zero,
although the use of fly ash for encapsulation  would be limited
to sites near facilities  producing such a waste.  Drilling
muds can provide a seal of permeability comparable to bentonite.
Being fluid, drilling muds should readily fill void spaces in
radwaste trenches, and the water in drilling muds is such an
integral part of the mud  structure that little excess water
(and thus, little leachate production) need be expected  from the
mud/radwaste contact.  Drilling muds being inorganic and
basically clay, would not degrade in the anaerobic environment
of a trench.  There are examples of drilling mud linings which
have successfully withstood mechanical and chemical assault
for many years (8).

     Due to the variety of materials that could  be used, costs
of in-situ encapsulation  would vary widely.  For instance,
costs for fly ash  filler would be limited almost exclusively to
the installation.  In general, costs will range from $2  to
$10/ft3, or up to $140,000 to $700,000 per trench.
                               66

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Advantages and Disadvantages

     Filling the void spaces with a material  of some structural
strength can inhibit the waste settling which undermines  trench
caps, causes cracks, and allows surface water infiltration.
Many fillers have indefinite life spans and employ relatively
inexpensive waste materials.

     On the other hand, there might be an initial  danger  of
leachate production from the injection of some slurried fillers
Furthermore, some of the filler materials (such as fly ash)  may
themselves contain constituents that are capable of producing
hazardous leachate.  There would likely be a lack  of quality
control when injecting into a closed trench; void  filling may
be incomplete.  The skilled personnel  necessary for application
would make the costs high even though  low cost waste materials
are used as fi1lers.
                               67

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                         CHAPTER 6

        BURIAL  TRENCH  MAINTENANCE  AND  MONITORING


INTRODUCTION

    No trench burial  method can be completely secure indefi-
nitely.   However, it  is questionable whether truly indefinite
security is really necessary.   Unlike  other hazardous materials,
radwastes will  decay  to innocuous  forms.   And, although
centuries may be necessary for complete decay, much shorter
time spans will yield  relatively safe  wastes.  The issue,  then,
becomes  one of  maintaining tight control  over water infiltra-
tion for a relatively  short period of  time, fifty years for
instance, after which  limited  infiltration and leakage can
be tolerated, since any leachate that  would then  be generated
would not be radioactive.

     How soon and how much leakage and leachate can be tolerated
is dependent largely on the hydrogeology and concomitant attenu-
ation mechanisms of the disposal site and regional environment.
In some  respects, the true working life of a disposal site includes
not only the secure lifetime of the trench itself but also the
movement time of contaminants from the trench to the biosphere.
The factors affecting this movement time include:

    •  Distance to groundwater;

    •  Direction and  rate of groundwater movement;

    •  Size and use of aquifer (volume of water);

    •  Hydraulic conductivity, porosity,  and mineralogy
       of the sub-trench lithology;

    t  lon-exchange/adsorption capacity of the subsurface
       soils;

    •  Position and extent of any fractures in the bedrock;
       and

    •  Distribution coefficients for nuclide movement
       through  the hydrostratigraphy.
                             68

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     Theoretically, without extensive trench modification  or
sealing, a radioactive waste requiring X years  to decay to a
safe level could be placed in ordinary trenches in an environ-
ment which had an X-year delay between trench and biosphere.
On the other hand, an environment allowing rapid transport of
contaminants to ground or surface water would require a trench
with a water-secure lifetime of at least X years.  In practice,
to account for unknowns and emergencies, safety factors dictate
a combination of trench life and movement rate  controls which
exceed the X years.  Consequently, site factors play a large
role in determining not only site acceptability but also the
nature and duration of the trench seal required to prevent
water infiltration.  It will likely be beneficial to incorporate
some combination of sealing, capping, or encapsulation at  all
burial sites, regardless of the natural attenuation charac-
teristics present.

     A good example of this type of reasoning is found in  the
design of the Barnwell , South Carolina, burial  site (43).
Although in a high rainfall area, this site possesses a highly
favorable groundwater hydrology.  A hydrostatic head reversal
prevents downward flow into an aquifer; thus, migration of
nuclides is confined to the direction of surface streams.   Given
the depth to the water table, the short flow path to a surface
stream, and the groundwater movement rate, the  estimated travel
time for subsurface water from the solid radioactive waste
storage site to this stream is about 70 years.   Consequently,
little attempt is made to prevent infiltration  into the trenches.
Trenches are pumped regularly to produce a short residence time
and a less contaminated leachate.  The 70 years is considered
sufficient to allow for complete attenuation of any radionuclides
in the leachate.

SURFACE MAINTENANCE

     Regardless of the type of cap, cover, trench, or berm,
some degree of site maintenance will undoubtedly be required
to ensure cap integrity and to minimize infiltration.  Any
system, especially a poorly-designed system, is subject to
failure from settlement or cover erosion.  Even the best systems
will require periodic inspection to identify problems and  to
indicate repairs if problems are found.

     The causes and effects of settlement have been noted
previously.  If waste settlement within a trench threatens the
integrity of a cover or cap, the only alternatives available
are to replace the cover and/or arrest the settling.  In severe
cases, where settlement has caused cover failure, it may be
necessary to remove the existing cover, recompact the wastes,
add soil or additional waste to fill the void,  and place a new
cover.  For the non-permanent cover types (soil sealants,
                               69

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synthetic  membranes,  clays,  etc.),  it  might  be  possible  to
simply compact the  cover material  well  and  place  a  new cover  on
top of the old one.   However,  further  settlement  could cause  a
repetition of the problem.

     It might be possible to arrest settling by injecting  a  non-
settleable material,  such as spent drilling  mud,  bentonite
slurry, concrete, or  similar grouting  substances, into the
trenches.   The major  objection to  such injection  is that these
all contain water and water  is the liquid  to be kept out of
the trenches.  However, for  some injectable  materials, such
as drilling muds, the water  is such an integral part of  the
slurry that leaching  will,  at  most, be minimal.  Significant
leaching will not likely occur with any of  the  materials.

     Erosion of the trench  cover can be caused  by wind,  water,
or temperature extremes.  In the earlier discussion of trench
caps, it was determined that a multi-layer  system where  the
cap was covered with  soil and  gravel layers  could effectively
control erosion.  Gravel covers for upstream runoff diversion
berms would also help prevent  erosion  of the berm material.

     Berms and trench covers can still be damaged by severe
weather incidents or  changes (e.g., torrential  rains, tornados,
hurricanes, heavy freezes,  spring  thaws) or  earthquakes.  Close
inspection following  such incidents is necessary  to locate  and
assess any damage.   In the  event of collapsed berms, rebuilding
might be necessary.  Damaged gravel and soil covers would  need
to be replaced where  necessary.  Cracks in  permanent caps  (e.g.,
concrete,  asphalt)  could be  patched with a  suitable synthetic
or asphaltic patching compound.

     In extreme cases where  a  cap  or berm is too  extensively
damaged to repair,  replacement would be necessary.   This is
not likely  if the  disposal  site is properly designed, con-
structed,  and maintained.

     Maintenance also includes keeping the  trenches water free.
A  sloped-bottom trench with  a  stone-filled  sump at the low end
and a permanent  standpipe  in  place can be  checked periodically
to see if, in spite of all  precautions, water has infiltrated.
If it has, the trenches can  be pumped  out.   If  trenches are
allowed to fill or if water  is allowed to stand in the trenches
for very long, opportunities for the formation  and movement  of
hazardous leachate are present.  The pumped water could be
examined for radioactivity and, if necessary, routed to holding
ponds for further treatment  before disposal.  There should  be
a  series of standpipes or a  length of  perforated  collection
pipe along the bottom of flat-bottomed trenches.  Construction
                              70

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of the sump and standpipe are considered routine.   Thus,  they
add nothing to the trench construction costs over  the normal.
A portable generator and pump could be used to dewater the
trenches.   Lengths of flexible hose would be needed to route the
water into temporary holding ponds.  A capital outlay of  less
than $1,000 should be sufficient.

     Because of the nature of the  wastes, it may be necessary
to monitor and pump indefinitely.   Leachate from radwastes
could be hazardous at any time during the hazardous lifetime
of the wastes.

VEGETATION AND LANDSCAPING

     Vegetation and landscaping can serve a dual purpose  at a
disposal site:  erosion control and aesthetic improvement.
A nicely landscaped site is far more pleasing to look at  than a
series of mounds covered with concrete, asphalt, or gravel.
Figure 13 shows a closed burial site which has been contoured
and planted with grass at Oak Ridge National Laboratory.
Shallow-rooted grasses are used for erosion control at Maxey
Flats (60).

     Vegetation serves a variety of purposes other than aesthetics
Roots hold the soil and prevent water and wind erosion of covers
and the soil between the trenches.  Fenimore's studies show
that once a grass cover is established, very little further care
and maintenance is required to maintain the cover.  Vegetation
also plays a significant part in water infiltration control
through evapotranspiration.

     The issue of landscaping is not simple, however.  Kenny
(51) reports that deep-rooted plants on the site of buried waste
from a nuclear reactor accident are radioactively contaminated
due to the raising of radionuclides through the plant.  Hawkins
and Morton (36) reported similar aftereffects in Bermuda  grass
and small plants.  They further concluded that plant growth
must be completely prevented if bentonite caps are used,  since
the clay has little resistance to  root penetration.  Also, plant
growth could conceivably aggravate minute cracks or holes in
other types of caps.  Such root penetration into the cap  will
tend to increase the potential for water infiltration.  Fenimore
examined several grasses for use as possible covers at radwaste
burial sites  (21).  He found that  Carpet grass roots could pene-
trate to 46 cm (18 inches), Bahia  and Dallis grass roots  to
16 inches, Centipede grass roots to 30 cm (12 inches), and
Bermuda grass  roots to 26 cm (10 inches).

     Overall,  the benefits derived from planting cover vegetation
on completed burial trenches (erosion control, aesthetics) may
be more significant than the costs of continuing surface
maintenance.   There are no published reports of any vegetation-
related problems at the Oak Ridge  or Maxey  Flats disposal areas,
for example.
                               71

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Figure 13.   Grass  covered  radwaste  disposal  site,




                        72

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     Alternatively,  gravel  cover can provide erosion  control
similar to that provided by vegetation,  without the potential
side-effects of cap  penetration and radionuclide trans!ocation.
Burial  sites prone to root  damage could  be kept free  of  unwanted
vegetation through the use  of gravel covers or the regular use
of herbicides.   If,  in the  future, aesthetics prove to be a
major issue, the site could be screened  with a line of trees,
hedges, walls,  or similar screening devices.

     Although gravel and other non-vegetative covers  can prevent
erosion and vegetation growths on the actual trench cover, the
uncovered areas between the trenches are subject to both.  In
fact, it is not unusual for deep-rooted  vegetation to become
established in  the uncovered soil or for severe erosion  to occur,
both of which can undermine cap integrity.  Non-vegetative covers
would require periodical herbicide treatments to keep down all
vegetation growth.  Erosion control would be considerably more
difficult.  Gravel covers have a further advantage in that they
discourage burrowing animals far more than vegetation would.

MONITORING

     In the past, most solid waste land  disposal sites have
incorporated a  total site monitoring system consisting of
monitoring devices situated along site property boundaries.
These systems have a serious flaw in that they detect leachate
only after it has been forming for some  time, possibly long
after the site  is closed.  Remedial measures at that time can
only stop the further formation of leachate; the leachate
already formed  may continue to transport hazardous contaminants
off the site.  The site boundary system  serves only to provide
an indication of the direction and rate  of leachate movement
so that precautions can be taken ahead of the flow.  For a more
complete discussion of total site monitoring systems, the reader
is referred to the several  studies on monitoring in the biblio-
graphy  (15, 24, 25, 27, 73, 90).

     A  proper monitoring system must anticipate leachate and
its probable rate and flow path  and detect it before contami-
nation  (if any) has progressed very far.   If leachate can be
detected while still in the immediate vicinity of a burial trench,
remedial steps  can be implemented which  will prevent or signifi-
cantly  delay off-site movement of  hazardous materials.  To
this end, a monitoring system  involving  detectors in and around
each burial trench is also desirable.

Trench  Monitoring Systems

     In the context of this report, individual trench monitoring
involves the detection of moisture  in the trench and is primarily
meant to:
                               73

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     •  Determine when  field  capacity  of  the  trench
        cover and walls  is  reached;

     •  Determine the efficiency of  the  infiltration
        control  systems  of  each trench;  and

     •  Establish when  pumping might be  necessary to
        reduce water levels in trenches  with  inadequate
        or faulty infiltration controls.

Ideally, the monitoring  system needed  to  achieve these goals
includes moisture cells  in  the compacted  soil  backfill, in the
trench bottom, to the sides of the trench,  and in the soil
beneath the trench.   In  practice, field  conditions may necessi-
tate variations  in the  placement, but  the overall purpose of  the
system - to detect infiltration into the  trench and  leachate
flow out of the  trench  - must be kept  in  mind.

     Commercial  electro-couple moisture  cells, such  as the
Soiltest® MC-310A,  are  the simplest means  for remotely monitor-
ing soil moisture.  Use  of  this type of  cell  requires prelimi-
nary engineering analysis to  determine the  field capacity of
the soils around the trench and the  backfill  material.  The
moisture cells can then  detect any changes  in  soil moisture
or simply the approach  of saturation and  flow.  Cells in the
soils around and below  the  trench can  monitor  groundwater and
soil moisture levels and flow; cells in  the  radwastes and
backfill soils can monitor  moisture  levels  in  the trench.

     The number  and  placement of the cells  is  largely dependent
on local moisture conditions; higher water  tables, more rain-
fall, more permeable soils  would require  greater numbers of
cells, for example.   For the  worst case,  cells should be.placed
in the mounded soil  cover,  below the trench  bottoms,  and in
two horizontal planes about 2 and 5  m deep  (Figure 14).  Cells
placed about 2 to 3  m apart can cover most  normal soil moisture
conditions.  It  is not necessary to  maintain  vertical planes
of eel Is.

     Although easier to place in new trenches, moisture cells
can be added to  filled  trenches by simply drilling holes into
the fill.  If it is  undesirable to drill  through the  cover,
slant drilling can be used  to place  probes  in the trench.
If it appears impossible to place a  cell  beneath each filled
trench without rupturing covers, liners,  or  radwaste  containers,
cells can be placed  between trenches below  the plane  of touch
bottoms.

     The cells are connected  to the  surface  by labelled leads.
These leads can  be gathered into groups  at appropriate places
                              74

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                                             CAP
MOISTURE
 PROBE
HOUSING
                                             MOISTURE
                                              PROBE
                                             HOUSING
                             COMPACTED
                              SOIL
                              COVER
  Figure 14.
Cross section of moisture monitoring  cells for
              a burial  trench
                   75

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and routed to a common moisture probe housing at either side
of the trench.   Monitoring would be a simple matter of attaching
a lead to a portable moisture meter and reading the electrical
resistance.  Graphs could be kept for each cell to maintain
"moisture profiles" of each trench.  At current (1977) prices,
moisture cells  cost about $10 to $12 each and another $10 to
$20 to place in a filled trench, depending on the equipment
used.   Placing  cells as a trench is filled can reduce placement
costs  substantially.  Complete costs for placing cells in a filled
trench could run as high as $9,000 per trench in a wet area.
Costs  would be  less in arid regions or for placement during
filling.  A portable moisture meter can be purchased for under
$300.   Maintenance would consist of periodic inspection of leads
or replacement  of faulty cells.

Monitoring Frequency

     The frequency of monitoring is a function of site climato-
logy and hydrogeology, and the completeness of the hydrogeologic
data;  it will probably vary somewhat from site to site.  As a
general rule, from a practical, cost point of view, monthly
monitoring intervals will likely suffice.  In extremely arid
regions (e.g.,  Beatty, Nevada), bimonthly sampling with weekly
sampling following major rains might be preferable.  For
excessively rainy or high-watertable sites, weekly or biweekly
sampling might  be necessary to ensure safe trench operation.

     Whatever monitoring method is selected, it should be noted
that monitoring is useless without an authority to react and
a set  of criteria specifying when or how to react.  The lack
of criteria or  authority has plagued environmental control
attempts from the beginning  and could serve to undermine any
attempts to establish safe radwaste land burial sites.
                               75

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                         BIBLIOGRAPHY
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                               79

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36.   Hawkins,  R.H.  and J.H,  Horton,   Bentonite  as  a  Protective
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                              80

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48.   Integrated Radioactive Waste Management Plan,  Savannah
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                               81

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59.   Maxwel1-Cook,  J.C,   Structural  Waterproofing.
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60.   Meyer,  G.L.   Preliminary Data on the Occurrence of
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61.   Miller,  D.W.,  F.A.  DeLuca,  and  T.L. Tessier.   Ground
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62.   Moeller, D.H.  and J.R. Ryffel.   Characteristics of
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63.   Morgan,  W.T.,  R.T.  Skrinde,  and P.C. Small.  Controlled
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                              84

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                          GLOSSARY


    (C i )
Curiv   '  - Arbitrary unit for specifying the amount
           of radioactivity.   It was originally defined
           as the rate of decay of Ig of radium, but
           it has more recently been redefined as
           3.70 x I0l° disintegrations/sec.
           (yCi - microcurie  (IQ-^Ci),
            nCi - nanocurie (10-9Ci))


Radwaste  - Radioactive wastes
Rem      - Roentgen equivalent man; radioactive dose
           unit which produces a biological  effect
           equivalent to the absorption of one
           roentgen of X'radiation
Transuranics -  Those elements having atomic numbers
           greater than 92.  In practice, plutonium
           is essentially the only element in this
           category.
                             85

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                                   TECHNICAL REPORT DATA
                            (Please read Instructions on the reverse before completing)
1. REPORT NO.
  ORP/LV-78-5
                              2.
                                                            I. RECIPIENT'S ACCESSION NO.
4. TITLE AND SUBTITLE
  Study of Engineering and Water Management Practices
  that will Minimize the Infiltration  of Precipitation
  into Trenches Containing Radioactive Waste
             5. REPORT DATE
                 September 1977
             6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
                                                            8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
  Stearns,  Conrad and Schmidt
  Consulting  Engineers, Inc.
  4014 Long Beach Blvd.
  Long Beach,  CA  90807
                                                            10. PROGRAM ELEMENT NO.
             11. CONTRACT/GRANT NO.
                68-03-2452
12. SPONSORING AGENCY NAME AND ADDRESS
  Office of Radiation Programs
  U.S. Environmental Protection Agency
  P.O. Box  15027
  Las Vegas,  NV  89114
                                                            13. TYPE OF REPORT AND PERIOD COVERED
             14. SPONSORING AGENCY CODE
15. SUPPLEMENTARY NOTES
16. ABSTRACT

       This  report is the final  output of a U.S. Environmental Protection  Agency
  contract which was funded to  review present engineering and water management practices
  to minimize the infiltration  of precipitation through  trench caps.  The  objective of
  this effort was to evaluate and compare the existing  practices in use  at sanitary
  landfills,  hazardous waste disposal facilities and  experimental burial sites, and to
  apply  these practices to the  commercial low-level radioactive waste sites.

       The  report is based on a review of the literature and general knowledge of
  the state-of-the-art in sanitary engineering developments.  The report describes
  presently  available techniques which may be applicable to current and  future shallow
  land burial operations.
17.
                                KEY WORDS AND DOCUMENT ANALYSIS
                  DESCRIPTORS
                                               b.lDENTIFIERS/OPEN ENDED TERMS
                           c.  COSATI Field/Group
  Radioactive waste (1406)
  Sanitary engineering  (1302)
 Disposal facilities
 Management practices
   18-G
   13-B
18. DISTRIBUTION STATEMENT

  Unlimited
19. SECURITY CLASS (This Report)
21. NO, OF PAGES
                                               20. SECURITY CLASS (This page)

                                                     NA
                                                                          22. PRICE
EPA Form 2220-1 (Rev. 4-77)   PREVIOUS EDITION is OBSOLETE

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