SEPA
United States
Environmental Protection
Agency
Region II Office
26 Federal Plaza
New York, N.Y. 10007
EPA 902/4-86-001
November 1986
Air
PHOTOCHEMICALLY
REACTIVE ORGANIC
COMPOUND EMISSIONS
FROM CONSUMER AND
COMMERCIAL PRODUCTS
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PHOTOCHEMICALLY REACTIVE ORGANIC COMPOUND
EMISSIONS FROM CONSUMER AND
COMMERCIAL PRODUCTS
FINAL REPORT
November 26, 1986
Submitted To:
Paul Truchan, Project Officer
U.S. Environmental Protection Agency
Air Programs Branch
26 Federal Plaza
New York, Nev York 10278
Submitted By:
Science Applications International Corporation
8400 Westpark Drive
McLean, VA 22102
Alan Jones
Harvey Rich
Granville Sewell
Michael Rogozen
Michael Katz
EPA Contract No. 68-02-3893, Work Assignment No. 8
SAIC Project No. 2-834-07-025-68
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This air pollution report is issued by Region II, U.S. Environmental
Protection Agency to assist State and local air pollution control agencies in
carrying out their program activities. Copies of this report may be obtained
for a nominal cost, from the National Technical Information Service, 5285 Port
Royal Road, Springfield, VA 22151.
This report was furnished to the Environmental Protection Agency by
Science Applications International Corporation, 8400 Westpark Drive, McLean,
VA 22102, in fulfillment of EPA Contract No. 68-02-3893. This report has been
reviewed by Region II, EPA, and approved for publication. Approval does not
signify that the contents necessarily reflect the views and policies of EPA,
nor does mention of trade names or commercial products constitute endorsement
or recommendations for use.
EPA Region II Publication No. 902/4-86-001
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TABLE OF CONTENTS
Page
1. INTRODUCTION 1-1
2. DEFINITION OF TERMS 2-1
3. TECHNICAL APPROACH 3-1
3.1 DESCRIPTION OF SOURCES 3-1
3.2 METHODOLOGY 3-2
4. UNCERTAINTIES/DATA GAPS 4-1
5. RESULTS 5-1
6. CONCLUSIONS 6-1
APPENDIX A - CONSUMER PRODUCT FORMULAS AND CONSUMPTION
APPENDIX B - REFERENCES
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LIST OF TABLES
Table Page
1 AVAILABILITY OF DATA BY PRODUCT SUBCATEGORY 4-5
2 RELATIVE EVAPORATION RATES - ALPHABETICAL 5-3
3 RELATIVE EVAPORATION RATES - NUMERICAL 5-10
4 VOC AND PROC EMISSIONS IN CALIFORNIA 5-18
5 VOC AND PROC EMISSIONS IN NEW JERSEY 5-25
6 VOC AND PROC EMISSIONS IN NEW YORK 5-33
7 CONSUMER PRODUCT SUBCATEGORIES RANKED IN ORDER OF LOW
TOTAL PROC EMISSIONS 6-6
8 CONSUMER PRODUCT SUBCATEGORIES RANKED IN ORDER OF HIGH
TOTAL PROC EMISSIONS 6-9
9 CONSUMER PRODUCT SUBCATEGORIES RANKED IN ORDER OF AVERAGE
TOTAL PROC EMISSIONS 6-12
10 VOC AND PROC RATIOS FOR PRODUCT CATEGORIES IN CALIFORNIA 6-15
11 VOC AND PROC RATIOS FOR PRODUCT CATEGORIES IN NEW YORK 6-16
12 VOC AND PROC RATIOS FOR PRODUCT CATEGORIES IN NEW JERSEY 6-17
13 VOC AND PROC EMISSIONS IN CALIFORNIA 6-18
14 PER CAPITA AVERAGE VOC AND PROC EMISSIONS (LB/PERSON) 6-19
15 PER CAPITA LOW VOC AND PROC EMISSIONS (LB/PERSON) 6-20
16 PER CAPITA HIGH VOC AND PROC EMISSIONS (LB/PERSON) 6-20
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1. INTRODUCTION
Pursuant to the Clean Air Act, States are required to attain the Federal
ambient ozone standard by 1987. EPA has found that the formation of oxidants
(e.g., ozone) is directly related to the emission of photochemically reactive
organic compounds (PROCs). Therefore, EPA and the States have initiated
control programs to reduce PROC emissions to meet the Federal ozone standard.
Organic compounds with high vapor pressures volatilize easily and are known as
volatile organic compounds (VOCs). Photoreactive organic compounds (PROCs), a
subset of VOCs, are chemically reactive in sunlight. Although substantial
controls on PROCs are in effect, parts of California, New Jersey, and New York
will not be able to attain the ozone standard unless further PROC emission
reductions occur. Preliminary emission estimates indicate that consumer and
commercial products represent a significant contribution to the uncontrolled
release of PROC. This study was undertaken to determine whether there was
potential for emission reductions from the consumer product source category.
The development of an emission reduction strategy requires an inventory
of VOC and PROC emissions from consumer and commercial products. Since
previous inventories of this type used information dating back to the early
1970s, EPA Regions 2 and 9, and the States of California, New Jersey, and New
York are supporting this study. The primary goals of the study are to (1)
identify the available secondary reference sources for the inventory, (2)
assess the quantity and quality of data which may be obtained from these
references for all consumer and commercial products, and (3) accurately
determine the quantity of VOC and PROC emissions from consumer and commercial
products for three geographical areas. The areas studied are: (1) the State
of California; (2) the State of New Jersey; and (2) the New York City
metropolitan area, which consists of the five boroughs of New York City, and
Nassau, Suffolk, Rockland, and Westchester counties.
This report, along with accompanying tables of emission estimates,
fulfills the requirements of Task 4 of the August 30, 1985 Work Plan. Where
possible, SAIC has estimated use and composition data for consumer and
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commercial products (Appendix A). SAIC has also calculated VOC and PROC
emissions for "typical" product formulations and individual product cate-
gories, and total emissions for all product categories in each of the three
assigned regions (Tables 4, 5, and 6).
The estimated emissions assume that all VOC and PROC are released to the
atmosphere. However, it is likely that not all such compounds are released
immediately upon use, some possibly not at all. A small fraction may remain
in the container or become chemically or physically bound in landfills or
water systems, thereby preventing release. Finally, some VOC or PROC may be
consumed by microbes in sewage systems or septic tanks.
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2. DEFINITION OF TERMS
The following are definitions of the terms used in presenting use and
emissions data in Tables 4, 5, and 6.
Annual Unit Distribution - Annual unit distribution is defined as the
number of units (i.e., containers, bottles, and cans, etc.) that are
distributed or produced in a given year. These data are based on the
Simmons Market Research Bureau 1983 survey and a 1984 survey conducted by
the Chemical Specialties Manufacturers Association. The distribution
numbers based on the Simmons survey were calculated by multiplying the
estimated population using the product by the quantity of the product
used in a given period. The distribution number generally represents all
product formulations within the product category.
Average Unit Weight - This is the average weight of all products
distributed in a product category. These data are primarily based upon
surveys conducted by the Western Aerosol Information Bureau (WAIB, 1982).
Geographic Multiplier - The geographic multiplier is a factor that
compares the regional usage of a specific product to the national
average. For some products, usage may vary significantly according to
geographic location. For example, use of suntan lotions in California is
estimated to be 1.16 times the National average. The geographic
multiplier is listed as a fraction of the National average, where the
National average is 1.00. Thus, multipliers greater than 1.00 indicate
usage is higher than the population in general and vice versa for
multipliers less than 1.00.
The geographic multipliers were obtained using data from Simmons 1983
Study of Media & Markets. The multipliers were based on data presented
for two of the five marketing regions established by Simmons for the
study: northeast and Pacific. The northeast States included
Connecticut, Maine, Massachusetts, New Jersey, New York, Pennsylvania,
Rhode Island, and Vermont. The Pacific States included Arizona,
California, Idaho, Nevada, Oregon, Utah, and Washington. For each
marketing region, an index was calculated by dividing the percentage of
the regional population using the product by the percentage of the total
U.S. population using the product. This index was used as the geographic
multiplier. Thus, for suntan lotions, the Simmons index for the pacific
marketing region was 116% or 1.16. Since California is part of the
Pacific region, the geographic multiplier for suntan lotions is 1.16.
National Consumption - National usage data are reported in pounds of
product consumed annually. Most data are based on Kline (1981, 1982).
Data for all-purpose cleaners and window and glass cleaners were con-
verted from millions of gallons to millions of pounds using a conversion
figure of 8.33 pounds per gallon. The consumption figure for shampoos
was given by Predicasts, Inc. (1984) to be 2.7 pounds per capita. This
was converted to pounds using a National population of 226,545,805.
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Photoreactiye Organic Compounds (PROCs) - All gaseous chemical
compounds that contain the element carbon are defined as reactive
by the EPA (Federal Register, 1983) excluding carbon monoxide, carbon
dioxide, carbonic acid, carbonates, metallic carbides, methane,
1,1,1-trichlorethane, methylene chloride, trifluoromethane, trichloro-
trifluoroethane, dichlorodifluoromethane, trichlorofluoromethane,
chlorodifluoromethane, dichlorotetrafluoroethane, chloropenta-
fluoroethane, and ethane.
Population Apportionment - This factor was used to adjust national data
to the individual regions. It is a ratio of the population of the region
divided by the population of the United States (U.S. Bureau of the
Census, 1986). Population bases ares (1) 226,545,805 persons in the
U.S., (2) 24,920,000 persons in CA, (3) 10,803,581 persons in N.Y., and
(4) 8,376,900 persons in N.J.
Relative Evaporation Rate (RER) - A measure of the volatility of a
compound relative to that of butyl acetate.- A compound's RER depends
upon its molecular weight and vapor pressure. See Section 3 for the
mathematical -definition.
Seasonal Variation - Variation in the use of a product or category of
products from winter to summer was investigated. In most cases, data
were not readily available. The only seasonal variations reported here
are those for the use of paints and finishes and suntan products. These
figures show the use of paint and suntan products in the summer compared
with winter usage. The summer tanning season corresponds to May to
October in California and June through September along the East Coast.
Total Volatile Organic Compound (VOC) Emissions - An organic compound is
classified as volatile if its Relative Evaporation Rate exceeds 0.1 or if
data for computing the RER are unavailable and the molecule has fewer
than 10 carbons. Low and high VOC emission values are reported for each
product subcategory. These are then aggregated into a low and a high
total annual VOC emissions estimate.
Weight Fraction VOC or PROG - This number indicates the proportion of VOC
or PROC in a given product formulation. Two fractions are generally
reported for each product category. The first is the lowest estimate of
VOC or PROC emitted from a set of formulations, while the second is the
highest estimate of VOC or PROC emitted from the same category. These
fractions may come from different product formulations. Weight fractions
for each product are given as percent of total weight in the individual
product formulations in Appendix A.
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3. TECHNICAL APPROACH
The Work Plan identified 11 aerosol and nonaerosol product categories,
and numerous subcategories. Tables 4, 5, and 6 report VOC and PROC emissions
for products in each of these categories. The 11 product categories are:
Aerosol Spray Products
(1) Insect Sprays
(2) Paints and Finishes
(3) Household Products
(4) Personal Products
(5) Animal Products
(6) Automotive and Industrial Products
(7) Food Products
(8) Miscellaneous Products
Nonaerosol Products
(1) Personal Products
(2) Household Products
(3) Garage Products
3.1 DESCRIPTION OF SOURCES
Composition and usage data for these product categories were derived from
the following sources:
Usage Data;
Chemical Specialties Manufacturers Association, Inc., (1984),
Pressurized Products Survey, United States Questionnaires for this
survey, which reports the number of aerosol units filled during 1984,
were returned by 217 companies, representing 88 percent of the
industry total.
Simmons Market Research Bureau, Inc., (1983), Simmons 1983 Study of
Media and Markets This company carries out annual surveys of
product usage in the United States. A representative sample of 19,248
adults, age 18 years and over, living in the coterminous 48 States,
was conducted between September 8, 1982 and July 5, 1983.
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Western Aerosol Information Bureau (WAIB) This organization is the
source of the only comprehensive information available on aerosol
product unit size. WAIB was not able to give detailed information
about the methodology it used to determine unit size.
C. H. Kline and Co., Inc., (1981), Consumer Pesticides and Fertilizers
Presents use and other data based on approximately 180 interviews
with competitive suppliers, distributors, raw material suppliers,
government agencies, and other trade factors. The survey was also
based on an extensive search of published literature and a review of
price lists, product descriptions, and other material from suppliers.
This source is believed to be the most accurate available for use
data.
C. H. Kline and Co., Inc., (1981), Household Cleansing Products
These data are based on telephone interviews with 38 major suppliers
as well as distributors, government agencies, and other trade factors.
This source is believed to be the most accurate available for use
data.
Composition Datat
Gosselin, Robert E., Robert P. Smith, and Harold C. Hodge, (1984),
Chemical Toxicology of Commercial Products, 5th ed. Williams and
Wilkins, Inc., Baltimore, MD This work, which presents "typical"
formulations for consumer products, was the source of composition data
for several product categories.
Wilkenson, J.B. and R.J. Moore, eds., (1982), Harry's Cpsmeticology,
7th ed., Chemical Publishing, New York This volume also presents
typical product formulations.
Micromedex, (1984), Poisindex source of composition data for a
portion of "paints and finishes."
Nowak et al., (1985), Aerosol Age source of composition data for
the remainder of "paints and finishes."
Chalmers, Louis, revised by Peter Bath, (1979), Household and
Industrial Chemical Specialties, vols. I and II, Chemical Publishing,
New York This was the only available source of formulas for several
product categories.
3.2 METHODOLOGY FOR DETERMINING VOLATILITY OF VOCs
A variety of formularies and market research volumes were examined, and
several associations were contacted, to obtain data on product use and
composition. Beacause use data were not available for individual product
formulations, high and low VOC and PROC emissions were estimated for each
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product subcategory. To develop these estimates, each formula was assumed to
be the representative of the subproduct category. The formula with the lowest
VOC and PROC emissions levels was then used as the low estimate and the
formula with the highest VOC and PROC emissions levels was used as the high
estimate.
The Relative Evaporation Rate (RER) index was used to determine the
consumer product constituents that should be considered "volatile" and those
that should be considered "nonvolatile." The RER is defined as (Stratte et
al., 1978):
RER = 0.8217 x (Vapor Pressure) x (YMolecular Weight).
This index expresses the volatility of the various organic compounds
relative to the volatility of n-butyl acetate (RER = 100). Molecular weights
were located in the Handbook of Chemistry and Physics (tfeast and Astle, 1981),
the Handbook of Environmental Data on Organic Chemicals (Verschueren, 1977),
and in the on-line data base HEILBRON, which is accessed through Dialog
Information Services, Inc. The HEILBRON data base summarizes information from
the Dictionary of Organic Compounds, 5th edition (1982). Compound names and
formulas were identified using the EPA series, Toxic Substances Control Act
Chemical Substances Inventory, Volumes II, III, and Cumulative Supplement
(USEPA, 1980).
Many compounds were identified in product formulas only as proprietary
ingredients, such as "DC-193 fluid," "PVP-VA copolymer E-735," or "carbopol
934." Others were listed generically in classes, such as alcohol, essential
oils, or chlorinated solvents. Where possible, the representative compounds
for each classification were used as surrogates for these classes and vola-
tility was decided on the basis of the surrogate. For example, isohexane was
used for "C6 isomers" and butyl benzyl phthalate was used for "plasticizers."
CHEMNAME, another on-line data base, was searched for Chemical Abstracts
Service (CAS) registry numbers and molecular weights of proprietary named
chemicals. Some compounds which could not be located using the other sources
were identified in this manner. The CAS numbers provided reference points for
locating physical and chemical data in the HEILBRON data base.
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Vapor pressures not available through one of the previously mentioned
sources were computed by using the following formula, which relates a com-
pound's vapor pressure at 20°C to its boiling point at 760 mm atmospheric
pressure (Hass and Newton, 1981):
2.8808 - log p = ,
293.1 - 0.15 At
where
At = boiling point(°C) - 20°C
log p = logarithm of the observed pressure in mm Hg
0 = entropy of vaporization at 760 mm.
The entropy of vaporization is determined from a set of curves presented by
Hass and Newton. For compounds whose boiling points are reported at a
different pressure than 760 mm, the boiling point at 760 mm must first be
iteratively obtained by a rewritten form of this formula, so that the above
computation may be carried out:
B760 " BP + (273.1 + Bp)(2.8808 - log p)/[0 + 0.15(2.8808 - log p)]
where
B = the observed boiling point at pressure P (mm)
Note that 0 is a function of the boiling point. Therefore, the equation must
be solved iteratively until successive values of B7go are very close (within
0.1°C in our case).
Most molecular formulas could be identified, but boiling points and vapor
pressures frequently were not reported in the literature. Because unknown
compounds needed to be systematically defined as "volatile" or "nonvolatile,"
long-chain hydrocarbons (e.g. waxes, oils, and some esters) were considered
nonvolatile. "Long-chain" generally meant 10 or more carbon atoms. Data were
lacking for a large number of the compounds, many of which were fatty acid
esters. Polymers and resins were also assumed to be nonvolatile. All
nonvolatile compounds were assigned a vapor pressure of 0 mm, so that their
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RERs were also 0. Substances known to be mixtures of volatile compounds,
such as "mineral spirits" or Stoddard solvent, were arbitrarily assigned a
molecular weight of 50 and a vapor pressure of 50 mm in order to generate RERs
indicative of volatile compounds. The RERs for these substances were 290.515.
Finally, compounds for which no physical data were available were assumed to
be nonvolatile.
Selection of a dividing line between "volatile" and "nonvolatile" was of
necessity arbitrary, since volatility was quantified by a relative measure,
the RER. For convenience, the lower limit of volatility was set at RER = 0.1,
or three orders of magnitude below that of butyl acetate. Examination of
compounds whose RERs lie on either side of 0.1 confirmed that the choice was
reasonable. Most of the compounds with RER <0.1 are solids at ambient
temperatures (e.g. thymol and benzoic acid) or are polar liquids with boiling
points above 200°C (e.g. diethylene glycol and myristil alcohol). Compounds
whose RERs slightly exceed 0.1 are liquids, most of which are known to be
volatile; these include ethylene and propylene glycols. All organic compounds
in the listed products, except methylene chloride, 1,1,1-trichloroethane, and
carbon dioxide, were considered reactive. Product category and total emis-
sions in Tables 3, 4, and 5, and percentages emitted in Appendix A are
reported separately for VOC and PROC.
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4. UNCERTAINTIES/DATA GAPS
The analysis estimated VOC and PROC emissions from consumer and
commercial products by combining composition data with distribution or use
data for product subcategories. Composition data within each subcategory were
further aggregated from individual formulas; while national usage was
frequently derived from several types of products, such as aerosol and
non-aerosol. Thus, at each stage of analysis, aggregation error enters the
result. The extent of this type of error is not known, although it varies
from one product subcategory to another. Table 1 shows the availability of
data for each product subcategory. The following list identifies sources of
uncertainty for composition and usage data:
Usage Data - The available use data often encompassed broad product
categories and could not be disaggregated to individual products and formu-
lations within each subcategory. In addition, use data were not readily
available for many subcategories. This was particularly true for nonaerosol
products. Several product subcategories were therefore merged and emissions
calculated on the basis of these merged data. Vhen aerosol and nonaerosol
products were combined, they were reported under aerosol/nonaerosol in Tables
4, 5, and 6.
Population Apportionment - The data used for the population apportionment
comes from 1984 and 1985 U.S. Bureau of Census population estimates. The data
were obtained from telephone conversations with Bureau of Census staff. SAIC
believes that this data is the most accurate available.
Geographic Multipliers - The geographic multipliers are based on the
Simmons 1983 Study of Media Markets. The study interviewed 19,248 adults and
is representative of the U.S. population, age 18 and over living in the
contiguous 48 States. The interview period was from September, 1982 through
July, 1983.
Factors influencing the accuracy of the geographic multiplier are the
number of States and the population in each marketing region, as well as the
frequency or quantity of usage within each marketing area. For example,
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California represents over 65 percent of the population in the Pacific
marketing region. We believe that the population of States outside
California, but vithin the Pacific marketing region, would have little
influence on the accuracy of the California data. However, New York and New
Jersey each represent only 36 percent and 15 percent respectively of the
northeast marketing region. Thus, other State populations could have a
significant impact on the accuracy of the usage data. Although we are
uncertain how this would affect typical product usage in the two States
compared to the Simmons regional data, we believe the influence in the
estimated error to be minimal. Our belief is based on Simmons' judgment in
establishing homogeneous marketing areas (i.e., similar consumer product usage
patterns throughout a marketing area).
Product use within each region varies more than use in all regions
combined. Use within regions may vary from 15 percent less to 20 percent
greater than the national average. However, an average use weighted by State
population does not differ greatly from a nonweighted use, within an entire
region. Therefore, it is reasonable to assume that the statewide geographic
multiplier is similar to the regional one.
The error in estimating PROC from the geographic multiplier is small
compared to other uncertainties, such as those present in the formulation and
consumption data.
Formulation Data - The accuracy of the formulation data presented in this
report cannot be easily assessed. For any given product category, a wide
range of formulas may be in use. These formulations vary significantly
according to the quality of the product and its specific use. Many of the
formulas, however, are proprietary or contain compounds that are proprietary.
Although formulations for specific brands were included when available, most
of the ones available for this report were "generic" formulations provided to
our references by the manufacturers of the product ingredients. These
formulations were verified where possible by a shelf survey. Few product
labels show percent by weight formulations. A somewhat larger number list
ingredients. However, generic terms are often used for these ingredients
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(e.g., inert ingredients, volatile organic compounds, driers, alcohol, or
plasticizer). Frequently, only the active ingredient is listed on the label.
All formulas are assumed to be representative of their product subcategory.
The formula data were often six to ten years old. Even where formularies were
recent, the reported composition was probably two or three years behind
current production lines. The degree of obsolescence of these formulas is
difficult to judge. Formulas are continually changing over time. These
changes are caused by improvement in product formulations, regulations such as
the chlorofluorocarbon ban, and the changing cost of intermediates. For the
purposes of this report, product lines are assumed to evolve slowly and that
all recent arrivals contain similarly volatile species.
Other formula uncertainties include the following:
Many formulations included chlorofluorocarbons as the propellant
although they have been banned in most consumer products. Attempts
were made to verify, through industry sources, the various assumptions
made regarding the type and quantity of the replacement propellant
through industry sources.
In several cases aerosol and nonaerosol formulations were combined.
This was necessary because only aggregated use data were available.
Composition and weight might be substantially different for aerosol
and nonaerosol products.
Formulations for many products consisted of percentage ranges for one
or more ingredients. It was often difficult to clearly delineate the
lower and upper bounds of volatile compounds for these products. This
problem arises because a decrease in one ingredient must be compen-
sated for by an increase in one or more other ingredients. Some of
the replacement ingredients may be volatile while others are non-
volatile. Our best professional judgment was used in such cases. It
is likely that results were not substantially affected in these cases.
Very few nonaerosol formulas were available for this report.
Product formulation descriptions occasionally aggregate dissimilar
ingredients, reporting the percent by weight of groups rather than of
individual compounds. For example, "xylol" and "driers" were combined
for the paints and finishes product category, even though they are
different compounds and have very different volatilities.
Product ingredients were frequently reported as classes of compound,
such as "alcohol" and "plasticizer." We had to choose a "typical"
ingredient and decide volatility on the basis of this surrogate.
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SAIC estimated the low and high VOC and PROC emissions for each
product subcategory by finding the formulation with the lowest weight
percent and the one with the highest weight percent VOC and PROC.
This means that subcategories with many formulations may have a
considerable range between the low and high emission estimate. One
particularly troublesome subcategory was insecticides, which comprised
primarily space insecticides, but also included one dust and one
target aerosol. PROC varies from 0 percent in one formula to 100
percent in another.
Although a number of other formulas were available in Gosselin (1985),
we chose "typical" formulas for product subcategories to reduce the
data set to a manageable size. Variation in chemical content from the
formulas that were not chosen to those that were used generated
additional uncertainty.
Ratio of Seasonal Variation - The seasonal variation of product usage was
only included in the paint and suntan products calculation. The ratio was not
included in other consumer product subcategories because of a lack of data
and, in many cases, the small likelihood of any significant variation between
seasons. For paint products, we assumed that 57.5 percent was used during the
ozone season. These figures are based on monthly sales figures collected by
the Bureau of census and are believed to be accurate. For suntan products,
100 percent was assumed to be used during the ozone season. Within the states
of New York and New Jersey, use outside of the summer season was assumed to be
negligible. In California, we assumed that use outside of the summer season
would be minimal. Even though the warm climate permits sunning during the
entire year, the less direct sun would reduce the need for protective
sunscreens or tanning lotions.
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TABLE 1. AVAILABILITY OF DATA BY PRODUCT SUBCATEGORY1
i
en
Category
Insecticides
Insect Repellants
Moth Control Products
Animal Insecticides
Herbicides and Fungicides
Paints, Primers, Varnishes
Paints and Finishes -
Related Products
Room Deodorants and
Disinfectants
Tile and Bathroom Cleaner
Oven Cleaners
Rug and Upholstery Cleaner
All Purpose Cleaner
Window and Glass Cleaner
Laundry Products - aerosol
Laundry Products - aerosol
and nonaerosol
Shoe Polishes, Waxes,
and Colorants
Units
Distributed
NA
NA
NA
NA
NA
Yes
Yes
Yes7
NA
NA
NA
NA
NA
Yes
Average
Product
Weight
NA
NA
NA
NA
NA
Yes
Yes
Yes
NA
NA
NA
NA
NA
Yes
National
Consumption
Yes
Yes
Yes
Yes
Yes
NA
NA
NA
Yes
Yes
Yes
Yes8
Yes8
NA
Population
Apportionment
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Geographic
Multiplier
No
No
No
No
No
Yes
No
Yes
No
Yes
No
Yes
Yes
No
Product
Formulations
Yes3
Yes4
Yes4
Yes4'5
Yes
Yes6
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
NA
NA
NA
NA
Yes
Yes
Yes
Yes
No
No
Yes
Yes
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TABLE 1. AVAILABILITY OP DATA BT PRODUCT SUBCATEGORY1 (Continued)
P-
i
Category
Other household Products
- aerosols
Other household Products
- aerosols and nonaerosols
Adhesives
Caulking and Sealing
Compounds
Shaving Cream
Hair Products - aerosols
Other Hair Care Products
Pharmaceuticals
Colognes, Perfumes,
Aftershaves
Personal Deodorants
Other Personal Care Products
Automotive Cleaners
Automotive Engine Degreasers
Lubricants and Silicones
Undercoat ings
Brake Cleaners
Units
Distributed
NA
NA
NA
Yes
Yes
NA
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Average
Product
Weight
NA
NA
NA
Yes
Yes
NA
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
National
Consumption
Yes
Yes
14
Yes
NA
NA
Yes
NA
14
11
NA
NA
NA
NA
NA
NA
NA
NA
Population
Apportionment
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Geographic
Multiplier
Yes
No
No
Yes
Yes
10
Yes
Yes
12
Yes
Yes
Yes
No
No
No
No
No
Product
Formulations
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
No
Tire Inflator and Sealant
Yes
Yes
NA
Yes
No
No
-------
D/834-025-68a/#9
TABLE 1. AVAILABILITY OF DATA BT PRODUCT SUBCATEGORY1 (Continued)
Category
Carborator and Choke Cleaner
Engine Starting Fluid
Auto Windshield Vasher
Fluid and Deicer
Floor Polishes and Waxes
Metal Cleaners and Polishes
Automotive Antifreezes
Car Polishes and Waxes
Laundry Products
Household Polishes
Units
Distributed
Yes
Yes
Yes13
MA
NA
NA
Yes
NA
NA
Average
Product
Weight
Yes
Yes
Yes13
NA
NA
NA
Yes
NA
NA
National
Consumption
NA
NA
NA
Yes
Yes
Yes
NA
Yes
Yes
Population
Apportionment
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Geographic
Multiplier2
No
No
No
Yes
No
No
Yes
No
Yes
Product
Formulations
Yes3
No
Yes13
Yes
Yes
Yes
Yes
Yes
Yes
The data for all product categories are subject to the uncertainties and limitations described in the text.
Other limitations and assumptions pertaining to specific categories are noted below and are further explained
in the text.
Where the goegraphic multiplier was not available, the value 1.0 was used for the purposes of the
calculations.
Because complete formula data was not available for some aerosols, the percentage of propellant was estimated
using data from WAIB and CSMA. See text for methodology and assumptions.
4The formulas available for the report showed a large percentage of inert ingredients. These inert
ingredients may or may not include propellants and other VOCs. See text for further explanation.
'Some of the formulas had composition data that did not equal 100%. In these cases, half of the unknown
ingredients were assumed to be volatile.
-------
D/834-025-68a/#9
TABLE 1. AVAILABILITY OF DATA BY PRODUCT SUBCATEGORY1 (Continued)
For the purposes of emissions calculations, halogenated hydrocarbons were replaced by aliphatic hydrocarbons
in some formulas. See text for further explanation.
j
See text for methodology of this calculation.
See text for methodology of this calculation.
g
Not for all products
For hair spray only.
See text for methodology of this calculation.
For fungicides only.
For Deicer only.
Includes industrial as well as consumer adhesive use.
i
oo
-------
E/834-025-68a/#13
5. RESULTS
VOC or PROC emissions were computed using the following two formulas:
Total VOC or PROC Emissions =
1. (units distributed) (avg. prod, wt.)
(pop. apport.) (geogr. mult.) (wt. fraction VOC or PROC)
2. (National consumption) (pop. apport.)
(geogr. mult.) (wt. fraction VOC or PROC)
Sample calculations illustrating equation 1, for a low PROC emissions estimate
and a high PROC emissions estimate for Pharmaceuticals in California are:
1. PROC Emissions = (43.7 x 106 units)(0.25 lb)(0.11)(1.08)(0.70)
low est. (1/2 x 103 tons/lb)
= 454.26 tons
PROC Emissions = (43.7 x 106 units)(0.25 lb)(0.11)(1.08)(0.99)
high est. (1/2.0 x 103 tons/lb)
= 642.46 tons
Sample calculations illustrating equation 2, for a low PROC emissions estimate
and a high PROC emissions estimate for all-purpose cleaners in California are:
2. PROC Emissions = (512 x 10s lb)(0.11)(1.07)(0.02)(l/2 x 103 tons/lb)
low est.
= 602.62 tons
PROC Emissions = (512 x 106 lb)(0.11)(1.07)(0.41)(l/2 x 103 tons/lb)
high est.
= 12353.79 tons
The molecular weights, boiling points, vapor pressures and RER's for the
chemical compounds listed under product formulations in Appendix A are
arranged in alphabetical order in Table 2. The compounds have been reordered
numerically by RER in Table 3, in order to more readily discern the division
between volatile and nonvolatile compounds.
5-1
-------
E/834-025-68a/#13
We decided to use low VOC/PROC and high VOC/PROC emissions rather than
some form of VOC/PROC weights by product type, which would then be multiplied
by the distribution or consumption data to yield the emission total for a
given subcategory. It was felt that the data uncertainties, discussed earlier
in the report, both within products and within product subcategories, were so
large that such results would be highly misleading. For example, it was not
possible to know how widely an individual product, versus other products
within a subcategory, was distributed in each region. Given these problems,
any weights which might be applied to the distribution figures, and the
emission estimates that would result, would present a spurious picture of the
accuracy of these estimates. For this reason, a range of values depicting
emission boundaries would make the reader more aware of the data limitations.
Annual VOC and PROC emissions are presented in Tables 4, 5, and 6. Low
and high estimates are based upon the likely range of VOC or PROC emissions in
each product category. For example, the ratio of VOC present in formulations
in "paints and finishes" in California ranges from 0.73 to 0.87 and is entered
under "weight fraction VOC." The appropriate fractions are multiplied to
yield annual low and high estimates for each product subcategory. The low and
high weight fractions were chosen by examination of the weight percents under
the product formulas listed in Appendix A. If formulas 1 and 4 were chosen
for a particular product subcategory, then formulations 1,4 were listed in
Tables 4, 5, and 6 for that subcategory. Product category subtotals were
obtained by summing VOC and PROC emission estimates for subcategories.
Addition of product category subtotals produced total emission estimates for
each region.
Tables 4, 5, and 6 report data for all product categories and
subcategories listed in the August 30, 1985 Work Plan, when data were
available. Where data were not available or incomplete, we listed NA in the
emission estimate column. Aerosol food products were omitted from the final
emission inventory since the propellent used in these products is nitrous
oxide and therefore not an organic compound (Kirk-Othmer, 1978).
5-2
-------
PRODUCT NAME
TABLE 2
RELATIVE EVAPORATION RATES - ALPHABETICAL
BP (C) PRESSURE HW VP RER COMMENTS
204.27 .00 .01
307
118.1
56.2
2-FUHALDEHYDE, 2,3:4,5-815-
(2-BUHLENE) TETRAHYDRO
2.4 BIS (ISOPROPYLAM1N01-6
METHOXY-S-TRIAZINE
2,4,5-TRICHLOROPHENOXYACET1C
ACID, POTASSIUM SALT
4-AHlNO-3,5,6-TR!CHLOROPlCOLINlC ACID
5-BENZYL-3-FURYL
AC POLYETHYLENE 6Z9
ACETIC ACID
N-ACETYLETHANOLANINE
ACETONE
ACRYLIC RESIN
ACRYSOL LEVELING AID
ADIPIC ACID
ALCOHOL 740 P
ALCOHOL-SOLUBLE LANOLIN
ALIPHATIC HYDROCARBONS
ALIPHATIC THINNER'
ALKYD RESIN
ALKYL ARYL SODIUM SULFONATE
ALKYL DIETHANOLAM1NE
ALKYLDIMETHYLBENZYLAMMONIUM
ALKYLDIMETHYLBENZYLAMHONIUN CHLORIDE
ALLETHRIN, D-TRANS 302.413
ALUMINUM PHENYLSULFONATE
AMINES
2-AHINO-2-METHYL PROPANOL 165.5
AMMONIUM CITRATE
AMMONIUM LAURYL ETHER SULPHATE
AMMONIUM OXALATE
AKMONYX 4002
AMP 165
AMPD 151.2
AHPHOHER
AMYL ACETATE 148
ANTARON FC-34
AROMATIC HYDROCARBONS
AROMATIC KETONE SOLVENT
BAYGON
BEESVAX
BENZETHONIUH
BENZOIC ACID 249,133
BENZYL BENZOATE 323.5
0-BENZYL-P-CHLOROPHENOL 161
BIOC IDE
BRONOCIL
BUTADIENE-STYRENE COPOLYMER
BUTANE -.1
0.00
60.05
50.00
58.08
50.00
86.17
86.17
88.13
73.14
89.14
142.11
89.14
10 105.14
737 130.20
92.10
92.10
209.24
10 122.13
212.25
3.5 218.68
58.12
0.00
10.53
50.00
132.49
0.00
50.00
0.00
50.00
50.00
0.00
0.00
.01
0.00
200.00
.33
0.00
0.00
0.00
0.00
.44
.00
0.00
3.05
0.00
22.00
22.00
0.00
0.00
.00
.00
.00
0.00
1544.67
0.00
0.00
0.00
0.00
67.68
290.51
829.65
0.00
0.00
0.00
290.51
0.00
381.38
381.38
0.00
0.00
.07
0.00
0.00
0.00
0.00
1405.47
2.53
0.00
0.00
0.00
0.00
3.41
.00
0.00
28.55
0.00
173.49
173.49
0.00
0.00
0.00
.03
.00
.00
0.00
0.00
0.00
9676.33
SALT-AS3UHED NONVOLATILE
ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
LARGE POLYMER
RESINS ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
HIGH-C FATTY ACIDS NONVOLATILE
HIGH-C FATTY CMPDS NONVOLATILE
USED HEXANE AS REPRESENTATIVE
USED HEXANE AS REPRESENTATIVE
RESINS ASSUMED NONVOLATILE
SALT
USED ETHYL DIETHANOLAMINE
NO DATA - ASSUMED NONVOLATILE
SALTS ASSUMED NONVOLATILE .
HIGH-CARBON ESTER-NONVOLATILE
SALTS ASSUMED NONVOLATILE
SURROGATE'DIETHYLAMINE
SALT ASSUMED NONVOLATILE
HIGH-CARBON SALT
NONVOLATILE SALT
VERY HIGH-CARBON COMPOUND
NO DATA - ASSUMED NONVOLATILE
USED N-AMYLACETATE
POLYMERS ASSUMED NONVOLATILE
SURROGATE - XYLENE
SURROGATE - XYLENE
CRYSTALLINE-ASSUMED NONVOLATILE
WAXES ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
SOLID - ASSUMED NONVOLATILE
LARGE POLYMER NONVOLATILE
5-3
-------
TABLE 2 (Continued)
RELATIVE EVAPORATION RATES - ALPHABETICAL
PRODUCT NAME
HP (C) PRESSURE
ny
VP
RER COMMENTS
BUTYL CELLOSOLVE
Cl.S.P. COMPOUNDS
CALCIUM THIQGLYCOLATE TRIHYDBATE
CALGQN
L-CAMPHOR
CARBARYL
CARBITOL
CARBOPOL 934
CARBOIYMETHYL CELLULOSE
CARNAUBA WAX
CARTARETINE F4
CATIONIC CELLULOSE
CELLOSOLVE ACETATE
CELLULOSE ACETATE BUTYRATE
CERES IN'
CETYL ALCOHOL, RAKES
CHLOR- AROMATIC SOLVENTS
CHLOR. PARAFFIN PLASTIC I ZER
CHLOIDANE
CHLORINATED SOLVENTS
CHLOROSULFONATED POLYETHYLENE
CITRIC ACID
CKANINO BETA1NE
COCONUT .AMI DOPROPYL-
3-D1METHYLAMINE BETA1NE
COCONUT OIL AHINE
COLOR
COLOR MIX
CONDANOL (DBS,DLS,MLS,SB/L)
COPPER NAPHTHENATE
COPPER UNDECYLENATE
CRESOL (0-.M-.P-)
CRQHEEN
CRYSTALLINE WAX
CUBE RESINS
CYCLOPROPANE CARBOXYLATE
D.L-CAMPHOR
D-CAHPHOR
DC 193 FLUID
DDVP
DEHYDROGENATED RESIN
DEODORANT
DETERGENT
H.N-DIALKYL-M-TOLUAMIDE
DIBUTYL PHTHALATE
0-D1CHLOROBENZENE
DICHLOROMETHANE
DICHLOROPENTANE
DIETHYLENE GLYCQL
170
SUBLIMES 9
202
156
190
DECOMPOSES
SUBLIMES
SUBLIMES §
140
160
340
130.5
41
245
118.17
152.24
134.20
132.16
15
112.56
409.78
50.00
192.12
108.13
152.24
152.24
20 220.98
50.00
19 191.27
278.35
147.00
84.93
141.04
106.12
.60
0.00
.28
o.oo-
.21
0.00
0.00
0.00
0.00
1.20
0.00
0.00
8.80
50.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
.11
0.00
0.00
0.00
.28
.28
0.00
.01
0.00
50.00
0.00
.00
.00
.89
349.00
14.02
.00
5.36
0.00
0.00
0.00
2.81
0.00
1.99
0.00
0.00
0.00
0.00
0.00
11.34
0.00
0.00
0.00
76.72
0.00
0.00
290.51
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
.96
0.00
0.00
0.00
0.00
2.81
2.81
0.00
.11
0.00
290.51
0.00
.02
.00
8.89
2642.83
136.81
.02
E.G. MONOBUTYL ETHER
NO DATA - ASSUMED NONVOLATILE
SALTS ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
NONVOLATILE CRYSTAL AT ROOM TEMP
NO DATA - ASSUMED NONVOLATILE
LARGE POLYMER
VAXES ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
LARGE POLYMER
NO DATA - ASSUMED NONVOLATILE .
HIGH-CARBON ALCOHOL - NONVOLATILE
SURROGATE'HONOCHLQROBENZENE
SURSOGATE=BUTYL BENZYL PHTHALATE
FROM STRUCTURE, PROBABLY NON-VOL
POLYMERS ASSUMED NONVOLATILE
ASSUMED NONVOLATILE
LONG-CHAIN POLYMER
LONG-CHAIN POLYMER
HIGH-CARBON
NO DATA - ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
NONVOLATILE SALT
METALLIC SALT
HIGH-CARBON SALT - NONVOLATILE
RER DERIVED FROM AVG RER'S
NO DATA - ASSUMED NONVOLATILE
VAXES ASSUMED NONVOLATILE
RESINS ASSUMED NONVOLATILE
USED CYFQTHRIN (HIGH-CARBON)
NO DATA - ASSUMED NONVOLATILE
RESINS ASSUMED NONVOLATILE
SURROGATE-SODIUM LAUHYL SULFATE
USED N,N-DIETHYL-H-TOLUAMIDE
SAME AS METHYLENE CHLORIDE
RER DERIVED FROM AVG BES'S
5-4
-------
TABLE 2 (Continued)
RELATIVE EVAPORATION RATES - ALPHABETICAL
PRODUCT NAME
BP (C) PRESSURE
nu
VP
RER COMMENTS
DIETHYLENE GLYCOL MONONETHYL ETHE
DIHETHYCONE COPOLYOL
DIMETHYL ETHER
DIHETHYLENE OXIDE
DIOCTYL PHTHALATE PLASTICIZER
DIPROPYLENE GLYCOL
DIPROPYLENE aYCOL HONOHETHYL ETH
DITHIQ-BIS-STEARYL PROPIONATE
DODECYL BENZENE SULFONATE
DOU 276-V9
DRIERS
DUREZ (14000,16470,22008)
DUREZ (19788,12686,12687)
DUREZ (26141,26739,26799)
DUREZ 7421A
EDTA
ELASTOHERIC BINDER
EMOLLIENT
EHULPHOR ON-870
EHULSIFIERS, HUH ECT ANTS, VAXES
ENDOSULPHAN
ESSENTIAL CEDAR OIL
ESSENTIAL OIL
ESTERS AND KETONES (ACETONE)
ETHANOL
ETHANOLAHINE
ETHOIYLATE TRIDECYL ALCOHOL
ETHOXYLATED FATTY ALCOHOL SULFATE
ETHYL ALCOHOL
ETHYL ALCOHOL OP
ETHYLENE BICHLORIDE
ETHYLENE GLYCOL
ETHYLENE GLYCOL HONOBUTYL ETHER
ETHYLENE GLYCOL NONOETHYL ETHER
ETHYLENE GLYCOL DISTEARATE
2-ETHYL-l,3-HEXANED10L
2-ETHYL HEXYL SALICYLATE
FATTY ACID AMIDES
FATTY ACID SOAP
FISH OIL
FLU (LAN
FOAM STABILIZERS
FOLPET
FORMALDEHYDE
FORMALIN
FRACTAL A
FRAGRANCE
FRAGRANCE. DYE
GANTREZ ES 22B OR ES 425
159
-25
385
292/232
187.2
78.5
172
78.4
78.4
83.5
198
135
244
296.555
-20
-20
120.15
46.70
44.05
390.56
134.20
162.23
50.00
50.00
46.07
61.08
46.07
46.07
99.00
62.10
118.17
90.10
146.23
30.00
30.00
50.00
50.00
1.88
0.00
3581.69
1095.00
.00
.01
.46
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
50.00
50.00
43.90
.40
0.00
0.00
43.90
43.90
61.00
.06
.60
3.80
0.00
.00
0.00
0.00
0.00
0.00
0.00
3243.38
3243.38
50.00
50.00
0.00
16.96
0.00
20112.19
5971.73
.00
.10
4.76
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
290.51
290.51
244.84
2.57
0.00
0.00
244.84
244.84
498.72
.39
5.36
29.64
0.00
.02
0.00
0.00
0.00
0.00
0.00
0.00
0.00
14597.26
14597.28
0.00
290.51
290.51
0.00
POLYMERS ASSUMED NONVOLATILE
RER SHOULD BE < 0.1
HIGH-CARBON ESTER - NONVOLATILE
HIGH-CARBON ESTER
NO DATA - ASSUMED NONVOLATILE
ASSUMED TO REMAIN IN THE COATINGS
PHENOL-FORMALDEHYDE RESIN
PHENOL-FORMALDEHYDE RESIN
PHENOL-FORMALDEHYDE RESIN
PHENOL-FORMALDEHYDE RESIN
NO DATA - ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
PROBABLY NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
FUNCTION IMPLIES WON VOLATILITY
HO DATA - ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
LONG-CHAIN ALCOHOL
HIGH-CARBON ASSUME NONVOLATILE
SAME AS ETHANOL
LONG-CHAIN ESTER
HIGH-CARBON ACID - NONVOLATILE
SURROGATE'. NYLON; ASSUMED NONVQLAT
SOAPS ASSUMED NONVOLATILE
ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
CRYSTALLINE- ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
NO DATA - ASSUMED VOLATILE
PROBABLY A RESIN - NONVOLATILE
5-5
-------
TABLE 2 (Continued)
RELATIVE EVAPORATION RATES - ALPHABETICAL
PRODUCT NAME
BP (C) PRESSURE
VP
RER COMMENTS
GELVA (TS 22,23,30,31,35)
GLYCEROL
GLYCOL ETHER
GRANULAR MINERAL BASE
HALOGENATED HYDROCARBON PRQPELLAN
HARD VAXES
HQECHST VAX
HUMECTANTS
HYDROCARBON PRQPELLANT
HYDROGENATED RESIN ESTER
HYDROIYALXYL CELLULOSE (KLUCEL HA
INERT INGREDIENTS (PESTICIDES)
ISOBUTANE
ISOBUTYLENE POLYMERS
1SOOCTYL ESTERS
ISOPARAFFIN1C SOLVENT
ISOP80PANOL
ISQPRQPYL ALCOHOL
1SOPHOPYL HYRISTATE
0-ISQPROXYPHENYL HETHYLCARBABATE
KELTHANE
KELZAN
KEROSENE
KOSOL
KP-UO
LANETO 100
LANOLIN
LATEX POLYMER ACRYLIC RESIN
LAURIC ACID
LAURIC DIETHANOLAHIDE
HALATH10N
MBTS (2-BENZOTHIAZOLYL SULFIOE)
MENTHOL
NETHOXYCHLOR
METHYL ALCOHOL
NETHYL ANTHRANILATE
METHYL P-HYDROXYBENZOATE
NETHYLBENZETHONIUH CHLORIDE
METHYLENE CHLORIDE
HGK
HICROCRYSTALLINE UAX
KILLED PALE CREPE
HILLED SMOKE RUBBER
MINERAL OIL
MINERAL SPIRITS
NIRANOL C2HSF
MONAHID 716
HONOETHYLENE GLYCOL
MONO ETHYL ETHER
DECOMPOSES 9 290
-.5
60.3
62.4
82.4
192.6
370.49
20
131
156.5
216
65
223.3
41
307
.7
92.11
90.10
50.00
58.12
86.18
60.10
60.10
270.46
50.00
1 200.33
330.35
332.47
156.27
32.04
152.15
84.93
204.27
198
50.00
62.10
90.10
.00
3.80
50.00
0.00
0.00
0.00
1544.67
0.00
0.00
58.12 1566.19
168.34
34.82
34.82
0.00
0.00
0.00
50.00
0.00
0.00
0.00
0.00
0.00
0.00
.00
.15
0.00
92.39
0.00
.07
0.00
365.66
.00
0.00
0.00
0.00
0.00
50.00
0.00
0.00
.06
3.80
0.00
.00
29.64
0.00
290.51
0.00
0.00
0.00
9676.33
0.00
0.00
1511.56
9811.14
0.00
0.00
1284.09
221.79
221.79
0.00
0.00
0.00
0.00
'290.51
0.00
0.00
0.00
0.00
0.00
0.00
0.00
.00
0.00
1.54
0.00
429.70
0.00
.67
0.00
2768.98
.01
0.00
0.00
0.00
0.00
290.51
0.00
0.00
.39
29.64
POLYVINYL ACETATE RESIN
SURROGATED. G. NONOETHYL ETHER
SOLID - ASSUMED NONVOLATILE
VAXES ASSURED NONVOLATILE
VAXES ASSUMED NONVOLATILE
FUNCTION IMPLIES NONVOLATILE
SURROGATE:BUTANE
RESINS ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
RER=VTD AVG OF TYPICAL INGRED.(2)
POLYMER - ASSUMED NONVOLATILE
FAIRLY HIGH CARBON ESTER
SURROGATE -- ISOHEXANE
HIGH-CARBON ESTER - NONVOLATILE
Cll COMPOUND ASSUMED NONVOLATILE
CRYSTALLINE-ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
KNOUN TO BE VOLATILE
STARCH (POWDER)
NO DATA - ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
ASSUMED NONVOLATILE
RESINS ASSUMED NONVOLATILE
HIGH-CARBON FATTY ACID-NONVOLATIL
HIGH-CARBON AMIDE - NONVOLATILE
CRYSTALLINE AT ROOM TEMP.
NONVOLATILE CRYSTAL AT ROOM TEMP
NO DATA - ASSUMED NONVOLATILE
SALTS ASSUMED NONVOLATILE
MGK 11 USED AS TYPICAL COMPOUND
VAXES ASSUMED NONVOLATILE
SOLID AT AMBIENT TEMPERATURE
SOLID AT AMBIENT TEMPERATURE
NO DATA - ASSUMED NONVOLATILE
KNOWN TO BE VOLATILE
HIGH-CARBON SALT
NO DATA - ASSUMED NONVOLATILE
5-6
-------
TABLE 2 (Continued)
RELATIVE EVAPORATION RATES - ALPHABETICAL
PRODUCT NAME
BP (C) PRESSURE
VP
8ER COMMENTS
HQNOGLYCEROL P-AHINOBENZOATE
HONURON
HORPHOL1NE 128
HYRISTIC ACID 250.5
MYRISTIL ALCOHOL 263.2
HAPHTHALENE 217.9
NEOPBENE
NITROCELLULOSE
NITRQPROPANE (1-.2-)
N-OCTYL-BICYCLOHEPTENE DICARBOXINIDE
NONYLPHENOXY ACETIC ACID
OILS
OLE 1C ACID 360
OXYGENATED ORGANIC ACIDS
PALMITIC ACID 350,267
PARAFFIN WAXES
PENTANE
PERCHLOROETHYLENE 121.4
PERFUME
PERFUME IN ALCOHOL
PERFUME OIL
PETREI 7-75T (DRY) 136
PETROLEUM AND SYNTHETIC VAXES
PETROLEUM DISTILLATE (NAPHTHA)
PETROLEUM ETHERS
PETROLEUM OIL
PETROLEUM SOLVENTS
PHENOLIC RESIN
PICLORAH
PINE OIL 155
PIPEBOMYL BUTQXIDE 160
PLASTIC
PLASTICIZER (D60-.3GH-)
PLURONIC F 108 DETERGENT
POLAVAX A 31
POLY-BETA-PINENE RESIN
POLYACRYLATE
POLYACRYLIC ACID (40X AQ.) H.U.10
PQLYD1 METHYLS I LQIANE
POLYETHOXYLATED (75 EQ) LANOLIN
POLYETHYLENE
POLYETHYLENE GLYCOL (400) MONOLAU
POLYISOBUTYLENE (TRI-,TETRA«ER- )
POLYOXYETHYLENE (2) CETYL ETHER 270
POLYOXYETHYLENE SORBITAN MONOSTEA8ATE
POLYQUATERNIUH 4
POLYTRIHETHYLDIHYDRO-QUINOLINE
POLYVINYL ACETATE
POTASSIUM SOAP OF OLE 1C ACID
87.12
100 228.38
214.40
128.16
89.09
50.00
282.46
50.00
100 256.43
72.15
165.83
50.00
50.00
50.00
11 234.30
50.00
90.10
50.00
50.00
136.23
1 338.44
312.36
196.38
466.39
0.00
8.00
.00
.00
.21
0.00
0.00
9.38
50.00
0.00
0.00
50.00
0.00
0.00
430.00
14.00
50.00
50.00
50.00
.01
0.00
50.00
3.80
50.00
50.00
0.00
3.00
.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
.53
.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
61.36
.00
.01
1.91
0.00
0.00
72.78
0.00
290.51
0.00
0.00
290.51
0.00
0.00
3001.23
148.14
290.51
290.51
290.51
.07
0.00
290.51
29.64
290.51
290.51
0.00
0.00
28.75
.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
5.71
.14
0.00
0.00
0.00
0.00
0.00
HIGH-CARBON ESTER - NONVOLATILE
PROBABLY AN OIL
LARGE POLYMER
LARGE POLYMER
RER DERIVED FROM AVG RER'S
HIGH-CARBON CMPD - ASSUMED NONVOL
HIGH CARBON SOLID
ASSUMED TO BE HIGH-C FATTY ACIDS
NEAR SOLID AT AMBIENT TEMP.
NO DATA - ASSUMED VOLATILE
HIGH-CARBON FATTY ACID-NONVOLATIL
VAXES ASSUMED NONVOLATILE
USED 2-ACETYL BENZOFURAN
VAXES ARE NONVOLATILE
KNOVN TO BE VOLATILE
SURROGATE - MONOETHYL ETHER
ASSUMED VOLATILE
KNOVN TO BE VOLATILE
RESINS ASSUMED NONVOLATILE
ASSUMED NONVOLATILE
SURROGATED I NENE
RESINS ASSUMED NONVOLATILE
SURROGATE-BUTYL BENZYL PHTHALATE
DETERGENT NONVOLATILE
VAXES ASSUMED NONVOLATILE
RESINS ASSUMED NONVOLATILE
LARGE POLYMER
POLYMERS ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
HIGH-CARBON ESTER - NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
LARGE POLYMER
SOAPS ARE NONVOLATILE
5-7
-------
TABLE 2 (Continued)
RELATIVE EVAPORATION SATES - ALPHABETICAL
PRODUCT NAME
BP (C) PRESSURE
NV
VP
8ER COMMENTS
PRESERVATIVES
PROCETYL AyS
PROPANE
H-PROPYL ALCOHOL
PROPYL P-HYDROXYBENZOATE
PROPYLENE GLYCOL
PROPYLENE GLYCOL DIPELA8GONATE
PROPYLENE GLYCOL 8ICINOLEATE
PROTEIN HYDROLYSATE
PVP-VA COPOLYHER E-73S
PYRETHRIN I
PYRETHRIN II
QUATERN1UN 26
EESYN 28-2930
RHOPLEX B
ROSIN
ROTEHONE
SALICYLANILIDE
SALICYLIC ACID
SANDOPAN DTC'ACID
SANDOPAN TFL CONCENTRATE
SAPAHINE COB-ST
SAPAHINE VL
SESAME OIL
-42.1
97.8
189
213
170
200
757
44.11
60.09
76.11
198.32
.1 328.46
.1 372.47
215
211
394.00
20 138.12
SILICONE DEFOAMER
SILICONS FLUID 220/350CS
SILICONE LE 452
SILICONE OIL 350 CS. 10000 CS
SINDAR TECHNICAL G4-40
SOAP
SODIUM DOOECYLBENZENE SULFONATE
SODIUH LAURYL SARCOSINATE
SODIUM LAURYL SULFATE
SODIUM Q-PHENYLPHENOLATE
SODIUH XYLENE SULFONATE
SOLVENTS
SORB I TAN MONOSTEARATE
SORBITOL
SPAN 80
SPAN 65
STEARATE EHULSIFIER
STEARIC ACID
STODDARD SOLVENT
STYRENATED ALKYD RESIN
SUNSCREEN AGENT
SURFACTANT NF
SURFACTANT «K
SYH-DI-BETA-NAPTHYL-P-PHENYL DIAM
295
383
50.00
5 182.18
428.61
284.47
50.00
0.00
0.00
8.50
15.41
.10
.08
0.00
0.00
0.00
.00
.00
0.00
0.00
0.00
.24
0.00
.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
50.00
0.00
0.00
0.00
0.00
0.00
50.00
0.00
0.00
0.00
0.00
0.00
46.39
98.17
.10
.75
.87
0.00
0.00
0.00
.00
.00
0.00
0.00
0.00
0.00
3.91
0.00
.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
290.51
0.00
0.00
0.00
0.00
0.00
0.00
290.51
0.00
0.00
0.00
0.00
0.00
FUNCTION IMPLIES NONVOLATILITY
HIGH-CARBON ASSUMED NONVOLATILE
NO DATA - ASSUMED VOLATILE
HIGH-CARBON ESTER - NONVOLATILE
ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
USED ABIETIC ACID - SOLID
HIGH CARBON - ASSUMED NONVOLATILE
HIGH-CARBON SALT
HIGH-CARBON SALT
STEARIC ACID AMIDE
STEARIC ACID AMIDE
HIGH-CARBON FATTY ACID
HIGH-CARBON ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
POLYMERS ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
SOAPS ARE NONVOLATILE
HIGH-CARBON SALT
LONG-CHAIN ESTER
HIGH-CARBON CMPD - NONVOLATILE
SALT
SALT
ASSUMED VOLATILE
HIGH-CARBON ESTE8 - NONVOLATILE
HIGH-CARBON SUGAR - NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
LONG-CHAIN ESTER
LONG-CHAIN FATTY ACID
KNOWN TO BE VOLATILE
RESINS ASSUMED NONVOLATILE
FUNCTION IMPLIES NGNVOLATILITY
ASSUMED NONVOLATILE
ASSUMED NONVOLATILE
GREASES
5-8
-------
TABLE 2 (Continued)
RELATIVE EVAPORATION RATES - ALPHABETICAL
PRODUCT NAME
BP (C) PRESSURE
VP
RER COMMENTS
TALL OIL
TARTAR1C ACID
TENSIOF1X (LX. VP)
TERGITOL ANIONIC 4
TERG1TOL NIN-FOAM
THICKENERS
THIURAH
THYMOL 233.92 2
TINOPAX ANA
TOLUENE 110.8
TRIBASIC LEAD MALEATE
TRIBUTOXYETHYL PHOSPHATE
TBIBUTTL PHOSPHATE
1,1,1-TRICHLOROETHANE 76
TRICHLOROETHYLENE 87
TRICRESYL PHOSPHATE
TRIETHANOL AH1NE OLEATE
TRIETHANOLAMINE 277 150
TRIETHYLENE GLYCOL 287.4
TRITON X-200
TURKEY RED OIL
TURPENTINE 155 136.23
TUEEN 81
UNDECYLENIC ACID
UREA CARBAMIDE
VEGETABLE OIL
UEQREZ S-71
VETTING AGENT
UHITE SPIRIT OR NAPTHA
VOOD FLOUR
XYLENE 144.4
XYLOL 144.4
ZINC DIMETHYL DITHIOCARBAMATE
ZINC NAPHTHENATE
ZINC UNDECYLENATE
0.00 0.00
168.10 0.00 0.00
0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00
150.22 .01 .09
0.00
92.10 21.48 169.35
0.00
0.00
0.00
133.41 100.00 949.09
131.29 66.08 622.12
368.37 .50 7.89
0.00 0.00
149.19 .00 .00
150.20 -.00 .00
0.00
0.00 0.00
3.00 28.75 40.92
0.00
0.00 0.00
0.00
0.00 0.00
0.00
0.00
50.00 50.00 290.51
0.00
106.17 5.00 42.33
106.17 5.00 42.33
0.00
0.00
0.00 0.00
RESINS ASSUMED NONVOLATILE
SOLID AT ROOM TENP
NO DATA - ASSUMED NONVOLATILE
NONVOLATILE SALT
NONVOLATILE SALT
FUNCTION IMPLIES NONVOLATILITY
CRYSTALLINE AT ROOM TEMP.
NO DATA - PROBABLY A SOLID
SALTS ASSUMED NONVOLATILE
SALT - ASSUMED NONVOLATILE
SALT - ASSUMED NONVOLATILE
UNION OIL DATA
HIGH-CARBON ESTER - NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
FATTY ACIDiNONVOLATILE
SURROGATED INENE
NO DATA - ASSUMED NONVOLATILE
HIGH-CARBON FATTY ACID
NO DATA - ASSUMED NONVOLATILE
ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
KNOVN TO BE VOLATILE
CELLULOSE AND LIGNITE-NONVOLATILE
SAME AS XYLENE
NO DATA - ASSUMED NONVOLATILE
METALLIC SALT
SALTS ASSUMED NONVOLATILE
5-9
-------
TABLE 3
RELATIVE EVAPORATION RATES - NUMERICAL
PRODUCT NAME
BP (C) PRESSURE
VP
RER COMMENTS
5-BENZYL-3-FURYL
AC POLYETHYLENE 6Z9
ACRYLIC RESIN
ACRYSOL LEVELING AID
AD1PIC ACID
ALCOHOL-SOLUBLE LANOLIN
ALKYO RESIN
ALKYL ARYL SODIUM SULFONATE
ALKYLDIHETHYLBENZYLAHMQNIUM
ALKYLDIMETHYLBENZYLAMMQNIUM CHLORIDE
ALLETHRIN, D-TRANS 302.41
ALUMINUM PHENYLSULFONATE
AKMONIUH CITRATE
AMMONIUM LAURYL ETHE5 SULPHATE
AHMOKIUM QXALATE
AHMONYX 4002
AMPHOHER
ANTARON FC-34
BAYGON
BEESUAX
BENZETHONIUH
BIOCIDE
BUTADIENE-STYRENE COPOLYMER
CALCIUM THIOGLYCOLATE TRIHYDRATE
CALGQN
CARBARYL
CARBOPQL 934
CARBOXYMETHYL CELLULOSE
CARNAUBA WAX
CARTARETINE F4
CAT ION1C CELLULOSE
CELLULOSE ACETATE BUTY8ATE
CERES IN
CETYL ALCOHOL. FLAKES 190.00
CHLOE. PARAFFIN PLASTICIZER
CHLORDANE
CHLOBOSULFONATED POLYETHYLENE
CITRIC ACID DECOMPOSES
COCAH1NO BETAINE
COCONUT ANIDOPROPYL-
3-DIMETHYLAMINE BETAINE
COCONUT OIL AMINE
COLOR
COLOR It IX
CONDANOL (DBS.DLS,MLS,SB/L)
COPPER UNDECYLENATE
CROHEEN
CRYSTALLINE UAX
CUBE RESINS
15.00
0.00 NO DATA - ASSUMED NONVOLATILE
0.00 0.00 LARGE POLYHER
0.00 0.00 RESINS ASSUMED NONVOLATILE
0.00 NO DATA - ASSUMED NONVOLATILE
0.00 H1GH-C FATTY ACIDS NONVOLATILE
0.00 0.00 HIGH-C FATTY CMPDS NONVOLATILE
0.00 0.00 RESINS ASSUMED NONVOLATILE
0.00 0.00 SALT
0.00 NO DATA - ASSUMED NONVOLATILE
0.00 SALTS ASSUMED NONVOLATILE
0.00 HIGH-CARBON ESTER-NONVOLATILE
0.00 0.00 SALTS ASSUMED NONVOLATILE
0.00 0.00 SALT ASSUMED NONVOLATILE
0.00 0.00 HIGH-CARBON SALT
142.11 0.00 0.00 NONVOLATILE SALT
0.00 0.00 VERY HIGH-CARBON COMPOUND
0.00 0.00 NO DATA - ASSUMED NONVOLATILE
0.00 0.00 POLYMERS ASSUMED NONVOLATILE
209.24 0.00 CRYSTALLINE-ASSUMED NONVOLATILE
0.00 0.00 WAXES ASSUMED NONVOLATILE
0.00 0.00 NO DATA - ASSUMED NONVOLATILE
0.00 NO DATA - ASSUMED NONVOLATILE
0.00 0.00 LARGE POLYHER NONVOLATILE
0.00 0.00 SALTS ASSUMED NONVOLATILE
0.00 NO DATA - ASSUMED NONVOLATILE
0.00 0.00 NONVOLATILE CRYSTAL AT ROOM TEMP
0.00 0.00 NO DATA '- ASSUMED NONVOLATILE
0.00 0.00 LARGE POLYMER
0.00 0.00 VAXES ASSUMED NONVOLATILE
0.00 NO DATA - ASSUMED NONVOLATILE
0.00 0.00 POLYMERS ASSUMED NONVOLATILE
0.00 0.00 LARGE POLYHER
0.00 NO DATA - ASSUMED NONVOLATILE
0.00 0.00 HIGH-CARBON ALCOHOL - NONVOLATILE
0.00 SURROGATE'BUTYL BENZYL PHTHALATE
409.78 0.00 FROM STRUCTURE, PROBABLY NON-VQL
0.00 POLYMERS ASSUMED NONVOLATILE
192.12 0.00 0.00 ASSUMED NONVOLATILE
0.00 0.00 LONG-CHAIN POLYHER
0.00 0.00 LONG-CHAIN POLYHER
0.00 0.00 HIGH-CARBON
0.00 0.00 NO DATA - ASSUMED NONVOLATILE
0.00 NO DATA - ASSUMED NONVOLATILE
0.00 0.00 NONVOLATILE SALT
0.00 0.00 HIGH-CARBON SALT - NONVOLATILE
0.00 0.00 NO DATA - ASSUMED NONVOLATILE
0.00 0.00 WAXES ASSUMED NONVOLATILE
0.00 0.00 RESINS ASSUMED NONVOLATILE
5-10
-------
TABLE 3 (Continued)
RELATIVE EVAPORATION BATES - NUMERICAL
PRODUCT NAME
BP (C) PRESSURE
MV
VP
RER COMMENTS
CYCLOPROPANE CARBOXYLATE
DC 193 FLUID
DEHYDBOGENATED RESIN
DETERGEKT
DIMETHYCGNE COPOLTGL
DITHIO-8IS-STEARYL PROPIONATE
DODECYL BENZENE SULFQNATE
DOU 276-V9
DRIERS
DUREZ (14000,16470.22008)
DUREZ (19788,12686,12687)
DUREZ (26141,26789,26799)
DUREZ 7421A
EDTA
ELASTOMERIC BINDER
EMOLLIENT
EMULPHOR QN-870
EHULSIFIERS, HUMECTANTS, WAXES
ENDOSULPHAN
ESSENTIAL CEDAR OIL
ETHOIYLATE TRIDECYL ALCOHOL
ETHOXYLATED FATTY'ALCOHOL SULFATE
ETHYLENE GLYCOL D1STEARATE
2-ETHYL HEXYL SALICYLATE
FATTY ACID AMIDES
FATTY ACID SOAP
FISH OIL
FLUILAN
FOAM STABILIZERS
FOLPET
FRACTAL A
GANTREZ E5 225 OR ES 425
GELVA (TS 22,23,30,31,85)
HARD VAXES
HOECHST VAX
HUHECTANTS
HYDROGENATED RESIN ESTER
HYDROXYALKYL CELLULOSE (KLUCEL HA
1SOPROPYL HYRISTATE
0-ISOPROXYPHENYL HETHYLCARBAMATE
KELTHANE
KELZAN
KOSOL
KP-140
LANETO 100
LANOLIN
LATEI POLYMER ACRYLIC RESIN
LAURIC ACID
LAURIC DIETHANOLAM1DE
296.56
192.60
370.49
20.00 270.46
131.00
1.00 200.33
0.00 USED CYPOTHRIN (HIGH-CARBON)
0.00 0.00 NO DATA - ASSUMED NONVOLATILE
0.00 0.00 RESINS ASSUMED NONVOLATILE
0.00 0.00 SURROGATE=SODIUN LAURYL SULFATE
0.00 0.00 POLYMERS ASSUMED NONVOLATILE
0.00 0.00 HIGH-CARBON ESTER - NONVOLATILE
0.00 0.00 HIGH-CARBON ESTER
0.00 NO DATA - ASSUMED NONVOLATILE
0.00 0.00 ASSUMED TO REMAIN IN THE COATINGS
0.00 0.00 PHENOL-FORMALDEHYDE RESIN
0.00 0.00 PHENOL-FORMALDEHYDE RESIN
0.00 0.00 PHENOL-FORMALDEHYDE RESIN
0.00 0.00 PHENOL-FORMALDEHYDE RESIN
0.00 NO DATA - ASSUMED NONVOLATILE
0.00 POLYMERS ASSUMED NONVOLATILE
0.00 0.00 PROBABLY NONVOLATILE
0.00 NO DATA - ASSUMED NONVOLATILE
0.00 0.00 FUNCTION IMPLIES NONVOLATILITY
0.00 NO DATA - ASSUMED NONVOLATILE
0.00 NO DATA - ASSUMED NONVOLATILE
0.00 0.00 LONG-CHAIN ALCOHOL
0.00 0.00 HIGH-CARBON ASSUME NONVOLATILE
0.00 0.00 LONG-CHAIN ESTER
0.00 0.00 HIGH-CARBON ACID - NONVOLATILE
0.00 0.00 SURROGATE'NYLON; ASSUMED NONVOLAT
0.00 0.00 SOAPS ASSUMED NONVOLATILE
0.00 0.00 ASSUMED NONVOLATILE
0.00 0;00 NO DATA - ASSUMED NONVOLATILE
0.00 NO DATA - ASSUMED NONVOLATILE
0.00 CRYSTALLINE-ASSUMED NONVOLATILE
0.00 NO DATA - ASSUMED NONVOLATILE
0.00 0.00 PROBABLY A RESIN - NONVOLATILE
0.00 POLYV1NYL ACETATE RESIN
0.00 0.00 VAXES ASSUMED NONVOLATILE
0.00 0.00 VAXES ASSUMED NONVOLATILE
0.00 0.00 FUNCTION IMPLIES NONVOLATILITY
0.00 0.00 RESINS ASSUMED NONVOLATILE
0.00 0.00 POLYMERS ASSUMED NONVOLATILE
0.00 0.00 HIGH-CARBON ESTER - NONVOLATILE
0.00 0.00 Cll COMPOUND ASSUMED NONVOLATILE
0.00 CRYSTALLINE-ASSUMED NONVOLATILE
0.00 0.00 POLYMERS ASSUMED NONVOLATILE
0.00 0.00 STARCH (POVDER)
0.00 NO DATA - ASSUMED NONVOLATILE
0.00 0.00 NO DATA - ASSUMED NONVOLATILE
0.00 0.00 ASSUMED NONVOLATILE
0.00 0.00 RESINS ASSUMED NONVOLATILE
0.00 0.00 HIGH-CARBON FATTY ACID-NONVOLATIL
0.00 0.00 HIGH-CARBON AMIDE - NONVOLATILE
5-11
-------
TABLE 3 (Continued)
BELATIVE EVAPORATION BATES - NUMERICAL
PRODUCT NAME
BP (C) PRESSURE
HU
VP
8ER COMMENTS
MBTS (2-BENZOTHIAZOLYL SULFIDE)
HETHOXYCHLOR
METHYL ANTHRANILATE
NETHYLBENZETHONIUM CHLORIDE
HICROCRYSTALLINE VAX
KILLED PALE CREPE
MILLED SMOKE RUBBER
MINERAL OIL
HIRANOL C2HSF
HONAMID 716
HONOGLYCEROL P-AN1NOBENZOATE
NEOPRENE
NITROCELLULOSE
N-OCTYL-BICYCLOHEPTENE DICARBOXIHIDE
OILS
OLEIC ACID 360.00
PALMITIC ACID 350,267
PARAFFIN WAXES
PETROLEUM AND SYNTHETIC UAXES
PHENOLIC RESIN
PLASTIC
PLASTICIZER (DGO-.3GH-)
PLURONIC F 108 DETERGENT
POLAVAX A 31
POLY-BETA-PINENE RESIN
POLYACRYLATE
POLYACRYL1C ACID (40% AQ.) N.U.10
POLYDIMETHYLSILOXANE
POLYETHOXYLATED (75 EQ) LANOLIN
POLYETHYLENE
POLYETHYLENE GLYCOL (400) HONOLAU
POLYOXYETHYLENE SORBITAN MONOSTEARATE
POLYQUATERNIUM 4
POLYTRIMETHYLDIHYDRO-QUINOLI ME
POLYVINYL ACETATE
POTASSIUM SOAP OF OLEIC ACID
PRESERVATIVES
PROCETYL AUS
PROPYLENE GLYCOL RICINOLEATE
PROTEIN HYDROLYSATE
PVP-VA COPOLYMER E-735
QUATERNIUM 26
RESYN 2B-2930
RHOPLEX B
ROSIN
SALICYLANILIDE
SANDOPAN DTC ACID
SANDOPAN TFL CONCENTRATE
SAPAHINE COB-ST
282.46
100.00 256.43
332.47 0.00 CRYSTALLINE AT ROOM TEMP.
0.00 0.00 NONVOLATILE CRYSTAL AT ROOM TEHP
0.00 0.00 NO DATA - ASSUMED NONVOLATILE
0.00 0.00 SALTS ASSUMED NONVOLATILE
0.00 0.00 UAXES ASSUMED NONVOLATILE
0.00 0.00 SOLID AT AMBIENT TEMPERATURE
0.00 0.00 SOLID AT AMBIENT TEMPERATURE
0.00 0.00 NO DATA - ASSUMED NONVOLATILE
0.00 0.00 HIGH-CARBON SALT
0.00 0.00 NO DATA - ASSUMED NONVOLATILE
0.00 0.00 HIGH-CARBON ESTER - NONVOLATILE
0.00 0.00 LARGE POLYMER
0.00 0.00 LARGE POLYMER
0.00 HIGH-CARBON CMPD - ASSUMED NONVOL
0.00 0.00 ASSUMED TO BE HIGH-C FATTY ACIDS
0.00 0.00 NEAR SOLID AT AMBIENT TEMP.
0.00 0.00 HIGH-CARBON FATTY ACIO-NONVOLATIL
0.00 0.00 UAXES ASSUMED NONVOLATILE
0.00 0.00 UAXES ARE NONVOLATILE
0.00 0.00 RESINS ASSUMED NONVOLATILE
0.00 0.00 RESINS ASSUMED NONVOLATILE
312.36 0.00 0.00 SURROGATE=BUTYL BENZYL PHTHALATE
0.00 0.00 DETERGENT NONVOLATILE '
0.00 0.00. UAXES ASSUMED NONVOLATILE
0.00 0.00 RESINS ASSUMED NONVOLATILE
0.00 0.00 LARGE POLYMER
0.00 0.00 POLYMERS ASSUMED NONVOLATILE
0.00 POLYMERS ASSUMED NONVOLATILE
0.00 0.00 POLYMERS ASSUMED NONVOLATILE
0.00 POLYMERS ASSUMED NONVOLATILE
0.00 0.00 POLYMERS ASSUMED NONVOLATILE
0.00 0.00 HIGH-CARBON ESTER - NONVOLATILE
0.00 0.00 POLYMERS ASSUMED NONVOLATILE
0.00 0.00 POLYMERS ASSUMED NONVOLATILE
0.00 0.00 LARGE POLYMER
0.00 0.00 SOAPS ARE NONVOLATILE
0.00 0.00 FUNCTION IMPLIES NONVOLAT1L1TY
0.00 0.00 HIGH-CARBON ASSUMED NONVOLATILE
0.00 0.00 HIGH-CARBON ESTER - NONVOLATILE
0.00 0.00 ASSUMED NONVOLATILE
0.00 0.00 POLYMERS ASSUMED NONVOLATILE
0.00 0.00 POLYMERS ASSUMED NONVOLATILE
0.00 0.00 POLYMERS ASSUMED NONVOLATILE
0.00 0.00 POLYMERS ASSUMED NONVOLATILE
0.00 USED AB1ET1C ACID - SOLID
0.00 0.00 HIGH CARBON - ASSUMED NONVOLATILE
0.00 HIGH-CARBON SALT
0.00 0.00 HIGH-CARBON SALT
0.00 0.00 STEARIC ACID AMIDE
5-12
-------
TABLE 3 (Continued)
RELATIVE EVAPORATION RATES - NUMERICAL
PRODUCT NAME
BP (C) PRESSURE
HU
VP
RER COMMENTS
SAPAH1NE UL 0.00
SESAME OIL 0.00
SEV1N
S1LICONE OEFOAMER
SILICQNE FLUID 220/350CS 0.00
SUICONE LE 452 0.00
SILICONE OIL 350 CS, 10000 CS 0.00
SINDAB TECHNICAL 64-40
SOAP
SODIUM DODECYLBENZENE SULFONATE 0.00
SODIUM LAURYL SARCOSINATE 0.00
SODIUM LAURYL SULFATE 0.00
SODIUM 0-PHENYLPHENOLATE 0.00
SODIUM XYLENE SULFONATE 0.00
SORBITAN HONOSTEARATE 0.00
SORB1TOL 295.00 5.00 182.18 0.00
SPAN 80 428.61 0.00
SPAN 85 0.00
STEABATE EMULSIFIES
STEARIC ACID 383.00
STYRENATED ALKYD RESIN
SUNSCREEN AGENT
SURFACTANT NF
SURFACTANT UK
SYM-DI-BETA-NAPTHYL-P-PHENYL DIAN
TALL OIL
TARTAR1C ACID 168.10
TENS!OFIX (LX. UP)
TERGITOL ANIONIC 4
TERGITOL MIN-FOAH
THICKENERS
THIURAM
TINOPAX ANA
TRIBASIC LEAD NALEATE
TRIBUTOXYETHYL PHOSPHATE
TRIBUTYL PHOSPHATE
TRIETHANOL AHINE OLEATE 0.00
TRITON X-200
TURKEY RED OIL 0.00
TUEEN81
UNDECYLENIC ACID 0.00
UREA CARBAMIDE
VEGETABLE OIL 0.00
VEOREZ S-71
VETTING AGENT
VOOD FLOUR
ZINC DIMETHYL DITHIOCARBAMATE
ZINC UNDECYLENATE 0.00
PYRETHRIN I 170.00 .10 328.46 .00
284.47 0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00 STEARIC ACID AMIDE
0.00 HIGH-CARBON FATTY ACID
0.00 HIGH-CARBON ASSUMED NONVOLATILE
0.00 NO DATA - ASSUMED NONVOLATILE
0.00 POLYMERS ASSUMED NONVOLATILE
0.00 POLYMERS ASSUMED NONVOLATILE
0.00 POLYMERS ASSUMED NONVOLATILE
0.00 NO DATA - ASSUMED NONVOLATILE
0.00 SOAPS ARE NONVOLATILE
0.00 HIGH-CARBON SALT
0.00 LONG-CHAIN ESTER
0.00 HIGH-CARBON CHPD - NONVOLATILE
0.00 SALT
0.00 SALT
0.00 HIGH-CARBON ESTER - NONVOLATILE
0.00 HIGH-CARBON SUGAR - NONVOLATILE
0.00 NO DATA - ASSUMED NONVOLATILE
0.00 NO DATA - ASSUMED NONVOLATILE
0.00 LONG-CHAIN ESTES
0.00 LONG-CHAIN FATTY ACID
0.00 RESINS ASSUMED NONVOLATILE
0.00 FUNCTION IMPLIES NONVOLATILE
0.00 ASSUMED NONVOLATILE
0.00 ASSUMED NONVOLATILE
0.00 GREASES
0.00 RESINS ASSUMED NONVOLATILE
0.00 SOLID AT ROOM TEMP
0.00 NO DATA - ASSUMED NONVOLATILE
0.00 NONVOLATILE SALT
0.00 NONVOLATILE SALT
0.00 FUNCTION IMPLIES NONVOLATILE
0.00 CRYSTALLINE AT ROOM TEMP.
0.00 NO DATA - PROBABLY A SOLID
0.00 SALTS ASSUMED NONVOLATILE
0.00 SALT - ASSUMED NONVOLATILE
0.00 SALT -ASSUMED NONVOLATILE
0.00 HIGH-CARBON ESTER - NONVOLATILE
0.00 NO DATA - ASSUMED NONVOLATILE
0.00 FATTY AC ID:NONVOLATILE
0.00 NO DATA - ASSUMED NONVOLATILE
0.00 HIGH-CARBON FATTY ACID
0.00 NO DATA - ASSUMED NONVOLATILE
0.00 ASSUMED NONVOLATILE
0.00 NO DATA - ASSUMED NONVOLATILE
0.00 NO DATA - ASSUMED NONVOLATILE
0.00 CELLULOSE AND LIGNITE-NONVOLATILE
0.00 NO DATA - ASSUMED NONVOLATILE
0.00 SALTS ASSUMED NONVOLATILE
.00
5-13
-------
TABLE 3 (Continued)
RELATIVE EVAPORATION RATES - NUMERICAL
PRODUCT NAHE
BP (C) PRESSURE
HU
VP
RER COMMENTS
PYRETHRIN 1!
PIPERONYL BUTOX1DE
HALATHION
DIOCTYL PHTHALATE PLASTIC12ER
HYRJSTIC ACID
SALICYLIC ACID
TRIETHANOLAHINE
0-BENZYL-P-CHLOROPHENOL
GLYCEROL
DIBUTYL PHTHALATE
TRIETHYLENE GLYCOL
BENZYL BENZOATE
AMPD
2,4 BIS (ISOPROPYLAMINO)-6
HETHOXY-S-TRIAZINE
4-ANINO-3,5,6-TRICHLQROPia!LlNIC
2,4,5-TRICHLOROPHENOXYACETIC
ACID, POTASSIUM SALT
Cl.S.P. COMPOUNDS
COPPER NAPHTHENATE
BROMOC1L
GRANULAR MINERAL BASE
ISOOCTYL ESTERS
ISOBUTYLENE POLYMERS
HONURON
PICLORAM
ZINC NAPHTHENATE
2-FUHALDEHYDE. 2,3:4,5-813-
(2-BUmENE) TETRAHYDRO
HYRISTIL ALCOHOL
HGK
2-ETHYL-l,3-HEXANEDIOL
N,N-DIALKYL-H-TQLUAMIDE
OIETHYLENE GLYCOL
BEN20IC ACID
PETREI 7-75T (DRY)
ALKYL DIETHANOLAHINE
THYMOL
DIPROPYLENE GLYCOL
PROPYL P-HYDROXYBENZOATE
DDVP
POLYOIYETHYLENE (2) CETYL ETHER
MONOETHYLENE GLYCOL
ETHYLENE GLYCOL
METHYL P-HYDROXYBENZOATE
PROPYLENE GLYCOL
PROPYLENE GLYCOL DIPELARGONATE
CRESOL <0-,N-,P->
MENTHOL
200.00
180.00
156.50
385.00
250.50
211.00
277.00
161.00
DECOMPOSES (
340.00
287.40
323.50
151.20
ACID
307.00
263.20
307.00
244.00
160.00
245.00
249,133
136.00
233,92
292/232
140.00
270.00
198.00
198.00
223.30
189.00
213.00
216.00
.10
1.00
.70
100.00
20.00
150.00
3.50
1 290
10.00
19.00
10.00
11.00
2.00
20.00
757.00
372.47
338.44
330.35
390.56
228.38
138.12
149. 19
218.68
92.11
278.35
150.20
212.25
105.14
204.27
214.40
204.27
146.23
191.27
106.12
122.13
234.30
88.13
150.22
134.20
220.98
466.89
62.10
62.10
152.15
76.11
196.32
108. 13
156.27
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
0.00
.00
.00
.00
.00
.00
.00
.01
.01
.01
.01
.01
.01
.06
.06
.07
.10
.08
.11
.15
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
,00
.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
.01
.01
.01
.02
.02
.02
.03
.07
.07
.09
.10
.10
.11
.14
.39
.39
.67
.75
.87
.96
1.54
ASSUMED NONVOLATILE
SALT- ASSUMED NONVOLATILE
NO DATA - ASSUMED NONVOLATILE
METALLIC SALT
SOLID - ASSUMED NONVOLATILE
SOLID - ASSUMED NONVOLATILE
FAIRLY HIGH CARBON ESTER
POLYMER - ASSUMED NONVOLATILE
PROBABLY AN OIL
ASSUMED NONVOLATILE
METALLIC SALT
MGK 11 USED AS TYPICAL COMPOUND
USED N,N-DIETHYL-M-TOLUAN!DE
USED 2-ACETYL BENZOFURAN
USED ETHYL DIETHANOLAHINE
REH SHOULD BE < 0. 1
NO DATA - ASSUMED VOLATILE
RER DERIVED FROM AVG SER'S
5-14
-------
TABLE 3 (Continued)
RELATIVE EVAPORATION HATES - HUMES1CAL
PRODUCT NAME
BP (C) PRESSURE
VP
RER COMMENTS
NAPHTHALENE
CARBITOL
2-AH1HO-2-HETHYL PROPANOL
ETHANOLAMINE
L-CAHPHOR
D.L-CAHPHOR
D-CAHPHQR
AMP
ROTENONE
D1PROPYLENE GLYCOL MONOMETHYL ETH
Bl/TYL CELLOSOLVE
ETHYLEME GLYCOL MONOBUTYL ETHER
POLY1SOBUTYLENE (TRI-.TETRAMER-
TRICRESYL PHOSPHATE
Q-DICHLOROBENZENE
CELLQSOLVE ACETATE
217.90
202.00
165.50
172.00
SUBLiHES 9
SUBLIMES
SUBLIHES 8
.165.00
215.00
187.20
170.00
)
180.50
156.00
DIETHYLENE GLYCOL HONOMETHYL ETHE 159.00
AHYL ACETATE
PINE OIL
PETROLEUM ETHERS
MONO ETHYL ETHER
ETHYLENE GLYCOL HONOETHYL ETHER
GLYCOL ETHER
TURPENTINE
XYLENE
XYLOL
PROPANE
NORPHOLINE :
ACETIC ACID
HITROPROPANE (1-.2-)
CHLOi-AROHATIC SOLVENTS
H-PROPYL ALCOHOL
DICHLOROPENTANE
PERCHLOROETHYLENE
TOLUENE
AROMATIC HYDROCARBONS
AROMATIC KETONE SOLVENT
ISOPROPANOL
ISQPSOPYL ALCOHOL
ETHANOL
ETHYL ALCOHOL
ETHYL ALCOHOL OP
ALCOHOL 740 P
CHLORINATED SOLVENTS
DEODORANT
ESSENTIAL OIL
ESTE8S AND KETONES (ACETONE)
FRAGRANCE
FRAGRANCE, DYE
148.00
155.00
135.00
155.00
144.40
144.40
-42.10
128.00
118.10
97.80
121.40
110.80
82.40
82.40
78.50
78.40
78.40
128.16
134.20
89.14
61.06
152.24
152.24
152.24
89.14
394.00
162.23
118.17
118.17
196.38
368.37
147.00
132.16
120.15
737.00 130.20
136.23
90.10
90.10
90.10
90.10
136.23 3.00
106.17
106.17
44.11
87.12
60.05
69.09
112.56
60.09
141.04
165.83
92.10
92.10
92.10
60.10
60.10
46.07
46.07
46.07
50.00
50.00
50.00
50.00
50.00
50.00
50.00
.21
.21
.33
.40
.28
.28
.28
.44
.24
.46
.60
.60
.53
.50
.89
1.20
1.88
3.05
3.00
3.80
3.80
3.80
3.80
28.75
5.00
5.00
8.50
8.00
10.63
9.38
8.80
15.41
14.02
14.00
21.48
22.00
22.00
34.82
34.82
43.90
43.90
43.90
50.00
50.00
50.00
50.00
50.00
50.00
50.00
1.91
1.99
2.53
2.57
2.81
2.81
2.81
3.41
3.91
4.76
5.36
5.36
5.71
7.89
8.89
11.34
16.96
28.55
28.75
29.64
29.64
29.64
29.64
40.92
42.33
42.33
46.39
61.36
67.68
72.78
76.72
98.17
136.81
148.14
169.35
173.49
173.49
221.79
221.79
244.84
244.84
244.84
290.51
290.51
290.51
290.51
290.51
290.51
290.51
E.G. HQNOBUTYL ETHER
UNION OIL DATA
USED N-AMYLACETATE
SURROGATED I NENE
SURROGATE = MONOETHYL ETHER
SURROGATE 'E.G. HONOETHYL
SURROGATED 1NENE
SAME AS XYLENE
RER DERIVED FROM AVG RER'
ETHER
S
SURROGATE'HQNOCHLOROBENZENE
RER DERIVED FROM AVG RER'
SURROGATE * XYLENE
SURROGATE - XYLENE
SAME AS ETHANOL
S
NO DATA - ASSUMED VOLATILE
5-15
-------
TABLE 3 (Continued)
RELATIVE EVAPORATION RATES - NUMERICAL
PRODUCT NAME
BP (C) PRESSURE
VP
RER COMMENTS
HALQGENATED HYDROCARBON PROPELLAN
KEROSENE
MINERAL SPIRITS
PERFUME
PERFUME IN ALCOHOL
PERFUME OIL
PETROLEUM DISTILLATE (NAPHTHA)
PETROLEUM OIL
PETROLEUM SOLVENTS
SOLVENTS
STODDARD SOLVENT
WHITE SPIRIT OR NAPTHA
N-ACETYLETHANOLAH1NE
NONYLPHENOXT ACETIC ACID
OXYGENATED ORGANIC ACIDS
ALIPHATIC HYDROCARBONS
ALIPHATIC THINNER
NETHYL ALCOHOL
ETHYLENE D I CHLORIDE
TRICHLOROETHYLENE
ACETONE
U.l-TRICHLOROETHANE
1SOPARAFFINIC SOLVENT
AMINES
INERT INGREDIENTS (PESTICIDES)
DICHLOROMETHANE
METHTLENE CHLORIDE
PENTANE
DIHETHYLENE OXIDE
HYDROCARBON PROPELLANT
BUTAIE
ISOBUTANE
FORMALDEHYDE
FORMALIN
DIMETHYL ETHER
65.00
83.50
87.00
56.20
76.00
60.30
41.00
41.00
-.10
-.50
-20.00
-20.00
-25.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
86.17
86.17
32.04
99.00
131.29
58.08
133.41
86.18
73.14
34.93
84.93
72.15
44.05
58.12
58.12
58.12
30.00
30.00
46.70
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
92.39
61.00
66.08
132.49
100.00.
168.34
200.00
349.00
365.66
430.00
1095.00
1544.67
1544.67
1566.19
3243.38
3243.38
3581.69
290.51
290.51
290.51
290.51
290.51
290.51
290.51
290.51
290.51
290.51
290.51
290.51
290.51
290.51
290.51
381.38
381.38
429.70
498.72
622.12
829.65
949.09
1284.09
1405.47
1511.56
2642.83
2768.98
3001.23
5971.73
9676.33
9676.33
9811.14
14597.26
14597.28
20112.19
KNOUN TO BE VOLATILE
KNOUN TO BE VOLATILE
KNOUN TO BE VOLATILE
ASSUMED VOLATILE
KNOUN TO BE VOLATILE
ASSUMED VOLATILE
KNOWN TO BE VOLATILE
KNOUN TO BE VOLATILE
HIGH CARBON SOLID
NO DATA - ASSUMED VOLATILE
USED HEXANE AS REPRESENTATIVE
USED HEXANE AS REPRESENTATIVE
SURROGATE - ISQHEXANE
SURROGATE D1ETHTLAMINE
RER=UTD AVG OF TYPICAL INGRED.(2)
SAME AS NETHYLENE CHLORIDE
SURROGATE:BUTANE
5-16
-------
Table 4
VOC AND PROC EMISSIONS IN CALIFORNIA
PRODUCT
MILLION AVG. UEIGHT FRACTION
UNITS PROD. NATIONAL GEOGR. VOC PROC
DISTRI VT. CONSUMPTION POP. MULT I-
BUTED (LB) (MILLION LB) APPORT. PLIER LOU HIGH LOU HIGH LOU HIGH
TOTAL VOC EMISSIONS TOTAL PROC EMISSIONS
(TONS) (TONS)
LOU HIGH
Oi
i
AEROSOL/NON-AEROSOL PRODUCTS (t)
INSECT SPRAY PRODUCTS
INSECT SPRAYS (AEROSOL AND
NON-AEROSOL)
FORMULATIONS 2,8
INSECT REPELLENTS (AEROSOL AND
NON-AEROSOL)
FORMULATIONS 1,5
MOTH CONTROL PRODUCTS (AEROSOL
AND NON-AEROSOL)
FORMULATIONS 1,2
ANIMAL INSECTICIDES (AEROSOL
AND NON-AEROSOL)
FORMULATIONS 3,4
SUB-TOTAL
PAINTS AND FINISHES
PAINTS, PRIMERS, VARNISHES
FORMULATIONS 5,6
FORMULATIONS 3,6
OTHER RELATED PRODUCTS
FORMULATIONS 1
SUB-TOTAL
HOUSEHOLD PRODUCTS
ROOM DEODORANTS AND DIS-
INFECTANTS (AEROSOL AND NON-
AEROSOL)
FORMULATIONS 2,4
FORMULATIONS 1,4
300.60
300.60
.75
.75
6.9 .69
265.50 .50
265.50 .50
192.5 .11 1.00 .05 1.00 0.00 1.00 529.38 10587.50 0.00 10587.50
12.00 .11 1.00 .35 .65 .35 .65 230.34 561.00 230.34 561.00
39.00 .11 1.00 .96 1.00 .96 1.00 2059.20 2136.42 2059.20 2136.42
6.00 .11 1.00 .55 1.00 .55 1.00 181.50 329.01 181.50 329.01
3000.4! 13613.93 2471.04 13613.93
.11 1.15 .73 .87
.11 1.15 .67
.11 1.00 .65 .65 .65
10423.85 12391.69
.87
9554.01 12391.69
.65 170.21 170.21 170.21 170.21
10594.06 12561.90 9724.21 12561.90
.11 .94 .35 i.OO 2436.43 6863.17
.11 - .94 .35 .87 2436.43 5970.96
-------
Table 4 (Continued)
VOC AND PROC EMISSIONS IN CALIFORNIA
PIODUCT
CLEANERS
TILE AND BATHROOM CLEANERS
FORMULATIONS 1,2,3,4,5 (2)
FORMULATIONS 2,3,4,5 (2)
MILLION AVG.
UNITS PROD.
DISTRI VT.
BUTED (LB)
NATIONAL
CONSUMPTION
(MILLION LB)
65.00
65.00
POP.
APPORT.
.11
.11
HEIGHT FRACTION
GEOGR. VOC PROC
MULTI-
PLIER LOV HIGH LOU HIGH
i.OO 0.00 .33
1.00 , 0.00 .33
TOTAL VOC EMISSIONS TOTAL PROC EMISSIONS
(TONS) (TONS)
LOU HIGH -LOV HIGH
0.00 1179.75
0.00 1179.75
Cn
I
00
OVEN CLEANERS (AEROSOL AND
NON-AEROSOL)
FORMULATIONS 3,4
RUG AND UPHOLSTERY CLEANERS
(AE80SOL AND NON-AEROSOL)
FORMULATIONS 1,3
ALL PURPOSE CLEANERS
(AEKOSOL AND NON-AEROSOL)
FORMULATIONS 1,2
UINDOU AND GLASS CLEANERS
(AEROSOL AND NON-AEROSOL)
FORMULATIONS 6,7
LAUNDRY PRODUCTS-AEROSOLS
STARCH, FABRIC FINISH
FORMULATIONS 1,2
LAUNDRY PRODUCTS
(AEROSOL AND NON-AEROSOL)
PREUASH STAIN REMOVERS
FORMULATIONS 1,2
SPOT REMOVERS
FORMULATIONS 1,2
UAXES AND POLISHES
FORMULATIONS 1,3
ALL OTHER HOUSEHOLD SPRAY PRODUCTS
FORMULATIONS
109.90 .75
33.00 .11 1.02 0.00 .20 0.00 .20 0.00 370.26 0.00 370.26
115.00 .11 1.00 .03- .26 .03 .26 215.05 1644.50 215.05 1644.50
512.00 .11 1.07 .02 .41 .02 .41 602.62 12323.66 602.62 12323.66
174.00 .11 .98 0.00 .42 0.00 .42 0.00 3939.01 0.00 3939.01
.11 1.00 .05 .11 .05 .11 222.14 507.74 222.14 507.74
45.2 .75
84.00 .11 1.00 0.00 0.00 0.00 0.00
2.30 .11 1.00 1.00 1.00 .90 1.00
58.00 .11 .95 .07 .34 .07 .34
.11 1.00
0.00 0.00 0.00 0.00
126.50 126.50 113.65 126.50
212.14 1030,37 212.14 1030.37
NA (4) NA NA NA
-------
Table 4 (Continued)
VOC AND PROC EMISSIONS IN CALIFORNIA
PRODUCT
MILLION AVG. VEIGHT FRACTION
UNITS PROD. NATIONAL GEOGR. VOC PROC
DISTRI UT. CONSUMPTION POP. HULJI-
BUTED (LB) (MILLION LB) APPORT. PLIER LOU HIGH LOU HIGH
TOTAL VOC EMISSIONS TOTAL PROC EMISSIONS
(TONS) (TONS)
LOU HIGH
LOU
HIGH
U1
SHOE POLISHES, UAXES AND COLOR-
ANTS (AEROSOL AND NON-AEROSOL)
FORMULATIONS 1,2
ANTISTATIC SPRAYS
FORMULATIONS 1,2
ADHESIVES (5)
(AEROSOL AND NON-AEROSOL)
FORMULATIONS 2,3,6 (2)
CAULKING AND SEALING CPDS (5)
(AEROSOL AND NON-AEROSOL)
FORMULATIONS 1,2
CARPET DEODORIZERS
(AEROSOL AND NON-AEROSOL)
FORMULATIONS 1
DRAIN OPENERS
(AEROSOL AND NON-AEROSOL)
LIQUIDS
FORMULATIONS 2 (NO VOC)
SOLIDS
FORMULATIONS 1
SUB-TOTAL
PERSONAL PRODUCTS
SHAVING LATHERS
FORMULATIONS 2,4
HAIR SPRAYS
FORMULATIONS 1,4
FORMULATIONS 4,5
STYLING MOUSSE
FORMULATIONS 1
270.70
270.70
6.00 .11 1.00 .13 .98 .13 .96 42.90 323.40 42.90 323.40
3.00 .11 1.00 0.00 .03 0.00 \03 0.00 4.95 0.00 4.95
3277.50 .11 1.00 0.00 .85 0.00 .85 0.00 153223.12 0.00 153223.12
432.80 .11 1.00 0.00 .20 0.00 .20 0.00 4760.80 0.00 4760.80
65.00 .11 .96 .02 .02 .02 .02 68.64 68.64 68.64 68.64
17 (HIL.GAL.) .11 .94 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
293.00 .11 .94 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
3926.41 186365.88 3913.76 185473.67
162.80 .50
.63
.63
106.10 .38
.11
.11
.11
.11
1.01 .03 .09 .03 .09 140.17 402.44 140.17 402.44
.93 .88 .97
.93 .73
7685.11 8505.09
.97 6376.64 6505.09
1.00 .24 .24 .24 .24 543.29 543.29 543.29 543.29
-------
Table 4 (Continued)
VOC AND PROC EMISSIONS IN CALIFORNIA
IS]
o
PIODUCT
MILLION AVG. HEIGHT FRACTION TOTAL VOC EMISSIONS TOTAL PROC EMISSIONS
UNITS PiOD. NATIONAL GEOGt. VOC PROC (TONS) (TONS)
DISTRI HT. CONSUMPTION POP. HULTI-
BUTED (LB) (MILLION LB) APPORT. PLIER LOV HIGH LOU HIGH LOU HIGH LOU HIGH
OTHER HAIR CARE PRODUCTS-SHAMPOO
(AEROSOL AND NON-AEROSOL)
FORMULATIONS 1,2,3 (2)
PHARMACEUTICALS
FORMULATIONS 1,3
FORMULATIONS 2,3
COLOGNES
FORMULATIONS 1
PERFUMES
FORMULATIONS 1
AFTERSHAVES
FORMULATIONS 1
PERSONAL DEODORANTS AND ANTI-
PERSPIRANTS
FORMULATIONS 1,2
OTHER PERSONAL CARE PRODUCTS
SUNTAN LOTIONS (2)
FORMULATIONS 1,4,5 (2)
DEPILATORIES
FORMULATIONS 1,2
SUB-TOTAL
ANIMAL PRODUCTS
VETERINARIAN AND PET PRODUCTS
SUB-TOTAL
43.70
43.70
44.00
82.00
23.00
.25
.25
.12
.03
.25
644.60 .11
.11
.11
.11
.11
.11
1.00
1.08
1.08
1.00
1.00
1.00
0.00
.70
1.00
1.00
.65
156.00 .25
15.1
15.10
AUTOMOTIVE AND INDUSTRIAL PRODUCTS
REFRIGERANTS
CLEANERS (AEROSOL AND NON-AEROSOL)
FORMULATIONS 4,7 14.70
.13
.13
.11
.11
.11
0.00
453.61
177.27
645.70
0.00 177.27
.70 .99
453.61 645.70
02.50 302.50 302.50 302.50
35.30 135.30 135.30 135.30
04.93 204.93 204.93 204.93
.86 .80 .95 .80 .95 1475.76 1752.46 1475.76 1752.46
1.16 0.00 .65 0.00 .65
1.03 .10 .10 .10 .10
0.00
81.41
0.00
81.41
11.12 11.66 11.12 11.68
10951.80 12762.06 9643.32 12762.06
NA
0.00
NA
0.00
NA
0.00
NA
0.00
.88
.11
NA NA NA NA
1.00 0.00 1.00 0.00 1.00 0.00 707.44 0.00 707.44
-------
Table 4 (Continued)
VOC AND PROC EMISSIONS IN CALIFORNIA
PRODUCT
MILLION AV6.
UNITS PROD.
DISTRI VT.
BUTED (LB)
NATIONAL GEM 8.
CONSUMPTION POP. MULTI-
(MILLION LB) APPORT. PLIER LOU HIGH
VEIGHT FRACTION
VOC PSOC
TOTAL VOC EMISSIONS TOTAL PROC EMISSIONS
(TONS) (TONS)
LOU HIGH
LOU
HIGH
LOU
HIGH
I
ro
ENGINE DEGREASERS
FORMULATIONS 1,2,3 (2) 23.90 .88
FORMULATIONS 3 23.90 .88
LUBRICANTS AND SILICONES
FORMULATIONS 1,2 75.40 .44
UNDERCOAT INGS
FORMULATIONS 1 8.30 .75
BRAKE CLEANERS
FORMULATIONS 1, 2, or 3 16.60 1.13
TIRE SEALANTS AND INFLATORS
FORMULATIONS 19.30 .69
CARBURETOR AND CHOKE CLEANERS
FORMULATIONS 2,3 39.80 .75
ENGINE STARTING FLUIDS
FORMULATIONS 1 30.80 .56
UINDSHIELD DEICER (AEROSOL AND NON)
FORMULATIONS 1,2 10.40 1.00
OTHER AUTO AND INDUSTRIAL PRODUCTS
SUB-TOTAL
MISCELLANEOUS PRODUCTS
HERBICIDES AND FUNGICIDES
FORMULATIONS 1,7
SUB-TOTAL
NON-AEROSOL PRODUCTS
PERSONAL PRODUCTS
NAIL POLISHES
NAIL POLISH REMOVERS
69.00
.11
.11
.11
.11
.11
.11
.11
.11
.11
.11
1.00 .69 1.00
1.00 .75 1.00
1.00 0.00 1.00 0.00 1.00
1.00 .25 .65 .25 .85
1.00 1.00 1.00 1.00 1.00
1.00
i.OO .28 1.00 .28 1.00
1.00 1.00 1.00 1.00 1.00
1.00 .75 i.OO .75 1.00
1025.97 1150.19
862.64 1150.19
0.00 1824.68 0.00 1824.68
85.59 291.02 65.59 291.02
1031.69 1031.69 1031.69 1031.69
NA NA NA NA
459.69 1641.75 459.69 1641.75
948.64 948.64 948.64 948.64
429.00 572.00 429.00 572.00
NA NA NA NA
3980,58 8167.40 3817.25 8167.40
1.00 0.00 .95 0.00 .95
0.00 3605.25
0.00 3605.25
0.00 3605.25
0.00 3605.25
NA
NA
NA
NA
NA
NA
NA
NA
-------
Table 4 (Continued)
VOC AND PROC EHISSIONS IN CALIFORNIA
PRODUCT
MILLION AVG.
UNITS PROD.
OISTBI UT.
BUTED (Lfi)
NATIONAL GEOGR.
CONSUMPTION POP. MULT I-
(HILLION LB) APPORT. PLIER
HEIGHT FRACTION
VOC PROC
LOU HIGH LOU HIGH
TOTAL VOC EMISSIONS TOTAL PROC EMISSIONS
(TONS) (TONS)
LOV
HIGH
LOU
HIGH
Ui
i
PERSONAL DEODORANTS AND ANTI-
PIRSPIRANTS
SHAVING LATHERS
PRE-SHAVE PREPARATIONS
AFTER-SHAVE LOTIONS & COLOGNES
(LISTED UNDER AEROSOL)
PERFUMES
(LISTED UNDER AEROSOL)
RUBBING COMPOUNDS (ALCOHOL)
FACE WASHES (LIKE ASTRINGENTS)
FACIAL CREAMS AND WASHES
HAND LOTIONS
SUN LOTIONS, CREAMS AND OILS
(LISTED UNDER AEROSOL)
HOUTHUASHES
HAIR SPRAYS
HAIR SHAMPOOS, RINSES AND OTHER
HAIR PRODUCTS
SUB-TOTAL
HOUSEHOLD PRODUCTS
SHOE POLISHES
BALL POINT AND POROUS POINT PENS
ROOM DEODORANTS AND DISINFECTANTS
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.00
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.00
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.00
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.00
NA
NA
NA
CLEANERS
OVEN CLEANERS
RUG AND UPHOLTERV CLEANERS
UINDOU AND GLASS CLEANERS
FLOOR CLEANERS
TILE AND BATHROOM CLEANERS
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
-------
Table 4 (Continued)
VOC AND PROC EMISSIONS IN CALIFORNIA
PRODUCT
HILLION AVG.
UNITS PtOD.
DISTRI UT.
BUTED (LB)
NATIONAL GEOGR.
CONSUMPTION POP. MULT I-
(HILLION LB) APPORT. PLIER LOU HIGH
WEIGHT FRACTION
VOC PROC
TOTAL VOC EMISSIONS TOTAL PROC EMISSIONS
(TONS) (TONS)
LOU HIGH
LOU
HIGH
LOU
HIGH
Ol
i
LJ
UALL CLEANERS
UAXES AND POLISHES (LIQUIDS)
FORMULATIONS 2,3
FLOOR UAXES OR POLISHES
FORMULATIONS 1,2,3 (2)
RUG DEODORIZERS AND FRESHENERS
LAUNDRY SPOT REMOVERS
HOTH CONTROL PRODUCTS
METAL CLEANERS AND POLISHES
FORMULATIONS 2,3,4,5,7 (2)
HOUSEHOLD ADHESIVES
FURNITURE POLISHES AND UAXES
SUB-TOTAL
NA
NA
NA
NA
3.00 .11
27.00 .11
24.00 .11
1.00 .24 .94 .24 .94 39.60
1.04 .20 .20 .20 .20 308.88
NA
NA
NA
1.00 0.00 1.00 0.00 1.00 0.00
NA
NA
348.48
155.10
308.86
NA
NA
NA
1320.00
NA
NA
1783.98
39.60
308.88
NA
NA
NA
o.oo
NA
NA
348.48
155.10
308.68
NA
NA
NA
1320.00
NA
NA
1783.98
AUTOMOTIVE
AUTO ANTIFREEZES
FORMULATIONS 1
CAR POLISHES AND UAXES
FORMULATIONS 1,2
WINDSHIELD UASHER FLUID
SUB-TOTAL
189.10 1.00
22.30 .11 1.00 .95 .95 .95
.11 1.05 .42 .42 .42
.95 1165.17 1165.17 1165.17 1165.17
GARAGE PRODUCTS
HOUSEHOLD GLUE AND BONDING AGENTS
HOUSEHOLD CAULKS AND SEALANTS
INSECTICIDES
HERBICIDES
FUNGICIDES
BARBECUE LIGHTER FLUIDS
AUTO WINDSHIELD UASHERS
.42 4619.38
NA
5784.56
NA
NA
NA
NA
NA
NA
NA
4630.30 4619.38 4630.30
NA NA NA
5795.48 5764.56 5795.48
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
-------
Table 4 (Continued)
VOC AND PROC EMISSIONS IN CALIFORNIA
MILLION AVG. HEIGHT FRACTION TOTAL VOC EMISSIONS TOTAL PROC EMISSIONS
UNITS PROD. NATIONAL GEOGR. VOC PROC (TONS) (TONS)
DISTRI UT. CONSUMPTION POP. MULTI-
PRODUCT BUTED
-------
Table 5
VOC AND PROC EMISSIONS IN NEU JERSEY
MILLION AVG. WEIGHT FRACTION TOTAL VOC EMISSIONS TOTAL PROC EMISSIONS
UNITS PROD. NATIONAL GEOGR. VOC PROC (TONS) (TONS)
DISTRI UT. CONSUMPTION POP. MULTI-
PBODUCT BUTED (LB) (HILLION LB) APPORT. PLIER LOU HIGH LOU HIGH LOU HIGH LOU HIGH
Ln
I
Nl
Ul
AEROSOL/NON-AEROSOL PRODUCTS (1)
INSECT SPRAY PRODUCTS
INSECT SPRAYS (AEROSOL AND
NON-AEROSOL)
FORMULATIONS 2,6
INSECT REPELLENTS (AEROSOL AND
NON-AEROSOL)
FORMULATIONS 1,5
MOTH CONTROL PRODUCTS (AEROSOL
AND NON-AEROSOL)
FORMULATIONS 1,2
ANIMAL INSECTICIDES (AEROSOL
AND NON-AEROSOL)
FORMULATIONS 3,4
SUB-TOTAL
PAINTS AND FINISHES
PAINTS, PRIMERS, VARNISHES
FORMULATIONS 5,6
FORMULATIONS 3,6
OTHER RELATED PRODUCTS
FORMULATIONS 1
SUB-TOTAL
HOUSEHOLD PRODUCTS
ROOM DEODORANTS AND DIS-
INFECTANTS (AEROSOL AND NON-
AEROSOL)
FORMULATIONS 2,4
FORMULATIONS 1,4
300.60
300.60
6.9
.75
.75
265.50 .50
265.50 .50
192.5 .03 1.00 .05 1.00 0.00 1.00 149.19 2963.75 0.00 2983.75
12.00 .03 1.00 .35 .65 .35 .65 64.91 158.10 64.91 158.10
39.00 .03 1.00 .96 1.00 .96 1.00 580.32 602.08 580.32 602.08
6.00 .03 1.00 .55 1.00 .55 1.00 51.15 92.72 51.15 92.72
645.57 3836.65 696.38 3836.65
.03 1.05 .73 .87
.03 1.05 .67
.03 1.00 .65 .65 .65
2682.18 3168.53
.87
2458.36 3168.53
.65 47.97 47.97 47.97 47.97
2730.15 3236.50 2506.33 3236.50
.03 .94 .35 1.00 686.63 1934.17
.03 .94 .35 .87 686.63 1682.73
-------
Tabte 5 (Continued)
VOC AND PROC EMISSIONS IN NEV JERSEY
PIODUCT
MILLION AVG.
UNITS PROD.
DISTRI VT.
BUTED (LB)
NATIONAL GEOGB.
CONSUMPTION POP. HULTI-
(MILLION LB) APPORT. PLIER
UEIGHT FRACTION
VOC PROC
LOU HIGH LOU HIGH
TOTAL VOC EMISSIONS TOTAL PROC EMISSIONS
(TONS) (TONS)
LOU
HIGH
LOU
HIGH
Ui
I
CLEANERS
TILE AND BATHROOM CLEANERS
FORMULATIONS 1,2,3,4,5 (2)
FORMULATIONS 2,3,4,5 (2)
OVEN CLEANERS (AEROSOL AND
NON-AEROSOL)
FORMULATIONS 3,4
RUG AND UPHOLSTERY CLEANERS
(AEROSOL AND NON-AEROSOL)
FORMULATIONS 1,3
ALL PURPOSE CLEANERS
(AEROSOL AND NON-AEROSOL)
FORMULATIONS 1,2
UINDOU AND GLASS CLEANERS
(AEROSOL AND NON-AEROSOL)
FORMULATIONS 6,7
LAUNDRY PRODUCTS-AEROSOLS
STARCH, FABRIC FINISH
FORMULATIONS 1,2
LAUNDRY PRODUCTS
(AEROSOL AND NON-AEROSOL)
PREUASH STAIN REMOVERS
FORMULATIONS 1,2
SPOT REMOVERS
FORMULATIONS 1,2
UAXES AND POLISHES
FORMULATIONS 1,3
ALL OTHER HOUSEHOLD SPRAY PRODUCTS
FORMULATIONS
109.90 .75
45.2 .75
65.00 .03 1.00 0.00 .33
65.00 .03 1.00 0.00 .33
33.00
115.00
512.00
174.00
84.00
2.30
58.00
.03
.03
.03
.03
.03
.03
.03
.03
.03
0.00
332.48
0.00 332.46
1.00 0.00 .20 0.00 .20
0.00
102.30
0.00 102.30
1.00 .03 .26 .03 .26
60.61
463.45
60.61 463.45
1.00 .02 .41 .02 .41 158.72 3245.62 158.72 3245.82
1.00 0.00 .42 0.00 .42
0.00 1132.74
0.00 1132.74
1.00 .05 .11 .05 .11
62.60
143.09
62.60 143.09
1.00 0.00 0.00 0.00 0.00
1.00 1.00 1.00 .90 1.00
0.00
35.65
0.00
0.00
35.65 32.09
1.00 .07 .34 ,07 .34
1.00
62.93
NA (4)
NA
NA
0.00
35.65
305.66 62.93 305.66
NA
-------
Table 5 (Continued)
VOC AND PROC EMISSIONS IN NEU JERSEY
PRODUCT
MILLION AVG. UEIGHT FRACTION
UNITS PROD. NATIONAL GEOGR. VOC PROC
DISTRI UT. CONSUMPTION POP. HULTI-
BUTED (LB) (MILLION LB) APPORT. PLIER LOV HIGH LOU HIGH
TOTAL VOC EMISSIONS TOTAL PROC EMISSIONS
(TONS) (TONS)
LOU
HIGH
LOU
HIGH
SHOE POLISHES, WAXES AND COLOR-
ANTS (AEROSOL AND NON-AEROSOL)
FORHULATIONS 1,2
ANTISTATIC SPRAYS
FORHULATIONS 1,2
ADHESIVES (5)
(AEROSOL AND NON-AEROSOL)
FORHULATIONS 2,3,6 (2)
CAULKING AND SEALING CPDS (5)
(AEROSOL AND NON-AEROSOL)
FORHULATIONS 1,2
CARPET DEODORIZERS
(AEROSOL AND NON-AEROSOL)
FORHULATIONS 1
DRAIN OPENERS
(AEROSOL AND NON-AEROSOL)
LIQUIDS
FORHULATIONS 2 (NO VOC)
SOLIDS
FORHULATIONS 1
SUB-TOTAL
PERSONAL PRODUCTS
SHAVING LATHERS
FORHULATIONS 2,4
HAIR SPRAYS
FORHULATIONS 1,4
FORHULATIONS 4,5
STYLING HOUSSE
FORHULATIONS 1
270.70
270.70
6.00 .03 1.00 .13 .98 .13 .96 12.09 91.14 12.09 91.14
3.00 .03 1.00 0.00 .03 0.00 .03 0.00 1.40 0.00 1.40
3277.50 .03 1.00 0.00 .85 0.00 .65 0.00 43181.06 0.00 43181-06
432.80 .03 1.00 0.00 .20 0.00 .20 0.00 1341.68 0.00 1341.68
65.00 .03 .96 .02 .02 .02 .02 19.34 19.34 19.34 19.34
17 (MIL.GAL.I .03 .94 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
293.00 .03 .94 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
1079.23 52310.63 1075.66 52059.19
162.80 .50
.63
.63
106.10 .38
.03
.03
.03
.03
1.07 .03 .09 .03 .09 41.85 120.15 41.85 120.15
.87 .88 .97
.87 .73
2026.08 2242.25
.97 1681.11 2242.25
1.00 .24 .24 .24 .24 153.11 153.11 153.11 153.11
-------
Table 5 (Continued)
VOC AND PROC EMISSIONS IN NEW JERSEY
Ul
1
to
00
PRODUCT
OTHER HAIR CARE PRODUCTS-SHAMPOO
(AEROSOL AND NON-AEROSOL)
FORMULATIONS 1,2,3 (2)
PHARMACEUTICALS
FORMULATIONS 1,3
FORMULATIONS 2,3
COLOGNES
FORMULATIONS 1
PERFUMES
FORMULATIONS 1
AFTERSHAVES
FORMULATIONS 1
PERSONAL DEODORANTS AND ANTI-
PERSPI RANTS
FORMULATIONS 1,2
OTHER PERSONAL CARE PRODUCTS
SUNTAN LOTIONS (2)
FORMULATIONS 1,4,5 (2)
DEPILATORIES
FORMULATIONS 1,2
SUB-TOTAL
MILLION AVG.
UNITS PROD. NATIONAL
DISTRI UT. CONSUMPTION POP.
BUTED (LB) (MILLION LB) APPORT.
43.70
43.70
44.00
82.00
23.00
156.00
15.1
15.10
.25
.25
.12
.03
.25
.25
.13
.13
644.60 .03
.03
.03
.03
.03
.03
.03
.03
.03
GEOGR.
MULTI-
PLIER
1.00
.98
.98
1.00
1.00
1.00
.89
1.06
1.08
. WEIGHT FRACTION
VOC PROC
LOU HIGH LOU HIGH
0.00
.70
1.00
1.00
.65
.80
0.00
.10
.01
.99
1.00
1.00
.65
.95
.65
.10
0.00
.70
1.00
1.00
.65
.80
0.00
.10
.01
.99
1.00
1.00
.65
.95
.65
.10
TOTAL VOC EMISSIONS
(TONS)
LOU HIGH
0.00
116.00
85.25
38.13
57.75
430.40
0.00
3.29
2951.86
49.96
165.12
85.25
38.13
57.75
511.10
20.96
3.45
3447.24
TOTAL PROC EMISSIONS
(TONS)
LOU HIGH
0.00
116.00
85.25
38.13
57.75
430.40
0.00
3.29
2606.89
49.96
165.12
85.25
38.13
57.75
511.10
20.96
3.45
3447.24
AN I HAL PRODUCTS
VETERINARIAN AND PET PRODUCTS
SUB-TOTAL
AUTOMOTIVE AND INDUSTRIAL PRODUCTS
REFRIGERANTS
CLEANERS (AEROSOL AND NON-AEROSOL)
FORMULATIONS 4,7 14.70
NA NA NA NA
0.00 0.00 0.00 0.00
.03
1.00 0.00 1.00 0.00 1.00
NA NA NA NA
0.00 199.37 0.00 199.37
-------
Table 5 (Continued)
VOC AND PROC EMISSIONS IN NEW JERSEY
PRODUCT
HILLI ON AV6.
UNITS PROD.
DISTRI VT.
BUTED (LB)
NATIONAL GEOGR.
CONSUMPTION POP. MULTI-
(MILLION LB) APPORT. PLIER LOU HIGH
UEIGHT FRACTION
VOC PROC
TOTAL VOC EHISSIONS TOTAL PROC EHISSIONS
(TONS) (TONS)
LOU HIGH
LOU
HIGH
LOU
HIGH
-------
Table S (Continued)
VOC AND PROC EMISSIONS IN NEU JERSEY
PRODUCT
MILLION AVG.
UNITS PIOD.
DISTRI VT.
BUTED (LB)
NATIONAL GEOGR.
CONSUMPTION POP. MULTI-
(HILLION LB) APPORT. PLIER
HEIGHT FRACTION
VOC PROC
LOU HIGH LOU HIGH
TOTAL VOC EHISSIONS
(TONS)
TOTAL PROC EMISSIONS
(TONS)
LOU
HIGH
LOU
HIGH
Ul
PERSONAL DEODORANTS AND ANTI-
PIRSPIRANTS
SHAVING LATHERS
PRE-SHAVE PREPARATIONS
AFTER-SHAVE LOTIONS I COLOGNES
(LISTED UNDER AEROSOL)
PERFUMES
(LISTED UNDER AEROSOL)
RUBBING COMPOUNDS (ALCOHOL)
FACE UASHES (LIKE ASTRINGENTS)
FACIAL CREAMS AND UASHES
HAND LOTIONS
SUN LOTIONS, CREAMS AND OILS
(LISTED UNDER AEROSOL)
HOUTHUASHES
HAIR SPRAYS
HAIR SHAMPOOS, RINSES AND OTHER
HAIR PRODUCTS
SUB-TOTAL
HOUSEHOLD PRODUCTS
SHOE POLISHES
BALL POINT AND POROUS POINT PENS
ROOM DEODORANTS AND DISINFECTANTS
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.00
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.00
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.00
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.00
NA
NA
NA
NA
NA
NA
NA
NA
NA
CLEANERS
OVEN CLEANERS
RUG AND UPHOLSTERY CLEANERS
UINDOU AND GLASS CLEANERS
FLOOR CLEANERS
TILE AND BATHROOM CLEANERS
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
-------
Table 5 (Continued)
VOC AND PROC EMISSIONS IN NEU JERSEY
PRODUCT
WALL CLEANERS
UAXES AND POLISHES (LIQUIDS)
FORMULATIONS 2,3
FLOOR WAKES OR POLISHES
POPULATIONS 1,2,3 (2)
RUG DEODORIZERS AND FRESHENERS
LAUNDRY SPOT REMOVERS
MOTH CONTROL PRODUCTS
HETAL CLEANERS AND POLISHES
FORMULATIONS 2,3,4,5,7 (2)
HOUSEHOLD ADHESIVES
FURNITURE POLISHES AND UAIES
SUB-TOTAL
MILLION AVG.
UNITS PROD.
DISTRI UT.
BUTED (LB)
WEIGHT FRACTION
TOTAL VOC EMISSIONS TOTAL PROC EMISSIONS
NATIONAL GEOGR.
CONSUMPTION POP. MULTI-
(MILLION LB) APPORT. PLIER
VOC
PROC
(TONS)
(TONS)
LOU HIGH LOU HIGH
LOU
HIGH
LOU
HIGH
NA
NA
NA
AUTOMOTIVE
AUTO ANTIFREEZES
FORMULATIONS 1
CAR POLISHES AND UAXES
FORMULATIONS 1,2
WINDSHIELD UASHER FLUID
SUB-TOTAL
189.10 1.00
GARAGE PRODUCTS
HOUSEHOLD GLUE AND BONDING AGENTS
HOUSEHOLD CAULKS AND SEALANTS
INSECTICIDES
HERBICIDES
FUNGICIDES
BARBECUE LIGHTER FLUIDS
AUTO WINDSHIELD UASHERS
NA
3.00
27.00
24.00
.03 1.00 .24 .94 .24 .94 ii.16
.03 1.02 .20 .20 .20 .20 85.37
NA
NA
NA
.03 1.00 0.00 1.00 0.00 1.00 0.00
NA
NA
96.53
43.71
85.37
NA
NA
NA
372.00
NA
NA
501.08
11.16
85.37
NA
NA
NA
0.00
NA
NA
96.53
43.71
85.37
NA
NA
NA
372.00
NA
NA
501.08
22.30 .03 1.00 .95 .95 .95 .95 328.37 328.37 328.37 328.37
.03 .90 .42 .42 .42 .42 1115.65 1118.49 1115.85 1118.49
NA NA NA NA
1444.22 1446.86 1444.22 1446.86
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
-------
Table 5 (Continued)
VOC AND PROC EMISSIONS IN NEU JERSEY
MILLION AVG. WEIGHT FRACTION TOTAL VOC EMISSIONS TOTAL PROC EMISSIONS
UNITS PROD. NATIONAL GEOGR. VOC PROC (TONS) (TONS)
DISTRI UT. CONSUMPTION POP. MULTI-
PRODUCT BUTED (LB) (MILLION LB) APPORT. PLIER LOU HIGH LOU HIGH LOU HIGH LOU HIGH
DEGREASERS NA NA NA NA
SUB-TOTAL 0.00 0.00 0.00 0.00
TOTAL EMISSIONS 10269.36 66096.71 9501.79 67645.27
(1) Products in these sub-categories are aerosol unless it Is indicated that aerosol and non-aerosol are conbined.
(2) More than two listed /emulations indicates that several product tabulations had the sane low or high weight percent.
(3) Suntan lotion use varies strongly with season. However, the total enission estiiate is independent of seasonal fluctuation.
<4> NA Indicates that emissions could not be calculated because either product use or foriulation data were not available.
(5) Includes industrial, connercial, and consuner products.
-------
Table 6
VOC AND PBOC EMISSIONS IN NEU YOIK
01
i
CJ
MILLION AV6. WEIGHT FRACTION TOTAL VOC EMISSIONS TOTAL PROC ENISSIONS
UNITS PROD. NATIONAL GE06R. VOC PROC (TONS) (TONS)
DISTRI UT. CONSUMPTION POP. MULTI-
PRODUCT BUTED (LB) (MILLION LB) APPORT. PLIER LOV HIGH LOU HIGH LOU HIGH LOU HIGH
AEROSOL/NON-AEROSOL PRODUCTS (1)
INSECT SPRAY PRODUCTS
INSECT SPRAYS (AEROSOL AND
NON-AEROSOL)
FORMULATIONS 2,8
INSECT REPELLENTS (AEROSOL AND
NON-AEROSOL)
FORMULATIONS 1,5
MOTH CONTROL PRODUCTS (AEROSOL
AND NON-AEROSOL)
FORMULATIONS 1,2
ANIMAL INSECTICIDES (AEROSOL
AND NON-AEROSOL)
FORMULATIONS 3,4
SUB-TOTAL
PAINTS AND FINISHES
PAINTS, PRIMERS, VARNISHES
FORMULATIONS 5,6
FORMULATIONS 3,6
OTHER RELATED PRODUCTS
FORMULATIONS 1
SUB-TOTAL
HOUSEHOLD PRODUCTS
ROQH DEODORANTS AND DIS-
INFECTANTS (AEROSOL AND NON-
AEROSOL)
FORMULATIONS 2,4
FORMULATIONS 1.4
300.60
300.60
.75
.75
6.9 .69
265.50 .50
265.50 .50
192.5 .05 1.00 .05 1.00 0.00 1.00 221.36 4427.50 0.00 4427.50
12.00 .05 1.00 .35 .65 .35 .65 96.32 234.60 96.32 234.60
39.00 .05 1.00 .96 1.00
1.00 861.12 893.41 861.12 693.41
6.00 .05 1.00 .55 1.00 .55 1.00 75.90 137.59 75.90 137.59
1254.72 5693.10 1033.34 5693.10
.05 1.05 .73 .67
.05 1.05 .67
.05 1.00 .65 .65 .65
3960.02 4731.37
.87
3647.89 4731.37
.65 71.18 71.18 71.18 71.18
4051.19 4602.55 3719.07 4802.55
.05 .94 .35 1.00 1018.67 2870.05
.05 .94 .35 .87 1018.87 2496.95
-------
Table 6 (Continued)
VOC AND PBOC EMISSIONS IN NEU YORK
PRODUCT
CLEANERS
TILE AND BATHROOM CLEANERS
FORMULATIONS 1,2,3,4,5 (2)
FORMULATIONS 2,3,4,5 (2)
MILLION
UNITS
DISTRI
BUTED
AVG.
PROD.
UT.
(LB)
NATIONAL
CONSUMPTION
(MILLION LB)
65.00
65.00
POP.
APPORT.
.05
.05
GEOGR.
MULTI-
PLIER
1.00
1.00
HEIGHT
VOC
LOU HIGH
FRACTION
PROC
LOU HIGH
*
0.00 .33
0.00 .33
TOTAL VOC
EMISSIONS
(TONS)
LOU
0.00
HIGH
493.35
TOTAL PROC
EMISSIONS
(TONS)
LOU
0.00
HIGH
493.35
Ul
i
OVEN CLEANERS (AEROSOL AND
NON- AEROSOL)
FORMULATIONS 3,4
RUG AND UPHOLSTERY CLEANERS
(AEROSOL AND NON-AEROSOL)
FORMULATIONS 1,3
ALL PURPOSE CLEANERS
(AEROSOL AND NON-AEROSOL)
FORMULATIONS 1,2
UINDOU AND GLASS CLEANERS
(AEROSOL AND NON-AEROSOL)
FORMULATIONS 6,7
LAUNDRY PRODUCTS-AEROSOLS
STARCH, FABRIC FINISH
FORMULATIONS 1,2
LAUNDRY PRODUCTS
(AEROSOL AND NON-AEROSOL)
PREUASH STAIN REMOVERS
FORMULATIONS 1,2
SPOT REMOVERS
FORMULATIONS 1,2
VAXES AND POLISHES
FORMULATIONS 1,3
ALL OTHER HOUSEHOLD SPRAY PRODUCTS
FORMULATIONS
109.90 .75
33.00 .05 1.00 0.00 .20 0.00 .20 0.00 151.60 0.00 151.80
115.00
512.00
174.00
84.00
2.30
56.00
.05 1.00 .03 .26 .03 .26 89.93 687.70 89.93 667.70
.05 1.00 .02 .41 .02 .41 235.52 4616.38 235.52 4616.38
.05
.05
45.2 .75
.05
.05
.05
.05
1.00 0.00 .42 0.00 .42 0.00 1680.64 0.00 1660.84
1.00 .05 .11 .05 .11 92.89 212.33 92.69 212.33
1.00 0.00 0.00 0.00 0.00
1.00 1.00 1.00 .90 1.00
1.00 .07 .34 .07 .34
1.00
0.00 0.00 0.00 0.00
52.90 52.90 47.61 52.90
93.38 453.56 93.38 453.56
NA (4) NA NA NA
-------
Table 6 (Continued)
VOC AND PROC EMISSIONS IN NEW YORK
MILLION AVG.
UNITS PROD. NATIONAL
DISTRI UT. CONSUMPTION POP.
PRODUCT BUTED (LB) (MILLION LB) APPORT.
OTHER HAIR CARE PRODUCTS-SHAMPOO
(AEROSOL AND NON-AEROSOL)
FORMULATIONS 1,2,3 (2)
PHARMACEUTICALS
FORMULATIONS 1,3 43.70 .25
FORMULATIONS 2,3 43.70 .25
COLOGNES
FORMULATIONS 1 44.00 .12
PERFUMES
FORMULATIONS 1 82.00 .03
7 AFTERSHAVES
£ FORMULATIONS 1 23.00 .25
PERSONAL DEODORANTS AND ANTI-
PERSPI RANTS
FORMULATIONS 1,2 156.00 .25
OTHER PERSONAL CARE PRODUCTS
SUNTAN LOTIONS (2)
FORMULATIONS 1,4,5 (2) 15.1 .13
DEPILATORIES
FORMULATIONS 1,2 15.10 .13
SUB-TOTAL
ANIMAL PRODUCTS
VETERINARIAN AND PET PRODUCTS
SUB-TOTAL
644.60 .05
.05
.05
.05
.05
.05
.05
.05
.05
HEIGHT FRACTION TOTAL VOC EMISSIONS
GEOGR. VOC PROC (TONS)
MULTI-
PLIER LOU HIGH LOU HIGH LOU HIGH
1.00 0.00 .01 0.00 .01 0.00
.98 .70 .99 172.13
.98 .70 .99
1.00 1.00 1.00 1.00 1.00 126.50
1.00 1.00 1.00 LOO 1.00 56.58
1.00 .65 .65 .65 .65 85.70
.69 .80 .95 .80 .95 638.66
1.06 0.00 .65 0.00 .65 0.00
1.08 .10 .10 .10 .10 4.88
4380.17
NA
0.00
74.13
245.02
126.50
56.58
65.70
758.41
31.11
5.12
5115.26
NA
0.00
TOTAL PROC EMISSIONS
(TONS)
LOU HIGH
0.00
172. 13
126.50
56.58
85.70
638.66
0.00
4.88
3868.30
NA
0.00
74.13
245.02
126.50
56.58
85.70
758.41
31.11
5.12
5115.26
NA
0.00
AUTOMOTIVE AND INDUSTRIAL PRODUCTS
REFRIGERANTS
CLEANERS (AEROSOL AND NON-AEROSOL)
FORMULATIONS 4,7 14.70 .88 .05 1.00 0.00 1.00 0.00 1.00 0.00 295.84 0.00 295.84
-------
Table 6 (Continued)
VOC AND PROC EMISSIONS-IN NEW YOiK
01
i
u>
ON
MILLION AVG. WEIGHT FRACTION TOTAL VOC EMISSIONS TOTAL PROC EMISSIONS
UNITS PROD. NATIONAL GEOGR. VOC PROC (TONS) (TONS)
DISTRI HT. CONSUMPTION POP. MULTI-
PRODUCT BUTED (LB) (MILLION LB) APPORT. PLIER LOU HIGH LOU HIGH LOU HIGH LOU HIGH
SHOE POLISHES, UAXES AND COLOR-
ANTS (AEROSOL AND NON-AEROSOL)
FORMULATIONS 1,2
ANTISTATIC SPRAYS
FORHULATIONS 1,2
ADHESIVES (S)
(AEROSOL AND NON-AEROSOL)
FORHULATIONS 2,3,6 (2)
CAULKING AND SEALING CPDS (5)
(AEROSOL AND NON-AEROSOL)
FORHULATIONS 1,2
CARPET DEODORIZERS
(AEROSOL AND NON-AEROSOL)
FORHULATIONS I
DRAIN OPENERS
(AEROSOL AND NON-AEROSOL)
LIQUIDS
FORHULATIONS 2 (NO VOC)
SOLIDS
FORHULATIONS I
SUB-TOTAL
PERSONAL PRODUCTS
SHAVING LATHERS
FORHULATIONS 2,4
HAIR SPRAYS
FORHULATIONS 1,4
FORHULATIONS 4,5
STYLING HOUSSE
FORHULATIONS I
6.00 .05 1.00 .13 .98 .13 .98 17.94 135.24 17.94 135.24
3.00 .05 1.00 0.00 .03 0.00 .03 0.00 2.07 0.00 2.07
3277.50 .05 1.00 0.00 .85 0.00 .85 0.00 64075.12 0.00 64075.12
432.80 .05 1.00 0.00 .20 0.00 .20 0.00 1990.88 0.00 1990.88
65.00 .05 .96 .02 .02 .02 .02 28.70 28.70 28.70 26.70
17 (MIL.GAL.) .05 .94 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
293.00 .05 .94 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
1601.43 77622.23 1596.14 77249.12
162.80 .50
270.70
270.70
.63
.63
106.10 .38
.05
.05
.05
.05
1.07 .03 .09 .03 .09 62.10 178.29 62.10 178.29
.87 .86 .97
.87 .73
3006.43 3327.21
.97 2494.56 3327.21
1.00 .24 .24 .24 .24 227.19 227.19 227.19 227.19
-------
Table 6 (Continued)
VOC AND PROC EMISSIONS IN NEW YOIK
in
I
MILLION AVG.
UNITS PROD. NATIONAL
DISTRI UT. CONSUMPTION POP.
PRODUCT BUTED (LB) (MILLION LB) APPORT.
ENGINE DEGREASERS
FORMULATIONS 1,2,3 (2) 23.90 .68
FORMULATIONS 3 23.90 .88
LUBRICANTS AND SILICONES
FORMULATIONS 1,2 75.40 .44
UNDERCOAT INGS
FORMULATIONS 1 8.30 .75
BRAKE CLEANERS
FORMULATIONS 1, 2, or 3 16.60 1.13
TIRE SEALANTS AND INFLATORS
FORMULATIONS 19.30 .69
CARBURETOR AND CHOKE CLEANERS
FORMULATIONS 2,3 39.80 .75
ENGINE STARTING FLUIDS
FORMULATIONS 1 30.60 .56
UINDSHIELD DEICER (AEROSOL AND NON)
FORMULATIONS 1,2 10.40 1.00
OTHER AUTO AND INDUSTRIAL PRODUCTS
SUB-TOTAL
MISCELLANEOUS PRODUCTS
HERBICIDES AND FUNGICIDES
FORMULATIONS 1,7
SUB-TOTAL
NON-AEROSOL PRODUCTS
.05
.05
.05
.05
.05
.05
.05
.05
.05
69.00 .05
WEIGHT FRACTION
GEOGR. VOC PROC
MULTI-
PLIER LOU HIGH LOU HIGH
1.00 .89 1.00
1.00 .75
1.00 0.00 1.00 0.00
1.00 .25 .85 .25
1.00 1.00 1.00 1.00
1.00
1.00 .28 1.00 .26
1.00 1.00 1.00 1.00
1.00 .75 1.00 .75
1.00 0.00 .95 0.00
1.00
1.00
.85
1.00
1.00
1.00
1.00
.95
TOTAL VOC EMISSIONS
(TONS)
LOU HIGH
429.04
0.00
35.79
431.43
NA
192.23
396.70
179.40
NA
1664.61
0.00
0.00
480.99
763.05
121.70
431.43
NA
686.55
396.70
239.20
NA
3415.46
1507.65
1507.65
TOTAL PROC EMISSIONS
(TONS)
LOU HIGH
360.74
0.00
35.79
431.43
NA
192.23
396.70
179.40
NA
1596.31
0.00
0.00
480.99
763.05
121.70
431.43
NA
686.55
396.70
239.20
NA
3415.46
1507.65
1507.65
PERSONAL PRODUCTS
NAIL POLISHES
NAIL POLISH REMOVERS
NA
NA
HA
NA
NA
NA
NA
NA
-------
Table 6 (Continued)
VOC AND PROC EMISSIONS IN NEU YORK
PIODUCT
MILLION AV6.
WITS PROD.
DISTRI VT.
BUTED (LB)
NATIONAL GEOGi.
CONSUHPTION POP. HULTI-
(HILLION LB) APPORT. PLIER
HEIGHT FRACTION
VOC PROC
LOU HIGH LOU HIGH
TOTAL VOC EHISSIONS
(TONS)
TOTAL PROC EMISSIONS
(TONS)
LOU
HIGH
LOU
HIGH
tn
I
CO
oo
PERSONAL DEODORANTS AND ANTI-
PIRSPIRANTS
SHAVING LATHERS
PRE-SHAVE PREPARATIONS
AFTER-SHAVE LOTIONS & COLOGNES
(LISTED UNDER AEROSOL)
PERFUHES
(LISTED UNDER AEROSOL)
RUBBING COMPOUNDS (ALCOHOL)
FACE UASHES (LIKE ASTRINGENTS)
FACIAL CREAKS AND UASHES
HAND LOTIONS
SUN LOTIONS, CREAHS AND OILS
(LISTED UNDER AEROSOL)
HQUTHUASHES
HAIR SPRAYS
HAIR SHAHPOOS, RINSES AND OTHER
HAIR PRODUCTS (SEE AEROSOL)
SUB-TOTAL
HOUSEHOLD PRODUCTS
SHOE POLISHES
BALL POINT AND POROUS POINT PENS
ROOM DEODORANTS AND DISINFECTANTS
CLEANERS
OVEN CLEANERS
RUG AND UPHOLSTERY CLEANERS
UINDOU AND GLASS CLEANERS
FLOOR CLEANERS
TILE AND BATHROOM CLEANERS
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.00
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.00
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.00
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.00
NA
NA
NA
NA
NA
NA
NA
NA
-------
Table 6 (Continued)
VOC AND PROC EMISSIONS IN NEU YORK
PIODUCT
MILLION AVG.
WITS PEOD.
DISTBI UT.
BUTED (LB)
NATIONAL GEOGB.
CONSUMPTION POP. MULTI-
(HILLION LB) APPORT. PLIEB LOU HIGH
WEIGHT FRACTION
VOC PROC
TOTAL VOC EMISSIONS TOTAL PROC EMISSIONS
(TONS) (TONS)
LOU HIGH
LOU
HIGH
LOU
HIGH
vO
UALL CLEANERS
UAXES AND POLISHES (LIQUIDS)
FORMULATIONS 2,3
FLOOR UAXES OR POLISHES
FORMULATIONS 1,2,3 (2)
RUG DEODORIZERS AND FRESHENERS
LAUNDRY SPOT REMOVERS
MOTH CONTROL PRODUCTS
METAL CLEANERS AND POLISHES
FORMULATIONS 2,3,4,5,7 (2)
HOUSEHOLD ADHESIVES
FURNITURE POLISHES AND UAXES
SUB-TOTAL
3.00
27.00
.05
.05
1.00 .24 .94 .24 .94
NA
16.56
NA
64.66
NA
16.56
1.02 .20 .20 .20 .20 126.68
24.00 .05 1.00 0.00 1.00 0.00 1.00
AUTOMOTIVE
AUTO ANTIFREEZES
FORMULATIONS 1
CAR POLISHES AND UAXES
FORMULATIONS 1,2
WINDSHIELD UASHER FLUID
SUB-TOTAL
189.10 1.00
GARAGE PRODUCTS
HOUSEHOLD GLUE AND BONDING AGENTS
HOUSEHOLD CAULKS AND SEALANTS
INSECTICIDES
HERBICIDES
FUNGICIDES
BARBECUE LIGHTER FLUIDS
AUTO WINDSHIELD VASHERS
NA
64.66
126.68
NA
NA
NA
0.00
NA
NA
143.24
126.68
NA
NA
NA
552.00
NA
NA
743.54
126.68
NA
NA
NA
0.00
NA
NA
143.24
126.68
NA
NA
NA
552.00
NA
NA
743.54
22.30 .05 1.00 .95 .95 .95 .95 487.25 487.25 487.25 467.25
.05 .90 .42 .42 .42 .42 1655.78 1659.69 1655.78 1659.69
NA NA NA NA
2143.03 2146.95 2143.03 2146.95
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
-------
Table 6 (Continued)
VOC AND PEOC EMISSIONS IN NEU YOIK
MILLION AVG. WEIGHT FRACTION TOTAL VOC EMISSIONS TOTAL PROC EMISSIONS
UNITS PROD. NATIONAL GEOGR. VOC PROC (TONS) (TONS)
DISTRI UT. CONSUMPTION POP. . MULTI-
PRODUCT BUTEO (LB) (MILLION LB) APPORT. PLIER LOU HIGH LOU HIGH LOU HIGH LOU HIGH
DEGREASERS NA NA NA NA
SUB-TOTAL 0.00 0.00 0.00 0.00
TOTAL EMISSIONS 15238.40 10(046.74 14099.44 100673.63
(1) Products In these sub-categories are aerosol unless It is indicated that aerosol and non-aerosol are combined.
(2) More than tuo listed formulations indicates that several product foriulations had the saie low or high weight percent.
(3) Suntan lotion use varies strongly with season. However, the total euission estimate is independent of seasonal fluctuation.
(4) NA indicates that emissions could not be calculated because either product use or formulation data were not available.
(5) Includes industrial, commercial, and consumer products.
-------
F/834-025-68a/#8
6. CONCLUSIONS
Tables 7, 8, and 9 summarize PROC and VOC emission estimates for consumer
products. The consumer product subcategories are arranged in descending order
according to the high PROC emission estimate, the low PROC emission estimate,
and an average of the two estimates. Only those product categories for which
all data are available are listed.
If the low PROC emissions estimates (Table 7) are assumed to be more
realistic, the categories with the largest emissions are:
Paints, primers, and varnishes
Hair sprays
Car polishes and waxes
Room deodorants and disinfectants
Moth control products.
If the high PROC emissions estimates (Table 8) are assumed to most
closely reflect the actual emissions, the categories of greatest emissions
are:
Adhesives
Paints, primers, and varnishes
All purpose cleaners
Insect sprays
Hair sprays
Room deodorants and disinfectants.
If the average of the high and the low emissions estimates (Table 9) is
assumed to be the most realistic, the product categories with the largest
emissions are:
Adhesives
Paints, primers, and varnishes
Hair sprays
All purpose cleaners
6-1
-------
F/834-025-68a/#8
Insect sprays
Car polishes and waxes
Room deodorants and disinfectants.
These seven subcategories account for approximately 85 percent of the
average PROC releases even though they represent less than 20 percent of the
product subcategories. Adhesives alone account for over 56 percent of total
PROC emissions.
Use data for adhesives and caulking and sealing compounds included
industrial as well as consumer use. If consumers use only 10 percent of the
adhesives, the seven product categories still release approximately 70 percent
of the average PROC emissions. Adhesives would continue to be a major source
of PROC emissions.
The range of possible total VOC and PROC emissions is quite large.
Annual California VOC emissions, for example, vary from a low of 38,800 tons
to a high of 245,000 tons. The low/high VOC and PROC ratios reported in
Tables 10, 11, and 12, indicate a wide variation in emission estimation
precision. This variation between the low and high VOC and PROC estimates is
accounted for by the uncertainties in the distribution, consumption, and
formulation data for many subcategories. For household products in
California, the low VOC or PROC is estimated to be only 2 percent of the high
VOC or PROC, whereas for personal products the low estimate is 86 percent of
the high estimate for VOC, and 76 percent for PROC. The insect spray
category, with low/high VOC and PROC ratios of 0.22 and 0.18, respectively, is
the other product category with a wide emissions estimate range. Taking into
consideration all products, the low/high VOC estimate is 0.16, while the
similar PROC ratio is 0.15.
In general, the amount of PROC emitted is very similar to that of VOC
emitted. This is not unexpected, given the relatively few volatile organic
compounds not considered to be photoreactive. The nonphotoreactive volatile
organic compounds that were found in the formulations were: carbon dioxide
(propellent), methylene chloride, and 1,1,1-trichloroethane. These compounds
appear not to be in widespread use in consumer products, explaining the
similarity in VOC and PROC emissions.
6-2
-------
F/834-025-68a/#8
Very little data were available for emissions of VOC and PROC from
nonaerosol products. Data collected by SAIC in an earlier report on organic
compound emissions in California (Rogozen et al., 1985) have been examined in
an attempt to decrease the uncertainty in this area. Estimated emissions from
several nonaerosol products are reported in Table 13. This remains an
incomplete list of nonaerosol products, but it sheds some light on the
approximate fraction of total VOC emissions that might be omitted from the
inventory. The total VOC emitted from nonaerosol products was 19,504 tons/yr
(Rogozen et al., 1985). This represents 8 percent of the high estimate of VOC
emitted in California. However, a more realistic assessment of the omitted
nonaerosol component, assuming VOC emissions are only an average of the
reported low and high figures, is 13 percent of total VOC emissions. This
means that our emission inventory probably has omitted between 8 and 13
percent of actual VOC emitted by consumer products. This estim'ate is likely
to be somewhat conservative, since not all omitted products have been taken
into account.
Tables 14, 15, and 16 indicate per capita emissions of VOC and PROC by
product subcategory. The average per capita PROC emissions vary from
approximately 9 to 11 Ib/person/year. These results are somewhat larger than
the 6.3 Ib/person/year recommended for estimating PROC by the EPA (EPA, 1980).
However, two factors suggest that these results are not directly
comparable with the EPA data. The first is the large proportion of total
emissions contributed by adhesives (in household products). It was not
possible to disaggregate industrial and consumer use of adhesives; therefore,
our total includes industrial as well as consumer use. Based upon industry
estimates (Broxterman, 1983), we may assume that 95 percent of the use of
these products is industrial and 5 percent consumer. Per capita average PROC
emissions are estimated to be: California, 5.40 Ib; New Jersey, 4.38 Ib; and
New York, 5.02 Ib, after subtracting the industrial proportion of adhesives
and adjusting the average per capita emissions.
The second adjustment factor stems from the lack of data for many
nonaerosol subcategories. Using the SAIC derived emission data (Rogozen et
al., 1985), reported in Table 13, as a partial adjustment for this omission,
6-3
-------
F/834-025-68a/#8
we now find the per capita annual emissions for these three regions to be:
California, 6.97 Ib/person; New Jersey, 5.95 Ib/person; and New York, 6.59
Ib/person. Thus, our final estimates are very close to the earlier EPA
estimate. These estimates are likely to be somewhat conservative since only
some of the unavailable emissions data have been replaced by the SAIC study
data.
Future Efforts
The results of this study indicate that the EPA estimate of PROC
emissions of 6.3 Ib/person/year is likely to be fairly accurate. Nonetheless,
these results were derived from data with considerable uncertainty. Each
stage of the data collection process presented accuracy and validity problems,
including defining "typical" products for a subcategory, disaggregating
aerosol and nonaerosol for industrial and consumer products, assessing
distribution or consumption by subcategory, knowing percent VOC or PROC within
any product, and finding the relative distribution of each of the products for
any subcategory. Thus, for some categories, the range of emissions from low
to high VOC or PROC is quite large.
Given these problems, it would be difficult to use the results as the
basis for calculating actual reductions in emissions of reactive hydrocarbons
as a result of regulation. However, these results may fruitfully be used as
the basis for targeting further research, and as the basis for focusing on
specific industries with a potential for substantial emission reductions. For
example, industrial users of adhesives would be a logical category to focus
upon.
Future research efforts would probably be better spent in focusing on
those areas which have the greatest potential for emission reduction, such as
adhesives, paints, hair sprays and cleaners. More detailed knowledge in these
subcategories about the specific amounts, types, and distribution patterns of
PROC emissions is likely to produce the greatest results.
There are two potentially rewarding research paths to pursue to gain
additional detailed information. Both require substantial expenditures of
6-4
-------
F/834-025-68a/#8
time and money. The first is to purchase marketing data from the large
marketing research firms such as Simmons or Kline, with their detailed
formulation and distribution data sets. The second is to track down
individual industries, either through a survey or through telephone calls and
personal visits with knowledgeable industry officials. It is likely that
individual companies have the required data but will not release them without
the proper authority, since they consider such information proprietary.
6-5
-------
TABLE 7. CONSUMER PRODUCT SUB-CATEGORIES RANKED IN ORDER
OF LOW TOTAL PROC EMISSIONS
STATE OF CALIFORNIA
VOC & PROC EMISSIONS
AEROSOL/ TOTAL VOC EMISSIONS (tons)
CONSUMER PRODUCT SUB -CATEGORY
PAINTS, PRIMERS, VARNISHES
HAIR SPRAYS
CAR POLISHES & WAXES
ROOM DEODORANTS & DISINFECTANTS
MOTH CONTROL PRODUCTS
PERSONAL DEODORANTS
AUTO ANTIFREEZES
BREAK CLEANERS
ENGINE STARTING FLUIDS
ENGINE DEGREASERS
ALL PURPOSE CLEANERS
STYLING MOUSE
CARBURETOR & CHOKE CLEANERS
PHARMACEUTICALS
WINDSHIELD DEICER
FLOOR WAXES OR POLISHES
COLOGNES
INSECT REPELLENTS
STARCH & FABRIC FINISH
RUG & UPHOLSTERY CLEANERS
WAXES & POLISHES
AFTERSHAVES
ANIMAL INSECTICIDES
PAINTS-OTHER RELATED PRODUCTS
SHAVING LATHERS
PERFUMES
SPOT REMOVERS
UNDERCOAT INGS
CARPET DEODORIZERS
SHOE POLISHES, WAXES & COLORANTS
WAXES & POLISHES LIQUIDS
DEPILATORIES
ADHESIVES
INSECT SPRAYS
CAULKING & SEALING COMPOUNDS
WINDOW & GLASS CLEANERS
HERBICIDES, FUNGICIDES
LUBRICANTS AND SI LI CONES
METAL CLEANERS & POLISHES
TILE & BATHROOM CLEANERS
AUTO CLEANERS
OVEN CLEANERS
HAIR CARE PRODUCTS - SHAMPOOS
SUNTAN LOTIONS
ANT I -STATIC SPRAYS
PREWASH STAIN REMOVERS
DRAIN OPENERS
TOTALS
nun-MCK.
(A/N)
A
A
N
A
A/N
A
N
A
A
A
A
A
A
A
A/N
N
A
A/N
A
A
A
A
A
A
A
A
A/N
A
A/N
A/N
N
A
A
A/N
A/N
A/N
A/N
A
N
A
A/N
A/N
A/N
A
A
A/N
A/N
LOW
10,424
7,685
4,619
2,436
2,059
1,476
1,165
1,032
949
1,026
603
543
460
454
429
309
303
230
222
215
212
205
182
170
140
135
127
86
69
43
40
11
0
529
0
0
0
0
0
0
0
0
0
0
0
0
0
38,587
HIGH
12,392
8,505
4,630
6,363
2,136
1,752
1,165
1,032
949
1,150
12,324
543
1,642
646
572
309
303
561
508
1,645
1,030
205
329
170
402
135
127
291
69
323
155
12
153,223
10,588
4,761
3,939
3,605
1,825
1,320
1,180
707
370
177
81
5
0
0
244,656
6-6
AVERAGE
11,408
8,095
4,625
4,650
2,098
1,614
1,165
1,032
949
1,088
6,463
543
1,051
550
501
309
303
396
365
930
621
205
255
170
271
135
127
188
69
183
97
11
76,612
5,558
2,380
1,970
1,803
913
660
590
354
185
89
41
3
0
0
141,622
TOTAL PROC EMISSIONS (tons)
LOW
9,554
6,377
4,619
2,436
2,059
1,476
1J65
1,032
949
863
603
543
460
454
429
309
303
230
222
215
212
205
182
170
140
135
114
86
69
43
40
11
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
HIGH
12,392
8,505
4,630
5,971
2,136
1,752
1,165
1,032
949
1,150
12,324
543
1,642
646
572
309
303
561
508
1,645
1,030
205
329
170
402
135
127
291
69
323
155
12
153,223
10,588
4,761
3,939
3,605
1,825
1,320
1,180
707
370
177
81
5
0
0
AVERAGE
10,973
7,441
4,625
4,204
2,098
1,614
1,165
1,032
949
1,006
6,463
543
1,051
550
501
309
303
396
365
930
621
205
255
170
271
135
120
188
69
183
97
11
76,612
5,294
2,380
1,970
1,803
913
660
590
354
185
89
41
3
0
0
35,703 243,764 139,734
-------
TABLE 7. CONSUMER PRODUCT SUB-CATEGORIES RANKED IN ORDER
OF LOW TOTAL PROC EMISSIONS (continued)
NEW YORK
VOC & PROC EMISSIONS
AEROSOL/ TOTAL VOC EMISSIONS (tons)
CONSUMER PRODUCT SUB -CATEGORY
PAINTS, PRIMERS, VARNISHES
HAIR SPRAYS
CAR POLISHES & WAXES
ROOM DEODORANTS & DISINFECTANTS
MOTH CONTROL PRODUCTS
PERSONAL DEODORANTS
AUTO ANTIFREEZES
BRAKE CLEANERS
ENGINE STARTING FLUIDS
ENGINE DEGREASERS
ALL PURPOSE CLEANERS
STYLING MOUSE
CARBURETOR & CHOKE CLEANERS
WINDSHIELD DEICER
PHARMACEUTICALS
FLOOR WAXES OR POLISHES
COLOGNES
INSECT REPELLENTS
WAXES & POLISHES
STARCH & FABRIC -FINISH
RUG & UPHOLSTERY CLEANERS
AFTERSHAVES
ANIMAL INSECTICIDES
PAINTS-OTHER RELATED PRODUCTS
SHAVING LATHERS
PERFUMES
SPOT REMOVERS
UNDERCOAT INGS
CARPET DEODORIZERS
SHOE POLISHES, WAXES & COLORANTS
WAXES & POLISHES LIQUIDS
DEPILATORIES
ADHESIVES
INSECT SPRAYS
CAULKING & SEALING COMPOUNDS
WINDOW & GLASS CLEANERS
HERBICIDES AND FUNGICIDES
LUBRICANTS AND SILICONES
METAL CLEANERS & POLISHES
TILE & BATHROOM CLEANERS
AUTO CLEANERS
OVEN CLEANERS
HAIR CARE PRODUCTS - SHAMPOOS
SUNTAN LOTIONS
ANTI -STATIC SPRAYS
PREVASH STAIN REMOVERS
DRAIN OPENERS
nun-HCK.
(A/N)
A
A
N
A
A/N
A
N
A
A
A
A '
A
A
a/n
A
N
A
A/N
A
A
A
A
A
A
A
A
A/N
A
A/N
A/N
N
A
A
A/N
A/N
A/N
A/N
A
N
A
A/N
A/N
A/N
A
A
A/N
A/N
LOW
3,980
3,006
1,656
1,019
861
639
487
431
397
429
236
227
192
179
172
127
127
96
93
93
90
86
76
71
62
57
53
36
29
18
17
5
0
221
0
0
0
0
0
0
0
0
0
0
0
0
0
HIGH
4,731
3,327
1,660
2,870
893
758
487
431
397
481
4,816
227
687
239
245
127
127
235
454
212
688
86
138
71
178
57
53
122
29
135
65
5
64,075
4,428
1,991
1,681
1,508
763
552
493
296
152
74
31
2
0
0
AVERAGE
4,356
3,167
1,658
1,944
877
699
487
431
397
455
2,526
227
439
209
209
127
127
165
273
153
389
86
107
71
120
57
53
79
29
77
41
5
32.038
2,324
995
840
754
382
276
247
148
76
37
16
1
0
0
TOTAL PROC EMISSIONS (tons)
LOW
3,648
2,495
1,656
1,019
861
639
487
431
397
361
236
227
192
179
172
127
127
96
93
93
90
86
76
71
62
57
48
36
29
18
17
5
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
HIGH
4,731
3,327
1,660
2,497
893
758
487
431
397
481
4,816
227
687
239
245
127
127
235
454
212
688
86
138
71
178
57
53
122
29
135
65
5
64,075
4,428
1,991
1,681
1,508
763
552
493
296
152
74
31
2
0
0
AVERAGE
4,190
2,911
1,658
1,758
877
699
487
431
397
421
2,526
227
439
209
209
127
127
165
273
153
389
86
107
71
120
57
50
79
29
77
41
5
32,038
2,214
995
840
754
382
276
247
148
76
37
16
1
0
0
TOTALS
15,267
101,075
6-7
58,171
14,128 100,702 57,415
-------
TABLE 7. CONSUMER PRODUCT SUB-CATEGORIES RANKED IN ORDER
OF LOW TOTAL PROC EMISSIONS (continued)
STATE OF NEW JERSEY
VOC & PROC EMISSIONS
AEROSOL/ TOTAL VOC EMISSIONS (tons)
CONSUMER PRODUCT SUB- CATEGORY
PAINTS, PRIMERS, VARNISHES
HAIR SPRAYS
CAR POLISHES & WAXES
ROOM DEODORANTS & DISINFECTANTS
MOTH CONTROL PRODUCTS
PERSONAL DEODORANTS
AUTO ANTIFREEZES
BRAKE CLEANERS
ENGINE STARTING FLUIDS
ENGINE DEGREASERS
ALL PURPOSE CLEANERS
STYLING MOUSE
CARBURETOR & CHOKE CLEANERS
WINDSHIELD DEICER
PHARMACEUTICALS
FLOOR WAXES OR POLISHES
COLOGNES
INSECT REPELLENTS
WAXES & POLISHES
STARCH & FABRIC FINISH
RUG & UPHOLSTERY CLEANERS
AFTERSHAVES
ANIMAL INSECTICIDES
PAINTS-OTHER RELATED PRODUCTS
SHAVING LATHERS
PERFUMES
SPOT REMOVERS
UNDERCOAT INGS
CARPET DEODORIZERS
SHOE POLISHES, WAXES & COLORANTS
WAXES & POLISHES LIQUIDS
DEPILATORIES
AOHESIVES
INSECT SPRAYS
CAULKING & SEALING COMPOUNDS
WINDOW & GLASS CLEANERS
HERBICIDES AND FUNGICIDES
LUBRICANTS AND SILICONES
METAL CLEANERS & POLISHES
TILE & BATHROOM CLEANERS
AUTO CLEANERS
OVEN CLEANERS
HIAR CARE PRODUCT - SHAMPOOS
SUNTAN LOTIONS
ANT I -STATIC SPRAYS
PREWASH STAIN REMOVERS
DRAIN OPENERS
TOTALS
(A/N)
A
A
N
A
A/N
A
N
A
A
A
A
A
A
A/N
A
N
A
A/N
A
A
A
A
A
A
A
A
A/N
A
A/N
A/N
N
A
A
A/N
A/N
A/N
.A/N
A
N
A
A/N
A/N
A/N
A
A
A/N
A/N
LOW
2,682
2,026
1,116
687
580
430
328
291
267
289
159
153
130
121
116
85
85
65
63
63
61
58
51
48
42
38
36
24
19
12
11
3
0
149
0
0
0
0
0
0
0
0
0
0
0
0
0
10,288
HIGH
3,189
2,242
1,118
1,934
602
511
328
291
267
324
3,246
153
463
161
165
85
85
158
306
143
463
58
93
48
120
38
36
82
19
91
44
3
43,181
2,984
1,342
1,133
1,016
514
372
332
199
102
50
21
1
0
0
68,114
6-8
AVERAGE
2,935
2,134
1,117
1,310
591
471
328
291
267
307
1,702
153
296
141
141
85
85
112
184
103
262
58
72
48
81
38
36
53
19
52
27
3
21,591
1,566
671
566
508
257
186
166
100
51
25
10
1
0
0
39,201
TOTAL PROC EMISSIONS (tons)
LOW
2,458
1,681
1,116
687
580
430
328
291
267
243
159
153
130
121
116
85
85
65
63
63
61
58
51
48
42
38
32
24
19
12
11
3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
HIGH
3,189
2,242
1,118
1,683
602
511
328
291
267
324
3,246
153
463
161
165
85
85
158
306
143
463
58
93
48
120
38
36
82
19
91
44
3
43,181
2,984
1,342
1,133
1,016
514
372
332
199
102
50
21
1
0
0
AVERAGE
2,823
1,962
1,117
1,185
591
471
328
291
267
284
1,702
153
296
141
141
85
85
112
184
103
262
58
72
48
81
38
34
53
19
52
27
3
21,591
1,492
671
566
508
257
186
166
100
51
25
10
1
0
0
9,521 67,863
38,692
-------
TABLE 8. CONSUMER PRODUCT SUB-CATEGORIES RANKED IN ORDER
OF HIGH TOTAL PROC EMISSIONS
STATE OF CALIFORNIA
VOC & PROC EMISSIONS
AEROSOL/ TOTAL VOC EMISSIONS (tons)
CONSUMER PRODUCT SUB- CATEGORY
ADHESIVES
PAINTS, PRIMERS, VARNISHES
ALL PURPOSE CLEANERS
INSECT SPRAYS
HAIR SPRAYS
ROOM DEODORANTS & DISINFECTANTS
CAULKING & SEALING COMPOUNDS
CAR POLISHES & WAXES
WINDOW & GLASS CLEANERS
HERBICIDES, FUNGICIDES
MOTH CONTROL PRODUCTS
LUBRICANTS AND SI LI CONES
PERSONAL DEODORANTS
RUG & UPHOLSTERY CLEANERS
CARBURETOR & CHOKE CLEANERS
METAL CLEANERS & POLISHES
TILE & BATHROOM CLEANERS
AUTO ANTIFREEZES
ENGINE DEGREASERS
BREAK CLEANERS
WAXES & POLISHES
ENGINE STARTING FLUIDS
AUTO CLEANERS
PHARMACEUTICALS
WINDSHIELD DEICER
INSECT REPELLENTS
STYLING MOUSE
STARCH & FABRIC FINISH
SHAVING LATHERS
OVEN CLEANERS
ANIMAL INSECTICIDES
SHOE POLISHES, WAXES & COLORANTS
FLOOR WAXES OR POLISHES
COLOGNES
UNDERCOAT INGS
AFTERSHAVES
HAIR CARE PRODUCTS - SHAMPOOS
PAINTS-OTHER RELATED PRODUCTS
WAXES & POLISHES LIQUIDS
PERFUMES
SPOT REMOVERS
SUNTAN LOTIONS
CARPET DEODORIZERS
DEPILATORIES
ANT I -STATIC SPRAYS
PREWASH STAIN REMOVERS
DRAIN OPENERS
TOTALS
HUN-MCK.
(A/N)
A
A
A
A/N
A
A
A/N
N
A/N
A/N
A/N
A
A
A
A
N
A
N
A
A
A
A
A/N
A
A/N
A/N
A
A
A
A/N
A
A/N
N
A
A
A
A/N
A
N
A
A/N
A
A/N
A
A
A/N
A/N
LOW
0
10,424
603
529
7,685
2,436
0
4,619
0
0
2,059
0
1,476
215
460
0
0
1,165
1,026
1,032
212
949
0
454
429
230
543
222
140
0
182
43
309
303
86
205
0
170
40
135
127
0
69
11
0
0
0
38,587
HIGH
153,223
12,392
12,324
10,588
8,505
6,863
4,761
4,630
3,939
3,605
2', 136
1,825
1,752
1,645
1,642
1,320
1,180
1,165
1,150
1,032
1,030
949
707
646
572
561
543
508
402
370
329
323
309
303
291
205
177
170
155
135
127
81
69
12
5
0
0
244,656
6-9
AVERAGE
76,612
11,408
6,463
5,558
8,095
4,650
2,380
4,625
1,970
1,803
2,098
913
1,614
930
1,051
660
590
1,165
1,088
1,032
621
949
354
550
501
396
543
365
271
185
255
183
309
303
188
205
89
170
97
135
127
41
69
11
3
0
0
141,622
TOTAL PROC EMISSIONS (tons)
LOW
0
9,554
603
0
6,377
2,436
0
4,619
0
0
2,059
0
1,476
215
460
0
0
1,165
863
1,032
212
949
0
454
429
230
543
222
140
0
182
43
309
303
86
205
0
170
40
135
114
0
69
11
0
0
0
HIGH
153,223
12,392
12,324
10,588
8,505
5,971
4,761
4,630
3,939
3,605
2,136
1,825
1,752
1,645
1,642
1,320
1,180
1,165
1,150
1,032
1,030
949
707
646
572
561
543
508
402
370
329
323
309
303
291
205
177
170
155
135
127
81
69
12
5
0
0
AVERAGE
76,612
10,973
6,463
5,294
7,441
4,204
2,380
4,625
1,970
1,803
2,098
913
1,614
930
1,051
660
590
1,165
1,006
1,032
621
949
354
550
501
396
543
365
271
185
255
183
309
303
188
205
89
170
97
135
120
41
69
11
3
0
0
35,703 243,764 139,734
-------
TABLE 8. CONSUMER PRODUCT SUB-CATEGORIES RANKED IN ORDER
OF HIGH TOTAL PROC EMISSIONS (continued)
STATE OF NEW YORK
VOC & PROC EMISSIONS
AEROSOL/ TOTAL VOC EMISSIONS (tons)
1
CONSUMER PRODUCT SUB -CATEGORY
ADHESIVES
ALL PURPOSE CLEANERS
PAINTS, PRIMERS, VARNISHES
INSECT SPRAYS
HAIR SPRAYS
ROOM DEODORANTS & DISINFECTANTS
CAULKING & SEALING COMPOUNDS
WINDOW & GLASS CLEANERS
CAR POLISHES & WAXES
HERBICIDES AND FUNGICIDES
MOTH CONTROL PRODUCTS
LUBRICANTS AND SILICONES
PERSONAL DEODORANTS
RUG & UPHOLSTERY CLEANERS
CARBURETOR & CHOKE CLEANERS
METAL CLEANERS & POLISHES
TILE & BATHROOM CLEANERS
AUTO ANTIFREEZES
ENGINE DEGREASERS
WAXES & POLISHES
BRAKE CLEANERS
ENGINE STARTING FLUIDS
AUTO CLEANERS
PHARMACEUTICALS
WINDSHIELD DEICER
INSECT REPELLENTS
STYLING MOUSE
STARCH & FABRIC FINISH
SHAVING LATHERS
OVEN CLEANERS
ANIMAL INSECTICIDES
SHOE POLISHES, WAXES & COLORANTS
FLOOR WAXES OR POLISHES
COLOGNES
UNDERCOATINGS
AFTERSHAVES
HAIR CARE PRODUCTS - SHAMPOOS
PAINTS-OTHER RELATED PRODUCTS
WAXES & POLISHES LIQUIDS
PERFUMES
SPOT REMOVERS
SUNTAN LOTIONS
CARPET DEODORIZERS
DEPILATORIES
ANT I -STATIC SPRAYS
PREUASH STAIN REMOVERS
DRAIN OPENERS
TOTALS
fflJN'ACK.
(A/N)
A
A '
A
A/N
A
A
A/N
A/N
N
A/N
A/N
A
A
A
A
N
A
N
A
A
A
A
A/N
A
a/n
A/N
A
A
A
A/N
A
A/N
N
A
A
A
A/N
A
N
A
A/N
A
A/N
A
A
A/N
A/N
'
LOW
0
236
3,980
221
3,006
1,019
0
0
1,656
0
861
0
639
90
192
0
0
487
429
93
431
397
0
172
179
96
227
93
62
0
76
18
127
127
36
86
0
71
17
57
53
0
29
5
0
0
0
15,267
HIGH
64,075
4,816
4,731
4,428
3,327
2,870
1,991
1,681
1,660
1,508
893
763
758
688
687
552
493
487
481
454
431
397
296
245
239
235
227
212
178
i 152
138
135
127
127
122
86
74
71
65
57
53
31
29
5
2
0
0
101,075
6-10
AVERAGE
32,038
2,526
4,356
2,324
3,167
1,944
995
840
1,658
754
877
382
699
389
439
276
247
487
455
273
431
397
148
209
209
165
227
153
120
76
107
77
127
127
79
86
37
71
41
57
53
16
29
5
1
0
0
58,171
TOTAL PROC EMISSIONS (tons)
LOW
0
236
3,648
0
2,495
1,019
0
0
1,656
0
861
0
639
90
192
0
0
487
361
93
431
397
0
172
179
96
227
93
62
0
76
18
127
127
36
86
0
71
17
57
48
0
29
5
0
0
0
HIGH
64,075
4,816
4,731
4,428
3,327
2,497
1,991
1,681
1,660
1,508
893
763
758
688
687
552
493
487
481
454
431
397
296
245
239
235
227
212
178
152
138
135
127
127
122
86
74
71
65
57
53
31
29
5
2
0
0
AVERAGE
32,038
2,526
4,190
2,214
2,911
1,758
995
840
1,658
754
877
' 382
699
389
439
276
247
487
421
273
431
397
148
209
209
165
227
153
120
76
107
77
127
127
79
86
37
71
41
57
50
16
29
5
1
0
0
14,128 100,702 57,415
-------
TABLE 8. CONSUMER PRODUCT SUB-CATEGORIES RANKED IN ORDER
OF HIGH TOTAL PROC EMISSIONS (continued)
STATE OF NEW JERSEY
VOC & PROC EMISSIONS
AEROSOL/ TOTAL VOC EMISSIONS (tons)
CONSUMER PRODUCT SUB -CATEGORY
ADHESIVES
ALL PURPOSE CLEANERS
PAINTS, PRIMERS, VARNISHES
INSECT SPRAYS
HAIR SPRAYS
ROOM DEODORANTS & DISINFECTANTS
CAULKING & SEALING COMPOUNDS
WINDOW & GLASS CLEANERS
CAR POLISHES & WAXES
HERBICIDES AND FUNGICIDES
MOTH CONTROL PRODUCTS
LUBRICANTS AND SILICONES
PERSONAL DEODORANTS
RUG & UPHOLSTERY CLEANERS
CARBURETOR & CHOICE CLEANERS
METAL CLEANERS & POLISHES
TILE & BATHROOM CLEANERS
AUTO ANTIFREEZES
ENGINE DEGREASERS
UAXES & POLISHES
BRAKE CLEANERS
ENGINE STARTING FLUIDS
AUTO CLEANERS
PHARMACEUTICALS
WINDSHIELD DEICER
INSECT REPELLENTS
STYLING MOUSE
STARCH & FABRIC FINISH
SHAVING LATHERS
OVEN CLEANERS
ANIMAL INSECTICIDES
SHOE POLISHES, WAXES & COLORANTS
FLOOR WAXES OR POLISHES
COLOGNES
UNDERCOAT INGS
AFTERSHAVES
HIAR CARE PRODUCT SHAMPOOS
PAINTS-OTHER RELATED PRODUCTS
WAXES & POLISHES LIQUIDS
PERFUMES
SPOT REMOVERS
SUNTAN LOTIONS
CARPET DEODORIZERS
DEPILATORIES
ANTI- STATIC SPRAYS
PREWASH STAIN REMOVERS
DRAIN OPENERS
TOTALS
nun-ACK.
(A/N)
A
A
A
A/N
A
A
A/N
A/N
N
A/N
A/N
A
A
A
A
N
A-
N
A
A
A
A
A/N
A
A/N
A/N
A
A
A
A/N
A
A/N
N
A
A
A
A/N
A
N
A
A/N
A
A/N
A
A
A/N
A/N
LOW
0
159
2,682
149
2,026
687
0
0
1,116
0
580
0
430
61
130
0
0
328
289
63
291
267
0
116
121
65
153
63
42
0
51
12
85
85
24
58
0
48
11
38
36
0
19
3
0
0
0
10,288
HIGH
43,181
3,246
3,189
2,984
2,242
1,934
1,342
1,133
1,118
1,016
602
514
511
463
463
372
332
328
324
306
291
267
199
165
161
158
153
143
120
102
93
91
85
85
82
58
50
48
44
38
36
21
19
3
1
0
0
68,114
6-11
AVERAGE
21,591
1,702
2,935
1,566
2,134
1,310
671
566
1,117
508
591
257
471
262
296
186
166
328
307
184
291
267
100
141
141
112
153
103
81
51
72
52
85
85
53
58
25
48
27
38
36
10
19
3
1
0
0
39,201
TOTAL PROC EMISSIONS (tons)
LOW
0
159
2,458
0
1,681
687
0
0
1,116
0
580
0
430
61
130
0
0
328
243
63
291
267
0
116
121
65
153
63
42
0
51
12
85
85
24
58
0
48
11
38
32
0
19
3
0
0
0
HIGH
43,181
3,246
3,189
2,984
2,242
1,683
1,342
1,133
1,118
1,016
602
514
511
463
463
372
332
328
324
306
291
267
199
165
161
158
153
143
120
102
93
91
85
85
82
58
50
48
44
38
36
21
19
3
1
0
0
AVERAGE
21,591
1,702
2,823
1,492
1,962
1,185
671
566
1,117
508
591
257
471
262
296
186
166
328
284
184
291
267
100
141
141
112
153
103
81
51
72
52
85
85
53
58
25
48
27
38
34
10
19
3
1
0
0
9,521
67,863 38,692
-------
TABLE 9. CONSUMER PRODUCT SUB-CATEGORIES RANKED IN ORDER
OF AVERAGE TOTAL PROC EMISSIONS
STATE OF CALIFORNIA
VOC & PROC EMISSIONS
AEROSOL/ TOTAL VOC EMISSIONS (tons)
CONSUMER PRODUCT SUB -CATEGORY
ADHESIVES
PAINTS, PRIMERS, VARNISHES
HAIR SPRAYS
ALL PURPOSE CLEANERS
INSECT SPRAYS
CAR POLISHES & WAXES
ROOM DEODORANTS & DISINFECTANTS
CAULKING & SEALING COMPOUNDS
MOTH CONTROL PRODUCTS
WINDOW & GLASS CLEANERS
HERBICIDES, FUNGICIDES
PERSONAL DEODORANTS
AUTO ANTIFREEZES
CARBURETOR & CHOICE CLEANERS
BREAK CLEANERS
ENGINE DEGREASERS
ENGINE STARTING FLUIDS
RUG & UPHOLSTERY CLEANERS
LUBRICANTS AND SILICONES
METAL CLEANERS & POLISHES
WAXES & POLISHES
TILE & BATHROOM CLEANERS
PHARMACEUTICALS
STYLING MOUSE
WINDSHIELD DEICER
INSECT REPELLENTS
STARCH & FABRIC FINISH
AUTO CLEANERS
FLOOR WAXES OR POLISHES
COLOGNES
SHAVING LATHERS
ANIMAL INSECTICIDES
AFTERSHAVES
UNDERCOAT INGS
OVEN CLEANERS
SHOE POLISHES, WAXES & COLORANTS
PAINTS-OTHER RELATED PRODUCTS
PERFUMES
SPOT REMOVERS
WAXES & POLISHES LIQUIDS
HAIR CARE PRODUCTS - SHAMPOOS
CARPET DEODORIZERS
SUNTAN LOTIONS
DEPILATORIES
ANTI- STATIC SPRAYS
PREWASH STAIN REMOVERS
DRAIN OPENERS
TOTALS
NUN-ACK.
(A/N)
A
A
A
A
A/N
N
A
A/N
A/N
A/N
A/N
A
N
A
A
A
A
A
A
N
A
A
A
A
A/N
A/N
A
A/N
N
A
A
A
A
A
A/N
A/N
A
A
A/N
N
A/N
A/N
A
A
A
A/N
A/N
LOW
0
10,424
7,685
603
529
4,619
2,436
0
2,059
0
0
1,476
1,165
460
1,032
1,026
949
215
0
0
212
0
454
543
429
230
222
0
309
303
140
182
205
86
0
43
170
135
127
40
0
69
0
11
0
0
0
38,587
HIGH
153,223
12,392
8,505
12,324
10,588
4,630
6,863
4,761
2,136
3,939
3,605
1,752
1,165
1,642
1,032
1,150
949
1,645
1,825
1,320
1,030
1,180
646
543
572
561
508
707
309
303
402
329
205
291
370
323
170
135
127
155
177
69
81
12
5
0
0
244,656
6-12
AVERAGE
76,612
11,408
8,095
6,463
5,558
4,625
4,650
2,380
2,098
,970
,803
,614
,165
,051
,032
,088
949
930
913
660
621
590
550
543
501
396
365
354
309
303
271
255
205
188
185
183
170
135
127
97
89
69
41
11
3
0
0
141,622
TOTAL PROC EMISSIONS (tons)
LOW
0
9,554
6,377
603
0
4,619
2,436
0
2,059
0
0
1,476
1,165
460
1,032
863
949
215
0
0
212
0
454
543
429
230
222
0
309
303
140
182
205
86
0
43
170
135
114
40
0
69
0
11
0
0
0
HIGH
153,223
12,392
8,505
12,324
10,588
4,630
5,971
4,761
2,136
3,939
3,605
1,752
1,165
1,642
1,032
1,150
949
1,645
1,825
1,320
1,030
1,180
646
543
572
561
508
707
309
303
402
329
205
291
370
323
170
135
127
155
177
69
81
12
5
0
0
AVERAGE
76,612
10,973
7,441
6,463
5,294
4,625
4,204
2,380
2,098
1,970
1,803
1,614
1,165
1,051
1,032
1,006
949
930
913
660
621
590
550
543
501
396
365
354
309
303
271
255
205
188
185
183
170
135
120
97
89
69
41
11
3
0
0
35,703 243,764 139,734
-------
TABLE 9. CONSUMER PRODUCT SUB-CATEGORIES RANKED IN ORDER
OF AVERAGE TOTAL PROC EMISSIONS (continued)
STATE OF NEW YORK
VOC & PROC EMISSIONS
AEROSOL/ TOTAL VOC EMISSIONS (tons)
CONSUMER PRODUCT SUB-CATEGORY
ADHESIVES
PAINTS, PRIMERS, VARNISHES
HAIR SPRAYS
ALL PURPOSE CLEANERS
INSECT SPRAYS
ROOM DEODORANTS & DISINFECTANTS
CAR POLISHES & WAXES
CAULKING & SEALING COMPOUNDS
MOTH CONTROL PRODUCTS
WINDOW & GLASS CLEANERS
HERBICIDES AND FUNGICIDES
PERSONAL DEODORANTS
AUTO ANTIFREEZES
CARBURETOR & CHOKE CLEANERS
BRAKE CLEANERS
ENGINE DEGREASERS
ENGINE STARTING FLUIDS
RUG & UPHOLSTERY CLEANERS
LUBRICANTS AND SI LI CONES
METAL CLEANERS & POLISHES
WAXES & POLISHES
TILE & BATHROOM CLEANERS
STYLING MOUSE
WINDSHIELD DEICER
PHARMACEUTICALS
INSECT REPELLENTS
STARCH & FABRIC FINISH
AUTO CLEANERS
FLOOR WAXES OR POLISHES
COLOGNES
SHAVING LATHERS
ANIMAL INSECTICIDES
AFTERSHAVES
UNDERCOAT INGS
SHOE POLISHES, WAXES & COLORANTS
OVEN CLEANERS
PAINTS-OTHER RELATED PRODUCTS
PERFUMES
SPOT REMOVERS
WAXES & POLISHES LIQUIDS
HAIR CARE PRODUCTS - SHAMPOOS
CARPET DEODORIZERS
SUNTAN LOTIONS
DEPILATORIES
ANTI -STATIC SPRAYS
PREWASH STAIN REMOVERS
DRAIN OPENERS
TOTALS
NUN-HGK.
(A/N)
A
A
A
A
A/N
A
N
A/N
A/N
A/N
A/N
A
N
A
A
A
A
A
A
N
A
A
A
a/n
A
A/N
A
A/N
N
A
A
A
A
A
A/N
A/N
A
A
A/N
N
A/N
A/N
A
A
A
A/N
A/N
LOW
0
3,980
3,006
236
221
1,019
1,656
0
861
0
0
639
487
192
431
429
397
90
0
0
93
0
227
179
172
96
93
0
127
127
62
76
86
36
18
0
71
57
53
17
0
29
0
5
0
0
0
15,267
HIGH
64,075
4,731
3,327
4,816
4,428
2,870
1,660
1,991
893
1,681
1,508
758
487
687
431
481
397
688
763
552
454
493
227
239
245
235
212
296
127
127
178
138
86
122
135
152
71
57
53
65
74
29
31
5
2
0
0
101,075
6-13
AVERAGE
32,038
4,356
3,167
2,526
2,324
1,944
1,658
995
877
840
754
699
487
439
431
455
397
389
382
276
273
247
227
209
209
165
153
148
127
127
120
107
86
79
77
76
71
57
53
41
37
29
16
5
1
0
0
58,171
TOTAL PROC EMISSIONS (tons)
LOW
0
3,648
2,495
236
0
1,019
1,656
0
861
0
0
639
487
192
431
361
397
90
0
0
93
0
227
179
172
96
93
0
127
127
62
76
86
36
18
0
71
57
48
17
0
29
0
5
0
0
0
HIGH
64,075
4,731
3,327
4,816
4,428
2,497
1,660
1,991
893
1,681
1,508
758
487
687
431
481
397
688
763
552
454
493
227
239
245
235
212
296
127
127
178
138
86
122
135
152
71
57
53
65
74
29
31
5
2
0
0
AVERAGE
32,038
4,190
2,911
2,526
2,214
1,758
1,658
995
877
840
754
699
487
439
431
421
397
389
382
276
273
247
227
209
209
165
153
148
127
127
120
107
86
79
77
76
71
57
50
41
37
29
16
5
1
0
0
14,128 100,702 57,415
-------
TABLE 9. CONSUMER PRODUCT SUB-CATEGORIES RANKED IN ORDER
OF AVERAGE TOTAL PROC EMISSIONS (continued)
STATE OF NEW JERSEY
VOC & PROC EMISSIONS
AEROSOL/ TOTAL VOC EMISSIONS (tons)
CONSUMER PRODUCT SUB -CATEGORY
ADHESIVES
PAINTS, PRIMERS, VARNISHES
HAIR SPRAYS
ALL PURPOSE CLEANERS
INSECT SPRAYS
ROOM DEODORANTS & DISINFECTANTS
CAR POLISHES & WAXES
CAULKING & SEALING COMPOUNDS
MOTH CONTROL PRODUCTS
WINDOW & GLASS CLEANERS
HERBICIDES AND FUNGICIDES
PERSONAL DEODORANTS
AUTO ANTIFREEZES
CARBURETOR & CHOKE CLEANERS
BRAKE CLEANERS
ENGINE DEGREASERS
ENGINE STARTING FLUIDS
RUG & UPHOLSTERY CLEANERS
LUBRICANTS AND SILICONES
METAL CLEANERS & POLISHES
WAXES & POLISHES
TILE & BATHROOM CLEANERS
STYLING MOUSE
WINDSHIELD DEICER
PHARMACEUTICALS
INSECT REPELLENTS
STARCH & FABRIC FINISH
AUTO CLEANERS
FLOOR WAXES OR POLISHES
COLOGNES
SHAVING LATHERS
ANIMAL INSECTICIDES
AFTERSHAVES
UNDERCOAT INGS
SHOE POLISHES, WAXES & COLORANTS
OVEN CLEANERS
PAINTS-OTHER RELATED PRODUCTS
PERFUMES
SPOT REMOVERS
WAXES & POLISHES LIQUIDS
HIAR CARE PRODUCT - SHAMPOOS
CARPET DEODORIZERS
SUNTAN LOTIONS
DEPILATORIES
ANT I -STATIC SPRAYS
PREWASH STAIN REMOVERS
DRAIN OPENERS
TOTALS
(A/N)
A
A
A
A
A/N
A
N
A/N
A/N
A/N
A/N
A
N
A
A
A
A
A
A
N
A
A
A
A/N
A
A/N
A
A/N
N
A
A
A
A
A
A/N
A/N
A
A
A/N
N
A/N
A/N
A
A
A
A/N
A/N
LOW
0
2,682
2,026
159
149
687
1,116
0
580
0
0
430
323
130
291
289
267
61
0
0
63
0
153
121
116
65
63
0
85
85
42
51
58
24
12
0
48
38
36
11
0
19
0
3
0
0
0
10,288
HIGH
43,181
3,189
2,242
3,246
2,984
1,934
1,118
1,342
602
1,133
1,016
511
328
463
291
324
267
463
514
372
306
332
153
161
165
158
143
199
85
85
120
93
58
82
91
102
48
38
36
44
50
19
21
3
1
0
0
68,114
6-14
AVERAGE
21,591
2,935
2,134
1,702
1,566
1,310
1,117
671
591
566
508
471
328
296
291
307
267
262
257
186
184
166
153
141
141
112
103
100
85
85
81
72
58
53
52
51
48
38
36
27
25
19
10
3
1
0
0
39,201
TOTAL PROC EMISSIONS (tons)
LOW
0
2,458
1,681
159
0
687
1,116
0
580
0.
0
430
328
130
291
243
267
61
0
0
63
0
153
121
116
65
63
0
.85
85
42
51
58
24
12
0
48
38
32
11
0
19
0
3
0
0
0
HIGH
43,181
3,189
2,242
3,246
2,984
1,683
1,118
1,342
602
1,133
1,016
511
328
463
291
324
267
463
514
372
306
332
153
161
165
158
143
199
85
85
120
93
58
82
91
102
48
38
36
44
50
19
21
3
1
0
0
AVERAGE
21,591
2,823
1,962
1,702
1,492
1,185
1,117
671
591
566
508
471
328
296
291
284
267
262
257
186
184
166
153
141
141
112
103
100
85
85
81
72
58
53
52
51
48
38
34
27
25
19
10
3
1
0
0
9,521 67,863
38,692
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D/834-025-68a/#19
TABLE 10. VOC AND PROC RATIOS FOR PRODUCT CATEGORIES IN CALIFORNIA
VOC (Low)/ PROC (Low)/ PROC (Low)/ PROC (High)/
Product Categories VOC (High) PROC (High) VOC (Low) VOC (High)
Aerosol Spray Products
Insect Sprays
Paints and Finishes
Household Products
Personal Products
Animal Products
Automotive and
Industrial Products
Miscellaneous Products
Non-Aerosol Products
Personal Products
Household Products
Automotive Products
0.22
0.84
0.02
0.86
0.49
0.00
0.20
1.00
0.18
0.77
0.02
0.76
__
0.47
0.00
.20
1.00
0.82
0.92
1.00
0.88
0.96
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
Garage Products
Total Emissions 0.16 0.15 0.92 1.00
6-15
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C/834-025-68a/#20
TABLE 11. VOC AND PROC RATIOS FOR PRODUCT CATEGORIES IN NEW YORK
VOC (Low)/ PROC (Low)/ PROC (Low)/ PROC (High)/
Product Categories VOC (High) PROC (High) VOC (Low) VOC (High)
Aerosol Spray Products
Insect Sprays 0.22 0.18 0.82 1.00
Paints and Finishes 0.84 0.77 0.92 1.00
Household Products 0.02 0.02 1.00 1.00
Personal Products 0.86 0.76 .88 1.00
Animal Products
Automotive and 0.49 0.47 0.96 1.00
Industrial Products
Miscellaneous Products 0.00 0.00 1.00
Non-Aerosol Products
Personal Products
Household Products 0.19 0.19 1.00 1.00
Automotive Products 1.00 1.00 1.00 1.00
Garage Products
Total Emissions 0.15 0.14 0.93 1.00
6-16
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C/834-025-68a/#21
TABLE 12. VOC AND PROC RATIOS FOR PRODUCT CATEGORIES IN NEW JERSEY
Product
Aerosol
Categories
Spray Products
VOC
VOC
(Low)/
(High)
PROC
PROC
(Low)/
(High)
PROC
VOC
(Low)/
(Low)
PROC
VOC
(High)/
(High)
Insect Sprays 0.22 0.18 0.82 1.00
Paints and Finishes 0.84 0.77 0.92 1.00
Household Products 0.02 0.02 1.00 1.00
Personal Products 0.86 0.76 0.86 1.00
Animal Products
Automotive and 0.48 0.47 0.96 1.00
Industrial Products
Miscellaneous Products
Non-Aerosol Products
Personal Products
Household Products 0.19 0.19, 1.00 1.00
Automotive Products 1.00 1.00 1.00 1.00
Garage Products
Total Emissions 0.15 0.14 0.93 1.00
6-17
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D/834-025-68a/#14
TABLE 13. ADDITIONAL VOC AND PROC EMISSIONS
Emissions (tons)
Product CA NJ1 NY1
Brake fluid for master cylinder
(ethylene glycol monethyl ethers
88,000 tons x 0.2 estimated
emission factor)
Gas driers (methanol)
Ball point and porous tip pens
(ethylene glycol)
Rubbing alcohol
Nail polish
Total
17,600
600
18
1,150
136
19,504
7,630
260
8
499
59
8,456
5,916
201
6
387
46
6,556
Based upon per capita emissions from California.
Source: Rogozen et al., (1985)
6-18
-------
TABLE 14
PER CAPITA AVERAGE VOC AND PROC EMISSIONS (LB/PERSQN)
Category
Aerosol:
Insect Sprays
Paints and Finishes
Household Products
Personal Products
Autoiotive and Indust.
Herbicides and Fungicides
Non-Aerosol:
Household
Autoiotive
CA
0.67
0.93
7.64
0.95
0.49
0.15
0.09
0.46
VOC
NJ
0.56
0.71
6.37
0.76
0.41
0.12
0.07
0.35
NY
0.64
0.82
7.33
0.88
0.47
0.14
0.08
0.40
CA
0.65
0.89
7.60
0.90
0.48
0.15
0.09
0.46
PROC
NJ
0.54
0.69
6.34
0.72
0.40
0.12
0.07
0.35
NY
0.62
0.79
7.3
0.83
0.46
0.14
0.08
0.40
Total Emissions 11.38 9.40 10.80 11.23 9.28 10.66
6-19
-------
TABLE 15
PER CAPITA LOU VOC AND PSOC EMISSIONS (LB/PERSQN)
VOC PROC
Category CA NJ NY CA NJ NY
Aerosol:
Insect Sprays 0.24 0.20 0.23 0.20 0.17 0.19
Paints and Finishes 0.85 0.65 0.75 0.78 0.60 0.69
Household Products 0.32 0.26 0.30 0.32 0.26 0.30
Personal Products 0.88 0.70 0.81 0.77 0.62 0.72
Autoiotive and Indust. 0.32 0.27 0.31 0.30 0.26 0.30
Herbicides and Fungicides 0.00 0.00 0.00 0.00 0.00 0.00
Non-Aerosol:
Household 0.03 0.02 0.03 0.03 0.02 0.03
Autoiotive 0.46 0.34 0.40 0.46 0.34 0.40
Total Eiissions 3.11 2.49 2.85 2.88 2.31 2.64
TABLE 16
PER CAPITA HIGH VOC AND PROC EMISSIONS (LB/PERSON)
Category
Aerosol:
Insect Sprays
Paints and Finishes
Household Products
Personal Products
Autoiotive and Indust.
Herbicides and Fungicides
Non-Aerosol:
Household
Autoiotive
CA
1.09
1.01
14.96
1.02
0.66
0.29
0.14
0.47
VOC
NJ
0.92
0.77
12.49
0.82
0.55
0.24
0.11
0.35
NY
1.05
0.89
14.39
0.95
0.63
0.26
0.14
0.40
CA
1.09
1.01
14.89
1.02
0.66
0.29
0.14
0.47
PROC
NJ
0.92
0.77
12.43
0.82
0.55
0.24
0.11
0.35
NY
1.05
0.89
14.30
0.95
0.63
0.28
0.14
0.40
Total Eiissions 19.65 16.30 18.74 19.56 16.24 18.67
6-20
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B/834-025-68a/#15
APPENDIX A
-------
B/834-025-68b/#2
INSECTICIDES - AEROSOL AND NONAEROSOL
National Consumption Population Geographic
(million Ib) Apportionment Multiplier
192.51 .11 (CA)2 NA
.046 (NY)
.031 (NJ)
(1982)
2U.S. Bureau of the Census (1986)
-1-
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B/834-025-68b/#2
INSECTICIDE FORMULATIONS
Percent VOC PROC
By Weight Volatility Emitted(%) Emitted(%)
Formula 1 86.5 86.5
Sevin 3.0 NV
Malathion 4.0 NV
Folpet (fungicide) 5.0 NV
Kelthane 1.5 NV
Inert ingredients 86.5 V
Formula 2 100.0 100.0
DDVP 18.6 V
Related compounds 1.4 V
Inert ingredients 80.0 V
Formula 3 99.3 99.3
d-trans Allethrin
(5-Benzyl-3-furyl) methyl-2,
2-dimethyl-3 , 2-methylpropenyl
cyclopropane carboxylate
Related compounds
Petroleum distillate
Sodium nitrite
Inert ingredients
Butane/Isobutane propellant
Formula 4
Baygon
DDVP
Petroleum distillates
Inert ingredients
Butane/Isobutane
Formula 5
Pyrethrins
Piperonyl butoxide
Petroleum distillates
Inert ingredients
Butane/Isobutane
0.50
0.08
0.01
10.20
0.08
59.12
30.00*
1.00
0.20
1.04
67.91
30.00*
0.25
0.80
1.04
67.91
30.00*
NV
NV
NV
V
-
V
V
99.0 99.0
NV
V
V
V
V
99.0 99.0
NV
NV
V
V
V
*Estimated from WAIB (1981) and CSMA (1986)
-2-
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B/834-025-68b/#2
INSECTICIDE FORMULATIONS (Continued)
Formula 6
Pyrethrins
Piperonyl butoxide
Petroleum distillates
Inert ingredients
Butane/Isobutane
Formula 7
d-trans Allethrin
Piperonyll butoxide
MGK 264
Petroleum distillates
Inert ingredients
Butane/Isobutane
Formula 8
Zinc dimethyl/dithiocarbamate
Endosulphan
Pyrethrins
Sulphoxide
Urea
Tensiofix LX
Tensiofix WP
Water
C02 propellant
Formula 9
Pyrethrins
Rotenone
Other Cube resins
Pine oil
Petroleum distillate
Inert ingredients
Butane/Isobutane
Formula 10
Insecticide solution in Kerosene
Span 85
Tveen 81
Deionized water
Butane
Percent
By Weight
0.50
1.00
11.83
58.00
30.00*
0.25
0.80
0.40
8.05
60.50
30.00*
0.12
0.68
0.16
0.20
0.40
0.06
0.04
43.34
5
0.06
0.01
0.02
0.90
0.40
68.61
30.00
15.5
1.5
1.0
42.0
40.0
Volatility
NV
NV
V
V
V
NV
NV
NV
V
V
V
NV
NV
NV
-
NV
NV
NV
-
V
NV
V
NV
V
V
V
V
V
NV
NV
-
V
VOC PROC
Emitted(%) Emitted(%)
98.5 98.5
98.6 98.6
5.0 5.0
99.9 99.9
55.5 55.5
*Estimated from WAIB (1981)
**Estimated from Chalimers/Bathe (1979)
-3-
-------
B/834-025-68b/tt2
INSECT REPELLENTS - AEROSOL AND NONAEROSOL
National Shipment Population Geographic
(million Ib) Apportionment Multiplier
121 .11 (CA)2 NA
.046 (NY)
.031 (NJ)
(1982)
2U.S. Bureau of the Census (1986)
-4-
-------
B/834-025-68b/t2
INSECT REPELLENT FORMULAS
% Composition
By Weight
Volatility
VOC PROC
Emitted(%) Emitted(X)
Formula 1*
N,N-Dialkyl-m-toluamide
Other isomers
Inert ingredients
14.25%
0.75
85.00
NV
NV
V
85.0
85.0
Formula 2a
N,N-Dialkyl-m-toluamide
Other isomers
N-Octyl-bicycloheptene
dicarboximide
2,3,4,5-Bis (2-butylene)
tetrahydro-2-furaldehyde
Inert ingredients
75.0
75.0
19.00%
1.00
4.00
1.00
75.00
NV
NV
NV
NV
Formula 3a
N,N-Dialkyl-m-toluamide
Other isomers
N-Octyl-bicycloheptene
dicarboximide
2,3,4,5-Bis (2-butylene)
tetrahydro-2-furaldehyde
Inert Ingredients
62.9
62.9
30.69%
1.00
4.31
1.08
62.92
NV
NV
NV
NV
V
Formula 4*
2-Ethyl-l,3-hexanediol '. 25.00%
N,N-Diethyl-m-toluamide 4.75
Other isomers 0.25
Inert ingredients and propellant 70.00
75.0
75.0
NV
NV
NV
V
Formula 5a
2-Ethyl-l,3-hexandeiol
N,N-Diethyl-m-toluamide
Other Isomers
Inert Ingredients
56.00%
8.65
0.45
34.90
34.9
34.9
NV
NV
NV
V
"Kline (1982)
-5-
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B/834-025-68b/#2
MOTH CONTROL PRODUCTS - AEROSOLS AND NONAEROSOLS
National Consumption Population Geographic
(million Ib) Apportionment Multiplier
391 .11 (CA)2 NA
=046 (NY)
.031 (NJ)
(1982)
2U.S. Bureau of the Census (1986)
-6-
-------
B/834-025-68b/f2
MOTH CONTROL PRODUCT FORMULAS
% Composition
By Weight Volatility
VOC PROC
Emitted(%) Emitted(%)
Formula la
Pyrethrin
Allethrin
N-octyl bicycloheptene
dicarboximide
Piperonyl butoxide
Essential cedar oil
Petroleum distillates
Inert ingredients
0.15
0.15
0.75
0.50
0.50
52.95
45.00
96.0
96.0
NV
NV
NV
NV
NV
V
V
Formula 2a
Cyclopropane carboxylate
Tetramethrin derivative
Phenoxybenzyl derivative
Related isomers
Isoparaffinic hydrocarbons
Inert ingredients
0.20
0.19
0.01
7.75
91.85
99.6
99.6
NV
NV
NV
V
V
'Kline (1982)
-7-
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B/834-025-68b/#2
ANIMAL INSECTICIDES - AEROSOL AND NONAEROSOL
National Consumption Population Geographic
(million Ib) Apportionment Multiplier
61 .11 (CA)2 NA
.046 (NY)
.031 (NJ)
(1982)
2U.S. Bureau of the Census (1986)
-8-
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B/834-025-68b/#2
ANIMAL INSECTICIDE FORMULAS
% Composition
By Weight Volatility
Formula 1
Pyrethrins
Piperonyl butoxide
Methoxychlor
Carbaryl (1-Naphthyl N-Methyl
carbomate)
2,3:4,5-Bis(2 Butylene) Tetra-
hydro-2-Furaldehyde
Petroleum distillate
Inert ingredients
Unknown ingredients (assume
half are volatile)
Formula 2
o-Isoproxyphenyl methylcarbomate
Inert ingredients
Unknown ingredients (assume
half are volatile)
Formula 3a
Benzyl Benzoate
Soap anhydrous
Chlordane
Inert ingredients
Unknown ingredients (assume
half are volatile)
Formula 4b
Pyrethrins
Piperonyl butoxide
2,3,4,5-Bis(2-Butylene) Tetra-
hydro-2-Furaldehyde
Petroleum distillate
Inert ingredients
Formula 5b
Pyrethrins
Piperonyl butoxide
N-octylbicycloheptenedicarboximide
2,3,4,5-Bis(2-Butylene) Tetra-
hydro-2-Furaldehyde
Petroleum distillate
Inert ingredients
.60
.48
.50
.50
.24
22.84
65.38
9.46
.25
89.84
10.11
33.80
7.50
.75
52.05
5.90
0.08%
TRACE
0.02
7.77
91.97
0.062
0.12
0.20
0.20
0.288
99.132
NV
NV
NV
NV
NV
V
V
4.73%V
NV
V
5.052V
NV
NV
NV
V
2.95%V
NV
NV
NV
V
V
NV
NV
NV
NV
V
V
VOC PROC
Emitted(%) Emitted(%;
92.9 92.9
94.9 94.9
55.0 55.0
99.7 99.7
99.4 99.4
'Source: Chalmers and Bathe (1979)
Kline (1982)
-9-
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B/834-025-68b/#2
PAINTS, PRIMERS, AND VARNISHES - AEROSOL
U.S.
Annual Unit
Distribution
(millions)
300. 61
Average
Unit Weight
(Ibs/unit)
.752
Population
Apportionment
.ll(CA)3
.046(NY)
.031(NJ)
Geographic
Multiplier
1.15(CA)5
1.05(NY)
1.05(NJ)
(1984); estimated millions of units filled in 1984
2WAIB (1981)
3U.S. Bureau of the Census (1986)
4 Simmons (1983)
-10-
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B/83A-025-68b/#2
PAINT FORMULAS
Percent
By Weight
Formulation 1*
Barium metaborate
Aluminum paste
Silicone resin
Xylol and driers
Aromatic hydrocarbons
Methylene chloride
Propane
Isobutane
Formulation 2*
Nonvolatile Compounds
Glycol ethers
Aliphatic and aromatic
hydrocarbons
Halogenated hydrocarbons1
Isobutane
Propane
Formulation 3*
Nonvolatile Compounds
Isobutane
Propane
Toluene
Xylene
Methylene chloride
Cellosolve acetate
Formulation 4a
Nonvolatile Compounds
Petroleum distillate
Aromatic hydrocarbons
Chlorinated solvents
Aliphatic hydrocarbon propellant
15/9
0.8
3.3
11.8
40.0
5.6
13.5
12,5
12.5
18.0
1.2
32.8
19.0
14.5
14.5
18.0
30.0
5.0
4.0
21.0
15.0
7.0
15.8
13.0
14.6
27.0
29.6
VOC
Volatility Emitted(%)
84.1
Lt
_
_
V
V
V
(Non-PROC)
V
V
82.0
NV
V
V
V
V
V
82.0
NV
V
V
V
V
V
(Non-PROC)
V
84.2
NV
V
V
V
V
PROC
Emitted(%)
70.6
82.0
67.0
84.2
'Poisindex (1984)
Replaced by aliphatic hydrocarbons such as butane, propane.
-11-
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B/834-025-68b/#2
PAINT FORMULAS (Continued)
Percent VOC PROC
By Weight Volatility Emitted(%) Emitted(X)
Formulation 5a
Nonvolatile Compounds
Chlorinated solvents
Aliphatic hydrocarbons
Aliphatic thinner
Formulation 6a
Nonvolatile Compounds
Dioctyl phthalate plasticizer
Aromatic hydrocarbons
Esters and ketones
Acetone and chlorinated
solvents
Halogenated hydrocarbon
propellant
26.9%
21.0%
23.1%
29.0%
13.1%
1.4%
9.5%
11.0%
35.0%
30.0%
73.1 73.1
NV
V
V
V
86.9 86.9
NV
V
V
V
V
V
*Poisindex (1984)
Replaced by aliphatic hydrocarbons such as butane, propane.
-12-
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B/834-025-68b/#2
PAINTS AND FINISHES - RELATED PRODUCTS - AEROSOLS
U.S.
Annual Unit
Distribution
(millions)
6.91
Average
Unit Weight
(Ib/unit)
.692
Population
Apportionment
.ll(CA)3
.46 (NY)
.31(NJ)
Geographic
Multiplier
NA
NA = not available
(1984); millions of Ibs sold in 1984
2WAIB (1981)
3U.S. Bureau of the Census (1986)
-13-
-------
B/834-025-68b/#2
PAINTS AND FINISHES - OTHER RELATED PRODUCTS
Percent VOC PROC
By Weight Volatility Emitted^) Emitted(%)
Formula la
Isopropanol 65%
Water 16%
Phosphoric Acid 19%
'Gosselin (1984)
-14-
-------
B/834-025-68b/#2
ROOM DEODORANTS AND DISINFECTANTS - AEROSOLS AND NONAEROSOLS
U.S.
Annual Unit
Distribution
(millions)
265. 51
Average
Unit Weight
(Ib/unit)
.52
Population
Apportionment
.ll(CA)3
.046(NY)
.031(NJ)
Geographic
Multiplier
.94(CA)4
.94(NY)
.94(NJ)
Estimated from Simmons (1983)
2WAIB (1981)
3U.S. Bureau of the Census (1986)
4 Simmons (1983)
-15-
-------
3/834-025-68b/#2
ROOM DEODORANT FORMULAS
Formula la
Triethylene glycol
Isopropyl alcohol
Water
Perfume
Carbon Dioxide
Formula 2a
Propylene glycol
Ethyl alcohol
Methylene chloride
Perfume
Carbon dioxide
Formula 3a
Perfume
Span 85
Tween 81
Propylene glycol
Triethylene glycol
Isopropyl alcohol
Water (deionized)
Butane
Formula 4"
Triethylene glycol
Emulsifier
Sodium nitrate
Perfume
Water (deionized)
Butane
Percent
By Weight
3.0
86.5
5.0
.5
5.0
10.8
48.0
35.0
1.2
5.0
0.5
1.3
0.7
3.0
2.0
8.0
44.5
40.0
3.00
0.75
0.05
0.50
60.70
35.00
Volatility
NV
V
-
V
V
V
V
V
V
V
V
NV
NV
V
NV
V
-
V
NV
NV
-
V
-
V
VOC PROC
Emitted(X) Emitted(2)
92.0 87.0
100.0 60.0
51.5 51.5
35.5 35.5
*Chalmers and Bathe (1979)
-16-
-------
B/83A-025-68b/tt2
TILE AND BATHROOM CLEANER - AEROSOL AND NONAEROSOL
National Consumption Population Geographic
(million Ib) Apportionment Multiplier
651 .11 (CA)2 NA
.046 (NY)
.036 (NJ)
Calculated from Kline (1982)
2U.S. Bureau of the Census (1986)
-17-
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B/834-025-68b/#2
TILE AND BATHROOM CLEANER FORMULATIONS
Percent
By Weight Volatility
VOC PROC
Emitted(%) Emitted(%)
Formula 1
0-Benzyl-p-chlorophenol 0.14% NV
Tetrasodium EDTA 4.56 NV
Isopropyl alcohol 2.40 V
Inert ingredients* 92.90 NV
*Includes cleaners, detergents,
and borax
Formula 2a
Alkyldimethylbenzylammonium
chloride 0.10% NV
Tetrasodium EDTA 1.52 NV
Sodium metasilicate 0.06
Inert ingredients 98.32 NV
Formula 3*
Sodium o-phenylphenolate 0.20% NV
Tetrasodium EDTA 2.75 NV
Sodium n-dodecylbenzene sulfonate 0.35 NV
Inert ingredients 96.70 NV
Formula 4b
Abrasive 88 NV
Sodium tripolyphosphate 5
Aklyl aryl sodium sulfonate 5
Trisodium sulfonate 2
Formula 5b
Stoddard solvent 0-31 V
Morpholine 0-2 V
Trisodium phosphate 0-3
Soap 0-3
Wetting agent 0-1 NV
Silica 0-65
Water to 100
2.4
2.4
0.0
0.0
0.0
0.0
0.0-33.0 0.0-33.0
0.0
33.0
'Kline (1982)
Gosselin (1985)
-18-
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B/834-025-68b/#2
OVEN CLEANERS - AEROSOL AND NONAEROSOL
National Consumption Population Geographic
(million Ib) Apportionment Multiplier
331 .11 (CA)2 1.02 (CA)3
.046 (NY) 1.0 (NY)
=031 (NJ) 1.0 (NJ)
(1982)
2U.S. Bureau of the Census (1986)
-19-
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B/834-025-68b/tt2
OVEN CLEANER FORMULATIONS
Formula 4a
Sodium hydroxide
Sodium carboxymethyl-
cellulose
Water, to make
Percent VOC PROC
By Weight Volatility Emitted(X) Emitted(X)
Formula la
Ammonium hydroxide
Veegum T-a
1,1, 1-Trichloroethane
Tergitol NPX-b
Ethyl alcohol
Water
Above concentrate
Propellant (Butane)
Formula 2a
Salt mixture-a
Calcium carbonate, up to
Thickener
Surfactant
Biocide
Water, to make
Formula 3a
Sodium hydroxide
Kelzan-c
Veegum T-a
Antaron FC 34-d
Water
Above concentrate
Propellant (Butane)
8
2
24
24
10
32
25
75
10.0
6.0
0.2
0.1
q.s.
100.0
10
i
2
87
80
20
8.5 8.5
_
NV
V
NV
V
-
V
NV
-
NV
NV
-
20.0 20.0
_
NV
NV
NV
: -
V
10.0
7.0
100.0
0.0
0.0
NV
"Kline (1982)
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RUG AND UPHOLSTERY CLEANERS - AEROSOL AND NONAEROSOL
National Consumption
(million Ib)
1151
Population
Apportionment
.11 (CA)2
.046 (NY)
.031 (NJ)
Geographic
Multiplier
NA
(1982)
2UoS. Bureau of the Census (1986)
-21-
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B/83A-025-68b/tt2
RUG AND UPHOLSTERY CLEANER FORMULATIONS
Percent
By Weight
Formulation la
Sodium lauryl sulfate
Dimethylene oxide
Ethylene glycol monobutyl ether
Preservatives and optical
brighteners
Aqueous solution
Formulation 2a
Water
Detergent
Butane propellant
Formulation 3b
Bentonite
Petroleum distillate (light)
Wood flour
May contain:
Salicylic acid
Volatility
5.4%
0.6
2.8
1.0
91.0
85%
10
5
60-70
26
5
1
VOC PROC
Emitted(%) Emitted(%)
3.4 3.4
NV
V
V
NV
-
5.0 5.0
NV
V
26.0 26.0
_
V
NV
NV
'Kline (1982)
"Gosselin (1985)
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ALL PURPOSE CLEANERS - AEROSOL AND NONAEROSOL
National Consumption Population
(million Ib) Apportionment
5121 .11 (CA)2
.046 (NY)
.031 (NJ)
Geographic
Multiplier
1.07 (CA)3
1.0 (NY)
1.0 (NJ)
(1982)
2U.S. Bureau of the Census (1986)
3 Simmons (1983)
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ALL PURPOSE CLEANER FORMULATIONS
Percent VOC PROC
By Weight Volatility Emitted(*) Emitted^)
Formulation la
Anionic and nonionic detergents
Alkaline builders
Foam stabilizers
Solvents
Chelating agents
Sodium xylene sulfonate or
ethyl alcohol solubilizer
Ammonia
Water (including color and
fragrance)
Formulation 2a
Pine oil
Isopropyl alcohol
Soap
Ethyl alcohol
EDTA
Inert ingredients
1-4
1-3
0-1
2-4
0-1
-
0-1
to 100
30.0
10.9
10.0
-
_
49.1
2.0-4.0 2.0-4.0
NV
-
NV
V
NV
NV
-
_
-
40.9 40.9
V
V
NV
V
NV
NV
'Kline (1982)
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WINDOW AND GLASS CLEANERS - AEROSOL AND NONAEROSOL
National Consumption Population Geographic
(million Ib) Apportionment Multiplier
1741 .ll(CA)2 .98 (CA)3
.046(NY) 1.0 (NY)
0.31(NJ) 1.0 (NJ)
Calculated from Kline (1982)
2U.S. Bureau of
3 Simmons (1983)
2U.S. Bureau of the Census (1986)
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WINDOW AND GLASS CLEANER FORMULAS
% Composition VOC PROC
By Weight Volatility Emitted(%) Emitted(%)
0.0-5.0 V
0.1-2.5 V
0.1-0.2
0.05-0.15 NV
0-0.1
q.s. V
100%
Formula la
Isopropyl alcohol
Higher glycols or ethers
Ammonia
Surfactant
Alkaline builders
Dye, fragrance
Water, to make
Formula 2a
Isopropyl alcohol 5.0 .V
Higher glycols 2.00 V
Sodium lauryl sulfate-a 0.15 NV
Ammonia, 28% solution 0.15
Dye, fragrance q.s V
Water, to make 100%
Formula 3a
Dipropylene glycol monomethyl ether 4.0 V
Isopropyl alcohol 4.0 V
Pluronic F 108 detergent 0.1 NV
Ammonium hydroxide, 28% 1.0
Distilled water 90.0
Formula 4*
Detergent
Ammonia
Fragrance
Isopropyl alcohol
Water
Propellant
Formula 5b
Butyl cellosolve 3-5 V
Alcohol 3-5 V
Wetting agent 0.5-1 NV
Isopropanol 0-15 V
Dyes trace NV
Silicone trace NV
Water to 100
0.1-0.3
0.5-1.0
0.1
10.0-35.0
60.0-85.0
4.0
NV
_
V
V
_
V
0.1-7.5
0.1-7.5
7.0
7.0
8.0
8.0
14.1-39.1 14.1-39.1
6.0-25.0 6.0-25.0
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WINDOW AND GLASS CLEANER FORMULAS (Continued)
% Composition
By Weight
Volatility
VOC PROC
Eraitted(Z) Emitted(Z)
Formula 6
Isopropyl alcohol
Glycol ether
Ethylene glycol
Surfactant (usually an
anionic but occasionally
a nonionic, such as
Triton X-200 or Turkey
red oil)
Water
Butane propellant
Formual 7b
Pine oil
Fatty acid soap
Synthetic anionic or nonionic
surfactant
Sodium polyphosphates
Amines
Ammonia
17.0-42.0 17.0-42.0
6-25
10-11
1
V
V
V
NV
60-80
0-5
0-10
5-30
0-20
0-15
0-5
0-5
0.0-10.0
0.0-10.0
V
NV
NV
Kline (1982)
'Gosselin (1985)
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LAUNDRY PRODUCTS - AEROSOLS
(STARCHES, SIZINGS)
U.S.
Annual Unit
Distribution
109. 91
Average
Unit Weight
(Ib/unit)
.752
Population
Apportionment
.ll(CA)3
.046(NY)
.031(NJ)
Geographic
Multiplier
NA
NA = not available
^SMA (1984); estimated millions of Ibs filled in 1984
2WAIB (1981)
3U.S. Bureau of the Census (1986)
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LAUNDRY PRODUCTS FORMULAS
Percent
By Weight
Volatility
VOC
Emitted(X)
PROC
Emitted^)
Formula 1*
Kosol predigested starch
Borax
Tinopax ANA
Formaldehyde solution (30/K)
Sodium nitrate
Silicone emulsion LE 463
Perfume
Isopropyl alcohol
Deionized water
Butane
5.0
.2
.2
.10
.15
.8
.05
6.0
82.5
5,0
11.2
11.2
NV
NV
V
NV
V
V
Formula 2a
"Chalmers and Bathe (1979)
4.9
4.9
Gelva emulsion TS 31
Calgon
Sindar technical G4-40
Carboxymethyl cellulose
Perfume
Deionized water
Sapamine VL
Butane
3.18
.01
.03
.11
.01
91.88
.09
4.76
NV
NV
NV
NV
V
NV
V
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LAUNDRY PRODUCTS - AEROSOLS AND NONAEROSOLS
National Consumption Population Geographic
(millions Ib) Apportionment Multiplier
Prevash Stain Removers
841 .11 (CA)2 NA
.046 (NY)
.031 (NJ)
Spot Removers
2.3 .11 (CA)2 NA
.046 (NY)
.031 (NJ)
(1982)
2U.S. Bureau of the Census (1986)
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LAUNDRY PRODUCT FORMULAS
Percent VOC PROC
By Weight Volatility Emitted(%) Emitted(X)
Prevash
Formula 1*
Ethoxylated fatty alcohol sulfate 20.0
Isoparaffinic solvent 20.0
Triethanol amine oleate 3.5
Sodium xylene sulfonate 30.0
Water 25.5
Formula 2*
Ethoxylated fatty alcohol sulfate 22.0
Isoparaffinic solvent 18.0
Triethanol amine oleate 2.5
Water 57.5
Spot Removers
Formula 1"
Trichloroethylene 75.0
Butane/Isobutane 25.0
Formula 2a
Perchloroethylene 65.0
Methylene chloride 10.0
Butane/Isobutane 25.0
0.0
0.0
NV
NV
NV
NV
0.0
0.0
NV
NV
NV
V
V
V
V
V
100.0
100.0
100.0
90.0
"Kline (1982)
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WAXES AND POLISHES - AEROSOLS
National Consumption Population Geographic
(millions Ib) Apportionment Multiplier
Liquids
31 .11 (CA)2 .95 (CA)3
.046 (NY) 1.0 (NY)
.031 (NJ) 1.0 (NJ)
Aerosols
581 .11 (CA)2 .95 (CA)
.046 (NY) 1.0 (NY)
.031 (NJ) 1.0 (NJ)
'Kline (1982)
bU.S. Bureau of the Consensus (1986)
cSimmons (1983)
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VAXES AND POLISHES - FORMULATIONS - AEROSOL
Percent
By Weight
Volatility
VOC PROC
Emitted(%) Emitted(%)
Aerosols
Formula 1!
Wax
Silicone oil
Emulsifier
Solvent
Water
Butane
Formula
Wax
Silicone oil
Emulsifier
Solvent
Water
Butane
Formula 3
0.5
2.5
0.5
2.5
89.5
4.5
2.0
3.0
1.0
20.0
62.0
12.00
'Kline (1982)
NV
NV
NV
V
NV
NV
NV
V
V
7.0
7.0
32.0
32.0
34.0
34.0
Water
Solvent
Propellant (assume butane)
Waxes and oils
Emulsifiers
60.0
20.0
14.0
5.0
1.0
-
V
V
NV
NV
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OTHER HOUSEHOLD PRODUCTS - AEROSOLS
U.S.
Annual Unit
Distribution
45. 21
Average
Unit Weight
(Lbs/unit)
752
Population
Apportionment
.ll(CA)3
.046(NY)
.031(NJ)
Seasonal Geographic
Variation Multiplier
NA NA
''CSMA (1984); estimated millions of units filled in 1984
2WAIB (1981)
3U.S. Bureau of the Census, personal communication
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SHOE POLISHES, WAXES, AND COLORANTS - AEROSOLS AND NONAEROSOLS
National Consumption Population Geographic
(million Ib) Apportionment Multiplier
61 .11 (CA)2 NA
.046 (NY)
.031 (NJ)
(1982)
2U.S. Bureau of the Census (1986)
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SHOE POLISHES, WAXES, AND COLORANTS FORMULAS
Percent
By Weight
Volatility
VOC PROC
Emitted(%) Emitted(%)
Formula la
Carnauba and other waxes 6-8
Naptha 5-6
Stearate emulsifier 3
Water 75
Propellant (Butane/Isobutane) 8
Formula 2*
Acrylic, vinyl, or other
synthetic waxes * 2-15
Naptha 0-15
Alcohol and other solvents 10-50
Butane/Isobutane propellant 25-80
Formula 3
'Kline (1982)
bChalmers and Bathe (1979)
13.0-14.0 13.0-14.0
NV
V
NV
85.0-98.0 85.0-98.0
NV
V
V
V
73.0
73.0
Wax
Crystalline
wax, 70 °C
Paraffin wax, 52°-54eC
Turpentine
White spirit
Colour mix
9.5
'0.5
14.0
33.0
40.0
3.0
NV
NV
NV
V
V
NV
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OTHER HOUSEHOLD PRODUCTS - AEROSOLS
National Consumption Population Geographic
(million Ib) Apportionment Multiplier
Antistatic Sprays
31 .ll(CA)2 NA
.046(NY)
.031(NJ)
(1982)
2 U.S. Bureau of the Census (1986)
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ANTISTATIC PRODUCTS - AEROSOL AND NONAEROSOL
Percent VOC PROC
By Weight Volatility Emitted(%) Emitted(%)
Formula la 0.0 0.0
Alkyl dimethyl benzyl
ammonium chloride .l-.5% NV
Water 99.9-99.5%
Formula 2* 3.0 3.0
N-Acetylethanolamine 1-3% V
Water 97-992
"Gosselin (1984)
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ADHESIVES1 - AEROSOLS AND NONAEROSOLS
National Consumption Population Geographic
(million Ib) Apportionment Multiplier
3277.52 .11 (CA)3 NA
.046 (NY)
.031 (NJ)
Includes industrial, commercial, and consumer adhesives
2U.S. Bureau of the Census (1982)
3U.S. Bureau of the Census (1986)
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ADHESIVES
Percent VOC PROC
By Weight Volatility Emitted(%) Emitted(%)
Formula la
Milled pale crepe 55
Poly-beta pinene resin,
m.p.70°C 41
Petroleum oil 3
Polytrimethyldihydroquinoline 1
Formula 2a
Milled smoke rubber
Zinc oxide
Dehydrogenated resin
Sym-di-beta naphthyl-p-phenylene
diamine
Lanolin
Formula 3a
Polyisobutylene (high molecular
weight) 60
Polyisobutylene (viscous fluid) 40
Formula 4a
Milled smoke rubber 29
Butadiene-styrene copolymer
(70:30 ratio) 29
Hydrogenated resin ester 29
Polytrimethyldihydroquinoline 1
Petroleum oil 12
Formula 5a
Neoprene 91.74
Magnesium oxide 3.67
Zinc oxide 4.59
Solids to make 20% by weight
Toluene 80.0
NV
NV
V
NV
42
21
32
1
4
NV
NV
NV
NV
NV
NV
NV
NV
NV
NV
V
NV
V
V
3.0
3.0
0.0
0.0
0.0
0.0
12.0
12.0
80.0
80.0
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ADHESIVES (Continued)
Percent
Composition
By Weight
Volatility
VOC PROC
Emitted(%) Emitted(%)
Formula 6a
Nitrocellulose (11.4% N)
Camphor
Acetone
Ethyl alcohol 74 OP
Amyl acetate
Formula 7a
Celulose acetate butyrate
(1/2 sec.)
Polyvynyl acetate
Petrex 7-75T (dry)
Dow 276-V9
Tricresyl phosphate
Alcohol (95% Tescol)
Toluene
Ni tropropane-1*
15
6
11
44
24
20.0
2.5
7.5
10.0
2.0
12.0
43.0
3.0
85.0
85.0
NV
V
V
V
V
60.0
60.0
NV
NV
NV
NV
V
V
V
V
Commercial solvent.
"Chalmers and Bathe (1979)
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CAULKING AND SEALING COMPOUNDS - AEROSOL AND NONAEROSOL
National Consumption
(million Ib)
432. 81
Population
Apportionment
.11 (CA)2
.046 (NY)
.031 (NJ)
Geographic
Multiplier
NA
1U.S. Bureau of the Census (1984); represents only synthetic base sealants and
special performance sealants
2U.S. Bureau of the Census (1986)
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CAULKING AND SEALANT FORMULAS
Percent
By Weight
Volatility
VOC PROC
Emitted(%) Emitted(%)
Formulation la
Hypalon (chlorosulfonated
poylethylene polymer)
Elastomeric binder
Chlorinated paraffin plasticizer
Asbestos or silicon dioxide extenders
Titanium dioxide pigment
Talc (extender)
Tribasic lead maleate
Rosin, MBTS, and Thiuram
Xylene
Tributyl phosphate
Fractal A
Isopropyl alcohol
Formulation 2a
Styrenated alkyd resin
Titanium dioxide
Calcium cardonate
Asbestos fiber
Xylene
Formulation 3a
Polydimethylsiloxane
Silica
2.0
2.0
20
20
10
12
8
6
0.
10
9
3
2
40
20
85
15
NV
NV
NV
NV
NV
NV
NV
V
NV
NV
V
NV
NV
V
NV
20.0
20.0
0.0
0.0
Gosselin (1985)
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A/834-025-68a/t3
OTHER HOUSEHOLD PRODUCTS - AEROSOLS AND NONAEROSOLS
National Consumption Population Geographic
(millions Ib) Apportionment Multiplier
Carpet Deodorizers
651 .11 (CA)2 .96 (CA)3
.046 (NY) .91 (NY)
.031 (NJ) .91 (NJ)
Drain Openers
17 (million gal. liquids)1 .11 (CA)2 .94 (CA)3
293 million Ibs solid .046 (NY) .94 (NY)
.031 (NJ) .94 (NJ)
(1982)
ureau
3 Simmons (1983)
2U.S. Bureau of the Census (1986)
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CARPET DEODORIZER
Percent VOC PROC
By Weight Volatility Emitted(%) Emitted^)
Formula la 2.0 2.0
Sodium sulfate <70%
Sodium bicarbonate <25% NV
Corn starch <15% NV
Fragrance <2% NV
"Gosselin (1984)
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OTHER HOUSEHOLD PRODUCTS FORMULATIONS
Percent VOC FROC
By Weight Volatility Emitted(%) Eraitted(X)
Drain Cleaners
Formula 1 (solid)9 0.0 0.0
Sodium hydroxide 54.2
Sodium nitrate 30.45
Aluminum 4.1
Inert ingredient 11.25
Formula 2 (liquid)0 0.0 0.0
Sodium hydroxide (502 solution) 10.0
Sodium hypochlorite (5% solution) 90.0
'Kline (1982)
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SHAVING CREAM - AEROSOLS
U.S.
Annual Unit
Distribution
(millions)
162. 81
Average
Unit Weight
(Ib/unit)
.52
Population
Apportionment
.11 (CA)3
.047 (NY)
.031 (NJ)
Geographic
Multiplier
1.01 (CA)4
1.07 (NY)
1.07 (NJ)
(1985); estimated millions of units filled in 1984
2(WAIB, 1981)
3U.S. Bureau of the Census (1986)
4Based on data from Simmons (1983)
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SHAVING CREAM FORMULAS
Percent
By Weight Volatility
VOC
Emitted(%)
PROC
Emmitted(%)
Formulation 1
8.8
8.8
2,
5,
1,
000
800
000
Stearic acid (95% purity)
Palmitic acid (97% purity)
Polyoxyethylene (2) cetyl ether
Hydroxyalkyl cellulose (Klucel HA) 0.067
Carbopol 934 0.180
Propylene glycol dipelargonate 2.750
Sorbitol (70% solution) 10.000
Propylene glycol 3.300
Triethanolamine 4.200
Water (deionized) 67.953
Fragrance, dye insign.
n-butane 0.550
n-pentane 2.200
Formulation 2
Palmitic acid
Myristic acid
Myristyl alcohol
Polyoxyethylene (20) cetyl ether
Laurie diethanolamide
Propylene glycol
Glycerol
Triethanolamine
Water (deionized)
Perfume
Concentrate
Propellant (Butane 48)
1.95
0.62
2.10
5.23
5.23
0.82
3.54
1.54
78.97
insign.
97.0
3.0
Formulation 3
Stearic acid
Laurie acid
Liquid anolin (Fluilan)
Cromeen
Triethanolamine
Water (deionized)
Perfume
Concentrate
Butane
4.0
2.0
1.0
3.0
2.5
87.5
insign.
96.0
4.0
NV
NV
NV
NV
NV
V
NV
V
NV
V
V
V
NV
NV
NV
V
NV
V
NV
NV
NV
NV
NV
NV
NV
V
V
8.9
8.9
4.0
4.0
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SHAVING CREAM FORMULAS (Continued)
Percent VOC PROC
By Weight Volatility Emitted(£) Eraitted(^)
Formulation 4
Palmitic acid
Laurie acid
Sodium lauryl sulphate
Polyethylene glycol (400)
monolaurate
Polyacrylic acid (40% aq.)
mol.wt 100.000
Triethanolamine
Potassium hydroxide
Glycerol
Water (deionized)
Perfume
Concentrate
-
5.0
1.0
1.0
0.5
1.5
2.0
0.8
5.0
83.2
insign.
96.9
Propellants, isobutane/propane 3.1
3.1 3.1
NV
NV
NV
NV
NV
NV
-
NV
-
V
V
Source: Harry's Cosmeticology (1982)
^romeen (Croda Chemicals Ltd.) is a substituted alkyl amine derivative of
various lanolin acids
2Listed as a chlorofluorocarbon propellant, now banned. WAIB states that
propane or butane are the most likely substitutes.
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HAIR PRODUCTS - AEROSOLS
U.S.
Annual Unit
Distribution
(millions)
Average
Unit Weight
(Ib/unit)
Population
Apportionment
Geographic
Multiplier
Hair Spray
270.71
.632
.046 (NY)
.032 (NJ)
.11 (CA)
.93 (CA)
.87 (NY)
.87 (NJ)
Mousse
106. I
.38
.046 (NY)
.031 (NJ)
.11 (CA)
NA
(1984); estimated millions of units filled in 1984
2WAIB (1981)
3U.S. Bureau of the Census (1986)
4 Simmons (1983)
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HAIR SPRAY FORMULATIONS
Percent
By Weight
Volatility
VOC
Emitted(%)
PROC
Emitted^)
Formulation la 88.1
Amphomer 1.80 NV
AMP 0.30 V
Monamid 716 0.10 NV
DC 193 Fluid 0.05 NV
Ethanol 40-1 (Anhyd) 52.75 V
Water 10.00
Methylene Chloride V
(Non-PROC)
Dimethyl Ether 35.00 V
Formulation 2* 97.4
Resyn 28-2930 2.50 NV
AMP 0.20 V
Monamid 716 0.10 NV
DC 193 Fluid 0.05 NV
Ethanol 40-1 (Anhyd) 47.15 V
Water
Methylene Chloride 15.00 V
(Non-PROC)
Dimethyl Chloride 35.00 V
Formulation 3b 95.9
Gantrez ES 225 or ES 425 4.00 NV
AMP 0.08 V
Polyethoxylated (75 EO) lanolin 0.10 NV
Perfume oil 0.10 V
Solvents 75.72 V
Isobutane/propane (90s 10) 20.00 V
Formulation 4b ... 97.5
Resyn 28-2930 1.50 NV
AMPD 0.38 NV
Alcohol-soluble lanolin 0.90 NV
Isopropyl myristate 0.40 NV
Dipropyleneglycol 0.10 NV
Perfume oil 0.35 V
Ethanol 96.37 V
Concentrate 75.00
Isobutane/propane (90:10) 25.00
88.1
82.4
95.9
97.5
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HAIR SPRAT FORMULATIONS (Continued)
Percent VOC PROC
By Weight Volatility Emitted(%) Emitted^)
Formulation 5b
Resyn 28-2930
AMP
Diraethicone copolyol*
Perfume
Methylene chloride
Et Hanoi
Carbon dioxide
*CTFA; polymer of dimethylsiloxane
polyoxypropylene side-chains.
2.25
0.18
0.12
0.10
20.00
72.85
4.50
with
93.1 73.1
NV
V
NV
V
V
(Non-PROC)
V
NV
(Non-PROC)
polyoxyethylene and/or
'Novak et al (1985)
bHarry's Cosmeticology (1982)
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STYLING MOUSSE FORMULAS
Percent VOC PROC
By Weight Volatility Emitted(%) Emitted(%)
Formulation 1 24.5 24.5
Polyquaternium-4 (2% solution) 50.00 NV
Quaternium-26 0.75 NV
Stearmidopropyl Cetearyl Dimonium
Tosylate (and) propulene glycol 0.50 V
Cetyl Alcohol 0.50 NV
Deionized Water 9.50
Ethanol 20.00 V
95X concentrate, 5% propane/isobutane propellant
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OTHER HAIR CARE PRODUCTS - AEROSOL AND NONAEROSOL
(SHAMPOOS)
National Consumption Population Geographic
(millions Ib.) Apportionment Multiplier
644.61 .11 (CA)2 1.01 (CA)3
.046 (NY) .00 (NJ)
.031 (NJ) .99 (NJ)
Calculated from Predicast (1984)
2U.S. Bureau of the Census (1986)
3 Simmons (1983)
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SHAMPOO FORMULATIONS
Percent VOC PROC
By Weight Volatility Emitted(%) Emitted(%)
Formula 1
Ammonium lauryl ether sulphate
Cocoamino betaine 31-32%
Sandopan TFL cone. 48%*
Adipic acid/dimethylamino
hydroxypropyl diethylene-
triamine copolymer
(Cartaretine F4)
Citric acid anhydrous
Water
25.00
25.00
4.20
3.33
0.98
to 100.00
0.0 0.0
NV
NV
NV
NV
NV
-
Formula 2 0.5 0.5
Polymer JR 30 M (CTFA:
Quaternium 19)
(MW = 30,000) 1.5 NV
Miranol C2MSF (CTFA:
Amphoteric 2) 70% 11.0 NV
Sandopan DTC acid (CTFA:
Trideceth-7-carboxylic
acid) 90% 15.0 NV
Ethyleneglycol distearate 2.0 NV
Methyl p-hydroxybenzoate 0.2 V
Propyl p-hydroxybenzoate 0.05 NV
Protein hydrolysate 0.5 NV
Perfume oil 0.3 V
Water to 100.0
Formula 3 0.0 0.0
Coconut amidopropyl-3-
dimethylamine betaine 5.4 NV
Sodium lauryl sarcosinate 5.2 NV
Ethoxylated tridecyl alcohol
(20 EO) 14.0 NV
Cationic cellulose (Polymer JR:
Union Carbide) 0.5 NV
Water to 100.0
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PHARMACEUTICALS - AEROSOLS
U.S.
Annual Unit
Distribution
(millions)
43. 71
Average
Unit Weight
(Ib/unit)
.252
Population
Apportionment
.11 (CA)3
.046 (NY)
.031 (NJ)
Geographic
Multiplier
1.08 (CA)4
o98 (NY)
.98 (NJ)
1CSMA (1984)
2WAIB (1981)
3U.S. Bureau of the Census (1986)
"Data for fungicides only (Simmons, 1983)
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PHARMACEUTICAL FORMULAS
Percent
By Weight
Volatility
VOC
Emitted(%)
PROC
Emitted(%)
Fungicides
Formulation la
Copper undecylenate 0-5% NV
Undecylenic acid 2-5% NV
Zinc undecylenate 0-20% NV
Available as:
Foam with 34.65% base V
Foam (aerosol) also contains:
Ethyl alcohol 60% V
Menthol 0.25% V
Methylbenzethonium chloride 0.1% NV
Formulation 2a
Benzoic acid 1-5% NV
Boric acid 0-15%
Salicylic acid 1-3% NV
Thymol 0-1% NV
Available as:
Spray with 80-92% base V
Formulation 3*
Alcohol 36-50%
Benzethonium 0.5% NV
Available as:
Spray with 50-63%
base/propellant V
May contain Salicylanilide 2.5% NV
69.9-97.9 69.9-97.9
78.0-90.0 78.0-90.0
97.0-99.5 97.0-99.5
"Gosselin (1984)
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COLOGNES, PERFUMES, AFTERSHAVES - AEROSOLS AND NONAEROSOLS
Perfumes
Colognes
U.S.
Annual Unit
Distribution
(millions)
821
44
Aftershaves 23
Average
Unit Weight
(Ib/unit)
0.032
0.125
0.25
Population
Apportionment
.11 (CA)3
.046 (NY)
.031 (NJ)
Same
Same
Geographic
Multiplier
NA
NA
NA
(1986)
2A shelf survey shoved that 'perfumes were typically 0.5 oz (.03 Ib), colognes
typically 2 oz (0.125 Ib), and aftershaves typically 4 oz (0.25 Ib)
3U.S. Bureau of the Census (1986)
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PERFUMES, COLOGNES, AND AFTERSHAVE FORMULAS
Percent VOC PROC
By Weight Volatility Emitted(Z) Emitted(JK)
Perfumes8 :
Formula 1
Perfume oil
Denatured alcohol
(SDA-40, 40-B, 39-C)
Colognes* ;
Formula 1
Perfume oil1
Denatured alcohol
Aftershaves'" :
Formula 1
Polawax A 31
Menthol
Alcohol 740 P
Demineralized water
Perfume
15-30
70-85
5-10
90-95
2.0
0.1
64.2
33.2
0.5
V
V
V
V
NV
V
V
NV
V
100.0 100.0
100.0 100.0
64.8 64.8
1Perfume oils can be composed of hundreds of different natural and synthetic
compounds and therefore cannot be characterized.
"Wenningen (1986); Etheridge (1986)
"Gosselin et al. (1984)
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PERSONAL DEODORANTS AND ANTIPERSPIRANTS - AEROSOLS
U.S.
Annual Unit
Distribution
(millions)
156. O1
Average
Unit Weight
(Ib/unit)
.25 Ibs/unit2
Population
Apportionment
.11 (CA)3
.046 (NY)
.031 (NJ)
Geographic
Multiplier
.86 (CA)4
.89 (NY)4
.89 (NJ)4
1CSMA (1984)
2WAIB (1981)
3U.S. Bureau of the Census (personal communication)
4Simmons (1983)
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DEODORANT AND ANTIPERSPIRANT FORMULATIONS
Percent
By Weight
Volatility
VOC PROC
Emitted(%) Emitted(%)
Formulation la
Alcohol (ethyl) 0->50 V
Propellant (Butane) 0->50 V
Antiperspirant salts
(e.g., aluminum chlorhydroxide) 0-10 NV
Deodorant agents 0-5 V
Other [oils, humectants,
suspending agents (e.g.,
bentonite)] 0-10 NV
Formulation 2"
80.0-90.0 80.0-90.0
89.0-95.0 89.0-95.0
Propellant (Butane)
Talc and fillers
Alcohol (ethyl)
Essential oil (fragrance)
Humectants
Formulation 3a
Aluminum phenolsulfonate
Propylene glycol
Alcohol
Perfume
>50
0-10
0-5
0.1-1
0.1-1
10.0
5.0
85.0
insign.
V
NV
V
V
NV
90 90
NV
V
V
V
'Gosselin (1984)
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OTHER PERSONAL CARE PRODUCTS - AEROSOLS
U.S.
Annual Unit
Distribution
(millions)
152
Average
Unit Weight
(Ib/unit)
.133
Population
Apportionment
.11 (CA)4
.046 (NY)
.033 (NJ)
Seasonal
Variation
1.0/0.0
Geographic
Multiplier
Sun tan lotions
1.16 (CA)5
1.06 (NY)5
1.06 (NJ)5
1.08 (NJ)'
Depilatories
1.03 (CA)5
1.08 (NY)5
:Suntan lotions and depilatories are combined in units distributed. Until
better data become available, we assume 80 percent of sales are suntan
products and 20 percent depilatories (11 million units suntan products, 2.7
million depilatories).
2CSMA (1984); estimated millions of units filled in 1984
3WAIB (1981)
4U.S. Bureau of the Census (1986)
5Simmons (1983)
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OTHER PERSONAL CARE PRODUCTS FORMULAS
Percent
By Weight
Volatility
VOC PROC
Emitted(%) Emitted(%)
Depilatories
Formulation 1
Thioglycolate (calcium or
ammonium)
Hydroxide (calcium or sodium)
Emulsifiers, humectants, waxes
Demineralized water
Propane/butane
Formulation 2
light
Calcium carbonate,
Calcium hydroxide
Calcium thioglycolate
trihydrate
Cetyl alcohol, flakes
Perfume
Sodium lauryl sulfate
Sodium silicate solution
Distilled or deionized water
Propellant: Butane/propane
Suntan Lotions
Formulation 1
Water
Fats, oils, waxes
Emulsifiers
Humectants
Preservatives
Essential oil (fragrance)
Sunscreen agent
Formulation 2
Monoglyceryl p-aminobenzoate
Mineral oil
Sorbitan monostearate
Polyoxyethylene sorbitan
monostearate
Demineralized water
5-10
2-6
0.1-1
up to 100
up to 10
0-21
0-1.5
2.2-6
0-4.5
0-0.5
0-0.5
0-3.5
up to 100
10
>50
10-25
1-10
0-10
0.1-1
0.1-1
1-5
3.0
25.0
4.0
6.0
62.0
10.0
10.0
NV
NV
V
10.5
10.5
NV
NV
V
NV
0.1-1.0
0.1-1.0
NV
NV
NV
NV
V
NV
NV
NV
NV
NV
0.0
0.0
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OTHER PERSONAL CARE PRODUCTS FORMULAS (Continued)
Percent VOC PROC
By Weight Volatility Emitted^) EmittedU)
Formulation 3
Oils (e.g., mineral) >50
Emollient 1-10
Thickeners 1-10
Sunscreen agent 1-5
Preservatives 0.1-1
Color 0.1-1
Essential oil (fragrance) 0.1-1
Formulation 4
Methyl anthranilate 5.0
Propylene glycol rinicoleate 10.0
Glycerol 10.0
Alcohol 65.0
Water 10.0
Formulation 5
2-Ethyl hexyl salicylate 5.0
Sesame oil 40.0
Mineral oil 55.0
NV
NV
NV
NV
NV
NV
V
NV
NV
NV
V
0.1-1.0
0.1-1.0
65.0
65.0
0.0
0.0
NV
NV
NV
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AUTOMOTIVE CLEANERS - AEROSOLS AND NONAEROSOLS
U.S.
Annual Unit
Distribution
(millions)
14. 71
Average
Unit Weight
(Ib/unit)
.8752
Population
Apportionment
.11 (CA)3
.046 (NY)
.031 (NJ)
Geographic
Multiplier
NA
(1985)
2WAIB (1981)
3U.S. Bureau of the Census (1986)
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AUTOMOTIVE CLEANERS - AEROSOL AND NONAEROSOL*
Percent VOC PROC
By Weight Volatility Emitted(%) Emitted(%)
Formula 1 9.0 9.0
Water 67%
Anionic and Nonionic surfactants 22% NV
Isopropanol 8% V
Glycol ether 1% V
Borax 1%
Thickener 1%
Formula 2 23.0 23.0
Inorganic polishing agents 42%
Water 25%
Petroleum distillates 23% V
Vegetable oils 5% NV
Detergents 5% NV
Formula 3 60.0 60.0
Petroleum napthas 50-60% V
o-Benzyl-p-chlorophenol .1% NV
Petroleum and synthetic waxes 40-50% NV
Formula 4 0.0 0.0
Alkyl aryl sodium sulfonate 40% NV
Sodium sulfate 60%
Formula 5 2.0 2.0
Sodium dodecylbenzene sulfonate
(alkyl aryl sodium sulfonate) 40-100% NV
Sodium sulfate 15-25%
Alkyl diethanolamine
Nonionic detergents
Formula 6
Dodecyl benzene sulfonate
Coconut oil amine
Water
Formula 7
Oxalic acid
Boric acid
2%
10-15%
6%
2%
92%
40%
60%
V
NV
0.0
NV
NV
-
0.0
"
0.0
0.0
'Gosselin (1984)
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a
AUTOMOTIVE CLEANERS - AEROSOL AND NONAEROSOL* (Continued)
Percent VOC PROC
By Weight Volatility Emitted(%) Emitted(Z)
Formula 8 100.0 100.0
Petroleum ethers 100% V
*Gosselin (1984)
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AUTOMOTIVE ENGINE DEGREASERS - AEROSOLS
U.S.
Annual Unit
Distribution
(millions)
23. 91
Average
Unit Weight
(Ib/unit)
.8752
Population
Apportionment
.11 (CA)3
.046 (NY)
.031 (NJ)
Geographic
Multiplier
NA
:CSMA (1984); estimated millions of units filled in 1984
2WAIB (1981)
3U.S. Bureau of the Census (1986)
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ENGINE DEGREASER FORMULATIONS
Percent VOC PROC
By Weight Volatility Emitted(%) Emitted(%)
Formulation 1*
Ethylene dichloride 63
(Other chlorinated hydro-
carbons may be substituted,
such as o-dichlorobenzene,
dichloropentane, methylene
dichloride, 1,1,1-
trichloroethylene)
Cresol (low-boiling cresylic 25
acids may be substituted)
Oleic acid 7.2
Potassium (or sodium) hydroxide 1.4
Water 3.0
This formulation equals 90% by weight
Butane Propellant* 10%
Formulation 2a
Methylene chloride 0.25
Perchloroethylene 5-60
Stoddard solvent 40-70
Butane Propellant* 10
Formulation 3
Perchloroethylene 0-60
Trichloroethane 0-60
Methylene chloride 0-25
Petroleum solvents 40-70
Chlor-aromatic solvents (see 0-100
o-dichlorobenzene, chlorinated
naphthalenes)
Detergent trace
Emulsifier trace
Butane Propellant* 10
89.2
89.2
V
V
NV
V
V
V
V
V
V
V
V
V
V
NV
NV
V
100.0
99.8
100.0
75.0-100.0
*Estimated from WAIB (1981) and CSMA (1986)
'Gosselin (1984)
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LUBRICANTS AND SILICONES - AEROSOL AND NONAEROSOL
u.s«.
Annual Unit
Distribution
(millions)
75. A1
Average
Unit Weight
(Ib/unit)
.442
Population
Apportionment
.11 (CA)3
.046 (NY)
.031 (NJ)
Geographic
Multiplier
NA
(1984); estimated millions of units filled in 1984
2Averaged from data in WAIB (1981)
3U.S. Bureau of the Census (1986)
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LUBRICANTS AND SILICONES - AEROSOL AND NONAEROSOL
Percent VOC PROC
By Weight Volatility Emitted(%) Emitted(%)
Formula 1* 0.0 0.0
Mineral oils 85-100% NV
Cl.SP compounds 0-10% NV
Isobutylene polymers 0-5% NV
Formula 2a 100.00 100.00
Colloidal graphite dispersion in
aliphatic naptha 5% V
Oxygentated organic acids 20% V
Naptha (aliphatic) 65% V
Tricresyl phosphate 10% V
Nonylphenoxy acetic acid trace V
'Gosselin (1984)
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UNDERCOATING - AEROSOLS
U.S.
Annual Unit
Distribution
(millions)
8.31
Average
Unit Weight
(Ib/unit)
.752
Population
Apportionment
.11 (CA)3
.046 (NY)
.031 (NJ)
Geographic
Multiplier
NA
(1984); estimated millions of units filled in 1984
2WAIB (1981)
3U.S. Bureau of the Census (1986)
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UNDERCOATING FORMULAS
Percent VOC PROC
By Weight Volatility Emitted^) Emitted(%)
Formulation 1
25-85
25-85
Pigment (15-50%)
Iron oxide
Silicates
Lead or lead salts
Zinc and zinc salts
May contain:
Titanium dioxide
Vehicle (50-85%)
Alkyd resin
Phenolic resin
Fish oil
Vegetable oil
Aromatic hydrocarbons
Aliphatic hydrocarbons1
0-50
0-50
0-50
0-50
0-50
0-50
0-50
0-25
0-25
0-50
0-50
_
_
_
_
NV
NV
NV
NV
V
V
'Gosselin (1984)
1Assumes that at least 50 percent of vehicat consists of aromatic or aliphtic
hydrocarbons
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BRAKE CLEANERS - AEROSOLS
U.S.
Annual Unit
Distribution
(millions)
16. 61
Average
Unit Weight
(Ib/unit)
1.132
Population
Apportionment
.11 (CA)3
.046 (NY)
.031 (NJ)
Geographic
Multiplier
NA
(1984); estimated millions of units filled in 1984
2WAIB (1981)
3U.S. Bureau of the Census (1986)
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AUTOMOTIVE BRAKE CLEANERS - AEROSOL AND NONAEROSOL*
Percent VOC PROC
By Weight Volatility Emitted(%) Emitted(%)
Formula 1 100.0 100.0
Methyl alcohol 100% V
Formula 2 100.0 100.0
Ethyl alcohol 100% V
Formula 3 100.0 100.0
Isopropyl alcohol 100% V
"Gosselin (1984)
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TIRE INFLATOR AND SEALANT - AEROSOLS
U.S.
Annual Unit
Distribution
(millions)
19.3
Average
Unit Weight
(Ib/unit)
.692
Population
Apportionment
.11 (CA)3
.46 (NY)
.031 (NJ)
Geographic
Multiplier
NA
(1985); estimated millions of units sold in 1984
2WAIB (1981)
3U.S. Bureau of the Census (1986)
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CARBURETOR AND CHOKE CLEANER - AEROSOLS
U.S.
Annual Unit
Distribution
(millions)
39. 81
Average
Unit Weight
(Ib/unit)
.752
Population
Apportionment
.11 (CA)3
.047 (NY)
.031 (NJ)
Geographic
Multiplier
NA
(1984); estimated millions of units filled in 1984
2WAIB (1981)
3U.S. Bureau of the Census (1986)
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CARBURETOR CLEANER FORMULAS
Percent VOC PROC
By Weight Volatility Emitted(%) Emitted(%)
Formulation la
Ethylene dichloride
(Other chlorinated hydro-
carbons may be substituted,
such as o-dichlorobenzene,
dichloropentane, and
raethylene dichloride)
Cresol (low-boiling cresylic
acids may be substituted)
Oleic acid
Potassium hydroxide (sodium
hydroxide)
Water
Butane propellant*
Formulation 2a
Aliphatic or Aromatic hydro-
carbons with oil soluble
wetting agents
Butane*
Formulation 3a
56.2
22.3
6.4
1.2
3.0
10.7
88
12
Gosselin (1984)
*Estimated from WAIB (1981) and CSMA (1986)
66.9
66.9
V
NV
NV
V
100.0
100.0
V
V
28.0-72.0 28.0-72.0
Tall Oil
Cresol
Potassium Hydroxide
Ethylene dichloride
Sodium chromate
Ammonium oxalate
Alcohol
Water
Butane*
5-18
10-25
1-4
15-50
.5-5
.3-3
1-10
10-40
12
NV
NV
-
V
-
NV
V
-
V
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ENGINE STARTING FLUIDS - AEROSOLS
U.S.
Annual Unit
Distribution
(millions)
30. 81
Average
Unit Weight
(Ib/unit)
.562
Population
Apportionment
.11 (CA)3
.046 (NY)
.031 (NJ)
Geographic
Multiplier
NA
(1984); estimated millions of units filled in 1984
2WAIB (1981)
3U.S. Bureau of the Census (1986)
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AUTOMOTIVE STARTING FLUIDS - AEROSOL AND NONAEROSOL*
Percent VOC PROC
By Weight Volatility Emitted(%) Emitted(%)
Formula 1 100.0 100.0
Ethyl Ether 100% V
'Gosselin (1984)
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AUTO WINDSHIELD WASHER FLUID AND DEICER
U.S. Average
Annual Unit Unit Weight Population Geographic
Distribution (Ib/unit) Apportionment Multiplier
(millions)
Windshield Washer Fluid
NA NA ,11 (CA)3 NA
.046 (NY)
.031 (NJ)
Windshield Deicer
10. 41 I2 .11 (CA)3 NA
.046 (NY)
.031 (NJ)
(1985)
2WAIB (1981)
3U.S. Bureau of the Census (1986)
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AUTO WINDSHIELD DEICER FORMULATION
Percent
By Weight Volatility
Formula 1
Isopropyl alcohol
Ethylene glycol
Water
Propellant, C02
Formula 2b
Isopropanol
Isobutone propellant
Formula 3b
Isopropanol
Ethylene glycol
Water
Fropellant, C02
Formula 4
Isopropanol
N-propanol, propyleneglycol,
ethylene glycol
Water
25
50
25
90-95
5-10
23.8
47.5
23.8
5.0
30-100
15-30
5-15
V
V
_
V
V
V
V
V
-
V
V
"~
VOC PROC
Emitted(X) Emitted(%)
75.0 75.0
100.00 100.00
76.3 71.3
95.0 95.0
'Chalmers and Bathe (1979)
'Gosselin (1984)
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HERBICIDES AND FUNGICIDES - AEROSOL AND NONAEROSOL
National Consumption Population Geographic
(million Ib) Apportionment Multiplier
692 .ll(CA)3 NA
.047(NY)
.031(NJ)
(1981)
2U.S. Bureau of the Census (1986)
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HERBICIDES AND FUNGICIDES - AEROSOL AND NONAEROSOL*
Percent VOC PROC
By Weight Volatility Emitted(%) Emitted(%)
Herbicides
Formula 1 95.0 95.0
Aromatic hydrocarbons
(primarily xylenes) 95% V
Inert ingredients 5% NV
Formula 2 59.2 59.2
Bromocil 40.8%
Inert ingredients 39.2%
(including an ethanol amine)
Formula 3 0.0 0.0
Bromocil 4% NV
Granular mineral base 96% NV
Formula 4 30.0 3.0
Monuron 17.69% NV
Trichloracetate acid 14.56% NV
Aromatic petroleum solvent 20-30% V
Dodecylbenzene sulfonic acid,
corrosion inhibitor, and
inert ingredients 35-45% NV
Formula 5 22.0 22.0
4-amino-3,5,6-trichloropicolinic
acid, isoctyl esters 15.1% NV
2,4,5-trichlorophenoxyacetic
acid, propylene glycol butyl
ether esters 63.4% NV
Inert ingredients (aromatic
petroleum solvent, methanol) 0-21.5% V
Formula 6 80.0 8.0
Urox liquid oil concentrate 18-20% NV
Heavy aromatic naptha 80-82% V
"Gosselin (1984)
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HERBICIDES AND FUNGICIDES - AEROSOL AND NONAEROSOL (Continued)
Percent VOC PROC
By Weight Volatility Emitted(%) Emitted(%)
Formula 7 0.0 0.0
4-amino-3,5,6-trichloropicolinic
acid, potassium salt 2.3% NV
Disodium tetraborate pentahydrate 79.2%
Disodium tetraborate decahydrate 16.5%
Formula 8 38.0 38.0
Picloram, isooctyl esters 62.4% NV
Heavy aromatic naptha, methanol 0-37.6% V
Formula 9 0.0 0.0
Sodium metaborate tetrahydrate 68%
Sodium chlorate 30%
Inert ingredients 2% NV
Formula 10 0.0 0.0
Sodium metaborate tetrahydrate 66.5%
Sodium chlorate 30%
Bromacil 1.5% NV
Inert ingredients 2% NV
Formula 11 93.0 93.0
Aliphatic petroleum distillates 83.27% V
Xylene 9.65% V
2,4-Bis(isopropylamino)-6-
methoxy-5-triazine .86% NV
Inert ingredients 6.22% NV
Fungicides
Formula 12 0.0
Copper sulfate 50%
Lime 50%
"Gosselin (1984)
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HERBICIDES AND FUNGICIDES- AEROSOL AND NONAEROSOL (Continued)
Percent VOC PROC
By Weight Volatility Emitted(%) Emitted(X)
Formula 13 30.0 30.0
Copper 8%
Copper naphthenate 70-80% NV
Petroleum distillate 20-30% V
Formula 14 45.0 45.0
Zinc naphthenate 55-60% NV
Petroleum distillate 40-45% V
Zinc 8%
aGosselin (1984)
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HOUSEHOLD POLISH FORMULATIONS - AEROSOL AND LIQUID
Percent VOC PROC
By Weight Volatility Emitted(£) Eraitted(%)
Liquids
Formula 1
Hard waxes
Microcrystalline wax
Silicone fluid
Naphtha or turpentine
Formula 2
Hard waxes
Microcrystalline wax
Silicone fluid
Naphtha or turpentine
Formula 3
Carnauba wax
Beeswax
Microcrystalline wax
White spirit or naptha
Stearic acid
Triethanolamine
Water
Formula 4
Carnauba wax
Beeswax
Microcrystalline wax
White spirit or naptha
Stearic acid
2-Amino-2 methyl-propanol
Water
Formula 5
Hoechst Wax 0
Ceresin
Silicone fluid 220/350 cS
Span 80
White spirit: turpentine 1:1
Deionized water
Perfume
13
8
9
70
3
1
2
94
4.2
2.2
.7
24.0
2.5
1.7
64.7
5.00
1.76
.70
24.00
2.81
1.76
63.97
2.0
1.5
2.5
1.5
28.5
64.0
q.s.
NV
NV
NV
V
NV
NV
NV
V
NV
NV
NV
V
NV
NV
-
NV
NV
NV
V
NV
V
-
NV
NV
NV
NV
V
-
V
70.0 70.0
94.0 94.0
24.0 24.0
25.76 25.76
28.5 28.5
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HOUSEHOLD POLISH FORMULATIONS (Continued)
Percent
By Weight
Volatility
VOC
Emitted(%)
PROC
Emitted(%)
Formula 6
37.0
37.0
Hoechst Wax
Oleic acid
Morpholine
White spirit
Silicone oil 350 cS
Silicone oil 10 000 cS
Deionized water
Perfume
8.0
1.3
1.0
36,0
1.5
2.0
50.2
q.s.
NV
NV
V
V
NV
NV
V
*Kline (1982)
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FLOOR POLISHES AND VAXES - NONAEROSOL
National Consumption Population Geographic
(million Ib) Apportionment Multiplier
271 .11 (CA)2 1.04 (CA)3
.046 (NY) 1.02 (NY, NJ)
.031 (NJ)
(1982)
2U.S. Bureau of the Census (1986)
3 Simmons (1983)
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FLOOR WAX AND POLISH FORMULATIONS - NONAEROSOL
Percent
By Weight Volatility
Formula 1*
Rhoplex B 38%-a
Polyethylene, 40%
Diethylene glycol
monomethylether
ACRYSOL leveling aid, 42%
Tributoxyethyl phosphate
Dibutyl phthalate
Formalin, 37%
Wetting agent, 1%
Silicone defoamer
Water or inorganic base to 100%
Formula 2a
Rhoplex B 38%-a
Polyethylene, 40%
Diethylene glycol
monomethylether
ACRYSOL leveling aid, 42%
Anionic surfactant, 35%
Tributoxyethyl phosphate
Formalin, 37%
Wetting agent, 1%
Silicone defoamer
Water or inorganic base to 100%
Formula 3a
Rhoplex B 38%0a
POLYETHYLENE, 40%
Diethylene glycol
monome thyle ther
ACRYSOL leveling aid, 42%
Tributoxyethyl phosphate
Formalin, 37%
Wetting agent, 1%
Silicone defoamer
Water or inorganic base to 100%
31.58
5.63
4.00
1.79
1.00
1.00
0.15
0.40
0.01
37.89
6.75
2.40
2.14
1.43
1.20
0.15
0.60
0.02
64.74
11.25
6.00
2.14
1.37
0.15
0.72
0.03
NV
NV
NV
NV
NV
NV
V
NV
NV
NV
NV
NV
NV
NV
NV
V
NV
-
NV
NV
NV
NV
NV
V
NV
-
VOC PROC
Emitted(%) Emitted(%)
0.2 0.2
0.2 0.2
0.2 0.2
'Chalmers and Bathe (1979)
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METAL CLEANERS AND POLISHES - NONAEROSOL
National Consumption Population Geographic
(millions Ib) Apportionment Multiplier
241 .11 (CA)2 NA
.046 (NY)
.031 (NJ)
lKline (1982)
2U.S. Bureau of the Census (1986)
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METAL CLEANER AND POLISH FORMULAS - NONAEROSOLS
Percent
By Weight Volatility
VOC PROC
Emitted(%) Emitted(%)
Formula la
Abrasive
Soap or synthetic surfactants
Thickening agent
Ethyl or isopropyl alcohol
Water, to make
Formula 2"
Dithio-bis-stearyl propionate
Abrasive
Surfactant
Preservative
Water, to make
Formula 3b
Sulfamic, citric, tartaric acid
Sodium chloride
Anionic synthetic surfactant
Siliceous abrasive
Formula Ab
Caustic soda or potash
(see alkali)
Trisodium phosphate
Sodium metasilicate
Soap or detergent (alkly aryl
sodium sulfonate)
Formula 5
Perchloroethylene
Trichloroethylene
1,1, 1-Trichloroethane
Formula 6b
Kerosene
Potassium soap of oleic acid
Glycol ether
Surfactant
5-35
5-7
.5-1
2-5
100%
5.0
20.0
6.0
0.1
100.0
5-10
5-10
1-3
to 100
0-50
25-75
10-75
5-20
1-100
1-100
1-100
5-80
5-25
5-20
5-20
NV
NV
NV
_
NV
NV
NV
NV
-
NV
-
NV
-
-
-
-
NV
V
V
V
V
NV
V
NV
2.0-5.0 2.0-5.0
0.0 0.0
0.0 0.0
0.0 0.0
100.0 1.0-100.0
55.0-90.0 55.0-90.0
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METAL CLEANER AND POLISH FORMULAS - NONAEROSOLS (Continued)
Percent
By Weight Volatility
VOC PROC
Eraitted(%) Eraitted(%)
Formula 7b
Hydrochloric acid or one or
more of the following!
Sulfuric acid
Chromic acid
Phosphoric acid
Citric acid
Surfactant
5-25
5-20
10-25
10-25
5-10
0.0
0.0
NV
"Kline (1982)
"Gosselin (1985)
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AUTOMOTIVE ANTIFREEZES - NONAEROSOL
National Consumption Population Geographic
(million Ib) Apportionment Multiplier
22. 31 .11 (CA)2 NA
.046 (NY)
.031 (NJ)
(1983)
2U.S. Bureau of the Census (1986)
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AUTOMOTIVE ANTIFREEZE FORMULAS
Percent VOC PROC
By Weight Volatility Emitted(2) Emitted(X)
Formula la 95.0 95.0
Glycols (95% monoethylene glycol, 95 V
5% kiethylene glycol)
Alkali metal borates and phosphates 2-3
Water 2-3
Dye trace V
"Gosselin (1985)
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CAR POLISHES AND VAXES - NONAEROSOLS
U.S.
Annual Unit
Distribution
(millions)
189. I1
Average
Unit Weight
(Ib/unit)
I2
Population
Apportionment
.11 (CA)3
.046 (NY)
.031 (NJ)
Geographic
Multiplier
1.05 (CA)4
.90 (NY)
.90 (NJ)
Calculated from Simmons (1983)
2Based on a shelf survey of several different brands and formulations
3U.S. Bureau of the Census (1986)
4 Simmons (1983)
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CAR WAX FORMULATIONS
Percent
Composition
by Weight
VOC PROC
Volatibility Emitted(X) Emitted(%)
Formula la
Carnauba wax
Beeswax
White spirit or naptha
Stearic acid
Triethanolamine
Water
5.1
4.5
42.4
4.0
1.5
42.5
NV
NV
V
NV
NV
42.4
42.4
Formula 2
Carnauba wax
Beeswax
Ceresin
White spirit or naptha
Triethanolamine
Stearic acid
Water
42.3
42.3
5.00
2.00
2.00
40.00
2.25
4.00
44,75
NV
NV
NV
V
V
NV
"Chalmers and Bathe (1979)
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APPENDIX B
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REFERENCES
Broxterman, W. 1983. "Worldwide Challenges and Opportunities," Chemical Week
(March 2).
CSMA (Chemical Specialty Manufacturers Association, Inc). 1984. Pressurized
Products Survey, United States 1984.
Dictionary of Organic Compounds, 5th ed. 1982
Etheridge, M. 1986. Personal communication from Bureau of Alcohol, Tobacco
and Firearms, Washington, D.C. (February).
Federal Register. 48 FR 49097. October 24, 1983.
Gosselin, R.E, R.P. Smith, and B.C. Hodge (Eds.). 1984. Chemical Toxicology
of Commercial Products, 5th ed. Williams and Wilkins, Inc., Baltimore,
Maryland.
Hass, H.B. and R.F. Newton. 1981. "Correction of Boiling Points to Standard
Pressure." In R.C. Weast and M.J. Astle (Eds.), CRC Handbook of Chemistry and
Physics, CRC Press, Inc., Boca Raton, Florida.
Kirk-Othmer. 1978. Encyclopedia of Chemical Technology 3rd ed. Wiley and
Sons, New York.
Kline and Co., C.H. 1981. Consumer Pesticides and Fertilizers, Fairfield,
New Jersey.
Kline and Co., C.H. 1982. Household Cleansing Products, Fairfield, New
Jersey.
Micromedex, Inc. 1984. Poisindex, Colorado.
Nowak, F., P.L. Bartlett, and J.J. Daly, Jr. 1985. "Dimethyl Ether: An
Alternative Propellant for Aerosol Hair Sprays," Aerosol Age, April.
Predicasts, Inc. (PTS U.S. Time Series) 1984. Cleveland, Ohio.
Rogozen, M., R. Rapoport, and A. Shocket. 1985. Development and Improvement
of Organic Compound Emission Inventories for California.Prepared by Science
Applications International Corporation for California Air Resources Board,
Sacramento, California.
Simmons Market Research Bureau, Inc. 1983. Simmons 1983 Study of Media and
Markets.
Stratte, J.J., P.W. Dillon, and R.H. Semp. 1978. "Evaporation of Organic
Co-solvents from Water-borne Formulations: Theory, Experimental Study,
Computer Simulation," Journal of Coating Technology 50(647):39-47.
U.S. Bureau of the Census, U.S. Department of Commerce. 1986. Personal
Communication with the Office of Population Estimates.
-------
U.S. Bureau of the Census, U.S. Department of Commerce. 1982. Census of
Manufacturers.
USEPA (U.S. Environmental Protection Agency). 1979. Toxic Substances
Control Act Chemical Substances Inventory. Vols. II, III"! Office of Toxic
Substances, Washington, D.C.
USEPA (U.S. Environmental Protection Agency). 1980. Toxic Substances
Control Act Chemical Substances Inventory, Cumulative Supplement Officer of
Toxic Substances, Washington, D.C.
USEPA (U.S. Environmental Protection Agency). Volatile Organic Compound
(VOC) Species Data Manual, 2nd ed. Office of Air Quality Planning and
Standards, Research Triangle Park, North Carolina.
Verschueren, D. 1977. Handbook of Environmental Data on Organic Chemicals.
Van Nostrand Reinhold Co., New York.
WAIB (Western Aerosol Information Bureau). 1982. Prepared by Public
Relations Committee, Shashir, L., P. Robinson, D. Vehagen, T. Donaldson, and
W. Lim. Analysis of Pressurized Products Relative to Hydrocarbon Propellants
and Other Volatile Organic Compounds.
Warnick, H. 1986. Deputy Branch Chief, Office of Pesticide Programs, U.S.
Environmental Protection Agency (11 June).
Weast, R.C., and M.J. Astle (Eds). 1981. CRC Handbook of Chemistry and
Physics. CRC Press, Inc., Boca Raton, Florida.
Wennigen, J. 1986. Personal communication from Bureau of Alcohol, Tabacco
and Firearms, Washington, D.C. (February).
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TECHNICAL REPORT DATA
I Please read Ins true nons an thu revene befon completing)
1. REPORT NO.
EPA 902/4-86-001
3. RECIPIENT'S ACCESSION NO.
TITLE AND SUBTITLE
Photochemically Reactive Organic Compound Emissions
From Consumer and Commercial Products
5. REPORT DATE
November. 1986
6. PERFORMING ORGANIZATION CODE
7. AUTMQR(S)
Jones, Alan; Rich, Harvey; Sewell, Granville;
Rogozen, Michael; Katz, Michael
8. PERFORMING ORGANIZATION REPORT NO.
8. PERFORMING ORGANIZATION NAME AND ADDRESS
SCIENCE APPLICATIONS INTERNATIONAL CORPORATION
8400 Westpark Drive
McLean, VA 22102
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-02-3893
12. SPONSORING AGENCY NAME ANO ADDRESS
U.S. Environmental Protection Agency, Region II
Air Programs Branch
26 Federal Plaza
New York. NY 10278
13. TYPE OF REPORT ANO PERIOD COVERED
Final
14. SPONSORING AGENCY CODE
15. SUPPLEMENTARY NOTES
Project Officer: Paul Truchan (212) 264-2518
18. ABSTRACT
This report estimates the emissions of volatile organic compounds (VOC)
and photochemically reactive organic compounds (PROC) released from
the use of consumer products in the States of California and New Jersey,
and the New York City metropolitan area. The report describes the
data sources and methodologies that were used to estimate VOC and PROC
emissions from consumer products, and presents emission estimates broken
down by consumer product subcategory and geographic region.
KEY WORDS AND DOCUMENT ANALYSIS
DESCRIPTORS
b. IDENTIFIERS/OPEN ENDED TERMS C. COSATI Field/Group
Air Pollution
Volatile Organic Compounds
Consumer and Commercial Products
Photochemical Oxidants
New Jersey
New York
California
* DISTRIBUTION STATEMENT
.Release Unlimited
19. SECURITY CLASS iThts Report)
Unclassified
21. NO. OF PAGES
20 SECURITY CLASS iTha paget
Unclassified
22. PRICE
Farm 2220-1 (R»»- 4-77) previous COITION i $ oasouerc
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