SEPA
          United States
          Environmental Protection
          Agency
Region II Office
26 Federal Plaza
New York, N.Y. 10007
EPA 902/4-86-001
November 1986
          Air
          PHOTOCHEMICALLY
          REACTIVE ORGANIC
          COMPOUND EMISSIONS
          FROM CONSUMER AND
          COMMERCIAL PRODUCTS

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                   PHOTOCHEMICALLY REACTIVE ORGANIC COMPOUND
                         EMISSIONS FROM CONSUMER AND
                              COMMERCIAL PRODUCTS
                                 FINAL REPORT
                               November 26, 1986
                                 Submitted To:

                         Paul Truchan, Project Officer
                     U.S. Environmental Protection Agency
                              Air Programs Branch
                               26 Federal  Plaza
                           New York,  Nev York 10278
                                 Submitted By:

                 Science Applications  International Corporation
                              8400 Westpark Drive
                               McLean, VA  22102
                                  Alan Jones
                                  Harvey Rich
                               Granville  Sewell
                                Michael Rogozen
                                 Michael  Katz
              EPA Contract No.  68-02-3893, Work Assignment  No.  8
                        SAIC  Project No.  2-834-07-025-68

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     This air pollution  report  is  issued by Region II, U.S. Environmental
Protection Agency  to  assist  State  and local air pollution control agencies in
carrying out their program activities.  Copies of this report may be obtained
for a nominal cost, from the National Technical Information Service, 5285 Port
Royal Road, Springfield,  VA  22151.
     This  report was  furnished  to  the Environmental Protection Agency by
Science Applications  International Corporation, 8400 Westpark Drive, McLean,
VA 22102,  in  fulfillment  of  EPA Contract No. 68-02-3893.  This report has been
reviewed by Region  II,  EPA,  and approved for publication.  Approval does not
signify that  the contents necessarily reflect  the views and policies of EPA,
nor does mention of trade names or commercial  products constitute endorsement
or recommendations  for  use.
     EPA Region  II  Publication  No.  902/4-86-001

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                              TABLE OF CONTENTS

                                                                     Page

1.   INTRODUCTION	     1-1

2.   DEFINITION OF TERMS	     2-1

3.   TECHNICAL APPROACH	     3-1

     3.1  DESCRIPTION OF SOURCES	     3-1
     3.2  METHODOLOGY			     3-2

4.   UNCERTAINTIES/DATA GAPS	     4-1

5.   RESULTS	     5-1

6.   CONCLUSIONS	     6-1


APPENDIX A -  CONSUMER PRODUCT FORMULAS AND CONSUMPTION

APPENDIX B -  REFERENCES

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                                LIST OF TABLES


Table                                                                Page

  1    AVAILABILITY OF DATA BY PRODUCT SUBCATEGORY                   4-5

  2    RELATIVE EVAPORATION RATES - ALPHABETICAL                     5-3

  3    RELATIVE EVAPORATION RATES - NUMERICAL                        5-10

  4    VOC AND PROC EMISSIONS IN CALIFORNIA                          5-18

  5    VOC AND PROC EMISSIONS IN NEW JERSEY                          5-25

  6    VOC AND PROC EMISSIONS IN NEW YORK                            5-33

  7    CONSUMER PRODUCT  SUBCATEGORIES RANKED IN ORDER OF LOW
       TOTAL  PROC  EMISSIONS                                          6-6

  8    CONSUMER PRODUCT  SUBCATEGORIES RANKED IN ORDER OF HIGH
       TOTAL  PROC  EMISSIONS                                          6-9

  9    CONSUMER PRODUCT  SUBCATEGORIES RANKED IN ORDER OF AVERAGE
       TOTAL  PROC  EMISSIONS                                          6-12

 10    VOC AND PROC RATIOS FOR PRODUCT CATEGORIES IN CALIFORNIA      6-15

 11    VOC AND PROC RATIOS FOR PRODUCT CATEGORIES IN NEW YORK        6-16

 12    VOC AND PROC RATIOS FOR PRODUCT CATEGORIES IN NEW JERSEY      6-17

 13    VOC AND PROC EMISSIONS IN CALIFORNIA                          6-18

 14    PER CAPITA  AVERAGE VOC AND PROC EMISSIONS (LB/PERSON)         6-19

 15    PER CAPITA  LOW VOC AND PROC EMISSIONS (LB/PERSON)             6-20

 16    PER CAPITA  HIGH VOC AND PROC EMISSIONS  (LB/PERSON)            6-20

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                               1.  INTRODUCTION
     Pursuant  to  the Clean Air Act, States are required to attain the Federal
ambient ozone  standard by 1987.  EPA has found that the formation of oxidants
(e.g., ozone)  is  directly related  to the emission of photochemically reactive
organic compounds (PROCs).  Therefore, EPA and the States have initiated
control programs  to reduce PROC emissions to meet the Federal ozone standard.
Organic compounds with high vapor  pressures volatilize easily and are known as
volatile organic  compounds (VOCs).  Photoreactive organic compounds (PROCs), a
subset of VOCs, are chemically reactive in sunlight.  Although substantial
controls on  PROCs are in effect, parts of California, New Jersey, and New York
will not be  able  to attain the ozone standard unless further PROC emission
reductions occur.  Preliminary emission estimates indicate that consumer and
commercial products represent a significant contribution to the uncontrolled
release of PROC.   This study was undertaken to determine whether there was
potential for  emission reductions  from the consumer product source category.

     The development of an emission reduction strategy requires an inventory
of VOC and PROC emissions from consumer and commercial products.  Since
previous inventories of this type  used information dating back to the early
1970s, EPA Regions 2 and 9, and the States of California, New Jersey, and New
York are supporting this study.  The primary goals of the study are to (1)
identify the available secondary reference sources for the inventory, (2)
assess the quantity and quality of data which may be obtained from these
references for all consumer and commercial products, and (3) accurately
determine the  quantity of VOC and  PROC emissions from consumer and commercial
products for three geographical areas.  The areas studied are: (1) the State
of California; (2) the State of New Jersey; and (2) the New York City
metropolitan area, which consists  of the five boroughs of New York City, and
Nassau, Suffolk,  Rockland, and Westchester counties.

     This report,  along with accompanying tables of emission estimates,
fulfills the requirements of Task  4 of the August 30, 1985 Work Plan.  Where
possible, SAIC has estimated use and composition data for consumer and
                                      1-1

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commercial products  (Appendix A).  SAIC has also calculated VOC and PROC
emissions for "typical" product  formulations and individual product cate-
gories, and total emissions  for  all product categories in each of the three
assigned regions (Tables 4,  5, and 6).

     The estimated emissions assume that all VOC and PROC are released to the
atmosphere.  However,  it is  likely that not all such compounds are released
immediately upon use,  some possibly not at all.  A small fraction may remain
in the  container or  become chemically or physically bound in landfills or
water systems,  thereby preventing release.  Finally, some VOC or PROC may be
consumed by microbes in sewage systems or septic tanks.
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                            2.   DEFINITION OF TERMS


     The following are definitions of  the  terms used in presenting use and
emissions data in Tables 4, 5,  and 6.


     Annual Unit Distribution - Annual unit  distribution is defined as the
     number of units  (i.e., containers, bottles, and cans, etc.) that are
     distributed or produced in a given year.  These data are based on the
     Simmons Market Research Bureau  1983 survey and a 1984 survey conducted by
     the Chemical Specialties Manufacturers  Association.  The distribution
     numbers based on the  Simmons survey were calculated by multiplying the
     estimated population  using the  product  by the quantity of the product
     used in a given  period.  The distribution number generally represents all
     product formulations  within the product category.

     Average Unit Weight - This is the average weight of all products
     distributed in a product category.  These data are primarily based upon
     surveys conducted by  the Western Aerosol Information Bureau (WAIB, 1982).

     Geographic Multiplier - The geographic  multiplier is a factor that
     compares the regional usage of  a specific product to the national
     average.  For some products, usage may  vary significantly according to
     geographic location.   For  example, use  of suntan lotions in California is
     estimated to be  1.16  times the  National average.  The geographic
     multiplier is listed  as a  fraction of the National average, where the
     National average is 1.00.  Thus, multipliers greater than 1.00 indicate
     usage is higher  than  the population in  general and vice versa for
     multipliers less than 1.00.

     The geographic multipliers were obtained using data from Simmons 1983
     Study of Media & Markets.  The  multipliers were based on data presented
     for two of the five marketing regions established by Simmons for the
     study:  northeast and Pacific.  The northeast States included
     Connecticut, Maine, Massachusetts, New  Jersey, New York, Pennsylvania,
     Rhode Island, and Vermont.  The Pacific States included Arizona,
     California, Idaho, Nevada, Oregon, Utah, and Washington.  For each
     marketing region, an  index was  calculated by dividing the percentage of
     the regional population using the product by  the percentage of the total
     U.S. population  using the  product.  This index was used as the geographic
     multiplier.  Thus, for suntan lotions,  the Simmons index for the pacific
     marketing region was  116%  or 1.16.  Since California is part of the
     Pacific region,  the geographic  multiplier for suntan lotions is 1.16.

     National Consumption  - National usage data are reported in pounds of
     product consumed annually.  Most data are based on Kline (1981, 1982).
     Data for all-purpose  cleaners and window and glass cleaners were con-
     verted from millions  of gallons to millions of pounds using a conversion
     figure of 8.33 pounds per  gallon.  The  consumption figure for shampoos
     was given by Predicasts, Inc. (1984)  to be 2.7 pounds per capita.  This
     was converted to pounds using a National population of 226,545,805.
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     Photoreactiye Organic Compounds  (PROCs) - All gaseous chemical
     compounds  that contain  the element carbon are defined as reactive
     by the EPA (Federal Register,  1983) excluding carbon monoxide, carbon
     dioxide, carbonic acid, carbonates, metallic carbides, methane,
     1,1,1-trichlorethane, methylene  chloride, trifluoromethane, trichloro-
     trifluoroethane, dichlorodifluoromethane, trichlorofluoromethane,
     chlorodifluoromethane,  dichlorotetrafluoroethane, chloropenta-
     fluoroethane, and ethane.

     Population Apportionment  - This  factor was used  to adjust national data
     to the individual regions.   It is a ratio of the population of the region
     divided  by the population of the United States (U.S. Bureau of the
     Census,  1986).   Population bases ares (1) 226,545,805 persons in the
     U.S.,  (2)  24,920,000  persons in  CA, (3) 10,803,581 persons in N.Y., and
     (4)  8,376,900 persons in  N.J.

     Relative Evaporation Rate (RER)  - A measure of the volatility of a
     compound relative to  that of butyl acetate.- A compound's RER depends
     upon its molecular weight and vapor pressure.  See Section 3 for the
     mathematical -definition.

     Seasonal Variation -  Variation in the use of a product or category of
     products from winter  to summer was investigated.  In most cases, data
     were not readily available.   The only seasonal variations reported here
     are  those  for  the use of  paints  and finishes and suntan products.  These
     figures  show  the use  of paint and suntan products in the summer compared
     with winter usage.  The summer tanning season corresponds to May to
     October  in California and June through September along the East Coast.

     Total Volatile Organic  Compound  (VOC) Emissions  - An organic compound  is
     classified as volatile  if its Relative Evaporation Rate exceeds 0.1 or if
     data for computing  the  RER are unavailable and the molecule has fewer
     than 10  carbons. Low and high VOC emission values are reported for each
     product  subcategory.  These  are  then aggregated  into a low and a high
     total annual VOC emissions estimate.

     Weight Fraction  VOC or  PROG  - This number indicates  the proportion of  VOC
     or PROC  in a given  product formulation.  Two fractions are generally
     reported for each product category.  The first is the lowest estimate  of
     VOC  or PROC emitted from  a set of formulations,  while the second is  the
     highest  estimate of VOC or PROC  emitted from the same category.  These
     fractions  may come  from different product formulations.  Weight fractions
     for  each product are  given as percent of total weight in  the individual
     product  formulations  in Appendix A.
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                            3.  TECHNICAL APPROACH

     The Work Plan identified 11 aerosol and nonaerosol product categories,
and numerous subcategories.  Tables 4, 5, and 6 report VOC and PROC emissions
for products in each of these categories.  The 11 product categories are:

     Aerosol Spray Products
     (1)  Insect Sprays
     (2)  Paints and Finishes
     (3)  Household Products
     (4)  Personal Products
     (5)  Animal Products
     (6)  Automotive and Industrial Products
     (7)  Food Products
     (8)  Miscellaneous Products

     Nonaerosol Products
     (1)  Personal Products
     (2)  Household Products
     (3)  Garage Products

3.1  DESCRIPTION OF SOURCES
     Composition and usage data for these product categories were derived from
the following sources:

     Usage Data;
     •  Chemical Specialties  Manufacturers Association, Inc., (1984),
        Pressurized Products  Survey, United States — Questionnaires for this
        survey, which  reports the number of aerosol units filled during 1984,
        were returned  by 217  companies, representing 88 percent of the
        industry total.
     •  Simmons Market Research Bureau, Inc., (1983), Simmons 1983 Study of
        Media and Markets —  This company carries out annual surveys of
        product usage  in the  United States.  A representative sample of 19,248
        adults, age 18 years  and over, living in the coterminous 48 States,
        was conducted  between September 8, 1982 and July 5, 1983.
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     •  Western Aerosol Information Bureau (WAIB) — This organization is  the
        source of the only comprehensive information available on aerosol
        product unit size.  WAIB was not able to give detailed information
        about the methodology it used to determine unit size.

     •  C. H. Kline and Co., Inc., (1981), Consumer Pesticides and Fertilizers
        — Presents use and other data based on approximately 180 interviews
        with competitive suppliers, distributors, raw material suppliers,
        government agencies, and other trade factors.  The survey was also
        based on an extensive search of published literature and a review of
        price lists, product descriptions, and other material from suppliers.
        This source is believed to be the most accurate available for use
        data.

     •  C. H. Kline and Co., Inc., (1981), Household Cleansing Products —
        These data are based on telephone interviews with 38 major suppliers
        as well as distributors, government agencies, and other trade factors.
        This source is believed to be the most accurate available for use
        data.


     Composition Datat

     •  Gosselin, Robert E., Robert P. Smith, and Harold C. Hodge, (1984),
        Chemical Toxicology of Commercial Products, 5th ed.  Williams and
        Wilkins, Inc., Baltimore, MD — This work, which presents "typical"
        formulations for consumer products, was the source of composition data
        for several product categories.

     •  Wilkenson, J.B. and R.J. Moore, eds., (1982), Harry's Cpsmeticology,
        7th ed., Chemical Publishing, New York — This volume also presents
        typical product formulations.

     •  Micromedex, (1984), Poisindex — source of composition data for a
        portion of "paints and finishes."

     •  Nowak et al., (1985), Aerosol Age — source of composition data for
        the remainder of "paints and finishes."

     •  Chalmers, Louis, revised by Peter Bath, (1979), Household and
        Industrial Chemical Specialties, vols. I and II, Chemical Publishing,
        New York — This was the only available source of formulas for several
        product categories.


3.2  METHODOLOGY FOR DETERMINING VOLATILITY OF VOCs

     A variety of formularies and market research volumes were examined, and

several associations were contacted, to obtain data on product use and

composition.  Beacause use data were not available for individual product

formulations, high and low VOC and PROC emissions were estimated for each
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product subcategory.  To develop these estimates, each formula was assumed  to
be the representative of the subproduct category.  The formula with the lowest
VOC and PROC emissions levels was then used as the low estimate and the
formula with the highest VOC and PROC emissions levels was used as the high
estimate.

     The Relative Evaporation Rate  (RER) index was used to determine the
consumer product constituents that  should be considered "volatile" and those
that should be considered  "nonvolatile."  The RER is defined as (Stratte et
al., 1978):
          RER = 0.8217 x  (Vapor Pressure) x (YMolecular Weight).

     This index expresses  the volatility of the various organic compounds
relative to  the volatility of n-butyl acetate (RER = 100).  Molecular weights
were located in the  Handbook of Chemistry and Physics (tfeast and Astle, 1981),
the Handbook of Environmental Data on Organic Chemicals (Verschueren, 1977),
and in  the on-line data base HEILBRON, which is accessed through Dialog
Information  Services, Inc.  The HEILBRON data base summarizes information from
the Dictionary of Organic  Compounds, 5th edition (1982).  Compound names and
formulas were identified using the EPA series, Toxic Substances Control Act
Chemical Substances  Inventory, Volumes II, III, and Cumulative Supplement
(USEPA, 1980).

     Many compounds  were  identified in product formulas only as proprietary
ingredients, such as "DC-193 fluid," "PVP-VA copolymer E-735," or "carbopol
934."   Others were listed  generically in classes, such as alcohol, essential
oils, or chlorinated solvents.  Where possible, the representative compounds
for each classification were used as surrogates for these classes and vola-
tility  was decided on the  basis of the surrogate.  For example, isohexane was
used for "C6 isomers" and  butyl benzyl phthalate was used for "plasticizers."
CHEMNAME, another on-line  data base, was searched for Chemical Abstracts
Service (CAS) registry numbers and molecular weights of proprietary named
chemicals.  Some compounds which could not be located using the other sources
were identified in this manner.  The CAS numbers provided reference points for
locating physical and chemical data in the HEILBRON data base.
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     Vapor pressures not available  through one of the previously mentioned
sources were computed by using  the  following formula, which relates a com-
pound's vapor pressure at 20°C  to its boiling point at 760 mm atmospheric
pressure (Hass and Newton,  1981):
          2.8808  -  log  p = ,
                            293.1 - 0.15  At
     where
               At  =  boiling  point(°C) - 20°C
            log p  =  logarithm of the observed pressure in mm Hg
                0  = entropy of vaporization at 760 mm.

The entropy of vaporization is determined from a set of curves presented by
Hass and Newton.  For  compounds whose boiling points are reported at a
different pressure  than  760 mm, the boiling point at 760 mm must first be
iteratively obtained by  a rewritten form of this formula, so that the above
computation may be  carried  out:
          B760  "  BP  +   (273.1  + Bp)(2.8808 - log p)/[0 + 0.15(2.8808 - log p)]
     where
          B   =  the  observed  boiling point at pressure P (mm)

Note that 0  is  a  function of the boiling point.  Therefore, the equation must
be solved iteratively until  successive values of B7go are very close (within
0.1°C in our  case).

     Most molecular  formulas could be identified, but boiling points and vapor
pressures frequently were not reported in the literature.  Because unknown
compounds needed  to  be systematically defined as "volatile" or "nonvolatile,"
long-chain hydrocarbons  (e.g. waxes, oils, and some esters) were considered
nonvolatile.  "Long-chain" generally meant 10 or more carbon atoms.  Data were
lacking for a large number of the compounds, many of which were fatty acid
esters.  Polymers and resins were also assumed to be nonvolatile.  All
nonvolatile compounds were assigned a vapor pressure of 0 mm, so that their
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RERs were also 0.  Substances known  to be mixtures of volatile compounds,
such as "mineral spirits" or Stoddard solvent, were arbitrarily assigned a
molecular weight of 50 and a vapor pressure of 50 mm in order to generate RERs
indicative of volatile compounds.  The RERs for these substances were 290.515.
Finally, compounds for which no physical data were available were assumed to
be nonvolatile.

     Selection of a dividing line between "volatile" and "nonvolatile" was of
necessity arbitrary, since volatility was quantified by a relative measure,
the RER.  For convenience, the lower limit of volatility was set at RER = 0.1,
or three orders of magnitude below that of butyl acetate.  Examination of
compounds whose RERs lie on either side of 0.1 confirmed that the choice was
reasonable.  Most of the compounds with RER <0.1 are solids at ambient
temperatures (e.g. thymol and benzoic acid) or are polar liquids with boiling
points  above 200°C (e.g. diethylene  glycol and myristil alcohol).  Compounds
whose RERs slightly exceed 0.1 are liquids, most of which are known to be
volatile; these include ethylene and propylene glycols.  All organic compounds
in the  listed products, except methylene chloride, 1,1,1-trichloroethane, and
carbon  dioxide, were considered reactive.  Product category and total emis-
sions in Tables 3, 4, and 5, and percentages emitted in Appendix A are
reported separately for VOC and PROC.
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                          4.   UNCERTAINTIES/DATA GAPS

     The analysis estimated VOC and PROC emissions from consumer and
commercial products by  combining composition data with distribution or use
data for product subcategories.  Composition data within each subcategory were
further aggregated from individual formulas; while national usage was
frequently derived from several types of products, such as aerosol and
non-aerosol.  Thus, at  each stage of analysis,  aggregation error enters the
result.  The extent of  this type of error is not known, although it varies
from one product subcategory  to another.  Table 1 shows the availability of
data for each product subcategory.  The following list identifies sources of
uncertainty for composition and usage data:

     Usage Data - The available use data often  encompassed broad product
categories and could not be disaggregated to individual products and formu-
lations within each subcategory.  In addition,  use data were not readily
available for many subcategories.  This was particularly true for nonaerosol
products.  Several product subcategories were therefore merged and emissions
calculated on the basis of these merged data.   Vhen aerosol and nonaerosol
products were combined,  they  were reported under aerosol/nonaerosol in Tables
4, 5, and 6.

     Population Apportionment - The data used for the population apportionment
comes from 1984 and 1985 U.S. Bureau of Census  population estimates.  The data
were obtained from telephone  conversations with Bureau of Census staff.  SAIC
believes that this data is the most accurate available.

     Geographic Multipliers - The geographic multipliers are based on the
Simmons 1983 Study of Media Markets.  The study interviewed 19,248 adults and
is representative of the U.S. population, age 18 and over living in the
contiguous 48 States.   The interview period was  from September, 1982 through
July, 1983.

     Factors influencing the accuracy of the geographic multiplier are the
number of States and the population in each marketing region, as well as the
frequency or quantity of usage within each marketing area.  For example,
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California represents over 65 percent of the population in the Pacific
marketing region.  We believe that the population of States outside
California, but vithin the Pacific marketing region, would have little
influence on the accuracy of the California data.  However, New York and New
Jersey each represent only 36 percent and 15 percent respectively of the
northeast marketing region.  Thus, other State populations could have a
significant impact on the accuracy of the usage data.  Although we are
uncertain how  this would affect typical product usage in the two States
compared to the Simmons regional data, we believe the influence in the
estimated error to be minimal.  Our belief is based on Simmons' judgment in
establishing homogeneous marketing areas (i.e., similar consumer product usage
patterns throughout a marketing area).

     Product use within each region varies more than use in all regions
combined.  Use within regions may vary from 15 percent less to 20 percent
greater than the national average.  However, an average use weighted by State
population does not differ greatly from a nonweighted use, within an entire
region.  Therefore, it is reasonable to assume that the statewide geographic
multiplier is  similar to the regional one.

     The error in estimating PROC from the geographic multiplier is small
compared to other uncertainties, such as those present in the formulation and
consumption data.

     Formulation Data - The accuracy of the formulation data presented in this
report cannot  be easily assessed.  For any given product category, a wide
range of formulas may be in use.  These formulations vary significantly
according to the quality of the product and its specific use.  Many of the
formulas, however, are proprietary or contain compounds that are proprietary.
Although formulations for specific brands were included when available, most
of the ones available for this report were "generic" formulations provided to
our references by the manufacturers of the product ingredients.  These
formulations were verified where possible by a shelf survey.  Few product
labels show percent by weight formulations.  A somewhat larger number list
ingredients.   However, generic terms are often used for these ingredients
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(e.g., inert ingredients, volatile organic compounds, driers, alcohol, or

plasticizer).  Frequently, only the active ingredient is listed on the label.

All formulas are assumed  to be representative of their product subcategory.
The formula data were often six to ten years old.  Even where formularies were

recent, the reported composition was probably two or three years behind

current production lines.  The degree of obsolescence of these formulas is

difficult to judge.  Formulas are continually changing over time.  These

changes are caused by improvement in product formulations, regulations such as

the chlorofluorocarbon ban, and the changing cost of intermediates.  For the

purposes of this report,  product lines are assumed to evolve slowly and that
all recent arrivals contain similarly volatile species.


     Other formula uncertainties include the following:


     •  Many formulations included chlorofluorocarbons as the propellant
        although they have been banned in most consumer products.  Attempts
        were made to verify,  through industry sources, the various assumptions
        made regarding the type and quantity of the replacement propellant
        through industry  sources.

     •  In several cases  aerosol and nonaerosol formulations were combined.
        This was necessary because only aggregated use data were available.
        Composition and weight might be substantially different for aerosol
        and nonaerosol products.

     •  Formulations for  many products consisted of percentage ranges for one
        or more ingredients.  It was often difficult to clearly delineate the
        lower and upper bounds of volatile compounds for these products.  This
        problem arises because a decrease in one ingredient must be compen-
        sated for by an increase in one or more other ingredients.  Some of
        the replacement ingredients may be volatile while others are non-
        volatile.  Our best professional judgment was used in such cases.  It
        is likely that results were not substantially affected in these cases.

     •  Very few nonaerosol formulas were available for this report.

     •  Product formulation descriptions occasionally aggregate dissimilar
        ingredients, reporting the percent by weight of groups rather than of
        individual compounds.  For example, "xylol" and "driers" were combined
        for the paints and finishes product category, even though they are
        different compounds and have very different volatilities.

     •  Product ingredients were frequently reported as classes of compound,
        such as "alcohol" and "plasticizer."  We had to choose a "typical"
        ingredient and decide volatility on the basis of this surrogate.
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     •  SAIC estimated the low and high VOC and PROC emissions for each
        product subcategory by finding the formulation with the lowest weight
        percent and the one with the highest weight percent VOC and PROC.
        This means that subcategories with many formulations may have a
        considerable range between the low and high emission estimate.  One
        particularly troublesome subcategory was insecticides, which comprised
        primarily space insecticides, but also included one dust and one
        target aerosol.  PROC varies from 0 percent in one formula to 100
        percent in another.

     •  Although a number of other formulas were available in Gosselin (1985),
        we chose "typical" formulas for product subcategories to reduce the
        data set to a manageable size.  Variation in chemical content from the
        formulas that were not chosen to those that were used generated
        additional uncertainty.


     Ratio of Seasonal Variation - The seasonal variation of product usage was

only included in the paint and suntan products calculation.  The ratio was not

included in other consumer product subcategories because of a lack of data
and, in many cases, the small likelihood of any significant variation between

seasons.  For paint products, we assumed that 57.5 percent was used during the
ozone season. These figures are based on monthly sales figures collected by
the Bureau of census and are believed to be accurate.  For suntan products,
100 percent was assumed to be used during the ozone season.  Within the states

of New York and New Jersey, use outside of the summer season was assumed to be

negligible.  In California, we assumed that use outside of the summer season

would be minimal. Even though the warm climate permits sunning during the

entire year, the less direct sun would reduce the need for protective

sunscreens or tanning lotions.
                                      4-4

-------
                                  TABLE 1.  AVAILABILITY OF DATA BY PRODUCT SUBCATEGORY1
i
en
Category

Insecticides

Insect Repellants

Moth Control Products

Animal Insecticides

Herbicides and Fungicides

Paints, Primers, Varnishes

Paints and Finishes -
  Related Products

Room Deodorants and
  Disinfectants

Tile and Bathroom Cleaner

Oven Cleaners

Rug and Upholstery Cleaner

All Purpose Cleaner

Window and Glass Cleaner

Laundry Products - aerosol

Laundry Products - aerosol
  and nonaerosol

Shoe Polishes, Waxes,
  and Colorants
Units
Distributed
NA
NA
NA
NA
NA
Yes
Yes
Yes7
NA
NA
NA
NA
NA
Yes
Average
Product
Weight
NA
NA
NA
NA
NA
Yes
Yes
Yes
NA
NA
NA
NA
NA
Yes
National
Consumption
Yes
Yes
Yes
Yes
Yes
NA
NA
NA
Yes
Yes
Yes
Yes8
Yes8
NA
Population
Apportionment
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Geographic
Multiplier
No
No
No
No
No
Yes
No
Yes
No
Yes
No
Yes
Yes
No
Product
Formulations
Yes3
Yes4
Yes4
Yes4'5
Yes
Yes6
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
                                     NA
                                     NA
NA
NA
Yes
Yes
Yes
Yes
No
No
Yes
Yes

-------
     D/834-025-68a/»9
                             TABLE 1.   AVAILABILITY OP DATA BT PRODUCT SUBCATEGORY1  (Continued)
•P-
i
Category

Other household Products
  - aerosols

Other household Products
  - aerosols and nonaerosols

Adhesives

Caulking and Sealing
  Compounds

Shaving Cream

Hair Products - aerosols

Other Hair Care Products

Pharmaceuticals

Colognes, Perfumes,
  Aftershaves

Personal Deodorants
     Other Personal Care Products
     Automotive Cleaners
     Automotive Engine Degreasers

     Lubricants and Silicones

     Undercoat ings
     Brake Cleaners
                                    Units
                                 Distributed
                                     NA
                                     NA
                                     NA
                                     Yes
                                     Yes
NA
                                      Yes
                                      Yes
                                      Yes
                                 Yes
                                 Yes
                                 Yes
                                 Yes
                                 Yes
                                 Yes
           Average
           Product
           Weight
            NA
            NA
            NA
            Yes
            Yes
NA
            Yes
            Yes
            Yes
            Yes
            Yes
            Yes
            Yes
            Yes
            Yes
             National
           Consumption
               Yes
               Yes
                                                                   14
               Yes
               NA
               NA
Yes
               NA
                                                                   14
                              11
               NA
               NA
               NA
               NA
               NA
               NA
               NA
               NA
             Population
           Apportionment
                Yes
                Yes
                Yes
                Yes
                Yes
                Yes
                Yes
                Yes
                Yes
                Yes
                Yes
                Yes
                Yes
                Yes
Geographic
Multiplier
   Yes
   No
   No
   Yes
   Yes
                                                                                                  10
   Yes
   Yes
                                                                                                  12
   Yes
   Yes
   Yes
   No
   No
   No
   No
   No
  Product
Formulations
    Yes
    Yes
    Yes
    Yes
    Yes
    Yes
    Yes
    Yes
    Yes
    Yes
    Yes
    Yes
    Yes
    Yes
    No
     Tire Inflator and Sealant
                                 Yes
            Yes
               NA
                Yes
   No
    No

-------
D/834-025-68a/#9
                        TABLE 1.   AVAILABILITY OF DATA BT PRODUCT  SUBCATEGORY1 (Continued)
Category

Carborator and Choke Cleaner

Engine Starting Fluid

Auto Windshield Vasher
  Fluid and Deicer

Floor Polishes and Waxes

Metal Cleaners and Polishes

Automotive Antifreezes

Car Polishes and Waxes

Laundry Products

Household Polishes
Units
Distributed
Yes
Yes
Yes13
MA
NA
NA
Yes
NA
NA
Average
Product
Weight
Yes
Yes
Yes13
NA
NA
NA
Yes
NA
NA
National
Consumption
NA
NA
NA
Yes
Yes
Yes
NA
Yes
Yes
Population
Apportionment
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Geographic
Multiplier2
No
No
No
Yes
No
No
Yes
No
Yes
Product
Formulations
Yes3
No
Yes13
Yes
Yes
Yes
Yes
Yes
Yes
 The data for all product categories are subject to the uncertainties and limitations described in the text.
 Other limitations and assumptions pertaining to specific categories are noted below and are further explained
 in the text.

 Where the goegraphic multiplier was not available, the value 1.0 was used for the purposes of the
 calculations.

 Because complete formula data was not available for some aerosols, the percentage of propellant was estimated
 using data from WAIB and CSMA.  See text for methodology and assumptions.

4The formulas available for the report showed a large percentage of inert ingredients.  These inert
 ingredients may or may not include propellants and other VOCs.  See text for further explanation.
'Some of the formulas had composition data that did not equal 100%.  In these cases, half of the unknown
 ingredients were assumed to be volatile.

-------
    D/834-025-68a/#9
                          TABLE 1.   AVAILABILITY OF DATA BY PRODUCT SUBCATEGORY1  (Continued)
     For the purposes of emissions calculations,  halogenated hydrocarbons  were  replaced  by aliphatic  hydrocarbons
     in some formulas.  See text for further explanation.
    •j
     See text for methodology of this calculation.


     See text for methodology of this calculation.

    g
     Not for all products


      For hair spray only.


      See text for methodology of this calculation.


      For fungicides only.


      For Deicer only.


      Includes industrial as well as consumer adhesive use.
i
oo

-------
E/834-025-68a/#13

                                  5.   RESULTS

     VOC or PROC emissions were computed using  the  following  two formulas:

     Total VOC or PROC Emissions  =

         1.   (units distributed)  (avg. prod, wt.)
              (pop. apport.)  (geogr. mult.)  (wt. fraction VOC  or PROC)
         2.   (National consumption) (pop. apport.)
              (geogr. mult.)  (wt.  fraction VOC or PROC)

Sample calculations illustrating  equation 1, for a  low PROC emissions estimate
and a high PROC emissions estimate for Pharmaceuticals in California are:

     1.  PROC Emissions  =   (43.7 x 106 units)(0.25 lb)(0.11)(1.08)(0.70)
         low  est.            (1/2  x 103 tons/lb)
                         =   454.26 tons
         PROC Emissions  =   (43.7 x 106 units)(0.25 lb)(0.11)(1.08)(0.99)
         high est.           (1/2.0 x  103 tons/lb)
                         =   642.46 tons

Sample calculations illustrating  equation 2, for a  low PROC emissions estimate
and a high PROC emissions estimate for all-purpose  cleaners in California are:

     2.  PROC Emissions  =   (512  x 10s lb)(0.11)(1.07)(0.02)(l/2 x 103  tons/lb)
         low  est.
                         =   602.62 tons
         PROC Emissions  =   (512  x 106 lb)(0.11)(1.07)(0.41)(l/2 x 103  tons/lb)
         high est.
                         =   12353.79  tons

     The molecular weights,  boiling points,  vapor pressures and RER's for the
chemical compounds listed under product formulations  in Appendix A are
arranged in alphabetical order in Table 2.   The compounds have been reordered
numerically by RER in Table  3, in order to  more readily discern the division
between volatile and nonvolatile  compounds.
                                      5-1

-------
E/834-025-68a/#13

     We decided to use low VOC/PROC and high VOC/PROC emissions rather  than
some form of VOC/PROC weights by product  type, which would then be multiplied
by the distribution or consumption data to yield the emission total for a
given subcategory.  It was felt that  the  data uncertainties, discussed  earlier
in the report, both within products and within product subcategories, were so
large that such results would be highly misleading.  For example, it was not
possible to know how widely an individual product, versus other products
within a subcategory, was distributed in  each region.  Given these problems,
any weights which might be applied to the distribution figures, and the
emission estimates that would result, would present a spurious picture  of the
accuracy of these estimates.  For this reason, a range of values depicting
emission boundaries would make the reader more aware of the data limitations.

     Annual VOC and PROC emissions are presented in Tables 4, 5, and 6.  Low
and high estimates are based upon the likely range of VOC or PROC emissions in
each product category.  For example,  the  ratio of VOC present in formulations
in "paints and finishes" in California ranges from 0.73 to 0.87 and is  entered
under "weight fraction VOC."  The appropriate fractions are multiplied  to
yield annual low and high estimates for each product subcategory.  The  low and
high weight fractions were chosen by  examination of the weight percents under
the product formulas listed in Appendix A.  If formulas 1 and 4 were chosen
for a particular product subcategory, then formulations 1,4 were listed in
Tables 4, 5, and 6 for that subcategory.  Product category subtotals were
obtained by summing VOC and PROC emission estimates for subcategories.
Addition of product category subtotals produced total emission estimates for
each region.

     Tables 4, 5, and 6 report data for all product categories and
subcategories listed in the August 30, 1985 Work Plan, when data were
available.  Where data were not available or incomplete, we listed NA in the
emission estimate column.  Aerosol food products were omitted from the  final
emission inventory since the propellent used in these products is nitrous
oxide and therefore not an organic compound (Kirk-Othmer, 1978).
                                      5-2

-------
PRODUCT NAME
                  TABLE 2
 RELATIVE EVAPORATION RATES - ALPHABETICAL

BP (C)   PRESSURE        HW       VP      RER    COMMENTS

                     204.27      .00      .01
                                        307
                                      118.1
                                       56.2
2-FUHALDEHYDE, 2,3:4,5-815-
  (2-BUHLENE) TETRAHYDRO
2.4 BIS (ISOPROPYLAM1N01-6
  METHOXY-S-TRIAZINE
2,4,5-TRICHLOROPHENOXYACET1C
  ACID, POTASSIUM SALT
4-AHlNO-3,5,6-TR!CHLOROPlCOLINlC ACID
5-BENZYL-3-FURYL	
AC POLYETHYLENE 6Z9
ACETIC ACID
N-ACETYLETHANOLANINE
ACETONE
ACRYLIC RESIN
ACRYSOL LEVELING AID
ADIPIC ACID
ALCOHOL 740 P
ALCOHOL-SOLUBLE LANOLIN
ALIPHATIC HYDROCARBONS
ALIPHATIC THINNER'
ALKYD RESIN
ALKYL ARYL SODIUM SULFONATE
ALKYL DIETHANOLAM1NE
ALKYLDIMETHYLBENZYLAMMONIUM
ALKYLDIMETHYLBENZYLAMHONIUN CHLORIDE
ALLETHRIN, D-TRANS                  302.413
ALUMINUM PHENYLSULFONATE
AMINES
2-AHINO-2-METHYL PROPANOL              165.5
AMMONIUM CITRATE
AMMONIUM LAURYL ETHER SULPHATE
AMMONIUM OXALATE
AKMONYX 4002
AMP                                     165
AMPD                                   151.2
AHPHOHER
AMYL ACETATE                            148
ANTARON FC-34
AROMATIC HYDROCARBONS
AROMATIC KETONE SOLVENT
BAYGON
BEESVAX
BENZETHONIUH
BENZOIC ACID                        249,133
BENZYL BENZOATE                       323.5
0-BENZYL-P-CHLOROPHENOL                 161
BIOC IDE
BRONOCIL
BUTADIENE-STYRENE COPOLYMER
BUTANE                                  -.1
                                                                              0.00




60.05
50.00
58.08



50.00

86.17
86.17


88.13




73.14
89.14


142.11

89.14
10 105.14

737 130.20

92.10
92.10
209.24


10 122.13
212.25
3.5 218.68



58.12



0.00
10.53
50.00
132.49
0.00


50.00
0.00
50.00
50.00
0.00
0.00
.01



0.00
200.00
.33
0.00
0.00
0.00
0.00
.44
.00
0.00
3.05
0.00
22.00
22.00

0.00
0.00
.00
.00
.00


0.00
1544.67
0.00
0.00
0.00
0.00
67.68
290.51
829.65
0.00
0.00
0.00
290.51
0.00
381.38
381.38
0.00
0.00
.07
0.00
0.00
0.00
0.00
1405.47
2.53
0.00
0.00
0.00
0.00
3.41
.00
0.00
28.55
0.00
173.49
173.49
0.00
0.00
0.00
.03
.00
.00
0.00
0.00
0.00
9676.33
                                                                                      SALT-AS3UHED NONVOLATILE
                                                                                      ASSUMED NONVOLATILE
                                                                                      NO DATA - ASSUMED NONVOLATILE
                                                                                      LARGE POLYMER
                                                                                      RESINS ASSUMED NONVOLATILE
                                                                                      NO DATA - ASSUMED NONVOLATILE
                                                                                      HIGH-C FATTY ACIDS NONVOLATILE

                                                                                      HIGH-C FATTY CMPDS NONVOLATILE
                                                                                      USED HEXANE AS REPRESENTATIVE
                                                                                      USED HEXANE AS REPRESENTATIVE
                                                                                      RESINS ASSUMED NONVOLATILE
                                                                                      SALT
                                                                                      USED ETHYL DIETHANOLAMINE
                                                                                      NO DATA - ASSUMED NONVOLATILE
                                                                                      SALTS ASSUMED NONVOLATILE .
                                                                                      HIGH-CARBON ESTER-NONVOLATILE
                                                                                      SALTS ASSUMED NONVOLATILE
                                                                                      SURROGATE'DIETHYLAMINE

                                                                                      SALT ASSUMED NONVOLATILE
                                                                                      HIGH-CARBON SALT
                                                                                      NONVOLATILE SALT
                                                                                      VERY HIGH-CARBON COMPOUND
                                                                                      NO DATA - ASSUMED NONVOLATILE
                                                                                      USED N-AMYLACETATE
                                                                                      POLYMERS ASSUMED NONVOLATILE
                                                                                      SURROGATE - XYLENE
                                                                                      SURROGATE - XYLENE
                                                                                      CRYSTALLINE-ASSUMED NONVOLATILE
                                                                                      WAXES ASSUMED NONVOLATILE
                                                                                      NO DATA - ASSUMED NONVOLATILE
                                                                                      NO DATA - ASSUMED NONVOLATILE
                                                                                      SOLID - ASSUMED NONVOLATILE
                                                                                      LARGE POLYMER NONVOLATILE
                                                         5-3

-------
                                                TABLE 2 (Continued)
                                     RELATIVE EVAPORATION RATES - ALPHABETICAL
PRODUCT NAME
HP (C)   PRESSURE
ny
VP
RER    COMMENTS
BUTYL CELLOSOLVE
Cl.S.P. COMPOUNDS
CALCIUM THIQGLYCOLATE TRIHYDBATE
CALGQN
L-CAMPHOR
CARBARYL
CARBITOL
CARBOPOL 934
CARBOIYMETHYL CELLULOSE
CARNAUBA WAX
CARTARETINE F4
CATIONIC CELLULOSE
CELLOSOLVE ACETATE
CELLULOSE ACETATE BUTYRATE
CERES IN'
CETYL ALCOHOL, RAKES
CHLOR- AROMATIC SOLVENTS
CHLOR. PARAFFIN PLASTIC I ZER
CHLOIDANE
CHLORINATED SOLVENTS
CHLOROSULFONATED POLYETHYLENE
CITRIC ACID
CKANINO BETA1NE
COCONUT .AMI DOPROPYL-
3-D1METHYLAMINE BETA1NE
COCONUT OIL AHINE
COLOR
COLOR MIX
CONDANOL (DBS,DLS,MLS,SB/L)
COPPER NAPHTHENATE
COPPER UNDECYLENATE
CRESOL (0-.M-.P-)
CRQHEEN
CRYSTALLINE WAX
CUBE RESINS
CYCLOPROPANE CARBOXYLATE
D.L-CAMPHOR
D-CAHPHOR
DC 193 FLUID
DDVP
DEHYDROGENATED RESIN
DEODORANT
DETERGENT
H.N-DIALKYL-M-TOLUAMIDE
DIBUTYL PHTHALATE
0-D1CHLOROBENZENE
DICHLOROMETHANE
DICHLOROPENTANE
DIETHYLENE GLYCQL
170



SUBLIMES 9

202





156


190





DECOMPOSES














SUBLIMES
SUBLIMES §

140



160
340
130.5
41

245
118.17



152.24

134.20





132.16


15
112.56

409.78
50.00

192.12









108.13




152.24
152.24

20 220.98

50.00

19 191.27
278.35
147.00
84.93
141.04
106.12
.60

0.00

.28
o.oo-
.21
0.00
0.00
0.00

0.00
1.20
0.00

0.00
8.80


50.00

0.00
0.00

0.00
0.00
0.00

0.00

0.00
.11
0.00
0.00
0.00

.28
.28
0.00
.01
0.00
50.00
0.00
.00
.00
.89
349.00
14.02
.00
5.36
0.00
0.00
0.00
2.81
0.00
1.99
0.00
0.00
0.00
0.00
0.00
11.34
0.00
0.00
0.00
76.72
0.00
0.00
290.51
0.00
0.00
0.00

0.00
0.00
0.00
0.00
0.00
0.00
0.00
.96
0.00
0.00
0.00
0.00
2.81
2.81
0.00
.11
0.00
290.51
0.00
.02
.00
8.89
2642.83
136.81
.02
E.G. MONOBUTYL ETHER
NO DATA - ASSUMED NONVOLATILE
SALTS ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE

NONVOLATILE CRYSTAL AT ROOM TEMP

NO DATA - ASSUMED NONVOLATILE
LARGE POLYMER
VAXES ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE

LARGE POLYMER
NO DATA - ASSUMED NONVOLATILE .
HIGH-CARBON ALCOHOL - NONVOLATILE
SURROGATE'HONOCHLQROBENZENE
SURSOGATE=BUTYL BENZYL PHTHALATE
FROM STRUCTURE, PROBABLY NON-VOL

POLYMERS ASSUMED NONVOLATILE
ASSUMED NONVOLATILE
LONG-CHAIN POLYMER

LONG-CHAIN POLYMER
HIGH-CARBON
NO DATA - ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
NONVOLATILE SALT
METALLIC SALT
HIGH-CARBON SALT - NONVOLATILE
RER DERIVED FROM AVG RER'S
NO DATA - ASSUMED NONVOLATILE
VAXES ASSUMED NONVOLATILE
RESINS ASSUMED NONVOLATILE
USED CYFQTHRIN (HIGH-CARBON)


NO DATA - ASSUMED NONVOLATILE

RESINS ASSUMED NONVOLATILE

SURROGATE-SODIUM LAUHYL SULFATE
USED N,N-DIETHYL-H-TOLUAMIDE


SAME AS METHYLENE CHLORIDE
RER DERIVED FROM AVG BES'S

                                                            5-4

-------
                                                TABLE 2  (Continued)
                                     RELATIVE EVAPORATION RATES - ALPHABETICAL
PRODUCT NAME
BP (C)   PRESSURE
nu
VP
RER    COMMENTS
DIETHYLENE GLYCOL MONONETHYL ETHE
DIHETHYCONE COPOLYOL
DIMETHYL ETHER
DIHETHYLENE OXIDE
DIOCTYL PHTHALATE PLASTICIZER
DIPROPYLENE GLYCOL
DIPROPYLENE aYCOL HONOHETHYL ETH
DITHIQ-BIS-STEARYL PROPIONATE
DODECYL BENZENE SULFONATE
DOU 276-V9
DRIERS
DUREZ (14000,16470,22008)
DUREZ (19788,12686,12687)
DUREZ (26141,26739,26799)
DUREZ 7421A
EDTA
ELASTOHERIC BINDER
EMOLLIENT
EHULPHOR ON-870
EHULSIFIERS, HUH ECT ANTS, VAXES
ENDOSULPHAN
ESSENTIAL CEDAR OIL
ESSENTIAL OIL
ESTERS AND KETONES (ACETONE)
ETHANOL
ETHANOLAHINE
ETHOIYLATE TRIDECYL ALCOHOL
ETHOXYLATED FATTY ALCOHOL SULFATE
ETHYL ALCOHOL
ETHYL ALCOHOL OP
ETHYLENE BICHLORIDE
ETHYLENE GLYCOL
ETHYLENE GLYCOL HONOBUTYL ETHER
ETHYLENE GLYCOL NONOETHYL ETHER
ETHYLENE GLYCOL DISTEARATE
2-ETHYL-l,3-HEXANED10L
2-ETHYL HEXYL SALICYLATE
FATTY ACID AMIDES
FATTY ACID SOAP
FISH OIL
FLU (LAN
FOAM STABILIZERS
FOLPET
FORMALDEHYDE
FORMALIN
FRACTAL A
FRAGRANCE
FRAGRANCE. DYE
GANTREZ ES 22B OR ES 425
159

-25

385
292/232
187.2

















78.5
172


78.4
78.4
83.5
198

135

244






296.555
-20
-20




120.15

46.70
44.05
390.56
134.20
162.23















50.00
50.00
46.07
61.08


46.07
46.07
99.00
62.10
118.17
90.10

146.23







30.00
30.00

50.00
50.00

1.88
0.00
3581.69
1095.00
.00
.01
.46
0.00
0.00

0.00
0.00
0.00
0.00
0.00


0.00

0.00


50.00
50.00
43.90
.40
0.00
0.00
43.90
43.90
61.00
.06
.60
3.80
0.00
.00
0.00
0.00
0.00
0.00
0.00


3243.38
3243.38

50.00
50.00
0.00
16.96
0.00
20112.19
5971.73
.00
.10
4.76
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
290.51
290.51
244.84
2.57
0.00
0.00
244.84
244.84
498.72
.39
5.36
29.64
0.00
.02
0.00
0.00
0.00
0.00
0.00
0.00
0.00
14597.26
14597.28
0.00
290.51
290.51
0.00

POLYMERS ASSUMED NONVOLATILE



RER SHOULD BE < 0.1

HIGH-CARBON ESTER - NONVOLATILE
HIGH-CARBON ESTER
NO DATA - ASSUMED NONVOLATILE
ASSUMED TO REMAIN IN THE COATINGS
PHENOL-FORMALDEHYDE RESIN
PHENOL-FORMALDEHYDE RESIN
PHENOL-FORMALDEHYDE RESIN
PHENOL-FORMALDEHYDE RESIN
NO DATA - ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
PROBABLY NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
FUNCTION IMPLIES WON VOLATILITY
HO DATA - ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE




LONG-CHAIN ALCOHOL
HIGH-CARBON ASSUME NONVOLATILE

SAME AS ETHANOL




LONG-CHAIN ESTER

HIGH-CARBON ACID - NONVOLATILE
SURROGATE'. NYLON; ASSUMED NONVQLAT
SOAPS ASSUMED NONVOLATILE
ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
CRYSTALLINE- ASSUMED NONVOLATILE


NO DATA - ASSUMED NONVOLATILE
NO DATA - ASSUMED VOLATILE

PROBABLY A RESIN - NONVOLATILE
                                                         5-5

-------
                                                 TABLE 2 (Continued)
                                      RELATIVE EVAPORATION RATES - ALPHABETICAL
PRODUCT NAME
    BP (C)   PRESSURE
                   VP
                     RER    COMMENTS
GELVA (TS 22,23,30,31,35)
GLYCEROL
GLYCOL ETHER
GRANULAR MINERAL BASE
HALOGENATED HYDROCARBON PRQPELLAN
HARD VAXES
HQECHST VAX
HUMECTANTS
HYDROCARBON PRQPELLANT
HYDROGENATED RESIN ESTER
HYDROIYALXYL CELLULOSE (KLUCEL HA
INERT INGREDIENTS (PESTICIDES)
ISOBUTANE
ISOBUTYLENE POLYMERS
1SOOCTYL ESTERS
ISOPARAFFIN1C SOLVENT
ISOP80PANOL
ISQPRQPYL ALCOHOL
1SOPHOPYL HYRISTATE
0-ISQPROXYPHENYL HETHYLCARBABATE
KELTHANE
KELZAN
KEROSENE
KOSOL
KP-UO
LANETO 100
LANOLIN
LATEX POLYMER ACRYLIC RESIN
LAURIC ACID
LAURIC DIETHANOLAHIDE
HALATH10N
MBTS (2-BENZOTHIAZOLYL SULFIOE)
MENTHOL
NETHOXYCHLOR
METHYL ALCOHOL
NETHYL ANTHRANILATE
METHYL P-HYDROXYBENZOATE
NETHYLBENZETHONIUH CHLORIDE
METHYLENE CHLORIDE
HGK
HICROCRYSTALLINE UAX
KILLED PALE CREPE
HILLED SMOKE RUBBER
MINERAL OIL
MINERAL SPIRITS
NIRANOL C2HSF
MONAHID 716
HONOETHYLENE GLYCOL
MONO ETHYL ETHER
DECOMPOSES 9 290
       -.5
      60.3
      62.4
      82.4
     192.6

    370.49
20
       131

     156.5

       216

        65

     223.3

        41
       307
.7
       92.11
       90.10

       50.00
                          58.12
 86.18
 60.10
 60.10
270.46
                          50.00
 1    200.33
330.35
332.47
156.27

 32.04

152.15

 84.93
204.27
       198
                          50.00
       62.10
       90.10
            .00
           3.80

          50.00
           0.00
           0.00
           0.00
        1544.67
           0.00
           0.00
       58.12  1566.19
168.34
 34.82
 34.82
  0.00
  0.00

  0.00
 50.00
  0.00

  0.00
  0.00
  0.00
  0.00
  0.00
   .00

   .15
  0.00
 92.39
  0.00
   .07
  0.00
365.66
   .00
  0.00
  0.00
  0.00
  0.00
 50.00
  0.00
  0.00
   .06
  3.80
   0.00
    .00
  29.64
   0.00
 290.51
   0.00
   0.00
   0.00
9676.33
   0.00
   0.00
1511.56
9811.14
   0.00
   0.00
1284.09
 221.79
 221.79
   0.00
   0.00
   0.00
   0.00
'290.51
   0.00
   0.00
   0.00
   0.00
   0.00
   0.00
   0.00
    .00
   0.00
   1.54
   0.00
 429.70
   0.00
    .67
   0.00
2768.98
    .01
   0.00
   0.00
   0.00
   0.00
 290.51
   0.00
   0.00
    .39
  29.64
POLYVINYL ACETATE RESIN

SURROGATED. G. NONOETHYL ETHER
SOLID - ASSUMED NONVOLATILE

VAXES ASSURED NONVOLATILE
VAXES ASSUMED NONVOLATILE
FUNCTION IMPLIES NONVOLATILE
SURROGATE:BUTANE
RESINS ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
RER=VTD AVG OF TYPICAL INGRED.(2)

POLYMER - ASSUMED NONVOLATILE
FAIRLY HIGH CARBON ESTER
SURROGATE -- ISOHEXANE
HIGH-CARBON ESTER - NONVOLATILE
Cll COMPOUND ASSUMED NONVOLATILE
CRYSTALLINE-ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
KNOUN TO BE VOLATILE
STARCH (POWDER)
NO DATA - ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
ASSUMED NONVOLATILE
RESINS ASSUMED NONVOLATILE
HIGH-CARBON FATTY ACID-NONVOLATIL
HIGH-CARBON AMIDE - NONVOLATILE

CRYSTALLINE AT ROOM TEMP.

NONVOLATILE CRYSTAL AT ROOM TEMP

NO DATA - ASSUMED NONVOLATILE

SALTS ASSUMED NONVOLATILE

MGK 11 USED AS TYPICAL COMPOUND
VAXES ASSUMED NONVOLATILE
SOLID AT AMBIENT TEMPERATURE
SOLID AT AMBIENT TEMPERATURE
NO DATA - ASSUMED NONVOLATILE
KNOWN TO BE VOLATILE
HIGH-CARBON SALT
NO DATA - ASSUMED NONVOLATILE
                                                         5-6

-------
                                                TABLE 2 (Continued)
                                     RELATIVE EVAPORATION RATES - ALPHABETICAL
PRODUCT NAME
BP (C)   PRESSURE
VP
8ER    COMMENTS
HQNOGLYCEROL P-AHINOBENZOATE
HONURON
HORPHOL1NE 128
HYRISTIC ACID 250.5
MYRISTIL ALCOHOL 263.2
HAPHTHALENE 217.9
NEOPBENE
NITROCELLULOSE
NITRQPROPANE (1-.2-)
N-OCTYL-BICYCLOHEPTENE DICARBOXINIDE
NONYLPHENOXY ACETIC ACID
OILS
OLE 1C ACID 360
OXYGENATED ORGANIC ACIDS
PALMITIC ACID 350,267
PARAFFIN WAXES
PENTANE
PERCHLOROETHYLENE 121.4
PERFUME
PERFUME IN ALCOHOL
PERFUME OIL
PETREI 7-75T (DRY) 136
PETROLEUM AND SYNTHETIC VAXES
PETROLEUM DISTILLATE (NAPHTHA)
PETROLEUM ETHERS
PETROLEUM OIL
PETROLEUM SOLVENTS
PHENOLIC RESIN
PICLORAH
PINE OIL 155
PIPEBOMYL BUTQXIDE 160
PLASTIC
PLASTICIZER (D60-.3GH-)
PLURONIC F 108 DETERGENT
POLAVAX A 31
POLY-BETA-PINENE RESIN
POLYACRYLATE
POLYACRYLIC ACID (40X AQ.) H.U.10
PQLYD1 METHYLS I LQIANE
POLYETHOXYLATED (75 EQ) LANOLIN
POLYETHYLENE
POLYETHYLENE GLYCOL (400) MONOLAU
POLYISOBUTYLENE (TRI-,TETRA«ER- )
POLYOXYETHYLENE (2) CETYL ETHER 270
POLYOXYETHYLENE SORBITAN MONOSTEA8ATE
POLYQUATERNIUH 4
POLYTRIHETHYLDIHYDRO-QUINOLINE
POLYVINYL ACETATE
POTASSIUM SOAP OF OLE 1C ACID


87.12
100 228.38
214.40
128.16


89.09

50.00

282.46
50.00
100 256.43

72.15
165.83
50.00
50.00
50.00
11 234.30

50.00
90.10
50.00
50.00


136.23
1 338.44

312.36









196.38
466.39





0.00

8.00
.00
.00
.21
0.00
0.00
9.38

50.00
0.00
0.00
50.00
0.00
0.00
430.00
14.00
50.00
50.00
50.00
.01
0.00
50.00
3.80
50.00
50.00
0.00

3.00
.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00

0.00

0.00
.53
.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
61.36
.00
.01
1.91
0.00
0.00
72.78
0.00
290.51
0.00
0.00
290.51
0.00
0.00
3001.23
148.14
290.51
290.51
290.51
.07
0.00
290.51
29.64
290.51
290.51
0.00
0.00
28.75
.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
5.71
.14
0.00
0.00
0.00
0.00
0.00
HIGH-CARBON ESTER - NONVOLATILE
PROBABLY AN OIL




LARGE POLYMER
LARGE POLYMER
RER DERIVED FROM AVG RER'S
HIGH-CARBON CMPD - ASSUMED NONVOL
HIGH CARBON SOLID
ASSUMED TO BE HIGH-C FATTY ACIDS
NEAR SOLID AT AMBIENT TEMP.
NO DATA - ASSUMED VOLATILE
HIGH-CARBON FATTY ACID-NONVOLATIL
VAXES ASSUMED NONVOLATILE





USED 2-ACETYL BENZOFURAN
VAXES ARE NONVOLATILE
KNOVN TO BE VOLATILE
SURROGATE - MONOETHYL ETHER
ASSUMED VOLATILE
KNOVN TO BE VOLATILE
RESINS ASSUMED NONVOLATILE
ASSUMED NONVOLATILE
SURROGATED I NENE

RESINS ASSUMED NONVOLATILE
SURROGATE-BUTYL BENZYL PHTHALATE
DETERGENT NONVOLATILE
VAXES ASSUMED NONVOLATILE
RESINS ASSUMED NONVOLATILE
LARGE POLYMER
POLYMERS ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE


HIGH-CARBON ESTER - NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
LARGE POLYMER
SOAPS ARE NONVOLATILE
                                                         5-7

-------
                                                 TABLE 2 (Continued)
                                      RELATIVE EVAPORATION SATES - ALPHABETICAL
PRODUCT NAME
                                     BP (C)   PRESSURE
           NV
             VP
           8ER    COMMENTS
PRESERVATIVES
PROCETYL AyS
PROPANE
H-PROPYL ALCOHOL
PROPYL P-HYDROXYBENZOATE
PROPYLENE GLYCOL
PROPYLENE GLYCOL DIPELA8GONATE
PROPYLENE GLYCOL 8ICINOLEATE
PROTEIN HYDROLYSATE
PVP-VA COPOLYHER E-73S
PYRETHRIN I
PYRETHRIN II
QUATERN1UN 26
EESYN 28-2930
RHOPLEX B
ROSIN
ROTEHONE
SALICYLANILIDE
SALICYLIC ACID
SANDOPAN DTC'ACID
SANDOPAN TFL CONCENTRATE
SAPAHINE COB-ST
SAPAHINE VL
SESAME OIL
                                      -42.1
                                       97.8

                                        189
                                        213
                                        170
                                        200
757
 44.11
 60.09

 76.11
198.32
 .1    328.46
 .1    372.47
                                        215

                                        211
       394.00

 20    138.12
SILICONE DEFOAMER
SILICONS FLUID 220/350CS
SILICONE LE 452
SILICONE OIL 350 CS. 10000 CS
SINDAR TECHNICAL G4-40
SOAP
SODIUM DOOECYLBENZENE SULFONATE
SODIUH LAURYL SARCOSINATE
SODIUM LAURYL SULFATE
SODIUM Q-PHENYLPHENOLATE
SODIUH XYLENE SULFONATE
SOLVENTS
SORB I TAN MONOSTEARATE
SORBITOL
SPAN 80
SPAN 65
STEARATE EHULSIFIER
STEARIC ACID
STODDARD SOLVENT
STYRENATED ALKYD RESIN
SUNSCREEN AGENT
SURFACTANT NF
SURFACTANT «K
SYH-DI-BETA-NAPTHYL-P-PHENYL DIAM
                                        295
                                        383
        50.00

  5    182.18
       428.61
       284.47
        50.00
 0.00
 0.00
 8.50
15.41

  .10
  .08
 0.00
 0.00
 0.00
  .00
  .00
 0.00
 0.00
 0.00

  .24
 0.00
  .00

 0.00
 0.00
 0.00
 0.00
                                                                     0.00
                                                                     0.00
                                                                     0.00
           0.00
           0.00
           0.00
           0.00
           0.00
          50.00
           0.00
           0.00
           0.00
           0.00

           0.00
          50.00

           0.00
           0.00
           0.00
  0.00
  0.00
 46.39
 98.17
   .10
   .75
   .87
  0.00
  0.00
  0.00
   .00
   .00
  0.00
  0.00
  0.00
  0.00
  3.91
  0.00
   .00
  0.00
  0.00
  0.00
  0.00
  0.00
  0.00
  0.00
  0.00
  0.00
  0.00
  0.00
  0.00
  0.00
  0.00
  0.00
  0.00
  0.00
290.51
  0.00
  0.00
  0.00
  0.00
  0.00
  0.00
290.51
  0.00
  0.00
  0.00
  0.00
  0.00
                                                                                      FUNCTION  IMPLIES NONVOLATILITY
                                                                                      HIGH-CARBON ASSUMED NONVOLATILE
                                   NO DATA - ASSUMED VOLATILE
                                                                                      HIGH-CARBON ESTER - NONVOLATILE
                                                                                      ASSUMED NONVOLATILE
                                                                                      POLYMERS ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
USED ABIETIC ACID - SOLID

HIGH CARBON - ASSUMED NONVOLATILE

HIGH-CARBON SALT
HIGH-CARBON SALT
STEARIC ACID AMIDE
STEARIC ACID AMIDE
HIGH-CARBON FATTY ACID
HIGH-CARBON ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
SOAPS ARE NONVOLATILE
HIGH-CARBON SALT
LONG-CHAIN ESTER
HIGH-CARBON CMPD - NONVOLATILE
SALT
SALT
ASSUMED VOLATILE
HIGH-CARBON ESTE8 - NONVOLATILE
HIGH-CARBON SUGAR - NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
LONG-CHAIN ESTER
LONG-CHAIN FATTY ACID
KNOWN TO BE VOLATILE
RESINS ASSUMED  NONVOLATILE
FUNCTION IMPLIES NGNVOLATILITY
ASSUMED NONVOLATILE
ASSUMED NONVOLATILE
GREASES
                                                         5-8

-------
                                                 TABLE 2 (Continued)
                                      RELATIVE EVAPORATION RATES - ALPHABETICAL
PRODUCT NAME
BP (C)   PRESSURE
VP
RER    COMMENTS
TALL OIL
TARTAR1C ACID
TENSIOF1X (LX.  VP)
TERGITOL ANIONIC 4
TERG1TOL NIN-FOAM
THICKENERS
THIURAH
THYMOL                               233.92          2
TINOPAX ANA
TOLUENE                               110.8
TRIBASIC LEAD MALEATE
TRIBUTOXYETHYL PHOSPHATE
TBIBUTTL PHOSPHATE
1,1,1-TRICHLOROETHANE                    76
TRICHLOROETHYLENE                        87
TRICRESYL PHOSPHATE
TRIETHANOL AH1NE OLEATE
TRIETHANOLAMINE                         277        150
TRIETHYLENE GLYCOL                    287.4
TRITON X-200
TURKEY RED OIL
TURPENTINE                              155     136.23
TUEEN 81
UNDECYLENIC ACID
UREA CARBAMIDE
VEGETABLE OIL
UEQREZ S-71
VETTING AGENT
UHITE SPIRIT OR NAPTHA
VOOD FLOUR
XYLENE                                144.4
XYLOL                                 144.4
ZINC DIMETHYL DITHIOCARBAMATE
ZINC NAPHTHENATE
ZINC UNDECYLENATE
                                0.00     0.00
                     168.10     0.00     0.00
                                         0.00
                                0.00     0.00
                                0.00     0.00
                                0.00     0.00
                                         0.00
                     150.22      .01      .09
                                         0.00
                      92.10    21.48   169.35
                                         0.00
                                         0.00
                                         0.00
                     133.41   100.00   949.09
                     131.29    66.08   622.12
                     368.37      .50     7.89
                                0.00     0.00
                     149.19      .00      .00
                     150.20     -.00      .00
                                         0.00
                                0.00     0.00
                       3.00    28.75    40.92
                                         0.00
                                0.00     0.00
                                         0.00
                                0.00     0.00
                                         0.00
                                         0.00
                      50.00    50.00   290.51
                                         0.00
                     106.17     5.00    42.33
                     106.17     5.00    42.33
                                         0.00
                                         0.00
                                0.00     0.00
               RESINS ASSUMED NONVOLATILE
               SOLID AT ROOM TENP
               NO DATA - ASSUMED NONVOLATILE
               NONVOLATILE SALT
               NONVOLATILE SALT
               FUNCTION IMPLIES NONVOLATILITY
               CRYSTALLINE AT ROOM TEMP.

               NO DATA - PROBABLY A SOLID

               SALTS ASSUMED NONVOLATILE
               SALT - ASSUMED NONVOLATILE
               SALT - ASSUMED NONVOLATILE
               UNION OIL DATA
               HIGH-CARBON ESTER - NONVOLATILE
               NO DATA - ASSUMED NONVOLATILE
               FATTY ACIDiNONVOLATILE
               SURROGATED INENE
               NO DATA - ASSUMED NONVOLATILE
               HIGH-CARBON FATTY ACID
               NO DATA - ASSUMED NONVOLATILE
               ASSUMED NONVOLATILE
               NO DATA - ASSUMED NONVOLATILE
               NO DATA - ASSUMED NONVOLATILE
               KNOVN TO BE VOLATILE
               CELLULOSE AND LIGNITE-NONVOLATILE

               SAME AS XYLENE
               NO DATA - ASSUMED NONVOLATILE
               METALLIC SALT
               SALTS ASSUMED NONVOLATILE
                                                          5-9

-------
                                                       TABLE 3
                                       RELATIVE EVAPORATION RATES - NUMERICAL
PRODUCT NAME
BP (C)   PRESSURE
             VP
RER    COMMENTS
5-BENZYL-3-FURYL	
AC POLYETHYLENE 6Z9
ACRYLIC RESIN
ACRYSOL LEVELING AID
AD1PIC ACID
ALCOHOL-SOLUBLE LANOLIN
ALKYO RESIN
ALKYL ARYL SODIUM SULFONATE
ALKYLDIHETHYLBENZYLAHMQNIUM
ALKYLDIMETHYLBENZYLAMMQNIUM CHLORIDE
ALLETHRIN, D-TRANS                   302.41
ALUMINUM PHENYLSULFONATE
AKMONIUH CITRATE
AMMONIUM LAURYL ETHE5 SULPHATE
AHMOKIUM QXALATE
AHMONYX 4002
AMPHOHER
ANTARON FC-34
BAYGON
BEESUAX
BENZETHONIUH
BIOCIDE
BUTADIENE-STYRENE COPOLYMER
CALCIUM THIOGLYCOLATE TRIHYDRATE
CALGQN
CARBARYL
CARBOPQL 934
CARBOXYMETHYL CELLULOSE
CARNAUBA WAX
CARTARETINE F4
CAT ION1C CELLULOSE
CELLULOSE ACETATE BUTY8ATE
CERES IN
CETYL ALCOHOL. FLAKES                190.00
CHLOE. PARAFFIN PLASTICIZER
CHLORDANE
CHLOBOSULFONATED POLYETHYLENE
CITRIC ACID                      DECOMPOSES
COCAH1NO BETAINE
COCONUT ANIDOPROPYL-
   3-DIMETHYLAMINE BETAINE
COCONUT OIL AMINE
COLOR
COLOR It IX
CONDANOL (DBS.DLS,MLS,SB/L)
COPPER UNDECYLENATE
CROHEEN
CRYSTALLINE UAX
CUBE RESINS
            15.00
                    0.00    NO DATA - ASSUMED NONVOLATILE
           0.00     0.00    LARGE POLYHER
           0.00     0.00    RESINS ASSUMED NONVOLATILE
                    0.00    NO DATA - ASSUMED NONVOLATILE
                    0.00    H1GH-C FATTY ACIDS NONVOLATILE
           0.00     0.00    HIGH-C FATTY CMPDS NONVOLATILE
           0.00     0.00    RESINS ASSUMED NONVOLATILE
           0.00     0.00    SALT
                    0.00    NO DATA - ASSUMED NONVOLATILE
                    0.00    SALTS ASSUMED NONVOLATILE
                    0.00    HIGH-CARBON ESTER-NONVOLATILE
           0.00     0.00    SALTS ASSUMED NONVOLATILE
           0.00     0.00    SALT ASSUMED NONVOLATILE
           0.00     0.00    HIGH-CARBON SALT
142.11     0.00     0.00    NONVOLATILE SALT
           0.00     0.00    VERY HIGH-CARBON COMPOUND
           0.00     0.00    NO DATA - ASSUMED NONVOLATILE
           0.00     0.00    POLYMERS ASSUMED NONVOLATILE
209.24              0.00    CRYSTALLINE-ASSUMED NONVOLATILE
           0.00     0.00    WAXES ASSUMED NONVOLATILE
           0.00     0.00    NO DATA - ASSUMED NONVOLATILE
                    0.00    NO DATA - ASSUMED NONVOLATILE
           0.00     0.00    LARGE POLYHER NONVOLATILE
           0.00     0.00    SALTS ASSUMED NONVOLATILE
                    0.00    NO DATA - ASSUMED NONVOLATILE
           0.00     0.00    NONVOLATILE CRYSTAL AT ROOM TEMP
           0.00     0.00    NO DATA '- ASSUMED NONVOLATILE
           0.00     0.00    LARGE POLYMER
           0.00     0.00    VAXES ASSUMED NONVOLATILE
                    0.00    NO DATA - ASSUMED NONVOLATILE
           0.00     0.00    POLYMERS ASSUMED NONVOLATILE
           0.00     0.00    LARGE POLYHER
                    0.00    NO DATA - ASSUMED NONVOLATILE
           0.00     0.00    HIGH-CARBON ALCOHOL - NONVOLATILE
                    0.00    SURROGATE'BUTYL BENZYL PHTHALATE
409.78              0.00    FROM STRUCTURE, PROBABLY NON-VQL
                    0.00    POLYMERS ASSUMED NONVOLATILE
192.12     0.00     0.00    ASSUMED NONVOLATILE
           0.00     0.00    LONG-CHAIN POLYHER

           0.00     0.00    LONG-CHAIN POLYHER
           0.00     0.00    HIGH-CARBON
           0.00     0.00    NO DATA - ASSUMED NONVOLATILE
                    0.00    NO DATA - ASSUMED NONVOLATILE
           0.00     0.00    NONVOLATILE SALT
           0.00     0.00    HIGH-CARBON SALT - NONVOLATILE
           0.00     0.00    NO DATA - ASSUMED NONVOLATILE
           0.00     0.00    WAXES ASSUMED NONVOLATILE
           0.00     0.00    RESINS ASSUMED NONVOLATILE
                                                         5-10

-------
                                                 TABLE 3 (Continued)
                                       RELATIVE EVAPORATION BATES - NUMERICAL
PRODUCT NAME
BP (C)   PRESSURE
             MV
  VP
RER    COMMENTS
CYCLOPROPANE CARBOXYLATE
DC 193 FLUID
DEHYDBOGENATED RESIN
DETERGEKT
DIMETHYCGNE COPOLTGL
DITHIO-8IS-STEARYL PROPIONATE
DODECYL BENZENE SULFQNATE
DOU 276-V9
DRIERS
DUREZ (14000,16470.22008)
DUREZ (19788,12686,12687)
DUREZ (26141,26789,26799)
DUREZ 7421A
EDTA
ELASTOMERIC BINDER
EMOLLIENT
EMULPHOR QN-870
EHULSIFIERS, HUMECTANTS, WAXES
ENDOSULPHAN
ESSENTIAL CEDAR OIL
ETHOIYLATE TRIDECYL ALCOHOL
ETHOXYLATED FATTY'ALCOHOL SULFATE
ETHYLENE GLYCOL D1STEARATE
2-ETHYL HEXYL SALICYLATE
FATTY ACID AMIDES
FATTY ACID SOAP
FISH OIL
FLUILAN
FOAM STABILIZERS
FOLPET
FRACTAL A
GANTREZ E5 225 OR ES 425
GELVA (TS 22,23,30,31,85)
HARD VAXES
HOECHST VAX
HUHECTANTS
HYDROGENATED RESIN ESTER
HYDROXYALKYL CELLULOSE (KLUCEL HA
1SOPROPYL HYRISTATE
0-ISOPROXYPHENYL HETHYLCARBAMATE
KELTHANE
KELZAN
KOSOL
KP-140
LANETO 100
LANOLIN
LATEI POLYMER ACRYLIC RESIN
LAURIC ACID
LAURIC DIETHANOLAM1DE
296.56
192.60

370.49
20.00    270.46
131.00
 1.00    200.33
         0.00    USED CYPOTHRIN (HIGH-CARBON)
0.00     0.00    NO DATA - ASSUMED NONVOLATILE
0.00     0.00    RESINS ASSUMED NONVOLATILE
0.00     0.00    SURROGATE=SODIUN LAURYL SULFATE
0.00     0.00    POLYMERS ASSUMED NONVOLATILE
0.00     0.00    HIGH-CARBON ESTER - NONVOLATILE
0.00     0.00    HIGH-CARBON ESTER
         0.00    NO DATA - ASSUMED NONVOLATILE
0.00     0.00    ASSUMED TO REMAIN IN THE COATINGS
0.00     0.00    PHENOL-FORMALDEHYDE RESIN
0.00     0.00    PHENOL-FORMALDEHYDE RESIN
0.00     0.00    PHENOL-FORMALDEHYDE RESIN
0.00     0.00    PHENOL-FORMALDEHYDE RESIN
         0.00    NO DATA - ASSUMED NONVOLATILE
         0.00    POLYMERS ASSUMED NONVOLATILE
0.00     0.00    PROBABLY NONVOLATILE
         0.00    NO DATA - ASSUMED NONVOLATILE
0.00     0.00    FUNCTION IMPLIES NONVOLATILITY
         0.00    NO DATA - ASSUMED NONVOLATILE
         0.00    NO DATA - ASSUMED NONVOLATILE
0.00     0.00    LONG-CHAIN ALCOHOL
0.00     0.00    HIGH-CARBON ASSUME NONVOLATILE
0.00     0.00    LONG-CHAIN ESTER
0.00     0.00    HIGH-CARBON ACID - NONVOLATILE
0.00     0.00    SURROGATE'NYLON; ASSUMED NONVOLAT
0.00     0.00    SOAPS ASSUMED NONVOLATILE
0.00     0.00    ASSUMED NONVOLATILE
0.00     0;00    NO DATA - ASSUMED NONVOLATILE
         0.00    NO DATA - ASSUMED NONVOLATILE
         0.00    CRYSTALLINE-ASSUMED NONVOLATILE
         0.00    NO DATA - ASSUMED NONVOLATILE
0.00     0.00    PROBABLY A RESIN - NONVOLATILE
         0.00    POLYV1NYL ACETATE RESIN
0.00     0.00    VAXES ASSUMED NONVOLATILE
0.00     0.00    VAXES ASSUMED NONVOLATILE
0.00     0.00    FUNCTION IMPLIES NONVOLATILITY
0.00     0.00    RESINS ASSUMED NONVOLATILE
0.00     0.00    POLYMERS ASSUMED NONVOLATILE
0.00     0.00    HIGH-CARBON ESTER - NONVOLATILE
0.00     0.00    Cll COMPOUND ASSUMED NONVOLATILE
         0.00    CRYSTALLINE-ASSUMED NONVOLATILE
0.00     0.00    POLYMERS ASSUMED NONVOLATILE
0.00     0.00    STARCH  (POVDER)
         0.00    NO DATA - ASSUMED NONVOLATILE
0.00     0.00    NO DATA - ASSUMED NONVOLATILE
0.00     0.00    ASSUMED NONVOLATILE
0.00     0.00    RESINS ASSUMED NONVOLATILE
0.00     0.00    HIGH-CARBON FATTY ACID-NONVOLATIL
0.00     0.00    HIGH-CARBON AMIDE - NONVOLATILE
                                                         5-11

-------
                                                 TABLE 3 (Continued)
                                       BELATIVE EVAPORATION BATES - NUMERICAL
PRODUCT NAME
BP (C)   PRESSURE
    HU
VP
8ER    COMMENTS
MBTS (2-BENZOTHIAZOLYL SULFIDE)
HETHOXYCHLOR
METHYL ANTHRANILATE
NETHYLBENZETHONIUM CHLORIDE
HICROCRYSTALLINE VAX
KILLED PALE CREPE
MILLED SMOKE RUBBER
MINERAL OIL
HIRANOL C2HSF
HONAMID 716
HONOGLYCEROL P-AN1NOBENZOATE
NEOPRENE
NITROCELLULOSE
N-OCTYL-BICYCLOHEPTENE DICARBOXIHIDE
OILS
OLEIC ACID                           360.00
PALMITIC ACID                       350,267
PARAFFIN WAXES
PETROLEUM AND SYNTHETIC UAXES
PHENOLIC RESIN
PLASTIC
PLASTICIZER (DGO-.3GH-)
PLURONIC F 108 DETERGENT
POLAVAX A 31
POLY-BETA-PINENE RESIN
POLYACRYLATE
POLYACRYL1C ACID (40% AQ.) N.U.10
POLYDIMETHYLSILOXANE
POLYETHOXYLATED (75 EQ) LANOLIN
POLYETHYLENE
POLYETHYLENE GLYCOL (400) HONOLAU
POLYOXYETHYLENE SORBITAN MONOSTEARATE
POLYQUATERNIUM 4
POLYTRIMETHYLDIHYDRO-QUINOLI ME
POLYVINYL ACETATE
POTASSIUM SOAP OF OLEIC ACID
PRESERVATIVES
PROCETYL AUS
PROPYLENE GLYCOL RICINOLEATE
PROTEIN HYDROLYSATE
PVP-VA COPOLYMER E-735
QUATERNIUM 26
RESYN 2B-2930
RHOPLEX B
ROSIN
SALICYLANILIDE
SANDOPAN DTC ACID
SANDOPAN TFL CONCENTRATE
SAPAHINE COB-ST
                     282.46
           100.00    256.43
332.47              0.00    CRYSTALLINE AT ROOM TEMP.
           0.00     0.00    NONVOLATILE CRYSTAL AT ROOM TEHP
           0.00     0.00    NO DATA - ASSUMED NONVOLATILE
           0.00     0.00    SALTS ASSUMED NONVOLATILE
           0.00     0.00    UAXES ASSUMED NONVOLATILE
           0.00     0.00    SOLID AT AMBIENT TEMPERATURE
           0.00     0.00    SOLID AT AMBIENT TEMPERATURE
           0.00     0.00    NO DATA - ASSUMED NONVOLATILE
           0.00     0.00    HIGH-CARBON SALT
           0.00     0.00    NO DATA - ASSUMED NONVOLATILE
           0.00     0.00    HIGH-CARBON ESTER - NONVOLATILE
           0.00     0.00    LARGE POLYMER
           0.00     0.00    LARGE POLYMER
                    0.00    HIGH-CARBON CMPD - ASSUMED NONVOL
           0.00     0.00    ASSUMED TO BE HIGH-C FATTY ACIDS
           0.00     0.00    NEAR SOLID AT AMBIENT TEMP.
           0.00     0.00    HIGH-CARBON FATTY ACIO-NONVOLATIL
           0.00     0.00    UAXES ASSUMED NONVOLATILE
           0.00     0.00    UAXES ARE NONVOLATILE
           0.00     0.00    RESINS ASSUMED NONVOLATILE
           0.00     0.00    RESINS ASSUMED NONVOLATILE
312.36     0.00     0.00    SURROGATE=BUTYL BENZYL PHTHALATE
           0.00     0.00    DETERGENT NONVOLATILE   '
           0.00     0.00.   UAXES ASSUMED NONVOLATILE
           0.00     0.00    RESINS ASSUMED NONVOLATILE
           0.00     0.00    LARGE POLYMER
           0.00     0.00    POLYMERS ASSUMED NONVOLATILE
                    0.00    POLYMERS ASSUMED NONVOLATILE
           0.00     0.00    POLYMERS ASSUMED NONVOLATILE
                    0.00    POLYMERS ASSUMED NONVOLATILE
           0.00     0.00    POLYMERS ASSUMED NONVOLATILE
           0.00     0.00    HIGH-CARBON ESTER - NONVOLATILE
           0.00     0.00    POLYMERS ASSUMED NONVOLATILE
           0.00     0.00    POLYMERS ASSUMED NONVOLATILE
           0.00     0.00    LARGE POLYMER
           0.00     0.00    SOAPS ARE NONVOLATILE
           0.00     0.00    FUNCTION IMPLIES NONVOLAT1L1TY
           0.00     0.00    HIGH-CARBON ASSUMED NONVOLATILE
           0.00     0.00    HIGH-CARBON ESTER - NONVOLATILE
           0.00     0.00    ASSUMED NONVOLATILE
           0.00     0.00    POLYMERS ASSUMED NONVOLATILE
           0.00     0.00    POLYMERS ASSUMED NONVOLATILE
           0.00     0.00    POLYMERS ASSUMED NONVOLATILE
           0.00     0.00    POLYMERS ASSUMED NONVOLATILE
                    0.00    USED AB1ET1C ACID - SOLID
           0.00     0.00    HIGH CARBON - ASSUMED NONVOLATILE
                    0.00    HIGH-CARBON SALT
           0.00     0.00    HIGH-CARBON SALT
           0.00     0.00    STEARIC ACID AMIDE
                                                          5-12

-------
                                                 TABLE 3 (Continued)
                                       RELATIVE EVAPORATION RATES - NUMERICAL
PRODUCT NAME
BP (C)   PRESSURE
HU
VP
RER    COMMENTS
SAPAH1NE UL                                                          0.00
SESAME OIL                                                           0.00
SEV1N
S1LICONE OEFOAMER
SILICQNE FLUID 220/350CS                                             0.00
SUICONE LE 452                                                      0.00
SILICONE OIL 350 CS,  10000 CS                                        0.00
SINDAB TECHNICAL 64-40
SOAP
SODIUM DODECYLBENZENE SULFONATE                                      0.00
SODIUM LAURYL SARCOSINATE                                            0.00
SODIUM LAURYL SULFATE                                                0.00
SODIUM 0-PHENYLPHENOLATE                                             0.00
SODIUM XYLENE SULFONATE                                              0.00
SORBITAN HONOSTEARATE                                                0.00
SORB1TOL                             295.00       5.00    182.18     0.00
SPAN 80                                                   428.61     0.00
SPAN 85                                                              0.00
STEABATE EMULSIFIES
STEARIC ACID                         383.00
STYRENATED ALKYD RESIN
SUNSCREEN AGENT
SURFACTANT NF
SURFACTANT UK
SYM-DI-BETA-NAPTHYL-P-PHENYL DIAN
TALL OIL
TARTAR1C ACID                                             168.10
TENS!OFIX (LX. UP)
TERGITOL ANIONIC 4
TERGITOL MIN-FOAH
THICKENERS
THIURAM
TINOPAX ANA
TRIBASIC LEAD NALEATE
TRIBUTOXYETHYL PHOSPHATE
TRIBUTYL PHOSPHATE
TRIETHANOL AHINE OLEATE                                              0.00
TRITON X-200
TURKEY RED OIL                                                       0.00
TUEEN81
UNDECYLENIC ACID                                                     0.00
UREA CARBAMIDE
VEGETABLE OIL                                                        0.00
VEOREZ S-71
VETTING AGENT
VOOD FLOUR
ZINC DIMETHYL DITHIOCARBAMATE
ZINC UNDECYLENATE                                                    0.00
PYRETHRIN I                          170.00         .10    328.46       .00
                     284.47     0.00

                                0.00
                                0.00
                                0.00
                                0.00
                                0.00

                                0.00
                                0.00
                                0.00
                0.00    STEARIC ACID AMIDE
                0.00    HIGH-CARBON FATTY ACID
                0.00    HIGH-CARBON ASSUMED NONVOLATILE
                0.00    NO DATA - ASSUMED NONVOLATILE
                0.00    POLYMERS ASSUMED NONVOLATILE
                0.00    POLYMERS ASSUMED NONVOLATILE
                0.00    POLYMERS ASSUMED NONVOLATILE
                0.00    NO DATA - ASSUMED NONVOLATILE
                0.00    SOAPS ARE NONVOLATILE
                0.00    HIGH-CARBON SALT
                0.00    LONG-CHAIN ESTER
                0.00    HIGH-CARBON CHPD - NONVOLATILE
                0.00    SALT
                0.00    SALT
                0.00    HIGH-CARBON ESTER - NONVOLATILE
                0.00    HIGH-CARBON SUGAR - NONVOLATILE
                0.00    NO DATA - ASSUMED NONVOLATILE
                0.00    NO DATA - ASSUMED NONVOLATILE
                0.00    LONG-CHAIN ESTES
                0.00    LONG-CHAIN FATTY ACID
                0.00    RESINS ASSUMED NONVOLATILE
                0.00    FUNCTION IMPLIES NONVOLATILE
                0.00    ASSUMED NONVOLATILE
                0.00    ASSUMED NONVOLATILE
                0.00    GREASES
                0.00    RESINS ASSUMED NONVOLATILE
                0.00    SOLID AT ROOM TEMP
                0.00    NO DATA - ASSUMED NONVOLATILE
                0.00    NONVOLATILE SALT
                0.00    NONVOLATILE SALT
                0.00    FUNCTION IMPLIES NONVOLATILE
                0.00    CRYSTALLINE AT ROOM TEMP.
                0.00    NO DATA - PROBABLY A SOLID
                0.00    SALTS ASSUMED NONVOLATILE
                0.00    SALT - ASSUMED NONVOLATILE
                0.00    SALT -ASSUMED NONVOLATILE
                0.00    HIGH-CARBON ESTER - NONVOLATILE
                0.00    NO DATA - ASSUMED NONVOLATILE
                0.00    FATTY AC ID:NONVOLATILE
                0.00    NO DATA - ASSUMED NONVOLATILE
                0.00    HIGH-CARBON FATTY ACID
                0.00    NO DATA - ASSUMED NONVOLATILE
                0.00    ASSUMED NONVOLATILE
                0.00    NO DATA - ASSUMED NONVOLATILE
                0.00    NO DATA - ASSUMED NONVOLATILE
                0.00    CELLULOSE AND LIGNITE-NONVOLATILE
                0.00    NO DATA - ASSUMED NONVOLATILE
                0.00    SALTS ASSUMED NONVOLATILE
                  .00
                                                        5-13

-------
                                                  TABLE 3 (Continued)
                                        RELATIVE EVAPORATION RATES  - NUMERICAL
PRODUCT NAHE
BP (C)   PRESSURE
HU
VP
RER    COMMENTS
PYRETHRIN 1!
PIPERONYL BUTOX1DE
HALATHION
DIOCTYL PHTHALATE PLASTIC12ER
HYRJSTIC ACID
SALICYLIC ACID
TRIETHANOLAHINE
0-BENZYL-P-CHLOROPHENOL
GLYCEROL
DIBUTYL PHTHALATE
TRIETHYLENE GLYCOL
BENZYL BENZOATE
AMPD
2,4 BIS (ISOPROPYLAMINO)-6
HETHOXY-S-TRIAZINE
4-ANINO-3,5,6-TRICHLQROPia!LlNIC
2,4,5-TRICHLOROPHENOXYACETIC
ACID, POTASSIUM SALT
Cl.S.P. COMPOUNDS
COPPER NAPHTHENATE
BROMOC1L
GRANULAR MINERAL BASE
ISOOCTYL ESTERS
ISOBUTYLENE POLYMERS
HONURON
PICLORAM
ZINC NAPHTHENATE
2-FUHALDEHYDE. 2,3:4,5-813-
(2-BUmENE) TETRAHYDRO
HYRISTIL ALCOHOL
HGK
2-ETHYL-l,3-HEXANEDIOL
N,N-DIALKYL-H-TQLUAMIDE
OIETHYLENE GLYCOL
BEN20IC ACID
PETREI 7-75T (DRY)
ALKYL DIETHANOLAHINE
THYMOL
DIPROPYLENE GLYCOL
PROPYL P-HYDROXYBENZOATE
DDVP
POLYOIYETHYLENE (2) CETYL ETHER
MONOETHYLENE GLYCOL
ETHYLENE GLYCOL
METHYL P-HYDROXYBENZOATE
PROPYLENE GLYCOL
PROPYLENE GLYCOL DIPELARGONATE
CRESOL <0-,N-,P->
MENTHOL
200.00
180.00
156.50
385.00
250.50
211.00
277.00
161.00
DECOMPOSES (
340.00
287.40
323.50
151.20


ACID












307.00
263.20
307.00
244.00
160.00
245.00
249,133
136.00

233,92
292/232

140.00
270.00
198.00
198.00
223.30
189.00
213.00

216.00
.10
1.00
.70

100.00
20.00
150.00
3.50
1 290



10.00



















19.00

10.00
11.00

2.00


20.00





757.00


372.47
338.44
330.35
390.56
228.38
138.12
149. 19
218.68
92.11
278.35
150.20
212.25
105.14















204.27
214.40
204.27
146.23
191.27
106.12
122.13
234.30
88.13
150.22
134.20

220.98
466.89
62.10
62.10
152.15
76.11
196.32
108. 13
156.27
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00















0.00
.00
.00
.00
.00
.00
.00
.01
.01
.01
.01

.01
.01
.06
.06
.07
.10
.08
.11
.15
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
,00
.00

0.00
0.00

0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00

.01
.01
.01
.02
.02
.02
.03
.07
.07
.09
.10
.10
.11
.14
.39
.39
.67
.75
.87
.96
1.54















ASSUMED NONVOLATILE

SALT- ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
METALLIC SALT
SOLID - ASSUMED NONVOLATILE
SOLID - ASSUMED NONVOLATILE
FAIRLY HIGH CARBON ESTER
POLYMER - ASSUMED NONVOLATILE
PROBABLY AN OIL
ASSUMED NONVOLATILE
METALLIC SALT



MGK 11 USED AS TYPICAL COMPOUND

USED N,N-DIETHYL-M-TOLUAN!DE


USED 2-ACETYL BENZOFURAN
USED ETHYL DIETHANOLAHINE

REH SHOULD BE < 0. 1
NO DATA - ASSUMED VOLATILE







RER DERIVED FROM AVG SER'S

                                                       5-14

-------
                                                TABLE 3  (Continued)
                                      RELATIVE EVAPORATION HATES - HUMES1CAL
PRODUCT NAME
BP (C)   PRESSURE
VP
RER    COMMENTS
NAPHTHALENE
CARBITOL
2-AH1HO-2-HETHYL PROPANOL
ETHANOLAMINE
L-CAHPHOR
D.L-CAHPHOR
D-CAHPHQR
AMP
ROTENONE
D1PROPYLENE GLYCOL MONOMETHYL ETH
Bl/TYL CELLOSOLVE
ETHYLEME GLYCOL MONOBUTYL ETHER
POLY1SOBUTYLENE (TRI-.TETRAMER-
TRICRESYL PHOSPHATE
Q-DICHLOROBENZENE
CELLQSOLVE ACETATE
217.90
202.00
165.50
172.00
SUBLiHES 9
SUBLIMES
SUBLIHES 8
.165.00
215.00
187.20
170.00

)

180.50
156.00
DIETHYLENE GLYCOL HONOMETHYL ETHE 159.00
AHYL ACETATE
PINE OIL
PETROLEUM ETHERS
MONO ETHYL ETHER
ETHYLENE GLYCOL HONOETHYL ETHER
GLYCOL ETHER
TURPENTINE
XYLENE
XYLOL
PROPANE
NORPHOLINE :
ACETIC ACID
HITROPROPANE (1-.2-)
CHLOi-AROHATIC SOLVENTS
H-PROPYL ALCOHOL
DICHLOROPENTANE
PERCHLOROETHYLENE
TOLUENE
AROMATIC HYDROCARBONS
AROMATIC KETONE SOLVENT
ISOPROPANOL
ISQPSOPYL ALCOHOL
ETHANOL
ETHYL ALCOHOL
ETHYL ALCOHOL OP
ALCOHOL 740 P
CHLORINATED SOLVENTS
DEODORANT
ESSENTIAL OIL
ESTE8S AND KETONES (ACETONE)
FRAGRANCE
FRAGRANCE, DYE
148.00
155.00


135.00

155.00
144.40
144.40
-42.10
128.00
118.10


97.80

121.40
110.80


82.40
82.40
78.50
78.40
78.40







128.16
134.20
89.14
61.06
152.24
152.24
152.24
89.14
394.00
162.23
118.17
118.17
196.38
• 368.37
147.00
132.16
120.15
737.00 130.20
136.23
90.10
90.10
90.10
90.10
136.23 3.00
106.17
106.17
44.11
87.12
60.05
69.09
112.56
60.09
141.04
165.83
92.10
92.10
92.10
60.10
60.10
46.07
46.07
46.07
50.00
50.00
50.00
50.00
50.00
50.00
50.00
.21
.21
.33
.40
.28
.28
.28
.44
.24
.46
.60
.60
.53
.50
.89
1.20
1.88
3.05
3.00
3.80
3.80
3.80
3.80
28.75
5.00
5.00
8.50
8.00
10.63
9.38
8.80
15.41
14.02
14.00
21.48
22.00
22.00
34.82
34.82
43.90
43.90
43.90
50.00
50.00
50.00
50.00
50.00
50.00
50.00
1.91
1.99
2.53
2.57
2.81
2.81
2.81
3.41
3.91
4.76
5.36
5.36
5.71
7.89
8.89
11.34
16.96
28.55
28.75
29.64
29.64
29.64
29.64
40.92
42.33
42.33
46.39
61.36
67.68
72.78
76.72
98.17
136.81
148.14
169.35
173.49
173.49
221.79
221.79
244.84
244.84
244.84
290.51
290.51
290.51
290.51
290.51
290.51
290.51










E.G. HQNOBUTYL ETHER


UNION OIL DATA



USED N-AMYLACETATE
SURROGATED I NENE



















SURROGATE = MONOETHYL ETHER


SURROGATE 'E.G. HONOETHYL
SURROGATED 1NENE

SAME AS XYLENE



RER DERIVED FROM AVG RER'


ETHER






S
SURROGATE'HQNOCHLOROBENZENE

RER DERIVED FROM AVG RER'


SURROGATE * XYLENE
SURROGATE - XYLENE




SAME AS ETHANOL






S














NO DATA - ASSUMED VOLATILE


                                                        5-15

-------
                                                  TABLE 3 (Continued)
                                        RELATIVE EVAPORATION RATES - NUMERICAL
PRODUCT  NAME
BP (C)   PRESSURE
VP
RER    COMMENTS
HALQGENATED HYDROCARBON PROPELLAN
KEROSENE
MINERAL SPIRITS
PERFUME
PERFUME IN ALCOHOL
PERFUME OIL
PETROLEUM DISTILLATE (NAPHTHA)
PETROLEUM OIL
PETROLEUM SOLVENTS
SOLVENTS
STODDARD SOLVENT
WHITE SPIRIT OR NAPTHA
N-ACETYLETHANOLAH1NE
NONYLPHENOXT ACETIC ACID
OXYGENATED ORGANIC ACIDS
ALIPHATIC HYDROCARBONS
ALIPHATIC THINNER
NETHYL ALCOHOL
ETHYLENE D I CHLORIDE
TRICHLOROETHYLENE
ACETONE
U.l-TRICHLOROETHANE
1SOPARAFFINIC SOLVENT
AMINES
INERT INGREDIENTS (PESTICIDES)
DICHLOROMETHANE
METHTLENE CHLORIDE
PENTANE
DIHETHYLENE OXIDE
HYDROCARBON PROPELLANT
BUTAIE
ISOBUTANE
FORMALDEHYDE
FORMALIN
DIMETHYL ETHER

















65.00
83.50
87.00
56.20
76.00
60.30


41.00
41.00



-.10
-.50
-20.00
-20.00
-25.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
86.17
86.17
32.04
99.00
131.29
58.08
133.41
86.18
73.14

34.93
84.93
72.15
44.05
58.12
58.12
58.12
30.00
30.00
46.70
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
92.39
61.00
66.08
132.49
100.00.
168.34
200.00

349.00
365.66
430.00
1095.00
1544.67
1544.67
1566.19
3243.38
3243.38
3581.69
290.51
290.51
290.51
290.51
290.51
290.51
290.51
290.51
290.51
290.51
290.51
290.51
290.51
290.51
290.51
381.38
381.38
429.70
498.72
622.12
829.65
949.09
1284.09
1405.47
1511.56
2642.83
2768.98
3001.23
5971.73
9676.33
9676.33
9811.14
14597.26
14597.28
20112.19

KNOUN TO BE VOLATILE
KNOUN TO BE VOLATILE



KNOUN TO BE VOLATILE
ASSUMED VOLATILE
KNOUN TO BE VOLATILE
ASSUMED VOLATILE
KNOWN TO BE VOLATILE
KNOUN TO BE VOLATILE

HIGH CARBON SOLID
NO DATA - ASSUMED VOLATILE
USED HEXANE AS REPRESENTATIVE
USED HEXANE AS REPRESENTATIVE





SURROGATE - ISQHEXANE
SURROGATE D1ETHTLAMINE
RER=UTD AVG OF TYPICAL INGRED.(2)
SAME AS NETHYLENE CHLORIDE



SURROGATE:BUTANE





                                                        5-16

-------
                                                                                   Table 4
                                                                       VOC AND PROC EMISSIONS IN CALIFORNIA
      PRODUCT
                                       MILLION  AVG.                                     UEIGHT  FRACTION
                                        UNITS  PROD.       NATIONAL            GEOGR.      VOC       PROC
                                       DISTRI   VT.      CONSUMPTION   POP.     MULT I-
                                        BUTED  (LB)    (MILLION LB)  APPORT.   PLIER   LOU  HIGH     LOU  HIGH       LOU      HIGH
                                                                                                                      TOTAL  VOC  EMISSIONS  TOTAL  PROC EMISSIONS
                                                                                                                            (TONS)                (TONS)
                                                                                     LOU      HIGH
Oi
 i
AEROSOL/NON-AEROSOL PRODUCTS (t)

INSECT SPRAY PRODUCTS
     INSECT SPRAYS (AEROSOL AND
     NON-AEROSOL)
       FORMULATIONS 2,8
     INSECT REPELLENTS (AEROSOL AND
     NON-AEROSOL)
       FORMULATIONS 1,5
     MOTH CONTROL PRODUCTS (AEROSOL
     AND NON-AEROSOL)
       FORMULATIONS 1,2
     ANIMAL INSECTICIDES (AEROSOL
     AND NON-AEROSOL)
       FORMULATIONS 3,4
SUB-TOTAL
      PAINTS AND FINISHES
           PAINTS, PRIMERS, VARNISHES
             FORMULATIONS 5,6
             FORMULATIONS 3,6
           OTHER RELATED PRODUCTS
             FORMULATIONS 1
      SUB-TOTAL
      HOUSEHOLD PRODUCTS
           ROOM DEODORANTS AND DIS-
           INFECTANTS  (AEROSOL AND NON-
           AEROSOL)
             FORMULATIONS 2,4
             FORMULATIONS 1,4
                                        300.60
                                        300.60
.75
.75
                                           6.9    .69
                                        265.50    .50
                                        265.50    .50
                                                                    192.5     .11     1.00   .05  1.00  0.00   1.00    529.38   10587.50      0.00   10587.50
                                                                    12.00     .11     1.00   .35   .65   .35    .65    230.34     561.00     230.34    561.00
                                                                    39.00     .11     1.00   .96  1.00   .96   1.00   2059.20    2136.42    2059.20    2136.42
                                                                     6.00     .11     1.00   .55  1.00   .55   1.00    181.50     329.01     181.50    329.01
                                                                                                                      3000.4!    13613.93   2471.04  13613.93
.11     1.15   .73   .87
.11     1.15               .67

.11     1.00   .65   .65    .65
     10423.85   12391.69
.87
9554.01  12391.69
                                                        .65     170.21     170.21    170.21    170.21
                                                            10594.06   12561.90   9724.21  12561.90
                      .11      .94   .35   i.OO                2436.43    6863.17
                      .11    -  .94               .35    .87                        2436.43   5970.96

-------
                                                                               Table 4 (Continued)
                                                                      VOC AND PROC EMISSIONS  IN CALIFORNIA



PIODUCT
CLEANERS
TILE AND BATHROOM CLEANERS
FORMULATIONS 1,2,3,4,5 (2)
FORMULATIONS 2,3,4,5 (2)
MILLION AVG.
UNITS PROD.
DISTRI VT.
BUTED (LB)





NATIONAL
CONSUMPTION
(MILLION LB)


65.00
65.00


POP.
APPORT.


.11
.11
HEIGHT FRACTION
GEOGR. VOC PROC
MULTI-
PLIER LOV HIGH LOU HIGH


i.OO 0.00 .33
1.00 , 0.00 .33
TOTAL VOC EMISSIONS TOTAL PROC EMISSIONS
(TONS) (TONS)

LOU HIGH -LOV HIGH


0.00 1179.75
0.00 1179.75
Cn
 I
00
  OVEN CLEANERS (AEROSOL AND
  NON-AEROSOL)
    FORMULATIONS 3,4
  RUG AND UPHOLSTERY CLEANERS
  (AE80SOL AND NON-AEROSOL)
    FORMULATIONS 1,3
  ALL PURPOSE CLEANERS
  (AEKOSOL AND NON-AEROSOL)
    FORMULATIONS 1,2
  UINDOU AND GLASS CLEANERS
  (AEROSOL AND NON-AEROSOL)
    FORMULATIONS 6,7
  LAUNDRY PRODUCTS-AEROSOLS
  STARCH, FABRIC FINISH
    FORMULATIONS 1,2

LAUNDRY PRODUCTS
(AEROSOL AND NON-AEROSOL)
  PREUASH STAIN REMOVERS
    FORMULATIONS 1,2
  SPOT REMOVERS
    FORMULATIONS 1,2

  UAXES AND POLISHES
    FORMULATIONS 1,3
  ALL OTHER HOUSEHOLD SPRAY PRODUCTS
    FORMULATIONS
                                             109.90    .75
                                                                   33.00     .11     1.02  0.00   .20  0.00    .20      0.00     370.26      0.00    370.26
                                                                  115.00     .11     1.00   .03-   .26    .03    .26    215.05    1644.50    215.05   1644.50
                                                                  512.00     .11      1.07   .02    .41    .02    .41    602.62   12323.66    602.62  12323.66
                                                                  174.00     .11       .98  0.00    .42  0.00    .42      0.00    3939.01      0.00   3939.01
          .11     1.00   .05   .11    .05     .11    222.14     507.74    222.14    507.74
                                               45.2    .75
84.00     .11     1.00  0.00  0.00  0.00   0.00

 2.30     .11     1.00  1.00  1.00   .90   1.00


58.00     .11      .95   .07   .34   .07    .34

          .11     1.00
  0.00       0.00      0.00      0.00

126.50     126.50    113.65    126.50


212.14    1030,37    212.14   1030.37

NA (4)         NA        NA        NA

-------
                                                                             Table  4  (Continued)
                                                                     VOC AND PROC EMISSIONS  IN CALIFORNIA
    PRODUCT
                                       MILLION  AVG.                                    VEIGHT  FRACTION
                                        UNITS  PROD.       NATIONAL            GEOGR.     VOC       PROC
                                       DISTRI    UT.     CONSUMPTION   POP.    HULJI-
                                        BUTED  (LB)     (MILLION LB)   APPORT.  PLIER   LOU  HIGH    LOU  HIGH
                                                                                                                   TOTAL VOC EMISSIONS  TOTAL PROC EMISSIONS
                                                                                                                         (TONS)               (TONS)
                                                                LOU      HIGH
                                                      LOU
                                                                        HIGH
U1
     SHOE POLISHES, UAXES AND COLOR-
     ANTS (AEROSOL AND NON-AEROSOL)
       FORMULATIONS 1,2
     ANTISTATIC SPRAYS
       FORMULATIONS 1,2
     ADHESIVES (5)
     (AEROSOL AND NON-AEROSOL)
       FORMULATIONS 2,3,6 (2)
     CAULKING AND SEALING CPDS (5)
     (AEROSOL AND NON-AEROSOL)
       FORMULATIONS 1,2
     CARPET DEODORIZERS
     (AEROSOL AND NON-AEROSOL)
       FORMULATIONS 1

   DRAIN OPENERS
     (AEROSOL AND NON-AEROSOL)
     LIQUIDS
       FORMULATIONS 2  (NO VOC)
     SOLIDS
       FORMULATIONS 1
SUB-TOTAL
    PERSONAL PRODUCTS
         SHAVING LATHERS
           FORMULATIONS 2,4
         HAIR SPRAYS
           FORMULATIONS 1,4
           FORMULATIONS 4,5
         STYLING MOUSSE
           FORMULATIONS 1
                                        270.70
                                        270.70
                                                                   6.00     .11      1.00    .13   .98   .13    .96     42.90     323.40     42.90    323.40

                                                                   3.00     .11      1.00  0.00   .03  0.00   \03      0.00       4.95      0.00      4.95
                                                                3277.50     .11      1.00  0.00   .85  0.00    .85      0.00  153223.12      0.00 153223.12
                                                                 432.80     .11      1.00  0.00    .20  0.00    .20      0.00    4760.80      0.00   4760.80
                                                                  65.00     .11       .96    .02   .02   .02    .02     68.64      68.64     68.64     68.64
                                                         17 (HIL.GAL.)      .11       .94  0.00  0.00  0.00   0.00      0.00       0.00      0.00      0.00

                                                                 293.00     .11       .94  0.00  0.00  0.00   0.00      0.00       0.00      0.00      0.00
                                                                                                                   3926.41  186365.88   3913.76 185473.67
                                        162.80    .50
.63
.63
                                        106.10    .38
.11

.11
.11

.11
                              1.01    .03    .09    .03    .09    140.17     402.44    140.17    402.44
.93   .88   .97
.93               .73
      7685.11    8505.09
.97                       6376.64   6505.09
                              1.00    .24    .24    .24    .24    543.29     543.29    543.29    543.29

-------
                                                                              Table 4 (Continued)
                                                                      VOC AND PROC EMISSIONS  IN CALIFORNIA
IS]
o


PIODUCT
MILLION AVG. HEIGHT FRACTION TOTAL VOC EMISSIONS TOTAL PROC EMISSIONS
UNITS PiOD. NATIONAL GEOGt. VOC PROC (TONS) (TONS)
DISTRI HT. CONSUMPTION POP. HULTI-
BUTED (LB) (MILLION LB) APPORT. PLIER LOV HIGH LOU HIGH LOU HIGH LOU HIGH
     OTHER HAIR CARE PRODUCTS-SHAMPOO
     (AEROSOL AND NON-AEROSOL)
       FORMULATIONS 1,2,3 (2)
     PHARMACEUTICALS
       FORMULATIONS 1,3
       FORMULATIONS 2,3
     COLOGNES
       FORMULATIONS 1
     PERFUMES
       FORMULATIONS 1
     AFTERSHAVES
       FORMULATIONS 1
     PERSONAL DEODORANTS AND ANTI-
     PERSPIRANTS
       FORMULATIONS 1,2
     OTHER PERSONAL CARE PRODUCTS
     SUNTAN LOTIONS (2)
       FORMULATIONS 1,4,5 (2)
     DEPILATORIES
       FORMULATIONS 1,2
SUB-TOTAL
      ANIMAL PRODUCTS
           VETERINARIAN AND PET PRODUCTS
      SUB-TOTAL

43.70
43.70
44.00
82.00
23.00

.25
.25
.12
.03
.25
644.60 .11
.11
.11
.11
.11
.11
1.00
1.08
1.08
1.00
1.00
1.00
0.00
.70
1.00
1.00
.65
                                             156.00    .25
 15.1

15.10
      AUTOMOTIVE  AND  INDUSTRIAL  PRODUCTS
           REFRIGERANTS
           CLEANERS (AEROSOL AND NON-AEROSOL)
             FORMULATIONS  4,7                   14.70
.13

.13
.11


.11

.11
                                                                                                                       0.00

                                                                                                                     453.61
                                                   177.27

                                                   645.70
                                                       0.00    177.27
                                                                                                        .70    .99
                                                     453.61    645.70

                                 02.50     302.50    302.50    302.50

                                 35.30     135.30    135.30    135.30

                                 04.93     204.93    204.93    204.93


 .86   .80   .95    .80     .95   1475.76    1752.46   1475.76   1752.46
                                                                                     1.16  0.00   .65  0.00     .65

                                                                                     1.03   .10   .10    .10     .10
                                  0.00
81.41
0.00
81.41
                                 11.12      11.66     11.12     11.68
                              10951.80   12762.06   9643.32  12762.06
                                                                                                                    NA
                                                                                                                  0.00
                                                       NA
                                                     0.00
                                                         NA
                                                       0.00
                       NA
                     0.00
                                                  .88
.11
                                    NA         NA        NA        NA

1.00  0.00  1.00 0.00    1.00      0.00     707.44      0.00    707.44

-------
                                                                                Table 4 (Continued)
                                                                        VOC AND PROC EMISSIONS  IN CALIFORNIA
       PRODUCT
                                       MILLION  AV6.
                                        UNITS  PROD.
                                       DISTRI    VT.
                                        BUTED  (LB)
   NATIONAL            GEM 8.
 CONSUMPTION   POP.     MULTI-
(MILLION LB)  APPORT.   PLIER   LOU  HIGH
                                                                                              VEIGHT  FRACTION
                                                                                                VOC      PSOC
                                TOTAL  VOC  EMISSIONS  TOTAL PROC EMISSIONS
                                      (TONS)               (TONS)
                   LOU  HIGH
   LOU
HIGH
LOU
HIGH
 I
ro
     ENGINE DEGREASERS
       FORMULATIONS 1,2,3 (2)            23.90    .88
       FORMULATIONS 3                    23.90    .88
     LUBRICANTS AND SILICONES
       FORMULATIONS 1,2                  75.40    .44
     UNDERCOAT INGS
       FORMULATIONS 1                     8.30    .75
     BRAKE CLEANERS
       FORMULATIONS 1, 2, or 3           16.60   1.13
     TIRE SEALANTS AND INFLATORS
       FORMULATIONS                      19.30    .69
     CARBURETOR AND CHOKE CLEANERS
       FORMULATIONS 2,3                  39.80    .75
     ENGINE STARTING FLUIDS
       FORMULATIONS 1                    30.80    .56
     UINDSHIELD DEICER (AEROSOL AND NON)
       FORMULATIONS 1,2                  10.40   1.00
     OTHER AUTO AND INDUSTRIAL PRODUCTS
SUB-TOTAL
       MISCELLANEOUS PRODUCTS
            HERBICIDES AND FUNGICIDES
              FORMULATIONS 1,7
       SUB-TOTAL
       NON-AEROSOL PRODUCTS

       PERSONAL PRODUCTS
            NAIL POLISHES
            NAIL POLISH REMOVERS
                                                              69.00
                 .11
                 .11

                 .11

                 .11

                 .11

                 .11

                 .11

                 .11

                 .11
                 .11
1.00   .69  1.00
1.00               .75    1.00

1.00  0.00  1.00  0.00    1.00

1.00   .25   .65   .25     .85

1.00  1.00  1.00  1.00    1.00

1.00

i.OO   .28  1.00   .28    1.00

1.00  1.00  1.00  1.00    1.00

1.00   .75  i.OO   .75    1.00
1025.97    1150.19
                      862.64    1150.19

   0.00    1824.68      0.00    1824.68

  85.59     291.02     65.59     291.02

1031.69    1031.69   1031.69    1031.69

     NA         NA        NA         NA

 459.69    1641.75    459.69    1641.75

 948.64     948.64    948.64     948.64

 429.00     572.00    429.00     572.00
     NA         NA        NA         NA
3980,58    8167.40   3817.25    8167.40
1.00  0.00   .95  0.00    .95
   0.00    3605.25
   0.00    3605.25
            0.00   3605.25
            0.00   3605.25
                                                                                                                    NA
                                                                                                                    NA
                                                                        NA
                                                                        NA
                                                         NA
                                                         NA
                                    NA
                                    NA

-------
                                                                          Table 4  (Continued)
                                                                 VOC AND PROC EHISSIONS  IN CALIFORNIA
PRODUCT
MILLION  AVG.
 UNITS  PROD.
OISTBI   UT.
 BUTED  (Lfi)
   NATIONAL            GEOGR.
 CONSUMPTION   POP.     MULT I-
(HILLION LB)  APPORT.   PLIER
                                                                                              HEIGHT  FRACTION
                                                                                               VOC       PROC

                                                                                            LOU  HIGH    LOU  HIGH
                                                                                                               TOTAL VOC EMISSIONS  TOTAL PROC EMISSIONS
                                                                                                                     (TONS)               (TONS)
                                                                                                                   LOV
HIGH
LOU
HIGH
Ui
 i
     PERSONAL DEODORANTS AND ANTI-
       PIRSPIRANTS
     SHAVING LATHERS
     PRE-SHAVE PREPARATIONS
     AFTER-SHAVE LOTIONS & COLOGNES
        (LISTED UNDER AEROSOL)
     PERFUMES
        (LISTED UNDER AEROSOL)
     RUBBING COMPOUNDS (ALCOHOL)
     FACE WASHES (LIKE ASTRINGENTS)
     FACIAL CREAMS AND WASHES
     HAND LOTIONS
     SUN LOTIONS, CREAMS AND OILS
        (LISTED UNDER AEROSOL)
     HOUTHUASHES
     HAIR SPRAYS
     HAIR SHAMPOOS, RINSES AND OTHER
     HAIR PRODUCTS
SUB-TOTAL
      HOUSEHOLD  PRODUCTS
            SHOE  POLISHES
            BALL  POINT AND POROUS POINT PENS
            ROOM  DEODORANTS  AND DISINFECTANTS
                                                                                                                    NA

                                                                                                                    NA
                                                                                                                    NA
                                                                                                                    NA

                                                                                                                    NA

                                                                                                                    NA
                                                                                                                    NA
                                                                                                                    NA
                                                                                                                    NA
                                                                                                                    NA

                                                                                                                    NA
                                                                                                                    NA

                                                                                                                    NA
                                                                                                                  0.00
                                                                                                                    NA
                                                                                                                    NA
                                                                                                                    NA
    NA

    NA
    NA
    NA

    NA

    NA
    NA
    NA
    NA
    NA
                                                                                                                                      NA

                                                                                                                                      NA
                                                                                                                                    0.00
                                                                                                                                NA
                                                                                                                                NA
                                                                                                                                NA
                                                                                                   NA

                                                                                                   NA
                                                                                                   NA
                                                                                                   NA

                                                                                                   NA

                                                                                                   NA
                                                                                                   NA
                                                                                                   NA
                                                                                                   NA
                                                                                                   NA

                                                                                                   NA
                                                                                                   NA

                                                                                                   NA
                                                                                                0.00
                                                                                                   NA
                                                                                                   NA
                                                                                                   NA
                                                                                            NA

                                                                                            NA
                                                                                            NA
                                                                                            NA

                                                                                            NA

                                                                                            NA
                                                                                            NA
                                                                                            NA
                                                                                            NA
                                                                                            NA

                                                                                            NA
                                                                                            NA

                                                                                            NA
                                                                                          0.00
                                                                                            NA
                                                                                            NA
                                                                                            NA
   CLEANERS
     OVEN CLEANERS
     RUG AND UPHOLTERV CLEANERS
     UINDOU AND GLASS CLEANERS
     FLOOR CLEANERS
     TILE AND BATHROOM CLEANERS
                                                                              NA
                                                                              NA
                                                                              NA
                                                                              NA
                                                                              NA
                                                                        NA
                                                                        NA
                                                                        NA
                                                                        NA
                                                                        NA
                                                                                                                                                NA
                                                                                                                                                NA
                                                                                                                                                NA
                                                                                                                                                NA
                                                                                                                                                NA
                                                                                                                                                   NA
                                                                                                                                                   NA
                                                                                                                                                   NA
                                                                                                                                                   NA
                                                                                                                                                   NA

-------
                                                                                Table 4 (Continued)
                                                                       VOC AND PROC EMISSIONS IN CALIFORNIA
      PRODUCT
                                       HILLION  AVG.
                                        UNITS  PtOD.
                                       DISTRI   UT.
                                        BUTED  (LB)
   NATIONAL            GEOGR.
 CONSUMPTION   POP.     MULT I-
(HILLION LB)  APPORT.   PLIER   LOU  HIGH
                                                                                              WEIGHT  FRACTION
                                                                                               VOC       PROC
             TOTAL VOC EMISSIONS  TOTAL PROC EMISSIONS
                   (TONS)                (TONS)
LOU  HIGH
                                                     LOU
HIGH
LOU
HIGH
Ol
 i
LJ
     UALL CLEANERS

     UAXES AND POLISHES (LIQUIDS)
       FORMULATIONS 2,3
     FLOOR UAXES OR POLISHES
       FORMULATIONS 1,2,3 (2)
     RUG DEODORIZERS AND FRESHENERS
     LAUNDRY SPOT REMOVERS
     HOTH CONTROL PRODUCTS
     METAL CLEANERS AND POLISHES
       FORMULATIONS 2,3,4,5,7 (2)
     HOUSEHOLD ADHESIVES
     FURNITURE POLISHES AND UAXES
SUB-TOTAL
                                                                                                                           NA
                                                                        NA
                                       NA
                                                                                     NA
3.00 .11
27.00 .11



24.00 .11



1.00 .24 .94 .24 .94 39.60
1.04 .20 .20 .20 .20 308.88
NA
NA
NA
1.00 0.00 1.00 0.00 1.00 0.00
NA
NA
348.48
155.10
308.86
NA
NA
NA
1320.00
NA
NA
1783.98
39.60
308.88
NA
NA
NA
o.oo
NA
NA
348.48
155.10
308.68
NA
NA
NA
1320.00
NA
NA
1783.98
      AUTOMOTIVE
           AUTO ANTIFREEZES
             FORMULATIONS 1
           CAR POLISHES AND UAXES
             FORMULATIONS 1,2
           WINDSHIELD UASHER FLUID
      SUB-TOTAL
                                        189.10   1.00
22.30     .11     1.00   .95   .95    .95

          .11     1.05   .42   .42    .42
                                                                                                          .95   1165.17    1165.17   1165.17   1165.17
      GARAGE PRODUCTS
           HOUSEHOLD GLUE AND BONDING AGENTS
           HOUSEHOLD CAULKS AND SEALANTS
           INSECTICIDES
           HERBICIDES
           FUNGICIDES
           BARBECUE LIGHTER FLUIDS
           AUTO WINDSHIELD UASHERS
                                                  .42   4619.38
                                                             NA
                                                        5784.56
                                                                                                                    NA
                                                                                                                    NA
                                                                                                                    NA
                                                                                                                    NA
                                                                                                                    NA
                                                                                                                    NA
                                                                                                                    NA
                        4630.30   4619.38   4630.30
                            NA       NA        NA
                        5795.48   5764.56   5795.48
                                                                        NA
                                                                        NA
                                                                        NA
                                                                        NA
                                                                        NA
                                                                        NA
                                                                        NA
                                      NA
                                      NA
                                      NA
                                      NA
                                      NA
                                      NA
                                      NA
                                                                                     NA
                                                                                     NA
                                                                                     NA
                                                                                     NA
                                                                                     NA
                                                                                     NA
                                                                                     NA

-------
                                                                         Table 4 (Continued)
                                                                 VOC AND PROC EMISSIONS IN CALIFORNIA
                                       MILLION  AVG.                                     HEIGHT   FRACTION        TOTAL  VOC EMISSIONS  TOTAL PROC EMISSIONS
                                        UNITS  PROD.       NATIONAL            GEOGR.      VOC       PROC               (TONS)                (TONS)
                                       DISTRI   UT.      CONSUMPTION   POP.     MULTI-
PRODUCT                                 BUTED  
-------
                                                                                    Table 5
                                                                        VOC AND PROC EMISSIONS IN NEU JERSEY
                                              MILLION  AVG.                                    WEIGHT  FRACTION        TOTAL VOC EMISSIONS  TOTAL PROC EMISSIONS
                                               UNITS  PROD.      NATIONAL            GEOGR.      VOC       PROC               (TONS)                (TONS)
                                              DISTRI   UT.     CONSUMPTION   POP.     MULTI-
       PBODUCT                                 BUTED  (LB)    (HILLION LB)  APPORT.  PLIER   LOU  HIGH    LOU  HIGH       LOU      HIGH        LOU      HIGH
Ln
 I
Nl
Ul
AEROSOL/NON-AEROSOL PRODUCTS (1)

INSECT SPRAY PRODUCTS
     INSECT SPRAYS (AEROSOL AND
     NON-AEROSOL)
       FORMULATIONS 2,6
     INSECT REPELLENTS (AEROSOL AND
     NON-AEROSOL)
       FORMULATIONS 1,5
     MOTH CONTROL PRODUCTS (AEROSOL
     AND NON-AEROSOL)
       FORMULATIONS 1,2
     ANIMAL INSECTICIDES (AEROSOL
     AND NON-AEROSOL)
       FORMULATIONS 3,4
SUB-TOTAL
        PAINTS  AND  FINISHES
             PAINTS,  PRIMERS,  VARNISHES
               FORMULATIONS  5,6
               FORMULATIONS  3,6
             OTHER  RELATED PRODUCTS
               FORMULATIONS  1
        SUB-TOTAL
        HOUSEHOLD PRODUCTS
             ROOM DEODORANTS  AND  DIS-
             INFECTANTS  (AEROSOL  AND NON-
             AEROSOL)
              FORMULATIONS 2,4
              FORMULATIONS 1,4
                                        300.60
                                        300.60

                                           6.9
.75
.75
                                        265.50    .50
                                        265.50    .50
                                                                     192.5     .03     1.00   .05  1.00  0.00   1.00    149.19     2963.75      0.00   2983.75
                                                                     12.00     .03     1.00   .35   .65   .35     .65     64.91      158.10     64.91     158.10
            39.00     .03     1.00    .96   1.00   .96   1.00    580.32     602.08    580.32    602.08
                                                                      6.00     .03     1.00   .55  1.00   .55    1.00     51.15      92.72     51.15     92.72
                                                                                                                       645.57    3836.65    696.38   3836.65
.03     1.05   .73   .87
.03     1.05               .67

.03     1.00   .65   .65   .65
      2682.18    3168.53
.87
2458.36   3168.53
                                                       .65     47.97      47.97     47.97     47.97
                                                             2730.15    3236.50   2506.33   3236.50
                      .03      .94    .35   1.00                 686.63    1934.17
                      .03      .94               .35    .87                         686.63   1682.73

-------
                                                                                Tabte 5 (Continued)
                                                                        VOC AND PROC EMISSIONS IN NEV JERSEY
        PIODUCT
MILLION  AVG.
 UNITS  PROD.
DISTRI   VT.
 BUTED  (LB)
   NATIONAL           GEOGB.
 CONSUMPTION   POP.    HULTI-
(MILLION LB)  APPORT.  PLIER
                                                                                    UEIGHT  FRACTION
                                                                                     VOC       PROC

                                                                                  LOU  HIGH    LOU  HIGH
                                                                                                                       TOTAL VOC  EMISSIONS  TOTAL PROC EMISSIONS
                                                                                                                             (TONS)               (TONS)
                                          LOU
                                                              HIGH
                       LOU
                     HIGH
Ui
 I
CLEANERS
  TILE AND BATHROOM CLEANERS
    FORMULATIONS 1,2,3,4,5 (2)
    FORMULATIONS 2,3,4,5 (2)
  OVEN CLEANERS (AEROSOL AND
  NON-AEROSOL)
    FORMULATIONS 3,4
  RUG AND UPHOLSTERY CLEANERS
  (AEROSOL AND NON-AEROSOL)
    FORMULATIONS 1,3
  ALL PURPOSE CLEANERS
  (AEROSOL AND NON-AEROSOL)
    FORMULATIONS 1,2
  UINDOU AND GLASS CLEANERS
  (AEROSOL AND NON-AEROSOL)
    FORMULATIONS 6,7
  LAUNDRY PRODUCTS-AEROSOLS
  STARCH, FABRIC FINISH
    FORMULATIONS 1,2

LAUNDRY PRODUCTS
(AEROSOL AND NON-AEROSOL)
  PREUASH STAIN REMOVERS
    FORMULATIONS 1,2
  SPOT REMOVERS
    FORMULATIONS 1,2

  UAXES AND POLISHES
    FORMULATIONS 1,3
  ALL OTHER HOUSEHOLD SPRAY PRODUCTS
    FORMULATIONS
                                                109.90    .75
                                                 45.2    .75
65.00     .03     1.00  0.00   .33
65.00     .03     1.00              0.00    .33
                                                                     33.00
                                                                    115.00
                                                                    512.00
                                                                    174.00
                                                                     84.00
 2.30
                                                                     58.00
.03
.03
.03
.03
.03
.03
.03
.03
.03
                                                                                                                         0.00
                                                   332.48
                                                                                                                                              0.00    332.46
                                         1.00  0.00   .20  0.00     .20
                                                    0.00
           102.30
            0.00    102.30
                                         1.00   .03   .26    .03     .26
                                                   60.61
           463.45
           60.61    463.45
                  1.00   .02   .41    .02    .41     158.72    3245.62    158.72   3245.82
                  1.00  0.00   .42  0.00    .42
  0.00    1132.74
            0.00   1132.74
                  1.00   .05   .11    .05     .11
 62.60
143.09
                                                                                               62.60    143.09
                  1.00  0.00  0.00  0.00   0.00
                                         1.00  1.00  1.00    .90   1.00
  0.00
                                                                                                                        35.65
  0.00
                                                                                                0.00
            35.65     32.09
                  1.00   .07   .34    ,07     .34
                  1.00
 62.93
NA (4)
    NA
                                                                                                  NA
                                                                                         0.00
                     35.65
305.66     62.93    305.66
                                                                                            NA

-------
                                                                         Table 5  (Continued)
                                                                 VOC AND PROC EMISSIONS  IN NEU JERSEY
PRODUCT
MILLION  AVG.                                     UEIGHT  FRACTION
 UNITS  PROD.       NATIONAL            GEOGR.      VOC       PROC
DISTRI   UT.     CONSUMPTION   POP.     HULTI-
 BUTED  (LB)    (MILLION LB)  APPORT.   PLIER   LOV  HIGH    LOU  HIGH
                                                                                                               TOTAL VOC EMISSIONS  TOTAL PROC EMISSIONS
                                                                                                                     (TONS)               (TONS)
                                                                LOU
                                                   HIGH
                                                      LOU
                                       HIGH
     SHOE POLISHES, WAXES AND COLOR-
     ANTS (AEROSOL AND NON-AEROSOL)
       FORHULATIONS 1,2
     ANTISTATIC SPRAYS
       FORHULATIONS 1,2
     ADHESIVES (5)
     (AEROSOL AND NON-AEROSOL)
       FORHULATIONS 2,3,6 (2)
     CAULKING AND SEALING CPDS (5)
     (AEROSOL AND NON-AEROSOL)
       FORHULATIONS 1,2
     CARPET DEODORIZERS
     (AEROSOL AND NON-AEROSOL)
       FORHULATIONS 1

   DRAIN OPENERS
     (AEROSOL AND NON-AEROSOL)
     LIQUIDS
       FORHULATIONS 2  (NO VOC)
      SOLIDS
       FORHULATIONS 1
SUB-TOTAL
PERSONAL PRODUCTS
     SHAVING LATHERS
       FORHULATIONS 2,4
     HAIR SPRAYS
       FORHULATIONS 1,4
       FORHULATIONS 4,5
     STYLING HOUSSE
       FORHULATIONS 1
 270.70
 270.70
                        6.00     .03     1.00   .13   .98    .13     .96      12.09      91.14     12.09     91.14

                        3.00     .03     1.00  0.00   .03   0.00     .03      0.00        1.40      0.00      1.40


                     3277.50     .03     1.00  0.00   .85   0.00     .65      0.00   43181.06      0.00  43181-06


                      432.80     .03     1.00  0.00   .20   0.00     .20      0.00     1341.68      0.00    1341.68


                       65.00     .03      .96   .02   .02    .02     .02      19.34      19.34     19.34     19.34
              17 (MIL.GAL.I      .03      .94  0.00  0.00 0.00   0.00      0.00       0.00      0.00      0.00

                      293.00     .03      .94  0.00  0.00 0.00   0.00      0.00       0.00      0.00      0.00
                                                                        1079.23   52310.63   1075.66  52059.19
 162.80    .50
.63
.63
 106.10    .38
.03

.03
.03

.03
                              1.07   .03    .09    .03    .09     41.85     120.15     41.85    120.15
.87   .88   .97
.87               .73
      2026.08    2242.25
.97                        1681.11    2242.25
                              1.00   .24    .24    .24    .24    153.11     153.11    153.11    153.11

-------
                                                                         Table 5 (Continued)
                                                                 VOC AND PROC  EMISSIONS  IN NEW JERSEY









Ul
1
to
00









PRODUCT
OTHER HAIR CARE PRODUCTS-SHAMPOO
(AEROSOL AND NON-AEROSOL)
FORMULATIONS 1,2,3 (2)
PHARMACEUTICALS
FORMULATIONS 1,3
FORMULATIONS 2,3
COLOGNES
FORMULATIONS 1
PERFUMES
FORMULATIONS 1
AFTERSHAVES
FORMULATIONS 1
PERSONAL DEODORANTS AND ANTI-
PERSPI RANTS
FORMULATIONS 1,2
OTHER PERSONAL CARE PRODUCTS
SUNTAN LOTIONS (2)
FORMULATIONS 1,4,5 (2)
DEPILATORIES
FORMULATIONS 1,2
SUB-TOTAL
MILLION AVG.
UNITS PROD. NATIONAL
DISTRI UT. CONSUMPTION POP.
BUTED (LB) (MILLION LB) APPORT.




43.70
43.70

44.00

82.00
23.00


156.00


15.1

15.10





.25
.25

.12

.03
.25


.25


.13

.13



644.60 .03

.03
.03

.03

.03
.03


.03


.03

.03

GEOGR.
MULTI-
PLIER


1.00

.98
.98

1.00

1.00
1.00


.89


1.06

1.08

. WEIGHT FRACTION
VOC PROC
LOU HIGH LOU HIGH


0.00

.70


1.00

1.00
.65


.80


0.00

.10



.01

.99


1.00

1.00
.65


.95


.65

.10



0.00


.70

1.00

1.00
.65


.80


0.00

.10



.01


.99

1.00

1.00
.65


.95


.65

.10

TOTAL VOC EMISSIONS
(TONS)
LOU HIGH


0.00

116.00


85.25

38.13
57.75


430.40


0.00

3.29
2951.86


49.96

165.12


85.25

38.13
57.75


511.10


20.96

3.45
3447.24
TOTAL PROC EMISSIONS
(TONS)
LOU HIGH


0.00


116.00

85.25

38.13
57.75


430.40


0.00

3.29
2606.89


49.96


165.12

85.25

38.13
57.75


511.10


20.96

3.45
3447.24
AN I HAL PRODUCTS
     VETERINARIAN AND PET PRODUCTS
SUB-TOTAL
AUTOMOTIVE AND INDUSTRIAL PRODUCTS
     REFRIGERANTS
     CLEANERS (AEROSOL AND NON-AEROSOL)
       FORMULATIONS 4,7                  14.70
                                            NA         NA        NA        NA
                                          0.00       0.00      0.00      0.00
.03
1.00  0.00  1.00 0.00    1.00
  NA         NA        NA        NA

0.00     199.37      0.00    199.37

-------
                                                                         Table 5 (Continued)
                                                                 VOC AND PROC EMISSIONS  IN NEW JERSEY
PRODUCT
HILLI ON  AV6.
 UNITS  PROD.
DISTRI   VT.
 BUTED  (LB)
   NATIONAL            GEOGR.
 CONSUMPTION   POP.     MULTI-
(MILLION LB)  APPORT.   PLIER   LOU   HIGH
                                                                                       UEIGHT  FRACTION
                                                                                         VOC       PROC
                                                 TOTAL VOC EHISSIONS  TOTAL PROC EHISSIONS
                                                       (TONS)               (TONS)
                                     LOU   HIGH
LOU
                                                                                                                                HIGH
                                                               LOU
HIGH

-------
                                                                               Table S (Continued)
                                                                       VOC AND PROC EMISSIONS IN NEU JERSEY
       PRODUCT
                                       MILLION  AVG.
                                        UNITS  PIOD.
                                       DISTRI   VT.
                                        BUTED  (LB)
   NATIONAL           GEOGR.
 CONSUMPTION   POP.    MULTI-
(HILLION LB)  APPORT.  PLIER
  HEIGHT  FRACTION
   VOC       PROC

LOU  HIGH    LOU  HIGH
                                                                                                                      TOTAL VOC EHISSIONS
                                                                                                                            (TONS)
                  TOTAL PROC EMISSIONS
                        (TONS)
LOU
HIGH
LOU
HIGH
Ul
     PERSONAL DEODORANTS AND ANTI-
       PIRSPIRANTS
     SHAVING LATHERS
     PRE-SHAVE PREPARATIONS
     AFTER-SHAVE LOTIONS I COLOGNES
        (LISTED UNDER AEROSOL)
     PERFUMES
        (LISTED UNDER AEROSOL)
     RUBBING COMPOUNDS (ALCOHOL)
     FACE UASHES (LIKE ASTRINGENTS)
     FACIAL CREAMS AND UASHES
     HAND LOTIONS
     SUN LOTIONS, CREAMS AND OILS
        (LISTED UNDER AEROSOL)
     HOUTHUASHES
     HAIR SPRAYS
     HAIR SHAMPOOS, RINSES AND OTHER
     HAIR PRODUCTS
SUB-TOTAL
       HOUSEHOLD PRODUCTS
            SHOE POLISHES
            BALL POINT AND POROUS  POINT PENS
            ROOM DEODORANTS  AND DISINFECTANTS
                                                             NA

                                                             NA
                                                             NA
                                                             NA

                                                             NA

                                                             NA
                                                             NA
                                                             NA
                                                             NA
                                                             NA

                                                             NA
                                                             NA

                                                             NA
                                                           0.00
                                                                                                                    NA
                                                                                                                    NA
                                                                                                                    NA
                                          NA

                                          NA
                                          NA
                                          NA

                                          NA

                                          NA
                                          NA
                                          NA
                                          NA
                                          NA

                                          NA
                                          NA

                                          NA
                                        0.00
                       NA

                       NA
                       NA
                       NA

                       NA

                       NA
                       NA
                       NA
                       NA
                       NA

                       NA
                       NA

                       NA
                     0.00
                        NA

                        NA
                        NA
                        NA

                        NA

                        NA
                        NA
                        NA
                        NA
                        NA

                        NA
                        NA

                        NA
                      0.00
                                                                        NA
                                                                        NA
                                                                        NA
                                                    NA
                                                    NA
                                                    NA
                                 NA
                                 NA
                                 NA
          CLEANERS
            OVEN CLEANERS
            RUG  AND UPHOLSTERY CLEANERS
            UINDOU AND GLASS CLEANERS
            FLOOR CLEANERS
            TILE AND  BATHROOM CLEANERS
                                                                                                                    NA
                                                                                                                    NA
                                                                                                                    NA
                                                                                                                    NA
                                                                                                                    NA
                                                                        NA
                                                                        NA
                                                                        NA
                                                                        NA
                                                                        NA
                                                    NA
                                                    NA
                                                    NA
                                                    NA
                                                    NA
                                 NA
                                 NA
                                 NA
                                 NA
                                 NA

-------
                                                                        Table 5 (Continued)
                                                                VOC AND PROC EMISSIONS IN NEU JERSEY
PRODUCT

     WALL CLEANERS

     UAXES AND POLISHES (LIQUIDS)
       FORMULATIONS 2,3
     FLOOR WAKES OR POLISHES
       POPULATIONS 1,2,3 (2)
     RUG DEODORIZERS AND FRESHENERS
     LAUNDRY SPOT REMOVERS
     MOTH CONTROL PRODUCTS
     HETAL CLEANERS AND POLISHES
       FORMULATIONS 2,3,4,5,7 (2)
     HOUSEHOLD ADHESIVES
     FURNITURE POLISHES AND UAIES
SUB-TOTAL
MILLION  AVG.
 UNITS  PROD.
DISTRI   UT.
 BUTED  (LB)
                                                                                       WEIGHT  FRACTION
                                                        TOTAL VOC EMISSIONS  TOTAL PROC EMISSIONS
   NATIONAL           GEOGR.
 CONSUMPTION  POP.    MULTI-
(MILLION LB)  APPORT.  PLIER
                                                                                        VOC
             PROC
   (TONS)
               (TONS)
LOU  HIGH    LOU  HIGH
LOU
HIGH
LOU
HIGH
                                                                             NA
                                                                        NA
                                                    NA
AUTOMOTIVE
     AUTO ANTIFREEZES
       FORMULATIONS 1
     CAR POLISHES AND UAXES
       FORMULATIONS 1,2
     WINDSHIELD UASHER FLUID
SUB-TOTAL
 189.10   1.00
GARAGE PRODUCTS
     HOUSEHOLD GLUE AND BONDING AGENTS
     HOUSEHOLD CAULKS AND SEALANTS
     INSECTICIDES
     HERBICIDES
     FUNGICIDES
     BARBECUE LIGHTER FLUIDS
     AUTO WINDSHIELD UASHERS
                                 NA
3.00
27.00



24.00



.03 1.00 .24 .94 .24 .94 ii.16
.03 1.02 .20 .20 .20 .20 85.37
NA
NA
NA
.03 1.00 0.00 1.00 0.00 1.00 0.00
NA
NA
96.53
43.71
85.37
NA
NA
NA
372.00
NA
NA
501.08
11.16
85.37
NA
NA
NA
0.00
NA
NA
96.53
43.71
85.37
NA
NA
NA
372.00
NA
NA
501.08
       22.30     .03      1.00    .95    .95   .95    .95    328.37     328.37    328.37    328.37

                 .03       .90    .42    .42   .42    .42   1115.65    1118.49   1115.85   1118.49
                                                             NA         NA        NA        NA
                                                        1444.22    1446.86   1444.22   1446.86
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA

-------
                                                                         Table 5 (Continued)
                                                                 VOC AND PROC EMISSIONS IN NEU JERSEY
                                       MILLION  AVG.                                     WEIGHT  FRACTION        TOTAL  VOC  EMISSIONS   TOTAL  PROC EMISSIONS
                                        UNITS  PROD.       NATIONAL            GEOGR.      VOC       PROC               (TONS)                (TONS)
                                       DISTRI   UT.     CONSUMPTION   POP.     MULTI-
PRODUCT                                 BUTED  (LB)    (MILLION LB)  APPORT.   PLIER   LOU  HIGH    LOU HIGH       LOU     HIGH        LOU      HIGH

     DEGREASERS                                                                                                     NA         NA       NA         NA
SUB-TOTAL                                                                                                          0.00      0.00      0.00       0.00
TOTAL EMISSIONS                                                                                                10269.36   66096.71   9501.79  67645.27
(1) Products in these sub-categories are aerosol unless it Is indicated that aerosol  and non-aerosol  are conbined.
(2) More than two listed /emulations indicates that several  product tabulations had the sane  low  or high  weight percent.
(3) Suntan lotion use varies strongly with season.  However,  the total enission estiiate is independent  of  seasonal  fluctuation.
<4> NA Indicates that emissions could not be calculated because either product use or foriulation data were not available.
(5) Includes industrial, connercial, and consuner products.

-------
                                                                                      Table 6
                                                                         VOC AND PBOC EMISSIONS IN NEU YOIK
01
 i
CJ
                                             MILLION  AV6.                                    WEIGHT  FRACTION        TOTAL VOC EMISSIONS  TOTAL PROC ENISSIONS
                                              UNITS  PROD.      NATIONAL            GE06R.     VOC       PROC               (TONS)               (TONS)
                                             DISTRI   UT.     CONSUMPTION   POP.    MULTI-
       PRODUCT                                BUTED  (LB)     (MILLION LB)  APPORT.  PLIER   LOV  HIGH    LOU  HIGH       LOU      HIGH        LOU      HIGH

       AEROSOL/NON-AEROSOL PRODUCTS (1)
 INSECT SPRAY PRODUCTS
      INSECT SPRAYS (AEROSOL AND
     NON-AEROSOL)
       FORMULATIONS 2,8
      INSECT REPELLENTS (AEROSOL AND
     NON-AEROSOL)
       FORMULATIONS 1,5
     MOTH CONTROL PRODUCTS (AEROSOL
     AND NON-AEROSOL)
       FORMULATIONS 1,2
     ANIMAL INSECTICIDES (AEROSOL
     AND NON-AEROSOL)
       FORMULATIONS 3,4
SUB-TOTAL
       PAINTS AND FINISHES
            PAINTS,  PRIMERS,  VARNISHES
              FORMULATIONS  5,6
              FORMULATIONS  3,6
            OTHER RELATED PRODUCTS
              FORMULATIONS  1
       SUB-TOTAL
      HOUSEHOLD  PRODUCTS
            ROQH  DEODORANTS  AND DIS-
            INFECTANTS  (AEROSOL AND NON-
            AEROSOL)
             FORMULATIONS 2,4
             FORMULATIONS 1.4
                                        300.60
                                        300.60
.75
.75
                                           6.9    .69
                                        265.50    .50
                                        265.50    .50
                                                                     192.5     .05     1.00   .05  1.00  0.00   1.00    221.36    4427.50      0.00   4427.50
                                                                    12.00     .05     1.00   .35   .65   .35    .65     96.32     234.60     96.32    234.60
                                                                    39.00     .05     1.00   .96  1.00
                                                       1.00    861.12     893.41    861.12    693.41
                                                                     6.00     .05     1.00   .55  1.00   .55   1.00     75.90     137.59     75.90    137.59
                                                                                                                      1254.72    5693.10   1033.34   5693.10
.05     1.05   .73   .67
.05     1.05               .67

.05     1.00   .65   .65   .65
      3960.02    4731.37
.87
3647.89   4731.37
                                                        .65     71.18      71.18     71.18     71.18
                                                             4051.19    4602.55   3719.07   4802.55
                      .05      .94   .35  1.00                1018.67    2870.05
                      .05      .94               .35    .87                        1018.87   2496.95

-------
                                                                               Table 6 (Continued)
                                                                       VOC AND PBOC EMISSIONS IN NEU YORK



PRODUCT
CLEANERS
TILE AND BATHROOM CLEANERS
FORMULATIONS 1,2,3,4,5 (2)
FORMULATIONS 2,3,4,5 (2)
MILLION
UNITS
DISTRI
BUTED




AVG.
PROD.
UT.
(LB)





NATIONAL
CONSUMPTION
(MILLION LB)


65.00
65.00


POP.
APPORT.


.05
.05

GEOGR.
MULTI-
PLIER


1.00
1.00
HEIGHT
VOC

LOU HIGH


FRACTION
PROC

LOU HIGH
*

0.00 .33

0.00 .33
TOTAL VOC
EMISSIONS
(TONS)

LOU


0.00


HIGH


493.35

TOTAL PROC
EMISSIONS
(TONS)

LOU



0.00

HIGH



493.35
Ul
 i
  OVEN CLEANERS (AEROSOL AND
  NON- AEROSOL)
    FORMULATIONS 3,4
  RUG AND UPHOLSTERY CLEANERS
  (AEROSOL AND NON-AEROSOL)
    FORMULATIONS 1,3
  ALL PURPOSE CLEANERS
  (AEROSOL AND NON-AEROSOL)
    FORMULATIONS 1,2
  UINDOU AND GLASS CLEANERS
  (AEROSOL AND NON-AEROSOL)
    FORMULATIONS 6,7
  LAUNDRY PRODUCTS-AEROSOLS
  STARCH, FABRIC FINISH
    FORMULATIONS 1,2

LAUNDRY PRODUCTS
(AEROSOL AND NON-AEROSOL)
  PREUASH STAIN REMOVERS
    FORMULATIONS 1,2
  SPOT REMOVERS
    FORMULATIONS 1,2

  VAXES AND POLISHES
    FORMULATIONS 1,3
  ALL OTHER HOUSEHOLD SPRAY PRODUCTS
    FORMULATIONS
                                             109.90    .75
                                                                  33.00     .05     1.00  0.00   .20  0.00    .20      0.00     151.60      0.00    151.80
115.00


512.00


174.00
                                                                  84.00

                                                                   2.30


                                                                  56.00
                                                                            .05     1.00   .03   .26   .03    .26     89.93     687.70     89.93    667.70
                                                                            .05     1.00   .02   .41   .02    .41     235.52    4616.38    235.52   4616.38
.05


.05
                                               45.2    .75
.05

.05


.05

.05
                                                                                    1.00  0.00   .42  0.00    .42     0.00     1680.64      0.00   1660.84
                   1.00   .05    .11    .05    .11     92.89     212.33     92.69    212.33
        1.00 0.00  0.00  0.00   0.00

        1.00 1.00  1.00   .90   1.00


        1.00   .07    .34   .07    .34

        1.00
                                                     0.00       0.00      0.00      0.00

                                                    52.90      52.90     47.61     52.90


                                                    93.38     453.56     93.38    453.56

                                                   NA (4)         NA        NA        NA

-------
                                                                           Table 6  (Continued)
                                                                   VOC AND PROC EMISSIONS  IN NEW YORK
MILLION AVG.
UNITS PROD. NATIONAL
DISTRI UT. CONSUMPTION POP.
PRODUCT BUTED (LB) (MILLION LB) APPORT.
OTHER HAIR CARE PRODUCTS-SHAMPOO
(AEROSOL AND NON-AEROSOL)
FORMULATIONS 1,2,3 (2)
PHARMACEUTICALS
FORMULATIONS 1,3 43.70 .25
FORMULATIONS 2,3 43.70 .25
COLOGNES
FORMULATIONS 1 44.00 .12
PERFUMES
FORMULATIONS 1 82.00 .03
7 AFTERSHAVES
£ FORMULATIONS 1 23.00 .25
PERSONAL DEODORANTS AND ANTI-
PERSPI RANTS
FORMULATIONS 1,2 156.00 .25
OTHER PERSONAL CARE PRODUCTS
SUNTAN LOTIONS (2)
FORMULATIONS 1,4,5 (2) 15.1 .13
DEPILATORIES
FORMULATIONS 1,2 15.10 .13
SUB-TOTAL
ANIMAL PRODUCTS
VETERINARIAN AND PET PRODUCTS
SUB-TOTAL


644.60 .05

.05
.05

.05

.05

.05


.05


.05

.05




HEIGHT FRACTION TOTAL VOC EMISSIONS
GEOGR. VOC PROC (TONS)
MULTI-
PLIER LOU HIGH LOU HIGH LOU HIGH


1.00 0.00 .01 0.00 .01 0.00

.98 .70 .99 172.13
.98 .70 .99

1.00 1.00 1.00 1.00 1.00 126.50

1.00 1.00 1.00 LOO 1.00 56.58

1.00 .65 .65 .65 .65 85.70


.69 .80 .95 .80 .95 638.66


1.06 0.00 .65 0.00 .65 0.00

1.08 .10 .10 .10 .10 4.88
4380.17

NA
0.00


74.13

245.02


126.50

56.58

65.70


758.41


31.11

5.12
5115.26

NA
0.00
TOTAL PROC EMISSIONS
(TONS)
LOU HIGH


0.00


172. 13

126.50

56.58

85.70


638.66


0.00

4.88
3868.30

NA
0.00


74.13


245.02

126.50

56.58

85.70


758.41


31.11

5.12
5115.26

NA
0.00
AUTOMOTIVE AND INDUSTRIAL PRODUCTS
     REFRIGERANTS
     CLEANERS (AEROSOL AND NON-AEROSOL)
       FORMULATIONS 4,7                  14.70    .88                   .05     1.00  0.00   1.00  0.00   1.00      0.00     295.84      0.00    295.84

-------
                                                                                Table 6 (Continued)
                                                                        VOC AND PROC EMISSIONS-IN NEW YOiK
01
 i
u>
ON
                                       MILLION  AVG.                                    WEIGHT  FRACTION        TOTAL VOC EMISSIONS  TOTAL PROC EMISSIONS
                                        UNITS  PROD.       NATIONAL            GEOGR.     VOC       PROC               (TONS)               (TONS)
                                       DISTRI   HT.      CONSUMPTION   POP.     MULTI-
PRODUCT                                 BUTED  (LB)     (MILLION LB)  APPORT.   PLIER    LOU  HIGH    LOU  HIGH       LOU      HIGH        LOU      HIGH

     SHOE POLISHES, UAXES AND COLOR-
     ANTS (AEROSOL AND NON-AEROSOL)
       FORMULATIONS 1,2
     ANTISTATIC SPRAYS
       FORHULATIONS 1,2
     ADHESIVES (S)
     (AEROSOL AND NON-AEROSOL)
       FORHULATIONS 2,3,6 (2)
     CAULKING AND SEALING CPDS (5)
     (AEROSOL AND NON-AEROSOL)
       FORHULATIONS 1,2
     CARPET DEODORIZERS
     (AEROSOL AND NON-AEROSOL)
       FORHULATIONS I

   DRAIN OPENERS
   (AEROSOL AND NON-AEROSOL)
     LIQUIDS
       FORHULATIONS 2  (NO VOC)
      SOLIDS
       FORHULATIONS I
SUB-TOTAL
      PERSONAL PRODUCTS
           SHAVING LATHERS
             FORHULATIONS 2,4
           HAIR SPRAYS
             FORHULATIONS 1,4
             FORHULATIONS 4,5
           STYLING HOUSSE
             FORHULATIONS I
             6.00     .05     1.00   .13    .98    .13     .98      17.94     135.24     17.94    135.24

             3.00     .05     1.00 0.00    .03  0.00     .03      0.00       2.07      0.00      2.07


          3277.50     .05     1.00 0.00    .85  0.00     .85      0.00   64075.12      0.00  64075.12


           432.80     .05     1.00 0.00    .20  0.00     .20      0.00    1990.88      0.00   1990.88


            65.00     .05      .96   .02    .02    .02     .02     28.70      28.70     28.70     26.70
                                                           17  (MIL.GAL.)       .05      .94  0.00  0.00  0.00   0.00      0.00      0.00      0.00      0.00

                                                                  293.00      .05      .94  0.00  0.00  0.00   0.00      0.00      0.00      0.00      0.00
                                                                                                                     1601.43  77622.23   1596.14  77249.12
                                        162.80    .50
                                        270.70
                                        270.70
.63
.63
                                        106.10    .38
.05

.05
.05

.05
                              1.07    .03    .09   .03    .09     62.10     178.29     62.10    178.29
.87   .86   .97
.87               .73
      3006.43    3327.21
.97                       2494.56   3327.21
                              1.00    .24    .24   .24    .24    227.19     227.19    227.19    227.19

-------
                                                                                 Table 6  (Continued)
                                                                         VOC AND PROC EMISSIONS IN NEW YOIK
in
 I
MILLION AVG.
UNITS PROD. NATIONAL
DISTRI UT. CONSUMPTION POP.
PRODUCT BUTED (LB) (MILLION LB) APPORT.
ENGINE DEGREASERS
FORMULATIONS 1,2,3 (2) 23.90 .68
FORMULATIONS 3 23.90 .88
LUBRICANTS AND SILICONES
FORMULATIONS 1,2 75.40 .44
UNDERCOAT INGS
FORMULATIONS 1 8.30 .75
BRAKE CLEANERS
FORMULATIONS 1, 2, or 3 16.60 1.13
TIRE SEALANTS AND INFLATORS
FORMULATIONS 19.30 .69
CARBURETOR AND CHOKE CLEANERS
FORMULATIONS 2,3 39.80 .75
ENGINE STARTING FLUIDS
FORMULATIONS 1 30.60 .56
UINDSHIELD DEICER (AEROSOL AND NON)
FORMULATIONS 1,2 10.40 1.00
OTHER AUTO AND INDUSTRIAL PRODUCTS
SUB-TOTAL
MISCELLANEOUS PRODUCTS
HERBICIDES AND FUNGICIDES
FORMULATIONS 1,7
SUB-TOTAL
NON-AEROSOL PRODUCTS

.05
.05

.05

.05

.05

.05

.05

.05

.05




69.00 .05


WEIGHT FRACTION
GEOGR. VOC PROC
MULTI-
PLIER LOU HIGH LOU HIGH

1.00 .89 1.00
1.00 .75

1.00 0.00 1.00 0.00

1.00 .25 .85 .25

1.00 1.00 1.00 1.00

1.00

1.00 .28 1.00 .26

1.00 1.00 1.00 1.00

1.00 .75 1.00 .75




1.00 0.00 .95 0.00




1.00

1.00

.85

1.00



1.00

1.00

1.00




.95


TOTAL VOC EMISSIONS
(TONS)
LOU HIGH

429.04


0.00

35.79

431.43

NA

192.23

396.70

179.40
NA
1664.61


0.00
0.00


480.99


763.05

121.70

431.43

NA

686.55

396.70

239.20
NA
3415.46


1507.65
1507.65

TOTAL PROC EMISSIONS
(TONS)
LOU HIGH


360.74

0.00

35.79

431.43

NA

192.23

396.70

179.40
NA
1596.31


0.00
0.00



480.99

763.05

121.70

431.43

NA

686.55

396.70

239.20
NA
3415.46


1507.65
1507.65

       PERSONAL  PRODUCTS
           NAIL POLISHES
           NAIL POLISH  REMOVERS
NA
NA
HA
NA
NA
NA
NA
NA

-------
                                                                                Table 6  (Continued)
                                                                        VOC AND PROC EMISSIONS IN NEU YORK
      PIODUCT
                                       MILLION  AV6.
                                        WITS  PROD.
                                       DISTRI   VT.
                                        BUTED  (LB)
   NATIONAL           GEOGi.
 CONSUHPTION    POP.    HULTI-
(HILLION LB)   APPORT.  PLIER
  HEIGHT  FRACTION
   VOC       PROC

LOU  HIGH    LOU  HIGH
                                                                                                                     TOTAL VOC EHISSIONS
                                                                                                                           (TONS)
                  TOTAL PROC EMISSIONS
                        (TONS)
LOU
HIGH
LOU
HIGH
tn
 I
CO
oo
     PERSONAL DEODORANTS AND ANTI-
       PIRSPIRANTS
     SHAVING LATHERS
     PRE-SHAVE PREPARATIONS
     AFTER-SHAVE LOTIONS & COLOGNES
         (LISTED UNDER AEROSOL)
     PERFUHES
         (LISTED UNDER AEROSOL)
     RUBBING COMPOUNDS (ALCOHOL)
     FACE UASHES (LIKE ASTRINGENTS)
     FACIAL CREAKS AND UASHES
     HAND LOTIONS
     SUN LOTIONS, CREAHS AND OILS
         (LISTED UNDER AEROSOL)
     HQUTHUASHES
     HAIR SPRAYS
     HAIR SHAHPOOS, RINSES AND OTHER
     HAIR PRODUCTS (SEE AEROSOL)
SUB-TOTAL
      HOUSEHOLD PRODUCTS
           SHOE POLISHES
           BALL POINT AND POROUS POINT PENS
           ROOM DEODORANTS AND DISINFECTANTS

         CLEANERS
           OVEN CLEANERS
           RUG  AND UPHOLSTERY CLEANERS
           UINDOU AND GLASS CLEANERS
           FLOOR CLEANERS
           TILE AND BATHROOM CLEANERS
                                                             NA

                                                             NA
                                                             NA
                                                             NA

                                                             NA

                                                             NA
                                                             NA
                                                             NA
                                                             NA
                                                             NA

                                                             NA
                                                             NA

                                                             NA
                                                           0.00
                                                                                                                    NA
                                                                                                                    NA
                                                                                                                    NA
                                                                                                                    NA
                                                                                                                    NA
                                                                                                                    NA
                                                                                                                    NA
                                                                                                                    NA
                                          NA

                                          NA
                                          NA
                                          NA

                                          NA

                                          NA
                                          NA
                                          NA
                                          NA
                                          NA

                                          NA
                                          NA

                                          NA
                                       0.00
                                                                        NA
                                                                        NA
                                                                        NA
                                                                        NA
                                                                        NA
                                                                        NA
                                                                        NA
                                                                        NA
                       NA

                       NA
                       NA
                       NA

                       NA

                       NA
                       NA
                       NA
                       NA
                       NA

                       NA
                       NA

                       NA
                    0.00
                                                   NA
                                                   NA
                                                   NA
                                                   NA
                                                   NA
                                                   NA
                                                   NA
                                                   NA
                        NA

                        NA
                        NA
                        NA

                        NA

                        NA
                        NA
                        NA
                        NA
                        NA

                        NA
                        NA

                        NA
                     0.00
                                NA
                                NA
                                NA
                                NA
                                NA
                                NA
                                NA
                                NA

-------
                                                                                Table 6 (Continued)
                                                                        VOC AND PROC EMISSIONS IN NEU YORK
     PIODUCT
                                       MILLION  AVG.
                                        WITS  PEOD.
                                       DISTBI    UT.
                                        BUTED  (LB)
   NATIONAL           GEOGB.
 CONSUMPTION   POP.    MULTI-
(HILLION LB)  APPORT.  PLIEB   LOU  HIGH
                                                                                            WEIGHT  FRACTION
                                                                                              VOC       PROC
                               TOTAL VOC EMISSIONS  TOTAL PROC EMISSIONS
                                      (TONS)               (TONS)
                   LOU  HIGH
 LOU
HIGH
 LOU
HIGH
vO
     UALL CLEANERS

     UAXES AND POLISHES (LIQUIDS)
       FORMULATIONS 2,3
     FLOOR UAXES OR POLISHES
       FORMULATIONS 1,2,3 (2)
     RUG DEODORIZERS AND FRESHENERS
     LAUNDRY SPOT REMOVERS
     MOTH CONTROL PRODUCTS
     METAL CLEANERS AND POLISHES
       FORMULATIONS 2,3,4,5,7 (2)
     HOUSEHOLD ADHESIVES
     FURNITURE POLISHES AND UAXES
SUB-TOTAL
                                                                    3.00

                                                                   27.00
                 .05

                 .05
1.00   .24   .94   .24    .94
                                                                                                                         NA
16.56
                                                                        NA
 64.66
                                                         NA
16.56
1.02   .20   .20   .20    .20    126.68
                                                                   24.00     .05     1.00  0.00  1.00 0.00    1.00
      AUTOMOTIVE
           AUTO ANTIFREEZES
             FORMULATIONS 1
           CAR POLISHES  AND UAXES
             FORMULATIONS 1,2
           WINDSHIELD UASHER FLUID
      SUB-TOTAL
                                        189.10   1.00
     GARAGE PRODUCTS
           HOUSEHOLD GLUE AND BONDING AGENTS
           HOUSEHOLD CAULKS AND SEALANTS
           INSECTICIDES
           HERBICIDES
           FUNGICIDES
           BARBECUE LIGHTER FLUIDS
           AUTO WINDSHIELD VASHERS
                                  NA
64.66
126.68
NA
NA
NA
0.00
NA
NA
143.24
126.68
NA
NA
NA
552.00
NA
NA
743.54
126.68
NA
NA
NA
0.00
NA
NA
143.24
126.68
NA
NA
NA
552.00
NA
NA
743.54
       22.30     .05     1.00    .95   .95   .95    .95    487.25     487.25    487.25     467.25

                 .05      .90    .42   .42   .42    .42   1655.78    1659.69   1655.78    1659.69
                                                             NA         NA       NA        NA
                                                        2143.03    2146.95   2143.03    2146.95
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA

-------
                                                                           Table 6 (Continued)
                                                                   VOC AND PEOC EMISSIONS IN NEU YOIK
                                       MILLION  AVG.                                    WEIGHT  FRACTION        TOTAL VOC EMISSIONS  TOTAL PROC EMISSIONS
                                        UNITS  PROD.      NATIONAL            GEOGR.     VOC       PROC               (TONS)               (TONS)
                                       DISTRI   UT.     CONSUMPTION   POP.   . MULTI-
PRODUCT                                 BUTEO  (LB)    (MILLION LB)  APPORT.  PLIER   LOU  HIGH    LOU  HIGH       LOU      HIGH        LOU      HIGH

     DEGREASERS                                                                                                      NA         NA        NA        NA
SUB-TOTAL                                                                                                          0.00       0.00      0.00      0.00
TOTAL EMISSIONS                                                                                                15238.40  10(046.74  14099.44 100673.63
(1) Products In these sub-categories are aerosol unless It is indicated that aerosol and non-aerosol are combined.
(2) More than tuo listed formulations indicates that several product foriulations had the saie low or high weight percent.
(3) Suntan lotion use varies strongly with season.  However, the total euission estimate is independent of seasonal fluctuation.
(4) NA indicates that emissions could not be calculated because either product use or formulation data were not available.
(5) Includes industrial, commercial, and consumer products.

-------
F/834-025-68a/#8

                                6.  CONCLUSIONS

     Tables 7, 8, and 9 summarize PROC and VOC emission estimates for consumer
products.  The consumer product subcategories are arranged in descending order
according to the high PROC emission estimate, the low PROC emission estimate,
and an average of the two estimates. Only those product categories for which
all data are available are listed.

     If the low PROC emissions estimates (Table 7) are assumed to be more
realistic, the categories with  the largest emissions are:

     •  Paints, primers, and varnishes
     •  Hair sprays
     •  Car polishes and waxes
     •  Room deodorants and disinfectants
     •  Moth control products.

     If the high PROC emissions estimates (Table 8) are assumed to most
closely reflect the actual emissions, the categories of greatest emissions
are:

     •  Adhesives
     •  Paints, primers, and varnishes
     •  All purpose cleaners
     •  Insect sprays
     •  Hair sprays
     •  Room deodorants and disinfectants.

     If the average of the high and the low emissions estimates (Table 9) is
assumed to be  the most realistic, the product categories with the largest
emissions are:
     •  Adhesives
     •  Paints, primers, and varnishes
     •  Hair sprays
     •  All purpose cleaners
                                      6-1

-------
F/834-025-68a/#8

     •  Insect sprays
     •  Car polishes and waxes
     •  Room deodorants and disinfectants.

     These seven subcategories account for approximately 85 percent of  the
average PROC releases even though they represent less than 20 percent of  the
product subcategories.  Adhesives alone account for over 56 percent of  total
PROC emissions.

     Use data for adhesives and caulking and sealing compounds included
industrial as well as consumer use.  If consumers use only 10 percent of  the
adhesives, the seven product categories still release approximately 70  percent
of the average PROC emissions.  Adhesives would continue to be a major  source
of PROC emissions.

     The range of possible total VOC and PROC emissions is quite large.
Annual California VOC emissions, for example, vary from a low of 38,800 tons
to a high of 245,000 tons.  The low/high VOC and PROC ratios reported in
Tables 10, 11, and 12, indicate a wide variation in emission estimation
precision.  This variation between the low and high VOC and PROC estimates is
accounted for by the uncertainties in the distribution, consumption, and
formulation data for many subcategories.  For household products in
California, the low VOC or PROC is estimated to be only 2 percent of the  high
VOC or PROC, whereas for personal products the low estimate is 86 percent of
the high estimate for VOC, and 76 percent for PROC.  The insect spray
category, with low/high VOC and PROC ratios of 0.22 and 0.18, respectively, is
the other product category with a wide emissions estimate range.  Taking  into
consideration all products, the low/high VOC estimate is 0.16, while the
similar PROC ratio is 0.15.

     In general, the amount of PROC emitted is very similar to that of  VOC
emitted.  This is not unexpected, given the relatively few volatile organic
compounds not considered to be photoreactive.  The nonphotoreactive volatile
organic compounds that were found in the formulations were:  carbon dioxide
(propellent), methylene chloride, and 1,1,1-trichloroethane.  These compounds
appear not to be in widespread use in consumer products, explaining the
similarity in VOC and PROC emissions.
                                      6-2

-------
F/834-025-68a/#8

     Very little data were available for emissions of VOC and PROC from
nonaerosol products.  Data collected by SAIC in an earlier report on organic
compound emissions in California (Rogozen et al., 1985) have been examined  in
an attempt to decrease the uncertainty in this area.  Estimated emissions from
several nonaerosol products are reported in Table 13.  This remains an
incomplete list of nonaerosol products, but it sheds some light on the
approximate fraction of total VOC emissions that might be omitted from the
inventory.  The total VOC emitted from nonaerosol products was 19,504 tons/yr
(Rogozen et al., 1985).  This represents 8 percent of the high estimate of  VOC
emitted in California.  However, a more realistic assessment of the omitted
nonaerosol component, assuming VOC emissions are only an average of the
reported low and high figures, is 13 percent of total VOC emissions.  This
means that our emission inventory probably has omitted between 8 and 13
percent of actual VOC emitted by consumer products.  This estim'ate is likely
to be somewhat conservative, since not all omitted products have been taken
into account.

     Tables 14, 15, and 16 indicate per capita emissions of VOC and PROC by
product subcategory.  The average per capita PROC emissions vary from
approximately 9 to 11 Ib/person/year.  These results are somewhat larger than
the 6.3 Ib/person/year recommended for estimating PROC by the EPA (EPA, 1980).

     However, two factors suggest that these results are not directly
comparable with the EPA data.  The first is the large proportion of total
emissions contributed by adhesives (in household products).  It was not
possible to disaggregate industrial and consumer use of adhesives; therefore,
our total includes industrial as well as consumer use.  Based upon industry
estimates (Broxterman, 1983), we may assume that 95 percent of the use of
these products is industrial and 5 percent consumer.  Per capita average PROC
emissions are estimated to be:  California, 5.40 Ib; New Jersey, 4.38 Ib; and
New York, 5.02 Ib, after subtracting the industrial proportion of adhesives
and adjusting the average per capita emissions.

     The second adjustment factor stems from the lack of data for many
nonaerosol subcategories.  Using the SAIC derived emission data (Rogozen et
al., 1985), reported in Table 13, as a partial adjustment for this omission,
                                      6-3

-------
F/834-025-68a/#8

we now find the per capita annual emissions for these three regions  to  be:
California, 6.97 Ib/person; New Jersey, 5.95 Ib/person; and New York, 6.59
Ib/person.  Thus, our final estimates are very close to the earlier  EPA
estimate.  These estimates are likely to be somewhat conservative since only
some of the unavailable emissions data have been replaced by  the SAIC study
data.

Future Efforts
     The results of this study indicate that the EPA estimate of PROC
emissions of 6.3 Ib/person/year is likely to be fairly accurate.  Nonetheless,
these results were derived from data with considerable uncertainty.  Each
stage of the data collection process presented accuracy and validity problems,
including defining "typical" products for a subcategory, disaggregating
aerosol and nonaerosol for industrial and consumer products, assessing
distribution or consumption by subcategory, knowing percent VOC or PROC within
any product, and finding the relative distribution of each of the products for
any subcategory.  Thus, for some categories, the range of emissions  from low
to high VOC or PROC is quite large.

     Given these problems, it would be difficult to use the results  as  the
basis for calculating actual reductions in emissions of reactive hydrocarbons
as a result of regulation.  However, these results may fruitfully be used as
the basis for targeting further research, and as the basis for focusing on
specific industries with a potential for substantial emission reductions.  For
example, industrial users of adhesives would be a logical category to focus
upon.

     Future research efforts would probably be better spent in focusing on
those areas which have the greatest potential for emission reduction, such as
adhesives, paints, hair sprays and cleaners.  More detailed knowledge in these
subcategories about the specific amounts, types, and distribution patterns of
PROC emissions is likely to produce the greatest results.

     There are two potentially rewarding research paths to pursue to gain
additional detailed information.  Both require substantial expenditures of
                                      6-4

-------
F/834-025-68a/#8

time and money.  The first is to purchase marketing data from the large
marketing research firms such as Simmons or Kline, with their detailed
formulation and distribution data sets.  The second is to track down
individual industries, either through a survey or through telephone calls and
personal visits with knowledgeable industry officials.  It is likely that
individual companies have the required data but will not release them without
the proper authority, since they consider such information proprietary.
                                      6-5

-------
                           TABLE 7. CONSUMER PRODUCT SUB-CATEGORIES RANKED IN ORDER
                                    OF LOW TOTAL PROC EMISSIONS
 STATE OF CALIFORNIA
VOC & PROC EMISSIONS
                           AEROSOL/   TOTAL VOC EMISSIONS (tons)
CONSUMER PRODUCT SUB -CATEGORY
PAINTS, PRIMERS, VARNISHES
HAIR SPRAYS
CAR POLISHES & WAXES
ROOM DEODORANTS & DISINFECTANTS
MOTH CONTROL PRODUCTS
PERSONAL DEODORANTS
AUTO ANTIFREEZES
BREAK CLEANERS
ENGINE STARTING FLUIDS
ENGINE DEGREASERS
ALL PURPOSE CLEANERS
STYLING MOUSE
CARBURETOR & CHOKE CLEANERS
PHARMACEUTICALS
WINDSHIELD DEICER
FLOOR WAXES OR POLISHES
COLOGNES
INSECT REPELLENTS
STARCH & FABRIC FINISH
RUG & UPHOLSTERY CLEANERS
WAXES & POLISHES
AFTERSHAVES
ANIMAL INSECTICIDES
PAINTS-OTHER RELATED PRODUCTS
SHAVING LATHERS
PERFUMES
SPOT REMOVERS
UNDERCOAT INGS
CARPET DEODORIZERS
SHOE POLISHES, WAXES & COLORANTS
WAXES & POLISHES LIQUIDS
DEPILATORIES
ADHESIVES
INSECT SPRAYS
CAULKING & SEALING COMPOUNDS
WINDOW & GLASS CLEANERS
HERBICIDES, FUNGICIDES
LUBRICANTS AND SI LI CONES
METAL CLEANERS & POLISHES
TILE & BATHROOM CLEANERS
AUTO CLEANERS
OVEN CLEANERS
HAIR CARE PRODUCTS - SHAMPOOS
SUNTAN LOTIONS
ANT I -STATIC SPRAYS
PREWASH STAIN REMOVERS
DRAIN OPENERS
TOTALS

nun-MCK.
(A/N)
A
A
N
A
A/N
A
N
A
A
A
A
A
A
A
A/N
N
A
A/N
A
A
A
A
A
A
A
A
A/N
A
A/N
A/N
N
A
A
A/N
A/N
A/N
A/N
A
N
A
A/N
A/N
A/N
A
A
A/N
A/N


LOW
10,424
7,685
4,619
2,436
2,059
1,476
1,165
1,032
949
1,026
603
543
460
454
429
309
303
230
222
215
212
205
182
170
140
135
127
86
69
43
40
11
0
529
0
0
0
0
0
0
0
0
0
0
0
0
0
38,587

HIGH
12,392
8,505
4,630
6,363
2,136
1,752
1,165
1,032
949
1,150
12,324
543
1,642
646
572
309
303
561
508
1,645
1,030
205
329
170
402
135
127
291
69
323
155
12
153,223
10,588
4,761
3,939
3,605
1,825
1,320
1,180
707
370
177
81
5
0
0
244,656
6-6
AVERAGE
11,408
8,095
4,625
4,650
2,098
1,614
1,165
1,032
949
1,088
6,463
543
1,051
550
501
309
303
396
365
930
621
205
255
170
271
135
127
188
69
183
97
11
76,612
5,558
2,380
1,970
1,803
913
660
590
354
185
89
41
3
0
0
141,622

TOTAL PROC EMISSIONS (tons)
LOW
9,554
6,377
4,619
2,436
2,059
1,476
1J65
1,032
949
863
603
543
460
454
429
309
303
230
222
215
212
205
182
170
140
135
114
86
69
43
40
11
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
HIGH
12,392
8,505
4,630
5,971
2,136
1,752
1,165
1,032
949
1,150
12,324
543
1,642
646
572
309
303
561
508
1,645
1,030
205
329
170
402
135
127
291
69
323
155
12
153,223
10,588
4,761
3,939
3,605
1,825
1,320
1,180
707
370
177
81
5
0
0
AVERAGE
10,973
7,441
4,625
4,204
2,098
1,614
1,165
1,032
949
1,006
6,463
543
1,051
550
501
309
303
396
365
930
621
205
255
170
271
135
120
188
69
183
97
11
76,612
5,294
2,380
1,970
1,803
913
660
590
354
185
89
41
3
0
0
                                                                         35,703     243,764     139,734

-------
                           TABLE 7. CONSUMER PRODUCT SUB-CATEGORIES RANKED  IN  ORDER
                                    OF LOW TOTAL PROC EMISSIONS (continued)
      NEW YORK
VOC & PROC EMISSIONS
                           AEROSOL/   TOTAL VOC EMISSIONS  (tons)
CONSUMER PRODUCT SUB -CATEGORY
PAINTS, PRIMERS, VARNISHES
HAIR SPRAYS
CAR POLISHES & WAXES
ROOM DEODORANTS & DISINFECTANTS
MOTH CONTROL PRODUCTS
PERSONAL DEODORANTS
AUTO ANTIFREEZES
BRAKE CLEANERS
ENGINE STARTING FLUIDS
ENGINE DEGREASERS
ALL PURPOSE CLEANERS
STYLING MOUSE
CARBURETOR & CHOKE CLEANERS
WINDSHIELD DEICER
PHARMACEUTICALS
FLOOR WAXES OR POLISHES
COLOGNES
INSECT REPELLENTS
WAXES & POLISHES
STARCH & FABRIC -FINISH
RUG & UPHOLSTERY CLEANERS
AFTERSHAVES
ANIMAL INSECTICIDES
PAINTS-OTHER RELATED PRODUCTS
SHAVING LATHERS
PERFUMES
SPOT REMOVERS
UNDERCOAT INGS
CARPET DEODORIZERS
SHOE POLISHES, WAXES & COLORANTS
WAXES & POLISHES LIQUIDS
DEPILATORIES
ADHESIVES
INSECT SPRAYS
CAULKING & SEALING COMPOUNDS
WINDOW & GLASS CLEANERS
HERBICIDES AND FUNGICIDES
LUBRICANTS AND SILICONES
METAL CLEANERS & POLISHES
TILE & BATHROOM CLEANERS
AUTO CLEANERS
OVEN CLEANERS
HAIR CARE PRODUCTS - SHAMPOOS
SUNTAN LOTIONS
ANTI -STATIC SPRAYS
PREVASH STAIN REMOVERS
DRAIN OPENERS
nun-HCK.
(A/N)
A
A
N
A
A/N
A
N
A
A
A
A '
A
A
a/n
A
N
A
A/N
A
A
A
A
A
A
A
A
A/N
A
A/N
A/N
N
A
A
A/N
A/N
A/N
A/N
A
N
A
A/N
A/N
A/N
A
A
A/N
A/N
LOW
3,980
3,006
1,656
1,019
861
639
487
431
397
429
236
227
192
179
172
127
127
96
93
93
90
86
76
71
62
57
53
36
29
18
17
5
0
221
0
0
0
0
0
0
0
0
0
0
0
0
0
HIGH
4,731
3,327
1,660
2,870
893
758
487
431
397
481
4,816
227
687
239
245
127
127
235
454
212
688
86
138
71
178
57
53
122
29
135
65
5
64,075
4,428
1,991
1,681
1,508
763
552
493
296
152
74
31
2
0
0
AVERAGE
4,356
3,167
1,658
1,944
877
699
487
431
397
455
2,526
227
439
209
209
127
127
165
273
153
389
86
107
71
120
57
53
79
29
77
41
5
32.038
2,324
995
840
754
382
276
247
148
76
37
16
1
0
0
                                 TOTAL PROC EMISSIONS (tons)
LOW
3,648
2,495
1,656
1,019
861
639
487
431
397
361
236
227
192
179
172
127
127
96
93
93
90
86
76
71
62
57
48
36
29
18
17
5
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
HIGH
4,731
3,327
1,660
2,497
893
758
487
431
397
481
4,816
227
687
239
245
127
127
235
454
212
688
86
138
71
178
57
53
122
29
135
65
5
64,075
4,428
1,991
1,681
1,508
763
552
493
296
152
74
31
2
0
0
AVERAGE
4,190
2,911
1,658
1,758
877
699
487
431
397
421
2,526
227
439
209
209
127
127
165
273
153
389
86
107
71
120
57
50
79
29
77
41
5
32,038
2,214
995
840
754
382
276
247
148
76
37
16
1
0
0
                    TOTALS
15,267
101,075

6-7
58,171
14,128    100,702     57,415

-------
                           TABLE 7. CONSUMER PRODUCT SUB-CATEGORIES RANKED IN ORDER
                                    OF LOW TOTAL PROC EMISSIONS (continued)
 STATE OF NEW JERSEY
VOC & PROC EMISSIONS
                           AEROSOL/   TOTAL VOC EMISSIONS (tons)
CONSUMER PRODUCT SUB- CATEGORY
PAINTS, PRIMERS, VARNISHES
HAIR SPRAYS
CAR POLISHES & WAXES
ROOM DEODORANTS & DISINFECTANTS
MOTH CONTROL PRODUCTS
PERSONAL DEODORANTS
AUTO ANTIFREEZES
BRAKE CLEANERS
ENGINE STARTING FLUIDS
ENGINE DEGREASERS
ALL PURPOSE CLEANERS
STYLING MOUSE
CARBURETOR & CHOKE CLEANERS
WINDSHIELD DEICER
PHARMACEUTICALS
FLOOR WAXES OR POLISHES
COLOGNES
INSECT REPELLENTS
WAXES & POLISHES
STARCH & FABRIC FINISH
RUG & UPHOLSTERY CLEANERS
AFTERSHAVES
ANIMAL INSECTICIDES
PAINTS-OTHER RELATED PRODUCTS
SHAVING LATHERS
PERFUMES
SPOT REMOVERS
UNDERCOAT INGS
CARPET DEODORIZERS
SHOE POLISHES, WAXES & COLORANTS
WAXES & POLISHES LIQUIDS
DEPILATORIES
AOHESIVES
INSECT SPRAYS
CAULKING & SEALING COMPOUNDS
WINDOW & GLASS CLEANERS
HERBICIDES AND FUNGICIDES
LUBRICANTS AND SILICONES
METAL CLEANERS & POLISHES
TILE & BATHROOM CLEANERS
AUTO CLEANERS
OVEN CLEANERS
HIAR CARE PRODUCT - SHAMPOOS
SUNTAN LOTIONS
ANT I -STATIC SPRAYS
PREWASH STAIN REMOVERS
DRAIN OPENERS
TOTALS

(A/N)
A
A
N
A
A/N
A
N
A
A
A
A
A
A
A/N
A
N
A
A/N
A
A
A
A
A
A
A
A
A/N
A
A/N
A/N
N
A
A
A/N
A/N
A/N
.A/N
A
N
A
A/N
A/N
A/N
A
A
A/N
A/N


LOW
2,682
2,026
1,116
687
580
430
328
291
267
289
159
153
130
121
116
85
85
65
63
63
61
58
51
48
42
38
36
24
19
12
11
3
0
149
0
0
0
0
0
0
0
0
0
0
0
0
0
10,288

HIGH
3,189
2,242
1,118
1,934
602
511
328
291
267
324
3,246
153
463
161
165
85
85
158
306
143
463
58
93
48
120
38
36
82
19
91
44
3
43,181
2,984
1,342
1,133
1,016
514
372
332
199
102
50
21
1
0
0
68,114
6-8
AVERAGE
2,935
2,134
1,117
1,310
591
471
328
291
267
307
1,702
153
296
141
141
85
85
112
184
103
262
58
72
48
81
38
36
53
19
52
27
3
21,591
1,566
671
566
508
257
186
166
100
51
25
10
1
0
0
39,201

TOTAL PROC EMISSIONS (tons)
LOW
2,458
1,681
1,116
687
580
430
328
291
267
243
159
153
130
121
116
85
85
65
63
63
61
58
51
48
42
38
32
24
19
12
11
3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
HIGH
3,189
2,242
1,118
1,683
602
511
328
291
267
324
3,246
153
463
161
165
85
85
158
306
143
463
58
93
48
120
38
36
82
19
91
44
3
43,181
2,984
1,342
1,133
1,016
514
372
332
199
102
50
21
1
0
0
AVERAGE
2,823
1,962
1,117
1,185
591
471
328
291
267
284
1,702
153
296
141
141
85
85
112
184
103
262
58
72
48
81
38
34
53
19
52
27
3
21,591
1,492
671
566
508
257
186
166
100
51
25
10
1
0
0
                                                                           9,521      67,863
                       38,692

-------
                           TABLE 8. CONSUMER PRODUCT SUB-CATEGORIES RANKED IN ORDER
                                    OF HIGH TOTAL PROC EMISSIONS
 STATE OF CALIFORNIA
VOC & PROC EMISSIONS
                           AEROSOL/   TOTAL VOC EMISSIONS (tons)
CONSUMER PRODUCT SUB- CATEGORY
ADHESIVES
PAINTS, PRIMERS, VARNISHES
ALL PURPOSE CLEANERS
INSECT SPRAYS
HAIR SPRAYS
ROOM DEODORANTS & DISINFECTANTS
CAULKING & SEALING COMPOUNDS
CAR POLISHES & WAXES
WINDOW & GLASS CLEANERS
HERBICIDES, FUNGICIDES
MOTH CONTROL PRODUCTS
LUBRICANTS AND SI LI CONES
PERSONAL DEODORANTS
RUG & UPHOLSTERY CLEANERS
CARBURETOR & CHOKE CLEANERS
METAL CLEANERS & POLISHES
TILE & BATHROOM CLEANERS
AUTO ANTIFREEZES
ENGINE DEGREASERS
BREAK CLEANERS
WAXES & POLISHES
ENGINE STARTING FLUIDS
AUTO CLEANERS
PHARMACEUTICALS
WINDSHIELD DEICER
INSECT REPELLENTS
STYLING MOUSE
STARCH & FABRIC FINISH
SHAVING LATHERS
OVEN CLEANERS
ANIMAL INSECTICIDES
SHOE POLISHES, WAXES & COLORANTS
FLOOR WAXES OR POLISHES
COLOGNES
UNDERCOAT INGS
AFTERSHAVES
HAIR CARE PRODUCTS - SHAMPOOS
PAINTS-OTHER RELATED PRODUCTS
WAXES & POLISHES LIQUIDS
PERFUMES
SPOT REMOVERS
SUNTAN LOTIONS
CARPET DEODORIZERS
DEPILATORIES
ANT I -STATIC SPRAYS
PREWASH STAIN REMOVERS
DRAIN OPENERS
TOTALS

HUN-MCK.
(A/N)
A
A
A
A/N
A
A
A/N
N
A/N
A/N
A/N
A
A
A
A
N
A
N
A
A
A
A
A/N
A
A/N
A/N
A
A
A
A/N
A
A/N
N
A
A
A
A/N
A
N
A
A/N
A
A/N
A
A
A/N
A/N


LOW
0
10,424
603
529
7,685
2,436
0
4,619
0
0
2,059
0
1,476
215
460
0
0
1,165
1,026
1,032
212
949
0
454
429
230
543
222
140
0
182
43
309
303
86
205
0
170
40
135
127
0
69
11
0
0
0
38,587

HIGH
153,223
12,392
12,324
10,588
8,505
6,863
4,761
4,630
3,939
3,605
2', 136
1,825
1,752
1,645
1,642
1,320
1,180
1,165
1,150
1,032
1,030
949
707
646
572
561
543
508
402
370
329
323
309
303
291
205
177
170
155
135
127
81
69
12
5
0
0
244,656
6-9
AVERAGE
76,612
11,408
6,463
5,558
8,095
4,650
2,380
4,625
1,970
1,803
2,098
913
1,614
930
1,051
660
590
1,165
1,088
1,032
621
949
354
550
501
396
543
365
271
185
255
183
309
303
188
205
89
170
97
135
127
41
69
11
3
0
0
141,622

TOTAL PROC EMISSIONS (tons)
LOW
0
9,554
603
0
6,377
2,436
0
4,619
0
0
2,059
0
1,476
215
460
0
0
1,165
863
1,032
212
949
0
454
429
230
543
222
140
0
182
43
309
303
86
205
0
170
40
135
114
0
69
11
0
0
0
HIGH
153,223
12,392
12,324
10,588
8,505
5,971
4,761
4,630
3,939
3,605
2,136
1,825
1,752
1,645
1,642
1,320
1,180
1,165
1,150
1,032
1,030
949
707
646
572
561
543
508
402
370
329
323
309
303
291
205
177
170
155
135
127
81
69
12
5
0
0
AVERAGE
76,612
10,973
6,463
5,294
7,441
4,204
2,380
4,625
1,970
1,803
2,098
913
1,614
930
1,051
660
590
1,165
1,006
1,032
621
949
354
550
501
396
543
365
271
185
255
183
309
303
188
205
89
170
97
135
120
41
69
11
3
0
0
                                                                          35,703     243,764    139,734

-------
                           TABLE 8. CONSUMER PRODUCT SUB-CATEGORIES RANKED IN ORDER
                                    OF HIGH TOTAL PROC EMISSIONS (continued)
  STATE OF NEW YORK
VOC & PROC EMISSIONS
                           AEROSOL/   TOTAL VOC EMISSIONS (tons)
1
CONSUMER PRODUCT SUB -CATEGORY
ADHESIVES
ALL PURPOSE CLEANERS
PAINTS, PRIMERS, VARNISHES
INSECT SPRAYS
HAIR SPRAYS
ROOM DEODORANTS & DISINFECTANTS
CAULKING & SEALING COMPOUNDS
WINDOW & GLASS CLEANERS
CAR POLISHES & WAXES
HERBICIDES AND FUNGICIDES
MOTH CONTROL PRODUCTS
LUBRICANTS AND SILICONES
PERSONAL DEODORANTS
RUG & UPHOLSTERY CLEANERS
CARBURETOR & CHOKE CLEANERS
METAL CLEANERS & POLISHES
TILE & BATHROOM CLEANERS
AUTO ANTIFREEZES
ENGINE DEGREASERS
WAXES & POLISHES
BRAKE CLEANERS
ENGINE STARTING FLUIDS
AUTO CLEANERS
PHARMACEUTICALS
WINDSHIELD DEICER
INSECT REPELLENTS
STYLING MOUSE
STARCH & FABRIC FINISH
SHAVING LATHERS
OVEN CLEANERS
ANIMAL INSECTICIDES
SHOE POLISHES, WAXES & COLORANTS
FLOOR WAXES OR POLISHES
COLOGNES
UNDERCOATINGS
AFTERSHAVES
HAIR CARE PRODUCTS - SHAMPOOS
PAINTS-OTHER RELATED PRODUCTS
WAXES & POLISHES LIQUIDS
PERFUMES
SPOT REMOVERS
SUNTAN LOTIONS
CARPET DEODORIZERS
DEPILATORIES
ANT I -STATIC SPRAYS
PREUASH STAIN REMOVERS
DRAIN OPENERS
TOTALS

fflJN'ACK.
(A/N)
A
A '
A
A/N
A
A
A/N
A/N
N
A/N
A/N
A
A
A
A
N
A
N
A
A
A
A
A/N
A
a/n
A/N
A
A
A
A/N
A
A/N
N
A
A
A
A/N
A
N
A
A/N
A
A/N
A
A
A/N
A/N

'
LOW
0
236
3,980
221
3,006
1,019
0
0
1,656
0
861
0
639
90
192
0
0
487
429
93
431
397
0
172
179
96
227
93
62
0
76
18
127
127
36
86
0
71
17
57
53
0
29
5
0
0
0
15,267

HIGH
64,075
4,816
4,731
4,428
3,327
2,870
1,991
1,681
1,660
1,508
893
763
758
688
687
552
493
487
481
454
431
397
296
245
239
235
227
212
178
i 152
138
135
127
127
122
86
74
71
65
57
53
31
29
5
2
0
0
101,075
6-10
AVERAGE
32,038
2,526
4,356
2,324
3,167
1,944
995
840
1,658
754
877
382
699
389
439
276
247
487
455
273
431
397
148
209
209
165
227
153
120
76
107
77
127
127
79
86
37
71
41
57
53
16
29
5
1
0
0
58,171

TOTAL PROC EMISSIONS (tons)
LOW
0
236
3,648
0
2,495
1,019
0
0
1,656
0
861
0
639
90
192
0
0
487
361
•93
431
397
0
172
179
96
227
93
62
0
76
18
127
127
36
86
0
71
17
57
48
0
29
5
0
0
0
HIGH
64,075
4,816
4,731
4,428
3,327
2,497
1,991
1,681
1,660
1,508
893
763
758
688
687
552
493
487
481
454
431
397
296
245
239
235
227
212
178
152
138
135
127
127
122
86
74
71
65
57
53
31
29
5
2
0
0
AVERAGE
32,038
2,526
4,190
2,214
2,911
1,758
995
840
1,658
754
877
' 382
699
389
439
276
247
487
421
273
431
397
148
209
209
165
227
153
120
76
107
77
127
127
79
86
37
71
41
57
50
16
29
5
1
0
0
                                                                          14,128     100,702     57,415

-------
                           TABLE 8. CONSUMER PRODUCT SUB-CATEGORIES RANKED IN ORDER
                                    OF HIGH TOTAL PROC EMISSIONS (continued)
 STATE OF NEW JERSEY
VOC & PROC EMISSIONS
                           AEROSOL/   TOTAL VOC EMISSIONS (tons)
CONSUMER PRODUCT SUB -CATEGORY
ADHESIVES
ALL PURPOSE CLEANERS
PAINTS, PRIMERS, VARNISHES
INSECT SPRAYS
HAIR SPRAYS
ROOM DEODORANTS & DISINFECTANTS
CAULKING & SEALING COMPOUNDS
WINDOW & GLASS CLEANERS
CAR POLISHES & WAXES
HERBICIDES AND FUNGICIDES
MOTH CONTROL PRODUCTS
LUBRICANTS AND SILICONES
PERSONAL DEODORANTS
RUG & UPHOLSTERY CLEANERS
CARBURETOR & CHOICE CLEANERS
METAL CLEANERS & POLISHES
TILE & BATHROOM CLEANERS
AUTO ANTIFREEZES
ENGINE DEGREASERS
UAXES & POLISHES
BRAKE CLEANERS
ENGINE STARTING FLUIDS
AUTO CLEANERS
PHARMACEUTICALS
WINDSHIELD DEICER
INSECT REPELLENTS
STYLING MOUSE
STARCH & FABRIC FINISH
SHAVING LATHERS
OVEN CLEANERS
ANIMAL INSECTICIDES
SHOE POLISHES, WAXES & COLORANTS
FLOOR WAXES OR POLISHES
COLOGNES
UNDERCOAT INGS
AFTERSHAVES
HIAR CARE PRODUCT • SHAMPOOS
PAINTS-OTHER RELATED PRODUCTS
WAXES & POLISHES LIQUIDS
PERFUMES
SPOT REMOVERS
SUNTAN LOTIONS
CARPET DEODORIZERS
DEPILATORIES
ANTI- STATIC SPRAYS
PREWASH STAIN REMOVERS
DRAIN OPENERS
TOTALS

nun-ACK.
(A/N)
A
A
A
A/N
A
A
A/N
A/N
N
A/N
A/N
A
A
A
A
N
A-
N
A
A
A
A
A/N
A
A/N
A/N
A
A
A
A/N
A
A/N
N
A
A
A
A/N
A
N
A
A/N
A
A/N
A
A
A/N
A/N


LOW
0
159
2,682
149
2,026
687
0
0
1,116
0
580
0
430
61
130
0
0
328
289
63
291
267
0
116
121
65
153
63
42
0
51
12
85
85
24
58
0
48
11
38
36
0
19
3
0
0
0
10,288

HIGH
43,181
3,246
3,189
2,984
2,242
1,934
1,342
1,133
1,118
1,016
602
514
511
463
463
372
332
328
324
306
291
267
199
165
161
158
153
143
120
102
93
91
85
85
82
58
50
48
44
38
36
21
19
3
1
0
0
68,114
6-11
AVERAGE
21,591
1,702
2,935
1,566
2,134
1,310
671
566
1,117
508
591
257
471
262
296
186
166
328
307
184
291
267
100
141
141
112
153
103
81
51
72
52
85
85
53
58
25
48
27
38
36
10
19
3
1
0
0
39,201

TOTAL PROC EMISSIONS (tons)
LOW
0
159
2,458
0
1,681
687
0
0
1,116
0
580
0
430
61
130
0
0
328
243
63
291
267
0
116
121
65
153
63
42
0
51
12
85
85
24
58
0
48
11
38
32
0
19
3
0
0
0
HIGH
43,181
3,246
3,189
2,984
2,242
1,683
1,342
1,133
1,118
1,016
602
514
511
463
463
372
332
328
324
306
291
267
199
165
161
158
153
143
120
102
93
91
85
85
82
58
50
48
44
38
36
21
19
3
1
0
0
AVERAGE
21,591
1,702
2,823
1,492
1,962
1,185
671
566
1,117
508
591
257
471
262
296
186
166
328
284
184
291
267
100
141
141
112
153
103
81
51
72
52
85
85
53
58
25
48
27
38
34
10
19
3
1
0
0
                                                                          9,521
            67,863     38,692

-------
                           TABLE 9. CONSUMER PRODUCT SUB-CATEGORIES RANKED IN ORDER
                                    OF AVERAGE TOTAL PROC EMISSIONS
 STATE OF CALIFORNIA
VOC & PROC EMISSIONS
                           AEROSOL/   TOTAL VOC EMISSIONS (tons)
CONSUMER PRODUCT SUB -CATEGORY
ADHESIVES
PAINTS, PRIMERS, VARNISHES
HAIR SPRAYS
ALL PURPOSE CLEANERS
INSECT SPRAYS
CAR POLISHES & WAXES
ROOM DEODORANTS & DISINFECTANTS
CAULKING & SEALING COMPOUNDS
MOTH CONTROL PRODUCTS
WINDOW & GLASS CLEANERS
HERBICIDES, FUNGICIDES
PERSONAL DEODORANTS
AUTO ANTIFREEZES
CARBURETOR & CHOICE CLEANERS
BREAK CLEANERS
ENGINE DEGREASERS
ENGINE STARTING FLUIDS
RUG & UPHOLSTERY CLEANERS
LUBRICANTS AND SILICONES
METAL CLEANERS & POLISHES
WAXES & POLISHES
TILE & BATHROOM CLEANERS
PHARMACEUTICALS
STYLING MOUSE
WINDSHIELD DEICER
INSECT REPELLENTS
STARCH & FABRIC FINISH
AUTO CLEANERS
FLOOR WAXES OR POLISHES
COLOGNES
SHAVING LATHERS
ANIMAL INSECTICIDES
AFTERSHAVES
UNDERCOAT INGS
OVEN CLEANERS
SHOE POLISHES, WAXES & COLORANTS
PAINTS-OTHER RELATED PRODUCTS
PERFUMES
SPOT REMOVERS
WAXES & POLISHES LIQUIDS
HAIR CARE PRODUCTS - SHAMPOOS
CARPET DEODORIZERS
SUNTAN LOTIONS
DEPILATORIES
ANTI- STATIC SPRAYS
PREWASH STAIN REMOVERS
DRAIN OPENERS
TOTALS

NUN-ACK.
(A/N)
A
A
A
A
A/N
N
A
A/N
A/N
A/N
A/N
A
N
A
A
A
A
A
A
N
A
A
A
A
A/N
A/N
A
A/N
N
A
A
A
A
A
A/N
A/N
A
A
A/N
N
A/N
A/N
A
A
A
A/N
A/N


LOW
0
10,424
7,685
603
529
4,619
2,436
0
2,059
0
0
1,476
1,165
460
1,032
1,026
949
215
0
0
212
0
454
543
429
230
222
0
309
303
140
182
205
86
0
43
170
135
127
40
0
69
0
11
0
0
0
38,587

HIGH
153,223
12,392
8,505
12,324
10,588
4,630
6,863
4,761
2,136
3,939
3,605
1,752
1,165
1,642
1,032
1,150
949
1,645
1,825
1,320
1,030
1,180
646
543
572
561
508
707
309
303
402
329
205
291
370
323
170
135
127
155
177
69
81
12
5
0
0
244,656
6-12
AVERAGE
76,612
11,408
8,095
6,463
5,558
4,625
4,650
2,380
2,098
,970
,803
,614
,165
,051
,032
,088
949
930
913
660
621
590
550
543
501
396
365
354
309
303
271
255
205
188
185
183
170
135
127
97
89
69
41
11
3
0
0
141,622

TOTAL PROC EMISSIONS (tons)
LOW
0
9,554
6,377
603
0
4,619
2,436
0
2,059
0
0
1,476
1,165
460
1,032
863
949
215
0
0
212
0
454
543
429
230
222
0
309
303
140
182
205
86
0
43
170
135
114
40
0
69
0
11
0
0
0
HIGH
153,223
12,392
8,505
12,324
10,588
4,630
5,971
4,761
2,136
3,939
3,605
1,752
1,165
1,642
1,032
1,150
949
1,645
1,825
1,320
1,030
1,180
646
543
572
561
508
707
309
303
402
329
205
291
370
323
170
135
127
155
177
69
81
12
5
0
0
AVERAGE
76,612
10,973
7,441
6,463
5,294
4,625
4,204
2,380
2,098
1,970
1,803
1,614
1,165
1,051
1,032
1,006
949
930
913
660
621
590
550
543
501
396
365
354
309
303
271
255
205
188
185
183
170
135
120
97
89
69
41
11
3
0
0
                                                                         35,703    243,764     139,734

-------
                           TABLE 9. CONSUMER PRODUCT SUB-CATEGORIES RANKED IN ORDER
                                    OF AVERAGE TOTAL PROC EMISSIONS (continued)
  STATE OF NEW YORK
VOC & PROC EMISSIONS
                           AEROSOL/   TOTAL VOC EMISSIONS (tons)
CONSUMER PRODUCT SUB-CATEGORY
ADHESIVES
PAINTS, PRIMERS, VARNISHES
HAIR SPRAYS
ALL PURPOSE CLEANERS
INSECT SPRAYS
ROOM DEODORANTS & DISINFECTANTS
CAR POLISHES & WAXES
CAULKING & SEALING COMPOUNDS
MOTH CONTROL PRODUCTS
WINDOW & GLASS CLEANERS
HERBICIDES AND FUNGICIDES
PERSONAL DEODORANTS
AUTO ANTIFREEZES
CARBURETOR & CHOKE CLEANERS
BRAKE CLEANERS
ENGINE DEGREASERS
ENGINE STARTING FLUIDS
RUG & UPHOLSTERY CLEANERS
LUBRICANTS AND SI LI CONES
METAL CLEANERS & POLISHES
WAXES & POLISHES
TILE & BATHROOM CLEANERS
STYLING MOUSE
WINDSHIELD DEICER
PHARMACEUTICALS
INSECT REPELLENTS
STARCH & FABRIC FINISH
AUTO CLEANERS
FLOOR WAXES OR POLISHES
COLOGNES
SHAVING LATHERS
ANIMAL INSECTICIDES
AFTERSHAVES
UNDERCOAT INGS
SHOE POLISHES, WAXES & COLORANTS
OVEN CLEANERS
PAINTS-OTHER RELATED PRODUCTS
PERFUMES
SPOT REMOVERS
WAXES & POLISHES LIQUIDS
HAIR CARE PRODUCTS - SHAMPOOS
CARPET DEODORIZERS
SUNTAN LOTIONS
DEPILATORIES
ANTI -STATIC SPRAYS
PREWASH STAIN REMOVERS
DRAIN OPENERS
TOTALS

NUN-HGK.
(A/N)
A
A
A
A
A/N
A
N
A/N
A/N
A/N
A/N
A
N
A
A
A
A
A
A
N
A
A
A
a/n
A
A/N
A
A/N
N
A
A
A
A
A
A/N
A/N
A
A
A/N
N
A/N
A/N
A
A
A
A/N
A/N


LOW
0
3,980
3,006
236
221
1,019
1,656
0
861
0
0
639
487
192
431
429
397
90
0
0
93
0
227
179
172
96
93
0
127
127
62
76
86
36
18
0
71
57
53
17
0
29
0
5
0
0
0
15,267

HIGH
64,075
4,731
3,327
4,816
4,428
2,870
1,660
1,991
893
1,681
1,508
758
487
687
431
481
397
688
763
552
454
493
227
239
245
235
212
296
127
127
178
138
86
122
135
152
71
57
53
65
74
29
31
5
2
0
0
101,075
6-13
AVERAGE
32,038
4,356
3,167
2,526
2,324
1,944
1,658
995
877
840
754
699
487
439
431
455
397
389
382
276
273
247
227
209
209
165
153
148
127
127
120
107
86
79
77
76
71
57
53
41
37
29
16
5
1
0
0
58,171

TOTAL PROC EMISSIONS (tons)
LOW
0
3,648
2,495
236
0
1,019
1,656
0
861
0
0
639
487
192
431
361
397
90
0
0
93
0
227
179
172
96
93
0
127
127
62
76
86
36
18
0
71
57
48
17
0
29
0
5
0
0
0
HIGH
64,075
4,731
3,327
4,816
4,428
2,497
1,660
1,991
893
1,681
1,508
758
487
687
431
• 481
397
688
763
552
454
493
227
239
245
235
212
296
127
127
178
138
86
122
135
152
71
57
53
65
74
29
31
5
2
0
0
AVERAGE
32,038
4,190
2,911
2,526
2,214
1,758
1,658
995
877
840
754
699
487
439
431
421
397
389
382
276
273
247
227
209
209
165
153
148
127
127
120
107
86
79
77
76
71
57
50
41
37
29
16
5
1
0
0
                                                                          14,128    100,702      57,415

-------
                           TABLE 9. CONSUMER PRODUCT SUB-CATEGORIES RANKED IN ORDER
                                    OF AVERAGE TOTAL PROC EMISSIONS (continued)
 STATE OF NEW JERSEY
VOC & PROC EMISSIONS
                           AEROSOL/   TOTAL VOC EMISSIONS (tons)
CONSUMER PRODUCT SUB -CATEGORY
ADHESIVES
PAINTS, PRIMERS, VARNISHES
HAIR SPRAYS
ALL PURPOSE CLEANERS
INSECT SPRAYS
ROOM DEODORANTS & DISINFECTANTS
CAR POLISHES & WAXES
CAULKING & SEALING COMPOUNDS
MOTH CONTROL PRODUCTS
WINDOW & GLASS CLEANERS
HERBICIDES AND FUNGICIDES
PERSONAL DEODORANTS
AUTO ANTIFREEZES
CARBURETOR & CHOKE CLEANERS
BRAKE CLEANERS
ENGINE DEGREASERS
ENGINE STARTING FLUIDS
RUG & UPHOLSTERY CLEANERS
LUBRICANTS AND SILICONES
METAL CLEANERS & POLISHES
WAXES & POLISHES
TILE & BATHROOM CLEANERS
STYLING MOUSE
WINDSHIELD DEICER
PHARMACEUTICALS
INSECT REPELLENTS
STARCH & FABRIC FINISH
AUTO CLEANERS
FLOOR WAXES OR POLISHES
COLOGNES
SHAVING LATHERS
ANIMAL INSECTICIDES
AFTERSHAVES
UNDERCOAT INGS
SHOE POLISHES, WAXES & COLORANTS
OVEN CLEANERS
PAINTS-OTHER RELATED PRODUCTS
PERFUMES
SPOT REMOVERS
WAXES & POLISHES LIQUIDS
HIAR CARE PRODUCT - SHAMPOOS
CARPET DEODORIZERS
SUNTAN LOTIONS
DEPILATORIES
ANT I -STATIC SPRAYS
PREWASH STAIN REMOVERS
DRAIN OPENERS
TOTALS

(A/N)
A
A
A
A
A/N
A
N
A/N
A/N
A/N
A/N
A
N
A
A
A
A
A
A
N
A
A
A
A/N
A
A/N
A
A/N
N
A
A
A
A
A
A/N
A/N
A
A
A/N
N
A/N
A/N
A
A
A
A/N
A/N


LOW
0
2,682
2,026
159
149
687
1,116
0
580
0
0
430
323
130
291
289
267
61
0
0
63
0
153
121
116
65
63
0
85
85
42
51
58
24
12
0
48
38
36
11
0
19
0
3
0
0
0
10,288

HIGH
43,181
3,189
2,242
3,246
2,984
1,934
1,118
1,342
602
1,133
1,016
511
328
463
291
324
267
463
514
372
306
332
153
161
165
158
143
199
85
85
120
93
58
82
91
102
48
38
36
44
50
19
21
3
1
0
0
68,114
6-14
AVERAGE
21,591
2,935
2,134
1,702
1,566
1,310
1,117
671
591
566
508
471
328
296
291
307
267
262
257
186
184
166
153
141
141
112
103
100
85
85
81
72
58
53
52
51
48
38
36
27
25
19
10
3
1
0
0
39,201

TOTAL PROC EMISSIONS (tons)
LOW
0
2,458
1,681
159
0
687
1,116
0
580
0.
0
430
328
130
291
243
267
61
0
0
63
0
153
121
116
65
63
0
.85
85
42
51
58
24
12
0
48
38
32
11
0
19
0
3
0
0
0
HIGH
43,181
3,189
2,242
3,246
2,984
1,683
1,118
1,342
602
1,133
1,016
511
328
463
291
324
267
463
514
372
306
332
153
161
165
158
143
199
85
85
120
93
58
82
91
102
48
38
36
44
50
19
21
3
1
0
0
AVERAGE
21,591
2,823
1,962
1,702
1,492
1,185
1,117
671
591
566
508
471
328
296
291
284
267
262
257
186
184
166
153
141
141
112
103
100
85
85
81
72
58
53
52
51
48
38
34
27
25
19
10
3
1
0
0
                                                                           9,521      67,863
                       38,692

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D/834-025-68a/#19


     TABLE 10.  VOC AND PROC RATIOS  FOR PRODUCT  CATEGORIES  IN  CALIFORNIA
                           VOC (Low)/   PROC (Low)/   PROC (Low)/  PROC (High)/
Product Categories         VOC (High)   PROC (High)    VOC (Low)    VOC (High)
Aerosol Spray Products
Insect Sprays
Paints and Finishes
Household Products
Personal Products
Animal Products
Automotive and
Industrial Products
Miscellaneous Products
Non-Aerosol Products
Personal Products
Household Products
Automotive Products

0.22
0.84
0.02
0.86
—
0.49

0.00


0.20
1.00

0.18
0.77
0.02
0.76
__
0.47

0.00


.20
1.00

0.82
0.92
1.00
0.88
—
0.96

—


1.00
1.00

1.00
1.00
1.00
1.00
—
1.00

1.00


1.00
1.00
  Garage Products

Total Emissions              0.16          0.15         0.92          1.00
                                      6-15

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C/834-025-68a/#20


      TABLE  11.   VOC AND PROC RATIOS FOR PRODUCT CATEGORIES IN NEW YORK
                           VOC (Low)/   PROC  (Low)/   PROC  (Low)/  PROC  (High)/
Product Categories         VOC (High)   PROC  (High)    VOC  (Low)    VOC  (High)


Aerosol Spray Products

  Insect Sprays              0.22          0.18         0.82           1.00
  Paints and Finishes        0.84          0.77         0.92           1.00
  Household Products         0.02          0.02         1.00           1.00
  Personal Products          0.86          0.76           .88           1.00
  Animal Products
  Automotive and             0.49          0.47         0.96           1.00
    Industrial Products
  Miscellaneous Products     0.00          0.00           —           1.00

Non-Aerosol Products

  Personal Products
  Household Products         0.19          0.19         1.00           1.00
  Automotive Products        1.00          1.00         1.00           1.00
  Garage Products

Total Emissions              0.15          0.14         0.93           1.00
                                     6-16

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C/834-025-68a/#21


     TABLE 12.  VOC AND PROC RATIOS FOR PRODUCT CATEGORIES IN NEW JERSEY
Product
Aerosol
Categories
Spray Products
VOC
VOC

(Low)/
(High)

PROC
PROC

(Low)/
(High)

PROC
VOC

(Low)/
(Low)

PROC
VOC

(High)/
(High)

  Insect Sprays              0.22          0.18         0.82          1.00
  Paints and Finishes        0.84          0.77         0.92          1.00
  Household Products         0.02          0.02         1.00          1.00
  Personal Products          0.86          0.76         0.86          1.00
  Animal Products
  Automotive and             0.48          0.47         0.96          1.00
    Industrial Products
  Miscellaneous Products

Non-Aerosol Products

  Personal Products
  Household Products         0.19          0.19,        1.00          1.00
  Automotive Products        1.00          1.00         1.00          1.00
  Garage Products

Total Emissions              0.15          0.14         0.93          1.00
                                      6-17

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D/834-025-68a/#14


                 TABLE 13.  ADDITIONAL VOC AND PROC EMISSIONS
                                  Emissions  (tons)
         Product                         CA              NJ1        NY1
Brake fluid for master cylinder
(ethylene glycol monethyl ethers
88,000 tons x 0.2 estimated
emission factor)
Gas driers (methanol)
Ball point and porous tip pens
(ethylene glycol)
Rubbing alcohol
Nail polish
Total



17,600
600

18
1,150
136
19,504



7,630
260

8
499
59
8,456



5,916
201

6
387
46
6,556
 Based upon per capita emissions  from California.

 Source:  Rogozen et al.,  (1985)
                                      6-18

-------
                               TABLE 14
             PER CAPITA AVERAGE VOC AND PROC EMISSIONS (LB/PERSQN)

Category
Aerosol:
Insect Sprays
Paints and Finishes
Household Products
Personal Products
Autoiotive and Indust.
Herbicides and Fungicides
Non-Aerosol:
Household
Autoiotive

CA

0.67
0.93
7.64
0.95
0.49
0.15

0.09
0.46
VOC
NJ

0.56
0.71
6.37
0.76
0.41
0.12

0.07
0.35

NY

0.64
0.82
7.33
0.88
0.47
0.14

0.08
0.40

CA

0.65
0.89
7.60
0.90
0.48
0.15

0.09
0.46
PROC
NJ

0.54
0.69
6.34
0.72
0.40
0.12

0.07
0.35

NY

0.62
0.79
7.3
0.83
0.46
0.14

0.08
0.40
Total Emissions                 11.38     9.40    10.80       11.23    9.28    10.66
                                        6-19

-------
                                      TABLE 15
                 PER CAPITA LOU VOC AND PSOC EMISSIONS (LB/PERSQN)
                                           VOC                          PROC
Category                           CA       NJ       NY          CA       NJ       NY

Aerosol:
   Insect Sprays                 0.24     0.20     0.23        0.20     0.17     0.19
   Paints and Finishes           0.85     0.65     0.75        0.78     0.60     0.69
   Household Products            0.32     0.26     0.30        0.32     0.26     0.30
   Personal Products             0.88     0.70     0.81        0.77     0.62     0.72
   Autoiotive and  Indust.        0.32     0.27     0.31        0.30     0.26     0.30
   Herbicides and Fungicides     0.00     0.00     0.00        0.00     0.00     0.00

Non-Aerosol:
   Household                     0.03     0.02     0.03        0.03     0.02     0.03
   Autoiotive                    0.46     0.34     0.40        0.46     0.34     0.40

Total Eiissions                  3.11     2.49     2.85        2.88     2.31     2.64
                                      TABLE  16
                 PER CAPITA HIGH VOC AND PROC EMISSIONS  (LB/PERSON)

Category
Aerosol:
Insect Sprays
Paints and Finishes
Household Products
Personal Products
Autoiotive and Indust.
Herbicides and Fungicides
Non-Aerosol:
Household
Autoiotive

CA

1.09
1.01
14.96
1.02
0.66
0.29

0.14
0.47
VOC
NJ

0.92
0.77
12.49
0.82
0.55
0.24

0.11
0.35

NY

1.05
0.89
14.39
0.95
0.63
0.26

0.14
0.40

CA

1.09
1.01
14.89
1.02
0.66
0.29

0.14
0.47
PROC
NJ

0.92
0.77
12.43
0.82
0.55
0.24

0.11
0.35

NY

1.05
0.89
14.30
0.95
0.63
0.28

0.14
0.40
Total Eiissions                  19.65     16.30    18.74        19.56    16.24    18.67
                                         6-20

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B/834-025-68a/#15
                                  APPENDIX A

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B/834-025-68b/#2


                    INSECTICIDES - AEROSOL AND NONAEROSOL
      National Consumption         Population              Geographic
        (million Ib)               Apportionment           Multiplier


          192.51                    .11 (CA)2                  NA

                                    .046 (NY)

                                    .031 (NJ)
       (1982)
2U.S. Bureau of the Census (1986)
                                      -1-

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B/834-025-68b/#2


                            INSECTICIDE FORMULATIONS
                                   Percent                  VOC        PROC
                                   By  Weight    Volatility   Emitted(%)  Emitted(%)
Formula 1                                                     86.5       86.5

Sevin                                  3.0            NV
Malathion                              4.0            NV
Folpet (fungicide)                     5.0            NV
Kelthane                               1.5            NV
Inert ingredients                     86.5             V

Formula 2                                                    100.0      100.0

DDVP        •                          18.6             V
Related compounds                      1.4             V
Inert ingredients                     80.0             V

Formula 3                                                     99.3       99.3
d-trans Allethrin
(5-Benzyl-3-furyl) methyl-2,
2-dimethyl-3 , 2-methylpropenyl
cyclopropane carboxylate
Related compounds
Petroleum distillate
Sodium nitrite
Inert ingredients
Butane/Isobutane propellant
Formula 4
Baygon
DDVP
Petroleum distillates
Inert ingredients
Butane/Isobutane
Formula 5
Pyrethrins
Piperonyl butoxide
Petroleum distillates
Inert ingredients
Butane/Isobutane
0.50


0.08
0.01
10.20
0.08
59.12
30.00*

1.00
0.20
1.04
67.91
30.00*

0.25
0.80
1.04
67.91
30.00*
NV


NV
NV
V
-
V
V
99.0 99.0
NV
V
V
V
V
99.0 99.0
NV
NV
V
V
V
 *Estimated  from WAIB  (1981)  and CSMA (1986)
                                      -2-

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B/834-025-68b/#2
                     INSECTICIDE  FORMULATIONS  (Continued)

Formula 6
Pyrethrins
Piperonyl butoxide
Petroleum distillates
Inert ingredients
Butane/Isobutane
Formula 7
d-trans Allethrin
Piperonyll butoxide
MGK 264
Petroleum distillates
Inert ingredients
Butane/Isobutane
Formula 8
Zinc dimethyl/dithiocarbamate
Endosulphan
Pyrethrins
Sulphoxide
Urea
Tensiofix LX
Tensiofix WP
Water
C02 propellant
Formula 9
Pyrethrins
Rotenone
Other Cube resins
Pine oil
Petroleum distillate
Inert ingredients
Butane/Isobutane
Formula 10
Insecticide solution in Kerosene
Span 85
Tveen 81
Deionized water
Butane
Percent
By Weight

0.50
1.00
11.83
58.00
30.00*

0.25
0.80
0.40
8.05
60.50
30.00*

0.12
0.68
0.16
0.20
0.40
0.06
0.04
43.34
5

0.06
0.01
0.02
0.90
0.40
68.61
30.00

15.5
1.5
1.0
42.0
40.0
Volatility

NV
NV
V
V
V

NV
NV
NV
V
V
V

NV
NV
NV
-
NV
NV
NV
-
V

NV
V
NV
V
V
V
V

V
NV
NV
-
V
VOC PROC
Emitted(%) Emitted(%)
98.5 98.5





98.6 98.6






5.0 5.0









99.9 99.9







55.5 55.5





 *Estimated from WAIB  (1981)
**Estimated from Chalimers/Bathe  (1979)
                                      -3-

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B/834-025-68b/tt2


                  INSECT REPELLENTS - AEROSOL AND NONAEROSOL
       National Shipment           Population           Geographic
         (million Ib)              Apportionment        Multiplier


       121                         .11 (CA)2            NA
                                   .046 (NY)
                                   .031 (NJ)
       (1982)

 2U.S. Bureau of the Census (1986)
                                      -4-

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B/834-025-68b/t2
                           INSECT REPELLENT FORMULAS
                               % Composition
                                 By Weight
          Volatility
         VOC      PROC
       Emitted(%) Emitted(X)
Formula 1*

N,N-Dialkyl-m-toluamide
Other isomers
Inert ingredients
14.25%
 0.75
85.00
NV
NV
 V
                         85.0
                     85.0
Formula 2a

N,N-Dialkyl-m-toluamide
Other isomers
N-Octyl-bicycloheptene
  dicarboximide
2,3,4,5-Bis  (2-butylene)
  tetrahydro-2-furaldehyde
Inert ingredients
                         75.0
                     75.0
19.00%
 1.00

 4.00
 1.00

75.00
NV
NV

NV
NV
 Formula 3a

 N,N-Dialkyl-m-toluamide
 Other isomers
 N-Octyl-bicycloheptene
  dicarboximide
 2,3,4,5-Bis  (2-butylene)
  tetrahydro-2-furaldehyde
 Inert Ingredients
                         62.9
                     62.9
30.69%
 1.00

 4.31

 1.08
62.92
NV
NV

NV

NV
 V
 Formula 4*

 2-Ethyl-l,3-hexanediol  '.             25.00%
 N,N-Diethyl-m-toluamide              4.75
 Other isomers                         0.25
 Inert ingredients  and propellant     70.00
                         75.0
                     75.0
               NV
               NV
               NV
                V
 Formula 5a

 2-Ethyl-l,3-hexandeiol
 N,N-Diethyl-m-toluamide
 Other Isomers
 Inert Ingredients
56.00%
 8.65
 0.45
34.90
                         34.9
                     34.9
NV
NV
NV
 V
 "Kline  (1982)
                                      -5-

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B/834-025-68b/#2

               MOTH CONTROL PRODUCTS - AEROSOLS AND NONAEROSOLS
       National Consumption        Population           Geographic
          (million Ib)             Apportionment        Multiplier

             391                   .11 (CA)2            NA
                                   =046 (NY)
                                   .031 (NJ)
       (1982)
 2U.S. Bureau of the Census (1986)
                                      -6-

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B/834-025-68b/f2
                         MOTH CONTROL PRODUCT FORMULAS
                                %  Composition
                                   By Weight    Volatility
                        VOC      PROC
                      Emitted(%) Emitted(%)
Formula la

Pyrethrin
Allethrin
N-octyl bicycloheptene
  dicarboximide
Piperonyl butoxide
Essential cedar oil
Petroleum distillates
Inert ingredients
 0.15
 0.15

 0.75
 0.50
 0.50
52.95
45.00
                         96.0
                    96.0
NV
NV

NV
NV
NV
 V
 V
 Formula 2a

 Cyclopropane carboxylate
  Tetramethrin derivative
  Phenoxybenzyl derivative
  Related isomers
 Isoparaffinic hydrocarbons
 Inert ingredients
 0.20
 0.19
 0.01
 7.75
91.85
                         99.6
                    99.6
NV
NV
NV
 V
 V
 'Kline  (1982)
                                      -7-

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B/834-025-68b/#2

                 ANIMAL INSECTICIDES - AEROSOL AND NONAEROSOL
     National Consumption        Population        Geographic
        (million Ib)            Apportionment      Multiplier
             61                     .11 (CA)2         NA
                                    .046 (NY)
                                    .031 (NJ)
       (1982)
 2U.S. Bureau of the Census (1986)
                                      -8-

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B/834-025-68b/#2
                         ANIMAL INSECTICIDE FORMULAS
% Composition
By Weight Volatility
Formula 1
Pyrethrins
Piperonyl butoxide
Methoxychlor
Carbaryl (1-Naphthyl N-Methyl
carbomate)
2,3:4,5-Bis(2 Butylene) Tetra-
hydro-2-Furaldehyde
Petroleum distillate
Inert ingredients
Unknown ingredients (assume
half are volatile)
Formula 2
o-Isoproxyphenyl methylcarbomate
Inert ingredients
Unknown ingredients (assume
half are volatile)
Formula 3a
Benzyl Benzoate
Soap anhydrous
Chlordane
Inert ingredients
Unknown ingredients (assume
half are volatile)
Formula 4b
Pyrethrins
Piperonyl butoxide
2,3,4,5-Bis(2-Butylene) Tetra-
hydro-2-Furaldehyde
Petroleum distillate
Inert ingredients
Formula 5b
Pyrethrins
Piperonyl butoxide
N-octylbicycloheptenedicarboximide
2,3,4,5-Bis(2-Butylene) Tetra-
hydro-2-Furaldehyde
Petroleum distillate
Inert ingredients

.60
.48
.50

.50

.24
22.84
65.38

9.46

.25
89.84

10.11

33.80
7.50
.75
52.05

5.90

0.08%
TRACE

0.02
7.77
91.97

0.062
0.12
0.20

0.20
0.288
99.132

NV
NV
NV

NV

NV
V
V

4.73%V

NV
V

5.052V

NV
NV
NV
V

2.95%V

NV
NV

NV
V
V

NV
NV
NV

NV
V
V
VOC PROC
Emitted(%) Emitted(%;
92.9 92.9











94.9 94.9




55.0 55.0






99.7 99.7






99.4 99.4







'Source:  Chalmers and Bathe  (1979)
 Kline (1982)
                                      -9-

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B/834-025-68b/#2
                   PAINTS, PRIMERS, AND VARNISHES - AEROSOL
U.S.
Annual Unit
Distribution
(millions)
300. 61


Average
Unit Weight
(Ibs/unit)
.752


Population
Apportionment
.ll(CA)3
.046(NY)
.031(NJ)
Geographic
Multiplier
1.15(CA)5
1.05(NY)
1.05(NJ)
      (1984); estimated millions of units  filled in 1984
 2WAIB (1981)
 3U.S. Bureau of  the Census  (1986)
 4 Simmons (1983)
                                      -10-

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B/83A-025-68b/#2
                                PAINT FORMULAS
Percent
By Weight
Formulation 1*

Barium metaborate
Aluminum paste
Silicone resin
Xylol and driers
Aromatic hydrocarbons
Methylene chloride

Propane
Isobutane
Formulation 2*
Nonvolatile Compounds
Glycol ethers
Aliphatic and aromatic
hydrocarbons
Halogenated hydrocarbons1
Isobutane
Propane
Formulation 3*
Nonvolatile Compounds
Isobutane
Propane
Toluene
Xylene
Methylene chloride

Cellosolve acetate
Formulation 4a
Nonvolatile Compounds
Petroleum distillate
Aromatic hydrocarbons
Chlorinated solvents
Aliphatic hydrocarbon propellant

15/9
0.8
3.3
11.8
40.0
5.6
13.5

12,5
12.5 •

18.0
1.2

32.8
19.0
14.5
14.5

18.0
30.0
5.0
4.0
21.0
15.0

7.0

15.8
13.0
14.6
27.0
29.6
VOC
Volatility Emitted(%)
84.1

Lt
_
_
V
V
V
(Non-PROC)
V
V
82.0
NV
V

V
V
V
V
82.0
NV
V
V
V
V
V
(Non-PROC)
V
84.2
NV
V
V
V
V
PROC
Emitted(%)
70.6










82.0







67.0








84.2





 'Poisindex  (1984)
 Replaced by aliphatic  hydrocarbons  such  as  butane,  propane.
                                     -11-

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B/834-025-68b/#2
                          PAINT FORMULAS (Continued)
                                Percent                VOC         PROC
                                By Weight  Volatility  Emitted(%)  Emitted(X)
Formulation 5a
Nonvolatile Compounds
Chlorinated solvents
Aliphatic hydrocarbons
Aliphatic thinner
Formulation 6a
Nonvolatile Compounds
Dioctyl phthalate plasticizer
Aromatic hydrocarbons
Esters and ketones
Acetone and chlorinated
solvents
Halogenated hydrocarbon
propellant

26.9%
21.0%
23.1%
29.0%

13.1%
1.4%
9.5%
11.0%

35.0%
30.0%
73.1 73.1
NV
V
V
V
86.9 86.9
NV
V
V
V

V
V
 *Poisindex (1984)

 Replaced by aliphatic hydrocarbons such as butane, propane.
                                     -12-

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B/834-025-68b/#2

              PAINTS AND FINISHES - RELATED PRODUCTS - AEROSOLS
U.S.
Annual Unit
Distribution
(millions)
6.91


Average
Unit Weight
(Ib/unit)
.692


Population
Apportionment
.ll(CA)3
.46 (NY)
.31(NJ)
Geographic
Multiplier
NA


     NA = not available
           (1984); millions of Ibs sold in 1984
     2WAIB (1981)
     3U.S. Bureau of the Census (1986)
                                     -13-

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B/834-025-68b/#2


                 PAINTS AND FINISHES - OTHER RELATED PRODUCTS
                                Percent                 VOC         PROC
                                By Weight  Volatility   Emitted^)  Emitted(%)
Formula la

  Isopropanol                          65%
  Water                                16%
  Phosphoric Acid                      19%
'Gosselin (1984)
                                     -14-

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B/834-025-68b/#2

         ROOM DEODORANTS AND DISINFECTANTS - AEROSOLS AND NONAEROSOLS
U.S.
Annual Unit
Distribution
(millions)
265. 51


Average
Unit Weight
(Ib/unit)
.52


Population
Apportionment
.ll(CA)3
.046(NY)
.031(NJ)
Geographic
Multiplier
.94(CA)4
.94(NY)
.94(NJ)
 Estimated from Simmons (1983)
 2WAIB (1981)
 3U.S. Bureau of the Census (1986)
 4 Simmons (1983)
                                     -15-

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3/834-025-68b/#2
                            ROOM DEODORANT FORMULAS

Formula la
Triethylene glycol
Isopropyl alcohol
Water
Perfume
Carbon Dioxide
Formula 2a
Propylene glycol
Ethyl alcohol
Methylene chloride
Perfume
Carbon dioxide
Formula 3a
Perfume
Span 85
Tween 81
Propylene glycol
Triethylene glycol
Isopropyl alcohol
Water (deionized)
Butane
Formula 4"
Triethylene glycol
Emulsifier
Sodium nitrate
Perfume
Water (deionized)
Butane
Percent
By Weight

3.0
86.5
5.0
.5
5.0

10.8
48.0
35.0
1.2
5.0

0.5
1.3
0.7
3.0
2.0
8.0
44.5
40.0

3.00
0.75
0.05
0.50
60.70
35.00
Volatility

NV
V
-
V
V

V
V
V
V
V

V
NV
NV
V
NV
V
-
V

NV
NV
-
V
-
V
VOC PROC
Emitted(X) Emitted(2)
92.0 87.0





100.0 60.0





51.5 51.5








35.5 35.5






 *Chalmers and Bathe  (1979)
                                     -16-

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B/83A-025-68b/tt2

              TILE AND BATHROOM CLEANER - AEROSOL AND NONAEROSOL
     National Consumption        Population        Geographic
         (million Ib)           Apportionment      Multiplier

         651                    .11 (CA)2          NA
                                .046 (NY)
                                .036 (NJ)
 Calculated from Kline (1982)
 2U.S. Bureau of the Census (1986)
                                     -17-

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B/834-025-68b/#2
                    TILE AND BATHROOM CLEANER FORMULATIONS
                                   Percent
                                   By  Weight   Volatility
VOC         PROC
Emitted(%) Emitted(%)
Formula 1

0-Benzyl-p-chlorophenol                 0.14%     NV
Tetrasodium EDTA                        4.56      NV
Isopropyl alcohol                       2.40       V
Inert ingredients*                     92.90      NV

*Includes cleaners,  detergents,
 and borax

Formula 2a

Alkyldimethylbenzylammonium
  chloride                              0.10%     NV
Tetrasodium EDTA                        1.52      NV
Sodium metasilicate                     0.06
Inert ingredients                      98.32      NV

Formula 3*

Sodium o-phenylphenolate               0.20%     NV
Tetrasodium EDTA                        2.75      NV
Sodium n-dodecylbenzene  sulfonate      0.35      NV
Inert ingredients                      96.70      NV

Formula 4b

Abrasive                                  88      NV
Sodium tripolyphosphate                    5
Aklyl aryl sodium sulfonate               5
Trisodium sulfonate                        2

Formula 5b

Stoddard solvent                        0-31       V
Morpholine                               0-2       V
Trisodium phosphate                      0-3
Soap                                     0-3
Wetting agent                            0-1      NV
Silica                                  0-65
Water                                 to 100
  2.4
 2.4
  0.0
 0.0
  0.0
 0.0
0.0-33.0   0.0-33.0
  0.0
33.0
 'Kline  (1982)
 Gosselin  (1985)
                                      -18-

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B/834-025-68b/#2

                    OVEN  CLEANERS  - AEROSOL AND NONAEROSOL
         National Consumption      Population        Geographic
            (million Ib)          Apportionment      Multiplier

            331                    .11 (CA)2         1.02 (CA)3
                                   .046 (NY)         1.0 (NY)
                                   =031 (NJ)         1.0 (NJ)
       (1982)
 2U.S. Bureau of the Census (1986)
                                     -19-

-------
B/834-025-68b/tt2
                           OVEN CLEANER FORMULATIONS
 Formula 4a

 Sodium hydroxide
 Sodium carboxymethyl-
   cellulose
 Water, to make
                                   Percent                VOC         PROC
                                   By Weight  Volatility  Emitted(X)  Emitted(X)
Formula la
Ammonium hydroxide
Veegum T-a
1,1, 1-Trichloroethane
Tergitol NPX-b
Ethyl alcohol
Water
Above concentrate
Propellant (Butane)
Formula 2a
Salt mixture-a
Calcium carbonate, up to
Thickener
Surfactant
Biocide
Water, to make
Formula 3a
Sodium hydroxide
Kelzan-c
Veegum T-a
Antaron FC 34-d
Water
Above concentrate
Propellant (Butane)

8
2
24
24
10
32
25
75

10.0
6.0
0.2
0.1
q.s.
100.0

10

i
2
87
80
20
8.5 8.5
_
NV
V
NV
V
-

V

NV
-
NV
NV

-
20.0 20.0
_
NV
NV
NV
: -

V
 10.0

  7.0
100.0
                          0.0
                     0.0
NV
 "Kline  (1982)
                                      -20-

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B/834-025-68b/#2






             RUG AND UPHOLSTERY CLEANERS - AEROSOL AND NONAEROSOL
National Consumption
(million Ib)
1151


Population
Apportionment
.11 (CA)2
.046 (NY)
.031 (NJ)
Geographic
Multiplier
NA


       (1982)
 2UoS. Bureau of the Census (1986)
                                     -21-

-------
B/83A-025-68b/tt2
                   RUG AND UPHOLSTERY CLEANER  FORMULATIONS
Percent
By Weight
Formulation la
Sodium lauryl sulfate
Dimethylene oxide
Ethylene glycol monobutyl ether
Preservatives and optical
brighteners
Aqueous solution
Formulation 2a
Water
Detergent
Butane propellant
Formulation 3b
Bentonite
Petroleum distillate (light)
Wood flour
May contain:
Salicylic acid
Volatility

5.4%
0.6
2.8

1.0
91.0

85%
10
5

60-70
26
5

1
VOC PROC
Emitted(%) Emitted(%)
3.4 3.4
NV
V
V

NV
-
5.0 5.0
—
NV
V
26.0 26.0
_
V
NV

NV
 'Kline (1982)



 "Gosselin (1985)
                                     -22-

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                 ALL PURPOSE CLEANERS - AEROSOL AND NONAEROSOL
National Consumption Population
(million Ib) Apportionment
5121 .11 (CA)2
.046 (NY)
.031 (NJ)
Geographic
Multiplier
1.07 (CA)3
1.0 (NY)
1.0 (NJ)
       (1982)



2U.S. Bureau of the Census (1986)



3 Simmons (1983)
                                     -23-

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                       ALL PURPOSE CLEANER FORMULATIONS
Percent VOC PROC
By Weight Volatility Emitted(*) Emitted^)
Formulation la
Anionic and nonionic detergents
Alkaline builders
Foam stabilizers
Solvents
Chelating agents
Sodium xylene sulfonate or
ethyl alcohol solubilizer
Ammonia
Water (including color and
fragrance)
Formulation 2a
Pine oil
Isopropyl alcohol
Soap
Ethyl alcohol
EDTA
Inert ingredients

1-4
1-3
0-1
2-4
0-1

-
0-1

to 100

30.0
10.9
10.0
-
_
49.1
2.0-4.0 2.0-4.0
NV
-
NV
V
NV
NV
-
_

-
40.9 40.9
V
V
NV
V
NV
NV
 'Kline (1982)
                                     -24-

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              WINDOW AND GLASS CLEANERS - AEROSOL AND NONAEROSOL
         National Consumption      Population        Geographic
          (million Ib)            Apportionment      Multiplier
              1741                 .ll(CA)2           .98 (CA)3
                                   .046(NY)          1.0 (NY)
                                   0.31(NJ)          1.0 (NJ)
Calculated from Kline (1982)
2U.S. Bureau of
3 Simmons (1983)
2U.S.  Bureau  of  the  Census  (1986)
                                     -25-

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                       WINDOW AND GLASS CLEANER FORMULAS
                              %  Composition                VOC       PROC
                                 By  Weight     Volatility  Emitted(%) Emitted(%)
                                       0.0-5.0     V
                                      0.1-2.5      V
                                      0.1-0.2
                                    0.05-0.15     NV
                                        0-0.1
                                         q.s.      V
                                         100%
Formula la

Isopropyl alcohol
Higher glycols or ethers
Ammonia
Surfactant
Alkaline builders
Dye, fragrance
Water, to make

Formula 2a

Isopropyl alcohol                        5.0      .V
Higher glycols                          2.00      V
Sodium lauryl sulfate-a                 0.15     NV
Ammonia, 28% solution                   0.15
Dye, fragrance                           q.s      V
Water, to make                          100%

Formula 3a

Dipropylene glycol monomethyl ether       4.0     V
Isopropyl alcohol                        4.0      V
Pluronic F 108 detergent                 0.1     NV
Ammonium hydroxide, 28%                  1.0
Distilled water                         90.0

Formula 4*

Detergent
Ammonia
Fragrance
Isopropyl alcohol
Water
Propellant

Formula 5b

Butyl cellosolve                         3-5      V
Alcohol                                  3-5      V
Wetting agent                           0.5-1     NV
Isopropanol                             0-15      V
Dyes                                    trace     NV
Silicone                                trace     NV
Water                                  to 100
0.1-0.3
0.5-1.0
0.1
10.0-35.0
60.0-85.0
4.0
NV
_
V
V
_
V
                                                           0.1-7.5
0.1-7.5
                                                               7.0
    7.0
                                                               8.0
  8.0
                                                             14.1-39.1 14.1-39.1
                                                              6.0-25.0 6.0-25.0
                                      -26-

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                 WINDOW AND GLASS CLEANER FORMULAS (Continued)
                               % Composition
                                 By Weight
       Volatility
          VOC        PROC
        Eraitted(Z) Emitted(Z)
Formula 6

Isopropyl alcohol
Glycol ether
Ethylene glycol
Surfactant (usually an
  anionic but occasionally
  a nonionic, such as
  Triton X-200 or Turkey
  red oil)
Water
Butane propellant

Formual 7b

Pine oil
Fatty acid soap
Synthetic anionic or nonionic
  surfactant
Sodium polyphosphates
Amines
Ammonia
                   17.0-42.0  17.0-42.0
 6-25
10-11
    1
 V
 V
 V
NV
60-80
  0-5
 0-10
 5-30

 0-20
 0-15
  0-5
  0-5
                   0.0-10.0
                    0.0-10.0
 V
NV

NV
 Kline (1982)

 'Gosselin (1985)
                                     -27-

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                          LAUNDRY PRODUCTS -  AEROSOLS
                              (STARCHES,  SIZINGS)
U.S.
Annual Unit
Distribution
109. 91


Average
Unit Weight
(Ib/unit)
.752


Population
Apportionment
.ll(CA)3
.046(NY)
.031(NJ)
Geographic
Multiplier
NA


     NA = not available
     ^SMA (1984); estimated millions of Ibs filled in 1984
     2WAIB (1981)
     3U.S. Bureau of  the Census  (1986)
                                     -28-

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                           LAUNDRY PRODUCTS FORMULAS
                                  Percent
                                  By  Weight
        Volatility
        VOC
        Emitted(X)
PROC
Emitted^)
Formula 1*

Kosol predigested starch
Borax
Tinopax ANA
Formaldehyde solution  (30/K)
Sodium nitrate
Silicone emulsion LE 463
Perfume
Isopropyl alcohol
Deionized water
Butane
 5.0
  .2
  .2
  .10
  .15
  .8
  .05
 6.0
82.5
 5,0
                      11.2
                       11.2
NV

NV
 V

NV
 V
 V
 Formula 2a
 "Chalmers and Bathe  (1979)
                      4.9
                     4.9
Gelva emulsion TS 31
Calgon
Sindar technical G4-40
Carboxymethyl cellulose
Perfume
Deionized water
Sapamine VL
Butane
3.18
.01
.03
.11
.01
91.88
.09
4.76
NV
NV
NV
NV
V
—
NV
V
                                      -29-

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                 LAUNDRY PRODUCTS  -  AEROSOLS  AND NONAEROSOLS
     National Consumption          Population            Geographic
       (millions Ib)              Apportionment          Multiplier
Prevash Stain Removers

            841                      .11 (CA)2               NA
                                      .046 (NY)
                                      .031 (NJ)
Spot Removers
            2.3                       .11 (CA)2               NA
                                      .046 (NY)
                                      .031 (NJ)
       (1982)

 2U.S. Bureau of the Census (1986)
                                     -30-

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                            LAUNDRY PRODUCT FORMULAS
                                   Percent                VOC         PROC
                                 By Weight   Volatility  Emitted(%)   Emitted(X)
Prevash

Formula 1*

Ethoxylated fatty alcohol  sulfate    20.0
Isoparaffinic solvent                20.0
Triethanol amine oleate               3.5
Sodium xylene sulfonate              30.0
Water       25.5

Formula 2*

Ethoxylated fatty alcohol  sulfate    22.0
Isoparaffinic solvent                18.0
Triethanol amine oleate               2.5
Water       57.5

Spot Removers

Formula 1"

Trichloroethylene                    75.0
Butane/Isobutane                     25.0

Formula 2a

Perchloroethylene                    65.0
Methylene chloride                   10.0
Butane/Isobutane                     25.0
           0.0
  0.0
NV
NV
NV
NV
           0.0
  0.0
NV
NV
NV
 V
 V
 V
 V
 V
         100.0
         100.0
100.0
 90.0
 "Kline (1982)
                                      -31-

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                        WAXES  AND POLISHES -  AEROSOLS
     National Consumption          Population            Geographic
       (millions Ib)              Apportionment          Multiplier
     Liquids

     31                              .11 (CA)2            .95 (CA)3
                                     .046 (NY)            1.0 (NY)
                                     .031 (NJ)            1.0 (NJ)

     Aerosols

     581                             .11 (CA)2            .95 (CA)
                                     .046 (NY)            1.0 (NY)
                                     .031 (NJ)            1.0 (NJ)
 'Kline (1982)

 bU.S. Bureau of the Consensus  (1986)

 cSimmons (1983)
                                     -32-

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                 VAXES AND POLISHES - FORMULATIONS - AEROSOL
                               Percent
                               By Weight
         Volatility
        VOC        PROC
        Emitted(%) Emitted(%)
Aerosols

Formula 1!
     Wax
     Silicone oil
     Emulsifier
     Solvent
     Water
     Butane
Formula
     Wax
     Silicone oil
     Emulsifier
     Solvent
     Water
     Butane
Formula 3
 0.5
 2.5
 0.5
 2.5
89.5
 4.5
 2.0
 3.0
 1.0
20.0
62.0
12.00
'Kline (1982)
NV
NV
NV
 V
NV
NV
NV
 V

 V
                          7.0
                       7.0
                         32.0
                      32.0
                         34.0
                      34.0
Water
Solvent
Propellant (assume butane)
Waxes and oils
Emulsifiers
60.0
20.0
14.0
5.0
1.0
-
V
V
NV
NV
                                     -33-

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                      OTHER HOUSEHOLD PRODUCTS - AEROSOLS
U.S.
Annual Unit
Distribution
45. 21


Average
Unit Weight
(Lbs/unit)
752


Population
Apportionment
.ll(CA)3
.046(NY)
.031(NJ)
Seasonal Geographic
Variation Multiplier
NA NA


 ''CSMA (1984); estimated millions of units  filled  in  1984
 2WAIB (1981)
 3U.S. Bureau of the Census,  personal  communication
                                      -34-

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        SHOE POLISHES,  WAXES, AND COLORANTS - AEROSOLS AND NONAEROSOLS
     National Consumption        Population        Geographic
         (million Ib)           Apportionment      Multiplier
            61                   .11 (CA)2           NA
                                 .046 (NY)
                                 .031 (NJ)
       (1982)
2U.S. Bureau of the Census (1986)
                                     -35-

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                  SHOE POLISHES,  WAXES,  AND COLORANTS FORMULAS
                                    Percent
                                   By Weight
Volatility
VOC        PROC
Emitted(%) Emitted(%)
Formula la

   Carnauba and other waxes           6-8
   Naptha                             5-6
   Stearate emulsifier                3
   Water                              75
   Propellant (Butane/Isobutane)      8

Formula 2*

   Acrylic, vinyl, or other
     synthetic waxes  *               2-15
   Naptha                             0-15
   Alcohol and other solvents         10-50
   Butane/Isobutane propellant        25-80

Formula 3
 'Kline (1982)

 bChalmers and Bathe  (1979)
            13.0-14.0  13.0-14.0
     NV
      V
     NV
            85.0-98.0  85.0-98.0
     NV
      V
      V
      V
                 73.0
                73.0
Wax
Crystalline

wax, 70 °C
Paraffin wax, 52°-54eC
Turpentine
White spirit
Colour mix



9.5
'0.5
14.0
33.0
40.0
3.0
NV
NV
NV
V
V
NV
                                     -36-

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                     OTHER HOUSEHOLD PRODUCTS - AEROSOLS
        National Consumption       Population         Geographic
          (million Ib)            Apportionment       Multiplier
     Antistatic Sprays

             31                    .ll(CA)2             NA

                                   .046(NY)

                                   .031(NJ)
            (1982)

     2 U.S. Bureau of the Census (1986)
                                     -37-

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                 ANTISTATIC PRODUCTS - AEROSOL AND NONAEROSOL
                                Percent                 VOC         PROC
                                By Weight  Volatility   Emitted(%)  Emitted(%)


Formula la                                                 0.0         0.0

  Alkyl dimethyl benzyl
    ammonium chloride                .l-.5%         NV
  Water                         99.9-99.5%


Formula 2*                                                 3.0         3.0

  N-Acetylethanolamine                 1-3%          V
  Water                              97-992


"Gosselin (1984)
                                     -38-

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                     ADHESIVES1 - AEROSOLS AND NONAEROSOLS
  National Consumption          Population Geographic
     (million Ib)            Apportionment Multiplier
           3277.52                .11 (CA)3           NA

                                  .046 (NY)

                                  .031 (NJ)
 Includes industrial, commercial, and consumer adhesives

 2U.S. Bureau of the Census (1982)

 3U.S. Bureau of the Census (1986)
                                     -39-

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A/834-025-68a/tt3
                                   ADHESIVES
                               Percent      VOC           PROC
                               By Weight    Volatility    Emitted(%)  Emitted(%)
Formula la

  Milled pale crepe                   55
  Poly-beta pinene resin,
   m.p.70°C                           41
  Petroleum oil                        3
  Polytrimethyldihydroquinoline        1

Formula 2a
  Milled smoke rubber
  Zinc oxide
  Dehydrogenated resin
  Sym-di-beta naphthyl-p-phenylene
   diamine
  Lanolin

 Formula 3a
  Polyisobutylene  (high molecular
   weight)                            60
  Polyisobutylene  (viscous  fluid)     40

 Formula 4a

  Milled smoke rubber                 29
  Butadiene-styrene copolymer
   (70:30 ratio)                      29
  Hydrogenated resin ester            29
  Polytrimethyldihydroquinoline        1
  Petroleum oil                       12

 Formula 5a

  Neoprene                            91.74
  Magnesium oxide                      3.67
  Zinc oxide                           4.59
  Solids to make 20% by weight
   Toluene                            80.0
NV

NV
 V
NV
42
21
32
1
4
NV
—
NV
NV
NV
NV
NV
NV

NV
NV
NV
 V
NV
 V
 V
             3.0
 3.0
             0.0
 0.0
             0.0
 0.0
            12.0
12.0
            80.0
80.0
                                      -40-

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                             ADHESIVES (Continued)
                                 Percent
                               Composition
                                By Weight
        Volatility
        VOC       PROC
        Emitted(%) Emitted(%)
Formula 6a

  Nitrocellulose (11.4% N)
  Camphor
  Acetone
  Ethyl alcohol 74 OP
  Amyl acetate

Formula 7a

  Celulose acetate butyrate
   (1/2 sec.)
  Polyvynyl acetate
  Petrex 7-75T (dry)
  Dow 276-V9
  Tricresyl phosphate
  Alcohol (95% Tescol)
  Toluene
  Ni tropropane-1*
15
 6
11
44
24
20.0
 2.5
 7.5
10.0
 2.0
12.0
43.0
 3.0
                        85.0
                     85.0
NV
 V
 V
 V
 V
                        60.0
                     60.0
NV
NV
NV
NV
 V
 V
 V
 V
 Commercial solvent.
 "Chalmers and Bathe  (1979)
                                     -41-

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           CAULKING AND  SEALING  COMPOUNDS  - AEROSOL AND NONAEROSOL
National Consumption
(million Ib)
432. 81
Population
Apportionment
.11 (CA)2
.046 (NY)
.031 (NJ)
Geographic
Multiplier
NA
 1U.S. Bureau of the Census (1984); represents only synthetic base sealants and
 special performance sealants

 2U.S. Bureau of the Census (1986)
                                     -42-

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                         CAULKING AND  SEALANT  FORMULAS
                                   Percent
                                   By  Weight
       Volatility
     VOC         PROC
     Emitted(%) Emitted(%)
Formulation la

Hypalon (chlorosulfonated
  poylethylene polymer)
Elastomeric binder
Chlorinated paraffin plasticizer
Asbestos or silicon dioxide  extenders
Titanium dioxide pigment
Talc (extender)
Tribasic lead maleate
Rosin, MBTS, and Thiuram
Xylene
Tributyl phosphate
Fractal A
Isopropyl alcohol

Formulation 2a

Styrenated alkyd resin
Titanium dioxide
Calcium cardonate
Asbestos fiber
Xylene

Formulation 3a

Polydimethylsiloxane
Silica
                        2.0
                     2.0
 20

 20
 10
 12
  8
  6
  0.
 10
  9
  3
  2
40
20
85
15
NV

NV
NV
NV
NV
NV
NV
 V
NV
NV
 V
              NV
              NV
 V
NV
                       20.0
                    20.0
                        0.0
                     0.0
 Gosselin  (1985)
                                      -43-

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A/834-025-68a/t3


             OTHER HOUSEHOLD PRODUCTS  - AEROSOLS AND NONAEROSOLS
     National Consumption          Population            Geographic
       (millions Ib)              Apportionment          Multiplier
     Carpet Deodorizers

            651                      .11 (CA)2                 .96 (CA)3
                                     .046 (NY)                 .91 (NY)
                                     .031 (NJ)                 .91 (NJ)

     Drain Openers

     17 (million gal. liquids)1      .11 (CA)2                 .94 (CA)3
     293 million Ibs solid           .046 (NY)                 .94 (NY)
                                     .031 (NJ)                 .94 (NJ)
       (1982)

       ureau

3 Simmons  (1983)
 2U.S. Bureau of the Census  (1986)
                                     -44-

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                               CARPET DEODORIZER
                                Percent                 VOC          PROC
                                By Weight  Volatility   Emitted(%)   Emitted^)
Formula la                                                  2.0         2.0

  Sodium sulfate                     <70%
  Sodium bicarbonate                 <25%          NV
  Corn starch                        <15%          NV
  Fragrance                            <2%          NV


"Gosselin (1984)
                                      -45-

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                     OTHER HOUSEHOLD PRODUCTS FORMULATIONS
                                   Percent               VOC        FROC
                                  By Weight  Volatility  Emitted(%) Eraitted(X)


Drain Cleaners

Formula 1 (solid)9                                          0.0        0.0

   Sodium hydroxide                    54.2
   Sodium nitrate                      30.45
   Aluminum                             4.1
   Inert ingredient                    11.25

Formula 2 (liquid)0                                         0.0        0.0

   Sodium hydroxide  (502 solution)     10.0
   Sodium hypochlorite  (5% solution)   90.0


'Kline (1982)
                                     -46-

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                           SHAVING CREAM - AEROSOLS
U.S.
Annual Unit
Distribution
(millions)
162. 81


Average
Unit Weight
(Ib/unit)
.52


Population
Apportionment
.11 (CA)3
.047 (NY)
.031 (NJ)
Geographic
Multiplier
1.01 (CA)4
1.07 (NY)
1.07 (NJ)
      (1985); estimated millions of units filled in 1984



 2(WAIB, 1981)



 3U.S. Bureau of the Census (1986)



 4Based on data from Simmons  (1983)
                                     -47-

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A/834-025-68a/#3
                             SHAVING CREAM FORMULAS
                                  Percent
                                  By Weight Volatility
                        VOC
                        Emitted(%)
                                                                    PROC
                                                                    Emmitted(%)
Formulation 1
                            8.8
                                                                        8.8
                                    2,
                                    5,
                                    1,
      000
      800
      000
Stearic acid (95% purity)
Palmitic acid (97% purity)
Polyoxyethylene (2) cetyl ether
Hydroxyalkyl cellulose (Klucel HA) 0.067
Carbopol 934                       0.180
Propylene glycol dipelargonate     2.750
Sorbitol (70% solution)           10.000
Propylene glycol                   3.300
Triethanolamine                    4.200
Water (deionized)                 67.953
Fragrance, dye                   insign.
n-butane                           0.550
n-pentane                          2.200
 Formulation 2

 Palmitic acid
 Myristic acid
 Myristyl alcohol
 Polyoxyethylene  (20)  cetyl ether
 Laurie diethanolamide
 Propylene glycol
 Glycerol
 Triethanolamine
 Water (deionized)
 Perfume

   Concentrate
   Propellant (Butane  48)
    1.95
    0.62
    2.10
    5.23
    5.23
    0.82
    3.54
    1.54
   78.97
 insign.

   97.0
    3.0
 Formulation  3

 Stearic acid
 Laurie acid
 Liquid anolin  (Fluilan)
 Cromeen
 Triethanolamine
 Water (deionized)
 Perfume

   Concentrate
   Butane
    4.0
    2.0
    1.0
    3.0
    2.5
   87.5
insign.

   96.0
    4.0
NV
NV
NV
NV
NV
 V
NV
 V
NV

 V
 V
 V
                                                 NV
                                                 NV
                                                 NV
                                                  V
                                                 NV
                                                  V
                                                 NV
                                                 NV
                                                 NV
                                                 NV
                                                 NV
                                                 NV
                                                 NV

                                                  V
                                                  V
                            8.9
                                                                        8.9
                            4.0
                                                                        4.0
                                      -48-

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                      SHAVING CREAM FORMULAS  (Continued)
                                 Percent               VOC         PROC
                                 By Weight Volatility  Emitted(£)  Eraitted(^)
Formulation 4
Palmitic acid
Laurie acid
Sodium lauryl sulphate
Polyethylene glycol (400)
monolaurate
Polyacrylic acid (40% aq.)
mol.wt 100.000
Triethanolamine
Potassium hydroxide
Glycerol
Water (deionized)
Perfume
Concentrate
-
5.0
1.0
1.0

0.5

1.5
2.0
0.8
5.0
83.2
insign.
96.9
Propellants, isobutane/propane 3.1
3.1 3.1
NV
NV
NV

NV

• NV
NV
-
NV
-
V

V
Source:  Harry's Cosmeticology (1982)

^romeen (Croda Chemicals Ltd.) is a substituted alkyl amine derivative of
 various lanolin acids

2Listed as a chlorofluorocarbon propellant, now banned.  WAIB states that
 propane or butane are the most likely substitutes.
                                     -49-

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                           HAIR PRODUCTS - AEROSOLS
         U.S.
     Annual Unit
     Distribution
      (millions)
  Average
Unit Weight
 (Ib/unit)
 Population
Apportionment
                                                   Geographic
                                                   Multiplier
Hair Spray


   270.71
                        .632

                        .046 (NY)

                        .032 (NJ)
                  .11 (CA)
                      .93 (CA)

                      .87 (NY)

                      .87 (NJ)
     Mousse
        106. I
   .38

   .046 (NY)

   .031 (NJ)
  .11 (CA)
                                                      NA
           (1984); estimated millions of units filled in 1984
     2WAIB (1981)

     3U.S. Bureau of the Census (1986)

     4 Simmons (1983)
                                     -50-

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A/834-025-68a/#3
                            HAIR SPRAY  FORMULATIONS
                                  Percent
                                  By Weight
Volatility
VOC
Emitted(%)
PROC
Emitted^)
Formulation la                                             88.1

Amphomer                            1.80          NV
AMP                                 0.30           V
Monamid 716                         0.10          NV
DC 193 Fluid                        0.05          NV
Ethanol 40-1 (Anhyd)               52.75           V
Water                              10.00
Methylene Chloride                    —           V
                                              (Non-PROC)
Dimethyl Ether                     35.00           V

Formulation 2*                                             97.4

Resyn 28-2930                       2.50          NV
AMP                                 0.20           V
Monamid 716                         0.10          NV
DC 193 Fluid                        0.05          NV
Ethanol 40-1 (Anhyd)               47.15           V
Water
Methylene Chloride                 15.00           V
                                              (Non-PROC)
Dimethyl Chloride                  35.00           V

Formulation 3b                                             95.9

Gantrez ES 225  or ES  425           4.00          NV
AMP                                 0.08           V
Polyethoxylated (75 EO)  lanolin    0.10          NV
Perfume oil                         0.10           V
Solvents                           75.72           V
Isobutane/propane  (90s 10)          20.00           V

Formulation 4b                                         ...   97.5

Resyn 28-2930                       1.50          NV
AMPD                                0.38          NV
Alcohol-soluble lanolin             0.90          NV
Isopropyl myristate                 0.40          NV
Dipropyleneglycol                   0.10          NV
Perfume oil                         0.35           V
Ethanol                            96.37           V
     Concentrate                  75.00
     Isobutane/propane (90:10)    25.00
                          88.1
                          82.4
                           95.9
                           97.5
                                      -51-

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                      HAIR SPRAT FORMULATIONS (Continued)
                                 Percent                VOC         PROC
                                 By Weight  Volatility  Emitted(%)  Emitted^)
Formulation 5b
Resyn 28-2930
AMP
Diraethicone copolyol*
Perfume
Methylene chloride

Et Hanoi
Carbon dioxide

*CTFA; polymer of dimethylsiloxane
polyoxypropylene side-chains.

2.25
0.18
0.12
0.10
20.00

72.85
4.50

with

93.1 73.1
NV
V
NV
V
V
(Non-PROC)
V
NV
(Non-PROC)
polyoxyethylene and/or

 'Novak et al (1985)

 bHarry's Cosmeticology  (1982)
                                     -52-

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                            STYLING MOUSSE FORMULAS
                                 Percent                VOC         PROC
                                 By Weight  Volatility  Emitted(%)  Emitted(%)
Formulation 1                                              24.5        24.5

Polyquaternium-4 (2% solution)      50.00        NV
Quaternium-26                        0.75        NV

Stearmidopropyl Cetearyl Dimonium
  Tosylate (and) propulene glycol    0.50         V

Cetyl Alcohol                        0.50        NV
Deionized Water                      9.50
Ethanol                             20.00         V

95X concentrate, 5% propane/isobutane  propellant
                                     -53-

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              OTHER HAIR CARE PRODUCTS - AEROSOL AND NONAEROSOL
                                  (SHAMPOOS)
National Consumption               Population                     Geographic
  (millions Ib.)                  Apportionment                   Multiplier


       644.61                       .11 (CA)2                     1.01 (CA)3

                                    .046 (NY)                      .00 (NJ)
                                    .031 (NJ)                      .99 (NJ)
 Calculated from Predicast (1984)

 2U.S. Bureau of the Census (1986)

 3 Simmons (1983)
                                     -54-

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                              SHAMPOO FORMULATIONS
Percent VOC PROC
By Weight Volatility Emitted(%) Emitted(%)
Formula 1
Ammonium lauryl ether sulphate
Cocoamino betaine 31-32%
Sandopan TFL cone. 48%*
Adipic acid/dimethylamino
hydroxypropyl diethylene-
triamine copolymer
(Cartaretine F4)
Citric acid anhydrous
Water

25.00
25.00
4.20



3.33
0.98
to 100.00
0.0 0.0
NV
NV
NV



NV
NV
-
Formula 2                                                   0.5          0.5

Polymer JR 30 M (CTFA:
  Quaternium 19)
  (MW = 30,000)                        1.5         NV
Miranol C2MSF (CTFA:
  Amphoteric 2) 70%                   11.0         NV
Sandopan DTC acid  (CTFA:
  Trideceth-7-carboxylic
  acid) 90%                           15.0         NV
Ethyleneglycol distearate              2.0         NV
Methyl p-hydroxybenzoate               0.2           V
Propyl p-hydroxybenzoate               0.05        NV
Protein hydrolysate                    0.5         NV
Perfume oil                            0.3           V
Water                             to  100.0

Formula 3                                                   0.0          0.0

Coconut amidopropyl-3-
  dimethylamine betaine                5.4         NV
Sodium lauryl sarcosinate              5.2         NV
Ethoxylated tridecyl alcohol
  (20 EO)                             14.0         NV
Cationic cellulose (Polymer JR:
  Union Carbide)                       0.5         NV
Water                             to  100.0
                                     -55-

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                          PHARMACEUTICALS - AEROSOLS
U.S.
Annual Unit
Distribution
(millions)
43. 71


Average
Unit Weight
(Ib/unit)
.252


Population
Apportionment
.11 (CA)3
.046 (NY)
.031 (NJ)
Geographic
Multiplier
1.08 (CA)4
o98 (NY)
.98 (NJ)
1CSMA (1984)



2WAIB (1981)



3U.S. Bureau of the Census (1986)



"Data for fungicides only (Simmons,  1983)
                                     -56-

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                            PHARMACEUTICAL FORMULAS
                                 Percent
                                 By Weight
Volatility
VOC
Emitted(%)
PROC
Emitted(%)
Fungicides

Formulation la

Copper undecylenate                  0-5%       NV
Undecylenic acid                     2-5%       NV
Zinc undecylenate                   0-20%       NV
  Available as:
    Foam with 34.65% base                        V
    Foam (aerosol) also contains:
      Ethyl alcohol                   60%        V
      Menthol                       0.25%        V
      Methylbenzethonium chloride    0.1%       NV

Formulation 2a

Benzoic acid                         1-5%       NV
Boric acid                          0-15%
Salicylic acid                       1-3%       NV
Thymol                               0-1%       NV
  Available as:
    Spray with 80-92% base                       V

Formulation 3*

Alcohol                             36-50%
Benzethonium                         0.5%       NV
  Available as:
    Spray with 50-63%
     base/propellant                             V
    May contain Salicylanilide       2.5%       NV
             69.9-97.9   69.9-97.9
             78.0-90.0   78.0-90.0
             97.0-99.5   97.0-99.5
"Gosselin (1984)
                                     -57-

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          COLOGNES,  PERFUMES, AFTERSHAVES - AEROSOLS AND NONAEROSOLS

Perfumes
Colognes
U.S.
Annual Unit
Distribution
(millions)
821
44
Aftershaves 23
Average
Unit Weight
(Ib/unit)
0.032
0.125
0.25
Population
Apportionment
.11 (CA)3
.046 (NY)
.031 (NJ)
Same
Same
Geographic
Multiplier
NA
NA
NA
       (1986)

2A shelf survey shoved that 'perfumes were typically 0.5 oz (.03 Ib), colognes
 typically 2 oz (0.125 Ib), and aftershaves  typically 4 oz (0.25 Ib)

3U.S. Bureau of the Census (1986)
                                     -58-

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                  PERFUMES, COLOGNES, AND AFTERSHAVE FORMULAS
                                 Percent                  VOC         PROC
                                 By Weight  Volatility  Emitted(Z)  Emitted(JK)
Perfumes8 :
Formula 1
Perfume oil
Denatured alcohol
(SDA-40, 40-B, 39-C)
Colognes* ;
Formula 1
Perfume oil1
Denatured alcohol
Aftershaves'" :
Formula 1
Polawax A 31
Menthol
Alcohol 740 P
Demineralized water
Perfume


15-30

70-85


5-10
90-95


2.0
0.1
64.2
33.2
0.5


V

V


V
V


NV
V
V
NV
V

100.0 100.0




100.0 100.0



64.8 64.8





1Perfume oils can be composed of hundreds of different natural and  synthetic
 compounds and therefore cannot be characterized.

"Wenningen (1986); Etheridge (1986)

"Gosselin et al. (1984)
                                     -59-

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              PERSONAL DEODORANTS AND ANTIPERSPIRANTS - AEROSOLS
U.S.
Annual Unit
Distribution
(millions)
156. O1
Average
Unit Weight
(Ib/unit)
.25 Ibs/unit2
Population
Apportionment
.11 (CA)3
.046 (NY)
.031 (NJ)
Geographic
Multiplier
.86 (CA)4
.89 (NY)4
.89 (NJ)4
1CSMA (1984)



2WAIB (1981)



3U.S. Bureau of  the Census  (personal communication)



4Simmons (1983)
                                      -60-

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                   DEODORANT AND ANTIPERSPIRANT FORMULATIONS
                                Percent
                                By Weight
Volatility
VOC        PROC
Emitted(%) Emitted(%)
Formulation la

Alcohol (ethyl)                     0->50        V
Propellant (Butane)                 0->50        V
Antiperspirant salts
  (e.g., aluminum chlorhydroxide)    0-10       NV
Deodorant agents                      0-5        V
  Other [oils, humectants,
  suspending agents (e.g.,
  bentonite)]                        0-10       NV

Formulation 2"
             80.0-90.0   80.0-90.0
             89.0-95.0   89.0-95.0
Propellant (Butane)
Talc and fillers
Alcohol (ethyl)
Essential oil (fragrance)
Humectants
Formulation 3a
Aluminum phenolsulfonate
Propylene glycol
Alcohol
Perfume
>50
0-10
0-5
0.1-1
0.1-1

10.0
5.0
85.0
insign.
V
NV
V
V
NV
90 90
NV
V
V
V
'Gosselin (1984)
                                     -61-

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                    OTHER PERSONAL CARE PRODUCTS - AEROSOLS
U.S.
Annual Unit
Distribution
(millions)

152
Average
Unit Weight
(Ib/unit)

.133
Population
Apportionment

.11 (CA)4
.046 (NY)
.033 (NJ)
Seasonal
Variation

1.0/0.0
Geographic
Multiplier
Sun tan lotions
1.16 (CA)5
1.06 (NY)5
1.06 (NJ)5
                                                   1.08  (NJ)'
                                                               Depilatories

                                                               1.03  (CA)5
                                                               1.08  (NY)5
 :Suntan lotions and depilatories are  combined  in units distributed.  Until
 better data become available, we  assume  80  percent of sales are suntan
 products and 20 percent depilatories (11 million units suntan products,  2.7
 million depilatories).

 2CSMA (1984); estimated millions of units filled in 1984

 3WAIB (1981)

 4U.S. Bureau of the Census  (1986)

 5Simmons (1983)
                                     -62-

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B/834-025-68b/#A
                     OTHER PERSONAL CARE PRODUCTS  FORMULAS
                                Percent
                                By Weight
                                           Volatility
                      VOC        PROC
                      Emitted(%) Emitted(%)
Depilatories

Formulation 1

Thioglycolate (calcium or
  ammonium)
Hydroxide (calcium or sodium)
Emulsifiers, humectants, waxes
Demineralized water
Propane/butane
 Formulation 2
                   light
Calcium  carbonate,
Calcium  hydroxide
Calcium  thioglycolate
  trihydrate
Cetyl alcohol,  flakes
Perfume
Sodium lauryl sulfate
Sodium silicate solution
Distilled or deionized water
Propellant:   Butane/propane

Suntan Lotions

Formulation  1

Water
Fats, oils,  waxes
Emulsifiers
Humectants
Preservatives
Essential oil (fragrance)
Sunscreen agent

Formulation  2

Monoglyceryl p-aminobenzoate
Mineral  oil
Sorbitan monostearate
Polyoxyethylene sorbitan
  monostearate
Demineralized water
                                  5-10
                                  2-6
                                  0.1-1
                                  up to 100
                                  up to 10
0-21
0-1.5

2.2-6
0-4.5
0-0.5
0-0.5
0-3.5
up to 100
10
                                   >50
                                   10-25
                                   1-10
                                   0-10
                                   0.1-1
                                   0.1-1
                                   1-5
                                   3.0
                                   25.0
                                   4.0

                                   6.0
                                   62.0
                                                           10.0
                                    10.0
               NV
               NV
                V
                                                           10.5
                                    10.5
                                                  NV
                                                  NV
                                                   V
                                                  NV
                                                           0.1-1.0
                                   0.1-1.0
               NV
               NV
               NV
               NV
                V
               NV
               NV
               NV
               NV

               NV
                                                            0.0
                                     0.0
                                      -63-

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               OTHER PERSONAL CARE PRODUCTS FORMULAS  (Continued)
                                Percent                 VOC         PROC
                                By Weight   Volatility  Emitted^)  EmittedU)
Formulation 3

Oils (e.g., mineral)                >50
Emollient                           1-10
Thickeners                          1-10
Sunscreen agent                     1-5
Preservatives                       0.1-1
Color                               0.1-1
Essential oil (fragrance)           0.1-1

Formulation 4

Methyl anthranilate                 5.0
Propylene glycol rinicoleate        10.0
Glycerol                            10.0
Alcohol                             65.0
Water                               10.0

Formulation 5

2-Ethyl hexyl salicylate            5.0
Sesame oil                          40.0
Mineral oil                         55.0
NV
NV
NV
NV
NV
NV
 V
NV
NV
NV
 V
        0.1-1.0
0.1-1.0
         65.0
  65.0
         0.0
   0.0
NV
NV
NV
                                      -64-

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                AUTOMOTIVE CLEANERS - AEROSOLS AND NONAEROSOLS
U.S.
Annual Unit
Distribution
(millions)
14. 71


Average
Unit Weight
(Ib/unit)
.8752


Population
Apportionment
.11 (CA)3
.046 (NY)
.031 (NJ)
Geographic
Multiplier
NA


      (1985)



 2WAIB (1981)



 3U.S. Bureau of the Census (1986)
                                     -65-

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                 AUTOMOTIVE CLEANERS - AEROSOL AND NONAEROSOL*
                                Percent                 VOC          PROC
                                By Weight  Volatility   Emitted(%)   Emitted(%)


Formula 1                                                  9.0          9.0

  Water                                67%
  Anionic and Nonionic surfactants     22%          NV
  Isopropanol                          8%           V
  Glycol ether                         1%           V
  Borax                                1%
  Thickener                            1%

Formula 2                                                  23.0         23.0

  Inorganic polishing agents           42%
  Water                                25%
  Petroleum distillates                23%           V
  Vegetable oils                       5%          NV
  Detergents                           5%          NV

Formula 3                                                  60.0         60.0

  Petroleum napthas                50-60%           V
  o-Benzyl-p-chlorophenol              .1%          NV
  Petroleum and synthetic  waxes    40-50%          NV

Formula 4                                                  0.0          0.0

  Alkyl aryl sodium  sulfonate          40%          NV
  Sodium sulfate                       60%

Formula 5                                                  2.0          2.0

  Sodium dodecylbenzene  sulfonate
     (alkyl aryl sodium sulfonate) 40-100%          NV
  Sodium sulfate                   15-25%
Alkyl diethanolamine
Nonionic detergents
Formula 6
Dodecyl benzene sulfonate
Coconut oil amine
Water
Formula 7
Oxalic acid
Boric acid
2%
10-15%

6%
2%
92%

40%
60%
V
NV
0.0
NV
NV
-
0.0
—
"


0.0



0.0


 'Gosselin  (1984)


                                      -66-

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                                                       a
           AUTOMOTIVE CLEANERS - AEROSOL AND NONAEROSOL* (Continued)



                                Percent                 VOC         PROC
                                By Weight  Volatility   Emitted(%)  Emitted(Z)


Formula 8                                                100.0       100.0

  Petroleum ethers                   100%           V


*Gosselin (1984)
                                      -67-

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                   AUTOMOTIVE ENGINE DEGREASERS - AEROSOLS
U.S.
Annual Unit
Distribution
(millions)
23. 91


Average
Unit Weight
(Ib/unit)
.8752


Population
Apportionment
.11 (CA)3
.046 (NY)
.031 (NJ)
Geographic
Multiplier
NA


:CSMA (1984); estimated millions of units filled in 1984



2WAIB (1981)



3U.S. Bureau of the Census  (1986)
                                     -68-

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                         ENGINE DEGREASER FORMULATIONS
                                 Percent                VOC          PROC
                                 By Weight  Volatility  Emitted(%)  Emitted(%)
Formulation 1*

  Ethylene dichloride                   63
    (Other chlorinated hydro-
    carbons may be substituted,
    such as o-dichlorobenzene,
    dichloropentane, methylene
    dichloride, 1,1,1-
    trichloroethylene)
  Cresol (low-boiling cresylic          25
    acids may be substituted)
  Oleic acid                           7.2
  Potassium (or sodium) hydroxide      1.4
  Water                                3.0
This formulation equals 90% by weight
  Butane Propellant*                   10%

Formulation 2a

  Methylene chloride                  0.25
  Perchloroethylene                   5-60
  Stoddard solvent                   40-70
  Butane Propellant*                    10

Formulation 3

  Perchloroethylene                   0-60
  Trichloroethane                     0-60
  Methylene chloride                  0-25
  Petroleum solvents                 40-70
  Chlor-aromatic solvents  (see       0-100
    o-dichlorobenzene, chlorinated
    naphthalenes)
  Detergent                          trace
  Emulsifier                         trace
  Butane Propellant*                    10
         89.2
    89.2
 V
 V

NV



 V
V
V
V
V
V
V
V
V
V
NV
NV
 V
        100.0
    99.8
        100.0
75.0-100.0
 *Estimated from WAIB  (1981) and CSMA  (1986)
 'Gosselin (1984)
                                     -69-

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              LUBRICANTS AND  SILICONES  - AEROSOL AND NONAEROSOL
u.s«.
Annual Unit
Distribution
(millions)
75. A1


Average
Unit Weight
(Ib/unit)
.442


Population
Apportionment
.11 (CA)3
.046 (NY)
.031 (NJ)
Geographic
Multiplier
NA


      (1984); estimated millions of units filled in 1984



2Averaged from data in WAIB (1981)



3U.S. Bureau of the Census (1986)
                                     -70-

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               LUBRICANTS AND SILICONES - AEROSOL AND NONAEROSOL
                                Percent                 VOC         PROC
                                By Weight  Volatility   Emitted(%)  Emitted(%)


Formula 1*                                                 0.0         0.0

  Mineral oils                    85-100%        NV
  Cl.SP compounds                   0-10%        NV
  Isobutylene polymers               0-5%        NV


Formula 2a                                               100.00      100.00

  Colloidal graphite dispersion in
    aliphatic naptha                   5%         V
  Oxygentated organic acids           20%         V
  Naptha (aliphatic)                  65%         V
  Tricresyl phosphate                 10%         V
  Nonylphenoxy acetic acid          trace         V


'Gosselin (1984)
                                     -71-

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                            UNDERCOATING -  AEROSOLS
U.S.
Annual Unit
Distribution
(millions)
8.31


Average
Unit Weight
(Ib/unit)
.752


Population
Apportionment
.11 (CA)3
.046 (NY)
.031 (NJ)
Geographic
Multiplier
NA


      (1984); estimated millions of units filled in 1984
 2WAIB (1981)



 3U.S. Bureau of the Census  (1986)
                                     -72-

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                             UNDERCOATING FORMULAS
                               Percent                  VOC        PROC
                               By Weight  Volatility  Emitted^)  Emitted(%)
Formulation 1
25-85
25-85
Pigment (15-50%)
Iron oxide
Silicates
Lead or lead salts
Zinc and zinc salts
May contain:
Titanium dioxide
Vehicle (50-85%)
Alkyd resin
Phenolic resin
Fish oil
Vegetable oil
Aromatic hydrocarbons
Aliphatic hydrocarbons1

0-50
0-50
0-50
0-50

0-50

0-50
0-50
0-25
0-25
0-50
0-50

_
_
_
_

—

NV
NV
NV
NV
V
V
 'Gosselin (1984)

 1Assumes that at least 50 percent of vehicat consists of aromatic or aliphtic
 hydrocarbons
                                     -73-

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                           BRAKE CLEANERS - AEROSOLS
U.S.
Annual Unit
Distribution
(millions)
16. 61


Average
Unit Weight
(Ib/unit)
1.132


Population
Apportionment
.11 (CA)3
.046 (NY)
.031 (NJ)
Geographic
Multiplier
NA


      (1984); estimated millions of units filled in 1984
 2WAIB (1981)
 3U.S. Bureau of the Census  (1986)
                                     -74-

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              AUTOMOTIVE BRAKE CLEANERS - AEROSOL AND NONAEROSOL*



                                Percent                 VOC         PROC
                                By Weight  Volatility   Emitted(%)  Emitted(%)


Formula 1                                                 100.0       100.0

  Methyl alcohol                     100%       V

Formula 2                                                 100.0       100.0

  Ethyl alcohol                      100%       V

Formula 3                                                 100.0       100.0

  Isopropyl alcohol                  100%       V


"Gosselin (1984)
                                      -75-

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                     TIRE INFLATOR AND SEALANT - AEROSOLS
U.S.
Annual Unit
Distribution
(millions)
19.3


Average
Unit Weight
(Ib/unit)
.692


Population
Apportionment
.11 (CA)3
.46 (NY)
.031 (NJ)
Geographic
Multiplier
NA


      (1985); estimated millions of units sold in 1984



 2WAIB (1981)



 3U.S. Bureau of the Census  (1986)
                                     -76-

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                    CARBURETOR AND CHOKE CLEANER - AEROSOLS
U.S.
Annual Unit
Distribution
(millions)
39. 81


Average
Unit Weight
(Ib/unit)
.752


Population
Apportionment
.11 (CA)3
.047 (NY)
.031 (NJ)
Geographic
Multiplier
NA


      (1984); estimated millions of units filled in 1984



 2WAIB (1981)



 3U.S. Bureau of  the Census  (1986)
                                      -77-

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                          CARBURETOR CLEANER FORMULAS
                                  Percent                VOC        PROC
                                  By Weight  Volatility  Emitted(%) Emitted(%)
Formulation la

  Ethylene dichloride
    (Other chlorinated hydro-
    carbons may be substituted,
    such as o-dichlorobenzene,
    dichloropentane, and
    raethylene dichloride)
  Cresol (low-boiling cresylic
    acids may be substituted)
  Oleic acid
  Potassium hydroxide (sodium
    hydroxide)
  Water
  Butane propellant*

Formulation 2a

  Aliphatic or Aromatic hydro-
    carbons with oil soluble
    wetting agents
  Butane*

Formulation 3a
56.2
22.3

 6.4

 1.2
 3.0
10.7
  88
  12
 Gosselin (1984)

*Estimated from WAIB  (1981) and CSMA  (1986)
                    66.9
                66.9
 V
NV

NV



 V
                      100.0
                  100.0
 V
 V
                     28.0-72.0  28.0-72.0
Tall Oil
Cresol
Potassium Hydroxide
Ethylene dichloride
Sodium chromate
Ammonium oxalate
Alcohol
Water
Butane*
5-18
10-25
1-4
15-50
.5-5
.3-3
1-10
10-40
12
NV
NV
-
V
-
NV
V
-
V
                                     -78-

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                       ENGINE STARTING FLUIDS  -  AEROSOLS
U.S.
Annual Unit
Distribution
(millions)
30. 81


Average
Unit Weight
(Ib/unit)
.562


Population
Apportionment
.11 (CA)3
.046 (NY)
.031 (NJ)
Geographic
Multiplier
NA


      (1984); estimated millions of units filled in 1984
 2WAIB (1981)



 3U.S. Bureau of  the Census  (1986)
                                      -79-

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              AUTOMOTIVE STARTING FLUIDS - AEROSOL AND NONAEROSOL*



                                 Percent                 VOC         PROC
                                 By Weight  Volatility   Emitted(%)  Emitted(%)


Formula 1                                                100.0       100.0

  Ethyl Ether                        100%         V


'Gosselin (1984)
                                      -80-

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B/834-025-68b/f4

                    AUTO WINDSHIELD WASHER FLUID AND DEICER
            U.S.          Average
        Annual Unit     Unit Weight      Population        Geographic
        Distribution     (Ib/unit)      Apportionment      Multiplier
         (millions)
Windshield Washer Fluid
           NA              NA              ,11 (CA)3            NA
                                           .046 (NY)
                                           .031 (NJ)
Windshield Deicer
           10. 41            I2              .11 (CA)3            NA
                                           .046 (NY)
                                           .031 (NJ)
      (1985)
 2WAIB (1981)
 3U.S. Bureau of  the  Census  (1986)
                                      -81-

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                       AUTO WINDSHIELD DEICER FORMULATION
Percent
By Weight Volatility
Formula 1
Isopropyl alcohol
Ethylene glycol
Water
Propellant, C02
Formula 2b
Isopropanol
Isobutone propellant
Formula 3b
Isopropanol
Ethylene glycol
Water
Fropellant, C02
Formula 4
Isopropanol
N-propanol, propyleneglycol,
ethylene glycol
Water

25
50
25


90-95
5-10

23.8
47.5
23.8
5.0

30-100

15-30
5-15

V
V
_
V

V
V

V
V
-


V

V
"~
VOC PROC
Emitted(X) Emitted(%)
75.0 75.0




100.00 100.00


76.3 71.3




95.0 95.0




 'Chalmers and  Bathe  (1979)
 'Gosselin (1984)
                                     -82-

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               HERBICIDES AND FUNGICIDES -  AEROSOL AND NONAEROSOL
       National Consumption       Population          Geographic
          (million Ib)           Apportionment        Multiplier
              692                   .ll(CA)3             NA

                                    .047(NY)
                                    .031(NJ)
       (1981)

 2U.S. Bureau of  the Census  (1986)
                                      -83-

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              HERBICIDES AND FUNGICIDES - AEROSOL AND NONAEROSOL*
                                Percent                 VOC         PROC
                                By Weight  Volatility   Emitted(%)  Emitted(%)


Herbicides

Formula 1                                                 95.0        95.0

  Aromatic hydrocarbons
    (primarily xylenes)               95%        V
  Inert ingredients                    5%       NV

Formula 2                                                 59.2        59.2

  Bromocil                          40.8%
  Inert ingredients                 39.2%
    (including an ethanol amine)

Formula 3                                                  0.0         0.0

  Bromocil                             4%       NV
  Granular mineral base               96%       NV

Formula 4                                                 30.0         3.0

  Monuron                          17.69%       NV
  Trichloracetate acid             14.56%       NV
  Aromatic petroleum solvent       20-30%        V
  Dodecylbenzene sulfonic acid,
    corrosion inhibitor, and
    inert ingredients              35-45%       NV

Formula 5                                                 22.0        22.0

  4-amino-3,5,6-trichloropicolinic
    acid, isoctyl esters            15.1%       NV
  2,4,5-trichlorophenoxyacetic
    acid, propylene glycol butyl
    ether esters                    63.4%       NV
  Inert ingredients (aromatic
    petroleum solvent, methanol)  0-21.5%        V

Formula 6                                                 80.0         8.0

  Urox liquid oil concentrate      18-20%       NV
  Heavy aromatic naptha            80-82%        V
"Gosselin  (1984)
                                     -84-

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         HERBICIDES AND FUNGICIDES - AEROSOL AND NONAEROSOL  (Continued)
                                Percent                 VOC         PROC
                                By Weight  Volatility   Emitted(%)  Emitted(%)


Formula 7                                                  0.0         0.0

  4-amino-3,5,6-trichloropicolinic
    acid, potassium salt             2.3%       NV
  Disodium tetraborate pentahydrate 79.2%
  Disodium tetraborate decahydrate  16.5%


Formula 8                                                 38.0        38.0

  Picloram,  isooctyl  esters         62.4%       NV
  Heavy aromatic naptha,  methanol 0-37.6%        V

Formula 9                                                  0.0         0.0

  Sodium metaborate tetrahydrate       68%
  Sodium chlorate                      30%
  Inert ingredients                    2%       NV


Formula 10                                                 0.0         0.0

  Sodium metaborate tetrahydrate    66.5%
  Sodium chlorate                      30%
  Bromacil                           1.5%       NV
  Inert ingredients                    2%       NV

Formula 11                                                93.0        93.0

  Aliphatic  petroleum distillates  83.27%        V
  Xylene                            9.65%        V
  2,4-Bis(isopropylamino)-6-
    methoxy-5-triazine                .86%       NV
  Inert ingredients                 6.22%       NV


Fungicides

Formula 12                                                 0.0

  Copper sulfate                       50%
  Lime                                 50%
 "Gosselin  (1984)
                                      -85-

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         HERBICIDES AND FUNGICIDES- AEROSOL AND NONAEROSOL (Continued)
                                Percent                 VOC         PROC
                                By Weight  Volatility   Emitted(%)  Emitted(X)


Formula 13                                                30.0        30.0

  Copper                               8%
  Copper naphthenate               70-80%       NV
  Petroleum distillate             20-30%        V

Formula 14                                                45.0        45.0

  Zinc naphthenate                 55-60%       NV
  Petroleum distillate             40-45%        V
  Zinc                                 8%


aGosselin  (1984)
                                     -86-

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A/834-025-68b/t5
               HOUSEHOLD POLISH FORMULATIONS -  AEROSOL AND LIQUID
Percent VOC PROC
By Weight Volatility Emitted(£) Eraitted(%)
Liquids
Formula 1
Hard waxes
Microcrystalline wax
Silicone fluid
Naphtha or turpentine
Formula 2
Hard waxes
Microcrystalline wax
Silicone fluid
Naphtha or turpentine
Formula 3
Carnauba wax
Beeswax
Microcrystalline wax
White spirit or naptha
Stearic acid
Triethanolamine
Water
Formula 4
Carnauba wax
Beeswax
Microcrystalline wax
White spirit or naptha
Stearic acid
2-Amino-2 methyl-propanol
Water
Formula 5
Hoechst Wax 0
Ceresin
Silicone fluid 220/350 cS
Span 80
White spirit: turpentine 1:1
Deionized water
Perfume


13
8
9
70

3
1
2
94

4.2
2.2
.7
24.0
2.5
1.7
64.7

5.00
1.76
.70
24.00
2.81
1.76
63.97

2.0
1.5
2.5
1.5
28.5
64.0
q.s.


NV
NV
NV
V

NV
NV
NV
V

NV
NV
NV
V
NV
NV
-

NV
NV
NV
V
NV
V
-

NV
NV
NV
NV
V
-
V

70.0 70.0




94.0 94.0




24.0 24.0







25.76 25.76







28.5 28.5







                                     -87-

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A/834-025-68b/t5
                   HOUSEHOLD POLISH FORMULATIONS (Continued)
                                Percent
                                By Weight
Volatility
VOC
Emitted(%)
PROC
Emitted(%)
Formula 6
                37.0
              37.0
Hoechst Wax
Oleic acid
Morpholine
White spirit
Silicone oil 350 cS
Silicone oil 10 000 cS
Deionized water
Perfume
8.0
1.3
1.0
36,0
1.5
2.0
50.2
q.s.
NV
NV
V
V
NV
NV
—
V
 *Kline  (1982)
                                      -88-

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                     FLOOR POLISHES AND VAXES - NONAEROSOL
     National Consumption        Population        Geographic
        (million Ib)            Apportionment      Multiplier


           271                   .11  (CA)2          1.04 (CA)3

                                 .046  (NY)          1.02 (NY, NJ)

                                 .031  (NJ)


        (1982)

2U.S. Bureau of  the Census  (1986)

3 Simmons  (1983)
                                      -89-

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                 FLOOR WAX AND POLISH  FORMULATIONS - NONAEROSOL
Percent
By Weight Volatility
Formula 1*
Rhoplex B 38%-a
Polyethylene, 40%
Diethylene glycol
monomethylether
ACRYSOL leveling aid, 42%
Tributoxyethyl phosphate
Dibutyl phthalate
Formalin, 37%
Wetting agent, 1%
Silicone defoamer
Water or inorganic base to 100%
Formula 2a
Rhoplex B 38%-a
Polyethylene, 40%
Diethylene glycol
monomethylether
ACRYSOL leveling aid, 42%
Anionic surfactant, 35%
Tributoxyethyl phosphate
Formalin, 37%
Wetting agent, 1%
Silicone defoamer
Water or inorganic base to 100%
Formula 3a
Rhoplex B 38%0a
POLYETHYLENE, 40%
Diethylene glycol
monome thyle ther
ACRYSOL leveling aid, 42%
Tributoxyethyl phosphate
Formalin, 37%
Wetting agent, 1%
Silicone defoamer
Water or inorganic base to 100%

31.58
5.63

4.00
1.79
1.00
1.00
0.15
0.40
0.01


37.89
6.75

2.40
2.14
1.43
1.20
0.15
0.60
0.02


64.74
11.25

6.00
2.14
1.37
0.15
0.72
0.03


NV
NV

NV
NV
NV
NV
V
NV
NV


NV
NV

NV
NV
NV
NV
V
NV
-


NV
NV

NV
NV
NV
V
NV
-

VOC PROC
Emitted(%) Emitted(%)
0.2 0.2











0.2 0.2











0.2 0.2










'Chalmers and Bathe (1979)
                                     -90-

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A/834-025-68b/#5


                   METAL CLEANERS AND POLISHES - NONAEROSOL
     National Consumption          Population            Geographic
       (millions Ib)              Apportionment          Multiplier


            241                      .11 (CA)2                 NA

                                     .046 (NY)

                                     .031 (NJ)


lKline (1982)

2U.S. Bureau of  the Census  (1986)
                                      -91-

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A/834-025-68b/#5
                METAL CLEANER AND POLISH FORMULAS - NONAEROSOLS
                                 Percent
                                By Weight  Volatility
VOC         PROC
Emitted(%)  Emitted(%)
Formula la
Abrasive
Soap or synthetic surfactants
Thickening agent
Ethyl or isopropyl alcohol
Water, to make
Formula 2"
Dithio-bis-stearyl propionate
Abrasive
Surfactant
Preservative
Water, to make
Formula 3b
Sulfamic, citric, tartaric acid
Sodium chloride
Anionic synthetic surfactant
Siliceous abrasive
Formula Ab
Caustic soda or potash
(see alkali)
Trisodium phosphate
Sodium metasilicate
Soap or detergent (alkly aryl
sodium sulfonate)
Formula 5
Perchloroethylene
Trichloroethylene
1,1, 1-Trichloroethane
Formula 6b
Kerosene
Potassium soap of oleic acid
Glycol ether
Surfactant

5-35
5-7
.5-1
2-5
100%

5.0
20.0
6.0
0.1
100.0

5-10
5-10
1-3
to 100


0-50
25-75
10-75

5-20

1-100
1-100
1-100

5-80
5-25
5-20
5-20

NV
NV
NV
_


NV
NV
NV
NV
-

NV
-
NV
-


-
-
-

NV

V
V
V

V
NV
V
NV
2.0-5.0 2.0-5.0





0.0 0.0





0.0 0.0




0.0 0.0






100.0 1.0-100.0



55.0-90.0 55.0-90.0




                                     -92-

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A/834-025-68b/#5
          METAL CLEANER AND POLISH FORMULAS - NONAEROSOLS (Continued)
                                 Percent
                                By Weight  Volatility
                    VOC        PROC
                  Eraitted(%)  Eraitted(%)
Formula 7b
Hydrochloric acid or one or
more of  the following!

   Sulfuric acid
   Chromic acid
   Phosphoric  acid
   Citric acid

Surfactant
5-25
5-20
10-25
10-25

5-10
                     0.0
                     0.0
NV
 "Kline  (1982)

 "Gosselin  (1985)
                                     -93-

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A/834-025-68b/#5

                      AUTOMOTIVE ANTIFREEZES - NONAEROSOL
     National Consumption          Population            Geographic
        (million Ib)              Apportionment          Multiplier

            22. 31                    .11  (CA)2               NA
                                     .046  (NY)
                                     .031  (NJ)
       (1983)
 2U.S.  Bureau  of  the  Census  (1986)
                                      -94-

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A/834-025-68b/#5


                         AUTOMOTIVE ANTIFREEZE FORMULAS
                                 Percent                  VOC        PROC
                                By Weight  Volatility   Emitted(2)  Emitted(X)


Formula la                                                    95.0      95.0

Glycols (95% monoethylene glycol,     95            V
  5% kiethylene glycol)
Alkali metal borates  and phosphates   2-3
Water                                 2-3
Dye                                   trace         V


"Gosselin  (1985)
                                      -95-

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A/834-025-68b/#5






                     CAR POLISHES AND VAXES - NONAEROSOLS
U.S.
Annual Unit
Distribution
(millions)
189. I1
Average
Unit Weight
(Ib/unit)
I2
Population
Apportionment
.11 (CA)3
.046 (NY)
.031 (NJ)
Geographic
Multiplier
1.05 (CA)4
.90 (NY)
.90 (NJ)
 Calculated  from  Simmons  (1983)
 2Based on a  shelf  survey  of  several different brands and formulations



 3U.S. Bureau of  the  Census  (1986)
 4 Simmons  (1983)
                                      -96-

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A/834-025-68b/tt5
                              CAR WAX FORMULATIONS
                               Percent
                              Composition
                               by Weight
        VOC         PROC
      Volatibility Emitted(X)   Emitted(%)
Formula la

  Carnauba wax
  Beeswax
  White spirit or naptha
  Stearic acid
  Triethanolamine
  Water
 5.1
 4.5
42.4
 4.0
 1.5
42.5
NV
NV
 V
NV
NV
                      42.4
                      42.4
Formula  2

  Carnauba wax
  Beeswax
  Ceresin
  White  spirit  or  naptha
  Triethanolamine
  Stearic acid
  Water
                      42.3
                      42.3
 5.00
 2.00
 2.00
40.00
 2.25
 4.00
44,75
NV
NV
NV
 V
 V
NV
 "Chalmers  and  Bathe (1979)
                                      -97-

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B/834-025-68a/#15
                                 APPENDIX B

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                                  REFERENCES


Broxterman, W.  1983.   "Worldwide  Challenges and Opportunities," Chemical Week
(March 2).                                                      	

CSMA (Chemical  Specialty  Manufacturers Association, Inc).  1984.  Pressurized
Products Survey, United States  1984.                              	

Dictionary of Organic  Compounds,  5th  ed.   1982

Etheridge, M.   1986.   Personal  communication  from Bureau of Alcohol, Tobacco
and Firearms, Washington,  D.C.  (February).

Federal Register.  48 FR 49097.  October 24, 1983.

Gosselin, R.E,  R.P. Smith,  and  B.C. Hodge  (Eds.).  1984.  Chemical Toxicology
of Commercial Products, 5th ed. Williams and  Wilkins, Inc., Baltimore,
Maryland.

Hass, H.B. and  R.F. Newton.   1981.  "Correction of Boiling Points to Standard
Pressure." In R.C. Weast  and M.J. Astle (Eds.), CRC Handbook of Chemistry and
Physics, CRC Press, Inc.,  Boca  Raton, Florida.

Kirk-Othmer.  1978.  Encyclopedia of  Chemical Technology 3rd ed.  Wiley and
Sons, New York.

Kline and Co.,  C.H.  1981.   Consumer  Pesticides and Fertilizers, Fairfield,
New Jersey.

Kline and Co.,  C.H.  1982.   Household Cleansing Products, Fairfield, New
Jersey.

Micromedex, Inc.   1984.   Poisindex, Colorado.

Nowak, F., P.L. Bartlett,  and J.J. Daly, Jr.  1985.  "Dimethyl Ether:  An
Alternative Propellant for Aerosol Hair Sprays," Aerosol Age, April.

Predicasts, Inc. (PTS  U.S.  Time Series) 1984.  Cleveland, Ohio.

Rogozen, M., R. Rapoport,  and A.  Shocket.  1985.  Development and Improvement
of Organic Compound Emission Inventories for  California.Prepared by Science
Applications International Corporation for California Air Resources Board,
Sacramento, California.

Simmons Market  Research Bureau, Inc.  1983.   Simmons 1983 Study of Media and
Markets.

Stratte, J.J.,  P.W. Dillon,  and R.H.  Semp.  1978.  "Evaporation of Organic
Co-solvents from Water-borne Formulations:  Theory, Experimental Study,
Computer Simulation,"  Journal of  Coating Technology 50(647):39-47.

U.S.  Bureau of  the Census,  U.S. Department of Commerce.  1986.  Personal
Communication with the Office of  Population Estimates.

-------
U.S. Bureau of the Census, U.S. Department of Commerce.  1982.  Census of
Manufacturers.

USEPA (U.S. Environmental Protection Agency).  1979.  Toxic Substances
Control Act Chemical Substances Inventory. Vols. II, III"!  Office of Toxic
Substances, Washington, D.C.

USEPA (U.S. Environmental Protection Agency).  1980.  Toxic Substances
Control Act Chemical Substances Inventory, Cumulative Supplement Officer of
Toxic Substances, Washington, D.C.

USEPA (U.S. Environmental Protection Agency).  Volatile Organic Compound
(VOC) Species Data Manual, 2nd ed.  Office of Air Quality Planning and
Standards, Research Triangle Park, North Carolina.

Verschueren, D.   1977.  Handbook of Environmental Data on Organic Chemicals.
Van Nostrand Reinhold Co., New York.

WAIB (Western Aerosol Information Bureau).   1982.  Prepared by Public
Relations Committee, Shashir, L., P. Robinson, D. Vehagen, T. Donaldson, and
W. Lim.  Analysis of Pressurized Products Relative to Hydrocarbon Propellants
and Other Volatile Organic Compounds.

Warnick, H. 1986.  Deputy Branch Chief, Office of Pesticide Programs, U.S.
Environmental Protection Agency  (11 June).

Weast, R.C., and  M.J. Astle  (Eds).  1981.  CRC Handbook of Chemistry and
Physics.  CRC Press, Inc., Boca Raton, Florida.

Wennigen, J.  1986.  Personal communication  from Bureau of Alcohol, Tabacco
and Firearms, Washington, D.C.  (February).

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                                    TECHNICAL REPORT DATA
                            I Please read Ins true nons an thu revene befon completing)
1. REPORT NO.
  EPA 902/4-86-001
              3. RECIPIENT'S ACCESSION NO.
 TITLE AND SUBTITLE
  Photochemically Reactive Organic Compound Emissions
  From Consumer  and Commercial  Products
                                                             5. REPORT DATE
                                                                   November.  1986
              6. PERFORMING ORGANIZATION CODE
7. AUTMQR(S)
  Jones, Alan;  Rich, Harvey;  Sewell,  Granville;
  Rogozen, Michael;  Katz, Michael
              8. PERFORMING ORGANIZATION REPORT NO.
8. PERFORMING ORGANIZATION NAME AND ADDRESS
  SCIENCE APPLICATIONS INTERNATIONAL CORPORATION
  8400 Westpark Drive
  McLean, VA    22102
              10. PROGRAM ELEMENT NO.
              11. CONTRACT/GRANT NO.

                    68-02-3893
 12. SPONSORING AGENCY NAME ANO ADDRESS

  U.S. Environmental Protection Agency, Region  II
  Air Programs Branch
  26 Federal Plaza
  New York.  NY   10278	
              13. TYPE OF REPORT ANO PERIOD COVERED
              	Final         	
              14. SPONSORING AGENCY CODE
 15. SUPPLEMENTARY NOTES
  Project Officer:  Paul Truchan (212) 264-2518
 18. ABSTRACT
       This report  estimates  the emissions  of volatile  organic compounds  (VOC)
       and  photochemically  reactive  organic  compounds  (PROC)  released  from
       the use of  consumer products  in the States  of California and New Jersey,
       and  the  New  York  City  metropolitan  area.   The  report  describes  the
       data sources and  methodologies  that  were  used to  estimate  VOC  and PROC
       emissions  from consumer  products, and presents emission  estimates broken
       down by consumer  product subcategory  and geographic region.
                                 KEY WORDS AND DOCUMENT ANALYSIS
                  DESCRIPTORS
b. IDENTIFIERS/OPEN ENDED TERMS  C. COSATI Field/Group
   Air Pollution
   Volatile  Organic Compounds
   Consumer  and Commercial  Products
   Photochemical Oxidants
   New Jersey
   New York
   California
 *• DISTRIBUTION STATEMENT
  .Release Unlimited
19. SECURITY CLASS iThts Report)
   Unclassified	
21. NO. OF PAGES
20 SECURITY CLASS iTha paget

  Unclassified	
                                                                           22. PRICE
   Farm 2220-1 (R»»- 4-77)    previous  COITION i $ oasouerc

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